HomeMy WebLinkAbout09015_TownandCounty_ O&M Plan_20240624
Via Email
June 24, 2024
NCDEQ – Division of Waste Management
Brownfields Redevelopment Section
1646 Mail Service Center
Raleigh, North Carolina 27699-1646
Attn: Ms. Carolyn Minnich
Re: Operations & Maintenance Plan
Town & Country Rent-A-Car
5324 E. Independence Boulevard
Charlotte, North Carolina
Brownfields Project No. 09015-05-060
H&H Project No. DCT-001
Dear Carolyn:
On behalf of AAN Real Estate LLC, please find the enclosed revised Operations & Maintenance
Plan prepared for the Town & Country Rent-A-Car Brownfields property for your review and
approval. Should you have questions or need additional information, please do not hesitate to
contact us.
Sincerely,
Hart & Hickman, PC
Ralph McGee, PG Haley Martin, PG
Senior Project Manager Project Manager
Enclosures
cc: Mr. Dave Morris, AAN Real Estate LLC (via email)
Ms. Joselyn Harriger, DEQ Brownfields (via email)
Mr. David Peacock, DEQ Brownfields (via email)
Attachment:
TOWN & COUNTRY RENT-A-CAR
5234 E. Independence Boulevard
Charlotte, North Carolina
Brownfields Project No. 09015-05-060
OPERATIONS & MAINTENANCE PLAN
H&H JOB NO. DCT-001
MAY 15, 2024
REVISED JUNE 24, 2024
2923 S Tryon Street, Suite 100
Charlotte, NC 28203
704 586 0007
harthickman.com Raleigh, NC 27607
919 847 4241
#C-1269 Engineering / #C-245 Geology
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Operations & Maintenance Plan Town & Country Rent-A-Car 5324 E. Independence Boulevard Charlotte, North Carolina H&H Job No. DCT-001 Table of Contents
1.0 Introduction .............................................................................................................................1
2.0 Current Chemical Storage .....................................................................................................3
3.0 Spill Prevention and Response ...............................................................................................5
3.1 Spill Prevention Measures .....................................................................................................5
3.2 Spill Response and Notification ............................................................................................5
3.3 Site Decommissioning ...........................................................................................................7
4.0 Plan Implementation and Approval ......................................................................................9
List of Figures
Figure 1 Site Location Map
Figure 2 Site Map
List of Appendices
Appendix A Site Photographs
Appendix B Safety Data Sheets
Appendix C Spill Report Form
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Operations & Maintenance Plan Town & Country Rent-A-Car 5324 E. Independence Boulevard Charlotte, North Carolina H&H Job No. DCT-001 1.0 Introduction
On behalf of AAN Real Estate LLC, Hart & Hickman, PC (H&H) has prepared this Operations
and Maintenance Plan (O&M Plan) for the Town & Country Rent-A-Car Brownfields property
(Brownfields Project No. 09015-05-060) located at 5324 E. Independence Boulevard in Charlotte,
Mecklenburg County, North Carolina (Site). The Site consists of one approximately 1.6-acre
parcel of land (Mecklenburg County Parcel Identification No. 16303226) developed with an
approximately 6,220 square foot (sq ft) unoccupied car wash facility and an approximate 2,130 sq
ft auto repair garage. Remaining portions of the Site consist of asphalt and concrete-paved vehicle
access and parking areas and vegetated areas. A Site location map is provided as Figure 1, and the
Site and surrounding area are shown in Figure 2.
The Site is located in a historically commercial and industrial-use area of Charlotte. Prior to the
early 1950s, the Site consisted of agricultural and vegetated land. By the mid-1950s, the Site was
developed with commercial structures. Before the early 1990s, the Site was utilized for heating
oil distribution, a gas station, and an automotive repair facility. In the early 1990s, the Site was
acquired by Reflections Carwash. In the late 1990s, the Site was occupied by Town & Country
Rent-A-Car for vehicle rentals. LB Auto Repair is the current Site occupant and utilizes the
approximate 2,130 sq ft auto service garage for limited automotive repair operations.
Based on potential environmental concerns associated with historical uses, the Site was entered
into the North Carolina Department of Environmental Quality (DEQ) Brownfields Redevelopment
Section (Brownfields Project No. 09015-05-060). A Notice of Brownfields Property and
Brownfields Agreement was recorded on the property deed on November 19, 2007. This O&M
Plan has been prepared to identify and implement Best Management Practices (BMPs) for current
chemical storage, provide an inventory of existing chemicals stored at the Site, and spill release
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prevention for ongoing auto repair operations to remain in compliance with the land use
restrictions (LURs) outlined in the recorded Brownfields Agreement.
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2.0 Current Chemical Storage
On April 22, 2024, H&H completed a Site visit to observe current LB Auto Repair operations at
the Site. H&H also conducted interviews with LB Auto Repair personnel at the time of the Site
visit. A photographic log of Site visit observations is provided in Appendix A.
LB Auto Repair operations include auto inspections, oil and transmission fluids changes, brake
repairs, tire repair and alignment, and other general vehicular maintenance. LB Auto Repair
operations do not include engine or transmission repairs, painting, or other auto body repairs.
H&H also documented waste streams and associated disposal methods employed at the Site.
Copies of safety data sheets (SDS) for chemicals observed during the April 2024 Site visit are
provided in Appendix B. H&H identified the following chemicals during the April 2024 Site visit:
Chemicals: new and used motor oil new and used anti-freeze hydraulic fluid
used oil filters
retail sized auto maintenance products retail sized cleaning products vehicle batteries 5-gallon containers of Purple Power degreaser/
cleaning compound
H&H observed used motor oil and transmission fluid stored in an approximately 350-gallon steel
AST within a cinderblock secondary containment area on a concrete pad located on the northern
exterior of the Site building (Photograph 2 and Photograph 3). The AST is emptied on an as-
needed basis by a third-party contractor and transported off-Site for recycling. A representative
photo of the waste disposal manifest provided by the third-party contractor is provided as
Photograph 7.
H&H observed a steel 55-gallon drum containing used oil filters. The 55-gallon drum was staged
on the concrete slab within the auto repair building. The concrete in the vicinity of the drum
appeared to be in good condition with no obvious evidence of significant staining, cracks, seams,
pitting, or other evidence of degradation. The drum is emptied on an as-needed basis by a third-
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party contractor and transported off-Site for disposal. A representative photo of the waste disposal
manifest provided by the third-party contractor is provided as Photograph 8.
Solid non-hazardous wastes at the Site are placed in waste containers located outside the Site
building and disposed off-Site at the municipal solid waste landfill. H&H did not observe evidence
of staining or other obvious evidence of a release to the concrete pad below the waste receptacles.
H&H observed multiple new oil storage containers staged on a metal storage rack within the Site
building (Photograph 4). In addition, retail-sized containers of non-chlorinated brake cleaner,
antifreeze, power steering fluid, transmission fluid, lubricants, and adhesives are stored within or
on storage cabinets within the Site building (Photograph 5 and Photograph 6). In addition, H&H
observed unopened 5-gallon containers of Purple Power degreaser/cleaning solution and an
unopened 5-gallon container of hydraulic fluid stored within the Site building. The concrete below
and in the vicinity of the stored chemicals appeared to be in good condition and H&H did not
observe obvious evidence of staining, cracks, seams, pitting, or other evidence of degradation to
the concrete floor below the new oil storage rack or stored chemicals.
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3.0 Spill Prevention and Response
3.1 Spill Prevention Measures
Based on Site visit observations, the following best management practices can be implemented to
minimize potential spills at the Site:
• Stage new oil storage rack and other small containers of materials (e.g., degreaser/cleaner
and hydraulic fluid) on Uline spill containment pallets. Smaller mobile containers do not
require secondary containment but will continue to be stored inside chemical storage
cabinets when not in use.
• Store used oil filters and soiled rags in appropriate sealable containers until transported off-
Site for disposal.
• Fluids collected in drip pans should be transferred into the on-Site used oil AST daily. The
used oil AST will be emptied on an as-needed basis by a third-party contractor.
• Stage the used oil AST within the covered concrete secondary containment system located
along the northern portion of the Site building.
• When not in use, secure the used oil AST with an appropriate cap and immediately clean
drips when transferring used oil to or from the tank.
3.2 Spill Response and Notification
Spill Response Procedures
1. Contain the spill in the smallest possible area. Designate an area of the facility with
spill containment equipment and materials. If it can be done safely, use absorbent
materials such as pads, socks, or other absorbent materials to contain the spill.
2. Begin the notification procedures. Contact H&H via the Emergency Notification
Phone List below, and H&H will determine if outside contractors are needed to help clean
a spill or if governmental agency reporting is required.
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3. Recover or clean up the spilled material. As much material as possible should be
recovered where appropriate. Liquids absorbed by solid materials should be shoveled
into open-top drums or other appropriate containers. When drums are filled or the
cleanup has been completed, the drum lids should be secured and appropriately labeled
identifying the contents. When possible, efforts should be made to avoid mixing different
waste types. Arrange for disposal of the waste material following applicable Federal and
State regulations and maintain disposal documentation.
4. Evaluate the cause and effectiveness of the response. Determine the cause of the
incident and evaluate if practices or spill response procedures need to be modified.
Correct the deficiencies, as needed.
Notification Procedures
1. Briefly assess the severity of the discharge, determining the extent and nature of the event
by considering the questions:
• Does the discharge represent a release to the environment?
• Could any release that gets outside of a building or outside of an impervious containment
area be a release to the environment?
• Does the quantity of material discharged represent a harmful quantity?
2. Call each Emergency Spill Response Coordinator identified on the below Emergency
Notification Phone List until contact is made and remain on the scene until that person
arrives.
3. Evacuate non-essential personnel from the area affected by the discharge.
4. Determine if a reportable quantity (RQ) of the spilled material has been exceeded, or if the
release has reached waters of the U.S. If so, notify DEQ and the National Response Center
(NRC) as appropriate. The RQ to DEQ for petroleum is 25 gallons.
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5. If outside discharge cleanup assistance is needed, contact the emergency response contractor
or the fire department’s HAZMAT team from the Notification List provided above.
6. If medical assistance is needed, call 911.
Emergency Notification Phone List
Contacts Response Role Office Phone 24-Hour Phone
AAN Real Estate LLC Site Contact (Property Owner) (704) 664-2204 (704) 975-1848
Ralph McGee (704) 887-4621 (704) 840-4775
Haley Martin (704) 526-2045 (704) 506-8107
National Response Center Incident Reporting
EPA Region IV Incident Reporting
Incident Reporting (704) 235-2100
Joselyn Harriger
DEQ Brownfields Incident Reporting (980) 297-4623
Fire Department & HazMat Team Emergency Medical, HazMat Response 911 911
3.3 Site Decommissioning
The facility will be decommissioned before the end of the LB Auto Repair lease period including
removal of chemicals, storage containers, and wastes. The Brownfields Redevelopment Section
will be notified at least 10 days prior to the start of decommissioning activities. Wastes will be
transported by licensed waste haulers and disposed off-Site at facilities permitted to accept such
wastes. Following notice from the property owner that the LB Auto Repair lease period has ended,
and the tenant has vacated the Site, H&H will complete a final Site inspection to verify compliance
with this O&M Plan.
H&H will notify AAN Real Estate LLC if observations indicate potential non-compliance with
the O&M Plan and/or Brownfields Agreement and recommend corrective measures. Following
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the completion of the recommended corrective action (if applicable), AAN Real Estate LLC will
request a follow-up final Site inspection. H&H will document observations, corrective measures
(if any), and decommissioning activities in a Site Inspection Report. A copy of the Site Inspection
Report will be provided to the Brownfields Redevelopment Section for their records.
REVISION NO. 0
JOB NO. DCT-001
DATE: 5-7-24
FIGURE NO. 2
TOWN & COUNTRY RENT-A-CAR
5324 EAST INDEPENDENCE BOULEVARD
CHARLOTTE, NORTH CAROLINA
SITE MAP
LEGEND
BROWNFIELDS PROPERTY BOUNDARY
PARCEL LINE
POLE-MOUNTED TRANSFORMER
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
NOTES:
1. AERIAL IMAGERY AND BASE DATA OBTAINED FROM
MECKLENBURG COUNTY GIS, 2024.
CONNECTION
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MECKLENBURG COUNTY ABC STORE #8
(4047 CONNECTION POINT BOULEVARD)
UNDER
CONSTRUCTION
7-ELEVEN
(6101 IDLEWILD ROAD)
CHIPOTLE MEXICAN GRILL
(4022 CONNECTION POINT BOULEVARD)
MULTI-TENANT COMMERCIAL PROPERTY
(5301-5323 EAST INDEPENDENCE BOULEVARD)
LB AUTO REPAIR VACANT CAR WASH
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Appendix A
Site Photographs
Photograph 1: Typical view of the Brownfields property
TOWN & COUNTRY RENT-A-CAR 5324. INDEPENDENCE BOULEVARDCHARLOTTE, NORTH CAROLINA
2923 S. Tryon Street, Suite 100
Charlotte, NC 28203704.586.0007(p) 704.586.0373(f)
Photograph 2: Location of the waste oil AST staged in secondary containment
Photograph 3: View of the waste oil AST located in the covered secondary containment area
2923 S. Tryon Street, Suite 100
Charlotte, NC 28203704.586.0007(p) 704.586.0373(f)
Photograph 4: View of the former location of the waste oil AST
TOWN & COUNTRY RENT-A-CAR 5324. INDEPENDENCE BOULEVARDCHARLOTTE, NORTH CAROLINA
Photograph 5: View of the chemical storage area within the Site building
2923 S. Tryon Street, Suite 100
Charlotte, NC 28203704.586.0007(p) 704.586.0373(f)
Photograph 6: View of the retail-sized chemical storage observed within the Site building
TOWN & COUNTRY RENT-A-CAR 5324. INDEPENDENCE BOULEVARDCHARLOTTE, NORTH CAROLINA
Photograph 7: Representative photo of the used oil waste manifest.
2923 S. Tryon Street, Suite 100
Charlotte, NC 28203704.586.0007(p) 704.586.0373(f)
Photograph 8: Representative photo of the used oil waste and used filters manifest.
TOWN & COUNTRY RENT-A-CAR 5324. INDEPENDENCE BOULEVARDCHARLOTTE, NORTH CAROLINA
Appendix B Safety Data Sheets
Safety Data Sheet
Issue Date: 05-Jun-2014 Revision Date: 20-May-2015 Version 1
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1. IDENTIFICATION
Product Identifier
Product Name CARQUEST Premium Hi-Temp Disc Brake Wheel Bearing Grease
Other means of identification
SDS # CQ-037
Recommended use of the chemical and restrictions on use
Recommended Use Lubricant.
Details of the supplier of the safety data sheet
Supplier Address Warren Oil Company 915 E. Jefferson Ave. West Memphis, AR 72301
Emergency Telephone Number
Company Phone Number 1-800-428-9284 Emergency Telephone (24 hr) CHEMTREC 1-800-424-9300 (North America) 1-703-527-3887 (International)
2. HAZARDS IDENTIFICATION
Appearance Amber semi-solid to solid Physical State Semi-solid to solid Odor Mild petroleum Classification
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2 Hazards Not Otherwise Classified (HNOC) May be harmful if swallowed
Signal Word Warning
Hazard Statements Causes skin irritation Causes serious eye irritation
Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear eye/face protection
CQ-037 - CARQUEST Premium Hi-Temp Disc Brake Wheel Bearing Grease
Revision Date: 20-May-2015
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Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water Take off contaminated clothing and wash it before reuse If skin irritation occurs: Get medical advice/attention Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Unknown Acute Toxicity 2.27% of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No Weight-%
Severely Hydrotreated Heavy Naphthenic Petroleum Oil 64742-52-5 60-70
Residual oils (petroleum), solvent refined 64742-01-4 1-10
Antimony diamyldithiocarbamate 15890-25-2 1-10
Lithium Hydroxide Solution 1310-66-3 1-10
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentageof composition has been withheld as a trade secret.**
4. FIRST-AID MEASURES
First Aid Measures
General Advice If exposed or concerned: Get medical advice/attention. Take proper precautions to ensureyour own health and safety before attempting rescue or providing first aid.
Eye Contact Check for and remove contact lenses. Flush eyes with cool, clean, low-pressure wate while occasionally lifting and lowering eyelids. Seek medical attention if excessive tearing,redness or pain persists.
Skin Contact If burned by hot material, cool skin by quenching with large amounts of cool water. Focontact with product at ambient temperatures, remove contaminated shoes and clothing.Wipe off excess material. Wash exposed skin with mild soap and water. Seek medicalattention if tissue appears damaged or if pain or irritation persists. Thoroughly cleancontaminated clothing before reuse. Clean or discard contaminated leather goods. Imaterial is injected under the skin, seek medical attention immediately.
Inhalation Vaporization is not expected at ambient temperatures. This material is not expected tocause inhalation-related disorders under anticipated conditions of use. In case ooverexposure, move the person to fresh air.
Ingestion Do not induce vomiting unless directed to by a physician. Rinse out mouth with water. Never give anything by mouth to a person who is not fully conscious. Allow small quantitiesto pass through the digestive system. If large amounts are swallowed or irritation odiscomfort, seek medical attention immediately.
Most important symptoms and effects
Symptoms May be harmful if swallowed. Causes skin irritation. Causes serious eye irritation.
CQ-037 - CARQUEST Premium Hi-Temp Disc Brake Wheel Bearing Grease
Revision Date: 20-May-2015
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Indication of any immediate medical attention and special treatment needed
Notes to Physician Skin: In the event of injection in underlying tissue, immediate treatment should includeextensive incision, debridement and saline irrigation. Inadequate treatment can result inischemia and gangrene. Early symptoms may be minimal. Ingestion: Check for possible bowel obstruction with ingestion of large quantities of material.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media Use dry chemical, foam, carbon dioxide or water fog.
Unsuitable Extinguishing Media Not determined.
Specific Hazards Arising from the Chemical
Water or foam may cause frothing. Molten material can form flaming droplets if ignited. Use of water on product above 100°C
(212°F) can cause product to expand with explosive force.
Hazardous Combustion Products Carbon dioxide, carbon monoxide, smoke, fumes, unburned hydrocarbons and oxides osulfur, phosphorus, zinc and/ or nitrogen.
Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Carbon dioxide and inert gas can displace oxygen. Use caution when applying carbon dioxide or inert gas inconfined spaces. Fight the fire from a safe distance in a protected location. Open any masses with a water stream to prevent re-ignition due to smoldering. Cool surface with water fog. Do not allow liquid runoff to enter sewers or public waters.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions Take proper precautions to ensure your own health and safety before attempting spillcontrol or clean-up. For more specific information, refer to section 8. Do not touchdamaged containers or spilled material unless wearing appropriate protective clothing.Slipping hazard; do not walk through spilled material.
Methods and material for containment and cleaning up
Methods for Containment Prevent further leakage or spillage if safe to do so. Prevent entry into waterways, sewer, basements or confined areas.
Methods for Clean-Up For small spills, absorb or cover with dry earth, sand or other inert non-combustible absorbent material and place into waste containers for lateral disposal. Contain large spills to maximize product recovery or disposal. In urban areas, clean up spill as soon aspossible. In natural environments, seek clean up advice from specialists to minimizephysical habitat damage.
7. HANDLING AND STORAGE
Precautions for safe handling
CQ-037 - CARQUEST Premium Hi-Temp Disc Brake Wheel Bearing Grease
Revision Date: 20-May-2015
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Advice on Safe Handling If this product is stored or applied in high-pressure systems such as grease guns o hydraulic lines, there is the potential for accidental injection into the skin and underlyingtissues. Empty containers may contain product residue that can ignite with explosive force.Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat,sparks or open flames.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible Materials Strong oxidizing agents.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Severely Hydrotreated Heavy Naphthenic Petroleum Oil 64742-52-5
TWA: 5 mg/m3 (oil mist) STEL: 10 mg/m3 (oil mist) TWA: 5mg/m3 (oil mist) STEL: none estab. TWA: none estab. STEL: none estab.
Antimony diamyldithiocarbamate 15890-25-2 TWA: 0.5 mg/m3 Sb TWA: 0.5 mg/m3 Sb (vacated) TWA: 0.5 mg/m3 Sb IDLH: 50 mg/m3 Sb TWA: 0.5 mg/m3 Sb
Barium Sulfonate 25619-56-1 TWA: 0.5 mg/m3 Ba TWA: 0.5 mg/m3 Ba (vacated) TWA: 0.5 mg/m3 Ba TWA: 0.5 mg/m3 except Barium sulfate Ba
Appropriate engineering controls
Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborneconcentrations of vapors below their respective threshold limit value. Ensure that eyewashstations and safety showers are proximal to the work-station location.
Individual protection measures, such as personal protective equipment
Eye/Face Protection Wear safety glasses with side shields (or goggles).
Skin and Body Protection Chemical resistant, impermeable gloves. Long sleeve shirt and long pants. Aprons. Wear alab coat.
Respiratory Protection Ensure adequate ventilation, especially in confined areas. In case of inadequate ventilationor risk of inhalation of vapors, use suitable respiratory equipment.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical State Semi-solid to solid Appearance Amber semi-solid to solid Odor Mild petroleum Color Amber Odor Threshold Not determined
Property Values Remarks • Method pH Not available Melting Point/Freezing Point Not available Boiling Point/Boiling Range Not available Flash Point 150 °C / 302 °F Open cup Evaporation Rate Not available
CQ-037 - CARQUEST Premium Hi-Temp Disc Brake Wheel Bearing Grease
Revision Date: 20-May-2015
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Flammability (Solid, Gas) Not determined Upper Flammability Limits Not available Lower Flammability Limit Not available Vapor Pressure <01001 kPA (<0.01 mm Hg)(at 20°C)
Vapor Density >10 (Air=1) Specific Gravity 0.93 (Water = 1) Water Solubility Negligible Solubility in other solvents Not determined Partition Coefficient Not determined Property Values Remarks • Method Auto-ignition Temperature Not available Decomposition Temperature Not determined Kinematic Viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined
10. STABILITY AND REACTIVITY
Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions.
Possibility of Hazardous Reactions None under normal processing.
Hazardous Polymerization Not expected to occur.
Conditions to Avoid Keep away from extreme heat, sparks, open flame and incompatible materials.
Incompatible Materials Strong oxidizing agents.
Hazardous Decomposition Products Carbon dioxide, carbon monoxide, smoke, fumes, unburned hydrocarbons and oxides of sulfur, phosphorus, zinc and/ or nitrogen.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Eye Contact Causes serious eye irritation.
Skin Contact Causes skin irritation.
Inhalation Do not inhale.
Ingestion May be harmful if swallowed.
Component Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
CQ-037 - CARQUEST Premium Hi-Temp Disc Brake Wheel Bearing Grease
Revision Date: 20-May-2015
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Lubricating oils (petroleum), hydrotreated spent 64742-58-1
> 2000 mg/kg ( Rat ) > 4480 mg/kg ( Rabbit ) -
Residual oils (petroleum), solvent refined 64742-01-4
> 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) = 2.18 mg/L ( Rat ) 4 h
zelaic acid 123-99-9 > 5 g/kg ( Rat ) - -
Information on physical, chemical and toxicological effects
Symptoms Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Carcinogenicity This product does not contain any carcinogens or potential carcinogens as listed by OSHA,IARC or NTP.
Numerical measures of toxicity Not determined
Unknown Acute Toxicity 2.27% of the mixture consists of ingredient(s) of unknown toxicity.
12. ECOLOGICAL INFORMATION
Ecotoxicity
The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Component Information
Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms Crustacea
Severely Hydrotreated Heavy Naphthenic Petroleum Oil 64742-52-5
5000: 96 h Oncorhynchus mykiss mg/L LC50 1000: 48 h Daphnia magna mg/L EC50
Lubricating oils (petroleum), hydrotreated spent 64742-58-1
79.6: 96 h Brachydanio rerio mg/L LC50 semi-static 3.2: 96 h Pimephales promelas mg/L LC50 semi-static
Residual oils (petroleum), solvent refined 64742-01-4
5000: 96 h Oncorhynchus mykiss mg/L LC50 1000: 48 h Daphnia magna mg/L EC50
Persistence/Degradability Not determined.
Bioaccumulation Not determined.
Mobility Not determined
Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS
CQ-037 - CARQUEST Premium Hi-Temp Disc Brake Wheel Bearing Grease
Revision Date: 20-May-2015
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Waste Treatment Methods
Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations.
California Hazardous Waste Status
Chemical Name California Hazardous Waste Status Antimony diamyldithiocarbamate 15890-25-2 Toxic
14. TRANSPORT INFORMATION
Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.
DOT Not regulated
IATA Not regulated
IMDG Not regulated
15. REGULATORY INFORMATION
International Inventories
Chemical Name TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS
Severely Hydrotreated Heavy Naphthenic Petroleum Oil
Present X Present Present X Present X X
Residual oils (petroleum), solvent refined Present X Present X Present X X
Antimony diamyldithiocarbamate Present X Present Present X X X
Lithium Hydroxide Solution Present X X X
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
US Federal Regulations
CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments andReauthorization Act (SARA) (40 CFR 355).
CQ-037 - CARQUEST Premium Hi-Temp Disc Brake Wheel Bearing Grease
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SARA 313
Chemical Name CAS No Weight-% SARA 313 - Threshold Values % Antimony diamyldithiocarbamate - 15890-25-2 15890-25-2 2.25 1.0
CWA (Clean Water Act)
Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances
Antimony diamyldithiocarbamate X
US State Regulations
California Proposition 65 This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
Antimony diamyldithiocarbamate 15890-25-2 X X
Lithium Hydroxide Solution 1310-66-3 X
Barium Sulfonate 25619-56-1 X X
16. OTHER INFORMATION
NFPA Health Hazards 1
Flammability 1
Instability 0
Special Hazards Not determined HMIS Health Hazards 1
Flammability 1
Physical Hazards 0
Personal Protection Not determined
Issue Date: 05-Jun-2014 Revision Date: 20-May-2015 Revision Note: New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
Product Name: TOYOTA GENUINE ATF WS
Revision Date: 12 May 2016
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SAFETY DATA SHEET
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
PRODUCT
Product Name: TOYOTA GENUINE ATF WS
Product Description: Base Oil and Additives
Product Code: 202030206522, 521377-00, 97Z693
Intended Use: Automatic transmission fluid
COMPANY IDENTIFICATION Supplier: EXXON MOBIL CORPORATION 22777 Springwoods Village Parkway Spring, TX 77253 USA 24 Hour Health Emergency 609-737-4411 Transportation Emergency Phone 800-424-9300 or 703-527-3887 CHEMTREC Product Technical Information 800-662-4525 MSDS Internet Address http://www.exxon.com, http://www.mobil.com
This material is not hazardous according to regulatory guidelines (see (M)SDS Section 15). Other hazard information: HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1910.1200. PHYSICAL / CHEMICAL HAZARDS
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No significant hazards. HEALTH HAZARDS
High-pressure injection under skin may cause serious damage. Excessive exposure may result in eye, skin, or respiratory irritation. ENVIRONMENTAL HAZARDS
No significant hazards.
NFPA Hazard ID: HMIS Hazard ID: NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert
advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person.
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
This material is defined as a mixture. Hazardous Substance(s) or Complex Substance(s) required for disclosure
Name CAS# Concentration* GHS Hazard Codes
ALKYL METHACRYLATE COPOLYMER 63150-07-2 1 - < 5% H319(2A)
ALKYL THIOPHOSPHITES Confidential 0.1 - < 1% H312, H314(1B), H400(M factor 10),
H410(M factor 10)
CATALYTIC DEWAXED LIGHT PARAFFINIC OIL (PETROLEUM) 64742-71-8 20 - < 30% H304
LUBRICATING OILS (PETROLEUM), HYDROTREATED NEUTRAL OIL-BASED 72623-86-0 30 - < 40% H304
SEVERELY HYDROTREATED HEAVY PARAFFINIC DISTILLATE 64742-54-7 20 - < 30% H304
* All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume. As per paragraph (i) of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity and exact percentage (concentration) of composition may have been withheld. Specific chemical identity and exact percentage composition will be provided to health professionals, employees, or designated representatives in accordance with applicable provisions of paragraph (i). SECTION 4 FIRST AID MEASURES INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
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immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the
body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.
EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5 FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames. Inappropriate Extinguishing Media: Straight Streams of Water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams,
sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Aldehydes, Incomplete combustion products, Oxides of carbon, Smoke, Fume, Sulfur oxides FLAMMABILITY PROPERTIES Flash Point [Method]: >175°C (347°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D
SECTION 6 ACCIDENTAL RELEASE MEASURES
NOTIFICATION PROCEDURES
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In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. US regulations require reporting releases of this material to the environment which exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The
National Response Center can be reached at (800)424-8802. PROTECTIVE MEASURES Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending
on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or
anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended. SPILL MANAGEMENT Land Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other
shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants.
Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7 HANDLING AND STORAGE HANDLING Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present (e.g., during switch-loading operations). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from
static accumulation. Consult local applicable standards for guidance. Additional references include American
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Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator. STORAGE
The type of container used to store the material may affect static accumulation and dissipation. Do not store in open or unlabelled containers. Keep away from incompatible materials.
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMIT VALUES Exposure limits/standards (Note: Exposure limits are not additive)
Substance Name Form Limit / Standard NOTE Source
CATALYTIC DEWAXED LIGHT PARAFFINIC OIL (PETROLEUM) Mist. TWA 5 mg/m3 N/A OSHA Z1
CATALYTIC DEWAXED LIGHT
PARAFFINIC OIL (PETROLEUM) Inhalable
fraction. TWA 5 mg/m3 N/A ACGIH
CATALYTIC DEWAXED LIGHT PARAFFINIC OIL (PETROLEUM) Mist. TWA 5 mg/m3 N/A ACGIH
LUBRICATING OILS (PETROLEUM), HYDROTREATED NEUTRAL OIL-BASED
Inhalable fraction. TWA 5 mg/m3 N/A ACGIH
SEVERELY HYDROTREATED HEAVY PARAFFINIC DISTILLATE Inhalable fraction. TWA 5 mg/m3 N/A ACGIH
SEVERELY HYDROTREATED HEAVY PARAFFINIC DISTILLATE Mist. TWA 5 mg/m3 N/A ACGIH
Exposure limits/standards for materials that can be formed when handling this product: When mists/aerosols
can occur the following are recommended: 5 mg/m³ - ACGIH TLV (inhalable fraction), 5 mg/m³ - OSHA PEL.
NOTE: Limits/standards shown for guidance only. Follow applicable regulations.
No biological limits allocated.
ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider:
No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION
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Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use.
Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good
industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and
soil. Protect the environment by applying appropriate control measures to prevent or limit emissions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION Physical State: Liquid
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Color: Red Odor: Characteristic Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 °C): 0.85 [ASTM D4052] Flammability (Solid, Gas): N/A Flash Point [Method]: >175°C (347°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316°C (600°F) Decomposition Temperature: N/D Vapor Density (Air = 1): > 2 at 101 kPa Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C Evaporation Rate (n-butyl acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 23 cSt (23 mm2/sec) at 40 °C | 5.45 cSt (5.45 mm2/sec) at 100°C [ASTM D 445] Oxidizing Properties: See Hazards Identification Section. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A DMSO Extract (mineral oil only), IP-346: < 3 %wt
SECTION 10 STABILITY AND REACTIVITY
REACTIVITY: See sub-sections below. STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur.
SECTION 11 TOXICOLOGICAL INFORMATION
INFORMATION ON TOXICOLOGICAL EFFECTS
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Inhalation
Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components.
Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures.
Ingestion
Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components.
Skin
Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components.
Skin Corrosion/Irritation: No end point data
for material. Negligible irritation to skin at ambient temperatures. Based on
assessment of the components. Eye
Serious Eye Damage/Irritation: No end point
data for material. May cause mild, short-lasting discomfort to eyes. Based on
assessment of the components. Sensitization
Respiratory Sensitization: No end point data
for material. Not expected to be a respiratory sensitizer.
Skin Sensitization: No end point data for material. Not expected to be a skin sensitizer. Based on assessment of the components.
Aspiration: Data available. Not expected to be an aspiration hazard. Based on physico-chemical properties of the material. Germ Cell Mutagenicity: No end point data for material. Not expected to be a germ cell mutagen. Based on assessment of the components.
Carcinogenicity: No end point data for material. Not expected to cause cancer. Based on assessment of the components. Reproductive Toxicity: No end point data for material. Not expected to be a reproductive toxicant. Based on assessment of the components.
Lactation: No end point data for material. Not expected to cause harm to breast-fed children.
Specific Target Organ Toxicity (STOT)
Single Exposure: No end point data for material. Not expected to cause organ damage from a single exposure.
Repeated Exposure: No end point data for material. Not expected to cause organ damage from prolonged or repeated exposure. Based on assessment of the components. OTHER INFORMATION Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of
immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals.
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The following ingredients are cited on the lists below: None.
SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY
Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL
Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13 DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It
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does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated.
Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken
for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14 TRANSPORT INFORMATION
LAND (DOT): Not Regulated for Land Transport LAND (TDG): Not Regulated for Land Transport SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code
Marine Pollutant: No
AIR (IATA): Not Regulated for Air Transport
SECTION 15 REGULATORY INFORMATION
OSHA HAZARD COMMUNICATION STANDARD: This material is not considered hazardous in accordance with
OSHA HazCom 2012, 29 CFR 1910.1200. Listed or exempt from listing/notification on the following chemical inventories: AICS, DSL, IECSC, KECI, PICCS, TSCA
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302 SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic Release Program.
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The following ingredients are cited on the lists below:
Chemical Name CAS Number List Citations
Code key: CARC=Carcinogen; REPRO=Reproductive
N/D = Not determined, N/A = Not applicable KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only): H304: May be fatal if swallowed and enters airways; Aspiration, Cat 1 H312: Harmful in contact with skin; Acute Tox Dermal, Cat 4 H314(1B): Causes severe skin burns and eye damage; Skin Corr/Irritation, Cat 1B H319(2A): Causes serious eye irritation; Serious Eye Damage/Irr, Cat 2A H400: Very toxic to aquatic life; Acute Env Tox, Cat 1 H410: Very toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 1 THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:
Composition: Component Table information was modified. Section 13: Disposal Considerations - Disposal Recommendations information was modified. Section 16: MSN, MAT ID information was modified. ----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is
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included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for
convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest.
-----------------------------------------------------------------------------------------------------------------------------------------------------
DGN: 7010438XUS (1025004) ----------------------------------------------------------------------------------------------------------------------------------------------------- Copyright 2002 Exxon Mobil Corporation, All rights reserved
SAFETY DATA SHEET
1. Identification
LPS® 3 (Aerosol)Product identifier
Other means of identification
00316Part Number
A specialized soft-film spray coating designed to prevent rust and corrosion on steel, aluminumand other metals.Recommended use
None known.Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Manufacturer
Company name ITW Pro Brands
Address 4647 Hugh Howell Rd.
Tucker, GA 30084
Country (U.S.A.)
Tel: +1 770-243-8800
In Case of Emergency 1-800-424-9300 (inside U.S.)
+001 703-527-3887 (outside U.S.)
Website www.lpslabs.com
E-mail lpssds@itwprobrands.com
2. Hazard(s) identification
Category 1Flammable aerosolsPhysical hazards
Compressed gasGases under pressure
Category 2Skin corrosion/irritationHealth hazards
Category 2ASerious eye damage/eye irritation
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Not classified.Environmental hazards
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes skinirritation. Causes serious eye irritation. May cause drowsiness or dizziness.
