FA-7978_42215_CA_FPR_20230831

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
August 31, 2023

Ms. Liz Price
NCDEQ-UST Section
Wilmington Regional Office
127 Cardinal Drive Extension
Wilmington, NC 28405

Re: Free Product Recovery Report
August 2023
Jimmy’s Gas Mart
3300 Highway 70 Business
Clayton, Johnston County
North Carolina
Facility ID Number: 00-0-0000035374
Incident Number: 42215
GRI Project Number: 6373

Dear Ms. Price,

Please find enclosed the referenced report, for the abovementioned site.
If you have any questions, please contact Scott Driscoll at 704-845-4010.

Sincerely,
Geological Resources, Inc.

Leslie Maxtone-Graham
Administrative Assistant

Enclosure

Cc: Mr. Jamal A. Qudura, file

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Free Product Recovery Report
August 2023
Jimmy’s Gas Mart
3300 Highway 70 Business
Clayton, Johnston County
North Carolina
Facility ID Number: 00-0-0000035374
Incident Number: 42215
GRI Project Number: 6373

Prepared for:

Mr. Jamal A. Qudura
4117 Brewster Drive
Raleigh, NC 27606-1711

August 31, 2023

Scott Driscoll
Project Manager
William Regenthal, P.G.
Report Reviewer

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: August 31, 2023 Jimmy’s Gas Mart
Project Manager: Scott Driscoll GRI Project No. 6373
i
SITE INFORMATION
1. Site Identification
 Jimmy’s Gas Mart (Facility ID 00-0-0000035374)
 Incident Number 42215 – High Risk (H185A)
 Location of Source Area: 3300 Highway 70 Business
Clayton, NC 27942
Johnston County
35.5555572°N, 78.386676°W (Topographic Map)

2. Information about Contacts Associated with the Leaking UST System

UST Owner
DAAQ, Inc
3300 US Hwy 70 W Business
Clayton, NC 27520
[e-mail]
919-369-4131

UST Operator
Jamal A. Qadura
3300 US Hwy 70 W Business
Clayton, NC 27520
[e-mail]
919-934-8833

Property Owner
Jamal A. Qadura
3300 US Hwy 70 W Business
Clayton, NC 27520
[e-mail]
919-934-8833

Property Occupant
Jimmy’s Gas Mart
3300 US Hwy 70 W Business
Clayton, NC 27520-6831
[e-mail]
919-934-8833

Consultant/Contractor
Geological Resources, Inc.
3502 Hayes Road
Monroe, NC 28110
[e-mail]
704-845-4010

Analytical Laboratory
Waypoint Analytical
449 Springbrook Road
Charlotte, NC 28217
State Certification No. 37735/402
704-529-6364
3. Information about Release
 Release was discovered on May 7, 2019
 An unknown amount of product was released from the former UST system(s). Two 8,000-gallon and
one 5,000-gallon gasoline USTs were removed on May 7, 2019

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: August 31, 2023 Jimmy’s Gas Mart
Project Manager: Scott Driscoll GRI Project No. 6373
ii
EXECUTIVE SUMMARY
Jimmy’s Gas Mart is located at 3300 Highway 70 Business in Clayton, Johnston County, North Carolina.
The property operates as a petroleum retail facility, convenience store and restaurant. Two 8,000-gallon
and one 5,000-gallon gasoline USTs were removed from the site in May 2019 and a release was observed.
One 12,000-gallon and two 4,000-gallon gasoline USTs and one 4,000-gallon diesel fuel UST are in use at
the site. The active USTs were installed April 30, 2019. The fueling islands and canopy front Highway 70
Business. The site is covered by concrete and asphalt in its central areas which are surrounded by grassy
islands and landscaped areas. Surrounding properties are used for residential, industrial and business
purposes.

On August 3, 2023, surface water samples were collected for analyses from the inlet, outlet and two basins
associated with the stormwater drain system that transects the property. Any reported contaminant
concentrations were less than the established ground water or surface water standards.

On August 3, 2023, free product thicknesses of 1.03 and 0.40 feet were measured in MW-4 and MW-8,
respectively. An 8-hour AFVR event was conducted by Eastern Environmental under the supervision of
GRI. Monitoring wells MW-4 and MW-8 were used as the extraction wells for the duration of the event.
The results of the AFVR event indicate that a total of 600 gallons of liquids were removed during the event.
Based on 8 hours of operation, the average liquid recovery rate was 75 gallons per hour. Based on mass
removal calculations, a total of 44.17 pounds or 7.07 gallons of vapor phase hydrocarbons were removed
during the event at a rate of 0.88 gallons per hour. Free product was not observed in the wells after the AFVR
event.

Based on this information, the risk classification for the site should remain high risk. It is recommended
that an additional ground water sampling and free-product gauging event be conducted at the site.
Results from the event will help determine if additional free product recovery is warranted in the future.
The next sampling event is tentatively scheduled for January 2024.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: August 31, 2023 Jimmy’s Gas Mart
Project Manager: Scott Driscoll GRI Project No. 6373

iii
ACRONYMS
ACM: Asbestos Containing Materials
AFVR: Aggressive Fluid-Vapor Recovery
ARR: Acknowledgement of Report Receipt
AS: Air Sparging
AST: Aboveground Storage Tank
ASTM: American Society for Testing and
Materials
BGS: Below Ground Surface
CAP: Corrective Action Plan
CFR: Code of Federal Regulations
CSA: Comprehensive Site Assessment
DPE: Dual Phase Extraction
DRO: Total Petroleum Hydrocarbons Diesel
Range Organics
DWM: Division of Waste Management
DWR: Department of Water Resources
EPA: Environmental Protection Agency
EPH: Extractible Petroleum Hydrocarbons
ESA: Environmental Site Assessment
GCL: Gross Contamination Level
GRI: Geological Resources, Inc.
GRO: Total Petroleum Hydrocarbons
Gasoline Range Organics
LSA: Limited Site Assessment
MAC: Maximum Allowable Concentration as
specified in T15A NCAC 2L.0202
MADEP: Massachusetts Department of
Environmental Protection
MCC: Maximum Contaminant
Concentrations
MMPE: Mobile Multi-Phase Extraction
NAPL: Non-Aqueous Phase Liquid, “Free
Product”
NCDEQ: North Carolina Department of
Environmental Quality
NCDOT: North Carolina Department of
Transportation
NFA: Notice of No Further Action
NORR: Notice of Regulatory Requirements
NOV: Notice of Violation
NPDES: National Pollutant Discharge
Elimination System
NRP: Notice of Residual Petroleum
O&M: Operation and Maintenance
PAHs: Polynuclear Aromatic Hydrocarbons
PCA: Pre-Construction Assessment
RAL: Regulatory Action Level
SCLs: Soil Cleanup Level
SPCC: Spill Prevention Control and
Countermeasures
SVE: Soil Vapor Extraction
SVOCs: Semi-Volatile Organic Compounds
SWPPP: Stormwater Pollution Prevention Plan
TCLP: Toxicity Characteristic Leaching
Procedure (EPA Method SW-846 1311)
TOC: Top of Casing
TPH: Total Petroleum Hydrocarbons
USGS: United States Geological Survey
UST: Underground Storage Tank
UVF: Ultraviolet Fluorescence
VOCs: Volatile Organic Compounds
VPH: Volatile Petroleum Hydrocarbons

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: August 31, 2023 Jimmy’s Gas Mart
Project Manager: Scott Driscoll GRI Project No. 6373

TABLE OF CONTENTS
SITE INFORMATION ............................................................................................................................ i
EXECUTIVE SUMMARY ....................................................................................................................... ii
ACRONYMS ....................................................................................................................................... iii
1.0 SITE HISTORY AND CHARACTERIZATION ...................................................................................1
2.0 SURFACE WATER SAMPLING ....................................................................................................3
3.0 FREE PRODUCT REMOVAL ........................................................................................................3
4.0 CONCLUSIONS .........................................................................................................................4
5.0 LIMITATIONS ...........................................................................................................................4
6.0 STATEMENTS AND CERTIFICATION ...........................................................................................5

FIGURES
Figure 1: Site Location Map
Figure 2: Site Map

TABLES
Table 1: UST Owner and Operator Information
Table 2: UST System Information
Table 3: Surface Water Sample Results
Table 4: Well Construction and Gauging Information
Table 5: Free Product Recovery Results
Table 6: Free Product Recovery Event Information
Table 7: Free Product Recovery Cost Summary

APPENDICES
Appendix A: State Correspondence
Appendix B: Laboratory Report – Surface Water Samples
Appendix C: AFVR Data Sheets, Calculations and Disposal Manifest

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: August 31, 2023 Jimmy’s Gas Mart
Project Manager: Scott Driscoll GRI Project No. 6373

1
1.0 SITE HISTORY AND CHARACTERIZATION
GRI presents the results of the August 2023 Free Product Recovery event at the Jimmy’s Gas Mart site
located at 3300 Highway 70 Business in Clayton, Johnston County, North Carolina (Figure 1). These
activities were conducted in accordance with GRI Proposal No. 23-267, which was submitted to NCDEQ
on June 5, 2023, and was approved as Task Authorization No. 42215-5 on June 6, 2023. State
correspondence has been included as Appendix A.

The site property is owned by Mr. Jamal A. Quadra and is operated as the Jimmys Gas Mart convenience
store. The site building houses the convenience store and has additional lease space that is occupied by
tenants. One 12,000-gallon and two 4,000-gallon gasoline USTs, and one 4,000-gallon diesel fuel UST are
operated at the site. The fueling dispensers associated with the USTs are located on the western portion
of the site fronting US Highway 70 Business. The USTs are owned and operated by DAAQ, Inc. UST
owner/operator information and UST system information are included as Tables 1 and 2, respectively.
The Registered Tank Report is shown below:

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: August 31, 2023 Jimmy’s Gas Mart
Project Manager: Scott Driscoll GRI Project No. 6373

2
In May 2019, the UST systems listed as Tank Id 1, 2, and 3 in the registered tank report were excavated
and removed from the site. The UST systems consisted of two 8,000-gallon and one 5,000-gallon gasoline
USTs. During the removal of the USTs, 1,680 gallons of ground water and petroleum mix were removed
from the former tank basin; and 1,124.29 tons of petroleum impacted soil were excavated and
transported off-site for disposal.

In August 2019, An LSA report detailed additional soil and ground water sampling in response to the
release. Ground water samples reported concentrations of dissolved petroleum constituents exceeding
GCL concentrations for benzene. Analyses of soil reported concentrations of individual petroleum
compounds at concentrations exceeding the MSCCs and Residential risk-based soil clean-up levels. A
receptor survey identified one water supply well used for irrigation within 250 feet of the release. Fifteen
water supply wells were identified within a 1,500-foot radius of the site. One potable well was identified
within 1,000 feet. In addition, a storm sewer line that transects the site was identified. It collects water
from ditches north of the site and from drains on-site and discharges into an unnamed tributary creek of
Reedy Branch across Highway 70 Business.

In January 2022, a CSA report summarized sampling results from eleven ground water monitoring wells,
the irrigation well located on the site, results of a soil boring survey, sampling of the surface water
drainage system, and historical free product recovery information. Additional assessment and sampling
were conducted by GRI and presented in a “Ground Water and Soil Boring Assessment Report” in April
2023.

The site is covered by concrete and asphalt in its central areas which are surrounded by grassy islands and
landscaped areas. Surrounding properties are used for residential, industrial, and business purposes. The
overall topography near the site is gently sloped toward the south. Public water is provided to the subject
site and is available to all surrounding properties by the Johnston County Public Utility West (JCPUW)
water system (PWS ID; NC0351070). The site is not located within a designated wellhead protection area.

Please note that some of the information contained in this report was obtained under the supervision of
Henry Nemargut Engineering Services, the previous consultant on the project until GRI was retained in
February 2023. Although GRI cannot verify the accuracy of their information, for the purpose of this
report it is assumed to be correct, and any inferences or interpretations made by GRI based on data that
may be incorrect are not the responsibility of GRI. Please refer to earlier submittals for additional
information regarding assessment activities.

A site location map is included as Figure 1. A Site Map showing the locations of the monitoring wells,
pertinent features and structures has been included as Figure 2.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: August 31, 2023 Jimmy’s Gas Mart
Project Manager: Scott Driscoll GRI Project No. 6373

3
2.0 SURFACE WATER SAMPLING
On August 3, 2023, surface water samples were collected for analyses from the inlet, outlet and two basins
associated with the stormwater drain system located on the subject property. The collected samples were
submitted for laboratory analyses of VOCs and oxygenates using EPA Method 6200B. Any reported
contaminant concentrations were less than the established ground water or surface water standards. A
summary of the sample results can be found in Table 3 and the complete laboratory report is included as
Appendix B.
3.0 FREE PRODUCT REMOVAL
On August 3, 2023, MW-4 and MW-8 were gauged prior to the start of the AFVR event. Free product
thicknesses of 1.03 and 0.40 feet were measured in MW-4 and MW-8, respectively. Well construction
and gauging information is summarized in Table 4.

The AFVR event was conducted by Eastern Environmental under the supervision of GRI. Monitoring wells
MW-4 and MW-8 were used as the extraction wells for the duration of the event. The AFVR equipment
included a liquid ring pump, a 3,300-gallon capacity vacuum tanker, flexible vacuum hoses, 1-inch
diameter PVC stinger pipes and associated couplings and pipe fittings to manifold to the wells. The AFVR
system was rated at 1,400 cfm at 21 in./Hg. The stinger pipe depth was initially set to 12.0 feet bgs in
MW-4 and 12.2 feet bgs in MW-8 for the first four hours of the event. The stingers were then adjusted to
14 feet bgs in both extraction wells for the remainder of the event.

Both wells were vacuumed continuously for the duration of the 8-hour event. During the event,
measurements of relative humidity, temperature, vacuum, exhaust velocity and off-gas concentrations
were recorded at the discharge stack every fifteen minutes for the first two hours, followed by every thirty
minutes for the remainder if the event. System vacuum remained at 21 in. Hg during the event. The
effluent velocity ranged from 206 to 463 feet per minute. The system temperature ranged from 80.8 to
118.0°F and relative humidity ranged from 94.6 to 100.0 percent. The VOC off-gas concentrations ranged
from 274.6 ppm to 2,061.0 ppm during the event. No free product was measured in either well at the
conclusion of the event. Copies of the AFVR calculations and disposal manifests have been included as
Appendix C. A summary of the gauging data for the August 2023 AFVR event has been listed below:

Well ID
Product
Thickness
before
Recovery
(feet)
Product Thickness
after Recovery
(feet)
Amount of Liquid
Recovered
(gallons)
Amount of Product
Recovered as Liquid
(gallons)
MW-4 1.03 0.00 600 7.07 MW-8 0.40 0.00

The results of the AFVR event indicate that a total of 600 gallons of liquids were removed during the event.
Of the total liquids extracted, no measurable free product was observed in the tanker at the conclusion
of the event. Based on 8 hours of operation, the average liquid recovery rate was 75 gallons per hour. A

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: August 31, 2023 Jimmy’s Gas Mart
Project Manager: Scott Driscoll GRI Project No. 6373

4
summary of free product recovery data has been included as Table 5. Summaries of AFVR event
information and cost analysis are provided in Tables 6 and 7, respectively. At the conclusion of the AFVR
event, all wastewater was transported to a permitted facility for disposal. A summary of the free product
recovery data from the AFVR event is listed below:

Well ID
Average
Effluent
Velocity
(ft/min)
Average
Effluent
Temperature
(°F)
Average
Effluent
Concentration
(ppm)
Amount of
Vaporized
Product
(gallons)
Amount of
Liquid
Recovered
(gallons)
Amount
of Product
Recovered
as Liquid
(gallons)
Total
Amount of
Product
Recovered
(gallons)
MW-4 /
MW-8 274 104 1,464.9 7.07 600 0.00 7.07
Totals to Date 7.07 600 0.00 7.07
4.0 CONCLUSIONS
 On August 3, 2023, free product thicknesses of 1.03 and 0.40 feet were measured in MW-4 and
MW-8, respectively. An 8-hour AFVR event was conducted by Eastern Environmental under the
supervision of GRI. Monitoring wells MW-4 and MW-8 were used as the extraction wells for the
duration of the event.
 The results of the AFVR event indicate that a total of 600 gallons of liquids were removed during
the event. Of the total liquids extracted, no measurable free product was observed in the tanker
at the conclusion of the event. Based on 8 hours of operation, the average liquid recovery rate
was 75 gallons per hour. Based on mass removal calculations, a total of 44.17 pounds or 7.07 gallons
of vapor phase hydrocarbons were removed during the event at a rate of 0.88 gallons per hour. Free
product was not observed in the wells after the AFVR event.
 On August 3, 2023, surface water samples were collected for analyses from the inlet, outlet and
two basins associated with the stormwater drain system that transects the property. Any
reported contaminant concentrations were less than the established ground water or surface
water standards.
 Based on this information, the risk classification for the site should remain high risk. It is
recommended that an additional ground water sampling and free-product gauging event be
conducted at the site. Results from the event will help determine if additional free product
recovery is warranted in the future. The next sampling event is tentatively scheduled for January
2024.
5.0 LIMITATIONS
This report has been prepared for the exclusive use of DAAQ, Inc. for specific application to the referenced
site in Johnston County, North Carolina. The assessment was conducted based on the scope of work and
level of effort desired by NCDEQ and with resources adequate only for that scope of work. Our findings
have been developed in accordance with generally accepted standards of environmental practices in the

FIGURES
SITE LOCATION
Figure 1
Site Location
Jimmy’s Gas Mart
3300 US 70 Business West
Clayton, North Carolina
Johnston County
Incident No. 42215
GRI Project No. 6373
500 M
2000 FT
Date: 03/02/2023 Location: 35.555572° N -78.386676° W
D
a
d

TABLES
UST ID Number 1-3, A1A,A1B, A1C,A1D Facility ID Number
Owner or Operator?
Owner/Operator
TABLE 1
UST OWNER/OPERATOR INFORMATION
JIMMY'S GAS MART (INCIDENT NO. 42215)
00-0-0000035374
Name of Owner or Operator Dates of Ownership / Operation
Jamal A Qadura, dba DAAQ Inc.04/2019 - Current
Address Telephone Number
3300 US Highway 70 Business West, Clayton, NC 27520 [phone]
Page 1 of 1
Date: 04/11/2023
Was Release
Associated
with UST
System?
(Yes / No)
1 Gasoline NA 8,000 04/20/1988 Single Wall Steel Unknown Other Closed Yes
2 Gasoline NA 8,000 04/20/1988 Single Wall Steel Unknown Other Closed Yes
3 Gasoline NA 5,000 04/20/1988 Single Wall Steel Unknown Other Closed Yes
A1A Gasoline NA 4,000 01/12/2019 Double Wall Steel Unknown Double Wall Flex Current Unknown
A1B Gasoline NA 12,000 01/12/2019 Double Wall Steel Unknown Double Wall Flex Current Unknown
A1C Gasoline NA 4,000 01/12/2019 Double Wall Steel Unknown Double Wall Flex Current Unknown
A1D Diesel NA 4,000 01/12/2019 Double Wall Steel Unknown Double Wall Flex Current Unknown
Tank
Dimensions
Description of
Associated
Product Piping
and
Pumps
Status
of
UST
Facility ID # : 00-0-0000035374
TABLE 2
UST SYSTEM INFORMATION
JIMMY'S GAS MART (INCIDENT NO. 42215)
UST
ID
No.
Current
or Most
Recent
Contents
Previous
Contents
Capacity
(gallons)
Date
Installed
Construction
Details
Page 1 of 1
Well
ID
Date
Collected
(mm/dd/y
y)
1 600 600 500 20 6 40 10 70 0.7 400 400
5,000 260,000 80,000 50,000 20,000 6,000 40,000 10,000 26,100 700 28,500 24,100
03/20/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <1.90 <1.60 <0.190 <0.220 <0.190 <0.180
08/03/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <1.90 <1.60 <0.190 <0.220 <0.190 <0.180
03/20/23 0.666 0.81 1.75 6.32 <0.140 <0.470 <1.90 <1.60 <0.190 <0.220 1.58 0.323 J
08/03/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <1.90 <1.60 <0.190 <0.220 <0.190 <0.180
03/20/23 0.437 J 0.804 1.91 6.79 <0.140 <0.470 <1.90 <1.60 <0.190 <0.220 1.59 0.333 J
08/03/23 0.606 0.412 J 1.73 6.51 <0.140 <0.470 <1.90 <1.60 0.254 J <0.220 2.20 0.442 J
03/20/23 0.452 J 0.334 J 0.976 3.43 <0.140 <0.470 <1.90 <1.60 <0.190 <0.220 0.741 <0.180
08/03/23 <0.180 <0.220 0.288 J 0.789 J <0.140 <0.470 <1.90 <1.60 <0.190 <0.220 0.315 J <0.180
Trip Blank 08/03/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 NA NA <0.190 <0.220 <0.190 <0.180
Notes:
• J: Estimated value.
• For other compounds reported refer to the laboratory reports.
Basin 2
Outfall
• Results reported in µg/l (micrograms per liter)
• MAC: Maximum Allowable Concenration as specified in T15A NCAC 2L.0202.
• GCL: Gross contamination level.
• < : Less than the method detection limit specified in the laboratory report.
1,
2
,
4

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MACs (μg/l)
GCL (μg/l)
Inlet
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Basin 1
MT
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Contaminant of
Concern
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TABLE 3
SUMMARY OF SURFACE WATER SAMPLE ANALYTICAL RESULTS
JIMMY'S GAS MART (INCIDENT NO. 42215)
Date: 08/21/2023 Facility ID #: 00-0-0000035374
Analytical Method
EPA Method 6200B + Oxygenates
Date: 08/21/2023
Well ID
Date
Water
Level
Measured
(m/dd/yy)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water
from
Top of
Casing
(feet)
Free
Product
Thickness
(ft.)
Ground
Water
Elevation
(ft.)
Comment
s
07/05/19 17.12 82.2308/03/23 12.91 1.03 86.20 Pre-AFVR
08/03/23 19.04 ---79.41 Post-AFVR
08/03/23 12.42 0.40 87.56 Pre-AFVR
08/03/23 19.92 ---79.81 Post-AFVR
Notes:
• NA : Not Applicable.
• Elevation relative to mean sea level.
• ft BGS : feet below ground surface.
MW-8 NM 99.73
MW-4 NM 98.45
TABLE 4
WELL CONSTRUCTION AND GAUGING INFORMATION
JIMMY'S GAS MART (INCIDENT NO. 42215)
Facility ID # : 00-0-0000035374
Date: 08/09/23
Method of Measurement:
Well ID Product Type
(gas, diesel, etc.)
Date of
Recovery
(mm/dd/yy)
Free Product
Recovery
Method*
Casing
Diameter
(inches)
Product
Thickness
before
Recovery
(feet)
Product
Thickness
after Recovery
(feet)
Amount of
Liquid
Recovered
(gallons)
Amount of
Product
Recovered as
Liquid (gallons)
MW-4 2 1.03 0.00
MW-8 2 0.40 0.00
Notes :
• *: Bailing, Skimming, Aggressive Fluid Vapor Recovery (AFVR), Mobile Multiphase Extraction (MMPE)
• Amount of Liquid Recovered (gallons) includes Total liquids (Water and Free Product) as indicated on Disposal Manifest.
• Amount of Product Recovered (in gallons) includes only the volume of free product in the tanker at the end of the event
(based on Disposal Manifest and/or Field Notes).
600.00 0.00AFVR08/03/23Gasoline
TABLE 5
FREE PRODUCT RECOVERY RESULTS
JIMMY'S GAS MART (INCIDENT NO. 42215)
Facilty ID #: 00-0-0000035374
Interface probe at top-of-casing
Date: 08/09/23
MW-4 , MW-
8 08/03/23 AFVR 274 103.8 1,468 7.07 600.00 0.00 7.07
7.07 600.00 0.00 7.07
Notes:
• *: Bailing, Skimming, Aggressive Fluid Vapor Recovery (AFVR), Mobile Multiphase Extraction (MMPE)
• Amount of Vaporized Product (in gallons) is based on Vapor Emissions Summary Sheet, = lbs emitted/6.15
• Amount of Liquid Recovered includes Total liquids (Water and Free Product)
• Amount of Product Recovered as Liquid includes only the volume of free product at the end of the event
• Total Amount of Product Recovered = Amount of Vaporized Product + Amount of Product Recovered as Liquid
• Total Fluids Removed = Amount of Vaporized Product + Amount of Liquid Recovered
• Information regarding historical free product recovery activities from other consulting companies were not included.
SUMMARY OF FLUID REMOVAL
TABLE 6
FREE PRODUCT RECOVERY EVENT INFORMATION
JIMMY'S GAS MART (INCIDENT NO. 42215)
Facility ID #: 00-0-0000035374
Well ID Date
(mm/dd/yy)
Product
Recovery
Method*
Average
Effluent
Velocity
(ft/min)
Average
Effluent
Temperature
(°F)
Average
Effluent
Concentratio
n (ppm)
Amount of
Vaporized
Product
(gallons)
Amount of
Liquid
Recovered
(gallons)
Amount of
Product
Recovered as
Liquid
(gallons)
Total
Amount of
Product
Recovered
(gallons)
Totals
Total To Date 607.07 7.07
Summary Total Fluids Removed (in gallons)Total Product Removed (in gallons)
Current Event 7.07 7.07
Date: 08/07/23
Wells Included in
Event
Product
Recovery
Method*
Date of
Event
(mm/dd/yy)
Total Amount of
Free Product plus
Ground Water
Recovered
(gallons)
Cost of Free
Product
Recovery Event
Cost Per
Gallon (total
fluids)
MW-4. MW-8 AFVR 08/03/23 607.07 $3,264.00 $5.38
607.07 $3,264.00 $5.38
Notes:
• *: Bailing, Skimming, Aggressive Fluid Vapor Recovery (AFVR), Mobile Multiphase Extraction (MMPE)
• Total Amount of Free Product Recovered = Amount of Vaporized Product + Amount of Product Recovered as Liquid
TOTAL (to date)
• Cost of Free Product Recovery Event includes supervision, travel, mileage, per diem, subcontractor costs, MMPE sampling, MMPE sampling
TABLE 7
FREE PRODUCT RECOVERY COST SUMMARY
JIMMY'S GAS MART (INCIDENT NO. 42215)
Facility ID #: 00-0-0000035374
Comments

APPENDICES

APPENDIX A
State Correspondence

April 17, 2023

DAAQ, INC
Jamal Qadura, Registered Agent
3300 US 70 Business Highway West
Clayton, NC 27520-6831

Re: Notice of Regulatory Requirement
15A NCAC 2L .0404
Risk-Based Assessment and Corrective Action for
Petroleum Underground Storage Tanks

Jimmy’s Gas Mart 3300 US 70 Business West
Clayton, Johnston County
Incident number:42215
Risk Classification: High /Ranking: H 185 A
Dear Mr. Qadura:
The subject incident has been determined by the Department to require free product removal. Therefore, you are directed to proceed with free product assessment and/or removal activities as required by 15A
NCAC 2L .0404. Specifically, you are required to:
1) Complete an inspection of the onsite culverted catch basin system and document any impacts
from the contaminated groundwater and free product.

2) Conduct a free product recovery event.

3) Submit a Free Product Recovery Report to this office in accordance with the rule and the most
recent version of the UST Section Assessment Guidelines, within 90 days of receipt of this letter.

The Department requires that all work following the submittal of the Limited Site Assessment Report (Title
15A NCAC 2L .0405) be preapproved if State Trust Fund reimbursement is anticipated. To comply with
this requirement, a completed Preapproval/Claim Authorization Form, encompassing the required remedial
activities, must be received in this office within 14 days of the date of this letter. Upon completion of the
preapproved activities, you should submit your claim promptly. Reimbursement funds are budgeted based
on completed preapprovals, but lengthy delays in reimbursement can occur if claims are not submitted
immediately following work completion.

6373 Received APR 17 2023
Because a release or discharge has been confirmed, a Licensed Geologist or a Professional Engineer,
certified by the State of North Carolina, is required to prepare and certify all reports submitted to the
Department in accordance with Title 15A NCAC 2L .0103(e) and 2L .0111(e).

Please note that before you sell, transfer, or request a “No Further Action” determination for a property that
has not been remediated to below “unrestricted use” standards, you must file a Notice of Residual Petroleum
("Notice") with the Register of Deeds in the county where the property is located (NCGS 143B-279.9 and
143B-279.11).

If you have any questions regarding trust fund eligibility or reimbursement from the Commercial
Petroleum Underground Storage Tank Cleanup Fund, please contact the UST Section Trust Fund Branch
at [phone]. If you have any questions regarding the actions that must be taken or the rules
mentioned in this letter, please contact me at the address or telephone number listed below.

Sincerely,
Liz Price
Hydrogeologist
Wilmington Regional Office
UST Section, Division of Waste Management, NCDEQ

cc: Johnston County Health Department
Scott Driscoll & Rae Brown – GRI, via email

Wilmington Regional Office | 127 Cardinal Drive Ext| Wilmington, NC 28405 | [phone]

APPENDIX B
Laboratory Report – Surface Water Samples

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

8/9/2023
Geological Resources, Inc. Scott Driscoll
113 W. Firetower Road, Suite G Winterville, NC, 28590
Ref: Analytical Testing
Lab Report Number: 23-216-0004 Client Project Description: Jimmy's Gas Mart
GRI #6373
Dear Scott Driscoll:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 8/4/2023 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love Project Manager
Page 1 of 37
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202437735State ProgramNorth Carolina
12/31/2023402State ProgramNorth Carolina
07/31/202399012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/23-216-0004
Page 2 of 37
Report Number:
Sample Summary Table
Client Project Description:
23-216-0004
Jimmy's Gas Mart
GRI #6373
Lab No Client Sample ID Matrix Date Collected Date Received
08/03/2023 06:40Aqueous 91521 Trip Blank 08/04/2023 10:30
08/03/2023 08:41Aqueous 91522 Inlet 08/04/2023 10:30
08/03/2023 08:53Aqueous 91523 Basin-1 08/04/2023 10:30
08/03/2023 09:08Aqueous 91524 Basin-2 08/04/2023 10:30
08/03/2023 09:22Aqueous 91525 Outlet 08/04/2023 10:30
Page 3 of 37
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-216-0004
Report Limit
Project:Jimmy's Gas Mart
V 91524Basin-2
0.606 08/07/2023 14:546200BBenzeneµg/L 0.180
1.73 08/07/2023 14:546200BEthylbenzeneµg/L 0.170
J0.254 08/07/2023 14:546200Bn-Propylbenzene µg/L 0.190
J0.412 08/07/2023 14:546200BTolueneµg/L 0.220
2.20 08/07/2023 14:546200B1,2,4-Trimethylbenzene µg/L 0.190
J0.442 08/07/2023 14:546200B1,3,5-Trimethylbenzene µg/L 0.180
1.20 08/07/2023 14:546200Bo-Xylene µg/L 0.210
5.31 08/07/2023 14:546200Bm,p-Xylene µg/L 0.420
6.51 08/07/2023 14:546200BXylene (Total)µg/L 0.210
V 91525Outlet
J0.288 08/07/2023 15:196200BEthylbenzeneµg/L 0.170
J0.315 08/07/2023 15:196200B1,2,4-Trimethylbenzene µg/L 0.190
J0.789 08/07/2023 15:196200Bm,p-Xylene µg/L 0.420
J0.789 08/07/2023 15:196200BXylene (Total)µg/L 0.210
Page 4 of 37

Client: Geological Resources, Inc. CASE NARRATIVE
Project: Jimmy's Gas Mart Lab Report Number: 23-216-0004
Date: 8/9/2023
Volatile Organic Compounds - GC/MS Method 6200B Analyte: 1,2,3-Trichlorobenzene QC Batch No: V36332/V36331
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.

Page 5 of 37
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-216-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6373 Received : 08/04/2023
Jimmy's Gas Mart
Report Date : 08/09/2023
Sample ID :
Lab No :
Sampled:Trip Blank
91521 Matrix:
8/3/2023 6:40
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36331 08/07/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 08/07/23 12:51 V36332MSA
<0.180 µg/L 0.180 0.500Benzene 1 08/07/23 12:51 V36332MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/07/23 12:51 V36332MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/07/23 12:51 V36332MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/07/23 12:51 V36332MSA
<1.50 µg/L 1.50 5.00Bromoform 1 08/07/23 12:51 V36332MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 08/07/23 12:51 V36332MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/07/23 12:51 V36332MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 08/07/23 12:51 V36332MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/07/23 12:51 V36332MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/07/23 12:51 V36332MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/07/23 12:51 V36332MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/07/23 12:51 V36332MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 08/07/23 12:51 V36332MSA
<0.220 µg/L 0.220 0.500Chloroform 1 08/07/23 12:51 V36332MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 08/07/23 12:51 V36332MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/07/23 12:51 V36332MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/07/23 12:51 V36332MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/07/23 12:51 V36332MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/07/23 12:51 V36332MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 08/07/23 12:51 V36332MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/07/23 12:51 V36332MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 6 of 37
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-216-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6373 Received : 08/04/2023
Jimmy's Gas Mart
Report Date : 08/09/2023
Sample ID :
Lab No :
Sampled:Trip Blank
91521 Matrix:
8/3/2023 6:40
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36331 08/07/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/07/23 12:51 V36332MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/07/23 12:51 V36332MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/07/23 12:51 V36332MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/07/23 12:51 V36332MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/07/23 12:51 V36332MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/07/23 12:51 V36332MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/07/23 12:51 V36332MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/07/23 12:51 V36332MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/07/23 12:51 V36332MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 08/07/23 12:51 V36332MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/07/23 12:51 V36332MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/07/23 12:51 V36332MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/07/23 12:51 V36332MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/07/23 12:51 V36332MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/07/23 12:51 V36332MSA
<42.0 µg/L 42.0 200Ethanol 1 08/07/23 12:51 V36332MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 08/07/23 12:51 V36332MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/07/23 12:51 V36332MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 08/07/23 12:51 V36332MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 08/07/23 12:51 V36332MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/07/23 12:51 V36332MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/07/23 12:51 V36332MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 7 of 37
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-216-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6373 Received : 08/04/2023
Jimmy's Gas Mart
Report Date : 08/09/2023
Sample ID :
Lab No :
Sampled:Trip Blank
91521 Matrix:
8/3/2023 6:40
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36331 08/07/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/07/23 12:51 V36332MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/07/23 12:51 V36332MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/07/23 12:51 V36332MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 08/07/23 12:51 V36332MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 08/07/23 12:51 V36332MSA
<0.220 µg/L 0.220 0.500Styrene 1 08/07/23 12:51 V36332MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/07/23 12:51 V36332MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/07/23 12:51 V36332MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/07/23 12:51 V36332MSA
<0.220 µg/L 0.220 0.500Toluene 1 08/07/23 12:51 V36332MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/07/23 12:51 V36332MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/07/23 12:51 V36332MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/07/23 12:51 V36332MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/07/23 12:51 V36332MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/07/23 12:51 V36332MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/07/23 12:51 V36332MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/07/23 12:51 V36332MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/07/23 12:51 V36332MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/07/23 12:51 V36332MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/07/23 12:51 V36332MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/07/23 12:51 V36332MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 08/07/23 12:51 V36332MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 8 of 37
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-216-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6373 Received : 08/04/2023
Jimmy's Gas Mart
Report Date : 08/09/2023
Sample ID :
Lab No :
Sampled:Trip Blank
91521 Matrix:
8/3/2023 6:40
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36331 08/07/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 08/07/23 12:51 V36332MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 08/07/23 12:51 V36332
Surrogate: 4-Bromofluorobenzene 92.8 Limits: 70-130%08/07/23 12:511 MSA V36332
Surrogate: Dibromofluoromethane 99.0 Limits: 70-130%08/07/23 12:511 MSA V36332
Surrogate: 1,2-Dichloroethane - d4 92.8 Limits: 70-130%08/07/23 12:511 MSA V36332
Surrogate: Toluene-d8 111 Limits: 70-130%08/07/23 12:511 MSA V36332
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 9 of 37
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-216-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6373 Received : 08/04/2023
Jimmy's Gas Mart
Report Date : 08/09/2023
Sample ID :
Lab No :
Sampled:Inlet
91522 Matrix:
8/3/2023 8:41
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 08/07/23 14:05 6200BMSA
Surrogate: 4-Bromofluorobenzene 94.8 Limits: 70-130%08/07/23 14:051 MSA V36332
Surrogate: Dibromofluoromethane 99.6 Limits: 70-130%08/07/23 14:051 MSA V36332
Surrogate: 1,2-Dichloroethane - d4 93.0 Limits: 70-130%08/07/23 14:051 MSA V36332
Surrogate: Toluene-d8 109 Limits: 70-130%08/07/23 14:051 MSA V36332
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 10 of 37
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-216-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6373 Received : 08/04/2023
Jimmy's Gas Mart
Report Date : 08/09/2023
Sample ID :
Lab No :
Sampled:Inlet
91522 Matrix:
8/3/2023 8:41
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36331 08/07/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 08/07/23 14:05 V36332MSA
<0.180 µg/L 0.180 0.500Benzene 1 08/07/23 14:05 V36332MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/07/23 14:05 V36332MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/07/23 14:05 V36332MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/07/23 14:05 V36332MSA
<1.50 µg/L 1.50 5.00Bromoform 1 08/07/23 14:05 V36332MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 08/07/23 14:05 V36332MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/07/23 14:05 V36332MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 08/07/23 14:05 V36332MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/07/23 14:05 V36332MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/07/23 14:05 V36332MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/07/23 14:05 V36332MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/07/23 14:05 V36332MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 08/07/23 14:05 V36332MSA
<0.220 µg/L 0.220 0.500Chloroform 1 08/07/23 14:05 V36332MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 08/07/23 14:05 V36332MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/07/23 14:05 V36332MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/07/23 14:05 V36332MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/07/23 14:05 V36332MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/07/23 14:05 V36332MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 08/07/23 14:05 V36332MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/07/23 14:05 V36332MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 11 of 37
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-216-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6373 Received : 08/04/2023
Jimmy's Gas Mart
Report Date : 08/09/2023
Sample ID :
Lab No :
Sampled:Inlet
91522 Matrix:
8/3/2023 8:41
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36331 08/07/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/07/23 14:05 V36332MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/07/23 14:05 V36332MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/07/23 14:05 V36332MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/07/23 14:05 V36332MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/07/23 14:05 V36332MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/07/23 14:05 V36332MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/07/23 14:05 V36332MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/07/23 14:05 V36332MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/07/23 14:05 V36332MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 08/07/23 14:05 V36332MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/07/23 14:05 V36332MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/07/23 14:05 V36332MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/07/23 14:05 V36332MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/07/23 14:05 V36332MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/07/23 14:05 V36332MSA
<42.0 µg/L 42.0 200Ethanol 1 08/07/23 14:05 V36332MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 08/07/23 14:05 V36332MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/07/23 14:05 V36332MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 08/07/23 14:05 V36332MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 08/07/23 14:05 V36332MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/07/23 14:05 V36332MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/07/23 14:05 V36332MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 12 of 37
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-216-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6373 Received : 08/04/2023
Jimmy's Gas Mart
Report Date : 08/09/2023
Sample ID :
Lab No :
Sampled:Inlet
91522 Matrix:
8/3/2023 8:41
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36331 08/07/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/07/23 14:05 V36332MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/07/23 14:05 V36332MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/07/23 14:05 V36332MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 08/07/23 14:05 V36332MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 08/07/23 14:05 V36332MSA
<0.220 µg/L 0.220 0.500Styrene 1 08/07/23 14:05 V36332MSA
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 08/07/23 14:05 V36332MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 08/07/23 14:05 V36332MSA
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 08/07/23 14:05 V36332MSA
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 08/07/23 14:05 V36332MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/07/23 14:05 V36332MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/07/23 14:05 V36332MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/07/23 14:05 V36332MSA
<0.220 µg/L 0.220 0.500Toluene 1 08/07/23 14:05 V36332MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/07/23 14:05 V36332MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/07/23 14:05 V36332MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/07/23 14:05 V36332MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/07/23 14:05 V36332MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/07/23 14:05 V36332MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/07/23 14:05 V36332MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/07/23 14:05 V36332MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/07/23 14:05 V36332MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 13 of 37
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-216-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6373 Received : 08/04/2023
Jimmy's Gas Mart
Report Date : 08/09/2023
Sample ID :
Lab No :
Sampled:Inlet
91522 Matrix:
8/3/2023 8:41
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36331 08/07/23 09:00
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/07/23 14:05 V36332MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/07/23 14:05 V36332MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/07/23 14:05 V36332MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 08/07/23 14:05 V36332MSA
<0.420 µg/L 0.420 1.00m,p-Xylene 1 08/07/23 14:05 V36332MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 08/07/23 14:05 V36332
Surrogate: 4-Bromofluorobenzene 94.8 Limits: 70-130%08/07/23 14:051 MSA V36332
Surrogate: Dibromofluoromethane 99.6 Limits: 70-130%08/07/23 14:051 MSA V36332
Surrogate: 1,2-Dichloroethane - d4 93.0 Limits: 70-130%08/07/23 14:051 MSA V36332
Surrogate: Toluene-d8 109 Limits: 70-130%08/07/23 14:051 MSA V36332
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 14 of 37
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-216-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6373 Received : 08/04/2023
Jimmy's Gas Mart
Report Date : 08/09/2023
Sample ID :
Lab No :
Sampled:Basin-1
91523 Matrix:
8/3/2023 8:53
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 08/07/23 14:30 6200BMSA
Surrogate: 4-Bromofluorobenzene 92.8 Limits: 70-130%08/07/23 14:301 MSA V36332
Surrogate: Dibromofluoromethane 98.6 Limits: 70-130%08/07/23 14:301 MSA V36332
Surrogate: 1,2-Dichloroethane - d4 91.8 Limits: 70-130%08/07/23 14:301 MSA V36332
Surrogate: Toluene-d8 109 Limits: 70-130%08/07/23 14:301 MSA V36332
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 15 of 37
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-216-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6373 Received : 08/04/2023
Jimmy's Gas Mart
Report Date : 08/09/2023
Sample ID :
Lab No :
Sampled:Basin-1
91523 Matrix:
8/3/2023 8:53
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36331 08/07/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 08/07/23 14:30 V36332MSA
<0.180 µg/L 0.180 0.500Benzene 1 08/07/23 14:30 V36332MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/07/23 14:30 V36332MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/07/23 14:30 V36332MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/07/23 14:30 V36332MSA
<1.50 µg/L 1.50 5.00Bromoform 1 08/07/23 14:30 V36332MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 08/07/23 14:30 V36332MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/07/23 14:30 V36332MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 08/07/23 14:30 V36332MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/07/23 14:30 V36332MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/07/23 14:30 V36332MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/07/23 14:30 V36332MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/07/23 14:30 V36332MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 08/07/23 14:30 V36332MSA
<0.220 µg/L 0.220 0.500Chloroform 1 08/07/23 14:30 V36332MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 08/07/23 14:30 V36332MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/07/23 14:30 V36332MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/07/23 14:30 V36332MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/07/23 14:30 V36332MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/07/23 14:30 V36332MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 08/07/23 14:30 V36332MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/07/23 14:30 V36332MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 16 of 37
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-216-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6373 Received : 08/04/2023
Jimmy's Gas Mart
Report Date : 08/09/2023
Sample ID :
Lab No :
Sampled:Basin-1
91523 Matrix:
8/3/2023 8:53
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36331 08/07/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/07/23 14:30 V36332MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/07/23 14:30 V36332MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/07/23 14:30 V36332MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/07/23 14:30 V36332MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/07/23 14:30 V36332MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/07/23 14:30 V36332MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/07/23 14:30 V36332MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/07/23 14:30 V36332MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/07/23 14:30 V36332MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 08/07/23 14:30 V36332MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/07/23 14:30 V36332MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/07/23 14:30 V36332MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/07/23 14:30 V36332MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/07/23 14:30 V36332MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/07/23 14:30 V36332MSA
<42.0 µg/L 42.0 200Ethanol 1 08/07/23 14:30 V36332MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 08/07/23 14:30 V36332MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/07/23 14:30 V36332MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 08/07/23 14:30 V36332MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 08/07/23 14:30 V36332MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/07/23 14:30 V36332MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/07/23 14:30 V36332MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 17 of 37
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-216-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6373 Received : 08/04/2023
Jimmy's Gas Mart
Report Date : 08/09/2023
Sample ID :
Lab No :
Sampled:Basin-1
91523 Matrix:
8/3/2023 8:53
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36331 08/07/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/07/23 14:30 V36332MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/07/23 14:30 V36332MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/07/23 14:30 V36332MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 08/07/23 14:30 V36332MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 08/07/23 14:30 V36332MSA
<0.220 µg/L 0.220 0.500Styrene 1 08/07/23 14:30 V36332MSA
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 08/07/23 14:30 V36332MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 08/07/23 14:30 V36332MSA
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 08/07/23 14:30 V36332MSA
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 08/07/23 14:30 V36332MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/07/23 14:30 V36332MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/07/23 14:30 V36332MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/07/23 14:30 V36332MSA
<0.220 µg/L 0.220 0.500Toluene 1 08/07/23 14:30 V36332MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/07/23 14:30 V36332MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/07/23 14:30 V36332MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/07/23 14:30 V36332MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/07/23 14:30 V36332MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/07/23 14:30 V36332MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/07/23 14:30 V36332MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/07/23 14:30 V36332MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/07/23 14:30 V36332MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 18 of 37
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-216-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6373 Received : 08/04/2023
Jimmy's Gas Mart
Report Date : 08/09/2023
Sample ID :
Lab No :
Sampled:Basin-1
91523 Matrix:
8/3/2023 8:53
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36331 08/07/23 09:00
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/07/23 14:30 V36332MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/07/23 14:30 V36332MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/07/23 14:30 V36332MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 08/07/23 14:30 V36332MSA
<0.420 µg/L 0.420 1.00m,p-Xylene 1 08/07/23 14:30 V36332MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 08/07/23 14:30 V36332
Surrogate: 4-Bromofluorobenzene 92.8 Limits: 70-130%08/07/23 14:301 MSA V36332
Surrogate: Dibromofluoromethane 98.6 Limits: 70-130%08/07/23 14:301 MSA V36332
Surrogate: 1,2-Dichloroethane - d4 91.8 Limits: 70-130%08/07/23 14:301 MSA V36332
Surrogate: Toluene-d8 109 Limits: 70-130%08/07/23 14:301 MSA V36332
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 19 of 37
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-216-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6373 Received : 08/04/2023
Jimmy's Gas Mart
Report Date : 08/09/2023
Sample ID :
Lab No :
Sampled:Basin-2
91524 Matrix:
8/3/2023 9:08
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 08/07/23 14:54 6200BMSA
Surrogate: 4-Bromofluorobenzene 94.0 Limits: 70-130%08/07/23 14:541 MSA V36332
Surrogate: Dibromofluoromethane 98.8 Limits: 70-130%08/07/23 14:541 MSA V36332
Surrogate: 1,2-Dichloroethane - d4 91.0 Limits: 70-130%08/07/23 14:541 MSA V36332
Surrogate: Toluene-d8 110 Limits: 70-130%08/07/23 14:541 MSA V36332
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 20 of 37
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-216-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6373 Received : 08/04/2023
Jimmy's Gas Mart
Report Date : 08/09/2023
Sample ID :
Lab No :
Sampled:Basin-2
91524 Matrix:
8/3/2023 9:08
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36331 08/07/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 08/07/23 14:54 V36332MSA
0.606 µg/L 0.180 0.500Benzene 1 08/07/23 14:54 V36332MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/07/23 14:54 V36332MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/07/23 14:54 V36332MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/07/23 14:54 V36332MSA
<1.50 µg/L 1.50 5.00Bromoform 1 08/07/23 14:54 V36332MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 08/07/23 14:54 V36332MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/07/23 14:54 V36332MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 08/07/23 14:54 V36332MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/07/23 14:54 V36332MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/07/23 14:54 V36332MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/07/23 14:54 V36332MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/07/23 14:54 V36332MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 08/07/23 14:54 V36332MSA
<0.220 µg/L 0.220 0.500Chloroform 1 08/07/23 14:54 V36332MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 08/07/23 14:54 V36332MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/07/23 14:54 V36332MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/07/23 14:54 V36332MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/07/23 14:54 V36332MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/07/23 14:54 V36332MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 08/07/23 14:54 V36332MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/07/23 14:54 V36332MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 21 of 37
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-216-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6373 Received : 08/04/2023
Jimmy's Gas Mart
Report Date : 08/09/2023
Sample ID :
Lab No :
Sampled:Basin-2
91524 Matrix:
8/3/2023 9:08
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36331 08/07/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/07/23 14:54 V36332MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/07/23 14:54 V36332MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/07/23 14:54 V36332MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/07/23 14:54 V36332MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/07/23 14:54 V36332MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/07/23 14:54 V36332MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/07/23 14:54 V36332MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/07/23 14:54 V36332MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/07/23 14:54 V36332MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 08/07/23 14:54 V36332MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/07/23 14:54 V36332MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/07/23 14:54 V36332MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/07/23 14:54 V36332MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/07/23 14:54 V36332MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/07/23 14:54 V36332MSA
<42.0 µg/L 42.0 200Ethanol 1 08/07/23 14:54 V36332MSA
1.73 µg/L 0.170 0.500Ethylbenzene 1 08/07/23 14:54 V36332MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/07/23 14:54 V36332MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 08/07/23 14:54 V36332MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 08/07/23 14:54 V36332MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/07/23 14:54 V36332MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/07/23 14:54 V36332MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 22 of 37
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-216-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6373 Received : 08/04/2023
Jimmy's Gas Mart
Report Date : 08/09/2023
Sample ID :
Lab No :
Sampled:Basin-2
91524 Matrix:
8/3/2023 9:08
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36331 08/07/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/07/23 14:54 V36332MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/07/23 14:54 V36332MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/07/23 14:54 V36332MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 08/07/23 14:54 V36332MSA
0.254 J µg/L 0.190 0.500n-Propylbenzene 1 08/07/23 14:54 V36332MSA
<0.220 µg/L 0.220 0.500Styrene 1 08/07/23 14:54 V36332MSA
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 08/07/23 14:54 V36332MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 08/07/23 14:54 V36332MSA
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 08/07/23 14:54 V36332MSA
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 08/07/23 14:54 V36332MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/07/23 14:54 V36332MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/07/23 14:54 V36332MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/07/23 14:54 V36332MSA
0.412 J µg/L 0.220 0.500Toluene 1 08/07/23 14:54 V36332MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/07/23 14:54 V36332MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/07/23 14:54 V36332MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/07/23 14:54 V36332MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/07/23 14:54 V36332MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/07/23 14:54 V36332MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/07/23 14:54 V36332MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/07/23 14:54 V36332MSA
2.20 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/07/23 14:54 V36332MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 23 of 37
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-216-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6373 Received : 08/04/2023
Jimmy's Gas Mart
Report Date : 08/09/2023
Sample ID :
Lab No :
Sampled:Basin-2
91524 Matrix:
8/3/2023 9:08
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36331 08/07/23 09:00
0.442 J µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/07/23 14:54 V36332MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/07/23 14:54 V36332MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/07/23 14:54 V36332MSA
1.20 µg/L 0.210 0.500o-Xylene 1 08/07/23 14:54 V36332MSA
5.31 µg/L 0.420 1.00m,p-Xylene 1 08/07/23 14:54 V36332MSA
6.51 µg/L 0.210 0.500Xylene (Total)1 08/07/23 14:54 V36332
Surrogate: 4-Bromofluorobenzene 94.0 Limits: 70-130%08/07/23 14:541 MSA V36332
Surrogate: Dibromofluoromethane 98.8 Limits: 70-130%08/07/23 14:541 MSA V36332
Surrogate: 1,2-Dichloroethane - d4 91.0 Limits: 70-130%08/07/23 14:541 MSA V36332
Surrogate: Toluene-d8 110 Limits: 70-130%08/07/23 14:541 MSA V36332
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 24 of 37
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-216-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6373 Received : 08/04/2023
Jimmy's Gas Mart
Report Date : 08/09/2023
Sample ID :
Lab No :
Sampled:Outlet
91525 Matrix:
8/3/2023 9:22
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 08/07/23 15:19 6200BMSA
Surrogate: 4-Bromofluorobenzene 94.0 Limits: 70-130%08/07/23 15:191 MSA V36332
Surrogate: Dibromofluoromethane 99.4 Limits: 70-130%08/07/23 15:191 MSA V36332
Surrogate: 1,2-Dichloroethane - d4 91.8 Limits: 70-130%08/07/23 15:191 MSA V36332
Surrogate: Toluene-d8 109 Limits: 70-130%08/07/23 15:191 MSA V36332
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 25 of 37
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-216-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6373 Received : 08/04/2023
Jimmy's Gas Mart
Report Date : 08/09/2023
Sample ID :
Lab No :
Sampled:Outlet
91525 Matrix:
8/3/2023 9:22
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36331 08/07/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 08/07/23 15:19 V36332MSA
<0.180 µg/L 0.180 0.500Benzene 1 08/07/23 15:19 V36332MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/07/23 15:19 V36332MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/07/23 15:19 V36332MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/07/23 15:19 V36332MSA
<1.50 µg/L 1.50 5.00Bromoform 1 08/07/23 15:19 V36332MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 08/07/23 15:19 V36332MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/07/23 15:19 V36332MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 08/07/23 15:19 V36332MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/07/23 15:19 V36332MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/07/23 15:19 V36332MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/07/23 15:19 V36332MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/07/23 15:19 V36332MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 08/07/23 15:19 V36332MSA
<0.220 µg/L 0.220 0.500Chloroform 1 08/07/23 15:19 V36332MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 08/07/23 15:19 V36332MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/07/23 15:19 V36332MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/07/23 15:19 V36332MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/07/23 15:19 V36332MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/07/23 15:19 V36332MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 08/07/23 15:19 V36332MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/07/23 15:19 V36332MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 26 of 37
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-216-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6373 Received : 08/04/2023
Jimmy's Gas Mart
Report Date : 08/09/2023
Sample ID :
Lab No :
Sampled:Outlet
91525 Matrix:
8/3/2023 9:22
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36331 08/07/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/07/23 15:19 V36332MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/07/23 15:19 V36332MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/07/23 15:19 V36332MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/07/23 15:19 V36332MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/07/23 15:19 V36332MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/07/23 15:19 V36332MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/07/23 15:19 V36332MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/07/23 15:19 V36332MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/07/23 15:19 V36332MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 08/07/23 15:19 V36332MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/07/23 15:19 V36332MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/07/23 15:19 V36332MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/07/23 15:19 V36332MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/07/23 15:19 V36332MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/07/23 15:19 V36332MSA
<42.0 µg/L 42.0 200Ethanol 1 08/07/23 15:19 V36332MSA
0.288 J µg/L 0.170 0.500Ethylbenzene 1 08/07/23 15:19 V36332MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/07/23 15:19 V36332MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 08/07/23 15:19 V36332MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 08/07/23 15:19 V36332MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/07/23 15:19 V36332MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/07/23 15:19 V36332MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 27 of 37
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-216-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6373 Received : 08/04/2023
Jimmy's Gas Mart
Report Date : 08/09/2023
Sample ID :
Lab No :
Sampled:Outlet
91525 Matrix:
8/3/2023 9:22
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36331 08/07/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/07/23 15:19 V36332MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/07/23 15:19 V36332MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/07/23 15:19 V36332MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 08/07/23 15:19 V36332MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 08/07/23 15:19 V36332MSA
<0.220 µg/L 0.220 0.500Styrene 1 08/07/23 15:19 V36332MSA
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 08/07/23 15:19 V36332MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 08/07/23 15:19 V36332MSA
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 08/07/23 15:19 V36332MSA
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 08/07/23 15:19 V36332MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/07/23 15:19 V36332MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/07/23 15:19 V36332MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/07/23 15:19 V36332MSA
<0.220 µg/L 0.220 0.500Toluene 1 08/07/23 15:19 V36332MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/07/23 15:19 V36332MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/07/23 15:19 V36332MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/07/23 15:19 V36332MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/07/23 15:19 V36332MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/07/23 15:19 V36332MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/07/23 15:19 V36332MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/07/23 15:19 V36332MSA
0.315 J µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/07/23 15:19 V36332MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 28 of 37
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-216-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6373 Received : 08/04/2023
Jimmy's Gas Mart
Report Date : 08/09/2023
Sample ID :
Lab No :
Sampled:Outlet
91525 Matrix:
8/3/2023 9:22
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36331 08/07/23 09:00
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/07/23 15:19 V36332MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/07/23 15:19 V36332MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/07/23 15:19 V36332MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 08/07/23 15:19 V36332MSA
0.789 J µg/L 0.420 1.00m,p-Xylene 1 08/07/23 15:19 V36332MSA
0.789 J µg/L 0.210 0.500Xylene (Total)1 08/07/23 15:19 V36332
Surrogate: 4-Bromofluorobenzene 94.0 Limits: 70-130%08/07/23 15:191 MSA V36332
Surrogate: Dibromofluoromethane 99.4 Limits: 70-130%08/07/23 15:191 MSA V36332
Surrogate: 1,2-Dichloroethane - d4 91.8 Limits: 70-130%08/07/23 15:191 MSA V36332
Surrogate: Toluene-d8 109 Limits: 70-130%08/07/23 15:191 MSA V36332
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 29 of 37
Quality Control Data
23-216-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Jimmy's Gas Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V36332QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V36331
Associated Lab Samples: 91521, 91522, 91523, 91524, 91525
LRB-V36331 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/07/23 12:2610.01.80<1.80µg/LAcetone
08/07/23 12:260.5000.180<0.180µg/LBenzene
08/07/23 12:260.5000.210<0.210µg/LBromobenzene
08/07/23 12:261.000.420<0.420µg/LBromochloromethane
08/07/23 12:260.5000.160<0.160µg/LBromodichloromethane
08/07/23 12:265.001.50<1.50µg/LBromoform
08/07/23 12:261.000.280<0.280µg/LBromomethane
08/07/23 12:260.5000.180<0.180µg/Ln-Butylbenzene
08/07/23 12:260.5000.200<0.200µg/Lsec-Butyl benzene
08/07/23 12:262.000.920<0.920µg/Ltert-Butyl benzene
08/07/23 12:260.5000.180<0.180µg/LCarbon Tetrachloride
08/07/23 12:260.5000.190<0.190µg/LChlorobenzene
08/07/23 12:260.5000.190<0.190µg/LChlorodibromomethane
08/07/23 12:261.000.430<0.430µg/LChloroethane
08/07/23 12:260.5000.220<0.220µg/LChloroform
08/07/23 12:260.5000.220<0.220µg/LChloromethane
08/07/23 12:260.5000.200<0.200µg/L2-Chlorotoluene
08/07/23 12:260.5000.200<0.200µg/L4-Chlorotoluene
08/07/23 12:260.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
08/07/23 12:262.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
08/07/23 12:260.5000.200<0.200µg/L1,2-Dibromoethane
08/07/23 12:260.5000.230<0.230µg/LDibromomethane
08/07/23 12:260.5000.220<0.220µg/L1,2-Dichlorobenzene
08/07/23 12:260.5000.190<0.190µg/L1,3-Dichlorobenzene
08/07/23 12:260.5000.210<0.210µg/L1,4-Dichlorobenzene
08/07/23 12:265.001.20<1.20µg/LDichlorodifluoromethane
08/07/23 12:260.5000.240<0.240µg/L1,1-Dichloroethane
Page 1 of 6Date:08/09/2023 01:19 PM
Page 30 of 37
Quality Control Data
23-216-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Jimmy's Gas Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V36332QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V36331
Associated Lab Samples: 91521, 91522, 91523, 91524, 91525
LRB-V36331 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/07/23 12:260.5000.150<0.150µg/L1,2-Dichloroethane
08/07/23 12:260.5000.150<0.150µg/L1,1-Dichloroethene
08/07/23 12:260.5000.200<0.200µg/Lcis-1,2-Dichloroethene
08/07/23 12:260.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
08/07/23 12:260.5000.190<0.190µg/L1,2-Dichloropropane
08/07/23 12:260.5000.130<0.130µg/L1,3-Dichloropropane
08/07/23 12:262.000.210<0.210µg/L2,2-Dichloropropane
08/07/23 12:260.5000.200<0.200µg/L1,1-Dichloropropene
08/07/23 12:260.5000.210<0.210µg/Lcis-1,3-Dichloropropene
08/07/23 12:260.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
08/07/23 12:2620042.0<42.0µg/LEthanol
08/07/23 12:260.5000.170<0.170µg/LEthylbenzene
08/07/23 12:263.000.350<0.350µg/LHexachlorobutadiene
08/07/23 12:261.000.380<0.380µg/L2-Hexanone
08/07/23 12:260.5000.180<0.180µg/LIsopropylbenzene
08/07/23 12:260.5000.089<0.089µg/L4-Isopropyl toluene
08/07/23 12:265.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
08/07/23 12:261.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
08/07/23 12:261.000.078<0.078µg/L4-Methyl-2-Pentanone
08/07/23 12:262.000.330<0.330µg/LMethylene Chloride
08/07/23 12:261.000.470<0.470µg/LNaphthalene
08/07/23 12:260.5000.190<0.190µg/Ln-Propylbenzene
08/07/23 12:260.5000.220<0.220µg/LStyrene
08/07/23 12:2610.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
08/07/23 12:2610.00.350<0.350µg/Ltert-Butyl formate (TBF)
08/07/23 12:2610.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
08/07/23 12:2610.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
Page 2 of 6Date:08/09/2023 01:19 PM
Page 31 of 37
Quality Control Data
23-216-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Jimmy's Gas Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V36332QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V36331
Associated Lab Samples: 91521, 91522, 91523, 91524, 91525
LRB-V36331 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/07/23 12:260.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
08/07/23 12:260.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
08/07/23 12:260.5000.220<0.220µg/LTetrachloroethene
08/07/23 12:260.5000.220<0.220µg/LToluene
08/07/23 12:260.5000.380<0.380µg/L1,2,3-Trichlorobenzene
08/07/23 12:260.5000.310<0.310µg/L1,2,4-Trichlorobenzene
08/07/23 12:260.5000.160<0.160µg/L1,1,1-Trichloroethane
08/07/23 12:260.5000.096<0.096µg/L1,1,2-Trichloroethane
08/07/23 12:260.5000.180<0.180µg/LTrichloroethene
08/07/23 12:260.5000.180<0.180µg/LTrichlorofluoromethane
08/07/23 12:260.5000.270<0.270µg/L1,2,3-Trichloropropane
08/07/23 12:260.5000.190<0.190µg/L1,2,4-Trimethylbenzene
08/07/23 12:260.5000.180<0.180µg/L1,3,5-Trimethylbenzene
08/07/23 12:265.001.00<1.00µg/LVinyl Acetate
08/07/23 12:260.5000.170<0.170µg/LVinyl Chloride
08/07/23 12:260.5000.210<0.210µg/Lo-Xylene
08/07/23 12:261.000.420<0.420µg/Lm,p-Xylene
08/07/23 12:2610.01.00<1.00µg/L3,3-Dimethyl-1-butanol
08/07/23 12:264-Bromofluorobenzene (S)94.8 70-130
08/07/23 12:26Dibromofluoromethane (S)99.2 70-130
08/07/23 12:261,2-Dichloroethane - d4 (S)91.6 70-130
08/07/23 12:26Toluene-d8 (S)111 70-130
Page 3 of 6Date:08/09/2023 01:19 PM
Page 32 of 37
Quality Control Data
23-216-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Jimmy's Gas Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V36332QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V36331
LCS-V36331 LCSD-V36331Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
17.8 44.540.516.240.0µg/LAcetone 40-160 9.4 20.0
17.1 85.586.517.320.0µg/LBenzene 70-130 1.1 20.0
19.7 98.597.519.520.0µg/LBromobenzene 70-130 1.0 20.0
18.5 92.592.018.420.0µg/LBromochloromethane 70-130 0.5 20.0
16.6 83.083.516.720.0µg/LBromodichloromethane 70-130 0.6 20.0
22.4 11211222.420.0µg/LBromoform 70-130 0.0 20.0
16.1 80.577.515.520.0µg/LBromomethane 60-140 3.7 20.0
19.5 97.599.019.820.0µg/Ln-Butylbenzene 70-130 1.5 20.0
20.4 10210420.720.0µg/Lsec-Butyl benzene 70-130 1.4 20.0
20.7 10410621.120.0µg/Ltert-Butyl benzene 70-130 1.9 20.0
18.0 90.091.518.320.0µg/LCarbon Tetrachloride 70-130 1.6 20.0
20.8 10410520.920.0µg/LChlorobenzene 70-130 0.4 20.0
21.9 11010721.420.0µg/LChlorodibromomethane 70-130 2.3 20.0
19.3 96.594.018.820.0µg/LChloroethane 60-140 2.6 20.0
16.5 82.584.016.820.0µg/LChloroform 70-130 1.8 20.0
16.2 81.080.516.120.0µg/LChloromethane 60-140 0.6 20.0
19.7 98.510220.420.0µg/L2-Chlorotoluene 70-130 3.4 20.0
20.2 10110320.520.0µg/L4-Chlorotoluene 70-130 1.4 20.0
14.0 70.070.014.020.0µg/LDi-Isopropyl Ether (DIPE)70-130 0.0 20.0
24.3 12211122.120.0µg/L1,2-Dibromo-3-Chloropropane 70-130 9.4 20.0
20.7 10499.519.920.0µg/L1,2-Dibromoethane 70-130 3.9 20.0
16.5 82.582.016.420.0µg/LDibromomethane 70-130 0.6 20.0
21.3 10710520.920.0µg/L1,2-Dichlorobenzene 70-130 1.8 20.0
21.2 10610621.120.0µg/L1,3-Dichlorobenzene 70-130 0.4 20.0
21.0 10510420.720.0µg/L1,4-Dichlorobenzene 70-130 1.4 20.0
17.8 89.090.518.120.0µg/LDichlorodifluoromethane 60-140 1.6 20.0
Page 4 of 6Date:08/09/2023 01:19 PM
Page 33 of 37
Quality Control Data
23-216-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Jimmy's Gas Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V36332QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V36331
LCS-V36331 LCSD-V36331Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
16.9 84.585.017.020.0µg/L1,1-Dichloroethane 70-130 0.5 20.0
15.2 76.077.515.520.0µg/L1,2-Dichloroethane 70-130 1.9 20.0
16.0 80.085.017.020.0µg/L1,1-Dichloroethene 70-130 6.0 20.0
16.4 82.082.516.520.0µg/Lcis-1,2-Dichloroethene 70-130 0.6 20.0
17.2 86.085.017.020.0µg/Ltrans-1,2-Dichloroethene 70-130 1.1 20.0
16.6 83.084.516.920.0µg/L1,2-Dichloropropane 70-130 1.7 20.0
19.9 99.596.019.220.0µg/L1,3-Dichloropropane 70-130 3.5 20.0
16.6 83.085.017.020.0µg/L2,2-Dichloropropane 70-130 2.3 20.0
18.1 90.591.518.320.0µg/L1,1-Dichloropropene 70-130 1.0 20.0
17.8 89.087.517.520.0µg/Lcis-1,3-Dichloropropene 70-130 1.6 20.0
17.6 88.085.517.120.0µg/Ltrans-1,3-Dichloropropene 70-130 2.8 20.0
397 79.480.8404500µg/LEthanol 60-140 1.7 20.0
19.3 96.598.019.620.0µg/LEthylbenzene 70-130 1.5 20.0
22.9 11512224.320.0µg/LHexachlorobutadiene 70-130 5.9 20.0
14.3 71.565.513.120.0µg/L2-Hexanone 60-140 8.7 20.0
21.2 10610921.720.0µg/LIsopropylbenzene 70-130 2.3 20.0
21.8 10911021.920.0µg/L4-Isopropyl toluene 70-130 0.4 20.0
18.8 94.090.018.020.0µg/LMethyl Ethyl Ketone (MEK)60-140 4.3 20.0
17.4 87.085.017.020.0µg/LMethyl tert-butyl ether (MTBE)70-130 2.3 20.0
13.3 66.566.013.220.0µg/L4-Methyl-2-Pentanone 60-140 0.7 20.0
14.8 74.072.014.420.0µg/LMethylene Chloride 70-130 2.7 20.0
21.8 10910320.620.0µg/LNaphthalene 70-130 5.6 20.0
19.4 97.099.519.920.0µg/Ln-Propylbenzene 70-130 2.5 20.0
21.0 10510621.220.0µg/LStyrene 70-130 0.9 20.0
36.6 91.590.536.240.0µg/Ltert-Butyl Alcohol (TBA)40-140 1.0 20.0
49.0 12311746.640.0µg/Ltert-Butyl formate (TBF)40-140 5.0 20.0
Page 5 of 6Date:08/09/2023 01:19 PM
Page 34 of 37
Quality Control Data
23-216-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Jimmy's Gas Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V36332QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V36331
LCS-V36331 LCSD-V36331Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
22.3 11211523.020.0µg/Ltert-Amyl Alcohol (TAA)40-140 3.0 20.0
34.7 86.784.033.640.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 3.2 20.0
21.5 10810921.720.0µg/L1,1,1,2-Tetrachloroethane 70-130 0.9 20.0
19.8 99.096.019.220.0µg/L1,1,2,2-Tetrachloroethane 70-130 3.0 20.0
22.3 11211422.820.0µg/LTetrachloroethene 70-130 2.2 20.0
17.2 86.085.517.120.0µg/LToluene 70-130 0.5 20.0
27.4 137*12224.420.0µg/L1,2,3-Trichlorobenzene 70-130 11.5 20.0
24.4 12211723.420.0µg/L1,2,4-Trichlorobenzene 70-130 4.1 20.0
16.8 84.085.017.020.0µg/L1,1,1-Trichloroethane 70-130 1.1 20.0
18.3 91.589.517.920.0µg/L1,1,2-Trichloroethane 70-130 2.2 20.0
18.2 91.090.518.120.0µg/LTrichloroethene 70-130 0.5 20.0
18.5 92.592.018.420.0µg/LTrichlorofluoromethane 60-140 0.5 20.0
19.4 97.092.018.420.0µg/L1,2,3-Trichloropropane 70-130 5.2 20.0
21.2 10610821.520.0µg/L1,2,4-Trimethylbenzene 70-130 1.4 20.0
21.3 10710921.720.0µg/L1,3,5-Trimethylbenzene 70-130 1.8 20.0
16.8 84.092.518.520.0µg/LVinyl Acetate 60-140 9.6 20.0
19.2 96.097.019.420.0µg/LVinyl Chloride 60-140 1.0 20.0
20.0 10010120.120.0µg/Lo-Xylene 70-130 0.4 20.0
42.3 10610742.740.0µg/Lm,p-Xylene 70-130 0.9 20.0
21.7 10993.018.620.0µg/L3,3-Dimethyl-1-butanol 70-130 15.3 20.0
95.094.84-Bromofluorobenzene (S)70-130
96.096.8Dibromofluoromethane (S)70-130
93.090.81,2-Dichloroethane - d4 (S)70-130
110111Toluene-d8 (S)70-130
Page 6 of 6* QC Fail Date:08/09/2023 01:19 PM
Page 35 of 37
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:23-216-0004
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 0.1C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:08/04/2023 11:22:35
Special precautions or instructions included?
Comments:
Page 36 of 37
Page 37 of 37

APPENDIX C
AFVR Data, Calculations and Disposal Manifest
Site Name:42215
Extraction Well(s):2
6
Date :08/03/23 Start Time :7:15 End Time :15:15
Frequency
(min)Time Vacuum
(in. of Hg)
Exhaust
Velocity
(ft/min)
Temperature
(°F)
Rel. Humidity
(%)
OVA
(ppm)
0 7:15 21.0 352 80.8 100.0 351.9
15 7:30 21.0 463 83.6 100.0 334.1
30 7:45 21.0 302 93.4 100.0 274.6
45 8:00 21.0 312 89.3 100.0 1,510.0
60 8:15 21.0 236 97.8 100.0 2,061.0
75 8:30 21.0 214 100.3 100.0 1,923.0
90 8:45 21.0 236 102.3 100.0 1,894.0
105 9:00 21.0 292 102.6 100.0 1,821.0
120 9:15 21.0 280 106.2 100.0 1,739.0
150 9:45 21.0 310 113.2 100.0 1,860.0
180 10:15 21.0 326 108.2 94.6 1,721.0
210 10:45 21.0 288 106.3 98.2 1,633.0
240 11:15 21.0 291 102.1 100.0 1,610.0
270 11:45 21.0 283 109.3 100.0 1,562.0
300 12:15 21.0 279 108.4 100.0 1,579.0
330 12:45 21.0 227 116.9 100.0 1,584.0
360 13:15 21.0 216 110.8 100.0 1,562.0
390 13:45 21.0 212 111.0 100.0 1,520.0
420 14:15 21.0 217 106.3 100.0 1,431.0
450 14:45 21.0 206 113.8 100.0 1,440.0
480 15:15 21.0 216 118.0 100.0 1,412.0
Total Liquids Recovered (in gallons) :
Total Product Recovered (in gallons) :
Note: Take all the readings listed below every 15 minutes for the first 2 hours of the AFVR and every
30 minutes thereafter.
1400 CFM @ 21 in./HgBlower Specifications For Vacuum Truck (e.g: 2500 cfm @ 24 in. of Hg):
0
AGGRESSIVE FLUID VAPOR RECOVERY EVENT - DATA SHEET
Diameter of Exhaust Stack (inches) :
Eastern Environmental
Geological Resources, Inc.
Test Conducted By (AFVR Contractor):
Test Supervised By (Consultant):
600
Jimmy's Gas Mart Incident Number:
Inner Dia. of Well (inches):MW-4, MW-8
Site Name:42215
Extraction Well(s):2
6
Date :08/03/23 Start Time :7:15 End Time :15:15
1400 CFM @ 21 in./HgBlower Specifications For Vacuum Truck (e.g: 2500 cfm @ 24 in. of Hg):
AGGRESSIVE FLUID VAPOR RECOVERY EVENT - DATA SHEET
Diameter of Exhaust Stack (inches) :
Eastern Environmental
Geological Resources, Inc.
Test Conducted By (AFVR Contractor):
Test Supervised By (Consultant):
Jimmy's Gas Mart Incident Number:
Inner Dia. of Well (inches):MW-4, MW-8
AFVR Well Obs. Well 1 Obs. Well 2 Obs. Well 3 Obs. Well 4
Well Name MW-4, MW-8
Diameter (in.)2
Distance from
AFVR Well (ft)0
Frequency
(min)Time MW-4, MW-8
Pre AFVR 8:00 12.91 12.42
60 8:15
120 9:15
180 10:15
240 11:15
300 12:15
360 13:15
420 14:15
480 15:15
Post AFVR 15:30 19.04 19.92
Note: Record water levels in Vacuum Well at start and end of AFVR.
Depth to Water Measurements (in feet)
Site Name:42215
Extraction Well(s):2
6
Date:Start Time:End Time :
AIR FLOW CALCULATIONS
Date Time Vacuum
(in. Hg)
Velocity
(ft/min)
Pipe ID
(in.)
Temp
(°F)
Rel Humid
(%)
Water Vapor
(%)
Flow
(DSCFM)
7:15 21.0 352 6 80.8 100.0 0.0233 66
7:30 21.0 463 6 83.6 100.0 0.0256 86
7:45 21.0 302 6 93.4 100.0 0.0354 55
8:00 21.0 312 6 89.3 100.0 0.0309 57
8:15 21.0 236 6 97.8 100.0 0.0408 42
8:30 21.0 214 6 100.3 100.0 0.0442 38
8:45 21.0 236 6 102.3 100.0 0.0472 41
9:00 21.0 292 6 102.6 100.0 0.0476 51
9:15 21.0 280 6 106.2 100.0 0.0534 49
9:45 21.0 310 6 113.2 100.0 0.0667 52
10:15 21.0 326 6 108.2 94.6 0.0539 56
10:45 21.0 288 6 106.3 98.2 0.0526 50
11:15 21.0 291 6 102.1 100.0 0.0469 51
11:45 21.0 283 6 109.3 100.0 0.0590 48
12:15 21.0 279 6 108.4 100.0 0.0573 48
12:45 21.0 227 6 116.9 100.0 0.0750 38
13:15 21.0 216 6 110.8 100.0 0.0619 37
13:45 21.0 212 6 111.0 100.0 0.0622 36
14:15 21.0 217 6 106.3 100.0 0.0536 38
14:45 21.0 206 6 113.8 100.0 0.0680 35
15:15 21.0 216 6 118.0 100.0 0.0776 36
21.0 274 6 103.8 99.7 0.0516 48
NOTES
Qstd = (1-Water Vapor) * velocity * (PI * (diameter/24)^2) * (528°R/(Temp + 460)) (DSCFM)
Vacuum = The level of vacuum being applied should be recorded from the vacuum truck tank (inches of Hg)
Velocity = The rate at which air flows is measured at the blower discharge piping (anemometer or pitot tube)
Pipe ID = The inside diameter of the blower discharge piping (from the vacuum truck)
Temperature = The temperature of the air stream exiting the blower discharge piping (dry bulb temp., in deg.°F)
Relative humidity = The % relative humidity of the air stream exiting the blower discharge piping
Water Vapor in % = Pounds of water per pound of dry air, derived from the Psychrometric chart
(temp Vs relative humidity)
DSCFM = Dry Standard Cubic Feet Per Minute
AGGRESSIVE FLUID VAPOR RECOVERY EVENT - CALCULATIONS
Averages
Jimmy's Gas Mart
Blower Specifications For Vacuum Truck (e.g: 2500 cfm @ 24 in. of Hg):1400 CFM @ 21 in./Hg
Test Conducted By (AFVR Contractor):
Test Supervised By (Consultant):
Eastern Environmental
Geological Resources, Inc.
Diameter of Exhaust Stack (inches) :
Inner Dia. of Well (inches):MW-4, MW-8
Incident Number:
08/03/23
185Site Elevation (feet):
15:157:1508/03/23
Site Name:42215
Extraction Well(s):2
6
Date:Start Time:End Time :
AGGRESSIVE FLUID VAPOR RECOVERY EVENT - CALCULATIONS
Jimmy's Gas Mart
Blower Specifications For Vacuum Truck (e.g: 2500 cfm @ 24 in. of Hg):1400 CFM @ 21 in./Hg
Test Conducted By (AFVR Contractor):
Test Supervised By (Consultant):
Eastern Environmental
Geological Resources, Inc.
Diameter of Exhaust Stack (inches) :
Inner Dia. of Well (inches):MW-4, MW-8
Incident Number:
185Site Elevation (feet):
15:157:1508/03/23
EMISSION CALCULATIONS
Elapsed Time
(min)
Flow
(DSCFM)
PPM
measured
(ppm)
K
(#C-gas)PPMg Cg:m
(mg/dsm^3)
Cg
(lb/dscf)
PMRg
(lb/hr)
PMR
(lb)
0 66 351.9 4 1,407.6 7,485.37 0.00046731 1.85 0.00
15 86 334.1 4 1,336.4 7,106.74 0.00044367 2.29 0.57
30 55 274.6 4 1,098.4 5,841.10 0.00036466 1.19 0.30
45 57 1,510.0 4 6,040.0 32,119.65 0.00200523 6.87 1.72
60 42 2,061.0 4 8,244.0 43,840.13 0.00273694 6.91 1.73
75 38 1,923.0 4 7,692.0 40,904.69 0.00255368 5.80 1.45
90 41 1,894.0 4 7,576.0 40,287.83 0.00251517 6.26 1.56
105 51 1,821.0 4 7,284.0 38,735.02 0.00241823 7.44 1.86
120 49 1,739.0 4 6,956.0 36,990.78 0.00230933 6.72 1.68
150 52 1,860.0 4 7,440.0 39,564.60 0.00247002 7.75 3.88
180 56 1,721.0 4 6,884.0 36,607.89 0.00228543 7.72 3.86
210 50 1,633.0 4 6,532.0 34,736.02 0.00216857 6.50 3.25
240 51 1,610.0 4 6,440.0 34,246.78 0.00213803 6.56 3.28
270 48 1,562.0 4 6,248.0 33,225.76 0.00207428 6.04 3.02
300 48 1,579.0 4 6,316.0 33,587.37 0.00209686 6.04 3.02
330 38 1,584.0 4 6,336.0 33,693.73 0.00210350 4.76 2.38
360 37 1,562.0 4 6,248.0 33,225.76 0.00207428 4.58 2.29
390 36 1,520.0 4 6,080.0 32,332.36 0.00201851 4.37 2.19
420 38 1,431.0 4 5,724.0 30,439.22 0.00190032 4.29 2.14
450 35 1,440.0 4 5,760.0 30,630.66 0.00191227 3.98 1.99
480 36 1,412.0 4 5,648.0 30,035.06 0.00187509 4.02 2.01
Averages 48 1,467.7 4 5,871.0 31,220.79 0.00194911 5.33 2.10
Total emissions (gal):7.07 Total emissions (lbs):44.17
NOTES
PPM measured = Actual measurements (ppm) taken with a OVA or TVA at the blower discharge piping
K = Number of carbons in calibration gas: (Methane K = 1, or Propane K = 3, or Hexane K = 6)
PPMg = PPMv, Volumetric concentration as gasoline emission, dry basis at STP
Cg:m = mg/dsm3, mass concentration of gasoline emission
Mg = 128 mg/mg-mole, molecular weight of gasoline (this value may vary depending on contaminant)
K3 = 24.07 dsm^3/1E6 mg-mole, mass to volume conversion factor at STP
Cg = lb/dcsf, mass concentration of gasoline emission, dry basis at STP
PMRg = lb/hr, pollutant mass removal rate of gasoline emission
PMR = pollutant mass removal of gasoline emission over time
EQUATIONS
PPMg = PPM measured * K
Cg:m = PPMg * (Mg / K3)
Cg = Cg:m * 62.43E-09 lb-m^3/mg-ft^3
PMRg = Cg * Qstd * 60 min/hr
PMR = PMRg * ((T2 - T1) / 60)
Total emmissions (gal) = Total emmissions (lbs)/6.25