24025_Crayton Printing Final Grade Soil Assessment_20240610

Via Email
June 10, 2024

NCDEQ – Division of Waste Management
Brownfields Redevelopment Section
1646 Mail Service Center
Raleigh, North Carolina 27699-1646

Attn: Mr. Bill Schmithorst

Re: Final Grade Soil Assessment Report
Crayton Printing
Distribution Street and Dunavant Street
Charlotte, North Carolina
Brownfields Project No. 24025-20-060
H&H Project No. AKR-005

Dear Bill:

On behalf of KA D&D Holdings LLC, enclosed please find a copy of the Final Grade Soil
Assessment Report prepared for the Crayton Printing Brownfields property (Brownfields Project
No. 24025-20-060) located in Charlotte, Mecklenburg County. Should you have questions or
need additional information, please do not hesitate to contact us.

Sincerely,
Hart & Hickman, PC
Haley Martin, PG Matt Bramblett, PE
Project Manager Principal

Attachments

cc: Mr. Dan Coith, Akridge (via email)
Mr. Dan Outen, Akridge (via email)
Ms. Laura Truesdale, Moore & Van Allen, PLLC (via email)
Ms. Mary Katherine Stukes, Moore & Van Allen, PLLC (via email)

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Final Grade Soil Assessment Report Distribution Street and Dunavant Street
Charlotte, North Carolina Brownfields Project No. 24025-20-060 H&H Job No. AKR-005
Table of Contents

1.0 Introduction ............................................................................................................................ 1
2.0 Final Grade Soil Assessment Activities ................................................................................ 3
2.1 Final Grade Soil Sampling Activities ................................................................................... 3
2.2 Final Grade Soil Sample Results .......................................................................................... 5
2.3 Soil Direct Exposure Risk Evaluation .................................................................................. 6
3.0 Summary and Conclusions ................................................................................................... 8
List of Tables

Table 1 Summary of Final Grade Soil Sampling Lithology
Table 2 Summary of Final Grade Soil Sample Analytical Results
List of Figures
Figure 1 Site Location Map
Figure 2 Site Map
Figure 3 Final Grade Soil Sample Location Map
List of Appendices
Appendix A Laboratory Analytical Report
Appendix B DEQ Risk Calculator
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Final Grade Soil Assessment Report Crayton Printing
Distribution Street and Dunavant Street Charlotte, North Carolina Brownfields Project No. 24025-20-060 H&H Job No. AKR-005
1.0 Introduction

On behalf of KA D&D Holdings LLC (Prospective Developer or PD), Hart & Hickman, P.C.
(H&H) has prepared this Final Grade Soil Assessment Report for the Crayton Printing Brownfields
property (Brownfields Project No. 24025-20-060) located south of the Distribution Street and
Dunavant Street intersection in Charlotte, Mecklenburg County, North Carolina (Site). The Site
consists of one approximate 2.85-acre parcel of land (Mecklenburg County Parcel Identification
No. 12104201) located in a mixed commercial and residential use area of South End Charlotte. A
Site location map is provided as Figure 1, and the Site and surrounding area are shown in Figure 2.

Redevelopment of the Site has included construction of a multifamily residential apartment
building and an associated parking deck known as Hawkins Press. An overlay of the Hawkins
Press redevelopment layout is shown in Figure 2. Redevelopment activities at the Site are nearing
completion and have been completed in general accordance with the North Carolina Department
of Environmental Quality (DEQ) approved Environmental Management Plan (EMP) dated
November 3, 2020.

A Brownfields Agreement between the DEQ and the PD was recorded on October 1, 2021. Land
Use Restriction (LUR) 12.f. of the Brownfields Agreement and the DEQ-approved EMP generally
state that no occupancy of the Brownfields property may occur after redevelopment until
representative final grade soil samples have been collected in areas at the Site that are not covered
by building foundations, sidewalks, or asphalt or concrete parking areas and driveways
(hardscape).

In accordance with the DEQ-approved EMP and LUR 12.f. of the recorded Brownfields
Agreement, H&H prepared a Final Grade Soil Assessment Work Plan (Work Plan) dated
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September 26, 2023 for DEQ review and approval. The Work Plan was approved by DEQ in a
letter dated November 20, 2023. A summary of the final grade sampling activities is provided in
the following sections.

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2.0 Final Grade Soil Assessment Activities
Final grade soil sampling activities were conducted at the Site in May 2024 to evaluate potential
soil direct exposure risks within areas at the Site that will not be covered with hardscape upon
completion of redevelopment activities. The final grade soil sampling activities were conducted
in general accordance with the DEQ Inactive Hazardous Sites Branch (IHSB) Guidelines for
Assessment and Cleanup of Contaminated Sites (Guidelines) dated September 2023, the most
recent versions of the U.S. Environmental Protection Agency (EPA) Region IV Laboratory
Services and Applied Science Division (LSASD) Field Branches Quality System and Technical
Procedures guidance, and the DEQ-approved Work Plan.

2.1 Final Grade Soil Sampling Activities

The Site is covered with hardscape surfaces except for generally isolated or narrow landscaped
areas. To evaluate for the potential presence of shallow soil impacts, landscaped areas were
divided into four evaluation areas (FG-1 through FG-4). Five shallow soil borings were advanced
in each area for collection of aliquot soil samples. The four final grade evaluation areas and aliquot
soil boring locations (designated as “A” through “E” within each evaluation area) are shown in
Figure 3 and are described further below:

• Final grade evaluation area FG-1 includes landscaped areas in the western portion of the
Site along Distribution Street;
• Final grade evaluation area FG-2 includes landscaped areas in the southern portion of the
Site and within the courtyard area located in the central portion of the Site;
• Final grade evaluation area FG-3 includes landscaped areas in the eastern portion of the
Site along Dunavant Street; and
• Final grade evaluation area FG-4 includes landscaped areas in the northern portion of the
Site along Dunavant Street.

Each aliquot soil boring was advanced from the surface to approximately two (2) feet below the
ground surface (ft bgs) utilizing a decontaminated stainless steel hand auger. Continuous soil
samples were collected from the center of the hand auger bucket at each boring location. The soil
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samples were described for lithologic purposes, observed for obvious evidence of staining and
unusual odors, and field screened for the presence of volatile organic vapors using a calibrated
photoionization detector (PID). Soil lithology generally consisted of moist silt with clay, sand,
and some gravel. Field screening results did not identify obvious evidence of potential impacts
(i.e., staining, unusual odors, etc.) in soil samples collected at the Site. Lithologic descriptions and
field screening results for each final grade aliquot boring are summarized in Table 1.

Soil sample aliquots from each evaluation area were combined and homogenized to form one
composite soil sample representative of shallow soil in that evaluation area. Composite soil
samples selected for laboratory analysis were collected directly into dedicated laboratory supplied
sample containers, labeled with the sample identification, date, and requested analyses, and placed
in a laboratory supplied cooler with ice. The samples were delivered to Waypoint Analytical
(Waypoint) under standard chain of custody protocols for analysis of semi-volatile organic
compounds (SVOCs) by EPA Method 8270 and Resource Conservation and Recovery Act
(RCRA) metals plus hexavalent chromium by EPA Methods 6020/7471/7199.

In addition to the composite soil samples described above, one representative grab soil sample was
collected from each evaluation area from undisturbed portions of soil in the hand auger bucket.
The grab soil samples were collected from a 1 ft interval (either 0 to 1 ft or 1 to 2 ft) depending on
the depth of the higher PID reading. The grab soil samples were placed directly into laboratory
supplied glassware, labeled, and placed in the laboratory supplied sample cooler with ice. The
grab soil samples were submitted to Waypoint for analysis of volatile organic compounds (VOCs)
by EPA Method 8260.

For quality assurance and quality control purposes, H&H collected one duplicate soil sample (FG-
DUP) from evaluation area FG-4. Duplicate sample laboratory analytical results are presented in
Table 2. Review of the duplicate sample results in comparison to the parent sample results indicate
a discrepancy greater than 10% for select compounds which is likely associated with sample matrix
variability.

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Following sampling activities, the soil borings were abandoned, and the surfaces were repaired
similar to pre-drilling conditions. Additionally, the soil boring locations were estimated using a
hand-held global positioning system (GPS) unit.

2.2 Final Grade Soil Sample Results

A tabular summary of the final grade soil sample analytical results is presented in Table 2, and
copies of the laboratory analytical report and chain of custody record are provided in Appendix A.
The laboratory analytical results were compared to the DEQ Residential and
Industrial/Commercial Preliminary Soil Remediation Goals (PSRGs) dated February 2024. In
addition to the PSRGs, metals results were compared to area-specific and published concentrations
for naturally occurring metals in North Carolina soil.

VOCs
Laboratory analytical results indicate that trace levels of acetone (up to 0.021 J milligrams per
kilogram [mg/kg]), carbon disulfide (up to 0.002 J mg/kg), n-hexane (up to 0.001 J mg/kg), and/or
methylene chloride (up to 0.005 J mg/kg) were detected at concentrations above the laboratory
method detection limits, but below the DEQ Residential PSRGs in select final grade soil samples.
Note that the J-flag indicates the compound was detected at a concentration above the laboratory
method detection limits, but below the laboratory reporting limits resulting in a laboratory
estimated concentrations. No other VOCs were detected at concentrations above the laboratory
method detection limits, and no VOCs were detected at concentrations above the DEQ Residential
PSRGs in final grade soil samples collected at the Site.

SVOCs
Laboratory analytical results indicate that polynuclear aromatic hydrocarbons (PAH) were
detected at concentrations above the laboratory method detection limits in final grade soil samples
except FG-2. The PAHs benzo(a)anthracene (1.34 mg/kg), benzo(a)pyrene (1.11 mg/kg), and
benzo(b)fluoranthene (1.41 mg/kg) were detected at concentrations above their respective DEQ
Residential PSRGs in the final grade soil sample collected along Distribution Street (FG-1). The
PAH benzo(a)pyrene (up to 0.490 J mg/kg) was also detected at concentrations above the DEQ
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Residential PSRG in samples collected along Dunavant Street (FG-3 and FG-DUP). No other
SVOCs were detected at concentrations above the DEQ Residential PSRGs in the final grade soil
samples collected at the Site.

Metals
Several metals including arsenic (up to 1.21 mg/kg), barium (up to 101 mg/kg), trivalent chromium
(up to 45.7 mg/kg), hexavalent chromium (up to 0.477 mg/kg), lead (up to 10.5 mg/kg), mercury
(up to 0.0173 J mg/kg), and selenium (up to 0.216 J mg/kg) were detected at concentrations
consistent with naturally occurring levels. The metal concentrations are considered to be
representative of background conditions at the Site and in the Site area.

2.3 Soil Direct Exposure Risk Evaluation

The DEQ PSRGs are conservative and based upon a Target Cancer Risk (TCR) of 1 x 10-6 for
potential carcinogenic effects and a Hazard Quotient (HQ) of 0.2 for potential non-carcinogenic
effects. DEQ and EPA acceptable soil direct exposure risks include a calculated cumulative
lifetime incremental carcinogenic risk (LICR) of 1 x 10-4 or less and a calculated cumulative hazard
index (HI) of 1.0 or less for potential non-carcinogenic risks.

H&H utilized the DEQ Risk Calculator (February 2024) under a residential land use scenario to
further evaluate potential cumulative risks for the soil direct exposure pathway. To model the
potential risks under a hypothetical “worst-case” scenario, H&H conservatively calculated the
cumulative risks using the highest concentration of any compound detected in any final grade soil
sample collected at the Site. Risk calculator results are summarized in the table below, and a copy
of the completed risk calculator is provided in Appendix B.

Evaluation Area Land Use Calculated Cumulative LICR Calculated Cumulative HI Acceptable Risk
Cumulative Worst Case Residential 1.8 x 10-5

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As shown in the table above, the results of the risk calculations indicate that the calculated
cumulative soil direct exposure risks do not exceed acceptable carcinogenic or noncarcinogenic
risk levels under a residential use scenario.

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3.0 Summary and Conclusions

H&H has completed final grade soil sampling activities at the Crayton Printing Brownfields
property (Brownfields Project No. 24025-20-060) located south of the Distribution Street and
Dunavant Street intersection in Charlotte, North Carolina. The final grade soil sampling activities
were conducted in general accordance with the DEQ Brownfields approved Work Plan dated
September 26, 2023. Final grade soil sampling activities included the collection of soil samples
to evaluate potential soil direct exposure risks in areas at the Site that will not be covered by
impervious surfaces following completion of redevelopment.

The Site was divided into four final grade evaluation areas and shallow soil samples were collected
for laboratory analysis within each area. Final grade soil sample laboratory analytical results
indicate that several organic compounds were detected at concentrations above the laboratory
method detection limits in each final grade evaluation area. No compounds were detected at
concentrations above the DEQ Residential PSRGs except for benzo(a)anthracene, benzo(a)pyrene,
and benzo(b)fluoranthene in select final grade evaluation areas located along Distribution Street
and Dunavant Street. Metals concentrations detected in the final grade soil samples are consistent
with published and area-specific background concentrations. Therefore, the metal concentrations
are considered to be representative of naturally occurring levels.

H&H utilized the most recent version of the DEQ Risk Calculator to further evaluate potential soil
direct exposure risks for a residential occupant. Hypothetical worst-case risk calculations were
completed for the Site using the highest concentration of any compound detected in any final grade
evaluation area. Results of the residential soil direct exposure risk calculations indicate that
cumulative risks are within acceptable levels for residential occupancy. Based on the data and
associated risk calculations, H&H recommends DEQ approval of this final grade soil assessment
report for residential occupancy of the Site.

Tables

Table 1
Summary of Final Grade Soil Sampling Lithology
Crayton Printing
Distribution Street and Dunavant Street
Charlotte, North Carolina
H&H Job No. AKR-005
Final Grade
Evaluation Area
Composite
Aliquot Sample Date Depth (ft bgs)PID Readings
(ppm)Moisture Content Stiffness Color Lithology Notes
0-1 1.9 Moist Very Firm Brown/Gray Gravel, some sand Heavy gravel component
1-2 28.6 Moist Very Firm Brown/Gray Gravel, some sand Heavy gravel component
0-1 27.4 Moist Firm Brown/Red Clayey Silt, Some Sand, Little Gravel -
1-2 62.4 * Moist Firm Gray, little Brown Clayey Silt, Some Sand, Little Gravel -
0-1 16.5 Moist Soft Brown/Gray Clayey silt, Some Sand, Little Gravel -
1-2 20.1 Moist Soft Brown/Gray Clayey silt, Some Sand, Little Gravel -
0-1 15.7 Moist Medium Stiff Gray/Brown Clayey silt, Some Sand, Trace Gravel -
1-2 33.6 Moist Medium Stiff Gray/Brown Clayey silt, Some Sand, Trace Gravel -
0-1 43.8 Moist Stiff Red/Brown Clayey silt, Some Sand, Trace Gravel -
1-2 41.2 Moist Stiff Red/Brown Clayey silt, Some Sand, Trace Gravel -
0-1 2.4 Moist Loose Brown Sand, Some Clayey Silt, Trace Gravel -
1-2 11.2 Moist Loose Brown Sand, Some Clayey Silt, Trace Gravel -
0-1 22.8 Moist Loose Light Brown Sand, Some Clayey Silt, Some Gravel -
1-2 20.8 Moist Loose Light Brown Sand, Some Clayey Silt, Some Gravel -
0-1 10.7 Moist Loose Dark Brown Clayey Silt, Some Sand, Trace Gravel -
1-2 23.2 Moist Loose Light Brown Clayey Silt, Some Sand, Trace Gravel -
0-1 21.7 Moist Loose Light Brown Clayey Silt, Some Sand, Trace Gravel -
1-2 23.7 * Moist Loose Light Brown Clayey Silt, Some Sand, Trace Gravel -
0-1 21.5 Dry Loose Red/Brown Sand, Some Clayey Silt, Trace Gravel -
1-2 16.4 Dry Medium Stiff Red/Brown Clayey Silt, Some Sand, Trace Gravel Trace Organics
0-1 40.1 Moist Loose Brown/Red Sand, Little Clayey Silt, Trace Gravel -
1-2 52.1 Moist Loose Brown/Red Sand, Little Clayey Silt, Trace Gravel -
0-1 54.2 Moist Dense Brown Sand, Little Clayey Silt, Trace Gravel -
1-2 58.2 Moist Dense Brown Sand, Little Clayey Silt, Trace Gravel -
0-1 23.1 Moist Loose Brown Sand, Little Clayey Silt, Trace Gravel -
1-2 17.7 Moist Loose Brown Sand, Little Clayey Silt, Trace Gravel -
0-1 23.1 Moist Loose Red/Brown Sand, Little Clayey Silt, Trace Gravel -
1-2 82.1 * Moist Loose Red/Brown Sand, Little Clayey Silt, Trace Gravel -
0-1 67.2 Moist Loose Red/Brown Sand, Trace Gravel -
1-2 77.6 Moist Loose Red/Brown Sand, Some Gravel -
0-1 3.5 Moist Very Stiff Brown Sand, Some Gravel, Few Clayey Silt -
1-2 21.2 Moist Very Stiff Brown Sand, Some Gravel, Few Clayey Silt -
0-1 34.9 Moist Very Stiff Brown Sand, Some Gravel, Few Clayey Silt -
1-2 31.9 * Moist Loose Brown/Red/Gray Clayey Silt, Some sand, Trace Gravel -
0-1 32.9 Moist Very Stiff Gray Sand, Some Gravel -
1-2 19.0 Moist Very Stiff Gray Sand, Some Gravel -
0-1 16.8 Moist Soft Red/Brown Clayey Silt, Trace Sand, Few Gravel -
1-2 24.5 Moist Soft Red/Brown Clayey Silt, Trace Sand, Few Gravel -
0-1 24.5 Moist Very Stiff Red/Brown Sand, Few Clayey Silt, Some Gravel -
1-2 16.7 Moist Very Stiff Red/Brown Mostly Gravel, Little Sand, Little Clayey Silt -
Notes:
Background photoionization detector (PID) readings ranged from 0.0 to 0.1 parts per million (ppm).
Duplicate sample (FG-DUP) collected from final grade evaluation area FG-4.
* = grab sample selected for laboratory analysis of volatile organic compounds
FG-4
FG-3
FG-2
FG-1
A
B
05/01/2024
E
C
D
A
B
05/01/2024C
D
C
E
A
E
05/01/2024
05/01/2024
C
D
A
B
D
E
B
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Table 1 (Page 1 of 1)
Hart & Hickman, PC
Table 2
Summary of Final Grade Soil Sample Analytical Results
Crayton Printing
Distribution Street and Dunavant Street
Charlotte, North Carolina
H&H Project No. AKR-005
Evaluation Area
Sample ID
Date
Depth (ft bgs)1-2 0-2 1-2 0-2 1-2 0-2 1-2 0-2 1-2 0-2
Sample Type Grab Composite Grab Composite Grab Composite Grab Composite Grab Composite
Units
VOCs (8260D)
Acetone 0.006 J NA 0.021 J NA 0.008 J NA 0.010 J NA 0.013 J NA 14,000 210,000 -- --
Carbon Disulfide <0.0007 NA <0.0008 NA 0.0010 J NA <0.0007 NA 0.002 J NA 160 740 -- --
n-Hexane <0.0007 NA 0.001 J NA <0.0008 NA <0.0008 NA <0.0008 NA 130 540 -- --
Methylene Chloride 0.004 J NA 0.004 J NA 0.004 J NA 0.002 J NA 0.005 J NA 58 650 -- --
SVOCs (8270E)
Acenaphthene NA 0.246 J NA <0.175 NA <0.168 NA <0.168 NA <0.171 290 1,200 -- --
Anthracene NA 0.622 J NA <0.198 NA <0.190 NA <0.190 NA <0.194 3,600 45,000 -- --
Benzo(a)anthracene NA 1.34 NA <0.186 NA 0.476 J NA 0.194 J NA 0.276 J 1.1 210 -- --
Benzo(a)pyrene NA 1.11 NA <0.197 NA 0.490 J NA <0.189 NA 0.249 J 0.11 2.1 -- --
Benzo(b)fluoranthene NA 1.41 NA <0.175 NA 0.761 NA 0.282 J NA 0.424 J 1.1 21 -- --
Benzo(g,h,i)perylene NA 0.477 J NA <0.172 NA 0.276 J NA <0.164 NA <0.168 NE NE -- --
Benzo(k)fluoranthene NA 0.386 J NA <0.186 NA <0.178 NA <0.178 NA <0.182 11 210 -- --
Bis(2-ethylhexyl)phthalate NA 0.231 J NA <0.211 NA <0.202 NA <0.202 NA <0.207 39 160 -- --
Chrysene NA 0.962 NA <0.174 NA 0.396 J NA <0.167 NA 0.205 J 110 2,100 -- --
Dibenz(a,h)anthracene NA 0.240 J,M NA <0.132 NA 0.254 J,M NA 0.237 J,M NA <0.129 11 2.1 -- --
Fluoranthene NA 2.50 NA <0.188 NA 0.923 NA 0.408 J NA 0.474 J 480 6,000 -- --
Fluorene NA 0.240 J NA <0.182 NA <0.175 NA <0.175 NA <0.178 480 6,000 -- --
Indeno(1,2,3-cd)pyrene NA 0.747 NA <0.180 NA 0.395 J NA <0.172 NA <0.176 1.1 21 -- --
Phenanthrene NA 1.77 NA <0.188 NA 0.576 J NA 0.265 J NA 0.339 J NE NE -- --
Pyrene NA 1.63 NA <0.191 NA 0.636 J NA 0.273 J NA 0.353 J 360 4,500 -- --
Metals (6020B/7471B/7199)
Arsenic NA 0.895 NA 1.21 NA 0.707 NA 1.06 NA 1.11 0.68 3.0 1.39 - 7.23 1.0 - 18
Barium NA 101 NA 98.2 NA 92.2 NA 71.9 NA 71.2 3,100 47,000 44.5 - 126 50 - 1,000
Cadmium NA <0.266 NA <0.299 NA <0.286 NA <0.286 NA <0.292 1.4 20 ND - 10.2 1.0 - 10
Chromium (total)NA 36.2 NA 43.1 NA 46.0 NA 36.0 NA 31.3 NE NE 22.1 - 67.8 7.0 - 300
Trivalent Chromium NA 36.0 NA 42.8 NA 45.7 NA 35.5 NA 31.0 23,000 350,000 22.1 - 67.8 NS
Hexavalent Chromium NA 0.249 NA 0.291 NA 0.320 NA 0.477 NA 0.339 0.31 6.5 ND - 0.715 NS
Lead NA 4.08 NA 7.30 NA 4.75 NA 10.5 NA 7.32 200 800 9.13 - 236 ND - 50
Mercury NA 0.0133 J NA 0.0173 J NA 0.0142 J NA <0.0137 NA 0.0146 J 4.7 70 0.0462 - 0.117 0.03 - 0.52
Selenium NA 0.216 J NA 0.156 J NA 0.117 J NA 0.140 J NA 0.176 J 78 1,200 ND - 1.34 <0.1 - 0.8
Silver NA <0.266 NA <0.299 NA <0.286 NA <0.286 NA <0.292 78 1,200 ND - 3.10 ND - 5.0
DEQ Cumulative Risk Calculator (4)
Cumulative LICR (Residential)
Cumulative Non-Carcinogenic HI (Residential)
Notes:
1) North Carolina Department of Environmental Quality (DEQ) Preliminary Soil Remediation Goals (PSRGs) dated February 2024.
2) Range values of area-specific background metals obtained from Phase II Environmental Site Assessment dated November 13, 2020 prepared for the Gas Fire Products Assembly Warehouse Brownfields property.
3) Range values of background metals for North Carolina soils taken from Elements in North American Soils by Dragun and Chekiri, 2005. Cd and Ag concentrations were taken from Southeastern & Conterminous US soils.
4) DEQ Cumulative Risk Calculator dated February 2024.
Concentrations are reported in milligrams per kilogram (mg/kg).
Concentrations are reported to the laboratory method detection limits.
Laboratory analytical methods are shown in parentheses.
With the exception of metals, only those compounds detected in at least one sample are shown in the table above.
Bold values exceed the Residential PSRGs.
VOCs = volatile organic compounds; SVOCs = semi-volatile organic compounds; ft bgs= feet below ground surface; NS = not specified; NE = not established; -- = not applicable; ND = not detected; NA = not analyzed; LICR = lifetime incremental cancer risk; HI = hazard inde
J = Compound was detected above the laboratory method detection limit but below the laboratory reporting limit, resulting in a laboratory estimated concentration.
M = Laboratory estimated minimal concentration.
Final Grade Screening Criteria Background Metals
FG-3
Residential
PSRGs (1)
Industrial/
Commercial
PSRGs (1)
Area Specific
Range (2)
1.8 x 10-5 <1 x 10-4
0.11 <1.0
FG-1
5/1/2024 5/1/2024
FG-2
5/1/2024 Published
Range (3)
5/1/2024 5/1/2024
mg/kg
Acceptable Risk Levels
FG-4 / FG-DUP
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5/21/2024
Table 2 (Page 1 of 1)
Hart & Hickman, PC

