9102T_VanceCoTS_LeachateReleaseAssmtRpt_FID1838475_20240516

May 8, 2024
Mr. Ervin Lane
1646 Mail Service Center
Raleigh, North Carolina 27699
RE: Recommended Soil Sampling - Results
Vance County Transfer Station
Henderson, North Carolina
Dear Mr. Lane:
On Thursday, March 7th, 2024 during a North Carolina Department of Environmental Quality
(NCDEQ) inspection at the Vance County Transfer Station, standing water was observed near
the southern end of transfer trailer loading bay. Upon the discovery of a repair project to the
area, NCDEQ representatives recommended the facility collect a confirmation soil sample to
ensure any possibly contaminated soils were removed. A plan to sample the potentially
impacted soils was submitted and approved1 by the NCDEQ. This letter report summarizes
the results from the soil sampling.
Sampling
On April 6th, 2024, S+G personnel collected two (2) discrete grab samples in locations shown
on to evaluate soil quality in the southern area of the transfer station.
Each soil sample was collected from a depth between one (1) and two (2) feet below grade.
Soil sample SS-1 and SS-2 were analyzed for the Appendix I list of constituents (40 CFR 258
Appendix I), 1,4 dioxane, total phosphorous, sulfates, nitrates, and pH by Waypoint Analytical
Laboratories Inc. (Waypoint), a North Carolina certified laboratory.
Due to the naturally occurring inorganic metals in the soils of North Carolina, background
samples (BG-1, BG-2 and BG-3) collected during a previous investigation, were used to
compare analytical results2. Background soil samples were collected from roughly 18 inches
below grade, these locations are also shown on . The previous background samples
were analyzed for the Appendix I list of constituents (40 CFR 258 Appendix I), sulfate, nitrate,
and pH by Prism Laboratories, Inc.
1 Approval of Recommended Sampling Plan, FID 1833595 – NCDEQ, April 04, 2024
2 Prism Laboratories, Inc. Analytical Results, Prism Work Order: 8040411, May 4, 2018
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Mr. Lane
May 8, 2024
Page 2 of 3
Results
Soil sample analytical data was compared to background analytical data as well as the NCDEQ
February 2024 Preliminary Soil Remediation Goals (PSRGs). Both Industrial and Protection of
Groundwater PSRGs were used for this evaluation. Of the constituents analyzed, only cobalt
exceeded Groundwater Protection PSRGs. Results from background samples indicated cobalt
is naturally occurring in the area at concentrations similar to those detected in SS-1 and SS-
2.
An additional Synthetic Precipitation Leaching Procedure (SPLP) analysis was performed on
both soil samples (SS-1 and SS-2), and the results were compared with the NCAC 02L
Standards for Groundwater Protection for Total Cobalt (1 μg/L). SPLP results indicated cobalt
concentrations were just above the NCAC 02L standard limit in SS-1 and SS-2 however, these
results are “J-flagged” as being between the method detection limit and practical quantitation
limit and are estimated values. These results are summarized in . The laboratory
report is included as .
Evaluation of Natural Occurrence of Cobalt
To further evaluate the natural occurrence of cobalt at the measured concentrations, S+G
reviewed USGS National Uranium Resource Evaluation (NURE)3 stream bed sample analysis
in this area of Vance County. The Nure samples were analyzed for a variety of inorganic
constituents to evaluate natural occurrence of these in stream sediments with the
understanding that this data may indicate uranium deposits in the area. Data from four (4)
historical NURE sediment samples taken near the site were used: 5300348, 5300350,
5300384, and 5300386. Of those samples, 5300386 reported cobalt concentrations above
PSRGs for groundwater protection, which support the natural occurrence of cobalt in soils in
Vance County. NURE sediment sample locations are shown in and relevant
concentration data in .
Conclusions
While the analytical results exhibit an exceedance of the Groundwater Protection PSRGs
(solid sample) for cobalt in SS-1 and SS-2, the three (3) background samples, collected at
various locations across the facility, all exceed the Groundwater Protection PSRGs for cobalt.
An additional NURE sediment sample was also reported with higher concentrations
(17mg/kg) than the PSRGs for groundwater protection for cobalt. The lack of organic
constituents, the background soil sample results, and the NURE sediment sample (5300386)
result indicate that cobalt concentrations are spatially variable and can occur naturally at
concentrations above PSRGs.
Based on this investigation, and given the SPLP analytical results are J-flagged values
(estimated values), we believe the results of cobalt reported in SS-1 and SS-2 are likely due
to naturally occurring inorganic constituents and no further action is warranted.
3 Geochemistry of sediments in the US from the NURE-HSSR database, https://mrdata.usgus.gove/nure/sediment
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Mr. Lane
May 8, 2024
Page 3 of 3
If you have any questions or require additional information, please contact us at 919-828-0577
or by email below.
Sincerely,
SMITH GARDNER, INC.
Lou J. Krasuski Joan A. Smyth, P.G.
Project Manager Senior Hydrogeologist
[e-mail] [e-mail]
Attachments - Figure 1
Figure 2
Table 1 - Detected Constituents – Vance County Transfer Station
Attachment A - Laboratory Report
cc: John Pfleger – GFL Environmental
Randy Deming – GFL Environmental
Jason Watkins – NCDEQ
Drew Hammonds – NCDEQ
Amanda Thompson – NCDEQ
File
H:\Projects\Waste Industries (Vance County Transfer Station)\GFLVANCE 24-1\Results\Vance County Recommended
Soil Sampling Results.docx
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5/8/2024

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Table 1
Detected Constituents
Vance County Transfer Station
April 6, 2024
BG-1 BG-2 B-3 SS-1 SS-1 (SPLP)SS-2 SS-2 (SPLP)5300348
(NURE)
5300350
(NURE)
5300384
(NURE)
5300386
(NURE)
mg/Kg mg/Kg mg/Kg mg/Kg µg/L mg/Kg µg/L mg/Kg mg/Kg mg/Kg mg/Kg
4/20/2018 4/20/2018 4/20/2018 4/26/2024 4/26/2024 4/26/2024 4/26/2024 11/2/1976 11/2/1976 11/3/1976 11/3/1976
Arsenic 3 5.8 10 1.1 J 0.39 J 0.66 J 0.74 NA 0.848 NA 1 1 NA NABarium47000580700297032162NA118NA130422220Beryllium470634.35 J 0.14 J 0.4 0.547 NA 0.261 J NA 1 0.5 0.5 1
Chromium (Total)NE NE 10 27 29 16 36.4 7 J 24.4 BDL 8 9 9 22
Chromium (III)3100000 360000 NA NA NA NA 36.4 J NA 24.4 NA NA NA NA NA
Chromium (VI)6.5 3.8 NA NA NA NA 0.216 NA 0.176 NA NA NA NA NA
Cobalt 70 0.9 1 6.4 24 16 11.1 2 J 26.4 3 J BDL BDL BDL 17Copper93007001000241102039NA49.5 NA 2 3 BDL 5LeadNE270156.8 0.53 9.1 2.74 NA 1.06 NA BDL 12 BDL BDL
Nickel 4600 130 100 7.1 32 13 23.5 NA 24 NA BDL BDL BDL 5
Silver 1200 3.4 20 BDL BDL BDL 0.011 J NA 0.0089 J NA 0.1 BDL BDL 0.2
Thallium 2.3 2.8 2 0.069 J 0.081 J 0.084 J 0.233 J NA 0.141 J NA NA NA NA NA
Vanadium 1200 140 7 97 70 84 72.2 NA 72.2 NA 10 80 60 180Zinc700001200100021 J 45 21 J 61.7 NA 73.1 NA 5 25 5 10
Acetone 210000 25 NE 0.96 0.029 0.2 BDL NA 0.006 J NA NA NA NA NA
pH NE NE NE 4.6 7.0 5.8 7.8 NA 7.8 NA NA NA NA NA
Note:
Preliminary Soil Remediation Goals (PSRG) from February 2024 DEQ Table and Companion Notes
NA - Not Analyzed
NE - PSRG has not been established
BDL - Below Detection Limit
J - "J-qualified" defined by the laboratory as "Detected but below the Reporting Limit; therefore, result is an estimated concentration."
D- The sample was analyzed at Dilution
Bold/Shaded - Concentration is greater than the lower value between the GW and Industrial PSRG
Bold/Shaded/Italicized - Concentration is greater than NCAC 02L Groundwater Standard
Data from Waypoint Laboratories Report #: 24-100-0103
Organic
Indicator
Inorganic
Constituents
NCDEQ
Preliminary Soil
Remediation Goals
(PSRGs) (mg/Kg)
Industrial Use
NCDEQ
Preliminary Soil
Remediation Goals
(PSRGs) (mg/Kg)
Groundwater
Protection
15A NCAC 02L
.0202 (µg/L)
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Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

5/1/2024
Smith & Gardner, Inc. Seth C. Rickerts
14 N. Boylan Avenue Raleigh, NC, 27603
Ref: Analytical Testing
Revised Lab Report Number: 24-100-0103 Client Project Description: GFL Vance 24-1
Dear Seth C. Rickerts:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 4/9/2024 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely,
Angela D Overcash Senior Project Manager
Page 1 of 34
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Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202437735State ProgramNorth Carolina
12/31/2024402State ProgramNorth Carolina
07/31/202499012State ProgramSouth Carolina
12/31/202499012State ProgramSouth Carolina
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State Program Lab ID Expiration Date
02/28/202540750State ProgramAlabama
02/07/202588-0650State ProgramArkansas
06/30/20242904State ProgramCalifornia
06/30/2024E871157State Program - NELAPFlorida
11/14/2025C044State ProgramGeorgia
06/30/202404015State ProgramGeorgia
10/31/2024200078State Program - NELAPIllinois
06/30/202480215State ProgramKentucky
12/31/2024KY90047State ProgramKentucky
12/31/2024LA037State Program - NELAPLouisiana
06/30/202404015State Program - NELAPLouisiana
11/14/2025MSState ProgramMississippi
07/31/202447701State ProgramNorth Carolina
12/31/2024415State ProgramNorth Carolina
05/31/202468-03195State Program - NELAPPennsylvania
06/30/202484002State ProgramSouth Carolina
11/14/202502027State ProgramTennessee
09/30/2024T104704180State Program - NELAPTexas
06/30/202400106State ProgramVirginia
09/14/2024460181State Program - NELAPVirginia
Page 1 of 1 00016/24-100-0103
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Report Number:
Sample Summary Table
Client Project Description:
24-100-0103
GFL Vance 24-1
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
04/06/2024 10:00Solids 90345 SS-1 04/09/2024 14:10
04/06/2024 10:00Solids 90345 SS-1 04/09/2024 14:10 6020B
04/06/2024 10:00Solids 90345 SS-1 04/09/2024 14:10 SW-7199
04/06/2024 10:30Solids 90346 SS-2 04/09/2024 14:10
04/06/2024 10:30Solids 90346 SS-2 04/09/2024 14:10 SW-7199
04/06/2024 10:30Solids 90346 SS-2 04/09/2024 14:10 6020B
04/06/2024 10:00 91715 SS-1 04/09/2024 14:10 1312
04/06/2024 10:00 91715 SS-1 04/09/2024 14:10 6010D
04/06/2024 10:30 91716 SS-2 04/09/2024 14:10 6010D
04/06/2024 10:30 91716 SS-2 04/09/2024 14:10 1312
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
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Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
24-100-0103
Report Limit
Project:GFL Vance 24-1
V 90345SS-1
0.740 04/12/2024 12:546020BArsenicmg/Kg - dry 0.0943
162 04/12/2024 12:546020BBariummg/Kg - dry 0.047
0.547 04/12/2024 12:546020BBerylliummg/Kg - dry 0.0218
36.4 04/17/2024 16:036020BChromiummg/Kg - dry 0.127
11.1 04/17/2024 16:036020BCobaltmg/Kg - dry 0.031
39.0 04/19/2024 17:226020BCoppermg/Kg - dry 0.0887
2.74 04/12/2024 12:546020BLeadmg/Kg - dry 0.0341
23.5 04/19/2024 17:226020BNickelmg/Kg - dry 0.0700
J0.0110 04/12/2024 12:546020BSilvermg/Kg - dry 0.0074
J0.233 04/12/2024 12:546020BThalliummg/Kg - dry 0.0273
72.2 04/12/2024 12:546020BVanadiummg/Kg - dry 0.243
61.7 04/17/2024 16:036020BZincmg/Kg - dry 0.590
7.82 04/29/2024 13:089045DpHs.u.
J3640004/17/2024 16:03CALCULATIONChromium, Tri-valent µg/Kg - dry 0.155
J0.216 04/29/2024 16:18SW-7199 Chromium, Hexavalent mg/Kg - dry 0.155
9.34 04/10/2024 12:30SW-DRYWT Moisture %
V 90346SS-2
0.848 04/12/2024 12:576020BArsenicmg/Kg - dry 0.0931
118 04/19/2024 17:286020BBariummg/Kg - dry 0.046
J0.261 04/12/2024 12:576020BBerylliummg/Kg - dry 0.0215
24.4 04/17/2024 16:166020BChromiummg/Kg - dry 0.126
26.4 04/17/2024 16:166020BCobaltmg/Kg - dry 0.031
49.5 04/19/2024 17:286020BCoppermg/Kg - dry 0.0877
1.06 04/12/2024 12:576020BLeadmg/Kg - dry 0.0337
24.0 04/19/2024 17:286020BNickelmg/Kg - dry 0.0691
J0.0089 04/12/2024 12:576020BSilvermg/Kg - dry 0.0073
J0.141 04/12/2024 12:576020BThalliummg/Kg - dry 0.0270
72.2 04/12/2024 12:576020BVanadiummg/Kg - dry 0.240
73.1 04/17/2024 16:166020BZincmg/Kg - dry 0.582
J0.006 04/09/2024 17:538260DAcetonemg/Kg - dry 0.002
7.78 04/29/2024 13:089045DpHs.u.
24400 04/17/2024 16:16CALCULATIONChromium, Tri-valent µg/Kg - dry 0.153
0.176 04/29/2024 16:39SW-7199 Chromium, Hexavalent mg/Kg - dry 0.153
8.21 04/10/2024 12:30SW-DRYWT Moisture %
V 91715SS-1
Leachate 04/29/2024 15:001312SPLP Extraction
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Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
24-100-0103
Report Limit
Project:GFL Vance 24-1
V 91715SS-1
Leachate 04/29/2024 15:001312SPLP Extraction
J0.0070 04/30/2024 16:116010DSPLP Chromium mg/L 0.004
J0.0020 04/30/2024 16:116010DSPLP Cobalt mg/L 0.002
V 91716SS-2
Leachate 04/29/2024 15:001312SPLP Extraction
Leachate 04/29/2024 15:001312SPLP Extraction
J0.0030 04/30/2024 16:176010DSPLP Cobalt mg/L 0.002
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Client: Smith & Gardner, Inc. CASE NARRATIVE
Project: GFL Vance 24-1 Lab Report Number: 24-100-0103
Date: 5/1/2024
Report Comments Revised Report: Revsion One SPLP cobalt, SPLP chromium and pH have been reported for both SS-1 and SS-2.
Metals Analyses Method 6020B
Sample 90346 (SS-2) Analyte: Arsenic
QC Batch No: L744621/L744155 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90346 (SS-2)
Analyte: Arsenic QC Batch No: L745466/L744155
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 90346 (SS-2) Analyte: Barium QC Batch No: L744621/L744155 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90346 (SS-2) Analyte: Barium
QC Batch No: L745466/L744155 The matrix spike, matrix spike duplicate and the dilution test were all outside of the quality control acceptance ranges. Matrix interference is suspected.
Sample 90346 (SS-2) Analyte: Barium
QC Batch No: L746008/L744155 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 90346 (SS-2) Analyte: Antimony
QC Batch No: L744621/L744155 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post digestion spike was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 90346 (SS-2)
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Analyte: Antimony
QC Batch No: L745466/L744155 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90346 (SS-2)
Analyte: Vanadium QC Batch No: L745466/L744155
The matrix spike, matrix spike duplicate and the dilution test were all outside of the quality control acceptance ranges. Matrix interference is suspected.
Sample 90346 (SS-2)
Analyte: Cobalt QC Batch No: L745466/L744945
The matrix spike, matrix spike duplicate and the dilution test were all outside of the quality control acceptance ranges. Matrix interference is suspected.
Sample 90346 (SS-2)
Analyte: Chromium QC Batch No: L745466/L744945
The matrix spike, matrix spike duplicate and the dilution test were all outside of the quality control acceptance ranges. Matrix interference is suspected. Sample 90346 (SS-2)
Analyte: Copper QC Batch No: L745466/L744945
The matrix spike, matrix spike duplicate and the dilution test were all outside of the quality control acceptance ranges. Matrix interference is suspected. Sample 90346 (SS-2) Analyte: Copper QC Batch No: L746008/L744945
The matrix spike, matrix spike duplicate and the dilution test were all outside of the quality control acceptance ranges. Matrix interference is suspected.
Sample 90346 (SS-2) Analyte: Nickel QC Batch No: L745466/L744945 The matrix spike, matrix spike duplicate and the dilution test were all outside of the quality control acceptance ranges. Matrix interference is suspected. Sample 90346 (SS-2) Analyte: Nickel QC Batch No: L746008/L744945 The matrix spike, matrix spike duplicate and the dilution test were all outside of the quality control acceptance ranges. Matrix interference is suspected. Sample 90346 (SS-2) Analyte: Selenium QC Batch No: L745466/L744945
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The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90346 (SS-2)
Analyte: Zinc QC Batch No: L745466/L744945
The matrix spike, matrix spike duplicate and the dilution test were all outside of the quality control acceptance ranges. Matrix interference is suspected.
Volatile Organic Compounds - GC/MS Method 8260D SIM Sample 90345 (SS-1) Analyte: 1,4-Dioxane
QC Batch No: V45881/V45880 Matrix spike/matrix spike duplicate recoveries are outside of control limits. Acceptable LCS recovery indicates the
system was in control, but the reported result could be affected by matrix interference.
Sample 90345 (SS-1) Analyte: 4-Bromofluorobenzene
QC Batch No: V45881/V45880 Surrogate(s) exhibited a high bias in this project sample where no target analytes were detected. The high
recovery(s) had no impact on the data. Batch QC samples (method blank and laboratory control samples) all showed surrogates within QC limits. Sample 90346 (SS-2)
Analyte: 4-Bromofluorobenzene QC Batch No: V45881/V45880
Surrogate(s) exhibited a high bias in this project sample where no target analytes were detected. The high recovery(s) had no impact on the data. Batch QC samples (method blank and laboratory control samples) all showed surrogates within QC limits.
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,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27603
24-100-0103
01186
Smith & Gardner, Inc.
14 N. Boylan Avenue
Seth C. Rickerts
Raleigh
Received : 04/09/2024
GFL Vance 24-1
Revised Report Date: 05/01/2024
Original Report Date : 04/23/2024
Sample ID :
Lab No :
Sampled:SS-1
90345 Matrix:
4/6/2024 10:00
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.0002 mg/Kg - dry 0.0002 0.0021,4-Dioxane 1 04/09/24 20:15 8260D SIMTBL
36400 J µg/Kg - dry 0.155 0.220Chromium, Tri-valent 1 04/17/24 16:03 CALCULATION
9.34 %Moisture 1 04/10/24 12:30 SW-DRYWTAKF
0.216 J mg/Kg - dry 0.155 0.220Chromium, Hexavalent 1 04/29/24 16:18 SW-7199MKD
7.82 s.u.pH 1 04/29/24 13:08 9045DGOB
<0.0339 mg/Kg - dry 0.0339 0.276Antimony 5 04/12/24 12:54 6020BCPW
0.740 mg/Kg - dry 0.0943 0.276Arsenic 5 04/12/24 12:54 6020BCPW
162 mg/Kg - dry 0.047 0.275Barium 5 04/12/24 12:54 6020BCPW
0.547 mg/Kg - dry 0.0218 0.276Beryllium 5 04/12/24 12:54 6020BCPW
<0.0286 mg/Kg - dry 0.0286 0.276Cadmium 5 04/12/24 12:54 6020BCPW
36.4 mg/Kg - dry 0.127 0.275Chromium 5 04/17/24 16:03 6020BCPW
11.1 mg/Kg - dry 0.031 0.275Cobalt 5 04/17/24 16:03 6020BCPW
39.0 mg/Kg - dry 0.0887 0.276Copper 5 04/19/24 17:22 6020BCPW
2.74 mg/Kg - dry 0.0341 0.276Lead 5 04/12/24 12:54 6020BCPW
23.5 mg/Kg - dry 0.0700 0.276Nickel 5 04/19/24 17:22 6020BCPW
<0.113 mg/Kg - dry 0.113 0.275Selenium 5 04/12/24 12:54 6020BCPW
0.0110 J mg/Kg - dry 0.0074 0.276Silver 5 04/12/24 12:54 6020BCPW
0.233 J mg/Kg - dry 0.0273 0.276 5 04/12/24 12:54 6020BCPW
72.2 mg/Kg - dry 0.243 1.38Vanadium 5 04/12/24 12:54 6020BCPW
61.7 mg/Kg - dry 0.590 2.76Zinc 5 04/17/24 16:03 6020BCPW
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
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,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27603
24-100-0103
01186
Smith & Gardner, Inc.
14 N. Boylan Avenue
Seth C. Rickerts
Raleigh
Received : 04/09/2024
GFL Vance 24-1
Revised Report Date: 05/01/2024
Original Report Date : 04/23/2024
Sample ID :
Lab No :
Sampled:SS-1
90345 Matrix:
4/6/2024 10:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):04/09/24 08:00
<0.002 mg/Kg - dry 0.002 0.022Acetone 1 04/09/24 17:26 V45887TBL
<0.0008 mg/Kg - dry 0.0008 0.022Acrylonitrile 1 04/09/24 17:26 V45887TBL
<0.0006 mg/Kg - dry 0.0006 0.005Benzene 1 04/09/24 17:26 V45887TBL
<0.0009 mg/Kg - dry 0.0009 0.005Bromochloromethane 1 04/09/24 17:26 V45887TBL
<0.001 mg/Kg - dry 0.001 0.005Bromodichloromethane 1 04/09/24 17:26 V45887TBL
<0.001 mg/Kg - dry 0.001 0.005Bromoform 1 04/09/24 17:26 V45887TBL
<0.002 mg/Kg - dry 0.002 0.011Bromomethane 1 04/09/24 17:26 V45887TBL
<0.0007 mg/Kg - dry 0.0007 0.005Carbon Disulfide 1 04/09/24 17:26 V45887TBL
<0.001 mg/Kg - dry 0.001 0.005Carbon Tetrachloride 1 04/09/24 17:26 V45887TBL
<0.0007 mg/Kg - dry 0.0007 0.005Chlorobenzene 1 04/09/24 17:26 V45887TBL
<0.0010 mg/Kg - dry 0.0010 0.005Chlorodibromomethane 1 04/09/24 17:26 V45887TBL
<0.0010 mg/Kg - dry 0.0010 0.011Chloroethane 1 04/09/24 17:26 V45887TBL
<0.001 mg/Kg - dry 0.001 0.005Chloroform 1 04/09/24 17:26 V45887TBL
<0.0007 mg/Kg - dry 0.0007 0.011Chloromethane 1 04/09/24 17:26 V45887TBL
<0.0008 mg/Kg - dry 0.0008 0.005Di-Isopropyl Ether (DIPE)1 04/09/24 17:26 V45887TBL
<0.0005 mg/Kg - dry 0.0005 0.0111,2-Dibromo-3-Chloropropane 1 04/09/24 17:26 V45887TBL
<0.0007 mg/Kg - dry 0.0007 0.0051,2-Dibromoethane 1 04/09/24 17:26 V45887TBL
<0.0006 mg/Kg - dry 0.0006 0.005Dibromomethane 1 04/09/24 17:26 V45887TBL
<0.0008 mg/Kg - dry 0.0008 0.011trans-1,4-Dichloro-2-butene 1 04/09/24 17:26 V45887TBL
<0.0003 mg/Kg - dry 0.0003 0.0051,2-Dichlorobenzene 1 04/09/24 17:26 V45887TBL
<0.001 mg/Kg - dry 0.001 0.011Dichlorodifluoromethane 1 04/09/24 17:26 V45887TBL
<0.0009 mg/Kg - dry 0.0009 0.0051,1-Dichloroethane 1 04/09/24 17:26 V45887TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 10 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27603
24-100-0103
01186
Smith & Gardner, Inc.
14 N. Boylan Avenue
Seth C. Rickerts
Raleigh
Received : 04/09/2024
GFL Vance 24-1
Revised Report Date: 05/01/2024
Original Report Date : 04/23/2024
Sample ID :
Lab No :
Sampled:SS-1
90345 Matrix:
4/6/2024 10:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):04/09/24 08:00
<0.001 mg/Kg - dry 0.001 0.0051,2-Dichloroethane 1 04/09/24 17:26 V45887TBL
<0.0008 mg/Kg - dry 0.0008 0.0051,1-Dichloroethene 1 04/09/24 17:26 V45887TBL
<0.0009 mg/Kg - dry 0.0009 0.005cis-1,2-Dichloroethene 1 04/09/24 17:26 V45887TBL
<0.001 mg/Kg - dry 0.001 0.005trans-1,2-Dichloroethene 1 04/09/24 17:26 V45887TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,2-Dichloropropane 1 04/09/24 17:26 V45887TBL
<0.0006 mg/Kg - dry 0.0006 0.005cis-1,3-Dichloropropene 1 04/09/24 17:26 V45887TBL
<0.0009 mg/Kg - dry 0.0009 0.005trans-1,3-Dichloropropene 1 04/09/24 17:26 V45887TBL
<0.015 mg/Kg - dry 0.015 0.1101,4-Dioxane 1 04/09/24 17:26 V45887TBL
<0.0006 mg/Kg - dry 0.0006 0.005Ethylbenzene 1 04/09/24 17:26 V45887TBL
<0.0007 mg/Kg - dry 0.0007 0.0222-Hexanone 1 04/09/24 17:26 V45887TBL
<0.0007 mg/Kg - dry 0.0007 0.022Methyl Ethyl Ketone (MEK)1 04/09/24 17:26 V45887TBL
<0.016 mg/Kg - dry 0.016 0.0224-Methyl-2-Pentanone 1 04/09/24 17:26 V45887TBL
<0.001 mg/Kg - dry 0.001 0.011Methylene Chloride 1 04/09/24 17:26 V45887TBL
<0.001 mg/Kg - dry 0.001 0.005Styrene 1 04/09/24 17:26 V45887TBL
<0.001 mg/Kg - dry 0.001 0.0051,1,1,2-Tetrachloroethane 1 04/09/24 17:26 V45887TBL
<0.0004 mg/Kg - dry 0.0004 0.0051,1,2,2-Tetrachloroethane 1 04/09/24 17:26 V45887TBL
<0.0010 mg/Kg - dry 0.0010 0.005 1 04/09/24 17:26 V45887TBL
<0.001 mg/Kg - dry 0.001 0.005 1 04/09/24 17:26 V45887TBL
<0.0007 mg/Kg - dry 0.0007 0.005 1 04/09/24 17:26 V45887TBL
<0.001 mg/Kg - dry 0.001 0.0051,1,1-Trichloroethane 1 04/09/24 17:26 V45887TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,1,2-Trichloroethane 1 04/09/24 17:26 V45887TBL
<0.001 mg/Kg - dry 0.001 0.005 1 04/09/24 17:26 V45887TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 11 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27603
24-100-0103
01186
Smith & Gardner, Inc.
14 N. Boylan Avenue
Seth C. Rickerts
Raleigh
Received : 04/09/2024
GFL Vance 24-1
Revised Report Date: 05/01/2024
Original Report Date : 04/23/2024
Sample ID :
Lab No :
Sampled:SS-1
90345 Matrix:
4/6/2024 10:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):04/09/24 08:00
<0.002 mg/Kg - dry 0.002 0.011 1 04/09/24 17:26 V45887TBL
<0.0008 mg/Kg - dry 0.0008 0.0051,2,3-Trichloropropane 1 04/09/24 17:26 V45887TBL
<0.0005 mg/Kg - dry 0.0005 0.011Vinyl Acetate 1 04/09/24 17:26 V45887TBL
<0.0005 mg/Kg - dry 0.0005 0.011Vinyl Chloride 1 04/09/24 17:26 V45887TBL
<0.0006 mg/Kg - dry 0.0006 0.005o-Xylene 1 04/09/24 17:26 V45887TBL
<0.001 mg/Kg - dry 0.001 0.011m,p-Xylene 1 04/09/24 17:26 V45887TBL
<0.0006 mg/Kg - dry 0.0006 0.005Xylene (Total)1 04/09/24 17:26 V45887
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: Toluene-d8
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 12 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27603
24-100-0103
01186
Smith & Gardner, Inc.
14 N. Boylan Avenue
Seth C. Rickerts
Raleigh
Received : 04/09/2024
GFL Vance 24-1
Revised Report Date: 05/01/2024
Original Report Date : 04/23/2024
Sample ID :
Lab No :
Sampled:SS-2
90346 Matrix:
4/6/2024 10:30
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.0002 mg/Kg - dry 0.0002 0.0021,4-Dioxane 1 04/09/24 20:40 8260D SIMTBL
24400 µg/Kg - dry 0.153 0.217Chromium, Tri-valent 1 04/17/24 16:16 CALCULATION
8.21 %Moisture 1 04/10/24 12:30 SW-DRYWTAKF
0.176 mg/Kg - dry 0.153 0.217Chromium, Hexavalent 1 04/29/24 16:39 SW-7199MKD
7.78 s.u.pH 1 04/29/24 13:08 9045DGOB
<0.0335 mg/Kg - dry 0.0335 0.272Antimony 5 04/12/24 12:57 6020BCPW
0.848 mg/Kg - dry 0.0931 0.272Arsenic 5 04/12/24 12:57 6020BCPW
118 mg/Kg - dry 0.046 0.272Barium 5 04/19/24 17:28 6020BCPW
0.261 J mg/Kg - dry 0.0215 0.272Beryllium 5 04/12/24 12:57 6020BCPW
<0.0283 mg/Kg - dry 0.0283 0.272Cadmium 5 04/19/24 17:28 6020BCPW
24.4 mg/Kg - dry 0.126 0.272Chromium 5 04/17/24 16:16 6020BCPW
26.4 mg/Kg - dry 0.031 0.272Cobalt 5 04/17/24 16:16 6020BCPW
49.5 mg/Kg - dry 0.0877 0.272Copper 5 04/19/24 17:28 6020BCPW
1.06 mg/Kg - dry 0.0337 0.272Lead 5 04/12/24 12:57 6020BCPW
24.0 mg/Kg - dry 0.0691 0.272Nickel 5 04/19/24 17:28 6020BCPW
<0.112 mg/Kg - dry 0.112 0.272Selenium 5 04/12/24 12:57 6020BCPW
0.0089 J mg/Kg - dry 0.0073 0.272Silver 5 04/12/24 12:57 6020BCPW
0.141 J mg/Kg - dry 0.0270 0.272 5 04/12/24 12:57 6020BCPW
72.2 mg/Kg - dry 0.240 1.36Vanadium 5 04/12/24 12:57 6020BCPW
73.1 mg/Kg - dry 0.582 2.72Zinc 5 04/17/24 16:16 6020BCPW
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 13 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27603
24-100-0103
01186
Smith & Gardner, Inc.
14 N. Boylan Avenue
Seth C. Rickerts
Raleigh
Received : 04/09/2024
GFL Vance 24-1
Revised Report Date: 05/01/2024
Original Report Date : 04/23/2024
Sample ID :
Lab No :
Sampled:SS-2
90346 Matrix:
4/6/2024 10:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):04/09/24 08:00
0.006 J mg/Kg - dry 0.002 0.021Acetone 1 04/09/24 17:53 V45887TBL
<0.0008 mg/Kg - dry 0.0008 0.021Acrylonitrile 1 04/09/24 17:53 V45887TBL
<0.0006 mg/Kg - dry 0.0006 0.005Benzene 1 04/09/24 17:53 V45887TBL
<0.0009 mg/Kg - dry 0.0009 0.005Bromochloromethane 1 04/09/24 17:53 V45887TBL
<0.001 mg/Kg - dry 0.001 0.005Bromodichloromethane 1 04/09/24 17:53 V45887TBL
<0.001 mg/Kg - dry 0.001 0.005Bromoform 1 04/09/24 17:53 V45887TBL
<0.001 mg/Kg - dry 0.001 0.010Bromomethane 1 04/09/24 17:53 V45887TBL
<0.0007 mg/Kg - dry 0.0007 0.005Carbon Disulfide 1 04/09/24 17:53 V45887TBL
<0.001 mg/Kg - dry 0.001 0.005Carbon Tetrachloride 1 04/09/24 17:53 V45887TBL
<0.0007 mg/Kg - dry 0.0007 0.005Chlorobenzene 1 04/09/24 17:53 V45887TBL
<0.0010 mg/Kg - dry 0.0010 0.005Chlorodibromomethane 1 04/09/24 17:53 V45887TBL
<0.0010 mg/Kg - dry 0.0010 0.010Chloroethane 1 04/09/24 17:53 V45887TBL
<0.001 mg/Kg - dry 0.001 0.005Chloroform 1 04/09/24 17:53 V45887TBL
<0.0007 mg/Kg - dry 0.0007 0.010Chloromethane 1 04/09/24 17:53 V45887TBL
<0.0008 mg/Kg - dry 0.0008 0.005Di-Isopropyl Ether (DIPE)1 04/09/24 17:53 V45887TBL
<0.0005 mg/Kg - dry 0.0005 0.0101,2-Dibromo-3-Chloropropane 1 04/09/24 17:53 V45887TBL
<0.0006 mg/Kg - dry 0.0006 0.0051,2-Dibromoethane 1 04/09/24 17:53 V45887TBL
<0.0006 mg/Kg - dry 0.0006 0.005Dibromomethane 1 04/09/24 17:53 V45887TBL
<0.0008 mg/Kg - dry 0.0008 0.010trans-1,4-Dichloro-2-butene 1 04/09/24 17:53 V45887TBL
<0.0003 mg/Kg - dry 0.0003 0.0051,2-Dichlorobenzene 1 04/09/24 17:53 V45887TBL
<0.001 mg/Kg - dry 0.001 0.010Dichlorodifluoromethane 1 04/09/24 17:53 V45887TBL
<0.0009 mg/Kg - dry 0.0009 0.0051,1-Dichloroethane 1 04/09/24 17:53 V45887TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 14 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27603
24-100-0103
01186
Smith & Gardner, Inc.
14 N. Boylan Avenue
Seth C. Rickerts
Raleigh
Received : 04/09/2024
GFL Vance 24-1
Revised Report Date: 05/01/2024
Original Report Date : 04/23/2024
Sample ID :
Lab No :
Sampled:SS-2
90346 Matrix:
4/6/2024 10:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):04/09/24 08:00
<0.001 mg/Kg - dry 0.001 0.0051,2-Dichloroethane 1 04/09/24 17:53 V45887TBL
<0.0008 mg/Kg - dry 0.0008 0.0051,1-Dichloroethene 1 04/09/24 17:53 V45887TBL
<0.0009 mg/Kg - dry 0.0009 0.005cis-1,2-Dichloroethene 1 04/09/24 17:53 V45887TBL
<0.001 mg/Kg - dry 0.001 0.005trans-1,2-Dichloroethene 1 04/09/24 17:53 V45887TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,2-Dichloropropane 1 04/09/24 17:53 V45887TBL
<0.0006 mg/Kg - dry 0.0006 0.005cis-1,3-Dichloropropene 1 04/09/24 17:53 V45887TBL
<0.0009 mg/Kg - dry 0.0009 0.005trans-1,3-Dichloropropene 1 04/09/24 17:53 V45887TBL
<0.015 mg/Kg - dry 0.015 0.1081,4-Dioxane 1 04/09/24 17:53 V45887TBL
<0.0006 mg/Kg - dry 0.0006 0.005Ethylbenzene 1 04/09/24 17:53 V45887TBL
<0.0007 mg/Kg - dry 0.0007 0.0212-Hexanone 1 04/09/24 17:53 V45887TBL
<0.0007 mg/Kg - dry 0.0007 0.021Methyl Ethyl Ketone (MEK)1 04/09/24 17:53 V45887TBL
<0.016 mg/Kg - dry 0.016 0.0214-Methyl-2-Pentanone 1 04/09/24 17:53 V45887TBL
<0.001 mg/Kg - dry 0.001 0.010Methylene Chloride 1 04/09/24 17:53 V45887TBL
<0.001 mg/Kg - dry 0.001 0.005Styrene 1 04/09/24 17:53 V45887TBL
<0.001 mg/Kg - dry 0.001 0.0051,1,1,2-Tetrachloroethane 1 04/09/24 17:53 V45887TBL
<0.0003 mg/Kg - dry 0.0003 0.0051,1,2,2-Tetrachloroethane 1 04/09/24 17:53 V45887TBL
<0.0010 mg/Kg - dry 0.0010 0.005 1 04/09/24 17:53 V45887TBL
<0.001 mg/Kg - dry 0.001 0.005 1 04/09/24 17:53 V45887TBL
<0.0007 mg/Kg - dry 0.0007 0.005 1 04/09/24 17:53 V45887TBL
<0.001 mg/Kg - dry 0.001 0.0051,1,1-Trichloroethane 1 04/09/24 17:53 V45887TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,1,2-Trichloroethane 1 04/09/24 17:53 V45887TBL
<0.001 mg/Kg - dry 0.001 0.005 1 04/09/24 17:53 V45887TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 15 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27603
24-100-0103
01186
Smith & Gardner, Inc.
14 N. Boylan Avenue
Seth C. Rickerts
Raleigh
Received : 04/09/2024
GFL Vance 24-1
Revised Report Date: 05/01/2024
Original Report Date : 04/23/2024
Sample ID :
Lab No :
Sampled:SS-2
90346 Matrix:
4/6/2024 10:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):04/09/24 08:00
<0.002 mg/Kg - dry 0.002 0.010 1 04/09/24 17:53 V45887TBL
<0.0008 mg/Kg - dry 0.0008 0.0051,2,3-Trichloropropane 1 04/09/24 17:53 V45887TBL
<0.0005 mg/Kg - dry 0.0005 0.010Vinyl Acetate 1 04/09/24 17:53 V45887TBL
<0.0005 mg/Kg - dry 0.0005 0.010Vinyl Chloride 1 04/09/24 17:53 V45887TBL
<0.0005 mg/Kg - dry 0.0005 0.005o-Xylene 1 04/09/24 17:53 V45887TBL
<0.001 mg/Kg - dry 0.001 0.010m,p-Xylene 1 04/09/24 17:53 V45887TBL
<0.0005 mg/Kg - dry 0.0005 0.005Xylene (Total)1 04/09/24 17:53 V45887
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: Toluene-d8
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 16 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27603
24-100-0103
01186
Smith & Gardner, Inc.
14 N. Boylan Avenue
Seth C. Rickerts
Raleigh
Received : 04/09/2024
GFL Vance 24-1
Revised Report Date: 05/01/2024
Original Report Date : 04/23/2024
Sample ID :
Lab No :
Sampled:SS-1
91715 Matrix:
4/6/2024 10:00
TCLP
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
0.0070 J mg/L 0.004 0.0110SPLP Chromium 1 04/30/24 16:11 6010DSML
0.0020 J mg/L 0.002 0.0110SPLP Cobalt 1 04/30/24 16:11 6010DSML
LeachateSPLP Extraction 1 04/29/24 15:00 1312TJT
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 17 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27603
24-100-0103
01186
Smith & Gardner, Inc.
14 N. Boylan Avenue
Seth C. Rickerts
Raleigh
Received : 04/09/2024
GFL Vance 24-1
Revised Report Date: 05/01/2024
Original Report Date : 04/23/2024
Sample ID :
Lab No :
Sampled:SS-2
91716 Matrix:
4/6/2024 10:30
TCLP
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.0040 mg/L 0.004 0.0110SPLP Chromium 1 04/30/24 16:17 6010DSML
0.0030 J mg/L 0.002 0.0110SPLP Cobalt 1 04/30/24 16:17 6010DSML
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
1312
LeachateSPLP Extraction 1 04/29/24 15:00 L747525TJT
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 18 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77
Quality Control Data
24-100-0103Report No:
Project Description:
Client ID:Smith & Gardner, Inc.
GFL Vance 24-1
QC Prep Batch Method:
Metals Analysis (SPLP)
6010D
L747799QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3015A
QC Prep:L747747
Associated Lab Samples: 91715, 91716
LRB-L747747 Matrix: TCLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
04/30/24 14:180.0110.004<0.004mg/LSPLP Chromium
04/30/24 14:180.0110.002<0.002mg/LSPLP Cobalt
LCS-L747747Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
1111.111.00mg/LSPLP Chromium 80-120
1061.061.00mg/LSPLP Cobalt 80-120
A 77816-MS-L747747 A 77816-MSD-L747747Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
5.77 98.05.775.685.680.193mg/LSPLP Chromium 98.0 75-125 0.0 20
5.42 95.05.435.685.680.037mg/LSPLP Cobalt 95.0 75-125 0.1 20
A 77816-PDS-L747747Post Digestion Spike
Parameter
Analyzed%
Recovery
PDS
ResultUnits
04/30/24 16:321032.96mg/LSPLP Chromium
04/30/24 16:3299.02.77mg/LSPLP Cobalt
Page 1 of 14Date:05/01/2024 01:20 PM
Page 19 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77
Quality Control Data
24-100-0103Report No:
Project Description:
Client ID:Smith & Gardner, Inc.
GFL Vance 24-1
QC Prep Batch Method:
Metals Analyses
6020B
L744621,L744858QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3050B
QC Prep:L744155
Associated Lab Samples: 90345, 90346
LRB-L744155 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
04/12/24 11:360.2500.0308<0.0308mg/KgAntimony
04/12/24 11:360.2500.0855<0.0855mg/KgArsenic
04/12/24 11:360.2500.042<0.042mg/KgBarium
04/12/24 11:360.2500.0198<0.0198mg/KgBeryllium
04/12/24 11:360.2500.0260<0.0260mg/KgCadmium
04/12/24 11:360.2500.0310<0.0310mg/KgLead
04/12/24 11:360.2500.103<0.103mg/KgSelenium
04/12/24 11:360.2500.0067<0.0067mg/KgSilver
04/12/24 11:360.2500.0248<0.0248mg/Kg
04/12/24 11:361.250.221<0.221mg/KgVanadium
LCS-L744155Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
10210.210.0mg/KgAntimony 80-120
1095.475.00mg/KgArsenic 80-120
10610.610.0mg/KgBarium 80-120
1085.405.00mg/KgBeryllium 80-120
1141.141.00mg/KgCadmium 80-120
1065.305.00mg/KgLead 80-120
45.0*4.4510.0mg/KgSelenium 80-120
1141.141.00mg/KgSilver 80-120
1011.011.00mg/Kg 80-120
11859.250.0mg/KgVanadium 80-120
Page 2 of 14* QC Fail Date:05/01/2024 01:20 PM
Page 20 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77
Quality Control Data
24-100-0103Report No:
Project Description:
Client ID:Smith & Gardner, Inc.
GFL Vance 24-1
QC Prep Batch Method:
Metals Analyses
6020B
L744621,L744858QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3050B
QC Prep:L744155
V 90346-MS-L744155 V 90346-MSD-L744155Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
0.708 15.0*0.7484.994.83<0.0308mg/KgAntimony 15.0*75-125 5.4 80
2.41 68.0*2.382.492.410.778mg/KgArsenic 64.0*75-125 1.2 80
136 21.0*1414.994.83135mg/KgBarium 120 75-125 3.6 80
2.50 94.02.532.492.410.240mg/KgBeryllium 92.0 75-125 1.1 80
0.507 99.00.5230.4990.4830.0294mg/KgCadmium 99.0 75-125 3.1 80
3.18 92.03.302.492.410.969mg/KgLead 94.0 75-125 3.7 80
3.15 63.0*3.264.994.830.105mg/KgSelenium 63.0*75-125 3.4 80
0.488 99.00.4980.4990.4830.0082mg/KgSilver 98.0 75-125 2.0 80
0.504 78.00.5260.4990.4830.129mg/Kg 80.0 75-125 4.2 80
90.2 99.088.724.924.166.3mg/KgVanadium 90.0 75-125 1.6 80
V 90346-PDS-L744155Post Digestion Spike
Parameter
Analyzed%
Recovery
PDS
ResultUnits
04/12/24 13:0688.02.12mg/KgAntimony
04/12/24 13:0692.01.17mg/KgArsenic
04/12/24 13:0610015.9mg/KgBarium
04/12/24 13:0696.01.17mg/KgBeryllium
04/12/24 13:061040.254mg/KgCadmium
04/12/24 13:0698.01.28mg/KgLead
04/15/24 18:3191.02.19mg/KgSelenium
04/12/24 13:061020.245mg/KgSilver
04/12/24 13:0690.00.228mg/Kg
04/12/24 13:0699.018.5mg/KgVanadium
Page 3 of 14* QC Fail Date:05/01/2024 01:20 PM
Page 21 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77
Quality Control Data
24-100-0103Report No:
Project Description:
Client ID:Smith & Gardner, Inc.
GFL Vance 24-1
QC Prep Batch Method:
Metals Analyses
6020B
L745466,L746008QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3050B
QC Prep:L744945
Associated Lab Samples: 90345, 90346
LRB-L744945 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
04/17/24 14:160.2500.116<0.116mg/KgChromium
04/17/24 14:160.2500.028<0.028mg/KgCobalt
04/17/24 14:160.2500.0805<0.0805mg/KgCopper
04/17/24 14:160.2500.0635<0.0635mg/KgNickel
04/17/24 14:162.500.535<0.535mg/KgZinc
LCS-L744945Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
1075.355.00mg/KgChromium 80-120
97.04.855.00mg/KgCobalt 80-120
95.02.372.50mg/KgCopper 80-120
96.02.412.50mg/KgNickel 80-120
10125.225.0mg/KgZinc 80-120
V 90346-MS-L744945 V 90346-MSD-L744945Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
21.7 0.0*22.84.784.7522.4mg/KgChromium 8.0*75-125 4.9 80
19.8 0.0*23.04.784.7524.2mg/KgCobalt 0.0*75-125 14.9 80
46.7 55.0*44.82.392.3745.4mg/KgCopper 0.0*75-125 4.1 80
24.3 97.023.22.392.3722.0mg/KgNickel 50.0*75-125 4.6 80
69.8 11.0*72.623.923.767.1mg/KgZinc 23.0*75-125 3.9 80
Page 4 of 14* QC Fail Date:05/01/2024 01:20 PM
Page 22 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77
Quality Control Data
24-100-0103Report No:
Project Description:
Client ID:Smith & Gardner, Inc.
GFL Vance 24-1
QC Prep Batch Method:
Metals Analyses
6020B
L745466,L746008QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3050B
QC Prep:L744945
V 90346-PDS-L744945Post Digestion Spike
Parameter
Analyzed%
Recovery
PDS
ResultUnits
04/17/24 16:3287.04.11mg/KgChromium
04/17/24 16:3277.03.77mg/KgCobalt
04/19/24 17:5285.04.92mg/KgCopper
04/19/24 17:5288.03.02mg/KgNickel
04/17/24 16:3286.016.3mg/KgZinc
Page 5 of 14Date:05/01/2024 01:20 PM
Page 23 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77
Quality Control Data
24-100-0103Report No:
Project Description:
Client ID:Smith & Gardner, Inc.
GFL Vance 24-1
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D SIM
V45881QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V45880
Associated Lab Samples: 90345, 90346
LRB-V45880 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/09/24 19:500.0020.0001<0.0001mg/Kg1,4-Dioxane
04/09/24 19:504-Bromofluorobenzene (S)123 70-130
LCS-V45880Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
88.20.0440.050mg/Kg1,4-Dioxane 70-130
92.24-Bromofluorobenzene (S)70-130
V 90345-MS-V45880 V 90345-MSD-V45880Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
0.032 65.8*0.0330.0500.050<0.0001mg/Kg1,4-Dioxane 67.0*70-130 1.8 20
1224-Bromofluorobenzene (S)124 70-130
Page 6 of 14* QC Fail Date:05/01/2024 01:20 PM
Page 24 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77
Quality Control Data
24-100-0103Report No:
Project Description:
Client ID:Smith & Gardner, Inc.
GFL Vance 24-1
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V45887QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V45886
Associated Lab Samples: 90345, 90346
LRB-V45886 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/09/24 14:520.0200.002<0.002mg/KgAcetone
04/09/24 14:520.0200.0008<0.0008mg/KgAcrylonitrile
04/09/24 14:520.0050.0006<0.0006mg/KgBenzene
04/09/24 14:520.0050.0008<0.0008mg/KgBromochloromethane
04/09/24 14:520.0050.001<0.001mg/KgBromodichloromethane
04/09/24 14:520.0050.001<0.001mg/KgBromoform
04/09/24 14:520.0100.001<0.001mg/KgBromomethane
04/09/24 14:520.0050.0006<0.0006mg/KgCarbon Disulfide
04/09/24 14:520.0050.001<0.001mg/KgCarbon Tetrachloride
04/09/24 14:520.0050.0007<0.0007mg/KgChlorobenzene
04/09/24 14:520.0050.0009<0.0009mg/KgChlorodibromomethane
04/09/24 14:520.0100.0009<0.0009mg/KgChloroethane
04/09/24 14:520.0050.001<0.001mg/KgChloroform
04/09/24 14:520.0100.0006<0.0006mg/KgChloromethane
04/09/24 14:520.0050.0007<0.0007mg/KgDi-Isopropyl Ether (DIPE)
04/09/24 14:520.0100.0004<0.0004mg/Kg1,2-Dibromo-3-Chloropropane
04/09/24 14:520.0050.0006<0.0006mg/Kg1,2-Dibromoethane
04/09/24 14:520.0050.0006<0.0006mg/KgDibromomethane
04/09/24 14:520.0100.0007<0.0007mg/Kgtrans-1,4-Dichloro-2-butene
04/09/24 14:520.0050.0003<0.0003mg/Kg1,2-Dichlorobenzene
04/09/24 14:520.0100.001<0.001mg/KgDichlorodifluoromethane
04/09/24 14:520.0050.0008<0.0008mg/Kg1,1-Dichloroethane
04/09/24 14:520.0050.001<0.001mg/Kg1,2-Dichloroethane
04/09/24 14:520.0050.0007<0.0007mg/Kg1,1-Dichloroethene
04/09/24 14:520.0050.0008<0.0008mg/Kgcis-1,2-Dichloroethene
04/09/24 14:520.0050.001<0.001mg/Kgtrans-1,2-Dichloroethene
04/09/24 14:520.0050.0004<0.0004mg/Kg1,2-Dichloropropane
Page 7 of 14Date:05/01/2024 01:20 PM
Page 25 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77
Quality Control Data
24-100-0103Report No:
Project Description:
Client ID:Smith & Gardner, Inc.
GFL Vance 24-1
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V45887QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V45886
Associated Lab Samples: 90345, 90346
LRB-V45886 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/09/24 14:520.0050.0005<0.0005mg/Kgcis-1,3-Dichloropropene
04/09/24 14:520.0050.0008<0.0008mg/Kgtrans-1,3-Dichloropropene
04/09/24 14:520.1000.014<0.014mg/Kg1,4-Dioxane
04/09/24 14:520.0050.0006<0.0006mg/KgEthylbenzene
04/09/24 14:520.0200.0006<0.0006mg/Kg2-Hexanone
04/09/24 14:520.0200.0007<0.0007mg/KgMethyl Ethyl Ketone (MEK)
04/09/24 14:520.0200.015<0.015mg/Kg4-Methyl-2-Pentanone
04/09/24 14:520.0100.001<0.001mg/KgMethylene Chloride
04/09/24 14:520.0050.001<0.001mg/KgStyrene
04/09/24 14:520.0050.001<0.001mg/Kg1,1,1,2-Tetrachloroethane
04/09/24 14:520.0050.0003<0.0003mg/Kg1,1,2,2-Tetrachloroethane
04/09/24 14:520.0050.0009<0.0009mg/Kg
04/09/24 14:520.0050.0009<0.0009mg/Kg
04/09/24 14:520.0050.0007<0.0007mg/Kg
04/09/24 14:520.0050.001<0.001mg/Kg1,1,1-Trichloroethane
04/09/24 14:520.0050.0005<0.0005mg/Kg1,1,2-Trichloroethane
04/09/24 14:520.0050.0009<0.0009mg/Kg
04/09/24 14:520.0100.002<0.002mg/Kg
04/09/24 14:520.0050.0007<0.0007mg/Kg1,2,3-Trichloropropane
04/09/24 14:520.0100.0005<0.0005mg/KgVinyl Acetate
04/09/24 14:520.0100.0005<0.0005mg/KgVinyl Chloride
04/09/24 14:520.0050.0005<0.0005mg/Kgo-Xylene
04/09/24 14:520.0100.001<0.001mg/Kgm,p-Xylene
04/09/24 14:524-Bromofluorobenzene (S)101 70-130
04/09/24 14:52Dibromofluoromethane (S)101 84-123
04/09/24 14:52 90.2 76-129
Page 8 of 14Date:05/01/2024 01:20 PM
Page 26 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77
Quality Control Data
24-100-0103Report No:
Project Description:
Client ID:Smith & Gardner, Inc.
GFL Vance 24-1
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V45887QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V45886
LCS-V45886 LCSD-V45886Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.111 1111210.1210.100mg/KgAcetone 29-198 8.6 20
0.093 93.394.90.0940.100mg/KgAcrylonitrile 65-134 1.7 20
0.042 85.487.80.0430.050mg/KgBenzene 74-127 2.7 20
0.043 87.291.80.0450.050mg/KgBromochloromethane 72-134 5.1 20
0.044 89.490.00.0450.050mg/KgBromodichloromethane 75-122 0.6 20
0.041 83.486.80.0430.050mg/KgBromoform 66-135 3.9 20
0.049 98.294.60.0470.050mg/KgBromomethane 20-180 3.7 20
0.042 85.289.40.0440.050mg/KgCarbon Disulfide 61-129 4.8 20
0.042 84.890.40.0450.050mg/KgCarbon Tetrachloride 64-143 6.3 20
0.039 79.081.40.0400.050mg/KgChlorobenzene 74-118 2.9 20
0.040 80.883.80.0410.050mg/KgChlorodibromomethane 73-122 3.6 20
0.048 96.699.60.0490.050mg/KgChloroethane 33-149 3.0 20
0.043 86.489.00.0440.050mg/KgChloroform 73-127 2.9 20
0.036 73.275.20.0370.050mg/KgChloromethane 45-143 2.6 20
0.042 85.285.60.0420.050mg/KgDi-Isopropyl Ether (DIPE)59-159 0.4 20
0.040 81.085.20.0420.050mg/Kg1,2-Dibromo-3-Chloropropane 55-157 5.0 20
0.042 85.887.40.0430.050mg/Kg1,2-Dibromoethane 70-132 1.8 20
0.046 92.293.80.0460.050mg/KgDibromomethane 74-133 1.7 20
0.035 70.873.40.0360.050mg/Kgtrans-1,4-Dichloro-2-butene 70-130 3.6 20
0.037 75.276.00.0380.050mg/Kg1,2-Dichlorobenzene 72-123 1.0 20
0.043 86.893.00.0460.050mg/KgDichlorodifluoromethane 26-146 6.8 20
0.041 82.886.20.0430.050mg/Kg1,1-Dichloroethane 74-127 4.0 20
0.045 90.093.80.0460.050mg/Kg1,2-Dichloroethane 68-128 4.1 20
0.040 81.486.00.0430.050mg/Kg1,1-Dichloroethene 67-149 5.4 20
0.042 85.687.00.0430.050mg/Kgcis-1,2-Dichloroethene 76-134 1.6 20
0.042 84.086.80.0430.050mg/Kgtrans-1,2-Dichloroethene 73-132 3.2 20
Page 9 of 14Date:05/01/2024 01:20 PM
Page 27 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77
Quality Control Data
24-100-0103Report No:
Project Description:
Client ID:Smith & Gardner, Inc.
GFL Vance 24-1
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V45887QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V45886
LCS-V45886 LCSD-V45886Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.043 86.088.40.0440.050mg/Kg1,2-Dichloropropane 73-130 2.7 20
0.045 91.091.80.0450.050mg/Kgcis-1,3-Dichloropropene 71-125 0.8 20
0.048 96.298.20.0490.050mg/Kgtrans-1,3-Dichloropropene 68-123 2.0 20
0.539 1081090.5440.500mg/Kg1,4-Dioxane 70-130 0.9 20
0.039 78.682.00.0410.050mg/KgEthylbenzene 74-128 4.2 20
0.045 90.099.80.0490.050mg/Kg2-Hexanone 61-157 10.3 20
0.052 1051110.0550.050mg/KgMethyl Ethyl Ketone (MEK)63-149 6.2 20
0.046 93.499.80.0490.050mg/Kg4-Methyl-2-Pentanone 57-162 6.6 20
0.039 78.280.00.0400.050mg/KgMethylene Chloride 74-129 2.2 20
0.042 85.487.80.0430.050mg/KgStyrene 77-121 2.7 20
0.039 79.881.60.0400.050mg/Kg1,1,1,2-Tetrachloroethane 72-115 2.2 20
0.039 78.479.40.0390.050mg/Kg1,1,2,2-Tetrachloroethane 56-126 1.2 20
0.043 87.291.60.0450.050mg/Kg 68-130 4.9 20
0.046 93.297.20.0480.050mg/Kg 70-130 4.2 20
0.043 86.088.00.0440.050mg/Kg 71-129 2.2 20
0.042 85.087.80.0430.050mg/Kg1,1,1-Trichloroethane 67-131 3.2 20
0.040 81.083.40.0410.050mg/Kg1,1,2-Trichloroethane 70-133 2.9 20
0.042 84.887.80.0430.050mg/Kg 75-133 3.4 20
0.044 88.695.20.0470.050mg/Kg 44-146 7.1 20
0.040 81.281.80.0400.050mg/Kg1,2,3-Trichloropropane 60-137 0.7 20
0.049 99.01080.0540.050mg/KgVinyl Acetate 60-140 8.6 20
0.040 81.086.40.0430.050mg/KgVinyl Chloride 48-147 6.4 20
0.040 81.483.60.0410.050mg/Kgo-Xylene 74-126 2.6 20
0.080 80.583.40.0830.100mg/Kgm,p-Xylene 75-124 3.5 20
97.095.84-Bromofluorobenzene (S)70-130
100100Dibromofluoromethane (S)84-123
Page 10 of 14Date:05/01/2024 01:20 PM
Page 28 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77
Quality Control Data
24-100-0103Report No:
Project Description:
Client ID:Smith & Gardner, Inc.
GFL Vance 24-1
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V45887QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V45886
LCS-V45886 LCSD-V45886Laboratory Control Sample & LCSD
LCSD
ResultParameter
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
90.490.6 76-129
Page 11 of 14Date:05/01/2024 01:20 PM
Page 29 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77
Quality Control Data
24-100-0103Report No:
Project Description:
Client ID:Smith & Gardner, Inc.
GFL Vance 24-1
pH in Solids
9045D
V46604QC Analytical Batch:
Analysis Method:
Analysis Description:
LCSLaboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
1006.876.86s.u.pH
V 90345-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 04/29/24 13:080.27.807.82s.u.pH
Page 12 of 14Date:05/01/2024 01:20 PM
Page 30 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77
Quality Control Data
24-100-0103Report No:
Project Description:
Client ID:Smith & Gardner, Inc.
GFL Vance 24-1
QC Prep Batch Method:
Hexavalent Chromium by Ion Chromatography
SW-7199
L747386QC Analytical Batch(es):
Analysis Method:
Analysis Description:
SW-3060A
QC Prep:L746885
Associated Lab Samples: 90345, 90346
LRB-L746885 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
04/29/24 15:560.2000.141<0.141mg/KgChromium, Hexavalent
LCS-L746885Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
92.03.674.00mg/KgChromium, Hexavalent 80-120
V 90345-DUP-L746885Duplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 04/29/24 16:290.0<0.200< 0.200mg/KgChromium, Hexavalent
V 90345-MS-L746885Matrix Spike
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
35.8 91.039.2< 1.38mg/KgChromium, Hexavalent 75-125
Page 13 of 14Date:05/01/2024 01:20 PM
Page 31 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77
Quality Control Data
24-100-0103Report No:
Project Description:
Client ID:Smith & Gardner, Inc.
GFL Vance 24-1
Dry Weight Determination
SW-DRYWT
V45870QC Analytical Batch:
Analysis Method:
Analysis Description:
V 90333-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 04/10/24 12:302.014.614.3%Moisture
V 90334-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 04/10/24 12:301.314.714.9%Moisture
Page 14 of 14Date:05/01/2024 01:20 PM
Page 32 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:24-100-0103
Smith & Gardner, Inc.
01186
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 3.2C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)?Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
ü
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)ü
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angela D Overcash Date & Time:04/09/2024 14:32:17
Special precautions or instructions included?
Comments:
Page 33 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77
Page 34 of 34
DocuSign Envelope ID: 5CD0B724-5692-4E64-838C-24FC063D6C77