Press Alt + R to read the document text or Alt + P to download or print.

No preview available

The URL can be used to link to this page

Home My WebLink About8102_Rutherford_South_MSWLF_April2024GW_FID1891383_20240801DEN R USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR I IEnvironmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Bunnell-Lammons Engineering, Inc. (consultant) Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Andrew W. Alexander. P.G. RSM Phone: (864) 288-1265 E-mail: andy.alexander(cDblecorp.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Rutherford County Avondale Landfill Rd 8102-MSWLF- April 19, 2024 South Landfill Mooresboro, NC 28114 1977 .0500 Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑X Detection Monitoring ❑ Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Groundwater monitoring data from private water supply wells ❑ Leachate monitoring data El water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Andrew W. Alexander, P.G. RSM Consultant Hydrogeologist (864) 288-1265 Facility Representative Name (Print) Title (Area Code) Telephone Number �� w a• �E,o•,........ , .a•",•o.o 08/01/2024 Signature Date 6004 Ponders Court, Greenville, SC, 29615 Facility Representative Address C-284 & C-1538 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 Affix NC Licensed/ Professional Geologist Seal SEMI-ANNUAL WATER QUALITY MONITORING REPORT FIRST EVENT OF 2024 RUTHERFORD COUNTY SOUTH LANDFILL RUTHERFORD COUNTY, NORTH CAROLINA Permit No. 8102-MSWLF-1977 Prepared For: Rutherford County Solid Waste Dept. Rutherfordton, North Carolina BLE Project Number J24-20955-02 August 1, 2024 BLE North Carolina Business Licenses C-284 & C-1538 is IM IM BUNNELL M LAMMONS ENGINEERING 6004 Ponders Court I Greenville, 5C 29615 864,288.1265 �I 864.288,4330 0 info@blecorp.com BLECORP.COM � CANNONS ENGINEERING August 1, 2024 Rutherford County Solid Waste Department P.O. Box 1957 Rutherfordton, North Carolina 28139 Attention: Mr. James Kilgo Subject: Semi -Annual Water Quality Monitoring Report First Event of 2024 Rutherford County South Landfill Rutherford County, North Carolina Facility Permit Number 8102-MSWLF-1977 BLE Project Number J24-20955-02 Dear Mr. Kilgo: Pursuant to authorization of Bunnell-Lammons Engineering, Inc. (BLE) contract number J24-20955-02, dated January 26, 2024, BLE has prepared this water quality report for the first semi-annual sampling event of 2024 at the Rutherford County South Landfill. Consistent with the North Carolina Division of Waste Management (DWM) — Solid Waste Section (SWS) approved monitoring program, sampling and analyses will be conducted twice in 2024. This report contains the information required by the SWS to document the sampling and analysis activities for the first event of 2024 in the State's permanent project record. Sincerely, BUNNELL LAMMONS ENGINEERING INC. ucker C. Ge gigaer Staff Geologist cc: Ms. Jackie Drummond —NC SWS 6 W / A �� Andrew W. Alex der, P.G., RSM Consultant Hydrogeologist Registered, NC #1475 '6004 Panders Court, Greenville, SC 29615 1,864,288.1265 A864,288.4430 info@hleccrp,com 6LECORP.COM 1s 1m 1i Water Quality Report -1st Semi -Annual Event 2024 August 1, 2024 Rutherford County South Landfill — Rutherford Co., North Carolina BLE Project No. J24-20955-02 TABLE OF CONTENTS 1.0 PROJECT INFORMATION........................................................................................................1 2.0 FIELD ACTIVITIES, SAMPLING, AND ANALYSIS.............................................................1 3.0 GROUNDWATER FLOW........................................................................................................... 2 4.0 RESULTS....................................................................................................................................... 2 4.1 Groundwater.................................................................................................................................... 2 4.2 Surface Water.................................................................................................................................. 2 4.3 PFAS Results................................................................................................................................... 2 5.0 SUMMARY AND RECOMMENDATIONS............................................................................... 2 6.0 QUALIFICATIONS OF REPORT.............................................................................................. 3 7.0 CLOSING.......................................................................................................................................3 Tables Table 1 SWS Approved Monitoring Matrix Table 2 Groundwater Monitoring Well Data Table 3 Groundwater VOCs Table 4 Groundwater Field Parameters and Total Metals Table 5 Surface Water VOCs Table 6 Surface Water Field Parameters and Total Metals Table 7 Summary of Per- and Polyfluoroalkyl Substances (PFAS) in Groundwater Table 8 Summary of Per- and Polyfluoroalkyl Substances (PFAS) in Surface Water Figures Figure 1 Site Location Map Figure 2 Groundwater Elevation Contour Map — April 19, 2024 Appendices Appendix A Field Sampling Logs — Pace Analytical Services, LLC. Appendix B Laboratory Analytical Data — Pace Analytical Services, LLC. iofi 1s 1m 1i Water Quality Report -1st Semi -Annual Event 2024 August 1, 2024 Rutherford County South Landfill — Rutherford Co., North Carolina BLE Project No. J24-20955-02 1.0 PROJECT INFORMATION The subject landfill site is located in Rutherford County, North Carolina, southeast of the town of Forest City with a physical address of 4 Avondale Landfill Road (Figure 1). Rutherford County owns the unlined inactive/closed MSWLF (Permit No. 8102-MS)VLF-1977). The existing groundwater monitoring network for the Rutherford County South Landfill consists of ten (10) wells (MW-1, MW-2A, MW-3, MW-4A, MW-5, MW-6, MW-7, MW-8, MW-9S, and MW-91)) [Figure 21. In accordance with rule 15A NCAC 13B .0602, two (2) surface water monitoring locations have been established for the facility to monitor surface water quality near the closed waste footprint. The existing surface water locations are designated SW-1 and SW-2 (Figure 2). The SWS issued a memorandum dated March 13, 2023 to all solid waste directors and landfill owners/operators. The memo requires that all groundwater, surface water, and leachate samples collected at solid waste sanitary landfills after July 1, 2023 be analyzed for PFAS. The SWS issued a second memorandum dated July 17, 2023 to all solid waste directors and landfill owners/operators. The second memo provides clarification to the PFAS monitoring requirements including an option to propose a subset of assessment/corrective action groundwater monitoring wells and a subset of surface water monitoring points. Odom Engineering, PLLC. on behalf of Rutherford County, issued a notice to the SWS dated September 25, 2023 (FID 1818145) that the facility would initiate the required PFAS monitoring program beginning with the April 2024 water quality sampling event. The SWS approved the monitoring request on September 27, 2023 (FID 1818149). The April 2024 event is the first PFAS monitoring event conducted at the Rutherford County South Landfill. 2.0 FIELD ACTIVITIES, SAMPLING, AND ANALYSIS Groundwater and surface water samples were collected for the first semi-annual sampling event by personnel from Pace Analytical Services, LLC. (Pace) on April 19, 2024. Groundwater samples were collected from the groundwater monitoring well locations located on the site as specified on Table 1. Both surface water locations were sampled during the event. The groundwater and surface water samples were delivered to and analyzed in Pace's Asheville, North Carolina, Charlotte, North Carolina, and Mt. Juliet, Tennessee laboratories for the constituents in the approved matrix (Table 1). PFAS samples were analyzed in Pace's Minneapolis Minnesota laboratory. The field parameters of pH, specific conductance, turbidity, and temperature were measured in the field by Pace. A copy of the Pace field sampling logs is included in Appendix A. A copy of the laboratory analytical data is included in Appendix B. A duplicate sample was collected from one well (MW-9S) in accordance with the quality control program (Table 1). The duplicate sample was laboratory blind. The laboratory results for the duplicate sample are included in Appendix B. 1 of 3 1s 1m 1i Water Quality Report -1st Semi -Annual Event 2024 August 1, 2024 Rutherford County South Landfill — Rutherford Co., North Carolina BLE Project No. J24-20955-02 3.0 GROUNDWATER FLOW The water level data collected during the groundwater sampling event on April 19, 2024 are presented in Table 2. A groundwater elevation contour map is presented as Figure 2 which includes generalized groundwater flow directions. 4.0 RESULTS 4.1 Groundwater The results of the groundwater field and laboratory analyses are summarized in Table 3 and Table 4 and the laboratory analytical data are included in Appendix B. Please refer to Table 3 and Table 4 for a summary of which groundwater constituents exceeded North Carolina Groundwater Quality Standards (NC2L) maximum contaminant levels' (MCLs). Field parameters measured in the groundwater included pH, specific conductance, turbidity, and temperature. The field parameter of pH was below its NC2L standard in all nine (9) of the sampled wells. Previous semi- annual reports for the subject site indicate that pH is frequently detected below the NC2L standards in the majority of the wells on site. No other field parameters were outside the NC2L standard limits for groundwater, if established. 4.2 Surface Water The results of the surface water field and laboratory analyses are summarized in Table 5 and Table 6 and the laboratory analytical data are included in Appendix B. Please refer to Table 5 and Table 6 for a summary of which surface water constituents exceeded their established North Carolina Surface Water Quality Standards (NC2B)2 standard limits. Field parameters measured in the surface water included pH, specific conductance, turbidity, and temperature. None of the sampled field parameters were outside their NC2B standard limits for surface water, if established. 4.3 PFAS Results The results of the PFAS analytical data are summarized in Table 7 (groundwater) and Table 8 (surface water). The laboratory analytical data is included in Appendix B. Please refer to Table 7 and Table 8 for a summary of which water constituents and field parameters exceeded their Health Advisory, Regional Screening Level, and/or MCL. 5.0 SUMMARY AND RECOMMENDATIONS Semi-annual assessment monitoring was performed during the first semi-annual event of 2024 in general accordance with the approved WQMP and SWS approved monitoring matrix (Table 1). Detected constituents which exceed their respective groundwater and surface water standards are identified on the summary tables. 'North Carolina Department of Environmental Quality, Classifications of Water Quality Standards, Section 15A NCAC 2L.0202, April 1, 2022. 2 North Carolina Department of Environmental Quality, Surface Waters and Wetlands Standards, Section 15A NCAC 02B workbook dated July 26, 2021. 2 of 3 1s 1M 1i Water Quality Report -1st Semi -Annual Event 2024 August 1, 2024 Rutherford County South Landfill — Rutherford Co., North Carolina BLE Project No. J24-20955-02 We recommend that semi-annual sampling continue in accordance with the SWS approved monitoring matrix. 6.0 QUALIFICATIONS OF REPORT The activities and evaluative approaches used in this assessment are consistent with those normally employed in hydrogeological and environmental assessments of this type. Our evaluation of site conditions has been based on our understanding of the site and project information and the data provided to BLE. This report has been prepared on behalf of and exclusively for the use of Rutherford County, North Carolina. This report and the fmdings contained herein shall not, in whole or in part, be used or relied upon by any other party (excluding the SWS) without BLE's prior written consent. 7.0 CLOSING We appreciate the opportunity to be of service to Rutherford County, North Carolina. Please contact us at (864) 288-1265 if you have any questions or comments. 3 of 3 TABLES Table 1 Spring 2024 Only - SWS Approved Monitoring Matrix Rutherford County South Landfill Avondale, North Carolina Permit No. 8102-MSWLF-1977 BLE Project Number J24-20955-02 Spring 2024 (April 2024) *Analytical Suite* 1,4-Dioxane PFAS Field Station ID a 0 3 MW-4A A-1 Yes Yes Yes - G U C� MW-1 A-1 Yes Yes Yes - G MW-2A A-1 Yes Yes Yes - G MW-3 A-1 Yes Yes Yes - G d MW-5 A-1 Yes Yes Yes - G o 3 MW-6 A-1 Yes Yes Yes - G 0 U MW-7 A-1 Yes Yes Yes - G MW-8 A-1 Yes Yes Yes - G MW-9S A-1 Yes Yes Yes - G MW-9D A-1 Yes Yes Yes - G w i SW-1 A-1 Yes Yes Yes - S L � �3 � SW-2 A-1 Yes Yes Yes- S Duplicate A-1 VOC Only - - - (1 Sample) L �, Field Blank (1 Sample) Yes U Equipment Rinse (1 Sample) - - Yes - Notes: A-1 = Appendix I VOCs & RCRA Metals S = Surface Water Field Parameters Specific Conductance Turbidity Temperature pH RCSLF SWS Approved Matrix 20955-02 T1 Spring 2024 Matrix G = Groundwater Field Parameters Water Level Oxidation Reduction Potential Dissolved Oxygen Specific Conductance Turbidity Temperature pH Prepared by: AWA Checked by: RLB Table 2 Groundwater Monitoring Well Data Rutherford County South Landfill Rutherford Co., North Carolina Permit No. 8102-MSWLF-1977 BLE Project Number J24-20995-02 Monitoring Point Latitude (north) Longitude (west) Northing Easting TOCI Ground Surface Elevation Depth to GW (ft) April 19, 2024 Groundwater Elevation (ft) Well Depth (below TOC) Geology Monitored Well Status/Purpose MW-1 DNA DNA DNA DNA 811.88 DNA 30.28 781.60 37.58 DNA Compliance MW-2A DNA DNA DNA DNA 790.40 DNA 29.67 760.73 45.21 DNA Compliance MW-3 DNA DNA DNA DNA 783.42 DNA 14.18 769.24 19.00 DNA Compliance MW-4A DNA DNA DNA DNA 845.17 DNA 22.43 822.74 30.35 DNA Background MW-5 DNA DNA DNA DNA 765.32 DNA 10.90 754.42 20.13 DNA Compliance MW-6 DNA DNA DNA DNA 801.87 DNA 26.98 774.89 37.00 DNA Compliance MW-7 DNA DNA DNA DNA 770.68 DNA 13.35 757.33 30.30 DNA Compliance MW-8 DNA DNA DNA DNA 813.03 DNA 30.87 782.16 42.30 DNA Compliance MW-9S DNA DNA DNA DNA 763.93 DNA 6.21 757.72 24.85 DNA Compliance MW-9D DNA DNA DNA DNA 764.28 DNA 5.63 758.65 67.70 DNA Compliance Notes• 1 - Data from report titled Results of Water Quality Sampling - June 2023 (FID 1817170) prepared by Scarlett Geophysical Consulting, PC. dated 8/25/23 TOC - Top Of Casing GS - Ground Surface All depth measurments in feet DNA - Data Not Available 20955-02 GW Tables (Completion, water levels, detections) Prepared by: TCG T2 MW Points Checked by: RLB Table 3 Groundwater VOCs Rutherford County South Landfill Rutherford Co., North Carolina Permit No. 8102-MSWLF-1977 BLE Project Number J24-20995-02 Sampled by Pace Analytical Services, LLC April 19, 2024 Compliance Wells TEST UNITS RL MDL MCL MW-1 MW-2A MW-3 MW-4A MW-5 MW-6 MW-7 MW-8 MW-9S MW-91) Acetone µg/L 25.0 5.1 6,000 <5.1 <5.1 <5.1 <5.1 <5.1 <5.1 <5.1 <5.1 <5.1 <5.1 Acrylonitrile lLg/L 10.0 1.8 NE <1.8 <1.8 <1.8 <1.8 <1.8 <1.8 <1.8 <1.8 <1.8 <1.8 Benzene µg/L 1.0 0.34 1.0 1.4 0.44 J <0.34 <0.34 0.48 J 1.1 <0.34 <0.34 <0.34 <0.34 Bromochloromethane µg/L 1.0 0.47 NE <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 Bromodichloromethane µg/L 1.0 0.31 0.6 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 Bromoform µg/L 1.0 0.34 4.0 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 Carbon Disulfide µg/L 2.0 0.36 700 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 Bromomethane (Methylbromide) µg/L 2.0 1.7 10 <1.7 <1.7 <1.7 <1.7 <1.7 <1.7 <1.7 <1.7 <1.7 <1.7 Carbon tetrachloride µg/L 1.0 0.33 0.3 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 Chlorobenzene (mono) µg/L 1.0 0.28 50 1.4 4.1 <0.28 <0.28 1.2 2.7 <0.28 <0.28 <0.28 <0.28 Chloroethane µg/L 1.0 0.65 3,000 5.0 0.79 J <0.65 <0.65 1.1 <0.65 <0.65 <0.65 <0.65 <0.65 Chloroform µg/L 1.0 0.43 70 0.51 J <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 Chloromethane (Methylchloride) µg/L 1.0 0.54 3.0 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 Dibromochloromethane µg/L 1.0 0.36 0.4 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 1,2-Dibromo-3-chloropropane; DBCP µg/L 2.0 0.34 0.04 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 1,2-Dibromoethane; Ethylene dibromide µg/L 1.0 0.27 0.02 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 Dibromomethane µg/L 1.0 0.39 70 (i) <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 1,2-Dichlorobenzene µg/L 1.0 0.34 20 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 1,4-Dichlorobenzene µg/L 1.0 0.33 6.0 <0.33 1.4 <0.33 <0.33 1.1 1.0 <0.33 <0.33 <0.33 <0.33 trans-1,4-Dichloro-2-butene µg/L 1.0 0.56 NE <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 1,1-Dichloroethane µg/L 1.0 0.37 6.0 48.3 <0.37 <0.37 <0.37 1.4 0.70 J <0.37 1.4 <0.37 <0.37 1,2-Dichloroethane µg/L 1.0 0.32 0.4 0.46 J <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 1,1-Dichloroethene (-ethylene) µg/L 1.0 0.35 350 1.0 <0.35 <0.35 <0.35 <0.35 <0.35 <0.35 <0.35 <0.35 <0.35 cis-1,2-Dichloroethene (-ethylene) µg/L 1.0 0.38 70 5.6 <0.38 <0.38 <0.38 3.2 1.6 <0.38 <0.38 <0.38 <0.38 trans-1,2-Dichloroethene (-ylene) µg/L 1.0 0.40 100 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 1,2-Dichloropropane µg/L 1.0 0.36 0.6 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 cis-1,3-Dichloropropene (-propylene) µg/L 1.0 0.36 0.4 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 trans-1,3-Dichloropropene (-propylene) µg/L 1.0 0.36 0.4 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 Ethylbenzene µg/L 1.0 0.30 600 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 2-Hexanone µg/L 5.0 0.48 40 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48 Iodomethane µg/L 20.0 9.7 NE <9.7 <9.7 <9.7 <9.7 <9.7 <9.7 <9.7 <9.7 <9.7 <9.7 Dichloromethane (Methylene chloride) µg/L 5.0 2.0 5.0 16.8 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 2-Butanone (Methyl ethyl ketone) µg/L 5.0 4.0 4,000 <4.0 <4.0 <4.0 <4.0 <4.0 <4.0 <4.0 <4.0 <4.0 <4.0 4-Methyl-2-Pentanone µg/L 5.0 2.7 NE <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 Styrene µg/L 1.0 0.29 70 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 1, 1, 1,2-Tetrachloroethane µg/L 1.0 0.31 1.0 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 1,1,2,2-Tetrachloroethane µg/L 1.0 0.22 0.2 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 Tetrachloroethene (-ethylene) µg/L 1.0 0.29 0.7 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 Toluene µg/L 1.0 0.24 600 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 1, 1, 1 -Trichloroethane µg/L 1.0 0.33 200 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 1,1,2-Trichloroethane µg/L 1.0 0.32 0.6 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 Trichloroethene (-ethylene) µg/L 1.0 0.38 3.0 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 Trichlorofluoromethane µg/L 1.0 0.30 2,000 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 1,2,3-Trichloropropane µg/L 1.0 0.26 0.005 <0.26 <0.26 <0.26 <0.26 <0.26 <0.26 <0.26 <0.26 <0.26 <0.26 Vinyl acetate µg/L 2.0 1.3 88 (i) <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 Vinyl chloride µg/L 1.0 0.39 0.03 <0.39 <0.39 <0.39 <0.39 0.84 J <0.39 <0.39 <0.39 <0.39 <0.39 Total Xylenes µg/L 1.0 0.34 500 2.5 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 1,4-Dioxane 3.0 0.60 3.0 <0.60 7.60 <0.60 <0.60 10.7 35.1 <0.60 <0.60 <0.60 <0.60 Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable to Groundwaters of North Carolina, Section 15A NCAC 2L .0202. Amended Eff. April 1, 2022 2. (i) = Interim Maximum Allowable Concentrations (IMACs). Updated April 1, 2022 3. Shaded cells indicate exceedances of lMACs 4. Shaded cells indicated exceedances of MCLs 5. NE = Not Established; North Carolina has not established a MCL 6. RL = Reporting Limit 7. MDL = Method Detection Limit 8. NT = Not Tested 9. NS = Not Sampled 10. "J"-flagged data (i.e., values estimated between the MDL and the RL) are presented on this spreadsheet. 20955-02 GW Tables (Completion, water levels, detections) Prepared by: TCG T3 (4-19-24) VOC Checked by: RLB Table 4 Groundwater Field Parameters and Total Metals Rutherford County South Landfill Rutherford Co., North Carolina Permit No. 8102-MSWLF-1977 BLE Project Number J24-20995-02 Sampled by Pace Analytical Services, LLC April 19, 2024 Compliance Wells TEST UNITS RL MDL MCL MW-1 MW-2A MW-3 MW-4A MW-5 MW-6 MW-7 MW-8 MW-9S MW-9D PH S.U. <6.5; >8.5 5.2 6.1 5.2 5.0 6.2 6.2 5.1 5.1 5.1 5.7 Specific Conductance µmhos/cm NE 48.5 335.0 67.2 39.6 403.0 861 35.2 36.8 34.8 38.5 Temperature °C NE 22.9 21.3 24.4 21.4 15.5 22.1 20.2 18.1 16.1 17.1 Turbidity NTU NE 1.7 4.5 1.5 4.1 7.4 1.2 9.3 7.1 3.7 0.9 Total Arsenic (As) µg/L 10 2.5 10 <2.5 13.3 <2.5 <2.5 5.8 J <2.5 <2.5 <2.5 <2.5 <2.5 Total Barium (Ba) µg/L 5.0 0.79 700 75.8 124 38.0 30.9 173 27.0 31.7 118 28.3 25.3 Total Cadmium (Cd) µg/L 1.0 0.29 2.0 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 Total Chromium (Cr) µg/L 5.0 0.63 10 <0.63 9.4 <0.63 <0.63 <0.63 <0.63 0.80 J <0.63 <0.63 <0.63 Total Lead (Pb) µg/L 5.0 1.4 15 <1.4 <1.4 <1.4 <1.4 3.1 J <1.4 <1.4 1.7 J <1.4 <1.4 Total Mercury (Hg) µg/L 0.20 0.12 1.0 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 0.99 <0.12 <0.12 Total Selenium (Se) µg/L 10 4.1 20 <4.1 <4.1 <4.1 <4.1 <4.1 <4.1 <4.1 <4.1 <4.1 <4.1 Total Silver A 5.0 0.49 20 1 <0.49 <0.49 1 <0.49 <0.49 <0.49 1 <0.49 <0.49 <0.49 <0.49 <0.49 Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable to Groundwaters of North Carolina, Section 15A NCAC 2L .0202. Amended Eff. April 1, 2022 2. Shaded cells indicated exceedances of MCLs 3. NE = Not Established; North Carolina has not established a MCL 4. RL = Reporting Limit 5. MDL = Method Detection Limit 6. NT = Not Tested 7. NS = Not Sampled 8. "J"-flagged data (i.e., values estimated between the MDL and the RL) are presented on this spreadsheet. 20955-02 GW Tables (Completion, water levels, detections) T4 (4-19-24) Metals Prepared by: TCG Checked by: RLB Table 5 Surface Water VOCs Rutherford County South Landfill Rutherford Co., North Carolina Permit No. 8102-MSWLF-1977 BLE Project Number J24-20955-02 Sampled by Pace Analytical Services, LLC April 19, 2024 TEST Acetone UNITS RL MDL NC211 SW-1 SW-2 µg/L 25.0 5.1 2,000 <5.1 <5.1 Acrylonitrile µg/L 10.0 1.8 0.061 <1.8 <1.8 Benzene µg/L 1.0 0.34 1.19 <0.34 <0.34 Bromochloromethane µg/L 1.0 0.47 NE <0.47 <0.47 Bromodichloromethane µg/L 1.0 0.31 NE <0.31 <0.31 Bromoform µg/L 1.0 0.34 7 <0.34 <0.34 Carbon Disulfide µg/L 2.0 0.36 100 <0.36 <0.36 Bromomethane (Methylbromide) µg/L 2.0 1.7 0.04 <1.7 <1.7 Carbon tetrachloride µg/L 1.0 0.33 0.254 <0.33 <0.33 Chlorobenzene (mono) µg/L 1.0 0.28 488 <0.28 <0.28 Chloroethane µg/L 1.0 0.65 NE <0.65 <0.65 Chloroform µg/L 1.0 0.43 60 <0.43 <0.43 Chloromethane (Methylchloride) µg/L 1.0 0.54 20 <0.54 <0.54 Dibromochloromethane µg/L 1.0 0.36 0.8 <0.36 <0.36 1,2-Dibromo-3-chloropropane; DBCP µg/L 2.0 0.34 0.13 <0.34 <0.34 1,2-Dibromoethane; Ethylene dibromide µg/L 1.0 0.27 0.1 <0.27 <0.27 Dibromomethane µg/L 1.0 0.39 NE <0.39 <0.39 1,2-Dichlorobenzene µg/L 1.0 0.34 448 <0.34 <0.34 1,4-Dichlorobenzene µg/L 1.0 0.33 448 <0.33 <0.33 trans-1,4-Dichloro-2butene µg/L, 1.0 0.56 NE <0.56 <0.56 1, 1 -Dichloroethane µg/L 1.0 0.37 100 <0.37 <0.37 1,2-Dichloroethane µg/L 1.0 0.32 650 <0.32 <0.32 1, 1 -Dichloroethene (-ethylene) µg/L 1.0 0.35 20,000 <0.35 <0.35 cis-1,2-Dichloroethene (-ethylene) µg/L 1.0 0.38 720 <0.38 <0.38 trans-1,2-Dichloroethene (-ylene) µg/L 1.0 0.40 4,000 <0.40 <0.40 1,2-Dichloropropane µg/L 1.0 0.36 31 <0.36 <0.36 cis-1,3-Dichloropropene (-propylene) µg/L 1.0 0.36 NE <0.36 <0.36 trans-1,3-Dichloropropene (-propylene) µg/L 1.0 0.36 NE <0.36 <0.36 Ethylbenzene µg/L 1.0 0.30 97 <0.30 <0.30 2-Hexanone µg/L 5.0 0.48 NE <0.48 <0.48 Iodomethane µg/L 20.0 9.7 NE <9.7 <9.7 Dichloromethane (Methylene chloride) µg/L 5.0 2.0 1,000 <2.0 <2.0 2-Butanone (Methyl ethyl ketone) µg/L 5.0 4.0 26,000 <4.0 <4.0 4-Methyl-2-Pentanone µg/L 5.0 2.7 26,000 <2.7 <2.7 Styrene µg/L 1.0 0.29 NE <0.29 <0.29 1, 1, 1,2-Tetrachloroethane µg/L 1.0 0.31 NE <0.31 <0.31 1,1,2,2-Tetrachloroethane µg/L 1.0 0.22 0.2 <0.22 <0.22 Tetrachloroethene (-ethylene) µg/L 1.0 0.29 0.7 <0.29 <0.29 Toluene µg/L 1.0 0.24 11 <0.24 <0.24 1, 1, 1 -Trichloroethane µg/L 1.0 0.33 200,000 <0.33 <0.33 1,1,2-Trichloroethane µg/L 1.0 0.32 8.9 <0.32 <0.32 Trichloroethene (-ethylene) µg/L 1.0 0.38 3 <0.38 <0.38 Trichlorofluoromethane µg/L 1.0 0.30 67,000 <0.30 <0.30 1,2,3-Trichloropropane µg/L 1.0 0.26 0.001 <0.26 <0.26 Vinyl acetate µg/L 2.0 1.3 NE <1.3 <1.3 Vinyl chloride µg/L 1.0 0.39 0.025 <0.39 <0.39 Total Xylenes µg/L 1.0 0.34 670 <0.34 <0.34 1,4-Dioxane µg/L 3.0 0.60 80 <0.60 <0.60 Notes: 1. NC213 = North Carolina Surface Water Standards for Class WS-IV freshwater under Title 15A Subchapter 2B. per NC DWR Surface Water Quality Standards, Criteria, & In -Stream Target Values (Workbook Dated 7-26-2021) 2. NE = Not Established; North Carolina has not established a MCL 3. Shaded cells indicated exceedances of MCLs 4. RL = Reporting Limit 5. MDL = Method Detection Limit 6. NT = Not Tested 7. NS = Not Sampled 8. "J"-flagged data (i.e., values estimated between the MDL and the RL) are presented on this spreadsheet. 20955-02 SW Tables Prepared by: TCG T5 SW VOC (4-19-24) Checked by: RLB Table 6 Surface Water Field Parameters and Total Metals Rutherford County South Landfill Rutherford Co., North Carolina Permit No. 8102-MSWLF-1977 BLE Project Number J24-20955-02 Sampled by Pace Analytical Services, LLC April 19, 2024 TEST UNITS RL MDL NC2B SW-1 SW-2 pH s.u. (on -site) - - <6.0; >9.0 6.5 6.5 Specific Conductance µmhos/cm (on -site) - - NE 78.0 73.1 Temperature °C (on -site) - - 29.0 19.2 17.0 Turbidity NTU (on -site) - - 50.0 49.4 7.2 Hardness mg/L 10 NT 100 NT NT Total Arsenic (As) µg/L 20.0 4.9 10 <4.9 <4.9 Total Barium (Ba) µg/L 10.0 1.60 1,000 39.8 30.8 Total Cadmium (Cd) µg/L 2.0 0.58 0.82 <0.58 <0.58 Total Chromium (Cr) µg/L 10.0 1.30 183.07 2.4 J <1.30 Total Lead (Pb) µg/L 10.0 2.7 13.88 <2.7 <2.7 Total Mercury (Hg) µg/L 0.20 0.12 0.012 <0.12 <0.12 Total Selenium (Se) µg/L 50.0 20.6 5.0 <20.6 <20.6 Total Silver A µ /L 10.0 0.98 0.3 <0.98 <0.98 Notes: 1. NC2B = North Carolina Surface Water Standards for Class WS-IV freshwater under Title 15A Subchapter 2B. per NC DWR Surface Water Quality Standards, Criteria, & In -Stream Target Values (Workbook Dated 7-26-2021) A hardness of 25 mg/L was utilized to calculate an acute standard at each surface water location for metals highlighted in green. 2. NE = Not Established; North Carolina has not established a standard 3. Shaded cells indicated exceedances of MCLs 4. RL = Reporting Limit 5. MDL = Method Detection Limit 6. NT = Not Tested 7. NS = Not Sampled 8. "J"-flagged data (i.e., values estimated between the MDL and the RL) are presented on this spreadsheet. 20955-02 SW Tables Prepared by: TCG T6 SW Metals (4-19-24) Checked by: RLB Table 7 Summary of Per- and Polyfluoroalkyl Substances (PFAS) in Groundwater Rutherford County South Landfill Rutherford Co., North Carolina Permit No. 8102-MSWLF-1977 BLE Project Number J24-20995-02 Sampled by Pace Analytical Services, LLC April 19, 2024 TEST CAS Number UNITS Method Analytical LOQ HA Interim Final HA MCL RSL MW-1 MW-2A MW-3 MW-4A MW-5 MW-6 MW-7 MW-8 MW-9S MW-91) I1-Chloroeicosafluoro-3-oxaundecane-I-sulfonic acid (I IC1-PF) 763051-92-9 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND 9-Chlorohexadecafluoro-3-oxanonane-l-sulfonic acid (90-MONS) 756426-58-1 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND 4,8-Dioxa-3H-perfluorononanoic acid (ADONA) 919005-14-4 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND 1H,1H,2H,2H-Perfluorodecane Sulfonate (8:2FTS) 39108-34-4 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND 1H,1H,2H,2H-Perfluorohexane Sulfonate (4:2) 757124-72-4 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND 1H,1H,2H,2H-Perfluorooctane Sulfonate (6:2 FTS) 27619-97-2 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND 2H,2H,3H,3H-Perfluorooctanoic acid (5:3FTCA) 914637-49-3 ng/L 1633 Var NE NE NE NE ND ND ND ND 81.2 J 363 ND ND ND ND Hexafluoropropylene oxide dimer acid (HFPO-DA) 13252-13-6 ng/L 1633 Var NE NE 10 NE ND ND ND ND ND ND ND ND ND ND N-ethyl perfluorooctanesulfonamide (NEtFOSA) 4151-50-2 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND N-ethyl perfluorooctanesulfonamido acetic acid (NEtFOSAA) 2991-50-6 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND N-ethyl perfluorooctanesulfonamidoethanol (NETOSE) 1691-99-2 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND N-methyl perfluorooctanesulfonamide (NMeFOSA) 31506-32-8 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND N-methyl perfluorooctanesulfonamido acetic acid (NMeFOSAA) 2355-31-9 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND N-methyl perfluorooctanesulfonamidoethanol (NMeFOSE) 24448-09-7 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND Nonafluoro-3,6-dioxaheptanoic acid (NFDHA) 151772-58-6 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND Perfluoro(2-ethoxyethane)sulfonic acid (PFEESA) 113507-82-7 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND Perfluoro-3-methoxypropanoic acid (PFMPA) 377-73-1 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND Perfluoro-4-methoxybutanoic acid (PFMBA) 863090-89-5 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND Perfluorobutanesulfonic acid (PFBS) 375-73-5 ng/L 1633 Var NE 2,000 NE 6,000 0.59 J 7.2 J 1.1 ND 9.8 J 31.6 1.5 ND ND ND Perfluorobutanoic Acid (PFBA) 375-22-4 ng/L 1633 Var NE NE NE NE 1.2 J 15.7 J 3.3 J ND 11.3 J 37.1 J ND ND ND ND Perfluorodecane Sulfonic Acid (PFDS) 335-77-3 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND Perfluorodecanoic acid (PFDA) 335-76-2 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND Perfluorododecanesulfonic acid (PFDoS) 79780-39-5 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND Perfluorododecanoic acid (PFDoA) 307-55-1 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND Perfluoroheptane Sulfonate (PFHpS) 375-92-8 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND Perfluoroheptanoic acid (PFHpA) 375-85-9 ng/L 1633 Var NE NE NE NE 0.35 J 20.2 1.8 ND 15.5 59.5 0.64 J ND ND ND 3-Perfluoroheptyl propanoic acid (7:3FTCA) 812-70-4 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND Perfluorohexanesulfonic acid (PFHxS) 355-46-4 ng/L 1633 Var NE NE 10 390 ND 13.2 1.3 ND 18.2 122 2.0 ND ND ND Perfluorohexanoic acid (PFHxA) 307-24-4 ng/L 1633 Var NE NE NE NE 2.1 37.6 5.3 ND 33.2 212 0.48 J ND ND 0.24 J Perfluorononanesulfonic Acid (PFNS) 68259-12-1 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND Perfluorononanoic acid (PFNA) 375-95-1 ng/L 1633 Var NE NE 10 59 ND ND 0.39 J ND ND ND ND ND ND ND Perfluorooctane Sulfonamide (PFOSA) 754-91-6 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND Perfluorooctanesulfonic acid (PFOS) 1763-23-1 ng/L 1633 Var 0.020 NE 4 40 ND ND 2.3 ND ND 13.4 0.29 J ND ND ND Perfluorooctanoic acid (PFOA) 335-67-1 ng/L 1633 Var 0.004 NE 4 60 0.46 J 24.0 4.3 ND 34.7 101 2.2 ND ND ND Perfluoropentanesulfonic Acid (PFPeS) 2706-91-4 ng/L 1633 Var NE NE NE NE ND 6.0 J 0.35 J ND 6.5 J 26.9 0.84 J ND ND ND Perfluoropentanoic Acid (PFPeA) 2706-90-3 ng/L 1633 Var NE NE NE NE 1.3 J 27.5 4.7 ND 15.0 J 64.4 0.38 J ND ND ND 3-Perfluoropropyl propanoic acid (3:3FTCA) 356-02-5 ng/L 1633 Var NE NE NE NE ND ND ND ND ND 33.4 J ND ND ND ND Perfluorotetradecanoic acid (PFTA) 376-06-7 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND Perfluorotridecanoic Acid (PFTriA) 72629-94-8 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND Perfluorododecanoic Acid (PFUnA) 2058-94-8 ng/L 1633 Var NE NE NE NE ND ND ND ND ND ND ND ND ND ND Hazard Index PFAS (PFNA, HFPO-DA, PFHxS, and PFBS) - unitless - - NE NE 1.0 NE 0 1 0 0 2 12 0 0 0 0 Notes: 1. NE = Not Established; EPA has not established an HA, Interim HA, RSL, or MCL 2. LOQ = Laboratory Limit of Quantitation 3. BG = Background 4. HA = Lifetime Health Advisory as established by the US EPA 5. Final and Interim HA established in US EPA Drinking Water Health Advisories for PFAS Fact Sheet for Communities dated August 2023 6. RSL = Regional Screening Level as established in US EPA Regional Screening Level Summary Table dated August 2023 7. Shaded cells indicate exceedance of Final HAs 8. Shaded cells indicate exceedances of Interim HAs 9. Shaded cells indicate exceedances of RSLs 10. Hazard Index MCL calculation from PFAS National Primary Drinking Water Regulation document dated April 10, 2024 11. Shaded cells indicate exceedances of MCLs 12. FB = Field Blank 13. NT = Not Tested 14. ND = Not Detected 15. Var=Various 20955-02 PFAS Tables T7 PFAS GW Prepared by: TCG Checked by: RLB Table 8 Summary of Per- and Polyfluoroalkyl Substances (PFAS) in Surface Water Rutherford County South Landfill Rutherford Co., North Carolina Permit No. 8102-MSWLF-1977 BLE Project Number J24-20995-02 Sampled by Pace Analytical Services, LLC April 19, 2024 TEST CAS Number UNITS Method Analytical LOQ HA Interim Final HA MCL RSL SW-1 SW-2 11 -Chloroeicosafluoro-3 -oxaundecane- I -sulfonic acid (11C1-PF) 763051-92-9 ng/L 1633 Var NE NE NE NE ND ND 9-Chlorohexadecafluoro-3-oxanonane-l-sulfonic acid (90-PBONS) 756426-58-1 ng/L 1633 Var NE NE NE NE ND ND 4,8-Dioxa-3H-perfluorononanoic acid (ADONA) 919005-14-4 ng/L 1633 Var NE NE NE NE ND ND 1H,1H,2H,2H-Perfluorodecane Sulfonate (8:2FTS) 39108-34-4 ng/L 1633 Var NE NE NE NE ND ND 1H,1H,2H,2H-Perfluorohexane Sulfonate (4:2) 757124-72-4 ng/L 1633 Var NE NE NE NE ND ND IH,IH,2H,2H-Perfluorooctane Sulfonate (6:2 FTS) 27619-97-2 ng/L 1633 Var NE NE NE NE ND ND 2H,2H,3H,3H-Perfluorooctanoic acid (5:3FTCA) 914637-49-3 ng/L 1633 Var NE NE NE NE ND ND Hexafluoropropylene oxide dimer acid (HFPO-DA) 13252-13-6 ng/L 1633 Var NE NE 10 NE ND ND N-ethyl perfluorooctanesulfonamide (NETOSA) 4151-50-2 ng/L 1633 Var NE NE NE NE ND ND N-ethyl perfluorooctanesulfonamido acetic acid (NEtFOSAA) 2991-50-6 ng/L 1633 Var NE NE NE NE ND ND N-ethyl perfluorooctanesulfonamidoethanol (NEWOSE) 1691-99-2 ng/L 1633 Var NE NE NE NE ND ND N-methyl perfluorooctanesulfonamide (NMeFOSA) 31506-32-8 ng/L 1633 Var NE NE NE NE ND ND N-methyl perfluorooctanesulfonamido acetic acid (NMeFOSAA) 2355-31-9 ng/L 1633 Var NE NE NE NE ND ND N-methyl perfluorooctanesulfonamidoethanol (NMeFOSE) 24448-09-7 ng/L 1633 Var NE NE NE NE ND ND Nonafluoro-3,6-dioxaheptanoic acid (NFDHA) 151772-58-6 ng/L 1633 Var NE NE NE NE ND ND Perfluoro(2-ethoxyethane)sulfonic acid (PFEESA) 113507-82-7 ng/L 1633 Var NE NE NE NE ND ND Perfluoro-3-methoxypropanoic acid (PFMPA) 377-73-1 ng/L 1633 Var NE NE NE NE ND ND Perfluoro-4-methoxybutanoic acid (PFMBA) 863090-89-5 ng/L 1633 Var NE NE NE NE ND ND Perfluorobutanesulfonic acid (PFBS) 375-73-5 ng/L 1633 Var NE 2,000 NE ,000 1.0 J 1.3 Perfluorobutanoic Acid (PFBA) 375-22-4 ng/L 1633 Var NE NE NE NE 0.99 J 1.6 J Perfluorodecane Sulfonic Acid (PFDS) 335-77-3 ng/L 1633 Var NE NE NE NE ND ND Perfluorodecanoic acid (PFDA) 335-76-2 ng/L 1633 Var NE NE NE NE ND ND Perfluorododecanesulfonic acid (PFDoS) 79780-39-5 ng/L 1633 Var NE NE NE NE ND ND Perfluorododecanoic acid (PFDoA) 307-55-1 ng/L 1633 Var NE NE NE NE ND ND Perfluoroheptane Sulfonate (PFHpS) 375-92-8 ng/L 1633 Var NE NE NE NE ND ND Perfluoroheptanoic acid (PFHpA) 375-85-9 ng/L 1633 Var NE NE NE NE ND 1.1 J 3-Perfluoroheptyl propanoic acid (7:3FTCA) 812-70-4 ng/L 1633 Var NE NE NE NE ND ND Perfluorohexanesulfonic acid (PFHxS) 355-46-4 ng/L 1633 Var NE NE 10 390 0.90 J 1.3 Perfluorohexanoic acid (PFHxA) 307-24-4 ng/L 1633 Var NE NE NE NE 0.78 J 2.4 Perfluorononanesulfonic Acid (PFNS) 68259-12-1 ng/L 1633 Var NE NE NE NE ND ND Perfluorononanoic acid (PFNA) 375-95-1 ng/L 1633 Var NE NE 10 59 ND ND Perfluorooctane Sulfonamide (PFOSA) 754-91-6 ng/L 1633 Var NE NE NE NE 0.71 J ND Perfluorooctanesulfonic acid (PFOS) 1763-23-1 ng/L 1633 Var 0.020 NE 4 40 1.6 1.1 J Perfluorooctanoic acid (PFOA) 335-67-1 ng/L 1633 Var 0.004 NE 4 60 0.61 J 3.2 Perfluoropentanesulfonic Acid (PFPeS) 2706-91-4 ng/L 1633 Var NE NE NE NE ND 0.41 J Perfluoropentanoic Acid (PFPeA) 2706-90-3 ng/L 1633 Var NE NE NE NE 0.50 J 1.5 J 3-Perfluoropropyl propanoic acid (3:3FTCA) 356-02-5 ng/L 1633 Var NE NE NE NE ND ND Perfluorotetradecanoic acid (PFTA) 376-06-7 ng/L 1633 Var NE NE NE NE ND ND Perfluorotridecanoic Acid (PFTriA) 72629-94-8 ng/L 1633 Var NE NE NE NE ND ND Perfluoroundecanoic Acid (PFUnA) 2058-94-8 ng/L 1633 Var NE NE NE NE ND ND Hazard Index PFAS (PFNA, HFPO-DA, PFHxS, and PFBS) unitless NE NE 1.0 NE 0 0 Notes: 1. NE = Not Established; EPA has not established an HA, Interim HA, RSL, or MCL 2. LOQ = Laboratory Limit of Quantitation 3. BG = Background 4. HA = Lifetime Health Advisory as established by the US EPA 5. Final and Interim HA established in US EPA Drinking Water Health Advisories for PFAS Fact Sheet for Communities dated August 2023 6. RSL = Regional Screening Level as established in US EPA Regional Screening Level Summary Table dated August 2023 7. Shaded cells indicate exceedance of Final HAs 8. Shaded cells indicate exceedances of Interim HAs 9. Shaded cells indicate exceedances of RSLs 1 10. Hazard Index MCL calculation from PFAS National Primary Drinking Water Regulation document dated April 10, 2024 11. Shaded cells indicate exceedances of MCLs 12. FB = Field Blank 13. NT = Not Tested 14. ND = Not Detected 15. Var=Various 20955-02 PFAS Tables Prepared by: TCG T8 PFAS SW Checked by: RLB FIGURES ARM DR to n HAMRICK RD s m Jay o- g 'b - p 10dR9 r 1 Po VIVIAN� — O Twin Airpark 0 0v FF a 0 zm M/CC S AV f 1 Op 900 y a 0 KELLY RD _ Cary Teen DOGWOOD Ow0p0 VALCE�i OpFRT COOPERL/NE R� a ck: W m \ W 2 0 Caroleen �� u y o h 0 �o i Avondale 1 FLp�F a o Henrietta_Cem �q� Q MCDOWELL Sr AVO E.LANOF�C I 4 R 18� _ Avondale moo \ •80.0� �� p CHORCH ST .:, 800 f OL Providence y— _ `r00 ted Me—thodist 0? 4 r,❑c�h Graveyard - �q�oQ �\S� PaS A q, a cm m _ IL dpO A RAG -TOWN RD Zion HM Cem y 800 J� o P /800 J / 13ellrletta �P� �H{tRAY ST l DOC ' _ MANkD HENRIETTA RD HARRIS REFERENCES: _Ilk �D - USGS TOPOGRAPHIC MAP, 7.5 2000 1000 0 2000 4000 �0 MINUTE SERIES, FOREST CITY. NC. - QUADRANGLE 2022 APPROXIMATE SCALE IN FEET CAKERD DRAWN: DATE: FIGURE KLW 6-26-24 is IM IM BUNNELL SITE LOCATION MAP M LAMM13NS RUTHERFORD COUNTY SOUTH LANDFILL CHECKED:RLB CAD: RUTHERFORDSOUTH-02SLM M ENGINEERING RUTHERFORD, NORTH CAROLINA 6004 Ponders Court, Greenville, SC 29615 APPROVEDAWA JOB NO: J24-20955-02 Phone: (864) 288-1265 Fax: (864) 288-4430 V_ :''r A 1166 Iimi'm A� , L_ i�• r Ar L Ali% SW-1 F - O MW-9D , MW-9S 758.65 757.72 r T i M W- 8 � 2.16 MW-5 78 754.42 C CA R MW-1 ti 781.60 f -.Ogg, oil I J F: MW-4A r7p r' 822.74 y j 73 pig MW-2A r ti 4 * IF VM6 M W-6 774.89 M W- 7 - L - • - ' - - 7 MW-3 769.24 ,c�� - ;., , A w - i •'Y', � l � L. l 1' kL , AVONDALE LANDFILL ROAD REVISIONS No. DESCRIPTION BY DRAWN: KLW CHECKED: TCG/RLB APPROVED: AWA M t 406 or R DATE: 6-17-24 CAD FII_E:RUTHERFORDSOUTH-02PROD JOB NO: J24-20955-02 r L� J y., r . • F �f �; I- ,� G L, t- 16 . � • , y y�j,Lr , Y z L •+ SECOND BROAD RIVER r 'I 'ILL La IM JBILINNELL LAMM � AMMONS ENGINEERING 6004 Ponders Court, Greenville, SC 29615 Phone; (864) 288-1265 Fox; (864) 288-4430 t W. ;As �k MONITORING LOCATION LEGEND MW-8 APPROXIMATE GROUNDWATER MONITORING WELL LOCATION SW-1 APPROXIMATE SURFACE WATER SAMPLE LOCATION TOPOGRAPHIC & GEOLOGIC LEGEND L 790 POTENTIOMETRIC SURFACE CONTOUR LINE (CI = 10') GROUNDWATER FLOW DIRECTION ` SURFACE WATER APPROXIMATE PARCEL BOUNDARY IL NOTES: SAMPLE LOCATIONS ARE APPROXIMATE AND LIMITED BY THE REFERENCES THEMSELVES GENERAL MAP REFERENCE ■ - I ,Y A y 150 75 0 150 300 ,.• APPROXIMATE SCALE IN FEET • '''� .r? .� i' J 1 y• - REFERENCES: 1. PROPERTY LINES SHOWN OBTAINED FROM RUTHERFORD COUNTY GIS. 2. GROUNDWATER MONITORING WELL AND SURFACE WATER LOCATIONS FROM r:{ FIGURE 2 — SITE MAP WITH CONTOURS, JUNE 15-2023. PREPARED BY SCARLETT GEOPHYSICAL CONSULTING, PC. LOCATIONS ARE APPROXIMATE. GROUNDWATER ELEVATION CONTOUR MAP - APRIL 19, 2024 RUTHERFORD COUNTY SOUTH LANDFILL RUTHERFORD COUNTY, NORTH CAROLINA FIGURE NO. 2 APPENDIX A FIELD SAMPLING LOGS PACE ANALYTICAL SERVICES, LLC. :Document Name: Field data Sheet Date Issued: March &, 2019 Page: I of I ceAo1)4lcd1 Document Number. F-CAR-FI.D-001-rev.0.3 issuing Authority: ©mHuntersvilteQuaI4 Field Data Sheet Client: Z = Locatio=TF%,-esd- C-4-v. C Project #: %d+tV LrA C.,SowA 4 r ap.'2ocy Name and Affiliation (Sampler(a): Field Data Sheet Review: S P Name and Affiliation (inspector): _ Date: 14 / -. S / Z14 By: Well Information' ` Ll I3o M 6,l. Well ID: - 910 L ` MW ^ Well Locked; / NO / Flushmount ) Well Diameter: �2_ Construction: Steel/Stainless Steel) Total Well Depth: 37.Sg ft Multi Factor*.* •-M ['(Radius/42)2x3.I4 x 7.481 Static Water Level; 30.2x ft Casing Volume: I. 19 gallons ' Height of Water Column: 7.-S 0 ft Cal.3 Volumes: 3.S 6 gallons Pump Intake: SS ft Purge Information Date Purged:` _/_LA_/ 0-1 Start: 11" Finish_ (13S Purge Rate: IN 11 :1 Purging Method: 'Msv)5gon Total Volume Purged: 1500 (gallons/<V/L) - Sampling Information Date Collected. 'I _/ 19 / Time Collected:: t t y is (m /pm) Sampling Equipment Used: MonSao n Instrument ID: YS j_021\' 's^ I� G 12_ Bottle Type Preservation Analysis Required 0_^ SOO «,\ f 1 r 125.41 �IreS to �-� TLAs t S. eft ".FS 1 �.So .,\ �\ las8 �c H1JO3 bow/7y�o -RGRA M��o\s Y3„$o_3V;,\ /3g 40.,\ Vty\ HU /MCL &Lot fti SILK jg,1w D t+.w Field Measurements/Observations Sample Temp (eC): ZZ.°I Time: 1144 ___Turbidity(ntu): 1,•'� Time: 1%4% Diss Oxy (mg/L): 0 1 Time: Fe 2+mg/L: Time: Specific Cond. (uS): t i K . S Time: Res. Cl (iiig/L)/(Icg/L): 'rime: Sample pfT (s.u.): S .2 _ Time: Odor: _,. WN Time: 114O ReDox(mV): .. 124-1 Time: tp -Appearance: c6,rW41APF Time: •,- ReDox (EfI value):XST ProPlus.+2OOmV 3,Z4.1 Other: Time: General/WeatherObservations: G \n.a.cIt 62Z unny/cloud (rainy) Temp.-M ff) WindO-S (mph) Sampler Signature: Q,_\A Date: , LA A 0, mA Stabilization Test Time Purged : Temp. (Co ) I Diss Oxy. (rng(L) Spec. Conti and. (u5) pH (s.u:) ReDox (mV) Turbidity (ntu) Volume removed (gaiTotvs;<�t ( L Water level (ft) Other Im's 2.23 O. 41.1,- CL'' lvk. 6. S00 3oa8 11 22. q 0.3 4x. S.2 10 4. 5 �.. I'ZI 1135-- 2 0.3 4&.b Document Name: Reid data Sheet Date Issued: March s, 2019 Page: 7 of �' dCeAn8lyfiCal IsSumg Auttwrlty: Paceliuntersvilfs Qualtty DocumenE Number, P-CAR-PLf)-0O3-cev.IXi ©ff14e Field Lh d Data Sheet Client: Location.- re �j C t F1� 4i�., Project ii: U%�L�( C L�, -SOLI - Fh �t7�� Name and Affiliation (Sampler(a): 4167r- - CA r Field Data Sheet Review: S A Name and Affiliation (Inspector): Date: w J ).Tf Zq t" Well Information 0q 130tva By. /> Well ID: `'91 a a -Ird W'ai� Weft Locked: ( E / NO / Flushmount) Well Dlame#er: a t i Construction: (U,�/Steel/Stainless Steel) Total Well Depth:�J • It Multi Factor*:b,) iP ~3 [*(Radius/12)2 x a lax y.asl Static taster Level: r_ft Casing Volume: -t gallons Height of Water Column:15.5-9 ft CaL 3 Volumes(: / - S gallons ' Pump Intake: I k/ If Puree Information Date Purged: U N d14 Start: QqQ Finishf O Purge Rate: Purging Method: the qr4, i'1 ti1 V5�Total Volume Purged: G 5C6 (gallons/Q/L) Sam lin Information Date Collected: D /L }anti Time Collected:' 33 am/Q Sampling Equipment Used: YE °�a It Onso0 � InstrumentID: `/517� o,} c)3 / TPW P� �07`q Bottle Type Preservation Analysis Required Field Measurements/Observations T SampleTemp (aC): I oTime:Turbidity (ntu): " 6' Time:Diss Oxy{mg/L): Time:Fe2+mg/L: Timer Specific Cond. (uS): ��> O Time:Res. Cl (nig/L)/(µg/L): Time:-® Sample pH (s,u.): � TimeOdox: fnI Pb kt :Time:. l � � S ReDox (mV): ''�5P Time_Appearance: �) e & Time: 1 �S ReDox (FH value):YSI ProPlus;+2QgmV I � 4, (0 Other: — — Time: General/Weather Observations: Sampler Signature: Y V%I e r `^i(N� Date: 1 1 Stabilization Test a� Volume Time Purged Temp. n { C) , Diss Oxy, (mgJL) Spec" Cond. (US) pH (s.u.) ReDox (mV)_ Turbidity (ntu)- removed (gallons/e�/ L Water level (ft) Other a �a• 3 �. wt. I ,v 3 s a, 1 -0 .1 7T,ca 1 (o, a;u Ivvv 70,tCp a a1,--) 1 0, 26. ' S. t 13 1 a . a • ia,o ca. —its. a ar,V v: a,�t � �of>7/swill c1C8AfTiilyllCl Doeuutent Name: Field Data Sheet Document Issued: March 8, 2019 Pagro2 of Dc>ruatent Number: Issueutg Authority: F-CAR-FLD-M.rev.03 Pace Huntersv lle Quality Office Client: I ✓ Location: f 0 (%S f C tic Project: f Vt P 4 c Fo3rci rrco, CJ o,t F ` a-0a,l Well ID: �i®a—�[N -A Reviewed Date and By: % 5 5�Pa Stabilization Test Oa 13,3 I tit( 5M a (Nell L?ismeter Nfultiplication Factor" 1 `- 0`.0408 1.2: OAMS 1.625 0°.10S0 2 01630 3 03670 4 0.6530 6 14680 S 26100 Time Purged Temp. (00 Diss Dxy. (mg/L) Spec. Cord. (us} pH (s.u,) ReDax (mV) Turbidity (ntu) Volume RemovedWater (gallonS(�i 9/L} circle one level (ft} Other ['�0 (o,D —)co.55 13,a 0750 3o.-ia 1310 ,1 0 31to i (0pp 4 , 10.3 3Sov 1319- DO-U O. i Sale CO-0 s' � 1 Llas0 3 0Jt 13dO 0.� 0.1 d� C�. r, e �oo� 30n �a 13a s` 0., 0, 1 330,3 , -W .9 S - $ 5 -75 133 aI1 0.9 33do1 (P. I -co'V.5 9.S G500 3f5.� Date Issued: March 8; 2019 ; Document Name: Field data Sheet Page: Iof_ I aC8AtkllytlCai' Issuing Authority: Pace Huutersville Quality Document Number. F-CAR-Pt.i}-QQl-rev.p3 Office Field Data She Client: DLL Location: 16ve � C' Name and Affiliation (Sampler(s): MEP- - P4 LP - Name and Affiliation (Inspector): NA QC Project#: p it-t3r� So v}k LF Field Data Sheet Review: s ph) Date: VT j 2T'l z k By: P. WeII Information -1 Purge Information Date Purged: t l /D 1 el / a '1 Start: I I 10 Finish, 1 1 3 0 ;Purge'Rate: Purging Method: ! r s I z• i a '� J Total Volume Purged: Z `t"U (gallons/ii s/L) Sampling Iriformation. Date Collected: '�' / Iv )-,I Time Collected; 113 5 /pm) Sampling Equipment Used: —Cc L, 544I frc- ELI ,e instrument ID: Y 1 0,)-Dcl IT NJ I S (a(o Bottle Type Preservation : Analysis Required 3xgGM'v' t by4C.at_y'c t IIGI sRd -` MSU>IM d)1d7D LowI-evet LF 1 x zSoMt. Nn)03 iof tl) TIuTU RLRA toe+ells Ix 1LSnu ( v, reS f FA5 - T'SS'Sc.-ee,, x PrAS 11e33 Field Measurements/Observations Sample Temp Cq: 4 Time: L 1 'a S Turbidity (ntu): I S Time: 113 S Diss Oxy (mg/40, Time Fe 2+ mg/L: Time: Specific Cond. uS IG T Time: Res. Clrn L It L : Cone: P ( ) ( g/ )J( gJ ). Sample pH (s.u.): =5 J_ Time: Odor:_ _ fTime: ReDox (mV): I' Time: 'V Appearance: r (-e , r rime: ReDox (EH value):XSI ProPlus:+200mV a i51' ' Other: Time: General/Weather Observations: 5 c (e z., '_lb, Qf i nAv l- loudy/rainy) Temp.FO (OF) Wind 1 (mph) Sampler Signature: / �i � Date: 4 -1`t"X4 Stabilization Testy 4 IY• xq Time Temp. Diss Oxy. Spec` Cond. pH (s.u.) ReDox Turbidity ' o vine removed Water OtherPurged, CC) (C) (mg/L,) (US) (mV)' (ntu) (�llons/�s/ level{ft} L II15 �a. L, I -I b`i 9 �;�' 95.5 2,°l C.7v v I .z t IIaO 7-4.5 U•t I G,T_7 5',3, §5'.1 1,3 1 Cc)b t v .Z IIa-5: zti.5 c),`I �7,.3 3 k3,;3' f,S f YDQ IY.ZK 13 7 24.5 C). 7, .'I T. -1 3 J - 1 3 � 1 Z O 0 I `' Lb' � DocumentN"anre: Field data ShcM Date Issued: March 8, 2019 pa e, 1 aE I /f PaceNtalyGCa!' Document Number: P-CAR-P[.D-001-rev.03 Issuing Authority: Pace Huntersville Qualiy r office Field Data Sheet NL, Client: BLE Location: Fo;-esIt-Li tom'" Project# puP"d Co. So-4k LF Name and Affiliation (Sampler(s): Mt iz -Phi LC Pfield Data Sheet Review: S p Name and Affiliation (Inspector): N Date: q C 2. T/ 2q By: P Well Information Ul/1Rj0. AtQ Well ID: 1 6' J M u " IA Well Locked: NO / Flushmourn ) Well Diameter: Construction: (VV /Steel/Stahiless Steel) Total Weil Depth: 30.3 S ft Multi Factor*: ()�63 madius/12)2014'0.481 Static Water Level: LZ' -1 ft Casing Volume: I rl gallons Height of Water Column: �• 9 3_ ft Cal. 3 Volumes: ? • k 7 gallons Pump intake: �' 2 ft Purge Information' Sa Da •gingMethod:_ �plinglnformati to Collected:_ Bottle '1/ -L4 Start : t 3 Z Z finish 1 3 H a- : Purge'Rate: n5-Vr-tht Total Volume Purged: 2H00 (gallons/6/1,) / Time Collected; I iul5__(am/0) me used: P2rt S i t - Ov,�-. ea Instrument ID: a is 1 o"20,-1 � � s Preservation Analysis Required 3 1 ka:-Lvrwt (-1tr.('. 8.XUJ)D Msu slnll.:S)LG06 L,wveve-i LP Vk f'3o 3 t201ol l `+lu (-LP-A Mz1 .lf UAJere r. ('FAS'- TSS Sate" vnF es. PFIAS 11e33 itOObservations Time: 13 ui S-Turbidity (ntu): ` t Time: 1 3 it S 1-d Time Pe 2+ mg/L: Time: Specific Cond. (u5): J11 Sample PH (s.u.): ReDox (mV): g ReDox (H value):XSI ProPlu General/Weather Observatio i Time: Res. Cl (mg/L)/(itg/L), — 'lime: m;.,, Odor: NQ T" _ _ une. , Appearance: t (2 r« rime: D8 L .-1 Other: Time: ( unit /cloudy/rainy) Temp. h) ff) Wind 3 (mph) iZ — Date: Li I l `i � )L q Spec.. Time Temp. Diss Oxy. Cond. pH (s.n;) ReDox Turbidity removed Water Other Purged n (C) (mg f Is (US) (mV) (ntu) (gallons// level (it) L L '' 2i.g H5,`1 y. '' 109..7 S' 3 ' (a pc Z2 55.ut Ll- i09,7 Si3 ', 3 •2�. u .� 311. 5 1 e. 9,1 3, i �zuv 3 3 '7 21,E I � � 3� 134), 21.3 IM 31, Volume ,3 ,� ��- 3,1 t �vv // Document Name. Field data Sheet pate IssuedrMarch 8, 2019 : Page: loft- BAtla&ical. / ' Issuing Authority: Himtersviile Quality Document Number: F-CAR-RID-001-rev.o3 Office Field Data Sheet Client PALE Location: t o,-es} C, }�1/�l Project #: Kai I^C"+On3, CO 5 ov-) 6- LF Name and Affiliation (Sampler(s): ME 2 " (Cu Field Data Sheet Review: Name and Affiliation (Inspector): fi Lt / 2 51 ( 2c(B Date: Y . Well Information AtIOL12A Well -ID: -- 11 U ;L- M W _ S Well Locked: (:E / NO /Flushmount ) Well Diameter: Construction:, (110/Steel/Stainless Steel) Total Well Depth; ft Multi Factor*:� r(Radius/ 12)2 x 3.14 x 7,48] Static Wafer Level: 1 0 `) n ft Casing Volume: S 3 gallons Height of Water Colurnn; R' y l £t Cal. 3 "Volumes:' $ l gallons Pump intake: ft Purge Information', L�"m� Date Purged. �f :! `� I / ali Start :y 1 1 O Pliiislx D 1 S 5' Purge Rate: i p PurgmgMethod: t cr. ykJfi r Pg_P Total Volume Purged: 5,1 Dc, (gallons/I /L) Sampling Information Date Collected: `9 / 19 / k Time Collected: 1 u h C+ _ Q1/pm) Sampling Equipment Used: � st ll c (av�InstrumentlD: YSF a:�vLl /Tiow i5ke Bottle Type Preservation Analysis Required 3 x p cl D r t- vial 13 x 1401"l, v,t t H 0 9,NPOD Aw V iLM 18.1006 LoW, Levz I Lj- x zsOML C, 11 LxL), (ooi0 /-)tii0 �-i.R,4.. `i K 12.S-M, L! VV% �P-A Si ":. Te-S 5': GrPPy� D it o 001.11 UAP'—rS �>nS Ile33, Field MeasurementslObservations Sample Temp (oq: I s•'i- Time: i U9—Turbidity (ntu): i, H Time: I oce Diss Oxy (mg/L): Qr Iv Time: 1 00 v Fe 2+ mg/L: — Time: Specific Cond. (uS): L103" Q Time: 1000 Res. Cl (mg/L)/(µg/L): Tuner " a i„ z J Sample pH (s.u.); h .l Time: (DaC} odor,.___1� Time: �OuD ReDox (mV); I i Time: I C) Appearance: ime: DOD ReDox (EH value):YSI ProPlus+200mV I `1 I Other: Time: General/Weather Observations: (sunny/cod /rainy) Temp 7D ('F) Wind N& (mph) Sampler Signature /✓ �i -?_., Date: 9 ' i 9 - 14 Stabilization Test G' Time Temp. Diss Oxy. Spec' Cont. pH (s.u:) ReDox Turbidity Volume removed Water Other Purged, (,C) (tng/L) (rnV) (ntu) {gattons/ rl / level (£f) , (US) L) fAP 441. aY p f5 ` IS•c t ' `iCl5 G-1 CT - 12 ,a Cvfiv Iao1 DvP Ise I, — c107.5 (P- I 17 V I 25.0 1 t)9'I37 Is. i, t yD3,tL lr. 3 to, `I 3t, S P Zoo i,o 3 09145i, Is, ! 0.$ L111olS I (a.,>- 8 y :)b,`i I Ikt70 0-03 0930: 1s:i D, I 403.`1 I U-1 i y,fr 1 DA 1 .14 DO I1.o3 clez,eil 0, Il rmz, �A�f06, rIGBAIIa%j/llCs?i Docunxenk Name: f iel&Data Sheet Oocumentlssued: Mawlf8, 2U19 Daument Number: Issueing Authority: P-CAR-Fi,D-0pl.revA3: Pace Huntersville Quality Office Client: i3LL- Location: I=va es {CA l �C - Project: RvK-crA d (it,. LF Sc �tl WellU.- 810).- MW-5 Reviewed Date and By: N)141%A k 4 Stabilization Test q<-?� 5-1 f � 1iTeD Mal meter 'Sultiplicetion Factor" 1 00403 1.2 0 0918 1.625 0.1080 2 0A630 3 '- 0.3670 4 0.6530 6 -- 14680 8 2.6100 Time Purged Temp. (°G) DissOxy. (mg/L) Spec; Cond, (US) pH.(slu.) ReDox(mV) Turbidity (ntu) Volume Re oved (gallons] jL') circle, one Waterleuel' (ft) Other 0g35 K-3L ').0 1-1019 b- - 5'• �1- Ilv.o 3�c-v It-c3 o94o 15.3 1 1,4 4l)),UI ta. 4,a Ia.Ll 3io'0c II.o3 094S t5,H O.9 403.0 fv: If: ti•ty 4 .Do It.D; 095 19to O,S3 403 3 i0. DIU it), S 4 30D I (. e3 0955 IS,5 C.-I 40) 0 c, T-1 LA DO It.C)"3 Pa e:3at tssuuig Authority: Pace Huntersville Quality %1�,,..MACCiIi?Aly1[CAI� i..... Document Number. F-CAR-FT-0al-rev.0.3 Office Document Nance: Field data Sheet Date ts9ued: March s, 2019 Feld Data Sheet / Client: j3L� Location: lv est-_( �YL NC Project#• �4t,rturl. C So rb, LF Name and Affiliation (Sampler(s): MEP CICC Field Data Sheet Review: Name and Affiliation (Inspector): N Date: ' By: Well Information Hh�lg,M k 81 D 1 M W -/o W 11 L ked f NO / Flushmount I Wen e oc Well Diameter: „ Construction: (PUG2 Steel/Stainless Steel) Total Well Depth: 3-T IL) It Multi Factor': b� r(Radius/12)2x3.i4 x 7 aeI Static Water Level: �U I K ft Casing Volume; -� (vi gallons Height of Water Column: I D. a ft Cal. 3 Volumes: S ` o I gallons ; Pump Intake: :2 3$ ft Purge Information `i 61 9 U ML/" ;" Date Purged: / , t Start: ( 21 S Finish:` 12 3 D Purge Rate: H.,q.LN 7 1 2(i ♦, ID Purging rvretno Sampling Infoi Date Collected: Sampling Equil Bottle T e:, ate 11,c r�. {3 TotalVolumePurged: 1 (gallons s/L) ra ion )m 'rime Collected; V?'� �- (am/ ) ent Used: JET r s 6 14t • C �c " ! Instrument ID:J Sl O D tl ) Yl W I S tvte pes Preservation Analysis Required 3 x aoMv � 4t N c I K,�"JN /N %sy - tg,zlaon Luw Level LF �.:.:. uA('res, ?FA,S �-TSS.Sc-een V^rr,es, I FAS 1633 Field MeasurementalObservatiOrt Sample Temp (°C) � I Time: 12 3 S -Turbidity (ntu): I ' 3- Time: 12 3 j Diss Oxy (mg/L):. l; a- Time. Fe 2+ mg/L: Time. Specific Cond. (uS): g u I Time: Res. Cl (mg/L)/(itg/ L): = Timer Sample PH (s.u.): (P, I% Time: Odor:_. 51, Time: ReDox(mV): "al-4 Tine: Appearance: z I -e rime: ReDox (H value):YSI ProPlus:+20omV 1? b Other: Time: General/Weather Observations: (srtpy/cloudy/rainy) Temp. 7-t (°F) Wind L3 (mph) Sampler Signature: ''� Date: k l l �t lay Stabilization Test' r� Time Purged TempDiss n ' (C) Ox y' (mg/L) Spec. Cond. (US) pH (s-r.) ReDox (rnV) Turbidity y (ritu) Volume removed (gallons/ �t) / _L Water level (ft) Other laav �1-U 1•�I' $(v 4 13.E f t100 27,30 fa,15 .4 t, 7i7 a. -19 `( t`0 90O -21L1p .,� CCAl7t7/yiiCal' Document Nnnm: Nietd data Sheet Date Issued: Marth &, 2019 Page: I of f DckumentNumber: F-CAR-F[SS-001-rev.OS Issuing Authority: Pace liuntersville Qualtty DffiCe Field Data Sheet Client:(= Location: roject#:i iAaA,.4C._�o�.i4 LF Ap�2�1y Name and Affiliation (Samplef(s): k W �Field Data Sheet Review: Name and Affiliation (Inspector): pYl ��d 26 /ali Weill Information Date: B Oq j 3 u 0 Lq y Qht S- WellID:- Kkcje_'LANA-1 Well Locked: /NO/Flushmount) Well Diameter: '1- ,, n Construction: kj�Steel/Stalnless Steel) Total Well Depth: 30 3 G ft Multi Factor*:0 , VI ia(Radius(12)2 x s 14x 7 as1 Static Water Level:1'33S - It Casing Volume: 2 •^7 (a gallons Height of Water Column: 6 A & ft Cal. 3 Volumes: i{ . 2 gallons Pump Intake: IL`, ft Purge Information Date Purged:/ l9 t A Start; 131 U Finishc `1325 Purge Rate: 1 `40 Purging Method:2�\Satre (r Total Volume Purged: iSdo (gallons/L) - Sampling Information Date Collected: 4 J t� 2� Time Collected;: I'S} % __ (am/(D Sampling Equipment Used: t ; a a�� e Instrument ID: 7S j O 9 A\ 'K3�� (112L Bottle Type Preservation Analysis Required 2nSoo 1 � I it I0.5n\ ?'FM. W-) / ?.r CAS 1 2So..1\_ Nlb bolo1-14to • Rou Me},\s 3 40 3 4o VkL1. rZbaA a sa slt+ 1Ya6ot� �+.s� La,lw.\ Field Measurements/Observations Sample Temp (C): 20.2 Time:, i33O __Turbidity (ntu): Time: 3i6 Piss Oxy,(mg/L): Time: Fe 2+ mg/L: Time: Specific Cond. (uS) 35 • L Timer Res. Cl�— Sample pH (s.u.): �S . \ Time: Odor:______ Time:' 133O ReDox (mV): \ 7 L .S Time: Appearance: dxe ry-( ;at, F me; i ReDox (CH value):YSI ProPlus +2(IpmV 312. S Other: Time; �— General/Weather Observations: /cloudy/rainy) Temp. go _(°F) Wind (mph) Sampler Signature. Date: Stabilization Test Spec. Volume Time Temp. Diss Oxy. Cond. pH (s.u.) ReDox Turbidity removed Water Other Purged; (C) (mg/1) (uS), (mv) (ntu) (gallons//4M/ level (ft) U 1315 ' 20.0, 01 12, I Soo- 13)5 20. 5.1 35.0 S. 611 111 S.00 11.35 l32 :2.6.6 35.E 6q. ll. loon I Document Name: Field dateSheet Date Issued. Mardi 8, 2019 or .RCeFl+uliyllCal a Page: 1 of a. T)ocunsnt Number., F-CAR-rLl?-OD't-rev.Q3 Issuing Authority,: Pace HuntersvilleQuality .-- Office Field Data Sheet Client: = _Locatiomy'k rend G ; Project #.'R,.&%_A_.a, co S-m LT - Name and Affiliation (Sampler(s): %\TW Field Data She t R{view: Name and Affiliation (lnspeetor): /z� l 2� Date, By: Well Information 0(4/ 3 b -Lc( �^I Well ID: " 8 I o I-' [�W Well Lacked: J NO J Ftushmount ) Well Diameter: 7. %, n Construction: jj!B�/Steel/Stainless Steel) Total Well Depth, "I=30 ft MultiPactor`-.0•_M r(Radius/12)20Nx7.481 Static Water Level 34 • 91 ft Casing Volume: I A• gallons Height of Water ft Cal.3volumes: 5•52 gallons Pump Intake: %9, ft Forge- Information Date Purged: l� /IR J,2y_Start:0°14G Finisk.1144t Purge Rate: i5ant Purging Method: Mon oo Total Volume Purged: 600a (gallons/ l L) Sam li Infortnation p n& Date Collected. q /JU 24 Time Collected: IoyS mvpm) Sampling Equipment Used: %5Ao pon InstrumentID:7SI 09-1\ Bettie Type Preservation Analysis Required tlxSo�i.,./Ix I�n� �1rsi•c � R 33�,�33�A�-t-F� lx2.Sa++�1 i?ksi•.c �f 1J63� 6G1oJ74,c- cRR Me�C,�T HLL LL Vzt,ob t+a� l;,1K fg1xj3i tnsv l ou Lcvk\ Field MeasurementWObservations Sample Temp (aC) l K . \ Time: 1 O Ll S 'rurbidity (ntu): 7. t rime: t o4S Diss Oxy (mg/L): a .O Timer Fe 2+ mg/L: Tilne: Specific Cond. (uS): 36.$ Time: Res. Cl (mg/L)/(µg/L): — Timer. Sample pH (a.rt.): Time: Odor: �� Tune: t a4s ReDox(mV): IOS.l Thne: Appearance:s\.� ,1% Tfime: �- ReDox (EH value):YSI ProPlus +200mV 3- S Other: Time: General/Weather Observations. ` coud rainy) Temp.%Cl (OF) Windd-S (mph) Sampler Signature: . ' Date: \A I1,\ to Stabilization Test Volume Time Temp. Diss Oxy: Spec' Cond.; PH (s.u.) ReDox Turbidity removed Water Outer Purged a (C) (mgJL) (u5) (mv) (ntu) (gallons/ t�ii7�J level (ft) L' OyNS li. 4.C3 LA -74,j 's. 1 5oc> '30.11 17.E 1.1 6 4'- ? .� 36.6 Soo 30`. -7 6 6z.5 I o0 ioo i 2 ,z 3T.y S: 2.6 2S. 2Soo to Is _, iQ.\ 1A —U-1 5.0 Document Name: Document Issued: March 8,2019 �.. aceArk7lyticsll` Field Data Sheet PageUf Z DocunrentNuniher: issueingAuthority: F-CAR FL:D-001.rev.03 Pace Huntersville Quality Office - Client: 3L Location:�o�ezi- Project. Well ID: o"r�+ 41w1,.y nri6_IzIG`-_WNI 4 Reviewed Date and By: t4 G 2, � 'p �(N Stabilization Test �)N13u�t�( LS ttreU Diameter 'Multiplication Factor* 1 0.0408 1.2 0.0918 1-625 01080 2 3 OA630 0.3670 4 0.6530 6 14680 8 2,6100 Nis Turbidity ®®®®®®®®®® Local! or f Document game: Field data Sheet - Date Issued: March &, 2019 BMA CRI `I page" 1 of! rkxument Number: F-CAR-FLD-001,rev.03 wing Authority: Pace Huntersville Quality Offtre Client: rrLl_ filiation (Sampler(s): jJyt' S Pleld Data Sheet Review: W S� filiation (Inspeetor}:^�` Well Information: Date: OW3011i,1 By. ref Well ID: &A- KV 15 Well Locked: YE / NO % Flushmount ) Well Diameter: 2' Construction: (PVC/Steel/Stainless Steel) Total Well Depth: Z` 1, rJ ft Multi Factor*: (J t 7 (+(Radius/12)2 x 3.ta x 7 as1 Static Water Level:----V-.-I-J ft Casing Volume: c&Q gallons Height of Water Column:' S . (9`C ft Cal. 3 Volumes: 4,0 gallons Pump Intake: 221. t2i4 N ft Pure Information Date Purged: /-tq—./ 2 4 Start: 1,02-5 Finish:_ 4 Purge Rate:_ ` p i M t`Jj gMethod: fefl�e�d1� Total Volume Purged: (gallons ml /L} ing Information ollected:1-1 Aq—/ 2t_ Time Collected: �0`7D �9/pm) pp ngEquipment Used: lefl�i(lZ InstrumentID: �- Bottle Type Preservation Analysis Required deasurements/Observations Temp M:- IIIW,( Time:--M��Turbidity (ntu): 3 Time: _lob(. Ky(mg/L): SA Time Fe2+mg/L: Time. Cond. (uS): ?>`(,3' Time �J-- Res. Cl (ing/L)/(ltg``/l', : Time: I Sample PH (s.u.): _� _ _ Time: Qdor:�-- I� Time: [OSO W ,N +az &A Wind 1-5 (mph) ater Time Temp. Diss Qxy: Spec. Cond. pH (s u.) ReDox Turbidity 0 ume removed . 888ArralyliGa!' Document Name: Field data Sheet Date Issued: March 6, 2019 Fa e:.1 of,] Ducument Number. F CAR -Ft TJ-001-rev.OS tssumi; Authoxity: Pace Htmtersville Quality Office I I_Field Data Sheet Client: Lev Loca//tt�ion: 4+-W Name and Affiliation (Sampler(s): iJ y-ed cR Field Data Sheet Review; Nameand Affiliation (Inspector):Dtf/'Z 1zQ ate: By: Well Information 0q130 1 -tt (in f Well ID: Z VZ' Mw' 92 Well Locked: ( / NO /Flushmount) Well Diameter: L it Construction: ep/Steel/Stainless Steel) Total el De the �97,Zy It Multi Factor*: yr (*(Radiusflz)z x3.10.x7.daj Static Water Level f6-,4. (D{ Casing Volume: gallons Height of Water Column-, It Cal, 3 Volumes: _ 0 � 3_.gallons Pump Intake: (QS,_06fl— ft Purge Information Date Purged:_Lt__/1j_./ 2N Start : 6L 35 Finish: :__J tS.5 Purge R4ter1 M�n Purging Method: 1 `'�� tC' Total Volume Purged: ' I)WO (gallons/&L) Sarnplinq Information Date Collected:_/ft_/_ +_ Time Collected: Utu _ (am/& Sampling Equipment Used: �¢hSikU(h% Instrument ID: '-f Bottle Type Preservation Analysis Required Field MeasurementslObservations Sample Temp (°C): _Turbidity (ntu): __ D _J__ Time: i w Diss Oxy (mg/L): (0.1 Time Fe 2+ mg/L Time: Specific Cond. (uS): __ Time: Res. Cl (mg/L)/(ltg/L): � Time: Sample PH (s.u.): ' �i.7. Time: Odor: Time:,. �i1f1J ReDox (znV): IU4,1 Time: Appearance Time: U-00 ReDox (EH value):YSI ProPlus+200mV 3014• 1 Other: Time: General/Weather Observations: t�oti /rainy) ampler Signature: _ _Date: `l tabilization Test /Temp. ' (°F) Wind I-S (mph) (j,q(A o uvile Time Tem p' Diss Ox ; y Spec. Cond. pH (s.u.) ReDox" Turbidtty, removed Water Other Purged ¢ (C) (mg/L) ( ) (mV) (ntu) (gallons/ 17s level (it) LP DUE t (0 J' Q4 153.8 2 t'i'� ` 17• 3$. loot. .0 2 1 � ® e Doeunient*me: Field data Sheet bite ls�auedavlarch 8,2019 C Page; e:?otaArk7MiCat ' s'ngA tlority;PaceHtt ersvili qu' tyCacumenNumbei:F-rARF.b-Qpl-rev:08 Office Natr Nair Well Well Well Tota State Field Data Sheet Lti : Location: jV0 041. h�ST?rgjeck fiHaticn7 (Sampler(s): iJiaF= Qum Pield Data SfieetReuiew:� Filiation (Inspector): 4.k l 1 Zz i Date: By: tion pal 3� 2 3 �OZ- sW - Well Locked: t) r: Construction: (P`v`eIS a sin ess feel) ptlt: it Multi Factor*: Radius/12)2 x 3.14 x7481 e 1: £t Casing Volume gallons er Column; ft Cal. 3 Volume • gallons Pump Int e: ft ation - �—Start: Finish' Purge Rate: od: Total Volume Purged: (gallons/mis/L) ormation Time Collected;. U-40 ?_ (am/� �i ipmentUsed: G- InstrumentID: q5-y�`�1/ll �ii VXY-) Type Preservation Analysis Required unents/Observations r (aC}: q Z Time:;.__�_y. �o__.__Turbfdfy. (ntu): . `�' Time: UAO IL): •� Time Fe 2+ mg/L: Time: (us): %$. Time: Res. Cl (mg/L)J(µ L� line: Time: Odor: Tune:, iZ4o ��$• Time:- Appearance:CicT.td riiu,lue: I1�10 1ue):YSI ProPlus +200mV 3 9S.- other: Time lierObservations: (4W POAAW42'u�gvte M. (ptus M wO u,�/pugJ UQ--K rm /el y/rainy) Temp.(°F) Windj:5 (mph) :ture:' Date: y`t/l-`-{ Test` Volume en11r. Diss Qxy. Spec.:. ReIIox Turbidity removed Water Time Purged Temp. (C} (rng/L), Cond. (US) pH (s.u.) (mv) ' Oita) (gallons/mis/ L level (ft) Other l . L (.e•3 'Ig.o (4•S l� . ''t9. or .0Page: p,xument Name: Field data Sheet Bate Issued: March k 2Enq I of _p .?C81Lk11yt1C:11- Document Number: F-CAR-Fl.n-0Q3-rev.o3 Issuing Authority: Pace Htmteraville Quality Olt ice Field Data Sheet p Client: ''BUL Location: ;b vi S l L N [ Project #: < tv l (�. S H Lr Name and Affiliation (Sampler(s): ME12 Field Data Sheet Review: V � Name and Affiliation (Inspector): N 4 / 2 � 12 °f Date: By: Well Information 'illitll,XtA 1 rf l Well ID: !R I D x - St.., ) WeH-1 ec*ed:.---(-4 S-/-N@ fFlushmount ) Well Diameter: C ee to n ess eel) Total Well Depth: it - Multi Factor`: ("(Radius/12)2 x 3.14-x 7.481 Static Water Level: ft Casing Volume: gallons Height of Water Column: J ft Cal. 3 Volumes: gallons ' Pump Intake: ft Purge n aEie Date Purged; // Star Purge Rate: PurgingMelhod: Total VlumeoPurged: allons/m1s/L) Sampling Information Date Collected: "I /1 tl/ 114 Time Collected; 0)'D-, a&/pnr) Sampling Equipment Used: 6ra6 Instrument ID: ys( Oat)LI I-rF-j &,PU Bottle Type Preservation Analysis Required 3 x `1oe-t.v c.t %3 x Llo-. t, yic,I Low Leve t LF r K zsa: e r FIf-�O1, „6_1o1-7NID r2cP-A MeLs 1 K t2�me f' Vn(lI'eS. PF✓iS --Fi,( SL✓e2. x Soa�M� v,Ierey, F�+SI1,33 '- Field Measurements/Observations Sample Temp (°C): 0 Time: I 0_0 T Turbidity (ntu): '3 Time: I DJ-0 Diss Oxy(mg/L), (o'. `t Time: 1 D 3 O -' Fe 2+ mg/L: Tune: Specific Cond. (uS) 'i 3. 1 Time: 0 ' -O Res. CI (mg/L)/(ltg/L): — Time: — Sample pH (s.u.): L'-S Time: r \3,1.17 ReDox (mV): 31• k Tune: �L0 Appearance: 1 e - r. Time: I 0 LC ReDox (E H value):XSI ProPlus +200mV J--5 `I Other: Time: General/Weather Observations: 6 PS ` 3 Ci ° i lF t Il . o ci " N, 81 fs ' (v. Ll ti 7 "L (sunny/ ou Y/rainy) Tempj -�- (OF) Wind 3 (mph) Sampler Signature: / '�' t --Date: `i I t el I '- ct Stabilization Test Spec. o ume Time mp. Temp. Diss Oxy: on on Cond. pH (s.u.) ReDox Turbidity removed Water Other Purged C) (mg/L) (usL, (mV) (ntu) (gallons/cols/ level (ft) t )F 17.® ( `1 ?3,1 (o.S 37.11 7,a- APPENDIX B LABORATORY ANALYTICAL DATA - PACE ANALYTICAL SERVICES, LLC. ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 May 06, 2024 James Kilgo Rutherford County Solid Waste PO Box 1957 Rutherfordton, NC 28139 RE: Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Dear James Kilgo: Enclosed are the analytical results for sample(s) received by the laboratory on April 19, 2024. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace National - Mt. Juliet • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Mr. Andy Alexander, Bunnell-Lammons Engineering Riley Blais, BLE Corp Accounts Payable, Rutherford County Landfill Director REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 53 Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Pace Analytical Services National 12065 Lebanon Road, Mt. Juliet, TN 37122 Alabama Certification #: 40660 Alaska Certification 17-026 Arizona Certification #: AZ0612 Arkansas Certification #: 88-0469 California Certification #: 2932 Canada Certification #: 1461.01 Colorado Certification #: TN00003 Connecticut Certification #: PH-0197 DOD Certification: #1461.01 EPA# TN00003 Florida Certification #: E87487 Georgia DW Certification #: 923 Georgia Certification: NELAP Idaho Certification #: TN00003 Illinois Certification #: 200008 Indiana Certification #: C-TN-01 Iowa Certification #: 364 Kansas Certification #: E-10277 Kentucky UST Certification #: 16 Kentucky Certification #: 90010 Louisiana Certification #: A130792 Louisiana DW Certification #: LA180010 Maine Certification #: TN0002 Maryland Certification #: 324 Massachusetts Certification #: M-TNO03 Michigan Certification #: 9958 Minnesota Certification #: 047-999-395 Mississippi Certification #: TN00003 Missouri Certification #: 340 Montana Certification M CERT0086 Nebraska Certification #: NE-OS-15-05 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 CERTIFICATIONS Nevada Certification #: TN-03-2002-34 New Hampshire Certification #: 2975 New Jersey Certification #: TNO02 New Mexico DW Certification New York Certification #: 11742 North Carolina Aquatic Toxicity Certification #: 41 North Carolina Drinking Water Certification #: 21704 North Carolina Environmental Certificate #: 375 North Dakota Certification #: R-140 Ohio VAP Certification #: CL0069 Oklahoma Certification #: 9915 Oregon Certification #: TN200002 Pennsylvania Certification #: 68-02979 Rhode Island Certification #: LA000356 South Carolina Certification #: 84004 South Dakota Certification Tennessee DW/Chem/Micro Certification #: 2006 Texas Certification #: T 104704245-17-14 Texas Mold Certification #: LAB0152 USDA Soil Permit #: P330-15-00234 Utah Certification #: TN00003 Vermont Dept. of Health: ID# VT-2006 Virginia Certification #: VT2006 Virginia Certification #: 460132 Washington Certification #: C847 West Virginia Certification #: 233 Wisconsin Certification #: 998093910 Wyoming UST Certification #: via A21-A 2926.01 A21-A-ISO 17025 Certification #: 1461.01 A21-A-ISO 17025 Certification #: 1461.02 AIHA-LAP/LLC EMLAP Certification #:100789 South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE SUMMARY Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Lab ID Sample ID Matrix Date Collected Date Received 92726233001 8102-MW-4A Water 04/19/2413:45 04/19/2416:00 92726233002 8102-MW-1 Water 04/19/2411:40 04/19/2416:00 92726233003 8102-MW-2A Water 04/19/2413:35 04/19/2416:00 92726233004 8102-MW-3 Water 04/19/2411:35 04/19/2416:00 92726233005 8102-MW-5 Water 04/19/2410:00 04/19/2416:00 92726233006 8102-MW-6 Water 04/19/2412:35 04/19/2416:00 92726233007 8102-MW-7 Water 04/19/2413:30 04/19/2416:00 92726233008 8102-MW-8 Water 04/19/2410:45 04/19/2416:00 92726233009 8102-MW-9S Water 04/19/2410:50 04/19/2416:00 92726233010 8102-MW-9D Water 04/19/2412:00 04/19/2416:00 92726233011 8102-SW-1 Water 04/19/2412:40 04/19/2416:00 92726233012 8102-SW-2 Water 04/19/2410:20 04/19/2416:00 92726233013 8102-Duplicate Water 04/19/2410:50 04/19/2416:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Rutherford Co. LF-South Apr 24 92726233 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92726233001 8102-MW-4A EPA 6010D DBB1 7 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D by SIM ACG 2 PAN EPA 8260D TMH 52 PASI-C 92726233002 8102-MW-1 EPA 6010D D661 7 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D by SIM ACG 2 PAN EPA 8260D TMH 52 PASI-C 92726233003 8102-MW-2A EPA 6010D D661 7 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D by SIM JIBE 2 PAN EPA 8260D TMH 52 PASI-C 92726233004 8102-MW-3 EPA 6010D D661 7 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D by SIM ACG 2 PAN EPA 8260D TMH 52 PASI-C 92726233005 8102-MW-5 EPA 6010D D661 7 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D by SIM ACG 2 PAN EPA 8260D TMH 52 PASI-C 92726233006 8102-MW-6 EPA 6010D D661 7 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D by SIM ACG 2 PAN EPA 8260D TMH 52 PASI-C 92726233007 8102-MW-7 EPA 6010D D661 7 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D by SIM ACG 2 PAN EPA 8260D TMH 52 PASI-C 92726233008 8102-MW-8 EPA 6010D D661 7 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D by SIM ACG 2 PAN EPA 8260D TMH 52 PASI-C 92726233009 8102-MW-9S EPA 6010D D661 7 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D by SIM ACG 2 PAN EPA 8260D TMH 52 PASI-C 92726233010 8102-MW-9D EPA 6010D D661 7 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Lab ID Sample ID Method Analysts Analytes Reported Laboratory EPA 7470A BM 1 PASI-A EPA 8260D by SIM JBE 2 PAN EPA 8260D TMH 52 PASI-C 92726233011 8102-SW-1 EPA 6010D D13131 7 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D by SIM JBE 2 PAN EPA 8260D TMH 52 PASI-C 92726233012 8102-SW-2 EPA 6010D D13131 7 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D by SIM JBE 2 PAN EPA 8260D TMH 52 PASI-C 92726233013 8102-Duplicate EPA 8260D TMH 52 PASI-C PAN = Pace National - Mt. Juliet PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-MW-4A Lab ID: 92726233001 Collected: 04/19/24 13:45 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 2.5 1 04/25/24 13:05 04/29/24 21:27 7440-38-2 Barium 30.9 ug/L 5.0 0.79 1 05/03/2414:12 05/05/2416:59 7440-39-3 Cadmium ND ug/L 1.0 0.29 1 04/25/24 13:05 04/29/24 21:27 7440-43-9 Chromium ND ug/L 5.0 0.63 1 04/25/24 13:05 04/29/24 21:27 7440-47-3 Lead ND ug/L 5.0 1.4 1 04/25/24 13:05 04/29/24 21:27 7439-92-1 Selenium ND ug/L 10.0 4.1 1 04/25/24 13:05 04/29/24 21:27 7782-49-2 Silver ND ug/L 5.0 0.49 1 04/25/24 13:05 04/29/24 21:27 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury ND ug/L 0.20 0.12 1 04/22/24 21:22 04/24/24 13:39 7439-97-6 VOA (GC/MS) 8260D-SIM Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM Pace National - Mt. Juliet 1,4-Dioxane (p-Dioxane) ND ug/L 3.00 0.597 1 04/27/24 00:25 04/27/24 00:25 123-91-1 Surrogates Toluene-d8 (S) 100 % 77.0-127 1 04/27/24 00:25 04/27/24 00:25 2037-26-5 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 04/23/24 07:58 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 04/23/24 07:58 107-13-1 Benzene ND ug/L 1.0 0.34 1 04/23/24 07:58 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 04/23/24 07:58 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 04/23/24 07:58 75-27-4 Bromoform ND ug/L 1.0 0.34 1 04/23/24 07:58 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 04/23/24 07:58 74-83-9 v2 2-Butanone (MEK) ND ug/L 5.0 4.0 1 04/23/24 07:58 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 04/23/24 07:58 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 04/23/24 07:58 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 04/23/24 07:58 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 04/23/24 07:58 75-00-3 Chloroform ND ug/L 1.0 0.43 1 04/23/24 07:58 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 04/23/24 07:58 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 04/23/24 07:58 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 04/23/24 07:58 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 04/23/24 07:58 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 04/23/24 07:58 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 04/23/24 07:58 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 04/23/24 07:58 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 04/23/24 07:58 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 04/23/24 07:58 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 04/23/24 07:58 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 04/23/24 07:58 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 04/23/24 07:58 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/06/2024 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-MW-4A Lab ID: 92726233001 Collected: 04/19/24 13:45 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/06/2024 03:30 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.40 1 04/23/24 07:58 156-60-5 ND ug/L 1.0 0.36 1 04/23/24 07:58 78-87-5 ND ug/L 1.0 0.36 1 04/23/24 07:58 10061-01-5 ND ug/L 1.0 0.36 1 04/23/24 07:58 10061-02-6 ND ug/L 1.0 0.30 1 04/23/24 07:58 100-41-4 ND ug/L 5.0 0.48 1 04/23/24 07:58 591-78-6 ND ug/L 20.0 9.7 1 04/23/24 07:58 74-88-4 v2 ND ug/L 5.0 2.0 1 04/23/24 07:58 75-09-2 ND ug/L 5.0 2.7 1 04/23/24 07:58 108-10-1 ND ug/L 1.0 0.29 1 04/23/24 07:58 100-42-5 ND ug/L 1.0 0.31 1 04/23/24 07:58 630-20-6 ND ug/L 1.0 0.22 1 04/23/24 07:58 79-34-5 ND ug/L 1.0 0.29 1 04/23/24 07:58 127-18-4 ND ug/L 1.0 0.24 1 04/23/24 07:58 108-88-3 ND ug/L 1.0 0.33 1 04/23/24 07:58 71-55-6 ND ug/L 1.0 0.32 1 04/23/24 07:58 79-00-5 ND ug/L 1.0 0.38 1 04/23/24 07:58 79-01-6 ND ug/L 1.0 0.30 1 04/23/24 07:58 75-69-4 ND ug/L 1.0 0.26 1 04/23/24 07:58 96-18-4 ND ug/L 2.0 1.3 1 04/23/24 07:58 108-05-4 ND ug/L 1.0 0.39 1 04/23/24 07:58 75-01-4 ND ug/L 1.0 0.34 1 04/23/24 07:58 1330-20-7 ND ug/L 2.0 0.71 1 04/23/24 07:58 179601-23-1 ND ug/L 1.0 0.34 1 04/23/24 07:58 95-47-6 96 % 70-130 1 04/23/24 07:58 460-00-4 107 % 70-130 1 04/23/24 07:58 17060-07-0 100 % 70-130 1 04/23/24 07:58 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-MW-1 Lab ID: 92726233002 Collected: 04/19/24 11:40 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 2.5 1 04/25/24 13:05 04/29/24 21:31 7440-38-2 Barium 75.8 ug/L 5.0 0.79 1 05/03/2414:12 05/05/2417:11 7440-39-3 Cadmium ND ug/L 1.0 0.29 1 04/25/24 13:05 04/29/24 21:31 7440-43-9 Chromium ND ug/L 5.0 0.63 1 04/25/24 13:05 04/29/24 21:31 7440-47-3 Lead ND ug/L 5.0 1.4 1 04/25/24 13:05 04/29/24 21:31 7439-92-1 Selenium ND ug/L 10.0 4.1 1 04/25/24 13:05 04/29/24 21:31 7782-49-2 Silver ND ug/L 5.0 0.49 1 04/25/24 13:05 04/29/24 21:31 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury ND ug/L 0.20 0.12 1 04/22/24 21:22 04/24/24 13:41 7439-97-6 VOA (GC/MS) 8260D-SIM Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM Pace National - Mt. Juliet 1,4-Dioxane (p-Dioxane) ND ug/L 3.00 0.597 1 04/27/24 00:46 04/27/24 00:46 123-91-1 Surrogates Toluene-d8 (S) 100 % 77.0-127 1 04/27/24 00:46 04/27/24 00:46 2037-26-5 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 04/23/24 08:16 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 04/23/24 08:16 107-13-1 Benzene 1.4 ug/L 1.0 0.34 1 04/23/24 08:16 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 04/23/24 08:16 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 04/23/24 08:16 75-27-4 Bromoform ND ug/L 1.0 0.34 1 04/23/24 08:16 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 04/23/24 08:16 74-83-9 v2 2-Butanone (MEK) ND ug/L 5.0 4.0 1 04/23/24 08:16 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 04/23/24 08:16 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 04/23/24 08:16 56-23-5 Chlorobenzene 1.4 ug/L 1.0 0.28 1 04/23/24 08:16 108-90-7 Chloroethane 5.0 ug/L 1.0 0.65 1 04/23/24 08:16 75-00-3 Chloroform 0.511 ug/L 1.0 0.43 1 04/23/24 08:16 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 04/23/24 08:16 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 04/23/24 08:16 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 04/23/24 08:16 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 04/23/24 08:16 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 04/23/24 08:16 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 04/23/24 08:16 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 04/23/24 08:16 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 04/23/24 08:16 110-57-6 1,1-Dichloroethane 48.3 ug/L 1.0 0.37 1 04/23/24 08:16 75-34-3 1,2-Dichloroethane 0.46J ug/L 1.0 0.32 1 04/23/24 08:16 107-06-2 1,1-Dichloroethene 1.0 ug/L 1.0 0.35 1 04/23/24 08:16 75-35-4 cis-1,2-Dichloroethene 5.6 ug/L 1.0 0.38 1 04/23/24 08:16 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/06/2024 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-MW-1 Lab ID: 92726233002 Collected: 04/19/24 11:40 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/06/2024 03:30 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.40 1 04/23/24 08:16 156-60-5 ND ug/L 1.0 0.36 1 04/23/24 08:16 78-87-5 ND ug/L 1.0 0.36 1 04/23/24 08:16 10061-01-5 ND ug/L 1.0 0.36 1 04/23/24 08:16 10061-02-6 ND ug/L 1.0 0.30 1 04/23/24 08:16 100-41-4 ND ug/L 5.0 0.48 1 04/23/24 08:16 591-78-6 ND ug/L 20.0 9.7 1 04/23/24 08:16 74-88-4 v2 16.8 ug/L 5.0 2.0 1 04/23/24 08:16 75-09-2 ND ug/L 5.0 2.7 1 04/23/24 08:16 108-10-1 ND ug/L 1.0 0.29 1 04/23/24 08:16 100-42-5 ND ug/L 1.0 0.31 1 04/23/24 08:16 630-20-6 ND ug/L 1.0 0.22 1 04/23/24 08:16 79-34-5 ND ug/L 1.0 0.29 1 04/23/24 08:16 127-18-4 ND ug/L 1.0 0.24 1 04/23/24 08:16 108-88-3 ND ug/L 1.0 0.33 1 04/23/24 08:16 71-55-6 ND ug/L 1.0 0.32 1 04/23/24 08:16 79-00-5 ND ug/L 1.0 0.38 1 04/23/24 08:16 79-01-6 ND ug/L 1.0 0.30 1 04/23/24 08:16 75-69-4 ND ug/L 1.0 0.26 1 04/23/24 08:16 96-18-4 ND ug/L 2.0 1.3 1 04/23/24 08:16 108-05-4 ND ug/L 1.0 0.39 1 04/23/24 08:16 75-01-4 2.5 ug/L 1.0 0.34 1 04/23/24 08:16 1330-20-7 ND ug/L 2.0 0.71 1 04/23/24 08:16 179601-23-1 2.5 ug/L 1.0 0.34 1 04/23/24 08:16 95-47-6 94 % 70-130 1 04/23/24 08:16 460-00-4 108 % 70-130 1 04/23/24 08:16 17060-07-0 99 % 70-130 1 04/23/24 08:16 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-MW-2A Lab ID: 92726233003 Collected: 04/19/24 13:35 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic 13.3 ug/L 10.0 2.5 1 04/25/24 13:05 04/29/24 21:34 7440-38-2 Barium 124 ug/L 5.0 0.79 1 05/03/2414:12 05/05/2417:13 7440-39-3 Cadmium ND ug/L 1.0 0.29 1 04/25/24 13:05 04/29/24 21:34 7440-43-9 Chromium 9.4 ug/L 5.0 0.63 1 04/25/24 13:05 04/29/24 21:34 7440-47-3 Lead ND ug/L 5.0 1.4 1 04/25/24 13:05 04/29/24 21:34 7439-92-1 Selenium ND ug/L 10.0 4.1 1 04/25/24 13:05 04/29/24 21:34 7782-49-2 Silver ND ug/L 5.0 0.49 1 04/25/24 13:05 04/29/24 21:34 7440-22-4 7470 Mercury Mercury VOA (GC/MS) 8260D-SIM 1,4-Dioxane (p-Dioxane) Surrogates Toluene-d8 (S) 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene Date: 05/06/2024 03:30 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 04/22/24 21:22 04/24/24 13:44 7439-97-6 Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM Pace National - Mt. Juliet 7.60 ug/L 3.00 0.597 1 04/29/24 23:56 04/29/24 23:56 123-91-1 107 % 77.0-127 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 0.44J ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 4.1 ug/L 1.0 0.79J ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 1.4 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 1 04/29/24 23:56 04/29/24 23:56 2037-26-5 5.1 1 04/23/24 08:34 67-64-1 1.8 1 04/23/24 08:34 107-13-1 0.34 1 04/23/24 08:34 71-43-2 0.47 1 04/23/24 08:34 74-97-5 0.31 1 04/23/24 08:34 75-27-4 0.34 1 04/23/24 08:34 75-25-2 1.7 1 04/23/24 08:34 74-83-9 4.0 1 04/23/24 08:34 78-93-3 0.36 1 04/23/24 08:34 75-15-0 0.33 1 04/23/24 08:34 56-23-5 0.28 1 04/23/24 08:34 108-90-7 0.65 1 04/23/24 08:34 75-00-3 0.43 1 04/23/24 08:34 67-66-3 0.54 1 04/23/24 08:34 74-87-3 0.34 1 04/23/24 08:34 96-12-8 0.36 1 04/23/24 08:34 124-48-1 0.27 1 04/23/24 08:34 106-93-4 0.39 1 04/23/24 08:34 74-95-3 0.34 1 04/23/24 08:34 95-50-1 0.33 1 04/23/24 08:34 106-46-7 0.56 1 04/23/24 08:34 110-57-6 0.37 1 04/23/24 08:34 75-34-3 0.32 1 04/23/24 08:34 107-06-2 0.35 1 04/23/24 08:34 75-35-4 0.38 1 04/23/24 08:34 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 10 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-MW-2A Lab ID: 92726233003 Collected: 04/19/24 13:35 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/06/2024 03:30 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.40 1 04/23/24 08:34 156-60-5 ND ug/L 1.0 0.36 1 04/23/24 08:34 78-87-5 ND ug/L 1.0 0.36 1 04/23/24 08:34 10061-01-5 ND ug/L 1.0 0.36 1 04/23/24 08:34 10061-02-6 ND ug/L 1.0 0.30 1 04/23/24 08:34 100-41-4 ND ug/L 5.0 0.48 1 04/23/24 08:34 591-78-6 ND ug/L 20.0 9.7 1 04/23/24 08:34 74-88-4 v2 ND ug/L 5.0 2.0 1 04/23/24 08:34 75-09-2 ND ug/L 5.0 2.7 1 04/23/24 08:34 108-10-1 ND ug/L 1.0 0.29 1 04/23/24 08:34 100-42-5 ND ug/L 1.0 0.31 1 04/23/24 08:34 630-20-6 ND ug/L 1.0 0.22 1 04/23/24 08:34 79-34-5 ND ug/L 1.0 0.29 1 04/23/24 08:34 127-18-4 ND ug/L 1.0 0.24 1 04/23/24 08:34 108-88-3 ND ug/L 1.0 0.33 1 04/23/24 08:34 71-55-6 ND ug/L 1.0 0.32 1 04/23/24 08:34 79-00-5 ND ug/L 1.0 0.38 1 04/23/24 08:34 79-01-6 ND ug/L 1.0 0.30 1 04/23/24 08:34 75-69-4 ND ug/L 1.0 0.26 1 04/23/24 08:34 96-18-4 ND ug/L 2.0 1.3 1 04/23/24 08:34 108-05-4 ND ug/L 1.0 0.39 1 04/23/24 08:34 75-01-4 ND ug/L 1.0 0.34 1 04/23/24 08:34 1330-20-7 ND ug/L 2.0 0.71 1 04/23/24 08:34 179601-23-1 ND ug/L 1.0 0.34 1 04/23/24 08:34 95-47-6 95 % 70-130 1 04/23/24 08:34 460-00-4 106 % 70-130 1 04/23/24 08:34 17060-07-0 99 % 70-130 1 04/23/24 08:34 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-MW-3 Lab ID: 92726233004 Collected: 04/19/24 11:35 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 2.5 1 04/25/24 13:05 04/29/24 21:37 7440-38-2 Barium 38.0 ug/L 5.0 0.79 1 05/03/2414:12 05/05/2417:16 7440-39-3 Cadmium ND ug/L 1.0 0.29 1 04/25/24 13:05 04/29/24 21:37 7440-43-9 Chromium ND ug/L 5.0 0.63 1 04/25/24 13:05 04/29/24 21:37 7440-47-3 Lead ND ug/L 5.0 1.4 1 04/25/24 13:05 04/29/24 21:37 7439-92-1 Selenium ND ug/L 10.0 4.1 1 04/25/24 13:05 04/29/24 21:37 7782-49-2 Silver ND ug/L 5.0 0.49 1 04/25/24 13:05 04/29/24 21:37 7440-22-4 7470 Mercury Mercury VOA (GC/MS) 8260D-SIM 1,4-Dioxane (p-Dioxane) Surrogates Toluene-d8 (S) 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene Date: 05/06/2024 03:30 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 04/22/24 21:22 04/24/24 13:46 7439-97-6 Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM Pace National - Mt. Juliet ND ug/L 3.00 0.597 1 04/28/2419:45 04/28/2419:45 123-91-1 106 % 77.0-127 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 1 04/28/2419:45 04/28/2419:45 2037-26-5 5.1 1 04/23/24 11:30 67-64-1 1.8 1 04/23/24 11:30 107-13-1 0.34 1 04/23/24 11:30 71-43-2 0.47 1 04/23/24 11:30 74-97-5 0.31 1 04/23/24 11:30 75-27-4 0.34 1 04/23/24 11:30 75-25-2 1.7 1 04/23/24 11:30 74-83-9 4.0 1 04/23/24 11:30 78-93-3 0.36 1 04/23/24 11:30 75-15-0 0.33 1 04/23/24 11:30 56-23-5 0.28 1 04/23/24 11:30 108-90-7 0.65 1 04/23/24 11:30 75-00-3 0.43 1 04/23/24 11:30 67-66-3 0.54 1 04/23/24 11:30 74-87-3 0.34 1 04/23/24 11:30 96-12-8 0.36 1 04/23/24 11:30 124-48-1 0.27 1 04/23/24 11:30 106-93-4 0.39 1 04/23/24 11:30 74-95-3 0.34 1 04/23/24 11:30 95-50-1 0.33 1 04/23/24 11:30 106-46-7 0.56 1 04/23/24 11:30 110-57-6 0.37 1 04/23/24 11:30 75-34-3 0.32 1 04/23/24 11:30 107-06-2 0.35 1 04/23/24 11:30 75-35-4 0.38 1 04/23/24 11:30 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 12 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-MW-3 Lab ID: 92726233004 Collected: 04/19/24 11:35 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/06/2024 03:30 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.40 1 04/23/2411:30 156-60-5 ND ug/L 1.0 0.36 1 04/23/2411:30 78-87-5 ND ug/L 1.0 0.36 1 04/23/24 11:30 10061-01-5 ND ug/L 1.0 0.36 1 04/23/2411:30 10061-02-6 ND ug/L 1.0 0.30 1 04/23/2411:30 100-41-4 ND ug/L 5.0 0.48 1 04/23/2411:30 591-78-6 ND ug/L 20.0 9.7 1 04/23/2411:30 74-88-4 v2 ND ug/L 5.0 2.0 1 04/23/2411:30 75-09-2 ND ug/L 5.0 2.7 1 04/23/2411:30 108-10-1 ND ug/L 1.0 0.29 1 04/23/2411:30 100-42-5 ND ug/L 1.0 0.31 1 04/23/2411:30 630-20-6 ND ug/L 1.0 0.22 1 04/23/2411:30 79-34-5 ND ug/L 1.0 0.29 1 04/23/2411:30 127-18-4 ND ug/L 1.0 0.24 1 04/23/2411:30 108-88-3 ND ug/L 1.0 0.33 1 04/23/2411:30 71-55-6 ND ug/L 1.0 0.32 1 04/23/2411:30 79-00-5 ND ug/L 1.0 0.38 1 04/23/2411:30 79-01-6 ND ug/L 1.0 0.30 1 04/23/2411:30 75-69-4 ND ug/L 1.0 0.26 1 04/23/2411:30 96-18-4 ND ug/L 2.0 1.3 1 04/23/2411:30 108-05-4 ND ug/L 1.0 0.39 1 04/23/2411:30 75-01-4 ND ug/L 1.0 0.34 1 04/23/2411:30 1330-20-7 ND ug/L 2.0 0.71 1 04/23/2411:30 179601-23-1 ND ug/L 1.0 0.34 1 04/23/2411:30 95-47-6 94 % 70-130 1 04/23/2411:30 460-00-4 108 % 70-130 1 04/23/2411:30 17060-07-0 100 % 70-130 1 04/23/2411:30 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-MW-5 Lab ID: 92726233005 Collected: 04/19/24 10:00 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic 5.8J ug/L 10.0 2.5 1 04/25/24 13:05 04/29/24 21:41 7440-38-2 Barium 173 ug/L 5.0 0.79 1 05/03/2414:12 05/05/2417:19 7440-39-3 Cadmium ND ug/L 1.0 0.29 1 04/25/24 13:05 04/29/24 21:41 7440-43-9 Chromium ND ug/L 5.0 0.63 1 04/25/24 13:05 04/29/24 21:41 7440-47-3 Lead 3.1J ug/L 5.0 1.4 1 04/25/24 13:05 04/29/24 21:41 7439-92-1 Selenium ND ug/L 10.0 4.1 1 04/25/24 13:05 04/29/24 21:41 7782-49-2 Silver ND ug/L 5.0 0.49 1 04/25/24 13:05 04/29/24 21:41 7440-22-4 7470 Mercury Mercury VOA (GC/MS) 8260D-SIM 1,4-Dioxane (p-Dioxane) Surrogates Toluene-d8 (S) 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene Date: 05/06/2024 03:30 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 04/22/24 21:22 04/24/24 13:48 7439-97-6 Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM Pace National - Mt. Juliet 10.7 ug/L 3.00 0.597 1 04/28/24 20:07 04/28/24 20:07 123-91-1 106 % 77.0-127 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 0.48J ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 1.2 ug/L 1.0 1.1 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 1.1 ug/L 1.0 ND ug/L 1.0 1.4 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 3.2 ug/L 1.0 1 04/28/24 20:07 04/28/24 20:07 2037-26-5 5.1 1 04/23/24 08:51 67-64-1 1.8 1 04/23/24 08:51 107-13-1 0.34 1 04/23/24 08:51 71-43-2 0.47 1 04/23/24 08:51 74-97-5 0.31 1 04/23/24 08:51 75-27-4 0.34 1 04/23/24 08:51 75-25-2 1.7 1 04/23/24 08:51 74-83-9 4.0 1 04/23/24 08:51 78-93-3 0.36 1 04/23/24 08:51 75-15-0 0.33 1 04/23/24 08:51 56-23-5 0.28 1 04/23/24 08:51 108-90-7 0.65 1 04/23/24 08:51 75-00-3 0.43 1 04/23/24 08:51 67-66-3 0.54 1 04/23/24 08:51 74-87-3 0.34 1 04/23/24 08:51 96-12-8 0.36 1 04/23/24 08:51 124-48-1 0.27 1 04/23/24 08:51 106-93-4 0.39 1 04/23/24 08:51 74-95-3 0.34 1 04/23/24 08:51 95-50-1 0.33 1 04/23/24 08:51 106-46-7 0.56 1 04/23/24 08:51 110-57-6 0.37 1 04/23/24 08:51 75-34-3 0.32 1 04/23/24 08:51 107-06-2 0.35 1 04/23/24 08:51 75-35-4 0.38 1 04/23/24 08:51 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 14 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-MW-5 Lab ID: 92726233005 Collected: 04/19/24 10:00 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/06/2024 03:30 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.40 1 04/23/24 08:51 156-60-5 ND ug/L 1.0 0.36 1 04/23/24 08:51 78-87-5 ND ug/L 1.0 0.36 1 04/23/24 08:51 10061-01-5 ND ug/L 1.0 0.36 1 04/23/24 08:51 10061-02-6 ND ug/L 1.0 0.30 1 04/23/24 08:51 100-41-4 ND ug/L 5.0 0.48 1 04/23/24 08:51 591-78-6 ND ug/L 20.0 9.7 1 04/23/24 08:51 74-88-4 v2 ND ug/L 5.0 2.0 1 04/23/24 08:51 75-09-2 ND ug/L 5.0 2.7 1 04/23/24 08:51 108-10-1 ND ug/L 1.0 0.29 1 04/23/24 08:51 100-42-5 ND ug/L 1.0 0.31 1 04/23/24 08:51 630-20-6 ND ug/L 1.0 0.22 1 04/23/24 08:51 79-34-5 ND ug/L 1.0 0.29 1 04/23/24 08:51 127-18-4 ND ug/L 1.0 0.24 1 04/23/24 08:51 108-88-3 ND ug/L 1.0 0.33 1 04/23/24 08:51 71-55-6 ND ug/L 1.0 0.32 1 04/23/24 08:51 79-00-5 ND ug/L 1.0 0.38 1 04/23/24 08:51 79-01-6 ND ug/L 1.0 0.30 1 04/23/24 08:51 75-69-4 ND ug/L 1.0 0.26 1 04/23/24 08:51 96-18-4 ND ug/L 2.0 1.3 1 04/23/24 08:51 108-05-4 0.84J ug/L 1.0 0.39 1 04/23/24 08:51 75-01-4 ND ug/L 1.0 0.34 1 04/23/24 08:51 1330-20-7 ND ug/L 2.0 0.71 1 04/23/24 08:51 179601-23-1 ND ug/L 1.0 0.34 1 04/23/24 08:51 95-47-6 100 % 70-130 1 04/23/24 08:51 460-00-4 106 % 70-130 1 04/23/24 08:51 17060-07-0 99 % 70-130 1 04/23/24 08:51 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-MW-6 Lab ID: 92726233006 Collected: 04/19/24 12:35 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 2.5 1 04/25/24 13:05 04/29/24 21:44 7440-38-2 Barium 27.0 ug/L 5.0 0.79 1 05/03/2414:12 05/05/2417:22 7440-39-3 Cadmium ND ug/L 1.0 0.29 1 04/25/24 13:05 04/29/24 21:44 7440-43-9 Chromium ND ug/L 5.0 0.63 1 04/25/24 13:05 04/29/24 21:44 7440-47-3 Lead ND ug/L 5.0 1.4 1 04/25/24 13:05 04/29/24 21:44 7439-92-1 Selenium ND ug/L 10.0 4.1 1 04/25/24 13:05 04/29/24 21:44 7782-49-2 Silver ND ug/L 5.0 0.49 1 04/25/24 13:05 04/29/24 21:44 7440-22-4 7470 Mercury Mercury VOA (GC/MS) 8260D-SIM 1,4-Dioxane (p-Dioxane) Surrogates Toluene-d8 (S) 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene Date: 05/06/2024 03:30 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 04/22/24 21:22 04/24/24 13:50 7439-97-6 Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM Pace National - Mt. Juliet 35.1 ug/L 3.00 0.597 1 04/28/24 20:29 04/28/24 20:29 123-91-1 106 % 77.0-127 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 1.1 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 2.7 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 1.0 ug/L 1.0 ND ug/L 1.0 0.70J ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 1.6 ug/L 1.0 1 04/28/24 20:29 04/28/24 20:29 2037-26-5 5.1 1 04/23/24 09:09 67-64-1 1.8 1 04/23/24 09:09 107-13-1 0.34 1 04/23/24 09:09 71-43-2 0.47 1 04/23/24 09:09 74-97-5 0.31 1 04/23/24 09:09 75-27-4 0.34 1 04/23/24 09:09 75-25-2 1.7 1 04/23/24 09:09 74-83-9 4.0 1 04/23/24 09:09 78-93-3 0.36 1 04/23/24 09:09 75-15-0 0.33 1 04/23/24 09:09 56-23-5 0.28 1 04/23/24 09:09 108-90-7 0.65 1 04/23/24 09:09 75-00-3 0.43 1 04/23/24 09:09 67-66-3 0.54 1 04/23/24 09:09 74-87-3 0.34 1 04/23/24 09:09 96-12-8 0.36 1 04/23/24 09:09 124-48-1 0.27 1 04/23/24 09:09 106-93-4 0.39 1 04/23/24 09:09 74-95-3 0.34 1 04/23/24 09:09 95-50-1 0.33 1 04/23/24 09:09 106-46-7 0.56 1 04/23/24 09:09 110-57-6 0.37 1 04/23/24 09:09 75-34-3 0.32 1 04/23/24 09:09 107-06-2 0.35 1 04/23/24 09:09 75-35-4 0.38 1 04/23/24 09:09 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 16 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-MW-6 Lab ID: 92726233006 Collected: 04/19/24 12:35 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/06/2024 03:30 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.40 1 04/23/24 09:09 156-60-5 ND ug/L 1.0 0.36 1 04/23/24 09:09 78-87-5 ND ug/L 1.0 0.36 1 04/23/24 09:09 10061-01-5 ND ug/L 1.0 0.36 1 04/23/24 09:09 10061-02-6 ND ug/L 1.0 0.30 1 04/23/24 09:09 100-41-4 ND ug/L 5.0 0.48 1 04/23/24 09:09 591-78-6 ND ug/L 20.0 9.7 1 04/23/24 09:09 74-88-4 v2 ND ug/L 5.0 2.0 1 04/23/24 09:09 75-09-2 ND ug/L 5.0 2.7 1 04/23/24 09:09 108-10-1 ND ug/L 1.0 0.29 1 04/23/24 09:09 100-42-5 ND ug/L 1.0 0.31 1 04/23/24 09:09 630-20-6 ND ug/L 1.0 0.22 1 04/23/24 09:09 79-34-5 ND ug/L 1.0 0.29 1 04/23/24 09:09 127-18-4 ND ug/L 1.0 0.24 1 04/23/24 09:09 108-88-3 ND ug/L 1.0 0.33 1 04/23/24 09:09 71-55-6 ND ug/L 1.0 0.32 1 04/23/24 09:09 79-00-5 ND ug/L 1.0 0.38 1 04/23/24 09:09 79-01-6 ND ug/L 1.0 0.30 1 04/23/24 09:09 75-69-4 ND ug/L 1.0 0.26 1 04/23/24 09:09 96-18-4 ND ug/L 2.0 1.3 1 04/23/24 09:09 108-05-4 ND ug/L 1.0 0.39 1 04/23/24 09:09 75-01-4 ND ug/L 1.0 0.34 1 04/23/24 09:09 1330-20-7 ND ug/L 2.0 0.71 1 04/23/24 09:09 179601-23-1 ND ug/L 1.0 0.34 1 04/23/24 09:09 95-47-6 99 % 70-130 1 04/23/24 09:09 460-00-4 106 % 70-130 1 04/23/24 09:09 17060-07-0 100 % 70-130 1 04/23/24 09:09 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-MW-7 Lab ID: 92726233007 Collected: 04/19/24 13:30 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 2.5 1 04/25/24 13:05 04/29/24 21:47 7440-38-2 Barium 31.7 ug/L 5.0 0.79 1 05/03/2414:12 05/05/2417:25 7440-39-3 Cadmium ND ug/L 1.0 0.29 1 04/25/24 13:05 04/29/24 21:47 7440-43-9 Chromium 0.80J ug/L 5.0 0.63 1 04/25/24 13:05 04/29/24 21:47 7440-47-3 Lead ND ug/L 5.0 1.4 1 04/25/24 13:05 04/29/24 21:47 7439-92-1 Selenium ND ug/L 10.0 4.1 1 04/25/24 13:05 04/29/24 21:47 7782-49-2 Silver ND ug/L 5.0 0.49 1 04/25/24 13:05 04/29/24 21:47 7440-22-4 7470 Mercury Mercury VOA (GC/MS) 8260D-SIM 1,4-Dioxane (p-Dioxane) Surrogates Toluene-d8 (S) 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene Date: 05/06/2024 03:30 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 04/22/24 21:22 04/24/24 13:53 7439-97-6 Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM Pace National - Mt. Juliet ND ug/L 3.00 0.597 1 04/28/24 20:51 04/28/24 20:51 123-91-1 105 % 77.0-127 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 1 04/28/24 20:51 04/28/24 20:51 2037-26-5 5.1 1 04/23/24 09:27 67-64-1 1.8 1 04/23/24 09:27 107-13-1 0.34 1 04/23/24 09:27 71-43-2 0.47 1 04/23/24 09:27 74-97-5 0.31 1 04/23/24 09:27 75-27-4 0.34 1 04/23/24 09:27 75-25-2 1.7 1 04/23/24 09:27 74-83-9 4.0 1 04/23/24 09:27 78-93-3 0.36 1 04/23/24 09:27 75-15-0 0.33 1 04/23/24 09:27 56-23-5 0.28 1 04/23/24 09:27 108-90-7 0.65 1 04/23/24 09:27 75-00-3 0.43 1 04/23/24 09:27 67-66-3 0.54 1 04/23/24 09:27 74-87-3 0.34 1 04/23/24 09:27 96-12-8 0.36 1 04/23/24 09:27 124-48-1 0.27 1 04/23/24 09:27 106-93-4 0.39 1 04/23/24 09:27 74-95-3 0.34 1 04/23/24 09:27 95-50-1 0.33 1 04/23/24 09:27 106-46-7 0.56 1 04/23/24 09:27 110-57-6 0.37 1 04/23/24 09:27 75-34-3 0.32 1 04/23/24 09:27 107-06-2 0.35 1 04/23/24 09:27 75-35-4 0.38 1 04/23/24 09:27 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 18 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-MW-7 Lab ID: 92726233007 Collected: 04/19/24 13:30 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/06/2024 03:30 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.40 1 04/23/24 09:27 156-60-5 ND ug/L 1.0 0.36 1 04/23/24 09:27 78-87-5 ND ug/L 1.0 0.36 1 04/23/24 09:27 10061-01-5 ND ug/L 1.0 0.36 1 04/23/24 09:27 10061-02-6 ND ug/L 1.0 0.30 1 04/23/24 09:27 100-41-4 ND ug/L 5.0 0.48 1 04/23/24 09:27 591-78-6 ND ug/L 20.0 9.7 1 04/23/24 09:27 74-88-4 v2 ND ug/L 5.0 2.0 1 04/23/24 09:27 75-09-2 ND ug/L 5.0 2.7 1 04/23/24 09:27 108-10-1 ND ug/L 1.0 0.29 1 04/23/24 09:27 100-42-5 ND ug/L 1.0 0.31 1 04/23/24 09:27 630-20-6 ND ug/L 1.0 0.22 1 04/23/24 09:27 79-34-5 ND ug/L 1.0 0.29 1 04/23/24 09:27 127-18-4 ND ug/L 1.0 0.24 1 04/23/24 09:27 108-88-3 ND ug/L 1.0 0.33 1 04/23/24 09:27 71-55-6 ND ug/L 1.0 0.32 1 04/23/24 09:27 79-00-5 ND ug/L 1.0 0.38 1 04/23/24 09:27 79-01-6 ND ug/L 1.0 0.30 1 04/23/24 09:27 75-69-4 ND ug/L 1.0 0.26 1 04/23/24 09:27 96-18-4 ND ug/L 2.0 1.3 1 04/23/24 09:27 108-05-4 ND ug/L 1.0 0.39 1 04/23/24 09:27 75-01-4 ND ug/L 1.0 0.34 1 04/23/24 09:27 1330-20-7 ND ug/L 2.0 0.71 1 04/23/24 09:27 179601-23-1 ND ug/L 1.0 0.34 1 04/23/24 09:27 95-47-6 93 % 70-130 1 04/23/24 09:27 460-00-4 104 % 70-130 1 04/23/24 09:27 17060-07-0 98 % 70-130 1 04/23/24 09:27 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-MW-8 Lab ID: 92726233008 Collected: 04/19/24 10:45 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 2.5 1 04/25/24 13:05 04/29/24 21:58 7440-38-2 Barium 118 ug/L 10.0 1.6 2 04/25/24 13:05 05/01/24 00:34 7440-39-3 Cadmium ND ug/L 1.0 0.29 1 04/25/24 13:05 04/29/24 21:58 7440-43-9 Chromium ND ug/L 5.0 0.63 1 04/25/24 13:05 04/29/24 21:58 7440-47-3 Lead 1.7J ug/L 5.0 1.4 1 04/25/24 13:05 04/29/24 21:58 7439-92-1 Selenium ND ug/L 10.0 4.1 1 04/25/24 13:05 04/29/24 21:58 7782-49-2 Silver ND ug/L 5.0 0.49 1 04/25/24 13:05 04/29/24 21:58 7440-22-4 7470 Mercury Mercury VOA (GC/MS) 8260D-SIM 1,4-Dioxane (p-Dioxane) Surrogates Toluene-d8 (S) 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene Date: 05/06/2024 03:30 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville 0.99 ug/L 0.20 0.12 1 04/22/24 21:22 04/24/24 13:59 7439-97-6 Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM Pace National - Mt. Juliet ND ug/L 3.00 0.597 1 04/28/24 21:12 04/28/24 21:12 123-91-1 105 % 77.0-127 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 1.4 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 1 04/28/24 21:12 04/28/24 21:12 2037-26-5 5.1 1 04/23/24 09:44 67-64-1 1.8 1 04/23/24 09:44 107-13-1 0.34 1 04/23/24 09:44 71-43-2 0.47 1 04/23/24 09:44 74-97-5 0.31 1 04/23/24 09:44 75-27-4 0.34 1 04/23/24 09:44 75-25-2 1.7 1 04/23/24 09:44 74-83-9 4.0 1 04/23/24 09:44 78-93-3 0.36 1 04/23/24 09:44 75-15-0 0.33 1 04/23/24 09:44 56-23-5 0.28 1 04/23/24 09:44 108-90-7 0.65 1 04/23/24 09:44 75-00-3 0.43 1 04/23/24 09:44 67-66-3 0.54 1 04/23/24 09:44 74-87-3 0.34 1 04/23/24 09:44 96-12-8 0.36 1 04/23/24 09:44 124-48-1 0.27 1 04/23/24 09:44 106-93-4 0.39 1 04/23/24 09:44 74-95-3 0.34 1 04/23/24 09:44 95-50-1 0.33 1 04/23/24 09:44 106-46-7 0.56 1 04/23/24 09:44 110-57-6 0.37 1 04/23/24 09:44 75-34-3 0.32 1 04/23/24 09:44 107-06-2 0.35 1 04/23/24 09:44 75-35-4 0.38 1 04/23/24 09:44 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 20 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-MW-8 Lab ID: 92726233008 Collected: 04/19/24 10:45 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/06/2024 03:30 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.40 1 04/23/24 09:44 156-60-5 ND ug/L 1.0 0.36 1 04/23/24 09:44 78-87-5 ND ug/L 1.0 0.36 1 04/23/24 09:44 10061-01-5 ND ug/L 1.0 0.36 1 04/23/24 09:44 10061-02-6 ND ug/L 1.0 0.30 1 04/23/24 09:44 100-41-4 ND ug/L 5.0 0.48 1 04/23/24 09:44 591-78-6 ND ug/L 20.0 9.7 1 04/23/24 09:44 74-88-4 v2 ND ug/L 5.0 2.0 1 04/23/24 09:44 75-09-2 ND ug/L 5.0 2.7 1 04/23/24 09:44 108-10-1 ND ug/L 1.0 0.29 1 04/23/24 09:44 100-42-5 ND ug/L 1.0 0.31 1 04/23/24 09:44 630-20-6 ND ug/L 1.0 0.22 1 04/23/24 09:44 79-34-5 ND ug/L 1.0 0.29 1 04/23/24 09:44 127-18-4 ND ug/L 1.0 0.24 1 04/23/24 09:44 108-88-3 ND ug/L 1.0 0.33 1 04/23/24 09:44 71-55-6 ND ug/L 1.0 0.32 1 04/23/24 09:44 79-00-5 ND ug/L 1.0 0.38 1 04/23/24 09:44 79-01-6 ND ug/L 1.0 0.30 1 04/23/24 09:44 75-69-4 ND ug/L 1.0 0.26 1 04/23/24 09:44 96-18-4 ND ug/L 2.0 1.3 1 04/23/24 09:44 108-05-4 ND ug/L 1.0 0.39 1 04/23/24 09:44 75-01-4 ND ug/L 1.0 0.34 1 04/23/24 09:44 1330-20-7 ND ug/L 2.0 0.71 1 04/23/24 09:44 179601-23-1 ND ug/L 1.0 0.34 1 04/23/24 09:44 95-47-6 96 % 70-130 1 04/23/24 09:44 460-00-4 105 % 70-130 1 04/23/24 09:44 17060-07-0 98 % 70-130 1 04/23/24 09:44 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-MW-9S Lab ID: 92726233009 Collected: 04/19/24 10:50 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic ND ug/L 20.0 4.9 2 04/25/24 13:05 05/01/24 00:46 7440-38-2 Barium 28.3 ug/L 10.0 1.6 2 04/25/24 13:05 05/01/24 00:46 7440-39-3 Cadmium ND ug/L 2.0 0.58 2 04/25/24 13:05 05/01/24 00:46 7440-43-9 Chromium ND ug/L 10.0 1.3 2 04/25/24 13:05 05/01/24 00:46 7440-47-3 Lead ND ug/L 10.0 2.7 2 04/25/24 13:05 05/01/24 00:46 7439-92-1 Selenium ND ug/L 50.0 20.6 5 04/25/24 13:05 05/01/2418:20 7782-49-2 Silver ND ug/L 10.0 0.98 2 04/25/24 13:05 05/01/24 00:46 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury ND ug/L 0.20 0.12 1 04/22/24 21:22 04/24/24 14:02 7439-97-6 VOA (GC/MS) 8260D-SIM Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM Pace National - Mt. Juliet 1,4-Dioxane (p-Dioxane) ND ug/L 3.00 0.597 1 04/28/24 21:35 04/28/24 21:35 123-91-1 Surrogates Toluene-d8 (S) 105 % 77.0-127 1 04/28/24 21:35 04/28/24 21:35 2037-26-5 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 04/23/24 10:02 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 04/23/24 10:02 107-13-1 Benzene ND ug/L 1.0 0.34 1 04/23/24 10:02 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 04/23/24 10:02 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 04/23/24 10:02 75-27-4 Bromoform ND ug/L 1.0 0.34 1 04/23/24 10:02 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 04/23/24 10:02 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 04/23/24 10:02 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 04/23/24 10:02 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 04/23/24 10:02 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 04/23/24 10:02 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 04/23/24 10:02 75-00-3 Chloroform ND ug/L 1.0 0.43 1 04/23/24 10:02 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 04/23/24 10:02 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 04/23/24 10:02 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 04/23/24 10:02 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 04/23/24 10:02 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 04/23/24 10:02 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 04/23/24 10:02 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 04/23/24 10:02 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 04/23/24 10:02 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 04/23/24 10:02 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 04/23/24 10:02 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 04/23/24 10:02 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 04/23/24 10:02 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/06/2024 03:30 PM without the written consent of Pace Analytical Services, LLC. D3 D3 D3 D3 D3 D3 v2 Page 22 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-MW-9S Lab ID: 92726233009 Collected: 04/19/24 10:50 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/06/2024 03:30 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.40 1 04/23/2410:02 156-60-5 ND ug/L 1.0 0.36 1 04/23/2410:02 78-87-5 ND ug/L 1.0 0.36 1 04/23/24 10:02 10061-01-5 ND ug/L 1.0 0.36 1 04/23/2410:02 10061-02-6 ND ug/L 1.0 0.30 1 04/23/2410:02 100-41-4 ND ug/L 5.0 0.48 1 04/23/2410:02 591-78-6 ND ug/L 20.0 9.7 1 04/23/2410:02 74-88-4 v2 ND ug/L 5.0 2.0 1 04/23/2410:02 75-09-2 ND ug/L 5.0 2.7 1 04/23/2410:02 108-10-1 ND ug/L 1.0 0.29 1 04/23/2410:02 100-42-5 ND ug/L 1.0 0.31 1 04/23/2410:02 630-20-6 ND ug/L 1.0 0.22 1 04/23/2410:02 79-34-5 ND ug/L 1.0 0.29 1 04/23/2410:02 127-18-4 ND ug/L 1.0 0.24 1 04/23/2410:02 108-88-3 ND ug/L 1.0 0.33 1 04/23/2410:02 71-55-6 ND ug/L 1.0 0.32 1 04/23/2410:02 79-00-5 ND ug/L 1.0 0.38 1 04/23/2410:02 79-01-6 ND ug/L 1.0 0.30 1 04/23/2410:02 75-69-4 ND ug/L 1.0 0.26 1 04/23/2410:02 96-18-4 ND ug/L 2.0 1.3 1 04/23/2410:02 108-05-4 ND ug/L 1.0 0.39 1 04/23/2410:02 75-01-4 ND ug/L 1.0 0.34 1 04/23/2410:02 1330-20-7 ND ug/L 2.0 0.71 1 04/23/2410:02 179601-23-1 ND ug/L 1.0 0.34 1 04/23/2410:02 95-47-6 91 % 70-130 1 04/23/2410:02 460-00-4 105 % 70-130 1 04/23/2410:02 17060-07-0 100 % 70-130 1 04/23/2410:02 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-MW-9D Lab ID: 92726233010 Collected: 04/19/24 12:00 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic ND ug/L 20.0 4.9 2 04/25/24 13:05 05/01/24 00:49 7440-38-2 Barium 25.3 ug/L 10.0 1.6 2 04/25/24 13:05 05/01/24 00:49 7440-39-3 Cadmium ND ug/L 2.0 0.58 2 04/25/24 13:05 05/01/24 00:49 7440-43-9 Chromium ND ug/L 10.0 1.3 2 04/25/24 13:05 05/01/24 00:49 7440-47-3 Lead ND ug/L 10.0 2.7 2 04/25/24 13:05 05/01/24 00:49 7439-92-1 Selenium ND ug/L 50.0 20.6 5 04/25/24 13:05 05/01/2418:23 7782-49-2 Silver ND ug/L 10.0 0.98 2 04/25/24 13:05 05/01/24 00:49 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury ND ug/L 0.20 0.12 1 04/22/24 21:22 04/24/24 14:04 7439-97-6 VOA (GC/MS) 8260D-SIM Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM Pace National - Mt. Juliet 1,4-Dioxane (p-Dioxane) ND ug/L 3.00 0.597 1 04/29/24 13:12 04/29/24 13:12 123-91-1 Surrogates Toluene-d8 (S) 103 % 77.0-127 1 04/29/24 13:12 04/29/24 13:12 2037-26-5 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 04/23/24 10:20 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 04/23/24 10:20 107-13-1 Benzene ND ug/L 1.0 0.34 1 04/23/24 10:20 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 04/23/24 10:20 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 04/23/24 10:20 75-27-4 Bromoform ND ug/L 1.0 0.34 1 04/23/24 10:20 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 04/23/24 10:20 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 04/23/24 10:20 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 04/23/24 10:20 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 04/23/24 10:20 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 04/23/24 10:20 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 04/23/24 10:20 75-00-3 Chloroform ND ug/L 1.0 0.43 1 04/23/24 10:20 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 04/23/24 10:20 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 04/23/24 10:20 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 04/23/24 10:20 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 04/23/24 10:20 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 04/23/24 10:20 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 04/23/24 10:20 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 04/23/24 10:20 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 04/23/24 10:20 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 04/23/24 10:20 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 04/23/24 10:20 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 04/23/24 10:20 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 04/23/24 10:20 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/06/2024 03:30 PM without the written consent of Pace Analytical Services, LLC. D3 D3 D3 D3 D3 D3 v2 Page 24 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-MW-9D Lab ID: 92726233010 Collected: 04/19/24 12:00 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/06/2024 03:30 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.40 1 04/23/2410:20 156-60-5 ND ug/L 1.0 0.36 1 04/23/2410:20 78-87-5 ND ug/L 1.0 0.36 1 04/23/24 10:20 10061-01-5 ND ug/L 1.0 0.36 1 04/23/2410:20 10061-02-6 ND ug/L 1.0 0.30 1 04/23/2410:20 100-41-4 ND ug/L 5.0 0.48 1 04/23/2410:20 591-78-6 ND ug/L 20.0 9.7 1 04/23/2410:20 74-88-4 v2 ND ug/L 5.0 2.0 1 04/23/2410:20 75-09-2 ND ug/L 5.0 2.7 1 04/23/2410:20 108-10-1 ND ug/L 1.0 0.29 1 04/23/2410:20 100-42-5 ND ug/L 1.0 0.31 1 04/23/2410:20 630-20-6 ND ug/L 1.0 0.22 1 04/23/2410:20 79-34-5 ND ug/L 1.0 0.29 1 04/23/2410:20 127-18-4 ND ug/L 1.0 0.24 1 04/23/2410:20 108-88-3 ND ug/L 1.0 0.33 1 04/23/2410:20 71-55-6 ND ug/L 1.0 0.32 1 04/23/2410:20 79-00-5 ND ug/L 1.0 0.38 1 04/23/2410:20 79-01-6 ND ug/L 1.0 0.30 1 04/23/2410:20 75-69-4 ND ug/L 1.0 0.26 1 04/23/2410:20 96-18-4 ND ug/L 2.0 1.3 1 04/23/2410:20 108-05-4 ND ug/L 1.0 0.39 1 04/23/2410:20 75-01-4 ND ug/L 1.0 0.34 1 04/23/2410:20 1330-20-7 ND ug/L 2.0 0.71 1 04/23/2410:20 179601-23-1 ND ug/L 1.0 0.34 1 04/23/2410:20 95-47-6 93 % 70-130 1 04/23/2410:20 460-00-4 103 % 70-130 1 04/23/2410:20 17060-07-0 101 % 70-130 1 04/23/2410:20 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 25 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-SW-1 Lab ID: 92726233011 Collected: 04/19/24 12:40 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic ND ug/L 20.0 4.9 2 04/25/24 13:05 05/01/24 00:51 7440-38-2 D3 Barium 39.8 ug/L 10.0 1.6 2 04/25/24 13:05 05/01/24 00:51 7440-39-3 Cadmium ND ug/L 2.0 0.58 2 04/25/24 13:05 05/01/24 00:51 7440-43-9 D3 Chromium 2AJ ug/L 10.0 1.3 2 04/25/24 13:05 05/01/24 00:51 7440-47-3 Lead ND ug/L 10.0 2.7 2 04/25/24 13:05 05/01/24 00:51 7439-92-1 D3 Selenium ND ug/L 50.0 20.6 5 04/25/24 13:05 05/01/2418:26 7782-49-2 D3 Silver ND ug/L 10.0 0.98 2 04/25/24 13:05 05/01/24 00:51 7440-22-4 D3 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury ND ug/L 0.20 0.12 1 04/22/24 21:22 04/24/24 14:06 7439-97-6 VOA (GC/MS) 8260D-SIM Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM Pace National - Mt. Juliet 1,4-Dioxane (p-Dioxane) ND ug/L 3.00 0.597 1 04/29/24 13:34 04/29/24 13:34 123-91-1 Surrogates Toluene-d8 (S) 102 % 77.0-127 1 04/29/24 13:34 04/29/24 13:34 2037-26-5 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 04/23/24 10:37 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 04/23/24 10:37 107-13-1 Benzene ND ug/L 1.0 0.34 1 04/23/24 10:37 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 04/23/24 10:37 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 04/23/24 10:37 75-27-4 Bromoform ND ug/L 1.0 0.34 1 04/23/24 10:37 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 04/23/24 10:37 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 04/23/24 10:37 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 04/23/24 10:37 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 04/23/24 10:37 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 04/23/24 10:37 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 04/23/24 10:37 75-00-3 Chloroform ND ug/L 1.0 0.43 1 04/23/24 10:37 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 04/23/24 10:37 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 04/23/24 10:37 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 04/23/24 10:37 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 04/23/24 10:37 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 04/23/24 10:37 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 04/23/24 10:37 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 04/23/24 10:37 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 04/23/24 10:37 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 04/23/24 10:37 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 04/23/24 10:37 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 04/23/24 10:37 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 04/23/24 10:37 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/06/2024 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-SW-1 Lab ID: 92726233011 Collected: 04/19/24 12:40 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/06/2024 03:30 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.40 1 04/23/2410:37 156-60-5 ND ug/L 1.0 0.36 1 04/23/2410:37 78-87-5 ND ug/L 1.0 0.36 1 04/23/24 10:37 10061-01-5 ND ug/L 1.0 0.36 1 04/23/2410:37 10061-02-6 ND ug/L 1.0 0.30 1 04/23/2410:37 100-41-4 ND ug/L 5.0 0.48 1 04/23/2410:37 591-78-6 ND ug/L 20.0 9.7 1 04/23/2410:37 74-88-4 ND ug/L 5.0 2.0 1 04/23/2410:37 75-09-2 ND ug/L 5.0 2.7 1 04/23/2410:37 108-10-1 ND ug/L 1.0 0.29 1 04/23/2410:37 100-42-5 ND ug/L 1.0 0.31 1 04/23/2410:37 630-20-6 ND ug/L 1.0 0.22 1 04/23/2410:37 79-34-5 ND ug/L 1.0 0.29 1 04/23/2410:37 127-18-4 ND ug/L 1.0 0.24 1 04/23/2410:37 108-88-3 ND ug/L 1.0 0.33 1 04/23/2410:37 71-55-6 ND ug/L 1.0 0.32 1 04/23/2410:37 79-00-5 ND ug/L 1.0 0.38 1 04/23/2410:37 79-01-6 ND ug/L 1.0 0.30 1 04/23/2410:37 75-69-4 ND ug/L 1.0 0.26 1 04/23/2410:37 96-18-4 ND ug/L 2.0 1.3 1 04/23/2410:37 108-05-4 ND ug/L 1.0 0.39 1 04/23/2410:37 75-01-4 ND ug/L 1.0 0.34 1 04/23/2410:37 1330-20-7 ND ug/L 2.0 0.71 1 04/23/2410:37 179601-23-1 ND ug/L 1.0 0.34 1 04/23/2410:37 95-47-6 94 % 70-130 1 04/23/2410:37 460-00-4 110 % 70-130 1 04/23/2410:37 17060-07-0 98 % 70-130 1 04/23/2410:37 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-SW-2 Lab ID: 92726233012 Collected: 04/19/24 10:20 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic ND ug/L 20.0 4.9 2 04/25/24 13:05 05/01/24 01:00 7440-38-2 D3 Barium 30.8 ug/L 10.0 1.6 2 04/25/24 13:05 05/01/24 01:00 7440-39-3 Cadmium ND ug/L 2.0 0.58 2 04/25/24 13:05 05/01/24 01:00 7440-43-9 D3 Chromium ND ug/L 10.0 1.3 2 04/25/24 13:05 05/01/24 01:00 7440-47-3 D3 Lead ND ug/L 10.0 2.7 2 04/25/24 13:05 05/01/24 01:00 7439-92-1 D3 Selenium ND ug/L 50.0 20.6 5 04/25/24 13:05 05/01/2418:29 7782-49-2 D3 Silver ND ug/L 10.0 0.98 2 04/25/24 13:05 05/01/24 01:00 7440-22-4 D3 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury ND ug/L 0.20 0.12 1 04/22/24 21:22 04/24/24 14:08 7439-97-6 VOA (GC/MS) 8260D-SIM Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM Pace National - Mt. Juliet 1,4-Dioxane (p-Dioxane) ND ug/L 3.00 0.597 1 04/29/24 13:56 04/29/24 13:56 123-91-1 Surrogates Toluene-d8 (S) 102 % 77.0-127 1 04/29/24 13:56 04/29/24 13:56 2037-26-5 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 04/23/24 10:55 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 04/23/24 10:55 107-13-1 Benzene ND ug/L 1.0 0.34 1 04/23/24 10:55 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 04/23/24 10:55 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 04/23/24 10:55 75-27-4 Bromoform ND ug/L 1.0 0.34 1 04/23/24 10:55 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 04/23/24 10:55 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 04/23/24 10:55 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 04/23/24 10:55 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 04/23/24 10:55 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 04/23/24 10:55 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 04/23/24 10:55 75-00-3 Chloroform ND ug/L 1.0 0.43 1 04/23/24 10:55 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 04/23/24 10:55 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 04/23/24 10:55 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 04/23/24 10:55 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 04/23/24 10:55 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 04/23/24 10:55 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 04/23/24 10:55 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 04/23/24 10:55 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 04/23/24 10:55 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 04/23/24 10:55 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 04/23/24 10:55 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 04/23/24 10:55 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 04/23/24 10:55 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/06/2024 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-SW-2 Lab ID: 92726233012 Collected: 04/19/24 10:20 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/06/2024 03:30 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.40 1 04/23/2410:55 156-60-5 ND ug/L 1.0 0.36 1 04/23/2410:55 78-87-5 ND ug/L 1.0 0.36 1 04/23/24 10:55 10061-01-5 ND ug/L 1.0 0.36 1 04/23/2410:55 10061-02-6 ND ug/L 1.0 0.30 1 04/23/2410:55 100-41-4 ND ug/L 5.0 0.48 1 04/23/2410:55 591-78-6 ND ug/L 20.0 9.7 1 04/23/2410:55 74-88-4 ND ug/L 5.0 2.0 1 04/23/2410:55 75-09-2 ND ug/L 5.0 2.7 1 04/23/2410:55 108-10-1 ND ug/L 1.0 0.29 1 04/23/2410:55 100-42-5 ND ug/L 1.0 0.31 1 04/23/2410:55 630-20-6 ND ug/L 1.0 0.22 1 04/23/2410:55 79-34-5 ND ug/L 1.0 0.29 1 04/23/2410:55 127-18-4 ND ug/L 1.0 0.24 1 04/23/2410:55 108-88-3 ND ug/L 1.0 0.33 1 04/23/2410:55 71-55-6 ND ug/L 1.0 0.32 1 04/23/2410:55 79-00-5 ND ug/L 1.0 0.38 1 04/23/2410:55 79-01-6 ND ug/L 1.0 0.30 1 04/23/2410:55 75-69-4 ND ug/L 1.0 0.26 1 04/23/2410:55 96-18-4 ND ug/L 2.0 1.3 1 04/23/2410:55 108-05-4 ND ug/L 1.0 0.39 1 04/23/2410:55 75-01-4 ND ug/L 1.0 0.34 1 04/23/2410:55 1330-20-7 ND ug/L 2.0 0.71 1 04/23/2410:55 179601-23-1 ND ug/L 1.0 0.34 1 04/23/2410:55 95-47-6 95 % 70-130 1 04/23/2410:55 460-00-4 107 % 70-130 1 04/23/2410:55 17060-07-0 99 % 70-130 1 04/23/2410:55 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 29 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-Duplicate Lab ID: 92726233013 Collected: 04/19/24 10:50 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Date: 05/06/2024 03:30 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 5.1 1 04/23/2411:13 67-64-1 ND ug/L 10.0 1.8 1 04/23/2411:13 107-13-1 ND ug/L 1.0 0.34 1 04/23/2411:13 71-43-2 ND ug/L 1.0 0.47 1 04/23/2411:13 74-97-5 ND ug/L 1.0 0.31 1 04/23/2411:13 75-27-4 ND ug/L 1.0 0.34 1 04/23/2411:13 75-25-2 ND ug/L 2.0 1.7 1 04/23/2411:13 74-83-9 ND ug/L 5.0 4.0 1 04/23/2411:13 78-93-3 ND ug/L 2.0 0.36 1 04/23/2411:13 75-15-0 ND ug/L 1.0 0.33 1 04/23/2411:13 56-23-5 ND ug/L 1.0 0.28 1 04/23/2411:13 108-90-7 ND ug/L 1.0 0.65 1 04/23/2411:13 75-00-3 ND ug/L 1.0 0.43 1 04/23/2411:13 67-66-3 ND ug/L 1.0 0.54 1 04/23/2411:13 74-87-3 ND ug/L 2.0 0.34 1 04/23/2411:13 96-12-8 ND ug/L 1.0 0.36 1 04/23/2411:13 124-48-1 ND ug/L 1.0 0.27 1 04/23/2411:13 106-93-4 ND ug/L 1.0 0.39 1 04/23/2411:13 74-95-3 ND ug/L 1.0 0.34 1 04/23/2411:13 95-50-1 ND ug/L 1.0 0.33 1 04/23/2411:13 106-46-7 ND ug/L 1.0 0.56 1 04/23/2411:13 110-57-6 ND ug/L 1.0 0.37 1 04/23/2411:13 75-34-3 ND ug/L 1.0 0.32 1 04/23/2411:13 107-06-2 ND ug/L 1.0 0.35 1 04/23/2411:13 75-35-4 ND ug/L 1.0 0.38 1 04/23/2411:13 156-59-2 ND ug/L 1.0 0.40 1 04/23/2411:13 156-60-5 ND ug/L 1.0 0.36 1 04/23/2411:13 78-87-5 ND ug/L 1.0 0.36 1 04/23/24 11:13 10061-01-5 ND ug/L 1.0 0.36 1 04/23/2411:13 10061-02-6 ND ug/L 1.0 0.30 1 04/23/2411:13 100-41-4 ND ug/L 5.0 0.48 1 04/23/2411:13 591-78-6 ND ug/L 20.0 9.7 1 04/23/2411:13 74-88-4 ND ug/L 5.0 2.0 1 04/23/2411:13 75-09-2 ND ug/L 5.0 2.7 1 04/23/2411:13 108-10-1 ND ug/L 1.0 0.29 1 04/23/2411:13 100-42-5 ND ug/L 1.0 0.31 1 04/23/2411:13 630-20-6 ND ug/L 1.0 0.22 1 04/23/2411:13 79-34-5 ND ug/L 1.0 0.29 1 04/23/2411:13 127-18-4 ND ug/L 1.0 0.24 1 04/23/2411:13 108-88-3 ND ug/L 1.0 0.33 1 04/23/2411:13 71-55-6 ND ug/L 1.0 0.32 1 04/23/2411:13 79-00-5 ND ug/L 1.0 0.38 1 04/23/2411:13 79-01-6 ND ug/L 1.0 0.30 1 04/23/2411:13 75-69-4 ND ug/L 1.0 0.26 1 04/23/2411:13 96-18-4 ND ug/L 2.0 1.3 1 04/23/2411:13 108-05-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 30 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Sample: 8102-Duplicate Parameters Lab ID: Results 92726233013 Units Collected: Report Limit 04/19/24 10:50 MDL DF Received: 04/19/24 16:00 Matrix: Water Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Vinyl chloride ND ug/L 1.0 0.39 1 04/23/24 11:13 75-01-4 Xylene (Total) ND ug/L 1.0 0.34 1 04/23/24 11:13 1330-20-7 m&p-Xylene ND ug/L 2.0 0.71 1 04/23/24 11:13 179601-23-1 o-Xylene ND ug/L 1.0 0.34 1 04/23/24 11:13 95-47-6 Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 1 04/23/24 11:13 460-00-4 1,2-Dichloroethane-d4 (S) 108 % 70-130 1 04/23/24 11:13 17060-07-0 Toluene-d8 (S) 98 % 70-130 1 04/23/24 11:13 2037-26-5 Date: 05/06/2024 03:30 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 31 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 QC Batch: 848920 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92726233001, 92726233002, 92726233003, 92726233004, 92726233005, 92726233006, 92726233007, 92726233008,92726233009,92726233010,92726233011,92726233012 METHOD BLANK: 4382301 Matrix: Water Associated Lab Samples: 92726233001, 92726233002, 92726233003, 92726233004, 92726233005, 92726233006, 92726233007, 92726233008,92726233009,92726233010,92726233011,92726233012 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.20 0.12 04/24/2413:12 LABORATORY CONTROL SAMPLE: 4382302 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.4 97 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4382303 4382304 MS MSD 92726144001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.6 2.5 102 99 75-125 3 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/06/2024 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 QC Batch: 849754 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92726233001, 92726233002, 92726233003, 92726233004, 92726233005, 92726233006, 92726233007 METHOD BLANK: 4386242 Matrix: Water Associated Lab Samples: 92726233001, 92726233002, 92726233003, 92726233004, 92726233005, 92726233006, 92726233007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic ug/L ND 10.0 2.5 04/29/24 20:14 Cadmium ug/L ND 1.0 0.29 04/29/24 20:14 Chromium ug/L ND 5.0 0.63 04/29/24 20:14 Lead ug/L ND 5.0 1.4 04/29/24 20:14 Selenium ug/L ND 10.0 4.1 04/29/24 20:14 Silver ug/L ND 5.0 0.49 04/29/24 20:14 LABORATORY CONTROL SAMPLE: 4386243 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic ug/L 500 517 103 80-120 Cadmium ug/L 500 529 106 80-120 Chromium ug/L 500 510 102 80-120 Lead ug/L 500 519 104 80-120 Selenium ug/L 500 497 99 80-120 Silver ug/L 250 246 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4386244 4386245 MS MSD 92726494001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L ND 500 500 525 535 103 106 75-125 2 20 Cadmium ug/L ND 500 500 485 491 97 98 75-125 1 20 Chromium ug/L ND 500 500 485 493 97 99 75-125 2 20 Lead ug/L ND 500 500 474 481 95 96 75-125 1 20 Selenium ug/L ND 500 500 506 514 101 103 75-125 1 20 Silver ug/L ND 250 250 257 261 103 105 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/06/2024 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 QC Batch: 849757 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92726233008, 92726233009, 92726233010, 92726233011, 92726233012 METHOD BLANK: 4386261 Matrix: Water Associated Lab Samples: 92726233008, 92726233009, 92726233010, 92726233011, 92726233012 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic ug/L ND 10.0 2.5 05/01/24 00:29 Barium ug/L ND 5.0 0.79 05/01/24 00:29 Cadmium ug/L ND 1.0 0.29 05/01/24 00:29 Chromium ug/L ND 5.0 0.63 05/01/24 00:29 Lead ug/L ND 5.0 1.4 05/01/24 00:29 Selenium ug/L ND 10.0 4.1 04/29/24 21:51 Silver ug/L ND 5.0 0.49 05/01/24 00:29 LABORATORY CONTROL SAMPLE: 4386262 Parameter Units Arsenic ug/L Barium ug/L Cadmium ug/L Chromium ug/L Lead ug/L Selenium ug/L Silver ug/L Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 500 463 93 80-120 500 484 97 80-120 500 468 94 80-120 500 473 95 80-120 500 468 94 80-120 500 503 101 80-120 250 234 94 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4386263 4386264 MS MSD 92726233008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L ND 500 500 516 507 103 101 75-125 2 20 Barium ug/L 118 500 500 627 604 102 97 75-125 4 20 Cadmium ug/L ND 500 500 523 510 104 102 75-125 3 20 Chromium ug/L ND 500 500 508 521 101 104 75-125 3 20 Lead ug/L 1.7J 500 500 509 505 102 101 75-125 1 20 Selenium ug/L ND 500 500 526 532 105 106 75-125 1 20 1g Silver ug/L ND 250 250 249 258 99 103 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/06/2024 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 QC Batch: 851965 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92726233001, 92726233002, 92726233003, 92726233004, 92726233005, 92726233006, 92726233007 METHOD BLANK: 4397354 Matrix: Water Associated Lab Samples: 92726233001, 92726233002, 92726233003, 92726233004, 92726233005, 92726233006, 92726233007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Barium ug/L ND 5.0 0.79 05/05/2416:42 LABORATORY CONTROL SAMPLE: 4397355 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Barium ug/L 500 478 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4397356 4397357 MS MSD 92726233001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Barium ug/L 30.9 500 500 543 533 102 100 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/06/2024 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 QC Batch: 2273876 Analysis Method: EPA 8260D by SIM QC Batch Method: 8260B-SIM Analysis Description: VOA (GC/MS) 8260D-SIM Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92726233001, 92726233002 METHOD BLANK: R4063445-3 Matrix: Water Associated Lab Samples: 92726233001, 92726233002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 3.00 0.597 04/26/24 19:29 Toluene-d8 (S) % 101 77.0-127 04/26/24 19:29 LABORATORY CONTROL SAMPLE & LCSD: R4063445-1 R4063445-2 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 50.0 48.4 44.2 96.8 88.4 55.0-138 9.07 24 Toluene-d8 (S) % 101 101 77.0-127 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/06/2024 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 QC Batch: 2276134 Analysis Method: EPA 8260D by SIM QC Batch Method: 8260B-SIM Analysis Description: VOA (GC/MS) 8260D-SIM Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92726233004, 92726233005, 92726233006, 92726233007, 92726233008, 92726233009 METHOD BLANK: R4063449-3 Matrix: Water Associated Lab Samples: 92726233004, 92726233005, 92726233006, 92726233007, 92726233008, 92726233009 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 3.00 0.597 04/28/24 13:09 Toluene-d8 (S) % 102 77.0-127 04/28/24 13:09 LABORATORY CONTROL SAMPLE & LCSD: R4063449-1 R4063449-2 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 50.0 38.8 43.4 77.6 86.8 55.0-138 11.2 24 Toluene-d8 (S) % 102 102 77.0-127 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/06/2024 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 QC Batch: 2276408 Analysis Method: EPA 8260D by SIM QC Batch Method: 8260B-SIM Analysis Description: VOA (GC/MS) 8260D-SIM Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92726233010, 92726233011, 92726233012 METHOD BLANK: R4063971-3 Matrix: Water Associated Lab Samples: 92726233010, 92726233011, 92726233012 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 3.00 0.597 04/29/24 12:06 Toluene-d8 (S) % 102 77.0-127 04/29/24 12:06 LABORATORY CONTROL SAMPLE & LCSD: R4063971-1 R4063971-2 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 50.0 41.1 43.3 82.2 86.6 55.0-138 5.21 24 Toluene-d8 (S) % 105 102 77.0-127 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/06/2024 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 QC Batch: 2276747 Analysis Method: EPA 8260D by SIM QC Batch Method: 8260B-SIM Analysis Description: VOA (GC/MS) 8260D-SIM Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92726233003 METHOD BLANK: R4063972-3 Matrix: Water Associated Lab Samples: 92726233003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 3.00 0.597 04/29/24 22:40 Toluene-d8 (S) % 104 77.0-127 04/29/24 22:40 LABORATORY CONTROL SAMPLE & LCSD: R4063972-1 R4063972-2 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 50.0 43.2 42.4 86.4 84.8 55.0-138 1.87 24 Toluene-d8 (S) % 103 103 77.0-127 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/06/2024 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 39 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 QC Batch: 848859 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92726233001, 92726233002, 92726233003, 92726233004, 92726233005, 92726233006, 92726233007, 92726233008,92726233009,92726233010,92726233011,92726233012,92726233013 METHOD BLANK: 4382100 Matrix: Water Associated Lab Samples: 92726233001, 92726233002, 92726233003, 92726233004, 92726233005, 92726233006, 92726233007, 92726233008,92726233009,92726233010,92726233011,92726233012,92726233013 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 04/23/24 07:23 1,1,1-Trichloroethane ug/L ND 1.0 0.33 04/23/24 07:23 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 04/23/24 07:23 1,1,2-Trichloroethane ug/L ND 1.0 0.32 04/23/24 07:23 1,1-Dichloroethane ug/L ND 1.0 0.37 04/23/24 07:23 1,1-Dichloroethene ug/L ND 1.0 0.35 04/23/24 07:23 1,2,3-Trichloropropane ug/L ND 1.0 0.26 04/23/24 07:23 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 04/23/24 07:23 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 04/23/24 07:23 1,2-Dichlorobenzene ug/L ND 1.0 0.34 04/23/24 07:23 1,2-Dichloroethane ug/L ND 1.0 0.32 04/23/24 07:23 1,2-Dichloropropane ug/L ND 1.0 0.36 04/23/24 07:23 1,4-Dichlorobenzene ug/L ND 1.0 0.33 04/23/24 07:23 2-Butanone (MEK) ug/L ND 5.0 4.0 04/23/24 07:23 2-Hexanone ug/L ND 5.0 0.48 04/23/24 07:23 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 04/23/24 07:23 Acetone ug/L ND 25.0 5.1 04/23/24 07:23 Acrylonitrile ug/L ND 10.0 1.8 04/23/24 07:23 Benzene ug/L ND 1.0 0.34 04/23/24 07:23 Bromochloromethane ug/L ND 1.0 0.47 04/23/24 07:23 Bromodichloromethane ug/L ND 1.0 0.31 04/23/24 07:23 Bromoform ug/L ND 1.0 0.34 04/23/24 07:23 Bromomethane ug/L ND 2.0 1.7 04/23/24 07:23 Carbon disulfide ug/L ND 2.0 0.36 04/23/24 07:23 Carbon tetrachloride ug/L ND 1.0 0.33 04/23/24 07:23 Chlorobenzene ug/L ND 1.0 0.28 04/23/24 07:23 Chloroethane ug/L ND 1.0 0.65 04/23/24 07:23 Chloroform ug/L ND 1.0 0.43 04/23/24 07:23 Chloromethane ug/L ND 1.0 0.54 04/23/24 07:23 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 04/23/24 07:23 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 04/23/24 07:23 Dibromochloromethane ug/L ND 1.0 0.36 04/23/24 07:23 Dibromomethane ug/L ND 1.0 0.39 04/23/24 07:23 Ethylbenzene ug/L ND 1.0 0.30 04/23/24 07:23 lodomethane ug/L ND 20.0 9.7 04/23/24 07:23 m&p-Xylene ug/L ND 2.0 0.71 04/23/24 07:23 Methylene Chloride ug/L ND 5.0 2.0 04/23/24 07:23 o-Xylene ug/L ND 1.0 0.34 04/23/24 07:23 Styrene ug/L ND 1.0 0.29 04/23/24 07:23 v2 v2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/06/2024 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 METHOD BLANK: 4382100 Matrix: Water Associated Lab Samples: 92726233001, 92726233002, 92726233003, 92726233004, 92726233005, 92726233006, 92726233007, 92726233008,92726233009,92726233010,92726233011,92726233012,92726233013 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Tetrachloroethene ug/L ND 1.0 0.29 04/23/24 07:23 Toluene ug/L ND 1.0 0.24 04/23/24 07:23 trans-1,2-Dichloroethene ug/L ND 1.0 0.40 04/23/24 07:23 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 04/23/24 07:23 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 04/23/24 07:23 Trichloroethene ug/L ND 1.0 0.38 04/23/24 07:23 Trichlorofluoromethane ug/L ND 1.0 0.30 04/23/24 07:23 Vinyl acetate ug/L ND 2.0 1.3 04/23/24 07:23 Vinyl chloride ug/L ND 1.0 0.39 04/23/24 07:23 Xylene (Total) ug/L ND 1.0 0.34 04/23/24 07:23 1,2-Dichloroethane-d4 (S) % 104 70-130 04/23/24 07:23 4-Bromofluorobenzene (S) % 96 70-130 04/23/24 07:23 Toluene-d8 (S) % 99 70-130 04/23/24 07:23 LABORATORY CONTROL SAMPLE: Parameter 4382101 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 20 21.7 108 70-130 1,1,1-Trichloroethane ug/L 20 20.2 101 70-130 1,1,2,2-Tetrachloroethane ug/L 20 21.2 106 70-130 1,1,2-Trichloroethane ug/L 20 21.0 105 70-130 1,1-Dichloroethane ug/L 20 20.7 103 70-130 1,1-Dichloroethene ug/L 20 21.3 107 69-131 1,2,3-Trichloropropane ug/L 20 21.1 105 70-130 1,2-Dibromo-3-chloropropane ug/L 20 21.3 107 70-130 1,2-Dibromoethane (EDB) ug/L 20 21.5 108 70-130 1,2-Dichlorobenzene ug/L 20 21.8 109 70-130 1,2-Dichloroethane ug/L 20 19.8 99 70-130 1,2-Dichloropropane ug/L 20 21.2 106 70-130 1,4-Dichlorobenzene ug/L 20 20.9 104 70-130 2-Butanone (MEK) ug/L 40 39.9 100 67-133 2-Hexanone ug/L 40 40.3 101 70-133 4-Methyl-2-pentanone (MIBK) ug/L 40 39.8 100 70-130 Acetone ug/L 40 40.6 101 67-130 Acrylonitrile ug/L 100 102 102 70-130 Benzene ug/L 20 21.0 105 70-130 Bromochloromethane ug/L 20 20.6 103 70-130 Bromodichloromethane ug/L 20 21.9 110 70-130 Bromoform ug/L 20 20.5 103 70-133 Bromomethane ug/L 20 14.6 73 41-148 v3 Carbon disulfide ug/L 20 20.2 101 70-131 Carbon tetrachloride ug/L 20 20.0 100 70-130 Chlorobenzene ug/L 20 20.6 103 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/06/2024 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 LABORATORY CONTROL SAMPLE: Parameter 4382101 Units Spike LCS Conc. Result Chloroethane ug/L 20 Chloroform ug/L 20 Chloromethane ug/L 20 cis-1,2-Dichloroethene ug/L 20 cis-1,3-Dichloropropene ug/L 20 Dibromochloromethane ug/L 20 Dibromomethane ug/L 20 Ethylbenzene ug/L 20 lodomethane ug/L 40 m&p-Xylene ug/L 40 Methylene Chloride ug/L 20 o-Xylene ug/L 20 Styrene ug/L 20 Tetrachloroethene ug/L 20 Toluene ug/L 20 trans-1,2-Dichloroethene ug/L 20 trans- 1,3-Dichloropropene ug/L 20 trans-1,4-Dichloro-2-butene ug/L 20 Trichloroethene ug/L 20 Trichlorofluoromethane ug/L 20 Vinyl acetate ug/L 40 Vinyl chloride ug/L 20 Xylene (Total) ug/L 60 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % LCS % Rec % Rec Limits Qualifiers 18.9 95 41-157 19.4 97 70-130 20.2 101 59-141 20.6 103 70-130 21.3 107 70-130 21.4 107 70-130 19.8 99 70-130 20.9 104 70-130 30.1 75 57-140 v3 42.1 105 70-130 21.0 105 62-130 21.1 106 70-130 21.8 109 70-130 21.5 108 70-130 20.1 101 70-130 21.5 107 70-130 21.5 108 70-130 17.6 88 57-149 21.4 107 70-130 18.3 91 57-130 42.1 105 70-141 20.4 102 66-140 63.2 105 70-130 97 70-130 96 70-130 100 70-130 MATRIX SPIKE SAMPLE: Parameter 4382102 Units 92726233001 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 23.9 120 70-146 1,1,1-Trichloroethane ug/L ND 20 24.6 123 70-150 1,1,2,2-Tetrachloroethane ug/L ND 20 23.1 115 66-144 1,1,2-Trichloroethane ug/L ND 20 23.3 117 70-142 1,1-Dichloroethane ug/L ND 20 23.4 117 68-150 1,1-Dichloroethene ug/L ND 20 25.8 129 64-162 1,2,3-Trichloropropane ug/L ND 20 22.9 115 66-144 1,2-Dibromo-3-chloropropane ug/L ND 20 22.3 111 62-146 1,2-Dibromoethane (EDB) ug/L ND 20 23.4 117 70-143 1,2-Dichlorobenzene ug/L ND 20 22.8 114 70-142 1,2-Dichloroethane ug/L ND 20 21.7 108 68-145 1,2-Dichloropropane ug/L ND 20 23.1 116 70-144 1,4-Dichlorobenzene ug/L ND 20 22.3 112 70-140 2-Butanone (MEK) ug/L ND 40 50.3 126 57-156 2-Hexanone ug/L ND 40 45.2 113 62-153 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/06/2024 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 42 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 MATRIX SPIKE SAMPLE: Parameter 4382102 Units 92726233001 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 4-Methyl-2-pentanone (MIBK) ug/L ND 40 43.3 108 65-144 Acetone ug/L ND 40 48.4 121 49-162 Acrylonitrile ug/L ND 100 122 122 59-155 Benzene ug/L ND 20 23.4 117 68-144 Bromochloromethane ug/L ND 20 23.9 119 70-148 Bromodichloromethane ug/L ND 20 23.6 118 70-141 Bromoform ug/L ND 20 22.0 110 59-144 Bromomethane ug/L ND 20 18.8 94 23-190 v3 Carbon disulfide ug/L ND 20 23.7 119 64-160 Carbon tetrachloride ug/L ND 20 22.8 114 70-147 Chlorobenzene ug/L ND 20 22.7 114 70-143 Chloroethane ug/L ND 20 23.5 118 55-190 Chloroform ug/L ND 20 23.5 118 67-148 Chloromethane ug/L ND 20 25.2 126 38-180 cis-1,2-Dichloroethene ug/L ND 20 24.1 121 67-151 cis-1,3-Dichloropropene ug/L ND 20 23.4 117 70-142 Dibromochloromethane ug/L ND 20 24.3 121 68-140 Dibromomethane ug/L ND 20 22.4 112 70-142 Ethylbenzene ug/L ND 20 22.9 115 70-145 lodomethane ug/L ND 40 42.2 106 37-160 v3 m&p-Xylene ug/L ND 40 45.0 112 70-148 Methylene Chloride ug/L ND 20 22.9 115 54-149 o-Xylene ug/L ND 20 23.4 117 70-145 Styrene ug/L ND 20 23.3 117 70-147 Tetrachloroethene ug/L ND 20 22.4 112 70-145 Toluene ug/L ND 20 22.1 111 65-146 trans-1,2-Dichloroethene ug/L ND 20 25.3 127 69-155 trans- 1,3-Dichloropropene ug/L ND 20 22.8 114 70-142 trans-1,4-Dichloro-2-butene ug/L ND 20 17.7 89 39-149 Trichloroethene ug/L ND 20 23.3 117 70-152 Trichlorofluoromethane ug/L ND 20 23.7 118 60-158 Vinyl acetate ug/L ND 40 43.9 110 56-157 Vinyl chloride ug/L ND 20 25.1 125 51-178 Xylene (Total) ug/L ND 60 68.4 114 70-146 1,2-Dichloroethane-d4 (S) % 94 70-130 4-Bromofluorobenzene (S) % 94 70-130 Toluene-d8 (S) % 98 70-130 SAMPLE DUPLICATE: 4382103 92726233002 Dup Max Parameter Units Result Result RPD RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/06/2024 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 43 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 SAMPLE DUPLICATE: 4382103 92726233002 Dup Max Parameter Units Result Result RPD RPD Qualifiers 1,1-Dichloroethane ug/L 48.3 47.5 2 30 1,1-Dichloroethene ug/L 1.0 0.94J 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L 0.46J ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Acrylonitrile ug/L ND ND 30 Benzene ug/L 1.4 1.4 1 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 30 v2 Carbon disulfide ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L 1.4 1.4 2 30 Chloroethane ug/L 5.0 4.4 14 30 Chloroform ug/L 0.511 ND 30 Chloromethane ug/L ND ND 30 cis-1,2-Dichloroethene ug/L 5.6 5.4 4 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 lodomethane ug/L ND ND 30 v2 m&p-Xylene ug/L ND ND 30 Methylene Chloride ug/L 16.8 16.6 1 30 o-Xylene ug/L 2.5 2.5 0 30 Styrene ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans- 1,3-Dichloropropene ug/L ND ND 30 trans-1,4-Dichloro-2-butene ug/L ND ND 30 Trichloroethene ug/L ND ND 30 Trichlorofluoromethane ug/L ND ND 30 Vinyl acetate ug/L ND ND 30 Vinyl chloride ug/L ND ND 30 Xylene (Total) ug/L 2.5 2.5 0 30 1,2-Dichloroethane-d4 (S) % 108 104 4-Bromofluorobenzene (S) % 94 93 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/06/2024 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 SAMPLE DUPLICATE: 4382103 92726233002 Dup Max Parameter Units Result Result RPD RPD Toluene-d8 (S) % 99 99 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/06/2024 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALIFIERS Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS 1g Reported from a Sequence that did not include a Closing ISCA/ICSAB. ICSAB immediately before this sample in the sequence meets all method acceptance criteria. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/06/2024 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 46 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Rutherford Co. LF-South Apr 24 92726233 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92726233001 8102-MW-4A EPA 3010A 849754 EPA 6010D 849905 92726233001 8102-MW-4A EPA 3010A 851965 EPA 6010D 852078 92726233002 8102-MW-1 EPA 3010A 849754 EPA 6010D 849905 92726233002 8102-MW-1 EPA 3010A 851965 EPA 6010D 852078 92726233003 8102-MW-2A EPA 3010A 849754 EPA 6010D 849905 92726233003 8102-MW-2A EPA 3010A 851965 EPA 6010D 852078 92726233004 8102-MW-3 EPA 3010A 849754 EPA 6010D 849905 92726233004 8102-MW-3 EPA 3010A 851965 EPA 6010D 852078 92726233005 8102-MW-5 EPA 3010A 849754 EPA 6010D 849905 92726233005 8102-MW-5 EPA 3010A 851965 EPA 6010D 852078 92726233006 8102-MW-6 EPA 3010A 849754 EPA 6010D 849905 92726233006 8102-MW-6 EPA 3010A 851965 EPA 6010D 852078 92726233007 8102-MW-7 EPA 3010A 849754 EPA 6010D 849905 92726233007 8102-MW-7 EPA 3010A 851965 EPA 6010D 852078 92726233008 8102-MW-8 EPA 3010A 849757 EPA 6010D 849908 92726233009 8102-MW-9S EPA 3010A 849757 EPA 6010D 849908 92726233010 8102-MW-9D EPA 3010A 849757 EPA 6010D 849908 92726233011 8102-SW-1 EPA 3010A 849757 EPA 6010D 849908 92726233012 8102-SW-2 EPA 3010A 849757 EPA 6010D 849908 92726233001 8102-MW-4A EPA 7470A 848920 EPA 7470A 848975 92726233002 8102-MW-1 EPA 7470A 848920 EPA 7470A 848975 92726233003 8102-MW-2A EPA 7470A 848920 EPA 7470A 848975 92726233004 8102-MW-3 EPA 7470A 848920 EPA 7470A 848975 92726233005 8102-MW-5 EPA 7470A 848920 EPA 7470A 848975 92726233006 8102-MW-6 EPA 7470A 848920 EPA 7470A 848975 92726233007 8102-MW-7 EPA 7470A 848920 EPA 7470A 848975 92726233008 8102-MW-8 EPA 7470A 848920 EPA 7470A 848975 92726233009 8102-MW-9S EPA 7470A 848920 EPA 7470A 848975 92726233010 8102-MW-9D EPA 7470A 848920 EPA 7470A 848975 92726233011 8102-SW-1 EPA 7470A 848920 EPA 7470A 848975 92726233012 8102-SW-2 EPA 7470A 848920 EPA 7470A 848975 92726233001 8102-MW-4A 8260D-SIM 2273876 EPA 8260D by SIM 2273876 92726233002 8102-MW-1 8260D-SIM 2273876 EPA 8260D by SIM 2273876 92726233003 8102-MW-2A 8260D-SIM 2276747 EPA 8260D by SIM 2276747 92726233004 8102-MW-3 8260D-SIM 2276134 EPA 8260D by SIM 2276134 92726233005 8102-MW-5 8260D-SIM 2276134 EPA 8260D by SIM 2276134 92726233006 8102-MW-6 8260D-SIM 2276134 EPA 8260D by SIM 2276134 92726233007 8102-MW-7 8260D-SIM 2276134 EPA 8260D by SIM 2276134 92726233008 8102-MW-8 8260D-SIM 2276134 EPA 8260D by SIM 2276134 92726233009 8102-MW-9S 8260D-SIM 2276134 EPA 8260D by SIM 2276134 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/06/2024 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 47 of 53 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Rutherford Co. LF-South Apr 24 Pace Project No.: 92726233 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92726233010 8102-MW-9D 8260D-SIM 2276408 EPA 8260D by SIM 2276408 92726233011 8102-SW-1 8260D-SIM 2276408 EPA 8260D by SIM 2276408 92726233012 8102-SW-2 8260D-SIM 2276408 EPA 8260D by SIM 2276408 92726233001 8102-MW-4A EPA 8260D 848859 92726233002 8102-MW-1 EPA 8260D 848859 92726233003 8102-MW-2A EPA 8260D 848859 92726233004 8102-MW-3 EPA 8260D 848859 92726233005 8102-MW-5 EPA 8260D 848859 92726233006 8102-MW-6 EPA 8260D 848859 92726233007 8102-MW-7 EPA 8260D 848859 92726233008 8102-MW-8 EPA 8260D 848859 92726233009 8102-MW-9S EPA 8260D 848859 92726233010 8102-MW-9D EPA 8260D 848859 92726233011 8102-SW-1 EPA 8260D 848859 92726233012 8102-SW-2 EPA 8260D 848859 92726233013 8102-Duplicate EPA 8260D 848859 Date: 05/06/2024 03:30 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 48 of 53 DC# Title: ENV-FRM-HUN1-0083 v03 Sample Condition Upon Receipt ace Effective Date:11/29/2023 4.16:30 PM Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville ® Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersville❑ Sample Conclaicin Client Name: CWO# : 92726233 Upon Receipt ProjeR fi: .. 1111 111 I Courier 0 Fed Ex L1 UP5 LJ usps f LJChent ❑ Commercial Pace ❑Other:� Custody Seal Present? ❑Yes �5No Packing Material: ❑ Bubble Wrap 92726233 Seals Intact? ❑Yes ❑ No 50 N/A /,G Date/initials Person Examining Contents �Ir r Zy Bubble Bags ❑ None ❑ Other Thermometer: IR Gun ID 7 -PP 32'z • Correction Factor: Cooler Temp: '?' i/ Add/Subtract ('Cj Type of Ice: C ® Wet 0 Blue l] None Cooler Temp Corrected (*Q: 3. Z L • � 3 • y USDA Regulated Soil ( ® N/A, water sample) Did samples originate In a quarantine zone wFthin the United States- CA, NY, or SC Irk.,L, -.11? r—I vsc la N. Biological Tissue Frozen? ❑ Yes ❑ No [RN/A Temp should be above freezing to 6'C ❑ Sample s out of to mp criteria. Sam pies on i ce, cooling process has begun Did samples originate from a foreign source (internationally, includine Hawaii and Puerto Ricci? ©Yes 10No Comments/Discrepancy: Chain of Custody Present? Yes ❑ No ] N/A 1. Samples Arrived within Hold Time? Yes ❑ No ❑ N/A 2. Short Hold Time Analysis (<72 hr.)? ❑ Yes ❑ No ilk N/A 3, Rush Turn Around Time Requested? ❑ Yes ❑ No 11 N/A 4. Sufficient Volume? 10 Yes ❑ No ❑ N/A S. Correct Containers Used? -Pace Containers Used? 11M Yes IaYes ❑ No ❑ No ❑ N/A ❑ N/A 6. Containers Intact? lI Yes ❑ No ❑ N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes ❑ No @ N/A 8. Sample Labels Match COOT -Includes Date/Time/ID/Analysis Matrix: goYes mot/ 7' ❑No ❑N/A 9. Headspace in VOA Vials (>5.6mm)7 ❑Yes J9 No ❑ N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? ❑ Yes ❑ Yes ❑ No ❑ No SIN/A N/A 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers. CLIENT NOTIFICATION/RESOLLfttON Person contacted: Date/Time: Field Data Required? LJYes iJ No Project Manager SCURF Review: Date: Project Manager SRF Review: Date: Qualtrax ID: 69614 Paae 1 of 2 Page 49 of 53 I ►a%Jv —. „ t . effective Date: 11/14/2022 •Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions, VOA, Coliform, TOC, Oil and Grease, DRO/8015 (viater) DOC, LLHq "Bottom half of box is to list number of bottles "Check all unpreserved Nitrates for chlorine Project # WO# : 92726233 . PH: SK Due Date: 05/06/24 CLIENT: KR—RuthLandf Z v ? 7 Z O N N as ry ' 4 � : I a r� n n U Z 2 ` 2 i Z Z Z I .- . A I Z I 2 d CI 71 u d Q ,M M z u 1-4 S Zv Y ry L Vec 0 On CI iQ a ? rn N N Z LC7 O • �j aVd M A4rl ro a E uti A a ..I E o a E QO ? d a J �, E _ ,n fy� ry n - E C' o m n, ,� E v, ry m E w E n a E d ° c E E ¢ a .., E = o c £ q a : E o iA n E a c 4 O > E a 0 > E a < O o > > E E O,f " y E v a i r vi E n d w E o E v ._ « 6 v d m N M a m tr, 7 N a m e+ ti V, Q rL a m m Z M a o a i m .-i a IL m •-1 •, c9 4 ri f^I « nt t9 Q a a .,� N v, N m W 0 a a O d,- m %3 O 0 a, �? fl q q, t7 > � a tl > O Jul r o. Se } N rI v. a ,n JI N n a. N `m 2 I 1 11 tZ pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative adjusted added Lot # I I —_ t _ I I I _ _ Note Whenewl there is a discreoancv affecting ;Inrivi Carolina contofiance samoles. a coov of this form • ill be sent to the NartIt Carolina OFNR Coridiratlon Officr fie Out Of hold, incorrect preservative, out of temp. IncorlQct containers. Qualtrax ID. 69614 Page 2 of 2 Page 50 of 53 ! MVV Effective Date., 11/14/2022 "Check mark top half of box if pH and/or dechlorination is verified and Project H within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC. LLHg f •'Bottom half of box is to list number of bottles ***Check all unpreserved Nitrates for chlorine t a O Z 1 M a rn z d y d v o3 7 a i y v S u q Z n x ¢ ¢ a sr ? a m tMi m t l? g O n v a iu O 0 a = n d n . V O w z L S � � n q ? a c c c a Z a O C� a c ^� v Z Q z a M r S a c a a = a a a Q ° E E 4 E e E 0 p O 0 e w E Q Q > > i } E E a`i c E E E m `a i o u E c E t l E E '° E € E E c N ..a N Q V q 4 'f 1l5 .— - N N N V N Z N m ti �• N V% C p 1n N •" 1 V en 11 Q Ur vY r1 In •1 rn 01 0% T T 01 M1 tg K M �+1 O V+ at W a, a a 0. d 0. A. a t3 V 0 0 to 0 Q t2 0 l9 {!. \ 0. a 0. 0 N ry _ m ra Co ra m m m m 3 ¢ a a a a a /o > > o x } In 66 m a a i= 3- ----- NNN-3 ` l [� a I l N \ K 1— I 1 l i t - I \ 11 �I � L�V\NFL�J��-�LL�TLELV I l pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot # adjusted I added Note- Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will tie sent to thr; North Carolina DENR Certllicauon Office (t e Out of hold, incorrect preservative, out of temp, incorrcu containers. Qualtrax ID_ 69614 Page 2 of 2 Page 51 of 53 Pace* Location Requested (City/State): LAB USE ONLY. Affix Workorder/Login Label Here nPace Analytical Charlotte CHAIN -OF -CUSTODY Analytical Request Document . Qce 98DO Kincey Ave. Suite 100, Huntersville, NC 28078 Chain -of -Custody is a LEGAL DOCUMENT - Complete all relevant fields Company Name: Rutherford County Landfill Contact/Report To: James Kilgo Street Address: PO Box 1957, Rutherfordton, NC 28I39 Phone p: 828.287-6W2 E Mail: james.kilgo@rutherfordcountync.gov - Scan OR Code for instructions Lc E4M2JI: Customer Project it: Specify Container Size " "container Si.; (1) IL, (2) S00.L,(312somL (a) 125mL is) 1DOmL (6140mLda:.:n [ficar. I!I invoice To: Accounts Payable Project Name: Rutherford Co LF - South Terratare, 1919DmL (LO) Other Invoice E-Mail: james.kilgo@rutherfordcountync.gov Identify Conta ner Preservative Type' ••. I'MervaliveTypes: (1) Hone, (1) HH03, (3f Site Collection Info/Facility ID {as applicable]: Purchase Order q (if H2SO4, (41 HCt, IS: NaOH, (6) Zn Acetate. IT; applicable): HaHSM, (5) Sod. Thiosullate, i9) AsearbieAod. (101 McOH, 111) Other Analysis Requested _ a prof. Mgr: Stephanie Knott `e - v Quote +r: Time Zone Collected: I ] AK [ ] PT [ ] MT [ ] CT I ] ET County/ State origin of sample(s): North Carolina Data Deliverables: Regulatory Program (OW, RCRA, etc.) as applicable: Reportable ] ] Yes I )NO AcctNum / Chent ID: [ ] tevel 11 [ 1 Leve4III ( ] Level ly {Pre -approval required]: Ow PWSfD a orWW permit aasapPircable a m mRush acable N• I ISameDay[ ] I Day l 12 Day [ ) 3 Oay I ]Other- _ _ _ > S a [ ] EQUIS Date Results Field Filtered (if applicable): ( ]Yes [ ] No ¢ _1 a A - 3 Profile / Template: Other Requested: Analysis: J y 17056 Prelog / Bottle Ord, ID: • Matrix Codes ]tnsert in Matrix box below): Drinking Water (DW), Ground Water ]GW), Waste Water (WW), Product (P), Soil Solid (55), Oil (OL), Wipe (WP), Tissue (TS), Bioassay (81, Vapor Surface Water SW Sediment SED Sludge SL Caulk ICKi. Leachate LL giosolid BS Other OT c r} EZ 3097806 0 comp / Composite Start Collected or Composite End 0 Res. Chlorine d Customer Sample II} Matrix ' Grab Cant. m Sample Comment a" Date Time Date Time Results uni. 8102-MW-4A Wi 1345 X X X 8102-MW-1 WT 1HO X X X 8102-MW-2A WT 1335 X X X 8102-MW-3 WT " s X X X 8102 - MW-5 WT 60D X X X 8102 - M W-6 WT 1235 X X X 8102-MW-7 WT S?j7�p X X X 8102-MW-8 WT 10l1; X X X 8102 - M W-9S WT 0 S7 X X X 8102-MW-90 WT 12co X X X Additional Instructions from Pace^ Collected By: /�Ly Customer Remarks / Special Conditions / Possible Hazards: Permit No:8102-MSWLF-1977 . 1' y ,, (Printed Name) aw I-M iF.Y a/i +++VVV ��a 111 �^^�"'��+++ BLE Project - J24.2095"2 Signature: scoolm; Thermometer to: Coaecmn Fana ('Q1 Obs. Temp. [•q Corrected Temp. (-c) on Ice: Relinquished by/Company; Oignaturel DateRme: Received by/Cwpany:I re] Date/T % Tra"gNumber: Relinquished by/Company: )Signature] Date/rme: Received by/Company: {Signature] Date✓rime: Delivered by: I ] In- Person [ ]Courier ]FedEX 1]UPS ]Other !l Relinqu fled by/Company:(Signaturel Date/Time: Received by/€ompany:(Signature) Dateirme: 0) to Relinq ed by/Company. ]Signature) Datefrme: Received by/CompanV: (Signature) DaterTme: Page: 1 of 2 CTI N SubitWeting a sample via this chain of custody constitutes acknowledgment and acceptance of the Pace- Terms and Conditions round at nttps://www.pacelaos.com/resource-uorary/resource/pace•terms•ana-conm❑ansr ��•• �Rr•.��.r,.,r .,.. _ _ W Pace" Location Requested (City/State): Pace Analytical Charlotte CHAIN -OF -CUSTODY Analytical Request Document 9800 Kincey Ave. Suite 100, Huntersville, NC 28078 Chain -of -Custody is a LEGAL DOCUMENT- Complete a I relevant fields LAB USE ONLY -Affix WorkorderlLogin Label Here Scan OR Code for instructions Company Name: Rutherford County Landfill Street Address: PO Box 1957, Rutherfordton, NC 28139 Customer Project x: Project Name: Rutherford Co LF - South Site Collection Info/Facility ID {as applicable): Contact/Report TO: James Kilgo Phone a: 828.287.6002 E-Mail: james.kilgo@rutherfordcountync.gov Cc E-Mail: Specify Container Size " "ContaVnn Site- (L) LL:2) 50DmL 131 250mL 14) 125mL 151 LOOmL :6i 40mi-vial, (7) Encore, (8) Teiracaa (9) 90mL 110) other Invoice TO: Accounts Payable Invoice E-Mail: james.kilgo@rutherfordcountync.gov Purchase Order 11(if applicable]: Quote q: Identify Container Preservative Type" • 01, rmtive Types:.li None,, 2: HNO3,13r H2504, (41 HO, (5) NaDH, (6) Zn Amate, (7) NaH504,(81$00 Thiwveate,IS: Aunrbicndd,JLOt McOH III, Other Analysis Requested c r` o _ c ro a c co > G Go Proj. Mgr: Stephanie Knott `a ' � 8 a is Z u Time Zone Collected: I ] AK [ )PT I ] MT I ] Cr I 1 ET County / State origin of sample(s): North Carolina Data Deliverables: [ ] Level11 ( ] Level III ( j Level IV [ ] EQUIS Other Regulatory Program (DW, RCRA, etc.) as applicable: Reportable ( ] Yes ( I No AcctNum / Client ID: Rush (Pro -approval required): [ ) Same Day I 1 1 Day [ 1 2 Oay [ ) 3 Day [ ]Other. DW PWSID n or WW Permit a as applicable C.'Table p. a Date Results Requested: Field Filtered {if applicable) I ] Yes I ]NO Analysis: 3 Profile / Template: 17056 ' Matrix Codes {insert in Matrix box below): Drinking Water (DW ,Ground Water (GW), Waste Water IWWI, Product P], Soil Solid {SS], Oil IOL, Wipe {WP), Tissue (TS], Bioassa B Vapor Surface Water SW Sediment SED Sludge SL Caulk CK Leachate LL Biosolid BS Other OT Prelog / Bottle Ord. ID: EZ 3097806 Customer Sample ID Matrix' Comp / Grab Composite Start Collected or Composite End p Cont. Res. Chlorine Sample Comment Date Time Date me Results Units 8102 - SW-1 WT 4 X X X 8102 - SW-2 VVT 1! MAN Low X X X 8102 L�AILA 1050 X Additional Instructions from Pace"- Permit No:8102•MSWLF-1977 BLE Project - J24-20955-02 Collected By: )Printed Name) tiv 1Ccv Signature: ��' aaa Customer Remarks / Special Conditions / Possible Hazards: 9Coolen: Thermometer ID: Correction Factor Cq: Obs, Temp.('C) Corroded Temp.('C) On Im Relinquished by/Company: (signature) .A adAr ,` 1 m. i4�{. Date//irnir: fy f �j i51� 1V Received by/Corn i5igna j �4.. +/fir Daee ime: •�j� Tracking Number: Relinquished by/Company: (Signature) Daterme: Reormod by/Company: (Signature) DateRme: Delivered try: ( ] In- Person [ j Courier ( 1 FedEx ( ]UPS ( ]Other Reinqushtd by/Company: (Signature) N to Dated e: Received by/Company; (Signature) Date/rime;. Regnq A hed by/Company: (Signature) U1 w 0alelrme: Received by/Company; (Signature) Dater -me: Page: 2 of 2 Submt` ting a sample via this chain of custody constitutes acknowledgment and acceptance of the Pace* Terms and Conditions found at https://+Nww pacelal)s.com/resourmiiorary/resourcetpace-terms-ano-concitionsJ Crvv-rrtm-�.vnl,t-w i a_vuc_ t w rcu or tr W ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 May 15, 2024 James Kilgo Rutherford County Solid Waste PO Box 1957 Rutherfordton, NC 28139 RE: Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Dear James Kilgo: Enclosed are the analytical results for sample(s) received by the laboratory on April 19, 2024. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Minneapolis If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Mr. Andy Alexander, Bunnell-Lammons Engineering Riley Blais, BLE Corp Accounts Payable, Rutherford County Landfill Director �pQ AC RFb REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 47 Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Pace Analytical Services, LLC - Minneapolis MN 1700 Elm Street SE, Minneapolis, MN 55414 Alabama Certification #: 40770 Alaska Contaminated Sites Certification #: 17-009 Alaska DW Certification #: MN00064 Arizona Certification #: AZ0014 Arkansas DW Certification #: MN00064 Arkansas WW Certification #: 88-0680 California Certification #: 2929 Colorado Certification #: MN00064 Connecticut Certification #: PH-0256 DoD Certification via A21-A #: 2926.01 EPA Region 8 Tribal Water Systems+Wyoming DW Certification #: via MN 027-053-137 Florida Certification #: E87605 Georgia Certification #: 959 GMP+ Certification #: GMP050884 Hawaii Certification #: MN00064 Idaho Certification #: MN00064 Illinois Certification #: 200011 Indiana Certification #: C-MN-01 Iowa Certification #: 368 ISO/IEC 17025 Certification via A21-A #: 2926.01 Kansas Certification #: E-10167 Kentucky DW Certification #: 90062 Kentucky WW Certification #: 90062 Louisiana DEQ Certification #: AI-03086 Louisiana DW Certification #: MN00064 Maine Certification #: MN00064 Maryland Certification M 322 Michigan Certification #: 9909 Minnesota Certification #: 027-053-137 Minnesota Dept ofAg Approval: via MN 027-053-137 Minnesota Petrofund Registration #: 1240 CERTIFICATIONS Mississippi Certification #: MN00064 Missouri Certification #: 10100 Montana Certification #: CERT0092 Nebraska Certification #: NE-OS-18-06 Nevada Certification #: MN00064 New Hampshire Certification #: 2081 New Jersey Certification #: MN002 New York Certification #: 11647 North Carolina DW Certification #: 27700 North Carolina WW Certification #: 530 North Dakota Certification (A2LA) #: R-036 North Dakota Certification (MN) #: R-036 Ohio DW Certification #: 41244 Ohio VAP Certification (1700) #: CL101 Oklahoma Certification #: 9507 Oregon Primary Certification #: MN300001 Oregon Secondary Certification #: MN200001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification #: MN00064 South Carolina Certification #:74003001 Tennessee Certification #: TN02818 Texas Certification #: T104704192 Utah Certification #: MN00064 Vermont Certification #: VT-027053137 Virginia Certification #: 460163 Washington Certification #: C486 West Virginia DEP Certification #: 382 West Virginia DW Certification #: 9952 C Wisconsin Certification #: 999407970 Wyoming UST Certification via A21-A #: 2926.01 USDA Permit #: P330-19-00208 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE SUMMARY Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Lab ID Sample ID Matrix Date Collected Date Received 92726234001 8102-MW-4A Water 04/19/2413:45 04/19/24 16:00 92726234002 8102-MW-1 Water 04/19/2411:40 04/19/24 16:00 92726234003 8102-MW-2A Water 04/19/2413:35 04/19/24 16:00 92726234004 8102-MW-3 Water 04/19/2411:35 04/19/24 16:00 92726234005 8102-MW-5 Water 04/19/2410:00 04/19/24 16:00 92726234006 8102-MW-6 Water 04/19/2412:35 04/19/24 16:00 92726234007 8102-MW-7 Water 04/19/2413:30 04/19/24 16:00 92726234008 8102-MW-8 Water 04/19/2410:45 04/19/24 16:00 92726234009 8102-MW-9S Water 04/19/2410:50 04/19/24 16:00 92726234010 8102-MW-9D Water 04/19/2412:00 04/19/24 16:00 92726234011 8102-SW-1 Water 04/19/2412:40 04/19/24 16:00 92726234012 8102-SW-2 Water 04/19/2410:20 04/19/24 16:00 92726234013 8102-Field Blank Water 04/19/24 13:00 04/19/24 16:00 92726234014 8102-Equipment Rinse Water 04/19/24 12:25 04/19/24 16:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Rutherford Co. LF-South PFAS 92726234 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92726234001 8102-MW-4A EPA 1633 DRAFT NBH 64 PASI-M 92726234002 8102-MW-1 EPA 1633 DRAFT NBH 64 PASI-M 92726234003 8102-MW-2A EPA 1633 DRAFT NBH 64 PASI-M 92726234004 8102-MW-3 EPA 1633 DRAFT NBH 64 PASI-M 92726234005 8102-MW-5 EPA 1633 DRAFT NBH 64 PASI-M 92726234006 8102-MW-6 EPA 1633 DRAFT NBH 64 PASI-M 92726234007 8102-MW-7 EPA 1633 DRAFT NBH 64 PASI-M 92726234008 8102-MW-8 EPA 1633 DRAFT NBH 64 PASI-M 92726234009 8102-MW-9S EPA 1633 DRAFT NBH 64 PASI-M 92726234010 8102-MW-9D EPA 1633 DRAFT NBH 64 PASI-M 92726234011 8102-SW-1 EPA 1633 DRAFT NBH 64 PASI-M 92726234012 8102-SW-2 EPA 1633 DRAFT NBH 64 PASI-M 92726234013 8102-Field Blank EPA 1633 DRAFT NBH 64 PASI-M 92726234014 8102-Equipment Rinse EPA 1633 DRAFT NBH 64 PASI-M PASI-M = Pace Analytical Services - Minneapolis REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-MW-4A Lab ID: 92726234001 Collected: 04/19/24 13:45 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis 11CI-PF30UdS ND ng/L 4.3 0.84 1 05/09/24 08:00 05/11/24 17:33 763051-92-9 3:3 FTCA ND ng/L 5.4 2.5 1 05/09/24 08:00 05/11/24 17:33 356-02-5 4:2 FTS ND ng/L 4.3 0.52 1 05/09/24 08:00 05/11/24 17:33 757124-72-4 5:3 FTCA ND ng/L 27.0 5.2 1 05/09/24 08:00 05/11/24 17:33 914637-49-3 6:2 FTS ND ng/L 4.3 1.1 1 05/09/24 08:00 05/11/24 17:33 27619-97-2 7:3 FTCA ND ng/L 27.0 5.6 1 05/09/24 08:00 05/11/24 17:33 812-70-4 8:2 FTS ND ng/L 4.3 1.1 1 05/09/24 08:00 05/11/24 17:33 39108-34-4 9CI-PF30NS ND ng/L 4.3 0.89 1 05/09/24 08:00 05/11/24 17:33 756426-58-1 ADONA ND ng/L 4.3 0.63 1 05/09/24 08:00 05/11/24 17:33 919005-14-4 HFPO-DA ND ng/L 4.3 0.84 1 05/09/24 08:00 05/11/24 17:33 13252-13-6 NEtFOSAA ND ng/L 1.1 0.38 1 05/09/24 08:00 05/11/24 17:33 2991-50-6 NEtFOSA ND ng/L 1.1 0.28 1 05/09/24 08:00 05/11/24 17:33 4151-50-2 NEtFOSE ND ng/L 10.8 3.5 1 05/09/24 08:00 05/11/24 17:33 1691-99-2 NFDHA ND ng/L 2.2 0.61 1 05/09/24 08:00 05/11/24 17:33 151772-58-6 NMeFOSAA ND ng/L 1.1 0.34 1 05/09/24 08:00 05/11/24 17:33 2355-31-9 NMeFOSA ND ng/L 1.1 0.29 1 05/09/24 08:00 05/11/24 17:33 31506-32-8 NMeFOSE ND ng/L 10.8 2.9 1 05/09/24 08:00 05/11/24 17:33 24448-09-7 PFBS ND ng/L 1.1 0.35 1 05/09/24 08:00 05/11/24 17:33 375-73-5 PFDA ND ng/L 1.1 0.19 1 05/09/24 08:00 05/11/24 17:33 335-76-2 PFHxA ND ng/L 1.1 0.16 1 05/09/24 08:00 05/11/24 17:33 307-24-4 PFBA ND ng/L 4.3 0.66 1 05/09/24 08:00 05/11/24 17:33 375-22-4 PFDS ND ng/L 1.1 0.29 1 05/09/24 08:00 05/11/24 17:33 335-77-3 PFDoS ND ng/L 1.1 0.30 1 05/09/24 08:00 05/11/24 17:33 79780-39-5 PFEESA ND ng/L 2.2 0.35 1 05/09/24 08:00 05/11/24 17:33 113507-82-7 PFHpS ND ng/L 1.1 0.26 1 05/09/24 08:00 05/11/24 17:33 375-92-8 PFMBA ND ng/L 2.2 0.34 1 05/09/24 08:00 05/11/24 17:33 863090-89-5 PFMPA ND ng/L 2.2 0.52 1 05/09/24 08:00 05/11/24 17:33 377-73-1 PFNS ND ng/L 1.1 0.26 1 05/09/24 08:00 05/11/24 17:33 68259-12-1 PFOSA ND ng/L 1.1 0.26 1 05/09/24 08:00 05/11/24 17:33 754-91-6 PFPeA ND ng/L 2.2 0.32 1 05/09/24 08:00 05/11/24 17:33 2706-90-3 PFPeS ND ng/L 1.1 0.20 1 05/09/24 08:00 05/11/24 17:33 2706-91-4 PFDoA ND ng/L 1.1 0.24 1 05/09/24 08:00 05/11/24 17:33 307-55-1 PFHpA ND ng/L 1.1 0.23 1 05/09/24 08:00 05/11/24 17:33 375-85-9 PFHxS ND ng/L 1.1 0.28 1 05/09/24 08:00 05/11/24 17:33 355-46-4 PFNA ND ng/L 1.1 0.25 1 05/09/24 08:00 05/11/24 17:33 375-95-1 PFOS ND ng/L 1.1 0.19 1 05/09/24 08:00 05/11/24 17:33 1763-23-1 PFOA ND ng/L 1.1 0.37 1 05/09/24 08:00 05/11/24 17:33 335-67-1 PFTeDA ND ng/L 1.1 0.31 1 05/09/24 08:00 05/11/24 17:33 376-06-7 PFTrDA ND ng/L 1.1 0.21 1 05/09/24 08:00 05/11/24 17:33 72629-94-8 PFUnA ND ng/L 1.1 0.27 1 05/09/24 08:00 05/11/24 17:33 2058-94-8 Surrogates 13C2-PFDoA (S) 67 %. 10-130 1 05/09/24 08:00 05/11/24 17:33 13C3HFPO-DA (S) 78 %. 40-130 1 05/09/24 08:00 05/11/24 17:33 13C3-PFBS (S) 86 %. 40-135 1 05/09/24 08:00 05/11/24 17:33 375-73-5 13C3-PFHxS (S) 87 %. 40-130 1 05/09/24 08:00 05/11/24 17:33 355-46-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-MW-4A Lab ID: 92726234001 Collected: 04/19/24 13:45 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis Surrogates 13C4-PFBA (S) 78 %. 5-130 1 05/09/24 08:00 05/11/24 17:33 375-22-4 13C4-PFHpA (S) 81 %. 40-130 1 05/09/24 08:00 05/11/24 17:33 375-85-9 13C5-PFHxA (S) 78 %. 40-130 1 05/09/24 08:00 05/11/24 17:33 307-24-4 13C5-PFPeA (S) 83 %. 40-130 1 05/09/24 08:00 05/11/24 17:33 2706-90-3 13C6-PFDA (S) 78 %. 40-130 1 05/09/24 08:00 05/11/24 17:33 335-76-2 13C8-PFDA (S) 79 %. 40-130 1 05/09/24 08:00 05/11/24 17:33 335-67-1 13C8-PFOS (S) 80 %. 40-130 1 05/09/24 08:00 05/11/24 17:33 1763-23-1 13C8-PFOSA(S) 67 %. 40-130 1 05/09/24 08:00 05/11/24 17:33 754-91-6 13C9-PFNA (S) 82 %. 40-130 1 05/09/24 08:00 05/11/24 17:33 375-95-1 d3-McFOSAA (S) 75 %. 40-170 1 05/09/24 08:00 05/11/24 17:33 2355-31-9 d3-NMeFOSA (S) 57 %. 10-130 1 05/09/24 08:00 05/11/24 17:33 31506-32-8 d5-EtFOSAA (S) 74 %. 25-135 1 05/09/24 08:00 05/11/24 17:33 2991-50-6 d5-NEtFOSA (S) 59 %. 10-130 1 05/09/24 08:00 05/11/24 17:33 4151-50-2 d7-NMeFOSE (S) 67 %. 10-130 1 05/09/24 08:00 05/11/24 17:33 24448-09-7 d9-NEtFOSE (S) 73 %. 10-130 1 05/09/24 08:00 05/11/24 17:33 1691-99-2 13C2-PFTA (S) 59 %. 10-130 1 05/09/24 08:00 05/11/24 17:33 13C7-PFUdA (S) 76 %. 30-130 1 05/09/24 08:00 05/11/24 17:33 2058-94-8 13C24:2FTS (S) 93 %. 40-200 1 05/09/24 08:00 05/11/24 17:33 13C26:2FTS (S) 98 %. 40-200 1 05/09/24 08:00 05/11/24 17:33 13C28:2FTS (S) 93 %. 40-300 1 05/09/24 08:00 05/11/24 17:33 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-MW-1 Lab ID: 92726234002 Collected: 04/19/24 11:40 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis 11CI-PF30UdS ND ng/L 3.8 0.75 1 05/09/24 08:00 05/11/24 17:49 763051-92-9 3:3 FTCA ND ng/L 4.8 2.2 1 05/09/24 08:00 05/11/24 17:49 356-02-5 4:2 FTS ND ng/L 3.8 0.46 1 05/09/24 08:00 05/11/24 17:49 757124-72-4 5:3 FTCA ND ng/L 24.0 4.6 1 05/09/24 08:00 05/11/24 17:49 914637-49-3 6:2 FTS ND ng/L 3.8 0.94 1 05/09/24 08:00 05/11/24 17:49 27619-97-2 7:3 FTCA ND ng/L 24.0 5.0 1 05/09/24 08:00 05/11/24 17:49 812-70-4 8:2 FTS ND ng/L 3.8 1.0 1 05/09/24 08:00 05/11/24 17:49 39108-34-4 9CI-PF30NS ND ng/L 3.8 0.79 1 05/09/24 08:00 05/11/24 17:49 756426-58-1 ADONA ND ng/L 3.8 0.56 1 05/09/24 08:00 05/11/24 17:49 919005-14-4 HFPO-DA ND ng/L 3.8 0.75 1 05/09/24 08:00 05/11/24 17:49 13252-13-6 NEtFOSAA ND ng/L 0.96 0.33 1 05/09/24 08:00 05/11/24 17:49 2991-50-6 NEtFOSA ND ng/L 0.96 0.25 1 05/09/24 08:00 05/11/24 17:49 4151-50-2 NEtFOSE ND ng/L 9.6 3.1 1 05/09/24 08:00 05/11/24 17:49 1691-99-2 NFDHA ND ng/L 1.9 0.54 1 05/09/24 08:00 05/11/24 17:49 151772-58-6 NMeFOSAA ND ng/L 0.96 0.31 1 05/09/24 08:00 05/11/24 17:49 2355-31-9 NMeFOSA ND ng/L 0.96 0.25 1 05/09/24 08:00 05/11/24 17:49 31506-32-8 NMeFOSE ND ng/L 9.6 2.6 1 05/09/24 08:00 05/11/24 17:49 24448-09-7 PFBS 0.591 ng/L 0.96 0.31 1 05/09/24 08:00 05/11/24 17:49 375-73-5 PFDA ND ng/L 0.96 0.17 1 05/09/24 08:00 05/11/24 17:49 335-76-2 PFHxA 2.1 ng/L 0.96 0.14 1 05/09/24 08:00 05/11/24 17:49 307-24-4 PFBA 1.2.1 ng/L 3.8 0.59 1 05/09/24 08:00 05/11/24 17:49 375-22-4 PFDS ND ng/L 0.96 0.25 1 05/09/24 08:00 05/11/24 17:49 335-77-3 PFDoS ND ng/L 0.96 0.27 1 05/09/24 08:00 05/11/24 17:49 79780-39-5 PFEESA ND ng/L 1.9 0.31 1 05/09/24 08:00 05/11/24 17:49 113507-82-7 PFHpS ND ng/L 0.96 0.23 1 05/09/24 08:00 05/11/24 17:49 375-92-8 PFMBA ND ng/L 1.9 0.30 1 05/09/24 08:00 05/11/24 17:49 863090-89-5 PFMPA ND ng/L 1.9 0.46 1 05/09/24 08:00 05/11/24 17:49 377-73-1 PFNS ND ng/L 0.96 0.23 1 05/09/24 08:00 05/11/24 17:49 68259-12-1 PFOSA ND ng/L 0.96 0.23 1 05/09/24 08:00 05/11/24 17:49 754-91-6 PFPeA 1.3J ng/L 1.9 0.29 1 05/09/24 08:00 05/11/24 17:49 2706-90-3 PFPeS ND ng/L 0.96 0.17 1 05/09/24 08:00 05/11/24 17:49 2706-91-4 PFDoA ND ng/L 0.96 0.21 1 05/09/24 08:00 05/11/24 17:49 307-55-1 PFHpA 0.35J ng/L 0.96 0.20 1 05/09/24 08:00 05/11/24 17:49 375-85-9 PFHxS ND ng/L 0.96 0.25 1 05/09/24 08:00 05/11/24 17:49 355-46-4 PFNA ND ng/L 0.96 0.22 1 05/09/24 08:00 05/11/24 17:49 375-95-1 PFOS ND ng/L 0.96 0.17 1 05/09/24 08:00 05/11/24 17:49 1763-23-1 PFOA 0.46J ng/L 0.96 0.33 1 05/09/24 08:00 05/11/24 17:49 335-67-1 PFTeDA ND ng/L 0.96 0.27 1 05/09/24 08:00 05/11/24 17:49 376-06-7 PFTrDA ND ng/L 0.96 0.19 1 05/09/24 08:00 05/11/24 17:49 72629-94-8 PFUnA ND ng/L 0.96 0.24 1 05/09/24 08:00 05/11/24 17:49 2058-94-8 Surrogates 13C2-PFDoA (S) 75 %. 10-130 1 05/09/24 08:00 05/11/24 17:49 13C3HFPO-DA (S) 76 %. 40-130 1 05/09/24 08:00 05/11/24 17:49 13C3-PFBS (S) 84 %. 40-135 1 05/09/24 08:00 05/11/24 17:49 375-73-5 13C3-PFHxS (S) 83 %. 40-130 1 05/09/24 08:00 05/11/24 17:49 355-46-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-MW-1 Lab ID: 92726234002 Collected: 04/19/24 11:40 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis Surrogates 13C4-PFBA (S) 79 %. 5-130 1 05/09/24 08:00 05/11/24 17:49 375-22-4 13C4-PFHpA (S) 80 %. 40-130 1 05/09/24 08:00 05/11/24 17:49 375-85-9 13C5-PFHxA (S) 79 %. 40-130 1 05/09/24 08:00 05/11/24 17:49 307-24-4 13C5-PFPeA (S) 82 %. 40-130 1 05/09/24 08:00 05/11/24 17:49 2706-90-3 13C6-PFDA (S) 82 %. 40-130 1 05/09/24 08:00 05/11/24 17:49 335-76-2 13C8-PFDA (S) 77 %. 40-130 1 05/09/24 08:00 05/11/24 17:49 335-67-1 13C8-PFOS (S) 77 %. 40-130 1 05/09/24 08:00 05/11/24 17:49 1763-23-1 13C8-PFOSA(S) 65 %. 40-130 1 05/09/24 08:00 05/11/24 17:49 754-91-6 13C9-PFNA (S) 79 %. 40-130 1 05/09/24 08:00 05/11/24 17:49 375-95-1 d3-McFOSAA (S) 70 %. 40-170 1 05/09/24 08:00 05/11/24 17:49 2355-31-9 d3-NMeFOSA (S) 57 %. 10-130 1 05/09/24 08:00 05/11/24 17:49 31506-32-8 d5-EtFOSAA (S) 74 %. 25-135 1 05/09/24 08:00 05/11/24 17:49 2991-50-6 d5-NEtFOSA (S) 59 %. 10-130 1 05/09/24 08:00 05/11/24 17:49 4151-50-2 d7-NMeFOSE (S) 67 %. 10-130 1 05/09/24 08:00 05/11/24 17:49 24448-09-7 d9-NEtFOSE (S) 75 %. 10-130 1 05/09/24 08:00 05/11/24 17:49 1691-99-2 13C2-PFTA (S) 73 %. 10-130 1 05/09/24 08:00 05/11/24 17:49 13C7-PFUdA (S) 78 %. 30-130 1 05/09/24 08:00 05/11/24 17:49 2058-94-8 13C24:2FTS (S) 90 %. 40-200 1 05/09/24 08:00 05/11/24 17:49 13C26:2FTS (S) 90 %. 40-200 1 05/09/24 08:00 05/11/24 17:49 13C28:2FTS (S) 87 %. 40-300 1 05/09/24 08:00 05/11/24 17:49 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-MW-2A Lab ID: 92726234003 Collected: 04/19/24 13:35 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis 11CI-PF30UdS ND ng/L 42.8 8.3 1 05/09/24 08:00 05/11/24 18:05 763051-92-9 3:3 FTCA ND ng/L 53.5 24.9 1 05/09/24 08:00 05/11/24 18:05 356-02-5 4:2 FTS ND ng/L 42.8 5.2 1 05/09/24 08:00 05/11/24 18:05 757124-72-4 5:3 FTCA ND ng/L 268 51.7 1 05/09/24 08:00 05/11/24 18:05 914637-49-3 6:2 FTS ND ng/L 42.8 10.4 1 05/09/24 08:00 05/11/24 18:05 27619-97-2 7:3 FTCA ND ng/L 268 56.0 1 05/09/24 08:00 05/11/24 18:05 812-70-4 8:2 FTS ND ng/L 42.8 11.2 1 05/09/24 08:00 05/11/24 18:05 39108-34-4 9CI-PF30NS ND ng/L 42.8 8.8 1 05/09/24 08:00 05/11/24 18:05 756426-58-1 ADONA ND ng/L 42.8 6.3 1 05/09/24 08:00 05/11/24 18:05 919005-14-4 HFPO-DA ND ng/L 42.8 8.3 1 05/09/24 08:00 05/11/24 18:05 13252-13-6 NEtFOSAA ND ng/L 10.7 3.7 1 05/09/24 08:00 05/11/24 18:05 2991-50-6 NEtFOSA ND ng/L 10.7 2.8 1 05/09/24 08:00 05/11/24 18:05 4151-50-2 NEtFOSE ND ng/L 107 34.4 1 05/09/24 08:00 05/11/24 18:05 1691-99-2 NFDHA ND ng/L 21.4 6.1 1 05/09/24 08:00 05/11/24 18:05 151772-58-6 NMeFOSAA ND ng/L 10.7 3.4 1 05/09/24 08:00 05/11/24 18:05 2355-31-9 NMeFOSA ND ng/L 10.7 2.8 1 05/09/24 08:00 05/11/24 18:05 31506-32-8 NMeFOSE ND ng/L 107 28.6 1 05/09/24 08:00 05/11/24 18:05 24448-09-7 PFBS 7.2J ng/L 10.7 3.4 1 05/09/24 08:00 05/11/24 18:05 375-73-5 PFDA ND ng/L 10.7 1.9 1 05/09/24 08:00 05/11/24 18:05 335-76-2 PFHxA 37.6 ng/L 10.7 1.6 1 05/09/24 08:00 05/11/24 18:05 307-24-4 PFBA 15.7J ng/L 42.8 6.6 1 05/09/24 08:00 05/11/24 18:05 375-22-4 PFDS ND ng/L 10.7 2.8 1 05/09/24 08:00 05/11/24 18:05 335-77-3 PFDoS ND ng/L 10.7 3.0 1 05/09/24 08:00 05/11/24 18:05 79780-39-5 PFEESA ND ng/L 21.4 3.4 1 05/09/24 08:00 05/11/24 18:05 113507-82-7 PFHpS ND ng/L 10.7 2.6 1 05/09/24 08:00 05/11/24 18:05 375-92-8 PFMBA ND ng/L 21.4 3.4 1 05/09/24 08:00 05/11/24 18:05 863090-89-5 PFMPA ND ng/L 21.4 5.2 1 05/09/24 08:00 05/11/24 18:05 377-73-1 PFNS ND ng/L 10.7 2.6 1 05/09/24 08:00 05/11/24 18:05 68259-12-1 PFOSA ND ng/L 10.7 2.5 1 05/09/24 08:00 05/11/24 18:05 754-91-6 PFPeA 27.5 ng/L 21.4 3.2 1 05/09/24 08:00 05/11/24 18:05 2706-90-3 PFPeS 6.OJ ng/L 10.7 1.9 1 05/09/24 08:00 05/11/24 18:05 2706-91-4 PFDoA ND ng/L 10.7 2.4 1 05/09/24 08:00 05/11/24 18:05 307-55-1 PFHpA 20.2 ng/L 10.7 2.3 1 05/09/24 08:00 05/11/24 18:05 375-85-9 PFHxS 13.2 ng/L 10.7 2.8 1 05/09/24 08:00 05/11/24 18:05 355-46-4 PFNA ND ng/L 10.7 2.5 1 05/09/24 08:00 05/11/24 18:05 375-95-1 PFOS ND ng/L 10.7 1.9 1 05/09/24 08:00 05/11/24 18:05 1763-23-1 PFOA 24.0 ng/L 10.7 3.7 1 05/09/24 08:00 05/11/24 18:05 335-67-1 PFTeDA ND ng/L 10.7 3.1 1 05/09/24 08:00 05/11/24 18:05 376-06-7 PFTrDA ND ng/L 10.7 2.1 1 05/09/24 08:00 05/11/24 18:05 72629-94-8 PFUnA ND ng/L 10.7 2.7 1 05/09/24 08:00 05/11/24 18:05 2058-94-8 Surrogates 13C2-PFDoA (S) 55 %. 10-130 1 05/09/24 08:00 05/11/24 18:05 13C3HFPO-DA (S) 65 %. 40-130 1 05/09/24 08:00 05/11/24 18:05 13C3-PFBS (S) 67 %. 40-135 1 05/09/24 08:00 05/11/24 18:05 375-73-5 13C3-PFHxS (S) 64 %. 40-130 1 05/09/24 08:00 05/11/24 18:05 355-46-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-MW-2A Lab ID: 92726234003 Collected: 04/19/24 13:35 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis Surrogates 13C4-PFBA (S) 69 %. 5-130 1 05/09/24 08:00 05/11/24 18:05 375-22-4 13C4-PFHpA (S) 67 %. 40-130 1 05/09/24 08:00 05/11/24 18:05 375-85-9 13C5-PFHxA (S) 66 %. 40-130 1 05/09/24 08:00 05/11/24 18:05 307-24-4 13C5-PFPeA (S) 69 %. 40-130 1 05/09/24 08:00 05/11/24 18:05 2706-90-3 13C6-PFDA (S) 62 %. 40-130 1 05/09/24 08:00 05/11/24 18:05 335-76-2 13C8-PFDA (S) 65 %. 40-130 1 05/09/24 08:00 05/11/24 18:05 335-67-1 13C8-PFOS (S) 69 %. 40-130 1 05/09/24 08:00 05/11/24 18:05 1763-23-1 13C8-PFOSA(S) 55 %. 40-130 1 05/09/24 08:00 05/11/24 18:05 754-91-6 13C9-PFNA (S) 66 %. 40-130 1 05/09/24 08:00 05/11/24 18:05 375-95-1 d3-McFOSAA (S) 63 %. 40-170 1 05/09/24 08:00 05/11/24 18:05 2355-31-9 d3-NMeFOSA (S) 45 %. 10-130 1 05/09/24 08:00 05/11/24 18:05 31506-32-8 d5-EtFOSAA (S) 61 %. 25-135 1 05/09/24 08:00 05/11/24 18:05 2991-50-6 d5-NEtFOSA (S) 45 %. 10-130 1 05/09/24 08:00 05/11/24 18:05 4151-50-2 d7-NMeFOSE (S) 54 %. 10-130 1 05/09/24 08:00 05/11/24 18:05 24448-09-7 d9-NEtFOSE (S) 60 %. 10-130 1 05/09/24 08:00 05/11/24 18:05 1691-99-2 13C2-PFTA (S) 59 %. 10-130 1 05/09/24 08:00 05/11/24 18:05 13C7-PFUdA (S) 58 %. 30-130 1 05/09/24 08:00 05/11/24 18:05 2058-94-8 13C24:2FTS (S) 76 %. 40-200 1 05/09/24 08:00 05/11/24 18:05 13C26:2FTS (S) 77 %. 40-200 1 05/09/24 08:00 05/11/24 18:05 13C28:2FTS (S) 68 %. 40-300 1 05/09/24 08:00 05/11/24 18:05 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-MW-3 Lab ID: 92726234004 Collected: 04/19/24 11:35 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis 11CI-PF30UdS ND ng/L 4.2 0.82 1 05/09/24 08:00 05/11/24 18:20 763051-92-9 3:3 FTCA ND ng/L 5.3 2.4 1 05/09/24 08:00 05/11/24 18:20 356-02-5 4:2 FTS ND ng/L 4.2 0.51 1 05/09/24 08:00 05/11/24 18:20 757124-72-4 5:3 FTCA ND ng/L 26.3 5.1 1 05/09/24 08:00 05/11/24 18:20 914637-49-3 6:2 FTS ND ng/L 4.2 1.0 1 05/09/24 08:00 05/11/24 18:20 27619-97-2 7:3 FTCA ND ng/L 26.3 5.5 1 05/09/24 08:00 05/11/24 18:20 812-70-4 8:2 FTS ND ng/L 4.2 1.1 1 05/09/24 08:00 05/11/24 18:20 39108-34-4 9CI-PF30NS ND ng/L 4.2 0.86 1 05/09/24 08:00 05/11/24 18:20 756426-58-1 ADONA ND ng/L 4.2 0.62 1 05/09/24 08:00 05/11/24 18:20 919005-14-4 HFPO-DA ND ng/L 4.2 0.82 1 05/09/24 08:00 05/11/24 18:20 13252-13-6 NEtFOSAA ND ng/L 1.1 0.37 1 05/09/24 08:00 05/11/24 18:20 2991-50-6 NEtFOSA ND ng/L 1.1 0.27 1 05/09/24 08:00 05/11/24 18:20 4151-50-2 NEtFOSE ND ng/L 10.5 3.4 1 05/09/24 08:00 05/11/24 18:20 1691-99-2 NFDHA ND ng/L 2.1 0.59 1 05/09/24 08:00 05/11/24 18:20 151772-58-6 NMeFOSAA ND ng/L 1.1 0.34 1 05/09/24 08:00 05/11/24 18:20 2355-31-9 NMeFOSA ND ng/L 1.1 0.28 1 05/09/24 08:00 05/11/24 18:20 31506-32-8 NMeFOSE ND ng/L 10.5 2.8 1 05/09/24 08:00 05/11/24 18:20 24448-09-7 PFBS 1.1 ng/L 1.1 0.34 1 05/09/24 08:00 05/11/24 18:20 375-73-5 PFDA ND ng/L 1.1 0.19 1 05/09/24 08:00 05/11/24 18:20 335-76-2 PFHxA 5.3 ng/L 1.1 0.16 1 05/09/24 08:00 05/11/24 18:20 307-24-4 PFBA 3.3J ng/L 4.2 0.64 1 05/09/24 08:00 05/11/24 18:20 375-22-4 PFDS ND ng/L 1.1 0.28 1 05/09/24 08:00 05/11/24 18:20 335-77-3 PFDoS ND ng/L 1.1 0.29 1 05/09/24 08:00 05/11/24 18:20 79780-39-5 PFEESA ND ng/L 2.1 0.34 1 05/09/24 08:00 05/11/24 18:20 113507-82-7 PFHpS ND ng/L 1.1 0.25 1 05/09/24 08:00 05/11/24 18:20 375-92-8 PFMBA ND ng/L 2.1 0.33 1 05/09/24 08:00 05/11/24 18:20 863090-89-5 PFMPA ND ng/L 2.1 0.51 1 05/09/24 08:00 05/11/24 18:20 377-73-1 PFNS ND ng/L 1.1 0.25 1 05/09/24 08:00 05/11/24 18:20 68259-12-1 PFOSA ND ng/L 1.1 0.25 1 05/09/24 08:00 05/11/24 18:20 754-91-6 PFPeA 4.7 ng/L 2.1 0.31 1 05/09/24 08:00 05/11/24 18:20 2706-90-3 PFPeS 0.35J ng/L 1.1 0.19 1 05/09/24 08:00 05/11/24 18:20 2706-91-4 PFDoA ND ng/L 1.1 0.23 1 05/09/24 08:00 05/11/24 18:20 307-55-1 PFHpA 1.8 ng/L 1.1 0.22 1 05/09/24 08:00 05/11/24 18:20 375-85-9 PFHxS 1.3 ng/L 1.1 0.27 1 05/09/24 08:00 05/11/24 18:20 355-46-4 PFNA 0.39J ng/L 1.1 0.24 1 05/09/24 08:00 05/11/24 18:20 375-95-1 PFOS 2.3 ng/L 1.1 0.18 1 05/09/24 08:00 05/11/24 18:20 1763-23-1 PFOA 4.3 ng/L 1.1 0.36 1 05/09/24 08:00 05/11/24 18:20 335-67-1 PFTeDA ND ng/L 1.1 0.30 1 05/09/24 08:00 05/11/24 18:20 376-06-7 PFTrDA ND ng/L 1.1 0.21 1 05/09/24 08:00 05/11/24 18:20 72629-94-8 PFUnA ND ng/L 1.1 0.27 1 05/09/24 08:00 05/11/24 18:20 2058-94-8 Surrogates 13C2-PFDoA (S) 73 %. 10-130 1 05/09/24 08:00 05/11/24 18:20 13C3HFPO-DA (S) 81 %. 40-130 1 05/09/24 08:00 05/11/24 18:20 13C3-PFBS (S) 88 %. 40-135 1 05/09/24 08:00 05/11/24 18:20 375-73-5 13C3-PFHxS (S) 87 %. 40-130 1 05/09/24 08:00 05/11/24 18:20 355-46-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-MW-3 Lab ID: 92726234004 Collected: 04/19/24 11:35 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis Surrogates 13C4-PFBA (S) 79 %. 5-130 1 05/09/24 08:00 05/11/24 18:20 375-22-4 13C4-PFHpA (S) 83 %. 40-130 1 05/09/24 08:00 05/11/24 18:20 375-85-9 13C5-PFHxA (S) 81 %. 40-130 1 05/09/24 08:00 05/11/24 18:20 307-24-4 13C5-PFPeA (S) 85 %. 40-130 1 05/09/24 08:00 05/11/24 18:20 2706-90-3 13C6-PFDA (S) 80 %. 40-130 1 05/09/24 08:00 05/11/24 18:20 335-76-2 13C8-PFDA (S) 78 %. 40-130 1 05/09/24 08:00 05/11/24 18:20 335-67-1 13C8-PFOS (S) 81 %. 40-130 1 05/09/24 08:00 05/11/24 18:20 1763-23-1 13C8-PFOSA(S) 71 %. 40-130 1 05/09/24 08:00 05/11/24 18:20 754-91-6 13C9-PFNA (S) 81 %. 40-130 1 05/09/24 08:00 05/11/24 18:20 375-95-1 d3-McFOSAA (S) 78 %. 40-170 1 05/09/24 08:00 05/11/24 18:20 2355-31-9 d3-NMeFOSA (S) 53 %. 10-130 1 05/09/24 08:00 05/11/24 18:20 31506-32-8 d5-EtFOSAA (S) 79 %. 25-135 1 05/09/24 08:00 05/11/24 18:20 2991-50-6 d5-NEtFOSA (S) 55 %. 10-130 1 05/09/24 08:00 05/11/24 18:20 4151-50-2 d7-NMeFOSE (S) 70 %. 10-130 1 05/09/24 08:00 05/11/24 18:20 24448-09-7 d9-NEtFOSE (S) 75 %. 10-130 1 05/09/24 08:00 05/11/24 18:20 1691-99-2 13C2-PFTA (S) 73 %. 10-130 1 05/09/24 08:00 05/11/24 18:20 13C7-PFUdA (S) 82 %. 30-130 1 05/09/24 08:00 05/11/24 18:20 2058-94-8 13C24:2FTS (S) 94 %. 40-200 1 05/09/24 08:00 05/11/24 18:20 13C26:2FTS (S) 87 %. 40-200 1 05/09/24 08:00 05/11/24 18:20 13C28:2FTS (S) 85 %. 40-300 1 05/09/24 08:00 05/11/24 18:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-MW-5 Lab ID: 92726234005 Collected: 04/19/24 10:00 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis 11CI-PF30UdS ND ng/L 40.9 8.0 1 05/09/24 08:00 05/11/24 19:07 763051-92-9 3:3 FTCA ND ng/L 51.1 23.8 1 05/09/24 08:00 05/11/24 19:07 356-02-5 4:2 FTS ND ng/L 40.9 4.9 1 05/09/24 08:00 05/11/24 19:07 757124-72-4 5:3 FTCA 81.2J ng/L 256 49.4 1 05/09/24 08:00 05/11/24 19:07 914637-49-3 6:2 FTS ND ng/L 40.9 10 1 05/09/24 08:00 05/11/24 19:07 27619-97-2 7:3 FTCA ND ng/L 256 53.5 1 05/09/24 08:00 05/11/24 19:07 812-70-4 8:2 FTS ND ng/L 40.9 10.7 1 05/09/24 08:00 05/11/24 19:07 39108-34-4 9CI-PF30NS ND ng/L 40.9 8.4 1 05/09/24 08:00 05/11/24 19:07 756426-58-1 ADONA ND ng/L 40.9 6.0 1 05/09/24 08:00 05/11/24 19:07 919005-14-4 HFPO-DA ND ng/L 40.9 8.0 1 05/09/24 08:00 05/11/24 19:07 13252-13-6 NEtFOSAA ND ng/L 10.2 3.6 1 05/09/24 08:00 05/11/24 19:07 2991-50-6 NEtFOSA ND ng/L 10.2 2.6 1 05/09/24 08:00 05/11/24 19:07 4151-50-2 NEtFOSE ND ng/L 102 32.8 1 05/09/24 08:00 05/11/24 19:07 1691-99-2 NFDHA ND ng/L 20.4 5.8 1 05/09/24 08:00 05/11/24 19:07 151772-58-6 NMeFOSAA ND ng/L 10.2 3.3 1 05/09/24 08:00 05/11/24 19:07 2355-31-9 NMeFOSA ND ng/L 10.2 2.7 1 05/09/24 08:00 05/11/24 19:07 31506-32-8 NMeFOSE ND ng/L 102 27.3 1 05/09/24 08:00 05/11/24 19:07 24448-09-7 PFBS 9.81 ng/L 10.2 3.3 1 05/09/24 08:00 05/11/24 19:07 375-73-5 PFDA ND ng/L 10.2 1.8 1 05/09/24 08:00 05/11/24 19:07 335-76-2 PFHxA 33.2 ng/L 10.2 1.5 1 05/09/24 08:00 05/11/24 19:07 307-24-4 PFBA 11.3J ng/L 40.9 6.3 1 05/09/24 08:00 05/11/24 19:07 375-22-4 PFDS ND ng/L 10.2 2.7 1 05/09/24 08:00 05/11/24 19:07 335-77-3 PFDoS ND ng/L 10.2 2.8 1 05/09/24 08:00 05/11/24 19:07 79780-39-5 PFEESA ND ng/L 20.4 3.3 1 05/09/24 08:00 05/11/24 19:07 113507-82-7 PFHpS ND ng/L 10.2 2.4 1 05/09/24 08:00 05/11/24 19:07 375-92-8 PFMBA ND ng/L 20.4 3.2 1 05/09/24 08:00 05/11/24 19:07 863090-89-5 PFMPA ND ng/L 20.4 4.9 1 05/09/24 08:00 05/11/24 19:07 377-73-1 PFNS ND ng/L 10.2 2.5 1 05/09/24 08:00 05/11/24 19:07 68259-12-1 PFOSA ND ng/L 10.2 2.4 1 05/09/24 08:00 05/11/24 19:07 754-91-6 PFPeA 115.0.1 ng/L 20.4 3.1 1 05/09/24 08:00 05/11/24 19:07 2706-90-3 PFPeS 6.5J ng/L 10.2 1.9 1 05/09/24 08:00 05/11/24 19:07 2706-91-4 PFDoA ND ng/L 10.2 2.3 1 05/09/24 08:00 05/11/24 19:07 307-55-1 PFHpA 15.5 ng/L 10.2 2.2 1 05/09/24 08:00 05/11/24 19:07 375-85-9 PFHxS 18.2 ng/L 10.2 2.6 1 05/09/24 08:00 05/11/24 19:07 355-46-4 PFNA ND ng/L 10.2 2.4 1 05/09/24 08:00 05/11/24 19:07 375-95-1 PFOS ND ng/L 10.2 1.8 1 05/09/24 08:00 05/11/24 19:07 1763-23-1 PFOA 34.7 ng/L 10.2 3.5 1 05/09/24 08:00 05/11/24 19:07 335-67-1 PFTeDA ND ng/L 10.2 2.9 1 05/09/24 08:00 05/11/24 19:07 376-06-7 PFTrDA ND ng/L 10.2 2.0 1 05/09/24 08:00 05/11/24 19:07 72629-94-8 PFUnA ND ng/L 10.2 2.6 1 05/09/24 08:00 05/11/24 19:07 2058-94-8 Surrogates 13C2-PFDoA (S) 73 %. 10-130 1 05/09/24 08:00 05/11/24 19:07 13C3HFPO-DA (S) 75 %. 40-130 1 05/09/24 08:00 05/11/24 19:07 13C3-PFBS (S) 82 %. 40-135 1 05/09/24 08:00 05/11/24 19:07 375-73-5 13C3-PFHxS (S) 80 %. 40-130 1 05/09/24 08:00 05/11/24 19:07 355-46-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-MW-5 Lab ID: 92726234005 Collected: 04/19/24 10:00 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis Surrogates 13C4-PFBA (S) 79 %. 5-130 1 05/09/24 08:00 05/11/24 19:07 375-22-4 13C4-PFHpA (S) 77 %. 40-130 1 05/09/24 08:00 05/11/24 19:07 375-85-9 13C5-PFHxA (S) 77 %. 40-130 1 05/09/24 08:00 05/11/24 19:07 307-24-4 13C5-PFPeA (S) 80 %. 40-130 1 05/09/24 08:00 05/11/24 19:07 2706-90-3 13C6-PFDA (S) 76 %. 40-130 1 05/09/24 08:00 05/11/24 19:07 335-76-2 13C8-PFDA (S) 77 %. 40-130 1 05/09/24 08:00 05/11/24 19:07 335-67-1 13C8-PFOS (S) 80 %. 40-130 1 05/09/24 08:00 05/11/24 19:07 1763-23-1 13C8-PFOSA(S) 71 %. 40-130 1 05/09/24 08:00 05/11/24 19:07 754-91-6 13C9-PFNA (S) 77 %. 40-130 1 05/09/24 08:00 05/11/24 19:07 375-95-1 d3-McFOSAA (S) 82 %. 40-170 1 05/09/24 08:00 05/11/24 19:07 2355-31-9 d3-NMeFOSA (S) 59 %. 10-130 1 05/09/24 08:00 05/11/24 19:07 31506-32-8 d5-EtFOSAA (S) 81 %. 25-135 1 05/09/24 08:00 05/11/24 19:07 2991-50-6 d5-NEtFOSA (S) 59 %. 10-130 1 05/09/24 08:00 05/11/24 19:07 4151-50-2 d7-NMeFOSE (S) 72 %. 10-130 1 05/09/24 08:00 05/11/24 19:07 24448-09-7 d9-NEtFOSE (S) 79 %. 10-130 1 05/09/24 08:00 05/11/24 19:07 1691-99-2 13C2-PFTA (S) 76 %. 10-130 1 05/09/24 08:00 05/11/24 19:07 13C7-PFUdA (S) 75 %. 30-130 1 05/09/24 08:00 05/11/24 19:07 2058-94-8 13C24:2FTS (S) 91 %. 40-200 1 05/09/24 08:00 05/11/24 19:07 13C26:2FTS (S) 90 %. 40-200 1 05/09/24 08:00 05/11/24 19:07 13C28:2FTS (S) 87 %. 40-300 1 05/09/24 08:00 05/11/24 19:07 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-MW-6 Lab ID: 92726234006 Collected: 04/19/24 12:35 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis 11CI-PF30UdS ND ng/L 42.0 8.2 1 05/09/24 08:00 05/11/24 19:23 763051-92-9 3:3 FTCA 33AJ ng/L 52.5 24.5 1 05/09/24 08:00 05/11/24 19:23 356-02-5 4:2 FTS ND ng/L 42.0 5.1 1 05/09/24 08:00 05/11/24 19:23 757124-72-4 5:3 FTCA 363 ng/L 263 50.7 1 05/09/24 08:00 05/11/24 19:23 914637-49-3 6:2 FTS ND ng/L 42.0 10.3 1 05/09/24 08:00 05/11/24 19:23 27619-97-2 7:3 FTCA ND ng/L 263 54.9 1 05/09/24 08:00 05/11/24 19:23 812-70-4 8:2 FTS ND ng/L 42.0 11.0 1 05/09/24 08:00 05/11/24 19:23 39108-34-4 9CI-PF30NS ND ng/L 42.0 8.6 1 05/09/24 08:00 05/11/24 19:23 756426-58-1 ADONA ND ng/L 42.0 6.2 1 05/09/24 08:00 05/11/24 19:23 919005-14-4 HFPO-DA ND ng/L 42.0 8.2 1 05/09/24 08:00 05/11/24 19:23 13252-13-6 NEtFOSAA ND ng/L 10.5 3.7 1 05/09/24 08:00 05/11/24 19:23 2991-50-6 NEtFOSA ND ng/L 10.5 2.7 1 05/09/24 08:00 05/11/24 19:23 4151-50-2 NEtFOSE ND ng/L 105 33.7 1 05/09/24 08:00 05/11/24 19:23 1691-99-2 NFDHA ND ng/L 21.0 5.9 1 05/09/24 08:00 05/11/24 19:23 151772-58-6 NMeFOSAA ND ng/L 10.5 3.4 1 05/09/24 08:00 05/11/24 19:23 2355-31-9 NMeFOSA ND ng/L 10.5 2.8 1 05/09/24 08:00 05/11/24 19:23 31506-32-8 NMeFOSE ND ng/L 105 28.0 1 05/09/24 08:00 05/11/24 19:23 24448-09-7 PFBS 31.6 ng/L 10.5 3.4 1 05/09/24 08:00 05/11/24 19:23 375-73-5 PFDA ND ng/L 10.5 1.9 1 05/09/24 08:00 05/11/24 19:23 335-76-2 PFHxA 212 ng/L 10.5 1.6 1 05/09/24 08:00 05/11/24 19:23 307-24-4 PFBA 37.1J ng/L 42.0 6.4 1 05/09/24 08:00 05/11/24 19:23 375-22-4 PFDS ND ng/L 10.5 2.8 1 05/09/24 08:00 05/11/24 19:23 335-77-3 PFDoS ND ng/L 10.5 2.9 1 05/09/24 08:00 05/11/24 19:23 79780-39-5 PFEESA ND ng/L 21.0 3.4 1 05/09/24 08:00 05/11/24 19:23 113507-82-7 PFHpS ND ng/L 10.5 2.5 1 05/09/24 08:00 05/11/24 19:23 375-92-8 PFMBA ND ng/L 21.0 3.3 1 05/09/24 08:00 05/11/24 19:23 863090-89-5 PFMPA ND ng/L 21.0 5.1 1 05/09/24 08:00 05/11/24 19:23 377-73-1 PFNS ND ng/L 10.5 2.5 1 05/09/24 08:00 05/11/24 19:23 68259-12-1 PFOSA ND ng/L 10.5 2.5 1 05/09/24 08:00 05/11/24 19:23 754-91-6 PFPeA 64.4 ng/L 21.0 3.1 1 05/09/24 08:00 05/11/24 19:23 2706-90-3 PFPeS 26.9 ng/L 10.5 1.9 1 05/09/24 08:00 05/11/24 19:23 2706-91-4 PFDoA ND ng/L 10.5 2.3 1 05/09/24 08:00 05/11/24 19:23 307-55-1 PFHpA 59.5 ng/L 10.5 2.2 1 05/09/24 08:00 05/11/24 19:23 375-85-9 PFHxS 122 ng/L 10.5 2.7 1 05/09/24 08:00 05/11/24 19:23 355-46-4 PFNA ND ng/L 10.5 2.4 1 05/09/24 08:00 05/11/24 19:23 375-95-1 PFOS 13.4 ng/L 10.5 1.8 1 05/09/24 08:00 05/11/24 19:23 1763-23-1 PFOA 101 ng/L 10.5 3.6 1 05/09/24 08:00 05/11/24 19:23 335-67-1 PFTeDA ND ng/L 10.5 3.0 1 05/09/24 08:00 05/11/24 19:23 376-06-7 PFTrDA ND ng/L 10.5 2.1 1 05/09/24 08:00 05/11/24 19:23 72629-94-8 PFUnA ND ng/L 10.5 2.7 1 05/09/24 08:00 05/11/24 19:23 2058-94-8 Surrogates 13C2-PFDoA (S) 69 %. 10-130 1 05/09/24 08:00 05/11/24 19:23 13C3HFPO-DA (S) 69 %. 40-130 1 05/09/24 08:00 05/11/24 19:23 13C3-PFBS (S) 80 %. 40-135 1 05/09/24 08:00 05/11/24 19:23 375-73-5 13C3-PFHxS (S) 79 %. 40-130 1 05/09/24 08:00 05/11/24 19:23 355-46-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-MW-6 Lab ID: 92726234006 Collected: 04/19/24 12:35 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis Surrogates 13C4-PFBA (S) 70 %. 5-130 1 05/09/24 08:00 05/11/24 19:23 375-22-4 13C4-PFHpA (S) 72 %. 40-130 1 05/09/24 08:00 05/11/24 19:23 375-85-9 13C5-PFHxA (S) 73 %. 40-130 1 05/09/24 08:00 05/11/24 19:23 307-24-4 13C5-PFPeA (S) 73 %. 40-130 1 05/09/24 08:00 05/11/24 19:23 2706-90-3 13C6-PFDA (S) 73 %. 40-130 1 05/09/24 08:00 05/11/24 19:23 335-76-2 13C8-PFDA (S) 73 %. 40-130 1 05/09/24 08:00 05/11/24 19:23 335-67-1 13C8-PFOS (S) 75 %. 40-130 1 05/09/24 08:00 05/11/24 19:23 1763-23-1 13C8-PFOSA(S) 66 %. 40-130 1 05/09/24 08:00 05/11/24 19:23 754-91-6 13C9-PFNA (S) 74 %. 40-130 1 05/09/24 08:00 05/11/24 19:23 375-95-1 d3-McFOSAA (S) 76 %. 40-170 1 05/09/24 08:00 05/11/24 19:23 2355-31-9 d3-NMeFOSA (S) 58 %. 10-130 1 05/09/24 08:00 05/11/24 19:23 31506-32-8 d5-EtFOSAA (S) 76 %. 25-135 1 05/09/24 08:00 05/11/24 19:23 2991-50-6 d5-NEtFOSA (S) 58 %. 10-130 1 05/09/24 08:00 05/11/24 19:23 4151-50-2 d7-NMeFOSE (S) 69 %. 10-130 1 05/09/24 08:00 05/11/24 19:23 24448-09-7 d9-NEtFOSE (S) 75 %. 10-130 1 05/09/24 08:00 05/11/24 19:23 1691-99-2 13C2-PFTA (S) 73 %. 10-130 1 05/09/24 08:00 05/11/24 19:23 13C7-PFUdA (S) 73 %. 30-130 1 05/09/24 08:00 05/11/24 19:23 2058-94-8 13C24:2FTS (S) 106 %. 40-200 1 05/09/24 08:00 05/11/24 19:23 13C26:2FTS (S) 86 %. 40-200 1 05/09/24 08:00 05/11/24 19:23 13C28:2FTS (S) 84 %. 40-300 1 05/09/24 08:00 05/11/24 19:23 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-MW-7 Lab ID: 92726234007 Collected: 04/19/24 13:30 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis 11CI-PF30UdS ND ng/L 4.2 0.82 1 05/09/24 08:12 05/10/24 23:36 763051-92-9 3:3 FTCA ND ng/L 5.2 2.4 1 05/09/24 08:12 05/10/24 23:36 356-02-5 4:2 FTS ND ng/L 4.2 0.51 1 05/09/24 08:12 05/10/24 23:36 757124-72-4 5:3 FTCA ND ng/L 26.2 5.1 1 05/09/24 08:12 05/10/24 23:36 914637-49-3 6:2 FTS ND ng/L 4.2 1.0 1 05/09/24 08:12 05/10/24 23:36 27619-97-2 7:3 FTCA ND ng/L 26.2 5.5 1 05/09/24 08:12 05/10/24 23:36 812-70-4 8:2 FTS ND ng/L 4.2 1.1 1 05/09/24 08:12 05/10/24 23:36 39108-34-4 9CI-PF30NS ND ng/L 4.2 0.86 1 05/09/24 08:12 05/10/24 23:36 756426-58-1 ADONA ND ng/L 4.2 0.62 1 05/09/24 08:12 05/10/24 23:36 919005-14-4 HFPO-DA ND ng/L 4.2 0.82 1 05/09/24 08:12 05/10/24 23:36 13252-13-6 NEtFOSAA ND ng/L 1.0 0.37 1 05/09/24 08:12 05/10/24 23:36 2991-50-6 NEtFOSA ND ng/L 1.0 0.27 1 05/09/24 08:12 05/10/24 23:36 4151-50-2 NEtFOSE ND ng/L 10.5 3.4 1 05/09/24 08:12 05/10/24 23:36 1691-99-2 NFDHA ND ng/L 2.1 0.59 1 05/09/24 08:12 05/10/24 23:36 151772-58-6 NMeFOSAA ND ng/L 1.0 0.33 1 05/09/24 08:12 05/10/24 23:36 2355-31-9 NMeFOSA ND ng/L 1.0 0.28 1 05/09/24 08:12 05/10/24 23:36 31506-32-8 NMeFOSE ND ng/L 10.5 2.8 1 05/09/24 08:12 05/10/24 23:36 24448-09-7 PFBS 1.5 ng/L 1.0 0.34 1 05/09/24 08:12 05/10/24 23:36 375-73-5 PFDA ND ng/L 1.0 0.19 1 05/09/24 08:12 05/10/24 23:36 335-76-2 PFHxA 0.48J ng/L 1.0 0.16 1 05/09/24 08:12 05/10/24 23:36 307-24-4 PFBA ND ng/L 4.2 0.64 1 05/09/24 08:12 05/10/24 23:36 375-22-4 PFDS ND ng/L 1.0 0.28 1 05/09/24 08:12 05/10/24 23:36 335-77-3 PFDoS ND ng/L 1.0 0.29 1 05/09/24 08:12 05/10/24 23:36 79780-39-5 PFEESA ND ng/L 2.1 0.34 1 05/09/24 08:12 05/10/24 23:36 113507-82-7 PFHpS ND ng/L 1.0 0.25 1 05/09/24 08:12 05/10/24 23:36 375-92-8 PFMBA ND ng/L 2.1 0.33 1 05/09/24 08:12 05/10/24 23:36 863090-89-5 PFMPA ND ng/L 2.1 0.51 1 05/09/24 08:12 05/10/24 23:36 377-73-1 PFNS ND ng/L 1.0 0.25 1 05/09/24 08:12 05/10/24 23:36 68259-12-1 PFOSA ND ng/L 1.0 0.25 1 05/09/24 08:12 05/10/24 23:36 754-91-6 PFPeA 0.38J ng/L 2.1 0.31 1 05/09/24 08:12 05/10/24 23:36 2706-90-3 PFPeS 0.84J ng/L 1.0 0.19 1 05/09/24 08:12 05/10/24 23:36 2706-91-4 PFDoA ND ng/L 1.0 0.23 1 05/09/24 08:12 05/10/24 23:36 307-55-1 PFHpA 0.64J ng/L 1.0 0.22 1 05/09/24 08:12 05/10/24 23:36 375-85-9 PFHxS 2.0 ng/L 1.0 0.27 1 05/09/24 08:12 05/10/24 23:36 355-46-4 PFNA ND ng/L 1.0 0.24 1 05/09/24 08:12 05/10/24 23:36 375-95-1 PFOS 0.29J ng/L 1.0 0.18 1 05/09/24 08:12 05/10/24 23:36 1763-23-1 PFOA 2.2 ng/L 1.0 0.36 1 05/09/24 08:12 05/10/24 23:36 335-67-1 PFTeDA ND ng/L 1.0 0.30 1 05/09/24 08:12 05/10/24 23:36 376-06-7 PFTrDA ND ng/L 1.0 0.21 1 05/09/24 08:12 05/10/24 23:36 72629-94-8 PFUnA ND ng/L 1.0 0.27 1 05/09/24 08:12 05/10/24 23:36 2058-94-8 Surrogates 13C2-PFDoA (S) 70 %. 10-130 1 05/09/24 08:12 05/10/24 23:36 13C3HFPO-DA (S) 76 %. 40-130 1 05/09/24 08:12 05/10/24 23:36 13C3-PFBS (S) 85 %. 40-135 1 05/09/24 08:12 05/10/24 23:36 375-73-5 13C3-PFHxS (S) 82 %. 40-130 1 05/09/24 08:12 05/10/24 23:36 355-46-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-MW-7 Lab ID: 92726234007 Collected: 04/19/24 13:30 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis Surrogates 13C4-PFBA (S) 78 %. 5-130 1 05/09/24 08:12 05/10/24 23:36 375-22-4 13C4-PFHpA (S) 79 %. 40-130 1 05/09/24 08:12 05/10/24 23:36 375-85-9 13C5-PFHxA (S) 78 %. 40-130 1 05/09/24 08:12 05/10/24 23:36 307-24-4 13C5-PFPeA (S) 81 %. 40-130 1 05/09/24 08:12 05/10/24 23:36 2706-90-3 13C6-PFDA (S) 79 %. 40-130 1 05/09/24 08:12 05/10/24 23:36 335-76-2 13C8-PFDA (S) 75 %. 40-130 1 05/09/24 08:12 05/10/24 23:36 335-67-1 13C8-PFOS (S) 81 %. 40-130 1 05/09/24 08:12 05/10/24 23:36 1763-23-1 13C8-PFOSA (S) 70 %. 40-130 1 05/09/24 08:12 05/10/24 23:36 754-91-6 13C9-PFNA (S) 79 %. 40-130 1 05/09/24 08:12 05/10/24 23:36 375-95-1 d3-McFOSAA (S) 77 %. 40-170 1 05/09/24 08:12 05/10/24 23:36 2355-31-9 d3-NMeFOSA (S) 61 %. 10-130 1 05/09/24 08:12 05/10/24 23:36 31506-32-8 d5-EtFOSAA (S) 73 %. 25-135 1 05/09/24 08:12 05/10/24 23:36 2991-50-6 d5-NEtFOSA (S) 61 %. 10-130 1 05/09/24 08:12 05/10/24 23:36 4151-50-2 d7-NMeFOSE (S) 70 %. 10-130 1 05/09/24 08:12 05/10/24 23:36 24448-09-7 d9-NEtFOSE (S) 74 %. 10-130 1 05/09/24 08:12 05/10/24 23:36 1691-99-2 13C2-PFTA (S) 71 %. 10-130 1 05/09/24 08:12 05/10/24 23:36 13C7-PFUdA (S) 76 %. 30-130 1 05/09/24 08:12 05/10/24 23:36 2058-94-8 13C24:2FTS (S) 84 %. 40-200 1 05/09/24 08:12 05/10/24 23:36 13C26:2FTS (S) 82 %. 40-200 1 05/09/24 08:12 05/10/24 23:36 13C28:2FTS (S) 83 %. 40-300 1 05/09/24 08:12 05/10/24 23:36 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-MW-8 Lab ID: 92726234008 Collected: 04/19/24 10:45 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis 11CI-PF30UdS ND ng/L 4.1 0.79 1 05/09/24 08:12 05/10/24 23:52 763051-92-9 3:3 FTCA ND ng/L 5.1 2.4 1 05/09/24 08:12 05/10/24 23:52 356-02-5 4:2 FTS ND ng/L 4.1 0.49 1 05/09/24 08:12 05/10/24 23:52 757124-72-4 5:3 FTCA ND ng/L 25.4 4.9 1 05/09/24 08:12 05/10/24 23:52 914637-49-3 6:2 FTS ND ng/L 4.1 0.99 1 05/09/24 08:12 05/10/24 23:52 27619-97-2 7:3 FTCA ND ng/L 25.4 5.3 1 05/09/24 08:12 05/10/24 23:52 812-70-4 8:2 FTS ND ng/L 4.1 1.1 1 05/09/24 08:12 05/10/24 23:52 39108-34-4 9CI-PF30NS ND ng/L 4.1 0.83 1 05/09/24 08:12 05/10/24 23:52 756426-58-1 ADONA ND ng/L 4.1 0.59 1 05/09/24 08:12 05/10/24 23:52 919005-14-4 HFPO-DA ND ng/L 4.1 0.79 1 05/09/24 08:12 05/10/24 23:52 13252-13-6 NEtFOSAA ND ng/L 1.0 0.35 1 05/09/24 08:12 05/10/24 23:52 2991-50-6 NEtFOSA ND ng/L 1.0 0.26 1 05/09/24 08:12 05/10/24 23:52 4151-50-2 NEtFOSE ND ng/L 10.1 3.3 1 05/09/24 08:12 05/10/24 23:52 1691-99-2 NFDHA ND ng/L 2.0 0.57 1 05/09/24 08:12 05/10/24 23:52 151772-58-6 NMeFOSAA ND ng/L 1.0 0.32 1 05/09/24 08:12 05/10/24 23:52 2355-31-9 NMeFOSA ND ng/L 1.0 0.27 1 05/09/24 08:12 05/10/24 23:52 31506-32-8 NMeFOSE ND ng/L 10.1 2.7 1 05/09/24 08:12 05/10/24 23:52 24448-09-7 PFBS ND ng/L 1.0 0.32 1 05/09/24 08:12 05/10/24 23:52 375-73-5 PFDA ND ng/L 1.0 0.18 1 05/09/24 08:12 05/10/24 23:52 335-76-2 PFHxA ND ng/L 1.0 0.15 1 05/09/24 08:12 05/10/24 23:52 307-24-4 PFBA ND ng/L 4.1 0.62 1 05/09/24 08:12 05/10/24 23:52 375-22-4 PFDS ND ng/L 1.0 0.27 1 05/09/24 08:12 05/10/24 23:52 335-77-3 PFDoS ND ng/L 1.0 0.28 1 05/09/24 08:12 05/10/24 23:52 79780-39-5 PFEESA ND ng/L 2.0 0.32 1 05/09/24 08:12 05/10/24 23:52 113507-82-7 PFHpS ND ng/L 1.0 0.24 1 05/09/24 08:12 05/10/24 23:52 375-92-8 PFMBA ND ng/L 2.0 0.32 1 05/09/24 08:12 05/10/24 23:52 863090-89-5 PFMPA ND ng/L 2.0 0.49 1 05/09/24 08:12 05/10/24 23:52 377-73-1 PFNS ND ng/L 1.0 0.24 1 05/09/24 08:12 05/10/24 23:52 68259-12-1 PFOSA ND ng/L 1.0 0.24 1 05/09/24 08:12 05/10/24 23:52 754-91-6 PFPeA ND ng/L 2.0 0.30 1 05/09/24 08:12 05/10/24 23:52 2706-90-3 PFPeS ND ng/L 1.0 0.18 1 05/09/24 08:12 05/10/24 23:52 2706-91-4 PFDoA ND ng/L 1.0 0.23 1 05/09/24 08:12 05/10/24 23:52 307-55-1 PFHpA ND ng/L 1.0 0.22 1 05/09/24 08:12 05/10/24 23:52 375-85-9 PFHxS ND ng/L 1.0 0.26 1 05/09/24 08:12 05/10/24 23:52 355-46-4 PFNA ND ng/L 1.0 0.24 1 05/09/24 08:12 05/10/24 23:52 375-95-1 PFOS ND ng/L 1.0 0.18 1 05/09/24 08:12 05/10/24 23:52 1763-23-1 PFOA ND ng/L 1.0 0.35 1 05/09/24 08:12 05/10/24 23:52 335-67-1 PFTeDA ND ng/L 1.0 0.29 1 05/09/24 08:12 05/10/24 23:52 376-06-7 PFTrDA ND ng/L 1.0 0.20 1 05/09/24 08:12 05/10/24 23:52 72629-94-8 PFUnA ND ng/L 1.0 0.26 1 05/09/24 08:12 05/10/24 23:52 2058-94-8 Surrogates 13C2-PFDoA (S) 70 %. 10-130 1 05/09/24 08:12 05/10/24 23:52 13C3HFPO-DA (S) 81 %. 40-130 1 05/09/24 08:12 05/10/24 23:52 13C3-PFBS (S) 84 %. 40-135 1 05/09/24 08:12 05/10/24 23:52 375-73-5 13C3-PFHxS (S) 83 %. 40-130 1 05/09/24 08:12 05/10/24 23:52 355-46-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-MW-8 Lab ID: 92726234008 Collected: 04/19/24 10:45 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis Surrogates 13C4-PFBA (S) 81 %. 5-130 1 05/09/24 08:12 05/10/24 23:52 375-22-4 13C4-PFHpA (S) 81 %. 40-130 1 05/09/24 08:12 05/10/24 23:52 375-85-9 13C5-PFHxA (S) 83 %. 40-130 1 05/09/24 08:12 05/10/24 23:52 307-24-4 13C5-PFPeA (S) 85 %. 40-130 1 05/09/24 08:12 05/10/24 23:52 2706-90-3 13C6-PFDA (S) 80 %. 40-130 1 05/09/24 08:12 05/10/24 23:52 335-76-2 13C8-PFDA (S) 83 %. 40-130 1 05/09/24 08:12 05/10/24 23:52 335-67-1 13C8-PFOS (S) 81 %. 40-130 1 05/09/24 08:12 05/10/24 23:52 1763-23-1 13C8-PFOSA (S) 70 %. 40-130 1 05/09/24 08:12 05/10/24 23:52 754-91-6 13C9-PFNA (S) 81 %. 40-130 1 05/09/24 08:12 05/10/24 23:52 375-95-1 d3-McFOSAA (S) 71 %. 40-170 1 05/09/24 08:12 05/10/24 23:52 2355-31-9 d3-NMeFOSA (S) 63 %. 10-130 1 05/09/24 08:12 05/10/24 23:52 31506-32-8 d5-EtFOSAA (S) 71 %. 25-135 1 05/09/24 08:12 05/10/24 23:52 2991-50-6 d5-NEtFOSA (S) 62 %. 10-130 1 05/09/24 08:12 05/10/24 23:52 4151-50-2 d7-NMeFOSE (S) 70 %. 10-130 1 05/09/24 08:12 05/10/24 23:52 24448-09-7 d9-NEtFOSE (S) 75 %. 10-130 1 05/09/24 08:12 05/10/24 23:52 1691-99-2 13C2-PFTA (S) 68 %. 10-130 1 05/09/24 08:12 05/10/24 23:52 13C7-PFUdA (S) 75 %. 30-130 1 05/09/24 08:12 05/10/24 23:52 2058-94-8 13C24:2FTS (S) 85 %. 40-200 1 05/09/24 08:12 05/10/24 23:52 13C26:2FTS (S) 82 %. 40-200 1 05/09/24 08:12 05/10/24 23:52 13C28:2FTS (S) 76 %. 40-300 1 05/09/24 08:12 05/10/24 23:52 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-MW-9S Lab ID: 92726234009 Collected: 04/19/24 10:50 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis 11CI-PF30UdS ND ng/L 4.1 0.81 1 05/09/24 08:12 05/11/24 00:07 763051-92-9 3:3 FTCA ND ng/L 5.2 2.4 1 05/09/24 08:12 05/11/24 00:07 356-02-5 4:2 FTS ND ng/L 4.1 0.50 1 05/09/24 08:12 05/11/24 00:07 757124-72-4 5:3 FTCA ND ng/L 25.9 5.0 1 05/09/24 08:12 05/11/24 00:07 914637-49-3 6:2 FTS ND ng/L 4.1 1.0 1 05/09/24 08:12 05/11/24 00:07 27619-97-2 7:3 FTCA ND ng/L 25.9 5.4 1 05/09/24 08:12 05/11/24 00:07 812-70-4 8:2 FTS ND ng/L 4.1 1.1 1 05/09/24 08:12 05/11/24 00:07 39108-34-4 9CI-PF30NS ND ng/L 4.1 0.85 1 05/09/24 08:12 05/11/24 00:07 756426-58-1 ADONA ND ng/L 4.1 0.61 1 05/09/24 08:12 05/11/24 00:07 919005-14-4 HFPO-DA ND ng/L 4.1 0.81 1 05/09/24 08:12 05/11/24 00:07 13252-13-6 NEtFOSAA ND ng/L 1.0 0.36 1 05/09/24 08:12 05/11/24 00:07 2991-50-6 NEtFOSA ND ng/L 1.0 0.27 1 05/09/24 08:12 05/11/24 00:07 4151-50-2 NEtFOSE ND ng/L 10.4 3.3 1 05/09/24 08:12 05/11/24 00:07 1691-99-2 NFDHA ND ng/L 2.1 0.59 1 05/09/24 08:12 05/11/24 00:07 151772-58-6 NMeFOSAA ND ng/L 1.0 0.33 1 05/09/24 08:12 05/11/24 00:07 2355-31-9 NMeFOSA ND ng/L 1.0 0.28 1 05/09/24 08:12 05/11/24 00:07 31506-32-8 NMeFOSE ND ng/L 10.4 2.8 1 05/09/24 08:12 05/11/24 00:07 24448-09-7 PFBS ND ng/L 1.0 0.33 1 05/09/24 08:12 05/11/24 00:07 375-73-5 PFDA ND ng/L 1.0 0.18 1 05/09/24 08:12 05/11/24 00:07 335-76-2 PFHxA ND ng/L 1.0 0.16 1 05/09/24 08:12 05/11/24 00:07 307-24-4 PFBA ND ng/L 4.1 0.64 1 05/09/24 08:12 05/11/24 00:07 375-22-4 PFDS ND ng/L 1.0 0.27 1 05/09/24 08:12 05/11/24 00:07 335-77-3 PFDoS ND ng/L 1.0 0.29 1 05/09/24 08:12 05/11/24 00:07 79780-39-5 PFEESA ND ng/L 2.1 0.33 1 05/09/24 08:12 05/11/24 00:07 113507-82-7 PFHpS ND ng/L 1.0 0.25 1 05/09/24 08:12 05/11/24 00:07 375-92-8 PFMBA ND ng/L 2.1 0.33 1 05/09/24 08:12 05/11/24 00:07 863090-89-5 PFMPA ND ng/L 2.1 0.50 1 05/09/24 08:12 05/11/24 00:07 377-73-1 PFNS ND ng/L 1.0 0.25 1 05/09/24 08:12 05/11/24 00:07 68259-12-1 PFOSA ND ng/L 1.0 0.25 1 05/09/24 08:12 05/11/24 00:07 754-91-6 PFPeA ND ng/L 2.1 0.31 1 05/09/24 08:12 05/11/24 00:07 2706-90-3 PFPeS ND ng/L 1.0 0.19 1 05/09/24 08:12 05/11/24 00:07 2706-91-4 PFDoA ND ng/L 1.0 0.23 1 05/09/24 08:12 05/11/24 00:07 307-55-1 PFHpA ND ng/L 1.0 0.22 1 05/09/24 08:12 05/11/24 00:07 375-85-9 PFHxS ND ng/L 1.0 0.27 1 05/09/24 08:12 05/11/24 00:07 355-46-4 PFNA ND ng/L 1.0 0.24 1 05/09/24 08:12 05/11/24 00:07 375-95-1 PFOS ND ng/L 1.0 0.18 1 05/09/24 08:12 05/11/24 00:07 1763-23-1 PFOA ND ng/L 1.0 0.35 1 05/09/24 08:12 05/11/24 00:07 335-67-1 PFTeDA ND ng/L 1.0 0.30 1 05/09/24 08:12 05/11/24 00:07 376-06-7 PFTrDA ND ng/L 1.0 0.21 1 05/09/24 08:12 05/11/24 00:07 72629-94-8 PFUnA ND ng/L 1.0 0.26 1 05/09/24 08:12 05/11/24 00:07 2058-94-8 Surrogates 13C2-PFDoA (S) 69 %. 10-130 1 05/09/24 08:12 05/11/24 00:07 13C3HFPO-DA (S) 79 %. 40-130 1 05/09/24 08:12 05/11/24 00:07 13C3-PFBS (S) 85 %. 40-135 1 05/09/24 08:12 05/11/24 00:07 375-73-5 13C3-PFHxS (S) 83 %. 40-130 1 05/09/24 08:12 05/11/24 00:07 355-46-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-MW-9S Lab ID: 92726234009 Collected: 04/19/24 10:50 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis Surrogates 13C4-PFBA (S) 80 %. 5-130 1 05/09/24 08:12 05/11/24 00:07 375-22-4 13C4-PFHpA (S) 81 %. 40-130 1 05/09/24 08:12 05/11/24 00:07 375-85-9 13C5-PFHxA (S) 80 %. 40-130 1 05/09/24 08:12 05/11/24 00:07 307-24-4 13C5-PFPeA (S) 83 %. 40-130 1 05/09/24 08:12 05/11/24 00:07 2706-90-3 13C6-PFDA (S) 79 %. 40-130 1 05/09/24 08:12 05/11/24 00:07 335-76-2 13C8-PFDA (S) 77 %. 40-130 1 05/09/24 08:12 05/11/24 00:07 335-67-1 13C8-PFOS (S) 79 %. 40-130 1 05/09/24 08:12 05/11/24 00:07 1763-23-1 13C8-PFOSA (S) 71 %. 40-130 1 05/09/24 08:12 05/11/24 00:07 754-91-6 13C9-PFNA (S) 80 %. 40-130 1 05/09/24 08:12 05/11/24 00:07 375-95-1 d3-McFOSAA (S) 75 %. 40-170 1 05/09/24 08:12 05/11/24 00:07 2355-31-9 d3-NMeFOSA (S) 59 %. 10-130 1 05/09/24 08:12 05/11/24 00:07 31506-32-8 d5-EtFOSAA (S) 73 %. 25-135 1 05/09/24 08:12 05/11/24 00:07 2991-50-6 d5-NEtFOSA (S) 58 %. 10-130 1 05/09/24 08:12 05/11/24 00:07 4151-50-2 d7-NMeFOSE (S) 69 %. 10-130 1 05/09/24 08:12 05/11/24 00:07 24448-09-7 d9-NEtFOSE (S) 74 %. 10-130 1 05/09/24 08:12 05/11/24 00:07 1691-99-2 13C2-PFTA (S) 71 %. 10-130 1 05/09/24 08:12 05/11/24 00:07 13C7-PFUdA (S) 74 %. 30-130 1 05/09/24 08:12 05/11/24 00:07 2058-94-8 13C24:2FTS (S) 87 %. 40-200 1 05/09/24 08:12 05/11/24 00:07 13C26:2FTS (S) 82 %. 40-200 1 05/09/24 08:12 05/11/24 00:07 13C28:2FTS (S) 86 %. 40-300 1 05/09/24 08:12 05/11/24 00:07 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-MW-9D Lab ID: 92726234010 Collected: 04/19/24 12:00 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis 11CI-PF30UdS ND ng/L 4.2 0.81 1 05/09/24 08:12 05/11/24 00:23 763051-92-9 3:3 FTCA ND ng/L 5.2 2.4 1 05/09/24 08:12 05/11/24 00:23 356-02-5 4:2 FTS ND ng/L 4.2 0.50 1 05/09/24 08:12 05/11/24 00:23 757124-72-4 5:3 FTCA ND ng/L 26.0 5.0 1 05/09/24 08:12 05/11/24 00:23 914637-49-3 6:2 FTS ND ng/L 4.2 1.0 1 05/09/24 08:12 05/11/24 00:23 27619-97-2 7:3 FTCA ND ng/L 26.0 5.4 1 05/09/24 08:12 05/11/24 00:23 812-70-4 8:2 FTS ND ng/L 4.2 1.1 1 05/09/24 08:12 05/11/24 00:23 39108-34-4 9CI-PF30NS ND ng/L 4.2 0.86 1 05/09/24 08:12 05/11/24 00:23 756426-58-1 ADONA ND ng/L 4.2 0.61 1 05/09/24 08:12 05/11/24 00:23 919005-14-4 HFPO-DA ND ng/L 4.2 0.81 1 05/09/24 08:12 05/11/24 00:23 13252-13-6 NEtFOSAA ND ng/L 1.0 0.36 1 05/09/24 08:12 05/11/24 00:23 2991-50-6 NEtFOSA ND ng/L 1.0 0.27 1 05/09/24 08:12 05/11/24 00:23 4151-50-2 NEtFOSE ND ng/L 10.4 3.3 1 05/09/24 08:12 05/11/24 00:23 1691-99-2 NFDHA ND ng/L 2.1 0.59 1 05/09/24 08:12 05/11/24 00:23 151772-58-6 NMeFOSAA ND ng/L 1.0 0.33 1 05/09/24 08:12 05/11/24 00:23 2355-31-9 NMeFOSA ND ng/L 1.0 0.28 1 05/09/24 08:12 05/11/24 00:23 31506-32-8 NMeFOSE ND ng/L 10.4 2.8 1 05/09/24 08:12 05/11/24 00:23 24448-09-7 PFBS ND ng/L 1.0 0.33 1 05/09/24 08:12 05/11/24 00:23 375-73-5 PFDA ND ng/L 1.0 0.19 1 05/09/24 08:12 05/11/24 00:23 335-76-2 PFHxA 0.24J ng/L 1.0 0.16 1 05/09/24 08:12 05/11/24 00:23 307-24-4 PFBA ND ng/L 4.2 0.64 1 05/09/24 08:12 05/11/24 00:23 375-22-4 PFDS ND ng/L 1.0 0.28 1 05/09/24 08:12 05/11/24 00:23 335-77-3 PFDoS ND ng/L 1.0 0.29 1 05/09/24 08:12 05/11/24 00:23 79780-39-5 PFEESA ND ng/L 2.1 0.33 1 05/09/24 08:12 05/11/24 00:23 113507-82-7 PFHpS ND ng/L 1.0 0.25 1 05/09/24 08:12 05/11/24 00:23 375-92-8 PFMBA ND ng/L 2.1 0.33 1 05/09/24 08:12 05/11/24 00:23 863090-89-5 PFMPA ND ng/L 2.1 0.50 1 05/09/24 08:12 05/11/24 00:23 377-73-1 PFNS ND ng/L 1.0 0.25 1 05/09/24 08:12 05/11/24 00:23 68259-12-1 PFOSA ND ng/L 1.0 0.25 1 05/09/24 08:12 05/11/24 00:23 754-91-6 PFPeA ND ng/L 2.1 0.31 1 05/09/24 08:12 05/11/24 00:23 2706-90-3 PFPeS ND ng/L 1.0 0.19 1 05/09/24 08:12 05/11/24 00:23 2706-91-4 PFDoA ND ng/L 1.0 0.23 1 05/09/24 08:12 05/11/24 00:23 307-55-1 PFHpA ND ng/L 1.0 0.22 1 05/09/24 08:12 05/11/24 00:23 375-85-9 PFHxS ND ng/L 1.0 0.27 1 05/09/24 08:12 05/11/24 00:23 355-46-4 PFNA ND ng/L 1.0 0.24 1 05/09/24 08:12 05/11/24 00:23 375-95-1 PFOS ND ng/L 1.0 0.18 1 05/09/24 08:12 05/11/24 00:23 1763-23-1 PFOA ND ng/L 1.0 0.36 1 05/09/24 08:12 05/11/24 00:23 335-67-1 PFTeDA ND ng/L 1.0 0.30 1 05/09/24 08:12 05/11/24 00:23 376-06-7 PFTrDA ND ng/L 1.0 0.21 1 05/09/24 08:12 05/11/24 00:23 72629-94-8 PFUnA ND ng/L 1.0 0.26 1 05/09/24 08:12 05/11/24 00:23 2058-94-8 Surrogates 13C2-PFDoA (S) 67 %. 10-130 1 05/09/24 08:12 05/11/24 00:23 13C3HFPO-DA (S) 78 %. 40-130 1 05/09/24 08:12 05/11/24 00:23 13C3-PFBS (S) 85 %. 40-135 1 05/09/24 08:12 05/11/24 00:23 375-73-5 13C3-PFHxS (S) 84 %. 40-130 1 05/09/24 08:12 05/11/24 00:23 355-46-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-MW-9D Lab ID: 92726234010 Collected: 04/19/24 12:00 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis Surrogates 13C4-PFBA (S) 77 %. 5-130 1 05/09/24 08:12 05/11/24 00:23 375-22-4 13C4-PFHpA (S) 79 %. 40-130 1 05/09/24 08:12 05/11/24 00:23 375-85-9 13C5-PFHxA (S) 80 %. 40-130 1 05/09/24 08:12 05/11/24 00:23 307-24-4 13C5-PFPeA (S) 82 %. 40-130 1 05/09/24 08:12 05/11/24 00:23 2706-90-3 13C6-PFDA (S) 77 %. 40-130 1 05/09/24 08:12 05/11/24 00:23 335-76-2 13C8-PFDA (S) 79 %. 40-130 1 05/09/24 08:12 05/11/24 00:23 335-67-1 13C8-PFOS (S) 79 %. 40-130 1 05/09/24 08:12 05/11/24 00:23 1763-23-1 13C8-PFOSA (S) 70 %. 40-130 1 05/09/24 08:12 05/11/24 00:23 754-91-6 13C9-PFNA (S) 80 %. 40-130 1 05/09/24 08:12 05/11/24 00:23 375-95-1 d3-McFOSAA (S) 76 %. 40-170 1 05/09/24 08:12 05/11/24 00:23 2355-31-9 d3-NMeFOSA (S) 60 %. 10-130 1 05/09/24 08:12 05/11/24 00:23 31506-32-8 d5-EtFOSAA (S) 74 %. 25-135 1 05/09/24 08:12 05/11/24 00:23 2991-50-6 d5-NEtFOSA (S) 58 %. 10-130 1 05/09/24 08:12 05/11/24 00:23 4151-50-2 d7-NMeFOSE (S) 67 %. 10-130 1 05/09/24 08:12 05/11/24 00:23 24448-09-7 d9-NEtFOSE (S) 71 %. 10-130 1 05/09/24 08:12 05/11/24 00:23 1691-99-2 13C2-PFTA (S) 66 %. 10-130 1 05/09/24 08:12 05/11/24 00:23 13C7-PFUdA (S) 73 %. 30-130 1 05/09/24 08:12 05/11/24 00:23 2058-94-8 13C24:2FTS (S) 88 %. 40-200 1 05/09/24 08:12 05/11/24 00:23 13C26:2FTS (S) 86 %. 40-200 1 05/09/24 08:12 05/11/24 00:23 13C28:2FTS (S) 85 %. 40-300 1 05/09/24 08:12 05/11/24 00:23 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-SW-1 Lab ID: 92726234011 Collected: 04/19/24 12:40 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis 11CI-PF30UdS ND ng/L 4.3 0.84 1 05/09/24 08:12 05/11/24 00:39 763051-92-9 3:3 FTCA ND ng/L 5.4 2.5 1 05/09/24 08:12 05/11/24 00:39 356-02-5 4:2 FTS ND ng/L 4.3 0.52 1 05/09/24 08:12 05/11/24 00:39 757124-72-4 5:3 FTCA ND ng/L 27.1 5.2 1 05/09/24 08:12 05/11/24 00:39 914637-49-3 6:2 FTS ND ng/L 4.3 1.1 1 05/09/24 08:12 05/11/24 00:39 27619-97-2 7:3 FTCA ND ng/L 27.1 5.7 1 05/09/24 08:12 05/11/24 00:39 812-70-4 8:2 FTS ND ng/L 4.3 1.1 1 05/09/24 08:12 05/11/24 00:39 39108-34-4 9CI-PF30NS ND ng/L 4.3 0.89 1 05/09/24 08:12 05/11/24 00:39 756426-58-1 ADONA ND ng/L 4.3 0.63 1 05/09/24 08:12 05/11/24 00:39 919005-14-4 HFPO-DA ND ng/L 4.3 0.84 1 05/09/24 08:12 05/11/24 00:39 13252-13-6 NEtFOSAA ND ng/L 1.1 0.38 1 05/09/24 08:12 05/11/24 00:39 2991-50-6 NEtFOSA ND ng/L 1.1 0.28 1 05/09/24 08:12 05/11/24 00:39 4151-50-2 NEtFOSE ND ng/L 10.8 3.5 1 05/09/24 08:12 05/11/24 00:39 1691-99-2 NFDHA ND ng/L 2.2 0.61 1 05/09/24 08:12 05/11/24 00:39 151772-58-6 NMeFOSAA ND ng/L 1.1 0.35 1 05/09/24 08:12 05/11/24 00:39 2355-31-9 NMeFOSA ND ng/L 1.1 0.29 1 05/09/24 08:12 05/11/24 00:39 31506-32-8 NMeFOSE ND ng/L 10.8 2.9 1 05/09/24 08:12 05/11/24 00:39 24448-09-7 PFBS 1.0J ng/L 1.1 0.35 1 05/09/24 08:12 05/11/24 00:39 375-73-5 PFDA ND ng/L 1.1 0.19 1 05/09/24 08:12 05/11/24 00:39 335-76-2 PFHxA 0.78J ng/L 1.1 0.16 1 05/09/24 08:12 05/11/24 00:39 307-24-4 PFBA 0.991 ng/L 4.3 0.66 1 05/09/24 08:12 05/11/24 00:39 375-22-4 PFDS ND ng/L 1.1 0.29 1 05/09/24 08:12 05/11/24 00:39 335-77-3 PFDoS ND ng/L 1.1 0.30 1 05/09/24 08:12 05/11/24 00:39 79780-39-5 PFEESA ND ng/L 2.2 0.35 1 05/09/24 08:12 05/11/24 00:39 113507-82-7 PFHpS ND ng/L 1.1 0.26 1 05/09/24 08:12 05/11/24 00:39 375-92-8 PFMBA ND ng/L 2.2 0.34 1 05/09/24 08:12 05/11/24 00:39 863090-89-5 PFMPA ND ng/L 2.2 0.52 1 05/09/24 08:12 05/11/24 00:39 377-73-1 PFNS ND ng/L 1.1 0.26 1 05/09/24 08:12 05/11/24 00:39 68259-12-1 PFOSA 0.71J ng/L 1.1 0.26 1 05/09/24 08:12 05/11/24 00:39 754-91-6 PFPeA 0.501 ng/L 2.2 0.32 1 05/09/24 08:12 05/11/24 00:39 2706-90-3 PFPeS ND ng/L 1.1 0.20 1 05/09/24 08:12 05/11/24 00:39 2706-91-4 PFDoA ND ng/L 1.1 0.24 1 05/09/24 08:12 05/11/24 00:39 307-55-1 PFHpA ND ng/L 1.1 0.23 1 05/09/24 08:12 05/11/24 00:39 375-85-9 PFHxS 0.901 ng/L 1.1 0.28 1 05/09/24 08:12 05/11/24 00:39 355-46-4 PFNA ND ng/L 1.1 0.25 1 05/09/24 08:12 05/11/24 00:39 375-95-1 PFOS 1.6 ng/L 1.1 0.19 1 05/09/24 08:12 05/11/24 00:39 1763-23-1 PFOA 0.61J ng/L 1.1 0.37 1 05/09/24 08:12 05/11/24 00:39 335-67-1 PFTeDA ND ng/L 1.1 0.31 1 05/09/24 08:12 05/11/24 00:39 376-06-7 PFTrDA ND ng/L 1.1 0.21 1 05/09/24 08:12 05/11/24 00:39 72629-94-8 PFUnA ND ng/L 1.1 0.27 1 05/09/24 08:12 05/11/24 00:39 2058-94-8 Surrogates 13C2-PFDoA (S) 66 %. 10-130 1 05/09/24 08:12 05/11/24 00:39 13C3HFPO-DA (S) 71 %. 40-130 1 05/09/24 08:12 05/11/24 00:39 13C3-PFBS (S) 73 %. 40-135 1 05/09/24 08:12 05/11/24 00:39 375-73-5 13C3-PFHxS (S) 74 %. 40-130 1 05/09/24 08:12 05/11/24 00:39 355-46-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-SW-1 Lab ID: 92726234011 Collected: 04/19/24 12:40 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis Surrogates 13C4-PFBA (S) 72 %. 5-130 1 05/09/24 08:12 05/11/24 00:39 375-22-4 13C4-PFHpA (S) 74 %. 40-130 1 05/09/24 08:12 05/11/24 00:39 375-85-9 13C5-PFHxA (S) 71 %. 40-130 1 05/09/24 08:12 05/11/24 00:39 307-24-4 13C5-PFPeA (S) 74 %. 40-130 1 05/09/24 08:12 05/11/24 00:39 2706-90-3 13C6-PFDA (S) 70 %. 40-130 1 05/09/24 08:12 05/11/24 00:39 335-76-2 13C8-PFDA (S) 74 %. 40-130 1 05/09/24 08:12 05/11/24 00:39 335-67-1 13C8-PFOS (S) 75 %. 40-130 1 05/09/24 08:12 05/11/24 00:39 1763-23-1 13C8-PFOSA (S) 70 %. 40-130 1 05/09/24 08:12 05/11/24 00:39 754-91-6 13C9-PFNA (S) 72 %. 40-130 1 05/09/24 08:12 05/11/24 00:39 375-95-1 d3-McFOSAA (S) 78 %. 40-170 1 05/09/24 08:12 05/11/24 00:39 2355-31-9 d3-NMeFOSA (S) 57 %. 10-130 1 05/09/24 08:12 05/11/24 00:39 31506-32-8 d5-EtFOSAA (S) 79 %. 25-135 1 05/09/24 08:12 05/11/24 00:39 2991-50-6 d5-NEtFOSA (S) 54 %. 10-130 1 05/09/24 08:12 05/11/24 00:39 4151-50-2 d7-NMeFOSE (S) 58 %. 10-130 1 05/09/24 08:12 05/11/24 00:39 24448-09-7 d9-NEtFOSE (S) 63 %. 10-130 1 05/09/24 08:12 05/11/24 00:39 1691-99-2 13C2-PFTA (S) 53 %. 10-130 1 05/09/24 08:12 05/11/24 00:39 13C7-PFUdA (S) 71 %. 30-130 1 05/09/24 08:12 05/11/24 00:39 2058-94-8 13C24:2FTS (S) 63 %. 40-200 1 05/09/24 08:12 05/11/24 00:39 13C26:2FTS (S) 85 %. 40-200 1 05/09/24 08:12 05/11/24 00:39 13C28:2FTS (S) 77 %. 40-300 1 05/09/24 08:12 05/11/24 00:39 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-SW-2 Lab ID: 92726234012 Collected: 04/19/24 10:20 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis 11CI-PF30UdS ND ng/L 4.7 0.91 1 05/09/24 08:12 05/11/24 00:54 763051-92-9 3:3 FTCA ND ng/L 5.9 2.7 1 05/09/24 08:12 05/11/24 00:54 356-02-5 4:2 FTS ND ng/L 4.7 0.56 1 05/09/24 08:12 05/11/24 00:54 757124-72-4 5:3 FTCA ND ng/L 29.3 5.7 1 05/09/24 08:12 05/11/24 00:54 914637-49-3 6:2 FTS ND ng/L 4.7 1.1 1 05/09/24 08:12 05/11/24 00:54 27619-97-2 7:3 FTCA ND ng/L 29.3 6.1 1 05/09/24 08:12 05/11/24 00:54 812-70-4 8:2 FTS ND ng/L 4.7 1.2 1 05/09/24 08:12 05/11/24 00:54 39108-34-4 9CI-PF30NS ND ng/L 4.7 0.96 1 05/09/24 08:12 05/11/24 00:54 756426-58-1 ADONA ND ng/L 4.7 0.69 1 05/09/24 08:12 05/11/24 00:54 919005-14-4 HFPO-DA ND ng/L 4.7 0.91 1 05/09/24 08:12 05/11/24 00:54 13252-13-6 NEtFOSAA ND ng/L 1.2 0.41 1 05/09/24 08:12 05/11/24 00:54 2991-50-6 NEtFOSA ND ng/L 1.2 0.30 1 05/09/24 08:12 05/11/24 00:54 4151-50-2 NEtFOSE ND ng/L 11.7 3.8 1 05/09/24 08:12 05/11/24 00:54 1691-99-2 NFDHA ND ng/L 2.3 0.66 1 05/09/24 08:12 05/11/24 00:54 151772-58-6 NMeFOSAA ND ng/L 1.2 0.37 1 05/09/24 08:12 05/11/24 00:54 2355-31-9 NMeFOSA ND ng/L 1.2 0.31 1 05/09/24 08:12 05/11/24 00:54 31506-32-8 NMeFOSE ND ng/L 11.7 3.1 1 05/09/24 08:12 05/11/24 00:54 24448-09-7 PFBS 1.3 ng/L 1.2 0.37 1 05/09/24 08:12 05/11/24 00:54 375-73-5 PFDA ND ng/L 1.2 0.21 1 05/09/24 08:12 05/11/24 00:54 335-76-2 PFHxA 2.4 ng/L 1.2 0.18 1 05/09/24 08:12 05/11/24 00:54 307-24-4 PFBA 1.6J ng/L 4.7 0.72 1 05/09/24 08:12 05/11/24 00:54 375-22-4 PFDS ND ng/L 1.2 0.31 1 05/09/24 08:12 05/11/24 00:54 335-77-3 PFDoS ND ng/L 1.2 0.32 1 05/09/24 08:12 05/11/24 00:54 79780-39-5 PFEESA ND ng/L 2.3 0.37 1 05/09/24 08:12 05/11/24 00:54 113507-82-7 PFHpS ND ng/L 1.2 0.28 1 05/09/24 08:12 05/11/24 00:54 375-92-8 PFMBA ND ng/L 2.3 0.37 1 05/09/24 08:12 05/11/24 00:54 863090-89-5 PFMPA ND ng/L 2.3 0.57 1 05/09/24 08:12 05/11/24 00:54 377-73-1 PFNS ND ng/L 1.2 0.28 1 05/09/24 08:12 05/11/24 00:54 68259-12-1 PFOSA ND ng/L 1.2 0.28 1 05/09/24 08:12 05/11/24 00:54 754-91-6 PFPeA 1.5J ng/L 2.3 0.35 1 05/09/24 08:12 05/11/24 00:54 2706-90-3 PFPeS 0.41J ng/L 1.2 0.21 1 05/09/24 08:12 05/11/24 00:54 2706-91-4 PFDoA ND ng/L 1.2 0.26 1 05/09/24 08:12 05/11/24 00:54 307-55-1 PFHpA 1.1J ng/L 1.2 0.25 1 05/09/24 08:12 05/11/24 00:54 375-85-9 PFHxS 1.3 ng/L 1.2 0.30 1 05/09/24 08:12 05/11/24 00:54 355-46-4 PFNA ND ng/L 1.2 0.27 1 05/09/24 08:12 05/11/24 00:54 375-95-1 PFOS 1.1.1 ng/L 1.2 0.20 1 05/09/24 08:12 05/11/24 00:54 1763-23-1 PFOA 3.2 ng/L 1.2 0.40 1 05/09/24 08:12 05/11/24 00:54 335-67-1 PFTeDA ND ng/L 1.2 0.33 1 05/09/24 08:12 05/11/24 00:54 376-06-7 PFTrDA ND ng/L 1.2 0.23 1 05/09/24 08:12 05/11/24 00:54 72629-94-8 PFUnA ND ng/L 1.2 0.30 1 05/09/24 08:12 05/11/24 00:54 2058-94-8 Surrogates 13C2-PFDoA (S) 75 %. 10-130 1 05/09/24 08:12 05/11/24 00:54 13C3HFPO-DA (S) 83 %. 40-130 1 05/09/24 08:12 05/11/24 00:54 13C3-PFBS (S) 87 %. 40-135 1 05/09/24 08:12 05/11/24 00:54 375-73-5 13C3-PFHxS (S) 86 %. 40-130 1 05/09/24 08:12 05/11/24 00:54 355-46-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-SW-2 Lab ID: 92726234012 Collected: 04/19/24 10:20 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis Surrogates 13C4-PFBA (S) 82 %. 5-130 1 05/09/24 08:12 05/11/24 00:54 375-22-4 13C4-PFHpA (S) 81 %. 40-130 1 05/09/24 08:12 05/11/24 00:54 375-85-9 13C5-PFHxA (S) 82 %. 40-130 1 05/09/24 08:12 05/11/24 00:54 307-24-4 13C5-PFPeA (S) 86 %. 40-130 1 05/09/24 08:12 05/11/24 00:54 2706-90-3 13C6-PFDA (S) 85 %. 40-130 1 05/09/24 08:12 05/11/24 00:54 335-76-2 13C8-PFDA (S) 80 %. 40-130 1 05/09/24 08:12 05/11/24 00:54 335-67-1 13C8-PFOS (S) 80 %. 40-130 1 05/09/24 08:12 05/11/24 00:54 1763-23-1 13C8-PFOSA (S) 70 %. 40-130 1 05/09/24 08:12 05/11/24 00:54 754-91-6 13C9-PFNA (S) 80 %. 40-130 1 05/09/24 08:12 05/11/24 00:54 375-95-1 d3-McFOSAA (S) 81 %. 40-170 1 05/09/24 08:12 05/11/24 00:54 2355-31-9 d3-NMeFOSA (S) 60 %. 10-130 1 05/09/24 08:12 05/11/24 00:54 31506-32-8 d5-EtFOSAA (S) 80 %. 25-135 1 05/09/24 08:12 05/11/24 00:54 2991-50-6 d5-NEtFOSA (S) 56 %. 10-130 1 05/09/24 08:12 05/11/24 00:54 4151-50-2 d7-NMeFOSE (S) 66 %. 10-130 1 05/09/24 08:12 05/11/24 00:54 24448-09-7 d9-NEtFOSE (S) 70 %. 10-130 1 05/09/24 08:12 05/11/24 00:54 1691-99-2 13C2-PFTA (S) 64 %. 10-130 1 05/09/24 08:12 05/11/24 00:54 13C7-PFUdA (S) 81 %. 30-130 1 05/09/24 08:12 05/11/24 00:54 2058-94-8 13C24:2FTS (S) 84 %. 40-200 1 05/09/24 08:12 05/11/24 00:54 13C26:2FTS (S) 91 %. 40-200 1 05/09/24 08:12 05/11/24 00:54 13C28:2FTS (S) 83 %. 40-300 1 05/09/24 08:12 05/11/24 00:54 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-Field Blank Lab ID: 92726234013 Collected: 04/19/24 13:00 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis 11CI-PF30UdS ND ng/L 4.2 0.81 1 05/09/24 08:12 05/11/24 01:10 763051-92-9 3:3 FTCA ND ng/L 5.2 2.4 1 05/09/24 08:12 05/11/24 01:10 356-02-5 4:2 FTS ND ng/L 4.2 0.50 1 05/09/24 08:12 05/11/24 01:10 757124-72-4 5:3 FTCA ND ng/L 26.0 5.0 1 05/09/24 08:12 05/11/24 01:10 914637-49-3 6:2 FTS ND ng/L 4.2 1.0 1 05/09/24 08:12 05/11/24 01:10 27619-97-2 7:3 FTCA ND ng/L 26.0 5.4 1 05/09/24 08:12 05/11/24 01:10 812-70-4 8:2 FTS ND ng/L 4.2 1.1 1 05/09/24 08:12 05/11/24 01:10 39108-34-4 9CI-PF30NS ND ng/L 4.2 0.85 1 05/09/24 08:12 05/11/24 01:10 756426-58-1 ADONA ND ng/L 4.2 0.61 1 05/09/24 08:12 05/11/24 01:10 919005-14-4 HFPO-DA ND ng/L 4.2 0.81 1 05/09/24 08:12 05/11/24 01:10 13252-13-6 NEtFOSAA ND ng/L 1.0 0.36 1 05/09/24 08:12 05/11/24 01:10 2991-50-6 NEtFOSA ND ng/L 1.0 0.27 1 05/09/24 08:12 05/11/24 01:10 4151-50-2 NEtFOSE ND ng/L 10.4 3.3 1 05/09/24 08:12 05/11/24 01:10 1691-99-2 NFDHA ND ng/L 2.1 0.59 1 05/09/24 08:12 05/11/24 01:10 151772-58-6 NMeFOSAA ND ng/L 1.0 0.33 1 05/09/24 08:12 05/11/24 01:10 2355-31-9 NMeFOSA ND ng/L 1.0 0.28 1 05/09/24 08:12 05/11/24 01:10 31506-32-8 NMeFOSE ND ng/L 10.4 2.8 1 05/09/24 08:12 05/11/24 01:10 24448-09-7 PFBS ND ng/L 1.0 0.33 1 05/09/24 08:12 05/11/24 01:10 375-73-5 PFDA ND ng/L 1.0 0.18 1 05/09/24 08:12 05/11/24 01:10 335-76-2 PFHxA ND ng/L 1.0 0.16 1 05/09/24 08:12 05/11/24 01:10 307-24-4 PFBA ND ng/L 4.2 0.64 1 05/09/24 08:12 05/11/24 01:10 375-22-4 PFDS ND ng/L 1.0 0.28 1 05/09/24 08:12 05/11/24 01:10 335-77-3 PFDoS ND ng/L 1.0 0.29 1 05/09/24 08:12 05/11/24 01:10 79780-39-5 PFEESA ND ng/L 2.1 0.33 1 05/09/24 08:12 05/11/24 01:10 113507-82-7 PFHpS ND ng/L 1.0 0.25 1 05/09/24 08:12 05/11/24 01:10 375-92-8 PFMBA ND ng/L 2.1 0.33 1 05/09/24 08:12 05/11/24 01:10 863090-89-5 PFMPA ND ng/L 2.1 0.50 1 05/09/24 08:12 05/11/24 01:10 377-73-1 PFNS ND ng/L 1.0 0.25 1 05/09/24 08:12 05/11/24 01:10 68259-12-1 PFOSA ND ng/L 1.0 0.25 1 05/09/24 08:12 05/11/24 01:10 754-91-6 PFPeA ND ng/L 2.1 0.31 1 05/09/24 08:12 05/11/24 01:10 2706-90-3 PFPeS ND ng/L 1.0 0.19 1 05/09/24 08:12 05/11/24 01:10 2706-91-4 PFDoA ND ng/L 1.0 0.23 1 05/09/24 08:12 05/11/24 01:10 307-55-1 PFHpA ND ng/L 1.0 0.22 1 05/09/24 08:12 05/11/24 01:10 375-85-9 PFHxS ND ng/L 1.0 0.27 1 05/09/24 08:12 05/11/24 01:10 355-46-4 PFNA ND ng/L 1.0 0.24 1 05/09/24 08:12 05/11/24 01:10 375-95-1 PFOS ND ng/L 1.0 0.18 1 05/09/24 08:12 05/11/24 01:10 1763-23-1 PFOA ND ng/L 1.0 0.36 1 05/09/24 08:12 05/11/24 01:10 335-67-1 PFTeDA ND ng/L 1.0 0.30 1 05/09/24 08:12 05/11/24 01:10 376-06-7 PFTrDA ND ng/L 1.0 0.21 1 05/09/24 08:12 05/11/24 01:10 72629-94-8 PFUnA ND ng/L 1.0 0.26 1 05/09/24 08:12 05/11/24 01:10 2058-94-8 Surrogates 13C2-PFDoA (S) 70 %. 10-130 1 05/09/24 08:12 05/11/24 01:10 13C3HFPO-DA (S) 76 %. 40-130 1 05/09/24 08:12 05/11/24 01:10 13C3-PFBS (S) 81 %. 40-135 1 05/09/24 08:12 05/11/24 01:10 375-73-5 13C3-PFHxS (S) 81 %. 40-130 1 05/09/24 08:12 05/11/24 01:10 355-46-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-Field Blank Lab ID: 92726234013 Collected: 04/19/24 13:00 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis Surrogates 13C4-PFBA (S) 75 %. 5-130 1 05/09/24 08:12 05/11/24 01:10 375-22-4 13C4-PFHpA (S) 75 %. 40-130 1 05/09/24 08:12 05/11/24 01:10 375-85-9 13C5-PFHxA (S) 75 %. 40-130 1 05/09/24 08:12 05/11/24 01:10 307-24-4 13C5-PFPeA (S) 78 %. 40-130 1 05/09/24 08:12 05/11/24 01:10 2706-90-3 13C6-PFDA (S) 74 %. 40-130 1 05/09/24 08:12 05/11/24 01:10 335-76-2 13C8-PFDA (S) 75 %. 40-130 1 05/09/24 08:12 05/11/24 01:10 335-67-1 13C8-PFOS (S) 75 %. 40-130 1 05/09/24 08:12 05/11/24 01:10 1763-23-1 13C8-PFOSA (S) 72 %. 40-130 1 05/09/24 08:12 05/11/24 01:10 754-91-6 13C9-PFNA (S) 74 %. 40-130 1 05/09/24 08:12 05/11/24 01:10 375-95-1 d3-McFOSAA (S) 74 %. 40-170 1 05/09/24 08:12 05/11/24 01:10 2355-31-9 d3-NMeFOSA (S) 61 %. 10-130 1 05/09/24 08:12 05/11/24 01:10 31506-32-8 d5-EtFOSAA (S) 75 %. 25-135 1 05/09/24 08:12 05/11/24 01:10 2991-50-6 d5-NEtFOSA (S) 61 %. 10-130 1 05/09/24 08:12 05/11/24 01:10 4151-50-2 d7-NMeFOSE (S) 69 %. 10-130 1 05/09/24 08:12 05/11/24 01:10 24448-09-7 d9-NEtFOSE (S) 74 %. 10-130 1 05/09/24 08:12 05/11/24 01:10 1691-99-2 13C2-PFTA (S) 70 %. 10-130 1 05/09/24 08:12 05/11/24 01:10 13C7-PFUdA (S) 74 %. 30-130 1 05/09/24 08:12 05/11/24 01:10 2058-94-8 13C24:2FTS (S) 90 %. 40-200 1 05/09/24 08:12 05/11/24 01:10 13C26:2FTS (S) 87 %. 40-200 1 05/09/24 08:12 05/11/24 01:10 13C28:2FTS (S) 80 %. 40-300 1 05/09/24 08:12 05/11/24 01:10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-Equipment Rinse Lab ID: 92726234014 Collected: 04/19/24 12:25 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis 11CI-PF30UdS ND ng/L 4.1 0.80 1 05/09/24 08:12 05/11/24 01:57 763051-92-9 3:3 FTCA ND ng/L 5.1 2.4 1 05/09/24 08:12 05/11/24 01:57 356-02-5 4:2 FTS ND ng/L 4.1 0.49 1 05/09/24 08:12 05/11/24 01:57 757124-72-4 5:3 FTCA ND ng/L 25.6 5.0 1 05/09/24 08:12 05/11/24 01:57 914637-49-3 6:2 FTS ND ng/L 4.1 1.0 1 05/09/24 08:12 05/11/24 01:57 27619-97-2 7:3 FTCA ND ng/L 25.6 5.4 1 05/09/24 08:12 05/11/24 01:57 812-70-4 8:2 FTS ND ng/L 4.1 1.1 1 05/09/24 08:12 05/11/24 01:57 39108-34-4 9CI-PF30NS ND ng/L 4.1 0.84 1 05/09/24 08:12 05/11/24 01:57 756426-58-1 ADONA ND ng/L 4.1 0.60 1 05/09/24 08:12 05/11/24 01:57 919005-14-4 HFPO-DA ND ng/L 4.1 0.80 1 05/09/24 08:12 05/11/24 01:57 13252-13-6 NEtFOSAA ND ng/L 1.0 0.36 1 05/09/24 08:12 05/11/24 01:57 2991-50-6 NEtFOSA ND ng/L 1.0 0.26 1 05/09/24 08:12 05/11/24 01:57 4151-50-2 NEtFOSE ND ng/L 10.3 3.3 1 05/09/24 08:12 05/11/24 01:57 1691-99-2 NFDHA ND ng/L 2.1 0.58 1 05/09/24 08:12 05/11/24 01:57 151772-58-6 NMeFOSAA ND ng/L 1.0 0.33 1 05/09/24 08:12 05/11/24 01:57 2355-31-9 NMeFOSA ND ng/L 1.0 0.27 1 05/09/24 08:12 05/11/24 01:57 31506-32-8 NMeFOSE ND ng/L 10.3 2.7 1 05/09/24 08:12 05/11/24 01:57 24448-09-7 PFBS ND ng/L 1.0 0.33 1 05/09/24 08:12 05/11/24 01:57 375-73-5 PFDA ND ng/L 1.0 0.18 1 05/09/24 08:12 05/11/24 01:57 335-76-2 PFHxA ND ng/L 1.0 0.15 1 05/09/24 08:12 05/11/24 01:57 307-24-4 PFBA ND ng/L 4.1 0.63 1 05/09/24 08:12 05/11/24 01:57 375-22-4 PFDS ND ng/L 1.0 0.27 1 05/09/24 08:12 05/11/24 01:57 335-77-3 PFDoS ND ng/L 1.0 0.28 1 05/09/24 08:12 05/11/24 01:57 79780-39-5 PFEESA ND ng/L 2.1 0.33 1 05/09/24 08:12 05/11/24 01:57 113507-82-7 PFHpS ND ng/L 1.0 0.25 1 05/09/24 08:12 05/11/24 01:57 375-92-8 PFMBA ND ng/L 2.1 0.32 1 05/09/24 08:12 05/11/24 01:57 863090-89-5 PFMPA ND ng/L 2.1 0.50 1 05/09/24 08:12 05/11/24 01:57 377-73-1 PFNS ND ng/L 1.0 0.25 1 05/09/24 08:12 05/11/24 01:57 68259-12-1 PFOSA ND ng/L 1.0 0.24 1 05/09/24 08:12 05/11/24 01:57 754-91-6 PFPeA ND ng/L 2.1 0.31 1 05/09/24 08:12 05/11/24 01:57 2706-90-3 PFPeS ND ng/L 1.0 0.19 1 05/09/24 08:12 05/11/24 01:57 2706-91-4 PFDoA ND ng/L 1.0 0.23 1 05/09/24 08:12 05/11/24 01:57 307-55-1 PFHpA ND ng/L 1.0 0.22 1 05/09/24 08:12 05/11/24 01:57 375-85-9 PFHxS ND ng/L 1.0 0.27 1 05/09/24 08:12 05/11/24 01:57 355-46-4 PFNA ND ng/L 1.0 0.24 1 05/09/24 08:12 05/11/24 01:57 375-95-1 PFOS ND ng/L 1.0 0.18 1 05/09/24 08:12 05/11/24 01:57 1763-23-1 PFOA ND ng/L 1.0 0.35 1 05/09/24 08:12 05/11/24 01:57 335-67-1 PFTeDA ND ng/L 1.0 0.29 1 05/09/24 08:12 05/11/24 01:57 376-06-7 PFTrDA ND ng/L 1.0 0.20 1 05/09/24 08:12 05/11/24 01:57 72629-94-8 PFUnA ND ng/L 1.0 0.26 1 05/09/24 08:12 05/11/24 01:57 2058-94-8 Surrogates 13C2-PFDoA (S) 75 %. 10-130 1 05/09/24 08:12 05/11/24 01:57 13C3HFPO-DA (S) 79 %. 40-130 1 05/09/24 08:12 05/11/24 01:57 13C3-PFBS (S) 86 %. 40-135 1 05/09/24 08:12 05/11/24 01:57 375-73-5 13C3-PFHxS (S) 85 %. 40-130 1 05/09/24 08:12 05/11/24 01:57 355-46-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Sample: 8102-Equipment Rinse Lab ID: 92726234014 Collected: 04/19/24 12:25 Received: 04/19/24 16:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual EPA 1633 DRAFT Water Analytical Method: EPA 1633 DRAFT Preparation Method: EPA 1633 DRAFT Pace Analytical Services - Minneapolis Surrogates 13C4-PFBA (S) 82 %. 5-130 1 05/09/24 08:12 05/11/24 01:57 375-22-4 13C4-PFHpA (S) 80 %. 40-130 1 05/09/24 08:12 05/11/24 01:57 375-85-9 13C5-PFHxA (S) 80 %. 40-130 1 05/09/24 08:12 05/11/24 01:57 307-24-4 13C5-PFPeA (S) 84 %. 40-130 1 05/09/24 08:12 05/11/24 01:57 2706-90-3 13C6-PFDA (S) 80 %. 40-130 1 05/09/24 08:12 05/11/24 01:57 335-76-2 13C8-PFDA (S) 78 %. 40-130 1 05/09/24 08:12 05/11/24 01:57 335-67-1 13C8-PFOS (S) 85 %. 40-130 1 05/09/24 08:12 05/11/24 01:57 1763-23-1 13C8-PFOSA (S) 77 %. 40-130 1 05/09/24 08:12 05/11/24 01:57 754-91-6 13C9-PFNA (S) 78 %. 40-130 1 05/09/24 08:12 05/11/24 01:57 375-95-1 d3-McFOSAA (S) 84 %. 40-170 1 05/09/24 08:12 05/11/24 01:57 2355-31-9 d3-NMeFOSA (S) 67 %. 10-130 1 05/09/24 08:12 05/11/24 01:57 31506-32-8 d5-EtFOSAA (S) 85 %. 25-135 1 05/09/24 08:12 05/11/24 01:57 2991-50-6 d5-NEtFOSA (S) 66 %. 10-130 1 05/09/24 08:12 05/11/24 01:57 4151-50-2 d7-NMeFOSE (S) 77 %. 10-130 1 05/09/24 08:12 05/11/24 01:57 24448-09-7 d9-NEtFOSE (S) 83 %. 10-130 1 05/09/24 08:12 05/11/24 01:57 1691-99-2 13C2-PFTA (S) 76 %. 10-130 1 05/09/24 08:12 05/11/24 01:57 13C7-PFUdA (S) 80 %. 30-130 1 05/09/24 08:12 05/11/24 01:57 2058-94-8 13C24:2FTS (S) 97 %. 40-200 1 05/09/24 08:12 05/11/24 01:57 13C26:2FTS (S) 94 %. 40-200 1 05/09/24 08:12 05/11/24 01:57 13C28:2FTS (S) 89 %. 40-300 1 05/09/24 08:12 05/11/24 01:57 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 QC Batch: 944469 Analysis Method: EPA 1633 DRAFT QC Batch Method: EPA 1633 DRAFT Analysis Description: 1633 W Laboratory: Pace Analytical Services - Minneapolis Associated Lab Samples: 92726234001, 92726234002, 92726234003, 92726234004, 92726234005, 92726234006 METHOD BLANK: 4942582 Matrix: Water Associated Lab Samples: 92726234001, 92726234002, 92726234003, 92726234004, 92726234005, 92726234006 Blank Reporting Parameter Units Result Limit MDL Analyzed 11Cl-PF30UdS ng/L ND 4.0 0.77 05/11/24 14:57 3:3 FTCA ng/L ND 5.0 2.3 05/11/24 14:57 4:2 FTS ng/L ND 4.0 0.48 05/11/24 14:57 5:3 FTCA ng/L ND 24.8 4.8 05/11/24 14:57 6:2 FTS ng/L ND 4.0 0.97 05/11/24 14:57 7:3 FTCA ng/L ND 24.8 5.2 05/11/24 14:57 8:2 FTS ng/L ND 4.0 1.0 05/11/24 14:57 9CI-PF30NS ng/L ND 4.0 0.82 05/11/24 14:57 ADONA ng/L ND 4.0 0.58 05/11/24 14:57 HFPO-DA ng/L ND 4.0 0.77 05/11/24 14:57 NEtFOSA ng/L ND 0.99 0.25 05/11/24 14:57 NEtFOSAA ng/L ND 0.99 0.35 05/11/24 14:57 NEtFOSE ng/L ND 9.9 3.2 05/11/24 14:57 NFDHA ng/L ND 2.0 0.56 05/11/24 14:57 NMeFOSA ng/L ND 0.99 0.26 05/11/24 14:57 NMeFOSAA ng/L ND 0.99 0.32 05/11/24 14:57 NMeFOSE ng/L ND 9.9 2.6 05/11/24 14:57 PFBA ng/L ND 4.0 0.61 05/11/24 14:57 PFBS ng/L ND 0.99 0.32 05/11/24 14:57 PFDA ng/L ND 0.99 0.18 05/11/24 14:57 PFDoA ng/L ND 0.99 0.22 05/11/24 14:57 PFDoS ng/L ND 0.99 0.27 05/11/24 14:57 PFDS ng/L ND 0.99 0.26 05/11/24 14:57 PFEESA ng/L ND 2.0 0.32 05/11/24 14:57 PFHpA ng/L ND 0.99 0.21 05/11/24 14:57 PFHpS ng/L ND 0.99 0.24 05/11/24 14:57 PFHxA ng/L ND 0.99 0.15 05/11/24 14:57 PFHxS ng/L ND 0.99 0.26 05/11/24 14:57 PFMBA ng/L ND 2.0 0.31 05/11/24 14:57 PFMPA ng/L ND 2.0 0.48 05/11/24 14:57 PFNA ng/L ND 0.99 0.23 05/11/24 14:57 PFNS ng/L ND 0.99 0.24 05/11/24 14:57 PFOA ng/L ND 0.99 0.34 05/11/24 14:57 PFOS ng/L ND 0.99 0.17 05/11/24 14:57 PFOSA ng/L ND 0.99 0.24 05/11/24 14:57 PFPeA ng/L ND 2.0 0.30 05/11/24 14:57 PFPeS ng/L ND 0.99 0.18 05/11/24 14:57 PFTeDA ng/L ND 0.99 0.28 05/11/24 14:57 PFTrDA ng/L ND 0.99 0.20 05/11/24 14:57 PFUnA ng/L ND 0.99 0.25 05/11/24 14:57 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 METHOD BLANK: 4942582 Matrix: Water Associated Lab Samples: 92726234001, 92726234002, 92726234003, 92726234004, 92726234005, 92726234006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 13C2-PFDoA (S) %. 71 10-130 05/11/24 14:57 13C2-PFTA (S) %. 70 10-130 05/11/24 14:57 13C24:2FTS (S) %. 100 40-200 05/11/24 14:57 13C26:2FTS (S) %. 100 40-200 05/11/24 14:57 13C28:2FTS (S) %. 88 40-300 05/11/24 14:57 13C3-PFBS (S) %. 82 40-135 05/11/24 14:57 13C3-PFHxS (S) %. 80 40-130 05/11/24 14:57 13C3HFPO-DA (S) %. 78 40-130 05/11/24 14:57 13C4-PFBA(S) %. 78 5-130 05/11/24 14:57 13C4-PFHpA (S) %. 78 40-130 05/11/24 14:57 13C5-PFHxA (S) %. 80 40-130 05/11/24 14:57 13C5-PFPeA (S) %. 82 40-130 05/11/24 14:57 13C6-PFDA (S) %. 77 40-130 05/11/24 14:57 13C7-PFUdA (S) %. 75 30-130 05/11/24 14:57 13C8-PFDA (S) %. 78 40-130 05/11/24 14:57 13C8-PFOS (S) %. 78 40-130 05/11/24 14:57 13C8-PFOSA (S) %. 69 40-130 05/11/24 14:57 13C9-PFNA (S) %. 78 40-130 05/11/24 14:57 d3-McFOSAA (S) %. 78 40-170 05/11/24 14:57 d3-NMeFOSA (S) %. 56 10-130 05/11/24 14:57 d5-EtFOSAA (S) %. 79 25-135 05/11/24 14:57 d5-NEtFOSA (S) %. 56 10-130 05/11/24 14:57 d7-NMeFOSE (S) %. 65 10-130 05/11/24 14:57 d9-NEtFOSE (S) %. 71 10-130 05/11/24 14:57 LABORATORY CONTROL SAMPLE & LCSD: 4942583 4942584 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 11Cl-PF30UdS ng/L 95.6 97.7 119 102 128 55-160 20 30 3:3 FTCA ng/L 127 120 112 95 91 65-130 7 30 4:2 FTS ng/L 95 99.7 78.0 105 84 70-145 24 30 5:3 FTCA ng/L 633 613 498 97 81 70-135 21 30 6:2 FTS ng/L 96.2 102 80.0 106 86 65-155 24 30 7:3 FTCA ng/L 633 582 470 92 76 50-145 21 30 8:2 FTS ng/L 97.5 107 83.8 110 88 60-150 25 30 9CI-PF30NS ng/L 95 99.2 127 104 137 70-155 24 30 ADONA ng/L 95.6 98.1 125 103 134 65-145 24 30 HFPO-DA ng/L 101 99.5 132 98 134 70-140 28 30 NEtFOSA ng/L 25.3 24.2 19.3 96 78 65-145 22 30 NEtFOSAA ng/L 25.3 25.2 19.3 100 78 70-145 27 30 NEtFOSE ng/L 253 237 186 94 76 70-135 24 30 NFDHA ng/L 50.6 47.5 40.9 94 83 50-150 15 30 NMeFOSA ng/L 25.3 25.8 20.7 102 84 60-150 22 30 NMeFOSAA ng/L 25.3 23.9 21.4 94 87 50-140 11 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 LABORATORY CONTROL SAMPLE & LCSD: Parameter 4942583 Units Spike Conc. 4942584 LCS LCSD Result Result LCS LCSD % Rec % Rec % Rec Limits RPD Max RPD Qualifiers NMeFOSE ng/L 253 253 202 100 82 70-145 23 30 PFBA ng/L 101 95.1 78.5 94 80 70-140 19 30 PFBS ng/L 22.5 21.7 17.7 97 81 60-145 20 30 PFDA ng/L 25.3 25.2 19.8 100 80 70-140 24 30 PFDoA ng/L 25.3 25.2 21.1 100 86 70-140 18 30 PFDoS ng/L 24.6 23.3 17.8 95 74 50-145 27 30 PFDS ng/L 24.4 23.5 18.0 96 76 60-145 26 30 PFEESA ng/L 45.1 44.3 36.5 98 83 70-140 19 30 PFHpA ng/L 25.3 24.6 20.4 97 83 70-150 19 30 PFHpS ng/L 24.1 24.4 19.5 101 83 70-150 22 30 PFHxA ng/L 25.3 25.3 20.5 100 83 70-145 21 30 PFHxS ng/L 23.2 23.2 17.2 100 76 65-145 30 30 PFMBA ng/L 50.6 44.5 37.9 88 77 60-150 16 30 PFMPA ng/L 50.6 50.0 42.4 99 86 55-140 16 30 PFNA ng/L 25.3 24.2 19.2 95 78 70-150 23 30 PFNS ng/L 24.4 23.0 18.2 94 77 65-145 23 30 PFOA ng/L 25.3 24.9 20.0 98 81 70-150 21 30 PFOS ng/L 23.5 22.6 17.9 96 78 55-150 23 30 PFOSA ng/L 25.3 24.6 19.9 97 81 70-145 21 30 PFPeA ng/L 50.6 50.5 40.5 100 82 65-135 22 30 PFPeS ng/L 23.8 24.6 18.6 103 80 65-140 28 30 PFTeDA ng/L 25.3 25.4 20.0 100 81 60-140 24 30 PFTrDA ng/L 25.3 26.8 21.0 106 85 65-140 24 30 PFUnA ng/L 25.3 25.4 20.5 100 83 70-145 21 30 13C2-PFDoA (S) %. 78 80 10-130 13C2-PFTA (S) %. 82 81 10-130 13C24:2FTS (S) %. 95 97 40-200 13C26:2FTS (S) %. 92 88 40-200 13C28:2FTS (S) %. 86 79 40-300 13C3-PFBS (S) %. 87 90 40-135 13C3-PFHxS (S) %. 81 89 40-130 13C3HFPO-DA (S) %. 79 87 40-130 13C4-PFBA (S) %. 83 90 5-130 13C4-PFHpA (S) %. 83 88 40-130 13C5-PFHxA (S) %. 82 88 40-130 13C5-PFPeA (S) %. 84 91 40-130 13C6-PFDA (S) %. 83 87 40-130 13C7-PFUdA (S) %. 82 85 30-130 13C8-PFDA (S) %. 81 86 40-130 13C8-PFOS (S) %. 84 91 40-130 13C8-PFOSA (S) %. 75 78 40-130 13C9-PFNA (S) %. 81 91 40-130 d3-McFOSAA (S) %. 85 78 40-170 d3-NMeFOSA (S) %. 61 57 10-130 d5-EtFOSAA (S) %. 86 81 25-135 d5-NEtFOSA (S) %. 63 59 10-130 d7-NMeFOSE (S) %. 72 71 10-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 LABORATORY CONTROL SAMPLE & LCSD: 4942583 4942584 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers d9-NEtFOSE (S) %. 81 79 10-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 QC Batch: 944624 Analysis Method: EPA 1633 DRAFT QC Batch Method: EPA 1633 DRAFT Analysis Description: 1633 W Laboratory: Pace Analytical Services - Minneapolis Associated Lab Samples: 92726234007,92726234008,92726234009,92726234010,92726234011,92726234012,92726234013, 92726234014 METHOD BLANK: 4943289 Matrix: Water Associated Lab Samples: 92726234007,92726234008,92726234009,92726234010,92726234011,92726234012,92726234013, 92726234014 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 11Cl-PF30UdS ng/L ND 4.0 0.79 05/10/24 22:34 3:3 FTCA ng/L ND 5.1 2.4 05/10/24 22:34 4:2 FTS ng/L ND 4.0 0.49 05/10/24 22:34 5:3 FTCA ng/L ND 25.3 4.9 05/10/24 22:34 6:2 FTS ng/L ND 4.0 0.99 05/10/24 22:34 7:3 FTCA ng/L ND 25.3 5.3 05/10/24 22:34 8:2 FTS ng/L ND 4.0 1.1 05/10/24 22:34 9CI-PF30NS ng/L ND 4.0 0.83 05/10/24 22:34 ADONA ng/L ND 4.0 0.59 05/10/24 22:34 HFPO-DA ng/L ND 4.0 0.79 05/10/24 22:34 NEtFOSA ng/L ND 1.0 0.26 05/10/24 22:34 NEtFOSAA ng/L ND 1.0 0.35 05/10/24 22:34 NEtFOSE ng/L ND 10.1 3.2 05/10/24 22:34 NFDHA ng/L ND 2.0 0.57 05/10/24 22:34 NMeFOSA ng/L ND 1.0 0.27 05/10/24 22:34 NMeFOSAA ng/L ND 1.0 0.32 05/10/24 22:34 NMeFOSE ng/L ND 10.1 2.7 05/10/24 22:34 PFBA ng/L ND 4.0 0.62 05/10/24 22:34 PFBS ng/L ND 1.0 0.32 05/10/24 22:34 PFDA ng/L ND 1.0 0.18 05/10/24 22:34 PFDoA ng/L ND 1.0 0.22 05/10/24 22:34 PFDoS ng/L ND 1.0 0.28 05/10/24 22:34 PFDS ng/L ND 1.0 0.27 05/10/24 22:34 PFEESA ng/L ND 2.0 0.32 05/10/24 22:34 PFHpA ng/L ND 1.0 0.22 05/10/24 22:34 PFHpS ng/L ND 1.0 0.24 05/10/24 22:34 PFHxA ng/L ND 1.0 0.15 05/10/24 22:34 PFHxS ng/L ND 1.0 0.26 05/10/24 22:34 PFMBA ng/L ND 2.0 0.32 05/10/24 22:34 PFMPA ng/L ND 2.0 0.49 05/10/24 22:34 PFNA ng/L ND 1.0 0.24 05/10/24 22:34 PFNS ng/L ND 1.0 0.24 05/10/24 22:34 PFOA ng/L ND 1.0 0.35 05/10/24 22:34 PFOS ng/L ND 1.0 0.18 05/10/24 22:34 PFOSA ng/L ND 1.0 0.24 05/10/24 22:34 PFPeA ng/L ND 2.0 0.30 05/10/24 22:34 PFPeS ng/L ND 1.0 0.18 05/10/24 22:34 PFTeDA ng/L ND 1.0 0.29 05/10/24 22:34 PFTrDA ng/L ND 1.0 0.20 05/10/24 22:34 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 METHOD BLANK: 4943289 Matrix: Water Associated Lab Samples: 92726234007,92726234008,92726234009,92726234010,92726234011,92726234012,92726234013, 92726234014 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers PFUnA ng/L ND 1.0 0.26 05/10/24 22:34 13C2-PFDoA (S) %. 74 10-130 05/10/24 22:34 13C2-PFTA (S) %. 76 10-130 05/10/24 22:34 13C24:2FTS (S) %. 90 40-200 05/10/24 22:34 13C26:2FTS (S) %. 90 40-200 05/10/24 22:34 13C28:2FTS (S) %. 85 40-300 05/10/24 22:34 13C3-PFBS (S) %. 83 40-135 05/10/24 22:34 13C3-PFHxS (S) %. 82 40-130 05/10/24 22:34 13C3HFPO-DA (S) %. 78 40-130 05/10/24 22:34 13C4-PFBA (S) %. 78 5-130 05/10/24 22:34 13C4-PFHpA (S) %. 79 40-130 05/10/24 22:34 13C5-PFHxA (S) %. 79 40-130 05/10/24 22:34 13C5-PFPeA (S) %. 82 40-130 05/10/24 22:34 13C6-PFDA (S) %. 81 40-130 05/10/24 22:34 13C7-PFUdA (S) %. 80 30-130 05/10/24 22:34 13C8-PFOA (S) %. 77 40-130 05/10/24 22:34 13C8-PFOS (S) %. 83 40-130 05/10/24 22:34 13C8-PFOSA (S) %. 75 40-130 05/10/24 22:34 13C9-PFNA (S) %. 80 40-130 05/10/24 22:34 d3-McFOSAA (S) %. 82 40-170 05/10/24 22:34 d3-NMeFOSA (S) %. 63 10-130 05/10/24 22:34 d5-EtFOSAA (S) %. 84 25-135 05/10/24 22:34 d5-NEtFOSA (S) %. 63 10-130 05/10/24 22:34 d7-NMeFOSE (S) %. 75 10-130 05/10/24 22:34 d9-NEtFOSE (S) %. 81 10-130 05/10/24 22:34 LABORATORY CONTROL SAMPLE & LCSD: 4943290 4943291 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 11Cl-PF30UdS ng/L 90.1 94.2 91.8 105 100 55-160 3 30 3:3 FTCA ng/L 119 122 122 102 101 65-130 0 30 4:2 FTS ng/L 89.5 92.2 92.3 103 102 70-145 0 30 5:3 FTCA ng/L 597 619 619 104 102 70-135 0 30 6:2 FTS ng/L 90.7 95.1 94.0 105 102 65-155 1 30 7:3 FTCA ng/L 597 584 585 98 97 50-145 0 30 8:2 FTS ng/L 91.9 100 103 109 110 60-150 3 30 9CI-PF30NS ng/L 89.5 96.5 95.7 108 105 70-155 1 30 ADONA ng/L 90.1 94.0 93.1 104 102 65-145 1 30 HFPO-DA ng/L 95.5 97.9 93.5 103 97 70-140 5 30 NEtFOSA ng/L 23.9 22.9 22.8 96 94 65-145 1 30 NEtFOSAA ng/L 23.9 22.9 23.7 96 98 70-145 4 30 NEtFOSE ng/L 239 222 229 93 94 70-135 3 30 NFDHA ng/L 47.7 46.4 44.7 97 92 50-150 4 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 LABORATORY CONTROL SAMPLE & LCSD: Parameter 4943290 Units Spike Conc. 4943291 LCS LCSD Result Result LCS LCSD % Rec % Rec % Rec Limits RPD Max RPD Qualifiers NMeFOSA ng/L 23.9 24.3 23.8 102 98 60-150 2 30 NMeFOSAA ng/L 23.9 22.0 22.2 92 92 50-140 1 30 NMeFOSE ng/L 239 234 237 98 98 70-145 1 30 PFBA ng/L 95.5 94.2 94.8 99 98 70-140 1 30 PFBS ng/L 21.2 20.5 21.0 97 98 60-145 3 30 PFDA ng/L 23.9 23.3 23.7 98 98 70-140 2 30 PFDoA ng/L 23.9 23.7 24.9 99 103 70-140 5 30 PFDoS ng/L 23.2 22.1 22.0 96 94 50-145 0 30 PFDS ng/L 23 22.2 22.5 96 96 60-145 1 30 PFEESA ng/L 42.5 42.2 42.5 99 99 70-140 1 30 PFHpA ng/L 23.9 23.8 24.3 100 100 70-150 2 30 PFHpS ng/L 22.7 23.2 23.2 102 101 70-150 0 30 PFHxA ng/L 23.9 24.1 24.6 101 102 70-145 2 30 PFHxS ng/L 21.8 20.3 20.7 93 93 65-145 2 30 PFMBA ng/L 47.7 40.3 40.9 85 85 60-150 2 30 PFMPA ng/L 47.7 46.9 47.5 98 98 55-140 1 30 PFNA ng/L 23.9 23.2 23.7 97 98 70-150 2 30 PFNS ng/L 23 21.8 22.4 95 96 65-145 3 30 PFOA ng/L 23.9 23.0 23.4 97 96 70-150 1 30 PFOS ng/L 22.1 20.7 20.6 93 92 55-150 0 30 PFOSA ng/L 23.9 23.3 23.5 98 97 70-145 1 30 PFPeA ng/L 47.7 46.9 48.4 98 100 65-135 3 30 PFPeS ng/L 22.4 21.7 21.7 97 95 65-140 0 30 PFTeDA ng/L 23.9 23.3 24.5 98 101 60-140 5 30 PFTrDA ng/L 23.9 25.0 25.7 105 106 65-140 3 30 PFUnA ng/L 23.9 24.3 24.6 102 102 70-145 1 30 13C2-PFDoA (S) %. 79 72 10-130 13C2-PFTA (S) %. 84 75 10-130 13C24:2FTS (S) %. 90 86 40-200 13C26:2FTS (S) %. 89 87 40-200 13C28:2FTS (S) %. 87 79 40-300 13C3-PFBS (S) %. 88 82 40-135 13C3-PFHxS (S) %. 87 83 40-130 13C3HFPO-DA (S) %. 78 77 40-130 13C4-PFBA (S) %. 80 78 5-130 13C4-PFHpA (S) %. 81 79 40-130 13C5-PFHxA (S) %. 79 78 40-130 13C5-PFPeA (S) %. 83 81 40-130 13C6-PFDA (S) %. 85 79 40-130 13C7-PFUdA (S) %. 81 76 30-130 13C8-PFDA (S) %. 81 80 40-130 13C8-PFOS (S) %. 81 79 40-130 13C8-PFOSA (S) %. 78 74 40-130 13C9-PFNA (S) %. 80 77 40-130 d3-McFOSAA (S) %. 81 79 40-170 d3-NMeFOSA (S) %. 65 64 10-130 d5-EtFOSAA (S) %. 80 79 25-135 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 39 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 LABORATORY CONTROL SAMPLE & LCSD: 4943290 4943291 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers d5-NEtFOSA (S) %. 65 64 10-130 d7-NMeFOSE (S) %. 76 73 10-130 d9-NEtFOSE (S) %. 82 78 10-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALIFIERS Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 47 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Rutherford Co. LF-South PFAS Pace Project No.: 92726234 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92726234001 8102-MW-4A EPA 1633 DRAFT 944469 EPA 1633 DRAFT 945564 92726234002 8102-MW-1 EPA 1633 DRAFT 944469 EPA 1633 DRAFT 945564 92726234003 8102-MW-2A EPA 1633 DRAFT 944469 EPA 1633 DRAFT 945564 92726234004 8102-MW-3 EPA 1633 DRAFT 944469 EPA 1633 DRAFT 945564 92726234005 8102-MW-5 EPA 1633 DRAFT 944469 EPA 1633 DRAFT 945564 92726234006 8102-MW-6 EPA 1633 DRAFT 944469 EPA 1633 DRAFT 945564 92726234007 8102-MW-7 EPA 1633 DRAFT 944624 EPA 1633 DRAFT 945507 92726234008 8102-MW-8 EPA 1633 DRAFT 944624 EPA 1633 DRAFT 945507 92726234009 8102-MW-9S EPA 1633 DRAFT 944624 EPA 1633 DRAFT 945507 92726234010 8102-MW-9D EPA 1633 DRAFT 944624 EPA 1633 DRAFT 945507 92726234011 8102-SW-1 EPA 1633 DRAFT 944624 EPA 1633 DRAFT 945507 92726234012 8102-SW-2 EPA 1633 DRAFT 944624 EPA 1633 DRAFT 945507 92726234013 8102-Field Blank EPA 1633 DRAFT 944624 EPA 1633 DRAFT 945507 92726234014 8102-Equipment Rinse EPA 1633 DRAFT 944624 EPA 1633 DRAFT 945507 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2024 04:31 PM without the written consent of Pace Analytical Services, LLC. Page 42 of 47 ACC DC# Title: ENV-FRM-HUN1-0083 v03_Sample Condition Upon Receipt Effective Date:11/29/2023 4:16:30 PM Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersville❑ Sample Condition Client Name: WO� � 92726234 Upon Receipt Project #: �r�4tr� G�rall Courier LJ d ❑ Commercial Rpaex UP5 ❑Other: 92726234 Custody Seal Present? ❑Yes KNo Seals Intact? ❑Yes ❑No ®N/A z��rfli= Date/initials Person Examining Contents• Packing Material; ❑ Bubble Wrap ❑ Bubble Bags iU9 None ❑ Other Thermometer: 12 IR Gun ID 1 J 7v e of Ice: ®Wet []Blue Correction FactoO Curler Temp: Add/SSubtract C' Cooler Temp Corrected j'Cj: 3-� �• tr USDA Regulated Soil ( Q N/A, water sample) Did samples originate inrVuarantine zone within the united States: CA, NY, or SC irhwrk mnncl?I�Yac IriNn Biological Tissue Frozen? ❑ Yes ❑ No ®N/A ❑ None Temp should be above freezing to 6'C ❑ Samples out of temp criteria. Samples on ice, cooling process has begun Did samples originate from a foreign source (internationally, includinYHawaii and Puerto Ricol?❑Yes Iallo Comments/Discrepancy- Chain of Custody Present? OYes ❑ No :3 N/A 1. Samples Arrived within Hold Time? ® Yes ❑ No ❑NIA 2. Short Hold Time Analysis (<72 hr.)? ❑ Yes ❑ No 11 N/A 3, Rush Turn Around Time Requested? ❑ Yes ❑ No @ N/A 4. Sufficient Volume? 10Yes ❑No ❑N/A S. Correct Containers Used? -Pace Containers Used? gYes RYes ❑ No ❑ No ❑ N/A ❑ N/A S. Containers Intact? 10 Yes ❑ No ❑ N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes ❑No ®N/A 8. Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matrix: I@ Yes W t ❑ No (J N/A 9. Headspace in VOA Vials (>S-6mm)? ❑Yes ❑ No N/A 10, Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes ❑Yes ❑No ❑No I2N/A Ig N/A 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers; CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review; Date/Time: Date: Date: Field Data Required? U Yes U No Qualtrax IQ: 69614 Paae 1 of 2 Page 43 of 47 f LAVV 1 Effective Date: 11/14/2022 'Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DA018015 (water) DOC. LLHC '*Bottom half of box is to list number of bottles ***Check all unpreserved Nitrates for chlorine Project 4 I WO# : 92726234 PM: 5K Due cote: 05/28/24 CLIENT: KR-RuthLandf 4 Z a n Q ? r, .-. Z Z R 7 9 7 9 r-1 C tt r, y V _ 1 r > v = w N e n a n n '0 al ,r �. nCIL 2 2 y ` Z Z CL a M a, O 0 0 0 d n CLQ " tl Gv, � � � v t � M y z C C c o �^ z ¢ t7 ii C N c 2 N a 3 c x = Ia li Z n = ry a Oa D r, m Y 2 ry a CL 12 = m a I u Gou D a Z Q Q Y .—� M a a a m CLd a ° E E d c q E O 0 O 0 N a 1 J a J E Q 4 ¢ ¢ > > ? > iL N J J E E E d c E E E c E E l E E a E E N ..+ N V tl tl y 7 1A .rn-. " N R 3 N Z N m LL i S vl v+ V Z r , > j Y Q M N V m V q •/ N M .r M a In C, � T 4, a a CL a n a A. I a to Q +9 d a a m m m Co cc co l 0 fl m 3 ¢ ¢ a a a o o a > a x � v, ,n Ji Z 3 \N1 r NN ----� I— — 4 1z pH Adjustment log for Preserved Samples Sample 10 Type of Preservative PH upon recelpt i Date preservation adjusted Time preservation 1 adjusted I Amount al Preservative added Lot It µ s I 1 Not@ Whenever there IS a discrepancy affecting North Carolina compliance Samples, a Copy of eh,s lorni .vlll be Sent to thr North Carolina DENR Cert1liCat1o11 Office (, e Out of hold, Incorrect preservative, out of ',enip, InCorrect conlainCrS. Qvaltrax ID. 69614 Page 2 of 2 Page 44 of 47 1 NVV Effective Date: 11/14/2022 `Check mark tap half of box if pH and/or dechlorination is verified and Project B within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOE, Oil and Grease, DRO/8015 (waterl DOC, LLHR "Bottom half of box is to list number of bottles •**Check all unpreserved Nitrates for chlorine b _ Z a y u v n s d Y `+ = a o a+ 'L r�1 CI Z n 4 17 n �� v C C C 0. O z O U 0. C ,may R 2 Of V J T 0. 7 D z c ''' S Z a c } n A U m c m d a IOU 2 2 ] S u m U a a a ° E E a q E 0 p O O 9 n W M J J E a q J a Q 5 7 > > a H � E E ;, E E E s v d ° p `v G c E E E E E E N 4 = N ry r•I I 7i , `^ — n O 4 O tiJ C O rAi v0i ,y N ,y .y .•� N Q O R 'T f `� M .-1 rl x 7 7 7 yr Z H m 7 Y +n ve v 2 N > > Y E Q M N ..l V rn a v ,-+ ,s M .•. M M 71 0% m m n L7 IM n al d a a a a a a 0. [7 V 0 V' to W t7 V 0 a Il n ra m as m m m m m ¢ Q Q Q ¢ ❑ o > IN\ s N I I —jN l I I I 6 7 8 9 10 11 12 I pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative lot # adjusted added Note Whenever there Is a discrepancy affecting North Carolina compliance samples. a copy of this farm %vlll be sent to the North Carolina DENR Certification Office Ise Out of hold, Incorrect preservative, out of temp, Incorrect containers. Qualtrax lb_ 69614 Page 2 of 2 Page 45 of 47 Pace° Location Requested (Cjty/State): LAB USE ONLY. Affix WorkordertLogin Label Here Pace Analytical Charlotte CHAIN -OF -CUSTODY Analytical Request Document -,g9900 Kincey Ave. Suite 100, Huntersville, NC 28079 Chain -of -Custody is a LEGAL DOCUMENT - Complete all relevant fields (ace 0 �� Company Name: Rutherford County Landfill Contact/Report Tw James Kilgo Street Address: PO Box 1957, Rutherfordton, NC 28139 Phone e: 828.287.6002 k E-Mail: james.kilgo@rutherfordcountync.gov Scan OR Code for instructions Cc E-Mail: Customer Project R: Specify Container Size " "Contamer Size: (1)1L (2) SOOmL. (3) 2SDmL 141 125mL (51100mL (6140m1. vial, (71 Encore, la) Invoice To: Accounts Payable Project Name: Rutherford Co. LF - South PFAS TerraCore. (9) 90mL 110) Other Invoice E-Mail: james.kilgo@rutherfordeountync.gov Identify Container Preservative Type— --' Prmmt" Types: It) None,121 HNO3, (3) Sit? Collection Info/Facility 10 (as applicable]: Purchase Order M (if MCI, (51 NaOM, Zn Acetate, cAdd. NaHSO applicablel: . ( ite hol r4coM, p1)Other Analysis Requested Ys eV Proj. Mgr; Stephanie Knott quote #: Time ZarR Collected: [ )AK [ ] PT [ ] MT I )CT [ ] ET County / State origin of sample(s)• North Carolina Oata Deliverables: Regulatory Program (DW, RCRA, etc.) as applicable: Reportable I ] Yes [ ] No ActtNum / Client to: c [ ]Level II ] level I I ;Level IV m Y Rush (Pre -approval required): DW PWSIn R or WW Permit tr as applicable. Table N: 11 Same Day I I I Day i; 2 Day I: 3 Day I I Other. Q E d 4 6 l EQUIS m 8 A Date Results Field Filtered (if applicable): [ ] Yes [ ] No 3 Profile / Template other Requested: Analysis: to W 17056 2 `a ' Matrix Codes Ilnsert n Matrix box belowl: Drinking Water:DW), Ground Water (GW), Waste Water I WW], Product (P), Soil Solid (SS1. 0 (OL). W'pe (WP), Tissue (TS , Bioassay Prelog / Bottle Ord. ID: (61, Vapor V Surface Water SW Sediment (SED1, S ud a SL Caulk (CKI, Leachate JLQ. Siosolid(BSI, Other OT H to ro 0 EZ 3097820 d [dmp / Composite Start Collected or Composite End N Res. Chlorine Customer Sample ID Maw Grab CoM. a a Sample Comment o` Date Time Date Time Results Units 8102 - M W 4A WT � 4.5 X X 8102 MW-1 WT UWD X X 8102 MW-2A WT X X 8102 - PAW-3 WT �1%� X X 8102 MW-5 WT 1000X X 8102 - MW'6 WT 12315 X X 8102-MW 7 WT �A%N X X 8102 - MW-8 WT IOLL5 X X 8102-MW-95 WT lobo X X 9102 - M W-90 WT ! m X X Additional Instructions from Patel: Collected By: jj�� n Customer Remarks / Special Conditions / Possible Hazards: �,SaatVlrarr' • (Printed Nam;0Z Signature:11 VVCC..f�//�"''' l a gaolers: TRermomeW iD; Correction Factor ('q: OM. Temp. ('q Corrected Temp. ('Cl On ice: Relinquished by/Com any: i;ignaturel Date/Time: KeeeivR by/Company: I atuj�I Dat ime: Tracking Number: 10 l C tllf - 14 kA gDoo Relinquished by/Company; 15ianature) Date/Time: Received by/Company: iggnature) Dateh e' Delivered by [ ] In- Person [ )Courier [ ] FtdEx ( )VPS ( ]Other RelinquUed by/Company isignaiure) Datepme: Received by/Company; (Signature) Date/rime: 0) to Relinq hed by/Company: (Signature) Dater? e: Received by/Company: (Signatuiel Datefrime: Page: 1 of 2 � rn Submirt` ting a sample via this chain of custody constitutes acknowledgment and acceptance of the Pace- Terms and Conditions found at http5://www.pacelaos.comfresource-norary/resourcefpace-terms-and-concHians! W_ r _. _ w.�.. 4 Pace° Location Requested (City/State): Pace Analytical Charlotte CHAIN -OF -CUSTODY Analytical Request Document 9800 Kincey Ave. Suite 2D0, Huntersville, NC 28078 Chain -of -Custody is a LEGAL DOCUMENT • Complete all relevant fields LA13 USE ONLY. Affix WorkorderfLogin Label Here Scan QR Code for instructions Company Name: Rutherford County Landfill Street Address: PO Box 1957, Rutherfordton, NC 28139 Customer ProieCt Ir: Project Name: Rutherford Co. LF - South PFAS Site Collection Info/Facility ID (as applicable): Contact/Report To: James Kilgo Phone #: 828-287-6002 E-Mail: james.kilgo@rutherfordcounrync.gov Cc E-Mail; Specify Container Size •• ••Container Si- p] IL, (2) 500m1,13) 150mL, (4) 12SmL (S)100M1,18) 40mi. dal (71 EnCore, (8) Term.',, (9) 90mL, (10) Other lnvoice To: Accounts Payable Invoice E-Mail: james.kilgo@rutherfordcountync.gov Purchase Order at (if applicable): Quote P: Identify Container Preservative Type"' ••• preservative Types: of Nona 121 HN01, O) 1-12504, (4) Ho, (5) NaOH, is) Zn Meat., (7) NaHSO4, (8) Sod. Thiosulfate, 191 Ascorbic Acid, 1101 Me0H, D 11 other Analysis Requested to (n H W Q u- a _m to ¢ a Proj. Mgr: Stephanie Knott `o - v � d E 3 .p a Time Zone Collected: I ] AK [ ] PT ( ) MT ( ) CT I JET lCounty / State origin of sample(s): North Carolina Data Deliverables: Regulatory Program (DW, RCRA, etc.) as applicable: Reportable [ I Yes ( ] No Level II [ ] Level lit I ] Level IV ( I RUSK (Pro -approval required): DW PWSID x or WW Permit p as applicable: ( ) Same Day [ ) 1 Day 1 ) 2 Day I ] 3 Day [ I Other [ ) E4U15 Date ResuRx Field Filtered (if applicable): [ ] Yes [ ] No Other Requested: Analysis: • Matrix Codes {Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Waste Water (WW), Product (P], Soil Solid (SS, Oil (OLI, Wipe (WP), Tissue (TS), ftassa 8 VaporIV),Surface Water SW Sediment SED Sludge ISL), Cautk 4CKJ achate LL Biosolid(BSI, OtherJOT) AcctNum / Client ID: 0 N Table R; 3 Profile / Template: 17056 Prelog / Bottle Ord. ID: IFZ 3097820 Customer Sample ID Matrix • Comp / Grab Composite Start Collected or Composite End k Con,, Res. Chlorine Sample Comment Date Time Date Time Results Units 8102 - SW-1 WT '"tr �e� w X X 8102 - SW-2 WT low X X 8102 - Field Blank WT `' X X 8102 - Equipment Rinse WT / X X Additional Instructions from Pace*: Collected By: { { 1fy -` (- (Printed Name► N tiZLC h&vni Signature: FFF 1 Customer Remarks / Special Conditions / Possible Hazards: e Coolers: Thermometer ID: Correction Factor MI: Oh. Temp. 1'C) Corrected Temp. ['CI On Ice: Relinquished by/Company: (Signaturel p LVC - i Date/Time: `t 44 �+Q MOD Received by/Company: (Signature) V'— 0 rn p/ �� f/ Tracking Number; Relinquished by/Company: (Signature) Date>T . Received by/Company: (Signature) Date/Trme: Delivered by: [ ) in. person ( ]Courier I I FedEx ( ]ups 1 3 Other Reimqudied by/Company: (Signaeure) o Datetrime; Received by/Company: (Signature) Datelnme: Aelinq hed bylCompaev: (Signature) _0,Page: 4 Daeeri— Received bYJCor^pany: [Signature} Datefrime: 2 of 2 Subm'Aing a sample via this chain of tustody constitutes acknowledgment and acceptance of the Pace' Terms and Conditions found at https://Www.paceiaos.comlresource-Norary/resourcelpace-terms-ano-conoluons/ CIY V-fRrvr� VRt. w 1 _Y _ V ILA . 4