7601_RandolphCountyMSWLF_May2023GWMR_FID1894107_20240826

REPORT
FIRST SEMI-ANNUAL 2023 WATER QUALITY
MONITORING EVENT
Closed Randolph County Landfill, Permit No. 76-01

Submitted to:
Mr. Ervin Lane
North Carolina Department of Environmental Quality
Division of Waste Management - Solid Waste Section
1646 Mail Service Center
Raleigh, North Carolina 27699-1646
31404568.018
October 5, 2023

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Project No. 31404568.018 Randolph County Landfill
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Executive Summary
On behalf of Waste Management of Carolinas, Inc. (Waste Management) and Randolph County, WSP USA Inc.
(WSP), is pleased to submit the enclosed Water Quality Monitoring Report, which documents the results of the
May 22 – 23, 2023, groundwater and surface water sampling event at the closed Randolph County Landfill, North
Carolina (NC) Solid Waste Permit (SWP) No. 76-01.

One inorganic constituent, cobalt, was detected at a quantified concentration above the practical quantitation limit
(PQL) and NC 2L Groundwater Standard (NC 2L Standard) in samples collected from downgradient monitoring
MW-7 during this monitoring event. Cobalt was also detected at an estimated concentration below the practical
quantitation limit (PQL), but above the NC 2L Standard in the samples collected from downgradient monitoring
well MW-6. The cobalt concentrations in samples collected from MW-6 and MW-7 are generally consistent with
historical data. With regards to the estimated cobalt concentration detected in samples collected from MW-6, per
15A NCAC 02L .0202 (b)(1), “where the standard (i.e., the NC 2L Standard) for a substance is less than the PQL,
the detection of that substance at or above the PQL constitutes a violation of the standard.” Historically, cobalt
has been intermittently detected in samples collected from the upgradient monitoring well, MW-5, at similar or
higher concentrations suggesting that cobalt is naturally occurring or could be from an off-site source. No other
inorganic constituents were detected in samples collected from the groundwater compliance network at
concentrations above applicable groundwater quality standards during this sampling event.

Two NC Appendix I listed organic constituents, 1,1-dichloroethane and tetrachloroethene, were detected at
quantified concentration above their respective PQLs and NC 2L Standards in samples collected from
downgradient compliance monitoring well MW-10S during the May 2023 sampling event, as they have been
historically. Vinyl chloride was detected at an estimated concentration below PQL but above the NC 2L Standard
in samples collected from MW-10S during the May 2023 sampling event, as it has been historically. The
constituent 1,4-dioxane was detected at quantified concentration above the NC 2L Standard in the samples
collected from the downgradient monitoring wells MW-6 and MW-10S. The constituent, 1,4 dioxane, is currently
sampled in accordance with the May 29, 2018 NC DEQ memorandum and is not currently required by permit or
regulation. Future trends for the detection of 1,4-dioxane will be monitored. No other organic compounds were
detected at concentrations above the applicable groundwater standards during the May 2023 sampling event.

One inorganic constituent, cobalt, was detected at an estimated concentration above the chronic NC In-Stream
Target Values for Surface Water in samples collected from the upstream surface water monitoring point, SW-1,
during the May 2023 sampling event. Cobalt was not detected in either downstream surface water sample during
this sampling event. No other inorganic or organic compounds were detected in samples collected from surface
water monitoring points at concentrations above the applicable surface water standards during the May 2023
event.

According to the current data and as indicated by the BIOCHLOR model described in detail in this report, it is
likely that the plume size has stabilized. Because of the low concentration of parent compounds and multiple
degradation pathways for cis-1,2-dichloroethene (e.g., aerobic and anaerobic), there are limited concentrations of
vinyl chloride and ethene in each of the plumes evaluated. The concentration trends show that cis-1,2-
dichloroethene is not accumulating and that degradation of the chlorinated compounds is continuing.

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Based on the May 2023 analytical results, the uppermost aquifer beneath this facility should continue to be
monitored in accordance with the requirements of the Assessment Monitoring Program as outlined in Title 15A of
North Carolina Administrative Code (NCAC) Subchapter 13B Rule .1634. The County will continue to sample
according to the reduced monitored natural attenuation (MNA) parameter list approved by NC Department of
Environmental Quality (DEQ) on October 18, 2017. The next sampling event is tentatively scheduled for October
2023.

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S I G N A T U R E S

PREPARED BY

Darren Cox
Associate Consultant, Environmental Scientist

REVIEWED BY

Benjamin S. Draper, PG, PMP
Lead Consultant, Geologist

This report was prepared by WSP USA Inc. for the account of Waste Management and Randolph County in
accordance with the professional services agreement. The disclosure of any information contained in this report is
the sole responsibility of the intended recipient. The material in it reflects WSP’s best judgement in light of the
information available to it at the time of preparation.
The original of the technology-based document sent herewith has been authenticated and will be retained by
WSP for a minimum of ten years. Since the file transmitted is now out of WSP’s control and its integrity can no
longer be ensured, no guarantee may be given with regards to any modifications made to this document.

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Project No. 31404568.018 Randolph County Landfill
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Distribution List

Kyle Mertens, Environmental Manager, South Atlantic, Waste Management, 321-403-2544. [e-mail]
Mike McFeeley, District Manager, Waste Management, 3597 Old Cedar Falls Road, Randleman, NC, 27317.
[e-mail]
Seth Ramaley, PG, Director, Groundwater Protection Program, Waste Management, 1850 Parkway Place, Suite
600, Atlanta, GA, 30067. 770-590-2933. [e-mail]
Paxton Arthurs, PE, Public Works Director, Randolph County Office Building, 725 McDowell Road, Asheboro, North
Carolina 27205. 336-318-6605. [e-mail]

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TABLE OF CONTENTS
1.0 INTRODUCTION……………………………………………………………………………….….3
1.1 Site Description and Background………………………………….…………………………………………..3
1.2 Compliance Monitoring History……………………………………………………………………………….. 3
1.3 Hydrogeologic Setting…………………………………………………..………………………………………. 4
2.0 FIELD PROGRAM, MONITORING RESULTS, AND DISCUSSION…………………………5
2.1 Visual Inspection Program……………………………………………………………………………………….5
2.2 Well Network and Groundwater Elevation Measurements…………………………………………………5
2.3 October 2022 Groundwater and Surface Water Monitoring Event………………………………………..6
2.4 Laboratory Analysis Program………………………………………………………………………………… 6
2.4.1 Compliance Monitoring………………………………………………………………………………………….. 7
2.4.2 Corrective Action Monitoring…………………………………………………………………………………… 7
3.0 LABORATORY AND FIELD QA/QC…………………………………………………………7
4.0 DATA EVALUATION…………………………………………………………………………...7
4.1 North Carolina Groundwater and Surface Water Standard Comparisons……………………………….7
5.0 CORRECTIVE ACTION PERFORMANCE MONITORING RESULTS AND MONITORED NATURAL
ATTENUATION EVALUATION……..…………………………………………………………………………….. 8
5.1 Corrective Action Monitoring Performance Results….………………………………………………………8
5.2 Monitored Natural Attenuation Evaluation…………………...……………………………………………….. 8
6.0 CONCLUSIONS…………………………………………………………………………………….10
7.0 REFERENCES……………………………………………………………………………………..11

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TABLES
Table 1 Summary of Historical Static Water Level Data
Table 2 Summary of Estimated Horizontal Flow Velocities
Table 3 Summary of Well Construction Information
Table 4 Summary of Historical Groundwater Monitoring Results
Table 5 Summary of Field Parameters
Table 6 Summary of Historical Surface Water Monitoring Results
Table 7 Summary of Surface Water Field Parameters
Table 8 Summary of Geochemical Parameters
Table 9 Summary of Constituents of Concern

FIGURES
Figure 1 Groundwater Surface Contour Map, May 23, 2023

APPENDICES
Appendix A Groundwater and Surface Water Sampling Logs.

Appendix B May 2023 Groundwater Certificates-of-Analysis, Chain-of-Custody Forms, Sampling Logs and Laboratory
Data Reviews.

Appendix C EPA Natural Attenuation Screening Protocol Forms and BIOCHLOR Monitored Natural Attenuation
Analysis.

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1.0 INTRODUCTION
On behalf of Waste Management of Carolinas, Inc. (Waste Management) and Randolph County, North Carolina (NC),
WSP USA Inc. (WSP), is submitting this Water Quality Monitoring Report in accordance with Title 15A of the North
Carolina Administrative Code (NCAC) Subchapter 13B .1634. This report summarizes the results of the May 22 – 23,
2023 sampling event at the closed Randolph County Landfill located in Randolph County, NC. The Randolph County
Landfill is a closed municipal solid waste (MSW) landfill and is maintained by Waste Management under NC Solid Waste
Permit No. 76-01 issued by the NC Department of Environmental Quality (DEQ).

1.1 Site Description and Background
The location of the closed Randolph County Landfill is shown on the inlay on Figure 1. The facility is located
approximately 3 miles northeast of the city of Asheboro, near the town of Central Falls in Randolph County, NC.
Randolph County operated a sanitary landfill from 1973 to 1985. A second sanitary landfill for MSW, construction and
demolition (C&D) debris, and land clearing and inert debris (LCID) was operated from 1985 to December 31, 1997. The
facility is located on approximately 600 acres, approximately half of which contains waste or is associated with activities
for the convenience center and the County’s solid waste transfer station. The existing transfer station was built before
final landfill closure in 1997 and operated until the opening of the Great Oak Landfill near Cedar Falls in 2017. Because it
operated past October 9, 1993, the Randolph County landfill is subject to Title 15A NCAC 13B .1630 of the NC Solid
Waste Management Regulations (SWMR).

As shown on Figure 1, the landfill is accessible by County Land Road to the southwest. The landfill is bound to the north
by the Deep River and bordered to the west, south, and east by residential and undeveloped, wooded properties.
Topographic relief at the landfill ranges from approximately 580 to 725 feet above mean sea level (amsl). Surface
drainage from the facility is toward an unnamed perennial stream to the west and a natural valley to the east. Runoff from
both features drains into the Deep River located northeast of the landfill (H&S, 1994).

1.2 Compliance Monitoring History
Groundwater monitoring wells for the second sanitary landfill have been sampled since 1987. The facility has been in the
assessment monitoring program since 1996, due to detections of volatile organic compounds (VOCs) in groundwater
samples at concentrations above applicable standards. The current Water Quality Monitoring Plan (WQMP) was included
in the facility’s Transition Plan, dated October 8, 1994, and was subsequently approved by NC DEQ, formerly the NC
Department of the Environment and Natural Resources (DENR), in 1995. In accordance with the WQMP, the current
water quality monitoring system consists of six groundwater monitoring wells (MW-5, MW-6, MW-7, MW-8, MW-9, and
MW-10S) and four surface water monitoring points [SW-1 and SW-3 (upstream) and SW-2 and SW-4 (downstream)].

A Nature and Extent Study (NES) was submitted to the NC DEQ on April 12, 2013, in response to exceedances of VOCs
in groundwater samples collected from the monitoring network. The NES was approved by NC DEQ on June 8, 2013. An
Assessment of Corrective Measures (ACM) was submitted to NC DEQ on October 3, 2013 and was approved on
December 2, 2013. A Corrective Action Plan (CAP) was submitted to NC DEQ on July 31, 2015 and approved on
September 10, 2015. As specified in the CAP, monitored natural attenuation (MNA) was implemented as the corrective
action for the facility. As part of the Corrective Action Performance Monitoring Plan (CAPMP), which was approved as

part of the CAP, downgradient monitoring well MW-1 was replaced with monitoring well MW-10S. Monitoring well MW-1
remains for the collection of water level data only. Per the CAPMP, monitoring wells MW-2, MW-3, MW-10D, and
MW-11S are sampled semi-annually as MNA corrective action monitoring wells. A Corrective Action Evaluation Report

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(CAER) was submitted to NC DEQ on May 4, 2021. The CAER requested that 1,4-dichlorobenzene, 1,2-dichloroethane,
cis-1,2-dichloroethene, methylene chloride, and 4 Methyl-2-pentanone be removed as constituents-of-concern (COCs) for
the facility. The CAER was approved by NC DEQ on May 10, 2021. Sampling and analysis of 1,4-dioxane is currently
performed in accordance with a May 2018 Memorandum from NC DEQ. Aside from the May 2018 Memorandum, 1,4-
dioxane is not currently included in the NC Solid Waste Management Rules, nor in the facility’s permit.

1.3 Hydrogeologic Setting
Geologically, the facility is located within the Carolina Slate Belt of the Piedmont Physiographic Province of NC. The
Carolina Slate Belt is composed of Late Proterozoic to Cambrian aged meta-sedimentary and meta-volcanic rocks that
locally have been intruded by diabase dikes and felsic intrusive suites (NCGS, 1985). The facility is underlain primarily by
felsic meta-volcanic tuffs with massive fabrics to steeply dipping foliations (GSA, 2008). STS Consultants Ltd. conducted
a geologic and hydrogeologic investigation as part of the Phase II Landfill Expansion in late 1984 and 1985 (H&S, 1994).
The topography of the area is characterized by rolling rounded hills and flat valleys with sharp draws containing streams
and ponds. The surficial geology on-site consists of saprolite (i.e., residual soils weathered from bedrock). The saprolite
generally consists of clayey silts and silty clays with some sandy silts and silty sands (H&S, 1994).

The uppermost groundwater beneath the facility is present in a shallow unconfined aquifer comprised of partially
weathered fractured meta-volcanic rock. Due to the rolling topography, groundwater occurs at depths ranging from
approximately 4 to 66 feet below grade. Depth-to-water measurements obtained during the May 2023 monitoring event
are summarized in Table 1 and were used to prepare a groundwater surface contour map presented on Figure 1.

As shown on Figure 1, the groundwater flow in the uppermost aquifer beneath the site is generally to the north or
northeast toward the Deep River which is located along the northern property boundary. The groundwater contour map
and interpreted flow directions are consistent with those previously submitted for this facility.

Based on the May 2023 groundwater surface contour map, the average hydraulic gradient in the shallow aquifer
underlying the site, as measured along the conceptual flow path shown on Figure 1, was calculated to be approximately
0.066 foot/foot (Table 2). Based on a local hydrogeologic investigation, a hydraulic conductivity of 2.75E-04
centimeter/second was used in linear groundwater velocity calculations (GSA, 2008). An estimated effective porosity of
0.15 was used for the shallow aquifer to represent a range from saprolite to fractured rock (H&S, 1997).

Using the above values, the estimated rate of groundwater flow for the uppermost aquifer beneath the facility was
calculated using the following modified Darcy equation:
𝑉= 𝐾 𝑥 𝑖
𝑛

where Vgw = average linear velocity (feet/year), K = hydraulic conductivity (feet/year), i = horizontal hydraulic gradient, and
ne = effective porosity.

The average estimated linear groundwater flow velocity under the waste management unit is approximately 124 feet/year,
which is generally consistent with previous estimates (Table 2). The range of groundwater flow rates is expected to vary
depending on the hydrogeologic unit in which it occurs. However, the linear velocity equation above makes the simplified
assumption of a homogeneous and isotropic aquifer. Therefore, this equation represents a likely average value for the
uppermost aquifer and does not account for heterogeneous and/or anisotropic conditions that may be present in the
uppermost aquifer at the facility. The saprolite may have areas that exhibit relict foliation, and these structures can result
in locally anisotropic groundwater flow directions.

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2.0 FIELD PROGRAM, MONITORING RESULTS, AND DISCUSSION
Field activities conducted for the May 2023 sampling event are discussed in the following sections.

2.1 Visual Inspection Program
To detect a potential release at the earliest possible time, a visual inspection program is used by sampling crews at the
closed Randolph County Landfill. This program includes observations of physical indicators such as potential water table
mounding beneath the waste management unit, physical examination of any stresses in biological communities, visible
signs of leachate migration (i.e., leachate seeps), unexplained changes in soil characteristics, and any other changes to
the environment due to the waste management unit. During this compliance monitoring event, no physical indicators of a
potential release were observed in the vicinity of the waste management area.

2.2 Well Network and Groundwater Elevation Measurements
The current groundwater monitoring network at the closed Randolph County Landfill consists of six monitoring wells (MW-
5, MW-6, MW-7, MW-8, MW-9, and MW-10S). Additionally, four monitoring wells (MW-2, MW-3, MW-10D, and MW-11S)
are sampled semi-annually for as performance monitoring wells associated with the MNA corrective action remedy.
Available monitoring well construction information is summarized on Table 3, and the well locations are shown on Figure
1. The groundwater monitoring network was constructed to target the preferential flow path for groundwater underlying
waste management units (i.e., partially weathered fractured rock that comprises the unconfined uppermost aquifer). Two
on-site surface water points (upstream SW-1 and downstream SW-2) and two off-site surface water points (upstream SW-
3 and downstream SW-4) are also monitored to assess water quality at the site in conjunction with groundwater
monitoring network.

Monitoring well MW-5 is the facility’s background well and is located hydraulically upgradient of the waste management
units. Monitoring wells MW-6, MW-7, MW-8, MW-9, and MW-10S are located downgradient of the waste management
units and represent the facility’s downgradient compliance network. Monitoring wells MW-7, MW-8, MW-9, and MW-10S
are screened in the shallow unconfined aquifer while monitoring wells MW-5 and MW-6 are screened in fractured
bedrock. Additionally, water levels are measured during each sampling event at nine observation wells; MW-1, MW-2,
MW-3, MW-4, MW-10D, MW-11S, MW-A1, MW-A2, and MW-A3. These measurements supplement groundwater
elevation data obtained from the compliance monitoring wells and are used in the creation of the groundwater contour
map included as Figure 1.

Depth-to-water measurements were recorded to the nearest 0.01 foot prior to initiating groundwater purging and sampling
activities. A summary of the current and historical water level elevations is presented in Table 1.

As presented, the data indicate that the hydraulic head level in the uppermost aquifer beneath the facility is relatively
consistent with temporal variation, with the long-term average ranging from approximately 2 to 20 feet (plus or minus). As
expected, the range in fluctuation appears to be greatest in upgradient well MW-5 which is located in a groundwater
recharge area. The range of fluctuation in downgradient compliance wells MW-6, MW-7, MW-8, MW-9, and MW-10S,
located near groundwater discharge areas, is less, presumably due to the stabilizing effect of the hydraulic discharge
boundary.

2.3 May 2023 Groundwater and Surface Water Monitoring Event
Personnel from WSP visited the facility on May 22 - 23, 2023 to purge and sample groundwater monitoring wells MW-2,
MW-3, MW-5, MW-6, MW-7, MW-8, MW-9, MW-10S, MW-10D, and MW-11S, and to sample surface water monitoring
points SW-1, SW-2, SW-3, and SW-4. Monitoring wells were purged with dedicated bladder pumps using low-flow

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micropurge procedures in accordance with applicable United States Environmental Protection Agency (USEPA) and NC
DEQ sampling protocols. Field measurements of temperature, pH, specific conductivity, dissolved oxygen (DO),
oxidation-reduction potential (ORP), and turbidity were recorded periodically (i.e., approximately every 3 to 5 minutes
based on the purge rate and flow cell volume) with field-calibrated instruments during the micro-purge process. In
general, the purge rate for each well was matched to the yield of the monitoring well, as determined by continuously
monitoring the depth to the water, up to a maximum purge rate of 500 milliliters per minute. Each monitoring well was
purged until stabilization was indicated by the water quality parameters.

Prior to sampling, laboratory-supplied sample containers were prepared. Each sample container was labeled with the
sample identification number, sampling personnel, date and time of sample collection, project name and number, and
requested chemical analysis. The groundwater samples were collected directly from the inline tubing connected to the
dedicated bladder pumps. Samples were placed into pre-preserved sample containers after purging was considered
complete based on the stabilization of field parameters.

Surface water samples were collected directly from the stream flow by lowering the sample containers into the stream with
the opening facing away from the current flow, taking care to prevent the overflow of the sample containers and to
minimize sample-induced turbidity. Measurements of temperature, pH, specific conductivity, DO, ORP, and turbidity were
recorded during the collection of the surface water samples.

After collection, the groundwater and surface water samples were placed in a cooler on ice, under chain-of-custody
control. Copies of the sampling logs are presented in Appendix A. Included in each log is a description of the sampling
equipment, sampling location, sampling method, field observations, and field measurements.

2.4 Laboratory Analysis Program
For the May 2023 compliance monitoring, groundwater and surface water samples were shipped via courier on May 22 -
23, 2023 to Eurofins Raleigh (Eurofins) located in Cary, NC, under chain-of-custody control. As noted in the laboratory
reports included in Appendix B, samples from monitoring wells MW-5, MW-6, MW-7, MW-8, MW-9, and MW-10S and
from surface water monitoring points SW-1, SW-2, SW-3, and SW-4 were received at the laboratory on May 25, 2023 in
good condition and properly preserved.

The MNA groundwater samples were shipped to Pace Analytical Gulf Coast (Pace) of Baton Rouge, Louisiana, under
chain-of-custody control. Groundwater samples from MW-2, MW-3, MW-7, MW-8, MW-10S, MW-10D, and MW-11S were
shipped on May 22, 2023 and were received by the laboratory on May 23, 2023. Monitoring well MW-5 was not sampled
during the May 2023 sampling event as the depth to groundwater was measured below the pump and this well went dry
during purging.

2.4.1 Compliance Monitoring
The compliance groundwater samples collected in May 2023 were analyzed for the NC Appendix II constituent list.
Surface water samples were analyzed for the NC Appendix I constituent list. Compliance groundwater and surface water
samples collected during this event were also analyzed for 1,4-dioxane per the May 29, 2018, NC DEQ memorandum.

2.4.2 Corrective Action Monitoring
A reduced list of MNA parameters was approved by the NC DEQ Solid Waste Section (SWS) in a letter dated October 18,
2017. However, the full MNA parameter list is required during back-to-back events every three years (the next full MNA
list event will be in October 2023). Groundwater from compliance monitoring wells MW-5, MW-7, MW-8, and MW-10S,
and corrective action wells MW-2, MW-3, MW-10D, and MW-11S, were analyzed for the following MNA parameters:

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carbon dioxide, chloride, ethane, ethene, methane, hydrogen, ferrous iron, nitrate, and sulfate. Corrective action wells
MW-2, MW-3, MW-10D, and MW-11S were also analyzed for constituents of concern (COCs) which include benzene, 1,1-
dichloroethane, tetrachloroethene, trichloroethene, and vinyl chloride. As presented in Section 2.4, monitoring well MW-5
was not sampled during the May 2023 sampling event as the depth to water was measured below the pump and the well
went dry during purging.

3.0 LABORATORY AND FIELD QA/QC
A laboratory-prepared trip blank accompanied the volatile sample containers for the May 2023 sampling event to and from
the laboratory. Eurofins analyzed the trip blank for NC Appendix II VOCs. Reviews of the laboratory data were performed
by WSP personnel and are included in Appendix B. Chloroform was detected at estimated concentrations in the trip
blank. Methylene chloride was detected in the method blank. Based on the data review, detections of chloroform in
samples collected from MW-8, SW-3, and SW-4 are considered blank-qualified. The detection of methylene chloride in
samples collected from MW-10S is also blank qualified.

4.0 DATA EVALUATION
The results of the data evaluations are presented in the following sections.

4.1 North Carolina Groundwater and Surface Water Standard Comparisons
Analytical results and field parameters for the May 2023 groundwater samples are summarized in Table 4 and Table 5
along with available historical data. The laboratory certificates-of-analysis, chain-of-custody forms, and laboratory data
reviews for the sampling event are included in Appendix B.

One inorganic constituent, cobalt, was detected at a quantified concentration above the practical quantitation limit (PQL)
and NC 2L Groundwater Standard (NC 2L Standard) in samples collected from the downgradient monitoring MW-7 during
this monitoring event. Cobalt was also detected at an estimated concentration below the practical quantitation limit (PQL),
but above the NC 2L Standard in the samples collected from downgradient monitoring well MW-6. The cobalt
concentrations in samples collected from MW-6 and MW-7 are generally consistent with historical data. With regards to
the estimated cobalt concentration detected in samples collected from MW-6, per 15A NCAC 02L .0202 (b)(1), “where the
standard (i.e., the NC 2L Standard) for a substance is less than the PQL, the detection of that substance at or above the
PQL constitutes a violation of the standard.” Historically, cobalt has been intermittently detected in samples collected
from the upgradient monitoring well MW-5 at similar or higher concentrations suggesting that cobalt is naturally occurring
or could be from an off-site source. No other inorganic constituents were detected in samples collected from the
groundwater compliance network at concentrations above applicable groundwater quality standards during this sampling
event.

As presented in Table 4, two NC Appendix I listed organic constituents, 1,1-dichloroethane and tetrachloroethene, were
detected at quantified concentration above the PQL and NC 2L Standard in samples collected from downgradient
compliance monitoring well MW-10S during the May 2023 sampling event, as they have been historically. Vinyl chloride
was detected at an estimated concentration below the PQL but above the NC 2L Standard in samples collected from MW-
10S during the May 2023 sampling event, as it has been historically. The constituent 1,4-dioxane was detected at
quantified concentration above the NC 2L Standard in the samples collected from the downgradient monitoring wells MW-
6 and MW-10S. The constituent, 1,4 dioxane, is currently sampled in accordance with the May 29, 2018 NC DEQ
memorandum and is not currently required by permit or regulation. Future trends for the detection of 1,4-dioxane will be
monitored. No other organic compounds were detected at concentrations above the applicable groundwater standards
during the May 2023 sampling event.

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One inorganic constituent, cobalt, was detected at an estimated concentration above the chronic NC In-Stream Target
Values for Surface Water in samples collected from the upstream surface water monitoring point, SW-1, during the May
2023 sampling event. Cobalt was not detected in either downstream surface water sample during this sampling event.
No other inorganic or organic compounds were detected in samples collected from surface water monitoring points at
concentrations above the applicable surface water standards during the May 2023 event.

5.0 CORRECTIVE ACTION PERFORMANCE MONITORING RESULTS AND
MONITORED NATURAL ATTENUATION EVALUATION

The CAPMP was approved as part of the CAP by NC DEQ on September 15, 2015. Per the CAPMP, MNA background
sampling began during the October 2015 semi-annual water quality monitoring event. The MNA sampling program was
updated with the submission of a CAER on May 4, 2021 and approved by NC DEQ on May 10, 2021. With approval of
the CAER, 1,4-dichlorobenzene; 1,2-dichloroethane; cis-1,2-dichloroethene; methylene chloride; and 4 Methyl-2-
pentanone were removed as constituents-of-concern (COCs) for the facility.

5.1 Corrective Action Performance Monitoring Results
Per the CAPMP, corrective action monitoring wells MW-2, MW-3, MW-10D, and MW-11S were sampled in addition to the
compliance monitoring wells during the May 2023 sampling event. Samples collected from MW-2, MW-3, MW-7, MW-8,
MW-10S, MW-10D, and MW-11S were analyzed for select MNA parameters, which included: sulfide, chloride, carbon
dioxide, ethane, ethene, methane, hydrogen, ferrous iron, nitrate, and sulfate. A sample for MNA parameters could not be
obtained from monitoring well MW-5 as the water level was measured below the top of the pump prior to purging and the
well was pumped dry before the samples could be collected. A summary of the MNA parameter data is included as Table
8, and the laboratory certificates-of-analyses are included in Appendix B

The samples collected from MW-2, MW-3, MW-10D, and MW-11S were also analyzed for a reduced list of COCs as
identified in the CAP, which included benzene, 1,1-dichloroethane, tetrachloroethene, trichloroethene, and vinyl chloride.
As presented, these constituents were also analyzed in samples collected from the compliance monitoring wells as part of
the routine semi-annual water quality monitoring event. A summary of the COC results from the performance monitoring
wells as well as the compliance monitoring wells is included in Table 9, and the laboratory certificates-of-analyses are
included in Appendix B.

As presented, two COCs, 1,1-dichloroethane and tetrachloroethene, were detected at a quantified concentration above
the PQL and the NC 2L Standard in samples collected from monitoring well MW-10S during the May 2023 sampling
event. Vinyl chloride was also detected at an estimated concentration below the PQL but above the NC 2L Standard in
samples collected from MW-10S and MW-10D during the May 2023 sampling event. No other COCs were detected
above the NC 2L Standards in samples collected from the corrective action monitoring wells during this sampling event.

5.2 Monitored Natural Attenuation Evaluation
In accordance with the CAPMP, monitoring wells MW-2, MW-3, MW-5, MW-7, MW-8, MW-10S, MW-10D, and MW-11S
serve as performance evaluation wells to assess the effectiveness of the MNA processes in reducing concentrations of
COCs at the site. These monitoring wells were selected as they are located in the areas designated for corrective action
by MNA in the approved CAP. The May 2023 analytical data for these monitoring wells were evaluated using the US
EPA’s ”Natural Attenuation Screening Protocol (1998)” tool.

First Semi-Annual 2023 Water Quality Monitoring Report Project No. 31404568.018
Randolph County Landfill
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Based on EPA screening protocols, monitoring wells MW-10S and MW-10D received scores of 29 and 20, respectively,
which indicates adequate to strong evidence for anaerobic biodegradation of chlorinated organics (EPA, 1998).
Monitoring wells MW-2, MW-3, MW-7, MW-8, and MW-11S received scores of 16, 13, 21, 11, and 17, respectively, which
indicate there is limited to strong evidence for anaerobic biodegradation of chlorinated organics (EPA, 1998). As
presented, monitoring well MW-5 (i.e., the background well) was not sampled during this event due to an inadequate
volume of groundwater. The natural attenuation screening protocol forms are included in Appendix C.

Based on the results of the screening protocol, there is evidence that anaerobic natural attenuation is occurring at the site.
Therefore, modeling was performed on the May 2023 data to simulate remediation by natural attenuation using the
BIOCHLOR screening model (EPA, 2000). Because three plumes with NC 2L Standard exceedances were identified in
the NES, each plume was modeled separately. However, the north plume was not modeled during this event because
tetrachloroethene, trichloroethene, dichloroethene (e.g., cis- and trans-), and vinyl chloride were not detected in samples
collected from MW-2 and MW-11S. Modeling parameters for advection, dispersion, and modeled area were the same as
previous models performed for the site. A 41-year simulation period was selected for the model, representing the time at
which waste was first placed in the landfill (i.e., the original source): it is assumed that waste was first accepted in 1981
per the approved CAP (Golder, 2015).

The May 2023 results represent current conditions at the facility and therefore, the models were calibrated to the current
sample results by adjusting the biotransformation data within a prescribed range specified by literature values within the
BIOCHLOR program. Once the models were calibrated, a forecasted model was created by changing the simulation
period to 100 years to assess the size of the contaminant plume in the future. BIOCHLOR generates plots that compare
concentrations of tetrachloroethene, trichloroethene, dichloroethene, vinyl chloride, and ethene over time with no
degradation to concentrations where sequential 1st order decay is occurring. The plots are provided in Appendix C. The
centerline plots can be used to forecast the contaminant plume size over time.

For the plume located northeast of the waste unit, analytical data for samples collected from MW-8 and MW-3 were
modeled and are presented in Appendix C on Figures C-9 and C-10. Vinyl chloride and ethene were not detected in
samples collected from MW-8 and tetrachloroethene, trichloroethene, dichloroethane, vinyl chloride, and ethene were not
detected in samples collected from MW-3. Cis-1,2-dichloroethene detected in samples collected from MW-8 plot on or
below their respective 1st order sequential decay curves. The cis-1,2-dichloroethene variety was the prominent form of
dichloroethene, indicating that the detections represent daughter products of tetrachloroethene and/or trichloroethene.
The results from these plots indicate that natural attenuation is occurring in the northeast plume. According to the current
data and as indicated by the BIOCHLOR model, it is likely that the plume size has stabilized.

For the plume located west of the waste management unit, analytical data for samples collected from MW-10S, MW-10D,
and SW-2 were modeled and are presented in Appendix C on Figures C-11 and C-12. Ethene was not detected in
samples collected from MW-10S; tetrachloroethene and trichloroethene were not detected in samples collected from
MW-10D; and tetrachloroethene, trichloroethene, dichloroethene, vinyl chloride, and ethene were not detected in samples
collected from SW-2. The concentrations of tetrachloroethene and dichloroethene in samples collected from MW-10S plot
below their respective 1st order sequential decay curve. The cis-1,2-dichloroethene isomer was again the prominent form
of dichloroethene, indicating that the detections represent daughter products of tetrachloroethene and/or trichloroethene.
Concentrations or vinyl chloride and ethene in samples collected from MW-10D plot below their respective 1st order
sequential decay curve. The results from these plots indicate that natural attenuation is occurring in the western plume.

According to the current data and as indicated by the BIOCHLOR model, it is likely that the plume size has stabilized.
Because of the low concentration of parent compounds and multiple degradation pathways for cis-1,2-dichloroethene
(aerobic and anaerobic), there are limited concentrations of vinyl chloride and ethene in each of the plumes evaluated.
The

First Semi-Annual 2023 Water Quality Monitoring Report Project No. 31404568.018
Randolph County Landfill
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Page 10
concentration trends show that cis-1,2-dichloroethene is not accumulating and that degradation of the chlorinated
compounds is continuing.

6.0 CONCLUSIONS
The results of the first semi-annual water quality monitoring event of 2023, shows continued evidence of natural
attenuation of VOCs in groundwater at the site. Evidence suggests that MNA continues to be a viable remedy. However,
due to the continued presence of VOCs above applicable groundwater standards, the Randolph County Landfill will
continue to be monitored in accordance with the requirements of the Assessment Monitoring Program as outlined in Title
15A NCAC 13B .1634. The next compliance and MNA monitoring event for this facility is tentatively scheduled for October
2023.

First Semi-Annual 2023 Water Quality Monitoring Report Project No. 31404568.018
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7.0 REFERENCES

Butler, J.R., and D.T. Secor, Jr., 1991, The Central Piedmont (Chapter 4) in J.W. Horton, Jr. and V.A. Zullo, eds., The
Geology of the Carolinas (Carolina Geological Society Fiftieth Anniversary Volume), The University of Tennessee Press,
pp. 66-71.

Carolina Piedmont, Department of Environment and Natural Resources, Groundwater Section, Resource Evaluation
Program Mooresville Regional Office.
EPA (United States Environmental Protection Agency), 1998, Technical Protocol for Evaluating Natural Attenuation of
Chlorinated Solvents in Ground Water, September, 1998
EPA (United States Environmental Protection Agency), 2003, Guidance for Developing Ecological Soil Screening Levels,
November 2003. Table 2.3.

Golder Associates, 2015, Corrective Action Plan, Randolph County Closed Municipal Solid Waste Landfill, Permit No. 76-
01, July 2015.

H&S (Hazen and Sawyer), 1994, Transition Plan - Randolph County Landfill, October 8, 1994, including the 1995 Water
Quality Monitoring Plan references.

H&S (Hazen and Sawyer), 1997, Randolph County Landfill Groundwater Monitoring Data H&S No. 3796, December 4,
1997.

H&S (Hazen and Sawyer), 1995. Baseline Groundwater Monitoring—Randolph County MSW-Landfill, October 19, 1995.
Johnson, A.I., 1967, Specific Yield – Compilation of Specific Yields for Various Materials: U.S. Geological Survey
Water Supply Paper 1662-D.

NCGS (North Carolina Geologic Survey), 1985. Geologic Map of North Carolina.

Pippin, Charles, et al., October 3, 2003, Distribution of Total Arsenic in Groundwater in the North.

Wang, Shuying et al., 2008. GSA (Geological Society of America), “Petrologic and Hydrogeologic Characteristics of a
Felsic Metavolcanic Tuff Hydrogeologic Unit in the Carolina Terrane: Preliminary Findings from the NC Zoo Groundwater
Research Station, Asheboro, Randolph County, NC” from Abstracts with Programs, Vol. 40, No. 4, p. 53.

