MO-29963_49049_CA_TECHDA_ 20230531

05/31/23
Technical Report for
Murphy Oil USA, Inc.
GESWCSC: Murphy #7214, Albemarle, NC
SGS Job Number: LA90738
Sampling Date: 05/15/23
Report to:
GES
104 Corporate Blvd, Ste 411
West Columbia, SC 29169
[e-mail]; [e-mail]
ATTN: Daniel Dabkowski, Tom Chmura
Total number of pages in report:
Certifications: LDEQ(2048), LDHH(LA150012), AR(14-045-04), AZ(AZ0805), FL(E87657), IL(200082), KY(#31),
NC(487), SC(73004001), NJ(LA007), TX(T104704186-18-16), WV(257)
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc.  500 Ambassador Caffery  Scott, LA 70583  tel: [phone]
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Suzanne Junkin 337-237-4775
Kesavalu Bagawandoss
General Manager
Scott, LA 05/31/23
e-Hardcopy 2.0
Automated Report
61
SGS is the sole authority for authorizing edits or modifications to this document.
Unauthorized modification of this report is strictly prohibited.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions
The results set forth herein are provided by SGS North America Inc.
Please share your ideas about
how we can serve you better at:
[e-mail]
1 of 61
LA90738
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Case Narrative/Conformance Summary ..............................................................4
Section 3: Summary of Hits ....................................................................................................6
Section 4: Sample Results ........................................................................................................7
4.1: LA90738-1: OW-1 ........................................................................................................8
4.2: LA90738-2: OW-2 ........................................................................................................18
Section 5: Misc. Forms ............................................................................................................28
5.1: Chain of Custody ...........................................................................................................29
Section 6: MS Volatiles - QC Data Summaries .....................................................................32
6.1: Method Blank Summary ................................................................................................33
6.2: Blank Spike/Blank Spike Duplicate Summary ..............................................................35
6.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................38
Section 7: MS Semi-volatiles - QC Data Summaries ............................................................41
7.1: Method Blank Summary ................................................................................................42
7.2: Blank Spike/Blank Spike Duplicate Summary ..............................................................45
Section 8: GC Volatiles - QC Data Summaries .....................................................................47
8.1: Method Blank Summary ................................................................................................48
8.2: Blank Spike/Blank Spike Duplicate Summary ..............................................................50
8.3: Duplicate Summary .......................................................................................................52
Section 9: GC/LC Semi-volatiles - QC Data Summaries .....................................................53
9.1: Method Blank Summary ................................................................................................54
9.2: Blank Spike/Blank Spike Duplicate Summary ..............................................................55
Section 10: Metals Analysis - QC Data Summaries ..............................................................56
10.1: Prep QC MP26340: Pb ................................................................................................57
1
2
3
4
5
6
7
8
9
10
2 of 61
LA90738
SGS North America Inc.
Sample Summary
Murphy Oil USA, Inc.
Job No:LA90738
GESWCSC: Murphy #7214, Albemarle, NC
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
LA90738-1 05/15/23 12:15 05/19/23 AQ Ground Water OW-1
LA90738-2 05/15/23 12:55 05/19/23 AQ Ground Water OW-2
3 of 61
LA90738
1
Two samples, 0 trip blanks and 0 field blanks were collected on 05/15/2023 and received intact at SGS North America Inc.-Scott
(SGS) on 05/19/2023, properly preserved and cool at 0.6 Deg C. These samples received an SGS job number of LA90738. A listing
of the Laboratory Sample ID, Client Sample ID and dates of collection are presented in the Results Summary Section of this report.
Per the client, the wrong COC was used in the field, this is the Albemarle, NC site Murphy 7214.
Except as noted below, all method specified calibrations and quality control performance criteria were met for this job. For more
information, please refer to QC summary pages.
Client:Murphy Oil USA, Inc.
Site:GESWCSC: Murphy #7214, Albemarle, NC
Job No:LA90738
Report Date 5/31/2023 8:41:05 AM
SAMPLE DELIVERY GROUP CASE NARRATIVE
MS Volatiles By Method SM 6200B
Matrix:AQ Batch ID:V2K4112
All samples were analyzed within the recommended method holding time.
Sample(s) LA90503-7MS, LA90503-7MSD were used as the QC samples indicated.
All method blanks for this batch meet method specific criteria.
Blank Spike Recovery(s) for Dichlorodifluoromethane are outside control limits.
Matrix Spike Duplicate Recovery(s) for Vinyl Acetate are outside control limits. Probable cause due to matrix interference.
LA90738-2 for Dichlorodifluoromethane: Associated CCV outside of control limits high, sample was ND.
LA90738-1 for Dichlorodifluoromethane: Associated CCV outside of control limits high, sample was ND.
LA90738-1 for Methyl Tert Butyl Ether: Hit due to possible carryover. Insufficient sample volume received for re-analysis to
confirm detection.
V2K4112-BS1 for Dichlorodifluoromethane: Outside control limits biased high. Analyte not detected in associated samples.
MS Semi-volatiles By Method EPA 625.1
Matrix:AQ Batch ID:OP22806
All samples were analyzed within the recommended method holding time.
All method blanks for this batch meet method specific criteria.
The following samples were extracted outside of holding time for method EPA 625.1: LA90738-1, LA90738-2
GC Volatiles By Method EPA 504.1
Matrix:AQ Batch ID:OP22822
All samples were extracted within the recommended method holding time.
All samples were analyzed within the recommended method holding time.
All method blanks for this batch meet method specific criteria.
GC Volatiles By Method MADEP VPH REV 2.1
Matrix:AQ Batch ID:GLE2416
All samples were analyzed within the recommended method holding time.
Sample(s) LA90738-1DUP were used as the QC samples indicated.
All method blanks for this batch meet method specific criteria.
Wednesday, May 31, 2023 Page 1 of 2
4 of 61
LA90738
2
GC/LC Semi-volatiles By Method MADEP EPH REV 2.1
Matrix:AQ Batch ID:OP22798
All samples were extracted within the recommended method holding time.
All samples were analyzed within the recommended method holding time.
All method blanks for this batch meet method specific criteria.
Metals Analysis By Method SW846 6010D
Matrix:AQ Batch ID:MP26340
All samples were digested within the recommended method holding time.
All samples were analyzed within the recommended method holding time.
All method blanks for this batch meet method specific criteria.
Sample(s) LA90738-1MS, LA90738-1MSD, LA90738-1SDL were used as the QC samples for metals.
RPD(s) for Serial Dilution for Lead is outside control limits for sample MP26340-SDL. Percent difference acceptable due to
low initial sample concentration (< 50 times IDL).
SGS North America Inc.-Scott (SGS) certifies that this report meets the project requirements for analytical data produced for the
samples as received at SGS and as stated on the COC. SGS certifies that the data meets the Data QualityObjectives for precision,
accuracy and completeness as specified in the SGS Quality Manual except as noted above. This report is to be used in its entirety.
SGS is not responsible for any assumptions of data quality if partial data packages are used
Wednesday, May 31, 2023 Page 2 of 2
5 of 61
LA90738
2
Summary of Hits Page 1 of 1
Job Number:LA90738
Account:Murphy Oil USA, Inc.
Project:GESWCSC: Murphy #7214, Albemarle, NC
Collected:05/15/23
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
LA90738-1 OW-1
1,2-Dichloroethane 0.00054 0.00020 0.00012 mg/l SM 6200B
Methyl Tert Butyl Ether a 0.00026 J 0.00050 0.000068 mg/l SM 6200B
1,1,2-Trichloroethane 0.00045 0.00030 0.00017 mg/l SM 6200B
bis(2-Ethylhexyl)phthalate 0.0041 J 0.0047 0.00016 mg/l EPA 625.1
Total TIC, Semi-Volatile 0.0356 J mg/l
C11-C22 Aromatics (Unadj.)5.28 0.40 0.25 mg/l MADEP EPH REV 2.1
C9-C18 Aliphatics 1.81 0.40 0.20 mg/l MADEP EPH REV 2.1
Lead 7.3 J 10 3.7 ug/l SW846 6010D
LA90738-2 OW-2
Total TIC, Semi-Volatile 0.0354 J mg/l
C11-C22 Aromatics (Unadj.)5.49 0.40 0.25 mg/l MADEP EPH REV 2.1
C9-C18 Aliphatics 1.94 0.40 0.20 mg/l MADEP EPH REV 2.1
Lead 7.1 J 10 3.7 ug/l SW846 6010D
(a) Hit due to possible carryover. Insufficient sample volume received for re-analysis to confirm detection.
6 of 61
LA90738
3
SGS North America Inc.
Sample Results
Report of Analysis
Scott, LA
Section 4
7 of 61
LA90738
4
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:OW-1
Lab Sample ID:LA90738-1 Date Sampled:05/15/23
Matrix:AQ - Ground Water Date Received:05/19/23
Method:SM 6200B Percent Solids:n/a
Project:GESWCSC: Murphy #7214, Albemarle, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 2K0146560.D 1 05/23/23 17:33 MB n/a n/a V2K4112
Run #2
Purge Volume
Run #1 25.0 ml
Run #2
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone 0.0012 U 0.010 0.0012 mg/l
71-43-2 Benzene 0.00027 U 0.00050 0.00027 mg/l
108-86-1 Bromobenzene 0.00018 U 0.00050 0.00018 mg/l
74-97-5 Bromochloromethane 0.00012 U 0.00050 0.00012 mg/l
75-27-4 Bromodichloromethane 0.00018 U 0.00050 0.00018 mg/l
75-25-2 Bromoform 0.00010 U 0.00050 0.00010 mg/l
104-51-8 n-Butylbenzene 0.000092 U 0.00050 0.000092mg/l
135-98-8 sec-Butylbenzene 0.00014 U 0.00050 0.00014 mg/l
98-06-6 tert-Butylbenzene 0.00016 U 0.00050 0.00016 mg/l
56-23-5 Carbon Tetrachloride 0.000092 U 0.00020 0.000092mg/l
108-90-7 Chlorobenzene 0.00016 U 0.00050 0.00016 mg/l
75-00-3 Chloroethane 0.000055 U 0.00050 0.000055mg/l
67-66-3 Chloroform 0.000094 U 0.00050 0.000094mg/l
95-49-8 o-Chlorotoluene 0.00016 U 0.00050 0.00016 mg/l
106-43-4 p-Chlorotoluene 0.00020 U 0.00050 0.00020 mg/l
124-48-1 Dibromochloromethane 0.000075 U 0.00020 0.000075mg/l
106-93-4 1,2-Dibromoethane 0.00024 U 0.00050 0.00024 mg/l
75-71-8 Dichlorodifluoromethane a 0.00012 U 0.00050 0.00012 mg/l
541-73-1 m-Dichlorobenzene 0.000063 U 0.00050 0.000063mg/l
95-50-1 o-Dichlorobenzene 0.00020 U 0.00050 0.00020 mg/l
106-46-7 p-Dichlorobenzene 0.00022 U 0.00050 0.00022 mg/l
75-34-3 1,1-Dichloroethane 0.00010 U 0.00050 0.00010 mg/l
107-06-2 1,2-Dichloroethane 0.00054 0.00020 0.00012 mg/l
75-35-4 1,1-Dichloroethylene 0.000094 U 0.00050 0.000094mg/l
156-59-2 cis-1,2-Dichloroethylene 0.00011 U 0.00050 0.00011 mg/l
156-60-5 trans-1,2-Dichloroethylene 0.00015 U 0.00050 0.00015 mg/l
78-87-5 1,2-Dichloropropane 0.00013 U 0.00030 0.00013 mg/l
142-28-9 1,3-Dichloropropane 0.00021 U 0.00050 0.00021 mg/l
594-20-7 2,2-Dichloropropane 0.000079 U 0.00050 0.000079mg/l
563-58-6 1,1-Dichloropropene 0.00012 U 0.00050 0.00012 mg/l
10061-01-5 cis-1,3-Dichloropropene 0.00010 U 0.00020 0.00010 mg/l
10061-02-6 trans-1,3-Dichloropropene 0.000056 U 0.00020 0.000056mg/l
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
8 of 61
LA90738
4
4.
