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HomeMy WebLinkAbout24003_North Davidson II_VIMS Post-Construction Report_Pavilion_20240329 Post-Construction Sampling Report Pavilion Structure North Davidson II Brownfields Property 2315 N. Davidson Street and 421 E. 26th Street Brownfields Project No. 24003-20-060 Charlotte, North Carolina H&H Job No. PAM-003 March 29, 2024 #C-1269 Engineering #C-245 Geology i https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/Pavilion Structure/Sampling/2024-01/Text/24003_North Davidson II_VIMS Post-Occ Report_Pavillion_3.29.24.docx Post-Construction Sampling Report Pavilion Structure North Davidson II Brownfields Property 2315 N. Davidson Street and 421 E. 26th Street Charlotte, North Carolina Brownfields Project No. 24003-20-060 H&H Job No. PAM-003 Table of Contents 1.0 Introduction and Background ...............................................................................................1  2.0 Post-Construction Sampling Activities .................................................................................3  2.1 Sub-Slab Vapor Sampling Methodology ..............................................................................3  2.2 Sub-Slab Vapor Sampling Results ........................................................................................4  2.3 Building Survey Activities ....................................................................................................6  2.4 Indoor Air Sampling Methodology .......................................................................................6  2.5 Indoor Air Sampling Results ................................................................................................8  3.0 Summary, Conclusions, and Recommendations ................................................................10  Figures Figure 1 Site Location Map Figure 2 Site Layout Map Figure 3 Sample Location Map Tables Table 1 Summary of Post-Construction Sampling Analytical Data ii https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/Pavilion Structure/Sampling/2024-01/Text/24003_North Davidson II_VIMS Post-Occ Report_Pavillion_3.29.24.docx Appendices Appendix A Excerpts from Previous Assessment Activities Appendix B Photographic Log Appendix C Field Forms Appendix D Laboratory Analytical Reports Appendix E DEQ Risk Calculator Summary Pages 1 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/Pavilion Structure/Sampling/2024-01/Text/24003_North Davidson II_VIMS Post-Occ Report_Pavillion_3.29.24.docx Post-Construction Sampling Report Pavilion Structure North Davidson II Brownfields Property 2315 N. Davidson Street and 421 E. 26th Street Charlotte, North Carolina Brownfields Project No. 24003-20-060 H&H Job No. PAM-003 1.0 Introduction and Background On behalf of Mill District Partners LLC (Prospective Developer, PD), Hart & Hickman, PC (H&H) has prepared this report summarizing post-construction sampling activities completed at the pavilion structure at the North Davidson II North Carolina Department of Environmental Quality (DEQ) Brownfields property (Brownfields Project No. 24003-20-060). The Brownfields property is located at 2315 N. Davidson Street and 421 E. 26th Street in Charlotte, Mecklenburg County, North Carolina (Site or subject Site). A Brownfields Agreement between DEQ and the PD was recorded for the Site on June 9, 2021. The Site has been developed for non-residential use by Mill District Partners, LLC which also manages the property. A Site location map is included as Figure 1, and a Site layout map is included as Figure 2. The Site consists of two parcels of land (Parcel Identification Numbers 08305204 and 08305206) that total approximately 3.8 acres and are separated by a pedestrian walkway that replaced an inactive rail corridor. The southeastern parcel (2315 N. Davidson Street) is developed with an approximate 29,000-square foot (sq ft) commercial building that was retrofitted to a commercial space known as the Urban District Market (UDM) food hall and office spaces. The northwestern parcel (421 E. 26th Street) is developed with an approximate 16,800-sq ft building that was retrofitted for Seoul Food Company, a commercial restaurant and entertainment space. A pavilion structure (Pavilion) was also constructed in between the two buildings which consists of a partially enclosed kitchen with a concession-style serving window. This report pertains to the post- construction sampling activities for the Pavilion. Vapor intrusion mitigation system (VIMS) activities for the 421 E. 26th Street building and 2315 N. Davidson Street building are documented under separate cover. 2 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/Pavilion Structure/Sampling/2024-01/Text/24003_North Davidson II_VIMS Post-Occ Report_Pavillion_3.29.24.docx The Pavilion is a one-story, partially enclosed building that is approximately 420 sq ft in area. Unlike the other two buildings at the Site, the Pavilion was built as new construction. The Pavilion will be utilized for restaurant services and includes a small kitchen and service window with exterior (non-enclosed) guest seating areas. To date, the Pavilion has not been occupied by a tenant and remains unused. To address potential environmental concerns in connection with the Site, a Brownfields Agreement between the DEQ and the PD was recorded for the Site on June 9, 2021. Land Use Restriction (LUR) h. included in the Brownfields Agreement generally states that no enclosed building on the property may be occupied until DEQ determines in writing that the building would be protective of users from risks of potential vapor intrusion. Historical assessments at the 421 E. 26th Street parcel prior to redevelopment indicated acceptable risk levels. However, historical assessment activities at the 2315 N. Davidson Street building indicated the presence of trichloroethylene (TCE) and tetrachlorethylene (PCE) in sub-slab vapor samples at concentrations above their respective screening limits (see Appendix A). Therefore, as a precaution for potential future migration of site contaminants, specifically TCE and PCE, a passive VIMS was installed at the Seoul Food building and an active VIMS was installed in the 2315 N. Davidson Street building in accordance with the Vapor Intrusion Mitigation Plan – Revision 2 (VIMP) dated May 6, 2021. A VIMS was not installed in the Pavilion. As discussed with DEQ via email and phone call regarding the Pavilion structure, two post-construction sampling events were required to evaluate risks from vapor intrusion into the Pavilion: one sampling event after the pavilion structure was complete and another approximately six months after completion. In a call with DEQ in December of 2023, DEQ stated that if vapor intrusion assessment data for the Pavilion indicates acceptable indoor air conditions for two consecutive post-construction sampling events, no further sampling at the Pavilion or retrofitting of the Pavilion with a VIMS will be necessary. A summary of the two semi-annual post-construction sampling events is discussed in the sections below. 3 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/Pavilion Structure/Sampling/2024-01/Text/24003_North Davidson II_VIMS Post-Occ Report_Pavillion_3.29.24.docx 2.0 Post-Construction Sampling Activities Post-construction sampling included collecting one sub-slab vapor sample and one indoor air sample during each sampling event. Comparison of the sub-slab vapor sample data to the indoor air sample data allows for evaluation of potential vapor intrusion pathways and potential above- slab interference due to potential off-gassing of vapors from construction materials. In order to collect a sub-slab vapor sample from the pavilion structure, H&H installed a sub-slab Cox- Colvin® Vapor Pin® (Vapor Pin) in the center of the pavilion structure which is identified as MP-P1. The Vapor Pin monitoring point was finished with a rubber cap and flush-mounted stainless-steel cover per standard manufacturer installation procedures. A photographic log of the pavilion structure is included as Appendix B. H&H performed post-construction sampling after construction of the Pavilion was completed in May 2023 and approximately eight months later in January 2024. The sub-slab vapor and indoor air sampling activities were conducted in general accordance with the DEQ-approved VIMPs for the other two Site buildings and the DEQ DWM Vapor Intrusion Guidance (Guidance) dated March 2018. Details regarding the sub-slab vapor and indoor air sampling methodology and results are described in the sections below. 2.1 Sub-Slab Vapor Sampling Methodology On May 17, 2023, and January 18, 2024, H&H collected one sub-slab vapor sample from a monitoring point (identified as P-1 or MP-P1) installed within the Pavilion for comparison to indoor air sample analytical data. The sub-slab vapor sample was collected following collection of the indoor air sample (Section 2.3) to avoid potential interference with the indoor air sampling during opening and purging of the monitoring point. At the monitoring point, Teflon sample tubing was secured to the Vapor Pin and connected to an airflow regulator and laboratory-supplied batch-certified 1-liter stainless steel Summa canister. The airflow regulator was preset by the laboratory to collect a vapor sample at a flow rate of approximately 100 milliliters per minute. 4 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/Pavilion Structure/Sampling/2024-01/Text/24003_North Davidson II_VIMS Post-Occ Report_Pavillion_3.29.24.docx Upon Summa canister receipt, H&H performed a shut-in test to verify the canister and regulator were properly sealed by the laboratory. Prior to sample collection, H&H conducted a leak test at the monitoring point by placing a shroud around the monitoring point and sampling train including the Summa canister. The air within the shroud was flooded with helium gas and concentrations were measured with a calibrated helium detector. Helium concentrations by volume within the shroud were maintained between approximately 10% to 15%. A small air pump was connected to the sample tubing outside of the shroud and used to purge a minimum of three sample train volumes into a Tedlar® bag at the sampling point. The helium gas detector was used to measure helium concentrations within the Tedlar® bag sample to confirm helium concentrations in the sample were less than 10% of that measured within the shroud. Results of the helium leak checks indicate that short-circuiting at the monitoring point or within the sampling train did not occur. Sub-slab vapor sample field forms completed by sampling personnel are included in Appendix C. Following a successful leak check, the airflow regulators were opened to allow collection of the sub-slab vapor sample. The vacuum in the Summa canister was monitored during the sampling event to confirm adequate sample volume was collected from the monitoring point. Per laboratory standard operating procedures, a vacuum of approximately 5 inches of mercury (inHg) was maintained within the canister at the conclusion of the sampling events. Upon completion of sample collection, the airflow regulator was closed to the Summa canister. The canisters were labeled with the sample identification, date, time, starting and ending vacuums, and requested analysis. The canisters were then placed in laboratory-supplied shipping containers and delivered to Waypoint Analytical (Waypoint) under standard chain of custody protocols for analysis of volatile organic compounds (VOCs) by Environmental Protection Agency (EPA) Method TO-15. 2.2 Sub-Slab Vapor Sampling Results A tabular summary of the sub-slab vapor sample analytical results is provided in Table 1. As the building is for commercial purposes, the sub-slab vapor sample laboratory analytical results were compared to the DEQ DWM Non-Residential Soil Gas Screening Levels (SGSLs) dated February 2024. The laboratory analytical reports with chain of custody records are provided as Appendix D. Note, during the January 2024 sampling, indoor air samples were also collected at 5 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/Pavilion Structure/Sampling/2024-01/Text/24003_North Davidson II_VIMS Post-Occ Report_Pavillion_3.29.24.docx the 2315 N. Davidson Street and 421 E. 26th Street buildings during the same sampling event. Therefore, these samples are included in the analytical laboratory reports but the data from these samples will be reported under separate cover. Laboratory analytical results indicate the presence of several VOCs detected above laboratory method detection limits (MDLs) during both sampling events, but all the detected compound concentrations are below the DEQ Non-Residential SGSLs. TCE, the primary contaminant of concern (COC) on the Site, was not detected in the sub-slab sample from MP-P1 during either sampling event. Risk Calculations The DEQ DWM Vapor Intrusion SGSLs used for comparison to the laboratory analytical results are conservative and based on a target carcinogenic risk (TCR) for potential carcinogenic risks of 1.0 x 10-6 and a non-carcinogenic hazard quotient (HQ) of 0.2. The DEQ acceptable level for potential carcinogenic risks is a cumulative lifetime incremental cancer risk (LICR) of 1.0 x 10-4 or less, and the acceptable level for non-carcinogenic risks is a cumulative hazard index (HI) of 1.0 or less. The HI is the sum of HQs for each detected compound. To further evaluate potential health risks associated with the sub-slab vapor concentrations, H&H used DEQ’s Risk Calculator dated February 2024 to calculate cumulative risk levels using MP-P1 data from both sampling events. Results of the risk calculations for a non-residential use scenario are shown in the table below and included in Table 1, and the DEQ Risk Calculator input/output summaries are provided as Appendix E. Sample Date Sample Location Cumulative LICR Cumulative HI May 17, 2023 P-1 1.2 x 10-7 0.0052 January 18, 2024 MP-P1 3.2 x 10-8 0.0048 As shown in the table above, risk calculator results indicate that calculated cumulative LICR values and HI values are below the acceptable risk levels for a non-residential use scenario. These sub- slab vapor sample results and risk calculations indicate that VOC concentrations below the slab 6 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/Pavilion Structure/Sampling/2024-01/Text/24003_North Davidson II_VIMS Post-Occ Report_Pavillion_3.29.24.docx are not present at levels that would pose an unacceptable risk to the commercial occupants of the pavilion structure. 2.3 Building Survey Activities Prior to beginning sub-slab vapor and indoor air sampling activities, H&H completed a survey in the building to identify materials used or stored in the building that may contain COCs. No storage or use of chemicals with COCs, such as TCE or other chlorinated solvents, was identified during the sampling event. Because the Pavilion is not currently occupied by a tenant, the building was under fully closed conditions during sampling, which is considered more conservative than likely normal operating conditions when the vendor service window would be opened and interior air in the conjoined kitchen would be actively vented out of the Pavilion. A copy of the indoor air building survey completed during the day of sampling is provided as Appendix C. 2.4 Indoor Air Sampling Methodology Prior to collecting sub-slab vapor samples on May 17, 2023, and January 18, 2024, H&H collected one indoor air sample from the center of the pavilion (identified as P-1 or IAS-P1) for laboratory analysis within the Pavilion. Upwind exterior background air samples, BKG-051723 and IAS-BKG, were collected concurrently with the indoor air samples to evaluate compound concentrations in ambient outdoor air. Additionally, one duplicate indoor air sample was collected during each sampling event. During the first post-construction sampling event in May 2023, the duplicate was collected from another building at the Site that was sampled at the same time as the Pavilion. During the second post-construction sampling event in January 2024, the duplicate (IAS- DUP) was collected along with the parent indoor air sample, IAS-P1. The duplicate samples were collected by utilizing a laboratory-supplied stainless-steel sampling “T”, which allows for the simultaneous collection of two indoor air samples from a single location. The indoor air sample location is shown on Figure 3. The indoor air samples were collected using laboratory-supplied 6-liter stainless steel Summa sample canisters connected to in-line flow controllers with a vacuum gauge. The Summa canisters 7 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/Pavilion Structure/Sampling/2024-01/Text/24003_North Davidson II_VIMS Post-Occ Report_Pavillion_3.29.24.docx used for the indoor air samples were individually-certified by the laboratory, while the Summa canisters for the background air samples were batch-certified by the laboratory. The flow controllers were calibrated by the laboratory to allow for sample collection over an approximate 8-hour period, which is consistent with a non-residential use scenario. Teflon tubing was connected to the flow controller with the Teflon tubing elevated by a laboratory stand so that the sample intake point was positioned approximately 5 ft above grade (typical breathing zone height) when the sample canister was set on its base. During sampling activities, indoor/outdoor air pressure differential was measured near the start, middle, and end of the sampling period using a manometer sensitive to 0.001 inches of water column (in-WC). In addition, barometric pressure, exterior wind speed, exterior wind direction, and indoor/outdoor temperature were recorded near the start, middle, and end of the sampling period. Results of differential pressure measurements indicated that there was no measurable difference between the indoor and outdoor pressures during the sampling events. A summary of the field measurement data collected at the time of the indoor air sampling event is included in Appendix C. For QA/QC purposes, H&H personnel periodically monitored the sample canisters to monitor vacuum pressures and prevent tampering or damage during the sampling event. Vacuum was measured in each of the Summa canisters prior to and after sampling activities. Per laboratory standard operating procedures, a vacuum of approximately 5 to 8 inches of mercury (inHg) was maintained within the canisters at the conclusion of the sampling event. After approximately 8 hours of sampling, the samples were closed to air intake, properly labeled with the sample identification, date, time, starting and ending vacuums, and requested analysis. The canisters were then placed in laboratory-supplied shipping containers and delivered to Waypoint under standard chain of custody protocols for analysis of VOCs by EPA Method TO-15. Note, the VIMP for the other Site buildings included a Site-specific TO-15 list for indoor air sampling, but due to a lack of VIMS and historical sampling at the footprint of the Pavilion, the indoor air samples were analyzed by full-list VOCs. 8 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/Pavilion Structure/Sampling/2024-01/Text/24003_North Davidson II_VIMS Post-Occ Report_Pavillion_3.29.24.docx 2.5 Indoor Air Sampling Results A tabular summary of the analytical results is provided in Table 1. The indoor air sample laboratory analytical results were compared to the DEQ DWM Non-Residential Indoor Air Screening Levels (IASLs) dated February 2024. The laboratory analytical reports and chain of custody records are included in Appendix D. The indoor air sample analytical results indicate that several compounds were detected at concentrations above laboratory MDLs in the indoor air samples; however, none of these concentrations were above the Non-Residential IASLs. TCE, the primary COC at the Site, was not detected above laboratory MDLs during either of the indoor air sampling events. During the January 2024 sampling event, TCE was detected at a concentration of 1.02 J µg/m3 in the ambient outdoor background sample, which was located south of the 2315 N. Davidson Street building. Risk Calculations The DEQ DWM IASLs used for comparison to the laboratory analytical results are conservative and based on a TCR for potential carcinogenic risks of 1.0 x 10-6 and a non-carcinogenic HQ of 0.2. The DEQ acceptable level for potential carcinogenic risks is a cumulative LICR of 1.0 x 10-4 or less, and the acceptable level for non-carcinogenic risks is a cumulative HI of 1.0 or less. The HI is the sum of HQs for each detected compound. To further evaluate potential health risks posed by indoor air conditions, H&H used DEQ’s Risk Calculator dated February 2024 to calculate cumulative carcinogenic and non-carcinogenic risk levels using May 2023 and January 2024 indoor air data. Results of the risk calculations for a non- residential use scenario are shown in the table below and included in Table 1, and the DEQ Risk Calculator input/output summaries are provided as Appendix E. Sample Date Monitoring Point Cumulative LICR Cumulative HI May 17, 2023 P-1 3.5 x 10-7 0.049 January 18, 2024 IAS-P-1 / IAS-DUP 7.7 x 10-7 0.029 9 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/Pavilion Structure/Sampling/2024-01/Text/24003_North Davidson II_VIMS Post-Occ Report_Pavillion_3.29.24.docx As shown in the table above, risk calculator results indicate that the cumulative LICR and HI values are below the DEQ acceptable risk levels for a non-residential use scenario. These indoor air sample results and risk calculations indicate that concentrations of compounds in indoor air are not present at levels that would pose an unacceptable risk to the commercial occupants of the Pavilion structure. 10 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/PAMAKA - PAM/PAM-003 N. Davidson & E. 26th/VIMS/Pavilion Structure/Sampling/2024-01/Text/24003_North Davidson II_VIMS Post-Occ Report_Pavillion_3.29.24.docx 3.0 Summary, Conclusions, and Recommendations H&H has completed the two semi-annual post-construction sub-slab vapor and indoor air sampling events at the pavilion structure located on the North Davidson II Brownfields Property in Charlotte, North Carolina. The results of the post-construction activities indicate the following:  In May 2023 and January 2024, H&H collected one indoor air sample and one sub-slab vapor sample from the Pavilion. No VOCs were detected above the Non-Residential SGSLs or Non-Residential IASLs.  The main Site contaminant of concern, TCE, was not detected in any of the indoor air or sub-slab vapor samples above the laboratory MDLs.  The results of cumulative risk calculations for both post-construction sampling events indicate that carcinogenic and non-carcinogenic risk levels are below DEQ acceptable levels for a non-residential use scenario. Recommendations Based on the results of vapor intrusion assessment and conclusions presented above, H&H requests no vapor intrusion mitigation and no further post-construction sampling be required at the Pavilion structure. Tables Table 1 Summary of Post-Construction Sampling Analytical Data North Davidson II Brownfields Site 2315 N. Davidson St. & 421 E. 26th St. Charlotte, North Carolina Brownfields Project No. 24003-20-060 H&H Job No. PAM-003 Evaluation Area Sample ID P-1 BKG-051723 IAS-BKG P-1 MP-P1 Sample Date 5/17/2023 5/17/2023 1/18/2024 5/18/2023 1/18/2024 Sample Type VOCs (TO-15) µg/m3 Acetone 138 14.7 14.3 20.1 8.25 B NE 6.71 6.79 B NE Benzene 0.527 J 1.01 J 1.02 J 0.421 J 0.888 J 1.6 0.338 J <0.073 160 Carbon Disulfide 0.258 J 1.29 J 0.750 J <0.060 0.890 J 610 1.75 J <0.060 61,000 Chloroform <0.086 <0.086 <0.086 <0.086 <0.086 0.53 3.51 0.737 J 53 Chloromethane 0.706 J 0.823 J 0.797 J 0.747 J 0.836 J 79 <0.067 <0.067 7,900 Dichlorodifluoromethane 2.32 J 2.79 2.78 2.37 J 2.80 88 12.5 13.4 8,800 Ethylbenzene <0.106 0.486 J 0.590 J <0.106 0.343 J 4.9 <0.106 0.968 J 490 1,1,2-Trichloro-1,2,2-trifluoroethane <0.128 0.574 J <0.128 <0.128 0.605 J 4,400 <0.128 <0.561 440,000 Heptane 0.831 J 0.459 J 0.581 J 0.549 J 0.454 J 350 <0.143 <0.143 35,000 n-Hexane 0.641 J 0.687 J 0.662 J 0.807 J 0.609 J 610 0.327 J 0.334 J 61,000 2-Hexanone 1.50 J <0.285 <0.285 <0.285 <0.285 26 <0.285 <0.285 2,600 Isopropyl Alcohol 15.2 3.97 J,B 3.92 J, B <0.139 3.13 J,B 180 1.21 J 2.92 J, B 18,000 Methyl Ethyl Ketone (MEK)9.54 1.38 J 1.38 J 1.05 J 2.90 4,400 0.751 J 0.931 J 440,000 4-Methyl-2-Pentanone (MIBK)0.421 J <0.121 <0.121 <0.121 <0.121 2,600 <0.121 <0.121 260,000 Methylene Chloride <0.488 1.54 J 1.32 J <0.488 1.23 J 530 2.07 1.46 J 53,000 Naphthalene <0.183 <0.183 <0.183 3.89 <0.183 0.36 1.46 J <0.183 36 Propene 0.786 J <0.242 <0.242 <0.242 <0.242 2,600 <0.242 <0.242 260,000 Styrene 0.711 J <0.124 <0.124 <0.124 <0.124 880 <0.124 <0.124 88,000 Tetrachloroethene 0.746 J <0.181 <0.181 <0.181 <0.181 35 63.8 76.1 3,500 Tetrahydrofuran 1.72 0.392 J 0.406 J <0.107 2.83 1,800 0.327 J 1.57 180,000 Toluene 6.90 2.00 2.16 1.67 J 2.08 4,400 1.13 J 0.395 J,B 440,000 1,1,1-Trichloroethane <0.144 <0.144 <0.144 <0.144 <0.144 4,400 2.54 J 0.932 J 440,000 Trichloroethene <0.199 <0.199 <0.199 <0.199 1.02 J 1.8 <0.199 <0.199 180 Trichlorofluoromethane 1.37 J 1.63 J 1.58 J 1.53 J 1.64 J NE 3.57 1.74 J NE 1,2,4-Trimethylbenzene 0.491 J <0.110 <0.110 <0.110 <0.110 53 1.06 J <0.110 5,300 o-Xylene 0.494 J 0.625 J 0.772 J <0.157 0.351 J 88 <0.157 1.53 J 8,800 m,p-Xylene <0.217 1.83 J 2.21 J <0.217 0.903 J 88 <0.217 4.52 J 8,800 Xylene (Total)0.494 J 2.46 J 2.98 J <0.157 1.25 J 88 <0.157 6.05 J 8,800 DEQ Cumulative Risk Calculator (3) Sample Date (Month, Year)May 2023 January 2024 May 2023 January 2024 Carcinogenic Risk (LICR)3.5 x 10-7 7.7 x 10-7 1.2 x 10-7 3.2 x 10-8 <1.0 x 10-4 Non-Carcinogenic Hazard Index (HI)0.049 0.029 0.0052 0.0048 <1.0 Notes: 1) North Carolina Department of Environmental Quality (DEQ) Division of Waste Management (DWM) Vapor Intrusion Indoor Air Screening Levels (IASLs) dated February 2024 and based upon TCR = 1 x 10-6 and THQ = 0.2. 2) North Carolina Department of Environmental Quality (DEQ) Division of Waste Management (DWM) Sub-Slab and Exterior Soil Gas Screening Levels (SGSLs) dated February 2024 and based upon TCR = 1 x 10-6 and THQ = 0.2.. 3) NCDEQ DWM Cumulative Risk Calculator dated February 2024. Cumulative LICR and HI calculated using the worst-case scenario and compared to DEQ and EPA acceptable risk levels for carcinogenic and non-carcinogenic risks. Green highlighted results are from the most recent sampling event. Concentrations are reported in micrograms per cubic meter (µg/m3). Laboratory analytical method is shown in parentheses. Only compounds detected in at least one sample are shown in the above table. Bold values indicate an exceedance of DWM Non-Residential IASL or SGSL. TCR = Target Cancer Risk; THQ = Non-Carcinogenic Target Hazard Quotient; LICR = Lifetime Incremental Cancer Risk; HI = Hazard Index VOCs = volatile organic compounds; NE = not established. J = Compound was detected above the laboratory method detection limit, but below the laboratory reporting limit resulting in a laboratory estimated concentration. B = Compound was detected in the laboratory method blank. Non-Residential IASLs (1) (µg/m3) Non-Residential - Indoor Air Pavilion Structure - 421 East 26th Street Acceptable Risk Levels Non-Residential - Soil Gas to Indoor Air Non-Residential SGSLs (2) (µg/m3) Background Sub-Slab IAS-P1 / IAS-DUP 1/18/2024 Indoor Air https://harthick.sharepoint.com/sites/MasterFiles‐1/Shared Documents/AAA‐Master Projects/PAMAKA ‐ PAM/PAM‐003 N. Davidson & E. 26th/VIMS/Pavilion Structure/Sampling/2024‐01/Tables/Tables ‐ Pavilion 2023‐2024 2/21/2024 Table 1 (Page 1 of 1) Hart & Hickman, PC Figures 0 2000 4000 APPROXIMATE SCALE IN FEETN U.S.G.S. QUADRANGLE MAP QUADRANGLE 7.5 MINUTE SERIES (TOPOGRAPHIC) CHARLOTTE EAST, NORTH CAROLINA 1991 TITLE PROJECT SITE LOCATION MAP NORTH DAVIDSON II BROWNFIELDS PROPERTY2315 N. DAVIDSON STREET & 421 E. 26TH STREETCHARLOTTE, NORTH CAROLINA DATE: JOB NO: REVISION NO: FIGURE: 5-18-20 0 1PAM-003 SITE REVISION NO. 0 JOB NO. PAM-003 DATE: 8-7-23 FIGURE NO. 2 NORTH DAVIDSON II BROWNFIELDS PROPERTY2315 N. DAVIDSON ST. & 421 E. 26TH ST. CHARLOTTE, NORTH CAROLINA SITE LAYOUT MAP LEGEND SITE PROPERTY BOUNDARY FORMER RAIL SPUR LITTLE SUGAR CREEK DRAINAGE FEATURE 2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 Geology LYN X L I G H T R A I L N. DA V I D S O N S T R E E T E 26 T H S T R E E T JORDA N P L A C E N. BR E V A R D S T R E E T NODA SELF STORAGE(FORMER U.S. TEXTILE CORP.)(2401 N. DAVIDSON STREET) YANDLE METAL SHOP(2414 N. DAVIDSON STREET) YANDLE METAL SHOP(FORMER GENERAL LATEX &CHEMICAL CORP.)(2414 N. DAVIDSON STREET) COLLECTIVE APARTMENT COMPLEX(FORMER R.H. BOULIGNY, INC.)(2300 N. DAVIDSON STREET) NODA BREWING COMPANY (FORMER GIBBS ELECTROPLATING) (2229 N. DAVIDSON STREET) PERFORMANCE LOGISTICS (511 E. 25TH STREET) WOODTECH INTERIORS, INC(2228 N. BREVARD STREET) SUPERIOR STONE OF THESOUTHEAST(2310 N. BREVARD STREET) FORMER APPLIED RESEARCH GROUP (2221 N. DAVIDSON STREET) RHINO MARKET & DELI ANDFREE RANGE BREWING(2320 N. DAVIDSON STREET) NOTES: 1. AERIAL IMAGERY AND BASE DATA OBTAINED FROMMECKLENBURG COUNTY GIS, 2023. APPROXIMATE LOCATION OF BUILDING SLAB EXTENSION OFFI C E S P A C E (EXI S I T I N G B U I L D I N G ) OPEN-AIR PATIO SPACE 421 E. 26TH STREETPARCEL 2315 N. DAVIDSON STREETPARCEL UDM F O O D H A L L (EXI S T I N G B U I L D I N G ) PAVILION(NEW CONSTRUCTION) SEO U L F O O D C O M P A N Y (E X I S T I N G B U I L D I N G ) S:\ A A A - M a s t e r P r o j e c t s \ P A M A K A - P A M \ P A M - 0 0 3 N . D a v i d s o n & E . 2 6 t h \ V I M S \ F i g u r e s \ 2 0 2 3 F i g u r e 2 \ S i t e M a p _ R 1 _ 2 0 2 3 . d w g REVISION NO. 0 JOB NO. PAM-003 DATE: 1-18-24 FIGURE NO. 3 NORTH DAVIDSON II BROWNFIELDS PROPERTY (BROWNFIELDS PROJECT NO. 24003-02-060) PAVILION BUILDING CHARLOTTE, NORTH CAROLINA SAMPLE LOCATION MAP LEGEND INTERNAL STUD WALL SUB-SLAB MONITORING POINT INDOOR AIR SAMPLE LOCATION BACKGROUND AIR SAMPLE LOCATION (MAY 2023) NOTES: 1. PRE-OCCUPANCY INDOOR AIR AND BACKGROUND SAMPLES WERE COLLECTED ON 5/17/23 AND 1/18/24. 2. THE BACKGROUND SAMPLE COLLECTED ON 1/18/24 WAS COLLECTED SOUTH OF THE 2315 N. DAVIDSON STREET BUILDING (NOT SHOWN ON FIGURE). 3. ONE SUB-SLAB VAPOR SAMPLE WAS COLLECTED FROM LOCATION MP-P1 ON 5/18/23 AND ON 1/18/24. 2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 Geology MP-P1 S:\ A A A - M a s t e r P r o j e c t s \ P A M A K A - P A M \ P A M - 0 0 3 N . D a v i d s o n & E . 2 6 t h \ V I M S \ P a v i l i o n S t r u c t u r e \ S a m p l i n g \ F i g u r e s \ P a v i l i o n _ S L M _ 2 0 2 4 . d w g , F I G 2 , 2 / 2 1 / 2 0 2 4 1 1 : 2 6 : 3 7 A M , m v a w t e r Appendix A Excerpts from Previous Assessment Activities MW-10 IAS-1/SS-1 MW-1 MW-3 SB-1 SS-6 IAS-3/SS-3 IAS-4/SS-4 SS-5 MW-2 SB-2 SB-3 SB-4 BKG-1 MW-4 SB-5 IAS-2/SS-2 SS-7 SB-9 SS-8 SS-9 SS-10 SS-13 SS-12 SB-7 SB-6 SB-8 SW-2 SW-1 SS-11 SED-1 REVISION NO. 0 JOB NO. PAM-003 DATE: 9-28-20 FIGURE NO. 3 NORTH DAVIDSON II BROWNFIELDS PROPERTY2315 N. DAVIDSON STREET & 421 E. 26TH STREET CHARLOTTE, NORTH CAROLINA SAMPLE LOCATION MAP LEGEND SITE PROPERTY BOUNDARY FORMER RAIL SPUR LITTLE SUGAR CREEK DRAINAGE FEATURE EXISTING GROUNDWATERMONITORING WELL SOIL BORING SUB-SLAB VAPOR SAMPLE POINT CO-LOCATED SUB-SLAB VAPOR AND INDOOR AIR SAMPLE POINT SURFACE WATER SAMPLELOCATION SEDIMENT SAMPLE LOCATION ABANDONED MONITORING WELL 2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 Geology LYN X L I G H T R A I L N. DA V I D S O N S T R E E T E 26 T H S T R E E T JORDA N P L A C E APPROXIMATE LOCATIONOF FORMER LUMBERWAREHOUSE APPROXIMATE LOCATION OF FORMER AUTO REPAIR SHOP N. BR E V A R D S T R E E T MW-5 SB-1 MW-1 NOTES: 1) MONITORING WELLS MW-1 THROUGH MW-5 WEREINSTALLED IN APRIL 2016 BY SUMMIT ENGINEERING. 2) SOIL SAMPLES WERE COLLECTED BY H&H ON 3/5/-6/2020 AND 8/11-12/2020. 3) SUB-SLAB VAPOR SAMPLES COLLECTED BY H&H ON8/8/2019 AND 8/11/2020. 4) INDOOR AIR SAMPLES COLLECTED BY H&H ON11/12/2019. 5) SEDIMENT AND SURFACE WATER SAMPLESCOLLECTED BY H&H ON 8/11/2020. IAS-1/SS-1 MW-10 SS-7 SW-1 SED-1 S:\ A A A - M a s t e r P r o j e c t s \ P A M A K A - P A M \ P A M - 0 0 3 N . D a v i d s o n & E . 2 6 t h \ E M P \ F i g u r e s \ S i t e M a p _ R 1 . d w g , 1 2 / 2 2 / 2 0 2 0 1 : 4 2 : 3 2 P M , D W G T o P D F . p c 3 Table 3 Summary of Groundwater Analytical Results North Davidson II Brownfields Property 2351 N. Davidson Street and 421 E. 26th Street Charlotte, North Carolina H&H Job No. PAM-003 Sample ID MW-1 MW-2 MW-DUP-1 MW-3 MW-4 MW-5 Date 3/5/2020 3/5/2020 3/5/2020 3/6/2020 Area of Potential Concern Former Lumber Shed Former Junkyard Area Former Auto Repair Shop Upgradient Portion of Site VOCs (8260D) Chloroform <2.3 <2.3 <2.3 <11.7 <11.7 3.0J 70 0.81 3.6cis-1,2-Dichloroethene <0.29 <0.29 <0.29 2.2J <1.5 <0.29 70 NS NSDiisopropyl ether <0.22 <0.22 <0.22 12.8 <1.1 <0.22 70 1,400 5,900 Methyl tert-butyl ether <0.28 <0.28 <0.28 636 <1.4 <0.28 20 450 2,000 Trichloroethene <0.22 <0.22 <0.22 110 669 <0.22 3.0 1.0 4.4 SVOCs (8270E)-- -- -- RCRA Metals (6020B, 7470A) Arsenic 0.395J 0.631J <0.250 0.403J 0.901J <0.250 10 -- -- Arsenic (Dissolved)NA <0.250 <0.250 <0.250 NA NA 10 -- -- Barium 92.0 77.0 22.4 28.9 35.3 78.6 700 -- -- Barium (Dissolved)NA 22.5 22.5 29.6 NA NA 700 -- -- Cadmium <0.160 <0.160 <0.160 0.424J <0.160 <0.160 2.0 -- -- Cadmium (Dissolved)NA <0.160 <0.160 <0.160 NA NA 2.0 -- -- Chromium 1.15J 17.8 1.01J 13.5 394 2.35 10 -- -- Chromium (Dissolved)NA 0.689J 0.738J 1.01J NA NA 10 -- -- Lead 0.970J 2.02 0.482J 1.01J 0.745J 1.21J 15 -- -- Lead (Dissolved)NA <0.240 0.284J <0.240 NA NA 15 -- -- Selenium <0.380 <0.380 <0.380 0.415J 1.33J <0.380 20 -- -- Selenium (Dissolved)NA <0.380 <0.380 <0.380 NA NA 20 -- -- Silver <0.310 <0.310 <0.310 <0.310 <0.310 <0.310 20 -- -- Silver (Dissolved)NA <0.310 <0.310 <0.310 NA NA 20 -- -- Mercury <0.0490 <0.0490 <0.0490 <0.0490 <0.0490 <0.0490 1.0 0.18 0.75 Mercury (Dissolved)NA <0.0490 <0.0490 <0.0490 NA NA 1.0 0.18 0.75 Notes: 1) North Carolina Department of Environmental Quality (DEQ) 15A NCAC 02L.0202 Groundwater Standards (2L Standards) (April 2013) 2) NC DEQ Division of Waste Management (DWM) Residential Vapor Intrusion Groundwater Screening Levels (GWSLs) (July 2020) 3) NC DEQ DWM Non-Residential Vapor Intrusion GWSLs (July 2020) With the exception of metals, only constituents detected in at least one sample are shown. Concentrations are reported in micrograms per liter (µg/L). Compound concentrations are reported to the laboratory method detection limits Laboratory analytical methods are shown in parentheses. Bold concentrations exceed the DEQ 2L Standard and/or the Residential GWSL. Underlined concentrations exceed the DEQ 2L Standard and the Non-Residential GWSL. VOCs = volatile organic compounds; SVOCs = semi-volatile organic compounds, RCRA = Resource Conservation and Recovery Act NA = not analyzed; NS = not specified; -- = not applicable J = estimated value between the laboratory method detection limit and the laboratory reporting limit All Below Laboratory Method Detection Limits NC 2L Groundwater Standards (1) Residential GWSL(2) Non-Residential GWSL(3) 3/6/2020 Former Junkyard Area S:\AAA-Master Projects\PAMAKA - PAM\PAM-003 N. Davidson & E. 26th\EMP\Data Tables\GW Data Table_10-12-20 10/19/2020 Table 3 Hart & Hickman, PC Table 5 Summary of Sub-slab Vapor Analytical Results North Davidson II Brownfields Property 2351 N. Davidson Street and 421 E. 26th Street Charlotte, North Carolina H&H Job No. PAM-003 Sa m p l e I D Sa m p l e L o c a t i o n Sa m p l e D a t e An a l y t i c a l M e t h o d Ac e t o n e Be n z e n e 2-B u t a n o n e ( M E K ) Ca r b o n D i s u l f i d e Ca r b o n T e t r a c h l o r i d e Ch l o r o f o r m Ch l o r o m e t h a n e Cy c l o h e x a n e 1,2 - D i c h l o r o b e n z e n e 1,4 - D i c h l o r o b e n z e n e Dic h l o r o d i f l u o r o m e t h a n e (F r e o n 1 2 ) cis - 1 , 2 - D i c h l o r o e t h y l e n e Et h a n o l Et h y l b e n z e n e 4- E t h y l t o l u e n e He p t a n e He x a n e 2- H e x a n o n e ( M B K ) Is o p r o p a n o l Me t h y l e n e C h l o r i d e 4- M e t h y l - 2 - p e n t a n o n e ( M I B K Na p h t h a l e n e Pr o p e n e St y r e n e Te t r a c h l o r o e t h e n e Te t r a h y d r o f u r a n To l u e n e Tr i c h l o r o e t h e n e Tr i c h l o r o f l u o r o m e t h a n e (F r e o n 1 1 ) 1,2 , 4 - T r i m e t h y l b e n z e n e 1,3 , 5 - T r i m e t h y l b e n z e n e m& p - X y l e n e o- X y l e n e SS-1 8/8/2019 100J <2.6 <9.2 <4.3 <4.1 260 <2.8 <4.9 <5.8 <7.3 <4.3 <3.2 120J <5.0 <6.0 <4.8 <12 <4.8 <6.0 <8.4 <3.9 <8.0 <3.4 <5.3 860 <3.9 <3.9 91,000 <6.5 <6.3 <6.2 <10 <5.4 SS-2 8/8/2019 120 0.5J 7.2J <0.43 0.63J 1.9 <0.28 <0.49 <0.58 <0.73 2.5 <0.32 130 <0.50 <0.60 <0.48 <1.2 <0.48 5.4J <0.84 <0.39 0.86J <0.34 <0.53 19 <0.39 0.89 27 2.0J <0.63 <0.62 <1.0 <0.54 SS-3 220 0.33J 5.7J 4.3J <0.41 1.3 <0.28 <0.49 <0.58 <0.73 <0.43 <0.32 130 <0.50 <0.60 <0.48 <1.2 <0.48 16J <0.84 <0.39 <0.80 <0.34 <0.53 3.2 <0.39 0.65J <0.43 1.9J <0.63 <0.62 <1.0 <0.54 DUP-2/SS-3 230 0.42J 7.5J 5.3J <0.41 <0.36 <0.28 <0.49 <0.58 <0.73 2.3 <0.32 110 <0.50 <0.60 <0.48 <1.2 <0.48 11J <0.84 <0.39 0.86J <0.34 <0.53 3.1 <0.39 0.83 <0.43 1.9J <0.63 <0.62 <1.0 <0.54 SS-4 8/8/2019 260 1.3 9.5J 25 <0.41 <0.36 <0.28 <0.49 <0.58 <0.73 2.9 <0.32 110 2.2 2.4 <0.48 <1.2 <0.48 12J 0.85J <0.39 0.94J 17 <0.53 <0.75 <0.39 3.2 <0.43 1.0J 14 8.9 8.9 3.6 SS-5 8/8/2019 72 1.1 10J 8.6 <0.41 <0.36 <0.28 <0.49 <0.58 <0.73 2.8 <0.32 51 0.94 <0.60 2.6 6.1J <0.48 9.4J <0.84 <0.39 1.7 <0.34 <0.53 7.4 <0.39 4.2 1.2 3.2J 2.6 1.4 3.4 1.5 SS-6 8/8/2019 56 0.87 6.9J 20 <0.41 <0.36 <0.28 <0.49 <0.58 <0.73 2.7 <0.32 51 0.64J <0.60 <0.48 <1.2 <0.48 6.7J <0.84 <0.39 1.7 <0.34 <0.53 8.4 <0.39 3.4 6.1 2.7J <0.63 <0.62 2.1 0.82J SS-7 <860 18J <150 <120 <25 92 <24 <25 <33 <20 <23 <20 2,600 22J 32J <27 <96 <35 <340 <120 <32 44J <87 <18 540 <110 23J 43,000 <64 120 49J 77J 43J SS-DUP/SS-7 <860 <14 <150 <120 <25 82 32J <25 <33 <20 <23 <20 600J <14 <23 <27 <96 <35 <340 <120 <32 <44 <87 <18 540 <110 <16 43,000 <64 31J <19 27J <17 SS-8 8/11/2020 600 1.8 22J <1.6 <0.33 29 0.45J 2.5 0.53J 1.1J 2.8 <0.27 1,000 34 82 1.2 <1.3 6.5 28 1.7J 3.4J 4.7J 2.6J 0.44J 170 <1.5 4.0 5,000 6.0 190 40 180 110 SS-9 8/11/2020 140J 0.27J 8.7J 34 <0.33 <0.24 <0.32 2.5 <0.44 0.36J <0.31 <0.27 52 1.6 51 1.3 <1.3 <0.46 7.6J <1.6 0.79J 3.9 <1.2 0.39J 1.4 <1.5 5.0 <0.40 1.5J 130 88 8.5 7.4 SS-10 8/11/2020 <860 <14 <150 <120 <25 150 33J <25 <33 <20 <23 <20 1,300 <14 32J <27 <96 <35 <340 <120 <32 <44 <87 <18 560 <110 <16 26,000 <64 66J 27J 42J 25J SS-11 8/11/2020 170 1.3 44 8.3 <0.33 <0.24 <0.32 1.5 <0.44 <0.27 2.9 <0.27 150 0.97 <0.30 2.2 2.9J 11 38 <1.6 30 1.5J 6.8J 1.3 8.5 <1.5 4.4 <0.40 2.1J 1.1 0.31J 230 0.76J SS-12 8/11/2020 59 0.58J 16J 4.9J <0.33 <0.24 <0.32 6.7 <0.44 <0.27 3.0 <0.27 150 0.28J 0.31J <0.35 <1.3 3.1 13J <1.6 <0.43 0.88J <1.2 0.31J 27 7.1 1.1 1.2 2.7J 0.47J <0.26 1.1J 0.43J SS-13 8/11/2020 38 <0.19 3.6J <1.6 0.45J 0.57J <0.32 2.1 <0.44 <0.27 2.9 1.7 300 0.23J 0.31J <0.35 <1.3 <0.46 12J <1.6 0.67J 0.84J 1.5J 0.77J 4.1 <1.5 0.83 3.1 1.8J 0.37J <0.26 0.8J 0.33J 220,000 120 35,000 4,900 160 41 630 42,000 1,400 85 700 NS NS 370 NS 2,800 4,900 210 1,400 4,200 21,000 21 21,000 7,000 280 14,000 35,000 14 NS 420 420 700 700 2,700,000 1,600 440,000 61,000 2,000 530 7,900 530,000 18,000 1,100 8,800 NS NS 4,900 NS 35,000 61,000 2,600 18,000 53,000 260,000 260 260,000 88,000 3,500 180,000 440,000 180 NS 5,300 5,300 8,800 8,800 Notes: 1) North Carolina Department of Environment Quality (DEQ) Division of Waste Management (DWM) Residential Sub-slab and Exterior Soil Gas Screening Levels (SGSLs) (February 2018)2) North Carlolina DEQ DWM Non-Residential SGSLs (February 2018). Bold values exceeds the NCDEQ DWM Residential SGSL. Bold and Underlined value exceeds the NCDEQ DWM Residential and Non-Residential SGSL. Compound concentrations are reported to the laboratory detection limits. Compound concentrations are reported in micrograms per cubic meter (µg/m3).J = estimated concentration between the laboratory method detection limit and the laboratory reporting limit NS = Not Specified DWM Residential SGSL (1) DWM Non-Residential SGSL (2) 2315 N. Davidson Street TO-15 8/8/2019 421 E. 26th Street 2315 N. Davidson Street 8/11/2020 421 E. 26th Street S:\AAA‐Master Projects\PAMAKA ‐ PAM\PAM‐003 N. Davidson & E. 26th\VIMS\Combined Data Tables (9‐18‐20) RJC.xlsx 1/7/2021 Table 5 Hart & Hickman, PC Table 6 Summary of Indoor Air Analytical Data North Davidson II Brownfields Brownfields Property 2315 N. Davidson Street and 421 E. 26th Street Charlotte, North Carolina H&H Job No. PAM-003 Sa m p l e I D Sa m p l e L o c a t i o n Sa m p l e D a t e An a l y t i c a l M e t h o d Ch l o r o f o r m Te t r a c h l o r o e t h y l e n e Tr i c h l o r o e t h y l e n e IAS-1 0.10 J <0.13 0.14 J IAS-1 Duplicate (DUP-1)0.20 0.34 <0.076 IAS-2 Southern Portion of 2315 N. Davidson Street Building 11/6/2019 0.086 J <0.13 <0.076 IAS-3 Northern Portion of 2315 N. Davidson Street Building 11/6/2019 0.13 J 0.16 J <0.076 IAS-4 Eastern Portion of 2315 N. Davidson Street Building 11/6/2019 0.12 J <0.23 <0.13 BKG-1 Upwind, West of 2315 N. Davidson Street Building 11/6/2019 <0.11 <0.23 <0.13 0.12 8.3 0.42 0.53 35 1.8 Notes: 1) North Carolina Department of Environment Quality (DEQ) Division of Waste Management (DWM) Residential and Non-Residential Indoor Air Screening Levels (IASLs) dated July 2020. Based on a Total Cumulative Risk of 1x10- and a Target Hazard Quotient of 0.2. Compound concentrations are reported in micrograms per cubic meter (µg/m ). Compound concentrations are reported to the laboratory detection limits. J = Compound was detected above the laboratory method detection limit, but below the laboratory reporting limit resulting in a laboratory estimated concentration. IAS = indoor air sample; BKG = background DWM Non-Residential IASL (1) TO-15 DWM Residential IASL (1) Western Portion of 2315 N. Davidson Street Building 11/6/2019 S:\AAA‐Master Projects\PAMAKA ‐ PAM\PAM‐003 N. Davidson & E. 26th\EMP\Data Tables\Indoor Air Data Table (11‐29‐19) 10/12/2020 Table 6 Hart & Hickman, PC Appendix B Photographic Log Photograph Nos. 1 & 2: General view of the exterior of the Pavilion PA M - 0 0 3 2923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) PAVILION STRUCTURE NORTH DAVIDSON II BROWNFIELDS SITE CHARLOTTE, NORTH CAROLINA Photograph No. 4: Monitoring point MP-P1 located in the central portion of the Pavilion PA M - 0 0 3 2923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) PAVILION STRUCTURE NORTH DAVIDSON II BROWNFIELDS SITE CHARLOTTE, NORTH CAROLINA Photograph No. 3: General view of the interior of the Pavilion Appendix C Field Forms &Žƌŵ^sͲϭ 6XE6ODE6RLO*DV9DSRU,QVWDOODWLRQ)LHOG)RUP 3URMHFW1RBBBBBBBBBBBBBBBBB 6DPSOHUBBBBBBBBBBBBBBBBBBBBB :HDWKHUBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBB Surface Material Slab Thickness (if appl.) Material Below Slab (if appl.) Depth of Screen (if appl.) Type Date & Time Ambient Temp.Purge Method Volume Purged Shroud Helium Conc. Purge Helium Conc. Leak Test Pass? (see note) SS, SG Perm., Temp.Concrete, soil, gravel, asphalt Inches Gravel, sand, clay, etc.ft bgs Full sample train or point-only mm/dd/yy 24-hr oF Syringe, pump Liters (see notes for calc.)%% or ppm(indicate units below) Yes / No ^͗ ͗ Z͗ ^͗ ͗ Z͗ ^͗ ͗ Z͗ ^͗ ͗ Z͗ ^͗ ͗ Z͗ ^͗ ͗ Z͗ S = sample ID; C = canister ID; R = regulator ID; SS = sub-slab; SG = soil gas; Perm = permanent; Temp = temporary; Volume Purged = x3 purge volumes = 3*L*a Last updated: 4/21/2022 " Hg = inches of mercury; ppm = parts per million 1RWHV___________________________________________________ ___________________________________________________ ___________________________________________________ ___________________________________________________ 6DPSOH,'Type 9DSRU0RQLWRULQJ3RLQW&RQVWUXFWLRQ +HOLXP/HDN7HVW EŽƚĞ͗>ĞĂŬdĞƐƚZĞƋƵŝƌĞŵĞŶƚƐ WĞƌEYtDsĂƉŽƌ/ŶƚƌƵƐŝŽŶ'ƵŝĚĂŶĐĞ͕ůĞĂŬƚĞƐƚƉĂƐƐĞƐŝĨŚĞůŝƵŵ ĐŽŶĐĞŶƚƌĂƚŝŽŶŝŶƉƵƌŐĞĂŝƌŝƐůĞƐƐƚŚĂŶϭϬйŽĨŚĞůŝƵŵĐŽŶĐĞŶƚƌĂƚŝŽŶŝŶ ƐŚƌŽƵĚ͘ L = length of tubing/pipe (ft)a = 0.163 for 2" diameter (L/ft)a = 0.010 for 0.25" diameter (L/ft) ͗ͰhƐĞƌƐͰŵǀĂǁƚĞƌͰƌŽƉďŽdžͰLJKƚŚĞƌͰ&ŽƌŵĚŝƚƐͰ/YͲ^^sͰsĂƉŽƌ^ĂŵƉůŝŶŐ&ŽƌŵƐͺsϲ͘Ϭ ^ƵďͲ^ůĂďͬ^Žŝů'ĂƐ^ĂŵƉůŝŶŐsĂƉŽƌ/ŶƐƚĂůůĂƚŝŽŶ&ŝĞůĚ&Žƌŵ ,ĂƌƚΘ,ŝĐŬŵĂŶ͕W PAM-003 AML 70s, partly cloudy P-1 11377 SS Temp Concrete 6 Gravel --Full 5/18/23 1240 71 Pump 1 L 10.6 0 ppm Yes 16213 MP-9 11374 SS Perm Concrete 6 Gravel --Full 5/19/23 1115 62 Pump 1 L 10.6 1025 ppm Yes13142 MP-3 11356 SS Perm Concrete 6 Gravel --Full 5/19/23 1225 64 Pump 1 L 10.6 2075 ppm Yes 16204 &Žƌŵ^sͲϮ 6XE6ODE6RLO*DV9DSRU6DPSOLQJ)LHOG)RUP 3URMHFW1RBBBBBBBBBBBBBBBBBBB 6DPSOHUBBBBBBBBBBBBBBBBBBBBBB :HDWKHUBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBB Date Proposed Sampling Duration Time Canister Pressure Outdoor Temperature Outdoor Humidity Indoor Temperature Indoor Humidity mm/dd/yy Minutes 24-hr " Hg oF %oF % ^͗Beginning ͗Middle Z͗End ^͗Beginning ͗Middle Z͗End ^͗Beginning ͗Middle Z͗End ^͗Beginning ͗Middle Z͗End ^͗Beginning ͗Middle Z͗End ^͗Beginning ͗Middle Z͗End S = sample ID; C = canister ID; R = regulator ID; SS = sub-slab; SG = soil gas; Perm = permanent; Temp = temporary Last updated: 6/18/2020 " Hg = inches of mercury 1RWHV________________________________________________ _______________________________________________ _______________________________________________ _______________________________________________ _______________________________________________ ^ŝnjĞ͗ &ůŽǁZĂƚĞ͗ ^ŝnjĞ͗ &ůŽǁZĂƚĞ͗ 6DPSOH,' ^ŝnjĞ͗ &ůŽǁZĂƚĞ͗ ^ŝnjĞ͗ &ůŽǁZĂƚĞ͗ ^ŝnjĞ͗ &ůŽǁZĂƚĞ͗ ^ŝnjĞ͗ &ůŽǁZĂƚĞ͗ 6DPSOLQJ,QIRUPDWLRQ ,QGRRU3DUDPHWHUV2XWGRRU3DUDPHWHUV Sampling Period EŽƚĞ͗ WĞƌEYtDsĂƉŽƌ/ŶƚƌƵƐŝŽŶ'ƵŝĚĂŶĐĞ͕ ƐŚƵƚͲŝŶƚĞƐƚĂŶĚŚĞůŝƵŵůĞĂŬĐŚĞĐŬŵƵƐƚďĞ ƉĂƐƐĞĚďĞĨŽƌĞƐĂŵƉůŝŶŐ͘ ͗ͰhƐĞƌƐͰŵǀĂǁƚĞƌͰƌŽƉďŽdžͰLJKƚŚĞƌͰ&ŽƌŵĚŝƚƐͰ/YͲ^^sͰsĂƉŽƌ^ĂŵƉůŝŶŐ&ŽƌŵƐͺsϲ͘Ϭ ^ƵďͲ^ůĂďͬ^Žŝů'ĂƐ^ĂŵƉůŝŶŐsĂƉŽƌ^ĂŵƉůŝŶŐ&ŝĞůĚ&Žƌŵ ,ĂƌƚΘ,ŝĐŬŵĂŶ͕W PAM-003 AML 70s, partly cloudy P-1 1 L11377 5/18/23 10 100 mL/min 1254 -17 71 45 45 16213 1301 -5 1249 -27 71 MP-9 1 L 1115 -28.5 11374 5/19/23 10 1120 -19 62 65 71 41 100 mL/min13142 1128 -5 MP-3 1230 -28.51 L11356 5/19/23 10 64 64 71 46 16204 100 mL/min 1235 -18.5 1243 -4 &Žƌŵ/^Ͳϭ ,QGRRU$LU6DPSOLQJ)LHOG)RUP 3URMHFW1RBBBBBBBBBBBBBBBBBBB 6DPSOHUBBBBBBBBBBBBBBBBBBBBBB :HDWKHUBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBB Date Proposed Sampling Duration Time Canister Pressure Differential Pressure Outdoor Temperature Outdoor Humidity Indoor Temperature Indoor Humidity mm/dd/yy Hours 24-hr " Hg " H2O oF %oF % ^͗Beginning ͗Middle Z͗End ^͗Beginning ͗Middle Z͗End ^͗Beginning ͗Middle Z͗End ^͗Beginning ͗Middle Z͗End ^͗Beginning ͗Middle Z͗End ^͗Beginning ͗Middle Z͗End S = sample ID; C = canister ID; R = regulator ID Note: negative differential pressure indicates that indoor pressure was lower than pressure outdoors.Last updated: 6/18/2020" Hg = inches of mercury; " H2O = inches of water column Time (EST)1RWHV____________________________________________ Precipitation (inches) ____________________________________________ Barometric Pressure (" Hg) ____________________________________________ Wind Direction ____________________________________________ Wind Speed (mph) ____________________________________________ ^ŝnjĞ͗ &ůŽǁZĂƚĞ͗ ^ŝnjĞ͗ &ůŽǁZĂƚĞ͗ ^ŝnjĞ͗ &ůŽǁZĂƚĞ͗ ^ŝnjĞ͗ &ůŽǁZĂƚĞ͗ ,QGRRU3DUDPHWHUV Sampling Period 6DPSOLQJ,QIRUPDWLRQ 2XWGRRU3DUDPHWHUV 6DPSOH,' ^ŝnjĞ͗ &ůŽǁZĂƚĞ͗ ^ŝnjĞ͗ &ůŽǁZĂƚĞ͗ ͗ͰhƐĞƌƐͰŵǀĂǁƚĞƌͰƌŽƉďŽdžͰLJKƚŚĞƌͰ&ŽƌŵĚŝƚƐͰ/YͲ^^sͰsĂƉŽƌ^ĂŵƉůŝŶŐ&ŽƌŵƐͺsϲ͘Ϭ /ŶĚŽŽƌŝƌ^ĂŵƉůŝŶŐ&ŝĞůĚ&Žƌŵ ,ĂƌƚΘ,ŝĐŬŵĂŶ͕W PAM-003 AML 70s, partly cloudy IAS-1 0924 -28 0.000 72 31 73 676 L28744 5/17/23 8 1350 -16.5 0.000 79 40 70 63 14326 12.5 1724 -7 0.000 82 53 73 47 IAS-DUP 0924 -28 0.000 72 31 73 676 L42652 5/17/23 8 1350 -16.5 0.000 79 40 70 63 14326 12.5 1724 -7 0.000 82 53 73 47 IAS-2 0923 -30 0.000 72 31 73 676 L36110 5/17/23 8 1350 -17.5 0.000 79 40 70 63 14307 12.5 1724 -6 0.000 82 53 73 47 IAS-3 0922 -29 0.000 72 31 73 676 L37255 5/17/23 8 1351 -16.5 0.000 79 40 70 63 14298 12.5 1726 -6 0.000 82 53 73 47 P-1 0925 -30 0.000 72 31 72 726 L42644 5/17/23 8 1353 -17 0.000 79 40 70 6312.514296 1730 -8 0.000 82 53 79 64 BKG-051723 0921 -29 0.000 72 31 -- --6 L46853 5/17/23 8 1354 -18 0.000 79 40 -- -- 17726 12.5 1726 -7.5 0.000 82 53 -- -- 0930 1400 1730 0 0 0 29.76 29.84 29.80 NNE NNE NNE 6 8 11 INDOOR AIR BUILDING SURVEY and SAMPLING FORM Site Name: ____________________________________ Preparer’s name: ________________________________ Preparer’s affiliation: ____________________________ #: ______________________ Date: __________________________ Phone #: _______________________ Part I - Occupants Building Address: ____________________________________________________________________ Property Contact: _______________________________ Owner / Renter / other: ______________ Contact’s Phone: home ( )__________ work ( )______________ cell ( )____________ # of Building occupants: Children under age 13 _____ Children age 13-18 ______ Adults _____ Part II – Building Characteristics Building type: Describe building: ________________________________________ Year constructed: _________ Sensitive population:(specify): _______________ Number of floors below grade: ______ Number of floors at or above grade: ______ Depth of basement below grade surface: ______ ft. Basement size: _______ ft2 Basement floor construction: Foundation walls: Basement sump present?Sump pump? ther (specify): ________________ other (specify)_______________ Water in sump? Type of heating system (c all that apply): hot air circulation hot air radiation wood steam radiation heat pump hot water radiation kerosene heater electric baseboard other (specify): ________________________ Type of ventilation system (c all that apply): bathroom ventilation fans outside air intake central air conditioning mechanical fans individual air conditioning units kitchen range hood fan other (specify): _________________ Type of fuel utilized (c all that apply): Natural gas electric fuel oil wood coal solar kerosene Are the basement walls or floor sealed with waterproof paint or epoxy coatings? Mill District Partners LLC other (specify) _____________ Is there a whole house fan? Septic system? Irrigation/private well? Type of ground cover outside of building: Existing subsurface depressurization (radon) system in place? Sub-slab vapor/moisture barrier in place? Type of barrier: ____________________________ Part III - Outside Contaminant Sources Other stationary sources nearby (gas stations, emission stacks, etc.): _____________________________ Heavy vehicular traffic nearby (or other mobile sources): ______________________________________ Part IV – Indoor Contaminant Sources Identify all potential indoor sources found in the building (including attached garages), the location of the source (floor and room), and whether the item was removed from the building 48 hours prior to indoor air sampling event. Any ventilation implemented after removal of the items should be completed at least 24 hours prior to the commencement of the indoor air sampling event. Potential Sources Location(s)Removed (Yes / No / NA) Gasoline storage cans Gas-powered equipment Kerosene storage cans Paints / thinners / strippers Cleaning solvents Oven cleaners Carpet / upholstery cleaners Other house cleaning products Moth balls Polishes / waxes Insecticides Furniture / floor polish Nail polish / polish remover Hairspray Cologne / perfume Air fresheners Fuel tank (inside building) Wood stove or fireplace New furniture / upholstery New carpeting / flooring Hobbies - glues, paints, etc. Part V – Miscellaneous Items Do any occupants of the building smoke?How often? ______________ Last time someone smoked in the building? ____________ hours days ago Does the building have an attached garage directly connected to living space? If so, is a car usually parked in the garage? Are gas-powered equipment or cans of gasoline/fuels stored in the garage? Do the occupants of the building have their clothes dry cleaned? If yes, how often? Do any of the occupants use solvents in work? If yes, what types of solvents are used? _______________________________________ If yes, are their clothes washed at work? If so, when and which chemicals? _________________________________________________ Has there ever been a fire in the building?If yes, when? _____________ Has painting or staining been done in the building in the last 6 months?Yes No If yes, when __________________ and where? ____________________________ Part VI – Sampling Information Sample Technician: ____________________________ Phone number:) _______ - __________ Sample Source Sampler Type Other (specify): _________________ Analytical Method:ther: _____________ Cert. Laboratory: Sample locations (floor, room): Field ID # _____ - ________________________ Field ID # _____-__________________________ Field ID # Were “Instructions for Occupants” followed? Provide Drawing of Sample Location(s) in Building Part VII - Meteorological Conditions Was there significant precipitation within 12 hours prior to (or during) the sampling event?Yes No Describe the general weather conditions: _________________________________________________ _____________________________________________________________________________________ Part VIII – General Observations Provide any information that may be pertinent to the sampling event and may assist in the data interpretation process (e.g., observed that drycleaner operated with door or windows propped open for ventilation). (Adapted from the NJDEP Vapor Intrusion Guidance, October 2005) Appendix D Laboratory Analytical Reports   Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.   5/30/2023 Hart & Hickman (Charlotte) Dave Kahn 2923 South Tryon St. Ste 100 Charlotte, NC, 28203 Ref: Analytical Testing Lab Report Number: 23-139-0102 Client Project Description: PAM-003 Dear Dave Kahn: Waypoint Analytical, LLC (Charlotte) received sample(s) on 5/19/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Angela D Overcash Senior Project Manager Page 1 of 50 Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date 07/31/202337735State ProgramNorth Carolina 12/31/2023402State ProgramNorth Carolina 07/31/202399012State ProgramSouth Carolina 12/31/202299012State ProgramSouth Carolina Page 1 of 1 00016/23-139-0102 Page 2 of 50 Report Number: Sample Summary Table Client Project Description: 23-139-0102 PAM-003 Lab No Client Sample ID Matrix Date Collected Date Received 05/17/2023Air 96673 IAS-DUP 05/19/2023 14:15 05/17/2023 09:24Air 96674 IAS-1 05/19/2023 14:15 05/17/2023 09:23Air 96675 IAS-2 05/19/2023 14:15 05/17/2023 09:22Air 96676 IAS-3 05/19/2023 14:15 05/17/2023 09:21Air 96677 BKG-051726 05/19/2023 14:15 05/17/2023 09:25Air 96678 P-1 05/19/2023 14:15 05/18/2023 12:49Air 96679 P-1 05/19/2023 14:15 05/19/2023 11:15Air 96680 MP-9 05/19/2023 14:15 05/19/2023 12:30Air 96681 MP-3 05/19/2023 14:15 Page 3 of 50 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-139-0102 Report Limit Project:PAM-003 V 96673IAS-DUP 14.9 05/24/2023 19:43TO-15 Acetone µg/m3 0.202 J0.370 05/24/2023 19:43TO-15 Benzene µg/m3 0.073 2.62 05/24/2023 19:43TO-15 Chloroform µg/m3 0.086 J0.768 05/24/2023 19:43TO-15 Chloromethane µg/m3 0.067 2.49 05/24/2023 19:43TO-15 Dichlorodifluoromethane µg/m3 0.134 2.32 05/24/2023 19:43TO-15 Ethyl Acetate µg/m3 0.136 J0.688 05/24/2023 19:43TO-15 Heptane µg/m3 0.143 J0.613 05/24/2023 19:43TO-15 n-Hexane µg/m3 0.047 J1.37 05/24/2023 19:43TO-15 Isopropyl Alcohol µg/m3 0.139 1.86 05/24/2023 19:43TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 2.34 05/24/2023 19:43TO-15 Styrene µg/m3 0.124 J0.678 05/24/2023 19:43TO-15 Tetrachloroethene µg/m3 0.181 J0.468 05/24/2023 19:43TO-15 Tetrahydrofuran µg/m3 0.107 J1.33 05/24/2023 19:43TO-15 Toluene µg/m3 0.090 J1.78 05/24/2023 19:43TO-15 Trichlorofluoromethane µg/m3 0.130 J1.92 05/24/2023 19:43TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J0.653 05/24/2023 19:43TO-15 1,3,5-Trimethylbenzene µg/m3 0.236 V 96674IAS-1 14.4 05/24/2023 20:33TO-15 Acetone µg/m3 0.202 J0.383 05/24/2023 20:33TO-15 Benzene µg/m3 0.073 JB1.31 05/24/2023 20:33TO-15 Carbon Disulfide µg/m3 0.060 3.17 05/24/2023 20:33TO-15 Chloroform µg/m3 0.086 J0.753 05/24/2023 20:33TO-15 Chloromethane µg/m3 0.067 2.53 05/24/2023 20:33TO-15 Dichlorodifluoromethane µg/m3 0.134 2.37 05/24/2023 20:33TO-15 Ethyl Acetate µg/m3 0.136 J0.631 05/24/2023 20:33TO-15 Heptane µg/m3 0.143 J0.641 05/24/2023 20:33TO-15 n-Hexane µg/m3 0.047 J1.60 05/24/2023 20:33TO-15 Isopropyl Alcohol µg/m3 0.139 1.80 05/24/2023 20:33TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 2.39 05/24/2023 20:33TO-15 Styrene µg/m3 0.124 J0.386 05/24/2023 20:33TO-15 Tetrahydrofuran µg/m3 0.107 J1.39 05/24/2023 20:33TO-15 Toluene µg/m3 0.090 J1.70 05/24/2023 20:33TO-15 Trichlorofluoromethane µg/m3 0.130 J1.94 05/24/2023 20:33TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J0.722 05/24/2023 20:33TO-15 1,3,5-Trimethylbenzene µg/m3 0.236 Page 4 of 50 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-139-0102 Report Limit Project:PAM-003 V 96675IAS-2 17.9 05/24/2023 21:23TO-15 Acetone µg/m3 0.202 J0.408 05/24/2023 21:23TO-15 Benzene µg/m3 0.073 7.56 05/24/2023 21:23TO-15 Chloroform µg/m3 0.086 J0.755 05/24/2023 21:23TO-15 Chloromethane µg/m3 0.067 J2.35 05/24/2023 21:23TO-15 Dichlorodifluoromethane µg/m3 0.134 2.57 05/24/2023 21:23TO-15 Ethyl Acetate µg/m3 0.136 J0.639 05/24/2023 21:23TO-15 Heptane µg/m3 0.143 J0.613 05/24/2023 21:23TO-15 n-Hexane µg/m3 0.047 J0.978 05/24/2023 21:23TO-15 Isopropyl Alcohol µg/m3 0.139 2.06 05/24/2023 21:23TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J1.35 05/24/2023 21:23TO-15 Styrene µg/m3 0.124 J0.353 05/24/2023 21:23TO-15 Tetrahydrofuran µg/m3 0.107 2.40 05/24/2023 21:23TO-15 Toluene µg/m3 0.090 J1.46 05/24/2023 21:23TO-15 Trichlorofluoromethane µg/m3 0.130 J0.560 05/24/2023 21:23TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 V 96676IAS-3 16.7 05/24/2023 22:13TO-15 Acetone µg/m3 0.202 J0.389 05/24/2023 22:13TO-15 Benzene µg/m3 0.073 J1.34 05/24/2023 22:13TO-15 Chloroform µg/m3 0.086 J0.689 05/24/2023 22:13TO-15 Chloromethane µg/m3 0.067 J2.31 05/24/2023 22:13TO-15 Dichlorodifluoromethane µg/m3 0.134 J0.724 05/24/2023 22:13TO-15 Ethyl Acetate µg/m3 0.136 J0.408 05/24/2023 22:13TO-15 4-Ethyltoluene µg/m3 0.128 J0.418 05/24/2023 22:13TO-15 Heptane µg/m3 0.143 J0.563 05/24/2023 22:13TO-15 n-Hexane µg/m3 0.047 J0.235 05/24/2023 22:13TO-15 Isopropyl Alcohol µg/m3 0.139 J1.42 05/24/2023 22:13TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J1.38 05/24/2023 22:13TO-15 Styrene µg/m3 0.124 J1.23 05/24/2023 22:13TO-15 Toluene µg/m3 0.090 J1.39 05/24/2023 22:13TO-15 Trichlorofluoromethane µg/m3 0.130 J2.35 05/24/2023 22:13TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J0.806 05/24/2023 22:13TO-15 1,3,5-Trimethylbenzene µg/m3 0.236 V 96677BKG-051726 20.1 05/24/2023 23:06TO-15 Acetone µg/m3 0.202 J0.421 05/24/2023 23:06TO-15 Benzene µg/m3 0.073 J0.747 05/24/2023 23:06TO-15 Chloromethane µg/m3 0.067 Page 5 of 50 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-139-0102 Report Limit Project:PAM-003 V 96677BKG-051726 J2.37 05/24/2023 23:06TO-15 Dichlorodifluoromethane µg/m3 0.134 J0.549 05/24/2023 23:06TO-15 Heptane µg/m3 0.143 J0.807 05/24/2023 23:06TO-15 n-Hexane µg/m3 0.047 J1.05 05/24/2023 23:06TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 3.89 05/24/2023 23:06TO-15 Naphthalene µg/m3 0.183 J1.67 05/24/2023 23:06TO-15 Toluene µg/m3 0.090 J1.53 05/24/2023 23:06TO-15 Trichlorofluoromethane µg/m3 0.130 V 96678P-1 138 05/26/2023 18:46TO-15 Acetone µg/m3 1.01 J0.527 05/26/2023 00:03TO-15 Benzene µg/m3 0.073 J0.258 05/26/2023 00:03TO-15 Carbon Disulfide µg/m3 0.060 J0.706 05/26/2023 00:03TO-15 Chloromethane µg/m3 0.067 J2.32 05/26/2023 00:03TO-15 Dichlorodifluoromethane µg/m3 0.134 J0.831 05/26/2023 00:03TO-15 Heptane µg/m3 0.143 J0.641 05/26/2023 00:03TO-15 n-Hexane µg/m3 0.047 J1.50 05/26/2023 00:03TO-15 2-Hexanone µg/m3 0.285 15.2 05/26/2023 00:03TO-15 Isopropyl Alcohol µg/m3 0.139 9.54 05/26/2023 00:03TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J0.421 05/26/2023 00:03TO-15 4-Methyl-2-Pentanone µg/m3 0.121 J0.786 05/26/2023 00:03TO-15 Propene µg/m3 0.242 J0.711 05/26/2023 00:03TO-15 Styrene µg/m3 0.124 J0.746 05/26/2023 00:03TO-15 Tetrachloroethene µg/m3 0.181 1.72 05/26/2023 00:03TO-15 Tetrahydrofuran µg/m3 0.107 6.90 05/26/2023 00:03TO-15 Toluene µg/m3 0.090 J1.37 05/26/2023 00:03TO-15 Trichlorofluoromethane µg/m3 0.130 J0.491 05/26/2023 00:03TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J0.494 05/26/2023 00:03TO-15 o-Xylene µg/m3 0.157 J0.494 05/26/2023 00:03TO-15 Xylene (Total)µg/m3 0.157 V 96679P-1 6.71 05/25/2023 17:42TO-15 Acetone µg/m3 0.202 J0.338 05/25/2023 17:42TO-15 Benzene µg/m3 0.073 J1.75 05/25/2023 17:42TO-15 Carbon Disulfide µg/m3 0.060 3.51 05/25/2023 17:42TO-15 Chloroform µg/m3 0.086 12.5 05/25/2023 17:42TO-15 Dichlorodifluoromethane µg/m3 0.134 J0.327 05/25/2023 17:42TO-15 n-Hexane µg/m3 0.047 J1.21 05/25/2023 17:42TO-15 Isopropyl Alcohol µg/m3 0.139 Page 6 of 50 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-139-0102 Report Limit Project:PAM-003 V 96679P-1 J0.751 05/25/2023 17:42TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 2.07 05/25/2023 17:42TO-15 Methylene Chloride µg/m3 0.488 J1.46 05/25/2023 17:42TO-15 Naphthalene µg/m3 0.183 63.8 05/25/2023 17:42TO-15 Tetrachloroethene µg/m3 0.181 J0.327 05/25/2023 17:42TO-15 Tetrahydrofuran µg/m3 0.107 J1.13 05/25/2023 17:42TO-15 Toluene µg/m3 0.090 J2.54 05/25/2023 17:42TO-15 1,1,1-Trichloroethane µg/m3 0.144 3.57 05/25/2023 17:42TO-15 Trichlorofluoromethane µg/m3 0.130 J1.06 05/25/2023 17:42TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 V 96680MP-9 9.99 05/25/2023 18:37TO-15 Acetone µg/m3 0.202 J0.396 05/25/2023 18:37TO-15 Benzene µg/m3 0.073 J1.08 05/25/2023 18:37TO-15 Carbon Disulfide µg/m3 0.060 J0.527 05/25/2023 18:37TO-15 Chloroform µg/m3 0.086 J2.42 05/25/2023 18:37TO-15 Dichlorodifluoromethane µg/m3 0.134 J0.542 05/25/2023 18:37TO-15 Ethylbenzene µg/m3 0.106 19.9 05/25/2023 18:37TO-15 4-Ethyltoluene µg/m3 0.128 J0.401 05/25/2023 18:37TO-15 n-Hexane µg/m3 0.047 J0.228 05/25/2023 18:37TO-15 Isopropyl Alcohol µg/m3 0.139 J1.35 05/25/2023 18:37TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J2.01 05/25/2023 18:37TO-15 4-Methyl-2-Pentanone µg/m3 0.121 2.66 05/25/2023 18:37TO-15 Methylene Chloride µg/m3 0.488 J0.477 05/25/2023 18:37TO-15 Naphthalene µg/m3 0.183 J0.613 05/25/2023 18:37TO-15 Styrene µg/m3 0.124 11.7 05/25/2023 18:37TO-15 Tetrachloroethene µg/m3 0.181 1.57 05/25/2023 18:37TO-15 Tetrahydrofuran µg/m3 0.107 J1.42 05/25/2023 18:37TO-15 Toluene µg/m3 0.090 J1.34 05/25/2023 18:37TO-15 1,1,1-Trichloroethane µg/m3 0.144 131 05/25/2023 18:37TO-15 Trichloroethene µg/m3 0.199 J1.78 05/25/2023 18:37TO-15 Trichlorofluoromethane µg/m3 0.130 168 05/25/2023 18:37TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 88.1 05/25/2023 18:37TO-15 1,3,5-Trimethylbenzene µg/m3 0.236 2.87 05/25/2023 18:37TO-15 o-Xylene µg/m3 0.157 J0.460 05/25/2023 18:37TO-15 m,p-Xylene µg/m3 0.217 J3.33 05/25/2023 18:37TO-15 Xylene (Total)µg/m3 0.157 Page 7 of 50 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-139-0102 Report Limit Project:PAM-003 V 96681MP-3 8.30 05/25/2023 19:29TO-15 Acetone µg/m3 0.202 J0.472 05/25/2023 19:29TO-15 Benzene µg/m3 0.073 J0.491 05/25/2023 19:29TO-15 Carbon Disulfide µg/m3 0.060 5.22 05/25/2023 19:29TO-15 Chloroform µg/m3 0.086 J0.685 05/25/2023 19:29TO-15 Chloromethane µg/m3 0.067 J2.27 05/25/2023 19:29TO-15 Dichlorodifluoromethane µg/m3 0.134 J0.586 05/25/2023 19:29TO-15 Ethylbenzene µg/m3 0.106 J0.673 05/25/2023 19:29TO-15 4-Ethyltoluene µg/m3 0.128 J0.315 05/25/2023 19:29TO-15 Heptane µg/m3 0.143 J0.613 05/25/2023 19:29TO-15 n-Hexane µg/m3 0.047 J2.49 05/25/2023 19:29TO-15 Isopropyl Alcohol µg/m3 0.139 J1.11 05/25/2023 19:29TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 2.10 05/25/2023 19:29TO-15 Methylene Chloride µg/m3 0.488 5.18 05/25/2023 19:29TO-15 Styrene µg/m3 0.124 1.86 05/25/2023 19:29TO-15 Tetrahydrofuran µg/m3 0.107 2.13 05/25/2023 19:29TO-15 Toluene µg/m3 0.090 J0.548 05/25/2023 19:29TO-15 Trichloroethene µg/m3 0.199 J1.42 05/25/2023 19:29TO-15 Trichlorofluoromethane µg/m3 0.130 13.3 05/25/2023 19:29TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 4.51 05/25/2023 19:29TO-15 1,3,5-Trimethylbenzene µg/m3 0.236 J0.792 05/25/2023 19:29TO-15 Vinyl Acetate µg/m3 0.224 J0.907 05/25/2023 19:29TO-15 o-Xylene µg/m3 0.157 J0.907 05/25/2023 19:29TO-15 Xylene (Total)µg/m3 0.157 Page 8 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:IAS-DUP 96673 Matrix: 5/17/2023 0:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/24/23 09:00 14.9 µg/m3 0.202 4.75Acetone 1 05/24/23 19:43 V33674ENM 0.370 J µg/m3 0.073 1.60Benzene 1 05/24/23 19:43 V33674ENM <0.147 µg/m3 0.147 10.4Benzyl Chloride 1 05/24/23 19:43 V33674ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 05/24/23 19:43 V33674ENM <0.153 µg/m3 0.153 5.17Bromoform 1 05/24/23 19:43 V33674ENM <0.115 µg/m3 0.115 1.94Bromomethane 1 05/24/23 19:43 V33674ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 05/24/23 19:43 V33674ENM <0.060 µg/m3 0.060 6.23Carbon Disulfide 1 05/24/23 19:43 V33674ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 05/24/23 19:43 V33674ENM <0.107 µg/m3 0.107 2.30Chlorobenzene 1 05/24/23 19:43 V33674ENM <0.208 µg/m3 0.208 4.26Chlorodibromomethane 1 05/24/23 19:43 V33674ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 05/24/23 19:43 V33674ENM 2.62 µg/m3 0.086 2.44Chloroform 1 05/24/23 19:43 V33674ENM 0.768 J µg/m3 0.067 1.03Chloromethane 1 05/24/23 19:43 V33674ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 05/24/23 19:43 V33674ENM <0.151 µg/m3 0.151 3.841,2-Dibromoethane 1 05/24/23 19:43 V33674ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 05/24/23 19:43 V33674ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 05/24/23 19:43 V33674ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 05/24/23 19:43 V33674ENM 2.49 µg/m3 0.134 2.47Dichlorodifluoromethane 1 05/24/23 19:43 V33674ENM <0.101 µg/m3 0.101 2.021,1-Dichloroethane 1 05/24/23 19:43 V33674ENM <0.129 µg/m3 0.129 2.021,2-Dichloroethane 1 05/24/23 19:43 V33674ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 9 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:IAS-DUP 96673 Matrix: 5/17/2023 0:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/24/23 09:00 <0.107 µg/m3 0.107 1.981,1-Dichloroethene 1 05/24/23 19:43 V33674ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 05/24/23 19:43 V33674ENM <0.108 µg/m3 0.108 1.98trans-1,2-Dichloroethene 1 05/24/23 19:43 V33674ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 05/24/23 19:43 V33674ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 05/24/23 19:43 V33674ENM <0.178 µg/m3 0.178 2.27cis-1,3-Dichloropropene 1 05/24/23 19:43 V33674ENM <0.178 µg/m3 0.178 2.27trans-1,3-Dichloropropene 1 05/24/23 19:43 V33674ENM <0.435 µg/m3 0.435 1.801,4-Dioxane 1 05/24/23 19:43 V33674ENM 2.32 µg/m3 0.136 1.80Ethyl Acetate 1 05/24/23 19:43 V33674ENM <0.106 µg/m3 0.106 2.17Ethylbenzene 1 05/24/23 19:43 V33674ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 05/24/23 19:43 V33674ENM <0.561 µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 05/24/23 19:43 V33674ENM 0.688 J µg/m3 0.143 2.05Heptane 1 05/24/23 19:43 V33674ENM <0.330 µg/m3 0.330 5.33Hexachlorobutadiene 1 05/24/23 19:43 V33674ENM 0.613 J µg/m3 0.047 1.76n-Hexane 1 05/24/23 19:43 V33674ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 05/24/23 19:43 V33674ENM 1.37 J µg/m3 0.139 4.92Isopropyl Alcohol 1 05/24/23 19:43 V33674ENM 1.86 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 05/24/23 19:43 V33674ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 05/24/23 19:43 V33674ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 05/24/23 19:43 V33674ENM <0.488 µg/m3 0.488 1.74Methylene Chloride 1 05/24/23 19:43 V33674ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 05/24/23 19:43 V33674ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 10 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:IAS-DUP 96673 Matrix: 5/17/2023 0:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/24/23 09:00 <0.242 µg/m3 0.242 0.860Propene 1 05/24/23 19:43 V33674ENM 2.34 µg/m3 0.124 2.13Styrene 1 05/24/23 19:43 V33674ENM <0.104 µg/m3 0.104 3.431,1,2,2-Tetrachloroethane 1 05/24/23 19:43 V33674ENM 0.678 J µg/m3 0.181 3.39 1 05/24/23 19:43 V33674ENM 0.468 J µg/m3 0.107 1.47 1 05/24/23 19:43 V33674ENM 1.33 J µg/m3 0.090 1.88 1 05/24/23 19:43 V33674ENM <0.209 µg/m3 0.209 3.711,2,4-Trichlorobenzene 1 05/24/23 19:43 V33674ENM <0.144 µg/m3 0.144 2.731,1,1-Trichloroethane 1 05/24/23 19:43 V33674ENM <0.087 µg/m3 0.087 2.731,1,2-Trichloroethane 1 05/24/23 19:43 V33674ENM <0.199 µg/m3 0.199 2.15 1 05/24/23 19:43 V33674ENM 1.78 J µg/m3 0.130 2.81 1 05/24/23 19:43 V33674ENM 1.92 J µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 05/24/23 19:43 V33674ENM 0.653 J µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 05/24/23 19:43 V33674ENM <0.224 µg/m3 0.224 1.76Vinyl Acetate 1 05/24/23 19:43 V33674ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 05/24/23 19:43 V33674ENM <0.157 µg/m3 0.157 2.17o-Xylene 1 05/24/23 19:43 V33674ENM <0.217 µg/m3 0.217 5.65m,p-Xylene 1 05/24/23 19:43 V33674ENM <0.157 µg/m3 0.157 2.17Xylene (Total)1 05/24/23 19:43 V33674 Surrogate: 4-Bromofluorobenzene Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 11 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:IAS-1 96674 Matrix: 5/17/2023 9:24 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/24/23 09:00 14.4 µg/m3 0.202 4.75Acetone 1 05/24/23 20:33 V33674ENM 0.383 J µg/m3 0.073 1.60Benzene 1 05/24/23 20:33 V33674ENM <0.147 µg/m3 0.147 10.4Benzyl Chloride 1 05/24/23 20:33 V33674ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 05/24/23 20:33 V33674ENM <0.153 µg/m3 0.153 5.17Bromoform 1 05/24/23 20:33 V33674ENM <0.115 µg/m3 0.115 1.94Bromomethane 1 05/24/23 20:33 V33674ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 05/24/23 20:33 V33674ENM 1.31 JB µg/m3 0.060 6.23Carbon Disulfide 1 05/24/23 20:33 V33674ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 05/24/23 20:33 V33674ENM <0.107 µg/m3 0.107 2.30Chlorobenzene 1 05/24/23 20:33 V33674ENM <0.208 µg/m3 0.208 4.26Chlorodibromomethane 1 05/24/23 20:33 V33674ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 05/24/23 20:33 V33674ENM 3.17 µg/m3 0.086 2.44Chloroform 1 05/24/23 20:33 V33674ENM 0.753 J µg/m3 0.067 1.03Chloromethane 1 05/24/23 20:33 V33674ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 05/24/23 20:33 V33674ENM <0.151 µg/m3 0.151 3.841,2-Dibromoethane 1 05/24/23 20:33 V33674ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 05/24/23 20:33 V33674ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 05/24/23 20:33 V33674ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 05/24/23 20:33 V33674ENM 2.53 µg/m3 0.134 2.47Dichlorodifluoromethane 1 05/24/23 20:33 V33674ENM <0.101 µg/m3 0.101 2.021,1-Dichloroethane 1 05/24/23 20:33 V33674ENM <0.129 µg/m3 0.129 2.021,2-Dichloroethane 1 05/24/23 20:33 V33674ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 12 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:IAS-1 96674 Matrix: 5/17/2023 9:24 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/24/23 09:00 <0.107 µg/m3 0.107 1.981,1-Dichloroethene 1 05/24/23 20:33 V33674ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 05/24/23 20:33 V33674ENM <0.108 µg/m3 0.108 1.98trans-1,2-Dichloroethene 1 05/24/23 20:33 V33674ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 05/24/23 20:33 V33674ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 05/24/23 20:33 V33674ENM <0.178 µg/m3 0.178 2.27cis-1,3-Dichloropropene 1 05/24/23 20:33 V33674ENM <0.178 µg/m3 0.178 2.27trans-1,3-Dichloropropene 1 05/24/23 20:33 V33674ENM <0.435 µg/m3 0.435 1.801,4-Dioxane 1 05/24/23 20:33 V33674ENM 2.37 µg/m3 0.136 1.80Ethyl Acetate 1 05/24/23 20:33 V33674ENM <0.106 µg/m3 0.106 2.17Ethylbenzene 1 05/24/23 20:33 V33674ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 05/24/23 20:33 V33674ENM <0.561 µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 05/24/23 20:33 V33674ENM 0.631 J µg/m3 0.143 2.05Heptane 1 05/24/23 20:33 V33674ENM <0.330 µg/m3 0.330 5.33Hexachlorobutadiene 1 05/24/23 20:33 V33674ENM 0.641 J µg/m3 0.047 1.76n-Hexane 1 05/24/23 20:33 V33674ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 05/24/23 20:33 V33674ENM 1.60 J µg/m3 0.139 4.92Isopropyl Alcohol 1 05/24/23 20:33 V33674ENM 1.80 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 05/24/23 20:33 V33674ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 05/24/23 20:33 V33674ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 05/24/23 20:33 V33674ENM <0.488 µg/m3 0.488 1.74Methylene Chloride 1 05/24/23 20:33 V33674ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 05/24/23 20:33 V33674ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 13 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:IAS-1 96674 Matrix: 5/17/2023 9:24 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/24/23 09:00 <0.242 µg/m3 0.242 0.860Propene 1 05/24/23 20:33 V33674ENM 2.39 µg/m3 0.124 2.13Styrene 1 05/24/23 20:33 V33674ENM <0.104 µg/m3 0.104 3.431,1,2,2-Tetrachloroethane 1 05/24/23 20:33 V33674ENM <0.181 µg/m3 0.181 3.39 1 05/24/23 20:33 V33674ENM 0.386 J µg/m3 0.107 1.47 1 05/24/23 20:33 V33674ENM 1.39 J µg/m3 0.090 1.88 1 05/24/23 20:33 V33674ENM <0.209 µg/m3 0.209 3.711,2,4-Trichlorobenzene 1 05/24/23 20:33 V33674ENM <0.144 µg/m3 0.144 2.731,1,1-Trichloroethane 1 05/24/23 20:33 V33674ENM <0.087 µg/m3 0.087 2.731,1,2-Trichloroethane 1 05/24/23 20:33 V33674ENM <0.199 µg/m3 0.199 2.15 1 05/24/23 20:33 V33674ENM 1.70 J µg/m3 0.130 2.81 1 05/24/23 20:33 V33674ENM 1.94 J µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 05/24/23 20:33 V33674ENM 0.722 J µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 05/24/23 20:33 V33674ENM <0.224 µg/m3 0.224 1.76Vinyl Acetate 1 05/24/23 20:33 V33674ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 05/24/23 20:33 V33674ENM <0.157 µg/m3 0.157 2.17o-Xylene 1 05/24/23 20:33 V33674ENM <0.217 µg/m3 0.217 5.65m,p-Xylene 1 05/24/23 20:33 V33674ENM <0.157 µg/m3 0.157 2.17Xylene (Total)1 05/24/23 20:33 V33674 Surrogate: 4-Bromofluorobenzene Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 14 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:IAS-2 96675 Matrix: 5/17/2023 9:23 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/24/23 09:00 17.9 µg/m3 0.202 4.75Acetone 1 05/24/23 21:23 V33674ENM 0.408 J µg/m3 0.073 1.60Benzene 1 05/24/23 21:23 V33674ENM <0.147 µg/m3 0.147 10.4Benzyl Chloride 1 05/24/23 21:23 V33674ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 05/24/23 21:23 V33674ENM <0.153 µg/m3 0.153 5.17Bromoform 1 05/24/23 21:23 V33674ENM <0.115 µg/m3 0.115 1.94Bromomethane 1 05/24/23 21:23 V33674ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 05/24/23 21:23 V33674ENM <0.060 µg/m3 0.060 6.23Carbon Disulfide 1 05/24/23 21:23 V33674ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 05/24/23 21:23 V33674ENM <0.107 µg/m3 0.107 2.30Chlorobenzene 1 05/24/23 21:23 V33674ENM <0.208 µg/m3 0.208 4.26Chlorodibromomethane 1 05/24/23 21:23 V33674ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 05/24/23 21:23 V33674ENM 7.56 µg/m3 0.086 2.44Chloroform 1 05/24/23 21:23 V33674ENM 0.755 J µg/m3 0.067 1.03Chloromethane 1 05/24/23 21:23 V33674ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 05/24/23 21:23 V33674ENM <0.151 µg/m3 0.151 3.841,2-Dibromoethane 1 05/24/23 21:23 V33674ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 05/24/23 21:23 V33674ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 05/24/23 21:23 V33674ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 05/24/23 21:23 V33674ENM 2.35 J µg/m3 0.134 2.47Dichlorodifluoromethane 1 05/24/23 21:23 V33674ENM <0.101 µg/m3 0.101 2.021,1-Dichloroethane 1 05/24/23 21:23 V33674ENM <0.129 µg/m3 0.129 2.021,2-Dichloroethane 1 05/24/23 21:23 V33674ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 15 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:IAS-2 96675 Matrix: 5/17/2023 9:23 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/24/23 09:00 <0.107 µg/m3 0.107 1.981,1-Dichloroethene 1 05/24/23 21:23 V33674ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 05/24/23 21:23 V33674ENM <0.108 µg/m3 0.108 1.98trans-1,2-Dichloroethene 1 05/24/23 21:23 V33674ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 05/24/23 21:23 V33674ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 05/24/23 21:23 V33674ENM <0.178 µg/m3 0.178 2.27cis-1,3-Dichloropropene 1 05/24/23 21:23 V33674ENM <0.178 µg/m3 0.178 2.27trans-1,3-Dichloropropene 1 05/24/23 21:23 V33674ENM <0.435 µg/m3 0.435 1.801,4-Dioxane 1 05/24/23 21:23 V33674ENM 2.57 µg/m3 0.136 1.80Ethyl Acetate 1 05/24/23 21:23 V33674ENM <0.106 µg/m3 0.106 2.17Ethylbenzene 1 05/24/23 21:23 V33674ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 05/24/23 21:23 V33674ENM <0.561 µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 05/24/23 21:23 V33674ENM 0.639 J µg/m3 0.143 2.05Heptane 1 05/24/23 21:23 V33674ENM <0.330 µg/m3 0.330 5.33Hexachlorobutadiene 1 05/24/23 21:23 V33674ENM 0.613 J µg/m3 0.047 1.76n-Hexane 1 05/24/23 21:23 V33674ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 05/24/23 21:23 V33674ENM 0.978 J µg/m3 0.139 4.92Isopropyl Alcohol 1 05/24/23 21:23 V33674ENM 2.06 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 05/24/23 21:23 V33674ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 05/24/23 21:23 V33674ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 05/24/23 21:23 V33674ENM <0.488 µg/m3 0.488 1.74Methylene Chloride 1 05/24/23 21:23 V33674ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 05/24/23 21:23 V33674ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 16 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:IAS-2 96675 Matrix: 5/17/2023 9:23 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/24/23 09:00 <0.242 µg/m3 0.242 0.860Propene 1 05/24/23 21:23 V33674ENM 1.35 J µg/m3 0.124 2.13Styrene 1 05/24/23 21:23 V33674ENM <0.104 µg/m3 0.104 3.431,1,2,2-Tetrachloroethane 1 05/24/23 21:23 V33674ENM <0.181 µg/m3 0.181 3.39 1 05/24/23 21:23 V33674ENM 0.353 J µg/m3 0.107 1.47 1 05/24/23 21:23 V33674ENM 2.40 µg/m3 0.090 1.88 1 05/24/23 21:23 V33674ENM <0.209 µg/m3 0.209 3.711,2,4-Trichlorobenzene 1 05/24/23 21:23 V33674ENM <0.144 µg/m3 0.144 2.731,1,1-Trichloroethane 1 05/24/23 21:23 V33674ENM <0.087 µg/m3 0.087 2.731,1,2-Trichloroethane 1 05/24/23 21:23 V33674ENM <0.199 µg/m3 0.199 2.15 1 05/24/23 21:23 V33674ENM 1.46 J µg/m3 0.130 2.81 1 05/24/23 21:23 V33674ENM 0.560 J µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 05/24/23 21:23 V33674ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 05/24/23 21:23 V33674ENM <0.224 µg/m3 0.224 1.76Vinyl Acetate 1 05/24/23 21:23 V33674ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 05/24/23 21:23 V33674ENM <0.157 µg/m3 0.157 2.17o-Xylene 1 05/24/23 21:23 V33674ENM <0.217 µg/m3 0.217 5.65m,p-Xylene 1 05/24/23 21:23 V33674ENM <0.157 µg/m3 0.157 2.17Xylene (Total)1 05/24/23 21:23 V33674 Surrogate: 4-Bromofluorobenzene Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 17 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:IAS-3 96676 Matrix: 5/17/2023 9:22 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/24/23 09:00 16.7 µg/m3 0.202 4.75Acetone 1 05/24/23 22:13 V33674ENM 0.389 J µg/m3 0.073 1.60Benzene 1 05/24/23 22:13 V33674ENM <0.147 µg/m3 0.147 10.4Benzyl Chloride 1 05/24/23 22:13 V33674ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 05/24/23 22:13 V33674ENM <0.153 µg/m3 0.153 5.17Bromoform 1 05/24/23 22:13 V33674ENM <0.115 µg/m3 0.115 1.94Bromomethane 1 05/24/23 22:13 V33674ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 05/24/23 22:13 V33674ENM <0.060 µg/m3 0.060 6.23Carbon Disulfide 1 05/24/23 22:13 V33674ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 05/24/23 22:13 V33674ENM <0.107 µg/m3 0.107 2.30Chlorobenzene 1 05/24/23 22:13 V33674ENM <0.208 µg/m3 0.208 4.26Chlorodibromomethane 1 05/24/23 22:13 V33674ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 05/24/23 22:13 V33674ENM 1.34 J µg/m3 0.086 2.44Chloroform 1 05/24/23 22:13 V33674ENM 0.689 J µg/m3 0.067 1.03Chloromethane 1 05/24/23 22:13 V33674ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 05/24/23 22:13 V33674ENM <0.151 µg/m3 0.151 3.841,2-Dibromoethane 1 05/24/23 22:13 V33674ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 05/24/23 22:13 V33674ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 05/24/23 22:13 V33674ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 05/24/23 22:13 V33674ENM 2.31 J µg/m3 0.134 2.47Dichlorodifluoromethane 1 05/24/23 22:13 V33674ENM <0.101 µg/m3 0.101 2.021,1-Dichloroethane 1 05/24/23 22:13 V33674ENM <0.129 µg/m3 0.129 2.021,2-Dichloroethane 1 05/24/23 22:13 V33674ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 18 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:IAS-3 96676 Matrix: 5/17/2023 9:22 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/24/23 09:00 <0.107 µg/m3 0.107 1.981,1-Dichloroethene 1 05/24/23 22:13 V33674ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 05/24/23 22:13 V33674ENM <0.108 µg/m3 0.108 1.98trans-1,2-Dichloroethene 1 05/24/23 22:13 V33674ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 05/24/23 22:13 V33674ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 05/24/23 22:13 V33674ENM <0.178 µg/m3 0.178 2.27cis-1,3-Dichloropropene 1 05/24/23 22:13 V33674ENM <0.178 µg/m3 0.178 2.27trans-1,3-Dichloropropene 1 05/24/23 22:13 V33674ENM <0.435 µg/m3 0.435 1.801,4-Dioxane 1 05/24/23 22:13 V33674ENM 0.724 J µg/m3 0.136 1.80Ethyl Acetate 1 05/24/23 22:13 V33674ENM <0.106 µg/m3 0.106 2.17Ethylbenzene 1 05/24/23 22:13 V33674ENM 0.408 J µg/m3 0.128 2.464-Ethyltoluene 1 05/24/23 22:13 V33674ENM <0.561 µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 05/24/23 22:13 V33674ENM 0.418 J µg/m3 0.143 2.05Heptane 1 05/24/23 22:13 V33674ENM <0.330 µg/m3 0.330 5.33Hexachlorobutadiene 1 05/24/23 22:13 V33674ENM 0.563 J µg/m3 0.047 1.76n-Hexane 1 05/24/23 22:13 V33674ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 05/24/23 22:13 V33674ENM 0.235 J µg/m3 0.139 4.92Isopropyl Alcohol 1 05/24/23 22:13 V33674ENM 1.42 J µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 05/24/23 22:13 V33674ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 05/24/23 22:13 V33674ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 05/24/23 22:13 V33674ENM <0.488 µg/m3 0.488 1.74Methylene Chloride 1 05/24/23 22:13 V33674ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 05/24/23 22:13 V33674ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 19 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:IAS-3 96676 Matrix: 5/17/2023 9:22 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/24/23 09:00 <0.242 µg/m3 0.242 0.860Propene 1 05/24/23 22:13 V33674ENM 1.38 J µg/m3 0.124 2.13Styrene 1 05/24/23 22:13 V33674ENM <0.104 µg/m3 0.104 3.431,1,2,2-Tetrachloroethane 1 05/24/23 22:13 V33674ENM <0.181 µg/m3 0.181 3.39 1 05/24/23 22:13 V33674ENM <0.107 µg/m3 0.107 1.47 1 05/24/23 22:13 V33674ENM 1.23 J µg/m3 0.090 1.88 1 05/24/23 22:13 V33674ENM <0.209 µg/m3 0.209 3.711,2,4-Trichlorobenzene 1 05/24/23 22:13 V33674ENM <0.144 µg/m3 0.144 2.731,1,1-Trichloroethane 1 05/24/23 22:13 V33674ENM <0.087 µg/m3 0.087 2.731,1,2-Trichloroethane 1 05/24/23 22:13 V33674ENM <0.199 µg/m3 0.199 2.15 1 05/24/23 22:13 V33674ENM 1.39 J µg/m3 0.130 2.81 1 05/24/23 22:13 V33674ENM 2.35 J µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 05/24/23 22:13 V33674ENM 0.806 J µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 05/24/23 22:13 V33674ENM <0.224 µg/m3 0.224 1.76Vinyl Acetate 1 05/24/23 22:13 V33674ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 05/24/23 22:13 V33674ENM <0.157 µg/m3 0.157 2.17o-Xylene 1 05/24/23 22:13 V33674ENM <0.217 µg/m3 0.217 5.65m,p-Xylene 1 05/24/23 22:13 V33674ENM <0.157 µg/m3 0.157 2.17Xylene (Total)1 05/24/23 22:13 V33674 Surrogate: 4-Bromofluorobenzene Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 20 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:BKG-051726 96677 Matrix: 5/17/2023 9:21 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/24/23 09:00 20.1 µg/m3 0.202 4.75Acetone 1 05/24/23 23:06 V33674ENM 0.421 J µg/m3 0.073 1.60Benzene 1 05/24/23 23:06 V33674ENM <0.147 µg/m3 0.147 10.4Benzyl Chloride 1 05/24/23 23:06 V33674ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 05/24/23 23:06 V33674ENM <0.153 µg/m3 0.153 5.17Bromoform 1 05/24/23 23:06 V33674ENM <0.115 µg/m3 0.115 1.94Bromomethane 1 05/24/23 23:06 V33674ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 05/24/23 23:06 V33674ENM <0.060 µg/m3 0.060 6.23Carbon Disulfide 1 05/24/23 23:06 V33674ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 05/24/23 23:06 V33674ENM <0.107 µg/m3 0.107 2.30Chlorobenzene 1 05/24/23 23:06 V33674ENM <0.208 µg/m3 0.208 4.26Chlorodibromomethane 1 05/24/23 23:06 V33674ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 05/24/23 23:06 V33674ENM <0.086 µg/m3 0.086 2.44Chloroform 1 05/24/23 23:06 V33674ENM 0.747 J µg/m3 0.067 1.03Chloromethane 1 05/24/23 23:06 V33674ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 05/24/23 23:06 V33674ENM <0.151 µg/m3 0.151 3.841,2-Dibromoethane 1 05/24/23 23:06 V33674ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 05/24/23 23:06 V33674ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 05/24/23 23:06 V33674ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 05/24/23 23:06 V33674ENM 2.37 J µg/m3 0.134 2.47Dichlorodifluoromethane 1 05/24/23 23:06 V33674ENM <0.101 µg/m3 0.101 2.021,1-Dichloroethane 1 05/24/23 23:06 V33674ENM <0.129 µg/m3 0.129 2.021,2-Dichloroethane 1 05/24/23 23:06 V33674ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 21 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:BKG-051726 96677 Matrix: 5/17/2023 9:21 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/24/23 09:00 <0.107 µg/m3 0.107 1.981,1-Dichloroethene 1 05/24/23 23:06 V33674ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 05/24/23 23:06 V33674ENM <0.108 µg/m3 0.108 1.98trans-1,2-Dichloroethene 1 05/24/23 23:06 V33674ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 05/24/23 23:06 V33674ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 05/24/23 23:06 V33674ENM <0.178 µg/m3 0.178 2.27cis-1,3-Dichloropropene 1 05/24/23 23:06 V33674ENM <0.178 µg/m3 0.178 2.27trans-1,3-Dichloropropene 1 05/24/23 23:06 V33674ENM <0.435 µg/m3 0.435 1.801,4-Dioxane 1 05/24/23 23:06 V33674ENM <0.136 µg/m3 0.136 1.80Ethyl Acetate 1 05/24/23 23:06 V33674ENM <0.106 µg/m3 0.106 2.17Ethylbenzene 1 05/24/23 23:06 V33674ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 05/24/23 23:06 V33674ENM <0.561 µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 05/24/23 23:06 V33674ENM 0.549 J µg/m3 0.143 2.05Heptane 1 05/24/23 23:06 V33674ENM <0.330 µg/m3 0.330 5.33Hexachlorobutadiene 1 05/24/23 23:06 V33674ENM 0.807 J µg/m3 0.047 1.76n-Hexane 1 05/24/23 23:06 V33674ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 05/24/23 23:06 V33674ENM <0.139 µg/m3 0.139 4.92Isopropyl Alcohol 1 05/24/23 23:06 V33674ENM 1.05 J µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 05/24/23 23:06 V33674ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 05/24/23 23:06 V33674ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 05/24/23 23:06 V33674ENM <0.488 µg/m3 0.488 1.74Methylene Chloride 1 05/24/23 23:06 V33674ENM 3.89 µg/m3 0.183 2.62Naphthalene 1 05/24/23 23:06 V33674ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 22 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:BKG-051726 96677 Matrix: 5/17/2023 9:21 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/24/23 09:00 <0.242 µg/m3 0.242 0.860Propene 1 05/24/23 23:06 V33674ENM <0.124 µg/m3 0.124 2.13Styrene 1 05/24/23 23:06 V33674ENM <0.104 µg/m3 0.104 3.431,1,2,2-Tetrachloroethane 1 05/24/23 23:06 V33674ENM <0.181 µg/m3 0.181 3.39 1 05/24/23 23:06 V33674ENM <0.107 µg/m3 0.107 1.47 1 05/24/23 23:06 V33674ENM 1.67 J µg/m3 0.090 1.88 1 05/24/23 23:06 V33674ENM <0.209 µg/m3 0.209 3.711,2,4-Trichlorobenzene 1 05/24/23 23:06 V33674ENM <0.144 µg/m3 0.144 2.731,1,1-Trichloroethane 1 05/24/23 23:06 V33674ENM <0.087 µg/m3 0.087 2.731,1,2-Trichloroethane 1 05/24/23 23:06 V33674ENM <0.199 µg/m3 0.199 2.15 1 05/24/23 23:06 V33674ENM 1.53 J µg/m3 0.130 2.81 1 05/24/23 23:06 V33674ENM <0.110 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 05/24/23 23:06 V33674ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 05/24/23 23:06 V33674ENM <0.224 µg/m3 0.224 1.76Vinyl Acetate 1 05/24/23 23:06 V33674ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 05/24/23 23:06 V33674ENM <0.157 µg/m3 0.157 2.17o-Xylene 1 05/24/23 23:06 V33674ENM <0.217 µg/m3 0.217 5.65m,p-Xylene 1 05/24/23 23:06 V33674ENM <0.157 µg/m3 0.157 2.17Xylene (Total)1 05/24/23 23:06 V33674 Surrogate: 4-Bromofluorobenzene Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 23 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:P-1 96678 Matrix: 5/17/2023 9:25 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/25/23 09:00 V33784 05/26/23 09:00 138 µg/m3 1.01 23.8Acetone 5 05/26/23 18:46 V33785ENM 0.527 J µg/m3 0.073 1.60Benzene 1 05/26/23 00:03 V33777ENM <0.147 µg/m3 0.147 10.4Benzyl Chloride 1 05/26/23 00:03 V33777ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 05/26/23 00:03 V33777ENM <0.153 µg/m3 0.153 5.17Bromoform 1 05/26/23 00:03 V33777ENM <0.115 µg/m3 0.115 1.94Bromomethane 1 05/26/23 00:03 V33777ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 05/26/23 00:03 V33777ENM 0.258 J µg/m3 0.060 6.23Carbon Disulfide 1 05/26/23 00:03 V33777ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 05/26/23 00:03 V33777ENM <0.107 µg/m3 0.107 2.30Chlorobenzene 1 05/26/23 00:03 V33777ENM <0.208 µg/m3 0.208 4.26Chlorodibromomethane 1 05/26/23 00:03 V33777ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 05/26/23 00:03 V33777ENM <0.086 µg/m3 0.086 2.44Chloroform 1 05/26/23 00:03 V33777ENM 0.706 J µg/m3 0.067 1.03Chloromethane 1 05/26/23 00:03 V33777ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 05/26/23 00:03 V33777ENM <0.151 µg/m3 0.151 3.841,2-Dibromoethane 1 05/26/23 00:03 V33777ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 05/26/23 00:03 V33777ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 05/26/23 00:03 V33777ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 05/26/23 00:03 V33777ENM 2.32 J µg/m3 0.134 2.47Dichlorodifluoromethane 1 05/26/23 00:03 V33777ENM <0.101 µg/m3 0.101 2.021,1-Dichloroethane 1 05/26/23 00:03 V33777ENM <0.129 µg/m3 0.129 2.021,2-Dichloroethane 1 05/26/23 00:03 V33777ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 24 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:P-1 96678 Matrix: 5/17/2023 9:25 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/25/23 09:00 V33784 05/26/23 09:00 <0.107 µg/m3 0.107 1.981,1-Dichloroethene 1 05/26/23 00:03 V33777ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 05/26/23 00:03 V33777ENM <0.108 µg/m3 0.108 1.98trans-1,2-Dichloroethene 1 05/26/23 00:03 V33777ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 05/26/23 00:03 V33777ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 05/26/23 00:03 V33777ENM <0.178 µg/m3 0.178 2.27cis-1,3-Dichloropropene 1 05/26/23 00:03 V33777ENM <0.178 µg/m3 0.178 2.27trans-1,3-Dichloropropene 1 05/26/23 00:03 V33777ENM <0.435 µg/m3 0.435 1.801,4-Dioxane 1 05/26/23 00:03 V33777ENM <0.136 µg/m3 0.136 1.80Ethyl Acetate 1 05/26/23 00:03 V33777ENM <0.106 µg/m3 0.106 2.17Ethylbenzene 1 05/26/23 00:03 V33777ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 05/26/23 00:03 V33777ENM <0.561 µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 05/26/23 00:03 V33777ENM 0.831 J µg/m3 0.143 2.05Heptane 1 05/26/23 00:03 V33777ENM <0.330 µg/m3 0.330 5.33Hexachlorobutadiene 1 05/26/23 00:03 V33777ENM 0.641 J µg/m3 0.047 1.76n-Hexane 1 05/26/23 00:03 V33777ENM 1.50 J µg/m3 0.285 2.052-Hexanone 1 05/26/23 00:03 V33777ENM 15.2 µg/m3 0.139 4.92Isopropyl Alcohol 1 05/26/23 00:03 V33777ENM 9.54 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 05/26/23 00:03 V33777ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 05/26/23 00:03 V33777ENM 0.421 J µg/m3 0.121 2.054-Methyl-2-Pentanone 1 05/26/23 00:03 V33777ENM <0.488 µg/m3 0.488 1.74Methylene Chloride 1 05/26/23 00:03 V33777ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 05/26/23 00:03 V33777ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 25 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:P-1 96678 Matrix: 5/17/2023 9:25 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/25/23 09:00 V33784 05/26/23 09:00 0.786 J µg/m3 0.242 0.860Propene 1 05/26/23 00:03 V33777ENM 0.711 J µg/m3 0.124 2.13Styrene 1 05/26/23 00:03 V33777ENM <0.104 µg/m3 0.104 3.431,1,2,2-Tetrachloroethane 1 05/26/23 00:03 V33777ENM 0.746 J µg/m3 0.181 3.39 1 05/26/23 00:03 V33777ENM 1.72 µg/m3 0.107 1.47 1 05/26/23 00:03 V33777ENM 6.90 µg/m3 0.090 1.88 1 05/26/23 00:03 V33777ENM <0.209 µg/m3 0.209 3.711,2,4-Trichlorobenzene 1 05/26/23 00:03 V33777ENM <0.144 µg/m3 0.144 2.731,1,1-Trichloroethane 1 05/26/23 00:03 V33777ENM <0.087 µg/m3 0.087 2.731,1,2-Trichloroethane 1 05/26/23 00:03 V33777ENM <0.199 µg/m3 0.199 2.15 1 05/26/23 00:03 V33777ENM 1.37 J µg/m3 0.130 2.81 1 05/26/23 00:03 V33777ENM 0.491 J µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 05/26/23 00:03 V33777ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 05/26/23 00:03 V33777ENM <0.224 µg/m3 0.224 1.76Vinyl Acetate 1 05/26/23 00:03 V33777ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 05/26/23 00:03 V33777ENM 0.494 J µg/m3 0.157 2.17o-Xylene 1 05/26/23 00:03 V33777ENM <0.217 µg/m3 0.217 5.65m,p-Xylene 1 05/26/23 00:03 V33777ENM 0.494 J µg/m3 0.157 2.17Xylene (Total)1 05/26/23 00:03 V33777 Surrogate: 4-Bromofluorobenzene Surrogate: 4-Bromofluorobenzene Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 26 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:P-1 96679 Matrix: 5/18/2023 12:49 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/25/23 09:00 6.71 µg/m3 0.202 4.75Acetone 1 05/25/23 17:42 V33777ENM 0.338 J µg/m3 0.073 1.60Benzene 1 05/25/23 17:42 V33777ENM <0.147 µg/m3 0.147 10.4Benzyl Chloride 1 05/25/23 17:42 V33777ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 05/25/23 17:42 V33777ENM <0.153 µg/m3 0.153 5.17Bromoform 1 05/25/23 17:42 V33777ENM <0.115 µg/m3 0.115 1.94Bromomethane 1 05/25/23 17:42 V33777ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 05/25/23 17:42 V33777ENM 1.75 J µg/m3 0.060 6.23Carbon Disulfide 1 05/25/23 17:42 V33777ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 05/25/23 17:42 V33777ENM <0.107 µg/m3 0.107 2.30Chlorobenzene 1 05/25/23 17:42 V33777ENM <0.208 µg/m3 0.208 4.26Chlorodibromomethane 1 05/25/23 17:42 V33777ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 05/25/23 17:42 V33777ENM 3.51 µg/m3 0.086 2.44Chloroform 1 05/25/23 17:42 V33777ENM <0.067 µg/m3 0.067 1.03Chloromethane 1 05/25/23 17:42 V33777ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 05/25/23 17:42 V33777ENM <0.151 µg/m3 0.151 3.841,2-Dibromoethane 1 05/25/23 17:42 V33777ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 05/25/23 17:42 V33777ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 05/25/23 17:42 V33777ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 05/25/23 17:42 V33777ENM 12.5 µg/m3 0.134 2.47Dichlorodifluoromethane 1 05/25/23 17:42 V33777ENM <0.101 µg/m3 0.101 2.021,1-Dichloroethane 1 05/25/23 17:42 V33777ENM <0.129 µg/m3 0.129 2.021,2-Dichloroethane 1 05/25/23 17:42 V33777ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 27 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:P-1 96679 Matrix: 5/18/2023 12:49 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/25/23 09:00 <0.107 µg/m3 0.107 1.981,1-Dichloroethene 1 05/25/23 17:42 V33777ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 05/25/23 17:42 V33777ENM <0.108 µg/m3 0.108 1.98trans-1,2-Dichloroethene 1 05/25/23 17:42 V33777ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 05/25/23 17:42 V33777ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 05/25/23 17:42 V33777ENM <0.178 µg/m3 0.178 2.27cis-1,3-Dichloropropene 1 05/25/23 17:42 V33777ENM <0.178 µg/m3 0.178 2.27trans-1,3-Dichloropropene 1 05/25/23 17:42 V33777ENM <0.435 µg/m3 0.435 1.801,4-Dioxane 1 05/25/23 17:42 V33777ENM <0.136 µg/m3 0.136 1.80Ethyl Acetate 1 05/25/23 17:42 V33777ENM <0.106 µg/m3 0.106 2.17Ethylbenzene 1 05/25/23 17:42 V33777ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 05/25/23 17:42 V33777ENM <0.561 µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 05/25/23 17:42 V33777ENM <0.143 µg/m3 0.143 2.05Heptane 1 05/25/23 17:42 V33777ENM <0.330 µg/m3 0.330 5.33Hexachlorobutadiene 1 05/25/23 17:42 V33777ENM 0.327 J µg/m3 0.047 1.76n-Hexane 1 05/25/23 17:42 V33777ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 05/25/23 17:42 V33777ENM 1.21 J µg/m3 0.139 4.92Isopropyl Alcohol 1 05/25/23 17:42 V33777ENM 0.751 J µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 05/25/23 17:42 V33777ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 05/25/23 17:42 V33777ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 05/25/23 17:42 V33777ENM 2.07 µg/m3 0.488 1.74Methylene Chloride 1 05/25/23 17:42 V33777ENM 1.46 J µg/m3 0.183 2.62Naphthalene 1 05/25/23 17:42 V33777ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 28 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:P-1 96679 Matrix: 5/18/2023 12:49 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/25/23 09:00 <0.242 µg/m3 0.242 0.860Propene 1 05/25/23 17:42 V33777ENM <0.124 µg/m3 0.124 2.13Styrene 1 05/25/23 17:42 V33777ENM <0.104 µg/m3 0.104 3.431,1,2,2-Tetrachloroethane 1 05/25/23 17:42 V33777ENM 63.8 µg/m3 0.181 3.39 1 05/25/23 17:42 V33777ENM 0.327 J µg/m3 0.107 1.47 1 05/25/23 17:42 V33777ENM 1.13 J µg/m3 0.090 1.88 1 05/25/23 17:42 V33777ENM <0.209 µg/m3 0.209 3.711,2,4-Trichlorobenzene 1 05/25/23 17:42 V33777ENM 2.54 J µg/m3 0.144 2.731,1,1-Trichloroethane 1 05/25/23 17:42 V33777ENM <0.087 µg/m3 0.087 2.731,1,2-Trichloroethane 1 05/25/23 17:42 V33777ENM <0.199 µg/m3 0.199 2.15 1 05/25/23 17:42 V33777ENM 3.57 µg/m3 0.130 2.81 1 05/25/23 17:42 V33777ENM 1.06 J µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 05/25/23 17:42 V33777ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 05/25/23 17:42 V33777ENM <0.224 µg/m3 0.224 1.76Vinyl Acetate 1 05/25/23 17:42 V33777ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 05/25/23 17:42 V33777ENM <0.157 µg/m3 0.157 2.17o-Xylene 1 05/25/23 17:42 V33777ENM <0.217 µg/m3 0.217 5.65m,p-Xylene 1 05/25/23 17:42 V33777ENM <0.157 µg/m3 0.157 2.17Xylene (Total)1 05/25/23 17:42 V33777 Surrogate: 4-Bromofluorobenzene Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 29 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:MP-9 96680 Matrix: 5/19/2023 11:15 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/25/23 09:00 9.99 µg/m3 0.202 4.75Acetone 1 05/25/23 18:37 V33777ENM 0.396 J µg/m3 0.073 1.60Benzene 1 05/25/23 18:37 V33777ENM <0.147 µg/m3 0.147 10.4Benzyl Chloride 1 05/25/23 18:37 V33777ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 05/25/23 18:37 V33777ENM <0.153 µg/m3 0.153 5.17Bromoform 1 05/25/23 18:37 V33777ENM <0.115 µg/m3 0.115 1.94Bromomethane 1 05/25/23 18:37 V33777ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 05/25/23 18:37 V33777ENM 1.08 J µg/m3 0.060 6.23Carbon Disulfide 1 05/25/23 18:37 V33777ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 05/25/23 18:37 V33777ENM <0.107 µg/m3 0.107 2.30Chlorobenzene 1 05/25/23 18:37 V33777ENM <0.208 µg/m3 0.208 4.26Chlorodibromomethane 1 05/25/23 18:37 V33777ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 05/25/23 18:37 V33777ENM 0.527 J µg/m3 0.086 2.44Chloroform 1 05/25/23 18:37 V33777ENM <0.067 µg/m3 0.067 1.03Chloromethane 1 05/25/23 18:37 V33777ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 05/25/23 18:37 V33777ENM <0.151 µg/m3 0.151 3.841,2-Dibromoethane 1 05/25/23 18:37 V33777ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 05/25/23 18:37 V33777ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 05/25/23 18:37 V33777ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 05/25/23 18:37 V33777ENM 2.42 J µg/m3 0.134 2.47Dichlorodifluoromethane 1 05/25/23 18:37 V33777ENM <0.101 µg/m3 0.101 2.021,1-Dichloroethane 1 05/25/23 18:37 V33777ENM <0.129 µg/m3 0.129 2.021,2-Dichloroethane 1 05/25/23 18:37 V33777ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 30 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:MP-9 96680 Matrix: 5/19/2023 11:15 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/25/23 09:00 <0.107 µg/m3 0.107 1.981,1-Dichloroethene 1 05/25/23 18:37 V33777ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 05/25/23 18:37 V33777ENM <0.108 µg/m3 0.108 1.98trans-1,2-Dichloroethene 1 05/25/23 18:37 V33777ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 05/25/23 18:37 V33777ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 05/25/23 18:37 V33777ENM <0.178 µg/m3 0.178 2.27cis-1,3-Dichloropropene 1 05/25/23 18:37 V33777ENM <0.178 µg/m3 0.178 2.27trans-1,3-Dichloropropene 1 05/25/23 18:37 V33777ENM <0.435 µg/m3 0.435 1.801,4-Dioxane 1 05/25/23 18:37 V33777ENM <0.136 µg/m3 0.136 1.80Ethyl Acetate 1 05/25/23 18:37 V33777ENM 0.542 J µg/m3 0.106 2.17Ethylbenzene 1 05/25/23 18:37 V33777ENM 19.9 µg/m3 0.128 2.464-Ethyltoluene 1 05/25/23 18:37 V33777ENM <0.561 µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 05/25/23 18:37 V33777ENM <0.143 µg/m3 0.143 2.05Heptane 1 05/25/23 18:37 V33777ENM <0.330 µg/m3 0.330 5.33Hexachlorobutadiene 1 05/25/23 18:37 V33777ENM 0.401 J µg/m3 0.047 1.76n-Hexane 1 05/25/23 18:37 V33777ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 05/25/23 18:37 V33777ENM 0.228 J µg/m3 0.139 4.92Isopropyl Alcohol 1 05/25/23 18:37 V33777ENM 1.35 J µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 05/25/23 18:37 V33777ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 05/25/23 18:37 V33777ENM 2.01 J µg/m3 0.121 2.054-Methyl-2-Pentanone 1 05/25/23 18:37 V33777ENM 2.66 µg/m3 0.488 1.74Methylene Chloride 1 05/25/23 18:37 V33777ENM 0.477 J µg/m3 0.183 2.62Naphthalene 1 05/25/23 18:37 V33777ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 31 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:MP-9 96680 Matrix: 5/19/2023 11:15 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/25/23 09:00 <0.242 µg/m3 0.242 0.860Propene 1 05/25/23 18:37 V33777ENM 0.613 J µg/m3 0.124 2.13Styrene 1 05/25/23 18:37 V33777ENM <0.104 µg/m3 0.104 3.431,1,2,2-Tetrachloroethane 1 05/25/23 18:37 V33777ENM 11.7 µg/m3 0.181 3.39 1 05/25/23 18:37 V33777ENM 1.57 µg/m3 0.107 1.47 1 05/25/23 18:37 V33777ENM 1.42 J µg/m3 0.090 1.88 1 05/25/23 18:37 V33777ENM <0.209 µg/m3 0.209 3.711,2,4-Trichlorobenzene 1 05/25/23 18:37 V33777ENM 1.34 J µg/m3 0.144 2.731,1,1-Trichloroethane 1 05/25/23 18:37 V33777ENM <0.087 µg/m3 0.087 2.731,1,2-Trichloroethane 1 05/25/23 18:37 V33777ENM 131 µg/m3 0.199 2.15 1 05/25/23 18:37 V33777ENM 1.78 J µg/m3 0.130 2.81 1 05/25/23 18:37 V33777ENM 168 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 05/25/23 18:37 V33777ENM 88.1 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 05/25/23 18:37 V33777ENM <0.224 µg/m3 0.224 1.76Vinyl Acetate 1 05/25/23 18:37 V33777ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 05/25/23 18:37 V33777ENM 2.87 µg/m3 0.157 2.17o-Xylene 1 05/25/23 18:37 V33777ENM 0.460 J µg/m3 0.217 5.65m,p-Xylene 1 05/25/23 18:37 V33777ENM 3.33 J µg/m3 0.157 2.17Xylene (Total)1 05/25/23 18:37 V33777 Surrogate: 4-Bromofluorobenzene Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 32 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:MP-3 96681 Matrix: 5/19/2023 12:30 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/25/23 09:00 8.30 µg/m3 0.202 4.75Acetone 1 05/25/23 19:29 V33777ENM 0.472 J µg/m3 0.073 1.60Benzene 1 05/25/23 19:29 V33777ENM <0.147 µg/m3 0.147 10.4Benzyl Chloride 1 05/25/23 19:29 V33777ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 05/25/23 19:29 V33777ENM <0.153 µg/m3 0.153 5.17Bromoform 1 05/25/23 19:29 V33777ENM <0.115 µg/m3 0.115 1.94Bromomethane 1 05/25/23 19:29 V33777ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 05/25/23 19:29 V33777ENM 0.491 J µg/m3 0.060 6.23Carbon Disulfide 1 05/25/23 19:29 V33777ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 05/25/23 19:29 V33777ENM <0.107 µg/m3 0.107 2.30Chlorobenzene 1 05/25/23 19:29 V33777ENM <0.208 µg/m3 0.208 4.26Chlorodibromomethane 1 05/25/23 19:29 V33777ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 05/25/23 19:29 V33777ENM 5.22 µg/m3 0.086 2.44Chloroform 1 05/25/23 19:29 V33777ENM 0.685 J µg/m3 0.067 1.03Chloromethane 1 05/25/23 19:29 V33777ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 05/25/23 19:29 V33777ENM <0.151 µg/m3 0.151 3.841,2-Dibromoethane 1 05/25/23 19:29 V33777ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 05/25/23 19:29 V33777ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 05/25/23 19:29 V33777ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 05/25/23 19:29 V33777ENM 2.27 J µg/m3 0.134 2.47Dichlorodifluoromethane 1 05/25/23 19:29 V33777ENM <0.101 µg/m3 0.101 2.021,1-Dichloroethane 1 05/25/23 19:29 V33777ENM <0.129 µg/m3 0.129 2.021,2-Dichloroethane 1 05/25/23 19:29 V33777ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 33 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:MP-3 96681 Matrix: 5/19/2023 12:30 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/25/23 09:00 <0.107 µg/m3 0.107 1.981,1-Dichloroethene 1 05/25/23 19:29 V33777ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 05/25/23 19:29 V33777ENM <0.108 µg/m3 0.108 1.98trans-1,2-Dichloroethene 1 05/25/23 19:29 V33777ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 05/25/23 19:29 V33777ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 05/25/23 19:29 V33777ENM <0.178 µg/m3 0.178 2.27cis-1,3-Dichloropropene 1 05/25/23 19:29 V33777ENM <0.178 µg/m3 0.178 2.27trans-1,3-Dichloropropene 1 05/25/23 19:29 V33777ENM <0.435 µg/m3 0.435 1.801,4-Dioxane 1 05/25/23 19:29 V33777ENM <0.136 µg/m3 0.136 1.80Ethyl Acetate 1 05/25/23 19:29 V33777ENM 0.586 J µg/m3 0.106 2.17Ethylbenzene 1 05/25/23 19:29 V33777ENM 0.673 J µg/m3 0.128 2.464-Ethyltoluene 1 05/25/23 19:29 V33777ENM <0.561 µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 05/25/23 19:29 V33777ENM 0.315 J µg/m3 0.143 2.05Heptane 1 05/25/23 19:29 V33777ENM <0.330 µg/m3 0.330 5.33Hexachlorobutadiene 1 05/25/23 19:29 V33777ENM 0.613 J µg/m3 0.047 1.76n-Hexane 1 05/25/23 19:29 V33777ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 05/25/23 19:29 V33777ENM 2.49 J µg/m3 0.139 4.92Isopropyl Alcohol 1 05/25/23 19:29 V33777ENM 1.11 J µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 05/25/23 19:29 V33777ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 05/25/23 19:29 V33777ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 05/25/23 19:29 V33777ENM 2.10 µg/m3 0.488 1.74Methylene Chloride 1 05/25/23 19:29 V33777ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 05/25/23 19:29 V33777ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 34 of 50 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-139-0102 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Dave Kahn Charlotte Received : 05/19/2023 PAM-003 Report Date : 05/30/2023 Sample ID : Lab No : Sampled:MP-3 96681 Matrix: 5/19/2023 12:30 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):05/25/23 09:00 <0.242 µg/m3 0.242 0.860Propene 1 05/25/23 19:29 V33777ENM 5.18 µg/m3 0.124 2.13Styrene 1 05/25/23 19:29 V33777ENM <0.104 µg/m3 0.104 3.431,1,2,2-Tetrachloroethane 1 05/25/23 19:29 V33777ENM <0.181 µg/m3 0.181 3.39 1 05/25/23 19:29 V33777ENM 1.86 µg/m3 0.107 1.47 1 05/25/23 19:29 V33777ENM 2.13 µg/m3 0.090 1.88 1 05/25/23 19:29 V33777ENM <0.209 µg/m3 0.209 3.711,2,4-Trichlorobenzene 1 05/25/23 19:29 V33777ENM <0.144 µg/m3 0.144 2.731,1,1-Trichloroethane 1 05/25/23 19:29 V33777ENM <0.087 µg/m3 0.087 2.731,1,2-Trichloroethane 1 05/25/23 19:29 V33777ENM 0.548 J µg/m3 0.199 2.15 1 05/25/23 19:29 V33777ENM 1.42 J µg/m3 0.130 2.81 1 05/25/23 19:29 V33777ENM 13.3 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 05/25/23 19:29 V33777ENM 4.51 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 05/25/23 19:29 V33777ENM 0.792 J µg/m3 0.224 1.76Vinyl Acetate 1 05/25/23 19:29 V33777ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 05/25/23 19:29 V33777ENM 0.907 J µg/m3 0.157 2.17o-Xylene 1 05/25/23 19:29 V33777ENM <0.217 µg/m3 0.217 5.65m,p-Xylene 1 05/25/23 19:29 V33777ENM 0.907 J µg/m3 0.157 2.17Xylene (Total)1 05/25/23 19:29 V33777 Surrogate: 4-Bromofluorobenzene Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 35 of 50 Quality Control Data 23-139-0102Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM-003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V33674QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V33657 Associated Lab Samples: 96673, 96674, 96675, 96676, 96677 LRB-V33657 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 05/24/23 11:334.750.202<0.202µg/m3Acetone 05/24/23 11:331.600.073<0.073µg/m3Benzene 05/24/23 11:3310.40.147<0.147µg/m3Benzyl Chloride 05/24/23 11:333.350.150<0.150µg/m3Bromodichloromethane 05/24/23 11:335.170.153<0.153µg/m3Bromoform 05/24/23 11:331.940.115<0.115µg/m3Bromomethane 05/24/23 11:331.110.328<0.328µg/m31,3-Butadiene 05/24/23 11:336.230.0600.523µg/m3Carbon Disulfide 05/24/23 11:333.150.155<0.155µg/m3Carbon Tetrachloride 05/24/23 11:332.300.107<0.107µg/m3Chlorobenzene 05/24/23 11:334.260.208<0.208µg/m3Chlorodibromomethane 05/24/23 11:331.320.164<0.164µg/m3Chloroethane 05/24/23 11:332.440.086<0.086µg/m3Chloroform 05/24/23 11:331.030.067<0.067µg/m3Chloromethane 05/24/23 11:333.440.161<0.161µg/m3Cyclohexane 05/24/23 11:333.840.151<0.151µg/m31,2-Dibromoethane 05/24/23 11:333.010.096<0.096µg/m31,2-Dichlorobenzene 05/24/23 11:3312.00.174<0.174µg/m31,3-Dichlorobenzene 05/24/23 11:333.010.186<0.186µg/m31,4-Dichlorobenzene 05/24/23 11:332.470.134<0.134µg/m3Dichlorodifluoromethane 05/24/23 11:332.020.101<0.101µg/m31,1-Dichloroethane 05/24/23 11:332.020.129<0.129µg/m31,2-Dichloroethane 05/24/23 11:331.980.107<0.107µg/m31,1-Dichloroethene 05/24/23 11:331.980.095<0.095µg/m3cis-1,2-Dichloroethene 05/24/23 11:331.980.108<0.108µg/m3trans-1,2-Dichloroethene 05/24/23 11:332.310.205<0.205µg/m31,2-Dichloropropane 05/24/23 11:333.500.622<0.622µg/m31,2-Dichlorotetrafluoroethane Page 1 of 11Date:05/30/2023 03:29 PM Page 36 of 50 Quality Control Data 23-139-0102Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM-003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V33674QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V33657 Associated Lab Samples: 96673, 96674, 96675, 96676, 96677 LRB-V33657 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 05/24/23 11:332.270.178<0.178µg/m3cis-1,3-Dichloropropene 05/24/23 11:332.270.178<0.178µg/m3trans-1,3-Dichloropropene 05/24/23 11:331.800.435<0.435µg/m31,4-Dioxane 05/24/23 11:331.800.136<0.136µg/m3Ethyl Acetate 05/24/23 11:332.170.106<0.106µg/m3Ethylbenzene 05/24/23 11:332.460.128<0.128µg/m34-Ethyltoluene 05/24/23 11:333.830.561<0.561µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 05/24/23 11:332.050.143<0.143µg/m3Heptane 05/24/23 11:335.330.330<0.330µg/m3Hexachlorobutadiene 05/24/23 11:331.760.047<0.047µg/m3n-Hexane 05/24/23 11:332.050.285<0.285µg/m32-Hexanone 05/24/23 11:334.920.139<0.139µg/m3Isopropyl Alcohol 05/24/23 11:331.470.224<0.224µg/m3Methyl Ethyl Ketone (MEK) 05/24/23 11:331.800.033<0.033µg/m3Methyl tert-butyl ether (MTBE) 05/24/23 11:332.050.121<0.121µg/m34-Methyl-2-Pentanone 05/24/23 11:331.740.488<0.488µg/m3Methylene Chloride 05/24/23 11:332.620.183<0.183µg/m3Naphthalene 05/24/23 11:330.8600.242<0.242µg/m3Propene 05/24/23 11:332.130.124<0.124µg/m3Styrene 05/24/23 11:333.430.104<0.104µg/m31,1,2,2-Tetrachloroethane 05/24/23 11:333.390.181<0.181µg/m3 05/24/23 11:331.470.107<0.107µg/m3 05/24/23 11:331.880.090<0.090µg/m3 05/24/23 11:333.710.209<0.209µg/m31,2,4-Trichlorobenzene 05/24/23 11:332.730.144<0.144µg/m31,1,1-Trichloroethane 05/24/23 11:332.730.087<0.087µg/m31,1,2-Trichloroethane 05/24/23 11:332.150.199<0.199µg/m3 Page 2 of 11Date:05/30/2023 03:29 PM Page 37 of 50 Quality Control Data 23-139-0102Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM-003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V33674QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V33657 Associated Lab Samples: 96673, 96674, 96675, 96676, 96677 LRB-V33657 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 05/24/23 11:332.810.130<0.130µg/m3 05/24/23 11:332.460.110<0.110µg/m31,2,4-Trimethylbenzene 05/24/23 11:332.460.236<0.236µg/m31,3,5-Trimethylbenzene 05/24/23 11:331.760.224<0.224µg/m3Vinyl Acetate 05/24/23 11:331.280.127<0.127µg/m3Vinyl Chloride 05/24/23 11:332.170.157<0.157µg/m3o-Xylene 05/24/23 11:335.650.217<0.217µg/m3m,p-Xylene 05/24/23 11:334-Bromofluorobenzene (S)91.6 70-130 LCS-V33657Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 11713.911.9µg/m3Acetone 70-130 10216.316.0µg/m3Benzene 70-130 11128.725.9µg/m3Benzyl Chloride 70-130 10133.833.5µg/m3Bromodichloromethane 70-130 10252.751.7µg/m3Bromoform 70-130 11422.119.4µg/m3Bromomethane 70-130 11112.311.1µg/m31,3-Butadiene 70-130 11417.815.6µg/m3Carbon Disulfide 70-130 99.631.431.5µg/m3Carbon Tetrachloride 70-130 10624.423.0µg/m3Chlorobenzene 70-130 10343.742.6µg/m3Chlorodibromomethane 70-130 11715.413.2µg/m3Chloroethane 70-130 10425.324.4µg/m3Chloroform 70-130 11712.010.3µg/m3Chloromethane 70-130 10618.317.2µg/m3Cyclohexane 70-130 Page 3 of 11Date:05/30/2023 03:29 PM Page 38 of 50 Quality Control Data 23-139-0102Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM-003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V33674QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V33657 LCS-V33657Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10540.438.4µg/m31,2-Dibromoethane 70-130 11434.330.1µg/m31,2-Dichlorobenzene 70-130 11334.130.1µg/m31,3-Dichlorobenzene 70-130 11334.130.1µg/m31,4-Dichlorobenzene 70-130 11428.124.7µg/m3Dichlorodifluoromethane 70-130 11423.020.2µg/m31,1-Dichloroethane 70-130 10521.220.2µg/m31,2-Dichloroethane 70-130 11522.819.8µg/m31,1-Dichloroethene 70-130 11522.719.8µg/m3cis-1,2-Dichloroethene 70-130 11522.819.8µg/m3trans-1,2-Dichloroethene 70-130 10223.623.1µg/m31,2-Dichloropropane 70-130 11440.035.0µg/m31,2-Dichlorotetrafluoroethane 70-130 10022.822.7µg/m3cis-1,3-Dichloropropene 70-130 10022.822.7µg/m3trans-1,3-Dichloropropene 70-130 10118.118.0µg/m31,4-Dioxane 70-130 11420.618.0µg/m3Ethyl Acetate 70-130 10522.721.7µg/m3Ethylbenzene 70-130 10726.324.6µg/m34-Ethyltoluene 70-130 11443.738.3µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 70-130 99.520.420.5µg/m3Heptane 70-130 10556.053.3µg/m3Hexachlorobutadiene 70-130 11319.917.6µg/m3n-Hexane 70-130 10521.520.5µg/m32-Hexanone 70-130 11414.012.3µg/m3Isopropyl Alcohol 70-130 11016.314.8µg/m3Methyl Ethyl Ketone (MEK)70-130 11120.018.0µg/m3Methyl tert-butyl ether (MTBE)70-130 10321.220.5µg/m34-Methyl-2-Pentanone 70-130 Page 4 of 11Date:05/30/2023 03:29 PM Page 39 of 50 Quality Control Data 23-139-0102Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM-003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V33674QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V33657 LCS-V33657Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 11920.717.4µg/m3Methylene Chloride 70-130 12432.526.2µg/m3Naphthalene 70-130 11710.18.61µg/m3Propene 70-130 10322.021.3µg/m3Styrene 70-130 10535.934.3µg/m31,1,2,2-Tetrachloroethane 70-130 10134.133.9µg/m3 70-130 10415.314.7µg/m3 70-130 98.418.518.8µg/m3 70-130 12245.237.1µg/m31,2,4-Trichlorobenzene 70-130 10127.527.3µg/m31,1,1-Trichloroethane 70-130 10428.527.3µg/m31,1,2-Trichloroethane 70-130 10027.026.9µg/m3 70-130 11431.928.1µg/m3 70-130 11027.024.6µg/m31,2,4-Trimethylbenzene 70-130 10726.224.6µg/m31,3,5-Trimethylbenzene 70-130 11119.517.6µg/m3Vinyl Acetate 70-130 11314.412.8µg/m3Vinyl Chloride 70-130 10422.621.7µg/m3o-Xylene 70-130 99.543.243.4µg/m3m,p-Xylene 70-130 94.64-Bromofluorobenzene (S)70-130 Page 5 of 11Date:05/30/2023 03:29 PM Page 40 of 50 Quality Control Data 23-139-0102Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM-003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V33777QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V33771 Associated Lab Samples: 96678, 96679, 96680, 96681 LRB-V33771 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 05/25/23 12:394.750.202<0.202µg/m3Acetone 05/25/23 12:391.600.073<0.073µg/m3Benzene 05/25/23 12:3910.40.147<0.147µg/m3Benzyl Chloride 05/25/23 12:393.350.150<0.150µg/m3Bromodichloromethane 05/25/23 12:395.170.153<0.153µg/m3Bromoform 05/25/23 12:391.940.115<0.115µg/m3Bromomethane 05/25/23 12:391.110.328<0.328µg/m31,3-Butadiene 05/25/23 12:396.230.060<0.060µg/m3Carbon Disulfide 05/25/23 12:393.150.155<0.155µg/m3Carbon Tetrachloride 05/25/23 12:392.300.107<0.107µg/m3Chlorobenzene 05/25/23 12:394.260.208<0.208µg/m3Chlorodibromomethane 05/25/23 12:391.320.164<0.164µg/m3Chloroethane 05/25/23 12:392.440.086<0.086µg/m3Chloroform 05/25/23 12:391.030.067<0.067µg/m3Chloromethane 05/25/23 12:393.440.161<0.161µg/m3Cyclohexane 05/25/23 12:393.840.151<0.151µg/m31,2-Dibromoethane 05/25/23 12:393.010.096<0.096µg/m31,2-Dichlorobenzene 05/25/23 12:3912.00.174<0.174µg/m31,3-Dichlorobenzene 05/25/23 12:393.010.186<0.186µg/m31,4-Dichlorobenzene 05/25/23 12:392.470.134<0.134µg/m3Dichlorodifluoromethane 05/25/23 12:392.020.101<0.101µg/m31,1-Dichloroethane 05/25/23 12:392.020.129<0.129µg/m31,2-Dichloroethane 05/25/23 12:391.980.107<0.107µg/m31,1-Dichloroethene 05/25/23 12:391.980.095<0.095µg/m3cis-1,2-Dichloroethene 05/25/23 12:391.980.108<0.108µg/m3trans-1,2-Dichloroethene 05/25/23 12:392.310.205<0.205µg/m31,2-Dichloropropane 05/25/23 12:393.500.622<0.622µg/m31,2-Dichlorotetrafluoroethane Page 6 of 11Date:05/30/2023 03:29 PM Page 41 of 50 Quality Control Data 23-139-0102Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM-003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V33777QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V33771 Associated Lab Samples: 96678, 96679, 96680, 96681 LRB-V33771 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 05/25/23 12:392.270.178<0.178µg/m3cis-1,3-Dichloropropene 05/25/23 12:392.270.178<0.178µg/m3trans-1,3-Dichloropropene 05/25/23 12:391.800.435<0.435µg/m31,4-Dioxane 05/25/23 12:391.800.136<0.136µg/m3Ethyl Acetate 05/25/23 12:392.170.106<0.106µg/m3Ethylbenzene 05/25/23 12:392.460.128<0.128µg/m34-Ethyltoluene 05/25/23 12:393.830.561<0.561µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 05/25/23 12:392.050.143<0.143µg/m3Heptane 05/25/23 12:395.330.330<0.330µg/m3Hexachlorobutadiene 05/25/23 12:391.760.047<0.047µg/m3n-Hexane 05/25/23 12:392.050.285<0.285µg/m32-Hexanone 05/25/23 12:394.920.139<0.139µg/m3Isopropyl Alcohol 05/25/23 12:391.470.224<0.224µg/m3Methyl Ethyl Ketone (MEK) 05/25/23 12:391.800.033<0.033µg/m3Methyl tert-butyl ether (MTBE) 05/25/23 12:392.050.121<0.121µg/m34-Methyl-2-Pentanone 05/25/23 12:391.740.488<0.488µg/m3Methylene Chloride 05/25/23 12:392.620.183<0.183µg/m3Naphthalene 05/25/23 12:390.8600.242<0.242µg/m3Propene 05/25/23 12:392.130.124<0.124µg/m3Styrene 05/25/23 12:393.430.104<0.104µg/m31,1,2,2-Tetrachloroethane 05/25/23 12:393.390.181<0.181µg/m3 05/25/23 12:391.470.107<0.107µg/m3 05/25/23 12:391.880.090<0.090µg/m3 05/25/23 12:393.710.209<0.209µg/m31,2,4-Trichlorobenzene 05/25/23 12:392.730.144<0.144µg/m31,1,1-Trichloroethane 05/25/23 12:392.730.087<0.087µg/m31,1,2-Trichloroethane 05/25/23 12:392.150.199<0.199µg/m3 Page 7 of 11Date:05/30/2023 03:29 PM Page 42 of 50 Quality Control Data 23-139-0102Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM-003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V33777QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V33771 Associated Lab Samples: 96678, 96679, 96680, 96681 LRB-V33771 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 05/25/23 12:392.810.130<0.130µg/m3 05/25/23 12:392.460.110<0.110µg/m31,2,4-Trimethylbenzene 05/25/23 12:392.460.236<0.236µg/m31,3,5-Trimethylbenzene 05/25/23 12:391.760.224<0.224µg/m3Vinyl Acetate 05/25/23 12:391.280.127<0.127µg/m3Vinyl Chloride 05/25/23 12:392.170.157<0.157µg/m3o-Xylene 05/25/23 12:395.650.217<0.217µg/m3m,p-Xylene 05/25/23 12:394-Bromofluorobenzene (S)91.3 70-130 LCS-V33771Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 11413.611.9µg/m3Acetone 70-130 10416.616.0µg/m3Benzene 70-130 11429.625.9µg/m3Benzyl Chloride 70-130 98.232.933.5µg/m3Bromodichloromethane 70-130 94.148.751.7µg/m3Bromoform 70-130 11923.119.4µg/m3Bromomethane 70-130 11412.611.1µg/m31,3-Butadiene 70-130 11618.115.6µg/m3Carbon Disulfide 70-130 95.230.031.5µg/m3Carbon Tetrachloride 70-130 11326.123.0µg/m3Chlorobenzene 70-130 10143.242.6µg/m3Chlorodibromomethane 70-130 12316.213.2µg/m3Chloroethane 70-130 10625.824.4µg/m3Chloroform 70-130 11712.110.3µg/m3Chloromethane 70-130 10718.417.2µg/m3Cyclohexane 70-130 Page 8 of 11Date:05/30/2023 03:29 PM Page 43 of 50 Quality Control Data 23-139-0102Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM-003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V33777QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V33771 LCS-V33771Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 11243.038.4µg/m31,2-Dibromoethane 70-130 12136.330.1µg/m31,2-Dichlorobenzene 70-130 12136.330.1µg/m31,3-Dichlorobenzene 70-130 12136.430.1µg/m31,4-Dichlorobenzene 70-130 11528.424.7µg/m3Dichlorodifluoromethane 70-130 11723.620.2µg/m31,1-Dichloroethane 70-130 10421.120.2µg/m31,2-Dichloroethane 70-130 11623.019.8µg/m31,1-Dichloroethene 70-130 11522.719.8µg/m3cis-1,2-Dichloroethene 70-130 11723.119.8µg/m3trans-1,2-Dichloroethene 70-130 10424.123.1µg/m31,2-Dichloropropane 70-130 11841.335.0µg/m31,2-Dichlorotetrafluoroethane 70-130 10223.122.7µg/m3cis-1,3-Dichloropropene 70-130 10223.122.7µg/m3trans-1,3-Dichloropropene 70-130 10318.618.0µg/m31,4-Dioxane 70-130 11420.518.0µg/m3Ethyl Acetate 70-130 11023.921.7µg/m3Ethylbenzene 70-130 11327.924.6µg/m34-Ethyltoluene 70-130 11644.438.3µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 70-130 97.520.020.5µg/m3Heptane 70-130 11360.153.3µg/m3Hexachlorobutadiene 70-130 11620.417.6µg/m3n-Hexane 70-130 10922.320.5µg/m32-Hexanone 70-130 10713.112.3µg/m3Isopropyl Alcohol 70-130 11016.314.8µg/m3Methyl Ethyl Ketone (MEK)70-130 11119.918.0µg/m3Methyl tert-butyl ether (MTBE)70-130 10120.820.5µg/m34-Methyl-2-Pentanone 70-130 Page 9 of 11Date:05/30/2023 03:29 PM Page 44 of 50 Quality Control Data 23-139-0102Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM-003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V33777QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V33771 LCS-V33771Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 12221.317.4µg/m3Methylene Chloride 70-130 12733.426.2µg/m3Naphthalene 70-130 1159.948.61µg/m3Propene 70-130 10823.121.3µg/m3Styrene 70-130 11138.134.3µg/m31,1,2,2-Tetrachloroethane 70-130 10334.833.9µg/m3 70-130 10114.914.7µg/m3 70-130 10119.018.8µg/m3 70-130 12747.137.1µg/m31,2,4-Trichlorobenzene 70-130 99.627.227.3µg/m31,1,1-Trichloroethane 70-130 11230.727.3µg/m31,1,2-Trichloroethane 70-130 10227.526.9µg/m3 70-130 11431.928.1µg/m3 70-130 11528.424.6µg/m31,2,4-Trimethylbenzene 70-130 11127.424.6µg/m31,3,5-Trimethylbenzene 70-130 10318.217.6µg/m3Vinyl Acetate 70-130 12015.312.8µg/m3Vinyl Chloride 70-130 11124.021.7µg/m3o-Xylene 70-130 10445.343.4µg/m3m,p-Xylene 70-130 93.04-Bromofluorobenzene (S)70-130 Page 10 of 11Date:05/30/2023 03:29 PM Page 45 of 50 Quality Control Data 23-139-0102Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM-003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V33785QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V33784 Associated Lab Samples: 96678 LRB-V33784 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 05/26/23 12:174.750.202<0.202µg/m3Acetone 05/26/23 12:174-Bromofluorobenzene (S)90.2 70-130 LCS-V33784Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 11413.611.9µg/m3Acetone 70-130 93.54-Bromofluorobenzene (S)70-130 Page 11 of 11Date:05/30/2023 03:29 PM Page 46 of 50 Fed Ex UPS US Postal Client Lab Courier Other : Shipment Receipt Form Customer Number: Customer Name: Report Number:23-139-0102 Hart & Hickman (Charlotte) 01102 Shipping Method Shipping container/cooler uncompromised? Thermometer ID:N/A Chain of Custody (COC) present?Yes No Yes No Not Present Yes No Not Present Yes No COC agrees with sample label(s)?Yes No COC properly completed Samples in proper containers? Sample containers intact? Sufficient sample volume for indicated test(s)? All samples received within holding time? Cooler temperature in compliance? Yes No Yes No Yes No Yes No Yes No Yes NoCooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. Yes No Yes No N/A Yes No N/A Yes No N/ASoil VOA method 5035 – compliance criteria met Water - Sample containers properly preserved Water - VOA vials free of headspace Yes No N/A Trip Blanks received with VOAs Low concentration EnCore samplers (48 hr) High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d) High concentration container (48 hr) Custody seals intact on shipping container/cooler? Custody seals intact on sample bottles? Number of coolers/boxes received Yes No 1 Signature:Angela D Overcash Date & Time:05/19/2023 16:47:52 Special precautions or instructions included? Comments: Page 47 of 50 Pa g e 4 8 o f 5 0 Pa g e 4 9 o f 5 0 Pa g e 5 0 o f 5 0   Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.   1/31/2024 Hart & Hickman (Charlotte) Matt Vawter 2923 South Tryon St. Ste 100 Charlotte, NC, 28203 Ref: Analytical Testing Lab Report Number: 24-019-0015 Client Project Description: PAM.003 Dear Matt Vawter: Waypoint Analytical, LLC (Charlotte) received sample(s) on 1/19/2024 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Angela D Overcash Senior Project Manager Page 1 of 66 Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date 07/31/202437735State ProgramNorth Carolina 12/31/2024402State ProgramNorth Carolina 07/31/202499012State ProgramSouth Carolina 12/31/202399012State ProgramSouth Carolina Page 1 of 1 00016/24-019-0015 Page 2 of 66 Report Number: Sample Summary Table Client Project Description: 24-019-0015 PAM.003 Lab No Client Sample ID Matrix Date Collected Date Received 01/18/2024 08:00Air 94745 IAS-P1 01/19/2024 13:01 01/18/2024Air 94746 IAS-DUP 01/19/2024 13:01 01/18/2024 10:15Air 94747 IAS-OFF-1 01/19/2024 13:01 01/18/2024 09:47Air 94748 IAS-1 (UDM)01/19/2024 13:01 01/18/2024 08:31Air 94749 IAS-3 01/19/2024 13:01 01/18/2024 08:39Air 94750 IAS-2 01/19/2024 13:01 01/18/2024 08:50Air 94751 IAS-OFF-2 01/19/2024 13:01 01/18/2024 08:24Air 94752 IAS-1 01/19/2024 13:01 01/18/2024 10:06Air 94753 IAS-3 (UDM)01/19/2024 13:01 01/18/2024 09:58Air 94754 IAS-2 (UDM)01/19/2024 13:01 01/18/2024 09:21Air 94755 IAS-BKG 01/19/2024 13:01 01/18/2024 10:02Air 94756 MP-P1 01/19/2024 13:01 Page 3 of 66 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 24-019-0015 Report Limit Project:PAM.003 V 94745IAS-P1 14.7 01/24/2024 20:53TO-15 Acetone µg/m3 0.202 J1.01 01/24/2024 20:53TO-15 Benzene µg/m3 0.073 J1.29 01/24/2024 20:53TO-15 Carbon Disulfide µg/m3 0.060 J0.823 01/24/2024 20:53TO-15 Chloromethane µg/m3 0.067 2.79 01/24/2024 20:53TO-15 Dichlorodifluoromethane µg/m3 0.134 J0.486 01/24/2024 20:53TO-15 Ethylbenzene µg/m3 0.106 J0.574 01/24/2024 20:53TO-15 1,1,2-Trichloro-1,2,2-trifluoroethane µg/m3 0.561 J0.459 01/24/2024 20:53TO-15 Heptane µg/m3 0.143 J0.687 01/24/2024 20:53TO-15 n-Hexane µg/m3 0.047 JB3.97 01/24/2024 20:53TO-15 Isopropyl Alcohol µg/m3 0.139 J1.38 01/24/2024 20:53TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J1.54 01/24/2024 20:53TO-15 Methylene Chloride µg/m3 0.488 J0.392 01/24/2024 20:53TO-15 Tetrahydrofuran µg/m3 0.107 2.00 01/24/2024 20:53TO-15 Toluene µg/m3 0.090 J1.63 01/24/2024 20:53TO-15 Trichlorofluoromethane µg/m3 0.130 J0.625 01/24/2024 20:53TO-15 o-Xylene µg/m3 0.157 J1.83 01/24/2024 20:53TO-15 m,p-Xylene µg/m3 0.217 J2.46 01/24/2024 20:53TO-15 Xylene (Total)µg/m3 0.157 V 94746IAS-DUP 14.3 01/24/2024 21:42TO-15 Acetone µg/m3 0.202 J1.02 01/24/2024 21:42TO-15 Benzene µg/m3 0.073 J0.750 01/24/2024 21:42TO-15 Carbon Disulfide µg/m3 0.060 J0.797 01/24/2024 21:42TO-15 Chloromethane µg/m3 0.067 2.78 01/24/2024 21:42TO-15 Dichlorodifluoromethane µg/m3 0.134 J0.590 01/24/2024 21:42TO-15 Ethylbenzene µg/m3 0.106 J0.581 01/24/2024 21:42TO-15 Heptane µg/m3 0.143 J0.662 01/24/2024 21:42TO-15 n-Hexane µg/m3 0.047 JB3.92 01/24/2024 21:42TO-15 Isopropyl Alcohol µg/m3 0.139 J1.38 01/24/2024 21:42TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J1.32 01/24/2024 21:42TO-15 Methylene Chloride µg/m3 0.488 J0.406 01/24/2024 21:42TO-15 Tetrahydrofuran µg/m3 0.107 2.16 01/24/2024 21:42TO-15 Toluene µg/m3 0.090 J1.58 01/24/2024 21:42TO-15 Trichlorofluoromethane µg/m3 0.130 J0.772 01/24/2024 21:42TO-15 o-Xylene µg/m3 0.157 J2.21 01/24/2024 21:42TO-15 m,p-Xylene µg/m3 0.217 J2.98 01/24/2024 21:42TO-15 Xylene (Total)µg/m3 0.157 Page 4 of 66 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 24-019-0015 Report Limit Project:PAM.003 V 94747IAS-OFF-1 34.8 01/24/2024 22:34TO-15 Acetone µg/m3 0.202 J1.07 01/24/2024 22:34TO-15 Benzene µg/m3 0.073 J1.69 01/24/2024 22:34TO-15 Carbon Disulfide µg/m3 0.060 J0.811 01/24/2024 22:34TO-15 Chloromethane µg/m3 0.067 13.8 01/24/2024 22:34TO-15 Cyclohexane µg/m3 0.161 2.84 01/24/2024 22:34TO-15 Dichlorodifluoromethane µg/m3 0.134 305 01/30/2024 18:33TO-15 Ethanol µg/m3 3.38 J1.16 01/24/2024 22:34TO-15 Ethylbenzene µg/m3 0.106 J1.51 01/24/2024 22:34TO-15 4-Ethyltoluene µg/m3 0.128 13.6 01/24/2024 22:34TO-15 Heptane µg/m3 0.143 J0.867 01/24/2024 22:34TO-15 n-Hexane µg/m3 0.047 44.2 01/24/2024 22:34TO-15 Isopropyl Alcohol µg/m3 0.139 3.74 01/24/2024 22:34TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 3.76 01/24/2024 22:34TO-15 Methylene Chloride µg/m3 0.488 J0.877 01/24/2024 22:34TO-15 Styrene µg/m3 0.124 1.74 01/24/2024 22:34TO-15 Tetrahydrofuran µg/m3 0.107 5.10 01/24/2024 22:34TO-15 Toluene µg/m3 0.090 J1.73 01/24/2024 22:34TO-15 Trichlorofluoromethane µg/m3 0.130 4.44 01/24/2024 22:34TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J1.75 01/24/2024 22:34TO-15 1,3,5-Trimethylbenzene µg/m3 0.236 J1.53 01/24/2024 22:34TO-15 o-Xylene µg/m3 0.157 J4.52 01/24/2024 22:34TO-15 m,p-Xylene µg/m3 0.217 V 94748IAS-1 (UDM) 11.6 01/24/2024 23:23TO-15 Acetone µg/m3 0.202 J0.856 01/24/2024 23:23TO-15 Benzene µg/m3 0.073 J1.08 01/24/2024 23:23TO-15 Carbon Disulfide µg/m3 0.060 J0.585 01/24/2024 23:23TO-15 Chloroform µg/m3 0.086 J0.858 01/24/2024 23:23TO-15 Chloromethane µg/m3 0.067 2.81 01/24/2024 23:23TO-15 Dichlorodifluoromethane µg/m3 0.134 270 01/30/2024 19:10TO-15 Ethanol µg/m3 3.38 J0.781 01/24/2024 23:23TO-15 Ethylbenzene µg/m3 0.106 J0.774 01/24/2024 23:23TO-15 Heptane µg/m3 0.143 J0.637 01/24/2024 23:23TO-15 n-Hexane µg/m3 0.047 B6.86 01/24/2024 23:23TO-15 Isopropyl Alcohol µg/m3 0.139 1.48 01/24/2024 23:23TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J1.67 01/24/2024 23:23TO-15 Methylene Chloride µg/m3 0.488 Page 5 of 66 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 24-019-0015 Report Limit Project:PAM.003 V 94748IAS-1 (UDM) J1.19 01/24/2024 23:23TO-15 Tetrachloroethene µg/m3 0.181 J0.763 01/24/2024 23:23TO-15 Tetrahydrofuran µg/m3 0.107 2.14 01/24/2024 23:23TO-15 Toluene µg/m3 0.090 J1.63 01/24/2024 23:23TO-15 Trichlorofluoromethane µg/m3 0.130 J0.683 01/24/2024 23:23TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J1.05 01/24/2024 23:23TO-15 o-Xylene µg/m3 0.157 J3.30 01/24/2024 23:23TO-15 m,p-Xylene µg/m3 0.217 V 94749IAS-3 B10.6 01/25/2024 20:42TO-15 Acetone µg/m3 0.202 J1.09 01/25/2024 20:42TO-15 Benzene µg/m3 0.073 J0.579 01/25/2024 20:42TO-15 Carbon Disulfide µg/m3 0.060 J1.62 01/25/2024 20:42TO-15 Chloroform µg/m3 0.086 J0.852 01/25/2024 20:42TO-15 Chloromethane µg/m3 0.067 2.84 01/25/2024 20:42TO-15 Dichlorodifluoromethane µg/m3 0.134 236 01/30/2024 19:46TO-15 Ethanol µg/m3 3.38 J0.451 01/25/2024 20:42TO-15 Ethylbenzene µg/m3 0.106 J0.511 01/25/2024 20:42TO-15 4-Ethyltoluene µg/m3 0.128 J0.557 01/25/2024 20:42TO-15 Heptane µg/m3 0.143 J0.870 01/25/2024 20:42TO-15 n-Hexane µg/m3 0.047 54.4 01/25/2024 20:42TO-15 Isopropyl Alcohol µg/m3 0.139 J1.15 01/25/2024 20:42TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 1.82 01/25/2024 20:42TO-15 Methylene Chloride µg/m3 0.488 J0.383 01/25/2024 20:42TO-15 Styrene µg/m3 0.124 J1.18 01/25/2024 20:42TO-15 Tetrachloroethene µg/m3 0.181 J0.271 01/25/2024 20:42TO-15 Tetrahydrofuran µg/m3 0.107 2.69 01/25/2024 20:42TO-15 Toluene µg/m3 0.090 J1.71 01/25/2024 20:42TO-15 Trichlorofluoromethane µg/m3 0.130 3.68 01/25/2024 20:42TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J1.17 01/25/2024 20:42TO-15 1,3,5-Trimethylbenzene µg/m3 0.236 J0.521 01/25/2024 20:42TO-15 o-Xylene µg/m3 0.157 J1.23 01/25/2024 20:42TO-15 m,p-Xylene µg/m3 0.217 V 94750IAS-2 16.4 01/25/2024 21:34TO-15 Acetone µg/m3 0.202 2.26 01/25/2024 21:34TO-15 Benzene µg/m3 0.073 J0.666 01/25/2024 21:34TO-15 Carbon Disulfide µg/m3 0.060 18.8 01/25/2024 21:34TO-15 Chloroform µg/m3 0.086 Page 6 of 66 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 24-019-0015 Report Limit Project:PAM.003 V 94750IAS-2 J0.900 01/25/2024 21:34TO-15 Chloromethane µg/m3 0.067 2.84 01/25/2024 21:34TO-15 Dichlorodifluoromethane µg/m3 0.134 1230 01/30/2024 20:23TO-15 Ethanol µg/m3 3.38 J0.638 01/25/2024 21:34TO-15 Ethylbenzene µg/m3 0.106 J0.486 01/25/2024 21:34TO-15 4-Ethyltoluene µg/m3 0.128 J1.06 01/25/2024 21:34TO-15 Heptane µg/m3 0.143 J0.909 01/25/2024 21:34TO-15 n-Hexane µg/m3 0.047 44.0 01/25/2024 21:34TO-15 Isopropyl Alcohol µg/m3 0.139 2.00 01/25/2024 21:34TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 2.07 01/25/2024 21:34TO-15 Methylene Chloride µg/m3 0.488 J0.724 01/25/2024 21:34TO-15 Styrene µg/m3 0.124 J0.698 01/25/2024 21:34TO-15 Tetrachloroethene µg/m3 0.181 J0.480 01/25/2024 21:34TO-15 Tetrahydrofuran µg/m3 0.107 2.90 01/25/2024 21:34TO-15 Toluene µg/m3 0.090 J1.86 01/25/2024 21:34TO-15 Trichlorofluoromethane µg/m3 0.130 3.98 01/25/2024 21:34TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J1.32 01/25/2024 21:34TO-15 1,3,5-Trimethylbenzene µg/m3 0.236 J0.833 01/25/2024 21:34TO-15 o-Xylene µg/m3 0.157 J2.33 01/25/2024 21:34TO-15 m,p-Xylene µg/m3 0.217 V 94751IAS-OFF-2 53.1 01/25/2024 22:22TO-15 Acetone µg/m3 0.202 J1.33 01/25/2024 22:22TO-15 Benzene µg/m3 0.073 J1.09 01/25/2024 22:22TO-15 Carbon Disulfide µg/m3 0.060 J0.825 01/25/2024 22:22TO-15 Chloromethane µg/m3 0.067 6.04 01/25/2024 22:22TO-15 Cyclohexane µg/m3 0.161 2.86 01/25/2024 22:22TO-15 Dichlorodifluoromethane µg/m3 0.134 206 01/30/2024 21:00TO-15 Ethanol µg/m3 3.38 J1.21 01/25/2024 22:22TO-15 Ethylbenzene µg/m3 0.106 2.83 01/25/2024 22:22TO-15 4-Ethyltoluene µg/m3 0.128 4.54 01/25/2024 22:22TO-15 Heptane µg/m3 0.143 J0.905 01/25/2024 22:22TO-15 n-Hexane µg/m3 0.047 31.2 01/25/2024 22:22TO-15 Isopropyl Alcohol µg/m3 0.139 4.14 01/25/2024 22:22TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 2.83 01/25/2024 22:22TO-15 4-Methyl-2-Pentanone µg/m3 0.121 1.98 01/25/2024 22:22TO-15 Methylene Chloride µg/m3 0.488 4.70 01/25/2024 22:22TO-15 Naphthalene µg/m3 0.183 Page 7 of 66 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 24-019-0015 Report Limit Project:PAM.003 V 94751IAS-OFF-2 J0.894 01/25/2024 22:22TO-15 Styrene µg/m3 0.124 J0.813 01/25/2024 22:22TO-15 Tetrachloroethene µg/m3 0.181 2.15 01/25/2024 22:22TO-15 Tetrahydrofuran µg/m3 0.107 6.76 01/25/2024 22:22TO-15 Toluene µg/m3 0.090 J1.66 01/25/2024 22:22TO-15 Trichlorofluoromethane µg/m3 0.130 8.62 01/25/2024 22:22TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J2.30 01/25/2024 22:22TO-15 1,3,5-Trimethylbenzene µg/m3 0.236 J1.80 01/25/2024 22:22TO-15 o-Xylene µg/m3 0.157 J5.41 01/25/2024 22:22TO-15 m,p-Xylene µg/m3 0.217 V 94752IAS-1 10.9 01/25/2024 23:10TO-15 Acetone µg/m3 0.202 J0.916 01/25/2024 23:10TO-15 Benzene µg/m3 0.073 J0.538 01/25/2024 23:10TO-15 Carbon Disulfide µg/m3 0.060 J1.27 01/25/2024 23:10TO-15 Chloroform µg/m3 0.086 J0.885 01/25/2024 23:10TO-15 Chloromethane µg/m3 0.067 2.76 01/25/2024 23:10TO-15 Dichlorodifluoromethane µg/m3 0.134 169 01/30/2024 21:36TO-15 Ethanol µg/m3 3.38 J0.777 01/25/2024 23:10TO-15 Ethylbenzene µg/m3 0.106 J0.545 01/25/2024 23:10TO-15 4-Ethyltoluene µg/m3 0.128 J0.495 01/25/2024 23:10TO-15 Heptane µg/m3 0.143 J0.666 01/25/2024 23:10TO-15 n-Hexane µg/m3 0.047 26.8 01/25/2024 23:10TO-15 Isopropyl Alcohol µg/m3 0.139 J1.19 01/25/2024 23:10TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J1.40 01/25/2024 23:10TO-15 Methylene Chloride µg/m3 0.488 J0.438 01/25/2024 23:10TO-15 Styrene µg/m3 0.124 J1.57 01/25/2024 23:10TO-15 Tetrachloroethene µg/m3 0.181 J0.327 01/25/2024 23:10TO-15 Tetrahydrofuran µg/m3 0.107 1.91 01/25/2024 23:10TO-15 Toluene µg/m3 0.090 J1.69 01/25/2024 23:10TO-15 Trichlorofluoromethane µg/m3 0.130 3.47 01/25/2024 23:10TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J1.08 01/25/2024 23:10TO-15 1,3,5-Trimethylbenzene µg/m3 0.236 J1.04 01/25/2024 23:10TO-15 o-Xylene µg/m3 0.157 J3.26 01/25/2024 23:10TO-15 m,p-Xylene µg/m3 0.217 V 94753IAS-3 (UDM) 12.9 01/26/2024 00:01TO-15 Acetone µg/m3 0.202 J0.865 01/26/2024 00:01TO-15 Benzene µg/m3 0.073 Page 8 of 66 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 24-019-0015 Report Limit Project:PAM.003 V 94753IAS-3 (UDM) J0.974 01/26/2024 00:01TO-15 Carbon Disulfide µg/m3 0.060 J1.36 01/26/2024 00:01TO-15 Chloroform µg/m3 0.086 J0.813 01/26/2024 00:01TO-15 Chloromethane µg/m3 0.067 2.76 01/26/2024 00:01TO-15 Dichlorodifluoromethane µg/m3 0.134 353 01/30/2024 22:13TO-15 Ethanol µg/m3 3.38 J0.373 01/26/2024 00:01TO-15 Ethylbenzene µg/m3 0.106 J0.922 01/26/2024 00:01TO-15 Heptane µg/m3 0.143 J0.637 01/26/2024 00:01TO-15 n-Hexane µg/m3 0.047 B10.1 01/26/2024 00:01TO-15 Isopropyl Alcohol µg/m3 0.139 1.55 01/26/2024 00:01TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J1.59 01/26/2024 00:01TO-15 Methylene Chloride µg/m3 0.488 J2.12 01/26/2024 00:01TO-15 Tetrachloroethene µg/m3 0.181 J0.917 01/26/2024 00:01TO-15 Tetrahydrofuran µg/m3 0.107 2.65 01/26/2024 00:01TO-15 Toluene µg/m3 0.090 J1.62 01/26/2024 00:01TO-15 Trichlorofluoromethane µg/m3 0.130 J1.25 01/26/2024 00:01TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J0.447 01/26/2024 00:01TO-15 1,3,5-Trimethylbenzene µg/m3 0.236 J0.455 01/26/2024 00:01TO-15 o-Xylene µg/m3 0.157 J1.20 01/26/2024 00:01TO-15 m,p-Xylene µg/m3 0.217 V 94754IAS-2 (UDM) B5.92 01/26/2024 00:48TO-15 Acetone µg/m3 0.202 J0.721 01/26/2024 00:48TO-15 Benzene µg/m3 0.073 J1.05 01/26/2024 00:48TO-15 Carbon Disulfide µg/m3 0.060 J0.624 01/26/2024 00:48TO-15 Chloroform µg/m3 0.086 J0.877 01/26/2024 00:48TO-15 Chloromethane µg/m3 0.067 2.77 01/26/2024 00:48TO-15 Dichlorodifluoromethane µg/m3 0.134 12.9 01/26/2024 00:48TO-15 Ethanol µg/m3 0.169 J0.360 01/26/2024 00:48TO-15 Heptane µg/m3 0.143 J0.475 01/26/2024 00:48TO-15 n-Hexane µg/m3 0.047 JB3.44 01/26/2024 00:48TO-15 Isopropyl Alcohol µg/m3 0.139 J0.961 01/26/2024 00:48TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J1.42 01/26/2024 00:48TO-15 Methylene Chloride µg/m3 0.488 J0.645 01/26/2024 00:48TO-15 Tetrahydrofuran µg/m3 0.107 J1.46 01/26/2024 00:48TO-15 Toluene µg/m3 0.090 J1.55 01/26/2024 00:48TO-15 Trichlorofluoromethane µg/m3 0.130 J0.308 01/26/2024 00:48TO-15 o-Xylene µg/m3 0.157 Page 9 of 66 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 24-019-0015 Report Limit Project:PAM.003 V 94754IAS-2 (UDM) J0.746 01/26/2024 00:48TO-15 m,p-Xylene µg/m3 0.217 V 94755IAS-BKG B8.25 01/26/2024 01:36TO-15 Acetone µg/m3 0.202 J0.888 01/26/2024 01:36TO-15 Benzene µg/m3 0.073 J0.890 01/26/2024 01:36TO-15 Carbon Disulfide µg/m3 0.060 J0.836 01/26/2024 01:36TO-15 Chloromethane µg/m3 0.067 2.80 01/26/2024 01:36TO-15 Dichlorodifluoromethane µg/m3 0.134 J0.343 01/26/2024 01:36TO-15 Ethylbenzene µg/m3 0.106 J0.605 01/26/2024 01:36TO-15 1,1,2-Trichloro-1,2,2-trifluoroethane µg/m3 0.561 J0.454 01/26/2024 01:36TO-15 Heptane µg/m3 0.143 J0.609 01/26/2024 01:36TO-15 n-Hexane µg/m3 0.047 JB3.13 01/26/2024 01:36TO-15 Isopropyl Alcohol µg/m3 0.139 2.90 01/26/2024 01:36TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J1.23 01/26/2024 01:36TO-15 Methylene Chloride µg/m3 0.488 2.83 01/26/2024 01:36TO-15 Tetrahydrofuran µg/m3 0.107 2.08 01/26/2024 01:36TO-15 Toluene µg/m3 0.090 J1.02 01/26/2024 01:36TO-15 Trichloroethene µg/m3 0.199 J1.64 01/26/2024 01:36TO-15 Trichlorofluoromethane µg/m3 0.130 J0.351 01/26/2024 01:36TO-15 o-Xylene µg/m3 0.157 J0.903 01/26/2024 01:36TO-15 m,p-Xylene µg/m3 0.217 J1.25 01/26/2024 01:36TO-15 Xylene (Total)µg/m3 0.157 V 94756MP-P1 B6.79 01/26/2024 14:09TO-15 Acetone µg/m3 0.202 J0.737 01/26/2024 14:09TO-15 Chloroform µg/m3 0.086 13.4 01/26/2024 14:09TO-15 Dichlorodifluoromethane µg/m3 0.134 J0.968 01/26/2024 14:09TO-15 Ethylbenzene µg/m3 0.106 J0.334 01/26/2024 14:09TO-15 n-Hexane µg/m3 0.047 JB2.92 01/26/2024 14:09TO-15 Isopropyl Alcohol µg/m3 0.139 J0.931 01/26/2024 14:09TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J1.46 01/26/2024 14:09TO-15 Methylene Chloride µg/m3 0.488 76.1 01/26/2024 14:09TO-15 Tetrachloroethene µg/m3 0.181 1.57 01/26/2024 14:09TO-15 Tetrahydrofuran µg/m3 0.107 JB0.395 01/26/2024 14:09TO-15 Toluene µg/m3 0.090 J0.932 01/26/2024 14:09TO-15 1,1,1-Trichloroethane µg/m3 0.144 J1.74 01/26/2024 14:09TO-15 Trichlorofluoromethane µg/m3 0.130 J1.53 01/26/2024 14:09TO-15 o-Xylene µg/m3 0.157 Page 10 of 66 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 24-019-0015 Report Limit Project:PAM.003 V 94756MP-P1 J4.52 01/26/2024 14:09TO-15 m,p-Xylene µg/m3 0.217 J6.05 01/26/2024 14:09TO-15 Xylene (Total)µg/m3 0.157 Page 11 of 66   Client: Hart & Hickman (Charlotte) CASE NARRATIVE Project: PAM.003 Lab Report Number: 24-019-0015 Date: 1/31/2024 Report Comments Revised Report: Revision 1 Sample reporting lists have been updated. Page 12 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-P1 94745 Matrix: 1/18/2024 8:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/24/24 09:00 14.7 µg/m3 0.202 4.75Acetone 1 01/24/24 20:53 V42735ENM 1.01 J µg/m3 0.073 1.60Benzene 1 01/24/24 20:53 V42735ENM <0.147 µg/m3 0.147 10.4Benzyl Chloride 1 01/24/24 20:53 V42735ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 01/24/24 20:53 V42735ENM <0.153 µg/m3 0.153 5.17Bromoform 1 01/24/24 20:53 V42735ENM <0.115 µg/m3 0.115 1.94Bromomethane 1 01/24/24 20:53 V42735ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 01/24/24 20:53 V42735ENM 1.29 J µg/m3 0.060 6.23Carbon Disulfide 1 01/24/24 20:53 V42735ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 01/24/24 20:53 V42735ENM <0.107 µg/m3 0.107 2.30Chlorobenzene 1 01/24/24 20:53 V42735ENM <0.208 µg/m3 0.208 4.26Chlorodibromomethane 1 01/24/24 20:53 V42735ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 01/24/24 20:53 V42735ENM <0.086 µg/m3 0.086 2.44Chloroform 1 01/24/24 20:53 V42735ENM 0.823 J µg/m3 0.067 1.03Chloromethane 1 01/24/24 20:53 V42735ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 01/24/24 20:53 V42735ENM <0.151 µg/m3 0.151 3.841,2-Dibromoethane 1 01/24/24 20:53 V42735ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 01/24/24 20:53 V42735ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 01/24/24 20:53 V42735ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 01/24/24 20:53 V42735ENM 2.79 µg/m3 0.134 2.47Dichlorodifluoromethane 1 01/24/24 20:53 V42735ENM <0.101 µg/m3 0.101 2.021,1-Dichloroethane 1 01/24/24 20:53 V42735ENM <0.129 µg/m3 0.129 2.021,2-Dichloroethane 1 01/24/24 20:53 V42735ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 13 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-P1 94745 Matrix: 1/18/2024 8:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/24/24 09:00 <0.107 µg/m3 0.107 1.981,1-Dichloroethene 1 01/24/24 20:53 V42735ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 01/24/24 20:53 V42735ENM <0.108 µg/m3 0.108 1.98trans-1,2-Dichloroethene 1 01/24/24 20:53 V42735ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 01/24/24 20:53 V42735ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 01/24/24 20:53 V42735ENM <0.178 µg/m3 0.178 2.27cis-1,3-Dichloropropene 1 01/24/24 20:53 V42735ENM <0.178 µg/m3 0.178 2.27trans-1,3-Dichloropropene 1 01/24/24 20:53 V42735ENM <0.435 µg/m3 0.435 1.801,4-Dioxane 1 01/24/24 20:53 V42735ENM <0.136 µg/m3 0.136 1.80Ethyl Acetate 1 01/24/24 20:53 V42735ENM 0.486 J µg/m3 0.106 2.17Ethylbenzene 1 01/24/24 20:53 V42735ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 01/24/24 20:53 V42735ENM 0.574 J µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 01/24/24 20:53 V42735ENM 0.459 J µg/m3 0.143 2.05Heptane 1 01/24/24 20:53 V42735ENM <0.330 µg/m3 0.330 5.33Hexachlorobutadiene 1 01/24/24 20:53 V42735ENM 0.687 J µg/m3 0.047 1.76n-Hexane 1 01/24/24 20:53 V42735ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 01/24/24 20:53 V42735ENM 3.97 JB µg/m3 0.139 4.92Isopropyl Alcohol 1 01/24/24 20:53 V42735ENM 1.38 J µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 01/24/24 20:53 V42735ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 01/24/24 20:53 V42735ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 01/24/24 20:53 V42735ENM 1.54 J µg/m3 0.488 1.74Methylene Chloride 1 01/24/24 20:53 V42735ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 01/24/24 20:53 V42735ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 14 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-P1 94745 Matrix: 1/18/2024 8:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/24/24 09:00 <0.242 µg/m3 0.242 0.860Propene 1 01/24/24 20:53 V42735ENM <0.124 µg/m3 0.124 2.13Styrene 1 01/24/24 20:53 V42735ENM <0.104 µg/m3 0.104 3.431,1,2,2-Tetrachloroethane 1 01/24/24 20:53 V42735ENM <0.181 µg/m3 0.181 3.39 1 01/24/24 20:53 V42735ENM 0.392 J µg/m3 0.107 1.47 1 01/24/24 20:53 V42735ENM 2.00 µg/m3 0.090 1.88 1 01/24/24 20:53 V42735ENM <0.209 µg/m3 0.209 3.711,2,4-Trichlorobenzene 1 01/24/24 20:53 V42735ENM <0.144 µg/m3 0.144 2.731,1,1-Trichloroethane 1 01/24/24 20:53 V42735ENM <0.087 µg/m3 0.087 2.731,1,2-Trichloroethane 1 01/24/24 20:53 V42735ENM <0.199 µg/m3 0.199 2.15 1 01/24/24 20:53 V42735ENM 1.63 J µg/m3 0.130 2.81 1 01/24/24 20:53 V42735ENM <0.110 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 01/24/24 20:53 V42735ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 01/24/24 20:53 V42735ENM <0.224 µg/m3 0.224 1.76Vinyl Acetate 1 01/24/24 20:53 V42735ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 01/24/24 20:53 V42735ENM 0.625 J µg/m3 0.157 2.17o-Xylene 1 01/24/24 20:53 V42735ENM 1.83 J µg/m3 0.217 5.65m,p-Xylene 1 01/24/24 20:53 V42735ENM 2.46 J µg/m3 0.157 2.17Xylene (Total)1 01/24/24 20:53 V42735 Surrogate: 4-Bromofluorobenzene Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 15 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-DUP 94746 Matrix: 1/18/2024 0:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/24/24 09:00 14.3 µg/m3 0.202 4.75Acetone 1 01/24/24 21:42 V42735ENM 1.02 J µg/m3 0.073 1.60Benzene 1 01/24/24 21:42 V42735ENM <0.147 µg/m3 0.147 10.4Benzyl Chloride 1 01/24/24 21:42 V42735ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 01/24/24 21:42 V42735ENM <0.153 µg/m3 0.153 5.17Bromoform 1 01/24/24 21:42 V42735ENM <0.115 µg/m3 0.115 1.94Bromomethane 1 01/24/24 21:42 V42735ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 01/24/24 21:42 V42735ENM 0.750 J µg/m3 0.060 6.23Carbon Disulfide 1 01/24/24 21:42 V42735ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 01/24/24 21:42 V42735ENM <0.107 µg/m3 0.107 2.30Chlorobenzene 1 01/24/24 21:42 V42735ENM <0.208 µg/m3 0.208 4.26Chlorodibromomethane 1 01/24/24 21:42 V42735ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 01/24/24 21:42 V42735ENM <0.086 µg/m3 0.086 2.44Chloroform 1 01/24/24 21:42 V42735ENM 0.797 J µg/m3 0.067 1.03Chloromethane 1 01/24/24 21:42 V42735ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 01/24/24 21:42 V42735ENM <0.151 µg/m3 0.151 3.841,2-Dibromoethane 1 01/24/24 21:42 V42735ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 01/24/24 21:42 V42735ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 01/24/24 21:42 V42735ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 01/24/24 21:42 V42735ENM 2.78 µg/m3 0.134 2.47Dichlorodifluoromethane 1 01/24/24 21:42 V42735ENM <0.101 µg/m3 0.101 2.021,1-Dichloroethane 1 01/24/24 21:42 V42735ENM <0.129 µg/m3 0.129 2.021,2-Dichloroethane 1 01/24/24 21:42 V42735ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 16 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-DUP 94746 Matrix: 1/18/2024 0:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/24/24 09:00 <0.107 µg/m3 0.107 1.981,1-Dichloroethene 1 01/24/24 21:42 V42735ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 01/24/24 21:42 V42735ENM <0.108 µg/m3 0.108 1.98trans-1,2-Dichloroethene 1 01/24/24 21:42 V42735ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 01/24/24 21:42 V42735ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 01/24/24 21:42 V42735ENM <0.178 µg/m3 0.178 2.27cis-1,3-Dichloropropene 1 01/24/24 21:42 V42735ENM <0.178 µg/m3 0.178 2.27trans-1,3-Dichloropropene 1 01/24/24 21:42 V42735ENM <0.435 µg/m3 0.435 1.801,4-Dioxane 1 01/24/24 21:42 V42735ENM <0.136 µg/m3 0.136 1.80Ethyl Acetate 1 01/24/24 21:42 V42735ENM 0.590 J µg/m3 0.106 2.17Ethylbenzene 1 01/24/24 21:42 V42735ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 01/24/24 21:42 V42735ENM <0.561 µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 01/24/24 21:42 V42735ENM 0.581 J µg/m3 0.143 2.05Heptane 1 01/24/24 21:42 V42735ENM <0.330 µg/m3 0.330 5.33Hexachlorobutadiene 1 01/24/24 21:42 V42735ENM 0.662 J µg/m3 0.047 1.76n-Hexane 1 01/24/24 21:42 V42735ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 01/24/24 21:42 V42735ENM 3.92 JB µg/m3 0.139 4.92Isopropyl Alcohol 1 01/24/24 21:42 V42735ENM 1.38 J µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 01/24/24 21:42 V42735ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 01/24/24 21:42 V42735ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 01/24/24 21:42 V42735ENM 1.32 J µg/m3 0.488 1.74Methylene Chloride 1 01/24/24 21:42 V42735ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 01/24/24 21:42 V42735ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 17 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-DUP 94746 Matrix: 1/18/2024 0:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/24/24 09:00 <0.242 µg/m3 0.242 0.860Propene 1 01/24/24 21:42 V42735ENM <0.124 µg/m3 0.124 2.13Styrene 1 01/24/24 21:42 V42735ENM <0.104 µg/m3 0.104 3.431,1,2,2-Tetrachloroethane 1 01/24/24 21:42 V42735ENM <0.181 µg/m3 0.181 3.39 1 01/24/24 21:42 V42735ENM 0.406 J µg/m3 0.107 1.47 1 01/24/24 21:42 V42735ENM 2.16 µg/m3 0.090 1.88 1 01/24/24 21:42 V42735ENM <0.209 µg/m3 0.209 3.711,2,4-Trichlorobenzene 1 01/24/24 21:42 V42735ENM <0.144 µg/m3 0.144 2.731,1,1-Trichloroethane 1 01/24/24 21:42 V42735ENM <0.087 µg/m3 0.087 2.731,1,2-Trichloroethane 1 01/24/24 21:42 V42735ENM <0.199 µg/m3 0.199 2.15 1 01/24/24 21:42 V42735ENM 1.58 J µg/m3 0.130 2.81 1 01/24/24 21:42 V42735ENM <0.110 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 01/24/24 21:42 V42735ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 01/24/24 21:42 V42735ENM <0.224 µg/m3 0.224 1.76Vinyl Acetate 1 01/24/24 21:42 V42735ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 01/24/24 21:42 V42735ENM 0.772 J µg/m3 0.157 2.17o-Xylene 1 01/24/24 21:42 V42735ENM 2.21 J µg/m3 0.217 5.65m,p-Xylene 1 01/24/24 21:42 V42735ENM 2.98 J µg/m3 0.157 2.17Xylene (Total)1 01/24/24 21:42 V42735 Surrogate: 4-Bromofluorobenzene Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 18 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-OFF-1 94747 Matrix: 1/18/2024 10:15 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/24/24 09:00 V42983 01/30/24 07:00 34.8 µg/m3 0.202 4.75Acetone 1 01/24/24 22:34 V42935ENM 1.07 J µg/m3 0.073 1.60Benzene 1 01/24/24 22:34 V42935ENM 1.69 J µg/m3 0.060 6.23Carbon Disulfide 1 01/24/24 22:34 V42935ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 01/24/24 22:34 V42935ENM <0.086 µg/m3 0.086 2.44Chloroform 1 01/24/24 22:34 V42935ENM 0.811 J µg/m3 0.067 1.03Chloromethane 1 01/24/24 22:34 V42935ENM 13.8 µg/m3 0.161 3.44Cyclohexane 1 01/24/24 22:34 V42935ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 01/24/24 22:34 V42935ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 01/24/24 22:34 V42935ENM 2.84 µg/m3 0.134 2.47Dichlorodifluoromethane 1 01/24/24 22:34 V42935ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 01/24/24 22:34 V42935ENM 305 µg/m3 3.38 100Ethanol 20 01/30/24 18:33 V42985ENM 1.16 J µg/m3 0.106 2.17Ethylbenzene 1 01/24/24 22:34 V42935ENM 1.51 J µg/m3 0.128 2.464-Ethyltoluene 1 01/24/24 22:34 V42935ENM 13.6 µg/m3 0.143 2.05Heptane 1 01/24/24 22:34 V42935ENM 0.867 J µg/m3 0.047 1.76n-Hexane 1 01/24/24 22:34 V42935ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 01/24/24 22:34 V42935ENM 44.2 µg/m3 0.139 4.92Isopropyl Alcohol 1 01/24/24 22:34 V42935ENM 3.74 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 01/24/24 22:34 V42935ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 01/24/24 22:34 V42935ENM 3.76 µg/m3 0.488 1.74Methylene Chloride 1 01/24/24 22:34 V42935ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 01/24/24 22:34 V42935ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 19 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-OFF-1 94747 Matrix: 1/18/2024 10:15 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/24/24 09:00 V42983 01/30/24 07:00 <0.242 µg/m3 0.242 0.860Propene 1 01/24/24 22:34 V42935ENM 0.877 J µg/m3 0.124 2.13Styrene 1 01/24/24 22:34 V42935ENM <0.181 µg/m3 0.181 3.39 1 01/24/24 22:34 V42935ENM 1.74 µg/m3 0.107 1.47 1 01/24/24 22:34 V42935ENM 5.10 µg/m3 0.090 1.88 1 01/24/24 22:34 V42935ENM <0.199 µg/m3 0.199 2.15 1 01/24/24 22:34 V42935ENM 1.73 J µg/m3 0.130 2.81 1 01/24/24 22:34 V42935ENM 4.44 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 01/24/24 22:34 V42935ENM 1.75 J µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 01/24/24 22:34 V42935ENM 1.53 J µg/m3 0.157 2.17o-Xylene 1 01/24/24 22:34 V42935ENM 4.52 J µg/m3 0.217 5.65m,p-Xylene 1 01/24/24 22:34 V42935ENM Surrogate: 4-Bromofluorobenzene Surrogate: 4-Bromofluorobenzene Surrogate: 4-Bromofluorobenzene Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 20 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-1 (UDM) 94748 Matrix: 1/18/2024 9:47 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/24/24 09:00 V42983 01/30/24 07:00 11.6 µg/m3 0.202 4.75Acetone 1 01/24/24 23:23 V42935ENM 0.856 J µg/m3 0.073 1.60Benzene 1 01/24/24 23:23 V42935ENM 1.08 J µg/m3 0.060 6.23Carbon Disulfide 1 01/24/24 23:23 V42935ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 01/24/24 23:23 V42935ENM 0.585 J µg/m3 0.086 2.44Chloroform 1 01/24/24 23:23 V42935ENM 0.858 J µg/m3 0.067 1.03Chloromethane 1 01/24/24 23:23 V42935ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 01/24/24 23:23 V42935ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 01/24/24 23:23 V42935ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 01/24/24 23:23 V42935ENM 2.81 µg/m3 0.134 2.47Dichlorodifluoromethane 1 01/24/24 23:23 V42935ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 01/24/24 23:23 V42935ENM 270 µg/m3 3.38 100Ethanol 20 01/30/24 19:10 V42985ENM 0.781 J µg/m3 0.106 2.17Ethylbenzene 1 01/24/24 23:23 V42935ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 01/24/24 23:23 V42935ENM 0.774 J µg/m3 0.143 2.05Heptane 1 01/24/24 23:23 V42935ENM 0.637 J µg/m3 0.047 1.76n-Hexane 1 01/24/24 23:23 V42935ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 01/24/24 23:23 V42935ENM 6.86 B µg/m3 0.139 4.92Isopropyl Alcohol 1 01/24/24 23:23 V42935ENM 1.48 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 01/24/24 23:23 V42935ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 01/24/24 23:23 V42935ENM 1.67 J µg/m3 0.488 1.74Methylene Chloride 1 01/24/24 23:23 V42935ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 01/24/24 23:23 V42935ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 21 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-1 (UDM) 94748 Matrix: 1/18/2024 9:47 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/24/24 09:00 V42983 01/30/24 07:00 <0.242 µg/m3 0.242 0.860Propene 1 01/24/24 23:23 V42935ENM <0.124 µg/m3 0.124 2.13Styrene 1 01/24/24 23:23 V42935ENM 1.19 J µg/m3 0.181 3.39 1 01/24/24 23:23 V42935ENM 0.763 J µg/m3 0.107 1.47 1 01/24/24 23:23 V42935ENM 2.14 µg/m3 0.090 1.88 1 01/24/24 23:23 V42935ENM <0.199 µg/m3 0.199 2.15 1 01/24/24 23:23 V42935ENM 1.63 J µg/m3 0.130 2.81 1 01/24/24 23:23 V42935ENM 0.683 J µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 01/24/24 23:23 V42935ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 01/24/24 23:23 V42935ENM 1.05 J µg/m3 0.157 2.17o-Xylene 1 01/24/24 23:23 V42935ENM 3.30 J µg/m3 0.217 5.65m,p-Xylene 1 01/24/24 23:23 V42935ENM Surrogate: 4-Bromofluorobenzene Surrogate: 4-Bromofluorobenzene Surrogate: 4-Bromofluorobenzene Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 22 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-3 94749 Matrix: 1/18/2024 8:31 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/25/24 09:00 V42983 01/30/24 07:00 10.6 B µg/m3 0.202 4.75Acetone 1 01/25/24 20:42 V42931ENM 1.09 J µg/m3 0.073 1.60Benzene 1 01/25/24 20:42 V42931ENM 0.579 J µg/m3 0.060 6.23Carbon Disulfide 1 01/25/24 20:42 V42931ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 01/25/24 20:42 V42931ENM 1.62 J µg/m3 0.086 2.44Chloroform 1 01/25/24 20:42 V42931ENM 0.852 J µg/m3 0.067 1.03Chloromethane 1 01/25/24 20:42 V42931ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 01/25/24 20:42 V42931ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 01/25/24 20:42 V42931ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 01/25/24 20:42 V42931ENM 2.84 µg/m3 0.134 2.47Dichlorodifluoromethane 1 01/25/24 20:42 V42931ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 01/25/24 20:42 V42931ENM 236 µg/m3 3.38 100Ethanol 20 01/30/24 19:46 V42985ENM 0.451 J µg/m3 0.106 2.17Ethylbenzene 1 01/25/24 20:42 V42931ENM 0.511 J µg/m3 0.128 2.464-Ethyltoluene 1 01/25/24 20:42 V42931ENM 0.557 J µg/m3 0.143 2.05Heptane 1 01/25/24 20:42 V42931ENM 0.870 J µg/m3 0.047 1.76n-Hexane 1 01/25/24 20:42 V42931ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 01/25/24 20:42 V42931ENM 54.4 µg/m3 0.139 4.92Isopropyl Alcohol 1 01/25/24 20:42 V42931ENM 1.15 J µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 01/25/24 20:42 V42931ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 01/25/24 20:42 V42931ENM 1.82 µg/m3 0.488 1.74Methylene Chloride 1 01/25/24 20:42 V42931ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 01/25/24 20:42 V42931ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 23 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-3 94749 Matrix: 1/18/2024 8:31 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/25/24 09:00 V42983 01/30/24 07:00 <0.242 µg/m3 0.242 0.860Propene 1 01/25/24 20:42 V42931ENM 0.383 J µg/m3 0.124 2.13Styrene 1 01/25/24 20:42 V42931ENM 1.18 J µg/m3 0.181 3.39 1 01/25/24 20:42 V42931ENM 0.271 J µg/m3 0.107 1.47 1 01/25/24 20:42 V42931ENM 2.69 µg/m3 0.090 1.88 1 01/25/24 20:42 V42931ENM <0.199 µg/m3 0.199 2.15 1 01/25/24 20:42 V42931ENM 1.71 J µg/m3 0.130 2.81 1 01/25/24 20:42 V42931ENM 3.68 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 01/25/24 20:42 V42931ENM 1.17 J µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 01/25/24 20:42 V42931ENM 0.521 J µg/m3 0.157 2.17o-Xylene 1 01/25/24 20:42 V42931ENM 1.23 J µg/m3 0.217 5.65m,p-Xylene 1 01/25/24 20:42 V42931ENM Surrogate: 4-Bromofluorobenzene Surrogate: 4-Bromofluorobenzene Surrogate: 4-Bromofluorobenzene Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 24 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-2 94750 Matrix: 1/18/2024 8:39 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/25/24 09:00 V42983 01/30/24 07:00 16.4 µg/m3 0.202 4.75Acetone 1 01/25/24 21:34 V42931ENM 2.26 µg/m3 0.073 1.60Benzene 1 01/25/24 21:34 V42931ENM 0.666 J µg/m3 0.060 6.23Carbon Disulfide 1 01/25/24 21:34 V42931ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 01/25/24 21:34 V42931ENM 18.8 µg/m3 0.086 2.44Chloroform 1 01/25/24 21:34 V42931ENM 0.900 J µg/m3 0.067 1.03Chloromethane 1 01/25/24 21:34 V42931ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 01/25/24 21:34 V42931ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 01/25/24 21:34 V42931ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 01/25/24 21:34 V42931ENM 2.84 µg/m3 0.134 2.47Dichlorodifluoromethane 1 01/25/24 21:34 V42931ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 01/25/24 21:34 V42931ENM 1230 µg/m3 3.38 100Ethanol 20 01/30/24 20:23 V42985ENM 0.638 J µg/m3 0.106 2.17Ethylbenzene 1 01/25/24 21:34 V42931ENM 0.486 J µg/m3 0.128 2.464-Ethyltoluene 1 01/25/24 21:34 V42931ENM 1.06 J µg/m3 0.143 2.05Heptane 1 01/25/24 21:34 V42931ENM 0.909 J µg/m3 0.047 1.76n-Hexane 1 01/25/24 21:34 V42931ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 01/25/24 21:34 V42931ENM 44.0 µg/m3 0.139 4.92Isopropyl Alcohol 1 01/25/24 21:34 V42931ENM 2.00 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 01/25/24 21:34 V42931ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 01/25/24 21:34 V42931ENM 2.07 µg/m3 0.488 1.74Methylene Chloride 1 01/25/24 21:34 V42931ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 01/25/24 21:34 V42931ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 25 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-2 94750 Matrix: 1/18/2024 8:39 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/25/24 09:00 V42983 01/30/24 07:00 <0.242 µg/m3 0.242 0.860Propene 1 01/25/24 21:34 V42931ENM 0.724 J µg/m3 0.124 2.13Styrene 1 01/25/24 21:34 V42931ENM 0.698 J µg/m3 0.181 3.39 1 01/25/24 21:34 V42931ENM 0.480 J µg/m3 0.107 1.47 1 01/25/24 21:34 V42931ENM 2.90 µg/m3 0.090 1.88 1 01/25/24 21:34 V42931ENM <0.199 µg/m3 0.199 2.15 1 01/25/24 21:34 V42931ENM 1.86 J µg/m3 0.130 2.81 1 01/25/24 21:34 V42931ENM 3.98 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 01/25/24 21:34 V42931ENM 1.32 J µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 01/25/24 21:34 V42931ENM 0.833 J µg/m3 0.157 2.17o-Xylene 1 01/25/24 21:34 V42931ENM 2.33 J µg/m3 0.217 5.65m,p-Xylene 1 01/25/24 21:34 V42931ENM Surrogate: 4-Bromofluorobenzene Surrogate: 4-Bromofluorobenzene Surrogate: 4-Bromofluorobenzene Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 26 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-OFF-2 94751 Matrix: 1/18/2024 8:50 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/25/24 09:00 V42983 01/30/24 07:00 53.1 µg/m3 0.202 4.75Acetone 1 01/25/24 22:22 V42931ENM 1.33 J µg/m3 0.073 1.60Benzene 1 01/25/24 22:22 V42931ENM 1.09 J µg/m3 0.060 6.23Carbon Disulfide 1 01/25/24 22:22 V42931ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 01/25/24 22:22 V42931ENM <0.086 µg/m3 0.086 2.44Chloroform 1 01/25/24 22:22 V42931ENM 0.825 J µg/m3 0.067 1.03Chloromethane 1 01/25/24 22:22 V42931ENM 6.04 µg/m3 0.161 3.44Cyclohexane 1 01/25/24 22:22 V42931ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 01/25/24 22:22 V42931ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 01/25/24 22:22 V42931ENM 2.86 µg/m3 0.134 2.47Dichlorodifluoromethane 1 01/25/24 22:22 V42931ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 01/25/24 22:22 V42931ENM 206 µg/m3 3.38 100Ethanol 20 01/30/24 21:00 V42985ENM 1.21 J µg/m3 0.106 2.17Ethylbenzene 1 01/25/24 22:22 V42931ENM 2.83 µg/m3 0.128 2.464-Ethyltoluene 1 01/25/24 22:22 V42931ENM 4.54 µg/m3 0.143 2.05Heptane 1 01/25/24 22:22 V42931ENM 0.905 J µg/m3 0.047 1.76n-Hexane 1 01/25/24 22:22 V42931ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 01/25/24 22:22 V42931ENM 31.2 µg/m3 0.139 4.92Isopropyl Alcohol 1 01/25/24 22:22 V42931ENM 4.14 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 01/25/24 22:22 V42931ENM 2.83 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 01/25/24 22:22 V42931ENM 1.98 µg/m3 0.488 1.74Methylene Chloride 1 01/25/24 22:22 V42931ENM 4.70 µg/m3 0.183 2.62Naphthalene 1 01/25/24 22:22 V42931ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 27 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-OFF-2 94751 Matrix: 1/18/2024 8:50 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/25/24 09:00 V42983 01/30/24 07:00 <0.242 µg/m3 0.242 0.860Propene 1 01/25/24 22:22 V42931ENM 0.894 J µg/m3 0.124 2.13Styrene 1 01/25/24 22:22 V42931ENM 0.813 J µg/m3 0.181 3.39 1 01/25/24 22:22 V42931ENM 2.15 µg/m3 0.107 1.47 1 01/25/24 22:22 V42931ENM 6.76 µg/m3 0.090 1.88 1 01/25/24 22:22 V42931ENM <0.199 µg/m3 0.199 2.15 1 01/25/24 22:22 V42931ENM 1.66 J µg/m3 0.130 2.81 1 01/25/24 22:22 V42931ENM 8.62 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 01/25/24 22:22 V42931ENM 2.30 J µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 01/25/24 22:22 V42931ENM 1.80 J µg/m3 0.157 2.17o-Xylene 1 01/25/24 22:22 V42931ENM 5.41 J µg/m3 0.217 5.65m,p-Xylene 1 01/25/24 22:22 V42931ENM Surrogate: 4-Bromofluorobenzene Surrogate: 4-Bromofluorobenzene Surrogate: 4-Bromofluorobenzene Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 28 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-1 94752 Matrix: 1/18/2024 8:24 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/25/24 09:00 V42983 01/30/24 07:00 10.9 µg/m3 0.202 4.75Acetone 1 01/25/24 23:10 V42931ENM 0.916 J µg/m3 0.073 1.60Benzene 1 01/25/24 23:10 V42931ENM 0.538 J µg/m3 0.060 6.23Carbon Disulfide 1 01/25/24 23:10 V42931ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 01/25/24 23:10 V42931ENM 1.27 J µg/m3 0.086 2.44Chloroform 1 01/25/24 23:10 V42931ENM 0.885 J µg/m3 0.067 1.03Chloromethane 1 01/25/24 23:10 V42931ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 01/25/24 23:10 V42931ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 01/25/24 23:10 V42931ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 01/25/24 23:10 V42931ENM 2.76 µg/m3 0.134 2.47Dichlorodifluoromethane 1 01/25/24 23:10 V42931ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 01/25/24 23:10 V42931ENM 169 µg/m3 3.38 100Ethanol 20 01/30/24 21:36 V42985ENM 0.777 J µg/m3 0.106 2.17Ethylbenzene 1 01/25/24 23:10 V42931ENM 0.545 J µg/m3 0.128 2.464-Ethyltoluene 1 01/25/24 23:10 V42931ENM 0.495 J µg/m3 0.143 2.05Heptane 1 01/25/24 23:10 V42931ENM 0.666 J µg/m3 0.047 1.76n-Hexane 1 01/25/24 23:10 V42931ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 01/25/24 23:10 V42931ENM 26.8 µg/m3 0.139 4.92Isopropyl Alcohol 1 01/25/24 23:10 V42931ENM 1.19 J µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 01/25/24 23:10 V42931ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 01/25/24 23:10 V42931ENM 1.40 J µg/m3 0.488 1.74Methylene Chloride 1 01/25/24 23:10 V42931ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 01/25/24 23:10 V42931ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 29 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-1 94752 Matrix: 1/18/2024 8:24 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/25/24 09:00 V42983 01/30/24 07:00 <0.242 µg/m3 0.242 0.860Propene 1 01/25/24 23:10 V42931ENM 0.438 J µg/m3 0.124 2.13Styrene 1 01/25/24 23:10 V42931ENM 1.57 J µg/m3 0.181 3.39 1 01/25/24 23:10 V42931ENM 0.327 J µg/m3 0.107 1.47 1 01/25/24 23:10 V42931ENM 1.91 µg/m3 0.090 1.88 1 01/25/24 23:10 V42931ENM <0.199 µg/m3 0.199 2.15 1 01/25/24 23:10 V42931ENM 1.69 J µg/m3 0.130 2.81 1 01/25/24 23:10 V42931ENM 3.47 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 01/25/24 23:10 V42931ENM 1.08 J µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 01/25/24 23:10 V42931ENM 1.04 J µg/m3 0.157 2.17o-Xylene 1 01/25/24 23:10 V42931ENM 3.26 J µg/m3 0.217 5.65m,p-Xylene 1 01/25/24 23:10 V42931ENM Surrogate: 4-Bromofluorobenzene Surrogate: 4-Bromofluorobenzene Surrogate: 4-Bromofluorobenzene Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 30 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-3 (UDM) 94753 Matrix: 1/18/2024 10:06 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/25/24 09:00 V42983 01/30/24 07:00 12.9 µg/m3 0.202 4.75Acetone 1 01/26/24 00:01 V42931ENM 0.865 J µg/m3 0.073 1.60Benzene 1 01/26/24 00:01 V42931ENM 0.974 J µg/m3 0.060 6.23Carbon Disulfide 1 01/26/24 00:01 V42931ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 01/26/24 00:01 V42931ENM 1.36 J µg/m3 0.086 2.44Chloroform 1 01/26/24 00:01 V42931ENM 0.813 J µg/m3 0.067 1.03Chloromethane 1 01/26/24 00:01 V42931ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 01/26/24 00:01 V42931ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 01/26/24 00:01 V42931ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 01/26/24 00:01 V42931ENM 2.76 µg/m3 0.134 2.47Dichlorodifluoromethane 1 01/26/24 00:01 V42931ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 01/26/24 00:01 V42931ENM 353 µg/m3 3.38 100Ethanol 20 01/30/24 22:13 V42985ENM 0.373 J µg/m3 0.106 2.17Ethylbenzene 1 01/26/24 00:01 V42931ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 01/26/24 00:01 V42931ENM 0.922 J µg/m3 0.143 2.05Heptane 1 01/26/24 00:01 V42931ENM 0.637 J µg/m3 0.047 1.76n-Hexane 1 01/26/24 00:01 V42931ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 01/26/24 00:01 V42931ENM 10.1 B µg/m3 0.139 4.92Isopropyl Alcohol 1 01/26/24 00:01 V42931ENM 1.55 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 01/26/24 00:01 V42931ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 01/26/24 00:01 V42931ENM 1.59 J µg/m3 0.488 1.74Methylene Chloride 1 01/26/24 00:01 V42931ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 01/26/24 00:01 V42931ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 31 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-3 (UDM) 94753 Matrix: 1/18/2024 10:06 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/25/24 09:00 V42983 01/30/24 07:00 <0.242 µg/m3 0.242 0.860Propene 1 01/26/24 00:01 V42931ENM <0.124 µg/m3 0.124 2.13Styrene 1 01/26/24 00:01 V42931ENM 2.12 J µg/m3 0.181 3.39 1 01/26/24 00:01 V42931ENM 0.917 J µg/m3 0.107 1.47 1 01/26/24 00:01 V42931ENM 2.65 µg/m3 0.090 1.88 1 01/26/24 00:01 V42931ENM <0.199 µg/m3 0.199 2.15 1 01/26/24 00:01 V42931ENM 1.62 J µg/m3 0.130 2.81 1 01/26/24 00:01 V42931ENM 1.25 J µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 01/26/24 00:01 V42931ENM 0.447 J µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 01/26/24 00:01 V42931ENM 0.455 J µg/m3 0.157 2.17o-Xylene 1 01/26/24 00:01 V42931ENM 1.20 J µg/m3 0.217 5.65m,p-Xylene 1 01/26/24 00:01 V42931ENM Surrogate: 4-Bromofluorobenzene Surrogate: 4-Bromofluorobenzene Surrogate: 4-Bromofluorobenzene Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 32 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-2 (UDM) 94754 Matrix: 1/18/2024 9:58 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/25/24 09:00 5.92 B µg/m3 0.202 4.75Acetone 1 01/26/24 00:48 V42931ENM 0.721 J µg/m3 0.073 1.60Benzene 1 01/26/24 00:48 V42931ENM 1.05 J µg/m3 0.060 6.23Carbon Disulfide 1 01/26/24 00:48 V42931ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 01/26/24 00:48 V42931ENM 0.624 J µg/m3 0.086 2.44Chloroform 1 01/26/24 00:48 V42931ENM 0.877 J µg/m3 0.067 1.03Chloromethane 1 01/26/24 00:48 V42931ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 01/26/24 00:48 V42931ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 01/26/24 00:48 V42931ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 01/26/24 00:48 V42931ENM 2.77 µg/m3 0.134 2.47Dichlorodifluoromethane 1 01/26/24 00:48 V42931ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 01/26/24 00:48 V42931ENM 12.9 µg/m3 0.169 5.00Ethanol 1 01/26/24 00:48 V42931ENM <0.106 µg/m3 0.106 2.17Ethylbenzene 1 01/26/24 00:48 V42931ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 01/26/24 00:48 V42931ENM 0.360 J µg/m3 0.143 2.05Heptane 1 01/26/24 00:48 V42931ENM 0.475 J µg/m3 0.047 1.76n-Hexane 1 01/26/24 00:48 V42931ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 01/26/24 00:48 V42931ENM 3.44 JB µg/m3 0.139 4.92Isopropyl Alcohol 1 01/26/24 00:48 V42931ENM 0.961 J µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 01/26/24 00:48 V42931ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 01/26/24 00:48 V42931ENM 1.42 J µg/m3 0.488 1.74Methylene Chloride 1 01/26/24 00:48 V42931ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 01/26/24 00:48 V42931ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 33 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-2 (UDM) 94754 Matrix: 1/18/2024 9:58 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/25/24 09:00 <0.242 µg/m3 0.242 0.860Propene 1 01/26/24 00:48 V42931ENM <0.124 µg/m3 0.124 2.13Styrene 1 01/26/24 00:48 V42931ENM <0.181 µg/m3 0.181 3.39 1 01/26/24 00:48 V42931ENM 0.645 J µg/m3 0.107 1.47 1 01/26/24 00:48 V42931ENM 1.46 J µg/m3 0.090 1.88 1 01/26/24 00:48 V42931ENM <0.199 µg/m3 0.199 2.15 1 01/26/24 00:48 V42931ENM 1.55 J µg/m3 0.130 2.81 1 01/26/24 00:48 V42931ENM <0.110 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 01/26/24 00:48 V42931ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 01/26/24 00:48 V42931ENM 0.308 J µg/m3 0.157 2.17o-Xylene 1 01/26/24 00:48 V42931ENM 0.746 J µg/m3 0.217 5.65m,p-Xylene 1 01/26/24 00:48 V42931ENM Surrogate: 4-Bromofluorobenzene Surrogate: 4-Bromofluorobenzene Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 34 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-BKG 94755 Matrix: 1/18/2024 9:21 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/25/24 09:00 8.25 B µg/m3 0.202 4.75Acetone 1 01/26/24 01:36 V42813ENM 0.888 J µg/m3 0.073 1.60Benzene 1 01/26/24 01:36 V42813ENM <0.147 µg/m3 0.147 10.4Benzyl Chloride 1 01/26/24 01:36 V42813ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 01/26/24 01:36 V42813ENM <0.153 µg/m3 0.153 5.17Bromoform 1 01/26/24 01:36 V42813ENM <0.115 µg/m3 0.115 1.94Bromomethane 1 01/26/24 01:36 V42813ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 01/26/24 01:36 V42813ENM 0.890 J µg/m3 0.060 6.23Carbon Disulfide 1 01/26/24 01:36 V42813ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 01/26/24 01:36 V42813ENM <0.107 µg/m3 0.107 2.30Chlorobenzene 1 01/26/24 01:36 V42813ENM <0.208 µg/m3 0.208 4.26Chlorodibromomethane 1 01/26/24 01:36 V42813ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 01/26/24 01:36 V42813ENM <0.086 µg/m3 0.086 2.44Chloroform 1 01/26/24 01:36 V42813ENM 0.836 J µg/m3 0.067 1.03Chloromethane 1 01/26/24 01:36 V42813ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 01/26/24 01:36 V42813ENM <0.151 µg/m3 0.151 3.841,2-Dibromoethane 1 01/26/24 01:36 V42813ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 01/26/24 01:36 V42813ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 01/26/24 01:36 V42813ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 01/26/24 01:36 V42813ENM 2.80 µg/m3 0.134 2.47Dichlorodifluoromethane 1 01/26/24 01:36 V42813ENM <0.101 µg/m3 0.101 2.021,1-Dichloroethane 1 01/26/24 01:36 V42813ENM <0.129 µg/m3 0.129 2.021,2-Dichloroethane 1 01/26/24 01:36 V42813ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 35 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-BKG 94755 Matrix: 1/18/2024 9:21 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/25/24 09:00 <0.107 µg/m3 0.107 1.981,1-Dichloroethene 1 01/26/24 01:36 V42813ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 01/26/24 01:36 V42813ENM <0.108 µg/m3 0.108 1.98trans-1,2-Dichloroethene 1 01/26/24 01:36 V42813ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 01/26/24 01:36 V42813ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 01/26/24 01:36 V42813ENM <0.178 µg/m3 0.178 2.27cis-1,3-Dichloropropene 1 01/26/24 01:36 V42813ENM <0.178 µg/m3 0.178 2.27trans-1,3-Dichloropropene 1 01/26/24 01:36 V42813ENM <0.435 µg/m3 0.435 1.801,4-Dioxane 1 01/26/24 01:36 V42813ENM <0.136 µg/m3 0.136 1.80Ethyl Acetate 1 01/26/24 01:36 V42813ENM 0.343 J µg/m3 0.106 2.17Ethylbenzene 1 01/26/24 01:36 V42813ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 01/26/24 01:36 V42813ENM 0.605 J µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 01/26/24 01:36 V42813ENM 0.454 J µg/m3 0.143 2.05Heptane 1 01/26/24 01:36 V42813ENM <0.330 µg/m3 0.330 5.33Hexachlorobutadiene 1 01/26/24 01:36 V42813ENM 0.609 J µg/m3 0.047 1.76n-Hexane 1 01/26/24 01:36 V42813ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 01/26/24 01:36 V42813ENM 3.13 JB µg/m3 0.139 4.92Isopropyl Alcohol 1 01/26/24 01:36 V42813ENM 2.90 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 01/26/24 01:36 V42813ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 01/26/24 01:36 V42813ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 01/26/24 01:36 V42813ENM 1.23 J µg/m3 0.488 1.74Methylene Chloride 1 01/26/24 01:36 V42813ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 01/26/24 01:36 V42813ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 36 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:IAS-BKG 94755 Matrix: 1/18/2024 9:21 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/25/24 09:00 <0.242 µg/m3 0.242 0.860Propene 1 01/26/24 01:36 V42813ENM <0.124 µg/m3 0.124 2.13Styrene 1 01/26/24 01:36 V42813ENM <0.104 µg/m3 0.104 3.431,1,2,2-Tetrachloroethane 1 01/26/24 01:36 V42813ENM <0.181 µg/m3 0.181 3.39 1 01/26/24 01:36 V42813ENM 2.83 µg/m3 0.107 1.47 1 01/26/24 01:36 V42813ENM 2.08 µg/m3 0.090 1.88 1 01/26/24 01:36 V42813ENM <0.209 µg/m3 0.209 3.711,2,4-Trichlorobenzene 1 01/26/24 01:36 V42813ENM <0.144 µg/m3 0.144 2.731,1,1-Trichloroethane 1 01/26/24 01:36 V42813ENM <0.087 µg/m3 0.087 2.731,1,2-Trichloroethane 1 01/26/24 01:36 V42813ENM 1.02 J µg/m3 0.199 2.15 1 01/26/24 01:36 V42813ENM 1.64 J µg/m3 0.130 2.81 1 01/26/24 01:36 V42813ENM <0.110 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 01/26/24 01:36 V42813ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 01/26/24 01:36 V42813ENM <0.224 µg/m3 0.224 1.76Vinyl Acetate 1 01/26/24 01:36 V42813ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 01/26/24 01:36 V42813ENM 0.351 J µg/m3 0.157 2.17o-Xylene 1 01/26/24 01:36 V42813ENM 0.903 J µg/m3 0.217 5.65m,p-Xylene 1 01/26/24 01:36 V42813ENM 1.25 J µg/m3 0.157 2.17Xylene (Total)1 01/26/24 01:36 V42813 Surrogate: 4-Bromofluorobenzene Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 37 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:MP-P1 94756 Matrix: 1/18/2024 10:02 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/26/24 09:00 6.79 B µg/m3 0.202 4.75Acetone 1 01/26/24 14:09 V42833ENM <0.073 µg/m3 0.073 1.60Benzene 1 01/26/24 14:09 V42833ENM <0.147 µg/m3 0.147 10.4Benzyl Chloride 1 01/26/24 14:09 V42833ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 01/26/24 14:09 V42833ENM <0.153 µg/m3 0.153 5.17Bromoform 1 01/26/24 14:09 V42833ENM <0.115 µg/m3 0.115 1.94Bromomethane 1 01/26/24 14:09 V42833ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 01/26/24 14:09 V42833ENM <0.060 µg/m3 0.060 6.23Carbon Disulfide 1 01/26/24 14:09 V42833ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 01/26/24 14:09 V42833ENM <0.107 µg/m3 0.107 2.30Chlorobenzene 1 01/26/24 14:09 V42833ENM <0.208 µg/m3 0.208 4.26Chlorodibromomethane 1 01/26/24 14:09 V42833ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 01/26/24 14:09 V42833ENM 0.737 J µg/m3 0.086 2.44Chloroform 1 01/26/24 14:09 V42833ENM <0.067 µg/m3 0.067 1.03Chloromethane 1 01/26/24 14:09 V42833ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 01/26/24 14:09 V42833ENM <0.151 µg/m3 0.151 3.841,2-Dibromoethane 1 01/26/24 14:09 V42833ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 01/26/24 14:09 V42833ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 01/26/24 14:09 V42833ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 01/26/24 14:09 V42833ENM 13.4 µg/m3 0.134 2.47Dichlorodifluoromethane 1 01/26/24 14:09 V42833ENM <0.101 µg/m3 0.101 2.021,1-Dichloroethane 1 01/26/24 14:09 V42833ENM <0.129 µg/m3 0.129 2.021,2-Dichloroethane 1 01/26/24 14:09 V42833ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 38 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:MP-P1 94756 Matrix: 1/18/2024 10:02 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/26/24 09:00 <0.107 µg/m3 0.107 1.981,1-Dichloroethene 1 01/26/24 14:09 V42833ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 01/26/24 14:09 V42833ENM <0.108 µg/m3 0.108 1.98trans-1,2-Dichloroethene 1 01/26/24 14:09 V42833ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 01/26/24 14:09 V42833ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 01/26/24 14:09 V42833ENM <0.178 µg/m3 0.178 2.27cis-1,3-Dichloropropene 1 01/26/24 14:09 V42833ENM <0.178 µg/m3 0.178 2.27trans-1,3-Dichloropropene 1 01/26/24 14:09 V42833ENM <0.435 µg/m3 0.435 1.801,4-Dioxane 1 01/26/24 14:09 V42833ENM <0.136 µg/m3 0.136 1.80Ethyl Acetate 1 01/26/24 14:09 V42833ENM 0.968 J µg/m3 0.106 2.17Ethylbenzene 1 01/26/24 14:09 V42833ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 01/26/24 14:09 V42833ENM <0.561 µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 01/26/24 14:09 V42833ENM <0.143 µg/m3 0.143 2.05Heptane 1 01/26/24 14:09 V42833ENM <0.330 µg/m3 0.330 5.33Hexachlorobutadiene 1 01/26/24 14:09 V42833ENM 0.334 J µg/m3 0.047 1.76n-Hexane 1 01/26/24 14:09 V42833ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 01/26/24 14:09 V42833ENM 2.92 JB µg/m3 0.139 4.92Isopropyl Alcohol 1 01/26/24 14:09 V42833ENM 0.931 J µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 01/26/24 14:09 V42833ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 01/26/24 14:09 V42833ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 01/26/24 14:09 V42833ENM 1.46 J µg/m3 0.488 1.74Methylene Chloride 1 01/26/24 14:09 V42833ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 01/26/24 14:09 V42833ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 39 of 66 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-019-0015 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Matt Vawter Charlotte Received : 01/19/2024 PAM.003 Report Date : 01/31/2024 Sample ID : Lab No : Sampled:MP-P1 94756 Matrix: 1/18/2024 10:02 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):01/26/24 09:00 <0.242 µg/m3 0.242 0.860Propene 1 01/26/24 14:09 V42833ENM <0.124 µg/m3 0.124 2.13Styrene 1 01/26/24 14:09 V42833ENM <0.104 µg/m3 0.104 3.431,1,2,2-Tetrachloroethane 1 01/26/24 14:09 V42833ENM 76.1 µg/m3 0.181 3.39 1 01/26/24 14:09 V42833ENM 1.57 µg/m3 0.107 1.47 1 01/26/24 14:09 V42833ENM 0.395 JB µg/m3 0.090 1.88 1 01/26/24 14:09 V42833ENM <0.209 µg/m3 0.209 3.711,2,4-Trichlorobenzene 1 01/26/24 14:09 V42833ENM 0.932 J µg/m3 0.144 2.731,1,1-Trichloroethane 1 01/26/24 14:09 V42833ENM <0.087 µg/m3 0.087 2.731,1,2-Trichloroethane 1 01/26/24 14:09 V42833ENM <0.199 µg/m3 0.199 2.15 1 01/26/24 14:09 V42833ENM 1.74 J µg/m3 0.130 2.81 1 01/26/24 14:09 V42833ENM <0.110 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 01/26/24 14:09 V42833ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 01/26/24 14:09 V42833ENM <0.224 µg/m3 0.224 1.76Vinyl Acetate 1 01/26/24 14:09 V42833ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 01/26/24 14:09 V42833ENM 1.53 J µg/m3 0.157 2.17o-Xylene 1 01/26/24 14:09 V42833ENM 4.52 J µg/m3 0.217 5.65m,p-Xylene 1 01/26/24 14:09 V42833ENM 6.05 J µg/m3 0.157 2.17Xylene (Total)1 01/26/24 14:09 V42833 Surrogate: 4-Bromofluorobenzene Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 40 of 66 Quality Control Data 24-019-0015Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM.003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V42735QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V42730 Associated Lab Samples: 94745, 94746 LRB-V42730 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 01/24/24 12:224.750.2020.959µg/m3Acetone 01/24/24 12:221.600.073<0.073µg/m3Benzene 01/24/24 12:2210.40.147<0.147µg/m3Benzyl Chloride 01/24/24 12:223.350.150<0.150µg/m3Bromodichloromethane 01/24/24 12:225.170.153<0.153µg/m3Bromoform 01/24/24 12:221.940.115<0.115µg/m3Bromomethane 01/24/24 12:221.110.328<0.328µg/m31,3-Butadiene 01/24/24 12:226.230.060<0.060µg/m3Carbon Disulfide 01/24/24 12:223.150.155<0.155µg/m3Carbon Tetrachloride 01/24/24 12:222.300.107<0.107µg/m3Chlorobenzene 01/24/24 12:224.260.208<0.208µg/m3Chlorodibromomethane 01/24/24 12:221.320.164<0.164µg/m3Chloroethane 01/24/24 12:222.440.086<0.086µg/m3Chloroform 01/24/24 12:221.030.067<0.067µg/m3Chloromethane 01/24/24 12:223.440.161<0.161µg/m3Cyclohexane 01/24/24 12:223.840.151<0.151µg/m31,2-Dibromoethane 01/24/24 12:223.010.096<0.096µg/m31,2-Dichlorobenzene 01/24/24 12:2212.00.174<0.174µg/m31,3-Dichlorobenzene 01/24/24 12:223.010.186<0.186µg/m31,4-Dichlorobenzene 01/24/24 12:222.470.134<0.134µg/m3Dichlorodifluoromethane 01/24/24 12:222.020.101<0.101µg/m31,1-Dichloroethane 01/24/24 12:222.020.129<0.129µg/m31,2-Dichloroethane 01/24/24 12:221.980.107<0.107µg/m31,1-Dichloroethene 01/24/24 12:221.980.095<0.095µg/m3cis-1,2-Dichloroethene 01/24/24 12:221.980.108<0.108µg/m3trans-1,2-Dichloroethene 01/24/24 12:222.310.205<0.205µg/m31,2-Dichloropropane 01/24/24 12:223.500.622<0.622µg/m31,2-Dichlorotetrafluoroethane Page 1 of 22Date:01/31/2024 03:04 PM Page 41 of 66 Quality Control Data 24-019-0015Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM.003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V42735QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V42730 Associated Lab Samples: 94745, 94746 LRB-V42730 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 01/24/24 12:222.270.178<0.178µg/m3cis-1,3-Dichloropropene 01/24/24 12:222.270.178<0.178µg/m3trans-1,3-Dichloropropene 01/24/24 12:221.800.435<0.435µg/m31,4-Dioxane 01/24/24 12:221.800.136<0.136µg/m3Ethyl Acetate 01/24/24 12:222.170.106<0.106µg/m3Ethylbenzene 01/24/24 12:222.460.128<0.128µg/m34-Ethyltoluene 01/24/24 12:223.830.561<0.561µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 01/24/24 12:222.050.143<0.143µg/m3Heptane 01/24/24 12:225.330.330<0.330µg/m3Hexachlorobutadiene 01/24/24 12:221.760.047<0.047µg/m3n-Hexane 01/24/24 12:222.050.285<0.285µg/m32-Hexanone 01/24/24 12:224.920.1391.98µg/m3Isopropyl Alcohol 01/24/24 12:221.470.224<0.224µg/m3Methyl Ethyl Ketone (MEK) 01/24/24 12:221.800.033<0.033µg/m3Methyl tert-butyl ether (MTBE) 01/24/24 12:222.050.121<0.121µg/m34-Methyl-2-Pentanone 01/24/24 12:221.740.488<0.488µg/m3Methylene Chloride 01/24/24 12:222.620.183<0.183µg/m3Naphthalene 01/24/24 12:220.8600.242<0.242µg/m3Propene 01/24/24 12:222.130.124<0.124µg/m3Styrene 01/24/24 12:223.430.104<0.104µg/m31,1,2,2-Tetrachloroethane 01/24/24 12:223.390.181<0.181µg/m3 01/24/24 12:221.470.107<0.107µg/m3 01/24/24 12:221.880.090<0.090µg/m3 01/24/24 12:223.710.209<0.209µg/m31,2,4-Trichlorobenzene 01/24/24 12:222.730.144<0.144µg/m31,1,1-Trichloroethane 01/24/24 12:222.730.087<0.087µg/m31,1,2-Trichloroethane 01/24/24 12:222.150.199<0.199µg/m3 Page 2 of 22Date:01/31/2024 03:04 PM Page 42 of 66 Quality Control Data 24-019-0015Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM.003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V42735QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V42730 Associated Lab Samples: 94745, 94746 LRB-V42730 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 01/24/24 12:222.810.130<0.130µg/m3 01/24/24 12:222.460.110<0.110µg/m31,2,4-Trimethylbenzene 01/24/24 12:222.460.236<0.236µg/m31,3,5-Trimethylbenzene 01/24/24 12:221.760.224<0.224µg/m3Vinyl Acetate 01/24/24 12:221.280.127<0.127µg/m3Vinyl Chloride 01/24/24 12:222.170.157<0.157µg/m3o-Xylene 01/24/24 12:225.650.217<0.217µg/m3m,p-Xylene 01/24/24 12:224-Bromofluorobenzene (S)99.1 70-130 LCS-V42730Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 98.311.711.9µg/m3Acetone 70-130 98.715.816.0µg/m3Benzene 70-130 10527.325.9µg/m3Benzyl Chloride 70-130 98.533.033.5µg/m3Bromodichloromethane 70-130 97.250.351.7µg/m3Bromoform 70-130 10219.719.4µg/m3Bromomethane 70-130 10011.111.1µg/m31,3-Butadiene 70-130 10115.815.6µg/m3Carbon Disulfide 70-130 97.430.731.5µg/m3Carbon Tetrachloride 70-130 10023.023.0µg/m3Chlorobenzene 70-130 98.141.842.6µg/m3Chlorodibromomethane 70-130 98.413.013.2µg/m3Chloroethane 70-130 99.524.324.4µg/m3Chloroform 70-130 10010.310.3µg/m3Chloromethane 70-130 98.216.917.2µg/m3Cyclohexane 70-130 Page 3 of 22Date:01/31/2024 03:04 PM Page 43 of 66 Quality Control Data 24-019-0015Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM.003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V42735QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V42730 LCS-V42730Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10138.638.4µg/m31,2-Dibromoethane 70-130 10832.430.1µg/m31,2-Dichlorobenzene 70-130 10732.230.1µg/m31,3-Dichlorobenzene 70-130 10732.330.1µg/m31,4-Dichlorobenzene 70-130 10024.824.7µg/m3Dichlorodifluoromethane 70-130 10020.320.2µg/m31,1-Dichloroethane 70-130 99.020.020.2µg/m31,2-Dichloroethane 70-130 10220.119.8µg/m31,1-Dichloroethene 70-130 10320.319.8µg/m3cis-1,2-Dichloroethene 70-130 10320.319.8µg/m3trans-1,2-Dichloroethene 70-130 98.222.723.1µg/m31,2-Dichloropropane 70-130 10235.635.0µg/m31,2-Dichlorotetrafluoroethane 70-130 10022.722.7µg/m3cis-1,3-Dichloropropene 70-130 99.522.622.7µg/m3trans-1,3-Dichloropropene 70-130 97.717.618.0µg/m31,4-Dioxane 70-130 97.217.518.0µg/m3Ethyl Acetate 70-130 10121.921.7µg/m3Ethylbenzene 70-130 10425.524.6µg/m34-Ethyltoluene 70-130 10239.138.3µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 70-130 98.020.120.5µg/m3Heptane 70-130 10053.353.3µg/m3Hexachlorobutadiene 70-130 10117.717.6µg/m3n-Hexane 70-130 97.019.920.5µg/m32-Hexanone 70-130 10212.512.3µg/m3Isopropyl Alcohol 70-130 99.314.714.8µg/m3Methyl Ethyl Ketone (MEK)70-130 10118.118.0µg/m3Methyl tert-butyl ether (MTBE)70-130 97.019.920.5µg/m34-Methyl-2-Pentanone 70-130 Page 4 of 22Date:01/31/2024 03:04 PM Page 44 of 66 Quality Control Data 24-019-0015Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM.003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V42735QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V42730 LCS-V42730Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 91.916.017.4µg/m3Methylene Chloride 70-130 99.626.126.2µg/m3Naphthalene 70-130 1008.638.61µg/m3Propene 70-130 10221.821.3µg/m3Styrene 70-130 98.833.934.3µg/m31,1,2,2-Tetrachloroethane 70-130 98.833.533.9µg/m3 70-130 96.514.214.7µg/m3 70-130 10018.818.8µg/m3 70-130 10940.637.1µg/m31,2,4-Trichlorobenzene 70-130 98.927.027.3µg/m31,1,1-Trichloroethane 70-130 98.126.827.3µg/m31,1,2-Trichloroethane 70-130 10026.926.9µg/m3 70-130 10228.728.1µg/m3 70-130 10926.924.6µg/m31,2,4-Trimethylbenzene 70-130 10726.424.6µg/m31,3,5-Trimethylbenzene 70-130 98.817.417.6µg/m3Vinyl Acetate 70-130 10213.012.8µg/m3Vinyl Chloride 70-130 10122.021.7µg/m3o-Xylene 70-130 10244.443.4µg/m3m,p-Xylene 70-130 1044-Bromofluorobenzene (S)70-130 Page 5 of 22Date:01/31/2024 03:04 PM Page 45 of 66 Quality Control Data 24-019-0015Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM.003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V42813QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V42810 Associated Lab Samples: 94755 LRB-V42810 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 01/25/24 10:524.750.2021.07µg/m3Acetone 01/25/24 10:521.600.073<0.073µg/m3Benzene 01/25/24 10:5210.40.147<0.147µg/m3Benzyl Chloride 01/25/24 10:523.350.150<0.150µg/m3Bromodichloromethane 01/25/24 10:525.170.153<0.153µg/m3Bromoform 01/25/24 10:521.940.115<0.115µg/m3Bromomethane 01/25/24 10:521.110.328<0.328µg/m31,3-Butadiene 01/25/24 10:526.230.060<0.060µg/m3Carbon Disulfide 01/25/24 10:523.150.155<0.155µg/m3Carbon Tetrachloride 01/25/24 10:522.300.107<0.107µg/m3Chlorobenzene 01/25/24 10:524.260.208<0.208µg/m3Chlorodibromomethane 01/25/24 10:521.320.164<0.164µg/m3Chloroethane 01/25/24 10:522.440.086<0.086µg/m3Chloroform 01/25/24 10:521.030.067<0.067µg/m3Chloromethane 01/25/24 10:523.440.161<0.161µg/m3Cyclohexane 01/25/24 10:523.840.151<0.151µg/m31,2-Dibromoethane 01/25/24 10:523.010.096<0.096µg/m31,2-Dichlorobenzene 01/25/24 10:5212.00.174<0.174µg/m31,3-Dichlorobenzene 01/25/24 10:523.010.186<0.186µg/m31,4-Dichlorobenzene 01/25/24 10:522.470.134<0.134µg/m3Dichlorodifluoromethane 01/25/24 10:522.020.101<0.101µg/m31,1-Dichloroethane 01/25/24 10:522.020.129<0.129µg/m31,2-Dichloroethane 01/25/24 10:521.980.107<0.107µg/m31,1-Dichloroethene 01/25/24 10:521.980.095<0.095µg/m3cis-1,2-Dichloroethene 01/25/24 10:521.980.108<0.108µg/m3trans-1,2-Dichloroethene 01/25/24 10:522.310.205<0.205µg/m31,2-Dichloropropane 01/25/24 10:523.500.622<0.622µg/m31,2-Dichlorotetrafluoroethane Page 6 of 22Date:01/31/2024 03:04 PM Page 46 of 66 Quality Control Data 24-019-0015Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM.003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V42813QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V42810 Associated Lab Samples: 94755 LRB-V42810 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 01/25/24 10:522.270.178<0.178µg/m3cis-1,3-Dichloropropene 01/25/24 10:522.270.178<0.178µg/m3trans-1,3-Dichloropropene 01/25/24 10:521.800.435<0.435µg/m31,4-Dioxane 01/25/24 10:521.800.136<0.136µg/m3Ethyl Acetate 01/25/24 10:522.170.106<0.106µg/m3Ethylbenzene 01/25/24 10:522.460.128<0.128µg/m34-Ethyltoluene 01/25/24 10:523.830.561<0.561µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 01/25/24 10:522.050.143<0.143µg/m3Heptane 01/25/24 10:525.330.330<0.330µg/m3Hexachlorobutadiene 01/25/24 10:521.760.047<0.047µg/m3n-Hexane 01/25/24 10:522.050.285<0.285µg/m32-Hexanone 01/25/24 10:524.920.1392.35µg/m3Isopropyl Alcohol 01/25/24 10:521.470.224<0.224µg/m3Methyl Ethyl Ketone (MEK) 01/25/24 10:521.800.033<0.033µg/m3Methyl tert-butyl ether (MTBE) 01/25/24 10:522.050.121<0.121µg/m34-Methyl-2-Pentanone 01/25/24 10:521.740.488<0.488µg/m3Methylene Chloride 01/25/24 10:522.620.183<0.183µg/m3Naphthalene 01/25/24 10:520.8600.242<0.242µg/m3Propene 01/25/24 10:522.130.124<0.124µg/m3Styrene 01/25/24 10:523.430.104<0.104µg/m31,1,2,2-Tetrachloroethane 01/25/24 10:523.390.181<0.181µg/m3 01/25/24 10:521.470.107<0.107µg/m3 01/25/24 10:521.880.090<0.090µg/m3 01/25/24 10:523.710.209<0.209µg/m31,2,4-Trichlorobenzene 01/25/24 10:522.730.144<0.144µg/m31,1,1-Trichloroethane 01/25/24 10:522.730.087<0.087µg/m31,1,2-Trichloroethane 01/25/24 10:522.150.199<0.199µg/m3 Page 7 of 22Date:01/31/2024 03:04 PM Page 47 of 66 Quality Control Data 24-019-0015Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM.003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V42813QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V42810 Associated Lab Samples: 94755 LRB-V42810 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 01/25/24 10:522.810.130<0.130µg/m3 01/25/24 10:522.460.110<0.110µg/m31,2,4-Trimethylbenzene 01/25/24 10:522.460.236<0.236µg/m31,3,5-Trimethylbenzene 01/25/24 10:521.760.224<0.224µg/m3Vinyl Acetate 01/25/24 10:521.280.127<0.127µg/m3Vinyl Chloride 01/25/24 10:522.170.157<0.157µg/m3o-Xylene 01/25/24 10:525.650.217<0.217µg/m3m,p-Xylene 01/25/24 10:524-Bromofluorobenzene (S)96.9 70-130 LCS-V42810Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10011.911.9µg/m3Acetone 70-130 10016.016.0µg/m3Benzene 70-130 10727.825.9µg/m3Benzyl Chloride 70-130 99.133.233.5µg/m3Bromodichloromethane 70-130 97.450.451.7µg/m3Bromoform 70-130 10119.619.4µg/m3Bromomethane 70-130 10211.311.1µg/m31,3-Butadiene 70-130 10316.015.6µg/m3Carbon Disulfide 70-130 98.731.131.5µg/m3Carbon Tetrachloride 70-130 10323.723.0µg/m3Chlorobenzene 70-130 98.542.042.6µg/m3Chlorodibromomethane 70-130 99.213.113.2µg/m3Chloroethane 70-130 10124.724.4µg/m3Chloroform 70-130 10210.510.3µg/m3Chloromethane 70-130 10117.317.2µg/m3Cyclohexane 70-130 Page 8 of 22Date:01/31/2024 03:04 PM Page 48 of 66 Quality Control Data 24-019-0015Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM.003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V42813QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V42810 LCS-V42810Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10439.838.4µg/m31,2-Dibromoethane 70-130 11233.630.1µg/m31,2-Dichlorobenzene 70-130 11133.330.1µg/m31,3-Dichlorobenzene 70-130 11334.030.1µg/m31,4-Dichlorobenzene 70-130 10225.324.7µg/m3Dichlorodifluoromethane 70-130 10220.620.2µg/m31,1-Dichloroethane 70-130 10120.420.2µg/m31,2-Dichloroethane 70-130 10420.619.8µg/m31,1-Dichloroethene 70-130 10420.519.8µg/m3cis-1,2-Dichloroethene 70-130 10420.519.8µg/m3trans-1,2-Dichloroethene 70-130 10123.323.1µg/m31,2-Dichloropropane 70-130 10336.035.0µg/m31,2-Dichlorotetrafluoroethane 70-130 10122.922.7µg/m3cis-1,3-Dichloropropene 70-130 10122.922.7µg/m3trans-1,3-Dichloropropene 70-130 98.817.818.0µg/m31,4-Dioxane 70-130 10018.018.0µg/m3Ethyl Acetate 70-130 10322.321.7µg/m3Ethylbenzene 70-130 10626.124.6µg/m34-Ethyltoluene 70-130 10439.738.3µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 70-130 10020.620.5µg/m3Heptane 70-130 10153.953.3µg/m3Hexachlorobutadiene 70-130 10218.017.6µg/m3n-Hexane 70-130 10120.720.5µg/m32-Hexanone 70-130 10212.612.3µg/m3Isopropyl Alcohol 70-130 10114.914.8µg/m3Methyl Ethyl Ketone (MEK)70-130 10118.218.0µg/m3Methyl tert-butyl ether (MTBE)70-130 10020.520.5µg/m34-Methyl-2-Pentanone 70-130 Page 9 of 22Date:01/31/2024 03:04 PM Page 49 of 66 Quality Control Data 24-019-0015Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM.003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V42813QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V42810 LCS-V42810Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 93.616.317.4µg/m3Methylene Chloride 70-130 10527.626.2µg/m3Naphthalene 70-130 1048.948.61µg/m3Propene 70-130 10221.821.3µg/m3Styrene 70-130 10034.434.3µg/m31,1,2,2-Tetrachloroethane 70-130 10134.433.9µg/m3 70-130 99.314.614.7µg/m3 70-130 10319.318.8µg/m3 70-130 11542.837.1µg/m31,2,4-Trichlorobenzene 70-130 10027.427.3µg/m31,1,1-Trichloroethane 70-130 99.227.127.3µg/m31,1,2-Trichloroethane 70-130 10227.426.9µg/m3 70-130 10429.328.1µg/m3 70-130 11227.624.6µg/m31,2,4-Trimethylbenzene 70-130 11027.024.6µg/m31,3,5-Trimethylbenzene 70-130 97.117.117.6µg/m3Vinyl Acetate 70-130 10213.112.8µg/m3Vinyl Chloride 70-130 10422.621.7µg/m3o-Xylene 70-130 10445.143.4µg/m3m,p-Xylene 70-130 1044-Bromofluorobenzene (S)70-130 Page 10 of 22Date:01/31/2024 03:04 PM Page 50 of 66 Quality Control Data 24-019-0015Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM.003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V42833QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V42830 Associated Lab Samples: 94756 LRB-V42830 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 01/26/24 10:254.750.2021.02µg/m3Acetone 01/26/24 10:251.600.073<0.073µg/m3Benzene 01/26/24 10:2510.40.147<0.147µg/m3Benzyl Chloride 01/26/24 10:253.350.150<0.150µg/m3Bromodichloromethane 01/26/24 10:255.170.153<0.153µg/m3Bromoform 01/26/24 10:251.940.115<0.115µg/m3Bromomethane 01/26/24 10:251.110.328<0.328µg/m31,3-Butadiene 01/26/24 10:256.230.0600.258µg/m3Carbon Disulfide 01/26/24 10:253.150.155<0.155µg/m3Carbon Tetrachloride 01/26/24 10:252.300.107<0.107µg/m3Chlorobenzene 01/26/24 10:254.260.208<0.208µg/m3Chlorodibromomethane 01/26/24 10:251.320.164<0.164µg/m3Chloroethane 01/26/24 10:252.440.086<0.086µg/m3Chloroform 01/26/24 10:251.030.067<0.067µg/m3Chloromethane 01/26/24 10:253.440.161<0.161µg/m3Cyclohexane 01/26/24 10:253.840.151<0.151µg/m31,2-Dibromoethane 01/26/24 10:253.010.096<0.096µg/m31,2-Dichlorobenzene 01/26/24 10:2512.00.174<0.174µg/m31,3-Dichlorobenzene 01/26/24 10:253.010.186<0.186µg/m31,4-Dichlorobenzene 01/26/24 10:252.470.134<0.134µg/m3Dichlorodifluoromethane 01/26/24 10:252.020.101<0.101µg/m31,1-Dichloroethane 01/26/24 10:252.020.129<0.129µg/m31,2-Dichloroethane 01/26/24 10:251.980.107<0.107µg/m31,1-Dichloroethene 01/26/24 10:251.980.095<0.095µg/m3cis-1,2-Dichloroethene 01/26/24 10:251.980.108<0.108µg/m3trans-1,2-Dichloroethene 01/26/24 10:252.310.205<0.205µg/m31,2-Dichloropropane 01/26/24 10:253.500.622<0.622µg/m31,2-Dichlorotetrafluoroethane Page 11 of 22Date:01/31/2024 03:04 PM Page 51 of 66 Quality Control Data 24-019-0015Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM.003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V42833QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V42830 Associated Lab Samples: 94756 LRB-V42830 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 01/26/24 10:252.270.178<0.178µg/m3cis-1,3-Dichloropropene 01/26/24 10:252.270.178<0.178µg/m3trans-1,3-Dichloropropene 01/26/24 10:251.800.435<0.435µg/m31,4-Dioxane 01/26/24 10:251.800.136<0.136µg/m3Ethyl Acetate 01/26/24 10:252.170.106<0.106µg/m3Ethylbenzene 01/26/24 10:252.460.128<0.128µg/m34-Ethyltoluene 01/26/24 10:253.830.561<0.561µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 01/26/24 10:252.050.143<0.143µg/m3Heptane 01/26/24 10:255.330.330<0.330µg/m3Hexachlorobutadiene 01/26/24 10:251.760.047<0.047µg/m3n-Hexane 01/26/24 10:252.050.285<0.285µg/m32-Hexanone 01/26/24 10:254.920.1392.10µg/m3Isopropyl Alcohol 01/26/24 10:251.470.224<0.224µg/m3Methyl Ethyl Ketone (MEK) 01/26/24 10:251.800.033<0.033µg/m3Methyl tert-butyl ether (MTBE) 01/26/24 10:252.050.121<0.121µg/m34-Methyl-2-Pentanone 01/26/24 10:251.740.488<0.488µg/m3Methylene Chloride 01/26/24 10:252.620.183<0.183µg/m3Naphthalene 01/26/24 10:250.8600.242<0.242µg/m3Propene 01/26/24 10:252.130.124<0.124µg/m3Styrene 01/26/24 10:253.430.104<0.104µg/m31,1,2,2-Tetrachloroethane 01/26/24 10:253.390.181<0.181µg/m3 01/26/24 10:251.470.107<0.107µg/m3 01/26/24 10:251.880.0900.271µg/m3 01/26/24 10:253.710.209<0.209µg/m31,2,4-Trichlorobenzene 01/26/24 10:252.730.144<0.144µg/m31,1,1-Trichloroethane 01/26/24 10:252.730.087<0.087µg/m31,1,2-Trichloroethane 01/26/24 10:252.150.199<0.199µg/m3 Page 12 of 22Date:01/31/2024 03:04 PM Page 52 of 66 Quality Control Data 24-019-0015Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM.003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V42833QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V42830 Associated Lab Samples: 94756 LRB-V42830 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 01/26/24 10:252.810.130<0.130µg/m3 01/26/24 10:252.460.110<0.110µg/m31,2,4-Trimethylbenzene 01/26/24 10:252.460.236<0.236µg/m31,3,5-Trimethylbenzene 01/26/24 10:251.760.224<0.224µg/m3Vinyl Acetate 01/26/24 10:251.280.127<0.127µg/m3Vinyl Chloride 01/26/24 10:252.170.157<0.157µg/m3o-Xylene 01/26/24 10:255.650.217<0.217µg/m3m,p-Xylene 01/26/24 10:254-Bromofluorobenzene (S)96.9 70-130 LCS-V42830Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10712.711.9µg/m3Acetone 70-130 10817.216.0µg/m3Benzene 70-130 11329.225.9µg/m3Benzyl Chloride 70-130 10635.533.5µg/m3Bromodichloromethane 70-130 10252.551.7µg/m3Bromoform 70-130 10921.219.4µg/m3Bromomethane 70-130 10912.111.1µg/m31,3-Butadiene 70-130 11017.215.6µg/m3Carbon Disulfide 70-130 10533.231.5µg/m3Carbon Tetrachloride 70-130 10925.023.0µg/m3Chlorobenzene 70-130 10444.142.6µg/m3Chlorodibromomethane 70-130 10614.013.2µg/m3Chloroethane 70-130 10826.424.4µg/m3Chloroform 70-130 10811.110.3µg/m3Chloromethane 70-130 10618.317.2µg/m3Cyclohexane 70-130 Page 13 of 22Date:01/31/2024 03:04 PM Page 53 of 66 Quality Control Data 24-019-0015Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM.003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V42833QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V42830 LCS-V42830Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10841.538.4µg/m31,2-Dibromoethane 70-130 11634.930.1µg/m31,2-Dichlorobenzene 70-130 11635.030.1µg/m31,3-Dichlorobenzene 70-130 11835.430.1µg/m31,4-Dichlorobenzene 70-130 11027.224.7µg/m3Dichlorodifluoromethane 70-130 10922.020.2µg/m31,1-Dichloroethane 70-130 10721.720.2µg/m31,2-Dichloroethane 70-130 11021.819.8µg/m31,1-Dichloroethene 70-130 11122.019.8µg/m3cis-1,2-Dichloroethene 70-130 11121.919.8µg/m3trans-1,2-Dichloroethene 70-130 10724.723.1µg/m31,2-Dichloropropane 70-130 10938.335.0µg/m31,2-Dichlorotetrafluoroethane 70-130 10924.722.7µg/m3cis-1,3-Dichloropropene 70-130 11024.922.7µg/m3trans-1,3-Dichloropropene 70-130 10619.118.0µg/m31,4-Dioxane 70-130 10819.418.0µg/m3Ethyl Acetate 70-130 10823.521.7µg/m3Ethylbenzene 70-130 11227.524.6µg/m34-Ethyltoluene 70-130 11142.438.3µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 70-130 10722.020.5µg/m3Heptane 70-130 10656.453.3µg/m3Hexachlorobutadiene 70-130 10919.117.6µg/m3n-Hexane 70-130 10421.320.5µg/m32-Hexanone 70-130 10813.312.3µg/m3Isopropyl Alcohol 70-130 10715.814.8µg/m3Methyl Ethyl Ketone (MEK)70-130 10919.618.0µg/m3Methyl tert-butyl ether (MTBE)70-130 10722.020.5µg/m34-Methyl-2-Pentanone 70-130 Page 14 of 22Date:01/31/2024 03:04 PM Page 54 of 66 Quality Control Data 24-019-0015Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM.003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V42833QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V42830 LCS-V42830Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 99.417.317.4µg/m3Methylene Chloride 70-130 11129.126.2µg/m3Naphthalene 70-130 1099.378.61µg/m3Propene 70-130 11023.521.3µg/m3Styrene 70-130 10536.034.3µg/m31,1,2,2-Tetrachloroethane 70-130 10836.633.9µg/m3 70-130 10515.514.7µg/m3 70-130 11020.718.8µg/m3 70-130 12044.737.1µg/m31,2,4-Trichlorobenzene 70-130 10729.227.3µg/m31,1,1-Trichloroethane 70-130 10528.727.3µg/m31,1,2-Trichloroethane 70-130 10929.326.9µg/m3 70-130 11131.228.1µg/m3 70-130 11728.924.6µg/m31,2,4-Trimethylbenzene 70-130 11528.224.6µg/m31,3,5-Trimethylbenzene 70-130 10718.917.6µg/m3Vinyl Acetate 70-130 10813.812.8µg/m3Vinyl Chloride 70-130 11023.821.7µg/m3o-Xylene 70-130 10947.543.4µg/m3m,p-Xylene 70-130 1044-Bromofluorobenzene (S)70-130 Page 15 of 22Date:01/31/2024 03:04 PM Page 55 of 66 Quality Control Data 24-019-0015Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM.003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V42935QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V42920 Associated Lab Samples: 94747, 94748 LRB-V42920 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 01/24/24 12:224.750.2020.959µg/m3Acetone 01/24/24 12:221.600.073<0.073µg/m3Benzene 01/24/24 12:226.230.060<0.060µg/m3Carbon Disulfide 01/24/24 12:223.150.155<0.155µg/m3Carbon Tetrachloride 01/24/24 12:222.440.086<0.086µg/m3Chloroform 01/24/24 12:221.030.067<0.067µg/m3Chloromethane 01/24/24 12:223.440.161<0.161µg/m3Cyclohexane 01/24/24 12:223.010.096<0.096µg/m31,2-Dichlorobenzene 01/24/24 12:223.010.186<0.186µg/m31,4-Dichlorobenzene 01/24/24 12:222.470.134<0.134µg/m3Dichlorodifluoromethane 01/24/24 12:221.980.095<0.095µg/m3cis-1,2-Dichloroethene 01/24/24 12:222.170.106<0.106µg/m3Ethylbenzene 01/24/24 12:222.460.128<0.128µg/m34-Ethyltoluene 01/24/24 12:222.050.143<0.143µg/m3Heptane 01/24/24 12:221.760.047<0.047µg/m3n-Hexane 01/24/24 12:222.050.285<0.285µg/m32-Hexanone 01/24/24 12:224.920.1391.98µg/m3Isopropyl Alcohol 01/24/24 12:221.470.224<0.224µg/m3Methyl Ethyl Ketone (MEK) 01/24/24 12:222.050.121<0.121µg/m34-Methyl-2-Pentanone 01/24/24 12:221.740.488<0.488µg/m3Methylene Chloride 01/24/24 12:222.620.183<0.183µg/m3Naphthalene 01/24/24 12:220.8600.242<0.242µg/m3Propene 01/24/24 12:222.130.124<0.124µg/m3Styrene 01/24/24 12:223.390.181<0.181µg/m3 01/24/24 12:221.470.107<0.107µg/m3 01/24/24 12:221.880.090<0.090µg/m3 01/24/24 12:222.150.199<0.199µg/m3 Page 16 of 22Date:01/31/2024 03:04 PM Page 56 of 66 Quality Control Data 24-019-0015Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM.003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V42935QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V42920 Associated Lab Samples: 94747, 94748 LRB-V42920 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 01/24/24 12:222.810.130<0.130µg/m3 01/24/24 12:222.460.110<0.110µg/m31,2,4-Trimethylbenzene 01/24/24 12:222.460.236<0.236µg/m31,3,5-Trimethylbenzene 01/24/24 12:222.170.157<0.157µg/m3o-Xylene 01/24/24 12:225.650.217<0.217µg/m3m,p-Xylene 01/24/24 12:224-Bromofluorobenzene (S)99.1 70-130 LCS-V42920Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 98.311.711.9µg/m3Acetone 70-130 98.715.816.0µg/m3Benzene 70-130 10115.815.6µg/m3Carbon Disulfide 70-130 97.430.731.5µg/m3Carbon Tetrachloride 70-130 99.524.324.4µg/m3Chloroform 70-130 10010.310.3µg/m3Chloromethane 70-130 98.216.917.2µg/m3Cyclohexane 70-130 10832.430.1µg/m31,2-Dichlorobenzene 70-130 10732.330.1µg/m31,4-Dichlorobenzene 70-130 10024.824.7µg/m3Dichlorodifluoromethane 70-130 10320.319.8µg/m3cis-1,2-Dichloroethene 70-130 10121.921.7µg/m3Ethylbenzene 70-130 10425.524.6µg/m34-Ethyltoluene 70-130 98.020.120.5µg/m3Heptane 70-130 10117.717.6µg/m3n-Hexane 70-130 97.019.920.5µg/m32-Hexanone 70-130 10212.512.3µg/m3Isopropyl Alcohol 70-130 Page 17 of 22Date:01/31/2024 03:04 PM Page 57 of 66 Quality Control Data 24-019-0015Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM.003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V42935QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V42920 LCS-V42920Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 99.314.714.8µg/m3Methyl Ethyl Ketone (MEK)70-130 97.019.920.5µg/m34-Methyl-2-Pentanone 70-130 91.916.017.4µg/m3Methylene Chloride 70-130 99.626.126.2µg/m3Naphthalene 70-130 1008.638.61µg/m3Propene 70-130 10221.821.3µg/m3Styrene 70-130 98.833.533.9µg/m3 70-130 96.514.214.7µg/m3 70-130 10018.818.8µg/m3 70-130 10026.926.9µg/m3 70-130 10228.728.1µg/m3 70-130 10926.924.6µg/m31,2,4-Trimethylbenzene 70-130 10726.424.6µg/m31,3,5-Trimethylbenzene 70-130 10122.021.7µg/m3o-Xylene 70-130 10244.443.4µg/m3m,p-Xylene 70-130 1044-Bromofluorobenzene (S)70-130 Page 18 of 22Date:01/31/2024 03:04 PM Page 58 of 66 Quality Control Data 24-019-0015Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM.003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V42931QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V42921 Associated Lab Samples: 94749, 94750, 94751, 94752, 94753, 94754 LRB-V42921 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 01/25/24 10:524.750.2021.07µg/m3Acetone 01/25/24 10:521.600.073<0.073µg/m3Benzene 01/25/24 10:526.230.060<0.060µg/m3Carbon Disulfide 01/25/24 10:523.150.155<0.155µg/m3Carbon Tetrachloride 01/25/24 10:522.440.086<0.086µg/m3Chloroform 01/25/24 10:521.030.067<0.067µg/m3Chloromethane 01/25/24 10:523.440.161<0.161µg/m3Cyclohexane 01/25/24 10:523.010.096<0.096µg/m31,2-Dichlorobenzene 01/25/24 10:523.010.186<0.186µg/m31,4-Dichlorobenzene 01/25/24 10:522.470.134<0.134µg/m3Dichlorodifluoromethane 01/25/24 10:521.980.095<0.095µg/m3cis-1,2-Dichloroethene 01/25/24 10:525.000.1690.414µg/m3Ethanol 01/25/24 10:522.170.106<0.106µg/m3Ethylbenzene 01/25/24 10:522.460.128<0.128µg/m34-Ethyltoluene 01/25/24 10:522.050.143<0.143µg/m3Heptane 01/25/24 10:521.760.047<0.047µg/m3n-Hexane 01/25/24 10:522.050.285<0.285µg/m32-Hexanone 01/25/24 10:524.920.1392.35µg/m3Isopropyl Alcohol 01/25/24 10:521.470.224<0.224µg/m3Methyl Ethyl Ketone (MEK) 01/25/24 10:522.050.121<0.121µg/m34-Methyl-2-Pentanone 01/25/24 10:521.740.488<0.488µg/m3Methylene Chloride 01/25/24 10:522.620.183<0.183µg/m3Naphthalene 01/25/24 10:520.8600.242<0.242µg/m3Propene 01/25/24 10:522.130.124<0.124µg/m3Styrene 01/25/24 10:523.390.181<0.181µg/m3 01/25/24 10:521.470.107<0.107µg/m3 01/25/24 10:521.880.090<0.090µg/m3 Page 19 of 22Date:01/31/2024 03:04 PM Page 59 of 66 Quality Control Data 24-019-0015Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM.003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V42931QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V42921 Associated Lab Samples: 94749, 94750, 94751, 94752, 94753, 94754 LRB-V42921 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 01/25/24 10:522.150.199<0.199µg/m3 01/25/24 10:522.810.130<0.130µg/m3 01/25/24 10:522.460.110<0.110µg/m31,2,4-Trimethylbenzene 01/25/24 10:522.460.236<0.236µg/m31,3,5-Trimethylbenzene 01/25/24 10:522.170.157<0.157µg/m3o-Xylene 01/25/24 10:525.650.217<0.217µg/m3m,p-Xylene 01/25/24 10:524-Bromofluorobenzene (S)96.9 70-130 LCS-V42921Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10011.911.9µg/m3Acetone 70-130 10016.016.0µg/m3Benzene 70-130 10316.015.6µg/m3Carbon Disulfide 70-130 98.731.131.5µg/m3Carbon Tetrachloride 70-130 10124.724.4µg/m3Chloroform 70-130 10210.510.3µg/m3Chloromethane 70-130 10117.317.2µg/m3Cyclohexane 70-130 11233.630.1µg/m31,2-Dichlorobenzene 70-130 11334.030.1µg/m31,4-Dichlorobenzene 70-130 10225.324.7µg/m3Dichlorodifluoromethane 70-130 10420.519.8µg/m3cis-1,2-Dichloroethene 70-130 95.48.999.42µg/m3Ethanol 70-130 10322.321.7µg/m3Ethylbenzene 70-130 10626.124.6µg/m34-Ethyltoluene 70-130 10020.620.5µg/m3Heptane 70-130 10218.017.6µg/m3n-Hexane 70-130 Page 20 of 22Date:01/31/2024 03:04 PM Page 60 of 66 Quality Control Data 24-019-0015Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM.003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V42931QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V42921 LCS-V42921Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10120.720.5µg/m32-Hexanone 70-130 10212.612.3µg/m3Isopropyl Alcohol 70-130 10114.914.8µg/m3Methyl Ethyl Ketone (MEK)70-130 10020.520.5µg/m34-Methyl-2-Pentanone 70-130 93.616.317.4µg/m3Methylene Chloride 70-130 10527.626.2µg/m3Naphthalene 70-130 1048.948.61µg/m3Propene 70-130 10221.821.3µg/m3Styrene 70-130 10134.433.9µg/m3 70-130 99.314.614.7µg/m3 70-130 10319.318.8µg/m3 70-130 10227.426.9µg/m3 70-130 10429.328.1µg/m3 70-130 11227.624.6µg/m31,2,4-Trimethylbenzene 70-130 11027.024.6µg/m31,3,5-Trimethylbenzene 70-130 10422.621.7µg/m3o-Xylene 70-130 10445.143.4µg/m3m,p-Xylene 70-130 1044-Bromofluorobenzene (S)70-130 Page 21 of 22Date:01/31/2024 03:04 PM Page 61 of 66 Quality Control Data 24-019-0015Report No: Project Description: Client ID:Hart & Hickman (Charlotte) PAM.003 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS V42985QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V42983 Associated Lab Samples: 94747, 94748, 94749, 94750, 94751, 94752, 94753 LRB-V42983 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 01/30/24 08:515.000.169<0.169µg/m3Ethanol 01/30/24 08:514-Bromofluorobenzene (S)98.6 70-130 LCS-V42983Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10710.19.42µg/m3Ethanol 70-130 1044-Bromofluorobenzene (S)70-130 Page 22 of 22Date:01/31/2024 03:04 PM Page 62 of 66 Fed Ex UPS US Postal Client Lab Courier Other : Shipment Receipt Form Customer Number: Customer Name: Report Number:24-019-0015 Hart & Hickman (Charlotte) 01102 Shipping Method Shipping container/cooler uncompromised? Thermometer ID:N/A Chain of Custody (COC) present?Yes No Yes No Not Present Yes No Not Present Yes No COC agrees with sample label(s)?Yes No COC properly completed Samples in proper containers? Sample containers intact? Sufficient sample volume for indicated test(s)? All samples received within holding time? Cooler temperature in compliance? Yes No Yes No Yes No Yes No Yes No Yes NoCooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. Yes No Yes No N/A Yes No N/A Yes No N/ASoil VOA method 5035 – compliance criteria met Water - Sample containers properly preserved Water - VOA vials free of headspace Yes No N/A Trip Blanks received with VOAs Low concentration EnCore samplers (48 hr) High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d) High concentration container (48 hr) Custody seals intact on shipping container/cooler? Custody seals intact on sample bottles? Number of coolers/boxes received Yes No 1 Signature:Angelo Norvell Date & Time:01/19/2024 13:24:59 Special precautions or instructions included? Comments: Page 63 of 66 Pa g e 6 4 o f 6 6 Pa g e 6 5 o f 6 6 Pa g e 6 6 o f 6 6 Appendix E DEQ Risk Calculator Summary Pages Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 2/19/2024 Prepared By:Hart & Hickman, PC Hart & Hickman, PC Pavilion Structure - Sub-Slab Vapor and Indoor Air Worst-Case (2023) North Carolina Department of Environmental Quality Risk Calculator North Davidson II Brownfields Site 2315 North Davidson St., Charlotte, NC DWM Brownfields 24003-20-060 February 2024 November 2023 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: February 2024 Basis: November 2023 EPA RSL Table Site ID: 24003-20-060 Exposure Unit ID: Pavilion Structure - Sub-Slab Vapor and Indoor Air Worst-Case (2023) Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: February 2024 Basis: November 2023 EPA RSL Table Site ID: 24003-20-060 Exposure Unit ID: Pavilion Structure - Sub-Slab Vapor and Indoor Air Worst-Case Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: February 2024 Basis: November 2023 EPA RSL Table Site ID: 24003-20-060 Exposure Unit ID: Pavilion Structure - Sub-Slab Vapor and Indoor Air Worst-Case (2023) Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 6.71 P-1 67-64-1 Acetone ug/m3 0.338 P-1 71-43-2 Benzene ug/m3 1.75 P-1 75-15-0 Carbon Disulfide ug/m3 3.51 P-1 67-66-3 Chloroform ug/m3 12.5 P-1 75-71-8 Dichlorodifluoromethane ug/m3 0.327 P-1 109-99-9 ~Tetrahydrofuran ug/m3 0.327 P-1 110-54-3 Hexane, N-ug/m3 1.21 P-1 67-63-0 Isopropanol ug/m3 0.751 P-1 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 2.07 P-1 75-09-2 Methylene Chloride ug/m3 1.46 P-1 91-20-3 ~Naphthalene ug/m3 63.8 P-1 127-18-4 Tetrachloroethylene ug/m3 1.13 P-1 108-88-3 Toluene ug/m3 2.54 P-1 71-55-6 Trichloroethane, 1,1,1-ug/m3 3.57 P-1 75-69-4 Trichlorofluoromethane ug/m3 1.06 P-1 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: February 2024 Basis: November 2023 EPA RSL Table Site ID: 24003-20-060 Exposure Unit ID: Pavilion Structure - Sub-Slab Vapor and Indoor Air Worst-Case (2023) Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes: CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 138 P-1 67-64-1 Acetone ug/m3 0.527 P-1 71-43-2 Benzene ug/m3 0.258 P-1 75-15-0 Carbon Disulfide ug/m3 0.706 P-1 74-87-3 Chloromethane ug/m3 2.32 P-1 75-71-8 Dichlorodifluoromethane ug/m3 1.72 P-1 109-99-9 ~Tetrahydrofuran ug/m3 0.831 P-1 142-82-5 Heptane, N-ug/m3 0.641 P-1 110-54-3 Hexane, N-ug/m3 1.5 P-1 591-78-6 Hexanone, 2-ug/m3 15.2 P-1 67-63-0 Isopropanol ug/m3 9.54 P-1 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 0.421 P-1 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 0.786 P-1 115-07-1 Propylene ug/m3 0.711 P-1 100-42-5 Styrene ug/m3 0.746 P-1 127-18-4 Tetrachloroethylene ug/m3 6.9 P-1 108-88-3 Toluene ug/m3 1.37 P-1 75-69-4 Trichlorofluoromethane ug/m3 0.491 P-1 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0.494 P-1 95-47-6 Xylene, o-ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: February 2024 Basis: November 2023 EPA RSL Table Site ID: 24003-20-060 Exposure Unit ID: Pavilion Structure - Sub-Slab Vapor and Indoor Air Worst-Case (2023) Receptor Pathway Carcinogenic Ris Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Ris Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.2E-07 5.2E-03 NO Indoor Air 3.5E-07 4.9E-02 NO Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: 3. NM = Not modeled, user did not check this pathway as complete. 4. NC = Pathway not calculated, required contaminant migration parameters were not entered. DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: February 2024 Basis: November 2023 EPA RSL Table Site ID: 24003-20-060 Exposure Unit ID: Pavilion Structure - Sub-Slab Vapor and Indoor Air Worst-Case (2023) CAS # Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 6.71 0.0671 -- 71-43-2 Benzene 0.338 0.00338 1.6E+00 2.6E+01 2.1E-09 2.6E-05 75-15-0 Carbon Disulfide 1.75 0.0175 -6.1E+02 5.7E-06 67-66-3 Chloroform 3.51 0.0351 5.3E-01 8.6E+01 6.6E-08 8.2E-05 75-71-8 Dichlorodifluoromethane 12.5 0.125 -8.8E+01 2.9E-04 109-99-9 ~Tetrahydrofuran 0.327 0.00327 -1.8E+03 3.7E-07 110-54-3 Hexane, N-0.327 0.00327 -6.1E+02 1.1E-06 67-63-0 Isopropanol 1.21 0.0121 -1.8E+02 1.4E-05 78-93-3 Methyl Ethyl Ketone (2-Butanone)0.751 0.00751 -4.4E+03 3.4E-07 75-09-2 Methylene Chloride 2.07 0.0207 1.2E+03 5.3E+02 1.7E-11 7.9E-06 91-20-3 ~Naphthalene 1.46 0.0146 3.6E-01 2.6E+00 4.0E-08 1.1E-03 127-18-4 Tetrachloroethylene 63.8 0.638 4.7E+01 3.5E+01 1.4E-08 3.6E-03 108-88-3 Toluene 1.13 0.0113 -4.4E+03 5.2E-07 71-55-6 Trichloroethane, 1,1,1-2.54 0.0254 -4.4E+03 1.2E-06 75-69-4 Trichlorofluoromethane 3.57 0.0357 -- 95-63-6 Trimethylbenzene, 1,2,4-1.06 0.0106 -5.3E+01 4.0E-05 Cumulative: 1.2E-07 5.2E-03 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air Version Date: February 2024 Basis: November 2023 EPA RSL Table Site ID: 24003-20-060 Exposure Unit ID: Pavilion Structure - Sub-Slab Vapor and Indoor Air Worst-Case (2023) CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 138 - - 71-43-2 Benzene 0.527 1.6E+00 2.6E+01 3.4E-07 4.0E-03 75-15-0 Carbon Disulfide 0.258 - 6.1E+02 8.4E-05 74-87-3 Chloromethane 0.706 - 7.9E+01 1.8E-03 75-71-8 Dichlorodifluoromethane 2.32 - 8.8E+01 5.3E-03 109-99-9 ~Tetrahydrofuran 1.72 - 1.8E+03 2.0E-04 142-82-5 Heptane, N-0.831 - 3.5E+02 4.7E-04 110-54-3 Hexane, N-0.641 - 6.1E+02 2.1E-04 591-78-6 Hexanone, 2-1.5 - 2.6E+01 1.1E-02 67-63-0 Isopropanol 15.2 - 1.8E+02 1.7E-02 78-93-3 Methyl Ethyl Ketone (2-Butanone)9.54 - 4.4E+03 4.4E-04 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)0.421 - 2.6E+03 3.2E-05 115-07-1 Propylene 0.786 - 2.6E+03 6.0E-05 100-42-5 Styrene 0.711 - 8.8E+02 1.6E-04 127-18-4 Tetrachloroethylene 0.746 4.7E+01 3.5E+01 1.6E-08 4.3E-03 108-88-3 Toluene 6.9 - 4.4E+03 3.2E-04 75-69-4 Trichlorofluoromethane 1.37 - - 95-63-6 Trimethylbenzene, 1,2,4- 0.491 - 5.3E+01 1.9E-03 95-47-6 Xylene, o- 0.494 - 8.8E+01 1.1E-03 Cumulative: 3.5E-07 4.9E-02 All concentrations are in u /3 Output Form 3F ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 2/19/2024 Prepared By:Hart & Hickman, PC Hart & Hickman, PC Pavilion Structure - Sub-Slab Vapor and Indoor Air Worst-Case (2024) North Carolina Department of Environmental Quality Risk Calculator North Davidson II Brownfields Site 2315 North Davidson St., Charlotte, NC DWM Brownfields 24003-20-060 February 2024 November 2023 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: February 2024 Basis: November 2023 EPA RSL Table Site ID: 24003-20-060 Exposure Unit ID: Pavilion Structure - Sub-Slab Vapor and Indoor Air Worst-Case (2024) Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: February 2024 Basis: November 2023 EPA RSL Table Site ID: 24003-20-060 Exposure Unit ID: Pavilion Structure - Sub-Slab Vapor and Indoor Air Worst-Case Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: February 2024 Basis: November 2023 EPA RSL Table Site ID: 24003-20-060 Exposure Unit ID: Pavilion Structure - Sub-Slab Vapor and Indoor Air Worst-Case (2024) Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes: CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 6.79 MP-P1 67-64-1 Acetone ug/m3 0.737 MP-P1 67-66-3 Chloroform ug/m3 13.4 MP-P1 75-71-8 Dichlorodifluoromethane ug/m3 0.968 MP-P1 100-41-4 Ethylbenzene ug/m3 1.57 MP-P1 109-99-9 ~Tetrahydrofuran ug/m3 0.334 MP-P1 110-54-3 Hexane, N-ug/m3 2.92 MP-P1 67-63-0 Isopropanol ug/m3 0.931 MP-P1 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 1.46 MP-P1 75-09-2 Methylene Chloride ug/m3 76.1 MP-P1 127-18-4 Tetrachloroethylene ug/m3 0.395 MP-P1 108-88-3 Toluene ug/m3 0.932 MP-P1 71-55-6 Trichloroethane, 1,1,1-ug/m3 1.74 MP-P1 75-69-4 Trichlorofluoromethane ug/m3 4.52 MP-P1 108-38-3 Xylene, m-ug/m3 1.53 MP-P1 95-47-6 Xylene, o-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: February 2024 Basis: November 2023 EPA RSL Table Site ID: 24003-20-060 Exposure Unit ID: Pavilion Structure - Sub-Slab Vapor and Indoor Air Worst-Case (2024) Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes: CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 14.7 IAS-P1 67-64-1 Acetone ug/m3 1.02 IAS-DUP 71-43-2 Benzene ug/m3 1.29 IAS-P1 75-15-0 Carbon Disulfide ug/m3 0.823 IAS-P1 74-87-3 Chloromethane ug/m3 2.79 IAS-P1 75-71-8 Dichlorodifluoromethane ug/m3 0.59 IAS-DUP 100-41-4 Ethylbenzene ug/m3 0.406 IAS-DUP 109-99-9 ~Tetrahydrofuran ug/m3 0.581 IAS-DUP 142-82-5 Heptane, N-ug/m3 0.687 IAS-P1 110-54-3 Hexane, N-ug/m3 3.97 IAS-P1 67-63-0 Isopropanol ug/m3 1.38 IAS-P1 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 1.54 IAS-P1 75-09-2 Methylene Chloride ug/m3 2.16 IAS-DUP 108-88-3 Toluene ug/m3 0.574 IAS-P1 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 1.63 IAS-P1 75-69-4 Trichlorofluoromethane ug/m3 2.21 IAS-DUP 108-38-3 Xylene, m-ug/m3 0.772 IAS-DUP 95-47-6 Xylene, o-ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: February 2024 Basis: November 2023 EPA RSL Table Site ID: 24003-20-060 Exposure Unit ID: Pavilion Structure - Sub-Slab Vapor and Indoor Air Worst-Case (2024) Receptor Pathway Carcinogenic Ris Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Ris Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 3.2E-08 4.8E-03 NO Indoor Air 7.7E-07 2.9E-02 NO Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not modeled, user did not check this pathway as complete. 4. NC = Pathway not calculated, required contaminant migration parameters were not entered. DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: February 2024 Basis: November 2023 EPA RSL Table Site ID: 24003-20-060 Exposure Unit ID: Pavilion Structure - Sub-Slab Vapor and Indoor Air Worst-Case (2024) CAS # Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 6.79 0.0679 -- 67-66-3 Chloroform 0.737 0.00737 5.3E-01 8.6E+01 1.4E-08 1.7E-05 75-71-8 Dichlorodifluoromethane 13.4 0.134 -8.8E+01 3.1E-04 100-41-4 Ethylbenzene 0.968 0.00968 4.9E+00 8.8E+02 2.0E-09 2.2E-06 109-99-9 ~Tetrahydrofuran 1.57 0.0157 -1.8E+03 1.8E-06 110-54-3 Hexane, N-0.334 0.00334 -6.1E+02 1.1E-06 67-63-0 Isopropanol 2.92 0.0292 -1.8E+02 3.3E-05 78-93-3 Methyl Ethyl Ketone (2-Butanone)0.931 0.00931 -4.4E+03 4.3E-07 75-09-2 Methylene Chloride 1.46 0.0146 1.2E+03 5.3E+02 1.2E-11 5.6E-06 127-18-4 Tetrachloroethylene 76.1 0.761 4.7E+01 3.5E+01 1.6E-08 4.3E-03 108-88-3 Toluene 0.395 0.00395 -4.4E+03 1.8E-07 71-55-6 Trichloroethane, 1,1,1-0.932 0.00932 -4.4E+03 4.3E-07 75-69-4 Trichlorofluoromethane 1.74 0.0174 -- 108-38-3 Xylene, m-4.52 0.0452 -8.8E+01 1.0E-04 95-47-6 Xylene, o-1.53 0.0153 -8.8E+01 3.5E-05 Cumulative: 3.2E-08 4.8E-03 All concentrations are in u /m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air Version Date: February 2024 Basis: November 2023 EPA RSL Table Site ID: 24003-20-060 Exposure Unit ID: Pavilion Structure - Sub-Slab Vapor and Indoor Air Worst-Case (2024) CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 14.7 - - 71-43-2 Benzene 1.02 1.6E+00 2.6E+01 6.5E-07 7.8E-03 75-15-0 Carbon Disulfide 1.29 - 6.1E+02 4.2E-04 74-87-3 Chloromethane 0.823 - 7.9E+01 2.1E-03 75-71-8 Dichlorodifluoromethane 2.79 - 8.8E+01 6.4E-03 100-41-4 Ethylbenzene 0.59 4.9E+00 8.8E+02 1.2E-07 1.3E-04 109-99-9 ~Tetrahydrofuran 0.406 - 1.8E+03 4.6E-05 142-82-5 Heptane, N-0.581 - 3.5E+02 3.3E-04 110-54-3 Hexane, N-0.687 - 6.1E+02 2.2E-04 67-63-0 Isopropanol 3.97 - 1.8E+02 4.5E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone)1.38 - 4.4E+03 6.3E-05 75-09-2 Methylene Chloride 1.54 1.2E+03 5.3E+02 1.3E-09 5.9E-04 108-88-3 Toluene 2.16 - 4.4E+03 9.9E-05 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-0.574 - 4.4E+03 2.6E-05 75-69-4 Trichlorofluoromethane 1.63 - - 108-38-3 Xylene, m- 2.21 - 8.8E+01 5.0E-03 95-47-6 Xylene, o- 0.772 - 8.8E+01 1.8E-03 Cumulative: 7.7E-07 2.9E-02 All concentrations are in u /3 Output Form 3F ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator