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HomeMy WebLinkAboutPRLF571_20240116_RA-16d_Crawlspace Air Sampling_Report2401 Brentwood Road, Suite 107 Raleigh, NC 27604 P (919) 873-2211 F (919) 873-9555 Terracon.com January 16, 2024 Sean Gallagher NCDEQ – Division of Waste Management Special Remediation Branch – Pre-Regulatory Landfill Unit 1646 Mail Service Center Raleigh, NC 27699-1646 Subject: Remedial Action Phase – Task Order 571RA-16d Albemarle Dump Nanny Drive Albemarle, Stanly County, North Carolina ID # NONCD0000571 State Contract # N42621-A Terracon Project # 71237029 Dear Mr. Gallagher: Terracon Consultants, Inc. (Terracon) is pleased to submit this letter summarizing crawlspace sampling activities for the former Albemarle Dump (site). This report has been prepared in general accordance with Terracon’s work plan for 571RA-16d dated November 7, 2023, and North Carolina Department of Environmental Quality (NCDEQ) Approval of Work Plan and Cost Proposal – Task Order 571RA-16d, dated November 9, 2023. These activities were requested by the NCDEQ Division of Waste Management (DWM), Superfund Section – Special Remediation Branch (SRB) Pre-Regulatory Landfill (PRLF) Unit project manager (Unit PM) at 32311 and 32322 Nanny Drive. Task Order 571RA-16d: Crawlspace Air Assessment – Residential Properties 32311 and 32322 Nanny Drive Terracon placed radial symmetry diffusive air samplers (Radiello®) in the crawlspace of each of the residences. The samples were collected to evaluate the potential presence of chlorinated solvents and Volatile Organic Compounds (VOCs) in the crawlspaces. Three samplers were placed in each residential crawl space. In addition, one duplicate sampler and one sampler in an outdoor/background sample location were placed for air sample collection. Albemarle Dump – NONCD0000571 Remedial Action Phase 571RA-16d | Albemarle, NC January 16, 2024| Terracon Project No. 71237029 Facilities | Environmental | Geotechnical | Materials 2 Terracon mobilized to the site on November 28, 2023, to deploy the Radiello® samplers in accordance with Terracon’s Standard Operating Procedures (SOP), laboratory provided instructions, and guidance from NCDEQ DWM. Sample location information as follows: Sample ID Address Location/ Notes On December 5, 2023, seven days following deployment, Terracon returned to the site to retrieve the samplers and prepare them for shipment to the laboratory for analysis. The six residential crawlspace samples, one duplicate, and one background sample were shipped via FedEx to Eurofins Air Toxics, LLC (Eurofins) in Folsom, California, and analyzed for chlorinated VOCs (CVOCs) and VOCs via Modified EPA Method TO-17. Field notes recorded during Radiello deployment and retrieval are included in Appendix A. Sampling locations are shown on Exhibit 1. Analytical Results and Risk Evaluation The laboratory analytical report provided by Eurofins indicated CVOCs and VOCs were detected at concentrations above laboratory method detection limits. At the direction of the Unit PM and in accordance with the DWM Trichloroethylene (TCE) Indoor Air Inhalation Immediate Action Levels (IAL) and Response (TCE Guidance) dated July 2019, Terracon compared the resulting concentrations of TCE to the Residential IAL of 2.1 µg/m3 to evaluate the need for immediate mitigation efforts to eliminate and/or reduce exposure concentrations. Detected concentrations of TCE did not exceed the Residential IAL, and mitigation efforts were not required. The laboratory reports are included in Appendix B and results are summarized on Table 1 Although TCE alone did not exceed its Residential IAL, a cumulative risk evaluation was completed using the July 2023 NCDEQ Risk Calculator. The detected concentrations of constituents at each sample location were entered into the NCDEQ Risk Calculator. Default exposure parameter values (e.g., lifetime, body weight, exposure duration) in the NCDEQ Risk Calculator were used for the evaluations. A cumulative carcinogenic risk of 1E-04 and a hazard index (HI) of 1.0 (cumulative non-carcinogenic risk) were also used as the target risk thresholds. Exceedance of one or more of the target risk thresholds indicate an unacceptable level of risk for that exposure pathway and receptor. The risk calculator evaluations are included in Appendix C and results are summarized on Table 1. Albemarle Dump – NONCD0000571 Remedial Action Phase 571RA-16d | Albemarle, NC January 16, 2024| Terracon Project No. 71237029 Facilities | Environmental | Geotechnical | Materials 3 The results of the NCDEQ Risk Calculator evaluation did not exceed risk thresholds for residential indoor air. If you have any questions, please contact Michael Dail at (984) 202-4055. Sincerely, Terracon Consultants, Inc. Erin E. Greene Michael B. Dail, PG Project Geologist Senior Geologist Allison K. Stenger Project Scientist Attachments: Exhibit 1 – Radiello® Sample Locations Map Table 1 – Radiello® Analytical Results Appendix A – Field Notes Appendix B – Laboratory Analytical Reports and Chain of Custody Records Appendix C – North Carolina Department of Environmental Quality Risk Calculations Exhibit WDA-B 571-RES-05 DUP-RES 571-RES-06 571-RES-04 571-RES-BKG 571-RES-03 571-RES-01 571-RES-02 1 EXHIBIT NO. Pre-Regulatory Landfill Albemarle Dump Site ID No. NONCD0000571 Albemarle, Stanly County, North Carolina Radiello® Sample Locations Map Phone: (919) 873-2211 Fax: (919) 873-9555 Raleigh, NC 276042401 Brentwood Road, Suite 107January 2024Date: Albermarle Maps Filename: 1 in = 90 ftScale: 71237029 Project No. MBDApproved By: EGChecked By: NSRDrawn By: EGPM: 0 90 18045 Feet Site Parcel Boundary Stanly County Parcels Disposal Area B Radiello® Sample Locations N : \ G I S \ 2 0 2 3 \ 7 1 2 3 7 0 2 9 _ N a n n y D r i v e \ M a p s \ P R L F M a p s \ A l b e r m a r l e M a p s \ A l b e r m a r l e M a p s . a p r x DATA SOURCES: Bing Aerial Basemap 2024; Parcels based on NC One Map Stanly County Table Task Order 571RA-16d | NONCD0000571 Albemarle Dump | Albemarle, NC January 2024 | Terracon Project No. 71237029 571-RES-01 571-RES-02 571-RES-03 571-RES-04 571-RES-06 571-RES-BKG 12/5/2023 12/5/2023 12/5/2023 12/5/2023 12/5/2023 12/5/2023 12/5/2023 12/5/2023 Analyte Unit DUP-RES 1,2,4-Trimethylbenzene ug/m3 0.32 0.39 0.26 ND ND ND ND ND 1,4-Dichlorobenzene ug/m3 0.48 0.46 0.41 ND ND ND ND ND 2-Butanone ug/m3 1.4 1.2 1.3 ND ND ND ND ND Benzene ug/m3 1.6 1.5 1.4 ND ND ND ND ND Carbon Tetrachloride ug/m3 0.18 0.20 0.17 0.19 0.19 0.18 0.18 0.15 Ethanol ug/m3 5.8 2.4 4.8 ND ND ND ND ND Ethylbenzene ug/m3 0.30 0.30 0.25 ND ND ND ND ND Hexane ug/m3 0.59 0.54 0.44 ND 0.16 ND ND 0.15 m,p-Xylenes ug/m3 0.86 0.85 0.71 ND 0.17 0.14 ND ND n-Heptane ug/m3 0.33 0.34 0.27 ND ND ND ND ND O-Xylene ug/m3 0.28 0.27 0.22 ND ND ND ND ND Tetrachloroethene ug/m3 0.28 0.32 0.27 1.4 0.55 0.50 0.71 ND Toluene ug/m3 1.8 1.8 1.5 0.34 0.38 0.34 0.33 0.31 Trichloroethene ug/m3 ND ND ND 0.29 ND ND 0.14 ND 7.9E-02 7.7E-02 6.8E-02 1.7E-01 1.7E-02 NE 8.6E-02 NE No No No No No NE No NE Notes: ug/m3 - micrograms per meter cubed EPA – Environmental Protection Agency A duplicate sample was collected from the 571-RES-05 location The NCDEQ Risk Calculator evaluation is provided in Appendix C NE - Not evaluated Modified EPA TO-17 571-RES-05 Table 1 Radiello® Analytical Results Sam le Location Sam le Date NCDEQ Risk Calculator Results Risk Exceedance Yes/No Residential Indoor Air Hazard Index 1 Facilities | Environmental | Geotechnical | Materials Appendix A Field Notes Appendix B Laboratory Analytical Report and Chain of Custody 12/12/2023 Ms. Erin Greene Terracon Consulting Engineers 2701 Westport Road Charlotte NC 28208 Project Name: Albemarle Dump Project #: 71237029 Dear Ms. Erin Greene The following report includes the data for the above referenced project for sample(s) received on 12/7/2023 at Eurofins Air Toxics LLC. The data and associated QC analyzed by Passive S.E. RAD130/SKC are compliant with the project requirements or laboratory criteria with the exception of the deviations noted in the attached case narrative. Thank you for choosing Eurofins Air Toxics LLC. for your air analysis needs. Eurofins Air Toxics Inc. is committed to providing accurate data of the highest quality. Please feel free to contact the Project Manager: Brian Whittaker at 916-985-1000 if you have any questions regarding the data in this report. Regards, Brian Whittaker Project Manager Workorder #: 2312126 Page 1 of 28 Ms. Erin Greene Terracon Consulting Engineers 2701 Westport Road Charlotte, NC 28208 WORK ORDER #: 2312126 CLIENT:BILL TO: PHONE: Accounts Payable Terracon Consulting Engineers 2701 Westport Road Charlotte, NC 28208 704-509-1777 704-509-1888 12/07/2023 DATE COMPLETED:12/12/2023 P.O. #71237029 PROJECT #71237029 Albemarle Dump Work Order Summary FAX: DATE RECEIVED:CONTACT:Brian Whittaker NAMEFRACTION #TEST 01A 571-RES-01_20231205 Passive S.E. RAD130/SKC 02A 571-RES-02_20231205 Passive S.E. RAD130/SKC 03A 571-RES-03_20231205 Passive S.E. RAD130/SKC 04A 571-RES-04_20231205 Passive S.E. RAD130/SKC 05A 571-RES-05_20231205 Passive S.E. RAD130/SKC 06A 571-RES-06_20231205 Passive S.E. RAD130/SKC 07A 571-RES-BKG_20231205 Passive S.E. RAD130/SKC 08A DUP-RES_20231205 Passive S.E. RAD130/SKC 09A Lab Blank Passive S.E. RAD130/SKC 10A CCV Passive S.E. RAD130/SKC 11A LCS Passive S.E. RAD130/SKC 11AA LCSD