1
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:OW-1
Lab Sample ID:LA90738-1 Date Sampled:05/15/23
Matrix:AQ - Ground Water Date Received:05/19/23
Method:SM 6200B Percent Solids:n/a
Project:GESWCSC: Murphy #7214, Albemarle, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 0.000073 U 0.00050 0.000073mg/l
64-17-5 Ethyl Alcohol 0.0084 U 0.050 0.0084 mg/l
100-41-4 Ethylbenzene 0.00020 U 0.00050 0.00020 mg/l
591-78-6 2-Hexanone 0.00042 U 0.0010 0.00042 mg/l
98-82-8 Isopropylbenzene 0.00013 U 0.00050 0.00013 mg/l
99-87-6 p-Isopropyltoluene 0.00013 U 0.00050 0.00013 mg/l
74-83-9 Methyl Bromide 0.00023 U 0.00050 0.00023 mg/l
74-87-3 Methyl Chloride 0.000066 U 0.00050 0.000066mg/l
75-09-2 Methylene Chloride 0.000080 U 0.00050 0.000080mg/l
78-93-3 Methyl Ethyl Ketone 0.00028 U 0.025 0.00028 mg/l
108-10-1 4-Methyl-2-pentanone 0.00024 U 0.00050 0.00024 mg/l
1634-04-4 Methyl Tert Butyl Ether b 0.00026 0.00050 0.000068mg/l J
91-20-3 Naphthalene 0.00010 U 0.00050 0.00010 mg/l
103-65-1 n-Propylbenzene 0.00022 U 0.00050 0.00022 mg/l
100-42-5 Styrene 0.00013 U 0.00050 0.00013 mg/l
630-20-6 1,1,1,2-Tetrachloroethane 0.00018 U 0.00050 0.00018 mg/l
79-34-5 1,1,2,2-Tetrachloroethane 0.00012 U 0.00020 0.00012 mg/l
127-18-4 Tetrachloroethylene 0.00022 U 0.00050 0.00022 mg/l
108-88-3 Toluene 0.00029 U 0.00050 0.00029 mg/l
87-61-6 1,2,3-Trichlorobenzene 0.00016 U 0.00050 0.00016 mg/l
120-82-1 1,2,4-Trichlorobenzene 0.00017 U 0.00050 0.00017 mg/l
71-55-6 1,1,1-Trichloroethane 0.00016 U 0.00050 0.00016 mg/l
79-00-5 1,1,2-Trichloroethane 0.00045 0.00030 0.00017 mg/l
79-01-6 Trichloroethylene 0.00018 U 0.00050 0.00018 mg/l
75-69-4 Trichlorofluoromethane 0.000073 U 0.00050 0.000073mg/l
96-18-4 1,2,3-Trichloropropane 0.000023 U 0.00050 0.000023mg/l
95-63-6 1,2,4-Trimethylbenzene 0.00015 U 0.00050 0.00015 mg/l
108-67-8 1,3,5-Trimethylbenzene 0.00016 U 0.00050 0.00016 mg/l
108-05-4 Vinyl Acetate 0.000069 U 0.00050 0.000069mg/l
75-01-4 Vinyl Chloride 0.000075 U 0.00010 0.000075mg/l
m,p-Xylene 0.00034 U 0.0010 0.00034 mg/l
95-47-6 o-Xylene 0.00015 U 0.00050 0.00015 mg/l
1330-20-7 Xylene (total)0.00016 U 0.00050 0.00016 mg/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 101%70-130%
2037-26-5 Toluene-D8 102%70-130%
460-00-4 4-Bromofluorobenzene 102%70-130%
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
9 of 61
LA90738
4
4.
1
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:OW-1
Lab Sample ID:LA90738-1 Date Sampled:05/15/23
Matrix:AQ - Ground Water Date Received:05/19/23
Method:SM 6200B Percent Solids:n/a
Project:GESWCSC: Murphy #7214, Albemarle, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
(a) Associated CCV outside of control limits high, sample was ND.
(b) Hit due to possible carryover. Insufficient sample volume received for re-analysis to confirm detection.
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
10 of 61
LA90738
4
4.
1
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:OW-1
Lab Sample ID:LA90738-1 Date Sampled:05/15/23
Matrix:AQ - Ground Water Date Received:05/19/23
Method:EPA 625.1 EPA 625.1 Percent Solids:n/a
Project:GESWCSC: Murphy #7214, Albemarle, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 W59216.D 1 05/25/23 23:31 BH 05/22/23 17:40 OP22806 EW2832
Run #2
Initial Volume Final Volume
Run #1 1080 ml 1.0 ml
Run #2
ABN List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
65-85-0 Benzoic Acid 0.0019 U 0.019 0.0019 mg/l
59-50-7 4-Chloro-3-methyl Phenol 0.00012 U 0.0047 0.00012 mg/l
95-57-8 2-Chlorophenol 0.00014 U 0.0047 0.00014 mg/l
120-83-2 2,4-Dichlorophenol 0.00015 U 0.0047 0.00015 mg/l
105-67-9 2,4-Dimethylphenol 0.00076 U 0.0047 0.00076 mg/l
51-28-5 2,4-Dinitrophenol 0.00070 U 0.019 0.00070 mg/l
534-52-1 4,6-Dinitro-o-cresol 0.00013 U 0.0093 0.00013 mg/l
95-48-7 2-Methylphenol 0.00025 U 0.0047 0.00025 mg/l
3&4-Methylphenol 0.00017 U 0.0047 0.00017 mg/l
88-75-5 2-Nitrophenol 0.00021 U 0.0047 0.00021 mg/l
100-02-7 4-Nitrophenol 0.00014 U 0.023 0.00014 mg/l
87-86-5 Pentachlorophenol 0.00021 U 0.0093 0.00021 mg/l
108-95-2 Phenol 0.00013 U 0.0047 0.00013 mg/l
88-06-2 2,4,6-Trichlorophenol 0.00021 U 0.0047 0.00021 mg/l
83-32-9 Acenaphthene 0.000074 U 0.00019 0.000074mg/l
208-96-8 Acenaphthylene 0.000061 U 0.00019 0.000061mg/l
120-12-7 Anthracene 0.000081 U 0.00019 0.000081mg/l
56-55-3 Benzo(a)anthracene 0.000052 U 0.00019 0.000052mg/l
50-32-8 Benzo(a)pyrene 0.000051 U 0.00019 0.000051mg/l
205-99-2 Benzo(b)fluoranthene 0.000047 U 0.00019 0.000047mg/l
191-24-2 Benzo(g,h,i)perylene 0.000052 U 0.00019 0.000052mg/l
207-08-9 Benzo(k)fluoranthene 0.000045 U 0.00019 0.000045mg/l
100-51-6 Benzyl Alcohol 0.00016 U 0.0093 0.00016 mg/l
101-55-3 4-Bromophenyl Phenyl Ether 0.00012 U 0.0047 0.00012 mg/l
85-68-7 Butyl Benzyl Phthalate 0.00012 U 0.0047 0.00012 mg/l
106-47-8 4-Chloroaniline 0.00062 U 0.0047 0.00062 mg/l
111-91-1 bis(2-Chloroethoxy)methane 0.00014 U 0.0047 0.00014 mg/l
111-44-4 bis(2-Chloroethyl)ether 0.00016 U 0.0047 0.00016 mg/l
108-60-1 2,2'-Oxybis(1-chloropropane)0.00035 U 0.0047 0.00035 mg/l
91-58-7 2-Chloronaphthalene 0.00013 U 0.0047 0.00013 mg/l
7005-72-3 4-Chlorophenyl Phenyl Ether 0.00012 U 0.0047 0.00012 mg/l
218-01-9 Chrysene 0.000061 U 0.00019 0.000061mg/l
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
11 of 61
LA90738
4
4.
1
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:OW-1
Lab Sample ID:LA90738-1 Date Sampled:05/15/23
Matrix:AQ - Ground Water Date Received:05/19/23
Method:EPA 625.1 EPA 625.1 Percent Solids:n/a
Project:GESWCSC: Murphy #7214, Albemarle, NC
ABN List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
53-70-3 Dibenzo(a,h)anthracene 0.000063 U 0.00019 0.000063mg/l
132-64-9 Dibenzofuran 0.00013 U 0.0047 0.00013 mg/l
95-50-1 1,2-Dichlorobenzene 0.00014 U 0.0047 0.00014 mg/l
541-73-1 1,3-Dichlorobenzene 0.00021 U 0.0047 0.00021 mg/l
106-46-7 1,4-Dichlorobenzene 0.00017 U 0.0047 0.00017 mg/l
91-94-1 3,3'-Dichlorobenzidine 0.00045 U 0.0093 0.00045 mg/l
84-66-2 Diethyl Phthalate 0.00015 U 0.0047 0.00015 mg/l
131-11-3 Dimethyl Phthalate 0.00010 U 0.0047 0.00010 mg/l
84-74-2 Di-n-butyl Phthalate 0.00012 U 0.0047 0.00012 mg/l
117-84-0 Di-n-octyl Phthalate 0.00012 U 0.0047 0.00012 mg/l
122-66-7 1,2-Diphenylhydrazine 0.00016 U 0.0047 0.00016 mg/l
117-81-7 bis(2-Ethylhexyl)phthalate 0.0041 0.0047 0.00016 mg/l J
206-44-0 Fluoranthene 0.00015 U 0.00019 0.00015 mg/l
86-73-7 Fluorene 0.000069 U 0.00019 0.000069mg/l
118-74-1 Hexachlorobenzene 0.00017 U 0.0047 0.00017 mg/l
87-68-3 Hexachlorobutadiene 0.000064 U 0.0047 0.000064mg/l
77-47-4 Hexachlorocyclopentadiene 0.00019 U 0.0093 0.00019 mg/l
67-72-1 Hexachloroethane 0.00021 U 0.0047 0.00021 mg/l
193-39-5 Indeno(1,2,3-cd)pyrene 0.000051 U 0.00019 0.000051mg/l
78-59-1 Isophorone 0.00013 U 0.0047 0.00013 mg/l
90-12-0 1-Methylnaphthalene 0.00016 U 0.00019 0.00016 mg/l
91-57-6 2-Methylnaphthalene 0.000049 U 0.00019 0.000049mg/l
91-20-3 Naphthalene 0.000066 U 0.00019 0.000066mg/l
98-95-3 Nitrobenzene 0.00012 U 0.0047 0.00012 mg/l
621-64-7 N-Nitroso-di-n-propylamine 0.00013 U 0.0047 0.00013 mg/l
86-30-6 N-Nitrosodiphenylamine 0.00064 U 0.0047 0.00064 mg/l
85-01-8 Phenanthrene 0.00017 U 0.00019 0.00017 mg/l
129-00-0 Pyrene 0.00016 U 0.00019 0.00016 mg/l
120-82-1 1,2,4-Trichlorobenzene 0.00014 U 0.0047 0.00014 mg/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
367-12-4 2-Fluorophenol 35%20-75%
4165-62-2 Phenol-d5 23%10-60%
118-79-6 2,4,6-Tribromophenol 92%38-138%
4165-60-0 Nitrobenzene-d5 82%44-132%
321-60-8 2-Fluorobiphenyl 80%40-119%
1718-51-0 Terphenyl-d14 80%40-127%
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
12 of 61
LA90738
4
4.
1
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:OW-1
Lab Sample ID:LA90738-1 Date Sampled:05/15/23
Matrix:AQ - Ground Water Date Received:05/19/23
Method:EPA 625.1 EPA 625.1 Percent Solids:n/a
Project:GESWCSC: Murphy #7214, Albemarle, NC
ABN List for NC, May 2012
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
4971-18-0 Unknown 3.93 .0082 mg/l JN
49622-18-6 Decane, 3,3,4-trimethyl-4.10 .0095 mg/l JN
108-67-8 Benzene, 1,3,5-trimethyl-4.40 .013 mg/l JN
57-10-3 n-Hexadecanoic acid 8.08 .0049 mg/l JN
Total TIC, Semi-Volatile .0356 mg/l J
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
13 of 61
LA90738
4
4.
1
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:OW-1
Lab Sample ID:LA90738-1 Date Sampled:05/15/23
Matrix:AQ - Ground Water Date Received:05/19/23
Method:EPA 504.1 EPA 504 Percent Solids:n/a
Project:GESWCSC: Murphy #7214, Albemarle, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LI138309.D 1 05/25/23 20:51 JT 05/25/23 12:00 OP22822 GLI1249
Run #2
Initial Volume Final Volume
Run #1 36.2 ml 2.0 ml
Run #2
CAS No.Compound Result RL MDL Units Q
106-93-4 1,2-Dibromoethane 0.0000037 U0.0000190.0000037mg/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
348-51-6 1-Chloro-2-fluorobenzene 97%70-130%
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
14 of 61
LA90738
4
4.
1
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:OW-1
Lab Sample ID:LA90738-1 Date Sampled:05/15/23
Matrix:AQ - Ground Water Date Received:05/19/23
Method:MADEP VPH REV 2.1 Percent Solids:n/a
Project:GESWCSC: Murphy #7214, Albemarle, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LE041287.D 1 05/22/23 14:48 JB n/a n/a GLE2416
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
MA VPH list
CAS No.Compound Result RL MDL Units Q
C5- C8 Aliphatics (Unadj.)0.050 U 0.10 0.050 mg/l
C9- C12 Aliphatics (Unadj.)0.050 U 0.10 0.050 mg/l
C9- C10 Aromatics (Unadj.)0.020 U 0.10 0.020 mg/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
615-59-8 2,5-Dibromotoluene 92%70-130%
615-59-8 2,5-Dibromotoluene 86%70-130%
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
15 of 61
LA90738
4
4.
1
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:OW-1
Lab Sample ID:LA90738-1 Date Sampled:05/15/23
Matrix:AQ - Ground Water Date Received:05/19/23
Method:MADEP EPH REV 2.1 SW846 3511 Percent Solids:n/a
Project:GESWCSC: Murphy #7214, Albemarle, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LZ0022786.D 1 05/24/23 23:32 KM 05/22/23 12:00 OP22798 GLZ496
Run #2
Initial Volume Final Volume
Run #1 50.0 ml 4.0 ml
Run #2
MAEPH List
CAS No.Compound Result RL MDL Units Q
C11-C22 Aromatics (Unadj.)5.28 0.40 0.25 mg/l
C9-C18 Aliphatics 1.81 0.40 0.20 mg/l
C19-C36 Aliphatics 0.086 U 0.40 0.086 mg/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
3386-33-2 1-Chlorooctadecane 89%40-140%
84-15-1 o-Terphenyl 105%40-140%
321-60-8 2-Fluorobiphenyl 90%40-140%
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
16 of 61
LA90738
4
4.
1
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:OW-1
Lab Sample ID:LA90738-1 Date Sampled:05/15/23
Matrix:AQ - Ground Water Date Received:05/19/23
Percent Solids:n/a
Project:GESWCSC: Murphy #7214, Albemarle, NC
Total Metals Analysis
Analyte Result RL MDL Units DF Prep Analyzed By Method Prep Method
Lead 7.3 J 10 3.7 ug/l 1 05/22/23 05/23/23 RD SW846 6010D 1 SW846 3010A 2
(1) Instrument QC Batch: MA25914
(2) Prep QC Batch: MP26340
RL = Reporting Limit U = Indicates a result < MDL
MDL = Method Detection Limit J = Indicates a result >= MDL but < RL
17 of 61
LA90738
4
4.
1
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:OW-2
Lab Sample ID:LA90738-2 Date Sampled:05/15/23
Matrix:AQ - Ground Water Date Received:05/19/23
Method:SM 6200B Percent Solids:n/a
Project:GESWCSC: Murphy #7214, Albemarle, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 2K0146561.D 1 05/23/23 18:02 MB n/a n/a V2K4112
Run #2
Purge Volume
Run #1 25.0 ml
Run #2
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone 0.0012 U 0.010 0.0012 mg/l
71-43-2 Benzene 0.00027 U 0.00050 0.00027 mg/l
108-86-1 Bromobenzene 0.00018 U 0.00050 0.00018 mg/l
74-97-5 Bromochloromethane 0.00012 U 0.00050 0.00012 mg/l
75-27-4 Bromodichloromethane 0.00018 U 0.00050 0.00018 mg/l
75-25-2 Bromoform 0.00010 U 0.00050 0.00010 mg/l
104-51-8 n-Butylbenzene 0.000092 U 0.00050 0.000092mg/l
135-98-8 sec-Butylbenzene 0.00014 U 0.00050 0.00014 mg/l
98-06-6 tert-Butylbenzene 0.00016 U 0.00050 0.00016 mg/l
56-23-5 Carbon Tetrachloride 0.000092 U 0.00020 0.000092mg/l
108-90-7 Chlorobenzene 0.00016 U 0.00050 0.00016 mg/l
75-00-3 Chloroethane 0.000055 U 0.00050 0.000055mg/l
67-66-3 Chloroform 0.000094 U 0.00050 0.000094mg/l
95-49-8 o-Chlorotoluene 0.00016 U 0.00050 0.00016 mg/l
106-43-4 p-Chlorotoluene 0.00020 U 0.00050 0.00020 mg/l
124-48-1 Dibromochloromethane 0.000075 U 0.00020 0.000075mg/l
106-93-4 1,2-Dibromoethane 0.00024 U 0.00050 0.00024 mg/l
75-71-8 Dichlorodifluoromethane a 0.00012 U 0.00050 0.00012 mg/l
541-73-1 m-Dichlorobenzene 0.000063 U 0.00050 0.000063mg/l
95-50-1 o-Dichlorobenzene 0.00020 U 0.00050 0.00020 mg/l
106-46-7 p-Dichlorobenzene 0.00022 U 0.00050 0.00022 mg/l
75-34-3 1,1-Dichloroethane 0.00010 U 0.00050 0.00010 mg/l
107-06-2 1,2-Dichloroethane 0.00012 U 0.00020 0.00012 mg/l
75-35-4 1,1-Dichloroethylene 0.000094 U 0.00050 0.000094mg/l
156-59-2 cis-1,2-Dichloroethylene 0.00011 U 0.00050 0.00011 mg/l
156-60-5 trans-1,2-Dichloroethylene 0.00015 U 0.00050 0.00015 mg/l
78-87-5 1,2-Dichloropropane 0.00013 U 0.00030 0.00013 mg/l
142-28-9 1,3-Dichloropropane 0.00021 U 0.00050 0.00021 mg/l
594-20-7 2,2-Dichloropropane 0.000079 U 0.00050 0.000079mg/l
563-58-6 1,1-Dichloropropene 0.00012 U 0.00050 0.00012 mg/l
10061-01-5 cis-1,3-Dichloropropene 0.00010 U 0.00020 0.00010 mg/l
10061-02-6 trans-1,3-Dichloropropene 0.000056 U 0.00020 0.000056mg/l
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
18 of 61
LA90738
4
4.
2
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:OW-2
Lab Sample ID:LA90738-2 Date Sampled:05/15/23
Matrix:AQ - Ground Water Date Received:05/19/23
Method:SM 6200B Percent Solids:n/a
Project:GESWCSC: Murphy #7214, Albemarle, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 0.000073 U 0.00050 0.000073mg/l
64-17-5 Ethyl Alcohol 0.0084 U 0.050 0.0084 mg/l
100-41-4 Ethylbenzene 0.00020 U 0.00050 0.00020 mg/l
591-78-6 2-Hexanone 0.00042 U 0.0010 0.00042 mg/l
98-82-8 Isopropylbenzene 0.00013 U 0.00050 0.00013 mg/l
99-87-6 p-Isopropyltoluene 0.00013 U 0.00050 0.00013 mg/l
74-83-9 Methyl Bromide 0.00023 U 0.00050 0.00023 mg/l
74-87-3 Methyl Chloride 0.000066 U 0.00050 0.000066mg/l
75-09-2 Methylene Chloride 0.000080 U 0.00050 0.000080mg/l
78-93-3 Methyl Ethyl Ketone 0.00028 U 0.025 0.00028 mg/l
108-10-1 4-Methyl-2-pentanone 0.00024 U 0.00050 0.00024 mg/l
1634-04-4 Methyl Tert Butyl Ether 0.000068 U 0.00050 0.000068mg/l
91-20-3 Naphthalene 0.00010 U 0.00050 0.00010 mg/l
103-65-1 n-Propylbenzene 0.00022 U 0.00050 0.00022 mg/l
100-42-5 Styrene 0.00013 U 0.00050 0.00013 mg/l
630-20-6 1,1,1,2-Tetrachloroethane 0.00018 U 0.00050 0.00018 mg/l
79-34-5 1,1,2,2-Tetrachloroethane 0.00012 U 0.00020 0.00012 mg/l
127-18-4 Tetrachloroethylene 0.00022 U 0.00050 0.00022 mg/l
108-88-3 Toluene 0.00029 U 0.00050 0.00029 mg/l
87-61-6 1,2,3-Trichlorobenzene 0.00016 U 0.00050 0.00016 mg/l
120-82-1 1,2,4-Trichlorobenzene 0.00017 U 0.00050 0.00017 mg/l
71-55-6 1,1,1-Trichloroethane 0.00016 U 0.00050 0.00016 mg/l
79-00-5 1,1,2-Trichloroethane 0.00017 U 0.00030 0.00017 mg/l
79-01-6 Trichloroethylene 0.00018 U 0.00050 0.00018 mg/l
75-69-4 Trichlorofluoromethane 0.000073 U 0.00050 0.000073mg/l
96-18-4 1,2,3-Trichloropropane 0.000023 U 0.00050 0.000023mg/l
95-63-6 1,2,4-Trimethylbenzene 0.00015 U 0.00050 0.00015 mg/l
108-67-8 1,3,5-Trimethylbenzene 0.00016 U 0.00050 0.00016 mg/l
108-05-4 Vinyl Acetate 0.000069 U 0.00050 0.000069mg/l
75-01-4 Vinyl Chloride 0.000075 U 0.00010 0.000075mg/l
m,p-Xylene 0.00034 U 0.0010 0.00034 mg/l
95-47-6 o-Xylene 0.00015 U 0.00050 0.00015 mg/l
1330-20-7 Xylene (total)0.00016 U 0.00050 0.00016 mg/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 101%70-130%
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 103%70-130%
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
19 of 61
LA90738
4
4.
2
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:OW-2
Lab Sample ID:LA90738-2 Date Sampled:05/15/23
Matrix:AQ - Ground Water Date Received:05/19/23
Method:SM 6200B Percent Solids:n/a
Project:GESWCSC: Murphy #7214, Albemarle, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
(a) Associated CCV outside of control limits high, sample was ND.
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
20 of 61
LA90738
4
4.
2
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:OW-2
Lab Sample ID:LA90738-2 Date Sampled:05/15/23
Matrix:AQ - Ground Water Date Received:05/19/23
Method:EPA 625.1 EPA 625.1 Percent Solids:n/a
Project:GESWCSC: Murphy #7214, Albemarle, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 W59217.D 1 05/25/23 23:54 BH 05/22/23 17:40 OP22806 EW2832
Run #2
Initial Volume Final Volume
Run #1 1080 ml 1.0 ml
Run #2
ABN List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
65-85-0 Benzoic Acid 0.0019 U 0.019 0.0019 mg/l
59-50-7 4-Chloro-3-methyl Phenol 0.00012 U 0.0047 0.00012 mg/l
95-57-8 2-Chlorophenol 0.00014 U 0.0047 0.00014 mg/l
120-83-2 2,4-Dichlorophenol 0.00015 U 0.0047 0.00015 mg/l
105-67-9 2,4-Dimethylphenol 0.00076 U 0.0047 0.00076 mg/l
51-28-5 2,4-Dinitrophenol 0.00070 U 0.019 0.00070 mg/l
534-52-1 4,6-Dinitro-o-cresol 0.00013 U 0.0093 0.00013 mg/l
95-48-7 2-Methylphenol 0.00025 U 0.0047 0.00025 mg/l
3&4-Methylphenol 0.00017 U 0.0047 0.00017 mg/l
88-75-5 2-Nitrophenol 0.00021 U 0.0047 0.00021 mg/l
100-02-7 4-Nitrophenol 0.00014 U 0.023 0.00014 mg/l
87-86-5 Pentachlorophenol 0.00021 U 0.0093 0.00021 mg/l
108-95-2 Phenol 0.00013 U 0.0047 0.00013 mg/l
88-06-2 2,4,6-Trichlorophenol 0.00021 U 0.0047 0.00021 mg/l
83-32-9 Acenaphthene 0.000074 U 0.00019 0.000074mg/l
208-96-8 Acenaphthylene 0.000061 U 0.00019 0.000061mg/l
120-12-7 Anthracene 0.000081 U 0.00019 0.000081mg/l
56-55-3 Benzo(a)anthracene 0.000052 U 0.00019 0.000052mg/l
50-32-8 Benzo(a)pyrene 0.000051 U 0.00019 0.000051mg/l
205-99-2 Benzo(b)fluoranthene 0.000047 U 0.00019 0.000047mg/l
191-24-2 Benzo(g,h,i)perylene 0.000052 U 0.00019 0.000052mg/l
207-08-9 Benzo(k)fluoranthene 0.000045 U 0.00019 0.000045mg/l
100-51-6 Benzyl Alcohol 0.00016 U 0.0093 0.00016 mg/l
101-55-3 4-Bromophenyl Phenyl Ether 0.00012 U 0.0047 0.00012 mg/l
85-68-7 Butyl Benzyl Phthalate 0.00012 U 0.0047 0.00012 mg/l
106-47-8 4-Chloroaniline 0.00062 U 0.0047 0.00062 mg/l
111-91-1 bis(2-Chloroethoxy)methane 0.00014 U 0.0047 0.00014 mg/l
111-44-4 bis(2-Chloroethyl)ether 0.00016 U 0.0047 0.00016 mg/l
108-60-1 2,2'-Oxybis(1-chloropropane)0.00035 U 0.0047 0.00035 mg/l
91-58-7 2-Chloronaphthalene 0.00013 U 0.0047 0.00013 mg/l
7005-72-3 4-Chlorophenyl Phenyl Ether 0.00012 U 0.0047 0.00012 mg/l
218-01-9 Chrysene 0.000061 U 0.00019 0.000061mg/l
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
21 of 61
LA90738
4
4.
2
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:OW-2
Lab Sample ID:LA90738-2 Date Sampled:05/15/23
Matrix:AQ - Ground Water Date Received:05/19/23
Method:EPA 625.1 EPA 625.1 Percent Solids:n/a
Project:GESWCSC: Murphy #7214, Albemarle, NC
ABN List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
53-70-3 Dibenzo(a,h)anthracene 0.000063 U 0.00019 0.000063mg/l
132-64-9 Dibenzofuran 0.00013 U 0.0047 0.00013 mg/l
95-50-1 1,2-Dichlorobenzene 0.00014 U 0.0047 0.00014 mg/l
541-73-1 1,3-Dichlorobenzene 0.00021 U 0.0047 0.00021 mg/l
106-46-7 1,4-Dichlorobenzene 0.00017 U 0.0047 0.00017 mg/l
91-94-1 3,3'-Dichlorobenzidine 0.00045 U 0.0093 0.00045 mg/l
84-66-2 Diethyl Phthalate 0.00015 U 0.0047 0.00015 mg/l
131-11-3 Dimethyl Phthalate 0.00010 U 0.0047 0.00010 mg/l
84-74-2 Di-n-butyl Phthalate 0.00012 U 0.0047 0.00012 mg/l
117-84-0 Di-n-octyl Phthalate 0.00012 U 0.0047 0.00012 mg/l
122-66-7 1,2-Diphenylhydrazine 0.00016 U 0.0047 0.00016 mg/l
117-81-7 bis(2-Ethylhexyl)phthalate 0.00016 U 0.0047 0.00016 mg/l
206-44-0 Fluoranthene 0.00015 U 0.00019 0.00015 mg/l
86-73-7 Fluorene 0.000069 U 0.00019 0.000069mg/l
118-74-1 Hexachlorobenzene 0.00017 U 0.0047 0.00017 mg/l
87-68-3 Hexachlorobutadiene 0.000064 U 0.0047 0.000064mg/l
77-47-4 Hexachlorocyclopentadiene 0.00019 U 0.0093 0.00019 mg/l
67-72-1 Hexachloroethane 0.00021 U 0.0047 0.00021 mg/l
193-39-5 Indeno(1,2,3-cd)pyrene 0.000051 U 0.00019 0.000051mg/l
78-59-1 Isophorone 0.00013 U 0.0047 0.00013 mg/l
90-12-0 1-Methylnaphthalene 0.00016 U 0.00019 0.00016 mg/l
91-57-6 2-Methylnaphthalene 0.000049 U 0.00019 0.000049mg/l
91-20-3 Naphthalene 0.000066 U 0.00019 0.000066mg/l
98-95-3 Nitrobenzene 0.00012 U 0.0047 0.00012 mg/l
621-64-7 N-Nitroso-di-n-propylamine 0.00013 U 0.0047 0.00013 mg/l
86-30-6 N-Nitrosodiphenylamine 0.00064 U 0.0047 0.00064 mg/l
85-01-8 Phenanthrene 0.00017 U 0.00019 0.00017 mg/l
129-00-0 Pyrene 0.00016 U 0.00019 0.00016 mg/l
120-82-1 1,2,4-Trichlorobenzene 0.00014 U 0.0047 0.00014 mg/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
367-12-4 2-Fluorophenol 37%20-75%
4165-62-2 Phenol-d5 24%10-60%
118-79-6 2,4,6-Tribromophenol 105%38-138%
4165-60-0 Nitrobenzene-d5 93%44-132%
321-60-8 2-Fluorobiphenyl 91%40-119%
1718-51-0 Terphenyl-d14 91%40-127%
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
22 of 61
LA90738
4
4.
2
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:OW-2
Lab Sample ID:LA90738-2 Date Sampled:05/15/23
Matrix:AQ - Ground Water Date Received:05/19/23
Method:EPA 625.1 EPA 625.1 Percent Solids:n/a
Project:GESWCSC: Murphy #7214, Albemarle, NC
ABN List for NC, May 2012
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
1576-87-0 Unknown 3.93 .0091 mg/l JN
49622-18-6 Decane, 3,3,4-trimethyl-4.10 .0099 mg/l JN
57-10-3 n-Hexadecanoic acid 8.09 .0099 mg/l JN
57-11-4 Octadecanoic acid 8.73 .0065 mg/l JN
Total TIC, Semi-Volatile .0354 mg/l J
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
23 of 61
LA90738
4
4.
2
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:OW-2
Lab Sample ID:LA90738-2 Date Sampled:05/15/23
Matrix:AQ - Ground Water Date Received:05/19/23
Method:EPA 504.1 EPA 504 Percent Solids:n/a
Project:GESWCSC: Murphy #7214, Albemarle, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LI138310.D 1 05/25/23 21:09 JT 05/25/23 12:00 OP22822 GLI1249
Run #2
Initial Volume Final Volume
Run #1 36.4 ml 2.0 ml
Run #2
CAS No.Compound Result RL MDL Units Q
106-93-4 1,2-Dibromoethane 0.0000037 U0.0000190.0000037mg/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
348-51-6 1-Chloro-2-fluorobenzene 106%70-130%
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
24 of 61
LA90738
4
4.
2
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:OW-2
Lab Sample ID:LA90738-2 Date Sampled:05/15/23
Matrix:AQ - Ground Water Date Received:05/19/23
Method:MADEP VPH REV 2.1 Percent Solids:n/a
Project:GESWCSC: Murphy #7214, Albemarle, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LE041286.D 1 05/22/23 14:16 JB n/a n/a GLE2416
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
MA VPH list
CAS No.Compound Result RL MDL Units Q
C5- C8 Aliphatics (Unadj.)0.050 U 0.10 0.050 mg/l
C9- C12 Aliphatics (Unadj.)0.050 U 0.10 0.050 mg/l
C9- C10 Aromatics (Unadj.)0.020 U 0.10 0.020 mg/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
615-59-8 2,5-Dibromotoluene 94%70-130%
615-59-8 2,5-Dibromotoluene 88%70-130%
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
25 of 61
LA90738
4
4.
2
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:OW-2
Lab Sample ID:LA90738-2 Date Sampled:05/15/23
Matrix:AQ - Ground Water Date Received:05/19/23
Method:MADEP EPH REV 2.1 SW846 3511 Percent Solids:n/a
Project:GESWCSC: Murphy #7214, Albemarle, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LZ0022746.D 1 05/24/23 16:50 KM 05/22/23 12:00 OP22798 GLZ496
Run #2
Initial Volume Final Volume
Run #1 50.0 ml 4.0 ml
Run #2
MAEPH List
CAS No.Compound Result RL MDL Units Q
C11-C22 Aromatics (Unadj.)5.49 0.40 0.25 mg/l
C9-C18 Aliphatics 1.94 0.40 0.20 mg/l
C19-C36 Aliphatics 0.086 U 0.40 0.086 mg/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
3386-33-2 1-Chlorooctadecane 88%40-140%
84-15-1 o-Terphenyl 97%40-140%
321-60-8 2-Fluorobiphenyl 88%40-140%
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
26 of 61
LA90738
4
4.
2
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:OW-2
Lab Sample ID:LA90738-2 Date Sampled:05/15/23
Matrix:AQ - Ground Water Date Received:05/19/23
Percent Solids:n/a
Project:GESWCSC: Murphy #7214, Albemarle, NC
Total Metals Analysis
Analyte Result RL MDL Units DF Prep Analyzed By Method Prep Method
Lead 7.1 J 10 3.7 ug/l 1 05/22/23 05/23/23 RD SW846 6010D 1 SW846 3010A 2
(1) Instrument QC Batch: MA25914
(2) Prep QC Batch: MP26340
RL = Reporting Limit U = Indicates a result < MDL
MDL = Method Detection Limit J = Indicates a result >= MDL but < RL
27 of 61
LA90738
4
4.
2
SGS North America Inc.
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
 Chain of Custody
Scott, LA
Section 5
28 of 61
LA90738
5
-SGS 1
,tuEM
1 d ,(P.!.: 1 or 1
iaurDd crirr hr6hdbn i.quhd Pb|..l rnrorm.lM
GES
Clrcle On )104 Coroo.al€ A,vd. Suite 411 237 No.th t yrtla Road
W6t Cdumbi5 SC 2c169 iruRtHY VERIS E (drt 'htck)PAYAALE (.nv "cru'l Prol'cr'rACCOUNTS7058
7058 Slzanne Junkin Suun.e Junrin@sgs "oo
SI!IEiGaslonla. NC
COLLECTED
SGS P LD
9o
-.o
*
llo
a.llj\\!o
-
$C\
P
oq.{
s
I
o o
z
a Eg=
a z
E o o
I
M{t8A C@E
SAMPLE ID
a
d
a
#
I
t
I oru-l u/5[,48 $"r,
2 t>'>5tlt\,
3
t
ecEprro rY / AfFrlr,ATroxx)ornoxrl coltErTa icltiqrrlHlo aY , rrFtlarloL
a.
3ATPIER XAIE ANO SICIIAIURE
C c. .rtcg *a!
BSa.'-c
alrilo //ww sos.com/e.rterms-and-condilpr6
lvc
tTl ll
ti))I-
e_
?-1t
I a!1.5
LA90738: Chain of Custody
Page 1 of 3
29 of 61
LA90738
5
5.
1
?l x
(J
t
t>
oa C..
,
l\
,(r
,
ct
,A aE
,
F
._
r

_
I
-<
>
-
-
_r

b
-<
-8

=F
$,
s
b
,
-
d
,
E
Il
--i
i
cl =,
-f

r{
.<

(s
,a
t
o

dB
LA90738: Chain of Custody
Page 2 of 3
30 of 61
LA90738
5
5.
1
Job Number:LA90738 Client:GES
Date / Time Received:5/19/2023 10:10:00 AM Delivery Method:FEDEX
Project:GES
4. No. Coolers:1
Airbill #'s:5801 3251 6414
Cooler Security
1. Custody Seals Present:
Y or N
2. Custody Seals Intact:
3. COC Present:
4. Smpl Dates/Time OK
2. Cooler temp verification:
Cooler Temperature Y or N
1. Temp criteria achieved:
3. Cooler media:Ice (direct contact)
Quality Control Preservation Y or N N/A
1. Trip Blank present / cooler:
2. Trip Blank listed on COC:
3. Samples preserved properly:
4. VOCs headspace free:
Sample Integrity - Documentation Y or N
1. Sample labels present on bottles:
2. Container labeling complete:
3. Sample container label / COC agree:
Sample Integrity - Condition Y or N
1. Sample recvd within HT:
3. Condition of sample:
2. All containers accounted for:
Sample Integrity - Instructions
1. Analysis requested is clear:
2. Bottles received for unspecified tests
3. Sufficient volume recvd for analysis:
4. Compositing instructions clear:
5. Filtering instructions clear:
Intact
Y or N
Comments Rec'd EPH in 1000ml Sulfuric bottles.
Y or N N/A
Cooler Temps:#1: (0.8/0.6);
SGS Sample Receipt Summary
Can use one container from the V6200NC and one container from the VMAVPHR to analyze for the BMAEPHR. Discussed this with Daniel Dabkowski at GES.
Suzanne Junkin 5-19-2023Responded to by:Response Date:
LA90738: Chain of Custody
Page 3 of 3
31 of 61
LA90738
5
5.
1
SGS North America Inc.
MS Volatiles
QC Data Summaries
Includes the following where applicable:
 Method Blank Summaries
 Blank Spike Summaries
 Matrix Spike and Duplicate Summaries
Scott, LA
Section 6
32 of 61
LA90738
6
Method Blank Summary Page 1 of 2
Job Number:LA90738
Account:MURPHY Murphy Oil USA, Inc.
Project:GESWCSC: Murphy #7214, Albemarle, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2K4112-MB1 2K0146549.D 1 05/23/23 MB n/a n/a V2K4112
The QC reported here applies to the following samples:Method: SM 6200B
LA90738-1, LA90738-2
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 10 1.2 ug/l
71-43-2 Benzene ND 0.50 0.27 ug/l
108-86-1 Bromobenzene ND 0.50 0.18 ug/l
74-97-5 Bromochloromethane ND 0.50 0.12 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.18 ug/l
75-25-2 Bromoform ND 0.50 0.10 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.092 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.14 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.16 ug/l
56-23-5 Carbon Tetrachloride ND 0.20 0.092 ug/l
108-90-7 Chlorobenzene ND 0.50 0.16 ug/l
75-00-3 Chloroethane ND 0.50 0.055 ug/l
67-66-3 Chloroform ND 0.50 0.094 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.16 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.20 ug/l
124-48-1 Dibromochloromethane ND 0.20 0.075 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.24 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.12 ug/l
541-73-1 m-Dichlorobenzene ND 0.50 0.063 ug/l
95-50-1 o-Dichlorobenzene ND 0.50 0.20 ug/l
106-46-7 p-Dichlorobenzene ND 0.50 0.22 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.10 ug/l
107-06-2 1,2-Dichloroethane ND 0.20 0.12 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.094 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.11 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.15 ug/l
78-87-5 1,2-Dichloropropane ND 0.30 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.21 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.079 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.12 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.20 0.10 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.20 0.056 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.073 ug/l
64-17-5 Ethyl Alcohol ND 50 8.4 ug/l
100-41-4 Ethylbenzene ND 0.50 0.20 ug/l
591-78-6 2-Hexanone ND 1.0 0.42 ug/l
33 of 61
LA90738
6
6.
1
.
1
Method Blank Summary Page 2 of 2
Job Number:LA90738
Account:MURPHY Murphy Oil USA, Inc.
Project:GESWCSC: Murphy #7214, Albemarle, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2K4112-MB1 2K0146549.D 1 05/23/23 MB n/a n/a V2K4112
The QC reported here applies to the following samples:Method: SM 6200B
LA90738-1, LA90738-2
CAS No.Compound Result RL MDL Units Q
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.23 ug/l
74-87-3 Methyl Chloride ND 0.50 0.066 ug/l
75-09-2 Methylene Chloride ND 0.50 0.080 ug/l
78-93-3 Methyl Ethyl Ketone ND 25 0.28 ug/l
108-10-1 4-Methyl-2-pentanone ND 0.50 0.24 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.068 ug/l
91-20-3 Naphthalene ND 0.50 0.10 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.22 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.18 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.20 0.12 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.22 ug/l
108-88-3 Toluene ND 0.50 0.29 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.16 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.17 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.16 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.30 0.17 ug/l
79-01-6 Trichloroethylene ND 0.50 0.18 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.073 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.023 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.15 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.16 ug/l
108-05-4 Vinyl Acetate ND 0.50 0.069 ug/l
75-01-4 Vinyl Chloride ND 0.10 0.075 ug/l
m,p-Xylene ND 1.0 0.34 ug/l
95-47-6 o-Xylene ND 0.50 0.15 ug/l
1330-20-7 Xylene (total)ND 0.50 0.16 ug/l
CAS No.Surrogate Recoveries Limits
17060-07-0 1,2-Dichloroethane-D4 98%70-130%
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 103%70-130%
34 of 61
LA90738
6
6.
1
.
1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 3
Job Number:LA90738
Account:MURPHY Murphy Oil USA, Inc.
Project:GESWCSC: Murphy #7214, Albemarle, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2K4112-BS1 2K0146546.D 1 05/23/23 MB n/a n/a V2K4112
V2K4112-BSD1 2K0146547.D 1 05/23/23 MB n/a n/a V2K4112
The QC reported here applies to the following samples:Method: SM 6200B
LA90738-1, LA90738-2
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
67-64-1 Acetone 50 58.3 117 60.1 120 3 70-130/30
71-43-2 Benzene 20 18.1 91 17.5 88 3 70-130/30
108-86-1 Bromobenzene 20 17.6 88 17.3 87 2 70-130/30
74-97-5 Bromochloromethane 20 19.1 96 18.9 95 1 70-130/30
75-27-4 Bromodichloromethane 20 21.3 107 20.7 104 3 70-130/30
75-25-2 Bromoform 20 19.3 97 19.6 98 2 70-130/30
104-51-8 n-Butylbenzene 20 19.2 96 19.1 96 1 70-130/30
135-98-8 sec-Butylbenzene 20 18.3 92 18.3 92 0 70-130/30
98-06-6 tert-Butylbenzene 20 18.1 91 18.2 91 1 70-130/30
56-23-5 Carbon Tetrachloride 20 20.4 102 20.4 102 0 70-130/30
108-90-7 Chlorobenzene 20 17.4 87 17.3 87 1 70-130/30
75-00-3 Chloroethane 20 19.9 100 19.3 97 3 60-140/30
67-66-3 Chloroform 20 17.4 87 16.6 83 5 70-130/30
95-49-8 o-Chlorotoluene 20 17.7 89 17.4 87 2 70-130/30
106-43-4 p-Chlorotoluene 20 17.8 89 17.8 89 0 70-130/30
124-48-1 Dibromochloromethane 20 21.9 110 22.1 111 1 70-130/30
106-93-4 1,2-Dibromoethane 20 19.4 97 19.6 98 1 70-130/30
75-71-8 Dichlorodifluoromethane 20 31.3 157* a 31.0 155* a 1 60-140/30
541-73-1 m-Dichlorobenzene 20 17.2 86 17.4 87 1 70-130/30
95-50-1 o-Dichlorobenzene 20 17.6 88 17.7 89 1 70-130/30
106-46-7 p-Dichlorobenzene 20 16.9 85 17.0 85 1 70-130/30
75-34-3 1,1-Dichloroethane 20 19.3 97 18.8 94 3 70-130/30
107-06-2 1,2-Dichloroethane 20 17.5 88 17.3 87 1 70-130/30
75-35-4 1,1-Dichloroethylene 20 19.7 99 19.5 98 1 70-130/30
156-59-2 cis-1,2-Dichloroethylene 20 18.6 93 18.3 92 2 70-130/30
156-60-5 trans-1,2-Dichloroethylene 20 19.5 98 19.3 97 1 70-130/30
78-87-5 1,2-Dichloropropane 20 19.2 96 18.6 93 3 70-130/30
142-28-9 1,3-Dichloropropane 20 18.6 93 18.7 94 1 70-130/30
594-20-7 2,2-Dichloropropane 20 21.3 107 20.9 105 2 70-130/30
563-58-6 1,1-Dichloropropene 20 19.3 97 18.8 94 3 70-130/30
10061-01-5 cis-1,3-Dichloropropene 20 20.9 105 20.6 103 1 70-130/30
10061-02-6 trans-1,3-Dichloropropene 20 21.4 107 21.8 109 2 70-130/30
108-20-3 Di-Isopropyl Ether 20 19.9 100 19.5 98 2 70-130/30
64-17-5 Ethyl Alcohol 400 396 99 399 100 1 70-130/30
100-41-4 Ethylbenzene 20 17.6 88 17.9 90 2 70-130/30
591-78-6 2-Hexanone 50 56.8 114 57.7 115 2 70-130/30
* = Outside of Control Limits.
35 of 61
LA90738
6
6.
2
.
1
Blank Spike/Blank Spike Duplicate Summary Page 2 of 3
Job Number:LA90738
Account:MURPHY Murphy Oil USA, Inc.
Project:GESWCSC: Murphy #7214, Albemarle, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2K4112-BS1 2K0146546.D 1 05/23/23 MB n/a n/a V2K4112
V2K4112-BSD1 2K0146547.D 1 05/23/23 MB n/a n/a V2K4112
The QC reported here applies to the following samples:Method: SM 6200B
LA90738-1, LA90738-2
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
98-82-8 Isopropylbenzene 20 17.9 90 17.9 90 0 70-130/30
99-87-6 p-Isopropyltoluene 20 18.4 92 18.5 93 1 70-130/30
74-83-9 Methyl Bromide 20 20.1 101 19.7 99 2 60-140/30
74-87-3 Methyl Chloride 20 22.9 115 22.5 113 2 60-140/30
75-09-2 Methylene Chloride 20 18.6 93 18.3 92 2 70-130/30
78-93-3 Methyl Ethyl Ketone 50 53.4 107 53.3 107 0 70-130/30
108-10-1 4-Methyl-2-pentanone 50 51.5 103 51.7 103 0 70-130/30
1634-04-4 Methyl Tert Butyl Ether 20 19.8 99 19.9 100 1 70-130/30
91-20-3 Naphthalene 20 21.0 105 21.5 108 2 70-130/30
103-65-1 n-Propylbenzene 20 18.2 91 18.4 92 1 70-130/30
100-42-5 Styrene 20 17.9 90 17.9 90 0 70-130/30
630-20-6 1,1,1,2-Tetrachloroethane 20 20.0 100 20.0 100 0 70-130/30
79-34-5 1,1,2,2-Tetrachloroethane 20 19.0 95 19.7 99 4 70-130/30
127-18-4 Tetrachloroethylene 20 17.6 88 17.6 88 0 70-130/30
108-88-3 Toluene 20 18.2 91 17.8 89 2 70-130/30
87-61-6 1,2,3-Trichlorobenzene 20 19.0 95 19.2 96 1 70-130/30
120-82-1 1,2,4-Trichlorobenzene 20 19.4 97 19.4 97 0 70-130/30
71-55-6 1,1,1-Trichloroethane 20 19.8 99 19.6 98 1 70-130/30
79-00-5 1,1,2-Trichloroethane 20 17.5 88 17.6 88 1 70-130/30
79-01-6 Trichloroethylene 20 19.3 97 18.9 95 2 70-130/30
75-69-4 Trichlorofluoromethane 20 20.2 101 19.9 100 1 60-140/30
96-18-4 1,2,3-Trichloropropane 20 20.6 103 20.8 104 1 70-130/30
95-63-6 1,2,4-Trimethylbenzene 20 18.2 91 18.1 91 1 70-130/30
108-67-8 1,3,5-Trimethylbenzene 20 18.5 93 18.5 93 0 70-130/30
108-05-4 Vinyl Acetate 20 24.3 122 24.3 122 0 70-130/30
75-01-4 Vinyl Chloride 20 20.0 100 19.9 100 1 60-140/30
m,p-Xylene 40 36.4 91 36.3 91 0 70-130/30
95-47-6 o-Xylene 20 18.2 91 17.8 89 2 70-130/30
1330-20-7 Xylene (total)60 54.6 91 54.1 90 1 70-130/30
CAS No.Surrogate Recoveries BSP BSD Limits
17060-07-0 1,2-Dichloroethane-D4 94%95%70-130%
2037-26-5 Toluene-D8 103%101%70-130%
460-00-4 4-Bromofluorobenzene 99%99%70-130%
* = Outside of Control Limits.
36 of 61
LA90738
6
6.
2
.
1
Blank Spike/Blank Spike Duplicate Summary Page 3 of 3
Job Number:LA90738
Account:MURPHY Murphy Oil USA, Inc.
Project:GESWCSC: Murphy #7214, Albemarle, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2K4112-BS1 2K0146546.D 1 05/23/23 MB n/a n/a V2K4112
V2K4112-BSD1 2K0146547.D 1 05/23/23 MB n/a n/a V2K4112
The QC reported here applies to the following samples:Method: SM 6200B
LA90738-1, LA90738-2
(a) Outside control limits biased high. Analyte not detected in associated samples.
* = Outside of Control Limits.
37 of 61
LA90738
6
6.
2
.
1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 3
Job Number:LA90738
Account:MURPHY Murphy Oil USA, Inc.
Project:GESWCSC: Murphy #7214, Albemarle, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
LA90503-7MS 2K0146551.D 5000 05/23/23 MB n/a n/a V2K4112
LA90503-7MSD 2K0146552.D 5000 05/23/23 MB n/a n/a V2K4112
LA90503-7 2K0146550.D 2000 05/23/23 MB n/a n/a V2K4112
The QC reported here applies to the following samples:Method: SM 6200B
LA90738-1, LA90738-2
LA90503-7 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
67-64-1 Acetone ND 250000 301000 120 250000 295000 118 2 70-130/20
71-43-2 Benzene 1460 100000 92800 91 100000 93100 92 0 70-130/20
108-86-1 Bromobenzene ND 100000 88600 89 100000 88800 89 0 70-130/20
74-97-5 Bromochloromethane ND 100000 99100 99 100000 98900 99 0 70-130/20
75-27-4 Bromodichloromethane ND 100000 108000 108 100000 109000 109 1 70-130/20
75-25-2 Bromoform ND 100000 97400 97 100000 101000 101 4 70-130/20
104-51-8 n-Butylbenzene ND 100000 97500 98 100000 97700 98 0 70-130/20
135-98-8 sec-Butylbenzene ND 100000 92800 93 100000 92900 93 0 70-130/20
98-06-6 tert-Butylbenzene ND 100000 91900 92 100000 91600 92 0 70-130/20
56-23-5 Carbon Tetrachloride ND 100000 104000 104 100000 106000 106 2 70-130/20
108-90-7 Chlorobenzene ND 100000 87500 88 100000 87700 88 0 70-130/20
75-00-3 Chloroethane ND 100000 71600 72 100000 71000 71 1 60-140/20
67-66-3 Chloroform ND 100000 88000 88 100000 88200 88 0 70-130/20
95-49-8 o-Chlorotoluene ND 100000 88700 89 100000 88300 88 0 70-130/20
106-43-4 p-Chlorotoluene ND 100000 89700 90 100000 90300 90 1 70-130/20
124-48-1 Dibromochloromethane ND 100000 111000 111 100000 115000 115 4 70-130/20
106-93-4 1,2-Dibromoethane ND 100000 99500 100 100000 102000 102 2 70-130/20
75-71-8 Dichlorodifluoromethane ND 100000 78500 79 100000 79400 79 1 60-140/20
541-73-1 m-Dichlorobenzene ND 100000 87600 88 100000 87100 87 1 70-130/20
95-50-1 o-Dichlorobenzene ND 100000 89300 89 100000 90000 90 1 70-130/20
106-46-7 p-Dichlorobenzene ND 100000 86600 87 100000 85900 86 1 70-130/20
75-34-3 1,1-Dichloroethane ND 100000 97400 97 100000 97600 98 0 70-130/20
107-06-2 1,2-Dichloroethane ND 100000 88600 89 100000 90500 91 2 70-130/20
75-35-4 1,1-Dichloroethylene ND 100000 101000 101 100000 101000 101 0 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 100000 94500 95 100000 95000 95 1 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 100000 98600 99 100000 100000 100 1 70-130/20
78-87-5 1,2-Dichloropropane ND 100000 97000 97 100000 98500 99 2 70-130/20
142-28-9 1,3-Dichloropropane ND 100000 94100 94 100000 97000 97 3 70-130/20
594-20-7 2,2-Dichloropropane ND 100000 106000 106 100000 107000 107 1 70-130/20
563-58-6 1,1-Dichloropropene ND 100000 98200 98 100000 97800 98 0 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 100000 106000 106 100000 107000 107 1 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 100000 108000 108 100000 110000 110 2 70-130/20
108-20-3 Di-Isopropyl Ether ND 100000 102000 102 100000 101000 101 1 70-130/20
64-17-5 Ethyl Alcohol 1960000 2000000 3680000 86 2000000 4080000 106 10 70-130/20
100-41-4 Ethylbenzene ND 100000 91000 91 100000 91400 91 0 70-130/20
591-78-6 2-Hexanone ND 250000 283000 113 250000 277000 111 2 70-130/20
* = Outside of Control Limits.
38 of 61
LA90738
6
6.
3
.
1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 3
Job Number:LA90738
Account:MURPHY Murphy Oil USA, Inc.
Project:GESWCSC: Murphy #7214, Albemarle, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
LA90503-7MS 2K0146551.D 5000 05/23/23 MB n/a n/a V2K4112
LA90503-7MSD 2K0146552.D 5000 05/23/23 MB n/a n/a V2K4112
LA90503-7 2K0146550.D 2000 05/23/23 MB n/a n/a V2K4112
The QC reported here applies to the following samples:Method: SM 6200B
LA90738-1, LA90738-2
LA90503-7 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
98-82-8 Isopropylbenzene ND 100000 91000 91 100000 91800 92 1 70-130/20
99-87-6 p-Isopropyltoluene ND 100000 92500 93 100000 92700 93 0 70-130/20
74-83-9 Methyl Bromide ND 100000 75900 76 100000 83200 83 9 60-140/20
74-87-3 Methyl Chloride ND 100000 91700 92 100000 93200 93 2 60-140/20
75-09-2 Methylene Chloride ND 100000 95100 95 100000 94300 94 1 70-130/20
78-93-3 Methyl Ethyl Ketone ND 250000 270000 108 250000 276000 110 2 70-130/20
108-10-1 4-Methyl-2-pentanone ND 250000 269000 108 250000 278000 111 3 70-130/20
1634-04-4 Methyl Tert Butyl Ether 851 J 100000 102000 101 100000 105000 104 3 70-130/20
91-20-3 Naphthalene 247 J 100000 105000 105 100000 110000 110 5 70-130/20
103-65-1 n-Propylbenzene ND 100000 92000 92 100000 92600 93 1 70-130/20
100-42-5 Styrene ND 100000 90500 91 100000 90500 91 0 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 100000 102000 102 100000 102000 102 0 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 100000 97300 97 100000 101000 101 4 70-130/20
127-18-4 Tetrachloroethylene ND 100000 86600 87 100000 89900 90 4 70-130/20
108-88-3 Toluene 1690 100000 92700 91 100000 93100 91 0 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 100000 95300 95 100000 97700 98 2 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 100000 99400 99 100000 99600 100 0 70-130/20
71-55-6 1,1,1-Trichloroethane ND 100000 100000 100 100000 103000 103 3 70-130/20
79-00-5 1,1,2-Trichloroethane ND 100000 88100 88 100000 89900 90 2 70-130/20
79-01-6 Trichloroethylene ND 100000 97200 97 100000 98700 99 2 70-130/20
75-69-4 Trichlorofluoromethane ND 100000 61800 62 100000 62400 62 1 60-140/20
96-18-4 1,2,3-Trichloropropane ND 100000 106000 106 100000 109000 109 3 70-130/20
95-63-6 1,2,4-Trimethylbenzene 863 J 100000 93000 92 100000 92900 92 0 70-130/20
108-67-8 1,3,5-Trimethylbenzene ND 100000 94100 94 100000 94400 94 0 70-130/20
108-05-4 Vinyl Acetate ND 100000 127000 127 100000 131000 131* a 3 70-130/20
75-01-4 Vinyl Chloride ND 100000 65800 66 100000 69300 69 5 60-140/20
m,p-Xylene ND 200000 185000 93 200000 184000 92 1 70-130/20
95-47-6 o-Xylene 513 J 100000 92000 91 100000 91600 91 0 70-130/20
1330-20-7 Xylene (total)1060 300000 277000 92 300000 276000 92 0 70-130/20
CAS No.Surrogate Recoveries MS MSD LA90503-7 Limits
17060-07-0 1,2-Dichloroethane-D4 95%98%99%70-130%
2037-26-5 Toluene-D8 103%102%102%70-130%
460-00-4 4-Bromofluorobenzene 100%99%103%70-130%
* = Outside of Control Limits.
39 of 61
LA90738
6
6.
3
.
1
Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number:LA90738
Account:MURPHY Murphy Oil USA, Inc.
Project:GESWCSC: Murphy #7214, Albemarle, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
LA90503-7MS 2K0146551.D 5000 05/23/23 MB n/a n/a V2K4112
LA90503-7MSD 2K0146552.D 5000 05/23/23 MB n/a n/a V2K4112
LA90503-7 2K0146550.D 2000 05/23/23 MB n/a n/a V2K4112
The QC reported here applies to the following samples:Method: SM 6200B
LA90738-1, LA90738-2
(a) Outside control limits due to matrix interference.
* = Outside of Control Limits.
40 of 61
LA90738
6
6.
3
.
1
SGS North America Inc.
MS Semi-volatiles
QC Data Summaries
Includes the following where applicable:
 Method Blank Summaries
 Blank Spike Summaries
 Matrix Spike and Duplicate Summaries
Scott, LA
Section 7
41 of 61
LA90738
7
Method Blank Summary Page 1 of 3
Job Number:LA90738
Account:MURPHY Murphy Oil USA, Inc.
Project:GESWCSC: Murphy #7214, Albemarle, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP22806-MB W59199.D 1 05/25/23 BH 05/22/23 OP22806 EW2832
The QC reported here applies to the following samples:Method: EPA 625.1
LA90738-1, LA90738-2
CAS No.Compound Result RL MDL Units Q
65-85-0 Benzoic Acid ND 20 2.0 ug/l
59-50-7 4-Chloro-3-methyl Phenol ND 5.0 0.13 ug/l
95-57-8 2-Chlorophenol ND 5.0 0.15 ug/l
120-83-2 2,4-Dichlorophenol ND 5.0 0.16 ug/l
105-67-9 2,4-Dimethylphenol ND 5.0 0.81 ug/l
51-28-5 2,4-Dinitrophenol ND 20 0.76 ug/l
534-52-1 4,6-Dinitro-o-cresol ND 10 0.14 ug/l
95-48-7 2-Methylphenol ND 5.0 0.27 ug/l
3&4-Methylphenol ND 5.0 0.18 ug/l
88-75-5 2-Nitrophenol ND 5.0 0.22 ug/l
100-02-7 4-Nitrophenol ND 25 0.15 ug/l
87-86-5 Pentachlorophenol ND 10 0.23 ug/l
108-95-2 Phenol ND 5.0 0.14 ug/l
88-06-2 2,4,6-Trichlorophenol ND 5.0 0.23 ug/l
83-32-9 Acenaphthene ND 0.20 0.079 ug/l
208-96-8 Acenaphthylene ND 0.20 0.065 ug/l
120-12-7 Anthracene ND 0.20 0.087 ug/l
56-55-3 Benzo(a)anthracene ND 0.20 0.056 ug/l
50-32-8 Benzo(a)pyrene ND 0.20 0.055 ug/l
205-99-2 Benzo(b)fluoranthene ND 0.20 0.051 ug/l
191-24-2 Benzo(g,h,i)perylene ND 0.20 0.056 ug/l
207-08-9 Benzo(k)fluoranthene ND 0.20 0.049 ug/l
100-51-6 Benzyl Alcohol ND 10 0.17 ug/l
101-55-3 4-Bromophenyl Phenyl Ether ND 5.0 0.13 ug/l
85-68-7 Butyl Benzyl Phthalate ND 5.0 0.13 ug/l
106-47-8 4-Chloroaniline ND 5.0 0.67 ug/l
111-91-1 bis(2-Chloroethoxy)methane ND 5.0 0.15 ug/l
111-44-4 bis(2-Chloroethyl)ether ND 5.0 0.18 ug/l
108-60-1 2,2'-Oxybis(1-chloropropane)ND 5.0 0.38 ug/l
91-58-7 2-Chloronaphthalene ND 5.0 0.14 ug/l
7005-72-3 4-Chlorophenyl Phenyl Ether ND 5.0 0.12 ug/l
218-01-9 Chrysene ND 0.20 0.066 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 0.20 0.068 ug/l
132-64-9 Dibenzofuran ND 5.0 0.13 ug/l
95-50-1 1,2-Dichlorobenzene ND 5.0 0.15 ug/l
541-73-1 1,3-Dichlorobenzene ND 5.0 0.22 ug/l
42 of 61
LA90738
7
7.
1
.
1
Method Blank Summary Page 2 of 3
Job Number:LA90738
Account:MURPHY Murphy Oil USA, Inc.
Project:GESWCSC: Murphy #7214, Albemarle, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP22806-MB W59199.D 1 05/25/23 BH 05/22/23 OP22806 EW2832
The QC reported here applies to the following samples:Method: EPA 625.1
LA90738-1, LA90738-2
CAS No.Compound Result RL MDL Units Q
106-46-7 1,4-Dichlorobenzene ND 5.0 0.18 ug/l
91-94-1 3,3'-Dichlorobenzidine ND 10 0.49 ug/l
84-66-2 Diethyl Phthalate ND 5.0 0.17 ug/l
131-11-3 Dimethyl Phthalate ND 5.0 0.11 ug/l
84-74-2 Di-n-butyl Phthalate ND 5.0 0.13 ug/l
117-84-0 Di-n-octyl Phthalate ND 5.0 0.13 ug/l
122-66-7 1,2-Diphenylhydrazine ND 5.0 0.17 ug/l
117-81-7 bis(2-Ethylhexyl)phthalate ND 5.0 0.17 ug/l
206-44-0 Fluoranthene ND 0.20 0.17 ug/l
86-73-7 Fluorene ND 0.20 0.075 ug/l
118-74-1 Hexachlorobenzene ND 5.0 0.18 ug/l
87-68-3 Hexachlorobutadiene ND 5.0 0.069 ug/l
77-47-4 Hexachlorocyclopentadiene ND 10 0.20 ug/l
67-72-1 Hexachloroethane ND 5.0 0.22 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 0.20 0.055 ug/l
78-59-1 Isophorone ND 5.0 0.14 ug/l
90-12-0 1-Methylnaphthalene ND 0.20 0.17 ug/l
91-57-6 2-Methylnaphthalene ND 0.20 0.053 ug/l
91-20-3 Naphthalene ND 0.20 0.071 ug/l
98-95-3 Nitrobenzene ND 5.0 0.13 ug/l
621-64-7 N-Nitroso-di-n-propylamine ND 5.0 0.14 ug/l
86-30-6 N-Nitrosodiphenylamine ND 5.0 0.68 ug/l
85-01-8 Phenanthrene ND 0.20 0.18 ug/l
129-00-0 Pyrene ND 0.20 0.17 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 5.0 0.15 ug/l
CAS No.Surrogate Recoveries Limits
367-12-4 2-Fluorophenol 56%20-75%
4165-62-2 Phenol-d5 44%10-60%
118-79-6 2,4,6-Tribromophenol 97%38-138%
4165-60-0 Nitrobenzene-d5 88%44-132%
321-60-8 2-Fluorobiphenyl 83%40-119%
1718-51-0 Terphenyl-d14 85%40-127%
43 of 61
LA90738
7
7.
1
.
1
Method Blank Summary Page 3 of 3
Job Number:LA90738
Account:MURPHY Murphy Oil USA, Inc.
Project:GESWCSC: Murphy #7214, Albemarle, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP22806-MB W59199.D 1 05/25/23 BH 05/22/23 OP22806 EW2832
The QC reported here applies to the following samples:Method:
LA90738-1, LA90738-2
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
1576-87-0 2-Pentenal, (E)-3.93 8.9 ug/l JN
565-75-3 Unknown 4.10 11 ug/l JN
Total TIC, Semi-Volatile 19.9 ug/l J
44 of 61
LA90738
7
7.
1
.
1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 2
Job Number:LA90738
Account:MURPHY Murphy Oil USA, Inc.
Project:GESWCSC: Murphy #7214, Albemarle, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP22806-BS W59200.D 1 05/25/23 BH 05/22/23 OP22806 EW2832
OP22806-BSD W59201.D 1 05/25/23 BH 05/22/23 OP22806 EW2832
The QC reported here applies to the following samples:Method: EPA 625.1
LA90738-1, LA90738-2
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
65-85-0 Benzoic Acid 100 43.2 43 40.7 41 6 12-61/34
59-50-7 4-Chloro-3-methyl Phenol 50 47.0 94 41.6 83 12 66-103/19
95-57-8 2-Chlorophenol 50 41.2 82 37.6 75 9 63-93/17
120-83-2 2,4-Dichlorophenol 50 46.0 92 40.3 81 13 70-104/18
105-67-9 2,4-Dimethylphenol 50 44.1 88 39.9 80 10 64-98/20
51-28-5 2,4-Dinitrophenol 50 48.2 96 43.9 88 9 40-138/24
534-52-1 4,6-Dinitro-o-cresol 50 51.2 102 44.8 90 13 57-131/21
95-48-7 2-Methylphenol 50 38.6 77 35.9 72 7 53-83/18
3&4-Methylphenol 50 37.2 74 34.8 70 7 51-77/18
88-75-5 2-Nitrophenol 50 48.6 97 42.2 84 14 67-114/18
100-02-7 4-Nitrophenol 50 29.9 60 28.1 56 6 23-62/28
87-86-5 Pentachlorophenol 50 47.1 94 40.6 81 15 56-113/22
108-95-2 Phenol 50 24.4 49 23.2 46 5 24-50/24
88-06-2 2,4,6-Trichlorophenol 50 49.3 99 44.4 89 10 65-116/19
83-32-9 Acenaphthene 50 46.3 93 40.1 80 14 69-107/18
208-96-8 Acenaphthylene 50 48.3 97 41.9 84 14 67-114/20
120-12-7 Anthracene 50 49.9 100 43.0 86 15 73-109/19
56-55-3 Benzo(a)anthracene 50 47.0 94 40.5 81 15 71-109/19
50-32-8 Benzo(a)pyrene 50 54.7 109 46.3 93 17 73-116/19
205-99-2 Benzo(b)fluoranthene 50 51.5 103 44.3 89 15 73-114/21
191-24-2 Benzo(g,h,i)perylene 50 52.5 105 44.5 89 16 75-113/19
207-08-9 Benzo(k)fluoranthene 50 52.8 106 44.9 90 16 71-118/19
100-51-6 Benzyl Alcohol 50 42.2 84 41.4 83 2 57-90/17
101-55-3 4-Bromophenyl Phenyl Ether 50 49.2 98 42.7 85 14 70-112/20
85-68-7 Butyl Benzyl Phthalate 50 51.2 102 43.2 86 17 72-118/20
106-47-8 4-Chloroaniline 50 42.4 85 43.8 88 3 60-105/17
111-91-1 bis(2-Chloroethoxy)methane 50 44.4 89 38.2 76 15 68-107/19
111-44-4 bis(2-Chloroethyl)ether 50 41.5 83 36.2 72 14 60-109/18
108-60-1 2,2'-Oxybis(1-chloropropane)50 41.2 82 35.6 71 15 48-119/18
91-58-7 2-Chloronaphthalene 50 45.4 91 38.6 77 16 67-106/19
7005-72-3 4-Chlorophenyl Phenyl Ether 50 47.7 95 41.3 83 14 67-115/19
218-01-9 Chrysene 50 46.1 92 39.1 78 16 74-108/19
53-70-3 Dibenzo(a,h)anthracene 50 53.6 107 45.4 91 17 75-115/19
132-64-9 Dibenzofuran 50 46.3 93 40.6 81 13 69-110/19
95-50-1 1,2-Dichlorobenzene 50 40.6 81 34.3 69 17 56-95/19
541-73-1 1,3-Dichlorobenzene 50 39.9 80 34.3 69 15 53-93/20
* = Outside of Control Limits.
45 of 61
LA90738
7
7.
2
.
1
Blank Spike/Blank Spike Duplicate Summary Page 2 of 2
Job Number:LA90738
Account:MURPHY Murphy Oil USA, Inc.
Project:GESWCSC: Murphy #7214, Albemarle, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP22806-BS W59200.D 1 05/25/23 BH 05/22/23 OP22806 EW2832
OP22806-BSD W59201.D 1 05/25/23 BH 05/22/23 OP22806 EW2832
The QC reported here applies to the following samples:Method: EPA 625.1
LA90738-1, LA90738-2
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
106-46-7 1,4-Dichlorobenzene 50 40.5 81 34.2 68 17 54-93/19
91-94-1 3,3'-Dichlorobenzidine 50 49.8 100 46.4 93 7 67-114/19
84-66-2 Diethyl Phthalate 50 49.8 100 42.6 85 16 72-115/19
131-11-3 Dimethyl Phthalate 50 48.8 98 42.3 85 14 71-114/19
84-74-2 Di-n-butyl Phthalate 50 53.2 106 45.9 92 15 74-113/20
117-84-0 Di-n-octyl Phthalate 50 53.5 107 45.8 92 16 69-118/20
122-66-7 1,2-Diphenylhydrazine 50 51.5 103 44.8 90 14 70-114/19
117-81-7 bis(2-Ethylhexyl)phthalate 50 53.5 107 45.3 91 17 69-118/20
206-44-0 Fluoranthene 50 51.1 102 43.9 88 15 73-113/20
86-73-7 Fluorene 50 48.2 96 41.4 83 15 70-112/19
118-74-1 Hexachlorobenzene 50 49.6 99 42.9 86 14 71-111/20
87-68-3 Hexachlorobutadiene 50 43.0 86 37.3 75 14 45-101/21
77-47-4 Hexachlorocyclopentadiene 50 31.3 63 27.1 54 14 36-109/25
67-72-1 Hexachloroethane 50 39.4 79 33.5 67 16 47-94/20
193-39-5 Indeno(1,2,3-cd)pyrene 50 54.2 108 45.9 92 17 75-114/19
78-59-1 Isophorone 50 46.8 94 40.4 81 15 67-111/18
90-12-0 1-Methylnaphthalene 50 46.5 93 39.5 79 16 67-102/19
91-57-6 2-Methylnaphthalene 50 44.6 89 38.5 77 15 67-102/18
91-20-3 Naphthalene 50 43.1 86 37.2 74 15 66-100/18
98-95-3 Nitrobenzene 50 44.3 89 38.2 76 15 69-109/18
621-64-7 N-Nitroso-di-n-propylamine 50 46.1 92 39.7 79 15 62-113/18
86-30-6 N-Nitrosodiphenylamine 50 47.3 95 40.8 82 15 69-110/20
85-01-8 Phenanthrene 50 47.9 96 41.6 83 14 73-106/20
129-00-0 Pyrene 50 46.7 93 40.1 80 15 74-111/18
120-82-1 1,2,4-Trichlorobenzene 50 42.5 85 36.4 73 15 57-99/19
CAS No.Surrogate Recoveries BSP BSD Limits
367-12-4 2-Fluorophenol 62%58%20-75%
4165-62-2 Phenol-d5 51%48%10-60%
118-79-6 2,4,6-Tribromophenol 104%90%38-138%
4165-60-0 Nitrobenzene-d5 95%80%44-132%
321-60-8 2-Fluorobiphenyl 91%77%40-119%
1718-51-0 Terphenyl-d14 89%75%40-127%
* = Outside of Control Limits.
46 of 61
LA90738
7
7.
2
.
1
SGS North America Inc.
GC Volatiles
QC Data Summaries
Includes the following where applicable:
 Method Blank Summaries
 Blank Spike Summaries
 Matrix Spike and Duplicate Summaries
Scott, LA
Section 8
47 of 61
LA90738
8
Method Blank Summary Page 1 of 1
Job Number:LA90738
Account:MURPHY Murphy Oil USA, Inc.
Project:GESWCSC: Murphy #7214, Albemarle, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
GLE2416-MB1 LE041285.D 1 05/22/23 JB n/a n/a GLE2416
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
LA90738-1, LA90738-2
CAS No.Compound Result RL MDL Units Q
C5- C8 Aliphatics (Unadj.)ND 100 50 ug/l
C9- C12 Aliphatics (Unadj.)ND 100 50 ug/l
C9- C10 Aromatics (Unadj.)ND 100 20 ug/l
CAS No.Surrogate Recoveries Limits
615-59-8 2,5-Dibromotoluene 88%70-130%
615-59-8 2,5-Dibromotoluene 83%70-130%
48 of 61
LA90738
8
8.
1
.
1
Method Blank Summary Page 1 of 1
Job Number:LA90738
Account:MURPHY Murphy Oil USA, Inc.
Project:GESWCSC: Murphy #7214, Albemarle, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP22822-MB LI138306.D 1 05/25/23 JT 05/25/23 OP22822 GLI1249
The QC reported here applies to the following samples:Method: EPA 504.1
LA90738-1, LA90738-2
CAS No.Compound Result RL MDL Units Q
106-93-4 1,2-Dibromoethane ND 0.020 0.0038 ug/l
CAS No.Surrogate Recoveries Limits
348-51-6 1-Chloro-2-fluorobenzene 105%70-130%
49 of 61
LA90738
8
8.
1
.
2
Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:LA90738
Account:MURPHY Murphy Oil USA, Inc.
Project:GESWCSC: Murphy #7214, Albemarle, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
GLE2416-BS1 LE041283.D 1 05/22/23 JB n/a n/a GLE2416
GLE2416-BSD1 LE041284.D 1 05/22/23 JB n/a n/a GLE2416
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
LA90738-1, LA90738-2
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
C5- C8 Aliphatics (Unadj.)120 131 110 125 104 5 70-130/25
C9- C12 Aliphatics (Unadj.)120 128 107 123 102 4 70-130/25
C9- C10 Aromatics (Unadj.)40 37.6 94 37.4 94 1 70-130/25
CAS No.Surrogate Recoveries BSP BSD Limits
615-59-8 2,5-Dibromotoluene 91%92%70-130%
615-59-8 2,5-Dibromotoluene 86%87%70-130%
* = Outside of Control Limits.
50 of 61
LA90738
8
8.
2
.
1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:LA90738
Account:MURPHY Murphy Oil USA, Inc.
Project:GESWCSC: Murphy #7214, Albemarle, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP22822-BS LI138307.D 1 05/25/23 JT 05/25/23 OP22822 GLI1249
OP22822-BSD LI138308.D 1 05/25/23 JT 05/25/23 OP22822 GLI1249
The QC reported here applies to the following samples:Method: EPA 504.1
LA90738-1, LA90738-2
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
106-93-4 1,2-Dibromoethane 0.251 0.24 95 0.24 95 0 70-130/20
CAS No.Surrogate Recoveries BSP BSD Limits
348-51-6 1-Chloro-2-fluorobenzene 96%97%70-130%
* = Outside of Control Limits.
51 of 61
LA90738
8
8.
2
.
2
Duplicate Summary Page 1 of 1
Job Number:LA90738
Account:MURPHY Murphy Oil USA, Inc.
Project:GESWCSC: Murphy #7214, Albemarle, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
LA90738-1DUP LE041288.D 1 05/22/23 JB n/a n/a GLE2416
LA90738-1 LE041287.D 1 05/22/23 JB n/a n/a GLE2416
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
LA90738-1, LA90738-2
LA90738-1 DUP
CAS No.Compound ug/l Q ug/l Q RPD Limits
C5- C8 Aliphatics (Unadj.)100 U ND nc 50
C9- C12 Aliphatics (Unadj.)100 U ND nc 50
C9- C10 Aromatics (Unadj.)100 U ND nc 50
CAS No.Surrogate Recoveries DUP LA90738-1 Limits
615-59-8 2,5-Dibromotoluene 90%92%70-130%
615-59-8 2,5-Dibromotoluene 85%86%70-130%
* = Outside of Control Limits.
52 of 61
LA90738
8
8.
3
.
1
SGS North America Inc.
GC/LC Semi-volatiles
QC Data Summaries
Includes the following where applicable:
 Method Blank Summaries
 Blank Spike Summaries
 Matrix Spike and Duplicate Summaries
Scott, LA
Section 9
53 of 61
LA90738
9
Method Blank Summary Page 1 of 1
Job Number:LA90738
Account:MURPHY Murphy Oil USA, Inc.
Project:GESWCSC: Murphy #7214, Albemarle, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP22798-MB LZ0022736.D 1 05/24/23 KM 05/22/23 OP22798 GLZ496
The QC reported here applies to the following samples:Method: MADEP EPH REV 2.1
LA90738-1, LA90738-2
CAS No.Compound Result RL MDL Units Q
C11-C22 Aromatics (Unadj.)ND 370 230 ug/l
C9-C18 Aliphatics ND 370 190 ug/l
C19-C36 Aliphatics ND 370 80 ug/l
CAS No.Surrogate Recoveries Limits
3386-33-2 1-Chlorooctadecane 95%40-140%
84-15-1 o-Terphenyl 97%40-140%
321-60-8 2-Fluorobiphenyl 78%40-140%
54 of 61
LA90738
9
9.
1
.
1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:LA90738
Account:MURPHY Murphy Oil USA, Inc.
Project:GESWCSC: Murphy #7214, Albemarle, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP22798-BS LZ0022732A.D1 05/24/23 KM 05/22/23 OP22798 GLZ496
OP22798-BSD LZ0022740.D 1 05/24/23 KM 05/22/23 OP22798 GLZ496
The QC reported here applies to the following samples:Method: MADEP EPH REV 2.1
LA90738-1, LA90738-2
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
C11-C22 Aromatics (Unadj.)7870 7430 94 6490 82 14 40-140/30
C9-C18 Aliphatics 2780 3480 125 2660 96 27 40-140/30
C19-C36 Aliphatics 3700 3830 103 3320 90 14 40-140/30
CAS No.Surrogate Recoveries BSP BSD Limits
3386-33-2 1-Chlorooctadecane 76%93%40-140%
84-15-1 o-Terphenyl 110%94%40-140%
321-60-8 2-Fluorobiphenyl 84%80%40-140%
Sample Compound Col #1 Col #2 Breakthrough Limit
OP22798-BS 2-Methylnaphthalene 464 ND 0.0%5.0
OP22798-BS Naphthalene 430 ND 0.0%5.0
OP22798-BSD 2-Methylnaphthalene 429 ND 0.0%5.0
OP22798-BSD Naphthalene 401 ND 0.0%5.0
* = Outside of Control Limits.
55 of 61
LA90738
9
9.
2
.
1
SGS North America Inc.
Metals Analysis
QC Data Summaries
Includes the following where applicable:
 Method Blank Summaries
 Matrix Spike and Duplicate Summaries
 Blank Spike and Lab Control Sample Summaries
 Serial Dilution Summaries
Scott, LA
Section 10
56 of 61
LA90738
10
BLANK RESULTS SUMMARY
Part 2 - Method Blanks
Login Number: LA90738
Account: MURPHY - Murphy Oil USA, Inc.
Project: GESWCSC: Murphy #7214, Albemarle, NC
QC Batch ID: MP26340 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 05/22/23
MB
Metal RL IDL MDL raw final
Aluminum 100 13 25
Antimony 6.0 2 3.6
Arsenic 10 2.4 8.6
Barium 10 .36 1.7
Beryllium 4.0 .06 .9
Boron 100 .72 42
Cadmium 5.0 .14 .9
Calcium 100 3.8 32
Chromium 10 .39 1.2
Cobalt 10 .26 1.1
Copper 10 .77 2.8
Iron 100 2.9 18
Lead 10 1.4 3.7 -0.71 <10
Lithium 10 2.4 4.3
Magnesium 100 22 40
Manganese 10 .11 .9
Molybdenum 10 .16 1.7
Nickel 10 .29 1.5
Potassium 500 50 120
Selenium 10 1.5 4.3
Silver 10 .57 3.7
Sodium 500 20 120
Strontium 10 .1 3
Thallium 10 1.5 4.6
Tin 10 .74 1.7
Titanium 10 .41 .8
Vanadium 10 .39 1.5
Zinc 20 .18 12
Associated samples MP26340: LA90738-1, LA90738-2
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
57 of 61
LA90738
10
10
.
1
.
1
MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: LA90738
Account: MURPHY - Murphy Oil USA, Inc.
Project: GESWCSC: Murphy #7214, Albemarle, NC
QC Batch ID: MP26340 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 05/22/23
LA90738-1 Spikelot QC
Metal Original MS ICPSPIKE1% Rec Limits
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead 7.3 977 1000 97.0 75-125
Lithium
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP26340: LA90738-1, LA90738-2
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
58 of 61
LA90738
10
10
.
1
.
2
MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: LA90738
Account: MURPHY - Murphy Oil USA, Inc.
Project: GESWCSC: Murphy #7214, Albemarle, NC
QC Batch ID: MP26340 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 05/22/23
LA90738-1 Spikelot MSD QC
Metal Original MSD ICPSPIKE1% Rec RPD Limit
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead 7.3 973 1000 96.6 0.4 20
Lithium
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP26340: LA90738-1, LA90738-2
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 2
59 of 61
LA90738
10
10
.
1
.
2
SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY
Login Number: LA90738
Account: MURPHY - Murphy Oil USA, Inc.
Project: GESWCSC: Murphy #7214, Albemarle, NC
QC Batch ID: MP26340 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 05/22/23
BSP Spikelot QC
Metal Result ICPSPIKE1% Rec Limits
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead 976 1000 97.6 80-120
Lithium
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP26340: LA90738-1, LA90738-2
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
60 of 61
LA90738
10
10
.
1
.
3
SERIAL DILUTION RESULTS SUMMARY
Login Number: LA90738
Account: MURPHY - Murphy Oil USA, Inc.
Project: GESWCSC: Murphy #7214, Albemarle, NC
QC Batch ID: MP26340 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 05/22/23
LA90738-1 QC
Metal Original SDL 1:5 %DIF Limits
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead 7.30 0.00 100.0(a) 0-20
Lithium
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP26340: LA90738-1, LA90738-2
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
(a) Percent difference acceptable due to low initial sample concentration (< 50 times IDL).
_________________________________________________________________________________________________________
Page 1
61 of 61
LA90738
10
10
.
1
.
4