Figures

REVISION NO. 0
JOB NO. AKR-005
DATE: 5-14-24
FIGURE NO. 2
CRAYTON PRINTING
DISTRIBUTION STREET AND DUNAVANT STREET
CHARLOTTE, NORTH CAROLINA
SITE MAP
LEGEND
BROWNFIELDS PROPERTY BOUNDARY
PARCEL BOUNDARY
BUILDING FOOTPRINT - LEVEL 1
BUILDING FOOTPRINT - LEVEL 2
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
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PARKING DECK
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LEGEND
1.AERIAL IMAGERY OBTAINED FROM MECKLENBURG COUNTY
GIS 2024.
2.BUILDING OVERLAY BASED ON REQUIRED PLANTING PLAN
PREPARED BY LANDDESIGN AND DATED 8/17/21.
HUB SOUTH END APARTMENTS
(2250 HAWKINS STREET)
MULTI-TENANT
COMMERCIAL BUILDING
(2326 DISTRIBUTION STREET)
MULTI-TENANT
COMMERCIAL BUILDING
(2401 DISTRIBUTION STREET)
VACANT COMMERCIAL BUILDING
(2322 DUNAVANT STREET)
JUNCTION 1504
LUXURY APARTMENTS
(1504 MAINLINE BOULEVARD)
MERV PLACE
UNDER
CONSTRUCTION
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REVISION NO. 0
JOB NO. AKR-005
DATE: 5-14-24
FIGURE NO. 3
CRAYTON PRINTING
DISTRIBUTION STREET AND DUNAVANT STREET
CHARLOTTE, NORTH CAROLINA
FINAL GRADE SOIL SAMPLE LOCATION MAP
LEGEND
BROWNFIELDS PROPERTY BOUNDARY
PARCEL BOUNDARY
BUILDING FOOTPRINT - LEVEL 1
BUILDING FOOTPRINT - LEVEL 2
LANDSCAPED AREA
PAVED AREA
FG-1 SOIL SAMPLE LOCATION
FG-2 SOIL ALIQUOT SAMPLE LOCATION
FG-3 SOIL ALIQUOT SAMPLE LOCATION
FG-4 SOIL ALIQUOT SAMPLE LOCATION
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
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PARKING DECK
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LEGEND
1. DEVELOPMENT PLANS PROVIDED BY BB+M, DATED 2-19-2020.
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Appendix A
Laboratory Analytical Report

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

5/10/2024
Hart & Hickman (Charlotte) Haley Martin
2923 South Tryon St. Ste 100 Charlotte, NC, 28203
Ref: Analytical Testing
Lab Report Number: 24-123-0002 Client Project Description: AKR-005
Dear Haley Martin:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 5/1/2024 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely,
Angela D Overcash Senior Project Manager
Page 1 of 71
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202437735State ProgramNorth Carolina
12/31/2024402State ProgramNorth Carolina
07/31/202499012State ProgramSouth Carolina
12/31/202499012State ProgramSouth Carolina
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State Program Lab ID Expiration Date
02/28/202540750State ProgramAlabama
02/07/202588-0650State ProgramArkansas
06/30/20242904State ProgramCalifornia
06/30/2024E871157State Program - NELAPFlorida
11/14/2025C044State ProgramGeorgia
06/30/202404015State ProgramGeorgia
10/31/2024200078State Program - NELAPIllinois
06/30/202480215State ProgramKentucky
12/31/2024KY90047State ProgramKentucky
12/31/2024LA037State Program - NELAPLouisiana
06/30/202404015State Program - NELAPLouisiana
11/14/2025MSState ProgramMississippi
07/31/202447701State ProgramNorth Carolina
12/31/2024415State ProgramNorth Carolina
05/31/202468-03195State Program - NELAPPennsylvania
06/30/202484002State ProgramSouth Carolina
11/14/202502027State ProgramTennessee
09/30/2024T104704180State Program - NELAPTexas
06/30/202400106State ProgramVirginia
09/14/2024460181State Program - NELAPVirginia
Page 1 of 1 00016/24-123-0002
Page 2 of 71
Report Number:
Sample Summary Table
Client Project Description:
24-123-0002
AKR-005
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
05/01/2024 11:55Solids 92436 FG-1 05/01/2024 17:22
05/01/2024 11:55Solids 92436 FG-1 05/01/2024 17:22 6020B
05/01/2024 11:55Solids 92436 FG-1 05/01/2024 17:22 SW-7199
05/01/2024 16:10Solids 92437 FG-2 05/01/2024 17:22
05/01/2024 16:10Solids 92437 FG-2 05/01/2024 17:22 SW-7199
05/01/2024 16:10Solids 92437 FG-2 05/01/2024 17:22 6020B
05/01/2024 15:10Solids 92438 FG-3 05/01/2024 17:22
05/01/2024 15:10Solids 92438 FG-3 05/01/2024 17:22 SW-7199
05/01/2024 15:10Solids 92438 FG-3 05/01/2024 17:22 6020B
05/01/2024 13:15Solids 92439 FG-4 05/01/2024 17:22
05/01/2024 13:15Solids 92439 FG-4 05/01/2024 17:22 SW-7199
05/01/2024 13:15Solids 92439 FG-4 05/01/2024 17:22 6020B
05/01/2024Solids 92440 FG-DUP 05/01/2024 17:22
05/01/2024Solids 92440 FG-DUP 05/01/2024 17:22 SW-7199
05/01/2024Solids 92440 FG-DUP 05/01/2024 17:22 6020B
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 3 of 71
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
24-123-0002
Report Limit
Project:AKR-005
V 92436FG-1
0.895 05/09/2024 21:336020BArsenicmg/Kg - dry 0.0909
101 05/08/2024 15:056020BBariummg/Kg - dry 0.045
36.2 05/08/2024 15:056020BChromiummg/Kg - dry 0.123
4.08 05/08/2024 15:056020BLeadmg/Kg - dry 0.0329
J0.216 05/08/2024 15:056020BSeleniummg/Kg - dry 0.109
J0.0133 05/06/2024 14:517471BMercury (Total)mg/Kg - dry 0.0128
J0.006 05/03/2024 11:118260DAcetonemg/Kg - dry 0.002
J0.004 05/03/2024 11:118260DMethylene Chloride mg/Kg - dry 0.001
J0.246 05/07/2024 23:178270EAcenaphthenemg/Kg - dry 0.156
J0.622 05/07/2024 23:178270EAnthracenemg/Kg - dry 0.176
1.34 05/07/2024 23:178270EBenzo(a)anthracene mg/Kg - dry 0.165
1.11 05/07/2024 23:178270EBenzo(a)pyrene mg/Kg - dry 0.175
1.41 05/07/2024 23:178270EBenzo(b)fluoranthene mg/Kg - dry 0.156
J0.477 05/07/2024 23:178270EBenzo(g,h,i)perylene mg/Kg - dry 0.153
J0.386 05/07/2024 23:178270EBenzo(k)fluoranthene mg/Kg - dry 0.165
J0.231 05/07/2024 23:178270EBis(2-ethylhexyl)phthalate mg/Kg - dry 0.188
0.962 05/07/2024 23:178270EChrysenemg/Kg - dry 0.155
JM0.240 05/07/2024 23:178270EDibenz(a,h)anthracene mg/Kg - dry 0.118
2.50 05/07/2024 23:178270EFluoranthenemg/Kg - dry 0.168
J0.240 05/07/2024 23:178270EFluorenemg/Kg - dry 0.162
0.747 05/07/2024 23:178270EIndeno(1,2,3-cd)pyrene mg/Kg - dry 0.160
1.77 05/07/2024 23:178270EPhenanthrenemg/Kg - dry 0.168
1.63 05/07/2024 23:178270EPyrenemg/Kg - dry 0.170
0.249 05/08/2024 20:06SW-7199 Chromium, Hexavalent mg/Kg - dry 0.149
5.97 05/03/2024 12:41SW-DRYWT Moisture %
V 92437FG-2
1.21 05/09/2024 21:486020BArsenicmg/Kg - dry 0.102
98.2 05/08/2024 15:106020BBariummg/Kg - dry 0.051
43.1 05/08/2024 15:106020BChromiummg/Kg - dry 0.138
7.30 05/08/2024 15:106020BLeadmg/Kg - dry 0.0370
J0.156 05/08/2024 15:106020BSeleniummg/Kg - dry 0.123
J0.0173 05/06/2024 14:537471BMercury (Total)mg/Kg - dry 0.0143
J0.021 05/03/2024 11:388260DAcetonemg/Kg - dry 0.002
J0.001 05/03/2024 11:388260Dn-Hexane mg/Kg - dry 0.0008
J0.004 05/03/2024 11:388260DMethylene Chloride mg/Kg - dry 0.001
0.291 05/08/2024 20:50SW-7199 Chromium, Hexavalent mg/Kg - dry 0.168
Page 4 of 71
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
24-123-0002
Report Limit
Project:AKR-005
V 92437FG-2
16.3 05/03/2024 12:41SW-DRYWT Moisture %
V 92438FG-3
0.707 05/09/2024 21:546020BArsenicmg/Kg - dry 0.0979
92.2 05/08/2024 15:166020BBariummg/Kg - dry 0.049
46.0 05/08/2024 15:166020BChromiummg/Kg - dry 0.132
4.75 05/08/2024 15:166020BLeadmg/Kg - dry 0.0355
J0.117 05/08/2024 15:166020BSeleniummg/Kg - dry 0.117
J0.0142 05/06/2024 14:567471BMercury (Total)mg/Kg - dry 0.0137
J0.008 05/03/2024 12:058260DAcetonemg/Kg - dry 0.002
J0.0010 05/03/2024 12:058260DCarbon Disulfide mg/Kg - dry 0.0007
J0.004 05/03/2024 12:058260DMethylene Chloride mg/Kg - dry 0.001
J0.476 05/08/2024 00:068270EBenzo(a)anthracene mg/Kg - dry 0.178
J0.490 05/08/2024 00:068270EBenzo(a)pyrene mg/Kg - dry 0.189
0.761 05/08/2024 00:068270EBenzo(b)fluoranthene mg/Kg - dry 0.168
J0.276 05/08/2024 00:068270EBenzo(g,h,i)perylene mg/Kg - dry 0.164
J0.396 05/08/2024 00:068270EChrysenemg/Kg - dry 0.167
JM0.254 05/08/2024 00:068270EDibenz(a,h)anthracene mg/Kg - dry 0.127
0.923 05/08/2024 00:068270EFluoranthenemg/Kg - dry 0.180
J0.395 05/08/2024 00:068270EIndeno(1,2,3-cd)pyrene mg/Kg - dry 0.172
J0.576 05/08/2024 00:068270EPhenanthrenemg/Kg - dry 0.180
J0.636 05/08/2024 00:068270EPyrenemg/Kg - dry 0.183
0.320 05/08/2024 21:01SW-7199 Chromium, Hexavalent mg/Kg - dry 0.161
12.7 05/03/2024 12:41SW-DRYWT Moisture %
V 92439FG-4
1.06 05/09/2024 21:596020BArsenicmg/Kg - dry 0.0979
71.9 05/08/2024 15:256020BBariummg/Kg - dry 0.049
36.0 05/08/2024 15:256020BChromiummg/Kg - dry 0.132
10.5 05/08/2024 15:256020BLeadmg/Kg - dry 0.0355
J0.140 05/08/2024 15:256020BSeleniummg/Kg - dry 0.117
J0.010 05/03/2024 12:328260DAcetonemg/Kg - dry 0.002
J0.002 05/03/2024 12:328260DMethylene Chloride mg/Kg - dry 0.001
J0.194 05/08/2024 00:318270EBenzo(a)anthracene mg/Kg - dry 0.178
J0.282 05/08/2024 00:318270EBenzo(b)fluoranthene mg/Kg - dry 0.168
JM0.237 05/08/2024 00:318270EDibenz(a,h)anthracene mg/Kg - dry 0.127
J0.408 05/08/2024 00:318270EFluoranthenemg/Kg - dry 0.180
J0.265 05/08/2024 00:318270EPhenanthrenemg/Kg - dry 0.180
Page 5 of 71
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
24-123-0002
Report Limit
Project:AKR-005
V 92439FG-4
J0.273 05/08/2024 00:318270EPyrenemg/Kg - dry 0.183
0.477 05/08/2024 21:12SW-7199 Chromium, Hexavalent mg/Kg - dry 0.161
12.7 05/03/2024 12:41SW-DRYWT Moisture %
V 92440FG-DUP
1.11 05/09/2024 22:056020BArsenicmg/Kg - dry 0.100
71.2 05/08/2024 15:326020BBariummg/Kg - dry 0.050
31.3 05/08/2024 15:326020BChromiummg/Kg - dry 0.135
7.32 05/08/2024 15:326020BLeadmg/Kg - dry 0.0362
J0.176 05/08/2024 15:326020BSeleniummg/Kg - dry 0.120
J0.0146 05/06/2024 15:087471BMercury (Total)mg/Kg - dry 0.0140
J0.013 05/03/2024 12:598260DAcetonemg/Kg - dry 0.002
J0.002 05/03/2024 12:598260DCarbon Disulfide mg/Kg - dry 0.0007
J0.005 05/03/2024 12:598260DMethylene Chloride mg/Kg - dry 0.001
J0.276 05/08/2024 00:568270EBenzo(a)anthracene mg/Kg - dry 0.182
J0.249 05/08/2024 00:568270EBenzo(a)pyrene mg/Kg - dry 0.192
J0.424 05/08/2024 00:568270EBenzo(b)fluoranthene mg/Kg - dry 0.171
J0.205 05/08/2024 00:568270EChrysenemg/Kg - dry 0.170
J0.474 05/08/2024 00:568270EFluoranthenemg/Kg - dry 0.184
J0.339 05/08/2024 00:568270EPhenanthrenemg/Kg - dry 0.184
J0.353 05/08/2024 00:568270EPyrenemg/Kg - dry 0.187
0.339 05/08/2024 21:23SW-7199 Chromium, Hexavalent mg/Kg - dry 0.164
14.5 05/03/2024 12:41SW-DRYWT Moisture %
Page 6 of 71

Client: Hart & Hickman (Charlotte) CASE NARRATIVE
Project: AKR-005 Lab Report Number: 24-123-0002
Date: 5/10/2024
Hexavalent Chromium by Ion Chromatography Method SW-7199 Sample 92436 (FG-1) Analyte: Hexavalent Chromium
QC Batch No: L749458/L749006 Insoluble Hexavalent Chromium spike recovery outside QC limits. See soluble spike recovery and LCS for system
verification.
Sample 92436 (FG-1) Analyte: Hexavalent Chromium
QC Batch No: L749458/L749006 Matrix Spike Recovery Low: A measure of the sample pH and its oxidation reduction potential (ORP) indicate that
the sample has reducing qualities which may not allow for the presence of Hexavalent Chromium. Solids Total Mercury Analysis - CVAA Method 7471B Sample 92256
Analyte: Mercury QC Batch No: V46877/V46852
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected. Volatile Organic Compounds - GC/MS Method 8260D Analyte: 1,2,3-Trichlorobenzene
QC Batch No: V46835/V46834 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Bromoform
QC Batch No: V46835/V46834 Target analyte did not meet calibration verification criteria. Analysis of a low level check demonstrated that there was adequate sensitivity to report this compound at the laboratory reporting limit as non-detect.
Analyte: Bromomethane QC Batch No: V46835/V46834
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Analyte: Chloroethane QC Batch No: V46835/V46834 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Chloromethane QC Batch No: V46835/V46834 Target analyte did not meet calibration verification criteria. Analysis of a low level check demonstrated that there was adequate sensitivity to report this compound at the laboratory reporting limit as non-detect. Analyte: Chloromethane
Page 7 of 71

QC Batch No: V46835/V46834
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: 1,2-Dibromo-3-chloropropane QC Batch No: V46835/V46834
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Dichlorodifluoromethane QC Batch No: V46835/V46834
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Ethanol QC Batch No: V46835/V46834
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Ethanol QC Batch No: V46835/V46834
Target analyte did not meet calibration verification criteria. Analysis of a low level check demonstrated that there was adequate sensitivity to report this compound at the laboratory reporting limit as non-detect.
Analyte: Naphthalene
QC Batch No: V46835/V46834 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Analyte: o-Xylene
QC Batch No: V46835/V46834 Target analyte did not meet calibration verification criteria. Analysis of a low level check demonstrated that there
was adequate sensitivity to report this compound at the laboratory reporting limit as non-detect. Analyte: Styrene QC Batch No: V46835/V46834 Target analyte did not meet calibration verification criteria. Analysis of a low level check demonstrated that there was adequate sensitivity to report this compound at the laboratory reporting limit as non-detect.
Analyte: Vinyl chloride
QC Batch No: V46835/V46834 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Semivolatile Organic Compounds - GC/MS Method 8270E Sample 91797 (SS-2) QC Batch No: V46903/V46854 Matrix spike/matrix spike duplicate recoveries are outside of control limits. Acceptable LCS recovery indicates the system was in control, but the reported result could be affected by matrix interference. Sample 91797 (SS-2) QC Batch No: V46903/V46854 The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly. Analyte: 2,4-Dimethylphenol QC Batch No: V46903/V46854 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable.
Page 8 of 71

Analyte: Benzo(b)fluoranthene QC Batch No: V46903/V46854
This target analyte was flagged for recoveries outside QC limits in the associated CCV. Results should be considered estimated due to the potential for a high bias.
Analyte: Benzoic Acid
QC Batch No: V46903/V46854 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable.
Analyte: Dibenz(a,h)anthracene
QC Batch No: V46903/V46854 This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this
analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for a low bias.
Analyte: Indeno(1,2,3-cd)pyrene
QC Batch No: V46903/V46854 This target analyte was flagged for recoveries outside QC limits in the associated CCV. Results should be
considered estimated due to the potential for a high bias.
Page 9 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-1
92436 Matrix:
5/1/2024 11:55
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
5.97 %Moisture 1 05/03/24 12:41 SW-DRYWTAKF
0.249 mg/Kg - dry 0.149 0.212Chromium, Hexavalent 1 05/08/24 20:06 SW-7199MKD
0.895 mg/Kg - dry 0.0909 0.266Arsenic 5 05/09/24 21:33 6020BCPW
101 mg/Kg - dry 0.045 0.265Barium 5 05/08/24 15:05 6020BTJS
<0.266 mg/Kg - dry 0.0276 0.266Cadmium 5 05/08/24 15:05 6020BTJS
36.2 mg/Kg - dry 0.123 0.265Chromium 5 05/08/24 15:05 6020BTJS
4.08 mg/Kg - dry 0.0329 0.266Lead 5 05/08/24 15:05 6020BTJS
0.0133 J mg/Kg - dry 0.0128 0.0319Mercury (Total)1 05/06/24 14:51 7471BNPC
0.216 J mg/Kg - dry 0.109 0.265Selenium 5 05/08/24 15:05 6020BTJS
<0.266 mg/Kg - dry 0.0071 0.266Silver 5 05/08/24 15:05 6020BTJS
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 10 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-1
92436 Matrix:
5/1/2024 11:55
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):05/03/24 08:00
0.006 J mg/Kg - dry 0.002 0.021Acetone 1 05/03/24 11:11 V46835TBL
<0.001 mg/Kg - dry 0.001 0.021Acrolein 1 05/03/24 11:11 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.021Acrylonitrile 1 05/03/24 11:11 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005Benzene 1 05/03/24 11:11 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.005Bromobenzene 1 05/03/24 11:11 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.005Bromochloromethane 1 05/03/24 11:11 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Bromodichloromethane 1 05/03/24 11:11 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Bromoform 1 05/03/24 11:11 V46835TBL
<0.001 mg/Kg - dry 0.001 0.010Bromomethane 1 05/03/24 11:11 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.005n-Butylbenzene 1 05/03/24 11:11 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005sec-Butyl benzene 1 05/03/24 11:11 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.005tert-Butyl benzene 1 05/03/24 11:11 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.005Carbon Disulfide 1 05/03/24 11:11 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Carbon Tetrachloride 1 05/03/24 11:11 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.005Chlorobenzene 1 05/03/24 11:11 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.005Chlorodibromomethane 1 05/03/24 11:11 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.010Chloroethane 1 05/03/24 11:11 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Chloroform 1 05/03/24 11:11 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.010Chloromethane 1 05/03/24 11:11 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.0052-Chlorotoluene 1 05/03/24 11:11 V46835TBL
<0.0004 mg/Kg - dry 0.0004 0.0054-Chlorotoluene 1 05/03/24 11:11 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.005Di-Isopropyl Ether (DIPE)1 05/03/24 11:11 V46835TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 11 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-1
92436 Matrix:
5/1/2024 11:55
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):05/03/24 08:00
<0.0005 mg/Kg - dry 0.0005 0.0101,2-Dibromo-3-Chloropropane 1 05/03/24 11:11 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.0051,2-Dibromoethane 1 05/03/24 11:11 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005Dibromomethane 1 05/03/24 11:11 V46835TBL
<0.0003 mg/Kg - dry 0.0003 0.0051,2-Dichlorobenzene 1 05/03/24 11:11 V46835TBL
<0.0004 mg/Kg - dry 0.0004 0.0051,3-Dichlorobenzene 1 05/03/24 11:11 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.0051,4-Dichlorobenzene 1 05/03/24 11:11 V46835TBL
<0.001 mg/Kg - dry 0.001 0.010Dichlorodifluoromethane 1 05/03/24 11:11 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.0051,1-Dichloroethane 1 05/03/24 11:11 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0051,2-Dichloroethane 1 05/03/24 11:11 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.0051,1-Dichloroethene 1 05/03/24 11:11 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.005cis-1,2-Dichloroethene 1 05/03/24 11:11 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005trans-1,2-Dichloroethene 1 05/03/24 11:11 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,2-Dichloropropane 1 05/03/24 11:11 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.0051,3-Dichloropropane 1 05/03/24 11:11 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0052,2-Dichloropropane 1 05/03/24 11:11 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.0051,1-Dichloropropene 1 05/03/24 11:11 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005cis-1,3-Dichloropropene 1 05/03/24 11:11 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.005trans-1,3-Dichloropropene 1 05/03/24 11:11 V46835TBL
<0.014 mg/Kg - dry 0.014 0.265Ethanol 1 05/03/24 11:11 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005Ethylbenzene 1 05/03/24 11:11 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.053Ethyl Tertiary Butyl Ether (ETBE)1 05/03/24 11:11 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.010Hexachlorobutadiene 1 05/03/24 11:11 V46835TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 12 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-1
92436 Matrix:
5/1/2024 11:55
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):05/03/24 08:00
<0.0007 mg/Kg - dry 0.0007 0.010n-Hexane 1 05/03/24 11:11 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.0212-Hexanone 1 05/03/24 11:11 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.005Isopropylbenzene 1 05/03/24 11:11 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0054-Isopropyl toluene 1 05/03/24 11:11 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.021Methyl Ethyl Ketone (MEK)1 05/03/24 11:11 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.005Methyl tert-butyl ether (MTBE)1 05/03/24 11:11 V46835TBL
<0.015 mg/Kg - dry 0.015 0.0214-Methyl-2-Pentanone 1 05/03/24 11:11 V46835TBL
0.004 J mg/Kg - dry 0.001 0.010Methylene Chloride 1 05/03/24 11:11 V46835TBL
<0.001 mg/Kg - dry 0.001 0.010Naphthalene 1 05/03/24 11:11 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005n-Propylbenzene 1 05/03/24 11:11 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Styrene 1 05/03/24 11:11 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0051,1,1,2-Tetrachloroethane 1 05/03/24 11:11 V46835TBL
<0.0003 mg/Kg - dry 0.0003 0.0051,1,2,2-Tetrachloroethane 1 05/03/24 11:11 V46835TBL
<0.0010 mg/Kg - dry 0.0010 0.005 1 05/03/24 11:11 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.005 1 05/03/24 11:11 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.0101,2,3-Trichlorobenzene 1 05/03/24 11:11 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.0101,2,4-Trichlorobenzene 1 05/03/24 11:11 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0051,1,1-Trichloroethane 1 05/03/24 11:11 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,1,2-Trichloroethane 1 05/03/24 11:11 V46835TBL
<0.0010 mg/Kg - dry 0.0010 0.005 1 05/03/24 11:11 V46835TBL
<0.002 mg/Kg - dry 0.002 0.010 1 05/03/24 11:11 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.0051,2,3-Trichloropropane 1 05/03/24 11:11 V46835TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 13 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-1
92436 Matrix:
5/1/2024 11:55
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):05/03/24 08:00
<0.0005 mg/Kg - dry 0.0005 0.0051,2,4-Trimethylbenzene 1 05/03/24 11:11 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.0051,3,5-Trimethylbenzene 1 05/03/24 11:11 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.010Vinyl Acetate 1 05/03/24 11:11 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.010Vinyl Chloride 1 05/03/24 11:11 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.005o-Xylene 1 05/03/24 11:11 V46835TBL
<0.001 mg/Kg - dry 0.001 0.010m,p-Xylene 1 05/03/24 11:11 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.005Xylene (Total)1 05/03/24 11:11 V46835
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: Toluene-d8
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):05/06/24 09:20
0.246 J mg/Kg - dry 0.156 0.701Acenaphthene 1 05/07/24 23:17 V46903AMP
<0.159 mg/Kg - dry 0.159 0.701Acenaphthylene 1 05/07/24 23:17 V46903AMP
<0.223 mg/Kg - dry 0.223 0.701Aniline 1 05/07/24 23:17 V46903AMP
0.622 J mg/Kg - dry 0.176 0.701Anthracene 1 05/07/24 23:17 V46903AMP
1.34 mg/Kg - dry 0.165 0.701Benzo(a)anthracene 1 05/07/24 23:17 V46903AMP
1.11 mg/Kg - dry 0.175 0.701Benzo(a)pyrene 1 05/07/24 23:17 V46903AMP
1.41 mg/Kg - dry 0.156 0.701Benzo(b)fluoranthene 1 05/07/24 23:17 V46903AMP
0.477 J mg/Kg - dry 0.153 0.701Benzo(g,h,i)perylene 1 05/07/24 23:17 V46903AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 14 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-1
92436 Matrix:
5/1/2024 11:55
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):05/06/24 09:20
0.386 J mg/Kg - dry 0.165 0.701Benzo(k)fluoranthene 1 05/07/24 23:17 V46903AMP
<0.616 mg/Kg - dry 0.616 2.13Benzoic Acid 1 05/07/24 23:17 V46903AMP
<0.165 mg/Kg - dry 0.165 0.701Benzyl alcohol 1 05/07/24 23:17 V46903AMP
<0.146 mg/Kg - dry 0.146 0.701Bis(2-Chloroethoxy)methane 1 05/07/24 23:17 V46903AMP
<0.129 mg/Kg - dry 0.129 0.701Bis(2-Chloroethyl)ether 1 05/07/24 23:17 V46903AMP
<0.139 mg/Kg - dry 0.139 0.350Bis(2-Chloroisopropyl)ether 1 05/07/24 23:17 V46903AMP
0.231 J mg/Kg - dry 0.188 0.701Bis(2-ethylhexyl)phthalate 1 05/07/24 23:17 V46903AMP
<0.168 mg/Kg - dry 0.168 0.7014-Bromophenyl phenyl ether 1 05/07/24 23:17 V46903AMP
<0.170 mg/Kg - dry 0.170 0.350Butyl benzyl phthalate 1 05/07/24 23:17 V46903AMP
<0.158 mg/Kg - dry 0.158 0.7014-Chloro-3-methylphenol 1 05/07/24 23:17 V46903AMP
<0.159 mg/Kg - dry 0.159 0.3504-Chloroaniline 1 05/07/24 23:17 V46903AMP
<0.163 mg/Kg - dry 0.163 0.7012-Chloronaphthalene 1 05/07/24 23:17 V46903AMP
<0.151 mg/Kg - dry 0.151 0.7012-Chlorophenol 1 05/07/24 23:17 V46903AMP
<0.156 mg/Kg - dry 0.156 1.064-Chlorophenyl phenyl ether 1 05/07/24 23:17 V46903AMP
0.962 mg/Kg - dry 0.155 0.701Chrysene 1 05/07/24 23:17 V46903AMP
0.240 JM mg/Kg - dry 0.118 0.701Dibenz(a,h)anthracene 1 05/07/24 23:17 V46903AMP
<0.168 mg/Kg - dry 0.168 0.701Dibenzofuran 1 05/07/24 23:17 V46903AMP
<0.136 mg/Kg - dry 0.136 0.7011,2-Dichlorobenzene 1 05/07/24 23:17 V46903AMP
<0.132 mg/Kg - dry 0.132 0.7011,3-Dichlorobenzene 1 05/07/24 23:17 V46903AMP
<0.125 mg/Kg - dry 0.125 0.3501,4-Dichlorobenzene 1 05/07/24 23:17 V46903AMP
<0.159 mg/Kg - dry 0.159 0.7013,3'-Dichlorobenzidine 1 05/07/24 23:17 V46903AMP
<0.148 mg/Kg - dry 0.148 0.7012,4-Dichlorophenol 1 05/07/24 23:17 V46903AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 15 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-1
92436 Matrix:
5/1/2024 11:55
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):05/06/24 09:20
<0.156 mg/Kg - dry 0.156 0.701Diethyl phthalate 1 05/07/24 23:17 V46903AMP
<0.166 mg/Kg - dry 0.166 0.701Dimethyl phthalate 1 05/07/24 23:17 V46903AMP
<0.225 mg/Kg - dry 0.225 0.7012,4-Dimethylphenol 1 05/07/24 23:17 V46903AMP
<0.181 mg/Kg - dry 0.181 0.701Di-n-butyl phthalate 1 05/07/24 23:17 V46903AMP
<0.255 mg/Kg - dry 0.255 1.604,6-Dinitro-2-methylphenol 1 05/07/24 23:17 V46903AMP
<0.553 mg/Kg - dry 0.553 1.602,4-Dinitrophenol 1 05/07/24 23:17 V46903AMP
<0.171 mg/Kg - dry 0.171 0.7012,4-Dinitrotoluene 1 05/07/24 23:17 V46903AMP
<0.176 mg/Kg - dry 0.176 0.7012,6-Dinitrotoluene 1 05/07/24 23:17 V46903AMP
<0.173 mg/Kg - dry 0.173 0.350Di-n-Octyl Phthalate 1 05/07/24 23:17 V46903AMP
2.50 mg/Kg - dry 0.168 0.701Fluoranthene 1 05/07/24 23:17 V46903AMP
0.240 J mg/Kg - dry 0.162 0.701Fluorene 1 05/07/24 23:17 V46903AMP
<0.159 mg/Kg - dry 0.159 0.701Hexachlorobenzene 1 05/07/24 23:17 V46903AMP
<0.103 mg/Kg - dry 0.103 0.701Hexachlorobutadiene 1 05/07/24 23:17 V46903AMP
<0.106 mg/Kg - dry 0.106 0.701Hexachlorocyclopentadiene 1 05/07/24 23:17 V46903AMP
<0.129 mg/Kg - dry 0.129 0.701Hexachloroethane 1 05/07/24 23:17 V46903AMP
0.747 mg/Kg - dry 0.160 0.701Indeno(1,2,3-cd)pyrene 1 05/07/24 23:17 V46903AMP
<0.128 mg/Kg - dry 0.128 0.701Isophorone 1 05/07/24 23:17 V46903AMP
<0.147 mg/Kg - dry 0.147 0.7011-Methylnaphthalene 1 05/07/24 23:17 V46903AMP
<0.153 mg/Kg - dry 0.153 0.7012-Methylnaphthalene 1 05/07/24 23:17 V46903AMP
<0.135 mg/Kg - dry 0.135 0.7012-Methylphenol 1 05/07/24 23:17 V46903AMP
<0.136 mg/Kg - dry 0.136 0.7013&4 Methylphenol 1 05/07/24 23:17 V46903AMP
<0.141 mg/Kg - dry 0.141 0.701Naphthalene 1 05/07/24 23:17 V46903AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 16 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-1
92436 Matrix:
5/1/2024 11:55
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):05/06/24 09:20
<0.140 mg/Kg - dry 0.140 0.7012-Nitroaniline 1 05/07/24 23:17 V46903AMP
<0.164 mg/Kg - dry 0.164 0.7013-Nitroaniline 1 05/07/24 23:17 V46903AMP
<0.144 mg/Kg - dry 0.144 0.3504-Nitroaniline 1 05/07/24 23:17 V46903AMP
<0.137 mg/Kg - dry 0.137 0.350Nitrobenzene 1 05/07/24 23:17 V46903AMP
<0.141 mg/Kg - dry 0.141 0.7012-Nitrophenol 1 05/07/24 23:17 V46903AMP
<0.177 mg/Kg - dry 0.177 0.7014-Nitrophenol 1 05/07/24 23:17 V46903AMP
<0.279 mg/Kg - dry 0.279 0.701N-Nitrosodimethylamine 1 05/07/24 23:17 V46903AMP
<0.193 mg/Kg - dry 0.193 0.701N-Nitrosodiphenylamine 1 05/07/24 23:17 V46903AMP
<0.157 mg/Kg - dry 0.157 0.701N-Nitroso-di-n-propylamine 1 05/07/24 23:17 V46903AMP
<0.369 mg/Kg - dry 0.369 1.06Pentachlorophenol 1 05/07/24 23:17 V46903AMP
1.77 mg/Kg - dry 0.168 0.701Phenanthrene 1 05/07/24 23:17 V46903AMP
<0.151 mg/Kg - dry 0.151 0.701Phenol 1 05/07/24 23:17 V46903AMP
1.63 mg/Kg - dry 0.170 0.701Pyrene 1 05/07/24 23:17 V46903AMP
<0.081 mg/Kg - dry 0.081 0.350Pyridine 1 05/07/24 23:17 V46903AMP
<0.140 mg/Kg - dry 0.140 0.7011,2,4-Trichlorobenzene 1 05/07/24 23:17 V46903AMP
<0.152 mg/Kg - dry 0.152 0.7012,4,5-Trichlorophenol 1 05/07/24 23:17 V46903AMP
<0.148 mg/Kg - dry 0.148 0.7012,4,6-Trichlorophenol 1 05/07/24 23:17 V46903AMP
Surrogate: Phenol-d5
Surrogate: 2-Fluorobiphenyl
Surrogate: 2-Fluorophenol
Surrogate: Nitrobenzene-d5
Surrogate: 4-Terphenyl-d14
Surrogate: 2,4,6-Tribromophenol
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 17 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-2
92437 Matrix:
5/1/2024 16:10
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
16.3 %Moisture 1 05/03/24 12:41 SW-DRYWTAKF
0.291 mg/Kg - dry 0.168 0.238Chromium, Hexavalent 1 05/08/24 20:50 SW-7199MKD
1.21 mg/Kg - dry 0.102 0.299Arsenic 5 05/09/24 21:48 6020BCPW
98.2 mg/Kg - dry 0.051 0.298Barium 5 05/08/24 15:10 6020BTJS
<0.299 mg/Kg - dry 0.0310 0.299Cadmium 5 05/08/24 15:10 6020BTJS
43.1 mg/Kg - dry 0.138 0.298Chromium 5 05/08/24 15:10 6020BTJS
7.30 mg/Kg - dry 0.0370 0.299Lead 5 05/08/24 15:10 6020BTJS
0.0173 J mg/Kg - dry 0.0143 0.0358Mercury (Total)1 05/06/24 14:53 7471BNPC
0.156 J mg/Kg - dry 0.123 0.298Selenium 5 05/08/24 15:10 6020BTJS
<0.299 mg/Kg - dry 0.0080 0.299Silver 5 05/08/24 15:10 6020BTJS
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 18 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-2
92437 Matrix:
5/1/2024 16:10
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):05/03/24 08:00
0.021 J mg/Kg - dry 0.002 0.023Acetone 1 05/03/24 11:38 V46835TBL
<0.001 mg/Kg - dry 0.001 0.023Acrolein 1 05/03/24 11:38 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.023Acrylonitrile 1 05/03/24 11:38 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.005Benzene 1 05/03/24 11:38 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005Bromobenzene 1 05/03/24 11:38 V46835TBL
<0.0010 mg/Kg - dry 0.0010 0.005Bromochloromethane 1 05/03/24 11:38 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Bromodichloromethane 1 05/03/24 11:38 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Bromoform 1 05/03/24 11:38 V46835TBL
<0.002 mg/Kg - dry 0.002 0.011Bromomethane 1 05/03/24 11:38 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005n-Butylbenzene 1 05/03/24 11:38 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.005sec-Butyl benzene 1 05/03/24 11:38 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005tert-Butyl benzene 1 05/03/24 11:38 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.005Carbon Disulfide 1 05/03/24 11:38 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Carbon Tetrachloride 1 05/03/24 11:38 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.005Chlorobenzene 1 05/03/24 11:38 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Chlorodibromomethane 1 05/03/24 11:38 V46835TBL
<0.001 mg/Kg - dry 0.001 0.011Chloroethane 1 05/03/24 11:38 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Chloroform 1 05/03/24 11:38 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.011Chloromethane 1 05/03/24 11:38 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.0052-Chlorotoluene 1 05/03/24 11:38 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.0054-Chlorotoluene 1 05/03/24 11:38 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.005Di-Isopropyl Ether (DIPE)1 05/03/24 11:38 V46835TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 19 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-2
92437 Matrix:
5/1/2024 16:10
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):05/03/24 08:00
<0.0005 mg/Kg - dry 0.0005 0.0111,2-Dibromo-3-Chloropropane 1 05/03/24 11:38 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.0051,2-Dibromoethane 1 05/03/24 11:38 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.005Dibromomethane 1 05/03/24 11:38 V46835TBL
<0.0004 mg/Kg - dry 0.0004 0.0051,2-Dichlorobenzene 1 05/03/24 11:38 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,3-Dichlorobenzene 1 05/03/24 11:38 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.0051,4-Dichlorobenzene 1 05/03/24 11:38 V46835TBL
<0.001 mg/Kg - dry 0.001 0.011Dichlorodifluoromethane 1 05/03/24 11:38 V46835TBL
<0.0010 mg/Kg - dry 0.0010 0.0051,1-Dichloroethane 1 05/03/24 11:38 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0051,2-Dichloroethane 1 05/03/24 11:38 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.0051,1-Dichloroethene 1 05/03/24 11:38 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.005cis-1,2-Dichloroethene 1 05/03/24 11:38 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005trans-1,2-Dichloroethene 1 05/03/24 11:38 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,2-Dichloropropane 1 05/03/24 11:38 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.0051,3-Dichloropropane 1 05/03/24 11:38 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0052,2-Dichloropropane 1 05/03/24 11:38 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.0051,1-Dichloropropene 1 05/03/24 11:38 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005cis-1,3-Dichloropropene 1 05/03/24 11:38 V46835TBL
<0.0010 mg/Kg - dry 0.0010 0.005trans-1,3-Dichloropropene 1 05/03/24 11:38 V46835TBL
<0.016 mg/Kg - dry 0.016 0.298Ethanol 1 05/03/24 11:38 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.005Ethylbenzene 1 05/03/24 11:38 V46835TBL
<0.0010 mg/Kg - dry 0.0010 0.059Ethyl Tertiary Butyl Ether (ETBE)1 05/03/24 11:38 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.011Hexachlorobutadiene 1 05/03/24 11:38 V46835TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 20 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-2
92437 Matrix:
5/1/2024 16:10
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):05/03/24 08:00
0.001 J mg/Kg - dry 0.0008 0.011n-Hexane 1 05/03/24 11:38 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.0232-Hexanone 1 05/03/24 11:38 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.005Isopropylbenzene 1 05/03/24 11:38 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0054-Isopropyl toluene 1 05/03/24 11:38 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.023Methyl Ethyl Ketone (MEK)1 05/03/24 11:38 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.005Methyl tert-butyl ether (MTBE)1 05/03/24 11:38 V46835TBL