TABLES

September 2023 31404568.018
TOC Elevation (ft AMSL)
Date GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW
MEAN 594.48 16.49 569.23 13.52 565.85 21.48 703.38 15.72 662.14 60.53 613.92 11.02 566.36 20.61 579.71 15.02 597.37 20.42 584.05 12.87 588.75 7.97 566.04 11.69 565.37 12.20 615.33 9.29 636.36 5.18 682.57 12.19MAXIMUM598.32 20.93 578.40 26.76 571.32 26.49 716.89 27.65 673.00 69.25 617.55 15.64 570.85 25.15 585.57 23.99 603.09 25.62 585.83 16.16 591.52 9.96 570.11 15.20 568.64 15.04 618.80 13.37 637.72 5.64 689.33 18.41MINIMUM590.04 12.65 555.99 4.35 560.84 16.01 691.45 2.21 653.42 49.67 609.32 7.41 561.82 16.12 570.74 9.16 592.17 14.70 580.76 11.09 586.72 5.16 562.53 7.62 562.53 8.93 611.25 5.82 635.90 3.82 676.35 5.43MAX-MEAN 3.84 4.44 9.17 13.24 5.47 5.01 13.51 11.93 10.86 8.72 3.63 4.62 4.49 4.54 5.86 8.97 5.72 5.20 1.78 3.29 2.77 1.99 4.07 3.51 3.27 2.84 3.47 4.08 1.36 0.46 6.76 6.22MAX-MIN 8.28 8.28 22.41 22.41 10.48 10.48 25.44 25.44 19.58 19.58 8.23 8.23 9.03 9.03 14.83 14.83 10.92 10.92 5.07 5.07 4.80 4.80 7.58 7.58 6.11 6.11 7.55 7.55 1.82 1.82 12.98 12.98
MW-5 MW-11SMW-10DMW-10S MW-A1MW-11D
624.62577.57577.73596.68596.92610.97 582.75
MW-1 MW-4MW-3MW-2 MW-9MW-8MW-7MW-6 MW-A3MW-A2
1 of 1
September 2023 31404568.018
Gradient Calculation
Segment Flow Direction Length (feet)Elevations (feet)
Horizontal Gradient
(i, feet)Porosity Conductivity Velocity
(Vgw, feet/year)
640
580
640
570
640
580
Notes:
Value for K is from Wang and others, 2008.
Groundwater Monitoring Data.
2.75E-04 105.80
161.43i3ENE7050.0851 0.15 2.75E-04
i 2 NE 1255 0.0558 0.15
TABLE 2
Summary of Estimated Horizontal Flow Velocities
Closed Randolph County Landfill, Permit No. 76-01
May 2023
i 1 NNE 1081 0.0555 0.15 2.75E-04 105.28
1 of 1
September 2023 31404568.018
Northing Easting
MW-1 May 1993 730969.68 1773296.52 609.21 610.97 24.0 2 585.21 - 600.21 NA Water Levels Only
MW-2 June 1987 731522.48 1774019.99 580.97 582.75 33.0 2 547.97 - 567.97 NA Corrective Action Well
MW-3 September 1987 730771.64 1774456.14 585.17 587.33 30.0 2 555.17 - 575.17 NA Corrective Action Well
MW-4 September 1987 729062.23 1773249.03 716.53 719.10 47.5 2 669.03 - 699.03 NA Water Levels Only
MW-5 September 17, 1994 729547.38 1773540.91 720.55 722.67 68.5 2 652.05 - 667.05 Bedrock Compliance Well
MW-6 September 12, 1994 730556.43 1772967.50 622.96 624.96 17.8 2 605.46 - 615.46 Saprolite / Bedrock Compliance Well
MW-7 September 12, 1994 731476.90 1774015.84 585.14 586.97 26.0 2 560.14 - 575.14 Saprolite Compliance Well
MW-8 September 1994 730738.59 1774321.51 592.68 594.73 29.0 2 564.68 - 579.68 NA Compliance Well
MW-9 September 13, 2014 729956.09 1774063.62 615.93 617.79 33.0 2 582.93 - 597.93 Saprolite / PWR Compliance Well
MW-10S December 8, 2010 731020.76 1773274.20 594.48 596.92 25.0 2 569.48 - 584.48 Saprolite Compliance Well
MW-10D December 7, 2010 731017.22 1773270.37 594.56 596.80 73.0 2 521.56 - 531.56 Bedrock Corrective Action Well
MW-11S December 1, 2010 731567.02 1774109.06 574.88 577.73 25.0 2 549.88 - 559.88
MW-11D December 2, 2010 731572.75 1774116.06 574.64 577.57 65.0 2 509.64 - 519.64 Bedrock Water Levels Only
MW-A1 June 1993 730435.04 1772857.60 623.50 624.62 15.0 2 611.00 - 622.00 NA Water Levels Only
MW-A2 May 1993 728762.14 1772787.17 639.41 641.54 17.5 2 623.41 - 639.41 NA Water Levels Only
MW-A3 June 1993 729065.19 1772398.70 693.14 694.76 32.0 2 663.14 - 683.14 NA Water Levels Only
Notes:ft AMSL = feet above mean sea level
ft bgs = feet below ground surface
TOC = Top of Well Casing Elevation
NA = no data available
PWR = partially weathered rock
Well construction informationfor all wells installed prior to 2010 provided by Hazen & Sawyer and Randolph County.
Groundwater Monitoring Network Information:
MW-5 is the facility's background well.
MW-2 was replaced by MW-7.
MW-3 was replaced by MW-8.
MW-4 was replaced by MW-5.
MW-A1 was replaced by MW-6.
TABLE 3
Summary of Well Construction Information
Closed Randolph County Landfill, Permit No. 76-01
Well
Identification
Surface
Elevation
TOCElevation(ft AMSL)
WellDepth(ft bgs)
WellDiameter(inches)
Screened
Interval(ft AMSL)
Well
Status
Geology of
Screened IntervalDate of Construction Coordinates
1 of 1
September 2023 31404568.018
MW-5 MW-6 MW-7 MW-8 MW-9 MW-10S
3.38 J --ND
1.18 J ND ND --ND
1.02 J 1.02 J 2.91 J ND 0.428 J 0.413 J ND
12 ND ND --ND
13 ND ND ND --ND
Summary of Historical Groundwater Monitoring Results
TABLE 4
Closed Randolph County Landfill, Permit No. 76-01
SWS Reporting Limit
Detected Monitoring
Constituent/Parameter Units Date BlanksDetection Limit
Downgradient WellsUpgradient WellQuanitation Limit
1 of 20
September 2023 31404568.018
MW-5 MW-6 MW-7 MW-8 MW-9 MW-10S
Summary of Historical Groundwater Monitoring Results
TABLE 4
Closed Randolph County Landfill, Permit No. 76-01
SWS Reporting Limit
Detected Monitoring
Constituent/Parameter Units Date BlanksDetection Limit
Downgradient WellsUpgradient WellQuanitation Limit
Barium ug/L 09/22/94 ----500 ND ND ND ND ND --NDNC 2L = 700 ug/L ug/L 11/08/94 ----500 ND ND ND ND ND --NDEPA MCL = 2000 ug/L ug/L 01/18/95 ----500 ND ND ND ND ND --NDug/L 04/23/96 ----500 ND ND ND ND ND --NDug/L 06/17/97 ----500 ND ND ND ND ND --NDug/L 10/16/97 ----500 ND ND ND ND ND --NDug/L 04/21/98 ----500 ND ND ND ND ND --NDug/L 04/07/99 ----500 ND ND ND ND ND --ND
ug/L 10/13/99 ----500 ND ND ND ND ND --NDug/L 04/05/00 ----500 ND ND ND ND ND --NDug/L 10/25/00 ----500 ND ND ND ND ND --NDug/L 04/04/01 ----500 ND ND ND ND ND --NDug/L 04/08/02 ----500 ND ND ND ND ND --NDug/L 10/21/02 ----500 ND ND ND ND ND --NDug/L 04/14/03 ----500 ND ND ND ND ND --NDug/L 10/01/03 ----500 ND ND ND ND ND --NDug/L 04/05/04 ----500 ND ND ND ND ND --NDug/L 10/18/04 ----500 ND ND ND ND ND --NDug/L 04/07/05 ----500 ND ND ND ND ND --NDug/L 10/06/05 ----500 ND ND ND ND ND --ND
ug/L 04/03/06 ----500 ND ND ND ND ND --NDug/L 10/03/06 ----500 ND ND ND ND ND --NDug/L 04/05/07 ----100 ND ND ND ND ND --NDug/L 10/18/07 ----100 1.2 J 54.4 J --1.2 J 4.6 J --0.04 Jug/L 04/29/08 ----100 4.0 J 13.6 J 1.4 J 2.4 J 7.9 J --0.2 Jug/L 10/23/08 ----100 ND 21.4 J 1.90 J 3.10 J 5.70 J --NDug/L 04/07/09 ----100 ND 16.9 J ND ND 9.48 J --NDug/L 10/19/09 ----100 1.81 J 21.3 J 2.84 J 1.61 J 6.45 J --NDug/L 04/28/10 ----100 1.77 J 34.2 J 1.81 J 2.95 J 14.1 J --NDug/L 10/12/10 ----100 1.74 J 18.7 J 2.22 J 2.03 J 5.67 J --NDug/L 04/11/11 ----100 2.68 J 18.9 J 1.94 J 2.57 J 10.2 J --NDug/L 10/04/11 ----100 3.26 J 23.7 J 2.84 J 2.09 J 6.87 J --NDug/L 04/10/12 ----100 ND 12.4 J 2.95 J 2.66 J 14.6 J --ND
ug/L 10/15/12 ----100 1.17 B 26.5 J 6.52 J 2.09 B 7.01 J --1.04 Jug/L 04/09/13 ----100 2.03 J 12.2 J 1.95 J 3.00 J 10.1 J --NDug/L 10/08/13 ----100 3.32 J 22.7 J 2.95 J 2.75 J 8.38 J --NDug/L 04/08/14 ----100 2.10 B 9.36 J 1.82 B 3.38 B 13.6 J --1.09 Jug/L 10/08/14 1.0 --100 4.33 B 24.7 J 2.43 B 3.40 B 6.83 B --3.14 Jug/L 04/08/15 1.0 --100 3.05 J 12.8 J 2.21 J 2.86 J 9.99 J --NDug/L 10/28/15 1.0 --100 1.93 B 19.6 J 2.21 B 2.17 B 6.98 J 4.44 B 1.20 Jug/L 04/05/16 1.0 --100 2.54 J 8.85 J 1.77 J 2.19 J 13.4 J 4.62 J NDug/L 10/04/16 1.0 --100 1.40 J 19.8 J 2.44 J 2.91 J 7.60 J 5.33 J NDug/L 04/03/17 1.0 --100 ND 18.9 J ND 2.53 J 8.82 J 4.93 J NDug/L 10/03/17 1.0 --100 1.52 B 15.4 J 2.20 B 2.17 B 5.52 B 4.91 B 2.77 Jug/L 05/22/18 1.0 --100 1.27 J 9.35 J 1.91 J 2.50 J 8.57 J 4.61 J ND
ug/L 10/23/18 1.1 10 --4.27 J 30.0 2.33 J 2.80 J 7.81 J 5.43 J ND
5 ND --ND
11 ND ND ND --ND5NDNDND--ND
2 of 20
September 2023 31404568.018
MW-5 MW-6 MW-7 MW-8 MW-9 MW-10S
Summary of Historical Groundwater Monitoring Results
TABLE 4
Closed Randolph County Landfill, Permit No. 76-01
SWS Reporting Limit
Detected Monitoring
Constituent/Parameter Units Date BlanksDetection Limit
Downgradient WellsUpgradient WellQuanitation Limit
Cadmium ug/L 09/22/94 ----1 ND ND ND ND ND --NDNC 2L = 2 ug/L ug/L 11/08/94 ----1 ND ND ND ND ND --NDEPA MCL = 5 ug/L ug/L 01/18/95 ----1 ND ND ND ND ND --NDug/L 04/23/96 ----1 1 ND ND ND 1 --NDug/L 06/17/97 ----1 ND ND ND ND ND --NDug/L 10/16/97 ----1 ND ND ND ND ND --NDug/L 04/21/98 ----1 ND ND ND ND ND --NDug/L 04/07/99 ----1 ND ND ND ND ND --ND
ug/L 10/13/99 ----1 ND ND ND ND ND --NDug/L 04/05/00 ----1 ND ND ND ND ND --NDug/L 10/25/00 ----1 ND ND ND ND ND --NDug/L 04/04/01 ----1 ND ND ND ND ND --NDug/L 04/08/02 ----1 ND ND ND ND ND --NDug/L 10/21/02 ----1 3 ND ND ND ND --NDug/L 04/14/03 ----1 2 ND ND ND ND --NDug/L 10/01/03 ----1 ND ND ND ND ND --NDug/L 04/05/04 ----1 1 ND ND ND ND --NDug/L 10/18/04 ----1 ND ND ND ND ND --NDug/L 04/07/05 ----1 ND ND ND ND ND --NDug/L 10/06/05 ----1 ND ND ND ND ND --ND
ug/L 04/03/06 ----1 ND 1 ND ND ND --NDug/L 10/03/06 ----1 2 ND ND ND ND --NDug/L 04/05/07 ----1 ND ND ND ND ND --NDug/L 10/18/07 ----1 0.5 J 1 --0.1 J 0.1 J --NDug/L 04/29/08 ----1 ND ND ND ND ND --NDug/L 10/23/08 ----1 ND ND ND ND ND --NDug/L 04/07/09 ----1 0.37 J ND 0.37 J ND 0.11 J --NDug/L 10/19/09 ----1 ND ND 0.640 J ND ND --NDug/L 04/28/10 ----1 ND ND ND ND ND --NDug/L 10/12/10 ----1 ND ND 0.501 J ND ND --NDug/L 04/11/11 ----1 ND ND ND ND ND --NDug/L 10/04/11 ----1 ND ND 0.429 J ND ND --NDug/L 04/10/12 ----1 ND ND 0.758 J ND ND --ND
ug/L 10/15/12 ----1 ND ND 0.730 B ND ND --0.433 Jug/L 04/09/13 ----1 ND ND 0.421 J ND ND --NDug/L 10/08/13 ----1 ND ND 0.446 J ND ND --NDug/L 04/08/14 ----1 ND ND 0.467 J ND ND --NDug/L 10/08/14 0.36 --1 ND 0.530 J 0.488 J ND ND --NDug/L 04/08/15 0.36 --1 ND ND ND ND ND --0.427 Jug/L 10/28/15 0.36 --1 ND ND 0.539 J ND ND ND NDug/L 04/05/16 0.36 --1 ND ND ND ND ND ND NDug/L 10/04/16 0.36 --1 ND ND 0.481 J ND ND ND NDug/L 04/03/17 0.36 --1 ND ND 0.536 J ND ND ND NDug/L 10/03/17 0.36 --1 ND ND ND ND ND ND NDug/L 05/22/18 0.36 --1 ND ND ND ND ND ND NDug/L 10/23/18 0.36 1 --ND ND ND ND ND ND ND
ug/L 04/16/19 0.36 1 --ND ND ND ND ND ND NDug/L 10/15/19 0.36 1 --ND 0.435 J ND ND ND ND NDug/L 04/14/20 0.36 1 --ND ND 0.429 J ND ND ND NDug/L 10/07/20 0.36 1 --ND ND 0.364 J ND ND ND NDug/L 05/10/21 0.36 1 --ND ND ND ND ND ND NDug/L 10/06/21 0.36 1 --ND ND ND ND ND ND NDug/L 05/17/22 0.36 1 --ND ND ND ND ND ND NDug/L 10/10/22 0.44 5 --DRY ND ND ND ND ND NDug/L 05/22/23 0.44 5 --DRY ND 0.5 J ND ND ND NDChromiumug/L 09/22/94 ----10 ND ND ND ND ND --NDNC 2L = 10 ug/L ug/L 11/08/94 ----10 ND ND ND ND ND --NDEPA MCL = 100 ug/L ug/L 01/18/95 ----10 ND ND ND ND ND --ND
ug/L 04/23/96 ----10 ND ND ND ND ND --NDug/L 06/17/97 ----10 ND ND ND 18 ND --NDug/L 10/16/97 ----10 ND ND 22 22 ND --NDug/L 04/21/98 ----10 ND ND ND ND ND --NDug/L 04/07/99 ----10 ND 28 ND ND ND --NDug/L 10/13/99 ----10 ND 81 ND 12 ND --NDug/L 04/05/00 ----10 ND 45 ND 15 ND --NDug/L 10/25/00 ----10 ND 152 23 24 ND --NDug/L 04/04/01 ----10 ND 104 ND 40 ND --NDug/L 04/08/02 ----10 ND 212 ND 33 ND --NDug/L 10/21/02 ----10 12 77 ND 14 ND --NDug/L 04/14/03 ----10 ND 94 ND ND ND --ND
ug/L 10/01/03 ----10 ND 28 11 43 ND --NDug/L 04/05/04 ----10 ND 14 ND ND 11 --NDug/L 10/18/04 ----10 ND 47 ND 12 ND --NDug/L 04/07/05 ----10 ND 21 ND ND ND --NDug/L 10/06/05 ----10 ND 26 ND ND ND --NDug/L 04/03/06 ----10 ND 28 ND ND ND --NDug/L 10/03/06 ----10 ND 12 ND ND ND --NDug/L 04/05/07 ----10 ND ND ND ND ND --NDug/L 10/18/07 ----10 0.4 J 8.6 J --ND ND --NDug/L 04/29/08 ----10 3.5 J ND ND ND ND --NDug/L 10/23/08 ----10 ND ND ND ND ND --NDug/L 04/07/09 ----10 0.8 J 1.4 J ND ND ND --NDug/L 10/19/09 ----10 ND ND 1.19 J ND ND --ND
ug/L 04/28/10 ----10 ND ND ND ND ND --NDug/L 10/12/10 ----10 ND ND ND ND ND --NDug/L 04/11/11 ----10 ND 1.88 J 3.98 J 4.25 J 4.16 J --NDug/L 10/04/11 ----10 1.03 J ND ND ND ND --NDug/L 04/10/12 ----10 ND ND ND ND ND --NDug/L 10/15/12 ----10 ND ND 3.03 J ND 1.13 J --NDug/L 04/09/13 ----10 ND 4.21 J ND ND ND --NDug/L 10/08/13 ----10 ND ND ND ND ND --NDug/L 04/08/14 ----10 1.68 J 1.41 J ND ND ND --NDug/L 10/08/14 1.4 --10 2.42 J 1.57 J ND ND ND --NDug/L 04/08/15 1.4 --10 ND ND ND ND ND --NDug/L 10/28/15 1.4 --10 ND ND ND ND ND ND ND
ug/L 04/05/16 1.4 --10 ND ND ND ND ND ND NDug/L 10/04/16 1.4 --10 ND 1.92 J ND ND ND ND NDug/L 04/03/17 1.4 --10 ND ND ND 3.01 B ND ND 4.45 Jug/L 10/03/17 1.4 --10 2.36 J ND ND ND ND ND NDug/L 05/22/18 1.4 --10 ND 1.59 J ND ND ND ND ND
ug/L 10/23/18 1.4 10 --2.15 J ND ND ND ND ND ND
10.5 (ND)ND ND 8.36 J ND
3 of 20
September 2023 31404568.018
MW-5 MW-6 MW-7 MW-8 MW-9 MW-10S
Summary of Historical Groundwater Monitoring Results
TABLE 4
Closed Randolph County Landfill, Permit No. 76-01
SWS Reporting Limit
Detected Monitoring
Constituent/Parameter Units Date BlanksDetection Limit
Downgradient WellsUpgradient WellQuanitation Limit
Cobalt ug/L 09/22/94 ----10 ND ND ND ND ND --NDNC 2L = 1 ug/L ug/L 11/08/94 ----10 ND 15 ND ND ND --ND(No EPA MCL)ug/L 01/18/95 ----10 ND ND ND ND ND --NDug/L 04/23/96 ----10 ND ND ND ND ND --NDug/L 06/17/97 ----10 ND 10 ND 25 ND --NDug/L 10/16/97 ----10 ND ND 17 18 ND --NDug/L 04/21/98 ----10 ND ND ND ND ND --NDug/L 04/07/99 ----10 ND 15 ND ND ND --ND
ug/L 10/13/99 ----10 ND 39 ND 10 ND --NDug/L 04/05/00 ----10 ND 21 ND 13 ND --NDug/L 10/25/00 ----10 ND 54 26 20 ND --NDug/L 04/04/01 ----10 ND 41 ND 35 ND --NDug/L 04/08/02 ----10 ND 78 ND 21 ND --NDug/L 10/21/02 ----10 19 39 ND 12 ND --NDug/L 04/14/03 ----10 10 42 ND ND ND --NDug/L 10/01/03 ----10 ND 19 16 46 ND --NDug/L 04/05/04 ----10 ND ND ND ND ND --NDug/L 10/18/04 ----10 ND 44 ND ND ND --NDug/L 04/07/05 ----10 ND 10 ND ND ND --NDug/L 10/06/05 ----10 ND ND ND ND ND --ND
ug/L 04/03/06 ----10 ND 11 ND ND ND --NDug/L 10/03/06 ----10 ND ND ND ND ND --NDug/L 04/05/07 ----10 ND ND ND ND ND --NDug/L 10/18/07 ----10 ND 3.5 J --ND ND --NDug/L 04/29/08 ----10 7.0 J ND 5.7 J ND ND --NDug/L 10/23/08 ----ND ND 6.8 J ND ND --NDug/L 04/07/09 ----10 ND 0.6 J 4.9 J ND ND --NDug/L 10/19/09 ----10 ND ND 6.86 J ND ND --NDug/L 04/28/10 ----10 ND ND 5.99 J ND ND --NDug/L 10/12/10 ----10 ND ND 3.67 J ND ND --NDug/L 04/11/11 ----10 ND ND 6.60 J ND ND --NDug/L 10/04/11 ----10 ND ND 4.13 J ND ND --NDug/L 04/10/12 ----10 ND ND 5.97 J ND ND --ND
ug/L 10/15/12 ----10 ND ND 6.68 J ND ND --NDug/L 04/09/13 ----10 ND ND 5.88 J ND ND --NDug/L 10/08/13 ----10 ND ND 6.44 J ND ND --NDug/L 04/08/14 ----10 ND 1.18 J 5.77 J ND ND --NDug/L 10/08/14 1.1 --10 ND ND 9.68 J ND ND --NDug/L 04/08/15 1.1 --10 ND ND 6.06 J ND ND --NDug/L 10/28/15 1.1 --10 ND ND 6.29 J ND ND 1.24 J NDug/L 04/05/16 1.1 --10 1.56 J ND 5.72 J ND ND 2.86 J NDug/L 10/04/16 1.1 --10 ND ND 6.06 J ND ND 2.54 J NDug/L 04/03/17 1.1 --10 ND 1.24 J 5.17 J ND ND 1.56 J NDug/L 10/03/17 1.1 --10 ND ND 5.74 J 1.17 J ND ND NDug/L 05/22/18 1.1 --10 ND ND 6.61 J ND ND 1.72 J NDug/L 10/23/18 1.4 10 --2.94 J 4.71 J 6.03 J ND ND 2.24 J ND
ug/L 04/16/19 1.4 10 --ND ND 7.59 J ND ND ND NDug/L 10/15/19 1.4 10 --ND 1.89 J 5.40 J ND ND ND NDug/L 04/14/20 1.4 10 --ND ND 10.6 (8.83)(J)ND ND ND NDug/L 10/07/20 1.4 10 --ND 9.24 J 4.42 J ND ND ND NDug/L 05/10/21 1.4 10 --ND ND 11.6 2.51 J ND ND NDVerification Event ug/L 08/19/21 1.4 10 ------7.39 J --------ug/L 10/06/21 1.4 10 --ND 2.86 J 6.53 J ND ND ND NDug/L 05/17/22 1.4 10 --ND ND 12.1 ND ND ND NDVerification Event ug/L 08/22/22 1.4 10 ------7.51 J --------Dissolved ug/L 08/22/22 1.4 10 ------6.50 J --------ug/L 10/10/22 1.4 10 --DRY 4.00 J 4.90 J ND ND ND NDug/L 05/22/23 1.4 10 --DRY 1.56 J 10.9 ND ND ND ND
Copper ug/L 09/22/94 ----200 ND ND ND ND ND --NDNC 2L = 1000 ug/L ug/L 11/08/94 ----200 ND ND ND ND ND --NDEPA MCL = 1300 ug/L#ug/L 01/18/95 ----200 ND ND ND ND ND --NDug/L 04/23/96 ----200 ND ND ND ND ND --NDug/L 06/17/97 ----200 ND 341 ND 437 ND --NDug/L 10/16/97 ----200 ND ND ND ND ND --NDug/L 04/21/98 ----200 ND ND ND ND ND --NDug/L 04/07/99 ----200 ND ND ND ND ND --NDug/L 10/13/99 ----200 ND 216 ND ND ND --NDug/L 04/05/00 ----200 ND ND ND ND ND --NDug/L 10/25/00 ----200 210 ND ND ND ND --NDug/L 04/04/01 ----200 ND ND ND ND ND --ND
ug/L 04/08/02 ----200 ND 334 ND ND ND --NDug/L 10/21/02 ----200 ND ND ND ND ND --NDug/L 04/14/03 ----200 ND ND ND ND ND --NDug/L 10/01/03 ----200 ND ND ND ND ND --NDug/L 04/05/04 ----200 ND ND ND ND ND --NDug/L 10/18/04 ----200 ND ND ND ND ND --NDug/L 04/07/05 ----200 ND ND ND ND ND --NDug/L 10/06/05 ----200 ND ND ND ND ND --NDug/L 04/03/06 ----200 ND ND ND ND ND --NDug/L 10/03/06 ----200 ND ND ND ND ND --NDug/L 04/05/07 ----10 ND ND ND ND ND --NDug/L 10/18/07 ----10 1.6 B 13 --0.3 B 0.2 B --0.7 Jug/L 04/29/08 ----10 10.5 2.4 B ND 1.2 B ND --0.9 J
ug/L 10/23/08 ----10 ND ND ND ND ND --NDug/L 04/07/09 ----10 ND 1.61 J ND ND ND --NDug/L 10/19/09 ----10 ND ND ND ND ND --1.60 Jug/L 04/28/10 ----10 ND ND ND ND ND --NDug/L 10/12/10 ----10 ND 2.72 B ND ND ND --1.60 Jug/L 04/11/11 ----10 ND 3.18 J ND 1.85 J ND --NDug/L 10/04/11 ----10 ND ND ND ND ND --NDug/L 04/10/12 ----10 ND ND 6.48 J ND ND --NDug/L 10/15/12 ----10 ND ND 7.40 J ND ND --NDug/L 04/09/13 ----10 ND 4.04 J ND ND ND --NDug/L 10/08/13 ----10 ND ND ND ND ND --NDug/L 04/08/14 ----10 ND ND ND ND ND --ND
ug/L 10/08/14 1.6 --10 ND 3.87 J ND 2.42 J ND --NDug/L 04/08/15 1.6 --10 ND ND ND ND ND --3.01 Jug/L 10/28/15 1.6 --10 ND ND ND ND ND ND NDug/L 04/05/16 1.6 --10 2.12 B 1.65 B ND ND ND ND 3.64 Jug/L 10/04/16 1.6 --10 7.33 B 7.07 B 3.76 B 2.54 B 4.65 B 3.38 B 5.15 Jug/L 04/03/17 1.6 --10 ND 4.23 B ND ND 4.00 B ND 3.21 Jug/L 10/03/17 1.6 --10 2.14 B 4.40 B ND 3.61 B 2.00 B ND 4.84 Jug/L 05/22/18 1.6 --10 ND 3.66 J ND ND ND ND NDug/L 10/23/18 1.6 10 --ND ND ND ND ND ND 1.97 Jug/L 04/16/19 1.6 10 --ND ND ND ND ND ND NDug/L 10/15/19 1.6 10 --ND 5.58 J ND 1.67 J ND ND NDug/L 04/14/20 1.6 10 --4.42 J ND ND ND 1.80 J ND NDug/L 10/07/20 1.6 10 --1.92 J 8.11 J ND 2.01 J ND ND ND
ug/L 05/10/21 1.6 10 --ND ND ND ND ND ND NDug/L 10/06/21 1.6 10 --ND 6.16 J ND ND ND ND NDug/L 05/17/22 1.6 10 --3.30 J 16.4 ND ND 12.4 ND NDug/L 10/10/22 3.2 20 --DRY 3.70 J ND ND ND ND NDug/L 05/22/23 3.2 20 --DRY 7.98 J ND ND ND ND ND
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Summary of Historical Groundwater Monitoring Results
TABLE 4
Closed Randolph County Landfill, Permit No. 76-01
SWS Reporting Limit
Detected Monitoring
Constituent/Parameter Units Date BlanksDetection Limit
Downgradient WellsUpgradient WellQuanitation Limit
Lead ug/L 09/22/94 ----10 ND ND ND ND ND --NDNC 2L = 15 ug/L ug/L 11/08/94 ----10 ND ND ND ND ND --NDEPA MCL = 15 ug/L#ug/L 01/18/95 ----10 ND ND ND ND ND --NDug/L 04/23/96 ----10 ND ND ND ND ND --NDug/L 06/17/97 ----10 ND 16 ND 31 11 --NDug/L 10/16/97 ----10 ND ND 13 19 ND --NDug/L 04/21/98 ----10 ND ND ND ND ND --NDug/L 04/07/99 ----10 ND 13 ND ND ND --ND
ug/L 10/13/99 ----10 ND 63 ND 13 ND --NDug/L 04/05/00 ----10 ND 12 ND ND ND --NDug/L 10/25/00 ----10 ND 75 12 15 ND --NDug/L 04/04/01 ----10 ND 3470 42 20 ND --NDug/L 04/08/02 ----10 ND 41 ND ND ND --NDug/L 10/21/02 ----10 ND 74 ND ND ND --NDug/L 04/14/03 ----10 ND 53 ND ND ND --NDug/L 10/01/03 ----10 ND ND 11 17 ND --NDug/L 04/05/04 ----10 ND ND ND ND ND --NDug/L 10/18/04 ----10 ND 119 ND ND ND --NDug/L 04/07/05 ----10 ND 46 ND ND ND --NDug/L 10/06/05 ----10 ND 41 ND 11 ND --ND
ug/L 04/03/06 ----10 ND 47 ND ND ND --NDug/L 10/03/06 ----10 ND 13 ND ND ND --NDug/L 04/05/07 ----10 ND ND ND ND ND --NDug/L 10/18/07 ----10 0.1 J 8.4 J --0.1 J ND --NDug/L 04/29/08 ----10 3.6 J ND ND ND ND --NDug/L 10/23/08 ----10 ND ND ND ND ND --NDug/L 04/07/09 ----10 ND ND ND ND ND --NDug/L 10/19/09 ----10 ND ND ND ND ND --NDug/L 04/28/10 ----10 ND ND ND ND ND --NDug/L 10/12/10 ----10 ND ND ND ND ND --NDug/L 04/11/11 ----10 ND ND ND ND ND --NDug/L 10/04/11 ----10 ND ND ND ND ND --NDug/L 04/10/12 ----10 ND ND ND 3.93 B 2.38 B --2.22 J
ug/L 10/15/12 ----10 ND ND 2.55 J ND ND --NDug/L 04/09/13 ----10 ND ND ND ND ND --NDug/L 10/08/13 ----10 ND ND ND ND ND --NDug/L 04/08/14 ----10 ND ND ND ND ND --NDug/L 10/08/14 2.1 --10 ND ND ND ND ND --NDug/L 04/08/15 2.1 --10 ND ND ND ND ND --NDug/L 10/28/15 2.1 --10 ND ND ND ND ND ND NDug/L 04/05/16 3.1 --10 ND ND ND ND ND ND NDug/L 10/04/16 3.1 --10 ND ND ND ND ND ND NDug/L 04/03/17 3.1 --10 ND ND ND ND ND ND NDug/L 10/03/17 3.1 --10 ND ND ND ND ND ND NDug/L 05/22/18 3.1 --10 ND ND ND ND ND ND ND
ug/L 10/23/18 3.1 10 --ND ND ND ND ND ND ND
3.8 --ND1.4 --ND2.0 --ND
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Summary of Historical Groundwater Monitoring Results
TABLE 4
Closed Randolph County Landfill, Permit No. 76-01
SWS Reporting Limit
Detected Monitoring
Constituent/Parameter Units Date BlanksDetection Limit
Downgradient WellsUpgradient WellQuanitation Limit
Selenium ug/L 09/22/94 ----20 ND ND ND ND ND --NDNC 2L = 20 ug/L ug/L 11/08/94 ----20 ND ND ND ND ND --NDEPA MCL = 50 ug/L ug/L 01/18/95 ----20 ND ND ND ND ND --NDug/L 04/23/96 ----20 ND ND ND ND ND --NDug/L 06/17/97 ----20 ND ND ND ND ND --NDug/L 10/16/97 ----20 ND ND ND ND ND --NDug/L 04/21/98 ----20 ND ND ND ND ND --NDug/L 04/07/99 ----20 ND ND ND ND ND --ND
ug/L 10/13/99 ----20 ND ND ND ND ND --NDug/L 04/05/00 ----20 ND ND ND ND ND --NDug/L 10/25/00 ----20 ND ND ND ND ND --NDug/L 04/04/01 ----20 ND ND ND ND ND --NDug/L 04/08/02 ----20 ND ND ND ND ND --NDug/L 10/21/02 ----20 ND ND ND ND ND --NDug/L 04/14/03 ----20 ND ND ND ND ND --NDug/L 10/01/03 ----20 ND ND ND ND ND --NDug/L 04/05/04 ----20 ND ND ND ND ND --NDug/L 10/18/04 ----20 ND ND ND ND ND --NDug/L 04/07/05 ----20 ND ND ND ND ND --NDug/L 10/06/05 ----20 ND ND ND ND ND --ND
ug/L 04/03/06 ----20 ND ND ND ND ND --NDug/L 10/03/06 ----20 ND ND ND ND ND --NDug/L 04/05/07 ----10 ND ND ND ND ND --NDug/L 10/18/07 ----10 0.9 J ND --ND ND --NDug/L 04/29/08 ----10 ND ND ND ND ND --3.9 Jug/L 10/23/08 ----10 ND ND ND ND ND --NDug/L 04/07/09 ----10 ND ND ND ND ND --3.7 Jug/L 10/19/09 ----10 ND ND ND ND ND --NDug/L 04/28/10 ----10 ND ND ND ND ND --NDug/L 10/12/10 ----10 ND ND ND ND ND --NDug/L 04/11/11 ----10 ND ND ND ND ND --2.85 Jug/L 10/04/11 ----10 ND ND ND ND ND --NDug/L 04/10/12 ----10 ND ND ND ND ND --ND
ug/L 10/15/12 ----10 ND ND ND ND ND --NDug/L 04/09/13 ----10 ND ND ND ND ND --NDug/L 10/08/13 ----10 ND ND ND ND ND --NDug/L 04/08/14 ----10 ND ND ND ND ND --NDug/L 10/08/14 5.0 --10 ND ND ND ND ND --NDug/L 04/08/15 5.0 --10 ND ND ND ND ND --NDug/L 10/28/15 5.0 --10 ND ND ND ND ND ND NDug/L 04/05/16 6.2 --10 ND ND ND ND ND ND NDug/L 10/04/16 6.2 --10 ND ND ND ND ND ND NDug/L 04/03/17 6.2 --10 ND ND ND ND ND ND NDug/L 10/03/17 6.2 --10 ND 34.5 (ND)ND ND ND ND NDug/L 05/22/18 6.2 --10 ND ND ND ND ND ND NDug/L 10/23/18 6.2 10 --ND ND ND ND ND ND ND
ug/L 04/16/19 6.2 10 --ND ND ND ND ND ND NDug/L 10/15/19 6.2 10 --ND ND ND ND ND ND NDug/L 04/14/20 6.2 10 --ND ND ND ND ND ND NDug/L 10/07/20 6.2 10 --ND ND ND ND ND ND NDug/L 05/10/21 6.2 10 --ND ND ND ND ND ND NDug/L 10/06/21 6.2 10 --ND ND ND ND ND ND NDug/L 05/17/22 6.2 10 --ND ND ND ND ND ND NDug/L 10/10/22 10 20 --DRY ND ND ND ND ND NDug/L 05/22/23 10 20 --DRY ND ND ND ND ND NDSilverug/L 09/22/94 ----10 ND ND ND ND ND --NDNC 2L = 20 ug/L ug/L 11/08/94 ----10 ND ND ND ND ND --NDEPA MCL = 100 ug/L*ug/L 01/18/95 ----10 ND ND ND ND ND --ND
ug/L 04/23/96 ----10 ND ND ND ND ND --NDug/L 06/17/97 ----10 ND ND ND ND ND --NDug/L 10/16/97 ----10 ND ND ND ND ND --NDug/L 04/21/98 ----10 ND ND ND ND ND --NDug/L 04/07/99 ----10 ND ND ND ND ND --NDug/L 10/13/99 ----10 ND ND ND ND ND --NDug/L 04/05/00 ----10 ND ND ND ND ND --NDug/L 10/25/00 ----10 ND ND ND ND ND --NDug/L 04/04/01 ----10 ND ND ND ND ND --NDug/L 04/08/02 ----10 ND ND ND ND ND --NDug/L 10/21/02 ----10 ND ND ND ND ND --NDug/L 04/14/03 ----10 ND ND ND ND ND --ND
ug/L 10/01/03 ----10 ND ND ND ND ND --NDug/L 04/05/04 ----10 ND ND ND ND ND --NDug/L 10/18/04 ----10 ND ND ND ND ND --NDug/L 04/07/05 ----10 ND ND ND ND ND --NDug/L 10/06/05 ----10 ND ND ND ND ND --NDug/L 04/03/06 ----10 ND ND ND ND ND --NDug/L 10/03/06 ----10 ND ND ND ND ND --NDug/L 04/05/07 ----10 ND ND ND ND ND --NDug/L 10/18/07 ----10 0.6 J ND --ND ND --NDug/L 04/29/08 ----10 ND ND ND ND ND --NDug/L 10/23/08 ----10 ND ND ND ND ND --NDug/L 04/07/09 ----10 1.8 B 1.5 B ND 1.7 B 1.9 B --1.4 Jug/L 10/19/09 ----10 ND ND ND ND ND --ND
ug/L 04/28/10 ----10 ND ND ND ND ND --NDug/L 10/12/10 ----10 ND ND ND ND ND --NDug/L 04/11/11 ----10 ND ND ND ND ND --NDug/L 10/04/11 ----10 ND ND ND ND ND --NDug/L 04/10/12 ----10 ND ND ND ND ND --NDug/L 10/15/12 ----10 ND ND ND ND ND --NDug/L 04/09/13 ----10 2.05 B 2.16 B ND ND 2.18 B --2.16 Jug/L 10/08/13 ----10 ND ND ND ND ND --NDug/L 04/08/14 ----10 3.21 B 2.56 B 2.48 B ND ND --3.31 Jug/L 10/08/14 1.9 --10 ND ND ND ND ND --2.42 Jug/L 04/08/15 1.9 --10 ND ND ND ND ND --NDug/L 10/28/15 1.9 --10 2.80 J ND ND ND ND ND ND
ug/L 04/05/16 1.9 --10 ND ND ND ND ND ND NDug/L 10/04/16 1.9 --10 ND ND ND ND ND ND NDug/L 04/03/17 1.9 --10 3.03 J 2.12 J ND ND 2.63 J ND NDug/L 10/03/17 1.9 --10 ND ND ND ND ND ND NDug/L 05/22/18 1.9 --10 ND ND ND ND ND ND NDug/L 10/23/18 1.9 10 --ND ND ND ND ND ND ND
ug/L 04/16/19 1.9 10 --ND ND ND ND ND ND NDug/L 10/15/19 1.9 10 --ND ND ND ND ND ND NDug/L 04/14/20 1.9 10 --ND ND ND ND ND ND NDug/L 10/07/20 1.9 10 --ND ND ND ND ND ND NDug/L 05/10/21 1.9 10 --ND ND ND ND ND ND NDug/L 10/06/21 1.9 10 --26.3 2.56 J ND ND ND ND NDug/L 05/17/22 1.9 10 --2.84 J ND ND ND ND ND ND
ug/L 10/10/22 1.5 10 --DRY 3.30 J ND ND 1.50 J ND NDug/L 05/22/23 1.5 10 --DRY ND ND ND ND ND ND
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Summary of Historical Groundwater Monitoring Results
TABLE 4
Closed Randolph County Landfill, Permit No. 76-01
SWS Reporting Limit
Detected Monitoring
Constituent/Parameter Units Date BlanksDetection Limit
Downgradient WellsUpgradient WellQuanitation Limit
Thallium ug/L 09/22/94 ----10 ND ND ND ND ND --NDNC 2L = 2 ug/L ug/L 11/08/94 ----10 ND ND ND ND ND --NDEPA MCL = 2 ug/L ug/L 01/18/95 ----10 ND ND ND ND ND --NDug/L 04/23/96 ----10 ND ND ND ND ND --NDug/L 06/17/97 ----10 ND ND ND ND ND --NDug/L 10/16/97 ----10 ND ND ND ND ND --NDug/L 04/21/98 ----10 ND ND ND ND ND --NDug/L 04/07/99 ----10 ND ND ND ND ND --ND
ug/L 10/13/99 ----10 ND ND ND ND ND --NDug/L 04/05/00 ----10 ND ND ND ND ND --NDug/L 10/25/00 ----10 ND ND ND ND ND --NDug/L 04/04/01 ----10 ND ND ND ND ND --NDug/L 04/08/02 ----10 ND ND ND ND ND --NDug/L 10/21/02 ----10 ND ND ND ND ND --NDug/L 04/14/03 ----10 ND ND ND ND ND --NDug/L 10/01/03 ----10 ND ND ND ND ND --NDug/L 04/05/04 ----10 ND ND ND ND ND --NDug/L 10/18/04 ----10 ND ND ND ND ND --NDug/L 04/07/05 ----10 ND ND ND ND ND --NDug/L 10/06/05 ----10 ND ND ND ND ND --ND
ug/L 04/03/06 ----10 ND ND ND ND ND --NDug/L 10/03/06 ----10 ND ND ND ND ND --NDug/L 04/05/07 ----5 ND ND ND ND ND --NDug/L 10/18/07 ----5 ND ND --ND ND --NDug/L 04/29/08 ----5.5 ND ND ND ND ND --NDug/L 10/23/08 ----5.5 ND ND ND ND ND --NDug/L 04/07/09 ----5.5 0.036 B 0.045 B 0.063 B ND 0.037 B --0.052 Jug/L 10/19/09 ----5.5 ND ND ND ND ND --NDug/L 04/28/10 ----5.5 ND ND ND ND ND --NDug/L 10/12/10 ----5.5 ND ND ND ND ND --NDug/L 04/11/11 ----5.5 ND ND ND ND ND --NDug/L 10/04/11 ----5.5 ND ND ND ND ND --NDug/L 04/10/12 ----5.5 ND ND ND ND ND --ND
ug/L 10/15/12 ----5.5 ND ND ND ND ND --NDug/L 04/09/13 ----5.5 ND ND ND ND ND --NDug/L 10/08/13 ----5.5 ND ND ND ND ND --NDug/L 04/08/14 ----5.5 ND ND ND ND ND --NDug/L 10/08/14 0.11 --5.5 ND ND ND ND ND --NDug/L 04/08/15 0.11 --5.5 ND ND ND 0.177 J ND --NDug/L 10/28/15 0.11 --5.5 ND ND ND ND ND ND NDug/L 04/05/16 0.11 --5.5 ND ND ND ND ND ND NDug/L 10/04/16 0.11 --5.5 ND ND ND ND ND ND NDug/L 04/03/17 0.11 --5.5 0.211 J 0.229 J 0.188 J 0.199 J 0.338 J 0.266 J NDug/L 10/03/17 0.11 --5.5 0.530 J 0.790 J 0.920 J 0.646 J 0.742 J 0.830 J NDug/L 05/22/18 0.11 --5.5 ND ND ND ND ND ND NDug/L 10/23/18 0.55 5 --ND ND ND ND ND ND ND
ug/L 04/16/19 0.11 1 --ND ND ND ND ND ND NDug/L 10/15/19 0.22 2 --ND ND ND ND ND ND NDug/L 04/14/20 0.22 2 --ND ND ND ND ND ND NDug/L 10/07/20 0.22 2 --ND ND ND ND ND ND NDug/L 05/10/21 0.22 2 --ND ND ND ND ND ND NDug/L 10/06/21 0.22 2 --ND ND ND ND ND ND NDug/L 05/17/22 0.22 2 --ND ND ND ND ND ND NDug/L 10/10/22 0.26 1 --DRY ND ND ND ND ND NDug/L 05/22/23 0.26 1 --DRY ND ND ND ND ND NDTin ug/L 09/22/94 ----100 ND ND ND ND ND --NDNC 2L = 2000 ug/L ug/L 11/08/94 ----100 ND ND ND ND ND --ND(No EPA MCL)ug/L 01/18/95 ----100 ND ND ND ND ND --ND
ug/L 04/23/96 ----100 ND ND ND ND ND --NDug/L 06/17/97 ----100 ND ND ND ND ND --NDug/L 10/16/97 ----100 ND ND ND ND ND --NDug/L 04/21/98 ----100 ND ND ND ND ND --NDug/L 04/07/99 ----100 ND ND ND ND ND --NDug/L 10/13/99 ----100 ND ND ND ND ND --NDug/L 04/05/00 ----100 ND ND ND ND ND --NDug/L 10/25/00 ----100 ND ND ND ND ND --NDug/L 04/04/01 ----100 414 282 ND 249 163 --NDug/L 04/08/02 ----100 360 336 ND 171 145 --NDug/L 10/21/02 ----100 ND ND ND ND ND --NDug/L 04/14/03 ----100 117 ND ND ND ND --ND
ug/L 10/01/03 ----100 ND ND ND ND ND --NDug/L 04/05/04 ----100 176 ND ND ND ND --NDug/L 10/18/04 ----100 ND ND ND ND ND --NDug/L 04/07/05 ----100 ND ND ND ND ND --NDug/L 10/06/05 ----100 ND ND ND ND ND --NDug/L 04/03/06 ----100 ND ND ND ND ND --NDug/L 10/03/06 ----100 ND ND ND ND ND --NDug/L 04/05/07 ----100 ND ND ND ND ND --NDug/L 04/29/08 ----100 2.5 J ND 2.4 J ND ND --NDug/L 04/07/09 ----100 ND ND ND ND ND --NDug/L 04/28/10 ----100 4.96 J 3.98 J ND 3.37 J 5.49 J --NDug/L 04/11/11 ----100 4.46 J ND 2.20 J 2.63 J 4.04 J --NDug/L 04/10/12 ----100 5.12 J ND ND 3.24 J 3.80 J --ND
ug/L 04/09/13 ----100 5.08 J ND ND ND 3.15 J --NDug/L 04/08/14 ----100 ND ND ND ND ND --NDug/L 04/08/15 12 --100 ND ND ND ND ND --NDug/L 04/05/16 2.4 --100 ND ND ND ND ND ND 3.18 Jug/L 04/03/17 2.4 --100 8.13 J ND ND 4.52 J ND ND NDug/L 05/22/18 2.4 --100 ND ND 2.40 J ND ND ND NDug/L 04/16/19 2.9 10 --ND ND ND ND ND ND NDug/L 04/14/20 2.9 10 --ND ND ND ND ND ND NDug/L 05/10/21 2.9 10 --ND ND ND ND 14.5 (ND)ND NDug/L 05/17/22 2.9 10 --ND ND ND ND ND ND ND
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Summary of Historical Groundwater Monitoring Results
TABLE 4
Closed Randolph County Landfill, Permit No. 76-01
SWS Reporting Limit
Detected Monitoring
Constituent/Parameter Units Date BlanksDetection Limit
Downgradient WellsUpgradient WellQuanitation Limit
Vanadium ug/L 09/22/94 ----40 ND ND ND 48 ND --NDNC 2L = 7 ug/L ug/L 11/08/94 ----40 ND ND ND ND ND --ND(No EPA MCL)ug/L 01/18/95 ----40 ND ND ND ND ND --NDug/L 04/23/96 ----40 ND ND ND ND ND --NDug/L 06/17/97 ----40 ND ND ND 84 ND --NDug/L 10/16/97 ----40 ND ND ND ND ND --NDug/L 04/21/98 ----40 ND ND ND ND ND --NDug/L 04/07/99 ----40 ND 94 ND ND ND --ND
ug/L 10/13/99 ----40 ND 210 ND ND ND --NDug/L 04/05/00 ----40 ND 94 ND ND ND --NDug/L 10/25/00 ----40 ND 295 76 54 ND --NDug/L 04/04/01 ----40 ND 206 ND 91 ND --NDug/L 04/08/02 ----40 ND ND ND ND ND --NDug/L 10/21/02 ----40 ND 155 ND ND ND --NDug/L 04/14/03 ----40 ND ND ND ND ND --NDug/L 10/01/03 ----40 ND 56 ND 86 ND --NDug/L 04/05/04 ----40 ND ND ND ND 76 --NDug/L 10/18/04 ----40 ND 41 ND ND ND --NDug/L 04/07/05 ----40 ND 57 ND ND ND --NDug/L 10/06/05 ----40 ND 62 ND ND ND --ND
ug/L 04/03/06 ----40 ND 72 ND ND ND --NDug/L 10/03/06 ----40 ND ND ND ND ND --NDug/L 04/05/07 ----40 ND ND ND ND ND --NDug/L 10/18/07 ----25 3.2 J 21.6 J --ND 1.5 J --NDug/L 04/29/08 ----25 10.3 J 5.9 J ND ND ND --NDug/L 10/23/08 ----25 ND ND ND ND ND --NDug/L 04/07/09 ----25 3.9 J 3.6 J ND ND 0.7 J --NDug/L 10/19/09 ----25 5.12 J ND ND ND 2.26 J --NDug/L 04/28/10 ----25 4.42 J 2.65 J ND ND ND --NDug/L 10/12/10 ----25 4.33 J 2.25 J ND 1.54 J 2.73 J --NDug/L 04/11/11 ----25 4.13 J 1.88 J ND ND 1.89 J --NDug/L 10/04/11 ----25 4.16 J ND ND ND 8.31 J --NDug/L 04/10/12 ----25 4.34 J 1.99 J ND ND ND --ND
ug/L 10/15/12 ----25 3.95 J ND 6.47 J ND 2.37 J --NDug/L 04/09/13 ----25 3.88 J 5.41 J ND ND 1.89 J --NDug/L 10/08/13 ----25 4.50 J ND ND ND 2.92 J --NDug/L 04/08/14 ----25 5.11 J 3.68 J ND ND ND --NDug/L 10/08/14 1.4 --25 5.04 J 2.47 J ND ND 4.16 J --NDug/L 04/08/15 1.4 --25 3.99 J ND ND ND ND --NDug/L 10/28/15 1.4 --25 4.19 J ND ND ND 4.53 J ND NDug/L 04/05/16 1.4 --25 5.51 J 1.99 J ND ND ND ND NDug/L 10/04/16 1.4 --25 5.23 J 3.30 J ND ND ND ND NDug/L 04/03/17 1.4 --25 4.72 J ND ND ND ND ND NDug/L 10/03/17 1.4 --25 3.54 J 1.79 J ND ND 2.91 J ND NDug/L 05/22/18 1.4 --25 5.33 J 3.61 J 1.95 J 1.72 J 1.45 J ND NDug/L 10/23/18 1.4 10 --3.11 J 1.42 J ND ND ND ND ND
ug/L 04/16/19 1.4 10 --3.90 J ND ND ND ND ND NDug/L 10/15/19 1.4 10 --4.40 J 3.11 J ND ND 4.48 J ND NDug/L 04/14/20 1.4 10 --5.38 J ND ND ND ND ND NDug/L 10/07/20 1.4 10 --2.63 J ND ND ND ND ND NDug/L 05/10/21 1.4 10 --3.46 J ND ND ND ND ND NDug/L 10/06/21 1.4 10 --ND ND ND ND ND ND NDug/L 05/17/22 1.4 10 --ND ND 1.86 J ND ND ND NDug/L 10/10/22 1 10 --DRY 1.70 J 1.00 J ND 2.30 J ND NDug/L 05/22/23 1 10 --DRY 3.28 J ND ND 1.83 J ND NDZincug/L 09/22/94 ----50 ND 67 59 ND ND --NDNC 2L = 1000 ug/L ug/L 11/08/94 ----50 ND ND ND ND ND --NDEPA MCL = 5000 ug/L*ug/L 01/18/95 ----50 ND ND ND ND ND --ND
ug/L 04/23/96 ----50 ND ND ND ND ND --NDug/L 06/17/97 ----50 52 B 93 B 112 B 527 86 B --72ug/L 10/16/97 ----50 ND ND 127 227 ND --NDug/L 04/21/98 ----50 ND ND ND ND ND --NDug/L 04/07/99 ----50 ND ND ND ND ND --NDug/L 10/13/99 ----50 ND 144 55 135 ND --NDug/L 04/05/00 ----50 ND 64 ND 143 ND --NDug/L 10/25/00 ----50 ND 193 127 185 ND --NDug/L 04/04/01 ----50 ND 110 ND 284 ND --NDug/L 04/08/02 ----50 ND 226 ND 234 ND --NDug/L 10/21/02 ----50 ND 61 ND 72 ND --NDug/L 04/14/03 ----50 ND 111 ND ND ND --ND
ug/L 10/01/03 ----50 ND 53 53 323 ND --NDug/L 04/05/04 ----50 ND ND ND ND ND --NDug/L 10/18/04 ----50 ND 175 ND 94 51 --NDug/L 04/07/05 ----50 ND 113 88 97 ND --NDug/L 10/06/05 ----50 ND 132 74 146 ND --NDug/L 04/03/06 ----50 ND 113 ND ND 50 --NDug/L 10/03/06 ----50 ND ND ND ND ND --NDug/L 04/05/07 ----10 ND 14 ND ND ND --NDug/L 10/18/07 ----10 6.9 B 33 --8.7 J 6.8 B --1.5 Jug/L 04/29/08 ----10 16.7 B 4.3 B 8.8 B 5.3 B 1.0 B --122ug/L 10/23/08 ----10 4.5 J ND ND ND ND --NDug/L 04/07/09 ----10 8.2 B 5.4 B 7.5 B ND ND --4.2 Jug/L 10/19/09 ----10 9.69 J 7.40 J 8.17 J ND ND --ND
ug/L 04/28/10 ----10 6.46 J 5.76 J 10.4 ND ND --NDug/L 10/12/10 ----10 6.37 J 6.24 J 5.90 J 4.65 J ND --NDug/L 04/11/11 ----10 17.4 3.88 J 6.94 J 5.96 J 7.76 J --NDug/L 10/04/11 ----10 14.2 ND 11.6 ND ND --NDug/L 04/10/12 ----10 6.09 J 5.35 J 7.32 J ND ND --NDug/L 10/15/12 ----10 5.95 J 6.33 J 21.3 ND ND --NDug/L 04/09/13 ----10 7.25 J ND 6.94 J 4.09 J ND --NDug/L 10/08/13 ----10 4.17 J 5.51 J 9.56 J ND ND --NDug/L 04/08/14 ----10 6.49 J ND 6.39 J ND ND --NDug/L 10/08/14 3.8 --10 9.39 J 11.7 12.4 5.99 J ND --NDug/L 04/08/15 3.8 --10 4.49 J ND 9.80 J ND ND --NDug/L 10/28/15 3.8 --10 7.53 J ND 7.40 J ND ND 12.4 ND
ug/L 04/05/16 4.4 --10 ND ND 4.46 J ND ND 11.4 NDug/L 10/04/16 4.4 --10 8.61 J 8.84 J 7.75 J ND ND 12.8 NDug/L 04/03/17 4.4 --10 ND ND ND ND ND 10.3 NDug/L 10/03/17 4.4 --10 ND ND 6.48 J ND ND 13.2 NDug/L 05/22/18 4.4 --10 ND ND 8.91 J ND ND 10.2 NDug/L 10/23/18 4.4 10 --4.93 J 11.3 7.76 J ND ND 13.2 ND
ug/L 04/16/19 4.4 10 --ND 5.23 J 8.07 J ND ND 10.8 NDug/L 10/15/19 4.4 10 --8.28 J 17.4 12.6 ND ND 13.4 NDug/L 04/14/20 4.4 10 --ND ND 10.2 ND ND 10.7 NDug/L 10/07/20 4.4 10 --5.08 J 23.1 7.26 J ND ND 18.6 NDug/L 05/10/21 4.4 10 --ND ND 6.48 J ND ND 10.5 NDug/L 10/06/21 4.4 10 --10.2 32.4 9.03 J ND ND 13.0 NDug/L 05/17/22 4.4 10 --23.4 31.7 8.78 J ND ND 12.7 ND
ug/L 10/10/22 8.7 20 --DRY ND ND ND ND 14.0 J NDug/L 05/22/23 8.7 20 --DRY ND ND ND ND 9.9 J ND
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September 2023 31404568.018
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Summary of Historical Groundwater Monitoring Results
TABLE 4
Closed Randolph County Landfill, Permit No. 76-01
SWS Reporting Limit
Detected Monitoring
Constituent/Parameter Units Date BlanksDetection Limit
Downgradient WellsUpgradient WellQuanitation Limit
Acetone ug/L 09/22/94 ----100 ND ND ND ND ND --NDNC 2L = 6000 ug/L ug/L 11/08/94 ----100 ND ND ND ND ND --ND(No EPA MCL)ug/L 01/18/95 ----100 ND ND ND ND ND --NDug/L 04/23/96 ----100 ND ND ND ND ND --NDug/L 06/17/97 ----100 ND ND ND ND ND --NDug/L 10/16/97 ----100 ND ND ND ND ND --NDug/L 04/21/98 ----100 ND ND ND ND ND --NDug/L 04/07/99 ----100 ND ND ND ND ND --ND
ug/L 10/13/99 ----100 ND ND ND ND ND --NDug/L 04/05/00 ----100 ND ND ND ND ND --NDug/L 10/25/00 ----100 ND ND ND ND ND --NDug/L 04/04/01 ----100 ND ND ND ND ND --NDug/L 04/08/02 ----100 ND ND ND ND ND --NDug/L 10/21/02 ----100 ND ND ND ND ND --NDug/L 04/14/03 ----100 ND ND ND ND ND --NDug/L 10/01/03 ----100 ND ND ND ND ND --NDug/L 04/05/04 ----100 ND ND ND ND ND --NDug/L 10/18/04 ----100 ND ND ND ND ND --NDug/L 04/07/05 ----100 ND ND ND ND ND --NDug/L 10/06/05 ----100 ND ND ND ND ND --ND
ug/L 04/03/06 ----100 ND ND ND ND ND --NDug/L 10/03/06 ----100 ND ND ND ND ND --NDug/L 04/05/07 ----100 ND ND ND ND ND --NDug/L 10/18/07 ----100 ND 1.3 J --ND ND --NDug/L 04/29/08 ----100 ND ND ND ND ND --2.7 Jug/L 10/23/08 ----100 ND 4.3 B 5.1 B 4.6 B 4.2 B --5.3 Jug/L 04/07/09 ----100 ND ND ND ND ND --NDug/L 10/19/09 ----100 ND ND ND ND ND --8.2 Jug/L 04/28/10 ----100 ND ND ND ND ND --NDug/L 10/12/10 ----100 ND ND ND ND ND --NDug/L 04/11/11 ----100 ND ND ND ND ND --NDug/L 10/04/11 ----100 ND ND ND ND ND ND NDug/L 04/10/12 ----100 ND ND ND ND ND --ND
ug/L 10/15/12 ----100 ND ND ND ND ND --NDug/L 04/09/13 ----100 ND ND ND ND ND --NDug/L 10/08/13 ----100 ND ND ND ND ND --NDug/L 04/08/14 ----100 ND ND ND ND ND --NDug/L 10/08/14 1.2 --100 ND ND ND ND ND --NDug/L 04/08/15 1.2 --100 ND ND ND ND ND --NDug/L 10/28/15 1.2 --100 ND ND ND ND ND ND NDug/L 04/05/16 1.2 --100 ND ND ND ND ND ND NDug/L 10/04/16 10 --100 ND ND ND ND ND ND NDug/L 04/03/17 10 --100 ND ND ND ND ND ND NDug/L 10/03/17 10 --100 ND ND ND ND ND ND NDug/L 05/22/18 10 --100 ND ND ND ND ND ND NDug/L 10/23/18 10 20 --ND ND ND ND ND ND ND
ug/L 04/16/19 10 20 --ND ND ND ND ND ND NDug/L 10/15/19 10 20 --ND ND ND ND ND ND NDug/L 04/14/20 10 20 --ND ND ND ND ND ND NDug/L 10/07/20 10 20 --ND ND ND ND ND ND NDug/L 05/10/21 10 20 --ND ND ND ND ND ND NDug/L 10/06/21 10 20 --ND ND ND ND ND ND 23ug/L 05/17/22 10 20 --ND ND ND ND ND ND NDug/L 10/10/22 3.7 10 --DRY ND ND ND ND ND NDug/L 05/22/23 10 20 --DRY ND ND ND ND ND NDAcetonitrileug/L 09/22/94 ----100 ND ND ND ND ND --ND(No NC 2L or IMAC)ug/L 11/08/94 ----100 ND ND ND ND ND --ND(No EPA MCL)ug/L 01/18/95 ----100 ND ND ND ND ND --ND
ug/L 04/23/96 ----100 ND ND ND ND ND --NDug/L 06/17/97 ----100 ND ND ND ND ND --NDug/L 10/16/97 ----100 ND ND ND ND ND --NDug/L 04/21/98 ----100 ND ND ND ND ND --NDug/L 04/07/99 ----100 ND ND ND ND ND --NDug/L 10/13/99 ----100 ND ND ND ND ND --NDug/L 04/05/00 ----100 ND ND ND ND ND --NDug/L 10/25/00 ----100 ND ND ND ND ND --NDug/L 04/04/01 ----100 ND ND ND ND ND --NDug/L 04/08/02 ----100 ND ND ND ND ND --NDug/L 10/21/02 ----100 ND ND ND ND ND --NDug/L 04/14/03 ----100 ND ND ND ND ND --ND
ug/L 10/01/03 ----100 ND ND ND ND ND --NDug/L 04/05/04 ----100 ND ND ND ND ND --NDug/L 10/18/04 ----100 ND ND ND ND ND --NDug/L 04/07/05 ----100 ND ND ND ND ND --NDug/L 10/06/05 ----100 ND ND ND ND ND --NDug/L 04/03/06 ----100 ND ND ND ND ND --NDug/L 10/03/06 ----100 ND ND ND ND ND --NDug/L 04/05/07 ----50 ND ND ND ND ND --NDug/L 10/18/07 ----50 ND ND --ND ND --22.6 Jug/L 04/29/08 ----55 ND ND ND ND ND --NDug/L 10/23/08 --------------------ug/L 04/07/09 ----55 ND ND ND ND ND --NDug/L 04/28/10 ----55 ND ND ND ND ND --ND
ug/L 04/11/11 ----55 ND ND ND ND ND --NDug/L 04/10/12 ----55 ND ND ND ND ND --NDug/L 04/09/13 ----55 ND ND ND ND ND --NDug/L 04/08/14 ----55 ND ND ND ND ND --NDug/L 04/08/15 100 --55 ND ND ND ND ND --NDug/L 04/05/16 5.0 --55 ND ND ND ND ND ND NDug/L 04/03/17 5.0 --55 ND ND ND ND ND ND NDug/L 05/22/18 5.0 --55 ND ND ND ND ND ND NDug/L 04/16/19 5.0 10 --ND ND ND ND ND ND NDug/L 04/14/20 5.0 10 --ND ND ND ND ND ND NDug/L 05/10/21 5.0 10 --ND ND ND ND ND ND NDug/L 05/17/22 5.0 10 --ND ND ND ND ND ND ND
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September 2023 31404568.018
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Summary of Historical Groundwater Monitoring Results
TABLE 4
Closed Randolph County Landfill, Permit No. 76-01
SWS Reporting Limit
Detected Monitoring
Constituent/Parameter Units Date BlanksDetection Limit
Downgradient WellsUpgradient WellQuanitation Limit
Benzene ug/L 09/22/94 ----5 ND ND ND ND ND --NDNC 2L = 1 ug/L ug/L 11/08/94 ----5 ND ND ND ND ND --NDEPA MCL = 5 ug/L ug/L 01/18/95 ----5 ND ND ND ND ND --NDug/L 04/23/96 ----5 ND ND ND ND ND --NDug/L 06/17/97 ----5 ND ND ND ND ND --NDug/L 10/16/97 ----5 ND ND ND ND ND --NDug/L 04/21/98 ----5 ND ND ND ND ND --NDug/L 04/07/99 ----5 ND ND ND ND ND --ND
ug/L 10/13/99 ----5 ND ND ND ND ND --NDug/L 04/05/00 ----5 ND ND ND ND ND --NDug/L 10/25/00 ----5 ND ND ND ND ND --NDug/L 04/04/01 ----5 ND ND ND ND ND --NDug/L 04/08/02 ----5 ND ND ND ND ND --NDug/L 10/21/02 ----5 ND ND ND ND ND --NDug/L 04/14/03 ----5 ND ND ND ND ND --NDug/L 10/01/03 ----5 ND ND ND ND ND --NDug/L 04/05/04 ----5 ND ND ND ND ND --NDug/L 10/18/04 ----5 ND ND ND ND ND --NDug/L 04/07/05 ----5 ND ND ----------ug/L 10/06/05 ----5 ND ND ND ND ND --ND
ug/L 04/03/06 ----5 ND ND ND ND ND --NDug/L 10/03/06 ----5 ND ND ND ND ND --NDug/L 04/05/07 ----3 ND ND ND ND ND --NDug/L 10/18/07 ----1 ND ND --ND ND --NDug/L 04/29/08 ----1 ND ND 0.78 J ND ND --NDug/L 10/23/08 ----1 ND ND 1.8 ND ND --NDug/L 04/07/09 ----1 ND ND ND ND ND --NDug/L 10/19/09 ----1 ND ND 1.9 ND ND --NDug/L 04/28/10 ----1 ND ND 1.3 ND ND --NDug/L 10/12/10 ----1 ND ND 2.0 ND ND --NDug/L 04/11/11 ----1 ND ND 1.3 ND ND --NDug/L 10/04/11 ----1 ND ND 2.0 ND ND ND NDug/L 04/10/12 ----1 ND ND 1.3 ND ND --ND
ug/L 10/15/12 ----1 ND ND 1.9 ND ND --NDug/L 04/09/13 ----1 ND ND 1.3 ND ND --NDug/L 10/08/13 ----1 ND ND 1.4 ND ND --NDug/L 04/08/14 ----1 ND ND 1.1 ND ND --NDug/L 10/08/14 0.15 --1 ND ND 1.4 ND ND --NDug/L 04/08/15 0.15 --1 ND ND 0.58 J ND ND --NDug/L 10/28/15 0.15 --1 ND ND 1.4 ND ND ND NDug/L 04/05/16 0.15 --1 ND ND 0.87 J ND ND ND NDug/L 10/04/16 0.15 --1 ND ND 1.4 ND ND ND NDug/L 04/03/17 0.15 --1 ND ND 1.4 ND ND ND NDug/L 10/03/17 0.15 --1 ND ND 1.3 ND ND ND NDug/L 05/22/18 0.15 --1 ND ND 1.0 ND ND ND NDug/L 10/23/18 0.15 1 --ND ND 1.0 ND ND 0.95 J ND
ug/L 04/16/19 0.15 1 --ND ND 0.89 J ND ND 0.44 J NDug/L 10/15/19 0.15 1 --ND ND 1.0 ND ND 1.2 NDug/L 04/14/20 0.15 1 --ND ND 0.54 J ND ND ND NDug/L 10/07/20 0.15 1 --ND ND 0.66 J ND ND 0.68 J NDug/L 05/10/21 0.15 1 --ND ND ND ND ND 0.50 J NDug/L 10/06/21 0.15 1 --ND ND 0.65 J ND ND 0.95 J NDug/L 05/17/22 0.15 1 --ND ND 0.49 J ND ND ND NDug/L 10/10/22 0.27 1 --DRY ND 0.67 J ND ND 0.75 J NDug/L 05/22/23 0.15 1.0 --DRY ND 0.507 J ND ND 0.84 J NDChlorobenzeneug/L 09/22/94 ----5 ND ND ND ND ND --NDNC 2L = 50 ug/L ug/L 11/08/94 ----5 ND ND ND ND ND --NDEPA MCL = 100 ug/L ug/L 01/18/95 ----5 ND ND ND ND ND --ND
ug/L 04/23/96 ----5 ND ND ND ND ND --NDug/L 06/17/97 ----5 ND ND ND ND ND --NDug/L 10/16/97 ----5 ND ND ND ND ND --NDug/L 04/21/98 ----5 ND ND ND ND ND --NDug/L 04/07/99 ----5 ND ND ND ND ND --NDug/L 10/13/99 ----5 ND ND ND ND ND --NDug/L 04/05/00 ----5 ND ND ND ND ND --NDug/L 10/25/00 ----5 ND ND ND ND ND --NDug/L 04/04/01 ----5 ND ND ND ND ND --NDug/L 04/08/02 ----5 ND ND ND ND ND --NDug/L 10/21/02 ----5 ND ND ND ND ND --NDug/L 04/14/03 ----5 ND ND ND ND ND --ND
ug/L 10/01/03 ----5 ND ND ND ND ND --NDug/L 04/05/04 ----5 ND ND ND ND ND --NDug/L 10/18/04 ----5 ND ND ND ND ND --NDug/L 04/07/05 ----5 ND ND ND ND ND --NDug/L 10/06/05 ----5 ND ND ND ND ND --NDug/L 04/03/06 ----5 ND ND ND ND ND --NDug/L 10/03/06 ----5 ND ND ND ND ND --NDug/L 04/05/07 ----3 ND ND ND ND ND --NDug/L 10/18/07 ----3 ND ND --ND ND --NDug/L 04/29/08 ----3 ND ND 1.0 J ND ND --NDug/L 10/23/08 ----3 ND ND 2.5 J ND ND --NDug/L 04/07/09 ----3 ND ND 0.84 J ND ND --NDug/L 10/19/09 ----3 ND ND 2.7 J ND ND --ND
ug/L 04/28/10 ----3 ND ND 1.3 J ND ND --NDug/L 10/12/10 ----3 ND ND 2.6 J ND ND --NDug/L 04/11/11 ----3 ND ND 1.5 J ND ND --NDug/L 10/04/11 ----3 ND ND 2.7 J ND ND ND NDug/L 04/10/12 ----3 ND ND 1.3 J ND ND --NDug/L 10/15/12 ----3 ND ND 2.6 J ND ND --NDug/L 04/09/13 ----3 ND ND 1.5 J ND ND --NDug/L 10/08/13 ----3 ND ND 1.7 J ND ND --NDug/L 04/08/14 ----3 ND ND ND ND ND --NDug/L 10/08/14 0.17 --3 ND ND 1.4 J ND ND --NDug/L 04/08/15 0.17 --3 ND ND 0.64 J ND ND --NDug/L 10/28/15 0.17 --3 ND 0.76 J 1.7 J ND 0.62 J ND ND
ug/L 04/05/16 0.17 --3 ND ND 0.85 J ND ND ND NDug/L 10/04/16 0.17 --3 ND ND 2.1 J ND ND ND NDug/L 04/03/17 0.17 --3 ND ND 1.7 J ND ND ND NDug/L 10/03/17 0.17 --3 ND ND 2.1 J ND ND ND NDug/L 05/22/18 0.17 --3 ND ND 1.2 J ND ND ND NDug/L 10/23/18 0.17 1 --ND ND 1.4 ND ND ND ND
ug/L 04/16/19 0.17 1 --ND ND 0.91 J ND ND ND NDug/L 10/15/19 0.17 1 --ND ND 1.5 ND ND ND NDug/L 04/14/20 0.17 1 --ND ND 0.59 J ND ND ND NDug/L 10/07/20 0.17 1 --ND ND 1.2 ND ND ND NDug/L 05/10/21 0.17 1 --ND ND ND ND ND ND NDug/L 10/06/21 0.17 1 --ND ND ND ND ND ND NDug/L 05/17/22 0.17 1 --ND ND ND ND ND ND ND
ug/L 10/10/22 0.15 1 --DRY ND 1.5 ND ND ND NDug/L 05/22/23 0.17 1 --DRY ND 1.07 ND ND ND ND
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September 2023 31404568.018
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Summary of Historical Groundwater Monitoring Results
TABLE 4
Closed Randolph County Landfill, Permit No. 76-01
SWS Reporting Limit
Detected Monitoring
Constituent/Parameter Units Date BlanksDetection Limit
Downgradient WellsUpgradient WellQuanitation Limit
Chloroethane ug/L 09/22/94 ----10 ND ND ND ND ND --NDNC 2L = 3000 ug/L ug/L 11/08/94 ----10 ND ND ND ND ND --ND(No EPA MCL)ug/L 01/18/95 ----10 ND ND ND ND ND --NDug/L 04/23/96 ----10 ND ND 38 ND ND --NDug/L 06/17/97 ----10 ND ND ND ND ND --NDug/L 10/16/97 ----10 ND ND ND ND ND --NDug/L 04/21/98 ----10 ND ND ND ND ND --NDug/L 04/07/99 ----10 ND ND ND ND ND --ND
ug/L 10/13/99 ----10 ND ND ND ND ND --NDug/L 04/05/00 ----10 ND ND ND ND ND --NDug/L 10/25/00 ----10 ND ND ND ND ND --NDug/L 04/04/01 ----10 ND ND 15 ND ND --NDug/L 04/04/02 ----10 ND ND ND ND ND --NDug/L 10/21/02 ----10 ND ND 10.2 ND ND --NDug/L 04/14/03 ----10 ND ND ND ND ND --NDug/L 10/01/03 ----10 ND ND ND ND ND --NDug/L 04/05/04 ----10 ND ND ND ND ND --NDug/L 10/18/04 ----10 ND ND ND ND ND --NDug/L 04/07/05 ----10 ND ND --------NDug/L 10/06/05 ----10 ND ND ND ND ND --ND
ug/L 04/03/06 ----10 ND ND ND ND ND --NDug/L 10/03/06 ----10 ND ND ND ND ND --NDug/L 04/05/07 ----10 ND ND ND ND ND --NDug/L 10/18/07 ----10 ND ND --ND 0.4 J --NDug/L 04/29/08 ----10 ND ND 3.1 J ND ND --NDug/L 10/23/08 ----10 ND ND 7.2 J ND ND --NDug/L 04/07/09 ----10 ND ND 3.1 J ND 0.91 J --NDug/L 10/19/09 ----10 ND ND 3.4 J ND ND --NDug/L 04/28/10 ----10 ND 0.75 J 3.4 J ND ND --NDug/L 10/12/10 ----10 ND ND 5.3 J ND ND --NDug/L 04/11/11 ----10 ND ND ND ND ND --NDug/L 10/04/11 ----10 ND ND 7.3 J ND ND 3.4 J NDug/L 04/10/12 ----10 ND ND 1.5 J ND ND --ND
ug/L 10/15/12 ----10 ND ND 3.5 J ND ND --NDug/L 04/09/13 ----10 ND ND ND ND ND --NDug/L 10/08/13 ----10 ND ND 3.7 J ND ND --NDug/L 04/08/14 ----10 ND ND 3.8 J ND ND --NDug/L 10/08/14 0.23 --10 ND ND 2.5 J ND ND --NDug/L 04/08/15 0.23 --10 ND ND ND ND ND --NDug/L 10/28/15 0.23 --10 ND ND 4.1 J ND ND 3.8 J NDug/L 04/05/16 0.23 --10 ND ND 2.4 J ND ND 1.5 J NDug/L 10/04/16 0.23 --10 ND ND 2.7 J ND ND 1.2 J NDug/L 04/03/17 0.23 --10 ND ND 3.6 J ND ND 2.9 J NDug/L 10/03/17 0.23 --10 ND ND 3.1 J ND ND 2.0 J NDug/L 05/22/18 0.23 --10 ND ND ND ND ND ND NDug/L 10/23/18 0.23 1 --ND ND 1.4 ND ND 1.5 ND
ug/L 04/16/19 0.23 1 --ND ND 1.6 ND ND 1.3 NDug/L 10/15/19 0.23 1 --ND ND 1.9 ND ND 1.6 NDug/L 04/14/20 0.23 1 --ND ND ND ND ND ND NDug/L 10/07/20 0.23 1 --ND ND ND ND ND ND NDug/L 05/10/21 0.23 1 --ND ND ND ND ND ND NDug/L 10/06/21 0.23 1 --ND ND ND ND ND ND NDug/L 05/17/22 0.23 1 --ND ND ND ND ND ND NDug/L 10/10/22 4.6 5 --DRY ND ND ND ND ND NDug/L 05/22/23 0.23 1 --DRY ND 0.791 J ND ND 0.879 J NDChloroformug/L 09/22/94 ----5 ND ND ND ND ND --NDNC 2L = 70 ug/L ug/L 11/08/94 ----5 ND ND ND ND ND --NDEPA MCL = 80 ug/L ug/L 01/18/95 ----5 ND ND ND ND ND --ND
ug/L 04/23/96 ----5 ND ND ND ND ND --NDug/L 06/17/97 ----5 ND ND ND ND ND --NDug/L 10/16/97 ----5 ND ND ND ND ND --NDug/L 04/21/98 ----5 ND ND ND ND ND --NDug/L 04/07/99 ----5 ND ND ND ND ND --NDug/L 10/13/99 ----5 ND ND ND ND ND --NDug/L 04/05/00 ----5 ND ND ND ND ND --NDug/L 10/25/00 ----5 ND ND ND ND ND --NDug/L 04/04/01 ----5 ND ND ND ND ND --NDug/L 04/04/02 ----5 ND ND ND ND ND --NDug/L 10/21/02 ----5 ND ND ND ND ND --NDug/L 04/14/03 ----5 ND ND ND ND ND --ND
ug/L 10/01/03 ----5 ND ND ND ND ND --NDug/L 04/05/04 ----5 ND ND ND ND ND --NDug/L 10/18/04 ----5 ND ND ND ND ND --NDug/L 04/07/05 ----5 ND ND ND ND ND --NDug/L 10/06/05 ----5 ND ND ND ND ND --NDug/L 04/03/06 ----5 ND ND ND ND ND --NDug/L 10/03/06 ----5 ND ND ND ND ND --NDug/L 04/05/07 ----5 ND ND ND ND ND --NDug/L 10/18/07 ----5 ND ND --ND ND --NDug/L 04/29/08 ----5 ND ND ND ND ND --NDug/L 10/23/08 ----5 ND ND ND ND ND --NDug/L 04/07/09 ----5 ND ND ND ND ND --NDug/L 10/19/09 ----5 ND ND ND ND ND --ND
ug/L 04/28/10 ----5 ND ND ND ND ND --NDug/L 10/12/10 ----5 ND ND ND ND ND --NDug/L 04/11/11 ----5 ND ND ND ND ND --NDug/L 10/04/11 ----5 ND ND ND ND ND ND NDug/L 04/10/12 ----5 ND ND ND ND ND --NDug/L 10/15/12 ----5 ND ND ND ND ND --NDug/L 04/09/13 ----5 ND ND ND ND ND --NDug/L 10/08/13 ----5 ND ND ND ND ND --NDug/L 04/08/14 ----5 ND ND ND ND ND --NDug/L 10/08/14 0.18 --5 ND ND ND ND ND --NDug/L 04/08/15 0.18 --5 ND ND ND ND ND --NDug/L 10/28/15 0.18 --5 ND ND ND ND ND ND ND
ug/L 04/05/16 0.18 --5 ND ND ND ND ND ND NDug/L 10/04/16 0.18 --5 ND ND ND ND ND ND NDug/L 04/03/17 0.18 --5 ND ND ND ND ND ND NDug/L 10/03/17 0.18 --5 ND ND ND ND ND ND NDug/L 05/22/18 0.18 --5 ND ND ND ND ND ND NDug/L 10/23/18 0.18 1 --ND ND ND ND ND ND ND
ug/L 04/16/19 0.18 1 --ND ND ND ND ND ND NDug/L 10/15/19 0.18 1 --ND ND ND ND ND ND NDug/L 04/14/20 0.18 1 --ND ND ND ND ND ND NDug/L 10/07/20 0.18 1 --ND ND ND ND ND ND NDug/L 05/10/21 0.18 1 --ND ND ND ND ND ND NDug/L 10/06/21 0.18 1 --ND ND ND ND ND ND NDug/L 05/17/22 0.18 1 --ND ND ND ND ND ND ND
ug/L 10/10/22 0.27 1 --DRY ND ND ND ND ND NDug/L 05/22/23 0.18 1 --DRY ND ND 0.181 B ND ND 0.205 J
11 of 20
September 2023 31404568.018
MW-5 MW-6 MW-7 MW-8 MW-9 MW-10S
Summary of Historical Groundwater Monitoring Results
TABLE 4
Closed Randolph County Landfill, Permit No. 76-01
SWS Reporting Limit
Detected Monitoring
Constituent/Parameter Units Date BlanksDetection Limit
Downgradient WellsUpgradient WellQuanitation Limit
1,4-Dichlorobenzene ug/L 09/22/94 ----5 ND ND ND ND ND --NDNC 2L = 6 ug/L ug/L 11/08/94 ----5 ND ND ND ND ND --NDEPA MCL = 75 ug/L ug/L 01/18/95 ----5 ND ND ND ND ND --NDug/L 04/23/96 ----5 ND ND ND ND ND --NDug/L 06/17/97 ----5 ND ND ND ND ND --NDug/L 10/16/97 ----5 ND ND ND ND ND --NDug/L 04/21/98 ----5 ND ND ND ND ND --NDug/L 04/07/99 ----5 ND ND ND ND ND --ND
ug/L 10/13/99 ----5 ND ND ND ND ND --NDug/L 04/05/00 ----5 ND ND ND ND ND --NDug/L 10/25/00 ----5 ND ND ND ND ND --NDug/L 04/04/01 ----5 ND ND ND ND ND --NDug/L 04/04/02 ----5 ND ND ND ND ND --NDug/L 10/21/02 ----5 ND ND ND ND ND --NDug/L 04/14/03 ----5 ND ND ND ND ND --NDug/L 10/01/03 ----5 ND ND ND ND ND --NDug/L 04/05/04 ----5 ND ND ND ND ND --NDug/L 10/18/04 ----5 ND ND ND ND ND --NDug/L 04/07/05 ----5 ND ND ND ND ND --NDug/L 10/06/05 ----5 ND ND ND ND ND --ND
ug/L 04/03/06 ----5 ND ND ND ND ND --NDug/L 10/03/06 ----5 ND ND ND ND ND --NDug/L 04/05/07 ----3 ND ND ND ND ND --NDug/L 10/18/07 ----1 ND ND --ND ND --NDug/L 04/29/08 ----1 ND ND ND ND ND --NDug/L 10/23/08 ----1 ND ND ND ND ND --NDug/L 04/07/09 ----1 ND ND ND ND ND --NDug/L 10/19/09 ----1 ND ND ND ND ND --NDug/L 04/28/10 ----1 ND ND 0.67 J ND ND --NDug/L 10/12/10 ----1 ND ND ND ND ND --NDug/L 04/11/11 ----1 ND ND ND ND ND --NDug/L 10/04/11 ----1 ND ND 1.0 ND ND ND NDug/L 04/10/12 ----1 ND ND ND ND ND --ND
ug/L 10/15/12 ----1 ND ND ND ND ND --NDug/L 04/09/13 ----1 ND ND 0.84 J ND ND --NDug/L 10/08/13 ----1 ND ND 0.67 J ND ND --NDug/L 04/08/14 ----1 ND ND ND ND ND --NDug/L 10/08/14 0.19 --1 ND ND ND ND ND --NDug/L 04/08/15 0.19 --1 ND ND ND ND ND --NDug/L 10/28/15 0.19 --1 ND ND 0.57 J ND ND 0.67 J NDug/L 04/05/16 0.19 --1 ND ND ND ND ND ND NDug/L 10/04/16 0.19 --1 ND ND ND ND ND ND NDug/L 04/03/17 0.19 --1 ND ND 0.55 J ND ND 0.77 J NDug/L 10/03/17 0.19 --1 ND ND 0.73 J ND ND 0.72 J NDug/L 05/22/18 0.19 --1 ND ND ND ND ND 0.41 J NDug/L 10/23/18 0.19 1 --ND ND 0.45 J ND ND 1.1 ND
ug/L 04/16/19 0.19 1 --ND ND ND ND ND 0.62 J NDug/L 10/15/19 0.19 1 --ND ND 0.46 J ND ND 0.83 J NDug/L 04/14/20 0.19 1 --ND ND ND ND ND 0.43 J NDug/L 10/07/20 0.19 1 --ND ND ND ND ND 0.85 J NDug/L 05/10/21 0.19 1 --ND ND ND ND ND 0.49 J NDug/L 10/06/21 0.19 1 --ND ND ND ND ND ND NDug/L 05/17/22 0.19 1 --ND ND ND ND ND ND NDug/L 10/10/22 0.31 1 --DRY ND 0.51 J ND ND 0.97 J NDug/L 05/22/23 0.19 1 --DRY ND ND ND ND ND NDDichlorodifluoromethaneug/L 09/22/94 ----5 ND ND ND ND ND --NDNC 2L = 1000 ug/L ug/L 11/08/94 ----5 ND ND ND ND ND --ND(No EPA MCL)ug/L 01/18/95 ----5 ND ND ND ND ND --ND
ug/L 04/23/96 ----5 ND ND 38 ND ND --NDug/L 06/17/97 ----5 ND ND ND ND ND --NDug/L 10/16/97 ----5 ND ND ND --------ug/L 04/21/98 ----5 ND ND ND ND ND --NDug/L 04/07/99 ----5 ND ND ND ND ND --NDug/L 10/13/99 ----5 ND ND ND ND ND --NDug/L 04/05/00 ----5 ND ND 5.8 ND ND --NDug/L 10/25/00 ----5 ND ND 8.8 ND ND --NDug/L 04/04/01 ----5 ND ND 8.1 ND ND --NDug/L 04/08/02 ----5 ND ND 7.2 ND ND --NDug/L 10/21/02 ----5 ND ND ND ND ND --NDug/L 04/14/03 ----5 ND ND 6.2 ND ND --ND
ug/L 10/01/03 ----5 ND ND ND ND ND --NDug/L 04/05/04 ----5 ND ND 7.1 ND ND --NDug/L 10/18/04 ----5 ND ND ND ND ND --NDug/L 04/07/05 ----5 ND ND ND ND ND --NDug/L 10/06/05 ----5 ND ND 8.1 ND ND --NDug/L 04/03/06 ----5 ND ND ND ND ND --NDug/L 10/03/06 ----5 ND ND ND ND ND --NDug/L 04/05/07 ----5 ND ND ND ND ND --NDug/L 10/18/07 ----5 ND ND --0.8 J ND --NDug/L 04/29/08 ----5 ND ND 1.2 J ND ND --NDug/L 04/07/09 ----5 ND ND 1.8 J 0.71 J ND --NDug/L 10/19/09 ----5 ND ND 2.0 J 0.58 J ND --NDug/L 04/28/10 ----5 ND ND 1.1 J ND ND --ND
ug/L 04/11/11 ----5 ND ND 0.63 J ND ND 4.0 J NDug/L 04/10/12 ----5 ND ND 0.52 J ND ND --NDug/L 04/09/13 ----5 ND ND ND ND ND --NDug/L 10/08/13 ----5 ND ND ND ND ND --NDug/L 04/08/14 ----5 ND ND ND ND ND --NDug/L 04/08/15 0.20 --5 ND ND ND ND ND --NDug/L 10/28/15 0.20 --5 ND ND ND 0.48 J ND 1.8 J NDug/L 04/05/16 0.20 --5 ND ND ND ND ND 1.5 J NDug/L 10/04/16 0.20 --5 ND ND ND ND ND 1.2 J NDug/L 04/03/17 0.20 --5 ND ND ND ND ND 1.8 J NDug/L 10/03/17 0.20 --5 ND ND ND ND ND 4.1 J NDug/L 05/22/18 0.20 --5 ND ND ND ND ND 0.43 J NDug/L 10/23/18 0.20 1 --ND ND ND ND ND 1.5 ND
ug/L 04/16/19 0.20 1 --ND ND ND ND ND ND NDug/L 10/15/19 0.20 1 --ND ND ND ND ND 2.9 NDug/L 04/14/20 0.20 1 --ND ND ND ND ND ND NDug/L 10/07/20 0.20 1 --ND ND ND ND ND 1.6 NDug/L 05/10/21 0.20 1 --ND ND ND ND ND ND NDug/L 10/06/21 0.20 1 --ND ND ND ND ND ND NDug/L 05/17/22 0.20 1 --ND ND ND ND ND ND NDug/L 10/10/22 0.36 1 --DRY ND ND ND ND ND NDug/L 05/22/23 0.20 1 --DRY ND ND ND ND 1.18 ND
12 of 20
September 2023 31404568.018
MW-5 MW-6 MW-7 MW-8 MW-9 MW-10S
Summary of Historical Groundwater Monitoring Results
TABLE 4
Closed Randolph County Landfill, Permit No. 76-01
SWS Reporting Limit
Detected Monitoring
Constituent/Parameter Units Date BlanksDetection Limit
Downgradient WellsUpgradient WellQuanitation Limit
1,1-Dichloroethane ug/L 09/22/94 ----5 ND ND ND ND ND --NDNC 2L = 6 ug/L ug/L 11/08/94 ----5 ND ND 17 ND ND --ND(No EPA MCL)ug/L 01/18/95 ----5 ND ND 13 ND ND --NDug/L 04/23/96 ----5 ND ND 21 ND ND --NDug/L 06/17/97 ----5 ND ND ND ND ND --NDug/L 10/16/97 ----5 ND ND 13 ND ND --NDug/L 04/21/98 ----5 ND ND 13 ND ND --NDug/L 04/07/99 ----5 ND ND 17 ND ND --ND
ug/L 10/13/99 ----5 ND ND 20 ND ND --NDug/L 04/05/00 ----5 ND ND 26 ND ND --NDug/L 10/25/00 ----5 ND ND 31 ND ND --NDug/L 04/04/01 ----5 ND ND 39 ND ND --NDug/L 04/08/02 ----5 ND ND 15.6 ND ND --NDug/L 10/21/02 ----5 ND ND 35.6 ND ND --NDug/L 04/14/03 ----5 ND ND 12.8 ND ND --NDug/L 10/01/03 ----5 ND ND 6.1 ND ND --NDug/L 04/05/04 ----5 ND ND 13.5 ND ND --NDug/L 10/18/04 ----5 ND ND ND ND ND --NDug/L 04/07/05 ----5 ND ND ----------ug/L 10/06/05 ----5 ND ND 16.4 ND ND --ND
ug/L 04/03/06 ----5 ND ND 5.4 ND ND --NDug/L 10/03/06 ----5 ND ND 12 ND ND --NDug/L 04/05/07 ----5 ND ND 6 ND ND --NDug/L 10/18/07 ----5 ND ND --2.2 J 1.2 J --NDug/L 04/29/08 ----5 ND ND 7.8 1.7 J 2.5 J --NDug/L 10/23/08 ----5 ND ND 15 2.6 J 1.4 J --NDug/L 04/07/09 ----5 ND ND 6.8 2.5 J 3.0 J --NDug/L 10/19/09 ----5 ND ND 11 2.6 J 1.1 J --NDug/L 04/28/10 ----5 ND 1.1 J 6.9 2.4 J 2.7 J --NDug/L 10/12/10 ----5 ND 0.59 J 12 3.9 J 1.5 J --NDug/L 04/11/11 ----5 ND ND 5.8 3.7 J 1.7 J --NDug/L 10/04/11 ----5 ND ND 13 5.6 1.9 J 26 NDug/L 04/10/12 ----5 ND ND 5.1 4.3 J 2.5 J --ND
ug/L 10/15/12 ----5 ND ND 6.6 5.7 0.88 J --NDug/L 04/09/13 ----5 ND ND 4.3 J 6.9 1.0 J --NDug/L 10/08/13 ----5 ND ND 4.0 J 5.1 1.1 J --NDug/L 04/08/14 ----5 ND ND 3.0 J 6.6 1.3 J --ND
ug/L 10/08/14 0.13 --5 ND 0.41 J 3.4 J 9.8 0.80 J --NDug/L 04/08/15 0.13 --5 ND 0.54 J 1.4 J 3.2 J ND --NDug/L 10/28/15 0.13 --5 ND ND 3.1 J 11 0.90 J 59 NDug/L 04/05/16 0.13 --5 ND ND 2.0 J 6.8 1.4 J 23 NDug/L 10/04/16 0.13 --5 ND ND 2.3 J 10 0.81 J 21 NDug/L 04/03/17 0.13 --5 ND 0.46 J 2.1 J 10 0.86 J 36 NDug/L 10/03/17 0.13 --5 ND 3.6 J 1.9 J 12 1.2 J 57 NDug/L 05/22/18 0.13 --5 ND ND 1.2 J 8.7 0.50 J 21 NDug/L 10/23/18 0.13 1 --ND ND 1.1 5.5 0.53 J 43 ND
ug/L 04/16/19 0.13 1 --ND ND ND 5.8 ND 27 NDug/L 10/15/19 0.13 1 --ND 4.2 1.2 13 0.96 J 71 NDug/L 04/14/20 0.13 1 --ND ND ND 8.7 0.42 J 18 NDug/L 10/07/20 0.13 1 --ND 1.8 0.58 J 7.4 0.70 J 36 NDug/L 05/10/21 0.13 1 --ND 1.5 ND 3.0 ND 22 NDug/L 10/06/21 0.13 1 --ND ND ND 13 ND 49 NDug/L 05/17/22 0.13 1 --ND 1.8 ND 7.9 ND 17 NDug/L 10/10/22 0.33 1 --DRY ND 0.90 J 7.5 0.74 J 44 ND
ug/L 05/22/23 0.13 1 --DRY 1.05 0.359 J 2.61 0.48 J 38.3 ND1,2-Dichloroethane ug/L 09/22/94 ----5 ND ND ND ND ND --NDNC 2L = 0.4 ug/L ug/L 11/08/94 ----5 ND ND ND ND ND --NDEPA MCL = 5 ug/L ug/L 01/18/95 ----5 ND ND ND ND ND --NDug/L 04/23/96 ----5 ND ND ND ND ND --NDug/L 06/17/97 ----5 ND ND ND ND ND --NDug/L 10/16/97 ----5 ND ND ND ND ND --NDug/L 04/21/98 ----5 ND ND ND ND ND --NDug/L 04/07/99 ----5 ND ND ND ND ND --NDug/L 10/13/99 ----5 ND ND ND ND ND --NDug/L 04/05/00 ----5 ND ND ND ND ND --NDug/L 10/25/00 ----5 ND ND ND ND ND --NDug/L 04/04/01 ----5 ND ND ND ND ND --ND
ug/L 04/08/02 ----5 ND ND ND ND ND --NDug/L 10/21/02 ----5 ND ND ND ND ND --NDug/L 04/14/03 ----5 ND ND ND ND ND --NDug/L 10/01/03 ----5 ND ND ND ND ND --NDug/L 04/05/04 ----5 ND ND ND ND ND --NDug/L 10/18/04 ----5 ND ND ND ND ND --NDug/L 04/07/05 ----5 ND ND ND ND ND --NDug/L 10/06/05 ----5 ND ND ND ND ND --NDug/L 04/03/06 ----5 ND ND ND ND ND --NDug/L 10/03/06 ----5 ND ND ND ND ND --NDug/L 04/05/07 ----3 ND ND ND ND ND --NDug/L 10/18/07 ----1 ND ND --ND ND --ND
ug/L 04/29/08 ----1 ND ND ND ND ND --NDug/L 10/23/08 ----1 ND ND ND ND ND --NDug/L 04/07/09 ----1 ND ND ND ND ND --NDug/L 10/19/09 ----1 ND ND ND ND ND --NDug/L 04/28/10 ----1 ND ND ND ND ND --NDug/L 10/12/10 ----1 ND ND ND ND ND --NDug/L 04/11/11 ----1 ND ND ND ND ND --NDug/L 10/04/11 ----1 ND ND ND ND ND ND NDug/L 04/10/12 ----1 ND ND ND ND ND --NDug/L 10/15/12 ----1 ND ND ND ND ND --NDug/L 04/09/13 ----1 ND ND ND ND ND --NDug/L 10/08/13 ----1 ND ND ND ND ND --NDug/L 04/08/14 ----1 ND ND ND ND ND --ND
ug/L 10/08/14 0.21 --1 ND ND ND ND ND --NDug/L 04/08/15 0.21 --1 ND ND ND ND ND --NDug/L 10/28/15 0.21 --1 ND ND ND ND ND ND NDug/L 04/05/16 0.21 --1 ND ND ND ND ND ND NDug/L 10/04/16 0.21 --1 ND ND ND ND ND ND NDug/L 04/03/17 0.21 --1 ND ND ND ND ND ND NDug/L 10/03/17 0.21 --1 ND ND ND ND ND ND NDug/L 05/22/18 0.21 --1 ND ND ND ND ND ND NDug/L 10/23/18 0.21 1 --ND ND ND ND ND ND NDug/L 04/16/19 0.21 1 --ND ND ND ND ND ND NDug/L 10/15/19 0.21 1 --ND ND ND ND ND ND NDug/L 04/14/20 0.21 1 --ND ND ND ND ND ND ND
ug/L 10/07/20 0.21 1 --ND ND ND ND ND ND NDug/L 05/10/21 0.21 1 --ND ND ND ND ND ND NDug/L 10/06/21 0.21 1 --ND ND ND ND ND ND NDug/L 05/17/22 0.21 1 --ND ND ND ND ND ND NDug/L 10/10/22 0.25 1 --DRY ND ND ND ND 0.39 J NDug/L 05/22/23 0.21 1 --DRY 1.05 ND ND ND 0.422 J ND
13 of 20
September 2023 31404568.018
MW-5 MW-6 MW-7 MW-8 MW-9 MW-10S
Summary of Historical Groundwater Monitoring Results
TABLE 4
Closed Randolph County Landfill, Permit No. 76-01
SWS Reporting Limit
Detected Monitoring
Constituent/Parameter Units Date BlanksDetection Limit
Downgradient WellsUpgradient WellQuanitation Limit
1,1-Dichloroethene ug/L 09/22/94 ----5 ND ND ND ND ND --NDNC 2L = 350 ug/L ug/L 11/08/94 ----5 ND ND ND ND ND --NDEPA MCL = 7 ug/L ug/L 01/18/95 ----5 ND ND ND ND ND --NDug/L 04/23/96 ----5 ND ND ND ND ND --NDug/L 06/17/97 ----5 ND ND ND ND ND --NDug/L 10/16/97 ----5 ND ND ND ND ND --NDug/L 04/21/98 ----5 ND ND ND ND ND --NDug/L 04/07/99 ----5 ND ND ND ND ND --ND
ug/L 10/13/99 ----5 ND ND ND ND ND --NDug/L 04/05/00 ----5 ND ND ND ND ND --NDug/L 10/25/00 ----5 ND ND ND ND ND --NDug/L 04/04/01 ----5 ND ND ND ND ND --NDug/L 04/08/02 ----5 ND ND ND ND ND --NDug/L 10/21/02 ----5 ND ND ND ND ND --NDug/L 04/14/03 ----5 ND ND ND ND ND --NDug/L 10/01/03 ----5 ND ND ND ND ND --NDug/L 04/05/04 ----5 ND ND ND ND ND --NDug/L 10/18/04 ----5 ND ND ND ND ND --NDug/L 04/07/05 ----5 ND ND ND ND ND --NDug/L 10/06/05 ----5 ND ND ND ND ND --ND
ug/L 10/03/06 ----5 ND ND 11.2 ND ND --NDug/L 10/18/07 ----5 ND ND --ND ND --NDug/L 04/29/08 ----5 ND ND ND ND ND --NDug/L 10/23/08 ----5 ND ND ND ND ND --NDug/L 04/07/09 ----5 ND ND ND ND ND --NDug/L 10/19/09 ----5 ND ND ND ND ND --NDug/L 04/28/10 ----5 ND ND ND ND ND --NDug/L 10/12/10 ----5 ND ND 0.42 J ND ND --NDug/L 04/11/11 ----5 ND ND ND ND ND --NDug/L 10/04/11 ----5 ND ND ND ND ND ND NDug/L 04/10/12 ----5 ND ND ND ND ND --NDug/L 10/15/12 ----5 ND ND ND ND ND --NDug/L 04/09/13 ----5 ND ND ND ND ND --ND
ug/L 10/08/13 ----5 ND ND ND ND ND --NDug/L 04/08/14 ----5 ND ND ND ND ND --NDug/L 10/08/14 0.21 --5 ND ND ND ND ND --NDug/L 04/08/15 0.21 --5 ND ND ND ND ND --NDug/L 10/28/15 0.21 --5 ND ND ND ND ND 0.82 J NDug/L 04/05/16 0.21 --5 ND ND ND ND ND ND NDug/L 10/04/16 0.21 --5 ND ND ND ND ND ND NDug/L 04/03/17 0.21 --5 ND ND ND ND ND ND NDug/L 10/03/17 0.21 --5 ND ND ND ND ND 0.72 J NDug/L 05/22/18 0.21 --5 ND ND ND ND ND ND NDug/L 10/23/18 0.21 1 --ND ND ND ND ND ND NDug/L 04/16/19 0.21 1 --ND ND ND ND ND ND ND
ug/L 10/15/19 0.21 1 --ND ND ND ND ND 0.59 J NDug/L 04/14/20 0.21 1 --ND ND ND ND ND ND NDug/L 10/07/20 0.21 1 --ND ND ND ND ND ND NDug/L 05/10/21 0.21 1 --ND ND ND ND ND ND NDug/L 10/06/21 0.21 1 --ND ND ND ND ND ND NDug/L 05/17/22 0.21 1 --ND ND ND ND ND ND NDug/L 10/10/22 0.33 1 --DRY ND ND ND ND ND NDug/L 05/22/23 0.21 1 --DRY ND ND ND ND ND NDcis-1,2-Dichloroethene ug/L 09/22/94 ----5 ND ND ND ND ND --NDNC 2L = 70 ug/L ug/L 11/08/94 ----5 ND ND ND ND ND --NDEPA MCL = 70 ug/L ug/L 01/18/95 ----5 ND ND ND ND ND --NDug/L 04/23/96 ----5 ND ND ND ND ND --NDug/L 06/17/97 ----5 ND ND ND ND ND --ND
ug/L 10/16/97 ----5 ND ND ND ND ND --NDug/L 04/21/98 ----5 ND ND ND ND ND --NDug/L 04/07/99 ----5 ND ND ND ND ND --NDug/L 10/13/99 ----5 ND ND ND ND ND --NDug/L 04/05/00 ----5 ND ND ND ND ND --NDug/L 10/25/00 ----5 ND ND ND ND ND --NDug/L 04/04/01 ----5 ND ND ND ND ND --NDug/L 04/08/02 ----5 ND ND ND ND ND --NDug/L 10/21/02 ----5 ND ND ND ND ND --NDug/L 04/14/03 ----5 ND ND ND ND ND --NDug/L 10/01/03 ----5 ND ND ND ND ND --NDug/L 04/05/04 ----5 ND ND ND ND ND --ND
ug/L 10/18/04 ----5 ND ND ND ND ND --NDug/L 04/07/05 ----5 ND ND ----------ug/L 10/06/05 ----5 ND ND ND ND ND --NDug/L 04/03/06 ----5 ND ND ND ND ND --NDug/L 10/03/06 ----5 ND ND ND ND ND --NDug/L 04/05/07 ----5 ND ND ND ND ND --NDug/L 10/18/07 ----5 ND ND --ND ND --NDug/L 04/29/08 ----5 ND ND 0.63 J ND 1.8 J --NDug/L 10/23/08 ----5 ND ND 1.4 J 0.40 J 0.80 J --NDug/L 04/07/09 ----5 ND ND 0.49 J ND 1.8 J --NDug/L 10/19/09 ----5 ND ND 1.6 J 0.48 J 0.73 J --NDug/L 04/28/10 ----5 ND ND 1.1 J 0.49 J 2.5 J --NDug/L 10/12/10 ----5 ND ND 1.9 J 0.69 J 0.90 J --ND
ug/L 04/11/11 ----5 ND ND 1.3 J 0.83 J 1.2 J --NDug/L 10/04/11 ----5 ND ND 1.8 J 0.84 J 0.86 J 2.6 J NDug/L 04/10/12 ----5 ND ND 1.2 J 0.85 J 3.3 J --NDug/L 10/15/12 ----5 ND ND 1.9 J 1.2 J 0.56 J --NDug/L 04/09/13 ----5 ND ND 1.5 J 0.91 J ND --NDug/L 10/08/13 ----5 ND ND 1.1 J 0.95 J 0.69 J --NDug/L 04/08/14 ----5 ND ND 0.97 J 1.2 J 1.5 J --NDug/L 10/08/14 0.15 --5 ND ND 1.2 J 1.8 J 0.46 J --NDug/L 04/08/15 0.15 --5 ND ND 0.41 J 0.60 J ND --NDug/L 10/28/15 0.15 --5 ND ND 1.1 J 2.2 J 0.53 J 6.3 NDug/L 04/05/16 0.15 --5 ND ND 0.75 J 1.1 J 2.2 J 2.3 J NDug/L 10/04/16 0.15 --5 ND ND 1.0 J 2.3 J 0.57 J 2.8 J ND
ug/L 04/03/17 0.15 --5 ND ND 0.97 J 1.7 J 0.50 J 4.2 J NDug/L 10/03/17 0.15 --5 ND ND 1.0 J 2.5 J 0.73 J 6.2 NDug/L 05/22/18 0.15 --5 ND ND 1.1 J 2.2 J 0.88 J 3.6 J NDug/L 10/23/18 0.15 1 --ND ND 0.85 J 1.6 ND 7.3 ND
ug/L 04/16/19 0.15 1 --ND ND 0.60 J 1.0 2.0 4.0 NDug/L 10/15/19 0.15 1 --ND ND 0.74 J 3.4 0.75 J 11 NDug/L 04/14/20 0.15 1 --ND ND ND 2.1 0.64 J 2.5 NDug/L 10/07/20 0.15 1 --ND ND 0.71 J 1.8 ND 6.8 NDug/L 05/10/21 0.15 1 --ND ND ND 1.0 ND 4.3 NDug/L 10/06/21 0.15 1 --ND ND ND 3.1 ND 7.3 NDug/L 05/17/22 0.15 1 --ND ND ND 1.7 ND 2.9 NDug/L 10/10/22 0.15 1 --ND ND ND 2.4 ND 9.9 NDug/L 05/22/23 0.15 1.0 --DRY ND 0.317 J 0.61 J 0.278 J 7.63 ND
14 of 20
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Summary of Historical Groundwater Monitoring Results
TABLE 4
Closed Randolph County Landfill, Permit No. 76-01
SWS Reporting Limit
Detected Monitoring
Constituent/Parameter Units Date BlanksDetection Limit
Downgradient WellsUpgradient WellQuanitation Limit
Chloromethane ug/L 09/22/94 ----10 ND ND ND ND ND --NDNC 2L = 3 ug/L ug/L 11/08/94 ----10 ND ND ND ND ND --ND(No EPA MCL)ug/L 01/18/95 ----10 ND ND ND ND ND --NDug/L 04/23/96 ----10 ND ND ND ND ND --NDug/L 06/17/97 ----10 ND ND ND ND ND --NDug/L 10/16/97 ----10 ND ND ND ND ND --NDug/L 04/21/98 ----10 ND ND ND ND ND --NDug/L 04/07/99 ----10 ND ND ND ND ND --ND