Passive S.E. RAD130/SKC CERTIFIED BY: Technical Director DATE: 12/12/23 Page 2 of 28 Certification numbers: AZ Licensure AZ0775, FL NELAP – E87680, LA NELAP – 02089, NH NELAP – 209222, NJ NELAP - CA016, NY NELAP - 11291, TX NELAP – T104704434-22-18, UT NELAP – CA009332022-14, VA NELAP - 12240, WA ELAP - C935 Name of Accreditation Body: NELAP/ORELAP (Oregon Environmental Laboratory Accreditation Program) CA300005-017 Eurofins Environment Testing Northern California, LLC certifies that the test results contained in this report meet all requirements of the 2016 TNI Standard. This report shall not be reproduced, except in full, without the written approval of Eurofins Air Toxics, LLC. 180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630 (916) 985-1000 LABORATORY NARRATIVE RAD130 Passive SE by Mod EPA TO-17 Terracon Consulting Engineers Workorder# 2312126 Eight Radiello 130 (Solvent) samples were received on December 07, 2023. The laboratory analyzed the charcoal sorbent bed of the passive sampler following modified method EPA TO-17. The VOCs were chemically extracted using carbon disulfide and an aliquot of the extract was injected into a GC/MS for identification and quantification of volatile organic compounds (VOCs). The mass of each target compound adsorbed by the sampler was converted to units of concentration using the sample deployment time and the sampling rate for each VOC. If sampling rates were calculated by the lab or the manufacturer, the concentration result has been flagged as an estimated value. Results are not corrected for desorption efficiency. The reference method used for this procedure is EPA TO-17, which describes the collection of VOCs in ambient air using sorbents and analysis by GC/MS. Because TO-17 describes active sample collection using a pump and thermal desorption as the preparation step, several modifications are required. Modifications to TO-17 are listed in the table below: Requirement ATL ModificationsTO-17 Sample Collection Pump pulls measured air volume through sorbent tube VOCs in air adsorbed onto sorbent bed passively through diffusion Sample Preparation Thermal extraction Solvent extraction Sorbent tube conditioning Condition newly packed tubes prior to use Charcoal-based sorbent is a single use media and conditioning is conducted by vendor. Instrumentation Thermal desorption introduction system Liquid injection introduction system Internal Standard Gas-phase internal standard introduced on the tube or focusing trap during analysis Liquid-phase internal standard introduced on the tube at the time of extraction Media and sample storage <4 deg C, 30 days Media shelf life is determined by vendor; sample hold-time is 6 months for the RAD130 and WMS. Sample preservation requirements are storage in a cool, solvent-free refrigerator and optional use of ice during shipping. Internal Standard Recovery +/-40% of daily CCV area -50% to +100% of daily CCV area Receiving Notes The Chain of Custody (COC) was not relinquished properly. A time was not provided by the field sampler. The uptake rates were corrected based on average field temperatures if provided. In the absence of Analytical Notes Page 3 of 28 field temperatures, the uptake rates determined at 25 deg C were used. If validated uptake rates were not available, rates were estimated using the chemical's diffusion coefficient in air and the geometric constant of the sampler. Chemicals that are poorly retained by the sorbent over the sampling duration may exhibit a low bias. All concentrations calculated using estimated rates are qualified with a "C" flag. To calculate ug/m3 concentrations in the Lab Blank, a sampling duration of 10122 minutes was applied. The assumed temperature used for the uptake rate is listed on the data page. If the field temperatures were provided, the rate was adjusted in the same manner as the field samples. Ten qualifiers may have been used on the data analysis sheets and indicate as follows: B - Compound present in laboratory blank greater than reporting limit (background subtraction not performed). J - Estimated value. E - Exceeds instrument calibration range. S - Saturated peak. Q - Exceeds quality control limits. U - Compound analyzed for but not detected above the reporting limit. UJ- Non-detected compound associated with low bias in the CCV N - The identification is based on presumptive evidence. C - Estimated concentration due to calculated sampling rate CN - See case narrative explanation. File extensions may have been used on the data analysis sheets and indicates as follows: a-File was requantified b-File was quantified by a second column and detector r1-File was requantified for the purpose of reissue Definition of Data Qualifying Flags Page 4 of 28 VOCS BY PASSIVE SAMPLER - GC/MS Summary of Detected Compounds Client Sample ID: 571-RES-01_20231205 Lab ID#: 2312126-01A (ug/m3)(ug)(ug/m3)(ug)Compound AmountAmountRpt. LimitRpt. Limit 1.0 0.97 6.0 5.8Ethanol 0.10 0.15 0.39 0.59Hexane 0.20 0.25 1.1 1.42-Butanone (Methyl Ethyl Ketone) 0.10 0.15 0.12 0.18Carbon Tetrachloride 0.40 0.50 1.3 1.6Benzene 0.10 0.17 0.19 0.33Heptane 0.10 0.13 1.3 1.8Toluene 0.10 0.17 0.16 0.28Tetrachloroethene 0.10 0.14 0.21 0.30Ethyl Benzene 0.10 0.14 0.61 0.86m,p-Xylene 0.10 0.15 0.18 0.28o-Xylene 0.10 0.19 0.25 0.481,4-Dichlorobenzene 0.10 0.20 0.16 0.321,2,4-Trimethylbenzene Client Sample ID: 571-RES-02_20231205 Lab ID#: 2312126-02A (ug/m3)(ug)(ug/m3)(ug)Compound AmountAmountRpt. LimitRpt. Limit 1.0 0.97 2.5 2.4Ethanol 0.10 0.15 0.36 0.54Hexane 0.20 0.25 0.97 1.22-Butanone (Methyl Ethyl Ketone) 0.10 0.15 0.14 0.20Carbon Tetrachloride 0.40 0.50 1.2 1.5Benzene 0.10 0.17 0.20 0.34Heptane 0.10 0.13 1.3 1.8Toluene 0.10 0.17 0.19 0.32Tetrachloroethene 0.10 0.15 0.20 0.30Ethyl Benzene 0.10 0.14 0.60 0.85m,p-Xylene 0.10 0.15 0.18 0.27o-Xylene 0.10 0.19 0.24 0.461,4-Dichlorobenzene 0.10 0.20 0.20 0.391,2,4-Trimethylbenzene Page 5 of 28 VOCS BY PASSIVE SAMPLER - GC/MS Summary of Detected Compounds Client Sample ID: 571-RES-03_20231205 Lab ID#: 2312126-03A (ug/m3)(ug)(ug/m3)(ug)Compound AmountAmountRpt. LimitRpt. Limit 1.0 0.97 4.9 4.8Ethanol 0.10 0.15 0.29 0.44Hexane 0.20 0.25 1.0 1.32-Butanone (Methyl Ethyl Ketone) 0.10 0.15 0.11 0.17Carbon Tetrachloride 0.40 0.50 1.1 1.4Benzene 0.10 0.17 0.16 0.27Heptane 0.10 0.13 1.1 1.5Toluene 0.10 0.17 0.16 0.27Tetrachloroethene 0.10 0.15 0.17 0.25Ethyl Benzene 0.10 0.14 0.50 0.71m,p-Xylene 0.10 0.15 0.14 0.22o-Xylene 0.10 0.19 0.21 0.411,4-Dichlorobenzene 0.10 0.20 0.13 0.261,2,4-Trimethylbenzene Client Sample ID: 571-RES-04_20231205 Lab ID#: 2312126-04A (ug/m3)(ug)(ug/m3)(ug)Compound AmountAmountRpt. LimitRpt. Limit 0.10 0.15 0.13 0.19Carbon Tetrachloride 0.10 0.14 0.20 0.29Trichloroethene 0.10 0.13 0.25 0.34Toluene 0.10 0.17 0.81 1.4Tetrachloroethene Client Sample ID: 571-RES-05_20231205 Lab ID#: 2312126-05A (ug/m3)(ug)(ug/m3)(ug)Compound AmountAmountRpt. LimitRpt. Limit 0.10 0.15 0.10 0.16Hexane 0.10 0.15 0.13 0.19Carbon Tetrachloride 0.10 0.13 0.29 0.38Toluene 0.10 0.17 0.33 0.55Tetrachloroethene 0.10 0.14 0.12 0.17m,p-Xylene Page 6 of 28 VOCS BY PASSIVE SAMPLER - GC/MS Summary of Detected Compounds Client Sample ID: 571-RES-06_20231205 Lab ID#: 2312126-06A (ug/m3)(ug)(ug/m3)(ug)Compound AmountAmountRpt. LimitRpt. Limit 0.10 0.15 0.12 0.18Carbon Tetrachloride 0.10 0.14 0.10 0.14Trichloroethene 0.10 0.13 0.25 0.33Toluene 0.10 0.17 0.42 0.71Tetrachloroethene Client Sample ID: 571-RES-BKG_20231205 Lab ID#: 2312126-07A (ug/m3)(ug)(ug/m3)(ug)Compound AmountAmountRpt. LimitRpt. Limit 0.10 0.15 0.10 0.15Hexane 0.10 0.15 0.10 0.15Carbon Tetrachloride 0.10 0.13 0.23 0.31Toluene Client Sample ID: DUP-RES_20231205 Lab ID#: 2312126-08A (ug/m3)(ug)(ug/m3)(ug)Compound AmountAmountRpt. LimitRpt. Limit 0.10 0.15 0.12 0.18Carbon Tetrachloride 0.10 0.13 0.25 0.34Toluene 0.10 0.17 0.30 0.50Tetrachloroethene 0.10 0.14 0.10 0.14m,p-Xylene Page 7 of 28 Client Sample ID: 571-RES-01_20231205 Lab ID#: 2312126-01A VOCS BY PASSIVE SAMPLER - GC/MS 18120718simFile Name: Dil. Factor:1.00 Date of Collection: 12/5/23 12:48:00 PM Date of Analysis: 12/7/23 03:39 PM Date of Extraction: 12/7/23 (ug/m3)(ug)(ug/m3)(ug)Compound AmountAmountRpt. LimitRpt. Limit 1.0 0.97 6.0 5.8Ethanol 0.10 0.15 Not Detected Not DetectedMethyl tert-butyl ether 0.10 0.15 0.39 0.59Hexane 0.40 0.51 Not Detected Not DetectedEthyl Acetate 0.20 0.25 1.1 1.42-Butanone (Methyl Ethyl Ketone) 0.10 0.13 Not Detected Not DetectedChloroform 0.10 0.16 Not Detected Not Detected1,1,1-Trichloroethane 0.10 0.18 Not Detected Not DetectedCyclohexane 0.10 0.15 0.12 0.18Carbon Tetrachloride 0.40 0.50 1.3 1.6Benzene 0.10 0.13 Not Detected Not Detected1,2-Dichloroethane 0.10 0.17 0.19 0.33Heptane 0.10 0.14 Not Detected Not DetectedTrichloroethene 0.20 0.30 Not Detected Not Detected4-Methyl-2-pentanone 0.10 0.13 1.3 1.8Toluene 0.10 0.17 0.16 0.28Tetrachloroethene 0.10 0.14 Not Detected Not DetectedChlorobenzene 0.10 0.14 0.21 0.30Ethyl Benzene 0.10 0.14 0.61 0.86m,p-Xylene 0.10 0.15 0.18 0.28o-Xylene 0.10 0.16 Not Detected Not DetectedStyrene 0.10 0.17 Not Detected Not DetectedPropylbenzene 0.10 0.19 0.25 0.481,4-Dichlorobenzene 0.10 0.40 Not Detected Not DetectedNaphthalene 0.10 0.16 Not Detected C Not Detected C1,1-Dichloroethane 0.40 0.52 Not Detected C Not Detected C1,1-Dichloroethene 0.10 0.16 Not Detected C Not Detected Ccis-1,2-Dichloroethene 0.10 0.16 Not Detected C Not Detected C1,1,2,2-Tetrachloroethane 0.20 0.33 Not Detected C Not Detected Ctrans-1,2-Dichloroethene 0.10 0.15 Not Detected C Not Detected C1,1,2-Trichloroethane 0.10 0.20 0.16 0.321,2,4-Trimethylbenzene 0.10 0.17 Not Detected C Not Detected C1,2-Dichlorobenzene 0.10 0.19 Not Detected C Not Detected C1,3,5-Trimethylbenzene 0.10 0.17 Not Detected C Not Detected C1,3-Dichlorobenzene C = Estimated concentration due to calculated sampling rate. Temperature = 77.0F , duration time = 10083 minutes. Container Type: Radiello 130 (Solvent) Limits%RecoverySurrogates Method Page 8 of 28 Client Sample ID: 571-RES-01_20231205 Lab ID#: 2312126-01A VOCS BY PASSIVE SAMPLER - GC/MS 18120718simFile Name: Dil. Factor:1.00 Date of Collection: 12/5/23 12:48:00 PM Date of Analysis: 12/7/23 03:39 PM Date of Extraction: 12/7/23 Limits%RecoverySurrogates Method 101 70-130Toluene-d8 Page 9 of 28 Client Sample ID: 571-RES-02_20231205 Lab ID#: 2312126-02A VOCS BY PASSIVE SAMPLER - GC/MS 18120719simFile Name: Dil. Factor:1.00 Date of Collection: 12/5/23 12:44:00 PM Date of Analysis: 12/7/23 04:07 PM Date of Extraction: 12/7/23 (ug/m3)(ug)(ug/m3)(ug)Compound AmountAmountRpt. LimitRpt. Limit 1.0 0.97 2.5 2.4Ethanol 0.10 0.15 Not Detected Not DetectedMethyl tert-butyl ether 0.10 0.15 0.36 0.54Hexane 0.40 0.51 Not Detected Not DetectedEthyl Acetate 0.20 0.25 0.97 1.22-Butanone (Methyl Ethyl Ketone) 0.10 0.13 Not Detected Not DetectedChloroform 0.10 0.16 Not Detected Not Detected1,1,1-Trichloroethane 0.10 0.18 Not Detected Not DetectedCyclohexane 0.10 0.15 0.14 0.20Carbon Tetrachloride 0.40 0.50 1.2 1.5Benzene 0.10 0.13 Not Detected Not Detected1,2-Dichloroethane 0.10 0.17 0.20 0.34Heptane 0.10 0.14 Not Detected Not DetectedTrichloroethene 0.20 0.30 Not Detected Not Detected4-Methyl-2-pentanone 0.10 0.13 1.3 1.8Toluene 0.10 0.17 0.19 0.32Tetrachloroethene 0.10 0.15 Not Detected Not DetectedChlorobenzene 0.10 0.15 0.20 0.30Ethyl Benzene 0.10 0.14 0.60 0.85m,p-Xylene 0.10 0.15 0.18 0.27o-Xylene 0.10 0.16 Not Detected Not DetectedStyrene 0.10 0.17 Not Detected Not DetectedPropylbenzene 0.10 0.19 0.24 0.461,4-Dichlorobenzene 0.10 0.40 Not Detected Not DetectedNaphthalene 0.10 0.16 Not Detected C Not Detected C1,1-Dichloroethane 0.40 0.52 Not Detected C Not Detected C1,1-Dichloroethene 0.10 0.16 Not Detected C Not Detected Ccis-1,2-Dichloroethene 0.10 0.16 Not Detected C Not Detected C1,1,2,2-Tetrachloroethane 0.20 0.33 Not Detected C Not Detected Ctrans-1,2-Dichloroethene 0.10 0.15 Not Detected C Not Detected C1,1,2-Trichloroethane 0.10 0.20 0.20 0.391,2,4-Trimethylbenzene 0.10 0.17 Not Detected C Not Detected C1,2-Dichlorobenzene 0.10 0.19 Not Detected C Not Detected C1,3,5-Trimethylbenzene 0.10 0.17 Not Detected C Not Detected C1,3-Dichlorobenzene C = Estimated concentration due to calculated sampling rate. Temperature = 77.0F , duration time = 10059 minutes. Container Type: Radiello 130 (Solvent) Limits%RecoverySurrogates Method Page 10 of 28 Client Sample ID: 571-RES-02_20231205 Lab ID#: 2312126-02A VOCS BY PASSIVE SAMPLER - GC/MS 18120719simFile Name: Dil. Factor:1.00 Date of Collection: 12/5/23 12:44:00 PM Date of Analysis: 12/7/23 04:07 PM Date of Extraction: 12/7/23 Limits%RecoverySurrogates Method 103 70-130Toluene-d8 Page 11 of 28 Client Sample ID: 571-RES-03_20231205 Lab ID#: 2312126-03A VOCS BY PASSIVE SAMPLER - GC/MS 18120720simFile Name: Dil. Factor:1.00 Date of Collection: 12/5/23 12:47:00 PM Date of Analysis: 12/7/23 04:34 PM Date of Extraction: 12/7/23 (ug/m3)(ug)(ug/m3)(ug)Compound AmountAmountRpt. LimitRpt. Limit 1.0 0.97 4.9 4.8Ethanol 0.10 0.15 Not Detected Not DetectedMethyl tert-butyl ether 0.10 0.15 0.29 0.44Hexane 0.40 0.51 Not Detected Not DetectedEthyl Acetate 0.20 0.25 1.0 1.32-Butanone (Methyl Ethyl Ketone) 0.10 0.13 Not Detected Not DetectedChloroform 0.10 0.16 Not Detected Not Detected1,1,1-Trichloroethane 0.10 0.18 Not Detected Not DetectedCyclohexane 0.10 0.15 0.11 0.17Carbon Tetrachloride 0.40 0.50 1.1 1.4Benzene 0.10 0.13 Not Detected Not Detected1,2-Dichloroethane 0.10 0.17 0.16 0.27Heptane 0.10 0.14 Not Detected Not DetectedTrichloroethene 0.20 0.30 Not Detected Not Detected4-Methyl-2-pentanone 0.10 0.13 1.1 1.5Toluene 0.10 0.17 0.16 0.27Tetrachloroethene 0.10 0.15 Not Detected Not DetectedChlorobenzene 0.10 0.15 0.17 0.25Ethyl Benzene 0.10 0.14 0.50 0.71m,p-Xylene 0.10 0.15 0.14 0.22o-Xylene 0.10 0.16 Not Detected Not DetectedStyrene 0.10 0.17 Not Detected Not DetectedPropylbenzene 0.10 0.19 0.21 0.411,4-Dichlorobenzene 0.10 0.40 Not Detected Not DetectedNaphthalene 0.10 0.16 Not Detected C Not Detected C1,1-Dichloroethane 0.40 0.52 Not Detected C Not Detected C1,1-Dichloroethene 0.10 0.16 Not Detected C Not Detected Ccis-1,2-Dichloroethene 0.10 0.16 Not Detected C Not Detected C1,1,2,2-Tetrachloroethane 0.20 0.33 Not Detected C Not Detected Ctrans-1,2-Dichloroethene 0.10 0.15 Not Detected C Not Detected C1,1,2-Trichloroethane 0.10 0.20 0.13 0.261,2,4-Trimethylbenzene 0.10 0.17 Not Detected C Not Detected C1,2-Dichlorobenzene 0.10 0.19 Not Detected C Not Detected C1,3,5-Trimethylbenzene 0.10 0.17 Not Detected C Not Detected C1,3-Dichlorobenzene C = Estimated concentration due to calculated sampling rate. Temperature = 77.0F , duration time = 10071 minutes. Container Type: Radiello 130 (Solvent) Limits%RecoverySurrogates Method Page 12 of 28 Client Sample ID: 571-RES-03_20231205 Lab ID#: 2312126-03A VOCS BY PASSIVE SAMPLER - GC/MS 18120720simFile Name: Dil. Factor:1.00 Date of Collection: 12/5/23 12:47:00 PM Date of Analysis: 12/7/23 04:34 PM Date of Extraction: 12/7/23 Limits%RecoverySurrogates Method 101 70-130Toluene-d8 Page 13 of 28 Client Sample ID: 571-RES-04_20231205 Lab ID#: 2312126-04A VOCS BY PASSIVE SAMPLER - GC/MS 18120721simFile Name: Dil. Factor:1.00 Date of Collection: 12/5/23 12:34:00 PM Date of Analysis: 12/7/23 05:01 PM Date of Extraction: 12/7/23 (ug/m3)(ug)(ug/m3)(ug)Compound AmountAmountRpt. LimitRpt. Limit 1.0 0.97 Not Detected Not DetectedEthanol 0.10 0.15 Not Detected Not DetectedMethyl tert-butyl ether 0.10 0.15 Not Detected Not DetectedHexane 0.40 0.51 Not Detected Not DetectedEthyl Acetate 0.20 0.25 Not Detected Not Detected2-Butanone (Methyl Ethyl Ketone) 0.10 0.13 Not Detected Not DetectedChloroform 0.10 0.16 Not Detected Not Detected1,1,1-Trichloroethane 0.10 0.18 Not Detected Not DetectedCyclohexane 0.10 0.15 0.13 0.19Carbon Tetrachloride 0.40 0.49 Not Detected Not DetectedBenzene 0.10 0.13 Not Detected Not Detected1,2-Dichloroethane 0.10 0.17 Not Detected Not DetectedHeptane 0.10 0.14 0.20 0.29Trichloroethene 0.20 0.30 Not Detected Not Detected4-Methyl-2-pentanone 0.10 0.13 0.25 0.34Toluene 0.10 0.17 0.81 1.4Tetrachloroethene 0.10 0.14 Not Detected Not DetectedChlorobenzene 0.10 0.14 Not Detected Not DetectedEthyl Benzene 0.10 0.14 Not Detected Not Detectedm,p-Xylene 0.10 0.15 Not Detected Not Detectedo-Xylene 0.10 0.16 Not Detected Not DetectedStyrene 0.10 0.17 Not Detected Not DetectedPropylbenzene 0.10 0.19 Not Detected Not Detected1,4-Dichlorobenzene 0.10 0.40 Not Detected Not DetectedNaphthalene 0.10 0.16 Not Detected C Not Detected C1,1-Dichloroethane 0.40 0.52 Not Detected C Not Detected C1,1-Dichloroethene 0.10 0.16 Not Detected C Not Detected Ccis-1,2-Dichloroethene 0.10 0.16 Not Detected C Not Detected C1,1,2,2-Tetrachloroethane 0.20 0.33 Not Detected C Not Detected Ctrans-1,2-Dichloroethene 0.10 0.15 Not Detected C Not Detected C1,1,2-Trichloroethane 0.10 0.20 Not Detected Not Detected1,2,4-Trimethylbenzene 0.10 0.17 Not Detected C Not Detected C1,2-Dichlorobenzene 0.10 0.19 Not Detected C Not Detected C1,3,5-Trimethylbenzene 0.10 0.17 Not Detected C Not Detected C1,3-Dichlorobenzene C = Estimated concentration due to calculated sampling rate. Temperature = 77.0F , duration time = 10118 minutes. Container Type: Radiello 130 (Solvent) Limits%RecoverySurrogates Method Page 14 of 28 Client Sample ID: 571-RES-04_20231205 Lab ID#: 2312126-04A VOCS BY PASSIVE SAMPLER - GC/MS 18120721simFile Name: Dil. Factor:1.00 Date of Collection: 12/5/23 12:34:00 PM Date of Analysis: 12/7/23 05:01 PM Date of Extraction: 12/7/23 Limits%RecoverySurrogates Method 102 70-130Toluene-d8 Page 15 of 28 Client Sample ID: 571-RES-05_20231205 Lab ID#: 2312126-05A VOCS BY PASSIVE SAMPLER - GC/MS 18120722simFile Name: Dil. Factor:1.00 Date of Collection: 12/5/23 12:25:00 PM Date of Analysis: 12/7/23 05:29 PM Date of Extraction: 12/7/23 (ug/m3)(ug)(ug/m3)(ug)Compound AmountAmountRpt. LimitRpt. Limit 1.0 0.97 Not Detected Not DetectedEthanol 0.10 0.15 Not Detected Not DetectedMethyl tert-butyl ether 0.10 0.15 0.10 0.16Hexane 0.40 0.51 Not Detected Not DetectedEthyl Acetate 0.20 0.25 Not Detected Not Detected2-Butanone (Methyl Ethyl Ketone) 0.10 0.13 Not Detected Not DetectedChloroform 0.10 0.16 Not Detected Not Detected1,1,1-Trichloroethane 0.10 0.18 Not Detected Not DetectedCyclohexane 0.10 0.15 0.13 0.19Carbon Tetrachloride 0.40 0.50 Not Detected Not DetectedBenzene 0.10 0.13 Not Detected Not Detected1,2-Dichloroethane 0.10 0.17 Not Detected Not DetectedHeptane 0.10 0.14 Not Detected Not DetectedTrichloroethene 0.20 0.30 Not Detected Not Detected4-Methyl-2-pentanone 0.10 0.13 0.29 0.38Toluene 0.10 0.17 0.33 0.55Tetrachloroethene 0.10 0.14 Not Detected Not DetectedChlorobenzene 0.10 0.14 Not Detected Not DetectedEthyl Benzene 0.10 0.14 0.12 0.17m,p-Xylene 0.10 0.15 Not Detected Not Detectedo-Xylene 0.10 0.16 Not Detected Not DetectedStyrene 0.10 0.17 Not Detected Not DetectedPropylbenzene 0.10 0.19 Not Detected Not Detected1,4-Dichlorobenzene 0.10 0.40 Not Detected Not DetectedNaphthalene 0.10 0.16 Not Detected C Not Detected C1,1-Dichloroethane 0.40 0.52 Not Detected C Not Detected C1,1-Dichloroethene 0.10 0.16 Not Detected C Not Detected Ccis-1,2-Dichloroethene 0.10 0.16 Not Detected C Not Detected C1,1,2,2-Tetrachloroethane 0.20 0.33 Not Detected C Not Detected Ctrans-1,2-Dichloroethene 0.10 0.15 Not Detected C Not Detected C1,1,2-Trichloroethane 0.10 0.20 Not Detected Not Detected1,2,4-Trimethylbenzene 0.10 0.17 Not Detected C Not Detected C1,2-Dichlorobenzene 0.10 0.19 Not Detected C Not Detected C1,3,5-Trimethylbenzene 0.10 0.17 Not Detected C Not Detected C1,3-Dichlorobenzene C = Estimated concentration due to calculated sampling rate. Temperature = 77.0F , duration time = 10095 minutes. Container Type: Radiello 130 (Solvent) Limits%RecoverySurrogates Method Page 16 of 28 Client Sample ID: 571-RES-05_20231205 Lab ID#: 2312126-05A VOCS BY PASSIVE SAMPLER - GC/MS 18120722simFile Name: Dil. Factor:1.00 Date of Collection: 12/5/23 12:25:00 PM Date of Analysis: 12/7/23 05:29 PM Date of Extraction: 12/7/23 Limits%RecoverySurrogates Method 102 70-130Toluene-d8 Page 17 of 28 Client Sample ID: 571-RES-06_20231205 Lab ID#: 2312126-06A VOCS BY PASSIVE SAMPLER - GC/MS 18120723simFile Name: Dil. Factor:1.00 Date of Collection: 12/5/23 12:32:00 PM Date of Analysis: 12/7/23 05:56 PM Date of Extraction: 12/7/23 (ug/m3)(ug)(ug/m3)(ug)Compound AmountAmountRpt. LimitRpt. Limit 1.0 0.97 Not Detected Not DetectedEthanol 0.10 0.15 Not Detected Not DetectedMethyl tert-butyl ether 0.10 0.15 Not Detected Not DetectedHexane 0.40 0.51 Not Detected Not DetectedEthyl Acetate 0.20 0.25 Not Detected Not Detected2-Butanone (Methyl Ethyl Ketone) 0.10 0.13 Not Detected Not DetectedChloroform 0.10 0.16 Not Detected Not Detected1,1,1-Trichloroethane 0.10 0.18 Not Detected Not DetectedCyclohexane 0.10 0.15 0.12 0.18Carbon Tetrachloride 0.40 0.49 Not Detected Not DetectedBenzene 0.10 0.13 Not Detected Not Detected1,2-Dichloroethane 0.10 0.17 Not Detected Not DetectedHeptane 0.10 0.14 0.10 0.14Trichloroethene 0.20 0.29 Not Detected Not Detected4-Methyl-2-pentanone 0.10 0.13 0.25 0.33Toluene 0.10 0.17 0.42 0.71Tetrachloroethene 0.10 0.14 Not Detected Not DetectedChlorobenzene 0.10 0.14 Not Detected Not DetectedEthyl Benzene 0.10 0.14 Not Detected Not Detectedm,p-Xylene 0.10 0.15 Not Detected Not Detectedo-Xylene 0.10 0.16 Not Detected Not DetectedStyrene 0.10 0.17 Not Detected Not DetectedPropylbenzene 0.10 0.19 Not Detected Not Detected1,4-Dichlorobenzene 0.10 0.40 Not Detected Not DetectedNaphthalene 0.10 0.16 Not Detected C Not Detected C1,1-Dichloroethane 0.40 0.52 Not Detected C Not Detected C1,1-Dichloroethene 0.10 0.16 Not Detected C Not Detected Ccis-1,2-Dichloroethene 0.10 0.16 Not Detected C Not Detected C1,1,2,2-Tetrachloroethane 0.20 0.33 Not Detected C Not Detected Ctrans-1,2-Dichloroethene 0.10 0.15 Not Detected C Not Detected C1,1,2-Trichloroethane 0.10 0.20 Not Detected Not Detected1,2,4-Trimethylbenzene 0.10 0.17 Not Detected C Not Detected C1,2-Dichlorobenzene 0.10 0.19 Not Detected C Not Detected C1,3,5-Trimethylbenzene 0.10 0.17 Not Detected C Not Detected C1,3-Dichlorobenzene C = Estimated concentration due to calculated sampling rate. Temperature = 77.0F , duration time = 10122 minutes. Container Type: Radiello 130 (Solvent) Limits%RecoverySurrogates Method Page 18 of 28 Client Sample ID: 571-RES-06_20231205 Lab ID#: 2312126-06A VOCS BY PASSIVE SAMPLER - GC/MS 18120723simFile Name: Dil. Factor:1.00 Date of Collection: 12/5/23 12:32:00 PM Date of Analysis: 12/7/23 05:56 PM Date of Extraction: 12/7/23 Limits%RecoverySurrogates Method 103 70-130Toluene-d8 Page 19 of 28 Client Sample ID: 571-RES-BKG_20231205 Lab ID#: 2312126-07A VOCS BY PASSIVE SAMPLER - GC/MS 18120724simFile Name: Dil. Factor:1.00 Date of Collection: 12/5/23 12:36:00 PM Date of Analysis: 12/7/23 06:23 PM Date of Extraction: 12/7/23 (ug/m3)(ug)(ug/m3)(ug)Compound AmountAmountRpt. LimitRpt. Limit 1.0 0.97 Not Detected Not DetectedEthanol 0.10 0.15 Not Detected Not DetectedMethyl tert-butyl ether 0.10 0.15 0.10 0.15Hexane 0.40 0.51 Not Detected Not DetectedEthyl Acetate 0.20 0.25 Not Detected Not Detected2-Butanone (Methyl Ethyl Ketone) 0.10 0.13 Not Detected Not DetectedChloroform 0.10 0.16 Not Detected Not Detected1,1,1-Trichloroethane 0.10 0.18 Not Detected Not DetectedCyclohexane 0.10 0.15 0.10 0.15Carbon Tetrachloride 0.40 0.50 Not Detected Not DetectedBenzene 0.10 0.13 Not Detected Not Detected1,2-Dichloroethane 0.10 0.17 Not Detected Not DetectedHeptane 0.10 0.14 Not Detected Not DetectedTrichloroethene 0.20 0.30 Not Detected Not Detected4-Methyl-2-pentanone 0.10 0.13 0.23 0.31Toluene 0.10 0.17 Not Detected Not DetectedTetrachloroethene 0.10 0.14 Not Detected Not DetectedChlorobenzene 0.10 0.14 Not Detected Not DetectedEthyl Benzene 0.10 0.14 Not Detected Not Detectedm,p-Xylene 0.10 0.15 Not Detected Not Detectedo-Xylene 0.10 0.16 Not Detected Not DetectedStyrene 0.10 0.17 Not Detected Not DetectedPropylbenzene 0.10 0.19 Not Detected Not Detected1,4-Dichlorobenzene 0.10 0.40 Not Detected Not DetectedNaphthalene 0.10 0.16 Not Detected C Not Detected C1,1-Dichloroethane 0.40 0.52 Not Detected C Not Detected C1,1-Dichloroethene 0.10 0.16 Not Detected C Not Detected Ccis-1,2-Dichloroethene 0.10 0.16 Not Detected C Not Detected C1,1,2,2-Tetrachloroethane 0.20 0.33 Not Detected C Not Detected Ctrans-1,2-Dichloroethene 0.10 0.15 Not Detected C Not Detected C1,1,2-Trichloroethane 0.10 0.20 Not Detected Not Detected1,2,4-Trimethylbenzene 0.10 0.17 Not Detected C Not Detected C1,2-Dichlorobenzene 0.10 0.19 Not Detected C Not Detected C1,3,5-Trimethylbenzene 0.10 0.17 Not Detected C Not Detected C1,3-Dichlorobenzene C = Estimated concentration due to calculated sampling rate. Temperature = 77.0F , duration time = 10086 minutes. Container Type: Radiello 130 (Solvent) Limits%RecoverySurrogates Method Page 20 of 28 Client Sample ID: 571-RES-BKG_20231205 Lab ID#: 2312126-07A VOCS BY PASSIVE SAMPLER - GC/MS 18120724simFile Name: Dil. Factor:1.00 Date of Collection: 12/5/23 12:36:00 PM Date of Analysis: 12/7/23 06:23 PM Date of Extraction: 12/7/23 Limits%RecoverySurrogates Method 100 70-130Toluene-d8 Page 21 of 28 Client Sample ID: DUP-RES_20231205 Lab ID#: 2312126-08A VOCS BY PASSIVE SAMPLER - GC/MS 18120725simFile Name: Dil. Factor:1.00 Date of Collection: 12/5/23 12:30:00 PM Date of Analysis: 12/7/23 06:50 PM Date of Extraction: 12/7/23 (ug/m3)(ug)(ug/m3)(ug)Compound AmountAmountRpt. LimitRpt. Limit 1.0 0.97 Not Detected Not DetectedEthanol 0.10 0.15 Not Detected Not DetectedMethyl tert-butyl ether 0.10 0.15 Not Detected Not DetectedHexane 0.40 0.51 Not Detected Not DetectedEthyl Acetate 0.20 0.25 Not Detected Not Detected2-Butanone (Methyl Ethyl Ketone) 0.10 0.13 Not Detected Not DetectedChloroform 0.10 0.16 Not Detected Not Detected1,1,1-Trichloroethane 0.10 0.18 Not Detected Not DetectedCyclohexane 0.10 0.15 0.12 0.18Carbon Tetrachloride 0.40 0.49 Not Detected Not DetectedBenzene 0.10 0.13 Not Detected Not Detected1,2-Dichloroethane 0.10 0.17 Not Detected Not DetectedHeptane 0.10 0.14 Not Detected Not DetectedTrichloroethene 0.20 0.30 Not Detected Not Detected4-Methyl-2-pentanone 0.10 0.13 0.25 0.34Toluene 0.10 0.17 0.30 0.50Tetrachloroethene 0.10 0.14 Not Detected Not DetectedChlorobenzene 0.10 0.14 Not Detected Not DetectedEthyl Benzene 0.10 0.14 0.10 0.14m,p-Xylene 0.10 0.15 Not Detected Not Detectedo-Xylene 0.10 0.16 Not Detected Not DetectedStyrene 0.10 0.17 Not Detected Not DetectedPropylbenzene 0.10 0.19 Not Detected Not Detected1,4-Dichlorobenzene 0.10 0.40 Not Detected Not DetectedNaphthalene 0.10 0.16 Not Detected C Not Detected C1,1-Dichloroethane 0.40 0.52 Not Detected C Not Detected C1,1-Dichloroethene 0.10 0.16 Not Detected C Not Detected Ccis-1,2-Dichloroethene 0.10 0.16 Not Detected C Not Detected C1,1,2,2-Tetrachloroethane 0.20 0.33 Not Detected C Not Detected Ctrans-1,2-Dichloroethene 0.10 0.15 Not Detected C Not Detected C1,1,2-Trichloroethane 0.10 0.20 Not Detected Not Detected1,2,4-Trimethylbenzene 0.10 0.17 Not Detected C Not Detected C1,2-Dichlorobenzene 0.10 0.19 Not Detected C Not Detected C1,3,5-Trimethylbenzene 0.10 0.17 Not Detected C Not Detected C1,3-Dichlorobenzene C = Estimated concentration due to calculated sampling rate. Temperature = 77.0F , duration time = 10102 minutes. Container Type: Radiello 130 (Solvent) Limits%RecoverySurrogates Method Page 22 of 28 Client Sample ID: DUP-RES_20231205 Lab ID#: 2312126-08A VOCS BY PASSIVE SAMPLER - GC/MS 18120725simFile Name: Dil. Factor:1.00 Date of Collection: 12/5/23 12:30:00 PM Date of Analysis: 12/7/23 06:50 PM Date of Extraction: 12/7/23 Limits%RecoverySurrogates Method 102 70-130Toluene-d8 Page 23 of 28 Client Sample ID: Lab Blank Lab ID#: 2312126-09A VOCS BY PASSIVE SAMPLER - GC/MS 18120705simFile Name: Dil. Factor:1.00 Date of Collection: NA Date of Analysis: 12/7/23 09:43 AM Date of Extraction: 12/7/23 (ug/m3)(ug)(ug/m3)(ug)Compound AmountAmountRpt. LimitRpt. Limit 1.0 0.97 Not Detected Not DetectedEthanol 0.10 0.15 Not Detected Not DetectedMethyl tert-butyl ether 0.10 0.15 Not Detected Not DetectedHexane 0.40 0.51 Not Detected Not DetectedEthyl Acetate 0.20 0.25 Not Detected Not Detected2-Butanone (Methyl Ethyl Ketone) 0.10 0.13 Not Detected Not DetectedChloroform 0.10 0.16 Not Detected Not Detected1,1,1-Trichloroethane 0.10 0.18 Not Detected Not DetectedCyclohexane 0.10 0.15 Not Detected Not DetectedCarbon Tetrachloride 0.40 0.49 Not Detected Not DetectedBenzene 0.10 0.13 Not Detected Not Detected1,2-Dichloroethane 0.10 0.17 Not Detected Not DetectedHeptane 0.10 0.14 Not Detected Not DetectedTrichloroethene 0.20 0.29 Not Detected Not Detected4-Methyl-2-pentanone 0.10 0.13 Not Detected Not DetectedToluene 0.10 0.17 Not Detected Not DetectedTetrachloroethene 0.10 0.14 Not Detected Not DetectedChlorobenzene 0.10 0.14 Not Detected Not DetectedEthyl Benzene 0.10 0.14 Not Detected Not Detectedm,p-Xylene 0.10 0.15 Not Detected Not Detectedo-Xylene 0.10 0.16 Not Detected Not DetectedStyrene 0.10 0.17 Not Detected Not DetectedPropylbenzene 0.10 0.19 Not Detected Not Detected1,4-Dichlorobenzene 0.10 0.40 Not Detected Not DetectedNaphthalene 0.10 0.16 Not Detected C Not Detected C1,1-Dichloroethane 0.40 0.52 Not Detected C Not Detected C1,1-Dichloroethene 0.10 0.16 Not Detected C Not Detected Ccis-1,2-Dichloroethene 0.10 0.16 Not Detected C Not Detected C1,1,2,2-Tetrachloroethane 0.20 0.33 Not Detected C Not Detected Ctrans-1,2-Dichloroethene 0.10 0.15 Not Detected C Not Detected C1,1,2-Trichloroethane 0.10 0.20 Not Detected Not Detected1,2,4-Trimethylbenzene 0.10 0.17 Not Detected C Not Detected C1,2-Dichlorobenzene 0.10 0.19 Not Detected C Not Detected C1,3,5-Trimethylbenzene 0.10 0.17 Not Detected C Not Detected C1,3-Dichlorobenzene C = Estimated concentration due to calculated sampling rate. Temperature = 77.0F , duration time = 10122 minutes. Container Type: Radiello 130 (Solvent) Limits%RecoverySurrogates Method Page 24 of 28 Client Sample ID: Lab Blank Lab ID#: 2312126-09A VOCS BY PASSIVE SAMPLER - GC/MS 18120705simFile Name: Dil. Factor:1.00 Date of Collection: NA Date of Analysis: 12/7/23 09:43 AM Date of Extraction: 12/7/23 Limits%RecoverySurrogates Method 101 70-130Toluene-d8 Page 25 of 28 Client Sample ID: CCV Lab ID#: 2312126-10A VOCS BY PASSIVE SAMPLER - GC/MS 18120702simFile Name: Dil. Factor:1.00 Date of Collection: NA Date of Analysis: 12/7/23 08:20 AM Date of Extraction: NA %RecoveryCompound 110Ethanol 99Methyl tert-butyl ether 102Hexane 110Ethyl Acetate 1022-Butanone (Methyl Ethyl Ketone) 92Chloroform 881,1,1-Trichloroethane 100Cyclohexane 90Carbon Tetrachloride 102Benzene 811,2-Dichloroethane 106Heptane 101Trichloroethene 1084-Methyl-2-pentanone 109Toluene 107Tetrachloroethene 109Chlorobenzene 109Ethyl Benzene 111m,p-Xylene 112o-Xylene 114Styrene 111Propylbenzene 1121,4-Dichlorobenzene 109Naphthalene 951,1-Dichloroethane 991,1-Dichloroethene 98cis-1,2-Dichloroethene 1091,1,2,2-Tetrachloroethane 100trans-1,2-Dichloroethene 1031,1,2-Trichloroethane 1161,2,4-Trimethylbenzene 1121,2-Dichlorobenzene 1141,3,5-Trimethylbenzene 1121,3-Dichlorobenzene Container Type: NA - Not Applicable Limits%RecoverySurrogates Method 101 70-130Toluene-d8 Page 26 of 28 Client Sample ID: LCS Lab ID#: 2312126-11A VOCS BY PASSIVE SAMPLER - GC/MS 18120703simFile Name: Dil. Factor:1.00 Date of Collection: NA Date of Analysis: 12/7/23 08:48 AM Date of Extraction: 12/7/23 Limits%RecoveryCompound Method 65 50-130Ethanol 107 70-130Methyl tert-butyl ether 110 70-130Hexane 112 70-130Ethyl Acetate 94 70-1302-Butanone (Methyl Ethyl Ketone) 91 70-130Chloroform 92 70-1301,1,1-Trichloroethane 111 70-130Cyclohexane 93 70-130Carbon Tetrachloride 105 70-130Benzene 80 70-1301,2-Dichloroethane 114 70-130Heptane 104 70-130Trichloroethene 107 70-1304-Methyl-2-pentanone 108 70-130Toluene 106 70-130Tetrachloroethene 101 70-130Chlorobenzene 111 70-130Ethyl Benzene 108 70-130m,p-Xylene 102 70-130o-Xylene 68 20-100Styrene 114 70-130Propylbenzene 87 50-1101,4-Dichlorobenzene 14 5-80Naphthalene 99 70-1301,1-Dichloroethane 109 70-1301,1-Dichloroethene 98 70-130cis-1,2-Dichloroethene 92 70-1301,1,2,2-Tetrachloroethane 105 70-130trans-1,2-Dichloroethene 98 70-1301,1,2-Trichloroethane 104 70-1301,2,4-Trimethylbenzene 81 50-1101,2-Dichlorobenzene 112 70-1301,3,5-Trimethylbenzene 92 50-1101,3-Dichlorobenzene Container Type: NA - Not Applicable Limits%RecoverySurrogates Method 104 70-130Toluene-d8 Page 27 of 28 Client Sample ID: LCSD Lab ID#: 2312126-11AA VOCS BY PASSIVE SAMPLER - GC/MS 18120704simFile Name: Dil. Factor:1.00 Date of Collection: NA Date of Analysis: 12/7/23 09:16 AM Date of Extraction: 12/7/23 Limits%RecoveryCompound Method 63 50-130Ethanol 109 70-130Methyl tert-butyl ether 110 70-130Hexane 112 70-130Ethyl Acetate 95 70-1302-Butanone (Methyl Ethyl Ketone) 91 70-130Chloroform 92 70-1301,1,1-Trichloroethane 112 70-130Cyclohexane 93 70-130Carbon Tetrachloride 106 70-130Benzene 80 70-1301,2-Dichloroethane 114 70-130Heptane 105 70-130Trichloroethene 106 70-1304-Methyl-2-pentanone 108 70-130Toluene 106 70-130Tetrachloroethene 100 70-130Chlorobenzene 110 70-130Ethyl Benzene 107 70-130m,p-Xylene 101 70-130o-Xylene 68 20-100Styrene 112 70-130Propylbenzene 85 50-1101,4-Dichlorobenzene 12 5-80Naphthalene 100 70-1301,1-Dichloroethane 110 70-1301,1-Dichloroethene 100 70-130cis-1,2-Dichloroethene 91 70-1301,1,2,2-Tetrachloroethane 107 70-130trans-1,2-Dichloroethene 98 70-1301,1,2-Trichloroethane 100 70-1301,2,4-Trimethylbenzene 80 50-1101,2-Dichlorobenzene 110 70-1301,3,5-Trimethylbenzene 90 50-1101,3-Dichlorobenzene Container Type: NA - Not Applicable Limits%RecoverySurrogates Method 104 70-130Toluene-d8 Page 28 of 28 Appendix C North Carolina Department of Environmental Quality Risk Calculations Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 1/4/2024 Prepared By:Erin Greene Kyle Church Mike Dail 32322 Nanny Drive - Crawlspace (571-RES-01) North Carolina Department of Environmental Quality Risk Calculator Albemarle Dump Nanny Drive, Albemarle NC DWM Special Remediation Branch: Pre-Regulatory Landfill Unit NONCD0000571 July 2023 May 2023 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32322 Nanny Drive - Crawlspace (571-RES-01) Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32322 Nanny Drive - Crawlspace (571-RES-01) Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual) 1.0E-06 Target Cancer Risk (cumulative) 1.0E-04 Target Hazard Index (individual) 2.0E-01 Target Hazard Index (cumulative) 1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg) 15 Exposure Duration (ED) (yr) 6 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr/d) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day) 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d) 0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 20 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr/d) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 25 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr/d) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Working Weeks (EW) (wk/yr) 50 Exposure Duration (ED) (yr) 1 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr/d) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day) 330 1 70 80 330 1 250 8 3527 0.3 50 100 19652 2.5 0.71 1 20 350 24 6032 0.07 0.54 1 70 80 2373 0.2 200 6365 0.78 Input Form 1B Exposure Unit ID: 32322 Nanny Drive - Crawlspace (571-RES-01) Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: 32322 Nanny Drive - Crawlspace (571-RES-01) Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr) 365 NA 365 Body Weight (BW) (kg) 15 NA 15 Exposure Duration 0-2 (ED) (yr) 2 NA 2 Exposure Duration 2-6 (ED) (yr) 4 NA 4 Exposure Frequency (EF) (d/yr) 195 NA 195 Exposure Time (ET) (hr/d) 2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day) 200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr) 0.12 NA 0.12 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day) 1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg) 80 45 80 Exposure Duration 6-16 (ED) (yr) 10 10 10 Exposure Duration 16-26 (ED) (yr) 10 0 10 Exposure Frequency (EF) (d/yr) 195 90 195 Exposure Time (ET) (hr/d) 2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day) 100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr) 0.11 0.11 0.11 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day) 1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32322 Nanny Drive - Crawlspace (571-RES-01) Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes: CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 1.6 71-43-2 Benzene ug/m3 0.18 56-23-5 Carbon Tetrachloride ug/m3 0.48 106-46-7 Dichlorobenzene, 1,4-ug/m3 0.3 100-41-4 Ethylbenzene ug/m3 0.33 142-82-5 Heptane, N-ug/m3 0.59 110-54-3 Hexane, N-ug/m3 1.4 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 0.28 127-18-4 Tetrachloroethylene ug/m3 1.8 108-88-3 Toluene ug/m3 0.32 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0.28 95-47-6 Xylene, o-ug/m3 0.86 106-42-3 Xylene, p-ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations Sample ID: 571-RES-01_20231205 32322 Nanny Drive - Carter Crawlspace Passive Sampler North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32322 Nanny Drive - Crawlspace (571-RES-01) Receptor Pathway Carcinogenic Ris Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use* NC NC NC Soil NC NC NC Groundwater Use* NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water* NC NC NC Receptor Pathway Carcinogenic Ris Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 7.0E-06 7.9E-02 NO Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 1.6E-06 1.9E-02 NO Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not modeled, user did not check this pathway as complete. 4. NC = Pathway not calculated, required contaminant migration parameters were not entered. DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Indoor Air Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32322 Nanny Drive - Crawlspace (571-RES-01) CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 71-43-2 Benzene 1.6 3.6E-01 6.3E+00 4.4E-06 5.1E-02 56-23-5 Carbon Tetrachloride 0.18 4.7E-01 2.1E+01 3.8E-07 1.7E-03 106-46-7 Dichlorobenzene, 1,4- 0.48 2.6E-01 1.7E+02 1.9E-06 5.8E-04 100-41-4 Ethylbenzene 0.3 1.1E+00 2.1E+02 2.7E-07 2.9E-04 142-82-5 Heptane, N- 0.33 - 8.3E+01 7.9E-04 110-54-3 Hexane, N- 0.59 - 1.5E+02 8.1E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone) 1.4 - 1.0E+03 2.7E-04 127-18-4 Tetrachloroethylene 0.28 1.1E+01 8.3E+00 2.6E-08 6.7E-03 108-88-3 Toluene 1.8 - 1.0E+03 3.5E-04 95-63-6 Trimethylbenzene, 1,2,4- 0.32 - 1.3E+01 5.1E-03 95-47-6 Xylene, o- 0.28 - 2.1E+01 2.7E-03 106-42-3 Xylene, p- 0.86 - 2.1E+01 8.2E-03 Cumulative: 7.0E-06 7.9E-02 All concentrations are in ug/m3 Output Form 3C ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32322 Nanny Drive - Crawlspace (571-RES-01) CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 71-43-2 Benzene 1.6 1.6E+00 2.6E+01 1.0E-06 1.2E-02 56-23-5 Carbon Tetrachloride 0.18 2.0E+00 8.8E+01 8.8E-08 4.1E-04 106-46-7 Dichlorobenzene, 1,4- 0.48 1.1E+00 7.0E+02 4.3E-07 1.4E-04 100-41-4 Ethylbenzene 0.3 4.9E+00 8.8E+02 6.1E-08 6.8E-05 142-82-5 Heptane, N- 0.33 - 3.5E+02 1.9E-04 110-54-3 Hexane, N- 0.59 - 6.1E+02 1.9E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone) 1.4 - 4.4E+03 6.4E-05 127-18-4 Tetrachloroethylene 0.28 4.7E+01 3.5E+01 5.9E-09 1.6E-03 108-88-3 Toluene 1.8 - 4.4E+03 8.2E-05 95-63-6 Trimethylbenzene, 1,2,4- 0.32 - 5.3E+01 1.2E-03 95-47-6 Xylene, o- 0.28 - 8.8E+01 6.4E-04 106-42-3 Xylene, p- 0.86 - 8.8E+01 2.0E-03 Cumulative: 1.6E-06 1.9E-02 All concentrations are in u /3 Output Form 3F ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 1/4/2024 Prepared By:Erin Greene Kyle Church Mike Dail 32322 Nanny Drive - Crawlspace (571-RES-02) North Carolina Department of Environmental Quality Risk Calculator Albemarle Dump Nanny Drive, Albemarle NC DWM Special Remediation Branch: Pre-Regulatory Landfill Unit NONCD0000571 July 2023 May 2023 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32322 Nanny Drive - Crawlspace (571-RES-02) Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32322 Nanny Drive - Crawlspace (571-RES-02) Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual) 1.0E-06 Target Cancer Risk (cumulative) 1.0E-04 Target Hazard Index (individual) 2.0E-01 Target Hazard Index (cumulative) 1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg) 15 Exposure Duration (ED) (yr) 6 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr/d) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day) 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d) 0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 20 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr/d) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 25 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr/d) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Working Weeks (EW) (wk/yr) 50 Exposure Duration (ED) (yr) 1 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr/d) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day) 330 1 70 80 330 1 250 8 3527 0.3 50 100 19652 2.5 0.71 1 20 350 24 6032 0.07 0.54 1 70 80 2373 0.2 200 6365 0.78 Input Form 1B Exposure Unit ID: 32322 Nanny Drive - Crawlspace (571-RES-02) Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: 32322 Nanny Drive - Crawlspace (571-RES-02) Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr) 365 NA 365 Body Weight (BW) (kg) 15 NA 15 Exposure Duration 0-2 (ED) (yr) 2 NA 2 Exposure Duration 2-6 (ED) (yr) 4 NA 4 Exposure Frequency (EF) (d/yr) 195 NA 195 Exposure Time (ET) (hr/d) 2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day) 200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr) 0.12 NA 0.12 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day) 1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg) 80 45 80 Exposure Duration 6-16 (ED) (yr) 10 10 10 Exposure Duration 16-26 (ED) (yr) 10 0 10 Exposure Frequency (EF) (d/yr) 195 90 195 Exposure Time (ET) (hr/d) 2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day) 100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr) 0.11 0.11 0.11 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day) 1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32322 Nanny Drive - Crawlspace (571-RES-02) Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes: CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 1.5 71-43-2 Benzene ug/m3 0.2 56-23-5 Carbon Tetrachloride ug/m3 0.46 106-46-7 Dichlorobenzene, 1,4-ug/m3 0.3 100-41-4 Ethylbenzene ug/m3 0.34 142-82-5 Heptane, N-ug/m3 0.54 110-54-3 Hexane, N-ug/m3 1.2 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 0.32 127-18-4 Tetrachloroethylene ug/m3 1.8 108-88-3 Toluene ug/m3 0.39 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0.27 95-47-6 Xylene, o-ug/m3 0.85 106-42-3 Xylene, p-ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations Sample ID: 571-RES-02_20231205 32322 Nanny Drive - Carter Crawlspace Passive Sampler North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32322 Nanny Drive - Crawlspace (571-RES-02) Receptor Pathway Carcinogenic Ris Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use* NC NC NC Soil NC NC NC Groundwater Use* NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water* NC NC NC Receptor Pathway Carcinogenic Ris Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 6.7E-06 7.7E-02 NO Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 1.5E-06 1.8E-02 NO Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not modeled, user did not check this pathway as complete. 4. NC = Pathway not calculated, required contaminant migration parameters were not entered. DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Indoor Air Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32322 Nanny Drive - Crawlspace (571-RES-02) CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 71-43-2 Benzene 1.5 3.6E-01 6.3E+00 4.2E-06 4.8E-02 56-23-5 Carbon Tetrachloride 0.2 4.7E-01 2.1E+01 4.3E-07 1.9E-03 106-46-7 Dichlorobenzene, 1,4- 0.46 2.6E-01 1.7E+02 1.8E-06 5.5E-04 100-41-4 Ethylbenzene 0.3 1.1E+00 2.1E+02 2.7E-07 2.9E-04 142-82-5 Heptane, N- 0.34 - 8.3E+01 8.2E-04 110-54-3 Hexane, N- 0.54 - 1.5E+02 7.4E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone) 1.2 - 1.0E+03 2.3E-04 127-18-4 Tetrachloroethylene 0.32 1.1E+01 8.3E+00 3.0E-08 7.7E-03 108-88-3 Toluene 1.8 - 1.0E+03 3.5E-04 95-63-6 Trimethylbenzene, 1,2,4- 0.39 - 1.3E+01 6.2E-03 95-47-6 Xylene, o- 0.27 - 2.1E+01 2.6E-03 106-42-3 Xylene, p- 0.85 - 2.1E+01 8.2E-03 Cumulative: 6.7E-06 7.7E-02 All concentrations are in ug/m3 Output Form 3C ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32322 Nanny Drive - Crawlspace (571-RES-02) CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 71-43-2 Benzene 1.5 1.6E+00 2.6E+01 9.5E-07 1.1E-02 56-23-5 Carbon Tetrachloride 0.2 2.0E+00 8.8E+01 9.8E-08 4.6E-04 106-46-7 Dichlorobenzene, 1,4- 0.46 1.1E+00 7.0E+02 4.1E-07 1.3E-04 100-41-4 Ethylbenzene 0.3 4.9E+00 8.8E+02 6.1E-08 6.8E-05 142-82-5 Heptane, N- 0.34 - 3.5E+02 1.9E-04 110-54-3 Hexane, N- 0.54 - 6.1E+02 1.8E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone) 1.2 - 4.4E+03 5.5E-05 127-18-4 Tetrachloroethylene 0.32 4.7E+01 3.5E+01 6.8E-09 1.8E-03 108-88-3 Toluene 1.8 - 4.4E+03 8.2E-05 95-63-6 Trimethylbenzene, 1,2,4- 0.39 - 5.3E+01 1.5E-03 95-47-6 Xylene, o- 0.27 - 8.8E+01 6.2E-04 106-42-3 Xylene, p- 0.85 - 8.8E+01 1.9E-03 Cumulative: 1.5E-06 1.8E-02 All concentrations are in u /3 Output Form 3F ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 1/4/2024 Prepared By:Erin Greene Kyle Church Mike Dail 32322 Nanny Drive - Crawlspace (571-RES-03) North Carolina Department of Environmental Quality Risk Calculator Albemarle Dump Nanny Drive, Albemarle NC DWM Special Remediation Branch: Pre-Regulatory Landfill Unit NONCD0000571 July 2023 May 2023 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32322 Nanny Drive - Crawlspace (571-RES-03) Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32322 Nanny Drive - Crawlspace (571-RES-03) Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual) 1.0E-06 Target Cancer Risk (cumulative) 1.0E-04 Target Hazard Index (individual) 2.0E-01 Target Hazard Index (cumulative) 1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg) 15 Exposure Duration (ED) (yr) 6 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr/d) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day) 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d) 0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 20 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr/d) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 25 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr/d) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Working Weeks (EW) (wk/yr) 50 Exposure Duration (ED) (yr) 1 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr/d) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day) 330 1 70 80 330 1 250 8 3527 0.3 50 100 19652 2.5 0.71 1 20 350 24 6032 0.07 0.54 1 70 80 2373 0.2 200 6365 0.78 Input Form 1B Exposure Unit ID: 32322 Nanny Drive - Crawlspace (571-RES-03) Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: 32322 Nanny Drive - Crawlspace (571-RES-03) Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr) 365 NA 365 Body Weight (BW) (kg) 15 NA 15 Exposure Duration 0-2 (ED) (yr) 2 NA 2 Exposure Duration 2-6 (ED) (yr) 4 NA 4 Exposure Frequency (EF) (d/yr) 195 NA 195 Exposure Time (ET) (hr/d) 2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day) 200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr) 0.12 NA 0.12 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day) 1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg) 80 45 80 Exposure Duration 6-16 (ED) (yr) 10 10 10 Exposure Duration 16-26 (ED) (yr) 10 0 10 Exposure Frequency (EF) (d/yr) 195 90 195 Exposure Time (ET) (hr/d) 2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day) 100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr) 0.11 0.11 0.11 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day) 1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32322 Nanny Drive - Crawlspace (571-RES-03) Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes: CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 1.4 71-43-2 Benzene ug/m3 0.17 56-23-5 Carbon Tetrachloride ug/m3 0.41 106-46-7 Dichlorobenzene, 1,4-ug/m3 0.25 100-41-4 Ethylbenzene ug/m3 0.27 142-82-5 Heptane, N-ug/m3 0.44 110-54-3 Hexane, N-ug/m3 1.3 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 0.27 127-18-4 Tetrachloroethylene ug/m3 1.5 108-88-3 Toluene ug/m3 0.26 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0.22 95-47-6 Xylene, o-ug/m3 0.71 106-42-3 Xylene, p-ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations Sample ID: 571-RES-03_20231205 32322 Nanny Drive - Carter Crawlspace Passive Sampler North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32322 Nanny Drive - Crawlspace (571-RES-03) Receptor Pathway Carcinogenic Ris Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use* NC NC NC Soil NC NC NC Groundwater Use* NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water* NC NC NC Receptor Pathway Carcinogenic Ris Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 6.1E-06 6.8E-02 NO Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 1.4E-06 1.6E-02 NO Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not modeled, user did not check this pathway as complete. 4. NC = Pathway not calculated, required contaminant migration parameters were not entered. DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Indoor Air Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32322 Nanny Drive - Crawlspace (571-RES-03) CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 71-43-2 Benzene 1.4 3.6E-01 6.3E+00 3.9E-06 4.5E-02 56-23-5 Carbon Tetrachloride 0.17 4.7E-01 2.1E+01 3.6E-07 1.6E-03 106-46-7 Dichlorobenzene, 1,4- 0.41 2.6E-01 1.7E+02 1.6E-06 4.9E-04 100-41-4 Ethylbenzene 0.25 1.1E+00 2.1E+02 2.2E-07 2.4E-04 142-82-5 Heptane, N- 0.27 - 8.3E+01 6.5E-04 110-54-3 Hexane, N- 0.44 - 1.5E+02 6.0E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone) 1.3 - 1.0E+03 2.5E-04 127-18-4 Tetrachloroethylene 0.27 1.1E+01 8.3E+00 2.5E-08 6.5E-03 108-88-3 Toluene 1.5 - 1.0E+03 2.9E-04 95-63-6 Trimethylbenzene, 1,2,4- 0.26 - 1.3E+01 4.2E-03 95-47-6 Xylene, o- 0.22 - 2.1E+01 2.1E-03 106-42-3 Xylene, p- 0.71 - 2.1E+01 6.8E-03 Cumulative: 6.1E-06 6.8E-02 All concentrations are in ug/m3 Output Form 3C ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32322 Nanny Drive - Crawlspace (571-RES-03) CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 71-43-2 Benzene 1.4 1.6E+00 2.6E+01 8.9E-07 1.1E-02 56-23-5 Carbon Tetrachloride 0.17 2.0E+00 8.8E+01 8.3E-08 3.9E-04 106-46-7 Dichlorobenzene, 1,4- 0.41 1.1E+00 7.0E+02 3.7E-07 1.2E-04 100-41-4 Ethylbenzene 0.25 4.9E+00 8.8E+02 5.1E-08 5.7E-05 142-82-5 Heptane, N- 0.27 - 3.5E+02 1.5E-04 110-54-3 Hexane, N- 0.44 - 6.1E+02 1.4E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone) 1.3 - 4.4E+03 5.9E-05 127-18-4 Tetrachloroethylene 0.27 4.7E+01 3.5E+01 5.7E-09 1.5E-03 108-88-3 Toluene 1.5 - 4.4E+03 6.8E-05 95-63-6 Trimethylbenzene, 1,2,4- 0.26 - 5.3E+01 9.9E-04 95-47-6 Xylene, o- 0.22 - 8.8E+01 5.0E-04 106-42-3 Xylene, p- 0.71 - 8.8E+01 1.6E-03 Cumulative: 1.4E-06 1.6E-02 All concentrations are in u /3 Output Form 3F ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 1/4/2024 Prepared By:Erin Greene Kyle Church Mike Dail 32311 Nanny Drive - Crawlspace (571-RES-04) North Carolina Department of Environmental Quality Risk Calculator Albemarle Dump Nanny Drive, Albemarle NC DWM Special Remediation Branch: Pre-Regulatory Landfill Unit NONCD0000571 July 2023 May 2023 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32311 Nanny Drive - Crawlspace (571-RES-04) Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32311 Nanny Drive - Crawlspace (571-RES-04) Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual) 1.0E-06 Target Cancer Risk (cumulative) 1.0E-04 Target Hazard Index (individual) 2.0E-01 Target Hazard Index (cumulative) 1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg) 15 Exposure Duration (ED) (yr) 6 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr/d) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day) 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d) 0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 20 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr/d) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 25 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr/d) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Working Weeks (EW) (wk/yr) 50 Exposure Duration (ED) (yr) 1 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr/d) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day) 330 1 70 80 330 1 250 8 3527 0.3 50 100 19652 2.5 0.71 1 20 350 24 6032 0.07 0.54 1 70 80 2373 0.2 200 6365 0.78 Input Form 1B Exposure Unit ID: 32311 Nanny Drive - Crawlspace (571-RES-04) Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: 32311 Nanny Drive - Crawlspace (571-RES-04) Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr) 365 NA 365 Body Weight (BW) (kg) 15 NA 15 Exposure Duration 0-2 (ED) (yr) 2 NA 2 Exposure Duration 2-6 (ED) (yr) 4 NA 4 Exposure Frequency (EF) (d/yr) 195 NA 195 Exposure Time (ET) (hr/d) 2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day) 200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr) 0.12 NA 0.12 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day) 1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg) 80 45 80 Exposure Duration 6-16 (ED) (yr) 10 10 10 Exposure Duration 16-26 (ED) (yr) 10 0 10 Exposure Frequency (EF) (d/yr) 195 90 195 Exposure Time (ET) (hr/d) 2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day) 100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr) 0.11 0.11 0.11 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day) 1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32311 Nanny Drive - Crawlspace (571-RES-04) Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes: CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 0.19 56-23-5 Carbon Tetrachloride ug/m3 1.4 127-18-4 Tetrachloroethylene ug/m3 0.34 108-88-3 Toluene ug/m3 0.29 79-01-6 Trichloroethylene ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations Sample ID: 571-RES-04_20231205 32311 Nanny Drive - Carter Crawlspace Passive Sampler North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32311 Nanny Drive - Crawlspace (571-RES-04) Receptor Pathway Carcinogenic Ris Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use* NC NC NC Soil NC NC NC Groundwater Use* NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water* NC NC NC Receptor Pathway Carcinogenic Ris Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 1.1E-06 1.7E-01 NO Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 2.2E-07 4.2E-02 NO Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not modeled, user did not check this pathway as complete. 4. NC = Pathway not calculated, required contaminant migration parameters were not entered. DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Indoor Air Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32311 Nanny Drive - Crawlspace (571-RES-04) CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 56-23-5 Carbon Tetrachloride 0.19 4.7E-01 2.1E+01 4.1E-07 1.8E-03 127-18-4 Tetrachloroethylene 1.4 1.1E+01 8.3E+00 1.3E-07 3.4E-02 108-88-3 Toluene 0.34 - 1.0E+03 6.5E-05 79-01-6 Trichloroethylene 0.29 4.8E-01 4.2E-01 6.1E-07 1.4E-01 Cumulative: 1.1E-06 1.7E-01 All concentrations are in ug/m3 Output Form 3C ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32311 Nanny Drive - Crawlspace (571-RES-04) CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 56-23-5 Carbon Tetrachloride 0.19 2.0E+00 8.8E+01 9.3E-08 4.3E-04 127-18-4 Tetrachloroethylene 1.4 4.7E+01 3.5E+01 3.0E-08 8.0E-03 108-88-3 Toluene 0.34 - 4.4E+03 1.6E-05 79-01-6 Trichloroethylene 0.29 3.0E+00 1.8E+00 9.7E-08 3.3E-02 Cumulative: 2.2E-07 4.2E-02 All concentrations are in u /3 Output Form 3F ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 32311 Nanny Drive - Crawlspace (571-RES-05) North Carolina Department of Environmental Quality Risk Calculator Albemarle Dump Nanny Drive, Albemarle NC DWM Special Remediation Branch: Pre-Regulatory Landfill Unit NONCD0000571 July 2023 May 2023 EPA RSL Table 1/4/2024 Prepared By:Erin Greene Kyle Church Mike Dail North Carolina DEQ Risk Calculator Table of Contents Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32311 Nanny Drive - Crawlspace (571-RES-05) Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32311 Nanny Drive - Crawlspace (571-RES-05) Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual) 1.0E-06 Target Cancer Risk (cumulative) 1.0E-04 Target Hazard Index (individual) 2.0E-01 Target Hazard Index (cumulative) 1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg) 15 Exposure Duration (ED) (yr) 6 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr/d) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day) 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d) 0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 20 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr/d) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 25 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr/d) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Working Weeks (EW) (wk/yr) 50 Exposure Duration (ED) (yr) 1 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr/d) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day) 330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: 32311 Nanny Drive - Crawlspace (571-RES-05) Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: 32311 Nanny Drive - Crawlspace (571-RES-05) Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr) 365 NA 365 Body Weight (BW) (kg) 15 NA 15 Exposure Duration 0-2 (ED) (yr) 2 NA 2 Exposure Duration 2-6 (ED) (yr) 4 NA 4 Exposure Frequency (EF) (d/yr) 195 NA 195 Exposure Time (ET) (hr/d) 2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day) 200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr) 0.12 NA 0.12 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day) 1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg) 80 45 80 Exposure Duration 6-16 (ED) (yr) 10 10 10 Exposure Duration 16-26 (ED) (yr) 10 0 10 Exposure Frequency (EF) (d/yr) 195 90 195 Exposure Time (ET) (hr/d) 2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day) 100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr) 0.11 0.11 0.11 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day) 1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32311 Nanny Drive - Crawlspace (571-RES-05) Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes: CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 0.19 56-23-5 Carbon Tetrachloride ug/m3 0.16 110-54-3 Hexane, N-ug/m3 0.55 127-18-4 Tetrachloroethylene ug/m3 0.38 108-88-3 Toluene ug/m3 0.17 108-38-3 Xylene, m-ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations Sample ID: 571-RES-05_20231205 32311 Nanny Drive - Page-Lambert Crawlspace Passive Sampler North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32311 Nanny Drive - Crawlspace (571-RES-05) Receptor Pathway Carcinogenic Ris Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use* NC NC NC Soil NC NC NC Groundwater Use* NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water* NC NC NC Receptor Pathway Carcinogenic Ris Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 4.6E-07 1.7E-02 NO Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 1.0E-07 4.0E-03 NO Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: 3. NM = Not modeled, user did not check this pathway as complete. 4. NC = Pathway not calculated, required contaminant migration parameters were not entered. DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Indoor Air Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32311 Nanny Drive - Crawlspace (571-RES-05) CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 56-23-5 Carbon Tetrachloride 0.19 4.7E-01 2.1E+01 4.1E-07 1.8E-03 110-54-3 Hexane, N- 0.16 - 1.5E+02 2.2E-04 127-18-4 Tetrachloroethylene 0.55 1.1E+01 8.3E+00 5.1E-08 1.3E-02 108-88-3 Toluene 0.38 - 1.0E+03 7.3E-05 108-38-3 Xylene, m- 0.17 - 2.1E+01 1.6E-03 Cumulative: 4.6E-07 1.7E-02 All concentrations are in ug/m3 Output Form 3C ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32311 Nanny Drive - Crawlspace (571-RES-05) CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 56-23-5 Carbon Tetrachloride 0.19 2.0E+00 8.8E+01 9.3E-08 4.3E-04 110-54-3 Hexane, N- 0.16 - 6.1E+02 5.2E-05 127-18-4 Tetrachloroethylene 0.55 4.7E+01 3.5E+01 1.2E-08 3.1E-03 108-88-3 Toluene 0.38 - 4.4E+03 1.7E-05 108-38-3 Xylene, m- 0.17 - 8.8E+01 3.9E-04 Cumulative: 1.0E-07 4.0E-03 All concentrations are in u /3 Output Form 3F ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 1/4/2024 Prepared By:Erin Greene Kyle Church Mike Dail 32311 Nanny Drive - Crawlspace (571-RES-06) North Carolina Department of Environmental Quality Risk Calculator Albemarle Dump Nanny Drive, Albemarle NC DWM Special Remediation Branch: Pre-Regulatory Landfill Unit NONCD0000571 July 2023 May 2023 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32311 Nanny Drive - Crawlspace (571-RES-06) Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32311 Nanny Drive - Crawlspace (571-RES-06) Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual) 1.0E-06 Target Cancer Risk (cumulative) 1.0E-04 Target Hazard Index (individual) 2.0E-01 Target Hazard Index (cumulative) 1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg) 15 Exposure Duration (ED) (yr) 6 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr/d) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day) 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d) 0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 20 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr/d) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 25 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr/d) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Working Weeks (EW) (wk/yr) 50 Exposure Duration (ED) (yr) 1 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr/d) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day) 330 1 70 80 330 1 250 8 3527 0.3 50 100 19652 2.5 0.71 1 20 350 24 6032 0.07 0.54 1 70 80 2373 0.2 200 6365 0.78 Input Form 1B Exposure Unit ID: 32311 Nanny Drive - Crawlspace (571-RES-06) Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: 32311 Nanny Drive - Crawlspace (571-RES-06) Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr) 365 NA 365 Body Weight (BW) (kg) 15 NA 15 Exposure Duration 0-2 (ED) (yr) 2 NA 2 Exposure Duration 2-6 (ED) (yr) 4 NA 4 Exposure Frequency (EF) (d/yr) 195 NA 195 Exposure Time (ET) (hr/d) 2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day) 200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr) 0.12 NA 0.12 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day) 1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg) 80 45 80 Exposure Duration 6-16 (ED) (yr) 10 10 10 Exposure Duration 16-26 (ED) (yr) 10 0 10 Exposure Frequency (EF) (d/yr) 195 90 195 Exposure Time (ET) (hr/d) 2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day) 100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr) 0.11 0.11 0.11 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day) 1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32311 Nanny Drive - Crawlspace (571-RES-06) Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes: CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 0.18 56-23-5 Carbon Tetrachloride ug/m3 0.71 127-18-4 Tetrachloroethylene ug/m3 0.33 108-88-3 Toluene ug/m3 0.14 79-01-6 Trichloroethylene ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations Sample ID: 571-RES-06_20231205 32311 Nanny Drive - Page-Lambert Crawlspace Passive Sampler North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32311 Nanny Drive - Crawlspace (571-RES-06) Receptor Pathway Carcinogenic Ris Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use* NC NC NC Soil NC NC NC Groundwater Use* NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water* NC NC NC Receptor Pathway Carcinogenic Ris Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 7.4E-07 8.6E-02 NO Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 1.5E-07 2.0E-02 NO Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not modeled, user did not check this pathway as complete. 4. NC = Pathway not calculated, required contaminant migration parameters were not entered. DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Indoor Air Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32311 Nanny Drive - Crawlspace (571-RES-06) CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 56-23-5 Carbon Tetrachloride 0.18 4.7E-01 2.1E+01 3.8E-07 1.7E-03 127-18-4 Tetrachloroethylene 0.71 1.1E+01 8.3E+00 6.6E-08 1.7E-02 108-88-3 Toluene 0.33 - 1.0E+03 6.3E-05 79-01-6 Trichloroethylene 0.14 4.8E-01 4.2E-01 2.9E-07 6.7E-02 Cumulative: 7.4E-07 8.6E-02 All concentrations are in ug/m3 Output Form 3C ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air Version Date: July 2023 Basis: May 2023 EPA RSL Table Site ID: NONCD0000571 Exposure Unit ID: 32311 Nanny Drive - Crawlspace (571-RES-06) CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 56-23-5 Carbon Tetrachloride 0.18 2.0E+00 8.8E+01 8.8E-08 4.1E-04 127-18-4 Tetrachloroethylene 0.71 4.7E+01 3.5E+01 1.5E-08 4.1E-03 108-88-3 Toluene 0.33 - 4.4E+03 1.5E-05 79-01-6 Trichloroethylene 0.14 3.0E+00 1.8E+00 4.7E-08 1.6E-02 Cumulative: 1.5E-07 2.0E-02 All concentrations are in u /3 Output Form 3F ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator