8106_DukeRogers_SemiAnnual Report_FID1894025_20240823

DENR USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No) Doc/Event #:
NC DENR I I Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
• Prepare one form for each individually monitored unit.
• Please type or print legibly.
• Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 213 surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
• Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
• Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
• Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
SynTerra Corporation (Consultant)
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Scott Spinner
E-mail: [e-mail]
Phone: [phone]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Duke Energy Carolinas, LLC 573 Duke Power Road 8106 .0500 April 16-17, 2024
Roger's Energy Complex Mooresboro, North Carolina April 26, 2024
Cliffside Steam Station
CCP Landfill
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring ® Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells ❑
Leachate monitoring data ❑
Surface water monitoring data
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Scott Spinner
Project Manager
Facility���Name (Print) Title
8/21 /2024
Signature Date
148 River Street, Suite 220, Greenville, SC 29601
Facility Representative Address
C-1478 / North Carolina Geological Corporation Number C-387
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009
[phone]
(Area Code) Telephone Number
Affix NC Licensed/ Professional Geologist Seal

REPORT VERIFICATION
PROJECT: SEMIANNUAL WATER QUALITY MONITORING REPORT
APRIL 2024 SAMPLING EVENT
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
CCP LANDFILL PHASES I THROUGH IV
PERMIT NO. 8106
TITLE: APRIL 2024 SAMPLING EVENT
This document has been reviewed for accuracy and quality commensurate with the intended
application.
Prepared by: Date: August 21, 2024
Trevor Ludwick
Approved by: Date
Scott Spinner
Project Manager: Scott Spinner, NC LG
August 21, 2024
Licensed Geologist Seal:
SynTerra
148 River Street, Suite 220
Greenville, SC 29601
North Carolina Geological Corporation Number C-387

Terra Science &Engineering Consultants
synsynterracorp.com
SEMIANNUAL
WATER QUALITY MONITORING REPORT
APRIL 2024 SAMPLING EVENT
CCP LANDFILL PHASES I THROUGH IV
PERMIT NO.8106-INDUS)
CLEVELAND AND RUTHERFORD COUNTIES
ROGERS ENERGY COMPLEX — CLIFFSIDE STEAM STATION
573 DUKE POWER ROAD
MOORESBORO, NORTH CAROLINA
AUGUST 21, 2024
PREPARED FOR
r� DUKE
ENERGY.:
CAROLINAS
DUKE ENERGY CAROLINAS, LLC
i
Kathy Webb
Senior Peer Reviewer
c��Fb�`(j 1oexd j1U,1C' �s
Trevor Ludwick
Project Scientist
Scott Spinner, NC LG #2243
Project Manager

Semiannual Water Quality Monitoring Report — April 2024 Sampling Event
Rogers Energy Complex—Cliffside Steam Station —CCP Landfill Phases I through IV (Permit No. 8106-INDUS)
Mooresboro, North Carolina
TABLE OF CONTENTS
SECTION
PAGE
1.0
INTRODUCTION AND BACKGROUND.........................................................................
1-1
1.1
Site and Landfill Information.......................................................................................1-1
1.2
Hydrogeologic Setting..................................................................................................1-1
1.3
Landfill Semiannual Monitoring Program....................................................................1-2
2.0
METHODS................................................................................................................
2-1
2.1
Sampling and Analysis Methods..................................................................................
2-1
2.2
Regulatory Criteria.......................................................................................................2-2
2.3
Statement of Work......................................................................................................
2-2
3.0
RESULTS...................................................................................................................3-1
3.1
Site Groundwater Flow................................................................................................3-1
3.2
Analytical Results.........................................................................................................3-1
3.3
Quality Assurance/Quality Control..............................................................................
3-2
4.0
REFERENCES.............................................................................................................4-1
August 2024
Page i
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — April 2024 Sampling Event
Rogers Energy Complex — Cliff side Steam Station — CCP Landfill Phases I through IV (Permit No. 8106-INDUS)
Mooresboro, North Carolina
LIST OF FIGURES
Figure 1 Site Location Map
Figure 2 Monitoring Locations
Figure 3A Groundwater Level Map — April 2024 — Upper (Shallow and Deep) Flow Zone
Figure 3B Groundwater Level Map — April 2024 — Bedrock Flow Zone
LIST OF TABLES
Table 1 Multi -Media Sampling Locations
Table 2 Summary of Well Construction Information
Table 3A Summary of Groundwater Constituents and Analytical Methods
Table 3B Summary of Surface Water Constituents and Analytical Methods
Table 3C Summary of Leachate Constituents and Analytical Methods
Table 4 Groundwater Seepage Velocities
Table 5 Field Data Parameters
Table 6 Groundwater Field and Analytical Results
Table 7 Field and Analytical Results Equal to or Greater than Groundwater Quality
Standards
Table 8 Surface Water Field and Analytical Results
Table 9 Leachate Field and Analytical Results
LIST OF APPENDICES
Appendix A Field Calibration Logs and Sampling Forms
Appendix B Laboratory Reports, Data Validation Checklists, and Chain -of -Custody Forms
August 2024
Page ii
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — April 2024 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106-INDUS)
Mooresboro, North Carolina
LIST OF ACRONYMS AND ABBREVIATIONS
µg/L
micrograms per liter
02B standards
Title 15A NCAC 02B .0200 Surface Water and Wetland Standards
02L standards
Title 15A NCAC 02L .0202(g) Groundwater Quality Standards
CCP
coal combustion products
CCR
coal combustion residuals
Cliffside
Cliffside Steam Station
Duke Energy
Duke Energy Carolinas, LLC
DWM
Division of Waste Management
EDD
electronic data deliverable
HDPE
high -density polyethylene
ISTV
in -stream target value
landfill
CCP Landfill Phases I through IV
mg/L
milligrams per liter
NCAC
North Carolina Administrative Code
NCDEQ
North Carolina Department of Environmental Quality
NRWQC
National Recommended Water Quality Criteria
Piedmont
Piedmont physiographic province
QA
quality assurance
QC
quality control
Site
Cliffside Steam Station
SW
solid waste
SWS
Solid Waste Section
USEPA
U.S. Environmental Protection Agency
WQMP
Water Quality Monitoring Plan
August 2024
Page iii
Project: 00.0092.67

Semiannual Water Quality Monitoring Report - April 2024 Sampling Event
Rogers Energy Complex - Cliffside Steam Station - CCP Landfill Phases I through IV (Permit No. 8106-INDUS)
Mooresboro, North Carolina
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This semiannual report pertains to the Duke Energy Carolinas, LLC (Duke Energy) Rogers Energy
Complex — Cliffside Steam Station (Cliffside or Site) Coal Combustion Products (CCP) Landfill
(landfill) and documents the results of the April 2024 groundwater, surface water, and leachate
monitoring event.
1.1 Site and Landfill Information
Duke Energy owns and operates Cliffside, located at 573 Duke Power Road in Cleveland and
Rutherford counties near Mooresboro, North Carolina (Figure 1).
The CCP Landfill has been developed in four Phases (Phases I through IV) and comprises a total
area of approximately 71.7 acres. The CCP Landfill currently accepts coal combustion residual
(CCR) material generated during coal-fired power generation and other CCR disposal needs for
the Site, which includes excavated CCR materials from the on -Site ash basins. The landfill
includes a liner system consisting of two geosynthetic barrier components (a 60-mil high -
density polyethylene (HDPE) geomembrane and a geosynthetic clay liner) between waste and
the groundwater beneath the landfill (SynTerra, 2024).
1.2 Hydrogeologic Setting
The Site is in the Inner Piedmont belt of the Piedmont physiographic province (Piedmont). The
Piedmont in North Carolina is characterized by gentle to steep, hilly terrain with small
quantities of alluvium. The Inner Piedmont belt is bounded on the northwest by the Brevard
Fault zone, on the southeast by the Kings Mountain Belt, and by the faults and shear zones that
define the central Piedmont structure.
As typical in the Piedmont, groundwater is present within the residuum, saprolite, partially
weathered rock, and fractured bedrock beneath the CCP Landfill. Groundwater in the vicinity of
the landfill may be first encountered in any of the hydrostratigraphic units depending on the
width of the overlying units and the general topography. In general, surface drainage from the
CCP Landfill flows from the west to the north, toward Duke Power Road, and to the south and
east, toward Suck Creek. The highest elevations at the landfill are along its western edge.
Two streams are near the CCP Landfill. Suck Creek is located approximately 1,200 feet
southeast of the landfill and flows north to the Broad River. An unnamed tributary to the Broad
River is located approximately 1,100 feet northwest of the landfill. Surface waters draining to
the Broad River are classified as WS-IV per Title 15A, North Carolina Administrative Code
(NCAC), Subchapter 02B, .0200 Surface Water and Wetland standards (02B standards). Based
on evaluation of local topography, shallow groundwater beneath the landfill liner is expected to
discharge to Suck Creek and the unnamed tributary.
The landfill and surrounding topographic and physiographic features are shown on Figure 2.
August 2024
Page 1-1
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — April 2024 Sampling Event
Rogers Energy Complex — Cliff side Steam Station — CCP Landfill Phases I through IV (Permit No. 8106-INDUS)
Mooresboro, North Carolina
1.3 Landfill Semiannual Monitoring Program
The previous Water Quality Monitoring Plan (WQMP; SynTerra, 2022) for the landfill has been
recently revised to incorporate changes. The April 2024 sampling event and this report comply
with Revision 1 of the WQMP (SynTerra, 2024), submitted to the North Carolina Department of
Environmental Quality (NCDEQ) Division of Waste Management (DWM), Solid Waste Section
(SWS) on February 7, 2024, and approved by the DWM on March 19, 2024. The landfill
semiannual monitoring program, described in detail in the revised WQMP, consists of 17
groundwater, three surface water, two leachate, and five water -level -only monitoring locations
listed in Table 1 and shown on Figure 2. A summary of monitoring well construction
information is presented in Table 2. Analytical parameters for the landfill semiannual
groundwater monitoring program are summarized in Table 3A, analytical parameters for the
surface water monitoring program are summarized in Table 313, and analytical parameters for
leachate are summarized in Table 3C.
August 2024
Page 1-2
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — April 2024 Sampling Event
Rogers Energy Complex — Cliff side Steam Station — CCP Landfill Phases I through IV (Permit No. 8106-INDUS)
Mooresboro, North Carolina
2.0 METHODS
2.1 Sampling and Analysis Methods
On April 16, 17, and 26, 2024, Pace Analytical Services personnel (North Carolina Field
Certification #5342) performed groundwater, surface water, and leachate sampling in
accordance with the North Carolina Solid Waste (SW) Management Guidelines. Copies of the
field calibration logs and sampling forms are included in Appendix A. Duke Energy Analytical
Laboratory (North Carolina Laboratory Certification #248) analyzed samples for the reported
parameters and constituents. Laboratory reports, data validation checklists, and chain -of -
custody forms are included in Appendix B.
In addition to 02B standards for surface water, Duke Energy provides comparisons against in -
stream target values (ISTV) and U.S. Environmental Protection Agency (USEPA) National
Recommended Water Quality Criteria (NRWQC). The ISTV comparison is conducted with the
qualification that an exceedance of the published value is not necessarily a violation of the
water quality standard for toxicity. As stated by the USEPA, NRWQC standards do not constitute
regulations, nor do they impose a legally binding requirement. Therefore, comparisons with
ISTV and USEPA NRWQC criteria are for screening or informational purposes only.
Additional information regarding surface water standards and screening criteria are presented
in Table 3B and outlined below:
Several 02B standards and ISTV require sampling methods specific to acute or chronic
concentrations and are not applicable to the grab sample method; however, acute
standards are considered more applicable to grab sampling and are included for
screening purposes only.
Hardness -dependent standards require sampling methods specific to acute or chronic
concentrations and are not applicable to the grab sample method. Duke Energy uses a
standard hardness of 25 milligrams per liter (mg/L) for screening purposes only;
however, if the in -stream hardness values for a given sampling event are less than or
greater than 25 mg/L, the minimum in -stream hardness value may be used to calculate
the hardness -dependent standard to more accurately screen analytical results.
The 02B surface water standards for chromium are based upon speciation for dissolved
trivalent and hexavalent chromium. Duke Energy analyzes surface water samples for
total and dissolved total chromium. Results are screened against the dissolved trivalent
02B standard; this standard is a hardness -dependent, acute standard and is based on 25
mg/L hardness and used for screening purposes only.
The 02B surface water standard for mercury represents a total concentration and is not
for acute, chronic, or hardness -dependent concentrations. The mercury 02B standard
for Class B, C, and water supply waters is 0.012 micrograms per liter (µg/L). Duke Energy
August 2024
Page 2-1
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — April 2024 Sampling Event
Rogers Energy Complex — Cliff side Steam Station — CCP Landfill Phases I through IV (Permit No. 8106-INDUS)
Mooresboro, North Carolina
uses the analytical method USEPA 245.1/SW 7470A for mercury analysis, which has a
reporting limit of 0.050 µg/L and is greater than the 02B criteria of 0.012 jig/L.
2.2 Regulatory Criteria
The semiannual monitoring analytical results are compared to the following regulatory criteria:
Groundwater
• 15A NCAC 02L .0202(g) Groundwater Quality standards (02L standards)
Surface Water
• 15A NCAC 02B .0200 Surface Water and Wetland standards (0213 standards)
Leachate
• Not compared to water quality standards
2.3 Statement of Work
The following tasks were completed for semiannual water quality monitoring:
• Collected groundwater, surface water, and leachate samples on April 16 and 17, 2024
(performed by Pace Analytical Services).
• Resampled surface water monitoring locations for total and dissolved analysis on April
26, 2024 (performed by Pace Analytical Services), because the initial dissolved metal
samples were lost by the shipping company while on transit to the Duke Energy
Analytical Laboratory.
• Reviewed the laboratory analytical results pertaining to the parameters listed in Tables
3A, 313, and 3C.
• Compared groundwater analytical results to 02L standards and historical concentration
ranges.
• Compared surface water analytical results to 02B standards and historical concentration
ranges.
• Developed generalized groundwater surface contour maps using groundwater elevation
data from a Site -wide water -level sweep conducted on April 15, 2024.
• Calculated groundwater flow velocities based on groundwater elevations at wells
perpendicular to groundwater flow.
• Converted the laboratory provided electronic data deliverable (EDD) to the format
requirements of the NCDEQ DWM EDD template and submitted copies of EDDs to the
NCDEQ DWM with this report.
• Prepared and submitted this report.
August 2024
Page 2-2
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — April 2024 Sampling Event
Rogers Energy Complex — Cliff side Steam Station — CCP Landfill Phases I through IV (Permit No. 8106-INDUS)
Mooresboro, North Carolina
t111=0*9111111141
3.1 Site Groundwater Flow
The predominant direction of groundwater flow at the Site is north toward the Broad River,
with a portion of groundwater in the central part of the Site flowing toward Suck Creek and
then north to the Broad River. Groundwater beneath the CCP Landfill flows east or southeast
toward Suck Creek, with a portion of the groundwater flowing north/northeast toward the
Broad River or northwest toward an unnamed tributary of the Broad River.
Generalized groundwater elevation contours and groundwater flow direction arrows in the
vicinity of the CCP Landfill are shown on Figure 3A for the upper (shallow and deep) flow zone
and Figure 3B for the bedrock flow zone. Those contours were developed by calculating
groundwater elevations in each monitoring well using depth -to -water measurements gauged
during a Site -wide water -level sweep conducted on April 15, 2024. Depth -to -water
measurements and calculated groundwater elevations are presented in Table 2. Calculated
groundwater seepage velocities are presented in Table 4. Calculated groundwater elevations,
based on depth -to -water measurements gauged during the Site -wide water -level sweep,
indicate groundwater at the landfill generally flows to the east/southeast, consistent with
historical Site observations.
3.2 Analytical Results
A summary of the groundwater, surface water, and leachate field data is presented in Table S.
Analytical results and reference comparisons discussed below are summarized in Table 6
through Table 9. Sample locations are depicted on Figure 2.
Groundwater Results
Field and analytical results for the collected downgradient and background groundwater
samples are presented in Table 6. Groundwater analytical results are compared with 02L
standards. Constituent concentrations equal to or greater than 02L standards are noted in
Table 6 by bold font and gray highlighted cells. The laboratory analytical reports are included in
Appendix B. A summary of the groundwater field and analytical results equal to or greater than
applicable comparison criteria is presented in Table 7. Note that for pH, the 02L standard is a
range of values, so pH results outside of the range are bolded and highlighted gray in Table 6
and included in Table 7. Constituent concentrations in Table 6 that are identified as being equal
to or greater than their applicable comparative criteria (or outside the comparative criteria
range for pH) are not attributed to a release from the CCP Landfill.
Surface Water
Field and analytical results for surface water samples are presented in Table 8. The sample
locations are depicted on Figure 2. Analytical results for surface water samples are compared
with applicable regulatory 02B standards for Class WS-IV waters (Section 1.2). There were no
August 2024
Page 3-1
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — April 2024 Sampling Event
Rogers Energy Complex — Cliff side Steam Station — CCP Landfill Phases I through IV (Permit No. 8106-INDUS)
Mooresboro, North Carolina
surface water analytical results equal to or greater than applicable 02B comparison criteria
during the April 2024 monitoring event.
Additionally, analytical results for surface water samples are compared with the screening
criteria discussed in Section 2.1 for informational purposes only. Constituent concentrations
equal to or greater than the screening criteria are noted in Table 8 by cells with only bold font.
Leachate
Leachate samples were collected from two discharge points (CCP-Leachate and CCP-Leachate-
34) located at the leachate pond. Leachate analytical results are presented in Table 9. Leachate
analytical results are not compared to groundwater (02L) or surface water (0213) quality
standards and are provided for informational purposes only.
3.3 Quality Assurance/Quality Control
Field -performed quality assurance and quality control (QA/QC) consisted of the collection and
analysis of field blanks to evaluate whether contamination was imparted to the samples by the
sample container, preservative, or other exogenous sources. A field duplicate sample was also
collected to estimate sampling and laboratory precision. The data were validated and deemed
usable.
Select samples were diluted, as is normal laboratory practice, to bring samples within the
calibrated range of the analysis. Specifics regarding the samples that were diluted, including the
dilution amount, are reported in the EDD and in the lab report. Additional QA/QC data,
laboratory analyses, and chain -of -custody forms are included in Appendix B.
August 2024 Page 3-2
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — April 2024 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106-INDUS)
Mooresboro, North Carolina
1191=11a94.4aL1toV
SynTerra. (2022). Water Quality Monitoring Plan, Rogers Energy Complex — Cliffside Steam
Station CCP Landfill Phases 1 Through IV. March 2022. Rev. 0.
SynTerra. (2024). Water Quality Monitoring Plan, Rogers Energy Complex — Cliffside Steam
Station CCP Landfill Phases I Through IV. February 2024. Rev. 1.
August 2024
Page 4-1
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — April 2024 Sampling Event
Rogers Energy Complex — Cliff side Steam Station — CCP Landfill Phases I through IV (Permit No. 8106-INDUS)
Mooresboro, North Carolina
FIGURES
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UPDATED APRIL 2023.
EV 0
FIGURE 1
DUKE
SITE LOCATION MAP
ENERGY RALEIG SEMIANNUAL WATER QUALITY MONITORING REPORT
• CCP LANDFILL PHASES I THROUGH IV
CHARLOTTE PERMIT NO. 8106-INDUS
• ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
MOORESBORO, NORTH CAROLINA
RUTHERFORD & WILMINGTO DRAWN BY B_ MCGANN DATE_ 10/20/2022
CLEVELAND REVISED BY E. ORDEMANN DATE: 06/17/2024 1,000 0 1,000 2,000
synTerrd COUNTIES CHECKED BY T LUDWICK DATE: 06/17/2024
APPROVED BY S_ SPINNER DATE 06/17/2oza GRAPHIC SCALE (IN FEET)
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NOTES:
t 1. WATER LEVELS WERE GAUGED ON APRIL 15 2024
} - y~ • "� 2. <- INDICATES THE WATER LEVEL IS BELOW THE TOP OF PUMPAND UNABLE TO BE
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^- 783.06 3. ELEVATIONS ARE REFERENCED TO THE NORTH AMERICAN VERTICAL DATUM OF 1988
-y_ (NAVD 88).
4. THE WATERS OF THE US DELINEATION HAS NOT BEEN APPROVED BY THE US ARMY
_ CORPS OF ENGINEERS AT THE TIME OF THE MAP CREATION. THIS MAP IS NOT TO BE USED
;- FOR JURISDICTIONAL DETERMINATION PURPOSES. THE WETLANDS AND STREAMS
} BOUNDARIES WERE OBTAINED FROM STREAM AND WETLAND DELINEATION CONDUCTED BY
AMEC FOSTER WHEELER ENVIRONMENTAL AND INFRASTRUCTURE, INC. NATURAL
RESOURCE TECHNICAL REPORT (NRTR) FOR CLIFFSIDE STEAM STATION, JUNE 2015.
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S. ALL BOUNDARIES ARE APPROXIMATE.
6. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY CAROLINAS.
7. AERIAL IMAGERY ISA COMBINATION OF DUKE ENERGY PROPELLER PHOTOGRAPHY
COLLECTED ON APRIL 25, 2024 ANDAERIAL PHOTOGRAPHY PROVIDED BY ESRI, COLLECTED
ONAPRIL2, 2020.
<788.828 — CCPMW-10 -
8. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE
COORDINATE SYSTEM RIPS 3200 (NAD83).
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150 300
(IN FEED
DRAWN BY: B. MCGANN
DATE: J0/20/2022
REVISED BY E ORDEMANN
DATE: 08/08/2024
CHECKED BY: T. LUDWICK
DATE: 08/OS/2024
APPROVED BY S-SPINNER
DATE: 08/08/2024
PROJECT MANAGER: S. SPINNER
FIGURE 3A
GROUNDWATER LEVEL MAP - APRIL 2024
UPPER (SHALLOW AND DEEP) FLOW ZONE
SEMIANNUAL WATER QUALITY MONITORING REPORT
CCP LANDFILL PHASES I THROUGH IV
PERMIT NO. 8106-INDUS
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
MOORESBORO, NORTH CAROLINA

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o� a ♦ �� `'♦sao
*.
+ 4'
d.
CCP LANDFILL
PHASE IV
ftM1J r •
CCR-CCP13G-113R.
836.30
aza
ss° CCPMW-2D 786.13 mod
830
._.�.._.. CCPMW-3D
+is �_e
_ _ _ _ GRAPHIC SCALE
3j,
x _ {' > DUKE 150 0 150 300
�.r.� . #.. #' ENERGY
e t. (IN FEET)
CAR^
.' DRAWN BY: B. MCGANN DATE: 10/26/2022
REVISEDBY:ON DATE: 06/17/2024
� CHECKED BY: T. LUDWICKUDWICK DATE: 06/17/2024
/ APPROVED BY: S. SPINNER DATE: 06/17/2024
• • t ` synTerra PROJECT MANAGER: S. SPINNER
www.s7nterracorp.com
GAO ARCGIS PRO F
2243
W
c } f 5,1
REV 0
LEGEND
SOLID WASTE SECTION MONITORING WELL
SOLID WASTE SECTION BACKGROUND MONITORING
WELL
WELL USED FOR WATER LEVEL ONLY
INFERRED GROUNDWATER ELEVATION CONTOUR (10'
CONTOUR)
GROUNDWATER FLOW DIRECTION
LANDFILL COMPLIANCE BOUNDARY
LANDFILL REVIEW BOUNDARY
---� LANDFILL LIMIT OF WASTE
— ASH BASIN WASTE BOUNDARY
- DUKE ENERGY CAROLINAS PROPERTY BOUNDARY
TOPOGRAPHY CONTOUR (10' INTERVAL)
I STREAM (AMEC NRTR)
® WETLANDS (AMEC NRTR)
NOTES:
1. WATER LEVELS WERE GAUGED ON APRIL 15, 2024.
2. ELEVATIONS ARE REFERENCED TO THE NORTH AMERICAN VERTICAL DATUM OF 1988 (NAVD
88).
3. THE WATERS OF THE US DELINEATION HAS NOT BEEN APPROVED BY THE US ARMY CORPS OF
ENGINEERS AT THE TIME OF THE MAP CREATION. THIS MAP IS NOT TO BE USED FOR
JURISDICTIONAL DETERMINATION PURPOSES. THE WETLANDS AND STREAMS BOUNDARIES
WERE OBTAINED FROM STREAM AND WETLAND DELINEATION CONDUCTED BYAMEC FOSTER
WHEELER ENVIRONMENTAL AND INFRASTRUCTURE,INC. NATURAL RESOURCE TECHNICAL
REPORT (NRTR) FOR CLIFFSIDE STEAM STATION, JUNE 2015.
4. ALL BOUNDARIES ARE APPROXIMATE.
5. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY CAROLINAS.
6. AERIAL IMAGERY IS A COMBINATION OF DUKE ENERGY PROPELLER PHOTOGRAPHY
COLLECTED ON APRIL 25, 2024 AND AERIAL PHOTOGRAPHY PROVIDED BY ESRI, COLLECTED ON
APRIL 2, 2020.
7. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE
COORDINATE SYSTEM HIPS 3200 (NAD83).
FIGURE 3B
GROUNDWATER LEVEL MAP -APRIL 2024
BEDROCK FLOW ZONE
SEMIANNUAL WATER QUALITY MONITORING REPORT
CCP LANDFILL PHASES I THROUGH IV
PERMIT NO. 8106-INDUS
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
MOORESBORO, NORTH CAROLINA

Semiannual Water Quality Monitoring Report — April 2024 Sampling Event
Rogers Energy Complex — Cliff side Steam Station — CCP Landfill Phases I through IV (Permit No. 8106-INDUS)
Mooresboro, North Carolina
TABLES
410
synTerra
Science & Engineering Consultants

TABLE 1
MULTI -MEDIA SAMPLING LOCATIONS
SEMIANNUAL WATER QUALITY MONITORING REPORT
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Monitoring Location ID
Media
Description
CCPMW-1S*
Groundwater
Installed to monitor background groundwater and is located west and upgradient of the landfill.
CCPMW-1D*
Installed to monitor background groundwater and is located west and upgradient of the landfill.
CCPMW-2S
Installed for assessment and is located south and downgradient of the landfill.
CCPMW-3D
Installed for assessment and is located south and downgradient of the landfill.
CCPMW-4
Installed for assessment and is located northwest and downgradient of the landfill.
CCPMW-5
Installed for assessment and is located north and downgradient of the landfill.
CCPMW-6S
Installed for assessment and is located north and downgradient of the landfill.
CCPMW-7
Installed for assessment and is located north and downgradient of the landfill.
CCPMW-10
Installed for assessment and is located south and downgradient of the landfill.
CCPMW-11
Installed for assessment and is located southeast and downgradient of the landfill.
CCR-CCP-18S
Installed as a part of a separate program for assessment and is located east and downgradient of the landfill.
CCR-CCP-19S
Installed as a part of a separate program for assessment and is located east and downgradient of the landfill.
CCR-CCP-20D
Installed as a part of a separate program for assessment and is located east and downgradient of the landfill.
CCR-CCPBG-1D*
Installed to monitor background groundwater and is located southwest and upgradient of the landfill.
CCR-CCPBG-1BR*
Installed to monitor background groundwater and is located southwest and upgradient of the landfill.
CCR-CCPMW-8D
Installed as a part of a separate program for assessment and is located south and downgradient of the landfill.
CCR-CCPTW-2D
Installed as a part of a separate program for assessment and is located south and downgradient of the landfill.
CCPSW-1
Surface Water
Surface water monitoring location is south and upgradient of the landfill.
CCPSW-2
Surface water monitoring location is east and downgradient of the landfill.
CCPSW-3
Surface water monitoring location is west and downgradient of the landfill.
CCP-Leachate
Leachate
Leachate sample, representing leachate from Phases 1 and 2 of the landfill, collected from an in -line sampling point south
and downgradient of the landfill.
CCP-Leachate-34
Leachate sample, representing leachate from Phases 3 and 4 of the landfill, collected from an in -line sampling point south
and clowngradient of the landfill.
Page 1 of 2

TABLE 1
MULTI -MEDIA SAMPLING LOCATIONS
SEMIANNUAL WATER QUALITY MONITORING REPORT
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Monitoring Location ID
Media
Description
Installed for assessment and is located south and downgradient of the landfill, but was removed from the sampling
CCPMW-2D
network and is now used for water level measurements only.
Installed for assessment and is located south and downgradient of the landfill, but was removed from the sampling
CCPMW-3S
Water Level
network and is now used for water level measurements only.
Installed for assessment and is located north and downgradient of the landfill, but was removed from the sampling
CCPMW-6D
Only
network and is now used for water level measurements only.
Installed for assessment and is located south and downgradient of the landfill, but was removed from the sampling
CCPMW-8
network and is now used for water level measurements only.
Installed for assessment and is located south and downgradient of the landfill, but was removed from the sampling
CCPTW-2
network and is now used for water level measurements only.
Note:
See Table 2 Well Construction Summary for monitoring well construction information.
* - Background groundwater monitoring well.
Prepared by: TWL Checked by: ADW
Page 2 of 2

TABLE 2
SUMMARY OF WELL CONSTRUCTION INFORMATION
SEMIANNUAL WATER QUALITY MONITORING REPORT
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Well ID
Date
Installed
Flow Zone
Material
Diameter
(inches)
Latitude
(degrees)
Longitude
(degrees)
Well Depth
(ft, BTOQ
Screened
Interval
(ft, BGS)
Measuring
Point TOC
(ft, NAVD 88)
Ground
Surface
(ft, NAVD 88)
Groundwater
Elevation
(ft, NAVD 88)
Depth
to Water
(ft, BTOQ
CCPMW-1S*
2/23/2010
Deep
PVC
2
35.206702100
-81.774304900
42.45
30.0 - 40.0
875.58
873.24
839.61
35.97
CCPMW-1D*
2/24/2010
Bedrock
PVC
2
35.206713399
-81.774299699
56.95
49.0 - 54.0
875.89
873.33
839.24
36.65
CCPMW-2S
2/24/2010
Shallow
PVC
2
35.203550900
-81.772735000
44.30
32.0 - 42.0
842.24
840.26
804.45
37.79
CCPMW-2D#
2/24/2010
Bedrock
PVC
2
35.203552399
-81.772721900
72.80
65.0 - 70.0
842.38
840.17
803.06
39.32
CCPMW-3S#
6/27/2007
Shallow
PVC
2
35.203409300
-81.771019100
15.29
9.0 - 14.0
811.56
810.56
800.48
11.08
CCPMW-3D
7/16/2007
Bedrock
PVC
2
35.203408701
-81.771000500
35.41
26.0 - 31.0
811.74
810.47
794.67
17.07
CCPMW-4
10/26/2015
Bedrock
PVC
2
35.208929900
-81.774815100
68.31
50.0 - 65.0
845.95
843.29
820.24
25.71
CCPMW-5
10/23/2015
Bedrock
PVC
2
35.209926100
-81.772851900
75.42
62.5 - 72.5
858.63
855.87
819.26
39.37
CCPMW-6S
10/21/2015
Deep
PVC
2
35.208665599
-81.771117398
46.79
33.5 - 43.5
854.38
851.48
815.87
38.51
CCPMW-6D#
10/26/2015
Bedrock
PVC
2
35.208653899
-81.771102700
63.00
50.0 - 60.0
854.35
851.45
815.92
38.43
CCPMW-7
7/8/2020
Shallow
PVC
2
35.207790757
-81.769444485
51.07
37.0 - 47.0
855.49
852.63
<812.89
42.60 (TOP)
CCPMW-8#
7/6/2020
Shallow
PVC
2
35.203717021
-81.769460949
49.05
35.0 - 45.0
831.52
828.24
<788.82
42.70 (TOP)
CCPMW-10
7/7/2020
Shallow
PVC
2
35.203376929
-81.768415081
45.38
32.0 - 42.0
812.98
810.45
777.06
35.92
CCPMW-11
7/1/2020
Shallow
PVC
2
35.203812900
-81.766750379
33.75
20.0 - 30.0
803.32
800.24
778.39
24.93
CCPTW-2#
2/25/2010
Shallow
PVC
2
35.203862801
-81.770429800
45.00
35.0 - 45.0
842.18
839.62
<798.38
43.80 (TOP)
CCR-CCP-18S
7/7/2020
Shallow
PVC
2
35.204474503
-81.766895821
40.70
27.0 - 37.0
814.40
811.92
783.06
31.34
CCR-CCP-19S
10/22/2020
Shallow
PVC
2
35.205423748
-81.766866496
51.03
37.0 - 47.0
827.56
824.82
784.14
43.42
CCR-CCP-20D
10/23/2020
Deep
PVC
2
35.206198116
-81.766883691
77.11
64.5 - 74.5
841.05
838.61
787.60
53.45
CCR-CCPBG-1D*
7/17/2020
Deep
PVC
2
35.203856335
-81.775968875
50.74
43.0 - 48.0
889.28
886.26
844.25
45.03
CCR-CCPBG-1BR*
7/23/2020
Bedrock
PVC
2
35.203831869
-81.775968852
98.75
91.0 - 96.0
889.02
886.52
836.30
52.72
CCR-CCPMW-8D
7/17/2020
Deep
PVC
2
35.203709358
-81.769442879
78.60
70.0 - 75.0
831.11
828.06
781.46
49.65
CCR-CCPTW-2D
7/17/2020
Bedrock
PVC
2
35.203724991
-81.770155815
82.74
73.0 - 78.0
839.85
836.67
786.13
53.72
Notes:
Groundwater elevations are based on water level data collected during a Site -wide water level sweep on April 15, 2024.
* - Background groundwater monitoring well.
# - Well used for water level only.
< - Indicates the water level is below the top of the pump and unable to be gauged. The elevation represents the top of the pump.
BGS - below ground surface
BTOC - below top of casing
ft - feet
NAVD 88 - Vertical elevations in feet based on North American Vertical Datum of 1988.
PVC - polyvinyl chloride
TOC - top of casing
TOP - Value represents depth to top of pump. Water level below the top of the pump and unable to be gauged.
Prepared by: TWL Checked by: ADW
Page 1 of 1

TABLE 3A
SUMMARY OF GROUNDWATER CONSTITUENTS AND ANALYTICAL METHODS
SEMIANNUAL WATER QUALITY MONITORING REPORT
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Constituent
Analytical
Methods
Units
15A NCAC 02L
Standards for
Groundwater
In Situ Parameters
pH
Multi -Parameter Water Quality Meter
S.U.
6.5-8.5
Temperature
Multi -Parameter Water Quality Meter
degrees Celsius
NE
Specific Conductance
Multi -Parameter Water Quality Meter
µmhos/cm
NE
Dissolved Oxygen
Multi -Parameter Water Quality Meter
mg/L
NE
Oxidation Reduction Potential
Multi -Parameter Water Quality Meter
millivolts
NE
Turbidity
Turbidimeter
NTU
NE
Water Level
Water Level Meter
ft
NE
Laboratory Analyses
Antimony
EPA 200.8 / SW 6020E
µg/L
1
Arsenic
EPA 200.8 / SW 6020E
µg/L
10
Barium
EPA 200.7 / SW 6010D
µg/L
700
Beryllium
EPA 200.8 / SW 6020E
µg/L
4
Boron
EPA 200.7 / SW 6010D
µg/L
700
Cadmium
EPA 200.8 / SW 6020E
µg/L
2
Calcium
EPA 200.7 / SW 6010D
mg/L
NE
Chloride
EPA 300.0 / EPA 9056A
mg/L
250
Chromium
EPA 200.8 / SW 6020E
µg/L
10
Cobalt
EPA 200.8 / SW 6020E
µg/L
1
Copper
EPA 200.8 / SW 6020E
µg/L
1,000
Fluoride
EPA 300.0 / EPA 9056A
mg/L
2
Iron
EPA 200.7 / SW 6010D
µg/L
300
Lead
EPA 200.8 / SW 6020E
µg/L
15
Lithium
EPA 200.7 / SW 6010D
µg/L
NE
Magnesium
EPA 200.7 / SW 6010D
mg/L
NE
Manganese
EPA 200.7 / SW 6010D
µg/L
50
Mercury
EPA 245.1 / SW 7470A
µg/L
1
Molybdenum
EPA 200.8 / SW 6020E
µg/L
NE
Nickel
EPA 200.8 / SW 6020E
µg/L
100
Nitrate (as N)
EPA 300.0 / EPA 9056A
mg-N/L
10
Selenium
EPA 200.8 / SW 6020E
µg/L
20
Silver
EPA 200.8 or SW 6020A
µg/L
20
Sulfate
EPA 300.0 / EPA 9056A
mg/L
250
Thallium
EPA 200.8 / SW 6020E
µg/L
2
Total Dissolved Solids
SM 2540C / EPA 160.1 / ASTM D5907
mg/L
500
Vanadium
EPA 200.8 / SW 6020E
µg/L
7
Zinc
EPA 200.7 / SW 6010D
µg/L
1,000
Prepared by: TWL Checked by: ADW
Notes:
15A NCAC 02L Standard refers to Class GA Standards as found in 15A NCAC 02L .0202 Groundwater quality Standards, last amended on April 1, 2022.
µg/L- micrograms per liter
µmhos/cm - micromhos per centimeter
ft - feet
mg/L- milligrams per liter
mg-N/L - milligrams nitrogen per liter
NCAC - North Carolina Administrative Code
NE - not established
NTU - nephelometric turbidity units
S.U. - standard units
Page 1 of 1

TABLE 3B
SUMMARY OF SURFACE WATER CONSTITUENTS AND ANALYTICAL METHODS
SEMIANNUAL WATER QUALITY MONITORING REPORT
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Constituent
Analytical
Methods
Units
15A NCAC 02B
(Class WS-IV) Standards,
ISTV,
and USEPA Criteria for
Surface Water
In Situ Parameters
pH
Multi -Parameter Water Quality Meter
S.U.
6.0-9.0
Temperature
Multi -Parameter Water Quality Meter
degrees Celsius
<_ 29
Specific Conductance
Multi -Parameter Water Quality Meter
µmhos/cm
NE
Dissolved Oxygen
Multi -Parameter Water Quality Meter
mg/L
>_ 4
Oxidation Reduction Potential
Multi -Parameter Water Quality Meter
I millivolts
NE
Turbidity
Turbidimeter
NTU
Streams <_ 50
Laboratory Analyses
Antimony
EPA 200.8 / SW 6020E
µg/L
5,300$
Arsenic
EPA 200.8 / SW 6020B
µg/L
10
Barium
EPA 200.7 / SW 6010D
µg/L
1,000
Beryllium
EPA 200.8 / SW 6020B
µg/L
NE
Beryllium (dissolved)
EPA 200.8 / SW 6020E
µg/L
65A
Boron
EPA 200.7 / SW 6010D
µg/L
34,000#
Cadmium
EPA 200.8 / SW 6020B
µg/L
NE
Cadmium (dissolved)
EPA 200.8 / SW 6020B
µg/L
0.75A't
Calcium
EPA 200.7 / SW 6010D
mg/L
NE
Chloride
EPA 300.0 / EPA 9056A
mg/L
230
Chromium
EPA 200.8 / SW 6020B
µg/L
NE
Chromium (dissolved)
EPA 200.8 / SW 6020B
µg/L
180 ' X
Cobalt
EPA 200.8 / SW 6020B
µg/L
3$
Copper
EPA 200.8 / SW 6020B
µg/L
1,300*
Copper (dissolved)
EPA 200.8 / SW 6020B
µg/L
3.6A't
Fluoride
EPA 300.0 / EPA 9056A
mg/L
1.8
Iron
EPA 200.7 / SW 6010D
µg/L
1,000.
Lead
EPA 200.8 / SW 6020B
µg/L
NE
Lead (dissolved)
EPA 200.8 / SW 6020B
µg/L
14 't
Lithium
EPA 200.7 / SW 6010D
µg/L
NE
Magnesium
EPA 200.7 / SW 6010D
mg/L
NE
Manganese
EPA 200.7 / SW 6010D
µg/L
50*
Mercury
EPA 245.1 / SW 7470A
µg/L
0.012
Molybdenum
EPA 200.8 / SW 6020B
µg/L
160$
Nickel
EPA 200.8 / SW 6020B
µg/L
25
Nickel (dissolved)
EPA 200.8 / SW 6020B
µg/L
140A't
Nitrate (as N)
EPA 300.0 / EPA 9056A
mg-N/L
10
Selenium
EPA 200.8 / SW 6020B
µg/L
170*
Selenium (dissolved)
EPA 200.8 / SW 6020B
µg/L
3.1&
Silver
EPA 200.8 or SW 6020A
µg/L
NE
Silver (dissolved)
EPA 200.8 or SW 6020A
µg/L
0.30A't
Page 1 of 2

TABLE 3B
SUMMARY OF SURFACE WATER CONSTITUENTS AND ANALYTICAL METHODS
SEMIANNUAL WATER QUALITY MONITORING REPORT
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
15A NCAC 02B
(Class WS-IV) Standards,
Analytical
Constituent
Methods
Units
ISTV,
and USEPA Criteria for
Surface Water
Laboratory Analyses (Continued)
Sulfate
EPA 300.0 / EPA 9056A
mg/L
250
Thallium
EPA 200.8 / SW 6020E
µg/L
2$
Total Dissolved Solids
SM 2540C / EPA 160.1 / ASTM D5907
mg/L
500
Total Hardness
Calculation [2.497 (calcium) + 4.118
mg/L
100
(magnesium)]
Vanadium
EPA 200.8 / SW 6020B
µg/L
NE
Zinc
EPA 200.7 / SW 6010D
µg/L
7,400
Zinc (dissolved)
EPA 200.7 / SW 6010D
µg/L
36A,t
Prepared by: TWL Checked by: ADW
Notes:
15A NCAC 02B Standards for Class WS-IV surface waters. North Carolina surface water and wetland standards (effective September 1, 2022).
ISTV - In -stream target values established per 15A NCAC 02B .0202 and .0208.
USEPA Criteria - U.S. Environmental Protection Agency National Recommended Water Quality Criteria.
For 15A NCAC 02B Standards and ISTVs with acute and chronic criteria, the acute criteria are considered more applicable to grab sampling; therefore,
those values are presented.
$ - An exceedance of a published ISTV is not automatically a violation of the water quality standard for toxicity. Comparison value presented is the lesser
of the Aquatic Life & Secondary Recreation or Fish Consumption value, when applicable.
"- ISTV is based on acute sampling method described in 15A NCAC 02B (11)(e). Compliance with acute instream standard is not applicable to sampling
method. An exceedance of a published ISTV is not automatically a violation of the water quality standard for toxicity.
USEPA National Recommended Water Quality Criteria are not a regulation, nor do they impose a legally -binding requirement.
Therefore, comparisons with these criteria are for situational context.
Comparison criteria based on acute sampling method described in 15A NCAC 02B (11)(e). Compliance with acute instream standard is not
applicable to sampling method and provided for screening purposes only.
Hardness -dependent standard calculated using 25 mg/L hardness and not actual in -stream hardness value. Provided for screening purposes only.
Hardness -dependent standard for chromium III calculated using 25 mg/L hardness and not actual in -stream hardness value. Provided for screening
purposes only.
& - Selenium standard for lotic water based on a 30-day average. Not applicable to the sampling method and provided for screening purposes only.
>_ - greater than or equal to
<_ - less than or equal to
µg/L - micrograms per liter
µmhos/cm - micromhos per centimeter
mg/L - milligrams per liter
mg-N/L - milligrams nitrogen per liter
NCAC - North Carolina Administrative Code
NE - not established
NTU - nephelometric turbidity units
S.U. - standard units
Page 2 of 2

TABLE 3C
SUMMARY OF LEACHATE CONSTITUENTS AND ANALYTICAL METHODS
SEMIANNUAL WATER QUALITY MONITORING REPORT
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Constituent
Analytical
Methods
Units
In Situ Parameters
pH
Multi -Parameter Water Quality Meter
S.U.
Temperature
Multi -Parameter Water Quality Meter
degrees Celsius
Specific Conductance
Multi -Parameter Water Quality Meter
µmhos/cm
Dissolved Oxygen
Multi -Parameter Water Quality Meter
mg/L
Oxidation Reduction Potential
Multi -Parameter Water Quality Meter
millivolts
Turbidity
Turbidimeter
NTU
Laboratory Analyses
Antimony
EPA 200.8 / SW 6020E
µg/L
Arsenic
EPA 200.8 / SW 6020E
µg/L
Barium
EPA 200.7 / SW 6010D
µg/L
Beryllium
EPA 200.8 / SW 6020E
µg/L
Boron
EPA 200.7 / SW 6010D
µg/L
Cadmium
EPA 200.8 / SW 6020E
µg/L
Calcium
EPA 200.7 / SW 6010D
mg/L
Chloride
EPA 300.0 / EPA 9056A
mg/L
Chromium
EPA 200.8 / SW 6020B
µg/L
Cobalt
EPA 200.8 / SW 6020E
µg/L
Copper
EPA 200.8 / SW 6020B
µg/L
Fluoride
EPA 300.0 / EPA 9056A
mg/L
Iron
EPA 200.7 / SW 6010D
µg/L
Lead
EPA 200.8 / SW 6020E
µg/L
Lithium
EPA 200.7 / SW 6010D
µg/L
Magnesium
EPA 200.7 / SW 6010D
mg/L
Manganese
EPA 200.7 / SW 6010D
µg/L
Mercury
EPA 245.1 / SW 7470A
µg/L
Molybdenum
EPA 200.8 / SW 6020E
µg/L
Nickel
EPA 200.8 / SW 6020E
µg/L
Nitrate (as N)
EPA 300.0 / EPA 9056A
mg-N/L
Selenium
EPA 200.8 / SW 6020E
µg/L
Silver
EPA 200.8 or SW 6020A
µg/L
Sulfate
EPA 300.0 / EPA 9056A
mg/L
Thallium
EPA 200.8 / SW 6020E
µg/L
Total Dissolved Solids
SM 2540C / EPA 160.1 / ASTM D5907
mg/L
Vanadium
EPA 200.8 / SW 6020E
µg/L
Zinc
EPA 200.7 / SW 6010D
µg/L
Prepared by: TWL Checked by: ADW
Notes:
Leachate is not compared to water quality standards and is analyzed for the same constituents as groundwater (Table 3A).
µg/L - micrograms per liter mg-N/L - milligrams nitrogen per liter
.mhos/cm - micromhos per centimeter NTU - nephelometric turbidity units
mg/L - milligrams per liter S.U. - standard units
Page 1 of 1

TABLE 4
GROUNDWATER SEEPAGE VELOCITIES
SEMIANNUAL WATER QUALITY MONITORING REPORT
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Upper (Shallow and Deep) Flow Zone
Upgradient
Downgradient
Seepage
Groundwater
Groundwater
K
Oh
Distance
Effective
Well ID
Velocity
Elevation
Elevation
(ft/day)"
(ft)
(ft)
Porosity2
(ft/day)
(ft, NAVD 88)
(ft, NAVD 88)
CCPMW-1S to CCPMW-10
839.61
777.06
1.02
62.55
2135
0.20
0.149
Bedrock Flow Zone
Upgradient
Downgradient
Seepage
Well ID
Groundwater
Groundwater
K
Ah
Distance
Effective
Velocity
Elevation
Elevation
(ft/day)'
(ft)
(ft)
Porosity2
(ft/day)3
(ft, NAVD 88)
(ft, NAVD 88)
CCPMW-1D to CCPMW-6D
839.24
815.92
1.30
23.32
1188
0.05
0.510
CCPMW-ID to CCR-CCPTW-2D
839.24
786.13
1.30
53.11
1648
0.05
0.838
Prepared by: TWL Checked by: ADW
Notes:
1- Values used are a calculated geomean of hydraulic conductivities (K) in paired wells. K values are derived from slug test data presented in the Groundwater Monitoring Well Installation Report
(SynTerra, April 2021).
Z - Value taken from Updated Groundwater Flow and Transport Modeling Report for Cliffside Steam Station, Mooresboro, NC, December 2019 (SynTerra) .
s - Value represents an estimate of the velocity of groundwater through bedrock fractures.
Ah - difference in groundwater elevation between upgradient and downgradient locations
ft - feet
ft/day - feet per day
Groundwater elevations are based on water level data collected on April 15, 2024.
Hydraulic gradients and groundwater velocities are approximate.
NAVD 88 - North American Vertical Datum of 1988
Page 1 of 1

TABLE 5
FIELD DATA PARAMETERS
SEMIANNUAL WATER QUALITY MONITORING REPORT
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Sample ID
Sample
Date
Appearance
Odor
Purge
Method
Average
Pump Rate
(mL/min)
Temp
(Deg C)
Specific
Conductance
(µmhos/cm)
pH
(S.U.)
ORP
(mV)
Dissolved
Oxygen
(mg/L)
Turbidity
(NTU)
Groundwater
Elevation
(ft, NAVD 88)
Depth to
Water
(ft, BTOC)
Groundwater Parameters
CCPMW-1S*
4/16/2024
Clear
None
Bladder Pump
80
23
23
5.3
49
8.1
0.9
839.61
35.97
CCPMW-1D*
4/16/2024
Clear
None
Bladder Pump
100
19
55
5.5
55
7.0
0.8
839.24
36.65
CCPMW-2S
4/16/2024
Clear
None
Bladder Pump
120
20
47
5.2
151
7.0
6.1
804.45
37.79
CCPMW-3D
4/16/2024
Clear
None
Bladder Pump
180
20
94
5.5
112
6.3
0.1
794.67
17.07
CCPMW-4
4/16/2024
Clear with fines
None
Bladder Pump
60
22
189
8.0
27
2.0
2.2
820.24
25.71
CCPMW-5
4/17/2024
Clear
None
Bladder Pump
125
20
205
10.6
116
4.4
0.1
819.26
39.37
CCPMW-6S
4/16/2024
Clear
None
Bladder Pump
150
21
64
5.2
194
4.6
8.7
815.87
38.51
CCPMW-7
4/16/2024
Clear
None
Bladder Pump
100
29
82
5.5
200
5.2
9.4
<812.89
42.60 (TOP)
CCPMW-10
4/16/2024
Clear
None
Mega Monsoon Pump
500
19
48
5.0
30
6.5
8.4
777.06
35.92
CCPMW-11
4/16/2024
Clear
None
Peristaltic Pump
60
27
52
5.4
44
4.5
3.4
778.39
24.93
CCR-CCP-18S
4/17/2024
Clear
None
Bladder Pump
50
28
60
5.5
203
5.3
0.7
783.06
31.34
CCR-CCP-19S
4/16/2024
Clear with small particulates
None
Bladder Pump
100
25
285
5.2
136
6.1
5.5
784.14
43.42
CCR-CCP-20D
4/16/2024
Clear
Slightly musty
Bladder Pump
100
23
233
7.0
-70
0.4
0.3
787.60
53.45
CCR-CCPBG-1D*
4/16/2024
Clear with fines
None
Mega Monsoon Pump
160
22
73
5.3
244
7.3
4.6
844.25
45.03
CCR-CCPBG-1BR*
4/16/2024
Clear
None
Bladder Pump
100
19
879
8.1
108
3.0
0.5
836.30
52.72
CCR-CCPMW-8D
4/16/2024
Clear
None
Bladder Pump
100
21
300
6.4
169
0.6
0.3
781.46
49.65
CCR-CCPTW-2D
4/16/2024
Clear
None
Bladder Pump
1 140
1 19
1 131
1 6.6
1 -8
0.4
1 0.7
1 786.13
1 53.72
Surface Water Parameters
CCPSW-1
4/16/2024
Clear
None
Grab
NA
18
44
6.2
153
8.5
6.0
NA
NA
CCPSW-1
4/26/2024
Clear
None
Grab
NA
14
48
7.3
93
9.5
6.0
NA
NA
CCPSW-2
4/16/2024
Clear
None
Grab
NA
17
43
6.4
164
8.1
5.1
NA
NA
CCPSW-2
4/26/2024
Clear
None
Grab
NA
14
42
6.8
104
8.6
7.8
NA
NA
CCPSW-3
4/16/2024
NS
NS
NS
NA
NS
NS
NS
NS
NS
NS
NA
NA
Leachate Collection Parameters
CCP-Leachate
4/16/2024
Clear
None
Grab
NA
20
33,733
4.7
258
3.2
4.9
NA
NA
CCP-Leachate-34
4/16/2024
Clear
None
Grab
NA
21
3,679
6.5
250
3.2
8.3
NA
NA
Notes:
* - Background groundwater monitoring well.
Analytical data presented in this table reflect the Duke Energy Biological Analytical Data Storage System (BASS) as of 06/19/2024.
CCPSW-1 and CCPSW-2 surface water monitoring locations were resampled for total and dissolved metals only, so the field data parameters from both samples are provided.
CCPSW-3 surface water monitoring location not sampled due to dry conditions.
Water level data collected during a Site -wide water level sweep on April 15, 2024.
< - Indicates the water level is below the top of the pump and unable to be gauged. The elevation represents the top of the pump.
µmhos/cm - micromhos per centimeter
BTOC - below top of casing
Deg C - degrees Celsius
ft - feet
Prepared by: I WL Checked by: ADW
mg/L - milligrams per liter
mL/min - milliliters per minute
NA - not applicable
mV - millivolts
NAVD 88 - North American Vertical Datum of 1988
NS - not sampled
NTU - nephelometric turbidity units
ORP - oxidation reduction potential
S.U. - standard units
TOP - Value represents depth to top of pump. Water level below the top of the pump and unable to be gauged.
Page 1 of 1

TABLE 6
GROUNDWATER FIELD AND ANALYTICAL RESULTS
SEMIANNUAL WATER QUALITY MONITORING REPORT
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Parameter
ID
Monitoring Wells
MDL
SW
15A NCAC
SWS
Units
CCPMW-1S
CCPMW-1D
CCPMW-2S
CCPMW-3D
CCPMW-4
CCPMW-5
CCPMW-6S
CCPMW-7
CCPMW-10
CCPMW-11
CCR-CCP-18S
CCR-CCP-19S
CCR-CCP-20D
CCR-CCPBG-1D
CCR-CCPBG-1BR
CCR-CCPMW-8D
CCR-CCPTW-2D
GWPS
02L Standard
pH
320
S.U.
5.3
5.5
5.2
5.5
8.0
10.6
5.2
5.5
5.0
5.4
5.5
5.2
7.0
5.3
8.1
6.4
6.6
NA
NE
6.5-8.5
Temperature
325
Deg C
23
19
20
20
22
20
21
29
19
27
28
25
23
22
19
21
19
NA
NE
NE
Specific Conductance
323
µmhos/cm
23
55
47
94
189
205
64
82
48
52
60
285
233
73
879
300
131
NA
NE
NE
Dissolved Oxygen
NE
mg/L
8.1
7.0
7.0
6.3
2.0
4.4
4.6
5.2
6.5
4.5
5.3
6.1
0.4
7.3
3.0
0.6
0.4
NA
NE
NE
Oxidation Reduction Potential
336
mV
49
55
151
112
27
116
194
200
30
44
203
136
-70
244
108
169
-8
NA
NE
NE
Eh
NE
mV
254
260
356
317
232
321
399
405
235
249
408
341
135
449
313
374
197
NA
NE
NE
Turbidity
330
NTU
0.9
0.8
6.1
0.1
2.2
0.1
8.7
9.4
8.4
3.4
0.7
5.5
0.3
4.6
0.5
0.3
0.7
NA
NE
NE
Antimony
13
µg/L
0.129 J
0.123 J
< 1
< 1
< 1
0.522 J
< 1
< 1
< 1
0.184 J
< 1
< 1
< 1
0.127 J
0.153 J
0.566 J
< 1
0.104
NE
1
Arsenic
14
µg/L
<1
<1
0.145J
<1
0.729J
5.28
0.134J
<1
<1
<1
<1
<1
0.341J
<1
0.962J
0.61J
<1
0.111
NE
10
Barium
15
µg/L
22
17
33
26
13
3 J
42
42
55
37
27
183
4 J
31
4 J
27
< 5
2
NE
700
Beryllium
23
µg/L
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
0.249
NE
4
Boron
428
µg/L
7J
8J
12J
42J
6J
191
<50
<50
<50
<50
10.1
9J
7J
<50
9J
8J
<50
5
NE
700
Cadmium
34
µg/L
<1
<1
<1
0.106J
<1
<1
0.032J
<1
<1
<1
<1
0.062J
<1
<1
<1
<1
<1
0.032
NE
2
Calcium
375
mg/L
0.181
2.80
2.59
9.58
27.6
21.6
1.74
5.05
1.91
2.32
3.52
21.1
18.5
3.60
33.3
11.2
10.3
0.012
NE
NE
Chloride
301
mg/L
4.4
8.1
2.6
5.6
1.6
4.7
4.6
11
5.9
5.2
6.5
71
11
9.0
98
27
6.0
0.0154
NE
250
Chromium
51
µg/L
0.692 J
0.321 J
4.19
1.12
0.436 J
4.36
2.68
0.909 J
1.80
0.944 J
0.662 J
1.24
0.24 J
2.29
2.12
0.787 J
< 1
0.185
NE
10
Cobalt
53
µg/L
1.31
0.3 J
0.938 J
0.087 J
< 1
< 1
1.51
0.086 J
1.46
0.184 J
0.245 J
0.681 J
< 1
0.872 J
< 1
0.08 J
< 1
0.077
NE
1
Copper
54
µg/L
< 1
< 1
1.72
0.909 J
< 1
1.32
< 1
< 1
1.03
< 1
0.952 J
1.36
< 1
< 1
< 1
1.47
< 1
0.787
NE
1,000
Fluoride
312
mg/L
<0.1
<0.1
<0.1
<0.1
0.15
0.1J
<0.1
<0.1
<0.1
<0.1
<0.1
<0.5
0.05J
<0.1
0.1J
0.08J
0.11
0.0479
NE
2
Iron
340
µg/L
39J
9J
450
4J
121
54
321
49J
274
94
13
166
1,170
306
27J
17J
2,020
4
NE
300
Lead
131
µg/L
0.274 J
< 1
0.395 J
< 1
0.06 J
0.149 J
0.205 J
0.038 J
0.303 J
0.22 J
0.065 J
0.178 J
< 1
0.142 J
< 1
0.042 J
< 1
0.037
NE
15
Lithium
NE
µg/L
<5
<5
<5
<5
3J
<5
<5
<5
<5
<5
<5
<5
3J
<5
12
<5
31
2
NE
NE
Magnesium
376
mg/L
0.712
1.47
1.93
2.21
1.16
0.294
2.08
1.99
1.89
1.96
1.74
12.6
1.53
2.27
2.08
2.23
1.91
0.008
NE
NE
Manganese
342
µg/L
21
7
42
6
13
3J
39
21
21
16
5J
108
64
33
15
27
41
1
NE
50
Mercury
132
µg/L
< 0.05
< 0.05
< 0.05
< 0.05
< 0.05
< 0.05
< 0.05
< 0.05
0.03 J
< 0.05
< 0.05
< 0.05
< 0.05
0.02 J
< 0.05
< 0.05
< 0.05
0.01
NE
1
Molybdenum
397
µg/L
< 1
< 1
< 1
0.209 J
8.73
1.72
< 1
< 1
< 1
< 1
< 1
< 1
1.25
< 1
16.0
5.47
0.866 J
0.18
NE
NE
Nickel
152
µg/L
0.607 J
1.18 J
2.29
< 1
0.338 J
1.38
2.74
0.944 J
1.16
2.35
0.869 J
4.60
0.652 J
1.95
1.96
0.902 J
< 1
0.256
NE
100
Nitrate (as N)
303
mg-N/L
0.04 J
0.39
1.3
1.2
0.01 J
0.64
3.2
2.1
1.8
1.4
2.1
3.6
0.01 J
3.6
0.43
2.0
0.04 J
0.002
NE
10
Selenium
183
µg/L
<1
<1
0.556J
0.262J
<1
0.22J
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
0.193
NE
20
Silver
184
µg/L
<1
<1
<1
<1
<1
0.085J
<1
<1
<1
<1
0.143J
0.493J
<1
<1
0.196J
<1
<1
0.035
NE
20
Sulfate
315
mg/L
0.51
1.4
6.1
17
13
17
2.5
0.43
0.22
0.46
0.60
1.1
24
0.46
140
33
17
0.0428
NE
250
Thallium
194
µg/L
< 0.2
< 0.2
0.051 J
0.042 J
< 0.2
< 0.2
0.119 J
0.057 J
0.061 J
0.055 J
0.049 J
0.089 J
< 0.2
0.067 J
< 0.2
< 0.2
< 0.2
0.041
NE
2
Total Dissolved Solids
311
mg/L
< 25
36.0
29.0
58.0
119
91.0
34.0
64.0
41.0
37.0
43.0
2,670
120
54.0
435
146
89.0
25
NE
500
Vanadium
209
µg/L
< 1
< 1
0.961 J
< 1
0.233 J
8.44
0.462 J
0.146 J
0.446 J
< 1
< 1
0.41
< 1
0.42 J
0.732 J
2.59
< 1
0.114
NE
7
Zinc
213
µg/L
5J
5J
<15
<15
<15
<15
5J
<15
<15
5J
<15
8J
5J
4.1
<15
<15
<15
4
NE
1,000
Notes:
Bold and Gray highlighted concentrations are equal to or greater than the 15A NCAC 02L Standard (or outside the 02L Standard range for pH).
15A NCAC 02L Standard refers to Class GA Standards as found in 15A NCAC 02L. 0202 Groundwater Quality Standards, last amended on April 1, 2022.
Analytical data presented in this table reflects the Duke Energy Biological Analytical Data Storage System (BASS) as of 06/19/2024.
CCPMW-1S/D and CCR-CCPBG-1D/BR are background groundwater monitoring wells.
Samples collected by Pace Analytical personnel on April 16-17, 2024.
<- Concentration not detected at or above the adjusted reporting limit.
J - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
MDL- Laboratory Method Detection Limit; MDL values presented are for samples not diluted by the laboratory during analysis.
SW GWPS - Solid Waste Groundwater Protection Standard
SWS ID -Solid Waste Section Identification Number
µg/L - micrograms per liter
µmhos/cm - micromhos per centimeter
Deg C - degrees Celsius
mg/L- milligrams per liter
mg-N/L- milligrams nitrogen per liter
mV - millivolts
NA - not applicable
NCAC- North Carolina Administrative Code
NE - not established
NTU - nephelometric turbidity units
S.U. - standard units
Prepared by: TWL Checked by: ADW
Page 1 of 1

TABLE 7
FIELD AND ANALYTICAL RESULTS EQUAL TO OR GREATER THAN GROUNDWATER QUALITY STANDARDS
SEMIANNUAL WATER QUALITY MONITORING REPORT
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Parameter
Sample ID
April 2024
Concentration
Units
15A NCAC
02L Standard
Historical
Concentration Range
Cause and Significance
pH
CCPMW-1S
5.3
S.U.
6.5 - 8.5
4.4 - 5.5
pH is consistent with the range of historical readings at CCPMW-1S.
CCPMW-1D
5.5
4.4 - 5.6
pH is consistent with the range of historical readings at CCPMW-1D.
CCPMW-2S
5.2
4.4 - 5.6
pH is consistent with the range of historical readings at CCPMW-2S.
CCPMW-3D
5.5
5.2 - 5.6
pH is consistent with the range of historical readings at CCPMW-3D.
CCPMW-5
10.6
10.0 - 11.0
pH is consistent with the range of historical readings at CCPMW-5.
CCPMW-6S
5.2
4.6 - 5.8
pH is consistent with the range of historical readings at CCPMW-6S.
CCPMW-7
5.5
4.7 - 5.8
pH is consistent with the range of historical readings at CCPMW-7.
CCPMW-10
5.0
4.5 - 5.2
pH is consistent with the range of historical readings at CCPMW-10.
CCPMW-11
5.4
5.3 - 5.8
pH is consistent with the range of historical readings at CCPMW-11.
CCR-CCP-18S
5.5
4.7 - 6.1
pH is consistent with the range of historical readings at CCR-CCP-18S.
CCR-CCP-19S
5.2
5.0 - 5.5
pH is consistent with the range of historical readings at CCR-CCP-195.
CCR-CCPBG-1D
5.3
5.1- 5.5
pH is consistent with the range of historical readings at CCR-CCPBG-1D.
CCR-CCPMW-8D
6.4
6.4 - 8.4
pH is consistent with the range of historical readings at CCR-CCPMW-8D.
Cobalt
CCPMW-1S
1.31
µg/L
1
0.6 - 10.7
Cobalt is consistent with the range of historical concentrations at CCPMW-1S.
CCPMW-6S
1.51
1.95 - 10.3
Cobalt is less than the range of historical concentrations at CCPMW-6S.
CCPMW-10
1.46
0.28 J - 2.5
Cobalt is consistent with the range of historical concentrations at CCPMW-10.
Iron
CCPMW-2S
450
µg/L
300
4.05 J - 1,310
Iron is consistent with the range of historical concentrations at CCPMW-2S.
CCPMW-6S
321
105 - 1,390
Iron is consistent with the range of historical concentrations at CCPMW-6S.
CCR-CCP-20D
1,170
NA
This is the first monitoring event where iron was analyzed at CCR-CCP-20D.
CCR-CCPBG-1D
306
54 - 530
Iron is consistent with the range of historical concentrations at CCR-CCPBG-1D.
CCR-CCPTW-2D
2,020
NA
This is the first monitoring event where iron was analyzed at CCR-CCPTW-2D.
Manganese
CCR-CCP-19S
108
µg/L
50
NA
This is the first monitoring event where manganese was analyzed at CCR-CCP-195.
CCR-CCP-20D
64
NA
This is the first monitoring event where manganese was analyzed at CCR-CCP-20D.
TDS
CCR-CCP-19S
2,670
mg/L
500
45.0 - 175
TDS is greater than the range of historical concentrations at CCR-CCP-195.
Vanadium
CCPMW-5
8.44
µg/L
7
7.54 - 17.1
Vanadium is consistent with the range of historical concentrations at CCPMW-5.
Notes:
Historical ranges are based on all applicable data in Duke Energy Carolinas, LLC (Duke Energy) analytical results database and previous reporting. Historical ranges exclude sample data with turbidity values greater than 10 NTUs.
Analytical data presented in this table reflects the Duke Energy Biological Analytical Data Storage System (BASS) as of 06/19/2024.
15A NCAC 02L Standard refers to Class GA Standards as found in 15A NCAC 02L .0202 Groundwater Quality Standards, last amended on April 1, 2022.
µg/L - micrograms per liter
J - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
mg/L - milligrams per liter
NA - not applicable
NCAC - North Carolina Administrative Code
NTU - nephelometric turbidity units
S.U. - standard units
TDS - total dissolved solids
Prepared by: TWL Checked by: ADW
Page 1 of 1

TABLE 8
SURFACE WATER FIELD AND ANALYTICAL RESULTS
SEMIANNUAL WATER QUALITY MONITORING REPORT
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Parameter
SWS ID
Units
Surface Water
Sample ID
MDL
15A NCAC 02B
(Class WS-IV)
Standards, ISTV,
and USEPA Criteria
CCPSW-1
CCPSW-1
(Resample)
CCPSW-2
CCPSW-2
(Resample)
CCPSW-3
pH
320
S.U.
6.2
7.3
6.4
6.8
NS
NA
6.0-9.0
Temperature
325
Deg C
18
14
17
14
NS
NA
<_ 29
Specific Conductance
323
µmhos/cm
44
48
43
42
NS
NA
NE
Dissolved Oxygen
NE
mg/L
8.5
9.5
8.1
8.6
NS
NA
>_ 4
Oxidation Reduction Potential
336
mV
153
93
164
104
NS
NA
NE
Eh
NE
mV
358
298
369
309
NS
NA
NE
Turbidity
330
NTU
6.0
6.0
5.1
7.8
NS
NA
Streams <_ 50
Antimony
13
µg/L
< 1
< 1
< 1
< 1
NS
0.104
5,300$
Arsenic
14
µg/L
0.241 J
0.215 J
0.231 J
0.222 J
NS
0.111
10
Barium
15
µg/L
24
22
24
22
NS
2
1,000
Beryllium
23
µg/L
< 1
< 1
< 1
< 1
NS
0.249
NE
Beryllium (dissolved)
23
µg/L
NA
< 1
NA
< 1
NS
0.249
65^
Boron
428
µg/L
6 J
9 J
< 50
111
NS
5
34,000"
Cadmium
34
µg/L
< 1
< 1
< 1
< 1
NS
0.032
NE
Cadmium (dissolved)
34
µg/L
NA
< 1
NA
< 1
NS
0.032
0.75�'t
Calcium
375
mg/L
2.54
2.43 J
2.71
2.54 J
NS
0.012
NE
Chloride
301
mg/L
3.6
NA
3.7
NA
NS
0.0154
230
Chromium
51
µg/L
0.506 J
0.307 J
0.601 J
0.43 J
NS
0.185
NE
Chromium (dissolved)
51
µg/L
NA
< 1
NA
0.305 J
NS
0.185
180^'"
Cobalt
53
µg/L
0.311 J
0.291 J
0.397 J
0.28 J
NS
0.077
3$
Copper
54
µg/L
1.33
< 1
< 1
< 1
NS
0.787
1,300
Copper (dissolved)
54
µg/L
NA
< 1
NA
< 1
NS
0.787
3.6A't
Fluoride
312
mg/L
< 0.1
NA
< 0.1
NA
NS
0.0479
1.8
Iron
340
µg/L
1,140
1,100
1,140
1,010
NS
4
1,000*
Lead
131
µg/L
0.242 J
0.204 J
0.327 J
0.199 J
NS
0.037
NE
Lead (dissolved)
131
µg/L
NA
< 1
NA
0.119 J
NS
0.037
14A't
Lithium
NE
µg/L
<5
<5
<5
<5
NS
2
NE
Magnesium
376
mg/L
1.28
1.20
1.33
1.25
NS
0.008
NE
Manganese
342
µg/L
44
43
53
41
NS
1
50*
Mercury
132
µg/L
< 0.05
< 0.05
< 0.05
< 0.05
NS
0.01
0.012
Molybdenum
397
µg/L
< 1
< 1
< 1
< 1
NS
0.18
160$
Nickel
152
µg/L
0.42 J
0.327 J
0.467 J
0.363 J
NS
0.256
25
Nickel (dissolved)
152
µg/L
NA
0.391 J
NA
0.288 J
NS
0.256
140^'t
Nitrate (as N)
303
mg-N/L
0.41
NA
0.45
NA
NS
0.002
10
Selenium
183
µg/L
< 1
< 1
< 1
< 1
NS
0.193
170*
Selenium (dissolved)
183
µg/L
NA
< 1
NA
< 1
NS
0.193
3.1&
Silver
184
µg/L
< 1
0.063 J
< 1
0.055 J
NS
0.035
NE
Silver (dissolved)
184
µg/L
NA
< 1
NA
< 1
NS
0.035
0.30A't
Sulfate
315
mg/L
1.4
NA
1.7
NA
NS
0.0428
250
Thallium
194
µg/L
<0.2
<0.2
<0.2
<0.2
NS
0.041
2$
Total Dissolved Solids
311
mg/L
26.0
NA
32.0
NA
NS
25
500
Total Hardness
NE
mg/L
11.6
11.0
12.2
11.5
NS
NA
100
Page 1 of 2

TABLE 8
SURFACE WATER FIELD AND ANALYTICAL RESULTS
SEMIANNUAL WATER QUALITY MONITORING REPORT
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Surface Water
15A NCAC 02B
Sample ID
(Class WS-IV)
Parameter
SWS ID
Units
MDL
CCPSW-1
CCPSW-2
Standards, ISTV,
CCPSW-1
(Resample)
CCPSW-2
(Resample)
CCPSW-3
and USEPA Criteria
Vanadium
209
µg/L
0.482 J
0.399 J
0.599 J
0.413 J
NS
0.114
NE
Zinc
213
µg/L
< 15
< 15
< 15
< 15
NS
4
7,400
Zinc (dissolved)
213
µg/L
NA
< 15
NA
< 15
NS
4
36"t
Prepared byTWL Checked by: ADW
Notes:
Bold and Gray highlighted concentrations are equal to or greater than the applicable 15A NCAC 02B Standard (or outside the 02B Standard range for pH and equal to or less than the 02B Standard for
dissolved oxygen). Concentrations greater than non -applicable screening criteria are only bold.
Analytical data presented in this table reflect the Duke Energy Biological Analytical Data Storage System (BASS) as of 06/19/2024.
Samples collected by Pace Analytical personnel on April 16, 2024. Total and dissolved metals were resampled for on April 26, 2024.
CCPSW-1 surface water monitoring location is upgradient of the CCP landfill.
CCPSW-3 surface water monitoring location not sampled due to dry conditions.
For constituents with acute and chronic criteria, the acute criteria are considered more applicable to grab sampling; therefore, those values are presented.
15A NCAC 02B Standards for Class WS-IV surface water. Water quality standards applicable to Class C waters also apply to Class WS-IV waters. North Carolina surface water and
wetland standards (effective September 1, 2022).
$ - An exceedance of a published ISTV is not automatically a violation of the water quality standard for toxicity. Comparison value presented is the lesser of the Aquatic Life & Secondary
Recreation or Fish Consumption value, when applicable.
# - ISTV is based on acute sampling method described in 15A NCAC 02B (11)(e). Compliance with acute instream standard is not applicable to sampling method. An exceedance of a
published ISTV is not automatically a violation of the water quality standard for toxicity.
USEPA National Recommended Water Quality Criteria are not a regulation, nor do they impose a legally -binding requirement. Therefore, comparisons with these criteria are for situational context.
Comparison criteria based on acute sampling method described in 15A NCAC 02B (11)(e). Compliance with acute instream standard is not applicable to sampling method and provided for
screening purposes only.
t - Hardness -dependent standard calculated using 25 mg/L hardness and not actual in -stream hardness value. Provided for screening purposes only.
`- Hardness -dependent standard for chromium III calculated using 25 mg/L hardness and not actual in -stream hardness value. Provided for screening purposes only.
& - Selenium standard for lotic water based on a 30-day average. Not applicable to the sampling method and provided for screening purposes only.
<- Concentration not detected at or above the adjusted reporting limit.
>_ - greater than or equal to
<_ - less than or equal to
µg/L - micrograms per liter
µmhos/cm - micromhos per centimeter
Deg C - degrees Celsius
ISTV - In -stream target values established per 15A NCAC 02B .0202 and .0208.
J - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
MDL - Laboratory Method Detection Limit; MDL values presented are for samples not diluted by the laboratory during analysis.
mg/L - milligrams per liter
mg-N/L - milligrams nitrogen per liter
mV - millivolts
NA - not applicable
NE - not established
NS - not sampled
NCAC - North Carolina Administrative Code
NTU - nephelometric turbidity units
S.U. - standard units
SWS ID - Solid Waste Section Identification Number
USEPA Criteria - U.S. Environmental Protection Agency National Recommended Water Quality Criteria
Page 2 of 2

TABLE 9
LEACHATE FIELD AND ANALYTICAL RESULTS
SEMIANNUAL WATER QUALITY MONITORING REPORT
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Parameter
SWS ID
Units
Leachate Sample ID
MDL
CCP-Leachate
CCP-Leachate-34
pH
320
S.U.
4.7
6.5
NA
Temperature
325
Deg C
20
21
NA
Specific Conductance
323
µmhos/cm
33,733
3,679
NA
Dissolved Oxygen
NE
mg/L
3.2
3.2
NA
Oxidation Reduction Potential
336
mV
258
250
NA
Eh
NE
mV
463
455
NA
Turbidity
330
NTU
4.9
8.3
NA
Antimony
13
µg/L
0.661 J
0.786 J
0.104
Arsenic
14
µg/L
13.2
1.56
0.111
Barium
15
µg/L
401
61
2
Beryllium
23
µg/L
1.17 J
< 1
0.249
Boron
428
µg/L
21,200
4,190
5
Cadmium
34
µg/L
2.12 J
0.033 J
0.032
Calcium
375
mg/L
7,510
654
0.012
Chloride
301
mg/L
15,000
370
0.0154
Chromium
51
µg/L
1.59 J
0.634 J
0.185
Cobalt
53
µg/L
670
2.77
0.077
Copper
54
µg/L
44.0
3.33
0.787
Fluoride
312
mg/L
< 20
0.26 J
0.0479
Iron
340
µg/L
640
26 J
4
Lead
131
µg/L
99.2
0.184J
0.037
Lithium
NE
µg/L
4,470
16
2
Magnesium
376
mg/L
52.9
65.4
0.008
Manganese
342
µg/L
13,600
143
1
Mercury
132
µg/L
0.02 J
< 0.05 J
0.01
Molybdenum
397
µg/L
669
25.3
0.18
Nickel
152
µg/L
118
2.68
0.256
Nitrate (as N)
303
mg-N/L
12
1.4
0.002
Selenium
183
µg/L
72.2
34.0
0.193
Silver
184
µg/L
0.182 J
0.496 J
0.035
Sulfate
315
mg/L
840
1,200
0.0428
Thallium
194
µg/L
11.6
0.089 J
0.041
Total Dissolved Solids
311
mg/L
23,900
247
25
Vanadium
209
µg/L
4.23 J
3.16
0.114
Zinc
213
µg/L
1 186
5 J
4
Prepared by: TWL Checked by: ADW
Notes:
Samples collected by Pace Analytical personnel on April 16, 2024.
Comparative criteria are not applied to leachate collection samples.
Analytical data presented in this table reflects the Duke Energy Biological Analytical Data Storage System (BASS) as of 06/19/2024.
<- Concentration not detected at or above the adjusted reporting limit.
J - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
MDL - Laboratory Method Detection Limit; MDL values presented are for samples not diluted by the laboratory during analysis.
Deg C - degrees Celsius
µg/L - micrograms per liter
µmhos/cm - micromhos per centimeter
mg/L - milligrams per liter
mg-N/L - milligrams nitrogen per liter
mV - millivolts
NA - not applicable
NE - not established
NTU - nephelometric turbidity units
S.U. - standard units
SWS ID - Solid Waste Section Identification Number
Page 1 of 1

Semiannual Water Quality Monitoring Report —April 2024 Sampling Event
Rogers Energy Complex—Cliffside Steam Station —CCP Landfill Phases I through IV (Permit No. 8106-INDUS)
Mooresboro, North Carolina
APPENDIX A
FIELD CALIBRATION LOGS AND SAMPLING FORMS
410
synTerra
Science & Engineering Consultants

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Document Name: Field data Sheet
Date Issued: March8, 2019'
I Page: I of 1
Document Number:F•CAR-FLD-0O1zev.Q3,
Issuing Aathoritys Pace Huntersvitld Quality
Office
i ld Dat Sheep
Client, , Location?:_ Prafeck#:(1
Name and Affiliation Field Data Sheet Review:
5
Name and Affiliation (Inspector): '�`- � /� 4 / 2� Y SK R � ��
Date: B :
Well Information 4 13-0 1 ZK
Well ID: =W - a5 Well Locked: YE / NO / Plushmount )
Well Diameter: �o1/, Construction: P /Steel/Stainless Steel)
Total Well Depth: 1r'1 L,30 ft MuIN Pastor*�� r(Rad us/1�2)2x3.14 x 7.asl
Static Water Level::57 iD�Y�� ft Casing Volume:_ gallons
"�
Height of Water Column: eft Cal, 3 Volumes:: ��� � �i gallons
Pump Intake: I It
Fur - Information „ L 15y tS �I nI� -1(po5
Date Purged; /� StarY : ggt}tis Purge Rate: 04I �A \n
7p Zvi In 4 N
Purging Method: •2 (DQIW Total Volume Purged: *ii ff000 (gallons ails L)
Sarn lin Information I l9 1 0
Date Collected:_ t- /-U-A Time Collected; _ (an
r p�ii t)
T)10 Ito
Sampling Equipment Used: /— no]InstrumentID:L ` l * V,q 0 3
Bottle Type Preservation Analysis Require
Field Measurements/Observations ��� j�
Sample Temp (eC): i Time: Ill I - _Turbidity (ntu): i Time: ( V 1 t-/
Diss Oxy (mg/L); 7. Li Time: Fe 2+ mg/L: Time. n 10
Specific Cond. (uS):14(6 , 8 Time: Res. Cl /(� I
(mg�//L)/(µg/L): Iune: �
Sample pH (s.u.): �=No �r _ Time: Odor:_. o Time: � �Q
ReDox (mV): 66. If Time; Appearance: Time: 100
ReDox (EH value):YSI ProPius +200mV ,350-�C'—Other: Time:
General/Weather Observations:
(sunny cloudy rainy) Temp. (°F) Wind (mph)
Sampler Signature: ZI -iG�— Date:
Stabilization Test
.
Volume
IV-6 . i 7 i D HG�-b 51 a ILA53 9 0 300e--3 37,

p�
EM7Fl ICAf
Document Noma FiOd data Sheet
Data Issued: talamb 8, 2019
Document Number:F-C,AR-rLD-001-rev.03
y: ac1ofi
tss'tta AutGoxit!'are Huntersvipe Quality
OEfire
Field Data Sheet /� �
Client Q �� �t"� LocationM 19ja22n & C Project #(_ ) Ws C - F 1�A 1
Name and Affiliation (Sa--plex(s): T� D ` (� Field Data Sheet Review: (U ) I
Name and Affiliation (Impector): C41z yl/m y 5 � %
Watt Inf irmation Date I )01 Lk1 By' McV_
Static
Heigl,
Puree
Date I
Samnli
Date Cc
Samplir
'1
?3D Well Locked: YE / NO / Flushmount )
ieter: Construction: PV /SteelfStalnlessSteel)
Depth: 3 5A �ft Multi Fa ctor*o r(IWjus/12)2 x and x 7 aei
=r Level; t (y L—it Casing Volume: � • � gallons
Nater Column:l632 ft CaL 3 Volumes 4 • C � gallons
Pump Intake: 33
armation
Start:) L'I q () Finfshl r� Purge Rate:
` Ilo 2N
ethod: I e � �idQ Total Volume Purged: I {gallm s ails, L)
information -0
(,�
'tPrI / I �/ a 1 Time Collected, f I () '..
Diss Oxy (mf
�jf(A.�1� (a�
zment Used: Instrument 1D: � i No w rFrWgW13
ype Preservation Analysis Required
aent's/IIO\\bservations r
C): ll Time* Turbidity (ntu): Time;
Time: Fe 2+ mg/L:_._N __Time:.
us): Time: Res. 0 (mg/L)j(µg/L): Time, _Time: Odor: . r Time: r! ✓' "
C! .� Time:, Appearance: _UQ�Time: ! r
Le)NSIProPlus+200mV Other: Time:
er Observations:
(sunny/ ou /rainy) Temp. (*F) Wind (mph)
are: Date:
•st
Time
Teemp.
Diss Oxy.
Spec.
Cond.
pH (s.u.)
ReDox
Turbidity
Volume
rentou_
Water
Other
Purged;
(C)
(mg/L)
{u)
(nV)
(ntu)
(gallons �mis
level(ft)
L
t
. 1
0Q
ICJ
.0
%
�'
P,C
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Document Name: Field dataghaet
Date lssng March &, 2Q19.
f ricat °
Ta a; a of 2
eAnah
Document Number: P-CAR-ELM-01-xev.0
wdfagce H`unteasville Quality
attice
Field Data Shei
Client: V iA� e ei U Location 5 e f LProject #: C1-5 C.0 p L F PeFrmi+ A prfl
Name and Affiliation (Sampler(s): U CM —Pa C.Q_< Field Data Sheet Review:
Name and Affiliation (Inspector), NIA
fomon �� Date: N�3olzy By:
Well Int�rL
well ia.TP w — Well Locked: Yli- NQ / Flushmourtt }
Well Diameter: �, l"M Construction: PVC,Steel/Stainless Steel)
Total Well Depth., G00 3 it Multi Factor*,��r(Aad wj 12)2x 3J4 x 7.481
Static Water Level: 2 5,7aft Casing Volume: 0,9H •.__ gallons
Height of Water ColummA �g✓ � ft Cal. 3 Volumes 90
// "Z3 gallons
Pump Intake: � 6 ft
Purge Information 6H6 Date Purged:-t" _/_� G /� Start;�_ Flnishi_� Forge Rate: 60 �tlltil
Purging Method:XctotaK� BAD _Total Volume Purged: 2-760 : (gallons/gXL)
SamplingIuformation
Date Collected:_//i Time Collected: 1 550(amy/� pm0` r
Sampling Equipment Used: NA kC P OKP Instrument ID: Y 6-� i Y6�1J
Bottle Type Preservation Analysis Required
iio1��2 �I�"---
Field Measurements/Observations
Sample Temp CC) 02, Time:_
Diss Oxy (mg/L): �1,0 Time: _
Specific Cond. (us): Time: _
Sample pH (s.u.): _ _ Time:
ReDox (mV):.. , --7. 0 Time:
ReDox (EH value)NSI ProPlus.+20QmV d
Generalf Weather Observations
Test
Turbidity(ntu); a.a Time: i550
Fe 2+ mg/L-. N, D - Time: 1550
Res. Cl (angf L)/(ltgf L}:—'iaue:
Odor: _AL-D-._.:�Time: Lr 5.0._
Appearance: CI& W '4te$ Time: 1 "150
Other: Time:
a
Time
Temp.
Diss Oxy.
Spec.
Cond.
pH (s.u.)
ReDox
Turbidity
o ume
removed
Water
Omer
Purged
(C)
(mg/L)
(US)
(mV)
(ntu)
(gallons Is
level (ft)
L
05
.G
I L-3
M,5
73
2- ,L1
73;G7
300
94,6
o
�:
' .
7-3
a5 ,33
C61
a
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o;
5
a7
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7,7
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ALL
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1900
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l�c
DocuutegE Name:
Field Data Sheet
Document lssoed: Maxcli &, M9
Pagealof 2-
/,�Ir""&Arralj?/Csif
DoenmeiitNuniUer:
(sspeirlg Avthoriky,
FCAR-FItD-M.IICV,03
?ace Huntersville Quality Office
DL^
U f� Client: F-Aer@
Location: moo (-64oml
p 1,
Project; CI-S ppC E 1-F I e- mi+ 6� n 12M
Well1D: CCiI'lVV'-1
Reviewed Date and By: z 14 ! 2 % �i_PkV
StalihlationTest 4130�21t MCP-
[Veil Diameter
1
1.2 `
1.625
.2
3
4
6
8
Multiplication Fa.Ctox'�
O.OAO$
6.0918
6.0s0
01630
0.36770
f1:6�30
1A680
2.6,100
Time
Purged
Temp,
(o i
DissOxy,
(mg/L)
Spec.
Cond
f uS}
pH (s.u,j
ReDox (mVj
.ur
Turbidity T
(ntuj
Volume Removed
m s
(gallons Lj
circle one
Waterleuel-
level
(ftj
Other
1530
a2;5
a, :
10,A
773
0,S
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Document Mane: Field data Sheet
Date Issued: March & 2Ri9
Page; I 7
aCeAnafytiCa7
of
lkxuntent Numb r: F-CAR-ff117-00'L3ev.03
Issuing AntBordy: Pace Huntersvitle Quality
Office
t
Field Data Sheek
Client: uu/0 LS Location: � ei _ t
,�• Projeck#•C S_ c oc;� A.f/ena7
Name'and Affiliation (Sampler(s}; ��/% ✓�� Data Sheet Review:
Soy
Name and Affiliation (inspector): -4-�—
r-�P2q
Well Information
jField
Date: 4 l;a f z4 By, �
We11ID: �S•- GGi�� �S
Well Locked:/ NO / FIushmount)
Well Diameter: 2
Construction:teel/Stahtless Steel)
' 3
Total Well Depth: �[_£t
141ultiFactor':_ r(gad;us/12)2x344x7481
Static Water Level: Sf • S-0 ft
Casing Volume: 5 gallons
Height of Water Column: d a-9 it
Cat. 3 Volumes: S gallons
Pump Intake: y�4 - �7 ft
Purgelnformation
D M, A, a I (o �t St t
��5�� - "��, z✓+/
1 `f)
a e rge / / ar . mts i, urge Rate.
Purging Method: 7 d P pµ I p Total Volume Purged: % 7 l (gallons nls L)
Sampling Information
Date Collected: t f /L(,/ L_
_
Time Collected: 1q ��' (am
Sampling Equipment 3--c0106
AvI tnstrumentID: � 41q i�`/
Bottle Type
Preservation Analysis Required
Field Measurements/Observations
Sample Temp (°C}:
._Turbidity (ntu): 5-- _? Time:
Diss Oxy (mg/): ct Time:
Fe 2+ mg/L: 0 Time:
Specific Cond. (uS):; Time:
Res. Cl (mg/L)/(gg/L): " Time:
Sample pB(s•u.): �'2 Time:
ReDox(mV): I �`1'2 Time:,.
Appearance: G4/W rime:
ReDox (EH value)NSl ProPlus +2OOmV 3
Lf %- Other: Time:
Generalf Weather Observations:
(sunny ou rainy) Temp. 57_(°F) Wind 0"i0 (mph)
Sampler Signature: //1 /
Date
Stabilization Test
Spec.
Vo utiie
Time
Purged
Temp.
(C)
Diss Oxy.
(mg/L)
Co
pH (s u.}
ReDox
ReDox
(mV)(gallons
removed y
nls)/
Water
level(£t)
Other
(US)
L(ntu)
ILf30'
7 i
G
-7(7,g
-� -
�i2z'
-7S P
6
I Lf �Y
2 l• y
k
z
2 2,1.
(yam 67
170
39--Fr0
ItI1b
71•
�1;�
G-
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i�150
22 sD
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N fs s
1,97__
1�, x
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1estrkvytical
Document Name: Field data Sheet
Date Issued: March 8, 2019:
page: 1 of :z_
Document Number: F-CAAM.q-001-rev.Q3
issu ng AuthoxRy: Pace Hmrtexsville Quality
.Office
Field Data Sheet - xy
Client: Project #: Fc
Name and Affiliation (Sampler(s): %�� ��
Field Data Sheet Review:
°'t
Name and Affiliation (Inspector): /U0 �
'qi 2 / 24
Information �i• y
7
Date: By: MCI? —
y 13v I z:K
Well ID:' i 4 — G(/°/i' W-
Well Locked: M51
NO / Flushmount )
Well Diameter: L
Construction: (/ Steel/Stahiless Steel)
Total Well Depth: �i / 0 7 It
Multi Factor*:041�3 C(Radius/12)2x3,14x7481
Static Water Level:�ft
Casing Volume 1 gallons
Heiglltof WaterCalutnn: ft
Cal.3 Volumes:%(`_gallons
Pump intake: I& $ 5 7 ft
Euro IInformatian
Date Purged,�_/�/ � 4 Start:
�1
/� FinishlZzO �M < Purge Rater
Purging Method: p6/JyCY1 %Ra Pvi /
Total Volume Purged: `i �� d (gallons/, 11. /L)
Samiriling Information
Date Collected:_ _/
Time Collected: ,z�� (am/
Sampling Equipment Used:0 402gY NO
w MP Instrument ID:
Battle Type ;
Preservation Analysis Required
Field Measurements/Observations
Sample Temp (,q: 74-`� Time.
z L 5 Turbidity (ntu): Time % zy
Dias Oxy (mg/L): j Time.
Fe 2+ mg/L: ✓i Time:
p�
Specific Cond. (uS): I�f I _ Time:
Res. CI (mg/L)/(pg/L): Time:
Sample pH (s.u.):' S Time:
n—
Odor: it//J Time:,
ReDox (mv): ZD(%' t Time:
Appearance: C_ / ""Time:
ReDox (EH value):YSI ProPlus +200mVOther: Time:
General/Weather Observations:
_ /cloudy/rainy) Temp.c67— ff) Wind K 117(mph)
um1Date:_
Sampler Signature
V
_
Stabilization
Test
Spec.
Volume
Time
Temp,
Diss Oxy.
Con d:
pH (s.u.)
ReDox
Turbidity
removed
Water
Other
Purged
(C)
(mg/L)
( .
(mV)
(ntu)
(gallons/ i s
L'
level (ft)
11)v
11
5
011,;'
i x,b''
I
s
—
11
Zfe,
III T_I
2_ (_
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5
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Docu wnt.Nanla: r?ucament Issued MMarel)8,;2pt9
Field Data Sheet 2.
r1C2ff€tcfi/yi%C�?/; Pase�•o€
Document Number. Issuemg AuthbriW,
F-CAR-FLD-0Ql.rev.o3 Pace Huntersvi le QuaRLY O€€iee
,% � G''/ CLS
�W�t'y� Client: /
Location;
Project: CC.O t J- c�
�Yf
Well ID: 6L5— ( CGPIMw _ -7
Reviewed Dote and By: (L1 f'z
stabilization Test L io 1,2-q NEE (Z
We;llL>iatrreter'
1•2
1.b25
3_
4
6
$ ''
:vhkltx
licatisrnFactaY"
�.�.
T
0.0918
_
0.1080
01630
03670
04530
14680
2,6100
Time
Purged
g
Temp.
(°Ci
Diss Oxys
fmg/Lj
Spec`
Cond,
(us}'
pN (s.u.j
ReDOX (mV}
Turbidity
(ntu}
-Volume Removed
(gallons/ Is/
circle, o
Water level'
fftl
Other'
1-00
)..,
25n 4
7
r • b
I % 2
_ /
�%) `
!?lap

azgnatnYe
,�
�—�i'®
Datec 4
- l 1p ' J-`1
tibh Test
Spee. '
volume
T �mp.
Disc-4xg
Cond:
pH (s.u.)
ieDox
(MV)
Turbidity
(OU)
removed
(gallons/it/
Water
liwel (ft)
Other.
9.(
Tp
+o:
4
�.,
239.7:
zso
s 5'
19. 1
7 O
sl.
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507 0
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boapmQrstlssued^ Marcti S, 2mg
Docuntegt Name.
Field 315eet
c�Artalyticr?!'
Data -
Page�o€_a"
Dotumerit Number::
Iasueing Avtbority:
F-t dR-FLD OQl.rev.63
PWHunterStgUe Quality Office
-Ivan [ $tex
Multiplikativn Factor*
Client:
14 Et&-5
1
o0408
Location:
Nloclre5M0ro,,AJC-
1,2.
Q0918
1.625
fl.lt}8Q
Projectt
CLS C c e LF PC(-4
y
�amf t A'j YCI l Z flsl
2
4.Ift9U
Well ID:
C`CPMw 1t7
&�o
4.:
0.65iQ
ReVieWed Date and ey: r Z
�' S('W
6
1,4680
RabitizationTest 5�3� L��
(' !
8
2.6100
Time
Temp.
Diss Qxy.
Speq.
Turbidity
a
Volume R ued
Water level
Purged
f°C)
(mg{L)
Codd�,
pH (s.u.)
ReDoR (mV)
(ntu}
(gallons n%L)
MY
Other
(us)
circle:one
isNY
1"1'•1
4
4 9� 3
;.F
3i7.D
14•8
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1
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•
_Llo�ryms�[e-mail] da SM-et:
bate Issued; rarch& 3kii9
I Pa
��ei9flnlylrCal
I7a4pment Namh4P F-�titt-k}.t}y-�-r@Y•03 ''
1�icuvg A4thun"tg.�'ace Ht�s�rersvr7Y�¢4a}itY
Field DatajSHeist.
/�
Client.,�V��t GV @t�c
t
LOCAhOn' �S a!eS6Of G PrQJeet :C.t C1 e
Name=arid Affili'ation(Sampler(sj
ME2-(CI ce � Field Data:Sheet Review:
htame and A011iation (Inspectery;
Date By:
?�s2M
TiVelTliiforination '
3 /
r
1M
VYellID: G( PMW
WellLo%ICed:/2ifE?fPltiluiiourt)
Well Diameter: _
Cotvstruction: (J�SteeT/Stainless Steel)
Total WeUDepth ., 3315
ft MuniFacto e lL3.plrtadiva/ivxs.lkx7.asl
Static Water Level: 2 4 • I`t ft C asing'Volume J. N 7 ` gallons, ,-
lief hto£WaferColuYtSrt p 1
ft Cdl.3-VpIupies: 1 gallons
Pump IniaT " 3 i
Purge Information
t l I J.H
Bate Fttrged:�,/t}�La / -
t
Stan: i 2 51' FlWshs i 3 (� Purge Rate: t�
PurgingMethod: t • s 1 .l Z
e��'total Volume Purged: i �2-� o (gallons,/Qs L)
Saig ingliformation
Date Collected: / a H
Tinfg Collected, i 3 Z z) (am/ ),
Sampling Equipment Used: s F �W &--f instrument ID: ` S l(
Bottle Type
Preservation Analysis Required
l�ukQ ICtk
Field Measurements/Observations
Sample Temp (°C): Time: i 3 2 a Turbidity (ntu): I `i ' Time: i 3 2. o
Diss Oxy (mg/l,)z 4.5
Time: i 3 2 0 Fe 2+ mg/i : ^J b Time: l 3 � D
Specific Fond. (uS)i Sl- Je
Time: 1 3 10 Res. Cl (mg/L)/(µ8/h)- �Time: `®
sample PH (s.u.): $, i
Time: 3 20 Odor: i�� ; Time: 1 3 o
WeDox (mY): y ), to Time. i 3 2 0 Appearance: c( e ti r "rime: L3 z D
2eDox (} H vahze):YSI ProPlus.+2OOmV 2L 3: - Other: Time:
seneral/Weather Observations:CIS r re ckar% . G c lZ. E is -ro. re ; j o, here e f S 0 0
(Ndi /cloudy/rainy) Temp. YD (T) Wind (mph)
iampler Signature Date: 4- t u- I H
Stabilization Test
volume
Time Temp. Diss Oxy,. Spec. I;eDox_ Turbidif removed Water
Purged (sC) (mg/L) (ond pH (sx.) (mv) (nta) Y (gallons/ level (Et) Other
_Y,�
13i3'
2- (>
4.5,
_S2,L
1
ya.a
I 3S
I zn•o.A
t.3i 6 ,
2b1
Vol
L

��eAtlaa(yticaF"
�°c�+mgnf tVpme: Field data $heel
Date.iesued: HlaxdiA MO. . .
Ea e::1 et1
Bacument t+Iuml~ier P'CIkR-E[.i��lcev�Ri
lasuing Authrnnly: ceH�mtetavilte�uality
�
Client:-'brtiILw E n&-Yy
,E riertow..
ethod: TotaIVolumePurged: (gallons/m]s/L)
gL#ormation
FIeId Measurements/Observationa
iample Temp (°C)t t 1 b Time:; 1 13 Turbidity (ntu): . a Time: (/ 3 9
7iss Oxy (mg/L): 3 . 2 Time, Fe 2+ mg/I !V Time:
ipecifiic Cond. u&j Time: Res. Cl (mg/Ly(µg�I j: Time: `
iample pNQ H Time: I l 3 9
ieDox (inV); 2 S 9 •9 Time: Appearance: G I E� f Tune:
IeDox (EH value)NSI FroPius 42nQmV" 4 S °j' © Other: Time:
Seneral/YYeather Observations:
(sunn. loudy/rainy) Temp. 4n (°F) Wind S' I`� (mph)
iarn r$!&nature:RY 5 4 /2,d
itabilization Test
Tune
Purged
Temp:
Co
Dissdxy.
(mg/L)
Spec.
Cond `
(US)
pH(s)
u
ReDox
(md)
Turbidity
(ntu) ,
Volume
removed
(gallons/mis/
L
Water
level (ft)
Other
e8 4/1Z
12, V.

C�Ana4fta1'..
Downtgat Nome: Fiedi data8deet
Date Iss4ea; Mired 8,-2kt1 "
pogg:IOf_l
u9�ent Numder� P-BAR-E[.p-0Ql-rev: .
IN"ihS A4tdorifpzPa jiee te�Mi ioua'4lity
Field Data. Sheek
Client: 9atcf- (AOel-f Locaflon: mo6,4C6orot,u� Project#:
r (4 LCP I F__PirM: f S s+�; n�
Name and Affiliation (Sampler.(# & k
fb-L 9
Aeld Data, Sheet Review:
Name°and Affiliation (inspeetor}: h( l A
��yy
/ 2 9/ K O> Y-�
Well Information
Date 13Al2it ilp: pttiZ
Well n La-"-k * -3 `{
_.
Well Locked: 1 E5
(, �-PIByskmotttt }
Well Diameter: —
Construction: (Pvr/1tael�&Wnless Steal)
Total Well Depth: ft
1GlultiFactor*: �-- [�aalus/I2)zxs.l4x.T.aa1
Static Water Level:' --._ ft
Casirtg Volume: c=== gallons
Height of Water Column: �, ft
Cai.3volumes: gallons
Pump Intake: ft
Purge in€ormallon
_
Date PurgedStart,
Finish:' -Purge Rate:
Purging Method -'-----
Total volume Purged: -- (gallons/mis/L)
Samplinglnformation
DeteCallectad: y /1 k 111
Time Collected: 1140 (�pm}
Sampling Equipment Used:
TnstrumentID: i y � ibq/T�r 60
Bottle Type
Preservation Analysis Required
Field Aftasurements(Obaervations
Sample Temp (°C): Z D Time:;
DissOxy(mg/L): 3 Z Time;
Specific Cond. (uS): 6 %,�{_ Time:
SainplepH(s.u.):_ _ _Timer
Re-Dox (mV): 2 h 0 • N Time;
ReDox (EH value):YSI PraPlus+200mv_
.Turbidity (ntu): g. 3 Time; t f N 9
Fe 2+ mg/L: N Time:
Res. Cl (mg/LY(ug/L): Lime:
nay" OJnAP f1'fJ
D. 4 tlth�ri
Tune. _
Time: -�
Time
Purgec€.
Temp.
(°C)
(m /L),
(mg/L)
Spec.
p
Cond.
PH (s.u.)
geDox.
(mV
Turbidity
(ntu}
o ume
removed
(gallons/mis/
L
CNater
level (ft}
Other

�
;17ocpment Name: Field data Sheet
date Issued: March k 2014
Page; I of,
CAIk'l1,yUCaf�
Issuing#ut(uixity" aceHtmtersvilldQuaiity
t
Document Number, F-CAR-S[1)-041-reu.43
.. ....Office
Static'
Heigh
Ra Yiooce..+n r....0
ffiliation (Inspector):
ation
,I_ -ap- I CIS
�f
x: t/
2pth:51103 It t
LeveLTUI�� 43,3'-44 t
tter Column:7, b� it E
z
ration
Date Furged:'�_..,/�/ I Start :.I
Forging Method:
SarnplingInfor
Date Collected:
Sampling Equipr
'... Iauciu uUw ancct ncvjcw. S
rn / rvu/ riusnmounrl
PV. Steel/Stainless Steel)
:�• 1�n3 V0kadlus/12)2x3.14�x7r181
re: gallons
W. gallons
Bottle Type Preservation
Field Measurements/Observations
Sample Temp (eC): Time: Turbidity (ntv)�: y�F
miss Oxy (mg/L): rr� aa Time: Fe 2+ mg/L, a U it
Specific Cond. (uS):Time: Res. Cl (ing/Lu(µW
Sample pH (s.u.): r Time. Odor:_
ReDox (mv): Time: Appearance:% ill
ReDox (EH value):YSl ProPlus +2OOmv Other:
General/Weather Observations:
sunn /cloudy/rainy) I
Sampler Signature: r� Date:
Stabilization Test
i (gallontl/rpls/L)
am
Analyais Required
2Ke (o ),Inn(_Q. i
r
7 Time; OD
'Time.1
Time,
Time:
e ! ime:
Time:
p_ - ff) Wind- (mph)
Spec.kReDoxTurbidity
Volume
Time
Temp.
Diss Oxy-
Cond:,
pH (s.u.)
remo
Water
Other
Purged'
(C)
('rig/L),
(uS}
(gallo .mis
level(ft)
L
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.G
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"
Document Name:
Field Data Sheet
Document Issued: March 8; 2019
page2nf A
Document Number:
lssueutgAuthority:
F CAR FL.D 001.rev.03
pace Huntersville Quality Office
Client, D,,KQ Et ks� 1
v
Project: t-//.1
Location' t� tirr-��-���'CI�✓��
—c&
Well ID: CCU ' CCP -Iqs
Reviewed Date and By: dal;A/z r/, -,)Pk)
Stabilization Test 4130124 AE L
SNrzll Diameter
Multiplication Factor"
1
00408
1.2
0.0418
1.623
0.1030
2
0A630
3
0.3670
4
0.6530
6
1,4660
8
2.6100
e sTurbidity
li circle one
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Datelsaved: (vTareh 8, 2014
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Document Numt�er.F-CAR-ELD-001-mv:03
IxsnLig Authm[ty:l+ace Hanteasvi(id QaalBY
b
Field Data Sheet gene:/E4
Well IDLC R _1 G Q Lo 0
WPi1 nfaniatar• Z e '\
Total Welt Depth: 7 7 . (j. ft MuIti Factor D ) b° 3 madiue/i"2)ixmwgal
Static Water Level; 53, u y ft Casing Volume: . S 10 gallons
Height of Water Column; .3. 6 6 ft Cal. 3 Volumes: gallons
Pump Intake: � 7` �S' ft
Start; 1 Z Zh Pittr'sh;;_I_sPurge Rate: 19 i S /m ;
Total'Volume Purged: 6 00 (gallowi ,)
Sampling Information
Date Collected: N J I b J Z Time Collectedi l i'3O (am{
Sampling Equipment Used: BIdd ee/ t' ^^t' Instrument ID: `� Rio 5 a /T �✓ bi 8l�
Bottle Type Preservation Analysis Required
Field,Measurementj
__ nervations
Sample Temp (C)r
!�• 5 Time:
13 3 Turbidity (ntu),• 9 , -3 Time; 1 3 3 -0
Diss Oxy (mg/L):
O' q Time:
Fe 2+ mg/L: N D Time:
Specific Cond. (uS):
2-32, Time:
Res: Cl_-
Sample pH (s u.):
7 ' 9 _ Time:
Odor:
`
ReDox (mV): — 70 AA Time;
¢94gbi:y
Appearance:/—
ReDox (PH value):YSI ProPlus +2Q11mV
) J9 . ,oOther: Time
General/Weather Observations:
(sunny/ oud •airy) Temp. (°F) Wind 5 - ( gmph)
Sampler Signature:
Ryan VI X5
Date: `i
Stabilization Test
Spec.
Volume
Time
Temp.
Diss Oxy.
Cond.
pH (s.u.)
ReDox
Turbidity
removed
Water
Other
Purged
(C)
(mg/L)
(uS)
(mV)
(ntu)
(gallons) Us
level (ft)
L
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DuemnentIssued,:Mardi'%?019
acaAnalytical'
Fieic} Data Sheat
Page Lof 2
DoeuMmtNumber.
Issuein :Aatbority,
F CAR PLD-M.wv.O&
pace 14i ntercv le Quality Office
Time
Temp.
Diss €7xy.
Spec.
Cand.
pH (s:u.)
ReDox (mv,}
Turbidity
Volume Removed
(gallons/ l)
Water level
Other
Purged
(�C)
(mgO }
(uS},
(ntu}
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Daument N=e,, Field data Sheet
Date Issued: March S, 2019-
AV eAtw4flCAt
Page: 1 of
Dueument Numtmr. F-CAR-FI.D-001-rev.03
Issuhig Authority: PaceHuntersvllle Quality
Office
Field Data Sheet
Client: Duae. E-Grgy Location: 1400,060"Z14C project#:LtSfGPLF
Name and Affiliation (Sampler(s): b g face Field Data Sheet Review:
Name and Affiliation (Inspector): N A Date:'l B : 5
Well Information +� 301 z'q y Mt)L
Well ID:tGR (-( PrAv✓ Well Locked, YES O / Flushmoustt )
Well Diameter: It., a Steel/Stainless Steel)
T6141Well Depth: 724a.(n0 it Multi Factor*:0,1, ("(Radius/12)2x3.14x7.48i
Static Water Level: 144. & D R Casing Volume: `f .7 7- gallons '
Height of Water Column: 2'l •o 0 It Cal,3 Volumes; 14.16 gallons
Pump Intake: 7 b ft
Purge Information
Date Start: ) 40" Finish: 1415 Purge Rake: `09AVA . I
Purging Method: gt—Je qArnP
Total Volume Purged: 1500 (gallons/U L)
Sampling Information
Date Collected: N f lk% 14
Time Collected: 1 42O (am/ tr
Sampling Equipment Used:
?4 r F Instrument ID: Y 1 t o S 6 0k 1 T ow b o a 4
Bottle Type,
Preservation Analysis Required
Field Measurements/Obser0ationa
Sample Temp (C): j_r _b Time:
I N 2 0 Turbidity (mu): 0,3 Time: 14 L0
Diss Oxy (mg/L): 0. b Time:
Fe 2+ mg/L: N Tune: It -
Specific Cond. (uS):' 3 o0' 4 Time:
Res. CI (mgJL)/(itg/L): I itne:
Sample pH (s.u.): b 4 _- _ Time:
Odor:_'
ReDox (mV): I (7 •7 Time:
4
1 Appearance: Ltea Time:
ReDox (EH value):YSI ProPlus`-+200mV
3 [7
rb.'? Other: Time:
General/Weather Observations:
(sunny(cloud ainy) Temp. 9'1 (T) Wind o' S (mph)
Sampler Signature: Rye.n' 4by a i
Date: 4116 (zN
Stabilization
Test
Spec.
Volume
Time
Purged
T qmp:
(C)
Disc Oxy.
(mg/L)
Cond.
(uS)
pH (s.u:)
ReDox
(mV)m1s
A;r,eed
WaterOther
level (ft)1
lag
o 1
4•b
IbRa'
44.71
b�P
20.s1
0.7
11.6
6. S
113
4I410
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Document Name: Field data Sheet Date Issued; March S, 2014im
pn e: 1 of
06Cf1Ikly7iC&/" : Wuir%Authority:PaceHimtersvilieQuality
Document Number. F-CAR F[.D-Oo13ev.0.3 Q
f fice
tt // _ Field Data Sheet {j
Client V I` U Location: Project # C r C ("(A A r e
Name and Affiliation (Same (s): 12 Pield Data Sheet Revlew: 5)per (� N
biome and Affiliation (Inspector): u
!zK(Zu
Well Infortnation Date ti 1 30) Zt1 By MC-1i2.
Well ID: (M —Q f 1W — �) D Well Locked: Cyi 5 / NO / Flushmoumt )
Well Diameter: 1 ( Construction:((PV Sfeel/Stein%ss Steer)
Total Well Depth: Multi Factol' �C/(RadiueJY2}z x3.id x y.ael
Static Water Level:,_ft Casing Volume:7 � 5 gallons
I-Iefght cif Writer Cotumn:_Q"ft Cal.3 Volumes:
Q � - gallons
Pump Intake: C1O ft
Pur a Information c�
Date Purged: �/ t/�",, ll ��Si1tart:pfihr) CI) Finish: J J� Purge Rate:_ /V0 /M 5 ij j IA
Purging Mefhod`,Dq_,B�SV TotalY%olumePurged:7700 (gallon n /L)
Sampling_Information
Date Collected.A_/((Q/-J!j_, Time Collected: t�_ Q_ pm)
Sampling Equipment Used: DA 6Q 0 (a Pam' instrument ID: S / ) C 23
Bottle Type Preservation Analysis Ifequired
Field Measurementps/Observations
Sample Temp (°G); Eq '_Time (� Turbidity (ntu): Time: 1100
Diss oxy: (mgx): _4 `Dime: ' Fe 2+ mg/L: . t Time: l 1 C) O
Spec
c . on . (uS )., Tune. Res. Cl kinglyL�Agg/L): Iune:
Sample pH (s.u.): (9 Time: Odor:: N �J--- Time: , (' ) Q
ReDox (nkN): r � Time: Appearance: C (Qw Time: 110 0
ReDox (PH valme):iSI ProPlixs t200mV . 19 •I�� Other: Time:
General/WeatherObservations:.F T! Y1�f� (ttr CCY" II CVSL("<
unny cloudy/rainy) Temp.(°F) Wind (mph)
Sampler Signature: —y4 ydaA- Date-Vr%/gw
Stabilization Test U M
Time
Temp.
Diss Oxy.
Spec
Cond:
pH (s.u)
ReDox
Turbidity
o uine
remov
Water
Other
Purged'
(C)
(tng(I)
(us) -
(in
(ntu)
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level (ft,)
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Docunent Name:
Field Data Sheet
Doemnent Issued: Marc) 8, 2019
Page2of
Document Number:
Issueing Authority:
r-
P CAR-FIi)-([M,rev.03:
Pace Huntersville Quality Office
Diameter .)VIUltiplication Factor"
Client: j� t 1 0.0403
Location: S�nCy�(i, +�n 1.2 0.0418 —
Project: CL, _.0 C L— { ��t^i t}� �� U, 1 2 0.1630
Well ID: l_LK _ Cr '�4i;_ t�l� 3 0.3670
4 0.6530
Reviewed Date and By: "/ 12 u 2 $PLV 6 1.4630
Stabilization Test LA3o12N MERL 8 2:6100
Time
Purged
Temp.
e
(0
-IF —o
Diss Oxy.
(mg/L)
Spec.
Cond':
(US)
pH (s u.)
ReOox (mV)
Turbidity r
(ntu)
Volume Re oved
(gallon ml A)
circle one
Water level'
(ft)
other
10 5
6— 5'
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to.CP
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isiame-'ana arnnanon inampiertsj;.j t.,�y 0 Utf- YWIcl vafa-Sheet!{evieW.: OLv 0� 1
Name and Affitiation (lnspectbr); \ 17ate: j `Z. 12 u %
Well Tn 61 natio
Welf lm:`: - tr - v Well Ldckeil Y133' f lrt0 f Sh�itPllnf) �*
Well Diameter: 1 t1 Construction: C feel/StaiatessSteel)
Total Well Depth: ft ix2nib Factor*_ ((I;adius{i�}zx3.7a x 7 as]
Static Water Level: Casing Volume: C),5(Q gallons
Height of Water Colu�Yu : 3.y 6 ft Cal. 3 Uolumes:.gallons
Pump intake: Hq .50 ft
Purge Information
Data / Start: iai5 Fiiah: Pi,rgebate: � O�LNA
PurgingMeth'od: 1WIO�I�fYOi\-Total Volume 0�f (gallons ms L)
Sampling Inf irr a io f' /
Date Collected: i er oZ A� Time Colloeted;: 3�0 (am
i �' y
Sampling Equipment Used; 2 I. 1V OV1S000 Instrument ID: Y,5 0 V V Ti 1-56 5
Bottle Type Preservation Analysis Required
POKL- -
Field rM asurme—MWObservations
Sample Temp ( q � Time:. 1310 Turbidity (ntu); A Time: 3l
Diss Oxy(mgm): 73 Time: _1 -3i�Fe 2+ mgft: I V Timer
Specific Cond. (uS): % Z Time: 1310 Res. Cl (nWL)f(µg f L): lime: +
Sample pH(s,u.):�—Time: NO Odor: NDTime:_J)'3�_�_
ReDQx (mv.), aH 33 Time: 31�D Appearance: C� W 6Time:
ReDox (iH value):YSI ProPlus +200rnVRN 3 •-I Otixer: 11 Time:
Genera}/WeatilerObservation"s: A co IA Vv ' b(adder.A ylj
WVD-S e CGR unn cloudy/rainy/) Temp.`�3—(T, Wind s-IO (mph)
Sampler5ignature:IZ?A- Date:
Stabilization Test
Spec. Volume
Time Temp: Diss Oxy. ReDox Turbidity removed hater
n IVOM IO(IN (»,afT Cond. pH(s.tl.) r,»�7\ r»,nv1

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DocuotentName::-;'
Field Rata Sheet
tissugd:Marcfi$,?019
Page2of 9
DucumetttNixutber;
lsaueingAvtharity;
F-CAR-FLD-001.rev.03
Pace Hunteieviliequality Office
�-
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Client: u �L
Di
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1
O.Q40$
Location: M0orE6
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1.625
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0.1630
W611IM cc �—CCPBC,
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3
0.3600
4
orsTrU
Reviewed'DateandBy:
6
1.4680
Stabilization Test
4i3oj2`l Mte-(Z
$ :
2,6100
Time
Temp.
Diss sexy,
Spec.
Cond.
pH (s.u.j
ReDox (MVj
Turbidity
Volume Removed
(gallons 13 Lj
Water level -
Other
Pinged
f`iCi
(mg/L)
(us)
fntuj
circle one
(ft)
q739`
0
AR
Mo
5,3
23S,5
10,7
5660
�55
3,0
5,3
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93
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300
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❑bcumehki �e Rtelil date Sheet
.. date4lsau�d; IeiarCh8,2al9f
of a
Dpcumenk hTNmtrer KAR-E[15-U41.rQv;Q3
FgAuthor<tp. aceHunteEBvii}eZ1up7[ty
Sampling Equipment Used:.? 6AAO-i - GtYi''1 F1 instrument ID: n* I V a I # 15�j5
Bottle Type Preservation Analysis1equired
Duke k,'3-
Field Measuremer[ts[0bservationa
Sample Temp(°C}r1L ___Time,. Twbidity(ntu): �, Time:
Dins OxY,(mg/I.}: 3.0 Time: 1050 Fe 2+ mg/L- 9 D -TUne: _ .j 5D
Specific Bond. (uS): _S79 Time:: 1050 Res. Cl (mg/L)/(µg/L): !: Time.
Sample pH (&U.): qi,i __Time:. Id50 Odor:__Time:
ReDox (my): 1072 Time: 1050 Appearance: 'Time:
ReDox (BH value):,YSl. ProPlus +200mV 3Q= ©they: Time:
General%Weather Ohservations:
fs� cloudy/rainy)/ Temp.7 _ (°F) Wind (mph)
Sampler Signature:__
Stabilization Test
Spec' Volume
Time Temp. Diss Oxy. Cond. Hsu. ReDox Turbidity removed Water
Purged CC) (mg/L un p (' ) (mU) (nw). (gallons/ s level (ft} . Other
10 7. 30 5 53.
Du 3,'a- 5 ,5 1 5005
73 V. 33 �yry� 25.• 1 I 3
a0 � 7 1) 3 i 0 53
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Doeuatent Name::
Field Data Sheet
Document lmued: Mawh 8,�2659
Pageaof
c?
DcxuatentNumlSex:
tssueing-Antharity:
�fG9°�fTii�yilf
F-CAR Ff Drow.mv.03
Pace Huntersvifle Quality Office
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Document blame: Field date Sheet
Date issued: March &, 201,
Page. 1 of
co R{ytl'Caf
Document Number. F-CAR-Ft.i'J-0Ql-reu.Q3
Iasubig Authamty: PaceHuntecsville Quabty
(�_
Office
Field Data Sheet
CIient:,�aKe E ^�r9y Location: Muo.L46o.c41M(
Projert#: LCQUn; F Apr. 2a2�
LLrj (t7
Name and Affiliation(Sampler(s): RMA
PaLP
PieldData SheetReview: 5{IlV
Name and Affiliation (Inspector): ht
(t
k/ Zif / 2 k
Well Information
Date; , 4 ) 3o 1 Z4
WellII3: tGP
Well Locked: (Yt;'R/�Ta1O1F1Flushmotmt)
Welt Diameter:
Construction: (PVC74P elf Stainless Steel)
Total Well Depth: fE
Multi Factorl r—O(Wius/12)2x3l: x7481
Static Water Level: " �ft
Casing Volume: -- gallons
Height of Water Column ft
Cat 3 Volumes: — '.gallons
Pump Intake: �' it
Purge Information
Date Purged; Start- Filusbt `-Purge Rate:
PurgingMethod:
Total Volume Purged: (gallons/mis/L)
Sampling Information
Date Collected: _/ I b f_
Time Collected: t040 (Opm)
Sampling Equipment Used: Cr io o
Instrument ID: YST o Sbe /T Pw baG tF
Bottle Type
Preservation Analysis Required.
h„tkt9 K�'F s
Field Measurements/Observations
Sample Temp ('q: 17. b Time:
I o `1'2 Turbidity (ntu): Time: 10 9 9
Diss Oxy (mg/L): 0).5 Time:
Fe 2+ mg/L: ND Time:
Specific Cond. (us): u 4 _3 Time:
Res. CI Time:
Sample pH (s.u.): �( Z _ Time:
Odor:_' N o,e Time: u�
ReDox (mV): 11 ti , t ( Time:;
Appearance: utea, r Time:
ReDox (EH value):YSI ProPlus +200mV
3 53 -14 Other: Time:
General/Weather Observations:
Bunn /cloudy/rainy) Temp. 7S (°F) Wind o ' (mph)
Sampler Sgnature: 4Lye n �*A�
5 Date: q(r 6 / �y
Stabilization
Test
Time
Purged,
Temp.
(C)
17.I0°-
Diss Oxy.
(mg/L)
Spec.
Cond.
(us)
pH (sx.)
IteDox
(mv)
Turbidity
(ntu)
Volume
removed
(gallons/mis/
I ,
Water
level (ft)
Other
g •
Wk.
fi u'
W-0

CAlW1l CAI
Document t�*ame: Nield data Sheet
Date Issued: March &, 2014'
page:: 1 of �.
Doeument Number. E-CAR-E[Ti-0pl-rev.0.3
Issuing Authoritq: I' am Huntenville Quality
o€fice
Field Data Sheet
Client:'l)L%Ke
MoordSGocg,NC 'Project#:uiCCpIGQPrMrt5.enpL
Name and Affiliation Pmpler(s): RI"
6 P °` Field Data Sheet Review:
Name and Affiliation (Inspector): (`(11A °"jf z� A/`z Y SP he
Well Information `
Date: M 130 2'1 By. E)—
Well ID C t f3 w, - Z
Well Locked: (YE97-170j Fhtrs4mount )
Well Diameter:
Construction: (PV , teel/Stainless steel)
Total Well Depth: It
Multi Factor*: �r(Radius/12)2x&14x7.481
Static Water Level:ft
Casing Volume: t -- gallons
Height of Water Column: ft
Cal. 3 Volumes: — gallons
Pump Intake: It
Purge Information
Date Purged:
Start; -- Finish: Purge
Purging Method:
_—Total Volume Purged: —� (gallons/mis/L)
Sampling Information
Date Collected: 14 / tb / 2y
Tmie Collected,: 1105 -- am pm)
Sampling Equipment Used: Go r 2 Instrument ID: Y42 o 5 &g / TP- 6 a
Bottle Type Preservation Analysis Required
Field MeasurementRIObservations
Sample Temp (C):; 17 Z Time: (1 o 5—Turbidity (ntu): Time: ll o S
Diss Oxy (mg/L); 3 .1 Time: Fe 2+ mg/ L: Time., L
Specific fond. (uS): 43.0 Time: Res. Cl (mg/ L)/(gg/ L) —,— Tiine:
Sample pH (s.u.): 6 , 4 _ Time: Odor:_ ---LV o A I°__ Time: ,.. Flo f
ReDox (mV): 16 4.O Time: Appearance: L (PA / Time: _.
ReDox (EH value):YSIProPlus+200mV 3 b 4 .o Other: Time:
General/Weather Observations:
pp sunn cloudy/rainy) Temp. %� (°F) Wind 0 ' (mph)
Sampler Signature' R%n Date:
Stabilization Test
Time
Purged
Tamp.
(�)
Diss Qxy.
(mg/I.)
Spec,
Cond
{),
PH (s.u.)
ReDox
(mV)
Turbidity
(ntu)
Volume
removed
(gallons/mis/
L
Water
level (ft)
Other
DiA P
17.2
�3.�
t a.0
,

Pucument Nmnec Field days Shcet
Date Issued: March S, 2019.
Page; l of 1
/litaiyticat'
Document Number: F-CM-AI.D-00,1-mv,09
Issubig"Authority: Pacekuntersville Quslity
Office
Field Data Sheet
mt: 'Qvkx Lnefg I
Location: mvore3tiorj,,NC
Project#:GLS G�i' LF I't°�M;1
5aw,( le
ne and Affiliation (Sampler(s):
M E R-- PA tz
Field Da _Shee0teview
f
meand Affiliation (Inspector):
�� Z 14 17.,E
11 Information
Date: �/ 9-1�1
By.
,
11 lD: GLS _ F D -I
well T ockpd;­.( }sS / II8 / l
usltnaeunkj--
11 Diameter —
Cer+st ii Ev rP tin
^er'�,y YtftWess4weI)-
al Well Depth:
Qt '. Ivlultl Factor*:
r(fb" thus/12)2x3.14x7.481
is Water Level:
ft Casing Volume:
gallons
ghtof Water Column: —
ft C41.3 Volumes:
gallons
Pump intake:
it
e Infexmation
uare Purged: / — ]- '- Star
sh:'
Purge Rate:
Purging Method:
Total Volume Purge
(gallons/mis/L)
Sampling Information
Date Collected: LA f I� ��
Time Collected:
Sampling Equipment Used: I d-f-
L',! P Instrument ID:
'I S 1 0 z 0 4
Bottle Type
Preservation
Analysis Required
Field Measurements/Observations
>ample Temp ' :
Time
Turbidity (ntu):
]iss Oxy (mg/L): "
-Tina
Fe 2+ mg/L:
Time:
>pecif c Cond. (us):
Timer..
in Lj/(ug/L):
Rune:
iample pH (s.u.):
Time:
Odor: .-,----Time:
Time.
2dt)ox(rt>v):
Time:'
Appearance:
tei]ox (EH value):YSI ProPlus+200mV
Other: -
Time
.eneral/WeatherObservations:
(si npy/cloudy/rainy) Temp.
% ('F) wind 3 (mph)
,-
-
iampler Signature:
stabilization
Test
Time
Purged.
Temp.
CC)
(C)
x .
(mg/L)
Spec.
Cond:
(uS
pH (s.u.)
ReDox
(mV)
Turbidity
(ntu)
Volume
removed
(gallons/mis/
L
Water
level (ft)
Other

Decunrcnt Isinne: Field data ShSet
Date Issued: March S, 2(n91
/ GEAtk:7ytiC.2I
Page: 1 of
Number. F-BAR-FLI)-0Ql-rev.03
Issuing Authority.,Pace Htmtersville QualityDocument
office
ata
He
,Cc--P L-F f�rrni+ kpc d
1 Affiliat on (Sampler(s} �Field Data Sheet Review: ����
[ Affiliation (Inspector): Q Z C ze4 (zt(
rinaHon OM
Date: 4 ` o l zK By: MEI2-
:1EPj Well 7_ �gr_ka i—�--( Yl �l.�il9-Flushrf tou tt }
teter: Construction: (PVC' St S+a nlesc ])
,�.
Date Pa rget
Purging Me
Sampling I
Date Collec
Sampling B
Butt
v�str5 ,
MuluRactot , rkRadlus/1212 xdj+X 2A81
vel: ft Casing Volume: gallons
r Column ft Cal. 3 Volumes: gallons
as ,
Pump Intake: ft
Start : " 'sh:r Pucge Rate:
I: Total Volume Purged: (ga on
7m ation r
�/ Time Collected: (am m
mumt used: (lR bInstrument tD:
ype' Preservation Analysis Required
4tC(rmpl�r�fP )+_-
nents/Observations
Sample Temp Cq:
Timer
r Turbidity (ntu):
Time:
DissOxy,(mg/L:
Time:
�Fe2+mg/L:
Time:
Specific Cond. (uS):
Time
Res. Cl (m&/L)/(µg/L):
Time:
Sample pH (s.u.):
Time:
Odor:_
ReDox (mV):
Time:
Appearance:
'rime:
ReDox (EH value)3'SI ProPlus,+2OOmV
Other:
Time:
General/Weather Observations:
of v_
(sunny/clou /rainy) Temp.
(°F) W nd (mph)
5antpler Signauareraei ti
— Date: j
Stabilization Test
ime
Temp.
Diss Oxy.
In 1)
Spec.
Co
US)
p13 (s.u.}
ReDox
(mV)
Turbidity
(ntu)
Volume
removed
(gallons/mis/
Q
Water
level (ft)
OtherPurged,

Document Name: Field data Sheet
Date Issued: March 8, 2614-
:
Pa :1of(
dCBNkliyt7Cs1/-
Document Numltor. F-CAR-FIdS-OQl-rev.0.3
Issuing Authority: Pace Huntersville Quality
1
office
;M1 V 0A .A t nrntinn
J\JLProlect illLk CC F IL P�'. -FefYll j =C
Name and Affiliation (Sampmr(s): Ij
Pield Data Sheet Review:
4(l
p�
S
Name and Affiliation (Inspector}:
'�
r412 Z41
T ')
IVe11 Information
Dam' ', 4j
3a ) 211
BY: M I. IL.
Well 1D: ` D —a
I 7-11 tanek�d
Well Diameter:
Constr t)
Total Well Depth: ; it
Multi Factor*: r Radius/12)zx3.14x 7.481
Static Water Level: ft
Casing Volume: gallons
Height of Water Column: ft
Cal. 3 Volumes: gallons
Pump intake, ft
Purge Information
Date Pu ' d; �(
Start : Finish: Purge Rate:
Purging Method:
Total Volume Purge :
nils(L)
Sampling Information
Date Cvllecte�t:(�G(l / �t_�
Time Collected: C,C?_ (a (ptn)
Sampling Equipment Used: D(d - B Oidder
Instrument ID: ----�
Bottle Type
Preservation Analysis
Required`
Field Measurements/Observations
cymriip T__ einn QC) Time:____.
_Turbidity (ntu):
Time:
DissOxy(mg/L):
Fe2+mg/L:
Time:
Specific Cond. (uS)i, Time:
m IL)f(ug(L):
Tune:
Sample pH (s,u.); Time:
—Odor:--
Time:..__ ._
ReDox (mV): Time:
Appearance:
ReDox (EH value):XSI ProPlus +200mV
Other:
^
General(WeatherObservations: trAU-08
CLC—C(-C-6CPnA)—dKU
\Time
_ g/cloudy/rainy) Temp.
(°F) Wind
Sampler Signature; JU p• A ��5--
Date:f
Stabilization Test
�ftne
Purged
Temp.
Diss Oxy.
L'
Spec,
Cond:
on
pH (s.u.)
ReDox
(mV)
Turbidity
(ntu)
volume
removed
(gallons/mis/
L'
Water
level (ft)
Other

BEeM�tilytiCttl `
r -
Document Name. Field data Sheet
pate Issued: March 0, 2019.
Page:(1 of �--
Document Number: F-CAR-FIST-001-rev.Q3
Iasumg Authority:. Pace Htmtersville QuaI4
Office
Field Data Sheet Lf_�
Client: /%/L�2 G2i�`5 Location- aoo/e"AAd Aa Project#
Name and Affiliation (Sampler(s)• 1/77
�tic/h
Field Data Sheet Review:
Name and Affiliation (Inspector): ti
�J lAI
Well Information
Date: 413o�Itt By: MC
Well ID:' 1Q S� Cc (�Mw
Well Locked:41Ste
NO / Flushmount)
Well Diameter: �
Construction:el/Stainless Steel)
Total Well Depth:,_ %5, ` I it
MultiFactor*: C9rt63 r(Radiue/12)2x3.14x7.48j
Static Water Level- 9°�- 5 .3 ft
Casing Volume: ' r5 gallons
Height of Water Column: S • �6%
ft
Cal. 3 Volumes: /7 5 gallons
Pump In#Lke:
Purge information
DatePur Purged 1 11 // '4 Start:
g / Jam/
/ 7 3� } g
Ainish: I ur a Rate:
Purging Method: fi 4�G/} ifs Pon ! I!
Total Volume Purged: 'Z 3 S 61) (gallons/_10L)
Sampling- Information
Date Collected: _/%/�/� `
Time Collected: --_ (am/pm)
Sampling Equipment Used:D&it•�/t'N+o 0AL4M/R
Instrument ID: fl
Bottle Type
Preservation Analysis Required.
Field Measurements/Observatiorts
Sample Temp.(°C) Time:
__Turbidity(ntu): Time:
Diss Oxy(mg/L): _ Time: '
Fe 2+ mg/L Time:
Specific Cond. (uS): Time::
Res. Cl (mg/Lu(µg ),—Time:
Sample pH (s.%): Time::
Odor:_---. , -_.m Time:.-..
ReDox (mV): mte:
Appearance: Time:
ReDox (EH value)Nsl ProPlus +200mV
Time:
General/Weather Observations-
sunn cloud Temp..�7 (OF)/Wind -10 (mph)
Sampler Signature'. tz
`aiiny)
Date: 7 1 1 —
Stabilization Test
Spec.
Volume
Time
Purged'
Temp.
e
{ C)
Diss Oxy.
(mg/L)
Cond.
pH (s.u:)
ReDox
(mV)
Turbidity
{ntu}
removed
(gallons/ 11
Water
level (ft)
Other
(u$)
L
���
i
Ita�'
zi3•b
3
7TV
0�0
21,
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1
1 5
—
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or
Document Name:
Field Data Sheet
Document Issued: March 8,.:2019
Page Hof Z'
ceAnritytica(`
Document Nvinlier:
Issueing Authority;
F-CAR-FLD-0O1sev.03
Face 14untersvdle Quality Office
Client: �C / �_./ �" / AW y CyS 'ran Diameter, 31u1#plicati(m Factoe
1 0.0409
Location: A 60fi esA01to /L:�-/. 1.2 0-0918
1.625 01080
Project: CLS C`PLF 1%r A-J' S`/i=gA4`/r- 2 0;16.30
u»' 3 0-36F0
WellID: CLS- c6pmVV _ Y-i6'`y
® 4'' 06530
Reviewed Date and By: L(W % 2. G! Cj ®- 6 1• 4630
Stabilization Test yt3u1ztii me?- a 2.6100
�
e

poeµmgnt Name: Field data Sheet
Date lssµed: March S, 20147
Pop: I of j
�001MOMI
Document Number: F-CAR-xTd7-tlQl-rev.03
Tmuing Aut}wnty: Pam limtelsvilie Quality
p
6trA
Static'
Heigh
Date I
Purgi
Samv
Date t
Samp]
Fie
Sal
Di:
SPf
Sax
Re]
Re]
V11 V",'Fwlwlh v
Sw - 3 4Vek1-i�oske�l:--_
fur om-41
ft Multi Factor*:_
it Casing Volume:
Pump Intake:
start
Total Volume rged
ng Equipment Used: �Instrumenf Sla:
Bottle Type Preservation Ana
2easurementsl0bservations
Te (°Cj: Time: ._..__Turbidity (ntu):
Ky (mg//l,) T'me: Ee 2+ mg/L:
Cond. (uS): Time:
pH (s.u.): _Time: Odor:
(mVj: Time: Appearance:
(EH value):YSI ProPlus +200mV Other:
Sampler Signature: G G
Stabilization Test
a)
'i
H
1f'yUv 1 '
i8]
(gallons/mis/L)
is gixThed
me:
ime:
'line:
ime: _
me:
2.11.5ty� 8i0 4la' 30:r173"tj
T) Wind 3 (mph)
Time
Purged
OCTDiss
(
Oxy.
Spec.
Cond.PH
(s.u.)
ReDox
(:V)
Turbidity
(ntu)
Volume
removed
(gallons/mis/
L
Water
level (ft)
Other

Document Name: Field data sheet
Date lwuedi With B, 2019
@fllk7/ytiCal:'
:
page, 1 of 2
Document idumler:p-t~A[t-6CS5-ool-rev:Q3
Is, Autlwxt4y,Pace Htmteusvilfe Qualtry
Woe
p3e1d Data Sheet
Client: OIL Ke- G ne-iql ____.l acatlon: May re5 h A rd,/ C. Project #: I L L fs r Ilk � F r �o
Name -and Affiliation (Sampler(,): (2 �t field Data Sheet Review: S
Name and Affiliation (Inspector)- M ( Y5j C zq tZ6 j
Date:.. By: 12
W611Inforfnation 41501z A
Well ID.- GGpe.w- 5 Well Locked- 13T0/Flnshmount)
Well Diameter: 2 `� Construction: VC teel f Stainless Steel)
Total Well Depth: :zS.uI it Multipactor*: (,)LI103r{ltadna/12}2x.3.t4x7.4s)
Static Water Level. 4 8 .Q I ft Casing Volume: 1A.3 1A gallons
Height of Water Cohmm.-I ,y -i_ft Cal. 3 Vohmies: 13 . 01 gallons
Pump Intake: N 7 3 it
Pury.e lnformation
Date Purged: 4 / 12-4_ Start; 0410 Fiitislt 1�3 5 Pttrge Rate: Lao-4/r .:�l
Purging Method: B I a d dGr C U" i' Total Volume Purged: 16000 (gallons//at/"l�
L)
i4mplingInforniation �, ll
Date Collected:�/ j/O ._ Time Collected: )14 0 atg pm)
Sampling Equipment Used: '910.d L e/ PU m P Instrument ID: Y 5i aS G!V Vt. 606
Bottle Type Preservation Analysis Required:
tea e, tc
Sample Temp Cq: 1 `{. 7 Time:___!, q
Turbidity (ntu):
0,1
Time: 1(4 0
Diss Oxy (mg/L): H. Times
Fe 2+ mg/L
M b
Time: _
f
Specific Cond. (us); 204 9 Time:
Res. Cl (mg/L)/(µgf L):
'-'- Lime:
�--
Sample pH (s,u.): 1 ° 6 i Ti ne:
Odor: N
ene
Tmte:
_
ReDox (mV); Al5. % Time:
Appearance:
oear
'I nte:
Lr_
ReDox (EH value);YS1 ProPlus+200un V 315, i
Other:
Time:
-�
General/weather Observations:
Sampler
117/
Temp. 7 2 (°F) Wind M-1
Spec.
Volume
Time
Temp.
Digs Oxy.
Cond.
pH (s.u.)
ReDox
Turbidity
removed
Water
Other
Purged
(C)
(mg/L)
(US
(mV)
(ntu)
(gallons mis
level (ft)
L
o�3S
1y.y
63
voo.4
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411.9
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L32
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DocuvrentName:
Fiitld•Data Sheet
bocumrxttlssted:Adarrlc ,2619
Pa$e 2of 2
Document Numldr;:
IssueittgAuthority:
F-GAR-FLD-0(T1..rev.03
Pace HuntersV eQualityofffce
VV4 Diameter
Multiplication Factor"
Location:
Moa'CS born /NL
D•0918
lhZ,5
0_1050
Project.
4LT_rrLIbE C.GP
LC- Paenm;+ Aer.2o7,sf
:
1i.1,fs30
Well ID:
UfrAW-5
3
Os3.bBO
0,4530
p
Reviewed Date and By: ��tG�6f 2 �1
b
14680
Stabilization Test 4�307,4 '.h1 IL
2.6100
g
Time
Temp.
a
Diss Oxy„
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Turbidity
Volume,Removed
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ACBAna&4tc8i.;
Document Now: Field data sheet
Date Tssuad; March $,2tF19
I Page, iota
_
Do€umentNumber, F-EAIi-FLT;--a'tll-ray.0$(
fining, Authority I'a4el3uuEarsvilteQua(ity
Otfi€e
Field Data Sheet
Client- Dag E tid"4 y Location: dam ^ es oFo,Nl Froject #:'�r; 4 pr. u2t f
Name -acid AffiRaticnt (Sampler(s): Rms r^ te
Field Data Sheet Review:
<f
Name and Affiliation (Inspector): NSA
/ ZLd /Z LJ
Well Information
Dater "t � 30I zu By, r_
Well ID LC P C t P 1 B 5
Well Locked:gYES
NO%Flushmount)
Well Diameter: 2 . ^
Construction:Steel/Stainless Steel)
Total Well De th; o '` O ft
F uj
Muld Factor*: o-(6 3 C(1aaluaJ1z)2x3.14><7.t81
a6tow?"mp
Static Water Level (32•lQ) ft
Casing Volume: "— gallons
Height of Water Column: N't ft
Cal. 3 Volumes: gallons
Pump intake: ^' 3 � ft
Purge information
50
Date Purged: `i / (� , ILA Start: 12111 Finish: 17 ; Purga Ratedg'a / in ` n
Purging Method:( L6d12/ R t� r
Total Volume Purged: 1009 (gallons) tls L)
Sampling. Information.
DxYe Collected: 4 /�/ z
Time Collected: 13 a'0 (am pm
Sampling Equipment Used: Instrument ID: gI fo 5 6 q; /TPW b bG Lf
Bottle Type
Preservation Analysis Required
1.Qtkz t, >'
Field Measurements/Observations
Sample Temp (eC): 3 7, I Time:,
t 3 0 0 Turbidity (ntu): % Time: I
Diss Oxy (mg/L): eJ . __� Time;
Fe 2+ mg/L: Time:
Specific Cond. (uS): S A . 0 Timer
Res. CI (ng/L)/(ug/L):
Sample pH (s.u.): 5 . 5 Time:
Odor:_p(a A f Time: (3 Q
ReDox(mV): -702-& Tiutes
Appearance: C(P_�,- "Time: L
ReDox (EH value):YSI ProP us +200mV
4Q 2. 6 Other: —' °Time:
General/Weather Observations:
'97 tarn Q_t
Wmd_vw_�(mph)
Sampler Signature.. Ryan 643.5 Date-. 4/17/Zq
Stabilization Test
Time
Temp:
Diss Oxy.
Spec`
Cond.
pH (s.u.)
ReDox
Turbidity,
Volume
removed
Water
Other
Purged
o
(C)
(rng/1 �
(u
(mV)
(ntu)
(gallons mis
level (ft)
L
iLd0
i7.7
6-Q
boI
5•6
tRb.2
I.
150
Bekow aAf
0u
Z7.
_
o. q
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i.
750
g_ T
2
Z-1,
5.
0.7
s 5
0%.
1,7
Sao
a5'Q
IT
-6
•5
z,
0.8,,
75
S 5
T7
5.14
ba,2
7"02,

*
Document Name: Field data Sheet,
pate Issued: Marche &, 2Q(9
Pee 1 of J
CCA1h71J`(iCAI
Document Number: F-C/}jj-Ft.t�-QQiKBV.�
Issuing Authority: FaCC }tUPtekBYltl�QPO�kIj•
Office
Field Data Sheet
Client: Duke E&e-(4
Location, Mooraf,boc�Nc Project#: Gt.5 of LF p_cr^;+ Aae.zo)-4
Flame and Affiliation (Sampler(s):
Q/a g Pal C� Field Data Sheet Review:
Name and Affiliation (Inspector);
N /A \t 13 o i 2\j ML" R-
Well Information
Date J 1� 2- By.
Well ID: L L QS W - (
Well Locked: (Yr � �r,�(1411,,..H,.,"R )
Well Diameter: —�
Construction: (PVC-/Steelf %At less Steel)
Total Well Depth: -
£t Multi Factor*: [*(Radius/12)2x 3,l4x 7 a81
Static Water Level:
ft Casing Volume: gallons
Height of Water Column: `�
ft Cal.3 Volumes: gallons
Dump Intake: ft
Purge, Information
Date Purged: `%��
Start: 1� Finish: 'Purge Rate: _—
Purging Method
Total Volume Purged: —^ (gallons/mils/L)
SampiingInformatiott
Date Collected:_/ t6 / 2t
Time Collected: l Z 5 `J __ (am urn)
Sampling Equipment Used: (r r a 5
Instrument ID: Y 52 v S 6 4/ 'tP v 6 as Z/
Bottle Type-'
Preservation : Analysis Required
me t4 t 5
D mefe ll
Field Measurements/Observations
Sample Temp loq: l ti . ( Time:.'
12 S —aTurbidity (ntu): Time: 1 S
Diss Oxy (mg/L): °I . h Time:
L
Fe 2+ mg/L: N`D Time:
Specific Cond. (uS): 4 4 . 9 Time:
Res. Cl (mg/LY(itg/L): — 'rime: —
Sample pH(s.u.): i.3 Time:
Odor: _ No e_ __Time:_ 12So
ReDox (mV): q' Tunes
Appearance: L I @ s / Time:
ReDox (EH value):YSI ProPlus +200mV
2-19 •
� Other: Time:
General/Weather Observations: Re y0. Yl2 - (r PS , 3 y • I 41 63 / -`31 • � 6 13 41
.!—;—A T.�-- 5 % laTP
4AI;-.4 ri - I
mpler Signature, R'! m`, g `i �y Date: 4 / 2,6 -Z u
Time
Temp.
Diss Oxy.
Spec` Cond.
pH (s u;)
volume,

Dockrnient Noma: Field data Sheet
bate lsaved: March 8, 2019
Page: 1.
r� L'Eflr7atyl1Cfi1'
of
Document Number; F-CAR-Fl )-Q01--rev.03
Issuing Authority:Pam HunteravilleQuality
f
Office
Field Data Sheet
Client: Dak-c rA6roy Location: Moo.eS horo,NC Project
Name and Affiliation (Sampler(s): R� 13
P-� 2
Field Data Sheet Review:
Name and Affiliation (Inspector): N / A
4 13d I tit Me ✓�
Well Information
Date: .�/3 By. `(m
Well ID. ct'P(i t✓- 2
Well Locked: ( YESf Fiushmeumt)
Well Diameter:
Construction: (PVC _G� J-9",less Steel)
Total Well Depth: -- it
Multi Factor : t adius(12)2 x 3.i1x 7.as]
Static Water Level:
Casing Volume: gallons
Heightof Water Column: "�ft
Cal.3 Volumes: gallons '
Pump Intake: ft
Purge Information
Date Purged: Start : Finish: — -- Purge Rate:
Purging Method.' ----
Total Volume Purged: (gallons/mils/L) `-
Sampling Information
Date Collected:2- tA
Time Collected: 131 S V_ (am pm)
Sampling Equipment Used: 4 o
Instrument ID: '(Si o S 6 p / %'4w 60 3'I
Bottle Type
Preservation Analysis Required
Me+at 5
Field Measurements/Observations
Sample Temp (°C): 141 . Time:_L3
1 5 Turbidity (ntu): 7. $ Time:
Diss Oxy(mg f L): 'b• b' Time:
Fe 2+ mg/L: N 17 Time:
Specific Cond. (uS): k I . Time:
Res. CI (=g/L)&g/L): -- 'rime.
Sample pH (s.um): h . 9- Time:
Odor:_:. N a nP Time: , 1315
ReDox (mV): 101 M Time:
Appearance: Glee r Time;
R D x H alu e NSI Pr PI +200 mV
391 Other: T^^..
e 0( V ).:O U9.. 1
General/WeatherObservations: Re5amgle . PS �i5."L05-LOO/
(sunnyf loudy ainy) Tem
R.l u / 2'6,
Time
fiurged
Temp.
{ C}
Diss Oxy;
(mg/L)
Spec.
Cond:
(uS)
pH (s.u,}
:ReDo,)x
V
Turbidity
(btu}
Volume
removed
(gallonsfmisf
L'
Watera
level {£t}
Other
baP
1�6
til.
t;,13
3.9
-7.S

Semiannual Water Quality Monitoring Report —April 2024 Sampling Event
Rogers Energy Complex—Cliffside Steam Station —CCP Landfill Phases I through IV (Permit No. 8106-INDUS)
Mooresboro, North Carolina
APPENDIX B
LABORATORY REPORTS,
DATA VALIDATION CHECKLISTS, AND
CHAIN -OF -CUSTODY FORMS
410
synTerra
Science & Engineering Consultants

Data Validation Checklist
Facility/Site Location/Sample os
State
CCP-LEACHATE, CCP-LEACHATE-34, CCPMW-1D, CCPMW-1S, CCPMW-2S, CCPMW-3D, CCPMW-4, CCPMW-5,
Cliffside
Steam Station
INC
CCPMW-6S, CCPMW-7, CCPMW-10, CCPMW-11, CCPSW-1, CCPSW-2, CCR-CCP-18S, CCR-CCP-19S, CCR-CCP-20D,
CCR-CCPBG-1BR, CCR-CCPBG-1D, CCR-CCPMW-8D, CCR-CCPTW-2D
Duke Central Lab
11-0�•EZE=
M i Groundwater
J24030273 4/16-17/2024 4/17-18/2024 5/8/2024
Surface Water
Other
References:
National Functional Guidelines for Organic/Inorganic Superfund Methods Data Review (USEPA 2020)
Guidance on Environmental Data Verification and Data Validation (USEPA 2002)
Radiochemical Data Verification and Validation (MARLAP Manual Volume I: Chapter 8, 2004)
Chain of Custody
�✓
/A
1) Do the sample IDs and laboratory analyses recorded on the Chain of Custody match the sample IDs and analyses listed in the laboratory package?
�✓
a) Do the dates and times of sampling listed on the Chain of Custody match the laboratory report?
�✓
2) Is the sample temperature upon receipt at the laboratory recorded on the Chain of Custody or sample receipt form?
❑✓
❑
❑ a) Is the sample temperature upon receipt less than 6 degrees Celsius? If NO, then:
❑
❑
�J 1) Was the presence of wet ice noted in the cooler? OR
❑
❑
�J 11) Were the samples collected less than two hours prior to receipt at the lab?
❑�
❑
3) Was the proper sample preservation used, confirmed, and documented on the Chain of Custody and/or sample receipt form?
❑J
❑
4) Are there any special notes, exceptions, and/or anomalies listed on the Chain of Custody, sample receipt form, or laboratory report?
❑
❑�
❑ 5) Was the transfer of custody of the samples properly documented and traceable through signature, date, and time by all persons who relinquished and/or received
custody of the samples?
-
®®Batch eAssurance/Quality
6) Was the holding time for preparation and/or analysis met for each parameter?
❑
�✓ a) Total Alkalinity, Bicarbonate Alkalinity, and Carbonate Alkalinity: Analyzed within 14 days of collection
❑�
❑
b) Bromide, Chloride, Fluoride, and Sulfate (Anions): Analyzed within 28 days of collection
❑
c) Sulfide: Analyzed within 7 days of collection
❑�
❑
d) Total Organic Carbon (TOC) and/or Nitrate -Nitrite: Analyzed within 28 days of collection
❑
❑
e) Total Phosphorus (TP) and Dissolved Phosphorus: Analyzed within 28 days of collection
❑
❑
�J f) Hexavalent Chromium and Dissolved Hexavalent Chromium: Analyzed within 24 hours (unpreserved) / 28 days (preserved) of collection
�✓
g) Mercury and Dissolved Mercury: Analyzed within 28 days of collection (preserved)
�✓
❑
h) Total Metals and Dissolved Metals: Analyzed within 180 days of collection
�J
❑
1) Total Suspended Solids (TSS) and/or Total Dissolved Solids (TDS): Analyzed within 7 days of collection
❑
q 1) Radionuclides: Analyzed within 180 days of collection
❑
❑
�J k) Methane: Analyzed within 14 days (preserved) / 7 days (unpreserved) of collection
❑
❑
�✓ 1) Oil and Grease: Analyzed within 28 days of collection
❑J
❑
❑ 7) Are there any qualifiers assigned by the laboratory and if so, are the qualifier definitions provided?
❑�
8) Method Blank- Were any parameters detected in the laboratory method blank(s)?
�J a) If YES, were any target analyses detected in the samples at concentrations less than ten times the method blank concentration?
�✓
9) Laboratory Control Sample (LCS) - Were any parameters flagged by the lab as being outside the limits of control in the associated LCS?
❑
�J
a) If YES, was the parameter recovery less than 50 percent or greater than 150 percent?
❑
�J b) Were the same parameters detected in the samples?
�✓
❑
10) Matrix Spike Sample (MS/MSD) - Did the laboratory provide matrix spike results? If so, then:
a) Was the original sample spiked a project sample? If so, then:
❑
b) Were any parameters flagged by the lab as being outside the limits of control in the associated matrix spike sample?

Batch !Assurance/Quality
❑ 11) Laboratory Duplicate Sample - Did the laboratory provide lab duplicate sample results? If so, then:
�✓ ❑ a) Was the sample analyzed as a laboratory duplicate a project sample? If so, then:
�J b) Were any parameters flagged by the lab as being outside the limits of control in the laboratory duplicate sample?
�✓ 12) Field Duplicate Sample - Is the relative percent difference between the parent and field duplicate sample results greater than 35 percent?
13) Field/Equipment/Trip Blanks - Were any parameters detected in the associated field, equipment, and/or trip blanks?
�✓ a) If yes, were any target analytes detected in the samples at a concentration less than ten times the Field/Equipment/Trip Blank concentration?
❑ 14) Were initial and continuing calibration blank information within acceptable criteria per the lab report?
❑ ❑ ❑ 15) Were any reporting limits for diluted, non -detect results greater than the screening criteria?
❑ ❑� 16) Radionuclides: Are quality control sample results provided?
❑ �J a) Are any results flagged or qualified?
�J b) Are Uncertainty, Minimum Detectable Concentration (MDC), and Tracer and/or Carrier % Recoveries provided for each sample?
Lab Qualifiers:
1 - Analyte detected above the MDL, but below the RL; analyte concentration should be considered an estimate.
M - MS and/or MSD recovery was outside of the control limits; the associated LCS recovery was acceptable.
Validation Qualifiers:
R - Result is unusable. The sample result is rejected due to serious deficiencies in meeting quality control criteria; the analyte may or may not be present in the sample.
J - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
U - Analyte was analyzed form but not detected above the minimum detectable concentration (MDC) or method detection limit (MDL).
B -Target analyte detected in the method blank an in the sample at a concentration less than 10x the blank concentration.
• Note: The dissolved metals samples for CCPSW-1 and CCPSW-2 were not analyzed due to a lab error. These locations were resampled for total/dissolved metals and will report underjob order
J24040661.
• Per the Chain of Custody, CCPSW-3 was not sampled because it was dry.
• Mercury MS/MSD % recoveries low for CCP-LEACHATE-34 (M).
• The RPD between CCPMW-1D and the field duplicate is greater than 35% for Nickel (1.18/0.824 ug/L).
• The RPD between CCR-CCPTW-2D and the field duplicate is greater than 35%for Nitrate (0.2/0.14 mg/L).
• Nitrate (0.1 mg/L), Nitrate as N (0.02 mg-N/L), Calcium (0.018 mg/L), Iron (0.006 mg/L), and Silver (0.062 ug/L) were detected in the 4/16/2024 Field Blank; Nitrate, Nitrate as N, Iron, and
Silver were also detected in the associated samples at concentrations less than 10x the blank concentrations.
• Lead (0.94 ug/L) was detected in the 4/17/2024 Field Blank (J24040465); Lead was also detected in the associated samples at concentrations less than 10x the blank concentration.
• Due to a dilution factor of 200, the Fluoride reporting limit (20 mg/L) is greater than the EPA Primary MCL (4 mg/L) and CCP-LEACHATE was reported as non -detect.
Review Determination: ❑ Usable ❑ Usable with Required Actions ❑ Unusable
Initials/Signatures: Date:
Data Quality Reviewer REB 6/17/2024
Technical Lead SAS 6/25/2024

DUKE
Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number:
J24030273
Project Name:
CLIFFSIDE - GW CCP LANDFILL
Task Code:
LF
Customer Name(s):
Bill Wylie,Bryan Moeller,Dee O Brien,Josh Stowe
Customer Address:
Cliffside Steam Station
573 Duke Power Rd
Mail Code: Clliffside Steam Station
Mooresboro, NC 28024
Lab Contact:
Peggy Kendall Phone: [phone]
Report Authorized By:
Date: 5/8/2024
P4g
(Signature)
)yenda:'
Program Comments:
Page 1 of 47
Note: The dissolved metal samples for CCPSW-1 and CCPSW-2 were not analyzed due to a lab error. These locations were re -
sampled for total/dissolved metals and will report under job order J24040661.
QC Note: CCP-Leachate 34 Hg MS/MSD recoveries fell below the QC limits. The blank and LCS were within the control limits.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Page 2 of 47
Sample ID
Plant/Station
Collection
Date and Time
Collected By
Sample Description
2024006028
CLIFFSIDE
16-Apr-24
11:30AM
MER
CLS_CCPMW-1S
2024006029
CLIFFSIDE
16-Apr-24
10:05AM
MER
CLS_CCPMW-1D
2024006030
CLIFFSIDE
16-Apr-24
4:10 PM
TJD
CLS_CCPMW-2S
2024006031
CLIFFSIDE
16-Apr-24
3:10 PM
TJD
CLS_CCPMW-3D
2024006032
CLIFFSIDE
16-Apr-24
3:50 PM
JCM
CLS_CCPMW-4
2024006033
CLIFFSIDE
17-Apr-24
11:40 AM
RMB
CLS_CCPMW-5
2024006034
CLIFFSIDE
16-Apr-24
2:55 PM
JFA
CLS_CCPMW-6S
2024006035
CLIFFSIDE
16-Apr-24
12:25 PM
JFA
CLS_CCPMW-7
2024006036
CLIFFSIDE
16-Apr-24
3:55 PM
MER
CLS_CCPMW-10
2024006037
CLIFFSIDE
16-Apr-24
1:20 PM
MER
CLS_CCPMW-11
2024006038
CLIFFSIDE
16-Apr-24
11:30 AM
RMB
CLS_CCP-Leachate
2024006039
CLIFFSIDE
16-Apr-24
11:40 AM
RMB
CLS_CCP-LEACHATE-34
2024006040
CLIFFSIDE
17-Apr-24
1:00 PM
RMB
CLS_CCR-CCP-18S
2024006041
CLIFFSIDE
16-Apr-24
1:05 PM
TJD
CLS_CCR-CCP-19S
2024006042
CLIFFSIDE
16-Apr-24
1:30 PM
RMB
CLS_CCR-CCP-20D
2024006043
CLIFFSIDE
16-Apr-24
2:20 PM
RMB
CLS_CCR-CCPMW-8D
2024006044
CLIFFSIDE
16-Apr-24
11:00 AM
TJD
CLS_CCR-CCPTW-2D
2024006045
CLIFFSIDE
16-Apr-24
1:10 PM
JCM
CLS_CCR-CCPBG-1D
2024006046
CLIFFSIDE
16-Apr-24
10:50AM
JCM
CLS_CCR-CCPBG-1BR
2024006047
CLIFFSIDE
16-Apr-24
10:40 AM
RMB
CLS_CCPSW-1
2024006071
CLIFFSIDE
16-Apr-24
11:05 AM
RMB
CLS_CCPSW-2
2024006073
CLIFFSIDE
16-Apr-24
MER
CLS_FD-20240416-1
2024006074
CLIFFSIDE
16-Apr-24
2:00 PM
TJD
CLS_FB-20240416-1400
2024006075
CLIFFSIDE
16-Apr-24
TJD
CLS_FD-20240416-2
24 Total Samples

Page 3 of 47
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals❑ Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
❑d Job Summary Report
❑d Sample Identification
❑� Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
❑� Analytical Laboratory QC Report
❑ Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑� Chain of Custody
❑� Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 5/8/2024

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030273
Site: CLS CCPMW-1S
Collection Date: 04/16/2024 11:30 AM Loc code: CLS CCPMW-lS
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q24040251
Chloride
4.4
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
0.18
mg/L
Nitrate as N
0.04
mg-N/L
Sulfate
0.51
mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040281
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040283
Barium (Ba)
0.022
mg/L
Boron (B)
0.007 J
mg/L
Calcium (Ca)
0.181
mg/L
Iron (Fe)
0.039
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
0.712
mg/L
Manganese (Mn)
0.021
mg/L
Zinc (Zn)
0.005 J
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040287
Antimony (Sb)
0.129 J
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.692 J
ug/L
Cobalt (Co)
1.31
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.274 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.607 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V)
0.114 U
ug/L
TOTAL DISSOLVED SOLIDS -
024040253
TDS 25 U mg/L
Sample #: 2024006028
Matrix: GW RCRA
Page 4 of 47
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/17/2024 07:45
BGN9034
0.1
0.0479
1
EPA 9056A
04/17/2024 07:45
BGN9034
0.1
0.0209
1
EPA 9056A
04/17/2024 07:45
BGN9034
0.023
0.002
1
EPA 9056A
04/17/2024 07:45
BGN9034
0.1
0.0428
1
EPA 9056A
04/17/2024 07:45
BGN9034
0.05
0.01
1
EPA 7470A
04/18/2024 11:47
CWSPEN3
0.005
0.002
1
SW 601 OD
04/22/2024 00:28
CELL106
0.05
0.005
1
SW 601 OD
04/22/2024 00:28
CELL106
0.05
0.012
1
SW 601 OD
04/22/2024 00:28
CELL106
0.01
0.004
1
SW 601 OD
04/22/2024 00:28
CELL106
0.005
0.002
1
SW 601 OD
04/22/2024 00:28
CELL106
0.02
0.008
1
SW 601 OD
04/22/2024 00:28
CELL106
0.005
0.001
1
SW 601 OD
04/22/2024 00:28
CELL106
0.015
0.004
1
SW 601 OD
04/22/2024 00:28
CELL106
1
0.104
1
SW 6020B
04/22/2024 12:48
MHALL3
1
0.111
1
SW 6020B
04/22/2024 12:48
MHALL3
1
0.249
1
SW 6020E
04/22/2024 12:48
MHALL3
1
0.032
1
SW 6020E
04/22/2024 12:48
MHALL3
1
0.185
1
SW 6020B
04/22/2024 12:48
MHALL3
1
0.077
1
SW 6020E
04/22/2024 12:48
MHALL3
1
0.787
1
SW 6020B
04/22/2024 12:48
MHALL3
1
0.037
1
SW 6020E
04/22/2024 12:48
MHALL3
1
0.18
1
SW 6020E
04/22/2024 12:48
MHALL3
1
0.256
1
SW 6020B
04/22/2024 12:48
MHALL3
1
0.193
1
SW 6020B
04/22/2024 12:48
MHALL3
1
0.035
1
SW 6020E
04/22/2024 12:48
MHALL3
0.2
0.041
1
SW 6020B
04/22/2024 12:48
MHALL3
1
0.114
1
SW 6020E
04/22/2024 12:48
MHALL3
25
25
1
SM2540C
04/17/202411:45
HHOOGKA

Certificate of Laboratory Analysis Page 5 of 47
This report shall not be reproduced, except in full.
Order # J24030273
Site: CLS CCPMW-1 D Sample #: 2024006029
Collection Date: 04/16/2024 10:05 AM Loc code: CLS CCPMW-1 D Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q24040251
Chloride
8.1
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
1.7
mg/L
Nitrate as N
0.39
mg-N/L
Sulfate
1.4
mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040281
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040283
Barium (Ba)
0.017
mg/L
Boron (B)
0.008 J
mg/L
Calcium (Ca)
2.80
mg/L
Iron (Fe)
0.009 J
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
1.47
mg/L
Manganese (Mn)
0.007
mg/L
Zinc (Zn)
0.005 J
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040287
Antimony (Sb)
0.123 J
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.321 J
ug/L
Cobalt (Co)
0.3 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
1.18
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V)
0.114 U
ug/L
TOTAL DISSOLVED SOLIDS -
024040253
TDS 36.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/17/2024 09:04
BGN9034
0.1
0.0479
1
EPA 9056A
04/17/2024 09:04
BGN9034
0.1
0.0209
1
EPA 9056A
04/17/2024 09:04
BGN9034
0.023
0.002
1
EPA 9056A
04/17/2024 09:04
BGN9034
0.1
0.0428
1
EPA 9056A
04/17/2024 09:04
BGN9034
0.05
0.01
1
EPA 7470A
04/18/2024 11:54
CWSPEN3
0.005
0.002
1
SW 601 OD
04/22/2024 00:43
CELL106
0.05
0.005
1
SW 601 OD
04/22/2024 00:43
CELL106
0.05
0.012
1
SW 601 OD
04/22/2024 00:43
CELL106
0.01
0.004
1
SW 601 OD
04/22/2024 00:43
CELL106
0.005
0.002
1
SW 601 OD
04/22/2024 00:43
CELL106
0.02
0.008
1
SW 601 OD
04/22/2024 00:43
CELL106
0.005
0.001
1
SW 601 OD
04/22/2024 00:43
CELL106
0.015
0.004
1
SW 601 OD
04/22/2024 00:43
CELL106
1
0.104
1
SW 6020B
04/22/2024 12:01
MHALL3
1
0.111
1
SW 6020B
04/22/2024 12:01
MHALL3
1
0.249
1
SW 6020E
04/22/2024 12:01
MHALL3
1
0.032
1
SW 6020E
04/22/2024 12:01
MHALL3
1
0.185
1
SW 6020B
04/22/2024 12:01
MHALL3
1
0.077
1
SW 6020E
04/22/2024 12:01
MHALL3
1
0.787
1
SW 6020B
04/22/2024 12:01
MHALL3
1
0.037
1
SW 6020E
04/22/2024 12:01
MHALL3
1
0.18
1
SW 6020E
04/22/2024 12:01
MHALL3
1
0.256
1
SW 6020B
04/22/2024 12:01
MHALL3
1
0.193
1
SW 6020B
04/22/2024 12:01
MHALL3
1
0.035
1
SW 6020E
04/22/2024 12:01
MHALL3
0.2
0.041
1
SW 6020B
04/22/2024 12:01
MHALL3
1
0.114
1
SW 6020E
04/22/2024 12:01
MHALL3
25
25
1
SM2540C
04/17/202411:45
HHOOGKA

Certificate of Laboratory Analysis Page 6 of 47
This report shall not be reproduced, except in full.
Order # J24030273
Site: CLS CCPMW-2S Sample #: 2024006030
Collection Date: 04/16/2024 04:10 PM Loc code: CLS CCPMW-2S Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q24040251
Chloride
2.6
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
5.9
mg/L
Nitrate as N
1.3
mg-N/L
Sulfate
6.1
mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040281
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040283
Barium (Ba)
0.033
mg/L
Boron (B)
0.012 J
mg/L
Calcium (Ca)
2.59
mg/L
Iron (Fe)
0.450
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
1.93
mg/L
Manganese (Mn)
0.042
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040287
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.145 J
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
4.19
ug/L
Cobalt (Co)
0.938 J
ug/L
Copper (Cu)
1.72
ug/L
Lead (Pb)
0.395 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
2.29
ug/L
Selenium (Se)
0.556 J
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.051 J
ug/L
Vanadium (V)
0.961 J
ug/L
TOTAL DISSOLVED SOLIDS -
024040253
TDS 29.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/17/2024 09:20
BGN9034
0.1
0.0479
1
EPA 9056A
04/17/2024 09:20
BGN9034
0.1
0.0209
1
EPA 9056A
04/17/2024 09:20
BGN9034
0.023
0.002
1
EPA 9056A
04/17/2024 09:20
BGN9034
0.1
0.0428
1
EPA 9056A
04/17/2024 09:20
BGN9034
0.05
0.01
1
EPA 7470A
04/18/2024 11:56
CWSPEN3
0.005
0.002
1
SW 601 OD
04/22/2024 00:49
CELL106
0.05
0.005
1
SW 601 OD
04/22/2024 00:49
CELL106
0.05
0.012
1
SW 601 OD
04/22/2024 00:49
CELL106
0.01
0.004
1
SW 601 OD
04/22/2024 00:49
CELL106
0.005
0.002
1
SW 601 OD
04/22/2024 00:49
CELL106
0.02
0.008
1
SW 601 OD
04/22/2024 00:49
CELL106
0.005
0.001
1
SW 601 OD
04/22/2024 00:49
CELL106
0.015
0.004
1
SW 601 OD
04/22/2024 00:49
CELL106
1
0.104
1
SW 6020B
04/22/2024 12:57
MHALL3
1
0.111
1
SW 6020B
04/22/2024 12:57
MHALL3
1
0.249
1
SW 6020E
04/22/2024 12:57
MHALL3
1
0.032
1
SW 6020E
04/22/2024 12:57
MHALL3
1
0.185
1
SW 6020B
04/22/2024 12:57
MHALL3
1
0.077
1
SW 6020E
04/22/2024 12:57
MHALL3
1
0.787
1
SW 6020B
04/22/2024 12:57
MHALL3
1
0.037
1
SW 6020E
04/22/2024 12:57
MHALL3
1
0.18
1
SW 6020E
04/22/2024 12:57
MHALL3
1
0.256
1
SW 6020B
04/22/2024 12:57
MHALL3
1
0.193
1
SW 6020B
04/22/2024 12:57
MHALL3
1
0.035
1
SW 6020E
04/22/2024 12:57
MHALL3
0.2
0.041
1
SW 6020B
04/22/2024 12:57
MHALL3
1
0.114
1
SW 6020E
04/22/2024 12:57
MHALL3
25
25
1
SM2540C
04/17/202411:45
HHOOGKA

Certificate of Laboratory Analysis Page 7 of 47
This report shall not be reproduced, except in full.
Order # J24030273
Site: CLS CCPMW-3D Sample #: 2024006031
Collection Date: 04/16/2024 03:10 PM Loc code: CLS CCPMW-3D Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q24040251
Chloride
5.6
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
5.3
mg/L
Nitrate as N
1.2
mg-N/L
Sulfate
17
mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040281
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040283
Barium (Ba)
0.026
mg/L
Boron (B)
0.042 J
mg/L
Calcium (Ca)
9.58
mg/L
Iron (Fe)
0.004 J
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
2.21
mg/L
Manganese (Mn)
0.006
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040287
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.106 J
ug/L
Chromium (Cr)
1.12
ug/L
Cobalt (Co)
0.087 J
ug/L
Copper (Cu)
0.909 J
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.209 J
ug/L
Nickel (Ni)
0.256 U
ug/L
Selenium (Se)
0.262 J
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.042 J
ug/L
Vanadium (V)
0.114 U
ug/L
TOTAL DISSOLVED SOLIDS -
024040253
TDS 58.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/17/2024 10:07
BGN9034
0.1
0.0479
1
EPA 9056A
04/17/2024 10:07
BGN9034
0.1
0.0209
1
EPA 9056A
04/17/2024 10:07
BGN9034
0.023
0.002
1
EPA 9056A
04/17/2024 10:07
BGN9034
0.5
0.0428
5
EPA 9056A
04/17/2024 10:07
BGN9034
0.05
0.01
1
EPA 7470A
04/18/2024 11:58
CWSPEN3
0.005
0.002
1
SW 601 OD
04/22/2024 00:54
CELL106
0.05
0.005
1
SW 601 OD
04/22/2024 00:54
CELL106
0.05
0.012
1
SW 601 OD
04/22/2024 00:54
CELL106
0.01
0.004
1
SW 601 OD
04/22/2024 00:54
CELL106
0.005
0.002
1
SW 601 OD
04/22/2024 00:54
CELL106
0.02
0.008
1
SW 601 OD
04/22/2024 00:54
CELL106
0.005
0.001
1
SW 601 OD
04/22/2024 00:54
CELL106
0.015
0.004
1
SW 601 OD
04/22/2024 00:54
CELL106
1
0.104
1
SW 6020B
04/22/2024 13:07
MHALL3
1
0.111
1
SW 6020B
04/22/2024 13:07
MHALL3
1
0.249
1
SW 6020E
04/22/2024 13:07
MHALL3
1
0.032
1
SW 6020E
04/22/2024 13:07
MHALL3
1
0.185
1
SW 6020B
04/22/2024 13:07
MHALL3
1
0.077
1
SW 6020E
04/22/2024 13:07
MHALL3
1
0.787
1
SW 6020B
04/22/2024 13:07
MHALL3
1
0.037
1
SW 6020E
04/22/2024 13:07
MHALL3
1
0.18
1
SW 6020E
04/22/2024 13:07
MHALL3
1
0.256
1
SW 6020B
04/22/2024 13:07
MHALL3
1
0.193
1
SW 6020B
04/22/2024 13:07
MHALL3
1
0.035
1
SW 6020E
04/22/2024 13:07
MHALL3
0.2
0.041
1
SW 6020B
04/22/2024 13:07
MHALL3
1
0.114
1
SW 6020E
04/22/2024 13:07
MHALL3
25
25
1
SM2540C
04/17/202411:45
HHOOGKA

Certificate of Laboratory Analysis Page 8 of 47
This report shall not be reproduced, except in full.
Order # J24030273
Site: CLS CCPMW-4 Sample #: 2024006032
Collection Date: 04/16/2024 03:50 PM Loc code: CLS CCPMW-4 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q24040251
Chloride
1.6
mg/L
Fluoride
0.15
mg/L
Nitrate
0.04 J
mg/L
Nitrate as N
0.01 J
mg-N/L
Sulfate
13
mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040281
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040283
Barium (Ba)
0.013
mg/L
Boron (B)
0.006 J
mg/L
Calcium (Ca)
27.6
mg/L
Iron (Fe)
0.121
mg/L
Lithium (Li)
0.003 J
mg/L
Magnesium (Mg)
1.16
mg/L
Manganese (Mn)
0.013
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040287
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.729 J
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.436 J
ug/L
Cobalt (Co)
0.077 U
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.06 J
ug/L
Molybdenum (Mo)
8.73
ug/L
Nickel (Ni)
0.338 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V)
0.233 J
ug/L
TOTAL DISSOLVED SOLIDS -
024040253
TDS 119 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/17/2024 10:23
BGN9034
0.1
0.0479
1
EPA 9056A
04/17/2024 10:23
BGN9034
0.1
0.0209
1
EPA 9056A
04/17/2024 10:23
BGN9034
0.023
0.002
1
EPA 9056A
04/17/2024 10:23
BGN9034
0.5
0.0428
5
EPA 9056A
04/17/2024 10:23
BGN9034
0.05
0.01
1
EPA 7470A
04/18/2024 12:01
CWSPEN3
0.005
0.002
1
SW 601 OD
04/22/2024 00:59
CELL106
0.05
0.005
1
SW 601 OD
04/22/2024 00:59
CELL106
0.05
0.012
1
SW 601 OD
04/22/2024 00:59
CELL106
0.01
0.004
1
SW 601 OD
04/22/2024 00:59
CELL106
0.005
0.002
1
SW 601 OD
04/22/2024 00:59
CELL106
0.02
0.008
1
SW 601 OD
04/22/2024 00:59
CELL106
0.005
0.001
1
SW 601 OD
04/22/2024 00:59
CELL106
0.015
0.004
1
SW 601 OD
04/22/2024 00:59
CELL106
1
0.104
1
SW 6020B
04/22/2024 13:16
MHALL3
1
0.111
1
SW 6020B
04/22/2024 13:16
MHALL3
1
0.249
1
SW 6020E
04/22/2024 13:16
MHALL3
1
0.032
1
SW 6020E
04/22/2024 13:16
MHALL3
1
0.185
1
SW 6020B
04/22/2024 13:16
MHALL3
1
0.077
1
SW 6020E
04/22/2024 13:16
MHALL3
1
0.787
1
SW 6020B
04/22/2024 13:16
MHALL3
1
0.037
1
SW 6020E
04/22/2024 13:16
MHALL3
1
0.18
1
SW 6020E
04/22/2024 13:16
MHALL3
1
0.256
1
SW 6020B
04/22/2024 13:16
MHALL3
1
0.193
1
SW 6020B
04/22/2024 13:16
MHALL3
1
0.035
1
SW 6020E
04/22/2024 13:16
MHALL3
0.2
0.041
1
SW 6020B
04/22/2024 13:16
MHALL3
1
0.114
1
SW 6020E
04/22/2024 13:16
MHALL3
25
25
1
SM2540C
04/17/202411:45
HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030273
Site: CLS CCPMW-5
Collection Date: 04/17/2024 11:40 AM Loc code: CLS CCPMW-5
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q24040279
Chloride 4.7 mg/L
Fluoride 0.1 J mg/L
Nitrate 2.8 mg/L
Nitrate as N 0.64 mg-N/L
Sulfate 17 mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040353
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040334
Barium (Ba)
0.003 J
mg/L
Boron (B)
0.019 J
mg/L
Calcium (Ca)
21.6
mg/L
Iron (Fe)
0.054
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
0.294
mg/L
Manganese (Mn)
0.003 J
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040339
Antimony (Sb)
0.522 J
ug/L
Arsenic (As)
5.28
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
4.36
ug/L
Cobalt (Co)
0.077 U
ug/L
Copper (Cu)
1.32
ug/L
Lead (Pb)
0.149 J
ug/L
Molybdenum (Mo)
1.72
ug/L
Nickel (Ni)
1.38
ug/L
Selenium (Se)
0.22 J
ug/L
Silver (Ag)
0.085 J
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V)
8.44
ug/L
TOTAL DISSOLVED SOLIDS -
024040280
TDS 91.0 mg/L
Sample #: 2024006033
Matrix: GW RCRA
Page 9 of 47
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/18/2024 08:56
BGN9034
0.1
0.0479
1
EPA 9056A
04/18/2024 08:56
BGN9034
0.1
0.0209
1
EPA 9056A
04/18/2024 08:56
BGN9034
0.023
0.002
1
EPA 9056A
04/18/2024 08:56
BGN9034
0.5
0.0428
5
EPA 9056A
04/18/2024 08:56
BGN9034
0.05
0.01
1
EPA 7470A
04/24/2024 11:43
SNEGLIA
0.005
0.002
1
SW 601OD
04/25/2024 10:33
CELL106
0.05
0.005
1
SW 601OD
04/25/2024 10:33
CELL106
0.05
0.012
1
SW 601OD
04/25/2024 10:33
CELL106
0.01
0.004
1
SW 601OD
04/25/2024 10:33
CELL106
0.005
0.002
1
SW 601OD
04/25/2024 10:33
CELL106
0.02
0.008
1
SW 601OD
04/25/2024 10:33
CELL106
0.005
0.001
1
SW 601OD
04/25/2024 10:33
CELL106
0.015
0.004
1
SW 601OD
04/25/2024 10:33
CELL106
1
0.104
1
SW 6020B
04/24/2024 14:02
SNEGLIA
1
0.111
1
SW 6020B
04/24/2024 14:02
SNEGLIA
1
0.249
1
SW 6020E
04/24/2024 14:02
SNEGLIA
1
0.032
1
SW 6020E
04/24/2024 14:02
SNEGLIA
1
0.185
1
SW 6020B
04/24/2024 14:02
SNEGLIA
1
0.077
1
SW 6020E
04/24/2024 14:02
SNEGLIA
1
0.787
1
SW 6020B
04/24/2024 14:02
SNEGLIA
1
0.037
1
SW 6020E
04/24/2024 14:02
SNEGLIA
1
0.18
1
SW 6020E
04/24/2024 14:02
SNEGLIA
1
0.256
1
SW 6020B
04/24/2024 14:02
SNEGLIA
1
0.193
1
SW 6020B
04/24/2024 14:02
SNEGLIA
1
0.035
1
SW 6020E
04/24/2024 14:02
SNEGLIA
0.2
0.041
1
SW 6020B
04/24/2024 14:02
SNEGLIA
1
0.114
1
SW 6020E
04/24/2024 14:02
SNEGLIA
25
25
1
SM2540C
04/18/202413:55
HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030273
Site: CLS CCPMW-6S
Collection Date: 04/16/2024 02:55 PM Loc code: CLS CCPMW-6S
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q24040251
Chloride
4.6
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
14
mg/L
Nitrate as N
3.2
mg-N/L
Sulfate
2.5
mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040281
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040283
Barium (Ba)
0.042
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
1.74
mg/L
Iron (Fe)
0.321
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
2.08
mg/L
Manganese (Mn)
0.039
mg/L
Zinc (Zn)
0.005 J
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040287
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.134 J
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 J
ug/L
Chromium (Cr)
2.68
ug/L
Cobalt (Co)
1.51
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.205 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
2.74
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.119 J
ug/L
Vanadium (V)
0.462 J
ug/L
TOTAL DISSOLVED SOLIDS -
024040253
TDS 34.0 mg/L
Sample #: 2024006034
Matrix: GW RCRA
Page 10 of 47
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/17/2024 08:33
BGN9034
0.1
0.0479
1
EPA 9056A
04/17/2024 08:33
BGN9034
0.5
0.0209
5
EPA 9056A
04/17/2024 08:33
BGN9034
0.115
0.002
5
EPA 9056A
04/17/2024 08:33
BGN9034
0.1
0.0428
1
EPA 9056A
04/17/2024 08:33
BGN9034
0.05
0.01
1
EPA 7470A
04/18/2024 12:03
CWSPEN3
0.005
0.002
1
SW 601 OD
04/22/2024 01:05
CELL106
0.05
0.005
1
SW 601 OD
04/22/2024 01:05
CELL106
0.05
0.012
1
SW 601 OD
04/22/2024 01:05
CELL106
0.01
0.004
1
SW 601 OD
04/22/2024 01:05
CELL106
0.005
0.002
1
SW 601 OD
04/22/2024 01:05
CELL106
0.02
0.008
1
SW 601 OD
04/22/2024 01:05
CELL106
0.005
0.001
1
SW 601 OD
04/22/2024 01:05
CELL106
0.015
0.004
1
SW 601 OD
04/22/2024 01:05
CELL106
1
0.104
1
SW 6020B
04/22/2024 13:25
MHALL3
1
0.111
1
SW 6020B
04/22/2024 13:25
MHALL3
1
0.249
1
SW 6020E
04/22/2024 13:25
MHALL3
1
0.032
1
SW 6020E
04/22/2024 13:25
MHALL3
1
0.185
1
SW 6020B
04/22/2024 13:25
MHALL3
1
0.077
1
SW 6020E
04/22/2024 13:25
MHALL3
1
0.787
1
SW 6020B
04/22/2024 13:25
MHALL3
1
0.037
1
SW 6020E
04/22/2024 13:25
MHALL3
1
0.18
1
SW 6020E
04/22/2024 13:25
MHALL3
1
0.256
1
SW 6020B
04/22/2024 13:25
MHALL3
1
0.193
1
SW 6020B
04/22/2024 13:25
MHALL3
1
0.035
1
SW 6020E
04/22/2024 13:25
MHALL3
0.2
0.041
1
SW 6020B
04/22/2024 13:25
MHALL3
1
0.114
1
SW 6020E
04/22/2024 13:25
MHALL3
25
25
1
SM2540C
04/17/202411:45
HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030273
Site: CLS CCPMW-7
Collection Date: 04/16/2024 12:25 PM Loc code: CLS CCPMW-7
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q24040251
Chloride
11
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
9.1
mg/L
Nitrate as N
2.1
mg-N/L
Sulfate
0.43
mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040281
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040283
Barium (Ba)
0.042
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
5.05
mg/L
Iron (Fe)
0.049
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
1.99
mg/L
Manganese (Mn)
0.021
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040287
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.909 J
ug/L
Cobalt (Co)
0.086 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.038 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.944 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.057 J
ug/L
Vanadium (V)
0.146 J
ug/L
TOTAL DISSOLVED SOLIDS -
024040253
TDS 64.0 mg/L
Sample #: 2024006035
Matrix: GW RCRA
Page 11 of 47
Method Analysis Date/Time Analyst
0.5
0.0154
5
EPA 9056A
04/17/2024 08:49
BGN9034
0.1
0.0479
1
EPA 9056A
04/17/2024 08:49
BGN9034
0.5
0.0209
5
EPA 9056A
04/17/2024 08:49
BGN9034
0.115
0.002
5
EPA 9056A
04/17/2024 08:49
BGN9034
0.1
0.0428
1
EPA 9056A
04/17/2024 08:49
BGN9034
0.05
0.01
1
EPA 7470A
04/18/2024 12:05
CWSPEN3
0.005
0.002
1
SW 601 OD
04/22/2024 01:10
CELL106
0.05
0.005
1
SW 601 OD
04/22/2024 01:10
CELL106
0.05
0.012
1
SW 601 OD
04/22/2024 01:10
CELL106
0.01
0.004
1
SW 601 OD
04/22/2024 01:10
CELL106
0.005
0.002
1
SW 601 OD
04/22/2024 01:10
CELL106
0.02
0.008
1
SW 601 OD
04/22/2024 01:10
CELL106
0.005
0.001
1
SW 601 OD
04/22/2024 01:10
CELL106
0.015
0.004
1
SW 601 OD
04/22/2024 01:10
CELL106
1
0.104
1
SW 6020B
04/22/2024 13:35
MHALL3
1
0.111
1
SW 6020B
04/22/2024 13:35
MHALL3
1
0.249
1
SW 6020E
04/22/2024 13:35
MHALL3
1
0.032
1
SW 6020E
04/22/2024 13:35
MHALL3
1
0.185
1
SW 6020B
04/22/2024 13:35
MHALL3
1
0.077
1
SW 6020E
04/22/2024 13:35
MHALL3
1
0.787
1
SW 6020B
04/22/2024 13:35
MHALL3
1
0.037
1
SW 6020E
04/22/2024 13:35
MHALL3
1
0.18
1
SW 6020E
04/22/2024 13:35
MHALL3
1
0.256
1
SW 6020B
04/22/2024 13:35
MHALL3
1
0.193
1
SW 6020B
04/22/2024 13:35
MHALL3
1
0.035
1
SW 6020E
04/22/2024 13:35
MHALL3
0.2
0.041
1
SW 6020B
04/22/2024 13:35
MHALL3
1
0.114
1
SW 6020E
04/22/2024 13:35
MHALL3
25
25
1
SM2540C
04/17/202411:45
HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030273
Site: CLS CCPMW-10
Collection Date: 04/16/2024 03:55 PM Loc code: CLS CCPMW-10
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q24040251
Chloride
5.9
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
8.0
mg/L
Nitrate as N
1.8
mg-N/L
Sulfate
0.22
mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040281
Mercury (Hg)
0.03 J
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040283
Barium (Ba)
0.055
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
1.91
mg/L
Iron (Fe)
0.274
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
1.89
mg/L
Manganese (Mn)
0.021
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040287
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
1.80
ug/L
Cobalt (Co)
1.46
ug/L
Copper (Cu)
1.03
ug/L
Lead (Pb)
0.303 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
1.16
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.061 J
ug/L
Vanadium (V)
0.446 J
ug/L
TOTAL DISSOLVED SOLIDS -
024040253
TDS 41.0 mg/L
Sample #: 2024006036
Matrix: GW RCRA
Page 12 of 47
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/17/2024 09:36
BGN9034
0.1
0.0479
1
EPA 9056A
04/17/2024 09:36
BGN9034
0.1
0.0209
1
EPA 9056A
04/17/2024 09:36
BGN9034
0.023
0.002
1
EPA 9056A
04/17/2024 09:36
BGN9034
0.1
0.0428
1
EPA 9056A
04/17/2024 09:36
BGN9034
0.05
0.01
1
EPA 7470A
04/18/2024 12:07
CWSPEN3
0.005
0.002
1
SW 601 OD
04/22/2024 01:15
CELL106
0.05
0.005
1
SW 601 OD
04/22/2024 01:15
CELL106
0.05
0.012
1
SW 601 OD
04/22/2024 01:15
CELL106
0.01
0.004
1
SW 601 OD
04/22/2024 01:15
CELL106
0.005
0.002
1
SW 601 OD
04/22/2024 01:15
CELL106
0.02
0.008
1
SW 601 OD
04/22/2024 01:15
CELL106
0.005
0.001
1
SW 601 OD
04/22/2024 01:15
CELL106
0.015
0.004
1
SW 601 OD
04/22/2024 01:15
CELL106
1
0.104
1
SW 6020B
04/22/2024 13:44
MHALL3
1
0.111
1
SW 6020B
04/22/2024 13:44
MHALL3
1
0.249
1
SW 6020E
04/22/2024 13:44
MHALL3
1
0.032
1
SW 6020E
04/22/2024 13:44
MHALL3
1
0.185
1
SW 6020B
04/22/2024 13:44
MHALL3
1
0.077
1
SW 6020E
04/22/2024 13:44
MHALL3
1
0.787
1
SW 6020B
04/22/2024 13:44
MHALL3
1
0.037
1
SW 6020E
04/22/2024 13:44
MHALL3
1
0.18
1
SW 6020E
04/22/2024 13:44
MHALL3
1
0.256
1
SW 6020B
04/22/2024 13:44
MHALL3
1
0.193
1
SW 6020B
04/22/2024 13:44
MHALL3
1
0.035
1
SW 6020E
04/22/2024 13:44
MHALL3
0.2
0.041
1
SW 6020B
04/22/2024 13:44
MHALL3
1
0.114
1
SW 6020E
04/22/2024 13:44
MHALL3
25
25
1
SM2540C
04/17/202411:45
HHOOGKA

Certificate of Laboratory Analysis Page 13of47
This report shall not be reproduced, except in full.
Order # J24030273
Site: CLS CCPMW-11 Sample #: 2024006037
Collection Date: 04/16/2024 01:20 PM Loc code: CLS CCPMW-11 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q24040251
Chloride
5.2
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
6.2
mg/L
Nitrate as N
1.4
mg-N/L
Sulfate
0.46
mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040281
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040283
Barium (Ba)
0.037
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
2.32
mg/L
Iron (Fe)
0.094
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
1.96
mg/L
Manganese (Mn)
0.016
mg/L
Zinc (Zn)
0.005 J
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040287
Antimony (Sb)
0.184 J
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.944 J
ug/L
Cobalt (Co)
0.184 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.22 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
2.35
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.055 J
ug/L
Vanadium (V)
0.114 U
ug/L
TOTAL DISSOLVED SOLIDS -
024040253
TDS 37.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/17/2024 09:51
BGN9034
0.1
0.0479
1
EPA 9056A
04/17/2024 09:51
BGN9034
0.1
0.0209
1
EPA 9056A
04/17/2024 09:51
BGN9034
0.023
0.002
1
EPA 9056A
04/17/2024 09:51
BGN9034
0.1
0.0428
1
EPA 9056A
04/17/2024 09:51
BGN9034
0.05
0.01
1
EPA 7470A
04/18/2024 12:10
CWSPEN3
0.005
0.002
1
SW 601 OD
04/22/2024 01:20
CELL106
0.05
0.005
1
SW 601 OD
04/22/2024 01:20
CELL106
0.05
0.012
1
SW 601 OD
04/22/2024 01:20
CELL106
0.01
0.004
1
SW 601 OD
04/22/2024 01:20
CELL106
0.005
0.002
1
SW 601 OD
04/22/2024 01:20
CELL106
0.02
0.008
1
SW 601 OD
04/22/2024 01:20
CELL106
0.005
0.001
1
SW 601 OD
04/22/2024 01:20
CELL106
0.015
0.004
1
SW 601 OD
04/22/2024 01:20
CELL106
1
0.104
1
SW 6020B
04/22/2024 13:53
MHALL3
1
0.111
1
SW 6020B
04/22/2024 13:53
MHALL3
1
0.249
1
SW 6020E
04/22/2024 13:53
MHALL3
1
0.032
1
SW 6020E
04/22/2024 13:53
MHALL3
1
0.185
1
SW 6020B
04/22/2024 13:53
MHALL3
1
0.077
1
SW 6020E
04/22/2024 13:53
MHALL3
1
0.787
1
SW 6020B
04/22/2024 13:53
MHALL3
1
0.037
1
SW 6020E
04/22/2024 13:53
MHALL3
1
0.18
1
SW 6020E
04/22/2024 13:53
MHALL3
1
0.256
1
SW 6020B
04/22/2024 13:53
MHALL3
1
0.193
1
SW 6020B
04/22/2024 13:53
MHALL3
1
0.035
1
SW 6020E
04/22/2024 13:53
MHALL3
0.2
0.041
1
SW 6020B
04/22/2024 13:53
MHALL3
1
0.114
1
SW 6020E
04/22/2024 13:53
MHALL3
25
25
1
SM2540C
04/17/202411:45
HHOOGKA

Certificate of Laboratory Analysis Page 14of47
This report shall not be reproduced, except in full.
Order # J24030273
Site: CLS CCP-Leachate Sample #: 2024006038
Collection Date: 04/16/2024 11:30 AM Loc code: CLS CCP-Leachate Matrix: GW RCRA
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q24040251
Chloride
15000
mg/L
200
0.0154
2000
EPA 9056A
04/17/2024 10:38
BGN9034
Fluoride
0.0479 U
mg/L
20
0.0479
200
EPA 9056A
04/17/2024 10:38
BGN9034
Nitrate
54
mg/L
20
0.0209
200
EPA 9056A
04/17/2024 10:38
BGN9034
Nitrate as N
12
mg-N/L
4.6
0.002
200
EPA 9056A
04/17/2024 10:38
BGN9034
Sulfate
840
mg/L
20
0.0428
200
EPA 9056A
04/17/2024 10:38
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040281
Mercury (Hg)
0.02 J
ug/L
0.05
0.01
1
EPA 7470A
04/18/2024 13:13
CWSPEN3
TOTAL RECOVERABLE METALS BY ICP - Q24040283
Barium (Ba)
0.401
mg/L
0.005
0.002
1
SW 601 OD
04/22/2024 01:27
CELL106
Boron (B)
21.2
mg/L
0.5
0.005
10
SW 601 OD
04/22/2024 01:27
CELL106
Calcium (Ca)
7510
mg/L
5
0.012
100
SW 601 OD
04/22/2024 01:27
CELL106
Iron (Fe)
0.640
mg/L
0.01
0.004
1
SW 601 OD
04/22/2024 01:27
CELL106
Lithium (Li)
4.47
mg/L
0.005
0.002
1
SW 601 OD
04/22/2024 01:27
CELL106
Magnesium (Mg)
52.9
mg/L
0.02
0.008
1
SW 601 OD
04/22/2024 01:27
CELL106
Manganese (Mn)
13.6
mg/L
0.005
0.001
1
SW 601 OD
04/22/2024 01:27
CELL106
Zinc (Zn)
0.186
mg/L
0.015
0.004
1
SW 601 OD
04/22/2024 01:27
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040287
Antimony (Sb)
0.661 J
ug/L
10
0.104
10
SW 6020B
04/22/2024 16:22
MHALL3
Arsenic (As)
13.2
ug/L
10
0.111
10
SW 6020B
04/22/2024 16:22
MHALL3
Beryllium (Be)
1.17 J
ug/L
10
0.249
10
SW 6020E
04/22/2024 16:22
MHALL3
Cadmium (Cd)
2.12 J
ug/L
10
0.032
10
SW 6020E
04/22/2024 16:22
MHALL3
Chromium (Cr)
1.59 J
ug/L
10
0.185
10
SW 6020B
04/22/2024 16:22
MHALL3
Cobalt (Co)
670
ug/L
10
0.077
10
SW 6020E
04/22/2024 16:22
MHALL3
Copper (Cu)
44.0
ug/L
10
0.787
10
SW 6020B
04/22/2024 16:22
MHALL3
Lead (Pb)
99.2
ug/L
10
0.037
10
SW 6020E
04/22/2024 16:22
MHALL3
Molybdenum (Mo)
669
ug/L
10
0.18
10
SW 6020E
04/22/2024 16:22
MHALL3
Nickel (Ni)
118
ug/L
10
0.256
10
SW 6020B
04/22/2024 16:22
MHALL3
Selenium (Se)
72.2
ug/L
10
0.193
10
SW 6020B
04/22/2024 16:22
MHALL3
Silver (Ag)
0.182 J
ug/L
10
0.035
10
SW 6020E
04/22/2024 16:22
MHALL3
Thallium (TI) Low Level
11.6
ug/L
2
0.041
10
SW 6020B
04/22/2024 16:22
MHALL3
Vanadium (V)
4.23 J
ug/L
10
0.114
10
SW 6020E
04/22/2024 16:22
MHALL3
TOTAL DISSOLVED SOLIDS -
Q24040280
TDS
23900
mg/L
500
25
1
SM2540C
04/18/202413:55
HHOOGKA

Certificate of Laboratory Analysis Page 15of47
This report shall not be reproduced, except in full.
Order # J24030273
Site: CLS CCP-LEACHATE-34 Sample #: 2024006039
Collection Date: 04/16/2024 11:40 AM Loc code: CLS CCP-LEACHATE-34 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q24040252
Chloride
370
mg/L
Fluoride
0.26 J
mg/L
Nitrate
6.4
mg/L
Nitrate as N
1.4
mg-N/L
Sulfate
1200
mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040281
Mercury (Hg)
0.01 U
ug/L M
TOTAL RECOVERABLE METALS BY ICP - Q24040283
Barium (Ba)
0.061
mg/L
Boron (B)
4.19
mg/L
Calcium (Ca)
654
mg/L
Iron (Fe)
0.026
mg/L
Lithium (Li)
0.016
mg/L
Magnesium (Mg)
65.4
mg/L
Manganese (Mn)
0.143
mg/L
Zinc (Zn)
0.005 J
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040287
Antimony (Sb)
0.786 J
ug/L
Arsenic (As)
1.56
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.033 J
ug/L
Chromium (Cr)
0.634 J
ug/L
Cobalt (Co)
2.77
ug/L
Copper (Cu)
3.33
ug/L
Lead (Pb)
0.184 J
ug/L
Molybdenum (Mo)
25.3
ug/L
Nickel (Ni)
2.68
ug/L
Selenium (Se)
34.0
ug/L
Silver (Ag)
0.496 J
ug/L
Thallium (TI) Low Level
0.089 J
ug/L
Vanadium (V)
3.16
ug/L
TOTAL DISSOLVED SOLIDS -
024040253
TDS 247 mg/L
Method Analysis Date/Time Analyst
20
0.0154
200
EPA 9056A
04/17/2024 15:15
BGN9034
2
0.0479
20
EPA 9056A
04/17/2024 15:15
BGN9034
2
0.0209
20
EPA 9056A
04/17/2024 15:15
BGN9034
0.46
0.002
20
EPA 9056A
04/17/2024 15:15
BGN9034
20
0.0428
200
EPA 9056A
04/17/2024 15:15
BGN9034
0.05
0.01
1
EPA 7470A
04/18/2024 12:16
CWSPEN3
0.005
0.002
1
SW 601 OD
04/22/2024 01:39
CELL106
0.05
0.005
1
SW 601 OD
04/22/2024 01:39
CELL106
0.5
0.012
10
SW 601 OD
04/22/2024 01:39
CELL106
0.01
0.004
1
SW 601 OD
04/22/2024 01:39
CELL106
0.005
0.002
1
SW 601 OD
04/22/2024 01:39
CELL106
0.02
0.008
1
SW 601 OD
04/22/2024 01:39
CELL106
0.005
0.001
1
SW 601 OD
04/22/2024 01:39
CELL106
0.015
0.004
1
SW 601 OD
04/22/2024 01:39
CELL106
1
0.104
1
SW 6020B
04/24/2024 12:10
SNEGLIA
1
0.111
1
SW 6020B
04/24/2024 12:10
SNEGLIA
1
0.249
1
SW 6020E
04/24/2024 12:10
SNEGLIA
1
0.032
1
SW 6020E
04/24/2024 12:10
SNEGLIA
1
0.185
1
SW 6020B
04/24/2024 12:10
SNEGLIA
1
0.077
1
SW 6020E
04/24/2024 12:10
SNEGLIA
1
0.787
1
SW 6020B
04/24/2024 12:10
SNEGLIA
1
0.037
1
SW 6020E
04/24/2024 12:10
SNEGLIA
1
0.18
1
SW 6020E
04/24/2024 12:10
SNEGLIA
1
0.256
1
SW 6020B
04/24/2024 12:10
SNEGLIA
1
0.193
1
SW 6020B
04/24/2024 12:10
SNEGLIA
1
0.035
1
SW 6020E
04/24/2024 12:10
SNEGLIA
0.2
0.041
1
SW 6020B
04/24/2024 12:10
SNEGLIA
1
0.114
1
SW 6020E
04/24/2024 12:10
SNEGLIA
25
25
1
SM2540C
04/17/202411:45
HHOOGKA

Certificate of Laboratory Analysis Page 16of47
This report shall not be reproduced, except in full.
Order # J24030273
Site: CLS CCR-CCP-18S Sample #: 2024006040
Collection Date: 04/17/2024 01:00 PM Loc code: CLS CCR-CCP-18S Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q24040279
Chloride 6.5 mg/L
Fluoride 0.0479 U mg/L
Nitrate 9.2 mg/L
Nitrate as N 2.1 mg-N/L
Sulfate 0.60 mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040353
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040334
Barium (Ba)
0.027
mg/L
Boron (B)
0.01 J
mg/L
Calcium (Ca)
3.52
mg/L
Iron (Fe)
0.013
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
1.74
mg/L
Manganese (Mn)
0.005 J
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040339
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.662 J
ug/L
Cobalt (Co)
0.245 J
ug/L
Copper (Cu)
0.952 J
ug/L
Lead (Pb)
0.065 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.869 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.143 J
ug/L
Thallium (TI) Low Level
0.049 J
ug/L
Vanadium (V)
0.114 U
ug/L
TOTAL DISSOLVED SOLIDS -
024040280
TDS 43.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/18/2024 09:12
BGN9034
0.1
0.0479
1
EPA 9056A
04/18/2024 09:12
BGN9034
0.1
0.0209
1
EPA 9056A
04/18/2024 09:12
BGN9034
0.023
0.002
1
EPA 9056A
04/18/2024 09:12
BGN9034
0.1
0.0428
1
EPA 9056A
04/18/2024 09:12
BGN9034
0.05
0.01
1
EPA 7470A
04/24/2024 11:49
SNEGLIA
0.005
0.002
1
SW 601OD
04/25/2024 10:49
CELL106
0.05
0.005
1
SW 601OD
04/25/2024 10:49
CELL106
0.05
0.012
1
SW 601OD
04/25/2024 10:49
CELL106
0.01
0.004
1
SW 601OD
04/25/2024 10:49
CELL106
0.005
0.002
1
SW 601OD
04/25/2024 10:49
CELL106
0.02
0.008
1
SW 601OD
04/25/2024 10:49
CELL106
0.005
0.001
1
SW 601OD
04/25/2024 10:49
CELL106
0.015
0.004
1
SW 601OD
04/25/2024 10:49
CELL106
1
0.104
1
SW 6020B
04/24/2024 13:15
SNEGLIA
1
0.111
1
SW 6020B
04/24/2024 13:15
SNEGLIA
1
0.249
1
SW 6020E
04/24/2024 13:15
SNEGLIA
1
0.032
1
SW 6020E
04/24/2024 13:15
SNEGLIA
1
0.185
1
SW 6020B
04/24/2024 13:15
SNEGLIA
1
0.077
1
SW 6020E
04/24/2024 13:15
SNEGLIA
1
0.787
1
SW 6020B
04/24/2024 13:15
SNEGLIA
1
0.037
1
SW 6020E
04/24/2024 13:15
SNEGLIA
1
0.18
1
SW 6020E
04/24/2024 13:15
SNEGLIA
1
0.256
1
SW 6020B
04/24/2024 13:15
SNEGLIA
1
0.193
1
SW 6020B
04/24/2024 13:15
SNEGLIA
1
0.035
1
SW 6020E
04/24/2024 13:15
SNEGLIA
0.2
0.041
1
SW 6020B
04/24/2024 13:15
SNEGLIA
1
0.114
1
SW 6020E
04/24/2024 13:15
SNEGLIA
25
25
1
SM2540C
04/18/202413:55
HHOOGKA

Certificate of Laboratory Analysis Page 17of47
This report shall not be reproduced, except in full.
Order # J24030273
Site: CLS CCR-CCP-19S Sample #: 2024006041
Collection Date: 04/16/2024 01:05 PM Loc code: CLS CCR-CCP-19S Matrix: GW RCRA
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q24040252
Chloride
71
mg/L
5
0.0154
50
EPA 9056A
04/17/2024 11:06
BGN9034
Fluoride
0.0479 U
mg/L
0.5
0.0479
5
EPA 9056A
04/17/2024 11:06
BGN9034
Nitrate
16
mg/L
0.5
0.0209
5
EPA 9056A
04/17/2024 11:06
BGN9034
Nitrate as N
3.6
mg-N/L
0.115
0.002
5
EPA 9056A
04/17/2024 11:06
BGN9034
Sulfate
1.1
mg/L
0.5
0.0428
5
EPA 9056A
04/17/2024 11:06
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040281
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/18/2024 12:23
CWSPEN3
TOTAL RECOVERABLE METALS BY ICP - Q24040283
Barium (Ba)
0.183
mg/L
0.005
0.002
1
SW 601 OD
04/22/2024 01:44
CELL106
Boron (B)
0.009 J
mg/L
0.05
0.005
1
SW 601 OD
04/22/2024 01:44
CELL106
Calcium (Ca)
21.1
mg/L
0.05
0.012
1
SW 601 OD
04/22/2024 01:44
CELL106
Iron (Fe)
0.166
mg/L
0.01
0.004
1
SW 601 OD
04/22/2024 01:44
CELL106
Lithium (Li)
0.002 U
mg/L
0.005
0.002
1
SW 601 OD
04/22/2024 01:44
CELL106
Magnesium (Mg)
12.6
mg/L
0.02
0.008
1
SW 601 OD
04/22/2024 01:44
CELL106
Manganese (Mn)
0.108
mg/L
0.005
0.001
1
SW 601 OD
04/22/2024 01:44
CELL106
Zinc (Zn)
0.008 J
mg/L
0.015
0.004
1
SW 601 OD
04/22/2024 01:44
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040287
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
04/22/2024 14:02
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
04/22/2024 14:02
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020E
04/22/2024 14:02
MHALL3
Cadmium (Cd)
0.062 J
ug/L
1
0.032
1
SW 6020E
04/22/2024 14:02
MHALL3
Chromium (Cr)
1.24
ug/L
1
0.185
1
SW 6020B
04/22/2024 14:02
MHALL3
Cobalt (Co)
0.681 J
ug/L
1
0.077
1
SW 6020E
04/22/2024 14:02
MHALL3
Copper (Cu)
1.36
ug/L
1
0.787
1
SW 6020B
04/22/2024 14:02
MHALL3
Lead (Pb)
0.178 J
ug/L
1
0.037
1
SW 6020E
04/22/2024 14:02
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020E
04/22/2024 14:02
MHALL3
Nickel (Ni)
4.60
ug/L
1
0.256
1
SW 6020B
04/22/2024 14:02
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
04/22/2024 14:02
MHALL3
Silver (Ag)
0.493 J
ug/L
1
0.035
1
SW 6020E
04/22/2024 14:02
MHALL3
Thallium (TI) Low Level
0.089 J
ug/L
0.2
0.041
1
SW 6020B
04/22/2024 14:02
MHALL3
Vanadium (V)
0.4 J
ug/L
1
0.114
1
SW 6020E
04/22/2024 14:02
MHALL3
TOTAL DISSOLVED SOLIDS -
Q24040253
TDS
2670
mg/L
50
25
1
SM2540C
04/17/202411:45
HHOOGKA

Certificate of Laboratory Analysis Page 18of47
This report shall not be reproduced, except in full.
Order # J24030273
Site: CLS CCR-CCP-20D Sample #: 2024006042
Collection Date: 04/16/2024 01:30 PM Loc code: CLS CCR-CCP-20D Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q24040252
Chloride
11
mg/L
Fluoride
0.05 J
mg/L
Nitrate
0.05 J
mg/L
Nitrate as N
0.01 J
mg-N/L
Sulfate
24
mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040281
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040283
Barium (Ba)
0.004 J
mg/L
Boron (B)
0.007 J
mg/L
Calcium (Ca)
18.5
mg/L
Iron (Fe)
1.17
mg/L
Lithium (Li)
0.003 J
mg/L
Magnesium (Mg)
1.53
mg/L
Manganese (Mn)
0.064
mg/L
Zinc (Zn)
0.005 J
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040287
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.341 J
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.24 J
ug/L
Cobalt (Co)
0.077 U
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
1.25
ug/L
Nickel (Ni)
0.652 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V)
0.114 U
ug/L
TOTAL DISSOLVED SOLIDS -
024040253
TDS 120 mg/L
Method Analysis Date/Time Analyst
0.5
0.0154
5
EPA 9056A
04/17/2024 13:58
BGN9034
0.1
0.0479
1
EPA 9056A
04/17/2024 13:58
BGN9034
0.1
0.0209
1
EPA 9056A
04/17/2024 13:58
BGN9034
0.023
0.002
1
EPA 9056A
04/17/2024 13:58
BGN9034
0.5
0.0428
5
EPA 9056A
04/17/2024 13:58
BGN9034
0.05
0.01
1
EPA 7470A
04/18/2024 12:25
CWSPEN3
0.005
0.002
1
SW 601 OD
04/22/2024 01:49
CELL106
0.05
0.005
1
SW 601 OD
04/22/2024 01:49
CELL106
0.05
0.012
1
SW 601 OD
04/22/2024 01:49
CELL106
0.01
0.004
1
SW 601 OD
04/22/2024 01:49
CELL106
0.005
0.002
1
SW 601 OD
04/22/2024 01:49
CELL106
0.02
0.008
1
SW 601 OD
04/22/2024 01:49
CELL106
0.005
0.001
1
SW 601 OD
04/22/2024 01:49
CELL106
0.015
0.004
1
SW 601 OD
04/22/2024 01:49
CELL106
1
0.104
1
SW 6020B
04/22/2024 14:40
MHALL3
1
0.111
1
SW 6020B
04/22/2024 14:40
MHALL3
1
0.249
1
SW 6020E
04/22/2024 14:40
MHALL3
1
0.032
1
SW 6020E
04/22/2024 14:40
MHALL3
1
0.185
1
SW 6020B
04/22/2024 14:40
MHALL3
1
0.077
1
SW 6020E
04/22/2024 14:40
MHALL3
1
0.787
1
SW 6020B
04/22/2024 14:40
MHALL3
1
0.037
1
SW 6020E
04/22/2024 14:40
MHALL3
1
0.18
1
SW 6020E
04/22/2024 14:40
MHALL3
1
0.256
1
SW 6020B
04/22/2024 14:40
MHALL3
1
0.193
1
SW 6020B
04/22/2024 14:40
MHALL3
1
0.035
1
SW 6020E
04/22/2024 14:40
MHALL3
0.2
0.041
1
SW 6020B
04/22/2024 14:40
MHALL3
1
0.114
1
SW 6020E
04/22/2024 14:40
MHALL3
25
25
1
SM2540C
04/17/202411:45
HHOOGKA

Certificate of Laboratory Analysis Page 19of47
This report shall not be reproduced, except in full.
Order # J24030273
Site: CLS CCR-CCPMW-8D Sample #: 2024006043
Collection Date: 04/16/2024 02:20 PM Loc code: CLS CCR-CCPMW-8D Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q24040252
Chloride
27
mg/L
Fluoride
0.08 J
mg/L
Nitrate
9.0
mg/L
Nitrate as N
2.0
mg-N/L
Sulfate
33
mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040281
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040283
Barium (Ba)
0.027
mg/L
Boron (B)
0.008 J
mg/L
Calcium (Ca)
11.2
mg/L
Iron (Fe)
0.017
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
2.23
mg/L
Manganese (Mn)
0.027
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040287
Antimony (Sb)
0.566 J
ug/L
Arsenic (As)
0.61 J
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.787 J
ug/L
Cobalt (Co)
0.08 J
ug/L
Copper (Cu)
1.47
ug/L
Lead (Pb)
0.042 J
ug/L
Molybdenum (Mo)
5.47
ug/L
Nickel (Ni)
0.902 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V)
2.59
ug/L
TOTAL DISSOLVED SOLIDS -
024040253
TDS 146 mg/L
Method Analysis Date/Time Analyst
0.5
0.0154
5
EPA 9056A
04/17/2024 14:13
BGN9034
0.1
0.0479
1
EPA 9056A
04/17/2024 14:13
BGN9034
0.1
0.0209
1
EPA 9056A
04/17/2024 14:13
BGN9034
0.023
0.002
1
EPA 9056A
04/17/2024 14:13
BGN9034
0.5
0.0428
5
EPA 9056A
04/17/2024 14:13
BGN9034
0.05
0.01
1
EPA 7470A
04/18/2024 12:28
CWSPEN3
0.005
0.002
1
SW 601 OD
04/22/2024 01:54
CELL106
0.05
0.005
1
SW 601 OD
04/22/2024 01:54
CELL106
0.05
0.012
1
SW 601 OD
04/22/2024 01:54
CELL106
0.01
0.004
1
SW 601 OD
04/22/2024 01:54
CELL106
0.005
0.002
1
SW 601 OD
04/22/2024 01:54
CELL106
0.02
0.008
1
SW 601 OD
04/22/2024 01:54
CELL106
0.005
0.001
1
SW 601 OD
04/22/2024 01:54
CELL106
0.015
0.004
1
SW 601 OD
04/22/2024 01:54
CELL106
1
0.104
1
SW 6020B
04/22/2024 14:49
MHALL3
1
0.111
1
SW 6020B
04/22/2024 14:49
MHALL3
1
0.249
1
SW 6020E
04/22/2024 14:49
MHALL3
1
0.032
1
SW 6020E
04/22/2024 14:49
MHALL3
1
0.185
1
SW 6020B
04/22/2024 14:49
MHALL3
1
0.077
1
SW 6020E
04/22/2024 14:49
MHALL3
1
0.787
1
SW 6020B
04/22/2024 14:49
MHALL3
1
0.037
1
SW 6020E
04/22/2024 14:49
MHALL3
1
0.18
1
SW 6020E
04/22/2024 14:49
MHALL3
1
0.256
1
SW 6020B
04/22/2024 14:49
MHALL3
1
0.193
1
SW 6020B
04/22/2024 14:49
MHALL3
1
0.035
1
SW 6020E
04/22/2024 14:49
MHALL3
0.2
0.041
1
SW 6020B
04/22/2024 14:49
MHALL3
1
0.114
1
SW 6020E
04/22/2024 14:49
MHALL3
25
25
1
SM2540C
04/17/202411:45
HHOOGKA

Certificate of Laboratory Analysis Page 20 of 47
This report shall not be reproduced, except in full.
Order # J24030273
Site: CLS CCR-CCPTW-2D Sample #: 2024006044
Collection Date: 04/16/2024 11:00 AM Loc code: CLS CCR-CCPTW-2D Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q24040252
Chloride
6.0
mg/L
Fluoride
0.11
mg/L
Nitrate
0.20
mg/L
Nitrate as N
0.04
mg-N/L
Sulfate
17
mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040281
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040283
Barium (Ba)
0.002 U
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
10.3
mg/L
Iron (Fe)
2.02
mg/L
Lithium (Li)
0.003 J
mg/L
Magnesium (Mg)
1.91
mg/L
Manganese (Mn)
0.041
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040287
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.185 U
ug/L
Cobalt (Co)
0.077 U
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.866 J
ug/L
Nickel (Ni)
0.256 U
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V)
0.114 U
ug/L
TOTAL DISSOLVED SOLIDS -
024040253
TDS 89.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/17/2024 14:28
BGN9034
0.1
0.0479
1
EPA 9056A
04/17/2024 14:28
BGN9034
0.1
0.0209
1
EPA 9056A
04/17/2024 14:28
BGN9034
0.023
0.002
1
EPA 9056A
04/17/2024 14:28
BGN9034
0.5
0.0428
5
EPA 9056A
04/17/2024 14:28
BGN9034
0.05
0.01
1
EPA 7470A
04/18/2024 12:30
CWSPEN3
0.005
0.002
1
SW 601 OD
04/22/2024 01:59
CELL106
0.05
0.005
1
SW 601 OD
04/22/2024 01:59
CELL106
0.05
0.012
1
SW 601 OD
04/22/2024 01:59
CELL106
0.01
0.004
1
SW 601 OD
04/22/2024 01:59
CELL106
0.005
0.002
1
SW 601 OD
04/22/2024 01:59
CELL106
0.02
0.008
1
SW 601 OD
04/22/2024 01:59
CELL106
0.005
0.001
1
SW 601 OD
04/22/2024 01:59
CELL106
0.015
0.004
1
SW 601 OD
04/22/2024 01:59
CELL106
1
0.104
1
SW 6020B
04/22/2024 14:58
MHALL3
1
0.111
1
SW 6020B
04/22/2024 14:58
MHALL3
1
0.249
1
SW 6020E
04/22/2024 14:58
MHALL3
1
0.032
1
SW 6020E
04/22/2024 14:58
MHALL3
1
0.185
1
SW 6020B
04/22/2024 14:58
MHALL3
1
0.077
1
SW 6020E
04/22/2024 14:58
MHALL3
1
0.787
1
SW 6020B
04/22/2024 14:58
MHALL3
1
0.037
1
SW 6020E
04/22/2024 14:58
MHALL3
1
0.18
1
SW 6020E
04/22/2024 14:58
MHALL3
1
0.256
1
SW 6020B
04/22/2024 14:58
MHALL3
1
0.193
1
SW 6020B
04/22/2024 14:58
MHALL3
1
0.035
1
SW 6020E
04/22/2024 14:58
MHALL3
0.2
0.041
1
SW 6020B
04/22/2024 14:58
MHALL3
1
0.114
1
SW 6020E
04/22/2024 14:58
MHALL3
25
25
1
SM2540C
04/17/202411:45
HHOOGKA

Certificate of Laboratory Analysis Page21 of47
This report shall not be reproduced, except in full.
Order # J24030273
Site: CLS CCR-CCPBG-1 D Sample #: 2024006045
Collection Date: 04/16/2024 01:10 PM Loc code: CLS CCR-CCPBG-1 D Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q24040251
Chloride
9.0
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
16
mg/L
Nitrate as N
3.6
mg-N/L
Sulfate
0.46
mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040281
Mercury (Hg)
0.02 J
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040283
Barium (Ba)
0.031
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
3.60
mg/L
Iron (Fe)
0.306
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
2.27
mg/L
Manganese (Mn)
0.033
mg/L
Zinc (Zn)
0.004 J
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040287
Antimony (Sb)
0.127 J
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
2.29
ug/L
Cobalt (Co)
0.872 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.142 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
1.95
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.067 J
ug/L
Vanadium (V)
0.42 J
ug/L
TOTAL DISSOLVED SOLIDS -
024040280
TDS 54.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/17/2024 11:40
BGN9034
0.1
0.0479
1
EPA 9056A
04/17/2024 11:40
BGN9034
0.5
0.0209
5
EPA 9056A
04/17/2024 11:40
BGN9034
0.115
0.002
5
EPA 9056A
04/17/2024 11:40
BGN9034
0.1
0.0428
1
EPA 9056A
04/17/2024 11:40
BGN9034
0.05
0.01
1
EPA 7470A
04/18/2024 12:32
CWSPEN3
0.005
0.002
1
SW 601 OD
04/22/2024 02:04
CELL106
0.05
0.005
1
SW 601 OD
04/22/2024 02:04
CELL106
0.05
0.012
1
SW 601 OD
04/22/2024 02:04
CELL106
0.01
0.004
1
SW 601 OD
04/22/2024 02:04
CELL106
0.005
0.002
1
SW 601 OD
04/22/2024 02:04
CELL106
0.02
0.008
1
SW 601 OD
04/22/2024 02:04
CELL106
0.005
0.001
1
SW 601 OD
04/22/2024 02:04
CELL106
0.015
0.004
1
SW 601 OD
04/22/2024 02:04
CELL106
1
0.104
1
SW 6020B
04/22/2024 15:08
MHALL3
1
0.111
1
SW 6020B
04/22/2024 15:08
MHALL3
1
0.249
1
SW 6020E
04/22/2024 15:08
MHALL3
1
0.032
1
SW 6020E
04/22/2024 15:08
MHALL3
1
0.185
1
SW 6020B
04/22/2024 15:08
MHALL3
1
0.077
1
SW 6020E
04/22/2024 15:08
MHALL3
1
0.787
1
SW 6020B
04/22/2024 15:08
MHALL3
1
0.037
1
SW 6020E
04/22/2024 15:08
MHALL3
1
0.18
1
SW 6020E
04/22/2024 15:08
MHALL3
1
0.256
1
SW 6020B
04/22/2024 15:08
MHALL3
1
0.193
1
SW 6020B
04/22/2024 15:08
MHALL3
1
0.035
1
SW 6020E
04/22/2024 15:08
MHALL3
0.2
0.041
1
SW 6020B
04/22/2024 15:08
MHALL3
1
0.114
1
SW 6020E
04/22/2024 15:08
MHALL3
25
25
1
SM2540C
04/18/202413:55
HHOOGKA

Certificate of Laboratory Analysis Page 22 of 47
This report shall not be reproduced, except in full.
Order # J24030273
Site: CLS CCR-CCPBG-1 BR Sample #: 2024006046
Collection Date: 04/16/2024 10:50 AM Loc code: CLS CCR-CCPBG-1 BR Matrix: GW RCRA
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q24040251
Chloride
98
mg/L
5
0.0154
50
EPA 9056A
04/17/2024 11:56
BGN9034
Fluoride
0.1 J
mg/L
0.5
0.0479
5
EPA 9056A
04/17/2024 11:56
BGN9034
Nitrate
1.9
mg/L
0.5
0.0209
5
EPA 9056A
04/17/2024 11:56
BGN9034
Nitrate as N
0.43
mg-N/L
0.115
0.002
5
EPA 9056A
04/17/2024 11:56
BGN9034
Sulfate
140
mg/L
5
0.0428
50
EPA 9056A
04/17/2024 11:56
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24040281
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
04/18/2024 12:34
CWSPEN3
TOTAL RECOVERABLE METALS BY ICP - Q24040283
Barium (Ba)
0.004 J
mg/L
0.005
0.002
1
SW 601 OD
04/22/2024 02:08
CELL106
Boron (B)
0.009 J
mg/L
0.05
0.005
1
SW 601 OD
04/22/2024 02:08
CELL106
Calcium (Ca)
33.3
mg/L
0.05
0.012
1
SW 601 OD
04/22/2024 02:08
CELL106
Iron (Fe)
0.027
mg/L
0.01
0.004
1
SW 601 OD
04/22/2024 02:08
CELL106
Lithium (Li)
0.012
mg/L
0.005
0.002
1
SW 601 OD
04/22/2024 02:08
CELL106
Magnesium (Mg)
2.08
mg/L
0.02
0.008
1
SW 601 OD
04/22/2024 02:08
CELL106
Manganese (Mn)
0.015
mg/L
0.005
0.001
1
SW 601 OD
04/22/2024 02:08
CELL106
Zinc (Zn)
0.004 U
mg/L
0.015
0.004
1
SW 601 OD
04/22/2024 02:08
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040287
Antimony (Sb)
0.153 J
ug/L
1
0.104
1
SW 6020B
04/22/2024 15:17
MHALL3
Arsenic (As)
0.962 J
ug/L
1
0.111
1
SW 6020B
04/22/2024 15:17
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020E
04/22/2024 15:17
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020E
04/22/2024 15:17
MHALL3
Chromium (Cr)
2.12
ug/L
1
0.185
1
SW 6020B
04/22/2024 15:17
MHALL3
Cobalt (Co)
0.077 U
ug/L
1
0.077
1
SW 6020E
04/22/2024 15:17
MHALL3
Copper (Cu)
0.787 U
ug/L
1
0.787
1
SW 6020B
04/22/2024 15:17
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020E
04/22/2024 15:17
MHALL3
Molybdenum (Mo)
16.0
ug/L
1
0.18
1
SW 6020E
04/22/2024 15:17
MHALL3
Nickel (Ni)
1.96
ug/L
1
0.256
1
SW 6020B
04/22/2024 15:17
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
04/22/2024 15:17
MHALL3
Silver (Ag)
0.196 J
ug/L
1
0.035
1
SW 6020E
04/22/2024 15:17
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
04/22/2024 15:17
MHALL3
Vanadium (V)
0.732 J
ug/L
1
0.114
1
SW 6020E
04/22/2024 15:17
MHALL3
TOTAL DISSOLVED SOLIDS -
Q24040280
TDS
435
mg/L
25
25
1
SM2540C
04/18/202413:55
HHOOGKA

Certificate of Laboratory Analysis Page 23 of 47
This report shall not be reproduced, except in full.
Order # J24030273
Site: CLS CCPSW-1 Sample #: 2024006047
Collection Date: 04/16/2024 10:40 AM Loc code: CLS CCPSW-1 Matrix: GW RCRA
Analyte Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q24040252
Chloride 3.6
mg/L
0.1
0.0154
1
EPA 9056A
04/17/2024 09:47
BGN9034
Fluoride 0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
04/17/2024 09:47
BGN9034
Nitrate 1.8
mg/L
0.1
0.0209
1
EPA 9056A
04/17/2024 09:47
BGN9034
Nitrate as N 0.41
mg-N/L
0.023
0.002
1
EPA 9056A
04/17/2024 09:47
BGN9034
Sulfate 1.4
mg/L
0.1
0.0428
1
EPA 9056A
04/17/2024 09:47
BGN9034
TOTAL DISSOLVED SOLIDS - Q24040253
TDS 26.0
mg/L
25
25
1
SM2540C
04/17/202411:45
HHOOGKA

Certificate of Laboratory Analysis Page 24 of 47
This report shall not be reproduced, except in full.
Order # J24030273
Site: CLS CCPSW-2 Sample #: 2024006071
Collection Date: 04/16/2024 11:05 AM Loc code: CLS CCPSW-2 Matrix: GW RCRA
Analyte Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q24040252
Chloride 3.7
mg/L
0.1
0.0154
1
EPA 9056A
04/17/2024 10:34
BGN9034
Fluoride 0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
04/17/2024 10:34
BGN9034
Nitrate 2.0
mg/L
0.1
0.0209
1
EPA 9056A
04/17/2024 10:34
BGN9034
Nitrate as N 0.45
mg-N/L
0.023
0.002
1
EPA 9056A
04/17/2024 10:34
BGN9034
Sulfate 1.7
mg/L
0.1
0.0428
1
EPA 9056A
04/17/2024 10:34
BGN9034
TOTAL DISSOLVED SOLIDS - Q24040253
TDS 32.0
mg/L
25
25
1
SM2540C
04/17/202411:45
HHOOGKA

Certificate of Laboratory Analysis Page 25 of 47
This report shall not be reproduced, except in full.
Order # J24030273
Site: CLS_FD-20240416-1 Duplicate Sample #: 2024006073
Collection Date: 04/16/2024 Loc code: CLS FD Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q24040252
Chloride
8.1
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
1.9
mg/L
Nitrate as N
0.42
mg-N/L
Sulfate
1.4
mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040281
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040283
Barium (Ba)
0.017
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
2.84
mg/L
Iron (Fe)
0.004 J
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
1.49
mg/L
Manganese (Mn)
0.007
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040287
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.195 J
ug/L
Cobalt (Co)
0.298 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.824 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V)
0.114 U
ug/L
TOTAL DISSOLVED SOLIDS -
024040253
TDS 36.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/17/2024 10:50
BGN9034
0.1
0.0479
1
EPA 9056A
04/17/2024 10:50
BGN9034
0.1
0.0209
1
EPA 9056A
04/17/2024 10:50
BGN9034
0.023
0.002
1
EPA 9056A
04/17/2024 10:50
BGN9034
0.1
0.0428
1
EPA 9056A
04/17/2024 10:50
BGN9034
0.05
0.01
1
EPA 7470A
04/18/2024 12:48
CWSPEN3
0.005
0.002
1
SW 601 OD
04/22/2024 02:23
CELL106
0.05
0.005
1
SW 601 OD
04/22/2024 02:23
CELL106
0.05
0.012
1
SW 601 OD
04/22/2024 02:23
CELL106
0.01
0.004
1
SW 601 OD
04/22/2024 02:23
CELL106
0.005
0.002
1
SW 601 OD
04/22/2024 02:23
CELL106
0.02
0.008
1
SW 601 OD
04/22/2024 02:23
CELL106
0.005
0.001
1
SW 601 OD
04/22/2024 02:23
CELL106
0.015
0.004
1
SW 601 OD
04/22/2024 02:23
CELL106
1
0.104
1
SW 6020B
04/22/2024 15:45
MHALL3
1
0.111
1
SW 6020B
04/22/2024 15:45
MHALL3
1
0.249
1
SW 6020E
04/22/2024 15:45
MHALL3
1
0.032
1
SW 6020E
04/22/2024 15:45
MHALL3
1
0.185
1
SW 6020B
04/22/2024 15:45
MHALL3
1
0.077
1
SW 6020E
04/22/2024 15:45
MHALL3
1
0.787
1
SW 6020B
04/22/2024 15:45
MHALL3
1
0.037
1
SW 6020E
04/22/2024 15:45
MHALL3
1
0.18
1
SW 6020E
04/22/2024 15:45
MHALL3
1
0.256
1
SW 6020B
04/22/2024 15:45
MHALL3
1
0.193
1
SW 6020B
04/22/2024 15:45
MHALL3
1
0.035
1
SW 6020E
04/22/2024 15:45
MHALL3
0.2
0.041
1
SW 6020B
04/22/2024 15:45
MHALL3
1
0.114
1
SW 6020E
04/22/2024 15:45
MHALL3
25
25
1
SM2540C
04/17/202411:45
HHOOGKA

Certificate of Laboratory Analysis Page 26 of 47
This report shall not be reproduced, except in full.
Order # J24030273
Site: CLS FB-20240416-1400 Field Blank Sample #: 2024006074
Collection Date: 04/16/2024 02:00 PM Loc code: CLS QA Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q24040252
Chloride 0.0154 U mg/L
Fluoride 0.0479 U mg/L
Nitrate 0.1 J mg/L
Nitrate as N 0.02 J mg-N/L
Sulfate 0.0428 U mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040281
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040334
Barium (Ba)
0.002 U
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
0.018 J
mg/L
Iron (Fe)
0.006 J
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
0.008 U
mg/L
Manganese (Mn)
0.001 U
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040339
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.185 U
ug/L
Cobalt (Co)
0.077 U
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.256 U
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.062 J
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V)
0.114 U
ug/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/17/2024 07:44
BGN9034
0.1
0.0479
1
EPA 9056A
04/17/2024 07:44
BGN9034
0.1
0.0209
1
EPA 9056A
04/17/2024 07:44
BGN9034
0.023
0.002
1
EPA 9056A
04/17/2024 07:44
BGN9034
0.1
0.0428
1
EPA 9056A
04/17/2024 07:44
BGN9034
0.05
0.01
1
EPA 7470A
04/18/2024 12:41
CWSPEN3
0.005
0.002
1
SW 601OD
04/25/2024 10:54
CELL106
0.05
0.005
1
SW 601OD
04/25/2024 10:54
CELL106
0.05
0.012
1
SW 601OD
04/25/2024 10:54
CELL106
0.01
0.004
1
SW 601OD
04/25/2024 10:54
CELL106
0.005
0.002
1
SW 601OD
04/25/2024 10:54
CELL106
0.02
0.008
1
SW 601OD
04/25/2024 10:54
CELL106
0.005
0.001
1
SW 601OD
04/25/2024 10:54
CELL106
0.015
0.004
1
SW 601OD
04/25/2024 10:54
CELL106
1
0.104
1
SW 6020B
04/24/2024 14:11
SNEGLIA
1
0.111
1
SW 6020B
04/24/2024 14:11
SNEGLIA
1
0.249
1
SW 6020E
04/24/2024 14:11
SNEGLIA
1
0.032
1
SW 6020E
04/24/2024 14:11
SNEGLIA
1
0.185
1
SW 6020B
04/24/2024 14:11
SNEGLIA
1
0.077
1
SW 6020E
04/24/2024 14:11
SNEGLIA
1
0.787
1
SW 6020B
04/24/2024 14:11
SNEGLIA
1
0.037
1
SW 6020E
04/24/2024 14:11
SNEGLIA
1
0.18
1
SW 6020E
04/24/2024 14:11
SNEGLIA
1
0.256
1
SW 6020B
04/24/2024 14:11
SNEGLIA
1
0.193
1
SW 6020B
04/24/2024 14:11
SNEGLIA
1
0.035
1
SW 6020E
04/24/2024 14:11
SNEGLIA
0.2
0.041
1
SW 6020B
04/24/2024 14:11
SNEGLIA
1
0.114
1
SW 6020E
04/24/2024 14:11
SNEGLIA

Certificate of Laboratory Analysis Page 27 of 47
This report shall not be reproduced, except in full.
Order # J24030273
Site: CLS_FD-20240416-2 Duplicate Sample #: 2024006075
Collection Date: 04/16/2024 Loc code: CLS FD Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q24040252
Chloride 5.3 mg/L
Fluoride 0.11 mg/L
Nitrate 0.14 mg/L
Nitrate as N 0.03 mg-N/L
Sulfate 16 mg/L
MERCURY (COLD VAPOR) IN WATER - Q24040281
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q24040334
Barium (Ba)
0.002 U
mg/L
Boron (B)
0.006 J
mg/L
Calcium (Ca)
9.94
mg/L
Iron (Fe)
2.18
mg/L
Lithium (Li)
0.003 J
mg/L
Magnesium (Mg)
1.84
mg/L
Manganese (Mn)
0.037
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q24040339
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.229 J
ug/L
Cobalt (Co)
0.077 U
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.684 J
ug/L
Nickel (Ni)
0.256 U
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.054 J
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V)
0.114 U
ug/L
TOTAL DISSOLVED SOLIDS -
024040253
TDS 99.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/17/2024 14:44
BGN9034
0.1
0.0479
1
EPA 9056A
04/17/2024 14:44
BGN9034
0.1
0.0209
1
EPA 9056A
04/17/2024 14:44
BGN9034
0.023
0.002
1
EPA 9056A
04/17/2024 14:44
BGN9034
0.5
0.0428
5
EPA 9056A
04/17/2024 14:44
BGN9034
0.05
0.01
1
EPA 7470A
04/18/2024 12:55
CWSPEN3
0.005
0.002
1
SW 601OD
04/25/2024 10:59
CELL106
0.05
0.005
1
SW 601OD
04/25/2024 10:59
CELL106
0.05
0.012
1
SW 601OD
04/25/2024 10:59
CELL106
0.01
0.004
1
SW 601OD
04/25/2024 10:59
CELL106
0.005
0.002
1
SW 601OD
04/25/2024 10:59
CELL106
0.02
0.008
1
SW 601OD
04/25/2024 10:59
CELL106
0.005
0.001
1
SW 601OD
04/25/2024 10:59
CELL106
0.015
0.004
1
SW 601OD
04/25/2024 10:59
CELL106
1
0.104
1
SW 6020B
04/24/2024 14:21
SNEGLIA
1
0.111
1
SW 6020B
04/24/2024 14:21
SNEGLIA
1
0.249
1
SW 6020E
04/24/2024 14:21
SNEGLIA
1
0.032
1
SW 6020E
04/24/2024 14:21
SNEGLIA
1
0.185
1
SW 6020B
04/24/2024 14:21
SNEGLIA
1
0.077
1
SW 6020E
04/24/2024 14:21
SNEGLIA
1
0.787
1
SW 6020B
04/24/2024 14:21
SNEGLIA
1
0.037
1
SW 6020E
04/24/2024 14:21
SNEGLIA
1
0.18
1
SW 6020E
04/24/2024 14:21
SNEGLIA
1
0.256
1
SW 6020B
04/24/2024 14:21
SNEGLIA
1
0.193
1
SW 6020B
04/24/2024 14:21
SNEGLIA
1
0.035
1
SW 6020E
04/24/2024 14:21
SNEGLIA
0.2
0.041
1
SW 6020B
04/24/2024 14:21
SNEGLIA
1
0.114
1
SW 6020E
04/24/2024 14:21
SNEGLIA
25
25
1
SM2540C
04/17/202411:45
HHOOGKA

Certificate of Laboratory Analysis Page 28 of 47
This report shall not be reproduced, except in full.
Order # J24030273
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an estimate.
M Matrix Spike and/or Matrix Spike Duplicate recovery was outside of the control limits. The associated Laboratory Control
Spike (LCS) recovery was acceptable.

Certificate of Laboratory Analysis Page 29 of 47
This report shall not be reproduced, except in full.
Order # J24030273
Level II QC Summary
Q24040251 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Fluoride
0
0
mg/L
1
0.0479
0.1
< MDL
Nitrate
0
0
mg/L
1
0.0209
0.1
< MDL
Sulfate
0
0
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
5.15
5.15
mg/L
1
0.0154
5
103
80
120
Fluoride
4.93
4.93
mg/L
1
0.0479
5
98.7
80
120
Nitrate
5.22
5.22
mg/L
1
0.0209
5
104
80
120
Sulfate
5.07
5.07
mg/L
1
0.0428
5
101
80
120
MS # 1
Parent Sample:
J24030273 -- 2024006028
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
9.24
9.24
mg/L
1
0.0154
5
95.9
80
120
Fluoride
4.71
4.71
mg/L
1
0.0479
5
94.1
80
120
Nitrate
5.29
5.29
mg/L
1
0.0209
5
102
80
120
Sulfate
5.53
5.53
mg/L
1
0.0428
5
100
80
120
MSD # 1
Parent Sample:
J24030273 -- 2024006028
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Qualifier
Chloride
9.25
9.25
mg/L
1
0.0154
5
96.2
80
120
0.292
Fluoride
4.74
4.74
mg/L
1
0.0479
5
94.7
80
120
0.593
Nitrate
5.3
5.3
mg/L
1
0.0209
5
103
80
120
0.117
Sulfate
5.57
5.57
mg/L
1
0.0428
5
101
80
120
0.674

Certificate of Laboratory Analysis Page 30 of 47
This report shall not be reproduced, except in full.
Order # J24030273
Level II QC Summary
Q24040252 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Fluoride
0
0
mg/L
1
0.0479
0.1
< MDL
Nitrate
0
0
mg/L
1
0.0209
0.1
< MDL
Sulfate
0.035
0.035
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
5.1
5.1
mg/L
1
0.0154
5
102
80
120
Fluoride
4.91
4.91
mg/L
1
0.0479
5
98.1
80
120
Nitrate
5.17
5.17
mg/L
1
0.0209
5
103
80
120
Sulfate
5.09
5.09
mg/L
1
0.0428
5
102
80
120
MS # 1
Parent Sample:
J24030273 -- 2024006047
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
8.66
8.66
mg/L
1
0.0154
5
101
80
120
Fluoride
4.98
4.98
mg/L
1
0.0479
5
99
80
120
Nitrate
7
7
mg/L
1
0.0209
5
103
80
120
Sulfate
6.41
6.41
mg/L
1
0.0428
5
101
80
120
MSD # 1
Parent Sample:
J24030273 -- 2024006047
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Qualifier
Chloride
8.59
8.59
mg/L
1
0.0154
5
100
80
120
1.39
Fluoride
4.92
4.92
mg/L
1
0.0479
5
97.8
80
120
1.18
Nitrate
6.92
6.92
mg/L
1
0.0209
5
102
80
120
1.5
Sulfate
6.38
6.38
mg/L
1
0.0428
5
100
80
120
0.537

Certificate of Laboratory Analysis Page 31 of47
This report shall not be reproduced, except in full.
Order # J24030273
Level II QC Summary
Q24040279 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Fluoride
0
0
mg/L
1
0.0479
0.1
< MDL
Nitrate
0
0
mg/L
1
0.0209
0.1
< MDL
Sulfate
0
0
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
5.09
10.2
mg/L
2
0.0154
5
102
80
120
Fluoride
4.9
9.81
mg/L
2
0.0479
5
98.1
80
120
Nitrate
5.16
10.3
mg/L
2
0.0209
5
103
80
120
Sulfate
5.08
10.2
mg/L
2
0.0428
5
102
80
120
MS # 1
Parent Sample:
J24040414 -- 2024009398
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
6.67
334
mg/L
50
0.0154
250
99.7
80
120
Fluoride
4.82
241
mg/L
50
0.0479
250
96.3
80
120
Nitrate
5.03
251
mg/L
50
0.0209
250
99.3
80
120
Sulfate
3.49
1750
mg/L
500
0.0428
250
102
80
120
MSD # 1
Parent Sample:
J24040414 -- 2024009398
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Qualifier
Chloride
6.75
337
mg/L
50
0.0154
250
101
80
120
1.46
Fluoride
4.87
243
mg/L
50
0.0479
250
97.2
80
120
0.914
Nitrate
5.07
253
mg/L
50
0.0209
250
100
80
120
0.848
Sulfate
3.55
1770
mg/L
500
0.0428
250
112
80
120
9.93

Certificate of Laboratory Analysis Page 32 of47
This report shall not be reproduced, except in full.
Order # J24030273
Level II QC Summary
Q24040281 HG 7470 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.005
0.005
ug/L
1
0.01
0.05
< MDL
Blank # 2
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0
0
ug/L
1
0.01
0.05
< MDL
Blank # 3
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.002
0.002
ug/L
1
0.01
0.05
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery LCL UCL
Qualifier
Mercury (Hg)
2.01
2.01
ug/L
1
0.01
2
100 85 115
LCS # 2
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.94
1.94
ug/L
1
0.01
2
97
85 115
MS # 1
Parent Sample:
J24030273 -- 2024006028
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1
1
ug/L
1
0.01
1
100
75 125
MSD # 1
Parent Sample:
J24030273 -- 2024006028
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL UCL RPD
Qualifier
Mercury (Hg)
0.988
0.988
ug/L
1
0.01
1
98.8
75 125 1.41
MS # 2
Parent Sample:
J24030273 -- 2024006039
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.747
0.747
ug/L
1
0.01
1
74.6
75 125
M
MSD # 2
Parent Sample:
J24030273 -- 2024006039
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.749
0.749
ug/L
1
0.01
1
74.8
75 125 0.268
M
MS # 3
Parent Sample:
J24030273 -- 2024006073
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.97
0.97
ug/L
1
0.01
1
97
75 125
MSD # 3
Parent Sample:
J24030273 -- 2024006073
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.988
0.988
ug/L
1
0.01
1
98.8
75 125 1.84

Certificate of Laboratory Analysis Page 33 of 47
This report shall not be reproduced, except in full.
Order # J24030273
Level II QC Summary
Q24040281 HG 7470 MERCURY (COLD VAPOR) IN WATER
Qualifiers:
M Matrix Spike and/or Matrix Spike Duplicate recovery was outside of the control limits. The associated
Laboratory Control Spike (LCS) recovery was acceptable.

Certificate of Laboratory Analysis Page 34 of 47
This report shall not be reproduced, except in full.
Order # J24030273
Level II QC Summary
Q24040353 HG 7470 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Mercury (Hg)
-0.004
-0.004
Blank # 2
Parameter
Measured
Final
Mercury (Hg)
-0.008
-0.008
LCS # 1
MS # 1
MSD # 1
MS # 2
MSD # 2
Parameter Measured Final
Mercury (Hg) 2.01 2.01
Parameter Measured Final
Mercury (Hg) 0.997 0.997
Parameter Measured Final
Mercury (Hg) 1.01 1.01
Parameter Measured Final
Mercury (Hg) 1.01 1.01
Parameter Measured Final
Mercury (Hg) 1.02 1.02
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
ug/L
1
0.01
0.05
< MDL
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
ug/L
1
0.01
0.05
< MDL
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
ug/L
1
0.01
2
100
85 115
Parent Sample:
J24030273 -- 2024006033
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
ug/L
1
0.01
1
99.7
75 125
Parent Sample:
J24030273 -- 2024006033
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
ug/L
1
0.01
1
101
75 125 1.59
Parent Sample:
J24040414 -- 2024009398
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
ug/L
1
0.01
1
101
75 125
Parent Sample:
J24040414 -- 2024009398
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
ug/L
1
0.01
1
101
75 125 0.593

Certificate of Laboratory Analysis Page 35 of 47
This report shall not be reproduced, except in full.
Order # J24030273
Level II QC Summary
Q24040283 ICP_TRM TOTAL RECOVERABLE METALS BY 1CP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
-0.000136
-0.000136
mg/L
1
0.002
0.005
< MDL
Boron (B)
0.00133
0.00133
mg/L
1
0.005
0.05
< MDL
Calcium (Ca)
0.00459
0.00459
mg/L
1
0.012
0.05
< MDL
Iron (Fe)
0.000393
0.000393
mg/L
1
0.004
0.01
< MDL
Lithium (Li)
-0.00106
-0.00106
mg/L
1
0.002
0.005
< MDL
Magnesium (Mg)
0.000844
0.000844
mg/L
1
0.008
0.02
< MDL
Manganese (Mn)
-0.000193
-0.000193
mg/L
1
0.001
0.005
< MDL
Zinc (Zn)
0.000129
0.000129
mg/L
1
0.004
0.015
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
5.05
5.05
mg/L
1
0.002
5
101
80
120
Boron (B)
4.89
4.89
mg/L
1
0.005
5
97.8
80
120
Calcium (Ca)
5.1
5.1
mg/L
1
0.012
5
102
80
120
Iron (Fe)
5.06
5.06
mg/L
1
0.004
5
101
80
120
Lithium (Li)
5
5
mg/L
1
0.002
5
100
80
120
Magnesium (Mg)
5.06
5.06
mg/L
1
0.008
5
101
80
120
Manganese (Mn)
5.05
5.05
mg/L
1
0.001
5
101
80
120
Zinc (Zn)
5.06
5.06
mg/L
1
0.004
5
101
80
120
MS # 1
Parent Sample:
J24030273
-- 2024006028
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
Barium (Ba)
4.99
4.99
mg/L
1
0.002
5
99.4
75
125
Boron (B)
4.86
4.86
mg/L
1
0.005
5
97
75
125
Calcium (Ca)
5.2
5.2
mg/L
1
0.012
5
100
75
125
Iron (Fe)
5.01
5.01
mg/L
1
0.004
5
99.4
75
125
Lithium (Li)
4.95
4.95
mg/L
1
0.002
5
98.9
75
125
Magnesium (Mg)
5.64
5.64
mg/L
1
0.008
5
98.5
75
125
Manganese (Mn)
4.98
4.98
mg/L
1
0.001
5
99.3
75
125
Zinc (Zn)
5.03
5.03
mg/L
1
0.004
5
100
75
125
MSD # 1
Parent Sample:
J24030273
-- 2024006028
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Barium (Ba)
5.02
5.02
mg/L
1
0.002
5
99.9
75
125
0.5
Boron (B)
4.9
4.9
mg/L
1
0.005
5
97.8
75
125
0.799
Calcium (Ca)
5.25
5.25
mg/L
1
0.012
5
101
75
125
0.995
Iron (Fe)
5.07
5.07
mg/L
1
0.004
5
101
75
125
1.25
Lithium (Li)
4.97
4.97
mg/L
1
0.002
5
99.4
75
125
0.464
Magnesium (Mg)
5.69
5.69
mg/L
1
0.008
5
99.6
75
125
1.01
Manganese (Mn)
5.02
5.02
mg/L
1
0.001
5
100
75
125
0.779
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 36 of 47
This report shall not be reproduced, except in full.
Order # J24030273
Level II QC Summary
Q24040283 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
MSD # 1 Parent Sample: J24030273 -- 2024006028
Parameter Measured Final Units Dil MDL Spike % Recovery LCL UCL RPD Qualifier
Zinc (Zn) 5.07 5.07 mg/L 1 0.004 5 101 75 125 0.773

Certificate of Laboratory Analysis Page 37 of 47
This report shall not be reproduced, except in full.
Order # J24030273
Level II QC Summary
Q24040334 ICP_TRM TOTAL RECOVERABLE METALS BY 1CP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
-0.000187
-0.000187
mg/L
1
0.002
0.005
< MDL
Boron (B)
0.00206
0.00206
mg/L
1
0.005
0.05
< MDL
Calcium (Ca)
0.00477
0.00477
mg/L
1
0.012
0.05
< MDL
Iron (Fe)
0.000365
0.000365
mg/L
1
0.004
0.01
< MDL
Lithium (Li)
-0.000528
-0.000528
mg/L
1
0.002
0.005
< MDL
Magnesium (Mg)
0.000019
0.000019
mg/L
1
0.008
0.02
< MDL
Manganese (Mn)
-0.000135
-0.000135
mg/L
1
0.001
0.005
< MDL
Zinc (Zn)
0.000201
0.000201
mg/L
1
0.004
0.015
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
5.12
5.12
mg/L
1
0.002
5
102
80
120
Boron (B)
4.97
4.97
mg/L
1
0.005
5
99.4
80
120
Calcium (Ca)
5.18
5.18
mg/L
1
0.012
5
104
80
120
Iron (Fe)
5.19
5.19
mg/L
1
0.004
5
104
80
120
Lithium (Li)
5.1
5.1
mg/L
1
0.002
5
102
80
120
Magnesium (Mg)
5.1
5.1
mg/L
1
0.008
5
102
80
120
Manganese (Mn)
5.13
5.13
mg/L
1
0.001
5
103
80
120
Zinc (Zn)
5.06
5.06
mg/L
1
0.004
5
101
80
120
MS # 1
Parent Sample:
J24030273
-- 2024006033
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
Barium (Ba)
4.87
4.87
mg/L
1
0.002
5
97.3
75
125
Boron (B)
4.75
4.75
mg/L
1
0.005
5
94.5
75
125
Calcium (Ca)
27.1
27.1
mg/L
1
0.012
5
109
75
125
Iron (Fe)
4.99
4.99
mg/L
1
0.004
5
98.6
75
125
Lithium (Li)
4.79
4.79
mg/L
1
0.002
5
95.7
75
125
Magnesium (Mg)
5.13
5.13
mg/L
1
0.008
5
96.8
75
125
Manganese (Mn)
4.85
4.85
mg/L
1
0.001
5
97
75
125
Zinc (Zn)
4.8
4.8
mg/L
1
0.004
5
96
75
125
MSD # 1
Parent Sample:
J24030273
-- 2024006033
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Barium (Ba)
4.81
4.81
mg/L
1
0.002
5
96.1
75
125
1.26
Boron (B)
4.69
4.69
mg/L
1
0.005
5
93.4
75
125
1.14
Calcium (Ca)
26.8
26.8
mg/L
1
0.012
5
103
75
125
1.14
Iron (Fe)
4.93
4.93
mg/L
1
0.004
5
97.6
75
125
1.07
Lithium (Li)
4.76
4.76
mg/L
1
0.002
5
95.2
75
125
0.566
Magnesium (Mg)
5.08
5.08
mg/L
1
0.008
5
95.7
75
125
1.1
Manganese (Mn)
4.8
4.8
mg/L
1
0.001
5
95.9
75
125
1.12
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 38 of 47
This report shall not be reproduced, except in full.
Order # J24030273
Level II QC Summary
Q24040334 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
MSD # 1 Parent Sample: J24030273 -- 2024006033
Parameter Measured Final Units Dil MDL Spike % Recovery LCL UCL RPD Qualifier
Zinc (Zn) 4.76 4.76 mg/L 1 0.004 5 95.1 75 125 1

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030273
Level II QC Summary
Q24040287 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
0.012
0.012
ug/L
1
0.104
1
< MDL
Arsenic (As)
0.006
0.006
ug/L
1
0.111
1
< MDL
Beryllium (Be)
0
0
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0.002
0.002
ug/L
1
0.032
1
< MDL
Chromium (Cr)
-0.048
-0.048
ug/L
1
0.185
1
< MDL
Cobalt (Co)
0.003
0.003
ug/L
1
0.077
1
< MDL
Copper (Cu)
-0.002
-0.002
ug/L
1
0.787
1
< MDL
Lead (Pb)
0.004
0.004
ug/L
1
0.037
1
< MDL
Molybdenum (Mo)
0.002
0.002
ug/L
1
0.18
1
< MDL
Nickel (Ni)
0.007
0.007
ug/L
1
0.256
1
< MDL
Selenium (Se)
-0.005
-0.005
ug/L
1
0.193
1
< MDL
Silver (Ag)
-0.001
-0.001
ug/L
1
0.035
1
< MDL
Thallium (TI) Low Level
-0.001
-0.001
ug/L
1
0.041
0.2
< MDL
Vanadium (V)
-0.034
-0.034
ug/L
1
0.114
1
< MDL
LCS # 1
Page 39 of 47
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
Antimony (Sb)
48.4
48.4
ug/L
1
0.104
50
96.9
80
120
Arsenic (As)
49.2
49.2
ug/L
1
0.111
50
98.3
80
120
Beryllium (Be)
49.7
49.7
ug/L
1
0.249
50
99.5
80
120
Cadmium (Cd)
48.7
48.7
ug/L
1
0.032
50
97.3
80
120
Chromium (Cr)
50.3
50.3
ug/L
1
0.185
50
101
80
120
Cobalt (Co)
50.3
50.3
ug/L
1
0.077
50
101
80
120
Copper (Cu)
50.7
50.7
ug/L
1
0.787
50
101
80
120
Lead (Pb)
51.5
51.5
ug/L
1
0.037
50
103
80
120
Molybdenum (Mo)
50.1
50.1
ug/L
1
0.18
50
100
80
120
Nickel (Ni)
49.3
49.3
ug/L
1
0.256
50
98.5
80
120
Selenium (Se)
49.4
49.4
ug/L
1
0.193
50
98.8
80
120
Silver (Ag)
49.2
49.2
ug/L
1
0.035
50
98.4
80
120
Thallium (TI) Low Level
50.5
50.5
ug/L
1
0.041
50
101
80
120
Vanadium (V)
49.9
49.9
ug/L
1
0.114
50
99.8
80
120
MS # 1
Parent Sample:
J24030273
-- 2024006029
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
49.2
49.2
ug/L
1
0.104
50
98.2
75
125
Arsenic (As)
49.7
49.7
ug/L
1
0.111
50
99.3
75
125
Beryllium (Be)
50.3
50.3
ug/L
1
0.249
50
101
75
125
Cadmium (Cd)
49.1
49.1
ug/L
1
0.032
50
98.2
75
125
Chromium (Cr)
50.5
50.5
ug/L
1
0.185
50
100
75
125
Cobalt (Co)
50.7
50.7
ug/L
1
0.077
50
101
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030273
Level II QC Summary
Q24040287 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
Copper(Cu)
50.5
50.5
ug/L
1
0.787
50
Lead (Pb)
51.4
51.4
ug/L
1
0.037
50
Molybdenum (Mo)
50.2
50.2
ug/L
1
0.18
50
Nickel (Ni)
50
50
ug/L
1
0.256
50
Selenium (Se)
48.8
48.8
ug/L
1
0.193
50
Silver (Ag)
49.2
49.2
ug/L
1
0.035
50
Thallium (TI) Low Level
50.5
50.5
ug/L
1
0.041
50
Vanadium (V)
49.7
49.7
ug/L
1
0.114
50
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
Antimony (Sb)
48.6
48.6
ug/L
1
0.104
50
Arsenic (As)
48.7
48.7
ug/L
1
0.111
50
Beryllium (Be)
50.1
50.1
ug/L
1
0.249
50
Cadmium (Cd)
48.3
48.3
ug/L
1
0.032
50
Chromium (Cr)
49.9
49.9
ug/L
1
0.185
50
Cobalt (Co)
49.7
49.7
ug/L
1
0.077
50
Copper (Cu)
49.7
49.7
ug/L
1
0.787
50
Lead (Pb)
50.6
50.6
ug/L
1
0.037
50
Molybdenum (Mo)
49.1
49.1
ug/L
1
0.18
50
Nickel (Ni)
49
49
ug/L
1
0.256
50
Selenium (Se)
48.4
48.4
ug/L
1
0.193
50
Silver (Ag)
48.3
48.3
ug/L
1
0.035
50
Thallium (TI) Low Level
49.5
49.5
ug/L
1
0.041
50
Vanadium (V)
49.6
49.6
ug/L
1
0.114
50
Page 40 of 47
Parent Sample: J24030273 -- 2024006029
% Recovery
LCL
UCL
100
75
125
103
75
125
100
75
125
97.6
75
125
97.6
75
125
98.3
75
125
101
75
125
99.5
75
125
Parent Sample: J24030273 -- 2024006029
% Recovery
LCL
UCL
RPD
96.9
75
125
1.31
97.4
75
125
1.97
100
75
125
0.455
96.5
75
125
1.75
99.2
75
125
1.2
98.7
75
125
2.16
98.8
75
125
1.5
101
75
125
1.58
98.1
75
125
2.32
95.7
75
125
2
96.8
75
125
0.835
96.5
75
125
1.84
99
75
125
1.86
99.2
75
125
0.284
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030273
Level II QC Summary
Q24040339 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
0
0
ug/L
1
0.104
1
< MDL
Arsenic (As)
0.008
0.008
ug/L
1
0.111
1
< MDL
Beryllium (Be)
-0.004
-0.004
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0.001
0.001
ug/L
1
0.032
1
< MDL
Chromium (Cr)
-0.077
-0.077
ug/L
1
0.185
1
< MDL
Cobalt (Co)
0.002
0.002
ug/L
1
0.077
1
< MDL
Copper (Cu)
0.003
0.003
ug/L
1
0.787
1
< MDL
Lead (Pb)
0.004
0.004
ug/L
1
0.037
1
< MDL
Molybdenum (Mo)
0.002
0.002
ug/L
1
0.18
1
< MDL
Nickel (Ni)
-0.011
-0.011
ug/L
1
0.256
1
< MDL
Selenium (Se)
-0.01
-0.01
ug/L
1
0.193
1
< MDL
Silver (Ag)
0.046
0.046
ug/L
1
0.035
1
> MDL
Thallium (TI) Low Level
0.001
0.001
ug/L
1
0.041
0.2
< MDL
Vanadium (V)
-0.029
-0.029
ug/L
1
0.114
1
< MDL
LCS # 1
Page 41 of 47
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
Antimony (Sb)
46.5
46.5
ug/L
1
0.104
50
92.9
80
120
Arsenic (As)
48.3
48.3
ug/L
1
0.111
50
96.6
80
120
Beryllium (Be)
49.9
49.9
ug/L
1
0.249
50
99.8
80
120
Cadmium (Cd)
47.8
47.8
ug/L
1
0.032
50
95.5
80
120
Chromium (Cr)
49.1
49.1
ug/L
1
0.185
50
98.2
80
120
Cobalt (Co)
47.8
47.8
ug/L
1
0.077
50
95.7
80
120
Copper (Cu)
48.6
48.6
ug/L
1
0.787
50
97.3
80
120
Lead (Pb)
50.6
50.6
ug/L
1
0.037
50
101
80
120
Molybdenum (Mo)
48.6
48.6
ug/L
1
0.18
50
97.2
80
120
Nickel (Ni)
47.7
47.7
ug/L
1
0.256
50
95.5
80
120
Selenium (Se)
48
48
ug/L
1
0.193
50
95.9
80
120
Silver (Ag)
45
45
ug/L
1
0.035
50
89.9
80
120
Thallium (TI) Low Level
48.9
48.9
ug/L
1
0.041
50
97.8
80
120
Vanadium (V)
48.9
48.9
ug/L
1
0.114
50
97.8
80
120
MS # 1
Parent Sample:
J24030273
-- 2024006040
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
48.1
48.1
ug/L
1
0.104
50
96
75
125
Arsenic (As)
48.6
48.6
ug/L
1
0.111
50
97.2
75
125
Beryllium (Be)
50.6
50.6
ug/L
1
0.249
50
101
75
125
Cadmium (Cd)
48.6
48.6
ug/L
1
0.032
50
97.1
75
125
Chromium (Cr)
50.1
50.1
ug/L
1
0.185
50
98.8
75
125
Cobalt (Co)
48.9
48.9
ug/L
1
0.077
50
97.3
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24030273
Level II QC Summary
Q24040339 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
Copper (Cu)
49.9
49.9
ug/L
1
0.787
50
Lead (Pb)
50.5
50.5
ug/L
1
0.037
50
Molybdenum (Mo)
49.2
49.2
ug/L
1
0.18
50
Nickel (Ni)
48.9
48.9
ug/L
1
0.256
50
Selenium (Se)
48
48
ug/L
1
0.193
50
Silver (Ag)
45.8
45.8
ug/L
1
0.035
50
Thallium (TI) Low Level
48.8
48.8
ug/L
1
0.041
50
Vanadium (V)
49
49
ug/L
1
0.114
50
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
Antimony (Sb)
48.4
48.4
ug/L
1
0.104
50
Arsenic (As)
48.4
48.4
ug/L
1
0.111
50
Beryllium (Be)
50.6
50.6
ug/L
1
0.249
50
Cadmium (Cd)
48.5
48.5
ug/L
1
0.032
50
Chromium (Cr)
50
50
ug/L
1
0.185
50
Cobalt (Co)
49
49
ug/L
1
0.077
50
Copper (Cu)
50.1
50.1
ug/L
1
0.787
50
Lead (Pb)
50.8
50.8
ug/L
1
0.037
50
Molybdenum (Mo)
49.2
49.2
ug/L
1
0.18
50
Nickel (Ni)
48.7
48.7
ug/L
1
0.256
50
Selenium (Se)
48.1
48.1
ug/L
1
0.193
50
Silver (Ag)
46.1
46.1
ug/L
1
0.035
50
Thallium (TI) Low Level
49.3
49.3
ug/L
1
0.041
50
Vanadium (V)
49.2
49.2
ug/L
1
0.114
50
Page 42 of 47
Parent Sample: J24030273 -- 2024006040
% Recovery
LCL
UCL
97.8
75
125
101
75
125
98.2
75
125
96.1
75
125
96.1
75
125
91.4
75
125
97.5
75
125
97.9
75
125
Parent Sample: J24030273 -- 2024006040
% Recovery
LCL
UCL
RPD
96.7
75
125
0.766
96.7
75
125
0.588
101
75
125
0.0929
97
75
125
0.117
98.8
75
125
0.0243
97.5
75
125
0.253
98.3
75
125
0.434
102
75
125
0.709
98.2
75
125
0.0428
95.7
75
125
0.496
96.2
75
125
0.119
91.9
75
125
0.567
98.6
75
125
1.06
98.4
75
125
0.526
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 43of47
This report shall not be reproduced, except in full.
Order # J24030273
Level II QC Summary
Q24040253 TDS TOTAL DISSOLVED SOLIDS
Blank # 1
Parameter Measured Final
TDS -0.3
Duplicate # 1
Parameter Measured Final
TDS 12
LCS # 1
Parameter Measured Final
TDS 490
Units
Dil
MDL
RDL
Relative Concentration
mg/L
1
25
25
< MDL
Parent Sample: J24030273 -- 2024006028
Units
Dil
MDL
RPD
mg/L
1
25
8.7
Units
Dil
MDL
Spike
% Recovery LCL UCL
mg/L
1
25
500
98 90 110
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 44of47
This report shall not be reproduced, except in full.
Order # J24030273
Level II QC Summary
Q24040280 TDS TOTAL DISSOLVED SOLIDS
Blank # 1
Blank # 2
Parameter Measured Final
TDS -0.4
Parameter Measured Final
TDS -0.2
Duplicate # 1
Parameter Measured Final
TDS 92
Duplicate # 2
Parameter Measured Final
TDS 434
LCS # 1
LCS # 2
Parameter Measured Final
TDS 495
Parameter Measured Final
TDS 497
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
25
25
< MDL
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
25
25
< MDL
Parent Sample:
J24030273 -- 2024006033
Units
Dil
MDL
RPD
Qualifier
mg/L
1
25
1.09
Parent Sample:
J24040393 -- 2024009271
Units
Dil
MDL
RPD
Qualifier
mg/L
1
25
0.917
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
25
500
99
90
110
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
25
500
99.4
90
110

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
Page 45 of 47
Energy Ana]ytical Laboratory.-i
i---------'- -- - - - - -------------------------------------- ._._._.�1 cal -------- Use Only---------' ----------------- .........
DUKEDuke
HHn 11r, a705t
ENERGY, ��. 28atr !
'Order# J24030273 Matrix WATER Nc_x_ Page_1_o1 2_
°�°��.nnaFrom sc ! DISTRIBUTION
—
.
17U) a7sszas I
i Lee=`'d ey O ` a T _�j SAMPLE PROGRAM ; ORIGINAL to LAB, COPY 10 CLIENT
_._._._._._._._._._._._._._._._._. _ _ F,r:Irat�a�,Np_._. .:
-EI
Project Name ROGERS CLIFPStDE CCP
LANDFILL PERMIT# 81-OB
Crinwn water UST v sed 3 11 2024 ,
RCRA Waste
iPo nr ..-.._.._..._.._cvoa/Ground 9Water=x.._.._.._—NPDES—_.._.._.._..v I _ -
Client BILL WYLIE. BRYAN MOELLER,
DEE O-BRIEN, JOSH STOWE
i Filtration (0.45 um) Unfiltered b Filtered
i Preservative ICE ICE
............................................... .._.._.._.._.._.._.._.._.._. •
Operating Unit: CS56
Procass:NGRDWTR
Account:
Project: ACSS60062 Activity ID: Facility ID: CLS Container Volume (ml-)
SOD
300
SOp
Program I EQuiS Task Code: CL5 sub-ProgramiTask code: Container Type
CCPILF
HOPE
PET
PET
(Metals Prep -TRM)t
Sa. Ba.
Cl, F,
P
Customer to complete all appropriate non -shaded areas. °+
� w �
B, C ,
6, Ca, F¢, Li, Mg, Mn.
Li, Mg,
NO3-N
(48-Hr
---------------------- Sample Description or ID
Zn (S}! Hg (SW 74�0A)
Hold
TDS
`o
Collection Information
i SAMPLE ID i
I (IMS - SW 5020BI Sb,
Time),
O
a�
i NUMBER i E 'n
As, Be, Cd, Cr, Co, Cu,
Pb, Mc, Ni, Se, Ag,
$04
a
Date Time Printed Name 5ja0ature 0 0
TI LL V 1141r
2024006028
CLS_CCPMW-1S
t I ", t LA
Ili9
/AeQ
x
1
1
7
3
2024006029
CLS_CCPMW-1D
/Jb to
(00
/YIf Q
x
1
1
1
3
! 2024066030 ,
--
CLS_CCPMW.25
4116 44
116 Is
-f ? Q
x
1
1
1
3
2024006031
CL5_CCPMW-3D
s3/j{r�iL1
S rj
T 7
{�� _
x
1
1
7
3
i 2024006032 1
CLS_CCPMW4
y f f L+�
1 �l�
7 (.�
x
1
1
1
3
x
7
1
1
S
2024006034 !
CLS_CCPMW-6S
V111o/1
IK��
� GA
f-
x
1
1
1
9
2024006035 !
i
CLS_CCPMW-7
M//w)-
1�15
TF
x
7
1
1
3
2024006036 !,
CLS_CCPMW-10
(�/(fi1441
SS S
ME
x
7
1
1
3
! 2024006037
i—
CLS_CCPMW-11
--
yfig
t310
ME(L
x
1
1
7
3
i 2024006038 i
CLS_CCP-LEACHATE
�/I(7ft
��39
e pp
4�ihV
�
x
1
1
1
1
3
2024006039 i
CLS_CCP-LEACHATE-34
fi/:
1`4!,
RIM
x
1
1
3
iek!s
ewt-eep as--
X
1
1
1
3
2024006041
CLS_CCR-CCP-19S
y/llrll>{
4 Q
r Q
l
x
1
1
1 ',
3
2024006042 l
CLC_CCR-CCP-20D
I (r
3 3 o
R rf
ynym
x
,
,
,
3
2024006043!
CLS_CCR-CCPMWOD
4
li L�
I•iZ<j
%� /Il`,
R g 5
a.n r>ti
x
1
1
1
3
i 20240060" i
CLS_CCR-CCPTW-2D
1} E/
i� 0
`
T S tl
x
1
1
1
3
20240060451
CLS_CCR-CCPSG-1D
14/16/W
1319
TC A
x
1
1
1
3
�, 2024006046
CLS CCR-CCPBG-lBR
C•
4/!(�/1
iDS9
�' �,/1�
x
1
1
1
3
Relinquished By Daterrime 1 94r
Accepted By: , Date(T3me
d
47A, Q 0. ��b/�4{ l ]
/r� M/L�r /lj i�f/
, - (Y\Z� /�
LlBy:
=
Requested Turnaround
Relinquished By DatafTlm¢
Accepted DatelTime
a c
a
21 Days
Relinquished By OatelTime
Accepted By: Daternme
Zi c E
a
14 Days X
SeaVLocked By DatelTimg
Sealed/Lock Opened By Date7Time
n �
7 Days
E m
_v
Comments
Regulatory Agency: NCDENRIDWM - SW Section EQUIS REQUIRED I PERMIT # 81-06
m
0
•other
Add. Cost Will Apply
U

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM Page 46 of 47
Duke Energy Analytical Laboratory -1 f—'_._-_._._._._._._._...._.__—_._._._._.___—._._._....._.___._._._.-._.___._.,,._._._._._.___._._._._._._._._._.
DUKEDUKE Anal cal Laboratory the Only
rn,u cEt 'r IeueaNy foal Iorder# J24030273 MatrtX WATER NC Page _
ENERGY. 13339 Hagers Fe ryRe 1 a.mpe aaa netlnr rmm —X- g 2—Ot 2
Hmeertl . N.C, xeale i y e sc ! DISTRIBUTIONS
Pall aeaxetl i it-oggedS
SAMPLE PROGRAM i ORIGINAL to LAB, COPY to CLIENT
F.::.gwiaraaoas__ _ _ _ Ground Water X NPDES
iProject Names ROGERS CLJFFSIDE CCP mae nlNo:- J iverdor / Drinking Waier,� UST_
i LANDFILL PERMIT# 81-06 ' L RCRA Wastes
; Client BILL WYLIE, BRYAN MOEr I ER, :Pas ---------..-.----__.—._..@ltrJ.._..._--_._.._„_.._.._.._.._.................. --- ..............
_
i DEE O•BRIEN, JOSH STOWE f Filtration (0.45 um) a Unfiltered J} Filtered
? Operating Unit: CS56 Process:NGRDWTR Account:
r i ' Prea@ryatlVe ICE ICE
I Project: AC5560062 Acgvity 1p; FacilRy ID: CLS Container Volumejm L) Soo 300 500 Soo
Program 1 EOuiS Task Code: CLS Sub-Programfrask Code:
CCPlLF Container Type HDPE PET PET HOPE
A (Metals Prep -TRM)I Cl, F,
Customer to complete all appropnafe non -shaded areas. w wu (ICP - SW 6010D) Ba, B, NO3-N S W6010D 2n f
Co. Fe, Li, Mg, Mn, 7n (48-Hf --------- '" SW 6020B Be, c
Sample Description or ID [aJ! Hg (SW 7470A)f TDS
Hold Cd. Cr, Cu, Pb, c
Collection Informatian M Be, Cd, Cr, Co, Cu,
SAMPLE ID A
NUMBER i sTSB Ni, Se, Ag
Doh Time Printed a Nmesignatured Pb, Mo, Ni, Se, Ag, o
o TI LL V 14 r
i 2024006047 ! CL.S_CCPSW-1 —LfjjbAA (pup RftN tw x t 1 i 1 4
i 2024006071 i CL.S_CCPSW-2 x i 1 i t 4
200224006072 — �r RiK11L(�} n x 1 i 1 1 4
2024006073 CLS FD- jlo%RoLtk( -( OWNM E *� x 1 i i a
2024006074 CL.s_FB--j.A0416 0 I.100 71 Q x
2
1 2024006075 CLS FD-Zp�g4 4►Irtr�K—yl 1} x
i
i
i�
)
i
i
u
Oer o sign dole a aw
Roilrup fished By --eempatelTlme Accepted By; atellirrre W
Rr Q T 4 [e bl ��i�� �� / '7i Q Requested Turnaround
Relinquished By DatelTlme A epred Sy; 7`- Da✓telTimee c
ro v 21 Days
Relinquished By DahlTime Accepted By: Daterr.— n o
14 Days X,
SeaLfLocked By Date/Tjme SeeleNLocN Operwd By DatalTime C a
a y
7 Days
E 'w
Comments
Regulatory Agency: NCDENRIDWm - SW Section EQUIS REQUIRED f PERMIT # 81-06 Include Total Hardness for CCPSW-1,CCPSW-2, CCPSW-3 0 'Other
'Add. Cost Will Apply
U

��� roDuke Energy Analytical Laboratory
M. caaa Marne levee's T40ay
E"
ENERGY. tt1].Hap•rs""°
C.
HmrlersNY, N, 4K,Ta
Pa41 a7rsue
_ _ _ __ ............ _ r.z a aTs-soae
d,Profect Name ^ �ROGERS CLIFFSIDE CCP •N•
LANDFILL PERMIT# 81-06
Client BILL WYLIE, BRYAN MOELLER,
a DEE O'BRIENr JOSH STOWE
OperalingUnit: CSSS Process:NGRDWTR Account:
Project: ACS540062 Activity ID: Facility ID: CLS
Program l ECuiS Task Coda; CLS Sub-PrnoramlTask Code:
SAMPLE ID
NUMBER
2024006033
CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
.._ -----------•-•-•----------------'Mal ql Laperata Use 4n---------------
J24030273 Matrix WATER
Filtration (0-46
Preserve
Container Volume i
Container 1
Customer to complete all appropriate non -shaded areas.
Sample Description or ID
Collection Information
EDate Time Prlyded Name 31
2024006040 4CLS_CCR-CCP-18S
_40 IwIlt o l 1)49
►r}/IYrLoI r30o I RP,13 1 9-f"
onp,verq rro„r NC—X-
sc_
SAMPLE PROGRAM
Ground Water X— NPDES
Ddnkdng Water_ UST_
RCi:R waste
8 Unfiltered
ICE ICE
Soo 300 S00
HOPE PET PET
(Metals Prep - TRW)1 Cl, F,
(ICP - SW 6010D) Ba, NO3-N
B, Ca, Fe, Li, Mg, Mn, (48-Hr
Zn (8)1 Hg (SW 7470A) HOIU TDS
Ho
1(IMS -SW 6020B) Sb, Hold
As, Be, Cd, Cr, Co, Cu, Time),
Pb, Mo, Ni, Se, Ag,
TILL V 1141
1 1 1
1 1 1
1 1 1
1 7 1
i i 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 T
1 1 1
1 1 /
1 1 1
1 1 1
1 1 i
1 1 1
1 1 1
1 1 1
Page 47 of 47
Page _I_ of _2_
DISTRIBUTION
ORIGINAL to LAB, COPY to CLIENT
.. Revised 3-11-2R24
Filtered
Relinquished By DatelTlme Aecjgpted By: ^ J 1 Ime
!7 Y/iJ! �GJ r� °S
R 4 1' f 4it 7ft I43� Requested Turnaround
V
Rellrlquistred By Daterrime Accepted By: ffawmnia
w 9 21 Days
G
w
Relinquished By DatelTime Accepted By: DatalTlme �
• • E 14 Days X
c �
SeallLocked By DatelTime 8ealed"ek opened By Date)Tlme a
a "7 Days
E '8
_ y
Comments
at
E Other
Regulatory Agency: NCDENRIDWM - SW Section EOUIS REQUIRED 1 PERMIT # 81-06
� `Add. Gost Will Apply
U
Page 47 of 47
Page _I_ of _2_
DISTRIBUTION
ORIGINAL to LAB, COPY to CLIENT
.. Revised 3-11-2R24
Filtered
Relinquished By DatelTlme Aecjgpted By: ^ J 1 Ime
!7 Y/iJ! �GJ r� °S
R 4 1' f 4it 7ft I43� Requested Turnaround
V
Rellrlquistred By Daterrime Accepted By: ffawmnia
w 9 21 Days
G
w
Relinquished By DatelTime Accepted By: DatalTlme �
• • E 14 Days X
c �
SeallLocked By DatelTime 8ealed"ek opened By Date)Tlme a
a "7 Days
E '8
_ y
Comments
at
E Other
Regulatory Agency: NCDENRIDWM - SW Section EOUIS REQUIRED 1 PERMIT # 81-06
� `Add. Gost Will Apply
U

Data Validation Checklist
Facility/Site Location/Sample r
Cliffside Steam Station
State
NC
CCPSW-1, CCPSW-2
Duke Central Lab
•
Groundwater
/24040661 4/26/2024 4/29/2024 S/13/2024
✓ Surface Water
Other
National Functional Guidelines for Organic/Inorganic Superfund Methods Data Review (USEPA 2020)
;r,eces:
Guidance on Environmental Data Verification and Data Validation (USEPA 2002)
Radiochemical Data Verification and Validation (MARLAP Manual Volume I: Chapter 8, 2004)
Chain of Custody
1) Do the sample IDs and laboratory analyses recorded on the Chain of Custody match the sample IDs and analyses listed in the laboratory package?
a) Do the dates and times of sampling listed on the Chain of Custody match the laboratory report?
�✓
2) Is the sample temperature upon receipt at the laboratory recorded on the Chain of Custody or sample receipt form?
❑
❑
�✓ a) Is the sample temperature upon receipt less than 6 degrees Celsius? If NO, then:
❑
❑
�J 1) Was the presence of wet ice noted in the cooler? OR
❑
❑
�✓ 11) Were the samples collected less than two hours prior to receipt at the lab?
❑✓
❑
3) Was the proper sample preservation used, confirmed, and documented on the Chain of Custody and/or sample receipt form?
❑✓
❑
4) Are there any special notes, exceptions, and/or anomalies listed on the Chain of Custody, sample receipt form, or laboratory report?
❑
❑✓
❑ 5) Was the transfer of custody of the samples properly documented and traceable through signature, date, and time by all persons who relinquished and/or received
custody of the samples?
-
®®Batch eAssurance/Quality
6) Was the holding time for preparation and/or analysis met for each parameter?
a) Total Alkalinity, Bicarbonate Alkalinity, and Carbonate Alkalinity: Analyzed within 14 days of collection
❑
�J b) Bromide, Chlo(de, Fluoride, and Sulfate (Anions): Analyzed within 28 days of collection
c) Sulfide: Analyzed within 7 days of collection
�✓ d) Total Organic Carbon (TOC) and/or Nitrate -Nitrite: Analyzed within 28 days of collection
e) Total Phosphorus (TP) and Dissolved Phosphorus: Analyzed within 28 days of collection
❑
❑
�✓ f) Hexavalent Chromium and Dissolved Hexavalent Chromium: Analyzed within 24 hours (unpreserved) / 28 days (preserved) of collection
❑
❑
�J g) Mercury and Dissolved Mercury: Analyzed within 28 days of collection (preserved)
❑✓
❑
❑ h) Total Metals and Dissolved Metals: Analyzed within 180 days of collection
❑
[A I 1) Total Suspended Solids (TSS) and/or Total Dissolved Solids (TDS): Analyzed within 7 days of collection
❑
❑✓ )) Radionuclides: Analyzed within 180 days of collection
❑
❑
�✓ k) Methane: Analyzed within 14 days (preserved) / 7 days (unpreserved) of collection
❑
❑
�✓ 1) Oil and Grease: Analyzed within 28 days of collection
7) Are there any qualifiers assigned by the laboratory and if so, are the qualifier definitions provided?
❑
❑✓
8) Method Blank- Were any parameters detected in the laboratory method blank(s)?
�J a) If YES, were any target analyses detected in the samples at concentrations less than ten times the method blank concentration?
�✓
9) Laboratory Control Sample (LCS) - Were any parameters flagged by the lab as being outside the limits of control in the associated LCS?
�✓
a) If YES, was the parameter recovery less than 50 percent or greater than 150 percent?
�✓ b) Were the same parameters detected in the samples?
�✓
10) Matrix Spike Sample (MS/MSD) - Did the laboratory provide matrix spike results? If so, then:
a) Was the original sample spiked a project sample? If so, then:
�J
b) Were any parameters flagged by the lab as being outside the limits of control in the associated matrix spike sample?

Batch !Assurance/Quality
�✓ ❑ 11) Laboratory Duplicate Sample - Did the laboratory provide lab duplicate sample results? If so, then:
a) Was the sample analyzed as a laboratory duplicate a project sample? If so, then:
b) Were any parameters flagged by the lab as being outside the limits of control in the laboratory duplicate sample?
�✓ 12) Field Duplicate Sample - Is the relative percent difference between the parent and field duplicate sample results greater than 35 percent?
13) Field/Equipment/Trip Blanks - Were any parameters detected in the associated field, equipment, and/or trip blanks?
�✓ a) If yes, were any target analytes detected in the samples at a concentration less than ten times the Field/Equipment/Trip Blank concentration?
❑ 14) Were initial and continuing calibration blank information within acceptable criteria per the lab report?
❑ ❑ 0 15) Were any reporting limits for diluted, non -detect results greater than the screening criteria?
❑� 16) Radionuclides: Are quality control sample results provided?
�J a) Are any results flagged or qualified?
�J b) Are Uncertainty, Minimum Detectable Concentration (MDC), and Tracer and/or Carrier % Recoveries provided for each sample?
Lab Qualifiers:
1 - Analyte detected above the MDL, but below the RL; analyte concentration should be considered an estimate.
M1- MS and/or MSD recovery was high; the associated LCS was acceptable. (This qualifier is for non -project QC samples.)
Validation Qualifiers:
R - Result is unusable. The sample result is rejected due to serious deficiencies in meeting quality control criteria; the analyte may or may not be present in the sample.
J - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
U - Analyte was analyzed form but not detected above the minimum detectable concentration (MDC) or method detection limit (MDL).
B -Target analyte detected in the method blank an in the sample at a concentration less than 10x the blank concentration.
• Note: This is a metals re -sample for the surface water locations related to the original CCP LF event collected 4/16 under job order J24030273.
• Calcium (31.2 ug/L) was detected in the Field Blank (J24050031); Calcium was also detected in the samples at concentrations less than 10x the blank concentration.
Review Determination: ❑ Usable ❑ Usable with Required Actions ❑ Unusable
Initials/Signatures: Date:
Data Quality Reviewer REB 6/14/2024
Technical Lead SAS 6/20/2024

DUKE
Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number:
J24040661
Project Name:
CLIFFSIDE - GW CCP LANDFILL
Task Code:
LF
Customer Name(s):
Bill Wylie,Bryan Moeller,Dee O Brien,Josh Stowe
Customer Address:
Cliffside Steam Station
573 Duke Power Rd
Mail Code: Clliffside Steam Station
Mooresboro, NC 28024
Lab Contact:
Peggy Kendall Phone: [phone]
Report Authorized By:
e -Date: 5/13/2024
(Signature)
AP yendall
Program Comments:
Note: This is a metals re -sample for the surface water locations related to the original CCP LF event collected 4/16 under job
orderJ24030273.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time Collected By
2024010619 CLIFFSIDE
2024010620 CLIFFSIDE
2 Total Samples
Sample Description
26-Apr-24 12:50 PM Ryan Byas/ PACE CLS_CCPSW-1
26-Apr-24 1:15 PM Ryan Byas/ PACE CLS_CCPSW-2

Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals❑ Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes ❑� No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
❑d Job Summary Report
❑d Sample Identification
❑� Technical Validation of Data Package
❑d Analytical Laboratory Certificate of Analysis
❑d Analytical Laboratory QC Report
❑ Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑d Chain of Custody
❑d Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 5/13/2024

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24040661
Site: CLS CCPSW-1
Collection Date: 04/26/2024 12:50 PM Loc code: CLS CCPSW-1
Analyte
Result
Units
Qualifiers RDL
MDL
DF
MERCURY (COLD VAPOR) IN WATER - Q24050023
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q24050027
Zinc (Zn)
0.004 U
mg/L
0.015
0.004
1
TOTAL RECOVERABLE METALS BY ICP - Q24050003
Barium (Ba)
0.022
mg/L
0.005
0.002
1
Boron (B)
0.009 J
mg/L
0.05
0.005
1
Calcium (Ca)
2.43
mg/L
0.05
0.012
1
Iron (Fe)
1.10
mg/L
0.01
0.004
1
Lithium (Li)
0.002 U
mg/L
0.005
0.002
1
Magnesium (Mg)
1.20
mg/L
0.02
0.008
1
Manganese (Mn)
0.043
mg/L
0.005
0.001
1
Total Hardness (Ca and Mg)
11.0
mg/L
0.19
1
(CaCO3)
Zinc (Zn)
0.004 U
mg/L
0.015
0.004
1
TOTAL RECOVERABLE METALS BY ICP-MS
(DISSOLVED) - Q24050031
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
Copper (Cu)
0.787 U
ug/L
1
0.787
1
Lead (Pb)
0.037 U
ug/L
1
0.037
1
Nickel (Ni)
0.391 J
ug/L
1
0.256
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Sample #: 2024010619
Matrix: GW RCRA
Method Analysis Date/Time Analyst
EPA 7470A 05/02/2024 11:18 SNEGLIA
SW 601 OD
05/08/2024 08:08
CELL106
SW 601OD
05/02/2024 13:16
CELL106
SW 601OD
05/02/2024 13:16
CELL106
SW 601OD
05/02/2024 13:16
CELL106
SW 601OD
05/02/2024 13:16
CELL106
SW 601OD
05/02/2024 13:16
CELL106
SW 601OD
05/02/2024 13:16
CELL106
SW 601OD
05/02/2024 13:16
CELL106
SW 6010D
05/02/2024 13:16
CELL106
SW 601OD
05/02/2024 13:16
CELL106
SW 6020B
05/06/2024 13:03
SNEGLIA
SW 6020B
05/06/2024 13:03
SNEGLIA
SW 6020B
05/06/2024 13:03
SNEGLIA
SW 6020B
05/06/2024 13:03
SNEGLIA
SW 6020B
05/06/2024 13:03
SNEGLIA
SW 6020B
05/06/2024 13:03
SNEGLIA
SW 6020B
05/06/2024 13:03
SNEGLIA
SW 6020B
05/06/2024 13:03
SNEGLIA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24040661
Site: CLS CCPSW-1
Collection Date: 04/26/2024 12:50 PM Loc code: CLS CCPSW-1
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS - Q24050005
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
Arsenic (As)
0.215 J
ug/L
1
0.111
1
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.307 J
ug/L
1
0.185
1
Cobalt (Co)
0.291 J
ug/L
1
0.077
1
Copper (Cu)
0.787 U
ug/L
1
0.787
1
Lead (Pb)
0.204 J
ug/L
1
0.037
1
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
Nickel (Ni)
0.327 J
ug/L
1
0.256
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.063 J
ug/L
1
0.035
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
Vanadium (V)
0.399 J
ug/L
1
0.114
1
Sample #: 2024010619
Matrix: GW RCRA
Method
Analysis Date/Time
Analyst
SW 6020B
05/02/2024 14:43
SNEGLIA
SW 6020B
05/02/2024 14:43
SNEGLIA
SW 6020B
05/02/2024 14:43
SNEGLIA
SW 6020B
05/02/2024 14:43
SNEGLIA
SW 6020B
05/02/2024 14:43
SNEGLIA
SW 6020B
05/02/2024 14:43
SNEGLIA
SW 6020B
05/02/2024 14:43
SNEGLIA
SW 6020B
05/02/2024 14:43
SNEGLIA
SW 6020B
05/02/2024 14:43
SNEGLIA
SW 6020B
05/02/2024 14:43
SNEGLIA
SW 6020B
05/02/2024 14:43
SNEGLIA
SW 6020B
05/02/2024 14:43
SNEGLIA
SW 6020B
05/02/2024 14:43
SNEGLIA
SW 6020B
05/02/2024 14:43
SNEGLIA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24040661
Site: CLS CCPSW-2
Collection Date: 04/26/2024 01:15 PM Loc code: CLS CCPSW-2
Analyte
Result
Units
Qualifiers RDL
MDL
DF
MERCURY (COLD VAPOR) IN WATER - Q24050023
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q24050027
Zinc (Zn)
0.004 U
mg/L
0.015
0.004
1
TOTAL RECOVERABLE METALS BY ICP - Q24050003
Barium (Ba)
0.022
mg/L
0.005
0.002
1
Boron (B)
0.011 J
mg/L
0.05
0.005
1
Calcium (Ca)
2.54
mg/L
0.05
0.012
1
Iron (Fe)
1.01
mg/L
0.01
0.004
1
Lithium (Li)
0.002 U
mg/L
0.005
0.002
1
Magnesium (Mg)
1.25
mg/L
0.02
0.008
1
Manganese (Mn)
0.041
mg/L
0.005
0.001
1
Total Hardness (Ca and Mg)
11.5
mg/L
0.19
1
(CaCO3)
Zinc (Zn)
0.004 U
mg/L
0.015
0.004
1
TOTAL RECOVERABLE METALS BY ICP-MS
(DISSOLVED) - Q24050031
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.305 J
ug/L
1
0.185
1
Copper (Cu)
0.787 U
ug/L
1
0.787
1
Lead (Pb)
0.119 J
ug/L
1
0.037
1
Nickel (Ni)
0.288 J
ug/L
1
0.256
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Sample #: 2024010620
Matrix: GW RCRA
Method Analysis Date/Time Analyst
EPA 7470A 05/02/2024 11:20 SNEGLIA
SW 601 OD
05/08/2024 08:08
CELL106
SW 601OD
05/02/2024 13:32
CELL106
SW 601OD
05/02/2024 13:32
CELL106
SW 601OD
05/02/2024 13:32
CELL106
SW 601OD
05/02/2024 13:32
CELL106
SW 601OD
05/02/2024 13:32
CELL106
SW 601OD
05/02/2024 13:32
CELL106
SW 601OD
05/02/2024 13:32
CELL106
SW 6010D
05/02/2024 13:32
CELL106
SW 601OD
05/02/2024 13:32
CELL106
SW 6020B
05/06/2024 12:35
SNEGLIA
SW 6020B
05/06/2024 12:35
SNEGLIA
SW 6020B
05/06/2024 12:35
SNEGLIA
SW 6020B
05/06/2024 12:35
SNEGLIA
SW 6020B
05/06/2024 12:35
SNEGLIA
SW 6020B
05/06/2024 12:35
SNEGLIA
SW 6020B
05/06/2024 12:35
SNEGLIA
SW 6020B
05/06/2024 12:35
SNEGLIA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24040661
Site: CLS CCPSW-2
Collection Date: 04/26/2024 01:15 PM Loc code: CLS CCPSW-2
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS - Q24050005
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
Arsenic (As)
0.222 J
ug/L
1
0.111
1
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.43 J
ug/L
1
0.185
1
Cobalt (Co)
0.28 J
ug/L
1
0.077
1
Copper (Cu)
0.787 U
ug/L
1
0.787
1
Lead (Pb)
0.199 J
ug/L
1
0.037
1
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
Nickel (Ni)
0.363 J
ug/L
1
0.256
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.055 J
ug/L
1
0.035
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
Vanadium (V)
0.413 J
ug/L
1
0.114
1
Sample #: 2024010620
Matrix: GW RCRA
Method
Analysis Date/Time
Analyst
SW 6020B
05/02/2024 13:56
SNEGLIA
SW 6020B
05/02/2024 13:56
SNEGLIA
SW 6020B
05/02/2024 13:56
SNEGLIA
SW 6020B
05/02/2024 13:56
SNEGLIA
SW 6020B
05/02/2024 13:56
SNEGLIA
SW 6020B
05/02/2024 13:56
SNEGLIA
SW 6020B
05/02/2024 13:56
SNEGLIA
SW 6020B
05/02/2024 13:56
SNEGLIA
SW 6020B
05/02/2024 13:56
SNEGLIA
SW 6020B
05/02/2024 13:56
SNEGLIA
SW 6020B
05/02/2024 13:56
SNEGLIA
SW 6020B
05/02/2024 13:56
SNEGLIA
SW 6020B
05/02/2024 13:56
SNEGLIA
SW 6020B
05/02/2024 13:56
SNEGLIA
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an estimate.

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24040661
Level II QC Summary
Q24050023 HG 7470 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.004
0.004
ug/L
1
0.01
0.05
< MDL
Blank # 2
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.011
0.011
ug/L
1
0.01
0.05
> MDL
Blank # 3
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.003
0.003
ug/L
1
0.01
0.05
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery LCL UCL
Qualifier
Mercury (Hg)
2.14
2.14
ug/L
1
0.01
2
107 85 115
LCS # 2
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
2.11
2.11
ug/L
1
0.01
2
105
85 115
MS # 1
Parent Sample:
J24040551 -- 2024010187
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.233
0.233
ug/L
1
0.01
1
23.3
75 125
M1
MSD # 1
Parent Sample:
J24040551 -- 2024010187
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.239
0.239
ug/L
1
0.01
1
23.9
75 125 2.54
M1
MS # 2
Parent Sample:
J24040679 -- 2024010692
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.182
0.182
ug/L
1
0.01
1
18.2
75 125
M1
MSD # 2
Parent Sample:
J24040679 -- 2024010692
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.186
0.186
ug/L
1
0.01
1
18.6
75 125 2.17
M1
MS # 3
Parent Sample:
J24050001 -- 2024010755
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.753
0.753
ug/L
1
0.01
1
75.3
75 125
MSD # 3
Parent Sample:
J24050001 -- 2024010755
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.762
0.762
ug/L
1
0.01
1
76.2
75 125 1.19

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24040661
Level II QC Summary
Q24050027 ICP_DIS_TRM TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Zinc (Zn)
0.000527
0.000527
mg/L
1
0.004
0.015
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Zinc (Zn)
5.16
5.16
mg/L
1
0.004
5
103
80
120
MS # 1
Parent Sample:
J24040661
-- 2024010619
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Zinc (Zn)
5.11
5.11
mg/L
1
0.004
5
102
70
130
MSD # 1
Parent Sample:
J24040661
-- 2024010619
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Zinc (Zn)
5.11
5.11
mg/L
1
0.004
5
102
70
130 0
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24040661
Level II QC Summary
Q24050003 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
-0.001
-0.001
mg/L
1
0.002
0.005
< MDL
Boron (B)
0.000019
0.000019
mg/L
1
0.005
0.05
< MDL
Calcium (Ca)
0.00634
0.00634
mg/L
1
0.012
0.05
< MDL
Iron (Fe)
-0.000271
-0.000271
mg/L
1
0.004
0.01
< MDL
Lithium (Li)
-0.000232
-0.000232
mg/L
1
0.002
0.005
< MDL
Magnesium (Mg)
0.000114
0.000114
mg/L
1
0.008
0.02
< MDL
Manganese (Mn)
-0.000171
-0.000171
mg/L
1
0.001
0.005
< MDL
Zinc (Zn)
-0.000241
-0.000241
mg/L
1
0.004
0.015
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
5.05
5.05
mg/L
1
0.002
5
101
80
120
Boron (B)
4.93
4.93
mg/L
1
0.005
5
98.6
80
120
Calcium (Ca)
5.14
5.14
mg/L
1
0.012
5
103
80
120
Iron (Fe)
5.2
5.2
mg/L
1
0.004
5
104
80
120
Lithium (Li)
4.96
4.96
mg/L
1
0.002
5
99.3
80
120
Magnesium (Mg)
5.04
5.04
mg/L
1
0.008
5
101
80
120
Manganese (Mn)
5.08
5.08
mg/L
1
0.001
5
102
80
120
Zinc (Zn)
5
5
mg/L
1
0.004
5
100
80
120
MS # 1
Parent Sample:
J24040661
-- 2024010619
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
5.09
5.09
mg/L
1
0.002
5
101
75
125
Boron (B)
4.91
4.91
mg/L
1
0.005
5
98.1
75
125
Calcium (Ca)
7.47
7.47
mg/L
1
0.012
5
101
75
125
Iron (Fe)
6.19
6.19
mg/L
1
0.004
5
102
75
125
Lithium (Li)
5.01
5.01
mg/L
1
0.002
5
100
75
125
Magnesium (Mg)
6.14
6.14
mg/L
1
0.008
5
98.7
75
125
Manganese (Mn)
5.13
5.13
mg/L
1
0.001
5
102
75
125
Zinc (Zn)
5
5
mg/L
1
0.004
5
100
75
125
MSD # 1
Parent Sample:
J24040661
-- 2024010619
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Barium (Ba)
5.01
5.01
mg/L
1
0.002
5
99.8
75
125
1.54
Boron (B)
4.89
4.89
mg/L
1
0.005
5
97.7
75
125
0.428
Calcium (Ca)
7.36
7.36
mg/L
1
0.012
5
98.7
75
125
1.42
Iron (Fe)
6.11
6.11
mg/L
1
0.004
5
100
75
125
1.3
Lithium (Li)
4.95
4.95
mg/L
1
0.002
5
99
75
125
1.16
Magnesium (Mg)
6.06
6.06
mg/L
1
0.008
5
97.2
75
125
1.23
Manganese (Mn)
5.06
5.06
mg/L
1
0.001
5
100
75
125
1.43
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24040661
Level II QC Summary
Q24050003 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
MSD # I Parent Sample: J24040661 -- 2024010619
Parameter Measured Final Units Dil MDL Spike % Recovery LCL UCL RPD Qualifier
Zinc (Zn) 4.94 4.94 mg/L 1 0.004 5 98.7 75 125 1.23

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24040661
Level II QC Summary
Q24050031 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Beryllium (Be)
0.003
0.003
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0
0
ug/L
1
0.032
1
< MDL
Chromium (Cr)
-0.061
-0.061
ug/L
1
0.185
1
< MDL
Copper (Cu)
0.013
0.013
ug/L
1
0.787
1
< MDL
Lead (Pb)
0.007
0.007
ug/L
1
0.037
1
< MDL
Nickel (Ni)
0
0
ug/L
1
0.256
1
< MDL
Selenium (Se)
-0.003
-0.003
ug/L
1
0.193
1
< MDL
Silver (Ag)
0
0
ug/L
1
0.035
1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Beryllium (Be)
49.9
49.9
ug/L
1
0.249
50
99.7
80
120
Cadmium (Cd)
47.7
47.7
ug/L
1
0.032
50
95.3
80
120
Chromium (Cr)
48.6
48.6
ug/L
1
0.185
50
97.2
80
120
Copper (Cu)
49.3
49.3
ug/L
1
0.787
50
98.6
80
120
Lead (Pb)
49.3
49.3
ug/L
1
0.037
50
98.5
80
120
Nickel (Ni)
48.2
48.2
ug/L
1
0.256
50
96.5
80
120
Selenium (Se)
46.2
46.2
ug/L
1
0.193
50
92.5
80
120
Silver (Ag)
47.9
47.9
ug/L
1
0.035
50
95.9
80
120
MS # 1
Parent Sample:
J24040661
-- 2024010620
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Beryllium (Be)
49.2
49.2
ug/L
1
0.249
50
98.5
75
125
Cadmium (Cd)
47
47
ug/L
1
0.032
50
94
75
125
Chromium (Cr)
48.2
48.2
ug/L
1
0.185
50
95.9
75
125
Copper (Cu)
48.6
48.6
ug/L
1
0.787
50
96.5
75
125
Lead (Pb)
49
49
ug/L
1
0.037
50
97.7
75
125
Nickel (Ni)
47.2
47.2
ug/L
1
0.256
50
93.8
75
125
Selenium (Se)
46.3
46.3
ug/L
1
0.193
50
92.5
75
125
Silver (Ag)
46.6
46.6
ug/L
1
0.035
50
93.3
75
125
MSD # 1
Parent Sample:
J24040661
-- 2024010620
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Beryllium (Be)
50
50
ug/L
1
0.249
50
100
75
125
1.6
Cadmium (Cd)
47.8
47.8
ug/L
1
0.032
50
95.6
75
125
1.69
Chromium (Cr)
49.8
49.8
ug/L
1
0.185
50
99
75
125
3.17
Copper (Cu)
49.2
49.2
ug/L
1
0.787
50
97.8
75
125
1.37
Lead (Pb)
50
50
ug/L
1
0.037
50
99.7
75
125
2.02
Nickel (Ni)
47.8
47.8
ug/L
1
0.256
50
95.1
75
125
1.42
Selenium (Se)
46.4
46.4
ug/L
1
0.193
50
92.8
75
125
0.371
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24040661
Level II QC Summary
Q24050031 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
MSD # 1 Parent Sample: J24040661 -- 2024010620
Parameter Measured Final Units Dil MDL Spike % Recovery LCL UCL RPD Qualifier
Silver (Ag) 47.5 47.5 ug/L 1 0.035 50 94.9 75 125 1.77

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24040661
Level II QC Summary
Q24050005 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
-0.024
-0.024
ug/L
1
0.104
1
< MDL
Arsenic (As)
-0.011
-0.011
ug/L
1
0.111
1
< MDL
Beryllium (Be)
0.004
0.004
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0
0
ug/L
1
0.032
1
< MDL
Chromium (Cr)
-0.182
-0.182
ug/L
1
0.185
1
< MDL
Cobalt (Co)
0.003
0.003
ug/L
1
0.077
1
< MDL
Copper (Cu)
0.007
0.007
ug/L
1
0.787
1
< MDL
Lead (Pb)
0.004
0.004
ug/L
1
0.037
1
< MDL
Molybdenum (Mo)
-0.003
-0.003
ug/L
1
0.18
1
< MDL
Nickel (Ni)
-0.002
-0.002
ug/L
1
0.256
1
< MDL
Selenium (Se)
-0.003
-0.003
ug/L
1
0.193
1
< MDL
Silver (Ag)
0
0
ug/L
1
0.035
1
< MDL
Thallium (TI) Low Level
0
0
ug/L
1
0.041
0.2
< MDL
Vanadium (V)
-0.063
-0.063
ug/L
1
0.114
1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
47.8
47.8
ug/L
1
0.104
50
95.6
80
120
Arsenic (As)
49.3
49.3
ug/L
1
0.111
50
98.6
80
120
Beryllium (Be)
49.9
49.9
ug/L
1
0.249
50
99.9
80
120
Cadmium (Cd)
48.6
48.6
ug/L
1
0.032
50
97.2
80
120
Chromium (Cr)
50.3
50.3
ug/L
1
0.185
50
101
80
120
Cobalt (Co)
50.9
50.9
ug/L
1
0.077
50
102
80
120
Copper(Cu)
50.5
50.5
ug/L
1
0.787
50
101
80
120
Lead (Pb)
50.3
50.3
ug/L
1
0.037
50
101
80
120
Molybdenum (Mo)
50.3
50.3
ug/L
1
0.18
50
101
80
120
Nickel (Ni)
49.8
49.8
ug/L
1
0.256
50
99.6
80
120
Selenium (Se)
49.3
49.3
ug/L
1
0.193
50
98.5
80
120
Silver (Ag)
47.1
47.1
ug/L
1
0.035
50
94.3
80
120
Thallium (TI) Low Level
48.9
48.9
ug/L
1
0.041
50
97.7
80
120
Vanadium (V)
49.6
49.6
ug/L
1
0.114
50
99.2
80
120
NIS # 1
Parent Sample:
J24040661
-- 2024010620
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
47.1
47.1
ug/L
1
0.104
50
94.3
75
125
Arsenic (As)
49.2
49.2
ug/L
1
0.111
50
97.9
75
125
Beryllium (Be)
50.1
50.1
ug/L
1
0.249
50
100
75
125
Cadmium (Cd)
48.1
48.1
ug/L
1
0.032
50
96.1
75
125
Chromium (Cr)
50.5
50.5
ug/L
1
0.185
50
100
75
125
Cobalt (Co)
50.8
50.8
ug/L
1
0.077
50
101
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J24040661
Level II QC Summary
Q24050005 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
Copper(Cu)
50.2
50.2
ug/L
1
0.787
50
Lead (Pb)
50.2
50.2
ug/L
1
0.037
50
Molybdenum (Mo)
49.7
49.7
ug/L
1
0.18
50
Nickel (Ni)
49.7
49.7
ug/L
1
0.256
50
Selenium (Se)
48.2
48.2
ug/L
1
0.193
50
Silver (Ag)
46.7
46.7
ug/L
1
0.035
50
Thallium (TI) Low Level
48.6
48.6
ug/L
1
0.041
50
Vanadium (V)
49.7
49.7
ug/L
1
0.114
50
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
Antimony (Sb)
47.8
47.8
ug/L
1
0.104
50
Arsenic (As)
49.6
49.6
ug/L
1
0.111
50
Beryllium (Be)
50.6
50.6
ug/L
1
0.249
50
Cadmium (Cd)
48.7
48.7
ug/L
1
0.032
50
Chromium (Cr)
50.6
50.6
ug/L
1
0.185
50
Cobalt (Co)
50.9
50.9
ug/L
1
0.077
50
Copper (Cu)
50.7
50.7
ug/L
1
0.787
50
Lead (Pb)
50.9
50.9
ug/L
1
0.037
50
Molybdenum (Mo)
50.2
50.2
ug/L
1
0.18
50
Nickel (Ni)
49.5
49.5
ug/L
1
0.256
50
Selenium (Se)
48.6
48.6
ug/L
1
0.193
50
Silver (Ag)
47.2
47.2
ug/L
1
0.035
50
Thallium (TI) Low Level
49.2
49.2
ug/L
1
0.041
50
Vanadium (V)
50.1
50.1
ug/L
1
0.114
50
Parent Sample: J24040661 -- 2024010620
% Recover v
LCL
UCL
99.8
75
125
100
75
125
99.4
75
125
98.6
75
125
96.2
75
125
93.4
75
125
97.1
75
125
98.6
75
125
Parent Sample: J24040661 -- 2024010620
% Recovery
LCL
UCL
RPD
95.6
75
125
1.46
98.7
75
125
0.81
101
75
125
0.918
97.5
75
125
1.36
100
75
125
0.146
101
75
125
0.107
101
75
125
0.973
101
75
125
1.38
100
75
125
0.881
98.2
75
125
0.35
97.1
75
125
0.892
94.2
75
125
0.889
98.3
75
125
1.22
99.3
75
125
0.714
Qualifier
Qualifier

CHAIN OF CUSTODY RECORD AND
T FORM
DUKE
�"C
Duke Energy Ana at Laaoratory ; ;
Mell Cede 9 Hager Ie FerryRd 7405I I IOider M `
FeryRd
ENERGY
Nunh(7041 e, N,C. 20078 I �—
umer 111.,
f7ot1 alssxt9 i reed By
Faa: 7W 97ade98 I I
Project Name ROGERS CIJFFSIDE CCP pho" N,!
LANDFILL PERMIT# 81-05
Client BILL WYUE, BRYAN MOELLER,
DEE O'BRIEN, JOSH STOWE
Operating Unit: C556
Procesa:NORDWTR
Account:
Project: ACS56DO62
Activlty ID:
Facility ID: CLS
Program I EQuiS Task Cade: CLS I Sub-Programrrask Code:
CCPI LF
Sample Description or ID
;Vender
i
I'Poa
i
Filtration (0.45 utnE
Preservative
Container Volume (mLi
Container Type
Customer to complete all appropriate non -shaded areas.
Collection Imormation
F
W. Orlp —N Fn NO—
Sc_
SAMPLE PROGRAM
Ground Water x NPDES
Drinking Water_ UST,
RCRA Waste _
b Unfiltered
500
HOPE
(Metals Prep -TRMI!
(ICP - sw 6010D) Be. B,
Ca, Fa, LI, Mg, Mn, Zn
(8)1 Hg (SW 7470AI I
DIMS - SW 6020B) Sh,
As. Be, Cd, Cr, Co, Cu.
Pb, Me, NI, Se, Ag,
THLL],,V N 41
1
Page _1_ of _1_
DISTRIBUTION
ORIGINAL to LAB, COPY to CLIENT
1l1MG24
b
Filtered
500
HDPE
SW6010D ZnI
c
SW 60208 Be,
Cd, Or, Cu, Pb,
U
Nf, Se, Ag
r
1
2
[
)L
y
Relinquished By
Datel7ime
ACCAM By:
Da /Time
P:
Requested Turnaround
C
Relinquished By Datemme
Accepted By: - Dateurnme
w a
,e c
m �
a
21 Days
Reanqulahod By Daternme
Accepted By: Date111me
�E
,
o a
14 Days X
SeatfLocked By Daternme
SeaiedlLock Opened By Daternme
a
7 Days
E w
v
`m
Comments
Regulatory Agency: NCDENRIDWm - SW Section EQUIS REQUIRED 1 PERMIT t181-06 Include Total Hardness
for CCPSW-1,CCPSW-2, CCPSW-3
E
m
'Other
' Add. Cost Will Apply
t)