ug/L 10/13/99 ----10 ND ND ND ND ND --NDug/L 04/05/00 ----10 ND ND ND ND ND --NDug/L 10/25/00 ----10 ND ND ND ND ND --NDug/L 04/04/01 ----10 ND ND ND ND ND --NDug/L 04/08/02 ----10 ND ND ND ND ND --NDug/L 10/21/02 ----10 ND ND ND ND ND --NDug/L 04/14/03 ----10 ND ND ND ND ND --NDug/L 10/01/03 ----10 ND ND ND ND ND --NDug/L 04/05/04 ----10 ND ND ND ND ND --NDug/L 10/18/04 ----10 ND ND ND ND ND --NDug/L 04/07/05 ----10 ND ND ND ND ND --NDug/L 10/06/05 ----10 ND ND ND ND ND --ND
ug/L 04/03/06 ----10 ND ND ND ND ND --NDug/L 10/03/06 ----10 ND ND ND ND ND --NDug/L 04/05/07 ----5 ND ND ND ND ND --NDug/L 10/18/07 ----1 0.5 J 0.5 J --0.4 J 0.5 J --NDug/L 04/29/08 ----1 ND ND ND ND ND --NDug/L 10/23/08 ----1 ND ND ND ND ND --NDug/L 04/07/09 ----1 ND ND ND ND ND --NDug/L 10/19/09 ----1 ND ND ND ND ND --NDug/L 04/28/10 ----1 ND ND ND ND ND --NDug/L 10/12/10 ----1 ND 0.51 B 0.94 B 0.51 B 0.53 B --0.49 Jug/L 04/11/11 ----1 ND ND ND ND ND --NDug/L 10/04/11 ----1 ND ND ND ND ND ND NDug/L 04/10/12 ----1 ND ND ND ND ND --ND
ug/L 10/15/12 ----1 ND ND ND ND ND --NDug/L 04/09/13 ----1 ND ND ND ND ND --NDug/L 10/08/13 ----1 ND ND ND ND ND --NDug/L 04/08/14 ----1 ND ND ND ND ND --NDug/L 10/08/14 0.13 --1 ND ND ND ND ND --NDug/L 04/08/15 0.13 --1 ND ND ND ND ND --NDug/L 10/28/15 0.13 --1 ND ND ND ND ND ND NDug/L 04/05/16 0.13 --1 ND ND ND ND ND ND NDug/L 10/04/16 0.13 --1 ND ND ND ND ND ND NDug/L 04/03/17 0.13 --1 ND ND ND ND ND ND NDug/L 10/03/17 0.13 --1 ND ND ND ND ND ND NDug/L 05/22/18 0.13 --1 ND ND ND ND ND ND NDug/L 10/23/18 0.13 1 --ND ND ND ND ND ND ND
ug/L 04/16/19 0.13 1 --ND ND ND ND ND ND NDug/L 10/15/19 0.13 1 --ND ND ND ND ND ND NDug/L 04/14/20 0.13 1 --ND ND ND ND ND ND NDug/L 10/07/20 0.13 1 --ND ND ND ND ND ND NDug/L 05/10/21 0.13 1 --ND ND ND ND ND ND NDug/L 10/06/21 0.13 1 --ND ND ND ND ND ND NDug/L 05/17/22 0.13 1 --ND ND ND ND ND ND NDug/L 10/10/22 0.54 1 --DRY ND ND ND ND ND NDug/L 05/22/23 0.13 1 --DRY 0.147 J ND ND ND ND NDMethylene chloride ug/L 09/22/94 ----10 ND ND ND ND ND --NDNC 2L = 5 ug/L ug/L 11/08/94 ----10 ND ND ND ND ND --NDEPA MCL = 5 ug/L ug/L 01/18/95 ----10 ND ND ND ND ND --ND
ug/L 04/23/96 ----10 ND ND ND ND ND --NDug/L 06/17/97 ----10 ND ND ND ND ND --NDug/L 10/16/97 ----10 ND ND ND ND ND --NDug/L 04/21/98 ----10 ND ND ND ND ND --NDug/L 04/07/99 ----10 ND ND ND ND ND --NDug/L 10/13/99 ----10 ND ND ND ND ND --NDug/L 04/05/00 ----10 ND ND 35 ND ND --NDug/L 10/25/00 ----10 ND ND 44 ND ND --NDug/L 04/04/01 ----10 ND ND 49 ND ND --NDug/L 04/08/02 ----10 ND ND 18.9 ND ND --NDug/L 10/21/02 ----10 ND ND 33.6 ND ND --NDug/L 04/14/03 ----10 ND ND 17.4 ND ND --ND
ug/L 10/01/03 ----10 ND ND ND ND ND --NDug/L 04/05/04 ----10 ND ND 14.6 ND ND --NDug/L 10/18/04 ----10 ND ND ND ND ND --NDug/L 04/07/05 ----10 ND ND ND ND ND --NDug/L 10/06/05 ----10 ND ND 10.4 ND ND --NDug/L 04/03/06 ----10 ND ND ND ND ND --NDug/L 10/03/06 ----10 ND ND ND ND ND --NDug/L 04/05/07 ----5 ND ND ND ND ND --NDug/L 10/18/07 ----1 ND ND --0.3 B ND --0.2 Jug/L 04/29/08 ----1 ND ND 7.0 ND ND --NDug/L 10/23/08 ----1 ND ND 11 ND ND --NDug/L 04/07/09 ----1 ND ND 5.4 ND ND --NDug/L 10/19/09 ----1 ND ND 8.5 ND ND --ND
ug/L 04/28/10 ----1 ND ND 7.5 ND ND --NDug/L 10/12/10 ----1 ND ND 12 ND ND --NDug/L 04/11/11 ----1 ND ND 4.4 0.45 J ND --NDug/L 10/04/11 ----1 ND ND 7.4 0.75 J ND 0.72 J NDug/L 04/10/12 ----1 ND ND 3.8 0.34 J ND --NDug/L 10/15/12 ----1 ND ND 4.6 0.47 J ND --NDug/L 04/09/13 ----1 ND ND 1.8 ND ND --NDug/L 10/08/13 ----1 ND ND 0.40 J ND ND --NDug/L 04/08/14 ----1 ND ND 0.97 J ND ND --NDug/L 10/08/14 0.23 --1 ND ND ND ND ND --NDug/L 04/08/15 0.23 --1 ND ND ND ND ND --NDug/L 10/28/15 0.23 --1 ND ND ND ND ND 0.47 J ND
ug/L 04/05/16 0.23 --1 ND ND 1.2 ND ND 0.43 J NDug/L 10/04/16 0.23 --1 ND ND ND ND ND ND NDug/L 04/03/17 0.23 --1 ND ND ND ND ND ND NDug/L 10/03/17 0.23 --1 ND ND ND ND ND ND 1.2ug/L 05/22/18 0.23 --1 ND ND ND ND ND ND NDug/L 10/23/18 0.23 1 --ND ND 0.44 J ND ND ND ND
ug/L 04/16/19 0.23 1 --ND ND ND ND ND ND NDug/L 10/15/19 0.23 1 --ND ND 0.60 J ND ND 0.67 J NDug/L 04/14/20 0.23 1 --ND ND ND ND ND ND 0.47 Jug/L 10/07/20 0.23 1 --ND ND ND ND ND ND NDug/L 05/10/21 0.23 1 --ND ND ND ND ND ND NDug/L 10/06/21 0.23 1 --ND ND ND ND ND ND NDug/L 05/17/22 0.23 1 --ND ND ND ND ND ND ND
ug/L 10/10/22 3.2 5 --DRY ND ND ND ND ND NDug/L 05/22/23 0.23 1 --DRY ND ND ND ND 0.241 B 0.2518 J
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September 2023 31404568.018
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Summary of Historical Groundwater Monitoring Results
TABLE 4
Closed Randolph County Landfill, Permit No. 76-01
SWS Reporting Limit
Detected Monitoring
Constituent/Parameter Units Date BlanksDetection Limit
Downgradient WellsUpgradient WellQuanitation Limit
2-Butanone ug/L 09/22/94 ----100 ND ND ND ND ND --NDNC 2L = 4000 ug/L ug/L 11/08/94 ----100 ND ND ND ND ND --ND(No EPA MCL)ug/L 01/18/95 ----100 ND ND ND ND ND --NDug/L 04/23/96 ----100 ND ND ND ND ND --NDug/L 06/17/97 ----100 ND ND ND ND ND --NDug/L 10/16/97 ----100 ND ND ND ND ND --NDug/L 04/21/98 ----100 ND ND ND ND ND --NDug/L 04/07/99 ----100 ND ND ND ND ND --ND
ug/L 10/13/99 ----100 ND ND ND ND ND --NDug/L 04/05/00 ----100 ND ND ND ND ND --NDug/L 10/25/00 ----100 ND ND ND ND ND --NDug/L 04/04/01 ----100 ND ND ND ND ND --NDug/L 04/08/02 ----100 ND ND ND ND ND --NDug/L 10/21/02 ----100 ND ND ND ND ND --NDug/L 04/14/03 ----100 ND ND ND ND ND --NDug/L 10/01/03 ----100 ND ND ND ND ND --NDug/L 04/05/04 ----100 ND ND ND ND ND --NDug/L 10/18/04 ----100 ND ND ND ND ND --NDug/L 04/07/05 ----100 ND ND ND ND ND --NDug/L 10/06/05 ----100 ND ND ND ND ND --ND
ug/L 04/03/06 ----100 ND ND ND ND ND --NDug/L 10/03/06 ----100 ND ND ND ND ND --NDug/L 04/05/07 ----100 ND ND ND ND ND --NDug/L 10/18/07 ----100 ND ND --ND ND --NDug/L 04/29/08 ----100 ND ND ND ND ND --NDug/L 10/23/08 ----100 ND ND ND ND ND --NDug/L 04/07/09 ----100 ND ND ND ND ND --NDug/L 10/19/09 ----100 ND ND ND ND ND --NDug/L 04/28/10 ----100 ND ND ND ND ND --NDug/L 10/12/10 ----100 ND ND ND ND ND --NDug/L 04/11/11 ----100 ND ND ND ND ND --NDug/L 10/04/11 ----100 ND ND ND ND ND ND NDug/L 04/10/12 ----100 ND ND ND ND ND --ND
ug/L 10/15/12 ----100 ND ND ND ND ND --NDug/L 04/09/13 ----100 ND ND ND ND ND --NDug/L 10/08/13 ----100 ND ND ND ND ND --NDug/L 04/08/14 ----100 ND ND ND ND ND --NDug/L 10/08/14 1.3 --100 ND ND ND ND ND --NDug/L 04/08/15 1.3 --100 ND 4.0 J ND ND ND --NDug/L 10/28/15 1.3 --100 ND ND ND ND ND ND NDug/L 04/05/16 1.3 --100 ND ND ND ND ND ND NDug/L 10/04/16 1.3 --100 ND ND ND ND ND ND NDug/L 04/03/17 1.3 --100 ND ND ND ND ND ND NDug/L 10/03/17 1.3 --100 ND ND ND ND ND ND NDug/L 05/22/18 1.3 --100 ND ND ND ND ND ND NDug/L 10/23/18 1.3 5 --ND ND ND ND ND ND ND
ug/L 04/16/19 1.3 5 --ND ND ND ND ND ND NDug/L 10/15/19 1.3 5 --ND ND ND ND ND ND NDug/L 04/14/20 1.3 5 --ND ND ND ND ND ND NDug/L 10/07/20 1.3 5 --ND ND ND ND ND ND NDug/L 05/10/21 1.3 5 --ND ND ND ND ND ND NDug/L 10/06/21 1.3 5 --ND ND ND ND ND ND NDug/L 05/17/22 1.3 5 --2.6 B ND ND ND ND 2.8 B 11ug/L 10/10/22 6.4 10 --DRY ND ND ND ND ND NDug/L 05/22/23 10 20 --DRY ND ND ND ND ND ND4-Methyl-2-pentanone ug/L 09/22/94 ----50 ND ND ND ND ND --NDIMAC = 100 ug/L ug/L 11/08/94 ----50 ND ND ND ND ND --NDEPA MCL = 5 ug/L ug/L 01/18/95 ----50 ND ND ND ND ND --ND
ug/L 04/23/96 ----50 ND ND ND ND ND --NDug/L 06/17/97 ----50 ND ND ND ND ND --NDug/L 10/16/97 ----50 ND ND ND ND ND --NDug/L 04/21/98 ----50 ND ND ND ND ND --NDug/L 04/07/99 ----50 ND ND ND ND ND --NDug/L 10/13/99 ----50 ND ND ND ND ND --NDug/L 04/05/00 ----50 ND ND ND ND ND --NDug/L 10/25/00 ----50 ND ND ND ND ND --NDug/L 04/04/01 ----50 ND ND ND ND ND --NDug/L 04/08/02 ----50 ND ND ND ND ND --NDug/L 10/21/02 ----100 ND ND ND ND ND --NDug/L 04/14/03 ----100 ND ND ND ND ND --ND
ug/L 10/01/03 ----100 ND ND ND ND ND --NDug/L 04/05/04 ----100 ND ND ND ND ND --NDug/L 10/18/04 ----100 ND ND ND ND ND --NDug/L 04/07/05 ----100 ND ND ND ND ND --NDug/L 10/06/05 ----100 ND ND ND ND ND --NDug/L 04/03/06 ----100 ND ND ND ND ND --NDug/L 10/03/06 ----100 ND ND ND ND ND --NDug/L 04/05/07 ----100 ND ND ND ND ND --NDug/L 10/18/07 ----100 ND ND --ND ND --NDug/L 04/29/08 ----100 ND ND ND ND ND --NDug/L 10/23/08 ----100 ND ND ND ND ND --NDug/L 04/07/09 ----100 ND ND ND ND ND --NDug/L 10/19/09 ----100 ND ND ND ND ND --ND
ug/L 04/28/10 ----100 ND ND ND ND ND --NDug/L 10/12/10 ----100 ND ND ND ND ND --NDug/L 04/11/11 ----100 ND ND ND ND ND --NDug/L 10/04/11 ----100 ND ND ND ND ND ND NDug/L 04/10/12 ----100 ND ND ND ND ND --NDug/L 10/15/12 ----100 ND ND ND ND ND --NDug/L 04/09/13 ----100 ND ND ND ND ND --NDug/L 10/08/13 ----100 ND ND ND ND ND --NDug/L 04/08/14 ----100 ND ND ND ND ND --NDug/L 10/08/14 1.1 --100 ND 1.4 J ND ND ND --NDug/L 04/08/15 1.1 --100 ND 5.0 J ND ND ND --NDug/L 10/28/15 1.1 --100 ND ND ND ND ND ND ND
ug/L 04/05/16 1.1 --100 ND ND ND ND ND ND NDug/L 10/04/16 1.1 --100 ND ND ND ND ND ND NDug/L 04/03/17 1.1 --100 ND ND ND ND ND ND NDug/L 10/03/17 1.1 --100 ND ND ND ND ND ND NDug/L 05/22/18 1.1 --100 ND ND ND ND ND ND NDug/L 10/23/18 1.1 5 --ND ND ND ND ND ND ND
ug/L 04/16/19 1.1 5 --ND ND ND ND ND ND NDug/L 10/15/19 1.1 5 --ND ND ND ND ND ND NDug/L 04/14/20 1.1 5 --ND ND ND ND ND ND NDug/L 10/07/20 1.1 5 --ND ND ND ND ND ND NDug/L 05/10/21 1.1 5 --ND ND ND ND ND ND NDug/L 10/06/21 1.1 5 --ND ND ND ND ND ND NDug/L 05/17/22 1.1 5 --ND ND ND ND ND ND ND
ug/L 10/10/22 2.7 10 --DRY ND ND ND ND ND NDug/L 05/22/23 1.1 5 --DRY ND ND ND ND ND ND
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September 2023 31404568.018
MW-5 MW-6 MW-7 MW-8 MW-9 MW-10S
Summary of Historical Groundwater Monitoring Results
TABLE 4
Closed Randolph County Landfill, Permit No. 76-01
SWS Reporting Limit
Detected Monitoring
Constituent/Parameter Units Date BlanksDetection Limit
Downgradient WellsUpgradient WellQuanitation Limit
1,1-Dichloroethane ug/L 09/22/94 ----5 ND ND ND ND ND --NDNC 2L = 0.7 ug/L ug/L 11/08/94 ----5 ND ND ND ND ND --NDEPA MCL = 5 ug/L ug/L 01/18/95 ----5 ND ND ND ND ND --NDug/L 04/23/96 ----5 ND ND ND ND ND --NDug/L 06/17/97 ----5 ND ND ND ND ND --NDug/L 10/16/97 ----5 ND ND ND ND ND --NDug/L 04/21/98 ----5 ND ND ND ND ND --NDug/L 04/07/99 ----5 ND ND ND ND ND --ND
ug/L 10/13/99 ----5 ND ND ND ND ND --NDug/L 04/05/00 ----5 ND ND ND ND ND --NDug/L 10/25/00 ----5 ND ND ND ND ND --NDug/L 04/04/01 ----5 ND ND ND ND ND --NDug/L 04/08/02 ----5 ND ND ND ND ND --NDug/L 10/21/02 ----5 ND ND ND ND ND --NDug/L 04/14/03 ----5 ND ND ND ND ND --NDug/L 10/01/03 ----5 ND ND ND ND ND --NDug/L 04/05/04 ----5 ND ND ND ND ND --NDug/L 10/18/04 ----5 ND ND ND ND ND --NDug/L 04/07/05 ----5 ND ND ----------ug/L 10/06/05 ----5 ND ND ND ND ND --ND
ug/L 04/03/06 ----5 ND ND ND ND ND --NDug/L 10/03/06 ----5 ND ND ND ND ND --NDug/L 04/05/07 ----3 ND ND ND ND ND --NDug/L 10/18/07 ----1 ND ND --0.2 J 0.3 J --NDug/L 04/29/08 ----1 ND ND ND ND ND --NDug/L 10/23/08 ----1 ND ND ND ND ND --NDug/L 04/07/09 ----1 ND ND ND ND ND --NDug/L 10/19/09 ----1 ND ND ND ND ND --NDug/L 04/28/10 ----1 ND ND ND ND 0.49 J --NDug/L 10/12/10 ----1 ND ND ND 0.48 J ND --NDug/L 04/11/11 ----1 ND ND ND ND ND --NDug/L 10/04/11 ----1 ND ND ND ND ND 2.8 NDug/L 04/10/12 ----1 ND ND ND 0.56 J ND --ND
ug/L 10/15/12 ----1 ND ND ND 0.46 J ND --NDug/L 04/09/13 ----1 ND ND ND 0.77 J ND --NDug/L 10/08/13 ----1 ND ND ND 0.45 J ND --NDug/L 04/08/14 ----1 ND ND ND 0.64 J ND --NDug/L 10/08/14 0.17 --1 ND ND ND 0.71 J ND --NDug/L 04/08/15 0.17 --1 ND ND ND ND ND --NDug/L 10/28/15 0.17 --1 ND ND ND 0.98 J ND 7.0 NDug/L 04/05/16 0.17 --1 ND ND ND ND ND 1.0 NDug/L 10/04/16 0.17 --1 ND ND ND 0.66 J ND 1.3 NDug/L 04/03/17 0.17 --1 ND ND ND 0.63 J ND 1.6 NDug/L 10/03/17 0.17 --1 ND ND ND 1.3 ND 5.4 NDug/L 05/22/18 0.17 --1 ND ND ND ND ND 1.1 NDug/L 10/23/18 0.17 1 --ND ND ND 0.60 J ND 2.2 ND
ug/L 04/16/19 0.17 1 --ND ND ND 0.43 J ND 1.2 NDug/L 10/15/19 0.17 1 --ND ND ND 0.95 J ND 4.3 NDug/L 04/14/20 0.17 1 --ND ND ND 0.53 J ND 1.1 ND1.6 ND1.4 ND1.1 ND 2.6 ND0.75 J ND2.2 ND2.54 ND
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September 2023 31404568.018
MW-5 MW-6 MW-7 MW-8 MW-9 MW-10S
Summary of Historical Groundwater Monitoring Results
TABLE 4
Closed Randolph County Landfill, Permit No. 76-01
SWS Reporting Limit
Detected Monitoring
Constituent/Parameter Units Date BlanksDetection Limit
Downgradient WellsUpgradient WellQuanitation Limit
Trichloroethene ug/L 09/22/94 ----5 ND ND ND ND ND --NDNC 2L = 3 ug/L ug/L 11/08/94 ----5 ND ND ND ND ND --NDEPA MCL = 5 ug/L ug/L 01/18/95 ----5 ND ND ND ND ND --NDug/L 04/23/96 ----5 ND ND ND ND ND --NDug/L 06/17/97 ----5 ND ND ND ND ND --NDug/L 10/16/97 ----5 ND ND ND ND ND --NDug/L 04/21/98 ----5 ND ND ND ND ND --NDug/L 04/07/99 ----5 ND ND ND ND ND --ND
ug/L 10/13/99 ----5 ND ND ND ND ND --NDug/L 04/05/00 ----5 ND ND ND ND ND --NDug/L 10/25/00 ----5 ND ND ND ND ND --NDug/L 04/04/01 ----5 ND ND ND ND ND --NDug/L 04/08/02 ----5 ND ND ND ND ND --NDug/L 10/21/02 ----5 ND ND ND ND ND --NDug/L 04/14/03 ----5 ND ND ND ND ND --NDug/L 10/01/03 ----5 ND ND ND ND ND --NDug/L 04/05/04 ----5 ND ND ND ND ND --NDug/L 10/18/04 ----5 ND ND ND ND ND --NDug/L 04/07/05 ----5 ND ND ----------ug/L 10/06/05 ----5 ND ND ND ND ND --ND
ug/L 04/03/06 ----5 ND ND ND ND ND --NDug/L 10/03/06 ----5 ND ND ND ND ND --NDug/L 04/05/07 ----3 ND ND ND ND ND --NDug/L 10/18/07 ----1 ND ND --0.7 J 0.2 J --NDug/L 04/29/08 ----1 ND ND ND 0.67 J 0.41 J --NDug/L 10/23/08 ----1 ND ND 0.51 J 0.95 J ND --NDug/L 04/07/09 ----1 ND ND ND 0.90 J 0.46 J --NDug/L 10/19/09 ----1 ND ND 0.53 J 1.2 ND --NDug/L 04/28/10 ----1 ND ND ND 1.1 0.51 J --NDug/L 10/12/10 ----1 ND ND 0.46 J 1.5 ND --NDug/L 04/11/11 ----1 ND ND ND 1.4 ND --NDug/L 10/04/11 ----1 ND ND ND 1.6 ND 2.2 NDug/L 04/10/12 ----1 ND ND ND 1.6 0.39 J --ND
ug/L 10/15/12 ----1 ND ND ND 1.8 ND --NDug/L 04/09/13 ----1 ND ND ND 2.4 ND --NDug/L 10/08/13 ----1 ND ND ND 1.9 ND --NDug/L 04/08/14 ----1 ND ND ND 2.3 ND --NDug/L 10/08/14 0.15 --1 ND ND ND 2.7 ND --NDug/L 04/08/15 0.15 --1 ND ND ND 0.96 J ND --NDug/L 10/28/15 0.15 --1 0.50 J ND ND 3.1 ND 3.6 NDug/L 04/05/16 0.15 --1 ND ND ND 1.4 ND 0.99 J NDug/L 10/04/16 0.15 --1 ND ND ND 2.4 ND 1.4 NDug/L 04/03/17 0.15 --1 ND ND ND 2.9 ND 1.5 NDug/L 10/03/17 0.15 --1 ND ND ND 3.2 ND 4.1 NDug/L 05/22/18 0.15 --1 ND ND ND 1.9 ND 1.0 NDug/L 10/23/18 0.15 1 --ND ND ND 1.2 ND 2.1 ND
ug/L 04/16/19 0.15 1 --ND ND ND 1.4 ND 1.2 NDug/L 10/15/19 0.15 1 --ND ND ND 2.9 ND 3.9 NDug/L 04/14/20 0.15 1 --ND ND ND 1.9 ND 0.94 J NDug/L 10/07/20 0.15 1 --ND ND ND ND ND 1.5 NDug/L 05/10/21 0.15 1 --ND ND ND ND ND ND NDug/L 10/06/21 0.15 1 --ND ND ND 1.9 ND 2.3 NDug/L 05/17/22 0.15 1 --ND ND ND ND ND ND NDug/L 10/10/22 0.20 1 --DRY ND ND 1.6 ND 2.0 NDug/L 05/22/23 0.15 1 --DRY ND ND ND ND 1.92 NDTrichlorofluoromethaneug/L 09/22/94 ----5 ND ND 19 ND ND --NDNC 2L = 2000 ug/L ug/L 11/08/94 ----5 ND ND 29 ND ND --ND(No EPA MCL)ug/L 01/18/95 ----5 ND ND 20 ND ND --ND
ug/L 04/23/96 ----5 ND ND ND ND ND --NDug/L 06/17/97 ----5 ND ND ND ND ND --NDug/L 10/16/97 ----5 ND ND 14 ND ND --NDug/L 04/21/98 ----5 ND ND 15 ND ND --NDug/L 04/07/99 ----5 ND ND 9.9 ND ND --NDug/L 10/13/99 ----5 ND ND 7 ND ND --NDug/L 04/05/00 ----5 ND ND 6.5 ND ND --NDug/L 10/25/00 ----5 ND ND ND ND ND --NDug/L 04/04/01 ----5 ND ND 6 ND ND --NDug/L 04/08/02 ----5 ND ND ND ND ND --NDug/L 10/21/02 ----5 ND ND 6.9 ND ND --NDug/L 04/14/03 ----5 ND ND ND ND ND --ND
ug/L 10/01/03 ----5 ND ND ND ND ND --NDug/L 04/05/04 ----5 ND ND ND ND ND --NDug/L 10/18/04 ----5 ND ND ND ND ND --NDug/L 04/07/05 ----5 ND ND ND ND ND --NDug/L 10/06/05 ----5 ND ND ND ND ND --NDug/L 04/03/06 ----5 ND ND ND ND ND --NDug/L 10/03/06 ----5 ND ND ND ND ND --NDug/L 04/05/07 ----5 ND ND ND ND ND --NDug/L 10/18/07 ----1 ND ND --0.5 J ND --NDug/L 04/29/08 ----1 ND ND 1.1 ND ND --NDug/L 10/23/08 ----1 ND ND 1.1 0.65 J ND --NDug/L 04/07/09 ----1 ND ND 1.1 0.86 J ND --NDug/L 10/19/09 ----1 ND ND 1.1 0.62 J ND --ND
ug/L 04/28/10 ----1 ND ND 1.0 0.49 J ND --NDug/L 10/12/10 ----1 ND ND 1.8 0.66 J ND --NDug/L 04/11/11 ----1 ND ND ND ND ND --NDug/L 10/04/11 ----1 ND ND 1.7 0.73 J ND 3.9 NDug/L 04/10/12 ----1 ND ND 0.55 J 0.36 J ND --NDug/L 10/15/12 ----1 ND ND 0.72 J ND ND --NDug/L 04/09/13 ----1 ND ND 0.47 J 0.70 J ND --NDug/L 10/08/13 ----1 ND ND 0.47 J ND ND --NDug/L 04/08/14 ----1 ND ND ND ND ND --NDug/L 10/08/14 0.24 --1 ND ND ND ND ND --NDug/L 04/08/15 0.24 --1 ND ND ND ND ND --NDug/L 10/28/15 0.24 --1 ND ND ND ND ND 3.2 ND
ug/L 04/05/16 0.24 --1 ND ND ND ND ND 1.5 NDug/L 10/04/16 0.24 --1 ND ND ND ND ND ND NDug/L 04/03/17 0.24 --1 ND ND ND ND ND 1.1 NDug/L 10/03/17 0.24 --1 ND ND ND ND ND 3.1 NDug/L 05/22/18 0.24 --1 ND ND ND ND ND ND NDug/L 10/23/18 0.24 1 --ND ND ND ND ND 0.68 J ND
ug/L 04/16/19 0.24 1 --ND ND ND ND ND ND NDug/L 10/15/19 0.24 1 --ND ND ND ND ND 1.6 NDug/L 04/14/20 0.24 1 --ND ND ND ND ND ND NDug/L 10/07/20 0.24 1 --ND ND ND ND ND ND NDug/L 05/10/21 0.24 1 --ND ND ND ND ND ND NDug/L 10/06/21 0.24 1 --ND ND ND ND ND ND NDug/L 05/17/22 0.24 1 --ND ND ND ND ND ND ND
ug/L 10/10/22 0.33 1 --DRY ND ND ND ND 1.0 NDug/L 05/22/23 0.24 1 --DRY ND ND ND ND ND ND
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September 2023 31404568.018
MW-5 MW-6 MW-7 MW-8 MW-9 MW-10S
Summary of Historical Groundwater Monitoring Results
TABLE 4
Closed Randolph County Landfill, Permit No. 76-01
SWS Reporting Limit
Detected Monitoring
Constituent/Parameter Units Date BlanksDetection Limit
Downgradient WellsUpgradient WellQuanitation Limit
Vinyl chloride ug/L 09/22/94 ----10 ND ND ND ND ND --NDNC 2L = 0.03 ug/L ug/L 11/08/94 ----10 ND ND ND ND ND --NDEPA MCL = 2 ug/L ug/L 01/18/95 ----10 ND ND ND ND ND --NDug/L 04/23/96 ----10 ND ND ND ND ND --NDug/L 06/17/97 ----10 ND ND ND ND ND --NDug/L 10/16/97 ----10 ND ND ND ND ND --NDug/L 04/21/98 ----10 ND ND ND ND ND --NDug/L 04/07/99 ----10 ND ND ND ND ND --ND
ug/L 10/13/99 ----10 ND ND ND ND ND --NDug/L 04/05/00 ----10 ND ND ND ND ND --NDug/L 10/25/00 ----10 ND ND ND ND ND --NDug/L 04/04/01 ----10 ND ND ND ND ND --NDug/L 04/04/02 ----10 ND ND ND ND ND --NDug/L 10/21/02 ----10 ND ND ND ND ND --NDug/L 04/14/03 ----10 ND ND ND ND ND --NDug/L 10/01/03 ----10 ND ND ND ND ND --NDug/L 04/05/04 ----10 ND ND ND ND ND --NDug/L 10/18/04 ----10 ND ND ND ND ND --NDug/L 04/07/05 ----10 ND ND ND ND ND --NDug/L 10/06/05 ----10 ND ND ND ND ND --ND
ug/L 04/03/06 ----10 ND ND ND ND ND --NDug/L 10/03/06 ----10 ND ND ND ND ND --NDug/L 04/05/07 ----10 ND ND ND ND ND --NDug/L 10/18/07 ----1 ND ND --ND ND --NDug/L 04/29/08 ----1 ND ND 0.41 J ND 0.54 J --NDug/L 10/23/08 ----1 ND ND 0.93 J ND ND --NDug/L 04/07/09 ----1 ND ND 0.46 J ND 0.71 J --NDug/L 10/19/09 ----1 ND ND 1.2 ND ND --NDug/L 04/28/10 ----1 ND ND 0.63 J ND 0.64 J --NDug/L 10/12/10 ----1 ND ND 1.0 ND ND --NDug/L 04/11/11 ----1 ND ND 0.70 J ND ND --NDug/L 10/04/11 ----1 ND ND 1.1 ND ND ND NDug/L 04/10/12 ----1 ND ND 0.51 J ND 0.34 J --ND
ug/L 10/15/12 ----1 ND ND 1.0 ND ND --NDug/L 04/09/13 ----1 ND ND 0.75 J ND ND --NDug/L 10/08/13 ----1 ND ND 0.74 J ND ND --NDug/L 04/08/14 ----1 ND ND 0.51 J ND ND --NDug/L 10/08/14 0.32 --1 ND ND 0.52 J ND ND --NDug/L 04/08/15 0.32 --1 ND ND ND ND ND --NDug/L 10/28/15 0.32 --1 ND ND 0.48 J ND ND 1.3 NDug/L 04/05/16 0.32 --1 ND ND ND ND ND ND NDug/L 10/04/16 0.32 --1 ND ND ND ND ND ND NDug/L 04/03/17 0.32 --1 ND ND ND ND ND 0.70 J NDug/L 10/03/17 0.32 --1 ND ND ND ND ND 1.2 NDug/L 05/22/18 0.32 --1 ND ND ND ND ND ND NDug/L 10/23/18 0.32 1 --ND ND ND ND ND 1.0 ND
ug/L 04/16/19 0.32 1 --ND ND ND ND ND 0.65 J NDug/L 10/15/19 0.32 1 --ND ND ND ND ND 1.3 NDug/L 04/14/20 0.32 1 --ND ND ND ND ND ND NDug/L 10/07/20 0.32 1 --ND ND ND ND ND 0.93 J NDug/L 05/10/21 0.32 1 --ND ND ND ND ND ND NDug/L 10/06/21 0.32 1 --ND ND ND ND ND 0.98 J NDug/L 05/17/22 0.32 1 --ND ND ND ND ND 0.47 J NDug/L 10/10/22 0.40 1 --DRY ND ND ND ND 0.86 J NDug/L 05/22/23 0.32 1 --DRY ND ND ND ND 0.665 J NDXylenes (Total)ug/L 09/22/94 ----5 ND ND ND ND ND --NDNC 2L = 500 ug/L ug/L 11/08/94 ----5 ND ND ND ND ND --NDEPA MCL = 10,000 ug/L ug/L 01/18/95 ----5 ND ND ND ND ND --ND
ug/L 04/23/96 ----5 ND ND ND ND ND --NDug/L 06/17/97 ----5 ND ND ND ND ND --NDug/L 10/16/97 ----5 ND ND ND ND ND --NDug/L 04/21/98 ----5 ND ND ND ND ND --NDug/L 04/07/99 ----5 ND ND ND ND ND --NDug/L 10/13/99 ----5 ND ND ND ND ND --NDug/L 04/05/00 ----5 ND ND ND ND ND --NDug/L 10/25/00 ----5 ND ND ND ND ND --NDug/L 04/04/01 ----5 ND ND ND ND ND --NDug/L 04/04/02 ----5 ND ND ND ND ND --NDug/L 10/21/02 ----5 ND ND ND ND ND --NDug/L 04/14/03 ----5 ND ND ND ND ND --ND
ug/L 10/01/03 ----5 ND ND ND ND ND --NDug/L 04/05/04 ----5 ND ND ND ND ND --NDug/L 10/18/04 ----5 ND ND ND ND ND --NDug/L 04/07/05 ----5 ND ND ND ND ND --NDug/L 10/06/05 ----5 ND ND ND ND ND --NDug/L 04/03/06 ----5 ND ND ND ND ND --NDug/L 10/03/06 ----5 ND ND ND ND ND --NDug/L 04/05/07 ----4 ND ND ND ND ND --NDug/L 10/18/07 ----5 ND ND --ND ND --NDug/L 04/29/08 ----5 ND ND ND ND ND --NDug/L 10/23/08 ----5 ND ND 1.2 J ND ND --NDug/L 04/07/09 ----5 ND ND ND ND ND --NDug/L 10/19/09 ----5 ND ND 1.2 J ND ND --ND
ug/L 04/28/10 ----5 ND ND 0.54 J ND ND --NDug/L 10/12/10 ----5 ND ND 1.0 J ND ND --NDug/L 04/11/11 ----5 ND ND ND ND ND --NDug/L 10/04/11 ----5 ND ND ND ND ND ND NDug/L 04/10/12 ----5 ND ND ND ND ND --NDug/L 10/15/12 ----5 ND ND 0.64 J ND ND --NDug/L 04/09/13 ----5 ND ND 0.57 J ND ND --NDug/L 10/08/13 ----5 ND ND ND ND ND --NDug/L 04/08/14 ----5 ND ND ND ND ND --NDug/L 10/08/14 0.45 --5 ND ND ND ND ND --NDug/L 04/08/15 0.45 --5 ND ND ND ND ND --NDug/L 10/28/15 0.45 --5 ND ND ND ND ND ND ND
ug/L 04/05/16 0.45 --5 ND ND ND ND ND ND NDug/L 10/04/16 0.45 --5 ND ND ND ND ND ND NDug/L 04/03/17 0.45 --5 ND ND ND ND ND ND NDug/L 10/03/17 0.45 --5 ND ND ND ND ND ND NDug/L 05/22/18 0.45 --5 ND ND ND ND ND ND NDug/L 10/23/18 0.45 3 --ND ND ND ND ND ND ND
ug/L 04/16/19 0.45 3 --ND ND ND ND ND ND NDug/L 10/15/19 0.45 3 --ND ND ND ND ND ND NDug/L 04/14/20 0.45 3 --ND ND ND ND ND ND NDug/L 10/07/20 0.45 3 --ND ND ND ND ND ND NDug/L 05/10/21 0.45 3 --ND ND ND ND ND ND NDug/L 10/06/21 0.45 3 --ND ND ND ND ND ND NDug/L 05/17/22 0.45 3 --ND ND ND ND ND ND ND
ug/L 10/10/22 0.23 1 --DRY ND ND ND ND ND NDug/L 05/22/23 0.45 3 --DRY ND ND ND ND ND ND
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September 2023 31404568.018
MW-5 MW-6 MW-7 MW-8 MW-9 MW-10S
Summary of Historical Groundwater Monitoring Results
TABLE 4
Closed Randolph County Landfill, Permit No. 76-01
SWS Reporting Limit
Detected Monitoring
Constituent/Parameter Units Date BlanksDetection Limit
Downgradient WellsUpgradient WellQuanitation Limit
1,4-Dioxane ug/L 10/23/18 1.2 2 --ND ND 2.3 ND 5.6 38 NDNC 2L = 3 ug/L ug/L 02/28/19 1.2 2 ----------ND 18 NDug/L 04/16/19 1.2 2 --ND 2.0 ND ND ND 16 NDug/L 10/15/19 1.2 2 --ND 21 2.5 1.4 J ND 25 NDug/L 04/14/20 0.8 2 --ND 6.2 1.2 J 0.93 J 0.84 J 12 NDug/L 10/07/20 0.8 2 --ND 12 1.9 J 0.99 J 1.1 J 23 NDug/L 05/10/21 0.8 2 ND 15 0.93 J ND 0.94 J 13 NDug/L 10/06/21 0.8 2 --ND 14 2.1 1.4 J 1.1 J 21 ND
ug/L 05/17/22 0.8 2 --ND 11 1.2 J 1.0 J 1.2 J 11 NDug/L 10/10/22 0.27 1.4 --DRY 11 5.7 2.1 1.9 42 NDug/L 05/22/23 0.32 0.5 --DRY 9.11 1.47 0.565 0.888 24.4 ND
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Notes:ug/L =micrograms per litermg/L = milligrams per literND =Not detected at the stated reporting limit for data before October 2007 and not detected at the laboratory detection limit for data from October 2007 forwardNM =Not measured
J =B =Blank-qualified resultR =unusable data-- =no data available# =EPA Action Level* =EPA Secondary MCLBlanks =field, trip and method blanksBold Only = Concentration above current NC 2L Groundwater Standard or NC SWS Groundwater Protection StandardShaded and Bold = Concentration above current NC 2L Groundwater Standard or NC SWS Groundwater Protection Standard and EPA MCLGWPS =Solid Waste Section Groundwater Protection StandardNC 2L = North Carolina 2L Groundwater StandardIMAC =Interim Maximum Allowable Concentration (under NC 2L Rules)EPA MCL =US Environmental Protection Agency Maximum Contaminant Level
SWS Reporting Limit = NCPQL or lab-specific reporting limit prior to October 2007 and NCSWSL starting in October 20071)Historical data prior to April 2008 provided by the County as taken from historical reports from Hazen and Sawyer and Environment 1.2)For the October 2017 event, selenium was detected in the sample from MW-6 by method 6010D; however, it was non-detect when analyzed by method 6020B.3)For the April 2019 event, diethylphthalate, a common laboratory contaminant, was re-analyzed outside of hold time for MW-7. Both results are included.4)During the April 2020 event, chromium and cobalt in the sample from MW-7 were re-analyzed. Re-analysis results are in parentheses.5)The dilutions during the May 2023 Event are as follows: antimony and thallium (2x): all points.
Prior to the October 2018 event, J flags are estimated values below the SWS Reporting limit. Beginning with the October 2018 event, J flags are estimated values between MDL and PQL.
September 2023 31404568.018
MW-5 MW-6 MW-7 MW-8 MW-9 MW-10S
Detected Monitoring Constituent/Parameter Units Date Downgradient WellsWell
1 of 3
September 2023 31404568.018
MW-5 MW-6 MW-7 MW-8 MW-9 MW-10S
Detected Monitoring Constituent/Parameter Units Date Downgradient WellsWell
Temperature (field)Celsius 11/08/94 ----15 15 13 --Celsius 01/18/95 ----14 10 13 --Celsius 04/23/96 17 16 15 13 16 --Celsius 06/17/97 19 15 17 15 17 --Celsius 10/16/97 16 15 15 15 14 --Celsius 04/21/98 15 12 14 14 15 --Celsius 04/07/99 18 14 16 14 15 --Celsius 10/13/99 16 16 16 16 16 --Celsius 04/05/00 15 12 13 13 14 --Celsius 10/25/00 16 16 16 16 15 --Celsius 04/04/01 14 12 13 13 15 --Celsius 04/08/02 16 13 11 16 16 --Celsius 10/21/02 17 17 16 16 16 --Celsius 04/14/03 18 12 15 14 17 --Celsius 10/01/03 16 16 16 15 15 --
Celsius 04/05/04 15 12 13 12 13 --
Celsius 10/18/04 17 16 15 15 15 --
Celsius 04/07/05 18 14 16 15 16 --
Celsius 10/06/05 18 18 18 17 17 --Celsius 04/03/06 17 15 16 15 16 --Celsius 10/03/06 18 18 17 16 16 --Celsius 04/05/07 17 13 15 13 15 --Celsius 10/18/07 18 17 --16 16 --Celsius 04/29/08 16.5 14.0 15.5 15.8 16.2 --Celsius 10/23/08 15.1 16.4 16.6 17.3 16.8 --Celsius 04/07/09 14.6 12.3 14.4 12.7 14.1 --Celsius 10/19/09 17.9 17.9 17.0 16.3 16.2 --Celsius 04/28/10 16.8 15.4 16.1 15.2 17.2 --Celsius 10/12/10 18.6 19.7 18.4 18.6 16.3 --Celsius 04/11/11 16.6 12.8 16.4 14.7 15.4 15.4Celsius10/04/11 18.6 18.0 17.4 17.1 16.7 --Celsius 04/10/12 16.4 14.6 15.4 13.5 15.4 --Celsius 10/15/12 17.5 17.2 16.5 16.5 15.7 --Celsius 04/09/13 18.1 14.4 15.9 14.8 15.8 --Celsius 10/07/13 17.3 17.3 16.5 15.9 15.5 --Celsius 04/08/14 17.9 11.9 14.9 13.2 14.8 --Celsius 10/08/14 17.8 17.3 17.2 16.0 15.6 --Celsius 04/08/15 16.0 13.4 16.2 14.3 14.8 --Celsius 10/28/15 18.5 16.2 17.3 16.9 15.0 17.1Celsius04/05/16 14.9 11.7 16.2 13.4 15.7 12.7
Celsius 10/04/16 17.3 17.9 17.3 18.3 15.7 17.0
Celsius 04/03/17 15.6 14.9 16.3 14.0 15.4 15.9
Celsius 10/03/17 19.81 17.9 18.1 17.5 17.7 16.8
Celsius 05/22/18 20.3 17.9 17.4 15.9 16.4 15.4Celsius10/23/18 14.6 15.8 16.5 16.8 13.1 15.5Celsius04/16/19 16.3 14.6 17.6 14.3 15.1 14.0Celsius10/15/19 17.5 17.3 17.2 17.7 15.5 17.4Celsius04/14/20 16.2 13.5 16.0 14.1 15.6 14.6Celsius10/07/20 17.2 19.2 18.5 17.9 16.2 16.3Celsius05/10/21 17.8 13.7 16.5 14.3 14.6 14.8Celsius08/19/21 ----17.6 ------Celsius 10/06/21 18.4 18.2 17.6 17.6 16.5 16.8Celsius05/17/22 19.9 15.8 18.2 14.5 14.9 15.8Verification Event Celsius 08/22/22 ----19.1 ------Celsius 10/10/22 Dry 15.8 17.1 16.4 16.4 16.2Verification Event Celsius 11/22/22 ----16.6 16.2 --16.0Celsius05/22/23 --17.0 15.8 15.1 15.1 15.2Turbidity (field)NTU 04/29/08 66.5 97.8 3.38 6.15 2.37 --NTU 10/23/08 3.03 23.6 1.66 26.6 1.44 --NTU 04/07/09 8.52 46.0 9.24 7.55 1.56 --NTU 10/19/09 16.7 32.6 5.53 13.1 7.89 --NTU 04/28/10 2.57 24.6 11 13.3 2.36 --NTU 10/12/10 5.45 45.3 2.05 39.4 0.00 --NTU 04/11/11 4.39 25.3 16.7 34.7 2.43 5.35NTU10/04/11 4.24 8.83 1.64 8.52 0.86 --
NTU 04/10/12 8.27 18.3 15.7 10.0 9.24 --
NTU 10/15/12 32.2 7.46 45.9 37.9 1.60 --
NTU 04/09/13 21.1 56.0 34.3 15.3 1.71 --
NTU 10/07/13 8.46 9.21 22.8 12.4 1.14 --NTU 04/08/14 10.2 60.8 19.3 19.5 2.97 --NTU 10/08/14 7.13 14.0 3.62 16.2 2.27 --NTU 04/08/15 1.45 11.1 7.27 7.22 4.02 --NTU 10/28/15 3.98 5.61 1.29 14.0 3.40 1.33NTU04/05/16 17.9 18.4 17.3 4.97 2.64 1.23NTU10/04/16 3.10 24.3 1.24 1.05 0.60 1.41NTU04/03/17 1.14 8.76 2.59 1.46 1.02 1.80NTU10/03/17 2.19 3.61 2.60 4.42 0.87 6.05NTU05/22/18 2.70 19.7 9.00 1.69 0.80 2.20NTU10/23/18 3.43 2.22 0.80 2.93 0.85 0.93NTU04/16/19 0.83 24.0 8.19 3.44 0.63 0.80NTU10/15/19 1.35 18.5 0.40 3.60 0.23 0.74NTU04/14/20 0.61 1.00 2.24 3.31 1.63 1.25NTU10/07/20 4.24 9.08 0.01 5.36 0.86 2.37NTU05/10/21 0.48 1.62 0.73 8.76 0.22 0.51NTU08/19/21 ----0.59 ------NTU 10/06/21 7.79 9.08 1.44 4.33 0.88 3.52NTU05/17/22 9.79 8.68 6.44 2.47 1.78 0.77Verification Event NTU 08/22/22 ----0.95 ------NTU 10/10/22 Dry 9.91 1.82 2.95 1.34 0.64Verification Event NTU 11/10/22 ----0.85 3.21 --1.71
NTU 05/22/23 --23.8 0.20 9.02 1.93 0.20
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September 2023 31404568.018
MW-5 MW-6 MW-7 MW-8 MW-9 MW-10S
Detected Monitoring Constituent/Parameter Units Date Downgradient WellsWell
Dissolved Oxygen (field)mg/L 04/29/08 --5.20 1.12 4.15 1.27 --mg/L 10/23/08 --0.00 0.00 3.41 0.00 --mg/L 04/07/09 5.39 4.77 1.11 5.73 1.16 --mg/L 10/19/09 3.48 1.92 1.19 3.67 2.33 --mg/L 04/28/10 4.30 2.20 0.86 3.97 1.13 --mg/L 10/12/10 4.88 2.97 0.44 2.85 0.53 --mg/L 04/11/11 2.69 4.95 1.10 4.24 1.52 1.67mg/L 10/04/11 4.18 2.60 0.73 2.97 0.68 --mg/L 04/10/12 --3.87 --3.54 0.88 --mg/L 10/15/12 --0.69 --2.61 1.44 --mg/L 04/09/13 --4.81 --3.70 1.98 --mg/L 10/07/13 --0.82 --2.97 0.60 --mg/L 04/08/14 --7.47 --3.71 0.68 --mg/L 10/08/14 2.61 0.63 0.98 3.14 0.83 --mg/L 04/08/15 1.81 2.88 0.73 3.12 1.06 --
mg/L 10/28/15 2.16 2.10 0.71 3.60 1.88 1.55
mg/L 04/05/16 3.43 3.45 0.85 3.39 1.14 2.24
mg/L 10/04/16 3.55 3.24 0.99 3.81 2.06 1.48
mg/L 04/03/17 5.94 2.19 0.82 5.60 1.80 2.53mg/L 10/03/17 3.98 1.05 0.78 4.80 1.02 0.52mg/L 05/22/18 4.71 2.93 0.39 1.78 1.30 0.87mg/L 10/23/18 --2.71 0.42 2.45 1.98 0.42mg/L 04/16/19 1.54 2.50 0.32 2.41 1.03 0.63mg/L 10/05/19 1.44 5.53 0.40 3.60 1.08 0.31mg/L 04/14/20 4.88 1.99 0.82 2.31 0.73 1.47mg/L 10/07/20 2.53 0.45 0.26 2.34 2.49 1.27mg/L 05/10/21 2.67 0.89 0.26 0.86 0.58 1.10mg/L 08/19/21 ----0.18 ------mg/L 10/06/21 3.60 0.50 0.81 1.36 2.80 1.15mg/L 05/17/22 4.29 1.12 0.99 1.69 1.69 4.10Verification Event mg/L 08/22/22 ----0.36 ------mg/L 10/10/22 Dry 2.13 1.39 3.50 0.59 0.24Verification Event mg/L 11/10/22 ----1.49 2.47 --1.15mg/L 05/22/23 --1.91 0.37 1.75 1.41 0.82Oxidation Reduction Potential (field)mV 04/29/08 --103 175 83.4 104 --mV 10/23/08 --157 167 87 79 --mV 04/07/09 205 200 225 147 176 --mV 10/19/09 161 167 162 126 137 --mV 04/28/10 97.8 111 134 115 75.2 --mV 10/12/10 170 136 164 308 114 --
mV 04/11/11 150 220 238 167 182 158
mV 10/04/11 -118 -51.3 19.8 -70.8 -107 --
mV 04/10/12 --117 --130 128 --
mV 10/15/12 --39.7 --63.2 43.9 --mV 04/09/13 --98.8 --52.8 47.8 --mV 10/07/13 --208 --163 135 --mV 04/08/14 --249 --202 149 --mV 10/08/14 152 202 161 184 74.1 --mV 04/08/15 31.7 95.8 70.6 26.9 30.7 --mV 10/28/15 11.0 142 137 178 138 115mV04/05/16 204 287 188 193 119 193mV10/04/16 220 199 196 90.0 155 247mV04/03/17 211 189 125 202 227 139mV10/03/17 110 101 126 118 79 117mV05/22/18 172 213 142 230 197 144mV10/23/18 --48.5 138 133 135 139mV04/16/19 147 363 123 348 71 96mV10/15/19 277 247 144 358 238 113mV04/14/20 96 234 57.2 183 177 304mV10/07/20 10.9 26.8 120 -24.3 25.4 189mV05/10/21 225 150 58.7 243 75.1 147mV08/19/21 ----135 ------mV 10/06/21 152 86.3 172 176 307 130mV05/17/22 179 25.6 174 123 139 45Verification Event mV 08/22/22 ----173 ------
mV 10/10/22 Dry 109 123 125 178 127
Verification Event mV 11/10/22 ----55 54 --55
mV 05/22/23 ---166.6 -318 -29 218.8 -341
Notes:mg/L = milligrams per literNTU =Nephelometric Turbidity UnitsmV =millivoltsS.U. =Standard Units-- =no data available
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September 2023 31404568.018
SW-1 SW-3 SW-2 SW-4
Antimony ug/L 09/22/94 ----30 ND ND ND ND ND
No SW Standard ug/L 11/08/94 ----30 ND ND ND ND ND
ug/L 01/18/95 ----30 ND ND ND ND ND
ug/L 04/23/96 ----30 ND ND ND ND ND
ug/L 06/17/97 ----30 ND ND ND ND ND
ug/L 10/16/97 ----30 ND ND ND ND ND
ug/L 04/21/98 ----30 ND ND ND ND ND
ug/L 04/07/99 ----30 ND ND ND ND ND
ug/L 10/13/99 ----30 ND ND ND ND ND
ug/L 04/05/00 ----30 ND ND ND ND ND
ug/L 10/25/00 ----30 ND ND ND ND ND
ug/L 04/04/01 ----30 ND ND ND ND ND
ug/L 04/08/02 ----30 ND ND ND ND ND
ug/L 10/21/02 ----30 ND ND ND ND ND
ug/L 04/14/03 ----30 ND ND ND ND ND
ug/L 10/01/03 ----30 ND ND ND ND ND
ug/L 04/05/04 ----30 ND ND ND ND ND
ug/L 10/18/04 ----30 ND ND ND ND ND
ug/L 04/07/05 ----30 ND ND ND ND ND
ug/L 10/06/05 ----30 ND ND ND ND ND
ug/L 04/03/06 ----30 ND ND ND ND ND
ug/L 10/03/06 ----30 ND ND ND ND ND
ug/L 04/05/07 ----6 ND ND ND ND ND
ug/L 10/18/07 ----6 --3.5 J --3.6 J 0.1 J
ug/L 04/29/08 ----6 ND 1.61 J ND ND ND
ug/L 10/23/08 ----6 Dry 1.25 J ND 1.96 J ND
ug/L 04/07/09 ----6 ND ND ND ND ND
ug/L 10/19/09 ----6 Dry 1.52 J Dry 2.36 J 0.102 J
ug/L 04/29/10 ----6 ND 1.09 J ND 0.905 J ND
ug/L 10/13/10 ----6 ND 1.45 J ND 1.17 J ND
ug/L 04/11/11 ----6 ND 0.532 J ND 0.418 J ND
ug/L 10/03/11 ----6 ND ND 0.561 J 0.835 J ND
ug/L 04/10/12 ----6 ND ND 0.900 J 0.533 J ND
ug/L 10/15/12 ----6 0.220 J 1.26 J 1.60 J ND ND
ug/L 04/09/13 ----6 ND ND ND ND ND
ug/L 10/08/13 ----6 ND 0.572 J 1.18 J 1.57 J ND
ug/L 04/08/14 ----6 ND ND ND ND ND
ug/L 10/08/14 0.22 --6 2.28 J dry 1.83 J 2.37 J ND
ug/L 04/08/15 0.22 --6 ND 0.914 J ND 0.641 J ND
ug/L 10/28/15 0.22 --6 ND 1.24 J ND 2.29 J ND
ug/L 04/05/16 0.22 --6 ND 1.40 J ND 0.786 J ND
ug/L 10/04/16 0.22 --6 ND 2.07 J ND 1.24 B 0.388 J
ug/L 04/03/17 0.37 --6 ND 0.775 J ND 0.981 J ND
ug/L 10/03/17 0.37 --6 ND 2.97 J Dry 2.10 J ND
ug/L 05/22/18 0.37 --6 ND ND ND ND ND
ug/L 10/23/18 1.85 5 --ND ND ND ND ND
ug/L 04/16/19 0.37 1 --ND ND ND ND ND
ug/L 10/16/19 0.74 2 --Dry 2.52 Dry 2.35 ND
ug/L 04/14/20 0.74 2 --ND ND ND ND ND
ug/L 10/07/20 0.74 2 --ND 0.781 J ND ND ND
ug/L 05/10/21 0.74 2 ND ND ND ND ND
ug/L 10/06/21 0.74 2 --Dry ND 1.09 J 0.975 J ND
ug/L 05/18/22 0.74 2 --ND 0.763 J ND ND ND
ug/L 10/10/22 0.52 5.0 --DRY 0.92 J DRY 0.59 J ND
ug/L 05/22/23 0.34 5 --ND ND ND ND ND
Arsenic ug/L 09/22/94 ----10 ND ND ND ND ND
Human Health SW Standard = 10 ug/L ug/L 11/08/94 ----10 ND ND ND ND ND
ug/L 01/18/95 ----10 ND ND ND ND ND
ug/L 04/23/96 ----10 ND ND ND ND ND
ug/L 06/17/97 ----10 ND ND ND ND ND
ug/L 10/16/97 ----10 ND ND ND ND ND
ug/L 04/21/98 ----10 ND ND ND ND ND
ug/L 04/07/99 ----10 ND ND ND ND ND
ug/L 10/13/99 ----10 ND ND ND ND ND
ug/L 04/05/00 ----10 ND ND ND ND ND
ug/L 10/25/00 ----10 ND ND ND ND ND
ug/L 04/04/01 ----10 ND ND ND ND ND
ug/L 04/08/02 ----10 ND ND ND ND ND
ug/L 10/21/02 ----10 ND ND ND ND ND
ug/L 04/14/03 ----10 ND ND ND ND ND
ug/L 10/01/03 ----10 ND ND ND ND ND
ug/L 04/05/04 ----10 ND ND ND ND ND
ug/L 10/18/04 ----10 ND ND ND ND ND
ug/L 04/07/05 ----10 ND ND ND ND ND
ug/L 10/06/05 ----10 ND ND ND ND ND
ug/L 04/03/06 ----10 ND ND ND ND ND
ug/L 10/03/06 ----10 ND ND ND ND ND
ug/L 04/05/07 ----10 ND ND ND ND ND
ug/L 10/18/07 ----10 --1.3 J --0.9 J ND
ug/L 04/29/08 ----6 ND ND ND ND ND
ug/L 10/23/08 ----10 Dry ND ND ND ND
ug/L 04/07/09 ----10 ND ND ND ND ND
ug/L 10/19/09 ----10 Dry 6.16 J Dry ND ND
ug/L 04/29/10 ----10 3.18 J ND ND 3.39 J ND
ug/L 10/13/10 ----10 ND ND 4.15 J ND ND
ug/L 04/11/11 ----10 3.69 J 3.83 J ND ND ND
ug/L 10/03/11 ----10 ND 4.44 J ND ND ND
ug/L 04/10/12 ----10 ND ND ND ND 3.79 J
ug/L 10/15/12 ----10 ND ND ND ND ND
ug/L 04/09/13 ----10 ND ND ND ND ND
ug/L 10/08/13 ----10 ND ND ND ND ND
ug/L 04/08/14 ----10 ND ND ND ND ND
ug/L 10/08/14 5.4 --10 ND dry ND ND ND
ug/L 04/08/15 5.4 --10 ND ND ND ND ND
ug/L 10/28/15 5.4 --10 ND ND ND ND ND
ug/L 04/05/16 6.8 --10 ND ND ND ND ND
ug/L 10/04/16 6.8 --10 ND ND ND ND ND
ug/L 04/03/17 6.8 --10 ND ND ND ND ND
ug/L 10/03/17 6.8 --10 ND ND Dry ND ND
ug/L 05/22/18 6.8 --10 7.34 J ND ND ND ND
ug/L 10/23/18 7.6 10 --ND ND ND ND ND
ug/L 04/16/19 7.6 10 --ND ND ND ND ND
ug/L 10/16/19 7.6 10 --Dry ND Dry ND ND
ug/L 04/14/20 7.6 10 --ND ND ND ND ND
ug/L 10/07/20 7.6 10 --ND ND ND ND ND
ug/L 05/10/21 7.6 10 --ND ND ND ND ND
ug/L 10/06/21 7.6 10 --Dry ND ND ND ND
ug/L 05/18/22 7.6 10 --ND ND ND ND ND
ug/L 10/10/22 6.4 20 --DRY ND DRY ND ND
Closed Randolph County Landfill, Permit No. 76-01
Summary of Historical Surface Water Monitoring Results
TABLE 6
Downstream BlanksDetected Monitoring Constituent/Parameter Units Date SWS Reporting
LimitDetection Quantitation
1 of 12
September 2023 31404568.018
SW-1 SW-3 SW-2 SW-4 BlanksDetected Monitoring Constituent/Parameter Units Date SWS Reporting
LimitDetection Quantitation
Barium ug/L 09/22/94 ----500 ND ND ND ND ND
Human Health SW Standard = 200000 ug/L ug/L 11/08/94 ----500 ND ND ND ND ND
ug/L 01/18/95 ----500 ND ND ND ND ND
ug/L 04/23/96 ----500 ND ND ND ND ND
ug/L 06/17/97 ----500 ND ND ND ND ND
ug/L 10/16/97 ----500 ND ND ND ND ND
ug/L 04/21/98 ----500 ND ND ND ND ND
ug/L 04/07/99 ----500 ND ND ND ND ND
ug/L 10/13/99 ----500 ND ND ND ND ND
ug/L 04/05/00 ----500 ND ND ND ND ND
ug/L 10/25/00 ----500 ND ND ND ND ND
ug/L 04/04/01 ----500 ND ND ND ND ND
ug/L 04/08/02 ----500 ND ND ND ND ND
ug/L 10/21/02 ----500 ND ND ND ND ND
ug/L 04/14/03 ----500 ND ND ND ND ND
ug/L 10/01/03 ----500 ND ND ND ND ND
ug/L 04/05/04 ----500 ND ND ND ND ND
ug/L 10/18/04 ----500 ND ND ND ND ND
ug/L 04/07/05 ----500 ND ND ND ND ND
ug/L 10/06/05 ----500 ND ND ND ND ND
ug/L 04/03/06 ----500 ND ND ND ND ND
ug/L 10/03/06 ----500 ND ND ND ND ND
ug/L 04/05/07 ----100 ND ND ND ND ND
ug/L 10/18/07 ----100 --17.7 J --23.2 J 0.04 J
ug/L 04/29/08 ----100 65.6 J 33.4 J 64.5 J 27.5 J 0.2 J
ug/L 10/23/08 ----100 Dry 32.2 J 37.1 J 35.8 J ND
ug/L 04/07/09 ----100 23.5 J 24.9 J 41.4 J 27.2 J ND
ug/L 10/19/09 ----100 Dry 28.5 J Dry 26.6 J ND
ug/L 04/29/10 ----100 29.1 J 32.4 J 57.1 J 23.3 J ND
ug/L 10/13/10 ----100 98.8 J 20.1 J 58.3 J 34.7 J ND
ug/L 04/11/11 ----100 30.5 J 25.0 J 30.3 J 25.5 J ND
ug/L 10/03/11 ----100 21.8 J 47.0 J 24.6 J 22.7 J ND
ug/L 04/10/12 ----100 24.6 J 29.2 J 27.5 J 26.3 J ND
ug/L 10/15/12 ----100 25.4 J 21.1 J 28.7 J 21.5 J 1.04 J
ug/L 04/09/13 ----100 22.7 J 23.9 J 30.1 J 21.9 J ND
ug/L 10/08/13 ----100 27.3 J 37.8 J 22.0 J 21.7 J ND
ug/L 04/08/14 ----100 35.0 J 24.0 J 47.3 J 24.2 J 1.09
ug/L 10/08/14 1.0 --100 23.2 J dry 22.6 J 24.1 J 3.14 J
ug/L 04/08/15 1.0 --100 22.9 J 24.0 J 30.9 J 26.4 J ND
ug/L 10/28/15 1.0 --100 28.3 J 23.5 J 28.7 J 33.6 J 1.20 J
ug/L 04/05/16 1.0 --100 18.0 J 24.9 J 27.3 J 23.5 J ND
ug/L 10/04/16 1.0 --100 43.3 J 46.3 J 37.4 J 26.4 J ND
ug/L 04/03/17 1.0 --100 18.2 J 22.2 J 28.7 J 22.5 J ND
ug/L 10/03/17 1.0 --100 25.7 J 20.9 J Dry 20.0 J 2.77 J
ug/L 05/22/18 1.0 --100 28.9 J 24.1 J 29.0 J 25.0 J ND
ug/L 10/23/18 1.1 10 --22.2 20.4 27.4 20.1 ND
ug/L 04/16/19 1.1 10 --25.8 22.8 31.2 22.2 ND
ug/L 10/16/19 1.1 10 --Dry 19.8 Dry 20.9 ND
ug/L 04/14/20 1.1 10 --33.0 22.6 30.4 21.0 ND
ug/L 10/07/20 1.1 10 --30.2 21.4 39.4 16.6 ND
ug/L 05/10/21 1.1 10 --22.0 17.8 26.1 18.5 ND
ug/L 10/06/21 1.1 10 --Dry 42.4 19.6 16.6 ND
ug/L 05/18/22 1.1 10 --35.3 46.0 36.5 25.0 ND
ug/L 10/10/22 4.4 10 --DRY 69 DRY 28 ND
ug/L 05/22/23 4.4 10 --45.5 32.8 20.8 19.1 ND
Beryllium ug/L 09/22/94 ----2 ND ND ND ND ND
Freshwater Acute SW Standard = 65 ug/L ug/L 11/08/94 ----2 ND ND ND ND ND
Freshwater Chronic SW Standard = 6.5 ug/L ug/L 01/18/95 ----2 ND ND ND ND ND
ug/L 04/23/96 ----2 ND ND ND ND ND
ug/L 06/17/97 ----2 ND ND ND ND ND
ug/L 10/16/97 ----2 ND ND ND ND ND
ug/L 04/21/98 ----2 ND 21 ND ND ND
ug/L 04/07/99 ----2 ND ND ND ND ND
ug/L 10/13/99 ----2 ND ND ND ND ND
ug/L 04/05/00 ----2 ND ND ND ND ND
ug/L 10/25/00 ----2 ND ND ND ND ND
ug/L 04/04/01 ----2 ND ND ND ND ND
ug/L 04/08/02 ----2 ND ND ND ND ND
ug/L 10/21/02 ----2 ND ND ND ND ND
ug/L 04/14/03 ----2 ND ND ND ND ND
ug/L 10/01/03 ----2 ND ND ND ND ND
ug/L 04/05/04 ----2 ND ND ND ND ND
ug/L 10/18/04 ----2 ND ND ND ND ND
ug/L 04/07/05 ----2 ND ND ND ND ND
ug/L 10/06/05 ----2 ND ND ND ND ND
ug/L 04/03/06 ----2 ND ND ND ND ND
ug/L 10/03/06 ----2 ND ND ND ND ND
ug/L 04/05/07 ----1 ND ND ND ND ND
ug/L 10/18/07 ----1 ND ND ND ND ND
ug/L 04/29/08 ----1 ND ND ND ND ND
ug/L 10/23/08 ----1 Dry ND ND ND ND
ug/L 04/07/09 ----1 ND ND ND ND ND
ug/L 10/19/09 ----1 Dry 0.104 B Dry 0.127 B 0.174 J
ug/L 04/29/10 ----1 ND ND ND ND ND
ug/L 10/13/10 ----1 ND ND ND ND ND
ug/L 04/11/11 ----1 ND ND ND ND ND
ug/L 10/03/11 ----1 ND ND ND ND ND
ug/L 04/10/12 ----1 ND ND ND ND ND
ug/L 10/15/12 ----1 ND ND ND ND ND
ug/L 04/09/13 ----1 ND ND ND ND ND
ug/L 10/08/13 ----1 ND ND ND ND ND
ug/L 04/08/14 ----1 ND ND ND ND ND
ug/L 10/08/14 0.10 --1 ND dry ND ND ND
ug/L 04/08/15 0.10 --1 ND ND ND ND ND
ug/L 10/28/15 0.10 --1 ND ND ND ND ND
ug/L 04/05/16 0.10 --1 ND ND ND ND ND
ug/L 10/04/16 0.10 --1 ND ND ND ND ND
ug/L 04/03/17 0.10 --1 ND ND ND ND ND
ug/L 10/03/17 0.13 --1 ND ND Dry ND 0.233 J
ug/L 05/22/18 0.13 --1 ND ND ND ND ND
ug/L 10/23/18 0.16 1 --ND ND ND ND ND
ug/L 04/16/19 0.16 1 --ND ND ND ND ND
ug/L 10/16/19 0.16 1 --Dry ND Dry ND ND
ug/L 04/14/20 0.16 1 --ND ND ND ND ND
ug/L 10/07/20 0.16 1 --ND ND ND ND 0.207
ug/L 05/10/21 0.16 1 --ND ND ND ND ND
ug/L 10/06/21 0.16 1 --Dry ND ND ND ND
ug/L 05/18/22 0.16 1 --ND ND ND ND ND
ug/L 10/10/22 0.30 4.0 --DRY 0.63 J DRY ND ND
2 of 12
September 2023 31404568.018
SW-1 SW-3 SW-2 SW-4 BlanksDetected Monitoring Constituent/Parameter Units Date SWS Reporting
LimitDetection Quantitation
Cadmium ug/L 09/22/94 ----1 ND ND ND ND ND
Freshwater Acute SW Standard = ug/L 11/08/94 ----1 ND ND ND ND ND
SW-1 - 1.93 ug/L ug/L 01/18/95 ----1 ND ND ND ND ND
SW-2 - 2.18 ug/L ug/L 04/23/96 ----1 ND ND ND ND ND
SW-3 - 2.03 ug/L ug/L 06/17/97 ----1 2 2 --ND ND
SW-4 - 2.48 ug/L ug/L 10/16/97 ----1 ND ND ND ND ND
Freshwater Chronic SW Standard =ug/L 04/21/98 ----1 1 ND ND ND ND
SW-1 - 0.31 ug/L ug/L 04/07/99 ----1 ND ND ND ND ND
SW-2 - 0.35 ug/L ug/L 10/13/99 ----1 ND ND ND ND ND
SW-3 - 0.33 ug/L ug/L 04/05/00 ----1 ND ND ND ND ND
SW-4 - 0.39 ug/L ug/L 10/25/00 ----1 ND ND ND ND ND
ug/L 04/04/01 ----1 ND ND ND ND ND
ug/L 04/08/02 ----1 ND ND ND ND ND
ug/L 10/21/02 ----1 4 ND ND ND ND
ug/L 04/14/03 ----1 2 ND ND ND ND
ug/L 10/01/03 ----1 ND ND 2 ND ND
ug/L 04/05/04 ----1 1 ND ND ND ND
ug/L 10/18/04 ----1 ND ND ND ND ND
ug/L 04/07/05 ----1 ND ND ND ND ND
ug/L 10/06/05 ----1 ND ND ND ND ND
ug/L 04/03/06 ----1 ND ND ND ND ND
ug/L 10/03/06 ----1 ND ND ND ND ND
ug/L 04/05/07 ----1 ND ND ND ND ND
ug/L 10/18/07 ----1 --0.2 J --0.7 J ND
ug/L 04/29/08 ----1 ND ND ND ND ND
ug/L 10/23/08 ----1 Dry ND ND ND ND
ug/L 04/07/09 ----1 0.10 J ND 0.13 J 0.12 J ND
ug/L 10/19/09 ----1 Dry ND Dry ND ND
ug/L 04/29/10 ----1 ND ND ND ND ND
ug/L 10/13/10 ----1 ND ND ND ND ND
ug/L 04/11/11 ----1 ND ND ND ND ND
ug/L 10/03/11 ----1 ND ND 0.625 J ND ND
ug/L 04/10/12 ----1 ND ND ND ND ND
ug/L 10/15/12 ----1 ND ND ND ND 0.433 J
ug/L 04/09/13 ----1 ND ND ND ND ND
ug/L 10/08/13 ----1 ND ND ND ND ND
ug/L 04/08/14 ----1 ND ND ND ND ND
ug/L 10/08/14 0.36 --1 ND dry ND 0.889 J ND
ug/L 04/08/15 0.36 --1 ND 0.838 B ND 2.36 0.427 J
ug/L 10/28/15 0.36 --1 ND ND ND ND ND
ug/L 04/05/16 0.36 --1 ND ND ND ND ND
ug/L 10/04/16 0.36 --1 ND ND ND ND ND
ug/L 04/03/17 0.36 --1 ND ND ND ND ND
ug/L 10/03/17 0.36 --1 ND ND Dry ND ND
ug/L 05/22/18 0.36 --1 ND ND ND ND ND
ug/L 10/23/18 0.36 1 --ND ND ND ND ND
ug/L 04/16/19 0.36 1 --ND ND ND ND ND
ug/L 10/16/19 0.36 1 --Dry ND Dry ND ND
ug/L 04/14/20 0.36 1 --ND ND ND ND ND
ug/L 10/07/20 0.36 1 --ND ND ND ND ND
ug/L 05/10/21 0.36 1 --ND ND ND ND ND
ug/L 10/06/21 0.36 1 --Dry ND ND ND ND
ug/L 05/18/22 0.36 1 --ND ND ND ND ND
ug/L 10/10/22 0.44 5.0 --DRY ND DRY ND ND
ug/L 05/22/23 0.44 5 --ND ND ND ND ND
Chromium ug/L 09/22/94 ----10 ND ND ND ND ND
Freshwater Acute SW Standard =ug/L 11/08/94 ----10 ND ND ND ND ND
SW-1 - 410 ug/L ug/L 01/18/95 ----10 ND ND ND ND ND
SW-2 - 460 ug/L ug/L 04/23/96 ----10 ND ND ND ND ND
SW-3 - 430 ug/L ug/L 06/17/97 ----10 ND ND ND ND ND
SW-4 - 518 ug/L ug/L 10/16/97 ----10 ND ND ND ND ND
Freshwater Chronic SW Standard = ug/L 04/21/98 ----10 20 ND ND 15 ND
SW-1 - 53.4 ug/L ug/L 04/07/99 ----10 ND ND ND ND ND
SW-2 - 59.8 ug/L ug/L 10/13/99 ----10 ND ND ND ND ND
SW-3 - 56.0 ug/L ug/L 04/05/00 ----10 ND ND ND ND ND
SW-4 - 67.4 ug/L ug/L 10/25/00 ----10 22 ND ----ND
ug/L 04/04/01 ----10 ND ND ND ND ND
ug/L 04/08/02 ----10 ND ND ND ND ND
ug/L 10/21/02 ----10 ND ND ND ND ND
ug/L 04/14/03 ----10 ND ND ND ND ND
ug/L 10/01/03 ----10 ND ND 121 ND ND
ug/L 04/05/04 ----10 ND ND ND ND ND
ug/L 10/18/04 ----10 ND ND ND ND ND
ug/L 04/07/05 ----10 ND ND ND ND ND
ug/L 10/06/05 ----10 ND ND ND ND ND
ug/L 04/03/06 ----10 ND ND ND ND ND
ug/L 10/03/06 ----10 ND ND ND ND ND
ug/L 04/05/07 ----10 ND ND ND ND ND
ug/L 10/18/07 ----10 --5.6 J --2.3 J ND
ug/L 04/29/08 ----10 2.7 J ND 4.6 J ND ND
ug/L 10/23/08 ----10 Dry ND ND ND ND
ug/L 04/07/09 ----10 ND ND ND ND ND
ug/L 10/19/09 ----10 Dry 1.64 J Dry 1.58 J ND
ug/L 04/29/10 ----10 1.21 J 1.36 J ND ND ND
ug/L 10/13/10 ----10 6.61 J 4.10 J ND 2.58 J ND
ug/L 04/11/11 ----10 5.92 J 2.02 J 4.49 J 1.90 J ND
ug/L 10/03/11 ----10 ND ND ND ND ND
ug/L 04/10/12 ----10 1.13 J ND 1.42 J ND ND
ug/L 10/15/12 ----10 ND ND ND ND ND
ug/L 04/09/13 ----10 ND 1.86 J ND ND ND
ug/L 10/08/13 ----10 ND ND ND ND ND
ug/L 04/08/14 ----10 2.79 J ND ND ND ND
ug/L 10/08/14 1.4 --10 ND dry 2.55 J 2.38 J ND
ug/L 04/08/15 1.4 --10 ND ND ND ND ND
ug/L 10/28/15 1.4 --10 ND ND ND ND ND
ug/L 04/05/16 1.4 --10 ND ND ND ND ND
ug/L 10/04/16 1.4 --10 ND 1.42 J ND 1.77 J ND
ug/L 04/03/17 1.1 --10 ND ND ND ND 4.45 J
ug/L 10/03/17 1.4 --10 ND ND Dry ND ND
ug/L 05/22/18 1.4 --10 2.03 J ND ND ND ND
ug/L 10/23/18 1.4 10 --ND 1.55 J ND 1.46 J ND
ug/L 04/16/19 1.4 10 --ND ND ND ND ND
ug/L 10/16/19 1.4 10 --Dry ND Dry ND ND
ug/L 04/14/20 1.4 10 --ND ND ND ND ND
ug/L 10/07/20 1.4 10 --1.56 J ND ND ND ND
ug/L 05/10/21 1.4 10 --ND ND ND ND ND
ug/L 10/06/21 1.4 10 --Dry ND ND ND ND
ug/L 05/18/22 1.4 10 --ND ND ND ND ND
ug/L 10/10/22 1.1 10 --DRY 28 DRY ND ND
3 of 12
September 2023 31404568.018
SW-1 SW-3 SW-2 SW-4 BlanksDetected Monitoring Constituent/Parameter Units Date SWS Reporting
LimitDetection Quantitation
Cobalt ug/L 09/22/94 ----10 ND ND 37 ND ND
No SW Standard ug/L 11/08/94 ----10 ND --37 --ND
ug/L 01/18/95 ----10 ND ND ND ND ND
ug/L 04/23/96 ----10 ND ND ND ND ND
ug/L 06/17/97 ----10 ND ND ND ND ND
ug/L 10/16/97 ----10 ND ND 17 ND ND
ug/L 04/21/98 ----10 ND ND ND 13 ND
ug/L 04/07/99 ----10 ND ND ND ND ND
ug/L 10/13/99 ----10 ND ND ND ND ND
ug/L 04/05/00 ----10 ND ND ND ND ND
ug/L 10/25/00 ----10 29 ND ----ND
ug/L 04/04/01 ----10 ND ND ND ND ND
ug/L 04/08/02 ----10 ND ND ND ND ND
ug/L 10/21/02 ----10 ND ND ND ND ND
ug/L 04/14/03 ----10 ND ND ND ND ND
ug/L 10/01/03 ----10 ND ND 112 ND ND
ug/L 04/05/04 ----10 ND ND ND ND ND
ug/L 10/18/04 ----10 ND ND 12 ND ND
ug/L 04/07/05 ----10 ND ND ND ND ND
ug/L 10/06/05 ----10 ND ND ND ND ND
ug/L 04/03/06 ----10 ND ND ND ND ND
ug/L 10/03/06 ----10 ND ND ND ND ND
ug/L 04/05/07 ----10 ND ND ND ND ND
ug/L 10/18/07 ----10 --1.5 J --1.0 J ND
ug/L 04/29/08 ----10 5.8 J ND 5.2 J ND ND
ug/L 10/23/08 ----10 Dry ND 2.6 J ND ND
ug/L 04/07/09 ----10 ND ND 1.7 J 0.9 J ND
ug/L 10/19/09 ----10 Dry ND Dry ND ND
ug/L 04/29/10 ----10 2.59 J 1.35 J 2.10 J ND ND
ug/L 10/13/10 ----10 12.9 ND 10.8 1.86 J ND
ug/L 04/11/11 ----10 2.58 J ND ND ND ND
ug/L 10/03/11 ----10 ND 1.13 J 1.11 J ND ND
ug/L 04/10/12 ----10 1.70 J ND ND ND ND
ug/L 10/15/12 ----10 ND 1.34 J ND 1.17 J ND
ug/L 04/09/13 ----10 1.26 J ND ND ND ND
ug/L 10/08/13 ----10 ND ND ND ND ND
ug/L 04/08/14 ----10 2.73 J ND 1.70 J ND ND
ug/L 10/08/14 1.1 --10 ND dry ND ND ND
ug/L 04/08/15 1.1 --10 ND ND ND ND ND
ug/L 10/28/15 1.1 --10 1.90 J 1.11 J ND 1.43 J ND
ug/L 04/05/16 1.1 --10 ND ND 1.22 J ND ND
ug/L 10/04/16 1.1 --10 3.74 J 1.21 J 1.11 J ND ND
ug/L 04/03/17 1.1 --10 ND 1.13 J ND ND ND
ug/L 10/03/17 1.1 --10 ND ND Dry ND ND
ug/L 05/22/18 1.1 --10 ND 1.11 J ND ND ND
ug/L 10/23/18 1.4 10 --ND ND ND ND ND
ug/L 04/16/19 1.4 10 --ND ND 2.17 J ND ND
ug/L 10/16/19 1.4 10 --Dry ND Dry ND ND
ug/L 04/14/20 1.4 10 --2.06 J ND ND ND ND
ug/L 10/07/20 1.4 10 --ND 1.88 J 1.92 J ND ND
ug/L 05/10/21 1.4 10 --ND ND ND ND ND
ug/L 10/06/21 1.4 10 --Dry ND ND ND ND
ug/L 05/18/22 1.4 10 --ND ND ND ND ND
ug/L 10/10/22 1.4 10 --DRY 8.5 J DRY ND ND
ug/L 05/22/23 1.4 10 --3.88 J ND ND ND ND
Copper ug/L 09/22/94 ----200 ND ND ND ND ND
Freshwater Acute SW Standard =ug/L 11/08/94 ----200 ND ND ND ND ND
SW-1 - 9.22 ug/L ug/L 01/18/95 ----200 ND ND ND ND ND
SW-2 - 10.5 ug/L ug/L 04/23/96 ----200 ND ND ND ND ND
SW-3 - 9.73 ug/L ug/L 06/17/97 ----200 ND ND ND ND ND
SW-4 - 12.0 ug/L ug/L 10/16/97 ----200 ND ND ND ND ND
Freshwater Chronic SW Standard = ug/L 04/21/98 ----200 ND ND ND ND ND
SW-1 - 6.36 ug/L ug/L 04/07/99 ----200 ND ND ND ND ND
SW-2 - 7.16 ug/L ug/L 10/13/99 ----200 ND ND ND ND ND
SW-3 - 6.68 ug/L ug/L 04/05/00 ----200 ND ND ND ND ND
SW-4 - 8.11 ug/L ug/L 10/25/00 ----200 ND ND ND ND ND
ug/L 04/04/01 ----200 ND ND ND ND ND
ug/L 04/08/02 ----200 ND ND ND ND ND
ug/L 10/21/02 ----200 ND ND ND ND ND
ug/L 04/14/03 ----200 ND ND ND ND ND
ug/L 10/01/03 ----200 ND ND ND ND ND
ug/L 04/05/04 ----200 ND ND ND ND ND
ug/L 10/18/04 ----200 ND ND ND ND ND
ug/L 04/07/05 ----200 ND ND ND ND ND
ug/L 10/06/05 ----200 ND ND ND ND ND
ug/L 04/03/06 ----200 ND ND ND ND ND
ug/L 10/03/06 ----200 ND ND ND ND ND
ug/L 04/05/07 ----10 ND ND ND ND ND
ug/L 10/18/07 ----10 5.4 J ND 3.7 J ND 0.7 J
ug/L 04/29/08 ----10 6.0 J 5.2 J 9.1 J 0.9 B 0.9 J
ug/L 10/23/08 ----10 Dry ND 2.1 J ND ND
ug/L 04/07/09 ----10 ND 1.31 J ND 1.74 J ND
ug/L 10/19/09 ----10 Dry ND Dry ND 1.60 J
ug/L 04/29/10 ----10 ND 2.90 J ND 1.97 J ND
ug/L 10/13/10 ----10 12.7 3.32 B 4.34 B 4.68 B 1.60 J
ug/L 04/11/11 ----10 3.54 J 3.47 J 3.56 J 4.27 J ND
ug/L 10/03/11 ----10 ND 4.85 J 3.35 J ND ND
ug/L 04/10/12 ----10 ND ND 3.22 J 2.10 J ND
ug/L 10/15/12 ----10 ND ND ND ND ND
ug/L 04/09/13 ----10 1.72 J 3.49 J ND 1.72 J ND
ug/L 10/08/13 ----10 ND ND ND 1.80 J ND
ug/L 04/08/14 ----10 3.04 J 2.38 J ND 2.35 J ND
ug/L 10/08/14 1.6 --10 2.90 J dry 2.51 J 5.56 J ND
ug/L 04/08/15 1.6 --10 ND 6.03 B ND 8.15 B 3.01 J
ug/L 10/28/15 1.6 --10 ND ND ND 1.68 J ND
ug/L 04/05/16 1.6 --10 ND 3.52 B ND 2.87 B 3.64 J
ug/L 10/04/16 1.6 --10 3.54 B 5.42 B 3.00 B 6.03 B 5.15 J
ug/L 04/03/17 0.87 --10 ND 4.76 B ND 5.01 B 3.21 J
ug/L 10/03/17 1.6 --10 1.82 B 3.78 B Dry 4.14 B 4.84 J
ug/L 05/22/18 1.6 --10 1.80 J 2.57 J ND 3.26 J ND
ug/L 10/23/18 1.6 10 --2.16 B 5.99 B 6.38 B 4.87 B 1.97 J
ug/L 04/16/19 1.6 10 --ND 3.36 J 1.73 J 2.40 J ND
ug/L 10/16/19 1.6 10 --Dry 2.96 J Dry 2.51 J ND
ug/L 04/14/20 1.6 10 --2.13 J 2.71 J 3.02 J 2.20 J ND
ug/L 10/07/20 1.6 10 --ND 3.96 J ND 4.22 J ND
ug/L 05/10/21 1.6 10 --ND ND ND ND ND
ug/L 10/06/21 1.6 10 --Dry ND ND 1.73 J ND
ug/L 05/18/22 1.6 10 --13.4 15.6 13.3 15.6 ND
ug/L 10/10/22 3.2 20 --DRY 73 DRY ND ND
4 of 12
September 2023 31404568.018
SW-1 SW-3 SW-2 SW-4 BlanksDetected Monitoring Constituent/Parameter Units Date SWS Reporting
LimitDetection Quantitation
Lead ug/L 09/22/94 ----10 ND ND ND ND ND
Freshwater Acute SW Standard =ug/L 11/08/94 ----10 ND ND ND ND ND
SW-1 - 41.7 ug/L ug/L 01/18/95 ----10 ND ND ND ND ND
SW-2 - 48.5 ug/L ug/L 04/23/96 ----10 ND ND ND ND ND
SW-3 - 44.4 ug/L ug/L 06/17/97 ----10 ND 15 --11 ND
SW-4 - 56.9 ug/L ug/L 10/16/97 ----10 ND ND ND ND ND
Freshwater Chronic SW Standard = ug/L 04/21/98 ----10 ND ND ND 16 ND
SW-1 - 1.62 ug/L ug/L 04/07/99 ----10 ND ND ND ND ND
SW-2 - 1.89 ug/L ug/L 10/13/99 ----10 ND ND ND ND ND
SW-3 - 1.73 ug/L ug/L 04/05/00 ----10 ND ND ND ND ND
SW-4 - 2.22 ug/L ug/L 10/25/00 ----10 ND ND ND ND ND
ug/L 04/04/01 ----10 ND ND 12 ND ND
ug/L 04/08/02 ----10 ND ND ND ND ND
ug/L 10/21/02 ----10 ND ND ND ND ND
ug/L 04/14/03 ----10 ND ND ND ND ND
ug/L 10/01/03 ----10 ND ND 41 ND ND
ug/L 04/05/04 ----10 ND ND ND ND ND
ug/L 10/18/04 ----10 ND ND ND ND ND
ug/L 04/07/05 ----10 ND ND ND ND ND
ug/L 10/06/05 ----10 ND ND ND ND ND
ug/L 04/03/06 ----10 ND ND ND ND ND
ug/L 10/03/06 ----10 ND ND ND ND ND
ug/L 04/05/07 ----10 ND ND ND ND ND
ug/L 10/18/07 ----10 --0.6 J --0.6 J ND
ug/L 04/29/08 ----10 2.6 J 3.8 J ND ND ND
ug/L 10/23/08 ----10 Dry ND ND ND ND
ug/L 04/07/09 ----10 ND ND ND ND ND
ug/L 10/19/09 ----10 Dry ND Dry ND ND
ug/L 04/29/10 ----10 ND ND ND ND ND
ug/L 10/13/10 ----10 2.51 J ND 2.87 J ND ND
ug/L 04/11/11 ----10 ND ND ND ND ND
ug/L 10/03/11 ----10 ND 2.26 J 2.16 J ND ND
ug/L 04/10/12 ----10 2.55 B 2.03 B 2.19 B 2.39 B 2.22 J
ug/L 10/15/12 ----10 ND ND ND ND ND
ug/L 04/09/13 ----10 ND ND ND ND ND
ug/L 10/08/13 ----10 ND ND ND ND ND
ug/L 04/08/14 ----10 ND ND ND 2.15 J ND
ug/L 10/08/14 2.1 --10 ND dry ND ND ND
ug/L 04/08/15 2.1 --10 ND ND ND ND ND
ug/L 10/28/15 2.1 --10 ND ND ND ND ND
ug/L 04/05/16 3.1 --10 ND ND ND ND ND
ug/L 10/04/16 3.1 --10 ND ND ND ND ND
ug/L 04/03/17 3.1 --10 ND ND ND ND ND
ug/L 10/03/17 3.1 --10 ND ND Dry ND ND
ug/L 05/22/18 3.1 --10 ND ND ND ND ND
ug/L 10/23/18 3.1 10 --ND ND ND ND ND
ug/L 04/16/19 3.1 10 --ND ND 3.4 (ND)J ND ND
ug/L 10/16/19 3.1 10 --Dry ND Dry ND ND
ug/L 04/14/20 3.1 10 --ND ND ND ND 3.83 J
ug/L 10/07/20 3.1 10 --ND ND ND ND ND
ug/L 05/10/21 3.1 10 --ND ND ND ND ND
ug/L 10/06/21 3.1 10 --Dry ND ND ND ND
ug/L 05/18/22 3.1 10 --ND ND ND ND ND
ug/L 10/10/22 6.6 10 --DRY 10 DRY ND ND
ug/L 05/22/23 6.6 10 --ND ND ND ND ND
Nickel ug/L 09/22/94 ----50 ND ND ND ND ND
Freshwater Acute SW Standard =ug/L 11/08/94 ----50 ND ND ND ND ND
SW-1 - 334 ug/L ug/L 01/18/95 ----50 ND ND ND ND ND
SW-2 - 375 ug/L ug/L 04/23/96 ----50 ND ND ND ND ND
SW-3 - 350 ug/L ug/L 06/17/97 ----50 ND ND ND ND ND
SW-4 - 424 ug/L ug/L 10/16/97 ----50 ND ND ND ND ND
Freshwater Chronic SW Standard = ug/L 04/21/98 ----50 ND ND ND ND ND
SW-1 - 37.1 ug/L ug/L 04/07/99 ----50 ND ND ND ND ND
SW-2 - 41.7 ug/L ug/L 10/13/99 ----50 ND ND ND ND ND
SW-3 - 38.9 ug/L ug/L 04/05/00 ----50 ND ND ND ND ND
SW-4 - 47.1 ug/L ug/L 10/25/00 ----50 ND ND ND ND ND
ug/L 04/04/01 ----50 ND ND ND ND ND
ug/L 04/08/02 ----50 ND ND ND ND ND
ug/L 10/21/02 ----50 ND ND ND ND ND
ug/L 04/14/03 ----50 ND ND ND ND ND
ug/L 10/01/03 ----50 ND ND 68 ND ND
ug/L 04/05/04 ----50 ND ND ND ND ND
ug/L 10/18/04 ----50 ND ND ND ND ND
ug/L 04/07/05 ----50 ND ND ND ND ND
ug/L 10/06/05 ----50 ND ND ND ND ND
ug/L 04/03/06 ----50 ND ND ND ND ND
ug/L 10/03/06 ----50 ND ND ND ND ND
ug/L 04/05/07 ----50 ND ND ND ND ND
ug/L 10/18/07 ----50 --2.7 J --1.9 J ND
ug/L 04/29/08 ----50 3.2 J ND 2.5 J ND ND
ug/L 10/23/08 ----50 Dry ND ND ND ND
ug/L 04/07/09 ----50 ND 1.0 J ND 1.0 J ND
ug/L 10/19/09 ----50 Dry ND Dry ND ND
ug/L 04/29/10 ----50 ND 7.03 J ND ND ND
ug/L 10/13/10 ----50 4.05 J ND ND ND ND
ug/L 04/11/11 ----50 17.1 B 4.55 B 17.5 B 4.86 B 3.53 J
ug/L 10/03/11 ----50 ND ND ND ND ND
ug/L 04/10/12 ----50 ND ND ND ND ND
ug/L 10/15/12 ----50 ND ND ND ND ND
ug/L 04/09/13 ----50 ND ND ND ND ND
ug/L 10/08/13 ----50 ND ND ND ND ND
ug/L 04/08/14 ----50 ND ND 2.07 J ND ND
ug/L 10/08/14 1.8 --50 ND dry ND ND ND
ug/L 04/08/15 1.8 --50 ND ND ND ND ND
ug/L 10/28/15 1.8 --50 ND ND ND ND ND
ug/L 04/05/16 2.2 --50 ND ND ND ND ND
ug/L 10/04/16 2.2 --50 ND ND ND ND ND
ug/L 04/03/17 2.2 --50 ND ND ND ND ND
ug/L 10/03/17 2.2 --50 ND ND Dry ND 2.66 J
ug/L 05/22/18 2.2 --50 ND ND ND ND ND
ug/L 10/23/18 2.2 10 --ND ND ND ND ND
ug/L 04/16/19 2.2 10 --ND ND ND 3.64 J ND
ug/L 10/16/19 2.2 10 --Dry ND Dry ND ND
ug/L 04/14/20 2.2 10 --ND ND ND ND ND
ug/L 10/07/20 2.2 10 --ND ND ND ND ND
ug/L 05/10/21 2.2 10 --ND ND ND ND ND
ug/L 10/06/21 2.2 10 --Dry ND ND ND ND
ug/L 05/18/22 2.2 10 --ND 5.47 J ND ND ND
ug/L 10/10/22 3.3 40 --DRY 17 J DRY ND ND
5 of 12
September 2023 31404568.018
SW-1 SW-3 SW-2 SW-4 BlanksDetected Monitoring Constituent/Parameter Units Date SWS Reporting
LimitDetection Quantitation
Selenium ug/L 09/22/94 ----20 ND ND ND ND ND
Freshwater Acute SW Standard = 5 ug/L ug/L 11/08/94 ----20 ND ND ND ND ND
Freshwater Chronic SW Standard = 5 ug/L ug/L 01/18/95 ----20 ND ND ND ND ND
ug/L 04/23/96 ----20 ND ND ND ND ND
ug/L 06/17/97 ----20 ND ND ND ND ND
ug/L 10/16/97 ----20 ND ND ND ND ND
ug/L 04/21/98 ----20 ND ND ND ND ND
ug/L 04/07/99 ----20 ND ND ND ND ND
ug/L 10/13/99 ----20 ND ND ND ND ND
ug/L 04/05/00 ----20 ND ND ND ND ND
ug/L 10/25/00 ----20 ND ND ND ND ND
ug/L 04/04/01 ----20 ND ND ND ND ND
ug/L 04/08/02 ----20 ND ND ND ND ND
ug/L 10/21/02 ----20 ND ND ND ND ND
ug/L 04/14/03 ----20 ND ND ND ND ND
ug/L 10/01/03 ----20 ND ND ND ND ND
ug/L 04/05/04 ----20 ND ND ND ND ND
ug/L 10/18/04 ----20 ND ND ND ND ND
ug/L 04/07/05 ----20 ND ND ND ND ND
ug/L 10/06/05 ----20 ND ND ND ND ND
ug/L 04/03/06 ----20 ND ND ND ND ND
ug/L 10/03/06 ----20 ND ND ND ND ND
ug/L 04/05/07 ----10 ND ND ND ND ND
ug/L 10/18/07 ----10 --0.6 J ----ND
ug/L 04/29/08 ----10 ND ND ND 2.7 B 3.9 J
ug/L 10/23/08 ----10 Dry ND ND ND ND
ug/L 04/07/09 ----10 ND ND ND ND 3.7 J
ug/L 10/19/09 ----10 Dry ND Dry ND ND
ug/L 04/29/10 ----10 ND ND ND ND ND
ug/L 10/13/10 ----10 0.929 J ND ND ND ND
ug/L 04/11/11 ----10 ND ND ND ND 2.85 J
ug/L 10/03/11 ----10 ND ND ND ND ND
ug/L 04/10/12 ----10 ND ND ND ND ND
ug/L 10/15/12 ----10 ND ND ND ND ND
ug/L 04/09/13 ----10 ND ND ND ND ND
ug/L 10/08/13 ----10 ND ND ND ND ND
ug/L 04/08/14 ----10 ND ND ND ND ND
ug/L 10/08/14 5.0 --10 ND dry ND ND ND
ug/L 04/08/15 5.0 --10 ND ND ND ND ND
ug/L 10/28/15 5.0 --10 ND ND ND ND ND
ug/L 04/05/16 6.2 --10 ND ND ND ND ND
ug/L 10/04/16 6.2 --10 ND ND ND ND ND
ug/L 04/03/17 6.2 --10 ND ND ND ND ND
ug/L 10/03/17 6.2 --10 ND ND Dry ND ND
ug/L 05/22/18 6.2 --10 ND ND ND ND ND
ug/L 10/23/18 6.2 10 --ND ND ND ND ND
ug/L 04/16/19 6.2 10 --ND ND ND ND ND
ug/L 10/16/19 6.2 10 --Dry ND Dry ND ND
ug/L 04/14/20 6.2 10 --ND ND ND ND ND
ug/L 10/07/20 6.2 10 --ND ND ND ND ND
ug/L 05/10/21 6.2 10 --ND ND ND ND ND
ug/L 10/06/21 6.2 10 --Dry ND ND ND ND
ug/L 05/18/22 6.2 10 --ND ND ND ND ND
ug/L 10/10/22 10 20 --DRY ND DRY ND ND
ug/L 05/22/23 10 20 --ND ND ND ND ND
Silver ug/L 09/22/94 ----10 ND ND ND ND ND
Freshwater Acute SW Standard =ug/L 11/08/94 ----10 ND ND ND ND ND
SW-1 - 1.62 ug/L ug/L 01/18/95 ----10 ND ND ND ND ND
SW-2 - 2.05 ug/L ug/L 04/23/96 ----10 ND ND ND ND ND
SW-3 - 1.78 ug/L ug/L 06/17/97 ----10 ND ND ND ND ND
SW-4 - 2.63 ug/L ug/L 10/16/97 ----10 ND ND ND ND ND
Freshwater Chronic SW Standard = 0.06 ug/L ug/L 04/21/98 ----10 ND ND ND ND ND
ug/L 04/07/99 ----10 ND ND ND ND ND
ug/L 10/13/99 ----10 ND ND ND ND ND
ug/L 04/05/00 ----10 ND ND ND ND ND
ug/L 10/25/00 ----10 ND ND ND ND ND
ug/L 04/04/01 ----10 ND ND ND ND ND
ug/L 04/08/02 ----10 ND ND ND ND ND
ug/L 10/21/02 ----10 ND ND ND ND ND
ug/L 04/14/03 ----10 ND ND ND ND ND
ug/L 10/01/03 ----10 ND ND ND ND ND
ug/L 04/05/04 ----10 ND ND ND ND ND
ug/L 10/18/04 ----10 ND ND ND ND ND
ug/L 04/07/05 ----10 ND ND ND ND ND
ug/L 10/06/05 ----10 ND ND ND ND ND
ug/L 04/03/06 ----10 ND ND ND ND ND
ug/L 10/03/06 ----10 ND ND ND ND ND
ug/L 04/05/07 ----10 ND ND ND ND ND
ug/L 10/18/07 ----10 --ND --ND ND
ug/L 04/29/08 ----10 ND ND ND ND ND
ug/L 10/23/08 ----10 Dry ND ND ND ND
ug/L 04/07/09 ----10 1.6 B 1.7 B 1.7 B 1.2 B 1.4 J
ug/L 10/19/09 ----10 Dry ND Dry ND ND
ug/L 04/29/10 ----10 ND ND ND ND ND
ug/L 10/13/10 ----10 ND ND ND ND ND
ug/L 04/11/11 ----10 ND ND ND ND ND
ug/L 10/03/11 ----10 ND ND ND ND ND
ug/L 04/10/12 ----10 ND ND ND ND ND
ug/L 10/15/12 ----10 ND ND ND ND ND
ug/L 04/09/13 ----10 2.04 B 1.98 B 1.94 B ND 2.16 J
ug/L 10/08/13 ----10 ND ND ND ND ND
ug/L 04/08/14 ----10 ND ND 2.86 B ND 3.31 J
ug/L 10/08/14 1.9 --10 ND dry ND ND 2.42 J
ug/L 04/08/15 1.9 --10 ND ND ND ND ND
ug/L 10/28/15 1.9 --10 ND ND ND ND ND
ug/L 04/05/16 1.9 --10 ND ND ND ND ND
ug/L 10/04/16 1.9 --10 ND ND ND ND ND
ug/L 04/03/17 1.9 --10 ND 2.30 J ND 2.60 J ND
ug/L 10/03/17 1.9 --10 ND ND Dry ND ND
ug/L 05/22/18 1.9 --10 ND ND ND ND ND
ug/L 10/23/18 1.9 10 --ND ND ND ND ND
ug/L 04/16/19 1.9 10 --ND ND ND ND ND
ug/L 10/16/19 1.9 10 --Dry ND Dry ND ND
ug/L 04/14/20 1.9 10 --ND ND ND ND ND
ug/L 10/07/20 1.9 10 --ND ND ND ND ND
ug/L 05/10/21 1.9 10 --ND ND ND ND ND
ug/L 10/06/21 1.9 10 --Dry ND ND ND ND
ug/L 05/18/22 1.9 10 --ND ND ND ND ND
ug/L 10/10/22 1.5 10 --DRY 5.4 J DRY ND ND
6 of 12
September 2023 31404568.018
SW-1 SW-3 SW-2 SW-4 BlanksDetected Monitoring Constituent/Parameter Units Date SWS Reporting
LimitDetection Quantitation
Thallium ug/L 09/22/94 ----10 ND ND ND ND ND
No SW Standard ug/L 11/08/94 ----10 ND ND ND ND ND
ug/L 01/18/95 ----10 ND ND ND ND ND
ug/L 04/23/96 ----10 ND ND ND ND ND
ug/L 06/17/97 ----10 ND ND ND ND ND
ug/L 10/16/97 ----10 ND ND ND ND ND
ug/L 04/21/98 ----10 ND ND ND ND ND
ug/L 04/07/99 ----10 ND ND ND ND ND
ug/L 10/13/99 ----10 ND ND ND ND ND
ug/L 04/05/00 ----100 ND ND ND ND ND
ug/L 10/25/00 ----10 ND ND ND ND ND
ug/L 04/04/01 ----10 ND ND ND ND ND
ug/L 04/08/02 ----10 ND ND ND ND ND
ug/L 10/21/02 ----10 ND ND ND ND ND
ug/L 04/14/03 ----10 ND ND ND ND ND
ug/L 10/01/03 ----10 ND ND ND ND ND
ug/L 04/05/04 ----10 ND ND ND ND ND
ug/L 10/18/04 ----10 ND ND ND ND ND
ug/L 04/07/05 ----10 ND ND ND ND ND
ug/L 10/06/05 ----10 ND ND ND ND ND
ug/L 04/03/06 ----10 ND ND ND ND ND
ug/L 10/03/06 ----10 ND ND ND ND ND
ug/L 04/05/07 ----5.5 ND ND ND ND ND
ug/L 10/18/07 ----5.5 ND ND ND ND ND
ug/L 04/29/08 ----5.5 0.037 J ND ND ND ND
ug/L 10/23/08 ----5.5 Dry ND ND ND ND
ug/L 04/07/09 ----5.5 0.039 B 0.045 B 0.039 B 0.050 B 0.052 J
ug/L 10/19/09 ----5.5 Dry ND Dry ND ND
ug/L 04/29/10 ----5.5 ND ND ND ND ND
ug/L 10/13/10 ----5.5 ND ND ND ND ND
ug/L 04/11/11 ----5.5 ND ND ND ND ND
ug/L 10/03/11 ----5.5 ND ND ND ND ND
ug/L 04/10/12 ----5.5 ND ND ND ND ND
ug/L 10/15/12 ----5.5 ND ND ND ND ND
ug/L 04/09/13 ----5.5 ND ND ND ND ND
ug/L 10/08/13 ----5.5 ND ND ND ND ND
ug/L 04/08/14 ----5.5 ND ND ND ND ND
ug/L 10/08/14 0.11 --5.5 ND dry ND ND ND
ug/L 04/08/15 0.11 --5.5 ND ND ND ND ND
ug/L 10/28/15 0.11 --5.5 ND ND ND ND ND
ug/L 04/05/16 0.11 --5.5 ND ND ND ND ND
ug/L 10/04/16 0.11 --5.5 ND ND ND ND ND
ug/L 04/03/17 0.11 --5.5 0.156 J 0.229 J 0.216 J 0.201 J ND
ug/L 10/03/17 0.11 --5.5 0.710 J 0.617 J Dry 0.536 J ND
ug/L 05/22/18 0.11 --5.5 ND ND ND ND ND
ug/L 10/23/18 0.55 5 --ND ND ND ND ND
ug/L 04/16/19 0.11 1 --ND ND ND ND ND
ug/L 10/16/19 0.22 2 --Dry ND Dry ND ND
ug/L 04/14/20 0.22 2 --ND ND ND ND ND
ug/L 10/07/20 0.22 2 --ND ND ND ND ND
ug/L 05/10/21 0.22 2 --ND ND ND ND ND
ug/L 10/06/21 0.22 2 --Dry ND ND ND ND
ug/L 05/18/22 0.22 2 --ND ND ND ND ND
ug/L 10/10/22 0.26 1.0 --DRY ND DRY ND ND
ug/L 05/22/23 0.26 1 --ND ND ND ND ND
Vanadium ug/L 09/22/94 ----40 ND ND ND ND ND
No SW Standard ug/L 11/08/94 ----40 ND ND ND ND ND
ug/L 01/18/95 ----40 ND ND ND ND ND
ug/L 04/23/96 ----40 ND ND ND ND ND
ug/L 06/17/97 ----40 ND ND ND ND ND
ug/L 10/16/97 ----40 ND ND ND ND ND
ug/L 04/21/98 ----40 ND ND ND ND ND
ug/L 04/07/99 ----40 ND ND ND ND ND
ug/L 10/13/99 ----40 ND ND ND ND ND
ug/L 04/05/00 ----40 ND ND ND ND ND
ug/L 10/25/00 ----40 57 ND ND ND ND
ug/L 04/04/01 ----40 ND ND ND ND ND
ug/L 04/08/02 ----40 ND ND ND ND ND
ug/L 10/21/02 ----40 ND ND ND ND ND
ug/L 04/14/03 ----40 ND ND ND ND ND
ug/L 10/01/03 ----40 ND ND 351 ND ND
ug/L 04/05/04 ----40 ND ND ND ND ND
ug/L 10/18/04 ----40 ND ND ND ND ND
ug/L 04/07/05 ----40 ND ND ND ND ND
ug/L 10/06/05 ----40 ND ND ND ND ND
ug/L 04/03/06 ----40 ND ND ND ND ND
ug/L 10/03/06 ----40 ND ND ND ND ND
ug/L 04/05/07 ----40 ND ND ND ND ND
ug/L 10/18/07 ----25 --1.8 J --2.3 J ND
ug/L 04/29/08 ----25 7.9 J 3.8 J 20 J ND ND
ug/L 10/23/08 ----25 Dry ND ND ND ND
ug/L 04/07/09 ----25 1.3 J 1.2 J ND 1.4 J ND
ug/L 10/19/09 ----25 Dry 1.86 J Dry 1.51 J ND
ug/L 04/29/10 ----25 4.82 J 2.21 J ND 1.70 J ND
ug/L 10/13/10 ----25 27.2 1.71 J 9.78 J 4.14 J ND
ug/L 04/11/11 ----25 5.17 J 2.06 J 2.24 J 2.66 J ND
ug/L 10/03/11 ----25 1.80 J ND 2.35 J 1.82 J ND
ug/L 04/10/12 ----25 2.67 J ND 2.56 J 1.79 J ND
ug/L 10/15/12 ----25 2.64 J 1.62 J ND 1.68 J ND
ug/L 04/09/13 ----25 4.04 J 1.87 J ND ND ND
ug/L 10/08/13 ----25 1.92 J ND ND ND ND
ug/L 04/08/14 ----25 6.83 J 2.94 J 3.72 J 3.03 J ND
ug/L 10/08/14 1.4 --25 ND dry ND ND ND
ug/L 04/08/15 1.4 --25 ND ND ND ND ND
ug/L 10/28/15 1.4 --25 7.18 J 2.73 J 3.63 J 2.63 J ND
ug/L 04/05/16 1.4 --25 2.04 J 3.33 J ND 2.92 J ND
ug/L 10/04/16 1.4 --25 2.43 J 2.90 J ND 3.99 J ND
ug/L 04/03/17 1.4 --25 ND ND 0.177 J ND ND
ug/L 10/03/17 1.4 --25 1.53 J 1.84 J Dry 1.95 J ND
ug/L 05/22/18 1.4 --25 6.26 J 3.51 J 3.20 J 3.87 J ND
ug/L 10/23/18 1.4 10 --ND ND ND ND ND
ug/L 04/16/19 1.4 10 --ND 1.72 J 1.93 J 1.98 J ND
ug/L 10/16/19 1.4 10 --Dry ND Dry 1.60 J ND
ug/L 04/14/20 1.4 10 --ND 1.98 J ND 1.68 J ND
ug/L 10/07/20 1.4 10 --ND ND ND ND ND
ug/L 05/10/21 1.4 10 --ND ND ND ND ND
ug/L 10/06/21 1.4 10 --Dry ND ND ND ND
ug/L 05/18/22 1.4 10 --ND ND ND ND ND
ug/L 10/10/22 1.0 10 --DRY 62 DRY 2.7 J ND
7 of 12
September 2023 31404568.018
SW-1 SW-3 SW-2 SW-4 BlanksDetected Monitoring Constituent/Parameter Units Date SWS Reporting
LimitDetection Quantitation
Zinc ug/L 09/22/94 ----50 62 ND ND ND ND
Freshwater Acute SW Standard =ug/L 11/08/94 ----50 ND ND ND ND ND
SW-1 - 83.5 ug/L ug/L 01/18/95 ----50 ND ND ND ND ND
SW-2 - 93.9 ug/L ug/L 04/23/96 ----50 ND ND ND ND ND
SW-3 - 87.7 ug/L ug/L 06/17/97 ----50 85 B 53 B --69 B 72
SW-4 - 106 ug/L ug/L 10/16/97 ----50 ND ND ND ND ND
Freshwater Chronic SW Standard = ug/L 04/21/98 ----50 175 ND ND ND ND
SW-1 - 84.1 ug/L ug/L 04/07/99 ----50 ND ND ND ND ND
SW-2 - 94.7 ug/L ug/L 10/13/99 ----50 121 ND ND ND ND
SW-3 - 88.4 ug/L ug/L 04/05/00 ----50 207 ND ND ND ND
SW-4 - 107 ug/L ug/L 10/25/00 ----50 271 ND --ND ND
ug/L 04/04/01 ----50 258 ND ND ND ND
ug/L 04/08/02 ----50 87 ND ND ND ND
ug/L 10/21/02 ----50 ND ND ND ND ND
ug/L 04/14/03 ----50 235 ND ND ND ND
ug/L 10/01/03 ----50 201 ND 455 ND ND
ug/L 04/05/04 ----50 362 ND ND ND ND
ug/L 10/18/04 ----50 ND ND ND ND ND
ug/L 04/07/05 ----50 304 ND ND ND ND
ug/L 10/06/05 ----50 ND ND ND ND ND
ug/L 04/03/06 ----50 122 ND ND ND ND
ug/L 10/03/06 ----50 ND ND ND ND ND
ug/L 04/05/07 ----10 192 ND 13 ND ND
ug/L 10/18/07 ----50 --18 --13 1.5 J
ug/L 04/29/08 ----10 21.4 B 23.5 B 22.6 B 5.2 B 122
ug/L 10/23/08 ----10 Dry ND ND ND ND
ug/L 04/07/09 ----10 4.9 B 6.3 B 32.0 6.9 B 4.2 J
ug/L 10/19/09 ----10 Dry 7.91 J Dry 5.11 J ND
ug/L 04/29/10 ----10 4.45 J 13.0 12.1 6.14 J ND
ug/L 10/13/10 ----10 39.6 5.56 J 7.47 J 18.5 ND
ug/L 04/11/11 ----10 5.69 J 4.59 J 6.30 J 4.74 J ND
ug/L 10/03/11 ----10 ND 17.2 8.93 J 4.01 J ND
ug/L 04/10/12 ----10 5.19 J 4.85 J 8.52 J 4.75 J ND
ug/L 10/15/12 ----10 ND ND ND ND ND
ug/L 04/09/13 ----10 4.52 J ND 4.69 J 4.00 J ND
ug/L 10/08/13 ----10 ND 4.59 J 3.88 J 3.80 J ND
ug/L 04/08/14 ----10 7.57 J ND 22.0 ND ND
ug/L 10/08/14 3.8 --10 10.3 dry 7.25 J 11.0 ND
ug/L 04/08/15 3.8 --10 5.47 J 15.5 ND 19.5 ND
ug/L 10/28/15 3.8 --10 4.78 J ND ND 41.6 ND
ug/L 04/05/16 4.4 --10 ND 23.8 ND ND ND
ug/L 10/04/16 4.4 --10 ND 12.9 ND 5.11 J ND
ug/L 04/03/17 4.4 --10 ND ND ND ND ND
ug/L 10/03/17 4.4 --10 ND 4.50 J Dry 5.26 J ND
ug/L 05/22/18 4.4 --10 5.49 J ND 5.25 J ND ND
ug/L 10/23/18 4.4 10 --ND ND ND ND ND
ug/L 04/16/19 4.4 10 --ND 5.33 J 7.27 J 9.59 J ND
ug/L 10/16/19 4.4 10 --Dry 5.25 J Dry 5.53 J ND
ug/L 04/14/20 4.4 10 --ND ND ND ND ND
ug/L 10/07/20 4.4 10 --ND ND ND ND ND
ug/L 05/10/21 4.4 10 --ND ND ND ND ND
ug/L 10/06/21 4.4 10 --Dry ND ND ND ND
ug/L 05/18/22 4.4 10 --11.9 5.26 J ND 4.94 J ND
ug/L 10/10/22 8.7 20 --DRY 82 DRY ND ND
ug/L 05/22/23 8.7 20 --ND ND ND ND ND
Acetone ug/L 09/22/94 ----100 ND ND ND ND ND
Freshwater SW Standard = 2000 ug/L ug/L 11/08/94 ----100 ND ND ND ND ND
ug/L 01/18/95 ----100 ND ND ND ND ND
ug/L 04/23/96 ----100 ND ND ND ND ND
ug/L 06/17/97 ----100 ND ND ND ND ND
ug/L 10/16/97 ----100 ND ND ND ND ND
ug/L 04/21/98 ----100 ND ND ND ND ND
ug/L 04/07/99 ----100 ND ND ND ND ND
ug/L 10/13/99 ----100 ND ND ND ND ND
ug/L 04/05/00 ----100 ND ND ND ND ND
ug/L 10/25/00 ----100 ND ND ND ND ND
ug/L 04/04/01 ----100 ND ND ND ND ND
ug/L 04/08/02 ----100 ND ND ND ND ND
ug/L 10/21/02 ----100 ND ND ND ND ND
ug/L 04/14/03 ----100 ND ND ND ND ND
ug/L 10/01/03 ----100 ND ND ND ND ND
ug/L 04/05/04 ----100 ND ND ND ND ND
ug/L 10/18/04 ----100 ND ND ND ND ND
ug/L 04/07/05 ----100 ND ND ND ND ND
ug/L 10/06/05 ----100 ND ND ND ND ND
ug/L 04/03/06 ----100 ND ND ND ND ND
ug/L 10/03/06 ----100 ND ND ND ND ND
ug/L 04/05/07 ----100 ND ND ND ND ND
ug/L 10/18/07 ----100 --2.3 J --1.8 J ND
ug/L 04/29/08 ----100 3.9 B ND ND 10 B 2.7 J
ug/L 10/23/08 ----100 Dry 5.9 B 6.2 B 5.1 B 5.3 J
ug/L 04/07/09 ----100 ND ND ND ND ND
ug/L 10/19/09 ----100 Dry ND Dry ND 8.2 J
ug/L 04/29/10 ----100 ND ND ND ND ND
ug/L 10/13/10 ----100 ND ND ND ND ND
ug/L 04/11/11 ----100 ND ND ND ND ND
ug/L 10/03/11 ----100 ND ND ND ND ND
ug/L 04/10/12 ----100 ND ND ND ND ND
ug/L 10/15/12 ----100 ND ND ND ND ND
ug/L 04/09/13 ----100 ND ND ND ND ND
ug/L 10/08/13 ----100 ND ND ND ND ND
ug/L 04/08/14 ----100 ND ND ND ND ND
ug/L 10/08/14 12 --100 ND dry ND ND ND
ug/L 04/08/15 12 --100 ND 3.2 J ND ND ND
ug/L 10/28/15 12 --100 ND ND ND ND ND
ug/L 04/05/16 12 --100 ND ND ND ND ND
ug/L 10/04/16 10 --100 ND ND ND ND ND
ug/L 04/03/17 10 --100 ND ND ND ND ND
ug/L 10/03/17 10 --100 ND ND Dry ND ND
ug/L 05/22/18 10 --100 ND ND ND ND ND
ug/L 10/23/18 10 20 --ND ND ND ND ND
ug/L 04/16/19 10 20 --ND ND ND ND ND
ug/L 10/16/19 10 20 --Dry ND Dry ND ND
ug/L 04/14/20 10 20 --ND ND ND ND ND
ug/L 10/07/20 10 20 --ND ND ND ND ND
ug/L 05/10/21 10 20 --ND ND ND ND ND
ug/L 10/06/21 10 20 --Dry ND ND ND 23
ug/L 05/18/22 10 20 --ND ND ND ND ND
ug/L 10/10/22 3.7 10 --DRY ND DRY ND ND
8 of 12
September 2023 31404568.018
SW-1 SW-3 SW-2 SW-4 BlanksDetected Monitoring Constituent/Parameter Units Date SWS Reporting
LimitDetection Quantitation
Bromodichloromethane ug/L 09/22/94 ----5 ND ND ND ND ND
No SW Standard ug/L 11/08/94 ----5 ND ND ND ND ND
ug/L 01/18/95 ----5 ND ND ND ND ND
ug/L 04/23/96 ----5 ND ND ND ND ND
ug/L 06/17/97 ----5 ND ND ND ND ND
ug/L 10/16/97 ----5 ND ND ND ND ND
ug/L 04/21/98 ----5 ND ND ND ND ND
ug/L 04/07/99 ----5 ND ND ND ND ND
ug/L 10/13/99 ----5 ND ND ND ND ND
ug/L 04/05/00 ----5 ND ND ND ND ND
ug/L 10/25/00 ----5 ND ND ND ND ND
ug/L 04/04/01 ----5 ND ND ND ND ND
ug/L 04/08/02 ----5 ND ND ND ND ND
ug/L 10/21/02 ----5 ND ND ND ND ND
ug/L 04/14/03 ----5 ND ND ND ND ND
ug/L 10/01/03 ----5 ND ND ND ND ND
ug/L 04/05/04 ----5 ND ND ND ND ND
ug/L 10/18/04 ----5 ND ND ND ND ND
ug/L 04/07/05 ----5 ND ND ND ND ND
ug/L 10/06/05 ----5 ND ND ND ND ND
ug/L 04/03/06 ----5 ND ND ND ND ND
ug/L 10/03/06 ----5 ND ND ND ND ND
ug/L 04/05/07 ----3 ND ND ND ND ND
ug/L 10/18/07 ----1 --1.2 J --0.3 J ND
ug/L 04/29/08 ----1 ND ND ND ND ND
ug/L 10/23/08 ----1 Dry ND ND ND ND
ug/L 04/07/09 ----1 ND ND ND ND ND
ug/L 10/19/09 ----1 Dry ND Dry ND ND
ug/L 04/29/10 ----1 ND ND ND ND ND
ug/L 10/13/10 ----1 ND 3.3 ND ND ND
ug/L 04/11/11 ----1 ND ND ND ND ND
ug/L 10/03/11 ----1 ND ND ND ND ND
ug/L 04/10/12 ----1 ND ND ND ND ND
ug/L 10/15/12 ----1 ND ND ND ND ND
ug/L 04/09/13 ----1 ND ND ND ND ND
ug/L 10/08/13 ----1 ND ND ND ND ND
ug/L 04/08/14 ----1 ND ND ND ND ND
ug/L 10/08/14 0.17 --1 ND dry ND ND ND
ug/L 04/08/15 0.17 --1 ND ND ND ND ND
ug/L 10/28/15 0.17 --1 ND ND ND ND ND
ug/L 04/05/16 0.17 --1 ND ND ND ND ND
ug/L 10/04/16 0.17 --1 ND 0.79 J ND ND ND
ug/L 04/03/17 0.17 --1 ND ND ND ND ND
ug/L 10/03/17 0.17 --1 ND 0.51 J Dry ND ND
ug/L 05/22/18 0.17 --1 ND ND ND ND ND
ug/L 10/23/18 0.17 1 --ND ND ND ND ND
ug/L 04/16/19 0.17 1 --ND ND ND ND ND
ug/L 10/16/19 0.17 1 --Dry ND Dry ND ND
ug/L 04/14/20 0.17 1 --ND ND ND ND ND
ug/L 10/07/20 0.17 1 --ND ND ND ND ND
ug/L 05/10/21 0.17 1 --ND ND ND ND ND
ug/L 10/06/21 0.17 1 --Dry ND ND ND ND
ug/L 05/18/22 0.17 1 --ND ND ND ND ND
ug/L 10/10/22 0.39 1.0 --DRY 0.44 J DRY ND ND
9 of 12
September 2023 31404568.018
SW-1 SW-3 SW-2 SW-4 BlanksDetected Monitoring Constituent/Parameter Units Date SWS Reporting
LimitDetection Quantitation
Chloroform ug/L 09/22/94 ----5 ND ND ND ND ND
No SW Standard ug/L 11/08/94 ----5 ND ND ND ND ND
ug/L 01/18/95 ----5 ND ND ND ND ND
ug/L 04/23/96 ----5 ND ND ND ND ND
ug/L 06/17/97 ----5 ND ND ND ND ND
ug/L 10/16/97 ----5 ND ND ND ND ND
ug/L 04/21/98 ----5 ND ND ND ND ND
ug/L 04/07/99 ----5 ND ND ND ND ND
ug/L 10/13/99 ----5 ND ND ND ND ND
ug/L 04/05/00 ----5 ND ND ND ND ND
ug/L 10/25/00 ----5 ND ND ND ND ND
ug/L 04/04/01 ----5 ND ND ND ND ND
ug/L 04/08/02 ----5 ND ND ND ND ND
ug/L 10/21/02 ----5 ND ND ND ND ND
ug/L 04/14/03 ----5 ND ND ND ND ND
ug/L 10/01/03 ----5 ND ND ND ND ND
ug/L 04/05/04 ----5 ND ND ND ND ND
ug/L 10/18/04 ----5 ND ND ND ND ND
ug/L 04/07/05 ----5 ND ND ND ND ND
ug/L 10/06/05 ----5 ND ND ND ND ND
ug/L 04/03/06 ----5 ND ND ND ND ND
ug/L 10/03/06 ----5 ND ND ND ND ND
ug/L 04/05/07 ----5 ND ND ND ND ND
ug/L 10/18/07 ----5 --2.3 J --0.9 J ND
ug/L 04/29/08 ----5 ND ND ND ND ND
ug/L 10/23/08 ----5 Dry 0.51 J ND 0.57 J ND
ug/L 04/07/09 ----5 ND ND ND ND ND
ug/L 10/19/09 ----5 Dry 0.44 J Dry 0.56 J ND
ug/L 04/29/10 ----5 ND ND ND ND ND
ug/L 10/13/10 ----5 ND 1.6 J ND 0.44 J ND
ug/L 04/11/11 ----5 ND ND ND ND ND
ug/L 10/03/11 ----5 ND ND ND ND ND
ug/L 04/10/12 ----5 ND ND ND 0.34 J ND
ug/L 10/15/12 ----5 ND ND ND 0.92 J ND
ug/L 04/09/13 ----5 ND ND ND ND ND
ug/L 10/08/13 ----5 ND ND ND 0.47 J ND
ug/L 04/08/14 ----5 ND ND ND ND ND
ug/L 10/08/14 0.18 --5 0.75 J dry ND 0.65 J ND
ug/L 04/08/15 0.18 --5 ND ND ND ND ND
ug/L 10/28/15 0.18 --5 ND ND ND 0.58 J ND
ug/L 04/05/16 0.18 --5 ND ND ND 0.47 J ND
ug/L 10/04/16 0.18 --5 ND 1.8 J ND 1.0 J ND
ug/L 04/03/17 0.18 --5 ND ND ND ND ND
ug/L 10/03/17 0.18 --5 ND ND Dry ND ND
ug/L 05/22/18 0.18 --5 ND ND ND ND ND
ug/L 10/23/18 0.18 1 --ND ND ND ND ND
ug/L 04/16/19 0.18 1 --ND ND ND ND ND
ug/L 10/16/19 0.18 1 --Dry 0.62 J Dry ND ND
ug/L 04/14/20 0.18 1 --ND ND ND ND ND
ug/L 10/07/20 0.18 1 --ND ND ND 0.44 J ND
ug/L 05/10/21 0.18 1 --ND ND ND ND ND
ug/L 10/06/21 0.18 1 --Dry ND ND ND ND
ug/L 05/18/22 0.18 1 --ND 0.53 J ND 0.66 J ND
ug/L 10/10/22 0.27 1.0 --DRY 0.89 J DRY 0.49 J ND
ug/L 05/22/23 0.18 1 --ND ND 0.725 B 0.733 B 0.205 J
Dibromochloromethane ug/L 09/22/94 ----5 ND ND ND ND ND
No SW Standard ug/L 11/08/94 ----5 ND ND ND ND ND
ug/L 01/18/95 ----5 ND ND ND ND ND
ug/L 04/23/96 ----5 ND ND ND ND ND
ug/L 06/17/97 ----5 ND ND ND ND ND
ug/L 10/16/97 ----5 ND ND ND ND ND
ug/L 04/21/98 ----5 ND ND ND ND ND
ug/L 04/07/99 ----5 ND ND ND ND ND
ug/L 10/13/99 ----5 ND ND ND ND ND
ug/L 04/05/00 ----5 ND ND ND ND ND
ug/L 10/25/00 ----5 ND ND ND ND ND
ug/L 04/04/01 ----5 ND ND ND ND ND
ug/L 04/08/02 ----5 ND ND ND ND ND
ug/L 10/21/02 ----5 ND ND ND ND ND
ug/L 04/14/03 ----5 ND ND ND ND ND
ug/L 10/01/03 ----5 ND ND ND ND ND
ug/L 04/05/04 ----5 ND ND ND ND ND
ug/L 10/18/04 ----5 ND ND ND ND ND
ug/L 04/07/05 ----5 ND ND ND ND ND
ug/L 10/06/05 ----5 ND ND ND ND ND
ug/L 04/03/06 ----5 ND ND ND ND ND
ug/L 10/03/06 ----5 ND ND ND ND ND
ug/L 04/05/07 ----3 ND ND ND ND ND
ug/L 10/18/07 ----3 --0.8 J --0.2 J ND
ug/L 04/29/08 ----3 ND ND ND ND ND
ug/L 10/23/08 ----3 Dry ND ND ND ND
ug/L 04/07/09 ----3 ND ND ND ND ND
ug/L 10/19/09 ----3 Dry ND Dry ND ND
ug/L 04/29/10 ----3 ND ND ND ND ND
ug/L 10/13/10 ----3 ND 4.0 ND ND ND
ug/L 04/11/11 ----3 ND ND ND ND ND
ug/L 10/03/11 ----3 ND ND ND ND ND
ug/L 04/10/12 ----3 ND ND ND ND ND
ug/L 10/15/12 ----3 ND ND ND ND ND
ug/L 04/09/13 ----3 ND ND ND ND ND
ug/L 10/08/13 ----3 ND ND ND ND ND
ug/L 04/08/14 ----3 ND ND ND ND ND
ug/L 10/08/14 0.17 --3 ND dry ND ND ND
ug/L 04/08/15 0.17 --3 ND ND ND ND ND
ug/L 10/28/15 0.17 --3 ND ND ND ND ND
ug/L 04/05/16 0.17 --3 ND ND ND ND ND
ug/L 10/04/16 0.17 --3 ND ND ND ND ND
ug/L 04/03/17 0.17 --3 ND ND ND ND ND
ug/L 10/03/17 0.17 --3 ND ND Dry ND ND
ug/L 05/22/18 0.17 --3 ND ND ND ND ND
ug/L 10/23/18 0.17 1 --ND ND ND ND ND
ug/L 04/16/19 0.17 1 --ND ND ND ND ND
ug/L 10/16/19 0.17 1 --Dry ND Dry ND ND
ug/L 04/14/20 0.17 1 --ND ND ND ND ND
ug/L 10/07/20 0.17 1 --ND ND ND ND ND
ug/L 05/10/21 0.17 1 --ND ND ND ND ND
ug/L 10/06/21 0.17 1 --Dry ND ND ND ND
ug/L 05/18/22 0.17 1 --ND ND ND ND ND
ug/L 10/10/22 0.25 1.0 --DRY 0.61 J DRY ND ND
10 of 12
September 2023 31404568.018
SW-1 SW-3 SW-2 SW-4 BlanksDetected Monitoring Constituent/Parameter Units Date SWS Reporting
LimitDetection Quantitation
1,1-Dichloroethane ug/L 09/22/94 ----5 ND ND ND ND ND
No SW Standard ug/L 11/08/94 ----5 ND ND ND ND ND
ug/L 01/18/95 ----5 ND ND ND ND ND
ug/L 04/23/96 ----5 ND ND 6 ND ND
ug/L 06/17/97 ----5 ND ND ND ND ND
ug/L 10/16/97 ----5 ND ND ND ND ND
ug/L 04/21/98 ----5 ND ND ND ND ND
ug/L 04/07/99 ----5 ND ND ND ND ND
ug/L 10/13/99 ----5 ND ND ND ND ND
ug/L 04/05/00 ----5 ND ND ND ND ND
ug/L 10/25/00 ----5 ND ND ND ND ND
ug/L 04/04/01 ----5 ND ND ND ND ND
ug/L 04/08/02 ----5 ND ND ND ND ND
ug/L 10/21/02 ----5 ND ND ND ND ND
ug/L 04/14/03 ----5 ND ND ND ND ND
ug/L 10/01/03 ----5 ND ND ND ND ND
ug/L 04/05/04 ----5 ND ND ND ND ND
ug/L 10/18/04 ----5 ND ND ND ND ND
ug/L 04/07/05 ----5 ND ND ND ND ND
ug/L 10/06/05 ----5 ND ND ND ND ND
ug/L 04/03/06 ----5 ND ND ND ND ND
ug/L 10/03/06 ----5 ND ND ND ND ND
ug/L 04/05/07 ----5 ND ND ND ND ND
ug/L 10/18/07 ----5 ND ND ND ND ND
ug/L 04/29/08 ----5 ND ND 1.5 J 1.9 J ND
ug/L 10/23/08 ----5 Dry ND ND ND ND
ug/L 04/07/09 ----5 ND ND 0.55 J ND ND
ug/L 10/19/09 ----5 Dry ND Dry ND ND
ug/L 04/29/10 ----5 ND ND ND ND ND
ug/L 10/13/10 ----5 ND ND ND ND ND
ug/L 04/11/11 ----5 ND ND 0.64 J ND ND
ug/L 10/03/11 ----5 ND 1.0 J ND ND ND
ug/L 04/10/12 ----5 ND 0.48 J ND ND ND
ug/L 10/15/12 ----5 ND ND ND ND ND
ug/L 04/09/13 ----5 ND ND 0.75 J ND ND
ug/L 10/08/13 ----5 ND ND ND ND ND
ug/L 04/08/14 ----5 ND ND ND ND ND
ug/L 10/08/14 0.13 --5 ND dry ND ND ND
ug/L 04/08/15 0.13 --5 ND ND ND ND ND
ug/L 10/28/15 0.13 --5 ND ND ND ND ND
ug/L 04/05/16 0.13 --5 ND ND 0.63 J ND ND
ug/L 10/04/16 0.13 --5 ND ND ND ND ND
ug/L 04/03/17 0.13 --5 ND ND ND ND ND
ug/L 10/03/17 0.13 --5 ND ND Dry ND ND
ug/L 05/22/18 0.13 --5 ND ND ND ND ND
ug/L 10/23/18 0.13 1 --ND ND ND ND ND
ug/L 04/16/19 0.13 1 --ND ND ND ND ND
ug/L 10/16/19 0.13 1 --Dry ND Dry ND ND
ug/L 04/14/20 0.13 1 --ND ND ND ND ND
ug/L 10/07/20 0.13 1 --ND ND ND ND ND
ug/L 05/10/21 0.13 1 --ND ND ND ND ND
ug/L 10/06/21 0.13 1 --Dry ND ND ND ND
ug/L 05/18/22 0.13 1 --ND ND ND ND ND
ug/L 10/10/22 0.33 1.0 --DRY ND DRY ND ND
11 of 12
September 2023 31404568.018
SW-1 SW-3 SW-2 SW-4 BlanksDetected Monitoring Constituent/Parameter Units Date SWS Reporting
LimitDetection Quantitation
Chloromethane ug/L 09/22/94 ----10 ND ND ND ND ND
No SW Standard ug/L 11/08/94 ----10 ND ND ND ND ND
ug/L 01/18/95 ----10 ND ND ND ND ND
ug/L 04/23/96 ----10 ND ND ND ND ND
ug/L 06/17/97 ----10 ND ND ND ND ND
ug/L 10/16/97 ----10 ND ND ND ND ND
ug/L 04/21/98 ----10 ND ND ND ND ND
ug/L 04/07/99 ----10 ND ND ND ND ND
ug/L 10/13/99 ----10 ND ND ND ND ND
ug/L 04/05/00 ----10 ND ND ND ND ND
ug/L 10/25/00 ----10 ND ND ND ND ND
ug/L 04/04/01 ----10 ND ND ND ND ND
ug/L 04/08/02 ----10 ND ND ND ND ND
ug/L 10/21/02 ----10 ND ND ND ND ND
ug/L 04/14/03 ----10 ND ND ND ND ND
ug/L 10/01/03 ----10 ND ND ND ND ND
ug/L 04/05/04 ----10 ND ND ND ND ND
ug/L 10/18/04 ----10 ND ND ND ND ND
ug/L 04/07/05 ----10 ND ND ND ND ND
ug/L 10/06/05 ----10 ND ND ND ND ND
ug/L 04/03/06 ----10 ND ND ND ND ND
ug/L 10/03/06 ----10 ND ND ND ND ND
ug/L 04/05/07 ----5 ND ND ND ND ND
ug/L 10/18/07 ----1 --0.6 J --0.4 J ND
ug/L 04/29/08 ----1 ND ND ND ND ND
ug/L 10/23/08 ----1 Dry ND ND ND ND
ug/L 04/07/09 ----1 ND ND ND ND ND
ug/L 10/19/09 ----1 Dry ND Dry ND ND
ug/L 04/29/10 ----1 ND ND ND ND ND
ug/L 10/13/10 ----1 ND ND ND ND 0.49 J
ug/L 04/11/11 ----1 ND ND ND ND ND
ug/L 10/03/11 ----1 ND ND ND ND ND
ug/L 04/10/12 ----1 ND ND ND ND ND
ug/L 10/15/12 ----1 ND ND ND ND ND
ug/L 04/09/13 ----1 ND ND ND ND ND
ug/L 10/08/13 ----1 ND ND ND ND ND
ug/L 04/08/14 ----1 ND ND ND ND ND
ug/L 10/08/14 0.13 --1 ND dry ND ND ND
ug/L 04/08/15 0.13 --1 ND ND ND ND ND
ug/L 10/28/15 0.13 --1 ND ND ND ND ND
ug/L 04/05/16 0.13 --1 ND ND ND ND ND
ug/L 10/04/16 0.13 --1 ND ND ND ND ND
ug/L 04/03/17 0.13 --1 ND ND ND ND ND
ug/L 10/03/17 0.13 --1 ND ND Dry ND ND
ug/L 05/22/18 0.13 --1 ND ND ND ND ND
ug/L 10/23/18 0.13 1 --ND ND ND ND ND
ug/L 04/16/19 0.13 1 --ND ND ND ND ND
ug/L 10/16/19 0.13 1 --Dry ND Dry ND ND
ug/L 04/14/20 0.13 1 --ND ND ND ND ND
ug/L 10/07/20 0.13 1 --ND ND ND ND ND
ug/L 05/10/21 0.13 1 --ND ND ND ND ND
ug/L 10/06/21 0.13 1 --Dry ND ND ND ND
ug/L 05/18/22 0.13 1 --ND ND ND ND ND
ug/L 10/10/22 0.54 1.0 --DRY ND DRY ND ND
ug/L 05/22/23 0.13 1 --ND ND ND ND ND
1,4-Dioxane (Human Health = 80 ug/L)ug/L 10/23/18 1.2 2 --1.6 J 29 14 12 ND
ug/L 04/16/19 1.2 2 --ND 2.1 10 2.3 ND
ug/L 10/16/19 1.2 2 --Dry 18 Dry 17 ND
ug/L 04/14/20 0.80 2 --0.81 J 2.8 14 2.4 ND
ug/L 10/07/20 0.80 2 --1.7 J ND 18 3.0 ND
ug/L 05/10/21 0.80 2 --1.0 J 1.3 J 20 1.6 J ND
ug/L 10/06/21 0.80 2 --Dry 25 2.2 6.4 ND
ug/L 05/18/22 0.80 2 --1.3 J 2.3 20 3.0 ND
ug/L 10/10/22 0.27 1.4 --DRY 11 DRY 6.2 ND
ug/L 05/22/23 0.32 0.5 --1.23 19.4 4.58 4.05 ND
Notes:mg/L =milligrams per liter
ug/L =micrograms per liter
ND =
J =
B =Blank-qualified result
-- =no data available
Bold =Concentrations above Human Health or Chronic Surface Water Standard
Shaded and Bold =
SW Standard =Surface Water Standard based on Freshwater Aquatic Life Classification
Blanks =field, trip and method blanks
SWS Reporting Limit =NCPQL or lab-specific reporting limit prior to October 2007 and NCSWSL starting in October 2007
(N) =Narrative Standard
(AL) =Action Level Standard
1)Historical data prior to April 2008 provided by the County and taken from historical reports from
2)Hazen and Sawyer and Environment 1.
3)During the April 2019 event, lead in the sample from SW-2 was re-analyzed by EPA method 6020B and did not confirm.
12 of 12
September 2023 31404568.018
SW-1 SW-3 SW-2 SW-4
pH (field)S.U.09/22/94 5.9 5.9 5.7 6.0
S.U.11/08/94 6.2 --6.2 --
S.U.01/18/95 6.3 --6.4 --
S.U.04/23/96 6.2 6.1 6.4 --
S.U.06/17/97 5.4 5.8 --4.5
S.U.10/16/97 6.0 6.2 5.5 6.1
S.U.04/21/98 6.4 6.4 6.2 6.8
S.U.04/07/99 6.4 7.1 6.2 7.0
S.U.10/13/99 7.7 7.5 6.9 7.4
S.U.04/05/00 7.8 6.8 6.6 7.0
S.U.10/25/00 6.3 7.0 --7.0
S.U.04/04/01 6.2 7.2 6.4 7.2
S.U.04/08/02 6.7 7.6 6.2 7.2
S.U.10/21/02 6.9 7.2 6.4 7.4
S.U.04/14/03 7.5 7.1 6.7 7.2
S.U.10/01/03 6.6 7.0 6.2 7.1
S.U.04/05/04 6.4 7.8 6.6 7.4
S.U.10/18/04 7.4 7.3 6.2 7.3
S.U.04/07/05 7.0 7.3 6.6 7.4
S.U.10/06/05 7.0 6.8 --7.3
S.U.04/03/06 7.0 7.3 6.4 7.3
S.U.10/03/06 6.7 7.1 --7.0
S.U.04/05/07 6.7 7.1 6.3 7.1
S.U.10/18/07 --7.4 --8.0
S.U.04/29/08 6.43 8.61 8.66 6.91
S.U.10/23/08 Dry 9.37 6.91 5.86
S.U.04/07/09 6.93 7.37 6.53 7.48
S.U.10/19/09 Dry 6.80 Dry 8.04
S.U.04/29/10 6.25 7.29 6.57 7.08
S.U.10/13/10 6.48 7.22 6.00 7.09
S.U.04/12/11 6.92 6.68 6.24 6.02
S.U.10/03/11 8.16 7.54 7.80 7.75
S.U.04/11/12 6.59 7.21 6.90 7.42
S.U.10/15/12 6.57 6.67 6.82 6.93
S.U.04/09/13 7.27 6.93 5.79 7.34
S.U.10/08/13 7.09 7.39 7.41 7.26
S.U.04/08/14 7.62 8.10 6.54 8.09
S.U.10/08/14 6.98 7.76 Dry 7.20
S.U.04/08/15 6.80 7.56 6.09 7.02
S.U.10/28/15 6.39 7.28 7.69 6.89
S.U.04/05/16 7.03 6.36 5.92 7.16
S.U.10/04/16 6.47 6.74 6.46 6.52
S.U.04/03/17 7.67 7.24 6.92 7.36
S.U.10/03/17 7.00 7.40 Dry 7.14
S.U.05/23/18 6.95 7.20 6.77 7.27
S.U.10/23/18 6.89 7.51 7.33 7.43
S.U.04/16/19 7.35 7.39 6.99 7.58
S.U.10/15/19 Dry 7.41 Dry 7.39
S.U.04/14/20 6.73 6.93 7.17 7.46
S.U.10/07/20 7.39 7.48 8.01 7.67
S.U.05/10/21 7.13 7.48 7.26 7.33
S.U.10/06/21 Dry 7.54 7.23 7.45
S.U.05/18/22 6.99 7.58 6.92 7.39
S.U.10/10/22 Dry 7.37 Dry 7.25
TABLE 7
Summary of Surface Water Field Parameters
Closed Randolph County Landfill, Permit No. 76-01
Detected Monitoring Constituent/Parameter Units Date
1 of 5
September 2023 31404568.018
SW-1 SW-3 SW-2 SW-4
Detected Monitoring Constituent/Parameter Units Date
Specific Conductivity (field)uS/cm 09/22/94 80 600 260 520
uS/cm 11/08/94 87 --230 --
uS/cm 01/18/95 270 --160 --
uS/cm 04/23/96 170 210 180 --
uS/cm 06/17/97 160 190 --200
uS/cm 10/16/97 170 620 260 460
uS/cm 04/21/98 610 100 200 94
uS/cm 04/07/99 300 180 220 180
uS/cm 10/13/99 1200 300 220 240
uS/cm 04/05/00 370 160 230 230
uS/cm 10/25/00 150 730 --500
uS/cm 04/04/01 530 130 200 130
uS/cm 04/08/02 260 180 200 210
uS/cm 10/21/02 342 192 251 197
uS/cm 04/14/03 1860 128 258 125
uS/cm 10/01/03 308 190 397 199
uS/cm 04/05/04 350 420 270 230
uS/cm 10/18/04 590 294 329 295
uS/cm 04/07/05 364 195 262 195
uS/cm 10/06/05 195 692 --618
uS/cm 04/03/06 255 269 288 298
uS/cm 10/03/06 180 167 --178
uS/cm 04/05/07 240 180 282 186
uS/cm 10/18/07 --556 --325
uS/cm 04/29/08 157 169 166 180
uS/cm 10/23/08 Dry 247 239 236
uS/cm 04/07/09 194 181 276 179
uS/cm 10/19/09 Dry 300 Dry 316
uS/cm 04/29/10 174 225 354 181
uS/cm 10/13/10 218 596 341 336
uS/cm 04/12/11 145 220 204 215
uS/cm 10/03/11 111 336 272 284
uS/cm 04/11/12 132 208 197 175
uS/cm 10/15/12 185 325 182 248
uS/cm 04/09/13 115 160 185 169
uS/cm 10/08/13 190 257 339 340
uS/cm 04/08/14 186 200 331 196
uS/cm 10/08/14 449 324 Dry 473
uS/cm 04/08/15 101 199 236 248
uS/cm 10/28/15 141 212 194 272
uS/cm 04/05/16 167 162 259 170
uS/cm 10/04/16 222 262 281 154
uS/cm 04/03/17 165 186 131 176
uS/cm 10/03/17 347 299 Dry 304
uS/cm 05/23/18 189 194 237 194
uS/cm 10/23/18 260 214 275 210
uS/cm 04/16/19 167 125 237 121
uS/cm 10/15/19 Dry 216 Dry 212
uS/cm 04/14/20 173 122 275 102
uS/cm 10/07/20 297 384 163 165
uS/cm 05/10/21 191 124 315 142
uS/cm 10/06/21 Dry 139 368 188
uS/cm 05/18/22 226 202 338 188
uS/cm 10/10/22 Dry 243 Dry 187
2 of 5
September 2023 31404568.018
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Detected Monitoring Constituent/Parameter Units Date
Temperature (field)Celsius 09/22/94 16 21 17 21
Celsius 11/08/94 9 --9 --
Celsius 01/18/95 8 --6 --
Celsius 04/23/96 17 20 16 --
Celsius 06/17/97 21 27 --27
Celsius 10/16/97 14 19 13 19
Celsius 04/21/98 14 16 12 16
Celsius 04/07/99 16 21 15 20
Celsius 10/13/99 11 18 17 18
Celsius 04/05/00 11 14 8 16
Celsius 10/25/00 15 18 --17
Celsius 04/04/01 11 12 9 12
Celsius 04/08/02 16 16 13 17
Celsius 10/21/02 15 15 15 15
Celsius 04/14/03 16 15 13 17
Celsius 10/01/03 14 18 13 18
Celsius 04/05/04 12 12 9 14
Celsius 10/18/04 15 17 13 17
Celsius 04/07/05 17 18 15 17
Celsius 10/06/05 21 24 --23
Celsius 04/03/06 15 18 15 18
Celsius 10/03/06 17 22 --22
Celsius 04/05/07 11 17 12 17
Celsius 10/18/07 --20 --20
Celsius 04/29/08 16.5 18.0 18.0 17.7
Celsius 10/23/08 Dry 16.4 11.5 16.0
Celsius 04/07/09 11.3 13.1 13.4 14.1
Celsius 10/19/09 Dry 14.3 Dry 14.6
Celsius 04/29/10 13.3 18.3 14.6 17.9
Celsius 10/13/10 16.4 18.8 15.8 18.8
Celsius 04/12/11 17.4 15.3 18.4 17.0
Celsius 10/03/11 13.0 19.0 14.2 20.5
Celsius 04/11/12 12.1 16.3 12.9 16.4
Celsius 10/15/12 14.6 16.9 14.9 17.7
Celsius 04/09/13 15.9 15.5 20.0 16.3
Celsius 10/08/13 16.0 20.9 16.2 21.0
Celsius 04/08/14 15.5 13.2 12.5 13.0
Celsius 10/08/14 19.8 21.4 Dry 21.5
Celsius 04/08/15 17.4 17.3 18.0 14.6
Celsius 10/28/15 16.7 16.4 15.3 16.4
Celsius 04/05/16 15.8 17.7 9.9 18.0
Celsius 10/04/16 17.4 21.4 17.4 21.2
Celsius 04/03/17 15.9 17.2 16.8 17.3
Celsius 10/03/17 14.1 20.8 Dry 20.8
Celsius 05/23/18 18.7 25.4 19.3 25.8
Celsius 10/23/18 10.2 16.3 10.3 16.6
Celsius 04/16/19 13.9 16.9 14.5 20.3
Celsius 10/15/19 Dry 19.9 Dry 19.7
Celsius 04/14/20 14.8 17.3 13.6 18.6
Celsius 10/07/20 15.3 15.7 20.4 18.7
Celsius 05/10/21 15.5 19.7 15.1 19.6
Celsius 10/06/21 Dry 23.3 20.7 22.9
Celsius 05/18/22 16.7 21.6 15.8 21.1
Celsius 10/10/22 Dry 17.6 Dry 17.8
3 of 5
September 2023 31404568.018
SW-1 SW-3 SW-2 SW-4
Detected Monitoring Constituent/Parameter Units Date
Turbidity (field)NTU 04/29/08 28.8 82.0 137 16.0
NTU 10/23/08 Dry 6.04 4.41 28.6
NTU 04/07/09 12.7 12.3 15.2 25.0
NTU 10/19/09 Dry 16.4 Dry 12.5
NTU 04/29/10 8.74 11.6 11.0 12.9
NTU 10/13/10 10.1 10.8 7.07 15.9
NTU 04/12/11 21.8 19.8 11.5 36.3
NTU 10/03/11 13.2 15.2 22.3 14.9
NTU 04/11/12 16.3 15.2 7.33 15.8
NTU 10/15/12 17.2 14.0 25.4 12.6
NTU 04/09/13 21.4 20.4 9.78 16.0
NTU 10/08/13 35.0 11.7 7.15 8.88
NTU 04/08/14 23.1 40.2 27.2 30.3
NTU 10/08/14 7.81 13.2 Dry 4.26
NTU 04/08/15 5.88 7.99 3.77 7.58
NTU 10/28/15 37.2 9.89 10.8 10.3
NTU 04/05/16 11.4 14.9 3.14 17.0
NTU 10/04/16 18.3 18.2 2.98 26.9
NTU 04/03/17 7.50 13.8 10.5 19.3
NTU 10/03/17 1.78 7.58 Dry 9.27
NTU 05/23/18 33.6 49.9 25.7 62.2
NTU 10/23/18 3.01 6.24 2.10 7.81
NTU 04/16/19 11.0 28.5 12.9 0.54
NTU 10/15/19 --8.80 --10.9
NTU 04/14/20 8.54 2.49 2.49 16.7
NTU 10/07/20 9.01 1.87 8.32 7.69
NTU 05/10/21 39.3 7.73 27.5 10.3
NTU 10/06/21 Dry 16.2 2.56 4.09
NTU 05/18/22 8.22 11.0 4.04 9.42
NTU 10/10/22 Dry 101 Dry 59.7
NTU 05/23/23 12.1 33.2 10.10 12.7
Dissolved Oxygen (field)mg/L 04/29/08 6.09 7.66 5.93 3.78
mg/L 10/23/08 Dry 7.14 8.80 5.72
mg/L 04/07/09 10.70 9.50 10.30 9.70
mg/L 10/19/09 Dry 8.55 Dry 7.45
mg/L 04/01/10 8.26 8.40 4.97 7.90
mg/L 10/13/10 2.98 5.54 3.50 6.53
mg/L 04/12/11 8.91 8.41 8.33 9.50
mg/L 10/03/11 13.01 8.78 7.36 10.27
mg/L 04/11/12 9.02 7.48 9.46 7.04
mg/L 10/15/12 8.29 6.14 6.96 7.14
mg/L 04/09/13 11.09 7.90 8.79 8.82
mg/L 10/08/13 7.15 4.34 6.53 3.98
mg/L 04/08/14 9.03 12.61 13.28 13.64
mg/L 10/08/14 5.50 5.30 Dry 6.26
mg/L 04/08/15 9.01 11.10 7.60 8.21
mg/L 10/28/15 6.45 7.80 8.54 5.74
mg/L 04/05/16 6.65 8.51 8.73 8.22
mg/L 10/04/16 3.87 4.01 6.16 3.46
mg/L 04/03/17 10.96 7.77 9.10 7.44
mg/L 10/03/17 7.87 4.44 Dry 5.01
mg/L 05/23/18 7.03 3.69 5.01 4.96
mg/L 10/23/18 7.14 6.82 7.59 5.65
mg/L 04/16/19 8.12 7.37 9.21 7.58
mg/L 10/15/19 Dry 4.65 Dry 5.86
mg/L 04/14/20 4.38 5.12 7.58 8.87
mg/L 10/07/20 8.30 8.70 7.78 8.01
mg/L 05/10/21 7.08 5.75 8.09 6.14
mg/L 10/06/21 Dry 8.77 6.67 6.45
mg/L 05/18/22 5.80 5.23 6.04 4.24
mg/L 10/10/22 Dry 4.38 Dry 4.90
4 of 5
September 2023 31404568.018
SW-1 SW-3 SW-2 SW-4
Detected Monitoring Constituent/Parameter Units Date
ORP (field)mV 10/23/08 Dry -44 -18 103
mV 04/07/09 111 158 12.7 159
mV 10/19/09 Dry 91.7 Dry 115
mV 04/29/10 8.6 89.9 98.4 105
mV 10/13/10 156 185 211 156
mV 04/12/11 44.2 189 238 155
mV 10/03/11 111 102 74.8 128
mV 04/11/12 23.7 54.1 32.1 57.1
mV 10/15/12 61.4 73.6 49.5 77.0
mV 04/09/13 -8.4 72.4 64.5 64.8
mV 10/08/13 1.2 41.3 51.1 52.5
mV 04/08/14 -17.1 76.9 78.8 220
mV 10/08/14 175 302 Dry 328
mV 04/08/15 14.0 82.8 93.4 57.2
mV 10/28/15 1.5 200 95.1 111
mV 04/05/16 149 157 96.0 128
mV 10/04/16 20.2 83.6 119 101
mV 04/03/17 161 152 143 223
mV 10/03/17 148 130 Dry 134
mV 05/23/18 154 157 91 160
mV 10/23/18 218 192 196 204
mV 04/16/19 370 329 394 315
mV 10/15/19 Dry 110 Dry 118
mV 04/14/20 32.5 114 50.6 144
mV 10/07/20 -2.1 -4.2 0.8 84
mV 05/10/21 -13.1 187 207 204
mV 10/06/21 Dry 153 177 160
mV 05/18/22 -14.3 76 83 106
mV 10/10/22 Dry 199 Dry 110
mV 05/23/23 116 152 116 169
Notes:mg/L =milligrams per liter
S.U. =Standard Units
NTU =Nephelometric Turbidity Units
ND =
uS/cm =
mV =Millivolts
-- =no data available
detected at the laboratory detection limit for data from October 2007 forward
5 of 5
September 2023 31404568.018
MW-5 MW-2 MW-3 MW-7 MW-8 MW-10S MW-10D MW-11S
Sulfide mg/L 04/11/11 0.01 --ND ND --ND ND ND ND ND ND
mg/L 10/28/15 0.01 --ND ND ND ND ND ND ND ND ND
mg/L 04/05/16 0.01 --ND ND ND ND ND ND ND ND ND
mg/L 10/04/16 0.01 --ND ND ND ND ND ND ND ND ND
mg/L 04/03/17 0.01 --ND ND ND ND ND ND ND ND ND
mg/L 10/03/17 0.01 --ND ND ND ND ND ND ND ND ND
mg/L 05/22/18 0.01 --ND ND ND ND ND ND ND ND ND
mg/L 10/23/18 0.01 --------------------
mg/L 04/16/19 0.01 0.1 ND ND ND ND ND ND ND ND ND
mg/L 10/15/19 0.01 --------------------
mg/L 04/14/20 0.01 0.1 ND ND ND ND ND ND ND ND ND
mg/L 10/07/20 0.01 0.1 ND ND ND ND ND ND ND ND ND
mg/L 05/10/21 0.01 0.1 ND ND ND ND ND ND ND ND ND
mg/L 05/17/22 0.01 0.1 --ND ND ND ND ND ND ND ND
mg/L 05/22/23 1.1 ----4.4 5.0 3.2 3.2 4.0 4.0 2.2 --
Chloride mg/L 04/11/11 0.047 --8.4 B 22 --20 10 32 270 5.3 B 1.9
mg/L 10/28/15 2.2 --6.1 48 4.6 J 19 13 47 280 4.3 J ND
mg/L 04/05/16 2.2 --6.2 15 4.7 J 12 11 27 270 5.2 ND
mg/L 10/04/16 6.5 --6.1 19 5.4 17 14 45 220 5.2 ND
mg/L 04/03/17 2.2 --6.2 18 6.8 13 12 33 190 5.0 ND
mg/L 10/03/17 2.2 --6.4 33 8.2 16 14 33 200 5.0 ND
mg/L 05/22/18 2.2 --6.5 17 4.0 J 11 12 30 190 5.9 ND
mg/L 10/23/18 2.2 5 6.2 27 6.2 12 11 55 200 5.7 ND
mg/L 04/16/19 2.2 5 6.1 5.9 2.6 J 8.9 9.7 27 190 5.7 ND
mg/L 10/15/19 2.2 5 6.1 40 8.1 11.0 14.0 39 170 5.3 ND
mg/L 04/14/20 2.2 5 8.8 20 5.5 9.3 11.0 29 180 6.4 ND
mg/L 10/07/20 2.2 5 7.6 18 6.4 11 11 42 170 6.3 ND
mg/L 05/10/21 2.2 5 6.9 17 ND 7.1 6.2 25 170 5.4 ND
mg/L 10/06/21 2.2 5 8.7 35 7.6 12 12 36 180 6.9 ND
mg/L 05/17/22 2.2 5 8.2 22 6.7 8.3 10 22 170 6.2 ND
mg/L 10/10/22 2.2 5 --63 10.8 14.7 15.7 59 194 7.2 ND
mg/L 05/22/23 0.05 ----13.80 7.48 8.65 7.60 38.6 175 6.52 --
Nitrate as N mg/L 04/11/11 0.025 --1.2 J ND --3.3 J 1.9 J ND ND ND --
mg/L 10/28/15 0.025 --1.0 J ND 0.10 J ND 0.16 J ND 0.11 J 0.11 J ND
mg/L 04/05/16 0.025 --1.1 J ND 0.13 J 0.047 J 0.13 J ND 0.10 J 0.09 J ND
mg/L 10/04/16 0.025 --1.1 J ND 0.15 J 0.048 J 0.16 J 0.064 J 0.058 J 0.11 J ND
mg/L 04/03/17 0.025 --0.92 J ND 0.10 J ND 0.12 J ND ND 0.082 J ND
mg/L 10/03/17 0.025 --1.2 J ND ND ND 0.17 J ND ND 0.05 J ND
mg/L 05/22/18 0.025 --1.0 J ND 0.093 J ND 0.061 J 0.064 J 0.052 J 0.110 J ND
mg/L 10/23/18 0.025 0.1 0.64 ND 0.046 J 0.052 J 0.053 J ND 0.078 J 0.14 ND
mg/L 04/16/19 0.041 0.1 0.82 0.22 ND ND 0.054 J 0.054 J ND 0.075 J ND
mg/L 10/15/19 0.041 0.1 0.92 ND ND ND 0.098 J ND ND 0.030 J ND
mg/L 04/14/20 0.041 0.1 1.10 ND ND ND ND ND ND 0.075 J ND
mg/L 10/07/20 0.041 0.1 1.30 ND ND ND 0.070 J ND ND 0.050 J ND
mg/L 05/10/21 0.041 0.1 1.10 ND ND ND ND ND ND 0.069 J ND
mg/L 10/06/21 0.041 0.1 0.74 ND ND ND ND ND ND 0.067 J ND
mg/L 05/17/22 0.041 0.1 0.65 0.041 J ND 0.042 J 0.059 J 0.12 0.082 J 0.12 ND
mg/L 10/10/22 0.041 0.1 --ND 0.102 J ND ND ND ND ND ND
mg/L 05/22/23 0.1 ----ND ND ND ND ND ND ND --
Nitrite as N mg/L 04/11/11 0.003 --ND ND --ND ND ND 0.0053 B ND 0.0038 J
mg/L 10/28/15 0.017 --ND ND 0.018 J ND ND ND ND ND ND
mg/L 04/05/16 0.017 --ND ND ND ND ND ND ND ND ND
mg/L 10/04/16 0.017 --ND ND ND ND ND ND ND ND ND
mg/L 04/03/17 0.017 --ND ND ND ND ND ND ND ND ND
mg/L 10/03/17 0.017 --ND ND ND ND ND ND ND ND ND
mg/L 05/23/18 0.017 --ND ND ND ND ND ND ND ND ND
mg/L 10/23/18 0.017 0.1 ND 0.033 J 0.042 J ND ND ND ND ND ND
mg/L 04/16/19 0.017 0.1 ND 0.087 J 0.020 J ND ND ND ND ND ND
mg/L 10/15/19 0.017 0.1 0.045 J 0.078 J 0.35 0.044 J 0.042 J 0.061 J 0.041 J 0.043 J ND
mg/L 04/14/20 0.017 0.1 ND ND ND ND ND ND ND ND ND
mg/L 10/07/20 0.017 0.1 ND ND 0.026 J ND ND ND ND ND ND
mg/L 05/10/21 0.017 0.1 ND 0.017 J 0.028 J ND ND ND ND ND ND
mg/L 10/06/21 0.017 0.1 ND ND 0.028 J ND ND ND ND ND ND
mg/L 05/17/22 0.017 0.1 0.018 J 0.021 J 0.020 J ND ND ND ND ND ND
Sulfate as SO4 mg/L 04/11/11 0.02 --9.7 J 6.4 J --2.1 J 2.1 J 15 J 35 J 4.5 J ND
mg/L 10/28/15 2.9 --7.1 J ND 3.0 J ND ND 8.8 J 17 J ND ND
mg/L 04/05/16 2.9 --7.5 J 3.1 J 3.1 J ND ND 7.2 J 14 J ND ND
mg/L 10/04/16 2.9 --8.4 J 3.3 J 3.3 J ND ND 8.7 J 3.2 J ND ND
mg/L 04/03/17 2.9 --7.0 J 3.3 J 3.1 J ND ND 8.0 J 3.1 J ND ND
mg/L 10/03/17 2.9 --6.2 J ND 4.0 J ND ND 7.3 J ND ND ND
mg/L 05/22/18 2.9 --5.9 J ND ND ND ND 6.8 J ND ND ND
mg/L 10/23/18 2.9 5 5.5 ND ND ND ND 8.9 ND ND ND
mg/L 04/16/19 2.9 5 12 2.9 J 3.4 J ND ND 7.0 ND ND ND
mg/L 10/15/19 2.9 5 11 ND 3.4 J ND ND 7.2 ND ND ND
mg/L 04/14/20 2.9 5 7.6 3.3 J 2.9 J ND ND 8.0 ND ND ND
mg/L 10/07/20 2.9 5 9.5 3.3 J 3.0 J ND ND 9.7 3.1 J ND ND
mg/L 05/10/21 2.9 5 15 1.8 J ND 0.29 J 0.85 J 7.0 0.34 J 0.52 J ND
mg/L 10/06/21 2.9 5 15 4.1 J 4.0 J ND ND 8.1 3.4 J ND ND
mg/L 05/17/22 2.9 5 9.3 3.2 J 3.2 J ND ND 7.0 3.4 J ND ND
mg/L 10/10/22 2.9 ----1.46 3.81 1.43 0.323 9.9 2.0 1.4 ND
mg/L 05/22/23 0.1 ----2.40 1.80 0.707 0.906 9.56 2.34 0.579 --
Biochemical Oxygen Demand mg/L 04/11/11 ----------------------
mg/L 10/28/15 2 --ND ND ND ND ND ND ND ND ND
mg/L 04/05/16 2 --ND ND ND ND ND ND ND ND ND
mg/L 10/04/16 2 --ND ND ND ND ND ND ND ND ND
mg/L 04/03/17 2 --ND ND ND ND ND ND ND ND ND
mg/L 10/03/17 2 --ND ND ND ND ND ND ND ND ND
mg/L 10/23/18 2 --------------------
mg/L 04/16/19 2 2 ND ND ND ND ND ND ND ND ND
mg/L 10/15/19 2 2 ------------------
mg/L 04/14/20 2 2 ND ND ND ND ND ND ND ND ND
mg/L 10/07/20 2 2 ND ND ND ND ND ND ND ND ND
mg/L 05/10/21 2 2 ------------------
mg/L 10/10/22 2 2 --ND ND ND ND ND ND ND --
mg/L 05/22/23 3 ----ND ND ND ND ND ND ND --
Chemical Oxygen Demand mg/L 04/11/11 ----------------------
mg/L 10/28/15 1 --12 35 48 10 10 12 31 10 ND
mg/L 04/05/16 10 --ND ND 10 ND ND ND 29 ND ND
mg/L 10/04/16 10 --ND 25 29 ND 10 ND 29 ND ND
mg/L 04/03/17 10 --ND 32 17 ND ND 17 32 ND ND
mg/L 10/03/17 10 --ND 17 ND ND ND ND 15 ND ND
mg/L 10/23/18 10 --------------------
mg/L 04/16/19 10 10 ND 30 ND ND ND ND 21 ND ND
mg/L 10/15/19 10 10 ------------------
mg/L 04/14/20 10 10 ND ND 16 ND ND ND 24 ND ND
mg/L 10/07/20 10 10 ND 28 11 ND 13 ND 22 ND ND
mg/L 05/10/21 10 10 ------------------
mg/L 10/10/22 10 10 --23 6.8 3.1 J 4.4 J 3.1 J 17.8 4.2 J --
mg/L 05/22/23 1.7 ----ND ND ND ND ND 6.3 ND --
Total Alkalinity as CaCO3 mg/L 04/11/11 12 --460 ND --26 88 43 330 18 ND
mg/L 10/28/15 14 --480 ND 44 40 1000 55 410 25 ND
mg/L 04/05/16 14 --530 19 47 24 94 46 410 26 ND
mg/L 10/04/16 14 --480 ND ND 33 100 44 440 16 ND
mg/L 04/03/17 14 --490 ND 58 37 91 45 440 19 ND
mg/L 10/03/17 14 --470 17 48 41 96 54 470 44 ND
mg/L 10/23/18 14 --------------------
mg/L 04/16/19 14 15 500 ND 24 17 79 34 430 ND ND
mg/L 10/15/19 14 15 ------------------
mg/L 04/14/20 14 15 420 ND 32 17 78 39 410 ND ND
mg/L 10/07/20 14 15 540 ND 46 41 93 65 460 21 ND
mg/L 05/10/21 14 15 ------------------
TABLE 8
Summary of Geochemical Parameters
Closed Randolph County Landfill, Permit No. 76-01
Detected Monitoring Constituent/Parameter Units Date Method Detection Limit
Upgradient Downgradient Wells BlanksPractical Quantatation Limit
1 of 5
September 2023 31404568.018
MW-5 MW-2 MW-3 MW-7 MW-8 MW-10S MW-10D MW-11S
TABLE 8
Summary of Geochemical Parameters
Closed Randolph County Landfill, Permit No. 76-01
Detected Monitoring Constituent/Parameter Units Date Method Detection Limit
Upgradient Downgradient Wells BlanksPractical Quantatation Limit
Total Organic Carbon mg/L 04/11/11 0.27 --1.6 6.4 --1.3 0.85 J 1.5 6.9 0.62 J ND
mg/L 10/28/15 0.34 --0.14 5.6 11 2.2 0.35 J 1.2 3.9 ND ND
mg/L 04/05/16 0.34 --ND 3.9 2.4 ND ND 1.3 4.7 0.36 J ND
mg/L 10/04/16 0.34 --1.8 6.2 4.0 3.7 0.94 J 1.6 6.1 0.43 J ND
mg/L 04/03/17 0.34 --1.7 2.9 2.2 2.9 0.79 J 1.3 6.5 0.44 J ND
mg/L 10/03/17 0.34 --1.1 5.9 2.5 3.8 1.3 2.0 7.1 ND ND
mg/L 10/23/18 0.34 --------------------
mg/L 04/16/19 0.34 1 6.9 7.8 2.5 9.2 2.9 5.3 15 1.7 ND
mg/L 10/15/19 0.34 1 ------------------
mg/L 04/14/20 0.34 1 0.53 J 2.7 4.6 0.58 J ND 0.36 J 4.3 ND ND
mg/L 10/07/20 0.54 1 1.7 6.0 2.2 1.9 0.91 J 1.3 6.3 ND ND
mg/L 05/10/21 0.54 1 ------------------
mg/L 05/22/23 0.3 ----4.93 1.96 J 4.38 1.47 J 3.26 17.4 1.01 J --
Nitrate/Nitrite as N mg/L 04/11/11 ----1.2 ND --3.3 1.9 ND ND 0.079 J ND
mg/L 10/28/15 ----1.00 ND 0.12 ND 0.16 ND 0.11 0.11 ND
mg/L 04/05/16 0.041 --1.1 B ND 0.13 B 0.047 B 0.13 B ND 0.1 B 0.09 B 0.072
mg/L 05/23/18 0.041 --1.0 ND 0.093 J ND 0.061 J 0.064 J 0.052 J 0.110 ND
mg/L 10/23/18 0.041 0.01 0.64 ND 0.046 J 0.052 J 0.053 J ND 0.078 J 0.14 ND
mg/L 04/16/19 0.041 0.1 0.82 0.30 ND ND 0.054 J 0.054 J ND 0.075 J ND
mg/L 10/15/19 0.041 0.1 0.97 ND 0.18 ND 0.14 0.044 J 0.051 J 0.073 J ND
mg/L 04/14/20 0.041 0.1 1.1 ND ND ND ND ND ND 0.075 J ND
mg/L 10/07/20 0.041 0.1 1.3 ND 0.063 J ND 0.07 J ND ND 0.050 J ND
mg/L 05/10/21 0.041 0.1 1.1 ND ND ND ND ND ND 0.069 J ND
mg/L 10/06/21 0.041 0.1 0.74 ND ND ND ND ND ND 0.067 J ND
mg/L 05/17/22 0.041 0.1 0.66 0.06 J 0.048 J 0.042 J 0.059 J 0.120 0.082 J 0.120 ND
Ethane mg/L 04/11/11 0.0015 --ND ND --ND ND ND ND ND ND
mg/L 10/28/15 0.00047 --ND ND ND ND ND ND ND ND ND
mg/L 04/05/16 0.00047 --ND ND ND ND ND ND ND ND ND
mg/L 10/04/16 0.001 --ND ND ND ND ND ND 0.0015 ND ND
mg/L 04/03/17 0.00005 --ND ND ND 0.00053 ND ND 0.0013 ND ND
mg/L 10/03/17 0.000006 --ND 0.0005 ND 0.00072 ND 0.00056 0.0012 ND ND
mg/L 05/22/18 0.000006 --ND ND ND 0.00053 ND ND 0.0016 ND ND
mg/L 10/23/18 0.000032 0.0002 ND 0.00031 ND 0.00065 ND 0.00063 0.0014 ND ND
mg/L 04/16/19 0.0002 0.0002 ND ND ND 0.00044 B ND 0.00023 B 0.0013 B ND ND
mg/L 10/15/19 0.000006 0.0002 ND 0.00053 ND 0.00066 ND 0.00032 0.0012 ND ND
mg/L 04/14/20 0.000006 0.0002 ND ND ND 0.00026 ND ND 0.00078 ND ND
mg/L 10/07/20 0.000075 0.0002 ND 0.00034 ND 0.0012 ND 0.00062 0.0017 ND ND
mg/L 05/10/21 0.000075 0.0002 ND 0.00048 J ND 0.00066 J ND 0.00027 J 0.0020 0.00025 J ND
mg/L 10/06/21 0.000075 0.0002 0.00022 J 0.00031 J ND 0.0017 ND 0.00081 J 0.0016 0.00035 J ND
mg/L 05/17/22 0.000170 0.0010 --0.00051 J 0.00021 J 0.00077 J ND ND 0.0013 0.00034 J ND
mg/L 10/10/22 0.000170 0.0010 --ND ND ND ND 0.0012 0.0006 ND ND
mg/L 05/22/23 0.000170 0.0010 --ND ND ND ND ND ND ND ND
Ethene mg/L 04/11/11 0.0016 --ND ND --ND ND ND ND ND ND
mg/L 10/28/15 0.00062 --ND ND ND ND ND ND ND ND ND
mg/L 04/05/16 0.00062 --ND ND ND ND ND ND ND ND ND
mg/L 10/04/16 0.001 --ND ND ND ND ND ND ND ND ND
mg/L 04/03/17 0.00007 --ND ND ND ND ND ND 0.00055 ND ND
mg/L 10/03/17 0.00002 --ND ND ND ND ND ND 0.00056 ND ND
mg/L 05/22/18 0.00002 --ND ND ND ND ND ND 0.00078 ND ND
mg/L 10/23/18 0.0000064 0.0002 ND ND ND ND ND ND 0.00074 ND ND
mg/L 04/16/19 0.0002 0.0002 ND ND ND ND ND ND 0.00075 ND ND
mg/L 10/15/19 0.000012 0.0002 ND ND ND ND ND ND 0.00062 ND ND
mg/L 04/14/20 0.000012 0.0002 ND ND ND ND ND ND 0.00048 ND ND
mg/L 10/07/20 0.00012 0.0002 ND ND ND ND ND ND 0.00071 ND ND
mg/L 05/10/21 0.00012 0.0002 ND 0.00031 J ND ND ND ND 0.00089 J ND ND
mg/L 10/06/21 0.00012 0.0002 ND ND ND ND ND ND 0.0011 0.00039 J ND
mg/L 05/17/22 0.00024 0.0001 --0.00076 J 0.00036 J 0.00027 J ND ND 0.0012 ND ND
mg/L 10/10/22 0.00024 0.0001 --ND ND ND ND ND ND ND ND
mg/L 05/22/23 0.00024 0.0001 --ND ND ND ND ND ND ND ND
Methane mg/L 04/11/11 0.00049 --ND ND --1.62 0.64 J ND 4.3 ND ND
mg/L 10/28/15 0.00044 --0.00452 0.408 ND 5.56 ND 1.38 ND 0.000608 J ND
mg/L 04/05/16 0.00044 --ND 0.0238 ND 1.13 ND 0.0208 ND ND ND
mg/L 10/04/16 0.0025 --0.0054 0.25 0.052 6.30 0.0065 0.43 0.13 0.034 ND
mg/L 04/03/17 0.00019 --ND 0.26 0.84 5.60 ND 0.18 0.094 0.0025 ND
mg/L 10/03/17 0.00003 --0.0036 0.95 0.10 5.40 ND 2.1 0.072 0.22 ND
mg/L 05/22/18 0.00003 --ND 0.20 0.023 4.8 ND 0.24 0.098 0.00057 ND
mg/L 10/23/18 0.00061 0.0005 0.0010 0.83 0.022 5.5 ND 1.2 0.084 0.00051 ND
mg/L 04/16/19 0.0005 0.0005 0.022 0.043 0.0016 4.3 ND 0.40 0.092 ND ND
mg/L 10/15/19 0.00007 0.0005 0.0028 0.53 0.60 5.7 ND 1.7 0.10 0.0001 ND
mg/L 04/14/20 0.00007 0.0005 0.0023 0.096 0.036 2.4 ND 0.24 0.065 0.0018 ND
mg/L 05/10/21 0.0025 0.0005 0.0020 J 0.49 0.54 2.9 0.0039 J 0.60 0.14 0.011 ND
mg/L 10/06/21 0.0025 0.0005 ND 0.16 0.22 5.4 0.0023 J 1.9 0.12 ND ND
mg/L 05/17/22 0.0020 0.0050 --0.17 ND 1.6 ND ND 0.05 ND ND
mg/L 10/10/22 0.00044 --ND ND 0.014 2.1 ND 2.6 0.03 0.063 ND
mg/L 05/22/23 0.0025 0.0005 --0.0393 0.0145 0.864 ND 0.263 0.0178 0.0037 ND
Hexanoic Acid mg/L 04/11/11 0.00007 0.0005 ND ND --ND ND ND ND ND ND
mg/L 10/28/15 0.00007 0.0005 ND ND ND ND ND ND ND ND ND
mg/L 04/05/16 0.00007 0.0005 ND ND ND ND ND ND ND ND ND
mg/L 10/04/16 0.00007 0.0005 ND ND ND ND ND ND ND ND ND
mg/L 04/03/17 0.00007 0.0005 ND ND ND ND ND ND ND ND ND
mg/L 10/03/17 0.00007 0.0005 ND ND ND ND ND ND ND ND ND
mg/L 04/16/19 0.26 0.5 ND ND ND ND ND ND ND ND ND
mg/L 04/14/20 0.26 0.5 ND --ND ND ND ND ND ND ND
mg/L 10/07/20 0.26 0.5 ND ND ND ND ND ND ND ND ND
mg/L 05/22/23 0.058 ----ND ND ND ND ND ND ND --
iso-Hexanoic Acid mg/L 04/11/11 0.00007 0.0005 ND ND --ND ND ND ND ND ND
mg/L 10/28/15 0.00007 0.0005 ND ND ND ND ND ND ND ND ND
mg/L 04/05/16 0.00007 0.0005 0.64 0.58 0.55 ND ND ND ND ND ND
mg/L 10/04/16 0.00007 0.0005 ND 0.58 ND ND ND ND ND ND ND
mg/L 04/03/17 0.00007 0.0005 ND ND ND ND ND ND ND ND ND
mg/L 10/03/17 0.00007 0.0005 ND ND ND ND ND ND ND ND ND
mg/L 04/16/19 0.44 0.5 ND ND ND ND ND ND ND ND ND
mg/L 04/14/20 0.44 0.5 ND --ND ND ND ND ND ND ND
mg/L 10/07/20 0.44 0.5 ND ND ND ND ND ND ND ND ND
mg/L 05/22/23 0.056 ----ND ND ND ND ND ND ND --
iso-Pentanoic Acid mg/L 04/11/11 0.00007 0.0005 ND ND --ND ND ND ND ND ND
mg/L 10/28/15 0.00007 0.0005 ND ND ND ND ND ND ND ND ND
mg/L 04/05/16 0.00007 0.0005 ND ND ND ND ND ND ND ND ND
mg/L 10/04/16 0.00007 0.0005 ND ND ND ND ND ND ND ND ND
mg/L 04/03/17 0.00007 0.0005 ND ND ND ND ND ND ND ND ND
mg/L 10/03/17 0.00007 0.0005 ND ND ND ND ND ND ND ND ND
mg/L 04/16/19 0.18 0.2 ND ND ND ND ND ND ND ND ND
mg/L 04/14/20 0.18 0.2 ND --ND ND ND ND ND ND ND
mg/L 10/07/20 0.18 0.2 ND ND ND ND ND ND ND ND ND
2 of 5
September 2023 31404568.018
MW-5 MW-2 MW-3 MW-7 MW-8 MW-10S MW-10D MW-11S
TABLE 8
Summary of Geochemical Parameters
Closed Randolph County Landfill, Permit No. 76-01
Detected Monitoring Constituent/Parameter Units Date Method Detection Limit
Upgradient Downgradient Wells BlanksPractical Quantatation Limit
Pentanoic Acid mg/L 04/11/11 0.00007 0.0005 ND ND --ND ND ND ND ND ND
mg/L 10/28/15 0.00007 0.0005 ND ND ND ND ND ND ND ND ND
mg/L 04/05/16 0.00007 0.0005 ND ND ND 0.26 ND ND ND ND ND
mg/L 10/04/16 0.00007 0.0005 ND ND ND ND ND ND ND ND ND
mg/L 04/03/17 0.00007 0.0005 0.18 J ND ND ND ND ND ND ND ND
mg/L 10/03/17 0.00007 0.0005 ND ND ND ND ND ND ND ND ND
mg/L 04/16/19 0.14 0.2 ND ND ND ND ND ND ND ND ND
mg/L 04/14/20 0.14 0.2 ND --ND ND ND ND ND ND ND
ug/L 10/07/20 0.14 0.2 ND ND ND ND ND ND ND ND ND
mg/L 05/22/23 0.056 ----ND ND ND ND ND ND ND --
Carbon dioxide mg/L 04/11/11 2 --43 167 --307 62.3 ND 79.0 53.2 ND
mg/L 10/28/15 0.21 --237 295 89.7 1030 166 967 129 171 ND
mg/L 04/05/16 0.21 --73.5 113 52.6 355 106 179 67.4 94.3 0.4
mg/L 10/04/16 0.005 --63 120 75 560 110 190 320 99 ND
mg/L 04/03/17 0.24 --61 120 48 430 74 150 250 57 ND
mg/L 10/03/17 0.51 --120 200 80 520 110 280 340 79 ND
mg/L 05/22/18 0.51 --57 110 92 540 120 190 420 110 ND
mg/L 10/23/18 0.1 5.0 68 180 110 480 87 290 390 100 ND
mg/L 04/16/19 0.1 5.0 81 91 55 490 73 260 440 97 ND
mg/L 10/15/19 0.1 5.0 88 240 80 600 100 290 400 110 ND
mg/L 04/14/20 0.1 5.0 70 160 63 370 92 200 360 110 ND
mg/L 10/07/20 2.5 5.0 37 85 40 233 64 137 186 48 ND
mg/L 05/10/21 2.5 5.0 35 56 47 172 38 115 67 12 ND
mg/L 10/06/21 2.5 5.0 84 161 65 446 96 326 354 111 ND
mg/L 05/17/22 2.5 18 --106 55 258 64 143 229 72 ND
mg/L 10/10/22 0.21 ----142 74.2 237 80.5 230 256 81.3 ND
mg/L 05/22/23 0.21 ----69.9 42.9 228 24.1 166 220 39.2 ND
Pyruvic Acid mg/L 04/11/11 0.1 5.0 ND ND --ND ND ND ND ND ND
mg/L 10/28/15 0.012 --ND ND ND ND ND ND ND ND ND
mg/L 04/05/16 0.012 --ND 0.023 J ND 0.018 J 0.017 J 0.02 J ND 0.014 J ND
mg/L 10/04/16 0.012 --ND ND ND ND ND ND ND ND ND
mg/L 04/03/17 0.012 --ND ND ND 0.019 J ND ND ND ND ND
mg/L 10/03/17 0.1 5.0 ND ND ND ND ND ND ND ND ND
mg/L 04/16/19 0.021 0.07 ND ND ND ND ND ND ND ND ND
mg/L 04/14/20 0.021 0.07 ND --ND ND ND ND ND ND ND
mg/L 10/07/20 0.021 0.07 ND ND ND ND ND ND ND ND ND
mg/L 05/22/23 0.06 ----ND ND ND ND ND ND ND --
mg/L 10/04/16 0.1 5.0 ND ND ND ND ND ND 8.8 ND ND
mg/L 04/03/17 0.1 5.0 0.32 ND ND ND ND ND 7.8 ND ND
mg/L 10/03/17 0.1 5.0 ND ND ND ND ND ND 9.3 ND ND
mg/L 04/16/19 0.18 0.2 ND ND ND ND ND ND 6.9 ND ND
mg/L 04/14/20 0.18 0.2 ND --ND ND ND ND 5.2 ND ND
mg/L 10/07/20 0.18 0.2 ND ND ND ND ND ND 5.1 ND ND
mg/L 05/22/23 0.12 0.2 --1.1 1.1 1.0 1.1 8.5 8.4 1.2 ND
Propionic Acid mg/L 04/11/11 0.1 5.0 ND ND --ND ND ND ND ND ND
mg/L 10/28/15 0.1 5.0 ND ND ND ND ND ND ND ND ND
mg/L 04/05/16 0.1 5.0 ND ND ND ND ND ND ND ND ND
mg/L 10/04/16 0.1 5.0 ND ND ND ND ND ND ND ND ND
mg/L 10/04/16 0.1 5.0 ND ND ND ND ND ND ND ND ND
mg/L 04/03/17 0.1 5.0 ND ND ND ND ND ND ND ND ND
mg/L 10/03/17 0.1 5.0 ND 0.20 0.60 0.21 ND 0.20 ND 0.22 ND
mg/L 04/16/19 0.065 0.1 ND ND ND ND ND ND ND ND ND
mg/L 04/14/20 0.065 0.1 ND --ND ND ND ND ND ND ND
mg/L 10/07/20 0.065 0.1 ND ND ND ND ND ND ND ND ND
mg/L 05/22/23 0.053 ----0.19 J 0.19 J 0.17 J 0.19 J 1.7 J 1.7 J 0.24 J --
Butyric Acid mg/L 04/11/11 0.1 5.0 ND ND --ND ND ND ND ND ND
mg/L 10/28/15 0.1 5.0 ND ND ND ND ND ND ND ND ND
mg/L 04/05/16 0.1 5.0 ND ND ND ND ND ND ND ND ND
mg/L 10/04/16 0.1 5.0 ND ND ND ND ND ND ND ND ND
mg/L 04/03/17 0.1 5.0 ND ND ND 0.019 J ND ND ND ND ND
mg/L 04/03/17 0.1 5.0 ND ND ND ND ND ND ND ND ND
mg/L 10/03/17 0.1 5.0 ND ND ND ND ND ND ND ND ND
mg/L 04/16/19 0.089 0.1 ND ND ND ND ND ND ND ND ND
mg/L 04/14/20 0.089 0.1 ND --ND ND ND ND ND ND ND
mg/L 10/07/20 0.089 0.1 ND ND ND ND ND ND ND ND ND
mg/L 05/22/23 0.058 ----ND ND ND ND ND ND ND ND
Formic Acid mg/L 05/22/23 0.055 ----5 5.4 5.6 5.2 51 4.9 6.1 --
Hydrogen nM 04/11/11 0.60 --2.7 0.75 --0.93 0.74 2.0 1.8 0.90 --
nM 10/28/15 0.088 --3.7 2.8 2.3 3.1 3.5 2.6 3.0 2.9 --
nM 04/05/16 0.088 --2.6 2.0 1.9 1.5 3.2 2.5 2.3 3.2 --
nM 10/04/16 0.60 --1.7 1.8 1.9 4.1 1.8 1.8 1.5 1.8 --
nM 04/03/17 0.075 --2.4 2.2 2.1 3.3 2.1 2.1 1.9 6.0 --
nM 10/03/17 0.16 ----9.0 1.8 25 1.6 2.0 22 2.1 ND
nM 05/22/18 0.16 --4.5 4.8 4.4 4.8 4.9 4.8 4.9 6.9 ND
nM 10/23/18 0.65 1.0 --2.0 2.2 1.7 2.2 1.8 1.9 2.1 --
nM 04/16/19 0.75 1.0 1.0 ND 1.3 ND 1.4 1.2 1.2 1.2 --
nM 10/15/19 0.75 1.0 1.2 1.6 --1.7 1.8 1.9 1.7 2.0 --
nM 04/14/20 0.75 1.0 1.9 1.5 96 1.5 1.6 3.6 1.7 20 --
nM 10/07/20 0.49 1.0 0.87 J 0.95 J 0.96 J 0.69 J 0.68 J 0.86 J 0.75 J 0.98 J --
nM 05/10/21 0.49 1.9 2.7 J 5.9 3.2 J 1.6 J 3.5 J 2.6 1.7 J 0.86 J --
nM 10/06/21 0.49 1.9 --1.2 J 0.92 J 0.87 J 0.94 J 0.73 J 1.0 J 58 --
nM 05/17/22 0.49 1.9 --5.9 0.75 J 25 1.50 J 43 40 56 --
nM 10/10/22 0.49 1.9 --1.2 J 1.3 J 1.2 J 1.10 J 23 4.1 0.85 J --
3 of 5
September 2023 31404568.018
MW-5 MW-2 MW-3 MW-7 MW-8 MW-10S MW-10D MW-11S
TABLE 8
Summary of Geochemical Parameters
Closed Randolph County Landfill, Permit No. 76-01
Detected Monitoring Constituent/Parameter Units Date Method Detection Limit
Upgradient Downgradient Wells BlanksPractical Quantatation Limit
Ferrous Iron mg/L 04/11/11 ----------------------
(field)mg/L 10/28/15 ----ND 1.2 ND 2.2 --0.6 ND ND --
mg/L 04/05/16 ----------------------
(laboratory)mg/L 10/04/16 0.50 --ND ND 0.51 1.9 ND ND 7.5 ND --
(laboratory)mg/L 04/03/17 0.046 --ND 0.67 1.8 1.5 ND ND 7.0 ND --
(laboratory)mg/L 10/03/17 0.031 --ND 3.6 ND 3.1 ND ND 5.5 ND --
(laboratory)mg/L 05/22/18 0.5 --ND 0.53 ND 1.4 ND ND 6.5 ND --
(laboratory)mg/L 10/23/18 0.040 0.5 ND 1.2 ND 2.4 ND ND 5.6 ND --
(laboratory)mg/L 04/16/19 0.12 0.5 ND ND ND 1.1 ND ND 5.7 ND --
(laboratory)mg/L 10/15/19 0.05 0.1 ND ND ND 2.1 ND ND ND ND --
(laboratory)mg/L 04/14/20 0.05 0.1 0.95 ND 1.0 1.7 ND ND 6.7 ND --
(laboratory)mg/L 10/07/20 0.02 0.1 0.03 J 1.8 ND 3.1 ND 0.17 2.8 ND --
(laboratory)mg/L 10/06/21 0.02 0.1 ND 1.3 ND 3.0 ND 0.35 4.4 ND --
(laboratory)mg/L 05/17/22 0.01 0.1 --1.4 0.06 1.6 ND 0.14 5.9 ND --
(laboratory)mg/L 10/10/22 0.01 0.1 --0.1 0.06 0.077 ND ND 0.5 ND --
(laboratory)mg/L 05/22/23 0.014 0.1 --ND 0.024 J 0.055 0.021 J ND 0.461 ND --
pH (field)S.U.04/11/11 ----6.63 4.52 --4.61 5.80 5.45 6.35 5.08 --
S.U.10/28/15 ----6.71 4.68 5.62 4.70 5.99 5.29 6.72 5.33 --
S.U.04/05/16 ----6.66 4.59 5.63 4.73 5.82 5.05 6.59 5.48 --
S.U.10/04/16 ----6.17 4.18 5.93 4.49 6.27 5.00 5.93 4.83 --
S.U.04/03/17 ----6.90 4.47 6.09 4.99 6.16 5.25 6.14 4.99 --
S.U.10/03/17 ----6.75 4.57 5.89 4.60 5.81 5.33 6.08 4.96 --
S.U.05/22/18 ----6.93 4.58 5.61 4.83 5.93 5.28 6.21 5.22 --
S.U.10/23/18 ----6.90 5.09 5.81 5.13 6.10 5.55 6.28 5.44 --
S.U.04/16/19 ----7.05 4.95 6.26 4.93 6.29 5.41 6.14 5.61 --
S.U.10/15/19 ----6.98 5.08 6.44 5.06 6.08 5.55 6.21 5.77 --
S.U.04/14/20 ----6.97 4.70 5.89 4.94 5.95 5.56 6.43 5.48 --
S.U.10/07/20 ----6.79 5.07 5.56 4.98 5.53 5.47 6.22 5.04 --
S.U.05/10/21 ----7.06 4.61 6.04 4.74 6.16 4.98 6.12 5.51 --
S.U.10/06/21 ----7.04 5.10 5.94 4.79 6.07 5.47 6.27 4.88 --
S.U.05/17/22 ----6.92 4.65 5.70 5.09 5.88 5.57 6.31 5.60 --
S.U.05/25/22 ------4.59 --------------
S.U.10/10/22 ----Dry 4.95 5.95 5.16 6.06 5.36 6.08 5.67 --
S.U.05/23/23 ------5.24 6.02 5.30 5.95 5.83 6.31 5.42 --
Specific Conductivity (field)uS/cm 04/11/11 ----884 132 --112 214 267 1665 71 --
uS/cm 10/28/15 ----794 186 106 141 230 263 1551 64.8 --
uS/cm 04/05/16 ----902 81 116 104 226 214 1614 72 --
uS/cm 10/04/16 ----843 91 109 148 232 193 1420 79 --
uS/cm 04/03/17 ----715 104.8 123 108 181 197 1276 77.1 --
uS/cm 10/03/17 ----811 145 139 125 232 194 1160 95 --
uS/cm 05/22/18 ----734 82.5 115.4 125.2 249.7 186.8 1314 75.9 --
uS/cm 10/23/18 ----812 102.4 128.6 105.7 223.4 279.2 1142 70.5 --
uS/cm 04/16/19 ----912 51.6 115.5 90.7 193.2 184.2 1364 67.0 --
uS/cm 10/15/19 ----996 146 188 116 238 283 1263 95.2 --
uS/cm 04/14/20 ----983 90.3 102 102 192 140 1157 63.1 --
uS/cm 10/07/20 ----947 103 129 116 203 207 1012 70.4 --
uS/cm 05/10/21 ----986 82 127 76 152 166 1291 49.7 --
uS/cm 10/06/21 ----751 145 114 91 176 240 98.6 54.9 --
uS/cm 05/17/22 ----825 99.0 124 70 161 181 1015 56.9 --
uS/cm 05/25/22 ------129 --------------
uS/cm 10/10/22 ----Dry 202 104 135 190 329 1128 83.8 --
uS/cm 05/23/23 ------73 142 92 147 243 1367 68.2 --
Temperature (field)Celsius 04/11/11 ----16.6 15.5 --16.4 14.7 15.4 16.0 16.9 --
Celsius 10/28/15 ----18.5 18.7 16.4 17.3 16.9 17.1 16.0 18.4 --
Celsius 04/05/16 ----14.9 15.2 14.6 16.2 13.4 12.7 13.1 16.1 --
Celsius 10/04/16 ----17.3 16.3 17.5 17.3 18.3 17.0 16.1 18.0 --
Celsius 04/03/17 ----15.6 16.6 15.1 16.3 14.0 15.9 16.1 17.2 --
Celsius 10/03/17 ----19.8 21.6 20.3 18.1 17.5 16.8 16.2 21.2 --
Celsius 05/22/18 ----20.3 16.4 16.8 17.4 15.9 15.4 16.4 17.0 --
Celsius 10/23/18 ----17.9 15.6 15.4 16.5 16.8 15.5 15.7 17.6 --
Celsius 04/16/19 ----16.3 15.7 13.7 17.6 14.3 14.0 14.4 15.8 --
Celsius 10/15/19 ----17.5 17.0 17.2 17.2 17.7 17.4 17.1 19.3 --
Celsius 04/14/20 ----16.2 13.7 13.9 16.0 14.1 14.6 15.1 16.9 --
Celsius 10/07/20 ----17.2 17.3 17.1 18.5 17.9 16.3 16.8 19.5 --
Celsius 05/10/21 ----17.8 16.3 14.9 16.5 14.3 14.8 15.1 16.5 --
Celsius 10/06/21 ----18.4 17.2 17.2 17.6 17.6 16.8 16.6 18.9 --
Celsius 05/17/22 ----19.9 16.1 15.4 18.2 14.5 15.8 15.6 17.3 --
Celsius 05/25/22 ------15.0 --------------
Celsius 10/10/22 ----Dry 16.1 14.3 17.1 16.4 16.2 16.2 18.5 --
Celsius 05/23/23 ------15.5 15.0 15.8 15.1 15.2 15.5 16.1 --
4 of 5
September 2023 31404568.018
MW-5 MW-2 MW-3 MW-7 MW-8 MW-10S MW-10D MW-11S
TABLE 8
Summary of Geochemical Parameters
Closed Randolph County Landfill, Permit No. 76-01
Detected Monitoring Constituent/Parameter Units Date Method Detection Limit
Upgradient Downgradient Wells BlanksPractical Quantatation Limit
Turbidity (field)NTU 04/11/11 ----4.39 91.4 --16.7 34.7 5.35 19.9 2.76 --
NTU 10/28/15 ----3.98 50.5 85.5 1.29 14.0 1.33 15.6 2.42 --
NTU 04/05/16 ----17.9 44.0 48.5 17.3 4.97 1.23 2.97 5.73 --
NTU 10/04/16 ----3.10 42.4 201 1.24 1.05 1.41 28.9 7.17 --
NTU 04/03/17 ----1.14 67.9 81.0 2.59 1.46 1.80 13.4 10.8 --
NTU 10/03/17 ----2.19 21.8 57.3 2.60 4.42 6.05 2.81 6.96 --
NTU 05/22/18 ----2.70 60.0 96.7 9.00 1.69 2.20 2.30 8.73 --
NTU 10/23/18 ----7.90 65.9 129 0.80 2.93 0.93 0.62 16.0 --
NTU 04/16/19 ----0.83 167 78.5 8.19 3.44 0.80 0.45 9.06 --
NTU 10/15/19 ----1.35 145 50.3 0.40 7.68 0.74 0.38 2.09 --
NTU 04/14/20 ----0.61 65.4 35.4 2.24 3.31 1.25 1.33 4.09 --
NTU 10/07/20 ----4.24 78.9 56.7 0.01 5.36 2.37 2.12 8.97 --
NTU 05/10/21 ----0.48 34.6 48.0 0.73 8.76 0.51 0.54 2.62 --
NTU 10/06/21 ----7.79 21.0 77.2 1.44 4.33 3.52 1.29 3.39 --
NTU 05/17/22 ----9.79 79.5 39.2 6.44 2.47 0.77 1.26 2.29 --
NTU 05/25/22 ------35.5 --------------
NTU 10/10/22 ----Dry 47.1 110 1.82 2.95 0.64 7.07 0.21 --
NTU 05/23/23 ------99.4 45.5 0.20 9.02 0.20 0.15 6.72 --
Dissolved Oxygen (field)mg/L 04/11/11 ----2.69 0.97 --1.10 4.24 1.67 3.20 2.07 --
mg/L 10/28/15 ----2.16 1.38 2.95 0.71 3.60 1.55 3.92 1.78 --
mg/L 04/05/16 ----3.43 0.85 4.01 0.85 3.39 2.24 4.80 2.27 --
mg/L 10/04/16 ----3.55 1.23 2.20 0.99 3.81 1.48 0.45 1.99 --
mg/L 04/03/17 ----5.94 0.97 3.23 0.82 5.60 2.53 0.81 3.72 --
mg/L 10/03/17 ----3.98 0.43 2.27 0.78 4.80 0.52 1.66 2.12 --
mg/L 05/22/18 ----4.71 1.02 2.34 0.39 1.78 0.87 0.68 3.33 --
mg/L 10/23/18 ------0.34 1.23 0.42 2.45 0.42 0.56 1.72 --
mg/L 04/16/19 ----1.54 0.26 4.03 0.32 2.41 0.63 0.33 2.18 --
mg/L 10/15/19 ----1.44 0.33 4.89 0.40 3.60 0.31 0.38 0.95 --
mg/L 04/14/20 ----4.88 0.55 1.41 0.82 2.31 1.47 0.35 1.99 --
mg/L 10/07/20 ----2.53 0.26 0.68 0.26 2.34 1.27 0.42 1.64 --
mg/L 05/10/21 ----2.67 3.03 1.09 0.26 0.86 1.10 0.40 1.46 --
mg/L 10/06/21 ----3.60 0.35 2.36 0.81 1.36 1.15 0.83 1.92 --
mg/L 05/17/22 ----4.29 1.49 1.41 0.99 1.69 4.10 0.96 3.07 --
mg/L 05/25/22 ------0.61 --------------
mg/L 10/10/22 ----Dry 0.92 0.99 1.39 3.50 0.24 0.21 0.62 --
mg/L 05/23/23 ------0.49 1.92 0.37 1.75 0.82 0.26 2.10 --
ORP (field)mV 04/11/11 ----150 237 --238 167 158 119 179 --
mV 10/28/15 ----11.0 90.0 199 137 178 115 99.4 178 --
mV 04/05/16 ----204 296 202 188 193 193 140 177 --
mV 10/04/16 ----220 304 60.2 196 90.0 247 8.6 280 --
mV 04/03/17 ----211 160 110 125 202 139 111 149 --
mV 10/03/17 ----110 84.1 81.4 126 118 117 233 79.8 --
mV 05/22/18 ----172 202 221 142 230 144 -3.8 221 --
mV 10/23/18 ------148 121 138 133 139 -0.8 179 --
mV 04/16/19 ----147 398 294 123 348 96.2 -5.0 382 --
mV 10/15/19 ----277 151 330 144 358 113 160 211 --
mV 04/14/20 ----95.8 269 65.2 57.2 183 304 1.21 243 --
mV 10/07/20 ----10.9 92.8 -196 119.8 -24.3 189 10.4 -123 --
mV 05/10/21 ----225 74.5 24.7 58.7 243 147 -22.1 196 --
mV 10/06/21 ----152 74.1 54.4 172 176 130 24.8 295 --
mV 05/17/22 ----179 160 55.5 174 123 45 -7.1 187 --
mV 05/25/22 ------180 --------------
mV 10/10/22 ----Dry 86.6 68.2 123 124.9 126.9 17.0 157.1 --
mV 05/23/23 -------302 -64.2 -318 -29.0 -341 -270 -5.1 --
Notes:ug/L =micrograms per liter
mg/L = milligrams per liter
ND =Not detected at the stated reporting limit for data before October 2007 and not detected at the laboratory detection limit for data from October 2007 forward
NM =Not measured
J =estimated concentration
B =Blank-qualified result
U=Compound was analyzed for but not detected
-- =no data available
# =EPA Action Level
* =EPA Secondary MCL
Blanks =field, trip and method blanks
Bold Only =
Shaded and Bold =and EPA MCL
NC 2L =North Carolina 2L Groundwater Standard
EPA MCL =US Environmental Protection Agency Maximum Contaminant Level
SWS Reporting Limit =NCPQL or lab-specific reporting limit prior to October 2007 and NCSWSL starting in October 2007
Wells MW-4, MW-A1, MW-A2, and MW-A3 are not sampled as part of the compliance network.
1)Well MW-3 went dry before hydrogen could be collected during the October 2019 event.
2)The following dilutions were noted for the May 2023 event: chloride MW-10D (4x); carbon dioxide (20x) all sampling points; hydrogen (2x) MW-2, -7, -8, -11S; ferrous iron (5x) MW-10D
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September 2023 31404568.018
MW-5 MW-2 MW-3 MW-6 MW-7 MW-8 MW-9 MW-10S MW-10D MW-11S MW-11D
1.8 ND ND --------ND
1.9 ND ND --------ND1.3 ND ND --------ND2.0 ND ND --------ND1.3 ND ND --------ND2.0 ND ND ND ND ND ND ND1.3 ND ND --------ND1.9 ND ND --------ND1.3 ND ND --------ND1.4 ND ND --------ND1.1 ND ND --------ND1.4 ND ND --------ND
1.4 ND ND ND ND ND --ND
1.4 ND ND ND 0.42 J ND --ND1.4 ND ND ND ND ND --ND1.3 ND ND ND ND ND --ND
1.2 0.50 J ND --ND
17 ND ND --------ND13NDND--------ND21NDND--------ND
13 ND ND --------ND13NDND--------ND17NDND--------ND20NDND--------ND26NDND--------ND31NDND--------ND39NDND--------ND15.6 ND ND --------ND35.6 ND ND --------ND12.8 ND ND --------ND6.1 ND ND --------ND13.5 ND ND --------ND
16.4 ND ND --------ND
12 ND ND --------ND
7.8 1.7 J 2.5 J --------ND152.6 J 1.4 J --------ND6.8 2.5 J 3.0 J --------ND112.6 J 1.1 J --------ND6.9 2.4 J 2.7 J --------ND123.9 J 1.5 J --------ND
13 5.6 1.9 J 26 23 ND ND ND
6.6 5.7 0.88 J --------ND6.9 1.0 J --------ND
6.6 1.3 J --------ND9.8 0.80 J --------ND
18 1.2 J ND 3.1 J 11 0.90 J 59 12 ND ND ND6.7 1.9 J ND 2.0 J 6.8 1.4 J 23 7.5 ND --ND100.81 J 21 8.7 ND --ND9.8 2.4 J 0.46 J 2.1 J 10 0.86 J 36 10 ND --ND190.40 J 3.6 J 1.9 J 12 1.2 J 57 7.3 ND --ND7.3 1.5 J ND 1.2 J 8.7 0.50 J 21 7.1 ND --ND142.8 ND 1.1 5.5 0.53 J 43 8.0 ND --ND276.3 ND --ND21ND4.2 1.2 13 0.96 J 71 5.2 ND --ND100.96 J ND ND 8.7 0.42 J 18 3.0 ND --ND8.6 2.5 1.8 0.58 J 7.4 0.70 J 36 3.6 ND --ND220.69 J ND --ND111.2 ND ND 13 ND 49 3.5 ND --ND132.6 1.8 ND 7.9 ND 17 2.8 ND --ND110.46 J ND 0.9 J 7.5 0.74 J 44 2.6 J 0.349 J --ND38.9 2.21 J ND --ND
Downgradient Wells BlanksDetected Monitoring Constituent/Parameter Units Date Detection Reporting Well
1 of 3
September 2023 31404568.018
MW-5 MW-2 MW-3 MW-6 MW-7 MW-8 MW-9 MW-10S MW-10D MW-11S MW-11D
Downgradient Wells BlanksDetected Monitoring Constituent/Parameter Units Date Detection Reporting Well
Tetrachloroethene ug/L 09/22/94 ----5 ND ----ND ND ND ND --------NDNC 2L = 0.7 ug/L ug/L 11/08/94 ----5 ND ----ND ND ND ND --------NDEPA MCL = 5 ug/L ug/L 01/18/95 ----5 ND ----ND ND ND ND --------NDug/L 04/23/96 ----5 ND ----ND ND ND ND --------NDug/L 06/17/97 ----5 ND ----ND ND ND ND --------NDug/L 10/16/97 ----5 ND ----ND ND ND ND --------NDug/L 04/21/98 ----5 ND ----ND ND ND ND --------NDug/L 04/07/99 ----5 ND ----ND ND ND ND --------NDug/L 10/13/99 ----5 ND ----ND ND ND ND --------NDug/L 04/05/00 ----5 ND ----ND ND ND ND --------NDug/L 10/25/00 ----5 ND ----ND ND ND ND --------NDug/L 04/04/01 ----5 ND ----ND ND ND ND --------NDug/L 04/08/02 ----5 ND ND --ND ND ND ND --------NDug/L 10/21/02 ----5 ND ND --ND ND ND ND --------NDug/L 04/14/03 ----5 ND ND --ND ND ND ND --------NDug/L 10/01/03 ----5 ND ND --ND ND ND ND --------NDug/L 04/05/04 ----5 ND ND --ND ND ND ND --------NDug/L 10/18/04 ----5 ND ND --ND ND ND ND --------NDug/L 04/07/05 ----5 ND ND --ND ----------------ug/L 10/06/05 ----5 ND ND --ND ND ND ND --------NDug/L 04/03/06 ----5 ND ND --ND ND ND ND --------NDug/L 10/03/06 ----5 ND ND --ND ND ND ND --------NDug/L 04/05/07 ----3 ND ND --ND ND ND ND --------NDug/L 10/18/07 ----1 ND ND --ND --0.2 J 0.3 J --------NDug/L 04/29/08 ----1 ND ----ND ND ND ND --------NDug/L 10/23/08 ----1 ND ----ND ND ND ND --------NDug/L 04/07/09 ----1 ND ----ND ND ND ND --------NDug/L 10/19/09 ----1 ND ----ND ND ND ND --------NDug/L 04/28/10 ----1 ND 0.43 J --ND ND ND 0.49 J --------NDug/L 10/12/10 ----1 ND ----ND ND 0.48 J ND --------NDug/L 04/11/11 ----1 ND ----ND ND ND ND --------NDug/L 10/04/11 ----1 ND ----ND ND ND ND 2.8 ND ND ND NDug/L 04/10/12 ----1 ND ----ND ND 0.56 J ND --------NDug/L 10/15/12 ----1 ND ----ND ND 0.46 J ND --------NDug/L 04/09/13 ----1 ND ----ND ND 0.77 J ND --------NDug/L 10/08/13 ----1 ND ----ND ND 0.45 J ND --------NDug/L 04/08/14 ----1 ND ----ND ND 0.64 J ND --------NDug/L 10/08/14 0.17 --1 ND ----ND ND 0.71 J ND --------NDug/L 04/08/15 0.17 --1 ND ----ND ND ND ND --------NDug/L 10/28/15 0.17 --1 ND ND ND ND ND 0.98 J ND 7.0 ND ND --NDug/L 04/05/16 0.17 --1 ND ND ND ND ND ND ND 1.0 ND ND --NDug/L 10/04/16 0.17 --1 ND 0.53 J 0.44 J ND ND 0.66 J ND 1.3 ND ND --NDug/L 04/03/17 0.17 --1 ND ND ND ND ND 0.63 J ND 1.6 ND ND --NDug/L 10/03/17 0.17 --1 ND ND ND ND ND 1.3 ND 5.4 ND ND --NDug/L 05/22/18 0.17 --1 ND ND ND ND ND ND ND 1.1 ND ND --NDug/L 10/23/18 0.17 1 --ND ND ND ND ND 0.60 J ND 2.2 ND ND --NDug/L 04/16/19 0.17 1 --ND ND ND ND ND 0.43 J ND 1.2 ND ND --NDug/L 10/15/19 0.17 1 --ND ND ND ND ND 0.95 J ND 4.3 ND ND --NDug/L 04/17/20 0.17 1 --ND ND ND ND ND 0.53 J ND 1.1 ND ND --NDug/L 10/07/20 0.17 1 --ND ND ND ND ND 0.63 J ND 1.6 ND ND --NDug/L 05/10/21 0.17 1 --ND ND ND ND ND ND ND 1.4 ND ND --NDug/L 10/06/21 0.17 1 --ND ND ND ND ND 1.1 ND 2.6 ND ND --NDug/L 05/18/22 0.17 1 --ND ND ND ND ND 0.60 J ND 0.75 J ND ND --NDug/L 10/10/22 0.17 1 --DRY ND ND ND ND 0.61 J ND 2.2 ND ND --NDug/L 05/22/23 0.17 1 --DRY ND ND ND ND 0.445 J ND 1.87 J ND ND --NDTrichloroetheneug/L 09/22/94 ----5 ND ----ND ND ND ND --------NDNC 2L = 3 ug/L ug/L 11/08/94 ----5 ND ----ND ND ND ND --------NDEPA MCL = 5 ug/L ug/L 01/18/95 ----5 ND ----ND ND ND ND --------NDug/L 04/23/96 ----5 ND ----ND ND ND ND --------NDug/L 06/17/97 ----5 ND ----ND ND ND ND --------NDug/L 10/16/97 ----5 ND ----ND ND ND ND --------NDug/L 04/21/98 ----5 ND ----ND ND ND ND --------NDug/L 04/07/99 ----5 ND ----ND ND ND ND --------NDug/L 10/13/99 ----5 ND ----ND ND ND ND --------NDug/L 04/05/00 ----5 ND ----ND ND ND ND --------NDug/L 10/25/00 ----5 ND ----ND ND ND ND --------NDug/L 04/04/01 ----5 ND ----ND ND ND ND --------NDug/L 04/08/02 ----5 ND ND --ND ND ND ND --------NDug/L 10/21/02 ----5 ND ND --ND ND ND ND --------NDug/L 04/14/03 ----5 ND ND --ND ND ND ND --------NDug/L 10/01/03 ----5 ND ND --ND ND ND ND --------NDug/L 04/05/04 ----5 ND ND --ND ND ND ND --------NDug/L 10/18/04 ----5 ND ND --ND ND ND ND --------NDug/L 04/07/05 ----5 ND ND --ND ----------------ug/L 10/06/05 ----5 ND ND --ND ND ND ND --------NDug/L 04/03/06 ----5 ND ND --ND ND ND ND --------NDug/L 10/03/06 ----5 ND ND --ND ND ND ND --------NDug/L 04/05/07 ----3 ND ND --ND ND ND ND --------NDug/L 10/18/07 ----1 ND 0.5 J --ND --0.7 J 0.2 J --------NDug/L 04/29/08 ----1 ND ----ND ND 0.67 J 0.41 J --------NDug/L 10/23/08 ----1 ND ----ND 0.51 J 0.95 J ND --------NDug/L 04/07/09 ----1 ND ----ND ND 0.90 J 0.46 J --------NDug/L 10/19/09 ----1 ND ----ND 0.53 J 1.2 ND --------NDug/L 04/28/10 ----1 ND ND --ND ND 1.1 0.51 J --------NDug/L 10/12/10 ----1 ND ----ND 0.46 J 1.5 ND --------NDug/L 04/11/11 ----1 ND ----ND ND 1.4 ND --------NDug/L 10/04/11 ----1 ND ----ND ND 1.6 ND 2.2 ND ND ND NDug/L 04/10/12 ----1 ND ----ND ND 1.6 0.39 J --------NDug/L 10/15/12 ----1 ND ----ND ND 1.8 ND --------NDug/L 04/09/13 ----1 ND ----ND ND 2.4 ND --------NDug/L 10/08/13 ----1 ND ----ND ND 1.9 ND --------NDug/L 04/08/14 ----1 ND ----ND ND 2.3 ND --------NDug/L 10/08/14 0.15 --1 ND ----ND ND 2.7 ND --------NDug/L 04/08/15 0.15 --1 ND ----ND ND 0.96 J ND --------NDug/L 10/28/15 0.15 --1 0.50 J ----ND ND 3.1 ND 3.6 ------NDug/L 04/05/16 0.15 --1 ND ND ND ND ND 1.4 ND 0.99 J ND ND --NDug/L 10/04/16 0.15 --1 ND ND 0.46 J ND ND 2.4 ND 1.4 ND ND --NDug/L 04/03/17 0.15 --1 ND ND ND ND ND 2.9 ND 1.5 ND ND --NDug/L 10/03/17 0.15 --1 ND ND ND ND ND 3.2 ND 4.1 ND ND --NDug/L 05/22/18 0.15 --1 ND ND ND ND ND 1.9 ND 1.0 ND ND --NDug/L 10/23/18 0.15 1 --ND ND 0.45 J ND ND 1.2 ND 2.1 ND ND --NDug/L 04/16/19 0.15 1 --ND ND ND ND ND 1.4 ND 1.2 ND ND --NDug/L 10/15/19 0.15 1 --ND ND ND ND ND 2.9 ND 3.9 ND ND --NDug/L 04/14/20 0.15 1 --ND ND 0.41 J ND ND 1.9 ND 0.94 J ND ND --NDug/L 10/07/20 0.15 1 --ND ND ND ND ND ND ND 1.5 ND ND --NDug/L 05/10/21 0.15 1 --ND ND ND ND ND ND ND ND ND ND --NDug/L 10/06/21 0.15 1 --ND ND ND ND ND 1.9 ND 2.3 ND ND --NDug/L 05/18/22 0.15 1 --ND ND ND ND ND ND ND ND ND ND --NDug/L 10/10/22 0.15 1 --DRY ND ND ND ND 1.6 ND 2.0 ND ND --NDug/L 05/22/23 0.15 1 --DRY ND ND ND 0.412 J ND ND ND ND ND --ND
2 of 3
September 2023 31404568.018
MW-5 MW-2 MW-3 MW-6 MW-7 MW-8 MW-9 MW-10S MW-10D MW-11S MW-11D
Downgradient Wells BlanksDetected Monitoring Constituent/Parameter Units Date Detection Reporting Well
Vinyl chloride ug/L 09/22/94 ----10 ND ----ND ND ND ND --------NDNC 2L = 0.03 ug/L ug/L 11/08/94 ----10 ND ----ND ND ND ND --------NDEPA MCL = 2 ug/L ug/L 01/18/95 ----10 ND ----ND ND ND ND --------NDug/L 04/23/96 ----10 ND ----ND ND ND ND --------NDug/L 06/17/97 ----10 ND ----ND ND ND ND --------NDug/L 10/16/97 ----10 ND ----ND ND ND ND --------NDug/L 04/21/98 ----10 ND ----ND ND ND ND --------NDug/L 04/07/99 ----10 ND ----ND ND ND ND --------NDug/L 10/13/99 ----10 ND ----ND ND ND ND --------NDug/L 04/05/00 ----10 ND ----ND ND ND ND --------NDug/L 10/25/00 ----10 ND ----ND ND ND ND --------NDug/L 04/04/01 ----10 ND ----ND ND ND ND --------NDug/L 04/04/02 ----10 ND ND --ND ND ND ND --------NDug/L 10/21/02 ----10 ND ND --ND ND ND ND --------NDug/L 04/14/03 ----10 ND ND --ND ND ND ND --------NDug/L 10/01/03 ----10 ND ND --ND ND ND ND --------NDug/L 04/05/04 ----10 ND ND --ND ND ND ND --------NDug/L 10/18/04 ----10 ND ND --ND ND ND ND --------NDug/L 04/07/05 ----10 ND ND --ND ND ND ND --------NDug/L 10/06/05 ----10 ND ND --ND ND ND ND --------NDug/L 04/03/06 ----10 ND ND --ND ND ND ND --------NDug/L 10/03/06 ----10 ND ND --ND ND ND ND --------NDug/L 04/05/07 ----10 ND ND --ND ND ND ND --------NDug/L 10/18/07 ----1 ND ND --ND --ND ND --------NDug/L 04/29/08 ----1 ND ----ND 0.41 J ND 0.54 J --------NDug/L 10/23/08 ----1 ND ----ND 0.93 J ND ND --------NDug/L 04/07/09 ----1 ND ----ND 0.46 J ND 0.71 J --------NDug/L 10/19/09 ----1 ND ----ND 1.2 ND ND --------NDug/L 04/28/10 ----1 ND ND --ND 0.63 J ND 0.64 J --------NDug/L 10/12/10 ----1 ND ----ND 1.0 ND ND --------NDug/L 04/11/11 ----1 ND ----ND 0.70 J ND ND --------NDug/L 10/04/11 ----1 ND ----ND 1.1 ND ND ND 0.63 J ND ND NDug/L 04/10/12 ----1 ND ----ND 0.51 J ND 0.34 J --------NDug/L 10/15/12 ----1 ND ----ND 1.0 ND ND --------NDug/L 04/09/13 ----1 ND ----ND 0.75 J ND ND --------NDug/L 10/08/13 ----1 ND ----ND 0.74 J ND ND --------NDug/L 04/08/14 ----1 ND ----ND 0.51 J ND ND --------NDug/L 10/08/14 0.32 --1 ND ----ND 0.52 J ND ND --------NDug/L 04/08/15 0.32 --1 ND ----ND ND ND ND --------NDug/L 10/28/15 0.32 --1 ND ND ND ND 0.48 J ND ND 1.3 ND ND --NDug/L 04/05/16 0.32 --1 ND ND ND ND ND ND ND ND ND ND --NDug/L 10/04/16 0.32 --1 ND ND ND ND ND ND ND ND 0.78 J ND --NDug/L 04/03/17 0.32 --1 ND ND ND ND ND ND ND 0.70 J 0.96 J ND --NDug/L 10/03/17 0.32 --1 ND ND ND ND ND ND ND 1.2 0.75 J ND --NDug/L 05/22/18 0.32 --1 ND ND ND ND ND ND ND ND 0.83 J ND --NDug/L 10/23/18 0.32 1 --ND ND ND ND ND ND ND 1.0 0.79 J ND --NDug/L 04/16/19 0.32 1 --ND ND ND ND ND ND ND 0.65 J 0.73 J ND --NDug/L 10/15/19 0.32 1 --ND ND ND ND ND ND ND 1.3 0.47 J ND --NDug/L 04/14/20 0.32 1 --ND ND ND ND ND ND ND ND ND ND --NDug/L 10/07/20 0.32 1 --ND ND ND ND ND ND ND 0.93 J ND ND --NDug/L 05/10/21 0.32 1 --ND ND ND ND ND ND ND ND ND ND --NDug/L 10/06/21 0.32 1 --ND ND ND ND ND ND ND 0.98 J ND ND --NDug/L 05/18/22 0.32 1 --ND ND ND ND ND ND ND 0.47 J 0.58 J ND --NDug/L 10/10/22 0.32 1 --DRY ND ND ND ND ND ND 0.86 J 0.36 J ND --NDug/L 05/22/23 0.32 1 --DRY ND ND ND ND ND ND 0.879 J 0.273 J ND --ND
Notes:ug/L =micrograms per litermg/L = milligrams per literND =Not detected at the stated reporting limit for data before October 2007 and not detected at the laboratory detection limit for data from October 2007 forwardNM =Not measuredJ =Prior to the October 2018 event, J flags are estimated values below the SWS Reporting limit. Beginning with the October 2018 event, J flags are estimated values between MDL and PQL.B =Blank-qualified resultR =unusable data-- =no data availableBlanks =field, trip and method blanksBold Only =Concentration above current NC 2L Groundwater Standard or NC SWS Groundwater Protection StandardShaded and Bold =Concentration above current NC 2L Groundwater Standard or NC SWS Groundwater Protection Standard and EPA MCLNC 2L =North Carolina 2L Groundwater StandardEPA MCL =US Environmental Protection Agency Maximum Contaminant LevelSWS Reporting Limit =NCPQL or lab-specific reporting limit prior to October 2007 and NCSWSL starting in October 2007Historical data prior to April 2008 provided by the County as taken from historical reports from Hazen and Sawyer and Environment 1.
3 of 3

FIGURE
670
670
660
670
660
660
65
0
640
630
63
0
62
0
62
0
610
610
600
600
590
590
570
570
580
580
660
670
650
640
i1
i2
i3
680
690
690
680
700
700
680
680
MW-11D
565.52 MW-11S
566.42
MW-7
566.97
MW-2
566.50
GM-3
SW-2
MW-10S
584.17
MW-10D
589.52
MW-1
595.44
GM-4
MW-6
613.74
MW-A1
615.75
MW-A2
636.24
MW-A3
681.89
701.21
MW-4
MW-5
653.42
GM-5
MW-9
596.97
GM-1
GM-2
579.28
MW-8
565.78
MW-3 SW-1
SITE LOCATION
SW-3
SW-4
CONSULTANT
DESIGN
PREPARED
REVIEW
APPROVED
YYYY-MM-DD TITLE
PROJECT No.Rev.
PROJECTCLIENT
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31404568.018
FIGURE
10
2023-08-25
SIB
JS
RANDOLPH COUNTY LANDFILL
PERMIT NO. 76-01
WASTE MANAGEMENT
GROUNDWATER SURFACE CONTOUR MAP
MAY 22, 2023
SITE LOCATION MAP
(NOT TO SCALE)
0
FEET
150 300
SCALE
EXISTING 10 FT GROUND SURFACE CONTOUR
EXISTING 2 FT GROUND SURFACE CONTOUR
APPROXIMATE LIMITS OF WASTE
EXISTING ROAD
GROUNDWATER ELEVATION 10 FT CONTOURS
GROUNDWATER FLOW ARROW
COMPLIANCE MONITORING WELL AND GROUNDWATER ELEVATIONS
NON-COMPLIANCE MONITORING WELL AND GROUNDWATER ELEVATIONS
LANDFILL GAS MONITORING PROBE
SURFACE WATER MONITORING POINT
LEGEND
NOTES
1.TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET
2.GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET
3.GROUNDWATER ELEVATIONS MEASURED ON MAY 22, 2023.
4.GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION BETWEEN AND
EXTRAPOLATION FROM KNOWN DATA, TOPOGRAPHIC CONTOURS, AND KNOWN FIELD
CONDITIONS. THEREFORE, GROUNDWATER CONTOURS MAY NOT REFLECT ACTUAL
CONDITIONS.
5.GROUNDWATER CONTOUR LINES SHOW THE WATER TABLE SHAPE AND ELEVATION. THESE
CONTOURS ARE INFERRED LINES FOLLOWING THE GROUNDWATER SURFACE AT A
CONSTANT ELEVATION ABOVE SEA LEVEL. THE GROUNDWATER FLOW DIRECTION IS
GENERALLY PERPENDICULAR TO THE GROUNDWATER SURFACE CONTOURS, SIMILAR TO
THE RELATIONSHIP BETWEEN SURFACE WATER FLOW AND TOPOGRAPHIC CONTOURS.
6.THE GROUNDWATER ELEVATION FOR MW-10D WAS NOT USED FOR CONTOURING.
7.MW-A1, MW-A2, MW-A3, MW-1, MW-2, MW-3, MW-4, MW-10D, MW-11S, AND MW-11D ARE NOT
SAMPLED AS PART OF THE COMPLIANCE NETWORK.
8.BASE MAP PROVIDED BY HAZEN AND SAWYER, INC. OVERALL GROUND SURFACE
TOPOGRAPHY OBTAINED FROM AERIAL SURVEY CONDUCTED BY KUCERA INTERNATIONAL
INC., WILLOUGHBY, OHIO ON 8/2/93.
9.COORDINATE SYSTEM IS N.C. STATE PLANE GRID.
10.THE GROUNDWATER ELEVATIONS FOR DEEP WELLS DENOTED BY "D" WERE NOT USED IN
THE CONSTRUCTION OF GROUNDWATER CONTOURS.
640
SW-1
GM-1
653.42
MW-5
i1
636.24
MW-A2
PG C-399
APPENDICES

APPENDIX A
Groundwater and Surface Water
Sampling Logs

APPENDIX B
May 2023 Groundwater and Surface
Water Certificates-ofAnalysis, Chain-of-
Custody Forms,and Laboratory Data
Reviews
ANALYTICAL REPORT
PREPARED FOR
Attn: Darren Cox
WSP USA Inc
5B Oak Branch Drive
Greensboro, North Carolina 27407
Generated 6/6/2023 3:03:41 PM
JOB DESCRIPTION
Randolph County Landfill
Randolph County - Spring
JOB NUMBER
752-7507-1
See page two for job notes and contact information.
Cary NC 27511
102-A Woodwinds Industrial Court
Eurofins Raleigh
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Eurofins Raleigh
Eurofins Savannah is a laboratory within Eurofins Environment Testing Southeast, LLC, a company within Eurofins Environment Testing Group of Companies
Job Notes
This report may not be reproduced except in full, and with written approval from the laboratory. The results relate only to the
samples tested. For questions please contact the Project Manager at the e-mail address or telephone number listed on this
page.
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the
methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written
approval of the laboratory. All questions should be directed to the Eurofins Environment Testing Southeast, LLC Project
Manager.
Authorization
Generated
6/6/2023 3:03:41 PM
Authorized for release by
Amanda Gaines, Project Manager
[e-mail]
[phone]
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Table of Contents
Client: WSP USA Inc
Project/Site: Randolph County Landfill
Laboratory Job ID: 752-7507-1
Page 3 of 63 Eurofins Raleigh6/6/2023
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3
Definitions/Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .10
Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .28
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .30
QC Association Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .49
Lab Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .53
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .56
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .57
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .58
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .59
Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .62
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Definitions/Glossary
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Qualifiers
GC/MS VOA
Qualifier Description
F1 MS and/or MSD recovery exceeds control limits.
Qualifier
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Metals
Qualifier Description
F1 MS and/or MSD recovery exceeds control limits.
Qualifier
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins Raleigh
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Case Narrative
Client: WSP USA Inc Job ID: 752-7507-1
Project/Site: Randolph County Landfill
Job ID: 752-7507-1
Laboratory: Eurofins Raleigh
Narrative
Job Narrative
752-7507-1
Comments
No additional comments.
Receipt
The samples were received on 5/25/2023 10:00 AM. Unless otherwise noted below, the samples arrived in good condition, and where
required, properly preserved and on ice. The temperature of the cooler at receipt was 2.0º C.
GC/MS VOA
Method 8260D: The matrix spike / matrix spike duplicate (MS/MSD) recoveries for analytical batch 752-3101 were outside control limits for
Carbon tetrachloride . See QC Sample Results for detail. Sample matrix interference and/or non-homogeneity are suspected because the
associated laboratory control sample (LCS) recovery is within acceptance limits.
Method 8260D: The CCV for analytical batch 752-3101 recovered outside control limits for the following analyte(s): 2-Butanone (MEK),
2-Hexanone, Acetone, Acrylonitrile, Bromomethane, Chloroethane, Chloromethane and Trichlorofluoromethane. These have been
identified as a poor performing analytes when analyzed using this method; therefore, re-extraction/re-analysis was not performed. These
results have been reported and qualified.
Method 8260D: The continuing calibration verification (CCV) associated with batch 752-3101 recovered above the upper control limit for
1,1,1-Trichloroethane, 1,2-Dichloroethane and Carbon tetrachloride. The samples associated with this CCV were non-detects for the
affected analytes; therefore, the data have been reported. The associated sample is impacted: (CCVIS 752-3101/3).
Method 8260D: The continuing calibration verification (CCV) associated with batch 752-3101 recovered outside acceptance criteria, low
biased, for Dibromofluoromethane (Surr), Toluene-d8 (Surr) and Vinyl chloride. A reporting limit (RL) standard was analyzed, and the
target analytes are detected. Since the associated samples were non-detect for the analyte(s), the data are reported.
Method 8260D: The CCV for analytical batch 752-3113 recovered outside control limits for the following analyte(s): 2-Hexanone,
Acrylonitrile, Bromomethane, Chloroethane, Chloromethane and Trichlorofluoromethane. These compounds have been identified as a
poor performing analytes when analyzed using this method; therefore, re-extraction/re-analysis was not performed. These results have
been reported and qualified.
Method 8260D: The continuing calibration verification (CCV) associated with batch 752-3113 recovered outside acceptance criteria, low
biased, for Dibromofluoromethane (Surr), Toluene-d8 (Surr) and Vinyl chloride. A reporting limit (RL) standard was analyzed, and the
target analytes are detected. Since the associated samples were non-detect for the analyte(s), the data are reported.
Method 8260D: The continuing calibration verification (CCV) associated with batch 752-3113 recovered above the upper control limit for
1,2-Dichloroethane and Carbon tetrachloride. The samples associated with this CCV were non-detects for the affected analytes;
therefore, the data have been reported.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
GC/MS Semi VOA
Method 8270E: The continuing calibration verification (CCV) analyzed in batch 680-780901 was outside the method criteria for the
following analyte(s): Diethyl phthalate. A CCV standard at or below the reporting limit (RL) was analyzed with the affected samples and
found to be acceptable. As indicated in the reference method, sample analysis may proceed; however, any detection for the affected
analyte(s) is considered estimated.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Metals
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
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Case Narrative
Client: WSP USA Inc Job ID: 752-7507-1
Project/Site: Randolph County Landfill
Job ID: 752-7507-1 (Continued)
Laboratory: Eurofins Raleigh (Continued)
Organic Prep
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
VOA Prep
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
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Detection Summary
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Client Sample ID: 7601-MW10S Lab Sample ID: 752-7507-1
1,4-Dioxane
RL
0.500 ug/L
MDL
0.320
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA124.4 8260 SIM
1,1-Dichloroethane 1.00 ug/L0.130 Total/NA138.3 8260D
1,2-Dichloroethane 1.00 ug/L0.210 Total/NA10.422 J 8260D
Benzene 1.00 ug/L0.150 Total/NA10.840 J 8260D
Chloroethane 1.00 ug/L0.230 Total/NA10.879 J 8260D
cis-1,2-Dichloroethene 1.00 ug/L0.150 Total/NA17.63 8260D
Dichlorodifluoromethane 1.00 ug/L0.200 Total/NA11.18 8260D
Methylene Chloride 1.00 ug/L0.230 Total/NA10.241 J 8260D
Tetrachloroethene 1.00 ug/L0.170 Total/NA12.54 8260D
Trichloroethene 1.00 ug/L0.150 Total/NA11.92 8260D
Vinyl chloride 1.00 ug/L0.320 Total/NA10.665 J 8260D
Barium 10.0 ug/L4.40 Total
Recoverable
14.73 J 6010D
Nickel 40.0 ug/L3.30 Total
Recoverable
13.84 J 6010D
Zinc 20.0 ug/L8.70 Total
Recoverable
19.90 J 6010D
Client Sample ID: 7601-MW6 Lab Sample ID: 752-7507-2
1,4-Dioxane
RL
0.500 ug/L
MDL
0.320
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA19.11 8260 SIM
1,1-Dichloroethane 1.00 ug/L0.130 Total/NA11.05 8260D
Chloromethane 1.00 ug/L0.130 Total/NA10.147 J 8260D
Barium 10.0 ug/L4.40 Total
Recoverable
120.9 6010D
Chromium 10.0 ug/L1.10 Total
Recoverable
11.22 J 6010D
Cobalt 10.0 ug/L1.40 Total
Recoverable
11.56 J 6010D
Copper 20.0 ug/L3.20 Total
Recoverable
17.98 J 6010D
Nickel 40.0 ug/L3.30 Total
Recoverable
15.10 J 6010D
Vanadium 10.0 ug/L1.00 Total
Recoverable
13.28 J 6010D
Client Sample ID: 7601-MW7 Lab Sample ID: 752-7507-3
1,4-Dioxane
RL
0.500 ug/L
MDL
0.320
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA11.47 8260 SIM
1,1-Dichloroethane 1.00 ug/L0.130 Total/NA10.359 J 8260D
Benzene 1.00 ug/L0.150 Total/NA10.507 J 8260D
Chlorobenzene 1.00 ug/L0.170 Total/NA11.07 8260D
Chloroethane 1.00 ug/L0.230 Total/NA10.791 J 8260D
cis-1,2-Dichloroethene 1.00 ug/L0.150 Total/NA10.317 J 8260D
Cadmium 5.00 ug/L0.440 Total
Recoverable
10.500 J 6010D
Cobalt 10.0 ug/L1.40 Total
Recoverable
110.9 6010D
Client Sample ID: 7601-MW8 Lab Sample ID: 752-7507-4
1,4-Dioxane
RL
0.500 ug/L
MDL
0.320
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA10.565 8260 SIM
Eurofins Raleigh
This Detection Summary does not include radiochemical test results.
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Detection Summary
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Client Sample ID: 7601-MW8 (Continued)Lab Sample ID: 752-7507-4
1,1-Dichloroethane
RL
1.00 ug/L
MDL
0.130
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA12.61 8260D
Chloroform 1.00 ug/L0.180 Total/NA10.181 J 8260D
cis-1,2-Dichloroethene 1.00 ug/L0.150 Total/NA10.610 J 8260D
Tetrachloroethene 1.00 ug/L0.170 Total/NA10.445 J 8260D
Client Sample ID: 7601-MW9 Lab Sample ID: 752-7507-5
1,4-Dioxane
RL
0.500 ug/L
MDL
0.320
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA10.888 8260 SIM
1,1-Dichloroethane 1.00 ug/L0.130 Total/NA10.480 J 8260D
cis-1,2-Dichloroethene 1.00 ug/L0.150 Total/NA10.278 J 8260D
Barium 10.0 ug/L4.40 Total
Recoverable
17.90 J 6010D
Vanadium 10.0 ug/L1.00 Total
Recoverable
11.83 J 6010D
Client Sample ID: 7601-SW1 Lab Sample ID: 752-7507-6
1,4-Dioxane
RL
0.500 ug/L
MDL
0.320
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA11.23 8260 SIM
Barium 10.0 ug/L4.40 Total
Recoverable
145.5 6010D
Cobalt 10.0 ug/L1.40 Total
Recoverable
13.88 J 6010D
Vanadium 10.0 ug/L1.00 Total
Recoverable
15.09 J 6010D
Client Sample ID: 7601-SW2 Lab Sample ID: 752-7507-7
1,4-Dioxane
RL
0.500 ug/L
MDL
0.320
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA119.4 8260 SIM
Barium 10.0 ug/L4.40 Total
Recoverable
132.8 6010D
Client Sample ID: 7601-SW3 Lab Sample ID: 752-7507-8
1,4-Dioxane
RL
0.500 ug/L
MDL
0.320
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA14.58 8260 SIM
Chloroform 1.00 ug/L0.180 Total/NA10.725 J 8260D
Barium 10.0 ug/L4.40 Total
Recoverable
120.8 6010D
Vanadium 10.0 ug/L1.00 Total
Recoverable
11.73 J 6010D
Client Sample ID: 7601-SW4 Lab Sample ID: 752-7507-9
1,4-Dioxane
RL
0.500 ug/L
MDL
0.320
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA14.05 8260 SIM
Bromodichloromethane 1.00 ug/L0.170 Total/NA10.287 J 8260D
Chloroform 1.00 ug/L0.180 Total/NA10.733 J 8260D
Barium 10.0 ug/L4.40 Total
Recoverable
119.1 6010D
Vanadium 10.0 ug/L1.00 Total
Recoverable
11.59 J 6010D
Eurofins Raleigh
This Detection Summary does not include radiochemical test results.
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Detection Summary
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Client Sample ID: 7601-Trip Blank Lab Sample ID: 752-7507-10
Chloroform
RL
1.00 ug/L
MDL
0.180
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1J0.205 8260D
Eurofins Raleigh
This Detection Summary does not include radiochemical test results.
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Client Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Lab Sample ID: 752-7507-1Client Sample ID: 7601-MW10S
Matrix: WaterDate Collected: 05/22/23 14:45
Date Received: 05/25/23 10:00
Method: SW846 8260 SIM - 1,4-Dioxane by SIM
RL MDL
24.4 0.500 0.320 ug/L 05/31/23 14:26 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,4-Dioxane
4-Bromofluorobenzene (Surr)100 70-130 05/31/23 14:26 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Method: SW846 8260D - Volatile Organic Compounds by GC/MS
RL MDL
<0.170 1.00 0.170 ug/L 06/02/23 19:51 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1,2-Tetrachloroethane
1.00 0.120 ug/L 06/02/23 19:51 1<0.1201,1,1-Trichloroethane
1.00 0.280 ug/L 06/02/23 19:51 1<0.2801,1,2,2-Tetrachloroethane
1.00 0.140 ug/L 06/02/23 19:51 1<0.1401,1,2-Trichloroethane
1.00 0.130 ug/L 06/02/23 19:51 138.31,1-Dichloroethane
1.00 0.210 ug/L 06/02/23 19:51 1<0.2101,1-Dichloroethene
1.00 0.490 ug/L 06/02/23 19:51 1<0.4901,2,3-Trichloropropane
1.00 0.480 ug/L 06/02/23 19:51 1<0.4801,2-Dibromo-3-Chloropropane
1.00 0.660 ug/L 06/02/23 19:51 1<0.6601,2-Dibromoethane
1.00 0.190 ug/L 06/02/23 19:51 1<0.1901,2-Dichlorobenzene
1.00 0.210 ug/L 06/02/23 19:51 10.422 J1,2-Dichloroethane
1.00 0.100 ug/L 06/02/23 19:51 1<0.1001,2-Dichloropropane
1.00 0.190 ug/L 06/02/23 19:51 1<0.1901,4-Dichlorobenzene
20.0 10.0 ug/L 06/02/23 19:51 1<10.02-Butanone (MEK)
5.00 0.880 ug/L 06/02/23 19:51 1<0.8802-Hexanone
5.00 1.10 ug/L 06/02/23 19:51 1<1.104-Methyl-2-pentanone (MIBK)
20.0 10.0 ug/L 06/02/23 19:51 1<10.0Acetone
10.0 3.50 ug/L 06/02/23 19:51 1<3.50Acrylonitrile
1.00 0.150 ug/L 06/02/23 19:51 10.840 JBenzene
1.00 0.480 ug/L 06/02/23 19:51 1<0.480Bromochloromethane
1.00 0.170 ug/L 06/02/23 19:51 1<0.170Bromodichloromethane
1.00 0.220 ug/L 06/02/23 19:51 1<0.220Bromoform
1.00 0.140 ug/L 06/02/23 19:51 1<0.140Bromomethane
5.00 1.50 ug/L 06/02/23 19:51 1<1.50Carbon disulfide
1.00 0.170 ug/L 06/02/23 19:51 1<0.170Carbon tetrachloride
1.00 0.170 ug/L 06/02/23 19:51 1<0.170Chlorobenzene
1.00 0.230 ug/L 06/02/23 19:51 10.879 JChloroethane
1.00 0.180 ug/L 06/02/23 19:51 1<0.180Chloroform
1.00 0.130 ug/L 06/02/23 19:51 1<0.130Chloromethane
1.00 0.150 ug/L 06/02/23 19:51 17.63cis-1,2-Dichloroethene
1.00 0.200 ug/L 06/02/23 19:51 1<0.200cis-1,3-Dichloropropene
1.00 0.170 ug/L 06/02/23 19:51 1<0.170Dibromochloromethane
1.00 0.270 ug/L 06/02/23 19:51 1<0.270Dibromomethane
1.00 0.200 ug/L 06/02/23 19:51 11.18Dichlorodifluoromethane
1.00 0.130 ug/L 06/02/23 19:51 1<0.130Ethylbenzene
5.00 1.70 ug/L 06/02/23 19:51 1<1.70Iodomethane
1.00 0.230 ug/L 06/02/23 19:51 10.241 JMethylene Chloride
1.00 0.110 ug/L 06/02/23 19:51 1<0.110Styrene
1.00 0.170 ug/L 06/02/23 19:51 12.54Tetrachloroethene
1.00 0.140 ug/L 06/02/23 19:51 1<0.140Toluene
1.00 0.210 ug/L 06/02/23 19:51 1<0.210trans-1,2-Dichloroethene
1.00 0.150 ug/L 06/02/23 19:51 1<0.150trans-1,3-Dichloropropene
1.00 0.700 ug/L 06/02/23 19:51 1<0.700trans-1,4-Dichloro-2-butene
Eurofins Raleigh
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Client Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Lab Sample ID: 752-7507-1Client Sample ID: 7601-MW10S
Matrix: WaterDate Collected: 05/22/23 14:45
Date Received: 05/25/23 10:00
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
1.92 1.00 0.150 ug/L 06/02/23 19:51 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Trichloroethene
1.00 0.240 ug/L 06/02/23 19:51 1<0.240Trichlorofluoromethane
5.00 0.950 ug/L 06/02/23 19:51 1<0.950Vinyl acetate
1.00 0.320 ug/L 06/02/23 19:51 10.665 JVinyl chloride
3.00 0.450 ug/L 06/02/23 19:51 1<0.450Xylenes, Total
4-Bromofluorobenzene (Surr)93 53-136 06/02/23 19:51 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)90 06/02/23 19:51 167-129
Toluene-d8 (Surr)79 06/02/23 19:51 159-134
Method: SW846 8270E - Semivolatile Organic Compounds (GC/MS)
RL MDL
<2.10 9.55 2.10 ug/L 05/27/23 12:41 05/29/23 22:19 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Diethyl phthalate
2,4,6-Tribromophenol (Surr)60 30-130 05/27/23 12:41 05/29/23 22:19 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
2-Fluorobiphenyl 68 05/27/23 12:41 05/29/23 22:19 125-130
2-Fluorophenol (Surr)31 05/27/23 12:41 05/29/23 22:19 110-130
Nitrobenzene-d5 (Surr)68 05/27/23 12:41 05/29/23 22:19 130-130
Phenol-d5 (Surr)20 05/27/23 12:41 05/29/23 22:19 110-130
Terphenyl-d14 (Surr)74 05/27/23 12:41 05/29/23 22:19 135-131
Method: SW846 6010D - Metals (ICP) - Total Recoverable
RL MDL
<6.40 20.0 6.40 ug/L 05/30/23 06:22 05/30/23 15:44 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Arsenic
10.0 4.40 ug/L 05/30/23 06:22 05/30/23 15:44 14.73 JBarium
4.00 0.300 ug/L 05/30/23 06:22 05/30/23 15:44 1<0.300Beryllium
5.00 0.440 ug/L 05/30/23 06:22 05/30/23 15:44 1<0.440Cadmium
10.0 1.10 ug/L 05/30/23 06:22 05/30/23 15:44 1<1.10Chromium
10.0 1.40 ug/L 05/30/23 06:22 05/30/23 15:44 1<1.40Cobalt
20.0 3.20 ug/L 05/30/23 06:22 05/30/23 15:44 1<3.20Copper
10.0 6.60 ug/L 05/30/23 06:22 05/30/23 15:44 1<6.60Lead
40.0 3.30 ug/L 05/30/23 06:22 05/30/23 15:44 13.84 JNickel
20.0 10.0 ug/L 05/30/23 06:22 05/30/23 15:44 1<10.0Selenium
10.0 1.50 ug/L 05/30/23 06:22 05/30/23 15:44 1<1.50Silver
10.0 1.00 ug/L 05/30/23 06:22 05/30/23 15:44 1<1.00Vanadium
20.0 8.70 ug/L 05/30/23 06:22 05/30/23 15:44 19.90 JZinc
Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable
RL MDL
<0.340 5.00 0.340 ug/L 05/30/23 06:22 05/30/23 23:06 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Antimony
1.00 0.260 ug/L 05/30/23 06:22 05/30/23 23:06 1<0.260Thallium
Method: SW846 7470A - Mercury (CVAA)
RL MDL
<0.0800 0.200 0.0800 ug/L 05/30/23 10:34 05/31/23 09:43 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Mercury
Eurofins Raleigh
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Client Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Lab Sample ID: 752-7507-2Client Sample ID: 7601-MW6
Matrix: WaterDate Collected: 05/23/23 11:15
Date Received: 05/25/23 10:00
Method: SW846 8260 SIM - 1,4-Dioxane by SIM
RL MDL
9.11 0.500 0.320 ug/L 06/01/23 15:40 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,4-Dioxane
4-Bromofluorobenzene (Surr)107 70-130 06/01/23 15:40 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Method: SW846 8260D - Volatile Organic Compounds by GC/MS
RL MDL
<0.170 1.00 0.170 ug/L 06/03/23 06:11 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1,2-Tetrachloroethane
1.00 0.120 ug/L 06/03/23 06:11 1<0.1201,1,1-Trichloroethane
1.00 0.280 ug/L 06/03/23 06:11 1<0.2801,1,2,2-Tetrachloroethane
1.00 0.140 ug/L 06/03/23 06:11 1<0.1401,1,2-Trichloroethane
1.00 0.130 ug/L 06/03/23 06:11 11.051,1-Dichloroethane
1.00 0.210 ug/L 06/03/23 06:11 1<0.2101,1-Dichloroethene
1.00 0.490 ug/L 06/03/23 06:11 1<0.4901,2,3-Trichloropropane
1.00 0.480 ug/L 06/03/23 06:11 1<0.4801,2-Dibromo-3-Chloropropane
1.00 0.660 ug/L 06/03/23 06:11 1<0.6601,2-Dibromoethane
1.00 0.190 ug/L 06/03/23 06:11 1<0.1901,2-Dichlorobenzene
1.00 0.210 ug/L 06/03/23 06:11 1<0.2101,2-Dichloroethane
1.00 0.100 ug/L 06/03/23 06:11 1<0.1001,2-Dichloropropane
1.00 0.190 ug/L 06/03/23 06:11 1<0.1901,4-Dichlorobenzene
20.0 10.0 ug/L 06/03/23 06:11 1<10.02-Butanone (MEK)
5.00 0.880 ug/L 06/03/23 06:11 1<0.8802-Hexanone
5.00 1.10 ug/L 06/03/23 06:11 1<1.104-Methyl-2-pentanone (MIBK)
20.0 10.0 ug/L 06/03/23 06:11 1<10.0Acetone
10.0 3.50 ug/L 06/03/23 06:11 1<3.50Acrylonitrile
1.00 0.150 ug/L 06/03/23 06:11 1<0.150Benzene
1.00 0.480 ug/L 06/03/23 06:11 1<0.480Bromochloromethane
1.00 0.170 ug/L 06/03/23 06:11 1<0.170Bromodichloromethane
1.00 0.220 ug/L 06/03/23 06:11 1<0.220Bromoform
1.00 0.140 ug/L 06/03/23 06:11 1<0.140Bromomethane
5.00 1.50 ug/L 06/03/23 06:11 1<1.50Carbon disulfide
1.00 0.170 ug/L 06/03/23 06:11 1<0.170Carbon tetrachloride
1.00 0.170 ug/L 06/03/23 06:11 1<0.170Chlorobenzene
1.00 0.230 ug/L 06/03/23 06:11 1<0.230Chloroethane
1.00 0.180 ug/L 06/03/23 06:11 1<0.180Chloroform
1.00 0.130 ug/L 06/03/23 06:11 10.147 JChloromethane
1.00 0.150 ug/L 06/03/23 06:11 1<0.150cis-1,2-Dichloroethene
1.00 0.200 ug/L 06/03/23 06:11 1<0.200cis-1,3-Dichloropropene
1.00 0.170 ug/L 06/03/23 06:11 1<0.170Dibromochloromethane
1.00 0.270 ug/L 06/03/23 06:11 1<0.270Dibromomethane
1.00 0.200 ug/L 06/03/23 06:11 1<0.200Dichlorodifluoromethane
1.00 0.130 ug/L 06/03/23 06:11 1<0.130Ethylbenzene
5.00 1.70 ug/L 06/03/23 06:11 1<1.70Iodomethane
1.00 0.230 ug/L 06/03/23 06:11 1<0.230Methylene Chloride
1.00 0.110 ug/L 06/03/23 06:11 1<0.110Styrene
1.00 0.170 ug/L 06/03/23 06:11 1<0.170Tetrachloroethene
1.00 0.140 ug/L 06/03/23 06:11 1<0.140Toluene
1.00 0.210 ug/L 06/03/23 06:11 1<0.210trans-1,2-Dichloroethene
1.00 0.150 ug/L 06/03/23 06:11 1<0.150trans-1,3-Dichloropropene
1.00 0.700 ug/L 06/03/23 06:11 1<0.700trans-1,4-Dichloro-2-butene
Eurofins Raleigh
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Client Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Lab Sample ID: 752-7507-2Client Sample ID: 7601-MW6
Matrix: WaterDate Collected: 05/23/23 11:15
Date Received: 05/25/23 10:00
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
<0.150 1.00 0.150 ug/L 06/03/23 06:11 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Trichloroethene
1.00 0.240 ug/L 06/03/23 06:11 1<0.240Trichlorofluoromethane
5.00 0.950 ug/L 06/03/23 06:11 1<0.950Vinyl acetate
1.00 0.320 ug/L 06/03/23 06:11 1<0.320Vinyl chloride
3.00 0.450 ug/L 06/03/23 06:11 1<0.450Xylenes, Total
4-Bromofluorobenzene (Surr)90 53-136 06/03/23 06:11 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)81 06/03/23 06:11 167-129
Toluene-d8 (Surr)75 06/03/23 06:11 159-134
Method: SW846 8270E - Semivolatile Organic Compounds (GC/MS)
RL MDL
<2.12 9.65 2.12 ug/L 05/27/23 12:41 05/29/23 22:40 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Diethyl phthalate
2,4,6-Tribromophenol (Surr)57 30-130 05/27/23 12:41 05/29/23 22:40 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
2-Fluorobiphenyl 61 05/27/23 12:41 05/29/23 22:40 125-130
2-Fluorophenol (Surr)29 05/27/23 12:41 05/29/23 22:40 110-130
Nitrobenzene-d5 (Surr)65 05/27/23 12:41 05/29/23 22:40 130-130
Phenol-d5 (Surr)20 05/27/23 12:41 05/29/23 22:40 110-130
Terphenyl-d14 (Surr)61 05/27/23 12:41 05/29/23 22:40 135-131
Method: SW846 6010D - Metals (ICP) - Total Recoverable
RL MDL
<6.40 20.0 6.40 ug/L 05/30/23 06:22 05/30/23 15:48 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Arsenic
10.0 4.40 ug/L 05/30/23 06:22 05/30/23 15:48 120.9Barium
4.00 0.300 ug/L 05/30/23 06:22 05/30/23 15:48 1<0.300Beryllium
5.00 0.440 ug/L 05/30/23 06:22 05/30/23 15:48 1<0.440Cadmium
10.0 1.10 ug/L 05/30/23 06:22 05/30/23 15:48 11.22 JChromium
10.0 1.40 ug/L 05/30/23 06:22 05/30/23 15:48 11.56 JCobalt
20.0 3.20 ug/L 05/30/23 06:22 05/30/23 15:48 17.98 JCopper
10.0 6.60 ug/L 05/30/23 06:22 05/30/23 15:48 1<6.60Lead
40.0 3.30 ug/L 05/30/23 06:22 05/30/23 15:48 15.10 JNickel
20.0 10.0 ug/L 05/30/23 06:22 05/30/23 15:48 1<10.0Selenium
10.0 1.50 ug/L 05/30/23 06:22 05/30/23 15:48 1<1.50Silver
10.0 1.00 ug/L 05/30/23 06:22 05/30/23 15:48 13.28 JVanadium
20.0 8.70 ug/L 05/30/23 06:22 05/30/23 15:48 1<8.70Zinc
Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable
RL MDL
<0.340 5.00 0.340 ug/L 05/30/23 06:22 05/30/23 23:10 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Antimony
1.00 0.260 ug/L 05/30/23 06:22 05/30/23 23:10 1<0.260Thallium
Method: SW846 7470A - Mercury (CVAA)
RL MDL
<0.0800 0.200 0.0800 ug/L 05/30/23 10:34 05/31/23 09:44 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Mercury
Eurofins Raleigh
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Client Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Lab Sample ID: 752-7507-3Client Sample ID: 7601-MW7
Matrix: WaterDate Collected: 05/22/23 09:44
Date Received: 05/25/23 10:00
Method: SW846 8260 SIM - 1,4-Dioxane by SIM
RL MDL
1.47 0.500 0.320 ug/L 05/31/23 15:36 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,4-Dioxane
4-Bromofluorobenzene (Surr)82 70-130 05/31/23 15:36 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Method: SW846 8260D - Volatile Organic Compounds by GC/MS
RL MDL
<0.170 1.00 0.170 ug/L 06/02/23 20:21 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1,2-Tetrachloroethane
1.00 0.120 ug/L 06/02/23 20:21 1<0.1201,1,1-Trichloroethane
1.00 0.280 ug/L 06/02/23 20:21 1<0.2801,1,2,2-Tetrachloroethane
1.00 0.140 ug/L 06/02/23 20:21 1<0.1401,1,2-Trichloroethane
1.00 0.130 ug/L 06/02/23 20:21 10.359 J1,1-Dichloroethane
1.00 0.210 ug/L 06/02/23 20:21 1<0.2101,1-Dichloroethene
1.00 0.490 ug/L 06/02/23 20:21 1<0.4901,2,3-Trichloropropane
1.00 0.480 ug/L 06/02/23 20:21 1<0.4801,2-Dibromo-3-Chloropropane
1.00 0.660 ug/L 06/02/23 20:21 1<0.6601,2-Dibromoethane
1.00 0.190 ug/L 06/02/23 20:21 1<0.1901,2-Dichlorobenzene
1.00 0.210 ug/L 06/02/23 20:21 1<0.2101,2-Dichloroethane
1.00 0.100 ug/L 06/02/23 20:21 1<0.1001,2-Dichloropropane
1.00 0.190 ug/L 06/02/23 20:21 1<0.1901,4-Dichlorobenzene
20.0 10.0 ug/L 06/02/23 20:21 1<10.02-Butanone (MEK)
5.00 0.880 ug/L 06/02/23 20:21 1<0.8802-Hexanone
5.00 1.10 ug/L 06/02/23 20:21 1<1.104-Methyl-2-pentanone (MIBK)
20.0 10.0 ug/L 06/02/23 20:21 1<10.0Acetone
10.0 3.50 ug/L 06/02/23 20:21 1<3.50Acrylonitrile
1.00 0.150 ug/L 06/02/23 20:21 10.507 JBenzene
1.00 0.480 ug/L 06/02/23 20:21 1<0.480Bromochloromethane
1.00 0.170 ug/L 06/02/23 20:21 1<0.170Bromodichloromethane
1.00 0.220 ug/L 06/02/23 20:21 1<0.220Bromoform
1.00 0.140 ug/L 06/02/23 20:21 1<0.140Bromomethane
5.00 1.50 ug/L 06/02/23 20:21 1<1.50Carbon disulfide
1.00 0.170 ug/L 06/02/23 20:21 1<0.170 F1Carbon tetrachloride
1.00 0.170 ug/L 06/02/23 20:21 11.07Chlorobenzene
1.00 0.230 ug/L 06/02/23 20:21 10.791 JChloroethane
1.00 0.180 ug/L 06/02/23 20:21 1<0.180Chloroform
1.00 0.130 ug/L 06/02/23 20:21 1<0.130Chloromethane
1.00 0.150 ug/L 06/02/23 20:21 10.317 Jcis-1,2-Dichloroethene
1.00 0.200 ug/L 06/02/23 20:21 1<0.200cis-1,3-Dichloropropene
1.00 0.170 ug/L 06/02/23 20:21 1<0.170Dibromochloromethane
1.00 0.270 ug/L 06/02/23 20:21 1<0.270Dibromomethane
1.00 0.200 ug/L 06/02/23 20:21 1<0.200Dichlorodifluoromethane
1.00 0.130 ug/L 06/02/23 20:21 1<0.130Ethylbenzene
5.00 1.70 ug/L 06/02/23 20:21 1<1.70Iodomethane
1.00 0.230 ug/L 06/02/23 20:21 1<0.230Methylene Chloride
1.00 0.110 ug/L 06/02/23 20:21 1<0.110Styrene
1.00 0.170 ug/L 06/02/23 20:21 1<0.170Tetrachloroethene
1.00 0.140 ug/L 06/02/23 20:21 1<0.140Toluene
1.00 0.210 ug/L 06/02/23 20:21 1<0.210trans-1,2-Dichloroethene
1.00 0.150 ug/L 06/02/23 20:21 1<0.150trans-1,3-Dichloropropene
1.00 0.700 ug/L 06/02/23 20:21 1<0.700trans-1,4-Dichloro-2-butene
Eurofins Raleigh
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Client Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Lab Sample ID: 752-7507-3Client Sample ID: 7601-MW7
Matrix: WaterDate Collected: 05/22/23 09:44
Date Received: 05/25/23 10:00
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
<0.150 1.00 0.150 ug/L 06/02/23 20:21 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Trichloroethene
1.00 0.240 ug/L 06/02/23 20:21 1<0.240Trichlorofluoromethane
5.00 0.950 ug/L 06/02/23 20:21 1<0.950Vinyl acetate
1.00 0.320 ug/L 06/02/23 20:21 1<0.320Vinyl chloride
3.00 0.450 ug/L 06/02/23 20:21 1<0.450Xylenes, Total
4-Bromofluorobenzene (Surr)89 53-136 06/02/23 20:21 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)90 06/02/23 20:21 167-129
Toluene-d8 (Surr)80 06/02/23 20:21 159-134
Method: SW846 8270E - Semivolatile Organic Compounds (GC/MS)
RL MDL
<2.20 9.99 2.20 ug/L 05/27/23 12:41 05/29/23 19:46 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Diethyl phthalate
2,4,6-Tribromophenol (Surr)62 30-130 05/27/23 12:41 05/29/23 19:46 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
2-Fluorobiphenyl 59 05/27/23 12:41 05/29/23 19:46 125-130
2-Fluorophenol (Surr)38 05/27/23 12:41 05/29/23 19:46 110-130
Nitrobenzene-d5 (Surr)73 05/27/23 12:41 05/29/23 19:46 130-130
Phenol-d5 (Surr)26 05/27/23 12:41 05/29/23 19:46 110-130
Terphenyl-d14 (Surr)73 05/27/23 12:41 05/29/23 19:46 135-131
Method: SW846 6010D - Metals (ICP) - Total Recoverable
RL MDL
<6.40 20.0 6.40 ug/L 05/30/23 06:51 05/30/23 14:34 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Arsenic
10.0 4.40 ug/L 05/30/23 06:51 05/30/23 14:34 1<4.40Barium
4.00 0.300 ug/L 05/30/23 06:51 05/30/23 14:34 1<0.300Beryllium
5.00 0.440 ug/L 05/30/23 06:51 05/30/23 14:34 10.500 JCadmium
10.0 1.10 ug/L 05/30/23 06:51 05/30/23 14:34 1<1.10Chromium
10.0 1.40 ug/L 05/30/23 06:51 05/30/23 14:34 110.9Cobalt
20.0 3.20 ug/L 05/30/23 06:51 05/30/23 14:34 1<3.20Copper
10.0 6.60 ug/L 05/30/23 06:51 05/30/23 14:34 1<6.60Lead
40.0 3.30 ug/L 05/30/23 06:51 05/30/23 14:34 1<3.30Nickel
20.0 10.0 ug/L 05/30/23 06:51 05/30/23 14:34 1<10.0Selenium
10.0 1.50 ug/L 05/30/23 06:51 05/30/23 14:34 1<1.50Silver
10.0 1.00 ug/L 05/30/23 06:51 05/30/23 14:34 1<1.00Vanadium
20.0 8.70 ug/L 05/30/23 06:51 05/30/23 14:34 1<8.70Zinc
Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable
RL MDL
<0.340 5.00 0.340 ug/L 05/30/23 06:51 05/30/23 20:32 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Antimony
1.00 0.260 ug/L 05/30/23 06:51 05/30/23 20:32 1<0.260Thallium
Method: SW846 7470A - Mercury (CVAA)
RL MDL
<0.0800 F1 0.200 0.0800 ug/L 05/30/23 10:34 05/31/23 09:46 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Mercury
Eurofins Raleigh
Page 15 of 63 6/6/2023
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Client Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Lab Sample ID: 752-7507-4Client Sample ID: 7601-MW8
Matrix: WaterDate Collected: 05/23/23 10:50
Date Received: 05/25/23 10:00
Method: SW846 8260 SIM - 1,4-Dioxane by SIM
RL MDL
0.565 0.500 0.320 ug/L 05/31/23 16:02 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,4-Dioxane
4-Bromofluorobenzene (Surr)99 70-130 05/31/23 16:02 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Method: SW846 8260D - Volatile Organic Compounds by GC/MS
RL MDL
<0.170 1.00 0.170 ug/L 06/03/23 06:40 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1,2-Tetrachloroethane
1.00 0.120 ug/L 06/03/23 06:40 1<0.1201,1,1-Trichloroethane
1.00 0.280 ug/L 06/03/23 06:40 1<0.2801,1,2,2-Tetrachloroethane
1.00 0.140 ug/L 06/03/23 06:40 1<0.1401,1,2-Trichloroethane
1.00 0.130 ug/L 06/03/23 06:40 12.611,1-Dichloroethane
1.00 0.210 ug/L 06/03/23 06:40 1<0.2101,1-Dichloroethene
1.00 0.490 ug/L 06/03/23 06:40 1<0.4901,2,3-Trichloropropane
1.00 0.480 ug/L 06/03/23 06:40 1<0.4801,2-Dibromo-3-Chloropropane
1.00 0.660 ug/L 06/03/23 06:40 1<0.6601,2-Dibromoethane
1.00 0.190 ug/L 06/03/23 06:40 1<0.1901,2-Dichlorobenzene
1.00 0.210 ug/L 06/03/23 06:40 1<0.2101,2-Dichloroethane
1.00 0.100 ug/L 06/03/23 06:40 1<0.1001,2-Dichloropropane
1.00 0.190 ug/L 06/03/23 06:40 1<0.1901,4-Dichlorobenzene
20.0 10.0 ug/L 06/03/23 06:40 1<10.02-Butanone (MEK)
5.00 0.880 ug/L 06/03/23 06:40 1<0.8802-Hexanone
5.00 1.10 ug/L 06/03/23 06:40 1<1.104-Methyl-2-pentanone (MIBK)
20.0 10.0 ug/L 06/03/23 06:40 1<10.0Acetone
10.0 3.50 ug/L 06/03/23 06:40 1<3.50Acrylonitrile
1.00 0.150 ug/L 06/03/23 06:40 1<0.150Benzene
1.00 0.480 ug/L 06/03/23 06:40 1<0.480Bromochloromethane
1.00 0.170 ug/L 06/03/23 06:40 1<0.170Bromodichloromethane
1.00 0.220 ug/L 06/03/23 06:40 1<0.220Bromoform
1.00 0.140 ug/L 06/03/23 06:40 1<0.140Bromomethane
5.00 1.50 ug/L 06/03/23 06:40 1<1.50Carbon disulfide
1.00 0.170 ug/L 06/03/23 06:40 1<0.170Carbon tetrachloride
1.00 0.170 ug/L 06/03/23 06:40 1<0.170Chlorobenzene
1.00 0.230 ug/L 06/03/23 06:40 1<0.230Chloroethane
1.00 0.180 ug/L 06/03/23 06:40 10.181 JChloroform
1.00 0.130 ug/L 06/03/23 06:40 1<0.130Chloromethane
1.00 0.150 ug/L 06/03/23 06:40 10.610 Jcis-1,2-Dichloroethene
1.00 0.200 ug/L 06/03/23 06:40 1<0.200cis-1,3-Dichloropropene
1.00 0.170 ug/L 06/03/23 06:40 1<0.170Dibromochloromethane
1.00 0.270 ug/L 06/03/23 06:40 1<0.270Dibromomethane
1.00 0.200 ug/L 06/03/23 06:40 1<0.200Dichlorodifluoromethane
1.00 0.130 ug/L 06/03/23 06:40 1<0.130Ethylbenzene
5.00 1.70 ug/L 06/03/23 06:40 1<1.70Iodomethane
1.00 0.230 ug/L 06/03/23 06:40 1<0.230Methylene Chloride
1.00 0.110 ug/L 06/03/23 06:40 1<0.110Styrene
1.00 0.170 ug/L 06/03/23 06:40 10.445 JTetrachloroethene
1.00 0.140 ug/L 06/03/23 06:40 1<0.140Toluene
1.00 0.210 ug/L 06/03/23 06:40 1<0.210trans-1,2-Dichloroethene
1.00 0.150 ug/L 06/03/23 06:40 1<0.150trans-1,3-Dichloropropene
1.00 0.700 ug/L 06/03/23 06:40 1<0.700trans-1,4-Dichloro-2-butene
Eurofins Raleigh
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Client Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Lab Sample ID: 752-7507-4Client Sample ID: 7601-MW8
Matrix: WaterDate Collected: 05/23/23 10:50
Date Received: 05/25/23 10:00
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
<0.150 1.00 0.150 ug/L 06/03/23 06:40 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Trichloroethene
1.00 0.240 ug/L 06/03/23 06:40 1<0.240Trichlorofluoromethane
5.00 0.950 ug/L 06/03/23 06:40 1<0.950Vinyl acetate
1.00 0.320 ug/L 06/03/23 06:40 1<0.320Vinyl chloride
3.00 0.450 ug/L 06/03/23 06:40 1<0.450Xylenes, Total
4-Bromofluorobenzene (Surr)91 53-136 06/03/23 06:40 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)86 06/03/23 06:40 167-129
Toluene-d8 (Surr)78 06/03/23 06:40 159-134
Method: SW846 8270E - Semivolatile Organic Compounds (GC/MS)
RL MDL
<2.03 9.24 2.03 ug/L 05/27/23 12:41 05/29/23 23:02 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Diethyl phthalate
2,4,6-Tribromophenol (Surr)62 30-130 05/27/23 12:41 05/29/23 23:02 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
2-Fluorobiphenyl 61 05/27/23 12:41 05/29/23 23:02 125-130
2-Fluorophenol (Surr)31 05/27/23 12:41 05/29/23 23:02 110-130
Nitrobenzene-d5 (Surr)69 05/27/23 12:41 05/29/23 23:02 130-130
Phenol-d5 (Surr)20 05/27/23 12:41 05/29/23 23:02 110-130
Terphenyl-d14 (Surr)70 05/27/23 12:41 05/29/23 23:02 135-131
Method: SW846 6010D - Metals (ICP) - Total Recoverable
RL MDL
<6.40 20.0 6.40 ug/L 05/30/23 06:51 05/30/23 14:44 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Arsenic
10.0 4.40 ug/L 05/30/23 06:51 05/30/23 14:44 1<4.40Barium
4.00 0.300 ug/L 05/30/23 06:51 05/30/23 14:44 1<0.300Beryllium
5.00 0.440 ug/L 05/30/23 06:51 05/30/23 14:44 1<0.440Cadmium
10.0 1.10 ug/L 05/30/23 06:51 05/30/23 14:44 1<1.10Chromium
10.0 1.40 ug/L 05/30/23 06:51 05/30/23 14:44 1<1.40Cobalt
20.0 3.20 ug/L 05/30/23 06:51 05/30/23 14:44 1<3.20Copper
10.0 6.60 ug/L 05/30/23 06:51 05/30/23 14:44 1<6.60Lead
40.0 3.30 ug/L 05/30/23 06:51 05/30/23 14:44 1<3.30Nickel
20.0 10.0 ug/L 05/30/23 06:51 05/30/23 14:44 1<10.0Selenium
10.0 1.50 ug/L 05/30/23 06:51 05/30/23 14:44 1<1.50Silver
10.0 1.00 ug/L 05/30/23 06:51 05/30/23 14:44 1<1.00Vanadium
20.0 8.70 ug/L 05/30/23 06:51 05/30/23 14:44 1<8.70Zinc
Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable
RL MDL
<0.340 5.00 0.340 ug/L 05/30/23 06:51 05/30/23 20:44 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Antimony
1.00 0.260 ug/L 05/30/23 06:51 05/30/23 20:44 1<0.260Thallium
Method: SW846 7470A - Mercury (CVAA)
RL MDL
<0.0800 0.200 0.0800 ug/L 05/30/23 10:34 05/31/23 09:54 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Mercury
Eurofins Raleigh
Page 17 of 63 6/6/2023
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Client Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Lab Sample ID: 752-7507-5Client Sample ID: 7601-MW9
Matrix: WaterDate Collected: 05/23/23 09:35
Date Received: 05/25/23 10:00
Method: SW846 8260 SIM - 1,4-Dioxane by SIM
RL MDL
0.888 0.500 0.320 ug/L 06/01/23 16:31 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,4-Dioxane
4-Bromofluorobenzene (Surr)101 70-130 06/01/23 16:31 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Method: SW846 8260D - Volatile Organic Compounds by GC/MS
RL MDL
<0.170 1.00 0.170 ug/L 06/03/23 07:10 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1,2-Tetrachloroethane
1.00 0.120 ug/L 06/03/23 07:10 1<0.1201,1,1-Trichloroethane
1.00 0.280 ug/L 06/03/23 07:10 1<0.2801,1,2,2-Tetrachloroethane
1.00 0.140 ug/L 06/03/23 07:10 1<0.1401,1,2-Trichloroethane
1.00 0.130 ug/L 06/03/23 07:10 10.480 J1,1-Dichloroethane
1.00 0.210 ug/L 06/03/23 07:10 1<0.2101,1-Dichloroethene
1.00 0.490 ug/L 06/03/23 07:10 1<0.4901,2,3-Trichloropropane
1.00 0.480 ug/L 06/03/23 07:10 1<0.4801,2-Dibromo-3-Chloropropane
1.00 0.660 ug/L 06/03/23 07:10 1<0.6601,2-Dibromoethane
1.00 0.190 ug/L 06/03/23 07:10 1<0.1901,2-Dichlorobenzene
1.00 0.210 ug/L 06/03/23 07:10 1<0.2101,2-Dichloroethane
1.00 0.100 ug/L 06/03/23 07:10 1<0.1001,2-Dichloropropane
1.00 0.190 ug/L 06/03/23 07:10 1<0.1901,4-Dichlorobenzene
20.0 10.0 ug/L 06/03/23 07:10 1<10.02-Butanone (MEK)
5.00 0.880 ug/L 06/03/23 07:10 1<0.8802-Hexanone
5.00 1.10 ug/L 06/03/23 07:10 1<1.104-Methyl-2-pentanone (MIBK)
20.0 10.0 ug/L 06/03/23 07:10 1<10.0Acetone
10.0 3.50 ug/L 06/03/23 07:10 1<3.50Acrylonitrile
1.00 0.150 ug/L 06/03/23 07:10 1<0.150Benzene
1.00 0.480 ug/L 06/03/23 07:10 1<0.480Bromochloromethane
1.00 0.170 ug/L 06/03/23 07:10 1<0.170Bromodichloromethane
1.00 0.220 ug/L 06/03/23 07:10 1<0.220Bromoform
1.00 0.140 ug/L 06/03/23 07:10 1<0.140Bromomethane
5.00 1.50 ug/L 06/03/23 07:10 1<1.50Carbon disulfide
1.00 0.170 ug/L 06/03/23 07:10 1<0.170Carbon tetrachloride
1.00 0.170 ug/L 06/03/23 07:10 1<0.170Chlorobenzene
1.00 0.230 ug/L 06/03/23 07:10 1<0.230Chloroethane
1.00 0.180 ug/L 06/03/23 07:10 1<0.180Chloroform
1.00 0.130 ug/L 06/03/23 07:10 1<0.130Chloromethane
1.00 0.150 ug/L 06/03/23 07:10 10.278 Jcis-1,2-Dichloroethene
1.00 0.200 ug/L 06/03/23 07:10 1<0.200cis-1,3-Dichloropropene
1.00 0.170 ug/L 06/03/23 07:10 1<0.170Dibromochloromethane
1.00 0.270 ug/L 06/03/23 07:10 1<0.270Dibromomethane
1.00 0.200 ug/L 06/03/23 07:10 1<0.200Dichlorodifluoromethane
1.00 0.130 ug/L 06/03/23 07:10 1<0.130Ethylbenzene
5.00 1.70 ug/L 06/03/23 07:10 1<1.70Iodomethane
1.00 0.230 ug/L 06/03/23 07:10 1<0.230Methylene Chloride
1.00 0.110 ug/L 06/03/23 07:10 1<0.110Styrene
1.00 0.170 ug/L 06/03/23 07:10 1<0.170Tetrachloroethene
1.00 0.140 ug/L 06/03/23 07:10 1<0.140Toluene
1.00 0.210 ug/L 06/03/23 07:10 1<0.210trans-1,2-Dichloroethene
1.00 0.150 ug/L 06/03/23 07:10 1<0.150trans-1,3-Dichloropropene
1.00 0.700 ug/L 06/03/23 07:10 1<0.700trans-1,4-Dichloro-2-butene
Eurofins Raleigh
Page 18 of 63 6/6/2023
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Client Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Lab Sample ID: 752-7507-5Client Sample ID: 7601-MW9
Matrix: WaterDate Collected: 05/23/23 09:35
Date Received: 05/25/23 10:00
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
<0.150 1.00 0.150 ug/L 06/03/23 07:10 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Trichloroethene
1.00 0.240 ug/L 06/03/23 07:10 1<0.240Trichlorofluoromethane
5.00 0.950 ug/L 06/03/23 07:10 1<0.950Vinyl acetate
1.00 0.320 ug/L 06/03/23 07:10 1<0.320Vinyl chloride
3.00 0.450 ug/L 06/03/23 07:10 1<0.450Xylenes, Total
4-Bromofluorobenzene (Surr)90 53-136 06/03/23 07:10 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)84 06/03/23 07:10 167-129
Toluene-d8 (Surr)76 06/03/23 07:10 159-134
Method: SW846 8270E - Semivolatile Organic Compounds (GC/MS)
RL MDL
<2.20 10.0 2.20 ug/L 05/27/23 12:41 05/29/23 23:24 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Diethyl phthalate
2,4,6-Tribromophenol (Surr)63 30-130 05/27/23 12:41 05/29/23 23:24 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
2-Fluorobiphenyl 63 05/27/23 12:41 05/29/23 23:24 125-130
2-Fluorophenol (Surr)33 05/27/23 12:41 05/29/23 23:24 110-130
Nitrobenzene-d5 (Surr)71 05/27/23 12:41 05/29/23 23:24 130-130
Phenol-d5 (Surr)22 05/27/23 12:41 05/29/23 23:24 110-130
Terphenyl-d14 (Surr)72 05/27/23 12:41 05/29/23 23:24 135-131
Method: SW846 6010D - Metals (ICP) - Total Recoverable
RL MDL
<6.40 20.0 6.40 ug/L 05/30/23 06:51 05/30/23 14:48 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Arsenic
10.0 4.40 ug/L 05/30/23 06:51 05/30/23 14:48 17.90 JBarium
4.00 0.300 ug/L 05/30/23 06:51 05/30/23 14:48 1<0.300Beryllium
5.00 0.440 ug/L 05/30/23 06:51 05/30/23 14:48 1<0.440Cadmium
10.0 1.10 ug/L 05/30/23 06:51 05/30/23 14:48 1<1.10Chromium
10.0 1.40 ug/L 05/30/23 06:51 05/30/23 14:48 1<1.40Cobalt
20.0 3.20 ug/L 05/30/23 06:51 05/30/23 14:48 1<3.20Copper
10.0 6.60 ug/L 05/30/23 06:51 05/30/23 14:48 1<6.60Lead
40.0 3.30 ug/L 05/30/23 06:51 05/30/23 14:48 1<3.30Nickel
20.0 10.0 ug/L 05/30/23 06:51 05/30/23 14:48 1<10.0Selenium
10.0 1.50 ug/L 05/30/23 06:51 05/30/23 14:48 1<1.50Silver
10.0 1.00 ug/L 05/30/23 06:51 05/30/23 14:48 11.83 JVanadium
20.0 8.70 ug/L 05/30/23 06:51 05/30/23 14:48 1<8.70Zinc
Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable
RL MDL
<0.340 5.00 0.340 ug/L 05/30/23 06:51 05/30/23 20:48 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Antimony
1.00 0.260 ug/L 05/30/23 06:51 05/30/23 20:48 1<0.260Thallium
Method: SW846 7470A - Mercury (CVAA)
RL MDL
<0.0800 0.200 0.0800 ug/L 05/30/23 10:34 05/31/23 09:55 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Mercury
Eurofins Raleigh
Page 19 of 63 6/6/2023
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Client Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Lab Sample ID: 752-7507-6Client Sample ID: 7601-SW1
Matrix: WaterDate Collected: 05/23/23 10:35
Date Received: 05/25/23 10:00
Method: SW846 8260 SIM - 1,4-Dioxane by SIM
RL MDL
1.23 0.500 0.320 ug/L 05/31/23 16:53 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,4-Dioxane
4-Bromofluorobenzene (Surr)93 70-130 05/31/23 16:53 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Method: SW846 8260D - Volatile Organic Compounds by GC/MS
RL MDL
<0.170 1.00 0.170 ug/L 06/03/23 07:39 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1,2-Tetrachloroethane
1.00 0.120 ug/L 06/03/23 07:39 1<0.1201,1,1-Trichloroethane
1.00 0.280 ug/L 06/03/23 07:39 1<0.2801,1,2,2-Tetrachloroethane
1.00 0.140 ug/L 06/03/23 07:39 1<0.1401,1,2-Trichloroethane
1.00 0.130 ug/L 06/03/23 07:39 1<0.1301,1-Dichloroethane
1.00 0.210 ug/L 06/03/23 07:39 1<0.2101,1-Dichloroethene
1.00 0.490 ug/L 06/03/23 07:39 1<0.4901,2,3-Trichloropropane
1.00 0.480 ug/L 06/03/23 07:39 1<0.4801,2-Dibromo-3-Chloropropane
1.00 0.660 ug/L 06/03/23 07:39 1<0.6601,2-Dibromoethane
1.00 0.190 ug/L 06/03/23 07:39 1<0.1901,2-Dichlorobenzene
1.00 0.210 ug/L 06/03/23 07:39 1<0.2101,2-Dichloroethane
1.00 0.100 ug/L 06/03/23 07:39 1<0.1001,2-Dichloropropane
1.00 0.190 ug/L 06/03/23 07:39 1<0.1901,4-Dichlorobenzene
20.0 10.0 ug/L 06/03/23 07:39 1<10.02-Butanone (MEK)
5.00 0.880 ug/L 06/03/23 07:39 1<0.8802-Hexanone
5.00 1.10 ug/L 06/03/23 07:39 1<1.104-Methyl-2-pentanone (MIBK)
20.0 10.0 ug/L 06/03/23 07:39 1<10.0Acetone
10.0 3.50 ug/L 06/03/23 07:39 1<3.50Acrylonitrile
1.00 0.150 ug/L 06/03/23 07:39 1<0.150Benzene
1.00 0.480 ug/L 06/03/23 07:39 1<0.480Bromochloromethane
1.00 0.170 ug/L 06/03/23 07:39 1<0.170Bromodichloromethane
1.00 0.220 ug/L 06/03/23 07:39 1<0.220Bromoform
1.00 0.140 ug/L 06/03/23 07:39 1<0.140Bromomethane
5.00 1.50 ug/L 06/03/23 07:39 1<1.50Carbon disulfide
1.00 0.170 ug/L 06/03/23 07:39 1<0.170Carbon tetrachloride
1.00 0.170 ug/L 06/03/23 07:39 1<0.170Chlorobenzene
1.00 0.230 ug/L 06/03/23 07:39 1<0.230Chloroethane
1.00 0.180 ug/L 06/03/23 07:39 1<0.180Chloroform
1.00 0.130 ug/L 06/03/23 07:39 1<0.130Chloromethane
1.00 0.150 ug/L 06/03/23 07:39 1<0.150cis-1,2-Dichloroethene
1.00 0.200 ug/L 06/03/23 07:39 1<0.200cis-1,3-Dichloropropene
1.00 0.170 ug/L 06/03/23 07:39 1<0.170Dibromochloromethane
1.00 0.270 ug/L 06/03/23 07:39 1<0.270Dibromomethane
1.00 0.130 ug/L 06/03/23 07:39 1<0.130Ethylbenzene
5.00 1.70 ug/L 06/03/23 07:39 1<1.70Iodomethane
1.00 0.230 ug/L 06/03/23 07:39 1<0.230Methylene Chloride
1.00 0.110 ug/L 06/03/23 07:39 1<0.110Styrene
1.00 0.170 ug/L 06/03/23 07:39 1<0.170Tetrachloroethene
1.00 0.140 ug/L 06/03/23 07:39 1<0.140Toluene
1.00 0.210 ug/L 06/03/23 07:39 1<0.210trans-1,2-Dichloroethene
1.00 0.150 ug/L 06/03/23 07:39 1<0.150trans-1,3-Dichloropropene
1.00 0.700 ug/L 06/03/23 07:39 1<0.700trans-1,4-Dichloro-2-butene
1.00 0.150 ug/L 06/03/23 07:39 1<0.150Trichloroethene
Eurofins Raleigh
Page 20 of 63 6/6/2023
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Client Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Lab Sample ID: 752-7507-6Client Sample ID: 7601-SW1
Matrix: WaterDate Collected: 05/23/23 10:35
Date Received: 05/25/23 10:00
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
<0.240 1.00 0.240 ug/L 06/03/23 07:39 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Trichlorofluoromethane
5.00 0.950 ug/L 06/03/23 07:39 1<0.950Vinyl acetate
1.00 0.320 ug/L 06/03/23 07:39 1<0.320Vinyl chloride
3.00 0.450 ug/L 06/03/23 07:39 1<0.450Xylenes, Total
4-Bromofluorobenzene (Surr)87 53-136 06/03/23 07:39 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)82 06/03/23 07:39 167-129
Toluene-d8 (Surr)78 06/03/23 07:39 159-134
Method: SW846 6010D - Metals (ICP) - Total Recoverable
RL MDL
<6.40 20.0 6.40 ug/L 05/30/23 06:22 05/30/23 15:51 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Arsenic
10.0 4.40 ug/L 05/30/23 06:22 05/30/23 15:51 145.5Barium
4.00 0.300 ug/L 05/30/23 06:22 05/30/23 15:51 1<0.300Beryllium
5.00 0.440 ug/L 05/30/23 06:22 05/30/23 15:51 1<0.440Cadmium
10.0 1.10 ug/L 05/30/23 06:22 05/30/23 15:51 1<1.10Chromium
10.0 1.40 ug/L 05/30/23 06:22 05/30/23 15:51 13.88 JCobalt
20.0 3.20 ug/L 05/30/23 06:22 05/30/23 15:51 1<3.20Copper
10.0 6.60 ug/L 05/30/23 06:22 05/30/23 15:51 1<6.60Lead
40.0 3.30 ug/L 05/30/23 06:22 05/30/23 15:51 1<3.30Nickel
20.0 10.0 ug/L 05/30/23 06:22 05/30/23 15:51 1<10.0Selenium
10.0 1.50 ug/L 05/30/23 06:22 05/30/23 15:51 1<1.50Silver
10.0 1.00 ug/L 05/30/23 06:22 05/30/23 15:51 15.09 JVanadium
20.0 8.70 ug/L 05/30/23 06:22 05/30/23 15:51 1<8.70Zinc
Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable
RL MDL
<0.340 5.00 0.340 ug/L 05/30/23 06:22 05/30/23 23:27 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Antimony
1.00 0.260 ug/L 05/30/23 06:22 05/30/23 23:27 1<0.260Thallium
Lab Sample ID: 752-7507-7Client Sample ID: 7601-SW2
Matrix: WaterDate Collected: 05/23/23 11:16
Date Received: 05/25/23 10:00
Method: SW846 8260 SIM - 1,4-Dioxane by SIM
RL MDL
19.4 0.500 0.320 ug/L 05/31/23 17:18 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,4-Dioxane
4-Bromofluorobenzene (Surr)88 70-130 05/31/23 17:18 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Method: SW846 8260D - Volatile Organic Compounds by GC/MS
RL MDL
<0.170 1.00 0.170 ug/L 06/03/23 08:09 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1,2-Tetrachloroethane
1.00 0.120 ug/L 06/03/23 08:09 1<0.1201,1,1-Trichloroethane
1.00 0.280 ug/L 06/03/23 08:09 1<0.2801,1,2,2-Tetrachloroethane
1.00 0.140 ug/L 06/03/23 08:09 1<0.1401,1,2-Trichloroethane
1.00 0.130 ug/L 06/03/23 08:09 1<0.1301,1-Dichloroethane
1.00 0.210 ug/L 06/03/23 08:09 1<0.2101,1-Dichloroethene
1.00 0.490 ug/L 06/03/23 08:09 1<0.4901,2,3-Trichloropropane
Eurofins Raleigh
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Client Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Lab Sample ID: 752-7507-7Client Sample ID: 7601-SW2
Matrix: WaterDate Collected: 05/23/23 11:16
Date Received: 05/25/23 10:00
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
<0.480 1.00 0.480 ug/L 06/03/23 08:09 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,2-Dibromo-3-Chloropropane
1.00 0.660 ug/L 06/03/23 08:09 1<0.6601,2-Dibromoethane
1.00 0.190 ug/L 06/03/23 08:09 1<0.1901,2-Dichlorobenzene
1.00 0.210 ug/L 06/03/23 08:09 1<0.2101,2-Dichloroethane
1.00 0.100 ug/L 06/03/23 08:09 1<0.1001,2-Dichloropropane
1.00 0.190 ug/L 06/03/23 08:09 1<0.1901,4-Dichlorobenzene
20.0 10.0 ug/L 06/03/23 08:09 1<10.02-Butanone (MEK)
5.00 0.880 ug/L 06/03/23 08:09 1<0.8802-Hexanone
5.00 1.10 ug/L 06/03/23 08:09 1<1.104-Methyl-2-pentanone (MIBK)
20.0 10.0 ug/L 06/03/23 08:09 1<10.0Acetone
10.0 3.50 ug/L 06/03/23 08:09 1<3.50Acrylonitrile
1.00 0.150 ug/L 06/03/23 08:09 1<0.150Benzene
1.00 0.480 ug/L 06/03/23 08:09 1<0.480Bromochloromethane
1.00 0.170 ug/L 06/03/23 08:09 1<0.170Bromodichloromethane
1.00 0.220 ug/L 06/03/23 08:09 1<0.220Bromoform
1.00 0.140 ug/L 06/03/23 08:09 1<0.140Bromomethane
5.00 1.50 ug/L 06/03/23 08:09 1<1.50Carbon disulfide
1.00 0.170 ug/L 06/03/23 08:09 1<0.170Carbon tetrachloride
1.00 0.170 ug/L 06/03/23 08:09 1<0.170Chlorobenzene
1.00 0.230 ug/L 06/03/23 08:09 1<0.230Chloroethane
1.00 0.180 ug/L 06/03/23 08:09 1<0.180Chloroform
1.00 0.130 ug/L 06/03/23 08:09 1<0.130Chloromethane
1.00 0.150 ug/L 06/03/23 08:09 1<0.150cis-1,2-Dichloroethene
1.00 0.200 ug/L 06/03/23 08:09 1<0.200cis-1,3-Dichloropropene
1.00 0.170 ug/L 06/03/23 08:09 1<0.170Dibromochloromethane
1.00 0.270 ug/L 06/03/23 08:09 1<0.270Dibromomethane
1.00 0.130 ug/L 06/03/23 08:09 1<0.130Ethylbenzene
5.00 1.70 ug/L 06/03/23 08:09 1<1.70Iodomethane
1.00 0.230 ug/L 06/03/23 08:09 1<0.230Methylene Chloride
1.00 0.110 ug/L 06/03/23 08:09 1<0.110Styrene
1.00 0.170 ug/L 06/03/23 08:09 1<0.170Tetrachloroethene
1.00 0.140 ug/L 06/03/23 08:09 1<0.140Toluene
1.00 0.210 ug/L 06/03/23 08:09 1<0.210trans-1,2-Dichloroethene
1.00 0.150 ug/L 06/03/23 08:09 1<0.150trans-1,3-Dichloropropene
1.00 0.700 ug/L 06/03/23 08:09 1<0.700trans-1,4-Dichloro-2-butene
1.00 0.150 ug/L 06/03/23 08:09 1<0.150Trichloroethene
1.00 0.240 ug/L 06/03/23 08:09 1<0.240Trichlorofluoromethane
5.00 0.950 ug/L 06/03/23 08:09 1<0.950Vinyl acetate
1.00 0.320 ug/L 06/03/23 08:09 1<0.320Vinyl chloride
3.00 0.450 ug/L 06/03/23 08:09 1<0.450Xylenes, Total
4-Bromofluorobenzene (Surr)85 53-136 06/03/23 08:09 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)84 06/03/23 08:09 167-129
Toluene-d8 (Surr)77 06/03/23 08:09 159-134
Method: SW846 6010D - Metals (ICP) - Total Recoverable
RL MDL
<6.40 20.0 6.40 ug/L 05/30/23 06:22 05/30/23 15:54 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Arsenic
10.0 4.40 ug/L 05/30/23 06:22 05/30/23 15:54 132.8Barium
Eurofins Raleigh
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Client Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Lab Sample ID: 752-7507-7Client Sample ID: 7601-SW2
Matrix: WaterDate Collected: 05/23/23 11:16
Date Received: 05/25/23 10:00
Method: SW846 6010D - Metals (ICP) - Total Recoverable (Continued)
RL MDL
<0.300 4.00 0.300 ug/L 05/30/23 06:22 05/30/23 15:54 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Beryllium
5.00 0.440 ug/L 05/30/23 06:22 05/30/23 15:54 1<0.440Cadmium
10.0 1.10 ug/L 05/30/23 06:22 05/30/23 15:54 1<1.10Chromium
10.0 1.40 ug/L 05/30/23 06:22 05/30/23 15:54 1<1.40Cobalt
20.0 3.20 ug/L 05/30/23 06:22 05/30/23 15:54 1<3.20Copper
10.0 6.60 ug/L 05/30/23 06:22 05/30/23 15:54 1<6.60Lead
40.0 3.30 ug/L 05/30/23 06:22 05/30/23 15:54 1<3.30Nickel
20.0 10.0 ug/L 05/30/23 06:22 05/30/23 15:54 1<10.0Selenium
10.0 1.50 ug/L 05/30/23 06:22 05/30/23 15:54 1<1.50Silver
10.0 1.00 ug/L 05/30/23 06:22 05/30/23 15:54 1<1.00Vanadium
20.0 8.70 ug/L 05/30/23 06:22 05/30/23 15:54 1<8.70Zinc
Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable
RL MDL
<0.340 5.00 0.340 ug/L 05/30/23 06:22 05/30/23 23:31 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Antimony
1.00 0.260 ug/L 05/30/23 06:22 05/30/23 23:31 1<0.260Thallium
Lab Sample ID: 752-7507-8Client Sample ID: 7601-SW3
Matrix: WaterDate Collected: 05/24/23 12:35
Date Received: 05/25/23 10:00
Method: SW846 8260 SIM - 1,4-Dioxane by SIM
RL MDL
4.58 0.500 0.320 ug/L 05/31/23 17:43 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,4-Dioxane
4-Bromofluorobenzene (Surr)97 70-130 05/31/23 17:43 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Method: SW846 8260D - Volatile Organic Compounds by GC/MS
RL MDL
<0.170 1.00 0.170 ug/L 06/03/23 08:39 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1,2-Tetrachloroethane
1.00 0.120 ug/L 06/03/23 08:39 1<0.1201,1,1-Trichloroethane
1.00 0.280 ug/L 06/03/23 08:39 1<0.2801,1,2,2-Tetrachloroethane
1.00 0.140 ug/L 06/03/23 08:39 1<0.1401,1,2-Trichloroethane
1.00 0.130 ug/L 06/03/23 08:39 1<0.1301,1-Dichloroethane
1.00 0.210 ug/L 06/03/23 08:39 1<0.2101,1-Dichloroethene
1.00 0.490 ug/L 06/03/23 08:39 1<0.4901,2,3-Trichloropropane
1.00 0.480 ug/L 06/03/23 08:39 1<0.4801,2-Dibromo-3-Chloropropane
1.00 0.660 ug/L 06/03/23 08:39 1<0.6601,2-Dibromoethane
1.00 0.190 ug/L 06/03/23 08:39 1<0.1901,2-Dichlorobenzene
1.00 0.210 ug/L 06/03/23 08:39 1<0.2101,2-Dichloroethane
1.00 0.100 ug/L 06/03/23 08:39 1<0.1001,2-Dichloropropane
1.00 0.190 ug/L 06/03/23 08:39 1<0.1901,4-Dichlorobenzene
20.0 10.0 ug/L 06/03/23 08:39 1<10.02-Butanone (MEK)
5.00 0.880 ug/L 06/03/23 08:39 1<0.8802-Hexanone
5.00 1.10 ug/L 06/03/23 08:39 1<1.104-Methyl-2-pentanone (MIBK)
20.0 10.0 ug/L 06/03/23 08:39 1<10.0Acetone
10.0 3.50 ug/L 06/03/23 08:39 1<3.50Acrylonitrile
1.00 0.150 ug/L 06/03/23 08:39 1<0.150Benzene
1.00 0.480 ug/L 06/03/23 08:39 1<0.480Bromochloromethane
1.00 0.170 ug/L 06/03/23 08:39 1<0.170Bromodichloromethane
Eurofins Raleigh
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Client Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Lab Sample ID: 752-7507-8Client Sample ID: 7601-SW3
Matrix: WaterDate Collected: 05/24/23 12:35
Date Received: 05/25/23 10:00
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
<0.220 1.00 0.220 ug/L 06/03/23 08:39 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Bromoform
1.00 0.140 ug/L 06/03/23 08:39 1<0.140Bromomethane
5.00 1.50 ug/L 06/03/23 08:39 1<1.50Carbon disulfide
1.00 0.170 ug/L 06/03/23 08:39 1<0.170Carbon tetrachloride
1.00 0.170 ug/L 06/03/23 08:39 1<0.170Chlorobenzene
1.00 0.230 ug/L 06/03/23 08:39 1<0.230Chloroethane
1.00 0.180 ug/L 06/03/23 08:39 10.725 JChloroform
1.00 0.130 ug/L 06/03/23 08:39 1<0.130Chloromethane
1.00 0.150 ug/L 06/03/23 08:39 1<0.150cis-1,2-Dichloroethene
1.00 0.200 ug/L 06/03/23 08:39 1<0.200cis-1,3-Dichloropropene
1.00 0.170 ug/L 06/03/23 08:39 1<0.170Dibromochloromethane
1.00 0.270 ug/L 06/03/23 08:39 1<0.270Dibromomethane
1.00 0.130 ug/L 06/03/23 08:39 1<0.130Ethylbenzene
5.00 1.70 ug/L 06/03/23 08:39 1<1.70Iodomethane
1.00 0.230 ug/L 06/03/23 08:39 1<0.230Methylene Chloride
1.00 0.110 ug/L 06/03/23 08:39 1<0.110Styrene
1.00 0.170 ug/L 06/03/23 08:39 1<0.170Tetrachloroethene
1.00 0.140 ug/L 06/03/23 08:39 1<0.140Toluene
1.00 0.210 ug/L 06/03/23 08:39 1<0.210trans-1,2-Dichloroethene
1.00 0.150 ug/L 06/03/23 08:39 1<0.150trans-1,3-Dichloropropene
1.00 0.700 ug/L 06/03/23 08:39 1<0.700trans-1,4-Dichloro-2-butene
1.00 0.150 ug/L 06/03/23 08:39 1<0.150Trichloroethene
1.00 0.240 ug/L 06/03/23 08:39 1<0.240Trichlorofluoromethane
5.00 0.950 ug/L 06/03/23 08:39 1<0.950Vinyl acetate
1.00 0.320 ug/L 06/03/23 08:39 1<0.320Vinyl chloride
3.00 0.450 ug/L 06/03/23 08:39 1<0.450Xylenes, Total
4-Bromofluorobenzene (Surr)88 53-136 06/03/23 08:39 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)88 06/03/23 08:39 167-129
Toluene-d8 (Surr)76 06/03/23 08:39 159-134
Method: SW846 6010D - Metals (ICP) - Total Recoverable
RL MDL
<6.40 20.0 6.40 ug/L 05/30/23 06:22 05/30/23 15:58 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Arsenic
10.0 4.40 ug/L 05/30/23 06:22 05/30/23 15:58 120.8Barium
4.00 0.300 ug/L 05/30/23 06:22 05/30/23 15:58 1<0.300Beryllium
5.00 0.440 ug/L 05/30/23 06:22 05/30/23 15:58 1<0.440Cadmium
10.0 1.10 ug/L 05/30/23 06:22 05/30/23 15:58 1<1.10Chromium
10.0 1.40 ug/L 05/30/23 06:22 05/30/23 15:58 1<1.40Cobalt
20.0 3.20 ug/L 05/30/23 06:22 05/30/23 15:58 1<3.20Copper
10.0 6.60 ug/L 05/30/23 06:22 05/30/23 15:58 1<6.60Lead
40.0 3.30 ug/L 05/30/23 06:22 05/30/23 15:58 1<3.30Nickel
20.0 10.0 ug/L 05/30/23 06:22 05/30/23 15:58 1<10.0Selenium
10.0 1.50 ug/L 05/30/23 06:22 05/30/23 15:58 1<1.50Silver
10.0 1.00 ug/L 05/30/23 06:22 05/30/23 15:58 11.73 JVanadium
20.0 8.70 ug/L 05/30/23 06:22 05/30/23 15:58 1<8.70Zinc
Eurofins Raleigh
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Client Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Lab Sample ID: 752-7507-8Client Sample ID: 7601-SW3
Matrix: WaterDate Collected: 05/24/23 12:35
Date Received: 05/25/23 10:00
Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable
RL MDL
<0.340 5.00 0.340 ug/L 05/30/23 06:22 05/30/23 23:35 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Antimony
1.00 0.260 ug/L 05/30/23 06:22 05/30/23 23:35 1<0.260Thallium
Lab Sample ID: 752-7507-9Client Sample ID: 7601-SW4
Matrix: WaterDate Collected: 05/24/23 13:07
Date Received: 05/25/23 10:00
Method: SW846 8260 SIM - 1,4-Dioxane by SIM
RL MDL
4.05 0.500 0.320 ug/L 05/31/23 18:08 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,4-Dioxane
4-Bromofluorobenzene (Surr)101 70-130 05/31/23 18:08 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Method: SW846 8260D - Volatile Organic Compounds by GC/MS
RL MDL
<0.170 1.00 0.170 ug/L 06/03/23 09:08 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1,2-Tetrachloroethane
1.00 0.120 ug/L 06/03/23 09:08 1<0.1201,1,1-Trichloroethane
1.00 0.280 ug/L 06/03/23 09:08 1<0.2801,1,2,2-Tetrachloroethane
1.00 0.140 ug/L 06/03/23 09:08 1<0.1401,1,2-Trichloroethane
1.00 0.130 ug/L 06/03/23 09:08 1<0.1301,1-Dichloroethane
1.00 0.210 ug/L 06/03/23 09:08 1<0.2101,1-Dichloroethene
1.00 0.490 ug/L 06/03/23 09:08 1<0.4901,2,3-Trichloropropane
1.00 0.480 ug/L 06/03/23 09:08 1<0.4801,2-Dibromo-3-Chloropropane
1.00 0.660 ug/L 06/03/23 09:08 1<0.6601,2-Dibromoethane
1.00 0.190 ug/L 06/03/23 09:08 1<0.1901,2-Dichlorobenzene
1.00 0.210 ug/L 06/03/23 09:08 1<0.2101,2-Dichloroethane
1.00 0.100 ug/L 06/03/23 09:08 1<0.1001,2-Dichloropropane
1.00 0.190 ug/L 06/03/23 09:08 1<0.1901,4-Dichlorobenzene
20.0 10.0 ug/L 06/03/23 09:08 1<10.02-Butanone (MEK)
5.00 0.880 ug/L 06/03/23 09:08 1<0.8802-Hexanone
5.00 1.10 ug/L 06/03/23 09:08 1<1.104-Methyl-2-pentanone (MIBK)
20.0 10.0 ug/L 06/03/23 09:08 1<10.0Acetone
10.0 3.50 ug/L 06/03/23 09:08 1<3.50Acrylonitrile
1.00 0.150 ug/L 06/03/23 09:08 1<0.150Benzene
1.00 0.480 ug/L 06/03/23 09:08 1<0.480Bromochloromethane
1.00 0.170 ug/L 06/03/23 09:08 10.287 JBromodichloromethane
1.00 0.220 ug/L 06/03/23 09:08 1<0.220Bromoform
1.00 0.140 ug/L 06/03/23 09:08 1<0.140Bromomethane
5.00 1.50 ug/L 06/03/23 09:08 1<1.50Carbon disulfide
1.00 0.170 ug/L 06/03/23 09:08 1<0.170Carbon tetrachloride
1.00 0.170 ug/L 06/03/23 09:08 1<0.170Chlorobenzene
1.00 0.230 ug/L 06/03/23 09:08 1<0.230Chloroethane
1.00 0.180 ug/L 06/03/23 09:08 10.733 JChloroform
1.00 0.130 ug/L 06/03/23 09:08 1<0.130Chloromethane
1.00 0.150 ug/L 06/03/23 09:08 1<0.150cis-1,2-Dichloroethene
1.00 0.200 ug/L 06/03/23 09:08 1<0.200cis-1,3-Dichloropropene
1.00 0.170 ug/L 06/03/23 09:08 1<0.170Dibromochloromethane
1.00 0.270 ug/L 06/03/23 09:08 1<0.270Dibromomethane
1.00 0.130 ug/L 06/03/23 09:08 1<0.130Ethylbenzene
Eurofins Raleigh
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Client Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Lab Sample ID: 752-7507-9Client Sample ID: 7601-SW4
Matrix: WaterDate Collected: 05/24/23 13:07
Date Received: 05/25/23 10:00
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
<1.70 5.00 1.70 ug/L 06/03/23 09:08 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Iodomethane
1.00 0.230 ug/L 06/03/23 09:08 1<0.230Methylene Chloride
1.00 0.110 ug/L 06/03/23 09:08 1<0.110Styrene
1.00 0.170 ug/L 06/03/23 09:08 1<0.170Tetrachloroethene
1.00 0.140 ug/L 06/03/23 09:08 1<0.140Toluene
1.00 0.210 ug/L 06/03/23 09:08 1<0.210trans-1,2-Dichloroethene
1.00 0.150 ug/L 06/03/23 09:08 1<0.150trans-1,3-Dichloropropene
1.00 0.700 ug/L 06/03/23 09:08 1<0.700trans-1,4-Dichloro-2-butene
1.00 0.150 ug/L 06/03/23 09:08 1<0.150Trichloroethene
1.00 0.240 ug/L 06/03/23 09:08 1<0.240Trichlorofluoromethane
5.00 0.950 ug/L 06/03/23 09:08 1<0.950Vinyl acetate
1.00 0.320 ug/L 06/03/23 09:08 1<0.320Vinyl chloride
3.00 0.450 ug/L 06/03/23 09:08 1<0.450Xylenes, Total
4-Bromofluorobenzene (Surr)87 53-136 06/03/23 09:08 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)83 06/03/23 09:08 167-129
Toluene-d8 (Surr)78 06/03/23 09:08 159-134
Method: SW846 6010D - Metals (ICP) - Total Recoverable
RL MDL
<6.40 20.0 6.40 ug/L 05/30/23 06:22 05/30/23 16:01 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Arsenic
10.0 4.40 ug/L 05/30/23 06:22 05/30/23 16:01 119.1Barium
4.00 0.300 ug/L 05/30/23 06:22 05/30/23 16:01 1<0.300Beryllium
5.00 0.440 ug/L 05/30/23 06:22 05/30/23 16:01 1<0.440Cadmium
10.0 1.10 ug/L 05/30/23 06:22 05/30/23 16:01 1<1.10Chromium
10.0 1.40 ug/L 05/30/23 06:22 05/30/23 16:01 1<1.40Cobalt
20.0 3.20 ug/L 05/30/23 06:22 05/30/23 16:01 1<3.20Copper
10.0 6.60 ug/L 05/30/23 06:22 05/30/23 16:01 1<6.60Lead
40.0 3.30 ug/L 05/30/23 06:22 05/30/23 16:01 1<3.30Nickel
20.0 10.0 ug/L 05/30/23 06:22 05/30/23 16:01 1<10.0Selenium
10.0 1.50 ug/L 05/30/23 06:22 05/30/23 16:01 1<1.50Silver
10.0 1.00 ug/L 05/30/23 06:22 05/30/23 16:01 11.59 JVanadium
20.0 8.70 ug/L 05/30/23 06:22 05/30/23 16:01 1<8.70Zinc
Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable
RL MDL
<0.340 5.00 0.340 ug/L 05/30/23 06:22 05/30/23 23:39 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Antimony
1.00 0.260 ug/L 05/30/23 06:22 05/30/23 23:39 1<0.260Thallium
Lab Sample ID: 752-7507-10Client Sample ID: 7601-Trip Blank
Matrix: WaterDate Collected: 05/22/23 14:45
Date Received: 05/25/23 10:00
Method: SW846 8260D - Volatile Organic Compounds by GC/MS
RL MDL
<0.170 1.00 0.170 ug/L 06/02/23 22:48 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1,2-Tetrachloroethane
1.00 0.120 ug/L 06/02/23 22:48 1<0.1201,1,1-Trichloroethane
1.00 0.280 ug/L 06/02/23 22:48 1<0.2801,1,2,2-Tetrachloroethane
1.00 0.140 ug/L 06/02/23 22:48 1<0.1401,1,2-Trichloroethane
1.00 0.130 ug/L 06/02/23 22:48 1<0.1301,1-Dichloroethane
Eurofins Raleigh
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Client Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Lab Sample ID: 752-7507-10Client Sample ID: 7601-Trip Blank
Matrix: WaterDate Collected: 05/22/23 14:45
Date Received: 05/25/23 10:00
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
<0.210 1.00 0.210 ug/L 06/02/23 22:48 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1-Dichloroethene
1.00 0.490 ug/L 06/02/23 22:48 1<0.4901,2,3-Trichloropropane
1.00 0.480 ug/L 06/02/23 22:48 1<0.4801,2-Dibromo-3-Chloropropane
1.00 0.660 ug/L 06/02/23 22:48 1<0.6601,2-Dibromoethane
1.00 0.190 ug/L 06/02/23 22:48 1<0.1901,2-Dichlorobenzene
1.00 0.210 ug/L 06/02/23 22:48 1<0.2101,2-Dichloroethane
1.00 0.100 ug/L 06/02/23 22:48 1<0.1001,2-Dichloropropane
1.00 0.190 ug/L 06/02/23 22:48 1<0.1901,4-Dichlorobenzene
20.0 10.0 ug/L 06/02/23 22:48 1<10.02-Butanone (MEK)
5.00 0.880 ug/L 06/02/23 22:48 1<0.8802-Hexanone
5.00 1.10 ug/L 06/02/23 22:48 1<1.104-Methyl-2-pentanone (MIBK)
20.0 10.0 ug/L 06/02/23 22:48 1<10.0Acetone
10.0 3.50 ug/L 06/02/23 22:48 1<3.50Acrylonitrile
1.00 0.150 ug/L 06/02/23 22:48 1<0.150Benzene
1.00 0.480 ug/L 06/02/23 22:48 1<0.480Bromochloromethane
1.00 0.170 ug/L 06/02/23 22:48 1<0.170Bromodichloromethane
1.00 0.220 ug/L 06/02/23 22:48 1<0.220Bromoform
1.00 0.140 ug/L 06/02/23 22:48 1<0.140Bromomethane
5.00 1.50 ug/L 06/02/23 22:48 1<1.50Carbon disulfide
1.00 0.170 ug/L 06/02/23 22:48 1<0.170Carbon tetrachloride
1.00 0.170 ug/L 06/02/23 22:48 1<0.170Chlorobenzene
1.00 0.230 ug/L 06/02/23 22:48 1<0.230Chloroethane
1.00 0.180 ug/L 06/02/23 22:48 10.205 JChloroform
1.00 0.130 ug/L 06/02/23 22:48 1<0.130Chloromethane
1.00 0.150 ug/L 06/02/23 22:48 1<0.150cis-1,2-Dichloroethene
1.00 0.200 ug/L 06/02/23 22:48 1<0.200cis-1,3-Dichloropropene
1.00 0.170 ug/L 06/02/23 22:48 1<0.170Dibromochloromethane
1.00 0.270 ug/L 06/02/23 22:48 1<0.270Dibromomethane
1.00 0.200 ug/L 06/02/23 22:48 1<0.200Dichlorodifluoromethane
1.00 0.130 ug/L 06/02/23 22:48 1<0.130Ethylbenzene
5.00 1.70 ug/L 06/02/23 22:48 1<1.70Iodomethane
1.00 0.230 ug/L 06/02/23 22:48 1<0.230Methylene Chloride
1.00 0.110 ug/L 06/02/23 22:48 1<0.110Styrene
1.00 0.170 ug/L 06/02/23 22:48 1<0.170Tetrachloroethene
1.00 0.140 ug/L 06/02/23 22:48 1<0.140Toluene
1.00 0.210 ug/L 06/02/23 22:48 1<0.210trans-1,2-Dichloroethene
1.00 0.150 ug/L 06/02/23 22:48 1<0.150trans-1,3-Dichloropropene
1.00 0.700 ug/L 06/02/23 22:48 1<0.700trans-1,4-Dichloro-2-butene
1.00 0.150 ug/L 06/02/23 22:48 1<0.150Trichloroethene
1.00 0.240 ug/L 06/02/23 22:48 1<0.240Trichlorofluoromethane
5.00 0.950 ug/L 06/02/23 22:48 1<0.950Vinyl acetate
1.00 0.320 ug/L 06/02/23 22:48 1<0.320Vinyl chloride
3.00 0.450 ug/L 06/02/23 22:48 1<0.450Xylenes, Total
4-Bromofluorobenzene (Surr)87 53-136 06/02/23 22:48 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)91 06/02/23 22:48 167-129
Toluene-d8 (Surr)77 06/02/23 22:48 159-134
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Surrogate Summary
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Method: 8260 SIM - 1,4-Dioxane by SIM
Prep Type: Total/NAMatrix: Water
Lab Sample ID Client Sample ID (70-130)
BFB
100752-7507-1
Percent Surrogate Recovery (Acceptance Limits)
7601-MW10S
107752-7507-2 7601-MW6
82752-7507-3 7601-MW7
105752-7507-3 MS 7601-MW7
105752-7507-3 MSD 7601-MW7
99752-7507-4 7601-MW8
101752-7507-5 7601-MW9
123752-7507-5 MS 7601-MW9
118752-7507-5 MSD 7601-MW9
93752-7507-6 7601-SW1
88752-7507-7 7601-SW2
97752-7507-8 7601-SW3
101752-7507-9 7601-SW4
113LCS 680-781127/20 Lab Control Sample
121LCS 680-781391/3 Lab Control Sample
107LCSD 680-781127/4 Lab Control Sample Dup
114LCSD 680-781391/4 Lab Control Sample Dup
101MB 680-781127/6 Method Blank
110MB 680-781391/6 Method Blank
Surrogate Legend
BFB = 4-Bromofluorobenzene (Surr)
Method: 8260D - Volatile Organic Compounds by GC/MS
Prep Type: Total/NAMatrix: Water
Lab Sample ID Client Sample ID (53-136)(67-129)(59-134)
BFB DBFM TOL
93 90 79752-7507-1
Percent Surrogate Recovery (Acceptance Limits)
7601-MW10S
90 81 75752-7507-2 7601-MW6
89 90 80752-7507-3 7601-MW7
96 83 76752-7507-3 MS 7601-MW7
93 80 76752-7507-3 MSD 7601-MW7
91 86 78752-7507-4 7601-MW8
90 84 76752-7507-5 7601-MW9
87 82 78752-7507-6 7601-SW1
85 84 77752-7507-7 7601-SW2
88 88 76752-7507-8 7601-SW3
87 83 78752-7507-9 7601-SW4
87 91 77752-7507-10 7601-Trip Blank
90 78 78LCS 752-3101/5 Lab Control Sample
90 78 77LCS 752-3113/5 Lab Control Sample
94 80 76LCSD 752-3101/6 Lab Control Sample Dup
90 78 75LCSD 752-3113/6 Lab Control Sample Dup
91 83 76MB 752-3101/8 Method Blank
93 82 75MB 752-3113/8 Method Blank
88 80 77MRL 752-3101/4 Lab Control Sample
89 83 77MRL 752-3113/4 Lab Control Sample
Surrogate Legend
Eurofins Raleigh
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Surrogate Summary
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
BFB = 4-Bromofluorobenzene (Surr)
DBFM = Dibromofluoromethane (Surr)
TOL = Toluene-d8 (Surr)
Method: 8270E - Semivolatile Organic Compounds (GC/MS)
Prep Type: Total/NAMatrix: Water
Lab Sample ID Client Sample ID (30-130)(25-130)(10-130)(30-130)(10-130)(35-131)
TBP FBP 2FP NBZ PHL TPHL
60 68 31 68 20 74752-7507-1
Percent Surrogate Recovery (Acceptance Limits)
7601-MW10S
57 61 29 2065 61752-7507-2 7601-MW6
62 59 38 2673 73752-7507-3 7601-MW7
67 72 34 2373 82752-7507-3 MS 7601-MW7
58 61 30 2261 77752-7507-3 MSD 7601-MW7
62 61 31 2069 70752-7507-4 7601-MW8
63 63 33 2271 72752-7507-5 7601-MW9
64 67 32 2368 82LCS 680-780784/2-A Lab Control Sample
65 71 35 2374 76MB 680-780784/1-A Method Blank
Surrogate Legend
TBP = 2,4,6-Tribromophenol (Surr)
FBP = 2-Fluorobiphenyl
2FP = 2-Fluorophenol (Surr)
NBZ = Nitrobenzene-d5 (Surr)
PHL = Phenol-d5 (Surr)
TPHL = Terphenyl-d14 (Surr)
Eurofins Raleigh
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QC Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Method: 8260 SIM - 1,4-Dioxane by SIM
Client Sample ID: Method BlankLab Sample ID: MB 680-781127/6
Matrix: Water Prep Type: Total/NA
Analysis Batch: 781127
RL MDL
1,4-Dioxane <0.320 0.500 0.320 ug/L 05/31/23 13:36 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
4-Bromofluorobenzene (Surr)101 70-130 05/31/23 13:36 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-781127/20
Matrix: Water Prep Type: Total/NA
Analysis Batch: 781127
1,4-Dioxane 10.0 9.451 ug/L 95 70-130
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
4-Bromofluorobenzene (Surr)70 -130
Surrogate
113
LCS LCS
Qualifier Limits%Recovery
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 680-781127/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 781127
1,4-Dioxane 10.0 10.10 ug/L 101 70-130 7 30
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
4-Bromofluorobenzene (Surr)70 -130
Surrogate
107
LCSD LCSD
Qualifier Limits%Recovery
Client Sample ID: 7601-MW7Lab Sample ID: 752-7507-3 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 781127
1,4-Dioxane 1.47 10.0 11.68 ug/L 102 70-130
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits
4-Bromofluorobenzene (Surr)70 -130
Surrogate
105
MS MS
Qualifier Limits%Recovery
Client Sample ID: 7601-MW7Lab Sample ID: 752-7507-3 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 781127
1,4-Dioxane 1.47 10.0 11.68 ug/L 102 70-130 0 30
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits LimitRPD
RPD
4-Bromofluorobenzene (Surr)70 -130
Surrogate
105
MSD MSD
Qualifier Limits%Recovery
Eurofins Raleigh
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QC Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Method: 8260 SIM - 1,4-Dioxane by SIM (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 680-781391/6
Matrix: Water Prep Type: Total/NA
Analysis Batch: 781391
RL MDL
1,4-Dioxane <0.320 0.500 0.320 ug/L 06/01/23 15:15 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
4-Bromofluorobenzene (Surr)110 70-130 06/01/23 15:15 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-781391/3
Matrix: Water Prep Type: Total/NA
Analysis Batch: 781391
1,4-Dioxane 10.0 9.727 ug/L 97 70-130
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
4-Bromofluorobenzene (Surr)70 -130
Surrogate
121
LCS LCS
Qualifier Limits%Recovery
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 680-781391/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 781391
1,4-Dioxane 10.0 9.956 ug/L 100 70-130 2 30
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
4-Bromofluorobenzene (Surr)70 -130
Surrogate
114
LCSD LCSD
Qualifier Limits%Recovery
Client Sample ID: 7601-MW9Lab Sample ID: 752-7507-5 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 781391
1,4-Dioxane 0.888 10.0 10.68 ug/L 98 70-130
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits
4-Bromofluorobenzene (Surr)70 -130
Surrogate
123
MS MS
Qualifier Limits%Recovery
Client Sample ID: 7601-MW9Lab Sample ID: 752-7507-5 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 781391
1,4-Dioxane 0.888 10.0 10.54 ug/L 96 70-130 1 30
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits LimitRPD
RPD
4-Bromofluorobenzene (Surr)70 -130
Surrogate
118
MSD MSD
Qualifier Limits%Recovery
Eurofins Raleigh
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QC Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Method: 8260D - Volatile Organic Compounds by GC/MS
Client Sample ID: Method BlankLab Sample ID: MB 752-3101/8
Matrix: Water Prep Type: Total/NA
Analysis Batch: 3101
RL MDL
1,1,1,2-Tetrachloroethane <0.170 1.00 0.170 ug/L 06/02/23 15:55 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
<0.120 0.1201.00 ug/L 06/02/23 15:55 11,1,1-Trichloroethane
<0.280 0.2801.00 ug/L 06/02/23 15:55 11,1,2,2-Tetrachloroethane
<0.140 0.1401.00 ug/L 06/02/23 15:55 11,1,2-Trichloroethane
<0.130 0.1301.00 ug/L 06/02/23 15:55 11,1-Dichloroethane
<0.210 0.2101.00 ug/L 06/02/23 15:55 11,1-Dichloroethene
<0.490 0.4901.00 ug/L 06/02/23 15:55 11,2,3-Trichloropropane
<0.480 0.4801.00 ug/L 06/02/23 15:55 11,2-Dibromo-3-Chloropropane
<0.660 0.6601.00 ug/L 06/02/23 15:55 11,2-Dibromoethane
<0.190 0.1901.00 ug/L 06/02/23 15:55 11,2-Dichlorobenzene
<0.210 0.2101.00 ug/L 06/02/23 15:55 11,2-Dichloroethane
<0.100 0.1001.00 ug/L 06/02/23 15:55 11,2-Dichloropropane
<0.190 0.1901.00 ug/L 06/02/23 15:55 11,4-Dichlorobenzene
<10.0 10.020.0 ug/L 06/02/23 15:55 12-Butanone (MEK)
<0.880 0.8805.00 ug/L 06/02/23 15:55 12-Hexanone
<1.10 1.105.00 ug/L 06/02/23 15:55 14-Methyl-2-pentanone (MIBK)
<10.0 10.020.0 ug/L 06/02/23 15:55 1Acetone
<3.50 3.5010.0 ug/L 06/02/23 15:55 1Acrylonitrile
<0.150 0.1501.00 ug/L 06/02/23 15:55 1Benzene
<0.480 0.4801.00 ug/L 06/02/23 15:55 1Bromochloromethane
<0.170 0.1701.00 ug/L 06/02/23 15:55 1Bromodichloromethane
<0.220 0.2201.00 ug/L 06/02/23 15:55 1Bromoform
<0.140 0.1401.00 ug/L 06/02/23 15:55 1Bromomethane
<1.50 1.505.00 ug/L 06/02/23 15:55 1Carbon disulfide
<0.170 0.1701.00 ug/L 06/02/23 15:55 1Carbon tetrachloride
<0.170 0.1701.00 ug/L 06/02/23 15:55 1Chlorobenzene
<0.230 0.2301.00 ug/L 06/02/23 15:55 1Chloroethane
<0.180 0.1801.00 ug/L 06/02/23 15:55 1Chloroform
<0.130 0.1301.00 ug/L 06/02/23 15:55 1Chloromethane
<0.150 0.1501.00 ug/L 06/02/23 15:55 1cis-1,2-Dichloroethene
<0.200 0.2001.00 ug/L 06/02/23 15:55 1cis-1,3-Dichloropropene
<0.170 0.1701.00 ug/L 06/02/23 15:55 1Dibromochloromethane
<0.270 0.2701.00 ug/L 06/02/23 15:55 1Dibromomethane
<0.200 0.2001.00 ug/L 06/02/23 15:55 1Dichlorodifluoromethane
<0.130 0.1301.00 ug/L 06/02/23 15:55 1Ethylbenzene
<1.70 1.705.00 ug/L 06/02/23 15:55 1Iodomethane
<0.230 0.2301.00 ug/L 06/02/23 15:55 1Methylene Chloride
<0.110 0.1101.00 ug/L 06/02/23 15:55 1Styrene
<0.170 0.1701.00 ug/L 06/02/23 15:55 1Tetrachloroethene
<0.140 0.1401.00 ug/L 06/02/23 15:55 1Toluene
<0.210 0.2101.00 ug/L 06/02/23 15:55 1trans-1,2-Dichloroethene
<0.150 0.1501.00 ug/L 06/02/23 15:55 1trans-1,3-Dichloropropene
<0.700 0.7001.00 ug/L 06/02/23 15:55 1trans-1,4-Dichloro-2-butene
<0.150 0.1501.00 ug/L 06/02/23 15:55 1Trichloroethene
<0.240 0.2401.00 ug/L 06/02/23 15:55 1Trichlorofluoromethane
<0.950 0.9505.00 ug/L 06/02/23 15:55 1Vinyl acetate
<0.320 0.3201.00 ug/L 06/02/23 15:55 1Vinyl chloride
<0.450 0.4503.00 ug/L 06/02/23 15:55 1Xylenes, Total
Eurofins Raleigh
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QC Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 752-3101/8
Matrix: Water Prep Type: Total/NA
Analysis Batch: 3101
4-Bromofluorobenzene (Surr)91 53-136 06/02/23 15:55 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
83 06/02/23 15:55 1Dibromofluoromethane (Surr)67-129
76 06/02/23 15:55 1Toluene-d8 (Surr)59-134
Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-3101/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 3101
1,1,1,2-Tetrachloroethane 20.0 20.79 ug/L 104 71-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
1,1,1-Trichloroethane 20.0 22.95 ug/L 115 72-143
1,1,2,2-Tetrachloroethane 20.0 15.97 ug/L 80 59-133
1,1,2-Trichloroethane 20.0 17.72 ug/L 89 67-120
1,1-Dichloroethane 20.0 18.70 ug/L 94 79-141
1,1-Dichloroethene 20.0 18.65 ug/L 93 75-133
1,2,3-Trichloropropane 20.0 19.67 ug/L 98 69-127
1,2-Dibromo-3-Chloropropane 20.0 20.22 ug/L 101 37-157
1,2-Dibromoethane 20.0 18.59 ug/L 93 66-123
1,2-Dichlorobenzene 20.0 17.84 ug/L 89 76-120
1,2-Dichloroethane 20.0 24.26 ug/L 121 72-151
1,2-Dichloropropane 20.0 16.94 ug/L 85 78-125
1,4-Dichlorobenzene 20.0 18.25 ug/L 91 76-122
2-Butanone (MEK)40.0 36.68 ug/L 92 36-135
2-Hexanone 40.0 28.11 ug/L 70 36-191
4-Methyl-2-pentanone (MIBK)40.0 30.81 ug/L 77 56-166
Acetone 40.0 27.12 ug/L 68 10-158
Acrylonitrile 60.0 43.82 ug/L 73 10-200
Benzene 20.0 18.70 ug/L 94 80-134
Bromochloromethane 20.0 19.80 ug/L 99 74-128
Bromodichloromethane 20.0 23.46 ug/L 117 72-129
Bromoform 20.0 23.10 ug/L 115 73-120
Bromomethane 20.0 11.43 ug/L 57 38-189
Carbon disulfide 20.0 19.31 ug/L 97 65-173
Carbon tetrachloride 20.0 28.00 ug/L 140 68-142
Chlorobenzene 20.0 19.09 ug/L 95 80-120
Chloroethane 20.0 14.66 ug/L 73 45-213
Chloroform 20.0 19.90 ug/L 99 78-138
Chloromethane 20.0 12.59 ug/L 63 56-171
cis-1,2-Dichloroethene 20.0 17.21 ug/L 86 69-120
cis-1,3-Dichloropropene 20.0 20.87 ug/L 104 63-125
Dibromochloromethane 20.0 20.93 ug/L 105 73-120
Dibromomethane 20.0 21.22 ug/L 106 76-124
Dichlorodifluoromethane 20.0 19.79 ug/L 99 25-161
Ethylbenzene 20.0 18.03 ug/L 90 68-124
Iodomethane 20.0 20.88 ug/L 104 34-140
Methylene Chloride 20.0 19.25 ug/L 96 68-128
Styrene 20.0 18.56 ug/L 93 73-120
Tetrachloroethene 20.0 22.99 ug/L 115 40-181
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QC Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-3101/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 3101
Toluene 20.0 18.56 ug/L 93 71-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
trans-1,2-Dichloroethene 20.0 17.62 ug/L 88 75-139
trans-1,3-Dichloropropene 20.0 22.75 ug/L 114 65-152
trans-1,4-Dichloro-2-butene 20.0 21.16 ug/L 106 10-142
Trichloroethene 20.0 20.80 ug/L 104 74-120
Trichlorofluoromethane 20.0 25.31 ug/L 127 68-183
Vinyl acetate 20.0 18.84 ug/L 94 10-198
Vinyl chloride 20.0 10.95 ug/L 55 49-150
Xylenes, Total 60.0 59.58 ug/L 99 77-121
4-Bromofluorobenzene (Surr)53 -136
Surrogate
90
LCS LCS
Qualifier Limits%Recovery
78Dibromofluoromethane (Surr)67 -129
78Toluene-d8 (Surr)59 -134
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-3101/6
Matrix: Water Prep Type: Total/NA
Analysis Batch: 3101
1,1,1,2-Tetrachloroethane 20.0 19.93 ug/L 100 71-120 4 16
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
1,1,1-Trichloroethane 20.0 21.63 ug/L 108 72-143 6 18
1,1,2,2-Tetrachloroethane 20.0 15.96 ug/L 80 59-133 0 16
1,1,2-Trichloroethane 20.0 17.95 ug/L 90 67-120 1 18
1,1-Dichloroethane 20.0 17.16 ug/L 86 79-141 9 19
1,1-Dichloroethene 20.0 16.68 ug/L 83 75-133 11 20
1,2,3-Trichloropropane 20.0 19.73 ug/L 99 69-127 0 17
1,2-Dibromo-3-Chloropropane 20.0 18.40 ug/L 92 37-157 9 18
1,2-Dibromoethane 20.0 18.26 ug/L 91 66-123 2 15
1,2-Dichlorobenzene 20.0 17.01 ug/L 85 76-120 5 16
1,2-Dichloroethane 20.0 23.03 ug/L 115 72-151 5 16
1,2-Dichloropropane 20.0 16.83 ug/L 84 78-125 1 19
1,4-Dichlorobenzene 20.0 17.25 ug/L 86 76-122 6 16
2-Butanone (MEK)40.0 35.49 ug/L 89 36-135 3 19
2-Hexanone 40.0 29.93 ug/L 75 36-191 6 17
4-Methyl-2-pentanone (MIBK)40.0 31.86 ug/L 80 56-166 3 19
Acetone 40.0 27.16 ug/L 68 10-158 0 78
Acrylonitrile 60.0 43.67 ug/L 73 10-200 0 36
Benzene 20.0 17.56 ug/L 88 80-134 6 17
Bromochloromethane 20.0 19.49 ug/L 97 74-128 2 18
Bromodichloromethane 20.0 21.91 ug/L 110 72-129 7 16
Bromoform 20.0 23.11 ug/L 116 73-120 0 44
Bromomethane 20.0 10.62 ug/L 53 38-189 7 27
Carbon disulfide 20.0 17.40 ug/L 87 65-173 10 38
Carbon tetrachloride 20.0 26.28 ug/L 131 68-142 6 17
Chlorobenzene 20.0 18.14 ug/L 91 80-120 5 16
Chloroethane 20.0 14.23 ug/L 71 45-213 3 26
Chloroform 20.0 19.09 ug/L 95 78-138 4 17
Eurofins Raleigh
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QC Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-3101/6
Matrix: Water Prep Type: Total/NA
Analysis Batch: 3101
Chloromethane 20.0 12.29 ug/L 61 56-171 2 28
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
cis-1,2-Dichloroethene 20.0 16.63 ug/L 83 69-120 3 18
cis-1,3-Dichloropropene 20.0 19.80 ug/L 99 63-125 5 17
Dibromochloromethane 20.0 20.43 ug/L 102 73-120 2 16
Dibromomethane 20.0 19.88 ug/L 99 76-124 7 15
Dichlorodifluoromethane 20.0 18.61 ug/L 93 25-161 6 48
Ethylbenzene 20.0 17.23 ug/L 86 68-124 5 16
Iodomethane 20.0 18.87 ug/L 94 34-140 10 15
Methylene Chloride 20.0 18.48 ug/L 92 68-128 4 17
Styrene 20.0 18.52 ug/L 93 73-120 0 23
Tetrachloroethene 20.0 22.34 ug/L 112 40-181 3 26
Toluene 20.0 17.76 ug/L 89 71-120 4 17
trans-1,2-Dichloroethene 20.0 17.32 ug/L 87 75-139 2 19
trans-1,3-Dichloropropene 20.0 22.87 ug/L 114 65-152 1 16
trans-1,4-Dichloro-2-butene 20.0 20.51 ug/L 103 10-142 3 28
Trichloroethene 20.0 20.51 ug/L 103 74-120 1 22
Trichlorofluoromethane 20.0 24.73 ug/L 124 68-183 2 22
Vinyl acetate 20.0 18.49 ug/L 92 10-198 2 21
Vinyl chloride 20.0 10.29 ug/L 51 49-150 6 27
Xylenes, Total 60.0 57.44 ug/L 96 77-121 4 16
4-Bromofluorobenzene (Surr)53 -136
Surrogate
94
LCSD LCSD
Qualifier Limits%Recovery
80Dibromofluoromethane (Surr)67 -129
76Toluene-d8 (Surr)59 -134
Client Sample ID: Lab Control SampleLab Sample ID: MRL 752-3101/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 3101
1,1,1,2-Tetrachloroethane 1.00 1.303 ug/L 130
Analyte
MRL MRL
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
1,1,1-Trichloroethane 1.00 1.375 ug/L 138
1,1,2,2-Tetrachloroethane 1.00 0.9814 J ug/L 98
1,1,2-Trichloroethane 1.00 1.173 ug/L 117
1,1-Dichloroethane 1.00 1.120 ug/L 112
1,1-Dichloroethene 1.00 0.9473 J ug/L 95
1,2,3-Trichloropropane 1.00 1.340 ug/L 134
1,2-Dibromo-3-Chloropropane 1.00 2.288 ug/L 229
1,2-Dibromoethane 1.00 1.103 ug/L 110
1,2-Dichlorobenzene 1.00 1.089 ug/L 109
1,2-Dichloroethane 1.00 1.476 ug/L 148
1,2-Dichloropropane 1.00 1.046 ug/L 105
1,4-Dichlorobenzene 1.00 1.409 ug/L 141
2-Butanone (MEK)2.00 <10.0 ug/L 402
2-Hexanone 2.00 1.142 J ug/L 57
4-Methyl-2-pentanone (MIBK)2.00 1.406 J ug/L 70
Acetone 2.00 <10.0 ug/L 10
Eurofins Raleigh
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QC Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: MRL 752-3101/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 3101
Acrylonitrile 5.00 3.688 J ug/L 74
Analyte
MRL MRL
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Benzene 1.00 1.236 ug/L 124
Bromochloromethane 1.00 1.199 ug/L 120
Bromodichloromethane 1.00 1.430 ug/L 143
Bromoform 1.00 1.069 ug/L 107
Bromomethane 1.00 0.1546 J ug/L 15
Carbon disulfide 2.00 2.338 J ug/L 117
Carbon tetrachloride 1.00 1.587 ug/L 159
Chlorobenzene 1.00 1.175 ug/L 117
Chloroethane 1.00 0.9688 J ug/L 97
Chloroform 1.00 1.535 ug/L 154
Chloromethane 1.00 0.7065 J ug/L 71
cis-1,2-Dichloroethene 1.00 1.062 ug/L 106
cis-1,3-Dichloropropene 1.00 1.132 ug/L 113
Dibromochloromethane 1.00 1.218 ug/L 122
Dibromomethane 1.00 1.746 ug/L 175
Dichlorodifluoromethane 1.00 1.238 ug/L 124
Ethylbenzene 1.00 0.8383 J ug/L 84
Iodomethane 2.00 1.939 J ug/L 97
Methylene Chloride 1.00 1.896 ug/L 190
Styrene 1.00 0.6913 J ug/L 69
Tetrachloroethene 1.00 1.448 ug/L 145
Toluene 1.00 1.242 ug/L 124
trans-1,2-Dichloroethene 1.00 1.379 ug/L 138
trans-1,3-Dichloropropene 1.00 1.155 ug/L 115
trans-1,4-Dichloro-2-butene 1.00 <0.700 ug/L 54
Trichloroethene 1.00 1.395 ug/L 140
Trichlorofluoromethane 1.00 1.279 ug/L 128
Vinyl acetate 2.00 1.040 J ug/L 52
Vinyl chloride 1.00 0.5129 J ug/L 51
Xylenes, Total 3.00 2.992 J ug/L 100
4-Bromofluorobenzene (Surr)53 -136
Surrogate
88
MRL MRL
Qualifier Limits%Recovery
80Dibromofluoromethane (Surr)67 -129
77Toluene-d8 (Surr)59 -134
Client Sample ID: 7601-MW7Lab Sample ID: 752-7507-3 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 3101
1,1,1,2-Tetrachloroethane <0.170 20.0 21.46 ug/L 107 71-120
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits
1,1,1-Trichloroethane <0.120 20.0 26.47 ug/L 132 72-143
1,1,2,2-Tetrachloroethane <0.280 20.0 15.96 ug/L 80 59-133
1,1,2-Trichloroethane <0.140 20.0 16.65 ug/L 83 67-120
1,1-Dichloroethane 0.359 J 20.0 19.62 ug/L 96 79-141
1,1-Dichloroethene <0.210 20.0 19.89 ug/L 99 75-133
Eurofins Raleigh
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QC Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: 7601-MW7Lab Sample ID: 752-7507-3 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 3101
1,2,3-Trichloropropane <0.490 20.0 19.68 ug/L 98 1-210
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits
1,2-Dibromo-3-Chloropropane <0.480 20.0 18.99 ug/L 95 37-157
1,2-Dibromoethane <0.660 20.0 17.94 ug/L 90 66-123
1,2-Dichlorobenzene <0.190 20.0 17.08 ug/L 85 76-120
1,2-Dichloroethane <0.210 20.0 23.96 ug/L 120 72-151
1,2-Dichloropropane <0.100 20.0 16.43 ug/L 82 78-125
1,4-Dichlorobenzene <0.190 20.0 17.96 ug/L 90 76-122
2-Butanone (MEK)<10.0 40.0 31.28 ug/L 78 36-135
2-Hexanone <0.880 40.0 26.44 ug/L 66 36-191
4-Methyl-2-pentanone (MIBK)<1.10 40.0 29.17 ug/L 73 56-166
Acetone <10.0 40.0 31.57 ug/L 79 10-158
Acrylonitrile <3.50 60.0 45.40 ug/L 76 10-200
Benzene 0.507 J 20.0 19.10 ug/L 93 80-134
Bromochloromethane <0.480 20.0 19.36 ug/L 97 74-128
Bromodichloromethane <0.170 20.0 23.54 ug/L 118 72-129
Bromoform <0.220 20.0 22.85 ug/L 114 73-120
Bromomethane <0.140 20.0 11.70 ug/L 58 38-189
Carbon disulfide <1.50 20.0 20.84 ug/L 104 65-173
Carbon tetrachloride <0.170 F1 20.0 31.87 F1 ug/L 159 68-142
Chlorobenzene 1.07 20.0 19.74 ug/L 93 80-120
Chloroethane 0.791 J 20.0 16.04 ug/L 76 45-213
Chloroform <0.180 20.0 20.98 ug/L 105 78-138
Chloromethane <0.130 20.0 13.61 ug/L 68 56-171
cis-1,2-Dichloroethene 0.317 J 20.0 17.02 ug/L 84 69-120
cis-1,3-Dichloropropene <0.200 20.0 16.66 ug/L 83 63-125
Dibromochloromethane <0.170 20.0 20.79 ug/L 104 73-120
Dibromomethane <0.270 20.0 20.03 ug/L 100 76-124
Dichlorodifluoromethane <0.200 20.0 23.02 ug/L 115 25-161
Ethylbenzene <0.130 20.0 17.97 ug/L 90 68-124
Iodomethane <1.70 20.0 18.84 ug/L 94 34-140
Methylene Chloride <0.230 20.0 19.27 ug/L 96 68-128
Styrene <0.110 20.0 18.16 ug/L 91 73-120
Tetrachloroethene <0.170 20.0 24.78 ug/L 124 40-181
Toluene <0.140 20.0 18.49 ug/L 92 71-120
trans-1,2-Dichloroethene <0.210 20.0 18.87 ug/L 94 75-139
trans-1,3-Dichloropropene <0.150 20.0 22.21 ug/L 111 65-152
trans-1,4-Dichloro-2-butene <0.700 20.0 19.85 ug/L 99 10-142
Trichloroethene <0.150 20.0 22.36 ug/L 112 74-120
Trichlorofluoromethane <0.240 20.0 29.86 ug/L 149 68-183
Vinyl acetate <0.950 20.0 16.86 ug/L 84 10-198
Vinyl chloride <0.320 20.0 11.28 ug/L 56 49-150
Xylenes, Total <0.450 60.0 60.07 ug/L 100 77-121
4-Bromofluorobenzene (Surr)53 -136
Surrogate
96
MS MS
Qualifier Limits%Recovery
83Dibromofluoromethane (Surr)67 -129
76Toluene-d8 (Surr)59 -134
Eurofins Raleigh
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QC Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: 7601-MW7Lab Sample ID: 752-7507-3 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 3101
1,1,1,2-Tetrachloroethane <0.170 20.0 19.45 ug/L 97 71-120 10 16
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits LimitRPD
RPD
1,1,1-Trichloroethane <0.120 20.0 24.34 ug/L 122 72-143 8 18
1,1,2,2-Tetrachloroethane <0.280 20.0 15.46 ug/L 77 59-133 3 16
1,1,2-Trichloroethane <0.140 20.0 17.64 ug/L 88 67-120 6 18
1,1-Dichloroethane 0.359 J 20.0 18.73 ug/L 92 79-141 5 19
1,1-Dichloroethene <0.210 20.0 18.60 ug/L 93 75-133 7 20
1,2,3-Trichloropropane <0.490 20.0 19.00 ug/L 95 1-210 4 17
1,2-Dibromo-3-Chloropropane <0.480 20.0 17.82 ug/L 89 37-157 6 18
1,2-Dibromoethane <0.660 20.0 17.30 ug/L 87 66-123 4 15
1,2-Dichlorobenzene <0.190 20.0 16.51 ug/L 83 76-120 3 16
1,2-Dichloroethane <0.210 20.0 24.07 ug/L 120 72-151 0 16
1,2-Dichloropropane <0.100 20.0 16.56 ug/L 83 78-125 1 19
1,4-Dichlorobenzene <0.190 20.0 17.32 ug/L 87 76-122 4 16
2-Butanone (MEK)<10.0 40.0 30.76 ug/L 77 36-135 2 19
2-Hexanone <0.880 40.0 25.69 ug/L 64 36-191 3 17
4-Methyl-2-pentanone (MIBK)<1.10 40.0 28.10 ug/L 70 56-166 4 19
Acetone <10.0 40.0 26.73 ug/L 67 10-158 17 78
Acrylonitrile <3.50 60.0 41.29 ug/L 69 10-200 9 36
Benzene 0.507 J 20.0 18.08 ug/L 88 80-134 5 17
Bromochloromethane <0.480 20.0 19.09 ug/L 95 74-128 1 18
Bromodichloromethane <0.170 20.0 23.19 ug/L 116 72-129 2 16
Bromoform <0.220 20.0 21.04 ug/L 105 73-120 8 44
Bromomethane <0.140 20.0 12.10 ug/L 61 38-189 3 27
Carbon disulfide <1.50 20.0 19.28 ug/L 96 65-173 8 38
Carbon tetrachloride <0.170 F1 20.0 29.78 F1 ug/L 149 68-142 7 17
Chlorobenzene 1.07 20.0 18.89 ug/L 89 80-120 4 16
Chloroethane 0.791 J 20.0 16.39 ug/L 78 45-213 2 26
Chloroform <0.180 20.0 19.66 ug/L 98 78-138 6 17
Chloromethane <0.130 20.0 14.63 ug/L 73 56-171 7 28
cis-1,2-Dichloroethene 0.317 J 20.0 16.53 ug/L 81 69-120 3 18
cis-1,3-Dichloropropene <0.200 20.0 17.22 ug/L 86 63-125 3 17
Dibromochloromethane <0.170 20.0 19.82 ug/L 99 73-120 5 16
Dibromomethane <0.270 20.0 20.96 ug/L 105 76-124 5 15
Dichlorodifluoromethane <0.200 20.0 24.71 ug/L 124 25-161 7 48
Ethylbenzene <0.130 20.0 16.72 ug/L 84 68-124 7 16
Iodomethane <1.70 20.0 18.53 ug/L 93 34-140 2 15
Methylene Chloride <0.230 20.0 17.23 ug/L 86 68-128 11 17
Styrene <0.110 20.0 17.04 ug/L 85 73-120 6 23
Tetrachloroethene <0.170 20.0 23.04 ug/L 115 40-181 7 26
Toluene <0.140 20.0 17.09 ug/L 85 71-120 8 17
trans-1,2-Dichloroethene <0.210 20.0 17.35 ug/L 87 75-139 8 19
trans-1,3-Dichloropropene <0.150 20.0 20.96 ug/L 105 65-152 6 16
trans-1,4-Dichloro-2-butene <0.700 20.0 18.46 ug/L 92 10-142 7 28
Trichloroethene <0.150 20.0 21.98 ug/L 110 74-120 2 22
Trichlorofluoromethane <0.240 20.0 30.74 ug/L 154 68-183 3 22
Vinyl acetate <0.950 20.0 16.21 ug/L 81 10-198 4 21
Vinyl chloride <0.320 20.0 13.05 ug/L 65 49-150 15 27
Xylenes, Total <0.450 60.0 57.06 ug/L 95 77-121 5 16
Eurofins Raleigh
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QC Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: 7601-MW7Lab Sample ID: 752-7507-3 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 3101
4-Bromofluorobenzene (Surr)53 -136
Surrogate
93
MSD MSD
Qualifier Limits%Recovery
80Dibromofluoromethane (Surr)67 -129
76Toluene-d8 (Surr)59 -134
Client Sample ID: Method BlankLab Sample ID: MB 752-3113/8
Matrix: Water Prep Type: Total/NA
Analysis Batch: 3113
RL MDL
1,1,1,2-Tetrachloroethane <0.170 1.00 0.170 ug/L 06/03/23 04:42 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
<0.120 0.1201.00 ug/L 06/03/23 04:42 11,1,1-Trichloroethane
<0.280 0.2801.00 ug/L 06/03/23 04:42 11,1,2,2-Tetrachloroethane
<0.140 0.1401.00 ug/L 06/03/23 04:42 11,1,2-Trichloroethane
<0.130 0.1301.00 ug/L 06/03/23 04:42 11,1-Dichloroethane
<0.210 0.2101.00 ug/L 06/03/23 04:42 11,1-Dichloroethene
<0.490 0.4901.00 ug/L 06/03/23 04:42 11,2,3-Trichloropropane
<0.480 0.4801.00 ug/L 06/03/23 04:42 11,2-Dibromo-3-Chloropropane
<0.660 0.6601.00 ug/L 06/03/23 04:42 11,2-Dibromoethane
<0.190 0.1901.00 ug/L 06/03/23 04:42 11,2-Dichlorobenzene
<0.210 0.2101.00 ug/L 06/03/23 04:42 11,2-Dichloroethane
<0.100 0.1001.00 ug/L 06/03/23 04:42 11,2-Dichloropropane
<0.190 0.1901.00 ug/L 06/03/23 04:42 11,4-Dichlorobenzene
<10.0 10.020.0 ug/L 06/03/23 04:42 12-Butanone (MEK)
<0.880 0.8805.00 ug/L 06/03/23 04:42 12-Hexanone
<1.10 1.105.00 ug/L 06/03/23 04:42 14-Methyl-2-pentanone (MIBK)
<10.0 10.020.0 ug/L 06/03/23 04:42 1Acetone
<3.50 3.5010.0 ug/L 06/03/23 04:42 1Acrylonitrile
<0.150 0.1501.00 ug/L 06/03/23 04:42 1Benzene
<0.480 0.4801.00 ug/L 06/03/23 04:42 1Bromochloromethane
<0.170 0.1701.00 ug/L 06/03/23 04:42 1Bromodichloromethane
<0.220 0.2201.00 ug/L 06/03/23 04:42 1Bromoform
<0.140 0.1401.00 ug/L 06/03/23 04:42 1Bromomethane
<1.50 1.505.00 ug/L 06/03/23 04:42 1Carbon disulfide
<0.170 0.1701.00 ug/L 06/03/23 04:42 1Carbon tetrachloride
<0.170 0.1701.00 ug/L 06/03/23 04:42 1Chlorobenzene
<0.230 0.2301.00 ug/L 06/03/23 04:42 1Chloroethane
<0.180 0.1801.00 ug/L 06/03/23 04:42 1Chloroform
<0.130 0.1301.00 ug/L 06/03/23 04:42 1Chloromethane
<0.150 0.1501.00 ug/L 06/03/23 04:42 1cis-1,2-Dichloroethene
<0.200 0.2001.00 ug/L 06/03/23 04:42 1cis-1,3-Dichloropropene
<0.170 0.1701.00 ug/L 06/03/23 04:42 1Dibromochloromethane
<0.270 0.2701.00 ug/L 06/03/23 04:42 1Dibromomethane
<0.200 0.2001.00 ug/L 06/03/23 04:42 1Dichlorodifluoromethane
<0.130 0.1301.00 ug/L 06/03/23 04:42 1Ethylbenzene
<1.70 1.705.00 ug/L 06/03/23 04:42 1Iodomethane
0.2518 J 0.2301.00 ug/L 06/03/23 04:42 1Methylene Chloride
<0.110 0.1101.00 ug/L 06/03/23 04:42 1Styrene
<0.170 0.1701.00 ug/L 06/03/23 04:42 1Tetrachloroethene
Eurofins Raleigh
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QC Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 752-3113/8
Matrix: Water Prep Type: Total/NA
Analysis Batch: 3113
RL MDL
Toluene <0.140 1.00 0.140 ug/L 06/03/23 04:42 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
<0.210 0.2101.00 ug/L 06/03/23 04:42 1trans-1,2-Dichloroethene
<0.150 0.1501.00 ug/L 06/03/23 04:42 1trans-1,3-Dichloropropene
<0.700 0.7001.00 ug/L 06/03/23 04:42 1trans-1,4-Dichloro-2-butene
<0.150 0.1501.00 ug/L 06/03/23 04:42 1Trichloroethene
<0.240 0.2401.00 ug/L 06/03/23 04:42 1Trichlorofluoromethane
<0.950 0.9505.00 ug/L 06/03/23 04:42 1Vinyl acetate
<0.320 0.3201.00 ug/L 06/03/23 04:42 1Vinyl chloride
<0.450 0.4503.00 ug/L 06/03/23 04:42 1Xylenes, Total
4-Bromofluorobenzene (Surr)93 53-136 06/03/23 04:42 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
82 06/03/23 04:42 1Dibromofluoromethane (Surr)67-129
75 06/03/23 04:42 1Toluene-d8 (Surr)59-134
Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-3113/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 3113
1,1,1,2-Tetrachloroethane 20.0 20.35 ug/L 102 71-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
1,1,1-Trichloroethane 20.0 21.63 ug/L 108 72-143
1,1,2,2-Tetrachloroethane 20.0 15.67 ug/L 78 59-133
1,1,2-Trichloroethane 20.0 17.15 ug/L 86 67-120
1,1-Dichloroethane 20.0 17.77 ug/L 89 79-141
1,1-Dichloroethene 20.0 16.46 ug/L 82 75-133
1,2,3-Trichloropropane 20.0 20.17 ug/L 101 69-127
1,2-Dibromo-3-Chloropropane 20.0 18.85 ug/L 94 37-157
1,2-Dibromoethane 20.0 17.78 ug/L 89 66-123
1,2-Dichlorobenzene 20.0 17.00 ug/L 85 76-120
1,2-Dichloroethane 20.0 24.09 ug/L 120 72-151
1,2-Dichloropropane 20.0 16.55 ug/L 83 78-125
1,4-Dichlorobenzene 20.0 16.84 ug/L 84 76-122
2-Butanone (MEK)40.0 36.34 ug/L 91 36-135
2-Hexanone 40.0 27.67 ug/L 69 36-191
4-Methyl-2-pentanone (MIBK)40.0 30.82 ug/L 77 56-166
Acetone 40.0 28.06 ug/L 70 10-158
Acrylonitrile 60.0 43.01 ug/L 72 10-200
Benzene 20.0 17.63 ug/L 88 80-134
Bromochloromethane 20.0 18.96 ug/L 95 74-128
Bromodichloromethane 20.0 22.08 ug/L 110 72-129
Bromoform 20.0 23.56 ug/L 118 73-120
Bromomethane 20.0 10.87 ug/L 54 38-189
Carbon disulfide 20.0 17.59 ug/L 88 65-173
Carbon tetrachloride 20.0 26.52 ug/L 133 68-142
Chlorobenzene 20.0 18.21 ug/L 91 80-120
Chloroethane 20.0 12.55 ug/L 63 45-213
Chloroform 20.0 19.15 ug/L 96 78-138
Eurofins Raleigh
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QC Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-3113/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 3113
Chloromethane 20.0 12.35 ug/L 62 56-171
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
cis-1,2-Dichloroethene 20.0 15.61 ug/L 78 69-120
cis-1,3-Dichloropropene 20.0 19.16 ug/L 96 63-125
Dibromochloromethane 20.0 19.75 ug/L 99 73-120
Dibromomethane 20.0 20.30 ug/L 102 76-124
Dichlorodifluoromethane 20.0 17.63 ug/L 88 25-161
Ethylbenzene 20.0 16.43 ug/L 82 68-124
Iodomethane 20.0 19.17 ug/L 96 34-140
Methylene Chloride 20.0 18.08 ug/L 90 68-128
Styrene 20.0 17.67 ug/L 88 73-120
Tetrachloroethene 20.0 21.28 ug/L 106 40-181
Toluene 20.0 16.41 ug/L 82 71-120
trans-1,2-Dichloroethene 20.0 16.74 ug/L 84 75-139
trans-1,3-Dichloropropene 20.0 21.05 ug/L 105 65-152
trans-1,4-Dichloro-2-butene 20.0 18.54 ug/L 93 10-142
Trichloroethene 20.0 20.83 ug/L 104 74-120
Trichlorofluoromethane 20.0 23.29 ug/L 116 68-183
Vinyl acetate 20.0 16.96 ug/L 85 10-198
Vinyl chloride 20.0 10.08 ug/L 50 49-150
Xylenes, Total 60.0 55.75 ug/L 93 77-121
4-Bromofluorobenzene (Surr)53 -136
Surrogate
90
LCS LCS
Qualifier Limits%Recovery
78Dibromofluoromethane (Surr)67 -129
77Toluene-d8 (Surr)59 -134
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-3113/6
Matrix: Water Prep Type: Total/NA
Analysis Batch: 3113
1,1,1,2-Tetrachloroethane 20.0 23.20 ug/L 116 71-120 13 16
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
1,1,1-Trichloroethane 20.0 23.63 ug/L 118 72-143 9 18
1,1,2,2-Tetrachloroethane 20.0 16.14 ug/L 81 59-133 3 16
1,1,2-Trichloroethane 20.0 17.52 ug/L 88 67-120 2 18
1,1-Dichloroethane 20.0 18.61 ug/L 93 79-141 5 19
1,1-Dichloroethene 20.0 18.50 ug/L 93 75-133 12 20
1,2,3-Trichloropropane 20.0 19.02 ug/L 95 69-127 6 17
1,2-Dibromo-3-Chloropropane 20.0 18.83 ug/L 94 37-157 0 18
1,2-Dibromoethane 20.0 18.36 ug/L 92 66-123 3 15
1,2-Dichlorobenzene 20.0 17.02 ug/L 85 76-120 0 16
1,2-Dichloroethane 20.0 24.31 ug/L 122 72-151 1 16
1,2-Dichloropropane 20.0 17.42 ug/L 87 78-125 5 19
1,4-Dichlorobenzene 20.0 17.56 ug/L 88 76-122 4 16
2-Butanone (MEK)40.0 36.97 ug/L 92 36-135 2 19
2-Hexanone 40.0 29.77 ug/L 74 36-191 7 17
4-Methyl-2-pentanone (MIBK)40.0 31.50 ug/L 79 56-166 2 19
Acetone 40.0 34.65 ug/L 87 10-158 21 78
Eurofins Raleigh
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QC Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-3113/6
Matrix: Water Prep Type: Total/NA
Analysis Batch: 3113
Acrylonitrile 60.0 47.38 ug/L 79 10-200 10 36
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
Benzene 20.0 18.06 ug/L 90 80-134 2 17
Bromochloromethane 20.0 20.04 ug/L 100 74-128 6 18
Bromodichloromethane 20.0 22.76 ug/L 114 72-129 3 16
Bromoform 20.0 23.97 ug/L 120 73-120 2 44
Bromomethane 20.0 11.83 ug/L 59 38-189 9 27
Carbon disulfide 20.0 18.84 ug/L 94 65-173 7 38
Carbon tetrachloride 20.0 27.91 ug/L 140 68-142 5 17
Chlorobenzene 20.0 19.18 ug/L 96 80-120 5 16
Chloroethane 20.0 14.28 ug/L 71 45-213 13 26
Chloroform 20.0 20.51 ug/L 103 78-138 7 17
Chloromethane 20.0 13.61 ug/L 68 56-171 10 28
cis-1,2-Dichloroethene 20.0 16.88 ug/L 84 69-120 8 18
cis-1,3-Dichloropropene 20.0 19.00 ug/L 95 63-125 1 17
Dibromochloromethane 20.0 20.43 ug/L 102 73-120 3 16
Dibromomethane 20.0 20.71 ug/L 104 76-124 2 15
Dichlorodifluoromethane 20.0 21.26 ug/L 106 25-161 19 48
Ethylbenzene 20.0 17.64 ug/L 88 68-124 7 16
Iodomethane 20.0 20.25 ug/L 101 34-140 5 15
Methylene Chloride 20.0 19.60 ug/L 98 68-128 8 17
Styrene 20.0 18.47 ug/L 92 73-120 4 23
Tetrachloroethene 20.0 22.09 ug/L 110 40-181 4 26
Toluene 20.0 17.72 ug/L 89 71-120 8 17
trans-1,2-Dichloroethene 20.0 17.76 ug/L 89 75-139 6 19
trans-1,3-Dichloropropene 20.0 21.30 ug/L 106 65-152 1 16
trans-1,4-Dichloro-2-butene 20.0 19.15 ug/L 96 10-142 3 28
Trichloroethene 20.0 21.60 ug/L 108 74-120 4 22
Trichlorofluoromethane 20.0 26.84 ug/L 134 68-183 14 22
Vinyl acetate 20.0 18.85 ug/L 94 10-198 11 21
Vinyl chloride 20.0 11.50 ug/L 58 49-150 13 27
Xylenes, Total 60.0 59.15 ug/L 99 77-121 6 16
4-Bromofluorobenzene (Surr)53 -136
Surrogate
90
LCSD LCSD
Qualifier Limits%Recovery
78Dibromofluoromethane (Surr)67 -129
75Toluene-d8 (Surr)59 -134
Client Sample ID: Lab Control SampleLab Sample ID: MRL 752-3113/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 3113
1,1,1,2-Tetrachloroethane 1.00 1.249 ug/L 125
Analyte
MRL MRL
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
1,1,1-Trichloroethane 1.00 1.437 ug/L 144
1,1,2,2-Tetrachloroethane 1.00 0.9843 J ug/L 98
1,1,2-Trichloroethane 1.00 1.079 ug/L 108
1,1-Dichloroethane 1.00 1.066 ug/L 107
1,1-Dichloroethene 1.00 1.028 ug/L 103
Eurofins Raleigh
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QC Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: MRL 752-3113/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 3113
1,2,3-Trichloropropane 1.00 1.244 ug/L 124
Analyte
MRL MRL
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
1,2-Dibromo-3-Chloropropane 1.00 1.746 ug/L 175
1,2-Dibromoethane 1.00 1.047 ug/L 105
1,2-Dichlorobenzene 1.00 1.049 ug/L 105
1,2-Dichloroethane 1.00 1.409 ug/L 141
1,2-Dichloropropane 1.00 1.011 ug/L 101
1,4-Dichlorobenzene 1.00 1.126 ug/L 113
2-Butanone (MEK)2.00 <10.0 ug/L 367
2-Hexanone 2.00 1.209 J ug/L 60
4-Methyl-2-pentanone (MIBK)2.00 1.394 J ug/L 70
Acetone 2.00 <10.0 ug/L 84
Acrylonitrile 5.00 <3.50 ug/L 62
Benzene 1.00 1.124 ug/L 112
Bromochloromethane 1.00 1.232 ug/L 123
Bromodichloromethane 1.00 1.484 ug/L 148
Bromoform 1.00 1.268 ug/L 127
Bromomethane 1.00 0.2786 J ug/L 28
Carbon disulfide 2.00 2.237 J ug/L 112
Carbon tetrachloride 1.00 1.491 ug/L 149
Chlorobenzene 1.00 1.232 ug/L 123
Chloroethane 1.00 0.9606 J ug/L 96
Chloroform 1.00 1.490 ug/L 149
Chloromethane 1.00 0.8534 J ug/L 85
cis-1,2-Dichloroethene 1.00 1.028 ug/L 103
cis-1,3-Dichloropropene 1.00 0.9670 J ug/L 97
Dibromochloromethane 1.00 1.041 ug/L 104
Dibromomethane 1.00 1.385 ug/L 139
Dichlorodifluoromethane 1.00 1.350 ug/L 135
Ethylbenzene 1.00 0.8276 J ug/L 83
Iodomethane 2.00 1.860 J ug/L 93
Methylene Chloride 1.00 1.854 ug/L 185
Styrene 1.00 0.6828 J ug/L 68
Tetrachloroethene 1.00 1.128 ug/L 113
Toluene 1.00 1.228 ug/L 123
trans-1,2-Dichloroethene 1.00 0.6794 J ug/L 68
trans-1,3-Dichloropropene 1.00 0.9969 J ug/L 100
trans-1,4-Dichloro-2-butene 1.00 1.054 ug/L 105
Trichloroethene 1.00 1.466 ug/L 147
Trichlorofluoromethane 1.00 1.181 ug/L 118
Vinyl acetate 2.00 0.9580 J ug/L 48
Vinyl chloride 1.00 0.6743 J ug/L 67
Xylenes, Total 3.00 2.914 J ug/L 97
4-Bromofluorobenzene (Surr)53 -136
Surrogate
89
MRL MRL
Qualifier Limits%Recovery
83Dibromofluoromethane (Surr)67 -129
77Toluene-d8 (Surr)59 -134
Eurofins Raleigh
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QC Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Method: 8270E - Semivolatile Organic Compounds (GC/MS)
Client Sample ID: Method BlankLab Sample ID: MB 680-780784/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 780901 Prep Batch: 780784
RL MDL
Diethyl phthalate <2.20 10.0 2.20 ug/L 05/27/23 12:41 05/29/23 17:10 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
2,4,6-Tribromophenol (Surr)65 30-130 05/29/23 17:10 1
MB MB
Surrogate
05/27/23 12:41
Dil FacPreparedAnalyzedQualifierLimits%Recovery
71 05/27/23 12:41 05/29/23 17:10 12-Fluorobiphenyl 25-130
35 05/27/23 12:41 05/29/23 17:10 12-Fluorophenol (Surr)10-130
74 05/27/23 12:41 05/29/23 17:10 1Nitrobenzene-d5 (Surr)30-130
23 05/27/23 12:41 05/29/23 17:10 1Phenol-d5 (Surr)10-130
76 05/27/23 12:41 05/29/23 17:10 1Terphenyl-d14 (Surr)35-131
Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-780784/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 780901 Prep Batch: 780784
Diethyl phthalate 200 203.1 ug/L 102 36-130
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
2,4,6-Tribromophenol (Surr)30 -130
Surrogate
64
LCS LCS
Qualifier Limits%Recovery
672-Fluorobiphenyl 25 -130
322-Fluorophenol (Surr)10 -130
68Nitrobenzene-d5 (Surr)30 -130
23Phenol-d5 (Surr)10 -130
82Terphenyl-d14 (Surr)35 -131
Client Sample ID: 7601-MW7Lab Sample ID: 752-7507-3 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 780901 Prep Batch: 780784
Diethyl phthalate <2.20 193 200.2 ug/L 104 36-130
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits
2,4,6-Tribromophenol (Surr)30 -130
Surrogate
67
MS MS
Qualifier Limits%Recovery
722-Fluorobiphenyl 25 -130
342-Fluorophenol (Surr)10 -130
73Nitrobenzene-d5 (Surr)30 -130
23Phenol-d5 (Surr)10 -130
82Terphenyl-d14 (Surr)35 -131
Client Sample ID: 7601-MW7Lab Sample ID: 752-7507-3 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 780901 Prep Batch: 780784
Diethyl phthalate <2.20 196 181.0 ug/L 92 36-130 10 50
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits LimitRPD
RPD
Eurofins Raleigh
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QC Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Method: 8270E - Semivolatile Organic Compounds (GC/MS) (Continued)
Client Sample ID: 7601-MW7Lab Sample ID: 752-7507-3 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 780901 Prep Batch: 780784
2,4,6-Tribromophenol (Surr)30 -130
Surrogate
58
MSD MSD
Qualifier Limits%Recovery
612-Fluorobiphenyl 25 -130
302-Fluorophenol (Surr)10 -130
61Nitrobenzene-d5 (Surr)30 -130
22Phenol-d5 (Surr)10 -130
77Terphenyl-d14 (Surr)35 -131
Method: 6010D - Metals (ICP)
Client Sample ID: Method BlankLab Sample ID: MB 680-780920/1-A
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 781123 Prep Batch: 780920
RL MDL
Arsenic <6.40 20.0 6.40 ug/L 05/30/23 06:22 05/30/23 15:21 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
<4.40 4.4010.0 ug/L 05/30/23 06:22 05/30/23 15:21 1Barium
<0.300 0.3004.00 ug/L 05/30/23 06:22 05/30/23 15:21 1Beryllium
<0.440 0.4405.00 ug/L 05/30/23 06:22 05/30/23 15:21 1Cadmium
<1.10 1.1010.0 ug/L 05/30/23 06:22 05/30/23 15:21 1Chromium
<1.40 1.4010.0 ug/L 05/30/23 06:22 05/30/23 15:21 1Cobalt
<3.20 3.2020.0 ug/L 05/30/23 06:22 05/30/23 15:21 1Copper
<6.60 6.6010.0 ug/L 05/30/23 06:22 05/30/23 15:21 1Lead
<3.30 3.3040.0 ug/L 05/30/23 06:22 05/30/23 15:21 1Nickel
<10.0 10.020.0 ug/L 05/30/23 06:22 05/30/23 15:21 1Selenium
<1.50 1.5010.0 ug/L 05/30/23 06:22 05/30/23 15:21 1Silver
<1.00 1.0010.0 ug/L 05/30/23 06:22 05/30/23 15:21 1Vanadium
<8.70 8.7020.0 ug/L 05/30/23 06:22 05/30/23 15:21 1Zinc
Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-780920/2-A
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 781123 Prep Batch: 780920
Arsenic 100 98.47 ug/L 98 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Barium 100 99.97 ug/L 100 80-120
Beryllium 50.0 51.28 ug/L 103 80-120
Cadmium 50.0 51.04 ug/L 102 80-120
Chromium 100 101.0 ug/L 101 80-120
Cobalt 50.0 51.61 ug/L 103 80-120
Copper 100 104.3 ug/L 104 80-120
Lead 500 481.6 ug/L 96 80-120
Nickel 100 99.85 ug/L 100 80-120
Selenium 100 93.97 ug/L 94 80-120
Silver 50.0 46.94 ug/L 94 80-120
Vanadium 100 97.86 ug/L 98 80-120
Zinc 100 104.2 ug/L 104 80-120
Eurofins Raleigh
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QC Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Method: 6010D - Metals (ICP) (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 680-780926/1-A
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 781123 Prep Batch: 780926
RL MDL
Arsenic <6.40 20.0 6.40 ug/L 05/30/23 06:51 05/30/23 14:28 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
<4.40 4.4010.0 ug/L 05/30/23 06:51 05/30/23 14:28 1Barium
<0.300 0.3004.00 ug/L 05/30/23 06:51 05/30/23 14:28 1Beryllium
<0.440 0.4405.00 ug/L 05/30/23 06:51 05/30/23 14:28 1Cadmium
<1.10 1.1010.0 ug/L 05/30/23 06:51 05/30/23 14:28 1Chromium
<1.40 1.4010.0 ug/L 05/30/23 06:51 05/30/23 14:28 1Cobalt
<3.20 3.2020.0 ug/L 05/30/23 06:51 05/30/23 14:28 1Copper
<6.60 6.6010.0 ug/L 05/30/23 06:51 05/30/23 14:28 1Lead
<3.30 3.3040.0 ug/L 05/30/23 06:51 05/30/23 14:28 1Nickel
<10.0 10.020.0 ug/L 05/30/23 06:51 05/30/23 14:28 1Selenium
<1.50 1.5010.0 ug/L 05/30/23 06:51 05/30/23 14:28 1Silver
<1.00 1.0010.0 ug/L 05/30/23 06:51 05/30/23 14:28 1Vanadium
<8.70 8.7020.0 ug/L 05/30/23 06:51 05/30/23 14:28 1Zinc
Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-780926/2-A
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 781123 Prep Batch: 780926
Arsenic 100 99.08 ug/L 99 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Barium 100 102.1 ug/L 102 80-120
Beryllium 50.0 51.71 ug/L 103 80-120
Cadmium 50.0 51.35 ug/L 103 80-120
Chromium 100 100.8 ug/L 101 80-120
Cobalt 50.0 51.40 ug/L 103 80-120
Copper 100 103.4 ug/L 103 80-120
Lead 500 484.1 ug/L 97 80-120
Nickel 100 98.99 ug/L 99 80-120
Selenium 100 91.18 ug/L 91 80-120
Silver 50.0 46.87 ug/L 94 80-120
Vanadium 100 97.41 ug/L 97 80-120
Zinc 100 99.04 ug/L 99 80-120
Client Sample ID: 7601-MW7Lab Sample ID: 752-7507-3 MS
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 781123 Prep Batch: 780926
Arsenic <6.40 100 99.18 ug/L 99 75-125
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits
Barium <4.40 100 103.2 ug/L 103 75-125
Beryllium <0.300 50.0 52.86 ug/L 106 75-125
Cadmium 0.500 J 50.0 52.59 ug/L 104 75-125
Chromium <1.10 100 103.4 ug/L 103 75-125
Cobalt 10.9 50.0 61.98 ug/L 102 75-125
Copper <3.20 100 104.6 ug/L 105 75-125
Lead <6.60 500 489.6 ug/L 98 75-125
Nickel <3.30 100 101.7 ug/L 102 75-125
Selenium <10.0 100 94.21 ug/L 94 75-125
Silver <1.50 50.0 48.15 ug/L 96 75-125
Eurofins Raleigh
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QC Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Method: 6010D - Metals (ICP) (Continued)
Client Sample ID: 7601-MW7Lab Sample ID: 752-7507-3 MS
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 781123 Prep Batch: 780926
Vanadium <1.00 100 100.6 ug/L 101 75-125
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits
Zinc <8.70 100 105.8 ug/L 106 75-125
Client Sample ID: 7601-MW7Lab Sample ID: 752-7507-3 MSD
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 781123 Prep Batch: 780926
Arsenic <6.40 100 98.56 ug/L 99 75-125 1 20
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits LimitRPD
RPD
Barium <4.40 100 102.4 ug/L 102 75-125 1 20
Beryllium <0.300 50.0 52.51 ug/L 105 75-125 1 20
Cadmium 0.500 J 50.0 52.03 ug/L 103 75-125 1 20
Chromium <1.10 100 102.3 ug/L 102 75-125 1 20
Cobalt 10.9 50.0 62.77 ug/L 104 75-125 1 20
Copper <3.20 100 103.6 ug/L 104 75-125 1 20
Lead <6.60 500 486.2 ug/L 97 75-125 1 20
Nickel <3.30 100 101.0 ug/L 101 75-125 1 20
Selenium <10.0 100 94.27 ug/L 94 75-125 0 20
Silver <1.50 50.0 47.66 ug/L 95 75-125 1 20
Vanadium <1.00 100 98.92 ug/L 99 75-125 2 20
Zinc <8.70 100 105.1 ug/L 105 75-125 1 20
Method: 6020B - Metals (ICP/MS)
Client Sample ID: Method BlankLab Sample ID: MB 680-780921/1-A
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 781125 Prep Batch: 780921
RL MDL
Antimony <0.340 5.00 0.340 ug/L 05/30/23 06:22 05/30/23 21:49 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
<0.260 0.2601.00 ug/L 05/30/23 06:22 05/30/23 21:49 1Thallium
Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-780921/2-A
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 781125 Prep Batch: 780921
Antimony 50.0 52.54 ug/L 105 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Thallium 50.0 53.69 ug/L 107 80-120
Client Sample ID: Method BlankLab Sample ID: MB 680-780928/1-A
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 781125 Prep Batch: 780928
RL MDL
Antimony <0.340 5.00 0.340 ug/L 05/30/23 06:51 05/30/23 20:24 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
<0.260 0.2601.00 ug/L 05/30/23 06:51 05/30/23 20:24 1Thallium
Eurofins Raleigh
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QC Sample Results
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Method: 6020B - Metals (ICP/MS) (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-780928/2-A
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 781125 Prep Batch: 780928
Antimony 50.0 51.99 ug/L 104 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Thallium 50.0 53.69 ug/L 107 80-120
Client Sample ID: 7601-MW7Lab Sample ID: 752-7507-3 MS
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 781125 Prep Batch: 780928
Antimony <0.340 50.0 54.60 ug/L 109 75-125
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits
Thallium <0.260 50.0 56.58 ug/L 113 75-125
Client Sample ID: 7601-MW7Lab Sample ID: 752-7507-3 MSD
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 781125 Prep Batch: 780928
Antimony <0.340 50.0 52.39 ug/L 105 75-125 4 20
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits LimitRPD
RPD
Thallium <0.260 50.0 54.64 ug/L 109 75-125 3 20
Method: 7470A - Mercury (CVAA)
Client Sample ID: Method BlankLab Sample ID: MB 680-781000/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 781270 Prep Batch: 781000
RL MDL
Mercury <0.0800 0.200 0.0800 ug/L 05/30/23 10:34 05/31/23 09:40 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-781000/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 781270 Prep Batch: 781000
Mercury 2.50 2.521 ug/L 101 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Client Sample ID: 7601-MW7Lab Sample ID: 752-7507-3 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 781270 Prep Batch: 781000
Mercury <0.0800 F1 1.00 0.6225 F1 ug/L 62 80-120
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits
Client Sample ID: 7601-MW7Lab Sample ID: 752-7507-3 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 781270 Prep Batch: 781000
Mercury <0.0800 F1 1.00 0.5713 F1 ug/L 57 80-120 9 20
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits LimitRPD
RPD
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QC Association Summary
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
GC/MS VOA
Analysis Batch: 3101
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 8260D752-7507-1 7601-MW10S Total/NA
Water 8260D752-7507-3 7601-MW7 Total/NA
Water 8260D752-7507-10 7601-Trip Blank Total/NA
Water 8260DMB 752-3101/8 Method Blank Total/NA
Water 8260DLCS 752-3101/5 Lab Control Sample Total/NA
Water 8260DLCSD 752-3101/6 Lab Control Sample Dup Total/NA
Water 8260DMRL 752-3101/4 Lab Control Sample Total/NA
Water 8260D752-7507-3 MS 7601-MW7 Total/NA
Water 8260D752-7507-3 MSD 7601-MW7 Total/NA
Analysis Batch: 3113
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 8260D752-7507-2 7601-MW6 Total/NA
Water 8260D752-7507-4 7601-MW8 Total/NA
Water 8260D752-7507-5 7601-MW9 Total/NA
Water 8260D752-7507-6 7601-SW1 Total/NA
Water 8260D752-7507-7 7601-SW2 Total/NA
Water 8260D752-7507-8 7601-SW3 Total/NA
Water 8260D752-7507-9 7601-SW4 Total/NA
Water 8260DMB 752-3113/8 Method Blank Total/NA
Water 8260DLCS 752-3113/5 Lab Control Sample Total/NA
Water 8260DLCSD 752-3113/6 Lab Control Sample Dup Total/NA
Water 8260DMRL 752-3113/4 Lab Control Sample Total/NA
Analysis Batch: 781127
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 8260 SIM752-7507-1 7601-MW10S Total/NA
Water 8260 SIM752-7507-3 7601-MW7 Total/NA
Water 8260 SIM752-7507-4 7601-MW8 Total/NA
Water 8260 SIM752-7507-6 7601-SW1 Total/NA
Water 8260 SIM752-7507-7 7601-SW2 Total/NA
Water 8260 SIM752-7507-8 7601-SW3 Total/NA
Water 8260 SIM752-7507-9 7601-SW4 Total/NA
Water 8260 SIMMB 680-781127/6 Method Blank Total/NA
Water 8260 SIMLCS 680-781127/20 Lab Control Sample Total/NA
Water 8260 SIMLCSD 680-781127/4 Lab Control Sample Dup Total/NA
Water 8260 SIM752-7507-3 MS 7601-MW7 Total/NA
Water 8260 SIM752-7507-3 MSD 7601-MW7 Total/NA
Analysis Batch: 781391
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 8260 SIM752-7507-2 7601-MW6 Total/NA
Water 8260 SIM752-7507-5 7601-MW9 Total/NA
Water 8260 SIMMB 680-781391/6 Method Blank Total/NA
Water 8260 SIMLCS 680-781391/3 Lab Control Sample Total/NA
Water 8260 SIMLCSD 680-781391/4 Lab Control Sample Dup Total/NA
Water 8260 SIM752-7507-5 MS 7601-MW9 Total/NA
Water 8260 SIM752-7507-5 MSD 7601-MW9 Total/NA
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QC Association Summary
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
GC/MS Semi VOA
Prep Batch: 780784
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3510C752-7507-1 7601-MW10S Total/NA
Water 3510C752-7507-2 7601-MW6 Total/NA
Water 3510C752-7507-3 7601-MW7 Total/NA
Water 3510C752-7507-4 7601-MW8 Total/NA
Water 3510C752-7507-5 7601-MW9 Total/NA
Water 3510CMB 680-780784/1-A Method Blank Total/NA
Water 3510CLCS 680-780784/2-A Lab Control Sample Total/NA
Water 3510C752-7507-3 MS 7601-MW7 Total/NA
Water 3510C752-7507-3 MSD 7601-MW7 Total/NA
Analysis Batch: 780901
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 8270E 780784752-7507-1 7601-MW10S Total/NA
Water 8270E 780784752-7507-2 7601-MW6 Total/NA
Water 8270E 780784752-7507-3 7601-MW7 Total/NA
Water 8270E 780784752-7507-4 7601-MW8 Total/NA
Water 8270E 780784752-7507-5 7601-MW9 Total/NA
Water 8270E 780784MB 680-780784/1-A Method Blank Total/NA
Water 8270E 780784LCS 680-780784/2-A Lab Control Sample Total/NA
Water 8270E 780784752-7507-3 MS 7601-MW7 Total/NA
Water 8270E 780784752-7507-3 MSD 7601-MW7 Total/NA
Metals
Prep Batch: 780920
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3005A752-7507-1 7601-MW10S Total Recoverable
Water 3005A752-7507-2 7601-MW6 Total Recoverable
Water 3005A752-7507-6 7601-SW1 Total Recoverable
Water 3005A752-7507-7 7601-SW2 Total Recoverable
Water 3005A752-7507-8 7601-SW3 Total Recoverable
Water 3005A752-7507-9 7601-SW4 Total Recoverable
Water 3005AMB 680-780920/1-A Method Blank Total Recoverable
Water 3005ALCS 680-780920/2-A Lab Control Sample Total Recoverable
Prep Batch: 780921
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3005A752-7507-1 7601-MW10S Total Recoverable
Water 3005A752-7507-2 7601-MW6 Total Recoverable
Water 3005A752-7507-6 7601-SW1 Total Recoverable
Water 3005A752-7507-7 7601-SW2 Total Recoverable
Water 3005A752-7507-8 7601-SW3 Total Recoverable
Water 3005A752-7507-9 7601-SW4 Total Recoverable
Water 3005AMB 680-780921/1-A Method Blank Total Recoverable
Water 3005ALCS 680-780921/2-A Lab Control Sample Total Recoverable
Prep Batch: 780926
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3005A752-7507-3 7601-MW7 Total Recoverable
Water 3005A752-7507-4 7601-MW8 Total Recoverable
Water 3005A752-7507-5 7601-MW9 Total Recoverable
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QC Association Summary
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Metals (Continued)
Prep Batch: 780926 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3005AMB 680-780926/1-A Method Blank Total Recoverable
Water 3005ALCS 680-780926/2-A Lab Control Sample Total Recoverable
Water 3005A752-7507-3 MS 7601-MW7 Total Recoverable
Water 3005A752-7507-3 MSD 7601-MW7 Total Recoverable
Prep Batch: 780928
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3005A752-7507-3 7601-MW7 Total Recoverable
Water 3005A752-7507-4 7601-MW8 Total Recoverable
Water 3005A752-7507-5 7601-MW9 Total Recoverable
Water 3005AMB 680-780928/1-A Method Blank Total Recoverable
Water 3005ALCS 680-780928/2-A Lab Control Sample Total Recoverable
Water 3005A752-7507-3 MS 7601-MW7 Total Recoverable
Water 3005A752-7507-3 MSD 7601-MW7 Total Recoverable
Prep Batch: 781000
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 7470A752-7507-1 7601-MW10S Total/NA
Water 7470A752-7507-2 7601-MW6 Total/NA
Water 7470A752-7507-3 7601-MW7 Total/NA
Water 7470A752-7507-4 7601-MW8 Total/NA
Water 7470A752-7507-5 7601-MW9 Total/NA
Water 7470AMB 680-781000/1-A Method Blank Total/NA
Water 7470ALCS 680-781000/2-A Lab Control Sample Total/NA
Water 7470A752-7507-3 MS 7601-MW7 Total/NA
Water 7470A752-7507-3 MSD 7601-MW7 Total/NA
Analysis Batch: 781123
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6010D 780920752-7507-1 7601-MW10S Total Recoverable
Water 6010D 780920752-7507-2 7601-MW6 Total Recoverable
Water 6010D 780926752-7507-3 7601-MW7 Total Recoverable
Water 6010D 780926752-7507-4 7601-MW8 Total Recoverable
Water 6010D 780926752-7507-5 7601-MW9 Total Recoverable
Water 6010D 780920752-7507-6 7601-SW1 Total Recoverable
Water 6010D 780920752-7507-7 7601-SW2 Total Recoverable
Water 6010D 780920752-7507-8 7601-SW3 Total Recoverable
Water 6010D 780920752-7507-9 7601-SW4 Total Recoverable
Water 6010D 780920MB 680-780920/1-A Method Blank Total Recoverable
Water 6010D 780926MB 680-780926/1-A Method Blank Total Recoverable
Water 6010D 780920LCS 680-780920/2-A Lab Control Sample Total Recoverable
Water 6010D 780926LCS 680-780926/2-A Lab Control Sample Total Recoverable
Water 6010D 780926752-7507-3 MS 7601-MW7 Total Recoverable
Water 6010D 780926752-7507-3 MSD 7601-MW7 Total Recoverable
Analysis Batch: 781125
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6020B 780921752-7507-1 7601-MW10S Total Recoverable
Water 6020B 780921752-7507-2 7601-MW6 Total Recoverable
Water 6020B 780928752-7507-3 7601-MW7 Total Recoverable
Water 6020B 780928752-7507-4 7601-MW8 Total Recoverable
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QC Association Summary
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Metals (Continued)
Analysis Batch: 781125 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6020B 780928752-7507-5 7601-MW9 Total Recoverable
Water 6020B 780921752-7507-6 7601-SW1 Total Recoverable
Water 6020B 780921752-7507-7 7601-SW2 Total Recoverable
Water 6020B 780921752-7507-8 7601-SW3 Total Recoverable
Water 6020B 780921752-7507-9 7601-SW4 Total Recoverable
Water 6020B 780921MB 680-780921/1-A Method Blank Total Recoverable
Water 6020B 780928MB 680-780928/1-A Method Blank Total Recoverable
Water 6020B 780921LCS 680-780921/2-A Lab Control Sample Total Recoverable
Water 6020B 780928LCS 680-780928/2-A Lab Control Sample Total Recoverable
Water 6020B 780928752-7507-3 MS 7601-MW7 Total Recoverable
Water 6020B 780928752-7507-3 MSD 7601-MW7 Total Recoverable
Analysis Batch: 781270
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 7470A 781000752-7507-1 7601-MW10S Total/NA
Water 7470A 781000752-7507-2 7601-MW6 Total/NA
Water 7470A 781000752-7507-3 7601-MW7 Total/NA
Water 7470A 781000752-7507-4 7601-MW8 Total/NA
Water 7470A 781000752-7507-5 7601-MW9 Total/NA
Water 7470A 781000MB 680-781000/1-A Method Blank Total/NA
Water 7470A 781000LCS 680-781000/2-A Lab Control Sample Total/NA
Water 7470A 781000752-7507-3 MS 7601-MW7 Total/NA
Water 7470A 781000752-7507-3 MSD 7601-MW7 Total/NA
Eurofins Raleigh
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Lab Chronicle
Client: WSP USA Inc Job ID: 752-7507-1
Project/Site: Randolph County Landfill
Client Sample ID: 7601-MW10S Lab Sample ID: 752-7507-1
Matrix: WaterDate Collected: 05/22/23 14:45
Date Received: 05/25/23 10:00
Analysis 8260 SIM NTA1781127 EET SAV
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA 05/31/23 14:26
Analysis 8260D 1 3101 RY EET ESCTotal/NA 06/02/23 19:51
Prep 3510C 780784 MR EET SAVTotal/NA 05/27/23 12:41
Analysis 8270E 1 780901 T1C EET SAVTotal/NA 05/29/23 22:19
Prep 3005A 780920 RR EET SAVTotal Recoverable 05/30/23 06:22
Analysis 6010D 1 781123 BJB EET SAVTotal Recoverable 05/30/23 15:44
Prep 3005A 780921 RR EET SAVTotal Recoverable 05/30/23 06:22
Analysis 6020B 1 781125 BJB EET SAVTotal Recoverable 05/30/23 23:06
Prep 7470A 781000 JKL EET SAVTotal/NA 05/30/23 10:34
Analysis 7470A 1 781270 JKL EET SAVTotal/NA 05/31/23 09:43
Client Sample ID: 7601-MW6 Lab Sample ID: 752-7507-2
Matrix: WaterDate Collected: 05/23/23 11:15
Date Received: 05/25/23 10:00
Analysis 8260 SIM NTA1781391 EET SAV
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA 06/01/23 15:40
Analysis 8260D 1 3113 RY EET ESCTotal/NA 06/03/23 06:11
Prep 3510C 780784 MR EET SAVTotal/NA 05/27/23 12:41
Analysis 8270E 1 780901 T1C EET SAVTotal/NA 05/29/23 22:40
Prep 3005A 780920 RR EET SAVTotal Recoverable 05/30/23 06:22
Analysis 6010D 1 781123 BJB EET SAVTotal Recoverable 05/30/23 15:48
Prep 3005A 780921 RR EET SAVTotal Recoverable 05/30/23 06:22
Analysis 6020B 1 781125 BJB EET SAVTotal Recoverable 05/30/23 23:10
Prep 7470A 781000 JKL EET SAVTotal/NA 05/30/23 10:34
Analysis 7470A 1 781270 JKL EET SAVTotal/NA 05/31/23 09:44
Client Sample ID: 7601-MW7 Lab Sample ID: 752-7507-3
Matrix: WaterDate Collected: 05/22/23 09:44
Date Received: 05/25/23 10:00
Analysis 8260 SIM NTA1781127 EET SAV
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA 05/31/23 15:36
Analysis 8260D 1 3101 RY EET ESCTotal/NA 06/02/23 20:21
Prep 3510C 780784 MR EET SAVTotal/NA 05/27/23 12:41
Analysis 8270E 1 780901 T1C EET SAVTotal/NA 05/29/23 19:46
Prep 3005A 780926 RR EET SAVTotal Recoverable 05/30/23 06:51
Analysis 6010D 1 781123 BJB EET SAVTotal Recoverable 05/30/23 14:34
Prep 3005A 780928 RR EET SAVTotal Recoverable 05/30/23 06:51
Analysis 6020B 1 781125 BJB EET SAVTotal Recoverable 05/30/23 20:32
Prep 7470A 781000 JKL EET SAVTotal/NA 05/30/23 10:34
Analysis 7470A 1 781270 JKL EET SAVTotal/NA 05/31/23 09:46
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Lab Chronicle
Client: WSP USA Inc Job ID: 752-7507-1
Project/Site: Randolph County Landfill
Client Sample ID: 7601-MW8 Lab Sample ID: 752-7507-4
Matrix: WaterDate Collected: 05/23/23 10:50
Date Received: 05/25/23 10:00
Analysis 8260 SIM NTA1781127 EET SAV
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA 05/31/23 16:02
Analysis 8260D 1 3113 RY EET ESCTotal/NA 06/03/23 06:40
Prep 3510C 780784 MR EET SAVTotal/NA 05/27/23 12:41
Analysis 8270E 1 780901 T1C EET SAVTotal/NA 05/29/23 23:02
Prep 3005A 780926 RR EET SAVTotal Recoverable 05/30/23 06:51
Analysis 6010D 1 781123 BJB EET SAVTotal Recoverable 05/30/23 14:44
Prep 3005A 780928 RR EET SAVTotal Recoverable 05/30/23 06:51
Analysis 6020B 1 781125 BJB EET SAVTotal Recoverable 05/30/23 20:44
Prep 7470A 781000 JKL EET SAVTotal/NA 05/30/23 10:34
Analysis 7470A 1 781270 JKL EET SAVTotal/NA 05/31/23 09:54
Client Sample ID: 7601-MW9 Lab Sample ID: 752-7507-5
Matrix: WaterDate Collected: 05/23/23 09:35
Date Received: 05/25/23 10:00
Analysis 8260 SIM NTA1781391 EET SAV
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA 06/01/23 16:31
Analysis 8260D 1 3113 RY EET ESCTotal/NA 06/03/23 07:10
Prep 3510C 780784 MR EET SAVTotal/NA 05/27/23 12:41
Analysis 8270E 1 780901 T1C EET SAVTotal/NA 05/29/23 23:24
Prep 3005A 780926 RR EET SAVTotal Recoverable 05/30/23 06:51
Analysis 6010D 1 781123 BJB EET SAVTotal Recoverable 05/30/23 14:48
Prep 3005A 780928 RR EET SAVTotal Recoverable 05/30/23 06:51
Analysis 6020B 1 781125 BJB EET SAVTotal Recoverable 05/30/23 20:48
Prep 7470A 781000 JKL EET SAVTotal/NA 05/30/23 10:34
Analysis 7470A 1 781270 JKL EET SAVTotal/NA 05/31/23 09:55
Client Sample ID: 7601-SW1 Lab Sample ID: 752-7507-6
Matrix: WaterDate Collected: 05/23/23 10:35
Date Received: 05/25/23 10:00
Analysis 8260 SIM NTA1781127 EET SAV
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA 05/31/23 16:53
Analysis 8260D 1 3113 RY EET ESCTotal/NA 06/03/23 07:39
Prep 3005A 780920 RR EET SAVTotal Recoverable 05/30/23 06:22
Analysis 6010D 1 781123 BJB EET SAVTotal Recoverable 05/30/23 15:51
Prep 3005A 780921 RR EET SAVTotal Recoverable 05/30/23 06:22
Analysis 6020B 1 781125 BJB EET SAVTotal Recoverable 05/30/23 23:27
Client Sample ID: 7601-SW2 Lab Sample ID: 752-7507-7
Matrix: WaterDate Collected: 05/23/23 11:16
Date Received: 05/25/23 10:00
Analysis 8260 SIM NTA1781127 EET SAV
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA 05/31/23 17:18
Eurofins Raleigh
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Lab Chronicle
Client: WSP USA Inc Job ID: 752-7507-1
Project/Site: Randolph County Landfill
Client Sample ID: 7601-SW2 Lab Sample ID: 752-7507-7
Matrix: WaterDate Collected: 05/23/23 11:16
Date Received: 05/25/23 10:00
Analysis 8260D RY13113 EET ESC
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA 06/03/23 08:09
Prep 3005A 780920 RR EET SAVTotal Recoverable 05/30/23 06:22
Analysis 6010D 1 781123 BJB EET SAVTotal Recoverable 05/30/23 15:54
Prep 3005A 780921 RR EET SAVTotal Recoverable 05/30/23 06:22
Analysis 6020B 1 781125 BJB EET SAVTotal Recoverable 05/30/23 23:31
Client Sample ID: 7601-SW3 Lab Sample ID: 752-7507-8
Matrix: WaterDate Collected: 05/24/23 12:35
Date Received: 05/25/23 10:00
Analysis 8260 SIM NTA1781127 EET SAV
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA 05/31/23 17:43
Analysis 8260D 1 3113 RY EET ESCTotal/NA 06/03/23 08:39
Prep 3005A 780920 RR EET SAVTotal Recoverable 05/30/23 06:22
Analysis 6010D 1 781123 BJB EET SAVTotal Recoverable 05/30/23 15:58
Prep 3005A 780921 RR EET SAVTotal Recoverable 05/30/23 06:22
Analysis 6020B 1 781125 BJB EET SAVTotal Recoverable 05/30/23 23:35
Client Sample ID: 7601-SW4 Lab Sample ID: 752-7507-9
Matrix: WaterDate Collected: 05/24/23 13:07
Date Received: 05/25/23 10:00
Analysis 8260 SIM NTA1781127 EET SAV
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA 05/31/23 18:08
Analysis 8260D 1 3113 RY EET ESCTotal/NA 06/03/23 09:08
Prep 3005A 780920 RR EET SAVTotal Recoverable 05/30/23 06:22
Analysis 6010D 1 781123 BJB EET SAVTotal Recoverable 05/30/23 16:01
Prep 3005A 780921 RR EET SAVTotal Recoverable 05/30/23 06:22
Analysis 6020B 1 781125 BJB EET SAVTotal Recoverable 05/30/23 23:39
Client Sample ID: 7601-Trip Blank Lab Sample ID: 752-7507-10
Matrix: WaterDate Collected: 05/22/23 14:45
Date Received: 05/25/23 10:00
Analysis 8260D RY13101 EET ESC
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA 06/02/23 22:48
Laboratory References:
EET ESC = Eurofins Raleigh, 102-A Woodwinds Industrial Court, Cary, NC 27511, TEL [phone]
EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL [phone]
Eurofins Raleigh
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Accreditation/Certification Summary
Client: WSP USA Inc Job ID: 752-7507-1
Project/Site: Randolph County Landfill
Laboratory: Eurofins Raleigh
The accreditations/certifications listed below are applicable to this report.
Authority Program Identification Number Expiration Date
North Carolina (WW/SW)State 591 12-31-23
Laboratory: Eurofins Savannah
The accreditations/certifications listed below are applicable to this report.
Authority Program Identification Number Expiration Date
North Carolina (WW/SW)State 269 12-31-23
Eurofins Raleigh
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Method Summary
Job ID: 752-7507-1Client: WSP USA Inc
Project/Site: Randolph County Landfill
Method Method Description LaboratoryProtocol
SW8468260 SIM 1,4-Dioxane by SIM EET SAV
SW8468260DVolatile Organic Compounds by GC/MS EET ESC
SW8468270ESemivolatile Organic Compounds (GC/MS)EET SAV
SW8466010DMetals (ICP)EET SAV
SW8466020BMetals (ICP/MS)EET SAV
SW8467470AMercury (CVAA)EET SAV
SW8463005APreparation, Total Recoverable or Dissolved Metals EET SAV
SW8463510CLiquid-Liquid Extraction (Separatory Funnel)EET SAV
SW8465030CPurge and Trap EET ESC
SW8465030CPurge and Trap EET SAV
SW8467470APreparation, Mercury EET SAV
Protocol References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
EET ESC = Eurofins Raleigh, 102-A Woodwinds Industrial Court, Cary, NC 27511, TEL [phone]
EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL [phone]
Eurofins Raleigh
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Sample Summary
Client: WSP USA Inc Job ID: 752-7507-1
Project/Site: Randolph County Landfill
Lab Sample ID Client Sample ID Matrix Collected Received
752-7507-1 7601-MW10S Water 05/22/23 14:45 05/25/23 10:00
752-7507-2 7601-MW6 Water 05/23/23 11:15 05/25/23 10:00
752-7507-3 7601-MW7 Water 05/22/23 09:44 05/25/23 10:00
752-7507-4 7601-MW8 Water 05/23/23 10:50 05/25/23 10:00
752-7507-5 7601-MW9 Water 05/23/23 09:35 05/25/23 10:00
752-7507-6 7601-SW1 Water 05/23/23 10:35 05/25/23 10:00
752-7507-7 7601-SW2 Water 05/23/23 11:16 05/25/23 10:00
752-7507-8 7601-SW3 Water 05/24/23 12:35 05/25/23 10:00
752-7507-9 7601-SW4 Water 05/24/23 13:07 05/25/23 10:00
752-7507-10 7601-Trip Blank Water 05/22/23 14:45 05/25/23 10:00
Eurofins RaleighPage 58 of 63 6/6/2023
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Login Sample Receipt Checklist
Client: WSP USA Inc Job Number: 752-7507-1
Login Number: 7507
Question Answer Comment
Creator: Yonish, Rachel
List Source: Eurofins Raleigh
List Number: 1
TrueRadioactivity wasn't checked or is </= background as measured by a survey
meter.
TrueThe cooler's custody seal, if present, is intact.
TrueSample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or
tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate
HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
TrueSample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
TrueContainers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
TrueResidual Chlorine Checked.
Eurofins Raleigh
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Login Sample Receipt Checklist
Client: WSP USA Inc Job Number: 752-7507-1
Login Number: 7507
Question Answer Comment
Creator: Harley, Tynisha
List Source: Eurofins Savannah
List Creation: 05/26/23 02:19 PMList Number: 2
N/ARadioactivity wasn't checked or is </= background as measured by a survey
meter.
TrueThe cooler's custody seal, if present, is intact.
TrueSample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or
tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate
HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
N/ASample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
N/AContainers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
Eurofins Raleigh
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WSP USA INC
QUALITY ASSURANCE & QUALITY CONTROL
LABORATORY DATA REVIEW
Page 1 of 4

Project Name: Randolph County Landfill
Project Reference Number: 31404568.018
Sampling Event Date: May 22 - 24, 2023
Review Date: August 8, 2023 Initials: JS
Report #: 752-7507-1 Review: MS
Person(s) performing the review are to initial each item on this form as acknowledgement of data
acceptance, or as acknowledgement of a review issue. In the case of the latter, a brief explanation
should follow the applicable item.

WSP USA Inc. has reviewed the laboratory certificates of analysis, chain-of-custody form, and laboratory
provided sample group quality assurance and quality control data for the above referenced sample group
to identify potential bias or inaccuracy, in general accordance with the following United States
Environmental Protection Agency documents:

 Region III Modifications to Functional Guidelines for Organic Data Review Multi-Media, Multi-
Concentration, September 1994;
 Region III Modifications to the Laboratory Data Validation Functional Guidelines for Evaluating
Inorganic Analyses, April 1993; and
 Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, July 1998.

COMPLIANCE ANALYTE LIST(S) (check all that apply)

NC Closed Facility List (.500 Rules)
NC C & D List (New Rules)
NC Appendix I Metals + VOAs + 1,4-Dioxane
NC Appendix I + Detects
NC Appendix II + Cyanide
NC Subtitle D Leachate List
Other: (Hg, Diethyl phthalate, Dichlorodifluoromethane [MWs only])

1.0 CHAIN OF CUSTODY (COC) REVIEW

JS COC was properly signed by all parties.

JS Correct project name and number are on the form.

JS Sample receipt condition at laboratory was acceptable.

JS Each sample and blank submitted for analysis appears in the report.

2.0 SAMPLE HOLDING TIMES

JS Holding times for extraction and/or analysis were met for each analytical method (see below for
reference).

Review Criteria
Method Analytes Holding Time
SW-846 Method 8260 and 8011 VOCs 14 days
SW-846 Methods 8270, 8080, 8081,
8082, and 8151
SVOCs, PCBs, pesticides
and herbicides
7 days for extraction, 40 days
from extraction for analysis
SW-846 Methods 6000 and 7000
Series
Metals except mercury 6 months (no temperature
requirements)
SW-846 Method 7470 Mercury 28 days
WSP USA INC
QUALITY ASSURANCE & QUALITY CONTROL
LABORATORY DATA REVIEW
Page 2 of 4

SW-846 Method 376.1 Sulfide 7 days
SW-846 Method 9010 Cyanide 14 days
EPA Method 300 Nitrate/Sulfate 48 hours/28 days
EPA Method 405.1 BOD 48 hours
EPA Method 410.4 COD 28 days
EPA Method 365.4 Phosphorous 28 days

3.0 LABORATORY QUALITY CONTROL REVIEW

JS Laboratory analyzed at least one internal blank for each method, where applicable.

JS Laboratory blank is interference-free.

 Chloroform in trip blank @ 0.205 ug/L (J)

JS Surrogate recoveries are provided for each analytical method, where applicable.

JS Surrogate recoveries for each method are within the acceptable limits (i.e., at least
50% of the surrogates were within range).

JS MS/MSD/LCS data results are provided for each analytical method.

JS MS/MSD/LCS recoveries for each method are within the acceptable limits (i.e., at least 1 of the 3
were within range).

Method 7470A – Mercury (CVAA)
 The matrix spike / matrix spike duplicate (MS/MSD) recoveries for analytical batch 781270
were outside control limits for Mercury. No laboratory comment was given for this
detection. (Sample ID: 752-7507-3 MS/MSD)

GC/MS VOA, Method 8260D
 The matrix spike / matrix spike duplicate (MS/MSD) recoveries for analytical batch 752-3101
were outside control limits for Carbon tetrachloride. Sample matrix interference and/or
non-homogeneity are suspected because the associated laboratory control sample (LCS)
recovery is within acceptance limits.
 The CCV for analytical batch 752-3101 recovered outside control limits for the following
analyte(s): 2-Butanone (MEK), 2-Hexanone, Acetone, Acrylonitrile, Bromomethane,
Chloroethane, Chloromethane and Trichlorofluoromethane. These have been identified as
poor performing analytes when analyzed using this method; therefore, re-extraction/re-
analysis was not performed. These results have been reported and qualified.
 The continuing calibration verification (CCV) associated with batch 752-3101 recovered
above the upper control limit for 1,1,1-Trichloroethane, 1,2-Dichloroethane and Carbon
tetrachloride. The samples associated with this CCV were non-detects for the affected
analytes; therefore, the data have been reported.
 The continuing calibration verification (CCV) associated with batch 752-3101 recovered
outside acceptance criteria, low biased, for Dibromofluoromethane (Surr), Toluene-d8
(Surr) and Vinyl chloride. A reporting limit (RL) standard was analyzed, and the target
analytes are detected. Since the associated samples were non-detect for the analyte(s),
the data are reported.
 The CCV for analytical batch 752-3113 recovered outside control limits for the following
analyte(s): 2-Hexanone, Acrylonitrile, Bromomethane, Chloroethane, Chloromethane and
Trichlorofluoromethane. These compounds have been identified as a poor performing
analytes when analyzed using this method; therefore, re-extraction/re-analysis was not
WSP USA INC
QUALITY ASSURANCE & QUALITY CONTROL
LABORATORY DATA REVIEW
Page 3 of 4

performed. These results have been reported and qualified.
 The continuing calibration verification (CCV) associated with batch 752-3113 recovered
outside acceptance criteria, low biased, for Dibromofluoromethane (Surr), Toluene-d8
(Surr) and Vinyl chloride. A reporting limit (RL) standard was analyzed, and the target
analytes are detected. Since the associated samples were non-detect for the analyte(s),
the data are reported.
 The continuing calibration verification (CCV) associated with batch 752-3113 recovered
above the upper control limit for 1,2-Dichloroethane and Carbon tetrachloride. The
samples associated with this CCV were non-detects for the affected analytes; therefore,
the data have been reported.
GC/MS Semi VOA, Method 8270E
 The continuing calibration verification (CCV) analyzed in batch 680-780901 was outside the
method criteria for the following analyte(s): Diethyl phthalate. A CCV standard at or below
the reporting limit (RL) was analyzed with the affected samples and found to be
acceptable. As indicated in the reference method, sample analysis may proceed; however,
any detection for the affected analyte(s) is considered estimated.

4.0 ANALYTE LISTS/METHODS

JS The proper number of constituents are present for each analyte list as identified above (including
detects where applicable).

JS Proper EPA SW-846 analytical methods were used for analysis.

5.0 DATA REPORTING

JS All analytical reporting associated with the event was performed by the contracted lab.

JS Trip, field and/or equipment, and laboratory blank results have all been reported. All detects for blanks
are listed below by constituent. All laboratory method blanks, if any, have been ‘flagged’ with a ‘B’
where detected in other samples as appropriate and a laboratory narrative was provided. If the
sample was flagged by the laboratory and is not within 5X of the concentration in the blank (or 10X
for commonly detected laboratory contaminants-acetone, methylene chloride and phthalates), list
below with explanation if flags should be removed. If flags need to be added for samples, also list
below.

 Trip Blank – Chloroform @ 0.205 (J)
 MW-8 @ 0.181 ug/L (J). B flag added.
 SW-3 @ 0.725 ug/L (J). B flag added.
 SW-4 @ 0.733 ug/L (J). B flag added.

 Method Blank – Methylene Chloride @ 0.2518 (J)
 MW-10s @ 0.241 ug/L (J). B flag added

JS It is clear from the laboratory report that samples have or have not been diluted during analysis, and if
the samples have been diluted, the result is reported as a multiple of the dilution (e.g., a sample
diluted 10x resulting in an analytical detection of 1.0 should be reported as 10). Those that have
been diluted are listed below with the dilution factor.

JS The report provides the reporting limit for each constituent.

JS The results were reported at or below their proper reporting limits with the proper reporting limit listed
WSP USA INC
QUALITY ASSURANCE & QUALITY CONTROL
LABORATORY DATA REVIEW
Page 4 of 4

beside them. State if the reporting limit error is due to dilutions.

JS No organic constituents were reported above their respective detection limits, and no inorganic or
organic constituents were reported above their respective NC 2L Drinking Water Standards/GWPS
in wells, or field/equipment/trip blanks, or above applicable surface water standards in surface water
points.

 1,1-Dichloroethane (NC 2L = 6 ug/L)
 MW-10S @ 38.3 ug/L

 1,4-Dioxane (NC 2L = 3 ug/L)
 MW-6 @ 9.11 ug/L
 MW-10S @ 24.4 ug/L
 Tetrachloroethene (NC 2L = 0.7 ug/L)
 MW-10S @ 2.54 ug/L

 Vinyl Chloride (NC 2L = 0.03 ug/L)
 MW-10S @ 0.665 ug/L (J)
 Cobalt (NC 2L = 1 ug/L)
 MW-6 @ 1.56 ug/L (J)
 MW-7 @ 10.9 ug/L

JS No inorganic and organic constituents were detected in a well or surface water point at quantified
concentrations outside of their historical range (more than 5X previous concentrations or first-time
detections).

 Chloroform (1st time detection)
 MW-8 @ 0.181 ug/L (B)

 Chloromethane (1st time detection since 2007)
 MW-6 @ 0.147 ug/L (J)

 Bromodichloromethane (1st time detection since 2007)
 SW-4 @ 0.287 ug/L (J)

JS Other report issues/Communications with laboratory/etc.:

Cover
ANALYTICAL RESULTS

PERFORMED BY

Pace Analytical Gulf Coast
7979 Innovation Park Dr.
Baton Rouge, LA 70820
[phone]

Report Date 06/12/2023

Report # 223052434
9999999999

Project Randolph Co 31404568.018

Samples Collected 5/22/23

Deliver To Additional Recipients
Darren Cox Matthew Scheidt, WSP
WSP / Golder
5B Oak Branch Dr
Greensboro, NC 27407

LELAP Certificate Number: 01955
A2LA Accredited (DoD ELAP-QSM 5.4) Certificate Number: 6429.01

Page 1 of 2806/12/2023 15:41Pace Gulf Coast Report#: 223052434

Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

Laboratory Endorsement

Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized
agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this
retention period the samples will be disposed in accordance with Pace Gulf Coast's Standard Operating Procedures.

Common Abbreviations that may be Utilized in this Report

ND Indicates the result was Not Detected at the specified reporting limit
NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030
DO Indicates the result was Diluted Out
MI Indicates the result was subject to Matrix Interference
TNTC Indicates the result was Too Numerous To Count
SUBC Indicates the analysis was Sub-Contracted FLD Indicates the analysis was performed in the Field
DL Detection Limit
LOD Limit of Detection
LOQ Limit of Quantitation
RE Re-analysis CF HPLC or GC Confirmation
00:01 Reported as a time equivalent to 12:00 AM

Reporting Flags that may be Utilized in this Report

J or I Indicates the result is between the MDL and LOQ
J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria
U Indicates the compound was analyzed for but not detected
B or V Indicates the analyte was detected in the associated Method Blank
Q Indicates a non-compliant QC Result (See Q Flag Application Report)
* Indicates a non-compliant or not applicable QC recovery or RPD – see narrative
E Organics - The result is estimated because it exceeded the instrument calibration range
E Metals - % diference for the serial dilution is > 10%
L Reporting Limits adjusted to meet risk-based limit.
P RPD between primary and confirmation result is greater than 40 DL Diluted analysis – when appended to Client Sample ID

Sample receipt at Pace Gulf Coast is documented through the attached chain of custody. In accordance with NELAC, this report shall be
reproduced only in full and with the written permission of Pace Gulf Coast. The results contained within this report relate only to the samples
reported. The documented results are presented within this report.

This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited.

I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and
Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee,
as verified by the following signature.

Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if
applicable.

Authorized Signature Pace Gulf Coast Report 223052434

Page 2 of 2806/12/2023 15:41Pace Gulf Coast Report#: 223052434

Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

Certifications

Certification Certification Number

Page 3 of 2806/12/2023 15:41Pace Gulf Coast Report#: 223052434

Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

Case Narrative
Client: Golder Associates - NC Report: 223052434
Pace Analytical Gulf Coast received and analyzed the sample(s) listed
on the Report Sample Summary page of this report. Receipt of the sample(s) is documented
by the attached chain of custody. This applies only to the sample(s) listed in this report.
No sample integrity or quality control exceptions were identified unless noted below.
VOLATILES MASS SPECTROMETRY
MSV: Batch 52880 in the Opening CCV, several non target analytes failed but all target analytes passed.
MISCELLANEOUS
See subcontract laboratory report case narrative.

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Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

Sample Summary
Lab ID Client ID Matrix Collect Date Receive Date
22305243401 MW-8 Water 5/22/23 10:50 5/23/23 10:10
22305243402 MW-3 Water 5/22/23 13:20 5/23/23 10:10
22305243403 MW-11S Water 5/22/23 14:58 5/23/23 10:10
22305243404 MW-2 Water 5/22/23 12:30 5/23/23 10:10
22305243405 MW-7 Water 5/22/23 09:44 5/23/23 10:10
22305243406 MW-10S Water 5/22/23 14:45 5/23/23 10:10
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Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

Detect Summary
Results and Detection Limits are adjusted for dilution and moisture when applicable

AM23G
Lab ID Client ID Parameter Units Result Dil. %Moist
22305243401 MW-8 Acetic Acid mg/L 1.1 1 NA
22305243401 MW-8 Formic Acid mg/L 5.2 1 NA
22305243401 MW-8 Lactic Acid mg/L 0.72 1 NA
22305243401 MW-8 Propionic Acid mg/L 0.19J 1 NA
22305243402 MW-3 Acetic Acid mg/L 1.1 1 NA
22305243402 MW-3 Formic Acid mg/L 5.4 1 NA
22305243402 MW-3 Lactic Acid mg/L 0.46J 1 NA
22305243402 MW-3 Propionic Acid mg/L 0.19J 1 NA
22305243403 MW-11S Acetic Acid mg/L 1.2 1 NA
22305243403 MW-11S Formic Acid mg/L 6.1 1 NA
22305243403 MW-11S Lactic Acid mg/L 0.25J 1 NA
22305243403 MW-11S Propionic Acid mg/L 0.24J 1 NA
22305243404 MW-2 Acetic Acid mg/L 1.1 1 NA
22305243404 MW-2 Formic Acid mg/L 5.0 1 NA
22305243404 MW-2 Propionic Acid mg/L 0.19J 1 NA
22305243405 MW-7 Acetic Acid mg/L 1.0 1 NA
22305243405 MW-7 Formic Acid mg/L 5.6 1 NA
22305243405 MW-7 Propionic Acid mg/L 0.17J 1 NA
22305243406 MW-10S Acetic Acid mg/L 8.5 10 NA
22305243406 MW-10S Formic Acid mg/L 51 10 NA
22305243406 MW-10S Propionic Acid mg/L 1.7J 10 NA

EPA 9034
Lab ID Client ID Parameter Units Result Dil. %Moist
22305243401 MW-8 Sulfide mg/L 3.2 1 NA
22305243402 MW-3 Sulfide mg/L 5.0 1 NA
22305243403 MW-11S Sulfide mg/L 2.2 1 NA
22305243404 MW-2 Sulfide mg/L 4.4 1 NA
22305243405 MW-7 Sulfide mg/L 3.2 1 NA
22305243406 MW-10S Sulfide mg/L 4.0 1 NA

EPA 9056A
Lab ID Client ID Parameter Units Result Dil. %Moist
22305243401 MW-8 Chloride mg/L 7.60 1 NA
22305243401 MW-8 Sulfate mg/L 0.906 1 NA
22305243402 MW-3 Chloride mg/L 7.48 1 NA
22305243402 MW-3 Nitrate mg/L-N 0.102J 1 NA
22305243402 MW-3 Sulfate mg/L 1.80 1 NA
22305243403 MW-11S Chloride mg/L 6.52 1 NA
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Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

Detect Summary (Continued)
Results and Detection Limits are adjusted for dilution and moisture when applicable

EPA 9056A
Lab ID Client ID Parameter Units Result Dil. %Moist
22305243403 MW-11S Sulfate mg/L 0.579 1 NA
22305243404 MW-2 Chloride mg/L 13.8 2 NA
22305243404 MW-2 Sulfate mg/L 2.40 1 NA
22305243405 MW-7 Chloride mg/L 8.65 1 NA
22305243405 MW-7 Sulfate mg/L 0.707 1 NA
22305243406 MW-10S Chloride mg/L 38.6 5 NA
22305243406 MW-10S Sulfate mg/L 9.56 1 NA

EPA 9060A
Lab ID Client ID Parameter Units Result Dil. %Moist
22305243401 MW-8 Total Organic Carbon mg/L 1.47J 1 NA
22305243402 MW-3 Total Organic Carbon mg/L 1.96J 1 NA
22305243403 MW-11S Total Organic Carbon mg/L 1.01J 1 NA
22305243404 MW-2 Total Organic Carbon mg/L 4.93 1 NA
22305243405 MW-7 Total Organic Carbon mg/L 4.38 1 NA
22305243406 MW-10S Total Organic Carbon mg/L 3.26 1 NA

SM 2320 B-2011
Lab ID Client ID Parameter Units Result Dil. %Moist
22305243401 MW-8 Total Alkalinity mg/L CaCO3 79.0 1 NA
22305243402 MW-3 Total Alkalinity mg/L CaCO3 66.6 1 NA
22305243403 MW-11S Total Alkalinity mg/L CaCO3 32.4 1 NA
22305243404 MW-2 Total Alkalinity mg/L CaCO3 4.0 1 NA
22305243405 MW-7 Total Alkalinity mg/L CaCO3 33.0 1 NA
22305243406 MW-10S Total Alkalinity mg/L CaCO3 91.6 1 NA

SM 3500-Fe B-2011
Lab ID Client ID Parameter Units Result Dil. %Moist
22305243401 MW-8 Ferrous Iron mg/L 0.021J 1 NA
22305243402 MW-3 Ferrous Iron mg/L 0.024J 1 NA
22305243405 MW-7 Ferrous Iron mg/L 0.055 1 NA

EPA 8260B
Lab ID Client ID Parameter Units Result Dil. %Moist
22305243404 MW-2 1,1-Dichloroethane ug/L 3.58J 1 NA
22305243405 MW-7 1,1-Dichloroethane ug/L 0.403J 1 NA
22305243405 MW-7 Trichloroethene ug/L 0.412J 1 NA
22305243406 MW-10S 1,1-Dichloroethane ug/L 38.9 1 NA
22305243406 MW-10S Tetrachloroethene ug/L 1.87J 1 NA
22305243406 MW-10S Vinyl chloride ug/L 0.879J 1 NA
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Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

Sample Results Sample Results
MW-8
MW-8 Collect Date 05/22/2023 10:50 Lab ID 22305243401
Receive Date 05/23/2023 10:10 Matrix Water

AM23G
AM23G

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/25/23 21:24 766494 LHM NA
CAS# Parameter Result DL LOQ Units
64-19-7 Acetic Acid 1.1 0.12 0.50 mg/L
107-92-6 Butyric Acid 0.058U 0.058 0.50 mg/L
64-18-6 Formic Acid 5.2 0.055 0.50 mg/L
142-62-1 Hexanoic Acid 0.058U 0.058 0.50 mg/L
646-07-1 i-Hexanoic Acid 0.056U 0.056 0.50 mg/L
503-74-2 i-Pentanoic Acid 0.061U 0.061 0.50 mg/L
50-21-5 Lactic Acid 0.72 0.053 0.50 mg/L
109-52-4 Pentanoic Acid 0.056U 0.056 0.50 mg/L
79-09-4 Propionic Acid 0.19J 0.053 0.50 mg/L
127-17-3 Pyruvic Acid 0.060U 0.060 0.50 mg/L
EPA 9034
EPA 9034
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/26/23 13:00 766574 RYC NA

CAS# Parameter Result DL LOQ Units
18496-25-8 Sulfide 3.2 1.1 2.0 mg/L
EPA 9056A
EPA 9056A
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/23/23 11:50 766209 CS NA

CAS# Parameter Result DL LOQ Units
16887-00-6 Chloride 7.60 0.050 0.200 mg/L
14797-55-8 Nitrate 0.100U 0.100 0.200 mg/L-N
14808-79-8 Sulfate 0.906 0.100 0.200 mg/L
EPA 9060A
EPA 9060A *Results are reported on a dry weight basis.
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/31/23 11:33 766751 CCL NA

CAS# Parameter Result DL LOQ Units
C-012 Total Organic Carbon 1.47J 0.300 2.00 mg/L
Page 8 of 2806/12/2023 15:41Pace Gulf Coast Report#: 223052434

Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

Sample Results

MW-8 Collect Date 05/22/2023 10:50 Lab ID 22305243401
Receive Date 05/23/2023 10:10 Matrix Water

HACH 8000
HACH 8000

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/25/23 13:27 766484 RYC NA
CAS# Parameter Result DL LOQ Units
C-004 COD 1.7U 1.7 5.0 mg/L
SM 2320 B-2011
SM 2320 B-2011
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/25/23 12:08 766520 MMP NA

CAS# Parameter Result DL LOQ Units
000000-00-5 Total Alkalinity 79.0 0.26 1.0 mg/L CaCO3
SM 3500-Fe B-2011
SM 3500-Fe B-2011
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/23/23 15:00 766458 RYC NA

CAS# Parameter Result DL LOQ Units
WET-045 Ferrous Iron 0.021J 0.014 0.050 mg/L
SM 5210 B-2016
SM 5210 B-2016
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
05/23/23 11:53 766364 BOD PREP 1 05/23/23 11:53 766638 MLG NA

CAS# Parameter Result DL LOQ Units
C-002 BOD 3U 3 3 mg/L
Subcontract Work
Subcontract Work
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA Subcontract Work 1 06/12/23 14:22 NA CW NA

CAS# Parameter Result DL LOQ Units
SHIP-001 Ship Result * mg/L
Page 9 of 2806/12/2023 15:41Pace Gulf Coast Report#: 223052434

Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

Sample Results

MW-8 Collect Date 05/22/2023 10:50 Lab ID 22305243401
Receive Date 05/23/2023 10:10 Matrix Water

-
Subcontract Work

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA Subcontract Work 1 06/12/23 14:22 NA CW NA
CAS# Parameter Result DL LOQ Units
SHIP-002 Ship Result * mg/L
MW-3
MW-3 Collect Date 05/22/2023 13:20 Lab ID 22305243402
Receive Date 05/23/2023 10:10 Matrix Water
AM23G
AM23G
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/25/23 22:15 766494 LHM NA

CAS# Parameter Result DL LOQ Units
64-19-7 Acetic Acid 1.1 0.12 0.50 mg/L
107-92-6 Butyric Acid 0.058U 0.058 0.50 mg/L
64-18-6 Formic Acid 5.4 0.055 0.50 mg/L
142-62-1 Hexanoic Acid 0.058U 0.058 0.50 mg/L
646-07-1 i-Hexanoic Acid 0.056U 0.056 0.50 mg/L
503-74-2 i-Pentanoic Acid 0.061U 0.061 0.50 mg/L
50-21-5 Lactic Acid 0.46J 0.053 0.50 mg/L
109-52-4 Pentanoic Acid 0.056U 0.056 0.50 mg/L
79-09-4 Propionic Acid 0.19J 0.053 0.50 mg/L
127-17-3 Pyruvic Acid 0.060U 0.060 0.50 mg/L
EPA 9034
EPA 9034

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/26/23 13:00 766574 RYC NA
CAS# Parameter Result DL LOQ Units
18496-25-8 Sulfide 5.0 1.1 2.0 mg/L
EPA 9056A
EPA 9056A

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/23/23 12:24 766209 CS NA
CAS# Parameter Result DL LOQ Units
16887-00-6 Chloride 7.48 0.050 0.200 mg/L
14797-55-8 Nitrate 0.102J 0.100 0.200 mg/L-N
14808-79-8 Sulfate 1.80 0.100 0.200 mg/L
Page 10 of 2806/12/2023 15:41Pace Gulf Coast Report#: 223052434

Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

Sample Results

MW-3 Collect Date 05/22/2023 13:20 Lab ID 22305243402
Receive Date 05/23/2023 10:10 Matrix Water

EPA 9060A
EPA 9060A *Results are reported on a dry weight basis.

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/31/23 12:46 766751 CCL NA
CAS# Parameter Result DL LOQ Units
C-012 Total Organic Carbon 1.96J 0.300 2.00 mg/L
HACH 8000
HACH 8000
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/25/23 13:27 766484 RYC NA

CAS# Parameter Result DL LOQ Units
C-004 COD 1.7U 1.7 5.0 mg/L
SM 2320 B-2011
SM 2320 B-2011
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/25/23 12:08 766520 MMP NA

CAS# Parameter Result DL LOQ Units
000000-00-5 Total Alkalinity 66.6 0.26 1.0 mg/L CaCO3
SM 3500-Fe B-2011
SM 3500-Fe B-2011
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/23/23 15:02 766458 RYC NA

CAS# Parameter Result DL LOQ Units
WET-045 Ferrous Iron 0.024J 0.014 0.050 mg/L
SM 5210 B-2016
SM 5210 B-2016
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
05/23/23 11:53 766364 BOD PREP 1 05/23/23 11:53 766638 MLG NA

CAS# Parameter Result DL LOQ Units
C-002 BOD 3U 3 3 mg/L
Page 11 of 2806/12/2023 15:41Pace Gulf Coast Report#: 223052434

Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

Sample Results

MW-3 Collect Date 05/22/2023 13:20 Lab ID 22305243402
Receive Date 05/23/2023 10:10 Matrix Water

Subcontract Work
Subcontract Work

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA Subcontract Work 1 06/12/23 14:22 NA CW NA
CAS# Parameter Result DL LOQ Units
SHIP-001 Ship Result * mg/L
-
Subcontract Work
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA Subcontract Work 1 06/12/23 14:22 NA CW NA

CAS# Parameter Result DL LOQ Units
SHIP-002 Ship Result * mg/L
MW-11S
MW-11S Collect Date 05/22/2023 14:58 Lab ID 22305243403
Receive Date 05/23/2023 10:10 Matrix Water
AM23G
AM23G
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/25/23 23:07 766494 LHM NA

CAS# Parameter Result DL LOQ Units
64-19-7 Acetic Acid 1.2 0.12 0.50 mg/L
107-92-6 Butyric Acid 0.058U 0.058 0.50 mg/L
64-18-6 Formic Acid 6.1 0.055 0.50 mg/L
142-62-1 Hexanoic Acid 0.058U 0.058 0.50 mg/L
646-07-1 i-Hexanoic Acid 0.056U 0.056 0.50 mg/L
503-74-2 i-Pentanoic Acid 0.061U 0.061 0.50 mg/L
50-21-5 Lactic Acid 0.25J 0.053 0.50 mg/L
109-52-4 Pentanoic Acid 0.056U 0.056 0.50 mg/L
79-09-4 Propionic Acid 0.24J 0.053 0.50 mg/L
127-17-3 Pyruvic Acid 0.060U 0.060 0.50 mg/L
EPA 9034
EPA 9034

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/26/23 13:00 766574 RYC NA
CAS# Parameter Result DL LOQ Units
18496-25-8 Sulfide 2.2 1.1 2.0 mg/L
Page 12 of 2806/12/2023 15:41Pace Gulf Coast Report#: 223052434

Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

Sample Results

MW-11S Collect Date 05/22/2023 14:58 Lab ID 22305243403
Receive Date 05/23/2023 10:10 Matrix Water

EPA 9056A
EPA 9056A

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/23/23 12:59 766209 CS NA
CAS# Parameter Result DL LOQ Units
16887-00-6 Chloride 6.52 0.050 0.200 mg/L
14797-55-8 Nitrate 0.100U 0.100 0.200 mg/L-N
14808-79-8 Sulfate 0.579 0.100 0.200 mg/L
EPA 9060A
EPA 9060A *Results are reported on a dry weight basis.
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/31/23 13:10 766751 CCL NA
CAS# Parameter Result DL LOQ Units
C-012 Total Organic Carbon 1.01J 0.300 2.00 mg/L
HACH 8000
HACH 8000

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/25/23 13:27 766484 RYC NA
CAS# Parameter Result DL LOQ Units
C-004 COD 1.7U 1.7 5.0 mg/L
SM 2320 B-2011
SM 2320 B-2011

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/25/23 12:08 766520 MMP NA
CAS# Parameter Result DL LOQ Units
000000-00-5 Total Alkalinity 32.4 0.26 1.0 mg/L CaCO3
SM 3500-Fe B-2011
SM 3500-Fe B-2011
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/23/23 15:02 766458 RYC NA

CAS# Parameter Result DL LOQ Units
WET-045 Ferrous Iron 0.014U 0.014 0.050 mg/L
Page 13 of 2806/12/2023 15:41Pace Gulf Coast Report#: 223052434

Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

Sample Results

MW-11S Collect Date 05/22/2023 14:58 Lab ID 22305243403
Receive Date 05/23/2023 10:10 Matrix Water

SM 5210 B-2016
SM 5210 B-2016

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
05/23/23 11:53 766364 BOD PREP 1 05/23/23 11:53 766638 MLG NA
CAS# Parameter Result DL LOQ Units
C-002 BOD 3U 3 3 mg/L
Subcontract Work
Subcontract Work
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA Subcontract Work 1 06/12/23 14:22 NA CW NA

CAS# Parameter Result DL LOQ Units
SHIP-001 Ship Result * mg/L
-
Subcontract Work
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA Subcontract Work 1 06/12/23 14:22 NA CW NA

CAS# Parameter Result DL LOQ Units
SHIP-002 Ship Result * mg/L
MW-2
MW-2 Collect Date 05/22/2023 12:30 Lab ID 22305243404
Receive Date 05/23/2023 10:10 Matrix Water
EPA 8260B
EPA 8260B
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/26/23 14:02 766594 KN1 NA

CAS# Parameter Result DL LOQ Units
75-34-3 1,1-Dichloroethane 3.58J 0.200 5.00 ug/L
127-18-4 Tetrachloroethene 0.200U 0.200 5.00 ug/L
79-01-6 Trichloroethene 0.200U 0.200 5.00 ug/L
75-01-4 Vinyl chloride 0.200U 0.200 2.00 ug/L
CAS# Surrogate Conc Spiked Conc Rec Units %Recovery %Rec Limits
460-00-4 4-Bromofluorobenzene 50 52.8 ug/L 106 78 - 130
1868-53-7 Dibromofluoromethane 50 57.9 ug/L 116 77 - 127
2037-26-5 Toluene d8 50 53.2 ug/L 106 76 - 134
17060-07-0 1,2-Dichloroethane-d4 50 56.9 ug/L 114 71 - 127
Page 14 of 2806/12/2023 15:41Pace Gulf Coast Report#: 223052434

Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

Sample Results

MW-2 Collect Date 05/22/2023 12:30 Lab ID 22305243404
Receive Date 05/23/2023 10:10 Matrix Water

AM23G
AM23G

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/25/23 23:58 766494 LHM NA
CAS# Parameter Result DL LOQ Units
64-19-7 Acetic Acid 1.1 0.12 0.50 mg/L
107-92-6 Butyric Acid 0.058U 0.058 0.50 mg/L
64-18-6 Formic Acid 5.0 0.055 0.50 mg/L
142-62-1 Hexanoic Acid 0.058U 0.058 0.50 mg/L
646-07-1 i-Hexanoic Acid 0.056U 0.056 0.50 mg/L
503-74-2 i-Pentanoic Acid 0.061U 0.061 0.50 mg/L
50-21-5 Lactic Acid 0.053U 0.053 0.50 mg/L
109-52-4 Pentanoic Acid 0.056U 0.056 0.50 mg/L
79-09-4 Propionic Acid 0.19J 0.053 0.50 mg/L
127-17-3 Pyruvic Acid 0.060U 0.060 0.50 mg/L
EPA 9034
EPA 9034
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/26/23 13:00 766574 RYC NA

CAS# Parameter Result DL LOQ Units
18496-25-8 Sulfide 4.4 1.1 2.0 mg/L
EPA 9056A
EPA 9056A
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/23/23 12:07 766209 CS NA

CAS# Parameter Result DL LOQ Units
14797-55-8 Nitrate 0.100U 0.100 0.200 mg/L-N
14808-79-8 Sulfate 2.40 0.100 0.200 mg/L
-
EPA 9056A *Results and limits are adjusted for dilution.

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 2 05/25/23 15:36 766545 CS NA
CAS# Parameter Result DL LOQ Units
16887-00-6 Chloride 13.8 0.100 0.400 mg/L
Page 15 of 2806/12/2023 15:41Pace Gulf Coast Report#: 223052434

Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

Sample Results

MW-2 Collect Date 05/22/2023 12:30 Lab ID 22305243404
Receive Date 05/23/2023 10:10 Matrix Water

EPA 9060A
EPA 9060A *Results are reported on a dry weight basis.

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/31/23 13:37 766751 CCL NA
CAS# Parameter Result DL LOQ Units
C-012 Total Organic Carbon 4.93 0.300 2.00 mg/L
HACH 8000
HACH 8000
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/25/23 13:27 766484 RYC NA

CAS# Parameter Result DL LOQ Units
C-004 COD 1.7U 1.7 5.0 mg/L
SM 2320 B-2011
SM 2320 B-2011
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 06/05/23 09:48 767024 MMP NA

CAS# Parameter Result DL LOQ Units
000000-00-5 Total Alkalinity 4.0 0.26 1.0 mg/L CaCO3
SM 3500-Fe B-2011
SM 3500-Fe B-2011
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/23/23 15:01 766458 RYC NA

CAS# Parameter Result DL LOQ Units
WET-045 Ferrous Iron 0.014U 0.014 0.050 mg/L
SM 5210 B-2016
SM 5210 B-2016
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
05/23/23 11:53 766364 BOD PREP 1 05/23/23 11:53 766638 MLG NA

CAS# Parameter Result DL LOQ Units
C-002 BOD 3U 3 3 mg/L
Page 16 of 2806/12/2023 15:41Pace Gulf Coast Report#: 223052434

Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

Sample Results

MW-2 Collect Date 05/22/2023 12:30 Lab ID 22305243404
Receive Date 05/23/2023 10:10 Matrix Water

Subcontract Work
Subcontract Work

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA Subcontract Work 1 06/12/23 14:22 NA CW NA
CAS# Parameter Result DL LOQ Units
SHIP-001 Ship Result * mg/L
-
Subcontract Work
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA Subcontract Work 1 06/12/23 14:22 NA CW NA

CAS# Parameter Result DL LOQ Units
SHIP-002 Ship Result * mg/L
MW-7
MW-7 Collect Date 05/22/2023 09:44 Lab ID 22305243405
Receive Date 05/23/2023 10:10 Matrix Water
EPA 8260B
EPA 8260B
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/26/23 18:14 766594 KN1 NA

CAS# Parameter Result DL LOQ Units
75-34-3 1,1-Dichloroethane 0.403J 0.200 5.00 ug/L
127-18-4 Tetrachloroethene 0.200U 0.200 5.00 ug/L
79-01-6 Trichloroethene 0.412J 0.200 5.00 ug/L
75-01-4 Vinyl chloride 0.200U 0.200 2.00 ug/L
CAS# Surrogate Conc Spiked Conc Rec Units %Recovery %Rec Limits
460-00-4 4-Bromofluorobenzene 50 52.3 ug/L 105 78 - 130
1868-53-7 Dibromofluoromethane 50 56.7 ug/L 113 77 - 127
2037-26-5 Toluene d8 50 51.6 ug/L 103 76 - 134
17060-07-0 1,2-Dichloroethane-d4 50 56.3 ug/L 113 71 - 127
AM23G
AM23G
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/26/23 00:50 766494 LHM NA

CAS# Parameter Result DL LOQ Units
64-19-7 Acetic Acid 1.0 0.12 0.50 mg/L
107-92-6 Butyric Acid 0.058U 0.058 0.50 mg/L
64-18-6 Formic Acid 5.6 0.055 0.50 mg/L
142-62-1 Hexanoic Acid 0.058U 0.058 0.50 mg/L
646-07-1 i-Hexanoic Acid 0.056U 0.056 0.50 mg/L
503-74-2 i-Pentanoic Acid 0.061U 0.061 0.50 mg/L
50-21-5 Lactic Acid 0.053U 0.053 0.50 mg/L
109-52-4 Pentanoic Acid 0.056U 0.056 0.50 mg/L
79-09-4 Propionic Acid 0.17J 0.053 0.50 mg/L
Page 17 of 2806/12/2023 15:41Pace Gulf Coast Report#: 223052434

Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

Sample Results

MW-7 Collect Date 05/22/2023 09:44 Lab ID 22305243405
Receive Date 05/23/2023 10:10 Matrix Water

AM23G (Continued)
AM23G (Continued)

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/26/23 00:50 766494 LHM NA
CAS# Parameter Result DL LOQ Units
127-17-3 Pyruvic Acid 0.060U 0.060 0.50 mg/L
EPA 9034
EPA 9034
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/26/23 13:00 766574 RYC NA

CAS# Parameter Result DL LOQ Units
18496-25-8 Sulfide 3.2 1.1 2.0 mg/L
EPA 9056A
EPA 9056A
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/23/23 11:33 766209 CS NA

CAS# Parameter Result DL LOQ Units
16887-00-6 Chloride 8.65 0.050 0.200 mg/L
14797-55-8 Nitrate 0.100U 0.100 0.200 mg/L-N
14808-79-8 Sulfate 0.707 0.100 0.200 mg/L
EPA 9060A
EPA 9060A *Results are reported on a dry weight basis.

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/31/23 14:24 766751 CCL NA
CAS# Parameter Result DL LOQ Units
C-012 Total Organic Carbon 4.38 0.300 2.00 mg/L
HACH 8000
HACH 8000
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/25/23 13:28 766484 RYC NA

CAS# Parameter Result DL LOQ Units
C-004 COD 1.7U 1.7 5.0 mg/L
Page 18 of 2806/12/2023 15:41Pace Gulf Coast Report#: 223052434

Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

Sample Results

MW-7 Collect Date 05/22/2023 09:44 Lab ID 22305243405
Receive Date 05/23/2023 10:10 Matrix Water

SM 2320 B-2011
SM 2320 B-2011

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 06/02/23 14:01 766937 MMP NA
CAS# Parameter Result DL LOQ Units
000000-00-5 Total Alkalinity 33.0 0.26 1.0 mg/L CaCO3
SM 3500-Fe B-2011
SM 3500-Fe B-2011
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/23/23 14:59 766458 RYC NA

CAS# Parameter Result DL LOQ Units
WET-045 Ferrous Iron 0.055 0.014 0.050 mg/L
SM 5210 B-2016
SM 5210 B-2016
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
05/23/23 11:53 766364 BOD PREP 1 05/23/23 11:53 766638 MLG NA

CAS# Parameter Result DL LOQ Units
C-002 BOD 3U 3 3 mg/L
Subcontract Work
Subcontract Work
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA Subcontract Work 1 06/12/23 14:22 NA CW NA

CAS# Parameter Result DL LOQ Units
SHIP-001 Ship Result * mg/L
-
Subcontract Work
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA Subcontract Work 1 06/12/23 14:22 NA CW NA

CAS# Parameter Result DL LOQ Units
SHIP-002 Ship Result * mg/L
Page 19 of 2806/12/2023 15:41Pace Gulf Coast Report#: 223052434

Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

Sample Results
MW-10S
MW-10S Collect Date 05/22/2023 14:45 Lab ID 22305243406
Receive Date 05/23/2023 10:10 Matrix Water

EPA 8260B
EPA 8260B

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/26/23 18:36 766594 KN1 NA
CAS# Parameter Result DL LOQ Units
75-34-3 1,1-Dichloroethane 38.9 0.200 5.00 ug/L
127-18-4 Tetrachloroethene 1.87J 0.200 5.00 ug/L
79-01-6 Trichloroethene 0.200U 0.200 5.00 ug/L
75-01-4 Vinyl chloride 0.879J 0.200 2.00 ug/L
CAS# Surrogate Conc Spiked Conc Rec Units %Recovery %Rec Limits
460-00-4 4-Bromofluorobenzene 50 52.3 ug/L 105 78 - 130
1868-53-7 Dibromofluoromethane 50 57 ug/L 114 77 - 127
2037-26-5 Toluene d8 50 54 ug/L 108 76 - 134
17060-07-0 1,2-Dichloroethane-d4 50 56.2 ug/L 112 71 - 127
AM23G
AM23G *Results and limits are adjusted for dilution.

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 10 05/26/23 01:41 766494 LHM NA
CAS# Parameter Result DL LOQ Units
64-19-7 Acetic Acid 8.5 1.2 5.0 mg/L
107-92-6 Butyric Acid 0.58U 0.58 5.0 mg/L
64-18-6 Formic Acid 51 0.55 5.0 mg/L
142-62-1 Hexanoic Acid 0.58U 0.58 5.0 mg/L
646-07-1 i-Hexanoic Acid 0.56U 0.56 5.0 mg/L
503-74-2 i-Pentanoic Acid 0.61U 0.61 5.0 mg/L
50-21-5 Lactic Acid 0.53U 0.53 5.0 mg/L
109-52-4 Pentanoic Acid 0.56U 0.56 5.0 mg/L
79-09-4 Propionic Acid 1.7J 0.53 5.0 mg/L
127-17-3 Pyruvic Acid 0.60U 0.60 5.0 mg/L
EPA 9034
EPA 9034
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/26/23 13:00 766574 RYC NA

CAS# Parameter Result DL LOQ Units
18496-25-8 Sulfide 4.0 1.1 2.0 mg/L
EPA 9056A
EPA 9056A
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/23/23 12:42 766209 CS NA

CAS# Parameter Result DL LOQ Units
14797-55-8 Nitrate 0.100U 0.100 0.200 mg/L-N
14808-79-8 Sulfate 9.56 0.100 0.200 mg/L
Page 20 of 2806/12/2023 15:41Pace Gulf Coast Report#: 223052434

Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

Sample Results

MW-10S Collect Date 05/22/2023 14:45 Lab ID 22305243406
Receive Date 05/23/2023 10:10 Matrix Water

-
EPA 9056A *Results and limits are adjusted for dilution.

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 5 05/25/23 15:52 766545 CS NA
CAS# Parameter Result DL LOQ Units
16887-00-6 Chloride 38.6 0.250 1.00 mg/L
EPA 9060A
EPA 9060A *Results are reported on a dry weight basis.
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/31/23 14:50 766751 CCL NA

CAS# Parameter Result DL LOQ Units
C-012 Total Organic Carbon 3.26 0.300 2.00 mg/L
HACH 8000
HACH 8000
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/25/23 13:28 766484 RYC NA

CAS# Parameter Result DL LOQ Units
C-004 COD 1.7U 1.7 5.0 mg/L
SM 2320 B-2011
SM 2320 B-2011
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/25/23 12:08 766520 MMP NA

CAS# Parameter Result DL LOQ Units
000000-00-5 Total Alkalinity 91.6 0.26 1.0 mg/L CaCO3
SM 3500-Fe B-2011
SM 3500-Fe B-2011
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/23/23 15:00 766458 RYC NA

CAS# Parameter Result DL LOQ Units
WET-045 Ferrous Iron 0.014U 0.014 0.050 mg/L
Page 21 of 2806/12/2023 15:41Pace Gulf Coast Report#: 223052434

Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

Sample Results

MW-10S Collect Date 05/22/2023 14:45 Lab ID 22305243406
Receive Date 05/23/2023 10:10 Matrix Water

SM 5210 B-2016
SM 5210 B-2016

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
05/23/23 11:53 766364 BOD PREP 1 05/23/23 11:53 766638 MLG NA
CAS# Parameter Result DL LOQ Units
C-002 BOD 3U 3 3 mg/L
Subcontract Work
Subcontract Work
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA Subcontract Work 1 06/12/23 14:22 NA CW NA

CAS# Parameter Result DL LOQ Units
SHIP-001 Ship Result * mg/L
-
Subcontract Work
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA Subcontract Work 1 06/12/23 14:22 NA CW NA

CAS# Parameter Result DL LOQ Units
SHIP-002 Ship Result * mg/L
Page 22 of 2806/12/2023 15:41Pace Gulf Coast Report#: 223052434

Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

QC Summary GC/MS Volatiles QC Summary
GC/MS Volatiles
Analytical Batch
766594

Client ID
Lab ID
Sample Type Prep Date
Analysis Date
Matrix

MB766594
2487626
MB NA
05/26/23 12:32
Water

LCS766594
2487627
LCS NA
05/26/23 11:11
Water

EPA 8260B Units
Result
ug/L
DL
Spike
Added Result %R Control
Limits%R
1,1-Dichloroethane 75-34-3 0.200U 0.200 50.0 48.1 96 74 - 127
Tetrachloroethene 127-18-4 0.200U 0.200 50.0 47.3 95 68 - 128 Trichloroethene 79-01-6 0.200U 0.200 50.0 47.8 96 76 - 129
Vinyl chloride 75-01-4 0.200U 0.200 50.0 44.5 89 68 - 132
Surrogate CAS# Rec %R Added Rec %R Limits
1,2-Dichloroethane-d4 17060-07-0 55 110 50 55 110 71 - 127
4-Bromofluorobenzene 460-00-4 52.6 105 50 55 110 78 - 130
Dibromofluoromethane 1868-53-7 57.9 116 50 55.5 111 77 - 127
Toluene d8 2037-26-5 54.4 109 50 51.6 103 76 - 134

Page 23 of 2806/12/2023 15:41Pace Gulf Coast Report#: 223052434

Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

General Chemistry QC Summary
General Chemistry Analytical Batch
766520

Client ID
Lab ID
Sample Type
Prep Date
Analysis Date
Matrix
MB766520
2487245
MB
NA
05/25/23 12:08
Water
LCS766520
2488175
LCS
NA
05/25/23 12:08
Water
LCSD766520
2487247
LCSD
NA
05/25/23 12:08
Water
SM 2320 B-2011 Units
Result
mg/L CaCO3
DL
Spike
Added Result %R Control
Limits%R
Spike
Added Result %R RPD RPD
Limit
Total Alkalinity 000000-00-5 0.26U 0.26 200 197 99 90 - 110 200 199 99

Analytical Batch
766937

Client ID
Lab ID
Sample Type
Prep Date Analysis Date
Matrix

MB766937
2489326
MB
NA 06/02/23 14:01
Water

LCS766937
2489327
LCS
NA 06/02/23 14:01
Water

LCSD766937
2489328
LCSD
NA 06/02/23 14:01
Water

SM 2320 B-2011 Units
Result
mg/L CaCO3
DL
Spike
Added Result %R Control
Limits%R
Spike
Added Result %R RPD RPD
Limit
Total Alkalinity 000000-00-5 0.26U 0.26 200 202 101 90 - 110 200 201 101 0 11

Analytical Batch
767024

Client ID
Lab ID
Sample Type
Prep Date
Analysis Date
Matrix

MB767024
2489766
MB
NA
06/05/23 09:48
Water

LCS767024
2489767
LCS
NA
06/05/23 09:48
Water

LCSD767024
2489768
LCSD
NA
06/05/23 09:48
Water

SM 2320 B-2011 Units
Result
mg/L CaCO3
DL
Spike
Added Result %R Control
Limits%R
Spike
Added Result %R RPD RPD
Limit
Total Alkalinity 000000-00-5 0.26U 0.26 10.0 9.6 96 90 - 110 10.0 10.1 100 4 11

Analytical Batch
766638
Prep Batch
766364
Prep Method
BOD PREP

Client ID
Lab ID
Sample Type
Prep Date
Analysis Date
Matrix

MB766364
2486425
MB 05/23/23 11:53
05/23/23 11:53
Water

LCS766364
2486427
LCS
05/23/23 11:53
05/23/23 11:53
Water

SM 5210 B-2016 Units
Result
mg/L
DL
Spike
Added Result %R Control
Limits%R
BOD C-002 3U 3 198 172 87 84.5 - 115.5

Analytical Batch
766574
Client ID
Lab ID Sample Type
Prep Date
Analysis Date
Matrix

MB766574
2487581 MB
NA
05/26/23 13:00
Water

LCS766574
2487582 LCS
NA
05/26/23 13:00
Water

LCSD766574
2487583 LCSD
NA
05/26/23 13:00
Water

EPA 9034 Units
Result
mg/L
DL
Spike
Added Result %R Control
Limits%R
Spike
Added Result %R RPD RPD
Limit
Sulfide 18496-25-8 1.1U 1.1 25.0 25.4 102 50 - 120 25.0 25.6 103 1 25

Analytical Batch
766484
Client ID
Lab ID
Sample Type
Prep Date
Analysis Date
Matrix

MB766484 2487101
MB
NA
05/25/23 13:21
Water

LCS766484
2487102
LCS
NA
05/25/23 13:21
Water

LCSD766484
2487103
LCSD
NA
05/25/23 13:22
Water

HACH 8000 Units
Result
mg/L
DL
Spike
Added Result %R Control
Limits%R
Spike
Added Result %R RPD RPD
Limit
COD C-004 1.8J 1.7 75.0 74.6 99 90 - 110 75.0 71.5 95 4 20
Page 24 of 2806/12/2023 15:41Pace Gulf Coast Report#: 223052434

Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

General Chemistry QC Summary
Analytical Batch
766458
Client ID
Lab ID
Sample Type
Prep Date
Analysis Date
Matrix
MB766458
2486953
MB
NA
05/23/23 14:58
Water
LCS766458
2486954
LCS
NA
05/23/23 14:58
Water
LCSD766458
2486955
LCSD
NA
05/23/23 14:59
Water
SM 3500-Fe B-2011 Units Result mg/L DL Spike Added Result %R Control Limits%R Spike Added Result %R RPD RPD Limit
Ferrous Iron WET-045 0.014U 0.014 1.00 1.01 101 89.5 - 110.5 1.00 1.03 102 1 20

Analytical Batch
766494
Client ID
Lab ID
Sample Type
Prep Date
Analysis Date
Matrix
MB766494
2487143
MB
NA
05/25/23 15:23
Water
LCS766494
2487144
LCS
NA
05/25/23 16:15
Water
LCSD766494
2487145
LCSD
NA
05/25/23 17:06
Water
AM23G Units
Result
mg/L
DL
Spike
Added Result %R Control
Limits%R
Spike
Added Result %R RPD RPD
Limit
Acetic Acid 64-19-7 0.12U 0.12 2.0 2.1 107 70 - 130 2.0 2.1 107 0 20
Butyric Acid 107-92-6 0.058U 0.058 2.0 2.1 104 70 - 130 2.0 2.1 104 0 20
Formic Acid 64-18-6 0.055U 0.055 2.0 2.0 99 70 - 130 2.0 2.0 98 1 20
Hexanoic Acid 142-62-1 0.058U 0.058 2.0 2.1 103 70 - 130 2.0 2.1 103 0 20
i-Hexanoic Acid 646-07-1 0.056U 0.056 2.0 2.0 100 70 - 130 2.0 1.9 96 4 20
i-Pentanoic Acid 503-74-2 0.061U 0.061 2.0 2.1 104 70 - 130 2.0 2.0 100 4 20
Lactic Acid 50-21-5 0.053U 0.053 2.0 2.2 111 70 - 130 2.0 2.2 111 0 20
Pentanoic Acid 109-52-4 0.056U 0.056 2.0 2.1 105 70 - 130 2.0 2.1 106 1 20
Propionic Acid 79-09-4 0.053U 0.053 2.0 2.1 105 70 - 130 2.0 2.1 105 0 20
Pyruvic Acid 127-17-3 0.060U 0.060 2.0 2.0 102 70 - 130 2.0 2.1 104 2 20

Analytical Batch
766209
Client ID
Lab ID
Sample Type
Prep Date
Analysis Date
Matrix
MB766209 2485841
MB
NA
05/23/23 10:13
Water
LCS766209
2485842
LCS
NA
05/23/23 10:30
Water
LCSD766209
2485843
LCSD
NA
05/23/23 10:48
Water
EPA 9056A Units
Result
mg/L
DL
Spike
Added Result %R Control
Limits%R
Spike
Added Result %R RPD RPD
Limit
Chloride 16887-00-6 0.050U 0.050 2.50 2.48 99 80 - 120 2.50 2.48 99 0 15
Nitrate 14797-55-8 0.100U 0.100 2.50 2.47 99 80 - 120 2.50 2.47 99 0 15
Sulfate 14808-79-8 0.100U 0.100 2.50 2.50 100 80 - 120 2.50 2.50 100 0 15

Analytical Batch
766545

Client ID
Lab ID
Sample Type Prep Date
Analysis Date
Matrix

MB766545
2487513
MB NA
05/25/23 13:05
Water

LCS766545
2487514
LCS NA
05/25/23 13:22
Water

LCSD766545
2487515
LCSD NA
05/25/23 13:39
Water

EPA 9056A Units
Result
mg/L
DL
Spike
Added Result %R Control
Limits%R
Spike
Added Result %R RPD RPD
Limit
Chloride 16887-00-6 0.050U 0.050 2.50 2.46 98 80 - 120 2.50 2.45 98 0 15

Analytical Batch
766751

Client ID
Lab ID
Sample Type
Prep Date
Analysis Date
Matrix

MB766751
2488438
MB
NA
05/31/23 11:09
Water

LCS766751
2488439
LCS
NA
05/31/23 10:20
Water

LCSD766751
2488440
LCSD
NA
05/31/23 10:44
Water

EPA 9060A Units
Result
mg/L
DL
Spike
Added Result %R Control
Limits%R
Spike
Added Result %R RPD RPD
Limit
Total Organic Carbon C-012 0.300U 0.300 50.0 50.5 101 90 - 110 50.0 50.7 101 0 20
Page 25 of 2806/12/2023 15:41Pace Gulf Coast Report#: 223052434

Report#: 223052434
Project ID: Randolph Co 31404568.018 Report Date: 06/12/2023

General Chemistry QC Summary
Analytical Batch
766751
Client ID
Lab ID
Sample Type
Prep Date
Analysis Date
Matrix
MW-8
22305243401
SAMPLE
NA
05/31/2023 11:33
Water
2486798MS
2488446
MS
NA
05/31/23 11:58
Water
2486798MSD
2488447
MSD
NA
05/31/23 12:21
Water
EPA 9060A Units Result mg/L DL Spike Added Result %R Control Limits%R Spike Added Result %R RPD RPD Limit
Total Organic Carbon C-012 1.47 0.300 50.0 49.3 96 80 - 120 50.0 51.8 101 5 20

Page 26 of 2806/12/2023 15:41Pace Gulf Coast Report#: 223052434
Page 27 of 2806/12/2023 15:41Pace Gulf Coast Report#: 223052434
SAMPLE RECEIVING CHECKLIST *223052434*
SAMPLE DELIVERY GROUP 223052434
Client PM RWe Transport Method
Golder - NC - Golder Associates
- NC
Profile Number Received By
300930 Perkins, Brennan
McCune, Dodie N.
Line Item(s)Receive Date(s)
3 - Waters 05/23/23
CHECKLIST YES NO
Samples received with proper thermal preservation?
Radioactivity is <1600 cpm? If no, record cpm value in notes section.
COC relinquished and complete (including sampleIDs, collect times, and sampler)?
All containers received in good condition and within hold time?
All sample labels and containers received match the chain of custody?
Preservative added to any containers?
If received, was headspace for VOC water containers < 6mm?
Samples collected in containers provided by Pace Gulf Coast?
COOLERS
Airbill Thermometer ID:E43 Temp oC
772217571944 3.6
4.3
DISCREPANCIES
None
LAB PRESERVATIONS
None
NOTES EXTRA VIALS REC'D FOR 8260 NOT LISTED ON COC-LOGGED PER CONATINER
Revision 1.6 Page 1 of 1
Page 28 of 2806/12/2023 15:41Pace Gulf Coast Report#: 223052434
L2329703
Pace Analytical Gulf Coast
223052434
RANDOLPH LF
Client:
Project Name:
Project Number:
06/12/23
320 Forbes Boulevard, Mansfield, MA 02048-1806
Lab Number:
Report Date:
508-822-9300 (Fax) 508-822-3288 800-624-9220 - www.alphalab.com
7979 Innovation Park Drive
Baton Rouge, LA 70820
Ruth WelshATTN:
ANALYTICAL REPORT
Certifications & Approvals: MA (M-MA030), NH NELAP (2062), CT (PH-0825), DoD (L2474), FL (E87814), IL (200081), IN (C-MA-04), KY (KY98046),
LA (85084), ME (MA00030), MD (350), MI (99110) , NJ (MA015), NY (11627), NC (685), OH (CL106), OR (MA-0262), PA (68-02089), RI (LAO00299), TX
(T104704419), VT (VT-0015), VA (460194), WA (C954), US Army Corps of Engineers, USDA (Permit #525-23-107-88708), USFWS (Permit #206964).
[phone]Phone:
The original project report/data package is held by Alpha Analytical. This report/data package is paginated and should be reproduced only in its
entirety. Alpha Analytical holds no responsibility for results and/or data that are not consistent with the original.
Serial_No:06122314:43
Page 1 of 32
L2329703-01
L2329703-02
L2329703-03
L2329703-04
L2329703-05
L2329703-06
Alpha
Sample ID
MW-8
MW-3
MW-11S
MW-2
MW-7
MW-10S
Client ID
Not Specified
Not Specified
Not Specified
Not Specified
Not Specified
Not Specified
Sample
Location
RANDOLPH LF
223052434
Project Name:
Project Number:
Lab Number:
Report Date:
L2329703
06/12/23
05/22/23 10:50
05/22/23 13:20
05/22/23 14:58
05/22/23 12:30
05/22/23 09:44
05/22/23 14:45
Collection
Date/TimeMatrix Receive Date
WATER
WATER
WATER
WATER
WATER
WATER
05/27/23
05/27/23
05/27/23
05/27/23
05/27/23
05/27/23
Serial_No:06122314:43
Page 2 of 32
RANDOLPH LF
223052434
Project Name:
Project Number:
Lab Number:
Report Date:
L2329703
06/12/23
Case Narrative
The samples were received in accordance with the Chain of Custody and no significant deviations were encountered during the preparation
or analysis unless otherwise noted. Sample Receipt, Container Information, and the Chain of Custody are located at the back of the report.
Results contained within this report relate only to the samples submitted under this Alpha Lab Number and meet NELAP requirements for all
NELAP accredited parameters unless otherwise noted in the following narrative. The data presented in this report is organized by parameter
(i.e. VOC, SVOC, etc.). Sample specific Quality Control data (i.e. Surrogate Spike Recovery) is reported at the end of the target analyte list
for each individual sample, followed by the Laboratory Batch Quality Control at the end of each parameter. Tentatively Identified
Compounds (TICs), if requested, are reported for compounds identified to be present and are not part of the method/program Target
Compound List, even if only a subset of the TCL are being reported. If a sample was re-analyzed or re-extracted due to a required quality
control corrective action and if both sets of data are reported, the Laboratory ID of the re-analysis or re-extraction is designated with an "R"
or "RE", respectively.
When multiple Batch Quality Control elements are reported (e.g. more than one LCS), the associated samples for each element are noted in
the grey shaded header line of each data table. Any Laboratory Batch, Sample Specific % recovery or RPD value that is outside the listed
Acceptance Criteria is bolded in the report. In reference to questions H (CAM) or 4 (RCP) when "NO" is checked, the performance criteria
for CAM and RCP methods allow for some quality control failures to occur and still be within method compliance. In these instances, the
specific failure is not narrated but noted in the associated QC Outlier Summary Report, located directly after the Case Narrative. QC
information is also incorporated in the Data Usability Assessment table (Format 11) of our Data Merger tool, where it can be reviewed in
conjunction with the sample result, associated regulatory criteria and any associated data usability implications.
Soil/sediments, solids and tissues are reported on a dry weight basis unless otherwise noted. Definitions of all data qualifiers and acronyms
used in this report are provided in the Glossary located at the back of the report.
HOLD POLICY - For samples submitted on hold, Alpha's policy is to hold samples (with the exception of Air canisters) free of charge for 21
calendar days from the date the project is completed. After 21 calendar days, we will dispose of all samples submitted including those put
on hold unless you have contacted your Alpha Project Manager and made arrangements for Alpha to continue to hold the samples. Air
canisters will be disposed after 3 business days from the date the project is completed.
Please contact Project Management at 800-624-9220 with any questions.
Serial_No:06122314:43
Page 3 of 32
Case Narrative (continued)
RANDOLPH LF
223052434
Project Name:
Project Number:
Lab Number:
Report Date:
L2329703
06/12/23
Report Submission
All non-detect (ND) or estimated concentrations (J-qualified) have been quantitated to the limit noted in the
MDL column.
Carbon Dioxide
L2329703-01 through -06: The samples were analyzed with the method required holding time exceeded, per
client permission.

I, the undersigned, attest under the pains and penalties of perjury that, to the best of my knowledge and
belief and based upon my personal inquiry of those responsible for providing the information contained
in this analytical report, such information is accurate and complete. This certificate of analysis is not
complete unless this page accompanies any and all pages of this report.

Authorized Signature:
Title: Technical Director/Representative Date: 06/12/23
Serial_No:06122314:43
Page 4 of 32
ORGANICS
Serial_No:06122314:43
Page 5 of 32
VOLATILES
Serial_No:06122314:43
Page 6 of 32
FF
Methane
Ethene
Ethane
Parameter Result Dilution Factor
ND
ND
ND
ug/l
ug/l
ug/l
1
1
1
Qualifier Units RL
Dissolved Gases by GC - Mansfield Lab
SAMPLE RESULTS
Project Name:
Project Number:
Lab Number:
Report Date:
RANDOLPH LF
223052434
L2329703
2.00
0.500
0.500
06/12/23
MW-8Client ID:
05/22/23 10:50Date Collected:
05/27/23Date Received:
Not SpecifiedSample Location:
L2329703-01Lab ID:
Field Prep:Not Specified
Matrix:Water
Analytical Method:
Analytical Date:
Analyst:
117,-
05/31/23 17:30
SRO
MDL
2.00
0.500
0.500
A
A
A
Column
Sample Depth:
Serial_No:06122314:43
Page 7 of 32
Carbon Dioxide
Parameter Result Dilution Factor
24.1 mg/l 2
Qualifier Units RL
Dissolved Gases by GC - Mansfield Lab
SAMPLE RESULTS
Project Name:
Project Number:
Lab Number:
Report Date:
RANDOLPH LF
223052434
L2329703
6.00
06/12/23
MW-8Client ID:
05/22/23 10:50Date Collected:
05/27/23Date Received:
Not SpecifiedSample Location:
L2329703-01Lab ID:
Field Prep:Not Specified
D
Matrix:Water
Analytical Method:
Analytical Date:
Analyst:
117,-
05/30/23 12:43
SRO
MDL
6.00
Sample Depth:
Serial_No:06122314:43
Page 8 of 32
Methane
Ethene
Ethane
Parameter Result Dilution Factor
14.5
ND
ND
ug/l
ug/l
ug/l
1
1
1
Qualifier Units RL
Dissolved Gases by GC - Mansfield Lab
SAMPLE RESULTS
Project Name:
Project Number:
Lab Number:
Report Date:
RANDOLPH LF
223052434
L2329703
2.00
0.500
0.500
06/12/23
MW-3Client ID:
05/22/23 13:20Date Collected:
05/27/23Date Received:
Not SpecifiedSample Location:
L2329703-02Lab ID:
Field Prep:Not Specified
Matrix:Water
Analytical Method:
Analytical Date:
Analyst:
117,-
06/01/23 17:57
SRO
MDL
2.00
0.500
0.500
A
A
A
Column
Sample Depth:
Serial_No:06122314:43
Page 9 of 32
Carbon Dioxide
Parameter Result Dilution Factor
42.9 mg/l 2
Qualifier Units RL
Dissolved Gases by GC - Mansfield Lab
SAMPLE RESULTS
Project Name:
Project Number:
Lab Number:
Report Date:
RANDOLPH LF
223052434
L2329703
6.00
06/12/23
MW-3Client ID:
05/22/23 13:20Date Collected:
05/27/23Date Received:
Not SpecifiedSample Location:
L2329703-02Lab ID:
Field Prep:Not Specified
D
Matrix:Water
Analytical Method:
Analytical Date:
Analyst:
117,-
05/30/23 13:01
SRO
MDL
6.00
Sample Depth:
Serial_No:06122314:43
Page 10 of 32
Methane
Ethene
Ethane
Parameter Result Dilution Factor
3.65
ND
ND
ug/l
ug/l
ug/l
1
1
1
Qualifier Units RL
Dissolved Gases by GC - Mansfield Lab
SAMPLE RESULTS
Project Name:
Project Number:
Lab Number:
Report Date:
RANDOLPH LF
223052434
L2329703
2.00
0.500
0.500
06/12/23
MW-11SClient ID:
05/22/23 14:58Date Collected:
05/27/23Date Received:
Not SpecifiedSample Location:
L2329703-03Lab ID:
Field Prep:Not Specified
Matrix:Water
Analytical Method:
Analytical Date:
Analyst:
117,-
06/01/23 18:15
SRO
MDL
2.00
0.500
0.500
A
A
A
Column
Sample Depth:
Serial_No:06122314:43
Page 11 of 32
Carbon Dioxide
Parameter Result Dilution Factor
39.2 mg/l 2
Qualifier Units RL
Dissolved Gases by GC - Mansfield Lab
SAMPLE RESULTS
Project Name:
Project Number:
Lab Number:
Report Date:
RANDOLPH LF
223052434
L2329703
6.00
06/12/23
MW-11SClient ID:
05/22/23 14:58Date Collected:
05/27/23Date Received:
Not SpecifiedSample Location:
L2329703-03Lab ID:
Field Prep:Not Specified
D
Matrix:Water
Analytical Method:
Analytical Date:
Analyst:
117,-
05/30/23 13:48
SRO
MDL
6.00
Sample Depth:
Serial_No:06122314:43
Page 12 of 32
Methane
Ethene
Ethane
Parameter Result Dilution Factor
39.3
ND
ND
ug/l
ug/l
ug/l
1
1
1
Qualifier Units RL
Dissolved Gases by GC - Mansfield Lab
SAMPLE RESULTS
Project Name:
Project Number:
Lab Number:
Report Date:
RANDOLPH LF
223052434
L2329703
2.00
0.500
0.500
06/12/23
MW-2Client ID:
05/22/23 12:30Date Collected:
05/27/23Date Received:
Not SpecifiedSample Location:
L2329703-04Lab ID:
Field Prep:Not Specified
Matrix:Water
Analytical Method:
Analytical Date:
Analyst:
117,-
06/01/23 18:33
SRO
MDL
2.00
0.500
0.500
A
A
A
Column
Sample Depth:
Serial_No:06122314:43
Page 13 of 32
Carbon Dioxide
Parameter Result Dilution Factor
69.9 mg/l 2
Qualifier Units RL
Dissolved Gases by GC - Mansfield Lab
SAMPLE RESULTS
Project Name:
Project Number:
Lab Number:
Report Date:
RANDOLPH LF
223052434
L2329703
6.00
06/12/23
MW-2Client ID:
05/22/23 12:30Date Collected:
05/27/23Date Received:
Not SpecifiedSample Location:
L2329703-04Lab ID:
Field Prep:Not Specified
D
Matrix:Water
Analytical Method:
Analytical Date:
Analyst:
117,-
05/30/23 14:05
SRO
MDL
6.00
Sample Depth:
Serial_No:06122314:43
Page 14 of 32
Methane
Ethene
Ethane
Parameter Result Dilution Factor
864
ND
ND
ug/l
ug/l
ug/l
1
1
1
Qualifier Units RL
Dissolved Gases by GC - Mansfield Lab
SAMPLE RESULTS
Project Name:
Project Number:
Lab Number:
Report Date:
RANDOLPH LF
223052434
L2329703
2.00
0.500
0.500
06/12/23
MW-7Client ID:
05/22/23 09:44Date Collected:
05/27/23Date Received:
Not SpecifiedSample Location:
L2329703-05Lab ID:
Field Prep:Not Specified
Matrix:Water
Analytical Method:
Analytical Date:
Analyst:
117,-
06/01/23 18:51
SRO
MDL
2.00
0.500
0.500
A
A
A
Column
Sample Depth:
Serial_No:06122314:43
Page 15 of 32
Carbon Dioxide
Parameter Result Dilution Factor
228 mg/l 2
Qualifier Units RL
Dissolved Gases by GC - Mansfield Lab
SAMPLE RESULTS
Project Name:
Project Number:
Lab Number:
Report Date:
RANDOLPH LF
223052434
L2329703
6.00
06/12/23
MW-7Client ID:
05/22/23 09:44Date Collected:
05/27/23Date Received:
Not SpecifiedSample Location:
L2329703-05Lab ID:
Field Prep:Not Specified
D
Matrix:Water
Analytical Method:
Analytical Date:
Analyst:
117,-
05/30/23 14:23
SRO
MDL
6.00
Sample Depth:
Serial_No:06122314:43
Page 16 of 32
Methane
Ethene
Ethane
Parameter Result Dilution Factor
263
ND
ND
ug/l
ug/l
ug/l
1
1
1
Qualifier Units RL
Dissolved Gases by GC - Mansfield Lab
SAMPLE RESULTS
Project Name:
Project Number:
Lab Number:
Report Date:
RANDOLPH LF
223052434
L2329703
2.00
0.500
0.500
06/12/23
MW-10SClient ID:
05/22/23 14:45Date Collected:
05/27/23Date Received:
Not SpecifiedSample Location:
L2329703-06Lab ID:
Field Prep:Not Specified
Matrix:Water
Analytical Method:
Analytical Date:
Analyst:
117,-
06/01/23 19:10
SRO
MDL
2.00
0.500
0.500
A
A
A
Column
Sample Depth:
Serial_No:06122314:43
Page 17 of 32
Carbon Dioxide
Parameter Result Dilution Factor
166 mg/l 2
Qualifier Units RL
Dissolved Gases by GC - Mansfield Lab
SAMPLE RESULTS
Project Name:
Project Number:
Lab Number:
Report Date:
RANDOLPH LF
223052434
L2329703
6.00
06/12/23
MW-10SClient ID:
05/22/23 14:45Date Collected:
05/27/23Date Received:
Not SpecifiedSample Location:
L2329703-06Lab ID:
Field Prep:Not Specified
D
Matrix:Water
Analytical Method:
Analytical Date:
Analyst:
117,-
05/30/23 14:40
SRO
MDL
6.00
Sample Depth:
Serial_No:06122314:43
Page 18 of 32
Method Blank Analysis
Batch Quality Control
Project Name:
Project Number:
Lab Number:
Report Date:
RANDOLPH LF
223052434
L2329703
05/30/23 08:56
117,-Analytical Method:
Analytical Date:
06/12/23
Analyst:SRO
Carbon Dioxide
Parameter Result
ND
RL
3.00mg/l
UnitsQualifier
Dissolved Gases by GC - Mansfield Lab for sample(s): 01-06 Batch: WG1784795-3
MDL
3.00
Serial_No:06122314:43
Page 19 of 32
Method Blank Analysis
Batch Quality Control
Project Name:
Project Number:
Lab Number:
Report Date:
RANDOLPH LF
223052434
L2329703
05/31/23 09:03
117,-Analytical Method:
Analytical Date:
06/12/23
Analyst:SRO
Methane
Ethene
Ethane
Parameter Result
ND
ND
ND
RL
2.00
0.500
0.500
ug/l
ug/l
ug/l
UnitsQualifier
Dissolved Gases by GC - Mansfield Lab for sample(s): 01 Batch: WG1785274-3
MDL
2.00
0.500
0.500
A
A
A
Serial_No:06122314:43
Page 20 of 32
Method Blank Analysis
Batch Quality Control
Project Name:
Project Number:
Lab Number:
Report Date:
RANDOLPH LF
223052434
L2329703
06/01/23 15:04
117,-Analytical Method:
Analytical Date:
06/12/23
Analyst:SRO
Methane
Ethene
Ethane
Parameter Result
ND
ND
ND
RL
2.00
0.500
0.500
ug/l
ug/l
ug/l
UnitsQualifier
Dissolved Gases by GC - Mansfield Lab for sample(s): 02-06 Batch: WG1786081-3
MDL
2.00
0.500
0.500
A
A
A
Serial_No:06122314:43
Page 21 of 32
Carbon Dioxide 95 -80-120 -
Parameter
LCS
%Recovery
LCSD
%Recovery
%Recovery
Limits RPD
RPD
Limits
Dissolved Gases by GC - Mansfield Lab Associated sample(s): 01-06 Batch: WG1784795-2
Lab Control Sample Analysis
Batch Quality ControlProject Name:
Project Number:
Lab Number:
Report Date:
RANDOLPH LF
223052434
L2329703
06/12/23
Qual Qual Qual
Serial_No:06122314:43
Page 22 of 32
Methane
Ethene
Ethane
95
87
85
-
-
-
80-120
80-120
80-120
-
-
-
25
25
25
Parameter
LCS
%Recovery
LCSD
%Recovery
%Recovery
Limits RPD
RPD
Limits
Dissolved Gases by GC - Mansfield Lab Associated sample(s): 01 Batch: WG1785274-2
Lab Control Sample Analysis
Batch Quality ControlProject Name:
Project Number:
Lab Number:
Report Date:
RANDOLPH LF
223052434
L2329703
06/12/23
Qual Qual Qual Column
A
A
A
Serial_No:06122314:43
Page 23 of 32
Methane
Ethene
Ethane
102
89
87
-
-
-
80-120
80-120
80-120
-
-
-
25
25
25
Parameter
LCS
%Recovery
LCSD
%Recovery
%Recovery
Limits RPD
RPD
Limits
Dissolved Gases by GC - Mansfield Lab Associated sample(s): 02-06 Batch: WG1786081-2
Lab Control Sample Analysis
Batch Quality ControlProject Name:
Project Number:
Lab Number:
Report Date:
RANDOLPH LF
223052434
L2329703
06/12/23
Qual Qual Qual Column
A
A
A
Serial_No:06122314:43
Page 24 of 32
*Values in parentheses indicate holding time in days
L2329703-01A
L2329703-01B
L2329703-01C
L2329703-01D
L2329703-01E
L2329703-02A
L2329703-02B
L2329703-02C
L2329703-02D
L2329703-02E
L2329703-03A
L2329703-03B
L2329703-03C
L2329703-03D
L2329703-03E
L2329703-04A
L2329703-04B
L2329703-04C
L2329703-04D
L2329703-04E
L2329703-05A
L2329703-05B
L2329703-05C
20ml Vial HCl preserved
20ml Vial HCl preserved
20ml Vial HCl preserved
Vial unpreserved 20ml
Vial unpreserved 20ml
20ml Vial HCl preserved
20ml Vial HCl preserved
20ml Vial HCl preserved
Vial unpreserved 20ml
Vial unpreserved 20ml
20ml Vial HCl preserved
20ml Vial HCl preserved
20ml Vial HCl preserved
Vial unpreserved 20ml
Vial unpreserved 20ml
20ml Vial HCl preserved
20ml Vial HCl preserved
20ml Vial HCl preserved
Vial unpreserved 20ml
Vial unpreserved 20ml
20ml Vial HCl preserved
20ml Vial HCl preserved
20ml Vial HCl preserved
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.9
1.9
1.9
1.9
1.9
1.9
1.9
1.9
1.9
1.9
1.9
1.9
1.9
1.9
1.9
1.9
1.9
1.9
1.9
1.9
1.9
1.9
1.9
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
A Absent
Cooler Custody Seal
Cooler Information
RANDOLPH LF
223052434
DISSGAS(14)
DISSGAS(14)
DISSGAS(14)
DISSGAS-CO2(7)
DISSGAS-CO2(7)
DISSGAS(14)
DISSGAS(14)
DISSGAS(14)
DISSGAS-CO2(7)
DISSGAS-CO2(7)
DISSGAS(14)
DISSGAS(14)
DISSGAS(14)
DISSGAS-CO2(7)
DISSGAS-CO2(7)
DISSGAS(14)
DISSGAS(14)
DISSGAS(14)
DISSGAS-CO2(7)
DISSGAS-CO2(7)
DISSGAS(14)
DISSGAS(14)
DISSGAS(14)
Project Name:
Project Number:
L2329703Lab Number:
Report Date:
Sample Receipt and Container Information
Container ID Container Type Cooler
Temp
deg C Pres Seal
Container Information
Analysis(*)
06/12/23
Were project specific reporting limits specified?YES
Frozen
Date/Time
Final
pH
Initial
pH
Serial_No:06122314:43
Page 25 of 32
*Values in parentheses indicate holding time in days
L2329703-05D
L2329703-05E
L2329703-06A
L2329703-06B
L2329703-06C
L2329703-06D
L2329703-06E
Vial unpreserved 20ml
Vial unpreserved 20ml
20ml Vial HCl preserved
20ml Vial HCl preserved
20ml Vial HCl preserved
Vial unpreserved 20ml
Vial unpreserved 20ml
A
A
A
A
A
A
A
NA
NA
NA
NA
NA
NA
NA
1.9
1.9
1.9
1.9
1.9
1.9
1.9
Y
Y
Y
Y
Y
Y
Y
Absent
Absent
Absent
Absent
Absent
Absent
Absent
RANDOLPH LF
223052434
DISSGAS-CO2(7)
DISSGAS-CO2(7)
DISSGAS(14)
DISSGAS(14)
DISSGAS(14)
DISSGAS-CO2(7)
DISSGAS-CO2(7)
Project Name:
Project Number:
L2329703Lab Number:
Report Date:
Container ID Container Type Cooler
Temp
deg C Pres Seal
Container Information
Analysis(*)
06/12/23
Frozen
Date/Time
Final
pH
Initial
pH
Serial_No:06122314:43
Page 26 of 32
Report Format:DU Report with 'J' Qualifiers
GLOSSARY
Project Name:
Project Number:
Lab Number:
Report Date:
L2329703RANDOLPH LF
223052434 06/12/23
Acronyms
DL
EDL
EMPC
EPA
LCS
LCSD
LFB
LOD
LOQ
MDL
MS
MSD
NA
NC
NDPA/DPA
NI
NP
NR
RL
RPD
SRM
STLP
TEF
TEQ
TIC
Detection Limit: This value represents the level to which target analyte concentrations are reported as estimated values, when
those target analyte concentrations are quantified below the limit of quantitation (LOQ). The DL includes any adjustments
from dilutions, concentrations or moisture content, where applicable. (DoD report formats only.)
Estimated Detection Limit: This value represents the level to which target analyte concentrations are reported as estimated
values, when those target analyte concentrations are quantified below the reporting limit (RL). The EDL includes any
adjustments from dilutions, concentrations or moisture content, where applicable. The use of EDLs is specific to the analysis
of PAHs using Solid-Phase Microextraction (SPME).
Estimated Maximum Possible Concentration: The concentration that results from the signal present at the retention time of an
analyte when the ions meet all of the identification criteria except the ion abundance ratio criteria. An EMPC is a worst-case
estimate of the concentration.
Environmental Protection Agency.
Laboratory Control Sample: A sample matrix, free from the analytes of interest, spiked with verified known amounts of
analytes or a material containing known and verified amounts of analytes.
Laboratory Control Sample Duplicate: Refer to LCS.
Laboratory Fortified Blank: A sample matrix, free from the analytes of interest, spiked with verified known amounts of
analytes or a material containing known and verified amounts of analytes.
Limit of Detection: This value represents the level to which a target analyte can reliably be detected for a specific analyte in a
specific matrix by a specific method. The LOD includes any adjustments from dilutions, concentrations or moisture content,
where applicable. (DoD report formats only.)
Limit of Quantitation: The value at which an instrument can accurately measure an analyte at a specific concentration. The
LOQ includes any adjustments from dilutions, concentrations or moisture content, where applicable. (DoD report formats
only.)
Limit of Quantitation: The value at which an instrument can accurately measure an analyte at a specific concentration. The
LOQ includes any adjustments from dilutions, concentrations or moisture content, where applicable. (DoD report formats
only.)
Method Detection Limit: This value represents the level to which target analyte concentrations are reported as estimated
values, when those target analyte concentrations are quantified below the reporting limit (RL). The MDL includes any
adjustments from dilutions, concentrations or moisture content, where applicable.
Matrix Spike Sample: A sample prepared by adding a known mass of target analyte to a specified amount of matrix sample for
which an independent estimate of target analyte concentration is available. For Method 332.0, the spike recovery is calculated
using the native concentration, including estimated values.
Matrix Spike Sample Duplicate: Refer to MS.
Not Applicable.
Not Calculated: Term is utilized when one or more of the results utilized in the calculation are non-detect at the parameter's
reporting unit.
N-Nitrosodiphenylamine/Diphenylamine.
Not Ignitable.
Non-Plastic: Term is utilized for the analysis of Atterberg Limits in soil.
No Results: Term is utilized when 'No Target Compounds Requested' is reported for the analysis of Volatile or Semivolatile
Organic TIC only requests.
Reporting Limit: The value at which an instrument can accurately measure an analyte at a specific concentration. The RL
includes any adjustments from dilutions, concentrations or moisture content, where applicable.
Relative Percent Difference: The results from matrix and/or matrix spike duplicates are primarily designed to assess the
precision of analytical results in a given matrix and are expressed as relative percent difference (RPD). Values which are less
than five times the reporting limit for any individual parameter are evaluated by utilizing the absolute difference between the
values; although the RPD value will be provided in the report.
Standard Reference Material: A reference sample of a known or certified value that is of the same or similar matrix as the
associated field samples.
Semi-dynamic Tank Leaching Procedure per EPA Method 1315.
Toxic Equivalency Factors: The values assigned to each dioxin and furan to evaluate their toxicity relative to 2,3,7,8-TCDD.
Toxic Equivalent: The measure of a sample's toxicity derived by multiplying each dioxin and furan by its corresponding TEF
and then summing the resulting values.
Tentatively Identified Compound: A compound that has been identified to be present and is not part of the target compound
list (TCL) for the method and/or program. All TICs are qualitatively identified and reported as estimated concentrations.
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
Serial_No:06122314:43
Page 27 of 32
Report Format:DU Report with 'J' Qualifiers
Project Name:
Project Number:
Lab Number:
Report Date:
L2329703RANDOLPH LF
223052434 06/12/23
Terms
Analytical Method: Both the document from which the method originates and the analytical reference method. (Example: EPA 8260B is
shown as 1,8260B.) The codes for the reference method documents are provided in the References section of the Addendum.
Chlordane: The target compound Chlordane (CAS No. 57-74-9) is reported for GC ECD analyses. Per EPA,this compound "refers to a
mixture of chlordane isomers, other chlorinated hydrocarbons and numerous other components." (Reference: USEPA Toxicological Review
of Chlordane, In Support of Summary Information on the Integrated Risk Information System (IRIS), December 1997.)
Difference: With respect to Total Oxidizable Precursor (TOP) Assay analysis, the difference is defined as the Post-Treatment value minus the
Pre-Treatment value.
Final pH: As it pertains to Sample Receipt & Container Information section of the report, Final pH reflects pH of container determined after
adjustment at the laboratory, if applicable. If no adjustment required, value reflects Initial pH.
Frozen Date/Time: With respect to Volatile Organics in soil, Frozen Date/Time reflects the date/time at which associated Reagent Water-
preserved vials were initially frozen. Note: If frozen date/time is beyond 48 hours from sample collection, value will be reflected in 'bold'.
Gasoline Range Organics (GRO): Gasoline Range Organics (GRO) results include all chromatographic peaks eluting from Methyl tert butyl
ether through Naphthalene, with the exception of GRO analysis in support of State of Ohio programs, which includes all chromatographic
peaks eluting from Hexane through Dodecane.
Initial pH: As it pertains to Sample Receipt & Container Information section of the report, Initial pH reflects pH of container determined upon
receipt, if applicable.
PAH Total: With respect to Alkylated PAH analyses, the 'PAHs, Total' result is defined as the summation of results for all or a subset of the
following compounds: Naphthalene, C1-C4 Naphthalenes, 2-Methylnaphthalene, 1-Methylnaphthalene, Biphenyl, Acenaphthylene,
Acenaphthene, Fluorene, C1-C3 Fluorenes, Phenanthrene, C1-C4 Phenanthrenes/Anthracenes, Anthracene, Fluoranthene, Pyrene, C1-C4
Fluoranthenes/Pyrenes, Benz(a)anthracene, Chrysene, C1-C4 Chrysenes, Benzo(b)fluoranthene, Benzo(j)+(k)fluoranthene, Benzo(e)pyrene,
Benzo(a)pyrene, Perylene, Indeno(1,2,3-cd)pyrene, Dibenz(ah)+(ac)anthracene, Benzo(g,h,i)perylene. If a 'Total' result is requested, the
results of its individual components will also be reported.
PFAS Total: With respect to PFAS analyses, the 'PFAS, Total (5)' result is defined as the summation of results for: PFHpA, PFHxS, PFOA,
PFNA and PFOS. In addition, the 'PFAS, Total (6)' result is defined as the summation of results for: PFHpA, PFHxS, PFOA, PFNA, PFDA
and PFOS. For MassDEP DW compliance analysis only, the 'PFAS, Total (6)' result is defined as the summation of results at or above the
RL. Note: If a 'Total' result is requested, the results of its individual components will also be reported.
Total: With respect to Organic analyses, a 'Total' result is defined as the summation of results for individual isomers or Aroclors. If a 'Total'
result is requested, the results of its individual components will also be reported. This is applicable to 'Total' results for methods 8260, 8081
and 8082.
Data Qualifiers
A
B
C
D
E
F
G
H
I
J
-
-
-
-
-
-
-
-
-
-
Spectra identified as "Aldol Condensates" are byproducts of the extraction/concentration procedures when acetone is introduced in
the process.
The analyte was detected above the reporting limit in the associated method blank. Flag only applies to associated field samples that
have detectable concentrations of the analyte at less than ten times (10x) the concentration found in the blank. For MCP-related
projects, flag only applies to associated field samples that have detectable concentrations of the analyte at less than ten times (10x)
the concentration found in the blank. For DOD-related projects, flag only applies to associated field samples that have detectable
concentrations of the analyte at less than ten times (10x) the concentration found in the blank AND the analyte was detected above
one-half the reporting limit (or above the reporting limit for common lab contaminants) in the associated method blank. For NJ-
Air-related projects, flag only applies to associated field samples that have detectable concentrations of the analyte above the
reporting limit. For NJ-related projects (excluding Air), flag only applies to associated field samples that have detectable
concentrations of the analyte, which was detected above the reporting limit in the associated method blank or above five times the
reporting limit for common lab contaminants (Phthalates, Acetone, Methylene Chloride, 2-Butanone).
Co-elution: The target analyte co-elutes with a known lab standard (i.e. surrogate, internal standards, etc.) for co-extracted
analyses.
Concentration of analyte was quantified from diluted analysis. Flag only applies to field samples that have detectable concentrations
of the analyte.
Concentration of analyte exceeds the range of the calibration curve and/or linear range of the instrument.
The ratio of quantifier ion response to qualifier ion response falls outside of the laboratory criteria. Results are considered to be an
estimated maximum concentration.
The concentration may be biased high due to matrix interferences (i.e, co-elution) with non-target compound(s). The result should
be considered estimated.
The analysis of pH was performed beyond the regulatory-required holding time of 15 minutes from the time of sample collection.
The lower value for the two columns has been reported due to obvious interference.
Estimated value. The Target analyte concentration is below the quantitation limit (RL), but above the Method Detection Limit
(MDL) or Estimated Detection Limit (EDL) for SPME-related analyses. This represents an estimated concentration for Tentatively
1 The reference for this analyte should be considered modified since this analyte is absent from the target analyte list of the
original method.
Footnotes
Serial_No:06122314:43
Page 28 of 32
Report Format:DU Report with 'J' Qualifiers
Project Name:
Project Number:
Lab Number:
Report Date:
L2329703RANDOLPH LF
223052434 06/12/23
Data Qualifiers
M
ND
NJ
P
Q
R
RE
S
V
Z
-
-
-
-
-
-
-
-
-
-
Identified Compounds (TICs).
Reporting Limit (RL) exceeds the MCP CAM Reporting Limit for this analyte.
Not detected at the method detection limit (MDL) for the sample, or estimated detection limit (EDL) for SPME-related analyses.
Presumptive evidence of compound. This represents an estimated concentration for Tentatively Identified Compounds (TICs), where
the identification is based on a mass spectral library search.
The RPD between the results for the two columns exceeds the method-specified criteria.
The quality control sample exceeds the associated acceptance criteria. For DOD-related projects, LCS and/or Continuing Calibration
Standard exceedences are also qualified on all associated sample results. Note: This flag is not applicable for matrix spike recoveries
when the sample concentration is greater than 4x the spike added or for batch duplicate RPD when the sample concentrations are less
than 5x the RL. (Metals only.)
Analytical results are from sample re-analysis.
Analytical results are from sample re-extraction.
Analytical results are from modified screening analysis.
The surrogate associated with this target analyte has a recovery outside the QC acceptance limits. (Applicable to MassDEP DW
Compliance samples only.)
The batch matrix spike and/or duplicate associated with this target analyte has a recovery/RPD outside the QC acceptance limits.
(Applicable to MassDEP DW Compliance samples only.)
Serial_No:06122314:43
Page 29 of 32
Alpha Analytical performs services with reasonable care and diligence normal to the analytical testing
laboratory industry. In the event of an error, the sole and exclusive responsibility of Alpha Analytical
shall be to re-perform the work at it's own expense. In no event shall Alpha Analytical be held liable
for any incidental, consequential or special damages, including but not limited to, damages in any way
connected with the use of, interpretation of, information or analysis provided by Alpha Analytical.
We strongly urge our clients to comply with EPA protocol regarding sample volume, preservation, cooling,
containers, sampling procedures, holding time and splitting of samples in the field.
LIMITATION OF LIABILITIES
117 Technical Guidance for the Natural Attenuation Indicators: Methane, Ethane, and
Ethene, EPA-NE, Revision 1, February 21, 2002 and Sample Preparation &
Calculations for Dissolved Gas Analysis in Water Samples using a GC Headspace
Equilibration Technique, EPA RSKSOP-175, Revision 2, May 2004.
Project Name:
Project Number:
Lab Number:
Report Date:
L2329703RANDOLPH LF
223052434
REFERENCES
06/12/23
Serial_No:06122314:43
Page 30 of 32
Alpha Analytical, Inc.ID No.:17873
Company-wide Revision 19
Quality Assurance Published Date: 4/2/2021 1:14:23 PM
Certificate/Approval Program Summary Page 1 of 1
Document Type: Form Pre-Qualtrax Document ID: 08-113
Certification Information
The following analytes are not included in our Primary NELAP Scope of Accreditation:
Westborough Facility
EPA 624/624.1: m/p-xylene, o-xylene, Naphthalene
EPA 625/625.1: alpha-Terpineol
EPA 8260C/8260D: NPW: 1,2,4,5-Tetramethylbenzene; 4-Ethyltoluene, Azobenzene; SCM: Iodomethane (methyl iodide), 1,2,4,5-Tetramethylbenzene;
4-Ethyltoluene.
EPA 8270D/8270E: NPW: Dimethylnaphthalene,1,4-Diphenylhydrazine, alpha-Terpineol; SCM: Dimethylnaphthalene,1,4-Diphenylhydrazine.
SM4500: NPW: Amenable Cyanide; SCM: Total Phosphorus, TKN, NO2, NO3.
Mansfield Facility
SM 2540D: TSS
EPA 8082A: NPW: PCB: 1, 5, 31, 87,101, 110, 141, 151, 153, 180, 183, 187.
EPA TO-15: Halothane, 2,4,4-Trimethyl-2-pentene, 2,4,4-Trimethyl-1-pentene, Thiophene, 2-Methylthiophene,
3-Methylthiophene, 2-Ethylthiophene, 1,2,3-Trimethylbenzene, Indan, Indene, 1,2,4,5-Tetramethylbenzene, Benzothiophene, 1-Methylnaphthalene.
Biological Tissue Matrix: EPA 3050B
The following analytes are included in our Massachusetts DEP Scope of Accreditation
Westborough Facility:
Drinking Water
EPA 300.0: Chloride, Nitrate-N, Fluoride, Sulfate; EPA 353.2: Nitrate-N, Nitrite-N; SM4500NO3-F: Nitrate-N, Nitrite-N; SM4500F-C, SM4500CN-CE,
EPA 180.1, SM2130B, SM4500Cl-D, SM2320B, SM2540C, SM4500H-B, SM4500NO2-B
EPA 332: Perchlorate; EPA 524.2: THMs and VOCs; EPA 504.1: EDB, DBCP.
Microbiology: SM9215B; SM9223-P/A, SM9223B-Colilert-QT,SM9222D.
Non-Potable Water
SM4500H,B, EPA 120.1, SM2510B, SM2540C, SM2320B, SM4500CL-E, SM4500F-BC, SM4500NH3-BH: Ammonia-N and Kjeldahl-N, EPA 350.1:
Ammonia-N, LACHAT 10-107-06-1-B: Ammonia-N, EPA 351.1, SM4500NO3-F, EPA 353.2: Nitrate-N, SM4500P-E, SM4500P-B, E, SM4500SO4-E,
SM5220D, EPA 410.4, SM5210B, SM5310C, SM4500CL-D, EPA 1664, EPA 420.1, SM4500-CN-CE, SM2540D, EPA 300: Chloride, Sulfate, Nitrate.
EPA 624.1: Volatile Halocarbons & Aromatics,
EPA 608.3: Chlordane, Toxaphene, Aldrin, alpha-BHC, beta-BHC, gamma-BHC, delta-BHC, Dieldrin, DDD, DDE, DDT, Endosulfan I, Endosulfan II,
Endosulfan sulfate, Endrin, Endrin Aldehyde, Heptachlor, Heptachlor Epoxide, PCBs
EPA 625.1: SVOC (Acid/Base/Neutral Extractables), EPA 600/4-81-045: PCB-Oil.
Microbiology: SM9223B-Colilert-QT; Enterolert-QT, SM9221E, EPA 1600, EPA 1603, SM9222D.
Mansfield Facility:
Drinking Water
EPA 200.7: Al, Ba, Cd, Cr, Cu, Fe, Mn, Ni, Na, Ag, Ca, Zn. EPA 200.8: Al, Sb, As, Ba, Be, Cd, Cr, Cu, Pb, Mn, Ni, Se, Ag, TL, Zn. EPA 245.1 Hg.
EPA 522, EPA 537.1.
Non-Potable Water
EPA 200.7: Al, Sb, As, Be, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Ag, Na, Sr, TL, Ti, V, Zn.
EPA 200.8: Al, Sb, As, Be, Cd, Cr, Cu, Fe, Pb, Mn, Ni, K, Se, Ag, Na, TL, Zn.
EPA 245.1 Hg.
SM2340B
For a complete listing of analytes and methods, please contact your Alpha Project Manager.
Serial_No:06122314:43
Page 31 of 32
Serial_No:06122314:43
Page 32 of 32

Cover
ANALYTICAL RESULTS

PERFORMED BY

Pace Analytical Gulf Coast
7979 Innovation Park Dr.
Baton Rouge, LA 70820
[phone]

Report Date 06/13/2023

Report # 223052466
9999999999

Project Randolph Co 31404568.018

Samples Collected 5/22/23 - 5/23/23

Deliver To Additional Recipients
Darren Cox Matthew Scheidt, WSP
WSP / Golder
5B Oak Branch Dr
Greensboro, NC 27407

LELAP Certificate Number: 01955
A2LA Accredited (DoD ELAP-QSM 5.4) Certificate Number: 6429.01

Page 1 of 1906/13/2023 10:01Pace Gulf Coast Report#: 223052466

Report#: 223052466
Project ID: Randolph Co 31404568.018 Report Date: 06/13/2023

Laboratory Endorsement

Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized
agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this
retention period the samples will be disposed in accordance with Pace Gulf Coast's Standard Operating Procedures.

Common Abbreviations that may be Utilized in this Report

ND Indicates the result was Not Detected at the specified reporting limit
NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030
DO Indicates the result was Diluted Out
MI Indicates the result was subject to Matrix Interference
TNTC Indicates the result was Too Numerous To Count
SUBC Indicates the analysis was Sub-Contracted FLD Indicates the analysis was performed in the Field
DL Detection Limit
LOD Limit of Detection
LOQ Limit of Quantitation
RE Re-analysis CF HPLC or GC Confirmation
00:01 Reported as a time equivalent to 12:00 AM

Reporting Flags that may be Utilized in this Report

J or I Indicates the result is between the MDL and LOQ
J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria
U Indicates the compound was analyzed for but not detected
B or V Indicates the analyte was detected in the associated Method Blank
Q Indicates a non-compliant QC Result (See Q Flag Application Report)
* Indicates a non-compliant or not applicable QC recovery or RPD – see narrative
E Organics - The result is estimated because it exceeded the instrument calibration range
E Metals - % diference for the serial dilution is > 10%
L Reporting Limits adjusted to meet risk-based limit.
P RPD between primary and confirmation result is greater than 40 DL Diluted analysis – when appended to Client Sample ID

Sample receipt at Pace Gulf Coast is documented through the attached chain of custody. In accordance with NELAC, this report shall be
reproduced only in full and with the written permission of Pace Gulf Coast. The results contained within this report relate only to the samples
reported. The documented results are presented within this report.

This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited.

I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and
Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee,
as verified by the following signature.

Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if
applicable.

Authorized Signature Pace Gulf Coast Report 223052466

Page 2 of 1906/13/2023 10:01Pace Gulf Coast Report#: 223052466

Report#: 223052466
Project ID: Randolph Co 31404568.018 Report Date: 06/13/2023

Certifications

Certification Certification Number

Page 3 of 1906/13/2023 10:01Pace Gulf Coast Report#: 223052466

Report#: 223052466
Project ID: Randolph Co 31404568.018 Report Date: 06/13/2023

Case Narrative
Client: Golder Associates - NC Report: 223052466
Pace Analytical Gulf Coast received and analyzed the sample(s) listed
on the Report Sample Summary page of this report. Receipt of the sample(s) is documented
by the attached chain of custody. This applies only to the sample(s) listed in this report.
No sample integrity or quality control exceptions were identified unless noted below.
VOLATILES MASS SPECTROMETRY
MSV: Batch 52880 in the Opening CCV, several non target analytes failed but all target analytes passed.
MISCELLANEOUS
See subcontract laboratory report case narrative.

Page 4 of 1906/13/2023 10:01Pace Gulf Coast Report#: 223052466

Report#: 223052466
Project ID: Randolph Co 31404568.018 Report Date: 06/13/2023

Sample Summary
Lab ID Client ID Matrix Collect Date Receive Date
22305246601 MW-11S Bubble Strip 5/22/23 14:45 5/24/23 09:56
22305246602 MW-8 Bubble Strip 5/22/23 10:50 5/24/23 09:56
22305246603 MW-3 Bubble Strip 5/22/23 13:20 5/24/23 09:56
22305246604 MW-7 Bubble Strip 5/22/23 09:44 5/24/23 09:56
22305246605 MW-2 Bubble Strip 5/22/23 12:30 5/24/23 09:56
22305246606 MW-10S Bubble Strip 5/22/23 14:45 5/24/23 09:56
22305246607 MW-10D Bubble Strip 5/23/23 00:01 5/24/23 09:56
22305246608 MW-10D Water 5/23/23 00:01 5/24/23 09:56
Page 5 of 1906/13/2023 10:01Pace Gulf Coast Report#: 223052466

Report#: 223052466
Project ID: Randolph Co 31404568.018 Report Date: 06/13/2023

Detect Summary
Results and Detection Limits are adjusted for dilution and moisture when applicable

AM23G
Lab ID Client ID Parameter Units Result Dil. %Moist
22305246608 MW-10D Acetic Acid mg/L 8.4 10 NA
22305246608 MW-10D Formic Acid mg/L 49 10 NA
22305246608 MW-10D Lactic Acid mg/L 0.73J 10 NA
22305246608 MW-10D Propionic Acid mg/L 1.7J 10 NA

EPA 9034
Lab ID Client ID Parameter Units Result Dil. %Moist
22305246608 MW-10D Sulfide mg/L 4.0 1 NA

EPA 9056A
Lab ID Client ID Parameter Units Result Dil. %Moist
22305246608 MW-10D Chloride mg/L 175 20 NA
22305246608 MW-10D Sulfate mg/L 2.34 2 NA

EPA 9060A
Lab ID Client ID Parameter Units Result Dil. %Moist
22305246608 MW-10D Total Organic Carbon mg/L 17.4 1 NA

HACH 8000
Lab ID Client ID Parameter Units Result Dil. %Moist
22305246608 MW-10D COD mg/L 6.3 1 NA

SM 2320 B-2011
Lab ID Client ID Parameter Units Result Dil. %Moist
22305246608 MW-10D Total Alkalinity mg/L CaCO3 465 1 NA

SM 3500-Fe B-2011
Lab ID Client ID Parameter Units Result Dil. %Moist
22305246608 MW-10D Ferrous Iron mg/L 0.461 1 NA

EPA 8260B
Lab ID Client ID Parameter Units Result Dil. %Moist
22305246608 MW-10D 1,1-Dichloroethane ug/L 2.21J 1 NA
22305246608 MW-10D Vinyl chloride ug/L 0.273J 1 NA

AM20GAX
Lab ID Client ID Parameter Units Result Dil. %Moist
22305246602 MW-8 Hydrogen nM 9.0 1 NA
22305246603 MW-3 Hydrogen nM 7.1 1 NA
Page 6 of 1906/13/2023 10:01Pace Gulf Coast Report#: 223052466

Report#: 223052466
Project ID: Randolph Co 31404568.018 Report Date: 06/13/2023

Detect Summary (Continued)
Results and Detection Limits are adjusted for dilution and moisture when applicable

AM20GAX
Lab ID Client ID Parameter Units Result Dil. %Moist
22305246604 MW-7 Hydrogen nM 8.9 1 NA
22305246605 MW-2 Hydrogen nM 5.7 1 NA
22305246606 MW-10S Hydrogen nM 5.7 1 NA
22305246607 MW-10D Hydrogen nM 6.8 1 NA
Page 7 of 1906/13/2023 10:01Pace Gulf Coast Report#: 223052466

Report#: 223052466
Project ID: Randolph Co 31404568.018 Report Date: 06/13/2023

Sample Results Sample Results
MW-11S
MW-11S Collect Date 05/22/2023 14:45 Lab ID 22305246601
Receive Date 05/24/2023 09:56 Matrix Bubble Strip

AM20GAX
AM20GAX

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 06/02/23 14:50 766934 BDP NA
CAS# Parameter Result DL LOQ Units
1333-74-0 Hydrogen 0.49U 0.49 1.9 nM
MW-8
MW-8 Collect Date 05/22/2023 10:50 Lab ID 22305246602
Receive Date 05/24/2023 09:56 Matrix Bubble Strip
AM20GAX
AM20GAX
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 06/02/23 15:03 766934 BDP NA

CAS# Parameter Result DL LOQ Units
1333-74-0 Hydrogen 9.0 0.49 1.9 nM
MW-3
MW-3 Collect Date 05/22/2023 13:20 Lab ID 22305246603
Receive Date 05/24/2023 09:56 Matrix Bubble Strip
AM20GAX
AM20GAX
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 06/02/23 15:20 766934 BDP NA
CAS# Parameter Result DL LOQ Units
1333-74-0 Hydrogen 7.1 0.49 1.9 nM
MW-7
MW-7 Collect Date 05/22/2023 09:44 Lab ID 22305246604
Receive Date 05/24/2023 09:56 Matrix Bubble Strip

AM20GAX
AM20GAX

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 06/02/23 15:33 766934 BDP NA
CAS# Parameter Result DL LOQ Units
1333-74-0 Hydrogen 8.9 0.49 1.9 nM
Page 8 of 1906/13/2023 10:01Pace Gulf Coast Report#: 223052466

Report#: 223052466
Project ID: Randolph Co 31404568.018 Report Date: 06/13/2023

Sample Results
MW-2
MW-2 Collect Date 05/22/2023 12:30 Lab ID 22305246605
Receive Date 05/24/2023 09:56 Matrix Bubble Strip

AM20GAX
AM20GAX

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 06/02/23 15:47 766934 BDP NA
CAS# Parameter Result DL LOQ Units
1333-74-0 Hydrogen 5.7 0.49 1.9 nM
MW-10S
MW-10S Collect Date 05/22/2023 14:45 Lab ID 22305246606
Receive Date 05/24/2023 09:56 Matrix Bubble Strip
AM20GAX
AM20GAX
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 06/02/23 16:12 766934 BDP NA

CAS# Parameter Result DL LOQ Units
1333-74-0 Hydrogen 5.7 0.49 1.9 nM
MW-10D
MW-10D Collect Date 05/23/2023 00:01 Lab ID 22305246607
Receive Date 05/24/2023 09:56 Matrix Bubble Strip
AM20GAX
AM20GAX
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 06/02/23 16:24 766934 BDP NA
CAS# Parameter Result DL LOQ Units
1333-74-0 Hydrogen 6.8 0.49 1.9 nM
MW-10D
MW-10D Collect Date 05/23/2023 00:01 Lab ID 22305246608
Receive Date 05/24/2023 09:56 Matrix Water

EPA 8260B
EPA 8260B

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/26/23 14:24 766594 KN1 NA
CAS# Parameter Result DL LOQ Units
75-34-3 1,1-Dichloroethane 2.21J 0.200 5.00 ug/L
127-18-4 Tetrachloroethene 0.200U 0.200 5.00 ug/L
79-01-6 Trichloroethene 0.200U 0.200 5.00 ug/L
Page 9 of 1906/13/2023 10:01Pace Gulf Coast Report#: 223052466

Report#: 223052466
Project ID: Randolph Co 31404568.018 Report Date: 06/13/2023

Sample Results

MW-10D Collect Date 05/23/2023 00:01 Lab ID 22305246608
Receive Date 05/24/2023 09:56 Matrix Water

EPA 8260B (Continued)
EPA 8260B (Continued)

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/26/23 14:24 766594 KN1 NA
CAS# Parameter Result DL LOQ Units
75-01-4 Vinyl chloride 0.273J 0.200 2.00 ug/L
CAS# Surrogate Conc Spiked Conc Rec Units %Recovery %Rec Limits
460-00-4 4-Bromofluorobenzene 50 51.1 ug/L 102 78 - 130
1868-53-7 Dibromofluoromethane 50 58.9 ug/L 118 77 - 127
2037-26-5 Toluene d8 50 52 ug/L 104 76 - 134
17060-07-0 1,2-Dichloroethane-d4 50 57.9 ug/L 116 71 - 127
AM23G
AM23G *Results and limits are adjusted for dilution.
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 10 05/31/23 02:15 766672 LHM NA

CAS# Parameter Result DL LOQ Units
64-19-7 Acetic Acid 8.4 1.2 5.0 mg/L
107-92-6 Butyric Acid 0.58U 0.58 5.0 mg/L
64-18-6 Formic Acid 49 0.55 5.0 mg/L
142-62-1 Hexanoic Acid 0.58U 0.58 5.0 mg/L
646-07-1 i-Hexanoic Acid 0.56U 0.56 5.0 mg/L
503-74-2 i-Pentanoic Acid 0.61U 0.61 5.0 mg/L
50-21-5 Lactic Acid 0.73J 0.53 5.0 mg/L
109-52-4 Pentanoic Acid 0.56U 0.56 5.0 mg/L
79-09-4 Propionic Acid 1.7J 0.53 5.0 mg/L
127-17-3 Pyruvic Acid 0.60U 0.60 5.0 mg/L
EPA 9034
EPA 9034
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/26/23 13:00 766574 RYC NA

CAS# Parameter Result DL LOQ Units
18496-25-8 Sulfide 4.0 1.1 2.0 mg/L
EPA 9056A
EPA 9056A *Results and limits are adjusted for dilution.

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 2 05/24/23 14:12 766504 CS NA
CAS# Parameter Result DL LOQ Units
14797-55-8 Nitrate 0.200U 0.200 0.400 mg/L-N
14808-79-8 Sulfate 2.34 0.200 0.400 mg/L
Page 10 of 1906/13/2023 10:01Pace Gulf Coast Report#: 223052466

Report#: 223052466
Project ID: Randolph Co 31404568.018 Report Date: 06/13/2023

Sample Results

MW-10D Collect Date 05/23/2023 00:01 Lab ID 22305246608
Receive Date 05/24/2023 09:56 Matrix Water

-
EPA 9056A *Results and limits are adjusted for dilution.

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 20 05/25/23 12:32 766543 CS NA
CAS# Parameter Result DL LOQ Units
16887-00-6 Chloride 175 1.00 4.00 mg/L
EPA 9060A
EPA 9060A *Results are reported on a dry weight basis.
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/31/23 15:16 766751 CCL NA

CAS# Parameter Result DL LOQ Units
C-012 Total Organic Carbon 17.4 0.300 2.00 mg/L
HACH 8000
HACH 8000
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/25/23 13:36 766485 RYC NA

CAS# Parameter Result DL LOQ Units
C-004 COD 6.3 1.7 5.0 mg/L
SM 2320 B-2011
SM 2320 B-2011
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 06/02/23 14:01 766937 MMP NA

CAS# Parameter Result DL LOQ Units
000000-00-5 Total Alkalinity 465 0.26 1.0 mg/L CaCO3
SM 3500-Fe B-2011
SM 3500-Fe B-2011
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 05/24/23 15:01 766461 RYC NA

CAS# Parameter Result DL LOQ Units
WET-045 Ferrous Iron 0.461 0.014 0.050 mg/L
Page 11 of 1906/13/2023 10:01Pace Gulf Coast Report#: 223052466

Report#: 223052466
Project ID: Randolph Co 31404568.018 Report Date: 06/13/2023

Sample Results

MW-10D Collect Date 05/23/2023 00:01 Lab ID 22305246608
Receive Date 05/24/2023 09:56 Matrix Water

SM 5210 B-2016
SM 5210 B-2016

Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
05/25/23 12:52 766466 BOD PREP 1 05/25/23 12:52 766700 MLG NA
CAS# Parameter Result DL LOQ Units
C-002 BOD 3U 3 3 mg/L
Subcontract Work
Subcontract Work
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA Subcontract Work 1 06/13/23 09:14 NA CW NA

CAS# Parameter Result DL LOQ Units
SHIP-001 Ship Result * mg/L
-
Subcontract Work
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA Subcontract Work 1 06/13/23 09:14 NA CW NA

CAS# Parameter Result DL LOQ Units
SHIP-002 Ship Result * mg/L
Page 12 of 1906/13/2023 10:01Pace Gulf Coast Report#: 223052466

Report#: 223052466
Project ID: Randolph Co 31404568.018 Report Date: 06/13/2023

QC Summary GC/MS Volatiles QC Summary
GC/MS Volatiles
Analytical Batch
766594

Client ID
Lab ID
Sample Type Prep Date
Analysis Date
Matrix

MB766594
2487626
MB NA
05/26/23 12:32
Water

LCS766594
2487627
LCS NA
05/26/23 11:11
Water

EPA 8260B Units
Result
ug/L
DL
Spike
Added Result %R Control
Limits%R
1,1-Dichloroethane 75-34-3 0.200U 0.200 50.0 48.1 96 74 - 127
Tetrachloroethene 127-18-4 0.200U 0.200 50.0 47.3 95 68 - 128 Trichloroethene 79-01-6 0.200U 0.200 50.0 47.8 96 76 - 129
Vinyl chloride 75-01-4 0.200U 0.200 50.0 44.5 89 68 - 132
Surrogate CAS# Rec %R Added Rec %R Limits
1,2-Dichloroethane-d4 17060-07-0 55 110 50 55 110 71 - 127
4-Bromofluorobenzene 460-00-4 52.6 105 50 55 110 78 - 130
Dibromofluoromethane 1868-53-7 57.9 116 50 55.5 111 77 - 127
Toluene d8 2037-26-5 54.4 109 50 51.6 103 76 - 134

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Report#: 223052466
Project ID: Randolph Co 31404568.018 Report Date: 06/13/2023

General Chemistry QC Summary
General Chemistry Analytical Batch
766937

Client ID
Lab ID
Sample Type
Prep Date
Analysis Date
Matrix
MB766937
2489326
MB
NA
06/02/23 14:01
Water
LCS766937
2489327
LCS
NA
06/02/23 14:01
Water
LCSD766937
2489328
LCSD
NA
06/02/23 14:01
Water
SM 2320 B-2011 Units
Result
mg/L CaCO3
DL
Spike
Added Result %R Control
Limits%R
Spike
Added Result %R RPD RPD
Limit
Total Alkalinity 000000-00-5 0.26U 0.26 200 202 101 90 - 110 200 201 101 0 11

Analytical Batch
766700
Prep Batch
766466 Prep Method
BOD PREP

Client ID
Lab ID
Sample Type
Prep Date Analysis Date
Matrix

MB766466
2487053
MB
05/24/23 12:13 05/24/23 12:13
Water

LCS766466
2487055
LCS
05/24/23 12:13 05/24/23 12:13
Water

SM 5210 B-2016 Units
Result
mg/L
DL
Spike
Added Result %R Control
Limits%R
BOD C-002 3U 3 198 171 86 84.5 - 115.5

Analytical Batch
766574

Client ID
Lab ID
Sample Type
Prep Date
Analysis Date
Matrix

MB766574
2487581
MB
NA
05/26/23 13:00
Water

LCS766574
2487582
LCS
NA
05/26/23 13:00
Water

LCSD766574
2487583
LCSD
NA
05/26/23 13:00
Water

EPA 9034 Units
Result
mg/L
DL
Spike
Added Result %R Control
Limits%R
Spike
Added Result %R RPD RPD
Limit
Sulfide 18496-25-8 1.1U 1.1 25.0 25.4 102 50 - 120 25.0 25.6 103 1 25

Analytical Batch
766485

Client ID
Lab ID
Sample Type
Prep Date
Analysis Date
Matrix

MB766485
2487104
MB NA
05/25/23 13:35
Water

LCS766485
2487105
LCS
NA
05/25/23 13:35
Water

LCSD766485
2487106
LCSD
NA
05/25/23 13:35
Water

HACH 8000 Units
Result
mg/L
DL
Spike
Added Result %R Control
Limits%R
Spike
Added Result %R RPD RPD
Limit
COD C-004 1.7U 1.7 75.0 74.0 99 90 - 110 75.0 76.2 102 3 20

Analytical Batch
766461
Client ID
Lab ID Sample Type
Prep Date
Analysis Date
Matrix

MB766461
2486996 MB
NA
05/24/23 15:00
Water

LCS766461
2486997 LCS
NA
05/24/23 15:00
Water

LCSD766461
2486998 LCSD
NA
05/24/23 15:01
Water

SM 3500-Fe B-2011 Units
Result
mg/L
DL
Spike
Added Result %R Control
Limits%R
Spike
Added Result %R RPD RPD
Limit
Ferrous Iron WET-045 0.014U 0.014 1.00 0.999 100 89.5 - 110.5 1.00 1.05 105 5 20

Page 14 of 1906/13/2023 10:01Pace Gulf Coast Report#: 223052466

Report#: 223052466
Project ID: Randolph Co 31404568.018 Report Date: 06/13/2023

General Chemistry QC Summary
Analytical Batch
766672
Client ID
Lab ID
Sample Type
Prep Date
Analysis Date
Matrix
MB766672
2488129
MB
NA
05/30/23 14:58
Water
LCS766672
2488130
LCS
NA
05/30/23 16:49
Water
LCSD766672
2488131
LCSD
NA
05/30/23 17:40
Water
AM23G Units Result mg/L DL Spike Added Result %R Control Limits%R Spike Added Result %R RPD RPD Limit
Acetic Acid 64-19-7 0.12U 0.12 2.0 2.2 108 70 - 130 2.0 2.2 108 0 20
Butyric Acid 107-92-6 0.058U 0.058 2.0 2.1 105 70 - 130 2.0 2.1 107 2 20
Formic Acid 64-18-6 0.055U 0.055 2.0 2.0 98 70 - 130 2.0 2.0 100 3 20
Hexanoic Acid 142-62-1 0.058U 0.058 2.0 2.0 98 70 - 130 2.0 2.0 102 3 20
i-Hexanoic Acid 646-07-1 0.056U 0.056 2.0 2.1 105 70 - 130 2.0 2.1 107 2 20 i-Pentanoic Acid 503-74-2 0.061U 0.061 2.0 2.1 104 70 - 130 2.0 2.1 105 1 20
Lactic Acid 50-21-5 0.053U 0.053 2.0 2.2 109 70 - 130 2.0 2.2 112 2 20
Pentanoic Acid 109-52-4 0.056U 0.056 2.0 2.1 104 70 - 130 2.0 2.2 108 4 20
Propionic Acid 79-09-4 0.053U 0.053 2.0 2.1 106 70 - 130 2.0 2.1 107 1 20
Pyruvic Acid 127-17-3 0.060U 0.060 2.0 2.0 101 70 - 130 2.0 2.1 104 4 20

Analytical Batch
766504
Client ID
Lab ID
Sample Type
Prep Date
Analysis Date
Matrix
MB766504 2487184
MB
NA
05/24/23 11:02
Water
LCS766504
2487185
LCS
NA
05/24/23 11:20
Water
LCSD766504
2487186
LCSD
NA
05/24/23 11:37
Water
EPA 9056A Units Result mg/L-N DL Spike Added Result %R Control Limits%R Spike Added Result %R RPD RPD Limit
Nitrate 14797-55-8 0.100U 0.100 2.50 2.41 96 80 - 120 2.50 2.41 97 0 15
Sulfate 14808-79-8 0.100U 0.100 2.50 2.46 98 80 - 120 2.50 2.42 97 2 15

Analytical Batch
766543
Client ID
Lab ID
Sample Type
Prep Date
Analysis Date
Matrix
MB766543
2487507
MB
NA
05/25/23 10:51
Water
LCS766543
2487508
LCS
NA
05/25/23 11:08
Water
LCSD766543
2487509
LCSD
NA
05/25/23 11:25
Water
EPA 9056A Units
Result
mg/L
DL
Spike
Added Result %R Control
Limits%R
Spike
Added Result %R RPD RPD
Limit
Chloride 16887-00-6 0.050U 0.050 2.50 2.24 90 80 - 120 2.50 2.24 89 0 15

Analytical Batch
766751

Client ID
Lab ID
Sample Type
Prep Date Analysis Date
Matrix
MB766751
2488438
MB
NA 05/31/23 11:09
Water
LCS766751
2488439
LCS
NA 05/31/23 10:20
Water
LCSD766751
2488440
LCSD
NA 05/31/23 10:44
Water
EPA 9060A Units
Result
mg/L
DL
Spike
Added Result %R Control
Limits%R
Spike
Added Result %R RPD RPD
Limit
Total Organic Carbon C-012 0.300U 0.300 50.0 50.5 101 90 - 110 50.0 50.7 101 0 20

Analytical Batch
766751

Client ID
Lab ID
Sample Type
Prep Date
Analysis Date
Matrix
MW-10D
22305246608
SAMPLE
NA
05/31/2023 15:16
Water
2486942MS
2488450
MS
NA
05/31/23 17:13
Water
2486942MSD
2488451
MSD
NA
05/31/23 17:49
Water
EPA 9060A Units
Result
mg/L
DL
Spike
Added Result %R Control
Limits%R
Spike
Added Result %R RPD RPD
Limit
Total Organic Carbon C-012 17.4 0.300 50.0 64.3 94 80 - 120 50.0 171 307* 91* 20

Page 15 of 1906/13/2023 10:01Pace Gulf Coast Report#: 223052466

Report#: 223052466
Project ID: Randolph Co 31404568.018 Report Date: 06/13/2023

General Chromatography QC Summary
General Chromatography Analytical Batch
766934

Client ID
Lab ID
Sample Type
Prep Date
Analysis Date
Matrix
MB766934
2489315
MB
NA
06/02/23 14:30
Bubble Strip
LCS766934
2489316
LCS
NA
06/02/23 13:21
Bubble Strip
LCSD766934
2489317
LCSD
NA
06/02/23 14:05
Bubble Strip
AM20GAX Units
Result
nM
DL
Spike
Added Result %R Control
Limits%R
Spike
Added Result %R RPD RPD
Limit
Hydrogen 1333-74-0 0.49U 0.49 12 12 105 70 - 130 12 12 104 1 20

Page 16 of 1906/13/2023 10:01Pace Gulf Coast Report#: 223052466
Page 17 of 1906/13/2023 10:01Pace Gulf Coast Report#: 223052466
Page 18 of 1906/13/2023 10:01Pace Gulf Coast Report#: 223052466
SAMPLE RECEIVING CHECKLIST *223052466*
SAMPLE DELIVERY GROUP 223052466
Client PM RWe Transport Method
Golder - NC - Golder Associates
- NC
Profile Number Received By
300930 Perkins, Brennan
McCune, Dodie N.
Line Item(s)Receive Date(s)
1 - Hydrogen
3 - Waters
05/24/23
CHECKLIST YES NO
Samples received with proper thermal preservation?
Radioactivity is <1600 cpm? If no, record cpm value in notes section.
COC relinquished and complete (including sampleIDs, collect times, and sampler)?
All containers received in good condition and within hold time?
All sample labels and containers received match the chain of custody?
Preservative added to any containers?
If received, was headspace for VOC water containers < 6mm?
Samples collected in containers provided by Pace Gulf Coast?
COOLERS
Airbill Thermometer ID:E43 Temp oC
772227747980 0.4
DISCREPANCIES
None
LAB PRESERVATIONS
None
NOTES NO SAMPLE COLLECT TIMES LISTED FOR SAMPLES -07 & -08
Revision 1.6 Page 1 of 1
Page 19 of 1906/13/2023 10:01Pace Gulf Coast Report#: 223052466
L2329700
Pace Analytical Gulf Coast
223052466
RANDOLPH LF
Client:
Project Name:
Project Number:
06/05/23
320 Forbes Boulevard, Mansfield, MA 02048-1806
Lab Number:
Report Date:
508-822-9300 (Fax) 508-822-3288 800-624-9220 - www.alphalab.com
7979 Innovation Park Drive
Baton Rouge, LA 70820
Ruth WelshATTN:
ANALYTICAL REPORT
Certifications & Approvals: MA (M-MA030), NH NELAP (2062), CT (PH-0825), DoD (L2474), FL (E87814), IL (200081), IN (C-MA-04), KY (KY98046),
LA (85084), ME (MA00030), MD (350), MI (99110) , NJ (MA015), NY (11627), NC (685), OH (CL106), OR (MA-0262), PA (68-02089), RI (LAO00299), TX
(T104704419), VT (VT-0015), VA (460194), WA (C954), US Army Corps of Engineers, USDA (Permit #525-23-107-88708), USFWS (Permit #206964).
[phone]Phone:
The original project report/data package is held by Alpha Analytical. This report/data package is paginated and should be reproduced only in its
entirety. Alpha Analytical holds no responsibility for results and/or data that are not consistent with the original.
Serial_No:06052319:30
Page 1 of 20
L2329700-01
Alpha
Sample ID
MW-10D
Client ID
Not Specified
Sample
Location
RANDOLPH LF
223052466
Project Name:
Project Number:
Lab Number:
Report Date:
L2329700
06/05/23
05/23/23 00:01
Collection
Date/TimeMatrix Receive Date
WATER 05/27/23
Serial_No:06052319:30
Page 2 of 20
RANDOLPH LF
223052466
Project Name:
Project Number:
Lab Number:
Report Date:
L2329700
06/05/23
Case Narrative
The samples were received in accordance with the Chain of Custody and no significant deviations were encountered during the preparation
or analysis unless otherwise noted. Sample Receipt, Container Information, and the Chain of Custody are located at the back of the report.
Results contained within this report relate only to the samples submitted under this Alpha Lab Number and meet NELAP requirements for all
NELAP accredited parameters unless otherwise noted in the following narrative. The data presented in this report is organized by parameter
(i.e. VOC, SVOC, etc.). Sample specific Quality Control data (i.e. Surrogate Spike Recovery) is reported at the end of the target analyte list
for each individual sample, followed by the Laboratory Batch Quality Control at the end of each parameter. Tentatively Identified
Compounds (TICs), if requested, are reported for compounds identified to be present and are not part of the method/program Target
Compound List, even if only a subset of the TCL are being reported. If a sample was re-analyzed or re-extracted due to a required quality
control corrective action and if both sets of data are reported, the Laboratory ID of the re-analysis or re-extraction is designated with an "R"
or "RE", respectively.
When multiple Batch Quality Control elements are reported (e.g. more than one LCS), the associated samples for each element are noted in
the grey shaded header line of each data table. Any Laboratory Batch, Sample Specific % recovery or RPD value that is outside the listed
Acceptance Criteria is bolded in the report. In reference to questions H (CAM) or 4 (RCP) when "NO" is checked, the performance criteria
for CAM and RCP methods allow for some quality control failures to occur and still be within method compliance. In these instances, the
specific failure is not narrated but noted in the associated QC Outlier Summary Report, located directly after the Case Narrative. QC
information is also incorporated in the Data Usability Assessment table (Format 11) of our Data Merger tool, where it can be reviewed in
conjunction with the sample result, associated regulatory criteria and any associated data usability implications.
Soil/sediments, solids and tissues are reported on a dry weight basis unless otherwise noted. Definitions of all data qualifiers and acronyms
used in this report are provided in the Glossary located at the back of the report.
HOLD POLICY - For samples submitted on hold, Alpha's policy is to hold samples (with the exception of Air canisters) free of charge for 21
calendar days from the date the project is completed. After 21 calendar days, we will dispose of all samples submitted including those put
on hold unless you have contacted your Alpha Project Manager and made arrangements for Alpha to continue to hold the samples. Air
canisters will be disposed after 3 business days from the date the project is completed.
Please contact Project Management at 800-624-9220 with any questions.
Serial_No:06052319:30
Page 3 of 20
Case Narrative (continued)
RANDOLPH LF
223052466
Project Name:
Project Number:
Lab Number:
Report Date:
L2329700
06/05/23
Report Submission
All non-detect (ND) or estimated concentrations (J-qualified) have been quantitated to the limit noted in the
MDL column.

I, the undersigned, attest under the pains and penalties of perjury that, to the best of my knowledge and
belief and based upon my personal inquiry of those responsible for providing the information contained
in this analytical report, such information is accurate and complete. This certificate of analysis is not
complete unless this page accompanies any and all pages of this report.

Authorized Signature:
Title: Technical Director/Representative Date: 06/05/23
Serial_No:06052319:30
Page 4 of 20
ORGANICS
Serial_No:06052319:30
Page 5 of 20
VOLATILES
Serial_No:06052319:30
Page 6 of 20
FF
Methane
Ethene
Ethane
Parameter Result Dilution Factor
17.8
ND
ND
ug/l
ug/l
ug/l
1
1
1
Qualifier Units RL
Dissolved Gases by GC - Mansfield Lab
SAMPLE RESULTS
Project Name:
Project Number:
Lab Number:
Report Date:
RANDOLPH LF
223052466
L2329700
2.00
0.500
0.500
06/05/23
MW-10DClient ID:
05/23/23 00:01Date Collected:
05/27/23Date Received:
Not SpecifiedSample Location:
L2329700-01Lab ID:
Field Prep:Not Specified
Matrix:Water
Analytical Method:
Analytical Date:
Analyst:
117,-
06/02/23 12:57
SRO
MDL
2.00
0.500
0.500
A
A
A
Column
Sample Depth:
Serial_No:06052319:30
Page 7 of 20
Carbon Dioxide
Parameter Result Dilution Factor
220 mg/l 2
Qualifier Units RL
Dissolved Gases by GC - Mansfield Lab
SAMPLE RESULTS
Project Name:
Project Number:
Lab Number:
Report Date:
RANDOLPH LF
223052466
L2329700
6.00
06/05/23
MW-10DClient ID:
05/23/23 00:01Date Collected:
05/27/23Date Received:
Not SpecifiedSample Location:
L2329700-01Lab ID:
Field Prep:Not Specified
D
Matrix:Water
Analytical Method:
Analytical Date:
Analyst:
117,-
05/30/23 14:58
SRO
MDL
6.00
Sample Depth:
Serial_No:06052319:30
Page 8 of 20
Method Blank Analysis
Batch Quality Control
Project Name:
Project Number:
Lab Number:
Report Date:
RANDOLPH LF
223052466
L2329700
05/30/23 08:56
117,-Analytical Method:
Analytical Date:
06/05/23
Analyst:SRO
Carbon Dioxide
Parameter Result
ND
RL
3.00mg/l
UnitsQualifier
Dissolved Gases by GC - Mansfield Lab for sample(s): 01 Batch: WG1784795-3
MDL
3.00
Serial_No:06052319:30
Page 9 of 20
Method Blank Analysis
Batch Quality Control
Project Name:
Project Number:
Lab Number:
Report Date:
RANDOLPH LF
223052466
L2329700
06/02/23 11:15
117,-Analytical Method:
Analytical Date:
06/05/23
Analyst:SRO
Methane
Ethene
Ethane
Parameter Result
ND
ND
ND
RL
2.00
0.500
0.500
ug/l
ug/l
ug/l
UnitsQualifier
Dissolved Gases by GC - Mansfield Lab for sample(s): 01 Batch: WG1786321-3
MDL
2.00
0.500
0.500
A
A
A
Serial_No:06052319:30
Page 10 of 20
Carbon Dioxide 95 -80-120 -
Parameter
LCS
%Recovery
LCSD
%Recovery
%Recovery
Limits RPD
RPD
Limits
Dissolved Gases by GC - Mansfield Lab Associated sample(s): 01 Batch: WG1784795-2
Lab Control Sample Analysis
Batch Quality ControlProject Name:
Project Number:
Lab Number:
Report Date:
RANDOLPH LF
223052466
L2329700
06/05/23
Qual Qual Qual
Serial_No:06052319:30
Page 11 of 20
Methane
Ethene
Ethane
93
88
87
-
-
-
80-120
80-120
80-120
-
-
-
25
25
25
Parameter
LCS
%Recovery
LCSD
%Recovery
%Recovery
Limits RPD
RPD
Limits
Dissolved Gases by GC - Mansfield Lab Associated sample(s): 01 Batch: WG1786321-2
Lab Control Sample Analysis
Batch Quality ControlProject Name:
Project Number:
Lab Number:
Report Date:
RANDOLPH LF
223052466
L2329700
06/05/23
Qual Qual Qual Column
A
A
A
Serial_No:06052319:30
Page 12 of 20
Methane
Ethene
Ethane
17.8
ND
ND
15.3
ND
ND
ug/l
ug/l
ug/l
15
NC
NC
25
25
25
Units RPDParameterNative Sample Duplicate Sample
RPD
Limits
Dissolved Gases by GC - Mansfield Lab Associated sample(s): 01 QC Batch ID: WG1786321-4 QC Sample: L2329700-01 Client ID: MW-10D
RANDOLPH LF
223052466
Project Name:
Project Number:
L2329700Lab Number:
Report Date:
Lab Duplicate Analysis
Batch Quality Control
06/05/23
Qual
A
A
A
Serial_No:06052319:30
Page 13 of 20
*Values in parentheses indicate holding time in days
L2329700-01A
L2329700-01B
L2329700-01C
L2329700-01D
L2329700-01E
20ml Vial HCl preserved
20ml Vial HCl preserved
20ml Vial HCl preserved
Vial unpreserved 20ml
Vial unpreserved 20ml
A
A
A
A
A
NA
NA
NA
NA
NA
1.9
1.9
1.9
1.9
1.9
Y
Y
Y
Y
Y
Absent
Absent
Absent
Absent
Absent
A Absent
Cooler Custody Seal
Cooler Information
RANDOLPH LF
223052466
DISSGAS(14)
DISSGAS(14)
DISSGAS(14)
DISSGAS-CO2(7)
DISSGAS-CO2(7)
Project Name:
Project Number:
L2329700Lab Number:
Report Date:
Sample Receipt and Container Information
Container ID Container Type Cooler
Temp
deg C Pres Seal
Container Information
Analysis(*)
06/05/23
Were project specific reporting limits specified?YES
Frozen
Date/Time
Final
pH
Initial
pH
Serial_No:06052319:30
Page 14 of 20
Report Format:DU Report with 'J' Qualifiers
GLOSSARY
Project Name:
Project Number:
Lab Number:
Report Date:
L2329700RANDOLPH LF
223052466 06/05/23
Acronyms
DL
EDL
EMPC
EPA
LCS
LCSD
LFB
LOD
LOQ
MDL
MS
MSD
NA
NC
NDPA/DPA
NI
NP
NR
RL
RPD
SRM
STLP
TEF
TEQ
TIC
Detection Limit: This value represents the level to which target analyte concentrations are reported as estimated values, when
those target analyte concentrations are quantified below the limit of quantitation (LOQ). The DL includes any adjustments
from dilutions, concentrations or moisture content, where applicable. (DoD report formats only.)
Estimated Detection Limit: This value represents the level to which target analyte concentrations are reported as estimated
values, when those target analyte concentrations are quantified below the reporting limit (RL). The EDL includes any
adjustments from dilutions, concentrations or moisture content, where applicable. The use of EDLs is specific to the analysis
of PAHs using Solid-Phase Microextraction (SPME).
Estimated Maximum Possible Concentration: The concentration that results from the signal present at the retention time of an
analyte when the ions meet all of the identification criteria except the ion abundance ratio criteria. An EMPC is a worst-case
estimate of the concentration.
Environmental Protection Agency.
Laboratory Control Sample: A sample matrix, free from the analytes of interest, spiked with verified known amounts of
analytes or a material containing known and verified amounts of analytes.
Laboratory Control Sample Duplicate: Refer to LCS.
Laboratory Fortified Blank: A sample matrix, free from the analytes of interest, spiked with verified known amounts of
analytes or a material containing known and verified amounts of analytes.
Limit of Detection: This value represents the level to which a target analyte can reliably be detected for a specific analyte in a
specific matrix by a specific method. The LOD includes any adjustments from dilutions, concentrations or moisture content,
where applicable. (DoD report formats only.)
Limit of Quantitation: The value at which an instrument can accurately measure an analyte at a specific concentration. The
LOQ includes any adjustments from dilutions, concentrations or moisture content, where applicable. (DoD report formats
only.)
Limit of Quantitation: The value at which an instrument can accurately measure an analyte at a specific concentration. The
LOQ includes any adjustments from dilutions, concentrations or moisture content, where applicable. (DoD report formats
only.)
Method Detection Limit: This value represents the level to which target analyte concentrations are reported as estimated
values, when those target analyte concentrations are quantified below the reporting limit (RL). The MDL includes any
adjustments from dilutions, concentrations or moisture content, where applicable.
Matrix Spike Sample: A sample prepared by adding a known mass of target analyte to a specified amount of matrix sample for
which an independent estimate of target analyte concentration is available. For Method 332.0, the spike recovery is calculated
using the native concentration, including estimated values.
Matrix Spike Sample Duplicate: Refer to MS.
Not Applicable.
Not Calculated: Term is utilized when one or more of the results utilized in the calculation are non-detect at the parameter's
reporting unit.
N-Nitrosodiphenylamine/Diphenylamine.
Not Ignitable.
Non-Plastic: Term is utilized for the analysis of Atterberg Limits in soil.
No Results: Term is utilized when 'No Target Compounds Requested' is reported for the analysis of Volatile or Semivolatile
Organic TIC only requests.
Reporting Limit: The value at which an instrument can accurately measure an analyte at a specific concentration. The RL
includes any adjustments from dilutions, concentrations or moisture content, where applicable.
Relative Percent Difference: The results from matrix and/or matrix spike duplicates are primarily designed to assess the
precision of analytical results in a given matrix and are expressed as relative percent difference (RPD). Values which are less
than five times the reporting limit for any individual parameter are evaluated by utilizing the absolute difference between the
values; although the RPD value will be provided in the report.
Standard Reference Material: A reference sample of a known or certified value that is of the same or similar matrix as the
associated field samples.
Semi-dynamic Tank Leaching Procedure per EPA Method 1315.
Toxic Equivalency Factors: The values assigned to each dioxin and furan to evaluate their toxicity relative to 2,3,7,8-TCDD.
Toxic Equivalent: The measure of a sample's toxicity derived by multiplying each dioxin and furan by its corresponding TEF
and then summing the resulting values.
Tentatively Identified Compound: A compound that has been identified to be present and is not part of the target compound
list (TCL) for the method and/or program. All TICs are qualitatively identified and reported as estimated concentrations.
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
Serial_No:06052319:30
Page 15 of 20
Report Format:DU Report with 'J' Qualifiers
Project Name:
Project Number:
Lab Number:
Report Date:
L2329700RANDOLPH LF
223052466 06/05/23
Terms
Analytical Method: Both the document from which the method originates and the analytical reference method. (Example: EPA 8260B is
shown as 1,8260B.) The codes for the reference method documents are provided in the References section of the Addendum.
Chlordane: The target compound Chlordane (CAS No. 57-74-9) is reported for GC ECD analyses. Per EPA,this compound "refers to a
mixture of chlordane isomers, other chlorinated hydrocarbons and numerous other components." (Reference: USEPA Toxicological Review
of Chlordane, In Support of Summary Information on the Integrated Risk Information System (IRIS), December 1997.)
Difference: With respect to Total Oxidizable Precursor (TOP) Assay analysis, the difference is defined as the Post-Treatment value minus the
Pre-Treatment value.
Final pH: As it pertains to Sample Receipt & Container Information section of the report, Final pH reflects pH of container determined after
adjustment at the laboratory, if applicable. If no adjustment required, value reflects Initial pH.
Frozen Date/Time: With respect to Volatile Organics in soil, Frozen Date/Time reflects the date/time at which associated Reagent Water-
preserved vials were initially frozen. Note: If frozen date/time is beyond 48 hours from sample collection, value will be reflected in 'bold'.
Gasoline Range Organics (GRO): Gasoline Range Organics (GRO) results include all chromatographic peaks eluting from Methyl tert butyl
ether through Naphthalene, with the exception of GRO analysis in support of State of Ohio programs, which includes all chromatographic
peaks eluting from Hexane through Dodecane.
Initial pH: As it pertains to Sample Receipt & Container Information section of the report, Initial pH reflects pH of container determined upon
receipt, if applicable.
PAH Total: With respect to Alkylated PAH analyses, the 'PAHs, Total' result is defined as the summation of results for all or a subset of the
following compounds: Naphthalene, C1-C4 Naphthalenes, 2-Methylnaphthalene, 1-Methylnaphthalene, Biphenyl, Acenaphthylene,
Acenaphthene, Fluorene, C1-C3 Fluorenes, Phenanthrene, C1-C4 Phenanthrenes/Anthracenes, Anthracene, Fluoranthene, Pyrene, C1-C4
Fluoranthenes/Pyrenes, Benz(a)anthracene, Chrysene, C1-C4 Chrysenes, Benzo(b)fluoranthene, Benzo(j)+(k)fluoranthene, Benzo(e)pyrene,
Benzo(a)pyrene, Perylene, Indeno(1,2,3-cd)pyrene, Dibenz(ah)+(ac)anthracene, Benzo(g,h,i)perylene. If a 'Total' result is requested, the
results of its individual components will also be reported.
PFAS Total: With respect to PFAS analyses, the 'PFAS, Total (5)' result is defined as the summation of results for: PFHpA, PFHxS, PFOA,
PFNA and PFOS. In addition, the 'PFAS, Total (6)' result is defined as the summation of results for: PFHpA, PFHxS, PFOA, PFNA, PFDA
and PFOS. For MassDEP DW compliance analysis only, the 'PFAS, Total (6)' result is defined as the summation of results at or above the
RL. Note: If a 'Total' result is requested, the results of its individual components will also be reported.
Total: With respect to Organic analyses, a 'Total' result is defined as the summation of results for individual isomers or Aroclors. If a 'Total'
result is requested, the results of its individual components will also be reported. This is applicable to 'Total' results for methods 8260, 8081
and 8082.
Data Qualifiers
A
B
C
D
E
F
G
H
I
J
-
-
-
-
-
-
-
-
-
-
Spectra identified as "Aldol Condensates" are byproducts of the extraction/concentration procedures when acetone is introduced in
the process.
The analyte was detected above the reporting limit in the associated method blank. Flag only applies to associated field samples that
have detectable concentrations of the analyte at less than ten times (10x) the concentration found in the blank. For MCP-related
projects, flag only applies to associated field samples that have detectable concentrations of the analyte at less than ten times (10x)
the concentration found in the blank. For DOD-related projects, flag only applies to associated field samples that have detectable
concentrations of the analyte at less than ten times (10x) the concentration found in the blank AND the analyte was detected above
one-half the reporting limit (or above the reporting limit for common lab contaminants) in the associated method blank. For NJ-
Air-related projects, flag only applies to associated field samples that have detectable concentrations of the analyte above the
reporting limit. For NJ-related projects (excluding Air), flag only applies to associated field samples that have detectable
concentrations of the analyte, which was detected above the reporting limit in the associated method blank or above five times the
reporting limit for common lab contaminants (Phthalates, Acetone, Methylene Chloride, 2-Butanone).
Co-elution: The target analyte co-elutes with a known lab standard (i.e. surrogate, internal standards, etc.) for co-extracted
analyses.
Concentration of analyte was quantified from diluted analysis. Flag only applies to field samples that have detectable concentrations
of the analyte.
Concentration of analyte exceeds the range of the calibration curve and/or linear range of the instrument.
The ratio of quantifier ion response to qualifier ion response falls outside of the laboratory criteria. Results are considered to be an
estimated maximum concentration.
The concentration may be biased high due to matrix interferences (i.e, co-elution) with non-target compound(s). The result should
be considered estimated.
The analysis of pH was performed beyond the regulatory-required holding time of 15 minutes from the time of sample collection.
The lower value for the two columns has been reported due to obvious interference.
Estimated value. The Target analyte concentration is below the quantitation limit (RL), but above the Method Detection Limit
(MDL) or Estimated Detection Limit (EDL) for SPME-related analyses. This represents an estimated concentration for Tentatively
1 The reference for this analyte should be considered modified since this analyte is absent from the target analyte list of the
original method.
Footnotes
Serial_No:06052319:30
Page 16 of 20
Report Format:DU Report with 'J' Qualifiers
Project Name:
Project Number:
Lab Number:
Report Date:
L2329700RANDOLPH LF
223052466 06/05/23
Data Qualifiers
M
ND
NJ
P
Q
R
RE
S
V
Z
-
-
-
-
-
-
-
-
-
-
Identified Compounds (TICs).
Reporting Limit (RL) exceeds the MCP CAM Reporting Limit for this analyte.
Not detected at the method detection limit (MDL) for the sample, or estimated detection limit (EDL) for SPME-related analyses.
Presumptive evidence of compound. This represents an estimated concentration for Tentatively Identified Compounds (TICs), where
the identification is based on a mass spectral library search.
The RPD between the results for the two columns exceeds the method-specified criteria.
The quality control sample exceeds the associated acceptance criteria. For DOD-related projects, LCS and/or Continuing Calibration
Standard exceedences are also qualified on all associated sample results. Note: This flag is not applicable for matrix spike recoveries
when the sample concentration is greater than 4x the spike added or for batch duplicate RPD when the sample concentrations are less
than 5x the RL. (Metals only.)
Analytical results are from sample re-analysis.
Analytical results are from sample re-extraction.
Analytical results are from modified screening analysis.
The surrogate associated with this target analyte has a recovery outside the QC acceptance limits. (Applicable to MassDEP DW
Compliance samples only.)
The batch matrix spike and/or duplicate associated with this target analyte has a recovery/RPD outside the QC acceptance limits.
(Applicable to MassDEP DW Compliance samples only.)
Serial_No:06052319:30
Page 17 of 20
Alpha Analytical performs services with reasonable care and diligence normal to the analytical testing
laboratory industry. In the event of an error, the sole and exclusive responsibility of Alpha Analytical
shall be to re-perform the work at it's own expense. In no event shall Alpha Analytical be held liable
for any incidental, consequential or special damages, including but not limited to, damages in any way
connected with the use of, interpretation of, information or analysis provided by Alpha Analytical.
We strongly urge our clients to comply with EPA protocol regarding sample volume, preservation, cooling,
containers, sampling procedures, holding time and splitting of samples in the field.
LIMITATION OF LIABILITIES
117 Technical Guidance for the Natural Attenuation Indicators: Methane, Ethane, and
Ethene, EPA-NE, Revision 1, February 21, 2002 and Sample Preparation &
Calculations for Dissolved Gas Analysis in Water Samples using a GC Headspace
Equilibration Technique, EPA RSKSOP-175, Revision 2, May 2004.
Project Name:
Project Number:
Lab Number:
Report Date:
L2329700RANDOLPH LF
223052466
REFERENCES
06/05/23
Serial_No:06052319:30
Page 18 of 20
Alpha Analytical, Inc.ID No.:17873
Company-wide Revision 19
Quality Assurance Published Date: 4/2/2021 1:14:23 PM
Certificate/Approval Program Summary Page 1 of 1
Document Type: Form Pre-Qualtrax Document ID: 08-113
Certification Information
The following analytes are not included in our Primary NELAP Scope of Accreditation:
Westborough Facility
EPA 624/624.1: m/p-xylene, o-xylene, Naphthalene
EPA 625/625.1: alpha-Terpineol
EPA 8260C/8260D: NPW: 1,2,4,5-Tetramethylbenzene; 4-Ethyltoluene, Azobenzene; SCM: Iodomethane (methyl iodide), 1,2,4,5-Tetramethylbenzene;
4-Ethyltoluene.
EPA 8270D/8270E: NPW: Dimethylnaphthalene,1,4-Diphenylhydrazine, alpha-Terpineol; SCM: Dimethylnaphthalene,1,4-Diphenylhydrazine.
SM4500: NPW: Amenable Cyanide; SCM: Total Phosphorus, TKN, NO2, NO3.
Mansfield Facility
SM 2540D: TSS
EPA 8082A: NPW: PCB: 1, 5, 31, 87,101, 110, 141, 151, 153, 180, 183, 187.
EPA TO-15: Halothane, 2,4,4-Trimethyl-2-pentene, 2,4,4-Trimethyl-1-pentene, Thiophene, 2-Methylthiophene,
3-Methylthiophene, 2-Ethylthiophene, 1,2,3-Trimethylbenzene, Indan, Indene, 1,2,4,5-Tetramethylbenzene, Benzothiophene, 1-Methylnaphthalene.
Biological Tissue Matrix: EPA 3050B
The following analytes are included in our Massachusetts DEP Scope of Accreditation
Westborough Facility:
Drinking Water
EPA 300.0: Chloride, Nitrate-N, Fluoride, Sulfate; EPA 353.2: Nitrate-N, Nitrite-N; SM4500NO3-F: Nitrate-N, Nitrite-N; SM4500F-C, SM4500CN-CE,
EPA 180.1, SM2130B, SM4500Cl-D, SM2320B, SM2540C, SM4500H-B, SM4500NO2-B
EPA 332: Perchlorate; EPA 524.2: THMs and VOCs; EPA 504.1: EDB, DBCP.
Microbiology: SM9215B; SM9223-P/A, SM9223B-Colilert-QT,SM9222D.
Non-Potable Water
SM4500H,B, EPA 120.1, SM2510B, SM2540C, SM2320B, SM4500CL-E, SM4500F-BC, SM4500NH3-BH: Ammonia-N and Kjeldahl-N, EPA 350.1:
Ammonia-N, LACHAT 10-107-06-1-B: Ammonia-N, EPA 351.1, SM4500NO3-F, EPA 353.2: Nitrate-N, SM4500P-E, SM4500P-B, E, SM4500SO4-E,
SM5220D, EPA 410.4, SM5210B, SM5310C, SM4500CL-D, EPA 1664, EPA 420.1, SM4500-CN-CE, SM2540D, EPA 300: Chloride, Sulfate, Nitrate.
EPA 624.1: Volatile Halocarbons & Aromatics,
EPA 608.3: Chlordane, Toxaphene, Aldrin, alpha-BHC, beta-BHC, gamma-BHC, delta-BHC, Dieldrin, DDD, DDE, DDT, Endosulfan I, Endosulfan II,
Endosulfan sulfate, Endrin, Endrin Aldehyde, Heptachlor, Heptachlor Epoxide, PCBs
EPA 625.1: SVOC (Acid/Base/Neutral Extractables), EPA 600/4-81-045: PCB-Oil.
Microbiology: SM9223B-Colilert-QT; Enterolert-QT, SM9221E, EPA 1600, EPA 1603, SM9222D.
Mansfield Facility:
Drinking Water
EPA 200.7: Al, Ba, Cd, Cr, Cu, Fe, Mn, Ni, Na, Ag, Ca, Zn. EPA 200.8: Al, Sb, As, Ba, Be, Cd, Cr, Cu, Pb, Mn, Ni, Se, Ag, TL, Zn. EPA 245.1 Hg.
EPA 522, EPA 537.1.
Non-Potable Water
EPA 200.7: Al, Sb, As, Be, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Ag, Na, Sr, TL, Ti, V, Zn.
EPA 200.8: Al, Sb, As, Be, Cd, Cr, Cu, Fe, Pb, Mn, Ni, K, Se, Ag, Na, TL, Zn.
EPA 245.1 Hg.
SM2340B
For a complete listing of analytes and methods, please contact your Alpha Project Manager.
Serial_No:06052319:30
Page 19 of 20
Serial_No:06052319:30
Page 20 of 20
WSP USA INC
QUALITY ASSURANCE & QUALITY CONTROL
LABORATORY DATA RTMIEW
Page 1 of 4

Project Name: Randolph County Landfill- MNA
Project Reference Number: 31404568.018
Sampling Event Date: May 22 – 24, 2023
Review Date: August 8, 2023 Initials: JS
Report #: 752-7507-1, 223052466, 223052434 Review: MS
Person(s) performing the review are to initial each item on this form as acknowledgement of data
acceptance, or as acknowledgement of a review issue. In the case of the latter, a brief explanation
should follow the applicable item.

WSP USA Inc. has reviewed the laboratory certificates of analysis, chain-of-custody form, and laboratory
provided sample group quality assurance and quality control data for the above referenced sample group
to identify potential bias or inaccuracy, in general accordance with the following United States
Environmental Protection Agency documents:

 Region III Modifications to Functional Guidelines for Organic Data Review Multi-Media, Multi-
Concentration, September 1994;
 Region III Modifications to the Laboratory Data Validation Functional Guidelines for Evaluating
Inorganic Analyses, April 1993; and
 Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, July 1998.

COMPLIANCE ANALYTE LIST(S) (check all that apply)

NC Closed Facility List (.500 Rules)
NC C & D List (New Rules)
NC Appendix I
NC Appendix I + Detects
NC Appendix II
NC Subtitle D Leachate List
Other: MNA Parameters

1.0 CHAIN OF CUSTODY (COC) REVIEW

JS COC was properly signed by all parties.

JS Correct project name and number are on the form.

JS Sample receipt condition at laboratory was acceptable.

JS Each sample and blank submitted for analysis appears in the report.

WSP USA INC

QUALITY ASSURANCE & QUALITY CONTROL
LABORATORY DATA RTMIEW
Page 2 of 4

2.0 SAMPLE HOLDING TIMES

JS Holding times for extraction and/or analysis were met for each analytical method (see below for
reference).

Review Criteria
Method Analytes Holding Time
SW-846 Method 8260 and 8011 VOCs 14 days
SW-846 Methods 8270, 8080, 8081,
8082, and 8151
SVOCs, PCBs, pesticides
and herbicides
7 days for extraction, 40 days
from extraction for analysis
SW-846 Methods 6000 and 7000
Series
Metals except mercury 6 months (no temperature
requirements)
SW-846 Method 7470 Mercury 28 days
SW-846 Method 376.1 Sulfide 7 days
SW-846 Method 9010 Cyanide 14 days
EPA Method 300 Nitrate/Sulfate 48 hours/28 days
EPA Method 405.1 BOD 48 hours
EPA Method 410.4 COD 28 days
EPA Method 365.4 Phosphorous 28 days

3.0 LABORATORY QUALITY CONTROL REVIEW

JS Laboratory analyzed at least one internal blank for each method, where applicable.

JS Laboratory blank is interference-free.

JS Surrogate recoveries are provided for each analytical method, where applicable.

JS Surrogate recoveries for each method are within the acceptable limits (i.e., at least
50% of the surrogates were within range).

JS MS/MSD/LCS data results are provided for each analytical method.

JS MS/MSD/LCS recoveries for each method are within the acceptable limits (i.e., at least 1 of the 3
were within range).

 Total Organic Carbon in MW-10D recovered outside the acceptable limits in the MSD
analysis (223052366).

4.0 ANALYTE LISTS/METHODS

JS The proper number of constituents are present for each analyte list as identified above (including
detects where applicable).

JS Proper EPA SW-846 analytical methods were used for analysis.

5.0 DATA REPORTING

JS All analytical reporting associated with the event was performed by the contracted lab.

JS Trip, field and/or equipment, and laboratory blank results have all been reported. All detects for
blanks are listed below by constituent. All laboratory method blanks, if any, have been ‘flagged’ with
a ‘B’ where detected in other samples as appropriate and a laboratory narrative was provided. If the
sample was flagged by the laboratory and is not within 5X of the concentration in the blank (or 10X
for commonly detected laboratory contaminants-acetone, methylene chloride and phthalates), list
WSP USA INC

QUALITY ASSURANCE & QUALITY CONTROL
LABORATORY DATA RTMIEW
Page 3 of 4

below with explanation if flags should be removed. If flags need to be added for samples, also list
below.

JS It is clear from the laboratory report that samples have or have not been diluted during analysis, and
if the samples have been diluted, the result is reported as a multiple of the dilution (e.g., a sample
diluted 10x resulting in an analytical detection of 1.0 should be reported as 10). Those that have
been diluted are listed below with the dilution factor.

 Chloride
 MW-10D (20X); MW-2 (2X), MW-10S (5X)
 Carbon Dioxide
 All sampling points (2X);
 Volatile Fatty Acids
 MW-10S, MW-10D (10X);
 Nitrate
 MW-10D (2X);
 Sulfate
 MW-10D (2X);

JS The report provides the reporting limit for each constituent.

JS The results were reported at or below their proper reporting limits. Those that are not reported
correctly are listed below (by constituent) with the proper reporting limit listed beside them. State if
the reporting limit error is due to dilutions.

JS No organic constituents were reported above their respective reporting limits, and no inorganic or
organic constituents were reported above their respective NC 2L Drinking Water Standards/NC 2L
IMAC in wells, field/equipment/trip blanks, or above applicable surface water standards in surface
water points. Those that were detected above applicable groundwater/surface water standards are
listed below.

 1,1-Dichloroethane (2L = 6 ug/L)
 MW-10S @ 38.3 ug/L

 Vinyl Chloride (2L = 0.03 ug/L)
 MW-10S @ 0.665 ug/L

JS No inorganic and organic constituents were detected in a well or surface water point at quantified
concentrations outside of their historical range (more than 5X previous concentrations or first-time
detections).

 Ferrous Iron (1st time detection)
 MW-8 @ 0.021 ug/L (J)

 Sulfide (1st time detections)
 MW-2 @ 4.4 mg/L
 MW-3 @ 5.0 mg/L
 MW-7 @ 3.2 mg/L
 MW-8 @ 3.2 mg/L
 MW-10S @ 4.0 mg/L
 MW-10D @ 4.0 mg/L
 MW-11S @ 2.2 mg/L

WSP USA INC

QUALITY ASSURANCE & QUALITY CONTROL
LABORATORY DATA RTMIEW
Page 4 of 4

 Lactic Acid (1st time detections)
 MW-3 @ 0.46 mg/L (J)
 MW-8 @ 0.72 mg/L
 MW-10D @ 0.073 mg/L (J)
 MW-11S @ 0.25 mg/L (J)

 Acetic Acid (1st time detection)
 MW-3 @ 1.1 mg/L

 Acetic Acid (>5X previous concentrations)
 MW-2 @ 1.1 mg/L
 MW-7 @ 1.0 mg/L
 MW-8 @ 1.1 mg/L
 MW-10S @ 8.5 mg/L
 MW-10D @ 8.4 mg/L
 MW-11S @ 1.2 mg/L

 Propionic Acid (1st time detections)
 MW-8 @ 0.19 mg/L (J)
 MW-10D @ 0.17 mg/L (J)

JS Other report issues/Communications with laboratory/etc.:

WSP USA INC.
QUALITY ASSURANCE & QUALITY CONTROL
LABORATORY DATA RTMIEW
Page 1 of 3

Project Name: Randolph County Landfill
Project Reference Number: 31404568.018
Sampling Event Date: May 22 - 24, 2023
Review Date: August 9, 2023 Initials: JS
Report #: 223052466 & 223052434 Review: MS
Person(s) performing the review are to initial each item on this form as acknowledgement of data
acceptance, or as acknowledgement of a review issue. In the case of the latter, a brief explanation
should follow the applicable item.

WSP USA Inc. has reviewed the laboratory certificates of analysis, chain-of-custody form, and laboratory
provided sample group quality assurance and quality control data for the above referenced sample group
to identify potential bias or inaccuracy, in general accordance with the following United States
Environmental Protection Agency documents:

 Region III Modifications to Functional Guidelines for Organic Data Review Multi-Media, Multi-
Concentration, September 1994;
 Region III Modifications to the Laboratory Data Validation Functional Guidelines for Evaluating
Inorganic Analyses, April 1993; and
 Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, July 1998.

COMPLIANCE ANALYTE LIST(S) (check all that apply)

NC Closed Facility List (.500 Rules)
NC C & D List (New Rules)
NC Appendix I
NC Appendix I + Detects
NC Appendix II
NC Subtitle D Leachate List
Other: Hydrogen, CO2, Ferrous Iron, Methane, Ethane, Ethene

1.0 CHAIN OF CUSTODY (COC) REVIEW

JS COC was properly signed by all parties.

JS Correct project name and number are on the form.

JS Sample receipt condition at laboratory was acceptable.

JS Each sample and blank submitted for analysis appears in the report.
2.0 SAMPLE HOLDING TIMES

JS Holding times for extraction and/or analysis were met for each analytical method (see below for
reference).

Review Criteria
Method Analytes Holding Time
SW-846 Method 8260 and 8011 VOCs 14 days
SW-846 Methods 8270, 8080, 8081,
8082, and 8151
SVOCs, PCBs, pesticides
and herbicides
7 days for extraction, 40 days
from extraction for analysis
SW-846 Methods 6000 and 7000
Series
Metals except mercury 6 months (no temperature
requirements)
SW-846 Method 7470 Mercury 28 days
SW-846 Method 376.1 Sulfide 7 days
WSP USA INC
QUALITY ASSURANCE & QUALITY CONTROL
LABORATORY DATA RTMIEW
Page 2 of 3

SW-846 Method 9010 Cyanide 14 days
EPA Method 300 Nitrate/Sulfate 48 hours/28 days
EPA Method 405.1 BOD 48 hours
EPA Method 410.4 COD 28 days
EPA Method 365.4 Phosphorous 28 days

3.0 LABORATORY QUALITY CONTROL REVIEW

JS Laboratory analyzed at least one internal blank for each method, where applicable.

JS Laboratory blank is interference-free.

JS Surrogate recoveries are provided for each analytical method, where applicable.

JS Surrogate recoveries for each method are within the acceptable limits (i.e., at least
50% of the surrogates were within range).

JS MS/MSD/LCS data results are provided for each analytical method.

JS MS/MSD/LCS recoveries for each method are within the acceptable limits (i.e., at least 1 of the 3
were within range).
 Total Organic Carbon in MW-10D recovered outside the acceptable limits in the MSD
analysis (223052366).

4.0 ANALYTE LISTS/METHODS

JS The proper number of constituents are present for each analyte list as identified above (including
detects where applicable).

JS Proper EPA SW-846 analytical methods were used for analysis.

5.0 DATA REPORTING

JS All analytical reporting associated with the event was performed by the contracted lab.

JS Trip, field and/or equipment, and laboratory blank results have all been reported. All detects for
blanks are listed below by constituent. All laboratory method blanks, if any, have been ‘flagged’ with
a ‘B’ where detected in other samples as appropriate and a laboratory narrative was provided. If the
sample was flagged by the laboratory and is not within 5X of the concentration in the blank (or 10X
for commonly detected laboratory contaminants-acetone, methylene chloride and phthalates), list
below with explanation if flags should be removed. If flags need to be added for samples, also list
below.

JS It is clear from the laboratory report that samples have or have not been diluted during analysis, and
if the samples have been diluted, the result is reported as a multiple of the dilution (e.g., a sample
diluted 10x resulting in an analytical detection of 1.0 should be reported as 10). Those that have
been diluted are listed below with the dilution factor.
 Carbon Dioxide
 All sampling points (2X);

JS The report provides the reporting limit for each constituent.

JS The results were reported at or below their proper reporting limits (i.e., MDLs with SWSLs reported).
Those that are not reported correctly are listed below (by constituent) with the proper reporting limit
WSP USA INC
QUALITY ASSURANCE & QUALITY CONTROL
LABORATORY DATA RTMIEW
Page 3 of 3

listed beside them. State if the reporting limit error is due to dilutions.

JS No organic constituents were reported above their respective SWSLs, and no inorganic or organic
constituents were reported above their respective NC 2L Drinking Water Standards/GWPS in wells,
or field/equipment/trip blanks, or above applicable surface water standards in surface water points.

JS No inorganic and organic constituents were detected in a well or surface water point at quantified
concentrations outside of their historical range (more than 5X previous concentrations or first-time
detections).

JS Other report issues/Communications with laboratory/etc.:

APPENDIX C
EPA Natural Attenuation Screening
Protocol Forms and BIOCHLOR
Monitored Natural Attenuation
Analysis

Reviewed By: NTT
Prepared By: NTT
Project #: 31404568.018
DATE: 9/6/2023
Appendix
C-2
Title:
MW-2 MNA SCREENING
May 2023 Baseline MNA Evaluation
Randolph County Landfill, Permit No. 76-01

Reviewed By: NTT
Prepared By: NTT
Project #: 31404568.018
DATE: 9/6/2023 Appendi
x
C-3
Title: MW-3 MNA SCREENING May 2023 Baseline MNA Evaluation Randolph County Landfill, Permit No. 76-01

Reviewed By: NTT
Prepared By: NTT
Project #: 31404568.018
DATE: 9/6/2023
Appendix
C-4
Title: MW-7 MNA SCREENING
May 2023 Baseline MNA Evaluation
Randolph County Landfill, Permit No. 76-01

Reviewed By: NTT
Prepared By: NTT
Project #: 31404568.018
DATE: 9/6/2023 Appendix
C-5
Title: MW-8 MNA SCREENING May 2023 Baseline MNA Evaluation Randolph County Landfill, Permit No. 76-01

Reviewed By: NTT
Prepared By: NTT
Project #: 31404568.018
DATE: 9/6/2023
Appendix
C-6
Title: MW-10S MNA SCREENING
May 2023 Baseline MNA Evaluation
Randolph County Landfill, Permit No. 76-01

Reviewed By: NTT
Prepared By: NTT
Project #: 31404568.018
DATE: 9/6/2023
Appendix
C-7
Title:
MW-10D MNA SCREENING
May 2023 Baseline MNA Evaluation
Randolph County Landfill, Permit No. 76-01

Reviewed By: NTT
Prepared By: NTT
Project #: 31404568.018
DATE: 9/6/2023 Appendi
x
C-8
Title: MW-11S MNA SCREENING May 2023 Baseline MNA Evaluation Randolph County Landfill, Permit No. 76-01

Appendix
C-9
Title:
BIOCHLOR DATA ENTRY SHEETS FOR
WELLS MW-8 AND MW-3
May 2023 Baseline MNA Evaluation
Randolph County Landfill, Permit No. 76-
01
Date: 9/6/2023
Project#:31404568.018
Prepared By: NTT
Review By: NTT

Reviewed By: NTT
Prepared By: NTT
Project# 31404568.018
Date: 9/9/2023
Appendix
C-10
Title:
BIOCHLOR MODEL FOR WELLS
MW-8 AND MW-3
May 2023 Baseline MNA Evaluation
Randolph County Landfill, Permit No. 76-01

Prepared By: NTT
Project# 31404568.018
DATE: 9/6/2023 Appendix
C-11
Title:
BIOCHLOR DATA ENTRY SHEETS FOR
WELLS MW-10S, MW-10D, AND SW-2
May 2023 Baseline MNA Evaluation
Randolph County Landfill, Permit No. 76-01 Review By: NTT

Reviewed By: NTT
Prepared By: NTT
Project# 31404568.018
Date: 9/9/2023
Appendix
C-12
Title:
BIOCHLOR MODEL FOR WELLS
MW-10S, MW-10D, AND SW-2
May 2023 Baseline MNA Evaluation
Randolph County Landfill, Permit No. 76-01