24025_Crayton Printing - VIMS Install - Western Section_20240423

Via Email April 23, 2024
NCDEQ – Division of Waste Management Brownfields Program 1646 Mail Service Center Raleigh, NC 27699-1646
Attn: Mr. Bill Schmithorst Re: Vapor Intrusion Mitigation System Installation Completion Report – Western Section Crayton Printing
Distribution and Dunavant Street Charlotte, North Carolina Brownfields Project No. 24025-20-060 H&H Project No. AKR-005
Dear Mr. Schmithorst: On behalf of KA D&D Holdings LLC., Hart & Hickman, PC (H&H) has prepared the attached VIMS Installation Completion Report – Western Section, dated April 23, 2024 for the eastern portion of the development at the Crayton Printing Brownfields property located in Charlotte,
Mecklenburg County. Should you have questions or need additional information, please do not hesitate to contact us at [phone].

Sincerely, Hart & Hickman, PC
Trinh DeSa, PE Matt Bramblett, PE Engineering Manager Principal
Attachments cc: Mr. Dan Coith and Mr. Dan Outen, Akridge (Via Email) Ms. Mary Katherine Stukes and Ms. Laura Truesdale, Moore & Van Allen (Via Email) Ms. Haley Martin, H&H (Via Email)

VIMS Installation Completion Report
Western Section

Crayton Printing
Distribution Street and Dunavant Street
Charlotte, North Carolina

Brownfields Project No. 24025-20-060

H&H Job No. AKR.005 April 23, 2024

#C-1269 Engineering #C-245 Geology
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VIMS Installation Completion Report – Western Section Crayton Printing Distribution Street and Dunavant Street Brownfields Project No. 24025-20-060 Charlotte, North Carolina H&H Job No. AKR.005 Table of Contents 1.0 Introduction .............................................................................................................................1
2.0 VIMS Installation and Influence Testing .............................................................................4
2.1 VIMS Installation ..................................................................................................................4
2.2 VIMS Influence Testing ........................................................................................................6
3.0 Pre-Occupancy VIMS Effectiveness Sampling ....................................................................8
3.1 Sub-Slab Soil Vapor Sampling Methodology .......................................................................8
3.2 Indoor Air Sampling Methodology .......................................................................................9
3.3 Building Survey Activities ..................................................................................................11
3.4 Sub-Slab Soil Vapor Sampling Results ...............................................................................12
3.5 Indoor Air Sampling Results ...............................................................................................13
3.6 Vapor Intrusion Evaluation .................................................................................................15
4.0 Summary and Conclusions ..................................................................................................17
5.0 Recommendation to Change Post-Occupancy Sampling Frequency ...............................20
6.0 Engineer’s Certification ........................................................................................................21

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List of Tables

Table 1 Summary of Sub-Slab Soil Vapor Analytical Results
Table 2 Summary of Indoor Air Analytical Results
List of Figures

Figure 1 Site Location Map
Figure 2 Site Map
Figure 3A Indoor Air and Sub-Slab Vapor Sample Location Map - Level 1

List of Appendices

Appendix A Historical Data Summary Tables and Sample Location Maps
Appendix B As-Built Drawings (dated March 25, 2024)
Appendix C VIMS Installation Photographs
Appendix D VIMS Product Specification Sheets
Appendix E Field Forms and Field Data
Appendix F Laboratory Analytical Reports
Appendix G DEQ Risk Calculators
Appendix H Construction Safety Data Sheets
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VIMS Installation Completion Report – Western Section Crayton Printing Distribution Street and Dunavant Street Brownfields Project No. 24025-20-060 Charlotte, North Carolina H&H Job No. AKR.005 1.0 Introduction

On behalf of KA D&D Holdings LLC (Prospective Developer, PD), Hart & Hickman, PC (H&H)
has prepared this report to document vapor intrusion mitigation system (VIMS) installation,
influence testing, and post-construction sub-slab and indoor air vapor assessment activities
completed for the Western Section of the Hawkins Press Apartments. This development is located
on the Crayton Printing Brownfields property (Brownfields Project No. 24025-20-060) located at
the intersection of Distribution Street and Dunavant Street in Charlotte, Mecklenburg County,
North Carolina (Site or subject Site). The Site consists of an approximate 2.85-acre parcel of land
(Parcel Identification Number 12104201) which is being redeveloped with a seven-story high-
density multi-family apartment building, known as Hawkins Press Apartments. A Site location
map is provided as Figure 1, and a Site map is provided as Figure 2.

Vapor intrusion assessment was completed at the Site in September 2020 and was documented in
the Brownfields Assessment Report prepared by H&H and dated October 6, 2020. A review of the
sub-slab vapor sample results identified exceedances of the residential screening levels and
allowable risk levels based on hypothetical worst-case risk calculations in multiple samples (SS-
2, SS-3, SS-7, SG-1, SG-2, SG-3, and SG-4). The risk exceedances were a result of petroleum
compound concentrations (benzene, ethylbenzene, and xylenes) in the Site soil gas samples, as
well as tetrachloroethylene (PCE) and dichlorodifluoromethane in sub-slab samples SS-2 and SS-
7, respectively. Prior data summary tables and sample location maps are provided in Appendix A.

A Brownfields Agreement between the North Carolina Department of Environmental Quality
(DEQ) and the PD was recorded for the Site on October 1, 2021. Land Use Restriction (LUR)
12(h) in the recorded Brownfields Agreement generally states that no enclosed building may be
constructed on the property until DEQ determines in writing that the building would be protective
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of users from risks of potential vapor intrusion. To address DEQ Brownfields requirements, H&H
prepared a Vapor Intrusion Mitigation Plan (VIMP) and revisions to the VIMP based on DEQ
comments. The VIMP revision dated August 24, 2021 was approved by DEQ in an email dated
August 24, 2021. H&H also prepared the Post-Construction VIMS Sampling Work Plan - Revision
1 dated December 21, 2021 that described the proposed post-construction (post-occupancy)
analytical sampling, which was approved by DEQ in an email dated December 22, 2021.

The VIMP includes installation of a passive VIMS below enclosed ground floor areas of the
building. This excludes the open-air parking garage because the garage is not enclosed and is
naturally and mechanically ventilated. Based on the building layout, the VIMS was separated into
different sections to optimize performance. Each VIMS section operates as a passive sub-slab
venting system that includes a network of horizontal sub-slab and vertical above slab riser piping
connected to wind-driven turbine ventilators installed above the building roof. Further, a vapor
barrier was installed below the slab and along select vertical walls.

On the west side, Level 1 of the apartment building is located completely on grade and consists of
apartment units, open-air parking, leasing, office, amenity, mechanical, and building services
areas. The enclosed space of the ground floor is approximately 25,000 sq ft. Due to the natural
rise in grade at the Site from northwest to southeast, Level 2 is partially located over the ground
level floor (northwestern portion), and approximately 32,000 sq ft of Level 2 is located on grade
(southeastern portion). Level 2 and subsequently higher levels consist of residences and
mechanical rooms. The apartment building has been constructed in sections with multiple
turnovers, or occupancy dates, planned for two different sections of the building. For ease of
reference, these two building sections are referred to as the Western Section and Eastern Section.
The Western and Eastern Sections are depicted in Figure 2.

The Eastern Section of the building contains a split level. Level 1 is comprised of utility and
amenity spaces on the southern side, and the leasing office is located on the northern side of the
building. Level 2 consists of residential units located on the ground floor and residential units
located above the Level 1 spaces. The Western Section consist of residential units on the ground
floor of Level 1. The Western and Eastern Sections are separated on the ground floor by the open-
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air parking garage. On the upper floors, the building sections along the southern portion of the
parking garage are interconnected with a hallway and apartment units. A fire door separates the
Western and Eastern Sections on each upper floor and these doors act to prevent direct air transfer
across the building sections.

The VIMS installation and post-construction analytical testing for the Eastern Section was
documented in the VIMS Installation Completion Report – Eastern Section, dated October 16,
2023, with compliance approval granted by DEQ for the Eastern Section in a letter dated
November 8, 2023. As indicated in the report prepared for the Eastern Section, a portion of the
concrete slab remained unfinished at the time of the report submittal because the area was utilized
as an ingress/egress for the crane and construction equipment staged in the courtyard. The slab
leave out location is shown on drawing VM-2 in Appendix B. The slab leave-out area has since
been completed, inspected, and tested as described in Section 2.0.

This report has been prepared to document the VIMS installation for the Western Section of the
building, and thus the completion of the VIMS for the entire building. A discussion of VIMS
installation and influence testing activities for the Western Section of the building is provided in
Section 2.0; a summary of VIMS effectiveness sampling activities is provided in Section 3.0;
summary and conclusions based on the results of the VIMS installation, soil vapor, and indoor air
assessment activities are provided in Section 4.0; a recommendation to modify post-occupancy
sampling frequency is in Section 5.0; and the engineer’s certification statement is provided in
Section 6.0.

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2.0 VIMS Installation and Influence Testing

Summaries of the VIMS inspections and influence testing for the Western Section of the building
and the slab leave out area in the Eastern Section are described in the following sections. As-built
drawings depicting the layout of the VIMS (VM-1) and the system specifications and details (VM-
2, VM-2, VM-3, and VM-3A) are provided in Appendix B. Representative installation
photographs are included in Appendix C, and product specifications for the main VIMS
components are included in Appendix D.

2.1 VIMS Installation
During installation of the VIMS, H&H conducted inspections during various phases of
construction to confirm the VIMS was installed in accordance with the DEQ-approved VIMP.
Inspections were completed by or under direction of a North Carolina Professional Engineer during
the following phases of installation:
(1) Inspection of the base course gravel layer, sub-slab piping layout, and monitoring points
prior to installing the vapor barrier;
(2) Inspection of the vapor barrier prior to pouring concrete and inspection of vapor barrier
at elevator pits and select vertical walls prior to backfilling around the walls;
(3) Inspection of riser pipe connections and above-grade vertical riser piping; and
(4) Inspection of turbine ventilators on the rooftop.

Based on observations made during the VIMS inspections, the VIMS was installed in general
accordance with the DEQ-approved VIMP. An H&H inspection checklist is provided in Appendix
E which indicates installation of the VIMS in accordance with the manufacturer instructions.
There were no notable modifications from the DEQ-approved VIMP drawings. A summary of the
main VIMS components is provided in the following paragraphs.

Passive sub-slab vapor extraction is achieved through an interconnected system of 3-inch Schedule
(SCH) 40 PVC perforated vapor collection/conveyance piping installed in a 5-inch permeable
gravel layer beneath the building. The permeable gravel layer (clean #57 stone) was installed
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beneath the mitigated areas of the building to enhance sub-slab vapor transmission and allow for
air movement beneath the slab. The sub-slab vapor collection piping is connected to five (5) 3-
inch SCH 40 PVC risers (F-2 through F-6) in the Western Section which extend vertically through
the building and discharge collected vapors above the roof of the building. The roof of the building
is a flat roof with parapets along the perimeter. Empire Model TV04SS (stainless steel) turbine
ventilators were installed on the discharge of the exhaust stacks on the roof to enhance the air flow
from the risers during times of wind.

Vaporblock® Plus 20 (VBP20), a vapor barrier manufactured by Viaflex, Inc. (Viaflex), formerly
known as Raven, was installed above the gravel layer and beneath the concrete slab of the building.
VBP20 is an ASTM-certified 20-mil, multi-layer, chemically-resistant vapor barrier designed to
prevent structural vapor intrusion of volatile organic compounds (VOCs). The vapor barrier was
installed by the construction contractor to cover the footprint of enclosed building spaces. Vapor
barrier was also installed along the base and sidewalls of the elevator pit and along select vertical
retaining walls as depicted in the as-built drawings (Appendix B). Briefly, the exterior edges of
the VBP20 were laid underneath the footings and/or attached and sealed to existing concrete
utilizing VaporSeal™ tape and Butyl Seal double-sided tape. Seams within the building footprint
were installed with a minimum 12-inch overlap and were sealed with VaporSeal™ tape. Product
specifications are provided in Appendix D. Utility banks containing multiple utility conduits that
couldn’t be sealed using standard tape and patch methods were sealed using Viaflex Pour-N-
Seal™.

The VIMS also includes permanent monitoring points constructed with 2-inch diameter SCH 40
PVC pipes. The Western Section of the building includes a total of seven (7) permanent
monitoring points (MP-3 through MP-9). The monitoring points were used to measure the pressure
differential between ambient air and the sub-slab during influence testing activities described
below and for collection of sub-slab vapor samples (Section 3.0). To prevent entering the
residential units during future monitoring events, the monitoring point access ports are generally
located in stairwells, corridors, maintenance rooms, and/or mounted in exterior walls. Several
monitoring points are connected to extended sub-slab horizontal pipes which place the intake of
the monitoring point below occupied residential spaces. The monitoring points are secured within
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a flush-mount sewer cleanout-type cover or wall-mounted box and an expandable well plug located
on the 2-inch pipe that allows for an airtight seal. Note, as the date of this report, several of the
monitoring points don’t contain the final flush-mount or wall-mounted covers due to flooring and
other finishing activities currently underway near the monitoring points. Prior to building
occupancy, an inspection of the completed monitoring points will be conducted by H&H to
confirm the final covers are installed.

2.2 VIMS Influence Testing
On May 18, 2023, H&H completed initial influence (pilot) testing on the VIMS to evaluate
sub-slab vacuum communication across the slab and document that sufficient depressurization can
be obtained should electric fans be needed in the future. DEQ considers 4 Pascals (Pa), or 0.016-
inches in-WC differential pressure the minimum vacuum needed for an active depressurization
system to effectively treat potential structural vapor intrusion. The influence test was completed
for both the Western and Eastern sections of the building on the same day and the Eastern Section
results were previously reported under separate cover.

VIMS vacuum influence pilot testing included use of the Festa AMG Eagle Extreme (Eagle
Extreme) fans to model an active depressurization system. An Eagle Extreme is a standard radon
mitigation style electric fan. Differential pressure measurements were collected at each vacuum
monitoring point using a Dwyer series 475 Mark III Digital manometer (capable of measuring
0.001 in-WC or 0.25 Pa) to establish baseline conditions prior to operation of the Eagle Extreme
electric fans. Following collection of baseline differential pressure measurements, the electric fans
were turned on and differential pressure measurements were collected at each monitoring point.

Results of the May 2023 influence tests indicated sub-slab vacuum measured at the monitoring
points (MP-3 through MP-9) on the Western Section ranged from 0.261 in-WC to 0.865 in-WC,
which demonstrates vacuum above the DEQ minimum of 0.016 in-WC could be achieved using
standard electric fans to pull air from below the slab of each VIMS area. The locations of the
permanent monitoring points (denoted by MP nomenclature) are shown in sheets VM-1 and VM-
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2 included in Appendix D. The influence test data are summarized in Table E-1 provided in
Appendix E.

In addition, the temporary slab leave-out area depicted in the as-built drawings for the crane access
to the courtyard was completed in January 2024. Therefore, an additional influence test was
conducted for this portion of the building to verify connectivity of the sub-slab pipe network below
the completed slab. On January 30, 2024, H&H performed additional pilot testing by temporarily
placing electric fans on risers F-10, F-12, and F-14 located north of the leave-out area and
measured vacuum at monitoring points located to the south of the leave-out area. Results of the
influence test indicated that vacuum was achieved in monitoring points MP-16 and MP-17 during
the January 2024 test, which verifies sub-slab connectivity across the completed VIMS in the
leave-out area. Note, the vacuum levels measured during the January 2024 influence test were
lower than the levels measured during the May 2023 influence test due to fewer electric fans placed
on risers during the January 2024 test. The influence test data from January 2024 is summarized
in Table E-2 provided in Appendix E.

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3.0 Pre-Occupancy VIMS Effectiveness Sampling

Following installation of the VIMS in the Western Section, completion of successful influence
testing, and enclosure of the building envelope, H&H collected four (4) sub-slab soil vapor
samples and five (5) indoor air samples. Comparison of the sub-slab vapor sample data to the
indoor air sample data allows for evaluation of potential above slab interference due to the use of
construction materials and activities in and near VIMS treatment areas at the time of indoor air
sampling activities.

The sub-slab soil vapor and indoor air assessment activities were conducted in accordance with
the DEQ-approved VIMP, the Post-Construction VIMS Sampling Work Plan – Revision 1 dated
December 21, 2021, and the DEQ DWM Vapor Intrusion Guidance (Guidance) dated March 2018.
Details of the sub-slab soil vapor and indoor air sampling activities and results are provided in the
following sections.

3.1 Sub-Slab Soil Vapor Sampling Methodology

H&H collected sub-slab soil vapor samples from select permanent monitoring points within the
Western Section of the building on January 7, 2024. The sampling was performed following VIMS
installation activities including several months after installation of the risers to the rooftop and
turbine ventilators on the riser discharge. As shown on Figure 3A, the sub-slab soil vapor samples
were collected from permanent monitoring points MP-3, MP-6, and MP-8, and MP-9.

To collect the sub-slab soil vapor samples, Teflon sample tubing was attached to a 2-inch
expandable well cap with a sampling port that was secured onto the 2-inch diameter PVC
monitoring point. The tubing was connected to an airflow regulator and laboratory-supplied
batch-certified 1-liter stainless steel Summa canister. The air flow regulator was preset by the
laboratory to collect a soil vapor sample over a 10-minute period at a flow rate of approximately
100 milliliters per minute.

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Prior to sample collection, H&H conducted a leak test at each monitoring point by placing a shroud
around the monitoring point, expandable well cap, and sampling train including the Summa
canister. The air within the shroud was flooded with helium vapor and concentrations were
measured with a calibrated helium detector. Helium concentrations within the shroud were
maintained between approximately 10% and 13%. A GilAir vacuum pump was connected to the
sample tubing outside of the shroud and used to purge a minimum of three volumes (monitoring
point and sample train) of soil vapor into a Tedlar® bag at each sampling point. The helium vapor
detector was used to measure helium concentrations within the Tedlar bag sample to confirm
helium concentrations in the sample train were less than 10% of that measured within the shroud.
Results of the helium leak checks indicate that no unacceptable short-circuiting at the monitoring
points or within the sampling train occurred. Sub-slab vapor sampling field forms completed by
field personnel are included in Appendix E.

Following successful leak checks, the air flow regulators were opened to allow collection of the
sub-slab vapor samples. Vacuum in the Summa canisters was monitored during the sampling
event to confirm adequate sample volume was collected at each monitoring point location. Upon
completion of sample collection, the air flow regulator was closed to the Summa canister. The
canisters were labeled with the sample identification, beginning and ending times, pressure
measurements, and the requested analysis. The canisters were then placed in laboratory supplied
shipping containers and delivered to Pace Analytical Services (Pace) under standard chain of
custody protocols for analysis of VOCs by Environmental Protection Agency (EPA) Method TO-
15.

3.2 Indoor Air Sampling Methodology
On January 6 and 7, 2024, H&H collected five (5) indoor air samples from within the Site building
prior to the collection of the sub-slab soil vapor samples. The indoor air samples were collected
prior to sub-slab soil vapor samples to avoid potential cross-contamination associated with
temporarily opening and purging the monitoring points.

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Heating, ventilation, and air conditioning (HVAC) equipment had not yet been installed during
the January 2024 sampling event, but the building was enclosed with walls, exterior doors, and
windows in place. During the indoor air sampling, exterior doors and windows were closed, but
interior doors in the vicinity of the sample locations were left open. The locations of the indoor
air samples are shown on Figure 3A and are described below.

• Sample IAS-2 (co-located with sub-slab vapor sample MP-3) was collected from the
resident’s storage area.
• Sample IAS-3 (co-located with sub-slab vapor sample MP-6) was collected from a
residential unit in the southwestern portion of the Site building.
• Sample IAS-4 (co-located with sub-slab vapor sample MP-8) was collected from a
residential unit in the central western portion of the Site building.
• Sample IAS-5 (co-located with sub-slab vapor sample MP-9) was collected from a
residential unit in the northwestern portion of the Site building.

In addition to the indoor air samples described above, one exterior background ambient air sample
(IAS-BKG) was collected concurrently with the indoor air samples. The location of the
background sample was upwind of the Site building as determined the day of the sampling event
based on the prevailing wind direction. The location of the background ambient air sample BAS-
1 is shown in Figure 3A.

The indoor air samples were collected using 6-liter stainless steel individually-certified Summa
sample canisters connected to in-line flow controllers with a vacuum gauge. The background air
sample was collected using a 6-liter stainless steel batch-certified Summa sample canister. The
flow controllers were set by the laboratory to allow for collection of the samples over a 24-hour
period for a residential use scenario. A sampling stand was utilized so that the sample intake point
was positioned approximately 5 feet above grade (typical breathing zone height) when the sample
canister was set on its base. One duplicate indoor air sample (IAS-DUP) was collected for quality
assurance/quality control (QA/QC) purposes from the IAS-4 parent location during the January
2024 sampling event. The duplicate sample was collected utilizing a laboratory supplied stainless-
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steel sampling “T” fitting which allows for the simultaneous collection of two indoor air samples
from a single location.

During the sampling activities, indoor/outdoor air pressure differential was measured for the
building near the start, middle, and end of the 24-hour sampling period using a manometer
sensitive to 0.001 inches of water. In addition, site-specific weather conditions including exterior
wind speed, exterior wind direction, indoor/outdoor temperature, barometric pressure, and
precipitation were recorded near the start, middle, and end of the sampling period. The differential
pressure measurements indicated the same pressure in the indoor air as the ambient air, which is
expected without the HVAC system operational. Indoor air sampling field forms completed by
sampling personnel are included in Appendix E.

Prior to and after the indoor and background air samples were collected, vacuum in the canisters
was measured using a laboratory-supplied vacuum gauge and recorded by sampling personnel.
The starting vacuum was within approximately 10% of the vacuum when the Summa canisters left
the laboratory. Final sample canister vacuum readings as measured in the field ranged from
approximately 3.5 to 10 inches of mercury (inHg). The starting and ending vacuums in each
canister were recorded by sampling personnel on the sample chain of custody. The sample
canisters were then labeled, packaged in a laboratory provided container, and shipped under
standard chain of custody protocols to a qualified laboratory for analysis of a select list of VOCs
by EPA Method TO-15. The target analyte list included VOCs detected in the sub-slab vapor
samples and select chlorinated compounds. A list of the select VOCs analyzed is included in the
laboratory analytical report provided in Appendix F.

3.3 Building Survey Activities

Prior to collecting indoor air samples, H&H completed a survey within the building to identify
potential sources of VOCs of concern from building materials or construction activities. Results
of the survey activities completed during the January 2024 indoor air sampling event identified
ongoing construction activities at the Site and the use of several construction materials containing
compounds that were part of the VOC analyte list for the Site. No VOC-containing products were
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observed in the areas where indoor air samples were collected. However, the parking garage was
utilized as a storage area for gasoline stored in small quantities for refueling on-Site construction
equipment. The indoor air building survey form completed by H&H sampling personnel during
the indoor air sampling event is included in Appendix E.

H&H also reviewed the Safety Data Sheets (SDSs) for building materials provided by the
construction contractors. A tabular summary of the compounds identified in materials used for
construction is provided as Table H-1 in Appendix H, and copies of the SDSs provided by the
general contractor are also provided in Appendix H. Note the tabular summary may not include
all compounds that may off gas from building materials because many standard building materials,
like wood and drywall may not have specific SDSs, or if the specific product information was not
provided by the general contractor.

3.4 Sub-Slab Soil Vapor Sampling Results
The January 2024 sub-slab soil vapor sample analytical results are summarized in Table 1. The
results were compared to the DEQ Residential Vapor Intrusion Sub-Slab and Exterior Soil Gas
Screening Levels (SGSLs) dated February 2024. Copies of the laboratory analytical report and
the chain of custody record are provided as Appendix F.

Laboratory analytical results indicate that the VOC tetrahydrofuran was detected at a concentration
of 30,000 micrograms per cubic meter (µg/m3) in sample MP-8, which is above the DEQ
Residential SGSL of 14,000 µg/m3. No other compounds were detected at concentrations above
DEQ Residential SGSLs in the January 2024 sub-slab vapor samples collected from the Western
Section of the building. The chlorinated VOCs PCE and trichloroethene (TCE) were not detected
above laboratory method detection limits (MDLs) in the sub-slab vapor samples.

Note that acetone and methyl ethyl ketone (MEK) were detected at concentrations orders of
magnitude higher than other compounds in sub-sab vapor samples MP-6 and MP-8. As a result of
these concentrations, the laboratory MDLs for several other compounds in samples MP-6 and MP-
8 were above the DEQ Residential SGSLs. While the laboratory MDLs for samples MP-6 and
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MP-8 were elevated, the laboratory MDLs for the remaining sub-slab vapor samples, MP-3 and
MP-9, were notably lower with most of the laboratory MDLs reported below the DEQ Residential
SGSLs.

The relatively high concentrations of acetone, MEK, and tetrahydrofuran are attributable to off-
gassing of VOCs from construction materials. Acetone and MEK (also known as 2-butanone) are
two of the main components in PVC primer, and tetrahydrofuran is one of the main components
in PVC glue. PVC primer and glue are common construction materials used throughout
construction of the building including on most sub-slab plumbing utilities. Samples MP-6 and
MP-8 were collected from areas with multiple residential units, and therefore these areas contain
a higher density of sub-slab PVC utilities where PVC glue and primer were used during
construction. Sub-slab vapor sample MP-3, where the concentrations of acetone, MEK, and
tetrahydrofuran where notably lower than the other samples, was collected from a residential
storage area where fewer sub-slab utilities are located. Therefore, the concentrations of acetone,
MEK, and tetrahydrofuran in the sub-slab vapor samples are attributed to VOC off-gassing from
the PVC primer and glue used on sub-surface utilities, and these concentrations are expected to
decrease over time. Copies of the SDSs for PVC glue and primer used during construction are
included in Appendix H.

3.5 Indoor Air Sampling Results
The indoor air sample analytical results are summarized in Table 2. The results were compared to
the DEQ Residential Vapor Intrusion Indoor Air Screening Levels (IASLs) dated February 2024.
Indoor air samples are a direct measurement of indoor air quality, and the data can be used to
determine direct risk levels to future occupants of the building. Copies of the laboratory analytical
report and the chain of custody record are provided as Appendix F.

The indoor air sample analytical results indicate that several compounds were detected at
concentrations above laboratory MDLs in each sample. The compounds benzene (up to 0.89
µg/m3), chloroform (up to 0.14 J µg/m3), ethylbenzene (up to 5.1 µg/m3), and naphthalene (up to
0.25 µg/m3) were detected at concentrations above the DEQ Residential IASLs in select samples.
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The compound TCE was detected in one sample, IAS-5, at a concentration of 0.33 µg/m3 which is
below the DEQ Residential IASL of 0.42 µg/m3, and below the DEQ Residential TCE Immediate
Action Level of 2.1 µg/m3.

The background ambient air sample IAS-BKG was collected upwind of the multi-family
residential building to evaluate ambient air conditions. Several compounds were detected in the
background sample at concentrations exceeding the laboratory MDLs, and benzene was detected
at concentrations exceeding the IASL. The detected concentrations of benzene and chloroform in
the outdoor, background air sample are similar to the concentrations detected in the indoor air
samples.

Although the low-level detection of TCE was below the DEQ Residential IASL and TCE was not
detected in sub-slab vapor samples, H&H conducted an investigation to identify potential vapor
intrusion pathways in the area of the IAS-5 sample location. H&H completed limited smoke (i.e.
fog) testing by blowing inert fog into monitoring point MP-9 to assess for potential leaks through
the slab. No leaks were identified in the slab in the area of the IAS-5 location or in the adjacent
residential units and nearby electric room. During the investigation, H&H identified multiple
sanitary sewer plumbing connections that were not filled with water, including toilets and shower
drains. Plumbing drains contain a P-trap that is designed to reduce the potential for vapors from
within the plumbing pipes to enter the interior of the building when they are filled with water
during normal use. However, before the plumbing pipes are filled with water, the pipes could
potentially be a pathway for sewer gases to enter the building. Therefore, the plumbing pipes may
have acted as a potential vapor intrusion pathway into the units during construction, but the P-traps
pipes are expected to continuously contain water during building occupancy which would
generally prevent vapor migration from the sewer pipes into the building. In addition, significant
vapor were not detected in the indoor air samples as described further below.

As indicated above, one duplicate indoor air sample (IAS-DUP) was collected for quality
assurance/quality control (QA/QC) purposes from the IAS-4 parent location during the January
2024 sampling event. Review of the duplicate sample results for the indoor air sample did not
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indicate significant variability compared with the results of the parent sample and confirm
adequate sampling and laboratory reproducibility.

3.6 Vapor Intrusion Evaluation
The DEQ Vapor Intrusion Screening Levels are conservative and based on a target carcinogenic
risk (TCR) of 1 x 10-6 and a hazard quotient (HQ) of 0.2 for potential non-carcinogenic risks. The
DEQ and EPA typically acceptable risk level for potential carcinogenic risks is a cumulative
lifetime incremental cancer risk (LICR) of 1 x 10-4 or less, and the acceptable level for non-
carcinogenic risks is a cumulative hazard index (HI) of 1.0 or less. The HI is the sum of hazard
quotients (HQs) for each target analyte. When sub-slab results are coupled with indoor air data
such as for this monitoring event, the indoor air results are relied upon because they are direct
concentration measurements.

To evaluate sub-slab soil vapor and indoor air concentrations, H&H utilized the most-recent
version of the DEQ Risk Calculator at the time of sampling (February 2024) to calculate sub-slab
vapor and indoor air risks for each individual sample collected. The calculated cumulative LICR
and HI values are provided in Tables 1 and 2 and are summarized in the table below.

Sample
ID
Land Use
Scenario
Calculated Cumulative LICR
Calculated Cumulative HI
LICR Exceeds
Acceptable
HI Exceeds
Acceptable
MP-3 Residential 1.1 x 10-6
7.5 x 10-6 0.31
0.0 0.20
6.4 x 10-6 0.29
0.0 0.50
Residential 1.1 x 10-5 0.46 No No
0.0 0.048
7.4 x 10-5 0.51

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The calculated cumulative residential use LICRs and HIs are within the DEQ and EPA acceptable
levels for each sub-slab vapor and indoor air sample. Note, for samples MP-6 and MP-8, the LICR
was 0.0 which indicates no compounds with a carcinogenic risk were detected in these samples.
Based on the analytical sampling and risk calculations, data do not indicate there is unacceptable
risk from vapor intrusion to future residential occupants of the building. Further, the
concentrations of acetone, MEK, and tetrahydrofuran detected in the sub-slab vapor samples are
expected to decrease overtime as the VOCs continue to off-gas and sub-slab vapors are discharged
through the VIMS vent piping.

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4.0 Summary and Conclusions

Installation of the VIMS has been completed at the Western Section of the Hawkins Press
Apartments at the Crayton Printing Brownfields property (Brownfields Project No. 24025-20-
060). Results of installation inspections, influence testing, and effectiveness sampling activities
indicate that the VIMS has been installed in accordance with the DEQ-approved VIMP for the
Western Section of the building. The VIMS for the Eastern Section of the building was completed
in 2023 and is documented in a separate report.

During construction of the building, H&H conducted VIMS installation inspections to verify that
the VIMS was installed as designed and completed pre-occupancy VIMS testing activities to
evaluate effectiveness of the VIMS. The VIMS installation inspections and post-installation
testing activities were completed in general accordance with the DEQ-approved VIMP. A brief
summary of the VIMS installation and pre-occupancy effectiveness assessment activities is
provided below.

VIMS Installation and Influence Testing
VIMS installation has been completed for the Western Section of the building that consists of
residential apartment units and associated amenity spaces. The VIMS operates as a passive sub-
slab venting system with vertical extraction piping to the roof connected to wind-driven ventilators
that enhance air exhaust from the risers. During installation of the VIMS, H&H personnel, under
direction of a North Carolina licensed Professional Engineer, conducted inspections during each
stage of installation. Results of the installation inspections indicate that the VIMS was installed
in accordance with the DEQ-approved VIMP.

H&H completed vacuum influence pilot testing following installation of the VIMS piping network
to evaluate vacuum communication beneath the slab. Final vacuum measurements collected
during the influence testing activities indicate that vacuum communication beneath the slab was
achieved with acceptable differential pressure levels. In addition, the crane leave-out area in the
Eastern Section of the building was completed, and influence testing in that area demonstrated
acceptable sub-slab communication below the finished slab.
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VIMS Effectiveness Testing – Sub-Slab Vapor
Laboratory analytical results identified several VOCs at concentrations above the laboratory
MDLs in the sub-slab vapor samples. Tetrahydrofuran was detected at a concentration above the
DEQ Residential SGSL in one sub-slab vapor sample, MP-8. No other compounds were detected
at concentrations above DEQ Residential SGSLs in the sub-slab vapor samples including the
chlorinated VOCs TCE and PCE. The sub-slab vapor samples risk calculations indicated
acceptable DEQ and EPA risk levels under a residential use scenario.

Note, select sub-slab vapor samples exhibited laboratory MDLs that were greater than DEQ
Residential SGSLs due to detections of compounds related to construction material off-gassing,
specifically VOC off-gassing from PVC glue and primer. The detected concentrations are
expected to decrease overtime as the construction materials continue to off-gas and the sub-slab
vapors discharge through the VIMS piping. In addition, significant vapors were not detected in
the indoor air samples.

VIMS Effectiveness Testing - Indoor Air
The indoor air sample analytical results indicate that the compounds benzene, chloroform,
ethylbenzene, and naphthalene were detected at concentrations above the DEQ Residential IASLs
in one or more samples. With the exception of naphthalene, these same compounds were detected
in the background air sample at similar concentrations. No other compounds were detected at
concentrations above the DEQ Residential IASLs. TCE was detected in one sample at a
concentration above the laboratory reporting limit, but below the DEQ Residential IASL. The
source of the TCE and certain other VOC concentrations in the indoor air samples could have been
sewer P-traps that were left unfilled by the contractor. Regardless, the indoor air sample risk
calculations indicated acceptable DEQ and EPA risk levels under a residential use scenario.

Summary
Based on the VIMS installation inspections, influence testing, and pre-occupancy sub-slab vapor
and indoor air sampling results, the VIMS in the Western Section of the Site building and in the
crane leave out area in the Eastern Section of the Site building were installed in accordance with
the DEQ-approved VIMP, and the indoor air data risk calculations are within acceptable risk levels
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under a residential use scenario. As such, the data indicate that there are no unacceptable risk
levels from potential vapor intrusion to the future occupants of the building. This report is intended
to satisfy the Brownfields Agreement LUR 12(h) regarding vapor intrusion for the areas of the
building described herein.

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5.0 Recommendation to Change Post-Occupancy Sampling Frequency

The Post-Construction VIMS Sampling Work Plan indicates that sub-slab vapor and indoor air
sampling will be conducted on a quarterly basis at select locations for the first year after occupancy
of the building. Based upon the acceptable sub-slab vapor intrusion risk levels for the sub-slab
vapor and indoor air samples, H&H proposes to conduct post-occupancy sampling on a semi-
annual (twice per year) frequency following occupancy of the building at the sample locations
sampled during the January 2024 sampling event. The semi-annual post-occupancy sampling
frequency aligns with current DEQ Brownfields Redevelopment Section guidelines for Sites that
contain residential units and with potential low levels of TCE present. If the semi-annual post-
occupancy sampling data indicate stable or decreasing concentrations, then a request to reduce or
terminate the sampling will be submitted for DEQ review and approval. No changes to the
sampling amounts or frequency will occur without DEQ written approval.

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6.0 Engineer’s Certification

According to the DWM Vapor Intrusion Guidance: “Risk-based screening is used to identify sites
or buildings likely to pose a health concern, to identify buildings that may warrant immediate
action, to help focus site-specific investigation activities or to provide support for building
mitigation and other risk management options including remediation.” The design and installation
of the vapor intrusion mitigation system was conducted to satisfy the vapor intrusion mitigation
condition in the Brownfields Agreement. Per the North Carolina Brownfields Property Reuse Act
130A-310.32, a prospective developer, with the assistance of H&H for this project, is to provide
NCDEQ with “information necessary to demonstrate that ... as a result of the implementation of
the brownfields agreement, the brownfields property will be suitable for the uses specified in the
agreement while fully protecting public health and the environment instead of being remediated to
unrestricted use standards.” It is in the context of these risk-based concepts that H&H’s
professional engineer makes the following statement.

The Vapor Intrusion Mitigation System (VIMS) detailed herein is designed to mitigate intrusion
of subsurface vapors into the subject building from known Brownfields Property contaminants in
a manner that is in accordance with the most recent and applicable guidelines including, but not
limited to, DWM Vapor Intrusion Guidance, Interstate Technology & Regulatory Council (ITRC)
guidance, and American National Standards Institute (ANSI)/American Association of Radon
Scientists and Technologists (AARST) standards. The sealing professional engineer below is
satisfied that the design and its installation are fully protective of public health from known
Brownfields Property contaminants.

[SEAL]

Trinh DeSa NC PE #044470 Hart & Hickman, PC (#C-1269)
Table 1
Summary of Sub-Slab Soil Vapor Analytical Results
Crayton Printing Brownfields Site
Distribution Street and Dunavant Street
Brownfields Project No. 24025-20-060
Charlotte, North Carolina
H&H Project No. AKR.005
Sample Location Screening Criteria
Sample ID MP-3 MP-6 MP-8 MP-9
Date Collected
OCs (TO-15) (µg/m3)
Acetone 28 11,000 14,000 2,500 NE
Benzene 0.27 J <15 <30 <1.5 12
1,3-Butadiene 2.9 <28 <56 <2.8 3.1
Carbon Tetrachloride 0.55 J <27 <54 <2.7 16
Chloroform 0.27 J <19 <38 <1.9 4.1
Chloromethane 0.68 J <13 28 J <1.3 630
Cyclohexane <0.30 <23 <46 <2.3 42,000
Dichlorodifluoromethane (Freon 12)2.7 <31 80 J 3.6 J 700
trans-1,2-Dichloroethylene <0.26 <19 <39 <1.9 280
Ethanol 12 J <750 <1,500 <75 NE
Ethyl Acetate <2.1 <160 <310 <16 490
Ethylbenzene 0.38 J <19 <38 <1.9 37
Heptane <0.52 <39 <78 <3.9 2,800
Hexane <9.3 <700 <1,400 <70 4,900
2-Hexanone (MBK)<0.35 <27 <53 <2.7 210
Isopropanol 26 <470 <940 <47 1,400
Methyl Ethyl Ketone (MEK)27 2,800 6,100 690 35,000
Methyl tert-Butyl Ether (MTBE)<0.35 <27 <53 <2.7 360
Naphthalene <0.70 <53 <110 <5.3 2.8
Styrene <0.46 <34 <68 <3.4 7,000
Tetrachloroethylene <0.51 <38 <76 <3.8 280
Tetrahydrofuran 23 13,000 30,000 3,000 14,000
Toluene 1.0 <21 <41 <2.1 35,000
Trichloroethylene <0.44 <33 <66 <3.3 14
Trichlorofluoromethane (Freon 11)1.5 J <35 <69 <3.5 NE
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)<0.34 <25 <51 <2.5 35,000
1,2,4-Trimethylbenzene 0.98 <34 <68 <3.4 420
Vinyl Acetate <2.5 <190 <380 <19 1,400
m&p-Xylene 1.0 J <46 <91 <4.6 700
o-Xylene 0.59 J <24 <48 <2.4 700
DEQ Cumulative Risk Calculator (2)Acceptable Risk Levels
Residential LICR 1.1 x 10-6 0.0 0.0 0.0 ≤1.0 x 10-4
Residential Non-Carcinogenic HI 0.048 0.20 0.50 0.048 ≤1.0
Notes:
1) North Carolina Department of Environment Quality (DEQ) Vapor Intrusion Sub-Slab & Exterior Soil Gas Screening Levels (SGSLs) dated February 2024 are based on TCR = 1 x 10-6 and THQ = 0.2.
2) DEQ Cumulative Risk Calculator dated February 2024.
Only constituents detected in at least one sample and select compounds are shown in the table above. Refer to laboratory analytical report for all compounds.
Compound concentrations and SGSLs are reported in micro rams per cubic meter µ/m3 .
Compound concentrations are reported to the laboratory method detection limits.
Bold values exceed the Residential SGSL.
VOCs = volatile organic compounds; NE = not established; LICR = lifetime incremental cancer risk; HI = hazard index; TCR = target cancer risk; THQ = target hazard quotient
J = Estimated value between the laboratory method detection limit and the laboratory reporting limit.
Residential
SGSLs (1)
Western Section
1/7/2024
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Table 1 (Page 1 of 1)
Hart & Hickman, PC
Table 2
Summary of Indoor Air Analytical Results
Crayton Printing Brownfields Site
Distribution Street and Dunavant Street
Brownfields Project No. 24025-20-060
Charlotte, North Carolina
H&H Project No. AKR.005
Sample Location Screening Criteria
Sample ID IAS-2 IAS-3 IAS-5 IAS-BKG
Date Collected
OCs TO-15 µ/m3
Acetone 23 43 55 47 69 14 NE
Benzene 0.68 0.61 0.63 0.63 0.89 0.88 0.36
1,3-Butadiene <0.065 <0.065 <0.064 <0.064 <0.065 <0.065 0.094
Carbon Tetrachloride 0.17 J 0.43 0.066 J 0.47 0.16 J 0.33 0.47
Chloroform 0.085 J 0.11 J 0.12 J 0.11 J 0.14 J 0.092 J 0.12
Chloromethane 1.2 1.2 1.1 1.2 1.2 1.1 19
Cyclohexane 0.11 J 0.75 0.66 0.64 0.52 0.21 1,300
Dichlorodifluoromethane (Freon 12)3.1 2.7 3.4 4.1 2.9 2.9 21
trans-1,2-Dichloroethylene <0.045 <0.045 <0.045 <0.045 0.069 J <0.045 8.3
Ethanol 53 82 E 35 37 290 E 10 NE
Ethyl Acetate 2.0 4.9 <0.36 <0.36 4.2 <0.36 15
Ethylbenzene 1.7 0.67 5.0 5.1 1.2 0.43 1.1
Heptane 0.37 0.58 0.47 0.49 0.96 0.39 83
Hexane <1.6 <1.6 <1.6 <1.6 2.3 J 1.8 J 150
2-Hexanone (MBK)0.27 0.18 0.36 <0.062 0.58 0.26 6.3
Isopropanol 6.1 5.0 3.4 J 3.2 J 9.9 1.6 J 42
Methyl Ethyl Ketone (MEK)4.6 3.2 J 5.8 5.0 5.5 1.3 J 1,000
Methyl tert-Butyl Ether (MTBE)0.11 J <0.062 <0.062 0.078 J 0.17 <0.062 11
Naphthalene 0.25 B,L-05,V-06 0.19 B,L-05,V-06 0.19 B,L-05,V-06 0.16 B,J,L-05,V-06 0.14 B,J,L-05,V-06 <0.12 0.083
Styrene 0.82 0.64 1.0 1.1 1.0 0.14 J 210
Tetrachloroethylene <0.089 <0.089 <0.088 <0.088 0.15 J <0.089 8.3
Tetrahydrofuran 2.5 L-03 20 L-03 34 L-03 34 L-03 31 L-03 0.75 J,L-03 420
Toluene 2.3 5.9 3.3 3.3 11 2.9 1,000
Trichloroethylene <0.076 <0.076 <0.076 <0.076 0.33 <0.076 0.42
Trichlorofluoromethane (Freon 11)1.5 1.5 1.4 1.5 1.4 1.4 NE
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 0.58 J 0.64 J 0.67 J 0.82 J 0.63 J 0.58 J 1,000
1,2,4-Trimethylbenzene 0.61 0.77 1.6 1.6 1.5 0.42 13
Vinyl Acetate 1.3 J,L-05,V-06 1.8 J,L-05,V-06 2.1 J,L-05,V-06 1.7 J,L-05,V-06 0.89 J,L-05,V-06 1.8 J,L-05,V-06 42
m&p-Xylene 6.1 2.2 18 19 4.1 1.3 21
o-Xylene 2.3 0.98 5.2 5.3 1.5 0.50 21
DEQ Cumulative Risk Calculator (2)Acceptable Risk Levels
Residential LICR 7.5 x 10-6 6.4 x 10-6 7.4 x 10-6 --≤1.0 x 10-4
Residential Non-Carcinogenic HI 0.31 0.29 0.51 --≤1.0
Notes:
1) North Carolina Department of Environment Quality (DEQ) Vapor Intrusion Indoor Air Screening Levels (IASLs) dated February 2024 and based on TCR = 1 x 10- and THQ = 0.2.
2) DEQ Cumulative Risk Calculator dated February 2024.
Only constituents detected in at least one sample and select compounds are shown in the table above. Refer to laboratory analytical report for all compounds.
Compound concentrations and SGSLs are reported in micrograms per cubic meter (µg/m ); Compound concentrations are reported to the laboratory method detection limits.
Bold values exceed the Residential IASL.
VOCs = volatile organic compounds; NE = not established; LICR = lifetime incremental cancer risk; HI = hazard index; TCR = target cancer risk; THQ = target hazard quotient; -- = not applicable
B = analyte detected in laboratory blank; E = estimated value over verified calibration range.
J = estimated value between the laboratory method detection limit and the laboratory reporting limit.
L-03 = laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this compound is likely to be biased on the low side.
L-05 = laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this compound is likely to be biased on the high side.
V-06 = continuing calibration verification did not meet method specifications and was biased on the high side for this compound.
Residential
IASLs (1)1/6/2024 - 1/7/2024
Western Section
0.46
1.1 x 10-5
IAS-4 / IAS-DUP
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Table 2 (Page 1 of 1)
Hart & Hickman, PC
USGS The National Map: National Boundaries Dataset, 3DEP ElevationProgram, Geographic Names Information System, National HydrographyDataset, National Land Cover Database, National Structures Dataset,and National Transportation Dataset; USGS Global Ecosystems; U.S.
Census Bureau TIGER/Line data; USFS Road Data; Natural Earth Data;U.S. Department of State Humanitarian Information Unit; and NOAANational Centers for Environmental Information, U.S. Coastal ReliefModel. Data refreshed February, 2020.
SITE LOCATION MAP
CRAYTON PRINTINGDISTRIBUTION STREET AND DUNAVANT STREET CHARLOTTE, NORTH CAROLINA
REVISION NO: 0
FIGURE NO: 1
2923 South Tryon Street - Suite 100Charlotte, North Carolina 28203704-586-0007 (p) 704-586-0373 (f)License # C-1269 / # C-245 Geology
0 2,000 4,000
SCALE IN FEET
SITE
N
U.S.G.S. QUADRANGLE MAP
CHARLOTTE EAST, NORTH CAROLINA 2013
QUADRANGLE7.5 MINUTE SERIES (TOPOGRAPHIC)
DATE: 10-2-2023
JOB NO. AKR-005
REVISION NO. 0
JOB NO. AKR-005
DATE: 10-2-2023
FIGURE NO. 2
CRAYTON PRINTING
DISTRIBUTION STREET AND DUNAVANT STREET
CHARLOTTE, NORTH CAROLINA
SITE MAP
LEGEND
BROWNFIELDS PROPERTY BOUNDARY
PARCEL BOUNDARY
EASTERN BUILDING SECTION
WESTERN BUILDING SECTION
2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 Geology
HUB SOUTH END APARTMENTS
(2250 HAWKINS STREET)
JUNCTION 1504
LUXURY APARTMENTS
(1504 MAINLINE BOULEVARD)
THE DUNAVANT RESTAURANT /
VACANT COMMERCIAL UNIT
(2322 DUNAVANT STREET)
MULTI-TENANT COMMERCIAL BUILDING
(2401 DISTRIBUTION STREET)
MULTI-TENANT
COMMERCIAL BUILDING
(2326 DISTRIBUTION STREET)
DIS
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LEGEND
1. PARCEL DATA OBTAINED FROM MECKLENBURG COUNTY
GIS (2023). AERIAL IMAGERY OBTAINED FROM
MECKLENBURG COUNTY GIS (2022).
2. DEVELOPMENT PLANS PROVIDED BY BB+M, DATED
8-3-2020.
SELLES-BAGWELL
BROWNFIELDS SITE
(BPN 24008-20-060)
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MECH.
DOG WASH
TRASH ROOM
ELEV. 712'
ELEV. 720'
ELEV. 719'-6"
ELEV. 718'
ELEV. 727'
ELEC.
ELEV. 717'
LOADING
ZONE
ELEV. 732'
ELEV. 722'
MAINTENANCE
TRASH STAGING AREA
BIKE STORAGE
ELEC.
ELEV LOBBY
ELEV. 717'-6"
ELEV. 730'
ELEV. 727'
ELEV. 729'
MECH. VENT
MAIL
CENTER
720' - 3"
LEVEL 1 TRASH
MECH.
LEASING/ LOUNGE
SERVICE
ELEV. 1 ELEV. 2
STAIR E
PACKAGE
STAIR B
ELEV. 3 ELEV. 4
CORRIDOR
722' - 3"
720' - 3"
LEASING/ LOUNGE
STAIR A
LYFT
WAITING
AREA
OUTDOOR
AMENITY
713' - 0 3/8"
720' - 3"
POOL ROOM
CHEM.
720' - 3"
4
13 10
LANAIS ABOVE
PARKING RAMP: 1
6.30%
719' - 9"
719' - 9"
719' - 9"
720' - 3"714' - 6 3/4"
717' - 4"
1"

/

1
2
"
1" / 12"
1"

/

1
2
"
714' - 6"
714' - 6"
714' - 6"
720' - 3"
714' - 6"
717' - 9"
719' - 9"
MECH
4'x8'
4'x8'
4'x8'
6.30%
6.30%
LARGESCALE
WASH
719' - 9"
717' - 4"4'x8'4'x8'
1/
4
"

/

1
2
"
719' - 9"
717' - 9"
STAIR C
2.75%
2.
1
0
%
0.6
2
%
0.
7
3
%
5.
2
2
%
720' - 3"
721' - 3"
720' - 3"
720' - 3"
9
5
8
6
717' - 8"
720' - 3"
721' - 3"
SL
O
P
E
DO
W
N
HS
S
8
X
4
X
1
/
4
HS
S
8
X
4
X
1
/
4
SW-#1
SW-#2
SW
-
#
4
SW-#5
SW-#6
SW-#7
SW-#8
SW
-
#
9
SW
-
#
1
0
SL
O
P
E
DO
W
N
SL
O
P
E
UP
SL
O
P
E
UP
SL
O
P
E
UP
F-1
F-2
F-3
F-4
F-5
F-6
F-8
MP-12
F-7
IAS-2
IAS-3
IAS-4
IAS-5
IAS-BKG
MP-3
MP-4
MP-6
MP-9
MP-10
MP-11
MP-14
MP-5
MP-1
MP-7
MP-8
JOB NO. AKR-005
INDOOR AIR AND
SUB-SLAB VAPOR
SAMPLE LOCATION
MAP - LEVEL 1
WESTERN
SECTION
MARCH 25, 2023
FIGURE NO. 3A
VAPOR MITIGATION PLAN PREPARED BY:
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
ISSUED FOR CONSTRUCTION
CR
A
Y
T
O
N

P
R
I
N
T
I
N
G
DI
S
T
R
I
B
U
T
I
O
N

S
T
R
E
E
T

A
N
D

D
U
N
A
V
A
N
T

S
T
R
E
E
T
CH
A
R
L
O
T
T
E
,

N
O
R
T
H

C
A
R
L
I
N
A
BR
O
W
N
F
I
E
L
D
S

P
R
O
J
E
C
T

N
O
.

2
4
0
2
5
-
2
0
-
0
6
0
LEGEND
SLAB GRADE CHANGE
OUTDOOR OR OPEN AIR
LEVEL 2 SLAB ON GRADE AREA
MONITORING POINT LOCATION
SUB-SLAB VAPOR SAMPLE LOCATION
WESTERN SECTION OF BUILDING
INDOOR AIR SAMPLE LOCATION
BACKGROUND/AMBIENT AIR SAMPLE LOCATION
MP-4
GROUNDLEVEL PORTION OF
LEVEL 2 (SEE FIGURE 3B)
LEASING OFFICE
AND LOUNGE
STAIRWELL C
APARTMENTS
MECHANICAL AND
SUPPORT ROOMS
PACKAGE STORAGE ROOM
PARKING
GARAGE
APARTMENTS
ELEVATORS 1 & 2
STAIRWELL A
ELEVATORS 3 & 4
STAIRWELL B
STAIRWELL E
MP-2
NOTES:
1.INDOOR AIR SAMPLES AND SUB-SLAB VAPOR
SAMPLES FOR THE WESTERN SECTION WERE
COLLECTED ON JANUARY 6 & 7, 2024.
2.REFER TO VIMS INSTALLATION COMPLETION
REPORT - EASTERN SECTION DATED OCTOBER 16,
2023, FOR LOCATIONS OF SAMPLES COLLECTED IN
THE EASTERN SECTION OF THE BUILDING.
S:\
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Appendix A
Historical Data Summary Tables and Sample Location Maps

Table 4
Summary of Sub-Slab Vapor and Soil Gas Analytical Data
Crayton Printing
Charlotte, North Carolina
H&H Job No. AKR-005
Evaluation Area
Sample ID SS-1 SS-2 SS-3 SS-4 SS-5 SS-6 SS-7 SG-1 SG-2 SG-3 SG-5
Sample Date
Sample Type
Units
VOCs (TO-15)
Acetone 24 55 29 76 180 42 28 <11 <11 21 <11 <11 29 220,000
Benzene <0.19 0.49 J 0.43 J 0.83 <0.19 0.43 J <0.19 13 26 17 32 31 0.66 12
2-Butanone (MEK)3.9 J 8.2 J 4.6 J 11 J 12 J 6.1 J 5.3 J 3.9 J 15 J 3.0 J 3.5 J 4.9 J 4.4 J 35,000
Carbon Disulfide <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 220 550 110 470 480 <1.6 4,900
Carbon Tetrachloride <0.33 <0.33 0.40 J <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 0.83 J <0.33 16
Chloroform <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 2.3 <0.24 1.6 <0.24 <0.24 <0.24 4.1
Chloromethane <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 0.92 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 630
Cyclohexane <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 13 <0.34 42,000
Dichlorodifluoromethane (Freon 12) <0.31 <0.31 19 <0.31 <0.31 <0.31 1200 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 700
1,1-Dichloroethane <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 7.1 7.2 <0.25 58
Ethanol 110 330 170 510 90 140 47 26 15 J 15 <4.6 <4.6 <4.6 NE
Ethylbenzene 2.3 1.1 0.56 J 2.2 1.6 0.76 J <0.18 150 170 230 210 200 16 37
4-Ethyltoluene <0.30 <0.30 <0.30 1.9 <0.30 <0.30 <0.30 62 56 100 120 110 4.9 NE
Heptane <0.35 <0.35 <0.35 <0.35 <0.35 <0.35 <0.35 6.8 100 4.8 <0.35 14 <0.35 2,800
Hexane <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 200 <1.3 51 51 <1.3 4,900
Isopropanol 5.5 J 16 J 5.0 J 20 J 20 <4.5 <4.5 <4.5 <4.5 <4.5 <4.5 <4.5 <4.5 1,400
Methyl tert-butyl ether <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 2.2 <0.29 <0.29 <0.29 360
Methylene Chloride 1.6 J <1.6 2.6 J <1.6 <1.6 3.9 J <1.6 2.0 J <1.6 <1.6 <1.6 <1.6 <1.6 3,400
Naphthalene 2.6 <0.59 15 2.4 1.8 <0.59 <0.59 <0.59 <0.59 <0.59 <0.59 <0.59 <0.59 2.8
Propene <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 95 760 4.6 J 88 87 <1.2 21,000
Styrene <0.24 <0.24 <0.24 0.75 J <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 7,000
Tetrachloroethylene <0.44 1100 2.5 <0.44 1.3 J 15 3.0 17 12 18 31 30 2.3 280
Toluene 9.4 4.5 2.9 9.4 9.5 3.7 1.9 520 690 700 650 620 24 35,000
1,1,1-Trichloroethane 0.55 J <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 35,000
Trichloroethylene <0.40 9.2 <0.40 <0.40 <0.40 <0.40 <0.40 5.2 <0.40 <0.40 <0.40 <0.40 <0.40 14
Trichlorofluoromethane (Freon 11)20 1.4 J 1.4 J 1.2 J 1.2 J 2.0 J 1.3 J 2.7 J 1.7 J 1.0 J 1.2 J <0.85 <0.85 NE
1,2,4-Trimethylbenzene 9.0 <0.22 <0.22 9.4 7.5 2.7 <0.22 150 130 240 240 230 20 420
1,3,5-Trimethylbenzene 1.5 0.77 J <0.26 1.6 1.3 0.43 J <0.26 39 34 65 73 69 4.2 420
m&p-Xylene 11 4.8 2.4 10 7.3 3.3 <0.30 550 580 830 700 680 64 700
o-Xylene 4.2 1.9 0.90 3.9 2.9 1.3 <0.23 190 190 280 240 220 26 700
Notes:
1) North Carolinia Department of Environmental Quality (DEQ) Division of Waste Management (DWM) Residential Vapor Intrusion Soil Gas Screening Levels (SGSLs) dated July 2020
Concentrations are reported in micrograms per cubic meter (µg/m ).
Compound concentrations are reported to the laboratory method detection limits.
Laboratory analytical methods are shown in parentheses.
Only compounds detected in at least one sample are shown in the above table.
VOCs = volatile organic compounds; NE = Not Established
J = Compound was detected above the laboratory method detction limit, but below the laboratory reporting limit resulting a laboratory estimated concentration.
Residential
SGSLs (1)
µg/m3
Proposed Parking Garage Proposed Apartment Building
Exterior Soil Gas
SG-4 / SG-DUP
9/14/2020
Sub-Slab
9/10/2020
S:\AAA‐Master Projects\Akridge\AKR.005 Dunavant Brownfileds Assessment\Report\Tables\Data Tables.xlsx
10/1/2020
Table 4 (Page 1 of 1)
Hart & Hickman, PC
#
#
#
#
#
"¬
"¬
"D
"D
"D
"GÑ
"GÑ
"GÑ
!
!
!!Ñ!!
#
"¬#
SS-1
SS-2
SS-3
SS-4
SS-5
SG-2
SG-4
SG-1/SB-2
SG-5/SB-5
SG-5/SB-7
TMW-1/SB-1
TMW-3/SB-6
TMW-4/SB-8
SB-3
SB-4
SB-9 SB-10 TMW-2
SS-7
SG-3
SS-6
726
710
726
730
724
722
728
712
726
724
722
714
718
716
720
SAMPLE LOCATION MAP
CRAYTON PRINTINGDISTRIBUTION STREET AND DUNAVANT STREETCHARLOTTE, NORTH CAROLINA
REVISION NO: 0
FIGURE NO: 4
2923 South Tryon Street - Suite 100Charlotte, North Carolina 28203704-586-0007 (p) 704-586-0373 (f)License # C-1269 / # C-245 Geology
0 50 100
SCALE IN FEET
N
DATE: 9-28-20
JOB NO. AKR-005
DUNAVANT STREET
DISTRIBUTION STREET
NOTE:
1. BASE DATA OBTAINED FROM MECKLENBURG COUNTY GIS, 2020.
2. ELEVATION DATA OBTAINED FROM MECKLENBURG COUNTY LIDAR, 2013.
Path: \\HHFS01\Redirectedfolders\sperry\My Documents\ArcGIS\PROJECTS\AKR-005\FIGURE 4 - Sample Location Map.mxd
HAWKINS STREET
PROPOSEDCOURTYARD
PROPOSEDPARKING DECK
LEGEND
BROWNFIELDS PROPERTY BOUNDARY
PARCEL BOUNDARY LINE
ELEVATION CONTOUR
!SOIL BORING
"¬SOIL GAS SAMPLE
"D CO-LOCATED SOIL GAS SAMPLE AND SOILBORING
#SUB-SLAB SOIL VAPOR SAMPLE
Ñ!!TEMPORARY MONITORING WELL
"GÑ CO-LOCATED TEMPORARY MONITORING WELLAND SOIL BORING
PROPOSED BUILDING FOOTPRINT
PROPOSED PARKING DECK
PROPOSED RESIDENTIAL
PROPOSED SERVICE OR AMENITY
"GÑ
"GÑ
"GÑ
Ñ!!
TMW-1/SB-1
TMW-3/SB-6
TMW-4/SB-8
TMW-2
726
710
726
730
724
722
728
712
726
724
722
714
718
716
720
SHALLOW GROUNDWATERPOTENTIOMETRIC MAP
CRAYTON PRINTINGDISTRIBUTION STREET AND DUNAVANT STREETCHARLOTTE, NORTH CAROLINA
REVISION NO: 0
FIGURE NO: 5
2923 South Tryon Street - Suite 100Charlotte, North Carolina 28203704-586-0007 (p) 704-586-0373 (f)License # C-1269 / # C-245 Geology
0 50 100
SCALE IN FEET
N
DATE: 9-28-20
JOB NO. AKR-005
DUNAVANT STREET
DISTRIBUTION STREET
NOTE:
1. BASE DATA OBTAINED FROM MECKLENBURG COUNTY GIS, 2020.
2. ELEVATION DATA OBTAINED FROM MECKLENBURG COUNTY LIDAR, 2013.
Path: \\HHFS01\Redirectedfolders\sperry\My Documents\ArcGIS\PROJECTS\AKR-005\FIGURE 5 - GW Gradient Map.mxd
HAWKINS STREET
PROPOSEDCOURTYARD
PROPOSEDPARKING DECK
LEGEND
BROWNFIELDS PROPERTY BOUNDARY
PARCEL BOUNDARY LINE
ELEVATION CONTOUR
Ñ!!TEMPORARY MONITORING WELL
"GÑ CO-LOCATED TEMPORARY MONITORINGWELL AND SOIL BORING
PROPOSED BUILDING FOOTPRINT
PROPOSED PARKING DECK
PROPOSED RESIDENTIAL
PROPOSED SERVICE OR
GROUNDWATER ELEVATION (FT.)
INFERRED GROUNDWATER CONTOUR (FT.)
INFERRED DIRECTION OF GROUNDWATERFLOW
90
92
94
96
94
100
(100.32)
(90.79)
(93.94)
(90.11)
(100.32)100
Version Date:
Basis:
Site Name:
Site Address:
DEQ Section:
Site ID:
Exposure Unit ID:
Submittal Date:
Reviewed By:
Site Wide Soil Gas - Hypothetical Worst Case
North Carolina Department of Environmental Quality
Risk Calculator
Crayton Printing
Dunavant Street and Distribution Street
Division of Waste Management - Brownfields Program
24025-20-060
July 2020
May 2020 EPA RSL Table
Prepared By:Haley Martin, PG
Matt Bramblett, PE
North Carolina DEQ Risk Calculator
Table of Contents
Version Date: July 2020
Basis: May 2020 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Site Wide Soil Gas - Hypothetical Worst Case
Form No.
Input Form 1A Complete Exposure Pathways
Input Form 1B Exposure Factors and Target Risks
Input Form 1C Contaminant Migration Parameters
Input Form 1D Sample Statistics
Input Form 2A Soil Exposure Point Concentration Table
Input Form 2B Groundwater Exposure Point Concentration Table
Input Form 2C Surface Water Exposure Point Concentration Table
Input Form 2D Soil Gas Exposure Point Concentration Table
Input Form 2E Indoor Air Exposure Point Concentration Table
Output Form 1A Risk for Individual Pathways
Output Form 1B Sitewide Risk
Output Form 2A Resident Soil
Output Form 2B Resident Groundwater Use
Output Form 2C Non-Residential Worker Soil
Output Form 2D Non-Residential Worker Groundwater Use
Output Form 2E Construction Worker Soil
Output Form 2F Recreator/Trespasser Soil
Output Form 2G Recreator/Trespasser Surface Water
Output Form 3A Resident Groundwater to Indoor Air
Output Form 3B Resident Soil Gas to Indoor Air
Output Form 3C Resident Indoor Air
Output Form 3D Non-Residential Worker Groundwater to Indoor Air
Output Form 3E Non-Residential Worker Soil Gas to Indoor Air
Output Form 3F Non-Residential Worker Indoor Air
Output Form 4A Soil to Groundwater - Forward Mode
Output Form 4B Groundwater to Groundwater - Forward Mode
Output Form 4C Soil to Surface Water - Forward Mode
Output Form 4D Groundwater to Surface Water - Forward Mode
Output Form 4E Soil to Groundwater - Backward Mode
Output Form 4F Groundwater to Groundwater - Backward Mode
Output Form 4G Soil to Surface Water - Backward Mode
Output Form 4H Groundwater to Surface Water - Backward Mode
Output Section 4 - Contaminant Migration to Worksheets
Output Section 3 - Vapor Intrusion Calculators
TOC
Description
DATA INPUT SHEETS
Check box
if included
Input Section 1 - Exposure Pathways & Parameters
Input Section 2 - Exposure Point Concentrations
DATA OUTPUT SHEETS
Output Section 1 - Summary Output for All Calculators
Output Section 2 - Direct Contact Soil and Groundwater Calculators
North Carolina DEQ Risk Calculator
Complete Exposure Pathways
Version Date: July 2020
Basis: May 2020 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Site Wide Soil Gas - Hypothetical Worst Case
Note: Risk output will only be calculated for complete exposure pathways.
Receptor Pathway
Check box if
pathway
complete
Soil
Groundwater Use
Soil
Groundwater Use
Construction Worker Soil
Soil
Surface Water
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Source Soil
Source Groundwater
Source Soil
Source Groundwater
Resident
Non-Residential Worker
CONTAMINANT MIGRATION PATHWAYS
Groundwater
Surface Water
Input Form 1A
VAPOR INTRUSION PATHWAYS
DIRECT CONTACT SOIL AND WATER PATHWAYS
Resident
Non-Residential Worker
Recreator/Trespasser
North Carolina DEQ Risk Calculator
Exposure Point Concentrations
Version Date: July 2020
Basis: May 2020 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Site Wide Soil Gas - Hypothetical Worst Case
Description of Exposure Point Concentration Selection:
Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.
Exposure Point Concentration
(ug/m3)
Notes: CAS Number Chemical
Minimum
Concentration
(Qualifier)
Maximum
Concentration
(Qualifier)
Units
Location of
Maximum
Concentration
Detection
Frequency
Range of
Detection
Limits
Concentration
Used for
Screening
Background
Value
Screening
Toxicity Value
(Screening Level) (n/c)
Potential
ARAR/TBC
Value
Potential
ARAR/TBC
Source
COPC Flag
(Y/N)
Rationale for
Selection or
Deletion
180 67-64-1 Acetone ug/m3
32 71-43-2 Benzene ug/m3
550 75-15-0 Carbon Disulfide ug/m3
0.83 56-23-5 Carbon Tetrachloride ug/m3
2.3 67-66-3 Chloroform ug/m3
0.92 74-87-3 Chloromethane ug/m3
13 110-82-7 Cyclohexane ug/m3
1200 75-71-8 Dichlorodifluoromethane ug/m3
7.2 75-34-3 Dichloroethane, 1,1-ug/m3
230 100-41-4 Ethylbenzene ug/m3
100 142-82-5 Heptane, N-ug/m3
200 110-54-3 Hexane, N-ug/m3
20 67-63-0 Isopropanol ug/m3
15 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3
2.2 1634-04-4 Methyl tert-Butyl Ether (MTBE)ug/m3
3.9 75-09-2 Methylene Chloride ug/m3
15 91-20-3 ~Naphthalene ug/m3
760 115-07-1 Propylene ug/m3
0.75 100-42-5 Styrene ug/m3
1100 127-18-4 Tetrachloroethylene ug/m3
700 108-88-3 Toluene ug/m3
0.55 71-55-6 Trichloroethane, 1,1,1-ug/m3
9.2 79-01-6 Trichloroethylene ug/m3
240 95-63-6 Trimethylbenzene, 1,2,4-ug/m3
73 108-67-8 Trimethylbenzene, 1,3,5-ug/m3
1110 1330-20-7 Xylenes ug/m3
Input Form 2D
Soil Gas Exposure Point Concentration Table
North Carolina DEQ Risk Calculator
Risk for Individual Pathways Output Form 1A
Version Date: July 2020
Basis: May 2020 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Site Wide Soil Gas - Hypothetical Worst Case
Receptor Pathway Carcinogenic
Ris Hazard Index Risk exceeded?
Soil NC NC NC
Groundwater Use* NC NC NC
Soil NC NC NC
Groundwater Use* NC NC NC
Construction Worker Soil NC NC NC
Soil NC NC NC
Surface Water* NC NC NC
Receptor Pathway Carcinogenic
Ris Hazard Index Risk exceeded?
Groundwater to Indoor Air NC NC NC
Soil Gas to Indoor Air 1.9E-05 2.0E+00 YES
Indoor Air NC NC NC
Groundwater to Indoor Air NC NC NC
Soil Gas to Indoor Air NC NC NC
Indoor Air NC NC NC
Pathway Source
Source Soil NC
Source Groundwater NC
Source Soil NC
Source Groundwater NC
3. NM = Not Modeled
4. NC = Pathway not complete
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the
NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based
closure.
Surface Water Exceedence of 2B at Receptor?
Exceedence of 2B at Receptor?
VAPOR INTRUSION CALCULATORS
Resident
Non-Residential Worker
CONTAMINANT MIGRATION CALCULATORS
Target Receptor Concentrations Exceeded?
Groundwater Exceedence of 2L at Receptor?
Exceedence of 2L at Receptor?
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead
concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
Notes:
DIRECT CONTACT SOIL AND WATER CALCULATORS
Resident
Non-Residential Worker
Recreator/Trespasser
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air
Version Date: July 2020
Basis: May 2020 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Site Wide Soil Gas - Hypothetical Worst Case
CAS # Chemical Name:
Soil Gas
Concentration
(ug/m3)
Calculated Indoor Air Concentration
(ug/m3)
Target Indoor
Air Conc. for
Carcinogens @
TCR = 1E-06
Target Indoor Air
Conc. for Non-
Carcinogens @
THQ = 0.2
Calculated Carcinogenic Risk
Calculated
Non-Carcinogenic Hazard Quotient
67-64-1 Acetone 180 5.4 - 6.5E+03 1.7E-04
71-43-2 Benzene 32 0.96 3.6E-01 6.3E+00 2.7E-06 3.1E-02
75-15-0 Carbon Disulfide 550 16.5 - 1.5E+02 2.3E-02
56-23-5 Carbon Tetrachloride 0.83 0.0249 4.7E-01 2.1E+01 5.3E-08 2.4E-0467-66-3 Chloroform 2.3 0.069 1.2E-01 2.0E+01 5.7E-07 6.8E-0474-87-3 Chloromethane 0.92 0.0276 - 1.9E+01 2.9E-04
110-82-7 Cyclohexane 13 0.39 - 1.3E+03 6.2E-05
75-71-8 Dichlorodifluoromethane 1200 36 - 2.1E+01 3.5E-01
75-34-3 Dichloroethane, 1,1- 7.2 0.216 1.8E+00 - 1.2E-07
100-41-4 Ethylbenzene 230 6.9 1.1E+00 2.1E+02 6.1E-06 6.6E-03
142-82-5 Heptane, N- 100 3 - 8.3E+01 7.2E-03
110-54-3 Hexane, N- 200 6 - 1.5E+02 8.2E-0367-63-0 Isopropanol 20 0.6 - 4.2E+01 2.9E-03
78-93-3 Methyl Ethyl Ketone (2-Butanone) 15 0.45 - 1.0E+03 8.6E-05
1634-04-4 Methyl tert-Butyl Ether (MTBE) 2.2 0.066 1.1E+01 6.3E+02 6.1E-09 2.1E-05
75-09-2 Methylene Chloride 3.9 0.117 1.0E+02 1.3E+02 1.2E-09 1.9E-04
91-20-3 ~Naphthalene 15 0.45 8.3E-02 6.3E-01 5.4E-06 1.4E-01
115-07-1 Propylene 760 22.8 - 6.3E+02 7.3E-03
100-42-5 Styrene 0.75 0.0225 - 2.1E+02 2.2E-05127-18-4 Tetrachloroethylene 1100 33 1.1E+01 8.3E+00 3.1E-06 7.9E-01108-88-3 Toluene 700 21 - 1.0E+03 4.0E-03
71-55-6 Trichloroethane, 1,1,1- 0.55 0.0165 - 1.0E+03 3.2E-06
79-01-6 Trichloroethylene 9.2 0.276 4.8E-01 4.2E-01 5.8E-07 1.3E-01
95-63-6 Trimethylbenzene, 1,2,4- 240 7.2 - 1.3E+01 1.2E-01
108-67-8 Trimethylbenzene, 1,3,5- 73 2.19 - 1.3E+01 3.5E-02
1330-20-7 Xylenes 1110 33.3 - 2.1E+01 3.2E-01
Cumulative: 1.9E-05 2.0E+00
All concentrations are in ug/m3
Output Form 3B
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.
North Carolina DEQ Risk Calculator

Appendix B
As-Built Drawings
(dated March 25, 2024)
ELEV. 720'
ELEV. 720'
ELEV. 732'
ELEV. 725'
ELEV. 715'
5.
2
1
%

U
P
6.5
7
%

U
P
FUTURE RESIDENT
PARKING
ELEV. 723'
CYCLE CENTER RESIDENT STORAGE
RISER
MECH VENT
MECH. VENT
MECH.
DOG WASH
TRASH ROOM
ELEV. 712'
ELEV. 720'
ELEV. 719'-6"
ELEV. 718'
ELEV. 727'
ELEC.
ELEV. 717'
LOADING
ZONE
ELEV. 732'
ELEV. 722'
MAINTENANCE
TRASH STAGING AREA
BIKE STORAGE
ELEC.
ELEV LOBBY
ELEV. 717'-6"
ELEV. 730'
ELEV. 727'
ELEV. 729'
MECH. VENT
MAIL
CENTER
720' - 3"
LEVEL 1 TRASH
MECH.
LEASING/ LOUNGE
SERVICE
ELEV. 1 ELEV. 2
STAIR E
PACKAGE
STAIR B
ELEV. 3 ELEV. 4
CORRIDOR
722' - 3"
720' - 3"
LEASING/ LOUNGE
STAIR A
LYFT
WAITING
AREA
OUTDOOR
AMENITY
713' - 0 3/8"
720' - 3"
POOL ROOM
CHEM.
720' - 3"
4
13 10
LANAIS ABOVE
PARKING RAMP: 1
6.30%
719' - 9"
719' - 9"
719' - 9"
720' - 3"714' - 6 3/4"
717' - 4"
1"

/

1
2
"
1" / 12"
1"

/

1
2
"
714' - 6"
714' - 6"
714' - 6"
720' - 3"
714' - 6"
717' - 9"
719' - 9"
MECH
4'x8'
4'x8'
4'x8'
6.30%
6.30%
LARGESCALE
WASH
719' - 9"
717' - 4"4'x8'4'x8'
1/
4
"

/

1
2
"
719' - 9"
717' - 9"
STAIR C
2.75%
2.
1
0
%
0.6
2
%
0.
7
3
%
5.
2
2
%
720' - 3"
721' - 3"
720' - 3"
720' - 3"
9
5
8
6
717' - 8"
720' - 3"
721' - 3"
SL
O
P
E
DO
W
N
HS
S
8
X
4
X
1
/
4
HS
S
8
X
4
X
1
/
4
SW-#1
SW-#2
SW
-
#
4
SW-#5
SW-#6
SW-#7
SW-#8
SW
-
#
9
SW
-
#
1
0
SL
O
P
E
DO
W
N
SL
O
P
E
UP
SL
O
P
E
UP
SL
O
P
E
UP
F-1
F-2
F-3
F-4
F-5
F-6
F-8F-7
MP-2
MP-3
MP-4
MP-6
MP-9
MP-10
MP-12MP-11
MP-14
MP-1
MP-8
MP-7
MP-5
VAPOR MITIGATION PLAN PREPARED BY:
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
LEGEND
SLAB GRADE CHANGE
THICKENED SLAB
OUTDOOR OR OPEN AIR
LEVEL 2 SLAB ON GRADE AREA
EXTENT OF VAPOR LINER
3" DIA SCH 40 SLOTTED PVC PIPE
3" DIA SCH 40 SOLID PVC PIPE
4" DIA SCH 40 SOLID PVC PIPE
WESTERN SECTION (REMAINING PORTION OF
BUILDING IS REFERRED TO AS EASTERN SECTION)
3" DIA SCH 40 SOLID PVC VERTICAL RISER WITH
FAN IDENTIFICATION NUMBER (REFER TO DETAIL
NUMBER 23 ON SHEET VM-3A)
2" DIA SOLID PVC PRESSURE MONITORING POINT
WITH FLUSH-MOUNTED COVER OR EXTERIOR
ACCESS PANEL
F-7
MP-4
SEE VM-2 FOR
LEVEL 2 VIMS
LAYOUT
3" VENT CAP AT ENDS
OF SLOTTED PIPE(TYP)
SCH 40 PVC TEE
(TYP)
4" TO 3" SCH 40 PVC
REDUCER (TYP)
3" TO 4" SCH 40 PVC
REDUCER (TYP)
1
VM-3
21
VM-3A
10
VM-3
6/22
VM-3/A
5
VM-3
21
VM-3A
9
VM-3
23
VM-3A
10
VM-3
25/26
VM-3A
7/22
VM-3/A
9
VM-3
16
VM-3
14
VM-3
14
VM-3
2
VM-3
6
VM-3 16
VM-3
3" VENT CAP AT ENDS
OF SLOTTED PIPE(TYP)
3" VENT CAP AT ENDS
OF SLOTTED PIPE(TYP)
15
VM-3
15
VM-3
5
VM-3
24
VM-3A
12
VM-3
12
VM-3
24
VM-3A
17
VM-3
19
VM-3
19
VM-3
11/22
VM-3/A
17
VM-3
20
VM-3A
11/22
VM-3/A
4
VM-3
4
VM-3
20
VM-3A
7/22
VM-3/A
12
VM-3
3
VM-3
21
VM-3A
14
VM-3
8
VM-3
12
VM-3
21
VM-3A
12
VM-3
1
VM-3
13
VM-3
3
VM-3
20
VM-3A
20
VM-3A
13
VM-3
H&H NO. AKR-005
VIMS LAYOUT -
LEVEL 1
WESTERN SECTION
MARCH 25, 2024
VM-1
PROFESSIONAL
APPROVAL
AS-BUILT
CR
A
Y
T
O
N

P
R
I
N
T
I
N
G
DI
S
T
R
I
B
U
T
I
O
N

S
T
R
E
E
T

A
N
D

D
U
N
A
V
A
N
T

S
T
R
E
E
T
CH
A
R
L
O
T
T
E
,

N
O
R
T
H

C
A
R
L
I
N
A
BR
O
W
N
F
I
E
L
D
S

P
R
O
J
E
C
T

N
O
.

2
4
0
2
5
-
2
0
-
0
6
0
20
VM-3A
3
VM-3
10
VM-3
10
VM-3
03/25/24
NOTE:
THE EASTERN SECTION OF THE BUILDING WAS
PREVIOUSLY COMPLETED AND INSTALLATION OF THE
VIMS FOR THE EASTERN SECTION IS DOCUMENTED IN
THE H&H VIMS INSTALLATION COMPLETION REPORT -
EASTERN SECTION, DATED OCTOBER 16, 2023.
S:\
A
A
A
-
M
a
s
t
e
r

P
r
o
j
e
c
t
s
\
A
k
r
i
d
g
e

(
A
K
R
)
\
A
K
R
.
0
0
5

D
u
n
a
v
a
n
t

B
r
o
w
n
f
i
e
l
d
s

A
s
s
e
s
s
m
e
n
t
\
V
I
M
S

i
n
s
t
a
l
l

r
e
p
o
r
t
\
F
i
g
u
r
e
s
\
V
I
M
S
_
P
l
a
n
V
i
e
w
_
A
s
-
B
u
i
l
t
.
d
w
g
4.8
6
%

U
P
MECH.STORAGE ELEC./ DATA
MECH.
ELEV. 726'
ELEV. 730'
ELEV. 727'
ELEV. 729'
732' - 3"
729' - 11"
732' - 3"
732' - 3"
732' - 3"
MECH.
732' - 3"
732' - 3"
MECH.
STAIR D
WELLNESS STUDIO
MECH.
CORRIDOR
CORRIDOR
CORRIDOR
CORRIDOR
CORRIDOR
732' - 3"
9
9
732' - 3"
STORAGE
6.
3
1
%
6.
5
7
%
16
5 2
14
10
6
12
7
SW-#1
SW-#2
SW-#3
SW
-
#
4
SW-#5
SW-#6
SW-#7
SW-#8
SW
-
#
9
SW
-
#
1
0
F-9
F-10
F-11
F-12
F-13
F-14
F-15
F-16
F-17
MP-20 MP-15
MP-16
MP-17MP-18
MP-19
H&H NO. AKR-005
VIMS LAYOUT -
LEVEL 2
MARCH 25, 2024
VM-2
VAPOR MITIGATION PLAN PREPARED BY:
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
PROFESSIONAL
APPROVAL
AS-BUILT
CR
A
Y
T
O
N

P
R
I
N
T
I
N
G
DI
S
T
R
I
B
U
T
I
O
N

S
T
R
E
E
T

A
N
D

D
U
N
A
V
A
N
T

S
T
R
E
E
T
CH
A
R
L
O
T
T
E
,

N
O
R
T
H

C
A
R
L
I
N
A
BR
O
W
N
F
I
E
L
D
S

P
R
O
J
E
C
T

N
O
.

2
4
0
2
5
-
2
0
-
0
6
0
LEGEND
THICKENED SLAB
OUTDOOR OR OPEN AIR
LEVEL 1 SLAB ON GRADE AREA
EXTENT OF VAPOR LINER
3" DIA SCH 40 SLOTTED PVC PIPE
3" DIA SCH 40 SOLID PVC PIPE
3" DIA SCH 40 SOLID PVC VERTICAL RISER WITH
FAN IDENTIFICATION NUMBER (REFER TO DETAIL
NUMBER 23 ON SHEET VM-3A)
2" DIA SOLID PVC PRESSURE MONITORING POINT
WITH FLUSH-MOUNTED COVER OR EXTERIOR
ACCESS PANEL
F-10
MP-17
SEE VM-1 FOR
LEVEL 1 (WESTERN
SECTION) VIMS
LAYOUT
SEE VM-1 FOR
LEVEL 1 VIMS
LAYOUT
3" VENT CAP AT ENDS
OF SLOTTED PIPE(TYP)
SCH 40 PVC TEE
(TYP)
90-DEGREE SCH 40
PVC ELBOW (TYP)
SCH 40 PVC TEE
(TYP)
6
VM-3
7/22
VM-3/A 7/22
VM-3/A
21
VM-3A
21
VM-3A
3" VENT CAP AT ENDS
OF SLOTTED PIPE(TYP)
2
VM-3
15
VM-3
12
VM-3
12
VM-31
VM-3
15
VM-3
21
VM-3A
18
VM-3
18
VM-3
PACKAGE ROOM
17
VM-3
17
VM-3
12
VM-3
1
VM-3
7/22
VM-3/A
3" VENT CAP AT ENDS
OF SLOTTED PIPE(TYP)
12
VM-3
4
VM-3
12
VM-3
18
VM-3
18
VM-3
2
VM-3
7/22
VM-3/A
2
VM-3
3" VENT CAP AT ENDS
OF SLOTTED PIPE(TYP)
7/22
VM-3/A
21
VM-3A
21
VM-3A
PREVIOUS SLAB LEAVE OUT
AREA COMPLETED
03/25/24
NOTE:
THE EASTERN SECTION OF THE BUILDING WAS
PREVIOUSLY COMPLETED AND INSTALLATION OF THE
VIMS FOR THE EASTERN SECTION IS DOCUMENTED IN
THE H&H VIMS INSTALLATION COMPLETION REPORT -
EASTERN SECTION, DATED OCTOBER 16, 2023. REFER
TO SHEET VM-1 FOR THE WESTERN SECTION OF THE
BUILDING.
S:\
A
A
A
-
M
a
s
t
e
r

P
r
o
j
e
c
t
s
\
A
k
r
i
d
g
e

(
A
K
R
)
\
A
K
R
.
0
0
5

D
u
n
a
v
a
n
t

B
r
o
w
n
f
i
e
l
d
s

A
s
s
e
s
s
m
e
n
t
\
V
I
M
S

i
n
s
t
a
l
l

r
e
p
o
r
t
\
F
i
g
u
r
e
s
\
V
I
M
S
_
P
l
a
n
V
i
e
w
_
A
s
-
B
u
i
l
t
.
d
w
g
VIMS VAPOR LINER AND BASE COURSE (TYP)1
VAPOR LINER (SEE SPECIFICATION #1)
CONCRETE FLOOR SLAB
NTSVM-3
VIMS SLOTTED COLLECTION PIPING (TYP)2
VAPOR LINER (SEE SPECIFICATION #1)
NTS
CONCRETE FLOOR SLAB
VM-3
BASE COURSE - CLEAN # 57 STONE (WASHED
WITH NO FINES), MIN 5" THICK BENEATH VIMS
VAPOR LINER
3" SCH 40 SLOTTED PVC PIPE
SET WITHIN MIN 5" BASE COURSE
SUB-BASE
SUB-BASE
BASE COURSE - CLEAN # 57 STONE (WASHED
WITH NO FINES), MIN 5" THICK BENEATH VIMS
VAPOR LINER
VIMS VAPOR LINER AT INTERIOR THICKENED SLAB (TYP)
NTS
3
VM-3
VIMS VAPOR LINER AT EXTERIOR THICKENED SLAB (TYP)
NTS
4
VM-3
CONCRETE
FLOOR SLAB
BASE COURSE
(SEE SPECIFICATION #1)
VAPOR LINER
(SEE SPECIFICATION #1)
SUB-BASE
WALL (VARIES)
VAPOR LINER
(SEE SPECIFICATION #1)
SOIL SUB-BASE. GRAVEL BETWEEN OPEN
AIR PARKING GARAGE AND OCCUPIED
SPACE SHALL BE DISCONTINUOUS WITH
MINIMUM 1-FT OF SOIL IN HORIZONTAL
DIRECTION BETWEEN GRAVEL LAYERS
(SEE SPECIFICATION #8)
WALL (VARIES)
OPEN AIR
PARKING GARAGEOCCUPIED SPACE
VAPOR LINER SEALED TO CONCRETE PER
MANUFACTURERS INSTRUCTIONS (TYP)
MINIMUM 5" THICKENED SLAB THICKNESS
VIMS PIPING THROUGH FOOTING (TYP)
NTS
5
VM-3
CONCRETE
FLOOR SLAB
BASE COURSE
(SEE SPECIFICATION #1)
SUB-BASE
SOLID 3"
SCH 40 PVC
SOLID TO SLOTTED 3" SCH 40
PVC PIPE TRANSITION (SLIP
COUPLING OR THREADED JOINT)
VAPOR LINER (SEE
SPECIFICATION #1)
WALL (VARIES)
PIPE SLEEVE
THROUGH FOOTING
PIPE SLEEVE SHALL NOT
PENETRATE VAPOR LINER
(SEE SPECIFICATION #11)
SLEEVE FOR FULL LENGTH OF PROJECTION
VAPOR LINER SEALED TO PIPE PER
MANUFACTURER INSTRUCTIONS (TYP)
VIMS AT VERTICAL RISERS WITH 90 DEGREE ELBOW (TYP)
NTS
7
VM-3
BASE COURSE
(SEE SPECIFICATION #1)
SUB-BASE
VAPOR LINER SEALED TO PIPE PER
MANUFACTURER INSTRUCTIONS
VAPOR LINER
(SEE SPECIFICATION #1)
3" SCH 40 PVC RISER DUCT PIPE
(SEE SPECIFICATION #3, #4 & #5)WALL (VARIES)
3" SCH 40 PVC
90-DEGREE ELBOW
SOLID TO SLOTTED 3" SCH 40
PVC PIPE TRANSITION (SLIP
COUPLING OR THREADED JOINT)
VIMS AT SLAB STEP WITH RISER DUCT PIPING (TYP)
NTS
11
VM-3
SUB-BASE
CONCRETE FLOOR SLAB
VAPOR LINER
(SEE SPECIFICATION #1)
SOLID 3" SCH 40 PVC
(SEE SPECIFICATION #2)
BASE COURSE
(SEE SPECIFICATION #1)
WALL (VARIES)
SOLID TO SLOTTED 3" SCH 40 PVC
PIPE TRANSITION (SLIP COUPLING
OR THREADED JOINT)
VAPOR LINER SEALED TO PIPE
PER MANUFACTURER
INSTRUCTIONS (TYP)
3" SCH 40 PVC
90-DEGREE ELBOW
3" SCH 40 PVC
90-DEGREE TEE
PIPE SLEEVE (SEE SPECIFICATION #11)
VIMS AT DEPRESSIONS IN SLAB-ON-GRADE (TYP)
NTS
9
VM-3
CONCRETE FLOOR SLAB
SUBBASEVAPOR BARRIER
(SEE SPECIFICATION #1)
BASE COURSE
(SEE SPECIFICATION #1)
VIMS PIPING THROUGH DEPRESSIONS IN SLAB-ON-GRADE (TYP)
NTS
10
VM-3
SUB-BASE
CONCRETE FLOOR SLAB
VAPOR LINER
(SEE SPECIFICATION #1)
BASE COURSE
(SEE SPECIFICATION #1)
SOLID TO SLOTTED 3" SCH 40
PVC PIPE TRANSITION (SLIP
COUPLING OR THREADED JOINT)
3" SCH 40 PVC
90-DEGREE ELBOW
VAPOR LINER SEALED TO
PIPE PER MANUFACTURER
INSTRUCTIONS
SOLID 3" SCH 40 PVC
(SEE SPECIFICATION #5)
PIPE SLEEVE (SEE
SPECIFICATION #11)
WALL (VARIES)
VIMS AT EXTERIOR FOOTING (TYP)
NTSVM-3
8
CONCRETE FLOOR SLAB
VAPOR LINER SEALED TO CONCRETE
PER MANUFACTURERS INSTRUCTIONS
VAPOR LINER
(SEE SPECIFICATION #1)
BASE COURSE
(SEE SPECIFICATION #1)
SUB-BASE
EXTERIOR GRADE
(VARIES)
WALL (VARIES)
VAPOR LINER EXTENDED TO EXTERIOR SIDE OF
FOOTER, IF POSSIBLE, BASED ON CONSTRUCTION
SEQUENCE. ENGINEER WILL APPROVE FINAL VAPOR
LINER TERMINATION POINT DURING CONSTRUCTION
COLUMN BLOCKOUT
VIMS AT EXTERIOR COLUMN (TYP)
NTS
15
VM-3
SUB-BASE
CONCRETE
FLOOR SLAB
BASE COURSE
(SEE SPECIFICATION #1)
VAPOR LINER
(SEE SPECIFICATION #1)
CIP CONCRETE COLUMN
VAPOR LINER SEALED
TO CONCRETE PER
MANUFACTURERS
INSTRUCTIONS
VIMS AT INTERIOR COLUMN (TYP)
NTS
14
VM-3
SUB-BASE
CONCRETE FLOOR SLAB
BASE COURSE
(SEE SPECIFICATION #1)
VAPOR LINER
(SEE SPECIFICATION #1)
CIP CONCRETE COLUMN
CONCRETE FOOTING
VAPOR LINER SEALED OUTSIDE OF
CONCRETE COLUMN PER
MANUFACTURER INSTRUCTIONS
VIMS AT VERTICAL RISERS WITH TEE (TYP)
NTS
6
VM-3
BASE COURSE
(SEE SPECIFICATION #1)SUB-BASE
SOLID 3" SCH 40 PVC
VAPOR LINER SEALED TO PIPE PER
MANUFACTURER INSTRUCTIONS
VAPOR LINER
(SEE SPECIFICATION #1)
SOLID TO SLOTTED 3" SCH 40
PVC PIPE TRANSITION (SLIP
COUPLING OR THREADED JOINT)
3" SCH 40 PVC RISER DUCT PIPE
(SEE SPECIFICATION #3, #4 & #5)WALL (VARIES)
3" SCH 40 PVC TEE
VAPOR LINER
BENEATH THICKENED SLAB
VAPOR BARRIER AT STAIR THICKENED SLAB13
NTSVM-3
STAIR STRINGER
SUBBASE
BASE COURSE
(SEE SPECIFICATION #1)
CONCRETE FLOOR
SLABVAPOR LINER
(SEE SPECIFICATION #1)
VAPOR BARRIER AT SLAB EDGE12
NTSVM-3
WALL (VARIES)
BASE COURSE
(SEE SPECIFICATION #1)
SUB-BASE
VAPOR LINER
(SEE SPECIFICATION #1)
WALL (VARIES)WALL (VARIES)
BASE COURSE
(SEE SPECIFICATION #1)
SUB-BASE
VAPOR LINER
(SEE SPECIFICATION #1)
OPEN AIR PATIO /
TERRACE
VIMS PIPING THROUGH FOOTING WITH REDUCER (TYP)
NTS
16
VM-3
OPEN AIR SPACE
CONCRETE FLOOR SLAB
BASE COURSE
(SEE SPECIFICATION #1)
SUB-BASE
SOLID 4" SCH 40 PVC
4" TO 3" SCH 40
PVC REDUCER
VAPOR LINER (SEE
SPECIFICATION #1)
WALL (VARIES) PIPE SLEEVE
THROUGH FOOTING
PIPE SLEEVE SHALL NOT
PENETRATE VAPOR LINER
(SEE SPECIFICATION #11)
VAPOR LINER SEALED TO PIPE PER
MANUFACTURER INSTRUCTIONS (TYP)
SLOTTED 3-INCH
SCH 40 PIPE
VIMS AT RETAINING WALL ADJACENT TO ENCLOSED SPACE (TYP)
NTS
17
VM-3
OCCUPIED SPACE
OCCUPIED SPACE
SUB-BASE
BASE COURSE
(SEE SPECIFICATION #1)
VAPOR LINER
(SEE SPECIFICATION #1)
VAPOR LINER SEALED TO OUTSIDE OF CONCRETE
AND WATERPROOFING/INSULATION (WHERE
PRESENT) PER MANUFACTURER INSTRUCTIONS
WATERPROOFING AND
RIGID INSULATION
DRAIN
WALL (VARIES)
CONCRETE
FLOOR SLAB
VIMS AT RETAINING WALL ADJACENT TO OPEN AIR SPACE (TYP)
NTS
18
VM-3
INTERIOR SPACE
OPEN AIR SPACE
SUB-BASE
CONCRETE
FLOOR SLAB
BASE COURSE
(SEE SPECIFICATION #1)
VAPOR LINER
(SEE SPECIFICATION #1)
WATERPROOFING AND
RIGID INSULATION
DRAIN
WALL (VARIES)
VIMS AT RETAINING WALL ADJACENT TO OCCUPIED SPACE (TYP)
NTS
19
VM-3
OPEN AIR SPACE
OCCUPIED SPACE
SUB-BASE
BASE COURSE
(SEE SPECIFICATION #1)
VAPOR LINER
(SEE SPECIFICATION #1)
VAPOR LINER SEALED TO OUTSIDE OF CONCRETE
AND WATERPROOFING/INSULATION (WHERE
PRESENT) PER MANUFACTURER INSTRUCTIONS
WATERPROOFING AND
RIGID INSULATION
DRAIN
WALL (VARIES)
CONCRETE
FLOOR SLAB
VAPOR MITIGATION PLAN PREPARED BY:
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
ISSUED FOR CONSTRUCTION
NOTES:
VIMS = VAPOR INTRUSION MITIGATION SYSTEM
TYP = TYPICAL
SCH = SCHEDULE
PVC = POLYVINYL CHLORIDE
NTS = NOT TO SCALE
ALL PIPE MEASUREMENTS ARE BY DIAMETER
H&H NO. AKR-005
VIMS DETAILS
#1 - 19
WESTERN SECTION
MARCH 25, 2024
VM-3
PROFESSIONAL
APPROVAL
AS-BUILT
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NTSVM-3A
VIMS AT ELEVATOR PIT (TYP)
CONTINUOUS VAPOR LINER
SEALED PER MANUFACTURER
INSTRUCTIONS
SUMP PIT
SUB-BASE
BASE COURSE
(SEE SPECIFICATION #1)
VAPOR LINER
(SEE SPECIFICATION #1)
OVERLAP WATERPROOFING WITH
VAPOR BARRIER TO CREATE
CONTINUOUS SEAL
CONTINUOUS 60-MIL
WATERPROOFING MEMBRANE
(SEE SPECIFICATION #13)
VIMS TURBINE VENTILATOR FAN & EXHAUST (TYP)22
NTS
TURBINE VENTILATOR FAN
(EMPIRE MODEL TV04SS OR ENGINEER
APPROVED EQUIVALENT)
OUTDOOR-RATED ELECTRICAL JUNCTION BOX FOR
POTENTIAL FUTURE VACUUM FAN (REFER TO
SPECIFICATION #4)
RISER DUCT PIPE THROUGH ROOF
FLASHING
ROOFTOP
VM-3A
4" X3" HEAVY DUTY NO
HUB COUPLING
SLP.
VIMS AT RAMP (TYP)
NTS
23
VM-3A
T.O.C.
SUB-BASE
SLOTTED 3-INCH
SCH 40 PIPE
VAPOR LINER
(SEE SPECIFICATION #1)CONCRETE FLOOR SLAB
BASE COURSE
(SEE SPECIFICATION #1)
EXTERIOR PERMANENT VACUUM MEASURING POINT (TYP)21
NTSVM-3A
WALL (VARIES)
PROVIDE LOCKABLE WEATHERPROOF
ENCLOSURE ON OUTSIDE OF BUILDING
WALL (OR SIMILAR). AFFIX LABEL AT
BOX WITH "VAPOR MITIGATION SYSTEM".
PLACE REMOVABLE PIPE PLUG AT END
OF 2" PIPE.
VAPOR LINER SEALED TO CONCRETE PER
MANUFACTURERS INSTRUCTIONS (TYP)
2" SOLID SCH 40 PVC PIPE
INSTALLER SHALL SECURE PIPE TO
PREVENT MOVEMENT OR DAMAGE TO
PIPE DURING THE CONCRETE POUR
EXTERIOR GRADE
(VARIES)
BASE COURSE
(SEE SPECIFICATION #1)
2" OPEN ENDED PIPE, PLACED AT A MINIMUM OF
5' FROM EXTERIOR TURN-DOWN SLABS
VENT PIPE PROTECTION SCREEN
PIPE SLEEVE. SEE SPECIFICATION #11. SLEEVE
SHALL NOT PENETRATE VAPOR LINER.
VAPOR LINER
(SEE SPECIFICATION #1)
VAPOR LINER SEALED TO PIPE PER
MANUFACTURERS INSTRUCTIONS (TYP)
FINISHED FLOOR SLAB
2" SCH 40 PVC SET WITHIN GRAVEL LAYER
(SEE DETAIL 14 & 15)
2" DRAIN EXPANSION TEST PLUG
VIMS MONITORING POINT - TYPICAL DETAIL VIEW
NTS
20
VM-3A
VAPOR BARRIER PENETRATION SEALED TO
PIPE PER MANUFACTURER INSTRUCTIONS
2" SCH 40 PVC 90 DEGREE ELBOW
FLOOR CLEANOUT, ADJUSTABLE, 4" DIA ZURN
INDUSTRIES MODEL #CO2450-PV4 (OR ENGINEER
APPROVED EQUIVALENT) FLUSH WITH FINISHED FLOOR
BASE COURSE
(SEE SPECIFICATION #1)
4" x 2" FLUSH REDUCER
BUSHING
2" VENT PIPE
PROTECTION SCREEN
VIMS AT STAIRWELL WITH DRAINPIPE (CROSS-SECTION VIEW)
NTS
25
VM-3A
VAPOR LINER
BASE COURSE
(SEE SPECIFICATION #1)
DRAIN
COMPACTED SOIL SUB-BASE
3" SCH 40 PVC
90-DEGREE ELBOW
SOLID 3" SCH 40 PVC
(SEE SPECIFICATION #5)3" SCH 40 PVC
90-DEGREE TEE
SLOTTED 3-INCH
SCH 40 PIPE
VAPOR LINER
(EXTENDED 3 FT
PAST DRAIN)
SOLID TO SLOTTED 3" SCH 40 PVC PIPE TRANSITION
(SLIP COUPLING OR THREADED JOINT)
PIPE SLEEVE THROUGH FOOTING
(SEE SPECIFICATION #11)
VIMS AT STAIRWELL WITH DRAINPIPE (PROFILE VIEW)
NTS
26
VM-3A
3" SCH 40 PVC
90-DEGREE TEE
COMPACTED SOIL
SUB-BASE
VAPOR LINER SLOTTED 3-INCH
SCH 40 PIPE
SOLID 3" SCH 40 PVC
(SEE SPECIFICATION #5)
3" SCH 40 PVC
90-DEGREE ELBOW
BASE COURSE
BASE COURSE
(SEE SPECIFICATION #1)
DRAIN
(PERFORATED)
VAPOR LINER
VAPOR MITIGATION PLAN PREPARED BY:
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
ISSUED FOR CONSTRUCTION
H&H NO. AKR-005
VIMS DETAILS
#20 - 26 AND
SPECIFICATIONS
WESTERN SECTION
MARCH 25, 2024
VM-3A
PROFESSIONAL
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NOTES:
VIMS = VAPOR INTRUSION MITIGATION SYSTEM
TYP = TYPICAL
SCH = SCHEDULE
PVC = POLYVINYL CHLORIDE
NTS = NOT TO SCALE
ALL PIPE MEASUREMENTS ARE BY DIAMETER
VIMS SPECIFICATIONS
1.THIS VAPOR MITIGATION PLAN WAS USED FOR DIRECTION OF VIMS COMPONENT INSTALLATION ONLY AND WAS NOT USED TO GUIDE CONSTRUCTION
OF BUILDING STRUCTURAL COMPONENTS. CONSTRUCTION CONTRACTOR VERIFIED CONSISTENCY OF VIMS DETAILS WITH APPLICABLE STRUCTURAL,
ARCHITECTURAL, MECHANICAL, & PLUMBING PLANS AND RESOLVED ANY INCONSISTENCIES PRIOR TO VIMS INSTALLATION.
VIMS VAPOR LINER CONSISTS OF VAPORBLOCK PLUS 20 (VBP20) 20-MIL VAPOR LINER MANUFACTURED BY VIAFLEX, INC. FORMERLY RAVEN
INDUSTRIES.
ONE VAPOR LINER PRODUCT AND ASSOCIATED ACCESSORIES WERE USED THROUGHOUT THE SYSTEM. THE VAPOR LINER WAS INSTALLED AS SPECIFIED
HEREIN AND PER MANUFACTURER INSTALLATION INSTRUCTIONS TO CREATE A CONTINUOUS LINER BELOW MITIGATED AREAS, AND ALONG RETAINING
WALLS AND SLAB-ON-GRADE FOLDS WITHIN THE EXTENT OF VAPOR LINER BOUNDARY. A MINIMUM 5-INCH THICK BASE COURSE CONSISTING OF
CLEAN #57 STONE (WASHED WITH NO FINES) WAS INSTALLED BENEATH THE VIMS VAPOR LINER.
THE VAPOR LINER WAS PROPERLY SEALED IN ACCORDANCE WITH THE MANUFACTURER INSTALLATION INSTRUCTIONS AS SPECIFIED IN THESE
DRAWINGS TO FOOTERS, SLAB STEPS, RETAINING WALLS, PENETRATIONS (SUCH AS PIPE PENETRATIONS), OR OTHER BUILDING COMPONENTS WITHIN
THE VIMS EXTENTS. VAPOR LINER WAS INSTALLED UNDER CMU WALLS WHICH SUPPORT OCCUPIED ENCLOSED SPACES.
VAPOR BARRIER WAS INSTALLED ON SLABS, WALLS, AND OTHER STRUCTURAL COMPONENTS WHICH COME IN CONTACT WITH BOTH AN OCCUPIABLE
ENCLOSED SPACE AND SOIL.
CONCRETE BOXOUTS INSPECTED BY H&H, INCLUDING BUT NOT LIMITED TO SHOWER/BATH TUB DRAINS, HAVE A CONTINUOUS VAPOR LINER
INSTALLED BELOW.
2.SUB-SLAB VAPOR COLLECTION PIPE CONSISTS OF THREADED FLUSH JOINT 3" SCH 40 PVC SLOTTED PIPE WITH 0.020" SLOT WIDTH AND 18" SLOT SPACING.
A VENT CAP WAS INSTALLED ON THE OPEN PIPE END. PVC PIPE JOINTS WERE JOINED WITH PVC PRIMER AND GLUE BELOW THE SLAB. SLOTTED
COLLECTION PIPING WAS SET WITHIN A MINIMUM 5” BASE COURSE LAYER, WITH APPROXIMATELY 1” OF BASE COURSE MATERIAL BELOW THE PIPING.
3.3" SCH 40 PVC RISER DUCT PIPING WAS INSTALLED TO CONNECT EACH SLAB PENETRATION LOCATION TO A ROOFTOP EXHAUST DISCHARGE POINT
WITH TURBINE VENTILATOR. ABOVE-SLAB RISER DUCT PIPE RUNS BETWEEN THE SLAB PENETRATION AND THE ROOFTOP EXHAUST DISCHARGE WERE
INSTALLED IN ACCORDANCE WITH THE VIMS PLANS AND AS SPECIFIED IN THE CONSTRUCTION DOCUMENTS AND DRAWINGS. VERTICAL RISER PIPING
WAS CONNECTED WITH PVC PRIMER AND GLUE. VIMS BELOW AND ABOVE GRADE SOLID PIPING ARE NOT BE TRAPPED AND ARE SLOPED A MINIMUM
OF 1/8 UNIT VERTICAL BY 12 UNITS HORIZONTAL (1% SLOPE) TO GRAVITY DRAIN. BENDS, TURNS, AND ELBOWS IN VERTICAL RISER PIPES WERE
MINIMIZED FROM THE SLAB TO THE ROOFTOP.
4.3" SCH 40 PVC RISER DUCT PIPING EXTENDS IN A VERTICAL ORIENTATION THROUGH THE BUILDING ROOF AND TERMINATES A MINIMUM OF 2 FT
ABOVE THE BUILDING ROOF LINE. EMPIRE MODEL TV04SS STAINLESS STEEL TURBINE VENTILATORS WERE INSTALLED ON THE EXHAUST DISCHARGE
END OF EACH RISER DUCT PIPE. THE 3" RISER DUCT PIPE AND THE FAN ARE SECURED TO THE PVC RISER IN A VERTICAL ORIENTATION. EXHAUST
DISCHARGE LOCATIONS ARE A MINIMUM OF 10 FT FROM ANY OPERABLE OPENING OR AIR INTAKE INTO THE BUILDING. NOTE THAT SOME DISCHARGE
LOCATIONS ON THE ROOFTOP DEPICTED IN THE VAPOR MITIGATION PLAN WERE REPOSITIONED WITH THE NEW POSITION MEETING THE
REQUIREMENTS PRESENTED ABOVE, WITH ENGINEER APPROVAL. AN ELECTRICAL JUNCTION BOX (120V REQUIRED) FOR OUTDOOR USE WAS
INSTALLED NEAR THE FAN LOCATION ON THE ROOFTOP FOR POTENTIAL FUTURE CONVERSION TO ELECTRIC FANS, IF REQUIRED.
5.ABOVE-SLAB ACCESSIBLE RISER DUCT PIPING IS PERMANENTLY IDENTIFIED BY MEANS OF A TAG OR STENCIL AT A MINIMUM OF ONCE EVERY 10-LINEAR
FT WITH "VAPOR MITIGATION. CONTACT MAINTENANCE". LABELS ARE ALSO FIXED TO THE TURBINE VENTILATORS IN AN ACCESSIBLE LOCATION ON
THE ROOFTOP.
6.MONITORING POINTS CONSIST OF 2-INCH DIAMETER SCH 40 PVC PIPE WITH A 90-DEGREE ELBOW TO FORM AN “L” SHAPE. A MINIMUM OF 6”
SECTION OF PIPING IS SET WITHIN THE BASE COURSE LAYER WITH AN OPEN ENDED PIPE OR PIPE PROTECTION SCREEN AT THE TERMINATION. THE PIPE
TERMINATION IS ENCASED WITHIN THE BASE COURSE LAYER. THE HORIZONTAL PIPING IS SLOPED A MINIMUM OF 1/8 UNIT VERTICAL BY 12 UNITS
HORIZONTAL (1% SLOPE) TO GRAVITY DRAIN TOWARDS THE PIPE TERMINATION AND PREVENT MOISTURE FROM COLLECTING AT THE 90-DEGREE
ELBOW. A 4-INCH DIAMETER ADJUSTABLE FLOOR CLEAN-OUT (ZURN INDUSTRIES MODEL #CO2450-PV4, OR EQUIVALENT) WAS INSTALLED AND SET
FLUSH WITH THE FINISHED CONCRETE SURFACE. FOR EXTERIOR MONITORING POINTS, THE PIPE TERMINATION IS COVERED IN A WEATHERPROOF
ENCLOSURE ON THE OUTSIDE OF THE WALL. THE PIPE TERMINATION IS APPROXIMATELY 2' ABOVE THE EXTERIOR GRADE. MONITORING POINT
INTAKES ARE A MINIMUM 5-FT FROM EXTERIOR FOOTING.
7.CONSTRUCTION CONTRACTORS AND SUB-CONTRACTORS WERE INSTRUCTED TO USE "LOW OR NO VOC" PRODUCTS AND MATERIALS, WHEN POSSIBLE,
AND WERE INSTRUCTED TO NOT USE PRODUCTS CONTAINING THE COMPOUNDS TETRACHLOROETHENE (PCE) OR TRICHLOROETHENE(TCE). THE
CONSTRUCTION CONTRACTOR AND SUB-CONTRACTORS PROVIDED SAFETY DATA SHEETS (SDS) TO THE ENGINEER FOR THE PRODUCTS AND MATERIALS
USED FOR CONSTRUCTION OF THE VIMS.
8.IN INSTANCES WHERE A THICKENED FOOTING OR RETAINING WALL WAS NOT SPECIFIED AT THE EXTENT OF VAPOR LINER, A THICKENED SLAB OR
FOOTER WAS INSTALLED BY THE CONTRACTOR THAT INCLUDES A SOIL SUBBASE TO CREATE A CUT-OFF FOOTER AT THE EXTENT OF VAPOR LINER. THE
ADDITIONAL THICKENED SLAB OR FOOTER DOES NOT ALLOW FOR CONTINUOUS GRAVEL BETWEEN THE VIMS EXTENTS AND EXTERIOR PORTIONS OF
THE BUILDING WITH AT LEAST 12" SEPARATION OF ADJACENT GRAVEL BEDS. THE THICKENED SLAB OR FOOTER IS A MINIMUM OF 5" GREATER IN
THICKNESS THAN THE SURROUNDING SLAB.
9.CONSTRUCTION CONTRACTORS AND SUB-CONTRACTORS AVOIDED THE USE OF TEMPORARY FORM BOARDS THAT PENETRATE THE VAPOR LINER
WHERE POSSIBLE. IF TEMPORARY FORM BOARDS ARE USED, THE SIZE AND NUMBER OF PENETRATIONS THROUGH THE VAPOR LINER WAS LIMITED
AND SMALL DIAMETER SOLID STAKES (I.E. METAL STAKES) WERE USED. AS FORM BOARDS WERE REMOVED, THE CONTRACTOR OR SUB-CONTRACTORS
RESEALED OBSERVED PENETRATIONS IN ACCORDANCE WITH VAPOR LINER MANUFACTURER INSTALLATION INSTRUCTIONS. CONTRACTORS AVOIDED
USING HOLLOW PIPING TO SUPPORT UTILITY PIPING IN PREPARATION FOR A CONCRETE SLAB POUR.
10.INSPECTIONS: INSPECTIONS OF EACH COMPONENT OF THE VIMS WAS CONDUCTED BY THE ENGINEER, OR ENGINEER'S DESIGNEE, TO CONFIRM VIMS
COMPONENTS ARE INSTALLED PER THE APPROVED DESIGN. THE REQUIRED INSPECTION COMPONENTS INCLUDED: (1) INSPECTION OF SUB-SLAB
PIPING LAYOUT, (2) GRAVEL PLACEMENT, AND (3) MONITORING POINT PLACEMENT PRIOR TO INSTALLING VAPOR BARRIER; (4) INSPECTION OF VAPOR
BARRIER PRIOR TO POURING CONCRETE; (5) INSPECTION OF ABOVE-GRADE PIPING LAYOUT; AND (6) INSPECTION OF TURBINE VENTILATORS AND RISER
DUCT PIPE CONNECTIONS. INSPECTIONS WERE COMBINED WHEN POSSIBLE DEPENDING ON THE CONSTRUCTION SEQUENCE/SCHEDULE. THE
CONSTRUCTION CONTRACTOR(S) COORDINATED WITH THE ENGINEER TO PERFORM THE REQUIRED INSPECTIONS.
11.PIPE SLEEVES WERE INSTALLED AND/OR SEALED TO PREVENT A PREFERENTIAL AIR PATHWAY FROM BELOW THE SLAB INTO THE BUILDING. REFER TO
TO STRUCTURAL DRAWINGS FOR FOOTING DETAILS ADDRESSING VIMS PIPING.
12.THE VAPOR BARRIER WAS INSTALLED BETWEEN WATERPROOFING AND ANY DRAINAGE FEATURES INCLUDING DRAINAGE MATS WHERE IT OVERLAPS.
THE INSTALLER CONFIRMED THAT THE WATERPROOFING PRODUCTS AND SEALANTS USED DURING CONSTRUCTION ARE COMPATIBLE WITH THE
SPECIFIED VAPOR BARRIER.
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Appendix C
VIMS Installation Photographs
CRAYTON PRINTING
DISTRIBUTION STREET & DUNAVANT STREET
CHARLOTTE, NORTH CAROLINAPr
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2923 S. Tryon Street, Suite 100
Charlotte, NC 28203704.586.0007(p) 704.586.0373(f)
Photograph 1: Representative view of sub-slab slotted piping network and gravel layer in
Western Section.
Photograph 2: Representative view of sub-slab slotted piping network and gravel layer in Western Section.
CRAYTON PRINTING
DISTRIBUTION STREET & DUNAVANT STREET
CHARLOTTE, NORTH CAROLINAPr
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Photograph 4: Representative view of Viaflex VaporBlock 20 Plus (VBP-20) vapor barrier installed
in Western Section.
2923 S. Tryon Street, Suite 100
Charlotte, NC 28203704.586.0007(p) 704.586.0373(f)
Photograph 3: Representative view of monitoring point prior to vapor barrier installation in Western
Section.
CRAYTON PRINTING
DISTRIBUTION STREET & DUNAVANT STREET
CHARLOTTE, NORTH CAROLINAPr
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Photograph 6: Representative view of Viaflex VBP20 vapor barrier and Viaflex Pour N’ Seal
installed in electrical room.
2923 S. Tryon Street, Suite 100
Charlotte, NC 28203704.586.0007(p) 704.586.0373(f)
Photograph 5: Representative view of Viaflex VBP20 vapor barrier installed in Western Section.
Viaflex Pour N’ Seal around
conduits
CRAYTON PRINTING
DISTRIBUTION STREET & DUNAVANT STREET
CHARLOTTE, NORTH CAROLINAPr
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Photograph 8: View of Viaflex VBP-20 and waterproofing drainage mat (black) installed around elevator pit
in Western Section. Note, the VBP-20 vapor barrier is installed below the drainage mat.
2923 S. Tryon Street, Suite 100
Charlotte, NC 28203704.586.0007(p) 704.586.0373(f)
Photograph 7: View of Viaflex VBP-20 vapor barrier installed in slab leave out for crane access in
the Eastern Section of the building.
CRAYTON PRINTING
DISTRIBUTION STREET & DUNAVANT STREET
CHARLOTTE, NORTH CAROLINAPr
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Photograph 10: Representative view of VIMS riser F-5 installed with label affixed.
2923 S. Tryon Street, Suite 100
Charlotte, NC 28203704.586.0007(p) 704.586.0373(f)
Photograph 9: Representative view of VIMS riser F-4 installed with label affixed.
CRAYTON PRINTING
DISTRIBUTION STREET & DUNAVANT STREET
CHARLOTTE, NORTH CAROLINAPr
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Photograph 11: Representative view of Empire turbine ventilators installed on the roof.
2923 S. Tryon Street, Suite 100
Charlotte, NC 28203704.586.0007(p) 704.586.0373(f)

Appendix D
VIMS Product Specification Sheets
PRODUCT PART #
VaporBlock® Plus™ 20 ................................................................ VBP20
UNDER-SLAB VAPOR / GAS BARRIER
Under-Slab Vapor/Gas Retarder
VAPORBLOCK® PLUS™VBP20
PRODUCT DESCRIPTION
VaporBlock® Plus™ is a seven-layer co-extruded barrier
made using high quality virgin-grade polyethylene and
EVOH resins to provide unmatched impact strength as well
as superior resistance to gas and moisture transmission.
VaporBlock® Plus™ 20 is more than 100 times less permeable
than typical high-performance polyethylene vapor retarders
against Methane, Radon, and other harmful VOCs. Tested and
verified for unsurpassed protection against BTEX, HS, TCE, PCE,
methane, radon, other toxic chemicals and odors.
VaporBlock® Plus™ 20 multi-layer gas barrier is manufactured
with the latest EVOH barrier technology to mitigate hazardous
vapor intrusion from damaging indoor air quality, and the safety
and health of building occupants. VBP20 is one of the most
effective underslab gas barriers in the building industry today
far exceeding ASTM E-1745 (Plastic Water Vapor Retarders
Used in Contact with Soil or Granular Fill Under Concrete Slabs)
Class A, B and C requirements. Available in a 20 (Class A) mil
thicknesses designed to meet the most stringent requirements.
VaporBlock® Plus™ 20 is produced within the strict guidelines
of our ISO 9001 Certified Management System.
PRODUCT USE
VaporBlock® Plus™ 20 resists gas and moisture migration
into the building envelop when properly installed to provide
protection from toxic/harmful chemicals. It can be installed as
part of a passive or active control system extending across the
entire building including floors, walls and crawl spaces. When
installed as a passive system it is recommended to also include
a ventilated system with sump(s) that could be converted to an
active control system with properly designed ventilation fans.
VaporBlock® Plus™ 20 works to protect your flooring and
other moisture-sensitive furnishings in the building’s interior
from moisture and water vapor migration, greatly reducing
condensation, mold and degradation.
SIZE & PACKAGING
VaporBlock® Plus™ 20 is available in 10’ x 150’ rolls to
maximize coverage. All rolls are folded on heavy-duty cores
for ease in handling and installation. Other custom sizes
with factory welded seams are available based on minimum
volume requirements. Installation instructions and ASTM E-1745
classifications accompany each roll.
© 2022 VIAFLEX, INC. All rights reserved.
APPLICATIONS
Radon Barrier
Methane Barrier
VOC Barrier
Brownfields Barrier
Vapor Intrusion Barrier
Under-Slab Vapor Retarder
Foundation Wall Vapor Retarder
VaporBlock® Plus™ is a seven-layer co-extruded barrier made using high quality virgin-grade polyethylene and EVOH resins to provide unmatched impact strength as well as superior resistance to gas and moisture transmission.
VaporBlock® Plus™ Placement
All instructions on architectural or structural drawings should be reviewed and followed.
Detailed installation instructions accompany each roll of VaporBlock® Plus™ and can also be located at www.ravenefd.com.
ASTM E-1643 also provides general installation information for vapor retarders.
VAPORBLOCK® PLUS™ 20
PROPERTIES TEST METHOD IMPERIAL METRIC
AppeArAnce White/Gold
Thickness, nominAl 20 mil 0.51 mm
WeighT 102 lbs/MSF 498 g/m²
clAssificATion ASTM E 1745 CLASS A, B & C
³ Tensile sTrengTh
ASTM E 154Section 9(D-882)58 lbf 102 N
impAcT resisTAnce ASTM D 1709 2600 g
permeAnce (neW mATeriAl)
ASTM E 154Section 7ASTM E 96Procedure B
0.0098 Perms
grains/(ft²·hr·in·Hg)
0.0064 Perms
g/(24hr·m²·mm Hg)
permeAnce (AfTer condiTioning)
(sAme meAsuremenT As Above permeAnce)
ASTM E 154Section 8, E96Section 11, E96Section 12, E96Section 13, E96
0.00790.00790.00970.0113
0.00520.00520.00640.0074
WvTr ASTM E 96Procedure B 0.0040 grains/hr-ft²0.0028 gm/hr-m²
benzene permeAnce See Note ⁶1.13 x 10-¹⁰ m²/sec or 3.62 x 10-¹³ m/s
Toluene permeAnce See Note ⁶1.57 x 10-¹⁰ m²/sec or 1.46 x 10-¹³ m/s
eThylbenzene permeAnce See Note ⁶1.23 x 10-¹⁰ m²/sec or 3.34 x 10-¹⁴ m/s
m & p-Xylenes permeAnce See Note ⁶1.17 x 10-¹⁰ m²/sec or 3.81 x 10-¹⁴ m/s
o-Xylene permeAnce See Note ⁶1.10 x 10-¹⁰ m²/sec or 3.43 x 10-¹⁴ m/s
hydrogen sulfide See Note 9 1.92E-⁰⁹ m/s
TrichloroeThylene (Tce) See Note ⁶7.66 x 10-¹¹ m²/sec or 1.05 x 10-¹⁴ m/s
perchloroeThylene (pce)See Note ⁶7.22 x 10-¹¹ m²/sec or 1.04 x 10-¹⁴ m/s
rAdon diffusion coeffiecienT K124/02/95 < 1.1 x 10-13 m2/s
meThAne permeAnce ASTM D 1434 3.68E-¹² m/sGas Transmission Rate (GTR):0.32 mL/m²•day•atm
mAXimum sTATic use TemperATure 180° F 82° C
minimum sTATic use TemperATure - 70° F - 57° C
UNDER-SLAB VAPOR / GAS BARRIER
VAPORBLOCK® PLUS™VBP20
³ Tests are an average of machine and transverse directions.5 Raven Industries performs seam testing at 20” per minute.6 Aqueous Phase Film Permeance.
Permeation of Volatile Organic Compounds through EVOH Thin Film Membranes and Coextruded LLDPE/EVOH/
LLDPE Geomembranes, McWatters and Rowe, Journal of Geotechnical and Geoenvironmental Engineering© ASCE/
September 2015. (Permeation is the Permeation Coefficient adjusted to actual film thickness - calculated at 1 kg/m³.)
The study used to determine PCE and TCE is titled: Evaluation of diffusion of PCE & TCE through high performance geomembranes by Di
Battista and Rowe, Queens University 8 Feb 2018.9 The study used to determine diffusion coefficients is titled: Hydrogen Sulfide (H₂S) Transport through Simulated Interim Covers with Conventional and Co-Extruded Ethylene-Vinyl Alcohol (EVOH) Geomembranes.
Scan QR Code to download technical data sheets.
Note: To the best of our knowledge, unless otherwise stated, these are typical property values and are intended as guides only, not as specification limits. Chemical resistance, odor transmission, longevity as well as other performance criteria is not implied or given and actual testing must be performed for applicability in specific applications and/or conditions. VIAFLEX MAKES NO WARRANTIES AS TO THE FITNESS FOR A SPECIFIC USE OR MERCHANTABILITY OF PRODUCTS REFERRED TO, no guarantee of satisfactory results from reliance upon contained information or recommendations and disclaims all liability for resulting loss or damage. Limited Warranty available at www.viaflex.com
VIAFLEX, INC.821 W Algonquin Street Sioux Falls, SD 57104 Ph: [phone] • TF: [phone]© 2022 VIAFLEX, INC. All rights reserved.27-0123 09/22
[e-mail] www.viaflex.com
INSTALLATION GUIDELINES - With VaporSeal™ Tape
VaporSeal™
4” Tape
Optional Butyl Seal
2-Sided Tape
Elements of a moisture/gas-resistant floor system. General illustration only.(Note: This example shows multiple options for waterstop placement.
VaporSeal™
4” Tape
VaporSeal™ 4” Tape
Fig. 2: VaporBlock® Plus™ Overlap Joint Sealing Methods
Fig. 1: VaporBlock® Plus™ Overlapping Roll-out Method
Please Note: Read these instructions thoroughly before installation to ensure proper use of VaporBlock® Plus™. ASTM E 1465, ASTM E 2121 and, ASTM E 1643 also provide valuable information regarding the installation of vapor / gas barriers. When installing this product, contractors shall conform to all applicable local, state and federal regulations and laws pertaining to residential and commercial building construction.
• When VaporBlock® Plus™ gas barrier is usedas part of an active control system for radon orother gas, a ventilation system will be required.
• If designed as a passive system, it is recommended to install a ventilation system that could beconverted to an active system if needed.
Materials List:VaporBlock® Plus™ Vapor / Gas BarrierVaporSeal™* 4” Seaming TapeVaporSeal™* 12” Seaming/Repair TapeButyl Seal 2-Sided TapeVaporBoot Plus Pipe Boots 12/Box (recommended)VaporBoot Tape (optional)POUR-N-SEAL™ (optional)1” Foam Weather Stripping (optional)Mako® Screed Supports (optional)
VAPORBLOCK® PLUS™ PLACEMENT
1.1. Level and tamp or roll granular base as specified. A base for a gas-reduction system may require a 4” to 6” gas permeable layer of clean coarse aggregate as specified by your architectural or structural drawings after installation of the recommended gas collection system. In this situation, a cushion layer consisting of a non-woven geotextile fabric placed directly under VaporBlock® Plus™ will help protect the barrier from damage due to possible sharp coarse aggregate.
1.2. Unroll VaporBlock® Plus™ running the longest dimension parallel with the direction of the pour and pull open all folds to full width. (Fig. 1)
1.3. Lap VaporBlock® Plus™ over the footings and seal with VIAFLEX Butyl Seal tape at the footing-wall connection. Prime concrete surfaces, when necessary, and assure they are dry and clean prior to applying VIAFLEX Butyl Seal Tape. Apply even and firm pressure with a rubber roller. Overlap joints a minimum of 6” and seal overlap with 4” VaporSeal™ Tape. When used as a gas barrier, overlap joints a minimum of 12” and seal in-between overlap with an optional 2-sided VIAFLEX Butyl Seal Tape. Then seal with 4” VaporSeal™ Tape centered on the overlap seam. (Fig. 2)
Page 1 of 4
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1.4. Seal around all plumbing, conduit, support columns or other penetrations that come through the VaporBlock® Plus™ membrane.
1.4a. Method 1: Pipes four inches or smaller can be sealed with VIAFLEX VaporBoot Plus preformed pipe boots. VaporBoot Plus preformed pipe boots are formed in steps for 1”, 2”, 3” and 4” PVC pipe or IPS size and are sold in units of 12 per box (Fig. 3 & 5).
Pipe boots may also be fabricated from excess VaporBlock® Plus™ membrane (Fig. 4 & 6) and sealed with VaporBoot Tape or VaporSeal™ Tape (sold separately).
1.4b. Method 2: To fabricate pipe boots from VaporBlock® Plus™ excess material (see Fig. 4 & 6 for A-F):
A)Cut a square large enough to overlap 12” in all directions.
B) Mark where to cut opening on the center of the square and cut four to eight slices about 3/8” less than the diameter of the pipe.
C) Force the square over the pipe leaving the tightly stretched cut area around the bottom of the pipe with approximately a 1/2” of the boot material running vertically up the pipe. (no more than a 1/2” of stretched boot material is recommended)
D) Once boot is positioned, seal the perimeter to the membrane by
applying 2-sided VIAFLEX Butyl Seal Tape in between the two layers. Secure boot down firmly over the membrane taking care not to have any large folds or creases.
E) Use VaporBoot Tape or VaporSeal™ Tape to secure the boot to the
pipe. VaporBoot Tape (option) – fold tape in half lengthwise, remove
half of the release liner and wrap around the pipe allowing 1” extra
for overlap sealing. Peel off the second half of the release liner
and work the tape outward gradually forming a complete seal.
VaporSeal™ Tape (option) - Tape completely around pipe
overlapping the VaporBlock® Plus™ square to create a tight seal
against the pipe.
F) Complete the process by taping over the boot perimeter edge with VaporSeal™ Tape to create a monolithic membrane between the surface of the slab and gas/moisture sources below and at the slab perimeter. (Fig. 4 & 6)
Preformed Pipe Boot Square Material Pipe Boot
Fig. 3
SINGLE PENETRATION PIPE BOOT INSTALLATION
Fig. 5 Fig. 6
1. Cut a square of VaporBlock® Plus™ barrier to extend at least12” from the pipe in all directions.
2. Cut four to eight slices about 3/8”less than the diameter of the pipe.
5. Use VIAFLEX VaporBoot orVaporSeal™ Tape andoverlap 1” at the seam.
4. Tape over the bootperimeter edge withVaporSeal™ Tape.
1. Cut out one of thepreformed boot steps(1” to 4”).
2. Tape the underside bootperimeter with 2-sidedButyl Seal Tape.
3. Force the boot overpipe and press tapefirmly in place.
4. Use VaporSeal™ Tape
to secure boot to thepipe.
5. Tape around entire bootedge with VaporSeal™Tape.
VaporBoot Flexible Tapeor VaporSeal™ 4” TapeVaporSeal™ 4” Tape
VaporBlock® Plus™Material
VaporSeal™ 4” Tape
VIAFLEX Butyl Seal2-Sided Tape VIAFLEX Butyl Seal2-Sided Tape
VaporBoot PlusPreformed Boot 12”(minimum)
3. Force over pipe and tape theunderside boot perimeter toexisting barrier with 2-sidedButyl Seal Tape.
Fig. 4
Page 2 of 4
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Method 1
Method 2
VaporSeal™4” Tape VaporBoot PlusPerformed Boot
VIAFLEX Butyl Seal 2-sided Tape VIAFLEX Butyl Seal 2-sided Tape
1.5. Sealing side-by-side multiple penetrations (option 1);
A) Cut a patch large enough to overlap 12” in all directions (Fig. 7)
of penetrations.
B) Mark where to cut openings and cut four to eight slices about
3/8” less than the diameter of the penetration for each.
C)Force patch material over penetration to achieve a tight fit and
form a lip.
D) Once patch is positioned, seal the perimeter to the membrane
by applying 2-sided VIAFLEX Butyl Seal Tape in-between the two layers. (Fig. 8)
E) After applying VIAFLEX Butyl Seal Tape between the patch
and membrane, tape around each of the penetrations and the
patch with VaporSeal™ 4” tape. (Fig. 9) For additional protection
apply POUR-N-SEAL™ or an acceptable polyurethane
elastomeric sealant around the penetrations. (Fig. 10)
Fig. 7 Fig. 8
Fig. 9 Fig. 10
MULTIPLE PENETRATION PIPE BOOT INSTALLATION
Fig. 6
Cut a patch large enough to overlap 12” in all directions and slide over penetrations (Make openings as tight as possible.)
Once the overlay patch is positioned, seal the perimeter to the membrane by applying 2-sided VIAFLEX Butyl Seal Tape in-between the two layers.
After applying VIAFLEX Butyl Seal Tape between the patch and membrane, tape around the perimeter of the penetration and the patch with VaporSeal™ 4” Tape.
For additional protection apply POUR-N-SEAL™ or an acceptable polyurethane elastomeric sealant around the penetrations.
VaporSeal™ 4” Tape VaporSeal™ 4” Tape
Page 3 of 4
Option 1
VIAFLEX Butyl Seal 2-sided Tape
1.6. POUR-N-SEAL™ method of sealing side-by-side multiple penetrations (option 2);
A) Install the vapor barrier as closely as possible to pipe penetrations tominimize the amount of POUR-N-SEAL™ necessary to seal around allpenetrations.
B) Once barrier is in place, remove soil or other particles with a dry clothor a fine broom to allow for improved adhesion to the POUR-N-SEAL™ liquid.
C) Create a dam around the penetration area approximately 2” awayfrom the pipe or other vertical penetrations by removing the releaseliner from the back of a 1” weather stripping foam and adhere to thevapor barrier. Form a complete circle to contain the POUR-N-SEAL™materials (Fig. 11).
D) Once mixed, pour contents around the pipe penetrations. If needed,a brush or a flat wooden stick can be used to direct the sealantcompletely around penetrations creating a complete seal (Fig. 12-13).
E) DO NOT leave excess POUR-N-SEAL™ in plastic container for longerthan the time it takes to pour sealant.
Fig. 12 Fig. 13
Fig. 11
Option 2
VAPORBLOCK® PLUS™ REPAIR INSTRUCTIONS
1.7. Proper installation requires all holes and openings are repaired prior
to placing concrete. When patching small holes, simply cut a 12” long
piece of 12” wide VaporSeal™ tape. Remove release liner and center
over the opening. Apply pressure to create a seal (Fig. 14-15).
1.8. When installing VaporBlock® Plus™ around pipe penetrations,
vertical columns, electrical ducts and other obstructions, you will
find it necessary to cut it to the nearest outside edge. This cut can
be easily sealed with 12” wide VaporSeal™ tape, by simply centering
it over the cut, 6” on either side. Once the tape is placed correctly,
apply pressure to assure a complete seal (Fig. 16).
Reminder Note: All holes or penetrations through the membrane will need
to be patched with 12” VaporSeal™ Tape.
Fig. 14
Page 4 of 5
Fig. 15
2.1. When installing reinforcing steel and utilities, in addition to the
placement of concrete, take precaution to protect VaporBlock®
Plus™. Carelessness during installation can damage the most
puncture–resistant membrane. Sheets of plywood cushioned with
geotextile fabric temporarily placed on VaporBlock® Plus™ provide
for additional protection in high traffic areas including concrete
buggies.
2.2. Use only brick-type or chair-type reinforcing bar supports to protect
VaporBlock® Plus™ from puncture.
2.3. Avoid driving stakes through VaporBlock® Plus™. If this cannot be
avoided, each individual hole must be repaired per section 1.7.
2.4. To avoid penetrating VaporBlock® Plus™ when installing screed
supports, utilize non-penetrating support, such as the Mako®
Screed Support System (Fig. 17). Avoid driving stakes through
VaporBlock® Plus™. If this cannot be avoided, each individual hole
must be repaired per figures 14-15.
2.5. If a cushion or blotter layer is required in the design between
VaporBlock® Plus™ and the slab, additional care should be given if
sharp crushed rock is used. Washed rock will provide less chance of
damage during placement. Care must be taken to protect blotter layer
from precipitation before concrete is placed.
VaporBlock® Plus™ Gas & Moisture Barrier can be identified on site
as gold/white in color printed in black ink with following logo and
classification listing (Fig. 18)
Page 5 of 5
VaporBlock® Plus™
Gas & Moisture Barrier
VAPORBLOCK® PLUS™ PROTECTION
Fig. 16
Fig. 18
Fig. 17
*Patent Pending
Note: To the best of our knowledge, unless otherwise stated, these are typical property values and are intended as guides only, not as specification limits. Chemical resistance, odor transmission, longevity as well as other performance criteria is not implied or given and actual testing must be performed for applicability in specific applications and/or conditions. VIAFLEX MAKES NO WARRANTIES AS TO THE FITNESS FOR A SPECIFIC USE OR MERCHANTABILITY OF PRODUCTS REFERRED TO, no guarantee of satisfactory results from reliance upon contained information or recommendations and disclaims all liability for resulting loss or damage. Limited Warranty available at www.viaflex.com
VIAFLEX, INC.
821 W Algonquin Street Sioux Falls, SD 57104 Ph: [phone] • TF: [phone]© 2022 VIAFLEX, INC. All rights reserved.27-0126 09/22
[e-mail] www.viaflex.com

 

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TURBINE VENTILATORS
CONSTRUCTION SPECIFICATIONS
“A”
THROAT SIZE
GUAGE NO. OF
BRACES
BRACE
MATERIALCROWN GALV.BLADE GALV.THROAT GALV.
4 24 28 26 3 ALUMINUM
6 24 28 26 3 ALUMINUM
8 24 28 26 3 ALUMINUM
10 24 28 26 3 ALUMINUM
12 24 28 24 3 ALUMINUM
14 22 26 24 3 ALUMINUM
16 22 26 24 3 STEEL
18 22 26 24 4 STEEL
20 20 26 24 4 STEEL
24 20 26 22 4 STEEL
DIMENSIONAL AND PERFORMACE DATA
“A”
THROAT SIZE
“B”
HEIGHT
“C”
OVERALL WIDTH
EXHAUSTED
CAPACITY*
APPROX.
SHIPPING WEIGHT
4 12 10 1/4 125 5
6 14 1/2 12 3/4 147 7
8 15 14 1/4 255 8
10 16 1/4 16 1/4 425 11
12 17 19 631 13
14 19 3/4 22 3/4 700 21
16 21 3/4 25 1/2 950 31
18 24 29 1200 38
20 25 1/4 31 5/8 1700 46
24 28 1/4 35 3/4 2350 58
*4 MPH WIND CFM











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Appendix E
Field Forms and Field Data

INDOOR AIR BUILDING SURVEY
and SAMPLING FORM
Site Name: ____________________________________
Preparer’s name: ________________________________
Preparer’s affiliation: ____________________________
6LWH,'#: ______________________
Date: __________________________
Phone #: _______________________
Part I - Occupants
Building Address: ____________________________________________________________________
Property Contact: _______________________________ Owner / Renter / other: ______________
Contact’s Phone: home ( )__________ work ( )______________ cell ( )____________
# of Building occupants: Children under age 13 _____ Children age 13-18 ______ Adults _____
Part II – Building Characteristics
Building type:
Describe building: ________________________________________ Year constructed: _________
Sensitive population:2WKHU(specify): _______________
Number of floors below grade: ______
Number of floors at or above grade: ______
Depth of basement below grade surface: ______ ft. Basement size: _______ ft2
Basement floor construction: 
Foundation walls:
Basement sump present?<HV1RSumppump?<HV1R
Rther (specify): ________________
other(specify)_______________B
Water in sump?<HV1R
Type of heating system (cKHFN all that apply):hot air circulation hot air radiation wood steam radiation
heat pump hot water radiation kerosene heater electric baseboard other (specify): ________________________
Type of ventilation system (cKHFN all that apply): bathroom ventilation fans outside air intake central air conditioning mechanical fans individual air conditioning units kitchen range hood fan other (specify): _________________
Type of fuel utilized (cKHFN all that apply): Natural gas electric  fuel oil  wood  coal  solar kerosene
Are the basement walls or floor sealed with waterproof paint or epoxy coatings? <HV1R
WR
Crayton Printing / Hawkins Press BF#: 24025-20-060
Jennifer Hoang
Hart & Hickman, PC [phone]
Dunavant Street and Distribution Street
Matt Trull
704 993-8898
Mid-rise Apartment 2023
7
0 0
Multi-Family Residential
one
Concrete
Poured Concrete
other (specify) _____________
Is there a whole house fan?<HV1R
Septic system? <HV<HV%XWQRWXVHG1R
Irrigation/private well? <HV<HV%XWQRWXVHG1R
Type of ground cover outside of building:BBBBBBBBBBBBBBBBBBBBB
Existing subsurface depressurization (radon) system in place?<HV1R 7\SHBBBBBBBBBBBB
Sub-slab vapor/moisture barrier in place? <HV1R
Type of barrier: ____________________________BBBBBBBBBBBBBBB
Part III - Outside Contaminant Sources
Other stationary sources nearby (gas stations, emission stacks, etc.): _____________________________
Heavy vehicular traffic nearby (or other mobile sources): ______________________________________
Part IV – Indoor Contaminant Sources
Identify all potential indoor sources found in the building (including attached garages), the location of
the source (floor and room), and whether the item was removed from the building 48 hours prior to
indoor air sampling event. Any ventilation implemented after removal of the items should be completed
at least 24 hours prior to the commencement of the indoor air sampling event.Potential Sources Location(s)Removed (Yes / No / NA)
Gasoline storage cans
Gas-powered equipment
Kerosene storage cans
Paints / thinners / strippers
Cleaning solvents
Oven cleaners
Carpet / upholstery cleaners
Other house cleaning products
Moth balls
Polishes / waxes
Insecticides
Furniture / floor polish
Nail polish / polish remover
Hairspray
Cologne / perfume
Air fresheners
Fuel tank (inside building)
Wood stove or fireplace
New furniture / upholstery
New carpeting / flooring
Hobbies - glues, paints, etc.
Yes, at corner of an intersection
N/A
In parking deck No
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Asphalt
VIMS
Viaflex/Raven VBP-20
Part V – Miscellaneous Items
Do any occupants of the building smoke?<HV1RHow often? ______________
Last time someone smoked in the building? ____________ hours days ago
Does the building have an attached garage directly connected to living space?<HV1R
If so, is a car usually parked in the garage?<HV1R
Are gas-powered equipment or cans of gasoline/fuels stored in the garage?<HV1R
Do the occupants of the building have their clothes dry cleaned?  <HV     1R
If yes, how often?:HHNO\0RQWKO\7LPHVSHU\HDU
Do any of the occupants use solvents in work?<HV1R
If yes, what types of solvents are used? _______________________________________
If yes, are their clothes washed at work?<HV1R
+DYHDQ\SHVWLFLGHVKHUELFLGHVEHHQDSSOLHGDURXQGWKHEXLOGLQJRULQWKH\DUG"<HV1R
If so, when and which chemicals? _________________________________________________
Has there ever been a fire in the building?<HV1R If yes, when? _____________
Has painting or staining been done in the building in the last 6 months?Yes  No
If yes, when __________________ and where? ____________________________
Part VI – Sampling Information
Sample Technician: ____________________________ Phone number:) _______ - __________
Sample SourceFKHFNDOOWKDWDSSO\
,QGRRU$LU&UDZOVSDFH$LU6XE6ODE1HDU6ODE6RLO*DV([WHULRU6RLO*DV
Sampler TypeFKHFNDOOWKDWDSSO\
7HGODU%DJ6RUEHQW6WDLQOHVV6WHHO&DQLVWHUOther (specify): _________________
Analytical Method:BBBBBBBBBBBBBBBBB2ther: _____________ Cert. Laboratory:BBBBBBBBBBBBB
Sample locations (floor, room):BBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBB
Field ID # _____ - ________________________Field ID # _____B-__________________________
Field ID #BBBBBBBBBBBBBBBBBBBBBBBBBBBBBBB)LHOG,'BBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBB
Were “Instructions for Occupants” followed?
,IQRWGHVFULEHPRGLILFDWLRQVBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBB
during construction in units
Jennifer Hoang 0007586704
Pace Analytical
IAS
MP
Ground Floor Units (Western) and Mechanical and Support Rooms
2,3,4,5, DUP, BKG
3,6,8,9
TO-15
Provide Drawing of Sample Location(s) in Building
Part VII - Meteorological Conditions
Was there significant precipitation within 12 hours prior to (or during) the sampling event?Yes No
Describe the general weather conditions: _________________________________________________
_____________________________________________________________________________________
Part VIII – General Observations
Provide any information that may be pertinent to the sampling event and may assist in the data interpretation process (e.g., observed that drycleaner operated with door or windows propped open for ventilation).
(Adapted from the NJDEP Vapor Intrusion Guidance, October 2005)
Rainy, 40s on 1/6/24; Sunny, 50s on 1/7/24
Select bathroom shower drains and toilet connections sealed with vapor tape and/or filled with water.
ELEV. 720'
5.21
%

U
P
6.57%

U
P
FUTURE RESIDENT
ELEV. 723'
CYCLE CENTER RESIDENT STORAGE
RISER
MECH VENT
MECH. VENT
MECH.
DOG WASH
TRASH ROOM
ELEV. 712'
ELEV. 720'
ELEV. 719'-6"
ELEV. 718'
ELEV. 727'
ELEC.
ELEV. 717'
LOADINGZONE
ELEV. 732'
ELEV. 722'
MAINTENANCE
TRASH STAGING AREA
BIKE STORAGE
ELEC.
ELEV LOBBY
ELEV. 717'-6"
ELEV. 730'
ELEV. 727'
ELEV. 729'
MECH. VENT
MAILCENTER
720' - 3"
LEVEL 1 TRASH
MECH.
LEASING/ LOUNGE
SERVICE
ELEV. 1 ELEV. 2
STAIR E
PACKAGE
STAIR B
ELEV. 3 ELEV. 4
CORRIDOR
722' - 3"
720' - 3"
LEASING/ LOUNGE
STAIR A
LYFTWAITINGAREA
OUTDOORAMENITY
713' - 0 3/8"
720' - 3"
POOL ROOM
CHEM.
720' - 3"
4
13 10
LANAIS ABOVE
PARKING RAMP: 1
6.30%
719' - 9"
719' - 9"
719' - 9"
720' - 3"714' - 6 3/4"
717' - 4"
1" /

1
2
"
1" / 12"
1" /
1
2
"
714' - 6"714' - 6"
714' - 6"
720' - 3"
714' - 6"
717' - 9"719' - 9"
MECH
4'x8'
4'x8'
4'x8'
6.30%
6.30%
LARGESCALEWASH
719' - 9"
717' - 4"4'x8'4'x8'
1/4"

/

1
2
"
719' - 9"
717' - 9"
STAIR C
2.75%
2.10
%
0.62%
0.73
%
5.22
%
720' - 3"
721' - 3"
720' - 3"
720' - 3"
9
5
8
6
717' - 8"
720' - 3"
721' - 3"
5.21
%

U
P
5.21
%

U
P
5.21
%

U
P
6.57%

U
P
6.57%

U
P
6.57%

U
P
RISER
MECH VENTTMMT
MECH. VENTNEENMMMNTNNNNH. VCHNTN
MECH.
ELEC.
LOADINGLOAADINGZONEZOONE
BIKE STORAGEKBKBEEEEEEGEE
ELEC
MECH. VENTMMMMMMMH. VH. VMM
MAILMAILCENTERCENTER
20' 3""720' - 3"720' - 3"
LEVEL 1 TRASHASASH
MECH.H.H.H.MMMMMMMM HHHHHMH
LEASING/ LOUNGE
PACKAGE
STAIR BR
CORRIDORRORROOOOROOOOOC
STAIR A
FTFTLYFLYINGNGGWAITWAITEAAAREAAR
3' 0 3/8"'3' - 0 3/8"3' - 0 3/8"
20' - 3"720' - 3"20' 3"720' - 3"
20' - 3"720' - 3"720' 3"720' 3"720' - 3"
4
131 101
PARKING RAMP: 1PAA
.30%6.30%6.30%6.30%
720' - 3""3"3720' - 3"720' - 3"
1" / 12"1" / 12"1" / 12"
1" /
1
2
"
2"11" /
1
2
"
1" /
1
2
"
14' - 6"714' - 6"714' 6"714' - 6"14' - 6"714' - 6"714' 6"714' - 6"
4' - 6"714' - 66"6"714' - 6"714' - 6"
20' - 3"720' - 3"720' 3"3720' - 3"
14' - 6"714' - 6"714' 6"714' - 6"
7' - 9"717' - 9"717' 9"717' - 9"
6 30%6.30%6.30%
66 30%66.30%6.30%
719' 9"9719' - 9"719' - 9"
717' 9"717' - 9"717' - 9"
STAIR C
2.75%2.75%2.75%
2 10
%
2.10
%
2.10
%
0 62%%600.62%0.62%
0.73
%
%
0.73
%
0.73
%
5 22
%
%25555.22
%
5.22
%
20' - 3"720' - 3"20' 3"'3"20' 3"720' - 3"
21' - 3"721' - 3"21' 3"721' - 3"
0' - 3"720' - 3"20' 3"720' - 3"
20' - 3"720' - 3"720' 3"720' 3"720' - 3"
9
5
8
6
20' - 3"720' - 3"720' 3"720' - 3"
"""
SLOP
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SLOPEUP
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OUTDOORAMENITY
STAIR 22' - 3"722' - 3"722' 3"722' - 3"
JOB NO.AKR-005
PROPOSED
INDOORAIR ANDSUB-SLABVAPORSAMPLELOCATIONMAP -LEVEL 1
AUGUST 4, 2021
FIGURE NO. 3A
VAPOR MITIGATION PLAN PREPARED BY:
2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 Geology
ISSUED FOR CONSTRUCTION
REVISION 1
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LEGEND
SLAB GRADE CHANGE
OUTDOOR OR OPEN AIR
LEVEL 2 SLAB ON GRADE AREA
MONITORING POINT LOCATION
PROPOSED INDOOR AIR SAMPLE LOCATION
MP-4
MP-2
MP-3
MP-4
MP-6
MP-9
MP-10
MP-12
GROUNDLEVEL PORTION OFLEVEL 2 (SEE FIGURE 3B)
MP-11
MP-14
MP-5
MP-1
MP-7
MP-8
IAS-2
IAS-3
IAS-4
IAS-5
IAS-6
LEASING OFFICEAND LOUNGE
STAIRWELL C
APARTMENTS
MECHANICAL ANDSUPPORT ROOMS
PACKAGE STORAGE ROOM
PARKINGGARAGE
APARTMENTS
ELEVATORS 1 & 2STAIRWELL A
ELEVATORS 3 & 4
STAIRWELL B
STAIRWELL E
IAS-1
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Form IAS‐1
Indoor Air Sampling Field Form
Project No.:___________________ Sampler:______________________ Weather:____________________________________________________________
Date
Proposed
Sampling
Duration
Time Canister
Pressure
Differential
Pressure
Outdoor
Temperature
Outdoor
Humidity
Indoor
Temperature
Indoor
Humidity
mm/dd/yy Hours 24-hr " Hg " H2O oF %oF %
S:Beginning
C:Middle
R:    End
S:Beginning
C:Middle
R:    End
S:Beginning
C:Middle
R:    End
S:Beginning
C:Middle
R:    End
S:Beginning
C:Middle
R:    End
S:Beginning
C:Middle
R:    End
S = sample ID; C = canister ID; R = regulator ID Note: negative differential pressure indicates that indoor pressure was lower than pressure outdoors.Last updated: 6/18/2020
" Hg = inches of mercury; " H2O = inches of water column
Time (EST)Notes:____________________________________________
Precipitation (inches) ____________________________________________
Barometric Pressure (" Hg) ____________________________________________
Wind Direction ____________________________________________
Wind Speed (mph) ____________________________________________
          Size:
Flow Rate:
          Size:
Flow Rate:
          Size:
Flow Rate:
          Size:
Flow Rate:
Indoor Parameters
Sampling
Period
Sampling Information Outdoor Parameters
Sample ID
          Size:
Flow Rate:
          Size:
Flow Rate:
C:\Users\mvawter\Dropbox\yOther\Form Edits\IAQ‐SSV\Vapor Sampling Forms_V6.0
Indoor Air  Sampling Field Form
Hart & Hickman, PC
Form SV‐1
Sub-Slab / Soil Gas Vapor Installation Field Form
Project No.:_________________ Sampler:_____________________Weather:____________________________________________________________
Surface
Material
Slab
Thickness (if
appl.)
Material Below
Slab
(if appl.)
Depth of
Screen
(if appl.)
Type Date & Time Ambient
Temp.Purge Method Volume
Purged
Shroud
Helium
Conc.
Purge
Helium Conc.
Leak Test
Pass?
(see note)
SS, SG Perm.,
Temp.
Concrete, soil,
gravel, asphalt Inches Gravel, sand,
clay, etc.ft bgs Full sample train or
point-only
mm/dd/yy
24-hr oF Syringe, pump
Liters
(see notes
for calc.)
%
% or ppm
(indicate units
below)
Yes / No
S:
C:
R:
S:
C:
R:
S:
C:
R:
S:
C:
R:
S:
C:
R:
S:
C:
R:
S = sample ID; C = canister ID; R = regulator ID; SS = sub-slab; SG = soil gas; Perm = permanent; Temp = temporary; Volume Purged = x3 purge volumes = 3*L*a Last updated: 4/21/2022
" Hg = inches of mercury; ppm = parts per million
Notes:___________________________________________________
___________________________________________________
___________________________________________________
___________________________________________________
Sample ID Type
Vapor Monitoring Point Construction Helium Leak Test
Note: Leak Test Requirements
Per NC DEQ DWM Vapor Intrusion Guidance, leak test passes if helium 
concentration in purge air is less than 10% of helium concentration in 
shroud. 
L = length of tubing/pipe (ft)
a = 0.163 for 2" diameter (L/ft)
a = 0.010 for 0.25" diameter (L/ft)
C:\Users\mvawter\Dropbox\yOther\Form Edits\IAQ‐SSV\Vapor Sampling Forms_V6.0
Sub‐Slab / Soil Gas Sampling Vapor Installation Field Form
Hart & Hickman, PC
Form SV‐2
Sub-Slab / Soil Gas Vapor Sampling Field Form
Project No.:___________________ Sampler:______________________ Weather:____________________________________________________________
Date
Proposed
Sampling
Duration
Time Canister
Pressure
Outdoor
Temperature
Outdoor
Humidity
Indoor
Temperature
Indoor
Humidity
mm/dd/yy Minutes 24-hr " Hg oF %oF %
S:Beginning
C:Middle
R:    End
S:Beginning
C:Middle
R:    End
S:Beginning
C:Middle
R:    End
S:Beginning
C:Middle
R:    End
S:Beginning
C:Middle
R:    End
S:Beginning
C:Middle
R:    End
S = sample ID; C = canister ID; R = regulator ID; SS = sub-slab; SG = soil gas; Perm = permanent; Temp = temporary Last updated: 6/18/2020
" Hg = inches of mercury
Notes:________________________________________________
_______________________________________________
_______________________________________________
_______________________________________________
_______________________________________________
          Size:
Flow Rate:
          Size:
Flow Rate:
Sample ID
          Size:
Flow Rate:
          Size:
Flow Rate:
          Size:
Flow Rate:
          Size:
Flow Rate:
Sampling Information Indoor ParametersOutdoor Parameters
Sampling
Period
Note: 
Per NC DEQ DWM Vapor Intrusion Guidance, 
shut‐in test and helium leak check must be 
passed before sampling.
C:\Users\mvawter\Dropbox\yOther\Form Edits\IAQ‐SSV\Vapor Sampling Forms_V6.0
Sub‐Slab / Soil Gas Sampling Vapor Sampling Field Form
Hart & Hickman, PC
Category Example Criteria
Proper gravel base layer and thickness
Proper placement, type, and pitch of VIMS vent piping
Proper placement, type, and pitch of monitoring points
Correct vapor barrier type
Proper vapor barrier overlap and seals around penetrations per
manufacturer instructions
elevators, etc.)
Good condition of vapor barrier
Riser pipe material and fitting connections
Proper pitch towards sub-slab (gravity drain)
Appropriate VIMS labels
Correct ventilator
Fan/ventilator function
Proper fittings and protection
Appropriate VIMS labels
Proper distance from roof intakes and parapets
Pilot test completed
Monitoring points finished and accessible
Vapor Intrusion Mitigation System - Inspection Checklist
Proper Installation
(Initial below)
Site Name and H&H Project #: Crayton Printing (AKR.005)
DEQ Brownfields ID: 24025-20-060
Building/Area ID: Level 1 - Western Section
Start Date and End Date: May 2022 - March 2024
H&H Construction Manager: Joseph Gentilcore IV (JCG) & Trinh DeSa (TCD)
Sub-Slab
Vapor Barrier
Vent Riser Piping
JCG
JCG
JCG
JCG
JCG
pending
Pilot Test / Checkout
JCG
JCG
JCG
JCG
JCG
JCG
JCG
Ventilators
JCG
JCG
JCG
JCG
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Akridge/AKR.005 Dunavant Brownfields Assessment/VIMS install report/Field forms/inspection checkilist\Template

Appendix F
Laboratory Analytical Reports

39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
January 12, 2024
Trinh Desa
Hart & Hickman - Charlotte, NC
2923 South Tryon Street, Suite 100
Charlotte, NC 28203
Project Location: Charlotte, NC
Client Job Number:
Project Number: AKR-005
Laboratory Work Order Number: 24A0806
Enclosed are results of analyses for samples as received by the laboratory on January 9, 2024. If you have any questions
concerning this report, please feel free to contact me.
Sincerely,
Rebecca Faust
Project Manager
QA Officer
Katherine Allen
Laboratory Manager
Daren Damboragian
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL SUMMARY
1/12/2024Hart & Hickman - Charlotte, NC
2923 South Tryon Street, Suite 100
Charlotte, NC 28203
ATTN: Trinh Desa
AKR-005
24A0806
The results of analyses performed on the following samples submitted to Con-Test, a Pace Analytical Laboratory, are found in this report.
PROJECT LOCATION:
PURCHASE ORDER NUMBER:
PROJECT NUMBER:
REPORT DATE:
WORK ORDER NUMBER:
FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB
Charlotte, NC
MP-3 24A0806-07 Sub Slab EPA TO-15
MP-6 24A0806-08 Sub Slab EPA TO-15
MP-8 24A0806-09 Sub Slab EPA TO-15
MP-9 24A0806-10 Sub Slab EPA TO-15
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CASE NARRATIVE SUMMARY
All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report.
EPA TO-15
Qualifications:
Laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this compound is likely to be
biased on the low side.
Analyte & Samples(s) Qualified:
L-03
1,2,4-Trichlorobenzene, Hexachlorobutadiene, Naphthalene
24A0806-07[MP-3], 24A0806-08[MP-6], 24A0806-09[MP-8], 24A0806-10[MP-9], B363185-BLK1, B363185-BS1
Elevated reporting limit due to high concentration of target compounds.
Analyte & Samples(s) Qualified:
RL-11
24A0806-08[MP-6], 24A0806-09[MP-8], 24A0806-10[MP-9]
The results of analyses reported only relate to samples submitted to Con-Test, a Pace Analytical Laboratory, for testing.
I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed
in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the
best of my knowledge and belief, accurate and complete.
Lisa A. Worthington
Technical Representative
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL RESULTS
Project Location: Charlotte, NC
Date Received: 1/9/2024
Work Order: 24A0806Sample Description/Location:
Field Sample #: MP-3
Sample ID: 24A0806-07
Sample Matrix: Sub Slab
Initial Vacuum(in Hg): -30
Final Vacuum(in Hg): -5
Receipt Vacuum(in Hg): -2.3
Sampled: 1/7/2024 13:45
Canister ID: 2850
Flow Controller ID: 4544
Sub Description/Location:
Canister Size: 1 liter
Flow Controller Type: Fixed-Orifice
Flow Controller Calibration
RPD Pre and Post-Sampling:
Sample Type: 10 min
RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
EPA TO-15
ppbv ug/m3
MDL MDL
Acetone 12 8.0 1/11/24 21:20 KMC28 4191.9 4.5
Benzene 0.084 0.20 1/11/24 21:20 KMCJ0.27 40.640.062 0.20
Benzyl chloride ND 0.20 1/11/24 21:20 KMCND41.00.11 0.56
Bromodichloromethane ND 0.20 1/11/24 21:20 KMCND41.30.054 0.36
Bromoform ND 0.20 1/11/24 21:20 KMCND42.10.071 0.73
Bromomethane ND 0.20 1/11/24 21:20 KMCND40.780.11 0.41
1,3-Butadiene 1.3 0.20 1/11/24 21:20 KMC2.9 40.440.17 0.37
2-Butanone (MEK)9.0 8.0 1/11/24 21:20 KMC27 4242.2 6.6
Carbon Disulfide ND 2.0 1/11/24 21:20 KMCND46.20.38 1.2
Carbon Tetrachloride 0.088 0.20 1/11/24 21:20 KMCJ0.55 41.30.058 0.36
Chlorobenzene ND 0.20 1/11/24 21:20 KMCND40.920.050 0.23
Chloroethane ND 0.20 1/11/24 21:20 KMCND40.530.13 0.33
Chloroform 0.056 0.20 1/11/24 21:20 KMCJ0.27 40.980.052 0.25
Chloromethane 0.33 0.40 1/11/24 21:20 KMCJ0.68 40.830.082 0.17
Cyclohexane ND 0.20 1/11/24 21:20 KMCND40.690.088 0.30
Dibromochloromethane ND 0.20 1/11/24 21:20 KMCND41.70.054 0.46
1,2-Dibromoethane (EDB)ND 0.20 1/11/24 21:20 KMCND41.50.067 0.51
1,2-Dichlorobenzene ND 0.20 1/11/24 21:20 KMCND41.20.070 0.42
1,3-Dichlorobenzene ND 0.20 1/11/24 21:20 KMCND41.20.074 0.45
1,4-Dichlorobenzene ND 0.20 1/11/24 21:20 KMCND41.20.074 0.44
Dichlorodifluoromethane (Freon 12)0.55 0.20 1/11/24 21:20 KMC2.7 40.990.084 0.42
1,1-Dichloroethane ND 0.20 1/11/24 21:20 KMCND40.810.064 0.26
1,2-Dichloroethane ND 0.20 1/11/24 21:20 KMCND40.810.075 0.30
1,1-Dichloroethylene ND 0.20 1/11/24 21:20 KMCND40.790.057 0.23
cis-1,2-Dichloroethylene ND 0.20 1/11/24 21:20 KMCND40.790.062 0.24
trans-1,2-Dichloroethylene ND 0.20 1/11/24 21:20 KMCND40.790.065 0.26
1,2-Dichloropropane ND 0.20 1/11/24 21:20 KMCND40.920.055 0.25
cis-1,3-Dichloropropene ND 0.20 1/11/24 21:20 KMCND40.910.090 0.41
trans-1,3-Dichloropropene ND 0.20 1/11/24 21:20 KMCND40.910.10 0.47
1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 1/11/24 21:20 KMCND41.40.080 0.56
1,4-Dioxane ND 2.0 1/11/24 21:20 KMCND47.20.98 3.5
Ethanol 6.6 8.0 1/11/24 21:20 KMCJ12 4155.3 10.0
Ethyl Acetate ND 2.0 1/11/24 21:20 KMCND47.20.58 2.1
Ethylbenzene 0.088 0.20 1/11/24 21:20 KMCJ0.38 40.870.058 0.25
4-Ethyltoluene ND 0.20 1/11/24 21:20 KMCND40.980.087 0.43
Heptane ND 0.20 1/11/24 21:20 KMCND40.820.13 0.52
Hexachlorobutadiene ND 0.20 1/11/24 21:20 KMCL-03 ND 42.10.12 1.2
Hexane ND 8.0 1/11/24 21:20 KMCND4282.6 9.3
2-Hexanone (MBK)ND 0.20 1/11/24 21:20 KMCND40.820.087 0.35
Isopropanol 11 8.0 1/11/24 21:20 KMC26 4202.5 6.2
Methyl tert-Butyl Ether (MTBE)ND 0.20 1/11/24 21:20 KMCND40.720.098 0.35
Methylene Chloride ND 2.0 1/11/24 21:20 KMCND46.90.54 1.9
4-Methyl-2-pentanone (MIBK)ND 0.20 1/11/24 21:20 KMCND40.820.11 0.43
Naphthalene ND 0.20 1/11/24 21:20 KMCL-03 ND 41.00.13 0.70
Propene ND 8.0 1/11/24 21:20 KMCND4142.2 3.7
Styrene ND 0.20 1/11/24 21:20 KMCND40.850.11 0.46
1,1,2,2-Tetrachloroethane ND 0.20 1/11/24 21:20 KMCND41.40.050 0.34
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL RESULTS
Project Location: Charlotte, NC
Date Received: 1/9/2024
Work Order: 24A0806Sample Description/Location:
Field Sample #: MP-3
Sample ID: 24A0806-07
Sample Matrix: Sub Slab
Initial Vacuum(in Hg): -30
Final Vacuum(in Hg): -5
Receipt Vacuum(in Hg): -2.3
Sampled: 1/7/2024 13:45
Canister ID: 2850
Flow Controller ID: 4544
Sub Description/Location:
Canister Size: 1 liter
Flow Controller Type: Fixed-Orifice
Flow Controller Calibration
RPD Pre and Post-Sampling:
Sample Type: 10 min
RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
EPA TO-15
ppbv ug/m3
MDL MDL
Tetrachloroethylene ND 0.20 1/11/24 21:20 KMCND41.40.075 0.51
Tetrahydrofuran 7.9 2.0 1/11/24 21:20 KMC23 45.90.41 1.2
Toluene 0.28 0.20 1/11/24 21:20 KMC1.0 40.750.073 0.27
1,2,4-Trichlorobenzene ND 0.20 1/11/24 21:20 KMCL-03 ND 41.50.11 0.80
1,1,1-Trichloroethane ND 0.20 1/11/24 21:20 KMCND41.10.063 0.34
1,1,2-Trichloroethane ND 0.20 1/11/24 21:20 KMCND41.10.051 0.28
Trichloroethylene ND 0.20 1/11/24 21:20 KMCND41.10.082 0.44
Trichlorofluoromethane (Freon 11)0.27 0.80 1/11/24 21:20 KMCJ1.5 44.50.082 0.46
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 1/11/24 21:20 KMCND46.10.044 0.34
1,2,4-Trimethylbenzene 0.20 0.20 1/11/24 21:20 KMC0.98 40.980.092 0.45
1,3,5-Trimethylbenzene ND 0.20 1/11/24 21:20 KMCND40.980.10 0.51
Vinyl Acetate ND 4.0 1/11/24 21:20 KMCND4140.71 2.5
Vinyl Chloride ND 0.20 1/11/24 21:20 KMCND40.510.091 0.23
m&p-Xylene 0.23 0.40 1/11/24 21:20 KMCJ1.0 41.70.14 0.61
o-Xylene 0.14 0.20 1/11/24 21:20 KMCJ0.59 40.870.073 0.32
Surrogates % Recovery % REC Limits
4-Bromofluorobenzene (1)99.9 1/11/24 21:2070-130
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL RESULTS
Project Location: Charlotte, NC
Date Received: 1/9/2024
Work Order: 24A0806Sample Description/Location:
Field Sample #: MP-6
Sample ID: 24A0806-08
Sample Matrix: Sub Slab
Initial Vacuum(in Hg): -28
Final Vacuum(in Hg): -5
Receipt Vacuum(in Hg): -4.4
Sampled: 1/7/2024 11:46
Canister ID: 2667
Flow Controller ID: 4537
Sub Description/Location:
Canister Size: 1 liter
Flow Controller Type: Fixed-Orifice
Flow Controller Calibration
RPD Pre and Post-Sampling:
Sample Type: 10 min
RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
EPA TO-15
ppbv ug/m3
Sample Flags: RL-11
MDL MDL
Acetone 4800 600 1/11/24 22:44 KMC11000 3001400140340
Benzene ND 15 1/11/24 22:44 KMCND300484.6 15
Benzyl chloride ND 15 1/11/24 22:44 KMCND300788.1 42
Bromodichloromethane ND 15 1/11/24 22:44 KMCND3001004.1 27
Bromoform ND 15 1/11/24 22:44 KMCND3001605.3 55
Bromomethane ND 15 1/11/24 22:44 KMCND300588.0 31
1,3-Butadiene ND 15 1/11/24 22:44 KMCND300331328
2-Butanone (MEK)940 600 1/11/24 22:44 KMC2800 3001800170500
Carbon Disulfide ND 150 1/11/24 22:44 KMCND3004702989
Carbon Tetrachloride ND 15 1/11/24 22:44 KMCND300944.3 27
Chlorobenzene ND 15 1/11/24 22:44 KMCND300693.8 17
Chloroethane ND 15 1/11/24 22:44 KMCND300409.5 25
Chloroform ND 15 1/11/24 22:44 KMCND300733.9 19
Chloromethane ND 30 1/11/24 22:44 KMCND300626.1 13
Cyclohexane ND 15 1/11/24 22:44 KMCND300526.6 23
Dibromochloromethane ND 15 1/11/24 22:44 KMCND3001304.0 34
1,2-Dibromoethane (EDB)ND 15 1/11/24 22:44 KMCND3001205.0 38
1,2-Dichlorobenzene ND 15 1/11/24 22:44 KMCND300905.2 32
1,3-Dichlorobenzene ND 15 1/11/24 22:44 KMCND300905.6 33
1,4-Dichlorobenzene ND 15 1/11/24 22:44 KMCND300905.5 33
Dichlorodifluoromethane (Freon 12)ND 15 1/11/24 22:44 KMCND300746.3 31
1,1-Dichloroethane ND 15 1/11/24 22:44 KMCND300614.8 19
1,2-Dichloroethane ND 15 1/11/24 22:44 KMCND300615.6 23
1,1-Dichloroethylene ND 15 1/11/24 22:44 KMCND300594.3 17
cis-1,2-Dichloroethylene ND 15 1/11/24 22:44 KMCND300594.6 18
trans-1,2-Dichloroethylene ND 15 1/11/24 22:44 KMCND300594.9 19
1,2-Dichloropropane ND 15 1/11/24 22:44 KMCND300694.1 19
cis-1,3-Dichloropropene ND 15 1/11/24 22:44 KMCND300686.7 30
trans-1,3-Dichloropropene ND 15 1/11/24 22:44 KMCND300687.7 35
1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 15 1/11/24 22:44 KMCND3001006.0 42
1,4-Dioxane ND 150 1/11/24 22:44 KMCND30054074270
Ethanol ND 600 1/11/24 22:44 KMCND3001100400750
Ethyl Acetate ND 150 1/11/24 22:44 KMCND30054043160
Ethylbenzene ND 15 1/11/24 22:44 KMCND300654.4 19
4-Ethyltoluene ND 15 1/11/24 22:44 KMCND300746.5 32
Heptane ND 15 1/11/24 22:44 KMCND300619.5 39
Hexachlorobutadiene ND 15 1/11/24 22:44 KMCL-03 ND 3001608.6 92
Hexane ND 600 1/11/24 22:44 KMCND3002100200700
2-Hexanone (MBK)ND 15 1/11/24 22:44 KMCND300616.5 27
Isopropanol ND 600 1/11/24 22:44 KMCND3001500190470
Methyl tert-Butyl Ether (MTBE)ND 15 1/11/24 22:44 KMCND300547.4 27
Methylene Chloride ND 150 1/11/24 22:44 KMCND30052040140
4-Methyl-2-pentanone (MIBK)ND 15 1/11/24 22:44 KMCND300617.9 33
Naphthalene ND 15 1/11/24 22:44 KMCL-03 ND 300791053
Propene ND 600 1/11/24 22:44 KMCND3001000160280
Styrene ND 15 1/11/24 22:44 KMCND300648.0 34
1,1,2,2-Tetrachloroethane ND 15 1/11/24 22:44 KMCND3001003.7 25
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL RESULTS
Project Location: Charlotte, NC
Date Received: 1/9/2024
Work Order: 24A0806Sample Description/Location:
Field Sample #: MP-6
Sample ID: 24A0806-08
Sample Matrix: Sub Slab
Initial Vacuum(in Hg): -28
Final Vacuum(in Hg): -5
Receipt Vacuum(in Hg): -4.4
Sampled: 1/7/2024 11:46
Canister ID: 2667
Flow Controller ID: 4537
Sub Description/Location:
Canister Size: 1 liter
Flow Controller Type: Fixed-Orifice
Flow Controller Calibration
RPD Pre and Post-Sampling:
Sample Type: 10 min
RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
EPA TO-15
ppbv ug/m3
Sample Flags: RL-11
MDL MDL
Tetrachloroethylene ND 15 1/11/24 22:44 KMCND3001005.6 38
Tetrahydrofuran 4500 150 1/11/24 22:44 KMC13000 3004403191
Toluene ND 15 1/11/24 22:44 KMCND300575.5 21
1,2,4-Trichlorobenzene ND 15 1/11/24 22:44 KMCL-03 ND 3001108.1 60
1,1,1-Trichloroethane ND 15 1/11/24 22:44 KMCND300824.7 26
1,1,2-Trichloroethane ND 15 1/11/24 22:44 KMCND300823.8 21
Trichloroethylene ND 15 1/11/24 22:44 KMCND300816.1 33
Trichlorofluoromethane (Freon 11)ND 60 1/11/24 22:44 KMCND3003406.1 35
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 60 1/11/24 22:44 KMCND3004603.3 25
1,2,4-Trimethylbenzene ND 15 1/11/24 22:44 KMCND300746.9 34
1,3,5-Trimethylbenzene ND 15 1/11/24 22:44 KMCND300747.7 38
Vinyl Acetate ND 300 1/11/24 22:44 KMCND300110054190
Vinyl Chloride ND 15 1/11/24 22:44 KMCND300386.8 17
m&p-Xylene ND 30 1/11/24 22:44 KMCND3001301146
o-Xylene ND 15 1/11/24 22:44 KMCND300655.5 24
Surrogates % Recovery % REC Limits
4-Bromofluorobenzene (1)98.7 1/11/24 22:4470-130
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL RESULTS
Project Location: Charlotte, NC
Date Received: 1/9/2024
Work Order: 24A0806Sample Description/Location:
Field Sample #: MP-8
Sample ID: 24A0806-09
Sample Matrix: Sub Slab
Initial Vacuum(in Hg): -28
Final Vacuum(in Hg): -5
Receipt Vacuum(in Hg): -3.0
Sampled: 1/7/2024 12:24
Canister ID: 2877
Flow Controller ID: 4536
Sub Description/Location:
Canister Size: 1 liter
Flow Controller Type: Fixed-Orifice
Flow Controller Calibration
RPD Pre and Post-Sampling:
Sample Type: 10 min
RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
EPA TO-15
ppbv ug/m3
Sample Flags: RL-11
MDL MDL
Acetone 5800 1200 1/11/24 23:38 KMC14000 6002900280670
Benzene ND 30 1/11/24 23:38 KMCND600969.3 30
Benzyl chloride ND 30 1/11/24 23:38 KMCND6001601683
Bromodichloromethane ND 30 1/11/24 23:38 KMCND6002008.2 55
Bromoform ND 30 1/11/24 23:38 KMCND60031011110
Bromomethane ND 30 1/11/24 23:38 KMCND6001201662
1,3-Butadiene ND 30 1/11/24 23:38 KMCND600662556
2-Butanone (MEK)2100 1200 1/11/24 23:38 KMC6100 6003500340990
Carbon Disulfide ND 300 1/11/24 23:38 KMCND60093057180
Carbon Tetrachloride ND 30 1/11/24 23:38 KMCND6001908.6 54
Chlorobenzene ND 30 1/11/24 23:38 KMCND6001407.5 35
Chloroethane ND 30 1/11/24 23:38 KMCND600791950
Chloroform ND 30 1/11/24 23:38 KMCND6001507.8 38
Chloromethane 14 60 1/11/24 23:38 KMCJ28 6001201225
Cyclohexane ND 30 1/11/24 23:38 KMCND6001001346
Dibromochloromethane ND 30 1/11/24 23:38 KMCND6002608.1 69
1,2-Dibromoethane (EDB)ND 30 1/11/24 23:38 KMCND6002301077
1,2-Dichlorobenzene ND 30 1/11/24 23:38 KMCND6001801063
1,3-Dichlorobenzene ND 30 1/11/24 23:38 KMCND6001801167
1,4-Dichlorobenzene ND 30 1/11/24 23:38 KMCND6001801167
Dichlorodifluoromethane (Freon 12)16 30 1/11/24 23:38 KMCJ80 6001501362
1,1-Dichloroethane ND 30 1/11/24 23:38 KMCND6001209.6 39
1,2-Dichloroethane ND 30 1/11/24 23:38 KMCND6001201146
1,1-Dichloroethylene ND 30 1/11/24 23:38 KMCND6001208.6 34
cis-1,2-Dichloroethylene ND 30 1/11/24 23:38 KMCND6001209.3 37
trans-1,2-Dichloroethylene ND 30 1/11/24 23:38 KMCND6001209.8 39
1,2-Dichloropropane ND 30 1/11/24 23:38 KMCND6001408.2 38
cis-1,3-Dichloropropene ND 30 1/11/24 23:38 KMCND6001401361
trans-1,3-Dichloropropene ND 30 1/11/24 23:38 KMCND6001401570
1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 30 1/11/24 23:38 KMCND6002101284
1,4-Dioxane ND 300 1/11/24 23:38 KMCND6001100150530
Ethanol ND 1200 1/11/24 23:38 KMCND60023008001500
Ethyl Acetate ND 300 1/11/24 23:38 KMCND600110087310
Ethylbenzene ND 30 1/11/24 23:38 KMCND6001308.8 38
4-Ethyltoluene ND 30 1/11/24 23:38 KMCND6001501364
Heptane ND 30 1/11/24 23:38 KMCND6001201978
Hexachlorobutadiene ND 30 1/11/24 23:38 KMCL-03 ND 60032017180
Hexane ND 1200 1/11/24 23:38 KMCND60042004001400
2-Hexanone (MBK)ND 30 1/11/24 23:38 KMCND6001201353
Isopropanol ND 1200 1/11/24 23:38 KMCND6002900380940
Methyl tert-Butyl Ether (MTBE)ND 30 1/11/24 23:38 KMCND6001101553
Methylene Chloride ND 300 1/11/24 23:38 KMCND600100081280
4-Methyl-2-pentanone (MIBK)ND 30 1/11/24 23:38 KMCND6001201665
Naphthalene ND 30 1/11/24 23:38 KMCL-03 ND 60016020110
Propene ND 1200 1/11/24 23:38 KMCND6002100320560
Styrene ND 30 1/11/24 23:38 KMCND6001301668
1,1,2,2-Tetrachloroethane ND 30 1/11/24 23:38 KMCND6002107.4 51
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL RESULTS
Project Location: Charlotte, NC
Date Received: 1/9/2024
Work Order: 24A0806Sample Description/Location:
Field Sample #: MP-8
Sample ID: 24A0806-09
Sample Matrix: Sub Slab
Initial Vacuum(in Hg): -28
Final Vacuum(in Hg): -5
Receipt Vacuum(in Hg): -3.0
Sampled: 1/7/2024 12:24
Canister ID: 2877
Flow Controller ID: 4536
Sub Description/Location:
Canister Size: 1 liter
Flow Controller Type: Fixed-Orifice
Flow Controller Calibration
RPD Pre and Post-Sampling:
Sample Type: 10 min
RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
EPA TO-15
ppbv ug/m3
Sample Flags: RL-11
MDL MDL
Tetrachloroethylene ND 30 1/11/24 23:38 KMCND6002001176
Tetrahydrofuran 10000 300 1/11/24 23:38 KMC30000 60088062180
Toluene ND 30 1/11/24 23:38 KMCND6001101141
1,2,4-Trichlorobenzene ND 30 1/11/24 23:38 KMCL-03 ND 60022016120
1,1,1-Trichloroethane ND 30 1/11/24 23:38 KMCND6001609.4 51
1,1,2-Trichloroethane ND 30 1/11/24 23:38 KMCND6001607.7 42
Trichloroethylene ND 30 1/11/24 23:38 KMCND6001601266
Trichlorofluoromethane (Freon 11)ND 120 1/11/24 23:38 KMCND6006701269
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 120 1/11/24 23:38 KMCND6009206.6 51
1,2,4-Trimethylbenzene ND 30 1/11/24 23:38 KMCND6001501468
1,3,5-Trimethylbenzene ND 30 1/11/24 23:38 KMCND6001501576
Vinyl Acetate ND 600 1/11/24 23:38 KMCND6002100110380
Vinyl Chloride ND 30 1/11/24 23:38 KMCND600771435
m&p-Xylene ND 60 1/11/24 23:38 KMCND6002602191
o-Xylene ND 30 1/11/24 23:38 KMCND6001301148
Surrogates % Recovery % REC Limits
4-Bromofluorobenzene (1)96.2 1/11/24 23:3870-130
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL RESULTS
Project Location: Charlotte, NC
Date Received: 1/9/2024
Work Order: 24A0806Sample Description/Location:
Field Sample #: MP-9
Sample ID: 24A0806-10
Sample Matrix: Sub Slab
Initial Vacuum(in Hg): -27.5
Final Vacuum(in Hg): -5
Receipt Vacuum(in Hg): -4.3
Sampled: 1/7/2024 13:04
Canister ID: 2885
Flow Controller ID: 4543
Sub Description/Location:
Canister Size: 1 liter
Flow Controller Type: Fixed-Orifice
Flow Controller Calibration
RPD Pre and Post-Sampling:
Sample Type: 10 min
RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
EPA TO-15
ppbv ug/m3
Sample Flags: RL-11
MDL MDL
Acetone 1000 60 1/11/24 21:46 KMC2500 301401434
Benzene ND 1.5 1/11/24 21:46 KMCND304.80.46 1.5
Benzyl chloride ND 1.5 1/11/24 21:46 KMCND307.80.81 4.2
Bromodichloromethane ND 1.5 1/11/24 21:46 KMCND30100.41 2.7
Bromoform ND 1.5 1/11/24 21:46 KMCND30160.53 5.5
Bromomethane ND 1.5 1/11/24 21:46 KMCND305.80.80 3.1
1,3-Butadiene ND 1.5 1/11/24 21:46 KMCND303.31.3 2.8
2-Butanone (MEK)240 60 1/11/24 21:46 KMC690 301801750
Carbon Disulfide ND 15 1/11/24 21:46 KMCND30472.9 8.9
Carbon Tetrachloride ND 1.5 1/11/24 21:46 KMCND309.40.43 2.7
Chlorobenzene ND 1.5 1/11/24 21:46 KMCND306.90.38 1.7
Chloroethane ND 1.5 1/11/24 21:46 KMCND304.00.95 2.5
Chloroform ND 1.5 1/11/24 21:46 KMCND307.30.39 1.9
Chloromethane ND 3.0 1/11/24 21:46 KMCND306.20.61 1.3
Cyclohexane ND 1.5 1/11/24 21:46 KMCND305.20.66 2.3
Dibromochloromethane ND 1.5 1/11/24 21:46 KMCND30130.40 3.4
1,2-Dibromoethane (EDB)ND 1.5 1/11/24 21:46 KMCND30120.50 3.8
1,2-Dichlorobenzene ND 1.5 1/11/24 21:46 KMCND309.00.52 3.2
1,3-Dichlorobenzene ND 1.5 1/11/24 21:46 KMCND309.00.56 3.3
1,4-Dichlorobenzene ND 1.5 1/11/24 21:46 KMCND309.00.55 3.3
Dichlorodifluoromethane (Freon 12)0.72 1.5 1/11/24 21:46 KMCJ3.6 307.40.63 3.1
1,1-Dichloroethane ND 1.5 1/11/24 21:46 KMCND306.10.48 1.9
1,2-Dichloroethane ND 1.5 1/11/24 21:46 KMCND306.10.56 2.3
1,1-Dichloroethylene ND 1.5 1/11/24 21:46 KMCND305.90.43 1.7
cis-1,2-Dichloroethylene ND 1.5 1/11/24 21:46 KMCND305.90.46 1.8
trans-1,2-Dichloroethylene ND 1.5 1/11/24 21:46 KMCND305.90.49 1.9
1,2-Dichloropropane ND 1.5 1/11/24 21:46 KMCND306.90.41 1.9
cis-1,3-Dichloropropene ND 1.5 1/11/24 21:46 KMCND306.80.67 3.0
trans-1,3-Dichloropropene ND 1.5 1/11/24 21:46 KMCND306.80.77 3.5
1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 1.5 1/11/24 21:46 KMCND30100.60 4.2
1,4-Dioxane ND 15 1/11/24 21:46 KMCND30547.4 27
Ethanol ND 60 1/11/24 21:46 KMCND301104075
Ethyl Acetate ND 15 1/11/24 21:46 KMCND30544.3 16
Ethylbenzene ND 1.5 1/11/24 21:46 KMCND306.50.44 1.9
4-Ethyltoluene ND 1.5 1/11/24 21:46 KMCND307.40.65 3.2
Heptane ND 1.5 1/11/24 21:46 KMCND306.10.95 3.9
Hexachlorobutadiene ND 1.5 1/11/24 21:46 KMCL-03 ND 30160.86 9.2
Hexane ND 60 1/11/24 21:46 KMCND302102070
2-Hexanone (MBK)ND 1.5 1/11/24 21:46 KMCND306.10.65 2.7
Isopropanol ND 60 1/11/24 21:46 KMCND301501947
Methyl tert-Butyl Ether (MTBE)ND 1.5 1/11/24 21:46 KMCND305.40.74 2.7
Methylene Chloride ND 15 1/11/24 21:46 KMCND30524.0 14
4-Methyl-2-pentanone (MIBK)ND 1.5 1/11/24 21:46 KMCND306.10.79 3.3
Naphthalene ND 1.5 1/11/24 21:46 KMCL-03 ND 307.91.0 5.3
Propene ND 60 1/11/24 21:46 KMCND301001628
Styrene ND 1.5 1/11/24 21:46 KMCND306.40.80 3.4
1,1,2,2-Tetrachloroethane ND 1.5 1/11/24 21:46 KMCND30100.37 2.5
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL RESULTS
Project Location: Charlotte, NC
Date Received: 1/9/2024
Work Order: 24A0806Sample Description/Location:
Field Sample #: MP-9
Sample ID: 24A0806-10
Sample Matrix: Sub Slab
Initial Vacuum(in Hg): -27.5
Final Vacuum(in Hg): -5
Receipt Vacuum(in Hg): -4.3
Sampled: 1/7/2024 13:04
Canister ID: 2885
Flow Controller ID: 4543
Sub Description/Location:
Canister Size: 1 liter
Flow Controller Type: Fixed-Orifice
Flow Controller Calibration
RPD Pre and Post-Sampling:
Sample Type: 10 min
RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
EPA TO-15
ppbv ug/m3
Sample Flags: RL-11
MDL MDL
Tetrachloroethylene ND 1.5 1/11/24 21:46 KMCND30100.56 3.8
Tetrahydrofuran 1000 15 1/11/24 21:46 KMC3000 30443.1 9.1
Toluene ND 1.5 1/11/24 21:46 KMCND305.70.55 2.1
1,2,4-Trichlorobenzene ND 1.5 1/11/24 21:46 KMCL-03 ND 30110.81 6.0
1,1,1-Trichloroethane ND 1.5 1/11/24 21:46 KMCND308.20.47 2.6
1,1,2-Trichloroethane ND 1.5 1/11/24 21:46 KMCND308.20.38 2.1
Trichloroethylene ND 1.5 1/11/24 21:46 KMCND308.10.61 3.3
Trichlorofluoromethane (Freon 11)ND 6.0 1/11/24 21:46 KMCND30340.61 3.5
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 6.0 1/11/24 21:46 KMCND30460.33 2.5
1,2,4-Trimethylbenzene ND 1.5 1/11/24 21:46 KMCND307.40.69 3.4
1,3,5-Trimethylbenzene ND 1.5 1/11/24 21:46 KMCND307.40.77 3.8
Vinyl Acetate ND 30 1/11/24 21:46 KMCND301105.4 19
Vinyl Chloride ND 1.5 1/11/24 21:46 KMCND303.80.68 1.7
m&p-Xylene ND 3.0 1/11/24 21:46 KMCND30131.1 4.6
o-Xylene ND 1.5 1/11/24 21:46 KMCND306.50.55 2.4
Surrogates % Recovery % REC Limits
4-Bromofluorobenzene (1)99.2 1/11/24 21:4670-130
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Sample Extraction Data
Prep Method: TO-15 Prep-EPA TO-15
Lab Number [Field ID]Batch Date
Pressure
Dilution
Pre
Dilution
Pre-Dil
Initial
mL
Pre-Dil
Final
mL
Default
Injection
mL
Actual
Injection
mL
24A0806-07 [MP-3]B363185 1.5 1 N/A 1000 200 75 01/11/24
24A0806-08 [MP-6]B363185 1.5 200 5 1000 200 200 01/11/24
24A0806-09 [MP-8]B363185 1.5 200 5 1000 200 100 01/11/24
24A0806-10 [MP-9]B363185 1.5 1 N/A 1000 200 10 01/11/24
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ug/m3 Spike Level
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Flag/Qual Analyte
Air Toxics by EPA Compendium Methods - Quality Control
QUALITY CONTROL
RL
ppbv
Results RL Results ppbv
Batch B363185 - TO-15 Prep
Blank (B363185-BLK1)Prepared & Analyzed: 01/11/24
0.80NDAcetone
0.020NDBenzene
0.020NDBenzyl chloride
0.020NDBromodichloromethane
0.020NDBromoform
0.020NDBromomethane
0.020ND1,3-Butadiene
0.80ND2-Butanone (MEK)
0.20NDCarbon Disulfide
0.020NDCarbon Tetrachloride
0.020NDChlorobenzene
0.020NDChloroethane
0.020NDChloroform
0.040NDChloromethane
0.020NDCyclohexane
0.020NDDibromochloromethane
0.020ND1,2-Dibromoethane (EDB)
0.020ND1,2-Dichlorobenzene
0.020ND1,3-Dichlorobenzene
0.020ND1,4-Dichlorobenzene
0.020NDDichlorodifluoromethane (Freon 12)
0.020ND1,1-Dichloroethane
0.020ND1,2-Dichloroethane
0.020ND1,1-Dichloroethylene
0.020NDcis-1,2-Dichloroethylene
0.020NDtrans-1,2-Dichloroethylene
0.020ND1,2-Dichloropropane
0.020NDcis-1,3-Dichloropropene
0.020NDtrans-1,3-Dichloropropene
0.020ND1,2-Dichloro-1,1,2,2-tetrafluoroethane
(Freon 114)
0.20ND1,4-Dioxane
0.80NDEthanol
0.20NDEthyl Acetate
0.020NDEthylbenzene
0.020ND4-Ethyltoluene
0.020NDHeptane
0.020 L-03NDHexachlorobutadiene
0.80NDHexane
0.020ND2-Hexanone (MBK)
0.80NDIsopropanol
0.020NDMethyl tert-Butyl Ether (MTBE)
0.20NDMethylene Chloride
0.020ND4-Methyl-2-pentanone (MIBK)
0.020 L-03NDNaphthalene
0.80NDPropene
0.020NDStyrene
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ug/m3 Spike Level
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Flag/Qual Analyte
Air Toxics by EPA Compendium Methods - Quality Control
QUALITY CONTROL
RL
ppbv
Results RL Results ppbv
Batch B363185 - TO-15 Prep
Blank (B363185-BLK1)Prepared & Analyzed: 01/11/24
0.020ND1,1,2,2-Tetrachloroethane
0.020NDTetrachloroethylene
0.20NDTetrahydrofuran
0.020NDToluene
0.020 L-03ND1,2,4-Trichlorobenzene
0.020ND1,1,1-Trichloroethane
0.020ND1,1,2-Trichloroethane
0.020NDTrichloroethylene
0.080NDTrichlorofluoromethane (Freon 11)
0.080ND1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
0.020ND1,2,4-Trimethylbenzene
0.020ND1,3,5-Trimethylbenzene
0.40NDVinyl Acetate
0.020NDVinyl Chloride
0.040NDm&p-Xylene
0.020NDo-Xylene
8.00 70-130Surrogate: 4-Bromofluorobenzene (1)96.17.69
LCS (B363185-BS1)Prepared & Analyzed: 01/11/24
5.00 70-1301005.00Acetone
5.00 70-13094.84.74Benzene
5.00 70-13074.43.72Benzyl chloride
5.00 70-13097.04.85Bromodichloromethane
5.00 70-13096.54.82Bromoform
5.00 70-1301206.00Bromomethane
5.00 70-1301075.331,3-Butadiene
5.00 70-13082.74.142-Butanone (MEK)
5.00 70-1301216.04Carbon Disulfide
5.00 70-13098.04.90Carbon Tetrachloride
5.00 70-13092.84.64Chlorobenzene
5.00 70-1301075.37Chloroethane
5.00 70-1301055.26Chloroform
5.00 70-1301085.42Chloromethane
5.00 70-13093.54.67Cyclohexane
5.00 70-13097.74.89Dibromochloromethane
5.00 70-13090.24.511,2-Dibromoethane (EDB)
5.00 70-13076.73.831,2-Dichlorobenzene
5.00 70-13087.74.381,3-Dichlorobenzene
5.00 70-13089.54.481,4-Dichlorobenzene
5.00 70-1301226.09Dichlorodifluoromethane (Freon 12)
5.00 70-1301135.651,1-Dichloroethane
5.00 70-13099.94.991,2-Dichloroethane
5.00 70-1301195.971,1-Dichloroethylene
5.00 70-13095.44.77cis-1,2-Dichloroethylene
5.00 70-1301145.69trans-1,2-Dichloroethylene
5.00 70-13097.04.851,2-Dichloropropane
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ug/m3 Spike Level
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Flag/Qual Analyte
Air Toxics by EPA Compendium Methods - Quality Control
QUALITY CONTROL
RL
ppbv
Results RL Results ppbv
Batch B363185 - TO-15 Prep
LCS (B363185-BS1)Prepared & Analyzed: 01/11/24
5.00 70-13093.34.66cis-1,3-Dichloropropene
5.00 70-13098.14.90trans-1,3-Dichloropropene
5.00 70-1301165.791,2-Dichloro-1,1,2,2-tetrafluoroethane
(Freon 114)
5.00 70-13085.74.281,4-Dioxane
5.00 70-1301015.04Ethanol
5.00 70-13079.33.96Ethyl Acetate
5.00 70-13096.34.82Ethylbenzene
5.00 70-13092.14.614-Ethyltoluene
5.00 70-13088.84.44Heptane
4.25 L-0370-13067.72.88Hexachlorobutadiene *
5.00 70-13094.24.71Hexane
5.00 70-13086.24.312-Hexanone (MBK)
5.00 70-13092.24.61Isopropanol
5.00 70-1301185.90Methyl tert-Butyl Ether (MTBE)
5.00 70-1301045.20Methylene Chloride
5.00 70-13088.64.434-Methyl-2-pentanone (MIBK)
3.68 L-0370-13061.62.27Naphthalene *
5.00 70-13085.74.29Propene
5.00 70-13089.64.48Styrene
5.00 70-13091.94.591,1,2,2-Tetrachloroethane
5.00 70-13092.24.61Tetrachloroethylene
5.00 70-13081.34.06Tetrahydrofuran
5.00 70-13094.54.72Toluene
3.90 L-0370-13068.92.691,2,4-Trichlorobenzene *
5.00 70-13092.94.641,1,1-Trichloroethane
5.00 70-1301015.051,1,2-Trichloroethane
5.00 70-13092.74.64Trichloroethylene
5.00 70-1301206.01Trichlorofluoromethane (Freon 11)
5.00 70-1301195.961,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
5.00 70-13087.74.381,2,4-Trimethylbenzene
5.00 70-13090.04.501,3,5-Trimethylbenzene
5.00 70-1301286.38Vinyl Acetate
5.00 70-1301135.67Vinyl Chloride
10.0 70-13098.89.88m&p-Xylene
5.00 70-13094.74.73o-Xylene
8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1018.07
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Note: Blank Subtraction is not performed unless otherwise noted
*QC result is outside of established limits.
†Wide recovery limits established for difficult compound.
‡Wide RPD limits established for difficult compound.
#Data exceeded client recommended or regulatory level
RL Reporting Limit
MDL Method Detection Limit
RPD Relative Percent Difference
LCS Laboratory Control Sample
Laboratory Control SampleLCS Dup Duplicate Laboratory Control Sample
MS Matrix Spike Sample
MS Dup Duplicate Matrix Spike Sample
REC Recovery
QC Quality Control
ppbv Parts per billion volume
EPA United States Environmental Protection Agency
Percent Recovery% REC
ND Not Detected
Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the
calculation which have not been rounded.
Not ApplicableN/A
DL Detection Limit
Not CalculatedNC
LFB/LCS Lab Fortified Blank/Lab Control Sample
ORP Oxidation-Reduction Potential
Not dry weight correctedwet
Percent weight% wt
KilogramKg
Gramg
Milligrammg
Microgramµg
Nanogramng
LiterL
MillilitermL
Microliter L
Cubic Meterm3
Extractable Petroleum HydrocarbonsEPH
Volatile Petroleum HydrocarbonsVPH
Air Petroleum HydrocarbonsAPH
Flame Ionization DetectorFID
Photo Ionization DetectorPID
FLAG/QUALIFIER SUMMARY
Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated
concentration (CLP J-Flag).
J
Laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this
compound is likely to be biased on the low side.
L-03
Elevated reporting limit due to high concentration of target compounds.RL-11
ANALYST
Rebecca FaustRLF
Kristen M CoutureKMC
Karriem G. Mariuskgm
Catherine M. RouleauCMR
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
INTERNAL STANDARD AREA AND RT SUMMARY
EPA TO-15
RTResponseInternal Standard Area %RT DiffResponse
Reference
RT
Reference Area %
Limits
RT Diff
Limit Q
Initial Cal Check (S091464-ICV1 )Lab File ID: L23A214020.D Analyzed: 08/02/23 23:42
Bromochloromethane (1)300782 2.867 314027 2.871 60 - 14096 -0.0040 +/-0.50
1,4-Difluorobenzene (1)878479 3.54 895773 3.54 60 - 14098 0.0000 +/-0.50
Chlorobenzene-d5 (1)823159 5.202 837397 5.202 60 - 14098 0.0000 +/-0.50
INTERNAL STANDARD AREA AND RT SUMMARY
EPA TO-15
RTResponseInternal Standard Area %RT DiffResponse
Reference
RT
Reference Area %
Limits
RT Diff
Limit Q
LCS (B363185-BS1 )Lab File ID: L24A011004.D Analyzed: 01/11/24 12:44
Bromochloromethane (1)232764 2.87 314027 2.871 60 - 14074 -0.0010 +/-0.50
1,4-Difluorobenzene (1)693705 3.538 895773 3.54 60 - 14077 -0.0020 +/-0.50
Chlorobenzene-d5 (1)636187 5.196 837397 5.202 60 - 14076 -0.0060 +/-0.50
Calibration Check (S099109-CCV1 )Lab File ID: L24A011006.D Analyzed: 01/11/24 13:34
Bromochloromethane (1)249952 2.864 314027 2.871 60 - 14080 -0.0070 +/-0.50
1,4-Difluorobenzene (1)755908 3.538 895773 3.54 60 - 14084 -0.0020 +/-0.50
Chlorobenzene-d5 (1)681410 5.196 837397 5.202 60 - 14081 -0.0060 +/-0.50
Blank (B363185-BLK1 )Lab File ID: L24A011009.D Analyzed: 01/11/24 15:07
Bromochloromethane (1)246545 2.864 249952 2.864 60 - 14099 0.0000 +/-0.50
1,4-Difluorobenzene (1)711228 3.538 755908 3.538 60 - 14094 0.0000 +/-0.50
Chlorobenzene-d5 (1)645896 5.194 681410 5.196 60 - 14095 -0.0020 +/-0.50
MP-3 (24A0806-07 )Lab File ID: L24A011023.D Analyzed: 01/11/24 21:20
Bromochloromethane (1)238579 2.87 249952 2.864 60 - 14095 0.0060 +/-0.50
1,4-Difluorobenzene (1)702275 3.538 755908 3.538 60 - 14093 0.0000 +/-0.50
Chlorobenzene-d5 (1)635455 5.196 681410 5.196 60 - 14093 0.0000 +/-0.50
MP-9 (24A0806-10 )Lab File ID: L24A011024.D Analyzed: 01/11/24 21:46
Bromochloromethane (1)234101 2.864 249952 2.864 60 - 14094 0.0000 +/-0.50
1,4-Difluorobenzene (1)694950 3.538 755908 3.538 60 - 14092 0.0000 +/-0.50
Chlorobenzene-d5 (1)621617 5.194 681410 5.196 60 - 14091 -0.0020 +/-0.50
MP-6 (24A0806-08 )Lab File ID: L24A011026.D Analyzed: 01/11/24 22:44
Bromochloromethane (1)235833 2.864 249952 2.864 60 - 14094 0.0000 +/-0.50
1,4-Difluorobenzene (1)703570 3.538 755908 3.538 60 - 14093 0.0000 +/-0.50
Chlorobenzene-d5 (1)637367 5.195 681410 5.196 60 - 14094 -0.0010 +/-0.50
MP-8 (24A0806-09 )Lab File ID: L24A011028.D Analyzed: 01/11/24 23:38
Bromochloromethane (1)238306 2.87 249952 2.864 60 - 14095 0.0060 +/-0.50
1,4-Difluorobenzene (1)700224 3.538 755908 3.538 60 - 14093 0.0000 +/-0.50
Chlorobenzene-d5 (1)632461 5.194 681410 5.196 60 - 14093 -0.0020 +/-0.50
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CONTINUING CALIBRATION CHECK
EPA TO-15
S099109-CCV1
COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL
CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR
STD
1.131929A 0.9 305.04 1.1222555.00Acetone
0.6742556A -7.1 304.65 0.72542935.00Benzene
0.651043A -0.1 304.99 0.651925.00Benzyl chloride
0.5501283A -1.2 304.94 0.55670475.00Bromodichloromethane
0.5060096A 2.7 305.14 0.49261015.00Bromoform
0.7461721A 18.3 305.91 0.63086765.00Bromomethane
0.6099027A 10.7 305.53 0.5511495.001,3-Butadiene
1.146831A -17.0 304.15 1.3816045.002-Butanone (MEK)
2.373582A 15.0 305.75 2.0637575.00Carbon Disulfide
0.4947353A -3.2 304.84 0.51103685.00Carbon Tetrachloride
0.7108273A -1.5 304.92 0.72198125.00Chlorobenzene
0.4345794A 5.5 305.28 0.4117515.00Chloroethane
1.516253A 5.3 305.27 1.4393325.00Chloroform
0.6389451A 4.7 305.24 0.61014595.00Chloromethane
0.2676474A -11.7 304.42 0.30302865.00Cyclohexane
0.5655332A 0.2 305.01 0.56441225.00Dibromochloromethane
0.4969484A -2.1 304.90 0.50764495.001,2-Dibromoethane (EDB)
0.6400587A 2.7 305.13 0.62347655.001,2-Dichlorobenzene
0.6928668A 10.6 305.53 0.62672365.001,3-Dichlorobenzene
0.6625885A 14.2 305.71 0.58013655.001,4-Dichlorobenzene
2.202938A 24.6 306.23 1.7680795.00Dichlorodifluoromethane (Freon 12)
1.59141A 14.3 305.71 1.3928245.001,1-Dichloroethane
1.011881A 3.5 305.18 0.97729275.001,2-Dichloroethane
1.332473A 18.2 305.91 1.1271875.001,1-Dichloroethylene
0.8772564A -3.5 304.83 0.9089525.00cis-1,2-Dichloroethylene
1.286705A 14.0 305.70 1.1282325.00trans-1,2-Dichloroethylene
0.2427068A -6.7 304.66 0.26019485.001,2-Dichloropropane
0.411631A 3.9 305.19 0.39622715.00cis-1,3-Dichloropropene
0.3205469A -9.0 304.55 0.35228425.00trans-1,3-Dichloropropene
2.220612A 24.4 306.22 1.7846875.001,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)
0.1555046A -10.8 304.46 0.17428525.001,4-Dioxane
0.1877673A 8.4 305.42 0.17324145.00Ethanol
0.1831136A -23.4 303.83 0.23901695.00Ethyl Acetate
1.190008A 1.1 305.06 1.1769025.00Ethylbenzene
1.258729A 0.9 305.05 1.2470695.004-Ethyltoluene
0.2003503A -12.4 304.38 0.22868475.00Heptane
0.486847A 2.4 305.12 0.47556165.00Hexachlorobutadiene
0.6774229A -9.0 304.55 0.74421785.00Hexane
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CONTINUING CALIBRATION CHECK
EPA TO-15
S099109-CCV1
COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL
CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR
STD
0.5654064A -5.7 304.72 0.59938995.002-Hexanone (MBK)
1.290814A 9.3 305.47 1.1806995.00Isopropanol
2.445186A 14.7 305.74 2.1308915.00Methyl tert-Butyl Ether (MTBE)
0.9265459A 6.3 305.32 0.87162145.00Methylene Chloride
0.2131667A -11.7 304.42 0.24143715.004-Methyl-2-pentanone (MIBK)
1.106677A 15.9 305.80 0.9546185.00Naphthalene
0.3472283A -14.8 304.26 0.40752365.00Propene
0.6768436A 1.3 305.07 0.66801735.00Styrene
0.7399833A 8.2 305.41 0.68382935.001,1,2,2-Tetrachloroethane
0.397531A -4.8 304.76 0.41745665.00Tetrachloroethylene
0.702138A -22.9 303.85 0.91119635.00Tetrahydrofuran
0.8990581A -4.2 304.79 0.93858055.00Toluene
0.4294131A 16.3 305.81 0.36932755.001,2,4-Trichlorobenzene
0.4913169A -3.2 304.84 0.50757925.001,1,1-Trichloroethane
0.3236818A 4.5 305.23 0.3096555.001,1,2-Trichloroethane
0.3074194A -8.4 304.58 0.33565985.00Trichloroethylene
2.225957A 22.5 306.13 1.8167435.00Trichlorofluoromethane (Freon 11)
1.751722A 21.9 306.10 1.4365825.001,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)
1.086289A 6.4 305.32 1.0213025.001,2,4-Trimethylbenzene
1.119451A 6.1 305.30 1.0552965.001,3,5-Trimethylbenzene
1.819876A 24.3 306.22 1.4635415.00Vinyl Acetate
0.8240174A 16.0 305.80 0.71057575.00Vinyl Chloride
1.014797A 4.5 3010.4 0.971150610.0m&p-Xylene
0.9734897A 1.9 305.10 0.95505185.00o-Xylene
* Values outside of QC limits
# Column to be used to flag Response Factor and %Diff/Drift values with an asterisk
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
EPA TO-15 in Air
NY,ME,NHAcetone
FL,NJ,NY,ME,NH,VABenzene
FL,NJ,NY,ME,NH,VABenzyl chloride
NJ,NY,ME,NH,VABromodichloromethane
NJ,NY,ME,NH,VABromoform
FL,NJ,NY,ME,NHBromomethane
NJ,NY,ME,NH,VA1,3-Butadiene
FL,NJ,NY,ME,NH,VA2-Butanone (MEK)
NJ,NY,ME,NH,VACarbon Disulfide
FL,NJ,NY,ME,NH,VACarbon Tetrachloride
FL,NJ,NY,ME,NH,VAChlorobenzene
FL,NJ,NY,ME,NH,VAChloroethane
FL,NJ,NY,ME,NH,VAChloroform
FL,NJ,NY,ME,NH,VAChloromethane
NJ,NY,ME,NH,VACyclohexane
NY,ME,NHDibromochloromethane
NJ,NY,ME,NH1,2-Dibromoethane (EDB)
FL,NJ,NY,ME,NH,VA1,2-Dichlorobenzene
NJ,NY,ME,NH1,3-Dichlorobenzene
FL,NJ,NY,ME,NH,VA1,4-Dichlorobenzene
NY,ME,NHDichlorodifluoromethane (Freon 12)
FL,NJ,NY,ME,NH,VA1,1-Dichloroethane
FL,NJ,NY,ME,NH,VA1,2-Dichloroethane
FL,NJ,NY,ME,NH,VA1,1-Dichloroethylene
FL,NY,ME,NH,VAcis-1,2-Dichloroethylene
NJ,NY,ME,NH,VAtrans-1,2-Dichloroethylene
FL,NJ,NY,ME,NH,VA1,2-Dichloropropane
FL,NJ,NY,ME,NH,VAcis-1,3-Dichloropropene
NY,ME,NHtrans-1,3-Dichloropropene
NJ,NY,ME,NH,VA1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)
NJ,NY,ME,NH,VA1,4-Dioxane
FL,NJ,NY,ME,NH,VAEthylbenzene
NJ,NY,ME,NH,VAHeptane
NJ,NY,ME,NH,VAHexachlorobutadiene
FL,NJ,NY,ME,NH,VAHexane
NY,ME,NHIsopropanol
FL,NJ,NY,ME,NH,VAMethyl tert-Butyl Ether (MTBE)
FL,NJ,NY,ME,NH,VAMethylene Chloride
FL,NJ,NY,ME,NH4-Methyl-2-pentanone (MIBK)
NY,ME,NHNaphthalene
FL,NJ,NY,ME,NH,VAStyrene
FL,NJ,NY,ME,NH,VA1,1,2,2-Tetrachloroethane
FL,NJ,NY,ME,NH,VATetrachloroethylene
FL,NJ,NY,ME,NH,VAToluene
NJ,NY,ME,NH,VA1,2,4-Trichlorobenzene
FL,NJ,NY,ME,NH,VA1,1,1-Trichloroethane
FL,NJ,NY,ME,NH,VA1,1,2-Trichloroethane
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
EPA TO-15 in Air
FL,NJ,NY,ME,NH,VATrichloroethylene
NY,ME,NHTrichlorofluoromethane (Freon 11)
NJ,NY,ME,NH,VA1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)
NJ,NY,ME,NH1,2,4-Trimethylbenzene
NJ,NY,ME,NH1,3,5-Trimethylbenzene
FL,NJ,NY,ME,NH,VAVinyl Acetate
FL,NJ,NY,ME,NH,VAVinyl Chloride
FL,NJ,NY,ME,NH,VAm&p-Xylene
FL,NJ,NY,ME,NH,VAo-Xylene
Con-Test, a Pace Environmental Laboratory, operates under the following certifications and accreditations:
Code Description Number Expires
10899 NELAPNew York State Department of HealthNY 04/1/2024
2516 NELAPNew Hampshire Environmental LabNH 02/5/2024
MA007 NELAPNew Jersey DEPNJ 06/30/2024
E871027 NELAPFlorida Department of HealthFL 06/30/2024
MA00100State of MaineME 06/9/2025
460217Commonwealth of VirginiaVA 12/14/2024
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
January 19, 2024
Trinh Desa
Hart & Hickman - Charlotte, NC
2923 South Tryon Street, Suite 100
Charlotte, NC 28203
Project Location: Charlotte, NC
Client Job Number:
Project Number: AKR-005
Laboratory Work Order Number: 24A0807
Enclosed are results of analyses for samples as received by the laboratory on January 9, 2024. If you have any questions
concerning this report, please feel free to contact me.
Sincerely,
Rebecca Faust
Project Manager
QA Officer
Katherine Allen
Laboratory Manager
Daren Damboragian
Page 1 of 24
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL SUMMARY
1/19/2024Hart & Hickman - Charlotte, NC
2923 South Tryon Street, Suite 100
Charlotte, NC 28203
ATTN: Trinh Desa
AKR-005
24A0807
The results of analyses performed on the following samples submitted to Con-Test, a Pace Analytical Laboratory, are found in this report.
PROJECT LOCATION:
PURCHASE ORDER NUMBER:
PROJECT NUMBER:
REPORT DATE:
WORK ORDER NUMBER:
FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB
Charlotte, NC
IAS-2 24A0807-01 Indoor air -
EPA TO-15
IAS-3 24A0807-02 Indoor air EPA TO-15
IAS-4 24A0807-03 Indoor air -
EPA TO-15
IAS-5 24A0807-04 Indoor air -
EPA TO-15
IAS-DUP 24A0807-05 Indoor air -
EPA TO-15
IAS-BKG 24A0807-06 Ambient Air -
EPA TO-15
Page 2 of 24
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CASE NARRATIVE SUMMARY
All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report.
EPA TO-15
Qualifications:
Analyte is found in the associated laboratory blank as well as in the sample.
Analyte & Samples(s) Qualified:
B
Naphthalene
24A0807-01[IAS-2], 24A0807-02[IAS-3], 24A0807-03[IAS-4], 24A0807-04[IAS-5], 24A0807-05[IAS-DUP], B363467-BLK1
Reported result is estimated. Value reported over verified calibration range.
Analyte & Samples(s) Qualified:
E
Ethanol
24A0807-02[IAS-3], 24A0807-04[IAS-5]
Laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this compound is likely to be
biased on the low side.
Analyte & Samples(s) Qualified:
L-03
Tetrahydrofuran
24A0807-01[IAS-2], 24A0807-02[IAS-3], 24A0807-03[IAS-4], 24A0807-04[IAS-5], 24A0807-05[IAS-DUP], 24A0807-06[IAS-BKG], B363467-BS1
Laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this compound is likely to be
biased on the high side.
Analyte & Samples(s) Qualified:
L-05
Naphthalene, Vinyl Acetate
24A0807-01[IAS-2], 24A0807-02[IAS-3], 24A0807-03[IAS-4], 24A0807-04[IAS-5], 24A0807-05[IAS-DUP], B363467-BS1, 24A0807-06[IAS-BKG]
Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side for this compound.
Analyte & Samples(s) Qualified:
V-06
Naphthalene, Vinyl Acetate
24A0807-01[IAS-2], 24A0807-02[IAS-3], 24A0807-03[IAS-4], 24A0807-04[IAS-5], 24A0807-05[IAS-DUP], B363467-BS1, S099219-CCV1, 24A0807-06[IAS-BKG]
Page 3 of 24
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
The results of analyses reported only relate to samples submitted to Con-Test, a Pace Analytical Laboratory, for testing.
I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed
in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the
best of my knowledge and belief, accurate and complete.
Lisa A. Worthington
Technical Representative
Page 4 of 24
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL RESULTS
Project Location: Charlotte, NC
Date Received: 1/9/2024
Work Order: 24A0807Sample Description/Location:
Field Sample #: IAS-2
Sample ID: 24A0807-01
Sample Matrix: Indoor air
Initial Vacuum(in Hg): -29
Final Vacuum(in Hg): -7
Receipt Vacuum(in Hg): -8.7
Sampled: 1/7/2024 10:15
Canister ID: P0430
Flow Controller ID: FC1891
Sub Description/Location:
Canister Size: 6 liter
Flow Controller Type: Fixed-Orifice
Flow Controller Calibration
RPD Pre and Post-Sampling:
Sample Type: 24 hr
RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
EPA TO-15
ppbv ug/m3
MDL MDL
Acetone 9.6 1.4 1/15/24 17:35 KMC23 0.6983.30.33 0.78
Benzene 0.21 0.035 1/15/24 17:35 KMC0.68 0.6980.110.011 0.034
1,3-Butadiene ND 0.035 1/15/24 17:35 KMCND0.6980.0770.029 0.065
2-Butanone (MEK)1.6 1.4 1/15/24 17:35 KMC4.6 0.6984.10.39 1.2
Carbon Disulfide ND 0.35 1/15/24 17:35 KMCND0.6981.10.067 0.21
Carbon Tetrachloride 0.027 0.035 1/15/24 17:35 KMCJ0.17 0.6980.220.010 0.063
Chloroform 0.017 0.035 1/15/24 17:35 KMCJ0.085 0.6980.170.0091 0.044
Chloromethane 0.57 0.070 1/15/24 17:35 KMC1.2 0.6980.140.014 0.029
Cyclohexane 0.031 0.035 1/15/24 17:35 KMCJ0.11 0.6980.120.015 0.053
1,2-Dibromoethane (EDB)ND 0.035 1/15/24 17:35 KMCND0.6980.270.012 0.089
1,4-Dichlorobenzene ND 0.035 1/15/24 17:35 KMCND0.6980.210.013 0.077
Dichlorodifluoromethane (Freon 12)0.62 0.035 1/15/24 17:35 KMC3.1 0.6980.170.015 0.072
1,1-Dichloroethane ND 0.035 1/15/24 17:35 KMCND0.6980.140.011 0.045
cis-1,2-Dichloroethylene ND 0.035 1/15/24 17:35 KMCND0.6980.140.011 0.043
trans-1,2-Dichloroethylene ND 0.035 1/15/24 17:35 KMCND0.6980.140.011 0.045
1,2-Dichloropropane ND 0.035 1/15/24 17:35 KMCND0.6980.160.0096 0.044
Ethanol 28 1.4 1/15/24 17:35 KMC53 0.6982.60.93 1.7
Ethyl Acetate 0.57 0.35 1/15/24 17:35 KMC2.0 0.6981.30.10 0.36
Ethylbenzene 0.38 0.035 1/15/24 17:35 KMC1.7 0.6980.150.010 0.044
Heptane 0.090 0.035 1/15/24 17:35 KMC0.37 0.6980.140.022 0.090
Hexane ND 1.4 1/15/24 17:35 KMCND0.6984.90.46 1.6
2-Hexanone (MBK)0.066 0.035 1/15/24 17:35 KMC0.27 0.6980.140.015 0.062
Isopropanol 2.5 1.4 1/15/24 17:35 KMC6.1 0.6983.40.44 1.1
Methyl tert-Butyl Ether (MTBE)0.030 0.035 1/15/24 17:35 KMCJ0.11 0.6980.130.017 0.062
Naphthalene 0.047 0.035 1/15/24 17:35 KMCB, V-06,
L-05
0.25 0.6980.180.023 0.12
Styrene 0.19 0.035 1/15/24 17:35 KMC0.82 0.6980.150.019 0.080
Tetrachloroethylene ND 0.035 1/15/24 17:35 KMCND0.6980.240.013 0.089
Tetrahydrofuran 0.84 0.35 1/15/24 17:35 KMCL-03 2.5 0.6981.00.072 0.21
Toluene 0.61 0.035 1/15/24 17:35 KMC2.3 0.6980.130.013 0.048
Trichloroethylene ND 0.035 1/15/24 17:35 KMCND0.6980.190.014 0.076
Trichlorofluoromethane (Freon 11)0.26 0.14 1/15/24 17:35 KMC1.5 0.6980.780.014 0.080
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)0.075 0.14 1/15/24 17:35 KMCJ0.58 0.6981.10.0077 0.059
1,2,4-Trimethylbenzene 0.12 0.035 1/15/24 17:35 KMC0.61 0.6980.170.016 0.079
Vinyl Acetate 0.37 0.70 1/15/24 17:35 KMCV-06, L-05, J 1.3 0.6982.50.12 0.44
Vinyl Chloride ND 0.035 1/15/24 17:35 KMCND0.6980.0890.016 0.041
m&p-Xylene 1.4 0.070 1/15/24 17:35 KMC6.1 0.6980.300.024 0.11
o-Xylene 0.54 0.035 1/15/24 17:35 KMC2.3 0.6980.150.013 0.055
Surrogates % Recovery % REC Limits
4-Bromofluorobenzene (1)99.6 1/15/24 17:3570-130
Page 5 of 24
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL RESULTS
Project Location: Charlotte, NC
Date Received: 1/9/2024
Work Order: 24A0807Sample Description/Location:
Field Sample #: IAS-3
Sample ID: 24A0807-02
Sample Matrix: Indoor air
Initial Vacuum(in Hg): -31
Final Vacuum(in Hg): -10
Receipt Vacuum(in Hg): -9.0
Sampled: 1/7/2024 10:30
Canister ID: 1115
Flow Controller ID: FC1449
Sub Description/Location:
Canister Size: 6 liter
Flow Controller Type: Fixed-Orifice
Flow Controller Calibration
RPD Pre and Post-Sampling:
Sample Type: 24 hr
RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
EPA TO-15
ppbv ug/m3
MDL MDL
Acetone 18 1.4 1/15/24 18:08 KMC43 0.6983.30.33 0.78
Benzene 0.19 0.035 1/15/24 18:08 KMC0.61 0.6980.110.011 0.034
1,3-Butadiene ND 0.035 1/15/24 18:08 KMCND0.6980.0770.029 0.065
2-Butanone (MEK)1.1 1.4 1/15/24 18:08 KMCJ3.2 0.6984.10.39 1.2
Carbon Disulfide ND 0.35 1/15/24 18:08 KMCND0.6981.10.067 0.21
Carbon Tetrachloride 0.069 0.035 1/15/24 18:08 KMC0.43 0.6980.220.010 0.063
Chloroform 0.022 0.035 1/15/24 18:08 KMCJ0.11 0.6980.170.0091 0.044
Chloromethane 0.58 0.070 1/15/24 18:08 KMC1.2 0.6980.140.014 0.029
Cyclohexane 0.22 0.035 1/15/24 18:08 KMC0.75 0.6980.120.015 0.053
1,2-Dibromoethane (EDB)ND 0.035 1/15/24 18:08 KMCND0.6980.270.012 0.089
1,4-Dichlorobenzene ND 0.035 1/15/24 18:08 KMCND0.6980.210.013 0.077
Dichlorodifluoromethane (Freon 12)0.56 0.035 1/15/24 18:08 KMC2.7 0.6980.170.015 0.072
1,1-Dichloroethane ND 0.035 1/15/24 18:08 KMCND0.6980.140.011 0.045
cis-1,2-Dichloroethylene ND 0.035 1/15/24 18:08 KMCND0.6980.140.011 0.043
trans-1,2-Dichloroethylene ND 0.035 1/15/24 18:08 KMCND0.6980.140.011 0.045
1,2-Dichloropropane ND 0.035 1/15/24 18:08 KMCND0.6980.160.0096 0.044
Ethanol 43 1.4 1/15/24 18:08 KMCE82 0.6982.60.93 1.7
Ethyl Acetate 1.4 0.35 1/15/24 18:08 KMC4.9 0.6981.30.10 0.36
Ethylbenzene 0.15 0.035 1/15/24 18:08 KMC0.67 0.6980.150.010 0.044
Heptane 0.14 0.035 1/15/24 18:08 KMC0.58 0.6980.140.022 0.090
Hexane ND 1.4 1/15/24 18:08 KMCND0.6984.90.46 1.6
2-Hexanone (MBK)0.044 0.035 1/15/24 18:08 KMC0.18 0.6980.140.015 0.062
Isopropanol 2.0 1.4 1/15/24 18:08 KMC5.0 0.6983.40.44 1.1
Methyl tert-Butyl Ether (MTBE)ND 0.035 1/15/24 18:08 KMCND0.6980.130.017 0.062
Naphthalene 0.037 0.035 1/15/24 18:08 KMCB, L-05,
V-06
0.19 0.6980.180.023 0.12
Styrene 0.15 0.035 1/15/24 18:08 KMC0.64 0.6980.150.019 0.080
Tetrachloroethylene ND 0.035 1/15/24 18:08 KMCND0.6980.240.013 0.089
Tetrahydrofuran 6.7 0.35 1/15/24 18:08 KMCL-03 20 0.6981.00.072 0.21
Toluene 1.6 0.035 1/15/24 18:08 KMC5.9 0.6980.130.013 0.048
Trichloroethylene ND 0.035 1/15/24 18:08 KMCND0.6980.190.014 0.076
Trichlorofluoromethane (Freon 11)0.26 0.14 1/15/24 18:08 KMC1.5 0.6980.780.014 0.080
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)0.084 0.14 1/15/24 18:08 KMCJ0.64 0.6981.10.0077 0.059
1,2,4-Trimethylbenzene 0.16 0.035 1/15/24 18:08 KMC0.77 0.6980.170.016 0.079
Vinyl Acetate 0.52 0.70 1/15/24 18:08 KMCL-05, V-06, J 1.8 0.6982.50.12 0.44
Vinyl Chloride ND 0.035 1/15/24 18:08 KMCND0.6980.0890.016 0.041
m&p-Xylene 0.50 0.070 1/15/24 18:08 KMC2.2 0.6980.300.024 0.11
o-Xylene 0.23 0.035 1/15/24 18:08 KMC0.98 0.6980.150.013 0.055
Surrogates % Recovery % REC Limits
4-Bromofluorobenzene (1)99.1 1/15/24 18:0870-130
Page 6 of 24
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL RESULTS
Project Location: Charlotte, NC
Date Received: 1/9/2024
Work Order: 24A0807Sample Description/Location:
Field Sample #: IAS-4
Sample ID: 24A0807-03
Sample Matrix: Indoor air
Initial Vacuum(in Hg): -27.5
Final Vacuum(in Hg): -9.5
Receipt Vacuum(in Hg): -12.0
Sampled: 1/7/2024 10:25
Canister ID: P2658
Flow Controller ID: 3542
Sub Description/Location:
Canister Size: 6 liter
Flow Controller Type: Fixed-Orifice
Flow Controller Calibration
RPD Pre and Post-Sampling:
Sample Type: 24 hr
RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
EPA TO-15
ppbv ug/m3
MDL MDL
Acetone 23 1.4 1/15/24 18:42 KMC55 0.6963.30.33 0.78
Benzene 0.20 0.035 1/15/24 18:42 KMC0.63 0.6960.110.011 0.034
1,3-Butadiene ND 0.035 1/15/24 18:42 KMCND0.6960.0770.029 0.064
2-Butanone (MEK)2.0 1.4 1/15/24 18:42 KMC5.8 0.6964.10.39 1.2
Carbon Disulfide ND 0.35 1/15/24 18:42 KMCND0.6961.10.067 0.21
Carbon Tetrachloride 0.010 0.035 1/15/24 18:42 KMCJ0.066 0.6960.220.010 0.063
Chloroform 0.024 0.035 1/15/24 18:42 KMCJ0.12 0.6960.170.0091 0.044
Chloromethane 0.54 0.070 1/15/24 18:42 KMC1.1 0.6960.140.014 0.029
Cyclohexane 0.19 0.035 1/15/24 18:42 KMC0.66 0.6960.120.015 0.053
1,2-Dibromoethane (EDB)ND 0.035 1/15/24 18:42 KMCND0.6960.270.012 0.089
1,4-Dichlorobenzene ND 0.035 1/15/24 18:42 KMCND0.6960.210.013 0.077
Dichlorodifluoromethane (Freon 12)0.68 0.035 1/15/24 18:42 KMC3.4 0.6960.170.015 0.072
1,1-Dichloroethane ND 0.035 1/15/24 18:42 KMCND0.6960.140.011 0.045
cis-1,2-Dichloroethylene ND 0.035 1/15/24 18:42 KMCND0.6960.140.011 0.043
trans-1,2-Dichloroethylene ND 0.035 1/15/24 18:42 KMCND0.6960.140.011 0.045
1,2-Dichloropropane ND 0.035 1/15/24 18:42 KMCND0.6960.160.0096 0.044
Ethanol 18 1.4 1/15/24 18:42 KMC35 0.6962.60.92 1.7
Ethyl Acetate ND 0.35 1/15/24 18:42 KMCND0.6961.30.10 0.36
Ethylbenzene 1.2 0.035 1/15/24 18:42 KMC5.0 0.6960.150.010 0.044
Heptane 0.11 0.035 1/15/24 18:42 KMC0.47 0.6960.140.022 0.090
Hexane ND 1.4 1/15/24 18:42 KMCND0.6964.90.46 1.6
2-Hexanone (MBK)0.089 0.035 1/15/24 18:42 KMC0.36 0.6960.140.015 0.062
Isopropanol 1.4 1.4 1/15/24 18:42 KMCJ3.4 0.6963.40.44 1.1
Methyl tert-Butyl Ether (MTBE)ND 0.035 1/15/24 18:42 KMCND0.6960.130.017 0.062
Naphthalene 0.037 0.035 1/15/24 18:42 KMCB, L-05,
V-06
0.19 0.6960.180.023 0.12
Styrene 0.25 0.035 1/15/24 18:42 KMC1.0 0.6960.150.019 0.079
Tetrachloroethylene ND 0.035 1/15/24 18:42 KMCND0.6960.240.013 0.088
Tetrahydrofuran 12 0.35 1/15/24 18:42 KMCL-03 34 0.6961.00.072 0.21
Toluene 0.88 0.035 1/15/24 18:42 KMC3.3 0.6960.130.013 0.048
Trichloroethylene ND 0.035 1/15/24 18:42 KMCND0.6960.190.014 0.076
Trichlorofluoromethane (Freon 11)0.26 0.14 1/15/24 18:42 KMC1.4 0.6960.780.014 0.080
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)0.087 0.14 1/15/24 18:42 KMCJ0.67 0.6961.10.0077 0.059
1,2,4-Trimethylbenzene 0.33 0.035 1/15/24 18:42 KMC1.6 0.6960.170.016 0.079
Vinyl Acetate 0.59 0.70 1/15/24 18:42 KMCL-05, V-06, J 2.1 0.6962.50.12 0.44
Vinyl Chloride ND 0.035 1/15/24 18:42 KMCND0.6960.0890.016 0.041
m&p-Xylene 4.3 0.070 1/15/24 18:42 KMC18 0.6960.300.024 0.11
o-Xylene 1.2 0.035 1/15/24 18:42 KMC5.2 0.6960.150.013 0.055
Surrogates % Recovery % REC Limits
4-Bromofluorobenzene (1)102 1/15/24 18:4270-130
Page 7 of 24
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL RESULTS
Project Location: Charlotte, NC
Date Received: 1/9/2024
Work Order: 24A0807Sample Description/Location:
Field Sample #: IAS-5
Sample ID: 24A0807-04
Sample Matrix: Indoor air
Initial Vacuum(in Hg): -27
Final Vacuum(in Hg): -3.5
Receipt Vacuum(in Hg): -4.6
Sampled: 1/7/2024 10:20
Canister ID: P1598
Flow Controller ID: FC0347
Sub Description/Location:
Canister Size: 6 liter
Flow Controller Type: Fixed-Orifice
Flow Controller Calibration
RPD Pre and Post-Sampling:
Sample Type: 24 hr
RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
EPA TO-15
ppbv ug/m3
MDL MDL
Acetone 29 1.4 1/15/24 19:15 KMC69 0.6983.30.33 0.78
Benzene 0.28 0.035 1/15/24 19:15 KMC0.89 0.6980.110.011 0.034
1,3-Butadiene ND 0.035 1/15/24 19:15 KMCND0.6980.0770.029 0.065
2-Butanone (MEK)1.9 1.4 1/15/24 19:15 KMC5.5 0.6984.10.39 1.2
Carbon Disulfide ND 0.35 1/15/24 19:15 KMCND0.6981.10.067 0.21
Carbon Tetrachloride 0.026 0.035 1/15/24 19:15 KMCJ0.16 0.6980.220.010 0.063
Chloroform 0.028 0.035 1/15/24 19:15 KMCJ0.14 0.6980.170.0091 0.044
Chloromethane 0.58 0.070 1/15/24 19:15 KMC1.2 0.6980.140.014 0.029
Cyclohexane 0.15 0.035 1/15/24 19:15 KMC0.52 0.6980.120.015 0.053
1,2-Dibromoethane (EDB)ND 0.035 1/15/24 19:15 KMCND0.6980.270.012 0.089
1,4-Dichlorobenzene ND 0.035 1/15/24 19:15 KMCND0.6980.210.013 0.077
Dichlorodifluoromethane (Freon 12)0.60 0.035 1/15/24 19:15 KMC2.9 0.6980.170.015 0.072
1,1-Dichloroethane ND 0.035 1/15/24 19:15 KMCND0.6980.140.011 0.045
cis-1,2-Dichloroethylene ND 0.035 1/15/24 19:15 KMCND0.6980.140.011 0.043
trans-1,2-Dichloroethylene 0.017 0.035 1/15/24 19:15 KMCJ0.069 0.6980.140.011 0.045
1,2-Dichloropropane ND 0.035 1/15/24 19:15 KMCND0.6980.160.0096 0.044
Ethanol 160 1.4 1/15/24 19:15 KMCE290 0.6982.60.93 1.7
Ethyl Acetate 1.2 0.35 1/15/24 19:15 KMC4.2 0.6981.30.10 0.36
Ethylbenzene 0.29 0.035 1/15/24 19:15 KMC1.2 0.6980.150.010 0.044
Heptane 0.23 0.035 1/15/24 19:15 KMC0.96 0.6980.140.022 0.090
Hexane 0.64 1.4 1/15/24 19:15 KMCJ2.3 0.6984.90.46 1.6
2-Hexanone (MBK)0.14 0.035 1/15/24 19:15 KMC0.58 0.6980.140.015 0.062
Isopropanol 4.0 1.4 1/15/24 19:15 KMC9.9 0.6983.40.44 1.1
Methyl tert-Butyl Ether (MTBE)0.046 0.035 1/15/24 19:15 KMC0.17 0.6980.130.017 0.062
Naphthalene 0.027 0.035 1/15/24 19:15 KMCB, L-05,
V-06, J
0.14 0.6980.180.023 0.12
Styrene 0.25 0.035 1/15/24 19:15 KMC1.0 0.6980.150.019 0.080
Tetrachloroethylene 0.022 0.035 1/15/24 19:15 KMCJ0.15 0.6980.240.013 0.089
Tetrahydrofuran 11 0.35 1/15/24 19:15 KMCL-03 31 0.6981.00.072 0.21
Toluene 2.9 0.035 1/15/24 19:15 KMC11 0.6980.130.013 0.048
Trichloroethylene 0.062 0.035 1/15/24 19:15 KMC0.33 0.6980.190.014 0.076
Trichlorofluoromethane (Freon 11)0.25 0.14 1/15/24 19:15 KMC1.4 0.6980.780.014 0.080
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)0.082 0.14 1/15/24 19:15 KMCJ0.63 0.6981.10.0077 0.059
1,2,4-Trimethylbenzene 0.31 0.035 1/15/24 19:15 KMC1.5 0.6980.170.016 0.079
Vinyl Acetate 0.25 0.70 1/15/24 19:15 KMCL-05, V-06, J 0.89 0.6982.50.12 0.44
Vinyl Chloride ND 0.035 1/15/24 19:15 KMCND0.6980.0890.016 0.041
m&p-Xylene 0.94 0.070 1/15/24 19:15 KMC4.1 0.6980.300.024 0.11
o-Xylene 0.35 0.035 1/15/24 19:15 KMC1.5 0.6980.150.013 0.055
Surrogates % Recovery % REC Limits
4-Bromofluorobenzene (1)102 1/15/24 19:1570-130
Page 8 of 24
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL RESULTS
Project Location: Charlotte, NC
Date Received: 1/9/2024
Work Order: 24A0807Sample Description/Location:
Field Sample #: IAS-DUP
Sample ID: 24A0807-05
Sample Matrix: Indoor air
Initial Vacuum(in Hg): -27.5
Final Vacuum(in Hg): -9.5
Receipt Vacuum(in Hg): -12.0
Sampled: 1/7/2024 00:00
Canister ID: P3649
Flow Controller ID: 3542
Sub Description/Location:
Canister Size: 6 liter
Flow Controller Type: Fixed-Orifice
Flow Controller Calibration
RPD Pre and Post-Sampling:
Sample Type: 24 hr
RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
EPA TO-15
ppbv ug/m3
MDL MDL
Acetone 20 1.4 1/15/24 19:50 KMC47 0.6963.30.33 0.78
Benzene 0.20 0.035 1/15/24 19:50 KMC0.63 0.6960.110.011 0.034
1,3-Butadiene ND 0.035 1/15/24 19:50 KMCND0.6960.0770.029 0.064
2-Butanone (MEK)1.7 1.4 1/15/24 19:50 KMC5.0 0.6964.10.39 1.2
Carbon Disulfide ND 0.35 1/15/24 19:50 KMCND0.6961.10.067 0.21
Carbon Tetrachloride 0.074 0.035 1/15/24 19:50 KMC0.47 0.6960.220.010 0.063
Chloroform 0.022 0.035 1/15/24 19:50 KMCJ0.11 0.6960.170.0091 0.044
Chloromethane 0.58 0.070 1/15/24 19:50 KMC1.2 0.6960.140.014 0.029
Cyclohexane 0.19 0.035 1/15/24 19:50 KMC0.64 0.6960.120.015 0.053
1,2-Dibromoethane (EDB)ND 0.035 1/15/24 19:50 KMCND0.6960.270.012 0.089
1,4-Dichlorobenzene ND 0.035 1/15/24 19:50 KMCND0.6960.210.013 0.077
Dichlorodifluoromethane (Freon 12)0.83 0.035 1/15/24 19:50 KMC4.1 0.6960.170.015 0.072
1,1-Dichloroethane ND 0.035 1/15/24 19:50 KMCND0.6960.140.011 0.045
cis-1,2-Dichloroethylene ND 0.035 1/15/24 19:50 KMCND0.6960.140.011 0.043
trans-1,2-Dichloroethylene ND 0.035 1/15/24 19:50 KMCND0.6960.140.011 0.045
1,2-Dichloropropane ND 0.035 1/15/24 19:50 KMCND0.6960.160.0096 0.044
Ethanol 19 1.4 1/15/24 19:50 KMC37 0.6962.60.92 1.7
Ethyl Acetate ND 0.35 1/15/24 19:50 KMCND0.6961.30.10 0.36
Ethylbenzene 1.2 0.035 1/15/24 19:50 KMC5.1 0.6960.150.010 0.044
Heptane 0.12 0.035 1/15/24 19:50 KMC0.49 0.6960.140.022 0.090
Hexane ND 1.4 1/15/24 19:50 KMCND0.6964.90.46 1.6
2-Hexanone (MBK)ND 0.035 1/15/24 19:50 KMCND0.6960.140.015 0.062
Isopropanol 1.3 1.4 1/15/24 19:50 KMCJ3.2 0.6963.40.44 1.1
Methyl tert-Butyl Ether (MTBE)0.022 0.035 1/15/24 19:50 KMCJ0.078 0.6960.130.017 0.062
Naphthalene 0.030 0.035 1/15/24 19:50 KMCB, L-05,
V-06, J
0.16 0.6960.180.023 0.12
Styrene 0.25 0.035 1/15/24 19:50 KMC1.1 0.6960.150.019 0.079
Tetrachloroethylene ND 0.035 1/15/24 19:50 KMCND0.6960.240.013 0.088
Tetrahydrofuran 12 0.35 1/15/24 19:50 KMCL-03 34 0.6961.00.072 0.21
Toluene 0.89 0.035 1/15/24 19:50 KMC3.3 0.6960.130.013 0.048
Trichloroethylene ND 0.035 1/15/24 19:50 KMCND0.6960.190.014 0.076
Trichlorofluoromethane (Freon 11)0.26 0.14 1/15/24 19:50 KMC1.5 0.6960.780.014 0.080
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)0.11 0.14 1/15/24 19:50 KMCJ0.82 0.6961.10.0077 0.059
1,2,4-Trimethylbenzene 0.32 0.035 1/15/24 19:50 KMC1.6 0.6960.170.016 0.079
Vinyl Acetate 0.49 0.70 1/15/24 19:50 KMCL-05, V-06, J 1.7 0.6962.50.12 0.44
Vinyl Chloride ND 0.035 1/15/24 19:50 KMCND0.6960.0890.016 0.041
m&p-Xylene 4.4 0.070 1/15/24 19:50 KMC19 0.6960.300.024 0.11
o-Xylene 1.2 0.035 1/15/24 19:50 KMC5.3 0.6960.150.013 0.055
Surrogates % Recovery % REC Limits
4-Bromofluorobenzene (1)102 1/15/24 19:5070-130
Page 9 of 24
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL RESULTS
Project Location: Charlotte, NC
Date Received: 1/9/2024
Work Order: 24A0807Sample Description/Location:
Field Sample #: IAS-BKG
Sample ID: 24A0807-06
Sample Matrix: Ambient Air
Initial Vacuum(in Hg): -30
Final Vacuum(in Hg): -6
Receipt Vacuum(in Hg): -4.9
Sampled: 1/7/2024 10:35
Canister ID: P2330
Flow Controller ID: FC1261
Sub Description/Location:
Canister Size: 6 liter
Flow Controller Type: Fixed-Orifice
Flow Controller Calibration
RPD Pre and Post-Sampling:
Sample Type: 24 hr
RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
EPA TO-15
ppbv ug/m3
MDL MDL
Acetone 5.9 1.4 1/15/24 20:23 KMC14 0.6983.30.33 0.78
Benzene 0.28 0.035 1/15/24 20:23 KMC0.88 0.6980.110.011 0.034
1,3-Butadiene ND 0.035 1/15/24 20:23 KMCND0.6980.0770.029 0.065
2-Butanone (MEK)0.45 1.4 1/15/24 20:23 KMCJ1.3 0.6984.10.39 1.2
Carbon Disulfide ND 0.35 1/15/24 20:23 KMCND0.6981.10.067 0.21
Carbon Tetrachloride 0.053 0.035 1/15/24 20:23 KMC0.33 0.6980.220.010 0.063
Chloroform 0.019 0.035 1/15/24 20:23 KMCJ0.092 0.6980.170.0091 0.044
Chloromethane 0.55 0.070 1/15/24 20:23 KMC1.1 0.6980.140.014 0.029
Cyclohexane 0.062 0.035 1/15/24 20:23 KMC0.21 0.6980.120.015 0.053
1,2-Dibromoethane (EDB)ND 0.035 1/15/24 20:23 KMCND0.6980.270.012 0.089
1,4-Dichlorobenzene ND 0.035 1/15/24 20:23 KMCND0.6980.210.013 0.077
Dichlorodifluoromethane (Freon 12)0.58 0.035 1/15/24 20:23 KMC2.9 0.6980.170.015 0.072
1,1-Dichloroethane ND 0.035 1/15/24 20:23 KMCND0.6980.140.011 0.045
cis-1,2-Dichloroethylene ND 0.035 1/15/24 20:23 KMCND0.6980.140.011 0.043
trans-1,2-Dichloroethylene ND 0.035 1/15/24 20:23 KMCND0.6980.140.011 0.045
1,2-Dichloropropane ND 0.035 1/15/24 20:23 KMCND0.6980.160.0096 0.044
Ethanol 5.4 1.4 1/15/24 20:23 KMC10 0.6982.60.93 1.7
Ethyl Acetate ND 0.35 1/15/24 20:23 KMCND0.6981.30.10 0.36
Ethylbenzene 0.099 0.035 1/15/24 20:23 KMC0.43 0.6980.150.010 0.044
Heptane 0.096 0.035 1/15/24 20:23 KMC0.39 0.6980.140.022 0.090
Hexane 0.52 1.4 1/15/24 20:23 KMCJ1.8 0.6984.90.46 1.6
2-Hexanone (MBK)0.063 0.035 1/15/24 20:23 KMC0.26 0.6980.140.015 0.062
Isopropanol 0.66 1.4 1/15/24 20:23 KMCJ1.6 0.6983.40.44 1.1
Methyl tert-Butyl Ether (MTBE)ND 0.035 1/15/24 20:23 KMCND0.6980.130.017 0.062
Naphthalene ND 0.035 1/15/24 20:23 KMCND0.6980.180.023 0.12
Styrene 0.033 0.035 1/15/24 20:23 KMCJ0.14 0.6980.150.019 0.080
Tetrachloroethylene ND 0.035 1/15/24 20:23 KMCND0.6980.240.013 0.089
Tetrahydrofuran 0.25 0.35 1/15/24 20:23 KMCL-03, J 0.75 0.6981.00.072 0.21
Toluene 0.76 0.035 1/15/24 20:23 KMC2.9 0.6980.130.013 0.048
Trichloroethylene ND 0.035 1/15/24 20:23 KMCND0.6980.190.014 0.076
Trichlorofluoromethane (Freon 11)0.25 0.14 1/15/24 20:23 KMC1.4 0.6980.780.014 0.080
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)0.075 0.14 1/15/24 20:23 KMCJ0.58 0.6981.10.0077 0.059
1,2,4-Trimethylbenzene 0.086 0.035 1/15/24 20:23 KMC0.42 0.6980.170.016 0.079
Vinyl Acetate 0.53 0.70 1/15/24 20:23 KMCL-05, V-06, J 1.8 0.6982.50.12 0.44
Vinyl Chloride ND 0.035 1/15/24 20:23 KMCND0.6980.0890.016 0.041
m&p-Xylene 0.30 0.070 1/15/24 20:23 KMC1.3 0.6980.300.024 0.11
o-Xylene 0.12 0.035 1/15/24 20:23 KMC0.50 0.6980.150.013 0.055
Surrogates % Recovery % REC Limits
4-Bromofluorobenzene (1)97.5 1/15/24 20:2370-130
Page 10 of 24
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Sample Extraction Data
Prep Method: TO-15 Prep-EPA TO-15
Lab Number [Field ID]Batch Date
Pressure
Dilution
Pre
Dilution
Pre-Dil
Initial
mL
Pre-Dil
Final
mL
Default
Injection
mL
Actual
Injection
mL
24A0807-01 [IAS-2]B363467 1.5 1 N/A 1000 200 430 01/15/24
24A0807-02 [IAS-3]B363467 1.5 1 N/A 1000 200 430 01/15/24
24A0807-03 [IAS-4]B363467 1.74 1 N/A 1000 200 500 01/15/24
24A0807-04 [IAS-5]B363467 1.5 1 N/A 1000 200 430 01/15/24
24A0807-05 [IAS-DUP]B363467 1.74 1 N/A 1000 200 500 01/15/24
24A0807-06 [IAS-BKG]B363467 1.5 1 N/A 1000 200 430 01/15/24
Page 11 of 24
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ug/m3 Spike Level
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Flag/Qual Analyte
Air Toxics by EPA Compendium Methods - Quality Control
QUALITY CONTROL
RL
ppbv
Results RL Results ppbv
Batch B363467 - TO-15 Prep
Blank (B363467-BLK1)Prepared & Analyzed: 01/15/24
0.80NDAcetone
0.020NDBenzene
0.020ND1,3-Butadiene
0.80ND2-Butanone (MEK)
0.20NDCarbon Disulfide
0.020NDCarbon Tetrachloride
0.020NDChloroform
0.040NDChloromethane
0.020NDCyclohexane
0.020ND1,2-Dibromoethane (EDB)
0.020ND1,4-Dichlorobenzene
0.020NDDichlorodifluoromethane (Freon 12)
0.020ND1,1-Dichloroethane
0.020NDcis-1,2-Dichloroethylene
0.020NDtrans-1,2-Dichloroethylene
0.020ND1,2-Dichloropropane
0.80NDEthanol
0.20NDEthyl Acetate
0.020NDEthylbenzene
0.020NDHeptane
0.80NDHexane
0.020ND2-Hexanone (MBK)
0.80NDIsopropanol
0.020NDMethyl tert-Butyl Ether (MTBE)
0.020 B, J0.014Naphthalene
0.020NDStyrene
0.020NDTetrachloroethylene
0.20NDTetrahydrofuran
0.020NDToluene
0.020NDTrichloroethylene
0.080NDTrichlorofluoromethane (Freon 11)
0.080ND1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
0.020ND1,2,4-Trimethylbenzene
0.40NDVinyl Acetate
0.020NDVinyl Chloride
0.040NDm&p-Xylene
0.020NDo-Xylene
8.00 70-130Surrogate: 4-Bromofluorobenzene (1)94.87.58
Page 12 of 24
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ug/m3 Spike Level
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Flag/Qual Analyte
Air Toxics by EPA Compendium Methods - Quality Control
QUALITY CONTROL
RL
ppbv
Results RL Results ppbv
Batch B363467 - TO-15 Prep
LCS (B363467-BS1)Prepared & Analyzed: 01/15/24
5.00 70-13099.14.95Acetone
5.00 70-13094.34.72Benzene
5.00 70-1301005.021,3-Butadiene
5.00 70-13083.44.172-Butanone (MEK)
5.00 70-1301135.65Carbon Disulfide
5.00 70-13092.84.64Carbon Tetrachloride
5.00 70-1301015.03Chloroform
5.00 70-1301015.06Chloromethane
5.00 70-13091.54.58Cyclohexane
5.00 70-13091.74.581,2-Dibromoethane (EDB)
5.00 70-1301045.181,4-Dichlorobenzene
5.00 70-1301145.69Dichlorodifluoromethane (Freon 12)
5.00 70-1301075.331,1-Dichloroethane
5.00 70-13093.44.67cis-1,2-Dichloroethylene
5.00 70-1301085.42trans-1,2-Dichloroethylene
5.00 70-13094.64.731,2-Dichloropropane
5.00 70-1301276.36Ethanol
5.00 70-13079.33.97Ethyl Acetate
5.00 70-13097.84.89Ethylbenzene
5.00 70-13090.84.54Heptane
5.00 70-13094.54.73Hexane
5.00 70-13098.44.922-Hexanone (MBK)
5.00 70-1301015.04Isopropanol
5.00 70-1301095.43Methyl tert-Butyl Ether (MTBE)
3.68 L-05, V-0670-1301324.85Naphthalene *
5.00 70-13095.04.75Styrene
5.00 70-13091.64.58Tetrachloroethylene
5.00 L-0370-13066.33.31Tetrahydrofuran *
5.00 70-13094.64.73Toluene
5.00 70-13089.84.49Trichloroethylene
5.00 70-1301095.47Trichlorofluoromethane (Freon 11)
5.00 70-1301095.431,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
5.00 70-13095.54.781,2,4-Trimethylbenzene
5.00 L-05, V-0670-1301316.56Vinyl Acetate *
5.00 70-1301075.33Vinyl Chloride
10.0 70-13010110.1m&p-Xylene
5.00 70-13098.44.92o-Xylene
8.00 70-130Surrogate: 4-Bromofluorobenzene (1)98.07.84
Page 13 of 24
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Note: Blank Subtraction is not performed unless otherwise noted
*QC result is outside of established limits.
†Wide recovery limits established for difficult compound.
‡Wide RPD limits established for difficult compound.
#Data exceeded client recommended or regulatory level
RL Reporting Limit
MDL Method Detection Limit
RPD Relative Percent Difference
LCS Laboratory Control Sample
Laboratory Control SampleLCS Dup Duplicate Laboratory Control Sample
MS Matrix Spike Sample
MS Dup Duplicate Matrix Spike Sample
REC Recovery
QC Quality Control
ppbv Parts per billion volume
EPA United States Environmental Protection Agency
Percent Recovery% REC
ND Not Detected
Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the
calculation which have not been rounded.
Not ApplicableN/A
DL Detection Limit
Not CalculatedNC
LFB/LCS Lab Fortified Blank/Lab Control Sample
ORP Oxidation-Reduction Potential
Not dry weight correctedwet
Percent weight% wt
KilogramKg
Gramg
Milligrammg
Microgramµg
Nanogramng
LiterL
MillilitermL
Microliter L
Cubic Meterm3
Extractable Petroleum HydrocarbonsEPH
Volatile Petroleum HydrocarbonsVPH
Air Petroleum HydrocarbonsAPH
Flame Ionization DetectorFID
Photo Ionization DetectorPID
FLAG/QUALIFIER SUMMARY
Analyte is found in the associated laboratory blank as well as in the sample.B
Reported result is estimated. Value reported over verified calibration range.E
Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated
concentration (CLP J-Flag).
J
Laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this
compound is likely to be biased on the low side.
L-03
Laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this
compound is likely to be biased on the high side.
L-05
Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side for
this compound.
V-06
Page 14 of 24
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYST
Report Queue StationSTATION
Rebecca FaustRLF
Kristen M CoutureKMC
Catherine M. RouleauCMR
Page 15 of 24
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
INTERNAL STANDARD AREA AND RT SUMMARY
EPA TO-15
RTResponseInternal Standard Area %RT DiffResponse
Reference
RT
Reference Area %
Limits
RT Diff
Limit Q
Initial Cal Check (S091464-ICV1 )Lab File ID: L23A214020.D Analyzed: 08/02/23 23:42
Bromochloromethane (1)300782 2.867 314027 2.871 60 - 14096 -0.0040 +/-0.50
1,4-Difluorobenzene (1)878479 3.54 895773 3.54 60 - 14098 0.0000 +/-0.50
Chlorobenzene-d5 (1)823159 5.202 837397 5.202 60 - 14098 0.0000 +/-0.50
INTERNAL STANDARD AREA AND RT SUMMARY
EPA TO-15
RTResponseInternal Standard Area %RT DiffResponse
Reference
RT
Reference Area %
Limits
RT Diff
Limit Q
Calibration Check (S099219-CCV1 )Lab File ID: L24A015003.D Analyzed: 01/15/24 10:02
Bromochloromethane (1)261026 2.865 314027 2.871 60 - 14083 -0.0060 +/-0.50
1,4-Difluorobenzene (1)766255 3.539 895773 3.54 60 - 14086 -0.0010 +/-0.50
Chlorobenzene-d5 (1)687264 5.196 837397 5.202 60 - 14082 -0.0060 +/-0.50
LCS (B363467-BS1 )Lab File ID: L24A015004.D Analyzed: 01/15/24 10:28
Bromochloromethane (1)266528 2.865 261026 2.865 60 - 140102 0.0000 +/-0.50
1,4-Difluorobenzene (1)775244 3.539 766255 3.539 60 - 140101 0.0000 +/-0.50
Chlorobenzene-d5 (1)701161 5.196 687264 5.196 60 - 140102 0.0000 +/-0.50
Blank (B363467-BLK1 )Lab File ID: L24A015007.D Analyzed: 01/15/24 12:00
Bromochloromethane (1)257260 2.87 261026 2.865 60 - 14099 0.0050 +/-0.50
1,4-Difluorobenzene (1)725549 3.538 766255 3.539 60 - 14095 -0.0010 +/-0.50
Chlorobenzene-d5 (1)663292 5.194 687264 5.196 60 - 14097 -0.0020 +/-0.50
IAS-2 (24A0807-01 )Lab File ID: L24A015017.D Analyzed: 01/15/24 17:35
Bromochloromethane (1)241300 2.87 261026 2.865 60 - 14092 0.0050 +/-0.50
1,4-Difluorobenzene (1)716611 3.538 766255 3.539 60 - 14094 -0.0010 +/-0.50
Chlorobenzene-d5 (1)642554 5.196 687264 5.196 60 - 14093 0.0000 +/-0.50
IAS-3 (24A0807-02 )Lab File ID: L24A015018.D Analyzed: 01/15/24 18:08
Bromochloromethane (1)238624 2.864 261026 2.865 60 - 14091 -0.0010 +/-0.50
1,4-Difluorobenzene (1)698897 3.538 766255 3.539 60 - 14091 -0.0010 +/-0.50
Chlorobenzene-d5 (1)645143 5.195 687264 5.196 60 - 14094 -0.0010 +/-0.50
IAS-4 (24A0807-03 )Lab File ID: L24A015019.D Analyzed: 01/15/24 18:42
Bromochloromethane (1)240128 2.87 261026 2.865 60 - 14092 0.0050 +/-0.50
1,4-Difluorobenzene (1)710737 3.538 766255 3.539 60 - 14093 -0.0010 +/-0.50
Chlorobenzene-d5 (1)639586 5.196 687264 5.196 60 - 14093 0.0000 +/-0.50
IAS-5 (24A0807-04 )Lab File ID: L24A015020.D Analyzed: 01/15/24 19:15
Bromochloromethane (1)247226 2.87 261026 2.865 60 - 14095 0.0050 +/-0.50
1,4-Difluorobenzene (1)732870 3.538 766255 3.539 60 - 14096 -0.0010 +/-0.50
Chlorobenzene-d5 (1)656344 5.196 687264 5.196 60 - 14096 0.0000 +/-0.50
Page 16 of 24
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
INTERNAL STANDARD AREA AND RT SUMMARY
EPA TO-15
RTResponseInternal Standard Area %RT DiffResponse
Reference
RT
Reference Area %
Limits
RT Diff
Limit Q
IAS-DUP (24A0807-05 )Lab File ID: L24A015021.D Analyzed: 01/15/24 19:50
Bromochloromethane (1)241793 2.865 261026 2.865 60 - 14093 0.0000 +/-0.50
1,4-Difluorobenzene (1)714452 3.538 766255 3.539 60 - 14093 -0.0010 +/-0.50
Chlorobenzene-d5 (1)642816 5.195 687264 5.196 60 - 14094 -0.0010 +/-0.50
IAS-BKG (24A0807-06 )Lab File ID: L24A015022.D Analyzed: 01/15/24 20:23
Bromochloromethane (1)250801 2.87 261026 2.865 60 - 14096 0.0050 +/-0.50
1,4-Difluorobenzene (1)728496 3.538 766255 3.539 60 - 14095 -0.0010 +/-0.50
Chlorobenzene-d5 (1)666513 5.196 687264 5.196 60 - 14097 0.0000 +/-0.50
Page 17 of 24
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CONTINUING CALIBRATION CHECK
EPA TO-15
S099219-CCV1
COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL
CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR
STD
1.158144A 3.2 305.16 1.1222555.00Acetone
0.7286285A 0.4 305.02 0.72542935.00Benzene
0.5986101A 8.6 305.43 0.5511495.001,3-Butadiene
1.197343A -13.3 304.33 1.3816045.002-Butanone (MEK)
2.379079A 15.3 305.76 2.0637575.00Carbon Disulfide
0.5245439A 2.6 305.13 0.51103685.00Carbon Tetrachloride
0.4226705A 2.7 305.13 0.4117515.00Chloroethane
1.548707A 7.6 305.38 1.4393325.00Chloroform
0.6548436A 7.3 305.37 0.61014595.00Chloromethane
0.2848472A -6.0 304.70 0.30302865.00Cyclohexane
0.5036993A -0.8 304.96 0.50764495.001,2-Dibromoethane (EDB)
0.6414094A 10.6 305.53 0.58013655.001,4-Dichlorobenzene
2.15409A 21.8 306.09 1.7680795.00Dichlorodifluoromethane (Freon 12)
1.562486A 12.2 305.61 1.3928245.001,1-Dichloroethane
0.9210669A 1.3 305.07 0.9089525.00cis-1,2-Dichloroethylene
1.273449A 12.9 305.64 1.1282325.00trans-1,2-Dichloroethylene
0.2656828A 2.1 305.10 0.26019485.001,2-Dichloropropane
0.1806287A 4.3 305.21 0.17324145.00Ethanol
0.1964249A -17.8 304.11 0.23901695.00Ethyl Acetate
1.248561A 6.1 305.30 1.1769025.00Ethylbenzene
0.2168218A -5.2 304.74 0.22868475.00Heptane
0.694104A -6.7 304.66 0.74421785.00Hexane
0.6427178A 7.2 305.36 0.59938995.002-Hexanone (MBK)
1.293952A 9.6 305.48 1.1806995.00Isopropanol
2.408753A 13.0 305.65 2.1308915.00Methyl tert-Butyl Ether (MTBE)
1.434474A 50.3 *307.51 0.9546185.00Naphthalene
0.3682821A -9.6 304.52 0.40752365.00Propene
0.7012339A 5.0 305.25 0.66801735.00Styrene
0.4060041A -2.7 304.86 0.41745665.00Tetrachloroethylene
0.7091217A -22.2 303.89 0.91119635.00Tetrahydrofuran
0.9373516A -0.1 304.99 0.93858055.00Toluene
0.324078A -3.5 304.83 0.33565985.00Trichloroethylene
2.138607A 17.7 305.89 1.8167435.00Trichlorofluoromethane (Freon 11)
1.719976A 19.7 305.99 1.4365825.001,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)
1.085897A 6.3 305.32 1.0213025.001,2,4-Trimethylbenzene
2.05612A 40.5 *307.02 1.4635415.00Vinyl Acetate
0.8254503A 16.2 305.81 0.71057575.00Vinyl Chloride
1.050142A 8.1 3010.8 0.971150610.0m&p-Xylene
Page 18 of 24
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CONTINUING CALIBRATION CHECK
EPA TO-15
S099219-CCV1
COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL
CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR
STD
1.016248A 6.4 305.32 0.95505185.00o-Xylene
* Values outside of QC limits
# Column to be used to flag Response Factor and %Diff/Drift values with an asterisk
Page 19 of 24
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
EPA TO-15 in Air
NY,ME,NHAcetone
FL,NJ,NY,ME,NH,VABenzene
NJ,NY,ME,NH,VA1,3-Butadiene
FL,NJ,NY,ME,NH,VA2-Butanone (MEK)
NJ,NY,ME,NH,VACarbon Disulfide
FL,NJ,NY,ME,NH,VACarbon Tetrachloride
FL,NJ,NY,ME,NH,VAChloroform
FL,NJ,NY,ME,NH,VAChloromethane
NJ,NY,ME,NH,VACyclohexane
NJ,NY,ME,NH1,2-Dibromoethane (EDB)
FL,NJ,NY,ME,NH,VA1,4-Dichlorobenzene
NY,ME,NHDichlorodifluoromethane (Freon 12)
FL,NJ,NY,ME,NH,VA1,1-Dichloroethane
FL,NY,ME,NH,VAcis-1,2-Dichloroethylene
NJ,NY,ME,NH,VAtrans-1,2-Dichloroethylene
FL,NJ,NY,ME,NH,VA1,2-Dichloropropane
FL,NJ,NY,ME,NH,VAEthylbenzene
NJ,NY,ME,NH,VAHeptane
FL,NJ,NY,ME,NH,VAHexane
NY,ME,NHIsopropanol
FL,NJ,NY,ME,NH,VAMethyl tert-Butyl Ether (MTBE)
NY,ME,NHNaphthalene
FL,NJ,NY,ME,NH,VAStyrene
FL,NJ,NY,ME,NH,VATetrachloroethylene
FL,NJ,NY,ME,NH,VAToluene
FL,NJ,NY,ME,NH,VATrichloroethylene
NY,ME,NHTrichlorofluoromethane (Freon 11)
NJ,NY,ME,NH,VA1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)
NJ,NY,ME,NH1,2,4-Trimethylbenzene
FL,NJ,NY,ME,NH,VAVinyl Acetate
FL,NJ,NY,ME,NH,VAVinyl Chloride
FL,NJ,NY,ME,NH,VAm&p-Xylene
FL,NJ,NY,ME,NH,VAo-Xylene
Con-Test, a Pace Environmental Laboratory, operates under the following certifications and accreditations:
Code Description Number Expires
10899 NELAPNew York State Department of HealthNY 04/1/2024
2516 NELAPNew Hampshire Environmental LabNH 02/5/2024
MA007 NELAPNew Jersey DEPNJ 06/30/2024
E871027 NELAPFlorida Department of HealthFL 06/30/2024
MA00100State of MaineME 06/9/2025
460217Commonwealth of VirginiaVA 12/14/2024
Page 20 of 24
Page 21 of 24
Page 22 of 24
Page 23 of 24
Page 24 of 24

Appendix G
DEQ Risk Calculators

Version Date:
Basis:
Site Name:
Site Address:
DEQ Section:
Site ID:
Exposure Unit ID:
Submittal Date:
Reviewed By:
Prepared By:Hart & Hickman
Hart & Hickman
North Carolina Department of Environmental Quality
Risk Calculator
February 2024
November 2023 EPA RSL Table
Sub-Slab Soil Gas Sample MP-3
Crayton Printing
Distribution Street and Dunavant Street
DWM Brownfields Redevelopment Section
24025-20-060
North Carolina DEQ Risk Calculator
Table of Contents
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Sub-Slab Soil Gas Sample MP-3
Form No.
Input Form 1A Complete Exposure Pathways
Input Form 1B Exposure Factors and Target Risks
Input Form 1C Contaminant Migration Parameters
Input Form 1D Sample Statistics
Input Form 2A Soil Exposure Point Concentration Table
Input Form 2B Groundwater Exposure Point Concentration Table
Input Form 2C Surface Water Exposure Point Concentration Table
Input Form 2D Soil Gas Exposure Point Concentration Table
Input Form 2E Indoor Air Exposure Point Concentration Table
Output Form 1A Risk for Individual Pathways
Output Form 1B Sitewide Risk
Output Form 2A Resident Soil
Output Form 2B Resident Groundwater Use
Output Form 2C Non-Residential Worker Soil
Output Form 2D Non-Residential Worker Groundwater Use
Output Form 2E Construction Worker Soil
Output Form 2F Recreator/Trespasser Soil
Output Form 2G Recreator/Trespasser Surface Water
Output Form 3A Resident Groundwater to Indoor Air
Output Form 3B Resident Soil Gas to Indoor Air
Output Form 3C Resident Indoor Air
Output Form 3D Non-Residential Worker Groundwater to Indoor Air
Output Form 3E Non-Residential Worker Soil Gas to Indoor Air
Output Form 3F Non-Residential Worker Indoor Air
Output Form 4A Soil to Groundwater - Forward Mode
Output Form 4B Groundwater to Groundwater - Forward Mode
Output Form 4C Soil to Surface Water - Forward Mode
Output Form 4D Groundwater to Surface Water - Forward Mode
Output Form 4E Soil to Groundwater - Backward Mode
Output Form 4F Groundwater to Groundwater - Backward Mode
Output Form 4G Soil to Surface Water - Backward Mode
Output Form 4H Groundwater to Surface Water - Backward Mode
Output Section 4 - Contaminant Migration Worksheets
Output Section 3 - Vapor Intrusion Calculators
Description
DATA INPUT SHEETS
Check box
if included
Input Section 1 - Exposure Pathways & Parameters
Input Section 2 - Exposure Point Concentrations
DATA OUTPUT SHEETS
Output Section 1 - Summary Output for All Calculators
Output Section 2 - Direct Contact Soil and Groundwater Calculators
North Carolina DEQ Risk Calculator
Complete Exposure Pathways
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Sub-Slab Soil Gas Sample MP-3
Note: Risk output will only be calculated for complete exposure pathways.
Receptor Pathway
Check box if
pathway
complete
Soil
Groundwater Use
Soil
Groundwater Use
Construction Worker Soil
Soil
Surface Water
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Source Soil
Source Groundwater
Source Soil
Source Groundwater
Input Form 1A
VAPOR INTRUSION PATHWAYS
DIRECT CONTACT SOIL AND WATER PATHWAYS
Resident
Non-Residential Worker
Recreator/Trespasser
Resident
Non-Residential Worker
CONTAMINANT MIGRATION PATHWAYS
Groundwater
Surface Water
North Carolina DEQ Risk Calculator
Exposure Point Concentrations
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Sub-Slab Soil Gas Sample MP-3
Description of Exposure Point Concentration Selection:
Exposure Point
Concentration
(ug/m3)
Notes:CAS Number Chemical
Minimum
Concentration
(Qualifier)
Maximum
Concentration
(Qualifier)
Units
Location of
Maximum
Concentration
Detection
Frequency
Range of
Detection
Limits
Concentration
Used for
Screening
Background
Value
Screening
Toxicity Value
(Screening
Level) (n/c)
Potential
ARAR/TBC
Value
Potential
ARAR/TBC
Source
COPC Flag
(Y/N)
Rationale for
Selection or
Deletion
28 67-64-1 Acetone 3
0.27 3
2.9 106-99-0 Butadiene, 1,3-3
0.55 3
0.27 3
0.68 3
2.7 75-71-8 Dichlorodifluoromethane 3
0.38 3
23 109-99-9 ~Tetrahydrofuran 3
26 67-63-0 Isopropanol 3
27 78-93-3 Methyl Ethyl Ketone (2-Butanone)3
1 108-88-3 Toluene 3
1.5 3
0.98 95-63-6 Trimethylbenzene, 1,2,4-3
1 3
0.59 3
Input Form 2D
Soil Gas Exposure Point Concentration Table
Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.
If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Sub-Slab Soil Gas Sample MP-3
CAS # Chemical Name:
Soil Gas
Concentration
(ug/m3)
Calculated
Indoor Air
Concentration
(ug/m3)
Target Indoor
Air Conc. for
Carcinogens @
TCR = 1E-06
Conc. for Non-
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non-
Carcinogenic
Hazard
Quotient
67-64-1
71-43-2
106-99-0
56-23-5
67-66-3
74-87-3
75-71-8
100-41-4
109-99-9
67-63-0
78-93-3
108-88-3
75-69-4
95-63-6
108-38-3
95-47-6
Cumulative: 1.1E-06 4.8E-02
Output Form 3B
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion
risk, no risk values are calculated for these chemicals.
North Carolina DEQ Risk Calculator
Risk for Individual Pathways
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Sub-Slab Soil Gas Sample MP-3
Receptor Pathway Hazard Index Risk exceeded?
Soil NC NC NC
NC
NC
NC
NC
NC
NC
Receptor Pathway Carcinogenic Hazard Index Risk exceeded?
Groundwater to Indoor Air NC NC NC
NO
NC
NC
NC
NC
Pathway Source
Source Soil NC
Source Groundwater NC
Source Soil NC
Source Groundwater NC
3. NM = Not modeled, user did not check this pathway as complete.
4. NC = Pathway not calculated, required contaminant migration parameters were not entered.
DIRECT CONTACT SOIL AND WATER CALCULATORS
Resident
Non-Residential Worker
Recreator/Trespasser
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the
NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based
closure.
Surface Water Exceedence of 2B at Receptor?
Exceedence of 2B at Receptor?
VAPOR INTRUSION CALCULATORS
Resident
Non-Residential Worker
CONTAMINANT MIGRATION CALCULATORS
Target Receptor Concentrations Exceeded?
Groundwater Exceedence of 2L at Receptor?
Exceedence of 2L at Receptor?
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead
concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
Notes:
North Carolina DEQ Risk Calculator
Version Date:
Basis:
Site Name:
Site Address:
DEQ Section:
Site ID:
Exposure Unit ID:
Submittal Date:
Reviewed By:
Prepared By:Hart & Hickman
North Carolina Department of Environmental Quality
Risk Calculator
February 2024
November 2023 EPA RSL Table
Sub-Slab Soil Gas Sample MP-6
Crayton Printing
Distribution Street and Dunavant Street
DWM Brownfields Redevelopment Section
24025-20-060
North Carolina DEQ Risk Calculator
Table of Contents
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Sub-Slab Soil Gas Sample MP-6
Form No.
Input Form 1A Complete Exposure Pathways
Input Form 1B Exposure Factors and Target Risks
Input Form 1C Contaminant Migration Parameters
Input Form 1D Sample Statistics
Input Form 2A Soil Exposure Point Concentration Table
Input Form 2B Groundwater Exposure Point Concentration Table
Input Form 2C Surface Water Exposure Point Concentration Table
Input Form 2D Soil Gas Exposure Point Concentration Table
Input Form 2E Indoor Air Exposure Point Concentration Table
Output Form 1A Risk for Individual Pathways
Output Form 1B Sitewide Risk
Output Form 2A Resident Soil
Output Form 2B Resident Groundwater Use
Output Form 2C Non-Residential Worker Soil
Output Form 2D Non-Residential Worker Groundwater Use
Output Form 2E Construction Worker Soil
Output Form 2F Recreator/Trespasser Soil
Output Form 2G Recreator/Trespasser Surface Water
Output Form 3A Resident Groundwater to Indoor Air
Output Form 3B Resident Soil Gas to Indoor Air
Output Form 3C Resident Indoor Air
Output Form 3D Non-Residential Worker Groundwater to Indoor Air
Output Form 3E Non-Residential Worker Soil Gas to Indoor Air
Output Form 3F Non-Residential Worker Indoor Air
Output Form 4A Soil to Groundwater - Forward Mode
Output Form 4B Groundwater to Groundwater - Forward Mode
Output Form 4C Soil to Surface Water - Forward Mode
Output Form 4D Groundwater to Surface Water - Forward Mode
Output Form 4E Soil to Groundwater - Backward Mode
Output Form 4F Groundwater to Groundwater - Backward Mode
Output Form 4G Soil to Surface Water - Backward Mode
Output Form 4H Groundwater to Surface Water - Backward Mode
Output Section 4 - Contaminant Migration Worksheets
Output Section 3 - Vapor Intrusion Calculators
Description
DATA INPUT SHEETS
Check box
if included
Input Section 1 - Exposure Pathways & Parameters
Input Section 2 - Exposure Point Concentrations
DATA OUTPUT SHEETS
Output Section 1 - Summary Output for All Calculators
Output Section 2 - Direct Contact Soil and Groundwater Calculators
North Carolina DEQ Risk Calculator
Complete Exposure Pathways
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Sub-Slab Soil Gas Sample MP-6
Note: Risk output will only be calculated for complete exposure pathways.
Receptor Pathway
Check box if
pathway
complete
Soil
Groundwater Use
Soil
Groundwater Use
Construction Worker Soil
Soil
Surface Water
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Source Soil
Source Groundwater
Source Soil
Source Groundwater
Input Form 1A
VAPOR INTRUSION PATHWAYS
DIRECT CONTACT SOIL AND WATER PATHWAYS
Resident
Non-Residential Worker
Recreator/Trespasser
Resident
Non-Residential Worker
CONTAMINANT MIGRATION PATHWAYS
Groundwater
Surface Water
North Carolina DEQ Risk Calculator
Exposure Point Concentrations
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Sub-Slab Soil Gas Sample MP-6
Description of Exposure Point Concentration Selection:
Exposure Point
Concentration
(ug/m3)
Notes:CAS Number Chemical
Minimum
Concentration
(Qualifier)
Maximum
Concentration
(Qualifier)
Units
Location of
Maximum
Concentration
Detection
Frequency
Range of
Detection
Limits
Concentration
Used for
Screening
Background
Value
Screening
Toxicity Value
(Screening
Level) (n/c)
Potential
ARAR/TBC
Value
Potential
ARAR/TBC
Source
COPC Flag
(Y/N)
Rationale for
Selection or
Deletion
11000 67-64-1 Acetone 3
13000 109-99-9 ~Tetrahydrofuran 3
2800 78-93-3 Methyl Ethyl Ketone (2-Butanone)3
Input Form 2D
Soil Gas Exposure Point Concentration Table
Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.
If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations
North Carolina DEQ Risk Calculator
Risk for Individual Pathways
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Sub-Slab Soil Gas Sample MP-6
Receptor Pathway Hazard Index Risk exceeded?
Soil NC NC NC
NC
NC
NC
NC
NC
NC
Receptor Pathway Carcinogenic Hazard Index Risk exceeded?
Groundwater to Indoor Air NC NC NC
NO
NC
NC
NC
NC
Pathway Source
Source Soil NC
Source Groundwater NC
Source Soil NC
Source Groundwater NC
3. NM = Not modeled, user did not check this pathway as complete.
4. NC = Pathway not calculated, required contaminant migration parameters were not entered.
DIRECT CONTACT SOIL AND WATER CALCULATORS
Resident
Non-Residential Worker
Recreator/Trespasser
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the
NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based
closure.
Surface Water Exceedence of 2B at Receptor?
Exceedence of 2B at Receptor?
VAPOR INTRUSION CALCULATORS
Resident
Non-Residential Worker
CONTAMINANT MIGRATION CALCULATORS
Target Receptor Concentrations Exceeded?
Groundwater Exceedence of 2L at Receptor?
Exceedence of 2L at Receptor?
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead
concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
Notes:
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Sub-Slab Soil Gas Sample MP-6
CAS # Chemical Name:
Soil Gas
Concentration
(ug/m3)
Calculated
Indoor Air
Concentration
(ug/m3)
Target Indoor
Air Conc. for
Carcinogens @
TCR = 1E-06
Conc. for Non-
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non-
Carcinogenic
Hazard
Quotient
67-64-1
109-99-9
78-93-3
Cumulative: 0.0E+00 2.0E-01
Output Form 3B
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion
risk, no risk values are calculated for these chemicals.
North Carolina DEQ Risk Calculator
Version Date:
Basis:
Site Name:
Site Address:
DEQ Section:
Site ID:
Exposure Unit ID:
Submittal Date:
Reviewed By:
Risk Calculator
February 2024
November 2023 EPA RSL Table
Sub-Slab Soil Gas Sample MP-8
Crayton Printing
Distribution Street and Dunavant Street
DWM Brownfields Redevelopment Section
24025-20-060
Prepared By:Hart & Hickman
North Carolina DEQ Risk Calculator
Table of Contents
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Sub-Slab Soil Gas Sample MP-8
Form No.
Input Form 1A Complete Exposure Pathways
Input Form 1B Exposure Factors and Target Risks
Input Form 1C Contaminant Migration Parameters
Input Form 1D Sample Statistics
Input Form 2A Soil Exposure Point Concentration Table
Input Form 2B Groundwater Exposure Point Concentration Table
Input Form 2C Surface Water Exposure Point Concentration Table
Input Form 2D Soil Gas Exposure Point Concentration Table
Input Form 2E Indoor Air Exposure Point Concentration Table
Output Form 1A Risk for Individual Pathways
Output Form 1B Sitewide Risk
Output Form 2A Resident Soil
Output Form 2B Resident Groundwater Use
Output Form 2C Non-Residential Worker Soil
Output Form 2D Non-Residential Worker Groundwater Use
Output Form 2E Construction Worker Soil
Output Form 2F Recreator/Trespasser Soil
Output Form 2G Recreator/Trespasser Surface Water
Output Form 3A Resident Groundwater to Indoor Air
Output Form 3B Resident Soil Gas to Indoor Air
Output Form 3C Resident Indoor Air
Output Form 3D Non-Residential Worker Groundwater to Indoor Air
Output Form 3E Non-Residential Worker Soil Gas to Indoor Air
Output Form 3F Non-Residential Worker Indoor Air
Output Form 4A Soil to Groundwater - Forward Mode
Output Form 4B Groundwater to Groundwater - Forward Mode
Output Form 4C Soil to Surface Water - Forward Mode
Output Form 4D Groundwater to Surface Water - Forward Mode
Output Form 4E Soil to Groundwater - Backward Mode
Output Form 4F Groundwater to Groundwater - Backward Mode
Output Form 4G Soil to Surface Water - Backward Mode
Output Form 4H Groundwater to Surface Water - Backward Mode
Output Section 4 - Contaminant Migration Worksheets
Output Section 3 - Vapor Intrusion Calculators
Description
DATA INPUT SHEETS
Check box
if included
Input Section 1 - Exposure Pathways & Parameters
Input Section 2 - Exposure Point Concentrations
DATA OUTPUT SHEETS
Output Section 1 - Summary Output for All Calculators
Output Section 2 - Direct Contact Soil and Groundwater Calculators
North Carolina DEQ Risk Calculator
Complete Exposure Pathways
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Sub-Slab Soil Gas Sample MP-8
Note: Risk output will only be calculated for complete exposure pathways.
Receptor Pathway
Check box if
pathway
complete
Soil
Groundwater Use
Soil
Groundwater Use
Construction Worker Soil
Soil
Surface Water
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Source Soil
Source Groundwater
Source Soil
Source Groundwater
Resident
Non-Residential Worker
CONTAMINANT MIGRATION PATHWAYS
Groundwater
Surface Water
Input Form 1A
VAPOR INTRUSION PATHWAYS
DIRECT CONTACT SOIL AND WATER PATHWAYS
Resident
Non-Residential Worker
Recreator/Trespasser
North Carolina DEQ Risk Calculator
Exposure Point Concentrations
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Sub-Slab Soil Gas Sample MP-8
Description of Exposure Point Concentration Selection:
Exposure Point
Concentration
(ug/m3)
Notes:CAS Number Chemical
Minimum
Concentration
(Qualifier)
Maximum
Concentration
(Qualifier)
Units
Location of
Maximum
Concentration
Detection
Frequency
Range of
Detection
Limits
Concentration
Used for
Screening
Background
Value
Screening
Toxicity Value
(Screening
Level) (n/c)
Potential
ARAR/TBC
Value
Potential
ARAR/TBC
Source
COPC Flag
(Y/N)
Rationale for
Selection or
Deletion
14000 67-64-1 Acetone 3
28 3
80 3
30000 109-99-9 ~Tetrahydrofuran 3
6100 78-93-3 Methyl Ethyl Ketone (2-Butanone)3
Input Form 2D
Soil Gas Exposure Point Concentration Table
Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.
If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations
North Carolina DEQ Risk Calculator
Risk for Individual Pathways
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Sub-Slab Soil Gas Sample MP-8
Receptor Pathway Hazard Index Risk exceeded?
Soil NC NC NC
NC
NC
NC
NC
NC
NC
Receptor Pathway Carcinogenic Hazard Index Risk exceeded?
Groundwater to Indoor Air NC NC NC
NO
NC
NC
NC
NC
Pathway Source
Source Soil NC
Source Groundwater NC
Source Soil NC
Source Groundwater NC
Groundwater Exceedence of 2L at Receptor?
Exceedence of 2L at Receptor?
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead
concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
Notes:
3. NM = Not modeled, user did not check this pathway as complete.
4. NC = Pathway not calculated, required contaminant migration parameters were not entered.
DIRECT CONTACT SOIL AND WATER CALCULATORS
Resident
Non-Residential Worker
Recreator/Trespasser
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the
NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based
closure.
Surface Water Exceedence of 2B at Receptor?
Exceedence of 2B at Receptor?
VAPOR INTRUSION CALCULATORS
Resident
Non-Residential Worker
CONTAMINANT MIGRATION CALCULATORS
Target Receptor Concentrations Exceeded?
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Sub-Slab Soil Gas Sample MP-8
CAS # Chemical Name:
Soil Gas
Concentration
(ug/m3)
Calculated
Indoor Air
Concentration
(ug/m3)
Target Indoor
Air Conc. for
Carcinogens @
TCR = 1E-06
Conc. for Non-
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non-
Carcinogenic
Hazard
Quotient
67-64-1
74-87-3
75-71-8
109-99-9 4.3E-01
78-93-3
Cumulative: 0.0E+00 5.0E-01
Output Form 3B
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion
risk, no risk values are calculated for these chemicals.
North Carolina DEQ Risk Calculator
Version Date:
Basis:
Site Name:
Site Address:
DEQ Section:
Site ID:
Exposure Unit ID:
Submittal Date:
Reviewed By:
Risk Calculator
February 2024
November 2023 EPA RSL Table
Sub-Slab Soil Gas Sample MP-9
Crayton Printing
Distribution Street and Dunavant Street
DWM Brownfields Redevelopment Section
24025-20-060
Prepared By:Hart & Hickman
North Carolina DEQ Risk Calculator
Table of Contents
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Sub-Slab Soil Gas Sample MP-9
Form No.
Input Form 1A Complete Exposure Pathways
Input Form 1B Exposure Factors and Target Risks
Input Form 1C Contaminant Migration Parameters
Input Form 1D Sample Statistics
Input Form 2A Soil Exposure Point Concentration Table
Input Form 2B Groundwater Exposure Point Concentration Table
Input Form 2C Surface Water Exposure Point Concentration Table
Input Form 2D Soil Gas Exposure Point Concentration Table
Input Form 2E Indoor Air Exposure Point Concentration Table
Output Form 1A Risk for Individual Pathways
Output Form 1B Sitewide Risk
Output Form 2A Resident Soil
Output Form 2B Resident Groundwater Use
Output Form 2C Non-Residential Worker Soil
Output Form 2D Non-Residential Worker Groundwater Use
Output Form 2E Construction Worker Soil
Output Form 2F Recreator/Trespasser Soil
Output Form 2G Recreator/Trespasser Surface Water
Output Form 3A Resident Groundwater to Indoor Air
Output Form 3B Resident Soil Gas to Indoor Air
Output Form 3C Resident Indoor Air
Output Form 3D Non-Residential Worker Groundwater to Indoor Air
Output Form 3E Non-Residential Worker Soil Gas to Indoor Air
Output Form 3F Non-Residential Worker Indoor Air
Output Form 4A Soil to Groundwater - Forward Mode
Output Form 4B Groundwater to Groundwater - Forward Mode
Output Form 4C Soil to Surface Water - Forward Mode
Output Form 4D Groundwater to Surface Water - Forward Mode
Output Form 4E Soil to Groundwater - Backward Mode
Output Form 4F Groundwater to Groundwater - Backward Mode
Output Form 4G Soil to Surface Water - Backward Mode
Output Form 4H Groundwater to Surface Water - Backward Mode
Output Section 4 - Contaminant Migration Worksheets
Output Section 3 - Vapor Intrusion Calculators
Description
DATA INPUT SHEETS
Check box
if included
Input Section 1 - Exposure Pathways & Parameters
Input Section 2 - Exposure Point Concentrations
DATA OUTPUT SHEETS
Output Section 1 - Summary Output for All Calculators
Output Section 2 - Direct Contact Soil and Groundwater Calculators
North Carolina DEQ Risk Calculator
Complete Exposure Pathways
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Sub-Slab Soil Gas Sample MP-9
Note: Risk output will only be calculated for complete exposure pathways.
Receptor Pathway
Check box if
pathway
complete
Soil
Groundwater Use
Soil
Groundwater Use
Construction Worker Soil
Soil
Surface Water
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Source Soil
Source Groundwater
Source Soil
Source Groundwater
Resident
Non-Residential Worker
CONTAMINANT MIGRATION PATHWAYS
Groundwater
Surface Water
Input Form 1A
VAPOR INTRUSION PATHWAYS
DIRECT CONTACT SOIL AND WATER PATHWAYS
Resident
Non-Residential Worker
Recreator/Trespasser
North Carolina DEQ Risk Calculator
Exposure Point Concentrations
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Sub-Slab Soil Gas Sample MP-9
Description of Exposure Point Concentration Selection:
Exposure Point
Concentration
(ug/m3)
Notes:CAS Number Chemical
Minimum
Concentration
(Qualifier)
Maximum
Concentration
(Qualifier)
Units
Location of
Maximum
Concentration
Detection
Frequency
Range of
Detection
Limits
Concentration
Used for
Screening
Background
Value
Screening
Toxicity Value
(Screening
Level) (n/c)
Potential
ARAR/TBC
Value
Potential
ARAR/TBC
Source
COPC Flag
(Y/N)
Rationale for
Selection or
Deletion
2500 67-64-1 Acetone 3
3.6 3
3000 109-99-9 ~Tetrahydrofuran 3
690 78-93-3 Methyl Ethyl Ketone (2-Butanone)3
Input Form 2D
Soil Gas Exposure Point Concentration Table
Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.
If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations
North Carolina DEQ Risk Calculator
Risk for Individual Pathways
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Sub-Slab Soil Gas Sample MP-9
Receptor Pathway Hazard Index Risk exceeded?
Soil NC NC NC
NC
NC
NC
NC
NC
NC
Receptor Pathway Carcinogenic Hazard Index Risk exceeded?
Groundwater to Indoor Air NC NC NC
NO
NC
NC
NC
NC
Pathway Source
Source Soil NC
Source Groundwater NC
Source Soil NC
Source Groundwater NC
Groundwater Exceedence of 2L at Receptor?
Exceedence of 2L at Receptor?
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead
concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
Notes:
3. NM = Not modeled, user did not check this pathway as complete.
4. NC = Pathway not calculated, required contaminant migration parameters were not entered.
DIRECT CONTACT SOIL AND WATER CALCULATORS
Resident
Non-Residential Worker
Recreator/Trespasser
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the
NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based
closure.
Surface Water Exceedence of 2B at Receptor?
Exceedence of 2B at Receptor?
VAPOR INTRUSION CALCULATORS
Resident
Non-Residential Worker
CONTAMINANT MIGRATION CALCULATORS
Target Receptor Concentrations Exceeded?
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Sub-Slab Soil Gas Sample MP-9
CAS # Chemical Name:
Soil Gas
Concentration
(ug/m3)
Calculated
Indoor Air
Concentration
(ug/m3)
Target Indoor
Air Conc. for
Carcinogens @
TCR = 1E-06
Conc. for Non-
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non-
Carcinogenic
Hazard
Quotient
67-64-1
75-71-8
109-99-9
78-93-3
Cumulative: 0.0E+00 4.8E-02
Output Form 3B
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion
risk, no risk values are calculated for these chemicals.
North Carolina DEQ Risk Calculator
Version Date:
Basis:
Site Name:
Site Address:
DEQ Section:
Site ID:
Exposure Unit ID:
Submittal Date:
Reviewed By:
Prepared By:Hart & Hickman
Hart & Hickman
Indoor Air Sample IAS-2
North Carolina Department of Environmental Quality
Risk Calculator
Crayton Printing
Distribution Street and Dunavant Street
DWM Brownfields Redevelopment Section
24025-20-060
February 2024
November 2023 EPA RSL Table
North Carolina DEQ Risk Calculator
Table of Contents
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Indoor Air Sample IAS-2
Form No.
Input Form 1A Complete Exposure Pathways
Input Form 1B Exposure Factors and Target Risks
Input Form 1C Contaminant Migration Parameters
Input Form 1D Sample Statistics
Input Form 2A Soil Exposure Point Concentration Table
Input Form 2B Groundwater Exposure Point Concentration Table
Input Form 2C Surface Water Exposure Point Concentration Table
Input Form 2D Soil Gas Exposure Point Concentration Table
Input Form 2E Indoor Air Exposure Point Concentration Table
Output Form 1A Risk for Individual Pathways
Output Form 1B Sitewide Risk
Output Form 2A Resident Soil
Output Form 2B Resident Groundwater Use
Output Form 2C Non-Residential Worker Soil
Output Form 2D Non-Residential Worker Groundwater Use
Output Form 2E Construction Worker Soil
Output Form 2F Recreator/Trespasser Soil
Output Form 2G Recreator/Trespasser Surface Water
Output Form 3A Resident Groundwater to Indoor Air
Output Form 3B Resident Soil Gas to Indoor Air
Output Form 3C Resident Indoor Air
Output Form 3D Non-Residential Worker Groundwater to Indoor Air
Output Form 3E Non-Residential Worker Soil Gas to Indoor Air
Output Form 3F Non-Residential Worker Indoor Air
Output Form 4A Soil to Groundwater - Forward Mode
Output Form 4B Groundwater to Groundwater - Forward Mode
Output Form 4C Soil to Surface Water - Forward Mode
Output Form 4D Groundwater to Surface Water - Forward Mode
Output Form 4E Soil to Groundwater - Backward Mode
Output Form 4F Groundwater to Groundwater - Backward Mode
Output Form 4G Soil to Surface Water - Backward Mode
Output Form 4H Groundwater to Surface Water - Backward Mode
Output Section 4 - Contaminant Migration Worksheets
Output Section 3 - Vapor Intrusion Calculators
Description
DATA INPUT SHEETS
Check box
if included
Input Section 1 - Exposure Pathways & Parameters
Input Section 2 - Exposure Point Concentrations
DATA OUTPUT SHEETS
Output Section 1 - Summary Output for All Calculators
Output Section 2 - Direct Contact Soil and Groundwater Calculators
North Carolina DEQ Risk Calculator
Complete Exposure Pathways
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Indoor Air Sample IAS-2
Note: Risk output will only be calculated for complete exposure pathways.
Receptor Pathway
Check box if
pathway
complete
Soil
Groundwater Use
Soil
Groundwater Use
Construction Worker Soil
Soil
Surface Water
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Source Soil
Source Groundwater
Source Soil
Source Groundwater
Input Form 1A
VAPOR INTRUSION PATHWAYS
DIRECT CONTACT SOIL AND WATER PATHWAYS
Resident
Non-Residential Worker
Recreator/Trespasser
Resident
Non-Residential Worker
CONTAMINANT MIGRATION PATHWAYS
Groundwater
Surface Water
North Carolina DEQ Risk Calculator
Exposure Point Concentrations
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Indoor Air Sample IAS-2
Description of Exposure Point Concentration Selection:
Exposure Point
Concentration
(ug/m3)
Notes:CAS Number Chemical
Minimum
Concentration
(Qualifier)
Maximum
Concentration
(Qualifier)
Units
Location of
Maximum
Concentration
Detection
Frequency
Range of
Detection
Limits
Concentration
Used for
Screening
Background
Value
Screening
Toxicity Value
(Screening
Level) (n/c)
Potential
ARAR/TBC
Value
Potential
ARAR/TBC
Source
COPC Flag
(Y/N)
Rationale for
Selection or
Deletion
23 67-64-1 Acetone 3
0.68 71-43-2 Benzene 3
0.17 3
0.085 3
1.2 74-87-3 Chloromethane 3
0.11 3
3.1 75-71-8 Dichlorodifluoromethane 3
2 141-78-6 Ethyl Acetate 3
1.7 100-41-4 Ethylbenzene 3
2.5 3
0.37 142-82-5 Heptane, N-3
0.27 591-78-6 Hexanone, 2-3
6.1 67-63-0 Isopropanol 3
4.6 78-93-3 Methyl Ethyl Ketone (2-Butanone)3
0.11 3
0.25 3
0.82 100-42-5 Styrene 3
2.3 108-88-3 Toluene 3
0.58 3
1.5 75-69-4 Trichlorofluoromethane 3
0.61 95-63-6 Trimethylbenzene, 1,2,4-3
1.3 3
6.1 108-38-3 Xylene, m-3
2.3 95-47-6 Xylene, o-3
Input Form 2E
Indoor Air Exposure Point Concentration Table
Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion.
If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Vapor Intrusion - Resident Indoor Air
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Indoor Air Sample IAS-2
CAS # Chemical Name:
Indoor Air
Concentration
(ug/m3)
Target Indoor
Air Conc. for
Carcinogens @
TCR = 1E-06
Conc. for Non-
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non-
Carcinogenic
Hazard
Quotient
67-64-1
71-43-2 1.9E-06 2.2E-02
56-23-5
67-66-3
74-87-3
110-82-7
75-71-8
141-78-6
100-41-4 1.5E-06 1.6E-03
109-99-9
142-82-5
591-78-6
67-63-0
78-93-3
1634-04-4
91-20-3 3.0E-06 8.0E-02
100-42-5
108-88-3
76-13-1
75-69-4
95-63-6
108-05-4
108-38-3
95-47-6
Cumulative: 7.5E-06 3.1E-01
Output Form 3C
** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate
carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3.
indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals
are likely not associated with vapor intrusion.
North Carolina DEQ Risk Calculator
Risk for Individual Pathways
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Indoor Air Sample IAS-2
Receptor Pathway Hazard Index Risk exceeded?
Soil NC NC NC
NC
NC
NC
NC
NC
NC
Receptor Pathway Carcinogenic Hazard Index Risk exceeded?
Groundwater to Indoor Air NC NC NC
NC
NO
NC
NC
NC
Pathway Source
Source Soil NC
Source Groundwater NC
Source Soil NC
Source Groundwater NC
3. NM = Not modeled, user did not check this pathway as complete.
4. NC = Pathway not calculated, required contaminant migration parameters were not entered.
DIRECT CONTACT SOIL AND WATER CALCULATORS
Resident
Non-Residential Worker
Recreator/Trespasser
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the
NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based
closure.
Surface Water Exceedence of 2B at Receptor?
Exceedence of 2B at Receptor?
VAPOR INTRUSION CALCULATORS
Resident
Non-Residential Worker
CONTAMINANT MIGRATION CALCULATORS
Target Receptor Concentrations Exceeded?
Groundwater Exceedence of 2L at Receptor?
Exceedence of 2L at Receptor?
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead
concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
Notes:
North Carolina DEQ Risk Calculator
Version Date:
Basis:
Site Name:
Site Address:
DEQ Section:
Site ID:
Exposure Unit ID:
Submittal Date:
Reviewed By:
Prepared By:Hart & Hickman
Hart & Hickman
Indoor Air Sample IAS-3
North Carolina Department of Environmental Quality
Risk Calculator
Crayton Printing
Distribution Street and Dunavant Street
DWM Brownfields Redevelopment Section
24025-20-060
February 2024
November 2023 EPA RSL Table
North Carolina DEQ Risk Calculator
Table of Contents
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Indoor Air Sample IAS-3
Form No.
Input Form 1A Complete Exposure Pathways
Input Form 1B Exposure Factors and Target Risks
Input Form 1C Contaminant Migration Parameters
Input Form 1D Sample Statistics
Input Form 2A Soil Exposure Point Concentration Table
Input Form 2B Groundwater Exposure Point Concentration Table
Input Form 2C Surface Water Exposure Point Concentration Table
Input Form 2D Soil Gas Exposure Point Concentration Table
Input Form 2E Indoor Air Exposure Point Concentration Table
Output Form 1A Risk for Individual Pathways
Output Form 1B Sitewide Risk
Output Form 2A Resident Soil
Output Form 2B Resident Groundwater Use
Output Form 2C Non-Residential Worker Soil
Output Form 2D Non-Residential Worker Groundwater Use
Output Form 2E Construction Worker Soil
Output Form 2F Recreator/Trespasser Soil
Output Form 2G Recreator/Trespasser Surface Water
Output Form 3A Resident Groundwater to Indoor Air
Output Form 3B Resident Soil Gas to Indoor Air
Output Form 3C Resident Indoor Air
Output Form 3D Non-Residential Worker Groundwater to Indoor Air
Output Form 3E Non-Residential Worker Soil Gas to Indoor Air
Output Form 3F Non-Residential Worker Indoor Air
Output Form 4A Soil to Groundwater - Forward Mode
Output Form 4B Groundwater to Groundwater - Forward Mode
Output Form 4C Soil to Surface Water - Forward Mode
Output Form 4D Groundwater to Surface Water - Forward Mode
Output Form 4E Soil to Groundwater - Backward Mode
Output Form 4F Groundwater to Groundwater - Backward Mode
Output Form 4G Soil to Surface Water - Backward Mode
Output Form 4H Groundwater to Surface Water - Backward Mode
Output Section 4 - Contaminant Migration Worksheets
Output Section 3 - Vapor Intrusion Calculators
Description
DATA INPUT SHEETS
Check box
if included
Input Section 1 - Exposure Pathways & Parameters
Input Section 2 - Exposure Point Concentrations
DATA OUTPUT SHEETS
Output Section 1 - Summary Output for All Calculators
Output Section 2 - Direct Contact Soil and Groundwater Calculators
North Carolina DEQ Risk Calculator
Complete Exposure Pathways
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Indoor Air Sample IAS-3
Note: Risk output will only be calculated for complete exposure pathways.
Receptor Pathway
Check box if
pathway
complete
Soil
Groundwater Use
Soil
Groundwater Use
Construction Worker Soil
Soil
Surface Water
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Source Soil
Source Groundwater
Source Soil
Source Groundwater
Input Form 1A
VAPOR INTRUSION PATHWAYS
DIRECT CONTACT SOIL AND WATER PATHWAYS
Resident
Non-Residential Worker
Recreator/Trespasser
Resident
Non-Residential Worker
CONTAMINANT MIGRATION PATHWAYS
Groundwater
Surface Water
North Carolina DEQ Risk Calculator
Exposure Point Concentrations
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Indoor Air Sample IAS-3
Description of Exposure Point Concentration Selection:
Exposure Point
Concentration
(ug/m3)
Notes:CAS Number Chemical
Minimum
Concentration
(Qualifier)
Maximum
Concentration
(Qualifier)
Units
Location of
Maximum
Concentration
Detection
Frequency
Range of
Detection
Limits
Concentration
Used for
Screening
Background
Value
Screening
Toxicity Value
(Screening
Level) (n/c)
Potential
ARAR/TBC
Value
Potential
ARAR/TBC
Source
COPC Flag
(Y/N)
Rationale for
Selection or
Deletion
43 67-64-1 Acetone 3
0.61 71-43-2 Benzene 3
0.43 56-23-5 Carbon Tetrachloride 3
0.11 3
1.2 74-87-3 Chloromethane 3
0.75 110-82-7 Cyclohexane 3
2.7 75-71-8 Dichlorodifluoromethane 3
4.9 141-78-6 Ethyl Acetate 3
0.67 100-41-4 Ethylbenzene 3
20 3
0.58 142-82-5 Heptane, N-3
0.18 591-78-6 Hexanone, 2-3
5 67-63-0 Isopropanol 3
3.2 3
0.19 3
0.64 100-42-5 Styrene 3
5.9 108-88-3 Toluene 3
0.64 3
1.5 75-69-4 Trichlorofluoromethane 3
0.77 95-63-6 Trimethylbenzene, 1,2,4-3
1.8 3
2.2 108-38-3 Xylene, m-3
0.98 95-47-6 Xylene, o-3
Input Form 2E
Indoor Air Exposure Point Concentration Table
Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion.
If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Vapor Intrusion - Resident Indoor Air
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Indoor Air Sample IAS-3
CAS # Chemical Name:
Indoor Air
Concentration
(ug/m3)
Target Indoor
Air Conc. for
Carcinogens @
TCR = 1E-06
Conc. for Non-
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non-
Carcinogenic
Hazard
Quotient
67-64-1
71-43-2 1.7E-06 1.9E-02
56-23-5
67-66-3
74-87-3
110-82-7
75-71-8
141-78-6
100-41-4
109-99-9
142-82-5
591-78-6
67-63-0
78-93-3
91-20-3 2.3E-06 6.1E-02
100-42-5
108-88-3
76-13-1
75-69-4
95-63-6
108-05-4
108-38-3
95-47-6
Cumulative: 6.4E-06 2.9E-01
Output Form 3C
** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate
carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3.
indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals
are likely not associated with vapor intrusion.
North Carolina DEQ Risk Calculator
Risk for Individual Pathways
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Indoor Air Sample IAS-3
Receptor Pathway Hazard Index Risk exceeded?
Soil NC NC NC
NC
NC
NC
NC
NC
NC
Receptor Pathway Carcinogenic Hazard Index Risk exceeded?
Groundwater to Indoor Air NC NC NC
NC
NO
NC
NC
NC
Pathway Source
Source Soil NC
Source Groundwater NC
Source Soil NC
Source Groundwater NC
3. NM = Not modeled, user did not check this pathway as complete.
4. NC = Pathway not calculated, required contaminant migration parameters were not entered.
DIRECT CONTACT SOIL AND WATER CALCULATORS
Resident
Non-Residential Worker
Recreator/Trespasser
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the
NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based
closure.
Surface Water Exceedence of 2B at Receptor?
Exceedence of 2B at Receptor?
VAPOR INTRUSION CALCULATORS
Resident
Non-Residential Worker
CONTAMINANT MIGRATION CALCULATORS
Target Receptor Concentrations Exceeded?
Groundwater Exceedence of 2L at Receptor?
Exceedence of 2L at Receptor?
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead
concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
Notes:
North Carolina DEQ Risk Calculator
Version Date:
Basis:
Site Name:
Site Address:
DEQ Section:
Site ID:
Exposure Unit ID:
Submittal Date:
Reviewed By:
Prepared By:Hart & Hickman
Hart & Hickman
Indoor Air Samples IAS-4 and IAS-DUP (Worst-Case)
North Carolina Department of Environmental Quality
Risk Calculator
Crayton Printing
Distribution Street and Dunavant Street
DWM Brownfields Redevelopment Section
24025-20-060
February 2024
November 2023 EPA RSL Table
North Carolina DEQ Risk Calculator
Table of Contents
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Indoor Air Samples IAS-4 and IAS-DUP (Worst-Case)
Form No.
Input Form 1A Complete Exposure Pathways
Input Form 1B Exposure Factors and Target Risks
Input Form 1C Contaminant Migration Parameters
Input Form 1D Sample Statistics
Input Form 2A Soil Exposure Point Concentration Table
Input Form 2B Groundwater Exposure Point Concentration Table
Input Form 2C Surface Water Exposure Point Concentration Table
Input Form 2D Soil Gas Exposure Point Concentration Table
Input Form 2E Indoor Air Exposure Point Concentration Table
Output Form 1A Risk for Individual Pathways
Output Form 1B Sitewide Risk
Output Form 2A Resident Soil
Output Form 2B Resident Groundwater Use
Output Form 2C Non-Residential Worker Soil
Output Form 2D Non-Residential Worker Groundwater Use
Output Form 2E Construction Worker Soil
Output Form 2F Recreator/Trespasser Soil
Output Form 2G Recreator/Trespasser Surface Water
Output Form 3A Resident Groundwater to Indoor Air
Output Form 3B Resident Soil Gas to Indoor Air
Output Form 3C Resident Indoor Air
Output Form 3D Non-Residential Worker Groundwater to Indoor Air
Output Form 3E Non-Residential Worker Soil Gas to Indoor Air
Output Form 3F Non-Residential Worker Indoor Air
Output Form 4A Soil to Groundwater - Forward Mode
Output Form 4B Groundwater to Groundwater - Forward Mode
Output Form 4C Soil to Surface Water - Forward Mode
Output Form 4D Groundwater to Surface Water - Forward Mode
Output Form 4E Soil to Groundwater - Backward Mode
Output Form 4F Groundwater to Groundwater - Backward Mode
Output Form 4G Soil to Surface Water - Backward Mode
Output Form 4H Groundwater to Surface Water - Backward Mode
Output Section 4 - Contaminant Migration Worksheets
Output Section 3 - Vapor Intrusion Calculators
Description
DATA INPUT SHEETS
Check box
if included
Input Section 1 - Exposure Pathways & Parameters
Input Section 2 - Exposure Point Concentrations
DATA OUTPUT SHEETS
Output Section 1 - Summary Output for All Calculators
Output Section 2 - Direct Contact Soil and Groundwater Calculators
North Carolina DEQ Risk Calculator
Complete Exposure Pathways
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Indoor Air Samples IAS-4 and IAS-DUP (Worst-Case)
Note: Risk output will only be calculated for complete exposure pathways.
Receptor Pathway
Check box if
pathway
complete
Soil
Groundwater Use
Soil
Groundwater Use
Construction Worker Soil
Soil
Surface Water
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Source Soil
Source Groundwater
Source Soil
Source Groundwater
Input Form 1A
VAPOR INTRUSION PATHWAYS
DIRECT CONTACT SOIL AND WATER PATHWAYS
Resident
Non-Residential Worker
Recreator/Trespasser
Resident
Non-Residential Worker
CONTAMINANT MIGRATION PATHWAYS
Groundwater
Surface Water
North Carolina DEQ Risk Calculator
Exposure Point Concentrations
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Indoor Air Samples IAS-4 and IAS-DUP (Worst-Case)
Description of Exposure Point Concentration Selection:
Exposure Point
Concentration
(ug/m3)
Notes:CAS Number Chemical
Minimum
Concentration
(Qualifier)
Maximum
Concentration
(Qualifier)
Units
Location of
Maximum
Concentration
Detection
Frequency
Range of
Detection
Limits
Concentration
Used for
Screening
Background
Value
Screening
Toxicity Value
(Screening
Level) (n/c)
Potential
ARAR/TBC
Value
Potential
ARAR/TBC
Source
COPC Flag
(Y/N)
Rationale for
Selection or
Deletion
55 67-64-1 Acetone 3
0.63 71-43-2 Benzene 3
0.47 56-23-5 Carbon Tetrachloride 3
0.12 3
1.2 74-87-3 Chloromethane 3
0.66 3
4.1 75-71-8 Dichlorodifluoromethane 3
5.1 100-41-4 Ethylbenzene 3
34 3
0.49 142-82-5 Heptane, N-3
0.36 591-78-6 Hexanone, 2-3
3.4 3
5.8 78-93-3 Methyl Ethyl Ketone (2-Butanone)3
0.078 3
0.19 3
1.1 100-42-5 Styrene 3
3.3 108-88-3 Toluene 3
0.82 3
1.5 75-69-4 Trichlorofluoromethane 3
1.6 95-63-6 Trimethylbenzene, 1,2,4-3
2.1 3
19 108-38-3 Xylene, m-3
5.3 95-47-6 Xylene, o-3
Input Form 2E
Indoor Air Exposure Point Concentration Table
Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion.
If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Vapor Intrusion - Resident Indoor Air
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Indoor Air Samples IAS-4 and IAS-DUP (Worst-Case)
CAS # Chemical Name:
Indoor Air
Concentration
(ug/m3)
Target Indoor
Air Conc. for
Carcinogens @
TCR = 1E-06
Conc. for Non-
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non-
Carcinogenic
Hazard
Quotient
67-64-1
71-43-2 1.8E-06 2.0E-02
56-23-5 1.0E-06 4.5E-03
67-66-3
74-87-3
110-82-7
75-71-8
100-41-4 4.5E-06 4.9E-03
109-99-9
142-82-5
591-78-6
67-63-0
78-93-3
1634-04-4
91-20-3 2.3E-06 6.1E-02
100-42-5
108-88-3
76-13-1
75-69-4
95-63-6
108-05-4
108-38-3
95-47-6
Cumulative: 1.1E-05 4.6E-01
Output Form 3C
** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate
carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3.
indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals
are likely not associated with vapor intrusion.
North Carolina DEQ Risk Calculator
Risk for Individual Pathways
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Indoor Air Samples IAS-4 and IAS-DUP (Worst-Case)
Receptor Pathway Hazard Index Risk exceeded?
Soil NC NC NC
NC
NC
NC
NC
NC
NC
Receptor Pathway Carcinogenic Hazard Index Risk exceeded?
Groundwater to Indoor Air NC NC NC
NC
NO
NC
NC
NC
Pathway Source
Source Soil NC
Source Groundwater NC
Source Soil NC
Source Groundwater NC
3. NM = Not modeled, user did not check this pathway as complete.
4. NC = Pathway not calculated, required contaminant migration parameters were not entered.
DIRECT CONTACT SOIL AND WATER CALCULATORS
Resident
Non-Residential Worker
Recreator/Trespasser
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the
NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based
closure.
Surface Water Exceedence of 2B at Receptor?
Exceedence of 2B at Receptor?
VAPOR INTRUSION CALCULATORS
Resident
Non-Residential Worker
CONTAMINANT MIGRATION CALCULATORS
Target Receptor Concentrations Exceeded?
Groundwater Exceedence of 2L at Receptor?
Exceedence of 2L at Receptor?
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead
concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
Notes:
North Carolina DEQ Risk Calculator
Version Date:
Basis:
Site Name:
Site Address:
DEQ Section:
Site ID:
Exposure Unit ID:
Submittal Date:
Reviewed By:
Risk Calculator
February 2024
November 2023 EPA RSL Table
Indoor Air Sample IAS-5
Crayton Printing
Distribution Street and Dunavant Street
DWM Brownfields Redevelopment Section
24025-20-060
Prepared By:Hart & Hickman
Hart & Hickman
North Carolina DEQ Risk Calculator
Table of Contents
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Indoor Air Sample IAS-5
Form No.
Input Form 1A Complete Exposure Pathways
Input Form 1B Exposure Factors and Target Risks
Input Form 1C Contaminant Migration Parameters
Input Form 1D Sample Statistics
Input Form 2A Soil Exposure Point Concentration Table
Input Form 2B Groundwater Exposure Point Concentration Table
Input Form 2C Surface Water Exposure Point Concentration Table
Input Form 2D Soil Gas Exposure Point Concentration Table
Input Form 2E Indoor Air Exposure Point Concentration Table
Output Form 1A Risk for Individual Pathways
Output Form 1B Sitewide Risk
Output Form 2A Resident Soil
Output Form 2B Resident Groundwater Use
Output Form 2C Non-Residential Worker Soil
Output Form 2D Non-Residential Worker Groundwater Use
Output Form 2E Construction Worker Soil
Output Form 2F Recreator/Trespasser Soil
Output Form 2G Recreator/Trespasser Surface Water
Output Form 3A Resident Groundwater to Indoor Air
Output Form 3B Resident Soil Gas to Indoor Air
Output Form 3C Resident Indoor Air
Output Form 3D Non-Residential Worker Groundwater to Indoor Air
Output Form 3E Non-Residential Worker Soil Gas to Indoor Air
Output Form 3F Non-Residential Worker Indoor Air
Output Form 4A Soil to Groundwater - Forward Mode
Output Form 4B Groundwater to Groundwater - Forward Mode
Output Form 4C Soil to Surface Water - Forward Mode
Output Form 4D Groundwater to Surface Water - Forward Mode
Output Form 4E Soil to Groundwater - Backward Mode
Output Form 4F Groundwater to Groundwater - Backward Mode
Output Form 4G Soil to Surface Water - Backward Mode
Output Form 4H Groundwater to Surface Water - Backward Mode
Output Section 4 - Contaminant Migration Worksheets
Output Section 3 - Vapor Intrusion Calculators
Description
DATA INPUT SHEETS
Check box
if included
Input Section 1 - Exposure Pathways & Parameters
Input Section 2 - Exposure Point Concentrations
DATA OUTPUT SHEETS
Output Section 1 - Summary Output for All Calculators
Output Section 2 - Direct Contact Soil and Groundwater Calculators
North Carolina DEQ Risk Calculator
Complete Exposure Pathways
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Indoor Air Sample IAS-5
Note: Risk output will only be calculated for complete exposure pathways.
Receptor Pathway
Check box if
pathway
complete
Soil
Groundwater Use
Soil
Groundwater Use
Construction Worker Soil
Soil
Surface Water
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Source Soil
Source Groundwater
Source Soil
Source Groundwater
Resident
Non-Residential Worker
CONTAMINANT MIGRATION PATHWAYS
Groundwater
Surface Water
Input Form 1A
VAPOR INTRUSION PATHWAYS
DIRECT CONTACT SOIL AND WATER PATHWAYS
Resident
Non-Residential Worker
Recreator/Trespasser
North Carolina DEQ Risk Calculator
Exposure Point Concentrations
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Indoor Air Sample IAS-5
Description of Exposure Point Concentration Selection:
Exposure Point
Concentration
(ug/m3)
Notes:CAS Number Chemical
Minimum
Concentration
(Qualifier)
Maximum
Concentration
(Qualifier)
Units
Location of
Maximum
Concentration
Detection
Frequency
Range of
Detection
Limits
Concentration
Used for
Screening
Background
Value
Screening
Toxicity Value
(Screening
Level) (n/c)
Potential
ARAR/TBC
Value
Potential
ARAR/TBC
Source
COPC Flag
(Y/N)
Rationale for
Selection or
Deletion
69 67-64-1 Acetone 3
0.89 71-43-2 Benzene 3
0.16 3
0.14 3
1.2 74-87-3 Chloromethane 3
0.52 110-82-7 Cyclohexane 3
2.9 75-71-8 Dichlorodifluoromethane 3
0.069 3
4.2 141-78-6 Ethyl Acetate 3
1.2 100-41-4 Ethylbenzene 3
31 3
0.96 142-82-5 Heptane, N-3
2.3 3
0.58 591-78-6 Hexanone, 2-3
9.9 67-63-0 Isopropanol 3
5.5 78-93-3 Methyl Ethyl Ketone (2-Butanone)3
0.17 1634-04-4 Methyl tert-Butyl Ether (MTBE)3
0.14 3
1 100-42-5 Styrene 3
0.15 3
11 108-88-3 Toluene 3
0.63 3
0.33 79-01-6 Trichloroethylene 3
1.4 75-69-4 Trichlorofluoromethane 3
1.5 95-63-6 Trimethylbenzene, 1,2,4-3
0.89 3
4.1 108-38-3 Xylene, m-3
1.5 95-47-6 Xylene, o-3
Input Form 2E
Indoor Air Exposure Point Concentration Table
Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion.
If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Vapor Intrusion - Resident Indoor Air
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Indoor Air Sample IAS-5
CAS # Chemical Name:
Indoor Air
Concentration
(ug/m3)
Target Indoor
Air Conc. for
Carcinogens @
TCR = 1E-06
Conc. for Non-
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non-
Carcinogenic
Hazard
Quotient
67-64-1
71-43-2 2.5E-06 2.8E-02
56-23-5
67-66-3 1.1E-06 1.4E-03
74-87-3
110-82-7
75-71-8
156-60-5
141-78-6
100-41-4 1.1E-06 1.2E-03
109-99-9
142-82-5
110-54-3
591-78-6
67-63-0
78-93-3
1634-04-4
91-20-3 1.7E-06 4.5E-02
100-42-5
127-18-4
108-88-3
76-13-1
79-01-6
75-69-4
95-63-6
108-05-4
108-38-3
95-47-6
Cumulative: 7.4E-06 5.1E-01
Output Form 3C
** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate
carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3.
indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals
are likely not associated with vapor intrusion.
North Carolina DEQ Risk Calculator
Risk for Individual Pathways
Version Date: February 2024
Basis: November 2023 EPA RSL Table
Site ID: 24025-20-060
Exposure Unit ID: Indoor Air Sample IAS-5
Receptor Pathway Hazard Index Risk exceeded?
Soil NC NC NC
NC
NC
NC
NC
NC
NC
Receptor Pathway Carcinogenic Hazard Index Risk exceeded?
Groundwater to Indoor Air NC NC NC
NC
NO
NC
NC
NC
Pathway Source
Source Soil NC
Source Groundwater NC
Source Soil NC
Source Groundwater NC
Groundwater Exceedence of 2L at Receptor?
Exceedence of 2L at Receptor?
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead
concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
Notes:
3. NM = Not modeled, user did not check this pathway as complete.
4. NC = Pathway not calculated, required contaminant migration parameters were not entered.
DIRECT CONTACT SOIL AND WATER CALCULATORS
Resident
Non-Residential Worker
Recreator/Trespasser
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the
NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based
closure.
Surface Water Exceedence of 2B at Receptor?
Exceedence of 2B at Receptor?
VAPOR INTRUSION CALCULATORS
Resident
Non-Residential Worker
CONTAMINANT MIGRATION CALCULATORS
Target Receptor Concentrations Exceeded?
North Carolina DEQ Risk Calculator

Appendix H
Construction Material Safety Data Sheets

Table H-1
Summary of Compounds Identified in Building Construction Materials
Crayton Printing Brownfields Site
Distribution Street and Dunavant Street
Charlotte, North Carolina
Brownfields Project No. 24025-20-060
H&H Job No. AKR.005
Sub-Group Product Material Potential Chemical of Concern (COC)% COC by
Weight CAS No.
Calcium Carbonate 40 - 60 471-34-1
2-butanone-O,O’,O’’-(phenylsilylidyne)trioxime <5 34036-80-1
Naphtha (petroleum), heavy alkylate <5 64741-65-7
Stearic acid, pure <5 57-11-4
Titanium Dioxide <1 13463-67-7
Octamethylcyclotetrasiloxane <1 556-67-2
Carbon Black 0.1 - <1.0 --
Quartz <1 14808-60-7
N-(2-aminoethyl)-N'-[3-
(trimethoxysilyl)propyl]ethylenediamine <1 35141-30-1
Calcium Carbonate 20 - <50 471-34-1
Polyvinyl Chloride 5 - <10 9002-86-2
Calcium Carbonate (Limestone)5 - <10 1317-65-3
Xylene 5 - <10 1330-20-7
Trade Secret 1 - <5 Trade Secret
Titanium Dioxide 1 - <2.5 13463-67-7
Diisodecyl Phthalate 0.3 - <1 26761-40-0
Ethylbenzene 0.1 - <1 100-41-4
Isophorone Diisocyanate 0.5 - <1 4098-71-9
Hydrotreated heavy naphthenic distillate 0.1 - <1 64742-52-5
Stearic acid 0.1 - <1 57-11-4
Dibutyl tin dilaurate 0.1 - <0.3 77-58-7
Iodopropynyl butylcarbamate 0.01 - <0.1 55406-53-6
Calcium Carbonate ≥7 - <20 471-34-1
Stoddard solvent ≥7 - <10 8052-41-3
Titanium Dioxide ≥3 - <5 13463-67-7
Calcium Oxide ≥0.3 - <1 1305-78-8
Trimethoxy(3-(oxiranylmethoxy)propyl)silane ≥0.3 - <1 2530-83-8
Calcium Carbonate (Limestone)≥10 - <20 1317-65-3
Quartz ≥0 - <0.3 14808-60-7
Stearic acid ≥0.3 - <3 57-11-4
Calcium Carbonate 30 - 60 471-34-1
Calcium Carbonate (Limestone)10 - 30 1317-65-3
Titanium Dioxide 1 - 5 13463-67-7
Stearic acid 1 - 5 57-11-4
Octamethylcyclotetrasiloxane 0.1 - 1 556-67-2
Aluminum Oxide 0.1 - 1 1344-28-1
Titanium Dioxide 4.12 13463-67-7
Zinc Oxide 2.04 1314-13-2
Titanium Dioxide 6.08 13463-67-7
2-(2-Methoxyethoxy)-ethanol 4.14 111-77-3
Cristobalite 0.15 14464-46-1
Sherwin-Williams PROMAR® 200
Zero VOC Interior Latex Semi-Gloss,
Extra White
Titanium Dioxide 13.1 13463-67-7
Calcium Carbonate (Limestone)30.24 1317-65-3
Titanium Dioxide 5.4 13463-67-7
Ethanol 1.56 64-17-5
Crystalline Silica, respirable powder 0.12 14808-60-7
Titanium Dioxide 14.5 13463-67-7
Epichlorohydrin-mercaptoethanol Alcohol 0.3 928768-73-4
Paint Thinner Sherwin-Williams Isopropyl Alcohol 2-Propanol 100.0 67-63-0
Acetone 25 - 40 67-64-1
Cyclohexanone 25 - 40 108-94-1
Tetrahydrofuran 15 - 30 109-99-9
Methyl Ethyl Ketone 15 - 30 78-93-3
Notes:
1) The above compounds were identified in Material Safety Data Sheets (MSDSs).
2) Product names listed above were provided by the general contractor or are general use products observed or assumed to be used by contractors. 
Sherwin-Williams A-100® Exterior
Acrylic Latex Satin Deep Base
Sherwin-Williams DTM ACRYLIC
Semi-Gloss Acrylic Coating Deep
Base
Dymonic 100 Gray - 30 CTG CS
Multi-Purpose Interior/Exterior Latex
Primer, WhitePrimer
MasterSeal NP 2
Tremco Spectrem 2 White
Sherwin-Williams Waterborne Acrylic
Dry Fall Flat, Brilliant White
Sealant
Paint
Pecora 890 NST
PVC Primer Oatey® Purple Primer
https://harthick.sharepoint.com/sites/MasterFiles‐1/Shared Documents/AAA‐Master Projects/Akridge/AKR.005 Dunavant Brownfields Assessment/VIMS install report/SDS/SDS table 8‐1‐23
9/18/2023
Table H-1 (Page 1 of 2)
Hart & Hickman, PC
Table H-1
Summary of Compounds Identified in Building Construction Materials
Crayton Printing Brownfields Site
Distribution Street and Dunavant Street
Charlotte, North Carolina
Brownfields Project No. 24025-20-060
H&H Job No. AKR.005
Sub-Group Product Material Potential Chemical of Concern (COC)% COC by
Weight CAS No.
Tetrahydrofuran 30 - 50 109-99-9
Acetone 10 - 25 67-64-1
Methyl Ethyl Ketone 25 - 40 78-93-3
Polyvinyl chloride 12 - 20 9002-86-2
Cyclohexanone 10 - 20 108-94-1
Fumed Silica 1 - 5 112945-52-5
Methyl Ethyl Ketone 20 - 40 78-93-3
Cyclohexanone 15 - 35 108-94-1
Tetrahydrofuran 10 - 30 109-99-9
Acetone 5 - 15 67-64-1
Pentanes <20 109-66-0
Toluene <20 108-88-3
Xylene <20 1330-20-7
Hexanes, Mixture of Isomers <15 Various
Heptane <15 142-82-5
Ethanol 0-10 64-17-5
Butane 0-10 106-97-8
Benzene <4.9 71-43-2
Ethlylbenzene <4 100-41-4
Cumene <4 98-82-8
n-hexane <3 110-54-3
Cyclohexane <3 110-82-7
1,2,4-Trimethylbenzene <2 95-63-6
Naphthalene <2 91-20-3
Diethylene Glycol Dibenzoate ≥3 - <5 120-55-8
Titanium Dioxide ≥0.3 - <1 13463-67-7
2,2,4-Trimethyl Pentanediol 1,3-Monoisobutyrat 4.25 - 6.37 25265-77-4
Propylene glycol ether <3 770-35-4
Ethanolamine 0.01 - 0.26 141-43-5
2-Ethyl-1-hexanol Trace 104-76-7
1,2-Benzisothaiazol-3(2H)-one Trace 2634-33-5
Petroleum Asphalt 8052-42-4 8052-42-4
Clay 1302-78-9 1302-78-9
Asphalts 60 - 80 8052-42-4
Distillates(petroleum), petroleum residues vaccum 60 - 80 68955-27-1
Calcium Carbonate (Limestone)15 - 20 1317-65-3
Crystalline Silica, quartz (inpurity)0.5 - 1.5 14808-60-7
Hydrogen Sulfide 0.001 - 0.01 7783-06-4
Notes:
1) The above compounds were identified in Material Safety Data Sheets (MSDSs).
2) Product names listed above were provided by the general contractor or are general use products observed or assumed to be used by contractors. 
Gasoline Unleaded Gasolines (All Types)
Caulk 850A Siliconized Acrylic Latex Caulk
White
Concrete Sealant Cure & Seal WB
Moisture Retarder /
Waterproofing Polyguard 650 Sheet Membrane
Oatey® Medium Clear Cement
Weld-On® 781™ Plumbing Gray
Low VOC Cement
PVC Glue
Dampproofing /
Waterproofing SEALMASTIC
https://harthick.sharepoint.com/sites/MasterFiles‐1/Shared Documents/AAA‐Master Projects/Akridge/AKR.005 Dunavant Brownfields Assessment/VIMS install report/SDS/SDS table 8‐1‐23
9/18/2023
Table H-1 (Page 2 of 2)
Hart & Hickman, PC
850A Acrylic Latex Caulk
White
Not available.
Liquid.
[phone]
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :THE SHERWIN-WILLIAMS COMPANY
101 Prospect Avenue N.W.
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
850A
850AProduct code :
Product Information
Telephone Number
:Not available.
Regulatory Information
Telephone Number
:[phone]
Transportation Emergency
Telephone Number
:[phone]
Section 2. Hazards identification
CARCINOGENICITY - Category 2Classification of the
substance or mixture
:
Signal word :Warning
Hazard pictograms :
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing.
Response :IF exposed or concerned: Get medical attention.
Storage :Store locked up.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
GHS label elements
General :Read label before use. Keep out of reach of children. If medical advice is needed, have
product container or label at hand.
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Suspected of causing cancer.:Hazard statements
Date of issue/Date of revision :11/29/2015 Date of previous issue :11/11/2015 Version :1.04 1/10
Section 2. Hazards identification
Hazards not otherwise
classified
:None known.
Please refer to the SDS for additional information. Do not transfer contents to other
containers for storage.
Supplemental label
elements
WARNING: This product contains chemicals known to the State of California to cause
cancer and birth defects or other reproductive harm. Adequate ventilation required when
sanding or abrading the dried film. If Adequate ventilation cannot be provided wear an
approved particulate respirator (NIOSH approved). Follow respirator manufacturer's
directions for respirator use. DELAYED EFFECTS FROM LONG TERM
OVEREXPOSURE. Abrading or sanding of the dry film may release Crystalline Silica
which has been shown to cause lung damage and cancer under long term exposure.
Section 3. Composition/information on ingredients
Diethylene Glycol Dibenzoate ≥3 - <5 120-55-8
Titanium Dioxide ≥0.3 - <1 13463-67-7
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place
in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
No known significant effects or critical hazards.:Eye contact
Potential acute health effects
Date of issue/Date of revision :11/29/2015 Date of previous issue :11/11/2015 Version :1.04 2/10
Section 4. First aid measures
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For non-emergency
personnel
For emergency responders :If specialised clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Date of issue/Date of revision :11/29/2015 Date of previous issue :11/11/2015 Version :1.04 3/10
Section 6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not ingest.
Avoid breathing vapor or mist. If during normal use the material presents a respiratory
hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Empty containers retain product residue and can be
hazardous. Do not reuse container.
:
Precautions for safe handling
Diethylene Glycol Dibenzoate None.
Titanium Dioxide ACGIH TLV (United States, 3/2015).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 2/2013).
TWA: 15 mg/m³ 8 hours. Form: Total dust
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Appropriate engineering
controls
:If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Control parameters
Occupational exposure limits
Date of issue/Date of revision :11/29/2015 Date of previous issue :11/11/2015 Version :1.04 4/10
Section 8. Exposure controls/personal protection
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.69
1 [Air = 1]
0.31 kPa (2.333 mm Hg) [at 20°C]
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate 0.09 (butyl acetate = 1)
Flash point Closed cup: >93.3°C (>199.9°F)
8
Not available.Odor threshold
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :100°C (212°F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Date of issue/Date of revision :11/29/2015 Date of previous issue :11/11/2015 Version :1.04 5/10
Section 9. Physical and chemical properties
Auto-ignition temperature Not available.
Not available.
Viscosity Kinematic (room temperature): >0.205 cm2/s (>20.5 cSt)
Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Partition coefficient: n-
octanol/water
:
:
:
Decomposition temperature :Not available.
Heat of combustion :2.812 kJ/g
Aerosol product
Molecular weight :Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Diethylene Glycol Dibenzoate LD50 Oral Rat 2830 mg/kg -
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Irritation/Corrosion
Diethylene Glycol Dibenzoate Eyes - Mild irritant Rabbit -24 hours 500
milligrams
-
Skin - Mild irritant Rabbit -24 hours 500
milligrams
-
Titanium Dioxide Skin - Mild irritant Human -72 hours 300
Micrograms
Intermittent
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
Classification
Date of issue/Date of revision :11/29/2015 Date of previous issue :11/11/2015 Version :1.04 6/10
Section 11. Toxicological information
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Not available.
Aspiration hazard
Not available.
Titanium Dioxide -2B -
Product/ingredient name NTPIARCOSHA
Not available.
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
No known significant effects or critical hazards.General :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects :Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects :Not available.
Date of issue/Date of revision :11/29/2015 Date of previous issue :11/11/2015 Version :1.04 7/10
Fertility effects :No known significant effects or critical hazards.
Numerical measures of toxicity
Oral 64727.8 mg/kg
Route ATE value
Acute toxicity estimates
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
Titanium Dioxide -352 low
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
:Disposal methods
Section 14. Transport information
--
Not regulated.Not regulated.
DOT
Classification
IMDG
UN number
UN proper
shipping name
TDG
Classification
Not regulated.
-
Mexico
Classification
Not regulated.
-
IATA
Not regulated.
-
Date of issue/Date of revision :11/29/2015 Date of previous issue :11/11/2015 Version :1.04 8/10
Section 14. Transport information
-
-
-
-
Special
provisions
Not Applicable
Emergency
schedules (EmS)
Not Applicable
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL
73/78 and the IBC Code
No.No.
Not available.
:
Proper shipping name :
Ship type :Not available.
Pollution category :Not available.
Not available.
:
-
-
No.
Special
provisions
Not Applicable
-
-
No.
Special
provisions
Not Applicable
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability
prior to shipment, and compliance with the applicable regulations is the sole
responsibility of the person offering the product for transport. People loading and
unloading dangerous goods must be trained on all of the risks deriving from the
substances and on all actions in case of emergency situations.
-
-
No.
Special
provisions
Not Applicable
Section 15. Regulatory information
SARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
Section 16. Other information
Hazardous Material Information System (U.S.A.)
1
0
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller [phone].
The customer is responsible for determining the PPE code for this material.
Procedure used to derive the classification
Classification Justification
Date of issue/Date of revision :11/29/2015 Date of previous issue :11/11/2015 Version :1.04 9/10
Section 16. Other information
11/29/2015
History
Date of printing
Date of issue/Date of
revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use
or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject
to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to
ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use
of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to
determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the
product for any purpose other than the purpose shown in the applicable section of this SDS without first
referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for
information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from
any other source.
Notice to reader
Date of previous issue
:
:
:
:
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
11/29/2015
11/11/2015
1.04
Carc. 2, H351 Calculation method
Date of issue/Date of revision :11/29/2015 Date of previous issue :11/11/2015 Version :1.04 10/10
Page: 1/10Safety Data Sheet
according to OSHA HCS (29CFR 1910.1200) and WHMIS 2015 Regulations
Revision: September 20, 2019
49.4.0
1 Identification
·Product identifier
·Trade name: Pecora 890 NST
·Other means of identification:Pecora 890 Non-Staining Technology
·Recommended use and restriction on use·Recommended use:Sealant·Restrictions on use:No relevant information available.
·Details of the supplier of the Safety Data Sheet·Manufacturer/Supplier:Pecora Corporation165 Wambold RoadHarleysville, PA 19438215-723-6051
·Emergency telephone number:CHEMTREC1-800-424-9300 (US/Canada)
2 Hazard(s) identification
·Classification of the substance or mixture
Skin Sens. 1 H317 May cause an allergic skin reaction.
Repr. 2 H361 Suspected of damaging fertility or the unborn child.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
·Label elements·GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).·Hazard pictograms:
GHS07 GHS08
·Signal word:Warning·Hazard statements:H317 May cause an allergic skin reaction.H361 Suspected of damaging fertility or the unborn child.H373 May cause damage to organs through prolonged or repeated exposure.·Precautionary statements:P201 Obtain special instructions before use.P202 Do not handle until all safety precautions have been read and understood.P260 Do not breathe dust/fume/gas/mist/vapors/spray.P272 Contaminated work clothing must not be allowed out of the workplace.P280 Wear protective gloves/protective clothing/eye protection.P302+P352 If on skin: Wash with plenty of soap and water.P314 Get medical advice/attention if you feel unwell.P333+P313 If skin irritation or rash occurs: Get medical advice/attention.P363 Wash contaminated clothing before reuse.P405 Store locked up.
(Cont'd. on page 2)
Page: 2/10Safety Data Sheet
according to OSHA HCS (29CFR 1910.1200) and WHMIS 2015 Regulations
Revision: September 20, 2019
Trade name:Pecora 890 NST
(Cont'd. of page 1)
49.4.0
P501 Dispose of contents/container in accordance with local/regional/national/internationalregulations.
·Other hazards There are no other hazards not otherwise classified that have been identified.
3 Composition/information on ingredients
·Chemical characterization: Mixtures
·Components:
471-34-1 Calcium carbonate 40-60%
34036-80-1 2-butanone-O,O’,O’’-(phenylsilylidyne)trioxime
STOT RE 2, H373Skin Sens. 1, H317
<5%
64741-65-7 Naphtha (petroleum), heavy alkylate
Flam. Liq. 3, H226Asp. Tox. 1, H304Skin Irrit. 2, H315; STOT SE 3, H336
<5%
57-11-4 Stearic acid, pure
Combustible Dust
<5%
13463-67-7 Titanium dioxide <1%
556-67-2 Octamethylcyclotetrasiloxane
Flam. Liq. 3, H226Repr. 2, H361
<1%
1333-86-4 Carbon black <1%
14808-60-7 Quartz <1%
35141-30-1 N-(2-aminoethyl)-N'-[3-(trimethoxysilyl)propyl]ethylenediamine
Eye Dam. 1, H318Acute Tox. 4, H332; Skin Sens. 1A, H317
<1%
·Additional information:Non-classification as a carcinogen is based on non-inhalable form of product. IARC listings for quartz and
titanium dioxide note that the substance must be respirable.For the wording of the listed Hazard Statements, refer to section 16.For the listed ingredient(s), the identity and/or exact percentage(s) are being withheld as a trade secret.
4 First-aid measures
·Description of first aid measures
·After inhalation:Supply fresh air; consult doctor in case of complaints.·After skin contact:Wash with soap and water.If skin irritation or rash occurs: Get medical advice/attention.·After eye contact:
Remove contact lenses if worn.Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.·After swallowing:Do not induce vomiting; immediately call for medical help.·Most important symptoms and effects, both acute and delayed:
Gastric or intestinal disorders when ingested.(Cont'd. on page 3)
Page: 3/10Safety Data Sheet
according to OSHA HCS (29CFR 1910.1200) and WHMIS 2015 Regulations
Revision: September 20, 2019
Trade name:Pecora 890 NST
(Cont'd. of page 2)
49.4.0
Slight irritant effect on eyes.Allergic reactions·Danger:
May cause damage to organs through prolonged or repeated exposure.Suspected of damaging fertility or the unborn child.·Indication of any immediate medical attention and special treatment needed:Contains 2-butanone-O,O’,O’’-(phenylsilylidyne)trioxime, N-(2-aminoethyl)-N'-[3-(trimethoxysilyl)propyl]ethylenediamine. May produce an allergic reaction.Treat skin and mucous membrane with antihistamine and corticoid preparations.
5 Fire-fighting measures
·Extinguishing media
·Suitable extinguishing agents:Carbon dioxideFire-extinguishing powderGaseous extinguishing agentsFoamSandWater fog / haze·For safety reasons unsuitable extinguishing agents:Water stream.·Special hazards arising from the substance or mixtureFormation of toxic gases is possible during heating or in case of fire.·Advice for firefighters·Protective equipment:Wear self-contained respiratory protective device.Wear fully protective suit.
6 Accidental release measures
·Personal precautions, protective equipment and emergency proceduresEnsure adequate ventilation.Use personal protective equipment as required.·Environmental precautionsDo not allow undiluted product or large quantities of it to reach ground water, water course or sewagesystem.·Methods and material for containment and cleaning up
Towel or mop up material and collect in a suitable container.For larger spills, add sawdust, chalk or other inert binding material, then sweep up and discard.·Reference to other sections
See Section 7 for information on safe handling.See Section 8 for information on personal protection equipment.See Section 13 for disposal information.
7 Handling and storage
·Handling (Cont'd. on page 4)
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according to OSHA HCS (29CFR 1910.1200) and WHMIS 2015 Regulations
Revision: September 20, 2019
Trade name:Pecora 890 NST
(Cont'd. of page 3)
49.4.0
·Precautions for safe handling:Open and handle receptacle with care.
Keep out of reach of children.Avoid contact with the eyes and skin.
·Conditions for safe storage, including any incompatibilities·Requirements to be met by storerooms and receptacles:Store in cool, dry conditions in well sealed receptacles.
·Information about storage in one common storage facility:Store away from foodstuffs.·Specific end use(s)No relevant information available.
8 Exposure controls/personal protection
·Control parameters
·Components with limit values that require monitoring at the workplace:
471-34-1 Calcium carbonate
PEL (USA) Long-term value: 15* 5** mg/m³*total dust **respirable fraction
REL (USA) Long-term value: 10* 5** mg/m³*total dust **respirable fraction
TLV (USA) TLV withdrawn
57-11-4 Stearic acid, pure
EL (Canada) Long-term value: 10 mg/m³except stearates of toxic metal
13463-67-7 Titanium dioxide
PEL (USA) Long-term value: 15* mg/m³*total dust
REL (USA) See Pocket Guide App. A
TLV (USA) Long-term value: 10 mg/m³
EL (Canada) Long-term value: 10* 3** mg/m³*total dust;**respirable fraction; IARC 2B
EV (Canada) Long-term value: 10 mg/m³total dust
LMPE (Mexico) Long-term value: 10 mg/m³A4
556-67-2 Octamethylcyclotetrasiloxane
WEEL (USA) Long-term value: 10* ppm*OARS WEEL
1333-86-4 Carbon black
PEL (USA) Long-term value: 3.5 mg/m³
REL (USA) Long-term value: 3.5* mg/m³*0.1 in presence of PAHs;See Pocket Guide Apps.A+C
TLV (USA) Long-term value: 3* mg/m³*inhalable fraction
EL (Canada) Long-term value: 3 mg/m³
(Cont'd. on page 5)
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Trade name:Pecora 890 NST
(Cont'd. of page 4)
49.4.0
IARC 2B
EV (Canada) Long-term value: 3.5 mg/m³
LMPE (Mexico) Long-term value: 3* mg/m³A3, *fracción inhalable
14808-60-7 Quartz
PEL (USA) Long-term value: 0.05* mg/m³*resp. dust; 30mg/m3/%SiO2+2
REL (USA) Long-term value: 0.05* mg/m³*respirable dust; See Pocket Guide App. A
TLV (USA) Long-term value: 0.025* mg/m³*as respirable fraction
EL (Canada) Long-term value: 0.025 mg/m³ACGIH A2; IARC 1
EV (Canada) Long-term value: 0.10* mg/m³*respirable fraction
LMPE (Mexico) Long-term value: 0.025* mg/m³A2, *fracción respirable
·Exposure controls
·General protective and hygienic measures:The usual precautionary measures for handling chemicals should be followed.Keep away from foodstuffs, beverages and feed.Avoid contact with the eyes and skin.Avoid breathing mist, vapors, or spray.·Engineering controls:No relevant information available.·Breathing equipment:Not required under normal conditions of use.Use suitable respiratory protective device in case of insufficient ventilation.A NIOSH approved dust respirator should be used for operations generating dust.·Protection of hands:Wear protective gloves to handle contents of damaged or leaking units.Gloves are advised for repeated or prolonged contact.·Eye protection:Follow relevant national guidelines concerning the use of protective eyewear.·Body protection:Protective work clothing·Limitation and supervision of exposure into the environment No special requirements.·Risk management measures No special requirements.
9 Physical and chemical properties
·Information on basic physical and chemical properties·Appearance:
Form:PasteColor:According to product specification·Odor:Mild·Odor threshold:Not determined.
·pH-value:Not determined.
(Cont'd. on page 6)
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(Cont'd. of page 5)
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·Melting point/Melting range:Not determined.·Boiling point/Boiling range:Not determined.
·Flash point:>140 °C (>284 °F)
·Flammability (solid, gaseous):Not applicable.
·Auto-ignition temperature:Not determined.
·Decomposition temperature:Not determined.
·Danger of explosion:Product does not present an explosion hazard.
·Explosion limitsLower:Not determined.
Upper:Not determined.·Oxidizing properties:Non-oxidizing.
·Vapor pressure:Not determined.
·Density:
Relative density:1.1-1.3Vapor density:Not determined.
Evaporation rate:Not determined.
·Solubility in / Miscibility withWater:Insoluble.
·Partition coefficient (n-octanol/water):Not determined.
·Viscosity
Dynamic:Not determined.Kinematic:Not determined.·VOC content:72 g/L·Other information No relevant information available.
10 Stability and reactivity
·Reactivity:No relevant information available.·Chemical stability:Stable under normal temperatures and pressures.·Thermal decomposition / conditions to be avoided:No decomposition if used and stored according to specifications.·Possibility of hazardous reactions Reacts with oxidizing agents.·Conditions to avoid Excessive heat.
·Incompatible materials Oxidizers·Hazardous decomposition productsUnder fire conditions only:Carbon monoxide and carbon dioxideNitrogen oxides (NOx)
11 Toxicological information
(Cont'd. on page 7)
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(Cont'd. of page 6)
49.4.0
·Information on toxicological effects·Acute toxicity:Based on available data, the classification criteria are not met.·LD/LC50 values that are relevant for classification:None.·Primary irritant effect:·On the skin:Based on available data, the classification criteria are not met.·On the eye:Based on available data, the classification criteria are not met.·Sensitization:Contains 2-butanone-O,O’,O’’-(phenylsilylidyne)trioxime, N-(2-aminoethyl)-N'-[3-(trimethoxysilyl)propyl]ethylenediamine. May produce an allergic reaction.
·IARC (International Agency for Research on Cancer):Reference to chemical component(s) listed below are based on unbound respirable particles and are notgenerally applicable to product as supplied.
13463-67-7 Titanium dioxide 2B
1333-86-4 Carbon black 2B
14808-60-7 Quartz 1
·NTP (National Toxicology Program):
14808-60-7 Quartz K
·OSHA-Ca (Occupational Safety & Health Administration):
None of the ingredients are listed.
·Probable route(s) of exposure:Ingestion.
Eye contact.Skin contact.·Germ cell mutagenicity:Based on available data, the classification criteria are not met.·Carcinogenicity:
Contains known or suspect carcinogens when inhaled. Product is in non-inhalable form and isnonclassifiable as a carcinogen.·Reproductive toxicity:Suspected of damaging fertility or the unborn child.·STOT-single exposure:Based on available data, the classification criteria are not met.·STOT-repeated exposure:May cause damage to organs through prolonged or repeated exposure.·Aspiration hazard:Based on available data, the classification criteria are not met.
12 Ecological information
·Toxicity·Aquatic toxicity Harmful to aquatic life with long lasting effects.·Persistence and degradability No relevant information available.·Bioaccumulative potential:No relevant information available.·Mobility in soil:No relevant information available.·Other adverse effects No relevant information available.
13 Disposal considerations
·Waste treatment methods
·Recommendation:(Cont'd. on page 8)
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(Cont'd. of page 7)
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Smaller quantities can be disposed of with household waste.Can be disposed of with household garbage after solidification following consultation with the wastedisposal facility operator and the pertinent authorities and adhering to the necessary technical regulations.The user of this material has the responsibility to dispose of unused material, residues and containers incompliance with all relevant local, state and federal laws and regulations regarding treatment, storage anddisposal for hazardous and nonhazardous wastes.
·Uncleaned packagings
·Recommendation:Disposal must be made according to official regulations.
14 Transport information
·UN-Number·DOT, ADR/RID/ADN, IMDG, IATA Not regulated.
·UN proper shipping name·DOT, ADR/RID/ADN, IMDG, IATA Not regulated.
·Transport hazard class(es)
·DOT, ADR/RID/ADN, IMDG, IATA·Class Not regulated.
·Packing group·DOT, ADR/RID/ADN, IMDG, IATA Not regulated.
·Environmental hazards
·Marine pollutant:No
·Special precautions for user Not applicable.
·Transport in bulk according to Annex II ofMARPOL73/78 and the IBC Code Not applicable.
15 Regulatory information
·Safety, health and environmental regulations/legislation specific for the substance or
mixture
·United States (USA)·SARA
·Section 302 (extremely hazardous substances):
None of the ingredients are listed.
·Section 355 (extremely hazardous substances):
None of the ingredients are listed.
·Section 313 (Specific toxic chemical listings):
None of the ingredients are listed.
·TSCA (Toxic Substances Control Act)
All ingredients are listed or exempt.
(Cont'd. on page 9)
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(Cont'd. of page 8)
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·Proposition 65 (California)·Chemicals known to cause cancer:
Reference to chemical component(s) listed below are based on unbound respirable particles and are notgenerally applicable to product as supplied.
13463-67-7 Titanium dioxide
1333-86-4 Carbon black
14808-60-7 Quartz
·Chemicals known to cause developmental toxicity for females:
None of the ingredients are listed.
·Chemicals known to cause developmental toxicity for males:
None of the ingredients are listed.
·Chemicals known to cause developmental toxicity:
None of the ingredients are listed.
·EPA (Environmental Protection Agency):
None of the ingredients are listed.
·IARC (International Agency for Research on Cancer):
Reference to chemical component(s) listed below are based on unbound respirable particles and are notgenerally applicable to product as supplied.
13463-67-7 Titanium dioxide 2B
1333-86-4 Carbon black 2B
14808-60-7 Quartz 1
·Canadian Domestic Substances List (DSL):
All ingredients are listed or exempt.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for anyspecific product features and shall not establish a legally valid contractual relationship.
·Abbreviations and acronyms:ADR: European Agreement concerning the International Carriage of Dangerous Goods by RoadIMDG: International Maritime Code for Dangerous GoodsDOT: US Department of TransportationIATA: International Air Transport AssociationCAS: Chemical Abstracts Service (division of the American Chemical Society)LC50: Lethal concentration, 50 percentLD50: Lethal dose, 50 percentOSHA: Occupational Safety & Health AdministrationFlam. Liq. 3: Flammable liquids – Category 3Acute Tox. 4: Acute toxicity – Category 4Skin Irrit. 2: Skin corrosion/irritation – Category 2Eye Dam. 1: Serious eye damage/eye irritation – Category 1Skin Sens. 1: Skin sensitisation – Category 1Skin Sens. 1A: Skin sensitisation – Category 1ARepr. 2: Reproductive toxicity – Category 2STOT SE 3: Specific target organ toxicity (single exposure) – Category 3STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2Asp. Tox. 1: Aspiration hazard – Category 1·SourcesWebsite, European Chemicals Agency (echa.europa.eu)
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(Cont'd. of page 9)
49.4.0
Website, US EPA Substance Registry Services (ofmpub.epa.gov/sor internet/registry/substreg/home/overview/home.do)Website, Chemical Abstracts Registry, American Chemical Society (www.cas.org)Patty's Industrial Hygiene, 6th ed., Rose, Vernon, ed. ISBN: 978-0-470-07488-6Casarett and Doull's Toxicology: The Basic Science of Poisons, 8th Ed., Klaasen, Curtis D., ed., ISBN:978-0-07-176923-5.Safety Data Sheets, Individual Manufacturers
SDS Prepared by:ChemTel Inc.1305 North Florida AvenueTampa, Florida USA 33602-2902Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573Website: www.chemtelinc.com
A-100® Exterior Acrylic Latex Satin
Deep Base
Not available.
Liquid.
US / Canada: [phone]
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
A82W153
A82W153Product code :
Product Information
Telephone Number
:US / Canada: Not Available
Mexico: Not Available
Regulatory Information
Telephone Number
:US / Canada: [phone]
Mexico: Not Available
Transportation Emergency
Telephone Number
:US / Canada: [phone]
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
National contact :The Sherwin-Williams Company
418 North Service Road East
Oakville, Ontario L6H 5R2 Canada
Section 2. Hazards identification
CARCINOGENICITY - Category 2Classification of the
substance or mixture
:
Signal word :Warning
Hazard pictograms :
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing.
Response :IF exposed or concerned: Get medical attention.
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 6.2%
Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 6.2%
Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 6.2%
General :Read label before use. Keep out of reach of children. If medical advice is needed, have
product container or label at hand.
Suspected of causing cancer.:Hazard statements
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Section 2. Hazards identification
Storage :Store locked up.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do
not transfer contents to other containers for storage.
Supplemental label
elements
WARNING: This product contains chemicals known to the State of California to cause
cancer and birth defects or other reproductive harm.
:
Section 3. Composition/information on ingredients
Titanium Dioxide 4.12 13463-67-7
Zinc Oxide 2.04 1314-13-2
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place
in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Potential acute health effects
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Section 4. First aid measures
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
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SHW-85-NA-GHS-CA
Section 6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill :
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination. See Section 10 for
incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not ingest.
Avoid breathing vapor or mist. If during normal use the material presents a respiratory
hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Empty containers retain product residue and can be
hazardous. Do not reuse container.
:
Precautions for safe handling
Titanium Dioxide ACGIH TLV (United States, 3/2017).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 6/2016).
TWA: 15 mg/m³ 8 hours. Form: Total dust
Zinc Oxide NIOSH REL (United States, 10/2016).
CEIL: 15 mg/m³ Form: Dust
TWA: 5 mg/m³ 10 hours. Form: Dust and
fumes
STEL: 10 mg/m³ 15 minutes. Form: Fume
OSHA PEL (United States, 6/2016).
TWA: 5 mg/m³ 8 hours. Form: Fume
TWA: 5 mg/m³ 8 hours. Form: Respirable
fraction
TWA: 15 mg/m³ 8 hours. Form: Total dust
ACGIH TLV (United States, 3/2017).
TWA: 2 mg/m³ 8 hours. Form: Respirable
fraction
STEL: 10 mg/m³ 15 minutes. Form:
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
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Section 8. Exposure controls/personal protection
Respirable fraction
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Eye/face protection :
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Zinc Oxide CA Alberta Provincial (Canada, 4/2009).
8 hrs OEL: 2 mg/m³ 8 hours. Form:
Respirable
15 min OEL: 10 mg/m³ 15 minutes. Form:
Respirable
CA British Columbia Provincial (Canada,
6/2017).
TWA: 2 mg/m³ 8 hours. Form: Respirable
STEL: 10 mg/m³ 15 minutes. Form:
Respirable
CA Ontario Provincial (Canada, 7/2015).
TWA: 2 mg/m³ 8 hours. Form: Respirable
fraction.
STEL: 10 mg/m³ 15 minutes. Form:
Respirable fraction.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 5 mg/m³ 8 hours. Form: fume
STEV: 10 mg/m³ 15 minutes. Form: fume
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 10 mg/m³ 15 minutes. Form:
respirable dust and fume
TWA: 2 mg/m³ 8 hours. Form: respirable
dust and fume
Ingredient name Exposure limits
Occupational exposure limits (Canada)
Environmental exposure
controls
:
Zinc Oxide NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 2 mg/m³ 8 hours. Form: Respirable
fraction
STEL: 10 mg/m³ 15 minutes. Form:
Respirable fraction
Ingredient name Exposure limits
Occupational exposure limits (Mexico)
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Respiratory protection :
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.18
1 [Air = 1]
2.3 kPa (17.5 mm Hg) [at 20°C]
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate 0.09 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: >93.3°C (>199.9°F)
Not available.
9.2
Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :100°C (212°F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
Heat of combustion :1.59 kJ/g
Aerosol product
Molecular weight :Not applicable.
Section 10. Stability and reactivity
The product is stable.Chemical stability :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Date of issue/Date of revision :4/2/2018 Date of previous issue :3/27/2018 Version :6 6/11
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SHW-85-NA-GHS-CA
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
No specific data.
:
:
Incompatible materials :
Section 11. Toxicological information
Acute toxicity
Not available.
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Titanium Dioxide Skin - Mild irritant Human -72 hours 300
Micrograms
Intermittent
-
Zinc Oxide Eyes - Mild irritant Rabbit -24 hours 500
milligrams
-
Skin - Mild irritant Rabbit -24 hours 500
milligrams
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Not available.
Aspiration hazard
Not available.
Information on toxicological effects
Classification
Titanium Dioxide -2B -
Product/ingredient name NTPIARCOSHA
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
:Not available.
Potential acute health effects
Date of issue/Date of revision :4/2/2018 Date of previous issue :3/27/2018 Version :6 7/11
A82W153 A-100® Exterior Acrylic Latex Satin
Deep Base
SHW-85-NA-GHS-CA
Not available.
No known significant effects or critical hazards.:Ingestion
No known significant effects or critical hazards.General :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects :Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects :Not available.
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
Zinc Oxide -60960 high
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Zinc Oxide Acute IC50 1.85 mg/l Marine water Algae - Skeletonema costatum 96 hours
Acute IC50 46 µg/l Fresh water Algae - Pseudokirchneriella
subcapitata - Exponential growth
phase
72 hours
Acute LC50 98 µg/l Fresh water Daphnia - Daphnia magna -
Neonate
48 hours
Acute LC50 1.1 ppm Fresh water Fish - Oncorhynchus mykiss 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Not available.
Date of issue/Date of revision :4/2/2018 Date of previous issue :3/27/2018 Version :6 8/11
A82W153 A-100® Exterior Acrylic Latex Satin
Deep Base
SHW-85-NA-GHS-CA
Section 12. Ecological information
Other adverse effects :No known significant effects or critical hazards.
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
:Disposal methods
Section 14. Transport information
-
-
-
-
-
-
Not regulated.Not regulated.
--
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No.No.
Not available.
:
Proper shipping name :
Ship type :Not available.
Pollution category :Not available.
Not available.
:
TDG
Classification
Not regulated.
-
-
-
No.
-
Mexico
Classification
Not regulated.
-
-
-
No.
-
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability
prior to shipment, and compliance with the applicable regulations is the sole
responsibility of the person offering the product for transport. People loading and
unloading dangerous goods must be trained on all of the risks deriving from the
substances and on all actions in case of emergency situations.
IATA
Not regulated.
-
-
-
No.
-
Date of issue/Date of revision :4/2/2018 Date of previous issue :3/27/2018 Version :6 9/11
A82W153 A-100® Exterior Acrylic Latex Satin
Deep Base
SHW-85-NA-GHS-CA
Section 15. Regulatory information
SARA 313
TSCA 5(a)2 proposed significant new use rules: 5-Chloro-2-methylisothiazolinone
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
Section 16. Other information
4/2/2018
History
Date of printing
Date of issue/Date of
revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use
or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject
to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to
ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use
of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to
determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the
product for any purpose other than the purpose shown in the applicable section of this SDS without first
Notice to reader
Date of previous issue
:
:
:
:
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
4/2/2018
3/27/2018
6
Hazardous Material Information System (U.S.A.)
1
0
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
CARCINOGENICITY - Category 2 Calculation method
Procedure used to derive the classification
Classification Justification
Date of issue/Date of revision :4/2/2018 Date of previous issue :3/27/2018 Version :6 10/11
A82W153 A-100® Exterior Acrylic Latex Satin
Deep Base
SHW-85-NA-GHS-CA
Section 16. Other information
referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for
information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from
any other source.
Date of issue/Date of revision :4/2/2018 Date of previous issue :3/27/2018 Version :6 11/11
A82W153 A-100® Exterior Acrylic Latex Satin
Deep Base
SHW-85-NA-GHS-CA
SAFETY DATA SHEET
1. Identification
PVC Medium Clear CementProduct identifier
Other means of identification
1101CSDS number
Part Numbers: Clear - 30350, 31017, 31018, 31019, 31020, 31021, 31535, 31536, 31537, 31538,31539, 31550, 31551, 31552, 31553, 31946, 31947, 31948, 31949, 32222, 32223, 32224, 32225Synonyms
Joining PVC PipesRecommended use
None known.Recommended restrictions
Manufacturer
Company Name Oatey Co.
Address 4700 West 160th St.
Cleveland, OH 44135
Telephone [phone]
E-mail [e-mail]
Transport Emergency Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)
Emergency First Aid 1-877-740-5015
Contact person MSDS Coordinator
2. Hazard(s) identification
Category 2Flammable liquidsPhysical hazards
Category 1Physical hazards not otherwise classified
Category 4Acute toxicity, oralHealth hazards
Category 2Skin corrosion/irritation
Category 2ASerious eye damage/eye irritation
Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 1Aspiration hazard
Category 1Health hazards not otherwise classified
Not classified.Environmental hazards
Label elements
Signal word Danger
Hazard statement Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and entersairways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Maycause drowsiness or dizziness.
Precautionary statement
Prevention Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.Keep container tightly closed. Ground and bond container and receiving equipment. Useexplosion-proof electrical/ventilating/lighting/equipment. Use non-sparking tools. Take action toprevent static discharges. Avoid breathing mist or vapor. Wash thoroughly after handling. Do noteat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wearprotective gloves/protective clothing/eye protection/face protection.
SDS CanadaPVC Medium Clear Cement
926291 Version #: 03 Revision date: 04/09/2018 Issue date: 12/17/2015 1 / 10
Distributor
Oatey Canada Supply Chain Services Co.
145 Walker Drive
Brampton, ON L6T 5P5, Canada
Response IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair):Take off immediately all contaminated clothing. Rinse skin with water or shower. IF INHALED:Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES:Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth.Do NOT induce vomiting. Take off contaminated clothing and wash it before reuse. In case of fire:Use appropriate media to extinguish.
Storage Keep cool. Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Other hazards Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.May form explosive peroxides.
Supplemental information Not applicable.
3. Composition/information on ingredients
Mixtures
109-99-9 30-50Furan, Tetrahydro-
CAS number %Chemical name
67-64-1 10-25Acetone
78-93-3 10-25Methyl ethyl ketone
9002-86-2 12-20Ethene, chloro-, homopolymer,Polyvinyl chloride; PVC;
108-94-1 10-20Cyclohexanone
112945-52-5 1-5Fumed Silica
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
4. First-aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISONCENTER or doctor/physician if you feel unwell.Inhalation
Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skinirritation occurs: Get medical advice/attention. Take off contaminated clothing and wash beforereuse.
Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.Eye contact
Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs,keep head low so that stomach content doesn't get into the lungs. Aspiration may causepulmonary edema and pneumonitis. If ingestion of a large amount does occur, call a poison controlcenter immediately.
Ingestion
Causes eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredvision. Skin irritation. May cause redness and pain. Vapors have a narcotic effect and may causeheadache, fatigue, dizziness and nausea.
Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically. Thermal burns: Flush with waterimmediately. While flushing, remove clothes which do not adhere to affected area. Call anambulance. Continue flushing during transport to hospital. In case of shortness of breath, giveoxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed.
Indication of immediate
medical attention and special
treatment needed
Take off all contaminated clothing immediately. IF exposed or concerned: Get medicaladvice/attention. Ensure that medical personnel are aware of the material(s) involved, and takeprecautions to protect themselves. Wash contaminated clothing before reuse.
General information
5. Fire-fighting measures
Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a sourceof ignition and flash back. During fire, gases hazardous to health may be formed.Specific hazards arising from
the chemical
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment
and precautions for firefighters
SDS CanadaPVC Medium Clear Cement
926291 Version #: 03 Revision date: 04/09/2018 Issue date: 12/17/2015 2 / 10
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can doso without risk.Fire fighting
equipment/instructions
Use standard firefighting procedures and consider the hazards of other involved materials. In theevent of fire, cool tanks with water spray. Cool containers exposed to flames with water until wellafter the fire is out.
Specific methods
Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosiveorganic peroxide when exposed to air or light or with age.General fire hazards
6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out oflow areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).Wear appropriate protective equipment and clothing during clean-up. Avoid inhalation of vapors ormists. Do not touch damaged containers or spilled material unless wearing appropriate protectiveclothing. Ventilate closed spaces before entering them. Local authorities should be advised ifsignificant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Personal precautions,
protective equipment and
emergency procedures
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Takeprecautionary measures against static discharge. Use only non-sparking tools. Keep combustibles(wood, paper, oil, etc.) away from spilled material. Use a non-combustible material like vermiculite,sand or earth to soak up the product and place into a container for later disposal. Use water sprayto reduce vapors or divert vapor cloud drift. Prevent entry into waterways, sewer, basements orconfined areas. Following product recovery, flush area with water.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.This product is miscible in water.
Methods and materials for
containment and cleaning up
Avoid discharge into drains, water courses or onto the ground.Environmental precautions
7. Handling and storage
Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame,sources of heat or sources of ignition. Protect material from direct sunlight. Take precautionarymeasures against static discharges. All equipment used when handling the product must begrounded. Use non-sparking tools and explosion-proof equipment. Do not taste or swallow. Avoidbreathing mist or vapor. Avoid contact with skin. Avoid contact with eyes. Avoid prolongedexposure. Avoid contact with clothing. Provide adequate ventilation. Wear appropriate personalprotective equipment. Observe good industrial hygiene practices. When using, do not eat, drink orsmoke. Wash hands thoroughly after handling.
Precautions for safe handling
Store locked up. Do not handle or store near an open flame, heat or other sources of ignition.Keep away from heat, sparks and open flame. This material can accumulate static charge whichmay cause spark and become an ignition source. Prevent electrostatic charge build-up by usingcommon bonding and grounding techniques. Store in a closed container away from incompatiblematerials. Store in original tightly closed container. Store in a cool, dry place out of direct sunlight.Keep container tightly closed. Store in a well-ventilated place. Keep out of the reach of children.Keep in an area equipped with sprinklers. Use care in handling/storage. Store away fromincompatible materials (see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. ACGIH Threshold Limit Values
ValueType FormComponents
STEL 750 ppmAcetone (CAS 67-64-1)
TWA 500 ppm
STEL 50 ppmCyclohexanone (CAS108-94-1)
TWA 20 ppm
TWA 3 mg/m3 Respirable particles.Ethene, chloro-,homopolymer, Polyvinylchloride; PVC; (CAS9002-86-2)STEL 100 ppmFuran, Tetrahydro- (CAS109-99-9)TWA 50 ppm
STEL 300 ppmMethyl ethyl ketone (CAS78-93-3)TWA 200 ppm
SDS CanadaPVC Medium Clear Cement
926291 Version #: 03 Revision date: 04/09/2018 Issue date: 12/17/2015 3 / 10
Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)
ValueType FormComponents
STEL 1800 mg/m3Acetone (CAS 67-64-1)
750 ppm
TWA 1200 mg/m3
500 ppm
STEL 200 mg/m3Cyclohexanone (CAS108-94-1)50 ppm
TWA 80 mg/m3
20 ppm
TWA 3 mg/m3 Respirable particles.Ethene, chloro-,homopolymer, Polyvinylchloride; PVC; (CAS9002-86-2)10 mg/m3 Total particulate.
STEL 295 mg/m3Furan, Tetrahydro- (CAS109-99-9)100 ppm
TWA 147 mg/m3
50 ppm
STEL 885 mg/m3Methyl ethyl ketone (CAS78-93-3)300 ppm
TWA 590 mg/m3
200 ppm
Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and
Safety Regulation 296/97, as amended)
ValueType FormComponents
STEL 500 ppmAcetone (CAS 67-64-1)
TWA 250 ppm
STEL 50 ppmCyclohexanone (CAS108-94-1)
TWA 20 ppm
TWA 3 mg/m3 Respirable fraction.Ethene, chloro-,homopolymer, Polyvinylchloride; PVC; (CAS9002-86-2)10 mg/m3 Total dust.
STEL 100 ppmFuran, Tetrahydro- (CAS109-99-9)TWA 50 ppm
STEL 100 ppmMethyl ethyl ketone (CAS78-93-3)TWA 50 ppm
Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act)
ValueType FormComponents
STEL 750 ppmAcetone (CAS 67-64-1)
TWA 500 ppm
STEL 50 ppmCyclohexanone (CAS108-94-1)TWA 20 ppm
TWA 10 mg/m3 Inhalable particles.Ethene, chloro-,homopolymer, Polyvinylchloride; PVC; (CAS9002-86-2)
STEL 100 ppmFuran, Tetrahydro- (CAS109-99-9)
TWA 50 ppm
SDS CanadaPVC Medium Clear Cement
926291 Version #: 03 Revision date: 04/09/2018 Issue date: 12/17/2015 4 / 10
Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act)
ValueType FormComponents
STEL 300 ppmMethyl ethyl ketone (CAS78-93-3)
TWA 200 ppm
Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)
ValueType FormComponents
STEL 750 ppmAcetone (CAS 67-64-1)
TWA 500 ppm
STEL 50 ppmCyclohexanone (CAS108-94-1)
TWA 20 ppm
TWA 3 mg/m3 Respirable particles.Ethene, chloro-,homopolymer, Polyvinylchloride; PVC; (CAS9002-86-2)10 mg/m3 Inhalable
STEL 100 ppmFuran, Tetrahydro- (CAS109-99-9)TWA 50 ppm
STEL 300 ppmMethyl ethyl ketone (CAS78-93-3)TWA 200 ppm
Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)
ValueType FormComponents
STEL 2380 mg/m3Acetone (CAS 67-64-1)
1000 ppm
TWA 1190 mg/m3
500 ppm
TWA 100 mg/m3Cyclohexanone (CAS108-94-1)25 ppm
TWA 10 mg/m3 Total dust.Ethene, chloro-,homopolymer, Polyvinylchloride; PVC; (CAS9002-86-2)
TWA 300 mg/m3Furan, Tetrahydro- (CAS109-99-9)
100 ppm
STEL 300 mg/m3Methyl ethyl ketone (CAS78-93-3)
100 ppm
TWA 150 mg/m3
50 ppm
Biological limit values
ACGIH Biological Exposure Indices
Value Sampling TimeDeterminant SpecimenComponents
50 mg/l Acetone Urine *Acetone (CAS 67-64-1)
80 mg/l 1,2-Cyclohexanediol,withhydrolysis
Urine *Cyclohexanone (CAS108-94-1)
8 mg/l Cyclohexanol,with hydrolysis Urine *
2 mg/l Tetrahydrofuran Urine *Furan, Tetrahydro- (CAS109-99-9)2 mg/l MEK Urine *Methyl ethyl ketone (CAS78-93-3)
* - For sampling details, please see the source document.
SDS CanadaPVC Medium Clear Cement
926291 Version #: 03 Revision date: 04/09/2018 Issue date: 12/17/2015 5 / 10
Exposure guidelines
Canada - Alberta OELs: Skin designation
Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin.
Furan, Tetrahydro- (CAS 109-99-9)Can be absorbed through the skin.
Canada - British Columbia OELs: Skin designation
Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin.Furan, Tetrahydro- (CAS 109-99-9)Can be absorbed through the skin.
Canada - Manitoba OELs: Skin designation
Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin.
Furan, Tetrahydro- (CAS 109-99-9)Can be absorbed through the skin.
Canada - Ontario OELs: Skin designation
Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin.
Furan, Tetrahydro- (CAS 109-99-9)Can be absorbed through the skin.
Canada - Quebec OELs: Skin designation
Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin.
Canada - Saskatchewan OELs: Skin designation
Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin.
Furan, Tetrahydro- (CAS 109-99-9)Can be absorbed through the skin.
US ACGIH Threshold Limit Values: Skin designation
Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin.
Furan, Tetrahydro- (CAS 109-99-9)Can be absorbed through the skin.
Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 airchanges per hour) should be used. Ventilation rates should be matched to conditions. Ifapplicable, use process enclosures, local exhaust ventilation, or other engineering controls tomaintain airborne levels below recommended exposure limits. If exposure limits have not beenestablished, maintain airborne levels to an acceptable level. Eye wash facilities and emergencyshower must be available when handling this product.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Wear safety glasses with side shields (or goggles).Eye/face protection
Skin protection
Wear appropriate chemical resistant gloves.Hand protection
Wear appropriate chemical resistant clothing.Other
If engineering controls do not maintain airborne concentrations below recommended exposurelimits (where applicable) or to an acceptable level (in countries where exposure limits have notbeen established), an approved respirator must be worn.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
When using, do not eat, drink or smoke. Wash hands after handling and before eating.General hygiene
considerations
9. Physical and chemical properties
Appearance
Liquid.Physical state
Translucent liquid.Form
Clear.Color
Solvent.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling
range
151 °F (66.11 °C)
Flash point 14.0 - 23.0 °F (-10.0 - -5.0 °C)
Evaporation rate 5.5 - 8
Not available.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
1.8
SDS CanadaPVC Medium Clear Cement
926291 Version #: 03 Revision date: 04/09/2018 Issue date: 12/17/2015 6 / 10
Flammability limit - upper
(%)
11.8
Explosive limit - lower (%)Not available.
Explosive limit - upper (%)Not available.
Vapor pressure 145 mm Hg @ 20 C
Vapor density 2.5
Relative density 0.93 +/- 0.02
Solubility(ies)
Solubility (water)Negligible
Partition coefficient
(n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity
Viscosity temperature
Other information
Bulk density
VOC (Weight %)
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Not available.
Not available.
Not available.
1200 - 2500 cP
77 °F (25 °C)
7.7 lbs/gal
< 510 g/l SCAQMD 1168/M316A
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials.
Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics.
No hazardous decomposition products are known.Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation May be fatal if swallowed and enters airways. May cause irritation to the respiratory system.Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea.Prolonged inhalation may be harmful.
Skin contact Causes skin irritation. Frequent or prolonged contact may defat and dry the skin, leading todiscomfort and dermatitis.
Eye contac Causes serious eye irritation.
Ingestion May be fatal if swallowed and enters airways. Harmful if swallowed.
Symptoms related to the
physical, chemical and
toxicological characteristics
Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Causeseye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skinirritation. May cause redness and pain.
Information on toxicological effects
Acute toxicit May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation.
Test ResultsComponentsSpecies
Cyclohexanone (CAS 108-94-1)
LD50 Rabbit
Dermal
Acute
948 mg/kg
LC50 Rat
Inhalation
8000 ppm, 4 hours
SDS CanadaPVC Medium Clear Cement
926291 Version #: 03 Revision date: 04/09/2018 Issue date: 12/17/2015 7 / 10
Test ResultsComponents Species
LD50 Rat
Oral
800 mg/kg
* Estimates for product may be based on additional component data not shown.
Causes skin irritation.Skin corrosion/irritation
Causes serious eye irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitization Not available.
This product is not expected to cause skin sensitization.Skin sensitization
No data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.Germ cell mutagenicity
Carcinogenicit Not classified.
ACGIH Carcinogens
Acetone (CAS 67-64-1)A4 Not classifiable as a human carcinogen.
Cyclohexanone (CAS 108-94-1)A3 Confirmed animal carcinogen with unknown relevance tohumans.
Ethene, chloro-, homopolymer, Polyvinyl chloride; PVC;(CAS 9002-86-2)A4 Not classifiable as a human carcinogen.
Furan, Tetrahydro- (CAS 109-99-9)A3 Confirmed animal carcinogen with unknown relevance tohumans.
Canada - Manitoba OELs: carcinogenicity
ACETONE (CAS 67-64-1)Not classifiable as a human carcinogen.
CYCLOHEXANONE (CAS 108-94-1)Confirmed animal carcinogen with unknown relevance to humans.
POLYVINYL CHLORIDE (PVC), RESPIRABLEFRACTION (CAS 9002-86-2)Not classifiable as a human carcinogen.
TETRAHYDROFURAN (CAS 109-99-9)Confirmed animal carcinogen with unknown relevance to humans.
IARC Monographs. Overall Evaluation of Carcinogenicity
Cyclohexanone (CAS 108-94-1)3 Not classifiable as to carcinogenicity to humans.
Ethene, chloro-, homopolymer, Polyvinyl chloride; PVC;(CAS 9002-86-2)3 Not classifiable as to carcinogenicity to humans.
Fumed Silica (CAS 112945-52-5)3 Not classifiable as to carcinogenicity to humans.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity -
single exposure
Narcotic effects. Respiratory tract irritation.
Specific target organ toxicity -
repeated exposure
Not classified.
Aspiration hazard May be fatal if swallowed and enters airways.
Chronic effects Prolonged inhalation may be harmful.
12. Ecological information
The product is not classified as environmentally hazardous. However, this does not exclude thepossibility that large or frequent spills can have a harmful or damaging effect on the environment.Ecotoxicity
Components Test ResultsSpecies
* Estimates for product may be based on additional component data not shown.
Cyclohexanone (CAS 108-94-1)
Aquatic
LC50Fish 481 - 578 mg/l, 96 hoursFathead minnow (Pimephales promelas)
No data is available on the degradability of this product.Persistence and degradability
No data available.Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
Acetone (CAS 67-64-1)-0.24
Cyclohexanone (CAS 108-94-1)0.81Furan, Tetrahydro- (CAS 109-99-9)0.46Methyl ethyl ketone (CAS 78-93-3)0.29
SDS CanadaPVC Medium Clear Cement
926291 Version #: 03 Revision date: 04/09/2018 Issue date: 12/17/2015 8 / 10
No data available.Mobility in soil
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This materialand its container must be disposed of as hazardous waste. Incinerate the material under controlledconditions in an approved incinerator. Do not incinerate sealed containers. Do not allow thismaterial to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches withchemical or used container. If discarded, this product is considered a RCRA ignitable waste, D001.Dispose of contents/container in accordance with local/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulations
The waste code should be assigned in discussion between the user, the producer and the wastedisposal company.Hazardous waste code
Dispose of in accordance with local regulations. Empty containers or liners may retain someproduct residues. This material and its container must be disposed of in a safe manner (see:Disposal instructions).
Waste from residues / unused
products
Since emptied containers may retain product residue, follow label warnings even after container isemptied. Empty containers should be taken to an approved waste handling site for recycling ordisposal.
Contaminated packaging
14. Transport information
TDG
UN1133UN number
AdhesivesUN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk
IIPacking group
DEnvironmental hazards
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
IATA
UN1133UN number
AdhesivesUN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk
IIPacking group
No.Environmental hazards
3LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
IMDG
UN1133UN number
AdhesivesUN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk
IIPacking group
No.Marine pollutant
Environmental hazards
F-E, S-DEmSRead safety instructions, SDS and emergency procedures before handling.Special precautions for user
Not available.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
Canadian regulations
Controlled Drugs and Substances Act
Not regulated.
SDS CanadaPVC Medium Clear Cement
926291 Version #: 03 Revision date: 04/09/2018 Issue date: 12/17/2015 9 / 10
Export Control List (CEPA 1999, Schedule 3)
Not listed.
Greenhouse Gases
Not listed.
Precursor Control Regulations
Acetone (CAS 67-64-1)Class B
Methyl ethyl ketone (CAS 78-93-3)Class B
International regulations
Stockholm Convention
Not applicable.
Rotterdam Convention
Not applicable.
Kyoto protocol
Not applicable.
Montreal Protocol
Not applicable.
Basel Convention
Not applicable.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS)YesAustralia
Domestic Substances List (DSL)YesCanada
Non-Domestic Substances List (NDSL)NoCanada
Inventory of Existing Chemical Substances in China (IECSC)YesChina
European Inventory of Existing Commercial ChemicalSubstances (EINECS)NoEurope
European List of Notified Chemical Substances (ELINCS)NoEurope
Inventory of Existing and New Chemical Substances (ENCS)YesJapan
Existing Chemicals List (ECL)YesKorea
New Zealand Inventory YesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances(PICCS)YesPhilippines
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
16. Other Information
17-December-2015Issue date
-Revision date
Version #01
List of abbreviations TWA: Time weighted average.STEL: Short term exposure limit.IATA: International Air Transport Association.IMDG: International Maritime Dangerous Goods.ACGIH: American Conference of Industrial Hygienists.CAS: Chemical Abstracts Service.OEL: Occupational Exposure Limit.LD50: Lethal dose 50% (dose that kills 50% of test animals).LC50: Lethal concentration 50% (concentration that kills 50% of test animals).MARPOL: International Convention for the Prevention of Pollution from Ships.
Oatey Co. cannot anticipate all conditions under which this information and its product, or theproducts of other manufacturers in combination with its product, may be used. It is the user’sresponsibility to ensure safe conditions for handling, storage and disposal of the product, and toassume liability for loss, injury, damage or expense due to improper use. The information in thesheet was written based on the best knowledge and experience currently available.
Disclaimer
SDS CanadaPVC Medium Clear Cement
926291 Version #: 03 Revision date: 04/09/2018 Issue date: 12/17/2015 10 / 10
SAFETY DATA SHEET
1. Identification
Oatey Purple Primer- NSF Listed for PVC and CPVCProduct identifier
Other means of identification
1402EProduct code
Part Numbers: 30755(TV), 30756(TV), 30757(TV), 30758, 30759, 30927Synonyms
Joining PVC PipesRecommended use
None known.Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Company Name Oatey Co.
Address 4700 West 160th St.
Cleveland, OH 44135
Telephone [phone]
E-mail [e-mail]
Transport Emergency Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)
Emergency First Aid 1-877-740-5015
Contact person MSDS Coordinator
2. Hazard(s) identification
Category 2Flammable liquidsPhysical hazards
Category 4Acute toxicity, oralHealth hazards
Category 2Skin corrosion/irritation
Category 2ASerious eye damage/eye irritation
Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 1Aspiration hazard
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and entersairways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Maycause drowsiness or dizziness.
Precautionary statement
Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightlyclosed. Ground/bond container and receiving equipment. Use explosion-proofelectrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionarymeasures against static discharge. Avoid breathing mist or vapor. Wash thoroughly afterhandling. Do not eat, drink or smoke when using this product. Use only outdoors or in awell-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection.
Response If swallowed: Immediately call a poison center/doctor. If on skin (or hair): Take off immediately allcontaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air andkeep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor ifyou feel unwell. Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medicaladvice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminatedclothing and wash before reuse. In case of fire: Use appropriate media to extinguish.
Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US
926733 Version #: 01 Revision date: - Issue date: 27-May-2015 1 / 10
Storage Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
classified (HNOC)
Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.May form explosive peroxides. Contains a chemical classified by the US EPA as a suspectedpossible carcinogen.
Supplemental information
Not applicable.
3. Composition/information on ingredients
Mixtures
67-64-1 25-40Acetone
CAS number %Chemical name
108-94-1 25-40Cyclohexanone
109-99-9 15-30Furan, Tetrahydro-
78-93-3 15-30Methyl ethyl ketone
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISONCENTER or doctor/physician if you feel unwell.Inhalation
Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skinirritation occurs: Get medical advice/attention.Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.Eye contact
Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs,keep head low so that stomach content doesn't get into the lungs. Aspiration may causepulmonary edema and pneumonitis.
Ingestion
Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eyeirritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Maycause respiratory irritation. Vapors have a narcotic effect and may cause headache, fatigue,dizziness and nausea. Skin irritation. May cause redness and pain.
Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically. Thermal burns: Flush with waterimmediately. While flushing, remove clothes which do not adhere to affected area. Call anambulance. Continue flushing during transport to hospital. In case of shortness of breath, giveoxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed.
Indication of immediate
medical attention and special
treatment needed
Take off all contaminated clothing immediately. Ensure that medical personnel are aware of thematerial(s) involved, and take precautions to protect themselves. Wash contaminated clothingbefore reuse.
General information
5. Fire-fighting measures
Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a sourceof ignition and flash back. During fire, gases hazardous to health may be formed.Specific hazards arising from
the chemical
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment
and precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can doso without risk.Fire fighting
equipment/instructions
Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods
Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosiveorganic peroxide when exposed to air or light or with age.General fire hazards
Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US
926733 Version #: 01 Revision date: - Issue date: 27-May-2015 2 / 10
6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out oflow areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist orvapor. Do not touch damaged containers or spilled material unless wearing appropriate protectiveclothing. Ventilate closed spaces before entering them. Local authorities should be advised ifsignificant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Personal precautions,
protective equipment and
emergency procedures
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Takeprecautionary measures against static discharge. Use only non-sparking tools. Keep combustibles(wood, paper, oil, etc.) away from spilled material. This product is miscible in water.
Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors ordivert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet toprevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up theproduct and place into a container for later disposal. Prevent entry into waterways, sewer,basements or confined areas. Following product recovery, flush area with water.
Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containersfor later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Methods and materials for
containment and cleaning up
Avoid discharge into drains, water courses or onto the ground.Environmental precautions
7. Handling and storage
Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame,sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proofgeneral and local exhaust ventilation. Take precautionary measures against static discharges. Allequipment used when handling the product must be grounded. Use non-sparking tools andexplosion-proof equipment. Avoid breathing mist or vapor. Avoid contact with eyes, skin, andclothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink orsmoke. Wear appropriate personal protective equipment. Wash hands thoroughly after handling.Observe good industrial hygiene practices.
Precautions for safe handling
Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic chargebuild-up by using common bonding and grounding techniques. Store in a cool, dry place out ofdirect sunlight. Store in original tightly closed container. Store in a well-ventilated place. Storeaway from incompatible materials (see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueTypeComponents
PEL 2400 mg/m3Acetone (CAS 67-64-1)
1000 ppm
PEL 200 mg/m3Cyclohexanone (CAS108-94-1)
50 ppm
PEL 590 mg/m3Furan, Tetrahydro- (CAS109-99-9)
200 ppm
PEL 590 mg/m3Methyl ethyl ketone (CAS78-93-3)
200 ppm
US. ACGIH Threshold Limit Values
ValueTypeComponents
STEL 750 ppmAcetone (CAS 67-64-1)
TWA 500 ppm
STEL 50 ppmCyclohexanone (CAS108-94-1)TWA 20 ppm
STEL 100 ppmFuran, Tetrahydro- (CAS109-99-9)
Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US
926733 Version #: 01 Revision date: - Issue date: 27-May-2015 3 / 10
US. ACGIH Threshold Limit Values
ValueTypeComponents
TWA 50 ppm
STEL 300 ppmMethyl ethyl ketone (CAS78-93-3)
TWA 200 ppm
US. NIOSH: Pocket Guide to Chemical Hazards
ValueTypeComponents
TWA 590 mg/m3Acetone (CAS 67-64-1)
250 ppm
TWA 100 mg/m3Cyclohexanone (CAS108-94-1)
25 ppm
STEL 735 mg/m3Furan, Tetrahydro- (CAS109-99-9)
250 ppm
TWA 590 mg/m3
200 ppm
STEL 885 mg/m3Methyl ethyl ketone (CAS78-93-3)
300 ppm
TWA 590 mg/m3
200 ppm
Biological limit values
ACGIH Biological Exposure Indices
Value Sampling TimeDeterminant SpecimenComponents
50 mg/l Acetone Urine *Acetone (CAS 67-64-1)
80 mg/l 1,2-Cyclohexanediol,withhydrolysis
Urine *Cyclohexanone (CAS108-94-1)
8 mg/l Cyclohexanol,with hydrolysis Urine *
2 mg/l Tetrahydrofuran Urine *Furan, Tetrahydro- (CAS109-99-9)
2 mg/l MEK Urine *Methyl ethyl ketone (CAS78-93-3)
* - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin.
US - Minnesota Haz Subs: Skin designation applies
Cyclohexanone (CAS 108-94-1)Skin designation applies.
US - Tennessee OELs: Skin designation
Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin.
US ACGIH Threshold Limit Values: Skin designation
Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin.Furan, Tetrahydro- (CAS 109-99-9)Can be absorbed through the skin.
US. NIOSH: Pocket Guide to Chemical Hazards
Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin.
Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 airchanges per hour) should be used. Ventilation rates should be matched to conditions. Ifapplicable, use process enclosures, local exhaust ventilation, or other engineering controls tomaintain airborne levels below recommended exposure limits. If exposure limits have not beenestablished, maintain airborne levels to an acceptable level. Eye wash facilities and emergencyshower must be available when handling this product.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Face shield is recommended. Wear safety glasses with side shields (or goggles).Eye/face protection
Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US
926733 Version #: 01 Revision date: - Issue date: 27-May-2015 4 / 10
Skin protection
Wear appropriate chemical resistant gloves.Hand protection
Wear appropriate chemical resistant clothing.Other
If engineering controls do not maintain airborne concentrations below recommended exposurelimits (where applicable) or to an acceptable level (in countries where exposure limits have notbeen established), an approved respirator must be worn.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, suchas washing after handling the material and before eating, drinking, and/or smoking. Routinely washwork clothing and protective equipment to remove contaminants.
General hygiene
considerations
9. Physical and chemical properties
Appearance
Liquid.Physical state
Translucent liquid.Form
PurpleColor
Solvent.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling
range
151 °F (66.11 °C)
Flash point 14.0 - 23.0 °F (-10.0 - -5.0 °C)
Evaporation rate 5.5 - 8
Not available.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
1.8
Flammability limit - upper
(%)
11.8
Explosive limit - lower (%)Not available.
Explosive limit - upper (%)Not available.
Vapor pressure 145 mm Hg @ 20 C
Vapor density 2.5
Relative density 0.84 +/- 0.02 @20°C
Solubility(ies)
Solubility (water)Negligible
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other information
Bulk density 7 lb/gal
VOC (Weight %)505 g/l SQACMD Method 24
10. Stability and reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity
Material is stable under normal conditions.Chemical stability
No dangerous reaction known under conditions of normal use.Possibility of hazardous
reactions
Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding theflash point. Contact with incompatible materials.Conditions to avoid
Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics.Incompatible materials
Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US
926733 Version #: 01 Revision date: - Issue date: 27-May-2015 5 / 10
No hazardous decomposition products are known.Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation May be fatal if swallowed and enters airways. Headache. Nausea, vomiting. May cause irritationto the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue,dizziness and nausea. Prolonged inhalation may be harmful.
Skin contact Causes skin irritation.
Eye contac Causes serious eye irritation.
Ingestion May be fatal if swallowed and enters airways. Harmful if swallowed. Harmful if swallowed. Dropletsof the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.
Symptoms related to the
physical, chemical and
toxicological characteristics
Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severeeye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Maycause respiratory irritation. Skin irritation. May cause redness and pain. Symptoms ofoverexosure ma be headache, dizziness, tiredness, nausea and vomitin .
Information on toxicological effects
Acute toxicit May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation.
Test ResultsComponents Species
Acetone (CAS 67-64-1)
LD50 Rabbit
Dermal
Acute
20 ml/kg
LC50 Rat
Inhalation
50 mg/l, 8 Hours
LD50 Rat
Oral
5800 mg/kg
Cyclohexanone (CAS 108-94-1)
LD50 Rabbit
Dermal
Acute
948 mg/kg
LC50 Rat
Inhalation
8000 ppm, 4 hours
LD50 Rat
Oral
1540 mg/kg
* Estimates for product may be based on additional component data not shown.
Causes skin irritation.Skin corrosion/irritation
Causes serious eye irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitization Not available.
This product is not expected to cause skin sensitization.Skin sensitization
No data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.Germ cell mutagenicity
Carcinogenicity In 2012 USEPA Integrated Risk Information System (IRIS) reviewed a two species inhalationlifetime study on THF conducted by NTP (1998). Male rats developed renal tumors and femalemice developed liver tumors while neither the female rats nor the male mice showed similarresults. Because the carcinogenic mechanisms could not be identified clearly in either species foreither tumor, the EPA determined that the male rat and female mouse findings are relevant to theassessment of carcinogenic potential in humans. Therefore, the IRIS review concludes that thesedata in aggregate indicate that there is "suggestive evidence of carcinogenic potential" followingexposure to THF by all routes of exposure.
IARC Monographs. Overall Evaluation of Carcinogenicity
Cyclohexanone (CAS 108-94-1) 3 Not classifiable as to carcinogenicity to humans.
Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US
926733 Version #: 01 Revision date: - Issue date: 27-May-2015 6 / 10
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity -
single exposure
Narcotic effects. May cause drowsiness and dizziness. Respiratory tract irritation.
Specific target organ toxicity -
repeated exposure
Not classified.
Aspiration hazard May be fatal if swallowed and enters airways.
Chronic effects Prolonged inhalation may be harmful.
12. Ecological information
The product is not classified as environmentally hazardous. However, this does not exclude thepossibility that large or frequent spills can have a harmful or damaging effect on the environment.Ecotoxicity
Components Test ResultsSpecies
Acetone (CAS 67-64-1)
Aquatic
LC50Fish > 100 mg/l, 96 hoursFathead minnow (Pimephales promelas)
* Estimates for product may be based on additional component data not shown.
Cyclohexanone (CAS 108-94-1)
Aquatic
LC50Fish 481 - 578 mg/l, 96 hoursFathead minnow (Pimephales promelas)
No data is available on the degradability of this product.Persistence and degradability
No data available.Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)Acetone (CAS 67-64-1)-0.24Cyclohexanone (CAS 108-94-1)0.81Furan, Tetrahydro- (CAS 109-99-9)0.46
Methyl ethyl ketone (CAS 78-93-3)0.29
No data available.Mobility in soil
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This materialand its container must be disposed of as hazardous waste. Do not allow this material to drain intosewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or usedcontainer. Dispose of contents/container in accordance with local/regional/national/internationalregulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulations
The waste code should be assigned in discussion between the user, the producer and the wastedisposal company.Hazardous waste code
Dispose of in accordance with local regulations. Empty containers or liners may retain someproduct residues. This material and its container must be disposed of in a safe manner (see:Disposal instructions).
Waste from residues / unused
products
Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.
Contaminated packaging
14. Transport information
DOT
UN1993UN number Flammable liquids, n.o.s. (Methyl ethyl ketone RQ = 26274 LBS, Acetone RQ = 13130 LBS)UN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk
3Label(s)IIPacking group
Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US
926733 Version #: 01 Revision date: - Issue date: 27-May-2015 7 / 10
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
IB2, T7, TP1, TP8, TP28Special provisions
150Packaging exceptions
202Packaging non bulk
242Packaging bulk
IATA
UN1993UN number
Flammable liquid, n.o.s. (Methyl ethyl ketone, Acetone)UN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk
IIPacking group
No.Environmental hazards 3HERG Code
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
IMDG
UN1993UN number
FLAMMABLE LIQUID, N.O.S. (Methyl ethyl ketone, Acetone)UN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk IIPacking group
No.Marine pollutant
Environmental hazards
F-E, S-EEmS
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
Not available.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
This product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Acetone (CAS 67-64-1) LISTEDCyclohexanone (CAS 108-94-1) LISTED
Furan, Tetrahydro- (CAS 109-99-9) LISTED
Methyl ethyl ketone (CAS 78-93-3) LISTED
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - YesDelayed Hazard - NoFire Hazard - YesPressure Hazard - NoReactivity Hazard - No
Hazard categories
SARA 302 Extremely hazardous substance
Not listed.
NoSARA 311/312 Hazardous
chemical
SARA 313 (TRI reporting)
Not regulated.
Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US
926733 Version #: 01 Revision date: - Issue date: 27-May-2015 8 / 10
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Not regulated.Safe Drinking Water Act
(SDWA)
Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and
Chemical Code Number
Acetone (CAS 67-64-1) 6532
Methyl ethyl ketone (CAS 78-93-3) 6714
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))
Acetone (CAS 67-64-1) 35 %WVMethyl ethyl ketone (CAS 78-93-3) 35 %WV
DEA Exempt Chemical Mixtures Code Number
Acetone (CAS 67-64-1) 6532
Methyl ethyl ketone (CAS 78-93-3) 6714
US state regulations
US. Massachusetts RTK - Substance List
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)Furan, Tetrahydro- (CAS 109-99-9)Methyl ethyl ketone (CAS 78-93-3)
US. New Jersey Worker and Community Right-to-Know Act
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
US. Pennsylvania Worker and Community Right-to-Know Law
Acetone (CAS 67-64-1)Cyclohexanone (CAS 108-94-1)Furan, Tetrahydro- (CAS 109-99-9)Methyl ethyl ketone (CAS 78-93-3)
US. Rhode Island RTK
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to containany chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Domestic Substances List (DSL)YesCanada
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
16. Other information, including date of preparation or last revision
27-May-2015Issue date
-Revision date
Version #01
Health: 2Flammability: 3Physical hazard: 0
HMIS® ratings
Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US
926733 Version #: 01 Revision date: - Issue date: 27-May-2015 9 / 10
NFPA ratings
02
3
The information in the sheet was written based on the best knowledge and experience currentlyavailable. Oatey Co. cannot anticipate all conditions under which this information and its product,or the products of other manufacturers in combination with its product, may be used. It is theuser’s responsibility to ensure safe conditions for handling, storage and disposal of the product,and to assume liability for loss, injury, damage or expense due to improper use.
Disclaimer
Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US
926733 Version #: 01 Revision date: - Issue date: 27-May-2015 10 / 10
Revised 12/30/15
DESCRIPTION
APPLICATION
PACKAGING
SHELF LIFE
CURE & SEAL WB is a water-based, non-yellowing, VOC
compliant acrylic polymer engineered to cure, seal, hard-
en, and dustproof freshly placed concrete and improve
the wearability and durability of aged concrete surfaces.
May contribute to LEED credits.
This low-odor, water-based formulation is ideal for interior
or exterior usage:
 Provides a tough glossy film that is resistant to
abrasion and common staining materials
 Prevents the adhesion of cementitious drop-
pings and the penetration of most oils and
greases
 Reduces maintenance and clean-up costs
 Cleans and brightens floors
 May be recoated prior to occupancy for a
glossy final finish
 May be recoated at any time without stripping
the prior application
Coverage: Ready to use. Do not dilute. Apply with a
sprayer, brush, roller or lambs wool applicator. Spraying
or a lambs wool applicator generally will provide superior
results. Avoid puddles. Apply in accordance with recom-
mended coverage rates.
Curing: 200 sq ft / gal
Dustproofing and Sealing: 200 – 400 sq ft / gal
Aged concrete: 200 – 400 sq ft / gal
For dustproofing and sealing benefits, apply two coats at
300 sq ft / gal. On broom or rough finished concrete, dou-
ble the coverage rate. Coverage may vary due to porosity
and conditions of the concrete. Application temperature
above 40o & rising is recommended.
New Concrete: CURE & SEAL WB should be applied
as soon as the surface water has disappeared and the
concrete surface will not be marred by the walking appli-
cator. At this point, apply in a uniform coat. For a superior
finish and added curing and sealing protection, apply a
second coat at 400 sq ft / gal.
Existing Concrete: Concrete surface must be clean,
dry or damp and free of all stains, oil, grease, dirt, and
incompatible coatings prior to application.
CURE & SEAL WB can be used on colored concrete and
will renovate existing concrete, brick or terrazzo floors.
These surfaces will be brighter and easier to clean and
maintain.
CURE & SEAL WB is compatible with most carpets, tile
and floor covering adhesives. Due to the wide variation in
the chemistry of adhesives, a test section is always rec-
ommended.
CURE & SEAL WB is available in 275 gallon totes, 55
gallon drums, and 5 gallon pails.
Shelf life of CURE & SEAL WB in the original tightly
closed containers is one year from the date of manufac-
ture. Do not allow the accumulation of water, dirt, or other
contaminants.
Water-based cure & seal (ASTM C-309 compliant)
CURE & SEAL WB
CLEANING
Application equipment can be cleaned with water if prod-
uct has not dried. Once product dries, xylene or other
approved solvents should be used.
TYPICAL PERFORMANCE DATA
Moisture Loss
(ASTM C-309) at 200 sq ft/gal (Kg/m2)
Test Result Required
0.39 Kg/m2 0.55 Kg/m2
STANDARDS
CURE & SEAL WB meets ASTM C-309, Type I, Class A
and B. V.O.C. emission requirements for curing and seal-
ing compounds (Actual VOC = 98 g/L).
Meets the Class A requirements for UV stability/yellowing
for ASTM C 1315, section 6.4.1; USDA accepted
T E C H N I C A L D A T A
1511 Baltimore Ave, Suite 600 Kansas City, MO 64108 www.specchemllc.com 866.791.8700
WARRANTY
NOTICE-READ CAREFULLY
CONDITIONS OF SALE
SpecChem offers this product for sale subject to and limited by the warranty which
may only be varied by written agreement of a duly authorized corporate officer of
SpecChem. No other representative of or for SpecChem is authorized to grant any
warranty or to waive limitation of liability set forth below.
WARRANTY LIMITATION
SpecChem warrants this product to be free of manufacturing defects. If the product
when purchased was defective and was within use period indicated on container or
carton, when used, SpecChem will replace the defective product with new product without charge to the purchaser. SpecChem makes no other warranty, either ex-
pressed or implied, concerning this product. There is no warranty of merchantability.
NO CLAIM OF ANY KIND SHALL BE GREATER THAN THE PURCHASE PRICE OF THE PRODUCT IN RESPECT OF WHICH DAMAGES ARE
CLAIMED.
INHERENT RISK
Purchaser assumes all risk associated with the use or application of the product.
1511 Baltimore Ave, Suite 600 Kansas City, MO 64108 www.specchemllc.com 866.791.8700
LIMITATIONS/PRECAUTIONS
 Does not provide a base for cementitious materials.
Not for use in fountains or pools.
 When used over colored concrete, CURE & SEAL
WB may enhance color variation or imperfections.
 Prepare a test panel to ensure acceptable results.
 Rubber wheeled vehicles may leave black marks.
 Protect from freezing.
 Contact SpecChem Technical Services for complete
application instructions and limitations.
 Additional precautions, safety and first aid infor-
mation are contained in the Material Safety Data
Sheet.
 Application temperature above 40o & rising is recom-
mended.
DO NOT EXPOSE TO OR APPLY NEAR FIRE OR
FLAMES. FOR WELL VENTILATED OR EXTERIOR USE ONLY!

Safety Data Sheet

Version 1
Cure & Seal WB
1.1 Trade Name (as labeled): Cure & Seal WB Synonyms: N/A CAS No: Mixture 1.2 Product Use: Water-based cure & seal 1.3 Company Name: SpecChem Company Address: 1511 Baltimore Ave; Suite 600 Company Address Cont: Kansas City, MO 64108 Business Phone: [phone] Website: www.specchemllc.com 1.4 Emergency Telephone Number: VelocityEHS 1-[phone] (North America) [phone] (International) 1-300-954-583 (Australia) 0-800-591-6042 (Brazil) 400-120-0751 (China) 000-800-100-4086 (India) 800-099-0731 (Mexico) Date of Last Revision: January 2, 2018 Date of Current Revision: July 1, 2018
EMERGENCY OVERVIEW: This product is a milky white liquid with a characteristic hydrocarbon odor. Health Hazards: May cause eye irritation. Flammability Hazards: This product is not a flammable liquid with a flash point of >200°F (93°C). Reactivity Hazards: None. Environmental Hazards: The environmental effects of this product have not been investigated, however release may cause long term adverse environmental effects. US DOT Symbols: Not Regulated EU and GHS Symbols: Not Applicable Signal Word: Warning 2.1 EU Labeling and Classification: This product meets the definition of a hazardous substance or preparation as defined by the European Union Council Directives 67/548/EEC, 1999/45/EC, 1272/2008/EC and subsequent Directives. EU HAZARD CLASSIFICATION OF INGREDIENTS PER DIRECTIVE 1272/2008/EC: Index Number: 212-22-7 is not listed in Annex I Substances not listed either individually or in group entries must be self classified. Components Contributing to Classification: Propylene glycol ether 2.2 Label Elements: GHS Hazard Classifications: Eye Irritation Category 2B Hazard Statements: H320 Causes eye irritation Precautionary Statements: P264 Wash thoroughly after handling
SECTION 1 – PRODUCT AND COMPANY IDENTIFICATION
SECTION 2 – HAZARDS IDENTIFICATION

Safety Data Sheet

Version 1
Cure & Seal WB
Response Statements: P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. P337+P313 If eye irritation persists: Get medical advice/ attention. Storage Statements: None applicable Disposal Statements: P501 Dispose of contents/container in accordance
with local/regional/national/international regulations. 2.3 Health Hazards or Risks From Exposure: Symptoms of Overexposure by Route of Exposure: The most significant routes of overexposure for this product are by contact with skin or eyes. The
symptoms of overexposure are described in the following paragraphs. Acute:
Inhalation: No serious effects anticipated under normal conditions. Skin Contact: May cause mild irritation to skin. Eye Contact: Contact with the eyes may be irritating. Ingestion: May cause gastrointestinal irritation, nausea, and vomiting. Chronic: Repeated exposure may cause skin dryness or cracking. Target Organs:
Acute: Eyes, Skin Chronic: Skin
Hazardous Ingredients WT% CAS No. EINECS No. Hazard Classification
Propylene glycol ether < 3% 770-35-4 212-22-7 Eye Irrit. 2
Balance of other ingredients are non-hazardous or less than 1% in concentration (or 0.1% for carcinogens, reproductive toxins, or respiratory sensitizers). Note: All WHMIS required information is included in appropriate sections based on the ANSI Z400.1-2010 format. This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR, EU Directives and the Japanese Industrial Standard JIS Z 7250:2000
4.1 Description of First Aid Measures: Eye Contact: If product enters the eyes, flush with plenty of water or eye wash solution for several minutes. Remove contacts if present and easy to do. Seek medical attention if irritation persists. Skin Contact: Wash skin thoroughly with soap and water after handling. Seek medical attention if irritation develops and persists. Inhalation: If breathing becomes difficult, remove victim to fresh air. If necessary, use artificial respiration to support vital functions. Seek medical attention. Ingestion: If product is swallowed, call physician or poison center if you feel unwell. If professional advice is not available, do not induce vomiting.
SECTION 4 – FIRST AID MEASURES
SECTION 3 – COMPOSITION / INFORMATION ON INGREDIENTS

Safety Data Sheet

Version 1
Cure & Seal WB
Never induce vomiting or give dilutents (milk or water) to someone who is unconscious, having convulsions, or who cannot swallow. Seek medical advice. Take a copy of the label and/or SDS with the victim to the health professional. Medical Conditions Generally Aggravated By Exposure: Pre-existing skin, respiratory system or eye problems may be aggravated by prolonged contact. 4.2 Symptoms and Effects Both Acute and Delayed: Exposure to the eyes may cause irritation. 4.3 Recommendations to Physicians: Treat symptoms and eliminate overexposure.

5.1 Fire Extinguishing Materials: Use the following fire extinguishing materials: Water Spray: Yes Foam: Yes Halon: Yes Carbon Dioxide: Yes Dry Chemical: Yes Other: Any “C” Class 5.2 Unusual Fire and Explosion Hazards: Irritating and toxic fumes may be produced at high temperatures. Use of water may result if the formation of a toxic aqueous solution. Do not allow run-off from fire fighting to enter drains or water courses. Explosive Sensitivity to Mechanical Impact: No
Explosive Sensitivity to Static Discharge: No 5.3 Special Fire-Fighting Procedures:
• Incipient fire responders should wear eye protection.
• Structural firefighters must wear Self-Contained Breathing
• Apparatus (SCBA) and full protective equipment.
• Isolate materials not yet involved in the fire and protect personnel.
• Move containers from fire area if this can be done without risk; otherwise, cool with carefully applied water spray.
• If possible, prevent run-off water from entering storm drains, bodies of water, or other environmentally sensitive areas.
SECTION 5 – FIRE FIGHTING MEASURES

Safety Data Sheet

Version 1
Cure & Seal WB

6.1 Personal Precautions, Protective Equipment and Emergency Procedures: Use cautious judgment when cleaning up spill. Wear suitable protective clothing, gloves, and eye/face protection. 6.2 Environmental Precautions: Construct a dike to prevent spreading. Keep out of sewers, storm drains, surface waters, and soils. 6.3 Spill and Leak Response: Small Spills:
• Collect material via broom or mop. Place in tightly sealed containers for proper disposal.
• Approach spill areas with caution.
• If liquid was introduced, create a dike or trench to contain material.
• Soak up with absorbent material such as clay, sand or other suitable non-reactive material. Large Spills:
• Place in leak-proof containers. Seal tightly for proper disposal.
• Dispose of in accordance with U.S. Federal, State, and local hazardous waste disposal regulations and those of Canada and its Provinces, those of Australia, Japan and EU Member States (see Section 13, Disposal Considerations).
7.1 Precautions for Safe Handling:
SECTION 7 - HANDLING AND STORAGE
SECTION 6 – ACCIDENTAL RELEASE MEASURES (STEPS FOR SPILLS)

Safety Data Sheet

Version 1
Cure & Seal WB
To prevent eye contact under the foreseeable conditions of use, wear appropriate safety eyewear. When handling, do not eat, drink, or smoke. Wash thoroughly after handling. Do not handle or store near heat, sparks, or flame. 7.2 Storage and Handling Practices: Keep away from incompatible materials. Keep container closed when not in use and store in well
ventilated area. 7.3 Specific Uses: 25% solids water-based cure & seal.
8.1 Exposure Parameters: Ingredients CAS No. OSHA PEL NIOSH PEL
Propylene glycol ether 770-35-4 Not listed Not listed
8.2 Exposure Controls: Ventilation and Engineering Controls: Use with adequate ventilation to ensure exposure levels are maintained below the limits provided above.
The following information on appropriate Personal Protective Equipment is provided to assist
employers in complying with OSHA regulations found in 29 CFR Subpart I (beginning at 1910.132), or
standards of EU member states (including EN 149 for respiratory PPE, and EN 166 for face/eye
protection), and those of Japan. Please reference applicable regulations and standards for relevant
details.
Respiratory Protection: Not required for properly ventilated areas. Maintain airborne contaminant concentrations below guidelines listed above, if applicable. If necessary, use only respiratory protection authorized in the U.S. Federal OSHA Respiratory Protection Standard (29 CFR 1910.134), equivalent U.S. State standards, Canadian CSA Standard Z94.4-93, the European Standard EN149, or EU member states. Eye Protection: Safety glasses or goggles are required. If necessary, refer to U.S. OSHA 29 CFR 1910.133, Canadian Standards, and the European Standard EN166, Australian Standards, or relevant Japanese Standards. Hand Protection: Chemical resistant gloves are required to prevent skin contact. If necessary, refer to U.S. OSHA 29 CFR 1910.138, the European Standard DIN EN 374,
SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION

Safety Data Sheet

Version 1
Cure & Seal WB
the appropriate Standards of Canada, Australian Standards, or relevant Japanese Standards. Body Protection: Use body protect appropriate to task being performed. If necessary, refer to appropriate Standards of Canada, or appropriate standards of the EU,
Australian Standards, or relevant Japanese Standards. If a hazard of injury to the feet exists due to falling objects, rolling objects, where objects may pierce the soles of the feet or where
employee’s feet may be exposed to electrical hazards, use foot protection, as described in
U.S. OSHA 29 CFR 1910.136.
9.1 Information on Basic Physical and Chemical Properties: Appearance (Physical State and Color): Milky white colored liquid Odor: Characteristic hydrocarbon Odor Threshold: No data available pH: No data available Melting/Freezing Point: No data available Boiling Point: 413°F (212°C) Flash Point: >200°F (93°C) Evaporation Rate: No data available Flammability (Solid; Gas): Not applicable Upper/Lower Flammability or Explosion Limits: Not data available Vapor Pressure (mm Hg @ 20°C (68° F): < 17mm Vapor Density: Heavier than air Relative Density: No data available Specific Gravity: 1.02 Solubility in Water: Fully miscible Weight per Gallon: No data available Partition Coefficient (n-octanol/water): No data available Auto-Ignition Temperature: No data available Decomposition Temperature: No data available Viscosity: No data available 9.2 Other Information: No data available
10.1 Reactivity: This product is not reactive. 10.2 Stability: Stable under conditions of normal storage and use. 10.3 Possibility of Hazardous Reactions: Will not occur. 10.4 Conditions to Avoid: Avoid excessive temperatures. 10.5 Incompatible Substances: Strong oxidizing agents.
SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES
SECTION 10 – STABILITY AND REACTIVITY

Safety Data Sheet

Version 1
Cure & Seal WB
10.6 Hazardous Decomposition Products: Carbon monoxide and dioxide smoke.
11.1 Information on Toxicological Effects: Toxicity Data:
Propylene glycol ether 770-35-4 LD50 Oral – Rat 2,830 mg/kg Suspected Cancer Agent: Ingredients within this product are found on one or more of the
following lists: FEDERAL OSHA Z LIST, NTP, IARC, or CAL/OSHA and therefore are considered to be cancer-causing
agents by these agencies. Irritancy: Skin and respiratory irritant. Sensitization to the Product: This product is not expected to cause skin sensitization. Germ Cell Mutagenicity: This product contains ingredients that are suspected to be a
germ cell mutagenic. Reproductive Toxicity: This product is not expected to be a human reproductive
toxicant.
12.1 Toxicity: Propylene glycol ether 770-35-4 LC50 – Fathead Minnow 280 mg/l – 96h 12.2 Persistence and Degradability: No specific data available on this product. 12.3 Bioaccumulative Potential: No specific data available on this product. 12.4 Mobility in Soil: No specific data available on this product. 12.5 Results of PBT and vPvB Assessment: No specific data available on this product. 12.6 Other Adverse Effects: No data available 12.7 Water Endangerment Class: At present, there are no ecotoxicological assessments for this product.
13.1 Waste Treatment Methods: Waste disposal must be in accordance with
appropriate U.S. Federal, State, and local regulations, those of Australia, EU Member States and Japan. 13.2 EU Waste Code: Not determined

SECTION 14 - TRANSPORTATION INFORMATION
SECTION 13 – DISPOSAL CONSIDERATIONS
SECTION 12 – ECOLOGICAL INFORMATION
SECTION 11 – TOXICOLOGY INFORMATION

Safety Data Sheet

Version 1
Cure & Seal WB
14.1 U.S. Department of Transportation (DOT) Shipping Regulations:
This product is classified (per 49 CFR 172.101) by the U.S. Department of Transportation, as follows. UN Identification Number: Not applicable Proper Shipping Name: Not regulated Hazard Class Number and Description: Not applicable Packing Group: Not applicable DOT Label(s) Required: Not applicable North American Emergency Response Guidebook Number: Not applicable 14.2 Environmental Hazards: Marine Pollutant: The components of this product are designated by the Department of Transportation to be Marine Pollutants
(49 CFR 172.101, Appendix B). 14.3 Special Precaution for User: None 14.4 International Air Transport Association Shipping Information (IATA): Not regulated. 14.5 International Maritime Organization Shipping Information (IMO): UN Identification Number: Not applicable Proper Shipping Name: Not regulated Hazard Class Number and Description: Not applicable Packing Group: Not applicable EMS-No: Not applicable
15.1 Safety, Health and Environmental Regulations Specific for the Substance or Mixture:
United States Regulations: U.S. SARA Reporting Requirements:
The components of this product are not subject to the reporting requirements of Sections 302, 304, and 313 of Title III of the Superfund Amendments and Reauthorization Act. U.S. SARA 311/312: Acute Health: Yes; Chronic Health: No; Fire: No; Reactivity; No U.S. CERCLA Reportable Quantity:
None U.S. TSCA Inventory Status: The components of this product are listed on the TSCA Inventory or are exempted from listing. Other U.S. Federal Regulations:
None known California Safe Drinking Water and Toxic Enforcement Act (Proposition 65): This product does not contain ingredients on the Proposition 65 Lists. 15.2 Canadian Regulations: Canadian DSL/NDSL Inventory Status:
Components are DSL Listed, NDSL Listed and/or are exempt from listing Other Canadian Regulations: Not applicable Canadian Environmental Protection Act (CEPA) Priorities Substances Lists:
SECTION 15 – REGULATORY INFORMATION

Safety Data Sheet

Version 1
Cure & Seal WB
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations. Canadian WHMIS Classification and Symbols: This product is Class B2, Flammable Liquid, and D2B, Materials causing other toxic effects, per WHMIS Controlled Product Regulations.
15.3 European Economic Community Information: This product meets the definition of a hazardous substance or preparation as defined by the European
Union Council Directives 67/548/EEC, 1999/45/EC, 1272/2008/EC and subsequent Directives. See Section 2 for Details. Chemical Safety Assessment: No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier. 15.4 Australian Information for Product: Components of this product are listed on the International Chemical Inventory list. 15.5 Japanese Information for Product: Japanese Minister of International Trade and Industry (MITI) Status: The components of this product are not
listed as Class I specified Chemical Substances, Class II Specified Chemical Substances, or Designated Chemical Substances by the Japanese MITI. 15.6 International Chemical Inventories: Listing of the components on individual country Chemical Inventories is as follows:
Australian Inventory of Chemical Substances (AICS): Listed Korean Existing Chemicals List (ECL): Listed
Japanese Existing National Inventory of Chemical Substances (ENCS): Listed Philippines Inventory if Chemicals and Chemical Substances (PICCS): Listed U.S. TSCA: Listed
Prepared By: Chris Eigbrett (MSDS to GHS Compliance) Date of Printing: July 1, 2018 The information contained herein is believed to be accurate but is not warranted to be so. Data and calculations are based on information furnished by the manufacturer of the product and manufacturers of the components of the product. Users are advised to confirm in advance of the need that information is current, applicable and suited to the circumstances of use. This safety sheet cannot cover all possible situations which the user may experience during processing. Each aspect of your operation should be examined to determine if, or where, additional precautions may be necessary. All health and safety information contained in this bulletin should be provided to your employees or customers. SpecChem assumes no responsibility for injury to vendee or third party person proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Furthermore, SpecChem assumes no responsibility for injury caused by abnormal use of this material even if reasonable safety procedures are followed. Compliance with all applicable federal, state, and local laws and local regulations remains the responsibility of the user.
SECTION 16 – OTHER INFORMATION

Safety Data Sheet

Version 1
Cure & Seal WB
END OF SDS SHEET
DTM ACRYLIC Semi-Gloss Acrylic CoatingDeep Base
Not available.
Liquid.
US / Canada: [phone]Mexico: SETIQ 01-800-00-214-00 / D.F. 5559-1588 24 hours / 365 days a year
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone number of the company
Section 1. Identification
:
:
:
:
Manufacturer :THE SHERWIN-WILLIAMS COMPANY101 W. Prospect AvenueCleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
B66W213
B66W213Product code :
Product Information
Telephone Number
:US / Canada: [phone]
Mexico: Not Available
Regulatory Information Telephone Number :US / Canada: [phone]Mexico: Not Available
Transportation Emergency
Telephone Number
:US / Canada: [phone]Mexico: SETIQ 01-800-00-214-00 / D.F. 5559-1588 24 hours / 365 days a year
CAS #:Not applicable.
Supplier :Compania Sherwin-Williams S.A. de C.V.Poniente 140 No.595Col. Industrial Vallejo, Del. AzcapotzalcoC.P. 02300, Ciudad de México, México
Section 2. Hazards identification
CARCINOGENICITY - Category 1ATOXIC TO REPRODUCTION (Unborn child) - Category 2SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Classification of the
substance or mixture
:
Signal word :Danger
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 10.2%
Hazard statements :H350 - May cause cancer.H361 - Suspected of damaging the unborn child.H373 - May cause damage to organs through prolonged or repeated exposure.
Date of issue/Date of revision :5/2/2017 Date of previous issue :4/18/2017 Version :1.01 1/11
Section 2. Hazards identification
Hazards not otherwise classified :None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage.
Supplemental label elements WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.Adequate ventilation required when sanding or abrading the dried film. If Adequate ventilation cannot be provided wear an approved particulate respirator (NIOSH approved). Follow respirator manufacturer's directions for respirator use. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Abrading or sanding of the dry film may release Crystalline Silica which has been shown to cause lung damage and cancer under long term exposure.
Prevention :P201 - Obtain special instructions before use.P202 - Do not handle until all safety precautions have been read and understood.P280 - Wear protective gloves. Wear eye or face protection. Wear protective clothing.P260 - Do not breathe vapor.
Response :P314 - Get medical attention if you feel unwell.P308 + P313 - IF exposed or concerned: Get medical attention.
Storage :P405 - Store locked up.
Disposal :P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations.
Section 3. Composition/information on ingredients
Titanium Dioxide 6.08 13463-67-7
2-(2-Methoxyethoxy)-ethanol 4.14 111-77-3Cristobalite0.15 14464-46-1
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of identification :Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
:
:
:
Description of necessary first aid measures
Date of issue/Date of revision :5/2/2017 Date of previous issue :4/18/2017 Version :1.01 2/11
Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Ingestion :
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:reduced fetal weightincrease in fetal deathsskeletal malformations
Adverse symptoms may include the following:reduced fetal weightincrease in fetal deathsskeletal malformations
Adverse symptoms may include the following:reduced fetal weightincrease in fetal deathsskeletal malformations
:
:
:
Eye contact :No specific data.
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Specific hazards arising from the chemical In a fire or if heated, a pressure increase will occur and the container may burst.
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
None known.
Suitable extinguishing media :
Unsuitable extinguishing media :
Date of issue/Date of revision :5/2/2017 Date of previous issue :4/18/2017 Version :1.01 3/11
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.
Hazardous thermal decomposition products Decomposition products may include the following materials:carbon dioxide
carbon monoxidemetal oxide/oxides
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
:
:
Special protective actions for fire-fighters :
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Section 7. Handling and storage
Advice on general
occupational hygiene
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative
made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Date of issue/Date of revision :5/2/2017 Date of previous issue :4/18/2017 Version :1.01 4/11
Section 7. Handling and storage
Conditions for safe storage,
including any incompatibilities
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.Use appropriate containment to avoid environmental contamination.
:
Titanium Dioxide ACGIH TLV (United States, 3/2016).
TWA: 10 mg/m³ 8 hours.OSHA PEL (United States, 6/2016). TWA: 15 mg/m³ 8 hours. Form: Total dust
2-(2-Methoxyethoxy)-ethanol None.Cristobalite OSHA PEL Z3 (United States, 6/2016).
TWA: 250 mppcf / 2 x (%SiO2+5) 8 hours.
Form: Respirable TWA: 10 mg/m³ / 2 x (%SiO2+2) 8 hours.Form: Respirable TWA: 30 mg/m³ / 2 x (%SiO2+2) 8 hours.Form: Total dustOSHA PEL (United States, 6/2016). TWA: 50 µg/m³ 8 hours. Form: Respirable dustACGIH TLV (United States, 3/2016).
TWA: 0.025 mg/m³ 8 hours. Form:Respirable fractionNIOSH REL (United States, 10/2013).
TWA: 0.05 mg/m³ 10 hours. Form: respirable dust
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering controls :If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Control parameters
Individual protection measures
Occupational exposure limits (OSHA United States)
None.
Ingredient name Exposure limits
Occupational exposure limits (Canada)
Environmental exposure controls :
None.
Ingredient name Exposure limits
Occupational exposure limits (Mexico)
Date of issue/Date of revision :5/2/2017 Date of previous issue :4/18/2017 Version :1.01 5/11
Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
:
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures :
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.11
1 [Air = 1]
2.3 kPa (17.5 mm Hg) [at 20°C]
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate 0.09 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: >93.3°C (>199.9°F)
Not available.
9
Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Not available.Odor threshold
Partition coefficient: n-octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :100°C (212°F)
Flammability (solid, gas):Not available.
Lower and upper explosive (flammable) limits :Lower: 0.6%Upper: 12.5%
Decomposition temperature :Not available.
Date of issue/Date of revision :5/2/2017 Date of previous issue :4/18/2017 Version :1.01 6/11
Section 9. Physical and chemical properties
Heat of combustion :3.135 kJ/g
Aerosol product
Molecular weight :Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.Chemical stability
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Not available.
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Titanium Dioxide Skin - Mild irritant Human -72 hours 300 Micrograms Intermittent
-
2-(2-Methoxyethoxy)-ethanol Eyes - Mild irritant Rabbit -24 hours 500 milligrams -
Eyes - Moderate irritant Rabbit -500 milligrams -
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
Classification
Titanium Dioxide -2B -Cristobalite -1 Known to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
Date of issue/Date of revision :5/2/2017 Date of previous issue :4/18/2017 Version :1.01 7/11
Section 11. Toxicological information
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
2-(2-Methoxyethoxy)-ethanol Category 3 Not applicable.Respiratory tract irritation and Narcotic effects
Name Category
Name Category
2-(2-Methoxyethoxy)-ethanol Category 2 Not determined Not determinedCristobaliteCategory 1 Inhalation respiratory tract
Aspiration hazard
Not available.
Route of exposure Target organs
Route of exposure Target organs
Not available.
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
May cause damage to organs through prolonged or repeated exposure.General :
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:reduced fetal weightincrease in fetal deathsskeletal malformations
Adverse symptoms may include the following:reduced fetal weightincrease in fetal deathsskeletal malformations
Adverse symptoms may include the following:reduced fetal weightincrease in fetal deathsskeletal malformations
:
:
:
Eye contact :No specific data.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
:Not available.
Potential acute health effects
Potential immediate effects :Not available.
Short term exposure
Potential delayed effects :Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects :Not available.
Date of issue/Date of revision :5/2/2017 Date of previous issue :4/18/2017 Version :1.01 8/11
May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
Suspected of damaging the unborn child.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Numerical measures of toxicity
Oral 102150 mg/kg
Route ATE value
Acute toxicity estimates
Section 12. Ecological information
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Not available.
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours2-(2-Methoxyethoxy)-ethanol Acute EC50 >930 ppm Fresh water Daphnia - Daphnia magna 48 hoursAcute LC50 7500000 µg/l Fresh water Fish - Lepomis macrochirus 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
:Disposal methods
Date of issue/Date of revision :5/2/2017 Date of previous issue :4/18/2017 Version :1.01 9/11
Section 14. Transport information
-
-
-
-
-
-
Not regulated.Not regulated.
--
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional information
Environmental hazards
Special precautions for user
Transport in bulk according to Annex II of MARPOL and the IBC Code
No.No.
Not available.
:
Proper shipping name :
Ship type :Not available.
Pollution category :Not available.
Not available.
:
TDG
Classification
Not regulated.
-
-
-
No.
Mexico
Classification
Not regulated.
-
-
-
No.
-
Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.
IATA
Not regulated.
-
-
-
No.
-
Section 15. Regulatory information
SARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.
California Prop. 65
Section 16. Other information
Hazardous Material Information System (U.S.A.)
2
0
0
*Health
Flammability
Physical hazards
The customer is responsible for determining the PPE code for this material.
Date of issue/Date of revision :5/2/2017 Date of previous issue :4/18/2017 Version :1.01 10/11
Section 16. Other information
5/2/2017
History
Date of printing
Date of issue/Date of revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use
or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first
referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for
information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from
any other source.
Notice to reader
Date of previous issue
:
:
:
:
Key to abbreviations :ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations
5/2/2017
4/18/2017
1.01
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller [phone].
CARCINOGENICITY - Category 1A Calculation methodTOXIC TO REPRODUCTION (Unborn child) - Category 2 Calculation methodSPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method
Procedure used to derive the classification
Classification Justification
Date of issue/Date of revision :5/2/2017 Date of previous issue :4/18/2017 Version :1.01 11/11

Version: 1.1 Revision Date: 05/11/2023

SAFETY DATA SHEET
1. Identification

Material name: DYMONIC 100 GRAY - 30 CTG CS
Material: 965712C323

Recommended use and restriction on use
Recommended use:
Restrictions on use:

Manufacturer/Importer/Supplier/Distributor Information
Tremco Canadian Sealants 220 Wicksteed Ave Toronto ON M4H 1G7 CA
Contact person:
Telephone:
Emergency telephone number:

2. Hazard(s) identification

Hazard Classification
Health Hazards
Acute toxicity (Inhalation - vapor) Category 4
Acute toxicity (Inhalation - dust and
mist)
Category 4
Respiratory sensitizer Category 1
Skin sensitizer Category 1
Carcinogenicity Category 1A
Toxic to reproduction Category 1B

Unknown toxicity - Health

Environmental Hazards
Acute hazards to the aquatic environment Category 3
Chronic hazards to the aquatic environment Category 3

Unknown toxicity - Environment

Version: 1.1 Revision Date: 05/11/2023

Hazard Symbol:

Signal Word:
Hazard Statement:

Precautionary
Statements
Prevention:

Response:

Storage:
Disposal:

Hazard(s) not otherwise
classified (HNOC):
3. Composition/information on ingredients
Label Elements

Version: 1.1 Revision Date: 05/11/2023

Mixtures

Chemical Identity CAS number Content in percent (%)*
Calcium carbonate 471-34-1 20 - <50%
Polyvinyl chloride 9002-86-2 5 - <10%
Calcium Carbonate (Limestone) 1317-65-3 5 - <10%
Xylene 1330-20-7 1 - <5%
Trade Secret Trade Secret 1 - <5%
Titanium dioxide 13463-67-7 1 - <2.5%
Diisodecyl phthalate 26761-40-0 0.3 - <1%
Ethylbenzene 100-41-4 0.1 - <1%
Isophorone Diisocyanate 4098-71-9 0.5 - <1%
Hydrotreated heavy naphthenic distillate 64742-52-5 0.1 - <1%
Stearic acid 57-11-4 0.1 - <1%
Dibutyl tin dilaurate 77-58-7 0.1 - <0.3%
Iodopropynyl butylcarbamate 55406-53-6 0.01 - <0.1% * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
4. First-aid measures
Description of necessary first-aid measures
Inhalation:
Get medical attention if symptoms occur. Destroy or thoroughly clean contaminated shoes. Immediately remove contaminated clothing and
shoes and wash skin with soap and plenty of water. If skin irritation or an allergic skin reaction develops, get medical attention.
Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Call a physician or poison control center immediately.
Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Most important symptoms/effects, acute and delayed
Symptoms:

Hazards:

Indication of immediate medical attention and special treatment needed

Treatment:

5. Fire-fighting measures

Version: 1.1 Revision Date: 05/11/2023

General Fire Hazards: No unusual fire or explosion hazards noted.

Suitable (and unsuitable) extinguishing media

Suitable extinguishing
media:
Use fire-extinguishing media appropriate for surrounding materials.

Unsuitable extinguishing
media:
Do not use water jet as an extinguisher, as this will spread the fire.

During fire, gases hazardous to health may be formed.

Special protective equipment and precautions for fire-fighters

Special fire-fighting
procedures:

Special protective equipment
for fire-fighters:

6. Accidental release measures

Ventilate closed spaces before entering them. Evacuate area. See Section 8 of the SDS for Personal Protective Equipment. Keep upwind. Keep unauthorized personnel away. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. Collect spillage in containers, seal securely and deliver for disposal according to local regulations.

Do not contaminate water sources or sewer. Prevent further leakage or spillage if safe to do so. Avoid release to the environment.

7. Handling and storage
Handling
Mechanical ventilation or local exhaust ventilation may be required. Observe good industrial hygiene practices. Observe occupational exposure limits and minimize the risk of inhalation of dust.

Version: 1.1 Revision Date: 05/11/2023

Safe handling advice:

Contact avoidance measures:
Hygiene measures:

Storage

Store locked up.
Safe packaging materials:
8. Exposure controls/personal protection

Control Parameters
Occupational Exposure Limits
Chemical Identity Type Exposure Limit Values Source
Calcium carbonate - Total dust. PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000), as amended (02 2006) Calcium carbonate - Respirable fraction. PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000), as amended (02 2006)
Calcium carbonate - Total dust. PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000), as amended (01 2017)
Calcium carbonate - Respirable fraction. TWA 5 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000), as amended (09 2016)
Calcium carbonate - Inhalable particles. TWA 10 mg/m3 US. ACGIH Threshold Limit Values, as amended (01 2021) Calcium carbonate - Respirable particles. TWA 3 mg/m3 US. ACGIH Threshold Limit Values, as amended (01 2021) Calcium carbonate - Respirable fraction. TWA 15 millions of particles per cubic foot of air
US. OSHA Table Z-3 (29 CFR 1910.1000), as amended (09 2016)
Calcium carbonate - Total dust. TWA 15 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000), as amended (09 2016)
TWA 50 millions of particles per cubic foot of air
US. OSHA Table Z-3 (29 CFR 1910.1000), as amended (09 2016)
Calcium carbonate - Respirable fraction. PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000), as amended (01 2017) Polyvinyl chloride - Respirable fraction. TWA 1 mg/m3 US. ACGIH Threshold Limit Values, as amended (2011) Polyvinyl chloride - as vinyl chloride monomer TWA 1 ppm US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053), as amended (02 2006)

Version: 1.1 Revision Date: 05/11/2023

STEL 5 ppm US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053), as amended (02 2006)
OSHA_ACT 0.5 ppm US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053), as amended (02 2006)
Polyvinyl chloride - Respirable fraction. PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000), as amended (02 2006) Polyvinyl chloride - Total dust. PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000), as amended (02 2006)
TWA 50 millions of particles per cubic foot of air
US. OSHA Table Z-3 (29 CFR 1910.1000), as amended (2000)
Polyvinyl chloride - Respirable fraction. TWA 15 millions of particles per cubic foot of air
US. OSHA Table Z-3 (29 CFR 1910.1000), as amended (2000)
Polyvinyl chloride - Total dust. TWA 15 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000), as amended (2000)
Polyvinyl chloride - Respirable fraction. TWA 5 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000), as amended (2000) Calcium Carbonate (Limestone) - Total dust. PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000), as amended (02 2006) Calcium Carbonate (Limestone) - Respirable fraction.
PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000), as amended (02 2006)
Xylene PEL 100 ppm 435 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000), as amended (02 2006)
TWA 20 ppm US. ACGIH Threshold Limit Values, as amended (01 2022)
Titanium dioxide - Total dust. PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000), as amended (02 2006)
Titanium dioxide - Respirable fraction. TWA 15 millions of particles per cubic foot of air
US. OSHA Table Z-3 (29 CFR 1910.1000), as amended (03 2016)
Titanium dioxide - Total dust. TWA 15 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000), as amended (03 2016) Titanium dioxide - Respirable fraction. TWA 5 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000), as amended (03 2016)
Titanium dioxide - Total dust. TWA 50 millions of particles per cubic foot of air
US. OSHA Table Z-3 (29 CFR 1910.1000), as amended (03 2016)
Titanium dioxide - Respirable finescale particles TWA 2.5 mg/m3 US. ACGIH Threshold Limit Values, as amended (01 2022) Titanium dioxide - Respirable nanoscale particles TWA 0.2 mg/m3 US. ACGIH Threshold Limit Values, as amended (01 2022) Ethylbenzene TWA 20 ppm US. ACGIH Threshold Limit Values, as amended (2011)
PEL 100 ppm 435 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000), as amended (02 2006) Isophorone Diisocyanate TWA 0.005 ppm US. ACGIH Threshold Limit Values, as amended (2008)
Hydrotreated heavy naphthenic distillate PEL 500 ppm 2,000 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000), as amended (02 2006) Hydrotreated heavy naphthenic distillate - Mist. PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000), as amended (02 2006) Hydrotreated heavy naphthenic distillate - TWA 5 mg/m3 US. ACGIH Threshold Limit Values, as amended (03 2014)

Version: 1.1 Revision Date: 05/11/2023

Inhalable fraction. Stearic acid - Respirable fraction. TWA 3 mg/m3 US. ACGIH Threshold Limit Values, as amended (03 2017) Stearic acid - Inhalable fraction. TWA 10 mg/m3 US. ACGIH Threshold Limit Values, as amended (03 2017) Dibutyl tin dilaurate - as Sn STEL 0.2 mg/m3 US. ACGIH Threshold Limit Values, as amended (2011)
TWA 0.1 mg/m3 US. ACGIH Threshold Limit Values, as amended (2011)
PEL 0.1 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000), as amended (02 2006)
Chemical name Type Exposure Limit Values Source
Calcium carbonate - Total dust. STEL 20 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Calcium carbonate - Respirable fraction. TWA 3 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Calcium carbonate - Total dust. TWA 10 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Calcium carbonate - Total dust. TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
Calcium carbonate - Respirable fraction. TWA 3 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (01 2020)
TWA 10 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (06 2020)
Calcium carbonate - Respirable fraction. TWA 3 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (06 2020)
Calcium carbonate - Respirable particles. TWA 3 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (01 2020)
Calcium carbonate - Inhalable particles. TWA 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (01 2020)
Calcium carbonate - Inhalable fraction. TWA 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (01 2020)
Polyvinyl chloride - Respirable. TWA 1 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Polyvinyl chloride - Respirable fraction. TWA 1 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (11 2010)
Polyvinyl chloride - Total dust. TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
Calcium Carbonate (Limestone) - Total dust. STEL 20 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
TWA 10 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board);

Version: 1.1 Revision Date: 05/11/2023

as amended (07 2007)
Calcium Carbonate (Limestone) - Respirable fraction.
TWA 3 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Calcium Carbonate (Limestone) - Total dust. TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
Xylene STEL 150 ppm Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
TWA 100 ppm Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Xylene STEL 150 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (11 2010)
TWA 100 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (11 2010)
Xylene TWA 100 ppm 434 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
STEL 150 ppm 651 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
Calcium oxide TWA 2 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Calcium oxide TWA 2 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (12 2007)
Calcium oxide TWA 2 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
Titanium dioxide - Total dust. TWA 10 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Titanium dioxide - Respirable fraction. TWA 3 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Titanium dioxide TWA 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (11 2010)
Titanium dioxide - Total dust. TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
Ethylbenzene TWA 20 ppm Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (09 2011)
Ethylbenzene TWA 20 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (06 2015)
Ethylbenzene TWA 20 ppm Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (03 2020)
Isophorone Diisocyanate TWA 0.005 ppm Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
CEILING 0.01 ppm Canada. British Columbia OELs: Table of

Version: 1.1 Revision Date: 05/11/2023

Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Isophorone Diisocyanate TWA 0.005 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (06 2015)
CEV 0.02 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (06 2015)
Isophorone Diisocyanate TWA 0.005 ppm 0.045 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
Hydrotreated heavy naphthenic distillate - Mist. TWA 1 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (05 2013)
Hydrotreated heavy naphthenic distillate - Inhalable fraction.
TWA 5 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (06 2015)
Hydrotreated heavy naphthenic distillate - Inhalable dusts and mists.
TWA 5 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (04 2022)

Chemical name Type Exposure Limit Values Source
Calcium carbonate - Total dust. STEL 20 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Calcium carbonate - Respirable fraction. TWA 3 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Calcium carbonate - Total dust. TWA 10 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Calcium carbonate - Total dust. TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
Calcium carbonate - Respirable fraction. TWA 3 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (01 2020)
TWA 10 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (06 2020)

Version: 1.1 Revision Date: 05/11/2023

Calcium carbonate - Respirable fraction. TWA 3 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (06 2020)
Calcium carbonate - Respirable particles. TWA 3 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (01 2020)
Calcium carbonate - Inhalable particles. TWA 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (01 2020)
Calcium carbonate - Inhalable fraction. TWA 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (01 2020)
Polyvinyl chloride - Respirable. TWA 1 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Polyvinyl chloride - Respirable fraction. TWA 1 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (11 2010)
Polyvinyl chloride - Total dust. TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
Calcium Carbonate (Limestone) - Total dust. STEL 20 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
TWA 10 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Calcium Carbonate (Limestone) - Respirable fraction.
TWA 3 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Calcium Carbonate (Limestone) - Total dust. TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
Xylene STEL 150 ppm Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
TWA 100 ppm Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Xylene STEL 150 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (11 2010)
TWA 100 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (11 2010)
Xylene TWA 100 ppm 434 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
STEL 150 ppm 651 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)

Version: 1.1 Revision Date: 05/11/2023

Calcium oxide TWA 2 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Calcium oxide TWA 2 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (12 2007)
Calcium oxide TWA 2 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
Titanium dioxide - Total dust. TWA 10 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Titanium dioxide - Respirable fraction. TWA 3 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Titanium dioxide TWA 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (11 2010)
Titanium dioxide - Total dust. TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
Diisodecyl phthalate TWA 5 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (11 2010)
Ethylbenzene TWA 20 ppm Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (09 2011)
Ethylbenzene TWA 20 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (06 2015)
Ethylbenzene TWA 20 ppm Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (03 2020)
Isophorone Diisocyanate TWA 0.005 ppm Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
CEILING 0.01 ppm Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Isophorone Diisocyanate TWA 0.005 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (06 2015)
CEV 0.02 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (06 2015)

Version: 1.1 Revision Date: 05/11/2023

Isophorone Diisocyanate TWA 0.005 ppm 0.045 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
Hydrotreated heavy naphthenic distillate - Mist. TWA 1 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (05 2013)
Hydrotreated heavy naphthenic distillate - Inhalable fraction.
TWA 5 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (06 2015)
Hydrotreated heavy naphthenic distillate - Inhalable dusts and mists.
TWA 5 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (04 2022)
Stearic acid - Respirable fraction. TWA 3 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (01 2020)
Stearic acid - Respirable. TWA 3 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (01 2021)
Stearic acid TWA 10 ppm Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (03 2020)
Dibutyl tin dilaurate - as Sn STEL 0.2 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
TWA 0.1 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Dibutyl tin dilaurate - as Sn TWA 0.1 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (11 2010)
Dibutyl tin dilaurate - as Sn STEL 0.2 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
TWA 0.1 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)

Version: 1.1 Revision Date: 05/11/2023

Aluminum oxide - Respirable fraction. TWA 1 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (11 2010)
Aluminum oxide - Inhalable fraction. TWA 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (06 2015)
Aluminum oxide - Respirable fraction. TWA 3 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (06 2015)
Aluminum oxide - Total dust. TWA 10 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (06 2020)
Aluminum oxide - Inhalable particles. TWA 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (01 2020)
Aluminum oxide - Respirable particles. TWA 3 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (01 2020)
Aluminum oxide - Respirable fraction. TWA 3 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (06 2020)
Aluminum oxide - Respirable. TWA 1.0 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (06 2022)
Aluminum oxide - Total dust. TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (04 2022)
Aluminum oxide - Respirable dust. TWA 5 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (04 2022)
Toluene TWA 20 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (11 2010)
Toluene TWA 20 ppm Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Toluene TWA 50 ppm 188 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
Stannous octoate - as Sn TWA 0.1 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2018)
STEL 0.2 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2018)
Stannous octoate - as Sn TWA 0.1 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (08 2017)
Stannous octoate - as Sn TWA 0.1 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
STEL 0.2 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)

Version: 1.1 Revision Date: 05/11/2023

Carbon Black - Inhalable TWA 3 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (09 2011)
Carbon Black - Inhalable fraction. TWA 3 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (06 2015)
Carbon Black - Inhalable dust. TWA 3 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (03 2020)
Amorphous silica - Respirable fraction. TWA 3 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (06 2020)
Amorphous silica - Inhalable fraction. TWA 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (01 2020)
Amorphous silica - Respirable particles. TWA 3 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (01 2020)
Amorphous silica - Total dust. TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (03 2020)
Amorphous silica - Respirable fraction. TWA 3 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (01 2020)
Amorphous silica - Total dust. TWA 10 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (06 2020)
Amorphous silica - Inhalable particles. TWA 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (01 2020)
Zirconium dioxide - as Zr TWA 5 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (11 2010)
STEL 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (11 2010)
Zirconium dioxide - as Zr TWA 5 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
STEL 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)

Version: 1.1 Revision Date: 05/11/2023

Zirconium dioxide - Respirable fraction. TWA 3 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (01 2020)
Zirconium dioxide - Total dust. TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (04 2019)
Zirconium dioxide - Inhalable fraction. TWA 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (01 2020)
Zirconium dioxide - Inhalable particles. TWA 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (01 2020)
Zirconium dioxide - Respirable fraction. TWA 3 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (06 2020)
Zirconium dioxide - Total dust. TWA 10 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (06 2020)
Zirconium dioxide - Respirable particles. TWA 3 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (01 2020)
Zirconium dioxide - as Zr TWA 5 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (06 2022)
STEL 10 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (06 2022)
Magnesium oxide - Respirable dust and/or fume. - as Mg
STEL 10 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Magnesium oxide - Inhalable fume. TWA 10 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Magnesium oxide - Respirable dust and/or fume. - as Mg
TWA 3 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Magnesium oxide - Inhalable fraction. TWA 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (11 2010)
Magnesium oxide - Inhalable dust. TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (03 2020)
Crystalline Silica (Quartz)/ Silica Sand - Respirable fraction.
TWA 0.10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (06 2015)
Crystalline Silica (Quartz)/ Silica Sand - Respirable dust. TWA 0.1 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
TWA 0.05 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (04 2022)

Version: 1.1 Revision Date: 05/11/2023

Calcium sulfate TWA 10 mg/m3 Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2), as amended (07 2009)
Calcium sulfate - Inhalable TWA 10 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Calcium sulfate - Inhalable fraction. TWA 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (11 2010)
Calcium sulfate - Total dust. TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (03 2020)
1,2,4-Trimethylbenzene TWA 25 ppm 123 mg/m3 Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2), as amended (07 2009)
1,2,4-Trimethylbenzene TWA 25 ppm Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
1,2,4-Trimethylbenzene TWA 25 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (11 2010)
1,2,4-Trimethylbenzene TWA 25 ppm Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (03 2020)
Iron oxide - Dust. - as Fe TWA 5 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Iron oxide - Fume. - as Fe STEL 10 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
TWA 5 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)

Version: 1.1 Revision Date: 05/11/2023

Iron oxide - Dust and fume. - as Fe TWA 5 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
Iron oxide - Respirable fraction. TWA 5 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (01 2020)
1,3,5-Trimethylbenzene TWA 25 ppm Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
1,3,5-Trimethylbenzene TWA 25 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (11 2010)
1,3,5-Trimethylbenzene TWA 25 ppm Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (03 2020)
2-Ethylhexanoic acid - Vapor and aerosol, inhalable. TWA 5 mg/m3 Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
2-Ethylhexanoic acid - Inhalable fraction and vapor. TWA 5 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (11 2010)
Methanol TWA 200 ppm Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Methanol TWA 200 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (11 2010)
STEL 250 ppm Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
STEL 250 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (11 2010)
Methanol STEL 250 ppm 328 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
TWA 200 ppm 262 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
Phenol TWA 5 ppm Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Phenol TWA 5 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (11 2010)
Phenol TWA 5 ppm 19 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
Cumene STEL 75 ppm Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
TWA 25 ppm Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)

Version: 1.1 Revision Date: 05/11/2023

Cumene TWA 50 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (11 2010)
Cumene TWA 50 ppm 246 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
Benzene STEL 2.5 ppm Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
TWA 0.5 ppm Canada. British Columbia OELs: Table of Exposure Limits for Chemical Biological Substances (Workers Compensation Board); as amended (07 2007)
Benzene TWA 0.5 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (06 2015)
STEL 2.5 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents), as amended (06 2015)
Benzene TWA 1 ppm 3 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)
STEL 5 ppm 15.5 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation respecting occupational health and safety), as amended (09 2017)

Biological Limit Values
Chemical Identity
Xylene (Methylhippuric acids: Sampling time: End of shift.) 1.5 g/g (Creatinine in urine) ACGIH BEI (03 2013)
Ethylbenzene (Sum of mandelic acid and phenylglyoxylic acid: Sampling time: End of shift.)
0.15 g/g (Creatinine in urine) ACGIH BEI (02 2014)

Mechanical ventilation or local exhaust ventilation may be required. Observe good industrial hygiene practices. Observe occupational exposure limits and minimize the risk of inhalation of dust.
Individual protection measures, such as personal protective equipment

Eye/face protection:

Skin Protection
Additional Information: Use suitable protective gloves if risk of skin contact.

Skin and Body Protection:

Version: 1.1 Revision Date: 05/11/2023

Respiratory Protection:

Hygiene measures:

9. Physical and chemical properties

Appearance
solid
Paste
Gray
Mild, Mild , Mild
No data available.
No data available.
No data available.
No data available.
No data available.
Slower than n-Butyl Acetate Slower than n-Butyl Acetate Slower than n-Butyl Acetate
No No No

No data available.
No data available.
No data available.
No data available.
No data available.
Vapors are heavier than air and may travel along the floor and in the bottom of containers. Vapors are heavier than air and
may travel along the floor and in the bottom of containers. Vapors are heavier than air and may travel along the floor and
in the bottom of containers.
1.3297
Insoluble in water Insoluble in water
Insoluble in water
No data available.
No data available.

Version: 1.1 Revision Date: 05/11/2023

Auto-ignition temperature:
Decomposition temperature:
Viscosity:
10. Stability and reactivity

No data available.

Material is stable under normal conditions.

No data available.
Avoid heat or contamination.
Alcohols. Amines. Strong acids. Avoid contact with oxidizing agents (e.g. nitric acid, peroxides and chromates). Strong bases. Water, moisture. Alcohols. Amines. Strong acids. Avoid contact with oxidizing agents (e.g.
nitric acid, peroxides and chromates). Strong bases. Water, moisture. Alcohols. Amines. Strong acids. Avoid contact with oxidizing agents (e.g.
nitric acid, peroxides and chromates). Strong bases. Water, moisture.

Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapors.

11. Toxicological information

Information on likely routes of exposure
In high concentrations, vapors, fumes or mists may irritate nose, throat and mucus membranes.
May be harmful in contact with skin. May cause an allergic skin reaction.
Causes serious eye damage.
Ingestion:

Symptoms related to the physical, chemical and toxicological characteristics
No data available.
No data available.
No data available.
Ingestion:

Information on toxicological effects

Acute toxicity (list all possible routes of exposure)

Oral
ATEmix: 4,495.23 mg/kg

Dermal

Version: 1.1 Revision Date: 05/11/2023

Product:

Inhalation ATEmix: 15.93 mg/l ATEmix : 1.21 mg/l

Repeated dose toxicity No data available.

Skin Corrosion/Irritation No data available.

Specified substance(s):
Calcium carbonate in vivo (Rabbit): Not irritant , 24 - 72 h

Xylene in vivo (Rat): Slightly irritating , 24 h

Trade Secret In vitro (In vitro): Not irritant , 0.25 - 42.25 h

Titanium dioxide in vivo (Rabbit): Not irritant , 24 h

Hydrotreated heavy naphthenic distillate in vivo (Rabbit): Category 2 , 24 - 72 h

Stearic acid in vivo (Rabbit): Not irritant , 24 h

Dibutyl tin dilaurate In vitro (Human, in vitro reconstituted epidermis model): Not irritant , 15 min

Serious Eye Damage/Eye Irritation No data available.
Specified substance(s):
Calcium carbonate Rabbit, 24 - 72 h: Not irritant
Xylene Rabbit, 72 h: Moderately irritating Rabbit, 1 h: Not irritant

Trade Secret Rabbit, 24 - 72 h: Category II
Titanium dioxide Rabbit, 24 - 72 h: Not irritant
Hydrotreated heavy
naphthenic distillate
Rabbit, 24 h: Not irritant
Stearic acid Rabbit, 27 - 72 h: Not irritant

Dibutyl tin dilaurate Rabbit, 24 h: Highly irritating

Respiratory or Skin Sensitization

Version: 1.1 Revision Date: 05/11/2023

Product:

Carcinogenicity Suspected of causing cancer.

IARC Monographs on the Evaluation of Carcinogenic Risks to Humans:

Ethylbenzene Overall evaluation: Possibly carcinogenic to humans.

US. National Toxicology Program (NTP) Report on Carcinogens: No carcinogenic components identified

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050), as amended:
Polyvinyl chloride Cancer

Germ Cell Mutagenicity

In vitro
No data available.

In vivo
No data available.

Reproductive toxicity May damage fertility or the unborn child.
Specific Target Organ Toxicity - Single Exposure No data available.
Specific Target Organ Toxicity - Repeated Exposure No data available.

Aspiration Hazard
No data available.

Version: 1.1 Revision Date: 05/11/2023

Other effects:

12. Ecological information

Ecotoxicity:

Acute hazards to the aquatic environment:

Fish No data available.

Specified substance(s):
Xylene LC 50 (Fathead minnow (Pimephales promelas), 96 h): 13.41 mg/l Mortality

Aquatic Invertebrates
No data available.
Specified substance(s):
Trade Secret EC 50 (Daphnia magna, 48 h): > 87.1 mg/l experimental result Experimental
result, Key study

Version: 1.1 Revision Date: 05/11/2023

Chronic hazards to the aquatic environment:

Fish No data available.

Specified substance(s): Hydrotreated heavy naphthenic distillate NOAEL (Oncorhynchus mykiss): >= 1,000 mg/l QSAR QSAR, Supporting study

Aquatic Invertebrates
No data available.

Specified substance(s): Titanium dioxide NOAEL (Daphnia magna): 100 mg/l experimental result Experimental result,
Supporting study

Toxicity to Aquatic Plants
No data available.

Persistence and Degradability

Biodegradation
No data available.

Specified substance(s):
Trade Secret 33 % (28 d) Detected in water. Experimental result, Key study

Version: 1.1 Revision Date: 05/11/2023

BOD/COD Ratio
Product:

Bioaccumulative potential
Bioconcentration Factor (BCF) No data available.

Specified substance(s): Xylene Oncorhynchus mykiss, Bioconcentration Factor (BCF): > 8.1 - < 25.9 Aquatic sediment Experimental result, Key study

Partition Coefficient n-octanol / water (log Kow) No data available.

Specified substance(s):
Xylene Log Kow: 2.77 - 3.15 No Not specified, Not specified

No data available.

Harmful to aquatic life with long lasting effects.
13. Disposal considerations

Dispose of waste at an appropriate treatment and disposal facility in
accordance with applicable laws and regulations, and product characteristics at time of disposal.
No data available.

14. Transport information

TDG:

Version: 1.1 Revision Date: 05/11/2023

Not Regulated
CFR / DOT: Not Regulated

IMDG: Not Regulated

Further Information: The above shipping description may not be accurate for all container sizes and all modes of transportation. Please refer to Bill of Lading.

15. Regulatory information

US Federal Regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) None present or none present in regulated quantities.

US. Toxic Substances Control Act (TSCA) Section 5(a)(2) Final Significant New Use Rules (SNURs)
(40 CFR 721, Subpt E) None present or none present in regulated quantities.

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050), as amended
Polyvinyl chloride Blood Liver Cancer Flammability Central nervous system
CERCLA Hazardous Substance List (40 CFR 302.4):
Xylene 100 lbs. Ethylbenzene 1000 lbs. Toluene 1000 lbs.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories Immediate (Acute) Health Hazards Delayed (Chronic) Health Hazard
Acute toxicity (any route or exposure) Respiratory or Skin Sensitization Carcinogenicity Reproductive toxicity

Version: 1.1 Revision Date: 05/11/2023

US. EPCRA (SARA Title III) Section 304 Extremely Hazardous Substances Reporting Quantities and
the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Hazardous
Substances Not regulated.
US. EPCRA (SARA Title III Section 313 Toxic Chemical Release Inventory (TRI) Reporting

Xylene 1.0% Ethylbenzene 0.1%
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
None present or none present in regulated quantities.
Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3)
Chemical Identity Reportable quantity Xylene Reportable quantity: 100 lbs.
US State Regulations
US. California Proposition 65

Cancer and Reproductive Harm - www.P65Warnings.ca.gov

International regulations
Montreal protocol
Not applicable
Stockholm convention
Not applicable
Rotterdam convention
Not applicable
Kyoto protocol Not applicable

VOC: Regulatory VOC (less water and exempt solvent) : 45 g/l
VOC Method 310 : 3.37 %

Version: 1.1 Revision Date: 05/11/2023

Inventory Status:
Canada DSL Inventory List: All components in this product are listed on or exempt from the Inventory.

Version: 1.1 Revision Date: 05/11/2023

16.Other information, including date of preparation or last revision

Revision Date:
Version #:
Further Information:
Disclaimer:

SAFETY DATA SHEET
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SDS Number:
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SECTION 1. IDENTIFICATION
Product name : MasterSeal NP 2 lst Product code : 000000000050304696 000000000050304696
Manufacturer or supplier's details
Company name of supplier : Master Builders-Construction Systems US, LLC Address : 23700 CHAGRIN BLVD Beachwood OH 44122 Emergency telephone : ChemTel: [phone] USA: [phone] Contract Number MIS9240420
Recommended use of the chemical and restrictions on use
Recommended use : Product for construction chemicals Restrictions on use : Reserved for industrial and professional use.
SECTION 2. HAZARDS IDENTIFICATION
GHS classification in accordance with 29 CFR 1910.1200
Specific target organ toxicity
- repeated exposure
: Category 1 (Central nervous system)
Carcinogenicity (Inhalation) : Category 1A
GHS label elements
Hazard pictograms

:

Signal Word : Danger
Hazard Statements : H350 May cause cancer. H372 Causes damage to organs (Central nervous system)
through prolonged or repeated exposure. Precautionary Statements : Prevention:
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection. P201 Obtain special instructions before use.
P260 Do not breathe dust or mist. P202 Do not handle until all safety precautions have been read and understood. P270 Do not eat, drink or smoke when using this product.
P264 Wash face, hands and any exposed skin thoroughly after handling.
Response:
P314 Get medical advice/ attention if you feel unwell.
P308 + P311 IF exposed or concerned: Call a POISON CENTER/ doctor.
SAFETY DATA SHEET
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Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/container to appropriate hazardous
waste collection point.
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature : No applicable information available.
Components
Chemical name CAS-No. Concentration (% w/w)
calcium carbonate 471-34-1 >= 7 - < 20
Stoddard solvent 8052-41-3 >= 7 - < 10
Titanium dioxide 13463-67-7 >= 3 - < 5
calcium oxide 1305-78-8 >= 0.3 - < 1
trimethoxy(3-(oxiranylmethoxy)propyl)silane 2530-83-8 >= 0.3 - < 1
Limestone 1317-65-3 >= 10 - < 20
Quartz (SiO2) 14808-60-7 >= 0 - < 0.3
stearic acid 57-11-4 >= 0.3 - < 3

SECTION 4. FIRST AID MEASURES
General advice : Move out of dangerous area. Show this material safety data sheet to the doctor in attend-
ance. Do not leave the victim unattended.
If inhaled : Remove the affected individual into fresh air and keep the
person calm. Assist in breathing if necessary.
Immediate medical attention required. In case of skin contact : Wash affected areas thoroughly with soap and water.
Consult a doctor if skin irritation persists. In case of eye contact : In case of contact with the eyes, rinse immediately for at least
15 minutes with plenty of water. Immediate medical attention required. If swallowed : Rinse mouth and then drink 200-300 ml of water. Do NOT induce vomiting.
Immediate medical attention required. Most important symptoms
and effects, both acute and delayed
: May cause cancer.
Causes damage to organs through prolonged or repeated exposure. Notes to physician : Treat symptomatically.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : Water spray
SAFETY DATA SHEET
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Foam Carbon dioxide (CO2) Specific hazards during fire fighting
: See SDS section 10 - Stability and reactivity.
Hazardous combustion prod-ucts
: harmful vapours nitrogen oxides fumes/smoke carbon black
carbon oxides
Further information : Sealed containers should be protected against heat as this results in pressure build-up. Special protective equipment for fire-fighters
: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protec-tive equipment and emer-
gency procedures
: Clear area. Ensure adequate ventilation.
Wear suitable personal protective clothing and equipment.
Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and materials for
containment and cleaning up
: Ensure adequate ventilation.
Avoid sources of ignition.
SECTION 7. HANDLING AND STORAGE
Advice on protection against fire and explosion

: Product is not explosive.

Normal measures for preventive fire protection.
Advice on safe handling : Avoid contact with the skin, eyes and clothing.
Avoid excessive temperatures. Avoid humidity. Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place.
Observe label precautions. Electrical installations / working materials must comply with
the technological safety standards. Further information on stor-
age conditions
: Keep only in the original container in a cool, dry, well-
ventilated place away from ignition sources, heat or flame. Protect from direct sunlight.
Materials to avoid : Observe TRGS 509/510 storage rules.
Further information on stor-
age stability
: No decomposition if stored and applied as directed.
SAFETY DATA SHEET
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SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Components CAS-No. Value type (Form of exposure)
Control parame-ters / Permissible concentration
Basis
stearic acid 57-11-4 TWA value
(Inhalable fraction)
10 mg/m3 ACGIHTLV
TWA value (Respirable fraction)
3 mg/m3 ACGIHTLV
TWA (Inhal-able particu-
late matter)
10 mg/m3 ACGIH
TWA (Res-pirable par-ticulate mat-ter)
3 mg/m3 ACGIH
calcium carbonate 471-34-1 REL value (Total) 10 mg/m3 NIOSH
REL value (Respirable) 5 mg/m3 NIOSH
PEL (Respir-
able fraction)
5 mg/m3 29 CFR
1910.1000 (Table Z-1) PEL (Total dust) 15 mg/m3 29 CFR 1910.1000 (Table Z-1) TWA (Res-pirable) 5 mg/m3 (Calcium car-
bonate)
NIOSH REL
TWA (total) 10 mg/m3 (Calcium car-bonate)
NIOSH REL
calcium oxide 1305-78-8 TWA value 2 mg/m3 ACGIHTLV REL value 2 mg/m3 NIOSH PEL 5 mg/m3 29 CFR 1910.1000
(Table Z-1) TWA value 5 mg/m3 29 CFR 1910.1000 (Table Z-1-A) TWA 2 mg/m3 ACGIH TWA 2 mg/m3 NIOSH REL TWA 5 mg/m3 OSHA Z-1 TWA 5 mg/m3 OSHA P0
Limestone 1317-65-3 REL value
(Respirable)
5 mg/m3 NIOSH
REL value (Total) 10 mg/m3 NIOSH
PEL (Respir-able fraction) 5 mg/m3 29 CFR 1910.1000
SAFETY DATA SHEET
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(Table Z-1) PEL (Total dust) 15 mg/m3 29 CFR 1910.1000 (Table Z-1) TWA value
(Respirable fraction)
5 mg/m3 29 CFR
1910.1000 (Table Z-1-A) TWA value (Total dust) 15 mg/m3 29 CFR 1910.1000 (Table Z-1-A) TWA (total dust) 15 mg/m3 OSHA Z-1
TWA (respir-able fraction) 5 mg/m3 OSHA Z-1
TWA (Total
dust)
15 mg/m3 OSHA P0
TWA (respir-able dust fraction)
5 mg/m3 OSHA P0
TWA (Res-
pirable)
5 mg/m3
(Calcium car-bonate)
NIOSH REL
TWA (total) 10 mg/m3 (Calcium car-bonate)
NIOSH REL
Titanium dioxide 13463-67-7 TWA value 10 mg/m3 ACGIHTLV PEL (Total dust) 15 mg/m3 29 CFR 1910.1000 (Table Z-1) TWA value
(Total dust)
10 mg/m3 29 CFR
1910.1000 (Table Z-1-A) TWA (total dust) 15 mg/m3 OSHA Z-1
TWA (Total
dust)
10 mg/m3 OSHA P0
TWA 10 mg/m3 (Titanium dioxide) ACGIH
Quartz (SiO2) 14808-60-7 TWA value (Respirable
fraction)
0.025 mg/m3 ACGIHTLV
TWA value 0.05 mg/m3 (Respirable dust) 29 CFR 1910.1001-1050 OSHA Action
level
0.025 mg/m3
(Respirable dust)
29 CFR
1910.1001-1050 REL value (Respirable dust)
0.05 mg/m3 NIOSH
TWA (Res-pirable dust) 0.05 mg/m3 OSHA Z-1
TWA (respir-able) 10 mg/m3 / %SiO2+2 OSHA Z-3
SAFETY DATA SHEET
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TWA (respir-able) 250 mppcf / %SiO2+5 OSHA Z-3
TWA (respir-able dust fraction)
0.1 mg/m3 OSHA P0
TWA (Res-pirable par-
ticulate mat-ter)
0.025 mg/m3 (Silica) ACGIH
PEL (respir-able) 0.05 mg/m3 OSHA CARC
TWA (Res-
pirable dust)
0.05 mg/m3
(Silica)
NIOSH REL
Stoddard solvent 8052-41-3 TWA value 100 ppm ACGIHTLV REL value 350 mg/m3 NIOSH Ceil_Time 1,800 mg/m3 NIOSH PEL 500 ppm 2,900 mg/m3 29 CFR 1910.1000
(Table Z-1) TWA value 100 ppm 525 mg/m3 29 CFR 1910.1000 (Table Z-1-A) TWA 100 ppm ACGIH TWA 350 mg/m3 NIOSH REL C 1,800 mg/m3 NIOSH REL TWA 500 ppm 2,900 mg/m3 OSHA Z-1
TWA 100 ppm 525 mg/m3 OSHA P0
Engineering measures : Provide local exhaust ventilation to control vapours/mists.
Personal protective equipment
Respiratory protection : When workers are facing concentrations above the occupa-tional exposure limits they must use appropriate certified respirators. Hand protection Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection : Safety glasses with side-shields. Wear face shield if splashing hazard exists. Skin and body protection : Body protection must be chosen based on level of activity and exposure. Protective measures : Do not inhale gases/vapours/aerosols. Avoid contact with the skin, eyes and clothing. Avoid exposure - obtain special instructions before use. Handle in accordance with good building materials hygiene and safety practice. Wearing of closed work clothing is recommended. Hygiene measures : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
SAFETY DATA SHEET
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Appearance : liquid Color : milky white Odor : like acrylic pH : No data available
Melting point : No applicable information available.
Boiling point : 469.00 °F / 242.78 °C No data available
Flash point : 240.01 °F / 115.56 °C

Evaporation rate : No applicable information available.
Flammability (solid, gas) : not determined
Upper explosion limit / Upper flammability limit

: 9.4 %(V)
Lower explosion limit / Lower
flammability limit
: 0.7 %(V)

Vapor pressure : No applicable information available.
Relative vapor density : Heavier than air.
Relative density : No applicable information available.
Density : 1.0312 g/cm3 (68 °F / 20 °C)
Solubility(ies) Water solubility : partly soluble
Solubility in other solvents : No applicable information available.
Partition coefficient: n-
octanol/water
: No data available.
Autoignition temperature : No data available
Decomposition temperature : No applicable information available.
Viscosity
Viscosity, dynamic : No applicable information available.
Viscosity, kinematic : No applicable information available.
Explosive properties : Not explosive Not explosive

Oxidizing properties : not fire-propagating
SAFETY DATA SHEET
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Sublimation point : No applicable information available.
Molecular weight : No data available

SECTION 10. STABILITY AND REACTIVITY
Reactivity : No applicable information available. No decomposition if stored and applied as directed. Chemical stability : No applicable information available. No decomposition if stored and applied as directed. Possibility of hazardous reac-
tions
: The product is chemically stable.
Conditions to avoid : Avoid moisture.
Avoid prolonged exposure to extreme heat. Avoid sources of ignition. Incompatible materials : Water Alcohols
Strong bases Oxidizing agents
Substances/products that react with isocyanates. Hazardous decomposition
products
: carbon oxides
nitrogen oxides
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Not classified based on available information.
Product:
Acute oral toxicity : Remarks: No applicable information available.
Acute inhalation toxicity : Remarks: No applicable information available.
Acute dermal toxicity : Remarks: No applicable information available.
Skin corrosion/irritation
Not classified based on available information.
Serious eye damage/eye irritation
Not classified based on available information.
Respiratory or skin sensitization
Skin sensitization
Not classified based on available information.
Respiratory sensitization
Not classified based on available information.
Germ cell mutagenicity
Not classified based on available information.
SAFETY DATA SHEET
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Carcinogenicity
May cause cancer.
Reproductive toxicity
Not classified based on available information.
STOT-single exposure
Not classified based on available information.
STOT-repeated exposure
Causes damage to organs (Central nervous system) through prolonged or repeated exposure.
Aspiration toxicity
Not classified based on available information.
Product:
No aspiration hazard expected.

Components:
stearic acid:
Not applicable

Further information
Product:
Remarks : No data available

SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
No data available
Persistence and degradability
Components:
Quartz (SiO2):
Biodegradability : Remarks: Not applicable
Bioaccumulative potential
Components:
Stoddard solvent:
Partition coefficient: n-
octanol/water
: log Pow: 3.5 - 6.4 (68 °F / 20 °C)
Method: Partition coefficient (n-octanol/water), HPLC method.
stearic acid:
Partition coefficient: n-
octanol/water
: Remarks: No data available.
log Pow: 8.23
Method: other (measured)
SAFETY DATA SHEET
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Mobility in soil
No data available
Other adverse effects
Product:
Additional ecological infor-
mation
: There is a high probability that the product is not acutely
harmful to aquatic organisms. The product has not been tested. The statements on ecotoxi-
cology have been derived from the properties of the individual components.

SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Do not contaminate ponds, waterways or ditches with chemi-cal or used container.
Do not discharge into drains/surface waters/groundwater. Dispose of in accordance with national, state and local regula-
tions. Contaminated packaging : Contaminated packaging should be emptied as far as possible
and disposed of in the same manner as the sub-stance/product.
SECTION 14. TRANSPORT INFORMATION
International Regulations
UNRTDG Not regulated as a dangerous good
IATA-DGR Not regulated as a dangerous good
IMDG-Code Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
49 CFR Not regulated as a dangerous good
SECTION 15. REGULATORY INFORMATION
US State Regulations
Pennsylvania Right To Know
calcium carbonate 471-34-1 Limestone 1317-65-3
Titanium dioxide 13463-67-7
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Stoddard solvent 8052-41-3 Carbon black 1333-86-4
New Jersey Right To Know
Limestone 1317-65-3
Titanium dioxide 13463-67-7 Stoddard solvent 8052-41-3
Quartz (SiO2) 14808-60-7
California Prop. 65
WARNING: This product can expose you to chemicals including lead, Titanium dioxide, Quartz (SiO2), Carbon black, 1,1-dichloroethylene, acrylonitrile, toluene, which is/are known to the State
of California to cause cancer and birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov.
The ingredients of this product are reported in the following inventories:
TSCA

: All chemical substances in this product are either listed as
active on the TSCA Inventory or are in compliance with a TSCA Inventory exemption.
SECTION 16. OTHER INFORMATION
Further information
NFPA 704: HMIS® IV:

HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal haz-ards or risks, and 4 representing signifi-cant hazards or risks. The "*" represents a chronic hazard, while the "/" represents the absence of a chronic hazard.

Full text of other abbreviations
29 CFR 1910.1000 (Table Z-1-A) : OSHA - Table Z-1-A (29 CFR 1910.1000)
29 CFR 1910.1000 (Table Z-1) : OSHA - Table Z-1 (Limits for Air Contaminants) 29 CFR 1910.1000 29 CFR 1910.1001-1050 : OSHA - Specifically Regulated Substances (29 CFR 1910.1001-1050) ACGIH : USA. ACGIH Threshold Limit Values (TLV) ACGIHTLV : American Conference of Governmental Industrial Hygienists - threshold limit values (US)
HEALTH
2
1

0

Flammability
Instability
Special hazard
FLAMMABILITY PHYSICAL HAZARD

Health
SAFETY DATA SHEET
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NIOSH : NIOSH Pocket Guide to Chemical Hazards (US) NIOSH REL : USA. NIOSH Recommended Exposure Limits
OSHA CARC : OSHA Specifically Regulated Chemicals/Carcinogens OSHA P0 : USA. OSHA - TABLE Z-1 Limits for Air Contaminants -
1910.1000 OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim-its for Air Contaminants OSHA Z-3 : USA. Occupational Exposure Limits (OSHA) - Table Z-3 Min-
eral Dusts 29 CFR 1910.1000 (Table Z-
1-A) / TWA value
: Time Weighted Average (TWA):
29 CFR 1910.1000 (Table Z-
1) / PEL
: Permissible exposure limit
29 CFR 1910.1001-1050 /
OSHA Action level
: OSHA Action level:
29 CFR 1910.1001-1050 /
TWA value
: Time Weighted Average (TWA):
ACGIH / TWA : 8-hour, time-weighted average
ACGIHTLV / TWA value : Time Weighted Average (TWA): NIOSH / Ceil_Time : Ceiling Limit Value and Time Period (if specified):
NIOSH / REL value : Recommended exposure limit (REL): NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour
workday during a 40-hour workweek NIOSH REL / C : Ceiling value not be exceeded at any time.
OSHA CARC / PEL : Permissible exposure limit (PEL) OSHA P0 / TWA : 8-hour time weighted average
OSHA Z-1 / TWA : 8-hour time weighted average OSHA Z-3 / TWA : 8-hour time weighted average
AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensa-tion, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of
the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely
Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration asso-
ciated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Har-monized System; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification
System; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dan-
gerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - In-
ternational Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Indus-trial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI -
Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International
Convention for the Prevention of Pollution from Ships; MSHA - Mine Safety and Health Admin-istration; n.o.s. - Not Otherwise Specified; NFPA - National Fire Protection Association; NO(A)EC
- No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New
Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop-ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu-
lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc-es; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA - Resource Conservation and
Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the
SAFETY DATA SHEET
MasterSeal NP 2 lst

Version
1.0
Revision Date:
01/05/2021
SDS Number:
000000534118
Date of last issue: -
Date of first issue: 01/05/2021

13 / 13
Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund
Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Sub-stance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations;
UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative
Revision Date : 01/05/2021

We support worldwide Responsible Care® initiatives. We value the health and safety of our em-ployees, customers, suppliers and neighbors, and the protection of the environment. Our com-
mitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensur-
ing the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and dis-
posal of our products.
IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE
, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO
DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING
WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET
FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE
SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU
EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY OUR COMPANY HEREUNDER ARE GIVEN GRATIS AND WE
ASSUME NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED
AT YOUR RISK.
US / EN

Multi-Purpose Interior/Exterior Latex Primer
White
Not available.
Liquid.
[phone]
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :THE SHERWIN-WILLIAMS COMPANY
101 Prospect Avenue N.W.
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
B51W450
B51W450Product code :
Product Information
Telephone Number
:Not available.
Regulatory Information
Telephone Number
:[phone]
Transportation Emergency
Telephone Number
:[phone]
Section 2. Hazards identification
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
Classification of the
substance or mixture
:
Signal word :Warning
Hazard pictograms :
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Use personal protective equipment as required. Wear
protective gloves. Avoid breathing vapor. Contaminated work clothing should not be
allowed out of the workplace.
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 32.8%
General :Read label before use. Keep out of reach of children. If medical advice is needed, have
product container or label at hand.
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
May cause an allergic skin reaction.
Suspected of causing cancer.
:Hazard statements
Date of issue/Date of revision :5/20/2015.Date of previous issue :4/23/2015.Version :1.04 1/10
Section 2. Hazards identification
Response :IF exposed or concerned: Get medical attention. IF ON SKIN: Wash with plenty of
soap and water. Wash contaminated clothing before reuse. If skin irritation or rash
occurs: Get medical attention.
Storage :Store locked up.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Please refer to the SDS for additional information. Do not transfer contents to other
containers for storage.
Supplemental label
elements
WARNING: This product contains chemicals known to the State of California to cause
cancer and birth defects or other reproductive harm.
Section 3. Composition/information on ingredients
Titanium Dioxide 14.5 13463-67-7
Epichlorohydrin-mercaptoethanol Alcohol 0.3 928768-73-4
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place
in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Date of issue/Date of revision :5/20/2015.Date of previous issue :4/23/2015.Version :1.04 2/10
Section 4. First aid measures
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :May cause an allergic skin reaction.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :No specific data.
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
metal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For non-emergency
personnel
Date of issue/Date of revision :5/20/2015.Date of previous issue :4/23/2015.Version :1.04 3/10
Section 6. Accidental release measures
Environmental precautions
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
:Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For emergency responders :If specialised clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure - obtain special instructions before use. Do not
handle until all safety precautions have been read and understood. Do not get in eyes
or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. If during normal
use the material presents a respiratory hazard, use only with adequate ventilation or
wear appropriate respirator. Keep in the original container or an approved alternative
made from a compatible material, kept tightly closed when not in use. Empty containers
retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Titanium Dioxide ACGIH TLV (United States, 4/2014).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 2/2013).
TWA: 15 mg/m³ 8 hours. Form: Total dust
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
Date of issue/Date of revision :5/20/2015.Date of previous issue :4/23/2015.Version :1.04 4/10
Section 8. Exposure controls/personal protection
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Liquid.
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate 0.09 (butyl acetate = 1)
Flash point Closed cup: >93.3°C (>199.9°F)
8.8
Not available.Odor threshold
:
:
:
:
:
:
:
:
Appearance
Boiling point :100°C (212°F)
Flammability (solid, gas):Not available.
Date of issue/Date of revision :5/20/2015.Date of previous issue :4/23/2015.Version :1.04 5/10
Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
Solubility
1.31
1 [Air = 1]
0.31 kPa (2.333 mm Hg) [at 20°C]
Not available.
Auto-ignition temperature Not available.
Not available.
Viscosity Kinematic (room temperature): >0.205 cm2/s (>20.5 cSt)
Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
Heat of combustion :0.00000067 kJ/g
Aerosol product
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Not available.
Carcinogenicity
Not available.
Mutagenicity
Not available.
Irritation/Corrosion
Titanium Dioxide Skin - Mild irritant Human -72 hours 300
Micrograms
Intermittent
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
Classification
Date of issue/Date of revision :5/20/2015.Date of previous issue :4/23/2015.Version :1.04 6/10
Section 11. Toxicological information
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Not available.
Aspiration hazard
Not available.
Titanium Dioxide -2B -
Product/ingredient name NTPIARCOSHA
Not available.
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :May cause an allergic skin reaction.
No known significant effects or critical hazards.:Eye contact
Once sensitized, a severe allergic reaction may occur when subsequently exposed to
very low levels.
General :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :No specific data.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects :Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects :Not available.
Date of issue/Date of revision :5/20/2015.Date of previous issue :4/23/2015.Version :1.04 7/10
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
Titanium Dioxide -352 low
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
:Disposal methods
Section 14. Transport information
Date of issue/Date of revision :5/20/2015.Date of previous issue :4/23/2015.Version :1.04 8/10
Section 14. Transport information
-
-
-
-
-
-
Not regulated.Not regulated.
Special
provisions
Not Applicable
Emergency
schedules (EmS)
Not Applicable
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL
73/78 and the IBC Code
No.No.
:Not available.
:
TDG
Classification
Not regulated.
-
-
-
No.
Special
provisions
Not Applicable
Mexico
Classification
Not regulated.
-
-
-
No.
Special
provisions
Not Applicable
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
IATA
Not regulated.
-
-
-
No.
Special
provisions
Not Applicable
Section 15. Regulatory information
U.S. Federal regulations :
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
State regulations
Section 16. Other information
Hazardous Material Information System (U.S.A.)
1
0
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller [phone].
The customer is responsible for determining the PPE code for this material.
Date of issue/Date of revision :5/20/2015.Date of previous issue :4/23/2015.Version :1.04 9/10
Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Regulatory requirements are subject to change and may differ between various
locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all
country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of
the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use
of this product. The customer/buyer/user should not use the product for any purpose other than the purpose
shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling
instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the
manufacturer cannot be responsible for SDSs obtained from any other source.
Notice to reader
Date of issue/Date of revision :5/20/2015.Date of previous issue :4/23/2015.Version :1.04 10/10
Product ID:
Product Name:
Revision Date:
Version:
Manufacturer's Name:
Address:
Cure & Seal WB
Concrete Sealer
SECTION 1) IDENTIFICATION
Aug 05, 2021 Date Printed:
1.0 Supersedes Date:
BLUESTONE PRODUCTS, a TCC Materials Company
2025 CENTRE POINTE BLVD, MENDOTA HEIGHTS, MN, US, 55120
Emergency Phone: [phone]
Information Phone Number:651-688-9116
Fax:
Product/Recommended Uses:
Aug 05, 2021
N.A.
SECTION 2) HAZARDS IDENTIFICATION
Classification
Flammable Liquids -Category 4
Skin Irritation -Category 3
Pictograms
None
Signal Word
Warning
Hazardous Statements -Health
H316 -Causes mild skin irritation
Hazardous Statements -Physical
H227 -Combustible Liquid
Precautionary Statements -General
P101 -If medical advice is needed, have product container or label at hand.
P102 -Keep out of reach of children.
P103 -Read label before use.
Precautionary Statements -Prevention
P210 -Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P280 -Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary Statements -Response
P370 + P378 -In case of fire: Use carbon-di oxide, alcohol foam, water spray or dry chemical to extinguish.
P332 + P313 -If skin irritation occurs: Get medical advice/attention.
Precautionary Statements -Storage
P403 -Store in a well-ventilated place.
Cure & Seal WB www.tccmaterials.com Page 1 of 7
SAFETY DATA SHEET
Cure & Seal WB
PROMAR® 200 Zero VOC Interior Latex Semi-Gloss
Extra White
Not available.
Liquid.
[phone]
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :Manufactured by:
THE SHERWIN-WILLIAMS COMPANY
101 Prospect Avenue N.W.
Cleveland, OH 44115
Distributed by:
SHERWIN-WILLIAMS CANADA INC.
170 Brunel Rd
Mississauga, ON L4Z 1T5
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
B31W2651
B31W2651Product code :
Product Information
Telephone Number
:Not available.
Regulatory Information
Telephone Number
:[phone]
Transportation Emergency
Telephone Number
:[phone]
Section 2. Hazards identification
CARCINOGENICITY - Category 2Classification of the
substance or mixture
:
Signal word :Warning
Hazard pictograms :
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Use personal protective equipment as required.
Response :IF exposed or concerned: Get medical attention.
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 42.1%
General :Read label before use. Keep out of reach of children. If medical advice is needed, have
product container or label at hand.
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Suspected of causing cancer.:Hazard statements
Date of issue/Date of revision :5/23/2015.Date of previous issue :4/7/2015.Version :1.01 1/10
Section 2. Hazards identification
Storage :Store locked up.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Please refer to the SDS for additional information. Do not transfer contents to other
containers for storage.
Supplemental label
elements
WARNING: This product contains chemicals known to the State of California to cause
cancer and birth defects or other reproductive harm.
Section 3. Composition/information on ingredients
Titanium Dioxide 13.1 13463-67-7
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place
in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Potential acute health effects
Date of issue/Date of revision :5/23/2015.Date of previous issue :4/7/2015.Version :1.01 2/10
Section 4. First aid measures
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
No known significant effects or critical hazards.:Ingestion
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
For non-emergency
personnel
For emergency responders :If specialised clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Date of issue/Date of revision :5/23/2015.Date of previous issue :4/7/2015.Version :1.01 3/10
Section 6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not ingest.
Avoid breathing vapor or mist. If during normal use the material presents a respiratory
hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Empty containers retain product residue and can be
hazardous. Do not reuse container.
:
Precautions for safe handling
Titanium Dioxide ACGIH TLV (United States, 4/2014).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 2/2013).
TWA: 15 mg/m³ 8 hours. Form: Total dust
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Control parameters
Individual protection measures
Occupational exposure limits
Date of issue/Date of revision :5/23/2015.Date of previous issue :4/7/2015.Version :1.01 4/10
Section 8. Exposure controls/personal protection
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.23
1 [Air = 1]
0.31 kPa (2.333 mm Hg) [at 20°C]
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate 0.09 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: >93.3°C (>199.9°F)
Not available.
9.1
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :100°C (212°F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
Date of issue/Date of revision :5/23/2015.Date of previous issue :4/7/2015.Version :1.01 5/10
Section 9. Physical and chemical properties
Viscosity Kinematic (room temperature): >0.205 cm2/s (>20.5 cSt)
Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
:
Heat of combustion :0.000001071 kJ/g
Aerosol product
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Not available.
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Titanium Dioxide Skin - Mild irritant Human -72 hours 300
Micrograms
Intermittent
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Information on toxicological effects
Classification
Titanium Dioxide -2B -
Product/ingredient name NTPIARCOSHA
Date of issue/Date of revision :5/23/2015.Date of previous issue :4/7/2015.Version :1.01 6/10
Section 11. Toxicological information
Not available.
Aspiration hazard
Not available.
Not available.
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
No known significant effects or critical hazards.General :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Not available.
Acute toxicity estimates
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects :Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects :Not available.
Date of issue/Date of revision :5/23/2015.Date of previous issue :4/7/2015.Version :1.01 7/10
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
Titanium Dioxide -352 low
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
:Disposal methods
Section 14. Transport information
-
-
-
-
-
-
Not regulated.Not regulated.
Special
provisions
Not Applicable
Emergency
schedules (EmS)
Not Applicable
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
No.No.
TDG
Classification
Not regulated.
-
-
-
No.
Special
provisions
Not Applicable
Mexico
Classification
Not regulated.
-
-
-
No.
Special
provisions
Not Applicable
IATA
Not regulated.
-
-
-
No.
Special
provisions
Not Applicable
Date of issue/Date of revision :5/23/2015.Date of previous issue :4/7/2015.Version :1.01 8/10
Section 14. Transport information
Special precautions for user
Transport in bulk according
to Annex II of MARPOL
73/78 and the IBC Code
:Not available.
:Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
Section 15. Regulatory information
U.S. Federal regulations :
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
State regulations
Section 16. Other information
Notice to reader
Hazardous Material Information System (U.S.A.)
1
0
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller [phone].
The customer is responsible for determining the PPE code for this material.
Date of issue/Date of revision :5/23/2015.Date of previous issue :4/7/2015.Version :1.01 9/10
Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Regulatory requirements are subject to change and may differ between various
locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all
country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of
the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use
of this product. The customer/buyer/user should not use the product for any purpose other than the purpose
shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling
instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the
manufacturer cannot be responsible for SDSs obtained from any other source.
Date of issue/Date of revision :5/23/2015.Date of previous issue :4/7/2015.Version :1.01 10/10

Version: 1.2 Revision Date: 11/30/2018

SAFETY DATA SHEET
1. Identification

Material name: SPECTREM 2 WHITE
Material: 947806 502

Recommended use and restriction on use
Recommended use:
Restrictions on use:

Manufacturer/Importer/Supplier/Distributor Information Tremco U.S Sealants 3735 Green Road Beachwood OH 44122 US
Contact person:
Telephone:
Emergency telephone number:
2. Hazard(s) identification

Hazard Classification
Health Hazards
Carcinogenicity Category 2
Toxic to reproduction Category 2

Unknown toxicity - Health

Hazard Symbol:

Signal Word:

Hazard Statement:
Label Elements

Version: 1.2 Revision Date: 11/30/2018

Precautionary
Statements
Prevention:

Response:
Storage:
Disposal:

Hazard(s) not otherwise
classified (HNOC):

3. Composition/information on ingredients

Mixtures

Chemical Identity CAS number Content in percent (%)*
Calcium carbonate 471-34-1 30 - 60%
Calcium Carbonate (Limestone)
1317-65-3 10 - 30%
Titanium dioxide 13463-67-7 1 - 5%
Stearic acid 57-11-4 1 - 5%
Octamethylcyclotetrasiloxane 556-67-2 0.1 - 1%
Aluminum oxide 1344-28-1 0.1 - 1% * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
4. First-aid measures

Ingestion:
Move to fresh air.
Wash skin thoroughly with soap and water. If skin irritation occurs: Get medical advice/attention.

Any material that contacts the eye should be washed out immediately with water. If easy to do, remove contact lenses. If eye irritation persists: Get medical advice/attention.
Most important symptoms/effects, acute and delayed
Symptoms:
Indication of immediate medical attention and special treatment needed
Treatment:

Version: 1.2 Revision Date: 11/30/2018

5. Fire-fighting measures

General Fire Hazards: No unusual fire or explosion hazards noted.

Suitable (and unsuitable) extinguishing media

Suitable extinguishing
media:
Use fire-extinguishing media appropriate for surrounding materials.

Unsuitable extinguishing
media:
Do not use water jet as an extinguisher, as this will spread the fire.

During fire, gases hazardous to health may be formed.

Special protective equipment and precautions for firefighters
Special fire fighting
procedures:

Special protective equipment
for fire-fighters:
6. Accidental release measures
No data available.
Collect spillage in containers, seal securely and deliver for disposal according to local regulations.

In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
Environmental Precautions:

7. Handling and storage
Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Use personal protective equipment as required. Ventilate well, avoid breathing vapors. Use approved respirator if air contamination is above accepted level. Use mechanical ventilation in case of handling which causes formation of dust.
Conditions for safe storage,
including any
incompatibilities:

Version: 1.2 Revision Date: 11/30/2018

8. Exposure controls/personal protection

Control Parameters
Occupational Exposure Limits
Chemical Identity Type Exposure Limit Values Source
Calcium carbonate - Total dust. PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) Calcium carbonate - Respirable fraction. PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) Calcium Carbonate (Limestone) - Total dust. PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) Calcium Carbonate (Limestone) - Respirable fraction.
PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006)
Titanium dioxide TWA 10 mg/m3 US. ACGIH Threshold Limit Values (2011) Titanium dioxide - Total dust. PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) Titanium dioxide - Respirable fraction. TWA 15 millions of particles per cubic foot of air
US. OSHA Table Z-3 (29 CFR 1910.1000) (03 2016)
Titanium dioxide - Total dust. TWA 15 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000) (03 2016) Titanium dioxide - Respirable fraction. TWA 5 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000) (03 2016) Titanium dioxide - Total dust. TWA 50 millions of particles per cubic foot of air
US. OSHA Table Z-3 (29 CFR 1910.1000) (03 2016)
Stearic acid - Respirable fraction. TWA 3 mg/m3 US. ACGIH Threshold Limit Values (03 2017)
Stearic acid - Inhalable fraction. TWA 10 mg/m3 US. ACGIH Threshold Limit Values (03 2017)
Aluminum oxide - Respirable fraction. TWA 1 mg/m3 US. ACGIH Threshold Limit Values (2011)
PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) Aluminum oxide - Total dust. PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006)
TWA 50 millions of particles per cubic foot of air
US. OSHA Table Z-3 (29 CFR 1910.1000) (03 2016)
Aluminum oxide - Respirable fraction. TWA 15 millions of particles per cubic foot of air
US. OSHA Table Z-3 (29 CFR 1910.1000) (03 2016)
TWA 5 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000) (03 2016) Aluminum oxide - Total dust. TWA 15 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000) (03 2016)

Version: 1.2 Revision Date: 11/30/2018

Chemical name Type Exposure Limit Values Source
Calcium carbonate - Total dust. STEL 20 mg/m3 Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007)
Calcium carbonate - Respirable fraction. TWA 3 mg/m3 Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007)
Calcium carbonate - Total dust. TWA 10 mg/m3 Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007)
Calcium carbonate - Total dust. TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) (09 2017)
Calcium Carbonate (Limestone) - Total dust. STEL 20 mg/m3 Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007)
TWA 10 mg/m3 Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007)
Calcium Carbonate (Limestone) - Respirable fraction.
TWA 3 mg/m3 Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007)
Calcium Carbonate (Limestone) - Total dust. TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) (09 2017)
Titanium dioxide - Total dust. TWA 10 mg/m3 Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007)
Titanium dioxide - Respirable fraction. TWA 3 mg/m3 Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007)
Titanium dioxide TWA 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (11 2010)
Titanium dioxide - Total dust. TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) (09 2017)
Stearic acid TWA 10 mg/m3 Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007)
Stearic acid TWA 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (11 2010)
Mechanical ventilation or local exhaust ventilation may be required. Observe good industrial hygiene practices. Observe occupational exposure limits and minimize the risk of inhalation of dust.

Version: 1.2 Revision Date: 11/30/2018

Individual protection measures, such as personal protective equipment
General information:
Wear safety glasses with side shields (or goggles).

Skin Protection Use suitable protective gloves if risk of skin contact.
Other:
Respiratory Protection:

Hygiene measures:

9. Physical and chemical properties

Appearance
solid
Paste
White
Mild sharp
No data available.
No data available.
No data available.
No data available.
No data available.
Slower than Ether
No

No data available.
No data available.
No data available.
No data available.
No data available.
Vapors are heavier than air and may travel along the floor and in the bottom of containers.
1.43
Practically Insoluble

Version: 1.2 Revision Date: 11/30/2018

Solubility (other):
Partition coefficient (n-octanol/water):
Auto-ignition temperature:
Decomposition temperature:
Viscosity:
10. Stability and reactivity

Reactivity: No data available.

Chemical Stability: Material is stable under normal conditions.
No data available.

Avoid heat or contamination.
Alcohols. Strong acids. Avoid contact with oxidizing agents (e.g. nitric acid, peroxides and chromates). Strong bases. Water, moisture.
Thermal decomposition or combustion may liberate carbon oxides and
other toxic gases or vapors.

11. Toxicological information

Information on likely routes of exposure In high concentrations, vapors, fumes or mists may irritate nose, throat and
mucus membranes.

May be harmful in contact with skin. Causes mild skin irritation.

Eye contact is possible and should be avoided.
Ingestion:

Symptoms related to the physical, chemical and toxicological characteristics

No data available.

No data available.

No data available.
Ingestion:

Information on toxicological effects

Acute toxicity (list all possible routes of exposure)
Oral ATEmix: 31,529.42 mg/kg

Version: 1.2 Revision Date: 11/30/2018

Dermal ATEmix: 3,955.98 mg/kg

Inhalation
Not classified for acute toxicity based on available data.

Specified substance(s): Titanium dioxide LC 50 (Rat): 3.43 mg/l

Octamethylcyclotetrasiloxane LC 50 (Rat): 36 mg/l
Aluminum oxide LC 50 (Rat): 7.6 mg/l

Repeated dose toxicity No data available.

Skin Corrosion/Irritation
No data available.

Specified substance(s): Calcium carbonate in vivo (Rabbit): Not irritant Experimental result, Key study

Titanium dioxide in vivo (Rabbit): Not irritant Experimental result, Supporting study

Stearic acid in vivo (Rabbit): Not irritant Experimental result, Key study

Octamethylcyclotetrasiloxane in vivo (Rabbit): Not irritant Experimental result, Key study

Aluminum oxide in vivo (Rabbit): Not irritant Experimental result, Key study

Serious Eye Damage/Eye Irritation
No data available.
Specified substance(s):
Calcium carbonate Rabbit, 24 - 72 hrs: Not irritating
Titanium dioxide Rabbit, 24 hrs: Not irritating
Stearic acid Rabbit, 27 - 72 hrs: Not irritating
Aluminum oxide Rabbit, 24 hrs: Not irritating

Respiratory or Skin Sensitization
No data available.

Version: 1.2 Revision Date: 11/30/2018

Carcinogenicity
Suspected of causing cancer.

IARC Monographs on the Evaluation of Carcinogenic Risks to Humans:

US. National Toxicology Program (NTP) Report on Carcinogens: No carcinogenic components identified

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050):
No carcinogenic components identified

Germ Cell Mutagenicity
In vitro No data available.

In vivo No data available.

Reproductive toxicity Suspected of damaging fertility or the unborn child.
Specific Target Organ Toxicity - Single Exposure
No data available.

Specific Target Organ Toxicity - Repeated Exposure
No data available.

Aspiration Hazard No data available.

No data available.

12. Ecological information

Ecotoxicity:

Acute hazards to the aquatic environment:

Fish
No data available.

Version: 1.2 Revision Date: 11/30/2018

Aquatic Invertebrates No data available.

Specified substance(s):
Titanium dioxide EC 50 (Water flea (Daphnia magna), 48 h): > 1,000 mg/l Intoxication

Chronic hazards to the aquatic environment:

Fish No data available.

Aquatic Invertebrates No data available.

Toxicity to Aquatic Plants No data available.

Persistence and Degradability

Biodegradation No data available.

BOD/COD Ratio
Product:

Bioaccumulative potential
Bioconcentration Factor (BCF)
No data available.

Specified substance(s): Octamethylcyclotetrasilox
ane
Fathead minnow (Pimephales promelas), Bioconcentration Factor (BCF):
14,261 (Flow through)

Partition Coefficient n-octanol / water (log Kow) No data available.

Specified substance(s):
Stearic acid Log Kow: 8.23
No data available.
No data available.
13. Disposal considerations

Version: 1.2 Revision Date: 11/30/2018

Disposal instructions:

No data available.

14. Transport information

TDG:

Not Regulated

CFR / DOT:
Not Regulated
IMDG: Not Regulated
15. Regulatory information

US Federal Regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) None present or none present in regulated quantities.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
None present or none present in regulated quantities.
CERCLA Hazardous Substance List (40 CFR 302.4):
Cyclohexane 1000 lbs. Methanol 5000 lbs.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories Delayed (Chronic) Health Hazard
SARA 302 Extremely Hazardous Substance None present or none present in regulated quantities.
SARA 304 Emergency Release Notification
Cyclohexane 1000 lbs. Methanol 5000 lbs.

Version: 1.2 Revision Date: 11/30/2018

SARA 311/312 Hazardous Chemical
Chemical Identity Threshold Planning Quantity
Calcium carbonate 10000 lbs Calcium Carbonate
(Limestone)
10000 lbs
Titanium dioxide 10000 lbs
Stearic acid 10000 lbs Octamethylcyclotetrasiloxane 10000 lbs
Aluminum oxide 10000 lbs

SARA 313 (TRI Reporting) None present or none present in regulated quantities.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
None present or none present in regulated quantities.
Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3) None present or none present in regulated quantities.

US State Regulations

US. California Proposition 65

Cancer and Reproductive Harm - www.P65Warnings.ca.gov

US. New Jersey Worker and Community Right-to-Know Act
Calcium carbonate Calcium Carbonate (Limestone) Titanium dioxide
US. Massachusetts RTK - Substance List
Calcium carbonate Calcium Carbonate (Limestone) Titanium dioxide Crystalline Silica (Quartz)/ Silica Sand
US. Pennsylvania RTK - Hazardous Substances
Calcium carbonate Calcium Carbonate (Limestone) Titanium dioxide
US. Rhode Island RTK
Calcium carbonate Calcium Carbonate (Limestone) Titanium dioxide
International regulations

Version: 1.2 Revision Date: 11/30/2018

Montreal protocol
Not applicable

Stockholm convention
Not applicable
Rotterdam convention
Not applicable

Kyoto protocol
Not applicable

VOC:
Regulatory VOC (less water and exempt solvent) : 30 g/l
VOC Method 310 : 2.08 %

Version: 1.2 Revision Date: 11/30/2018

Inventory Status:Australia AICS: One or more components in this product are
not listed on or exempt from the Inventory.

16.Other information, including date of preparation or last revision

Revision Date:

Version #:

Further Information:

Version: 1.2 Revision Date: 11/30/2018

Disclaimer:

Waterborne Acrylic Dry Fall
Flat Brilliant White
Not available.
Liquid.
US / Canada: [phone]
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
B42W1
B42W1Product code :
Product Information
Telephone Number
:US / Canada: [phone]
Mexico: Not Available
Regulatory Information
Telephone Number
:US / Canada: [phone]
Mexico: Not Available
Transportation Emergency
Telephone Number
:US / Canada: [phone]
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
National contact :Sherwin-Williams Canada Inc.
180 Brunel Road
Mississauga, Ontario L4Z 1T5 Canada
Section 2. Hazards identification
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 1A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Classification of the
substance or mixture
:
Signal word :Danger
Hazard pictograms :
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 35.6%
Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 37.2%
Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 35.
6%
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B42W1 Waterborne Acrylic Dry Fall
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Section 2. Hazards identification
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Use only outdoors or in a well-ventilated area. Do not breathe
vapor. Wash hands thoroughly after handling.
Response :Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or physician if you feel unwell. IF ON SKIN: Wash with plenty
of soap and water. Take off contaminated clothing and wash it before reuse. If skin
irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If
eye irritation persists: Get medical attention.
Storage :Store locked up.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Causes serious eye irritation.
Causes skin irritation.
May cause cancer.
May cause respiratory irritation.
May cause damage to organs through prolonged or repeated exposure.
:Hazard statements
Please refer to the SDS for additional information. Keep out of reach of children. Do
not transfer contents to other containers for storage.
Supplemental label
elements
WARNING: This product contains chemicals known to the State of California to cause
cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.
Adequate ventilation required when sanding or abrading the dried film. If Adequate
ventilation cannot be provided wear an approved particulate respirator (NIOSH
approved). Follow respirator manufacturer's directions for respirator use. DELAYED
EFFECTS FROM LONG TERM OVEREXPOSURE. Abrading or sanding of the dry film
may release Crystalline Silica which has been shown to cause lung damage and cancer
under long term exposure.
:
Section 3. Composition/information on ingredients
Calcium Carbonate 30.24 1317-65-3
Titanium Dioxide 5.4 13463-67-7
Ethanol 1.56 64-17-5
Crystalline Silica, respirable powder 0.12 14808-60-7
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
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Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Description of necessary first aid measures
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
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Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Section 7. Handling and storage
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use. Empty
containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Date of issue/Date of revision :1/16/2018 Date of previous issue :12/4/2017 Version :6.01 4/12
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Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination. See Section 10 for
incompatible materials before handling or use.
:
:
Calcium Carbonate NIOSH REL (United States, 10/2016).
TWA: 5 mg/m³ 10 hours. Form: Respirable
fraction
TWA: 10 mg/m³ 10 hours. Form: Total
OSHA PEL (United States, 6/2016).
TWA: 5 mg/m³ 8 hours. Form: Respirable
fraction
TWA: 15 mg/m³ 8 hours. Form: Total dust
Titanium Dioxide ACGIH TLV (United States, 3/2016).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 6/2016).
TWA: 15 mg/m³ 8 hours. Form: Total dust
Ethanol ACGIH TLV (United States, 3/2016).
STEL: 1000 ppm 15 minutes.
NIOSH REL (United States, 10/2016).
TWA: 1000 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
OSHA PEL (United States, 6/2016).
TWA: 1000 ppm 8 hours.
TWA: 1900 mg/m³ 8 hours.
Crystalline Silica, respirable powder OSHA PEL Z3 (United States, 6/2016).
TWA: 250 mppcf / (%SiO2+5) 8 hours. Form:
Respirable
TWA: 10 mg/m³ / (%SiO2+2) 8 hours. Form:
Respirable
OSHA PEL (United States, 6/2016).
TWA: 50 µg/m³ 8 hours. Form: Respirable
dust
ACGIH TLV (United States, 3/2016).
TWA: 0.025 mg/m³ 8 hours. Form:
Respirable fraction
NIOSH REL (United States, 10/2016).
TWA: 0.05 mg/m³ 10 hours. Form: respirable
dust
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
Occupational exposure limits (Canada)
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Section 8. Exposure controls/personal protection
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor
or mist, use process enclosures, local exhaust ventilation or other engineering controls
to keep worker exposure to airborne contaminants below any recommended or statutory
limits.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
ethanol CA Alberta Provincial (Canada, 4/2009).
8 hrs OEL: 1000 ppm 8 hours.
8 hrs OEL: 1880 mg/m³ 8 hours.
CA British Columbia Provincial (Canada,
7/2016).
STEL: 1000 ppm 15 minutes.
CA Ontario Provincial (Canada, 7/2015).
STEL: 1000 ppm 15 minutes.
CA Québec Provincial (Canada, 1/2014).
TWAEV: 1000 ppm 8 hours.
TWAEV: 1880 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 1250 ppm 15 minutes.
TWA: 1000 ppm 8 hours.
Ingredient name Exposure limits
Environmental exposure
controls
:
ethanol NOM-010-STPS-2014 (Mexico, 4/2016).
STEL: 1000 ppm 15 minutes.
Ingredient name Exposure limits
Occupational exposure limits (Mexico)
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Section 8. Exposure controls/personal protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Respiratory protection :
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.45
1 [Air = 1]
5.9 kPa (44 mm Hg) [at 20°C]
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate 1.6 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: >93.3°C (>199.9°F)
Not available.
9.5
Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :77°C (170.6°F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Lower: 3.3%
Upper: 19%
Decomposition temperature :Not available.
Heat of combustion :1.17 kJ/g
Aerosol product
Molecular weight :Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
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Section 11. Toxicological information
Acute toxicity
Ethanol LC50 Inhalation Vapor Rat 124700 mg/m³4 hours
LD50 Oral Rat 7 g/kg -
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Titanium Dioxide Skin - Mild irritant Human -72 hours 300
Micrograms
Intermittent
-
Ethanol Eyes - Mild irritant Rabbit -24 hours 500
milligrams
-
Eyes - Moderate irritant Rabbit -0.066666667
minutes 100
milligrams
-
Eyes - Moderate irritant Rabbit -100
microliters
-
Eyes - Severe irritant Rabbit -500
milligrams
-
Skin - Mild irritant Rabbit -400
milligrams
-
Skin - Moderate irritant Rabbit -24 hours 20
milligrams
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Calcium Carbonate Category 3 Not applicable.Respiratory tract
irritation
Ethanol Category 3 Not applicable.Respiratory tract
irritation and
Narcotic effects
Name Category Route of
exposure
Target organs
Information on toxicological effects
Classification
Titanium Dioxide -2B -
Ethanol -1 -
Crystalline Silica, respirable
powder
-1 Known to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
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Section 11. Toxicological information
Name Category
Ethanol Category 2 Not determined Not determined
Crystalline Silica, respirable powder Category 1 Inhalation Not determined
Aspiration hazard
Not available.
Route of
exposure
Target organs
Not available.
Information on the likely
routes of exposure
Inhalation :May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
May cause damage to organs through prolonged or repeated exposure.General :
May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Not available.
Acute toxicity estimates
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects :Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects :Not available.
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Section 12. Ecological information
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Not available.
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Ethanol --Readily
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Ethanol Acute EC50 17.921 mg/l Marine water Algae - Ulva pertusa 96 hours
Acute EC50 2000 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 25500 µg/l Marine water Crustaceans - Artemia
franciscana - Larvae
48 hours
Acute LC50 42000 µg/l Fresh water Fish - Oncorhynchus mykiss 4 days
Chronic NOEC 4.995 mg/l Marine water Algae - Ulva pertusa 96 hours
Chronic NOEC 100 ul/L Fresh water Daphnia - Daphnia magna -
Neonate
21 days
Chronic NOEC 0.375 ul/L Fresh water Fish - Gambusia holbrooki -
Larvae
12 weeks
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
:Disposal methods
Section 14. Transport information
-
-
-
-
Not regulated.Not regulated.
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
TDG
Classification
Not regulated.
-
-
Mexico
Classification
Not regulated.
-
-
IATA
Not regulated.
-
-
Date of issue/Date of revision :1/16/2018 Date of previous issue :12/4/2017 Version :6.01 10/12
B42W1 Waterborne Acrylic Dry Fall
Flat Brilliant White
Section 14. Transport information
--
--
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No.No.
Not available.
:
Proper shipping name :
Ship type :Not available.
Pollution category :Not available.
Not available.
:
-
No.
-
-
No.
-
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability
prior to shipment, and compliance with the applicable regulations is the sole
responsibility of the person offering the product for transport. People loading and
unloading dangerous goods must be trained on all of the risks deriving from the
substances and on all actions in case of emergency situations.
-
No.
-
Section 15. Regulatory information
SARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
Section 16. Other information
1/16/2018
History
Date of printing :
:1/16/2018
Hazardous Material Information System (U.S.A.)
2
0
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
SKIN CORROSION/IRRITATION - Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method
CARCINOGENICITY - Category 1A Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method
Procedure used to derive the classification
Classification Justification
Date of issue/Date of revision :1/16/2018 Date of previous issue :12/4/2017 Version :6.01 11/12
B42W1 Waterborne Acrylic Dry Fall
Flat Brilliant White
Section 16. Other information
Date of issue/Date of
revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use
or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject
to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to
ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use
of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to
determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the
product for any purpose other than the purpose shown in the applicable section of this SDS without first
referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for
information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from
any other source.
Notice to reader
Date of previous issue
:
:
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
12/4/2017
6.01
Date of issue/Date of revision :1/16/2018 Date of previous issue :12/4/2017 Version :6.01 12/12
B42W1 Waterborne Acrylic Dry Fall
Flat Brilliant White

Date Revised: MAR 2020
Supersedes: DEC 2018
SECTION I - PRODUCT AND COMPANY IDENTIFICATION
Weld-On® 781™ Plumbing Gray Low VOC Cement for PVC Plastic Pipe
Low VOC Solvent Cement for PVC Plastic Pipe
RESTRICTIONS ON USE: No relevant information available MANUFACTURER:IPS Corporation
17109 South Main Street, Gardena, CA 90248-3127
P.O. Box 379, Gardena, CA 90247-0379
Tel. [phone] E-mail address: [e-mail]
EMERGENCY: Transportation: CHEMTEL Tel. [phone] (International) Medical: CHEMTEL Tel. [phone] (International)
SECTION 2 - HAZARDS IDENTIFICATION
Acute Toxicity: Category 2 Acute Toxicity:None Known Flammable Liquid Category 2
Skin Irritation: Category 3 Chronic Toxicity:None Known
Skin Sensitization: NOCarcinogenicity:Category 2Eye Irritation:
GHS LABEL:
Signal Word:Danger
H225: Highly flammable liquid and vapor P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking
H319: Causes serious eye irritation P261: Avoid breathing dust/fume/gas/mist/vapors/spray
H335: May cause respiratory irritation P280: Wear protective gloves/protective clothing/eye protection/face protection
H336: May cause drowsiness or dizziness P337+P313: Get medical advice/attentionH351: Suspected of causing cancer P403+P233: Store in a well ventilated place. Keep container tightly closedP501: Dispose of contents/container in accordance with local regulation
P301+310: IF SWALLOWED: Call a POISON CENTER and get Medical Attention P304+340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P331: Do NOT induce vomiting.P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. P303+361+353: IF ON SKIN (or hair): Take off immediately all contaminated clothing.Remove contact lenses, if present and easy to do. Continue rinsing.Rinse skin with water [or shower].P308+313: IF exposed or concerned: Get medical advice/attention.
Physical Hazards Not Otherwise Classified May form explosive peroxides
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
CONCENTRATION % by WeightTetrahydrofuran (THF)109-99-9 203-726-8 10 - 30
Methyl Ethyl Ketone (MEK)78-93-3 201-159-0 20 - 40
Cyclohexanone 108-94-1 203-631-1 15 - 35Acetone67-64-1 200-662-2 5 - 15
All of the constituents of this adhesive product are listed on the TSCA inventory of chemical substances maintained by the US EPA, or are exempt from that listing. * Indicates this chemical is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 (40CFR372).# indicates that this chemical is found on Proposition 65’s List of chemicals known to the State of California to cause cancer or reproductive toxicity.
SECTION 4 - FIRST AID MEASURES
Contact with eyes:Flush eyes immediately with plenty of water for 15 minutes and seek medical advice immediately. Skin contact:Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water. If irritation develops, seek medical advice.
Inhalation:Remove to fresh air. If breathing is stopped, give artificial respiration. If breathing is difficult, give oxygen. Seek medical advice. Ingestion:Rinse mouth with water. Give 1 or 2 glasses of water or milk to dilute. Do not induce vomiting. Seek medical advice immediately.
SECTION 5 - FIREFIGHTING MEASURES
Suitable Extinguishing Media:Dry chemical powder, carbon dioxide gas, foam, Halon, water fog.HMIS NFPA 0-Minimal Unsuitable Extinguishing Media:Water spray or stream. Health 2 2 1-Slight Exposure Hazards:Inhalation and dermal contact Flammability 3 3 2-Moderate Combustion Products:Oxides of carbon, hydrogen chloride and smoke Reactivity 0 0 3-SeriousPPEB4-Severe Protection for Firefighters:Self-contained breathing apparatus or full-face positive pressure airline masks.Safety Glasses and Gloves
SECTION 6 - ACCIDENTAL RELEASE MEASURES Personal precautions:Keep away from heat, sparks and open flame.
Provide sufficient ventilation, use explosion-proof exhaust ventilation equipment or wear suitable respiratory protective equipment.
Prevent contact with skin or eyes (see section 8). Environmental Precautions:Prevent product or liquids contaminated with product from entering sewers, drains, soil or open water course. Methods for Cleaning up:Clean up with sand or other inert absorbent material. Transfer to a closable steel vessel. Materials not to be used for clean up:Aluminum or plastic containers
SECTION 7 - HANDLING AND STORAGE Handling: Avoid breathing of vapor, avoid contact with eyes, skin and clothing.Keep away from ignition sources, use only electrically grounded handling equipment and ensure adequate ventilation/fume exhaust hoods.Do not eat, drink or smoke while handling. Storage: Store in ventilated room or shade below 44°C (110°F) and away from direct sunlight.Keep away from ignition sources and incompatible materials: caustics, ammonia, inorganic acids, strong oxidizers and isocyanates.
Follow all precautionary information on container label, product bulletins and solvent cementing literature.
SECTION 8 - PRECAUTIONS TO CONTROL EXPOSURE / PERSONAL PROTECTION
EXPOSURE LIMITS:ACGIH 8-HOUR TLV
ACGIH 15-MINUTE STEL
OSHA 8-HOUR PEL
OSHA 15-MINUTE STEL
OSHA PEL-Ceiling
CAL/OSHA 8-HOUR PEL
CAL/OSHA 15-MINUTECeiling
CAL/OSHA 15-MINUTE STEL
Tetrahydrofuran (THF)50 ppm 100 ppm 200 ppm N/E N/E 200 ppm N/E 250 ppmMethyl Ethyl Ketone (MEK)200 ppm 300 ppm 200 ppm N/E N/E 200 ppm N/E 300 ppm20 ppm 50 ppm 50 ppm N/E N/E 25 ppm N/E N/EAcetone250 ppm 500 ppm 1000 ppm N/E N/E 500 ppm 3000 ppm 750 ppm Engineering Controls:Use local exhaust as needed.
Monitoring:Maintain breathing zone airborne concentrations below exposure limits. Personal Protective Equipment (PPE): Eye Protection:Avoid contact with eyes, wear splash-proof chemical goggles, face shield, safety glasses (spectacles) with brow guards and side shields,etc. as may be appropriate for the exposure.
Skin Protection:Prevent contact with the skin as much as possible. Butyl rubber gloves should be used for frequent immersion. Use of solvent-resistant gloves or solvent-resistant barrier cream should provide adequate protection when normal adhesive applicationpractices and procedures are used for making structural bonds.
Respiratory Protection: Prevent inhalation of the solvents. Use in a well-ventilated room. Open doors and/or windows to ensure airflow and air changes. Use localexhaust ventilation to remove airborne contaminants from employee breathing zone and to keep contaminants below levels listed above.
With normal use, the Exposure Limit Value will not usually be reached. When limits approached, use respiratory protection equipment.
GHS SAFETY DATA SHEET
Weld-On® 781™ Plumbing Gray Low VOC Cement for PVC Plastic Pipe
PRODUCT NAME:
PRODUCT USE:
SUPPLIER:
GHS CLASSIFICATION:Health Environmental Physical
Category 2
HAZARD STATEMENTS PRECAUTIONARY STATEMENTS
RESPONSE STATEMENTS
CAS EINECS REACH Registration Number 01-2119444314-46-0000
01-2119457290-43-0000
01-2119453616-35-000001-2119471330-49-0000
Component
Cyclohexanone
Filename: W-O781 Plumbing Gray LoVoc 3-20.xls Page 1 of 2 3/31/2020 8:37 AM

Date Revised: MAR 2020
Supersedes: DEC 2018
GHS SAFETY DATA SHEET
Weld-On® 781™ Plumbing Gray Low VOC Cement for PVC Plastic Pipe
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance:Gray, medium syrupy liquid Odor:Ketone Odor Threshold: 0.88 ppm (Cyclohexanone) pH:Not Applicable Melting/Freezing Point:-108.5°C (-163.3°F) Based on first melting component: THF Boiling Range:56°C (133°F) to 156°C (313°F) Boiling Point:56°C (133°F) Based on first boiling component: Acetone Evaporation Rate:> 1.0 (BUAC = 1) Flash Point:-20°C (-4°F) TCC based on Acetone Flammability:Category 2 Specific Gravity: 0.920 @23°C ( 73°F)Flammability Limits:LEL: 1.1% based on Cyclohexanone
Solubility:Solvent portion soluble in water. Resin portion separates out.UEL: 12.8% based on Acetone Partition Coefficient n-octanol/water:Not Available Vapor Pressure:190 mm Hg @ 20°C (68°F) Acetone Auto-ignition Temperature:321°C (610°F) based on THF Vapor Density:>2.0 (Air = 1)Not Applicable Decomposition Temperature:Not Applicable Other Data: Viscosity:Medium bodied
VOC Content:When applied as directed, per SCAQMD Rule 1168, Test Method 316A,VOC content is: < 510 g/l.SECTION 10 - STABILITY AND REACTIVITY
Reactivity: Heating may cause a fire
Stability: Stable under normal conditions
Hazardous decomposition products:None in normal use. When forced to burn, this product gives off oxides of carbon, hydrogen chloride and smoke.Conditions to avoid: Keep away from heat, sparks, open flame and other ignition sources. Incompatible Materials:Oxidizers, strong acids and bases, amines, ammonia
SECTION 11 - TOXICOLOGICAL INFORMATION
Likely Routes of Exposure:Inhalation, Eye and Skin ContactAcute symptoms and effects:
Vapors slightly uncomfortable. Overexposure may result in severe eye injury with corneal or conjunctival inflammation on contact with the liquid.
Swallowing can cause nausea, vomiting, diarrhea and loss of consciousness.
Chronic (long-term) effects: (MEK): Low level chronic exposure has been shown to cause decreased memory and impairment of the central nervous system.
Respiratory or Skin Sensitization:Not Applicable
Carcinogenicity: Tetrahydrofuran (THF): Category 2: Suspected of causing cancer
Toxicity:8 hrs. 23,500 mg/m3 (rat)
3 hrs. 21,000 mg/m3 (rat)5800 mg/kg (rat)
Acute Toxicity Category 2
Calculated (ATEs)Acute (Dermal) Toxicity: Category 2 Acute (Inhalation) Toxicity: Category 2
CategorySpecific Target Exposure Toxicity Methyl Ethyl Ketone 3 Central Nervous System
(Single Exposure): Cyclohexanone N/E
Tetrahydrofuran 3 Central Nervous System
Acetone 3 Central Nervous System
Specific Target Exposure Toxicity (Repeated Exposure):
Aspiration Hazard: Based on available data, the classification criteria are not met.
SECTION 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Mobility in Soil: If released into the environment, this product can move rapidly through the soil.
Degradability:Not readily biodegradable Bioaccumulation:Minimal to none. Results of PBT and vPvB assessment: PBT: Not applicable. vPvB: Not applicable
Other adverse effects:No relevant information available.
SECTION 13 - WASTE DISPOSAL CONSIDERATIONS
Dispose of waste and containers in compliance with applicable Federal, State, and Local Regulations. Consult disposal expert. Do not reuse empty containers.
SECTION 14 - TRANSPORT INFORMATION Proper Shipping Name: Adhesives Hazard Class:3 DOT Limited Quantity: Up to 5L per inner packaging, 30 kg gross weight per package. Secondary Risk:None Consumer Commodity: Depending on packaging, these quantities may qualify under DOT as ORM-D Identification Number:UN 1133 Packing Group:PG II TDG CLASS: FLAMMABLE LIQUID 3 Label Required:Class 3 Flammable Liquid SHIPPING NAME: ADHESIVES Marine Pollutant:NO UN NUMBER/PACKING GROUP:UN 1133, PG II
SECTION 15 - REGULATORY INFORMATION
Highly Flammable, Irritant, Carc. Cat. 2 Ingredient Listings: USA TSCA, Europe EINECS, Canada DSL, Australia
Symbols:F, Xi AICS, Korea ECL/TCCL, Japan MITI (ENCS)Compliance Statement: This SDS was prepared to be in accordance with:
US OSHA Hazard Communication Standard 29 CFR 1910.1200 (Rev 2012)
Canadian Workplace Hazardous Materials Information System (WHMIS) 2015
European Regulation (EC) No (EU) 2015/830 on classification, labelling and packaging of substances and mixtures  
SECTION 16 - OTHER INFORMATION
Specification Information: Department issuing data sheet:IPS, Safety Health & Environmental Affairs All ingredients are compliant with the requirements of the European E-mail address:<[e-mail]>Directive on RoHS (Restriction of Hazardous Substances).
Training necessary:Yes, training in practices and procedures contained in product literature. Reissue date / reason for reissue:3/31/2020 / Updated GHS Standard Format Intended Use of Product:Solvent Cement for PVC Plastic Pipe
This product is intended for use by skilled individuals at their own risk. The information contained herein is based on data considered accurate based on current state ofknowledge and experience. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof.
Inhalation:Excessive exposure to vapors or spray mists can result in headache, dizziness, incoordination and loss of consciousness. Irritation of the eyes, nose, throat and lungs can also occur when exposed to high vapor concentrations. Some reports have associated repeated and prolonged occupational overexposure to
solvents with permanent nervous system damage.
Eye Contact: Skin Contact:Liquid contact may remove natural skin oils resulting in skin irritation. May cause defatting and irritation of skin (Dermatitis) upon prolonged or repeated Ingestion:
Health Hazards Not Otherwise Classified: This material may cause defatting and irritation of skin (Dermatitis) upon prolonged or repeated contact.
Reproductive Effects Teratogenicity Mutagenicity Embryotoxicity Sensitization to Product Synergistic ProductsNot Established Not Established Not Established Not Established Not Established Not Established
LD50 (Oral)LD50 (Dermal)LC50 (Inhalation)
Methyl Ethyl Ketone 2737 mg/kg (rat)6480 mg/kg (rabbit)
Cyclohexanone 1535 mg/kg (rat)948 mg/kg (rabbit) 4 hrs. 8,000 PPM (rat)
Tetrahydrofuran 2842 mg/kg (rat) > 2,000 mg/kg (rat)Acetone 20000 mg/kg (rabbit) 50,100 mg/m3 (rat)
Acute (Oral) Toxicity: Category 2
Route of Exposure Affected OrgansInhalationN/E N/E
Inhalation
Inhalation
No Data Available
LC50 EC50 EC50
Acute Aquatic Toxicity:Pimephales promelas (fathead minnow); 96-hour
Daphnia magna (water flea): 48-hour
Pseudokirchneriella subcapitata (microalgae)Growth rate inhibitor
No Data Available
Methyl Ethyl Ketone > 100 mg/L > 100 mg/L 2,029 mg/l - 96 hour
Cyclohexanone 527 mg/L > 100 mg/L 0.925 mg/l - 72 hour
EXCEPTION for Ground Shipping
TDG INFORMATION
Precautionary Label Information:
Tetrahydrofuran 2160 mg/L No Data Available 3,700 mg/l - 192 hour
Acetone No Data Available 7630
Filename: W-O781 Plumbing Gray LoVoc 3-20.xls Page 2 of 2 3/31/2020 8:37 AM
Conforms to HazCom 2012/ United States
Safety Data Sheet
Section 1. Identification

GHS product Identifier 650 Sheet Membrane Other means of identification Not available Relevant identified used of the substance or mixtures and uses advised against Polymer modified bitumen membrane used as a post concrete self-adhesive water proofing membrane/vapor retarder that virtually eliminates water and vapor transmission through concrete slabs. Supplier’s details Polyguard Products, Inc. 4101 South Interstate 45 Ennis, TX 75119 Tel: [phone] Emergency telephone number) with hours of operation) CHEMTREC, US 1-800-424-9300 International 1-703-527-3887 (24/7)
Section 2. Hazards Identification

OSHA/HCS status While this material is not considered hazardous by the OSHA Hazardous Communications Standard ( 49CFR1910.1200) , this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product. Classification of the substance or mixture Not classified
This product is manufactured as an article under the United States Hazard Communication System and is exempted from the regulatory requirements under HCS. GHS label elements Signal word No signal word Hazard statement No known significant effects or critical hazards. Precautionary statements Prevention Not applicable Response Not applicable Storage Not applicable Disposal Not applicable Hazards not otherwise classified None known Section 3. Composition/Information on Ingredients
Substance/Mixture Mixture Other means of identification Not available
Ingredient name % CAS # Asphalts 60-80 8052-42-4 Distillates( petroleum), petroleum residues vaccum 60-80 68955-27-1 Hydrogen Sulfide 0.001-0.01 7783-06-4 Limestone 15 - 20 1317-65-3 Crystalline Silica, quartz (inpurity) 0.5 – 1.5 14808-60-7 The exact percentage (concentration) in the composition has been withheld as a trade secret.
Occupational exposure limits, if available are listed in section 8. None of the components of this article are in a respirable state.

650 Sheet Membrane

Polyguard Products, Inc. Tel: [phone] www.polyguardproducts.com 2/7

Section 4. First Aid Measures
Description of necessary first aid measures.
Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if symptoms occur. Inhalation Because of the nature of this product, inhalation is not a route of exposure. Skin contact Material is in a solid form. If skin contact, wash area with soap and water. Get medical
attention if skin irritation occurs. Ingestion Ingestion is not a route of exposure. Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact No known significant effects or critical hazards Inhalation No known significant effects or critical hazards Skin contact No known significant effects or critical hazards Ingestion No known significant effects or critical hazards Over-exposure signs/symptoms Eye contact No known significant effects or critical hazards Inhalation No known significant effects or critical hazards Skin contact No known significant effects or critical hazards Ingestion No known significant effects or critical hazards Indication of immediate medical attention and special treatment needed, if necessary. Notes to physician: Treat symptomatically. Specific treatments No specific treatment Protection of first aiders No action shall be taken involving any personal risk or without suitable training. Section 5. Fire-Fighting Measures
Extinguishing media Suitable extinguishing media Use an extinguishing agent suitable for the surrounding fire. Unsuitable extinguishing media None known Specific hazards arising from the chemical No specific fire or explosion hazard.
Hazardous thermal decomposition products Decomposition products may include the following materials: Carbon Dioxide Carbon Monoxide Sulfur oxides
Low MW hydrocarbons Special protective equipment Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full-face piece operated in a positive pressure mode. Special protective actions for fire fighters Promptly isolate the scene by removing all persons from the vicinity of the incident is there is a fire. No action shall be taken involving any personal risks or without suitable training.

650 Sheet Membrane

Polyguard Products, Inc. Tel: [phone] www.polyguardproducts.com 3/7

Section 6. Accidental Release Measures
Personal precautions, protective equipment and emergency procedures. For non emergency personal Put on appropriate personal protective equipment. For emergency responders If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in “For non-emergency personnel.” Enviromental precautions Material will not spill.
Methods and materials for containment and cleaning up Spill Due to the physical state of this material, spills are not possible. Section 7. Handling and Storage
Precautions for safe handling Protective measures Put on appropriate personal protective equipment (see Section 8). Advice on general occupational hygiene Eating, drinking and smoking should be prohibited in areas where material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See section 8 for additional information on hygiene measures. Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry cool and well-ventilated area away from incompatible materials (see section 10) and food and drink. Keep container tightly closed and sealed until ready to use. Do not store in unlabeled containers. Section 8. Exposure Controls/Personal Protection
Occupational exposure limits
Ingredient name Exposure limits
Asphalt NIOSH REL (United States, 10/2016) CEIL: 5 mg/m3 15 minutes. Form: fume ACGIH TLV ( United States, 3/2019) TWA: 0.5 mg/m3 , (as benzene soluble aerosol) 8 hours. Form: inhalable fraction. Distillates( petroleum), petroleum residues vaccum
None
Hydrogen Sulfide ACGIH TLV ( United States, 3/2018) TWA: 1 ppm 8 hours STEL: 5 ppm 15 minutes OSHA PEL Z2 ( United States, 2/2013) CEIL:20 ppm AMP: 50 ppm 10 minutes. NIOSH REL (United States, 10/2016) CEIL: 15 mg/m3 10 minutes. Limestone NIOSH REL (United States, 10/2016) TWA: 10 mg/m3 (total) TWA 5 mg/m3 (respirable) OSHA PEL ( United States, 2/2013) TWA: 15 mg/m3 (total) TWA 5 mg/m3 ( respirable) Crystalline Silica, quartz (inpurity) NIOSH REL (United States, 10/2016) Ca TWA: 0.05 mg/m3
650 Sheet Membrane

Polyguard Products, Inc. Tel: [phone] www.polyguardproducts.com 4/7

Section 8. Exposure Controls/Personal Protection
Appropriate engineering controls No special ventilation requirements. Good ventilation should be sufficient to control
worker exposure to airborne contaminants. Environmental exposure controls Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Hygiene measure Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking, and using the lavatory and at the end of the working period. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection Safety eyewear complying with an approved standard should be used when risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases
and dusts. Skin Protection Hand protection Chemical- resistant, imprevious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Body protection Personal protective equipment for the body should be selected based on the task being
preformed and the risks involved and should be approved by a specialist before handling this product. Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being preformed and the risks involved and should be approved by a
specialist before handling this product. Respiratory protection Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Section 9. Physical and Chemical Properties
Appearance Physical state Solid Color Black/white backing Odor Asphaltic(slight) Odor threshold Not available pH Not applicable Melting point Not available Boiling point Not applicable Flash Point Not determined Evaporation rate: Not applicable Flammability (solid, gas) Not applicable Lower & upper explosive
(flammable) limits
Not applicable
Vapor density Not applicable Vapor pressure Not applicable Relative density 1.09 Solubility Insoluble in water Partition coefficient: n- octanol/water Not available Auto- ignition temperature Not applicable Decomposition temperature Not applicable Viscosity Not applicable VOC 0 g/l

650 Sheet Membrane

Polyguard Products, Inc. Tel: [phone] www.polyguardproducts.com 5/7

Section 10. Stability and Reactivity
Reactivity No specific test data related to reactivity available for this product or its
ingredients. Chemical stability This product is stable. Possibility of hazardous reactions Under normal conditions of storage and use, hazardous reaction will not occur. Conditions to avoid: No specific data. Incompatible materials Reactive or incompatible with the following materials: Oxidizing
materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition
products should not be produced. Section 11. Toxicological Information
Information on toxicological effects Acute toxicity
Product/ingredient name Result Species Dose Exposure
Asphalt LD50 Oral Rat >5000 mg/kg -
Hydrogen Sulfide LC50 Inhalation Gas Rat 444 ppm 4 hours LC50 Inhalation Vapor Rat 700 mg/m3 4 hours Limestone LD50 Oral Rat 6450 mg/kg - Crystalline Silica, quartz (inpurity) LD50 Oral Rat Mouse 500 mg/kg -
Irritation/Corrosion There is no data available Sensitization There is no data available Mutagenicity There is no data available Carcinogenicity Classification Product/ingredient name OSHA IARC NTP
Asphalt - 2B -
Crystalline Silica, quartz (inpurity) - 1 - Reproductive toxicity There is no data available Teratogenicity There is no data available Specific target organ toxicity (single exposure) There is no data available Specific target organ toxicity (repeated exposure) There is no data available Aspiration hazard There is no data available Information on the likely routes of exposure Routes of entry anticipated: dermal contact Routes of entry not anticipated: Oral, inhalation, ingestion Potential acute health effects Eye contact No known significant effects or critical hazards Inhalation No known significant effects or critical hazards Skin contact No known significant effects or critical hazards Ingestion No known significant effects or critical hazards Symptoms related to the physical, chemical and toxicological characteristics Eye contact No known significant effects or critical hazards Inhalation No known significant effects or critical hazards Skin contact No known significant effects or critical hazards Ingestion No known significant effects or critical hazards
650 Sheet Membrane

Polyguard Products, Inc. Tel: [phone] www.polyguardproducts.com 6/7

Section 11. Toxicological Information
Delayed and immediate effects and chronic effects from short- and long-term exposure Short term exposure Potential immediate effects No known significant effects or critical hazards Potential delayed effects No known significant effects or critical hazards Long term exposure Potential immediate effects No known significant effects or critical hazards Potential delayed effects No known significant effects or critical hazards Potential chronic health effects General No known significant effects or critical hazards Carcinogenicity No known significant effects or critical hazards Mutagenicity No known significant effects or critical hazards
Teratogenicity No known significant effects or critical hazards Developmental effects No known significant effects or critical hazards Fertility effects No known significant effects or critical hazards Numerical measures of toxicity Acute toxicity estimates There is no data available Section 12. Ecological Information
Toxicity
Product/ingredient name Result Species Exposure
Hydrogen Sulfide Acute EC50 62 g/L Fresh water Crustaceans-Gammarus pseudolimnaeus 2 days
Acute LC50 2 g/L Fresh water Fish- Coregonus clupeaformis- Yolk Sac fry 96 hours
Persistence and degradability There is no data available Bioaccumulative potential There is no data available Mobility in soil Soil/water partition coefficient (KOC) There is no data available.
Other adverse effects No known significant effects or critical hazards Section 13. Disposal Considerations
Disposal methods The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Section 14. Transportation Information
AERG: Not applicable Regulatory Information:
DOT/TDG/IMDG/IATA Not regulated
650 Sheet Membrane

Polyguard Products, Inc. Tel: [phone] www.polyguardproducts.com 7/7

Section 15. Regulatory Information
U.S. Federal regulations: TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8 b): all components are listed or exempted Clean Air Act Section 112 (b) Hazardous air pollutants (HAPs)
Not listed
Clean Air Act (CAA) Section 602 Class I Substances Not listed
Clean Air Act (CAA) Section 602 Class II Substances Not listed
DEA List I Chemicals ( Precursor chemicals) Not listed
DEA List II Chemicals (Essential Chemicals) Not listed
SARA 302/304 Composition/information on ingredients SARA 304 RQ Not applicable SARA 311/312 Not applicable SARA 313 Not applicable State regulations Massachusetts The following components are listed: Petroleum asphalt New Jersey The following components are listed: Petroleum asphalt New York None of the components are listed Pennsylvania The following components are listed: Petroleum asphalt California Prop.65 None of the components are listed on the Prob 65 list dated 1-3-2020.

16. Other Information
Date of revision 3-20-2020 Date of previous issue 12-17-2014 Revisions Change Mfg. Address to 4101 S. I-45. Change phone number to 214-515-5000 from 800 number. Update product composition information Version 5 Prepared by C. Rogalski Notice to reader: To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Isopropyl Alcohol
Not available.
Liquid.
[phone]
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :THE SHERWIN-WILLIAMS COMPANY
101 Prospect Avenue N.W.
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
R6K20
R6K20Product code :
Product Information
Telephone Number
:Not available.
Regulatory Information
Telephone Number
:[phone]
Transportation Emergency
Telephone Number
:[phone]
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation and Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Classification of the
substance or mixture
:
Signal word :Danger
Hazard pictograms :
Precautionary statements
GHS label elements
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Highly flammable liquid and vapor.
Causes serious eye irritation.
May cause respiratory irritation.
May cause drowsiness and dizziness.
May cause damage to organs through prolonged or repeated exposure.
:Hazard statements
Date of issue/Date of revision :3/13/2015.Date of previous issue :No previous validation.Version :1 1/11
Section 2. Hazards identification
Prevention :Wear protective gloves. Wear eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-
proof electrical, ventilating, lighting and all material-handling equipment. Use only non-
sparking tools. Take precautionary measures against static discharge. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor.
Wash hands thoroughly after handling.
Response :Get medical attention if you feel unwell. IF INHALED: Remove victim to fresh air and
keep at rest in a position comfortable for breathing. Call a POISON CENTER or
physician if you feel unwell. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water or shower. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical attention.
Storage :Store locked up. Store in a well-ventilated place. Keep cool.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Please refer to the SDS for additional information. Do not transfer contents to other
containers for storage.
Supplemental label
elements
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. FOR
INDUSTRIAL USE ONLY.
Section 3. Composition/information on ingredients
2-Propanol 100.0 67-63-0
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Substance
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Inhalation :
:
Description of necessary first aid measures
Date of issue/Date of revision :3/13/2015.Date of previous issue :No previous validation.Version :1 2/11
Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. If necessary,
call a poison center or physician. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt
or waistband.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention following
exposure or if feeling unwell. Wash clothing before reuse. Clean shoes thoroughly
before reuse.
Skin contact
Ingestion :
:
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness. May cause respiratory irritation.
Can cause central nervous system (CNS) depression. Irritating to mouth, throat and
stomach.
:Ingestion
Skin contact :No known significant effects or critical hazards.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
No specific data.
No specific data.
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Date of issue/Date of revision :3/13/2015.Date of previous issue :No previous validation.Version :1 3/11
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur
and the container may burst, with the risk of a subsequent explosion. The vapor/gas is
heavier than air and will spread along the ground. Vapors may accumulate in low or
confined areas or travel a considerable distance to a source of ignition and flash back.
Runoff to sewer may create fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO₂, water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialised clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Date of issue/Date of revision :3/13/2015.Date of previous issue :No previous validation.Version :1 4/11
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Do not breathe
vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
:
Precautions for safe handling
2-Propanol ACGIH TLV (United States, 4/2014).
TWA: 200 ppm 8 hours.
STEL: 400 ppm 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 400 ppm 10 hours.
TWA: 980 mg/m³ 10 hours.
STEL: 500 ppm 15 minutes.
STEL: 1225 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 400 ppm 8 hours.
TWA: 980 mg/m³ 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Control parameters
Individual protection measures
Occupational exposure limits
Date of issue/Date of revision :3/13/2015.Date of previous issue :No previous validation.Version :1 5/11
Section 8. Exposure controls/personal protection
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
0.78
2.07 [Air = 1]
0.59 kPa (4.399 mm Hg) [at 20°C]
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate 1.44 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: 12°C (53.6°F) [Pensky-Martens Closed Cup]
Not available.
Not available.
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :81°C (177.8°F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Lower: 2%
Upper: 12.7%
Decomposition temperature :Not available.
Date of issue/Date of revision :3/13/2015.Date of previous issue :No previous validation.Version :1 6/11
Section 9. Physical and chemical properties
Viscosity Kinematic (room temperature): >0.07 cm2/s (>7 cSt)
Kinematic (40°C (104°F)): >0.07 cm2/s (>7 cSt)
:
Heat of combustion :0.0000274 kJ/g
Aerosol product
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
2-Propanol LD50 Dermal Rabbit 12800 mg/kg -
LD50 Oral Rat 5000 mg/kg -
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Reproductive toxicity
Irritation/Corrosion
2-Propanol Eyes - Moderate irritant Rabbit -24 hours 100
milligrams
-
Eyes - Moderate irritant Rabbit -10 milligrams -
Eyes - Severe irritant Rabbit -100
milligrams
-
Skin - Mild irritant Rabbit -500
milligrams
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
Classification
2-Propanol -3 -
Product/ingredient name NTPIARCOSHA
Date of issue/Date of revision :3/13/2015.Date of previous issue :No previous validation.Version :1 7/11
Section 11. Toxicological information
Teratogenicity
Not available.
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
2-Propanol Category 3 Not applicable.Respiratory tract
irritation and
Narcotic effects
Name Category
Name Category
2-Propanol Category 2 Not determined Not determined
Aspiration hazard
Not available.
Route of
exposure
Target organs
Route of
exposure
Target organs
Information on the likely
routes of exposure
Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness. May cause respiratory irritation.
Can cause central nervous system (CNS) depression. Irritating to mouth, throat and
stomach.
:Ingestion
Skin contact :No known significant effects or critical hazards.
Causes serious eye irritation.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
No specific data.
No specific data.
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Delayed and immediate effects and also chronic effects from short and long term exposure
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects :Not available.
Long term exposure
Date of issue/Date of revision :3/13/2015.Date of previous issue :No previous validation.Version :1 8/11
Not available.
May cause damage to organs through prolonged or repeated exposure.General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Potential chronic health effects
Numerical measures of toxicity
Oral 5000 mg/kg
Route ATE value
Acute toxicity estimates
Potential immediate
effects
:Not available.
Potential delayed effects :Not available.
Section 12. Ecological information
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Not available.
Product/ingredient name Aquatic half-life Photolysis Biodegradability
2-Propanol --Readily
Toxicity
2-Propanol Acute LC50 1400000 µg/l Marine water Crustaceans - Crangon crangon 48 hours
Acute LC50 4200 mg/l Fresh water Fish - Rasbora heteromorpha 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
:Disposal methods
Date of issue/Date of revision :3/13/2015.Date of previous issue :No previous validation.Version :1 9/11
Section 13. Disposal considerations
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
Section 14. Transport information
Isopropanol or
Isopropyl alcohol
3
II
Isopropanol or
Isopropyl alcohol
3
II
UN1219 UN1219
Special
provisions
Not Applicable
Emergency
schedules (EmS)
F-E, S-D
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL
73/78 and the IBC Code
No.No.
:Not available.
:
TDG
Classification
UN1219
Isopropanol or
Isopropyl alcohol
3
II
No.
Special
provisions
Not Applicable
Mexico
Classification
UN1219
Isopropanol or
Isopropyl alcohol
3
II
No.
Special
provisions
(ERG#129)
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
IATA
UN1219
Isopropanol or
Isopropyl alcohol
3
II
No.
Special
provisions
Not Applicable
Section 15. Regulatory information
U.S. Federal regulations :
State regulations
Section 16. Other information
Hazardous Material Information System (U.S.A.)
2
3
0
Health
Flammability
Physical hazards
Date of issue/Date of revision :3/13/2015.Date of previous issue :No previous validation.Version :1 10/11
Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Regulatory requirements are subject to change and may differ between various
locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all
country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of
the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use
of this product. The customer/buyer/user should not use the product for any purpose other than the purpose
shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling
instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the
manufacturer cannot be responsible for SDSs obtained from any other source.
Notice to reader
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller [phone].
The customer is responsible for determining the PPE code for this material.
Date of issue/Date of revision :3/13/2015.Date of previous issue :No previous validation.Version :1 11/11
MATERIAL SAFETY DATA SHEET
Gasoline, All Grades MSDS No. 9950

Revision Date: 09/25/2007 Page 1 of 9
NFPA 704 (Section 16)
EMERGENCY OVERVIEW DANGER! EXTREMELY FLAMMABLE - EYE AND MUCOUS MEMBRANE IRRITANT - EFFECTS CENTRAL NERVOUS SYSTEM - HARMFUL OR FATAL IF SWALLOWED - ASPIRATION HAZARD
High fire hazard. Keep away from heat, spark, open flame, and other ignition sources.
If ingested, do NOT induce vomiting, as this may cause chemical pneumonia (fluid in the lungs). Contact may cause eye, skin and mucous membrane irritation. Harmful if absorbed through the skin. Avoid
prolonged breathing of vapors or mists. Inhalation may cause irritation, anesthetic effects (dizziness, nausea, headache, intoxication), and respiratory system effects.
Long-term exposure may cause effects to specific organs, such as to the liver, kidneys, blood, nervous system, and skin. Contains benzene, which can cause blood disease, including anemia and leukemia.

1. CHEMICAL PRODUCT and COMPANY INFORMATION
Hess Corporation 1 Hess Plaza Woodbridge, NJ 07095-0961
EMERGENCY TELEPHONE NUMBER (24 hrs): CHEMTREC [phone] COMPANY CONTACT (business hours): Corporate Safety [phone] MSDS (Environment, Health, Safety) Internet Website www.hess.com
SYNONYMS: Hess Conventional (Oxygenated and Non-oxygenated) Gasoline; Reformulated Gasoline (RFG); Reformulated Gasoline Blendstock for Oxygenate Blending (RBOB); Unleaded Motor or Automotive Gasoline
See Section 16 for abbreviations and acronyms.
2. COMPOSITION and INFORMATION ON INGREDIENTS *
INGREDIENT NAME (CAS No.) CONCENTRATION PERCENT BY WEIGHT
Gasoline (86290-81-5) 100 Benzene (71-43-2) 0.1 - 4.9 (0.1 - 1.3 reformulated gasoline) n-Butane (106-97-8) < 10 Ethyl Alcohol (Ethanol) (64-17-5) 0 - 10 Ethyl benzene (100-41-4) < 3 n-Hexane (110-54-3) 0.5 to 4 Methyl-tertiary butyl ether (MTBE) (1634-04-4) 0 to 15.0 Tertiary-amyl methyl ether (TAME) (994-05-8) 0 to 17.2 Toluene (108-88-3) 1 - 25 1,2,4- Trimethylbenzene (95-63-6) < 6 Xylene, mixed isomers (1330-20-7) 1 - 15 A complex blend of petroleum-derived normal and branched-chain alkane, cycloalkane, alkene, and aromatic hydrocarbons. May contain antioxidant and multifunctional additives. Non-oxygenated Conventional Gasoline and RBOB do not have oxygenates (Ethanol or MTBE and/or TAME).
MATERIAL SAFETY DATA SHEET
Gasoline, All Grades MSDS No. 9950

Revision Date: 09/25/2007 Page 2 of 9
Oxygenated Conventional and Reformulated Gasoline will have oxygenates for octane enhancement or as legally required.

3. HAZARDS IDENTIFICATION
EYES Moderate irritant. Contact with liquid or vapor may cause irritation.
SKIN Practically non-toxic if absorbed following acute (single) exposure. May cause skin irritation with prolonged or repeated contact. Liquid may be absorbed through the skin in toxic amounts if large areas of skin are exposed repeatedly.
INGESTION The major health threat of ingestion occurs from the danger of aspiration (breathing) of liquid drops into the lungs, particularly from vomiting. Aspiration may result in chemical pneumonia (fluid in the lungs), severe lung damage, respiratory failure and even death.
Ingestion may cause gastrointestinal disturbances, including irritation, nausea, vomiting and diarrhea, and central nervous system (brain) effects similar to alcohol intoxication. In severe cases, tremors, convulsions, loss of consciousness, coma, respiratory arrest, and death may occur.
INHALATION Excessive exposure may cause irritations to the nose, throat, lungs and respiratory tract. Central nervous system (brain) effects may include headache, dizziness, loss of balance and coordination, unconsciousness, coma, respiratory failure, and death.
WARNING: the burning of any hydrocarbon as a fuel in an area without adequate ventilation may result in hazardous levels of combustion products, including carbon monoxide, and inadequate oxygen levels,
which may cause unconsciousness, suffocation, and death.
CHRONIC EFFECTS and CARCINOGENICITY Contains benzene, a regulated human carcinogen. Benzene has the potential to cause anemia and other blood diseases, including leukemia, after repeated and prolonged exposure. Exposure to light hydrocarbons in the same boiling range as this product has been associated in animal studies with systemic toxicity. See also Section 11 - Toxicological Information.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Irritation from skin exposure may aggravate existing open wounds, skin disorders, and dermatitis (rash). Chronic respiratory disease, liver or kidney dysfunction, or pre-existing central nervous system disorders
may be aggravated by exposure.
4. FIRST AID MEASURES EYES In case of contact with eyes, immediately flush with clean, low-pressure water for at least 15 min. Hold
eyelids open to ensure adequate flushing. Seek medical attention.
SKIN Remove contaminated clothing. Wash contaminated areas thoroughly with soap and water or waterless hand cleanser. Obtain medical attention if irritation or redness develops.
INGESTION
MATERIAL SAFETY DATA SHEET
Gasoline, All Grades MSDS No. 9950

Revision Date: 09/25/2007 Page 3 of 9
DO NOT INDUCE VOMITING. Do not give liquids. Obtain immediate medical attention. If spontaneous vomiting occurs, lean victim forward to reduce the risk of aspiration. Small amounts of material which enter the mouth should be rinsed out until the taste is dissipated.
INHALATION Remove person to fresh air. If person is not breathing, ensure an open airway and provide artificial respiration. If necessary, provide additional oxygen once breathing is restored if trained to do so. Seek medical attention immediately.

5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES: FLASH POINT: -45 oF (-43oC) AUTOIGNITION TEMPERATURE: highly variable; > 530 oF (>280 oC) OSHA/NFPA FLAMMABILITY CLASS: 1A (flammable liquid) LOWER EXPLOSIVE LIMIT (%): 1.4%
UPPER EXPLOSIVE LIMIT (%): 7.6%
FIRE AND EXPLOSION HAZARDS Vapors may be ignited rapidly when exposed to heat, spark, open flame or other source of ignition. Flowing product may be ignited by self-generated static electricity. When mixed with air and exposed to an ignition source, flammable vapors can burn in the open or explode in confined spaces. Being heavier than air, vapors may travel long distances to an ignition source and flash back. Runoff to sewer may cause fire or explosion hazard.
EXTINGUISHING MEDIA SMALL FIRES: Any extinguisher suitable for Class B fires, dry chemical, CO2, water spray, fire fighting
foam, or Halon.
LARGE FIRES: Water spray, fog or fire fighting foam. Water may be ineffective for fighting the fire, but may be used to cool fire-exposed containers.
During certain times of the year and/or in certain geographical locations, gasoline may contain MTBE and/or TAME. Firefighting foam suitable for polar solvents is recommended for fuel with greater than 10% oxygenate concentration - refer to NFPA 11 “Low Expansion Foam - 1994 Edition.”
FIRE FIGHTING INSTRUCTIONS Small fires in the incipient (beginning) stage may typically be extinguished using handheld portable fire extinguishers and other fire fighting equipment.
Firefighting activities that may result in potential exposure to high heat, smoke or toxic by-products of combustion should require NIOSH/MSHA- approved pressure-demand self-contained breathing apparatus with full facepiece and full protective clothing.
Isolate area around container involved in fire. Cool tanks, shells, and containers exposed to fire and
excessive heat with water. For massive fires the use of unmanned hose holders or monitor nozzles may be advantageous to further minimize personnel exposure. Major fires may require withdrawal, allowing
the tank to burn. Large storage tank fires typically require specially trained personnel and equipment to extinguish the fire, often including the need for properly applied fire fighting foam.
See Section 16 for the NFPA 704 Hazard Rating.
MATERIAL SAFETY DATA SHEET
Gasoline, All Grades MSDS No. 9950

Revision Date: 09/25/2007 Page 4 of 9

6. ACCIDENTAL RELEASE MEASURES
ACTIVATE FACILITY SPILL CONTINGENCY or EMERGENCY PLAN.
Evacuate nonessential personnel and remove or secure all ignition sources. Consider wind direction; stay upwind and uphill, if possible. Evaluate the direction of product travel, diking, sewers, etc. to confirm spill areas. Spills may infiltrate subsurface soil and groundwater; professional assistance may be necessary to determine the extent of subsurface impact.
Carefully contain and stop the source of the spill, if safe to do so. Protect bodies of water by diking, absorbents, or absorbent boom, if possible. Do not flush down sewer or drainage systems, unless
system is designed and permitted to handle such material. The use of fire fighting foam may be useful in certain situations to reduce vapors. The proper use of water spray may effectively disperse product vapors or the liquid itself, preventing contact with ignition sources or areas/equipment that require protection.
Take up with sand or other oil absorbing materials. Carefully shovel, scoop or sweep up into a waste container for reclamation or disposal - caution, flammable vapors may accumulate in closed containers. Response and clean-up crews must be properly trained and must utilize proper protective equipment (see Section 8).
7. HANDLING and STORAGE
HANDLING PRECAUTIONS ******USE ONLY AS A MOTOR FUEL****** ******DO NOT SIPHON BY MOUTH****** Handle as a flammable liquid. Keep away from heat, sparks, and open flame! Electrical equipment should be approved for classified area. Bond and ground containers during product transfer to reduce the possibility of static-initiated fire or explosion.
Special slow load procedures for "switch loading" must be followed to avoid the static ignition hazard that can exist when higher flash point material (such as fuel oil) is loaded into tanks previously containing low flash point products (such as this product) - see API Publication 2003, "Protection Against Ignitions Arising Out Of Static, Lightning and Stray Currents.
STORAGE PRECAUTIONS Keep away from flame, sparks, excessive temperatures and open flame. Use approved vented
containers. Keep containers closed and clearly labeled. Empty product containers or vessels may contain explosive vapors. Do not pressurize, cut, heat, weld or expose such containers to sources of ignition.
Store in a well-ventilated area. This storage area should comply with NFPA 30 "Flammable and Combustible Liquid Code". Avoid storage near incompatible materials. The cleaning of tanks previously containing this product should follow API Recommended Practice (RP) 2013 "Cleaning Mobile Tanks In Flammable and Combustible Liquid Service" and API RP 2015 "Cleaning Petroleum Storage Tanks".
WORK/HYGIENIC PRACTICES Emergency eye wash capability should be available in the near proximity to operations presenting a potential splash exposure. Use good personal hygiene practices. Avoid repeated and/or prolonged skin exposure. Wash hands before eating, drinking, smoking, or using toilet facilities. Do not use as a cleaning solvent on the skin. Do not use solvents or harsh abrasive skin cleaners for washing this product from exposed skin areas. Waterless hand cleaners are effective. Promptly remove contaminated clothing and launder before reuse. Use care when laundering to prevent the formation of flammable
vapors which could ignite via washer or dryer. Consider the need to discard contaminated leather shoes and gloves.
MATERIAL SAFETY DATA SHEET
Gasoline, All Grades MSDS No. 9950

Revision Date: 09/25/2007 Page 5 of 9

8. EXPOSURE CONTROLS and PERSONAL PROTECTION
EXPOSURE LIMITS Component (CAS No.) Exposure Limits Source TWA (ppm) STEL (ppm) Note
Gasoline (86290-81-5) ACGIH 300 500 A3 Benzene (71-43-2) OSHA ACGIH USCG
1 0.5 1
5 2.5 5
Carcinogen A1, skin n-Butane (106-97-8) ACGIH 1000 -- Aliphatic Hydrocarbon Gases Alkane (C1-C4) Ethyl Alcohol (ethanol) (64-17-5) OSHA ACGIH 1000 1000 -- -- A4
Ethyl benzene (100-41-4) OSHA ACGIH 100 100 -- 125 A3
n-Hexane (110-54-3) OSHA ACGIH 500 50 -- -- Skin Methyl-tertiary butyl ether [MTBE] (1634-04-4) ACGIH 50 A3 Tertiary-amyl methyl ether [TAME] (994-05-8) None established
Toluene (108-88-3) OSHA ACGIH 200 20 -- Ceiling: 300 ppm; Peak: 500 ppm (10 min.) A4
1,2,4- Trimethylbenzene (95-63-6) ACGIH 25 -- Xylene, mixed isomers (1330-20-7) OSHA ACGIH 100 100 -- 150 A4 ENGINEERING CONTROLS Use adequate ventilation to keep vapor concentrations of this product below occupational exposure and flammability limits, particularly in confined spaces.
EYE/FACE PROTECTION
Safety glasses or goggles are recommended where there is a possibility of splashing or spraying.
SKIN PROTECTION Gloves constructed of nitrile or neoprene are recommended. Chemical protective clothing such as that made of of E.I. DuPont Tychem ®, products or equivalent is recommended based on degree of exposure.
Note: The resistance of specific material may vary from product to product as well as with degree of exposure. Consult manufacturer specifications for further information.
RESPIRATORY PROTECTION
A NIOSH-approved air-purifying respirator with organic vapor cartridges or canister may be permissible under certain circumstances where airborne concentrations are or may be expected to exceed exposure
limits or for odor or irritation. Protection provided by air-purifying respirators is limited. Refer to OSHA 29 CFR 1910.134, NIOSH Respirator Decision Logic, and the manufacturer for additional guidance on respiratory protection selection and limitations.
Use a positive pressure, air-supplied respirator if there is a potential for uncontrolled release, exposure levels are not known, in oxygen-deficient atmospheres, or any other circumstance where an air-purifying respirator may not provide adequate protection.
9. PHYSICAL and CHEMICAL PROPERTIES
APPEARANCE A translucent, straw-colored or light yellow liquid
MATERIAL SAFETY DATA SHEET
Gasoline, All Grades MSDS No. 9950

Revision Date: 09/25/2007 Page 6 of 9
ODOR A strong, characteristic aromatic hydrocarbon odor. Oxygenated gasoline with MTBE and/or TAME may have a sweet, ether-like odor and is detectable at a lower concentration than non-oxygenated gasoline.
ODOR THRESHOLD Odor Detection Odor Recognition Non-oxygenated gasoline: 0.5 - 0.6 ppm 0.8 - 1.1 ppm Gasoline with 15% MTBE: 0.2 - 0.3 ppm 0.4 - 0.7 ppm Gasoline with 15% TAME: 0.1 ppm 0.2 ppm
BASIC PHYSICAL PROPERTIES BOILING RANGE: 85 to 437 oF (39 to 200 oC) VAPOR PRESSURE: 6.4 - 15 RVP @ 100 oF (38 oC) (275-475 mm Hg @ 68 oF (20 oC) VAPOR DENSITY (air = 1): AP 3 to 4 SPECIFIC GRAVITY (H2O = 1): 0.70 – 0.78 EVAPORATION RATE: 10-11 (n-butyl acetate = 1) PERCENT VOLATILES: 100 % SOLUBILITY (H2O): Non-oxygenated gasoline - negligible (< 0.1% @ 77 oF). Gasoline with 15% MTBE - slight (0.1 - 3% @ 77 oF); ethanol is readily soluble in water
10. STABILITY and REACTIVITY )
STABILITY: Stable. Hazardous polymerization will not occur.
CONDITIONS TO AVOID Avoid high temperatures, open flames, sparks, welding, smoking and other ignition sources
INCOMPATIBLE MATERIALS
Keep away from strong oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS Carbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke). Contact with nitric and sulfuric acids will form nitrocresols that can decompose violently.
11. TOXICOLOGICAL PROPERTIES
ACUTE TOXICITY Acute Dermal LD50 (rabbits): > 5 ml/kg Acute Oral LD50 (rat): 18.75 ml/kg Primary dermal irritation (rabbits): slightly irritating Draize eye irritation (rabbits): non-irritating Guinea pig sensitization: negative
CHRONIC EFFECTS AND CARCINOGENICITY Carcinogenicity: OSHA: NO IARC: YES - 2B NTP: NO ACGIH: YES (A3)
IARC has determined that gasoline and gasoline exhaust are possibly carcinogenic in humans. Inhalation exposure to completely vaporized unleaded gasoline caused kidney cancers in male rats and liver tumors
in female mice. The U.S. EPA has determined that the male kidney tumors are species-specific and are irrelevant for human health risk assessment. The significance of the tumors seen in female mice is not known. Exposure to light hydrocarbons in the same boiling range as this product has been associated in animal studies with effects to the central and peripheral nervous systems, liver, and kidneys. The significance of these animal models to predict similar human response to gasoline is uncertain.
This product contains benzene. Human health studies indicate that prolonged and/or repeated overexposure to benzene may cause damage to the blood-forming system (particularly bone marrow), and serious blood disorders such as aplastic anemia and leukemia. Benzene is listed as a human carcinogen by the NTP, IARC, OSHA and ACGIH.
MATERIAL SAFETY DATA SHEET
Gasoline, All Grades MSDS No. 9950

Revision Date: 09/25/2007 Page 7 of 9
This product may contain methyl tertiary butyl ether (MTBE ): animal and human health effects studies indicate that MTBE may cause eye, skin, and respiratory tract irritation, central nervous system depression and neurotoxicity. MTBE is classified as an animal carcinogen (A3) by the ACGIH.
12. ECOLOGICAL INFORMATION
Keep out of sewers, drainage areas and waterways. Report spills and releases, as applicable, under Federal and State regulations. If released, oxygenates such as ethers and alcohols will be expected to exhibit fairly high mobility in soil, and therefore may leach into groundwater. The API (www.api.org)
provides a number of useful references addressing petroleum and oxygenate contamination of groundwater.
13. DISPOSAL CONSIDERATIONS
Consult federal, state and local waste regulations to determine appropriate disposal options.

14. TRANSPORTATION INFORMATION

DOT PROPER SHIPPING NAME: Gasoline
DOT HAZARD CLASS and PACKING GROUP: 3, PG II
DOT IDENTIFICATION NUMBER: UN 1203 DOT SHIPPING LABEL:
FLAMMABLE LIQUID
PLACARD:

15. REGULATORY INFORMATION U.S. FEDERAL, STATE, and LOCAL REGULATORY INFORMATION This product and its constituents listed herein are on the EPA TSCA Inventory. Any spill or uncontrolled
release of this product, including any substantial threat of release, may be subject to federal, state and/or local reporting requirements. This product and/or its constituents may also be subject to other federal, state, or local regulations; consult those regulations applicable to your facility/operation.
CLEAN WATER ACT (OIL SPILLS) Any spill or release of this product to "navigable waters" (essentially any surface water, including certain wetlands) or adjoining shorelines sufficient to cause a visible sheen or deposit of a sludge or emulsion must be reported immediately to the National Response Center (1-800-424-8802) as required by U.S. Federal Law. Also contact appropriate state and local regulatory agencies as required.
CERCLA SECTION 103 and SARA SECTION 304 (RELEASE TO THE ENVIRONMENT) The CERCLA definition of hazardous substances contains a “petroleum exclusion” clause which exempts crude oil, refined, and unrefined petroleum products and any indigenous components of such. However, other federal reporting requirements (e.g., SARA Section 304 as well as the Clean Water Act if the spill occurs on navigable waters) may still apply.
SARA SECTION 311/312 - HAZARD CLASSES
ACUTE HEALTH CHRONIC HEALTH FIRE SUDDEN RELEASE OF PRESSURE REACTIVE X X X -- --
SARA SECTION 313 - SUPPLIER NOTIFICATION This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372:
INGREDIENT NAME (CAS NUMBER) CONCENTRATION WT. PERCENT
Benzene (71-43-2) 0.1 to 4.9 (0.1 to 1.3 for reformulated gasoline)
Ethyl benzene (100-41-4) < 3
MATERIAL SAFETY DATA SHEET
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Revision Date: 09/25/2007 Page 8 of 9
n-Hexane (110-54-3) 0.5 to 4
Methyl-tertiary butyl ether (MTBE) (1634-04-4) 0 to 15.0
Toluene (108-88-3) 1 to 15
1,2,4- Trimethylbenzene (95-63-6) < 6
Xylene, mixed isomers (1330-20-7) 1 to 15
US EPA guidance documents (www.epa.gov/tri) for reporting Persistent Bioaccumulating Toxics (PBTs) indicate this product may contain the following deminimis levels of toxic chemicals subject to Section 313 reporting:
INGREDIENT NAME (CAS NUMBER) CONCENTRATION - Parts per million (ppm) by weight Polycyclic aromatic compounds (PACs) Benzo (g,h,i) perylene (191-24-2) Lead (7439-92-1)
17 2.55 0.079
CALIFORNIA PROPOSITION 65 LIST OF CHEMICALS This product contains the following chemicals that are included on the Proposition 65 “List of Chemicals” required by the California Safe Drinking Water and Toxic Enforcement Act of 1986: INGREDIENT NAME (CAS NUMBER) Date Listed Benzene 2/27/1987 Ethyl benzene 6/11/2004 Toluene 1/1/1991 CANADIAN REGULATORY INFORMATION (WHMIS) Class B, Division 2 (Flammable Liquid) Class D, Division 2A (Very toxic by other means) and Class D, Division 2B (Toxic by other means)
16. OTHER INFORMATION
NFPA® HAZARD RATING HEALTH: 1 Slight
FIRE: 3 Serious REACTIVITY: 0 Minimal
HMIS® HAZARD RATING HEALTH: 1 * Slight FIRE: 3 Serious PHYSICAL: 0 Minimal * CHRONIC
SUPERSEDES MSDS DATED: 07/01/06
ABBREVIATIONS: AP = Approximately < = Less than > = Greater than N/A = Not Applicable N/D = Not Determined ppm = parts per million
ACRONYMS: ACGIH American Conference of Governmental Industrial Hygienists AIHA American Industrial Hygiene Association ANSI American National Standards Institute
[phone] API American Petroleum Institute
[phone]
CERCLA Comprehensive Emergency Response, Compensation, and Liability Act
DOT U.S. Department of Transportation [General Info: [phone]]
EPA U.S. Environmental Protection Agency HMIS Hazardous Materials Information System
MATERIAL SAFETY DATA SHEET Gasoline, All Grades MSDS No. 9950

Revision Date: 09/25/2007 Page 9 of 9
IARC International Agency For Research On Cancer
MSHA Mine Safety and Health Administration NFPA National Fire Protection Association [phone] NIOSH National Institute of Occupational Safety and Health NOIC Notice of Intended Change (proposed change to ACGIH TLV) NTP National Toxicology Program OPA Oil Pollution Act of 1990 OSHA U.S. Occupational Safety & Health Administration PEL Permissible Exposure Limit (OSHA) RCRA Resource Conservation and Recovery Act
REL Recommended Exposure Limit (NIOSH) SARA Superfund Amendments and Reauthorization Act of 1986 Title III SCBA Self-Contained Breathing Apparatus SPCC Spill Prevention, Control, and Countermeasures STEL Short-Term Exposure Limit (generally 15 minutes) TLV Threshold Limit Value (ACGIH) TSCA Toxic Substances Control Act TWA Time Weighted Average (8 hr.) WEEL Workplace Environmental Exposure Level (AIHA) WHMIS Workplace Hazardous Materials Information System (Canada)
DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES
Information presented herein has been compiled from sources considered to be dependable, and is accurate and reliable to the best of our knowledge and belief, but is not guaranteed to be so. Since conditions of use are beyond our control, we make no warranties, expressed or implied, except those that may be contained in our written contract of sale or acknowledgment.
Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, vendor assumes no responsibility for injury to vendee or third persons proximately caused by abnormal use of the material, even if reasonable safety procedures are followed. Furthermore, vendee assumes the risk in their use of the material.
Address:
HMIS
|1|
|1|
|0|
| |
% by SARA LEL
CAS Number Weight 313 (@25°C)
8052-42-4 35-40 No N/A
1302-78-9 10-15 No N/E
PEL PEL/CEILING PEL/STEL SKIN TLV TLV/STEL SKIN
5 mg/m3*N/E N/E No 0.5 mg/m3*N/E N/E
2. Clay 15 mg/m3+N/E N/E No 10 mg/m3+N/E N/E
spontaneously occurs, prevent lung aspiration. Seek immediate medical attention.
INHALATION: Not expected to be an exposure route as supplied. If respiratory symptoms develop, seek medical attention.
INGESTION: Dilute with liquid unless the victim is unconscious or very drowsy. Do not induce vomiting. If vomiting
SECTION 5: FIRE AND EXPLOSIVES HAZARDS
N/E
SECTION 6: ACCIDENTAL RELEASE MEASURES
CHEMICAL/COMBUSTION HAZARDS: Oxides and compounds of nitrogen/sulfur, carbon monoxide/dioxide, and incomplete
PRECAUTIONS/PERSONAL PROTECTIVE EQUIPMENT: Avoid smoke inhalation. Use appropriate personal protective equipment.
PERSONAL PROTECTIVE EQUIPMENT: Safety glasses, chemical-resistant gloves.
ENGINEERING CONTROLS: None required under normal use conditions.
SPILL OR LEAK PROCEDURES: Avoid direct contact. Dike and contain spilled material. Remove source of spill if safe to do so.
Apply absorbent and place clean-up material in sealed/marked containers for proper disposal. Clean-up materials will be
SECTION 7: HANDLING AND STORAGE
classified as non-hazardous waste.
SAFE STORAGE: Prevent product from freezing.
Part Number: 6350055
In case of emergency, dial [phone] (CHEMTREC)
300 Industrial Drive
Hampshire, Illinois 60140
Page 1 of 2
SECTION 4: EMERGENCY AND FIRST AID PROCEDURES
Under the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1966
(SARA) and 40 CFR Part 372, chemicals listed on the 313 List (40 CFR Part 373.65) are identified under the heading "SARA 313."
SECTION 2: HAZARDS IDENTIFICATION/EXPOSURE LIMITS
SECTION 1: PRODUCT AND COMPANY IDENTIFICATIONProduct:
Manufacturer:
SEALMASTIC™ TYPES I, II, IIIW. R. MEADOWS, INC.
HAZARD STATEMENTS
WARNING!
SECTION 3: HAZARDS COMPONENTS
Chemical Name:
Telephone:[phone]
Revision Date:8/16/2022
PRECAUTIONARY STATEMENTS
Avoid direct contact.
Vapor Pressure
(mm Hg@20°C)
Product Use:Dampproofing Product
|Health|
|Flammability|
|Reactivity|
|Personal Protection|
Causes mild skin irritation. (Category 3)
SKIN CONTACT: Wash affected areas with mild soap and water.
EYE CONTACT: Flush eyes with water for fifteen (15) minutes. If symptoms persist, seek medical attention.
combustion products.
N/A
N/A
N/A = Not Applicable N/E = Not Established
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND CHRONIC: See Section Eleven for Symptoms/Effects.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Chemical Name:TLV/CEILING
*: Asphalt Fumes +: Total Dust, 5 mg/m3 Respirable Fraction N/E: Not Established
1. Petroleum Asphalt
FLASHPOINT: Product will not flash due to water content.
EXTINGUISHING MEDIA: Water fog, foam, dry chemical.
SAFE HANDLING PROCEDURES: Avoid direct contact.
SAFETY DATA SHEET
OSHA ACGIH
1. Petroleum Asphalt
2. Clay
N/E
N/E N/E N/E
N/E
N/A N/A
None.
PREPARED BY:Dave Carey
VAPOR DENSITY: N/A
EVAPORATION RATE: <1 (Ether=1)pH LEVEL: N/A
WEIGHT PER GALLON: 9.0
ODOR: None ODOR THRESHOLD: N/D
FLASH POINT: See Section 5 FLAMMABILITY: N/D
reduced lung function.
VAPOR PRESSURE: N/D RELATIVE DENSITY: N/D
CONDITIONS AND MATERIALS TO AVOID: None recognized.
HAZARDOUS DECOMPOSITION PRODUCTS: None recognized.
PARTITION COEFFICENT: N/D
VISCOSITY: N/D N/A = Not Applicable N/D: Not Determined
SECTION 10: STABILITY/REACTIVITY
STABILITY: Stable.HAZARDOUS POLYMERIZATION: Will not occur.
INHALATION: Not anticipated to be an exposure route.
SECTION 11: TOXICOLOGICAL INFORMATION
SIGNS AND SYMPTOMS: Symptoms of eye irritation include tearing, reddening, and swelling. Symptoms of skin irritation
Symptoms of respiratory irritation include runny nose, sore throat, coughing, chest discomfort, shortness of breath, and
INGESTION: Not anticipated to be an exposure route.
Date of Preparation: 8/16/22 Page 2 of 2 6350055
BOILING POINT: 212 °F
SAFETY DATA SHEET
EYE CONTACT: Direct contact may cause mild irritation.
SKIN CONTACT: Direct contact may cause slight skin irritation. Prolonged/repeated contact may result in irritation.
VOC CONTENT: 0 g/L
MELTING/FREEZING POINT: N/D
UEL/LEL: N/D
SOLUBILITY: N/D
DECOMPOSITION TEMPERATURE: N/D
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT APPEARANCE: Black Liquid
AUTOIGNITION TEMPERATURE: N/D
PREPARATION DATE:8/16/2022
from the use thereof. We assume no responsibility for injury from the use of this product described herein.
The information contained herein is based on the data available to us and is believed to be correct. However,we make no warranty, expressed or implied regarding the accuracy of this data or the results to be obtained
HAZARDOUS/NON-HAZARDOUS MATERIAL: Not regulated by DOT.
BULK TRANSPORTATION INFORMATION:
SPECIAL PRECAUTIONS:SECTION 15: REGULATORY INFORMATIONOTHER REGULATORY CONSIDERATIONS:SECTION 16: OTHER INFORMATION
ENVIRONMENTAL HAZARDS: None recognized.
None recognized.
HAZARD CLASS:
UN PROPER SHIPPING NAME: N/A
UN NUMBER: None.
Prevent product from freezing.N/A: Not Applicable
% VOLATILE BY VOLUME: N/A
% VOLATILE BY WEIGHT: 50
None Recognized
BIOACCUMULATIVE POTENTIAL:
N/E: Not Established
PACKING GROUP:
SECTION 13: WASTE DISPOSAL INFORMATION
AGGRAVATED MEDICAL CONDITIONS: Pre-existing skin, eye, and respiratory disorders may be aggravated by exposure to
OTHER HEALTH EFFECTS: ACGIH Classifies asphalt as Not Classifiable as a Human Carcinogen; A4.
WASTE DISPOSAL INFORMATION: Solidified product can be landfill disposed. No free liquids.
SECTION 14: TRANSPORTATION INFORMATION
SOIL MOBILITY:OTHER ADVERSE EFFECTS:
ECOTOXICITY:DEGRADABILITY:
SECTION 12: ECOLOGICAL INFORMATION
include redness and swelling. Gastrointestinal irritation symptoms include nausea, vomiting, and abdominal discomfort.
this product.