<0.017 mg/Kg - dry 0.017 0.0234-Methyl-2-Pentanone 1 05/03/24 11:38 V46835TBL
0.004 J mg/Kg - dry 0.001 0.011Methylene Chloride 1 05/03/24 11:38 V46835TBL
<0.001 mg/Kg - dry 0.001 0.011Naphthalene 1 05/03/24 11:38 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005n-Propylbenzene 1 05/03/24 11:38 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Styrene 1 05/03/24 11:38 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0051,1,1,2-Tetrachloroethane 1 05/03/24 11:38 V46835TBL
<0.0004 mg/Kg - dry 0.0004 0.0051,1,2,2-Tetrachloroethane 1 05/03/24 11:38 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005 1 05/03/24 11:38 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.005 1 05/03/24 11:38 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.0111,2,3-Trichlorobenzene 1 05/03/24 11:38 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.0111,2,4-Trichlorobenzene 1 05/03/24 11:38 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0051,1,1-Trichloroethane 1 05/03/24 11:38 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.0051,1,2-Trichloroethane 1 05/03/24 11:38 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005 1 05/03/24 11:38 V46835TBL
<0.002 mg/Kg - dry 0.002 0.011 1 05/03/24 11:38 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.0051,2,3-Trichloropropane 1 05/03/24 11:38 V46835TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 21 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-2
92437 Matrix:
5/1/2024 16:10
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):05/03/24 08:00
<0.0006 mg/Kg - dry 0.0006 0.0051,2,4-Trimethylbenzene 1 05/03/24 11:38 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.0051,3,5-Trimethylbenzene 1 05/03/24 11:38 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.011Vinyl Acetate 1 05/03/24 11:38 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.011Vinyl Chloride 1 05/03/24 11:38 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005o-Xylene 1 05/03/24 11:38 V46835TBL
<0.001 mg/Kg - dry 0.001 0.011m,p-Xylene 1 05/03/24 11:38 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005Xylene (Total)1 05/03/24 11:38 V46835
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: Toluene-d8
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):05/06/24 09:20
<0.175 mg/Kg - dry 0.175 0.788Acenaphthene 1 05/07/24 23:41 V46903AMP
<0.179 mg/Kg - dry 0.179 0.788Acenaphthylene 1 05/07/24 23:41 V46903AMP
<0.250 mg/Kg - dry 0.250 0.788Aniline 1 05/07/24 23:41 V46903AMP
<0.198 mg/Kg - dry 0.198 0.788Anthracene 1 05/07/24 23:41 V46903AMP
<0.186 mg/Kg - dry 0.186 0.788Benzo(a)anthracene 1 05/07/24 23:41 V46903AMP
<0.197 mg/Kg - dry 0.197 0.788Benzo(a)pyrene 1 05/07/24 23:41 V46903AMP
<0.175 mg/Kg - dry 0.175 0.788Benzo(b)fluoranthene 1 05/07/24 23:41 V46903AMP
<0.172 mg/Kg - dry 0.172 0.788Benzo(g,h,i)perylene 1 05/07/24 23:41 V46903AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 22 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-2
92437 Matrix:
5/1/2024 16:10
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):05/06/24 09:20
<0.186 mg/Kg - dry 0.186 0.788Benzo(k)fluoranthene 1 05/07/24 23:41 V46903AMP
<0.692 mg/Kg - dry 0.692 2.39Benzoic Acid 1 05/07/24 23:41 V46903AMP
<0.186 mg/Kg - dry 0.186 0.788Benzyl alcohol 1 05/07/24 23:41 V46903AMP
<0.164 mg/Kg - dry 0.164 0.788Bis(2-Chloroethoxy)methane 1 05/07/24 23:41 V46903AMP
<0.145 mg/Kg - dry 0.145 0.788Bis(2-Chloroethyl)ether 1 05/07/24 23:41 V46903AMP
<0.156 mg/Kg - dry 0.156 0.394Bis(2-Chloroisopropyl)ether 1 05/07/24 23:41 V46903AMP
<0.211 mg/Kg - dry 0.211 0.788Bis(2-ethylhexyl)phthalate 1 05/07/24 23:41 V46903AMP
<0.188 mg/Kg - dry 0.188 0.7884-Bromophenyl phenyl ether 1 05/07/24 23:41 V46903AMP
<0.191 mg/Kg - dry 0.191 0.394Butyl benzyl phthalate 1 05/07/24 23:41 V46903AMP
<0.178 mg/Kg - dry 0.178 0.7884-Chloro-3-methylphenol 1 05/07/24 23:41 V46903AMP
<0.179 mg/Kg - dry 0.179 0.3944-Chloroaniline 1 05/07/24 23:41 V46903AMP
<0.183 mg/Kg - dry 0.183 0.7882-Chloronaphthalene 1 05/07/24 23:41 V46903AMP
<0.169 mg/Kg - dry 0.169 0.7882-Chlorophenol 1 05/07/24 23:41 V46903AMP
<0.175 mg/Kg - dry 0.175 1.194-Chlorophenyl phenyl ether 1 05/07/24 23:41 V46903AMP
<0.174 mg/Kg - dry 0.174 0.788Chrysene 1 05/07/24 23:41 V46903AMP
<0.132 M mg/Kg - dry 0.132 0.788Dibenz(a,h)anthracene 1 05/07/24 23:41 V46903AMP
<0.188 mg/Kg - dry 0.188 0.788Dibenzofuran 1 05/07/24 23:41 V46903AMP
<0.152 mg/Kg - dry 0.152 0.7881,2-Dichlorobenzene 1 05/07/24 23:41 V46903AMP
<0.149 mg/Kg - dry 0.149 0.7881,3-Dichlorobenzene 1 05/07/24 23:41 V46903AMP
<0.140 mg/Kg - dry 0.140 0.3941,4-Dichlorobenzene 1 05/07/24 23:41 V46903AMP
<0.179 mg/Kg - dry 0.179 0.7883,3'-Dichlorobenzidine 1 05/07/24 23:41 V46903AMP
<0.167 mg/Kg - dry 0.167 0.7882,4-Dichlorophenol 1 05/07/24 23:41 V46903AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 23 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-2
92437 Matrix:
5/1/2024 16:10
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):05/06/24 09:20
<0.175 mg/Kg - dry 0.175 0.788Diethyl phthalate 1 05/07/24 23:41 V46903AMP
<0.187 mg/Kg - dry 0.187 0.788Dimethyl phthalate 1 05/07/24 23:41 V46903AMP
<0.253 mg/Kg - dry 0.253 0.7882,4-Dimethylphenol 1 05/07/24 23:41 V46903AMP
<0.204 mg/Kg - dry 0.204 0.788Di-n-butyl phthalate 1 05/07/24 23:41 V46903AMP
<0.286 mg/Kg - dry 0.286 1.794,6-Dinitro-2-methylphenol 1 05/07/24 23:41 V46903AMP
<0.621 mg/Kg - dry 0.621 1.792,4-Dinitrophenol 1 05/07/24 23:41 V46903AMP
<0.192 mg/Kg - dry 0.192 0.7882,4-Dinitrotoluene 1 05/07/24 23:41 V46903AMP
<0.198 mg/Kg - dry 0.198 0.7882,6-Dinitrotoluene 1 05/07/24 23:41 V46903AMP
<0.194 mg/Kg - dry 0.194 0.394Di-n-Octyl Phthalate 1 05/07/24 23:41 V46903AMP
<0.188 mg/Kg - dry 0.188 0.788Fluoranthene 1 05/07/24 23:41 V46903AMP
<0.182 mg/Kg - dry 0.182 0.788Fluorene 1 05/07/24 23:41 V46903AMP
<0.179 mg/Kg - dry 0.179 0.788Hexachlorobenzene 1 05/07/24 23:41 V46903AMP
<0.116 mg/Kg - dry 0.116 0.788Hexachlorobutadiene 1 05/07/24 23:41 V46903AMP
<0.119 mg/Kg - dry 0.119 0.788Hexachlorocyclopentadiene 1 05/07/24 23:41 V46903AMP
<0.145 mg/Kg - dry 0.145 0.788Hexachloroethane 1 05/07/24 23:41 V46903AMP
<0.180 mg/Kg - dry 0.180 0.788Indeno(1,2,3-cd)pyrene 1 05/07/24 23:41 V46903AMP
<0.144 mg/Kg - dry 0.144 0.788Isophorone 1 05/07/24 23:41 V46903AMP
<0.166 mg/Kg - dry 0.166 0.7881-Methylnaphthalene 1 05/07/24 23:41 V46903AMP
<0.172 mg/Kg - dry 0.172 0.7882-Methylnaphthalene 1 05/07/24 23:41 V46903AMP
<0.151 mg/Kg - dry 0.151 0.7882-Methylphenol 1 05/07/24 23:41 V46903AMP
<0.152 mg/Kg - dry 0.152 0.7883&4 Methylphenol 1 05/07/24 23:41 V46903AMP
<0.158 mg/Kg - dry 0.158 0.788Naphthalene 1 05/07/24 23:41 V46903AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 24 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-2
92437 Matrix:
5/1/2024 16:10
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):05/06/24 09:20
<0.157 mg/Kg - dry 0.157 0.7882-Nitroaniline 1 05/07/24 23:41 V46903AMP
<0.185 mg/Kg - dry 0.185 0.7883-Nitroaniline 1 05/07/24 23:41 V46903AMP
<0.162 mg/Kg - dry 0.162 0.3944-Nitroaniline 1 05/07/24 23:41 V46903AMP
<0.154 mg/Kg - dry 0.154 0.394Nitrobenzene 1 05/07/24 23:41 V46903AMP
<0.158 mg/Kg - dry 0.158 0.7882-Nitrophenol 1 05/07/24 23:41 V46903AMP
<0.199 mg/Kg - dry 0.199 0.7884-Nitrophenol 1 05/07/24 23:41 V46903AMP
<0.314 mg/Kg - dry 0.314 0.788N-Nitrosodimethylamine 1 05/07/24 23:41 V46903AMP
<0.217 mg/Kg - dry 0.217 0.788N-Nitrosodiphenylamine 1 05/07/24 23:41 V46903AMP
<0.176 mg/Kg - dry 0.176 0.788N-Nitroso-di-n-propylamine 1 05/07/24 23:41 V46903AMP
<0.414 mg/Kg - dry 0.414 1.19Pentachlorophenol 1 05/07/24 23:41 V46903AMP
<0.188 mg/Kg - dry 0.188 0.788Phenanthrene 1 05/07/24 23:41 V46903AMP
<0.169 mg/Kg - dry 0.169 0.788Phenol 1 05/07/24 23:41 V46903AMP
<0.191 mg/Kg - dry 0.191 0.788Pyrene 1 05/07/24 23:41 V46903AMP
<0.091 mg/Kg - dry 0.091 0.394Pyridine 1 05/07/24 23:41 V46903AMP
<0.157 mg/Kg - dry 0.157 0.7881,2,4-Trichlorobenzene 1 05/07/24 23:41 V46903AMP
<0.170 mg/Kg - dry 0.170 0.7882,4,5-Trichlorophenol 1 05/07/24 23:41 V46903AMP
<0.167 mg/Kg - dry 0.167 0.7882,4,6-Trichlorophenol 1 05/07/24 23:41 V46903AMP
Surrogate: Phenol-d5
Surrogate: 2-Fluorobiphenyl
Surrogate: 2-Fluorophenol
Surrogate: Nitrobenzene-d5
Surrogate: 4-Terphenyl-d14
Surrogate: 2,4,6-Tribromophenol
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 25 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-3
92438 Matrix:
5/1/2024 15:10
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
12.7 %Moisture 1 05/03/24 12:41 SW-DRYWTAKF
0.320 mg/Kg - dry 0.161 0.229Chromium, Hexavalent 1 05/08/24 21:01 SW-7199MKD
0.707 mg/Kg - dry 0.0979 0.286Arsenic 5 05/09/24 21:54 6020BCPW
92.2 mg/Kg - dry 0.049 0.286Barium 5 05/08/24 15:16 6020BTJS
<0.286 mg/Kg - dry 0.0297 0.286Cadmium 5 05/08/24 15:16 6020BTJS
46.0 mg/Kg - dry 0.132 0.286Chromium 5 05/08/24 15:16 6020BTJS
4.75 mg/Kg - dry 0.0355 0.286Lead 5 05/08/24 15:16 6020BTJS
0.0142 J mg/Kg - dry 0.0137 0.0344Mercury (Total)1 05/06/24 14:56 7471BNPC
0.117 J mg/Kg - dry 0.117 0.286Selenium 5 05/08/24 15:16 6020BTJS
<0.286 mg/Kg - dry 0.0077 0.286Silver 5 05/08/24 15:16 6020BTJS
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 26 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-3
92438 Matrix:
5/1/2024 15:10
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):05/03/24 08:00
0.008 J mg/Kg - dry 0.002 0.022Acetone 1 05/03/24 12:05 V46835TBL
<0.001 mg/Kg - dry 0.001 0.022Acrolein 1 05/03/24 12:05 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.022Acrylonitrile 1 05/03/24 12:05 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.005Benzene 1 05/03/24 12:05 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005Bromobenzene 1 05/03/24 12:05 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.005Bromochloromethane 1 05/03/24 12:05 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Bromodichloromethane 1 05/03/24 12:05 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Bromoform 1 05/03/24 12:05 V46835TBL
<0.002 mg/Kg - dry 0.002 0.011Bromomethane 1 05/03/24 12:05 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005n-Butylbenzene 1 05/03/24 12:05 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005sec-Butyl benzene 1 05/03/24 12:05 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005tert-Butyl benzene 1 05/03/24 12:05 V46835TBL
0.0010 J mg/Kg - dry 0.0007 0.005Carbon Disulfide 1 05/03/24 12:05 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Carbon Tetrachloride 1 05/03/24 12:05 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.005Chlorobenzene 1 05/03/24 12:05 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Chlorodibromomethane 1 05/03/24 12:05 V46835TBL
<0.001 mg/Kg - dry 0.001 0.011Chloroethane 1 05/03/24 12:05 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Chloroform 1 05/03/24 12:05 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.011Chloromethane 1 05/03/24 12:05 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.0052-Chlorotoluene 1 05/03/24 12:05 V46835TBL
<0.0004 mg/Kg - dry 0.0004 0.0054-Chlorotoluene 1 05/03/24 12:05 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.005Di-Isopropyl Ether (DIPE)1 05/03/24 12:05 V46835TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 27 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-3
92438 Matrix:
5/1/2024 15:10
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):05/03/24 08:00
<0.0005 mg/Kg - dry 0.0005 0.0111,2-Dibromo-3-Chloropropane 1 05/03/24 12:05 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.0051,2-Dibromoethane 1 05/03/24 12:05 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005Dibromomethane 1 05/03/24 12:05 V46835TBL
<0.0004 mg/Kg - dry 0.0004 0.0051,2-Dichlorobenzene 1 05/03/24 12:05 V46835TBL
<0.0004 mg/Kg - dry 0.0004 0.0051,3-Dichlorobenzene 1 05/03/24 12:05 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.0051,4-Dichlorobenzene 1 05/03/24 12:05 V46835TBL
<0.001 mg/Kg - dry 0.001 0.011Dichlorodifluoromethane 1 05/03/24 12:05 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.0051,1-Dichloroethane 1 05/03/24 12:05 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0051,2-Dichloroethane 1 05/03/24 12:05 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.0051,1-Dichloroethene 1 05/03/24 12:05 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.005cis-1,2-Dichloroethene 1 05/03/24 12:05 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005trans-1,2-Dichloroethene 1 05/03/24 12:05 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,2-Dichloropropane 1 05/03/24 12:05 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.0051,3-Dichloropropane 1 05/03/24 12:05 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0052,2-Dichloropropane 1 05/03/24 12:05 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.0051,1-Dichloropropene 1 05/03/24 12:05 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005cis-1,3-Dichloropropene 1 05/03/24 12:05 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.005trans-1,3-Dichloropropene 1 05/03/24 12:05 V46835TBL
<0.016 mg/Kg - dry 0.016 0.286Ethanol 1 05/03/24 12:05 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.005Ethylbenzene 1 05/03/24 12:05 V46835TBL
<0.0010 mg/Kg - dry 0.0010 0.057Ethyl Tertiary Butyl Ether (ETBE)1 05/03/24 12:05 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.011Hexachlorobutadiene 1 05/03/24 12:05 V46835TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 28 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-3
92438 Matrix:
5/1/2024 15:10
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):05/03/24 08:00
<0.0008 mg/Kg - dry 0.0008 0.011n-Hexane 1 05/03/24 12:05 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.0222-Hexanone 1 05/03/24 12:05 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.005Isopropylbenzene 1 05/03/24 12:05 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0054-Isopropyl toluene 1 05/03/24 12:05 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.022Methyl Ethyl Ketone (MEK)1 05/03/24 12:05 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.005Methyl tert-butyl ether (MTBE)1 05/03/24 12:05 V46835TBL
<0.017 mg/Kg - dry 0.017 0.0224-Methyl-2-Pentanone 1 05/03/24 12:05 V46835TBL
0.004 J mg/Kg - dry 0.001 0.011Methylene Chloride 1 05/03/24 12:05 V46835TBL
<0.001 mg/Kg - dry 0.001 0.011Naphthalene 1 05/03/24 12:05 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005n-Propylbenzene 1 05/03/24 12:05 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Styrene 1 05/03/24 12:05 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0051,1,1,2-Tetrachloroethane 1 05/03/24 12:05 V46835TBL
<0.0004 mg/Kg - dry 0.0004 0.0051,1,2,2-Tetrachloroethane 1 05/03/24 12:05 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005 1 05/03/24 12:05 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.005 1 05/03/24 12:05 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.0111,2,3-Trichlorobenzene 1 05/03/24 12:05 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.0111,2,4-Trichlorobenzene 1 05/03/24 12:05 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0051,1,1-Trichloroethane 1 05/03/24 12:05 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,1,2-Trichloroethane 1 05/03/24 12:05 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005 1 05/03/24 12:05 V46835TBL
<0.002 mg/Kg - dry 0.002 0.011 1 05/03/24 12:05 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.0051,2,3-Trichloropropane 1 05/03/24 12:05 V46835TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 29 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-3
92438 Matrix:
5/1/2024 15:10
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):05/03/24 08:00
<0.0006 mg/Kg - dry 0.0006 0.0051,2,4-Trimethylbenzene 1 05/03/24 12:05 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.0051,3,5-Trimethylbenzene 1 05/03/24 12:05 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.011Vinyl Acetate 1 05/03/24 12:05 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.011Vinyl Chloride 1 05/03/24 12:05 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005o-Xylene 1 05/03/24 12:05 V46835TBL
<0.001 mg/Kg - dry 0.001 0.011m,p-Xylene 1 05/03/24 12:05 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005Xylene (Total)1 05/03/24 12:05 V46835
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: Toluene-d8
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):05/06/24 09:20
<0.168 mg/Kg - dry 0.168 0.757Acenaphthene 1 05/08/24 00:06 V46903AMP
<0.171 mg/Kg - dry 0.171 0.757Acenaphthylene 1 05/08/24 00:06 V46903AMP
<0.240 mg/Kg - dry 0.240 0.757Aniline 1 05/08/24 00:06 V46903AMP
<0.190 mg/Kg - dry 0.190 0.757Anthracene 1 05/08/24 00:06 V46903AMP
0.476 J mg/Kg - dry 0.178 0.757Benzo(a)anthracene 1 05/08/24 00:06 V46903AMP
0.490 J mg/Kg - dry 0.189 0.757Benzo(a)pyrene 1 05/08/24 00:06 V46903AMP
0.761 mg/Kg - dry 0.168 0.757Benzo(b)fluoranthene 1 05/08/24 00:06 V46903AMP
0.276 J mg/Kg - dry 0.164 0.757Benzo(g,h,i)perylene 1 05/08/24 00:06 V46903AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 30 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-3
92438 Matrix:
5/1/2024 15:10
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):05/06/24 09:20
<0.178 mg/Kg - dry 0.178 0.757Benzo(k)fluoranthene 1 05/08/24 00:06 V46903AMP
<0.664 mg/Kg - dry 0.664 2.29Benzoic Acid 1 05/08/24 00:06 V46903AMP
<0.178 mg/Kg - dry 0.178 0.757Benzyl alcohol 1 05/08/24 00:06 V46903AMP
<0.158 mg/Kg - dry 0.158 0.757Bis(2-Chloroethoxy)methane 1 05/08/24 00:06 V46903AMP
<0.139 mg/Kg - dry 0.139 0.757Bis(2-Chloroethyl)ether 1 05/08/24 00:06 V46903AMP
<0.150 mg/Kg - dry 0.150 0.378Bis(2-Chloroisopropyl)ether 1 05/08/24 00:06 V46903AMP
<0.202 mg/Kg - dry 0.202 0.757Bis(2-ethylhexyl)phthalate 1 05/08/24 00:06 V46903AMP
<0.180 mg/Kg - dry 0.180 0.7574-Bromophenyl phenyl ether 1 05/08/24 00:06 V46903AMP
<0.183 mg/Kg - dry 0.183 0.378Butyl benzyl phthalate 1 05/08/24 00:06 V46903AMP
<0.170 mg/Kg - dry 0.170 0.7574-Chloro-3-methylphenol 1 05/08/24 00:06 V46903AMP
<0.171 mg/Kg - dry 0.171 0.3784-Chloroaniline 1 05/08/24 00:06 V46903AMP
<0.176 mg/Kg - dry 0.176 0.7572-Chloronaphthalene 1 05/08/24 00:06 V46903AMP
<0.162 mg/Kg - dry 0.162 0.7572-Chlorophenol 1 05/08/24 00:06 V46903AMP
<0.168 mg/Kg - dry 0.168 1.154-Chlorophenyl phenyl ether 1 05/08/24 00:06 V46903AMP
0.396 J mg/Kg - dry 0.167 0.757Chrysene 1 05/08/24 00:06 V46903AMP
0.254 JM mg/Kg - dry 0.127 0.757Dibenz(a,h)anthracene 1 05/08/24 00:06 V46903AMP
<0.180 mg/Kg - dry 0.180 0.757Dibenzofuran 1 05/08/24 00:06 V46903AMP
<0.146 mg/Kg - dry 0.146 0.7571,2-Dichlorobenzene 1 05/08/24 00:06 V46903AMP
<0.143 mg/Kg - dry 0.143 0.7571,3-Dichlorobenzene 1 05/08/24 00:06 V46903AMP
<0.135 mg/Kg - dry 0.135 0.3781,4-Dichlorobenzene 1 05/08/24 00:06 V46903AMP
<0.171 mg/Kg - dry 0.171 0.7573,3'-Dichlorobenzidine 1 05/08/24 00:06 V46903AMP
<0.160 mg/Kg - dry 0.160 0.7572,4-Dichlorophenol 1 05/08/24 00:06 V46903AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 31 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-3
92438 Matrix:
5/1/2024 15:10
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):05/06/24 09:20
<0.168 mg/Kg - dry 0.168 0.757Diethyl phthalate 1 05/08/24 00:06 V46903AMP
<0.179 mg/Kg - dry 0.179 0.757Dimethyl phthalate 1 05/08/24 00:06 V46903AMP
<0.242 mg/Kg - dry 0.242 0.7572,4-Dimethylphenol 1 05/08/24 00:06 V46903AMP
<0.195 mg/Kg - dry 0.195 0.757Di-n-butyl phthalate 1 05/08/24 00:06 V46903AMP
<0.274 mg/Kg - dry 0.274 1.724,6-Dinitro-2-methylphenol 1 05/08/24 00:06 V46903AMP
<0.595 mg/Kg - dry 0.595 1.722,4-Dinitrophenol 1 05/08/24 00:06 V46903AMP
<0.184 mg/Kg - dry 0.184 0.7572,4-Dinitrotoluene 1 05/08/24 00:06 V46903AMP
<0.190 mg/Kg - dry 0.190 0.7572,6-Dinitrotoluene 1 05/08/24 00:06 V46903AMP
<0.186 mg/Kg - dry 0.186 0.378Di-n-Octyl Phthalate 1 05/08/24 00:06 V46903AMP
0.923 mg/Kg - dry 0.180 0.757Fluoranthene 1 05/08/24 00:06 V46903AMP
<0.175 mg/Kg - dry 0.175 0.757Fluorene 1 05/08/24 00:06 V46903AMP
<0.171 mg/Kg - dry 0.171 0.757Hexachlorobenzene 1 05/08/24 00:06 V46903AMP
<0.111 mg/Kg - dry 0.111 0.757Hexachlorobutadiene 1 05/08/24 00:06 V46903AMP
<0.114 mg/Kg - dry 0.114 0.757Hexachlorocyclopentadiene 1 05/08/24 00:06 V46903AMP
<0.139 mg/Kg - dry 0.139 0.757Hexachloroethane 1 05/08/24 00:06 V46903AMP
0.395 J mg/Kg - dry 0.172 0.757Indeno(1,2,3-cd)pyrene 1 05/08/24 00:06 V46903AMP
<0.138 mg/Kg - dry 0.138 0.757Isophorone 1 05/08/24 00:06 V46903AMP
<0.159 mg/Kg - dry 0.159 0.7571-Methylnaphthalene 1 05/08/24 00:06 V46903AMP
<0.164 mg/Kg - dry 0.164 0.7572-Methylnaphthalene 1 05/08/24 00:06 V46903AMP
<0.145 mg/Kg - dry 0.145 0.7572-Methylphenol 1 05/08/24 00:06 V46903AMP
<0.146 mg/Kg - dry 0.146 0.7573&4 Methylphenol 1 05/08/24 00:06 V46903AMP
<0.152 mg/Kg - dry 0.152 0.757Naphthalene 1 05/08/24 00:06 V46903AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 32 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-3
92438 Matrix:
5/1/2024 15:10
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):05/06/24 09:20
<0.151 mg/Kg - dry 0.151 0.7572-Nitroaniline 1 05/08/24 00:06 V46903AMP
<0.177 mg/Kg - dry 0.177 0.7573-Nitroaniline 1 05/08/24 00:06 V46903AMP
<0.155 mg/Kg - dry 0.155 0.3784-Nitroaniline 1 05/08/24 00:06 V46903AMP
<0.147 mg/Kg - dry 0.147 0.378Nitrobenzene 1 05/08/24 00:06 V46903AMP
<0.152 mg/Kg - dry 0.152 0.7572-Nitrophenol 1 05/08/24 00:06 V46903AMP
<0.191 mg/Kg - dry 0.191 0.7574-Nitrophenol 1 05/08/24 00:06 V46903AMP
<0.301 mg/Kg - dry 0.301 0.757N-Nitrosodimethylamine 1 05/08/24 00:06 V46903AMP
<0.208 mg/Kg - dry 0.208 0.757N-Nitrosodiphenylamine 1 05/08/24 00:06 V46903AMP
<0.169 mg/Kg - dry 0.169 0.757N-Nitroso-di-n-propylamine 1 05/08/24 00:06 V46903AMP
<0.397 mg/Kg - dry 0.397 1.15Pentachlorophenol 1 05/08/24 00:06 V46903AMP
0.576 J mg/Kg - dry 0.180 0.757Phenanthrene 1 05/08/24 00:06 V46903AMP
<0.162 mg/Kg - dry 0.162 0.757Phenol 1 05/08/24 00:06 V46903AMP
0.636 J mg/Kg - dry 0.183 0.757Pyrene 1 05/08/24 00:06 V46903AMP
<0.087 mg/Kg - dry 0.087 0.378Pyridine 1 05/08/24 00:06 V46903AMP
<0.151 mg/Kg - dry 0.151 0.7571,2,4-Trichlorobenzene 1 05/08/24 00:06 V46903AMP
<0.163 mg/Kg - dry 0.163 0.7572,4,5-Trichlorophenol 1 05/08/24 00:06 V46903AMP
<0.160 mg/Kg - dry 0.160 0.7572,4,6-Trichlorophenol 1 05/08/24 00:06 V46903AMP
Surrogate: Phenol-d5
Surrogate: 2-Fluorobiphenyl
Surrogate: 2-Fluorophenol
Surrogate: Nitrobenzene-d5
Surrogate: 4-Terphenyl-d14
Surrogate: 2,4,6-Tribromophenol
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 33 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-4
92439 Matrix:
5/1/2024 13:15
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
12.7 %Moisture 1 05/03/24 12:41 SW-DRYWTAKF
0.477 mg/Kg - dry 0.161 0.229Chromium, Hexavalent 1 05/08/24 21:12 SW-7199MKD
1.06 mg/Kg - dry 0.0979 0.286Arsenic 5 05/09/24 21:59 6020BCPW
71.9 mg/Kg - dry 0.049 0.286Barium 5 05/08/24 15:25 6020BTJS
<0.286 mg/Kg - dry 0.0297 0.286Cadmium 5 05/08/24 15:25 6020BTJS
36.0 mg/Kg - dry 0.132 0.286Chromium 5 05/08/24 15:25 6020BTJS
10.5 mg/Kg - dry 0.0355 0.286Lead 5 05/08/24 15:25 6020BTJS
<0.0137 mg/Kg - dry 0.0137 0.0344Mercury (Total)1 05/06/24 15:05 7471BNPC
0.140 J mg/Kg - dry 0.117 0.286Selenium 5 05/08/24 15:25 6020BTJS
<0.286 mg/Kg - dry 0.0077 0.286Silver 5 05/08/24 15:25 6020BTJS
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 34 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-4
92439 Matrix:
5/1/2024 13:15
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):05/03/24 08:00
0.010 J mg/Kg - dry 0.002 0.022Acetone 1 05/03/24 12:32 V46835TBL
<0.001 mg/Kg - dry 0.001 0.022Acrolein 1 05/03/24 12:32 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.022Acrylonitrile 1 05/03/24 12:32 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.005Benzene 1 05/03/24 12:32 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005Bromobenzene 1 05/03/24 12:32 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.005Bromochloromethane 1 05/03/24 12:32 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Bromodichloromethane 1 05/03/24 12:32 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Bromoform 1 05/03/24 12:32 V46835TBL
<0.002 mg/Kg - dry 0.002 0.011Bromomethane 1 05/03/24 12:32 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005n-Butylbenzene 1 05/03/24 12:32 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005sec-Butyl benzene 1 05/03/24 12:32 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005tert-Butyl benzene 1 05/03/24 12:32 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.005Carbon Disulfide 1 05/03/24 12:32 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Carbon Tetrachloride 1 05/03/24 12:32 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.005Chlorobenzene 1 05/03/24 12:32 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Chlorodibromomethane 1 05/03/24 12:32 V46835TBL
<0.001 mg/Kg - dry 0.001 0.011Chloroethane 1 05/03/24 12:32 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Chloroform 1 05/03/24 12:32 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.011Chloromethane 1 05/03/24 12:32 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.0052-Chlorotoluene 1 05/03/24 12:32 V46835TBL
<0.0004 mg/Kg - dry 0.0004 0.0054-Chlorotoluene 1 05/03/24 12:32 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.005Di-Isopropyl Ether (DIPE)1 05/03/24 12:32 V46835TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 35 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-4
92439 Matrix:
5/1/2024 13:15
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):05/03/24 08:00
<0.0005 mg/Kg - dry 0.0005 0.0111,2-Dibromo-3-Chloropropane 1 05/03/24 12:32 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.0051,2-Dibromoethane 1 05/03/24 12:32 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005Dibromomethane 1 05/03/24 12:32 V46835TBL
<0.0004 mg/Kg - dry 0.0004 0.0051,2-Dichlorobenzene 1 05/03/24 12:32 V46835TBL
<0.0004 mg/Kg - dry 0.0004 0.0051,3-Dichlorobenzene 1 05/03/24 12:32 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.0051,4-Dichlorobenzene 1 05/03/24 12:32 V46835TBL
<0.001 mg/Kg - dry 0.001 0.011Dichlorodifluoromethane 1 05/03/24 12:32 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.0051,1-Dichloroethane 1 05/03/24 12:32 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0051,2-Dichloroethane 1 05/03/24 12:32 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.0051,1-Dichloroethene 1 05/03/24 12:32 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.005cis-1,2-Dichloroethene 1 05/03/24 12:32 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005trans-1,2-Dichloroethene 1 05/03/24 12:32 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,2-Dichloropropane 1 05/03/24 12:32 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.0051,3-Dichloropropane 1 05/03/24 12:32 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0052,2-Dichloropropane 1 05/03/24 12:32 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.0051,1-Dichloropropene 1 05/03/24 12:32 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005cis-1,3-Dichloropropene 1 05/03/24 12:32 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.005trans-1,3-Dichloropropene 1 05/03/24 12:32 V46835TBL
<0.016 mg/Kg - dry 0.016 0.286Ethanol 1 05/03/24 12:32 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.005Ethylbenzene 1 05/03/24 12:32 V46835TBL
<0.0010 mg/Kg - dry 0.0010 0.057Ethyl Tertiary Butyl Ether (ETBE)1 05/03/24 12:32 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.011Hexachlorobutadiene 1 05/03/24 12:32 V46835TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 36 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-4
92439 Matrix:
5/1/2024 13:15
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):05/03/24 08:00
<0.0008 mg/Kg - dry 0.0008 0.011n-Hexane 1 05/03/24 12:32 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.0222-Hexanone 1 05/03/24 12:32 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.005Isopropylbenzene 1 05/03/24 12:32 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0054-Isopropyl toluene 1 05/03/24 12:32 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.022Methyl Ethyl Ketone (MEK)1 05/03/24 12:32 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.005Methyl tert-butyl ether (MTBE)1 05/03/24 12:32 V46835TBL
<0.017 mg/Kg - dry 0.017 0.0224-Methyl-2-Pentanone 1 05/03/24 12:32 V46835TBL
0.002 J mg/Kg - dry 0.001 0.011Methylene Chloride 1 05/03/24 12:32 V46835TBL
<0.001 mg/Kg - dry 0.001 0.011Naphthalene 1 05/03/24 12:32 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005n-Propylbenzene 1 05/03/24 12:32 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Styrene 1 05/03/24 12:32 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0051,1,1,2-Tetrachloroethane 1 05/03/24 12:32 V46835TBL
<0.0004 mg/Kg - dry 0.0004 0.0051,1,2,2-Tetrachloroethane 1 05/03/24 12:32 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005 1 05/03/24 12:32 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.005 1 05/03/24 12:32 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.0111,2,3-Trichlorobenzene 1 05/03/24 12:32 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.0111,2,4-Trichlorobenzene 1 05/03/24 12:32 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0051,1,1-Trichloroethane 1 05/03/24 12:32 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,1,2-Trichloroethane 1 05/03/24 12:32 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005 1 05/03/24 12:32 V46835TBL
<0.002 mg/Kg - dry 0.002 0.011 1 05/03/24 12:32 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.0051,2,3-Trichloropropane 1 05/03/24 12:32 V46835TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 37 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-4
92439 Matrix:
5/1/2024 13:15
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):05/03/24 08:00
<0.0006 mg/Kg - dry 0.0006 0.0051,2,4-Trimethylbenzene 1 05/03/24 12:32 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.0051,3,5-Trimethylbenzene 1 05/03/24 12:32 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.011Vinyl Acetate 1 05/03/24 12:32 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.011Vinyl Chloride 1 05/03/24 12:32 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005o-Xylene 1 05/03/24 12:32 V46835TBL
<0.001 mg/Kg - dry 0.001 0.011m,p-Xylene 1 05/03/24 12:32 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005Xylene (Total)1 05/03/24 12:32 V46835
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: Toluene-d8
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):05/06/24 09:20
<0.168 mg/Kg - dry 0.168 0.756Acenaphthene 1 05/08/24 00:31 V46903AMP
<0.171 mg/Kg - dry 0.171 0.756Acenaphthylene 1 05/08/24 00:31 V46903AMP
<0.240 mg/Kg - dry 0.240 0.756Aniline 1 05/08/24 00:31 V46903AMP
<0.190 mg/Kg - dry 0.190 0.756Anthracene 1 05/08/24 00:31 V46903AMP
0.194 J mg/Kg - dry 0.178 0.756Benzo(a)anthracene 1 05/08/24 00:31 V46903AMP
<0.189 mg/Kg - dry 0.189 0.756Benzo(a)pyrene 1 05/08/24 00:31 V46903AMP
0.282 J mg/Kg - dry 0.168 0.756Benzo(b)fluoranthene 1 05/08/24 00:31 V46903AMP
<0.164 mg/Kg - dry 0.164 0.756Benzo(g,h,i)perylene 1 05/08/24 00:31 V46903AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 38 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-4
92439 Matrix:
5/1/2024 13:15
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):05/06/24 09:20
<0.178 mg/Kg - dry 0.178 0.756Benzo(k)fluoranthene 1 05/08/24 00:31 V46903AMP
<0.664 mg/Kg - dry 0.664 2.29Benzoic Acid 1 05/08/24 00:31 V46903AMP
<0.178 mg/Kg - dry 0.178 0.756Benzyl alcohol 1 05/08/24 00:31 V46903AMP
<0.158 mg/Kg - dry 0.158 0.756Bis(2-Chloroethoxy)methane 1 05/08/24 00:31 V46903AMP
<0.139 mg/Kg - dry 0.139 0.756Bis(2-Chloroethyl)ether 1 05/08/24 00:31 V46903AMP
<0.150 mg/Kg - dry 0.150 0.378Bis(2-Chloroisopropyl)ether 1 05/08/24 00:31 V46903AMP
<0.202 mg/Kg - dry 0.202 0.756Bis(2-ethylhexyl)phthalate 1 05/08/24 00:31 V46903AMP
<0.180 mg/Kg - dry 0.180 0.7564-Bromophenyl phenyl ether 1 05/08/24 00:31 V46903AMP
<0.183 mg/Kg - dry 0.183 0.378Butyl benzyl phthalate 1 05/08/24 00:31 V46903AMP
<0.170 mg/Kg - dry 0.170 0.7564-Chloro-3-methylphenol 1 05/08/24 00:31 V46903AMP
<0.171 mg/Kg - dry 0.171 0.3784-Chloroaniline 1 05/08/24 00:31 V46903AMP
<0.176 mg/Kg - dry 0.176 0.7562-Chloronaphthalene 1 05/08/24 00:31 V46903AMP
<0.162 mg/Kg - dry 0.162 0.7562-Chlorophenol 1 05/08/24 00:31 V46903AMP
<0.168 mg/Kg - dry 0.168 1.154-Chlorophenyl phenyl ether 1 05/08/24 00:31 V46903AMP
<0.167 mg/Kg - dry 0.167 0.756Chrysene 1 05/08/24 00:31 V46903AMP
0.237 JM mg/Kg - dry 0.127 0.756Dibenz(a,h)anthracene 1 05/08/24 00:31 V46903AMP
<0.180 mg/Kg - dry 0.180 0.756Dibenzofuran 1 05/08/24 00:31 V46903AMP
<0.146 mg/Kg - dry 0.146 0.7561,2-Dichlorobenzene 1 05/08/24 00:31 V46903AMP
<0.143 mg/Kg - dry 0.143 0.7561,3-Dichlorobenzene 1 05/08/24 00:31 V46903AMP
<0.135 mg/Kg - dry 0.135 0.3781,4-Dichlorobenzene 1 05/08/24 00:31 V46903AMP
<0.171 mg/Kg - dry 0.171 0.7563,3'-Dichlorobenzidine 1 05/08/24 00:31 V46903AMP
<0.160 mg/Kg - dry 0.160 0.7562,4-Dichlorophenol 1 05/08/24 00:31 V46903AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 39 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-4
92439 Matrix:
5/1/2024 13:15
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):05/06/24 09:20
<0.168 mg/Kg - dry 0.168 0.756Diethyl phthalate 1 05/08/24 00:31 V46903AMP
<0.179 mg/Kg - dry 0.179 0.756Dimethyl phthalate 1 05/08/24 00:31 V46903AMP
<0.242 mg/Kg - dry 0.242 0.7562,4-Dimethylphenol 1 05/08/24 00:31 V46903AMP
<0.195 mg/Kg - dry 0.195 0.756Di-n-butyl phthalate 1 05/08/24 00:31 V46903AMP
<0.274 mg/Kg - dry 0.274 1.724,6-Dinitro-2-methylphenol 1 05/08/24 00:31 V46903AMP
<0.595 mg/Kg - dry 0.595 1.722,4-Dinitrophenol 1 05/08/24 00:31 V46903AMP
<0.184 mg/Kg - dry 0.184 0.7562,4-Dinitrotoluene 1 05/08/24 00:31 V46903AMP
<0.190 mg/Kg - dry 0.190 0.7562,6-Dinitrotoluene 1 05/08/24 00:31 V46903AMP
<0.186 mg/Kg - dry 0.186 0.378Di-n-Octyl Phthalate 1 05/08/24 00:31 V46903AMP
0.408 J mg/Kg - dry 0.180 0.756Fluoranthene 1 05/08/24 00:31 V46903AMP
<0.175 mg/Kg - dry 0.175 0.756Fluorene 1 05/08/24 00:31 V46903AMP
<0.171 mg/Kg - dry 0.171 0.756Hexachlorobenzene 1 05/08/24 00:31 V46903AMP
<0.111 mg/Kg - dry 0.111 0.756Hexachlorobutadiene 1 05/08/24 00:31 V46903AMP
<0.114 mg/Kg - dry 0.114 0.756Hexachlorocyclopentadiene 1 05/08/24 00:31 V46903AMP
<0.139 mg/Kg - dry 0.139 0.756Hexachloroethane 1 05/08/24 00:31 V46903AMP
<0.172 mg/Kg - dry 0.172 0.756Indeno(1,2,3-cd)pyrene 1 05/08/24 00:31 V46903AMP
<0.138 mg/Kg - dry 0.138 0.756Isophorone 1 05/08/24 00:31 V46903AMP
<0.159 mg/Kg - dry 0.159 0.7561-Methylnaphthalene 1 05/08/24 00:31 V46903AMP
<0.164 mg/Kg - dry 0.164 0.7562-Methylnaphthalene 1 05/08/24 00:31 V46903AMP
<0.145 mg/Kg - dry 0.145 0.7562-Methylphenol 1 05/08/24 00:31 V46903AMP
<0.146 mg/Kg - dry 0.146 0.7563&4 Methylphenol 1 05/08/24 00:31 V46903AMP
<0.152 mg/Kg - dry 0.152 0.756Naphthalene 1 05/08/24 00:31 V46903AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 40 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-4
92439 Matrix:
5/1/2024 13:15
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):05/06/24 09:20
<0.151 mg/Kg - dry 0.151 0.7562-Nitroaniline 1 05/08/24 00:31 V46903AMP
<0.177 mg/Kg - dry 0.177 0.7563-Nitroaniline 1 05/08/24 00:31 V46903AMP
<0.155 mg/Kg - dry 0.155 0.3784-Nitroaniline 1 05/08/24 00:31 V46903AMP
<0.147 mg/Kg - dry 0.147 0.378Nitrobenzene 1 05/08/24 00:31 V46903AMP
<0.152 mg/Kg - dry 0.152 0.7562-Nitrophenol 1 05/08/24 00:31 V46903AMP
<0.191 mg/Kg - dry 0.191 0.7564-Nitrophenol 1 05/08/24 00:31 V46903AMP
<0.301 mg/Kg - dry 0.301 0.756N-Nitrosodimethylamine 1 05/08/24 00:31 V46903AMP
<0.208 mg/Kg - dry 0.208 0.756N-Nitrosodiphenylamine 1 05/08/24 00:31 V46903AMP
<0.169 mg/Kg - dry 0.169 0.756N-Nitroso-di-n-propylamine 1 05/08/24 00:31 V46903AMP
<0.397 mg/Kg - dry 0.397 1.15Pentachlorophenol 1 05/08/24 00:31 V46903AMP
0.265 J mg/Kg - dry 0.180 0.756Phenanthrene 1 05/08/24 00:31 V46903AMP
<0.162 mg/Kg - dry 0.162 0.756Phenol 1 05/08/24 00:31 V46903AMP
0.273 J mg/Kg - dry 0.183 0.756Pyrene 1 05/08/24 00:31 V46903AMP
<0.087 mg/Kg - dry 0.087 0.378Pyridine 1 05/08/24 00:31 V46903AMP
<0.151 mg/Kg - dry 0.151 0.7561,2,4-Trichlorobenzene 1 05/08/24 00:31 V46903AMP
<0.163 mg/Kg - dry 0.163 0.7562,4,5-Trichlorophenol 1 05/08/24 00:31 V46903AMP
<0.160 mg/Kg - dry 0.160 0.7562,4,6-Trichlorophenol 1 05/08/24 00:31 V46903AMP
Surrogate: Phenol-d5
Surrogate: 2-Fluorobiphenyl
Surrogate: 2-Fluorophenol
Surrogate: Nitrobenzene-d5
Surrogate: 4-Terphenyl-d14
Surrogate: 2,4,6-Tribromophenol
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 41 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-DUP
92440 Matrix:
5/1/2024 0:00
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
14.5 %Moisture 1 05/03/24 12:41 SW-DRYWTAKF
0.339 mg/Kg - dry 0.164 0.233Chromium, Hexavalent 1 05/08/24 21:23 SW-7199MKD
1.11 mg/Kg - dry 0.100 0.292Arsenic 5 05/09/24 22:05 6020BCPW
71.2 mg/Kg - dry 0.050 0.292Barium 5 05/08/24 15:32 6020BTJS
<0.292 mg/Kg - dry 0.0304 0.292Cadmium 5 05/08/24 15:32 6020BTJS
31.3 mg/Kg - dry 0.135 0.292Chromium 5 05/08/24 15:32 6020BTJS
7.32 mg/Kg - dry 0.0362 0.292Lead 5 05/08/24 15:32 6020BTJS
0.0146 J mg/Kg - dry 0.0140 0.0351Mercury (Total)1 05/06/24 15:08 7471BNPC
0.176 J mg/Kg - dry 0.120 0.292Selenium 5 05/08/24 15:32 6020BTJS
<0.292 mg/Kg - dry 0.0078 0.292Silver 5 05/08/24 15:32 6020BTJS
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 42 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-DUP
92440 Matrix:
5/1/2024 0:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):05/03/24 08:00
0.013 J mg/Kg - dry 0.002 0.023Acetone 1 05/03/24 12:59 V46835TBL
<0.001 mg/Kg - dry 0.001 0.023Acrolein 1 05/03/24 12:59 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.023Acrylonitrile 1 05/03/24 12:59 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.005Benzene 1 05/03/24 12:59 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005Bromobenzene 1 05/03/24 12:59 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.005Bromochloromethane 1 05/03/24 12:59 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Bromodichloromethane 1 05/03/24 12:59 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Bromoform 1 05/03/24 12:59 V46835TBL
<0.002 mg/Kg - dry 0.002 0.011Bromomethane 1 05/03/24 12:59 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005n-Butylbenzene 1 05/03/24 12:59 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.005sec-Butyl benzene 1 05/03/24 12:59 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005tert-Butyl benzene 1 05/03/24 12:59 V46835TBL
0.002 J mg/Kg - dry 0.0007 0.005Carbon Disulfide 1 05/03/24 12:59 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Carbon Tetrachloride 1 05/03/24 12:59 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.005Chlorobenzene 1 05/03/24 12:59 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Chlorodibromomethane 1 05/03/24 12:59 V46835TBL
<0.001 mg/Kg - dry 0.001 0.011Chloroethane 1 05/03/24 12:59 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Chloroform 1 05/03/24 12:59 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.011Chloromethane 1 05/03/24 12:59 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.0052-Chlorotoluene 1 05/03/24 12:59 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.0054-Chlorotoluene 1 05/03/24 12:59 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.005Di-Isopropyl Ether (DIPE)1 05/03/24 12:59 V46835TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 43 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-DUP
92440 Matrix:
5/1/2024 0:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):05/03/24 08:00
<0.0005 mg/Kg - dry 0.0005 0.0111,2-Dibromo-3-Chloropropane 1 05/03/24 12:59 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.0051,2-Dibromoethane 1 05/03/24 12:59 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.005Dibromomethane 1 05/03/24 12:59 V46835TBL
<0.0004 mg/Kg - dry 0.0004 0.0051,2-Dichlorobenzene 1 05/03/24 12:59 V46835TBL
<0.0004 mg/Kg - dry 0.0004 0.0051,3-Dichlorobenzene 1 05/03/24 12:59 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.0051,4-Dichlorobenzene 1 05/03/24 12:59 V46835TBL
<0.001 mg/Kg - dry 0.001 0.011Dichlorodifluoromethane 1 05/03/24 12:59 V46835TBL
<0.0010 mg/Kg - dry 0.0010 0.0051,1-Dichloroethane 1 05/03/24 12:59 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0051,2-Dichloroethane 1 05/03/24 12:59 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.0051,1-Dichloroethene 1 05/03/24 12:59 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.005cis-1,2-Dichloroethene 1 05/03/24 12:59 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005trans-1,2-Dichloroethene 1 05/03/24 12:59 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,2-Dichloropropane 1 05/03/24 12:59 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.0051,3-Dichloropropane 1 05/03/24 12:59 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0052,2-Dichloropropane 1 05/03/24 12:59 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.0051,1-Dichloropropene 1 05/03/24 12:59 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005cis-1,3-Dichloropropene 1 05/03/24 12:59 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.005trans-1,3-Dichloropropene 1 05/03/24 12:59 V46835TBL
