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HomeMy WebLinkAbout09015_TownandCounty_ O&M Plan_20240624 Via Email June 24, 2024 NCDEQ – Division of Waste Management Brownfields Redevelopment Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Attn: Ms. Carolyn Minnich Re: Operations & Maintenance Plan Town & Country Rent-A-Car 5324 E. Independence Boulevard Charlotte, North Carolina Brownfields Project No. 09015-05-060 H&H Project No. DCT-001 Dear Carolyn: On behalf of AAN Real Estate LLC, please find the enclosed revised Operations & Maintenance Plan prepared for the Town & Country Rent-A-Car Brownfields property for your review and approval. Should you have questions or need additional information, please do not hesitate to contact us. Sincerely, Hart & Hickman, PC Ralph McGee, PG Haley Martin, PG Senior Project Manager Project Manager Enclosures cc: Mr. Dave Morris, AAN Real Estate LLC (via email) Ms. Joselyn Harriger, DEQ Brownfields (via email) Mr. David Peacock, DEQ Brownfields (via email) Attachment: TOWN & COUNTRY RENT-A-CAR 5234 E. Independence Boulevard Charlotte, North Carolina Brownfields Project No. 09015-05-060 OPERATIONS & MAINTENANCE PLAN H&H JOB NO. DCT-001 MAY 15, 2024 REVISED JUNE 24, 2024 2923 S Tryon Street, Suite 100 Charlotte, NC 28203 704 586 0007 harthickman.com Raleigh, NC 27607 919 847 4241 #C-1269 Engineering / #C-245 Geology i https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/direct uniform/o&m plan/09105 - om plan - town country.docx Operations & Maintenance Plan Town & Country Rent-A-Car 5324 E. Independence Boulevard Charlotte, North Carolina H&H Job No. DCT-001 Table of Contents 1.0 Introduction .............................................................................................................................1 2.0 Current Chemical Storage .....................................................................................................3 3.0 Spill Prevention and Response ...............................................................................................5 3.1 Spill Prevention Measures .....................................................................................................5 3.2 Spill Response and Notification ............................................................................................5 3.3 Site Decommissioning ...........................................................................................................7 4.0 Plan Implementation and Approval ......................................................................................9 List of Figures Figure 1 Site Location Map Figure 2 Site Map List of Appendices Appendix A Site Photographs Appendix B Safety Data Sheets Appendix C Spill Report Form 1 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/direct uniform/o&m plan/09105 - om plan - town country.docx Operations & Maintenance Plan Town & Country Rent-A-Car 5324 E. Independence Boulevard Charlotte, North Carolina H&H Job No. DCT-001 1.0 Introduction On behalf of AAN Real Estate LLC, Hart & Hickman, PC (H&H) has prepared this Operations and Maintenance Plan (O&M Plan) for the Town & Country Rent-A-Car Brownfields property (Brownfields Project No. 09015-05-060) located at 5324 E. Independence Boulevard in Charlotte, Mecklenburg County, North Carolina (Site). The Site consists of one approximately 1.6-acre parcel of land (Mecklenburg County Parcel Identification No. 16303226) developed with an approximately 6,220 square foot (sq ft) unoccupied car wash facility and an approximate 2,130 sq ft auto repair garage. Remaining portions of the Site consist of asphalt and concrete-paved vehicle access and parking areas and vegetated areas. A Site location map is provided as Figure 1, and the Site and surrounding area are shown in Figure 2. The Site is located in a historically commercial and industrial-use area of Charlotte. Prior to the early 1950s, the Site consisted of agricultural and vegetated land. By the mid-1950s, the Site was developed with commercial structures. Before the early 1990s, the Site was utilized for heating oil distribution, a gas station, and an automotive repair facility. In the early 1990s, the Site was acquired by Reflections Carwash. In the late 1990s, the Site was occupied by Town & Country Rent-A-Car for vehicle rentals. LB Auto Repair is the current Site occupant and utilizes the approximate 2,130 sq ft auto service garage for limited automotive repair operations. Based on potential environmental concerns associated with historical uses, the Site was entered into the North Carolina Department of Environmental Quality (DEQ) Brownfields Redevelopment Section (Brownfields Project No. 09015-05-060). A Notice of Brownfields Property and Brownfields Agreement was recorded on the property deed on November 19, 2007. This O&M Plan has been prepared to identify and implement Best Management Practices (BMPs) for current chemical storage, provide an inventory of existing chemicals stored at the Site, and spill release 2 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/direct uniform/o&m plan/09105 - om plan - town country.docx prevention for ongoing auto repair operations to remain in compliance with the land use restrictions (LURs) outlined in the recorded Brownfields Agreement. 3 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/direct uniform/o&m plan/09105 - om plan - town country.docx 2.0 Current Chemical Storage On April 22, 2024, H&H completed a Site visit to observe current LB Auto Repair operations at the Site. H&H also conducted interviews with LB Auto Repair personnel at the time of the Site visit. A photographic log of Site visit observations is provided in Appendix A. LB Auto Repair operations include auto inspections, oil and transmission fluids changes, brake repairs, tire repair and alignment, and other general vehicular maintenance. LB Auto Repair operations do not include engine or transmission repairs, painting, or other auto body repairs. H&H also documented waste streams and associated disposal methods employed at the Site. Copies of safety data sheets (SDS) for chemicals observed during the April 2024 Site visit are provided in Appendix B. H&H identified the following chemicals during the April 2024 Site visit: Chemicals: new and used motor oil new and used anti-freeze hydraulic fluid used oil filters retail sized auto maintenance products retail sized cleaning products vehicle batteries 5-gallon containers of Purple Power degreaser/ cleaning compound H&H observed used motor oil and transmission fluid stored in an approximately 350-gallon steel AST within a cinderblock secondary containment area on a concrete pad located on the northern exterior of the Site building (Photograph 2 and Photograph 3). The AST is emptied on an as- needed basis by a third-party contractor and transported off-Site for recycling. A representative photo of the waste disposal manifest provided by the third-party contractor is provided as Photograph 7. H&H observed a steel 55-gallon drum containing used oil filters. The 55-gallon drum was staged on the concrete slab within the auto repair building. The concrete in the vicinity of the drum appeared to be in good condition with no obvious evidence of significant staining, cracks, seams, pitting, or other evidence of degradation. The drum is emptied on an as-needed basis by a third- 4 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/direct uniform/o&m plan/09105 - om plan - town country.docx party contractor and transported off-Site for disposal. A representative photo of the waste disposal manifest provided by the third-party contractor is provided as Photograph 8. Solid non-hazardous wastes at the Site are placed in waste containers located outside the Site building and disposed off-Site at the municipal solid waste landfill. H&H did not observe evidence of staining or other obvious evidence of a release to the concrete pad below the waste receptacles. H&H observed multiple new oil storage containers staged on a metal storage rack within the Site building (Photograph 4). In addition, retail-sized containers of non-chlorinated brake cleaner, antifreeze, power steering fluid, transmission fluid, lubricants, and adhesives are stored within or on storage cabinets within the Site building (Photograph 5 and Photograph 6). In addition, H&H observed unopened 5-gallon containers of Purple Power degreaser/cleaning solution and an unopened 5-gallon container of hydraulic fluid stored within the Site building. The concrete below and in the vicinity of the stored chemicals appeared to be in good condition and H&H did not observe obvious evidence of staining, cracks, seams, pitting, or other evidence of degradation to the concrete floor below the new oil storage rack or stored chemicals. 5 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/direct uniform/o&m plan/09105 - om plan - town country.docx 3.0 Spill Prevention and Response 3.1 Spill Prevention Measures Based on Site visit observations, the following best management practices can be implemented to minimize potential spills at the Site: • Stage new oil storage rack and other small containers of materials (e.g., degreaser/cleaner and hydraulic fluid) on Uline spill containment pallets. Smaller mobile containers do not require secondary containment but will continue to be stored inside chemical storage cabinets when not in use. • Store used oil filters and soiled rags in appropriate sealable containers until transported off- Site for disposal. • Fluids collected in drip pans should be transferred into the on-Site used oil AST daily. The used oil AST will be emptied on an as-needed basis by a third-party contractor. • Stage the used oil AST within the covered concrete secondary containment system located along the northern portion of the Site building. • When not in use, secure the used oil AST with an appropriate cap and immediately clean drips when transferring used oil to or from the tank. 3.2 Spill Response and Notification Spill Response Procedures 1. Contain the spill in the smallest possible area. Designate an area of the facility with spill containment equipment and materials. If it can be done safely, use absorbent materials such as pads, socks, or other absorbent materials to contain the spill. 2. Begin the notification procedures. Contact H&H via the Emergency Notification Phone List below, and H&H will determine if outside contractors are needed to help clean a spill or if governmental agency reporting is required. 6 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/direct uniform/o&m plan/09105 - om plan - town country.docx 3. Recover or clean up the spilled material. As much material as possible should be recovered where appropriate. Liquids absorbed by solid materials should be shoveled into open-top drums or other appropriate containers. When drums are filled or the cleanup has been completed, the drum lids should be secured and appropriately labeled identifying the contents. When possible, efforts should be made to avoid mixing different waste types. Arrange for disposal of the waste material following applicable Federal and State regulations and maintain disposal documentation. 4. Evaluate the cause and effectiveness of the response. Determine the cause of the incident and evaluate if practices or spill response procedures need to be modified. Correct the deficiencies, as needed. Notification Procedures 1. Briefly assess the severity of the discharge, determining the extent and nature of the event by considering the questions: • Does the discharge represent a release to the environment? • Could any release that gets outside of a building or outside of an impervious containment area be a release to the environment? • Does the quantity of material discharged represent a harmful quantity? 2. Call each Emergency Spill Response Coordinator identified on the below Emergency Notification Phone List until contact is made and remain on the scene until that person arrives. 3. Evacuate non-essential personnel from the area affected by the discharge. 4. Determine if a reportable quantity (RQ) of the spilled material has been exceeded, or if the release has reached waters of the U.S. If so, notify DEQ and the National Response Center (NRC) as appropriate. The RQ to DEQ for petroleum is 25 gallons. 7 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/direct uniform/o&m plan/09105 - om plan - town country.docx 5. If outside discharge cleanup assistance is needed, contact the emergency response contractor or the fire department’s HAZMAT team from the Notification List provided above. 6. If medical assistance is needed, call 911. Emergency Notification Phone List Contacts Response Role Office Phone 24-Hour Phone AAN Real Estate LLC Site Contact (Property Owner) (704) 664-2204 (704) 975-1848 Ralph McGee (704) 887-4621 (704) 840-4775 Haley Martin (704) 526-2045 (704) 506-8107 National Response Center Incident Reporting EPA Region IV Incident Reporting Incident Reporting (704) 235-2100 Joselyn Harriger DEQ Brownfields Incident Reporting (980) 297-4623 Fire Department & HazMat Team Emergency Medical, HazMat Response 911 911 3.3 Site Decommissioning The facility will be decommissioned before the end of the LB Auto Repair lease period including removal of chemicals, storage containers, and wastes. The Brownfields Redevelopment Section will be notified at least 10 days prior to the start of decommissioning activities. Wastes will be transported by licensed waste haulers and disposed off-Site at facilities permitted to accept such wastes. Following notice from the property owner that the LB Auto Repair lease period has ended, and the tenant has vacated the Site, H&H will complete a final Site inspection to verify compliance with this O&M Plan. H&H will notify AAN Real Estate LLC if observations indicate potential non-compliance with the O&M Plan and/or Brownfields Agreement and recommend corrective measures. Following 8 https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/direct uniform/o&m plan/09105 - om plan - town country.docx the completion of the recommended corrective action (if applicable), AAN Real Estate LLC will request a follow-up final Site inspection. H&H will document observations, corrective measures (if any), and decommissioning activities in a Site Inspection Report. A copy of the Site Inspection Report will be provided to the Brownfields Redevelopment Section for their records. REVISION NO. 0 JOB NO. DCT-001 DATE: 5-7-24 FIGURE NO. 2 TOWN & COUNTRY RENT-A-CAR 5324 EAST INDEPENDENCE BOULEVARD CHARLOTTE, NORTH CAROLINA SITE MAP LEGEND BROWNFIELDS PROPERTY BOUNDARY PARCEL LINE POLE-MOUNTED TRANSFORMER 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology NOTES: 1. AERIAL IMAGERY AND BASE DATA OBTAINED FROM MECKLENBURG COUNTY GIS, 2024. CONNECTION P O I N T B O U L E V A R D EAS T I N D E P E N D E N C E B O U L E V A R D ZEUS S T R E E T ZE P H Y R W I N D W A Y LO N G A V E N U E AMERICAN ARMY NAVY SURPLUS STORE (5326 EAST INDEPENDENCE BOULEVARD) FRAME WAREHOUSE (5300 EAST INDEPENDENCE BOULEVARD) MECKLENBURG COUNTY ABC STORE #8 (4047 CONNECTION POINT BOULEVARD) UNDER CONSTRUCTION 7-ELEVEN (6101 IDLEWILD ROAD) CHIPOTLE MEXICAN GRILL (4022 CONNECTION POINT BOULEVARD) MULTI-TENANT COMMERCIAL PROPERTY (5301-5323 EAST INDEPENDENCE BOULEVARD) LB AUTO REPAIR VACANT CAR WASH S: \ A A A - M a s t e r P r o j e c t s \ D i r e c t U n i f o r m \ S o i l R e m o v a l W o r k P l a n \ F i g u r e s \ D C T . 0 0 1 _ 2 0 2 4 0 5 0 7 . d w g , F I G 2 , 5 / 1 4 / 2 0 2 4 8 : 1 5 : 3 9 A M , d r a b u r n Appendix A Site Photographs Photograph 1: Typical view of the Brownfields property TOWN & COUNTRY RENT-A-CAR 5324. INDEPENDENCE BOULEVARDCHARLOTTE, NORTH CAROLINA 2923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) Photograph 2: Location of the waste oil AST staged in secondary containment Photograph 3: View of the waste oil AST located in the covered secondary containment area 2923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) Photograph 4: View of the former location of the waste oil AST TOWN & COUNTRY RENT-A-CAR 5324. INDEPENDENCE BOULEVARDCHARLOTTE, NORTH CAROLINA Photograph 5: View of the chemical storage area within the Site building 2923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) Photograph 6: View of the retail-sized chemical storage observed within the Site building TOWN & COUNTRY RENT-A-CAR 5324. INDEPENDENCE BOULEVARDCHARLOTTE, NORTH CAROLINA Photograph 7: Representative photo of the used oil waste manifest. 2923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) Photograph 8: Representative photo of the used oil waste and used filters manifest. TOWN & COUNTRY RENT-A-CAR 5324. INDEPENDENCE BOULEVARDCHARLOTTE, NORTH CAROLINA Appendix B Safety Data Sheets Safety Data Sheet Issue Date: 05-Jun-2014 Revision Date: 20-May-2015 Version 1 ____________________________________________________________________________________________ Page 1 / 8 1. IDENTIFICATION Product Identifier Product Name CARQUEST Premium Hi-Temp Disc Brake Wheel Bearing Grease Other means of identification SDS # CQ-037 Recommended use of the chemical and restrictions on use Recommended Use Lubricant. Details of the supplier of the safety data sheet Supplier Address Warren Oil Company 915 E. Jefferson Ave. West Memphis, AR 72301 Emergency Telephone Number Company Phone Number 1-800-428-9284 Emergency Telephone (24 hr) CHEMTREC 1-800-424-9300 (North America) 1-703-527-3887 (International) 2. HAZARDS IDENTIFICATION Appearance Amber semi-solid to solid Physical State Semi-solid to solid Odor Mild petroleum Classification Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Hazards Not Otherwise Classified (HNOC) May be harmful if swallowed Signal Word Warning Hazard Statements Causes skin irritation Causes serious eye irritation Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear eye/face protection CQ-037 - CARQUEST Premium Hi-Temp Disc Brake Wheel Bearing Grease Revision Date: 20-May-2015 _____________________________________________________________________________________________ ____________________________________________________________________________________________ Page 2 / 8 Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water Take off contaminated clothing and wash it before reuse If skin irritation occurs: Get medical advice/attention Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Unknown Acute Toxicity 2.27% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Severely Hydrotreated Heavy Naphthenic Petroleum Oil 64742-52-5 60-70 Residual oils (petroleum), solvent refined 64742-01-4 1-10 Antimony diamyldithiocarbamate 15890-25-2 1-10 Lithium Hydroxide Solution 1310-66-3 1-10 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentageof composition has been withheld as a trade secret.** 4. FIRST-AID MEASURES First Aid Measures General Advice If exposed or concerned: Get medical advice/attention. Take proper precautions to ensureyour own health and safety before attempting rescue or providing first aid. Eye Contact Check for and remove contact lenses. Flush eyes with cool, clean, low-pressure wate while occasionally lifting and lowering eyelids. Seek medical attention if excessive tearing,redness or pain persists. Skin Contact If burned by hot material, cool skin by quenching with large amounts of cool water. Focontact with product at ambient temperatures, remove contaminated shoes and clothing.Wipe off excess material. Wash exposed skin with mild soap and water. Seek medicalattention if tissue appears damaged or if pain or irritation persists. Thoroughly cleancontaminated clothing before reuse. Clean or discard contaminated leather goods. Imaterial is injected under the skin, seek medical attention immediately. Inhalation Vaporization is not expected at ambient temperatures. This material is not expected tocause inhalation-related disorders under anticipated conditions of use. In case ooverexposure, move the person to fresh air. Ingestion Do not induce vomiting unless directed to by a physician. Rinse out mouth with water. Never give anything by mouth to a person who is not fully conscious. Allow small quantitiesto pass through the digestive system. If large amounts are swallowed or irritation odiscomfort, seek medical attention immediately. Most important symptoms and effects Symptoms May be harmful if swallowed. Causes skin irritation. Causes serious eye irritation. CQ-037 - CARQUEST Premium Hi-Temp Disc Brake Wheel Bearing Grease Revision Date: 20-May-2015 _____________________________________________________________________________________________ ____________________________________________________________________________________________ Page 3 / 8 Indication of any immediate medical attention and special treatment needed Notes to Physician Skin: In the event of injection in underlying tissue, immediate treatment should includeextensive incision, debridement and saline irrigation. Inadequate treatment can result inischemia and gangrene. Early symptoms may be minimal. Ingestion: Check for possible bowel obstruction with ingestion of large quantities of material. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use dry chemical, foam, carbon dioxide or water fog. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Water or foam may cause frothing. Molten material can form flaming droplets if ignited. Use of water on product above 100°C (212°F) can cause product to expand with explosive force. Hazardous Combustion Products Carbon dioxide, carbon monoxide, smoke, fumes, unburned hydrocarbons and oxides osulfur, phosphorus, zinc and/ or nitrogen. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Carbon dioxide and inert gas can displace oxygen. Use caution when applying carbon dioxide or inert gas inconfined spaces. Fight the fire from a safe distance in a protected location. Open any masses with a water stream to prevent re-ignition due to smoldering. Cool surface with water fog. Do not allow liquid runoff to enter sewers or public waters. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Take proper precautions to ensure your own health and safety before attempting spillcontrol or clean-up. For more specific information, refer to section 8. Do not touchdamaged containers or spilled material unless wearing appropriate protective clothing.Slipping hazard; do not walk through spilled material. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Prevent entry into waterways, sewer, basements or confined areas. Methods for Clean-Up For small spills, absorb or cover with dry earth, sand or other inert non-combustible absorbent material and place into waste containers for lateral disposal. Contain large spills to maximize product recovery or disposal. In urban areas, clean up spill as soon aspossible. In natural environments, seek clean up advice from specialists to minimizephysical habitat damage. 7. HANDLING AND STORAGE Precautions for safe handling CQ-037 - CARQUEST Premium Hi-Temp Disc Brake Wheel Bearing Grease Revision Date: 20-May-2015 _____________________________________________________________________________________________ ____________________________________________________________________________________________ Page 4 / 8 Advice on Safe Handling If this product is stored or applied in high-pressure systems such as grease guns o hydraulic lines, there is the potential for accidental injection into the skin and underlyingtissues. Empty containers may contain product residue that can ignite with explosive force.Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat,sparks or open flames. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Incompatible Materials Strong oxidizing agents. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Severely Hydrotreated Heavy Naphthenic Petroleum Oil 64742-52-5 TWA: 5 mg/m3 (oil mist) STEL: 10 mg/m3 (oil mist) TWA: 5mg/m3 (oil mist) STEL: none estab. TWA: none estab. STEL: none estab. Antimony diamyldithiocarbamate 15890-25-2 TWA: 0.5 mg/m3 Sb TWA: 0.5 mg/m3 Sb (vacated) TWA: 0.5 mg/m3 Sb IDLH: 50 mg/m3 Sb TWA: 0.5 mg/m3 Sb Barium Sulfonate 25619-56-1 TWA: 0.5 mg/m3 Ba TWA: 0.5 mg/m3 Ba (vacated) TWA: 0.5 mg/m3 Ba TWA: 0.5 mg/m3 except Barium sulfate Ba Appropriate engineering controls Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborneconcentrations of vapors below their respective threshold limit value. Ensure that eyewashstations and safety showers are proximal to the work-station location. Individual protection measures, such as personal protective equipment Eye/Face Protection Wear safety glasses with side shields (or goggles). Skin and Body Protection Chemical resistant, impermeable gloves. Long sleeve shirt and long pants. Aprons. Wear alab coat. Respiratory Protection Ensure adequate ventilation, especially in confined areas. In case of inadequate ventilationor risk of inhalation of vapors, use suitable respiratory equipment. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Semi-solid to solid Appearance Amber semi-solid to solid Odor Mild petroleum Color Amber Odor Threshold Not determined Property Values Remarks • Method pH Not available Melting Point/Freezing Point Not available Boiling Point/Boiling Range Not available Flash Point 150 °C / 302 °F Open cup Evaporation Rate Not available CQ-037 - CARQUEST Premium Hi-Temp Disc Brake Wheel Bearing Grease Revision Date: 20-May-2015 _____________________________________________________________________________________________ ____________________________________________________________________________________________ Page 5 / 8 Flammability (Solid, Gas) Not determined Upper Flammability Limits Not available Lower Flammability Limit Not available Vapor Pressure <01001 kPA (<0.01 mm Hg)(at 20°C) Vapor Density >10 (Air=1) Specific Gravity 0.93 (Water = 1) Water Solubility Negligible Solubility in other solvents Not determined Partition Coefficient Not determined Property Values Remarks • Method Auto-ignition Temperature Not available Decomposition Temperature Not determined Kinematic Viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Not expected to occur. Conditions to Avoid Keep away from extreme heat, sparks, open flame and incompatible materials. Incompatible Materials Strong oxidizing agents. Hazardous Decomposition Products Carbon dioxide, carbon monoxide, smoke, fumes, unburned hydrocarbons and oxides of sulfur, phosphorus, zinc and/ or nitrogen. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact Causes serious eye irritation. Skin Contact Causes skin irritation. Inhalation Do not inhale. Ingestion May be harmful if swallowed. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 CQ-037 - CARQUEST Premium Hi-Temp Disc Brake Wheel Bearing Grease Revision Date: 20-May-2015 _____________________________________________________________________________________________ ____________________________________________________________________________________________ Page 6 / 8 Lubricating oils (petroleum), hydrotreated spent 64742-58-1 > 2000 mg/kg ( Rat ) > 4480 mg/kg ( Rabbit ) - Residual oils (petroleum), solvent refined 64742-01-4 > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) = 2.18 mg/L ( Rat ) 4 h zelaic acid 123-99-9 > 5 g/kg ( Rat ) - - Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity This product does not contain any carcinogens or potential carcinogens as listed by OSHA,IARC or NTP. Numerical measures of toxicity Not determined Unknown Acute Toxicity 2.27% of the mixture consists of ingredient(s) of unknown toxicity. 12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms Crustacea Severely Hydrotreated Heavy Naphthenic Petroleum Oil 64742-52-5 5000: 96 h Oncorhynchus mykiss mg/L LC50 1000: 48 h Daphnia magna mg/L EC50 Lubricating oils (petroleum), hydrotreated spent 64742-58-1 79.6: 96 h Brachydanio rerio mg/L LC50 semi-static 3.2: 96 h Pimephales promelas mg/L LC50 semi-static Residual oils (petroleum), solvent refined 64742-01-4 5000: 96 h Oncorhynchus mykiss mg/L LC50 1000: 48 h Daphnia magna mg/L EC50 Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Not determined Other Adverse Effects Not determined 13. DISPOSAL CONSIDERATIONS CQ-037 - CARQUEST Premium Hi-Temp Disc Brake Wheel Bearing Grease Revision Date: 20-May-2015 _____________________________________________________________________________________________ ____________________________________________________________________________________________ Page 7 / 8 Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Status Chemical Name California Hazardous Waste Status Antimony diamyldithiocarbamate 15890-25-2 Toxic 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT Not regulated IATA Not regulated IMDG Not regulated 15. REGULATORY INFORMATION International Inventories Chemical Name TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS Severely Hydrotreated Heavy Naphthenic Petroleum Oil Present X Present Present X Present X X Residual oils (petroleum), solvent refined Present X Present X Present X X Antimony diamyldithiocarbamate Present X Present Present X X X Lithium Hydroxide Solution Present X X X Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments andReauthorization Act (SARA) (40 CFR 355). CQ-037 - CARQUEST Premium Hi-Temp Disc Brake Wheel Bearing Grease Revision Date: 20-May-2015 _____________________________________________________________________________________________ ____________________________________________________________________________________________ Page 8 / 8 SARA 313 Chemical Name CAS No Weight-% SARA 313 - Threshold Values % Antimony diamyldithiocarbamate - 15890-25-2 15890-25-2 2.25 1.0 CWA (Clean Water Act) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Antimony diamyldithiocarbamate X US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania Antimony diamyldithiocarbamate 15890-25-2 X X Lithium Hydroxide Solution 1310-66-3 X Barium Sulfonate 25619-56-1 X X 16. OTHER INFORMATION NFPA Health Hazards 1 Flammability 1 Instability 0 Special Hazards Not determined HMIS Health Hazards 1 Flammability 1 Physical Hazards 0 Personal Protection Not determined Issue Date: 05-Jun-2014 Revision Date: 20-May-2015 Revision Note: New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet   Product Name: TOYOTA GENUINE ATF WS Revision Date: 12 May 2016 Page 1 of 12 ______________________________________________________________________________________________________________________ SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: TOYOTA GENUINE ATF WS Product Description: Base Oil and Additives Product Code: 202030206522, 521377-00, 97Z693 Intended Use: Automatic transmission fluid COMPANY IDENTIFICATION Supplier: EXXON MOBIL CORPORATION 22777 Springwoods Village Parkway Spring, TX 77253 USA 24 Hour Health Emergency 609-737-4411 Transportation Emergency Phone 800-424-9300 or 703-527-3887 CHEMTREC Product Technical Information 800-662-4525 MSDS Internet Address http://www.exxon.com, http://www.mobil.com This material is not hazardous according to regulatory guidelines (see (M)SDS Section 15). Other hazard information: HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1910.1200. PHYSICAL / CHEMICAL HAZARDS Product Name: TOYOTA GENUINE ATF WS Revision Date: 12 May 2016 Page 2 of 12 ______________________________________________________________________________________________________________________ No significant hazards. HEALTH HAZARDS High-pressure injection under skin may cause serious damage. Excessive exposure may result in eye, skin, or respiratory irritation. ENVIRONMENTAL HAZARDS No significant hazards. NFPA Hazard ID: HMIS Hazard ID: NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS This material is defined as a mixture. Hazardous Substance(s) or Complex Substance(s) required for disclosure Name CAS# Concentration* GHS Hazard Codes ALKYL METHACRYLATE COPOLYMER 63150-07-2 1 - < 5% H319(2A) ALKYL THIOPHOSPHITES Confidential 0.1 - < 1% H312, H314(1B), H400(M factor 10), H410(M factor 10) CATALYTIC DEWAXED LIGHT PARAFFINIC OIL (PETROLEUM) 64742-71-8 20 - < 30% H304 LUBRICATING OILS (PETROLEUM), HYDROTREATED NEUTRAL OIL-BASED 72623-86-0 30 - < 40% H304 SEVERELY HYDROTREATED HEAVY PARAFFINIC DISTILLATE 64742-54-7 20 - < 30% H304 * All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume. As per paragraph (i) of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity and exact percentage (concentration) of composition may have been withheld. Specific chemical identity and exact percentage composition will be provided to health professionals, employees, or designated representatives in accordance with applicable provisions of paragraph (i). SECTION 4 FIRST AID MEASURES INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek Product Name: TOYOTA GENUINE ATF WS Revision Date: 12 May 2016 Page 3 of 12 ______________________________________________________________________________________________________________________ immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight Streams of Water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Aldehydes, Incomplete combustion products, Oxides of carbon, Smoke, Fume, Sulfur oxides FLAMMABILITY PROPERTIES Flash Point [Method]: >175°C (347°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES Product Name: TOYOTA GENUINE ATF WS Revision Date: 12 May 2016 Page 4 of 12 ______________________________________________________________________________________________________________________ In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. US regulations require reporting releases of this material to the environment which exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National Response Center can be reached at (800)424-8802. PROTECTIVE MEASURES Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended. SPILL MANAGEMENT Land Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. SECTION 7 HANDLING AND STORAGE HANDLING Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present (e.g., during switch-loading operations). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Product Name: TOYOTA GENUINE ATF WS Revision Date: 12 May 2016 Page 5 of 12 ______________________________________________________________________________________________________________________ Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator. STORAGE The type of container used to store the material may affect static accumulation and dissipation. Do not store in open or unlabelled containers. Keep away from incompatible materials. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMIT VALUES Exposure limits/standards (Note: Exposure limits are not additive) Substance Name Form Limit / Standard NOTE Source CATALYTIC DEWAXED LIGHT PARAFFINIC OIL (PETROLEUM) Mist. TWA 5 mg/m3 N/A OSHA Z1 CATALYTIC DEWAXED LIGHT PARAFFINIC OIL (PETROLEUM) Inhalable fraction. TWA 5 mg/m3 N/A ACGIH CATALYTIC DEWAXED LIGHT PARAFFINIC OIL (PETROLEUM) Mist. TWA 5 mg/m3 N/A ACGIH LUBRICATING OILS (PETROLEUM), HYDROTREATED NEUTRAL OIL-BASED Inhalable fraction. TWA 5 mg/m3 N/A ACGIH SEVERELY HYDROTREATED HEAVY PARAFFINIC DISTILLATE Inhalable fraction. TWA 5 mg/m3 N/A ACGIH SEVERELY HYDROTREATED HEAVY PARAFFINIC DISTILLATE Mist. TWA 5 mg/m3 N/A ACGIH Exposure limits/standards for materials that can be formed when handling this product: When mists/aerosols can occur the following are recommended: 5 mg/m³ - ACGIH TLV (inhalable fraction), 5 mg/m³ - OSHA PEL. NOTE: Limits/standards shown for guidance only. Follow applicable regulations. No biological limits allocated. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Product Name: TOYOTA GENUINE ATF WS Revision Date: 12 May 2016 Page 6 of 12 ______________________________________________________________________________________________________________________ Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION Physical State: Liquid Product Name: TOYOTA GENUINE ATF WS Revision Date: 12 May 2016 Page 7 of 12 ______________________________________________________________________________________________________________________ Color: Red Odor: Characteristic Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 °C): 0.85 [ASTM D4052] Flammability (Solid, Gas): N/A Flash Point [Method]: >175°C (347°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316°C (600°F) Decomposition Temperature: N/D Vapor Density (Air = 1): > 2 at 101 kPa Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C Evaporation Rate (n-butyl acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 23 cSt (23 mm2/sec) at 40 °C | 5.45 cSt (5.45 mm2/sec) at 100°C [ASTM D 445] Oxidizing Properties: See Hazards Identification Section. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A DMSO Extract (mineral oil only), IP-346: < 3 %wt SECTION 10 STABILITY AND REACTIVITY REACTIVITY: See sub-sections below. STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS Product Name: TOYOTA GENUINE ATF WS Revision Date: 12 May 2016 Page 8 of 12 ______________________________________________________________________________________________________________________ Inhalation Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures. Ingestion Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Corrosion/Irritation: No end point data for material. Negligible irritation to skin at ambient temperatures. Based on assessment of the components. Eye Serious Eye Damage/Irritation: No end point data for material. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components. Sensitization Respiratory Sensitization: No end point data for material. Not expected to be a respiratory sensitizer. Skin Sensitization: No end point data for material. Not expected to be a skin sensitizer. Based on assessment of the components. Aspiration: Data available. Not expected to be an aspiration hazard. Based on physico-chemical properties of the material. Germ Cell Mutagenicity: No end point data for material. Not expected to be a germ cell mutagen. Based on assessment of the components. Carcinogenicity: No end point data for material. Not expected to cause cancer. Based on assessment of the components. Reproductive Toxicity: No end point data for material. Not expected to be a reproductive toxicant. Based on assessment of the components. Lactation: No end point data for material. Not expected to cause harm to breast-fed children. Specific Target Organ Toxicity (STOT) Single Exposure: No end point data for material. Not expected to cause organ damage from a single exposure. Repeated Exposure: No end point data for material. Not expected to cause organ damage from prolonged or repeated exposure. Based on assessment of the components. OTHER INFORMATION Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals. Product Name: TOYOTA GENUINE ATF WS Revision Date: 12 May 2016 Page 9 of 12 ______________________________________________________________________________________________________________________ The following ingredients are cited on the lists below: None. SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability. SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It Product Name: TOYOTA GENUINE ATF WS Revision Date: 12 May 2016 Page 10 of 12 ______________________________________________________________________________________________________________________ does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (DOT): Not Regulated for Land Transport LAND (TDG): Not Regulated for Land Transport SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code Marine Pollutant: No AIR (IATA): Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: This material is not considered hazardous in accordance with OSHA HazCom 2012, 29 CFR 1910.1200. Listed or exempt from listing/notification on the following chemical inventories: AICS, DSL, IECSC, KECI, PICCS, TSCA SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302 SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic Release Program. Product Name: TOYOTA GENUINE ATF WS Revision Date: 12 May 2016 Page 11 of 12 ______________________________________________________________________________________________________________________ The following ingredients are cited on the lists below: Chemical Name CAS Number List Citations Code key: CARC=Carcinogen; REPRO=Reproductive N/D = Not determined, N/A = Not applicable KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only): H304: May be fatal if swallowed and enters airways; Aspiration, Cat 1 H312: Harmful in contact with skin; Acute Tox Dermal, Cat 4 H314(1B): Causes severe skin burns and eye damage; Skin Corr/Irritation, Cat 1B H319(2A): Causes serious eye irritation; Serious Eye Damage/Irr, Cat 2A H400: Very toxic to aquatic life; Acute Env Tox, Cat 1 H410: Very toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 1 THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Composition: Component Table information was modified. Section 13: Disposal Considerations - Disposal Recommendations information was modified. Section 16: MSN, MAT ID information was modified. ----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is Product Name: TOYOTA GENUINE ATF WS Revision Date: 12 May 2016 Page 12 of 12 ______________________________________________________________________________________________________________________ included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------- DGN: 7010438XUS (1025004) ----------------------------------------------------------------------------------------------------------------------------------------------------- Copyright 2002 Exxon Mobil Corporation, All rights reserved SAFETY DATA SHEET 1. Identification LPS® 3 (Aerosol)Product identifier Other means of identification 00316Part Number A specialized soft-film spray coating designed to prevent rust and corrosion on steel, aluminumand other metals.Recommended use None known.Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Manufacturer Manufacturer Company name ITW Pro Brands Address 4647 Hugh Howell Rd. Tucker, GA 30084 Country (U.S.A.) Tel: +1 770-243-8800 In Case of Emergency 1-800-424-9300 (inside U.S.) +001 703-527-3887 (outside U.S.) Website www.lpslabs.com E-mail lpssds@itwprobrands.com 2. Hazard(s) identification Category 1Flammable aerosolsPhysical hazards Compressed gasGases under pressure Category 2Skin corrosion/irritationHealth hazards Category 2ASerious eye damage/eye irritation Category 3 narcotic effectsSpecific target organ toxicity, single exposure Not classified.Environmental hazards Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes skinirritation. Causes serious eye irritation. May cause drowsiness or dizziness. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an openflame or other ignition source. Do not pierce or burn, even after use. Avoid breathing gas. Useonly outdoors or in a well-ventilated area. Wash thoroughly after handling. Wear protective glovesand eye/face protection. Response If swallowed: Call a poison center/doctor if you feel unwell. Rinse mouth. If inhaled: Removeperson to fresh air and keep comfortable for breathing. Call a POISON CENTER ordoctor/physician if you feel unwell. If in eyes: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Getmedical advice/attention. If on skin: Wash with plenty of water. Take off contaminated clothingand wash it before reuse. If skin irritation occurs: Get medical advice/attention. Storage Keep container tightly closed. Store in a well-ventilated place. Store locked up. Protect fromsunlight. Do not expose to temperatures exceeding 50°C/122°F. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. 1 / 10 Material name: LPS® 3 (Aerosol) 00316 Version #: 04 Revision date: 07-11-2017 Issue date: 10-14-2015 SDS US Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None known. 3. Composition/information on ingredients Mixtures 64742-47-8Distillates Petroleum HydrotreatedLight 50 - 60 5131-66-81-butoxy-2-propanol 1 - 10 67-64-1Acetone 1 - 10 64742-54-7Distillates Petroleum HydrotreatedHeavy 1 - 10 124-38-9Carbon Dioxide 1 - 5 471-34-1Calcium Carbonate 0.1 - 1 64742-82-1Hydrodesulferized Heavy PetroleumNaptha 0.1 - 1 All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen orartificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance.Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or otherproper respiratory medical device. Call a POISON CENTER or doctor/physician if you feel unwell. Inhalation In case of contact, immediately flush skin with plenty of water for at least 15 minutes whileremoving contaminated clothing and shoes. Get medical attention if irritation develops andpersists. Skin contact Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses.Get medical attention if irritation develops and persists.Eye contact Call a physician or poison control center immediately. Only induce vomiting at the instruction ofmedical personnel. Never give anything by mouth to an unconscious person. If vomiting occurs,keep head low so that stomach content doesn't get into the lungs. Ingestion Irritant effects. Symptoms may include stinging, tearing, redness, swelling, and blurred vision.Defatting of the skin. Rash. Symptoms of overexposure can include shortness of breath,drowsiness, headaches, confusion, decreased coordination, visual disturbances and vomiting, andare reversible if exposure is stopped. Most important symptoms/effects, acute and delayed Provide general supportive measures and treat symptomatically. In case of shortness of breath,give oxygen. Keep victim under observation. Symptoms may be delayed.Indication of immediate medical attention and special treatment needed In the case of accident or if you feel unwell, seek medical advice immediately (show the label precautions to protect themselves. General information 5. Fire-fighting measures Powder. Alcohol resistant foam. Carbon dioxide (CO2).Suitable extinguishing media Do not use a solid water stream as it may scatter and spread fire.Unsuitable extinguishing media Contents under pressure. Pressurized container may explode when exposed to heat or flame.Specific hazards arising from the chemical Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA.Special protective equipment and precautions for firefighters Move containers from fire area if you can do so without risk. Containers should be cooled with holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Water runoff can causeenvironmental damage. Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials. Movecontainer from fire area if it can be done without risk. In the event of fire and/or explosion do notbreathe fumes. Specific methods Extremely flammable aerosol.General fire hazards 2 / 10 Material name: LPS® 3 (Aerosol) 00316 Version #: 04 Revision date: 07-11-2017 Issue date: 10-14-2015 SDS US 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out oflow areas. Wear appropriate personal protective equipment. Do not touch damaged containers orspilled material unless wearing appropriate protective clothing. Ventilate closed spaces beforeentering them. Local authorities should be advised if significant spillages cannot be contained. Usepersonal protection recommended in Section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (nosmoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.)away from spilled material. The product is immiscible with water and will spread on the watersurface. Stop leak if you can do so without risk. Isolate area until gas has dispersed. Collectspillage. Use water spray to reduce vapors or divert vapor cloud drift. Prevent entry into Methods and materials for containment and cleaning up Avoid release to the environment. Contact local authorities in case of spillage to drain/aquaticenvironment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoiddischarge into drains, water courses or onto the ground. Environmental precautions 7. Handling and storage Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missingor defective. Do not spray on a naked flame or any other incandescent material. Do not smoke expose containers to heat, flame, sparks, or other sources of ignition. All equipment used whenhandling the product must be grounded. Avoid breathing gas. Avoid contact with skin. Avoidcontact with eyes. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriatepersonal protective equipment. Observe good industrial hygiene practices. Wash hands thoroughlyafter handling. Avoid release to the environment. Precautions for safe handling Level 3 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame,heat or other sources of ignition. Store locked up. Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits ValueComponents FormType PEL 5 mg/m3 Oil mistDistillates PetroleumHydrotreated Light (CAS64742-47-8) US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponentsType PEL 2400 mg/m3Acetone (CAS 67-64-1) 1000 ppm PEL 9000 mg/m3Carbon Dioxide (CAS124-38-9)5000 ppm ACGIH ValueComponents FormType TWA 5 mg/m3 Oil mistDistillates PetroleumHydrotreated Light (CAS64742-47-8) US. ACGIH Threshold Limit Values ValueComponentsType STEL 500 ppmAcetone (CAS 67-64-1) TWA 250 ppm STEL 30000 ppmCarbon Dioxide (CAS124-38-9) TWA 5000 ppm US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents FormType TWA 590 mg/m3Acetone (CAS 67-64-1) 3 / 10 Material name: LPS® 3 (Aerosol) 00316 Version #: 04 Revision date: 07-11-2017 Issue date: 10-14-2015 SDS US US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents FormType 250 ppm TWA 5 mg/m3 Respirable.Calcium Carbonate (CAS471-34-1)10 mg/m3 Total STEL 54000 mg/m3Carbon Dioxide (CAS124-38-9)30000 ppm TWA 9000 mg/m3 5000 ppm Biological limit values ValueComponents Determinant Specimen Sampling Time 25 mg/l Acetone Urine *Acetone (CAS 67-64-1) * - For sampling details, please see the source document. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation ratesshould be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,or other engineering controls to maintain airborne levels below recommended exposure limits. Ifexposure limits have not been established, maintain airborne levels to an acceptable level. Appropriate engineering controls Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles). Eye wash fountain is recommended.Eye/face protection Skin protection Chemical resistant gloves are recommended.Hand protection Avoid contact with clothing. Wear suitable protective clothing. Chemical resistant gloves.Other No personal respiratory protective equipment normally required. Use a positive-pressureair-supplied respirator if there is any potential for an uncontrolled release, exposure levels are notknown, or any other circumstances where air-purifying respirators may not provide adequateprotection. Respiratory protection Not applicable.Thermal hazards When using, do not eat, drink or smoke. Always observe good personal hygiene measures, suchas washing after handling the material and before eating, drinking, and/or smoking. RoutinelyGeneral hygiene considerations 9. Physical and chemical properties Cloudy. Liquid.Appearance Gas.Physical state Aerosol.Form Brown.Color Mild. Cherry.Odor Odor threshold Not available. pH Not applicable Melting point/freezing point Not available. Initial boiling point and boiling range Not available. Flash point 64.4 °F (18.0 °C) Tag Closed Cup Evaporation rate 151 (Ethyl Ether) Flammable gas.Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) 0.6 % Flammability limit - upper (%) 6 % Explosive limit - lower (%)Not available. Explosive limit - upper (%)Not available. 4 / 10 Material name: LPS® 3 (Aerosol) 00316 Version #: 04 Revision date: 07-11-2017 Issue date: 10-14-2015 SDS US Vapor pressure Not available. Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water)Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 446 °F (230 °C) Decomposition temperature Not available. Viscosity Not available. Other information Density 7.28 lb/gal Percent volatile 63 - 82 % Specific gravity 0.87 VOC 62.8 % per U.S. State and Federal Consumer Product Regulations 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity Material is stable under normal conditions.Chemical stability Hazardous polymerization does not occur.Possibility of hazardous reactions Avoid temperatures exceeding the flash point.Conditions to avoid Strong oxidizing agents.Incompatible materials Upon decomposition this product emits acrid dense smoke with carbon dioxide, carbon monoxide,Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure May cause drowsiness and dizziness. Skin contact Causes skin irritation. Eye contact Causes serious eye irritation. Ingestion May cause discomfort if swallowed. However, ingestion is not likely to be a primary route ofoccupational exposure. Symptoms related to the physical, chemical and toxicological characteristics Irritating to eyes, respiratory system and skin. Symptoms may include stinging, tearing, redness,swelling, and blurred vision. Information on toxicological effects Test ResultsComponentsSpecies 1-butoxy-2-propanol (CAS 5131-66-8) Dermal Acute LD50 Rabbit 1400 mg/kg, 24 Hours Oral LD50 Rat > 2000 mg/kg Calcium Carbonate (CAS 471-34-1) Dermal Acute LD50 Rat > 2000 mg/kg, 24 Hours Oral LD50 Rat > 2000 mg/kg 5 / 10 Material name: LPS® 3 (Aerosol) 00316 Version #: 04 Revision date: 07-11-2017 Issue date: 10-14-2015 SDS US Test ResultsComponentsSpecies Distillates Petroleum Hydrotreated Heavy (CAS 64742-54-7) Dermal Acute LD50 Rabbit > 2000 mg/kg Inhalation LC50 Rat > 3.9 mg/l, 4 Hours Oral LD50 Rat > 2000 mg/kg Distillates Petroleum Hydrotreated Light (CAS 64742-47-8) Dermal Acute LD50 Rabbit > 2000 mg/kg Inhalation LC50 Rat > 4.5 mg/l, 4 Hours Vapor Hydrodesulferized Heavy Petroleum Naptha (CAS 64742-82-1) Dermal Acute LD50 Rabbit > 1900 mg/kg, 24 Hours Oral LD50 Rat 4820 mg/kg Causes skin irritation.Skin corrosion/irritation Causes serious eye irritation.Serious eye damage/eye irritation Respiratory or skin sensitization Not a respiratory sensitizer. This product is not expected to cause skin sensitization.Skin sensitization No data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.Germ cell mutagenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. ACGIH Carcinogens Acetone (CAS 67-64-1)A4 Not classifiable as a human carcinogen. IARC Monographs. Overall Evaluation of Carcinogenicity Not listed. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. US. National Toxicology Program (NTP) Report on Carcinogens Not listed. This product is not expected to cause reproductive or developmental effects.Reproductive toxicity Specific target organ toxicity - single exposure Narcotic effects. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not likely, due to the form of the product. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Not expected to be harmful to aquatic organisms.Ecotoxicity 6 / 10 Material name: LPS® 3 (Aerosol) 00316 Version #: 04 Revision date: 07-11-2017 Issue date: 10-14-2015 SDS US Components Test ResultsSpecies Acetone (CAS 67-64-1) Aquatic EC50Crustacea 10294 - 17704 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish 4740 - 6330 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss) Calcium Carbonate (CAS 471-34-1) Aquatic LC50Fish > 56000 mg/l, 96 hoursWestern mosquitofish (Gambusia affinis) Distillates Petroleum Hydrotreated Light (CAS 64742-47-8) Aquatic LC50Fish 2.9 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss) Not inherently biodegradable.Persistence and degradability No data available for this product.Bioaccumulative potential Acetone -0.24 Not available.Mobility in soil None known. 13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contentsunder pressure. Do not puncture, incinerate or crush. This material and its container must bedisposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Donot contaminate ponds, waterways or ditches with chemical or used container. Dispose ofcontents/container in accordance with local/regional/national/international regulations. Disposal instructions D001: Waste Flammable material with a flash point <140 FD003: Waste Reactive materialHazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain someproduct residues. This material and its container must be disposed of in a safe manner (see:Disposal instructions). Waste from residues / unused products Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied. Do not re-use empty containers. Contaminated packaging 14. Transport information DOT UN1950UN number Aerosols, flammableUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk 2.1Label(s) Not available.Packing group NoMarine pollutant Environmental hazards Not available.Special precautions for user N82Special provisions 306Packaging exceptions NonePackaging non bulk NonePackaging bulk IATA UN1950UN number Aerosols, flammableUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk 2.1Label(s) 7 / 10 Material name: LPS® 3 (Aerosol) 00316 Version #: 04 Revision date: 07-11-2017 Issue date: 10-14-2015 SDS US Not available.Packing group No.Environmental hazards Not available.Special precautions for user Allowed with restrictions.Passenger and cargo aircraft Other information Allowed with restrictions.Cargo aircraft only IMDG UN1950UN number Aerosols, flammableUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk 2.1Label(s) Not available.Packing group NoMarine pollutant Environmental hazards Not available.EmS Not available.Special precautions for user Not available.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code DOT IATA; IMDG 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Acetone (CAS 67-64-1)Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. 8 / 10 Material name: LPS® 3 (Aerosol) 00316 Version #: 04 Revision date: 07-11-2017 Issue date: 10-14-2015 SDS US Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - YesDelayed Hazard - NoFire Hazard - YesPressure Hazard - YesReactivity Hazard - No Hazard categories SARA 302 Extremely hazardous substance Not listed. YesSARA 311/312 Hazardous chemical SARA 313 (TRI reporting)Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated.Safe Drinking Water Act (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Acetone (CAS 67-64-1)6532 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1)35 %WV DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1)6532 FEMA Priority Substances Respiratory Health and Safety in the Flavor Manufacturing Workplace Acetone (CAS 67-64-1)Low priority US state regulations US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) Acetone (CAS 67-64-1)Distillates Petroleum Hydrotreated Heavy (CAS 64742-54-7)Hydrodesulferized Heavy Petroleum Naptha (CAS 64742-82-1) International Inventories Country(s) or region Inventory name On inventory (yes/no)* NoAustraliaAustralian Inventory of Chemical Substances (AICS) YesCanadaDomestic Substances List (DSL) NoCanadaNon-Domestic Substances List (NDSL) NoChinaInventory of Existing Chemical Substances in China (IECSC) NoEuropeEuropean Inventory of Existing Commercial ChemicalSubstances (EINECS) NoEuropeEuropean List of Notified Chemical Substances (ELINCS) NoJapanInventory of Existing and New Chemical Substances (ENCS) NoKoreaExisting Chemicals List (ECL) NoNew Zealand New Zealand Inventory NoPhilippinesPhilippine Inventory of Chemicals and Chemical Substances(PICCS) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) country(s). 16. Other information, including date of preparation or last revision 10-14-2015Issue date 07-11-2017Revision date 9 / 10 Material name: LPS® 3 (Aerosol) 00316 Version #: 04 Revision date: 07-11-2017 Issue date: 10-14-2015 SDS US Version #04 The information provided in this Safety Data Sheet is correct to the best of our knowledge,information and belief at the date of its publication. The information given is designed only as aguidance for safe handling, use, processing, storage, transportation, disposal and release and isnot to be considered a warranty or quality specification. The information relates only to the specificmaterial designated and may not be valid for such material used in combination with any othermaterials or in any process, unless specified in the text. Disclaimer Hazard(s) identification: Hazard statementHazard(s) identification: PreventionHazard(s) identification: ResponseHazard(s) identification: StorageComposition / Information on Ingredients: Disclosure OverridesRegulatory Information: Risk Phrases - LabelingGHS: Classification Revision information 10 / 10 Material name: LPS® 3 (Aerosol) 00316 Version #: 04 Revision date: 07-11-2017 Issue date: 10-14-2015 SDS US MATERIAL SAFETY DATA SHEET SLICK 50® ENGINE TREATMENT FOR HIGH MILEAGE VEHICLES 1. PRODUCT AND COMPANY IDENTIFICATION MSDS Number: 24400 Version Date: 05/29/01 Product Name: SLICK 50® ENGINE TREATMENT FOR HIGH MILEAGE VEHICLES Product Use: Engine treatment Synonyms: 50101015, 50106015 Company Information SOPUS Products P.O. Box 4427 Houston, TX 77210-4427 USA Phone Numbers Medical Emergency: 1-800-546-6040 Transportation Emergency (USA): 1-800-424-9300 Transportation Emergency (International): 1-703-527-3887(Call Collect) MSDS Assistance: 1-800-546-6227 Fax On Demand: 1-800-546-6227 Technical Assistance: 1-800-458-4998 Customer Service: 1-800-468-8397 Fax Number: 713-217-3181 Internet Address: www.MSDS.PZLQS.com ______________________________________________________________________________________ 2. COMPONENT INFORMATION Component CAS No. Weight Percent Range Hazardous in Blend SOLVENT-DEWAXED HEAVY PARAFFINIC DISTILLATE 64742-65-0 > 80 No ANTIWEAR RUST & OXIDATION MIXTURE MIXTURE < 10 No PROPRIETARY MIXTURE TRADESECRET < 10 No Under normal conditions of use or in a foreseeable emergency, this product does not meet the definition of a hazardous chemical when evaluated according to the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Other: No information available ___________________________________________________________________________________ 3. HAZARDS IDENTIFICATION Emergency and Hazards Overview CAUTION: Contains Petroleum Lubricant. Repeated skin contact can cause skin disorders. ATTENTION: Used motor oil is a possible skin cancer hazard based on animal data. Repeated exposure to oil mist in excess of the OSHA limit (5mg/m3) can result in accumulation of oil droplets in pulmonary tissue. NFPA Ratings: Health 1 Flammability 1 Reactivity 0 Primary Route of Exposure: Skin X Inhalation -- Eye -- Health Effect Information Eye Contact: This product is practically non-irritating to the eyes upon direct contact. Based on testing of similar products and/or components. Skin Contact: Avoid skin contact. This product is minimally irritating to the skin upon direct contact. Based on testing of similar products and/or components. Prolonged or repeated contact may result in contact dermatitis which is characterized by dryness, chapping, and reddening. Prolonged or repeated contact may result in oil acne which is characterized by blackheads with possible secondary infection. Avoid prolonged and repeated skin contact with used motor oils. See Section 11 - Toxicological Information. MATERIAL SAFETY DATA SHEET MSDS Number: 24400 SLICK 50® ENGINE TREATMENT FOR HIGH MILEAGE VEHICLES Page 2 of 7 Inhalation: This product has a low vapor pressure and is not expected to present an inhalation hazard at ambient conditions. Caution should be taken to prevent aerosolization or misting of this product. On rare occasions, prolonged and repeated exposure to oil mist poses a ris k of pulmonary disease such as chronic lung inflammation. Signs of respiratory effects vary with concentration and length of exposure and include nasal discharge, sore throat, coughing, bronchitis, pulmonary edema and difficulty breathing. Shortness of breath and cough are the most common symptoms. Ingestion: Do not ingest. This product is relatively non-toxic by ingestion. This product has laxative properties and may result in abdominal cramps and diarrhea. Exposure to a large single dose, or repeated smaller doses, may lead to lung aspiration, which can lead to lipid pneumonia or chronic lung inflammation. These are low-grade, chronic localized tissue reactions. Medical Conditions Aggravated by Exposure: Drying and chapping may make the skin more susceptible to other irritants, sensitizers and disease. Other: No information available ___________________________________________________________________________________ 4. FIRST AID INFORMATION Eye Contact: Immediately flush eyes with large amounts of water and continue flushing until irritation subsides. If irritation persists, seek medical attention. Skin Contact: No treatment is necessary under ordinary circumstances. Remove contaminated clothing. Wash contaminated area thoroughly with soap and water. If material is hot, submerge injured area in cold water. If victim is severely burned, remove to a hospital immediately. Inhalation: This material does not present any known inhalation hazard. No treatment is necessary under ordinary circumstances. Ingestion: No treatment is necessary under ordinary circumstances. Do not induce vomiting. If victim exhibits signs of lung aspiration such as coughing or choking, seek immediate medical assistance. Notes to Physician: No information available Other: No information available ______________________________________________________________________________________ 5. FIRE AND EXPLOSION INFORMATION Flammable Properties Flash Point: >375 F, >190.6 C Test Method: ASTM D-92 (C.O.C.) Flammable Limits in Air Upper Percent: No data available Lower Percent: No data available Autoignition Temperature: No data available Test Method: No information available NFPA Classification: Class III-B combustible liquid Extinguishing Media: Use dry chemical, foam, or carbon dioxide. Fire Fighting Measures Special Fire Fighting Procedures and Equipment: No special fire fighting procedures are required. Unusual Fire and Explosion Conditions: Dense smoke may be generated while burning. Carbon monoxide, carbon dioxide, and other oxides may be generated as products of combustion. MATERIAL SAFETY DATA SHEET MSDS Number: 24400 SLICK 50® ENGINE TREATMENT FOR HIGH MILEAGE VEHICLES Page 3 of 7 Hazardous Combustion By-Products: None Other: No information available ______________________________________________________________________________________ 6. ACCIDENTAL RELEASE MEASURES Personnel Safeguards: Consult Health Effect Information in Section 3, Personal Protection Information in Section 8, Fire and Explosion Information in Section 5, and Stability and Reactivity Information in Section 10. Regulatory Notifications: No notification required Containment and Clean up: No special cleanup procedures are necessary. Do not allow spill to enter sewers or watercourses. Small spills may be picked up with absorbent material. Other: No information available ______________________________________________________________________________________ 7. HANDLING AND STORAGE INFORMATION Handling: No special handling procedures are necessary. Storage: Do not transfer to unmarked containers. Store in closed containers away from heat, sparks, open flame, or oxidizing materials. Empty Container Warnings Drums: Not applicable Plastic: Do not reuse this container. Empty container may retain product residues. Other: No information available ______________________________________________________________________________________ 8. EXPOSURE CONTROLS / PERSONAL PROTECTION INFORMATION Exposure Limits and Guidelines This product does not contain any components with OSHA or ACGIH exposure limits. Personal Protective Equipment Eye/Face Protection: Eye protection is not required under conditions of normal use. If material is handled such that it could be sprayed into eyes, wear plastic face shield or splash-proof safety goggles. Skin Protection: Skin protection is not required under conditions of normal use. Launder soiled clothes. Respiratory Protection: Respiratory protection is not required under conditions of normal use. Personal Hygiene: Consumption of food and beverage should be avoided in work areas where this product is present. Always wash hands and face with soap and water before eating, drinking, or smoking. Engineering Controls / Work Practices Ventilation: General room ventilation is normally sufficient. Other: No information available MATERIAL SAFETY DATA SHEET MSDS Number: 24400 SLICK 50® ENGINE TREATMENT FOR HIGH MILEAGE VEHICLES Page 4 of 7 ______________________________________________________________________________________ 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Amber oil Odor: No information available Vapor Pressure: No data available Physical state: Liquid Vapor Density (air=1): > 1 pH: No data available Percent Volatile by Volume: No data available Boiling Point: No data available Volatile Organic Content: No data available Melting Point: No data available Molecular Weight: No data available Specific Gravity: 0.87 Average Carbon Number: No data available Pour Point: No data available Viscosity @ 100 F: > 4300 SUS Viscosity @ 40 C: No data available Solubility in Water: Negligible in water Octanol / Water Coefficient: Log Kow = No data available ______________________________________________________________________________________ 10. STABILITY AND REACTIVITY INFORMATION Chemical Stability: Stable Conditions to Avoid: High heat and open flames. Incompatible Materials to Avoid: May react with strong oxidizing agents. Other: No information available ______________________________________________________________________________________ 11. TOXICOLOGICAL INFORMATION Primary Eye Irritation: No information available Primary Skin Irritation: No information available Acute Dermal Toxicity: No information available Subacute Dermal Toxicity: No information available Dermal Sensitization: No information available Inhalation Toxicity: No information available Inhalation Sensitization: No information available Oral Toxicity: No information available Mutagenicity: No information available Carcinogenicity: The International Agency for Research on Cancer (IARC) has concluded that there is inadequate data to evaluate the carcinogenicity to experimental animals of this class of product. IARC has concluded there is sufficient evidence that used gasoline-engine motor oils produce skin tumors in experimental animals. Also, IARC has determined this class of products belongs to Group 3-"not classifiable as to its carcinogenicity to humans". MATERIAL SAFETY DATA SHEET MSDS Number: 24400 SLICK 50® ENGINE TREATMENT FOR HIGH MILEAGE VEHICLES Page 5 of 7 Reproductive and Developmental Toxicity: No information available Teratogenicity: No information available Immunotoxicity: No information available Neurotoxicity: No information available Other: No information available ______________________________________________________________________________________ 12. ECOLOGICAL INFORMATION Aquatic Toxicity: No information available Terrestrial Toxicity: No information available Chemical Fate and Transport: No information available Other: No information available ______________________________________________________________________________________ 13. DISPOSAL INFORMATION Regulatory Information: Dispose of residual products and empty containers responsibly. Waste Disposal Methods: Waste material may be landfilled or incinerated at an approved facility. Other: No information available ______________________________________________________________________________________ 14. TRANSPORTATION INFORMATION U.S. Department of Transportation (DOT) Highway / Rail (Bulk): Not Regulated Highway / Rail (Non-Bulk): Not Regulated For US shipments, US DOT law requires the shipper to determine the proper shipping description of the material that is being shipped. The shipping information and description contained in this section may not be suitable for all shipments of this material, but may help the shipper determine the proper shipping description for a particular shipment. International Information Vessel: IMDG Regulated: -- IMDG Not Regulated: X Air: ICAO Regulated: -- ICAO Not Regulated: X Other: No information available ______________________________________________________________________________________ 15. Regulatory Information Regulatory Lists Searched: The components listed in Section 2 of this MSDS were compared to substances that appear on the following regulatory lists. Each list is numerically identified. See Regulatory Search Results below. Health & Safety: 10 - IARC carcinogen, 11 - NTP carcinogen, 12 - OSHA carcinogen, 15 - ACGIH TLV, 16 - OSHA PEL, 17 - NIOSH exposure limit, 20 - US DOT Appendix A, Hazardous substances, 22 - FDA 21 CFR Total food additives, 23 - NFPA 49 or 325 MATERIAL SAFETY DATA SHEET MSDS Number: 24400 SLICK 50® ENGINE TREATMENT FOR HIGH MILEAGE VEHICLES Page 6 of 7 Environmental: 30 - CAA 1990 Hazardous air pollutants, 31 - CAA Ozone depletors, 33 - CAA HON rule, 34 - CAA Toxic substance for accidental release prevention, 35 - CAA Volatile organic compounds (VOC's) in SOCMI, 41 - CERCLA / SARA Section 302 extremely hazardous substances, 42 - CERCLA / SARA Section 313 emissions reporting, 43 - CWA Hazardous substances, 44 - CWA Priority pollutants, 45 - CWA Toxic pollutants, 46 - EPA Proposed test rule for hazardous air pollutants, 47 - RCRA Basis for listing - Appendix VII, 48 - RCRA waste, 49 - SDWA - (S)MCLs International: 50 - Canada - WHMIS Classification of substance, 54 - Mexico - Drinking water - ecological criteria, 55 - Mexico - Wastewater discharges, 56 - US -TSCA Section (12)(b) - export notification State Lists: 60 - CA - Proposition 65, 61 - FL - Substances, 62 - MI - Critical materials, 63 - MA - RTK, 64 - MA - Extraordinarily hazardous substances, 65 - MN - Hazardous substances, 66 - PA - RTK, 67 - NJ - RTK, 68 - NJ - Environmental hazardous substances, 69 - NJ - Special hazardous substances Inventories: 80 - Canada - Domestic substances , 81 - European - EINECS, 82 - Japan - ENCS, 83 - Korea - Existing and evaluated chemical substances, 84 - US - TSCA , 85 - China Inventory Regulatory Search Results: SOLVENT-DEWAXED HEAVY PARAFFINIC DISTILLATE: 80, 81, 83, 84, 85 U.S. TSCA Inventory: All components of this material are on the US TSCA Inventory. SARA Section 313: This product is not known to contain any SARA, Title III, Section 313 Reportable Chemicals at or greater than 1.0% (0.1% for carcinogens). IARC: No information available SARA 311 / 312 Categories Acute: --Chronic: --Fire: --Pressure: --Reactive: -- Not Regulated: X Canadian WHMIS Classification Not a controlled substance under WHMIS European Union Classification Hazard Symbols: No classification recommended Risk Phrases: No classification recommended Safety Phrases: No classification recommended Other: No information available ______________________________________________________________________________________ 16. OTHER INFORMATION Health and Environmental Label Language WARNING: Continuous contact with used gasoline engine oils has caused skin cancer in animal tests. ATTENTION: Prolonged or repeated skin contact may cause oil acne or dermatitis. Repeated exposure to oil mist in excess of the OSHA limit (5mg/m3 can result in accumulation of oil droplets in pulmonary tissue. Precautionary Measures: Avoid prolonged or repeated contact with eyes, skin and clothing. Avoid generation and inhalation of oil mists. MATERIAL SAFETY DATA SHEET MSDS Number: 24400 SLICK 50® ENGINE TREATMENT FOR HIGH MILEAGE VEHICLES Page 7 of 7 First Aid: Skin Contact: Wash skin with soap and water. Launder soiled clothes and discard oil- soaked shoes. If irritation persists seek medical attention. Eye Contact: Flush with water. If irritation persists seek medical attention. Ingestion: Do not induce vomiting. In general, no treatment is necessary unless large quantities of product are ingested. If discomfort persists seek medical assistance. Instructions in Case of Fire or Spill: In case of fire, use water fog, foam, dry chemical or carbon dioxide. Water spray may be ineffective, but can be used to cool containers. Do not use a direct stream of water. Material will float and can be reignited on surface of water. Spill or Leak: Dike and contain spill. Do not use water; soak up with absorbent material such as clay, sand or other suitable material. Place in non-leaking container and seal tightly for proper disposal. Contains: highly refined petroleum distillate, mixture; zinc compounds, mixture; polymer additives, mixture. KEEP OUT OF REACH OF CHILDREN. (If intended for retail also) MSDS Revisions Previous Version Date: 03/12/01 Previous Version Information Revised all sections, new 16 section MSDS format. Other No information available Prepared By: SOPUS Products P.O. Box 4427 Houston, TX 77210-4453 USA Disclaimer of Warranty: The information contained herein is based upon data and information available to us, and reflects our best professional judgment. This product may be formulated in part with components purchased from other companies. In many instances, especially when proprietary or trade secret materials are used, SOPUS Products must rely upon the hazard evaluation of such components submitted by that product’s manufacturer or importer. No warranty of merchantability, fitness for any use, or any other warranty is expressed or implied regarding the accuracy of such data or information, the results to be obtained from the use thereof, or that any such use do not infringe any patent. Since the information contained herein may be applied under conditions of use beyond our control and with which we may be unfamiliar, we do not assume responsibility for the results of such application. This information is furnished upon the condition that the person receiving it shall make his own determination of the suitability of the material for his particular use. SAFETY DATA SHEET 1. Identification Throttle Body & Air-Intake CleanerProduct identifier Other means of identification No. 05078 (Item# 1003688)Product code Fuel-Injection air intake cleanerRecommended use None known.Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Manufactured or sold by: CRC Industries, Inc.Company name 885 Louis Dr.Address Warminster, PA 18974 US Telephone 215-674-4300General Information 800-521-3168Technical Assistance 800-272-4620Customer Service 800-424-9300 (US)24-Hour Emergency 703-527-3887 (International)(CHEMTREC) www.crcindustries.comWebsite 2. Hazard(s) identification Category 1Flammable aerosolsPhysical hazards Compressed gasGases under pressure Category 2ASerious eye damage/eye irritationHealth hazards Category 2Reproductive toxicity (the unborn child) Category 3 narcotic effectsSpecific target organ toxicity, single exposure Category 2 (central nervous system, kidney,peripheral nervous system)Specific target organ toxicity, repeatedexposure Category 2Hazardous to the aquatic environment, acutehazardEnvironmental hazards Category 2Hazardous to the aquatic environment,long-term hazard Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causesserious eye irritation. May cause drowsiness or dizziness. Suspected of damaging the unbornchild. May cause damage to organs (central nervous system, kidney, peripheral nervous system)through prolonged or repeated exposure. Toxic to aquatic life with long lasting effects. 1 / 11 Material name: Throttle Body & Air-Intake Cleaner No. 05078 (Item# 1003688) Version #: 03 Revision date: 08-22-2017 Issue date: 05-07-2015 SDS US Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do notspray on an open flame or other ignition source. Pressurized container: Do not pierce or burn,even after use. Do not apply while equipment is energized. Extinguish all flames, pilot lights andheaters. Vapors will accumulate readily and may ignite. Do not breathe mist or vapor. Use only doors and windows or use other means to ensure a fresh air supply during use and while productis drying. If you experience any symptoms listed on this label, increase ventilation or leave thearea. Wash thoroughly after handling. Wear protective gloves/protective clothing/eyeprotection/face protection. Avoid release to the environment. Response If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poisoncenter/doctor if you feel unwell. If in eyes: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Getmedical advice/attention. If exposed or concerned: Get medical advice/attention. Collect spillage. Storage Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose totemperatures exceeding 50°C/122°F. Exposure to high temperature may cause can to burst. Disposal Dispose of contents/container in accordance with local/regional/national regulations. Hazard(s) not otherwise classified (HNOC) Static accumulating flammable liquid can become electrostatically charged even in bonded andgrounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion. 3. Composition/information on ingredients Mixtures 67-64-1acetone 80 - 90 124-38-9carbon dioxide 5 - 10 142-82-5n-heptane 1 - 3 108-88-3toluene 1 - 3 591-76-42-methylhexane < 1 589-34-43-methylhexane < 1 562-49-23,3-dimethylpentane < 0.2 617-78-73-ethylpentane < 0.2 Specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISONCENTER or doctor/physician if you feel unwell.Inhalation Rinse skin with water/shower. Get medical attention if irritation develops and persists.Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.Eye contact In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth.Ingestion May cause drowsiness and dizziness. Narcosis. Headache. Nausea, vomiting. Behavioralchanges. Decrease in motor functions. Severe eye irritation. Symptoms may include stinging,tearing, redness, swelling, and blurred vision. Edema. Prolonged exposure may cause chroniceffects. Most important symptoms/effects, acute and delayed Provide general supportive measures and treat symptomatically. Keep victim under observation.Symptoms may be delayed.Indication of immediate medical attention and special treatment needed IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are awareof the material(s) involved, and take precautions to protect themselves. Show this safety datasheet to the doctor in attendance. General information 5. Fire-fighting measures Water fog. Alcohol resistant foam. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide,sand or earth may be used for small fires only.Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing media 2 / 11 Material name: Throttle Body & Air-Intake Cleaner No. 05078 (Item# 1003688) Version #: 03 Revision date: 08-22-2017 Issue date: 05-07-2015 SDS US Contents under pressure. Pressurized container may rupture when exposed to heat or flame. Thisproduct is a poor conductor of electricity and can become electrostatically charged. If sufficientcharge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulationmay be significantly increased by the presence of small quantities of water or other contaminants.Material will float and may ignite on surface of water. During fire, gases hazardous to health maybe formed. Specific hazards arising from the chemical Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA.Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so withoutrisk. Containers should be cooled with water to prevent vapor pressure build up. Extremely flammable aerosol. Contents under pressure. Pressurized container may rupture whenexposed to heat or flame.General fire hazards 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Remove allpossible sources of ignition in the surrounding area. Keep out of low areas. Many gases areheavier than air and will spread along ground and collect in low or confined areas (sewers,basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Do notbreathe mist or vapor. Emergency personnel need self-contained breathing equipment. Do nottouch damaged containers or spilled material unless wearing appropriate protective clothing.Ventilate closed spaces before entering them. Use appropriate containment to avoidenvironmental contamination. Local authorities should be advised if significant spillages cannot becontained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keepcombustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water.This material is classified as a water pollutant under the Clean Water Act and should be preventedfrom contaminating soil or from entering sewage and drainage systems which lead to waterways.Stop the flow of material, if this is without risk. Wipe up with absorbent material (e.g. cloth, fleece).Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 ofthe SDS. Methods and materials for containment and cleaning up Avoid release to the environment. Inform appropriate managerial or supervisory personnel of allenvironmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge intodrains, water courses or onto the ground. Use appropriate containment to avoid environmentalcontamination. Environmental precautions 7. Handling and storage Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Minimize fire risks from flammable and combustible materials (includingcombustible dust and static accumulating liquids) or dangerous reactions with incompatiblematerials. Pressurized container: Do not pierce or burn, even after use. Do not use if spray buttonis missing or defective. Do not spray on a naked flame or any other incandescent material. Do notsmoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind,or expose containers to heat, flame, sparks, or other sources of ignition. Use caution aroundenergized equipment. The metal container will conduct electricity if it contacts a live source. Thismay result in injury to the user from electrical shock and/or flash fire. Do not breathe mist or vapor.Avoid contact with eyes. Avoid prolonged exposure. Pregnant or breastfeeding women must nothandle this product. Should be handled in closed systems, if possible. Use only in well-ventilatedareas. Wear appropriate personal protective equipment. Observe good industrial hygienepractices. Avoid release to the environment. For product usage instructions, see the product label. Precautions for safe handling Level 3 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame,heat or other sources of ignition. This material can accumulate static charge which may causespark and become an ignition source. Avoid spark promoters. These alone may be insufficient toremove static electricity. Store in a well-ventilated place. Store away from incompatible materials(see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits ValueComponentsType PEL 2400 mg/m3acetone (CAS 67-64-1) 1000 ppm 3 / 11 Material name: Throttle Body & Air-Intake Cleaner No. 05078 (Item# 1003688) Version #: 03 Revision date: 08-22-2017 Issue date: 05-07-2015 SDS US US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponentsType PEL 9000 mg/m3carbon dioxide (CAS124-38-9) 5000 ppm PEL 2000 mg/m3n-heptane (CAS 142-82-5) 500 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) ValueComponentsType Ceiling 300 ppmtoluene (CAS 108-88-3) TWA 200 ppm US. ACGIH Threshold Limit Values ValueComponentsType STEL 500 ppm2-methylhexane (CAS591-76-4) TWA 400 ppm STEL 500 ppm3,3-dimethylpentane (CAS562-49-2) TWA 400 ppm STEL 500 ppm3-ethylpentane (CAS617-78-7) TWA 400 ppm STEL 500 ppm3-methylhexane (CAS589-34-4) TWA 400 ppm STEL 500 ppmacetone (CAS 67-64-1) TWA 250 ppm STEL 30000 ppmcarbon dioxide (CAS124-38-9) TWA 5000 ppm STEL 500 ppmn-heptane (CAS 142-82-5) TWA 400 ppm TWA 20 ppmtoluene (CAS 108-88-3) US. NIOSH: Pocket Guide to Chemical Hazards ValueComponentsType TWA 590 mg/m3acetone (CAS 67-64-1) 250 ppm STEL 54000 mg/m3carbon dioxide (CAS124-38-9)30000 ppm TWA 9000 mg/m3 5000 ppm Ceiling 1800 mg/m3n-heptane (CAS 142-82-5) 440 ppm TWA 350 mg/m3 85 ppm STEL 560 mg/m3toluene (CAS 108-88-3) 150 ppm TWA 375 mg/m3 100 ppm Biological limit values ValueComponents Determinant Specimen Sampling Time 25 mg/l Acetone Urine *acetone (CAS 67-64-1) 0.3 mg/g o-Cresol, withhydrolysis Creatinine inurine *toluene (CAS 108-88-3) 4 / 11 Material name: Throttle Body & Air-Intake Cleaner No. 05078 (Item# 1003688) Version #: 03 Revision date: 08-22-2017 Issue date: 05-07-2015 SDS US ACGIH Biological Exposure Indices ValueComponents Determinant Specimen Sampling Time 0.03 mg/l Toluene Urine * 0.02 mg/l Toluene Blood * * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation toluene (CAS 108-88-3)Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies toluene (CAS 108-88-3)Skin designation applies. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation ratesshould be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,or other engineering controls to maintain airborne levels below recommended exposure limits. Ifexposure limits have not been established, maintain airborne levels to an acceptable level. Provideeyewash station. Appropriate engineering controls Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles).Eye/face protection Skin protection Wear protective gloves such as: Nitrile. Neoprene. Polyvinyl alcohol (PVA).Hand protection Wear suitable protective clothing.Other If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use aNIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-containedbreathing apparatus in confined spaces and for emergencies. Air monitoring is needed todetermine actual employee exposure levels. Respiratory protection Wear appropriate thermal protective clothing, when necessary.Thermal hazards When using do not smoke. Always observe good personal hygiene measures, such as washingafter handling the material and before eating, drinking, and/or smoking. Routinely wash workclothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Appearance Liquid.Physical state Aerosol.Form Clear. Colorless.Color Ketone.Odor Odor threshold Not available. pH Not available. Melting point/freezing point -138.8 °F (-94.9 °C) estimated Initial boiling point and boiling range 132.9 °F (56.1 °C) estimated Flash point < 0 °F (< -17.8 °C) Tag Closed Cup Evaporation rate Fast. Not available.Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) 1.1 % estimated Flammability limit - upper (%) 12.8 % estimated Vapor pressure 5856.8 hPa estimated Vapor density 2 (air = 1) Relative density 0.86 estimated Solubility (water)Slightly soluble. 5 / 11 Material name: Throttle Body & Air-Intake Cleaner No. 05078 (Item# 1003688) Version #: 03 Revision date: 08-22-2017 Issue date: 05-07-2015 SDS US Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 539.6 °F (282 °C) estimated Decomposition temperature Not available. Viscosity (kinematic)Not available. Percent volatile 90.1 % estimated 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity Material is stable under normal conditions.Chemical stability No dangerous reaction known under conditions of normal use.Possibility of hazardous reactions Heat, flames and sparks. Contact with incompatible materials.Conditions to avoid Acids. Aluminum. Strong oxidizing agents.Incompatible materials Carbon oxides.Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation May cause damage to organs through prolonged or repeated exposure by inhalation. May causedrowsiness and dizziness. Headache. Nausea, vomiting. Skin contact Prolonged skin contact may cause temporary irritation. Eye contact Causes serious eye irritation. Ingestion Health injuries are not known or expected under normal use. Symptoms related to the physical, chemical and toxicological characteristics May cause drowsiness and dizziness. Narcosis. Headache. Nausea, vomiting. Behavioralchanges. Decrease in motor functions. Severe eye irritation. Symptoms may include stinging,tearing, redness, swelling, and blurred vision. Edema. Information on toxicological effects Test ResultsComponentsSpecies 3-methylhexane (CAS 589-34-4) Dermal Acute LD50 Rabbit > 2000 mg/kg Oral LD50 Rat > 2000 mg/kg acetone (CAS 67-64-1) Dermal Acute LD50 Rabbit 20000 mg/kg Oral LD50 Rat 5800 mg/kg n-heptane (CAS 142-82-5) Dermal Acute * Estimates for product may be based on additional component data not shown. LD50 Rabbit 3000 mg/kg Prolonged skin contact may cause temporary irritation.Skin corrosion/irritation Causes serious eye irritation.Serious eye damage/eye irritation Not a respiratory sensitizer. This product is not expected to cause skin sensitization.Skin sensitization 6 / 11 Material name: Throttle Body & Air-Intake Cleaner No. 05078 (Item# 1003688) Version #: 03 Revision date: 08-22-2017 Issue date: 05-07-2015 SDS US No data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.Germ cell mutagenicity Not classifiable as to carcinogenicity to humans. IARC Monographs. Overall Evaluation of Carcinogenicity toluene (CAS 108-88-3)3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. US. National Toxicology Program (NTP) Report on Carcinogens Not listed. Suspected of damaging the unborn child.Reproductive toxicity Specific target organ toxicity - single exposure May cause drowsiness and dizziness. Specific target organ toxicity - repeated exposure May cause damage to organs (central nervous system, kidney, peripheral nervous system)through prolonged or repeated exposure. Aspiration hazard Not an aspiration hazard. Chronic effects May cause damage to organs through prolonged or repeated exposure. Prolonged inhalation maybe harmful. 12. Ecological information Toxic to aquatic life with long lasting effects.Ecotoxicity Components Test ResultsSpecies acetone (CAS 67-64-1) Aquatic EC50Crustacea 10294 - 17704 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish 4740 - 6330 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss) n-heptane (CAS 142-82-5) Aquatic Acute EC50Crustacea 1.5 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish 2.1 - 2.98 mg/l, 96 hoursFathead minnow (Pimephales promelas) toluene (CAS 108-88-3) Aquatic Acute EC50Crustacea 6 mg/l, 48 hoursWater flea (Daphnia magna) * Estimates for product may be based on additional component data not shown. LC50Fish 5.5 mg/l, 96 hoursCoho salmon,silver salmon(Oncorhynchus kisutch) Persistence and degradability Bioaccumulative potential acetone -0.24 n-heptane 4.66 toluene 2.73 Bioconcentration factor (BCF)toluene 90 No data available.Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations If discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim ordispose in sealed containers at licensed waste disposal site. Contents under pressure. Do notpuncture, incinerate or crush. Dispose in accordance with all applicable regulations. Disposal of waste from residues / unused products D001: Waste Flammable material with a flash point <140 FHazardous waste code 7 / 11 Material name: Throttle Body & Air-Intake Cleaner No. 05078 (Item# 1003688) Version #: 03 Revision date: 08-22-2017 Issue date: 05-07-2015 SDS US Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied. Contaminated packaging 14. Transport information DOT UN1950UN number Aerosols, flammable, Limited QuantityUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk 2.1Label(s) Not applicable.Packing group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user N82Special provisions 306Packaging exceptions NonePackaging non bulk NonePackaging bulk IATA UN1950UN number Aerosols, flammable, Limited QuantityUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk Not applicable.Packing group 10LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Allowed with restrictions.Passenger and cargo aircraft Other information Allowed with restrictions.Cargo aircraft only IMDG UN1950UN number AEROSOLS, Limited QuantityUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk Not applicable.Packing group No.Marine pollutant Environmental hazards Not available.EmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance toluene (CAS 108-88-3) CERCLA Hazardous Substance List (40 CFR 302.4) 3,3-dimethylpentane (CAS 562-49-2)Listed. acetone (CAS 67-64-1)Listed. toluene (CAS 108-88-3)Listed. CERCLA Hazardous Substances: Reportable quantity 3,3-dimethylpentane (CAS 562-49-2)100 LBS 8 / 11 Material name: Throttle Body & Air-Intake Cleaner No. 05078 (Item# 1003688) Version #: 03 Revision date: 08-22-2017 Issue date: 05-07-2015 SDS US acetone (CAS 67-64-1)5000 LBS toluene (CAS 108-88-3)1000 LBS Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the NationalResponse Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List toluene (CAS 108-88-3) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated.Safe Drinking Water Act (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number acetone (CAS 67-64-1)6532toluene (CAS 108-88-3)6594 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) acetone (CAS 67-64-1)35 %WV toluene (CAS 108-88-3)35 %WV DEA Exempt Chemical Mixtures Code Number acetone (CAS 67-64-1)6532toluene (CAS 108-88-3)594 FEMA Priority Substances Respiratory Health and Safety in the Flavor Manufacturing Workplace acetone (CAS 67-64-1)Low priority Not regulated.Food and Drug Administration (FDA) Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - YesDelayed Hazard - YesFire Hazard - YesPressure Hazard - YesReactivity Hazard - No Section 311/312 Hazard categories NoSARA 302 Extremely hazardous substance US state regulations US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) acetone (CAS 67-64-1)toluene (CAS 108-88-3) US. New Jersey Worker and Community Right-to-Know Act 3-methylhexane (CAS 589-34-4)acetone (CAS 67-64-1) carbon dioxide (CAS 124-38-9) n-heptane (CAS 142-82-5) toluene (CAS 108-88-3) US. Massachusetts RTK - Substance List 2-methylhexane (CAS 591-76-4) 3-methylhexane (CAS 589-34-4)acetone (CAS 67-64-1)carbon dioxide (CAS 124-38-9)n-heptane (CAS 142-82-5)toluene (CAS 108-88-3) US. Pennsylvania Worker and Community Right-to-Know Law 3,3-dimethylpentane (CAS 562-49-2) 3-methylhexane (CAS 589-34-4) acetone (CAS 67-64-1) carbon dioxide (CAS 124-38-9) n-heptane (CAS 142-82-5) toluene (CAS 108-88-3) US. Rhode Island RTK acetone (CAS 67-64-1)carbon dioxide (CAS 124-38-9) 9 / 11 Material name: Throttle Body & Air-Intake Cleaner No. 05078 (Item# 1003688) Version #: 03 Revision date: 08-22-2017 Issue date: 05-07-2015 SDS US n-heptane (CAS 142-82-5) toluene (CAS 108-88-3) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or otherreproductive harm. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance acetaldehyde (CAS 75-07-0)Listed: April 1, 1988 benzene (CAS 71-43-2)Listed: February 27, 1987 cumene (CAS 98-82-8)Listed: April 6, 2010 ethylbenzene (CAS 100-41-4)Listed: June 11, 2004 naphthalene (CAS 91-20-3)Listed: April 19, 2002 US - California Proposition 65 - CRT: Listed date/Developmental toxin benzene (CAS 71-43-2)Listed: December 26, 1997toluene (CAS 108-88-3)Listed: January 1, 1991 US - California Proposition 65 - CRT: Listed date/Male reproductive toxin benzene (CAS 71-43-2)Listed: December 26, 1997 Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)) 9.1 % CompliantConsumer products (40 CFR 59, Subpt. C) State This product is regulated as a Fuel Injection Air Intake Cleaner. This product is compliant for use inall 50 states.Consumer products VOC content (CA)9.1 % VOC content (OTC)9.1 % International Inventories Country(s) or region Inventory name On inventory (yes/no)* NoAustraliaAustralian Inventory of Chemical Substances (AICS) NoCanadaDomestic Substances List (DSL) YesCanadaNon-Domestic Substances List (NDSL) NoChinaInventory of Existing Chemical Substances in China (IECSC) NoEuropeEuropean Inventory of Existing Commercial ChemicalSubstances (EINECS) NoEuropeEuropean List of Notified Chemical Substances (ELINCS) NoJapanInventory of Existing and New Chemical Substances (ENCS) YesKoreaExisting Chemicals List (ECL) NoNew Zealand New Zealand Inventory YesPhilippinesPhilippine Inventory of Chemicals and Chemical Substances(PICCS) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) country(s). 16. Other information, including date of preparation or last revision 05-07-2015Issue date 08-22-2017Revision date Allison YoonPrepared by Version #03 CRC # 464K/1002465Further information Health: 2*Flammability: 4Physical hazard: 0Personal protection: B HMIS® ratings 10 / 11 Material name: Throttle Body & Air-Intake Cleaner No. 05078 (Item# 1003688) Version #: 03 Revision date: 08-22-2017 Issue date: 05-07-2015 SDS US Health: 2Flammability: 4Instability: 0 NFPA ratings NFPA ratings 02 4 The information contained in this document applies to this specific material as supplied. It may notbe valid for this material if it is used in combination with any other materials. This information isaccurate to the best of CRC's knowledge or obtained from sources believed by CRC to beaccurate. Before using any product, read all warnings and directions on the label. For furtherclarification of any information contained on this (M)SDS consult your supervisor, a health & safetyprofessional, or CRC Industries, Inc.. Disclaimer This document has undergone significant changes and should be reviewed in its entirety.Revision Information 11 / 11 Material name: Throttle Body & Air-Intake Cleaner No. 05078 (Item# 1003688) Version #: 03 Revision date: 08-22-2017 Issue date: 05-07-2015 SDS US Page: 1 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 11/2/2017 SDS Number: R0382635 Valvoline™ ATF+4 Full Synthetic Automatic Transmission Fluid 822348 Version: 1.5 1 / 17 29 CFR 1910.1200 (OSHA HazCom 2012) SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Trade name : Valvoline™ ATF+4 Full Synthetic Automatic Transmission Fluid Relevant identified uses of the substance or mixture and uses advised against Recommended use : Engine, gear & lubricating oil. Details of the supplier of the safety data sheet Emergency telephone number Regulatory Information Number Product Information SECTION 2. HAZARDS IDENTIFICATION GHS Classification Skin sensitization : Category 1 GHS label elements Hazard pictograms : Signal Word : Warning Hazard Statements : May cause an allergic skin reaction. Precautionary Statements : If medical advice is needed, have product container or label at hand. Keep out of reach of children. Read label before use. Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves. Page: 2 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 11/2/2017 SDS Number: R0382635 Valvoline™ ATF+4 Full Synthetic Automatic Transmission Fluid 822348 Version: 1.5 2 / 17 Disposal: Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Chemical nature : Defatter Hazardous components Chemical name CAS-No. Classification Concentration (%) HYDROTREATED LIGHT PARAFFINIC DISTILLATE 64742-55-8 This material is not considered hazardous under the OSHA Hazard Communication Standard (HazCom 2012). 59.3321 Distillates (Petroleum), Hydrotreated Heavy Paraffinic 64742-54-7 Asp. Tox. 1; H304 25.6673 HYDROTREATED LIGHT PARAFFINIC DISTILLATE 64742-55-8 Asp. Tox. 1; H304 3.2526 Mineral Oil Asp. Tox. 1; H304 3.1046 BENZENE, POLYPROPENE DERIVATIVES, SULFONATED, CALCIUM SALTS Eye Irrit. 2A; H319 Skin Sens. 1; H317 0.7703 DODECYL HYDROXYPROPYL SULFIDE 67124-09-8 Skin Sens. 1; H317 0.7703 C14-C18 alpha-olefin epoxide, reaction products with boric acid Skin Sens. 1; H317 0.3813 SECTION 4. FIRST AID MEASURES Page: 3 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 11/2/2017 SDS Number: R0382635 Valvoline™ ATF+4 Full Synthetic Automatic Transmission Fluid 822348 Version: 1.5 3 / 17 General advice : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. If inhaled : If breathed in, move person into fresh air. If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact : Remove contaminated clothing. If irritation develops, get medical attention. If on skin, rinse well with water. First aid is not normally required. However, it is recommended that exposed areas be cleaned by washing with soap and water. Wash contaminated clothing before re-use. In case of eye contact : Flush eyes with water as a precaution. Remove contact lenses. Protect unharmed eye. If eye irritation persists, consult a specialist. If swallowed : Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Most important symptoms and effects, both acute and delayed : Acute aspiration of large amounts of oil-laden material may produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of long-term sequelae. Repeated aspiration of small quantities of mineral oil can produce chronic inflammation of the lungs (i.e. lipoid pneumonia) that may progress to pulmonary fibrosis. Symptoms are often subtle and radiological changes appear worse than clinical abnormalities. Occasionally, persistent cough, irritation of the upper respiratory tract, shortness of breath with exertion, fever, and bloody sputum occur. Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary abnormalities. Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include: acne stomach or intestinal upset (nausea, vomiting, diarrhea) irritation (nose, throat, airways) May cause an allergic skin reaction. Notes to physician : No hazards which require special first aid measures. Page: 4 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 11/2/2017 SDS Number: R0382635 Valvoline™ ATF+4 Full Synthetic Automatic Transmission Fluid 822348 Version: 1.5 4 / 17 SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray Foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media : High volume water jet Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products : carbon dioxide and carbon monoxide Hydrocarbons Aldehydes Specific extinguishing methods : Product is compatible with standard fire-fighting agents. Further information : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. Other information : Comply with all applicable federal, state, and local regulations. Page: 5 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 11/2/2017 SDS Number: R0382635 Valvoline™ ATF+4 Full Synthetic Automatic Transmission Fluid 822348 Version: 1.5 5 / 17 SECTION 7. HANDLING AND STORAGE Advice on safe handling : Do not breathe vapours/dust. Do not smoke. Persons susceptible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. Container hazardous when empty. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. Smoking, eating and drinking should be prohibited in the application area. For personal protection see section 8. Dispose of rinse water in accordance with local and national regulations. Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Page: 6 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 11/2/2017 SDS Number: R0382635 Valvoline™ ATF+4 Full Synthetic Automatic Transmission Fluid 822348 Version: 1.5 6 / 17 Hazardous components without workplace control parameters Components CAS-No. Mineral Oil BENZENE, POLYPROPENE DERIVATIVES, SULFONATED, CALCIUM SALTS DODECYL HYDROXYPROPYL SULFIDE 67124-09-8 C14-C18 alpha-olefin epoxide, reaction products with boric acid : Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Personal protective equipment Hand protection Page: 7 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 11/2/2017 SDS Number: R0382635 Valvoline™ ATF+4 Full Synthetic Automatic Transmission Fluid 822348 Version: 1.5 7 / 17 SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Physical state : liquid Colour : red Odour : No data available Odour Threshold : No data available pH : No data available Melting point/freezing point : No data available Boiling point/boiling range : No data available Flash point : > 390 °F / > 199 °C Method: Cleveland open cup Evaporation rate : No data available Flammability (solid, gas) : No data available Upper explosion limit : 6 %(V) Calculated Explosive Limit Lower explosion limit : 1 %(V) Calculated Explosive Limit Vapour pressure : 0.0133333 hPa (21.11 °C) Calculated Vapor Pressure Relative vapour density : No data available Relative density : 0.854 (15.6 °C) Density : 0.8508 g/cm3 (15.56 °C) Solubility(ies) Page: 8 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 11/2/2017 SDS Number: R0382635 Valvoline™ ATF+4 Full Synthetic Automatic Transmission Fluid 822348 Version: 1.5 8 / 17 Viscosity SECTION 10. STABILITY AND REACTIVITY Reactivity : No decomposition if stored and applied as directed. Chemical stability : Stable under recommended storage conditions. Possibility of hazardous reactions : Product will not undergo hazardous polymerization. Conditions to avoid : excessive heat Incompatible materials : Strong oxidizing agents Hazardous decomposition products carbon dioxide and carbon monoxide Hydrocarbons SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation Skin contact Eye Contact Ingestion Acute toxicity Not classified based on available information. Components: Distillates (Petroleum), Hydrotreated Heavy Paraffinic: Acute oral toxicity : LD50 (Rat): > 15 g/kg Acute dermal toxicity : LD50 (Rabbit): > 5 g/kg Page: 9 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 11/2/2017 SDS Number: R0382635 Valvoline™ ATF+4 Full Synthetic Automatic Transmission Fluid 822348 Version: 1.5 9 / 17 DODECYL HYDROXYPROPYL SULFIDE: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg GLP: yes Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Assessment: Not classified as acutely toxic by dermal absorption under GHS. Skin corrosion/irritation Not classified based on available information. Product: Remarks: May cause skin irritation in susceptible persons. Components: HYDROTREATED LIGHT PARAFFINIC DISTILLATE: Result: Slight, transient irritation Distillates (Petroleum), Hydrotreated Heavy Paraffinic: Result: Slight, transient irritation HYDROTREATED LIGHT PARAFFINIC DISTILLATE: Result: Slight, transient irritation BENZENE, POLYPROPENE DERIVATIVES, SULFONATED, CALCIUM SALTS: Result: Slight, transient irritation DODECYL HYDROXYPROPYL SULFIDE: Species: Rabbit Result: No skin irritation C14-C18 alpha-olefin epoxide, reaction products with boric acid: Result: No skin irritation Serious eye damage/eye irritation Not classified based on available information. Product: Result: Slight, transient irritation Remarks: Expected based on components. Remarks: Unlikely to cause eye irritation or injury. Components: HYDROTREATED LIGHT PARAFFINIC DISTILLATE: Result: Slight, transient irritation Distillates (Petroleum), Hydrotreated Heavy Paraffinic: Result: No eye irritation HYDROTREATED LIGHT PARAFFINIC DISTILLATE: Page: 10 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 11/2/2017 SDS Number: R0382635 Valvoline™ ATF+4 Full Synthetic Automatic Transmission Fluid 822348 Version: 1.5 10 / 17 BENZENE, POLYPROPENE DERIVATIVES, SULFONATED, CALCIUM SALTS: Result: Irritating to eyes. DODECYL HYDROXYPROPYL SULFIDE: Species: Rabbit Result: No eye irritation C14-C18 alpha-olefin epoxide, reaction products with boric acid: Result: No eye irritation Respiratory or skin sensitisation Skin sensitisation: May cause an allergic skin reaction. Respiratory sensitisation: Not classified based on available information. Components: BENZENE, POLYPROPENE DERIVATIVES, SULFONATED, CALCIUM SALTS: Assessment: May cause sensitisation by skin contact. DODECYL HYDROXYPROPYL SULFIDE: Test Type: Local lymph node assay Species: Guinea pig Assessment: May cause sensitisation by skin contact. Method: OECD Test Guideline 429 C14-C18 alpha-olefin epoxide, reaction products with boric acid: Assessment: May cause sensitisation by skin contact. Germ cell mutagenicity Not classified based on available information. Components: DODECYL HYDROXYPROPYL SULFIDE: Genotoxicity in vitro : Test Type: Ames test Test species: Salmonella typhimurium Metabolic activation: with and without metabolic activation Result: negative Carcinogenicity Not classified based on available information. Reproductive toxicity Not classified based on available information. STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Aspiration toxicity Not classified based on available information. Components: Distillates (Petroleum), Hydrotreated Heavy Paraffinic: Page: 11 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 11/2/2017 SDS Number: R0382635 Valvoline™ ATF+4 Full Synthetic Automatic Transmission Fluid 822348 Version: 1.5 11 / 17 HYDROTREATED LIGHT PARAFFINIC DISTILLATE: May be fatal if swallowed and enters airways. Mineral Oil: May be fatal if swallowed and enters airways. Further information Product: Remarks: No data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Ecotoxicology Assessment Components: Distillates (Petroleum), Hydrotreated Heavy Paraffinic: Toxicity to fish : LL50 (Fish): > 100 mg/l Toxicity to daphnia and other aquatic invertebrates : EL50 (Aquatic invertebrates): > 10,000 mg/l Toxicity to algae : EL50 (Algae, algal mat (Algae)): > 100 mg/l Toxicity to fish (Chronic toxicity) : NOEC (Fish): 10 mg/l Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Aquatic invertebrates): 10 mg/l DODECYL HYDROXYPROPYL SULFIDE: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 0.75 mg/l Exposure time: 96 h Test Type: semi-static test Method: OECD Test Guideline 203 GLP: yes Toxicity to daphnia and other aquatic invertebrates : EL50 (Daphnia magna (Water flea)): 0.58 mg/l Exposure time: 48 h Test Type: static test Test substance: WAF Page: 12 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 11/2/2017 SDS Number: R0382635 Valvoline™ ATF+4 Full Synthetic Automatic Transmission Fluid 822348 Version: 1.5 12 / 17 Persistence and degradability DODECYL HYDROXYPROPYL SULFIDE: Biodegradability : Result: Not readily biodegradable. Biodegradation: 5 % Exposure time: 28 d Method: OECD Test Guideline 301F No data available Bioaccumulative potential DODECYL HYDROXYPROPYL SULFIDE: Partition coefficient: n- octanol/water : log Pow: 4.7 - 6.5 No data available Mobility in soil No data available Other adverse effects No data available Product: Additional ecological information : An environmental hazard cannot be excluded in the event of unprofessional handling or disposal., Harmful to aquatic life with long lasting effects. SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Page: 13 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 11/2/2017 SDS Number: R0382635 Valvoline™ ATF+4 Full Synthetic Automatic Transmission Fluid 822348 Version: 1.5 13 / 17 SECTION 14. TRANSPORT INFORMATION International transport regulations REGULATION ID NUMBER PROPER SHIPPING NAME *HAZARD CLASS SUBSIDIARY HAZARDS PACKING GROUP MARINE POLLUTANT / LTD. QTY. U.S. DOT - ROAD Not dangerous goods CFR_RAIL_C Not dangerous goods U.S. DOT - INLAND WATERWAYS Not dangerous goods TDG_ROAD_C Not dangerous goods TDG_RAIL_C Not dangerous goods TDG_INWT_C Not dangerous goods INTERNATIONAL MARITIME DANGEROUS GOODS Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO Not dangerous goods Page: 14 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 11/2/2017 SDS Number: R0382635 Valvoline™ ATF+4 Full Synthetic Automatic Transmission Fluid 822348 Version: 1.5 14 / 17 INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER Not dangerous goods MX_DG Not dangerous goods *ORM = ORM-D, CBL = COMBUSTIBLE LIQUID Marine pollutant no Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) BENZENE 71-43-2 10 * *: Calculated RQ exceeds reasonably attainable upper limit. SARA 304 Extremely Hazardous Substances Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) SULFUR DIOXIDE 7446-09-5 500 * SULFUR DIOXIDE 7446-09-5 * *: Calculated RQ exceeds reasonably attainable upper limit. SARA 311/312 Hazards SARA 313 California Prop 65 The components of this product are reported in the following inventories: DSL : All components of this product are on the Canadian DSL AICS : On the inventory, or in compliance with the inventory ENCS : Not in compliance with the inventory KECI : On the inventory, or in compliance with the inventory Page: 15 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 11/2/2017 SDS Number: R0382635 Valvoline™ ATF+4 Full Synthetic Automatic Transmission Fluid 822348 Version: 1.5 15 / 17 Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) SECTION 16. OTHER INFORMATION Further information Revision Date: 05/22/2017 NFPA: HMIS III: NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class IIIB Full text of H-Statements H304 May be fatal if swallowed and enters airways. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. Sources of key data used to compile the Safety Data Sheet Valvoline internal data including own and sponsored test reports The UNECE administers regional agreements implementing harmonised classification for labelling (GHS) and transport. Flammability He a l t h In s t a b i l i t y 2 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 2 Special hazard.0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page: 16 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 11/2/2017 SDS Number: R0382635 Valvoline™ ATF+4 Full Synthetic Automatic Transmission Fluid 822348 Version: 1.5 16 / 17 The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Valvoline's Environmental Health and Safety Department (1-800-VALVOLINE). List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the “International Air Transport Association” (IATA). ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the “International Civil Aviation Organization” IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System Page: 17 SAFETY DATA SHEET Revision Date: 05/22/2017 Print Date: 11/2/2017 SDS Number: R0382635 Valvoline™ ATF+4 Full Synthetic Automatic Transmission Fluid 822348 Version: 1.5 17 / 17 Page: 1 SAFETY DATA SHEET Revision Date: 12/11/2013 Print Date: 3/25/2014 MSDS Number: R0321370 Zerex™ G-05™ Formula 50/50 ANTIFREEZE COOLANT ZXG05RU1 Version: 1.16 Page 1 / 12 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 2. HAZARDS IDENTIFICATION Emergency Overview Appearance: liquid, light yellow WARNING! MAY AFFECT THE CENTRAL NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. HARMFUL IF SWALLOWED. Potential Health Effects Exposure routes Inhalation, Skin absorption, Skin contact, Eye Contact, Ingestion Eye contact May cause mild eye irritation. Symptoms include stinging, tearing, and redness. Skin contact No data Ingestion Swallowing this material may be harmful. Liver, kidney and brain damage in humans has resulted from swallowing lethal or near-lethal amounts of ethylene glycol. Inhalation It is possible to breathe this material under certain conditions of handling and use (for example, during heating, spraying, or stirring). Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts may be harmful. Symptoms are not expected at air concentrations below the recommended exposure limits, if applicable (see Section 8.). Aggravated Medical Condition Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material:, lung (for example, asthma-like conditions), Liver, Kidney, Central nervous system, Exposure to this material may aggravate any preexisting condition sensitive to a decrease in available oxygen, such as chronic lung disease, coronary artery disease or anemias. Page: 2 SAFETY DATA SHEET Revision Date: 12/11/2013 Print Date: 3/25/2014 MSDS Number: R0321370 Zerex™ G-05™ Formula 50/50 ANTIFREEZE COOLANT ZXG05RU1 Version: 1.16 Page 2 / 12 Symptoms Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include:, stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways), Cough, central nervous system excitation (giddiness, liveliness, light-headed feeling) followed by central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness) and other central nervous system effects, involuntary eye movement, pain in the abdomen and lower back, cyanosis (causes blue coloring of the skin and nails from lack of oxygen), lung edema (fluid buildup in the lung tissue), acute kidney failure (sudden slowing or stopping of urine production), liver damage, Convulsions, coma Target Organs Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals:, reproductive effects, kidney damage, liver damage, central nervous system damage, Overexposure to this material (or its components) has been suggested as a cause of the following effects in humans:, liver damage, kidney damage Carcinogenicity This material is not listed as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), or the Occupational Safety and Health Administration (OSHA). Reproductive hazard Ethylene glycol has caused birth defects in animal studies at high oral doses. However, it did not cause harm to the pregnant animal or to the fetus when applied to the skin of the pregnant animal., This material (or a component) has been shown to cause harm to the fetus in laboratory animal studies. Harm to the fetus occurs only at exposure levels that harm the pregnant animal. The relevance of these findings to humans is uncertain. ETHYLENE GLYCOL 107-21-1 >=40-<50% DIETHYLENE GLYCOL 111-46-6 >=1.5-<5% SODIUM BENZOATE 532-32-1 >=1.5-<5% Eyes If symptoms develop, move individual away from exposure and into fresh air. Flush eyes gently with water while holding eyelids apart. If symptoms persist or there is any visual difficulty, seek medical attention. Skin Remove contaminated clothing. Wash exposed area with soap and water. If symptoms persist, seek medical attention. Launder clothing before reuse. Page: 3 SAFETY DATA SHEET Revision Date: 12/11/2013 Print Date: 3/25/2014 MSDS Number: R0321370 Zerex™ G-05™ Formula 50/50 ANTIFREEZE COOLANT ZXG05RU1 Version: 1.16 Page 3 / 12 Ingestion Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended. Inhalation If symptoms develop, immediately move individual away from exposure and into fresh air. Seek immediate medical attention; keep person warm and quiet. If person is not breathing, begin artificial respiration. If breathing is difficult, administer oxygen. Notes to physician Hazards: Effects of acute ethylene glycol poisoning appear in three fairly distinct stages. The initial stage occurs shortly after exposure, lasts 6-12 hours, and is characterized by central nervous system effects (transient exhilaration, nausea, vomiting, and in severe cases, coma, convulsions, and possible death). The second stage lasts from 12-36 hours after exposure and is initiated by the onset of coma. This phase is characterized by tachypnia, tachycardia, mild hypotension, cyanosis, and in severe cases, pulmonary edema, bronchopneumonia, cardiac enlargement, and congestive failure. The final stage occurs 24-72 post-exposure and is characterized by renal failure, ranging from a mild increase in blood urea nitrogen and creatinine followed by recovery, to complete anuria with acute tubular necrosis that can lead to death. Oxaluria is found in most cases. The most significant laboratory finding in ethylene glycol intoxication is severe metabolic acidosis. Ingestion or other significant exposure to this material (or a component) may cause metabolic acidosis. Treatment: This product contains ethylene glycol. Ethanol decreases the metabolism of ethylene glycol to toxic metabolites. Ethanol should be administered as soon as possible in cases of severe poisoning since the elimination half-life of ethylene glycol is 3 hours. If medical care will be delayed several hours, give the patient three to four 1-ounce oral "shots" of 86-proof or higher whiskey before or during transport to the hospital. Fomepizole (4-methylpyrazole) is an effective antagonist of alcohol dehydrogenase, and as such, may be used as an antidote in the treatment of ethylene glycol poisoning. Hemodialysis effectively removes ethylene glycol and its metabolites from the body. Fomepizole (4-methylpyrazole) is an effective antagonist of alcohol dehydrogenase, and as such, may be used as an antidote in the treatment of ethylene glycol, diethylene glycol and methanol poisoning. Suitable extinguishing media Dry chemical, Carbon dioxide (CO2), Water spray Hazardous combustion products Alcohols, Aldehydes, carbon dioxide and carbon monoxide, ethers, Hydrocarbons, Sodium oxides, toxic fumes Precautions for fire-fighting Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA). DO NOT direct a solid stream of water or foam into hot, burning pools of liquid since this may cause frothing and increase fire intensity. Frothing can be violent and possibly endanger any firefighter standing too close to the burning liquid. Use water spray to cool fire exposed containers and structures until fire is out if it can be done with minimal risk. Avoid spreading burning material with water used for cooling purposes. Page: 4 SAFETY DATA SHEET Revision Date: 12/11/2013 Print Date: 3/25/2014 MSDS Number: R0321370 Zerex™ G-05™ Formula 50/50 ANTIFREEZE COOLANT ZXG05RU1 Version: 1.16 Page 4 / 12 NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class IIIB Personal precautions For personal protection see section 8. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions Prevent spreading over a wide area (e.g. by containment or oil barriers). Do not let product enter drains. Do not flush into surface water or sanitary sewer system. Methods for cleaning up Keep in suitable, closed containers for disposal. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Other information Comply with all applicable federal, state, and local regulations. Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Storage Store in a cool, dry, ventilated area, away from incompatible substances. Store in a cool, dry, ventilated area. Keep containers closed when not in use. Do not store near extreme heat, open flame, or sources of ignition.Store in a cool, dry, ventilated area. Exposure Guidelines ACGIH Ceiling Limit Value: 100 mg/m3 Aerosol. WEEL time weighted average 10 mg/m3 General advice These recommendations provide general guidance for handling this product. Personal protective equipment should be selected for individual applications and should consider factors which affect exposure Page: 5 SAFETY DATA SHEET Revision Date: 12/11/2013 Print Date: 3/25/2014 MSDS Number: R0321370 Zerex™ G-05™ Formula 50/50 ANTIFREEZE COOLANT ZXG05RU1 Version: 1.16 Page 5 / 12 potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local authorities. Exposure controls Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Eye protection Not required under normal conditions of use. Wear splash-proof safety goggles if material could be misted or splashed into eyes. Skin and body protection Wear resistant gloves such as: Neoprene Nitrile rubber polyvinyl chloride Polyethylene Wear normal work clothing including long pants, long-sleeved shirts and foot covering to prevent direct contact of the product with the skin. Launder clothing before reuse. If skin irritation develops, contact your facility health and safety professional or your local safety equipment supplier to determine the proper personal protective equipment for your use. Wear resistant gloves (consult your safety equipment supplier). Respiratory protection Respiratory protection is not required under normal conditions of use. liquidlight yellow 225 °F / 107 °C @ 760.00 mmHg (Average) 8.0 > 250.0 °F / > 121.1 °C Cleveland open cup 1.7 %(V) / 15.3 %(V) 1.800 mmHg @ 68.00 °F / 20.00 °C (>)1.000 AIR=1 1.0779 g/cm3 @ 60.01 °F / 15.56 °C Stability Stable. Conditions to avoid excessive heat Page: 6 SAFETY DATA SHEET Revision Date: 12/11/2013 Print Date: 3/25/2014 MSDS Number: R0321370 Zerex™ G-05™ Formula 50/50 ANTIFREEZE COOLANT ZXG05RU1 Version: 1.16 Page 6 / 12 Incompatible products Acids, Aldehydes, Alkali metals, Alkaline earth metals, Bases, iron salts, strong alkalis, Strong oxidizing agents, Sulphur compounds Hazardous decomposition products Alcohols, Aldehydes, carbon dioxide and carbon monoxide, ethers, Hydrocarbons, Organic acids, Sodium oxides, ketones Hazardous reactions Product will not undergo hazardous polymerization. Product Acute oral toxicity : no data available Acute inhalation toxicity : no data available Acute dermal toxicity : no data available Skin corrosion/irritation : no data available Serious eye damage/eye irritation : no data available Respiratory or skin sensitisation : no data available Target Organ Systemic Toxicant - Repeated Exposure : Target Organs: Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals:, reproductive effects, kidney damage, liver damage, central nervous system damage, Overexposure to this material (or its components) has been suggested as a cause of the following effects in humans:, liver damage, kidney damage Page: 7 SAFETY DATA SHEET Revision Date: 12/11/2013 Print Date: 3/25/2014 MSDS Number: R0321370 Zerex™ G-05™ Formula 50/50 ANTIFREEZE COOLANT ZXG05RU1 Version: 1.16 Page 7 / 12 Components: ETHYLENE GLYCOL: Acute oral toxicity : LD 50 Rat: 6,140 mg/kg Acute dermal toxicity : LD 50 Rabbit: 9,530 mg/kg STOT - repeated exposure : Exposure routes: Ingestion Target Organs: Kidney, Liver Assessment: May cause damage to organs through prolonged or repeated exposure. DIETHYLENE GLYCOL: Acute oral toxicity : LD 50 Rat: 12,565 mg/kg Acute inhalation toxicity : LC Lo Mouse: 130 mg/m3 Exposure time: 2 h Acute dermal toxicity : LD 50 Rabbit: 11,890 mg/kg Experience with human exposure : Liver SODIUM BENZOATE: Acute oral toxicity : LD 50 Rat, male and female: 3,450 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity Product: no data available Components: ETHYLENE GLYCOL: Toxicity to fish : LC 50 (Bluegill (Lepomis macrochirus)): 27,540 mg/l Exposure time: 96 h Method: Static Mortality LC 50 (Fathead minnow (Pimephales promelas)): 8,050 mg/l Exposure time: 96 h Page: 8 SAFETY DATA SHEET Revision Date: 12/11/2013 Print Date: 3/25/2014 MSDS Number: R0321370 Zerex™ G-05™ Formula 50/50 ANTIFREEZE COOLANT ZXG05RU1 Version: 1.16 Page 8 / 12 DIETHYLENE GLYCOL: Toxicity to fish : LC 50 (Western mosquitofish (Gambusia affinis)): > 32,000 mg/l Exposure time: 96 h Method: Static Mortality Toxicity to daphnia and other aquatic invertebrates : LC 50 (Water flea (Daphnia magna)): > 10,000 mg/l Exposure time: 24 h Method: Static Mortality SODIUM BENZOATE: Toxicity to fish : LC 50 (Fathead minnow (Pimephales promelas)): > 100 mg/l Exposure time: 96 h Test Method: static test Method: Static Mortality Toxicity to daphnia and other aquatic invertebrates : LC 50 (Water flea (Daphnia magna)): > 100 mg/l Exposure time: 96 h Test Method: static test Method: Static Mortality Persistence and degradability Product: no data available Components: DIETHYLENE GLYCOL: Biodegradability : Biodegradation: 92 % Exposure time: 28 d Bioaccumulative potential Page: 9 SAFETY DATA SHEET Revision Date: 12/11/2013 Print Date: 3/25/2014 MSDS Number: R0321370 Zerex™ G-05™ Formula 50/50 ANTIFREEZE COOLANT ZXG05RU1 Version: 1.16 Page 9 / 12 Product: no data available Components: ETHYLENE GLYCOL: Bioaccumulation : Species: Crayfish (Procambarus) Exposure time: 61 d Concentration: 1000 mg/l Bioconcentration factor (BCF): 0.27 Method: Flow through Partition coefficient: n-octanol/water : log Pow: -1.36 DIETHYLENE GLYCOL: Partition coefficient: n-octanol/water : log Pow: -1.47 Mobility in soil Product: no data available Components: ETHYLENE GLYCOL: Surface tension : 48.4 mN/m DIETHYLENE GLYCOL: Surface tension : 48.5 mN/m 13. DISPOSAL CONSIDERATIONS Waste disposal methods Dispose of in accordance with all applicable local, state and federal regulations. 14. TRANSPORT INFORMATION REGULATION Page: 10 SAFETY DATA SHEET Revision Date: 12/11/2013 Print Date: 3/25/2014 MSDS Number: R0321370 Zerex™ G-05™ Formula 50/50 ANTIFREEZE COOLANT ZXG05RU1 Version: 1.16 Page 10 / 12 U.S. DOT - ROAD Not dangerous goods U.S. DOT - RAIL Not dangerous goods U.S. DOT - INLAND WATERWAYS Not dangerous goods TRANSPORT CANADA - ROAD Not dangerous goods TRANSPORT CANADA - RAIL Not dangerous goods TRANSPORT CANADA - INLAND WATERWAYS Not dangerous goods INTERNATIONAL MARITIME DANGEROUS GOODS Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER Not dangerous goods MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND WASTES Not dangerous goods *ORM = ORM-D, CBL = COMBUSTIBLE LIQUID Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. California Prop. 65 Page: 11 SAFETY DATA SHEET Revision Date: 12/11/2013 Print Date: 3/25/2014 MSDS Number: R0321370 Zerex™ G-05™ Formula 50/50 ANTIFREEZE COOLANT ZXG05RU1 Version: 1.16 Page 11 / 12 SARA Hazard Classification SARA 311/312 Classification SARA 313 Component(s) New Jersey RTK Label Information WATER 7732-18-5 ETHYLENE GLYCOL 107-21-1 DIETHYLENE GLYCOL 111-46-6 SODIUM BENZOATE 532-32-1 Pennsylvania RTK Label InformationWATER 7732-18-5 ETHYLENE GLYCOL 107-21-1 DIETHYLENE GLYCOL 111-46-6 Notification status US. Toxic Substances Control Act y (positive listing) Canada. Canadian Environmental Protection Act (CEPA). Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133) y (positive listing) Australia. Industrial Chemical (Notification and Assessment) Act y (positive listing) Japan. ENCS - Existing and New Chemical Substances Inventory n (Negative listing) Korea. Toxic Chemical Control Law (TCCL) List n (Negative listing) Philippines. The Toxic Substances and Hazardous and Nuclear Waste Control Act y (positive listing) China. Inventory of Existing Chemical Substances y (positive listing) Reportable quantity - ProductUS. EPA CERCLA Hazardous Substances (40 CFR 302) 11766 lbs Reportable quantity-ComponentsETHYLENE GLYCOL 107-21-1 5000 lbs Health 1* 1 Flammability 1 1 Physical hazards 0 Instability 0 Specific Hazard -- -- Page: 12 SAFETY DATA SHEET Revision Date: 12/11/2013 Print Date: 3/25/2014 MSDS Number: R0321370 Zerex™ G-05™ Formula 50/50 ANTIFREEZE COOLANT ZXG05RU1 Version: 1.16 Page 12 / 12 The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's Environmental Health and Safety Department (1-800-325-3751). List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the “International Air Transport Association” (IATA). ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the “International Civil Aviation Organization” IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System Material Safety Data Sheet Page 1 of 7 Section 1: Product & Company Identification Product Name: Carquest Non-Chlorinated Brake Parts Cleaner (aerosol) Product Number (s): 1010, 1010C (CRC Part# 09621, 79621) Product Use: brake parts cleaner Manufacturer / Supplier Contact Information: In United States: In Canada: In Mexico: CRC Industries, Inc. CRC Canada Co. CRC Industries Mexico 885 Louis Drive 2-1246 Lorimar Drive Av. Benito Juárez 4055 G Warminster, PA 18974 Mississauga, Ontario L5S 1R2 Colonia Orquídea www.crcindustries.com www.crc-canada.ca San Luís Potosí, SLP CP 78394 1-215-674-4300 (General) 1-905-670-2291 www.crc-mexico.com (800) 521-3168 (Technical) 52-444-824-1666 (800) 272-4620 (Customer Service) 24-Hr Emergency – CHEMTREC: (800) 424-9300 or (703) 527-3887 Section 2: Hazards Identification Emergency Overview DANGER: Extremely Flammable. Harmful or Fatal if Swallowed. May Cause Blindness if Swallowed. Vapor Harmful. Eye and Skin Irritant. Contents Under Pressure. Appearance & Odor: Clear liquid, solvent odor Potential Health Effects: ACUTE EFFECTS: EYE: Moderate eye irritant. Exposure can cause irritation including stinging, tearing, redness, blurred vision, and swelling of the eyes. SKIN: Moderate skin irritant. Prolonged or repeated contact may dry the skin. Symptoms may include redness, burning, drying and cracking of the skin, and skin burns. Passage of this material into the body through the skin is possible, but it is unlikely that this would result in harmful effects during safe handling and use. INHALATION: Breathing large amounts of this material may be harmful. Symptoms include irritation of the nose and throat and central nervous system excitation (giddiness), followed by CNS depression (dizziness, drowsiness, weakness, headache, nausea, unconsciousness). INGESTION: Swallowing small amounts is not likely to cause harmful effects. May cause stomach or intestinal upset. Swallowing larger amounts may be harmful as this material may be aspirated into the lungs during swallowing or vomiting. This results in lung inflammation and other lung injury. CHRONIC EFFECTS: Overexposure to methanol may lead to visual impairment. TARGET ORGANS: Liver, kidneys, blood, central nervous system, eyes Medical Conditions Aggravated by Exposure: skin sensitivities, lung conditions, central nervous system conditions See Section 11 for toxicology and carcinogenicity information on product ingredients. Product Name: Carquest Non-Chlorinated Brake Parts Cleaner (aerosol) Product Number (s): 1010, 1010C (CRC Part# 09621, 79621) Page 2 of 7 Section 3: Composition/Information on Ingredients COMPONENT CAS NUMBER % by Wt. Methanol 67-56-1 40 – 50 Toluene 108-88-3 35 – 45 Acetone 67-64-1 5 – 15 Carbon dioxide 124-38-9 3 – 8 Section 4: First Aid Measures Eye Contact: Immediately flush with plenty of water for 15 minutes. Call a physician if irritation persists. Skin Contact: Remove contaminated clothing and wash affected area with soap and water. Call a physician if irritation persists. Wash contaminated clothing prior to re-use. Inhalation: Remove person to fresh air. Keep person calm. If not breathing, give artificial respiration. If breathing is difficult give oxygen. Call a physician. Ingestion: Seek medical attention. Do not induce vomiting unless instructed by medical personnel. Have victim drink a glass of water if conscious. Note to Physicians: This material is an aspiration hazard. This material (or a component) has produced hyperglycemia and ketosis following substantial ingestion. Inhalation of high concentrations of this material may be associated with cardiac arrhythmias. Sympathomimetic drugs may initiate cardiac arrhythmias in persons exposed to this material. This product contains methanol. The metabolites of methanol can cause metabolic acidosis, visual disturbances and blindness. Section 5: Fire-Fighting Measures Flammable Properties: This product is extremely flammable in accordance with aerosol flammability definitions. (See 16 CFR 1500.3(c)(6) ). Flash Point: 0°F / -18°C (TCC) Upper Explosive Limit: ND Autoignition Temperature: 725°F / 385°C Lower Explosive Limit: ND Fire and Explosion Data: Suitable Extinguishing Media: Dry chemical, carbon dioxide, alcohol foam, Class B extinguishers Products of Combustion: Oxides of carbon Explosion Hazards: Aerosol containers, when exposed to heat from fire, may build pressure and explode. Vapors may accumulate in a confined space and create a flammable atmosphere. Protection of Fire-Fighters: Firefighters should wear self-contained, NIOSH-approved breathing apparatus for protection against suffocation and possible toxic decomposition products. Vapors are heavier than air and will accumulate near the ground. Proper eye and skin protection should be provided. Use water spray to keep fire-exposed containers cool and to knock down vapors which may result from product decomposition. Product Name: Carquest Non-Chlorinated Brake Parts Cleaner (aerosol) Product Number (s): 1010, 1010C (CRC Part# 09621, 79621) Page 3 of 7 Section 6: Accidental Release Measures Personal Precautions: Use personal protection recommended in Section 8. Environmental Precautions: Take precautions to prevent contamination of ground and surface waters. Do not flush into sewers or storm drains. Methods for Containment & Clean-up: Eliminate sources of ignition. Dike area to contain spill. Ventilate the area with fresh air. If in confined space or limited air circulation area, clean-up workers should wear appropriate respiratory protection. Recover or absorb spilled material using an absorbent designed for chemical spills. Place used absorbents into proper waste containers. Section 7: Handling and Storage Handling Procedures: Do not use near potential sources of ignition. Do not use on energized equipment. Use with adequate ventilation. Avoid contact with skin and eyes. Avoid inhaling vapors. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. For product use instructions, please see the product label. Storage Procedures: Store in a cool dry area out of direct sunlight. Aerosol cans must be maintained below 120°F / 49°C to prevent cans from rupturing. Aerosol Storage Level: III Section 8: Exposure Controls/Personal Protection Exposure Guidelines: OSHA ACGIH OTHER COMPONENT TWA STEL TWA STEL TWA SOURCE UNIT Methanol 200 NE 200 250 (s) NE ppm Toluene 200 300 (c) 20 NE NE ppm Acetone 1000 NE 500 750 NE ppm Carbon dioxide 5000 30000(v 5000 30000 NE ppm N.E. – Not Established (c) – ceiling (s) – skin (v) – vacated Controls and Protection: Engineering Controls: Area should have ventilation to provide fresh air. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at the source, preventing dispersion into the general work area. Use mechanical means if necessary to maintain vapor levels below the exposure guidelines. If working in a confined space, follow applicable OSHA regulations. Respiratory Protection: None required for normal work where adequate ventilation is provided. If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with organic vapor cartridge. Air monitoring is needed to determine actual employee exposure levels. Use a self-contained breathing apparatus in confined spaces and for emergencies. Eye/face Protection: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid contact, wear splash-proof goggles. Product Name: Carquest Non-Chlorinated Brake Parts Cleaner (aerosol) Product Number (s): 1010, 1010C (CRC Part# 09621, 79621) Page 4 of 7 Skin Protection: Use protective gloves such as nitrile, PVA, or neoprene. Also, use full protective clothing if there is prolonged or repeated contact of liquid with skin. Section 9: Physical and Chemical Properties Physical State: liquid Color: clear Odor: solvent Odor Threshold: ND Specific Gravity: 0.825 Initial Boiling Point: 132°F / 56°C Freezing Point: ND Vapor Pressure: ND Vapor Density: > 1 (air = 1) Evaporation Rate: fast Solubility: slightly soluble in water Coefficient of water/oil distribution: ND pH: NA Volatile Organic Compounds: wt %: 84.1 g/L: 693.6 lbs./gal: 5.8 Section 10: Stability and Reactivity Stability: Stable Conditions to Avoid: Sources of ignition; temperature extremes Incompatible Materials: Acids, alkalis, reducing agents, strong oxidizing agents, hypochlorites, peroxides, reactive metals such as aluminum and magnesium, sodium, zinc Hazardous Decomposition Products: Oxides of carbon, various hydrocarbons Possibility of Hazardous Reactions: No Section 11: Toxicological Information Long-term toxicological studies have not been conducted for this product. The following information is available for components of this product. Acute Toxicity: Component Oral LD50 (rat) Dermal LD50 (rabbit) Inhalation LC50 (rat) Methanol 5600 mg/kg 15,800 mg/kg 81,000 mg/m /14H Toluene 636 mg/kg 14,100 µL/kg 49 g/m /4H Acetone 5800 mg/kg No data 50,100 mg/m /8H Carbon dioxide No data No data 470,000 ppm/30M Product Name: Carquest Non-Chlorinated Brake Parts Cleaner (aerosol) Product Number (s): 1010, 1010C (CRC Part# 09621, 79621) Page 5 of 7 Chronic Toxicity: Component OSHA Carcinogen IARC Carcinogen NTP Carcinogen Irritant Sensitizer Methanol No No No E & S (moderate) UnknownToluene No No No E, S & R (mild) Unknown Acetone No No No E & S (moderate) / R (mild) Yes Carbon dioxide No No No No No Reproductive Toxicity: No information availableTeratogenicity: No information availableMutagenicity: No information availableSynergistic Effects: No information available Section 12: Ecological Information Ecological studies have not been conducted for this product. The following information is available for components of this product. Ecotoxicity: Acetone – 48H LC50 Daphnia: 10 mg/l Persistence / Degradability: No information availableBioaccumulation / Accumulation: No information availableMobility in Environment: No information available Section 13: Disposal Considerations Waste Classification: The dispensed liquid product is a RCRA hazardous waste for the characteristic of ignitability with the following potential waste code(s): D001, F003, F005. (See 40 CFR Part 261.20 – 261.33) Empty aerosol containers may be recycled. All disposal activities must comply with federal, state, provincial and local regulations. Local regulations may be more stringent than state, provincial or national requirements. Section 14: Transport Information US DOT (ground): Consumer Commodity, ORM-D ICAO/IATA (air): Consumer Commodity, ID8000, 9 IMO/IMDG (water): Aerosols, UN1950, 2.1, Limited Quantity Special Provisions: None Section 15: Regulatory Information U.S. Federal Regulations: E – Eye S – Skin R - Respiratory Product Name: Carquest Non-Chlorinated Brake Parts Cleaner (aerosol) Product Number (s): 1010, 1010C (CRC Part# 09621, 79621) Page 6 of 7 Toxic Substances Control Act (TSCA): All ingredients are either listed on the TSCA inventory or are exempt. Comprehensive Environmental Response, Compensation and Liability Act (CERCLA): Reportable Quantities (RQ’s) exist for the following ingredients: Acetone (5000 lbs), Toluene (1000 lbs), Methanol (5000 lbs) Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Superfund Amendments Reauthorization Act (SARA) Title III: Section 302 Extremely Hazardous Substances (EHS): None Section 311/312 Hazard Categories: Fire Hazard Yes Reactive Hazard No Release of Pressure Yes Acute Health Hazard Yes Chronic Health Hazard No Section 313 Toxic Chemicals: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: Toluene (< 39%), Methanol (< 46%) Clean Air Act: Section 112 Hazardous Air Pollutants (HAPs): Toluene, Methanol Occupational Safety and Health Administration: This product is regulated by the Hazard Communications Standard. U.S. State Regulations: California Safe Drinking Water and Toxic Enforcement Act (Prop 65): This product may contain the following chemicals known to the state of California to cause cancer, birth defects or other reproductive harm: Toluene Consumer Products VOC Regulations: This product does not comply with Consumer Products VOC regulations and cannot be used in California, Connecticut, Delaware, The District of Columbia, Illinois, Indiana, Maine, Maryland, Massachusetts, Michigan, New Jersey, New Hampshire, New York, Ohio, Pennsylvania, Rhode Island, and parts of Utah and Virginia. State Right to Know: New Jersey: 67-64-1, 108-88-3, 67-56-1, 124-38-9Pennsylvania: 67-64-1, 108-88-3, 67-56-1, 124-38-9Massachusetts: 67-64-1, 108-88-3, 67-56-1, 124-38-9Rhode Island : 67-64-1, 108-88-3, 67-56-1, 124-38-9 Canadian Regulations: Controlled Products Regulations: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. WHMIS Hazard Class: A, B5, D1A, D2A, D2B Canadian DSL Inventory: All ingredients are either listed on the DSL Inventory or are exempt. European Union Regulations: Product Name: Carquest Non-Chlorinated Brake Parts Cleaner (aerosol) Product Number (s): 1010, 1010C (CRC Part# 09621, 79621) Page 7 of 7 RoHS Compliance: This product is compliant with Directive 2002/95/EC of the European Parliament and of the Council of 27 January 2003. This product does not contain any of the restricted substances as listed in Article 4(1) of the RoHS Directive. Additional Regulatory Information: None Section 16: Other Information HMIS® (II) Health: 2 Flammability: 3 Reactivity: 0 PPE: B Ratings range from 0 (no hazard) to 4 (severe hazard) NFPA Prepared By: Michelle Rudnick CRC #: 581J Revision Date: 08/26/2014 Changes since last revision: Section 15: Consumer Products VOC Regulations The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this MSDS consult your supervisor, a health & safety professional, or CRC Industries. ACGIH: American Conference of Governmental Industrial Hygienists CAS: Chemical Abstract Service CFR: Code of Federal Regulations DOT: Department of Transportation DSL: Domestic Substance List g/L: grams per Liter HMIS: Hazardous Materials Identification System IARC: International Agency for Research on Cancer IATA: International Air Transport Association ICAO: International Civil Aviation Organization IMDG: International Maritime Dangerous Goods IMO: International Maritime Organization lbs./gal: pounds per gallon LC: Lethal Concentration LD: Lethal Dose NA: Not Applicable ND: Not Determined NIOSH: National Institute of Occupational Safety & Health NFPA: National Fire Protection Association NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration PMCC: Pensky-Martens Closed Cup PPE: Personal Protection Equipment ppm: Parts per Million RoHS: Restriction of Hazardous Substances STEL: Short Term Exposure Limit TCC: Tag Closed Cup TWA: Time Weighted Average WHMIS: Workplace Hazardous Materials Information System 3 02 SAFETY DATA SHEET 1. Identification Car Quest Multi-Purpose LubricantProduct identifier Other means of identification 1020SDS number 1020Part No. 3403.19.1000Tariff code LubricantRecommended use None known.Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Manufacturer RSC Chemical Solutions Address 600 Radiator Road Company name Website Telephone Customer Service:(704) 821-7643 Technical:(704) 684-1811 Emergency phone number Emergency Telephone:(303) 623-5716 Emergency Contact:RMPDC (877-740-5015) E-mail United States Not available. Indian Trail, NC 28079 2. Hazard(s) identification Category 2Flammable aerosolsPhysical hazards Category 2Skin corrosion/irritationHealth hazards Category 2BSerious eye damage/eye irritation Category 1BGerm cell mutagenicity Category 1BCarcinogenicity Category 2Reproductive toxicity Category 3 narcotic effectsSpecific target organ toxicity, single exposure Category 1Specific target organ toxicity, repeatedexposure Category 2Hazardous to the aquatic environment, acutehazardEnvironmental hazards Category 2Hazardous to the aquatic environment,long-term hazard Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Causes skin irritation. Causes eye irritation. May cause drowsiness or dizziness. May causegenetic defects. May cause cancer. Suspected of damaging fertility or the unborn child. Causesdamage to organs through prolonged or repeated exposure. Toxic to aquatic life. Toxic to aquaticlife with long lasting effects. Flammable aerosol. 1 / 12 Material name: Car Quest Multi-Purpose Lubricant 1020 Version #: 01 Issue date: 05-15-2015 SDS US Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do notspray on an open flame or other ignition source. Pressurized container: Do not pierce or burn,even after use. Do not breathe mist or vapor. Wash thoroughly after handling. Do not eat, drink orsmoke when using this product. Use only outdoors or in a well-ventilated area. Avoid release tothe environment. Wear protective gloves/protective clothing/eye protection/face protection. Response If on skin: Wash with plenty of water. If inhaled: Remove person to fresh air and keep comfortablefor breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses,if present and easy to do. Continue rinsing. If exposed or concerned: Get medicaladvice/attention. Call a poison center/doctor if you feel unwell. If skin irritation occurs: Get medicaladvice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminatedclothing and wash before reuse. Collect spillage. Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect fromsunlight. Do not expose to temperatures exceeding 50°C/122°F. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) Combustible. Supplemental information 69.21% of the mixture consists of component(s) of unknown acute hazards to the aquaticenvironment. 68.04% of the mixture consists of component(s) of unknown long-term hazards tothe aquatic environment. 3. Composition/information on ingredients Mixtures CAS number %Common name and synonymsChemical name 64742-52-5Distillates (petroleum),Hydrotreated Heavy Naphthenic 30 - < 40 64742-47-8Distillates (petroleum),Hydrotreated Light 30 - < 40 8052-41-3Stoddard Solvent 20 - < 30 112-34-52-(2-butoxyéthoxy) Éthanol 3 - < 5 124-38-9Carbon Dioxide 1 - < 3 25551-13-7Trimethylbenzene 1 - < 3 100-41-4ETHYLBENZENE < 1 98-82-8BENZENE,1-METHYLETHYL-< 0.3 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISONCENTER or doctor/physician if you feel unwell.Inhalation Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Getmedical advice/attention. Wash contaminated clothing before reuse.Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.Eye contact In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth. Donot induce vomiting without advice from poison control center. If vomiting occurs, keep head lowso that stomach content doesn't get into the lungs. Ingestion May cause drowsiness and dizziness. Headache. Nausea, vomiting. Diarrhea. Irritation of eyes.Exposed individuals may experience eye tearing, redness, and discomfort. Skin irritation. Maycause redness and pain. Prolonged exposure may cause chronic effects. Most important symptoms/effects, acute and delayed Provide general supportive measures and treat symptomatically. Keep victim under observation.Symptoms may be delayed.Indication of immediate medical attention and special treatment needed IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice(show the label where possible). Ensure that medical personnel are aware of the material(s)involved, and take precautions to protect themselves. Show this safety data sheet to the doctor inattendance. General information 2 / 12 Material name: Car Quest Multi-Purpose Lubricant 1020 Version #: 01 Issue date: 05-15-2015 SDS US 5. Fire-fighting measures Powder. Alcohol resistant foam. Dry chemicals. Carbon dioxide (CO2).Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing media Contents under pressure. Pressurized container may explode when exposed to heat or flame.During fire, gases hazardous to health may be formed.Specific hazards arising from the chemical Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA.Special protective equipment and precautions for firefighters Move containers from fire area if you can do so without risk. Cool containers exposed to heat with prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder ormonitor nozzles, if possible. If not, withdraw and let fire burn out. Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials. Movecontainers from fire area if you can do so without risk. In the event of fire and/or explosion do notbreathe fumes. Specific methods Combustible. Flammable aerosol.General fire hazards 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wearappropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Donot touch damaged containers or spilled material unless wearing appropriate protective clothing.Ventilate closed spaces before entering them. Local authorities should be advised if significantspillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Refer to attached safety data sheets and/or instructions for use. Keep combustibles (wood, paper,oil, etc.) away from spilled material. This material is classified as a water pollutant under the CleanWater Act and should be prevented from contaminating soil or from entering sewage and drainagesystems which lead to waterways. Stop leak if you can do so without risk. Move the cylinder to asafe and open area if the leak is irreparable. Use water spray to reduce vapors or divert vaporcloud drift. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earthand place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoiddischarge into drains, water courses or onto the ground. Inform appropriate managerial orsupervisory personnel of all environmental releases. Environmental precautions 7. Handling and storage Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spraybutton is missing or defective. Do not spray on a naked flame or any other incandescent material.Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill,grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated contact breastfeeding women must not handle this product. Should be handled in closed systems, ifpossible. Use only in well-ventilated areas. Wear appropriate personal protective equipment.Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrialhygiene practices. Precautions for safe handling Level 3 Aerosol. Store locked up. Pressurized container. Protect from sunlight and do not expose to temperaturesexceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an openflame, heat or other sources of ignition. This material can accumulate static charge which maycause spark and become an ignition source. Keep out of the reach of children. Store away fromincompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 3 / 12 Material name: Car Quest Multi-Purpose Lubricant 1020 Version #: 01 Issue date: 05-15-2015 SDS US 8. Exposure controls/personal protection Occupational exposure limits ValueComponents FormType PEL 245 mg/m3BENZENE,1-METHYLETHYL-(CAS 98-82-8) 50 ppm PEL 9000 mg/m3Carbon Dioxide (CAS124-38-9) 5000 ppm PEL 5 mg/m3 Mist.Distillates (petroleum),Hydrotreated HeavyNaphthenic (CAS64742-52-5) 2000 mg/m3 500 ppm PEL 435 mg/m3ETHYLBENZENE (CAS100-41-4) 100 ppm PEL 2900 mg/m3Stoddard Solvent (CAS8052-41-3) 500 ppm US. ACGIH Threshold Limit Values ValueComponents FormType TWA 10 ppm Inhalable fraction andvapor.2-(2-butoxyéthoxy) Éthanol(CAS 112-34-5)TWA 50 ppmBENZENE,1-METHYLETHYL-(CAS 98-82-8)STEL 30000 ppmCarbon Dioxide (CAS124-38-9)TWA 5000 ppm TWA 5 mg/m3 Inhalable fraction.Distillates (petroleum),Hydrotreated HeavyNaphthenic (CAS64742-52-5) TWA 20 ppmETHYLBENZENE (CAS100-41-4) TWA 100 ppmStoddard Solvent (CAS8052-41-3) TWA 25 ppmTrimethylbenzene (CAS25551-13-7) US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents FormType TWA 245 mg/m3BENZENE,1-METHYLETHYL-(CAS 98-82-8) 50 ppm STEL 54000 mg/m3Carbon Dioxide (CAS124-38-9) 30000 ppm TWA 9000 mg/m3 5000 ppm Ceiling 1800 mg/m3Distillates (petroleum),Hydrotreated HeavyNaphthenic (CAS64742-52-5) STEL 10 mg/m3 Mist. TWA 100 mg/m3Distillates (petroleum),Hydrotreated Light (CAS64742-47-8) STEL 545 mg/m3ETHYLBENZENE (CAS100-41-4) 125 ppm 4 / 12 Material name: Car Quest Multi-Purpose Lubricant 1020 Version #: 01 Issue date: 05-15-2015 SDS US US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents FormType TWA 435 mg/m3 100 ppm Ceiling 1800 mg/m3Stoddard Solvent (CAS8052-41-3)TWA 350 mg/m3 Biological limit values ValueComponents Determinant Specimen Sampling Time 0.15 g/g Sum ofmandelic acidandphenylglyoxylicacid Creatinine inurine *ETHYLBENZENE (CAS100-41-4) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation BENZENE,1-METHYLETHYL- (CAS 98-82-8)Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies BENZENE,1-METHYLETHYL- (CAS 98-82-8)Skin designation applies. US - Tennessee OELs: Skin designation BENZENE,1-METHYLETHYL- (CAS 98-82-8)Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation BENZENE,1-METHYLETHYL- (CAS 98-82-8)Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) BENZENE,1-METHYLETHYL- (CAS 98-82-8)Can be absorbed through the skin. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation ratesshould be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,or other engineering controls to maintain airborne levels below recommended exposure limits. Ifexposure limits have not been established, maintain airborne levels to an acceptable level. Eye Appropriate engineering controls Individual protection measures, such as personal protective equipment Chemical respirator with organic vapor cartridge and full facepiece.Eye/face protection Skin protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glovesupplier.Hand protection Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.Other Chemical respirator with organic vapor cartridge and full facepiece.Respiratory protection Wear appropriate thermal protective clothing, when necessary.Thermal hazards When using do not smoke. Always observe good personal hygiene measures, such as washingafter handling the material and before eating, drinking, and/or smoking. Routinely wash workclothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Liquid. Clear.Appearance Liquid.Physical state Aerosol.Form YellowColor PetroleumOdor Odor threshold Not available. pH Not available. Melting point/freezing point -94 °F (-70 °C) estimated Initial boiling point and boiling range 302 °F (150 °C) estimated 5 / 12 Material name: Car Quest Multi-Purpose Lubricant 1020 Version #: 01 Issue date: 05-15-2015 SDS US Flash point 142.0 °F (61.1 °C) Tag Closed Cup Evaporation rate Not available. Not applicable.Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) 0.7 % estimated Flammability limit - upper (%) 6 % estimated Explosive limit - lower (%)Not available. Explosive limit - upper (%)Not available. Vapor pressure 1.21 hPa estimated Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water)Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 410 °F (210 °C) estimated Decomposition temperature Not available. Viscosity Not available. Other information Density 7.38 lbs/gal estimated Not explosive.Explosive properties Flame extension > 26 in Flammability (flash back)No Flammability class Combustible IIIA estimated Heat of combustion (NFPA 30B) 35.23 kJ/g estimated Not oxidizing.Oxidizing properties Percent volatile 5.53 % estimated Specific gravity 0.88 estimated VOC (Weight %)23.31 % 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity Material is stable under normal conditions.Chemical stability Hazardous polymerization does not occur.Possibility of hazardous reactions Avoid temperatures exceeding the flash point. Contact with incompatible materials.Conditions to avoid Strong oxidizing agents.Incompatible materials No hazardous decomposition products are known.Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation May cause damage to organs through prolonged or repeated exposure by inhalation. May causedrowsiness and dizziness. Headache. Nausea, vomiting. Skin contact Causes skin irritation. Eye contact Causes eye irritation. Ingestion Expected to be a low ingestion hazard. Symptoms related to the physical, chemical and toxicological characteristics Headache. May cause drowsiness and dizziness. Nausea, vomiting. Diarrhea. Irritation of eyes.Exposed individuals may experience eye tearing, redness, and discomfort. Skin irritation. Maycause redness and pain. 6 / 12 Material name: Car Quest Multi-Purpose Lubricant 1020 Version #: 01 Issue date: 05-15-2015 SDS US Information on toxicological effects Narcotic effects. Test ResultsComponentsSpecies 2-(2-butoxyéthoxy) Éthanol (CAS 112-34-5) Dermal Acute LD50 Rabbit 2700 mg/kg Oral LD50 Guinea pig 2000 mg/kg Mouse 2400 mg/kg Rabbit 2200 mg/kg Rat 4500 mg/kg BENZENE,1-METHYLETHYL- (CAS 98-82-8) Inhalation Acute LC50 Mouse 2000 ppm, 7 Hours 24.7 mg/l, 2 Hours Rat 8000 ppm, 4 Hours Oral LD50 Rat 1400 mg/kg ETHYLBENZENE (CAS 100-41-4) Dermal Acute LD50 Rabbit 17800 mg/kg Oral LD50 Rat 3500 mg/kg Trimethylbenzene (CAS 25551-13-7) Oral Acute * Estimates for product may be based on additional component data not shown. LD50 Rat 8970 mg/kg Causes skin irritation.Skin corrosion/irritation Causes eye irritation.Serious eye damage/eye irritation Respiratory or skin sensitization Not a respiratory sensitizer. This product is not expected to cause skin sensitization.Skin sensitization May cause genetic defects.Germ cell mutagenicity May cause cancer. IARC Monographs. Overall Evaluation of Carcinogenicity BENZENE,1-METHYLETHYL- (CAS 98-82-8)2B Possibly carcinogenic to humans. ETHYLBENZENE (CAS 100-41-4)2B Possibly carcinogenic to humans. Stoddard Solvent (CAS 8052-41-3)3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. US. National Toxicology Program (NTP) Report on Carcinogens Distillates (petroleum), Hydrotreated Heavy Naphthenic(CAS 64742-52-5)Known To Be Human Carcinogen. Suspected of damaging fertility or the unborn child.Reproductive toxicity Specific target organ toxicity - single exposure May cause drowsiness and dizziness. 7 / 12 Material name: Car Quest Multi-Purpose Lubricant 1020 Version #: 01 Issue date: 05-15-2015 SDS US Specific target organ toxicity - repeated exposure Causes damage to organs through prolonged or repeated exposure. Aspiration hazard Not an aspiration hazard. Chronic effects Causes damage to organs through prolonged or repeated exposure. Prolonged inhalation may beharmful. Prolonged exposure may cause chronic effects. 12. Ecological information Toxic to aquatic life with long lasting effects.Ecotoxicity Components Test ResultsSpecies 2-(2-butoxyéthoxy) Éthanol (CAS 112-34-5) Aquatic LC50Fish 1300 mg/l, 96 hoursBluegill (Lepomis macrochirus) BENZENE,1-METHYLETHYL- (CAS 98-82-8) Aquatic EC50Crustacea 3.55 - 11.29 mg/l, 48 hoursBrine shrimp (Artemia sp.) LC50Fish 2.7 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss) Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8) Aquatic LC50Fish 2.9 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss) ETHYLBENZENE (CAS 100-41-4) Aquatic EC50Crustacea 1.37 - 4.4 mg/l, 48 hoursWater flea (Daphnia magna) * Estimates for product may be based on additional component data not shown. LC50Fish 7.5 - 11 mg/l, 96 hoursFathead minnow (Pimephales promelas) No data is available on the degradability of this product. Persistence and degradability Bioaccumulative potential 2-(2-butoxyéthoxy) Éthanol 0.56BENZENE,1-METHYLETHYL-3.66ETHYLBENZENE3.15Stoddard Solvent 3.16 - 7.15 No data available.Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contentsunder pressure. Do not puncture, incinerate or crush. Do not allow this material to drain intosewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or usedcontainer. Dispose of contents/container in accordance with local/regional/national/internationalregulations. Disposal instructions Dispose in accordance with all applicable regulations.Local disposal regulations The waste code should be assigned in discussion between the user, the producer and the wastedisposal company.Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain someproduct residues. This material and its container must be disposed of in a safe manner (see:Disposal instructions). Waste from residues / unused products Since emptied containers may retain product residue, follow label warnings even after container isemptied. Empty containers should be taken to an approved waste handling site for recycling ordisposal. Do not re-use empty containers. Contaminated packaging 14. Transport information DOT Not available.UN number 8 / 12 Material name: Car Quest Multi-Purpose Lubricant 1020 Version #: 01 Issue date: 05-15-2015 SDS US Comsumer CommodityUN proper shipping name ORM-DClass Transport hazard class(es) -Subsidiary risk 2.2Label(s) Not applicable.Packing group YesMarine pollutant Environmental hazards Read safety instructions, SDS and emergency procedures before handling.Special precautions for user T75, TP5Special provisions 304Packaging non bulk 314, 315Packaging bulk IATA UN1950UN number Aerosols, flammableUN proper shipping name 2Class Transport hazard class(es) -Subsidiary risk IIIPacking group YesEnvironmental hazards 9LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Allowed.Passenger and cargo aircraft Other information Allowed.Cargo aircraft only IMDG UN1950UN number Aerosols, flammableUN proper shipping name 2Class Transport hazard class(es) -Subsidiary risk Not applicable.Packing group YesMarine pollutant Environmental hazards F-D, S-UEmSRead safety instructions, SDS and emergency procedures before handling.Special precautions for user Not established.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code IATA; IMDG 9 / 12 Material name: Car Quest Multi-Purpose Lubricant 1020 Version #: 01 Issue date: 05-15-2015 SDS US Marine pollutant IMDG Regulated Marine Pollutant. DOT Regulated Marine Pollutant.General information 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) 2-(2-butoxyéthoxy) Éthanol (CAS 112-34-5)Listed.BENZENE,1-METHYLETHYL- (CAS 98-82-8)Listed. ETHYLBENZENE (CAS 100-41-4)Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - YesDelayed Hazard - YesFire Hazard - YesPressure Hazard - NoReactivity Hazard - No Hazard categories SARA 302 Extremely hazardous substance Not listed. NoSARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Chemical name CAS number % by wt. 2-(2-butoxyéthoxy) Éthanol 112-34-5 3 - < 5ETHYLBENZENE100-41-4 < 1 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List 2-(2-butoxyéthoxy) Éthanol (CAS 112-34-5) BENZENE,1-METHYLETHYL- (CAS 98-82-8) ETHYLBENZENE (CAS 100-41-4) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated.Safe Drinking Water Act (SDWA) US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) 2-(2-butoxyéthoxy) Éthanol (CAS 112-34-5)BENZENE,1-METHYLETHYL- (CAS 98-82-8) Distillates (petroleum), Hydrotreated Heavy Naphthenic (CAS 64742-52-5) Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8) ETHYLBENZENE (CAS 100-41-4) 10 / 12 Material name: Car Quest Multi-Purpose Lubricant 1020 Version #: 01 Issue date: 05-15-2015 SDS US Stoddard Solvent (CAS 8052-41-3)Trimethylbenzene (CAS 25551-13-7) US. Massachusetts RTK - Substance List BENZENE,1-METHYLETHYL- (CAS 98-82-8) Carbon Dioxide (CAS 124-38-9) Distillates (petroleum), Hydrotreated Heavy Naphthenic (CAS 64742-52-5) Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8)ETHYLBENZENE (CAS 100-41-4)Stoddard Solvent (CAS 8052-41-3)Trimethylbenzene (CAS 25551-13-7) US. New Jersey Worker and Community Right-to-Know Act 2-(2-butoxyéthoxy) Éthanol (CAS 112-34-5) BENZENE,1-METHYLETHYL- (CAS 98-82-8) Carbon Dioxide (CAS 124-38-9) Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8) ETHYLBENZENE (CAS 100-41-4) Stoddard Solvent (CAS 8052-41-3) Trimethylbenzene (CAS 25551-13-7) US. Pennsylvania Worker and Community Right-to-Know Law 2-(2-butoxyéthoxy) Éthanol (CAS 112-34-5)BENZENE,1-METHYLETHYL- (CAS 98-82-8)Carbon Dioxide (CAS 124-38-9) Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8) ETHYLBENZENE (CAS 100-41-4) Stoddard Solvent (CAS 8052-41-3) Trimethylbenzene (CAS 25551-13-7) US. Rhode Island RTK 2-(2-butoxyéthoxy) Éthanol (CAS 112-34-5)BENZENE,1-METHYLETHYL- (CAS 98-82-8)ETHYLBENZENE (CAS 100-41-4) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance BENZENE,1-METHYLETHYL- (CAS 98-82-8)Listed: April 6, 2010 ETHYLBENZENE (CAS 100-41-4)Listed: June 11, 2004 International Inventories Country(s) or region Inventory name On inventory (yes/no)* YesAustraliaAustralian Inventory of Chemical Substances (AICS) YesCanadaDomestic Substances List (DSL) NoCanadaNon-Domestic Substances List (NDSL) YesChinaInventory of Existing Chemical Substances in China (IECSC) YesEuropeEuropean Inventory of Existing Commercial ChemicalSubstances (EINECS) NoEuropeEuropean List of Notified Chemical Substances (ELINCS) NoJapanInventory of Existing and New Chemical Substances (ENCS) YesKoreaExisting Chemicals List (ECL) YesNew Zealand New Zealand Inventory YesPhilippinesPhilippine Inventory of Chemicals and Chemical Substances(PICCS) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) country(s). 16. Other information, including date of preparation or last revision 05-15-2015Issue date Version #01 11 / 12 Material name: Car Quest Multi-Purpose Lubricant 1020 Version #: 01 Issue date: 05-15-2015 SDS US The information provided in this Safety Data Sheet is correct to the best of our knowledge,information and belief at the date of its publication. The information given is designed only as aguidance for safe handling, use, processing, storage, transportation, disposal and release and isnot to be considered a warranty or quality specification. The information relates only to the specificmaterial designated and may not be valid for such material used in combination with any othermaterials or in any process, unless specified in the text. Disclaimer 12 / 12 Material name: Car Quest Multi-Purpose Lubricant 1020 Version #: 01 Issue date: 05-15-2015 SDS US Better than it has to be 1601 McCloskey Boulevard Hookers Point - Tampa, Florida 33605 U.S.A. E-MAIL: info@amalie.com www.amalie.com Compounding Blending Blow Molding Packaging 815852082 Safety data sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Page 1/9 Revision: 2/01/2015 1 Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: CARQUEST SAE 5W-20 · Application of the substance / the preparation Product Component · 1.3 Details of the supplier of the Safety Data Sheet · Manufacturer/Supplier: CARQUEST MADE IN USA · 1.4 Emergency telephone number: ChemTel Inc. (800)255-3924, +1 (813)248-0585 2 Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 The product is not classified according to the CLP regulation. · Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable. · Information concerning particular hazards for human and environment: The product does not have to be labeled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. · Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. The classification is in accordance with the latest editions of international substances lists, and is supplemented by information from technical literature and by information provided by the company. · 2.2 Label elements · Labeling according to Regulation (EC) No 1272/2008 N/A · Hazard pictograms N/A · Signal word N/A · Hazard statements N/A · Hazard description: · WHMIS-symbols: Not hazardous under WHMIS. (Contd. on page 2) Page 2/9 Safety data sheet according to 1907/2006/EC (REACH), Revision: 02/01/2015 Trade name: CARQUEST SAE 5W-20 · HMIS Long Term Health Hazard Substances None of the ingredients is listed. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. (Contd. of page 1) 3 Composition/information on ingredients · 3.2 Mixtures · Description: Mixture of substances listed below with nonhazardous additions. Dangerous components: EINECS: 265-157-1 Index number: 649-467-00-8 substance with a Community workplace exposure limit Carc. Cat. 2 EINECS: 265-169-7 Carc. Cat. 2 26% · Additional information: Note L: The classification as a carcinogen need not apply if it can be shown that the substance contains less than 3 % DMSO extract as measured by IP 346 ‘Determination of polycyclic aromatics in unused lubricating base oils and asphaltene free petroleum fractions - Dimethyl sulphoxide extraction refractive index method’, Institute of Petroleum, London. This product meets these requirements. For the wording of the listed risk phrases refer to section 16. 4 First aid measures · 4.1 Description of first aid measures · General information: No special measures required. · After inhalation: Supply fresh air; consult doctor in case of complaints. · After skin contact: Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. · After eye contact: Remove contact lenses if worn. Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting; call for medical help immediately. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. (Contd. on page 3) Page 3/9 Safety data sheet according to 1907/2006/EC (REACH), Revision: 02/01/2015 Trade name: CARQUEST SAE 5W-20 · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. (Contd. of page 2) 5 Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents: Carbon dioxide Water haze or fog Foam Fire-extinguishing powder · For safety reasons unsuitable extinguishing agents: W ater with full jet · 5.2 Special hazards arising from the substance or mixture In case of fire, the following can be released: Carbon monoxide (CO) Under certain fire conditions, traces of other toxic gases cannot be excluded. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit. 6 Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water. Prevent from spreading (e.g. by damming-in or oil barriers). · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Send for recovery or disposal in suitable receptacles. Do not flush with water or aqueous cleansing agents · 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage · 7.1 Precautions for safe handling Avoid the formation of oil haze. · Information about fire - and explosion protection: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: No special requirements. (Contd. on page 4) Page 4/9 Safety data sheet according to 1907/2006/EC (REACH), Revision: 02/01/2015 Trade name: CARQUEST SAE 5W-20 · Information about storage in one common storage facility: Store away from foodstuffs. Store away from oxidizing agents. (Contd. of page 3) · Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. · 7.3 Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection · Additional information about design of technical facilities: No further data; see item 7. · 8.1 Control parameters Ingredients with limit values that require monitoring at the workplace: 64742-54-7 Distillates (petroleum), hydrotreated heavy paraffinic TLV (USA) Short-term value: 10 mg/m³ Long-term value: 5 mg/m³ · Additional information: The lists valid during the making were used as basis. · 8.2 Exposure controls · Personal protective equipment: · General protective and hygienic measures: The usual precautionary measures are to be adhered to when handling chemicals. Keep away from foodstuffs, beverages and feed. Avoid contact with the eyes. · Respiratory protection: Not necessary if room is well-ventilated. Use suitable respiratory protective device in case of insufficient ventilation. · Protection of hands: Protective gloves Oil resistant gloves · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. · Eye protection: Safety glasses Goggles recommended during refilling (Contd. on page 5) Page 5/9 Safety data sheet according to 1907/2006/EC (REACH), Revision: 02/01/2015 Trade name: CARQUEST SAE 5W-20 (Contd. of page 4) 9 Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Oily Colour: Amber coloured · Odour: Characteristic · Odour threshold: Not determined. · pH-value: Not determined. · Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: Undetermined. · Flash point: 200°C (392°F) · Flammability (solid, gaseous): Not applicable. · Ignition temperature: Not determined. · Decomposition temperature: Not determined. · Self-igniting: Product is not self-igniting. · Danger of explosion: Product does not present an explosion hazard. · Explosion limits: Lower: Not determined. Upper: Not determined. · Vapour pressure: Not determined. · Density at 20°C: 0,86 g/cm³ · Relative density Not determined. · Vapour density Not determined. · Evaporation rate Not determined. · Solubility in / Miscibility with water: Not miscible or difficult to mix. · Partition coefficient (n-octanol/water): > 2,0 log POW (Estimate) · Viscosity: Viscosity Index: 140 Kinematic at 40°C: 50 cSt (8,5 cSt @ 100°C) · Solvent content: Organic solvents: 0,0 % · 9.2 Other information No further relevant information available. (Contd. on page 6) Page 6/9 Safety data sheet according to 1907/2006/EC (REACH), Revision: 02/01/2015 Trade name: CARQUEST SAE 5W-20 (Contd. of page 5) 10 Stability and reactivity · 10.1 Reactivity · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications. · 10.3 Possibility of hazardous reactions Reacts with strong oxidizing agents. · 10.4 Conditions to avoid Store away from oxidizing agents. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: Carbon monoxide and carbon dioxide Possible in traces. Sulphur oxides (SOx) Nitrogen oxides (NOx) 11 Toxicological information · 11.1 Information on toxicological effects · Acute toxicity: LD/LC50 values relevant for classification: · Primary irritant effect: · on the skin: Slight irritant effect on skin and mucous membranes. · on the eye: Slight irritant effect on eyes. · Sensitization: Sensitizing effect by skin contact is possible by prolonged exposure. · Additional toxicological information: The product is not subject to classification according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version. When used and handled according to specifications, the product does not have any harmful effects to our experience and the information provided to us. 12 Ecological information · 12.1 Toxicity · Aquatic toxicity: The material is harmful to the environment. · 12.2 Persistence and degradability Not easily biodegradable · 12.3 Bioaccumulative potential May be accumulated in organism · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water Danger to drinking water if even small quantities leak into the ground. Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. (Contd. on page 7) Page 7/9 Safety data sheet according to 1907/2006/EC (REACH), Revision: 02/01/2015 Trade name: CARQUEST SAE 5W-20 · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. (Contd. of page 6) 13 Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. Can be reused after reprocessing. Delivery of waste oil to officially authorized collectors only. · Uncleaned packaging: · Recommendation: Disposal must be made according to official regulations. 14 Transport information · 14.1 UN-Number · DOT, ADN, IMDG, IATA N/A · 14.2 UN proper shipping name · DOT, ADR, ADN, IMDG, IATA N/A · 14.3 Transport hazard class(es) · DOT, ADR, ADN, IMDG, IATA · Class N/A · 14.4 Packing group · DOT, ADR, IMDG, IATA N/A · 14.5 Environmental hazards: · Marine pollutant: No · 14.6 Special precautions for user Not applicable. · 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · UN "Model Regulation": - (Contd. on page 8) Page 8/9 Safety data sheet according to 1907/2006/EC (REACH), Revision: 02/01/2015 Trade name: CARQUEST SAE 5W-20 (Contd. of page 7) 15 Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · United States (USA) · SARA Section 355 (extremely hazardous substances): · Section 313 (Specific toxic chemical listings): · TSCA (Toxic Substances Control Act): · Proposition 65 (California): Chemicals known to cause cancer: · Chemicals known to cause reproductive toxicity for females: · Chemicals known to cause reproductive toxicity for males: · Chemicals known to cause developmental toxicity: · Carcinogenic Categories EPA (Environmental Protection Agency) · IARC (International Agency for Research on Cancer) TLV (Threshold Limit Value established by ACGIH) · MAK (German Maximum Workplace Concentration) · NIOSH-Ca (National Institute for Occupational Safety and Health) · OSHA-Ca (Occupational Safety & Health Administration) · Canada Canadian Domestic Substances List (DSL) · Canadian Ingredient Disclosure list (limit 0.1%) (Contd. on page 9) Page 9/9 Safety data sheet according to 1907/2006/EC (REACH), Revision: 02/01/2015 Trade name: CARQUEST SAE 5W-20 · Canadian Ingredient Disclosure list (limit 1%) None of the ingredients is listed. (Contd. of page 8) · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labeling of Chemicals ACGIH: American Conference of Governmental Industrial Hygienists LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent · Sources The manufacturer believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. No warranty of fitness, warranty of merchantability or any other warranty, expressed or implied, is made concerning the information provided herein. The information provided herein relates only to the specific product designated and may not be valid where such product is used in combination with any other materials or process. Further, since the conditions and methods of use of this product and of the information referred to herein are beyond the control of the manufacturer, the manufacturer expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information. This document was authored and reviewed by the technical and scientific staff at Chem Tel Inc. Descriptions, classifications and calculations are based upon data provided by manufacturer and augmented by published data in conjunction with expert analysis by degreed scientists. SDS Prepared by: ChemTel Inc. 1305 North Florida Avenue Tampa, Florida USA 33602-2902 Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573 Website: www.chemtelinc.com AOCUSA  1601 McCloskey Boulevard Tampa, Florida 33605 U.S.A. E-MAIL: Telephone: (813)248-1988 Fax: (813) 248-1488 847403282 Page 1/9 Safety data sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Revision: 07.17.2015 1 Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: FRAM PREMIUM HYDRAULIC AW 32 · Application of the substance / the preparation Lubricating Oils · 1.3 Details of the supplier of the Safety Data Sheet · Manufacturer/Supplier: AOCUSA Made in U.S.A. · 1.4 Emergency telephone number: ChemTel Inc. (800)255-3924, +1 (813)248-0585 2 Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 The product is not classified according to the CLP regulation. · Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable. · Information concerning particular hazards for human and environment: The product does not have to be labeled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. · Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. The classification is in accordance with the latest editions of international s ubstances lists, and is supplemented by information from technical literature and by information provided by the company. · 2.2 Label elements · Labeling according to Regulation (EC) No 1272/2008 N/A · Hazard pictograms N/A · Signal word N/A · Hazard statements N/A · Hazard description: · WHMIS-symbols: Not hazardous under WHMIS. (Contd. on page 2) Page 2/9 Safety data sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Trade name: FRAM PREMIUM HYDRAULIC AW 32 · HMIS Long Term Health Hazard Substances None of the ingredients is listed. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. (Contd. of page 1) 3 Composition/information on ingredients · 3.2 Mixtures · Description: Mixture of substances listed below with nonhazardous additions. · Dangerous components: CAS: 64742-54-7 EINECS: 265-157-1 Index number: 649-467-00-8 Distillates (petroleum), hydrotreated heavy paraffinic substance with a Community workplace exposure limit Carc. Cat. 2 99% · Additional information: Note L: The classification as a carcinogen need not apply if it can be shown that the substance contains less than 3 % DMSO extract as measured by IP 346 ‘Determination of polycyclic aromatics in unused lubricating base oils and asphaltene free petroleum fractions - Dimethyl sulphoxide extraction refractive index method’, Institute of Petroleum, London. This product meets these requirements. For the wording of the listed risk phrases refer to section 16. 4 First aid measures · 4.1 Description of first aid measures · General information: No special measures required. · After inhalation: Supply fresh air; consult doctor in case of complaints. · After skin contact: Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. · After eye contact: Remove contact lenses if worn. Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting; call for medical help immediately. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. (Contd. on page 3) Page 3/9 Safety data sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Trade name: FRAM PREMIUM HYDRAULIC AW 32 (Contd. of page 2) 5 Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents: Carbon dioxide Water haze or fog Foam Fire-extinguishing powder · For safety reasons unsuitable extinguishing agents: Water with full jet · 5.2 Special hazards arising from the substance or mixture Sulphur dioxide (SO2) Nitrogen oxides (NOx) Carbon monoxide (CO) · 5.3 Advice for firefighters · Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit. 6 Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation · 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water. Prevent from spreading (e.g. by damming-in or oil barriers). · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Send for recovery or disposal in suitable receptacles. Do not flush with water or aqueous cleansing agents · 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage · 7.1 Precautions for safe handling Avoid the formation of oil haze. · Information about fire - and explosion protection: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: No special requirements. · Information about storage in one common storage facility: Store away from oxidizing agents. · Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. (Contd. on page 4) Page 4/9 Safety data sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Trade name: FRAM PREMIUM HYDRAULIC AW 32 · 7.3 Specific end use(s) No further relevant information available. (Contd. of page 3) 8 Exposure controls/personal protection · Additional information about design of technical facilities: No further data; see item 7. · 8.1 Control parameters · Ingredients with limit values that require monitoring at the workplace: 64742-54-7 Distillates (petroleum), hydrotreated heavy paraffinic PEL (USA) TLV (USA) 5 mg/m³ Short-term value: 10 mg/m³ Long-term value: 5 mg/m³ · Additional information: The lists valid during the making were used as basis. · 8.2 Exposure controls · Personal protective equipment: · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing The usual precautionary measures are to be adhered to when handling chemicals. · Respiratory protection: Not necessary if room is well-ventilated. Use suitable respiratory protective device in case of insufficient ventilation. · Protection of hands: Protective gloves Oil resistant gloves · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. · Eye protection: Safety glasses Goggles recommended during refilling · Body protection: Protective work clothing (Contd. on page 5) Page 5/9 Safety data sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Trade name: FRAM PREMIUM HYDRAULIC AW 32 (Contd. of page 4) 9 Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Oily Colour: Amber coloured · Odour: Characteristic · Odour threshold: Not determined. · pH-value: Not determined. · Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: Undetermined. · Flash point: 200°C (392°F) · Flammability (solid, gaseous): Not applicable. · Ignition temperature: Decomposition temperature: Not determined. · Self-igniting: Product is not self-igniting. · Danger of explosion: Product does not present an explosion hazard. · Explosion limits: Lower: Not determined. Upper: Not determined. · Vapour pressure: Not determined. · Density at 20°C: 0,87 g/cm³ · Relative density Not determined. · Vapour density Not determined. · Evaporation rate Not determined. · Solubility in / Miscibility with water: Not miscible or difficult to mix. · Partition coefficient (n-octanol/water): > 2,0 log POW (Estimate) · Viscosity: Viscosity Index: 100 Kinematic at 40°C: 32 cSt (5,5 @ 100°C) · Solvent content: Organic solvents: 0,0 % · 9.2 Other information No further relevant information available. (Contd. on page 6) Page 6/9 Safety data sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Trade name: FRAM PREMIUM HYDRAULIC AW 32 (Contd. of page 5) 10 Stability and reactivity · 10.1 Reactivity · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions Reacts with strong oxidizing agents. · 10.4 Conditions to avoid Store away from oxidizing agents. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: Carbon monoxide and carbon dioxide Possible in traces. Sulphur oxides (SOx) Nitrogen oxides (NOx) 11 Toxicological information · 11.1 Information on toxicological effects · Acute toxicity: · LD/LC50 values relevant for classification: Oral Dermal LD50 LD50 >2000 mg/kg (rat) >2000 mg/kg (rabbit) · Primary irritant effect: · on the skin: Slight irritant effect on skin and mucous membranes. · on the eye: Slight irritant effect on eyes. · Sensitization: Sensitizing effect by skin contact is possible by prolonged exposure. · Additional toxicological information: The product is not subject to classification according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version. When used and handled according to specifications, the product does not have any harmful effects to our experience and the information provided to us. 12 Ecological information · 12.1 Toxicity · Aquatic toxicity: The material is harmful to the environment. · 12.2 Persistence and degradability Not easily biodegradable · 12.3 Bioaccumulative potential May be accumulated in organism · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water Danger to drinking water if even small quantities leak into the ground. Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. (Contd. on page 7) Page 7/9 Safety data sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Trade name: FRAM PREMIUM HYDRAULIC AW 32 · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. (Contd. of page 6) 13 Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. Can be reused after reprocessing. Delivery of waste oil to officially authorized collectors only. · Uncleaned packaging: · Recommendation: Disposal must be made according to official regulations. 14 Transport information · 14.1 UN-Number · DOT, ADN, IMDG, IATA N/A · 14.2 UN proper shipping name · DOT, ADR, ADN, IMDG, IATA N/A · 14.3 Transport hazard class(es) · DOT, ADR, ADN, IMDG, IATA · Class N/A · 14.4 Packing group · DOT, ADR, IMDG, IATA N/A · 14.5 Environmental hazards: · Marine pollutant: No · 14.6 Special precautions for user Not applicable. · 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · UN "Model Regulation": - (Contd. on page 8) Page 8/9 Safety data sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Trade name: FRAM PREMIUM HYDRAULIC AW 32 (Contd. of page 7) 15 Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · United States (USA) · SARA · Section 355 (extremely hazardous substances): None of the ingredients is listed. · Section 313 (Specific toxic chemical listings): None of the ingredients is listed. · TSCA (Toxic Substances Control Act): All ingredients are listed. · Proposition 65 (California): · Chemicals known to cause cancer: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Carcinogenic Categories · EPA (Environmental Protection Agency) None of the ingredients is listed. · IARC (International Agency for Research on Cancer) None of the ingredients is listed. · TLV (Threshold Limit Value established by ACGIH) None of the ingredients is listed. · MAK (German Maximum Workplace Concentration) None of the ingredients is listed. · NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. · Canada · Canadian Domestic Substances List (DSL) All ingredients are listed. · Canadian Ingredient Disclosure list (limit 0.1%) None of the ingredients is listed. (Contd. on page 9) Page 9/9 Safety data sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Trade name: FRAM PREMIUM HYDRAULIC AW 32 · Canadian Ingredient Disclosure list (limit 1%) None of the ingredients is listed. (Contd. of page 8) · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labeling of Chemicals ACGIH: American Conference of Governmental Industrial Hygienists LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent The manufacturer believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. No warranty of fitness, warranty of merchantability or any other warranty, expressed or implied, is made concerning the information provided herein. The information provided herein relates only to the specific product designated and may not be valid where such product is used in combination with any other materials or process. Further, since the conditions and methods of use of this product and of the information referred to herein are beyond the control of the manufacturer, the manufacturer expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information. This document was authored and reviewed by the technical and scientific staff at ChemTel Inc. Descriptions, classifications and calculations are bas ed upon data provided by manufacturer and augmented by published data in conjunction with expert analysis by degreed scientists. SDS Prepared by: ChemTel Inc. 1305 North Florida Avenue Tampa, Florida USA 33602-2902 Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573 Website: www.chemtelinc.com                    Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Page: 1/9   Revision: 20 March 2021   SECTION 1: Identification of the substance/mixture and of the company/ undertaking  ꞏ 1.1 Product identifier  ꞏ Trade name: FRAM POWER STEERING FLUID ꞏ CAS number: 64742-54-7 ꞏ EC number: 265-157-1 ꞏ Index number: 649-467-00-8 ꞏ Registration number: 01-2119484627-25-XXXX ꞏ 1.2 Relevant identified uses of the substance or mixture and uses advised against ꞏ Application of the substance / the mixture: Lubricant ꞏ Uses advised against: No further relevant information available. ꞏ 1.3 Details of the supplier of the Safety Data Sheet ꞏ Manufacturer/Supplier:  1601 McCloskey Boulevard Tampa, FL 33605 Phone: 813-248-1988 Technical or Further Information: 1-800-368-1264 ꞏ 1.4 Emergency telephone number: ChemTel Inc. (800)255-3924 (North America) +1 (813)248-0585 (International)     SECTION 2: Hazards identification  ꞏ 2.1 Classification of the substance or mixture ꞏ Classification according to Regulation (EC) No 1272/2008 The product is not classified as hazardous according to the Globally Harmonized System (GHS). The product is not classified as hazardous according to OSHA GHS regulations within the United States. The substance is not classified as hazardous according to the CLP regulation.   ꞏ 2.2 Label elements ꞏ Labelling according to Regulation (EC) No 1272/2008       (Cont'd. on page 2)           Page: 2 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Revision: 20 March 2021     Trade name:FRAM POWER STEERING FLUID     (Cont'd. from page 1) The product is not classified as hazardous according to OSHA GHS regulations within the United States. The product is not classified as hazardous according to the CLP regulation. ꞏ Hazard pictograms None. ꞏ Signal word Not Regulated ꞏ Hazard statements None ꞏ Precautionary statements None. ꞏ 2.3 Other hazards There are no other hazards not otherwise classified that have been identified. ꞏ Results of PBT and vPvB assessment ꞏ PBT: Not applicable. ꞏ vPvB: Not applicable.     SECTION 3: Composition/information on ingredients  ꞏ 3.1 Substances ꞏ CAS No. Description 64742-54-7 distillates (petroleum), hydrotreated heavy paraffinic ꞏ Identification number(s) ꞏ EC number: 265-157-1 ꞏ Index number: 649-467-00-8 ꞏ Additional information: Note L: The classification as a carcinogen need not apply if it can be shown that the substance contains less than 3 % DMSO extract as measured by IP 346 ‘Determination of polycyclic aromatics in unused lubricating base oils and asphaltene free petroleum fractions - Dimethyl sulphoxide extraction refractive index method’, Institute of Petroleum, London. This product meets these requirements.     SECTION 4: First aid measures  ꞏ 4.1 Description of first aid measures ꞏ After inhalation: Supply fresh air; consult doctor in case of complaints. ꞏ After skin contact: Immediately wash with water and soap and rinse thoroughly. If skin irritation is experienced, consult a doctor. ꞏ After eye contact: Remove contact lenses if worn. Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. ꞏ After swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting; call for medical help immediately. ꞏ 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. ꞏ 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available.     SECTION 5: Firefighting measures    (Cont'd. on page 3)                 46.1.7 Page: 3 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Revision: 20 March 2021     Trade name: FRAM POWER STEERING FLUID        ꞏ 5.1 Extinguishing media ꞏ Suitable extinguishing agents: Water haze or fog Foam Fire-extinguishing powder Carbon dioxide ꞏ For safety reasons unsuitable extinguishing agents: Water with full jet ꞏ 5.2 Special hazards arising from the substance or mixture In case of fire, the following can be released: Carbon monoxide (CO) Under certain fire conditions, traces of other toxic gases cannot be excluded. ꞏ 5.3 Advice for firefighters ꞏ Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit. (Cont'd. from page 2)     SECTION 6: Accidental release measures  ꞏ 6.1 Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation Wear protective equipment. Keep unprotected persons away. ꞏ 6.2 Environmental precautions Do not allow to enter sewers/ surface or ground water. Prevent from spreading (e.g. by damming-in or oil barriers). ꞏ 6.3 Methods and material for containment and cleaning up Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Send for recovery or disposal in suitable receptacles. Do not flush with water or aqueous cleansing agents Dispose of the material collected according to regulations. ꞏ 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.     SECTION 7: Handling and storage  ꞏ 7.1 Precautions for safe handling Avoid the formation of oil haze. Open and handle receptacle with care. ꞏ Information about fire - and explosion protection: No special measures required. ꞏ 7.2 Conditions for safe storage, including any incompatibilities ꞏ Requirements to be met by storerooms and receptacles: Store in cool, dry conditions in well sealed receptacles. ꞏ Information about storage in one common storage facility: Store away from foodstuffs. Store away from oxidising agents.                             (Cont'd. on page 4)           Page: 4 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Revision: 20 March 2021       46.1.7 Page: 5 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Revision: 20 March 2021     Trade name: FRAM POWER STEERING FLUID      Store away from water. ꞏ 7.3 Specific end use(s) No further relevant information available. (Cont'd. from page 3)     SECTION 8: Exposure controls/personal protection  ꞏ 8.1 Control parameters ꞏ Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. ꞏ 8.2 Exposure controls ꞏ General protective and hygienic measures: The usual precautionary measures are to be adhered to when handling chemicals. Keep away from foodstuffs, beverages and feed. Avoid contact with the eyes. ꞏ Respiratory protection: Not required under normal conditions of use. Use suitable respiratory protective device when aerosol or mist is formed. ꞏ Protection of hands:   Protective gloves Oil resistant gloves ꞏ Eye protection:   Safety glasses Goggles recommended during refilling ꞏ Body protection: Not required under normal conditions of use. ꞏ Limitation and supervision of exposure into the environment: No special requirements. ꞏ Risk management measures: No special requirements.     SECTION 9: Physical and chemical properties  ꞏ 9.1 Information on basic physical and chemical properties ꞏ Appearance Form: Oily Colour: Clear ꞏ Odour: Mild ꞏ Odour threshold: Not determined.  ꞏ pH-value: Not determined. ꞏ Melting point/freezing point: Not determined. ꞏ Initial boiling point and boiling range: >350 °C (>662 °F)  ꞏ Flash point: >200 °C (>392 °F)                               (Cont'd. on page 5)           Page: 6 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Revision: 20 March 2021       46.1.7 Page: 7 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Revision: 20 March 2021     Trade name: FRAM POWER STEERING FLUID     (Cont'd. from page 4)  ꞏ Flammability (solid, gas): Not applicable. ꞏ Auto/Self-ignition temperature: Not determined. ꞏ Decomposition temperature: Not determined. ꞏ Explosive properties: Product does not present an explosion hazard. ꞏ Explosion limits Lower: Not determined. Upper: Not determined. ꞏ Oxidising properties Not determined. ꞏ Vapour pressure: Not determined. ꞏ Density at 20 °C (68 °F): 0,90 ± 0,05 g/cm³ (7,51 lbs/gal) ꞏ Relative density: Not determined. ꞏ Vapour density: Not determined. ꞏ Evaporation rate: Not determined. ꞏ Solubility in / Miscibility with water: Not miscible or difficult to mix. ꞏ Partition coefficient: n-octanol/water: Not determined. ꞏ Viscosity Dynamic at 40 °C (104 °F): 37 cSt Kinematic: Not determined. ꞏ 9.2 Other information No further relevant information available.     SECTION 10: Stability and reactivity  ꞏ 10.1 Reactivity No further relevant information available. ꞏ 10.2 Chemical stability Stable under normal temperatures and pressures. ꞏ Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications. ꞏ 10.3 Possibility of hazardous reactions Reacts with strong oxidising agents. ꞏ 10.4 Conditions to avoid Store away from oxidising agents. ꞏ 10.5 Incompatible materials No further relevant information available. ꞏ 10.6 Hazardous decomposition products Carbon monoxide and carbon dioxide Hydrocarbons Possible in traces: Nitrogen oxides (NOx) Sulphur oxides (SOx)     SECTION 11: Toxicological information  ꞏ 11.1 Information on toxicological effects        (Cont'd. on page 6)                 46.1.7 Page: 8 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Revision: 20 March 2021     Trade name: FRAM POWER STEERING FLUID      ꞏ Acute toxicity: Based on available data, the classification criteria are not met. ꞏ LD/LC50 values relevant for classification: None. ꞏ Primary irritant effect ꞏ Skin corrosion/irritation: Based on available data, the classification criteria are not met. (Cont'd. from page 5) ꞏ Serious eye damage/irritation: Based on available data, the classification criteria are not met. ꞏ Respiratory or skin sensitisation: Based on available data, the classification criteria are not met.  ꞏ IARC (Inte national Agency fo Resea ch on Cance ): 71-43-2 benzene 1 ꞏ Probable routes of exposure: Ingestion. Inhalation. Eye contact. Skin contact. ꞏ Germ cell mutagenicity: Based on available data, the classification criteria are not met. ꞏ Carcinogenicity: Based on available data, the classification criteria are not met. ꞏ Reproductive toxicity: Based on available data, the classification criteria are not met. ꞏ STOT-single exposure: Based on available data, the classification criteria are not met. ꞏ STOT-repeated exposure: Based on available data, the classification criteria are not met. ꞏ Aspiration hazard: Based on available data, the classification criteria are not met.     SECTION 12: Ecological information  ꞏ 12.1 Toxicity ꞏ Aquatic toxicity: No further relevant information available. ꞏ 12.2 Persistence and degradability Not easily biodegradable. ꞏ 12.3 Bioaccumulative potential May be accumulated in organism ꞏ 12.4 Mobility in soil No further relevant information available. ꞏ Additional ecological information: ꞏ General notes: Avoid release to the environment. ꞏ 12.5 Results of PBT and vPvB assessment ꞏ PBT: Not applicable. ꞏ vPvB: Not applicable. ꞏ 12.6 Other adverse effects No further relevant information available.     SECTION 13: Disposal considerations  ꞏ 13.1 Waste treatment methods ꞏ Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. Can be reused after reprocessing. Delivery of waste oil to officially authorized collectors only. The user of this material has the responsibility to dispose of unused material, residues and containers in compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and disposal for hazardous and nonhazardous wastes. ꞏ Uncleaned packaging: (Cont'd. on page 7)             Page: 9 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Revision: 20 March 2021     46.1.7 Page: 10 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Revision: 20 March 2021     Trade name: FRAM POWER STEERING FLUID      ꞏ Recommendation: Disposal must be made according to official regulations. (Cont'd. from page 6)     SECTION 14: Transport information   ꞏ 14.1 UN-Number ꞏ DOT, ADR, IMDG, IATA Not Regulated ꞏ 14.2 UN proper shipping name ꞏ DOT, ADR, IMDG, IATA Not Regulated ꞏ 14.3 Transport hazard class(es)  ꞏ DOT, ADR, IMDG, IATA ꞏ Class Not Regulated ꞏ 14.4 Packing group ꞏ DOT, ADR, IMDG, IATA Not Regulated ꞏ 14.5 Environmental hazards: ꞏ Marine pollutant: No ꞏ 14.6 Special precautions for user Not applicable. ꞏ 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable.     SECTION 15: Regulatory information  ꞏ 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture ꞏ United States (USA) ꞏ SARA  ꞏ Section 355 (ext emely haza dous substances): Substance is not listed. ꞏ Section 313 (Specific toxic chemical listings): Substance is not listed. ꞏ TSCA (Toxic Substances Control Act): Substance is listed. ꞏ Proposition 65 (California):  W ARNING: This product can expose you to chemicals including benzene, which is known to the State of California to cause cancer and birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov.  ꞏ EPA (Environmental Protection Agency) Substance is not listed. (Cont'd. on page 8)               Page: 11 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Revision: 20 March 2021     46.1.7 Page: 12 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Revision: 20 March 2021     Trade name: FRAM POWER STEERING FLUID     (Cont'd. from page 7)  ꞏ IARC (Inte national Agency fo Resea ch on Cance ) 71-43-2 benzene 1 ꞏ NIOSH-Ca (National Institute for Occupational Safety and Health) 71-43-2 benzene ꞏ Canadian Domestic Substances List (DSL) Substance is listed. ꞏ Directive 2012/18/EU ꞏ Named dangerous substances - ANNEX I Substance is not listed. ꞏ Other regulations, limitations and prohibitive regulations ꞏ Substances of very high concern (SVHC) according to REACH, Article 57 Substance is not listed.  ꞏ 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.     SECTION 16: Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. ꞏ Abbreviations and acronyms: ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistant, Bio-accumulable, Toxic SVHC: Substances of Very High Concern vPvB: very Persistent and very Bioaccumulative ꞏ Sources Website, European Chemicals Agency (echa.europa.eu) W ebsite, US EPA Substance Registry Services (ofmpub.epa.gov/sor internet/registry/substreg/home/ overview/home.do) Website, Chemical Abstracts Registry, American Chemical Society (www.cas.org) Patty's Industrial Hygiene, 6th ed., Rose, Vernon, ed. ISBN: 978-0-470-07488-6 Casarett and Doull's Toxicology: The Basic Science of Poisons, 8th Ed., Klaasen, Curtis D., ed., ISBN: 978-0-07-176923-5. Safety Data Sheets, Individual Manufacturers The manufacturer believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. No warranty of fitness, warranty of merchantability or any other warranty, expressed or implied, is made concerning the information provided herein. The information provided herein relates only to the specific product designated and may not be valid where such product is used in combination with any other materials or process. Further, since the conditions and methods of use of this product and of the information referred to herein are beyond the control of the manufacturer, the manufacturer expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information. (Cont'd. on page 9)               46.1.7 Page: 13 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Revision: 20 March 2021     Trade name: FRAM POWER STEERING FLUID        SDS Prepared by: ChemTel Inc. 1305 North Florida Avenue Tampa, Florida USA 33602-2902 Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573 Website: www.chemtelinc.com (Cont'd. from page 8)                                                                                                               Page: 14 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Revision: 20 March 2021     46.1.7 Gorilla Spray Adhesive SDS Page 1 of 19 Safety Data Sheet – Gorilla Spray Adhesive Date Revised: 11/01/2019 Date Issued: 02/28/2017 Version 1.1 FOR CHEMICAL EMERGENCY DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186 According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations. SECTION 1: IDENTIFICATION Product Identifier Product Form: Mixture Product Name: Gorilla Spray Adhesive Intended Use of the Product Adhesive. Name, Address, and Telephone of the Responsible Party Company The Gorilla Glue Company 2101 E. Kemper Road Cincinnati, Ohio 45241 513-271-3300 www.gorillatough.com Emergency Telephone Number Emergency Number : 1-800-420-7186 (Prosar) SECTION 2: HAZARDS IDENTIFICATION Classification of the Substance or Mixture GHS-US Classification Simple Asphy Flam. Aerosol 1 H222 Liquefied gas H280 Skin Irrit. 2 H315 Eye Irrit. 2A H319 STOT SE 3 H336 Full text of hazard classes and H-statements : see section 16 Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) : GHS02 GHS04 GHS07 GHS08 Signal Word (GHS-US) : Danger Hazard Statements (GHS-US) : May displace oxygen and cause rapid suffocation. H222 - Extremely flammable aerosol. H280 - Contains gas under pressure; may explode if heated. H315 - Causes skin irritation. H319 - Causes serious eye irritation. H336 - May cause drowsiness or dizziness. Precautionary Statements (GHS-US) : P210 - Keep away from extremely high or low temperatures, ignition sources, and incompatible materials. - No smoking. P211 - Do not spray on an open flame or other ignition source. P251 - Pressurized container: Do not pierce or burn, even after use. P261 - Avoid breathing vapors, mist, or spray. P264 - Wash hands, forearms, and other exposed areas thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P273 - Avoid release to the environment. P280 - Wear protective gloves, protective clothing, and eye protection. Gorilla Spray Adhesive SDS Page 2 of 19 Safety Data Sheet – Gorilla Spray Adhesive Date Revised: 11/01/2019 Date Issued: 02/28/2017 Version 1.1 FOR CHEMICAL EMERGENCY DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186 According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations. P302+P352 - If on skin: Wash with plenty of water. P304+P340 - If inhaled: Remove person to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 - Call a poison center or doctor if you feel unwell. P321 - Specific treatment (see section 4 on this SDS). P332+P313 - If skin irritation occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P362+P364 - Take off contaminated clothing and wash it before reuse. P391 - Collect spillage. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P405 - Store locked up. P410+P403 - Protect from sunlight. Store in a well-ventilated place. P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. P501 - Dispose of contents/container in accordance with local, regional, national, and international regulations. Other Hazards Exposure may aggravate pre-existing eye, skin, or respiratory conditions. Contact with gas escaping the container can cause frostbite. Unknown Acute Toxicity (GHS-US) No data available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Substance Not applicable Mixture Name Product Identifier % GHS-US classification Methyl acetate (CAS No) 79-20-9 15-40 Flam. Liq. 2, H225 Eye Irrit. 2A, H319 STOT SE 3, H336 Cyclohexane (CAS No) 110-82-7 5-15 Flam. Liq. 2, H225 Skin Irrit. 2, H315 STOT SE 3, H336 Asp. Tox. 1, H304 Acetone (CAS No) 67-64-1 5-15 Flam. Liq. 2, H225 Eye Irrit. 2A, H319 STOT SE 3, H336 1,1-Difluoroethane (CAS No) 75-37-6 5-15 Simple Asphy Flam. Gas 1, H220 Liquefied gas, H280 Dimethyl ether (CAS No) 115-10-6 5-15 Simple Asphy Flam. Gas 1, H220 Liquefied gas, H280 Petroleum hydrocarbon resin (CAS No) Proprietary 5-15 Eye Irrit. 2B, H320 Gorilla Spray Adhesive SDS Page 3 of 19 Safety Data Sheet – Gorilla Spray Adhesive Date Revised: 11/01/2019 Date Issued: 02/28/2017 Version 1.1 FOR CHEMICAL EMERGENCY DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186 According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations. Propane (CAS No) 74-98-6 1-5 Simple Asphy Flam. Gas 1, H220 Liquefied gas, H280 Butane (CAS No) 106-97-8 1-5 Simple Asphy Flam. Gas 1, H220 Liquefied gas, H280 Acetaldehyde (CAS No) 75-07-0 <0.1 Flam. Liq. 1, H224 Acute Tox. 4 (Oral), H302 Eye Irrit. 2A, H319 Carc. 2, H351 STOT SE 3, H335 Methyl alcohol (CAS No) 67-56-1 <0.1 Flam. Liq. 2, H225 Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation:vapor), H331 STOT SE 1, H370 Acetic acid (CAS No) 64-19-7 <0.1 Flam. Liq. 3, H226 Skin Corr. 1A, H314 Eye Dam. 1, H318 Benzene (CAS No) 71-43-2 <0.001 Flam. Liq. 2, H225 Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Muta. 1B, H340 Carc. 1A, H350 STOT RE 1, H372 Asp. Tox. 1, H304 Naphthalene (CAS No) 91-20-3 < 0.001 Flam. Sol. 2, H228 Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Carc. 2, H351 Full text of H-phrases: see section 16 SECTION 4: FIRST AID MEASURES Description of First-aid Measures First-aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). If frostbite or freezing occurs, immediately flush with plenty of lukewarm water to GENTLY warm the affected area. Do not use hot water. Do not rub affected area. Get immediate medical attention. First-aid Measures After Inhalation: First, take proper precautions to ensure your own safety before attempting rescue (e.g. wear appropriate respiratory protective equipment, use the buddy system), then remove the exposed person to fresh air. Keep at rest in a position comfortable for breathing. Obtain medical attention if breathing difficulty persists. First-aid Measures After Skin Contact: Remove contaminated clothing. Drench affected area with water for at least 15 minutes. Obtain medical attention if irritation develops or persists. Thaw frosted parts with lukewarm water. Do not rub affected area. Get immediate medical advice/attention. First-aid Measures After Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention. If frostbite or freezing occurs, immediately flush with plenty of lukewarm water to GENTLY warm the affected area. Do not use hot water. Do not rub affected area. Get immediate medical attention. Gorilla Spray Adhesive SDS Page 4 of 19 Safety Data Sheet – Gorilla Spray Adhesive Date Revised: 11/01/2019 Date Issued: 02/28/2017 Version 1.1 FOR CHEMICAL EMERGENCY DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186 According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations. First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Obtain medical attention. Most Important Symptoms and Effects Both Acute and Delayed Symptoms/Injuries: May cause frostbite on contact with the liquid. Causes serious eye irritation. Causes skin irritation. May cause drowsiness and dizziness. Asphyxia by lack of oxygen: risk of death. Symptoms/Injuries After Inhalation: High concentrations may cause central nervous system depression such as dizziness, vomiting, numbness, drowsiness, headache, and similar narcotic symptoms. In elevated concentrations may cause asphyxiation, central nervous system effects, and increased breathing rate. Symptoms of asphyxiation include headache, dizziness, rapid breathing, increased pulse, mood changes, tremors, cyanosis, muscular weakness, narcosis, numbness of the extremities, unconsciousness and death. Symptoms/Injuries After Skin Contact: Redness, pain, swelling, itching, burning, dryness, and dermatitis. Contact with gas/liquid escaping the container can cause frostbite and freeze burns. Symptoms/Injuries After Eye Contact: Contact causes severe irritation with redness and swelling of the conjunctiva. Contact with gas/liquid escaping the container can cause frostbite, freeze burns, and permanent eye damage. Symptoms/Injuries After Ingestion: Not considered a potential route of exposure, but contact with gas/liquid escaping the container can cause freeze burns and frostbite. Chronic Symptoms: None known. Indication of Any Immediate Medical Attention and Special Treatment Needed If exposed or concerned, get medical advice and attention. If medical advice is needed, have product container or label at hand. SECTION 5: FIRE-FIGHTING MEASURES Extinguishing Media Special Hazards Arising From the Substance or Mixture Advice for Firefighters Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Firefighting Instructions: Remove containers from fire area if this can be done without risk. Use water spray or fog for cooling exposed containers. Do not get water inside containers. Do not apply water stream directly at source of leak. DO NOT fight fire when fire reaches containers. Evacuate area. Fight fire remotely due to the risk of explosion. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Hazardous Combustion Products: Thermal decomposition generates: Carbon oxides (CO, CO2). Nitrogen oxides. Aliphatic fragments. Hydrocarbons. Fluorinated hydrocarbons. Methanol. Formaldehyde. hydrofluoric acid. Phosgene. Fluorine compounds. Aldehydes. Ketones. Irritating fumes. Other Information: Do not allow run-off from fire fighting to enter drains or water courses. SECTION 6: ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep away from heat, hot surfaces, sparks, open flames, and other ignition sources. No smoking. Do not get in eyes, on skin, or on clothing. Do not breathe vapors, gas. For Non-Emergency Personnel Protective Equipment: Use appropriate personal protective equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel. Stop leak if safe to do so. For Emergency Personnel Protective Equipment: Equip cleanup crew with proper protection. Suitable Extinguishing Media: Use fire extinguisher with class B rating. Carbon dioxide, dry chemical. Sand. Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire. Fire Hazard: Flammable aerosol. Explosion Hazard: Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. Container may explode in heat of fire. Reactivity: Reacts violently with strong oxidizers. Increased risk of fire or explosion. Hazardous reactions may occur on contact with certain chemicals. Refer to incompatible materials. Gorilla Spray Adhesive SDS Page 5 of 19 Safety Data Sheet – Gorilla Spray Adhesive Date Revised: 11/01/2019 Date Issued: 02/28/2017 Version 1.1 FOR CHEMICAL EMERGENCY DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186 According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations. Emergency Procedures: Ventilate area. Eliminate ignition sources. Evacuate unnecessary personnel, isolate, and ventilate area. Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods, protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit. Environmental Precautions Prevent entry to sewers and public waters. Avoid release to the environment. Collect spillage. Methods and Materials for Containment and Cleaning Up For Containment: Stop leak, if possible without risk. As an immediate precautionary measure, isolate spill or leak area in all directions. Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Eliminate all ignition sources. Stop the source of the release, if safe to do so. Consider the use of water spray to disperse vapors. Isolate the area until gas has dispersed. Ventilate and gas test area before entering. Absorb and/or contain spill with inert material. Use only non-sparking tools. Transfer spilled material to a suitable container for disposal. Contact competent authorities after a spill. Reference to Other Sections See Section 8 for exposure controls and personal protection and Section 13 for disposal considerations. SECTION 7: HANDLING AND STORAGE Precautions for Safe Handling Additional Hazards When Processed: Pressurized container: may burst if heated. Do not pierce or burn, even after use. Do not pressurize, cut, or weld containers. Ruptured cylinders may rocket. Asphyxiating gas at high concentrations. Contact with the liquefied gas may cause frostbite. Precautions for Safe Handling: Do not handle until all safety precautions have been read and understood. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Do not spray on an open flame or other ignition source. Avoid contact with eyes, skin and clothing. Do not breathe gas. Use appropriate personal protective equipment (PPE). Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Comply with applicable regulations. Proper grounding procedures to avoid static electricity should be followed. Storage Conditions: Store in a dry, cool and well-ventilated place. Keep only in the original container in a cool, well ventilated place away from ignition sources. Keep/Store away from direct sunlight, extremely high or low temperatures and incompatible materials. Protect from sunlight. Do not expose to temperatures exceeding 50°C/ 122°F. Keep in fireproof place. Incompatible Materials: Strong acids, strong bases, strong oxidizers. Concentrated Oxygen. Acid anhydrides. Powdered metals. Alkalis. Alkali earth metals. Nitric acid. Sulfuric acid. Potassium permanganate. Halogenated compounds. Attacks some forms of plastics, rubber, and coatings. Specific End Use(s) No use is specified. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Control Parameters For substances listed in section 3 that are not listed here, there are no established exposure limits from the manufacturer, supplier, importer, or the appropriate advisory agency including: ACGIH (TLV), AIHA (WEEL), NIOSH (REL), or OSHA (PEL). Dimethyl ether (115-10-6) USA AIHA WEEL TWA (ppm) 1000 ppm 1,1-Difluoroethane (75-37-6) USA AIHA WEEL TWA (ppm) 1000 ppm Propane (74-98-6) USA NIOSH NIOSH REL (TWA) (mg/m³) 1800 mg/m³ USA NIOSH NIOSH REL (TWA) (ppm) 1000 ppm USA IDLH US IDLH (ppm) 2100 ppm (10% LEL) Gorilla Spray Adhesive SDS Page 6 of 19 Safety Data Sheet – Gorilla Spray Adhesive Date Revised: 11/01/2019 Date Issued: 02/28/2017 Version 1.1 FOR CHEMICAL EMERGENCY DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186 According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations. USA OSHA OSHA PEL (TWA) (mg/m³) 1800 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm Butane (106-97-8) USA ACGIH ACGIH STEL (ppm) 1000 ppm USA NIOSH NIOSH REL (TWA) (mg/m³) 1900 mg/m³ USA NIOSH NIOSH REL (TWA) (ppm) 800 ppm Cyclohexane (110-82-7) USA ACGIH ACGIH TWA (ppm) 100 ppm USA NIOSH NIOSH REL (TWA) (mg/m³) 1050 mg/m³ USA NIOSH NIOSH REL (TWA) (ppm) 300 ppm USA IDLH US IDLH (ppm) 1300 ppm (10% LEL) USA OSHA OSHA PEL (TWA) (mg/m³) 1050 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 300 ppm Benzene (71-43-2) USA ACGIH ACGIH TWA (ppm) 0.5 ppm USA ACGIH ACGIH STEL (ppm) 2.5 ppm USA ACGIH ACGIH chemical category Skin - potential significant contribution to overall exposure by the cutaneous route,Confirmed Human Carcinogen USA ACGIH Biological Exposure Indices (BEI) 25 µg/g Kreatinin Parameter: S-Phenylmercapturic acid - Medium: urine - Sampling time: end of shift (background) 500 µg/g Kreatinin Parameter: t,t-Muconic acid - Medium: urine - Sampling time: end of shift (background) USA NIOSH NIOSH REL (TWA) (ppm) 0.1 ppm USA NIOSH NIOSH REL (STEL) (ppm) 1 ppm USA IDLH US IDLH (ppm) 500 ppm USA OSHA OSHA PEL (TWA) (ppm) 10 ppm 1 ppm USA OSHA OSHA PEL (STEL) (ppm) 5 ppm (see 29 CFR 1910.1028) USA OSHA OSHA PEL (Ceiling) (ppm) 25 ppm Methyl acetate (79-20-9) USA ACGIH ACGIH TWA (ppm) 200 ppm USA ACGIH ACGIH STEL (ppm) 250 ppm USA NIOSH NIOSH REL (TWA) (mg/m³) 610 mg/m³ USA NIOSH NIOSH REL (TWA) (ppm) 200 ppm USA NIOSH NIOSH REL (STEL) (mg/m³) 760 mg/m³ USA NIOSH NIOSH REL (STEL) (ppm) 250 ppm USA IDLH US IDLH (ppm) 3100 ppm (10% LEL) USA OSHA OSHA PEL (TWA) (mg/m³) 610 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 200 ppm Acetaldehyde (75-07-0) USA ACGIH ACGIH Ceiling (ppm) 25 ppm USA ACGIH ACGIH chemical category Suspected Human Carcinogen USA IDLH US IDLH (ppm) 2000 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 360 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 200 ppm Gorilla Spray Adhesive SDS Page 7 of 19 Safety Data Sheet – Gorilla Spray Adhesive Date Revised: 11/01/2019 Date Issued: 02/28/2017 Version 1.1 FOR CHEMICAL EMERGENCY DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186 According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations. Methyl alcohol (67-56-1) USA ACGIH ACGIH TWA (ppm) 200 ppm USA ACGIH ACGIH STEL (ppm) 250 ppm USA ACGIH ACGIH chemical category Skin - potential significant contribution to overall exposure by the cutaneous route USA ACGIH Biological Exposure Indices (BEI) 15 mg/l Parameter: Methanol - Medium: urine - Sampling time: end of shift (background, nonspecific) USA NIOSH NIOSH REL (TWA) (mg/m³) 260 mg/m³ USA NIOSH NIOSH REL (TWA) (ppm) 200 ppm USA NIOSH NIOSH REL (STEL) (mg/m³) 325 mg/m³ USA NIOSH NIOSH REL (STEL) (ppm) 250 ppm USA IDLH US IDLH (ppm) 6000 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 260 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 200 ppm Acetic acid (64-19-7) USA ACGIH ACGIH TWA (ppm) 10 ppm USA ACGIH ACGIH STEL (ppm) 15 ppm USA NIOSH NIOSH REL (TWA) (mg/m³) 25 mg/m³ USA NIOSH NIOSH REL (TWA) (ppm) 10 ppm USA NIOSH NIOSH REL (STEL) (mg/m³) 37 mg/m³ USA NIOSH NIOSH REL (STEL) (ppm) 15 ppm USA IDLH US IDLH (ppm) 50 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 25 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 10 ppm Acetone (67-64-1) USA ACGIH ACGIH TWA (ppm) 250 ppm USA ACGIH ACGIH STEL (ppm) 500 ppm USA ACGIH ACGIH chemical category Not Classifiable as a Human Carcinogen USA ACGIH Biological Exposure Indices (BEI) 25 mg/l Parameter: Acetone - Medium: urine - Sampling time: end of shift (nonspecific) USA NIOSH NIOSH REL (TWA) (mg/m³) 590 mg/m³ USA NIOSH NIOSH REL (TWA) (ppm) 250 ppm USA IDLH US IDLH (ppm) 2500 ppm (10% LEL) USA OSHA OSHA PEL (TWA) (mg/m³) 2400 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm Naphthalene (91-20-3) USA ACGIH ACGIH TWA (ppm) 10 ppm USA ACGIH ACGIH chemical category Skin - potential significant contribution to overall exposure by the cutaneous route, Confirmed Animal Carcinogen with Unknown Relevance to Humans USA ACGIH Biological Exposure Indices (BEI) Parameter: 1-Naphthol with hydrolysis plus 2-Naphthol with hydrolysis - Sampling time: end of shift (nonquantitative, nonspecific) USA NIOSH NIOSH REL (TWA) (mg/m³) 50 mg/m³ USA NIOSH NIOSH REL (TWA) (ppm) 10 ppm USA NIOSH NIOSH REL (STEL) (mg/m³) 75 mg/m³ Gorilla Spray Adhesive SDS Page 8 of 19 Safety Data Sheet – Gorilla Spray Adhesive Date Revised: 11/01/2019 Date Issued: 02/28/2017 Version 1.1 FOR CHEMICAL EMERGENCY DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186 According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations. USA NIOSH NIOSH REL (STEL) (ppm) 15 ppm USA IDLH US IDLH (ppm) 250 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 50 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 10 ppm Particulates not otherwise classified (PNOC) (Not applicable) USA ACGIH ACGIH TWA (mg/m³) 3 mg/m3 Respirable fraction 10 mg/m3 Total Dust USA OSHA OSHA PEL (TWA) (mg/m³) 5 mg/m3 Respirable fraction 15 mg/m3 Total Dust Exposure Controls Appropriate Engineering Controls : Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure adequate ventilation, especially in confined areas. Gas detectors should be used when flammable gases or vapors may be released. Oxygen detectors should be used when asphyxiating gases may be released. Proper grounding procedures to avoid static electricity should be followed. Use explosion-proof equipment. Ensure all national/local regulations are observed. Personal Protective Equipment : Gloves. Protective clothing. Protective goggles. Insufficient ventilation: wear respiratory protection. Respiratory protection of the dependent type. Materials for Protective Clothing : Chemically resistant materials and fabrics. Wear fire/flame resistant/retardant clothing. Hand Protection : Wear protective gloves. If material is cold, wear thermally resistant protective gloves. Eye Protection : Chemical safety goggles. Skin and Body Protection : Wear suitable protective clothing. Respiratory Protection : Use a NIOSH-approved self-contained breathing apparatus whenever exposure may exceed established Occupational Exposure Limits. Thermal Hazard Protection : Wear thermally resistant protective clothing. Environmental Exposure Controls : Avoid release to the environment. Other Information : When using, do not eat, drink or smoke. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Information on Basic Physical and Chemical Properties Physical State : Gas Appearance : No data available Odor : No data available Odor Threshold : No data available pH : No data available Evaporation Rate : No data available Melting Point : No data available Freezing Point : No data available Boiling Point : 57.6 °C (135.68 °F) estimated Flash Point : -104.4 °C (-155.92 °F) Propellant - estimated Gorilla Spray Adhesive SDS Page 9 of 19 Safety Data Sheet – Gorilla Spray Adhesive Date Revised: 11/01/2019 Date Issued: 02/28/2017 Version 1.1 FOR CHEMICAL EMERGENCY DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186 According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations. Auto-ignition Temperature : No data available Decomposition Temperature : No data available Flammability (solid, gas) : No data available Vapor Pressure : No data available Relative Vapor Density at 20°C : No data available Relative Density : No data available Specific Gravity : 0.72 Solubility : No data available Partition Coefficient: N-Octanol/Water : No data available Viscosity : No data available Explosive Properties : Contains gas under pressure; may explode if heated. Lower Flammable Limit : 3 % Upper Flammable Limit : 14.8 % Other Information Gas Group : Liquefied gas Flame projection : 24 in. with Flash Back of 2 in. Concentrate Viscosity : 75-225 cPs SECTION 10: STABILITY AND REACTIVITY Reactivity: Reacts violently with strong oxidizers. Increased risk of fire or explosion. Hazardous reactions may occur on contact with certain chemicals. Refer to incompatible materials. Chemical Stability: Flammable aerosol. Pressurized container: may burst if heated. Possibility of Hazardous Reactions: Hazardous polymerization will not occur. Conditions to Avoid: Direct sunlight, extremely high or low temperatures, heat, hot surfaces, sparks, open flames, incompatible materials, and other ignition sources. Incompatible Materials: Strong acids, strong bases, strong oxidizers. Concentrated Oxygen. Acid anhydrides. Powdered metals. Alkalis. Alkaline earth metals. Nitric acid. Sulfuric acid. Potassium permanganate. Halogenated compounds. Attacks some forms of plastics, rubber, and coatings. Hazardous Decomposition Products: Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: TOXICOLOGICAL INFORMATION Information on Toxicological Effects Acute Toxicity: Not classified Dimethyl ether (115-10-6) LC50 Inhalation Rat 308 mg/l/4h Propane (74-98-6) LC50 Inhalation Rat 658 mg/l/4h Butane (106-97-8) LC50 Inhalation Rat 30957 mg/m³ (Exposure time: 4 h) Cyclohexane (110-82-7) LD50 Oral Rat 12705 mg/kg LD50 Dermal Rabbit > 2000 mg/kg LC50 Inhalation Rat 13.9 mg/l/4h Benzene (71-43-2) LD50 Oral Rat 810 mg/kg Gorilla Spray Adhesive SDS Page 10 of 19 Safety Data Sheet – Gorilla Spray Adhesive Date Revised: 11/01/2019 Date Issued: 02/28/2017 Version 1.1 FOR CHEMICAL EMERGENCY DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186 According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations. LD50 Dermal Rabbit > 8200 mg/kg LC50 Inhalation Rat 44.66 mg/l/4h Methyl acetate (79-20-9) LD50 Oral Rat > 5 g/kg LD50 Dermal Rabbit > 5 g/kg LC50 Inhalation Rat 16000 ppm/4h Acetaldehyde (75-07-0) LD50 Oral Rat 660 mg/kg LC50 Inhalation Rat 24 mg/l/4h LC50 Inhalation Rat 13000 ppm/4h Methyl alcohol (67-56-1) LC50 Inhalation Rat 3 mg/l/4h LC50 Inhalation Rat 22500 ppm (Exposure time: 8 h) ATE (Oral) 100.00 mg/kg body weight ATE (Dermal) 300.00 mg/kg body weight Acetic acid (64-19-7) LD50 Oral Rat 3310 mg/kg Acetone (67-64-1) LD50 Oral Rat 5800 mg/kg LD50 Dermal Rabbit 15688 mg/kg LC50 Inhalation Rat 44 g/m³ LC50 Inhalation Rat 75.8 mg/l/4h Naphthalene (91-20-3) LD50 Oral Rat 533 - 710 mg/kg LD50 Dermal Rat 1120 mg/kg LC50 Inhalation Rat > 340 mg/m³ (Exposure time: 1 h) Skin Corrosion/Irritation: Causes skin irritation. Serious Eye Damage/Irritation: Causes serious eye irritation. Respiratory or Skin Sensitization: Not classified Germ Cell Mutagenicity: Not classified Carcinogenicity: Not classified Benzene (71-43-2) IARC group 1 National Toxicology Program (NTP) Status Evidence of Carcinogenicity, Known Human Carcinogens. OSHA Hazard Communication Carcinogen List In OSHA Hazard Communication Carcinogen list. OSHA Specifically Regulated Carcinogen List In OSHA Specifically Regulated Carcinogen list. Acetaldehyde (75-07-0) IARC group 1, 2B National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen. OSHA Hazard Communication Carcinogen List In OSHA Hazard Communication Carcinogen list. Naphthalene (91-20-3) IARC group 2B National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen. OSHA Hazard Communication Carcinogen List In OSHA Hazard Communication Carcinogen list. Gorilla Spray Adhesive SDS Page 11 of 19 Safety Data Sheet – Gorilla Spray Adhesive Date Revised: 11/01/2019 Date Issued: 02/28/2017 Version 1.1 FOR CHEMICAL EMERGENCY DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186 According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations. Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): May cause drowsiness or dizziness. Specific Target Organ Toxicity (Repeated Exposure): Not classified Aspiration Hazard: Not classified Symptoms/Injuries After Inhalation: High concentrations may cause central nervous system depression such as dizziness, vomiting, numbness, drowsiness, headache, and similar narcotic symptoms. In elevated concentrations may cause asphyxiation, central nervous system effects, and increased breathing rate. Symptoms of asphyxiation include headache, dizziness, rapid breathing, increased pulse, mood changes, tremors, cyanosis, muscular weakness, narcosis, numbness of the extremities, unconsciousness and death. Symptoms/Injuries After Skin Contact: Redness, pain, swelling, itching, burning, dryness, and dermatitis. Contact with gas/liquid escaping the container can cause frostbite and freeze burns. Symptoms/Injuries After Eye Contact: Contact causes severe irritation with redness and swelling of the conjunctiva. Contact with gas/liquid escaping the container can cause frostbite, freeze burns, and permanent eye damage. Symptoms/Injuries After Ingestion: Not considered a potential route of exposure, but contact with gas/liquid escaping the container can cause freeze burns and frostbite. Chronic Symptoms: None known. SECTION 12: ECOLOGICAL INFORMATION Toxicity Ecology - General : Toxic to aquatic life. Toxic to aquatic life with long lasting effects. 1,1-Difluoroethane (75-37-6) LC50 Fish 1 733 mg/l EC50 Daphnia 1 720 mg/l ErC50 (Algae) 419 mg/l Cyclohexane (110-82-7) LC50 Fish 1 3.96 - 5.18 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) EC50 Daphnia 1 0.9 mg/l LC50 Fish 2 23.03 - 42.07 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) Benzene (71-43-2) LC50 Fish 1 10.7 - 14.7 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) EC50 Daphnia 1 8.76 - 15.6 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static]) LC50 Fish 2 5.3 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through]) EC50 Daphnia 2 10 mg/l (Exposure time: 48 h - Species: Daphnia magna) Methyl acetate (79-20-9) LC50 Fish 1 295 - 348 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) EC50 Daphnia 1 1026.7 mg/l (Exposure time: 48 h - Species: Daphnia magna) LC50 Fish 2 250 - 350 mg/l (Exposure time: 96 h - Species: Brachydanio rerio [static]) Acetaldehyde (75-07-0) LC50 Fish 1 28 (28.0 - 34.0) mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow- through]) EC50 Daphnia 1 3.64 (3.64 - 6.15) mg/l (Exposure time: 48 h - Species: Daphnia magna [Static]) LC50 Fish 2 53 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static]) EC50 Daphnia 2 48.3 mg/l (Exposure time: 48 h - Species: Daphnia magna) Methyl alcohol (67-56-1) LC50 Fish 1 28200 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) EC50 Daphnia 1 1340 mg/l Gorilla Spray Adhesive SDS Page 12 of 19 Safety Data Sheet – Gorilla Spray Adhesive Date Revised: 11/01/2019 Date Issued: 02/28/2017 Version 1.1 FOR CHEMICAL EMERGENCY DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186 According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations. LC50 Fish 2 > 100 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) Acetic acid (64-19-7) LC50 Fish 1 79 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) EC50 Daphnia 1 65 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static]) LC50 Fish 2 75 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static]) Acetone (67-64-1) LC50 Fish 1 4144.846 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss) EC50 Daphnia 1 1679.66 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static]) LC50 Fish 2 6210 (6210 - 8120) mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) EC50 Daphnia 2 12600 (12600 - 12700) mg/l (Exposure time: 48 h - Species: Daphnia magna) Naphthalene (91-20-3) LC50 Fish 1 5.74 - 6.44 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) EC50 Daphnia 1 2.16 mg/l (Exposure time: 48 h - Species: Daphnia magna) LC50 Fish 2 1.6 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through]) EC50 Daphnia 2 1.96 mg/l (Exposure time: 48 h - Species: Daphnia magna [Flow through]) Persistence and Degradability Gorilla Spray Adhesive Persistence and Degradability May cause long-term adverse effects in the environment. Acetone (67-64-1) Persistence and Degradability Readily biodegradable in water. Bioaccumulative Potential Gorilla Spray Adhesive Bioaccumulative Potential Not established. Dimethyl ether (115-10-6) Log Pow -0.18 Propane (74-98-6) Log Pow 2.3 Butane (106-97-8) Log Pow 2.89 Cyclohexane (110-82-7) Log Pow 3.44 Benzene (71-43-2) BCF Fish 1 3.5 - 4.4 Log Pow 2.1 Methyl acetate (79-20-9) Log Pow 0.18 Acetaldehyde (75-07-0) Log Pow 0.5 Methyl alcohol (67-56-1) BCF Fish 1 < 10 Log Pow -0.77 Acetic acid (64-19-7) Log Pow -0.31 (at 20 °C) Gorilla Spray Adhesive SDS Page 13 of 19 Safety Data Sheet – Gorilla Spray Adhesive Date Revised: 11/01/2019 Date Issued: 02/28/2017 Version 1.1 FOR CHEMICAL EMERGENCY DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186 According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations. Acetone (67-64-1) BCF Fish 1 0.69 Log Pow -0.24 Log Kow -0.24 Naphthalene (91-20-3) BCF Fish 1 30 - 430 Log Pow 3.6 Mobility in Soil No additional information available Other Adverse Effects Other Information : Avoid release to the environment. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste Treatment Methods Waste Disposal Recommendations: Dispose of contents/container in accordance with local, regional, national, and international regulations. Do not pierce or burn, even after use. Additional Information: Container may remain hazardous when empty. Continue to observe all precautions. Do not puncture or incinerate container. Ecology - Waste Materials: Avoid release to the environment. This material is hazardous to the aquatic environment. Keep out of sewers and waterways. SECTION 14: TRANSPORT INFORMATION The shipping description(s) stated herein were prepared in accordance with certain assumptions at the time the SDS was authored, and can vary based on a number of variables that may or may not have been known at the time the SDS was issued. In Accordance with DOT Proper Shipping Name : AEROSOLS flammable, (each not exceeding 1 L capacity) Hazard Class : 2.1 Identification Number : UN1950 Label Codes : 2.1 Marine Pollutant : Marine pollutant ERG Number Other Information : : 126 A marine pollutant designation is not required when shipped in a single package or combination packaging containing inner packaging with contents of 5L or less. Otherwise, the above descriptions apply. In Accordance with IMDG Proper Shipping Name : AEROSOLS flammable, (each not exceeding 1 L capacity) Hazard Class : 2 Division : 2.1 Identification Number : UN1950 Label Codes : 2.1 EmS-No. (Fire) : F-D EmS-No. (Spillage) : S-U Marine Pollutant Additional Information : : Marine pollutant This product, when in compliance with IMDG Code 37-14, section 2.10.2.7, is not subject to any other provisions of the IMDG code relevant to marine pollutants. For inclusion in another hazard class all provisions of the IMDG code relevant to any additional hazards continue to apply. Gorilla Spray Adhesive SDS Page 14 of 19 Safety Data Sheet – Gorilla Spray Adhesive Date Revised: 11/01/2019 Date Issued: 02/28/2017 Version 1.1 FOR CHEMICAL EMERGENCY DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186 According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations. In Accordance with IATA Proper Shipping Name : AEROSOLS, flammable, (each not exceeding 1 L capacity) Identification Number : UN1950 Hazard Class : 2 Label Codes : 2.1 Division : 2.1 ERG Code (IATA) : 10L SECTION 15: REGULATORY INFORMATION US Federal Regulations Gorilla Spray Adhesive SARA Section 311/312 Hazard Classes Fire hazard Sudden release of pressure hazard Immediate (acute) health hazard Dimethyl ether (115-10-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory 1,1-Difluoroethane (75-37-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory Propane (74-98-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory Butane (106-97-8) Listed on the United States TSCA (Toxic Substances Control Act) inventory Cyclohexane (110-82-7) Listed on the United States TSCA (Toxic Substances Control Act) inventory Subject to reporting requirements of United States SARA Section 313 CERCLA RQ 1000 lb SARA Section 313 - Emission Reporting 1.0 % Benzene (71-43-2) Listed on the United States TSCA (Toxic Substances Control Act) inventory Subject to reporting requirements of United States SARA Section 313 CERCLA RQ 10 lb SARA Section 313 - Emission Reporting 0.1 % Methyl acetate (79-20-9) Listed on the United States TSCA (Toxic Substances Control Act) inventory Acetaldehyde (75-07-0) Listed on the United States TSCA (Toxic Substances Control Act) inventory Subject to reporting requirements of United States SARA Section 313 EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA CERCLA RQ 1000 lb SARA Section 313 - Emission Reporting 0.1 % Methyl alcohol (67-56-1) Listed on the United States TSCA (Toxic Substances Control Act) inventory Subject to reporting requirements of United States SARA Section 313 CERCLA RQ 5000 lb Gorilla Spray Adhesive SDS Page 15 of 19 Safety Data Sheet – Gorilla Spray Adhesive Date Revised: 11/01/2019 Date Issued: 02/28/2017 Version 1.1 FOR CHEMICAL EMERGENCY DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186 According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations. SARA Section 313 - Emission Reporting 1.0 % Acetic acid (64-19-7) Listed on the United States TSCA (Toxic Substances Control Act) inventory CERCLA RQ 5000 lb Acetone (67-64-1) Listed on the United States TSCA (Toxic Substances Control Act) inventory CERCLA RQ 5000 lb Benzene, ethenyl-, polymer with 1-methyl-4-(1-methylethenyl)cyclohexene (64536-06-7) Listed on the United States TSCA (Toxic Substances Control Act) inventory EPA TSCA Regulatory Flag XU - XU - indicates a substance exempt from reporting under the Inventory Update Reporting Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(C)) Naphthalene (91-20-3) Listed on the United States TSCA (Toxic Substances Control Act) inventory Subject to reporting requirements of United States SARA Section 313 CERCLA RQ 100 lb SARA Section 313 - Emission Reporting 0.1 % Benzene, 1,3-diethenyl-, polymer with 1,3-butadiene and ethenylbenzene (26471-45-4) Listed on the United States TSCA (Toxic Substances Control Act) inventory EPA TSCA Regulatory Flag XU - XU - indicates a substance exempt from reporting under the Inventory Update Reporting Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(C)) US State Regulations Benzene (71-43-2) U.S. - California - Proposition 65 - Carcinogens List WARNING: This product contains chemicals known to the State of California to cause cancer. U.S. - California - Proposition 65 - Developmental Toxicity WARNING: This product contains chemicals known to the State of California to cause birth defects. U.S. - California - Proposition 65 - Reproductive Toxicity - Male WARNING: This product contains chemicals known to the State of California to cause (Male) reproductive harm. Acetaldehyde (75-07-0) U.S. - California - Proposition 65 - Carcinogens List WARNING: This product contains chemicals known to the State of California to cause cancer. Methyl alcohol (67-56-1) U.S. - California - Proposition 65 - Developmental Toxicity WARNING: This product contains chemicals known to the State of California to cause birth defects. Naphthalene (91-20-3) U.S. - California - Proposition 65 - Carcinogens List WARNING: This product contains chemicals known to the State of California to cause cancer. Dimethyl ether (115-10-6) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List 1,1-Difluoroethane (75-37-6) Gorilla Spray Adhesive SDS Page 16 of 19 Safety Data Sheet – Gorilla Spray Adhesive Date Revised: 11/01/2019 Date Issued: 02/28/2017 Version 1.1 FOR CHEMICAL EMERGENCY DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186 According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations. U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List Propane (74-98-6) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Butane (106-97-8) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Cyclohexane (110-82-7) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List Benzene (71-43-2) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) - Special Hazardous Substances U.S. - Pennsylvania - RTK (Right to Know) List Methyl acetate (79-20-9) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Acetaldehyde (75-07-0) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List Methyl alcohol (67-56-1) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List Acetic acid (64-19-7) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List Acetone (67-64-1) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List Naphthalene (91-20-3) Gorilla Spray Adhesive SDS Page 17 of 19 Safety Data Sheet – Gorilla Spray Adhesive Date Revised: 11/01/2019 Date Issued: 02/28/2017 Version 1.1 FOR CHEMICAL EMERGENCY DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186 According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations. U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200 NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. NFPA fire hazard : 4 - Will rapidly or completely vaporize at normal pressure and temperature, or is readily dispersed in air and will burn readily. NFPA reactivity : 1 - Normally stable, but can become unstable at elevated temperatures and pressures or may react with water with some release of energy, but not violently. GHS Full Text Phrases: ------ Acute Tox. 3 (Dermal) Acute toxicity (dermal) Category 3 ------ Acute Tox. 3 (Inhalation:vapor) Acute toxicity (inhalation:vapor) Category 3 ------ Acute Tox. 3 (Oral) Acute toxicity (oral) Category 3 ------ Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category 4 ------ Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4 ------ Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category 1 ------ Aquatic Acute 2 Hazardous to the aquatic environment - Acute Hazard Category 2 ------ Aquatic Acute 3 Hazardous to the aquatic environment - Acute Hazard Category 3 ------ Aquatic Chronic 1 Hazardous to the aquatic environment - Chronic Hazard Category 1 ------ Aquatic Chronic 2 Hazardous to the aquatic environment - Chronic Hazard Category 2 ------ Aquatic Chronic 3 Hazardous to the aquatic environment - Chronic Hazard Category 3 ------ Asp. Tox. 1 Aspiration hazard Category 1 ------ Carc. 1A Carcinogenicity Category 1A ------ Carc. 2 Carcinogenicity Category 2 ------ Comb. Dust Combustible Dust ------ Eye Dam. 1 Serious eye damage/eye irritation Category 1 ------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A ------ Eye Irrit. 2B Serious eye damage/eye irritation Category 2B ------ Flam. Aerosol 1 Flammable aerosol Category 1 ------ Flam. Gas 1 Flammable gases Category 1 ------ Flam. Liq. 1 Flammable liquids Category 1 ------ Flam. Liq. 2 Flammable liquids Category 2 ------ Flam. Liq. 3 Flammable liquids Category 3 ------ Flam. Sol. 2 Flammable solids Category 2 ------ Liquefied gas Gases under pressure Liquefied gas ------ Muta. 1B Germ cell mutagenicity Category 1B Gorilla Spray Adhesive SDS Page 18 of 19 Safety Data Sheet – Gorilla Spray Adhesive Date Revised: 11/01/2019 Date Issued: 02/28/2017 Version 1.1 FOR CHEMICAL EMERGENCY DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186 According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations. ------ Simple Asphy Simple Asphyxiant ------ Skin Corr. 1A Skin corrosion/irritation Category 1A ------ Skin Irrit. 2 Skin corrosion/irritation Category 2 ------ STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1 ------ STOT SE 1 Specific target organ toxicity (single exposure) Category 1 ------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3 ------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3 ------ H220 Extremely flammable gas ------ H222 Extremely flammable aerosol ------ H224 Extremely flammable liquid and vapor ------ H225 Highly flammable liquid and vapor ------ H226 Flammable liquid and vapor ------ H228 Flammable solid ------ H280 Contains gas under pressure; may explode if heated ------ H301 Toxic if swallowed ------ H302 Harmful if swallowed ------ H304 May be fatal if swallowed and enters airways ------ H311 Toxic in contact with skin ------ H312 Harmful in contact with skin ------ H314 Causes severe skin burns and eye damage ------ H315 Causes skin irritation ------ H318 Causes serious eye damage ------ H319 Causes serious eye irritation ------ H320 Causes eye irritation ------ H331 Toxic if inhaled ------ H335 May cause respiratory irritation ------ H336 May cause drowsiness or dizziness ------ H340 May cause genetic defects ------ H350 May cause cancer ------ H351 Suspected of causing cancer ------ H370 Causes damage to organs ------ H372 Causes damage to organs through prolonged or repeated exposure ------ Simple Asphy May displace oxygen and cause rapid suffocation ------ H400 Very toxic to aquatic life ------ H401 Toxic to aquatic life ------ H402 Harmful to aquatic life ------ H410 Very toxic to aquatic life with long lasting effects ------ H411 Toxic to aquatic life with long lasting effects ------ H412 Harmful to aquatic life with long lasting effects Gorilla Spray Adhesive SDS Page 19 of 19 Safety Data Sheet – Gorilla Spray Adhesive Date Revised: 11/01/2019 Date Issued: 02/28/2017 Version 1.1 FOR CHEMICAL EMERGENCY DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186 According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations. The information presented in this Safety Data Sheet was prepared by qualified personnel and to the best of our knowledge is true and accurate. The information and recommendations are furnished for this product with the understanding that the purchaser will independently determine the suitability of the product for this purpose. This data does not constitute a warranty, expressed or implied, statutory or otherwise, nor is it representation for which The Gorilla Glue Company assumes legal responsibility. The data is submitted for the user’s information and consideration only. Any use of this product must be determined by the user to be in accordance with applicable federal, state, provincial and local laws and regulations. Gorilla Glue US GHS SDS 2015 SAFETY DATA SHEET Page : 1 / 11 Revision nr : 2.0 Issue date : 04/10/2016 Honda ATF DW1 Supersedes : 30/08/2013 HONDA-608 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name/designation : Honda ATF DW1 Product code : 0826899901/4HE Document no. : HONDA-608 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.2.1. Relevant identified uses Use of the substance/mixture : Lubricants 1.2.2. Uses advised against No data available 1.3. Details of the supplier of the safety data sheet Honda Motor Europe Logistics NV Langerbruggestraat 104 9000 Gent - BELGIUM T +32 (0)9 250 1211 - F +32 (0)9 250 1230 Kristiaan.van.renterghem@honda-eu.com National representative: United Kingdom: Honda Motor Europe Ltd London Road 470, SL3 8QY Slough Berkshire, Great Britain Tel: 0044 1753590326 1.4. Emergency telephone number Emergency number : +32 (0)3 575 0330 This telephone number is available 24 hours per day, 7 days per week. Country Official advisory body Address Emergency number Ireland National Poisons Information Centre Beaumont Hospital Beaumont Hospital Beaumont Road 9 Dublin +353 1 809 21 66 (public, 8am - 10pm, 7/7) +353 01 809 2566 (Professionals, 24/7) United Kingdom National Poisons Information Service (Newcastle Centre) Regional Drugs and Therapeutics Centre, Wolfson Unit Claremont Place Newcastle-upon-Tyne NE1 4LP Newcastle 0844 892 0111 (UK only, Monday to Friday, 08.00 to 18.00 hours, healthcare professionals only) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Aquatic Chronic 3 H412 Full text of hazard classes and H-statements : see section 16 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display Signal word : - SAFETY DATA SHEET Page : 2 / 11 Revision nr : 2.0 Issue date : 04/10/2016 Honda ATF DW1 Supersedes : 30/08/2013 HONDA-608 Hazard statements : H412 - Harmful to aquatic life with long lasting effects. Precautionary statements : P273 - Avoid release to the environment. P501 - Dispose of contents/container to an approved waste disposal plant. Extra phrases : EUH208 - Contains N-Phenyl-1-Naphthylamine. May produce an allergic reaction. 2.3. Other hazards Other hazards : PBT/vPvB data. This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB). SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Comments : Lubricating oils, DMSO< 3% (IP 346) Substance name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Severly refined mineral oils (CAS No) - (EC no) - (EC Index) - 80 - 90 Not classified 2,6-di-tert-butyl-p-cresol (CAS No) 128-37-0 (EC no) 204-881-4 (EC Index) - < 0,4 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 N-Phenyl-1-Naphthylamine (CAS No) 90-30-2 (EC no) 201-983-0 < 0,2 Acute Tox. 4 (Oral), H302 Skin Sens. 1, H317 STOT RE 2, H373 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Full text of H-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures Additional advice : First aider: Pay attention to self-protection. See also section 8 . Never give anything by mouth to an unconscious person. Treat symptomatically. Show this safety data sheet to the doctor in attendance. In case of doubt or persistent symptoms, consult always a physician. Inhalation : Provide fresh air. Keep at rest. If breathing is irregular or stopped, administer artificial respiration. If breathing is difficult, give oxygen. In case of doubt or persistent symptoms, consult always a physician. Skin contact : Wash with plenty of soap and water. Remove contaminated, saturated clothing immediately. Wash contaminated clothing before reuse. In case of doubt or persistent symptoms, consult always a physician. Eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. In case of doubt or persistent symptoms, consult always a physician. In case of ingestion : Rinse mouth. If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Get immediate medical advice/attention. 4.2. Most important symptoms and effects, both acute and delayed Inhalation : Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. SAFETY DATA SHEET Page : 3 / 11 Revision nr : 2.0 Issue date : 04/10/2016 Honda ATF DW1 Supersedes : 30/08/2013 HONDA-608 Skin contact : May be irritating. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. Eye contact : Contact with eyes may cause irritation. Ingestion : May cause gastrointestinal irritation, nausea, vomiting and diarrhoea. 4.3. Indication of any immediate medical attention and special treatment needed No data available. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Use powder, CO2, water spray or alcohol resistant foam. Unsuitable extinguishing media : Strong water jet. 5.2. Special hazards arising from the substance or mixture Specific hazards : Combustible. Thermal decomposition can lead to the escape of irritating gases and vapours. Dispose of contaminated materials in accordance with current regulations. In case of fire and/or explosion do not breathe fumes. 5.3. Advice for firefighters Firefighting instructions : Special protective equipment for firefighters. In case of fire: Wear self-contained breathing apparatus. Use water spray or fog for cooling exposed containers. Do not allow run-off from fire-fighting to enter drains or water courses. Dispose of waste in accordance with environmental legislation. Evacuate personnel to a safe area. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel For non-emergency personnel : Evacuate personnel to a safe area. Provide adequate ventilation. Use personal protective equipment as required. Reference to other sections: 8. Avoid contact with skin and eyes. Do not breathe vapour/aerosol. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. 6.1.2. For emergency responders For emergency responders : Ensure procedures and training for emergency decontamination and disposal are in place. Reference to other sections: 8. 6.2. Environmental precautions Do not allow to enter into surface water or drains. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Stop leak if safe to do so. Dam up. Take up liquid spill into absorbent material, e.g.: sand, earth, vermiculite or powdered limestone. Take up mechanically, placing in appropriate containers for disposal. Special danger of slipping by leaking/spilling product. Dispose of contaminated materials in accordance with current regulations. Clean contaminated areas thoroughly. 6.4. Reference to other sections Reference to other sections: 8, 12 & 13. SAFETY DATA SHEET Page : 4 / 11 Revision nr : 2.0 Issue date : 04/10/2016 Honda ATF DW1 Supersedes : 30/08/2013 HONDA-608 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Provide adequate ventilation. Use personal protective equipment as required. Reference to other sections: 8. Do not ingest. Avoid contact with skin and eyes. Do not breathe vapour/aerosol. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Provide adequate precautions, such as electrical grounding and bonding, or inert atmospheres. Do not burn, or use a cutting torch on, the empty drum. Never use pressure to empty container. After use replace the closing cap immediately. Ensure proper process control to avoid excess waste discharge (temperature, concentration, pH, time). Do not allow to enter into surface water or drains. Take any precaution to avoid mixing with incompatible materials. See also section 10. Hygiene measures : Keep good industrial hygiene. Wash hands and face before breaks and immediately after handling of the product. When using do not eat, drink or smoke. Keep away from food, drink and animal feedingstuffs. Keep work clothes separately. Take off contaminated clothing. Wash contaminated clothing before reuse. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Keep container tightly closed in a cool, well-ventilated place. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ensure equipment is adequately earthed. Do not store near or with any of the incompatible materials listed in section 10. Packaging materials : Keep/Store only in original container. 7.3. Specific end use(s) Not applicable. SECTION 8: Exposure controls/personal protection 8.1. Control parameters EU Mineral oil OEL's : oil (mist) TLV-TWA (mg/m³) : 1 (se, no); 5 (be, nl, gb, fr, de, fi, dk) oil (mist) TLV-STEL (mg/m³) : 3 (se); 10 (be, gb): 2,6-di-tert-butyl-p-cresol (128-37-0) Austria MAK (mg/m³) 10 mg/m³ Belgium Limit value (mg/m³) 2 mg/m³ (aerosol and vapor) Bulgaria OEL TWA (mg/m³) 10 mg/m³ Bulgaria OEL STEL (mg/m³) 50 mg/m³ Croatia GVI (granična vrijednost izloženosti) (mg/m³) 10 mg/m³ Denmark Grænseværdie (langvarig) (mg/m³) 10 mg/m³ Finland HTP-arvo (8h) (mg/m³) 10 mg/m³ Finland HTP-arvo (15 min) 20 mg/m³ France VME (mg/m³) 10 mg/m³ Germany TRGS 900 Occupational exposure limit value (mg/m³) 10 mg/m³ (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed-inhalable fraction) Greece OEL TWA (mg/m³) 10 mg/m³ Ireland OEL (8 hours ref) (mg/m³) 10 mg/m³ Ireland OEL (15 min ref) (mg/m3) 30 mg/m³ (calculated) Portugal OEL TWA (mg/m³) 2 mg/m³ (inhalable fraction, aerosol and vapor) Slovenia OEL TWA (mg/m³) 10 mg/m³ (inhalable fraction) SAFETY DATA SHEET Page : 5 / 11 Revision nr : 2.0 Issue date : 04/10/2016 Honda ATF DW1 Supersedes : 30/08/2013 HONDA-608 2,6-di-tert-butyl-p-cresol (128-37-0) Spain VLA-ED (mg/m³) 10 mg/m³ United Kingdom WEL TWA (mg/m³) 10 mg/m³ United Kingdom WEL STEL (mg/m³) 30 mg/m³ (calculated) Switzerland VME (mg/m³) 10 mg/m³ (inhalable dust) Switzerland VLE (mg/m³) 40 mg/m³ (inhalable dust) Australia TWA (mg/m³) 10 mg/m³ Canada (Quebec) VECD (mg/m³) 10 mg/m³ USA - ACGIH ACGIH TWA (mg/m³) 2 mg/m³ (inhalable fraction and vapor) USA - NIOSH NIOSH REL (TWA) (mg/m³) 10 mg/m³ Additional information : Concentration measurement in air. Personal air monitoring 8.2. Exposure controls Engineering control measures : Provide adequate ventilation. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Take precautionary measures against static discharges. Organisational measures to prevent /limit releases, dispersion and exposure. See also section 7. Personal protection equipment : Not required for normal conditions of use. Choose body protection according to the amount and concentration of the dangerous substance at the work place. Hand protection : During splash contact: Wear chemically resistant gloves (tested to EN374) . NBR (Nitrile rubber),. Fluorinated rubber . Thickness of the glove material: > 0,3mm. The selection of specific gloves for a specific application and time of use in a working area, should also take into account other factors on the working space, such as (but not limited to): other chemicals that are possibly used, physical requirements (protection against cutting/drilling, skill, thermal protection), and the instructions/specification of the supplier of gloves. The exact break through time can be obtained from the protective glove producer and this has to be observed Eye protection : During splash contact: Wear eye glasses with side protection according to EN 166. Body protection : Wear suitable protective clothing. Overalls, apron and boots recommended Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Full face mask (EN 136). Half-face mask (DIN EN 140). Filter type: AP. (EN141) Thermal hazard protection : Heat resistant gloves. Environmental exposure controls : Do not allow to enter into surface water or drains. Comply with applicable Community environmental protection legislation. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : liquid Appearance : clear. Colour : red. Odour : slight. Odour threshold : No data available pH : No data available Relative evaporation rate (butylacetate=1) : No data available Melting point/freezing point : No data available Freezing point : No data available Initial boiling point and boiling range : No data available Flash point : 172 °C (COC) SAFETY DATA SHEET Page : 6 / 11 Revision nr : 2.0 Issue date : 04/10/2016 Honda ATF DW1 Supersedes : 30/08/2013 HONDA-608 Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : Not applicable,liquid Vapour pressure : No data available Vapour density : No data available Relative density : No data available Density : 0,8501 g/cm³ (@15°C) Solubility : No data available. Water: Insoluble Partition coefficient n-octanol/water : No data available Kinematic viscosity : 6,816 (@ 100°C) 24,85 mm²/s (@40°C) Dynamic viscosity : No data available Explosive properties : Not applicable. The study does not need to be conducted because there are no chemical groups associated with explosive properties present in the molecule. Oxidising properties : Not applicable. The classification procedure needs not to be applied because there are no chemical groups present in the molecule which are associated with oxidising properties. Explosive limits : No data available 9.2. Other information Other properties : Pour point -50,0°C. SECTION 10: Stability and reactivity 10.1. Reactivity Reference to other sections: 10.5. 10.2. Chemical stability Stable under recommended storage conditions. 10.3. Possibility of hazardous reactions Hazardous polymerisation does not occur. See also section 7. 10.4. Conditions to avoid Keep away from sources of heat (e.g. hot surfaces), sparks and open flames. See also section 7 : Handling and storage. 10.5. Incompatible materials Strong oxidizing agents. Strong bases. See also section 7 : Handling and storage. 10.6. Hazardous decomposition products Thermal decomposition can lead to the escape of irritating gases and vapours. Reference to other sections: 5.2. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified (Based on available data, the classification criteria are not met) Severly refined mineral oils (-) LD50/oral/rat > 2000 mg/kg LD50/dermal/rat > 2000 mg/kg LD50/dermal/rabbit > 2000 mg/kg LC50/inhalation/4h/rat > 5 mg/l/4h 2,6-di-tert-butyl-p-cresol (128-37-0) LD50/oral/rat 890 mg/kg SAFETY DATA SHEET Page : 7 / 11 Revision nr : 2.0 Issue date : 04/10/2016 Honda ATF DW1 Supersedes : 30/08/2013 HONDA-608 2,6-di-tert-butyl-p-cresol (128-37-0) LD50/dermal/rat > 2000 mg/kg LC50/inhalation/4h/rat 546 mg/m³ N-Phenyl-1-Naphthylamine (90-30-2) LD50/oral/rat 1625 mg/kg Skin corrosion/irritation : Not classified (Based on available data, the classification criteria are not met) pH: No data available Serious eye damage/eye irritation : Not classified (Based on available data, the classification criteria are not met) pH: No data available Respiratory or skin sensitisation : Not classified (Based on available data, the classification criteria are not met) Germ cell mutagenicity : Not classified (Based on available data, the classification criteria are not met) Carcinogenicity : Not classified (Based on available data, the classification criteria are not met) Base oil - unspecified (DMSO < 3%) Reproductive toxicity : Not classified (Based on available data, the classification criteria are not met) STOT-single exposure : Not classified (Based on available data, the classification criteria are not met) STOT-repeated exposure : Not classified (Based on available data, the classification criteria are not met) Aspiration hazard : Not classified (Based on available data, the classification criteria are not met) Other information : Symptoms related to the physical, chemical and toxicological characteristics. Reference to other sections: 4.2. SECTION 12: Ecological information 12.1. Toxicity Environmental properties : Harmful to aquatic life with long lasting effects. Severly refined mineral oils (-) LC50 fish 1 5000 mg/l Oncorhynchus mykiss (Rainbow trout) LC50 other aquatic organisms 1 10000 mg/l Lepomis macrochirus (Bluegill) EC50 Daphnia 1 1000 mg/l Daphnia magna (Big water flea) EC50 other aquatic organisms 1 > 100 mg/l (WAF) LOEC (acute) >= 100 mg/l (WAF) 12.2. Persistence and degradability Persistence and degradability No information available. 12.3. Bioaccumulative potential Partition coefficient n-octanol/water No data available Bioaccumulative potential No information available. Severly refined mineral oils (-) Partition coefficient n-octanol/water > 6 2,6-di-tert-butyl-p-cresol (128-37-0) BCF fish 1 230 - 2500 Partition coefficient n-octanol/water 4,17 12.4. Mobility in soil Mobility in soil No information available SAFETY DATA SHEET Page : 8 / 11 Revision nr : 2.0 Issue date : 04/10/2016 Honda ATF DW1 Supersedes : 30/08/2013 HONDA-608 Honda ATF DW1 Surface tension No data available Ecology - soil No information available. 12.5. Results of PBT and vPvB assessment Results of PBT assessment The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII. 12.6. Other adverse effects Additional information : No information available SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Handle with care. Safe handling: see section 7 : Handling and storage . Dispose of contaminated materials in accordance with current regulations. Refer to manufacturer/supplier for information on recovery/recycling. Collect and dispose of waste product at an authorised disposal facility. Liquid product may not be disposed of with household waste or landfilled. Do not allow to enter into drains/waters or in the soil. Additional information : Delivery to an approved waste disposal company. This material and its container must be disposed of as hazardous. List of proposed waste codes/waste designations in accordance with EWC (2001/573/EC, 75/442/EEC, 91/689/EEC) : Classified as hazardous waste according to European Union regulations The following Waste Codes are only suggestions: 130205 - mineral-based non-chlorinated engine, gear and lubricating oils Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN ADR IMDG IATA ADN RID 14.1. UN number 14.2. UN proper shipping name Transport document description 14.3. Transport hazard class(es) 14.4. Packing group 14.5. Environmental hazards 14.6. Special precautions for user Special precautions for user : Not applicable SAFETY DATA SHEET Page : 9 / 11 Revision nr : 2.0 Issue date : 04/10/2016 Honda ATF DW1 Supersedes : 30/08/2013 HONDA-608 - Overland transport No data available - Transport by sea No data available - Air transport No data available - Inland waterway transport No data available - Rail transport No data available 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Code: IBC : Not applicable. SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations The following restrictions are applicable according to Annex XVII of the REACH Regulation (EC) No 1907/2006: 3. Liquid substances or mixtures which are regarded as dangerous in accordance with Directive 1999/45/EC or are fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008 Honda ATF DW1 - N-Phenyl-1-Naphthylamine 3.b. Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10 N-Phenyl-1-Naphthylamine 3.c. Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class 4.1 Honda ATF DW1 - N-Phenyl-1-Naphthylamine Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances 15.1.2. National regulations France Installations classées : Not applicable Germany VwVwS Annex reference : Water hazard class (WGK) 1, low hazard to waters (Classification according to VwVwS, Annex 4) Risk classification according to VbF : Not applicable 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) TA Luft : Organic Substances Netherlands Waterbezwaarlijkheid : 8 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment Saneringsinspanningen : A - In principe niet lozen; zo ja, dan toepassen van beste bestaande technieken SAFETY DATA SHEET Page : 10 / 11 Revision nr : 2.0 Issue date : 04/10/2016 Honda ATF DW1 Supersedes : 30/08/2013 HONDA-608 SZW-lijst van kankerverwekkende stoffen : None of the components are listed SZW-lijst van mutagene stoffen : None of the components are listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Borstvoeding : None of the components are listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Vruchtbaarheid : None of the components are listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Ontwikkeling : None of the components are listed 15.2. Chemical safety assessment No data available SECTION 16: Other information Indication of changes: Safety datasheet sections which have been updated : 1-2-3-4-9-10-11-12-14-15-16. Abbreviations and acronyms: DNEL = Derived No Effect Level DMEL = Derived Minimal Effect level PNEC = Predicted No Effect Concentration OEL = Occupational Exposure Limits - Short Term Exposure Limits (STELs) TWA = time weighted average LC50 = Median lethal concentration LD50 = Median lethal dose LL50 = Median lethal level EC50 = Median Effective Concentration EL50 = Median effective level ErC50 = EC50 in terms of reduction of growth rate ErL50 = EL50 in terms of reduction of growth rate NOEL = no-observed-effect level NOEC = No observed effect concentration NOELR = No observed effect loading rate NOAEC = No observed adverse effect concentration NOAEL = No observed adverse effect level EWC = European waste catalogue NA = Not applicable N.O.S. = Not Otherwise Specified VOC = Volatile organic compounds Quantitative structure-activity relationship (QSAR) SAFETY DATA SHEET Page : 11 / 11 Revision nr : 2.0 Issue date : 04/10/2016 Honda ATF DW1 Supersedes : 30/08/2013 HONDA-608 ADN = Accord Européen relatif au Transport International des Marchandises Dangereuses par voie de Navigation du Rhin ADR = Accord européen relatif au transport international des marchandises Dangereuses par Route CLP = Classification, Labelling and Packaging Regulation according to 1272/2008/EC IATA = International Air Transport Association IMDG = International Maritime Dangerous Goods Code LEL = Lower Explosive Limit/Lower Explosion Limit UEL = Upper Explosion Limit/Upper Explosive Limit REACH = Registration, Evaluation, Authorisation and Restriction of Chemicals WGK = Wassergefährdungsklasse (Water Hazard Class under German Federal Water Management Act) ABM = Algemene beoordelingsmethodiek STOT = Specific Target Organ Toxicity Sources of key data used to compile the datasheet : Name (SDS) : HONDA ATF DW-1. Manufacturer/Supplier : IDEMITSU. Date of issue : 24-Sep-2013. Revision date : 15-Apr-2015. Training advice : Training staff on good practice. Other information : Assessment/classification CLP. Article 9. Calculation method. Full text of H- and EUH-statements: Acute Tox. 4 (Oral) Acute toxicity Category 4 Aquatic Acute 1 Hazardous to the aquatic environment - Aquatic Acute 1 Aquatic Chronic 1 Hazardous to the aquatic environment - chronic hazard category 1 Aquatic Chronic 3 Hazardous to the aquatic environment - chronic hazard category 3 Skin Sens. 1 Skin sensitisation, hazard category 1 STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2 H302 Harmful if swallowed. H317 May cause an allergic skin reaction. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. EUH208 Contains . May produce an allergic reaction SAFETY DATA SHEET Purple Power Cleaner/Degreaser 1 Section 1: Product and Company Identification: Product Name: Purple Power Concentrated Industrial Strength Cleaner/Degreaser Product Use: Cleaner Part#’s: 4315PS, 4332PS, 4380DG, 4320P, 4322P, 4325P, 4330, 4340, PP275 Manufacture/Supplier: Aiken Chemical Company, Inc. P.O. Box 27147, Greenville, SC 29616 12 Shelter Drive, Greer, SC 29650 Phone Number: (864) 968-1250 1-800-828-1860 Emergency Phone: 1-800-424-9300 Date of Preparation: March 30, 2015 Section 2: Hazards Identification: Emergency Overview: Warning: Corrosive Material – May Cause Burns, Irritating to Eyes and Skin. Potential Health Effects: See Section 11 for more information. Likely Routes of Exposure: Eye contact, skin contact, ingestion, and inhalation. Eye: May cause burns and Irritating to eyes. Skin: May cause burns and Irritating to skin. Ingestion: May cause burns and may be harmful if swallowed. May cause stomach distress, nausea, or vomiting Inhalation: May cause respiratory tract irritation. May cause burns Chronic Effects: Prolonged or repeated contact may dry skin and cause irritation. Signs and symptoms: Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Symptoms may include redness, edema, drying, de-fatting and cracking of the skin. Medical Conditions Aggravated By Exposure: Because of its irritating properties, product may aggravate preexisting skin, eye, and respiratory conditions. Target Organs: Skin, eyes, gastrointestinal tract, respiratory system Potential Environmental Effects: See Section 12 from more information. Section 3: Composition / Information on Ingredients: Ingredient CAS# Percent Diethylene glycol monobutyl ether 112-34-5 1-5 Section 4: First Aid Measures: Eye Contact: Remove contact lenses if present. Immediately flush eyes with large amounts of water for at least 15 minutes, lifting upper and lower eyelids periodically to insure complete flushing. Seek medical attention immediately. Skin Contact: Remove contaminated clothing immediately. Thoroughly wash exposed area with soap and water for at least 15 minutes. Seek medical attention immediately. Inhalation: Remove individual to fresh air. If breathing has stopped, give artificial respiration. Seek medical attention immediately. Ingestion: DO NOT induce vomiting. If conscious, dilute by giving 2-3 glasses of water. Seek medical attention immediately General Advice: In case of accident or if you feel unwell, seek medical advice immediately. Show the label or SDS where possible. Note to Physicians: Symptoms may not appear immediately. Hazard Determination System (HDS): Health, Flammability, Reactivity 1 0 0 SAFETY DATA SHEET Purple Power Cleaner/Degreaser 2 Section 5: Fire Fighting Measures: Flammability: Not Flammable by WHMIS/OSHA Criteria. Means of Extinguishing: Suitable extinguishing media: Use water fog, alcohol foam, carbon dioxide or dry chemical. Unsuitable Extinguishing Media: Not Available. Products of Combustion: Not Available. Explosion Data: Sensitivity to Mechanical Impact: Not Available. Sensitivity to Static Discharge: Not Available. Protection of Firefighters: Keep Upwind of fire. Wear full fire fighting turn-out gear, (full Bunker gear), and respiratory protection (SCBA) Section 6: Accidental Release Measures: Personal Precautions: Use personal protection recommended in section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental Precautions: Not Available. Methods for Containment: Contain and/or absorb spill with inert material, (e.g. sand, vermiculite), then place in a suitable container. Use appropriate Personal Protective Equipment, (PPE). Methods for Clean-up: Scoop up material and place in a disposal container. Provide ventilation. Other Information: Not Available. Section 7: Handling and Storage: Handling: Avoid contact with skin and eyes. Do not swallow. Do not breathe gas/fumes/vapor/spray. Use only in well-ventilated areas. Handle and open container with care. Launder contaminated clothing before reuse. When using, do not eat or drink. Wash hands before eating, drinking, or smoking. Storage: Do not store in aluminum, copper, or galvanized containers. Separate from acids, reactive metals, and ammonium salts. Section 8: Exposure Controls/Personal Protections: Exposure Guidelines: Ingredient Exposure Limits OSHA-PEL ACGIH-TLV Diethylene glycol monobutyl ether: Not Available 10 ppm Engineering Controls: Use Ventilation adequate to keep exposures, (airborne levels of dust, fume, vapor, etc.), below recommended exposure limits. Personal Protective Equipment: Eye/Face Protection: Wear eye/face protection. Hand Protection: Wear suitable gloves, (Neoprene, Nitrile Rubber, and Polyethylene). Skin and Body Protection: Wear body-covering, impervious clothing, chemical resistant gloves and boots. General Hygiene Considerations: Handle according to established industrial hygiene and safety practices. Section 9: Physical and Chemical Properties: Appearance and Odor: Purple liquid with Characteristic odor. Physical State: Liquid. pH: 12.98 Freezing Point: ~2°C (~28.4°F) Boiling Point: ~100°C (~212°F) Flash Point (Method Used): >200°F (PMCC) Evaporation Rate (Butyl Acetate= 1) : <1.0 LEL: Not Determined SAFETY DATA SHEET Purple Power Cleaner/Degreaser 3 UEL: Not Determined Vapor Pressure (mm Hg.): Not Determined Vapor Density (AIR=1): Not Determined Specific Gravity: 1.0197 Solubility in Water: Complete Melting Point: NA Auto-Ignition Temperature: Not Determined Percent Volatile, wt%: Not Determined VOC content, wt. %: < 0.2 Section 10: Stability and Reactivity: Stability: Stable under normal storage conditions. Conditions to Avoid: Mixing or blending with oxidizing or low pH solutions Incompatibility (Materials to Avoid): Avoid contact with reactive metals, strong mineral acids and organic acids. Hazardous Decomposition or Byproducts: Carbon dioxide, carbon monoxide, various hydrocarbons and can include aldehydes, ketones, organic acids and other organics. Hazardous Polymenzation: Will Not Occur. Section 11: Toxicology Information: Effects of Acute Exposure Component Analysis: Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. (Poly (oxy-1, 2-ethanediyl), a-(2-propylheptyl)-w-hydroxy-): Acute Toxicity/Effects: Assessment of acute toxicity: Slightly toxic after single ingestion. Oral: LD50 judged > 500 mg/kg based on deaths at 200mg/kg (0/6) and 2000mg/kg (2/3) plus oral LD50 data on surrogate chemicals. Irritation/corrosion: Causes serious eye damage and causes skin irritation as well as, may cause irritations to the respiratory tract. Skin: Species: rabbit, Result: Irritation. Method: OECD Guideline 404 Eye: Species: Rabbit, Results: Risk of serious damage to eyes. Method: OECD Guideline 405 Sensitization: Guinea pig maximization test: Species: guinea pig. Result: Skin sensitizing effects were not observed in animal studies. Method: OECD Guideline 406. Aspiration Hazard: No aspiration hazard expected. Chronic Toxicity/Effects Symptoms of Exposure: The most important known symptoms and effects are described in the labeling, (see section 2), and/or in section 11. Further important symptoms and effects are so far not known. Diethylene glycol monobutyl ether: Effects, Acute Exposure: Skin Contact: May be slightly irritating Skin Absorption: Yes; Toxic effects unlikely by this route unless contact is extensive in area & prolonged Eye Contact: Likely to be severely irritating (by animal testing) Inhalation: Headache, dizziness, intoxication possible, low vapor pressure makes this unlikely. Ingestion: Headache, dizziness, intoxication; in severe cases, cyanosis (blue coloring), low blood pressure, & unconsciousness SAFETY DATA SHEET Purple Power Cleaner/Degreaser 4 Effects, Chronic Exposure: General: Little to no effect reported Sensitizing: Not a sensitizer in humans or animals Carcinogen/Tumorigen: Not considered a Tumorigen or a carcinogen in humans or animals. Reproductive Effect: No known effect in humans or animals Mutagen: No known effect on humans or animals Synergistic With: Not Known LD50 (oral): 4500 to 9625mg/kg (rat), 2400 to 525mg/kg (mouse), 1720 to 2310mg/kg (guinea pig), and 2200mg/kg (rabbit) LD50 (skin): 2700mg/kg (rabbit) LC50 (inhalation): None – exposure of rats to DB vapor (saturated at 100 °C & cooled to room temp.) for 7hrs caused no mortality or other adverse symptoms Section 12: Toxicology Information: Ecotoxicity: Not Available. Persistence/Degradability: Not Available. Bioaccumulation/Accumulation: Not Available Mobility in Environment: Not Available. Section 13: Disposal Considerations: Disposal Instructions: This material must be disposed of in accordance with all local, state, provincial, and federal regulations. Section 14: Transportation Information: Proper Shipping Name: Not D.O.T. Regulated Hazard Class: N/A ID Number: N/A Packing Group N/A IATA: N/A Section 15: Regulatory Information: Chemical Inventories: TSCA: All components of this product are either on the TSCA 8(b) Inventory or otherwise exempt from listing. SARA Section 311: Acute SARA Section 313: Toxic Release Inventory Chemical: Glycol Ethers, California Safe Drinking Water Enforcement Act (Prop 65): This product contains no listed substances known to the State of California to cause cancer, birth defects or other reproductive harm, at levels which would require a warning under the stature. Pennsylvania (Worker and Community Right-to-Know act): Pennsylvania Special Hazardous Substance List and/or Pennsylvania Environmental Hazardous Substance list: To the best of our knowledge, this product does not contain chemicals that require reporting under this stature. New Jersey Right-to-Know Hazardous Substance List: To the best of our knowledge, this product does not contain chemicals that require reporting under this stature. SAFETY DATA SHEET Purple Power Cleaner/Degreaser 5 Massachusetts Substance List: To the best of our knowledge, this product does not contain chemicals that require reporting under this stature. Section 16: Other Information: NFPA Health Hazard Flammability Instability Physical &Chemical Hazards 1 0 0 COR HMIS Health Hazard Flammability Physical Hazard Personal Protection 1 0 0 C Prepared By: Aiken Chemical Company, Inc. 12 Shelter Drive Greer, SC 29650 Preparation/Revision Date: March 30, 2015 Revision Date: Revision Note General Disclaimer: The information provided in this Safety Data Sheet is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. _____________________________________________________________________ Revision Number: 18 Revision Date: January 31, 2023 1 of 8 Delo Gear ESI SAE 80W-90, 85W-140 SDS : 6698 Safety Data Sheet SECTION 1 PRODUCT AND COMPANY IDENTIFICATION Delo Gear ESI SAE 80W-90, 85W-140 Product Use: Axle Oil Product Number(s): 224503, 224504, 224605, 224606 Synonyms: Delo Gear ESI SAE 80W-90 ISOCLEAN Certified; Delo Gear ESI SAE 85W-140 ISOCLEAN Certified Company Identification Chevron Products Company a division of Chevron U.S.A. Inc. 6001 Bollinger Canyon Rd. San Ramon, CA 94583 United States of America www.chevronlubricants.com Transportation Emergency Response CHEMTREC: (800) 424-9300 or (703) 527-3887 Health Emergency Chevron Emergency & Information Center: Located in the USA. International collect calls accepted. (800) 231-0623 or (510) 231-0623 Product Information email : lubemsds@chevron.com Product Information: 1 (800) 582-3835, LUBETEK@chevron.com SECTION 2 HAZARDS IDENTIFICATION CLASSIFICATION: • Acute aquatic toxicant: Category 3. • Chronic aquatic toxicant: Category 3. Environmental Hazards: • Harmful to aquatic life with long lasting effects. PRECAUTIONARY STATEMENTS: Prevention: • Avoid release to the environment. Disposal: • Dispose of contents/container in accordance with applicable local/regional/national/international regulations. HAZARDS NOT OTHERWISE CLASSIFIED: Heating may release highly toxic and flammable hydrogen sulfide (H2S). Do not attempt rescue without supplied-air respiratory protection. _____________________________________________________________________ Revision Number: 18 Revision Date: January 31, 2023 2 of 8 Delo Gear ESI SAE 80W-90, 85W-140 SDS : 6698 SECTION 3 COMPOSITION/ INFORMATION ON INGREDIENTS COMPONENTS CAS NUMBER AMOUNT Highly refined mineral oil (C15 - C50) Mixture 70 - 99 %weight Borate dispersion 20786-60-1 1 - < 3 %weight Alkyl phosphorous acid esters Trade secret 0.1 - < 1 %weight Calcium long chain alkaryl sulfonate 115733-09-0 < 0.25 %weight SECTION 4 FIRST AID MEASURES Description of first aid measures Eye: No specific first aid measures are required. As a precaution, remove contact lenses, if worn, and flush eyes with water. Skin: No specific first aid measures are required. As a precaution, remove clothing and shoes if contaminated. To remove the material from skin, use soap and water. Discard contaminated clothing and shoes or thoroughly clean before reuse. Ingestion: No specific first aid measures are required. Do not induce vomiting. As a precaution, get medical advice. Inhalation: No specific first aid measures are required. If exposed to excessive levels of material in the air, move the exposed person to fresh air. Get medical attention if coughing or respiratory discomfort occurs. If exposure to hydrogen sulfide (H2S) gas is possible during an emergency, wear an approved, positive pressure air-supplying respirator. Move the exposed person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Most important symptoms and effects, both acute and delayed IMMEDIATE HEALTH EFFECTS Eye: Not expected to cause prolonged or significant eye irritation. Skin: Contact with the skin is not expected to cause prolonged or significant irritation. Contact with the skin is not expected to cause an allergic skin response. Not expected to be harmful to internal organs if absorbed through the skin. Ingestion: Not expected to be harmful if swallowed. Inhalation: Not expected to be harmful if inhaled. Contains a petroleum-based mineral oil. May cause respiratory irritation or other pulmonary effects following prolonged or repeated inhalation of oil mist at airborne levels above the recommended mineral oil mist exposure limit. Symptoms of respiratory irritation may include coughing and difficulty breathing. Hydrogen sulfide has a strong rotten-egg odor. However, with continued exposure and at high levels, H2S may deaden a person's sense of smell. If the rotten egg odor is no longer noticeable, it may not necessarily mean that exposure has stopped. At low levels, hydrogen sulfide causes irritation of the eyes, nose, and throat. Moderate levels can cause headache, dizziness, nausea, and vomiting, as well as coughing and difficulty breathing. Higher levels can cause shock, convulsions, coma, and death. After a serious exposure, symptoms usually begin immediately. The U.S. National Institute for Occupational Safety and Health (NIOSH) considers air concentrations of hydrogen sulfide gas greater than 100 ppm to be Immediately Dangerous to Life and Health (IDLH). DELAYED OR OTHER HEALTH EFFECTS: Not classified Indication of any immediate medical attention and special treatment needed Note to Physicians: Administration of 100% oxygen and supportive care is the preferred treatment for poisoning by hydrogen sulfide gas. For additional information on H2S, see Chevron SDS No. 301. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. _____________________________________________________________________ Revision Number: 18 Revision Date: January 31, 2023 3 of 8 Delo Gear ESI SAE 80W-90, 85W-140 SDS : 6698 PROTECTION OF FIRE FIGHTERS: Fire Fighting Instructions: This material will burn although it is not easily ignited. See Section 7 for proper handling and storage. For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment, including self-contained breathing apparatus. Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic compounds will be evolved when this material undergoes combustion. Combustion may form oxides of: Boron, Sulfur. SECTION 6 ACCIDENTAL RELEASE MEASURES Protective Measures: Eliminate all sources of ignition in vicinity of spilled material. Spill Management: Stop the source of the release if you can do it without risk. Contain release to prevent further contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing precautions in Exposure Controls/Personal Protection. Use appropriate techniques such as applying non-combustible absorbent materials or pumping. Where feasible and appropriate, remove contaminated soil. Place contaminated materials in disposable containers and dispose of in a manner consistent with applicable regulations. Reporting: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at (800) 424-8802 as appropriate or required. SECTION 7 HANDLING AND STORAGE General Handling Information: Avoid contaminating soil or releasing this material into sewage and drainage systems and bodies of water. Precautionary Measures: Do not breathe gas. Wash thoroughly after handling. Keep out of the reach of children. Unusual Handling Hazards: Toxic quantities of hydrogen sulfide (H2S) may be present in storage tanks and bulk transport vessels which contain or have contained this material. Persons opening or entering these compartments should first determine if H2S is present. See Exposure Controls/Personal Protection -Section 8. Do not attempt rescue of a person over exposed to H2S without wearing approved supplied- air or self-contained breathing equipment. If there is a potential for exceeding one-half the occupational exposure standard, monitoring of hydrogen sulfide levels is required. Since the sense of smell cannot be relied upon to detect the presence of H2S, the concentration should be measured by the use of fixed or portable devices. Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this material. To minimize this hazard, bonding and grounding may be necessary but may not, by themselves, be sufficient. Review all operations which have the potential of generating and accumulating an electrostatic charge and/or a flammable atmosphere (including tank and container filling, splash filling, tank cleaning, sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations) and use appropriate mitigating procedures. Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty container or it may rupture with explosive force. Empty containers retain product residue (solid, liquid, and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode and cause injury or death. Empty containers should be completely drained, properly closed, and promptly returned to a drum reconditioner or disposed of properly. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION GENERAL CONSIDERATIONS: Consider the potential hazards of this material (see Section 2), applicable exposure limits, job activities, and other substances in the workplace when designing engineering controls and selecting personal _____________________________________________________________________ Revision Number: 18 Revision Date: January 31, 2023 4 of 8 Delo Gear ESI SAE 80W-90, 85W-140 SDS : 6698 protective equipment (PPE). If engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, refer to PPE information below. Factors that affect PPE include, but are not limited to: properties of the chemical, other chemicals which may contact the same PPE, physical requirements (fit & sizing, cut/puncture protection, dexterity, thermal protection, etc.), and potential allergic reactions to the PPE material. It is the responsibility of the user to read and understand all instructions and limitations supplied with the equipment since protection is usually provided for a limited time or under certain circumstances. Refer to appropriate CEN standards. ENGINEERING CONTROLS: Use in a well-ventilated area. PERSONAL PROTECTIVE EQUIPMENT Eye/Face Protection: Wear protective equipment to prevent eye contact. Selection of protective equipment may include safety glasses, chemical goggles, face shields, or a combination depending on the work operations conducted. Skin Protection: Wear chemical personal protective equipment (PPE) to prevent skin contact. Selection of chemical protective clothing should be performed by an Occupational Hygienist or Safety Professional and be based upon applicable standards (ASTM F739 or EN 374). Using chemical PPE depends upon operations conducted and may include chemical gloves, boots, chemical apron, chemical suit, and complete facial protection. Refer to PPE manufacturers to obtain breakthrough time information to determine how long PPE can be used before it needs to be replaced. Unless specific glove manufacturer data indicates otherwise, the below table is based upon available industry data to assist in the glove selection process and is intended to be used as reference only. Chemical Glove Material Thickness (mm) Typical Breakthrough Time (minutes) Butyl 0.7 120 Neoprene 0.61 120 Nitrile 0.8 120 Polyvinyl Chloride (PVC) 1.1 120 Viton Butyl 0.3 120 Respiratory Protection: No respiratory protection is normally required. If material is heated and emits hydrogen sulfide, determine if airborne concentrations are below the occupational exposure limit for hydrogen sulfide. If not, wear an approved positive pressure air-supplying respirator. For more information on hydrogen sulfide, see Chevron SDS No. 301. If user operations generate an oil mist, determine if airborne concentrations are below the occupational exposure limit for mineral oil mist. If not, wear an approved respirator that provides adequate protection from the measured concentrations of this material. For air-purifying respirators use a particulate cartridge. Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not provide adequate protection. Occupational Exposure Limits: Component Agency Form TWA STEL Ceiling Notation Highly refined mineral oil (C15 - C50) ACGIH -- 5 mg/m3 10 mg/m3 -- -- Highly refined mineral oil (C15 - C50) OSHA Z-1 -- 5 mg/m3 -- -- -- Consult local authorities for appropriate values. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Attention: the data below are typical values and do not constitute a specification. _____________________________________________________________________ Revision Number: 18 Revision Date: January 31, 2023 5 of 8 Delo Gear ESI SAE 80W-90, 85W-140 SDS : 6698 Color: Brown to yellow Physical State: Liquid Odor: Petroleum odor Odor Threshold: No data available pH: Not Applicable Vapor Pressure: No data available Vapor Density (Air = 1): No data available Initial Boiling Point: No data available Solubility: Soluble in hydrocarbons; insoluble in water Freezing Point: Not Applicable Density: 0.8882 kg/l - 0.9013 kg/l @ 15°C (59°F) (Typical) Viscosity: 13.70 mm2/s @ 100°C (212°F) (Minimum) Evaporation Rate: No data available Decomposition temperature: No data available Octanol/Water Partition Coefficient: No data available FLAMMABLE PROPERTIES: Flammability (solid, gas): Not Applicable Flashpoint: (Cleveland Open Cup) 180 °C (356 °F) (Minimum) Autoignition: No data available Flammability (Explosive) Limits (% by volume in air): Lower: Not Applicable Upper: Not Applicable SECTION 10 STABILITY AND REACTIVITY Reactivity: May react with strong acids or strong oxidizing agents, such as chlorates, nitrates, peroxides, etc. Chemical Stability: This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. Incompatibility With Other Materials: Not applicable Hazardous Decomposition Products: Hydrogen Sulfide (Elevated temperatures) Hazardous Polymerization: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Information on toxicological effects Serious Eye Damage/Irritation: The material is not considered an eye irritant. The product has not been tested. The statement is based on evaluation of data for similar materials or product components. Skin Corrosion/Irritation: The material is not considered a skin irritant. The product has not been tested. The statement is based on evaluation of data for similar materials or product components. Skin Sensitization: The material is not considered a skin sensitizer. The product has not been tested. The statement is based on evaluation of data for similar materials or product components. Acute Dermal Toxicity: The material is not considered a dermal toxicant. The product has not been tested. The statement is based on evaluation of data for similar materials or product components. Acute Oral Toxicity: The material is not considered an oral toxicant. The product has not been tested. The statement is based on evaluation of data for similar materials or product components. Acute Inhalation Toxicity: The material is not considered an inhalation toxicant. The product has not been tested. The statement is based on evaluation of data for similar materials or product components. Acute Toxicity Estimate: Not Determined _____________________________________________________________________ Revision Number: 18 Revision Date: January 31, 2023 6 of 8 Delo Gear ESI SAE 80W-90, 85W-140 SDS : 6698 Germ Cell Mutagenicity: The material is not considered a mutagen. The product has not been tested. The statement is based on evaluation of data for similar materials or product components. Carcinogenicity: The material is not considered a carcinogen. The product has not been tested. The statement is based on evaluation of data for similar materials or product components. Reproductive Toxicity: The material is not considered a reproductive toxicant. The product has not been tested. The statement is based on evaluation of data for similar materials or product components. Specific Target Organ Toxicity - Single Exposure: The material is not considered a target organ toxicant (single exposure). The product has not been tested. The statement is based on evaluation of data for similar materials or product components. Specific Target Organ Toxicity - Repeated Exposure: The material is not considered a target organ toxicant (repeated exposure). The product has not been tested. The statement is based on evaluation of data for similar materials or product components. Aspiration Hazard: The material is not considered an aspiration hazard. ADDITIONAL TOXICOLOGY INFORMATION: This product contains petroleum base oils which may be refined by various processes including severe solvent extraction, severe hydrocracking, or severe hydrotreating. None of the oils requires a cancer warning under the OSHA Hazard Communication Standard (29 CFR 1910.1200). These oils have not been listed in the National Toxicology Program (NTP) Annual Report nor have they been classified by the International Agency for Research on Cancer (IARC) as; carcinogenic to humans (Group 1), probably carcinogenic to humans (Group 2A), or possibly carcinogenic to humans (Group 2B). These oils have not been classified by the American Conference of Governmental Industrial Hygienists (ACGIH) as: confirmed human carcinogen (A1), suspected human carcinogen (A2), or confirmed animal carcinogen with unknown relevance to humans (A3). SECTION 12 ECOLOGICAL INFORMATION ECOTOXICITY This material is expected to be harmful to aquatic organisms and may cause long-term adverse effects in the aquatic environment. The product has not been tested. The statement has been derived from the properties of the individual components. MOBILITY No data available. PERSISTENCE AND DEGRADABILITY This material is not expected to be readily biodegradable. The product has not been tested. The statement has been derived from the properties of the individual components. POTENTIAL TO BIOACCUMULATE Bioconcentration Factor: No data available. Octanol/Water Partition Coefficient: No data available SECTION 13 DISPOSAL CONSIDERATIONS Use material for its intended purpose or recycle if possible. Oil collection services are available for used oil recycling or disposal. Place contaminated materials in containers and dispose of in a manner consistent with applicable regulations. Contact your sales representative or local environmental or health _____________________________________________________________________ Revision Number: 18 Revision Date: January 31, 2023 7 of 8 Delo Gear ESI SAE 80W-90, 85W-140 SDS : 6698 authorities for approved disposal or recycling methods. SECTION 14 TRANSPORT INFORMATION The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous Goods Regulations, for additional description requirements (e.g., technical name) and mode- specific or quantity-specific shipping requirements. DOT Shipping Description: NOT REGULATED AS HAZARDOUS MATERIAL UNDER 49 CFR IMO/IMDG Shipping Description: NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORT UNDER THE IMDG CODE ICAO/IATA Shipping Description: NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORT UNDER ICAO Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code: Not applicable SECTION 15 REGULATORY INFORMATION EPCRA 311/312 CATEGORIES: Not applicable REGULATORY LISTS SEARCHED: 01-1=IARC Group 1 05=MA RTK 01-2A=IARC Group 2A 06=NJ RTK 01-2B=IARC Group 2B 07=PA RTK 02=NTP Carcinogen 08-1=TSCA 5(e) 03=EPCRA 313 08-2=TSCA 12(b) 04=CA Proposition 65 No components of this material were found on the regulatory lists above. CHEMICAL INVENTORIES: All components comply with the following chemical inventory requirements: AIIC (Australia), DSL (Canada), ENCS (Japan), IECSC (China), NZIoC (New Zealand), TCSI (Taiwan), TSCA (United States). One or more components is listed on ELINCS (European Union). All other components are listed or exempted from listing on EINECS. NEW JERSEY RTK CLASSIFICATION: Under the New Jersey Right-to-Know Act L. 1983 Chapter 315 N.J.S.A. 34:5A-1 et. seq., the product is to be identified as follows: PETROLEUM OIL (Gear oil) SECTION 16 OTHER INFORMATION NFPA RATINGS: Health: 2 Flammability: 1 Reactivity: 0 HMIS RATINGS: Health: 0 Flammability: 1 Reactivity: 0 (0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index recommendation, *- Chronic Effect Indicator). These values are obtained using the guidelines or published evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint _____________________________________________________________________ Revision Number: 18 Revision Date: January 31, 2023 8 of 8 Delo Gear ESI SAE 80W-90, 85W-140 SDS : 6698 and Coating Association (for HMIS ratings). REVISION STATEMENT: SECTION 03 - Composition information was modified. SECTION 08 - Eye/Face Protection information was modified. SECTION 08 - General Considerations information was modified. SECTION 08 - Personal Protective Equipment List information was deleted. SECTION 08 - Personal Protective Equipment information was added. SECTION 08 - Skin Protection information was modified. SECTION 15 - Chemical Inventories information was modified. Revision Date: January 31, 2023 ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT: TLV - Threshold Limit Value TWA - Time Weighted Average STEL - Short-term Exposure Limit PEL - Permissible Exposure Limit GHS - Globally Harmonized System CAS - Chemical Abstract Service Number ACGIH - American Conference of Governmental Industrial Hygienists IMO/IMDG - International Maritime Dangerous Goods Code API - American Petroleum Institute SDS - Safety Data Sheet HMIS - Hazardous Materials Information System NFPA - National Fire Protection Association (USA) DOT - Department of Transportation (USA) NTP - National Toxicology Program (USA) IARC - International Agency for Research on Cancer OSHA - Occupational Safety and Health Administration NCEL - New Chemical Exposure Limit EPA - Environmental Protection Agency SCBA - Self-Contained Breathing Apparatus Prepared according to the 29 CFR 1910.1200 (2012) by Chevron Technical Center, 6001 Bollinger Canyon Road, San Ramon, CA 94583. The above information is based on the data of which we are aware and is believed to be correct as of the date hereof. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may suggest modifications of the information, we do not assume any responsibility for the results of its use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose. Appendix C Spill Report Form https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master projects/direct uniform/o&m plan/appendix b - spill reporting form.docx Spill Reporting Form 5324 E. Independence Boulevard Charlotte, North Carolina Name of Employee Responding to the Release: Location of Spill: Date/Time of Spill: Weather Conditions: Material Involved: Amount Spilled: Rate of Spillage: Duration: Cause of Spill: Description of Spill Direction and Response Activities: Damages or Injuries: Agencies/Companies Notified: Environmental Media Effected (water, soil, etc.): What Absorbent Materials Were Used (replenish, if necessary): Waste Generated and Disposal Method: Actions Taken to Prevent Future Spills: