DC680016_20240827_Soil_SG_Report

AECOM
5438 Wade Park Boulevard, Suite 200
Raleigh, NC 27607
T: 919.461.1100
aecom.com
August 28, 2024
North Carolina Department of Environmental Quality
Division of Waste Management – DSCA Program
1646 Mail Service Center
Raleigh, NC 27699
Att:Ms. Ariana Rivera
DSCA Project Manager
Re:Soil and Soil Gas Assessment Report
Carolina Cleaners DSCA Site ID DC680016
406 W. Franklin Street, Chapel Hill, Orange County, North Carolina
Dear Ms. Rivera:
AECOM Technical Services of North Carolina, Inc. (AECOM) is pleased to provide this Soil and Soil Gas
Assessment Report for the former Carolina Cleaners (site) located at 406 W. Franklin Street in Chapel Hill,
Orange County, North Carolina. Soil assessment activities were completed in accordance with the
objectives defined in the scope of work approved by DSCA under State Lead Authorization for Work (SLAW)
004, approved April 12, 2024.
Background
According to DSCA documentation, it is suspected that the former Carolina Cleaners (DSCA Site ID 680016)
operated as a dry-cleaning facility at the 406 W. Franklin Street location for an unknown duration of time
prior to 1965, though a review of historical Sanborn fire insurance maps indicates that the Carolina Cleaners
was in operation as early as 1949 at the adjacent 400 W. Franklin Street location (DSCA Site ID DC680015).
It is unknown when dry-cleaning operations began or ceased at either the 400 or 406 W. Franklin Street
locations. Other nearby DSCA dry-cleaning sites include Chapel Hill Cleaners (DSCA Site ID DC680010),
located at 422 W. Franklin Street, and One Hour Koretizing (DSCA Site ID DC680006), located at 301 W.
Franklin Street. A map depicting the location of the 406 W. Franklin site (DC680016), 400 W. Franklin site
(DC680015), the Chapel Hill Cleaners site (DC680010), and the One Hour Koretizing site (DC680006) is
included as Figure 1.
Numerous soil and vapor intrusion assessment activities have been completed to date at the Carolina
Cleaners DC680016 site, the adjacent Carolina Cleaners DC680015 site, and the Chapel Hill Cleaners
DC680010 site. A soil quality summary map for these three DSCA sites is included as Figure 2a (samples
collected from 0 to 2 feet below ground surface [bgs]) and Figure 2b (samples collected greater than 2 feet
bgs). A vapor quality summary map for these three DSCA sites is included as Figure 3. During previous
assessments, soil samples beneath the Mediterranean Deli building (410 W. Franklin Street) could not be
collected further south than SB-17 due to limited working area in the shallow crawl space beneath the
restaurant dining room and were limited in other areas by restaurant operations. On July 22, 2023, a fire
broke out in the Deli causing extensive damage to the building, destroying a large portion of the rear of the
building. Site demolition of the damaged section of building and redevelopment has removed the rear portion
of the building to ground level as the property is prepared for building renovation.
Soil and Soil Gas Sampling
As the section of the site beneath the destroyed rear portion of the Mediterranean Deli is temporarily
accessible, AECOM collected soil samples on May 7, 2024 from six soil borings (SB-18 through SB-23) in
the rear area of the former Mediterranean Deli. The locations of soil borings SB-18 through SB-23 are
indicated on Figure 2a and Figure 2b. Two samples were collected from each boring, one from the
shallowest one-foot interval and one from the interval with the highest field PID screening level, in
accordance with the Soil Sampling Using a Hand Auger AECOM Standard Operating Procedure (Appendix
A). Samples were collected, packed on ice, and submitted to Pace Analytical Services, LLC (Pace) for VOC
analysis by EPA Method 8260D.
During the May 7, 2024 sampling event, AECOM intended to collect soil gas samples from two of the soil
borings; however, due to heavy rain in early May, the soil onsite was saturated to within one foot of ground
surface and soil gas sampling was unable to be completed.
AECOM returned to the site to collect two soil gas samples (SG-5 and SG-6) on June 20, 2024. The locations
of soil gas samples SG-5 and SG-6 are indicated on Figure 3. The soil gas sampling was completed using
a vapor implant in accordance with the Soil Gas Sampling Standard Operating Procedure (Appendix A).
Samples were collected into lab-provided batch certified 1-liter summa canisters and submitted to Enthalpy
Analytical, LLC (Enthalpy) for TO-15 analysis.
A photographic log of the field work is included as Appendix B.
Results
Soil sampling results are summarized in Table 2 and Figure 2a for shallow soils (0 to 2 feet bgs) and Figure
2b for deeper soils (greater than 2 feet bgs). Results are as follows:
- Soil boring SB-22 contained tetrachloroethylene (PCE) at 0.0304 milligrams per kilogram (mg/kg)
in the shallow sample (0 to 1 feet bgs) and 3.7 mg/kg in the deeper sample (3 to 4 feet bgs), which
exceed the North Carolina Department of Environmental Quality (NCDEQ) Preliminary Soil
Remediation Goal (PSRG) of 0.0063 mg/kg. PCE degradation products trichloroethylene (TCE),
cis-1,2-dichloroethylene (cis-1,2-DCE) and vinyl chloride were also detected in the SB-22 (3 to 4
feet bgs) sample, with TCE and vinyl chloride concentrations exceeding their respective PSRGs.
- PCE was detected at 0.0266 mg/kg in the deeper sample at SB-18 (3 to 4 feet bgs), which exceeds
its PSRG.
- Volatile organic compounds were not present above laboratory reporting limits in the remaining
eight samples collected.
Soil gas sampling results are summarized in Table 4 and Figure 3. As summarized on the following table,
soil gas risk was evaluated using the DSCA Soil Gas Risk calculators, included on Appendix C,which
indicate the following:
Sample ID Sample Date
Cumulative Risk:
Resident Non-Residential Worker
CR HI CR HI
SG-5 6/20/2024 8.0E-07 0.13 4.1E-08 0.01
SG-6 6/20/2024 1.2E-03 270.0 6.3E-05 22.00
CR = Calculated cumulative carcinogenic risk; acceptable calculated risk values are less than 1E-04.
HI = Calculated non-carcinogenic hazard quotient; acceptable hazard index values are less than 1.0.
Red = Value does not exceed acceptable CR or HI
Red = Value exceeds acceptable CR or HI
NRC = No Risk Calculated because compounds were not present above the laboratory method
detection limits
As summarized above and depicted on Figure 3, soil gas contaminant concentrations exceed acceptable
calculated vapor intrusion risk for residential and non-residential worker exposure at soil gas sample location
SG-6, which is located in proximity to soil boring SB-21 and historical soil boring SB-17. Soil gas sample
location SG-5 indicates that soil gas contaminant levels near the eastern boundary of 410 W. Franklin Street
and soil borings SB-18 and SB-19 do not exceed acceptable calculated risk levels for residential or non-
residential worker exposure. It should be noted that previous soil gas sampling in this area – specifically
subslab vapor sample SS-3 – also indicated soil gas contaminant concentrations exceeding acceptable
calculated vapor intrusion risk for residential and non-residential worker exposure; however, indoor air
samples collected from within the Mediterranean Deli indicated acceptable conditions for both residential
and non-residential worker exposure.
The laboratory analytical reports for the May 2024 soil sampling event and the June 2024 soil gas sampling
event are included as Appendix D, and historical site maps are included for reference as Appendix E.
Review of Analytical Results
AECOM received Pace’s laboratory report on May 14, 2024. Based on AECOM’s review of the laboratory
report, the quality assurance/quality control issues identified by Pace appear minor and data are deemed
usable for the purposes of the assessment activities and conclusions documented in this submittal.
AECOM received Enthalpy’s laboratory report on July 8, 2024. Based on AECOM’s review of the laboratory
report, the quality assurance/quality control issues identified by Enthalpy appear minor and data are deemed
usable for the purposes of the assessment activities and conclusions documented in this submittal.
If you have any questions or require additional information, please do not hesitate to call either Rob
MacWilliams at 704-499-4839 or Michelle Friedman at 919-461-1422.
Sincerely,
Michelle Friedman, PG
Project Manager
NC License No. 2332
Robert H. MacWilliams, PG
Program Manager
Tables
Table 1 – Site Chronology
Table 2 – Analytical Data for Soil
Table 3 – Analytical Data for Sub-Slab Gas
Table 4 - Analytical Data for Soil Gas
Table 5 – Analytical Data for Indoor and Outdoor Air
Table 10 – Water Well(s) Survey Data
Figures
Figure 1 – Surrounding DSCA Site Locations Map
Figure 2a – Soil Quality Results - 0-2 foot depth
Figure 2a – Soil Quality Results - >2 foot depth
Figure 3 – Vapor Quality Results Map
Appendices
Appendix A – Standard Operating Procedures
Appendix B – Photographic Log
Appendix C – DSCA Vapor Intrusion Risk Calculators
Appendix D – Laboratory Reports
Appendix E – Historical Maps
TABLES
DSCA ID No.:
Submittal Date:
Analytical Data Tables
for
North Carolina Dry-Cleaning Solvent Cleanup Act Program
Prepared By:
Facility Name:Carolina Cleaners
406 W. Franklin Street, Chapel Hill, Orange County, NC
5438 Wade Park Boulevard, Suite 200, Raleigh, NC 27607
AECOM Technical Services of North Carolina, Inc.
August 2024
DC680016
Table 1: Site Chronology
DSCA ID No.: DC680016
Chronology of Events
It is suspected that the former Carolina Cleaners operated as a dry-cleaning facility at the 406 W. Franklin Street
location (DC680016) for an unknown duration of time prior to 1965. According to historical Sanborn fire insurance
maps, the Carolina Cleaners also was in operation in 1949 at the adjacent 400 W. Franklin Street location (DC680015).
10/20-10/27/2017 AECOM performed initial site investigation activities including indoor and ambient air sampling, subslab vapor
sampling, and soil sampling at the adjacent Carolina Cleaners (DC680015) property at 400 W. Franklin Street.
8/13/2018 The Carolina Cleaners site was petitioned into the DSCA program.
10/30/2018 AECOM completed a 0.5-mile receptor survey to identify potential sensitive populations, ecological receptors, and
water supply wells.
11/27-11/28/2018
AECOM performed Prioritization Activities (PA) at the site, including the collection of one indoor air sample (IA-
DBSutton) and one subslab vapor sample (SSV-DBSutton) at DB Sutton & Co. salon and wine store, and the collection
of three soil samples (SB-11 through SB-13) from beneath and behind the salon, as well as two additional soil samples
(SB-9 and SB-10) from the adjacent 400 W. Franklin Street location (DC680015).
6/18/2019
AECOM installed and sampled four additional soil borings to the north in the gravel parking area (SB-14), and to the
west within accessible areas inside the crawl space of the adjacent tenant space currently occupied by the Mediterranean
Deli (SB-15 through SB-17).
7/3/2019
AECOM collected two flux chamber samples (FC-1 and FC-2) in the gravel parking lot area in close proximity to
existing boring SB-13, to evaluate potential risk of vapor intrusion into existing and future structures in this area of soil
contamination.
4/26-27/2021 AECOM collected seven soil samples (SB-01 through SB-07) and one soil gas sample (SG-02-2021) from behind the
410-418 W. Franklin Street buildings to determine the extent of soil and soil gas impacts.
3/14 & 3/17/22
AECOM installed and sampled one soil gas monitoring point (SG-3) to the west of Mediterranean Deli (410 W Franklin
St), and one soil gas monitoring point (SG-4) and three sub-slab vapor points (SSV-2 through SSV-4) in the vicinity of
the Carolina Cleaners DC680015 property to determine vapor impacts from the Carolina Cleaners DC680016 site.
5/7/2024 AECOM collected two samples each from six soil boring locations (SB-18 through SB-23) in the vicinity of the former
Mediterranean Deli (410 W Franklin St).
6/20/2024 AECOM collected two additional soil gas samples (SG-5 and SG-6) in the areas of SB-18 and SB-21.
Instructions: Brief description of all significant events that have occurred since a problem was
suspected at the facility. Commence with the first date a problem was suspected and continue
through the most recent activity described in the current report.
Date
Table 2: Analytical Data for Soil
DSCA ID No.: DC680016
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SB-1 4-5'4-5 10/27/17 < 0.0012 < 0.0012 < 0.0012 < 0.0012 < 0.0012 0.0017 < 0.0012 < 0.0012 < 0.0012 < 0.0012 < 0.0024 < 0.026 0.0025 J < 0.0066 < 0.0012 < 0.0012 < 0.0012 N/A
SB-2 5-6'5-6 10/27/17 < 0.0012 < 0.0012 < 0.0012 < 0.0012 < 0.0012 0.0013 < 0.0012 < 0.0012 < 0.0012 < 0.0012 < 0.0023 < 0.026 0.0024 J < 0.0066 < 0.0012 < 0.0012 < 0.0012 N/A
SB-3 2-3'2-3 10/27/17 < 0.0012 < 0.0011 < 0.0012 < 0.0012 < 0.0012 0.0027 < 0.0011 < 0.0011 < 0.0011 < 0.0011 < 0.0022 < 0.026 < 0.0055 < 0.0066 < 0.0011 < 0.0011 < 0.0011 N/A
SB-4 1-2'1-2 10/27/17 < 0.0012 < 0.0011 < 0.0012 < 0.0012 < 0.0012 0.0016 < 0.0011 < 0.0011 < 0.0011 < 0.0011 < 0.0023 < 0.026 < 0.0057 < 0.0066 < 0.0011 < 0.0011 < 0.0011 N/A
SB-5 5-6'5-6 10/27/17 < 0.0012 < 0.0012 < 0.0012 < 0.0012 < 0.0012 0.0013 < 0.0012 < 0.0012 < 0.0012 < 0.0012 < 0.0025 < 0.026 < 0.0062 < 0.0066 < 0.0012 < 0.0012 < 0.0012 N/A
SB-6 0-1'0-1 10/27/17 < 0.0012 < 0.0012 < 0.0012 < 0.0012 < 0.0012 0.0078 < 0.0012 < 0.0012 < 0.0012 < 0.0012 < 0.0023 < 0.026 < 0.0058 < 0.0066 < 0.0012 < 0.0012 < 0.0012 N/A
SB-7 1-2'1-2 10/27/17 < 0.0012 < 0.0012 < 0.0012 < 0.0012 < 0.0012 0.0024 < 0.0012 < 0.0012 < 0.0012 < 0.0012 < 0.0024 < 0.026 0.0024 J < 0.0066 < 0.0012 < 0.0012 < 0.0012 N/A
SB-8 0-1'0-1 10/27/17 < 0.0012 < 0.0016 < 0.0012 < 0.0012 < 0.0012 0.0030 < 0.0016 < 0.0016 < 0.0016 < 0.0016 < 0.0032 < 0.026 < 0.0079 < 0.0066 < 0.0016 < 0.0016 < 0.0016 N/A
SB-9 0-1'0-1 11/28/18 < 0.0012 < 0.0012 < 0.0012 < 0.0012 < 0.0012 0.00083 J < 0.0012 < 0.0012 < 0.0012 < 0.0012 < 0.0035 0.067 0.0027 0.0067 < 0.0012 < 0.0012 < 0.0012 N/A
SB-10 2-3'2-3 11/28/18 < 0.0013 < 0.0013 < 0.0013 < 0.0013 < 0.0013 0.00070 J < 0.0013 < 0.0013 < 0.0013 < 0.0013 < 0.0040 0.03 0.0048 < 0.0066 < 0.0013 < 0.0013 < 0.0013 N/A
SB-11 0-1'0-1 11/28/18 < 0.14 < 0.14 < 0.14 < 0.14 < 0.14 16 < 0.14 < 0.14 < 0.14 < 0.14 < 0.43 < 2.9 < 0.29 < 0.72 < 0.14 < 0.14 < 0.14 N/A
SB-12 2-3'2-3 11/28/18 < 0.0010 < 0.0010 < 0.0010 < 0.0010 < 0.0010 0.00052 J < 0.0010 < 0.0010 < 0.0010 < 0.0010 < 0.0031 0.020 J 0.0028 < 0.0052 < 0.0010 < 0.0010 < 0.0010 N/A
SB-13 1-2'1-2 11/28/18 < 0.13 < 0.13 < 0.13 < 0.13 < 0.13 1.5 < 0.13 < 0.13 < 0.13 < 0.13 < 0.39 < 2.6 < 0.26 < 0.64 < 0.13 < 0.13 < 0.13 N/A
SB-14 3-4'3-4 6/18/19 < 0.0010 < 0.0010 < 0.0010 < 0.0010 < 0.0010 0.0023 < 0.0010 < 0.0010 < 0.0010 < 0.0010 < 0.0030 0.022 < 0.0020 < 0.0051 < 0.0010 < 0.0010 < 0.0010 N/A
SB-15 3-4'3-4 6/18/19 < 0.00096 0.012 < 0.00096 < 0.00096 < 0.00096 19 < 0.00096 < 0.00096 0.055 < 0.00096 < 0.0029 0.016 J < 0.0019 < 0.0048 0.00040 J < 0.00096 < 0.00096 N/A
SB-16 1-2'1-2 6/18/19 < 0.13 < 0.13 < 0.13 < 0.13 < 0.13 < 0.13 < 0.13 < 0.13 < 0.13 < 0.13 < 0.38 < 2.6 0.16 J < 0.64 < 0.13 0.75 0.63 N/A
SB-17 0-1'0-1 6/18/19 < 0.0012 < 0.0012 < 0.0012 < 0.0012 < 0.0012 < 0.0010 < 0.0012 < 0.0012 < 0.0012 < 0.0012 < 0.0035 0.029 < 0.0024 < 0.0059 < 0.0012 < 0.0012 < 0.0012 N/A
SB-01-2021 1-2'1-2 4/26/21 < 0.00087 < 0.00087 < 0.00087 < 0.00087 < 0.00087 < 0.00087 < 0.00087 < 0.00087 < 0.00087 < 0.00087 < 0.0026 0.042 < 0.00064 0.006 < 0.00013 0.0076 0.0037 0.0015
SB-02-2021 0-1'0-1 4/26/21 < 0.00083 < 0.00083 < 0.00083 < 0.00083 < 0.00083 < 0.00083 < 0.00083 < 0.00083 < 0.00083 < 0.00083 < 0.0025 0.037 < 0.00061 0.0045 < 0.00012 < 0.00083 < 0.00083 < 0.00083
SB-03-2021 1-2'1-2 4/26/21 < 0.00091 < 0.00091 < 0.00091 < 0.00091 < 0.00091 0.003 < 0.00091 < 0.00091 < 0.00091 < 0.00091 < 0.0027 < 0.018 < 0.00066 < 0.0045 < 0.00014 < 0.00091 < 0.00091 < 0.00083
SB-04-2021 0-1'0-1 4/26/21 < 0.0011 < 0.0011 < 0.0011 < 0.0011 < 0.0011 0.00071 J < 0.0011 < 0.0011 < 0.0011 < 0.0011 < 0.0032 < 0.022 < 0.00079 < 0.0054 < 0.00016 < 0.0011 < 0.0011 < 0.00083
SB-05-2021 1-2'1-2 4/26/21 < 0.0012 < 0.0012 < 0.0012 < 0.0012 < 0.0012 0.007 < 0.0012 < 0.0012 < 0.0012 < 0.0012 < 0.0035 < 0.023 < 0.00084 < 0.0058 < 0.00017 < 0.0012 < 0.0012 < 0.00083
SB-06-2021 1-2'1-2 4/26/21 < 0.0012 < 0.0012 < 0.0012 0.00065 J < 0.0012 < 0.0012 < 0.0012 < 0.0012 < 0.0012 < 0.0012 < 0.0036 < 0.024 < 0.00086 < 0.0059 < 0.00018 < 0.0012 < 0.0012 < 0.00083
SB-07-2021 2-3'2-3 4/26/21 < 0.0010 < 0.0010 < 0.0010 < 0.0010 0.00044 J < 0.0010 < 0.0010 < 0.0010 < 0.0010 < 0.0010 < 0.0030 0.069 < 0.00074 0.0066 < 0.00015 0.04 0.0076 0.0048
SB-18 0-1'0-1 5/7/24 <0.0063 <0.0063 <0.0063 <0.0063 <0.0063 <0.0063 <0.0063 <0.0063 <0.0063 <0.0126 <0.0189 <0.126 <0.0252 <0.126 <0.0063 <0.0063 <0.0063 <0.0063
SB-18 3-4'3-4 5/7/24 <0.0061 <0.0061 <0.0061 <0.0061 0.0337 0.0266 <0.0061 <0.0061 <0.0061 <0.0122 <0.0183 <0.122 <0.0243 <0.122 <0.0061 <0.0061 <0.0061 <0.0061
SB-19 0-1'0-1 5/7/24 <0.0068 <0.0068 <0.0068 <0.0068 <0.0068 <0.0068 <0.0068 <0.0068 <0.0068 <0.0136 <0.0204 <0.136 <0.0273 <0.136 <0.0068 <0.0068 <0.0068 <0.0068
SB-19 1-2 1-2 5/7/24 <0.0071 <0.0071 <0.0071 <0.0071 <0.0071 <0.0071 <0.0071 <0.0071 <0.0071 <0.0143 <0.0214 <0.143 <0.0286 <0.143 <0.0071 <0.0071 <0.0071 <0.0071
SB-20 0-1'0-1 5/7/24 <0.0108 <0.0108 <0.0108 <0.0108 <0.0108 <0.0108 <0.0108 <0.0108 <0.0108 <0.0217 <0.0325 <0.217 <0.0433 <0.217 <0.0108 <0.0108 <0.0108 <0.0108
SB-20 4-5'4-5 5/7/24 <0.0063 <0.0063 <0.0063 <0.0063 <0.0063 <0.0063 <0.0063 <0.0063 <0.0063 <0.0126 <0.0189 <0.126 <0.0252 <0.126 <0.0063 <0.0063 <0.0063 <0.0063
SB-21 0-1 0-1 5/7/24 <0.0057 <0.0057 <0.0057 <0.0057 <0.0057 <0.0057 <0.0057 <0.0057 <0.0057 <0.0115 <0.0173 <0.115 <0.023 <0.115 <0.0057 <0.0057 <0.0057 <0.0057
SB-21 4-5'4-5 5/7/24 <0.0071 <0.0071 <0.0071 <0.0071 <0.0071 <0.0071 <0.0071 <0.0071 <0.0071 <0.0143 <0.0214 <0.143 <0.0286 <0.143 <0.0071 <0.0071 <0.0071 <0.0071
SB-22 0-1'0-1 5/7/24 <0.0071 <0.0071 <0.0071 <0.0071 <0.0071 0.0304 <0.0071 <0.0071 <0.0071 <0.0143 <0.0214 <0.143 <0.0286 <0.143 <0.0071 <0.0071 <0.0071 <0.0071
SB-22 2-4'3-4 5/7/24 <0.0067 0.285 <0.0067 <0.0067 <0.0067 3.7 <0.0067 <0.0067 0.556 0.0372 <0.0202 <0.135 <0.027 <0.135 <0.0067 <0.0067 <0.0067 <0.0067
SB-23 0-1'0-1 5/7/24 <0.0088 <0.0088 <0.0088 <0.0088 <0.0088 <0.0088 <0.0088 <0.0088 <0.0088 <0.0177 <0.0265 <0.177 <0.0353 <0.177 <0.0088 <0.0088 <0.0088 <0.0088
SB-23 3-4'3-4 5/7/24 <0.0067 <0.0067 <0.0067 <0.0067 <0.0067 <0.0067 <0.0067 <0.0067 <0.0067 <0.0133 <0.0202 <0.135 <0.027 <0.135 <0.0067 <0.0067 <0.0067 <0.0067
Bold = Compound detected
N/A = data not available
Soil data associated with Carolina Cleaners (DC680016), located at 406 W. Franklin Street:
Soil data associated with Carolina Cleaners (DC680015), located at 400 W. Franklin Street:
Soil data associated with Carolina Cleaners (DC680016), located at 406 W. Franklin Street:
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Table 3: Analytical Data for Sub-slab Gas
DSCA ID No.: DC680016
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e
n
e
s

(
t
o
t
a
l
)
SSV-8 6 0.5 h 11/27/18 NA < 0.16 NA NA NA 170 NA < 0.16 2.5 < 0.16 NA
SSV-2 6 6 0.5 h 3/17/22 NA < 0.79 NA NA NA 510 NA < 0.79 < 1.1 < 0.51 NA
SSV-3 6 6 0.5 h 3/17/22 NA < 0.79 NA NA NA 1800 NA < 0.79 1.6 < 0.51 NA
SSV-4 6 6 0.5 h 3/17/22 NA < 0.79 NA NA NA 110 NA < 0.79 < 1.1 < 0.51 NA
Bold = Compound detected
NA = not analyzed
1 Indicate "G" for grab sample or for longer samples indicate the number of hours followed by "h".
Sa
m
p
l
e

I
D
Sa
m
p
l
i
n
g

D
a
t
e

(
m
m
/
d
d
/
y
y
)
De
p
t
h
[i
n
c
h
e
s

b
g
s
]
[µg/m3]Sl
a
b

T
h
i
c
k
n
e
s
s
[i
n
c
h
e
s
]
Sa
m
p
l
i
n
g

D
u
r
a
t
i
o
n
1
Table 4: Analytical Data for Soil Gas
DSCA ID No.: DC680016
Be
n
z
e
n
e
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
y
l
e
n
e
Et
h
y
l
b
e
n
z
e
n
e
Me
t
h
y
l

t
e
r
t
-
b
u
t
y
l

e
t
h
e
r
(M
T
B
E
)
Na
p
h
t
h
a
l
e
n
e
Te
t
r
a
c
h
l
o
r
o
e
t
h
y
l
e
n
e
To
l
u
e
n
e
tr
a
n
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
y
l
e
n
e
Tr
i
c
h
l
o
r
o
e
t
h
y
l
e
n
e
Vi
n
y
l

c
h
l
o
r
i
d
e
Xy
l
e
n
e
s

(
t
o
t
a
l
)
SG-02-2021 0.5 0.5 h 4/27/21 NA <0.79 NA NA NA 3.9 NA <0.79 <1.1 <0.51 NA
SG-3 5 0.5 h 3/14/22 NA 13 NA NA NA 34000 NA 4.6 350 3 NA
SG-4 5 0.5 h 3/14/22 NA 1.6 NA NA NA 970 NA <0.79 2.4 1.5 NA
SG-5 5 0.15 h 6/20/24 NA 1.08 NA NA NA 136 NA 0.462 1.89 1.67 NA
SG-6 5 0.18 h 6/20/24 NA 3425 NA NA NA 7988 NA 1810 18187 51.1 NA
Bold = Compound detected
NA = not analyzed
Sa
m
p
l
e

D
u
r
a
t
i
o
n
1
1 Indicate "G" for grab sample or for longer samples indicate the number of hours followed by "h".
Sa
m
p
l
e

I
D
Sa
m
p
l
i
n
g

D
a
t
e

(
m
m
/
d
d
/
y
y
)
De
p
t
h
[f
e
e
t

b
g
s
]
[µg/m3]
Table 5: Analytical Data for Indoor and Outdoor Air
DSCA ID No.: DC680016
Be
n
z
e
n
e
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
y
l
e
n
e
Et
h
y
l
b
e
n
z
e
n
e
Me
t
h
y
l

t
e
r
t
-
b
u
t
y
l

e
t
h
e
r
(M
T
B
E
)
Na
p
h
t
h
a
l
e
n
e
Te
t
r
a
c
h
l
o
r
o
e
t
h
y
l
e
n
e
To
l
u
e
n
e
tr
a
n
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
y
l
e
n
e
Tr
i
c
h
l
o
r
o
e
t
h
y
l
e
n
e
Vi
n
y
l

c
h
l
o
r
i
d
e
Xy
l
e
n
e
s

(
t
o
t
a
l
)
IA-
DBSutton 11/27/18 F SU 8 h NA <
0.057 NA NA NA 0.65 NA <
0.056
<
0.076
<
0.057 NA
FC-1 07/03/19 F FC G NA 0.882 NA NA NA 272 NA < 0.32 11.6 < 0.32 NA
FC-2 07/03/19 F FC G NA < 0.16 NA NA NA 1.71 NA < 0.16 < 0.22 < 0.16 NA
Bold = Compound detected
NA = not analyzed
Notes:
2 Indicate "SU" for summa canister, "FC" for flux chambers, "T" for tedlar bags, "P" for passive samplers, "O" for other.
3 Indicate "8h" for 8-hour, "24h" for 24-hour, "G" for grab sample, for other hours indicate the number of hours followed by "h" or "d" for days.
1 Indicate "F" for former or current dry-cleaning facility, "AD" for adjacent space, "R" for residence, "C" for commercial not adjacent space. If sample
was taken outdoors, leave blank.
Sa
m
p
l
e

L
o
c
a
t
i
o
n
1
Sa
m
p
l
i
n
g

D
u
r
a
t
i
o
n
3
Sa
m
p
l
i
n
g

M
e
t
h
o
d
2
Sa
m
p
l
e

I
D
Sa
m
p
l
i
n
g

D
a
t
e

(
m
m
/
d
d
/
y
y
)
[µg/m3]
Table 5(2): Additional Data for Indoor and Outdoor Air
DSCA ID No.: DC680016
Attachment:
Sampling location map that indicates where all indoor air samples were collected. The map should clearly indicate the names/types of businesses and residence names sampled and in the vicinity of the
subject site that may be of concern.
Is dry-cleaning facility at the site: Operating Pick-up Only Abandoned
If facility is operating, solvents used are: Perc Petroleum Green Earth Other
For the active or former dry-cleaning space, describe the type and location of the air handling/HVAC unit (for example - a shared unit supplying two adjacent spaces; unit located on the roof):
The former dry-cleaning facility has a single unit located on the roof.
For any other indoor spaces tested, describe the type and location of the air handling/HVAC unit (for example - a shared unit supplying two adjacent spaces; unit located on the roof):
For any indoor air spaces tested, describe the current use of the space (for example - an ABC liquor store adjacent to the dry-cleaner, a residence approximately 200 feet from the dry-cleaner, etc.):
The former dry-cleaner currently houses DB Sutton Co. Salon and Wine Store.
Table 5(3): Additional Data for Indoor and Outdoor Air
DSCA ID No.: DC680016
Sample ID Name and Address for Sampling Location Property Owner Name, Address, and Phone Number Tenant Name, Address, and Phones Number
IA-DBSutton,
FC-1, FC-2
DB Sutton & Co.
406 W. Franklin Street
Chapel Hill, NC 27516
Piccolo Ramo LLC (c/o David Sutton)
402 W. Franklin Street
Chapel Hill, NC 27514
DB Sutton & Co.
406 W. Franklin Street
Chapel Hill, NC 27516
Table 10: Water Well(s) Survey Data
DSCA ID No.: DC680016
Ref. No./
Well ID
Sampling
Location Name
and Address
Property Owner
Name, Address, and
Phone Number
Tenant Name,
Address, and Phone
Number
Distance
from
Source
Well
Depth
[feet]
Screen
Interval
[feet]
Use of Well Source of Well
Identification
Direction
(downgradient,
upgradient, etc.,
Status
(Active/
Inactive)
1 414 E. Main Street
Carrboro, NC 27510
414 E. Main Street
Carrboro, NC 27510
414 E. Main Street
Carrboro, NC 27510 1,500 Unknown Unknown Unknown Receptor Survey *Upgradient Unknown
2 400 Ransom Street
Chapel Hill, NC 27516
Robert Kelly and Jane
Sommers-Kelly
Chapel Hill, NC 27516
Unknown 2,250 Unknown Unknown Unknown Receptor Survey *Crossgradient Unknown
* Properties outside of the mailing radius of the 2023 Public Outreach Mailings, documented on October 11, 2023
Page 1 of 1
FIGURES
Carolina Cleaners
406 W. Franklin St.
(DC680016)
Carolina Cleaners
400 W. Franklin St.
(DC680015)
Chapel Hill Cleaners
422 W. Franklin St.
(DC680010)
One Hour Koretizing
301 W. Franklin St.
(DC680006)
APPROX. SCALE, ft.
0
SHEET:
DR
A
W
N

B
Y
:
CH
E
C
K
E
D

B
Y
:
PR
O
J
E
C
T

N
O
.
:
60
SD
H

-

1
2
/
1
4
/
2
0
1
8
CE
S

-

1
2
/
1
7
/
2
0
1
8
60
5
8
9
7
6
9
AE
C
O
M

T
E
C
H
N
I
C
A
L

S
E
R
V
I
C
E
S

O
F
N
O
R
T
H

C
A
R
O
L
I
N
A
59
2
5

C
A
R
N
E
G
I
E

B
L
V
D
,

S
U
I
T
E

3
0
0
TE
L
:

(
7
0
4
)

5
5
3
-
6
1
5
0
FA
X
:

(
7
0
4
)

5
5
3
-
6
1
5
1
CH
A
R
L
O
T
T
E
,

N
C

2
8
2
1
0
Su
r
r
o
u
n
d
i
n
g

D
S
C
A

S
i
t
e

L
o
c
a
t
i
o
n
s

M
a
p
Ca
r
o
l
i
n
a

C
l
e
a
n
e
r
s
40
6

W
.

F
r
a
n
k
l
i
n

S
t
r
e
e
t
Ch
a
p
e
l

H
i
l
l
,

N
C
DS
C
A

S
i
t
e

D
C
6
8
0
0
1
6
Figure 1
APPROX. SCALE, ft.
0
SHEET:
60
Soil Boring Location
LEGEND
milligrams per kilogrammg/kg
Estimate ValueJ
PCE - Tetrachloroethene
TCE - Trichloroethene
cis-1,2-DCE - cis-1,2-Dichloroethene
VC - Vinyl Chloride
MTBE - Methyl-tert-Butyl Ether
Suspected Soil Source Area
(PCE > 10 mg/kg)
Inferred Area of PCE Soil Impacts >
the Preliminary Soil Remediation
Goal (PSRG) 0-2 feet bgs
Unknown Underground Interference,
Possible Historic Utility
Figure 2a
SB-18 (0-1’) (5/7/24)
BDL
SB-19 (0-1’) (5/7/24)
BDL
SB-19 (1-2’)
BDL
SB-20 (0-1’) (5/7/24)
BDL
SB-21 (0-1’) (5/7/24)
BDL
SB-22 (0-1’) (5/7/24)
PCE - 0.0304 mg/kg
SB-23 (0-1’) (5/7/24)
BDL
APPROX. SCALE, ft.
0
SHEET:
60
Figure 2b
SB-18 (3-4’)
PCE - 0.0266 mg/kg
Naphthalene - 0.0337 mg/kg
SB-20 (4-5’)
BDLSB-21 (4-5’)
BDL
SB-22 (3-4’)
PCE - 3.7 mg/kg
TCE - 0.556 mg/kg
cis-1,2-DCE - 0.285 mg/kg
VC - 0.0372 mg/kg
SB-23 (3-4’)
BDL
SB-3 6’ (8/19/12)
Soil Boring Location
LEGEND
milligrams per kilogrammg/kg
Estimate ValueJ
PCE - Tetrachloroethene
TCE - Trichloroethene
cis-1,2-DCE - cis-1,2-Dichloroethene
VC - Vinyl Chloride
MTBE - Methyl-tert-Butyl Ether
Suspected Soil Source Area
(PCE > 10 mg/kg)
Inferred Area of PCE Soil Impacts >
the Preliminary Soil Remediation
Goal (PSRG) >2 feet bgs
Unknown Underground Interference,
Possible Historic Utility
APPROX. SCALE, ft.
0
SHEET:
60
Figure 3
SG-5 (6/20/24)
PCE - 136 µg/m3
TCE - 1.89 µg/m3
cis-1,2-DCE - 1.08 µg/m3
trans-1,2-DCE - 0.462 µg/m3
VC - 1.67 µg/m3
SG-6 (6/20/24)
PCE - 7,988 µg/m3
TCE - 18,187 µg/m3
cis-1,2-DCE - 3,425 µg/m3
trans-1,2-DCE - 1,810 µg/m3
VC - 51.1 µg/m3
Indoor/Ambient Air Sample
LEGEND
Subslab Vapor Sample
micrograms per cubic meterµg/m3
BDL Below Detection Limit
PCE - Tetrachloroethene
TCE - Trichloroethene
cis-1,2-DCE - cis-1,2-Dichloroethene
trans-1,2-DCE - trans-1,2-Dichloroethene
Soil Gas Sample Location
Inferred Area of Soil Gas Impacts
Which Exceed Acceptable Calculated
Vapor Intrusion Risk for Non-
Residential Use
Analytical results do not exceed calculated
vapor intrusion risk for residential or
non-residential exposure – DSCA Indoor
Air Risk Calculator
Analytical results do not exceed calculated
vapor intrusion risk for non-residential
exposure but do exceed for residential
exposure – DSCA Indoor Air Risk
Calculator
Analytical results exceed calculated vapor
intrusion risk for residential and non-resi-
dential exposure – DSCA Indoor Air Risk
Calculator
Unknown Underground Interference,
Possible Historic Utility
APPENDIX A
STANDARD OPERATING PROCEDURES

Soil Gas Sampling (Rev2)Revision November 2023
PRINTED COPIES ARE UNCONTROLLED. CONTROLLED COPY IS AVAILABLE ON COMPANY INTRANET.1/4
AECOM – North Carolina Standard Operating Procedures
Soil Gas Sampling
1.Purpose and Scope
Standard operating procedure for the collection of soil gas samples using laboratory provided Summa canisters.
2.Procedure
2.1 Required Equipment:
Project Health and Safety Plan (HASP)
Work Plan
Summa Canister with a Flow Regulator from a certified laboratory (pre-calibrated for a 200 ml/min flow rate,
Image-2, A1)
Field forms – Summa Canister Field Sampling Data Sheet
¼” Stainless steel nuts and ferrules
Stainless-steel hand auger
Stainless-steel SGV 6 IN. Screened Implant with Stepped Fitting (AMS Vapor Implants Sampling Method,
Image-1 and Image-2, B1)1/4" OD x 1/8" ID Teflon tubingHammer drill (If soil gas installation is being conducted in a location were concrete/asphalt is present)
Hammer drill bit, diameter size based on size of stainless-steel hand auger
Extension cord
Portable generator (If power is not available and hammer drill is required for installation)
#2 driller sand
Hydraulic cement and/or bentonite
Water
Decontamination equipment
Ziplock bags
Helium detector
Helium
Helium chamber
50mL Syringe with Luer-Lock tip Tedlar bags (Image-2, C1)
Safety Cones
Laminated Sign to notify Air Sampling in progress
Chain of Custody (COC)
FedEx forms Standard wrench setDigital camera3-Way Stopcock Valve (Image-2, D1)Two 1/4 in. O.D. Polypropylene Push-to-Connect Valve (Image-2, E1 & E2)
1/4 in. Push-To-Connect Polypropylene Tee Fitting (Image-2, F1)Shut-in Leak Check Assembly: Image-2, In-line vacuum pressure gauge (G1) and Brass two-way valve (G2).
2.2 Vapor Implant Sampling Method
1.Prior to mobilizing to the field, ensure summa canisters had adequate vacuum for sampling. Additionally, ensure
all summa canister components have been provided by the lab that are necessary to complete the sampling. If
there is any issues with a summa canister, contact the lab immediately for replacement.
2.Prior to intrusive activities, locate any underground utilities to ensure the safety of subsurface work conditions.

AECOM
Soil Gas Sampling (Rev2)Revision November 2023
PRINTED COPIES ARE UNCONTROLLED. CONTROLLED COPY IS AVAILABLE ON COMPANY INTRANET.2/4
3.Use a clean, stainless steel hand auger to auger down to a minimum of 6 feet beneath the ground surface (ft
Bgs). If a minimum depth of 6 ft Bgs cannot be reached, notify the AECOM project manager for the site before
collecting a sample.
Note: Vapor implant should not be placed in saturated soils. Additionally, Soil gas sampling should not occur
during a significant rain event (e.g., 1/2 inch or greater of rainfall during a 24-hour period). A minimum of 5 days
after a significant rain event or 5 days after watering has stopped in areas that are irrigated to complete soil gas
sampling. This does not apply to areas where infiltration has not occurred, such as under buildings or high-
integrity pavement.
4.Attach Teflon tubing to the barbed tang of a 6” AMS Vapor Implant (AMS Item #21010). Make sure that the
connection between the barbed end of the implant and the Teflon tubing is secure.
*Stainless Steel SGV 6 IN. Screened Implant with Stepped Fitting (Image-1)
5.Lower the AMS Vapor Implant and attached tubing into the borehole until the Implant reaches the desired depth.
The top of the vapor implant should be a minimum of five feet below ground surface.
6.Cut the tubing to the desired length so that you have approximately 2’ of extra tubing to attach to the summa
canister.
7.Using #2A filter sand, add enough sand to cover the 6” Implant and 2-3” above the Implant. Check the depth of
sand using a measuring tape. The top of the sand should be a minimum of five feet below ground surface.
8.Add hydraulic cement or bentonite above the top of the sand to the surface to create a seal. If using cement,
place a thin layer of 1-2 inches of dry bentonite above the sand pack to prevent the cement from intruding into
the sand pack before it hardens. If using bentonite, hydrate the bentonite to ensure a proper seal. Wait 2 hours
or until the hydraulic cement has fully hardened, whichever is longer.
9.Use a syringe to purge the subsurface air through the Teflon tubing. Purge a maximum of three pore volume of
the borehole. The pore volume should be a minimum of the volume of the tubing and sand filter pack.
Calculate pore volume using formula: v = π ra2La + π rt2Lt where:
v =Volume
La =Length of sand-filled annular space, and
ra =Radius of annular space
Lt =Length of tubing, and
rt =Radius of tubing
10.Thread the tubing through the helium leak test device (helium chamber).
11.Connect the Teflon tubing from the soil gas point to a 2-way valve (Image-2, E1) and use Teflon tubing to
connect the 2-way valve (Image-2, E1) to the tee fitting (Image-2, F1).
12.Connect Teflon tubing to the stainless-steel summa canister (Image-2, A1) using air-tight stainless-steel fittings
and then connect the Teflon tubing to tee fitting (Image-2, F1).

AECOM
Soil Gas Sampling (Rev2)Revision November 2023
PRINTED COPIES ARE UNCONTROLLED. CONTROLLED COPY IS AVAILABLE ON COMPANY INTRANET.3/4
13.Connect Teflon tubing to the last open connection on the tee fitting (Image-2, F1) then connect the Teflon tubing
to a 2-way valve (Image-2, E2).
14.Connect the 2-way valve (Image-2, E2) to the in line Shut-in Leak Check Assembly (Image-2: G1 and G2).
15.Connect the in line Shut-in Leak Check Assembly (Image-2: G1 and G2) to the 3-way stopcock valve (Image-2,
D1). One connection will be used to apply a vacuum using a syringe (Image-2, C1) and one connection will be
connected to a Tedlar bag.
16.Conduct the leak test and shut-in test as outlined in Section 3.
17.After the completion of the leak test and shut-in test, utilize the laboratory supplied flow controller to pull the
sample over the desired time interval. The extraction rate of the summa canister should not exceed 200 ml/min.
18.To remove the stainless-steel Implant, break up the hydraulic seal. Tug gently on the Teflon tubing until the
Implant is freed.
19.Remove the Teflon tubing from the barb and dispose of the tubing and the disposable stainless-steel Implant.
20.Backfill borehole with hydraulic cement.
3.Leak Test and Shut-In Test Procedure
1.Close the 2-way valve closest to the soil gas point (Image-2, E1).
2.Use a syringe (Image-2, C1) to extract a negative pressure of approximately 10-inches of mercury (inHg) to the
sample train.
* Shut-In Test Procedure (Image-2)

AECOM
Soil Gas Sampling (Rev2)Revision November 2023
PRINTED COPIES ARE UNCONTROLLED. CONTROLLED COPY IS AVAILABLE ON COMPANY INTRANET.4/4
3.Close the 2-way brass valve (Image-2, G2) between the vacuum pressure gauge (Image-2, G1) and the vacuum
pump or syringe (Image-2, C1).
4.Record the initial negative pressure displayed on the vacuum pressure gauge (Image-2, G1).
5.Monitor the vacuum pressure gauge (Image-2, G1) for 5 minutes. Ensure that the negative pressure does not
decrease by more than 1-inHg.
6.Record the negative pressure reading on the summa cannister field data sheet. If the reading has dropped less
than 1-inHg, proceed to the next step. If the negative pressure reading has dropped more than 1-inHg,
reconstruct the sample train as necessary and repeat the test.
7.Close the 2-way valve (Image-2, E2) between the vacuum pressure gauge (Image-2, G1) and the tee fitting
(Image-2, F1).
8.Open the 2-way valve (Image-2, E1) between the tee fitting (Image-2, F1) and the soil gas point.
9.Monitor the vacuum presusure gauge for 5 minutes. Ensure that the negative pressure does not decrease by
more than 1-inHg.
10.Record the negative pressure reading. If the reading has dropped by less than 1-inHg, proceed to the next step.
If the negative pressure reading has dropped by more than 1-inHg, reconstruct the sample train as necessary
and repeat the test.
11.Open all 2-way valves (Image-2, E2 and G2) between the syringe (Image-2, C1) and the tee fitting (Image-2,
G1).
12.Attach the helium detector to the helium chamber. Attach the helium container to the helium chamber using
teflon tubing and fill the helium chamber with helium until the helium detector reads >50%.
13.Use the syringe to fill a 1 Liter Tedlar bag with air from the sample port. This can be done by filling the syringe
with the 3-way stopcock valve (Image-2, D1) to the Tedlar bag closed and the connection to the soil gas point
open and emptying the syringe with the 3-way stopcock valve (Image-2, D1) to the Tedlar bag open and the
connection to the soil gas point closed.
14.Close the Tedlar bag and detach it from the pump.
15.Turn off the flow of helium into the helium leak test device.
16.Remove the helium detector from the leak test device and allow the helium detector reading to reach 0 ppm.
17.Insert the helium detector into the silicon tubing attached to the Tedlar bag and open valve on the bag.
18.Record the reading. If the reading is below 10% of the value measured within the test device, proceed to the
next step. If the reading is above 10%, repeat the leak test and reconstruct the sample point as necessary.
19.Be sure that the valve to the Tedlar bag is open and that nothing is blocking the flow to the helium detector. The
detector may produce false readings if the detector pump is strained or if methane is present in the soil gas.
4.Records
a.Summa Canister Field Data Sheet
b.Equipment Calibration Sheets
5.Attachments
a.Summa Canister Field Data Sheet
Site:
Samplers:
Date:
Sample#
Location
Summa Canister ID
Flow Controller ID
NO/NO/NO/NO/NO/
Additional Tubing Added YES - How much YES - How much YES - How much YES - How much YES - How much
Purge Time (Start)
Purge Time (Stop)
Total Purge Time (min)
Purge Volume
Tracer Gas Results (He)
Shut-In Test Reading (inHg)
Pressure Gauge - before
sampling
Sample Time (Start)
Sample Time (Stop)
Total Sample Time (min)
Pressure Gauge - after
sampling
Sample Volume
Canister Pressure Went to
Ambient Pressure?YES / NO YES / NO YES / NO YES / NO YES / NO
Summa Canister Sampling Field Data Sheet
General Comments:

Soil Sampling Using Direct Push Technology ()
Revision 1 June 7, 2017
PRINTED COPIES ARE UNCONTROLLED. CONTROLLED COPY IS AVAILABLE ON COMPANY INTRANET. 1/2

AECOM – North Carolina Standard Operating Procedures
Soil Sampling Using a Hand Auger

1. Purpose and Scope
Standard operating procedure for the collection of soil samples using a stainless steel hand auger.
2. Procedure
2.1 Required Equipment
 Stainless Steel Hand Auger with extensions
 Gloves (Leather, Latex and/or Nitrile)
 Sample Containers
 Field Logbook
 Sample Labels
 Chain-of-Custody
 Cooler with Ice
 GPS Unit
 Tape Measure
 Bentonite Chips/Portland Cement
 Organic Vapor Analyzer
2.2 Procedure
1. Verify sample collection location, sample identification, and required analyses.
2. Record GPS coordinates as applicable.
3. Assemble clean hand auger and inspect for damage.
4. Don new, uncontaminated gloves.
5. Advance the hand auger into the soil by turning the auger clockwise until the auger bucket is full.
6. Remove the soil from the auger bucket. Use a tape measure to periodically gauge depth of soil boring.
7. Retrieve a sample at interval specified in the scope of work, for screening with an organic vapor analysis
(OVA) meter, such as a photo ionization detector (PID).
8. Samples collected from each boring will be submitted to laboratory for analysis based on the parameters
and goals specific to each work plan.
9. Repeat steps 4 to 7 until the boring termination conditions are met.
10. Backfill soil borings terminated above the water table with native cuttings or bentonite chips. Backfill soil
borings that breach the water table using bentonite.
11. Complete all required documentation, including field logbook entries, soil description, sample container
label, and chain-of-custody form.
12. GPS, flag, stake, or otherwise mark the sample collection locations as necessary.

AECOM
Soil Sampling Using Direct Push Technology ()
Revision 1 June 7, 2017
PRINTED COPIES ARE UNCONTROLLED. CONTROLLED COPY IS AVAILABLE ON COMPANY INTRANET. 2/2

3. Records
a. Field Notes
b. Equipment Calibration
APPENDIX B
PHOTOGRAPHIC LOG
DSCA Site DC680016
Carolina Cleaners
Date of Photograph:
5/7/2024
Direction:
South
Description:
General site condition after rain
and during construction
Photolog, Photo No. 1
DSCA Site DC680016
Carolina Cleaners
Date of Photograph:
5/7/2024
Direction:
Northwest
Description:
General site condition after rain
and during construction
Photolog, Photo No. 2
DSCA Site DC680016
Carolina Cleaners
Date of Photograph:
5/7/2024
Direction:
West
Description:
Conditions inside former
Mediterranean Deli restaurant,
currently under reconstruction
Photolog, Photo No. 3
DSCA Site DC680016
Carolina Cleaners
Date of Photograph:
5/7/2024
Direction:
East
Description:
Pink line indicates unknown
underground pipe
Photolog, Photo No. 4
DSCA Site DC680016
Carolina Cleaners
Date of Photograph:
5/7/2024
Direction:
Southeast
Description:
SB-18 location and area flooding
Photolog, Photo No. 5
DSCA Site DC680016
Carolina Cleaners
Date of Photograph:
5/7/2024
Direction:
East
Description:
Locations of SB-19 and SB-20
along eastern wall
Photolog, Photo No. 6
DSCA Site DC680016
Carolina Cleaners
Date of Photograph:
5/7/2024
Direction:
Southeast
Description:
SB-19 and area flooding
Photolog, Photo No. 7
DSCA Site DC680016
Carolina Cleaners
Date of Photograph:
5/7/2024
Direction:
Southeast
Description:
SB-20 and close-up view of
flooding in hole
Photolog, Photo No. 8
DSCA Site DC680016
Carolina Cleaners
Date of Photograph:
5/7/2024
Direction:
East
Description:
SB-21
Photolog, Photo No. 9
DSCA Site DC680016
Carolina Cleaners
Date of Photograph:
5/7/2024
Direction:
Northwest
Description:
SB-22 and SB-23 locations
Photolog, Photo No.
10
DSCA Site DC680016
Carolina Cleaners
Date of Photograph:
5/7/2024
Direction:
Southwest
Description:
SB-22 and SB-23
Photolog, Photo No.
11
APPENDIX C
DSCA VAPOR INTRUSION RISK CALCULATORS
DSCA ID No:
Name/Address of DSCA Site:Carolina Cleaners
Name/Address of Sampling Location:Carolina Cleaners/406 W Franklin St, Chapel Hill, NC
Sampling Date:6/20/2024
Sample ID:SG-5
All concentrations are in ug/m3
CAS #Chemical Name:
Soil Gas
Concentration
(ug/m3)
Calculated Indoor
Air
Concentration
(ug/m3)
Indoor Air
Screening Level
for Carcinogens
@ TCR = 1E-06
Indoor Air
Screening
Level for Non-
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic Risk
Calculated Non-
Carcinogenic
Hazard
Quotient
156-59-2 Dichloroethylene, cis-1,2-1.08 0.0324 -8.3E+00 7.8E-04
156-60-5 Dichloroethylene, trans-1,2-0.462 0.01386 -8.3E+00 3.3E-04
127-18-4 Tetrachloroethylene 136 4.08 1.1E+01 8.3E+00 3.8E-07 9.8E-02
79-01-6 Trichloroethylene 1.89 0.0567 4.8E-01 4.2E-01 1.2E-07 2.7E-02
75-01-4 Vinyl Chloride 1.67 0.0501 1.7E-01 1.7E+01 3.0E-07 6.0E-04
Cumulative:8.0E-07 1.3E-01
DSCA Soil Gas Risk Calculator - Cumulative Risk for Resident
Version 11, July 2023
DC680016
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk
values are calculated for these chemicals.
DSCA ID No:
Name/Address of DSCA Site:Carolina Cleaners
Name/Address of Sampling Location:Carolina Cleaners/406 W Franklin St, Chapel Hill, NC
Sampling Date:6/20/2024
Sample ID:SG-5
All concentrations are in ug/m3
CAS #Chemical Name:
Soil Gas
Concentration
(ug/m3)
Calculated Indoor
Air Concentration
(ug/m3)
Indoor Air
Screening Level
for Carcinogens
@ TCR = 1E-06
Indoor Air
Screening Level
for Non-
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic Risk
Calculated Non-
Carcinogenic
Hazard Quotient
156-59-2 1.08 0.0108 -3.5E+01 6.2E-05
156-60-5 0.462 0.00462 -3.5E+01 2.6E-05
127-18-4 136 1.36 4.7E+01 3.5E+01 2.9E-08 7.8E-03
79-01-6 1.89 0.0189 3.0E+00 1.8E+00 6.3E-09 2.2E-03
75-01-4 1.67 0.0167 2.8E+00 7.0E+01 6.0E-09 4.8E-05
Cumulative:4.1E-08 1.0E-02
DSCA Soil Gas Risk Calculator - Cumulative Risk for Non-Residential Worker
Version 11, July 2023
DC680016
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk
values are calculated for these chemicals.
DSCA ID No:
Name/Address of DSCA Site:Carolina Cleaners
Name/Address of Sampling Location:Carolina Cleaners/406 W Franklin St, Chapel Hill, NC
Sampling Date:6/20/2024
Sample ID:SG-6
All concentrations are in ug/m3
CAS #Chemical Name:
Soil Gas
Concentration
(ug/m3)
Calculated Indoor
Air Concentration
(ug/m3)
Indoor Air
Screening Level
for Carcinogens
@ TCR = 1E-06
Indoor Air
Screening Level
for Non-
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic Risk
Calculated Non-
Carcinogenic
Hazard Quotient
156-59-2 3425 102.75 -8.3E+00 2.5E+00
156-60-5 1810 54.3 -8.3E+00 1.3E+00
127-18-4 7988 239.64 1.1E+01 8.3E+00 2.2E-05 5.7E+00
79-01-6 18187 545.61 4.8E-01 4.2E-01 1.1E-03 2.6E+02
75-01-4 51.1 1.533 1.7E-01 1.7E+01 9.1E-06 1.8E-02
Cumulative:1.2E-03 2.7E+02
DSCA Soil Gas Risk Calculator - Cumulative Risk for Resident
Version 11, July 2023
DC680016
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk
values are calculated for these chemicals.
DSCA ID No:
Name/Address of DSCA Site:Carolina Cleaners
Name/Address of Sampling Location:Carolina Cleaners/406 W Franklin St, Chapel Hill, NC
Sampling Date:6/20/2024
Sample ID:SG-6
All concentrations are in ug/m3
CAS #Chemical Name:
Soil Gas
Concentration
(ug/m3)
Calculated Indoor
Air Concentration
(ug/m3)
Indoor Air
Screening Level
for Carcinogens
@ TCR = 1E-06
Indoor Air
Screening Level
for Non-
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic Risk
Calculated Non-
Carcinogenic
Hazard Quotient
156-59-2 3425 34.25 -3.5E+01 2.0E-01
156-60-5 1810 18.1 -3.5E+01 1.0E-01
127-18-4 7988 79.88 4.7E+01 3.5E+01 1.7E-06 4.6E-01
79-01-6 18187 181.87 3.0E+00 1.8E+00 6.1E-05 2.1E+01
75-01-4 51.1 0.511 2.8E+00 7.0E+01 1.8E-07 1.5E-03
Cumulative:6.3E-05 2.2E+01
DSCA Soil Gas Risk Calculator - Cumulative Risk for Non-Residential Worker
Version 11, July 2023
DC680016
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk
values are calculated for these chemicals.
APPENDIX D
LABORATORY REPORTS
#=CL#
May 14, 2024
LIMS USE: FR - STEPHANIE HEMPEL
LIMS OBJECT ID: 92730039
92730039
Project:
Pace Project No.:
RE:
Stephanie Hempel
AECOM
5438 Wade Park Boulevard,
Suite 200
Raleigh, NC 27607
Carolina Cleaners DC680016
Dear Stephanie Hempel:
Enclosed are the analytical results for sample(s) received by the laboratory on May 08, 2024. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Nicole D'Oleo
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 42
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 42
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92730039001 SB-18 (0-1)EPA 8260D 70 PASI-CSAS
SW-846 1 PASI-CCHC
92730039002 SB-18 (3-4)EPA 8260D 70 PASI-CSAS
SW-846 1 PASI-CCHC
92730039003 SB-19 (0-1)EPA 8260D 70 PASI-CSAS
SW-846 1 PASI-CCHC
92730039004 SB-19 (1-2)EPA 8260D 70 PASI-CSAS
SW-846 1 PASI-CCHC
92730039005 SB-20 (0-1)EPA 8260D 70 PASI-CSAS
SW-846 1 PASI-CCHC
92730039006 SB-20 (4-5)EPA 8260D 70 PASI-CSAS
SW-846 1 PASI-CCHC
92730039007 SB-21 (0-1)EPA 8260D 70 PASI-CSAS
SW-846 1 PASI-CCHC
92730039008 SB-21 (4-5)EPA 8260D 70 PASI-CSAS
SW-846 1 PASI-CCHC
92730039009 SB-22 (0-1)EPA 8260D 70 PASI-CSAS
SW-846 1 PASI-CCHC
92730039010 SB-22 (3-4)EPA 8260D 70 PASI-CSAS
SW-846 1 PASI-CCHC
92730039011 SB-23 (0-1)EPA 8260D 70 PASI-CSAS
SW-846 1 PASI-CCHC
92730039012 SB-23 (3-4)EPA 8260D 70 PASI-CSAS
SW-846 1 PASI-CCHC
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Sample:SB-18 (0-1)Lab ID:92730039001 Collected:05/07/24 12:45 Received:05/08/24 10:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone ND ug/kg 05/10/24 02:58 67-64-105/09/24 21:371261
Benzene ND ug/kg 05/10/24 02:58 71-43-205/09/24 21:376.3 1
Bromobenzene ND ug/kg 05/10/24 02:58 108-86-105/09/24 21:376.3 1
Bromochloromethane ND ug/kg 05/10/24 02:58 74-97-505/09/24 21:376.3 1
Bromodichloromethane ND ug/kg 05/10/24 02:58 75-27-405/09/24 21:376.3 1
Bromoform ND ug/kg 05/10/24 02:58 75-25-205/09/24 21:376.3 1
Bromomethane ND ug/kg 05/10/24 02:58 74-83-905/09/24 21:3725.2 1
2-Butanone (MEK)ND ug/kg 05/10/24 02:58 78-93-305/09/24 21:371261
n-Butylbenzene ND ug/kg 05/10/24 02:58 104-51-805/09/24 21:376.3 1
sec-Butylbenzene ND ug/kg 05/10/24 02:58 135-98-805/09/24 21:376.3 1
tert-Butylbenzene ND ug/kg 05/10/24 02:58 98-06-605/09/24 21:376.3 1
Carbon tetrachloride ND ug/kg 05/10/24 02:58 56-23-505/09/24 21:376.3 1
Chlorobenzene ND ug/kg 05/10/24 02:58 108-90-705/09/24 21:376.3 1
Chloroethane ND ug/kg 05/10/24 02:58 75-00-305/09/24 21:3712.6 1
Chloroform ND ug/kg 05/10/24 02:58 67-66-305/09/24 21:376.3 1
Chloromethane ND ug/kg 05/10/24 02:58 74-87-305/09/24 21:3712.6 1
2-Chlorotoluene ND ug/kg 05/10/24 02:58 95-49-805/09/24 21:376.3 1
4-Chlorotoluene ND ug/kg 05/10/24 02:58 106-43-405/09/24 21:376.3 1
1,2-Dibromo-3-chloropropane ND ug/kg 05/10/24 02:58 96-12-805/09/24 21:376.3 1
Dibromochloromethane ND ug/kg 05/10/24 02:58 124-48-105/09/24 21:376.3 1
1,2-Dibromoethane (EDB)ND ug/kg 05/10/24 02:58 106-93-405/09/24 21:376.3 1
Dibromomethane ND ug/kg 05/10/24 02:58 74-95-305/09/24 21:376.3 1
1,2-Dichlorobenzene ND ug/kg 05/10/24 02:58 95-50-105/09/24 21:376.3 1
1,3-Dichlorobenzene ND ug/kg 05/10/24 02:58 541-73-105/09/24 21:376.3 1
1,4-Dichlorobenzene ND ug/kg 05/10/24 02:58 106-46-705/09/24 21:376.3 1
Dichlorodifluoromethane ND ug/kg 05/10/24 02:58 75-71-8 IH05/09/24 21:3712.6 1
1,1-Dichloroethane ND ug/kg 05/10/24 02:58 75-34-305/09/24 21:376.3 1
1,2-Dichloroethane ND ug/kg 05/10/24 02:58 107-06-205/09/24 21:376.3 1
1,1-Dichloroethene ND ug/kg 05/10/24 02:58 75-35-405/09/24 21:376.3 1
cis-1,2-Dichloroethene ND ug/kg 05/10/24 02:58 156-59-205/09/24 21:376.3 1
trans-1,2-Dichloroethene ND ug/kg 05/10/24 02:58 156-60-505/09/24 21:376.3 1
1,2-Dichloropropane ND ug/kg 05/10/24 02:58 78-87-505/09/24 21:376.3 1
1,3-Dichloropropane ND ug/kg 05/10/24 02:58 142-28-905/09/24 21:376.3 1
2,2-Dichloropropane ND ug/kg 05/10/24 02:58 594-20-705/09/24 21:376.3 1
1,1-Dichloropropene ND ug/kg 05/10/24 02:58 563-58-605/09/24 21:376.3 1
cis-1,3-Dichloropropene ND ug/kg 05/10/24 02:58 10061-01-505/09/24 21:376.3 1
trans-1,3-Dichloropropene ND ug/kg 05/10/24 02:58 10061-02-605/09/24 21:376.3 1
Diisopropyl ether ND ug/kg 05/10/24 02:58 108-20-305/09/24 21:376.3 1
Ethylbenzene ND ug/kg 05/10/24 02:58 100-41-405/09/24 21:376.3 1
Hexachloro-1,3-butadiene ND ug/kg 05/10/24 02:58 87-68-305/09/24 21:3712.6 1
2-Hexanone ND ug/kg 05/10/24 02:58 591-78-605/09/24 21:3763.1 1
Isopropylbenzene (Cumene)ND ug/kg 05/10/24 02:58 98-82-805/09/24 21:376.3 1
p-Isopropyltoluene ND ug/kg 05/10/24 02:58 99-87-605/09/24 21:376.3 1
Methylene Chloride ND ug/kg 05/10/24 02:58 75-09-205/09/24 21:3725.2 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 05/10/24 02:58 108-10-105/09/24 21:3763.1 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Sample:SB-18 (0-1)Lab ID:92730039001 Collected:05/07/24 12:45 Received:05/08/24 10:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Methyl-tert-butyl ether ND ug/kg 05/10/24 02:58 1634-04-405/09/24 21:376.3 1
Naphthalene ND ug/kg 05/10/24 02:58 91-20-305/09/24 21:376.3 1
n-Propylbenzene ND ug/kg 05/10/24 02:58 103-65-105/09/24 21:376.3 1
Styrene ND ug/kg 05/10/24 02:58 100-42-505/09/24 21:376.3 1
1,1,1,2-Tetrachloroethane ND ug/kg 05/10/24 02:58 630-20-605/09/24 21:376.3 1
1,1,2,2-Tetrachloroethane ND ug/kg 05/10/24 02:58 79-34-505/09/24 21:376.3 1
Tetrachloroethene ND ug/kg 05/10/24 02:58 127-18-405/09/24 21:376.3 1
Toluene ND ug/kg 05/10/24 02:58 108-88-305/09/24 21:376.3 1
1,2,3-Trichlorobenzene ND ug/kg 05/10/24 02:58 87-61-605/09/24 21:376.3 1
1,2,4-Trichlorobenzene ND ug/kg 05/10/24 02:58 120-82-105/09/24 21:376.3 1
1,1,1-Trichloroethane ND ug/kg 05/10/24 02:58 71-55-605/09/24 21:376.3 1
1,1,2-Trichloroethane ND ug/kg 05/10/24 02:58 79-00-505/09/24 21:376.3 1
Trichloroethene ND ug/kg 05/10/24 02:58 79-01-605/09/24 21:376.3 1
Trichlorofluoromethane ND ug/kg 05/10/24 02:58 75-69-405/09/24 21:376.3 1
1,2,3-Trichloropropane ND ug/kg 05/10/24 02:58 96-18-405/09/24 21:376.3 1
1,2,4-Trimethylbenzene ND ug/kg 05/10/24 02:58 95-63-605/09/24 21:376.3 1
1,3,5-Trimethylbenzene ND ug/kg 05/10/24 02:58 108-67-805/09/24 21:376.3 1
Vinyl acetate ND ug/kg 05/10/24 02:58 108-05-405/09/24 21:3763.1 1
Vinyl chloride ND ug/kg 05/10/24 02:58 75-01-405/09/24 21:3712.6 1
Xylene (Total)ND ug/kg 05/10/24 02:58 1330-20-705/09/24 21:3712.6 1
m&p-Xylene ND ug/kg 05/10/24 02:58 179601-23-105/09/24 21:3712.6 1
o-Xylene ND ug/kg 05/10/24 02:58 95-47-605/09/24 21:376.3 1
Surrogates
Toluene-d8 (S)103 %05/10/24 02:58 2037-26-505/09/24 21:3770-130 1
4-Bromofluorobenzene (S)107 %05/10/24 02:58 460-00-405/09/24 21:3770-130 1
1,2-Dichloroethane-d4 (S)114 %05/10/24 02:58 17060-07-005/09/24 21:3770-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 17.1 %05/10/24 10:40 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Sample:SB-18 (3-4)Lab ID:92730039002 Collected:05/07/24 12:50 Received:05/08/24 10:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone ND ug/kg 05/10/24 03:17 67-64-105/09/24 21:371221
Benzene ND ug/kg 05/10/24 03:17 71-43-205/09/24 21:376.1 1
Bromobenzene ND ug/kg 05/10/24 03:17 108-86-105/09/24 21:376.1 1
Bromochloromethane ND ug/kg 05/10/24 03:17 74-97-505/09/24 21:376.1 1
Bromodichloromethane ND ug/kg 05/10/24 03:17 75-27-405/09/24 21:376.1 1
Bromoform ND ug/kg 05/10/24 03:17 75-25-205/09/24 21:376.1 1
Bromomethane ND ug/kg 05/10/24 03:17 74-83-905/09/24 21:3724.3 1
2-Butanone (MEK)ND ug/kg 05/10/24 03:17 78-93-305/09/24 21:371221
n-Butylbenzene ND ug/kg 05/10/24 03:17 104-51-805/09/24 21:376.1 1
sec-Butylbenzene ND ug/kg 05/10/24 03:17 135-98-805/09/24 21:376.1 1
tert-Butylbenzene ND ug/kg 05/10/24 03:17 98-06-605/09/24 21:376.1 1
Carbon tetrachloride ND ug/kg 05/10/24 03:17 56-23-505/09/24 21:376.1 1
Chlorobenzene ND ug/kg 05/10/24 03:17 108-90-705/09/24 21:376.1 1
Chloroethane ND ug/kg 05/10/24 03:17 75-00-305/09/24 21:3712.2 1
Chloroform ND ug/kg 05/10/24 03:17 67-66-305/09/24 21:376.1 1
Chloromethane ND ug/kg 05/10/24 03:17 74-87-305/09/24 21:3712.2 1
2-Chlorotoluene ND ug/kg 05/10/24 03:17 95-49-805/09/24 21:376.1 1
4-Chlorotoluene ND ug/kg 05/10/24 03:17 106-43-405/09/24 21:376.1 1
1,2-Dibromo-3-chloropropane ND ug/kg 05/10/24 03:17 96-12-805/09/24 21:376.1 1
Dibromochloromethane ND ug/kg 05/10/24 03:17 124-48-105/09/24 21:376.1 1
1,2-Dibromoethane (EDB)ND ug/kg 05/10/24 03:17 106-93-405/09/24 21:376.1 1
Dibromomethane ND ug/kg 05/10/24 03:17 74-95-305/09/24 21:376.1 1
1,2-Dichlorobenzene ND ug/kg 05/10/24 03:17 95-50-105/09/24 21:376.1 1
1,3-Dichlorobenzene ND ug/kg 05/10/24 03:17 541-73-105/09/24 21:376.1 1
1,4-Dichlorobenzene ND ug/kg 05/10/24 03:17 106-46-705/09/24 21:376.1 1
Dichlorodifluoromethane ND ug/kg 05/10/24 03:17 75-71-8 IH05/09/24 21:3712.2 1
1,1-Dichloroethane ND ug/kg 05/10/24 03:17 75-34-305/09/24 21:376.1 1
1,2-Dichloroethane ND ug/kg 05/10/24 03:17 107-06-205/09/24 21:376.1 1
1,1-Dichloroethene ND ug/kg 05/10/24 03:17 75-35-405/09/24 21:376.1 1
cis-1,2-Dichloroethene ND ug/kg 05/10/24 03:17 156-59-205/09/24 21:376.1 1
trans-1,2-Dichloroethene ND ug/kg 05/10/24 03:17 156-60-505/09/24 21:376.1 1
1,2-Dichloropropane ND ug/kg 05/10/24 03:17 78-87-505/09/24 21:376.1 1
1,3-Dichloropropane ND ug/kg 05/10/24 03:17 142-28-905/09/24 21:376.1 1
2,2-Dichloropropane ND ug/kg 05/10/24 03:17 594-20-705/09/24 21:376.1 1
1,1-Dichloropropene ND ug/kg 05/10/24 03:17 563-58-605/09/24 21:376.1 1
cis-1,3-Dichloropropene ND ug/kg 05/10/24 03:17 10061-01-505/09/24 21:376.1 1
trans-1,3-Dichloropropene ND ug/kg 05/10/24 03:17 10061-02-605/09/24 21:376.1 1
Diisopropyl ether ND ug/kg 05/10/24 03:17 108-20-305/09/24 21:376.1 1
Ethylbenzene ND ug/kg 05/10/24 03:17 100-41-405/09/24 21:376.1 1
Hexachloro-1,3-butadiene ND ug/kg 05/10/24 03:17 87-68-305/09/24 21:3712.2 1
2-Hexanone ND ug/kg 05/10/24 03:17 591-78-605/09/24 21:3760.8 1
Isopropylbenzene (Cumene)ND ug/kg 05/10/24 03:17 98-82-805/09/24 21:376.1 1
p-Isopropyltoluene ND ug/kg 05/10/24 03:17 99-87-605/09/24 21:376.1 1
Methylene Chloride ND ug/kg 05/10/24 03:17 75-09-205/09/24 21:3724.3 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 05/10/24 03:17 108-10-105/09/24 21:3760.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Sample:SB-18 (3-4)Lab ID:92730039002 Collected:05/07/24 12:50 Received:05/08/24 10:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Methyl-tert-butyl ether ND ug/kg 05/10/24 03:17 1634-04-405/09/24 21:376.1 1
Naphthalene 33.7 ug/kg 05/10/24 03:17 91-20-305/09/24 21:376.1 1
n-Propylbenzene ND ug/kg 05/10/24 03:17 103-65-105/09/24 21:376.1 1
Styrene ND ug/kg 05/10/24 03:17 100-42-505/09/24 21:376.1 1
1,1,1,2-Tetrachloroethane ND ug/kg 05/10/24 03:17 630-20-605/09/24 21:376.1 1
1,1,2,2-Tetrachloroethane ND ug/kg 05/10/24 03:17 79-34-505/09/24 21:376.1 1
Tetrachloroethene 26.6 ug/kg 05/10/24 03:17 127-18-405/09/24 21:376.1 1
Toluene ND ug/kg 05/10/24 03:17 108-88-305/09/24 21:376.1 1
1,2,3-Trichlorobenzene ND ug/kg 05/10/24 03:17 87-61-605/09/24 21:376.1 1
1,2,4-Trichlorobenzene ND ug/kg 05/10/24 03:17 120-82-105/09/24 21:376.1 1
1,1,1-Trichloroethane ND ug/kg 05/10/24 03:17 71-55-605/09/24 21:376.1 1
1,1,2-Trichloroethane ND ug/kg 05/10/24 03:17 79-00-505/09/24 21:376.1 1
Trichloroethene ND ug/kg 05/10/24 03:17 79-01-605/09/24 21:376.1 1
Trichlorofluoromethane ND ug/kg 05/10/24 03:17 75-69-405/09/24 21:376.1 1
1,2,3-Trichloropropane ND ug/kg 05/10/24 03:17 96-18-405/09/24 21:376.1 1
1,2,4-Trimethylbenzene ND ug/kg 05/10/24 03:17 95-63-605/09/24 21:376.1 1
1,3,5-Trimethylbenzene ND ug/kg 05/10/24 03:17 108-67-805/09/24 21:376.1 1
Vinyl acetate ND ug/kg 05/10/24 03:17 108-05-405/09/24 21:3760.8 1
Vinyl chloride ND ug/kg 05/10/24 03:17 75-01-405/09/24 21:3712.2 1
Xylene (Total)ND ug/kg 05/10/24 03:17 1330-20-705/09/24 21:3712.2 1
m&p-Xylene ND ug/kg 05/10/24 03:17 179601-23-105/09/24 21:3712.2 1
o-Xylene ND ug/kg 05/10/24 03:17 95-47-605/09/24 21:376.1 1
Surrogates
Toluene-d8 (S)101 %05/10/24 03:17 2037-26-505/09/24 21:3770-130 1
4-Bromofluorobenzene (S)282 %05/10/24 03:17 460-00-4 S505/09/24 21:3770-130 1
1,2-Dichloroethane-d4 (S)109 %05/10/24 03:17 17060-07-005/09/24 21:3770-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 12.7 %05/10/24 10:40 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Sample:SB-19 (0-1)Lab ID:92730039003 Collected:05/07/24 13:00 Received:05/08/24 10:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone ND ug/kg 05/10/24 03:35 67-64-105/09/24 21:371361
Benzene ND ug/kg 05/10/24 03:35 71-43-205/09/24 21:376.8 1
Bromobenzene ND ug/kg 05/10/24 03:35 108-86-105/09/24 21:376.8 1
Bromochloromethane ND ug/kg 05/10/24 03:35 74-97-505/09/24 21:376.8 1
Bromodichloromethane ND ug/kg 05/10/24 03:35 75-27-405/09/24 21:376.8 1
Bromoform ND ug/kg 05/10/24 03:35 75-25-205/09/24 21:376.8 1
Bromomethane ND ug/kg 05/10/24 03:35 74-83-905/09/24 21:3727.3 1
2-Butanone (MEK)ND ug/kg 05/10/24 03:35 78-93-305/09/24 21:371361
n-Butylbenzene ND ug/kg 05/10/24 03:35 104-51-805/09/24 21:376.8 1
sec-Butylbenzene ND ug/kg 05/10/24 03:35 135-98-805/09/24 21:376.8 1
tert-Butylbenzene ND ug/kg 05/10/24 03:35 98-06-605/09/24 21:376.8 1
Carbon tetrachloride ND ug/kg 05/10/24 03:35 56-23-505/09/24 21:376.8 1
Chlorobenzene ND ug/kg 05/10/24 03:35 108-90-705/09/24 21:376.8 1
Chloroethane ND ug/kg 05/10/24 03:35 75-00-305/09/24 21:3713.6 1
Chloroform ND ug/kg 05/10/24 03:35 67-66-305/09/24 21:376.8 1
Chloromethane ND ug/kg 05/10/24 03:35 74-87-305/09/24 21:3713.6 1
2-Chlorotoluene ND ug/kg 05/10/24 03:35 95-49-805/09/24 21:376.8 1
4-Chlorotoluene ND ug/kg 05/10/24 03:35 106-43-405/09/24 21:376.8 1
1,2-Dibromo-3-chloropropane ND ug/kg 05/10/24 03:35 96-12-805/09/24 21:376.8 1
Dibromochloromethane ND ug/kg 05/10/24 03:35 124-48-105/09/24 21:376.8 1
1,2-Dibromoethane (EDB)ND ug/kg 05/10/24 03:35 106-93-405/09/24 21:376.8 1
Dibromomethane ND ug/kg 05/10/24 03:35 74-95-305/09/24 21:376.8 1
1,2-Dichlorobenzene ND ug/kg 05/10/24 03:35 95-50-105/09/24 21:376.8 1
1,3-Dichlorobenzene ND ug/kg 05/10/24 03:35 541-73-105/09/24 21:376.8 1
1,4-Dichlorobenzene ND ug/kg 05/10/24 03:35 106-46-705/09/24 21:376.8 1
Dichlorodifluoromethane ND ug/kg 05/10/24 03:35 75-71-8 IH05/09/24 21:3713.6 1
1,1-Dichloroethane ND ug/kg 05/10/24 03:35 75-34-305/09/24 21:376.8 1
1,2-Dichloroethane ND ug/kg 05/10/24 03:35 107-06-205/09/24 21:376.8 1
1,1-Dichloroethene ND ug/kg 05/10/24 03:35 75-35-405/09/24 21:376.8 1
cis-1,2-Dichloroethene ND ug/kg 05/10/24 03:35 156-59-205/09/24 21:376.8 1
trans-1,2-Dichloroethene ND ug/kg 05/10/24 03:35 156-60-505/09/24 21:376.8 1
1,2-Dichloropropane ND ug/kg 05/10/24 03:35 78-87-505/09/24 21:376.8 1
1,3-Dichloropropane ND ug/kg 05/10/24 03:35 142-28-905/09/24 21:376.8 1
2,2-Dichloropropane ND ug/kg 05/10/24 03:35 594-20-705/09/24 21:376.8 1
1,1-Dichloropropene ND ug/kg 05/10/24 03:35 563-58-605/09/24 21:376.8 1
cis-1,3-Dichloropropene ND ug/kg 05/10/24 03:35 10061-01-505/09/24 21:376.8 1
trans-1,3-Dichloropropene ND ug/kg 05/10/24 03:35 10061-02-605/09/24 21:376.8 1
Diisopropyl ether ND ug/kg 05/10/24 03:35 108-20-305/09/24 21:376.8 1
Ethylbenzene ND ug/kg 05/10/24 03:35 100-41-405/09/24 21:376.8 1
Hexachloro-1,3-butadiene ND ug/kg 05/10/24 03:35 87-68-305/09/24 21:3713.6 1
2-Hexanone ND ug/kg 05/10/24 03:35 591-78-605/09/24 21:3768.1 1
Isopropylbenzene (Cumene)ND ug/kg 05/10/24 03:35 98-82-805/09/24 21:376.8 1
p-Isopropyltoluene ND ug/kg 05/10/24 03:35 99-87-605/09/24 21:376.8 1
Methylene Chloride ND ug/kg 05/10/24 03:35 75-09-205/09/24 21:3727.3 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 05/10/24 03:35 108-10-105/09/24 21:3768.1 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Sample:SB-19 (0-1)Lab ID:92730039003 Collected:05/07/24 13:00 Received:05/08/24 10:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Methyl-tert-butyl ether ND ug/kg 05/10/24 03:35 1634-04-405/09/24 21:376.8 1
Naphthalene ND ug/kg 05/10/24 03:35 91-20-305/09/24 21:376.8 1
n-Propylbenzene ND ug/kg 05/10/24 03:35 103-65-105/09/24 21:376.8 1
Styrene ND ug/kg 05/10/24 03:35 100-42-505/09/24 21:376.8 1
1,1,1,2-Tetrachloroethane ND ug/kg 05/10/24 03:35 630-20-605/09/24 21:376.8 1
1,1,2,2-Tetrachloroethane ND ug/kg 05/10/24 03:35 79-34-505/09/24 21:376.8 1
Tetrachloroethene ND ug/kg 05/10/24 03:35 127-18-405/09/24 21:376.8 1
Toluene ND ug/kg 05/10/24 03:35 108-88-305/09/24 21:376.8 1
1,2,3-Trichlorobenzene ND ug/kg 05/10/24 03:35 87-61-605/09/24 21:376.8 1
1,2,4-Trichlorobenzene ND ug/kg 05/10/24 03:35 120-82-105/09/24 21:376.8 1
1,1,1-Trichloroethane ND ug/kg 05/10/24 03:35 71-55-605/09/24 21:376.8 1
1,1,2-Trichloroethane ND ug/kg 05/10/24 03:35 79-00-505/09/24 21:376.8 1
Trichloroethene ND ug/kg 05/10/24 03:35 79-01-605/09/24 21:376.8 1
Trichlorofluoromethane ND ug/kg 05/10/24 03:35 75-69-405/09/24 21:376.8 1
1,2,3-Trichloropropane ND ug/kg 05/10/24 03:35 96-18-405/09/24 21:376.8 1
1,2,4-Trimethylbenzene ND ug/kg 05/10/24 03:35 95-63-605/09/24 21:376.8 1
1,3,5-Trimethylbenzene ND ug/kg 05/10/24 03:35 108-67-805/09/24 21:376.8 1
Vinyl acetate ND ug/kg 05/10/24 03:35 108-05-405/09/24 21:3768.1 1
Vinyl chloride ND ug/kg 05/10/24 03:35 75-01-405/09/24 21:3713.6 1
Xylene (Total)ND ug/kg 05/10/24 03:35 1330-20-705/09/24 21:3713.6 1
m&p-Xylene ND ug/kg 05/10/24 03:35 179601-23-105/09/24 21:3713.6 1
o-Xylene ND ug/kg 05/10/24 03:35 95-47-605/09/24 21:376.8 1
Surrogates
Toluene-d8 (S)101 %05/10/24 03:35 2037-26-505/09/24 21:3770-130 1
4-Bromofluorobenzene (S)104 %05/10/24 03:35 460-00-405/09/24 21:3770-130 1
1,2-Dichloroethane-d4 (S)106 %05/10/24 03:35 17060-07-005/09/24 21:3770-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 20.9 %05/10/24 10:41 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Sample:SB-19 (1-2)Lab ID:92730039004 Collected:05/07/24 13:05 Received:05/08/24 10:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone ND ug/kg 05/10/24 03:53 67-64-105/09/24 21:371431
Benzene ND ug/kg 05/10/24 03:53 71-43-205/09/24 21:377.1 1
Bromobenzene ND ug/kg 05/10/24 03:53 108-86-105/09/24 21:377.1 1
Bromochloromethane ND ug/kg 05/10/24 03:53 74-97-505/09/24 21:377.1 1
Bromodichloromethane ND ug/kg 05/10/24 03:53 75-27-405/09/24 21:377.1 1
Bromoform ND ug/kg 05/10/24 03:53 75-25-205/09/24 21:377.1 1
Bromomethane ND ug/kg 05/10/24 03:53 74-83-905/09/24 21:3728.6 1
2-Butanone (MEK)ND ug/kg 05/10/24 03:53 78-93-305/09/24 21:371431
n-Butylbenzene ND ug/kg 05/10/24 03:53 104-51-805/09/24 21:377.1 1
sec-Butylbenzene ND ug/kg 05/10/24 03:53 135-98-805/09/24 21:377.1 1
tert-Butylbenzene ND ug/kg 05/10/24 03:53 98-06-605/09/24 21:377.1 1
Carbon tetrachloride ND ug/kg 05/10/24 03:53 56-23-505/09/24 21:377.1 1
Chlorobenzene ND ug/kg 05/10/24 03:53 108-90-705/09/24 21:377.1 1
Chloroethane ND ug/kg 05/10/24 03:53 75-00-305/09/24 21:3714.3 1
Chloroform ND ug/kg 05/10/24 03:53 67-66-305/09/24 21:377.1 1
Chloromethane ND ug/kg 05/10/24 03:53 74-87-305/09/24 21:3714.3 1
2-Chlorotoluene ND ug/kg 05/10/24 03:53 95-49-805/09/24 21:377.1 1
4-Chlorotoluene ND ug/kg 05/10/24 03:53 106-43-405/09/24 21:377.1 1
1,2-Dibromo-3-chloropropane ND ug/kg 05/10/24 03:53 96-12-805/09/24 21:377.1 1
Dibromochloromethane ND ug/kg 05/10/24 03:53 124-48-105/09/24 21:377.1 1
1,2-Dibromoethane (EDB)ND ug/kg 05/10/24 03:53 106-93-405/09/24 21:377.1 1
Dibromomethane ND ug/kg 05/10/24 03:53 74-95-305/09/24 21:377.1 1
1,2-Dichlorobenzene ND ug/kg 05/10/24 03:53 95-50-105/09/24 21:377.1 1
1,3-Dichlorobenzene ND ug/kg 05/10/24 03:53 541-73-105/09/24 21:377.1 1
1,4-Dichlorobenzene ND ug/kg 05/10/24 03:53 106-46-705/09/24 21:377.1 1
Dichlorodifluoromethane ND ug/kg 05/10/24 03:53 75-71-8 IH05/09/24 21:3714.3 1
1,1-Dichloroethane ND ug/kg 05/10/24 03:53 75-34-305/09/24 21:377.1 1
1,2-Dichloroethane ND ug/kg 05/10/24 03:53 107-06-205/09/24 21:377.1 1
1,1-Dichloroethene ND ug/kg 05/10/24 03:53 75-35-405/09/24 21:377.1 1
cis-1,2-Dichloroethene ND ug/kg 05/10/24 03:53 156-59-205/09/24 21:377.1 1
trans-1,2-Dichloroethene ND ug/kg 05/10/24 03:53 156-60-505/09/24 21:377.1 1
1,2-Dichloropropane ND ug/kg 05/10/24 03:53 78-87-505/09/24 21:377.1 1
1,3-Dichloropropane ND ug/kg 05/10/24 03:53 142-28-905/09/24 21:377.1 1
2,2-Dichloropropane ND ug/kg 05/10/24 03:53 594-20-705/09/24 21:377.1 1
1,1-Dichloropropene ND ug/kg 05/10/24 03:53 563-58-605/09/24 21:377.1 1
cis-1,3-Dichloropropene ND ug/kg 05/10/24 03:53 10061-01-505/09/24 21:377.1 1
trans-1,3-Dichloropropene ND ug/kg 05/10/24 03:53 10061-02-605/09/24 21:377.1 1
Diisopropyl ether ND ug/kg 05/10/24 03:53 108-20-305/09/24 21:377.1 1
Ethylbenzene ND ug/kg 05/10/24 03:53 100-41-405/09/24 21:377.1 1
Hexachloro-1,3-butadiene ND ug/kg 05/10/24 03:53 87-68-305/09/24 21:3714.3 1
2-Hexanone ND ug/kg 05/10/24 03:53 591-78-605/09/24 21:3771.4 1
Isopropylbenzene (Cumene)ND ug/kg 05/10/24 03:53 98-82-805/09/24 21:377.1 1
p-Isopropyltoluene ND ug/kg 05/10/24 03:53 99-87-605/09/24 21:377.1 1
Methylene Chloride ND ug/kg 05/10/24 03:53 75-09-205/09/24 21:3728.6 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 05/10/24 03:53 108-10-105/09/24 21:3771.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Sample:SB-19 (1-2)Lab ID:92730039004 Collected:05/07/24 13:05 Received:05/08/24 10:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Methyl-tert-butyl ether ND ug/kg 05/10/24 03:53 1634-04-405/09/24 21:377.1 1
Naphthalene ND ug/kg 05/10/24 03:53 91-20-305/09/24 21:377.1 1
n-Propylbenzene ND ug/kg 05/10/24 03:53 103-65-105/09/24 21:377.1 1
Styrene ND ug/kg 05/10/24 03:53 100-42-505/09/24 21:377.1 1
1,1,1,2-Tetrachloroethane ND ug/kg 05/10/24 03:53 630-20-605/09/24 21:377.1 1
1,1,2,2-Tetrachloroethane ND ug/kg 05/10/24 03:53 79-34-505/09/24 21:377.1 1
Tetrachloroethene ND ug/kg 05/10/24 03:53 127-18-405/09/24 21:377.1 1
Toluene ND ug/kg 05/10/24 03:53 108-88-305/09/24 21:377.1 1
1,2,3-Trichlorobenzene ND ug/kg 05/10/24 03:53 87-61-605/09/24 21:377.1 1
1,2,4-Trichlorobenzene ND ug/kg 05/10/24 03:53 120-82-105/09/24 21:377.1 1
1,1,1-Trichloroethane ND ug/kg 05/10/24 03:53 71-55-605/09/24 21:377.1 1
1,1,2-Trichloroethane ND ug/kg 05/10/24 03:53 79-00-505/09/24 21:377.1 1
Trichloroethene ND ug/kg 05/10/24 03:53 79-01-605/09/24 21:377.1 1
Trichlorofluoromethane ND ug/kg 05/10/24 03:53 75-69-405/09/24 21:377.1 1
1,2,3-Trichloropropane ND ug/kg 05/10/24 03:53 96-18-405/09/24 21:377.1 1
1,2,4-Trimethylbenzene ND ug/kg 05/10/24 03:53 95-63-605/09/24 21:377.1 1
1,3,5-Trimethylbenzene ND ug/kg 05/10/24 03:53 108-67-805/09/24 21:377.1 1
Vinyl acetate ND ug/kg 05/10/24 03:53 108-05-405/09/24 21:3771.4 1
Vinyl chloride ND ug/kg 05/10/24 03:53 75-01-405/09/24 21:3714.3 1
Xylene (Total)ND ug/kg 05/10/24 03:53 1330-20-705/09/24 21:3714.3 1
m&p-Xylene ND ug/kg 05/10/24 03:53 179601-23-105/09/24 21:3714.3 1
o-Xylene ND ug/kg 05/10/24 03:53 95-47-605/09/24 21:377.1 1
Surrogates
Toluene-d8 (S)101 %05/10/24 03:53 2037-26-505/09/24 21:3770-130 1
4-Bromofluorobenzene (S)102 %05/10/24 03:53 460-00-405/09/24 21:3770-130 1
1,2-Dichloroethane-d4 (S)106 %05/10/24 03:53 17060-07-005/09/24 21:3770-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 23.9 %05/10/24 10:41 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Sample:SB-20 (0-1)Lab ID:92730039005 Collected:05/07/24 14:25 Received:05/08/24 10:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone ND ug/kg 05/10/24 04:12 67-64-105/09/24 21:372171
Benzene ND ug/kg 05/10/24 04:12 71-43-205/09/24 21:3710.8 1
Bromobenzene ND ug/kg 05/10/24 04:12 108-86-105/09/24 21:3710.8 1
Bromochloromethane ND ug/kg 05/10/24 04:12 74-97-505/09/24 21:3710.8 1
Bromodichloromethane ND ug/kg 05/10/24 04:12 75-27-405/09/24 21:3710.8 1
Bromoform ND ug/kg 05/10/24 04:12 75-25-205/09/24 21:3710.8 1
Bromomethane ND ug/kg 05/10/24 04:12 74-83-905/09/24 21:3743.3 1
2-Butanone (MEK)ND ug/kg 05/10/24 04:12 78-93-305/09/24 21:372171
n-Butylbenzene ND ug/kg 05/10/24 04:12 104-51-805/09/24 21:3710.8 1
sec-Butylbenzene ND ug/kg 05/10/24 04:12 135-98-805/09/24 21:3710.8 1
tert-Butylbenzene ND ug/kg 05/10/24 04:12 98-06-605/09/24 21:3710.8 1
Carbon tetrachloride ND ug/kg 05/10/24 04:12 56-23-505/09/24 21:3710.8 1
Chlorobenzene ND ug/kg 05/10/24 04:12 108-90-705/09/24 21:3710.8 1
Chloroethane ND ug/kg 05/10/24 04:12 75-00-305/09/24 21:3721.7 1
Chloroform ND ug/kg 05/10/24 04:12 67-66-305/09/24 21:3710.8 1
Chloromethane ND ug/kg 05/10/24 04:12 74-87-305/09/24 21:3721.7 1
2-Chlorotoluene ND ug/kg 05/10/24 04:12 95-49-805/09/24 21:3710.8 1
4-Chlorotoluene ND ug/kg 05/10/24 04:12 106-43-405/09/24 21:3710.8 1
1,2-Dibromo-3-chloropropane ND ug/kg 05/10/24 04:12 96-12-805/09/24 21:3710.8 1
Dibromochloromethane ND ug/kg 05/10/24 04:12 124-48-105/09/24 21:3710.8 1
1,2-Dibromoethane (EDB)ND ug/kg 05/10/24 04:12 106-93-405/09/24 21:3710.8 1
Dibromomethane ND ug/kg 05/10/24 04:12 74-95-305/09/24 21:3710.8 1
1,2-Dichlorobenzene ND ug/kg 05/10/24 04:12 95-50-105/09/24 21:3710.8 1
1,3-Dichlorobenzene ND ug/kg 05/10/24 04:12 541-73-105/09/24 21:3710.8 1
1,4-Dichlorobenzene ND ug/kg 05/10/24 04:12 106-46-705/09/24 21:3710.8 1
Dichlorodifluoromethane ND ug/kg 05/10/24 04:12 75-71-8 IH05/09/24 21:3721.7 1
1,1-Dichloroethane ND ug/kg 05/10/24 04:12 75-34-305/09/24 21:3710.8 1
1,2-Dichloroethane ND ug/kg 05/10/24 04:12 107-06-205/09/24 21:3710.8 1
1,1-Dichloroethene ND ug/kg 05/10/24 04:12 75-35-405/09/24 21:3710.8 1
cis-1,2-Dichloroethene ND ug/kg 05/10/24 04:12 156-59-205/09/24 21:3710.8 1
trans-1,2-Dichloroethene ND ug/kg 05/10/24 04:12 156-60-505/09/24 21:3710.8 1
1,2-Dichloropropane ND ug/kg 05/10/24 04:12 78-87-505/09/24 21:3710.8 1
1,3-Dichloropropane ND ug/kg 05/10/24 04:12 142-28-905/09/24 21:3710.8 1
2,2-Dichloropropane ND ug/kg 05/10/24 04:12 594-20-705/09/24 21:3710.8 1
1,1-Dichloropropene ND ug/kg 05/10/24 04:12 563-58-605/09/24 21:3710.8 1
cis-1,3-Dichloropropene ND ug/kg 05/10/24 04:12 10061-01-505/09/24 21:3710.8 1
trans-1,3-Dichloropropene ND ug/kg 05/10/24 04:12 10061-02-605/09/24 21:3710.8 1
Diisopropyl ether ND ug/kg 05/10/24 04:12 108-20-305/09/24 21:3710.8 1
Ethylbenzene ND ug/kg 05/10/24 04:12 100-41-405/09/24 21:3710.8 1
Hexachloro-1,3-butadiene ND ug/kg 05/10/24 04:12 87-68-305/09/24 21:3721.7 1
2-Hexanone ND ug/kg 05/10/24 04:12 591-78-605/09/24 21:371081
Isopropylbenzene (Cumene)ND ug/kg 05/10/24 04:12 98-82-805/09/24 21:3710.8 1
p-Isopropyltoluene ND ug/kg 05/10/24 04:12 99-87-605/09/24 21:3710.8 1
Methylene Chloride ND ug/kg 05/10/24 04:12 75-09-205/09/24 21:3743.3 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 05/10/24 04:12 108-10-105/09/24 21:371081
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Sample:SB-20 (0-1)Lab ID:92730039005 Collected:05/07/24 14:25 Received:05/08/24 10:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Methyl-tert-butyl ether ND ug/kg 05/10/24 04:12 1634-04-405/09/24 21:3710.8 1
Naphthalene ND ug/kg 05/10/24 04:12 91-20-305/09/24 21:3710.8 1
n-Propylbenzene ND ug/kg 05/10/24 04:12 103-65-105/09/24 21:3710.8 1
Styrene ND ug/kg 05/10/24 04:12 100-42-505/09/24 21:3710.8 1
1,1,1,2-Tetrachloroethane ND ug/kg 05/10/24 04:12 630-20-605/09/24 21:3710.8 1
1,1,2,2-Tetrachloroethane ND ug/kg 05/10/24 04:12 79-34-505/09/24 21:3710.8 1
Tetrachloroethene ND ug/kg 05/10/24 04:12 127-18-405/09/24 21:3710.8 1
Toluene ND ug/kg 05/10/24 04:12 108-88-305/09/24 21:3710.8 1
1,2,3-Trichlorobenzene ND ug/kg 05/10/24 04:12 87-61-605/09/24 21:3710.8 1
1,2,4-Trichlorobenzene ND ug/kg 05/10/24 04:12 120-82-105/09/24 21:3710.8 1
1,1,1-Trichloroethane ND ug/kg 05/10/24 04:12 71-55-605/09/24 21:3710.8 1
1,1,2-Trichloroethane ND ug/kg 05/10/24 04:12 79-00-505/09/24 21:3710.8 1
Trichloroethene ND ug/kg 05/10/24 04:12 79-01-605/09/24 21:3710.8 1
Trichlorofluoromethane ND ug/kg 05/10/24 04:12 75-69-405/09/24 21:3710.8 1
1,2,3-Trichloropropane ND ug/kg 05/10/24 04:12 96-18-405/09/24 21:3710.8 1
1,2,4-Trimethylbenzene ND ug/kg 05/10/24 04:12 95-63-605/09/24 21:3710.8 1
1,3,5-Trimethylbenzene ND ug/kg 05/10/24 04:12 108-67-805/09/24 21:3710.8 1
Vinyl acetate ND ug/kg 05/10/24 04:12 108-05-405/09/24 21:371081
Vinyl chloride ND ug/kg 05/10/24 04:12 75-01-405/09/24 21:3721.7 1
Xylene (Total)ND ug/kg 05/10/24 04:12 1330-20-705/09/24 21:3721.7 1
m&p-Xylene ND ug/kg 05/10/24 04:12 179601-23-105/09/24 21:3721.7 1
o-Xylene ND ug/kg 05/10/24 04:12 95-47-605/09/24 21:3710.8 1
Surrogates
Toluene-d8 (S)101 %05/10/24 04:12 2037-26-505/09/24 21:3770-130 1
4-Bromofluorobenzene (S)101 %05/10/24 04:12 460-00-405/09/24 21:3770-130 1
1,2-Dichloroethane-d4 (S)102 %05/10/24 04:12 17060-07-005/09/24 21:3770-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 20.5 %05/10/24 10:41 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Sample:SB-20 (4-5)Lab ID:92730039006 Collected:05/07/24 14:30 Received:05/08/24 10:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone ND ug/kg 05/10/24 04:30 67-64-105/09/24 21:371261
Benzene ND ug/kg 05/10/24 04:30 71-43-205/09/24 21:376.3 1
Bromobenzene ND ug/kg 05/10/24 04:30 108-86-105/09/24 21:376.3 1
Bromochloromethane ND ug/kg 05/10/24 04:30 74-97-505/09/24 21:376.3 1
Bromodichloromethane ND ug/kg 05/10/24 04:30 75-27-405/09/24 21:376.3 1
Bromoform ND ug/kg 05/10/24 04:30 75-25-205/09/24 21:376.3 1
Bromomethane ND ug/kg 05/10/24 04:30 74-83-905/09/24 21:3725.2 1
2-Butanone (MEK)ND ug/kg 05/10/24 04:30 78-93-305/09/24 21:371261
n-Butylbenzene ND ug/kg 05/10/24 04:30 104-51-805/09/24 21:376.3 1
sec-Butylbenzene ND ug/kg 05/10/24 04:30 135-98-805/09/24 21:376.3 1
tert-Butylbenzene ND ug/kg 05/10/24 04:30 98-06-605/09/24 21:376.3 1
Carbon tetrachloride ND ug/kg 05/10/24 04:30 56-23-505/09/24 21:376.3 1
Chlorobenzene ND ug/kg 05/10/24 04:30 108-90-705/09/24 21:376.3 1
Chloroethane ND ug/kg 05/10/24 04:30 75-00-305/09/24 21:3712.6 1
Chloroform ND ug/kg 05/10/24 04:30 67-66-305/09/24 21:376.3 1
Chloromethane ND ug/kg 05/10/24 04:30 74-87-305/09/24 21:3712.6 1
2-Chlorotoluene ND ug/kg 05/10/24 04:30 95-49-805/09/24 21:376.3 1
4-Chlorotoluene ND ug/kg 05/10/24 04:30 106-43-405/09/24 21:376.3 1
1,2-Dibromo-3-chloropropane ND ug/kg 05/10/24 04:30 96-12-805/09/24 21:376.3 1
Dibromochloromethane ND ug/kg 05/10/24 04:30 124-48-105/09/24 21:376.3 1
1,2-Dibromoethane (EDB)ND ug/kg 05/10/24 04:30 106-93-405/09/24 21:376.3 1
Dibromomethane ND ug/kg 05/10/24 04:30 74-95-305/09/24 21:376.3 1
1,2-Dichlorobenzene ND ug/kg 05/10/24 04:30 95-50-105/09/24 21:376.3 1
1,3-Dichlorobenzene ND ug/kg 05/10/24 04:30 541-73-105/09/24 21:376.3 1
1,4-Dichlorobenzene ND ug/kg 05/10/24 04:30 106-46-705/09/24 21:376.3 1
Dichlorodifluoromethane ND ug/kg 05/10/24 04:30 75-71-8 IH05/09/24 21:3712.6 1
1,1-Dichloroethane ND ug/kg 05/10/24 04:30 75-34-305/09/24 21:376.3 1
1,2-Dichloroethane ND ug/kg 05/10/24 04:30 107-06-205/09/24 21:376.3 1
1,1-Dichloroethene ND ug/kg 05/10/24 04:30 75-35-405/09/24 21:376.3 1
cis-1,2-Dichloroethene ND ug/kg 05/10/24 04:30 156-59-205/09/24 21:376.3 1
trans-1,2-Dichloroethene ND ug/kg 05/10/24 04:30 156-60-505/09/24 21:376.3 1
1,2-Dichloropropane ND ug/kg 05/10/24 04:30 78-87-505/09/24 21:376.3 1
1,3-Dichloropropane ND ug/kg 05/10/24 04:30 142-28-905/09/24 21:376.3 1
2,2-Dichloropropane ND ug/kg 05/10/24 04:30 594-20-705/09/24 21:376.3 1
1,1-Dichloropropene ND ug/kg 05/10/24 04:30 563-58-605/09/24 21:376.3 1
cis-1,3-Dichloropropene ND ug/kg 05/10/24 04:30 10061-01-505/09/24 21:376.3 1
trans-1,3-Dichloropropene ND ug/kg 05/10/24 04:30 10061-02-605/09/24 21:376.3 1
Diisopropyl ether ND ug/kg 05/10/24 04:30 108-20-305/09/24 21:376.3 1
Ethylbenzene ND ug/kg 05/10/24 04:30 100-41-405/09/24 21:376.3 1
Hexachloro-1,3-butadiene ND ug/kg 05/10/24 04:30 87-68-305/09/24 21:3712.6 1
2-Hexanone ND ug/kg 05/10/24 04:30 591-78-605/09/24 21:3763.1 1
Isopropylbenzene (Cumene)ND ug/kg 05/10/24 04:30 98-82-805/09/24 21:376.3 1
p-Isopropyltoluene ND ug/kg 05/10/24 04:30 99-87-605/09/24 21:376.3 1
Methylene Chloride ND ug/kg 05/10/24 04:30 75-09-205/09/24 21:3725.2 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 05/10/24 04:30 108-10-105/09/24 21:3763.1 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Sample:SB-20 (4-5)Lab ID:92730039006 Collected:05/07/24 14:30 Received:05/08/24 10:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Methyl-tert-butyl ether ND ug/kg 05/10/24 04:30 1634-04-405/09/24 21:376.3 1
Naphthalene ND ug/kg 05/10/24 04:30 91-20-305/09/24 21:376.3 1
n-Propylbenzene ND ug/kg 05/10/24 04:30 103-65-105/09/24 21:376.3 1
Styrene ND ug/kg 05/10/24 04:30 100-42-505/09/24 21:376.3 1
1,1,1,2-Tetrachloroethane ND ug/kg 05/10/24 04:30 630-20-605/09/24 21:376.3 1
1,1,2,2-Tetrachloroethane ND ug/kg 05/10/24 04:30 79-34-505/09/24 21:376.3 1
Tetrachloroethene ND ug/kg 05/10/24 04:30 127-18-405/09/24 21:376.3 1
Toluene ND ug/kg 05/10/24 04:30 108-88-305/09/24 21:376.3 1
1,2,3-Trichlorobenzene ND ug/kg 05/10/24 04:30 87-61-605/09/24 21:376.3 1
1,2,4-Trichlorobenzene ND ug/kg 05/10/24 04:30 120-82-105/09/24 21:376.3 1
1,1,1-Trichloroethane ND ug/kg 05/10/24 04:30 71-55-605/09/24 21:376.3 1
1,1,2-Trichloroethane ND ug/kg 05/10/24 04:30 79-00-505/09/24 21:376.3 1
Trichloroethene ND ug/kg 05/10/24 04:30 79-01-605/09/24 21:376.3 1
Trichlorofluoromethane ND ug/kg 05/10/24 04:30 75-69-405/09/24 21:376.3 1
1,2,3-Trichloropropane ND ug/kg 05/10/24 04:30 96-18-405/09/24 21:376.3 1
1,2,4-Trimethylbenzene ND ug/kg 05/10/24 04:30 95-63-605/09/24 21:376.3 1
1,3,5-Trimethylbenzene ND ug/kg 05/10/24 04:30 108-67-805/09/24 21:376.3 1
Vinyl acetate ND ug/kg 05/10/24 04:30 108-05-405/09/24 21:3763.1 1
Vinyl chloride ND ug/kg 05/10/24 04:30 75-01-405/09/24 21:3712.6 1
Xylene (Total)ND ug/kg 05/10/24 04:30 1330-20-705/09/24 21:3712.6 1
m&p-Xylene ND ug/kg 05/10/24 04:30 179601-23-105/09/24 21:3712.6 1
o-Xylene ND ug/kg 05/10/24 04:30 95-47-605/09/24 21:376.3 1
Surrogates
Toluene-d8 (S)99 %05/10/24 04:30 2037-26-505/09/24 21:3770-130 1
4-Bromofluorobenzene (S)100 %05/10/24 04:30 460-00-405/09/24 21:3770-130 1
1,2-Dichloroethane-d4 (S)106 %05/10/24 04:30 17060-07-005/09/24 21:3770-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 18.2 %05/10/24 10:41 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Sample:SB-21 (0-1)Lab ID:92730039007 Collected:05/07/24 14:35 Received:05/08/24 10:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone ND ug/kg 05/10/24 04:49 67-64-105/09/24 21:371151
Benzene ND ug/kg 05/10/24 04:49 71-43-205/09/24 21:375.8 1
Bromobenzene ND ug/kg 05/10/24 04:49 108-86-105/09/24 21:375.8 1
Bromochloromethane ND ug/kg 05/10/24 04:49 74-97-505/09/24 21:375.8 1
Bromodichloromethane ND ug/kg 05/10/24 04:49 75-27-405/09/24 21:375.8 1
Bromoform ND ug/kg 05/10/24 04:49 75-25-205/09/24 21:375.8 1
Bromomethane ND ug/kg 05/10/24 04:49 74-83-905/09/24 21:3723.0 1
2-Butanone (MEK)ND ug/kg 05/10/24 04:49 78-93-305/09/24 21:371151
n-Butylbenzene ND ug/kg 05/10/24 04:49 104-51-805/09/24 21:375.8 1
sec-Butylbenzene ND ug/kg 05/10/24 04:49 135-98-805/09/24 21:375.8 1
tert-Butylbenzene ND ug/kg 05/10/24 04:49 98-06-605/09/24 21:375.8 1
Carbon tetrachloride ND ug/kg 05/10/24 04:49 56-23-505/09/24 21:375.8 1
Chlorobenzene ND ug/kg 05/10/24 04:49 108-90-705/09/24 21:375.8 1
Chloroethane ND ug/kg 05/10/24 04:49 75-00-305/09/24 21:3711.5 1
Chloroform ND ug/kg 05/10/24 04:49 67-66-305/09/24 21:375.8 1
Chloromethane ND ug/kg 05/10/24 04:49 74-87-305/09/24 21:3711.5 1
2-Chlorotoluene ND ug/kg 05/10/24 04:49 95-49-805/09/24 21:375.8 1
4-Chlorotoluene ND ug/kg 05/10/24 04:49 106-43-405/09/24 21:375.8 1
1,2-Dibromo-3-chloropropane ND ug/kg 05/10/24 04:49 96-12-805/09/24 21:375.8 1
Dibromochloromethane ND ug/kg 05/10/24 04:49 124-48-105/09/24 21:375.8 1
1,2-Dibromoethane (EDB)ND ug/kg 05/10/24 04:49 106-93-405/09/24 21:375.8 1
Dibromomethane ND ug/kg 05/10/24 04:49 74-95-305/09/24 21:375.8 1
1,2-Dichlorobenzene ND ug/kg 05/10/24 04:49 95-50-105/09/24 21:375.8 1
1,3-Dichlorobenzene ND ug/kg 05/10/24 04:49 541-73-105/09/24 21:375.8 1
1,4-Dichlorobenzene ND ug/kg 05/10/24 04:49 106-46-705/09/24 21:375.8 1
Dichlorodifluoromethane ND ug/kg 05/10/24 04:49 75-71-8 IH05/09/24 21:3711.5 1
1,1-Dichloroethane ND ug/kg 05/10/24 04:49 75-34-305/09/24 21:375.8 1
1,2-Dichloroethane ND ug/kg 05/10/24 04:49 107-06-205/09/24 21:375.8 1
1,1-Dichloroethene ND ug/kg 05/10/24 04:49 75-35-405/09/24 21:375.8 1
cis-1,2-Dichloroethene ND ug/kg 05/10/24 04:49 156-59-205/09/24 21:375.8 1
trans-1,2-Dichloroethene ND ug/kg 05/10/24 04:49 156-60-505/09/24 21:375.8 1
1,2-Dichloropropane ND ug/kg 05/10/24 04:49 78-87-505/09/24 21:375.8 1
1,3-Dichloropropane ND ug/kg 05/10/24 04:49 142-28-905/09/24 21:375.8 1
2,2-Dichloropropane ND ug/kg 05/10/24 04:49 594-20-705/09/24 21:375.8 1
1,1-Dichloropropene ND ug/kg 05/10/24 04:49 563-58-605/09/24 21:375.8 1
cis-1,3-Dichloropropene ND ug/kg 05/10/24 04:49 10061-01-505/09/24 21:375.8 1
trans-1,3-Dichloropropene ND ug/kg 05/10/24 04:49 10061-02-605/09/24 21:375.8 1
Diisopropyl ether ND ug/kg 05/10/24 04:49 108-20-305/09/24 21:375.8 1
Ethylbenzene ND ug/kg 05/10/24 04:49 100-41-405/09/24 21:375.8 1
Hexachloro-1,3-butadiene ND ug/kg 05/10/24 04:49 87-68-305/09/24 21:3711.5 1
2-Hexanone ND ug/kg 05/10/24 04:49 591-78-605/09/24 21:3757.6 1
Isopropylbenzene (Cumene)ND ug/kg 05/10/24 04:49 98-82-805/09/24 21:375.8 1
p-Isopropyltoluene ND ug/kg 05/10/24 04:49 99-87-605/09/24 21:375.8 1
Methylene Chloride ND ug/kg 05/10/24 04:49 75-09-205/09/24 21:3723.0 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 05/10/24 04:49 108-10-105/09/24 21:3757.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Sample:SB-21 (0-1)Lab ID:92730039007 Collected:05/07/24 14:35 Received:05/08/24 10:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Methyl-tert-butyl ether ND ug/kg 05/10/24 04:49 1634-04-405/09/24 21:375.8 1
Naphthalene ND ug/kg 05/10/24 04:49 91-20-305/09/24 21:375.8 1
n-Propylbenzene ND ug/kg 05/10/24 04:49 103-65-105/09/24 21:375.8 1
Styrene ND ug/kg 05/10/24 04:49 100-42-505/09/24 21:375.8 1
1,1,1,2-Tetrachloroethane ND ug/kg 05/10/24 04:49 630-20-605/09/24 21:375.8 1
1,1,2,2-Tetrachloroethane ND ug/kg 05/10/24 04:49 79-34-505/09/24 21:375.8 1
Tetrachloroethene ND ug/kg 05/10/24 04:49 127-18-405/09/24 21:375.8 1
Toluene ND ug/kg 05/10/24 04:49 108-88-305/09/24 21:375.8 1
1,2,3-Trichlorobenzene ND ug/kg 05/10/24 04:49 87-61-605/09/24 21:375.8 1
1,2,4-Trichlorobenzene ND ug/kg 05/10/24 04:49 120-82-105/09/24 21:375.8 1
1,1,1-Trichloroethane ND ug/kg 05/10/24 04:49 71-55-605/09/24 21:375.8 1
1,1,2-Trichloroethane ND ug/kg 05/10/24 04:49 79-00-505/09/24 21:375.8 1
Trichloroethene ND ug/kg 05/10/24 04:49 79-01-605/09/24 21:375.8 1
Trichlorofluoromethane ND ug/kg 05/10/24 04:49 75-69-405/09/24 21:375.8 1
1,2,3-Trichloropropane ND ug/kg 05/10/24 04:49 96-18-405/09/24 21:375.8 1
1,2,4-Trimethylbenzene ND ug/kg 05/10/24 04:49 95-63-605/09/24 21:375.8 1
1,3,5-Trimethylbenzene ND ug/kg 05/10/24 04:49 108-67-805/09/24 21:375.8 1
Vinyl acetate ND ug/kg 05/10/24 04:49 108-05-405/09/24 21:3757.6 1
Vinyl chloride ND ug/kg 05/10/24 04:49 75-01-405/09/24 21:3711.5 1
Xylene (Total)ND ug/kg 05/10/24 04:49 1330-20-705/09/24 21:3711.5 1
m&p-Xylene ND ug/kg 05/10/24 04:49 179601-23-105/09/24 21:3711.5 1
o-Xylene ND ug/kg 05/10/24 04:49 95-47-605/09/24 21:375.8 1
Surrogates
Toluene-d8 (S)101 %05/10/24 04:49 2037-26-505/09/24 21:3770-130 1
4-Bromofluorobenzene (S)101 %05/10/24 04:49 460-00-405/09/24 21:3770-130 1
1,2-Dichloroethane-d4 (S)106 %05/10/24 04:49 17060-07-005/09/24 21:3770-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 22.6 %05/10/24 10:41 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Sample:SB-21 (4-5)Lab ID:92730039008 Collected:05/07/24 14:40 Received:05/08/24 10:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone ND ug/kg 05/10/24 05:07 67-64-105/09/24 21:371411
Benzene ND ug/kg 05/10/24 05:07 71-43-205/09/24 21:377.1 1
Bromobenzene ND ug/kg 05/10/24 05:07 108-86-105/09/24 21:377.1 1
Bromochloromethane ND ug/kg 05/10/24 05:07 74-97-505/09/24 21:377.1 1
Bromodichloromethane ND ug/kg 05/10/24 05:07 75-27-405/09/24 21:377.1 1
Bromoform ND ug/kg 05/10/24 05:07 75-25-205/09/24 21:377.1 1
Bromomethane ND ug/kg 05/10/24 05:07 74-83-905/09/24 21:3728.3 1
2-Butanone (MEK)ND ug/kg 05/10/24 05:07 78-93-305/09/24 21:371411
n-Butylbenzene ND ug/kg 05/10/24 05:07 104-51-805/09/24 21:377.1 1
sec-Butylbenzene ND ug/kg 05/10/24 05:07 135-98-805/09/24 21:377.1 1
tert-Butylbenzene ND ug/kg 05/10/24 05:07 98-06-605/09/24 21:377.1 1
Carbon tetrachloride ND ug/kg 05/10/24 05:07 56-23-505/09/24 21:377.1 1
Chlorobenzene ND ug/kg 05/10/24 05:07 108-90-705/09/24 21:377.1 1
Chloroethane ND ug/kg 05/10/24 05:07 75-00-305/09/24 21:3714.1 1
Chloroform ND ug/kg 05/10/24 05:07 67-66-305/09/24 21:377.1 1
Chloromethane ND ug/kg 05/10/24 05:07 74-87-305/09/24 21:3714.1 1
2-Chlorotoluene ND ug/kg 05/10/24 05:07 95-49-805/09/24 21:377.1 1
4-Chlorotoluene ND ug/kg 05/10/24 05:07 106-43-405/09/24 21:377.1 1
1,2-Dibromo-3-chloropropane ND ug/kg 05/10/24 05:07 96-12-805/09/24 21:377.1 1
Dibromochloromethane ND ug/kg 05/10/24 05:07 124-48-105/09/24 21:377.1 1
1,2-Dibromoethane (EDB)ND ug/kg 05/10/24 05:07 106-93-405/09/24 21:377.1 1
Dibromomethane ND ug/kg 05/10/24 05:07 74-95-305/09/24 21:377.1 1
1,2-Dichlorobenzene ND ug/kg 05/10/24 05:07 95-50-105/09/24 21:377.1 1
1,3-Dichlorobenzene ND ug/kg 05/10/24 05:07 541-73-105/09/24 21:377.1 1
1,4-Dichlorobenzene ND ug/kg 05/10/24 05:07 106-46-705/09/24 21:377.1 1
Dichlorodifluoromethane ND ug/kg 05/10/24 05:07 75-71-8 IH05/09/24 21:3714.1 1
1,1-Dichloroethane ND ug/kg 05/10/24 05:07 75-34-305/09/24 21:377.1 1
1,2-Dichloroethane ND ug/kg 05/10/24 05:07 107-06-205/09/24 21:377.1 1
1,1-Dichloroethene ND ug/kg 05/10/24 05:07 75-35-405/09/24 21:377.1 1
cis-1,2-Dichloroethene ND ug/kg 05/10/24 05:07 156-59-205/09/24 21:377.1 1
trans-1,2-Dichloroethene ND ug/kg 05/10/24 05:07 156-60-505/09/24 21:377.1 1
1,2-Dichloropropane ND ug/kg 05/10/24 05:07 78-87-505/09/24 21:377.1 1
1,3-Dichloropropane ND ug/kg 05/10/24 05:07 142-28-905/09/24 21:377.1 1
2,2-Dichloropropane ND ug/kg 05/10/24 05:07 594-20-705/09/24 21:377.1 1
1,1-Dichloropropene ND ug/kg 05/10/24 05:07 563-58-605/09/24 21:377.1 1
cis-1,3-Dichloropropene ND ug/kg 05/10/24 05:07 10061-01-505/09/24 21:377.1 1
trans-1,3-Dichloropropene ND ug/kg 05/10/24 05:07 10061-02-605/09/24 21:377.1 1
Diisopropyl ether ND ug/kg 05/10/24 05:07 108-20-305/09/24 21:377.1 1
Ethylbenzene ND ug/kg 05/10/24 05:07 100-41-405/09/24 21:377.1 1
Hexachloro-1,3-butadiene ND ug/kg 05/10/24 05:07 87-68-305/09/24 21:3714.1 1
2-Hexanone ND ug/kg 05/10/24 05:07 591-78-605/09/24 21:3770.7 1
Isopropylbenzene (Cumene)ND ug/kg 05/10/24 05:07 98-82-805/09/24 21:377.1 1
p-Isopropyltoluene ND ug/kg 05/10/24 05:07 99-87-605/09/24 21:377.1 1
Methylene Chloride ND ug/kg 05/10/24 05:07 75-09-205/09/24 21:3728.3 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 05/10/24 05:07 108-10-105/09/24 21:3770.7 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Sample:SB-21 (4-5)Lab ID:92730039008 Collected:05/07/24 14:40 Received:05/08/24 10:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Methyl-tert-butyl ether ND ug/kg 05/10/24 05:07 1634-04-405/09/24 21:377.1 1
Naphthalene ND ug/kg 05/10/24 05:07 91-20-305/09/24 21:377.1 1
n-Propylbenzene ND ug/kg 05/10/24 05:07 103-65-105/09/24 21:377.1 1
Styrene ND ug/kg 05/10/24 05:07 100-42-505/09/24 21:377.1 1
1,1,1,2-Tetrachloroethane ND ug/kg 05/10/24 05:07 630-20-605/09/24 21:377.1 1
1,1,2,2-Tetrachloroethane ND ug/kg 05/10/24 05:07 79-34-505/09/24 21:377.1 1
Tetrachloroethene ND ug/kg 05/10/24 05:07 127-18-405/09/24 21:377.1 1
Toluene ND ug/kg 05/10/24 05:07 108-88-305/09/24 21:377.1 1
1,2,3-Trichlorobenzene ND ug/kg 05/10/24 05:07 87-61-605/09/24 21:377.1 1
1,2,4-Trichlorobenzene ND ug/kg 05/10/24 05:07 120-82-105/09/24 21:377.1 1
1,1,1-Trichloroethane ND ug/kg 05/10/24 05:07 71-55-605/09/24 21:377.1 1
1,1,2-Trichloroethane ND ug/kg 05/10/24 05:07 79-00-505/09/24 21:377.1 1
Trichloroethene ND ug/kg 05/10/24 05:07 79-01-605/09/24 21:377.1 1
Trichlorofluoromethane ND ug/kg 05/10/24 05:07 75-69-405/09/24 21:377.1 1
1,2,3-Trichloropropane ND ug/kg 05/10/24 05:07 96-18-405/09/24 21:377.1 1
1,2,4-Trimethylbenzene ND ug/kg 05/10/24 05:07 95-63-605/09/24 21:377.1 1
1,3,5-Trimethylbenzene ND ug/kg 05/10/24 05:07 108-67-805/09/24 21:377.1 1
Vinyl acetate ND ug/kg 05/10/24 05:07 108-05-405/09/24 21:3770.7 1
Vinyl chloride ND ug/kg 05/10/24 05:07 75-01-405/09/24 21:3714.1 1
Xylene (Total)ND ug/kg 05/10/24 05:07 1330-20-705/09/24 21:3714.1 1
m&p-Xylene ND ug/kg 05/10/24 05:07 179601-23-105/09/24 21:3714.1 1
o-Xylene ND ug/kg 05/10/24 05:07 95-47-605/09/24 21:377.1 1
Surrogates
Toluene-d8 (S)100 %05/10/24 05:07 2037-26-505/09/24 21:3770-130 1
4-Bromofluorobenzene (S)100 %05/10/24 05:07 460-00-405/09/24 21:3770-130 1
1,2-Dichloroethane-d4 (S)104 %05/10/24 05:07 17060-07-005/09/24 21:3770-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 17.2 %05/10/24 10:41 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Sample:SB-22 (0-1)Lab ID:92730039009 Collected:05/07/24 15:15 Received:05/08/24 10:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone ND ug/kg 05/10/24 05:25 67-64-105/09/24 21:371421
Benzene ND ug/kg 05/10/24 05:25 71-43-205/09/24 21:377.1 1
Bromobenzene ND ug/kg 05/10/24 05:25 108-86-105/09/24 21:377.1 1
Bromochloromethane ND ug/kg 05/10/24 05:25 74-97-505/09/24 21:377.1 1
Bromodichloromethane ND ug/kg 05/10/24 05:25 75-27-405/09/24 21:377.1 1
Bromoform ND ug/kg 05/10/24 05:25 75-25-205/09/24 21:377.1 1
Bromomethane ND ug/kg 05/10/24 05:25 74-83-905/09/24 21:3728.5 1
2-Butanone (MEK)ND ug/kg 05/10/24 05:25 78-93-305/09/24 21:371421
n-Butylbenzene ND ug/kg 05/10/24 05:25 104-51-805/09/24 21:377.1 1
sec-Butylbenzene ND ug/kg 05/10/24 05:25 135-98-805/09/24 21:377.1 1
tert-Butylbenzene ND ug/kg 05/10/24 05:25 98-06-605/09/24 21:377.1 1
Carbon tetrachloride ND ug/kg 05/10/24 05:25 56-23-505/09/24 21:377.1 1
Chlorobenzene ND ug/kg 05/10/24 05:25 108-90-705/09/24 21:377.1 1
Chloroethane ND ug/kg 05/10/24 05:25 75-00-305/09/24 21:3714.2 1
Chloroform ND ug/kg 05/10/24 05:25 67-66-305/09/24 21:377.1 1
Chloromethane ND ug/kg 05/10/24 05:25 74-87-305/09/24 21:3714.2 1
2-Chlorotoluene ND ug/kg 05/10/24 05:25 95-49-805/09/24 21:377.1 1
4-Chlorotoluene ND ug/kg 05/10/24 05:25 106-43-405/09/24 21:377.1 1
1,2-Dibromo-3-chloropropane ND ug/kg 05/10/24 05:25 96-12-805/09/24 21:377.1 1
Dibromochloromethane ND ug/kg 05/10/24 05:25 124-48-105/09/24 21:377.1 1
1,2-Dibromoethane (EDB)ND ug/kg 05/10/24 05:25 106-93-405/09/24 21:377.1 1
Dibromomethane ND ug/kg 05/10/24 05:25 74-95-305/09/24 21:377.1 1
1,2-Dichlorobenzene ND ug/kg 05/10/24 05:25 95-50-105/09/24 21:377.1 1
1,3-Dichlorobenzene ND ug/kg 05/10/24 05:25 541-73-105/09/24 21:377.1 1
1,4-Dichlorobenzene ND ug/kg 05/10/24 05:25 106-46-705/09/24 21:377.1 1
Dichlorodifluoromethane ND ug/kg 05/10/24 05:25 75-71-8 IH05/09/24 21:3714.2 1
1,1-Dichloroethane ND ug/kg 05/10/24 05:25 75-34-305/09/24 21:377.1 1
1,2-Dichloroethane ND ug/kg 05/10/24 05:25 107-06-205/09/24 21:377.1 1
1,1-Dichloroethene ND ug/kg 05/10/24 05:25 75-35-405/09/24 21:377.1 1
cis-1,2-Dichloroethene ND ug/kg 05/10/24 05:25 156-59-205/09/24 21:377.1 1
trans-1,2-Dichloroethene ND ug/kg 05/10/24 05:25 156-60-505/09/24 21:377.1 1
1,2-Dichloropropane ND ug/kg 05/10/24 05:25 78-87-505/09/24 21:377.1 1
1,3-Dichloropropane ND ug/kg 05/10/24 05:25 142-28-905/09/24 21:377.1 1
2,2-Dichloropropane ND ug/kg 05/10/24 05:25 594-20-705/09/24 21:377.1 1
1,1-Dichloropropene ND ug/kg 05/10/24 05:25 563-58-605/09/24 21:377.1 1
cis-1,3-Dichloropropene ND ug/kg 05/10/24 05:25 10061-01-505/09/24 21:377.1 1
trans-1,3-Dichloropropene ND ug/kg 05/10/24 05:25 10061-02-605/09/24 21:377.1 1
Diisopropyl ether ND ug/kg 05/10/24 05:25 108-20-305/09/24 21:377.1 1
Ethylbenzene ND ug/kg 05/10/24 05:25 100-41-405/09/24 21:377.1 1
Hexachloro-1,3-butadiene ND ug/kg 05/10/24 05:25 87-68-305/09/24 21:3714.2 1
2-Hexanone ND ug/kg 05/10/24 05:25 591-78-605/09/24 21:3771.2 1
Isopropylbenzene (Cumene)ND ug/kg 05/10/24 05:25 98-82-805/09/24 21:377.1 1
p-Isopropyltoluene ND ug/kg 05/10/24 05:25 99-87-605/09/24 21:377.1 1
Methylene Chloride ND ug/kg 05/10/24 05:25 75-09-205/09/24 21:3728.5 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 05/10/24 05:25 108-10-105/09/24 21:3771.2 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Sample:SB-22 (0-1)Lab ID:92730039009 Collected:05/07/24 15:15 Received:05/08/24 10:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Methyl-tert-butyl ether ND ug/kg 05/10/24 05:25 1634-04-405/09/24 21:377.1 1
Naphthalene ND ug/kg 05/10/24 05:25 91-20-305/09/24 21:377.1 1
n-Propylbenzene ND ug/kg 05/10/24 05:25 103-65-105/09/24 21:377.1 1
Styrene ND ug/kg 05/10/24 05:25 100-42-505/09/24 21:377.1 1
1,1,1,2-Tetrachloroethane ND ug/kg 05/10/24 05:25 630-20-605/09/24 21:377.1 1
1,1,2,2-Tetrachloroethane ND ug/kg 05/10/24 05:25 79-34-505/09/24 21:377.1 1
Tetrachloroethene 30.4 ug/kg 05/10/24 05:25 127-18-405/09/24 21:377.1 1
Toluene ND ug/kg 05/10/24 05:25 108-88-305/09/24 21:377.1 1
1,2,3-Trichlorobenzene ND ug/kg 05/10/24 05:25 87-61-605/09/24 21:377.1 1
1,2,4-Trichlorobenzene ND ug/kg 05/10/24 05:25 120-82-105/09/24 21:377.1 1
1,1,1-Trichloroethane ND ug/kg 05/10/24 05:25 71-55-605/09/24 21:377.1 1
1,1,2-Trichloroethane ND ug/kg 05/10/24 05:25 79-00-505/09/24 21:377.1 1
Trichloroethene ND ug/kg 05/10/24 05:25 79-01-605/09/24 21:377.1 1
Trichlorofluoromethane ND ug/kg 05/10/24 05:25 75-69-405/09/24 21:377.1 1
1,2,3-Trichloropropane ND ug/kg 05/10/24 05:25 96-18-405/09/24 21:377.1 1
1,2,4-Trimethylbenzene ND ug/kg 05/10/24 05:25 95-63-605/09/24 21:377.1 1
1,3,5-Trimethylbenzene ND ug/kg 05/10/24 05:25 108-67-805/09/24 21:377.1 1
Vinyl acetate ND ug/kg 05/10/24 05:25 108-05-405/09/24 21:3771.2 1
Vinyl chloride ND ug/kg 05/10/24 05:25 75-01-405/09/24 21:3714.2 1
Xylene (Total)ND ug/kg 05/10/24 05:25 1330-20-705/09/24 21:3714.2 1
m&p-Xylene ND ug/kg 05/10/24 05:25 179601-23-105/09/24 21:3714.2 1
o-Xylene ND ug/kg 05/10/24 05:25 95-47-605/09/24 21:377.1 1
Surrogates
Toluene-d8 (S)98 %05/10/24 05:25 2037-26-505/09/24 21:3770-130 1
4-Bromofluorobenzene (S)101 %05/10/24 05:25 460-00-405/09/24 21:3770-130 1
1,2-Dichloroethane-d4 (S)105 %05/10/24 05:25 17060-07-005/09/24 21:3770-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 21.1 %05/10/24 10:42 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Sample:SB-22 (3-4)Lab ID:92730039010 Collected:05/07/24 15:20 Received:05/08/24 10:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone ND ug/kg 05/10/24 05:44 67-64-105/09/24 21:371351
Benzene ND ug/kg 05/10/24 05:44 71-43-205/09/24 21:376.7 1
Bromobenzene ND ug/kg 05/10/24 05:44 108-86-105/09/24 21:376.7 1
Bromochloromethane ND ug/kg 05/10/24 05:44 74-97-505/09/24 21:376.7 1
Bromodichloromethane ND ug/kg 05/10/24 05:44 75-27-405/09/24 21:376.7 1
Bromoform ND ug/kg 05/10/24 05:44 75-25-205/09/24 21:376.7 1
Bromomethane ND ug/kg 05/10/24 05:44 74-83-905/09/24 21:3727.0 1
2-Butanone (MEK)ND ug/kg 05/10/24 05:44 78-93-305/09/24 21:371351
n-Butylbenzene ND ug/kg 05/10/24 05:44 104-51-805/09/24 21:376.7 1
sec-Butylbenzene ND ug/kg 05/10/24 05:44 135-98-805/09/24 21:376.7 1
tert-Butylbenzene ND ug/kg 05/10/24 05:44 98-06-605/09/24 21:376.7 1
Carbon tetrachloride ND ug/kg 05/10/24 05:44 56-23-505/09/24 21:376.7 1
Chlorobenzene ND ug/kg 05/10/24 05:44 108-90-705/09/24 21:376.7 1
Chloroethane ND ug/kg 05/10/24 05:44 75-00-305/09/24 21:3713.5 1
Chloroform ND ug/kg 05/10/24 05:44 67-66-305/09/24 21:376.7 1
Chloromethane ND ug/kg 05/10/24 05:44 74-87-305/09/24 21:3713.5 1
2-Chlorotoluene ND ug/kg 05/10/24 05:44 95-49-805/09/24 21:376.7 1
4-Chlorotoluene ND ug/kg 05/10/24 05:44 106-43-405/09/24 21:376.7 1
1,2-Dibromo-3-chloropropane ND ug/kg 05/10/24 05:44 96-12-805/09/24 21:376.7 1
Dibromochloromethane ND ug/kg 05/10/24 05:44 124-48-105/09/24 21:376.7 1
1,2-Dibromoethane (EDB)ND ug/kg 05/10/24 05:44 106-93-405/09/24 21:376.7 1
Dibromomethane ND ug/kg 05/10/24 05:44 74-95-305/09/24 21:376.7 1
1,2-Dichlorobenzene ND ug/kg 05/10/24 05:44 95-50-105/09/24 21:376.7 1
1,3-Dichlorobenzene ND ug/kg 05/10/24 05:44 541-73-105/09/24 21:376.7 1
1,4-Dichlorobenzene ND ug/kg 05/10/24 05:44 106-46-705/09/24 21:376.7 1
Dichlorodifluoromethane ND ug/kg 05/10/24 05:44 75-71-8 IH05/09/24 21:3713.5 1
1,1-Dichloroethane ND ug/kg 05/10/24 05:44 75-34-305/09/24 21:376.7 1
1,2-Dichloroethane ND ug/kg 05/10/24 05:44 107-06-205/09/24 21:376.7 1
1,1-Dichloroethene ND ug/kg 05/10/24 05:44 75-35-405/09/24 21:376.7 1
cis-1,2-Dichloroethene 285 ug/kg 05/10/24 05:44 156-59-205/09/24 21:376.7 1
trans-1,2-Dichloroethene ND ug/kg 05/10/24 05:44 156-60-505/09/24 21:376.7 1
1,2-Dichloropropane ND ug/kg 05/10/24 05:44 78-87-505/09/24 21:376.7 1
1,3-Dichloropropane ND ug/kg 05/10/24 05:44 142-28-905/09/24 21:376.7 1
2,2-Dichloropropane ND ug/kg 05/10/24 05:44 594-20-705/09/24 21:376.7 1
1,1-Dichloropropene ND ug/kg 05/10/24 05:44 563-58-605/09/24 21:376.7 1
cis-1,3-Dichloropropene ND ug/kg 05/10/24 05:44 10061-01-505/09/24 21:376.7 1
trans-1,3-Dichloropropene ND ug/kg 05/10/24 05:44 10061-02-605/09/24 21:376.7 1
Diisopropyl ether ND ug/kg 05/10/24 05:44 108-20-305/09/24 21:376.7 1
Ethylbenzene ND ug/kg 05/10/24 05:44 100-41-405/09/24 21:376.7 1
Hexachloro-1,3-butadiene ND ug/kg 05/10/24 05:44 87-68-305/09/24 21:3713.5 1
2-Hexanone ND ug/kg 05/10/24 05:44 591-78-605/09/24 21:3767.4 1
Isopropylbenzene (Cumene)ND ug/kg 05/10/24 05:44 98-82-805/09/24 21:376.7 1
p-Isopropyltoluene ND ug/kg 05/10/24 05:44 99-87-605/09/24 21:376.7 1
Methylene Chloride ND ug/kg 05/10/24 05:44 75-09-205/09/24 21:3727.0 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 05/10/24 05:44 108-10-105/09/24 21:3767.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Sample:SB-22 (3-4)Lab ID:92730039010 Collected:05/07/24 15:20 Received:05/08/24 10:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Methyl-tert-butyl ether ND ug/kg 05/10/24 05:44 1634-04-405/09/24 21:376.7 1
Naphthalene ND ug/kg 05/10/24 05:44 91-20-305/09/24 21:376.7 1
n-Propylbenzene ND ug/kg 05/10/24 05:44 103-65-105/09/24 21:376.7 1
Styrene ND ug/kg 05/10/24 05:44 100-42-505/09/24 21:376.7 1
1,1,1,2-Tetrachloroethane ND ug/kg 05/10/24 05:44 630-20-605/09/24 21:376.7 1
1,1,2,2-Tetrachloroethane ND ug/kg 05/10/24 05:44 79-34-505/09/24 21:376.7 1
Tetrachloroethene 3700 ug/kg 05/10/24 05:44 127-18-405/09/24 21:376.7 1
Toluene ND ug/kg 05/10/24 05:44 108-88-305/09/24 21:376.7 1
1,2,3-Trichlorobenzene ND ug/kg 05/10/24 05:44 87-61-605/09/24 21:376.7 1
1,2,4-Trichlorobenzene ND ug/kg 05/10/24 05:44 120-82-105/09/24 21:376.7 1
1,1,1-Trichloroethane ND ug/kg 05/10/24 05:44 71-55-605/09/24 21:376.7 1
1,1,2-Trichloroethane ND ug/kg 05/10/24 05:44 79-00-505/09/24 21:376.7 1
Trichloroethene 556 ug/kg 05/10/24 05:44 79-01-605/09/24 21:376.7 1
Trichlorofluoromethane ND ug/kg 05/10/24 05:44 75-69-405/09/24 21:376.7 1
1,2,3-Trichloropropane ND ug/kg 05/10/24 05:44 96-18-405/09/24 21:376.7 1
1,2,4-Trimethylbenzene ND ug/kg 05/10/24 05:44 95-63-605/09/24 21:376.7 1
1,3,5-Trimethylbenzene ND ug/kg 05/10/24 05:44 108-67-805/09/24 21:376.7 1
Vinyl acetate ND ug/kg 05/10/24 05:44 108-05-405/09/24 21:3767.4 1
Vinyl chloride 37.2 ug/kg 05/10/24 05:44 75-01-405/09/24 21:3713.5 1
Xylene (Total)ND ug/kg 05/10/24 05:44 1330-20-705/09/24 21:3713.5 1
m&p-Xylene ND ug/kg 05/10/24 05:44 179601-23-105/09/24 21:3713.5 1
o-Xylene ND ug/kg 05/10/24 05:44 95-47-605/09/24 21:376.7 1
Surrogates
Toluene-d8 (S)99 %05/10/24 05:44 2037-26-505/09/24 21:3770-130 1
4-Bromofluorobenzene (S)100 %05/10/24 05:44 460-00-405/09/24 21:3770-130 1
1,2-Dichloroethane-d4 (S)107 %05/10/24 05:44 17060-07-005/09/24 21:3770-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 22.0 %05/10/24 10:42 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Sample:SB-23 (0-1)Lab ID:92730039011 Collected:05/07/24 15:25 Received:05/08/24 10:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone ND ug/kg 05/10/24 06:02 67-64-105/09/24 21:371771
Benzene ND ug/kg 05/10/24 06:02 71-43-205/09/24 21:378.8 1
Bromobenzene ND ug/kg 05/10/24 06:02 108-86-105/09/24 21:378.8 1
Bromochloromethane ND ug/kg 05/10/24 06:02 74-97-505/09/24 21:378.8 1
Bromodichloromethane ND ug/kg 05/10/24 06:02 75-27-405/09/24 21:378.8 1
Bromoform ND ug/kg 05/10/24 06:02 75-25-205/09/24 21:378.8 1
Bromomethane ND ug/kg 05/10/24 06:02 74-83-905/09/24 21:3735.3 1
2-Butanone (MEK)ND ug/kg 05/10/24 06:02 78-93-305/09/24 21:371771
n-Butylbenzene ND ug/kg 05/10/24 06:02 104-51-805/09/24 21:378.8 1
sec-Butylbenzene ND ug/kg 05/10/24 06:02 135-98-805/09/24 21:378.8 1
tert-Butylbenzene ND ug/kg 05/10/24 06:02 98-06-605/09/24 21:378.8 1
Carbon tetrachloride ND ug/kg 05/10/24 06:02 56-23-505/09/24 21:378.8 1
Chlorobenzene ND ug/kg 05/10/24 06:02 108-90-705/09/24 21:378.8 1
Chloroethane ND ug/kg 05/10/24 06:02 75-00-305/09/24 21:3717.7 1
Chloroform ND ug/kg 05/10/24 06:02 67-66-305/09/24 21:378.8 1
Chloromethane ND ug/kg 05/10/24 06:02 74-87-305/09/24 21:3717.7 1
2-Chlorotoluene ND ug/kg 05/10/24 06:02 95-49-805/09/24 21:378.8 1
4-Chlorotoluene ND ug/kg 05/10/24 06:02 106-43-405/09/24 21:378.8 1
1,2-Dibromo-3-chloropropane ND ug/kg 05/10/24 06:02 96-12-805/09/24 21:378.8 1
Dibromochloromethane ND ug/kg 05/10/24 06:02 124-48-105/09/24 21:378.8 1
1,2-Dibromoethane (EDB)ND ug/kg 05/10/24 06:02 106-93-405/09/24 21:378.8 1
Dibromomethane ND ug/kg 05/10/24 06:02 74-95-305/09/24 21:378.8 1
1,2-Dichlorobenzene ND ug/kg 05/10/24 06:02 95-50-105/09/24 21:378.8 1
1,3-Dichlorobenzene ND ug/kg 05/10/24 06:02 541-73-105/09/24 21:378.8 1
1,4-Dichlorobenzene ND ug/kg 05/10/24 06:02 106-46-705/09/24 21:378.8 1
Dichlorodifluoromethane ND ug/kg 05/10/24 06:02 75-71-8 IH05/09/24 21:3717.7 1
1,1-Dichloroethane ND ug/kg 05/10/24 06:02 75-34-305/09/24 21:378.8 1
1,2-Dichloroethane ND ug/kg 05/10/24 06:02 107-06-205/09/24 21:378.8 1
1,1-Dichloroethene ND ug/kg 05/10/24 06:02 75-35-405/09/24 21:378.8 1
cis-1,2-Dichloroethene ND ug/kg 05/10/24 06:02 156-59-205/09/24 21:378.8 1
trans-1,2-Dichloroethene ND ug/kg 05/10/24 06:02 156-60-505/09/24 21:378.8 1
1,2-Dichloropropane ND ug/kg 05/10/24 06:02 78-87-505/09/24 21:378.8 1
1,3-Dichloropropane ND ug/kg 05/10/24 06:02 142-28-905/09/24 21:378.8 1
2,2-Dichloropropane ND ug/kg 05/10/24 06:02 594-20-705/09/24 21:378.8 1
1,1-Dichloropropene ND ug/kg 05/10/24 06:02 563-58-605/09/24 21:378.8 1
cis-1,3-Dichloropropene ND ug/kg 05/10/24 06:02 10061-01-505/09/24 21:378.8 1
trans-1,3-Dichloropropene ND ug/kg 05/10/24 06:02 10061-02-605/09/24 21:378.8 1
Diisopropyl ether ND ug/kg 05/10/24 06:02 108-20-305/09/24 21:378.8 1
Ethylbenzene ND ug/kg 05/10/24 06:02 100-41-405/09/24 21:378.8 1
Hexachloro-1,3-butadiene ND ug/kg 05/10/24 06:02 87-68-305/09/24 21:3717.7 1
2-Hexanone ND ug/kg 05/10/24 06:02 591-78-605/09/24 21:3788.3 1
Isopropylbenzene (Cumene)ND ug/kg 05/10/24 06:02 98-82-805/09/24 21:378.8 1
p-Isopropyltoluene ND ug/kg 05/10/24 06:02 99-87-605/09/24 21:378.8 1
Methylene Chloride ND ug/kg 05/10/24 06:02 75-09-205/09/24 21:3735.3 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 05/10/24 06:02 108-10-105/09/24 21:3788.3 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Sample:SB-23 (0-1)Lab ID:92730039011 Collected:05/07/24 15:25 Received:05/08/24 10:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Methyl-tert-butyl ether ND ug/kg 05/10/24 06:02 1634-04-405/09/24 21:378.8 1
Naphthalene ND ug/kg 05/10/24 06:02 91-20-305/09/24 21:378.8 1
n-Propylbenzene ND ug/kg 05/10/24 06:02 103-65-105/09/24 21:378.8 1
Styrene ND ug/kg 05/10/24 06:02 100-42-505/09/24 21:378.8 1
1,1,1,2-Tetrachloroethane ND ug/kg 05/10/24 06:02 630-20-605/09/24 21:378.8 1
1,1,2,2-Tetrachloroethane ND ug/kg 05/10/24 06:02 79-34-505/09/24 21:378.8 1
Tetrachloroethene ND ug/kg 05/10/24 06:02 127-18-405/09/24 21:378.8 1
Toluene ND ug/kg 05/10/24 06:02 108-88-305/09/24 21:378.8 1
1,2,3-Trichlorobenzene ND ug/kg 05/10/24 06:02 87-61-605/09/24 21:378.8 1
1,2,4-Trichlorobenzene ND ug/kg 05/10/24 06:02 120-82-105/09/24 21:378.8 1
1,1,1-Trichloroethane ND ug/kg 05/10/24 06:02 71-55-605/09/24 21:378.8 1
1,1,2-Trichloroethane ND ug/kg 05/10/24 06:02 79-00-505/09/24 21:378.8 1
Trichloroethene ND ug/kg 05/10/24 06:02 79-01-605/09/24 21:378.8 1
Trichlorofluoromethane ND ug/kg 05/10/24 06:02 75-69-405/09/24 21:378.8 1
1,2,3-Trichloropropane ND ug/kg 05/10/24 06:02 96-18-405/09/24 21:378.8 1
1,2,4-Trimethylbenzene ND ug/kg 05/10/24 06:02 95-63-605/09/24 21:378.8 1
1,3,5-Trimethylbenzene ND ug/kg 05/10/24 06:02 108-67-805/09/24 21:378.8 1
Vinyl acetate ND ug/kg 05/10/24 06:02 108-05-405/09/24 21:3788.3 1
Vinyl chloride ND ug/kg 05/10/24 06:02 75-01-405/09/24 21:3717.7 1
Xylene (Total)ND ug/kg 05/10/24 06:02 1330-20-705/09/24 21:3717.7 1
m&p-Xylene ND ug/kg 05/10/24 06:02 179601-23-105/09/24 21:3717.7 1
o-Xylene ND ug/kg 05/10/24 06:02 95-47-605/09/24 21:378.8 1
Surrogates
Toluene-d8 (S)101 %05/10/24 06:02 2037-26-505/09/24 21:3770-130 1
4-Bromofluorobenzene (S)101 %05/10/24 06:02 460-00-405/09/24 21:3770-130 1
1,2-Dichloroethane-d4 (S)107 %05/10/24 06:02 17060-07-005/09/24 21:3770-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 16.8 %05/10/24 11:22 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Sample:SB-23 (3-4)Lab ID:92730039012 Collected:05/07/24 15:30 Received:05/08/24 10:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone ND ug/kg 05/10/24 06:21 67-64-105/09/24 21:371331
Benzene ND ug/kg 05/10/24 06:21 71-43-205/09/24 21:376.7 1
Bromobenzene ND ug/kg 05/10/24 06:21 108-86-105/09/24 21:376.7 1
Bromochloromethane ND ug/kg 05/10/24 06:21 74-97-505/09/24 21:376.7 1
Bromodichloromethane ND ug/kg 05/10/24 06:21 75-27-405/09/24 21:376.7 1
Bromoform ND ug/kg 05/10/24 06:21 75-25-205/09/24 21:376.7 1
Bromomethane ND ug/kg 05/10/24 06:21 74-83-905/09/24 21:3726.6 1
2-Butanone (MEK)ND ug/kg 05/10/24 06:21 78-93-305/09/24 21:371331
n-Butylbenzene ND ug/kg 05/10/24 06:21 104-51-805/09/24 21:376.7 1
sec-Butylbenzene ND ug/kg 05/10/24 06:21 135-98-805/09/24 21:376.7 1
tert-Butylbenzene ND ug/kg 05/10/24 06:21 98-06-605/09/24 21:376.7 1
Carbon tetrachloride ND ug/kg 05/10/24 06:21 56-23-505/09/24 21:376.7 1
Chlorobenzene ND ug/kg 05/10/24 06:21 108-90-705/09/24 21:376.7 1
Chloroethane ND ug/kg 05/10/24 06:21 75-00-305/09/24 21:3713.3 1
Chloroform ND ug/kg 05/10/24 06:21 67-66-305/09/24 21:376.7 1
Chloromethane ND ug/kg 05/10/24 06:21 74-87-305/09/24 21:3713.3 1
2-Chlorotoluene ND ug/kg 05/10/24 06:21 95-49-805/09/24 21:376.7 1
4-Chlorotoluene ND ug/kg 05/10/24 06:21 106-43-405/09/24 21:376.7 1
1,2-Dibromo-3-chloropropane ND ug/kg 05/10/24 06:21 96-12-805/09/24 21:376.7 1
Dibromochloromethane ND ug/kg 05/10/24 06:21 124-48-105/09/24 21:376.7 1
1,2-Dibromoethane (EDB)ND ug/kg 05/10/24 06:21 106-93-405/09/24 21:376.7 1
Dibromomethane ND ug/kg 05/10/24 06:21 74-95-305/09/24 21:376.7 1
1,2-Dichlorobenzene ND ug/kg 05/10/24 06:21 95-50-105/09/24 21:376.7 1
1,3-Dichlorobenzene ND ug/kg 05/10/24 06:21 541-73-105/09/24 21:376.7 1
1,4-Dichlorobenzene ND ug/kg 05/10/24 06:21 106-46-705/09/24 21:376.7 1
Dichlorodifluoromethane ND ug/kg 05/10/24 06:21 75-71-8 IH05/09/24 21:3713.3 1
1,1-Dichloroethane ND ug/kg 05/10/24 06:21 75-34-305/09/24 21:376.7 1
1,2-Dichloroethane ND ug/kg 05/10/24 06:21 107-06-205/09/24 21:376.7 1
1,1-Dichloroethene ND ug/kg 05/10/24 06:21 75-35-405/09/24 21:376.7 1
cis-1,2-Dichloroethene ND ug/kg 05/10/24 06:21 156-59-205/09/24 21:376.7 1
trans-1,2-Dichloroethene ND ug/kg 05/10/24 06:21 156-60-505/09/24 21:376.7 1
1,2-Dichloropropane ND ug/kg 05/10/24 06:21 78-87-505/09/24 21:376.7 1
1,3-Dichloropropane ND ug/kg 05/10/24 06:21 142-28-905/09/24 21:376.7 1
2,2-Dichloropropane ND ug/kg 05/10/24 06:21 594-20-705/09/24 21:376.7 1
1,1-Dichloropropene ND ug/kg 05/10/24 06:21 563-58-605/09/24 21:376.7 1
cis-1,3-Dichloropropene ND ug/kg 05/10/24 06:21 10061-01-505/09/24 21:376.7 1
trans-1,3-Dichloropropene ND ug/kg 05/10/24 06:21 10061-02-605/09/24 21:376.7 1
Diisopropyl ether ND ug/kg 05/10/24 06:21 108-20-305/09/24 21:376.7 1
Ethylbenzene ND ug/kg 05/10/24 06:21 100-41-405/09/24 21:376.7 1
Hexachloro-1,3-butadiene ND ug/kg 05/10/24 06:21 87-68-305/09/24 21:3713.3 1
2-Hexanone ND ug/kg 05/10/24 06:21 591-78-605/09/24 21:3766.6 1
Isopropylbenzene (Cumene)ND ug/kg 05/10/24 06:21 98-82-805/09/24 21:376.7 1
p-Isopropyltoluene ND ug/kg 05/10/24 06:21 99-87-605/09/24 21:376.7 1
Methylene Chloride ND ug/kg 05/10/24 06:21 75-09-205/09/24 21:3726.6 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 05/10/24 06:21 108-10-105/09/24 21:3766.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Sample:SB-23 (3-4)Lab ID:92730039012 Collected:05/07/24 15:30 Received:05/08/24 10:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Methyl-tert-butyl ether ND ug/kg 05/10/24 06:21 1634-04-405/09/24 21:376.7 1
Naphthalene ND ug/kg 05/10/24 06:21 91-20-305/09/24 21:376.7 1
n-Propylbenzene ND ug/kg 05/10/24 06:21 103-65-105/09/24 21:376.7 1
Styrene ND ug/kg 05/10/24 06:21 100-42-505/09/24 21:376.7 1
1,1,1,2-Tetrachloroethane ND ug/kg 05/10/24 06:21 630-20-605/09/24 21:376.7 1
1,1,2,2-Tetrachloroethane ND ug/kg 05/10/24 06:21 79-34-505/09/24 21:376.7 1
Tetrachloroethene ND ug/kg 05/10/24 06:21 127-18-405/09/24 21:376.7 1
Toluene ND ug/kg 05/10/24 06:21 108-88-305/09/24 21:376.7 1
1,2,3-Trichlorobenzene ND ug/kg 05/10/24 06:21 87-61-605/09/24 21:376.7 1
1,2,4-Trichlorobenzene ND ug/kg 05/10/24 06:21 120-82-105/09/24 21:376.7 1
1,1,1-Trichloroethane ND ug/kg 05/10/24 06:21 71-55-605/09/24 21:376.7 1
1,1,2-Trichloroethane ND ug/kg 05/10/24 06:21 79-00-505/09/24 21:376.7 1
Trichloroethene ND ug/kg 05/10/24 06:21 79-01-605/09/24 21:376.7 1
Trichlorofluoromethane ND ug/kg 05/10/24 06:21 75-69-405/09/24 21:376.7 1
1,2,3-Trichloropropane ND ug/kg 05/10/24 06:21 96-18-405/09/24 21:376.7 1
1,2,4-Trimethylbenzene ND ug/kg 05/10/24 06:21 95-63-605/09/24 21:376.7 1
1,3,5-Trimethylbenzene ND ug/kg 05/10/24 06:21 108-67-805/09/24 21:376.7 1
Vinyl acetate ND ug/kg 05/10/24 06:21 108-05-405/09/24 21:3766.6 1
Vinyl chloride ND ug/kg 05/10/24 06:21 75-01-405/09/24 21:3713.3 1
Xylene (Total)ND ug/kg 05/10/24 06:21 1330-20-705/09/24 21:3713.3 1
m&p-Xylene ND ug/kg 05/10/24 06:21 179601-23-105/09/24 21:3713.3 1
o-Xylene ND ug/kg 05/10/24 06:21 95-47-605/09/24 21:376.7 1
Surrogates
Toluene-d8 (S)102 %05/10/24 06:21 2037-26-505/09/24 21:3770-130 1
4-Bromofluorobenzene (S)102 %05/10/24 06:21 460-00-405/09/24 21:3770-130 1
1,2-Dichloroethane-d4 (S)109 %05/10/24 06:21 17060-07-005/09/24 21:3770-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 19.6 %05/10/24 11:23 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 42
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
853559
EPA 5035A/5030B
EPA 8260D
8260D 5035A 5030B
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92730039001, 92730039002, 92730039003, 92730039004, 92730039005, 92730039006, 92730039007,
92730039008, 92730039009, 92730039010, 92730039011, 92730039012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4404738
Associated Lab Samples:92730039001, 92730039002, 92730039003, 92730039004, 92730039005, 92730039006, 92730039007,
92730039008, 92730039009, 92730039010, 92730039011, 92730039012
Matrix:Solid
Analyzed
1,1,1,2-Tetrachloroethane ug/kg ND 5.0 05/09/24 23:00
1,1,1-Trichloroethane ug/kg ND 5.0 05/09/24 23:00
1,1,2,2-Tetrachloroethane ug/kg ND 5.0 05/09/24 23:00
1,1,2-Trichloroethane ug/kg ND 5.0 05/09/24 23:00
1,1-Dichloroethane ug/kg ND 5.0 05/09/24 23:00
1,1-Dichloroethene ug/kg ND 5.0 05/09/24 23:00
1,1-Dichloropropene ug/kg ND 5.0 05/09/24 23:00
1,2,3-Trichlorobenzene ug/kg ND 5.0 05/09/24 23:00
1,2,3-Trichloropropane ug/kg ND 5.0 05/09/24 23:00
1,2,4-Trichlorobenzene ug/kg ND 5.0 05/09/24 23:00
1,2,4-Trimethylbenzene ug/kg ND 5.0 05/09/24 23:00
1,2-Dibromo-3-chloropropane ug/kg ND 5.0 05/09/24 23:00
1,2-Dibromoethane (EDB)ug/kg ND 5.0 05/09/24 23:00
1,2-Dichlorobenzene ug/kg ND 5.0 05/09/24 23:00
1,2-Dichloroethane ug/kg ND 5.0 05/09/24 23:00
1,2-Dichloropropane ug/kg ND 5.0 05/09/24 23:00
1,3,5-Trimethylbenzene ug/kg ND 5.0 05/09/24 23:00
1,3-Dichlorobenzene ug/kg ND 5.0 05/09/24 23:00
1,3-Dichloropropane ug/kg ND 5.0 05/09/24 23:00
1,4-Dichlorobenzene ug/kg ND 5.0 05/09/24 23:00
2,2-Dichloropropane ug/kg ND 5.0 05/09/24 23:00
2-Butanone (MEK)ug/kg ND 100 05/09/24 23:00
2-Chlorotoluene ug/kg ND 5.0 05/09/24 23:00
2-Hexanone ug/kg ND 50.0 05/09/24 23:00
4-Chlorotoluene ug/kg ND 5.0 05/09/24 23:00
4-Methyl-2-pentanone (MIBK)ug/kg ND 50.0 05/09/24 23:00
Acetone ug/kg ND 100 05/09/24 23:00
Benzene ug/kg ND 5.0 05/09/24 23:00
Bromobenzene ug/kg ND 5.0 05/09/24 23:00
Bromochloromethane ug/kg ND 5.0 05/09/24 23:00
Bromodichloromethane ug/kg ND 5.0 05/09/24 23:00
Bromoform ug/kg ND 5.0 05/09/24 23:00
Bromomethane ug/kg ND 20.0 05/09/24 23:00
Carbon tetrachloride ug/kg ND 5.0 05/09/24 23:00
Chlorobenzene ug/kg ND 5.0 05/09/24 23:00
Chloroethane ug/kg ND 10.0 05/09/24 23:00
Chloroform ug/kg ND 5.0 05/09/24 23:00
Chloromethane ug/kg ND 10.0 05/09/24 23:00
cis-1,2-Dichloroethene ug/kg ND 5.0 05/09/24 23:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 42
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4404738
Associated Lab Samples:92730039001, 92730039002, 92730039003, 92730039004, 92730039005, 92730039006, 92730039007,
92730039008, 92730039009, 92730039010, 92730039011, 92730039012
Matrix:Solid
Analyzed
cis-1,3-Dichloropropene ug/kg ND 5.0 05/09/24 23:00
Dibromochloromethane ug/kg ND 5.0 05/09/24 23:00
Dibromomethane ug/kg ND 5.0 05/09/24 23:00
Dichlorodifluoromethane ug/kg ND 10.0 IH05/09/24 23:00
Diisopropyl ether ug/kg ND 5.0 05/09/24 23:00
Ethylbenzene ug/kg ND 5.0 05/09/24 23:00
Hexachloro-1,3-butadiene ug/kg ND 10.0 05/09/24 23:00
Isopropylbenzene (Cumene)ug/kg ND 5.0 05/09/24 23:00
m&p-Xylene ug/kg ND 10.0 05/09/24 23:00
Methyl-tert-butyl ether ug/kg ND 5.0 05/09/24 23:00
Methylene Chloride ug/kg ND 20.0 05/09/24 23:00
n-Butylbenzene ug/kg ND 5.0 05/09/24 23:00
n-Propylbenzene ug/kg ND 5.0 05/09/24 23:00
Naphthalene ug/kg ND 5.0 05/09/24 23:00
o-Xylene ug/kg ND 5.0 05/09/24 23:00
p-Isopropyltoluene ug/kg ND 5.0 05/09/24 23:00
sec-Butylbenzene ug/kg ND 5.0 05/09/24 23:00
Styrene ug/kg ND 5.0 05/09/24 23:00
tert-Butylbenzene ug/kg ND 5.0 05/09/24 23:00
Tetrachloroethene ug/kg ND 5.0 05/09/24 23:00
Toluene ug/kg ND 5.0 05/09/24 23:00
trans-1,2-Dichloroethene ug/kg ND 5.0 05/09/24 23:00
trans-1,3-Dichloropropene ug/kg ND 5.0 05/09/24 23:00
Trichloroethene ug/kg ND 5.0 05/09/24 23:00
Trichlorofluoromethane ug/kg ND 5.0 05/09/24 23:00
Vinyl acetate ug/kg ND 50.0 05/09/24 23:00
Vinyl chloride ug/kg ND 10.0 05/09/24 23:00
Xylene (Total)ug/kg ND 10.0 05/09/24 23:00
1,2-Dichloroethane-d4 (S)%115 70-130 05/09/24 23:00
4-Bromofluorobenzene (S)%99 70-130 05/09/24 23:00
Toluene-d8 (S)%102 70-130 05/09/24 23:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4404739LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/kg 467500 93 70-130
1,1,1-Trichloroethane ug/kg 470500 94 70-130
1,1,2,2-Tetrachloroethane ug/kg 442500 88 70-130
1,1,2-Trichloroethane ug/kg 438500 88 70-130
1,1-Dichloroethane ug/kg 485500 97 70-130
1,1-Dichloroethene ug/kg 474500 95 70-132
1,1-Dichloropropene ug/kg 457500 91 70-130
1,2,3-Trichlorobenzene ug/kg 437500 87 62-136
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 42
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4404739LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,3-Trichloropropane ug/kg 450500 90 70-130
1,2,4-Trichlorobenzene ug/kg 448500 90 70-130
1,2,4-Trimethylbenzene ug/kg 475500 95 70-130
1,2-Dibromo-3-chloropropane ug/kg 460500 92 65-130
1,2-Dibromoethane (EDB)ug/kg 441500 88 70-130
1,2-Dichlorobenzene ug/kg 429500 86 70-130
1,2-Dichloroethane ug/kg 464500 93 70-130
1,2-Dichloropropane ug/kg 466500 93 70-130
1,3,5-Trimethylbenzene ug/kg 438500 88 70-130
1,3-Dichlorobenzene ug/kg 453500 91 70-130
1,3-Dichloropropane ug/kg 439500 88 70-130
1,4-Dichlorobenzene ug/kg 407500 81 70-130
2,2-Dichloropropane ug/kg 468500 94 60-130
2-Butanone (MEK)ug/kg 9151000 92 66-130
2-Chlorotoluene ug/kg 450500 90 70-130
2-Hexanone ug/kg 8851000 89 68-130
4-Chlorotoluene ug/kg 472500 94 70-130
4-Methyl-2-pentanone (MIBK)ug/kg 8911000 89 70-130
Acetone ug/kg 8921000 89 60-130
Benzene ug/kg 457500 91 70-130
Bromobenzene ug/kg 451500 90 70-130
Bromochloromethane ug/kg 500500 100 70-130
Bromodichloromethane ug/kg 461500 92 70-130
Bromoform ug/kg 438500 88 70-130
Bromomethane ug/kg 522500 104 43-175
Carbon tetrachloride ug/kg 450500 90 70-130
Chlorobenzene ug/kg 466500 93 70-130
Chloroethane ug/kg 452500 90 70-145
Chloroform ug/kg 456500 91 70-130
Chloromethane ug/kg 548500 110 66-146
cis-1,2-Dichloroethene ug/kg 462500 92 70-130
cis-1,3-Dichloropropene ug/kg 432500 86 70-130
Dibromochloromethane ug/kg 471500 94 70-130
Dibromomethane ug/kg 457500 91 70-130
Dichlorodifluoromethane ug/kg 560 IH50011242-197
Diisopropyl ether ug/kg 466500 93 68-130
Ethylbenzene ug/kg 441500 88 70-130
Hexachloro-1,3-butadiene ug/kg 450500 90 70-130
Isopropylbenzene (Cumene)ug/kg 464500 93 70-130
m&p-Xylene ug/kg 9231000 92 70-130
Methyl-tert-butyl ether ug/kg 458500 92 70-130
Methylene Chloride ug/kg 489500 98 65-130
n-Butylbenzene ug/kg 469500 94 70-130
n-Propylbenzene ug/kg 469500 94 70-130
Naphthalene ug/kg 461500 92 65-135
o-Xylene ug/kg 460500 92 70-130
p-Isopropyltoluene ug/kg 455500 91 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 42
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4404739LABORATORY CONTROL SAMPLE:
LCSSpike
sec-Butylbenzene ug/kg 462500 92 70-130
Styrene ug/kg 470500 94 70-130
tert-Butylbenzene ug/kg 461500 92 70-130
Tetrachloroethene ug/kg 434500 87 70-130
Toluene ug/kg 456500 91 70-130
trans-1,2-Dichloroethene ug/kg 480500 96 70-130
trans-1,3-Dichloropropene ug/kg 444500 89 70-130
Trichloroethene ug/kg 466500 93 70-130
Trichlorofluoromethane ug/kg 469500 94 62-140
Vinyl acetate ug/kg 9701000 97 70-140
Vinyl chloride ug/kg 543500 109 70-152
Xylene (Total)ug/kg 13801500 92 70-130
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
4404740MATRIX SPIKE SAMPLE:
MSSpike
Result
92730036001
1,1,1,2-Tetrachloroethane ug/kg 13401260 106 22-166ND
1,1,1-Trichloroethane ug/kg 13901260 110 23-172ND
1,1,2,2-Tetrachloroethane ug/kg 12001260 95 21-158ND
1,1,2-Trichloroethane ug/kg 12101260 96 25-160ND
1,1-Dichloroethane ug/kg 14001260 111 22-166ND
1,1-Dichloroethene ug/kg 14501260 115 18-183ND
1,1-Dichloropropene ug/kg 13401260 106 20-181ND
1,2,3-Trichlorobenzene ug/kg 4241260 34 10-161ND
1,2,3-Trichloropropane ug/kg 11701260 93 21-147ND
1,2,4-Trichlorobenzene ug/kg 7711260 61 10-159ND
1,2,4-Trimethylbenzene ug/kg 12801260 101 17-170ND
1,2-Dibromo-3-chloropropane ug/kg 8591260 68 10-135ND
1,2-Dibromoethane (EDB)ug/kg 12301260 97 30-154ND
1,2-Dichlorobenzene ug/kg 11901260 95 26-162ND
1,2-Dichloroethane ug/kg 13401260 106 23-161ND
1,2-Dichloropropane ug/kg 13901260 110 29-165ND
1,3,5-Trimethylbenzene ug/kg 12201260 96 20-172ND
1,3-Dichlorobenzene ug/kg 13301260 106 22-164ND
1,3-Dichloropropane ug/kg 12401260 99 27-156ND
1,4-Dichlorobenzene ug/kg 11001260 87 20-161ND
2,2-Dichloropropane ug/kg 13101260 103 10-159ND
2-Butanone (MEK)ug/kg 19602520 78 13-143ND
2-Chlorotoluene ug/kg 12501260 99 21-166ND
2-Hexanone ug/kg 19602520 78 19-145ND
4-Chlorotoluene ug/kg 12301260 98 19-163ND
4-Methyl-2-pentanone (MIBK)ug/kg 23802520 94 21-151ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 42
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
4404740MATRIX SPIKE SAMPLE:
MSSpike
Result
92730036001
Acetone ug/kg 17802520 64 10-133165J
Benzene ug/kg 13101260 104 29-156ND
Bromobenzene ug/kg 12401260 98 25-161ND
Bromochloromethane ug/kg 14201260 112 27-158ND
Bromodichloromethane ug/kg 13101260 104 23-158ND
Bromoform ug/kg 11901260 94 19-152ND
Bromomethane ug/kg 8851260 70 10-152ND
Carbon tetrachloride ug/kg 11401260 90 18-172ND
Chlorobenzene ug/kg 13101260 104 26-166ND
Chloroethane ug/kg 10001260 80 10-130ND
Chloroform ug/kg 12901260 103 25-161ND
Chloromethane ug/kg 17001260 135 27-197ND
cis-1,2-Dichloroethene ug/kg 13601260 108 28-165ND
cis-1,3-Dichloropropene ug/kg 12501260 99 23-159ND
Dibromochloromethane ug/kg 13001260 103 21-151ND
Dibromomethane ug/kg 13201260 105 38-158ND
Dichlorodifluoromethane ug/kg 1720 IH126013610-200ND
Diisopropyl ether ug/kg 13501260 107 23-160ND
Ethylbenzene ug/kg 12801260 101 22-163ND
Hexachloro-1,3-butadiene ug/kg 12301260 97 10-192ND
Isopropylbenzene (Cumene)ug/kg 13501260 107 24-173ND
m&p-Xylene ug/kg 26502520 105 22-171ND
Methyl-tert-butyl ether ug/kg 12601260 100 25-153ND
Methylene Chloride ug/kg 15201260 120 10-165ND
n-Butylbenzene ug/kg 12601260 100 10-186ND
n-Propylbenzene ug/kg 12601260 100 16-171ND
Naphthalene ug/kg 4321260 34 10-159ND
o-Xylene ug/kg 13401260 106 23-171ND
p-Isopropyltoluene ug/kg 12601260 100 13-184ND
sec-Butylbenzene ug/kg 12901260 102 16-182ND
Styrene ug/kg 13101260 103 25-169ND
tert-Butylbenzene ug/kg 9621260 76 20-174ND
Tetrachloroethene ug/kg 11401260 90 14-171ND
Toluene ug/kg 13401260 106 24-166ND
trans-1,2-Dichloroethene ug/kg 13301260 105 24-170ND
trans-1,3-Dichloropropene ug/kg 12601260 100 22-157ND
Trichloroethene ug/kg 13901260 110 23-176ND
Trichlorofluoromethane ug/kg 14501260 115 10-138ND
Vinyl acetate ug/kg 26302520 104 11-166ND
Vinyl chloride ug/kg 13701260 109 21-200ND
Xylene (Total)ug/kg 39803790 105 23-170ND
1,2-Dichloroethane-d4 (S)%114 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 42
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result QualifiersRPDResult
92729643004
4404741SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/kg NDND
1,1,1-Trichloroethane ug/kg NDND
1,1,2,2-Tetrachloroethane ug/kg NDND
1,1,2-Trichloroethane ug/kg NDND
1,1-Dichloroethane ug/kg NDND
1,1-Dichloroethene ug/kg NDND
1,1-Dichloropropene ug/kg NDND
1,2,3-Trichlorobenzene ug/kg NDND
1,2,3-Trichloropropane ug/kg NDND
1,2,4-Trichlorobenzene ug/kg NDND
1,2,4-Trimethylbenzene ug/kg 136 6128
1,2-Dibromo-3-chloropropane ug/kg NDND
1,2-Dibromoethane (EDB)ug/kg NDND
1,2-Dichlorobenzene ug/kg NDND
1,2-Dichloroethane ug/kg NDND
1,2-Dichloropropane ug/kg NDND
1,3,5-Trimethylbenzene ug/kg 40.0 239.2
1,3-Dichlorobenzene ug/kg NDND
1,3-Dichloropropane ug/kg NDND
1,4-Dichlorobenzene ug/kg NDND
2,2-Dichloropropane ug/kg NDND
2-Butanone (MEK)ug/kg NDND
2-Chlorotoluene ug/kg NDND
2-Hexanone ug/kg NDND
4-Chlorotoluene ug/kg NDND
4-Methyl-2-pentanone (MIBK)ug/kg NDND
Acetone ug/kg NDND
Benzene ug/kg NDND
Bromobenzene ug/kg NDND
Bromochloromethane ug/kg NDND
Bromodichloromethane ug/kg NDND
Bromoform ug/kg NDND
Bromomethane ug/kg NDND
Carbon tetrachloride ug/kg NDND
Chlorobenzene ug/kg NDND
Chloroethane ug/kg NDND
Chloroform ug/kg NDND
Chloromethane ug/kg NDND
cis-1,2-Dichloroethene ug/kg NDND
cis-1,3-Dichloropropene ug/kg NDND
Dibromochloromethane ug/kg NDND
Dibromomethane ug/kg NDND
Dichlorodifluoromethane ug/kg ND IHND
Diisopropyl ether ug/kg NDND
Ethylbenzene ug/kg NDND
Hexachloro-1,3-butadiene ug/kg NDND
Isopropylbenzene (Cumene)ug/kg 6.8JND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 42
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result QualifiersRPDResult
92729643004
4404741SAMPLE DUPLICATE:
m&p-Xylene ug/kg 97.6 394.8
Methyl-tert-butyl ether ug/kg NDND
Methylene Chloride ug/kg NDND
n-Butylbenzene ug/kg 12.4 511.7
n-Propylbenzene ug/kg NDND
Naphthalene ug/kg 9.6ND
o-Xylene ug/kg 28.8 726.9
p-Isopropyltoluene ug/kg NDND
sec-Butylbenzene ug/kg NDND
Styrene ug/kg NDND
tert-Butylbenzene ug/kg NDND
Tetrachloroethene ug/kg NDND
Toluene ug/kg 26.2 325.4
trans-1,2-Dichloroethene ug/kg NDND
trans-1,3-Dichloropropene ug/kg NDND
Trichloroethene ug/kg NDND
Trichlorofluoromethane ug/kg NDND
Vinyl acetate ug/kg NDND
Vinyl chloride ug/kg NDND
Xylene (Total)ug/kg 126 4122
1,2-Dichloroethane-d4 (S)%103111
4-Bromofluorobenzene (S)%9999
Toluene-d8 (S)%100103
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 42
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
853660
SW-846
SW-846
Dry Weight/Percent Moisture
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92730039001, 92730039002, 92730039003, 92730039004, 92730039005, 92730039006, 92730039007,
92730039008, 92730039009, 92730039010
Parameter Units
Dup
Result QualifiersRPDResult
92730000001
4405061SAMPLE DUPLICATE:
Percent Moisture %23.7 N21221.0
Parameter Units
Dup
Result QualifiersRPDResult
92730039010
4405062SAMPLE DUPLICATE:
Percent Moisture %20.6 N2722.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 42
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
853672
SW-846
SW-846
Dry Weight/Percent Moisture
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92730039011, 92730039012
Parameter Units
Dup
Result QualifiersRPDResult
92729821001
4405130SAMPLE DUPLICATE:
Percent Moisture %84.3 N2084.0
Parameter Units
Dup
Result QualifiersRPDResult
92728333004
4405131SAMPLE DUPLICATE:
Percent Moisture %80.0 N2080.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 42
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be
considered an estimated value.IH
The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.N2
Surrogate recovery outside control limits due to matrix interferences (not confirmed by re-analysis).S5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 42
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92730039
Carolina Cleaners DC680016
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92730039001 853559 853619SB-18 (0-1)EPA 5035A/5030B EPA 8260D
92730039002 853559 853619SB-18 (3-4)EPA 5035A/5030B EPA 8260D
92730039003 853559 853619SB-19 (0-1)EPA 5035A/5030B EPA 8260D
92730039004 853559 853619SB-19 (1-2)EPA 5035A/5030B EPA 8260D
92730039005 853559 853619SB-20 (0-1)EPA 5035A/5030B EPA 8260D
92730039006 853559 853619SB-20 (4-5)EPA 5035A/5030B EPA 8260D
92730039007 853559 853619SB-21 (0-1)EPA 5035A/5030B EPA 8260D
92730039008 853559 853619SB-21 (4-5)EPA 5035A/5030B EPA 8260D
92730039009 853559 853619SB-22 (0-1)EPA 5035A/5030B EPA 8260D
92730039010 853559 853619SB-22 (3-4)EPA 5035A/5030B EPA 8260D
92730039011 853559 853619SB-23 (0-1)EPA 5035A/5030B EPA 8260D
92730039012 853559 853619SB-23 (3-4)EPA 5035A/5030B EPA 8260D
92730039001 853660SB-18 (0-1)SW-846
92730039002 853660SB-18 (3-4)SW-846
92730039003 853660SB-19 (0-1)SW-846
92730039004 853660SB-19 (1-2)SW-846
92730039005 853660SB-20 (0-1)SW-846
92730039006 853660SB-20 (4-5)SW-846
92730039007 853660SB-21 (0-1)SW-846
92730039008 853660SB-21 (4-5)SW-846
92730039009 853660SB-22 (0-1)SW-846
92730039010 853660SB-22 (3-4)SW-846
92730039011 853672SB-23 (0-1)SW-846
92730039012 853672SB-23 (3-4)SW-846
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/14/2024 09:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 42
Page 39 of 42
Page 40 of 42
Page 41 of 42
Page 42 of 42
AECOM - Morrisville
1600 Perimeter Park Drive, Suite 400
Morrisville, NC 27560

Carolina Cleaners (DC680016)
Client Project# 60731175

Analytical Report
(0524-035)

EPA Method TO-15
DSCA5 Target Compound List

Enthalpy Analytical, LLC
Phone: (919) 850 - 4392 / Fax: (919) 850 - 9012 / www.enthalpy.com
800-1 Capitola Drive Durham, NC 27713-4385
I certify that to the best of my knowledge all analytical data presented in this report:
Have been checked for completeness
Are accurate, error-free, and legible
Have been conducted in accordance with approved protocol, and that all deviations and
analytical problems are summarized in the appropriate narrative(s)
This analytical report was prepared in Portable Document Format (.PDF). This report shall not be
reproduced except in full without approval of the laboratory. This will provide assurance that parts of a
report are not taken out of context.
Report Issued: 7/8/24
EA Job# 0524-035 Page 2 of 20

Results
EA Job# 0524-035 Page 3 of 20
Sample Name
Sample Info.
Sampling Date
Received Date
Sample Type
Batch
Data File
Dilution
Pressurization Factor
Acquisition Date
Instrument Method
Matrix
Analyst
Instrument
Enthalpy ID
Target Compound Concentration
(ppbv)
RL
(ppbv)
MDL
(ppbv)
Concentration
(ug/m³)
RL
(ug/m³)
MDL
(ug/m³)
Flags
Chloroethene (Vinyl chloride)0.653 0.104 0.0910 1.67 0.266 0.233 m
trans-1,2-Dichloroethene 0.117 0.106 0.0910 0.462 0.420 0.361
cis-1,2-Dichloroethene 0.272 0.105 0.0910 1.08 0.416 0.361 m
Trichloroethene 0.352 0.105 0.0910 1.89 0.565 0.489
Tetrachloroethene 20.0 0.106 0.0910 136 0.721 0.617
Compound Response Retention
Time (min)
Concentration
(ppbv)
Flag
Bromochloromethane (IS)832,381 11.02 5.21 pass
1,4-Difluorobenzene (IS)3,198,991 12.44 5.16 pass
Chlorobenzene-d5 (IS)2,643,490 16.57 4.92 pass
(ND) = Not Detected
(J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration
IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40%
Air
TDD
Xavier
0524-035.SG-5.Can
X2402942.D
1.000
2.601
2024-06-25 11:25
TO15_SCNV6.M
0524-035; 500mL load; Can #C18036; MP2
2024-06-20 13:15
2024-06-24 00:00
Sample
Xavier_X062424A_0524-035.v1
Enthalpy Analytical
Job No.: 0524-035-1 EPA Method TO-15 Analysis -- Run
AECOM - Morrisville 60731175 Carolina Cleaners DC680016
SG-5
EA Job# 0524-035 Page 4 of 20
Sample Name
Sample Info.
Sampling Date
Received Date
Sample Type
Batch
Data File
Dilution
Pressurization Factor
Acquisition Date
Instrument Method
Matrix
Analyst
Instrument
Enthalpy ID
Target Compound Concentration
(ppbv)
RL
(ppbv)
MDL
(ppbv)
Concentration
(ug/m³)
RL
(ug/m³)
MDL
(ug/m³)
Flags
Chloroethene (Vinyl chloride)20.0 0.0983 0.0861 51.1 0.251 0.220
Compound Response Retention
Time (min)
Concentration
(ppbv)
Flag
Bromochloromethane (IS)896,998 11.02 5.21 pass
(ND) = Not Detected
(J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration
IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40%
Air
TDD
Xavier
0524-035.SG-6.Can
X2402945.D
1.000
2.460
2024-06-25 14:33
TO15_SCNV6.M
0524-035; 500mL load; Can #C10111; MP3
2024-06-20 13:32
2024-06-24 00:00
Sample
Xavier_X062424A_0524-035.v1
Enthalpy Analytical
Job No.: 0524-035-1 EPA Method TO-15 Analysis -- Run
AECOM - Morrisville 60731175 Carolina Cleaners DC680016
SG-6
EA Job# 0524-035 Page 5 of 20
Sample Name
Sample Info.
Sampling Date
Received Date
Sample Type
Batch
Data File
Dilution
Pressurization Factor
Acquisition Date
Instrument Method
Matrix
Analyst
Instrument
Enthalpy ID
Target Compound Concentration
(ppbv)
RL
(ppbv)
MDL
(ppbv)
Concentration
(ug/m³)
RL
(ug/m³)
MDL
(ug/m³)
Flags
trans-1,2-Dichloroethene 457 5.02 4.30 1,810 19.9 17.1
cis-1,2-Dichloroethene 864 4.97 4.30 3,425 19.7 17.1
Trichloroethene 3,386 4.97 4.30 18,187 26.7 23.1
Tetrachloroethene 1,179 5.03 4.30 7,988 34.1 29.2
Compound Response Retention
Time (min)
Concentration
(ppbv)
Flag
Bromochloromethane (IS)899,253 11.02 5.21 pass
1,4-Difluorobenzene (IS)3,449,419 12.44 5.16 pass
Chlorobenzene-d5 (IS)2,943,667 16.57 4.92 pass
(ND) = Not Detected
(J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration
IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40%
Air
TDD
Xavier
0524-035.SG-6.Can
X2402947.D
50.000
2.460
2024-06-25 16:05
TO15_SCNV6.M
0524-035; *50=10mL load; Can #C10111; MP3
2024-06-20 13:32
2024-06-24 00:00
Sample
Xavier_X062424A_0524-035.v1
Enthalpy Analytical
Job No.: 0524-035-1 EPA Method TO-15 Analysis -- Run
AECOM - Morrisville 60731175 Carolina Cleaners DC680016
SG-6
EA Job# 0524-035 Page 6 of 20
Job No.
Company
Site
Can Number C18036 C10111
Job 0524-035 0524-035
Sample ID SG-5 SG-6
CleanDate 03/05/2024 03/20/2024
LeakCheckDate 03/05/2024 03/24/2024
LeakCheckAnalyst buddhikaranawella pamooney
BlankCheckRef X2401145 X2401356
Weather Station ID 97 97
Weather Station Exp.08/24/2025 08/24/2025
Transducer ID 3 3
Transducer Exp.11/17/2024 11/17/2024
Can Size (L)1.4 6
Evac Temp (F)66.8 69.6
Evac Pbar (mmHg)762.0 755.7
Evac Gauge (mmHg)-762.0 -755.7
Evac Analyst buddhikaranawella pamooney
Evac Time 05/31/24 13:02 05/02/24 15:37
Evac Vol (L)0.000 0.000
Recd. Temp (F)68.2 68.2
Recd. Pbar (mmHg)755.4 755.4
Recd. Gauge (mmHg)-157.0 -123.0
Recd Vol (L)1.102 4.991
P1 Temp (F)68.2 68.2
P1 Pbar (mmHg)755.4 755.4
P1 Gauge (mmHg)801.0 800.0
P1 Analyst buddhikaranawella buddhikaranawella
P1 Time 06/25/24 09:06 06/25/24 09:11
P1 Fill Gas Nitrogen Nitrogen
P1 Vol (L)2.866 12.275
P1 DF Override false false
P1 Dilution Factor 2.601 2.460
Enthalpy Analytical -- Canister Pressurization
0524-035
AECOM - Morrisville
Carolina Cleaners DC680016
Canister Pressurization Report ver. 20240301 Report Printed 6/26/2024 11:15:16 AM
EA Job# 0524-035 Page 7 of 20

Lab QC
EA Job# 0524-035 Page 8 of 20
Sample Name
Sample Info.
Sampling Date
Received Date
Sample Type
Batch
Data File
Dilution
Pressurization Factor
Acquisition Date
Instrument Method
Matrix
Parent
Enthalpy ID
Target Compound Parent Conc
(ppbv)
Concentration
(ppbv)
RL
(ppbv)
MDL
(ppbv)
Concentration
(ug/m³)
RL
(ug/m³)
Dup
Diff (%)
Flags
trans-1,2-Dichloroethene 457 453 5.02 4.30 1,795 19.9 0.9 pass
cis-1,2-Dichloroethene 864 852 4.97 4.30 3,374 19.7 1.5 pass
Trichloroethene 3,386 3,368 4.97 4.30 18,086 26.7 0.6 pass
Tetrachloroethene 1,179 1,186 5.03 4.30 8,041 34.1 0.7 pass
Compound Response Retention
Time (min)
Concentration
(ppbv)
Flag
Bromochloromethane (IS)905,215 11.02 5.21 pass
1,4-Difluorobenzene (IS)3,490,950 12.44 5.16 pass
Chlorobenzene-d5 (IS)2,997,640 16.57 4.92 pass
(ND) = Not Detected
(J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration
IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40%
17.1
17.1
23.1
29.2
Air
0524-035.SG-6.Can
0524-035.SG-6.LD
MDL
(ug/m³)
X2402948.D
50.000
2.460
2024-06-25 16:51
TO15_SCNV6.M
0524-035; *50=10mL load; Can #10111; MP3
2024-06-20 13:32
2024-06-24 00:00
LabDup
Xavier_X062424A_0524-035.v1
Enthalpy Analytical
Job No.: 0524-035-1 EPA Method TO-15 Analysis -- Run
AECOM - Morrisville 60731175 Carolina Cleaners DC680016
0524-035.SG-6.LD
EA Job# 0524-035 Page 9 of 20
Sample Name
Sample Info.
Sample Type
Batch
Data File
Dilution
Pressurization Factor
Acquisition Date
Instrument Method
Matrix
Analyst
Instrument
Enthalpy ID
Target Compound Concentration
(ppbv)
RL
(ppbv)
MDL
(ppbv)
Concentration
(ug/m³)
RL
(ug/m³)
MDL
(ug/m³)
Flags
Chloroethene (Vinyl chloride)ND 0.0400 0.0350 ND 0.102 0.0894 pass
trans-1,2-Dichloroethene ND 0.0408 0.0350 ND 0.162 0.139 pass
cis-1,2-Dichloroethene ND 0.0404 0.0350 ND 0.160 0.139 pass
Trichloroethene ND 0.0404 0.0350 ND 0.217 0.188 pass
Tetrachloroethene ND 0.0409 0.0350 ND 0.277 0.237 pass
Compound Response Retention
Time (min)
Concentration
(ppbv)
Flag
Bromochloromethane (IS)854,131 11.02 5.21 pass
1,4-Difluorobenzene (IS)3,331,645 12.44 5.16 pass
Chlorobenzene-d5 (IS)2,852,369 16.57 4.92 pass
Xavier
X062424A_Humid Blank #0702
(ND) = Not Detected
(J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration
IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40%
1.000
2024-06-24 22:59
TO15_SCNV6.M
Air
TDD
500mL load
Blank
Xavier_X062424A_0524-035.v1
X2402928.D
1.000
Enthalpy Analytical
Job No.: 0524-035-1 EPA Method TO-15 Analysis -- Run
AECOM - Morrisville 60731175 Carolina Cleaners DC680016
X062424A_Humid Blank #0702
EA Job# 0524-035 Page 10 of 20
Sample Name
Sample Info.
Sample Type
Batch
Data File
Dilution
Pressurization Factor
Acquisition Date
Instrument Method
Matrix
Enthalpy ID
Target Compound Response Concentration
(ppbv)
Expected
Conc (ppbv)
Recovery
(%)
Flags
Chloroethene (Vinyl chloride)331,597 3.86 5.00 77.3 pass, m
trans-1,2-Dichloroethene 1,177,281 5.55 5.10 109 pass
cis-1,2-Dichloroethene 1,369,658 5.86 5.05 116 pass
Trichloroethene 1,116,070 4.55 5.06 90.1 pass
Tetrachloroethene 1,580,163 4.74 5.12 92.7 pass
Compound Response Retention Time
(min)
Concentration
(ppbv)
Flag
Bromochloromethane (IS)878,388 11.02 5.21 pass
1,4-Difluorobenzene (IS)3,314,046 12.44 5.16 pass
Chlorobenzene-d5 (IS)2,876,735 16.57 4.92 pass
(ND) = Not Detected
(J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration
IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40%
1.000
2024-06-24 20:23
TO15_SCNV6.M
Air
X062424A_5ppbv TO15 LCS
125mL load; Can #C98007; GCMSPrepPg1367
QC
Xavier_X062424A_0524-035.v1
X2402925.D
1.000
Enthalpy Analytical
Job No.: 0524-035-1 EPA Method TO-15 Analysis -- Run
AECOM - Morrisville 60731175 Carolina Cleaners DC680016
X062424A_5ppbv TO15 LCS
EA Job# 0524-035 Page 11 of 20
Sample Name
Sample Info.
Sample Type
Batch
Data File
Dilution
Pressurization Factor
Acquisition Date
Instrument Method
Matrix
Parent
Enthalpy ID
Target Compound Response Concentration
(ppbv)
Expected
Conc (ppbv)
Parent
Conc (ppbv)
Recovery
(%)
Diff
(%)
Flags
Chloroethene (Vinyl chloride)331,082 3.87 5.00 3.86 77.4 0.2 pass, m
trans-1,2-Dichloroethene 1,197,144 5.67 5.10 5.55 111 2.0 pass
cis-1,2-Dichloroethene 1,391,580 5.97 5.05 5.86 118 2.0 pass
Trichloroethene 1,148,922 4.66 5.06 4.55 92.3 2.4 pass
Tetrachloroethene 1,630,590 4.88 5.12 4.74 95.4 2.8 pass
Compound Response Retention Time
(min)
Concentration
(ppbv)
Flag
Bromochloromethane (IS)875,091 11.02 5.21 pass
1,4-Difluorobenzene (IS)3,331,238 12.44 5.16 pass
Chlorobenzene-d5 (IS)2,885,280 16.57 4.92 pass
X062424A_5ppbv TO15 LCS LD
(ND) = Not Detected
(J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration
IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40%
1.000
2024-06-24 21:11
TO15_SCNV6.M
Air
X062424A_5ppbv TO15 LCS
125mL load; Can #C98007; GCMSPrepPg1367
QcDup
Xavier_X062424A_0524-035.v1
X2402926.D
1.000
`
Job No.: 0524-035-1 EPA Method TO-15 Analysis -- Run
AECOM - Morrisville 60731175 Carolina Cleaners DC680016
X062424A_5ppbv TO15 LCS LD
EA Job# 0524-035 Page 12 of 20

Narrative Summary

EA Job# 0524-035 Page 13 of 20

Enthalpy Analytical Narrative Summary

Company AECOM - Morrisville Client #Carolina Cleaners (DC680016) ;
60731175
Analyst TDD Job #0524-035
Parameters EPA Method TO-15 # Samples 2 (1.4L) Canisters

Custody Julia Serrano received the samples on 6/24/24 after being relinquished by
AECOM - Morrisville. The samples were received at ambient
temperature and in good condition.
Prior to, during, and after analysis, the samples were kept under lock with
access only to authorized personnel by Enthalpy Analytical, LLC.
Analysis The samples were analyzed for the DSCA5 target compound list using
the analytical procedures in EPA Method TO-15, Determination of
Volatile Organic Compounds (VOCs) In Air Collected In Specially-
Prepared Canister And Analyzed by Gas Chromatography/Mass
Spectrometry (GC/MS).
Upon receipt, the canister pressures were measured and recorded. The
canisters were then pressurized with UHP nitrogen and a dilution ratio
was calculated for each canister. See the Canister Pressurization Data
sheet located in the Results section of this report.
Both samples were analyzed undiluted. Sample SG-6 was also analyzed
at a subsequent 50-fold analytical dilution to bring all compounds
excluding vinyl chloride into the instrument’s calibration range. Dilution
factors are located in the sample header information.
The Agilent Technologies Model 6890N, Gas Chromatograph "Xavier"
(S/N US10721018) equipped with a 5975C VL Mass Selective Detector
(S/N US71215962) was used for this analysis. The samples and standards
were introduced directly to the analyzer using an Entech 7200
Preconcentrator.

Calibration The BFB tune analyses associated with the initial and continuing
calibrations met all method acceptance criteria.
The initial calibration (X100722A-TO15) met the 30% RSD criteria. The
initial calibration verification (ICV) met the 70-130% recovery criteria.
The continuing calibration (CCV) met the 30% difference criteria. Full
calibration data is available upon request.
Chromatographic
Conditions
The acquisition method (TO15_SCNV6.M) may be made available upon
request.
EA Job# 0524-035 Page 14 of 20

Enthalpy Analytical Narrative Summary
(continued)

QC Notes All internal standard area (IS) responses and retention time criteria were
met for this analysis.
The Laboratory Duplicate (LD) associated with this sample set met the
25% difference criteria for all reported compounds. The LCS was also
analyzed in duplicate and met the 25% difference criteria for all reported
compounds.
The laboratory humid blank associated with this analysis did not contain
any of the target analytes at a concentration greater than 3x their MDL.
The Laboratory Control Sample (LCS) met the 70-130% recovery criteria
for all reported compounds.
The samples were analyzed within the 30-day holding time required by
the method.
Reporting Notes The analysis met the requirements of the TNI Standard. Any deviations
from the requirements of the reference method or TNI Standard have been
stated above.
The results presented in this report are representative of the samples as
provided to the laboratory.

EA Job# 0524-035 Page 15 of 20

General Reporting Notes

The following are general reporting notes that are applicable to all Enthalpy Analytical, LLC data
reports, unless specifically noted otherwise.

 Any analysis which refers to the method as “Type” represents a planned deviation from the
reference method. For instance a Hydrogen Sulfide assay from a Tedlar bag would be labeled
as “EPA Method 16-Type” because Tedlar bags are not mentioned as one of the collection
options in EPA Method 16.
 The acronym MDL represents the Minimum Detection Limit. Below this value the laboratory
cannot determine the presence of the analyte of interest reliably.
 The acronym LOQ represents the Limit of Quantification. Below this value the laboratory
cannot quantitate the analyte of interest within the criteria of the method.
 The acronym ND following a value indicates a non-detect or analytical result below the MDL.
 The letter J in the Qualifier or Flag column in the results indicates that the value is between
the MDL and the LOQ. The laboratory can positively identify the analyte of interest as
present, but the value should be considered an estimate.
 The letter E in the Qualifier or Flag column indicates an analytical result exceeding 100% of
the highest calibration point. The associated value should be considered as an estimate.
 Sample results are presented ‘as measured’ for single injection methodologies, or an average
value if multiple injections are made. If all injections are below the MDL, the sample is
considered non-detect and the ND value is presented. If one, but not all, are below the MDL,
the MDL value is used for any injections that are below the MDL. For example, if the MDL is
0.500 and LOQ is 1.00, and the instrument measures 0.355, 0.620, and 0.442 - the result
reported is the average of 0.500, 0.620, and 0.500 - - - i.e. 0.540 with a J flag.
 When a spike recovery (Bag Spike, Collocated Spike Train, or liquid matrix spike) is being
calculated, the native (unspiked) sample result is used in the calculations, as long as the value
is above the MDL. If a sample is ND, then 0 is used as the native amount (not the MDL
value).
 The acronym DF represents Dilution Factor. This number represents dilution of the sample
during the preparation and/or analysis process. The analytical result taken from a laboratory
instrument is multiplied by the DF to determine the final undiluted sample results.
 The addition of MS to the Sample ID represents a Matrix Spike. An aliquot of an actual
sample is spiked with a known amount of analyte so that a percent recovery value can be
determined. The MS analysis indicates what effect the sample matrix may have on the target
analyte, i.e. whether or not anything in the sample matrix interferes with the analysis of the
analyte(s).
EA Job# 0524-035 Page 16 of 20

General Reporting Notes
(continued)
 The addition of MSD to the Sample ID represents a Matrix Spike Duplicate. Prepared in the
same manner as a MS, the use of duplicate matrix spikes allows further confirmation of
laboratory quality by showing the consistency of results gained by performing the same steps
multiple times.
 The addition of LD to the Sample ID represents a Laboratory Duplicate. The analyst prepares
an additional aliquot of sample for testing and the results of the duplicate analysis are
compared to the initial result. The result should have a difference value of within 10% of the
initial result (if the results of the original analysis are greater than the LOQ).
 The addition of AD to the Sample ID represents an Alternate Dilution. The analyst prepares an
additional aliquot at a different dilution factor (usually double the initial factor). This analysis
helps confirm that no additional compound is present and coeluting or sharing absorbance with
the analyte of interest, as they would have a different response/absorbance than the analyte of
interest.
 The Sample ID LCS represents a Laboratory Control Sample. Clean matrix, similar to the
client sample matrix, prepared and analyzed by the laboratory using the same reagents, spiking
standards and procedures used for the client samples. The LCS is used to assess the control of
the laboratory’s analytical system. Whenever spikes are prepared for our client projects, two
spikes are retained as LCSs. The LCSs are labeled with the associated project number and kept
in-house at the appropriate temperature conditions. When the project samples are received for
analysis, the LCSs are analyzed to confirm that the analyte could be recovered from the media,
separate from the samples which were used on the project and which may have been affected
by source matrix, sample collection, and/or sample transport.
 Significant Figures: Where the reported value is much greater than unity (1.00) in the units
expressed, the number is rounded to a whole number of units, rather than to 3 significant
figures. For example, a value of 10,456.45 ug catch is rounded to 10,456 ug. There are five
significant digits displayed, but no confidence should be placed on more than two significant
digits. In the case of small numbers, generally 3 significant figures are presented, but still only
2 should be used with confidence. Many neat materials are only certified to 3 digits, and as the
mathematically correct final result is always 1 digit less than all its pre-cursors - 2 significant
figures are what are most defensible.
 Manual Integration: The data systems used for processing will flag manually integrated
peaks with an “M”. There are several reasons a peak may be manually integrated. These
reasons will be identified by the following two letter designations on sample chromatograms,
if provided in the report. The peak was not integrated by the software “NI”, the peak was
integrated incorrectly by the software “II” or the wrong peak was integrated by the software
“WP”. These codes will accompany the analyst’s manual integration stamp placed next to the
compound name on the chromatogram.
EA Job# 0524-035 Page 17 of 20

Sample Custody
EA Job# 0524-035 Page 18 of 20
EA Job# 0524-035 Page 19 of 20

This Is The Last Page
Of This Report.

EA Job# 0524-035 Page 20 of 20
APPENDIX E
HISTORICAL MAPS
DR
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Att. 7
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LEGEND
SITE PARCEL
MAP SOURCE:·PARCEL LINES FROM ORANGE COUNTY,
GIS DATABASE.
·AERIAL IMAGERY FROM NC OneMap
GeoSpacial PORTAL.
Chapel Hill Cleaners
(#DC680010)
Carolina Cleaners
406 W. Franklin St.
(#DC680016)
Carolina Cleaners
400 W. Franklin St.
(#DC680015)
APPROX. SCALE, ft.
0
SHEET:
DR
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B
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:
CH
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:
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:
60
SD
H

-

1
2
/
1
4
/
2
0
1
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CE
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-

1
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1
7
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1
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AE
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59
2
5

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3
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2
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2
4
Carolina Cleaners
AAAAAAA-1-1-1-1-1 ((10/20/20000171771711)
D
IAIAAIAAAI-1-111-111 ((((((10110101/2/2//20/202017))
- 3.6 μg
SSV-V-V-1111 (11110/0/0/0/20020202/2/2//220101010101010177)7)77)7)
E μgμgμμμg
Att. 22
SSSSSSS-4-4-4-4-4-4-4 (((((6/6/6/6/242424244244/1/1/1/114)4)4)4)4))
P - μgμgμgμgμg
μμgμgμgμgμ
μgμgμgμgμ
SSSSSSSS-3-3-- (6//24242422/14))
- 18 2 μgμμμμμ
2 1 μgμμgμμμμ/
DCE - μgμgμμ
ans- μg/
IAIAIAIA-6-6-66-6-6-6 ((((6/6//6 10101010010-6-6-6666-6//2/2/2/2//4/44/4/4/4/141141414)
μgμgμgμg
μμgμgμgμμμ
- μgμμμμ
IAAAIAI-1-0 00 (6(6(66(6(6(66(6/1/1/11/0-0-0-00 6//66////24242424242244///11////4)4 - Basememenent
μgμμμμ
T μgμμμμμμ
is- μgμ/
IA-11 (6(6(66/1/1/1/00-0-0 6/6//6/2422444222/1/4)4) -BBBBBBassaaaemmmemmenett
P E - μgμμgμg
- μgμgμgμgμgμgμg
μgμg
IAIA-77777 (((((6//1010100-6-66/2/2/2/24/4/4/4/114414111))))))
- μgμgμμg
- μgμgμgμg
μgμg
IAIAIAIAIAIAA-8-88-88 (((((6/6/6/6/666 110101101-6-6-6-666--6/2/2/2/2/2/2/24/4/4//14141414141414))) ) ) )- BaBaBBasesesemememntnttt
μgμgμgμμg
μgμg
- μgμg
IA 11 (6((6(6/1000000 6/6/6//6 24222244242/1///4)4 BBBB
IA-9- (6/10-6/24/4/4/44 141414141144)))) ))) ----BaBaaBsesseesessemmmememement24/1444))))BBB t
μgμgμμgμgμgμg
μgμgμμ/
0.07 μgμgμgμgμ
Va
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Q
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R
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6
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6
Indoor/Ambient Air Sample
LEGEND
Subslab Vapor Sample
micrograms per cubic meterμg/m3
BDL - Below Detection Limit
PCE - Tetrachloroethene
TCE - Trichloroethene
cis-1,2-DCE - cis-1,2-Dichloroethene
trans-1,2-DCE - trans-1,2-Dichloroethene
Sample does not exceed acceptable commercial or residential risk (DSCA Calculator Version 6 - Nov. 2017)
Sample does not exceed acceptable commercial risk but does exceed residential risk (DSCA Calculator Version 6 - Nov. 2017)
Sample exceeds acceptable commercial and residential risk (DSCA Calculator Version 6 - Nov. 2017)
IA-DBSutton (11/27/2018)
PCE - 0.65 μg/m3
SSV-DBSutton (11/27/2018)
PCE - 170 μg/m3
TCE - 2.5 μg/m3