<0.016 mg/Kg - dry 0.016 0.292Ethanol 1 05/03/24 12:59 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.005Ethylbenzene 1 05/03/24 12:59 V46835TBL
<0.0010 mg/Kg - dry 0.0010 0.058Ethyl Tertiary Butyl Ether (ETBE)1 05/03/24 12:59 V46835TBL
<0.0009 mg/Kg - dry 0.0009 0.011Hexachlorobutadiene 1 05/03/24 12:59 V46835TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 44 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-DUP
92440 Matrix:
5/1/2024 0:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):05/03/24 08:00
<0.0008 mg/Kg - dry 0.0008 0.011n-Hexane 1 05/03/24 12:59 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.0232-Hexanone 1 05/03/24 12:59 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.005Isopropylbenzene 1 05/03/24 12:59 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0054-Isopropyl toluene 1 05/03/24 12:59 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.023Methyl Ethyl Ketone (MEK)1 05/03/24 12:59 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.005Methyl tert-butyl ether (MTBE)1 05/03/24 12:59 V46835TBL
<0.017 mg/Kg - dry 0.017 0.0234-Methyl-2-Pentanone 1 05/03/24 12:59 V46835TBL
0.005 J mg/Kg - dry 0.001 0.011Methylene Chloride 1 05/03/24 12:59 V46835TBL
<0.001 mg/Kg - dry 0.001 0.011Naphthalene 1 05/03/24 12:59 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005n-Propylbenzene 1 05/03/24 12:59 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005Styrene 1 05/03/24 12:59 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0051,1,1,2-Tetrachloroethane 1 05/03/24 12:59 V46835TBL
<0.0004 mg/Kg - dry 0.0004 0.0051,1,2,2-Tetrachloroethane 1 05/03/24 12:59 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005 1 05/03/24 12:59 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.005 1 05/03/24 12:59 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.0111,2,3-Trichlorobenzene 1 05/03/24 12:59 V46835TBL
<0.0007 mg/Kg - dry 0.0007 0.0111,2,4-Trichlorobenzene 1 05/03/24 12:59 V46835TBL
<0.001 mg/Kg - dry 0.001 0.0051,1,1-Trichloroethane 1 05/03/24 12:59 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,1,2-Trichloroethane 1 05/03/24 12:59 V46835TBL
<0.001 mg/Kg - dry 0.001 0.005 1 05/03/24 12:59 V46835TBL
<0.002 mg/Kg - dry 0.002 0.011 1 05/03/24 12:59 V46835TBL
<0.0008 mg/Kg - dry 0.0008 0.0051,2,3-Trichloropropane 1 05/03/24 12:59 V46835TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 45 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-DUP
92440 Matrix:
5/1/2024 0:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):05/03/24 08:00
<0.0006 mg/Kg - dry 0.0006 0.0051,2,4-Trimethylbenzene 1 05/03/24 12:59 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.0051,3,5-Trimethylbenzene 1 05/03/24 12:59 V46835TBL
<0.0005 mg/Kg - dry 0.0005 0.011Vinyl Acetate 1 05/03/24 12:59 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.011Vinyl Chloride 1 05/03/24 12:59 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005o-Xylene 1 05/03/24 12:59 V46835TBL
<0.001 mg/Kg - dry 0.001 0.011m,p-Xylene 1 05/03/24 12:59 V46835TBL
<0.0006 mg/Kg - dry 0.0006 0.005Xylene (Total)1 05/03/24 12:59 V46835
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: Toluene-d8
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):05/06/24 09:20
<0.171 mg/Kg - dry 0.171 0.773Acenaphthene 1 05/08/24 00:56 V46903AMP
<0.175 mg/Kg - dry 0.175 0.773Acenaphthylene 1 05/08/24 00:56 V46903AMP
<0.245 mg/Kg - dry 0.245 0.773Aniline 1 05/08/24 00:56 V46903AMP
<0.194 mg/Kg - dry 0.194 0.773Anthracene 1 05/08/24 00:56 V46903AMP
0.276 J mg/Kg - dry 0.182 0.773Benzo(a)anthracene 1 05/08/24 00:56 V46903AMP
0.249 J mg/Kg - dry 0.192 0.773Benzo(a)pyrene 1 05/08/24 00:56 V46903AMP
0.424 J mg/Kg - dry 0.171 0.773Benzo(b)fluoranthene 1 05/08/24 00:56 V46903AMP
<0.168 mg/Kg - dry 0.168 0.773Benzo(g,h,i)perylene 1 05/08/24 00:56 V46903AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 46 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-DUP
92440 Matrix:
5/1/2024 0:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):05/06/24 09:20
<0.182 mg/Kg - dry 0.182 0.773Benzo(k)fluoranthene 1 05/08/24 00:56 V46903AMP
<0.678 mg/Kg - dry 0.678 2.34Benzoic Acid 1 05/08/24 00:56 V46903AMP
<0.182 mg/Kg - dry 0.182 0.773Benzyl alcohol 1 05/08/24 00:56 V46903AMP
<0.161 mg/Kg - dry 0.161 0.773Bis(2-Chloroethoxy)methane 1 05/08/24 00:56 V46903AMP
<0.142 mg/Kg - dry 0.142 0.773Bis(2-Chloroethyl)ether 1 05/08/24 00:56 V46903AMP
<0.153 mg/Kg - dry 0.153 0.385Bis(2-Chloroisopropyl)ether 1 05/08/24 00:56 V46903AMP
<0.207 mg/Kg - dry 0.207 0.773Bis(2-ethylhexyl)phthalate 1 05/08/24 00:56 V46903AMP
<0.184 mg/Kg - dry 0.184 0.7734-Bromophenyl phenyl ether 1 05/08/24 00:56 V46903AMP
<0.187 mg/Kg - dry 0.187 0.385Butyl benzyl phthalate 1 05/08/24 00:56 V46903AMP
<0.174 mg/Kg - dry 0.174 0.7734-Chloro-3-methylphenol 1 05/08/24 00:56 V46903AMP
<0.175 mg/Kg - dry 0.175 0.3854-Chloroaniline 1 05/08/24 00:56 V46903AMP
<0.180 mg/Kg - dry 0.180 0.7732-Chloronaphthalene 1 05/08/24 00:56 V46903AMP
<0.166 mg/Kg - dry 0.166 0.7732-Chlorophenol 1 05/08/24 00:56 V46903AMP
<0.171 mg/Kg - dry 0.171 1.174-Chlorophenyl phenyl ether 1 05/08/24 00:56 V46903AMP
0.205 J mg/Kg - dry 0.170 0.773Chrysene 1 05/08/24 00:56 V46903AMP
<0.129 M mg/Kg - dry 0.129 0.773Dibenz(a,h)anthracene 1 05/08/24 00:56 V46903AMP
<0.184 mg/Kg - dry 0.184 0.773Dibenzofuran 1 05/08/24 00:56 V46903AMP
<0.149 mg/Kg - dry 0.149 0.7731,2-Dichlorobenzene 1 05/08/24 00:56 V46903AMP
<0.146 mg/Kg - dry 0.146 0.7731,3-Dichlorobenzene 1 05/08/24 00:56 V46903AMP
<0.138 mg/Kg - dry 0.138 0.3851,4-Dichlorobenzene 1 05/08/24 00:56 V46903AMP
<0.175 mg/Kg - dry 0.175 0.7733,3'-Dichlorobenzidine 1 05/08/24 00:56 V46903AMP
<0.163 mg/Kg - dry 0.163 0.7732,4-Dichlorophenol 1 05/08/24 00:56 V46903AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 47 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-DUP
92440 Matrix:
5/1/2024 0:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):05/06/24 09:20
<0.171 mg/Kg - dry 0.171 0.773Diethyl phthalate 1 05/08/24 00:56 V46903AMP
<0.183 mg/Kg - dry 0.183 0.773Dimethyl phthalate 1 05/08/24 00:56 V46903AMP
<0.247 mg/Kg - dry 0.247 0.7732,4-Dimethylphenol 1 05/08/24 00:56 V46903AMP
<0.200 mg/Kg - dry 0.200 0.773Di-n-butyl phthalate 1 05/08/24 00:56 V46903AMP
<0.280 mg/Kg - dry 0.280 1.754,6-Dinitro-2-methylphenol 1 05/08/24 00:56 V46903AMP
<0.608 mg/Kg - dry 0.608 1.752,4-Dinitrophenol 1 05/08/24 00:56 V46903AMP
<0.188 mg/Kg - dry 0.188 0.7732,4-Dinitrotoluene 1 05/08/24 00:56 V46903AMP
<0.194 mg/Kg - dry 0.194 0.7732,6-Dinitrotoluene 1 05/08/24 00:56 V46903AMP
<0.190 mg/Kg - dry 0.190 0.385Di-n-Octyl Phthalate 1 05/08/24 00:56 V46903AMP
0.474 J mg/Kg - dry 0.184 0.773Fluoranthene 1 05/08/24 00:56 V46903AMP
<0.178 mg/Kg - dry 0.178 0.773Fluorene 1 05/08/24 00:56 V46903AMP
<0.175 mg/Kg - dry 0.175 0.773Hexachlorobenzene 1 05/08/24 00:56 V46903AMP
<0.114 mg/Kg - dry 0.114 0.773Hexachlorobutadiene 1 05/08/24 00:56 V46903AMP
<0.116 mg/Kg - dry 0.116 0.773Hexachlorocyclopentadiene 1 05/08/24 00:56 V46903AMP
<0.142 mg/Kg - dry 0.142 0.773Hexachloroethane 1 05/08/24 00:56 V46903AMP
<0.176 mg/Kg - dry 0.176 0.773Indeno(1,2,3-cd)pyrene 1 05/08/24 00:56 V46903AMP
<0.141 mg/Kg - dry 0.141 0.773Isophorone 1 05/08/24 00:56 V46903AMP
<0.162 mg/Kg - dry 0.162 0.7731-Methylnaphthalene 1 05/08/24 00:56 V46903AMP
<0.168 mg/Kg - dry 0.168 0.7732-Methylnaphthalene 1 05/08/24 00:56 V46903AMP
<0.148 mg/Kg - dry 0.148 0.7732-Methylphenol 1 05/08/24 00:56 V46903AMP
<0.149 mg/Kg - dry 0.149 0.7733&4 Methylphenol 1 05/08/24 00:56 V46903AMP
<0.155 mg/Kg - dry 0.155 0.773Naphthalene 1 05/08/24 00:56 V46903AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 48 of 71
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-123-0002
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Haley Martin
Charlotte
Received : 05/01/2024
AKR-005
Report Date : 05/10/2024
Sample ID :
Lab No :
Sampled:FG-DUP
92440 Matrix:
5/1/2024 0:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):05/06/24 09:20
<0.154 mg/Kg - dry 0.154 0.7732-Nitroaniline 1 05/08/24 00:56 V46903AMP
<0.181 mg/Kg - dry 0.181 0.7733-Nitroaniline 1 05/08/24 00:56 V46903AMP
<0.159 mg/Kg - dry 0.159 0.3854-Nitroaniline 1 05/08/24 00:56 V46903AMP
<0.150 mg/Kg - dry 0.150 0.385Nitrobenzene 1 05/08/24 00:56 V46903AMP
<0.155 mg/Kg - dry 0.155 0.7732-Nitrophenol 1 05/08/24 00:56 V46903AMP
<0.195 mg/Kg - dry 0.195 0.7734-Nitrophenol 1 05/08/24 00:56 V46903AMP
<0.307 mg/Kg - dry 0.307 0.773N-Nitrosodimethylamine 1 05/08/24 00:56 V46903AMP
<0.212 mg/Kg - dry 0.212 0.773N-Nitrosodiphenylamine 1 05/08/24 00:56 V46903AMP
<0.173 mg/Kg - dry 0.173 0.773N-Nitroso-di-n-propylamine 1 05/08/24 00:56 V46903AMP
<0.405 mg/Kg - dry 0.405 1.17Pentachlorophenol 1 05/08/24 00:56 V46903AMP
0.339 J mg/Kg - dry 0.184 0.773Phenanthrene 1 05/08/24 00:56 V46903AMP
<0.166 mg/Kg - dry 0.166 0.773Phenol 1 05/08/24 00:56 V46903AMP
0.353 J mg/Kg - dry 0.187 0.773Pyrene 1 05/08/24 00:56 V46903AMP
<0.089 mg/Kg - dry 0.089 0.385Pyridine 1 05/08/24 00:56 V46903AMP
<0.154 mg/Kg - dry 0.154 0.7731,2,4-Trichlorobenzene 1 05/08/24 00:56 V46903AMP
<0.167 mg/Kg - dry 0.167 0.7732,4,5-Trichlorophenol 1 05/08/24 00:56 V46903AMP
<0.163 mg/Kg - dry 0.163 0.7732,4,6-Trichlorophenol 1 05/08/24 00:56 V46903AMP
Surrogate: Phenol-d5
Surrogate: 2-Fluorobiphenyl
Surrogate: 2-Fluorophenol
Surrogate: Nitrobenzene-d5
Surrogate: 4-Terphenyl-d14
Surrogate: 2,4,6-Tribromophenol
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Page 49 of 71
Quality Control Data
24-123-0002Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
AKR-005
QC Prep Batch Method:
Metals Analyses
6020B
L749451,L749688QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3050B
QC Prep:L748965
Associated Lab Samples: 92436, 92437, 92438, 92439, 92440
LRB-L748965 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
05/09/24 21:280.2500.0855<0.0855mg/KgArsenic
05/08/24 14:200.2500.042<0.042mg/KgBarium
05/08/24 14:200.2500.0260<0.0260mg/KgCadmium
05/08/24 14:200.2500.1160.127mg/KgChromium
05/08/24 14:200.2500.0310<0.0310mg/KgLead
05/08/24 14:200.2500.103<0.103mg/KgSelenium
05/08/24 14:200.2500.0067<0.0067mg/KgSilver
LCS-L748965Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
92.02.302.50mg/KgArsenic 80-120
97.04.835.00mg/KgBarium 80-120
94.00.4680.500mg/KgCadmium 80-120
99.04.945.00mg/KgChromium 80-120
92.02.312.50mg/KgLead 80-120
91.04.575.00mg/KgSelenium 80-120
93.00.4630.500mg/KgSilver 80-120
E 65620-MS-L748965 E 65620-MSD-L748965Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
2.58 95.02.542.482.450.251mg/KgArsenic 92.0 75-125 1.5 80
15.7 10215.64.964.9010.7mg/KgBarium 99.0 75-125 0.6 80
0.817 82.00.7950.4960.4900.414mg/KgCadmium 77.0 75-125 2.7 80
6.63 98.06.554.964.901.84mg/KgChromium 95.0 75-125 1.2 80
Page 1 of 20Date:05/10/2024 01:02 PM
Page 50 of 71
Quality Control Data
24-123-0002Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
AKR-005
QC Prep Batch Method:
Metals Analyses
6020B
L749451,L749688QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3050B
QC Prep:L748965
E 65620-MS-L748965 E 65620-MSD-L748965Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
3.81 93.03.802.482.451.53mg/KgLead 92.0 75-125 0.2 80
4.59 94.04.614.964.90<0.103mg/KgSelenium 93.0 75-125 0.4 80
0.485 94.00.4660.4960.4900.0226mg/KgSilver 89.0 75-125 3.9 80
E 65620-PDS-L748965Post Digestion Spike
Parameter
Analyzed%
Recovery
PDS
ResultUnits
05/09/24 22:5196.01.13mg/KgArsenic
05/08/24 16:271003.38mg/KgBarium
05/09/24 22:5195.00.260mg/KgCadmium
05/08/24 16:2795.02.38mg/KgChromium
05/08/24 16:2798.01.28mg/KgLead
05/08/24 16:2795.02.20mg/KgSelenium
05/09/24 22:5198.00.228mg/KgSilver
Page 2 of 20Date:05/10/2024 01:02 PM
Page 51 of 71
Quality Control Data
24-123-0002Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
AKR-005
QC Prep Batch Method:
Solids Total Mercury Analysis - CVAA
7471B
V46877QC Analytical Batch(es):
Analysis Method:
Analysis Description:
7471B (Prep)
QC Prep:V46852
Associated Lab Samples: 92436, 92437, 92438, 92439, 92440
LRB-V46852 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
05/06/24 14:270.03000.0120<0.0120mg/KgMercury (Total)
LCS-V46852Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
1070.4460.417mg/KgMercury (Total)80-120
V 92256-MS-V46852 V 92256-MSD-V46852Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
0.430 1030.5170.4170.4170.0188mg/KgMercury (Total)124*80-120 18.3 20
V 92256-PDS-V46852Post Digestion Spike
Parameter
Analyzed%
Recovery
PDS
ResultUnits
05/06/24 14:371190.236mg/KgMercury (Total)
Page 3 of 20* QC Fail Date:05/10/2024 01:02 PM
Page 52 of 71
Quality Control Data
24-123-0002Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
AKR-005
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V46835QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V46834
Associated Lab Samples: 92436, 92437, 92438, 92439, 92440
LRB-V46834 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
05/03/24 10:440.0200.002<0.002mg/KgAcetone
05/03/24 10:440.0200.001<0.001mg/KgAcrolein
05/03/24 10:440.0200.0008<0.0008mg/KgAcrylonitrile
05/03/24 10:440.0050.0006<0.0006mg/KgBenzene
05/03/24 10:440.0050.0005<0.0005mg/KgBromobenzene
05/03/24 10:440.0050.0008<0.0008mg/KgBromochloromethane
05/03/24 10:440.0050.001<0.001mg/KgBromodichloromethane
05/03/24 10:440.0050.001<0.001mg/KgBromoform
05/03/24 10:440.0100.001<0.001mg/KgBromomethane
05/03/24 10:440.0050.0005<0.0005mg/Kgn-Butylbenzene
05/03/24 10:440.0050.0006<0.0006mg/Kgsec-Butyl benzene
05/03/24 10:440.0050.0005<0.0005mg/Kgtert-Butyl benzene
05/03/24 10:440.0050.0006<0.0006mg/KgCarbon Disulfide
05/03/24 10:440.0050.001<0.001mg/KgCarbon Tetrachloride
05/03/24 10:440.0050.0007<0.0007mg/KgChlorobenzene
05/03/24 10:440.0050.0009<0.0009mg/KgChlorodibromomethane
05/03/24 10:440.0100.0009<0.0009mg/KgChloroethane
05/03/24 10:440.0050.001<0.001mg/KgChloroform
05/03/24 10:440.0100.0006<0.0006mg/KgChloromethane
05/03/24 10:440.0050.0005<0.0005mg/Kg2-Chlorotoluene
05/03/24 10:440.0050.0004<0.0004mg/Kg4-Chlorotoluene
05/03/24 10:440.0050.0007<0.0007mg/KgDi-Isopropyl Ether (DIPE)
05/03/24 10:440.0100.0004<0.0004mg/Kg1,2-Dibromo-3-Chloropropane
05/03/24 10:440.0050.0006<0.0006mg/Kg1,2-Dibromoethane
05/03/24 10:440.0050.0006<0.0006mg/KgDibromomethane
05/03/24 10:440.0050.0003<0.0003mg/Kg1,2-Dichlorobenzene
05/03/24 10:440.0050.0004<0.0004mg/Kg1,3-Dichlorobenzene
Page 4 of 20Date:05/10/2024 01:02 PM
Page 53 of 71
Quality Control Data
24-123-0002Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
AKR-005
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V46835QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V46834
Associated Lab Samples: 92436, 92437, 92438, 92439, 92440
LRB-V46834 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
05/03/24 10:440.0050.0006<0.0006mg/Kg1,4-Dichlorobenzene
05/03/24 10:440.0100.001<0.001mg/KgDichlorodifluoromethane
05/03/24 10:440.0050.0008<0.0008mg/Kg1,1-Dichloroethane
05/03/24 10:440.0050.001<0.001mg/Kg1,2-Dichloroethane
05/03/24 10:440.0050.0007<0.0007mg/Kg1,1-Dichloroethene
05/03/24 10:440.0050.0008<0.0008mg/Kgcis-1,2-Dichloroethene
05/03/24 10:440.0050.001<0.001mg/Kgtrans-1,2-Dichloroethene
05/03/24 10:440.0050.0004<0.0004mg/Kg1,2-Dichloropropane
05/03/24 10:440.0050.0006<0.0006mg/Kg1,3-Dichloropropane
05/03/24 10:440.0050.001<0.001mg/Kg2,2-Dichloropropane
05/03/24 10:440.0050.0008<0.0008mg/Kg1,1-Dichloropropene
05/03/24 10:440.0050.0005<0.0005mg/Kgcis-1,3-Dichloropropene
05/03/24 10:440.0050.0008<0.0008mg/Kgtrans-1,3-Dichloropropene
05/03/24 10:440.2500.014<0.014mg/KgEthanol
05/03/24 10:440.0050.0006<0.0006mg/KgEthylbenzene
05/03/24 10:440.0500.0008<0.0008mg/KgEthyl Tertiary Butyl Ether (ETBE)
05/03/24 10:440.0100.0008<0.0008mg/KgHexachlorobutadiene
05/03/24 10:440.0100.0007<0.0007mg/Kgn-Hexane
05/03/24 10:440.0200.0006<0.0006mg/Kg2-Hexanone
05/03/24 10:440.0050.0005<0.0005mg/KgIsopropylbenzene
05/03/24 10:440.0050.001<0.001mg/Kg4-Isopropyl toluene
05/03/24 10:440.0200.0007<0.0007mg/KgMethyl Ethyl Ketone (MEK)
05/03/24 10:440.0050.0006<0.0006mg/KgMethyl tert-butyl ether (MTBE)
05/03/24 10:440.0200.015<0.015mg/Kg4-Methyl-2-Pentanone
05/03/24 10:440.0100.001<0.001mg/KgMethylene Chloride
05/03/24 10:440.0100.0010<0.0010mg/KgNaphthalene
05/03/24 10:440.0050.0005<0.0005mg/Kgn-Propylbenzene
Page 5 of 20Date:05/10/2024 01:02 PM
Page 54 of 71
Quality Control Data
24-123-0002Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
AKR-005
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V46835QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V46834
Associated Lab Samples: 92436, 92437, 92438, 92439, 92440
LRB-V46834 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
05/03/24 10:440.0050.001<0.001mg/KgStyrene
05/03/24 10:440.0050.001<0.001mg/Kg1,1,1,2-Tetrachloroethane
05/03/24 10:440.0050.0003<0.0003mg/Kg1,1,2,2-Tetrachloroethane
05/03/24 10:440.0050.0009<0.0009mg/Kg
05/03/24 10:440.0050.0007<0.0007mg/Kg
05/03/24 10:440.0100.0005<0.0005mg/Kg1,2,3-Trichlorobenzene
05/03/24 10:440.0100.0006<0.0006mg/Kg1,2,4-Trichlorobenzene
05/03/24 10:440.0050.001<0.001mg/Kg1,1,1-Trichloroethane
05/03/24 10:440.0050.0005<0.0005mg/Kg1,1,2-Trichloroethane
05/03/24 10:440.0050.0009<0.0009mg/Kg
05/03/24 10:440.0100.002<0.002mg/Kg
05/03/24 10:440.0050.0007<0.0007mg/Kg1,2,3-Trichloropropane
05/03/24 10:440.0050.0005<0.0005mg/Kg1,2,4-Trimethylbenzene
05/03/24 10:440.0050.0005<0.0005mg/Kg1,3,5-Trimethylbenzene
05/03/24 10:440.0100.0005<0.0005mg/KgVinyl Acetate
05/03/24 10:440.0100.0005<0.0005mg/KgVinyl Chloride
05/03/24 10:440.0050.0005<0.0005mg/Kgo-Xylene
05/03/24 10:440.0100.001<0.001mg/Kgm,p-Xylene
05/03/24 10:444-Bromofluorobenzene (S)104 70-130
05/03/24 10:44Dibromofluoromethane (S)99.6 84-123
05/03/24 10:44 104 76-129
LCS-V46834 LCSD-V46834Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.086 86.992.70.0920.100mg/KgAcetone 29-198 6.4 20
Page 6 of 20Date:05/10/2024 01:02 PM
Page 55 of 71
Quality Control Data
24-123-0002Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
AKR-005
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V46835QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V46834
LCS-V46834 LCSD-V46834Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.095 95.21090.1090.100mg/KgAcrolein 70-130 13.5 20
0.089 89.699.80.0990.100mg/KgAcrylonitrile 65-134 10.7 20
0.044 89.085.80.0420.050mg/KgBenzene 74-127 3.6 20
0.048 97.296.00.0480.050mg/KgBromobenzene 73-125 1.2 20
0.044 89.693.60.0460.050mg/KgBromochloromethane 72-134 4.3 20
0.047 94.295.60.0470.050mg/KgBromodichloromethane 75-122 1.4 20
0.045 90.61080.0540.050mg/KgBromoform 66-135 17.7 20
0.037 75.81310.0650.050mg/KgBromomethane 20-180 53.1*20
0.050 1011070.0530.050mg/Kgn-Butylbenzene 65-135 5.3 20
0.046 92.896.60.0480.050mg/Kgsec-Butyl benzene 66-131 4.0 20
0.044 88.892.20.0460.050mg/Kgtert-Butyl benzene 67-132 3.7 20
0.040 81.883.60.0410.050mg/KgCarbon Disulfide 61-129 2.1 20
0.040 81.494.40.0470.050mg/KgCarbon Tetrachloride 64-143 14.7 20
0.045 91.091.80.0450.050mg/KgChlorobenzene 74-118 0.8 20
0.045 90.295.80.0470.050mg/KgChlorodibromomethane 73-122 6.0 20
0.036 73.893.60.0460.050mg/KgChloroethane 33-149 23.6*20
0.044 89.489.00.0440.050mg/KgChloroform 73-127 0.4 20
0.033 66.897.60.0480.050mg/KgChloromethane 45-143 37.4*20
0.046 93.095.40.0470.050mg/Kg2-Chlorotoluene 67-124 2.5 20
0.046 93.095.40.0470.050mg/Kg4-Chlorotoluene 71-126 2.5 20
0.042 85.090.60.0450.050mg/KgDi-Isopropyl Ether (DIPE)59-159 6.3 20
0.035 71.497.60.0480.050mg/Kg1,2-Dibromo-3-Chloropropane 55-157 31.0*20
0.049 98.699.20.0490.050mg/Kg1,2-Dibromoethane 70-132 0.6 20
0.048 96.894.40.0470.050mg/KgDibromomethane 74-133 2.5 20
0.047 95.697.20.0480.050mg/Kg1,2-Dichlorobenzene 72-123 1.6 20
0.046 93.895.20.0470.050mg/Kg1,3-Dichlorobenzene 71-120 1.4 20
Page 7 of 20* QC Fail Date:05/10/2024 01:02 PM
Page 56 of 71
Quality Control Data
24-123-0002Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
AKR-005
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V46835QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V46834
LCS-V46834 LCSD-V46834Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.043 87.690.80.0450.050mg/Kg1,4-Dichlorobenzene 71-123 3.5 20
0.041 82.01160.0570.050mg/KgDichlorodifluoromethane 26-146 34.0*20
0.042 85.286.40.0430.050mg/Kg1,1-Dichloroethane 74-127 1.3 20
0.044 88.891.40.0450.050mg/Kg1,2-Dichloroethane 68-128 2.8 20
0.041 82.486.80.0430.050mg/Kg1,1-Dichloroethene 67-149 5.2 20
0.043 86.888.40.0440.050mg/Kgcis-1,2-Dichloroethene 76-134 1.8 20
0.041 83.488.60.0440.050mg/Kgtrans-1,2-Dichloroethene 73-132 6.0 20
0.045 91.890.80.0450.050mg/Kg1,2-Dichloropropane 73-130 1.0 20
0.048 97.493.60.0460.050mg/Kg1,3-Dichloropropane 75-124 3.9 20
0.042 84.289.80.0440.050mg/Kg2,2-Dichloropropane 50-142 6.4 20
0.042 84.486.60.0430.050mg/Kg1,1-Dichloropropene 71-130 2.5 20
0.048 96.696.60.0480.050mg/Kgcis-1,3-Dichloropropene 71-125 0.0 20
0.049 99.61010.0500.050mg/Kgtrans-1,3-Dichloropropene 68-123 1.5 20
1.02 81.61021.271.25mg/KgEthanol 70-130 21.8*20
0.045 90.090.40.0450.050mg/KgEthylbenzene 74-128 0.4 20
0.089 89.190.70.0900.100mg/KgEthyl Tertiary Butyl Ether (ETBE)70-130 1.7 20
0.036 73.082.40.0410.050mg/KgHexachlorobutadiene 64-125 12.0 20
0.040 80.885.80.0420.050mg/Kgn-Hexane 70-130 6.0 20
0.038 77.887.00.0430.050mg/Kg2-Hexanone 61-157 11.1 20
0.046 92.695.20.0470.050mg/KgIsopropylbenzene 68-126 2.7 20
0.046 93.097.00.0480.050mg/Kg4-Isopropyl toluene 68-129 4.2 20
0.039 79.883.40.0410.050mg/KgMethyl Ethyl Ketone (MEK)63-149 4.4 20
0.045 90.089.20.0440.050mg/KgMethyl tert-butyl ether (MTBE)70-130 0.8 20
0.044 88.099.00.0490.050mg/Kg4-Methyl-2-Pentanone 57-162 11.7 20
0.039 79.284.40.0420.050mg/KgMethylene Chloride 74-129 6.3 20
0.036 72.01000.0500.050mg/KgNaphthalene 57-157 32.7*20
Page 8 of 20* QC Fail Date:05/10/2024 01:02 PM
Page 57 of 71
Quality Control Data
24-123-0002Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
AKR-005
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V46835QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V46834
LCS-V46834 LCSD-V46834Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.046 92.896.40.0480.050mg/Kgn-Propylbenzene 67-130 3.8 20
0.047 94.41060.0530.050mg/KgStyrene 77-121 11.9 20
0.044 89.296.00.0480.050mg/Kg1,1,1,2-Tetrachloroethane 72-115 7.3 20
0.048 96.81020.0500.050mg/Kg1,1,2,2-Tetrachloroethane 56-126 4.8 20
0.042 85.699.00.0490.050mg/Kg 68-130 14.5 20
0.046 92.094.20.0470.050mg/Kg 71-129 2.3 20
0.037 74.491.80.0450.050mg/Kg1,2,3-Trichlorobenzene 68-130 20.9*20
0.037 75.692.20.0460.050mg/Kg1,2,4-Trichlorobenzene 66-125 19.7 20
0.041 82.090.40.0450.050mg/Kg1,1,1-Trichloroethane 67-131 9.7 20
0.048 96.293.80.0460.050mg/Kg1,1,2-Trichloroethane 70-133 2.5 20
0.043 86.292.20.0460.050mg/Kg 75-133 6.7 20
0.041 83.293.80.0460.050mg/Kg 44-146 11.9 20
0.048 96.897.60.0480.050mg/Kg1,2,3-Trichloropropane 60-137 0.8 20
0.048 96.098.00.0490.050mg/Kg1,2,4-Trimethylbenzene 69-129 2.0 20
0.047 94.697.60.0480.050mg/Kg1,3,5-Trimethylbenzene 69-128 3.1 20
0.052 1061070.0530.050mg/KgVinyl Acetate 60-140 1.3 20
0.039 79.01110.0550.050mg/KgVinyl Chloride 48-147 33.3*20
0.045 91.81010.0500.050mg/Kgo-Xylene 74-126 9.5 20
0.091 91.094.10.0940.100mg/Kgm,p-Xylene 75-124 3.3 20
99.697.64-Bromofluorobenzene (S)70-130
93.896.0Dibromofluoromethane (S)84-123
10296.0 76-129
Page 9 of 20* QC Fail Date:05/10/2024 01:02 PM
Page 58 of 71
Quality Control Data
24-123-0002Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
AKR-005
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V46903QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V46854
Associated Lab Samples: 92436, 92437, 92438, 92439, 92440
LRB-V46854 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
05/07/24 16:130.6600.147<0.147mg/KgAcenaphthene
05/07/24 16:130.6600.150<0.150mg/KgAcenaphthylene
05/07/24 16:130.6600.210<0.210mg/KgAniline
05/07/24 16:130.6600.166<0.166mg/KgAnthracene
05/07/24 16:130.6600.156<0.156mg/KgBenzo(a)anthracene
05/07/24 16:130.6600.165<0.165mg/KgBenzo(a)pyrene
05/07/24 16:130.6600.147<0.147mg/KgBenzo(b)fluoranthene
05/07/24 16:130.6600.144<0.144mg/KgBenzo(g,h,i)perylene
05/07/24 16:130.6600.156<0.156mg/KgBenzo(k)fluoranthene
05/07/24 16:132.000.580<0.580mg/KgBenzoic Acid
05/07/24 16:130.6600.156<0.156mg/KgBenzyl alcohol
05/07/24 16:130.6600.138<0.138mg/KgBis(2-Chloroethoxy)methane
05/07/24 16:130.6600.122<0.122mg/KgBis(2-Chloroethyl)ether
05/07/24 16:130.3300.131<0.131mg/KgBis(2-Chloroisopropyl)ether
05/07/24 16:130.6600.177<0.177mg/KgBis(2-ethylhexyl)phthalate
05/07/24 16:130.6600.158<0.158mg/Kg4-Bromophenyl phenyl ether
05/07/24 16:130.3300.160<0.160mg/KgButyl benzyl phthalate
05/07/24 16:130.6600.149<0.149mg/Kg4-Chloro-3-methylphenol
05/07/24 16:130.3300.150<0.150mg/Kg4-Chloroaniline
05/07/24 16:130.6600.154<0.154mg/Kg2-Chloronaphthalene
05/07/24 16:130.6600.142<0.142mg/Kg2-Chlorophenol
05/07/24 16:131.000.147<0.147mg/Kg4-Chlorophenyl phenyl ether
05/07/24 16:130.6600.146<0.146mg/KgChrysene
05/07/24 16:130.6600.111<0.111mg/KgDibenz(a,h)anthracene
05/07/24 16:130.6600.158<0.158mg/KgDibenzofuran
05/07/24 16:130.6600.128<0.128mg/Kg1,2-Dichlorobenzene
05/07/24 16:130.6600.125<0.125mg/Kg1,3-Dichlorobenzene
Page 10 of 20Date:05/10/2024 01:02 PM
Page 59 of 71
Quality Control Data
24-123-0002Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
AKR-005
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V46903QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V46854
Associated Lab Samples: 92436, 92437, 92438, 92439, 92440
LRB-V46854 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
05/07/24 16:130.3300.118<0.118mg/Kg1,4-Dichlorobenzene
05/07/24 16:130.6600.150<0.150mg/Kg3,3'-Dichlorobenzidine
05/07/24 16:130.6600.140<0.140mg/Kg2,4-Dichlorophenol
05/07/24 16:130.6600.147<0.147mg/KgDiethyl phthalate
05/07/24 16:130.6600.157<0.157mg/KgDimethyl phthalate
05/07/24 16:130.6600.212<0.212mg/Kg2,4-Dimethylphenol
05/07/24 16:130.6600.171<0.171mg/KgDi-n-butyl phthalate
05/07/24 16:131.500.240<0.240mg/Kg4,6-Dinitro-2-methylphenol
05/07/24 16:131.500.520<0.520mg/Kg2,4-Dinitrophenol
05/07/24 16:130.6600.161<0.161mg/Kg2,4-Dinitrotoluene
05/07/24 16:130.6600.166<0.166mg/Kg2,6-Dinitrotoluene
05/07/24 16:130.3300.163<0.163mg/KgDi-n-Octyl Phthalate
05/07/24 16:130.6600.158<0.158mg/KgFluoranthene
05/07/24 16:130.6600.153<0.153mg/KgFluorene
05/07/24 16:130.6600.150<0.150mg/KgHexachlorobenzene
05/07/24 16:130.6600.097<0.097mg/KgHexachlorobutadiene
05/07/24 16:130.6600.100<0.100mg/KgHexachlorocyclopentadiene
05/07/24 16:130.6600.122<0.122mg/KgHexachloroethane
05/07/24 16:130.6600.151<0.151mg/KgIndeno(1,2,3-cd)pyrene
05/07/24 16:130.6600.121<0.121mg/KgIsophorone
05/07/24 16:130.6600.139<0.139mg/Kg1-Methylnaphthalene
05/07/24 16:130.6600.144<0.144mg/Kg2-Methylnaphthalene
05/07/24 16:130.6600.127<0.127mg/Kg2-Methylphenol
05/07/24 16:130.6600.128<0.128mg/Kg3&4 Methylphenol
05/07/24 16:130.6600.133<0.133mg/KgNaphthalene
05/07/24 16:130.6600.132<0.132mg/Kg2-Nitroaniline
05/07/24 16:130.6600.155<0.155mg/Kg3-Nitroaniline
Page 11 of 20Date:05/10/2024 01:02 PM
Page 60 of 71
Quality Control Data
24-123-0002Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
AKR-005
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V46903QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V46854
Associated Lab Samples: 92436, 92437, 92438, 92439, 92440
LRB-V46854 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
05/07/24 16:130.3300.136<0.136mg/Kg4-Nitroaniline
05/07/24 16:130.3300.129<0.129mg/KgNitrobenzene
05/07/24 16:130.6600.133<0.133mg/Kg2-Nitrophenol
05/07/24 16:130.6600.167<0.167mg/Kg4-Nitrophenol
05/07/24 16:130.6600.263<0.263mg/KgN-Nitrosodimethylamine
05/07/24 16:130.6600.182<0.182mg/KgN-Nitrosodiphenylamine
05/07/24 16:130.6600.148<0.148mg/KgN-Nitroso-di-n-propylamine
05/07/24 16:131.000.347<0.347mg/KgPentachlorophenol
05/07/24 16:130.6600.158<0.158mg/KgPhenanthrene
05/07/24 16:130.6600.142<0.142mg/KgPhenol
05/07/24 16:130.6600.160<0.160mg/KgPyrene
05/07/24 16:130.3300.076<0.076mg/KgPyridine
05/07/24 16:130.6600.132<0.132mg/Kg1,2,4-Trichlorobenzene
05/07/24 16:130.6600.143<0.143mg/Kg2,4,5-Trichlorophenol
05/07/24 16:130.6600.140<0.140mg/Kg2,4,6-Trichlorophenol
05/07/24 16:132-Fluorobiphenyl (S)88.0 44-115
05/07/24 16:132-Fluorophenol (S)90.3 35-115
05/07/24 16:13Nitrobenzene-d5 (S)85.0 37-122
05/07/24 16:134-Terphenyl-d14 (S)89.2 54-127
05/07/24 16:132,4,6-Tribromophenol (S)82.8 39-132
05/07/24 16:13Phenol-d5 (S)94.8 34-121
LCS-V46854Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
91.01.521.67mg/KgAcenaphthene 40-123
98.81.651.67mg/KgAcenaphthylene 32-132
Page 12 of 20Date:05/10/2024 01:02 PM
Page 61 of 71
Quality Control Data
24-123-0002Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
AKR-005
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V46903QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V46854
LCS-V46854Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
1572.631.67mg/KgAniline 12-197
94.01.571.67mg/KgAnthracene 47-123
93.41.561.67mg/KgBenzo(a)anthracene 49-126
1262.111.67mg/KgBenzo(a)pyrene 45-129
1282.141.67mg/KgBenzo(b)fluoranthene 45-132
1131.881.67mg/KgBenzo(g,h,i)perylene 43-134
95.81.601.67mg/KgBenzo(k)fluoranthene 47-132
126*2.101.67mg/KgBenzoic Acid 10-83
1051.761.67mg/KgBenzyl alcohol 29-122
86.81.451.67mg/KgBis(2-Chloroethoxy)methane 36-121
74.81.251.67mg/KgBis(2-Chloroethyl)ether 31-120
80.21.341.67mg/KgBis(2-Chloroisopropyl)ether 33-131
1041.741.67mg/KgBis(2-ethylhexyl)phthalate 51-133
90.41.511.67mg/Kg4-Bromophenyl phenyl ether 46-124
1031.721.67mg/KgButyl benzyl phthalate 48-132
1071.791.67mg/Kg4-Chloro-3-methylphenol 45-122
94.61.581.67mg/Kg4-Chloroaniline 17-106
88.61.481.67mg/Kg2-Chloronaphthalene 41-114
95.81.601.67mg/Kg2-Chlorophenol 34-121
86.81.451.67mg/Kg4-Chlorophenyl phenyl ether 45-121
77.21.291.67mg/KgChrysene 50-124
40.4*0.6751.67mg/KgDibenz(a,h)anthracene 45-134
95.21.591.67mg/KgDibenzofuran 44-120
86.21.441.67mg/Kg1,2-Dichlorobenzene 33-117
80.21.341.67mg/Kg1,3-Dichlorobenzene 30-115
74.21.241.67mg/Kg1,4-Dichlorobenzene 31-115
85.01.421.67mg/Kg3,3'-Dichlorobenzidine 22-121
Page 13 of 20* QC Fail Date:05/10/2024 01:02 PM
Page 62 of 71
Quality Control Data
24-123-0002Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
AKR-005
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V46903QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V46854
LCS-V46854Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
1021.711.67mg/Kg2,4-Dichlorophenol 40-122
99.41.661.67mg/KgDiethyl phthalate 50-124
99.41.661.67mg/KgDimethyl phthalate 48-124
129*2.161.67mg/Kg2,4-Dimethylphenol 30-127
95.81.601.67mg/KgDi-n-butyl phthalate 51-128
1081.811.67mg/Kg4,6-Dinitro-2-methylphenol 29-132
1292.151.67mg/Kg2,4-Dinitrophenol 27-129
1021.701.67mg/Kg2,4-Dinitrotoluene 48-126
1202.011.67mg/Kg2,6-Dinitrotoluene 46-124
1312.181.67mg/KgDi-n-Octyl Phthalate 45-140
97.01.621.67mg/KgFluoranthene 50-127
97.01.621.67mg/KgFluorene 43-125
91.01.521.67mg/KgHexachlorobenzene 45-122
96.41.611.67mg/KgHexachlorobutadiene 32-123
82.01.371.67mg/KgHexachlorocyclopentadiene 32-117
76.01.271.67mg/KgHexachloroethane 28-117
1292.161.67mg/KgIndeno(1,2,3-cd)pyrene 45-133
76.01.271.67mg/KgIsophorone 30-122
90.41.511.67mg/Kg1-Methylnaphthalene 40-119
91.61.531.67mg/Kg2-Methylnaphthalene 38-122
97.01.621.67mg/Kg2-Methylphenol 32-122
88.61.481.67mg/Kg3&4 Methylphenol 34-119
85.61.431.67mg/KgNaphthalene 35-123
99.41.661.67mg/Kg2-Nitroaniline 44-127
1011.681.67mg/Kg3-Nitroaniline 33-119
1111.851.67mg/Kg4-Nitroaniline 63-147
87.41.461.67mg/KgNitrobenzene 34-122
Page 14 of 20* QC Fail Date:05/10/2024 01:02 PM
Page 63 of 71
Quality Control Data
24-123-0002Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
AKR-005
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V46903QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V46854
LCS-V46854Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
94.01.571.67mg/Kg2-Nitrophenol 36-123
98.21.641.67mg/Kg4-Nitrophenol 30-132
70.01.171.67mg/KgN-Nitrosodimethylamine 10-146
1131.881.67mg/KgN-Nitrosodiphenylamine 38-127
95.81.601.67mg/KgN-Nitroso-di-n-propylamine 36-120
1091.821.67mg/KgPentachlorophenol 25-133
93.41.561.67mg/KgPhenanthrene 50-121
93.41.561.67mg/KgPhenol 34-121
90.41.511.67mg/KgPyrene 47-127
52.40.8761.67mg/KgPyridine 10-80
86.81.451.67mg/Kg1,2,4-Trichlorobenzene 34-118
1061.771.67mg/Kg2,4,5-Trichlorophenol 41-124
1031.721.67mg/Kg2,4,6-Trichlorophenol 39-126
89.22-Fluorobiphenyl (S)44-115
91.82-Fluorophenol (S)35-115
87.4Nitrobenzene-d5 (S)37-122
86.24-Terphenyl-d14 (S)54-127
97.52,4,6-Tribromophenol (S)39-132
96.9Phenol-d5 (S)34-121
V 91797-MS-V46854 V 91797-MSD-V46854Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
1.35 80.81.321.671.67<0.588mg/KgAcenaphthene 79.0 40-123 2.2 20
1.43 85.61.511.671.67<0.600mg/KgAcenaphthylene 90.4 32-132 5.4 20
1.49 89.21.401.671.67<0.839mg/KgAniline 83.8 12-197 6.2 20
Page 15 of 20Date:05/10/2024 01:02 PM
Page 64 of 71
Quality Control Data
24-123-0002Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
AKR-005
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V46903QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V46854
V 91797-MS-V46854 V 91797-MSD-V46854Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
1.39 83.21.431.671.67<0.664mg/KgAnthracene 85.6 47-123 2.8 20
1.46 87.41.531.671.67<0.624mg/KgBenzo(a)anthracene 91.6 49-126 4.6 20
1.76 1051.751.671.67<0.660mg/KgBenzo(a)pyrene 105 45-129 0.5 20
1.67 1001.871.671.67<0.588mg/KgBenzo(b)fluoranthene 112 45-132 11.2 20
1.54 92.21.471.671.67<0.576mg/KgBenzo(g,h,i)perylene 88.0 43-134 4.6 20
1.34 80.21.111.671.67<0.624mg/KgBenzo(k)fluoranthene 66.4 47-132 18.7 20
3.63 217*3.631.671.67<2.32mg/KgBenzoic Acid 217*10-83 0.0 20
1.31 78.41.391.671.67<0.624mg/KgBenzyl alcohol 83.2 29-122 5.9 20
1.19 71.21.191.671.67<0.552mg/KgBis(2-Chloroethoxy)methane 71.2 36-121 0.0 20
0.986 59.01.001.671.67<0.488mg/KgBis(2-Chloroethyl)ether 59.8 31-120 1.4 20
1.08 64.61.111.671.67<0.524mg/KgBis(2-Chloroisopropyl)ether 66.4 33-131 2.7 20
2.14 1282.151.671.67<0.708mg/KgBis(2-ethylhexyl)phthalate 129 51-133 0.4 20
1.31 78.41.661.671.67<0.632mg/Kg4-Bromophenyl phenyl ether 99.4 46-124 23.5*20
2.09 1252.311.671.67<0.640mg/KgButyl benzyl phthalate 138*48-132 10.0 20
1.51 90.41.581.671.67<0.596mg/Kg4-Chloro-3-methylphenol 94.6 45-122 4.5 20
1.05 62.81.101.671.67<0.600mg/Kg4-Chloroaniline 65.8 17-106 4.6 20
1.29 77.21.311.671.67<0.616mg/Kg2-Chloronaphthalene 78.4 41-114 1.5 20
1.23 73.61.291.671.67<0.568mg/Kg2-Chlorophenol 77.2 34-121 4.7 20
1.28 76.61.311.671.67<0.588mg/Kg4-Chlorophenyl phenyl ether 78.4 45-121 2.3 20
1.61 96.40.9581.671.67<0.584mg/KgChrysene 57.3 50-124 50.7*20
2.13 1281.291.671.67<0.444mg/KgDibenz(a,h)anthracene 77.2 45-134 49.1*20
1.34 80.21.381.671.67<0.632mg/KgDibenzofuran 82.6 44-120 2.9 20
1.14 68.21.161.671.67<0.512mg/Kg1,2-Dichlorobenzene 69.4 33-117 1.7 20
1.13 67.61.141.671.67<0.500mg/Kg1,3-Dichlorobenzene 68.2 30-115 0.8 20
1.10 65.81.111.671.67<0.472mg/Kg1,4-Dichlorobenzene 66.4 31-115 0.9 20
1.24 74.21.181.671.67<0.600mg/Kg3,3'-Dichlorobenzidine 70.6 22-121 4.9 20
Page 16 of 20* QC Fail Date:05/10/2024 01:02 PM
Page 65 of 71
Quality Control Data
24-123-0002Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
AKR-005
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V46903QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V46854
V 91797-MS-V46854 V 91797-MSD-V46854Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
1.37 82.01.501.671.67<0.560mg/Kg2,4-Dichlorophenol 89.8 40-122 9.0 20
1.38 82.61.461.671.67<0.588mg/KgDiethyl phthalate 87.4 50-124 5.6 20
1.41 84.41.411.671.67<0.628mg/KgDimethyl phthalate 84.4 48-124 0.0 30
1.81 1081.911.671.67<0.848mg/Kg2,4-Dimethylphenol 114 30-127 5.3 20
1.77 1061.841.671.67<0.684mg/KgDi-n-butyl phthalate 110 51-128 3.8 20
2.98 178*3.041.671.67<0.960mg/Kg4,6-Dinitro-2-methylphenol 182*29-132 1.9 20
3.78 226*3.911.671.67<2.08mg/Kg2,4-Dinitrophenol 234*27-129 3.3 20
1.82 1091.741.671.67<0.644mg/Kg2,4-Dinitrotoluene 104 48-126 4.4 20
1.81 1081.981.671.67<0.664mg/Kg2,6-Dinitrotoluene 119 46-124 8.9 20
2.56 153*2.601.671.67<0.652mg/KgDi-n-Octyl Phthalate 156*45-140 1.5 20
1.47 88.01.511.671.67<0.632mg/KgFluoranthene 90.4 50-127 2.6 20
1.34 80.21.381.671.67<0.612mg/KgFluorene 82.6 43-125 2.9 20
1.36 81.41.371.671.67<0.600mg/KgHexachlorobenzene 82.0 45-122 0.7 20
1.45 86.81.411.671.67<0.390mg/KgHexachlorobutadiene 84.4 32-123 2.7 20
1.24 74.21.271.671.67<0.400mg/KgHexachlorocyclopentadiene 76.0 32-117 2.3 20
1.06 63.41.151.671.67<0.488mg/KgHexachloroethane 68.8 28-117 8.1 20
1.93 1161.891.671.67<0.604mg/KgIndeno(1,2,3-cd)pyrene 113 45-133 2.0 20
0.960 57.41.031.671.67<0.484mg/KgIsophorone 61.6 30-122 7.0 20
1.29 77.21.381.671.67<0.556mg/Kg1-Methylnaphthalene 82.6 40-119 6.7 20
1.38 82.61.351.671.67<0.576mg/Kg2-Methylnaphthalene 80.8 38-122 2.1 20
1.29 77.21.271.671.67<0.508mg/Kg2-Methylphenol 76.0 32-122 1.5 20
1.18 70.61.181.671.67<0.510mg/Kg3&4 Methylphenol 70.6 34-119 0.0 20
1.24 74.21.241.671.67<0.532mg/KgNaphthalene 74.2 35-123 0.0 20
1.71 1021.781.671.67<0.528mg/Kg2-Nitroaniline 107 44-127 4.0 20
1.41 84.41.441.671.67<0.620mg/Kg3-Nitroaniline 86.2 33-119 2.1 20
1.46 87.41.371.671.67<0.544mg/Kg4-Nitroaniline 82.0 63-147 6.3 20
Page 17 of 20* QC Fail Date:05/10/2024 01:02 PM
Page 66 of 71
Quality Control Data
24-123-0002Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
AKR-005
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V46903QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V46854
V 91797-MS-V46854 V 91797-MSD-V46854Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
1.13 67.61.181.671.67<0.516mg/KgNitrobenzene 70.6 34-122 4.3 20
1.87 1121.921.671.67<0.532mg/Kg2-Nitrophenol 115 32-123 2.6 20
1.98 1191.991.671.67<0.668mg/Kg4-Nitrophenol 119 30-132 0.5 20
<1.05 0.0*<1.051.671.67<1.05mg/KgN-Nitrosodimethylamine 0.0*10-146 0.0 30
1.62 97.01.671.671.67<0.728mg/KgN-Nitrosodiphenylamine 100 38-127 3.0 20
1.24 74.21.251.671.67<0.592mg/KgN-Nitroso-di-n-propylamine 74.8 36-120 0.8 20
2.29 137*2.261.671.67<1.39mg/KgPentachlorophenol 135*25-133 1.3 20
1.35 80.81.361.671.67<0.632mg/KgPhenanthrene 81.4 50-121 0.7 20
1.16 69.41.181.671.67<0.568mg/KgPhenol 70.6 34-121 1.7 20
1.30 77.81.341.671.67<0.640mg/KgPyrene 80.2 47-127 3.0 20
<0.307 0.0*<0.3071.671.67<0.307mg/KgPyridine 0.0*10-80 0.0 20
1.23 73.61.271.671.67<0.528mg/Kg1,2,4-Trichlorobenzene 76.0 34-118 3.2 20
1.34 80.21.541.671.67<0.572mg/Kg2,4,5-Trichlorophenol 92.2 41-124 13.8 20
1.44 86.21.391.671.67<0.560mg/Kg2,4,6-Trichlorophenol 83.2 39-126 3.5 20
73.62-Fluorobiphenyl (S)75.4 44-115
73.22-Fluorophenol (S)70.5 35-115
70.0Nitrobenzene-d5 (S)72.4 37-122
72.44-Terphenyl-d14 (S)73.6 54-127
93.02,4,6-Tribromophenol (S)94.8 39-132
76.5Phenol-d5 (S)74.1 34-121
Page 18 of 20* QC Fail Date:05/10/2024 01:02 PM
Page 67 of 71
Quality Control Data
24-123-0002Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
AKR-005
QC Prep Batch Method:
Hexavalent Chromium by Ion Chromatography
SW-7199
L749458QC Analytical Batch(es):
Analysis Method:
Analysis Description:
SW-3060A
QC Prep:L749006
Associated Lab Samples: 92436, 92437, 92438, 92439, 92440
LRB-L749006 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
05/08/24 19:450.2000.141<0.141mg/KgChromium, Hexavalent
LCS-L749006Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
89.03.564.00mg/KgChromium, Hexavalent 80-120
V 92436-DUP-L749006Duplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 05/08/24 20:1716.0<0.2000.235mg/KgChromium, Hexavalent
Page 19 of 20Date:05/10/2024 01:02 PM
Page 68 of 71
Quality Control Data
24-123-0002Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
AKR-005
Dry Weight Determination
SW-DRYWT
V46805QC Analytical Batch:
Analysis Method:
Analysis Description:
V 92592-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 05/03/24 12:411.117.517.3%Moisture
V 92593-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 05/03/24 12:411.018.819.0%Moisture
Page 20 of 20Date:05/10/2024 01:02 PM
Page 69 of 71
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:24-123-0002
Hart & Hickman (Charlotte)
01102
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 2.6C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)?Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
ü
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)ü
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:05/02/2024 08:50:59
Special precautions or instructions included?
Comments:
Page 70 of 71
Page 71 of 71

Appendix B
DEQ Risk Calculator
Version Date:
Basis:
Site Name:
Site Address:
DEQ Section:
Site ID:
Exposure Unit ID:
Submittal Date:
Reviewed By:
Final Grade - Hypothetical Worst Case
North Carolina Department of Environmental Quality
Risk Calculator
Crayton Printing
Distribution Street and Dunavant Street, Charlotte, NC
Brownfields Redvelopment
24025-20-060
February 2024
November 2023 EPA RSL Table
5/1/2024
Prepared By:Hart & Hickman, PC
2923 S. Tryon Street, Suite 100, Charlotte, NC 28203
Hart & Hickman, PC
North Carolina DEQ Risk Calculator
Complete Exposure Pathways
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Final Grade - Hypothetical Worst Case
Note: Risk output will only be calculated for complete exposure pathways.
Receptor Pathway
Check box if
pathway
complete
Soil
Groundwater Use
Soil
Groundwater Use
Construction Worker Soil
Soil
Surface Water
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Source Soil
Source Groundwater
Source Soil
Source Groundwater
Resident
Non-Residential Worker
CONTAMINANT MIGRATION PATHWAYS
Groundwater
Surface Water
Input Form 1A
VAPOR INTRUSION PATHWAYS
DIRECT CONTACT SOIL AND WATER PATHWAYS
Resident
Non-Residential Worker
Recreator/Trespasser
North Carolina DEQ Risk Calculator
Exposure Point Concentrations
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Final Grade - Hypothetical Worst Case
NOTE: If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations
Exposure Point
Concentration
(mg/kg)
Notes: CAS Number
Chemical
For the chemicals highlighted in blue, data entry notes are provided in the
PSRG Table link on the Main Menu
Minimum
Concentration
(Qualifier)
Maximum
Concentration
(Qualifier)
Units
Location of
Maximum
Concentration
Detection
Frequency
Range of
Detection Limits
Concentration
Used for
Screening
Background
Value
Screening
Toxicity Value
(Screening
Level) (n/c)
Potential
ARAR/TBC
Value
Potential
ARAR/TBC
Source
COPC
Flag
(Y/N)
Rationale for
Selection or
Deletion
0.021 J 67-64-1 Acetone mg/kg
1.21 7440-38-2 Arsenic, Inorganic mg/kg
101 7440-39-3 Barium mg/kg
0.002 J 75-15-0 Carbon Disulfide mg/kg
45.7 16065-83-1 Chromium(III), Insoluble Salts mg/kg
0.477 18540-29-9 Chromium(VI)mg/kg
0.001 J 110-54-3 Hexane, N-mg/kg
10.5 7439-92-1 ~Lead and Compounds mg/kg
0.0173 J 7487-94-7 ~Mercuric Chloride (and other Mercury salts)mg/kg
0.005 J 75-09-2 Methylene Chloride mg/kg
0.231 J 117-81-7 ~Bis(2-ethylhexyl)phthalate mg/kg
0.246 J 83-32-9 ~Acenaphthene mg/kg
0.622 J 120-12-7 ~Anthracene mg/kg
1.34 56-55-3 ~Benz[a]anthracene
1.11 50-32-8 ~Benzo[a]pyrene mg/kg
1.41 205-99-2 ~Benzo[b]fluoranthene mg/kg
0.386 J 207-08-9 ~Benzo[k]fluoranthene mg/kg
0.962 218-01-9 ~Chrysene mg/kg
0.254 J, M 53-70-3 ~Dibenz[a,h]anthracene mg/kg
2.5 206-44-0 ~Fluoranthene mg/kg
0.24 J 86-73-7 ~Fluorene mg/kg
0.747 193-39-5 ~Indeno[1,2,3-cd]pyrene mg/kg
1.63 129-00-0 ~Pyrene mg/kg
0.216 J 7782-49-2 Selenium mg/kg
Input Form 2A
Soil Exposure Point Concentration Table
Description of Exposure Point Concentration Selection:
North Carolina DEQ Risk Calculator
Risk for Individual Pathways Output Form 1A
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Final Grade - Hypothetical Worst Case
Receptor Pathway Carcinogenic
Ris Hazard Index Risk exceeded?
Soil 1.8E-05 1.1E-01 NO
Groundwater Use* NC NC NC
Soil 1.3E-06 8.3E-03 NO
Groundwater Use* NC NC NC
Construction Worker Soil NC NC NC
Soil NC NC NC
Surface Water* NC NC NC
Receptor Pathway Carcinogenic
Ris Hazard Index Risk exceeded?
Groundwater to Indoor Air NC NC NC
Soil Gas to Indoor Air NC NC NC
Indoor Air NC NC NC
Groundwater to Indoor Air NC NC NC
Soil Gas to Indoor Air NC NC NC
Indoor Air NC NC NC
Pathway Source
Source Soil NC
Source Groundwater NC
Source Soil NC
Source Groundwater NC
Groundwater Exceedence of 2L at Receptor?
Exceedence of 2L at Receptor?
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead
concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
Notes:
3. NM = Not modeled, user did not check this pathway as complete.
4. NC = Pathway not calculated, required contaminant migration parameters were not entered.
DIRECT CONTACT SOIL AND WATER CALCULATORS
Resident
Non-Residential Worker
Recreator/Trespasser
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the
NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based
closure.
Surface Water Exceedence of 2B at Receptor?
Exceedence of 2B at Receptor?
VAPOR INTRUSION CALCULATORS
Resident
Non-Residential Worker
CONTAMINANT MIGRATION CALCULATORS
Target Receptor Concentrations Exceeded?
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Direct Contact - Resident Soil
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Final Grade - Hypothetical Worst Case
* - Note that inhalation on this calculator refers to outdoor inhalation of volatiles and particulates, not indoor inhalation associated with vapor intrusion.
CAS # Chemical Name:
Ingestion
Concentration
(mg/kg)
Dermal
Concentration
(mg/kg)
Inhalation
Concentration
(mg/kg)*
Ingestion
Carcinogenic
Risk
Dermal
Carcinogenic
Risk
Inhalation
Carcinogenic
Risk*
Calculated
Carcinogenic
Risk
Ingestion
Hazard
Quotient
Dermal
Hazard
Quotient
Inhalation
Hazard
Quotient*
Calculated
Non-
Carcinogenic
Hazard
Quotient
67-64-1 Acetone 0.021 0.021 0.021 3.0E-07 3.0E-07
7440-38-2 Arsenic, Inorganic 1.21 1.21 1.21 1.6E-06 2.2E-07 3.1E-11 1.8E-06 3.1E-02 3.7E-03 1.3E-06 3.5E-02
7440-39-3 Barium 101 101 101 6.5E-03 3.3E-06 6.5E-03
75-15-0 Carbon Disulfide 0.002 0.002 0.002 2.6E-07 8.7E-07 1.1E-06
16065-83-1 Chromium(III), Insoluble Salts 45.7 45.7 45.7 3.9E-04 3.9E-04
18540-29-9 Chromium(VI) 0.477 0.477 0.477 1.6E-06 6.7E-10 1.6E-06 2.0E-03 7.7E-08 2.0E-03
110-54-3 Hexane, N- 0.001 0.001 0.001 4.4E-07 4.4E-07
7439-92-1 ~Lead and Compounds 10.5 10.5 10.5 <SL** <SL** <SL**
7487-94-7 ~Mercuric Chloride (and other Mercury salts) 0.0173 0.0173 0.0173 7.4E-04 9.3E-10 7.4E-04
75-09-2 Methylene Chloride 0.005 0.005 0.005 6.5E-11 1.6E-11 8.1E-11 1.1E-05 2.5E-06 1.3E-05
117-81-7 ~Bis(2-ethylhexyl)phthalate 0.231 0.231 0.231 4.7E-09 1.3E-09 3.3E-15 6.0E-09 1.5E-04 3.5E-05 1.8E-04
83-32-9 ~Acenaphthene 0.246 0.246 0.246 5.2E-05 1.6E-05 6.9E-05
120-12-7 ~Anthracene 0.622 0.622 0.622 2.7E-05 8.2E-06 3.5E-05
56-55-3 ~Benz[a]anthracene 1.34 1.34 1.34 8.7E-07 2.9E-07 1.7E-08 1.2E-06
50-32-8 ~Benzo[a]pyrene 1.11 1.11 1.11 7.2E-06 2.4E-06 1.1E-11 9.7E-06 4.7E-02 1.5E-02 9.0E-06 6.2E-02
205-99-2 ~Benzo[b]fluoranthene 1.41 1.41 1.41 9.2E-07 3.1E-07 1.4E-12 1.2E-06
207-08-9 ~Benzo[k]fluoranthene 0.386 0.386 0.386 2.5E-08 8.4E-09 3.9E-14 3.4E-08
218-01-9 ~Chrysene 0.962 0.962 0.962 6.3E-09 2.1E-09 9.6E-15 8.4E-09
53-70-3 ~Dibenz[a,h]anthracene 0.254 0.254 0.254 1.7E-06 5.5E-07 2.5E-12 2.2E-06
206-44-0 ~Fluoranthene 2.5 2.5 2.5 8.0E-04 2.5E-04 1.0E-03
86-73-7 ~Fluorene 0.24 0.24 0.24 7.7E-05 2.4E-05 1.0E-04
193-39-5 ~Indeno[1,2,3-cd]pyrene 0.747 0.747 0.747 4.9E-07 1.6E-07 7.5E-13 6.5E-07
129-00-0 ~Pyrene 1.63 1.63 1.63 6.9E-04 2.1E-04 9.1E-04
7782-49-2 Selenium 0.216 0.216 0.216 5.5E-04 1.7E-10 5.5E-04
Cumulative: 1.8E-05 1.1E-01
Out ut Form
** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate cancer risk or hazard quotient. Lead concentrations are compared to the EPA screening level of 200 mg/kg for residential soil. If it has been demonstrated that additional sources of lead are present (e.g., lead water service lines or lead-based paint), the EPA screening level is 100 mg/kg, which is used below for comparison to be
conservative.
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Direct Contact - Non-Residential Worker Soil
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Final Grade - Hypothetical Worst Case
* - Note that inhalation on this calculator refers to outdoor inhalation of volatiles and particulates, not indoor inhalation associated with vapor intrusion.
CAS # Chemical Name:
Ingestion
Concentration
(mg/kg)
Dermal
Concentration
(mg/kg)
Inhalation
Concentration
(mg/kg)*
Ingestion
Carcinogenic
Risk
Dermal
Carcinogenic
Risk
Inhalation
Carcinogenic
Risk
Calculated
Carcinogenic
Risk
Ingestion
Hazard
Quotient
Dermal
Hazard
Quotient
Inhalation
Hazard
Quotient
Calculated
Non-
Carcinogenic
Hazard
Quotient
67-64-1 Acetone 0.021 0.021 0.021 2.0E-08 2.0E-08
7440-38-2 Arsenic, Inorganic 1.21 1.21 1.21 3.3E-07 7.0E-08 7.2E-12 4.0E-07 2.1E-03 4.4E-04 3.1E-07 2.5E-03
7440-39-3 Barium 101 101 101 4.3E-04 7.8E-07 4.3E-04
75-15-0 Carbon Disulfide 0.002 0.002 0.002 1.7E-08 2.1E-07 2.2E-07
16065-83-1 Chromium(III), Insoluble Salts 45.7 45.7 45.7 2.6E-05 2.6E-05
18540-29-9 Chromium(VI) 0.477 0.477 0.477 7.3E-08 5.5E-11 7.3E-08 1.4E-04 1.8E-08 1.4E-04
110-54-3 Hexane, N- 0.001 0.001 0.001 1.0E-07 1.0E-07
7439-92-1 ~Lead and Compounds 10.5 10.5 10.5 <SL** <SL** <SL**
7487-94-7 ~Mercuric Chloride (and other Mercury salts) 0.0173 0.0173 0.0173 4.9E-05 2.2E-10 4.9E-05
75-09-2 Methylene Chloride 0.005 0.005 0.005 3.1E-12 1.3E-12 4.4E-12 7.1E-07 6.1E-07 1.3E-06
117-81-7 ~Bis(2-ethylhexyl)phthalate 0.231 0.231 0.231 9.9E-10 4.2E-10 7.6E-16 1.4E-09 9.9E-06 4.2E-06 1.4E-05
83-32-9 ~Acenaphthene 0.246 0.246 0.246 3.5E-06 1.9E-06 5.4E-06
120-12-7 ~Anthracene 0.622 0.622 0.622 1.8E-06 9.8E-07 2.8E-06
56-55-3 ~Benz[a]anthracene 1.34 1.34 1.34 4.1E-08 2.3E-08 1.4E-09 6.5E-08
50-32-8 ~Benzo[a]pyrene 1.11 1.11 1.11 3.4E-07 1.9E-07 9.2E-13 5.3E-07 3.2E-03 1.7E-03 2.1E-06 4.9E-03
205-99-2 ~Benzo[b]fluoranthene 1.41 1.41 1.41 4.3E-08 2.4E-08 1.2E-13 6.7E-08
207-08-9 ~Benzo[k]fluoranthene 0.386 0.386 0.386 1.2E-09 6.5E-10 3.2E-15 1.8E-09
218-01-9 ~Chrysene 0.962 0.962 0.962 2.9E-10 1.6E-10 7.9E-16 4.6E-10
53-70-3 ~Dibenz[a,h]anthracene 0.254 0.254 0.254 7.8E-08 4.3E-08 2.1E-13 1.2E-07206-44-0 ~Fluoranthene 2.5 2.5 2.5 5.4E-05 2.9E-05 8.3E-05
86-73-7 ~Fluorene 0.24 0.24 0.24 5.1E-06 2.8E-06 8.0E-06
193-39-5 ~Indeno[1,2,3-cd]pyrene 0.747 0.747 0.747 2.3E-08 1.3E-08 6.2E-14 3.5E-08
129-00-0 ~Pyrene 1.63 1.63 1.63 4.7E-05 2.6E-05 7.2E-05
7782-49-2 Selenium 0.216 0.216 0.216 3.7E-05 4.2E-11 3.7E-05
Cumulative: 1.3E-06 8.3E-03
Output Form 2C
** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate cancer risk or hazard quotient. Lead concentrations are compared to the EPA screening level of 800
mg/kg for commercial/industrial soil.
North Carolina DEQ Risk Calculator