Precautionary statement
Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an openflame or other ignition source. Do not pierce or burn, even after use. Avoid breathing gas. Useonly outdoors or in a well-ventilated area. Wash thoroughly after handling. Wear protective glovesand eye/face protection.
Response If swallowed: Call a poison center/doctor if you feel unwell. Rinse mouth. If inhaled: Removeperson to fresh air and keep comfortable for breathing. Call a POISON CENTER ordoctor/physician if you feel unwell. If in eyes: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Getmedical advice/attention. If on skin: Wash with plenty of water. Take off contaminated clothingand wash it before reuse. If skin irritation occurs: Get medical advice/attention.
Storage Keep container tightly closed. Store in a well-ventilated place. Store locked up. Protect fromsunlight. Do not expose to temperatures exceeding 50°C/122°F.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
1 / 10
Material name: LPS® 3 (Aerosol)
00316 Version #: 04 Revision date: 07-11-2017 Issue date: 10-14-2015
SDS US
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information None known.
3. Composition/information on ingredients
Mixtures
64742-47-8Distillates Petroleum HydrotreatedLight 50 - 60
5131-66-81-butoxy-2-propanol 1 - 10
67-64-1Acetone 1 - 10
64742-54-7Distillates Petroleum HydrotreatedHeavy 1 - 10
124-38-9Carbon Dioxide 1 - 5
471-34-1Calcium Carbonate 0.1 - 1
64742-82-1Hydrodesulferized Heavy PetroleumNaptha 0.1 - 1
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
4. First-aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen orartificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance.Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or otherproper respiratory medical device. Call a POISON CENTER or doctor/physician if you feel unwell.
Inhalation
In case of contact, immediately flush skin with plenty of water for at least 15 minutes whileremoving contaminated clothing and shoes. Get medical attention if irritation develops andpersists.
Skin contact
Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses.Get medical attention if irritation develops and persists.Eye contact
Call a physician or poison control center immediately. Only induce vomiting at the instruction ofmedical personnel. Never give anything by mouth to an unconscious person. If vomiting occurs,keep head low so that stomach content doesn't get into the lungs.
Ingestion
Irritant effects. Symptoms may include stinging, tearing, redness, swelling, and blurred vision.Defatting of the skin. Rash. Symptoms of overexposure can include shortness of breath,drowsiness, headaches, confusion, decreased coordination, visual disturbances and vomiting, andare reversible if exposure is stopped.
Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically. In case of shortness of breath,give oxygen. Keep victim under observation. Symptoms may be delayed.Indication of immediate
medical attention and special
treatment needed
In the case of accident or if you feel unwell, seek medical advice immediately (show the label
precautions to protect themselves.
General information
5. Fire-fighting measures
Powder. Alcohol resistant foam. Carbon dioxide (CO2).Suitable extinguishing media
Do not use a solid water stream as it may scatter and spread fire.Unsuitable extinguishing
media
Contents under pressure. Pressurized container may explode when exposed to heat or flame.Specific hazards arising from
the chemical
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA.Special protective equipment
and precautions for firefighters
Move containers from fire area if you can do so without risk. Containers should be cooled with
holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Water runoff can causeenvironmental damage.
Fire fighting
equipment/instructions
Use standard firefighting procedures and consider the hazards of other involved materials. Movecontainer from fire area if it can be done without risk. In the event of fire and/or explosion do notbreathe fumes.
Specific methods
Extremely flammable aerosol.General fire hazards
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6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out oflow areas. Wear appropriate personal protective equipment. Do not touch damaged containers orspilled material unless wearing appropriate protective clothing. Ventilate closed spaces beforeentering them. Local authorities should be advised if significant spillages cannot be contained. Usepersonal protection recommended in Section 8 of the SDS.
Personal precautions,
protective equipment and
emergency procedures
Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (nosmoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.)away from spilled material. The product is immiscible with water and will spread on the watersurface. Stop leak if you can do so without risk. Isolate area until gas has dispersed. Collectspillage. Use water spray to reduce vapors or divert vapor cloud drift. Prevent entry into
Methods and materials for
containment and cleaning up
Avoid release to the environment. Contact local authorities in case of spillage to drain/aquaticenvironment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoiddischarge into drains, water courses or onto the ground.
Environmental precautions
7. Handling and storage
Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missingor defective. Do not spray on a naked flame or any other incandescent material. Do not smoke
expose containers to heat, flame, sparks, or other sources of ignition. All equipment used whenhandling the product must be grounded. Avoid breathing gas. Avoid contact with skin. Avoidcontact with eyes. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriatepersonal protective equipment. Observe good industrial hygiene practices. Wash hands thoroughlyafter handling. Avoid release to the environment.
Precautions for safe handling
Level 3 Aerosol.
Pressurized container. Protect from sunlight and do not expose to temperatures exceeding50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame,heat or other sources of ignition. Store locked up.
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
ValueComponents FormType
PEL 5 mg/m3 Oil mistDistillates PetroleumHydrotreated Light (CAS64742-47-8)
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueComponentsType
PEL 2400 mg/m3Acetone (CAS 67-64-1)
1000 ppm
PEL 9000 mg/m3Carbon Dioxide (CAS124-38-9)5000 ppm
ACGIH
ValueComponents FormType
TWA 5 mg/m3 Oil mistDistillates PetroleumHydrotreated Light (CAS64742-47-8)
US. ACGIH Threshold Limit Values
ValueComponentsType
STEL 500 ppmAcetone (CAS 67-64-1)
TWA 250 ppm
STEL 30000 ppmCarbon Dioxide (CAS124-38-9)
TWA 5000 ppm
US. NIOSH: Pocket Guide to Chemical Hazards
ValueComponents FormType
TWA 590 mg/m3Acetone (CAS 67-64-1)
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US. NIOSH: Pocket Guide to Chemical Hazards
ValueComponents FormType
250 ppm
TWA 5 mg/m3 Respirable.Calcium Carbonate (CAS471-34-1)10 mg/m3 Total
STEL 54000 mg/m3Carbon Dioxide (CAS124-38-9)30000 ppm
TWA 9000 mg/m3
5000 ppm
Biological limit values
ValueComponents Determinant Specimen Sampling Time
25 mg/l Acetone Urine *Acetone (CAS 67-64-1)
* - For sampling details, please see the source document.
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation ratesshould be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,or other engineering controls to maintain airborne levels below recommended exposure limits. Ifexposure limits have not been established, maintain airborne levels to an acceptable level.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Wear safety glasses with side shields (or goggles). Eye wash fountain is recommended.Eye/face protection
Skin protection
Chemical resistant gloves are recommended.Hand protection
Avoid contact with clothing. Wear suitable protective clothing. Chemical resistant gloves.Other
No personal respiratory protective equipment normally required. Use a positive-pressureair-supplied respirator if there is any potential for an uncontrolled release, exposure levels are notknown, or any other circumstances where air-purifying respirators may not provide adequateprotection.
Respiratory protection
Not applicable.Thermal hazards
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, suchas washing after handling the material and before eating, drinking, and/or smoking. RoutinelyGeneral hygiene
considerations
9. Physical and chemical properties
Cloudy. Liquid.Appearance
Gas.Physical state
Aerosol.Form
Brown.Color
Mild. Cherry.Odor
Odor threshold Not available.
pH Not applicable
Melting point/freezing point Not available.
Initial boiling point and boiling
range
Not available.
Flash point 64.4 °F (18.0 °C) Tag Closed Cup
Evaporation rate 151 (Ethyl Ether)
Flammable gas.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
0.6 %
Flammability limit - upper
(%)
6 %
Explosive limit - lower (%)Not available.
Explosive limit - upper (%)Not available.
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Vapor pressure Not available.
Vapor density Not available.
Relative density Not available.
Solubility(ies)
Solubility (water)Not available.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature 446 °F (230 °C)
Decomposition temperature Not available.
Viscosity Not available.
Other information
Density 7.28 lb/gal
Percent volatile 63 - 82 %
Specific gravity 0.87
VOC 62.8 % per U.S. State and Federal Consumer Product Regulations
10. Stability and reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity
Material is stable under normal conditions.Chemical stability
Hazardous polymerization does not occur.Possibility of hazardous
reactions
Avoid temperatures exceeding the flash point.Conditions to avoid
Strong oxidizing agents.Incompatible materials
Upon decomposition this product emits acrid dense smoke with carbon dioxide, carbon monoxide,Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
May cause drowsiness and dizziness.
Skin contact Causes skin irritation.
Eye contact Causes serious eye irritation.
Ingestion May cause discomfort if swallowed. However, ingestion is not likely to be a primary route ofoccupational exposure.
Symptoms related to the
physical, chemical and
toxicological characteristics
Irritating to eyes, respiratory system and skin. Symptoms may include stinging, tearing, redness,swelling, and blurred vision.
Information on toxicological effects
Test ResultsComponentsSpecies
1-butoxy-2-propanol (CAS 5131-66-8)
Dermal
Acute
LD50 Rabbit 1400 mg/kg, 24 Hours
Oral
LD50 Rat > 2000 mg/kg
Calcium Carbonate (CAS 471-34-1)
Dermal
Acute
LD50 Rat > 2000 mg/kg, 24 Hours
Oral
LD50 Rat > 2000 mg/kg
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Test ResultsComponentsSpecies
Distillates Petroleum Hydrotreated Heavy (CAS 64742-54-7)
Dermal
Acute
LD50 Rabbit > 2000 mg/kg
Inhalation
LC50 Rat > 3.9 mg/l, 4 Hours
Oral
LD50 Rat > 2000 mg/kg
Distillates Petroleum Hydrotreated Light (CAS 64742-47-8)
Dermal
Acute
LD50 Rabbit > 2000 mg/kg
Inhalation
LC50 Rat > 4.5 mg/l, 4 Hours
Vapor
Hydrodesulferized Heavy Petroleum Naptha (CAS 64742-82-1)
Dermal
Acute
LD50 Rabbit > 1900 mg/kg, 24 Hours
Oral
LD50 Rat 4820 mg/kg
Causes skin irritation.Skin corrosion/irritation
Causes serious eye irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Not a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitization
No data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.Germ cell mutagenicity
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
ACGIH Carcinogens
Acetone (CAS 67-64-1)A4 Not classifiable as a human carcinogen.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity -
single exposure
Narcotic effects.
Specific target organ toxicity -
repeated exposure
Not classified.
Aspiration hazard Not likely, due to the form of the product.
Chronic effects Prolonged inhalation may be harmful.
12. Ecological information
Not expected to be harmful to aquatic organisms.Ecotoxicity
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Components Test ResultsSpecies
Acetone (CAS 67-64-1)
Aquatic
EC50Crustacea 10294 - 17704 mg/l, 48 hoursWater flea (Daphnia magna)
LC50Fish 4740 - 6330 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss)
Calcium Carbonate (CAS 471-34-1)
Aquatic
LC50Fish > 56000 mg/l, 96 hoursWestern mosquitofish (Gambusia affinis)
Distillates Petroleum Hydrotreated Light (CAS 64742-47-8)
Aquatic
LC50Fish 2.9 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss)
Not inherently biodegradable.Persistence and degradability
No data available for this product.Bioaccumulative potential
Acetone -0.24
Not available.Mobility in soil
None known.
13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contentsunder pressure. Do not puncture, incinerate or crush. This material and its container must bedisposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Donot contaminate ponds, waterways or ditches with chemical or used container. Dispose ofcontents/container in accordance with local/regional/national/international regulations.
Disposal instructions
D001: Waste Flammable material with a flash point <140 FD003: Waste Reactive materialHazardous waste code
Dispose of in accordance with local regulations. Empty containers or liners may retain someproduct residues. This material and its container must be disposed of in a safe manner (see:Disposal instructions).
Waste from residues / unused
products
Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied. Do not re-use empty containers.
Contaminated packaging
14. Transport information
DOT
UN1950UN number
Aerosols, flammableUN proper shipping name
2.1Class
Transport hazard class(es)
-Subsidiary risk 2.1Label(s)
Not available.Packing group
NoMarine pollutant
Environmental hazards
Not available.Special precautions for user
N82Special provisions
306Packaging exceptions
NonePackaging non bulk
NonePackaging bulk
IATA
UN1950UN number
Aerosols, flammableUN proper shipping name
2.1Class
Transport hazard class(es)
-Subsidiary risk
2.1Label(s)
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Not available.Packing group
No.Environmental hazards
Not available.Special precautions for user
Allowed with restrictions.Passenger and cargo
aircraft
Other information
Allowed with restrictions.Cargo aircraft only
IMDG
UN1950UN number
Aerosols, flammableUN proper shipping name
2.1Class
Transport hazard class(es)
-Subsidiary risk
2.1Label(s)
Not available.Packing group
NoMarine pollutant
Environmental hazards
Not available.EmS
Not available.Special precautions for user
Not available.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
DOT
IATA; IMDG
15. Regulatory information
This product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Acetone (CAS 67-64-1)Listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
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Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - YesDelayed Hazard - NoFire Hazard - YesPressure Hazard - YesReactivity Hazard - No
Hazard categories
SARA 302 Extremely hazardous substance
Not listed.
YesSARA 311/312 Hazardous
chemical
SARA 313 (TRI reporting)Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Not regulated.Safe Drinking Water Act
(SDWA)
Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and
Chemical Code Number
Acetone (CAS 67-64-1)6532
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))
Acetone (CAS 67-64-1)35 %WV
DEA Exempt Chemical Mixtures Code Number
Acetone (CAS 67-64-1)6532
FEMA Priority Substances Respiratory Health and Safety in the Flavor Manufacturing Workplace
Acetone (CAS 67-64-1)Low priority
US state regulations
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd.
(a))
Acetone (CAS 67-64-1)Distillates Petroleum Hydrotreated Heavy (CAS 64742-54-7)Hydrodesulferized Heavy Petroleum Naptha (CAS 64742-82-1)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
NoAustraliaAustralian Inventory of Chemical Substances (AICS)
YesCanadaDomestic Substances List (DSL)
NoCanadaNon-Domestic Substances List (NDSL)
NoChinaInventory of Existing Chemical Substances in China (IECSC)
NoEuropeEuropean Inventory of Existing Commercial ChemicalSubstances (EINECS)
NoEuropeEuropean List of Notified Chemical Substances (ELINCS)
NoJapanInventory of Existing and New Chemical Substances (ENCS)
NoKoreaExisting Chemicals List (ECL)
NoNew Zealand New Zealand Inventory
NoPhilippinesPhilippine Inventory of Chemicals and Chemical Substances(PICCS)
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
country(s).
16. Other information, including date of preparation or last revision
10-14-2015Issue date
07-11-2017Revision date
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SDS US
Version #04
The information provided in this Safety Data Sheet is correct to the best of our knowledge,information and belief at the date of its publication. The information given is designed only as aguidance for safe handling, use, processing, storage, transportation, disposal and release and isnot to be considered a warranty or quality specification. The information relates only to the specificmaterial designated and may not be valid for such material used in combination with any othermaterials or in any process, unless specified in the text.
Disclaimer
Hazard(s) identification: Hazard statementHazard(s) identification: PreventionHazard(s) identification: ResponseHazard(s) identification: StorageComposition / Information on Ingredients: Disclosure OverridesRegulatory Information: Risk Phrases - LabelingGHS: Classification
Revision information
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MATERIAL SAFETY DATA SHEET
SLICK 50® ENGINE TREATMENT FOR HIGH MILEAGE VEHICLES
1. PRODUCT AND COMPANY IDENTIFICATION MSDS Number: 24400
Version Date: 05/29/01
Product Name: SLICK 50® ENGINE TREATMENT FOR HIGH MILEAGE VEHICLES
Product Use: Engine treatment
Synonyms: 50101015, 50106015
Company Information
SOPUS Products
P.O. Box 4427
Houston, TX 77210-4427
USA
Phone Numbers
Medical Emergency: 1-800-546-6040
Transportation Emergency (USA): 1-800-424-9300
Transportation Emergency (International):
1-703-527-3887(Call Collect)
MSDS Assistance: 1-800-546-6227
Fax On Demand: 1-800-546-6227
Technical Assistance: 1-800-458-4998
Customer Service: 1-800-468-8397
Fax Number: 713-217-3181
Internet Address: www.MSDS.PZLQS.com
______________________________________________________________________________________
2. COMPONENT INFORMATION
Component CAS No. Weight Percent
Range
Hazardous
in Blend
SOLVENT-DEWAXED HEAVY PARAFFINIC
DISTILLATE
64742-65-0 > 80 No
ANTIWEAR RUST & OXIDATION MIXTURE MIXTURE < 10 No
PROPRIETARY MIXTURE TRADESECRET < 10 No
Under normal conditions of use or in a foreseeable emergency, this product does not meet the definition of
a hazardous chemical when evaluated according to the OSHA Hazard Communication Standard, 29 CFR
1910.1200.
Other: No information available
___________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Emergency and Hazards Overview
CAUTION: Contains Petroleum Lubricant. Repeated skin contact can cause skin disorders.
ATTENTION: Used motor oil is a possible skin cancer hazard based on animal data. Repeated exposure
to oil mist in excess of the OSHA limit (5mg/m3) can result in accumulation of oil droplets in pulmonary
tissue.
NFPA Ratings: Health 1 Flammability 1 Reactivity 0
Primary Route of Exposure: Skin X Inhalation -- Eye --
Health Effect Information
Eye Contact: This product is practically non-irritating to the eyes upon direct contact. Based on testing
of similar products and/or components.
Skin Contact: Avoid skin contact. This product is minimally irritating to the skin upon direct contact.
Based on testing of similar products and/or components. Prolonged or repeated contact may result
in contact dermatitis which is characterized by dryness, chapping, and reddening. Prolonged or
repeated contact may result in oil acne which is characterized by blackheads with possible
secondary infection. Avoid prolonged and repeated skin contact with used motor oils. See Section
11 - Toxicological Information.
MATERIAL SAFETY DATA SHEET
MSDS Number: 24400 SLICK 50® ENGINE TREATMENT FOR HIGH MILEAGE
VEHICLES Page 2 of 7
Inhalation: This product has a low vapor pressure and is not expected to present an inhalation hazard at
ambient conditions. Caution should be taken to prevent aerosolization or misting of this product.
On rare occasions, prolonged and repeated exposure to oil mist poses a ris k of pulmonary disease
such as chronic lung inflammation. Signs of respiratory effects vary with concentration and length
of exposure and include nasal discharge, sore throat, coughing, bronchitis, pulmonary edema and
difficulty breathing. Shortness of breath and cough are the most common symptoms.
Ingestion: Do not ingest. This product is relatively non-toxic by ingestion. This product has laxative
properties and may result in abdominal cramps and diarrhea. Exposure to a large single dose, or
repeated smaller doses, may lead to lung aspiration, which can lead to lipid pneumonia or chronic
lung inflammation. These are low-grade, chronic localized tissue reactions.
Medical Conditions Aggravated by Exposure: Drying and chapping may make the skin more susceptible
to other irritants, sensitizers and disease.
Other: No information available
___________________________________________________________________________________
4. FIRST AID INFORMATION
Eye Contact: Immediately flush eyes with large amounts of water and continue flushing until irritation
subsides. If irritation persists, seek medical attention.
Skin Contact: No treatment is necessary under ordinary circumstances. Remove contaminated clothing.
Wash contaminated area thoroughly with soap and water. If material is hot, submerge injured area
in cold water. If victim is severely burned, remove to a hospital immediately.
Inhalation: This material does not present any known inhalation hazard. No treatment is necessary under
ordinary circumstances.
Ingestion: No treatment is necessary under ordinary circumstances. Do not induce vomiting. If victim
exhibits signs of lung aspiration such as coughing or choking, seek immediate medical assistance.
Notes to Physician: No information available
Other: No information available
______________________________________________________________________________________
5. FIRE AND EXPLOSION INFORMATION
Flammable Properties
Flash Point: >375 F, >190.6 C Test Method: ASTM D-92 (C.O.C.)
Flammable Limits in Air
Upper Percent: No data available
Lower Percent: No data available
Autoignition Temperature: No data available Test Method: No information available
NFPA Classification: Class III-B combustible liquid
Extinguishing Media: Use dry chemical, foam, or carbon dioxide.
Fire Fighting Measures
Special Fire Fighting Procedures and Equipment: No special fire fighting procedures are required.
Unusual Fire and Explosion Conditions: Dense smoke may be generated while burning. Carbon
monoxide, carbon dioxide, and other oxides may be generated as products of combustion.
MATERIAL SAFETY DATA SHEET
MSDS Number: 24400 SLICK 50® ENGINE TREATMENT FOR HIGH MILEAGE
VEHICLES Page 3 of 7
Hazardous Combustion By-Products: None
Other: No information available
______________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Personnel Safeguards: Consult Health Effect Information in Section 3, Personal Protection Information in
Section 8, Fire and Explosion Information in Section 5, and Stability and Reactivity Information
in Section 10.
Regulatory Notifications: No notification required
Containment and Clean up: No special cleanup procedures are necessary. Do not allow spill to enter
sewers or watercourses. Small spills may be picked up with absorbent material.
Other: No information available
______________________________________________________________________________________
7. HANDLING AND STORAGE INFORMATION
Handling: No special handling procedures are necessary.
Storage: Do not transfer to unmarked containers. Store in closed containers away from heat, sparks, open
flame, or oxidizing materials.
Empty Container Warnings
Drums: Not applicable
Plastic: Do not reuse this container. Empty container may retain product residues.
Other: No information available
______________________________________________________________________________________
8. EXPOSURE CONTROLS / PERSONAL PROTECTION INFORMATION
Exposure Limits and Guidelines
This product does not contain any components with OSHA or ACGIH exposure limits.
Personal Protective Equipment
Eye/Face Protection: Eye protection is not required under conditions of normal use. If material is
handled such that it could be sprayed into eyes, wear plastic face shield or splash-proof safety
goggles.
Skin Protection: Skin protection is not required under conditions of normal use. Launder soiled clothes.
Respiratory Protection: Respiratory protection is not required under conditions of normal use.
Personal Hygiene: Consumption of food and beverage should be avoided in work areas where this product
is present. Always wash hands and face with soap and water before eating, drinking, or smoking.
Engineering Controls / Work Practices
Ventilation: General room ventilation is normally sufficient.
Other: No information available
MATERIAL SAFETY DATA SHEET
MSDS Number: 24400 SLICK 50® ENGINE TREATMENT FOR HIGH MILEAGE
VEHICLES Page 4 of 7
______________________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Amber oil
Odor: No information available Vapor Pressure: No data available
Physical state: Liquid Vapor Density (air=1): > 1
pH: No data available Percent Volatile by Volume: No data available
Boiling Point: No data available Volatile Organic Content: No data available
Melting Point: No data available Molecular Weight: No data available
Specific Gravity: 0.87 Average Carbon Number: No data available
Pour Point: No data available Viscosity @ 100 F: > 4300 SUS
Viscosity @ 40 C: No data available
Solubility in Water: Negligible in water
Octanol / Water Coefficient: Log Kow = No data available
______________________________________________________________________________________
10. STABILITY AND REACTIVITY INFORMATION
Chemical Stability: Stable
Conditions to Avoid: High heat and open flames.
Incompatible Materials to Avoid: May react with strong oxidizing agents.
Other: No information available
______________________________________________________________________________________
11. TOXICOLOGICAL INFORMATION
Primary Eye Irritation: No information available
Primary Skin Irritation: No information available
Acute Dermal Toxicity: No information available
Subacute Dermal Toxicity: No information available
Dermal Sensitization: No information available
Inhalation Toxicity: No information available
Inhalation Sensitization: No information available
Oral Toxicity: No information available
Mutagenicity: No information available
Carcinogenicity: The International Agency for Research on Cancer (IARC) has concluded that there is
inadequate data to evaluate the carcinogenicity to experimental animals of this class of product.
IARC has concluded there is sufficient evidence that used gasoline-engine motor oils produce skin
tumors in experimental animals. Also, IARC has determined this class of products belongs to
Group 3-"not classifiable as to its carcinogenicity to humans".
MATERIAL SAFETY DATA SHEET
MSDS Number: 24400 SLICK 50® ENGINE TREATMENT FOR HIGH MILEAGE
VEHICLES Page 5 of 7
Reproductive and Developmental Toxicity: No information available
Teratogenicity: No information available
Immunotoxicity: No information available
Neurotoxicity: No information available
Other: No information available
______________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Aquatic Toxicity: No information available
Terrestrial Toxicity: No information available
Chemical Fate and Transport: No information available
Other: No information available
______________________________________________________________________________________
13. DISPOSAL INFORMATION
Regulatory Information: Dispose of residual products and empty containers responsibly.
Waste Disposal Methods: Waste material may be landfilled or incinerated at an approved facility.
Other: No information available
______________________________________________________________________________________
14. TRANSPORTATION INFORMATION
U.S. Department of Transportation (DOT)
Highway / Rail (Bulk): Not Regulated
Highway / Rail (Non-Bulk): Not Regulated
For US shipments, US DOT law requires the shipper to determine the proper shipping description
of the material that is being shipped. The shipping information and description contained in this
section may not be suitable for all shipments of this material, but may help the shipper determine
the proper shipping description for a particular shipment.
International Information
Vessel: IMDG Regulated: -- IMDG Not Regulated: X
Air: ICAO Regulated: -- ICAO Not Regulated: X
Other: No information available
______________________________________________________________________________________
15. Regulatory Information
Regulatory Lists Searched: The components listed in Section 2 of this MSDS were compared to
substances that appear on the following regulatory lists. Each list is numerically identified. See
Regulatory Search Results below.
Health & Safety: 10 - IARC carcinogen, 11 - NTP carcinogen, 12 - OSHA carcinogen, 15 - ACGIH TLV,
16 - OSHA PEL, 17 - NIOSH exposure limit, 20 - US DOT Appendix A, Hazardous substances, 22 - FDA
21 CFR Total food additives, 23 - NFPA 49 or 325
MATERIAL SAFETY DATA SHEET
MSDS Number: 24400 SLICK 50® ENGINE TREATMENT FOR HIGH MILEAGE
VEHICLES Page 6 of 7
Environmental: 30 - CAA 1990 Hazardous air pollutants, 31 - CAA Ozone depletors, 33 - CAA HON
rule, 34 - CAA Toxic substance for accidental release prevention, 35 - CAA Volatile organic compounds
(VOC's) in SOCMI, 41 - CERCLA / SARA Section 302 extremely hazardous substances, 42 - CERCLA /
SARA Section 313 emissions reporting, 43 - CWA Hazardous substances, 44 - CWA Priority pollutants, 45
- CWA Toxic pollutants, 46 - EPA Proposed test rule for hazardous air pollutants, 47 - RCRA Basis for
listing - Appendix VII, 48 - RCRA waste, 49 - SDWA - (S)MCLs
International: 50 - Canada - WHMIS Classification of substance, 54 - Mexico - Drinking water -
ecological criteria, 55 - Mexico - Wastewater discharges, 56 - US -TSCA Section (12)(b) - export
notification
State Lists: 60 - CA - Proposition 65, 61 - FL - Substances, 62 - MI - Critical materials, 63 - MA - RTK,
64 - MA - Extraordinarily hazardous substances, 65 - MN - Hazardous substances, 66 - PA - RTK, 67 - NJ
- RTK, 68 - NJ - Environmental hazardous substances, 69 - NJ - Special hazardous substances
Inventories: 80 - Canada - Domestic substances , 81 - European - EINECS, 82 - Japan - ENCS, 83 - Korea
- Existing and evaluated chemical substances, 84 - US - TSCA , 85 - China Inventory
Regulatory Search Results:
SOLVENT-DEWAXED HEAVY PARAFFINIC DISTILLATE: 80, 81, 83, 84, 85
U.S. TSCA Inventory: All components of this material are on the US TSCA Inventory.
SARA Section 313: This product is not known to contain any SARA, Title III, Section 313 Reportable
Chemicals at or greater than 1.0% (0.1% for carcinogens).
IARC: No information available
SARA 311 / 312 Categories
Acute: --Chronic: --Fire: --Pressure: --Reactive: --
Not Regulated: X
Canadian WHMIS Classification
Not a controlled substance under WHMIS
European Union Classification
Hazard Symbols:
No classification recommended
Risk Phrases:
No classification recommended
Safety Phrases:
No classification recommended
Other: No information available
______________________________________________________________________________________
16. OTHER INFORMATION
Health and Environmental Label Language
WARNING: Continuous contact with used gasoline engine oils has caused skin cancer in animal
tests.
ATTENTION: Prolonged or repeated skin contact may cause oil acne or dermatitis. Repeated
exposure to oil mist in excess of the OSHA limit (5mg/m3 can result in accumulation of oil
droplets in pulmonary tissue.
Precautionary Measures: Avoid prolonged or repeated contact with eyes, skin and clothing.
Avoid generation and inhalation of oil mists.
MATERIAL SAFETY DATA SHEET
MSDS Number: 24400 SLICK 50® ENGINE TREATMENT FOR HIGH MILEAGE
VEHICLES Page 7 of 7
First Aid: Skin Contact: Wash skin with soap and water. Launder soiled clothes and discard oil-
soaked shoes. If irritation persists seek medical attention. Eye Contact: Flush with water. If
irritation persists seek medical attention. Ingestion: Do not induce vomiting. In general, no
treatment is necessary unless large quantities of product are ingested. If discomfort persists seek
medical assistance.
Instructions in Case of Fire or Spill: In case of fire, use water fog, foam, dry chemical or carbon
dioxide. Water spray may be ineffective, but can be used to cool containers. Do not use a direct
stream of water. Material will float and can be reignited on surface of water.
Spill or Leak: Dike and contain spill. Do not use water; soak up with absorbent material such as
clay, sand or other suitable material. Place in non-leaking container and seal tightly for proper
disposal.
Contains: highly refined petroleum distillate, mixture; zinc compounds, mixture; polymer
additives, mixture.
KEEP OUT OF REACH OF CHILDREN. (If intended for retail also)
MSDS Revisions
Previous Version Date: 03/12/01
Previous Version Information
Revised all sections, new 16 section MSDS format.
Other
No information available
Prepared By:
SOPUS Products
P.O. Box 4427
Houston, TX 77210-4453 USA
Disclaimer of Warranty: The information contained herein is based upon data and information available
to us, and reflects our best professional judgment. This product may be formulated in part with
components purchased from other companies. In many instances, especially when proprietary or
trade secret materials are used, SOPUS Products must rely upon the hazard evaluation of such
components submitted by that product’s manufacturer or importer. No warranty of
merchantability, fitness for any use, or any other warranty is expressed or implied regarding the
accuracy of such data or information, the results to be obtained from the use thereof, or that any
such use do not infringe any patent. Since the information contained herein may be applied under
conditions of use beyond our control and with which we may be unfamiliar, we do not assume
responsibility for the results of such application. This information is furnished upon the condition
that the person receiving it shall make his own determination of the suitability of the material for
his particular use.
SAFETY DATA SHEET
1. Identification
Throttle Body & Air-Intake CleanerProduct identifier
Other means of identification
No. 05078 (Item# 1003688)Product code
Fuel-Injection air intake cleanerRecommended use
None known.Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Manufactured or sold by:
CRC Industries, Inc.Company name
885 Louis Dr.Address
Warminster, PA 18974 US
Telephone
215-674-4300General Information
800-521-3168Technical Assistance
800-272-4620Customer Service
800-424-9300 (US)24-Hour Emergency
703-527-3887 (International)(CHEMTREC)
www.crcindustries.comWebsite
2. Hazard(s) identification
Category 1Flammable aerosolsPhysical hazards
Compressed gasGases under pressure
Category 2ASerious eye damage/eye irritationHealth hazards
Category 2Reproductive toxicity (the unborn child)
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 2 (central nervous system, kidney,peripheral nervous system)Specific target organ toxicity, repeatedexposure
Category 2Hazardous to the aquatic environment, acutehazardEnvironmental hazards
Category 2Hazardous to the aquatic environment,long-term hazard
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causesserious eye irritation. May cause drowsiness or dizziness. Suspected of damaging the unbornchild. May cause damage to organs (central nervous system, kidney, peripheral nervous system)through prolonged or repeated exposure. Toxic to aquatic life with long lasting effects.
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Material name: Throttle Body & Air-Intake Cleaner
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SDS US
Precautionary statement
Prevention Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do notspray on an open flame or other ignition source. Pressurized container: Do not pierce or burn,even after use. Do not apply while equipment is energized. Extinguish all flames, pilot lights andheaters. Vapors will accumulate readily and may ignite. Do not breathe mist or vapor. Use only
doors and windows or use other means to ensure a fresh air supply during use and while productis drying. If you experience any symptoms listed on this label, increase ventilation or leave thearea. Wash thoroughly after handling. Wear protective gloves/protective clothing/eyeprotection/face protection. Avoid release to the environment.
Response If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poisoncenter/doctor if you feel unwell. If in eyes: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Getmedical advice/attention. If exposed or concerned: Get medical advice/attention. Collect spillage.
Storage Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose totemperatures exceeding 50°C/122°F. Exposure to high temperature may cause can to burst.
Disposal Dispose of contents/container in accordance with local/regional/national regulations.
Hazard(s) not otherwise
classified (HNOC)
Static accumulating flammable liquid can become electrostatically charged even in bonded andgrounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion.
3. Composition/information on ingredients
Mixtures
67-64-1acetone 80 - 90
124-38-9carbon dioxide 5 - 10
142-82-5n-heptane 1 - 3
108-88-3toluene 1 - 3
591-76-42-methylhexane < 1
589-34-43-methylhexane < 1
562-49-23,3-dimethylpentane < 0.2
617-78-73-ethylpentane < 0.2
Specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISONCENTER or doctor/physician if you feel unwell.Inhalation
Rinse skin with water/shower. Get medical attention if irritation develops and persists.Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.Eye contact
In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth.Ingestion
May cause drowsiness and dizziness. Narcosis. Headache. Nausea, vomiting. Behavioralchanges. Decrease in motor functions. Severe eye irritation. Symptoms may include stinging,tearing, redness, swelling, and blurred vision. Edema. Prolonged exposure may cause chroniceffects.
Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically. Keep victim under observation.Symptoms may be delayed.Indication of immediate
medical attention and special
treatment needed
IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are awareof the material(s) involved, and take precautions to protect themselves. Show this safety datasheet to the doctor in attendance.
General information
5. Fire-fighting measures
Water fog. Alcohol resistant foam. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide,sand or earth may be used for small fires only.Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
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SDS US
Contents under pressure. Pressurized container may rupture when exposed to heat or flame. Thisproduct is a poor conductor of electricity and can become electrostatically charged. If sufficientcharge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulationmay be significantly increased by the presence of small quantities of water or other contaminants.Material will float and may ignite on surface of water. During fire, gases hazardous to health maybe formed.
Specific hazards arising from
the chemical
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA.Special protective equipment
and precautions for firefighters
Fire-fighting
equipment/instructions
In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so withoutrisk. Containers should be cooled with water to prevent vapor pressure build up.
Extremely flammable aerosol. Contents under pressure. Pressurized container may rupture whenexposed to heat or flame.General fire hazards
6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Remove allpossible sources of ignition in the surrounding area. Keep out of low areas. Many gases areheavier than air and will spread along ground and collect in low or confined areas (sewers,basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Do notbreathe mist or vapor. Emergency personnel need self-contained breathing equipment. Do nottouch damaged containers or spilled material unless wearing appropriate protective clothing.Ventilate closed spaces before entering them. Use appropriate containment to avoidenvironmental contamination. Local authorities should be advised if significant spillages cannot becontained. For personal protection, see section 8 of the SDS.
Personal precautions,
protective equipment and
emergency procedures
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keepcombustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water.This material is classified as a water pollutant under the Clean Water Act and should be preventedfrom contaminating soil or from entering sewage and drainage systems which lead to waterways.Stop the flow of material, if this is without risk. Wipe up with absorbent material (e.g. cloth, fleece).Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 ofthe SDS.
Methods and materials for
containment and cleaning up
Avoid release to the environment. Inform appropriate managerial or supervisory personnel of allenvironmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge intodrains, water courses or onto the ground. Use appropriate containment to avoid environmentalcontamination.
Environmental precautions
7. Handling and storage
Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Minimize fire risks from flammable and combustible materials (includingcombustible dust and static accumulating liquids) or dangerous reactions with incompatiblematerials. Pressurized container: Do not pierce or burn, even after use. Do not use if spray buttonis missing or defective. Do not spray on a naked flame or any other incandescent material. Do notsmoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind,or expose containers to heat, flame, sparks, or other sources of ignition. Use caution aroundenergized equipment. The metal container will conduct electricity if it contacts a live source. Thismay result in injury to the user from electrical shock and/or flash fire. Do not breathe mist or vapor.Avoid contact with eyes. Avoid prolonged exposure. Pregnant or breastfeeding women must nothandle this product. Should be handled in closed systems, if possible. Use only in well-ventilatedareas. Wear appropriate personal protective equipment. Observe good industrial hygienepractices. Avoid release to the environment. For product usage instructions, see the product label.
Precautions for safe handling
Level 3 Aerosol.
Pressurized container. Protect from sunlight and do not expose to temperatures exceeding50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame,heat or other sources of ignition. This material can accumulate static charge which may causespark and become an ignition source. Avoid spark promoters. These alone may be insufficient toremove static electricity. Store in a well-ventilated place. Store away from incompatible materials(see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
ValueComponentsType
PEL 2400 mg/m3acetone (CAS 67-64-1)
1000 ppm
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SDS US
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueComponentsType
PEL 9000 mg/m3carbon dioxide (CAS124-38-9)
5000 ppm
PEL 2000 mg/m3n-heptane (CAS 142-82-5)
500 ppm
US. OSHA Table Z-2 (29 CFR 1910.1000)
ValueComponentsType
Ceiling 300 ppmtoluene (CAS 108-88-3)
TWA 200 ppm
US. ACGIH Threshold Limit Values
ValueComponentsType
STEL 500 ppm2-methylhexane (CAS591-76-4)
TWA 400 ppm
STEL 500 ppm3,3-dimethylpentane (CAS562-49-2)
TWA 400 ppm
STEL 500 ppm3-ethylpentane (CAS617-78-7)
TWA 400 ppm
STEL 500 ppm3-methylhexane (CAS589-34-4)
TWA 400 ppm
STEL 500 ppmacetone (CAS 67-64-1)
TWA 250 ppm
STEL 30000 ppmcarbon dioxide (CAS124-38-9)
TWA 5000 ppm
STEL 500 ppmn-heptane (CAS 142-82-5)
TWA 400 ppm
TWA 20 ppmtoluene (CAS 108-88-3)
US. NIOSH: Pocket Guide to Chemical Hazards
ValueComponentsType
TWA 590 mg/m3acetone (CAS 67-64-1)
250 ppm
STEL 54000 mg/m3carbon dioxide (CAS124-38-9)30000 ppm
TWA 9000 mg/m3
5000 ppm
Ceiling 1800 mg/m3n-heptane (CAS 142-82-5)
440 ppm
TWA 350 mg/m3
85 ppm
STEL 560 mg/m3toluene (CAS 108-88-3)
150 ppm
TWA 375 mg/m3
100 ppm
Biological limit values
ValueComponents Determinant Specimen Sampling Time
25 mg/l Acetone Urine *acetone (CAS 67-64-1)
0.3 mg/g o-Cresol, withhydrolysis Creatinine inurine *toluene (CAS 108-88-3)
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SDS US
ACGIH Biological Exposure Indices
ValueComponents Determinant Specimen Sampling Time
0.03 mg/l Toluene Urine *
0.02 mg/l Toluene Blood *
* - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
toluene (CAS 108-88-3)Can be absorbed through the skin.
US - Minnesota Haz Subs: Skin designation applies
toluene (CAS 108-88-3)Skin designation applies.
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation ratesshould be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,or other engineering controls to maintain airborne levels below recommended exposure limits. Ifexposure limits have not been established, maintain airborne levels to an acceptable level. Provideeyewash station.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Wear safety glasses with side shields (or goggles).Eye/face protection
Skin protection
Wear protective gloves such as: Nitrile. Neoprene. Polyvinyl alcohol (PVA).Hand protection
Wear suitable protective clothing.Other
If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use aNIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-containedbreathing apparatus in confined spaces and for emergencies. Air monitoring is needed todetermine actual employee exposure levels.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
When using do not smoke. Always observe good personal hygiene measures, such as washingafter handling the material and before eating, drinking, and/or smoking. Routinely wash workclothing and protective equipment to remove contaminants.
General hygiene
considerations
9. Physical and chemical properties
Appearance
Liquid.Physical state
Aerosol.Form
Clear. Colorless.Color
Ketone.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing point -138.8 °F (-94.9 °C) estimated
Initial boiling point and boiling
range
132.9 °F (56.1 °C) estimated
Flash point < 0 °F (< -17.8 °C) Tag Closed Cup
Evaporation rate Fast.
Not available.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
1.1 % estimated
Flammability limit - upper
(%)
12.8 % estimated
Vapor pressure 5856.8 hPa estimated
Vapor density 2 (air = 1)
Relative density 0.86 estimated
Solubility (water)Slightly soluble.
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SDS US
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature 539.6 °F (282 °C) estimated
Decomposition temperature Not available.
Viscosity (kinematic)Not available.
Percent volatile 90.1 % estimated
10. Stability and reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity
Material is stable under normal conditions.Chemical stability
No dangerous reaction known under conditions of normal use.Possibility of hazardous
reactions
Heat, flames and sparks. Contact with incompatible materials.Conditions to avoid
Acids. Aluminum. Strong oxidizing agents.Incompatible materials
Carbon oxides.Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause damage to organs through prolonged or repeated exposure by inhalation. May causedrowsiness and dizziness. Headache. Nausea, vomiting.
Skin contact Prolonged skin contact may cause temporary irritation.
Eye contact Causes serious eye irritation.
Ingestion Health injuries are not known or expected under normal use.
Symptoms related to the
physical, chemical and
toxicological characteristics
May cause drowsiness and dizziness. Narcosis. Headache. Nausea, vomiting. Behavioralchanges. Decrease in motor functions. Severe eye irritation. Symptoms may include stinging,tearing, redness, swelling, and blurred vision. Edema.
Information on toxicological effects
Test ResultsComponentsSpecies
3-methylhexane (CAS 589-34-4)
Dermal
Acute
LD50 Rabbit > 2000 mg/kg
Oral
LD50 Rat > 2000 mg/kg
acetone (CAS 67-64-1)
Dermal
Acute
LD50 Rabbit 20000 mg/kg
Oral
LD50 Rat 5800 mg/kg
n-heptane (CAS 142-82-5)
Dermal
Acute
* Estimates for product may be based on additional component data not shown.
LD50 Rabbit 3000 mg/kg
Prolonged skin contact may cause temporary irritation.Skin corrosion/irritation
Causes serious eye irritation.Serious eye damage/eye
irritation
Not a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitization
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SDS US
No data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.Germ cell mutagenicity
Not classifiable as to carcinogenicity to humans.
IARC Monographs. Overall Evaluation of Carcinogenicity
toluene (CAS 108-88-3)3 Not classifiable as to carcinogenicity to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Suspected of damaging the unborn child.Reproductive toxicity
Specific target organ toxicity -
single exposure
May cause drowsiness and dizziness.
Specific target organ toxicity -
repeated exposure
May cause damage to organs (central nervous system, kidney, peripheral nervous system)through prolonged or repeated exposure.
Aspiration hazard Not an aspiration hazard.
Chronic effects May cause damage to organs through prolonged or repeated exposure. Prolonged inhalation maybe harmful.
12. Ecological information
Toxic to aquatic life with long lasting effects.Ecotoxicity
Components Test ResultsSpecies
acetone (CAS 67-64-1)
Aquatic
EC50Crustacea 10294 - 17704 mg/l, 48 hoursWater flea (Daphnia magna)
LC50Fish 4740 - 6330 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss)
n-heptane (CAS 142-82-5)
Aquatic
Acute
EC50Crustacea 1.5 mg/l, 48 hoursWater flea (Daphnia magna)
LC50Fish 2.1 - 2.98 mg/l, 96 hoursFathead minnow (Pimephales promelas)
toluene (CAS 108-88-3)
Aquatic
Acute
EC50Crustacea 6 mg/l, 48 hoursWater flea (Daphnia magna)
* Estimates for product may be based on additional component data not shown.
LC50Fish 5.5 mg/l, 96 hoursCoho salmon,silver salmon(Oncorhynchus kisutch)
Persistence and degradability
Bioaccumulative potential
acetone -0.24
n-heptane 4.66
toluene 2.73
Bioconcentration factor (BCF)toluene 90
No data available.Mobility in soil
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
If discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim ordispose in sealed containers at licensed waste disposal site. Contents under pressure. Do notpuncture, incinerate or crush. Dispose in accordance with all applicable regulations.
Disposal of waste from
residues / unused products
D001: Waste Flammable material with a flash point <140 FHazardous waste code
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SDS US
Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.
Contaminated packaging
14. Transport information
DOT
UN1950UN number
Aerosols, flammable, Limited QuantityUN proper shipping name
2.1Class
Transport hazard class(es)
-Subsidiary risk
2.1Label(s)
Not applicable.Packing group
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
N82Special provisions
306Packaging exceptions
NonePackaging non bulk
NonePackaging bulk
IATA
UN1950UN number
Aerosols, flammable, Limited QuantityUN proper shipping name
2.1Class
Transport hazard class(es)
-Subsidiary risk Not applicable.Packing group
10LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
Allowed with restrictions.Passenger and cargo
aircraft
Other information
Allowed with restrictions.Cargo aircraft only
IMDG
UN1950UN number AEROSOLS, Limited QuantityUN proper shipping name
2.1Class
Transport hazard class(es)
-Subsidiary risk
Not applicable.Packing group
No.Marine pollutant
Environmental hazards
Not available.EmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
15. Regulatory information
This product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
toluene (CAS 108-88-3)
CERCLA Hazardous Substance List (40 CFR 302.4)
3,3-dimethylpentane (CAS 562-49-2)Listed.
acetone (CAS 67-64-1)Listed.
toluene (CAS 108-88-3)Listed.
CERCLA Hazardous Substances: Reportable quantity
3,3-dimethylpentane (CAS 562-49-2)100 LBS
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SDS US
acetone (CAS 67-64-1)5000 LBS
toluene (CAS 108-88-3)1000 LBS
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the NationalResponse Center (800-424-8802) and to your Local Emergency Planning Committee.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
toluene (CAS 108-88-3)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Not regulated.Safe Drinking Water Act
(SDWA)
Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical
Code Number
acetone (CAS 67-64-1)6532toluene (CAS 108-88-3)6594
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))
acetone (CAS 67-64-1)35 %WV
toluene (CAS 108-88-3)35 %WV
DEA Exempt Chemical Mixtures Code Number
acetone (CAS 67-64-1)6532toluene (CAS 108-88-3)594
FEMA Priority Substances Respiratory Health and Safety in the Flavor Manufacturing Workplace
acetone (CAS 67-64-1)Low priority
Not regulated.Food and Drug
Administration (FDA)
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - YesDelayed Hazard - YesFire Hazard - YesPressure Hazard - YesReactivity Hazard - No
Section 311/312
Hazard categories
NoSARA 302 Extremely
hazardous substance
US state regulations
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd.
(a))
acetone (CAS 67-64-1)toluene (CAS 108-88-3)
US. New Jersey Worker and Community Right-to-Know Act
3-methylhexane (CAS 589-34-4)acetone (CAS 67-64-1)
carbon dioxide (CAS 124-38-9)
n-heptane (CAS 142-82-5)
toluene (CAS 108-88-3)
US. Massachusetts RTK - Substance List
2-methylhexane (CAS 591-76-4)
3-methylhexane (CAS 589-34-4)acetone (CAS 67-64-1)carbon dioxide (CAS 124-38-9)n-heptane (CAS 142-82-5)toluene (CAS 108-88-3)
US. Pennsylvania Worker and Community Right-to-Know Law
3,3-dimethylpentane (CAS 562-49-2)
3-methylhexane (CAS 589-34-4)
acetone (CAS 67-64-1)
carbon dioxide (CAS 124-38-9)
n-heptane (CAS 142-82-5)
toluene (CAS 108-88-3)
US. Rhode Island RTK
acetone (CAS 67-64-1)carbon dioxide (CAS 124-38-9)
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SDS US
n-heptane (CAS 142-82-5)
toluene (CAS 108-88-3)
US. California Proposition 65
WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or otherreproductive harm.
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
acetaldehyde (CAS 75-07-0)Listed: April 1, 1988
benzene (CAS 71-43-2)Listed: February 27, 1987
cumene (CAS 98-82-8)Listed: April 6, 2010
ethylbenzene (CAS 100-41-4)Listed: June 11, 2004
naphthalene (CAS 91-20-3)Listed: April 19, 2002
US - California Proposition 65 - CRT: Listed date/Developmental toxin
benzene (CAS 71-43-2)Listed: December 26, 1997toluene (CAS 108-88-3)Listed: January 1, 1991
US - California Proposition 65 - CRT: Listed date/Male reproductive toxin
benzene (CAS 71-43-2)Listed: December 26, 1997
Volatile organic compounds (VOC) regulations
EPA
VOC content (40 CFR
51.100(s))
9.1 %
CompliantConsumer products
(40 CFR 59, Subpt. C)
State
This product is regulated as a Fuel Injection Air Intake Cleaner. This product is compliant for use inall 50 states.Consumer products
VOC content (CA)9.1 %
VOC content (OTC)9.1 %
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
NoAustraliaAustralian Inventory of Chemical Substances (AICS)
NoCanadaDomestic Substances List (DSL)
YesCanadaNon-Domestic Substances List (NDSL)
NoChinaInventory of Existing Chemical Substances in China (IECSC)
NoEuropeEuropean Inventory of Existing Commercial ChemicalSubstances (EINECS)
NoEuropeEuropean List of Notified Chemical Substances (ELINCS)
NoJapanInventory of Existing and New Chemical Substances (ENCS)
YesKoreaExisting Chemicals List (ECL)
NoNew Zealand New Zealand Inventory
YesPhilippinesPhilippine Inventory of Chemicals and Chemical Substances(PICCS)
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
country(s).
16. Other information, including date of preparation or last revision
05-07-2015Issue date
08-22-2017Revision date
Allison YoonPrepared by
Version #03
CRC # 464K/1002465Further information
Health: 2*Flammability: 4Physical hazard: 0Personal protection: B
HMIS® ratings
10 / 11
Material name: Throttle Body & Air-Intake Cleaner
No. 05078 (Item# 1003688) Version #: 03 Revision date: 08-22-2017 Issue date: 05-07-2015
SDS US
Health: 2Flammability: 4Instability: 0
NFPA ratings
NFPA ratings
02
4
The information contained in this document applies to this specific material as supplied. It may notbe valid for this material if it is used in combination with any other materials. This information isaccurate to the best of CRC's knowledge or obtained from sources believed by CRC to beaccurate. Before using any product, read all warnings and directions on the label. For furtherclarification of any information contained on this (M)SDS consult your supervisor, a health & safetyprofessional, or CRC Industries, Inc..
Disclaimer
This document has undergone significant changes and should be reviewed in its entirety.Revision Information
11 / 11
Material name: Throttle Body & Air-Intake Cleaner
No. 05078 (Item# 1003688) Version #: 03 Revision date: 08-22-2017 Issue date: 05-07-2015
SDS US
Page: 1
SAFETY DATA SHEET Revision Date: 05/22/2017
Print Date: 11/2/2017
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Version: 1.5
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29 CFR 1910.1200 (OSHA HazCom 2012)
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product identifier
Trade name : Valvoline™ ATF+4 Full Synthetic Automatic Transmission Fluid
Relevant identified uses of the substance or mixture and uses advised against Recommended use
: Engine, gear & lubricating oil.
Details of the supplier of the safety data
sheet
Emergency telephone number
Regulatory Information Number
Product Information
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification Skin sensitization
: Category 1
GHS label elements
Hazard pictograms :
Signal Word : Warning Hazard Statements : May cause an allergic skin reaction. Precautionary Statements : If medical advice is needed, have product container or label at hand. Keep out of reach of children. Read label before use. Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves.
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Disposal:
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture
: Mixture
Chemical nature
: Defatter
Hazardous components
Chemical name CAS-No. Classification Concentration (%)
HYDROTREATED LIGHT
PARAFFINIC DISTILLATE
64742-55-8 This material is not
considered hazardous under the OSHA
Hazard Communication
Standard (HazCom 2012).
59.3321
Distillates (Petroleum), Hydrotreated Heavy Paraffinic 64742-54-7 Asp. Tox. 1; H304
25.6673
HYDROTREATED LIGHT
PARAFFINIC DISTILLATE
64742-55-8 Asp. Tox. 1; H304
3.2526
Mineral Oil Asp. Tox. 1; H304
3.1046
BENZENE, POLYPROPENE DERIVATIVES, SULFONATED, CALCIUM SALTS
Eye Irrit. 2A; H319 Skin Sens. 1; H317
0.7703
DODECYL HYDROXYPROPYL SULFIDE 67124-09-8 Skin Sens. 1; H317
0.7703
C14-C18 alpha-olefin epoxide,
reaction products with boric acid
Skin Sens. 1; H317
0.3813
SECTION 4. FIRST AID MEASURES
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General advice
: Move out of dangerous area.
Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended.
If inhaled
: If breathed in, move person into fresh air.
If unconscious, place in recovery position and seek medical advice.
If symptoms persist, call a physician.
In case of skin contact : Remove contaminated clothing. If irritation develops, get medical attention.
If on skin, rinse well with water. First aid is not normally required. However, it is
recommended that exposed areas be cleaned by washing with soap and water.
Wash contaminated clothing before re-use.
In case of eye contact : Flush eyes with water as a precaution. Remove contact lenses.
Protect unharmed eye. If eye irritation persists, consult a specialist.
If swallowed
: Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person. If symptoms persist, call a physician.
Most important symptoms
and effects, both acute and delayed
: Acute aspiration of large amounts of oil-laden material may
produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of
long-term sequelae. Repeated aspiration of small quantities of mineral oil can produce chronic inflammation of the lungs
(i.e. lipoid pneumonia) that may progress to pulmonary fibrosis. Symptoms are often subtle and radiological changes
appear worse than clinical abnormalities. Occasionally, persistent cough, irritation of the upper respiratory tract,
shortness of breath with exertion, fever, and bloody sputum occur. Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary abnormalities.
Signs and symptoms of exposure to this material through
breathing, swallowing, and/or passage of the material through the skin may include: acne stomach or intestinal upset (nausea, vomiting, diarrhea)
irritation (nose, throat, airways) May cause an allergic skin reaction.
Notes to physician : No hazards which require special first aid measures.
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SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media
: Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment. Water spray
Foam Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing media
: High volume water jet
Specific hazards during
firefighting
: Do not allow run-off from fire fighting to enter drains or water
courses.
Hazardous combustion products
: carbon dioxide and carbon monoxide Hydrocarbons
Aldehydes
Specific extinguishing methods
:
Product is compatible with standard fire-fighting agents.
Further information : Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
Special protective equipment for firefighters
: In the event of fire, wear self-contained breathing apparatus.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions,
protective equipment and emergency procedures
: Use personal protective equipment.
Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions
: Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform
respective authorities. Methods and materials for containment and cleaning up
: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.
Other information : Comply with all applicable federal, state, and local regulations.
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SECTION 7. HANDLING AND STORAGE
Advice on safe handling : Do not breathe vapours/dust. Do not smoke.
Persons susceptible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not
be employed in any process in which this mixture is being used.
Container hazardous when empty. Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes. Smoking, eating and drinking should be prohibited in the
application area. For personal protection see section 8.
Dispose of rinse water in accordance with local and national regulations.
Conditions for safe storage
: Keep container tightly closed in a dry and well-ventilated
place. Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
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Hazardous components without workplace control parameters
Components CAS-No.
Mineral Oil
BENZENE, POLYPROPENE DERIVATIVES,
SULFONATED, CALCIUM SALTS
DODECYL HYDROXYPROPYL SULFIDE 67124-09-8
C14-C18 alpha-olefin epoxide,
reaction products with boric acid
: Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects.
Personal protective equipment Hand protection
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SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : liquid
Physical state : liquid
Colour : red
Odour : No data available
Odour Threshold : No data available
pH : No data available
Melting point/freezing point : No data available
Boiling point/boiling range : No data available
Flash point : > 390 °F / > 199 °C Method: Cleveland open cup
Evaporation rate
: No data available
Flammability (solid, gas)
: No data available
Upper explosion limit : 6 %(V) Calculated Explosive Limit Lower explosion limit
: 1 %(V)
Calculated Explosive Limit Vapour pressure
: 0.0133333 hPa (21.11 °C)
Calculated Vapor Pressure Relative vapour density : No data available
Relative density : 0.854 (15.6 °C)
Density : 0.8508 g/cm3 (15.56 °C)
Solubility(ies)
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Viscosity
SECTION 10. STABILITY AND REACTIVITY
Reactivity
: No decomposition if stored and applied as directed.
Chemical stability
: Stable under recommended storage conditions.
Possibility of hazardous
reactions
: Product will not undergo hazardous polymerization.
Conditions to avoid : excessive heat
Incompatible materials : Strong oxidizing agents
Hazardous decomposition products carbon dioxide and carbon monoxide
Hydrocarbons
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of
exposure
: Inhalation
Skin contact Eye Contact
Ingestion
Acute toxicity Not classified based on available information.
Components: Distillates (Petroleum), Hydrotreated Heavy Paraffinic:
Acute oral toxicity : LD50 (Rat): > 15 g/kg Acute dermal toxicity : LD50 (Rabbit): > 5 g/kg
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DODECYL HYDROXYPROPYL SULFIDE: Acute oral toxicity
: LD50 (Rat): > 5,000 mg/kg
GLP: yes
Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Assessment: Not classified as acutely toxic by dermal
absorption under GHS.
Skin corrosion/irritation Not classified based on available information.
Product: Remarks: May cause skin irritation in susceptible persons.
Components: HYDROTREATED LIGHT PARAFFINIC DISTILLATE: Result: Slight, transient irritation
Distillates (Petroleum), Hydrotreated Heavy Paraffinic:
Result: Slight, transient irritation HYDROTREATED LIGHT PARAFFINIC DISTILLATE: Result: Slight, transient irritation
BENZENE, POLYPROPENE DERIVATIVES, SULFONATED, CALCIUM SALTS:
Result: Slight, transient irritation DODECYL HYDROXYPROPYL SULFIDE: Species: Rabbit
Result: No skin irritation
C14-C18 alpha-olefin epoxide, reaction products with boric acid: Result: No skin irritation
Serious eye damage/eye irritation
Not classified based on available information.
Product:
Result: Slight, transient irritation Remarks: Expected based on components.
Remarks: Unlikely to cause eye irritation or injury.
Components:
HYDROTREATED LIGHT PARAFFINIC DISTILLATE: Result: Slight, transient irritation
Distillates (Petroleum), Hydrotreated Heavy Paraffinic:
Result: No eye irritation HYDROTREATED LIGHT PARAFFINIC DISTILLATE:
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BENZENE, POLYPROPENE DERIVATIVES, SULFONATED, CALCIUM SALTS: Result: Irritating to eyes.
DODECYL HYDROXYPROPYL SULFIDE:
Species: Rabbit Result: No eye irritation
C14-C18 alpha-olefin epoxide, reaction products with boric acid:
Result: No eye irritation
Respiratory or skin sensitisation Skin sensitisation: May cause an allergic skin reaction.
Respiratory sensitisation: Not classified based on available information.
Components: BENZENE, POLYPROPENE DERIVATIVES, SULFONATED, CALCIUM SALTS: Assessment: May cause sensitisation by skin contact.
DODECYL HYDROXYPROPYL SULFIDE: Test Type: Local lymph node assay
Species: Guinea pig Assessment: May cause sensitisation by skin contact.
Method: OECD Test Guideline 429
C14-C18 alpha-olefin epoxide, reaction products with boric acid:
Assessment: May cause sensitisation by skin contact.
Germ cell mutagenicity Not classified based on available information.
Components: DODECYL HYDROXYPROPYL SULFIDE:
Genotoxicity in vitro : Test Type: Ames test Test species: Salmonella typhimurium
Metabolic activation: with and without metabolic activation Result: negative
Carcinogenicity
Not classified based on available information.
Reproductive toxicity
Not classified based on available information.
STOT - single exposure
Not classified based on available information.
STOT - repeated exposure
Not classified based on available information.
Aspiration toxicity
Not classified based on available information.
Components:
Distillates (Petroleum), Hydrotreated Heavy Paraffinic:
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HYDROTREATED LIGHT PARAFFINIC DISTILLATE: May be fatal if swallowed and enters airways.
Mineral Oil:
May be fatal if swallowed and enters airways.
Further information
Product:
Remarks: No data available
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Product:
Ecotoxicology Assessment
Components: Distillates (Petroleum), Hydrotreated Heavy Paraffinic:
Toxicity to fish : LL50 (Fish): > 100 mg/l
Toxicity to daphnia and other aquatic invertebrates
: EL50 (Aquatic invertebrates): > 10,000 mg/l
Toxicity to algae
: EL50 (Algae, algal mat (Algae)): > 100 mg/l
Toxicity to fish (Chronic
toxicity)
: NOEC (Fish): 10 mg/l
Toxicity to daphnia and other aquatic invertebrates
(Chronic toxicity)
: NOEC (Aquatic invertebrates): 10 mg/l
DODECYL HYDROXYPROPYL SULFIDE: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 0.75 mg/l Exposure time: 96 h Test Type: semi-static test
Method: OECD Test Guideline 203 GLP: yes
Toxicity to daphnia and other aquatic invertebrates
: EL50 (Daphnia magna (Water flea)): 0.58 mg/l Exposure time: 48 h Test Type: static test
Test substance: WAF
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Persistence and degradability DODECYL HYDROXYPROPYL SULFIDE: Biodegradability
: Result: Not readily biodegradable.
Biodegradation: 5 % Exposure time: 28 d
Method: OECD Test Guideline 301F
No data available
Bioaccumulative potential
DODECYL HYDROXYPROPYL SULFIDE: Partition coefficient: n-
octanol/water
: log Pow: 4.7 - 6.5
No data available
Mobility in soil
No data available
Other adverse effects
No data available
Product:
Additional ecological information
: An environmental hazard cannot be excluded in the event of unprofessional handling or disposal., Harmful to aquatic life with long lasting effects.
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
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SECTION 14. TRANSPORT INFORMATION
International transport regulations
REGULATION
ID NUMBER PROPER SHIPPING NAME *HAZARD
CLASS
SUBSIDIARY
HAZARDS
PACKING
GROUP
MARINE
POLLUTANT / LTD. QTY.
U.S. DOT - ROAD
Not dangerous goods
CFR_RAIL_C
Not dangerous goods
U.S. DOT - INLAND WATERWAYS
Not dangerous goods
TDG_ROAD_C
Not dangerous goods
TDG_RAIL_C
Not dangerous goods
TDG_INWT_C
Not dangerous goods
INTERNATIONAL MARITIME DANGEROUS GOODS
Not dangerous goods
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO
Not dangerous goods
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INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER
Not dangerous goods
MX_DG
Not dangerous goods
*ORM = ORM-D, CBL = COMBUSTIBLE LIQUID
Marine pollutant no
Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific
exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment.
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
Components CAS-No. Component RQ
(lbs)
Calculated product RQ
(lbs)
BENZENE 71-43-2 10 *
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
Components CAS-No. Component RQ
(lbs)
Calculated product RQ
(lbs)
SULFUR DIOXIDE 7446-09-5 500 *
SULFUR DIOXIDE 7446-09-5 *
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 311/312 Hazards
SARA 313
California Prop 65
The components of this product are reported in the following inventories:
DSL : All components of this product are on the Canadian DSL
AICS : On the inventory, or in compliance with the inventory ENCS : Not in compliance with the inventory
KECI : On the inventory, or in compliance with the inventory
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Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
(Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)
SECTION 16. OTHER INFORMATION
Further information
Revision Date: 05/22/2017
NFPA: HMIS III:
NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class IIIB
Full text of H-Statements H304 May be fatal if swallowed and enters airways. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation.
Sources of key data used to compile the Safety Data Sheet
Valvoline internal data including own and sponsored test reports The UNECE administers regional agreements implementing harmonised classification for
labelling (GHS) and transport.
Flammability
He
a
l
t
h
In
s
t
a
b
i
l
i
t
y
2
1
0
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
1
0
2
Special hazard.0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic
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The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the
information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Valvoline's Environmental Health and Safety Department (1-800-VALVOLINE).
List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet :
ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index
CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction
FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals.
H-statement : Hazard Statement IATA : International Air Transport Association.
IATA-DGR : Dangerous Goods Regulation by the “International Air Transport Association” (IATA).
ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the “International Civil Aviation Organization”
IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization
logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population
LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance
Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified
OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit
P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic
PPE : Personal Protective Equipment STEL : Short-term exposure limit
STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value
TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level
CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation
FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association
NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration
PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System
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Page: 1
SAFETY DATA SHEET Revision Date: 12/11/2013
Print Date: 3/25/2014 MSDS Number: R0321370 Zerex™ G-05™ Formula 50/50 ANTIFREEZE COOLANT ZXG05RU1
Version: 1.16
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1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance: liquid, light yellow WARNING! MAY AFFECT THE CENTRAL NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. HARMFUL IF SWALLOWED.
Potential Health Effects
Exposure routes Inhalation, Skin absorption, Skin contact, Eye Contact, Ingestion
Eye contact May cause mild eye irritation. Symptoms include stinging, tearing, and redness.
Skin contact
No data
Ingestion Swallowing this material may be harmful. Liver, kidney and brain damage in humans has resulted from swallowing lethal or near-lethal amounts of ethylene glycol.
Inhalation
It is possible to breathe this material under certain conditions of handling and use (for example, during heating, spraying, or stirring). Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts may be harmful. Symptoms are not expected at air concentrations below the recommended exposure limits, if applicable (see Section 8.).
Aggravated Medical Condition Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material:, lung (for example, asthma-like conditions), Liver, Kidney, Central nervous system, Exposure to this material may aggravate any preexisting condition sensitive to a decrease in available oxygen, such as chronic lung disease, coronary artery disease or anemias.
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Symptoms Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include:, stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways), Cough, central nervous system excitation (giddiness, liveliness, light-headed feeling) followed by central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness) and other central nervous system effects, involuntary eye movement, pain in the abdomen and lower back, cyanosis (causes blue coloring of the skin and nails from lack of oxygen), lung edema (fluid buildup in the lung tissue), acute kidney failure (sudden slowing or stopping of urine production), liver damage, Convulsions, coma
Target Organs
Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals:, reproductive effects, kidney damage, liver damage, central nervous system damage, Overexposure to this material (or its components) has been suggested as a cause of the following effects in humans:, liver damage, kidney damage
Carcinogenicity
This material is not listed as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), or the Occupational Safety and Health Administration (OSHA).
Reproductive hazard
Ethylene glycol has caused birth defects in animal studies at high oral doses. However, it did not cause harm to the pregnant animal or to the fetus when applied to the skin of the pregnant animal., This material (or a component) has been shown to cause harm to the fetus in laboratory animal studies. Harm to the fetus occurs only at exposure levels that harm the pregnant animal. The relevance of these findings to humans is uncertain.
ETHYLENE GLYCOL 107-21-1 >=40-<50%
DIETHYLENE GLYCOL 111-46-6 >=1.5-<5%
SODIUM BENZOATE 532-32-1 >=1.5-<5%
Eyes
If symptoms develop, move individual away from exposure and into fresh air. Flush eyes gently with water while holding eyelids apart. If symptoms persist or there is any visual difficulty, seek medical attention.
Skin
Remove contaminated clothing. Wash exposed area with soap and water. If symptoms persist, seek medical attention. Launder clothing before reuse.
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SAFETY DATA SHEET Revision Date: 12/11/2013
Print Date: 3/25/2014 MSDS Number: R0321370 Zerex™ G-05™ Formula 50/50 ANTIFREEZE COOLANT ZXG05RU1
Version: 1.16
Page 3 / 12
Ingestion
Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended.
Inhalation
If symptoms develop, immediately move individual away from exposure and into fresh air. Seek immediate medical attention; keep person warm and quiet. If person is not breathing, begin artificial respiration. If breathing is difficult, administer oxygen.
Notes to physician
Hazards: Effects of acute ethylene glycol poisoning appear in three fairly distinct stages. The initial stage occurs shortly after exposure, lasts 6-12 hours, and is characterized by central nervous system effects (transient exhilaration, nausea, vomiting, and in severe cases, coma, convulsions, and possible death). The second stage lasts from 12-36 hours after exposure and is initiated by the onset of coma. This phase is characterized by tachypnia, tachycardia, mild hypotension, cyanosis, and in severe cases, pulmonary edema, bronchopneumonia, cardiac enlargement, and congestive failure. The final stage occurs 24-72 post-exposure and is characterized by renal failure, ranging from a mild increase in blood urea nitrogen and creatinine followed by recovery, to complete anuria with acute tubular necrosis that can lead to death. Oxaluria is found in most cases. The most significant laboratory finding in ethylene glycol intoxication is severe metabolic acidosis. Ingestion or other significant exposure to this material (or a component) may cause metabolic acidosis.
Treatment: This product contains ethylene glycol. Ethanol decreases the metabolism of ethylene glycol to toxic metabolites. Ethanol should be administered as soon as possible in cases of severe poisoning since the elimination half-life of ethylene glycol is 3 hours. If medical care will be delayed several hours, give the patient three to four 1-ounce oral "shots" of 86-proof or higher whiskey before or during transport to the hospital. Fomepizole (4-methylpyrazole) is an effective antagonist of alcohol dehydrogenase, and as such, may be used as an antidote in the treatment of ethylene glycol poisoning. Hemodialysis effectively removes ethylene glycol and its metabolites from the body. Fomepizole (4-methylpyrazole) is an effective antagonist of alcohol dehydrogenase, and as such, may be used as an antidote in the treatment of ethylene glycol, diethylene glycol and methanol poisoning.
Suitable extinguishing media
Dry chemical, Carbon dioxide (CO2), Water spray
Hazardous combustion products
Alcohols, Aldehydes, carbon dioxide and carbon monoxide, ethers, Hydrocarbons, Sodium oxides, toxic fumes
Precautions for fire-fighting
Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA). DO NOT direct a solid stream of water or foam into hot, burning pools of liquid since this may cause frothing and increase fire intensity. Frothing can be violent and possibly endanger any firefighter standing too close to the burning liquid. Use water spray to cool fire exposed containers and structures until fire is out if it can be done with minimal risk. Avoid spreading burning material with water used for cooling purposes.
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SAFETY DATA SHEET Revision Date: 12/11/2013
Print Date: 3/25/2014 MSDS Number: R0321370 Zerex™ G-05™ Formula 50/50 ANTIFREEZE COOLANT ZXG05RU1
Version: 1.16
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NFPA Flammable and Combustible Liquids Classification
Combustible Liquid Class IIIB
Personal precautions
For personal protection see section 8. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed.
Environmental precautions
Prevent spreading over a wide area (e.g. by containment or oil barriers). Do not let product enter drains. Do not flush into surface water or sanitary sewer system.
Methods for cleaning up
Keep in suitable, closed containers for disposal. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
Other information
Comply with all applicable federal, state, and local regulations.
Handling
Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed.
Storage
Store in a cool, dry, ventilated area, away from incompatible substances. Store in a cool, dry, ventilated area. Keep containers closed when not in use. Do not store near extreme heat, open flame, or sources of ignition.Store in a cool, dry, ventilated area.
Exposure Guidelines
ACGIH Ceiling Limit Value: 100 mg/m3 Aerosol.
WEEL time weighted average 10 mg/m3
General advice
These recommendations provide general guidance for handling this product. Personal protective equipment should be selected for individual applications and should consider factors which affect exposure
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SAFETY DATA SHEET Revision Date: 12/11/2013
Print Date: 3/25/2014 MSDS Number: R0321370 Zerex™ G-05™ Formula 50/50 ANTIFREEZE COOLANT ZXG05RU1
Version: 1.16
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potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local authorities.
Exposure controls
Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects.
Eye protection Not required under normal conditions of use. Wear splash-proof safety goggles if material could be misted or splashed into eyes.
Skin and body protection
Wear resistant gloves such as: Neoprene Nitrile rubber polyvinyl chloride Polyethylene Wear normal work clothing including long pants, long-sleeved shirts and foot covering to prevent direct contact of the product with the skin. Launder clothing before reuse. If skin irritation develops, contact your facility health and safety professional or your local safety equipment supplier to determine the proper personal protective equipment for your use. Wear resistant gloves (consult your safety equipment supplier).
Respiratory protection
Respiratory protection is not required under normal conditions of use.
liquidlight yellow 225 °F / 107 °C @ 760.00 mmHg
(Average) 8.0
> 250.0 °F / > 121.1 °C Cleveland open cup
1.7 %(V) / 15.3 %(V)
1.800 mmHg @ 68.00 °F / 20.00 °C
(>)1.000 AIR=1
1.0779 g/cm3 @ 60.01 °F / 15.56 °C
Stability
Stable.
Conditions to avoid
excessive heat
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SAFETY DATA SHEET Revision Date: 12/11/2013
Print Date: 3/25/2014 MSDS Number: R0321370 Zerex™ G-05™ Formula 50/50 ANTIFREEZE COOLANT ZXG05RU1
Version: 1.16
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Incompatible products
Acids, Aldehydes, Alkali metals, Alkaline earth metals, Bases, iron salts, strong alkalis, Strong oxidizing agents, Sulphur compounds
Hazardous decomposition products
Alcohols, Aldehydes, carbon dioxide and carbon monoxide, ethers, Hydrocarbons, Organic acids, Sodium oxides, ketones
Hazardous reactions
Product will not undergo hazardous polymerization.
Product
Acute oral toxicity : no data available
Acute inhalation toxicity : no data available
Acute dermal toxicity : no data available
Skin corrosion/irritation : no data available
Serious eye damage/eye irritation : no data available
Respiratory or skin sensitisation : no data available
Target Organ Systemic Toxicant - Repeated Exposure : Target Organs: Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals:, reproductive effects, kidney damage, liver damage, central nervous system damage, Overexposure to this material (or its components) has been suggested as a cause of the following effects in humans:, liver damage, kidney damage
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SAFETY DATA SHEET Revision Date: 12/11/2013
Print Date: 3/25/2014 MSDS Number: R0321370 Zerex™ G-05™ Formula 50/50 ANTIFREEZE COOLANT ZXG05RU1
Version: 1.16
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Components:
ETHYLENE GLYCOL: Acute oral toxicity : LD 50 Rat: 6,140 mg/kg
Acute dermal toxicity : LD 50 Rabbit: 9,530 mg/kg
STOT - repeated exposure : Exposure routes: Ingestion Target Organs: Kidney, Liver
Assessment: May cause damage to organs through prolonged or repeated exposure.
DIETHYLENE GLYCOL: Acute oral toxicity : LD 50 Rat: 12,565 mg/kg
Acute inhalation toxicity : LC Lo Mouse: 130 mg/m3 Exposure time: 2 h
Acute dermal toxicity : LD 50 Rabbit: 11,890 mg/kg
Experience with human exposure : Liver
SODIUM BENZOATE: Acute oral toxicity : LD 50 Rat, male and female: 3,450 mg/kg
12. ECOLOGICAL INFORMATION
Ecotoxicity
Product:
no data available
Components:
ETHYLENE GLYCOL:
Toxicity to fish : LC 50 (Bluegill (Lepomis macrochirus)): 27,540 mg/l Exposure time: 96 h Method: Static Mortality
LC 50 (Fathead minnow (Pimephales promelas)): 8,050 mg/l Exposure time: 96 h
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SAFETY DATA SHEET Revision Date: 12/11/2013
Print Date: 3/25/2014 MSDS Number: R0321370 Zerex™ G-05™ Formula 50/50 ANTIFREEZE COOLANT ZXG05RU1
Version: 1.16
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DIETHYLENE GLYCOL:
Toxicity to fish : LC 50 (Western mosquitofish (Gambusia affinis)): > 32,000 mg/l Exposure time: 96 h Method: Static Mortality Toxicity to daphnia and other aquatic invertebrates : LC 50 (Water flea (Daphnia magna)): > 10,000 mg/l Exposure time: 24 h Method: Static Mortality
SODIUM BENZOATE:
Toxicity to fish : LC 50 (Fathead minnow (Pimephales promelas)): > 100 mg/l Exposure time: 96 h Test Method: static test Method: Static Mortality Toxicity to daphnia and other aquatic invertebrates : LC 50 (Water flea (Daphnia magna)): > 100 mg/l Exposure time: 96 h Test Method: static test Method: Static Mortality
Persistence and degradability
Product:
no data available
Components:
DIETHYLENE GLYCOL:
Biodegradability : Biodegradation: 92 % Exposure time: 28 d
Bioaccumulative potential
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SAFETY DATA SHEET Revision Date: 12/11/2013
Print Date: 3/25/2014 MSDS Number: R0321370 Zerex™ G-05™ Formula 50/50 ANTIFREEZE COOLANT ZXG05RU1
Version: 1.16
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Product:
no data available
Components:
ETHYLENE GLYCOL:
Bioaccumulation : Species: Crayfish (Procambarus) Exposure time: 61 d Concentration: 1000 mg/l Bioconcentration factor (BCF): 0.27 Method: Flow through Partition coefficient: n-octanol/water : log Pow: -1.36
DIETHYLENE GLYCOL:
Partition coefficient: n-octanol/water : log Pow: -1.47
Mobility in soil
Product:
no data available
Components:
ETHYLENE GLYCOL:
Surface tension : 48.4 mN/m
DIETHYLENE GLYCOL:
Surface tension : 48.5 mN/m
13. DISPOSAL CONSIDERATIONS
Waste disposal methods
Dispose of in accordance with all applicable local, state and federal regulations.
14. TRANSPORT INFORMATION
REGULATION
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SAFETY DATA SHEET Revision Date: 12/11/2013
Print Date: 3/25/2014 MSDS Number: R0321370 Zerex™ G-05™ Formula 50/50 ANTIFREEZE COOLANT ZXG05RU1
Version: 1.16
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U.S. DOT - ROAD
Not dangerous goods
U.S. DOT - RAIL
Not dangerous goods
U.S. DOT - INLAND WATERWAYS
Not dangerous goods
TRANSPORT CANADA - ROAD Not dangerous goods
TRANSPORT CANADA - RAIL
Not dangerous goods
TRANSPORT CANADA - INLAND WATERWAYS
Not dangerous goods
INTERNATIONAL MARITIME DANGEROUS GOODS
Not dangerous goods
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO
Not dangerous goods
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER
Not dangerous goods
MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND WASTES Not dangerous goods
*ORM = ORM-D, CBL = COMBUSTIBLE LIQUID Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment.
California Prop. 65
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SAFETY DATA SHEET Revision Date: 12/11/2013
Print Date: 3/25/2014 MSDS Number: R0321370 Zerex™ G-05™ Formula 50/50 ANTIFREEZE COOLANT ZXG05RU1
Version: 1.16
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SARA Hazard Classification
SARA 311/312 Classification
SARA 313 Component(s)
New Jersey RTK Label Information
WATER 7732-18-5
ETHYLENE GLYCOL 107-21-1
DIETHYLENE GLYCOL 111-46-6
SODIUM BENZOATE 532-32-1
Pennsylvania RTK Label InformationWATER 7732-18-5 ETHYLENE GLYCOL 107-21-1 DIETHYLENE GLYCOL 111-46-6
Notification status
US. Toxic Substances Control Act y (positive listing)
Canada. Canadian Environmental Protection Act (CEPA). Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133) y (positive listing)
Australia. Industrial Chemical (Notification and Assessment) Act y (positive listing)
Japan. ENCS - Existing and New Chemical Substances Inventory n (Negative listing)
Korea. Toxic Chemical Control Law (TCCL) List n (Negative listing)
Philippines. The Toxic Substances and Hazardous and Nuclear Waste Control Act y (positive listing)
China. Inventory of Existing Chemical Substances y (positive listing)
Reportable quantity - ProductUS. EPA CERCLA Hazardous Substances (40 CFR 302) 11766 lbs
Reportable quantity-ComponentsETHYLENE GLYCOL 107-21-1 5000 lbs
Health 1* 1 Flammability 1 1 Physical hazards 0 Instability 0 Specific Hazard -- --
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SAFETY DATA SHEET Revision Date: 12/11/2013
Print Date: 3/25/2014 MSDS Number: R0321370 Zerex™ G-05™ Formula 50/50 ANTIFREEZE COOLANT ZXG05RU1
Version: 1.16
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The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's Environmental Health and Safety Department (1-800-325-3751). List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the “International Air Transport Association” (IATA). ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the “International Civil Aviation Organization” IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System
Material Safety Data Sheet
Page 1 of 7
Section 1: Product & Company Identification
Product Name: Carquest Non-Chlorinated Brake Parts Cleaner (aerosol)
Product Number (s): 1010, 1010C (CRC Part# 09621, 79621) Product Use: brake parts cleaner
Manufacturer / Supplier Contact Information: In United States: In Canada: In Mexico: CRC Industries, Inc. CRC Canada Co. CRC Industries Mexico 885 Louis Drive 2-1246 Lorimar Drive Av. Benito Juárez 4055 G Warminster, PA 18974 Mississauga, Ontario L5S 1R2 Colonia Orquídea www.crcindustries.com www.crc-canada.ca San Luís Potosí, SLP CP 78394 1-215-674-4300 (General) 1-905-670-2291 www.crc-mexico.com (800) 521-3168 (Technical) 52-444-824-1666
(800) 272-4620 (Customer Service)
24-Hr Emergency – CHEMTREC: (800) 424-9300 or (703) 527-3887
Section 2: Hazards Identification
Emergency Overview
DANGER: Extremely Flammable. Harmful or Fatal if Swallowed. May Cause Blindness if Swallowed. Vapor Harmful. Eye and Skin Irritant. Contents Under Pressure. Appearance & Odor: Clear liquid, solvent odor
Potential Health Effects: ACUTE EFFECTS: EYE: Moderate eye irritant. Exposure can cause irritation including stinging, tearing, redness, blurred vision, and swelling of the eyes. SKIN: Moderate skin irritant. Prolonged or repeated contact may dry the skin. Symptoms may include redness, burning, drying and cracking of the skin, and skin burns. Passage of this material into the body through the skin is possible, but it is unlikely that this would result in harmful effects during safe handling and use.
INHALATION: Breathing large amounts of this material may be harmful. Symptoms include irritation of the nose and throat and central nervous system excitation (giddiness), followed by CNS depression (dizziness, drowsiness, weakness, headache, nausea, unconsciousness).
INGESTION: Swallowing small amounts is not likely to cause harmful effects. May cause stomach or intestinal upset. Swallowing larger amounts may be harmful as this material may be aspirated into the lungs during swallowing or vomiting. This results in lung inflammation and other lung injury.
CHRONIC EFFECTS: Overexposure to methanol may lead to visual impairment.
TARGET ORGANS: Liver, kidneys, blood, central nervous system, eyes Medical Conditions Aggravated by Exposure: skin sensitivities, lung conditions, central nervous system conditions See Section 11 for toxicology and carcinogenicity information on product ingredients.
Product Name: Carquest Non-Chlorinated Brake Parts Cleaner (aerosol)
Product Number (s): 1010, 1010C (CRC Part# 09621, 79621)
Page 2 of 7
Section 3: Composition/Information on Ingredients
COMPONENT CAS NUMBER % by Wt.
Methanol 67-56-1 40 – 50
Toluene 108-88-3 35 – 45
Acetone 67-64-1 5 – 15
Carbon dioxide 124-38-9 3 – 8
Section 4: First Aid Measures
Eye Contact: Immediately flush with plenty of water for 15 minutes. Call a physician if irritation persists. Skin Contact: Remove contaminated clothing and wash affected area with soap and water. Call a physician if irritation persists. Wash contaminated clothing prior to re-use.
Inhalation: Remove person to fresh air. Keep person calm. If not breathing, give artificial respiration. If breathing is difficult give oxygen. Call a physician. Ingestion: Seek medical attention. Do not induce vomiting unless instructed by medical personnel. Have victim drink a glass of water if conscious.
Note to Physicians: This material is an aspiration hazard. This material (or a component) has produced hyperglycemia and ketosis following substantial ingestion. Inhalation of high concentrations of this material may be associated with cardiac arrhythmias. Sympathomimetic drugs may initiate cardiac arrhythmias in persons exposed to this material. This product contains methanol. The metabolites of methanol can cause metabolic acidosis, visual disturbances and blindness.
Section 5: Fire-Fighting Measures
Flammable Properties: This product is extremely flammable in accordance with aerosol flammability definitions. (See 16 CFR 1500.3(c)(6) ). Flash Point: 0°F / -18°C (TCC) Upper Explosive Limit: ND Autoignition Temperature: 725°F / 385°C Lower Explosive Limit: ND Fire and Explosion Data: Suitable Extinguishing Media: Dry chemical, carbon dioxide, alcohol foam, Class B extinguishers
Products of Combustion: Oxides of carbon Explosion Hazards: Aerosol containers, when exposed to heat from fire, may build pressure and explode. Vapors may accumulate in a confined space and create a flammable atmosphere.
Protection of Fire-Fighters: Firefighters should wear self-contained, NIOSH-approved breathing apparatus for protection against suffocation and possible toxic decomposition products. Vapors are
heavier than air and will accumulate near the ground. Proper eye and skin protection should be provided. Use water spray to keep fire-exposed containers cool and to knock down vapors which may result from product decomposition.
Product Name: Carquest Non-Chlorinated Brake Parts Cleaner (aerosol)
Product Number (s): 1010, 1010C (CRC Part# 09621, 79621)
Page 3 of 7
Section 6: Accidental Release Measures
Personal Precautions: Use personal protection recommended in Section 8.
Environmental Precautions: Take precautions to prevent contamination of ground and surface waters. Do not flush into sewers or storm drains. Methods for Containment & Clean-up: Eliminate sources of ignition. Dike area to contain spill. Ventilate the area with fresh air. If in confined space or limited air circulation area, clean-up workers should wear appropriate respiratory protection. Recover or absorb spilled
material using an absorbent designed for chemical spills. Place used absorbents into proper waste containers.
Section 7: Handling and Storage
Handling Procedures: Do not use near potential sources of ignition. Do not use on energized equipment. Use with adequate ventilation. Avoid contact with skin and eyes. Avoid inhaling vapors. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. For product use instructions, please see the product label. Storage Procedures: Store in a cool dry area out of direct sunlight. Aerosol cans must be maintained below 120°F / 49°C to prevent cans from rupturing. Aerosol Storage Level: III
Section 8: Exposure Controls/Personal Protection
Exposure Guidelines: OSHA ACGIH OTHER
COMPONENT TWA STEL TWA STEL TWA SOURCE UNIT
Methanol 200 NE 200 250 (s) NE ppm
Toluene 200 300 (c) 20 NE NE ppm
Acetone 1000 NE 500 750 NE ppm
Carbon dioxide 5000 30000(v 5000 30000 NE ppm
N.E. – Not Established (c) – ceiling (s) – skin (v) – vacated
Controls and Protection: Engineering Controls: Area should have ventilation to provide fresh air. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at the source, preventing dispersion into the general work area. Use mechanical means if necessary to maintain vapor levels below the exposure guidelines. If working in a confined space, follow applicable OSHA regulations.
Respiratory Protection: None required for normal work where adequate ventilation is provided. If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved
cartridge respirator with organic vapor cartridge. Air monitoring is needed to determine actual employee exposure levels. Use a self-contained breathing apparatus in confined spaces and for emergencies. Eye/face Protection: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid contact, wear splash-proof goggles.
Product Name: Carquest Non-Chlorinated Brake Parts Cleaner (aerosol)
Product Number (s): 1010, 1010C (CRC Part# 09621, 79621)
Page 4 of 7
Skin Protection: Use protective gloves such as nitrile, PVA, or neoprene. Also, use full protective clothing if there is prolonged or repeated contact of liquid with skin.
Section 9: Physical and Chemical Properties
Physical State: liquid Color: clear Odor: solvent Odor Threshold: ND Specific Gravity: 0.825 Initial Boiling Point: 132°F / 56°C Freezing Point: ND Vapor Pressure: ND Vapor Density: > 1 (air = 1) Evaporation Rate: fast Solubility: slightly soluble in water Coefficient of water/oil distribution: ND pH: NA Volatile Organic Compounds: wt %: 84.1 g/L: 693.6 lbs./gal: 5.8
Section 10: Stability and Reactivity
Stability: Stable Conditions to Avoid: Sources of ignition; temperature extremes Incompatible Materials: Acids, alkalis, reducing agents, strong oxidizing agents, hypochlorites, peroxides, reactive
metals such as aluminum and magnesium, sodium, zinc Hazardous Decomposition Products: Oxides of carbon, various hydrocarbons Possibility of Hazardous Reactions: No
Section 11: Toxicological Information
Long-term toxicological studies have not been conducted for this product. The following information is available for components of this product. Acute Toxicity: Component Oral LD50 (rat) Dermal LD50 (rabbit) Inhalation LC50 (rat) Methanol 5600 mg/kg 15,800 mg/kg 81,000 mg/m /14H Toluene 636 mg/kg 14,100 µL/kg 49 g/m /4H Acetone 5800 mg/kg No data 50,100 mg/m /8H Carbon dioxide No data No data 470,000 ppm/30M
Product Name: Carquest Non-Chlorinated Brake Parts Cleaner (aerosol)
Product Number (s): 1010, 1010C (CRC Part# 09621, 79621)
Page 5 of 7
Chronic Toxicity:
Component OSHA Carcinogen IARC Carcinogen NTP Carcinogen Irritant Sensitizer Methanol No No No E & S (moderate) UnknownToluene No No No E, S & R (mild) Unknown
Acetone No No No E & S (moderate) / R (mild) Yes
Carbon dioxide No No No No No
Reproductive Toxicity: No information availableTeratogenicity: No information availableMutagenicity: No information availableSynergistic Effects: No information available
Section 12: Ecological Information
Ecological studies have not been conducted for this product. The following information is available for components of this product. Ecotoxicity: Acetone – 48H LC50 Daphnia: 10 mg/l Persistence / Degradability: No information availableBioaccumulation / Accumulation: No information availableMobility in Environment: No information available
Section 13: Disposal Considerations
Waste Classification: The dispensed liquid product is a RCRA hazardous waste for the characteristic of ignitability
with the following potential waste code(s): D001, F003, F005. (See 40 CFR Part 261.20 – 261.33)
Empty aerosol containers may be recycled.
All disposal activities must comply with federal, state, provincial and local regulations. Local regulations may be more stringent than state, provincial or national requirements.
Section 14: Transport Information
US DOT (ground): Consumer Commodity, ORM-D
ICAO/IATA (air): Consumer Commodity, ID8000, 9
IMO/IMDG (water): Aerosols, UN1950, 2.1, Limited Quantity
Special Provisions: None
Section 15: Regulatory Information
U.S. Federal Regulations:
E – Eye S – Skin R - Respiratory
Product Name: Carquest Non-Chlorinated Brake Parts Cleaner (aerosol)
Product Number (s): 1010, 1010C (CRC Part# 09621, 79621)
Page 6 of 7
Toxic Substances Control Act (TSCA): All ingredients are either listed on the TSCA inventory or are exempt. Comprehensive Environmental Response, Compensation and Liability Act (CERCLA): Reportable Quantities (RQ’s) exist for the following ingredients: Acetone (5000 lbs), Toluene (1000 lbs), Methanol (5000 lbs)
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to
the National Response Center (800-424-8802) and to your Local Emergency Planning Committee.
Superfund Amendments Reauthorization Act (SARA) Title III: Section 302 Extremely Hazardous Substances (EHS): None Section 311/312 Hazard Categories: Fire Hazard Yes
Reactive Hazard No Release of Pressure Yes
Acute Health Hazard Yes Chronic Health Hazard No Section 313 Toxic Chemicals: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: Toluene (< 39%), Methanol (< 46%) Clean Air Act: Section 112 Hazardous Air Pollutants (HAPs): Toluene, Methanol Occupational Safety and Health Administration: This product is regulated by the Hazard Communications Standard.
U.S. State Regulations:
California Safe Drinking Water and Toxic Enforcement Act (Prop 65): This product may contain the following chemicals known to the state of California to cause cancer, birth defects or other reproductive harm:
Toluene
Consumer Products VOC Regulations: This product does not comply with Consumer Products VOC regulations and cannot be used in California, Connecticut, Delaware, The District of Columbia,
Illinois, Indiana, Maine, Maryland, Massachusetts, Michigan, New Jersey, New Hampshire, New York, Ohio, Pennsylvania, Rhode Island, and parts of Utah
and Virginia. State Right to Know: New Jersey: 67-64-1, 108-88-3, 67-56-1, 124-38-9Pennsylvania: 67-64-1, 108-88-3, 67-56-1, 124-38-9Massachusetts: 67-64-1, 108-88-3, 67-56-1, 124-38-9Rhode Island : 67-64-1, 108-88-3, 67-56-1, 124-38-9
Canadian Regulations: Controlled Products Regulations:
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. WHMIS Hazard Class: A, B5, D1A, D2A, D2B Canadian DSL Inventory: All ingredients are either listed on the DSL Inventory or are exempt. European Union Regulations:
Product Name: Carquest Non-Chlorinated Brake Parts Cleaner (aerosol)
Product Number (s): 1010, 1010C (CRC Part# 09621, 79621)
Page 7 of 7
RoHS Compliance: This product is compliant with Directive 2002/95/EC of the European Parliament and of the Council of 27 January 2003. This product does not contain any of the restricted substances as listed in Article 4(1) of the RoHS Directive. Additional Regulatory Information: None
Section 16: Other Information
HMIS® (II)
Health: 2
Flammability: 3
Reactivity: 0
PPE: B
Ratings range from 0 (no hazard) to 4 (severe hazard)
NFPA
Prepared By: Michelle Rudnick CRC #: 581J Revision Date: 08/26/2014 Changes since last revision: Section 15: Consumer Products VOC Regulations The information contained in this document applies to this specific material as supplied. It may not be valid for this
material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and
directions on the label. For further clarification of any information contained on this MSDS consult your supervisor, a health & safety professional, or CRC Industries. ACGIH: American Conference of Governmental Industrial Hygienists CAS: Chemical Abstract Service CFR: Code of Federal Regulations DOT: Department of Transportation DSL: Domestic Substance List g/L: grams per Liter HMIS: Hazardous Materials Identification System IARC: International Agency for Research on Cancer IATA: International Air Transport Association ICAO: International Civil Aviation Organization IMDG: International Maritime Dangerous Goods IMO: International Maritime Organization lbs./gal: pounds per gallon LC: Lethal Concentration LD: Lethal Dose
NA: Not Applicable ND: Not Determined NIOSH: National Institute of Occupational Safety & Health NFPA: National Fire Protection Association NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration PMCC: Pensky-Martens Closed Cup PPE: Personal Protection Equipment ppm: Parts per Million RoHS: Restriction of Hazardous Substances STEL: Short Term Exposure Limit TCC: Tag Closed Cup TWA: Time Weighted Average WHMIS: Workplace Hazardous Materials Information System
3
02
SAFETY DATA SHEET
1. Identification
Car Quest Multi-Purpose LubricantProduct identifier
Other means of identification
1020SDS number
1020Part No.
3403.19.1000Tariff code
LubricantRecommended use
None known.Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
RSC Chemical Solutions
Address 600 Radiator Road
Company name
Website
Telephone Customer Service:(704) 821-7643
Technical:(704) 684-1811
Emergency phone number Emergency Telephone:(303) 623-5716
Emergency Contact:RMPDC (877-740-5015)
E-mail
United States
Not available.
Indian Trail, NC 28079
2. Hazard(s) identification
Category 2Flammable aerosolsPhysical hazards
Category 2Skin corrosion/irritationHealth hazards
Category 2BSerious eye damage/eye irritation
Category 1BGerm cell mutagenicity
Category 1BCarcinogenicity
Category 2Reproductive toxicity
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 1Specific target organ toxicity, repeatedexposure
Category 2Hazardous to the aquatic environment, acutehazardEnvironmental hazards
Category 2Hazardous to the aquatic environment,long-term hazard
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Causes skin irritation. Causes eye irritation. May cause drowsiness or dizziness. May causegenetic defects. May cause cancer. Suspected of damaging fertility or the unborn child. Causesdamage to organs through prolonged or repeated exposure. Toxic to aquatic life. Toxic to aquaticlife with long lasting effects. Flammable aerosol.
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Material name: Car Quest Multi-Purpose Lubricant
1020 Version #: 01 Issue date: 05-15-2015
SDS US
Precautionary statement
Prevention Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do notspray on an open flame or other ignition source. Pressurized container: Do not pierce or burn,even after use. Do not breathe mist or vapor. Wash thoroughly after handling. Do not eat, drink orsmoke when using this product. Use only outdoors or in a well-ventilated area. Avoid release tothe environment. Wear protective gloves/protective clothing/eye protection/face protection.
Response If on skin: Wash with plenty of water. If inhaled: Remove person to fresh air and keep comfortablefor breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses,if present and easy to do. Continue rinsing. If exposed or concerned: Get medicaladvice/attention. Call a poison center/doctor if you feel unwell. If skin irritation occurs: Get medicaladvice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminatedclothing and wash before reuse. Collect spillage.
Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect fromsunlight. Do not expose to temperatures exceeding 50°C/122°F.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
classified (HNOC)
Combustible.
Supplemental information 69.21% of the mixture consists of component(s) of unknown acute hazards to the aquaticenvironment. 68.04% of the mixture consists of component(s) of unknown long-term hazards tothe aquatic environment.
3. Composition/information on ingredients
Mixtures
CAS number %Common name and synonymsChemical name
64742-52-5Distillates (petroleum),Hydrotreated Heavy Naphthenic 30 - < 40
64742-47-8Distillates (petroleum),Hydrotreated Light 30 - < 40
8052-41-3Stoddard Solvent 20 - < 30
112-34-52-(2-butoxyéthoxy) Éthanol 3 - < 5
124-38-9Carbon Dioxide 1 - < 3
25551-13-7Trimethylbenzene 1 - < 3
100-41-4ETHYLBENZENE < 1
98-82-8BENZENE,1-METHYLETHYL-< 0.3
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISONCENTER or doctor/physician if you feel unwell.Inhalation
Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Getmedical advice/attention. Wash contaminated clothing before reuse.Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.Eye contact
In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth. Donot induce vomiting without advice from poison control center. If vomiting occurs, keep head lowso that stomach content doesn't get into the lungs.
Ingestion
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Diarrhea. Irritation of eyes.Exposed individuals may experience eye tearing, redness, and discomfort. Skin irritation. Maycause redness and pain. Prolonged exposure may cause chronic effects.
Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically. Keep victim under observation.Symptoms may be delayed.Indication of immediate
medical attention and special
treatment needed
IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice(show the label where possible). Ensure that medical personnel are aware of the material(s)involved, and take precautions to protect themselves. Show this safety data sheet to the doctor inattendance.
General information
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SDS US
5. Fire-fighting measures
Powder. Alcohol resistant foam. Dry chemicals. Carbon dioxide (CO2).Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
Contents under pressure. Pressurized container may explode when exposed to heat or flame.During fire, gases hazardous to health may be formed.Specific hazards arising from
the chemical
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA.Special protective equipment
and precautions for firefighters
Move containers from fire area if you can do so without risk. Cool containers exposed to heat with
prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder ormonitor nozzles, if possible. If not, withdraw and let fire burn out.
Fire fighting
equipment/instructions
Use standard firefighting procedures and consider the hazards of other involved materials. Movecontainers from fire area if you can do so without risk. In the event of fire and/or explosion do notbreathe fumes.
Specific methods
Combustible. Flammable aerosol.General fire hazards
6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wearappropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Donot touch damaged containers or spilled material unless wearing appropriate protective clothing.Ventilate closed spaces before entering them. Local authorities should be advised if significantspillages cannot be contained. For personal protection, see section 8 of the SDS.
Personal precautions,
protective equipment and
emergency procedures
Refer to attached safety data sheets and/or instructions for use. Keep combustibles (wood, paper,oil, etc.) away from spilled material. This material is classified as a water pollutant under the CleanWater Act and should be prevented from contaminating soil or from entering sewage and drainagesystems which lead to waterways. Stop leak if you can do so without risk. Move the cylinder to asafe and open area if the leak is irreparable. Use water spray to reduce vapors or divert vaporcloud drift. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earthand place into containers. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination. For waste disposal, see section 13 of the SDS.
Methods and materials for
containment and cleaning up
Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoiddischarge into drains, water courses or onto the ground. Inform appropriate managerial orsupervisory personnel of all environmental releases.
Environmental precautions
7. Handling and storage
Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spraybutton is missing or defective. Do not spray on a naked flame or any other incandescent material.Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill,grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used
mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated contact
breastfeeding women must not handle this product. Should be handled in closed systems, ifpossible. Use only in well-ventilated areas. Wear appropriate personal protective equipment.Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrialhygiene practices.
Precautions for safe handling
Level 3 Aerosol.
Store locked up. Pressurized container. Protect from sunlight and do not expose to temperaturesexceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an openflame, heat or other sources of ignition. This material can accumulate static charge which maycause spark and become an ignition source. Keep out of the reach of children. Store away fromincompatible materials (see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
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8. Exposure controls/personal protection
Occupational exposure limits
ValueComponents FormType
PEL 245 mg/m3BENZENE,1-METHYLETHYL-(CAS 98-82-8)
50 ppm
PEL 9000 mg/m3Carbon Dioxide (CAS124-38-9)
5000 ppm
PEL 5 mg/m3 Mist.Distillates (petroleum),Hydrotreated HeavyNaphthenic (CAS64742-52-5)
2000 mg/m3
500 ppm
PEL 435 mg/m3ETHYLBENZENE (CAS100-41-4)
100 ppm
PEL 2900 mg/m3Stoddard Solvent (CAS8052-41-3)
500 ppm
US. ACGIH Threshold Limit Values
ValueComponents FormType
TWA 10 ppm Inhalable fraction andvapor.2-(2-butoxyéthoxy) Éthanol(CAS 112-34-5)TWA 50 ppmBENZENE,1-METHYLETHYL-(CAS 98-82-8)STEL 30000 ppmCarbon Dioxide (CAS124-38-9)TWA 5000 ppm
TWA 5 mg/m3 Inhalable fraction.Distillates (petroleum),Hydrotreated HeavyNaphthenic (CAS64742-52-5)
TWA 20 ppmETHYLBENZENE (CAS100-41-4)
TWA 100 ppmStoddard Solvent (CAS8052-41-3)
TWA 25 ppmTrimethylbenzene (CAS25551-13-7)
US. NIOSH: Pocket Guide to Chemical Hazards
ValueComponents FormType
TWA 245 mg/m3BENZENE,1-METHYLETHYL-(CAS 98-82-8)
50 ppm
STEL 54000 mg/m3Carbon Dioxide (CAS124-38-9)
30000 ppm
TWA 9000 mg/m3
5000 ppm
Ceiling 1800 mg/m3Distillates (petroleum),Hydrotreated HeavyNaphthenic (CAS64742-52-5)
STEL 10 mg/m3 Mist.
TWA 100 mg/m3Distillates (petroleum),Hydrotreated Light (CAS64742-47-8)
STEL 545 mg/m3ETHYLBENZENE (CAS100-41-4)
125 ppm
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US. NIOSH: Pocket Guide to Chemical Hazards
ValueComponents FormType
TWA 435 mg/m3
100 ppm
Ceiling 1800 mg/m3Stoddard Solvent (CAS8052-41-3)TWA 350 mg/m3
Biological limit values
ValueComponents Determinant Specimen Sampling Time
0.15 g/g Sum ofmandelic acidandphenylglyoxylicacid
Creatinine inurine *ETHYLBENZENE (CAS100-41-4)
* - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
BENZENE,1-METHYLETHYL- (CAS 98-82-8)Can be absorbed through the skin.
US - Minnesota Haz Subs: Skin designation applies
BENZENE,1-METHYLETHYL- (CAS 98-82-8)Skin designation applies.
US - Tennessee OELs: Skin designation
BENZENE,1-METHYLETHYL- (CAS 98-82-8)Can be absorbed through the skin.
US NIOSH Pocket Guide to Chemical Hazards: Skin designation
BENZENE,1-METHYLETHYL- (CAS 98-82-8)Can be absorbed through the skin.
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
BENZENE,1-METHYLETHYL- (CAS 98-82-8)Can be absorbed through the skin.
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation ratesshould be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,or other engineering controls to maintain airborne levels below recommended exposure limits. Ifexposure limits have not been established, maintain airborne levels to an acceptable level. Eye
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Chemical respirator with organic vapor cartridge and full facepiece.Eye/face protection
Skin protection
Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glovesupplier.Hand protection
Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.Other
Chemical respirator with organic vapor cartridge and full facepiece.Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
When using do not smoke. Always observe good personal hygiene measures, such as washingafter handling the material and before eating, drinking, and/or smoking. Routinely wash workclothing and protective equipment to remove contaminants.
General hygiene
considerations
9. Physical and chemical properties
Liquid. Clear.Appearance
Liquid.Physical state
Aerosol.Form
YellowColor
PetroleumOdor
Odor threshold Not available.
pH Not available.
Melting point/freezing point -94 °F (-70 °C) estimated
Initial boiling point and boiling
range
302 °F (150 °C) estimated
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SDS US
Flash point 142.0 °F (61.1 °C) Tag Closed Cup
Evaporation rate Not available.
Not applicable.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
0.7 % estimated
Flammability limit - upper
(%)
6 % estimated
Explosive limit - lower (%)Not available.
Explosive limit - upper (%)Not available.
Vapor pressure 1.21 hPa estimated
Vapor density Not available.
Relative density Not available.
Solubility(ies)
Solubility (water)Not available.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature 410 °F (210 °C) estimated
Decomposition temperature Not available.
Viscosity Not available.
Other information
Density 7.38 lbs/gal estimated
Not explosive.Explosive properties
Flame extension > 26 in
Flammability (flash back)No
Flammability class Combustible IIIA estimated
Heat of combustion (NFPA
30B)
35.23 kJ/g estimated
Not oxidizing.Oxidizing properties
Percent volatile 5.53 % estimated
Specific gravity 0.88 estimated
VOC (Weight %)23.31 %
10. Stability and reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity
Material is stable under normal conditions.Chemical stability
Hazardous polymerization does not occur.Possibility of hazardous
reactions
Avoid temperatures exceeding the flash point. Contact with incompatible materials.Conditions to avoid
Strong oxidizing agents.Incompatible materials
No hazardous decomposition products are known.Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause damage to organs through prolonged or repeated exposure by inhalation. May causedrowsiness and dizziness. Headache. Nausea, vomiting.
Skin contact Causes skin irritation.
Eye contact Causes eye irritation.
Ingestion Expected to be a low ingestion hazard.
Symptoms related to the
physical, chemical and
toxicological characteristics
Headache. May cause drowsiness and dizziness. Nausea, vomiting. Diarrhea. Irritation of eyes.Exposed individuals may experience eye tearing, redness, and discomfort. Skin irritation. Maycause redness and pain.
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SDS US
Information on toxicological effects
Narcotic effects.
Test ResultsComponentsSpecies
2-(2-butoxyéthoxy) Éthanol (CAS 112-34-5)
Dermal
Acute
LD50 Rabbit 2700 mg/kg
Oral
LD50 Guinea pig 2000 mg/kg
Mouse 2400 mg/kg
Rabbit 2200 mg/kg
Rat 4500 mg/kg
BENZENE,1-METHYLETHYL- (CAS 98-82-8)
Inhalation
Acute
LC50 Mouse 2000 ppm, 7 Hours
24.7 mg/l, 2 Hours
Rat 8000 ppm, 4 Hours
Oral
LD50 Rat 1400 mg/kg
ETHYLBENZENE (CAS 100-41-4)
Dermal
Acute
LD50 Rabbit 17800 mg/kg
Oral
LD50 Rat 3500 mg/kg
Trimethylbenzene (CAS 25551-13-7)
Oral
Acute
* Estimates for product may be based on additional component data not shown.
LD50 Rat 8970 mg/kg
Causes skin irritation.Skin corrosion/irritation
Causes eye irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Not a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitization
May cause genetic defects.Germ cell mutagenicity
May cause cancer.
IARC Monographs. Overall Evaluation of Carcinogenicity
BENZENE,1-METHYLETHYL- (CAS 98-82-8)2B Possibly carcinogenic to humans.
ETHYLBENZENE (CAS 100-41-4)2B Possibly carcinogenic to humans.
Stoddard Solvent (CAS 8052-41-3)3 Not classifiable as to carcinogenicity to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
US. National Toxicology Program (NTP) Report on Carcinogens
Distillates (petroleum), Hydrotreated Heavy Naphthenic(CAS 64742-52-5)Known To Be Human Carcinogen.
Suspected of damaging fertility or the unborn child.Reproductive toxicity
Specific target organ toxicity -
single exposure
May cause drowsiness and dizziness.
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SDS US
Specific target organ toxicity -
repeated exposure
Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard Not an aspiration hazard.
Chronic effects Causes damage to organs through prolonged or repeated exposure. Prolonged inhalation may beharmful. Prolonged exposure may cause chronic effects.
12. Ecological information
Toxic to aquatic life with long lasting effects.Ecotoxicity
Components Test ResultsSpecies
2-(2-butoxyéthoxy) Éthanol (CAS 112-34-5)
Aquatic
LC50Fish 1300 mg/l, 96 hoursBluegill (Lepomis macrochirus)
BENZENE,1-METHYLETHYL- (CAS 98-82-8)
Aquatic
EC50Crustacea 3.55 - 11.29 mg/l, 48 hoursBrine shrimp (Artemia sp.)
LC50Fish 2.7 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss)
Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8)
Aquatic
LC50Fish 2.9 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss)
ETHYLBENZENE (CAS 100-41-4)
Aquatic
EC50Crustacea 1.37 - 4.4 mg/l, 48 hoursWater flea (Daphnia magna)
* Estimates for product may be based on additional component data not shown.
LC50Fish 7.5 - 11 mg/l, 96 hoursFathead minnow (Pimephales promelas)
No data is available on the degradability of this product. Persistence and degradability
Bioaccumulative potential
2-(2-butoxyéthoxy) Éthanol 0.56BENZENE,1-METHYLETHYL-3.66ETHYLBENZENE3.15Stoddard Solvent 3.16 - 7.15
No data available.Mobility in soil
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contentsunder pressure. Do not puncture, incinerate or crush. Do not allow this material to drain intosewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or usedcontainer. Dispose of contents/container in accordance with local/regional/national/internationalregulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulations
The waste code should be assigned in discussion between the user, the producer and the wastedisposal company.Hazardous waste code
Dispose of in accordance with local regulations. Empty containers or liners may retain someproduct residues. This material and its container must be disposed of in a safe manner (see:Disposal instructions).
Waste from residues / unused
products
Since emptied containers may retain product residue, follow label warnings even after container isemptied. Empty containers should be taken to an approved waste handling site for recycling ordisposal. Do not re-use empty containers.
Contaminated packaging
14. Transport information
DOT
Not available.UN number
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Material name: Car Quest Multi-Purpose Lubricant
1020 Version #: 01 Issue date: 05-15-2015
SDS US
Comsumer CommodityUN proper shipping name
ORM-DClass
Transport hazard class(es)
-Subsidiary risk
2.2Label(s)
Not applicable.Packing group
YesMarine pollutant
Environmental hazards
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
T75, TP5Special provisions
304Packaging non bulk
314, 315Packaging bulk
IATA
UN1950UN number Aerosols, flammableUN proper shipping name
2Class
Transport hazard class(es)
-Subsidiary risk
IIIPacking group YesEnvironmental hazards
9LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
Allowed.Passenger and cargo
aircraft
Other information
Allowed.Cargo aircraft only
IMDG
UN1950UN number Aerosols, flammableUN proper shipping name
2Class
Transport hazard class(es)
-Subsidiary risk
Not applicable.Packing group
YesMarine pollutant
Environmental hazards
F-D, S-UEmSRead safety instructions, SDS and emergency procedures before handling.Special precautions for user
Not established.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
IATA; IMDG
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Marine pollutant
IMDG Regulated Marine Pollutant. DOT Regulated Marine Pollutant.General information
15. Regulatory information
This product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
2-(2-butoxyéthoxy) Éthanol (CAS 112-34-5)Listed.BENZENE,1-METHYLETHYL- (CAS 98-82-8)Listed.
ETHYLBENZENE (CAS 100-41-4)Listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - YesDelayed Hazard - YesFire Hazard - YesPressure Hazard - NoReactivity Hazard - No
Hazard categories
SARA 302 Extremely hazardous substance
Not listed.
NoSARA 311/312 Hazardous
chemical
SARA 313 (TRI reporting)
Chemical name CAS number % by wt.
2-(2-butoxyéthoxy) Éthanol 112-34-5 3 - < 5ETHYLBENZENE100-41-4 < 1
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
2-(2-butoxyéthoxy) Éthanol (CAS 112-34-5)
BENZENE,1-METHYLETHYL- (CAS 98-82-8)
ETHYLBENZENE (CAS 100-41-4)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Not regulated.Safe Drinking Water Act
(SDWA)
US state regulations
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd.
(a))
2-(2-butoxyéthoxy) Éthanol (CAS 112-34-5)BENZENE,1-METHYLETHYL- (CAS 98-82-8)
Distillates (petroleum), Hydrotreated Heavy Naphthenic (CAS 64742-52-5)
Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8)
ETHYLBENZENE (CAS 100-41-4)
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SDS US
Stoddard Solvent (CAS 8052-41-3)Trimethylbenzene (CAS 25551-13-7)
US. Massachusetts RTK - Substance List
BENZENE,1-METHYLETHYL- (CAS 98-82-8)
Carbon Dioxide (CAS 124-38-9)
Distillates (petroleum), Hydrotreated Heavy Naphthenic (CAS 64742-52-5)
Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8)ETHYLBENZENE (CAS 100-41-4)Stoddard Solvent (CAS 8052-41-3)Trimethylbenzene (CAS 25551-13-7)
US. New Jersey Worker and Community Right-to-Know Act
2-(2-butoxyéthoxy) Éthanol (CAS 112-34-5)
BENZENE,1-METHYLETHYL- (CAS 98-82-8)
Carbon Dioxide (CAS 124-38-9)
Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8)
ETHYLBENZENE (CAS 100-41-4)
Stoddard Solvent (CAS 8052-41-3)
Trimethylbenzene (CAS 25551-13-7)
US. Pennsylvania Worker and Community Right-to-Know Law
2-(2-butoxyéthoxy) Éthanol (CAS 112-34-5)BENZENE,1-METHYLETHYL- (CAS 98-82-8)Carbon Dioxide (CAS 124-38-9)
Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8)
ETHYLBENZENE (CAS 100-41-4)
Stoddard Solvent (CAS 8052-41-3)
Trimethylbenzene (CAS 25551-13-7)
US. Rhode Island RTK
2-(2-butoxyéthoxy) Éthanol (CAS 112-34-5)BENZENE,1-METHYLETHYL- (CAS 98-82-8)ETHYLBENZENE (CAS 100-41-4)
US. California Proposition 65
WARNING: This product contains a chemical known to the State of California to cause cancer.
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
BENZENE,1-METHYLETHYL- (CAS 98-82-8)Listed: April 6, 2010
ETHYLBENZENE (CAS 100-41-4)Listed: June 11, 2004
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
YesAustraliaAustralian Inventory of Chemical Substances (AICS)
YesCanadaDomestic Substances List (DSL)
NoCanadaNon-Domestic Substances List (NDSL)
YesChinaInventory of Existing Chemical Substances in China (IECSC)
YesEuropeEuropean Inventory of Existing Commercial ChemicalSubstances (EINECS)
NoEuropeEuropean List of Notified Chemical Substances (ELINCS)
NoJapanInventory of Existing and New Chemical Substances (ENCS)
YesKoreaExisting Chemicals List (ECL)
YesNew Zealand New Zealand Inventory
YesPhilippinesPhilippine Inventory of Chemicals and Chemical Substances(PICCS)
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
country(s).
16. Other information, including date of preparation or last revision
05-15-2015Issue date
Version #01
11 / 12
Material name: Car Quest Multi-Purpose Lubricant
1020 Version #: 01 Issue date: 05-15-2015
SDS US
The information provided in this Safety Data Sheet is correct to the best of our knowledge,information and belief at the date of its publication. The information given is designed only as aguidance for safe handling, use, processing, storage, transportation, disposal and release and isnot to be considered a warranty or quality specification. The information relates only to the specificmaterial designated and may not be valid for such material used in combination with any othermaterials or in any process, unless specified in the text.
Disclaimer
12 / 12
Material name: Car Quest Multi-Purpose Lubricant
1020 Version #: 01 Issue date: 05-15-2015
SDS US
Better than it has to be
1601 McCloskey Boulevard
Hookers Point - Tampa, Florida 33605 U.S.A.
E-MAIL: info@amalie.com
www.amalie.com
Compounding
Blending Blow Molding Packaging
815852082 Safety data sheet
according to 1907/2006/EC (REACH),
1272/2008/EC (CLP), and GHS
Page 1/9
Revision: 2/01/2015
1 Identification of the substance/mixture and of the company/undertaking
· 1.1 Product identifier
· Trade name: CARQUEST SAE 5W-20
· Application of the substance / the preparation Product Component
· 1.3 Details of the supplier of the Safety Data Sheet
· Manufacturer/Supplier: CARQUEST MADE IN USA
· 1.4 Emergency telephone number: ChemTel Inc. (800)255-3924, +1 (813)248-0585
2 Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 The product is not classified according to the CLP regulation.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable.
· Information concerning particular hazards for human and environment: The product does not have to be labeled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. · Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. The classification is in accordance with the latest editions of international substances lists, and is supplemented by information from technical literature and by information provided by the company.
· 2.2 Label elements · Labeling according to Regulation (EC) No 1272/2008 N/A · Hazard pictograms N/A · Signal word N/A · Hazard statements N/A · Hazard description: · WHMIS-symbols: Not hazardous under WHMIS. (Contd. on page 2)
Page 2/9 Safety data sheet
according to 1907/2006/EC (REACH),
Revision: 02/01/2015
Trade name: CARQUEST SAE 5W-20
· HMIS Long Term Health Hazard Substances
None of the ingredients is listed.
· 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable.
(Contd. of page 1)
3 Composition/information on ingredients · 3.2 Mixtures · Description: Mixture of substances listed below with nonhazardous additions.
Dangerous components:
EINECS: 265-157-1 Index number: 649-467-00-8 substance with a Community workplace exposure limit Carc. Cat. 2
EINECS: 265-169-7 Carc. Cat. 2 26%
· Additional information:
Note L: The classification as a carcinogen need not apply if it can be shown that the substance contains less than 3 % DMSO extract as measured by IP 346 ‘Determination of polycyclic aromatics in unused lubricating base oils and asphaltene free petroleum fractions - Dimethyl sulphoxide extraction refractive index method’, Institute of Petroleum, London. This product meets these requirements. For the wording of the listed risk phrases refer to section 16.
4 First aid measures · 4.1 Description of first aid measures
· General information: No special measures required. · After inhalation: Supply fresh air; consult doctor in case of complaints. · After skin contact: Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. · After eye contact: Remove contact lenses if worn. Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting; call for medical help immediately. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. (Contd. on page 3)
Page 3/9 Safety data sheet
according to 1907/2006/EC (REACH),
Revision: 02/01/2015
Trade name: CARQUEST SAE 5W-20
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
(Contd. of page 2)
5 Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents: Carbon dioxide Water haze or fog Foam Fire-extinguishing powder · For safety reasons unsuitable extinguishing agents: W ater with full jet · 5.2 Special hazards arising from the substance or mixture In case of fire, the following can be released: Carbon monoxide (CO) Under certain fire conditions, traces of other toxic gases cannot be excluded. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit. 6 Accidental release measures
· 6.1 Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water. Prevent from spreading (e.g. by damming-in or oil barriers). · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Send for recovery or disposal in suitable receptacles. Do not flush with water or aqueous cleansing agents · 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.
7 Handling and storage
· 7.1 Precautions for safe handling Avoid the formation of oil haze.
· Information about fire - and explosion protection: No special measures required.
· 7.2 Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: No special requirements.
(Contd. on page 4)
Page 4/9 Safety data sheet
according to 1907/2006/EC (REACH),
Revision: 02/01/2015
Trade name: CARQUEST SAE 5W-20
· Information about storage in one common storage facility:
Store away from foodstuffs. Store away from oxidizing agents.
(Contd. of page 3)
· Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. · 7.3 Specific end use(s) No further relevant information available.
8 Exposure controls/personal protection · Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
Ingredients with limit values that require monitoring at the workplace:
64742-54-7 Distillates (petroleum), hydrotreated heavy paraffinic
TLV (USA) Short-term value: 10 mg/m³ Long-term value: 5 mg/m³
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls · Personal protective equipment: · General protective and hygienic measures: The usual precautionary measures are to be adhered to when handling chemicals. Keep away from foodstuffs, beverages and feed. Avoid contact with the eyes. · Respiratory protection: Not necessary if room is well-ventilated. Use suitable respiratory protective device in case of insufficient ventilation. · Protection of hands:
Protective gloves
Oil resistant gloves · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. · Eye protection:
Safety glasses
Goggles recommended during refilling
(Contd. on page 5)
Page 5/9 Safety data sheet
according to 1907/2006/EC (REACH),
Revision: 02/01/2015
Trade name: CARQUEST SAE 5W-20
(Contd. of page 4)
9 Physical and chemical properties
· 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Oily Colour: Amber coloured · Odour: Characteristic · Odour threshold: Not determined.
· pH-value: Not determined.
· Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: Undetermined.
· Flash point: 200°C (392°F)
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature: Not determined.
· Decomposition temperature: Not determined.
· Self-igniting: Product is not self-igniting.
· Danger of explosion: Product does not present an explosion hazard.
· Explosion limits: Lower: Not determined. Upper: Not determined.
· Vapour pressure: Not determined.
· Density at 20°C: 0,86 g/cm³ · Relative density Not determined. · Vapour density Not determined. · Evaporation rate Not determined.
· Solubility in / Miscibility with water: Not miscible or difficult to mix.
· Partition coefficient (n-octanol/water): > 2,0 log POW (Estimate)
· Viscosity: Viscosity Index: 140 Kinematic at 40°C: 50 cSt (8,5 cSt @ 100°C)
· Solvent content: Organic solvents: 0,0 % · 9.2 Other information No further relevant information available.
(Contd. on page 6)
Page 6/9 Safety data sheet
according to 1907/2006/EC (REACH),
Revision: 02/01/2015
Trade name: CARQUEST SAE 5W-20
(Contd. of page 5)
10 Stability and reactivity · 10.1 Reactivity · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications. · 10.3 Possibility of hazardous reactions Reacts with strong oxidizing agents. · 10.4 Conditions to avoid Store away from oxidizing agents. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: Carbon monoxide and carbon dioxide Possible in traces. Sulphur oxides (SOx) Nitrogen oxides (NOx)
11 Toxicological information · 11.1 Information on toxicological effects
· Acute toxicity: LD/LC50 values relevant for classification:
· Primary irritant effect:
· on the skin: Slight irritant effect on skin and mucous membranes. · on the eye: Slight irritant effect on eyes. · Sensitization: Sensitizing effect by skin contact is possible by prolonged exposure. · Additional toxicological information: The product is not subject to classification according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version. When used and handled according to specifications, the product does not have any harmful effects to our experience and the information provided to us.
12 Ecological information
· 12.1 Toxicity
· Aquatic toxicity: The material is harmful to the environment. · 12.2 Persistence and degradability Not easily biodegradable · 12.3 Bioaccumulative potential May be accumulated in organism · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water Danger to drinking water if even small quantities leak into the ground. Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. (Contd. on page 7)
Page 7/9 Safety data sheet
according to 1907/2006/EC (REACH),
Revision: 02/01/2015
Trade name: CARQUEST SAE 5W-20
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available.
(Contd. of page 6)
13 Disposal considerations
· 13.1 Waste treatment methods · Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system. Can be reused after reprocessing. Delivery of waste oil to officially authorized collectors only.
· Uncleaned packaging: · Recommendation: Disposal must be made according to official regulations.
14 Transport information
· 14.1 UN-Number · DOT, ADN, IMDG, IATA N/A
· 14.2 UN proper shipping name
· DOT, ADR, ADN, IMDG, IATA N/A
· 14.3 Transport hazard class(es)
· DOT, ADR, ADN, IMDG, IATA · Class N/A
· 14.4 Packing group · DOT, ADR, IMDG, IATA N/A
· 14.5 Environmental hazards: · Marine pollutant: No
· 14.6 Special precautions for user Not applicable.
· 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable.
· UN "Model Regulation": -
(Contd. on page 8)
Page 8/9 Safety data sheet
according to 1907/2006/EC (REACH),
Revision: 02/01/2015
Trade name: CARQUEST SAE 5W-20
(Contd. of page 7)
15 Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · United States (USA) · SARA
Section 355 (extremely hazardous substances):
· Section 313 (Specific toxic chemical listings):
· TSCA (Toxic Substances Control Act):
· Proposition 65 (California):
Chemicals known to cause cancer:
· Chemicals known to cause reproductive toxicity for females:
· Chemicals known to cause reproductive toxicity for males:
· Chemicals known to cause developmental toxicity:
· Carcinogenic Categories
EPA (Environmental Protection Agency)
· IARC (International Agency for Research on Cancer)
TLV (Threshold Limit Value established by ACGIH)
· MAK (German Maximum Workplace Concentration)
· NIOSH-Ca (National Institute for Occupational Safety and Health)
· OSHA-Ca (Occupational Safety & Health Administration)
· Canada Canadian Domestic Substances List (DSL)
· Canadian Ingredient Disclosure list (limit 0.1%)
(Contd. on page 9)
Page 9/9 Safety data sheet
according to 1907/2006/EC (REACH),
Revision: 02/01/2015
Trade name: CARQUEST SAE 5W-20
· Canadian Ingredient Disclosure list (limit 1%)
None of the ingredients is listed.
(Contd. of page 8)
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.
· Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labeling of Chemicals ACGIH: American Conference of Governmental Industrial Hygienists LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent · Sources The manufacturer believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. No warranty of fitness, warranty of merchantability or any other warranty, expressed or implied, is made concerning the information provided herein. The information provided herein relates only to the specific product designated and may not be valid where such product is used in combination with any other materials or process. Further, since the conditions and methods of use of this product and of the information referred to herein are beyond the control of the manufacturer, the manufacturer expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information. This document was authored and reviewed by the technical and scientific staff at Chem Tel Inc. Descriptions, classifications and calculations are based upon data provided by manufacturer and augmented by published data in conjunction with expert analysis by degreed scientists. SDS Prepared by: ChemTel Inc. 1305 North Florida Avenue Tampa, Florida USA 33602-2902 Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573 Website: www.chemtelinc.com
AOCUSA
1601 McCloskey Boulevard Tampa, Florida 33605 U.S.A. E-MAIL:
Telephone: (813)248-1988 Fax: (813) 248-1488
847403282
Page 1/9
Safety data sheet
according to 1907/2006/EC (REACH),
1272/2008/EC (CLP), and GHS Revision: 07.17.2015
1 Identification of the substance/mixture and of the company/undertaking
· 1.1 Product identifier
· Trade name: FRAM PREMIUM HYDRAULIC AW 32
· Application of the substance / the preparation Lubricating Oils
· 1.3 Details of the supplier of the Safety Data Sheet · Manufacturer/Supplier: AOCUSA Made in U.S.A.
· 1.4 Emergency telephone number: ChemTel Inc.
(800)255-3924, +1 (813)248-0585
2 Hazards identification
· 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008
The product is not classified according to the CLP regulation.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable.
· Information concerning particular hazards for human and environment: The product does not have to be labeled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. · Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. The classification is in accordance with the latest editions of international s ubstances lists, and is supplemented by information from technical literature and by information provided by the company.
· 2.2 Label elements
· Labeling according to Regulation (EC) No 1272/2008 N/A · Hazard pictograms N/A · Signal word N/A · Hazard statements N/A · Hazard description: · WHMIS-symbols: Not hazardous under WHMIS.
(Contd. on page 2)
Page 2/9 Safety data sheet
according to 1907/2006/EC (REACH),
1272/2008/EC (CLP), and GHS
Trade name: FRAM PREMIUM HYDRAULIC AW 32
· HMIS Long Term Health Hazard Substances
None of the ingredients is listed.
· 2.3 Other hazards · Results of PBT and vPvB assessment
· PBT: Not applicable. · vPvB: Not applicable.
(Contd. of page 1)
3 Composition/information on ingredients · 3.2 Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
CAS: 64742-54-7 EINECS: 265-157-1 Index number: 649-467-00-8
Distillates (petroleum), hydrotreated heavy paraffinic substance with a Community workplace exposure limit Carc. Cat. 2
99%
· Additional information: Note L: The classification as a carcinogen need not apply if it can be shown that the substance contains less than 3 % DMSO extract as measured by IP 346 ‘Determination of polycyclic aromatics in unused lubricating base oils and asphaltene free petroleum fractions - Dimethyl sulphoxide extraction refractive index method’, Institute of Petroleum, London. This product meets these requirements.
For the wording of the listed risk phrases refer to section 16.
4 First aid measures
· 4.1 Description of first aid measures
· General information: No special measures required. · After inhalation: Supply fresh air; consult doctor in case of complaints. · After skin contact:
Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. · After eye contact:
Remove contact lenses if worn. Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing:
Rinse out mouth and then drink plenty of water. Do not induce vomiting; call for medical help immediately. · 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available. (Contd. on page 3)
Page 3/9 Safety data sheet
according to 1907/2006/EC (REACH),
1272/2008/EC (CLP), and GHS
Trade name: FRAM PREMIUM HYDRAULIC AW 32
(Contd. of page 2)
5 Firefighting measures
· 5.1 Extinguishing media
· Suitable extinguishing agents: Carbon dioxide Water haze or fog Foam Fire-extinguishing powder
· For safety reasons unsuitable extinguishing agents: Water with full jet · 5.2 Special hazards arising from the substance or mixture Sulphur dioxide (SO2) Nitrogen oxides (NOx) Carbon monoxide (CO) · 5.3 Advice for firefighters · Protective equipment:
Wear self-contained respiratory protective device. Wear fully protective suit.
6 Accidental release measures
· 6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation
· 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water. Prevent from spreading (e.g. by damming-in or oil barriers). · 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Send for recovery or disposal in suitable receptacles. Do not flush with water or aqueous cleansing agents
· 6.4 Reference to other sections
See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.
7 Handling and storage
· 7.1 Precautions for safe handling Avoid the formation of oil haze.
· Information about fire - and explosion protection: No special measures required.
· 7.2 Conditions for safe storage, including any incompatibilities · Storage:
· Requirements to be met by storerooms and receptacles: No special requirements. · Information about storage in one common storage facility: Store away from oxidizing agents.
· Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. (Contd. on page 4)
Page 4/9 Safety data sheet
according to 1907/2006/EC (REACH),
1272/2008/EC (CLP), and GHS
Trade name: FRAM PREMIUM HYDRAULIC AW 32 · 7.3 Specific end use(s) No further relevant information available.
(Contd. of page 3)
8 Exposure controls/personal protection · Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
64742-54-7 Distillates (petroleum), hydrotreated heavy paraffinic
PEL (USA) TLV (USA) 5 mg/m³ Short-term value: 10 mg/m³ Long-term value: 5 mg/m³
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls · Personal protective equipment:
· General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing The usual precautionary measures are to be adhered to when handling chemicals. · Respiratory protection:
Not necessary if room is well-ventilated. Use suitable respiratory protective device in case of insufficient ventilation. · Protection of hands:
Protective gloves
Oil resistant gloves · Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. · Eye protection:
Safety glasses
Goggles recommended during refilling · Body protection: Protective work clothing (Contd. on page 5)
Page 5/9 Safety data sheet
according to 1907/2006/EC (REACH),
1272/2008/EC (CLP), and GHS
Trade name: FRAM PREMIUM HYDRAULIC AW 32
(Contd. of page 4)
9 Physical and chemical properties
· 9.1 Information on basic physical and chemical properties
· General Information · Appearance:
Form: Oily
Colour: Amber coloured · Odour: Characteristic · Odour threshold: Not determined.
· pH-value: Not determined.
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: Undetermined.
· Flash point: 200°C (392°F)
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature:
Decomposition temperature: Not determined.
· Self-igniting: Product is not self-igniting.
· Danger of explosion: Product does not present an explosion hazard.
· Explosion limits:
Lower: Not determined. Upper: Not determined.
· Vapour pressure: Not determined.
· Density at 20°C: 0,87 g/cm³
· Relative density Not determined. · Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· Partition coefficient (n-octanol/water): > 2,0 log POW (Estimate)
· Viscosity: Viscosity Index: 100
Kinematic at 40°C: 32 cSt (5,5 @ 100°C)
· Solvent content:
Organic solvents: 0,0 %
· 9.2 Other information No further relevant information available.
(Contd. on page 6)
Page 6/9 Safety data sheet
according to 1907/2006/EC (REACH),
1272/2008/EC (CLP), and GHS
Trade name: FRAM PREMIUM HYDRAULIC AW 32
(Contd. of page 5)
10 Stability and reactivity
· 10.1 Reactivity
· 10.2 Chemical stability · Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions Reacts with strong oxidizing agents. · 10.4 Conditions to avoid Store away from oxidizing agents.
· 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products:
Carbon monoxide and carbon dioxide Possible in traces. Sulphur oxides (SOx) Nitrogen oxides (NOx)
11 Toxicological information · 11.1 Information on toxicological effects · Acute toxicity: · LD/LC50 values relevant for classification:
Oral
Dermal
LD50
LD50
>2000 mg/kg (rat)
>2000 mg/kg (rabbit)
· Primary irritant effect:
· on the skin: Slight irritant effect on skin and mucous membranes. · on the eye: Slight irritant effect on eyes.
· Sensitization: Sensitizing effect by skin contact is possible by prolonged exposure. · Additional toxicological information:
The product is not subject to classification according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version.
When used and handled according to specifications, the product does not have any harmful effects to our experience and the information provided to us.
12 Ecological information · 12.1 Toxicity
· Aquatic toxicity: The material is harmful to the environment. · 12.2 Persistence and degradability Not easily biodegradable · 12.3 Bioaccumulative potential May be accumulated in organism
· 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water Danger to drinking water if even small quantities leak into the ground. Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. (Contd. on page 7)
Page 7/9 Safety data sheet
according to 1907/2006/EC (REACH),
1272/2008/EC (CLP), and GHS
Trade name: FRAM PREMIUM HYDRAULIC AW 32 · 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable. · vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.
(Contd. of page 6)
13 Disposal considerations
· 13.1 Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system. Can be reused after reprocessing. Delivery of waste oil to officially authorized collectors only.
· Uncleaned packaging: · Recommendation: Disposal must be made according to official regulations.
14 Transport information
· 14.1 UN-Number · DOT, ADN, IMDG, IATA N/A
· 14.2 UN proper shipping name
· DOT, ADR, ADN, IMDG, IATA N/A
· 14.3 Transport hazard class(es)
· DOT, ADR, ADN, IMDG, IATA
· Class N/A
· 14.4 Packing group
· DOT, ADR, IMDG, IATA N/A
· 14.5 Environmental hazards:
· Marine pollutant: No
· 14.6 Special precautions for user Not applicable.
· 14.7 Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
· UN "Model Regulation": -
(Contd. on page 8)
Page 8/9 Safety data sheet
according to 1907/2006/EC (REACH),
1272/2008/EC (CLP), and GHS
Trade name: FRAM PREMIUM HYDRAULIC AW 32
(Contd. of page 7)
15 Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· United States (USA)
· SARA
· Section 355 (extremely hazardous substances):
None of the ingredients is listed.
· Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
· TSCA (Toxic Substances Control Act):
All ingredients are listed.
· Proposition 65 (California):
· Chemicals known to cause cancer:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
· Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
· Carcinogenic Categories
· EPA (Environmental Protection Agency)
None of the ingredients is listed.
· IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
· TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
· MAK (German Maximum Workplace Concentration)
None of the ingredients is listed.
· NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
· OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
· Canada
· Canadian Domestic Substances List (DSL)
All ingredients are listed.
· Canadian Ingredient Disclosure list (limit 0.1%)
None of the ingredients is listed.
(Contd. on page 9)
Page 9/9 Safety data sheet
according to 1907/2006/EC (REACH),
1272/2008/EC (CLP), and GHS
Trade name: FRAM PREMIUM HYDRAULIC AW 32
· Canadian Ingredient Disclosure list (limit 1%)
None of the ingredients is listed.
(Contd. of page 8)
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labeling of Chemicals ACGIH: American Conference of Governmental Industrial Hygienists LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent The manufacturer believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. No warranty of fitness, warranty of merchantability or any other warranty, expressed or implied, is made concerning the information provided herein. The information provided herein relates only to the specific product designated and may not be valid where such product is used in combination with any other materials or process. Further, since the conditions and methods of use of this product and of the information referred to herein are beyond the control of the manufacturer, the manufacturer expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information. This document was authored and reviewed by the technical and scientific staff at ChemTel Inc. Descriptions, classifications and calculations are bas ed upon data provided by manufacturer and augmented by published data in conjunction with expert analysis by degreed scientists. SDS Prepared by: ChemTel Inc. 1305 North Florida Avenue Tampa, Florida USA 33602-2902 Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573 Website: www.chemtelinc.com
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS
Page: 1/9
Revision: 20 March 2021
SECTION 1: Identification of the substance/mixture and of the company/ undertaking
ꞏ 1.1 Product identifier
ꞏ Trade name: FRAM POWER STEERING FLUID ꞏ CAS number: 64742-54-7 ꞏ EC number: 265-157-1 ꞏ Index number: 649-467-00-8 ꞏ Registration number: 01-2119484627-25-XXXX ꞏ 1.2 Relevant identified uses of the substance or mixture and uses advised against ꞏ Application of the substance / the mixture: Lubricant ꞏ Uses advised against: No further relevant information available.
ꞏ 1.3 Details of the supplier of the Safety Data Sheet ꞏ Manufacturer/Supplier:
1601 McCloskey Boulevard Tampa, FL 33605 Phone: 813-248-1988 Technical or Further Information: 1-800-368-1264
ꞏ 1.4 Emergency telephone number: ChemTel Inc. (800)255-3924 (North America) +1 (813)248-0585 (International)
SECTION 2: Hazards identification
ꞏ 2.1 Classification of the substance or mixture
ꞏ Classification according to Regulation (EC) No 1272/2008 The product is not classified as hazardous according to the Globally Harmonized System (GHS). The product is not classified as hazardous according to OSHA GHS regulations within the United States.
The substance is not classified as hazardous according to the CLP regulation.
ꞏ 2.2 Label elements ꞏ Labelling according to Regulation (EC) No 1272/2008
(Cont'd. on page 2)
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Revision: 20 March 2021
Trade name:FRAM POWER STEERING FLUID
(Cont'd. from page 1) The product is not classified as hazardous according to OSHA GHS regulations within the United States. The product is not classified as hazardous according to the CLP regulation. ꞏ Hazard pictograms None. ꞏ Signal word Not Regulated ꞏ Hazard statements None ꞏ Precautionary statements None.
ꞏ 2.3 Other hazards There are no other hazards not otherwise classified that have been identified. ꞏ Results of PBT and vPvB assessment ꞏ PBT: Not applicable. ꞏ vPvB: Not applicable.
SECTION 3: Composition/information on ingredients
ꞏ 3.1 Substances ꞏ CAS No. Description 64742-54-7 distillates (petroleum), hydrotreated heavy paraffinic ꞏ Identification number(s) ꞏ EC number: 265-157-1 ꞏ Index number: 649-467-00-8 ꞏ Additional information: Note L: The classification as a carcinogen need not apply if it can be shown that the substance contains less than 3 % DMSO extract as measured by IP 346 ‘Determination of polycyclic aromatics in unused lubricating base oils and asphaltene free petroleum fractions - Dimethyl sulphoxide extraction refractive index method’, Institute of Petroleum, London. This product meets these requirements.
SECTION 4: First aid measures
ꞏ 4.1 Description of first aid measures ꞏ After inhalation: Supply fresh air; consult doctor in case of complaints.
ꞏ After skin contact: Immediately wash with water and soap and rinse thoroughly. If skin irritation is experienced, consult a doctor. ꞏ After eye contact: Remove contact lenses if worn. Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. ꞏ After swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting; call for medical help immediately. ꞏ 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. ꞏ 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available.
SECTION 5: Firefighting measures
(Cont'd. on page 3)
46.1.7
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Revision: 20 March 2021
Trade name: FRAM POWER STEERING FLUID
ꞏ 5.1 Extinguishing media ꞏ Suitable extinguishing agents: Water haze or fog Foam Fire-extinguishing powder Carbon dioxide ꞏ For safety reasons unsuitable extinguishing agents: Water with full jet ꞏ 5.2 Special hazards arising from the substance or mixture In case of fire, the following can be released: Carbon monoxide (CO) Under certain fire conditions, traces of other toxic gases cannot be excluded. ꞏ 5.3 Advice for firefighters ꞏ Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit.
(Cont'd. from page 2)
SECTION 6: Accidental release measures
ꞏ 6.1 Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation Wear protective equipment. Keep unprotected persons away. ꞏ 6.2 Environmental precautions Do not allow to enter sewers/ surface or ground water. Prevent from spreading (e.g. by damming-in or oil barriers). ꞏ 6.3 Methods and material for containment and cleaning up Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Send for recovery or disposal in suitable receptacles. Do not flush with water or aqueous cleansing agents Dispose of the material collected according to regulations. ꞏ 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.
SECTION 7: Handling and storage
ꞏ 7.1 Precautions for safe handling Avoid the formation of oil haze. Open and handle receptacle with care. ꞏ Information about fire - and explosion protection: No special measures required.
ꞏ 7.2 Conditions for safe storage, including any incompatibilities
ꞏ Requirements to be met by storerooms and receptacles: Store in cool, dry conditions in well sealed receptacles. ꞏ Information about storage in one common storage facility: Store away from foodstuffs. Store away from oxidising agents.
(Cont'd. on page 4)
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Revision: 20 March 2021
46.1.7
Page: 5 Safety Data Sheet
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Revision: 20 March 2021
Trade name: FRAM POWER STEERING FLUID
Store away from water. ꞏ 7.3 Specific end use(s) No further relevant information available.
(Cont'd. from page 3)
SECTION 8: Exposure controls/personal protection
ꞏ 8.1 Control parameters
ꞏ Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
ꞏ 8.2 Exposure controls
ꞏ General protective and hygienic measures: The usual precautionary measures are to be adhered to when handling chemicals. Keep away from foodstuffs, beverages and feed. Avoid contact with the eyes. ꞏ Respiratory protection: Not required under normal conditions of use. Use suitable respiratory protective device when aerosol or mist is formed. ꞏ Protection of hands:
Protective gloves
Oil resistant gloves ꞏ Eye protection:
Safety glasses
Goggles recommended during refilling ꞏ Body protection: Not required under normal conditions of use. ꞏ Limitation and supervision of exposure into the environment: No special requirements. ꞏ Risk management measures: No special requirements.
SECTION 9: Physical and chemical properties
ꞏ 9.1 Information on basic physical and chemical properties
ꞏ Appearance Form: Oily Colour: Clear ꞏ Odour: Mild ꞏ Odour threshold: Not determined.
ꞏ pH-value: Not determined. ꞏ Melting point/freezing point: Not determined. ꞏ Initial boiling point and boiling range: >350 °C (>662 °F)
ꞏ Flash point: >200 °C (>392 °F)
(Cont'd. on page 5)
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Revision: 20 March 2021
46.1.7
Page: 7 Safety Data Sheet
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Revision: 20 March 2021
Trade name: FRAM POWER STEERING FLUID
(Cont'd. from page 4)
ꞏ Flammability (solid, gas): Not applicable.
ꞏ Auto/Self-ignition temperature: Not determined.
ꞏ Decomposition temperature: Not determined.
ꞏ Explosive properties: Product does not present an explosion hazard.
ꞏ Explosion limits Lower: Not determined. Upper: Not determined. ꞏ Oxidising properties Not determined.
ꞏ Vapour pressure: Not determined.
ꞏ Density at 20 °C (68 °F): 0,90 ± 0,05 g/cm³ (7,51 lbs/gal) ꞏ Relative density: Not determined. ꞏ Vapour density: Not determined. ꞏ Evaporation rate: Not determined.
ꞏ Solubility in / Miscibility with water: Not miscible or difficult to mix.
ꞏ Partition coefficient: n-octanol/water: Not determined.
ꞏ Viscosity Dynamic at 40 °C (104 °F): 37 cSt Kinematic: Not determined. ꞏ 9.2 Other information No further relevant information available.
SECTION 10: Stability and reactivity
ꞏ 10.1 Reactivity No further relevant information available. ꞏ 10.2 Chemical stability Stable under normal temperatures and pressures. ꞏ Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications. ꞏ 10.3 Possibility of hazardous reactions Reacts with strong oxidising agents. ꞏ 10.4 Conditions to avoid Store away from oxidising agents. ꞏ 10.5 Incompatible materials No further relevant information available. ꞏ 10.6 Hazardous decomposition products Carbon monoxide and carbon dioxide Hydrocarbons Possible in traces: Nitrogen oxides (NOx) Sulphur oxides (SOx)
SECTION 11: Toxicological information
ꞏ 11.1 Information on toxicological effects
(Cont'd. on page 6)
46.1.7
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Revision: 20 March 2021
Trade name: FRAM POWER STEERING FLUID
ꞏ Acute toxicity: Based on available data, the classification criteria are not met. ꞏ LD/LC50 values relevant for classification: None. ꞏ Primary irritant effect ꞏ Skin corrosion/irritation: Based on available data, the classification criteria are not met.
(Cont'd. from page 5)
ꞏ Serious eye damage/irritation: Based on available data, the classification criteria are not met. ꞏ Respiratory or skin sensitisation: Based on available data, the classification criteria are not met.
ꞏ IARC (Inte national Agency fo Resea ch on Cance ):
71-43-2 benzene 1
ꞏ Probable routes of exposure: Ingestion. Inhalation. Eye contact. Skin contact. ꞏ Germ cell mutagenicity: Based on available data, the classification criteria are not met. ꞏ Carcinogenicity: Based on available data, the classification criteria are not met. ꞏ Reproductive toxicity: Based on available data, the classification criteria are not met. ꞏ STOT-single exposure: Based on available data, the classification criteria are not met. ꞏ STOT-repeated exposure: Based on available data, the classification criteria are not met. ꞏ Aspiration hazard: Based on available data, the classification criteria are not met.
SECTION 12: Ecological information
ꞏ 12.1 Toxicity ꞏ Aquatic toxicity: No further relevant information available. ꞏ 12.2 Persistence and degradability Not easily biodegradable. ꞏ 12.3 Bioaccumulative potential May be accumulated in organism ꞏ 12.4 Mobility in soil No further relevant information available. ꞏ Additional ecological information: ꞏ General notes: Avoid release to the environment. ꞏ 12.5 Results of PBT and vPvB assessment ꞏ PBT: Not applicable. ꞏ vPvB: Not applicable. ꞏ 12.6 Other adverse effects No further relevant information available.
SECTION 13: Disposal considerations
ꞏ 13.1 Waste treatment methods ꞏ Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. Can be reused after reprocessing. Delivery of waste oil to officially authorized collectors only. The user of this material has the responsibility to dispose of unused material, residues and containers in compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and disposal for hazardous and nonhazardous wastes.
ꞏ Uncleaned packaging:
(Cont'd. on page 7)
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Revision: 20 March 2021
46.1.7
Page: 10 Safety Data Sheet
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Revision: 20 March 2021
Trade name: FRAM POWER STEERING FLUID
ꞏ Recommendation: Disposal must be made according to official regulations. (Cont'd. from page 6)
SECTION 14: Transport information
ꞏ 14.1 UN-Number ꞏ DOT, ADR, IMDG, IATA Not Regulated
ꞏ 14.2 UN proper shipping name ꞏ DOT, ADR, IMDG, IATA Not Regulated
ꞏ 14.3 Transport hazard class(es)
ꞏ DOT, ADR, IMDG, IATA ꞏ Class Not Regulated
ꞏ 14.4 Packing group ꞏ DOT, ADR, IMDG, IATA Not Regulated
ꞏ 14.5 Environmental hazards: ꞏ Marine pollutant: No
ꞏ 14.6 Special precautions for user Not applicable.
ꞏ 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable.
SECTION 15: Regulatory information
ꞏ 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture ꞏ United States (USA) ꞏ SARA
ꞏ Section 355 (ext emely haza dous substances):
Substance is not listed.
ꞏ Section 313 (Specific toxic chemical listings):
Substance is not listed.
ꞏ TSCA (Toxic Substances Control Act):
Substance is listed.
ꞏ Proposition 65 (California):
W ARNING: This product can expose you to chemicals including benzene, which is known to the State of California to cause cancer and birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov.
ꞏ EPA (Environmental Protection Agency)
Substance is not listed.
(Cont'd. on page 8)
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Revision: 20 March 2021
46.1.7
Page: 12 Safety Data Sheet
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Revision: 20 March 2021
Trade name: FRAM POWER STEERING FLUID
(Cont'd. from page 7)
ꞏ IARC (Inte national Agency fo Resea ch on Cance )
71-43-2 benzene 1
ꞏ NIOSH-Ca (National Institute for Occupational Safety and Health)
71-43-2 benzene
ꞏ Canadian Domestic Substances List (DSL)
Substance is listed.
ꞏ Directive 2012/18/EU ꞏ Named dangerous substances - ANNEX I Substance is not listed.
ꞏ Other regulations, limitations and prohibitive regulations
ꞏ Substances of very high concern (SVHC) according to REACH, Article 57
Substance is not listed.
ꞏ 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.
ꞏ Abbreviations and acronyms: ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistant, Bio-accumulable, Toxic SVHC: Substances of Very High Concern vPvB: very Persistent and very Bioaccumulative ꞏ Sources Website, European Chemicals Agency (echa.europa.eu) W ebsite, US EPA Substance Registry Services (ofmpub.epa.gov/sor internet/registry/substreg/home/ overview/home.do) Website, Chemical Abstracts Registry, American Chemical Society (www.cas.org) Patty's Industrial Hygiene, 6th ed., Rose, Vernon, ed. ISBN: 978-0-470-07488-6 Casarett and Doull's Toxicology: The Basic Science of Poisons, 8th Ed., Klaasen, Curtis D., ed., ISBN: 978-0-07-176923-5. Safety Data Sheets, Individual Manufacturers The manufacturer believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. No warranty of fitness, warranty of merchantability or any other warranty, expressed or implied, is made concerning the information provided herein. The information provided herein relates only to the specific product designated and may not be valid where such product is used in combination with any other materials or process. Further, since the conditions and methods of use of this product and of the information referred to herein are beyond the control of the manufacturer, the manufacturer expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information. (Cont'd. on page 9)
46.1.7
Page: 13 Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS
Revision: 20 March 2021
Trade name: FRAM POWER STEERING FLUID
SDS Prepared by: ChemTel Inc. 1305 North Florida Avenue Tampa, Florida USA 33602-2902 Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573 Website: www.chemtelinc.com
(Cont'd. from page 8)
Page: 14 Safety Data Sheet
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Revision: 20 March 2021
46.1.7
Gorilla Spray Adhesive SDS Page 1 of 19
Safety Data Sheet – Gorilla Spray Adhesive
Date Revised: 11/01/2019
Date Issued: 02/28/2017
Version 1.1
FOR CHEMICAL EMERGENCY
DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations.
SECTION 1: IDENTIFICATION
Product Identifier
Product Form: Mixture
Product Name: Gorilla Spray Adhesive
Intended Use of the Product Adhesive.
Name, Address, and Telephone of the Responsible Party
Company
The Gorilla Glue Company
2101 E. Kemper Road
Cincinnati, Ohio 45241
513-271-3300
www.gorillatough.com
Emergency Telephone Number
Emergency Number : 1-800-420-7186 (Prosar)
SECTION 2: HAZARDS IDENTIFICATION
Classification of the Substance or Mixture
GHS-US Classification
Simple Asphy
Flam. Aerosol 1 H222
Liquefied gas H280
Skin Irrit. 2 H315
Eye Irrit. 2A H319
STOT SE 3 H336
Full text of hazard classes and H-statements : see section 16
Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US) :
GHS02 GHS04 GHS07 GHS08
Signal Word (GHS-US) : Danger
Hazard Statements (GHS-US) : May displace oxygen and cause rapid suffocation.
H222 - Extremely flammable aerosol.
H280 - Contains gas under pressure; may explode if heated.
H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H336 - May cause drowsiness or dizziness.
Precautionary Statements (GHS-US) : P210 - Keep away from extremely high or low temperatures, ignition sources, and
incompatible materials. - No smoking.
P211 - Do not spray on an open flame or other ignition source.
P251 - Pressurized container: Do not pierce or burn, even after use.
P261 - Avoid breathing vapors, mist, or spray.
P264 - Wash hands, forearms, and other exposed areas thoroughly after handling.
P271 - Use only outdoors or in a well-ventilated area.
P273 - Avoid release to the environment.
P280 - Wear protective gloves, protective clothing, and eye protection.
Gorilla Spray Adhesive SDS Page 2 of 19
Safety Data Sheet – Gorilla Spray Adhesive
Date Revised: 11/01/2019
Date Issued: 02/28/2017
Version 1.1
FOR CHEMICAL EMERGENCY
DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations.
P302+P352 - If on skin: Wash with plenty of water.
P304+P340 - If inhaled: Remove person to fresh air and keep at rest in a position
comfortable for breathing.
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P312 - Call a poison center or doctor if you feel unwell.
P321 - Specific treatment (see section 4 on this SDS).
P332+P313 - If skin irritation occurs: Get medical advice/attention.
P337+P313 - If eye irritation persists: Get medical advice/attention.
P362+P364 - Take off contaminated clothing and wash it before reuse.
P391 - Collect spillage.
P403+P233 - Store in a well-ventilated place. Keep container tightly closed.
P405 - Store locked up.
P410+P403 - Protect from sunlight. Store in a well-ventilated place.
P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F.
P501 - Dispose of contents/container in accordance with local, regional, national,
and international regulations.
Other Hazards
Exposure may aggravate pre-existing eye, skin, or respiratory conditions. Contact with gas escaping the container can cause frostbite.
Unknown Acute Toxicity (GHS-US)
No data available
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Not applicable
Mixture
Name Product Identifier % GHS-US classification
Methyl acetate (CAS No) 79-20-9 15-40 Flam. Liq. 2, H225
Eye Irrit. 2A, H319
STOT SE 3, H336
Cyclohexane (CAS No) 110-82-7 5-15 Flam. Liq. 2, H225
Skin Irrit. 2, H315
STOT SE 3, H336
Asp. Tox. 1, H304
Acetone (CAS No) 67-64-1 5-15 Flam. Liq. 2, H225
Eye Irrit. 2A, H319
STOT SE 3, H336
1,1-Difluoroethane (CAS No) 75-37-6 5-15 Simple Asphy
Flam. Gas 1, H220
Liquefied gas, H280
Dimethyl ether (CAS No) 115-10-6 5-15 Simple Asphy
Flam. Gas 1, H220
Liquefied gas, H280
Petroleum hydrocarbon resin (CAS No) Proprietary 5-15 Eye Irrit. 2B, H320
Gorilla Spray Adhesive SDS Page 3 of 19
Safety Data Sheet – Gorilla Spray Adhesive
Date Revised: 11/01/2019
Date Issued: 02/28/2017
Version 1.1
FOR CHEMICAL EMERGENCY
DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations.
Propane (CAS No) 74-98-6 1-5 Simple Asphy
Flam. Gas 1, H220
Liquefied gas, H280
Butane (CAS No) 106-97-8 1-5 Simple Asphy
Flam. Gas 1, H220
Liquefied gas, H280
Acetaldehyde (CAS No) 75-07-0 <0.1 Flam. Liq. 1, H224
Acute Tox. 4 (Oral), H302
Eye Irrit. 2A, H319
Carc. 2, H351
STOT SE 3, H335
Methyl alcohol (CAS No) 67-56-1 <0.1 Flam. Liq. 2, H225
Acute Tox. 3 (Oral), H301
Acute Tox. 3 (Dermal), H311
Acute Tox. 3 (Inhalation:vapor), H331
STOT SE 1, H370
Acetic acid (CAS No) 64-19-7 <0.1 Flam. Liq. 3, H226
Skin Corr. 1A, H314
Eye Dam. 1, H318
Benzene (CAS No) 71-43-2 <0.001 Flam. Liq. 2, H225
Acute Tox. 4 (Oral), H302
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Muta. 1B, H340
Carc. 1A, H350
STOT RE 1, H372
Asp. Tox. 1, H304
Naphthalene (CAS No) 91-20-3 < 0.001 Flam. Sol. 2, H228
Acute Tox. 4 (Oral), H302
Acute Tox. 4 (Dermal), H312
Carc. 2, H351
Full text of H-phrases: see section 16
SECTION 4: FIRST AID MEASURES
Description of First-aid Measures
First-aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible). If frostbite or freezing occurs, immediately flush with plenty of lukewarm water to GENTLY
warm the affected area. Do not use hot water. Do not rub affected area. Get immediate medical attention.
First-aid Measures After Inhalation: First, take proper precautions to ensure your own safety before attempting rescue (e.g.
wear appropriate respiratory protective equipment, use the buddy system), then remove the exposed person to fresh air. Keep
at rest in a position comfortable for breathing. Obtain medical attention if breathing difficulty persists.
First-aid Measures After Skin Contact: Remove contaminated clothing. Drench affected area with water for at least 15 minutes.
Obtain medical attention if irritation develops or persists. Thaw frosted parts with lukewarm water. Do not rub affected area. Get
immediate medical advice/attention.
First-aid Measures After Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. Obtain medical attention. If frostbite or freezing occurs, immediately flush with plenty of lukewarm
water to GENTLY warm the affected area. Do not use hot water. Do not rub affected area. Get immediate medical attention.
Gorilla Spray Adhesive SDS Page 4 of 19
Safety Data Sheet – Gorilla Spray Adhesive
Date Revised: 11/01/2019
Date Issued: 02/28/2017
Version 1.1
FOR CHEMICAL EMERGENCY
DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations.
First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Obtain medical attention.
Most Important Symptoms and Effects Both Acute and Delayed
Symptoms/Injuries: May cause frostbite on contact with the liquid. Causes serious eye irritation. Causes skin irritation. May
cause drowsiness and dizziness. Asphyxia by lack of oxygen: risk of death.
Symptoms/Injuries After Inhalation: High concentrations may cause central nervous system depression such as dizziness,
vomiting, numbness, drowsiness, headache, and similar narcotic symptoms. In elevated concentrations may cause asphyxiation,
central nervous system effects, and increased breathing rate. Symptoms of asphyxiation include headache, dizziness, rapid
breathing, increased pulse, mood changes, tremors, cyanosis, muscular weakness, narcosis, numbness of the extremities,
unconsciousness and death.
Symptoms/Injuries After Skin Contact: Redness, pain, swelling, itching, burning, dryness, and dermatitis. Contact with gas/liquid
escaping the container can cause frostbite and freeze burns.
Symptoms/Injuries After Eye Contact: Contact causes severe irritation with redness and swelling of the conjunctiva. Contact
with gas/liquid escaping the container can cause frostbite, freeze burns, and permanent eye damage.
Symptoms/Injuries After Ingestion: Not considered a potential route of exposure, but contact with gas/liquid escaping the
container can cause freeze burns and frostbite.
Chronic Symptoms: None known.
Indication of Any Immediate Medical Attention and Special Treatment Needed
If exposed or concerned, get medical advice and attention. If medical advice is needed, have product container or label at hand.
SECTION 5: FIRE-FIGHTING MEASURES
Extinguishing Media
Special Hazards Arising From the Substance or Mixture
Advice for Firefighters
Precautionary Measures Fire: Exercise caution when fighting any chemical fire.
Firefighting Instructions: Remove containers from fire area if this can be done without risk. Use water spray or fog for cooling
exposed containers. Do not get water inside containers. Do not apply water stream directly at source of leak. DO NOT fight fire when
fire reaches containers. Evacuate area. Fight fire remotely due to the risk of explosion.
Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection.
Hazardous Combustion Products: Thermal decomposition generates: Carbon oxides (CO, CO2). Nitrogen oxides. Aliphatic fragments.
Hydrocarbons. Fluorinated hydrocarbons. Methanol. Formaldehyde. hydrofluoric acid. Phosgene. Fluorine compounds. Aldehydes.
Ketones. Irritating fumes.
Other Information: Do not allow run-off from fire fighting to enter drains or water courses.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Keep away from heat, hot surfaces, sparks, open flames, and other ignition sources. No smoking. Do not get in
eyes, on skin, or on clothing. Do not breathe vapors, gas.
For Non-Emergency Personnel
Protective Equipment: Use appropriate personal protective equipment (PPE).
Emergency Procedures: Evacuate unnecessary personnel. Stop leak if safe to do so.
For Emergency Personnel
Protective Equipment: Equip cleanup crew with proper protection.
Suitable Extinguishing Media: Use fire extinguisher with class B rating. Carbon dioxide, dry chemical. Sand.
Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire.
Fire Hazard: Flammable aerosol.
Explosion Hazard: Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries.
Container may explode in heat of fire.
Reactivity: Reacts violently with strong oxidizers. Increased risk of fire or explosion. Hazardous reactions may occur on contact with
certain chemicals. Refer to incompatible materials.
Gorilla Spray Adhesive SDS Page 5 of 19
Safety Data Sheet – Gorilla Spray Adhesive
Date Revised: 11/01/2019
Date Issued: 02/28/2017
Version 1.1
FOR CHEMICAL EMERGENCY
DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations.
Emergency Procedures: Ventilate area. Eliminate ignition sources. Evacuate unnecessary personnel, isolate, and ventilate area.
Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods, protect oneself and the
public, secure the area, and call for the assistance of trained personnel as soon as conditions permit.
Environmental Precautions
Prevent entry to sewers and public waters. Avoid release to the environment. Collect spillage.
Methods and Materials for Containment and Cleaning Up
For Containment: Stop leak, if possible without risk. As an immediate precautionary measure, isolate spill or leak area in all
directions.
Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Eliminate all ignition sources. Stop the source of
the release, if safe to do so. Consider the use of water spray to disperse vapors. Isolate the area until gas has dispersed. Ventilate
and gas test area before entering. Absorb and/or contain spill with inert material. Use only non-sparking tools. Transfer spilled
material to a suitable container for disposal. Contact competent authorities after a spill.
Reference to Other Sections
See Section 8 for exposure controls and personal protection and Section 13 for disposal considerations.
SECTION 7: HANDLING AND STORAGE
Precautions for Safe Handling
Additional Hazards When Processed: Pressurized container: may burst if heated. Do not pierce or burn, even after use. Do not
pressurize, cut, or weld containers. Ruptured cylinders may rocket. Asphyxiating gas at high concentrations. Contact with the
liquefied gas may cause frostbite.
Precautions for Safe Handling: Do not handle until all safety precautions have been read and understood. Wash hands and other
exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Do not spray on an open flame
or other ignition source. Avoid contact with eyes, skin and clothing. Do not breathe gas. Use appropriate personal protective
equipment (PPE).
Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures.
Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures: Comply with applicable regulations. Proper grounding procedures to avoid static electricity should be followed.
Storage Conditions: Store in a dry, cool and well-ventilated place. Keep only in the original container in a cool, well ventilated place
away from ignition sources. Keep/Store away from direct sunlight, extremely high or low temperatures and incompatible materials.
Protect from sunlight. Do not expose to temperatures exceeding 50°C/ 122°F. Keep in fireproof place.
Incompatible Materials: Strong acids, strong bases, strong oxidizers. Concentrated Oxygen. Acid anhydrides. Powdered metals.
Alkalis. Alkali earth metals. Nitric acid. Sulfuric acid. Potassium permanganate. Halogenated compounds. Attacks some forms of
plastics, rubber, and coatings.
Specific End Use(s) No use is specified.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Control Parameters
For substances listed in section 3 that are not listed here, there are no established exposure limits from the manufacturer, supplier,
importer, or the appropriate advisory agency including: ACGIH (TLV), AIHA (WEEL), NIOSH (REL), or OSHA (PEL).
Dimethyl ether (115-10-6)
USA AIHA WEEL TWA (ppm) 1000 ppm
1,1-Difluoroethane (75-37-6)
USA AIHA WEEL TWA (ppm) 1000 ppm
Propane (74-98-6)
USA NIOSH NIOSH REL (TWA) (mg/m³) 1800 mg/m³
USA NIOSH NIOSH REL (TWA) (ppm) 1000 ppm
USA IDLH US IDLH (ppm) 2100 ppm (10% LEL)
Gorilla Spray Adhesive SDS Page 6 of 19
Safety Data Sheet – Gorilla Spray Adhesive
Date Revised: 11/01/2019
Date Issued: 02/28/2017
Version 1.1
FOR CHEMICAL EMERGENCY
DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations.
USA OSHA OSHA PEL (TWA) (mg/m³) 1800 mg/m³
USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm
Butane (106-97-8)
USA ACGIH ACGIH STEL (ppm) 1000 ppm
USA NIOSH NIOSH REL (TWA) (mg/m³) 1900 mg/m³
USA NIOSH NIOSH REL (TWA) (ppm) 800 ppm
Cyclohexane (110-82-7)
USA ACGIH ACGIH TWA (ppm) 100 ppm
USA NIOSH NIOSH REL (TWA) (mg/m³) 1050 mg/m³
USA NIOSH NIOSH REL (TWA) (ppm) 300 ppm
USA IDLH US IDLH (ppm) 1300 ppm (10% LEL)
USA OSHA OSHA PEL (TWA) (mg/m³) 1050 mg/m³
USA OSHA OSHA PEL (TWA) (ppm) 300 ppm
Benzene (71-43-2)
USA ACGIH ACGIH TWA (ppm) 0.5 ppm
USA ACGIH ACGIH STEL (ppm) 2.5 ppm
USA ACGIH ACGIH chemical category Skin - potential significant contribution to overall exposure by the
cutaneous route,Confirmed Human Carcinogen
USA ACGIH Biological Exposure Indices (BEI) 25 µg/g Kreatinin Parameter: S-Phenylmercapturic acid - Medium:
urine - Sampling time: end of shift (background)
500 µg/g Kreatinin Parameter: t,t-Muconic acid - Medium: urine -
Sampling time: end of shift (background)
USA NIOSH NIOSH REL (TWA) (ppm) 0.1 ppm
USA NIOSH NIOSH REL (STEL) (ppm) 1 ppm
USA IDLH US IDLH (ppm) 500 ppm
USA OSHA OSHA PEL (TWA) (ppm) 10 ppm
1 ppm
USA OSHA OSHA PEL (STEL) (ppm) 5 ppm (see 29 CFR 1910.1028)
USA OSHA OSHA PEL (Ceiling) (ppm) 25 ppm
Methyl acetate (79-20-9)
USA ACGIH ACGIH TWA (ppm) 200 ppm
USA ACGIH ACGIH STEL (ppm) 250 ppm
USA NIOSH NIOSH REL (TWA) (mg/m³) 610 mg/m³
USA NIOSH NIOSH REL (TWA) (ppm) 200 ppm
USA NIOSH NIOSH REL (STEL) (mg/m³) 760 mg/m³
USA NIOSH NIOSH REL (STEL) (ppm) 250 ppm
USA IDLH US IDLH (ppm) 3100 ppm (10% LEL)
USA OSHA OSHA PEL (TWA) (mg/m³) 610 mg/m³
USA OSHA OSHA PEL (TWA) (ppm) 200 ppm
Acetaldehyde (75-07-0)
USA ACGIH ACGIH Ceiling (ppm) 25 ppm
USA ACGIH ACGIH chemical category Suspected Human Carcinogen
USA IDLH US IDLH (ppm) 2000 ppm
USA OSHA OSHA PEL (TWA) (mg/m³) 360 mg/m³
USA OSHA OSHA PEL (TWA) (ppm) 200 ppm
Gorilla Spray Adhesive SDS Page 7 of 19
Safety Data Sheet – Gorilla Spray Adhesive
Date Revised: 11/01/2019
Date Issued: 02/28/2017
Version 1.1
FOR CHEMICAL EMERGENCY
DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations.
Methyl alcohol (67-56-1)
USA ACGIH ACGIH TWA (ppm) 200 ppm
USA ACGIH ACGIH STEL (ppm) 250 ppm
USA ACGIH ACGIH chemical category Skin - potential significant contribution to overall exposure by the
cutaneous route
USA ACGIH Biological Exposure Indices (BEI) 15 mg/l Parameter: Methanol - Medium: urine - Sampling time: end
of shift (background, nonspecific)
USA NIOSH NIOSH REL (TWA) (mg/m³) 260 mg/m³
USA NIOSH NIOSH REL (TWA) (ppm) 200 ppm
USA NIOSH NIOSH REL (STEL) (mg/m³) 325 mg/m³
USA NIOSH NIOSH REL (STEL) (ppm) 250 ppm
USA IDLH US IDLH (ppm) 6000 ppm
USA OSHA OSHA PEL (TWA) (mg/m³) 260 mg/m³
USA OSHA OSHA PEL (TWA) (ppm) 200 ppm
Acetic acid (64-19-7)
USA ACGIH ACGIH TWA (ppm) 10 ppm
USA ACGIH ACGIH STEL (ppm) 15 ppm
USA NIOSH NIOSH REL (TWA) (mg/m³) 25 mg/m³
USA NIOSH NIOSH REL (TWA) (ppm) 10 ppm
USA NIOSH NIOSH REL (STEL) (mg/m³) 37 mg/m³
USA NIOSH NIOSH REL (STEL) (ppm) 15 ppm
USA IDLH US IDLH (ppm) 50 ppm
USA OSHA OSHA PEL (TWA) (mg/m³) 25 mg/m³
USA OSHA OSHA PEL (TWA) (ppm) 10 ppm
Acetone (67-64-1)
USA ACGIH ACGIH TWA (ppm) 250 ppm
USA ACGIH ACGIH STEL (ppm) 500 ppm
USA ACGIH ACGIH chemical category Not Classifiable as a Human Carcinogen
USA ACGIH Biological Exposure Indices (BEI) 25 mg/l Parameter: Acetone - Medium: urine - Sampling time: end
of shift (nonspecific)
USA NIOSH NIOSH REL (TWA) (mg/m³) 590 mg/m³
USA NIOSH NIOSH REL (TWA) (ppm) 250 ppm
USA IDLH US IDLH (ppm) 2500 ppm (10% LEL)
USA OSHA OSHA PEL (TWA) (mg/m³) 2400 mg/m³
USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm
Naphthalene (91-20-3)
USA ACGIH ACGIH TWA (ppm) 10 ppm
USA ACGIH ACGIH chemical category Skin - potential significant contribution to overall exposure by the
cutaneous route, Confirmed Animal Carcinogen with Unknown
Relevance to Humans
USA ACGIH Biological Exposure Indices (BEI) Parameter: 1-Naphthol with hydrolysis plus 2-Naphthol with
hydrolysis - Sampling time: end of shift (nonquantitative,
nonspecific)
USA NIOSH NIOSH REL (TWA) (mg/m³) 50 mg/m³
USA NIOSH NIOSH REL (TWA) (ppm) 10 ppm
USA NIOSH NIOSH REL (STEL) (mg/m³) 75 mg/m³
Gorilla Spray Adhesive SDS Page 8 of 19
Safety Data Sheet – Gorilla Spray Adhesive
Date Revised: 11/01/2019
Date Issued: 02/28/2017
Version 1.1
FOR CHEMICAL EMERGENCY
DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations.
USA NIOSH NIOSH REL (STEL) (ppm) 15 ppm
USA IDLH US IDLH (ppm) 250 ppm
USA OSHA OSHA PEL (TWA) (mg/m³) 50 mg/m³
USA OSHA OSHA PEL (TWA) (ppm) 10 ppm
Particulates not otherwise classified (PNOC) (Not applicable)
USA ACGIH ACGIH TWA (mg/m³) 3 mg/m3 Respirable fraction
10 mg/m3 Total Dust
USA OSHA OSHA PEL (TWA) (mg/m³) 5 mg/m3 Respirable fraction
15 mg/m3 Total Dust
Exposure Controls
Appropriate Engineering Controls : Emergency eye wash fountains and safety showers should be available in the
immediate vicinity of any potential exposure. Ensure adequate ventilation,
especially in confined areas. Gas detectors should be used when flammable gases
or vapors may be released. Oxygen detectors should be used when asphyxiating
gases may be released. Proper grounding procedures to avoid static electricity
should be followed. Use explosion-proof equipment. Ensure all national/local
regulations are observed.
Personal Protective Equipment : Gloves. Protective clothing. Protective goggles. Insufficient ventilation: wear
respiratory protection. Respiratory protection of the dependent type.
Materials for Protective Clothing : Chemically resistant materials and fabrics. Wear fire/flame resistant/retardant
clothing.
Hand Protection : Wear protective gloves. If material is cold, wear thermally resistant protective
gloves.
Eye Protection : Chemical safety goggles.
Skin and Body Protection : Wear suitable protective clothing.
Respiratory Protection : Use a NIOSH-approved self-contained breathing apparatus whenever exposure may
exceed established Occupational Exposure Limits.
Thermal Hazard Protection : Wear thermally resistant protective clothing.
Environmental Exposure Controls : Avoid release to the environment.
Other Information : When using, do not eat, drink or smoke.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on Basic Physical and Chemical Properties
Physical State : Gas
Appearance : No data available
Odor : No data available
Odor Threshold : No data available
pH : No data available
Evaporation Rate : No data available
Melting Point : No data available
Freezing Point : No data available
Boiling Point : 57.6 °C (135.68 °F) estimated
Flash Point : -104.4 °C (-155.92 °F) Propellant - estimated
Gorilla Spray Adhesive SDS Page 9 of 19
Safety Data Sheet – Gorilla Spray Adhesive
Date Revised: 11/01/2019
Date Issued: 02/28/2017
Version 1.1
FOR CHEMICAL EMERGENCY
DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations.
Auto-ignition Temperature : No data available
Decomposition Temperature : No data available
Flammability (solid, gas) : No data available
Vapor Pressure : No data available
Relative Vapor Density at 20°C : No data available
Relative Density : No data available
Specific Gravity : 0.72
Solubility : No data available
Partition Coefficient: N-Octanol/Water : No data available
Viscosity : No data available
Explosive Properties : Contains gas under pressure; may explode if heated.
Lower Flammable Limit : 3 %
Upper Flammable Limit : 14.8 %
Other Information
Gas Group : Liquefied gas
Flame projection : 24 in. with Flash Back of 2 in.
Concentrate Viscosity : 75-225 cPs
SECTION 10: STABILITY AND REACTIVITY
Reactivity: Reacts violently with strong oxidizers. Increased risk of fire or explosion. Hazardous reactions may occur on contact with
certain chemicals. Refer to incompatible materials.
Chemical Stability: Flammable aerosol. Pressurized container: may burst if heated.
Possibility of Hazardous Reactions: Hazardous polymerization will not occur.
Conditions to Avoid: Direct sunlight, extremely high or low temperatures, heat, hot surfaces, sparks, open flames, incompatible
materials, and other ignition sources.
Incompatible Materials: Strong acids, strong bases, strong oxidizers. Concentrated Oxygen. Acid anhydrides. Powdered metals.
Alkalis. Alkaline earth metals. Nitric acid. Sulfuric acid. Potassium permanganate. Halogenated compounds. Attacks some forms of
plastics, rubber, and coatings.
Hazardous Decomposition Products: Under normal conditions of storage and use, hazardous decomposition products should not
be produced.
SECTION 11: TOXICOLOGICAL INFORMATION
Information on Toxicological Effects
Acute Toxicity: Not classified
Dimethyl ether (115-10-6)
LC50 Inhalation Rat 308 mg/l/4h
Propane (74-98-6)
LC50 Inhalation Rat 658 mg/l/4h
Butane (106-97-8)
LC50 Inhalation Rat 30957 mg/m³ (Exposure time: 4 h)
Cyclohexane (110-82-7)
LD50 Oral Rat 12705 mg/kg
LD50 Dermal Rabbit > 2000 mg/kg
LC50 Inhalation Rat 13.9 mg/l/4h
Benzene (71-43-2)
LD50 Oral Rat 810 mg/kg
Gorilla Spray Adhesive SDS Page 10 of 19
Safety Data Sheet – Gorilla Spray Adhesive
Date Revised: 11/01/2019
Date Issued: 02/28/2017
Version 1.1
FOR CHEMICAL EMERGENCY
DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations.
LD50 Dermal Rabbit > 8200 mg/kg
LC50 Inhalation Rat 44.66 mg/l/4h
Methyl acetate (79-20-9)
LD50 Oral Rat > 5 g/kg
LD50 Dermal Rabbit > 5 g/kg
LC50 Inhalation Rat 16000 ppm/4h
Acetaldehyde (75-07-0)
LD50 Oral Rat 660 mg/kg
LC50 Inhalation Rat 24 mg/l/4h
LC50 Inhalation Rat 13000 ppm/4h
Methyl alcohol (67-56-1)
LC50 Inhalation Rat 3 mg/l/4h
LC50 Inhalation Rat 22500 ppm (Exposure time: 8 h)
ATE (Oral) 100.00 mg/kg body weight
ATE (Dermal) 300.00 mg/kg body weight
Acetic acid (64-19-7)
LD50 Oral Rat 3310 mg/kg
Acetone (67-64-1)
LD50 Oral Rat 5800 mg/kg
LD50 Dermal Rabbit 15688 mg/kg
LC50 Inhalation Rat 44 g/m³
LC50 Inhalation Rat 75.8 mg/l/4h
Naphthalene (91-20-3)
LD50 Oral Rat 533 - 710 mg/kg
LD50 Dermal Rat 1120 mg/kg
LC50 Inhalation Rat > 340 mg/m³ (Exposure time: 1 h)
Skin Corrosion/Irritation: Causes skin irritation.
Serious Eye Damage/Irritation: Causes serious eye irritation.
Respiratory or Skin Sensitization: Not classified
Germ Cell Mutagenicity: Not classified
Carcinogenicity: Not classified
Benzene (71-43-2)
IARC group 1
National Toxicology Program (NTP) Status Evidence of Carcinogenicity, Known Human Carcinogens.
OSHA Hazard Communication Carcinogen List In OSHA Hazard Communication Carcinogen list.
OSHA Specifically Regulated Carcinogen List In OSHA Specifically Regulated Carcinogen list.
Acetaldehyde (75-07-0)
IARC group 1, 2B
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen.
OSHA Hazard Communication Carcinogen List In OSHA Hazard Communication Carcinogen list.
Naphthalene (91-20-3)
IARC group 2B
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen.
OSHA Hazard Communication Carcinogen List In OSHA Hazard Communication Carcinogen list.
Gorilla Spray Adhesive SDS Page 11 of 19
Safety Data Sheet – Gorilla Spray Adhesive
Date Revised: 11/01/2019
Date Issued: 02/28/2017
Version 1.1
FOR CHEMICAL EMERGENCY
DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations.
Reproductive Toxicity: Not classified
Specific Target Organ Toxicity (Single Exposure): May cause drowsiness or dizziness.
Specific Target Organ Toxicity (Repeated Exposure): Not classified
Aspiration Hazard: Not classified
Symptoms/Injuries After Inhalation: High concentrations may cause central nervous system depression such as dizziness,
vomiting, numbness, drowsiness, headache, and similar narcotic symptoms. In elevated concentrations may cause asphyxiation,
central nervous system effects, and increased breathing rate. Symptoms of asphyxiation include headache, dizziness, rapid
breathing, increased pulse, mood changes, tremors, cyanosis, muscular weakness, narcosis, numbness of the extremities,
unconsciousness and death.
Symptoms/Injuries After Skin Contact: Redness, pain, swelling, itching, burning, dryness, and dermatitis. Contact with gas/liquid
escaping the container can cause frostbite and freeze burns.
Symptoms/Injuries After Eye Contact: Contact causes severe irritation with redness and swelling of the conjunctiva. Contact
with gas/liquid escaping the container can cause frostbite, freeze burns, and permanent eye damage.
Symptoms/Injuries After Ingestion: Not considered a potential route of exposure, but contact with gas/liquid escaping the
container can cause freeze burns and frostbite.
Chronic Symptoms: None known.
SECTION 12: ECOLOGICAL INFORMATION
Toxicity
Ecology - General : Toxic to aquatic life. Toxic to aquatic life with long lasting effects.
1,1-Difluoroethane (75-37-6)
LC50 Fish 1 733 mg/l
EC50 Daphnia 1 720 mg/l
ErC50 (Algae) 419 mg/l
Cyclohexane (110-82-7)
LC50 Fish 1 3.96 - 5.18 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through])
EC50 Daphnia 1 0.9 mg/l
LC50 Fish 2 23.03 - 42.07 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])
Benzene (71-43-2)
LC50 Fish 1 10.7 - 14.7 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through])
EC50 Daphnia 1 8.76 - 15.6 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static])
LC50 Fish 2 5.3 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through])
EC50 Daphnia 2 10 mg/l (Exposure time: 48 h - Species: Daphnia magna)
Methyl acetate (79-20-9)
LC50 Fish 1 295 - 348 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through])
EC50 Daphnia 1 1026.7 mg/l (Exposure time: 48 h - Species: Daphnia magna)
LC50 Fish 2 250 - 350 mg/l (Exposure time: 96 h - Species: Brachydanio rerio [static])
Acetaldehyde (75-07-0)
LC50 Fish 1 28 (28.0 - 34.0) mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-
through])
EC50 Daphnia 1 3.64 (3.64 - 6.15) mg/l (Exposure time: 48 h - Species: Daphnia magna [Static])
LC50 Fish 2 53 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static])
EC50 Daphnia 2 48.3 mg/l (Exposure time: 48 h - Species: Daphnia magna)
Methyl alcohol (67-56-1)
LC50 Fish 1 28200 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through])
EC50 Daphnia 1 1340 mg/l
Gorilla Spray Adhesive SDS Page 12 of 19
Safety Data Sheet – Gorilla Spray Adhesive
Date Revised: 11/01/2019
Date Issued: 02/28/2017
Version 1.1
FOR CHEMICAL EMERGENCY
DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations.
LC50 Fish 2 > 100 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])
Acetic acid (64-19-7)
LC50 Fish 1 79 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])
EC50 Daphnia 1 65 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static])
LC50 Fish 2 75 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static])
Acetone (67-64-1)
LC50 Fish 1 4144.846 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss)
EC50 Daphnia 1 1679.66 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static])
LC50 Fish 2 6210 (6210 - 8120) mg/l (Exposure time: 96 h - Species: Pimephales promelas
[static])
EC50 Daphnia 2 12600 (12600 - 12700) mg/l (Exposure time: 48 h - Species: Daphnia magna)
Naphthalene (91-20-3)
LC50 Fish 1 5.74 - 6.44 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through])
EC50 Daphnia 1 2.16 mg/l (Exposure time: 48 h - Species: Daphnia magna)
LC50 Fish 2 1.6 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through])
EC50 Daphnia 2 1.96 mg/l (Exposure time: 48 h - Species: Daphnia magna [Flow through])
Persistence and Degradability
Gorilla Spray Adhesive
Persistence and Degradability May cause long-term adverse effects in the environment.
Acetone (67-64-1)
Persistence and Degradability Readily biodegradable in water.
Bioaccumulative Potential
Gorilla Spray Adhesive
Bioaccumulative Potential Not established.
Dimethyl ether (115-10-6)
Log Pow -0.18
Propane (74-98-6)
Log Pow 2.3
Butane (106-97-8)
Log Pow 2.89
Cyclohexane (110-82-7)
Log Pow 3.44
Benzene (71-43-2)
BCF Fish 1 3.5 - 4.4
Log Pow 2.1
Methyl acetate (79-20-9)
Log Pow 0.18
Acetaldehyde (75-07-0)
Log Pow 0.5
Methyl alcohol (67-56-1)
BCF Fish 1 < 10
Log Pow -0.77
Acetic acid (64-19-7)
Log Pow -0.31 (at 20 °C)
Gorilla Spray Adhesive SDS Page 13 of 19
Safety Data Sheet – Gorilla Spray Adhesive
Date Revised: 11/01/2019
Date Issued: 02/28/2017
Version 1.1
FOR CHEMICAL EMERGENCY
DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations.
Acetone (67-64-1)
BCF Fish 1 0.69
Log Pow -0.24
Log Kow -0.24
Naphthalene (91-20-3)
BCF Fish 1 30 - 430
Log Pow 3.6
Mobility in Soil No additional information available
Other Adverse Effects
Other Information : Avoid release to the environment.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste Treatment Methods
Waste Disposal Recommendations: Dispose of contents/container in accordance with local, regional, national, and international
regulations. Do not pierce or burn, even after use.
Additional Information: Container may remain hazardous when empty. Continue to observe all precautions. Do not puncture or
incinerate container.
Ecology - Waste Materials: Avoid release to the environment. This material is hazardous to the aquatic environment. Keep out
of sewers and waterways.
SECTION 14: TRANSPORT INFORMATION
The shipping description(s) stated herein were prepared in accordance with certain assumptions at the time the SDS was authored,
and can vary based on a number of variables that may or may not have been known at the time the SDS was issued.
In Accordance with DOT
Proper Shipping Name : AEROSOLS flammable, (each not exceeding 1 L capacity)
Hazard Class : 2.1
Identification Number : UN1950
Label Codes : 2.1
Marine Pollutant : Marine pollutant
ERG Number
Other Information
:
:
126
A marine pollutant designation is not required when shipped in a single package or
combination packaging containing inner packaging with contents of 5L or less. Otherwise, the
above descriptions apply.
In Accordance with IMDG
Proper Shipping Name : AEROSOLS flammable, (each not exceeding 1 L capacity)
Hazard Class : 2
Division : 2.1
Identification Number : UN1950
Label Codes : 2.1
EmS-No. (Fire) : F-D
EmS-No. (Spillage) : S-U
Marine Pollutant
Additional Information
:
:
Marine pollutant
This product, when in compliance with IMDG Code 37-14, section 2.10.2.7, is not subject to
any other provisions of the IMDG code relevant to marine pollutants. For inclusion in another
hazard class all provisions of the IMDG code relevant to any additional hazards continue to
apply.
Gorilla Spray Adhesive SDS Page 14 of 19
Safety Data Sheet – Gorilla Spray Adhesive
Date Revised: 11/01/2019
Date Issued: 02/28/2017
Version 1.1
FOR CHEMICAL EMERGENCY
DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations.
In Accordance with IATA
Proper Shipping Name : AEROSOLS, flammable, (each not exceeding 1 L capacity)
Identification Number : UN1950
Hazard Class : 2
Label Codes : 2.1
Division : 2.1
ERG Code (IATA) : 10L
SECTION 15: REGULATORY INFORMATION
US Federal Regulations
Gorilla Spray Adhesive
SARA Section 311/312 Hazard Classes Fire hazard
Sudden release of pressure hazard
Immediate (acute) health hazard
Dimethyl ether (115-10-6)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
1,1-Difluoroethane (75-37-6)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Propane (74-98-6)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Butane (106-97-8)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Cyclohexane (110-82-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
CERCLA RQ 1000 lb
SARA Section 313 - Emission Reporting 1.0 %
Benzene (71-43-2)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
CERCLA RQ 10 lb
SARA Section 313 - Emission Reporting 0.1 %
Methyl acetate (79-20-9)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Acetaldehyde (75-07-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule
under TSCA
CERCLA RQ 1000 lb
SARA Section 313 - Emission Reporting 0.1 %
Methyl alcohol (67-56-1)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
CERCLA RQ 5000 lb
Gorilla Spray Adhesive SDS Page 15 of 19
Safety Data Sheet – Gorilla Spray Adhesive
Date Revised: 11/01/2019
Date Issued: 02/28/2017
Version 1.1
FOR CHEMICAL EMERGENCY
DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations.
SARA Section 313 - Emission Reporting 1.0 %
Acetic acid (64-19-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
CERCLA RQ 5000 lb
Acetone (67-64-1)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
CERCLA RQ 5000 lb
Benzene, ethenyl-, polymer with 1-methyl-4-(1-methylethenyl)cyclohexene (64536-06-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
EPA TSCA Regulatory Flag XU - XU - indicates a substance exempt from reporting under the
Inventory Update Reporting Rule, i.e, Partial Updating of the TSCA
Inventory Data Base Production and Site Reports (40 CFR 710(C))
Naphthalene (91-20-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
CERCLA RQ 100 lb
SARA Section 313 - Emission Reporting 0.1 %
Benzene, 1,3-diethenyl-, polymer with 1,3-butadiene and ethenylbenzene (26471-45-4)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
EPA TSCA Regulatory Flag XU - XU - indicates a substance exempt from reporting under the
Inventory Update Reporting Rule, i.e, Partial Updating of the TSCA
Inventory Data Base Production and Site Reports (40 CFR 710(C))
US State Regulations
Benzene (71-43-2)
U.S. - California - Proposition 65 - Carcinogens List WARNING: This product contains chemicals known to the State of
California to cause cancer.
U.S. - California - Proposition 65 - Developmental
Toxicity
WARNING: This product contains chemicals known to the State of
California to cause birth defects.
U.S. - California - Proposition 65 - Reproductive
Toxicity - Male
WARNING: This product contains chemicals known to the State of
California to cause (Male) reproductive harm.
Acetaldehyde (75-07-0)
U.S. - California - Proposition 65 - Carcinogens List WARNING: This product contains chemicals known to the State of
California to cause cancer.
Methyl alcohol (67-56-1)
U.S. - California - Proposition 65 - Developmental
Toxicity
WARNING: This product contains chemicals known to the State of
California to cause birth defects.
Naphthalene (91-20-3)
U.S. - California - Proposition 65 - Carcinogens List WARNING: This product contains chemicals known to the State of
California to cause cancer.
Dimethyl ether (115-10-6)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List
1,1-Difluoroethane (75-37-6)
Gorilla Spray Adhesive SDS Page 16 of 19
Safety Data Sheet – Gorilla Spray Adhesive
Date Revised: 11/01/2019
Date Issued: 02/28/2017
Version 1.1
FOR CHEMICAL EMERGENCY
DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations.
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
Propane (74-98-6)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List
Butane (106-97-8)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List
Cyclohexane (110-82-7)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List
Benzene (71-43-2)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) - Special Hazardous Substances
U.S. - Pennsylvania - RTK (Right to Know) List
Methyl acetate (79-20-9)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List
Acetaldehyde (75-07-0)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List
Methyl alcohol (67-56-1)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List
Acetic acid (64-19-7)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List
Acetone (67-64-1)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List
Naphthalene (91-20-3)
Gorilla Spray Adhesive SDS Page 17 of 19
Safety Data Sheet – Gorilla Spray Adhesive
Date Revised: 11/01/2019
Date Issued: 02/28/2017
Version 1.1
FOR CHEMICAL EMERGENCY
DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations.
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
Other Information : This document has been prepared in accordance with the SDS
requirements of the OSHA Hazard Communication Standard 29 CFR
1910.1200
NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given.
NFPA fire hazard : 4 - Will rapidly or completely vaporize at normal pressure and temperature, or is readily dispersed in air and will burn readily.
NFPA reactivity : 1 - Normally stable, but can become unstable at elevated temperatures and pressures or may react with water with some release of energy, but not violently.
GHS Full Text Phrases:
------ Acute Tox. 3 (Dermal) Acute toxicity (dermal) Category 3
------ Acute Tox. 3 (Inhalation:vapor) Acute toxicity (inhalation:vapor) Category 3
------ Acute Tox. 3 (Oral) Acute toxicity (oral) Category 3
------ Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category 4
------ Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4
------ Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category 1
------ Aquatic Acute 2 Hazardous to the aquatic environment - Acute Hazard Category 2
------ Aquatic Acute 3 Hazardous to the aquatic environment - Acute Hazard Category 3
------ Aquatic Chronic 1 Hazardous to the aquatic environment - Chronic Hazard Category 1
------ Aquatic Chronic 2 Hazardous to the aquatic environment - Chronic Hazard Category 2
------ Aquatic Chronic 3 Hazardous to the aquatic environment - Chronic Hazard Category 3
------ Asp. Tox. 1 Aspiration hazard Category 1
------ Carc. 1A Carcinogenicity Category 1A
------ Carc. 2 Carcinogenicity Category 2
------ Comb. Dust Combustible Dust
------ Eye Dam. 1 Serious eye damage/eye irritation Category 1
------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A
------ Eye Irrit. 2B Serious eye damage/eye irritation Category 2B
------ Flam. Aerosol 1 Flammable aerosol Category 1
------ Flam. Gas 1 Flammable gases Category 1
------ Flam. Liq. 1 Flammable liquids Category 1
------ Flam. Liq. 2 Flammable liquids Category 2
------ Flam. Liq. 3 Flammable liquids Category 3
------ Flam. Sol. 2 Flammable solids Category 2
------ Liquefied gas Gases under pressure Liquefied gas
------ Muta. 1B Germ cell mutagenicity Category 1B
Gorilla Spray Adhesive SDS Page 18 of 19
Safety Data Sheet – Gorilla Spray Adhesive
Date Revised: 11/01/2019
Date Issued: 02/28/2017
Version 1.1
FOR CHEMICAL EMERGENCY
DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations.
------ Simple Asphy Simple Asphyxiant
------ Skin Corr. 1A Skin corrosion/irritation Category 1A
------ Skin Irrit. 2 Skin corrosion/irritation Category 2
------ STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1
------ STOT SE 1 Specific target organ toxicity (single exposure) Category 1
------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3
------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3
------ H220 Extremely flammable gas
------ H222 Extremely flammable aerosol
------ H224 Extremely flammable liquid and vapor
------ H225 Highly flammable liquid and vapor
------ H226 Flammable liquid and vapor
------ H228 Flammable solid
------ H280 Contains gas under pressure; may explode if heated
------ H301 Toxic if swallowed
------ H302 Harmful if swallowed
------ H304 May be fatal if swallowed and enters airways
------ H311 Toxic in contact with skin
------ H312 Harmful in contact with skin
------ H314 Causes severe skin burns and eye damage
------ H315 Causes skin irritation
------ H318 Causes serious eye damage
------ H319 Causes serious eye irritation
------ H320 Causes eye irritation
------ H331 Toxic if inhaled
------ H335 May cause respiratory irritation
------ H336 May cause drowsiness or dizziness
------ H340 May cause genetic defects
------ H350 May cause cancer
------ H351 Suspected of causing cancer
------ H370 Causes damage to organs
------ H372 Causes damage to organs through prolonged or repeated exposure
------ Simple Asphy May displace oxygen and cause rapid suffocation
------ H400 Very toxic to aquatic life
------ H401 Toxic to aquatic life
------ H402 Harmful to aquatic life
------ H410 Very toxic to aquatic life with long lasting effects
------ H411 Toxic to aquatic life with long lasting effects
------ H412 Harmful to aquatic life with long lasting effects
Gorilla Spray Adhesive SDS Page 19 of 19
Safety Data Sheet – Gorilla Spray Adhesive
Date Revised: 11/01/2019
Date Issued: 02/28/2017
Version 1.1
FOR CHEMICAL EMERGENCY
DURING BUSINESS HOURS: (800) 966-3458 | OUTSIDE BUSINESS HOURS: (800) 420-7186
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations.
The information presented in this Safety Data Sheet was prepared by qualified personnel and to the best of our knowledge is true and
accurate. The information and recommendations are furnished for this product with the understanding that the purchaser will
independently determine the suitability of the product for this purpose. This data does not constitute a warranty, expressed or implied,
statutory or otherwise, nor is it representation for which The Gorilla Glue Company assumes legal responsibility. The data is submitted
for the user’s information and consideration only. Any use of this product must be determined by the user to be in accordance with
applicable federal, state, provincial and local laws and regulations.
Gorilla Glue US GHS SDS 2015
SAFETY DATA SHEET Page : 1 / 11
Revision nr : 2.0
Issue date : 04/10/2016
Honda ATF DW1 Supersedes : 30/08/2013
HONDA-608
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Trade name/designation : Honda ATF DW1
Product code : 0826899901/4HE
Document no. : HONDA-608
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Use of the substance/mixture : Lubricants
1.2.2. Uses advised against
No data available
1.3. Details of the supplier of the safety data sheet
Honda Motor Europe Logistics NV Langerbruggestraat 104 9000 Gent - BELGIUM T +32 (0)9 250 1211 - F +32 (0)9 250 1230 Kristiaan.van.renterghem@honda-eu.com National representative: United Kingdom: Honda Motor Europe Ltd London Road 470, SL3 8QY Slough Berkshire, Great Britain Tel: 0044 1753590326
1.4. Emergency telephone number
Emergency number : +32 (0)3 575 0330 This telephone number is available 24 hours per day, 7 days per week.
Country Official advisory body Address Emergency number
Ireland National Poisons Information Centre Beaumont Hospital
Beaumont Hospital Beaumont Road 9 Dublin +353 1 809 21 66 (public, 8am - 10pm, 7/7) +353 01 809 2566 (Professionals, 24/7)
United Kingdom National Poisons Information Service (Newcastle Centre) Regional Drugs and Therapeutics Centre, Wolfson Unit
Claremont Place Newcastle-upon-Tyne NE1 4LP Newcastle
0844 892 0111 (UK only, Monday to Friday, 08.00 to 18.00 hours, healthcare professionals only)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to
Regulation (EU) 2015/830 (REACH Annex II)
Aquatic Chronic 3 H412
Full text of hazard classes and H-statements : see section 16
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display
Signal word : -
SAFETY DATA SHEET Page : 2 / 11
Revision nr : 2.0
Issue date : 04/10/2016
Honda ATF DW1 Supersedes : 30/08/2013
HONDA-608
Hazard statements : H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements : P273 - Avoid release to the environment. P501 - Dispose of contents/container to an approved waste disposal plant.
Extra phrases : EUH208 - Contains N-Phenyl-1-Naphthylamine. May produce an allergic reaction.
2.3. Other hazards
Other hazards : PBT/vPvB data. This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
3.2. Mixture
Comments : Lubricating oils, DMSO< 3% (IP 346)
Substance name Product identifier % Classification according
to Regulation (EC) No.
1272/2008 [CLP]
Severly refined mineral oils (CAS No) - (EC no) - (EC Index) -
80 - 90 Not classified
2,6-di-tert-butyl-p-cresol (CAS No) 128-37-0 (EC no) 204-881-4 (EC Index) -
< 0,4 Aquatic Acute 1, H400 Aquatic Chronic 1, H410
N-Phenyl-1-Naphthylamine (CAS No) 90-30-2 (EC no) 201-983-0 < 0,2 Acute Tox. 4 (Oral), H302 Skin Sens. 1, H317 STOT RE 2, H373 Aquatic Acute 1, H400 Aquatic Chronic 1, H410
Full text of H-statements: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
Additional advice : First aider: Pay attention to self-protection. See also section 8 . Never give anything by mouth to an unconscious person. Treat symptomatically. Show this safety data sheet to the doctor in attendance. In case of doubt or persistent symptoms, consult always a physician.
Inhalation : Provide fresh air. Keep at rest. If breathing is irregular or stopped, administer artificial respiration. If breathing is difficult, give oxygen. In case of doubt or persistent symptoms, consult always a physician.
Skin contact : Wash with plenty of soap and water. Remove contaminated, saturated clothing immediately. Wash contaminated clothing before reuse. In case of doubt or persistent symptoms, consult always a physician.
Eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. In case of doubt or persistent symptoms, consult always a physician.
In case of ingestion : Rinse mouth. If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Get immediate medical advice/attention.
4.2. Most important symptoms and effects, both acute and delayed
Inhalation : Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting.
SAFETY DATA SHEET Page : 3 / 11
Revision nr : 2.0
Issue date : 04/10/2016
Honda ATF DW1 Supersedes : 30/08/2013
HONDA-608
Skin contact : May be irritating. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons.
Eye contact : Contact with eyes may cause irritation.
Ingestion : May cause gastrointestinal irritation, nausea, vomiting and diarrhoea.
4.3. Indication of any immediate medical attention and special treatment needed
No data available.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Use powder, CO2, water spray or alcohol resistant foam.
Unsuitable extinguishing media : Strong water jet.
5.2. Special hazards arising from the substance or mixture
Specific hazards : Combustible. Thermal decomposition can lead to the escape of irritating gases and vapours. Dispose of contaminated materials in accordance with current regulations. In case of fire and/or explosion do not breathe fumes.
5.3. Advice for firefighters
Firefighting instructions : Special protective equipment for firefighters. In case of fire: Wear self-contained breathing apparatus. Use water spray or fog for cooling exposed containers. Do not allow run-off from fire-fighting to enter drains or water courses. Dispose of waste in accordance with environmental legislation. Evacuate personnel to a safe area.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
For non-emergency personnel : Evacuate personnel to a safe area. Provide adequate ventilation. Use personal protective equipment as required. Reference to other sections: 8. Avoid contact with skin and eyes. Do not breathe vapour/aerosol. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
6.1.2. For emergency responders
For emergency responders : Ensure procedures and training for emergency decontamination and disposal are in place. Reference to other sections: 8.
6.2. Environmental precautions
Do not allow to enter into surface water or drains.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Stop leak if safe to do so. Dam up. Take up liquid spill into absorbent material, e.g.: sand, earth, vermiculite or powdered limestone. Take up mechanically, placing in appropriate containers for disposal. Special danger of slipping by leaking/spilling product. Dispose of contaminated materials in accordance with current regulations. Clean contaminated areas thoroughly.
6.4. Reference to other sections
Reference to other sections: 8, 12 & 13.
SAFETY DATA SHEET Page : 4 / 11
Revision nr : 2.0
Issue date : 04/10/2016
Honda ATF DW1 Supersedes : 30/08/2013
HONDA-608
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling : Provide adequate ventilation. Use personal protective equipment as required. Reference to other sections: 8. Do not ingest. Avoid contact with skin and eyes. Do not breathe vapour/aerosol. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Provide adequate precautions, such as electrical grounding and bonding, or inert atmospheres. Do not burn, or use a cutting torch on, the empty drum. Never use pressure to empty container. After use replace the closing cap immediately. Ensure proper process control to avoid excess waste discharge (temperature, concentration, pH, time). Do not allow to enter into surface water or drains. Take any precaution to avoid mixing with incompatible materials. See also section 10.
Hygiene measures : Keep good industrial hygiene. Wash hands and face before breaks and immediately after handling of the product. When using do not eat, drink or smoke. Keep away from food, drink and animal feedingstuffs. Keep work clothes separately. Take off contaminated clothing. Wash contaminated clothing before reuse.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Keep container tightly closed in a cool, well-ventilated place. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ensure equipment is adequately earthed. Do not store near or with any of the incompatible materials listed in section 10.
Packaging materials : Keep/Store only in original container.
7.3. Specific end use(s)
Not applicable.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
EU Mineral oil OEL's : oil (mist) TLV-TWA (mg/m³) : 1 (se, no); 5 (be, nl, gb, fr, de, fi, dk) oil (mist) TLV-STEL (mg/m³) : 3 (se); 10 (be, gb):
2,6-di-tert-butyl-p-cresol (128-37-0)
Austria MAK (mg/m³) 10 mg/m³
Belgium Limit value (mg/m³) 2 mg/m³ (aerosol and vapor)
Bulgaria OEL TWA (mg/m³) 10 mg/m³
Bulgaria OEL STEL (mg/m³) 50 mg/m³
Croatia GVI (granična vrijednost izloženosti) (mg/m³) 10 mg/m³
Denmark Grænseværdie (langvarig) (mg/m³) 10 mg/m³
Finland HTP-arvo (8h) (mg/m³) 10 mg/m³
Finland HTP-arvo (15 min) 20 mg/m³
France VME (mg/m³) 10 mg/m³
Germany TRGS 900 Occupational exposure limit value (mg/m³) 10 mg/m³ (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed-inhalable fraction)
Greece OEL TWA (mg/m³) 10 mg/m³
Ireland OEL (8 hours ref) (mg/m³) 10 mg/m³
Ireland OEL (15 min ref) (mg/m3) 30 mg/m³ (calculated)
Portugal OEL TWA (mg/m³) 2 mg/m³ (inhalable fraction, aerosol and vapor)
Slovenia OEL TWA (mg/m³) 10 mg/m³ (inhalable fraction)
SAFETY DATA SHEET Page : 5 / 11
Revision nr : 2.0
Issue date : 04/10/2016
Honda ATF DW1 Supersedes : 30/08/2013
HONDA-608
2,6-di-tert-butyl-p-cresol (128-37-0)
Spain VLA-ED (mg/m³) 10 mg/m³
United Kingdom WEL TWA (mg/m³) 10 mg/m³
United Kingdom WEL STEL (mg/m³) 30 mg/m³ (calculated)
Switzerland VME (mg/m³) 10 mg/m³ (inhalable dust)
Switzerland VLE (mg/m³) 40 mg/m³ (inhalable dust)
Australia TWA (mg/m³) 10 mg/m³
Canada (Quebec) VECD (mg/m³) 10 mg/m³
USA - ACGIH ACGIH TWA (mg/m³) 2 mg/m³ (inhalable fraction and vapor)
USA - NIOSH NIOSH REL (TWA) (mg/m³) 10 mg/m³
Additional information : Concentration measurement in air. Personal air monitoring
8.2. Exposure controls
Engineering control measures : Provide adequate ventilation. Emergency eye wash fountains and safety showers
should be available in the immediate vicinity of any potential exposure. Take precautionary measures against static discharges. Organisational measures to prevent /limit releases, dispersion and exposure. See also section 7.
Personal protection equipment : Not required for normal conditions of use. Choose body protection according to the amount and concentration of the dangerous substance at the work place.
Hand protection : During splash contact: Wear chemically resistant gloves (tested to EN374) . NBR (Nitrile rubber),. Fluorinated rubber . Thickness of the glove material: > 0,3mm. The selection of specific gloves for a specific application and time of use in a working area, should also take into account other factors on the working space, such as (but not limited to): other chemicals that are possibly used, physical requirements (protection against cutting/drilling, skill, thermal protection), and the instructions/specification of the supplier of gloves. The exact break through time can be obtained from the protective glove producer and this has to be observed
Eye protection : During splash contact: Wear eye glasses with side protection according to EN 166.
Body protection : Wear suitable protective clothing. Overalls, apron and boots recommended
Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Full face mask (EN 136). Half-face mask (DIN EN 140). Filter type: AP. (EN141)
Thermal hazard protection : Heat resistant gloves.
Environmental exposure controls : Do not allow to enter into surface water or drains. Comply with applicable Community environmental protection legislation.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : liquid
Appearance : clear.
Colour : red.
Odour : slight.
Odour threshold : No data available
pH : No data available Relative evaporation rate (butylacetate=1) : No data available Melting point/freezing point : No data available
Freezing point : No data available
Initial boiling point and boiling range : No data available
Flash point : 172 °C (COC)
SAFETY DATA SHEET Page : 6 / 11
Revision nr : 2.0
Issue date : 04/10/2016
Honda ATF DW1 Supersedes : 30/08/2013
HONDA-608
Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : Not applicable,liquid
Vapour pressure : No data available
Vapour density : No data available
Relative density : No data available Density : 0,8501 g/cm³ (@15°C)
Solubility : No data available. Water: Insoluble
Partition coefficient n-octanol/water : No data available
Kinematic viscosity : 6,816 (@ 100°C) 24,85 mm²/s (@40°C) Dynamic viscosity : No data available Explosive properties : Not applicable. The study does not need to be conducted because there are no chemical groups associated with explosive properties present in the molecule. Oxidising properties : Not applicable. The classification procedure needs not to be applied because there are no chemical groups present in the molecule which are associated with oxidising properties.
Explosive limits : No data available
9.2. Other information
Other properties : Pour point -50,0°C.
SECTION 10: Stability and reactivity
10.1. Reactivity
Reference to other sections: 10.5.
10.2. Chemical stability
Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous polymerisation does not occur. See also section 7.
10.4. Conditions to avoid
Keep away from sources of heat (e.g. hot surfaces), sparks and open flames. See also section 7 : Handling and storage.
10.5. Incompatible materials
Strong oxidizing agents. Strong bases. See also section 7 : Handling and storage.
10.6. Hazardous decomposition products
Thermal decomposition can lead to the escape of irritating gases and vapours. Reference to other sections: 5.2.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Not classified (Based on available data, the classification criteria are not met)
Severly refined mineral oils (-)
LD50/oral/rat > 2000 mg/kg
LD50/dermal/rat > 2000 mg/kg
LD50/dermal/rabbit > 2000 mg/kg
LC50/inhalation/4h/rat > 5 mg/l/4h
2,6-di-tert-butyl-p-cresol (128-37-0)
LD50/oral/rat 890 mg/kg
SAFETY DATA SHEET Page : 7 / 11
Revision nr : 2.0
Issue date : 04/10/2016
Honda ATF DW1 Supersedes : 30/08/2013
HONDA-608
2,6-di-tert-butyl-p-cresol (128-37-0)
LD50/dermal/rat > 2000 mg/kg
LC50/inhalation/4h/rat 546 mg/m³
N-Phenyl-1-Naphthylamine (90-30-2)
LD50/oral/rat 1625 mg/kg
Skin corrosion/irritation : Not classified (Based on available data, the classification criteria are not met)
pH: No data available
Serious eye damage/eye irritation : Not classified (Based on available data, the classification criteria are not met)
pH: No data available
Respiratory or skin sensitisation : Not classified (Based on available data, the classification criteria are not met)
Germ cell mutagenicity : Not classified (Based on available data, the classification criteria are not met)
Carcinogenicity : Not classified (Based on available data, the classification criteria are not met)
Base oil - unspecified (DMSO < 3%)
Reproductive toxicity : Not classified (Based on available data, the classification criteria are not met)
STOT-single exposure : Not classified (Based on available data, the classification criteria are not met)
STOT-repeated exposure : Not classified (Based on available data, the classification criteria are not met)
Aspiration hazard : Not classified (Based on available data, the classification criteria are not met)
Other information : Symptoms related to the physical, chemical and toxicological characteristics. Reference to other sections: 4.2.
SECTION 12: Ecological information
12.1. Toxicity
Environmental properties : Harmful to aquatic life with long lasting effects.
Severly refined mineral oils (-)
LC50 fish 1 5000 mg/l Oncorhynchus mykiss (Rainbow trout)
LC50 other aquatic organisms 1 10000 mg/l Lepomis macrochirus (Bluegill)
EC50 Daphnia 1 1000 mg/l Daphnia magna (Big water flea)
EC50 other aquatic organisms 1 > 100 mg/l (WAF)
LOEC (acute) >= 100 mg/l (WAF)
12.2. Persistence and degradability
Persistence and degradability No information available.
12.3. Bioaccumulative potential
Partition coefficient n-octanol/water No data available
Bioaccumulative potential No information available.
Severly refined mineral oils (-)
Partition coefficient n-octanol/water > 6
2,6-di-tert-butyl-p-cresol (128-37-0)
BCF fish 1 230 - 2500
Partition coefficient n-octanol/water 4,17
12.4. Mobility in soil
Mobility in soil No information available
SAFETY DATA SHEET Page : 8 / 11
Revision nr : 2.0
Issue date : 04/10/2016
Honda ATF DW1 Supersedes : 30/08/2013
HONDA-608
Honda ATF DW1
Surface tension No data available
Ecology - soil No information available.
12.5. Results of PBT and vPvB assessment
Results of PBT assessment The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
12.6. Other adverse effects
Additional information : No information available
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste disposal recommendations : Handle with care. Safe handling: see section 7 : Handling and storage . Dispose of
contaminated materials in accordance with current regulations. Refer to manufacturer/supplier for information on recovery/recycling. Collect and dispose of waste product at an authorised disposal facility. Liquid product may not be disposed of with household waste or landfilled. Do not allow to enter into drains/waters or in the soil.
Additional information : Delivery to an approved waste disposal company. This material and its container must be disposed of as hazardous.
List of proposed waste codes/waste designations in accordance with EWC (2001/573/EC, 75/442/EEC, 91/689/EEC)
: Classified as hazardous waste according to European Union regulations The following Waste Codes are only suggestions: 130205 - mineral-based non-chlorinated engine, gear and lubricating oils Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities
SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
ADR IMDG IATA ADN RID
14.1. UN number
14.2. UN proper shipping name
Transport document description
14.3. Transport hazard class(es)
14.4. Packing group
14.5. Environmental hazards
14.6. Special precautions for user
Special precautions for user : Not applicable
SAFETY DATA SHEET Page : 9 / 11
Revision nr : 2.0
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HONDA-608
- Overland transport
No data available
- Transport by sea
No data available
- Air transport
No data available
- Inland waterway transport
No data available
- Rail transport
No data available
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Code: IBC : Not applicable.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
The following restrictions are applicable according to Annex XVII of the REACH Regulation (EC) No 1907/2006:
3. Liquid substances or mixtures which are regarded as dangerous in accordance with Directive 1999/45/EC or are fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008
Honda ATF DW1 - N-Phenyl-1-Naphthylamine
3.b. Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10
N-Phenyl-1-Naphthylamine
3.c. Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class 4.1 Honda ATF DW1 - N-Phenyl-1-Naphthylamine
Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances
15.1.2. National regulations
France Installations classées :
Not applicable
Germany
VwVwS Annex reference : Water hazard class (WGK) 1, low hazard to waters (Classification according to VwVwS, Annex 4)
Risk classification according to VbF : Not applicable
12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
TA Luft : Organic Substances
Netherlands
Waterbezwaarlijkheid : 8 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Saneringsinspanningen : A - In principe niet lozen; zo ja, dan toepassen van beste bestaande technieken
SAFETY DATA SHEET Page : 10 / 11
Revision nr : 2.0
Issue date : 04/10/2016
Honda ATF DW1 Supersedes : 30/08/2013
HONDA-608
SZW-lijst van kankerverwekkende stoffen : None of the components are listed
SZW-lijst van mutagene stoffen : None of the components are listed
NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Borstvoeding : None of the components are listed
NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Vruchtbaarheid
: None of the components are listed
NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Ontwikkeling : None of the components are listed
15.2. Chemical safety assessment
No data available
SECTION 16: Other information
Indication of changes:
Safety datasheet sections which have been updated : 1-2-3-4-9-10-11-12-14-15-16.
Abbreviations and acronyms:
DNEL = Derived No Effect Level
DMEL = Derived Minimal Effect level
PNEC = Predicted No Effect Concentration
OEL = Occupational Exposure Limits - Short Term Exposure Limits (STELs)
TWA = time weighted average
LC50 = Median lethal concentration
LD50 = Median lethal dose
LL50 = Median lethal level
EC50 = Median Effective Concentration
EL50 = Median effective level
ErC50 = EC50 in terms of reduction of growth rate
ErL50 = EL50 in terms of reduction of growth rate
NOEL = no-observed-effect level
NOEC = No observed effect concentration
NOELR = No observed effect loading rate
NOAEC = No observed adverse effect concentration
NOAEL = No observed adverse effect level
EWC = European waste catalogue
NA = Not applicable
N.O.S. = Not Otherwise Specified
VOC = Volatile organic compounds
Quantitative structure-activity relationship (QSAR)
SAFETY DATA SHEET Page : 11 / 11
Revision nr : 2.0
Issue date : 04/10/2016
Honda ATF DW1 Supersedes : 30/08/2013
HONDA-608
ADN = Accord Européen relatif au Transport International des Marchandises Dangereuses par voie de Navigation du Rhin ADR = Accord européen relatif au transport international des marchandises Dangereuses par Route CLP = Classification, Labelling and Packaging Regulation according to 1272/2008/EC IATA = International Air Transport Association IMDG = International Maritime Dangerous Goods Code LEL = Lower Explosive Limit/Lower Explosion Limit UEL = Upper Explosion Limit/Upper Explosive Limit REACH = Registration, Evaluation, Authorisation and Restriction of Chemicals
WGK = Wassergefährdungsklasse (Water Hazard Class under German Federal Water Management Act)
ABM = Algemene beoordelingsmethodiek
STOT = Specific Target Organ Toxicity
Sources of key data used to compile the datasheet : Name (SDS) : HONDA ATF DW-1. Manufacturer/Supplier : IDEMITSU. Date of issue : 24-Sep-2013. Revision date : 15-Apr-2015.
Training advice : Training staff on good practice.
Other information : Assessment/classification CLP. Article 9. Calculation method.
Full text of H- and EUH-statements:
Acute Tox. 4 (Oral) Acute toxicity Category 4
Aquatic Acute 1 Hazardous to the aquatic environment - Aquatic Acute 1
Aquatic Chronic 1 Hazardous to the aquatic environment - chronic hazard category 1
Aquatic Chronic 3 Hazardous to the aquatic environment - chronic hazard category 3
Skin Sens. 1 Skin sensitisation, hazard category 1
STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2
H302 Harmful if swallowed.
H317 May cause an allergic skin reaction.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
EUH208 Contains . May produce an allergic reaction
SAFETY DATA SHEET
Purple Power Cleaner/Degreaser
1
Section 1: Product and Company Identification:
Product Name: Purple Power Concentrated Industrial Strength Cleaner/Degreaser
Product Use: Cleaner
Part#’s: 4315PS, 4332PS, 4380DG, 4320P, 4322P, 4325P, 4330, 4340, PP275
Manufacture/Supplier: Aiken Chemical Company, Inc.
P.O. Box 27147, Greenville, SC 29616
12 Shelter Drive, Greer, SC 29650
Phone Number: (864) 968-1250
1-800-828-1860
Emergency Phone: 1-800-424-9300
Date of Preparation: March 30, 2015
Section 2: Hazards Identification:
Emergency Overview:
Warning: Corrosive Material – May Cause Burns, Irritating to Eyes and Skin.
Potential Health Effects: See Section 11 for more information.
Likely Routes of Exposure: Eye contact, skin contact, ingestion, and inhalation.
Eye: May cause burns and Irritating to eyes.
Skin: May cause burns and Irritating to skin.
Ingestion: May cause burns and may be harmful if swallowed. May cause stomach distress,
nausea, or vomiting
Inhalation: May cause respiratory tract irritation. May cause burns
Chronic Effects: Prolonged or repeated contact may dry skin and cause irritation.
Signs and symptoms: Symptoms may include discomfort or pain, excess blinking and tear production,
with marked redness and swelling of the conjunctiva. Symptoms may include
redness, edema, drying, de-fatting and cracking of the skin.
Medical Conditions Aggravated By Exposure:
Because of its irritating properties, product may aggravate preexisting skin, eye, and
respiratory conditions.
Target Organs: Skin, eyes, gastrointestinal tract, respiratory system
Potential Environmental Effects: See Section 12 from more information.
Section 3: Composition / Information on Ingredients:
Ingredient CAS# Percent
Diethylene glycol monobutyl ether 112-34-5 1-5
Section 4: First Aid Measures:
Eye Contact: Remove contact lenses if present. Immediately flush eyes with large amounts of water
for at least 15 minutes, lifting upper and lower eyelids periodically to insure complete
flushing. Seek medical attention immediately.
Skin Contact: Remove contaminated clothing immediately. Thoroughly wash exposed area with soap
and water for at least 15 minutes. Seek medical attention immediately.
Inhalation: Remove individual to fresh air. If breathing has stopped, give artificial respiration. Seek
medical attention immediately.
Ingestion: DO NOT induce vomiting. If conscious, dilute by giving 2-3 glasses of water. Seek medical
attention immediately
General Advice: In case of accident or if you feel unwell, seek medical advice immediately. Show the label
or SDS where possible.
Note to Physicians: Symptoms may not appear immediately.
Hazard Determination System (HDS): Health, Flammability, Reactivity
1 0 0
SAFETY DATA SHEET
Purple Power Cleaner/Degreaser
2
Section 5: Fire Fighting Measures:
Flammability: Not Flammable by WHMIS/OSHA Criteria.
Means of Extinguishing:
Suitable extinguishing media: Use water fog, alcohol foam, carbon dioxide or dry chemical.
Unsuitable Extinguishing Media: Not Available.
Products of Combustion: Not Available.
Explosion Data:
Sensitivity to Mechanical Impact: Not Available.
Sensitivity to Static Discharge: Not Available.
Protection of Firefighters: Keep Upwind of fire. Wear full fire fighting turn-out gear, (full Bunker
gear), and respiratory protection (SCBA)
Section 6: Accidental Release Measures:
Personal Precautions: Use personal protection recommended in section 8. Isolate the hazard area and deny
entry to unnecessary and unprotected personnel.
Environmental Precautions: Not Available.
Methods for Containment: Contain and/or absorb spill with inert material, (e.g. sand, vermiculite), then place in a
suitable container. Use appropriate Personal Protective Equipment, (PPE).
Methods for Clean-up: Scoop up material and place in a disposal container. Provide ventilation.
Other Information: Not Available.
Section 7: Handling and Storage:
Handling: Avoid contact with skin and eyes. Do not swallow. Do not breathe
gas/fumes/vapor/spray. Use only in well-ventilated areas. Handle and open container
with care. Launder contaminated clothing before reuse. When using, do not eat or drink.
Wash hands before eating, drinking, or smoking.
Storage: Do not store in aluminum, copper, or galvanized containers. Separate from acids,
reactive metals, and ammonium salts.
Section 8: Exposure Controls/Personal Protections:
Exposure Guidelines:
Ingredient Exposure Limits
OSHA-PEL ACGIH-TLV
Diethylene glycol monobutyl ether: Not Available 10 ppm
Engineering Controls: Use Ventilation adequate to keep exposures, (airborne levels of dust, fume,
vapor, etc.), below recommended exposure limits.
Personal Protective Equipment:
Eye/Face Protection: Wear eye/face protection.
Hand Protection: Wear suitable gloves, (Neoprene, Nitrile Rubber, and Polyethylene).
Skin and Body Protection: Wear body-covering, impervious clothing, chemical resistant gloves and boots.
General Hygiene Considerations: Handle according to established industrial hygiene and safety practices.
Section 9: Physical and Chemical Properties:
Appearance and Odor: Purple liquid with Characteristic odor.
Physical State: Liquid.
pH: 12.98
Freezing Point: ~2°C (~28.4°F)
Boiling Point: ~100°C (~212°F)
Flash Point (Method Used): >200°F (PMCC)
Evaporation Rate (Butyl Acetate= 1) : <1.0
LEL: Not Determined
SAFETY DATA SHEET
Purple Power Cleaner/Degreaser
3
UEL: Not Determined
Vapor Pressure (mm Hg.): Not Determined
Vapor Density (AIR=1): Not Determined
Specific Gravity: 1.0197
Solubility in Water: Complete
Melting Point: NA
Auto-Ignition Temperature: Not Determined
Percent Volatile, wt%: Not Determined
VOC content, wt. %: < 0.2
Section 10: Stability and Reactivity:
Stability: Stable under normal storage conditions.
Conditions to Avoid: Mixing or blending with oxidizing or low pH solutions
Incompatibility (Materials to Avoid): Avoid contact with reactive metals, strong mineral acids and organic acids.
Hazardous Decomposition or Byproducts: Carbon dioxide, carbon monoxide, various hydrocarbons and can
include aldehydes, ketones, organic acids and other organics.
Hazardous Polymenzation: Will Not Occur.
Section 11: Toxicology Information:
Effects of Acute Exposure
Component Analysis: Routes of entry for solids and liquids are ingestion and inhalation, but may
include eye or skin contact. Routes of entry for gases include inhalation and eye
contact. Skin contact may be a route of entry for liquefied gases.
(Poly (oxy-1, 2-ethanediyl), a-(2-propylheptyl)-w-hydroxy-):
Acute Toxicity/Effects:
Assessment of acute toxicity: Slightly toxic after single ingestion.
Oral: LD50 judged > 500 mg/kg based on deaths at 200mg/kg (0/6) and 2000mg/kg (2/3)
plus oral LD50 data on surrogate chemicals.
Irritation/corrosion: Causes serious eye damage and causes skin irritation as well as, may cause
irritations to the respiratory tract.
Skin: Species: rabbit, Result: Irritation. Method: OECD Guideline 404
Eye: Species: Rabbit, Results: Risk of serious damage to eyes. Method: OECD
Guideline 405
Sensitization: Guinea pig maximization test: Species: guinea pig. Result: Skin sensitizing
effects were not observed in animal studies. Method: OECD Guideline 406.
Aspiration Hazard: No aspiration hazard expected.
Chronic Toxicity/Effects
Symptoms of Exposure: The most important known symptoms and effects are described in the labeling,
(see section 2), and/or in section 11. Further important symptoms and effects
are so far not known.
Diethylene glycol monobutyl ether:
Effects, Acute Exposure:
Skin Contact: May be slightly irritating
Skin Absorption: Yes; Toxic effects unlikely by this route unless contact is extensive in area &
prolonged
Eye Contact: Likely to be severely irritating (by animal testing)
Inhalation: Headache, dizziness, intoxication possible, low vapor pressure makes this
unlikely.
Ingestion: Headache, dizziness, intoxication; in severe cases, cyanosis (blue coloring), low
blood pressure, & unconsciousness
SAFETY DATA SHEET
Purple Power Cleaner/Degreaser
4
Effects, Chronic Exposure:
General: Little to no effect reported
Sensitizing: Not a sensitizer in humans or animals
Carcinogen/Tumorigen: Not considered a Tumorigen or a carcinogen in humans or animals.
Reproductive Effect: No known effect in humans or animals
Mutagen: No known effect on humans or animals
Synergistic With: Not Known
LD50 (oral): 4500 to 9625mg/kg (rat), 2400 to 525mg/kg (mouse), 1720 to
2310mg/kg (guinea pig), and 2200mg/kg (rabbit)
LD50 (skin): 2700mg/kg (rabbit)
LC50 (inhalation): None – exposure of rats to DB vapor (saturated at 100 °C &
cooled to room temp.) for 7hrs caused no mortality or other adverse symptoms
Section 12: Toxicology Information:
Ecotoxicity: Not Available.
Persistence/Degradability: Not Available.
Bioaccumulation/Accumulation: Not Available
Mobility in Environment: Not Available.
Section 13: Disposal Considerations:
Disposal Instructions: This material must be disposed of in accordance with all local, state, provincial,
and federal regulations.
Section 14: Transportation Information:
Proper Shipping Name: Not D.O.T. Regulated
Hazard Class: N/A
ID Number: N/A
Packing Group N/A
IATA: N/A
Section 15: Regulatory Information:
Chemical Inventories:
TSCA: All components of this product are either on the TSCA 8(b) Inventory
or otherwise exempt from listing.
SARA Section 311: Acute
SARA Section 313: Toxic Release Inventory Chemical: Glycol Ethers,
California Safe Drinking Water Enforcement Act (Prop 65):
This product contains no listed substances known to the State of California to cause cancer, birth defects
or other reproductive harm, at levels which would require a warning under the stature.
Pennsylvania (Worker and Community Right-to-Know act):
Pennsylvania Special Hazardous Substance List and/or Pennsylvania Environmental Hazardous
Substance list:
To the best of our knowledge, this product does not contain chemicals that require reporting under this
stature.
New Jersey Right-to-Know Hazardous Substance List:
To the best of our knowledge, this product does not contain chemicals that require reporting under this
stature.
SAFETY DATA SHEET
Purple Power Cleaner/Degreaser
5
Massachusetts Substance List:
To the best of our knowledge, this product does not contain chemicals that require reporting under this
stature.
Section 16: Other Information:
NFPA Health Hazard Flammability Instability Physical &Chemical Hazards
1 0 0 COR
HMIS Health Hazard Flammability Physical Hazard Personal Protection
1 0 0 C
Prepared By: Aiken Chemical Company, Inc.
12 Shelter Drive
Greer, SC 29650
Preparation/Revision Date: March 30, 2015
Revision Date:
Revision Note
General Disclaimer: The information provided in this Safety Data Sheet is correct to the best of our knowledge, information, and belief at the date of its publication. The
information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or
quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in
any process, unless specified in the text.
_____________________________________________________________________
Revision Number: 18
Revision Date: January 31, 2023 1 of 8 Delo Gear ESI SAE 80W-90, 85W-140
SDS : 6698
Safety Data Sheet
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
Delo Gear ESI SAE 80W-90, 85W-140
Product Use: Axle Oil
Product Number(s): 224503, 224504, 224605, 224606
Synonyms: Delo Gear ESI SAE 80W-90 ISOCLEAN Certified; Delo Gear ESI SAE 85W-140
ISOCLEAN Certified
Company Identification
Chevron Products Company
a division of Chevron U.S.A. Inc.
6001 Bollinger Canyon Rd.
San Ramon, CA 94583
United States of America
www.chevronlubricants.com
Transportation Emergency Response
CHEMTREC: (800) 424-9300 or (703) 527-3887
Health Emergency
Chevron Emergency & Information Center: Located in the USA. International collect calls accepted. (800)
231-0623 or (510) 231-0623
Product Information
email : lubemsds@chevron.com
Product Information: 1 (800) 582-3835, LUBETEK@chevron.com
SECTION 2 HAZARDS IDENTIFICATION
CLASSIFICATION:
• Acute aquatic toxicant: Category 3.
• Chronic aquatic toxicant: Category 3.
Environmental Hazards:
• Harmful to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENTS:
Prevention:
• Avoid release to the environment.
Disposal:
• Dispose of contents/container in accordance with applicable local/regional/national/international
regulations.
HAZARDS NOT OTHERWISE CLASSIFIED: Heating may release highly toxic and flammable hydrogen
sulfide (H2S). Do not attempt rescue without supplied-air respiratory protection.
_____________________________________________________________________
Revision Number: 18
Revision Date: January 31, 2023 2 of 8 Delo Gear ESI SAE 80W-90, 85W-140
SDS : 6698
SECTION 3 COMPOSITION/ INFORMATION ON INGREDIENTS
COMPONENTS CAS NUMBER AMOUNT
Highly refined mineral oil (C15 - C50) Mixture 70 - 99 %weight
Borate dispersion 20786-60-1 1 - < 3 %weight
Alkyl phosphorous acid esters Trade secret 0.1 - < 1 %weight
Calcium long chain alkaryl sulfonate 115733-09-0 < 0.25 %weight
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye: No specific first aid measures are required. As a precaution, remove contact lenses, if worn, and
flush eyes with water.
Skin: No specific first aid measures are required. As a precaution, remove clothing and shoes if
contaminated. To remove the material from skin, use soap and water. Discard contaminated clothing
and shoes or thoroughly clean before reuse.
Ingestion: No specific first aid measures are required. Do not induce vomiting. As a precaution, get
medical advice.
Inhalation: No specific first aid measures are required. If exposed to excessive levels of material in the
air, move the exposed person to fresh air. Get medical attention if coughing or respiratory discomfort
occurs. If exposure to hydrogen sulfide (H2S) gas is possible during an emergency, wear an approved,
positive pressure air-supplying respirator. Move the exposed person to fresh air. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention.
Most important symptoms and effects, both acute and delayed
IMMEDIATE HEALTH EFFECTS
Eye: Not expected to cause prolonged or significant eye irritation.
Skin: Contact with the skin is not expected to cause prolonged or significant irritation. Contact with the
skin is not expected to cause an allergic skin response. Not expected to be harmful to internal organs if
absorbed through the skin.
Ingestion: Not expected to be harmful if swallowed.
Inhalation: Not expected to be harmful if inhaled. Contains a petroleum-based mineral oil. May cause
respiratory irritation or other pulmonary effects following prolonged or repeated inhalation of oil mist at
airborne levels above the recommended mineral oil mist exposure limit. Symptoms of respiratory irritation
may include coughing and difficulty breathing. Hydrogen sulfide has a strong rotten-egg odor. However,
with continued exposure and at high levels, H2S may deaden a person's sense of smell. If the rotten egg
odor is no longer noticeable, it may not necessarily mean that exposure has stopped. At low levels,
hydrogen sulfide causes irritation of the eyes, nose, and throat. Moderate levels can cause headache,
dizziness, nausea, and vomiting, as well as coughing and difficulty breathing. Higher levels can cause
shock, convulsions, coma, and death. After a serious exposure, symptoms usually begin immediately.
The U.S. National Institute for Occupational Safety and Health (NIOSH) considers air concentrations of
hydrogen sulfide gas greater than 100 ppm to be Immediately Dangerous to Life and Health (IDLH).
DELAYED OR OTHER HEALTH EFFECTS: Not classified
Indication of any immediate medical attention and special treatment needed
Note to Physicians: Administration of 100% oxygen and supportive care is the preferred treatment for
poisoning by hydrogen sulfide gas. For additional information on H2S, see Chevron SDS No. 301.
SECTION 5 FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.
_____________________________________________________________________
Revision Number: 18
Revision Date: January 31, 2023 3 of 8 Delo Gear ESI SAE 80W-90, 85W-140
SDS : 6698
PROTECTION OF FIRE FIGHTERS:
Fire Fighting Instructions: This material will burn although it is not easily ignited. See Section 7 for
proper handling and storage. For fires involving this material, do not enter any enclosed or confined fire
space without proper protective equipment, including self-contained breathing apparatus.
Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne
solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic
compounds will be evolved when this material undergoes combustion. Combustion may form oxides of:
Boron, Sulfur.
SECTION 6 ACCIDENTAL RELEASE MEASURES
Protective Measures: Eliminate all sources of ignition in vicinity of spilled material.
Spill Management: Stop the source of the release if you can do it without risk. Contain release to
prevent further contamination of soil, surface water or groundwater. Clean up spill as soon as possible,
observing precautions in Exposure Controls/Personal Protection. Use appropriate techniques such as
applying non-combustible absorbent materials or pumping. Where feasible and appropriate, remove
contaminated soil. Place contaminated materials in disposable containers and dispose of in a manner
consistent with applicable regulations.
Reporting: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at
(800) 424-8802 as appropriate or required.
SECTION 7 HANDLING AND STORAGE
General Handling Information: Avoid contaminating soil or releasing this material into sewage and
drainage systems and bodies of water.
Precautionary Measures: Do not breathe gas. Wash thoroughly after handling. Keep out of the reach
of children.
Unusual Handling Hazards: Toxic quantities of hydrogen sulfide (H2S) may be present in storage tanks
and bulk transport vessels which contain or have contained this material. Persons opening or entering
these compartments should first determine if H2S is present. See Exposure Controls/Personal Protection
-Section 8. Do not attempt rescue of a person over exposed to H2S without wearing approved supplied-
air or self-contained breathing equipment. If there is a potential for exceeding one-half the occupational
exposure standard, monitoring of hydrogen sulfide levels is required. Since the sense of smell cannot be
relied upon to detect the presence of H2S, the concentration should be measured by the use of fixed or
portable devices.
Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling
this material. To minimize this hazard, bonding and grounding may be necessary but may not, by
themselves, be sufficient. Review all operations which have the potential of generating and accumulating
an electrostatic charge and/or a flammable atmosphere (including tank and container filling, splash filling,
tank cleaning, sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations)
and use appropriate mitigating procedures.
Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty
container or it may rupture with explosive force. Empty containers retain product residue (solid, liquid,
and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode
and cause injury or death. Empty containers should be completely drained, properly closed, and promptly
returned to a drum reconditioner or disposed of properly.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
GENERAL CONSIDERATIONS:
Consider the potential hazards of this material (see Section 2), applicable exposure limits, job activities,
and other substances in the workplace when designing engineering controls and selecting personal
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Revision Number: 18
Revision Date: January 31, 2023 4 of 8 Delo Gear ESI SAE 80W-90, 85W-140
SDS : 6698
protective equipment (PPE). If engineering controls or work practices are not adequate to prevent
exposure to harmful levels of this material, refer to PPE information below.
Factors that affect PPE include, but are not limited to: properties of the chemical, other chemicals which
may contact the same PPE, physical requirements (fit & sizing, cut/puncture protection, dexterity, thermal
protection, etc.), and potential allergic reactions to the PPE material. It is the responsibility of the user to
read and understand all instructions and limitations supplied with the equipment since protection is
usually provided for a limited time or under certain circumstances. Refer to appropriate CEN standards.
ENGINEERING CONTROLS:
Use in a well-ventilated area.
PERSONAL PROTECTIVE EQUIPMENT
Eye/Face Protection: Wear protective equipment to prevent eye contact. Selection of protective
equipment may include safety glasses, chemical goggles, face shields, or a combination depending on
the work operations conducted.
Skin Protection: Wear chemical personal protective equipment (PPE) to prevent skin contact. Selection
of chemical protective clothing should be performed by an Occupational Hygienist or Safety Professional
and be based upon applicable standards (ASTM F739 or EN 374). Using chemical PPE depends upon
operations conducted and may include chemical gloves, boots, chemical apron, chemical suit, and
complete facial protection. Refer to PPE manufacturers to obtain breakthrough time information to
determine how long PPE can be used before it needs to be replaced. Unless specific glove manufacturer
data indicates otherwise, the below table is based upon available industry data to assist in the glove
selection process and is intended to be used as reference only.
Chemical Glove Material Thickness
(mm) Typical Breakthrough Time
(minutes)
Butyl 0.7 120
Neoprene 0.61 120
Nitrile 0.8 120
Polyvinyl Chloride (PVC) 1.1 120
Viton Butyl 0.3 120
Respiratory Protection: No respiratory protection is normally required.
If material is heated and emits hydrogen sulfide, determine if airborne concentrations are below the
occupational exposure limit for hydrogen sulfide. If not, wear an approved positive pressure air-supplying
respirator. For more information on hydrogen sulfide, see Chevron SDS No. 301. If user operations
generate an oil mist, determine if airborne concentrations are below the occupational exposure limit for
mineral oil mist. If not, wear an approved respirator that provides adequate protection from the measured
concentrations of this material. For air-purifying respirators use a particulate cartridge.
Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not
provide adequate protection.
Occupational Exposure Limits:
Component Agency Form TWA STEL Ceiling Notation
Highly refined mineral oil
(C15 - C50) ACGIH -- 5 mg/m3 10 mg/m3 -- --
Highly refined mineral oil
(C15 - C50) OSHA Z-1 -- 5 mg/m3 -- -- --
Consult local authorities for appropriate values.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Attention: the data below are typical values and do not constitute a specification.
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Revision Number: 18
Revision Date: January 31, 2023 5 of 8 Delo Gear ESI SAE 80W-90, 85W-140
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Color: Brown to yellow
Physical State: Liquid
Odor: Petroleum odor
Odor Threshold: No data available
pH: Not Applicable
Vapor Pressure: No data available
Vapor Density (Air = 1): No data available
Initial Boiling Point: No data available
Solubility: Soluble in hydrocarbons; insoluble in water
Freezing Point: Not Applicable
Density: 0.8882 kg/l - 0.9013 kg/l @ 15°C (59°F) (Typical)
Viscosity: 13.70 mm2/s @ 100°C (212°F) (Minimum)
Evaporation Rate: No data available
Decomposition temperature: No data available
Octanol/Water Partition Coefficient: No data available
FLAMMABLE PROPERTIES:
Flammability (solid, gas): Not Applicable
Flashpoint: (Cleveland Open Cup) 180 °C (356 °F) (Minimum)
Autoignition: No data available
Flammability (Explosive) Limits (% by volume in air): Lower: Not Applicable Upper: Not
Applicable
SECTION 10 STABILITY AND REACTIVITY
Reactivity: May react with strong acids or strong oxidizing agents, such as chlorates, nitrates,
peroxides, etc.
Chemical Stability: This material is considered stable under normal ambient and anticipated storage
and handling conditions of temperature and pressure.
Incompatibility With Other Materials: Not applicable
Hazardous Decomposition Products: Hydrogen Sulfide (Elevated temperatures)
Hazardous Polymerization: Hazardous polymerization will not occur.
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
Serious Eye Damage/Irritation: The material is not considered an eye irritant. The product has not been
tested. The statement is based on evaluation of data for similar materials or product components.
Skin Corrosion/Irritation: The material is not considered a skin irritant. The product has not been tested.
The statement is based on evaluation of data for similar materials or product components.
Skin Sensitization: The material is not considered a skin sensitizer. The product has not been tested.
The statement is based on evaluation of data for similar materials or product components.
Acute Dermal Toxicity: The material is not considered a dermal toxicant. The product has not been
tested. The statement is based on evaluation of data for similar materials or product components.
Acute Oral Toxicity: The material is not considered an oral toxicant. The product has not been tested.
The statement is based on evaluation of data for similar materials or product components. Acute Inhalation Toxicity: The material is not considered an inhalation toxicant. The product has not
been tested. The statement is based on evaluation of data for similar materials or product components.
Acute Toxicity Estimate: Not Determined
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Revision Number: 18
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Germ Cell Mutagenicity: The material is not considered a mutagen. The product has not been tested.
The statement is based on evaluation of data for similar materials or product components.
Carcinogenicity: The material is not considered a carcinogen. The product has not been tested. The
statement is based on evaluation of data for similar materials or product components.
Reproductive Toxicity: The material is not considered a reproductive toxicant. The product has not been
tested. The statement is based on evaluation of data for similar materials or product components.
Specific Target Organ Toxicity - Single Exposure: The material is not considered a target organ
toxicant (single exposure). The product has not been tested. The statement is based on evaluation of
data for similar materials or product components.
Specific Target Organ Toxicity - Repeated Exposure: The material is not considered a target organ
toxicant (repeated exposure). The product has not been tested. The statement is based on evaluation of
data for similar materials or product components.
Aspiration Hazard: The material is not considered an aspiration hazard.
ADDITIONAL TOXICOLOGY INFORMATION:
This product contains petroleum base oils which may be refined by various processes including severe
solvent extraction, severe hydrocracking, or severe hydrotreating. None of the oils requires a cancer
warning under the OSHA Hazard Communication Standard (29 CFR 1910.1200). These oils have not
been listed in the National Toxicology Program (NTP) Annual Report nor have they been classified by the
International Agency for Research on Cancer (IARC) as; carcinogenic to humans (Group 1), probably
carcinogenic to humans (Group 2A), or possibly carcinogenic to humans (Group 2B).
These oils have not been classified by the American Conference of Governmental Industrial Hygienists
(ACGIH) as: confirmed human carcinogen (A1), suspected human carcinogen (A2), or confirmed animal
carcinogen with unknown relevance to humans (A3).
SECTION 12 ECOLOGICAL INFORMATION
ECOTOXICITY
This material is expected to be harmful to aquatic organisms and may cause long-term adverse effects in
the aquatic environment.
The product has not been tested. The statement has been derived from the properties of the individual
components.
MOBILITY
No data available.
PERSISTENCE AND DEGRADABILITY
This material is not expected to be readily biodegradable. The product has not been tested. The
statement has been derived from the properties of the individual components.
POTENTIAL TO BIOACCUMULATE
Bioconcentration Factor: No data available.
Octanol/Water Partition Coefficient: No data available
SECTION 13 DISPOSAL CONSIDERATIONS
Use material for its intended purpose or recycle if possible. Oil collection services are available for used
oil recycling or disposal. Place contaminated materials in containers and dispose of in a manner
consistent with applicable regulations. Contact your sales representative or local environmental or health
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authorities for approved disposal or recycling methods.
SECTION 14 TRANSPORT INFORMATION
The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate
Dangerous Goods Regulations, for additional description requirements (e.g., technical name) and mode-
specific or quantity-specific shipping requirements.
DOT Shipping Description: NOT REGULATED AS HAZARDOUS MATERIAL UNDER 49 CFR
IMO/IMDG Shipping Description: NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORT
UNDER THE IMDG CODE
ICAO/IATA Shipping Description: NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORT
UNDER ICAO
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code:
Not applicable
SECTION 15 REGULATORY INFORMATION
EPCRA 311/312 CATEGORIES: Not applicable
REGULATORY LISTS SEARCHED:
01-1=IARC Group 1 05=MA RTK
01-2A=IARC Group 2A 06=NJ RTK
01-2B=IARC Group 2B 07=PA RTK
02=NTP Carcinogen 08-1=TSCA 5(e)
03=EPCRA 313 08-2=TSCA 12(b)
04=CA Proposition 65
No components of this material were found on the regulatory lists above.
CHEMICAL INVENTORIES:
All components comply with the following chemical inventory requirements: AIIC (Australia), DSL
(Canada), ENCS (Japan), IECSC (China), NZIoC (New Zealand), TCSI (Taiwan), TSCA (United States).
One or more components is listed on ELINCS (European Union). All other components are listed or
exempted from listing on EINECS.
NEW JERSEY RTK CLASSIFICATION:
Under the New Jersey Right-to-Know Act L. 1983 Chapter 315 N.J.S.A. 34:5A-1 et. seq., the product is to
be identified as follows: PETROLEUM OIL (Gear oil)
SECTION 16 OTHER INFORMATION
NFPA RATINGS: Health: 2 Flammability: 1 Reactivity: 0
HMIS RATINGS: Health: 0 Flammability: 1 Reactivity: 0
(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index
recommendation, *- Chronic Effect Indicator). These values are obtained using the guidelines or
published evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint
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Revision Date: January 31, 2023 8 of 8 Delo Gear ESI SAE 80W-90, 85W-140
SDS : 6698
and Coating Association (for HMIS ratings).
REVISION STATEMENT: SECTION 03 - Composition information was modified.
SECTION 08 - Eye/Face Protection information was modified.
SECTION 08 - General Considerations information was modified.
SECTION 08 - Personal Protective Equipment List information was deleted.
SECTION 08 - Personal Protective Equipment information was added.
SECTION 08 - Skin Protection information was modified.
SECTION 15 - Chemical Inventories information was modified.
Revision Date: January 31, 2023
ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:
TLV - Threshold Limit Value TWA - Time Weighted Average
STEL - Short-term Exposure Limit PEL - Permissible Exposure Limit
GHS - Globally Harmonized System CAS - Chemical Abstract Service Number
ACGIH - American Conference of Governmental
Industrial Hygienists IMO/IMDG - International Maritime Dangerous Goods
Code
API - American Petroleum Institute SDS - Safety Data Sheet
HMIS - Hazardous Materials Information System NFPA - National Fire Protection Association (USA)
DOT - Department of Transportation (USA) NTP - National Toxicology Program (USA)
IARC - International Agency for Research on
Cancer OSHA - Occupational Safety and Health Administration
NCEL - New Chemical Exposure Limit EPA - Environmental Protection Agency
SCBA - Self-Contained Breathing Apparatus
Prepared according to the 29 CFR 1910.1200 (2012) by Chevron Technical Center, 6001 Bollinger
Canyon Road, San Ramon, CA 94583.
The above information is based on the data of which we are aware and is believed to be correct
as of the date hereof. Since this information may be applied under conditions beyond our control
and with which we may be unfamiliar and since data made available subsequent to the date
hereof may suggest modifications of the information, we do not assume any responsibility for the
results of its use. This information is furnished upon condition that the person receiving it shall
make his own determination of the suitability of the material for his particular purpose.
Appendix C
Spill Report Form
https://harthick.sharepoint.com/sites/masterfiles-1/shared documents/aaa-master
projects/direct uniform/o&m plan/appendix b - spill reporting form.docx
Spill Reporting Form
5324 E. Independence Boulevard
Charlotte, North Carolina
Name of Employee Responding to the Release:
Location of Spill: Date/Time of Spill:
Weather Conditions: Material Involved:
Amount Spilled: Rate of Spillage:
Duration:
Cause of Spill:
Description of Spill Direction and Response Activities:
Damages or Injuries:
Agencies/Companies Notified:
Environmental Media Effected (water, soil, etc.):
What Absorbent Materials Were Used (replenish, if necessary):
Waste Generated and Disposal Method:
Actions Taken to Prevent Future Spills: