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HomeMy WebLinkAboutWS-5641_19846_CA_MRP_2023051720231597.001A | CLT23R153742 May 17, 2023 © 2023 Kleinfelder www.kleinfelder.com KLEINFELDER 9009 Perimeter Woods Drive | Suite E, Charlotte, NC 28216 p| 704.598.1049 May 17, 2023 Ms. April Haley Procter and Gamble Manufacturing Company Post Office Box 18647 Greensboro, North Carolina 27419 SUBJECT: 2023 Annual Groundwater Monitoring Report Procter and Gamble Manufacturing Company 6200 Bryan Park Road Browns Summit, North Carolina Dear Ms. Haley: Please find enclosed a copy of the Annual Groundwater Monitoring Report conducted at monitoring well MW-2R at the Browns Summit facility. A copy of this report has been submitted to the Guilford County Department of Environmental Health. Kleinfelder appreciates this opportunity to provide groundwater monitoring services to Procter and Gamble. Should questions arise or additional information be required, please contact the undersigned or Ms. Christine Brenk at 704.378.9175. Very truly yours, KLEINFELDER, INC. Thomas Sipe, PE Senior Professional Michael J. Burns, PG Program Manager TS/MJB:wma Enclosure WS-5641, #19846 20231597.001A | CLT23R153742 May 17, 2023 © 2023 Kleinfelder www.kleinfelder.com © 2023 Kleinfelder All Rights Reserved ONLY THE CLIENT OR ITS DESIGNATED REPRESENTATIVES MAY USE THIS DOCUMENT AND ONLY FOR THE SPECIFIC PROJECT FOR WHICH THIS REPORT WAS PREPARED. 2023 ANNUAL GROUNDWATER MONITORING REPORT PROCTER AND GAMBLE MANUFACTURING COMPANY BROWNS SUMMIT, NORTH CAROLINA KLEINFELDER PROJECT NO.: 20231597.001A May 17, 2023 20231597.001A | CLT23R153742 Page iii of iii May 17, 2023 © 2023 Kleinfelder www.kleinfelder.com TABLE OF CONTENTS 1.0 INTRODUCTION ............................................................................................................ 2 1.1 BACKGROUND .................................................................................................. 2 1.2 INCIDENT HISTORY .......................................................................................... 2 1.3 RECEPTOR INFORMATION .............................................................................. 4 2.0 FIELD ACTIVITIES ........................................................................................................ 5 2.1 SITE HYDROLOGY ............................................................................................ 5 2.2 GROUNDWATER SAMPLING AND ANALYSIS ................................................. 5 3.0 RESULTS ...................................................................................................................... 6 4.0 CONCLUSIONS ............................................................................................................. 7 5.0 LIMITATIONS ................................................................................................................ 8 TABLES 1 Monitoring Well and Groundwater Elevation Data 2 Historical Groundwater Elevation Data 3 Summary of Groundwater Sample Results FIGURES 1 Site Location Map 2 Site Plan 3 Monitoring Well Locations 4 Potentiometric Surface Map 5 Decamethylcyclopentasiloxane Concentration Compared with Groundwater Elevation APPENDIX Laboratory Report 20231597.001A | CLT23R153742 Page 2 of 8 May 17, 2023 © 2023 Kleinfelder www.kleinfelder.com 2023 ANNUAL GROUNDWATER MONITORING REPORT PROCTER AND GAMBLE MANUFACTURING COMPANY 6200 BRYAN PARK ROAD, BROWNS SUMMIT, NORTH CAROLINA 1 INTRODUCTION 1.1 BACKGROUND Kleinfelder has completed the Annual Groundwater Monitoring Event for the Procter and Gamble Manufacturing Company (P&G) facility located at 6200 Bryan Park Road in Browns Summit, Guilford County, North Carolina (Figure 1 and Figure 2). The purpose of the groundwater monitoring was to evaluate siloxane concentrations at monitoring wells surrounding a former leaking UST. 1.2 INCIDENT HISTORY The property is owned and operated by P&G and is used for the manufacture of personal care products. A silicone product used in manufacturing antiperspirants was historically stored in a portion of a segmented UST located on the west side of the facility (Figure 2). The 20,000-gallon UST contained 10,000 gallons of capacity for the silicone fluid and 10,000 gallons of capacity for perfume. The silicone fluid is an odorless, clear liquid containing decamethylcyclopentasiloxane (CAS registration number 541-02-6) and mixed cyclosiloxanes (CAS registration number 69430- 24-6). The UST was filled with sand and closed in-place in August 1998. Subsequent to the UST closure, monitoring well MW-1 was installed approximately 40 feet to the east of the closed in-place tank. In April of 2001, Kleinfelder installed one monitoring well (MW-2) adjacent to the UST formerly containing the silicone fluid. The base of the UST was within one foot of the water table; therefore, soil samples were not collected. The monitoring well was developed and groundwater samples were collected and analyzed for volatile organic compounds (VOCs) by EPA Method 8260 and semi-volatile organic compounds (SVOCs) by EPA Method 8270 including a 10 peak library search. The laboratory identified decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, and octamethylcyclotetrasiloxane by the SVOC library search. Since a North Carolina Groundwater Quality Standard (NCGQS) has not been established for siloxanes, detectable concentrations over the laboratory detection limits [10 micrograms per liter (µg/L)] serve as the practical groundwater standard. In January 2002, Kleinfelder installed three additional Type II monitoring wells, MW-3, MW-4, and MW-6, and one Type III monitoring well, MW-5D, to determine the horizontal and vertical extent of the contamination. The monitoring well 20231597.001A | CLT23R153742 Page 3 of 8 May 17, 2023 © 2023 Kleinfelder www.kleinfelder.com locations are shown on Figure 3. All of the monitoring wells were sampled during the comprehensive site assessment (CSA). The laboratory analytical results indicated that only two of the 6 groundwater samples contained decamethylcyclopentasiloxane. Decamethylcyclopentasiloxane was detected in monitoring well MW-1 at a concentration of 490 micrograms per liter (g/L) and in MW-2 at a concentration of 320,000 g/L. A Corrective Action Plan (CAP) was written to address the siloxane compounds in the vicinity of the UST. The CAP recommended Aggressive Fluid Vapor Recovery (AFVR) followed by natural attenuation. On July 12, 2002, Kleinfelder initiated the first AFVR event at monitoring wells MW- 1 and MW-2. The radius of influence from each extraction well during the extraction event was approximately 70 feet. The event lasted approximately eight hours and removed approximately 623 gallons of groundwater and silicone fluid. From July 12, 2002 to April 20, 2004, a total of 10 AFVR events were conducted at the site. Decamethylcyclopentasiloxane levels in MW-1 decreased from 490 μg/L to below the laboratory detection limits after the initial AFVR event. During the same time period, decamethylcyclopentasiloxane levels in MW-2 fluctuated between 320,000 μg/L to 2,200 μg/L. The fluctuation in contaminant levels in the vicinity of the UST indicated that contaminants in the soil were acting as a continuous source. In June of 2004, Kleinfelder was contracted to remove the UST and surrounding soil backfill in an attempt to remove the secondary source of decamethylcyclopentasiloxane to groundwater in the vicinity of the UST. Monitoring well MW-2 was abandoned prior to the UST removal. Soil backfill was excavated from the south and east sides of the UST and stockpiled for disposal. The UST was buried approximately three feet below ground surface and was 12 feet in diameter and 24 feet in length. No holes or areas of extensive corrosion were observed. The tank was cleaned, cut into scrap pieces, and taken to a metal recycling facility. Groundwater was observed seeping through the concrete ballast pad at an approximate depth of 16 feet below ground surface. Soil samples were not collected at the bottom of the excavation or sidewalls due to unstable conditions and presence of groundwater at the bottom of the excavation. A total of 6,369 gallons of water from the UST and 286 tons of stockpiled soil and sand were transported to a disposal facility. Following the removal of the UST, monitoring well MW-2R was installed to a depth of 33 feet with the screened interval from 13 to 33 feet. Monitoring well MW-1 had three sampling events with siloxane concentrations below the laboratory detection limits. Therefore, only monitoring well 20231597.001A | CLT23R153742 Page 4 of 8 May 17, 2023 © 2023 Kleinfelder www.kleinfelder.com MW-2R is typically sampled on an annual schedule. This report includes groundwater sample analytical results for the sample collected from MW-2R on April 18, 2023. 1.3 RECEPTOR INFORMATION Property within 1,500 feet of the source area is owned by P&G with the exception of the area to the southwest of Bryan Park Road (Figure 1). One water supply well is located approximately 600 feet north of the source area on the P&G property; however, the well has never been used. Based on the Division of Environmental Health Public Water Supply Section’s list of wellhead protection areas, there are no wellhead protection areas within Guilford County. The City of Greensboro receives its water supply from 3 surface water bodies: Lake Townsend, Lake Brandt, and Lake Higgins. The lakes and their intakes are at least 3,000 feet from the source area. Municipal water is available to the surrounding area. The closest surface water feature to the source area is a manmade retention pond located approximately 300 feet to the southwest (Figure 2). An unnamed tributary to Reedy Fork Creek is located approximately 1,500 feet northwest of the source area. The tributary flows northeast into Reedy Fork Creek that is dammed to form Hardy’s Mill Pond approximately 1,500 feet northeast of the source area. Another unnamed tributary to Reedy Fork Creek is located approximately 1,500 feet south of the source area. The concrete paved area in the vicinity of the former UST has a trench drain that empties into the retention pond located approximately 300 feet to the southwest (Figure 2). No other underground utilities or structures have been identified in the source area. Land use within 1,500 feet of the source area is primarily industrial and commercial; however, the majority of the property is open or wooded, undeveloped land. The site and surrounding area are zoned for industrial usage. 20231597.001A | CLT23R153742 Page 5 of 8 May 17, 2023 © 2023 Kleinfelder www.kleinfelder.com 2 FIELD ACTIVITIES 2.1 SITE HYDROLOGY The depth to groundwater of the six monitoring wells at the site (MW-1, MW-2R, MW-3, MW-4, MW-5D and MW-6) was measured on April 18, 2023. The depth to groundwater ranged from approximately 15.05 to 20.50 feet below top of casing. Groundwater and well construction details are summarized in Table 1. Information regarding historical groundwater elevations is summarized in Table 2. A potentiometric surface map was prepared and is presented in Figure 4. The potentiometric surface map shows groundwater flow predominately to the southeast in the shallow unconfined aquifer. The groundwater is flowing under an average gradient of 0.0098 feet per foot, as measured between MW-3 to MW-2R and 0.0454 as measured between MW-4 and MW-6. Based on an average groundwater gradient of 0.0276 feet per foot, a calculated hydraulic conductivity of 1.0 foot per day from the bail down tests conducted at MW-4 during the CSA, and an assumed porosity of 40-percent, the rate of groundwater flow was estimated to be about 0.069 feet per day (25.2 feet per year). 2.2 GROUNDWATER SAMPLING AND ANALYSIS Groundwater samples were collected from monitoring wells on April 18, 2023. The groundwater samples were sent to Waypoint Analytical, LLC (Waypoint) and analyzed for siloxanes by EPA Method 8270E. Prior to collecting the groundwater samples, the static water level in the monitoring wells were recorded and the monitoring wells were purged of approximately three well volumes of water using a new disposable bailer. After allowing the water level to recover, the groundwater samples were collected and placed in laboratory prepared containers. The groundwater samples were maintained on ice until delivery to Waypoint. A chain-of-custody document was utilized throughout the collection and transportation process and is included with the laboratory report in the Appendix. 20231597.001A | CLT23R153742 Page 6 of 8 May 17, 2023 © 2023 Kleinfelder www.kleinfelder.com 3 RESULTS Decamethylcyclopentasiloxane was detected in the groundwater sample collected from MW-2R at an estimated concentration of 30.7 g/L. Octamethylcyclotetrasiloxane was not detected in the groundwater sample collected from MW-2R. Groundwater laboratory analytical results are summarized in Table 3. Historical groundwater elevations were averaged and graphed to determine the range in groundwater fluctuation and frequency across the site. In order to make a comparison of the relative fluctuation of groundwater and contaminant concentration, contaminant levels from monitoring well MW-2R were also graphed. Figure 5 shows the correlation between groundwater elevation and contaminant concentration in MW-2R. 20231597.001A | CLT23R153742 Page 7 of 8 May 17, 2023 © 2023 Kleinfelder www.kleinfelder.com 4 CONCLUSIONS Laboratory analytical results of groundwater samples collected from monitoring well MW-2R indicated the presence of decamethylcyclopentasiloxane. The concentration of this constituent detected during the April 2023 monitoring event (30.7 g/L) was higher than the estimated concentration of 5.49 g/L during the April 2022 event and the estimated concentration of 10.8 g/L during the August 2022 event. Groundwater flow is to the southeast at an approximate rate of about 25.20 feet per year. No sensitive receptors or groundwater users have been identified within 1,500 feet of the release. The adjacent property in the direction of groundwater flow is more than 1,500 feet southeast of the former UST location. 20231597.001A | CLT23R153742 Page 8 of 8 May 17, 2023 © 2023 Kleinfelder www.kleinfelder.com 5 LIMITATIONS Kleinfelder offers various levels of investigative and engineering services to suit the varying needs of different clients. It should be recognized that definition and evaluation of geologic and environmental conditions are a difficult and inexact science. Judgments leading to conclusions and recommendations are generally made with incomplete knowledge of the subsurface conditions present due to the limitations of data from field studies. Although risk can never be eliminated, more-detailed and extensive studies yield more information, which may help understand and manage the level of risk. Since detailed study and analysis involves greater expense, our clients participate in determining levels of service that provide adequate information for their purposes at acceptable levels of risk. During the course of the performance of Kleinfelder’s services, hazardous materials may have been discovered. Kleinfelder assumes no responsibility or liability whatsoever for any claim, loss of property value, damage, or injury that results from pre-existing hazardous materials being encountered or present on the project site, or from the discovery of such hazardous materials. Nothing contained in this report should be construed or interpreted as requiring Kleinfelder to assume the status of an owner, operator, or generator, or person who arranges for disposal, transport, storage or treatment of hazardous materials within the meaning of any governmental statute, regulation or order. P&G is solely responsible for directing notification of all governmental agencies, and the public at large, of the existence, release, treatment or disposal of any hazardous materials observed at the project site, either before or during performance of Kleinfelder’s services. P&G is responsible for directing all arrangements to lawfully store, treat, recycle, dispose, or otherwise handle hazardous materials, including cuttings and samples resulting from Kleinfelder’s services. The information included on graphic representations in the Groundwater Monitoring Report has been compiled from a variety of sources and is subject to change without notice. Kleinfelder makes no representations or warranties, express or implied, as to accuracy, completeness, timeliness, or rights to the use of such information. These documents are not intended for use as a land survey product, nor are they designed or intended as a construction design document. The use or misuse of the information contained on these graphic representations is at the sole risk of the party using or misusing the information. 20231597.001A | CLT23R153742 May 17, 2023 © 2023 Kleinfelder www.kleinfelder.com TABLES WELL ID DATE INSTALLED SCREENED INTERVAL BOTTOM OF WELL (ft TOC) TOP OF CASING ELEVATION (ft TBM) DEPTH TO WATER (ft TOC) GROUNDWATER ELEVATION (ft TBM) MW-1 12/08/98 14 - 29 30.00 100.00 20.50 79.50 MW-2R 06/25/04 13 - 33 33.00 96.41 17.35 79.06 MW-3 12/18/01 15 - 25 24.69 95.95 16.40 79.55 MW-4 12/18/01 15 - 25 24.00 96.28 15.05 81.23 MW-5D 12/19/01 53 - 58 57.35 96.68 17.20 79.48 MW-6 12/20/01 15 - 25 23.31 94.98 16.93 78.05 NOTES: Groundwater Levels Measured on April 18, 2023 Temporary benchmark for elevation measurements is MW-1 at an assumed elevation of 100.00 feet ft bgs = feet below ground surface ft TOC = feet below top of well casing ft TBM = feet below temporary benchmark TABLE 1: MONITORING WELL AND GROUNDWATER ELEVATION DATA 20231597.001A Copyright 2023 Kleinfelder 5/16/2023 MW-1 MW-2R MW-3 MW-4 MW-5D MW-6 04/29/02 79.08 78.89 79.35 78.97 79.22 79.24 07/12/02 78.74 78.90 78.97 80.19 78.87 77.38 08/26/02 79.26 79.40 79.39 79.24 79.03 77.63 10/07/02 79.44 79.57 79.62 81.11 79.52 78.12 11/08/02 80.45 80.67 80.68 82.11 80.57 79.09 01/20/03 80.51 80.70 79.93 81.87 80.69 79.00 03/27/03 81.25 81.46 81.44 82.59 81.33 79.77 06/05/03 81.24 81.45 81.44 82.58 81.28 78.70 07/24/03 81.23 81.50 81.46 82.49 81.27 80.50 09/26/03 80.94 81.24 80.86 80.90 81.02 79.42 04/20/04 79.84 80.04 79.97 81.26 80.06 78.35 11/16/04 79.46 79.54 79.76 81.01 79.70 78.13 11/15/05 78.61 78.58 78.86 79.97 78.64 77.14 01/26/06 79.92 80.03 80.19 79.73 80.08 80.07 04/17/06 79.57 79.63 79.33 79.36 79.65 79.66 04/17/07 79.99 80.02 80.15 81.60 80.16 78.70 04/01/08 79.06 79.07 79.34 80.65 79.74 77.72 04/09/09 79.71 79.78 79.95 81.15 79.74 78.23 06/08/10 79.42 79.64 79.74 80.85 79.6 77.93 04/18/11 79.05 79.19 79.32 80.97 79.57 77.74 04/04/12 79.27 79.09 79.75 81.30 79.64 78.19 04/15/13 79.25 78.84 79.54 81.07 79.75 77.84 04/08/14 79.78 79.36 80.00 81.63 79.80 78.39 04/22/15 81.08 81.66 82.05 82.84 81.13 80.44 04/29/16 79.15 78.71 79.30 80.88 79.38 77.68 04/25/17 78.93 78.38 78.98 80.90 79.19 77.74 04/19/18 79.57 79.16 79.62 81.27 79.64 78.17 04/26/19 79.96 79.45 79.48 81.27 79.76 79.42 04/22/20 79.60 79.20 79.84 81.32 79.93 78.15 04/23/21 79.87 79.41 80.10 81.56 80.27 78.38 04/11/22 79.57 79.16 80.10 81.29 79.98 78.08 08/02/22 78.83 78.33 80.04 80.53 79.10 77.48 04/18/23 79.50 79.06 79.55 81.23 79.48 78.05 NOTE: ft TBM = feet below temporary benchmark GROUNDWATER ELEVATION (ft TBM)DATE Temporary benchmark for elevation measurements is MW-1 at an assumed elevation of 100.00 feet MW-2 was removed during the UST removal process. MW-2R was installed in the vicinity of the removed UST on June 25, 2004 TABLE 2: HISTORICAL GROUNDWATER ELEVATION DATA 20231597.001A Copyright 2023 Kleinfelder 5/16/2023 ANALYTICAL METHOD 8270 (Siloxanes only) Contaminant of Concern WELL ID DATE COLLECTED 11/14/01 490 < 40 06/11/02 < 10 < 10 07/25/02 < 10 < 10 11/16/04 < 10 < 10 04/22/20 < 10 < 50 08/02/22 < 5.20 < 25.9 MW-2 11/14/01 320,000 < 20,000 06/11/02 150,000 < 10,000 07/25/02 140,000 < 5,000 09/03/02 62,000 < 4,000 10/14/02 4,300 < 1,000 11/18/02 7,800 < 1,000 02/05/03 59,000 < 1,000 04/08/03 36,000 < 2,000 06/05/03 2,200 < 2000 08/01/03 8,000 < 2,000 10/06/03 49,000 < 4000 04/26/04 101,000 1,340 06/25/04 1,210 < 50 11/16/04 2,310 < 200 11/15/05 < 10 < 10 01/26/06 64 35.9 04/17/06 448 < 40 04/17/07 159 < 20 04/01/08 40.7 <5.1 04/09/09 160 15.3 06/08/10 184 13.5 04/18/11 176 < 27.4 04/04/12 1,170 < 52.6 04/15/13 160 3.3 04/08/14 540 11 A 04/22/15 650 16 04/29/16 44 < 10 04/25/17 250 E < 10 04/19/18 220 5.3 J 04/26/19 190 < 51 04/22/20 65 < 50 04/23/21 40.8 <25.3 04/11/22 5.49 J <25.5 08/02/22 10.8 <25.0 04/18/23 30.7 N.D. 12/28/01 < 10 < 10 04/22/20 < 10 < 50 08/02/22 < 5.00 < 25.0 12/28/01 < 10 < 10 04/22/20 < 10 < 50 08/02/22 < 5.00 < 25.0 01/02/02 < 10 < 10 04/22/20 < 10 < 50 08/02/22 < 5.20 < 26.1 12/28/01 < 10 < 10 04/22/20 < 10 < 50 08/02/22 < 5.00 < 25.0 NOTES: E = Estimated concentration above calibration range J = Estimated concentration below the Reporting Limit 2L Groundwater Standards have not been established for the compounds detected μg/L = micrograms per liter A = Analyte reported with possible low bias. Laboratory control sample recovery below the quality control limit. N.D. = Non-Detect MW-6 Decamethylcyclopentasiloxane (μg/L) Octamethylcyclotetrasiloxane (μg/L) TABLE 3: SUMMARY OF GROUNDWATER SAMPLE RESULTS MW-5D MW-1 MW-3 MW-4 MW-2R 20231597.001A Copyright 2023 Kleinfelder 5/16/2023 20231597.001A | CLT23R153742 May 17, 2023 © 2023 Kleinfelder www.kleinfelder.com FIGURES DATE: 05-16-2023 PROJECT NO: 20231597.001A SCALE: 1" = 2,000' APPROVED BY: SOURCE: USGS 7.5' TOPOGRAPHIC MAP, BROWNS SUMMIT QUADRANGLE Procter & Gamble Manufacturing Co. 6200 Bryan Park Road Browns Summit, North Carolina FIGURE 1 SITE LOCATION MAP x 3500 Gateway Centre Blvd., Suite 200 Morrisville, NC 27560 Phone: 919-755-5011 www.kleinfelder.com SITE CA D F I L E : \ \ k l e i n f e l d e r . c o m \ s h a r e s \ C H A R L O T T E - D A T A \ W O R K I N G \ E N V I R O \ C l i e n t P r o p o s a l a n d P r o j e c t F i l e s \ P r o c t e r & G a m b l e - B r o w n s S u m m i t \ P r o j e c t s \ 2 0 2 3 S u p p o r t \ G r o u n d w a t e r S a m p l i n g \ F i g u r e s \ I n d i v i d u a l F i g u r e s a n d C A D \ L A Y O U T : F I G U R E 1 POND x RA I L R O A D T R A C K S SUPPLY WELL TRENCH DRAIN INVESTIGATION AREA BR Y A N P A R K R O A D SUMMIT AVENUEThe information included on this graphic representation has been compiled from a variety of sources and is subject to change without notice. Kleinfelder makes no representations orwarranties, express or implied, as to accuracy, completeness, timeliness, or rights to the use ofsuch information. This document is not intended for use of a land survey product nor is itdesigned or intended as a construction design document. The use or misuse of the information contained on this graphic representation is at the sole risk of the party using or misusing the information. DATE: 05-16-2023 PROJECT NO: 20231597.001A SCALE: 1" = 400' APPROVED BY: DRAWN BY: TS/NL Procter & Gamble Manufacturing Co. 6200 Bryan Park Road Browns Summit, North Carolina FIGURE 2 SITE PLAN 3500 Gateway Centre Blvd., Suite 200 Morrisville, NC 27560 Phone: 919-755-5011 www.kleinfelder.com CAD FILE: \\kleinfelder.com\shares\CHARLOTTE-DATA\WORKING\ENVIRO\Client Proposal and Project Files\Procter & Gamble - Browns Summit\Projects\2023 Support\Groundwater Sampling\Figures\Individual Figures and CAD\ LAYOUT: FIGURE 2 MONITORING WELL LOCATION LEGEND MW-1 The information included on this graphic representation has been compiled from a variety of sources and is subject to change without notice. Kleinfelder makes no representations or warranties, express or implied, as to accuracy, completeness, timeliness, or rights to the use of such information. This document is not intended for use of a land survey product nor is itdesigned or intended as a construction design document. The use or misuse of the informationcontained on this graphic representation is at the sole risk of the party using or misusing theinformation. 0 20 40 80 GRAPHIC SCALE x TR A C K C TR A C K A MW-4 MW-1 MW-5D MW-6 MW-3 TR E N C H D R A I N TANK FARM MW-2R CATCH BASIN FORMER PERFUME UST FORMER SILICONE/ PERFUME UST SHED SILO SILO DATE: 05-16-2023 PROJECT NO: 20231597.001A SCALE: 1" = 40' APPROVED BY: Procter & Gamble Manufacturing Co. 6200 Bryan Park Road Browns Summit, North Carolina FIGURE 3 MONITORING WELL LOCATIONS DRAWN BY: TS/NL 3500 Gateway Centre Blvd., Suite 200 Morrisville, NC 27560 Phone: 919-755-5011 www.kleinfelder.com CA D F I L E : \ \ k l e i n f e l d e r . c o m \ s h a r e s \ C H A R L O T T E - D A T A \ W O R K I N G \ E N V I R O \ C l i e n t P r o p o s a l a n d P r o j e c t F i l e s \ P r o c t e r & G a m b l e - B r o w n s S u m m i t \ P r o j e c t s \ 2 0 2 3 S u p p o r t \ G r o u n d w a t e r S a m p l i n g \ F i g u r e s \ I n d i v i d u a l F i g u r e s a n d C A D \ L A Y O U T : F I G U R E 3 MONITORING WELL LOCATION WITH GROUNDWATER ELEVATION GROUNDWATER CONTOUR LINE LEGEND MW-1 (79.50) 80.0 GROUNDWATER ELEVATIONS WERE MEASURED AUGUST 2, 2022. MONITORING WELL MW-5D IS SCREENED BELOW THE WATER TABLE AND WAS NOT USED TO GENERATE GROUNDWATER CONTOUR LINES. The information included on this graphic representation has been compiled from a variety ofsources and is subject to change without notice. Kleinfelder makes no representations orwarranties, express or implied, as to accuracy, completeness, timeliness, or rights to the use ofsuch information. This document is not intended for use of a land survey product nor is it designed or intended as a construction design document. The use or misuse of the information contained on this graphic representation is at the sole risk of the party using or misusing the information. 0 20 40 80 GRAPHIC SCALE x TR A C K C TR A C K A TR E N C H D R A I N TANK FARMCATCH BASIN FORMER PERFUME UST FORMER SILICONE/ PERFUME UST DIRECTION OF GROUNDWATER FLOW79.5 SHED SILO SILO MW-1 (79.50) MW-6 (78.05) MW-4 MW-2R (79.06) MW-3 (79.55) MW-5D (79.48) (81.23) 79.5 80.0 79. 0 78.5 80.5 81.0 DATE: 05-16-2023 PROJECT NO: 20231597.001A SCALE: 1" = 40' APPROVED BY: Procter & Gamble Manufacturing Co. 6200 Bryan Park Road Browns Summit, North Carolina FIGURE 4 POTENTIOMETRIC SURFACE MAP DRAWN BY: TS/NL 3500 Gateway Centre Blvd., Suite 200 Morrisville, NC 27560 Phone: 919-755-5011 www.kleinfelder.com CA D F I L E : \ \ k l e i n f e l d e r . c o m \ s h a r e s \ C H A R L O T T E - D A T A \ W O R K I N G \ E N V I R O \ C l i e n t P r o p o s a l a n d P r o j e c t F i l e s \ P r o c t e r & G a m b l e - B r o w n s S u m m i t \ P r o j e c t s \ 2 0 2 3 S u p p o r t \ G r o u n d w a t e r S a m p l i n g \ F i g u r e s \ I n d i v i d u a l F i g u r e s a n d C A D \ L A Y O U T : F I G U R E 4 77 78 79 80 81 82 83 84 1 10 100 1,000 10,000 100,000 1,000,000 Nov-01 May-03 Nov-04 May-06 Nov-07 May-09 Nov-10 May-12 Nov-13 May-15 Nov-16 May-18 Nov-19 May-21 Nov-22 Gr o u n d w a t e r E l e v a t i o n ( f t T B M ) Co n c e n t r a t i o n ( u g / L ) Date Figure 5: Decamethylcyclopentasiloxane Concentration Compared with Groundwater Elevation MW-2 DMCPS Concentration Average Groundwater Elevation Note: DMCPS = Decamethylcyclopentasiloxane 20231597.001A | CLT23R153742 May 17, 2023 © 2023 Kleinfelder www.kleinfelder.com APPENDIX A LABORATORY REPORT   Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.   5/12/2023 Kleinfelder SE, Inc. (Charlotte) Thomas Sipe 9009 Perimeter Woods Drive Suite E Charlotte, NC, 28216 Ref: Analytical Testing Revised Lab Report Number: 23-109-9008 (Original Report 23-109-0008) Client Project Description: P&G (Siloxanes) Dear Thomas Sipe: Waypoint Analytical, LLC (Charlotte) received sample(s) on 4/19/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Terri W Cole Laboratory Project Manager Page 1 of 7 Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date 07/31/202337735State ProgramNorth Carolina 12/31/2023402State ProgramNorth Carolina 07/31/202399012State ProgramSouth Carolina 12/31/202299012State ProgramSouth Carolina Page 1 of 1 00016/23-109-9008 Page 2 of 7 Report Number: Sample Summary Table Client Project Description: 23-109-9008 P&G (Siloxanes) Lab No Client Sample ID Matrix Date Collected Date Received 04/18/2023 10:40Aqueous 94292 MW-2R 04/19/2023 13:23 Page 3 of 7   Client: Kleinfelder SE, Inc. (Charlotte) CASE NARRATIVE Project: P&G (Siloxanes) Lab Report Number: 23-109-9008 Date: 5/12/2023 This is a revised report and supersedes the original laboratory report dated 5/11/23. The reporting units have been corrected. Page 4 of 7 Sample ID Report Lab NoLRB-V32379 23-109-0008 LRB Paramater Result Units Dilution Factor Method Analysis Date/Time Analyst Batch ID Hexadecanoic Acid 21.9 ug/L 1 8270 4/26/2023 10:34 APANN V32490 Sample ID Report Lab No MW-2R 23-109-0008 94292 Paramater Result Units Dilution Factor Method Analysis Date/Time Analyst Batch ID Decamethylcyclopentasilox ane 30.7 ug/L 1 8270 4/26/2023 15:35 APANN V32490Octamethylcyclotetrasiloxa ne N.D. ug/L 1 8270 4/26/2023 15:35 APANN V32490 Page 5 of 7 Fed Ex UPS US Postal Client Lab Courier Other : Shipment Receipt Form Customer Number: Customer Name: Report Number:23-109-0008 Kleinfelder SE, Inc. (Charlotte) 01122 Shipping Method Shipping container/cooler uncompromised? Thermometer ID:IRT15 3.7C Chain of Custody (COC) present?Yes No Yes No Not Present Yes No Not Present Yes No COC agrees with sample label(s)? Yes No COC properly completed Samples in proper containers? Sample containers intact? Sufficient sample volume for indicated test(s)? All samples received within holding time? Cooler temperature in compliance? Yes No Yes No Yes No Yes No Yes No Yes NoCooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. Yes No Yes No N/A Yes No N/A Yes No N/ASoil VOA method 5035 – compliance criteria met Water - Sample containers properly preserved Water - VOA vials free of headspace Yes No N/A Trip Blanks received with VOAs Low concentration EnCore samplers (48 hr) High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d) High concentration container (48 hr) Custody seals intact on shipping container/cooler? Custody seals intact on sample bottles? Number of coolers/boxes received Yes No 1 Signature:Angelo Norvell Date & Time:04/19/2023 15:18:32 Special precautions or instructions included? Comments: Page 6 of 7 Page 7 of 7