FA-7725_42006_CA_MRP_20230728

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]

July 28, 2023

Mr. Ken Currie
NCDEQ-UST Section
Fayetteville Regional Office
Systel Building
225 Green Street, Suite 714
Fayetteville, NC 28301-5043

Re: Ground Water Monitoring Report
June 2023
Cruz N Mart
6500 Andrew Jackson Highway
Laurel Hill, Scotland County,
North Carolina
Facility ID Number: 0-00-0000009383
Incident Number: 42006
GRI Project Number: 3787

Dear Mr. Currie,

Please find attached the referenced report for the above mentioned site.
If you have any questions, please contact Scott Driscoll at 704-845-4010.

Sincerely,
Geological Resources, Inc.

Johanna Moats
AP/AR Coordinator

Enclosure

Cc: Mr. Teddy Norton, file

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Ground Water Monitoring Report
June 2023
Cruz N Mart
6500 Andrew Jackson Highway
Laurel Hill, Scotland County, North Carolina
Facility ID Number: 0-00-0000009383
Incident Number: 42006
GRI Project Number: 3787

Prepared for:

Teddy D. Norton
12820 Pinewood Trail
Laurinburg, North Carolina 28352

July 28, 2023

Scott Driscoll
Project Manager
Sharon Lowther
Report Writer

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: July 28, 2023 Cruz N Mart
Project Manager: Scott Driscoll GRI Project No. 3787
i
SITE INFORMATION
1. Site Identification
 Cruz N Mart (Facility ID 0-00-0000009383)
 Incident Number 42006 – High Risk (H305A)
 Location of Source Area: 6500 Andrew Jackson Highway
Laurel Hill, NC 28314
Scotland County
34.827313°N, 79.591042°W (Topographical Map)
2. Information about Contacts Associated with the Leaking UST System

UST Owner
Teddy D. Norton
12820 Pinewood Trail
Laurinburg, NC 28352
[e-mail]
910-610-5149

UST Operator
Teddy D. Norton
12820 Pinewood Trail
Laurinburg, NC 28352
[e-mail]
910-610-5149

Property Owner
Teddy D. Norton
12820 Pinewood Trail
Laurinburg, NC 28352
[e-mail]
910-610-5149

Property Occupant
Cruz N Mart
6500 Andrew Jackson Highway
Laurel Hill, NC 28351
[e-mail]
910-610-5149

Consultant/Contractor
Geological Resources, Inc.
3502 Hayes Road
Monroe, NC 28110
[e-mail]
704-845-4010

Analytical Laboratory
Waypoint Analytical
449 Springbrook Road
Charlotte, NC 28217
NC Cert No. 402/37735
704-529-6364
3. Information about Release
 Release was discovered on September 16, 2016
 An unknown amount of product was released from the leaking UST System
 One 6,000-gallon gasoline UST and one 20,000-gallon compartmentalized gasoline UST (14,000
and 6,000-gallon) are currently in operation at the site. Two 4,000-gallon gasoline USTs and one
550-gallon kerosene UST were removed from the site on September 16, 2016

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: July 28, 2023 Cruz N Mart
Project Manager: Scott Driscoll GRI Project No. 3787
ii
EXECUTIVE SUMMARY
Cruz N Mart is located at 6500 Andrew Jackson Highway in Laurel Hill, Scotland County, North Carolina.
The site is currently owned and operated by Teddy D. Norton as a petroleum retail facility. A release was
discovered at the site in September 2016 during the closure of two 4,000-gallon gasoline USTs and one
550-gallon kerosene UST. Currently, one 6,000-gallon gasoline UST and one 20,000-gallon two
compartment gasoline UST (14,000 and 6,000-gallon) are active at the site. The adjoining properties are
a mixture of commercial and residential properties.

According to the information determined during receptor survey activities, twelve potable water supply
wells were identified within a 1,000-foot radius of the source area. Of the twelve water supply wells,
there are three potable wells located within 250 feet of the source area. Public water is available to the
site and surrounding properties within a 1,500-foot radius of the site.

A CSA was completed between February and April 2018 and an additional phase of the CSA was completed
in October 2019. The CSA concluded that the groundwater contaminant plume remains undefined to the
south and southeast and the site is classified as High Risk due to eleven potable water supply wells located
within 1,000 feet of the source area. A CAP has not been developed for this incident.

In February 2020, an attempt to lower the risk ranking of the site was made by obtaining permission to
connect potable water supply wells users located within a 1,000-foot radius of site to municipal water.
Water connection agreements were obtained from the owner of WSW-1, WSW-2 and WSW-9; however,
the owner of WSW-3 did not grant permission for switching over to municipal water. A well agreement
to connect WSW-OX is incomplete pending additional discussion with the property owner.

On June 27, 2023, six monitoring wells were gauged, purged and sampled. No free product was observed
at the site. Concentrations of benzene, toluene, xylenes, MTBE, naphthalene, tert- amyl alcohol (TAA),
tert-butyl alcohol (TBA), n-propylbenzene, 1,2,4-trimethylbenzene and/or 1,3,5-trimethylbenzene that
exceeded the MACs were reported in the ground water samples collected from MW-1, MW-2, MW-3, and
MW-5. All of the reported contaminant concentrations were less than the GCLs. Contaminant mass at
the site has decreased by 26% between October 2019 and June 2023.

Based on the information, the previously submitted TA for connecting WSW-1, WSW-2 and WSW-9 to the
municipal connection and/or abandonment should proceed. Contaminant Fate & Transport modelling
should be completed in relation to WSW-3 to determine if the well is at risk as the well is located outside
of 250 feet and cross-gradient from the source area.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: July 28, 2023 Cruz N Mart
Project Manager: Scott Driscoll GRI Project No. 3787
iii
ACRONYMS
ACM: Asbestos Containing Materials
AFVR: Aggressive Fluid-Vapor Recovery
ARR: Acknowledgement of Report Receipt
AS: Air Sparging
AST: Aboveground Storage Tank
ASTM: American Society for Testing and
Materials
BGS: Below Ground Surface
CAP: Corrective Action Plan
CFR: Code of Federal Regulations
CSA: Comprehensive Site Assessment
DPE: Dual Phase Extraction
DRO: Total Petroleum Hydrocarbons Diesel
Range Organics
DWM: Division of Waste Management
DWR: Department of Water Resources
EPA: Environmental Protection Agency
EPH: Extractible Petroleum Hydrocarbons
ESA: Environmental Site Assessment
GCL: Gross Contamination Level
GRI: Geological Resources, Inc.
GRO: Total Petroleum Hydrocarbons
Gasoline Range Organics
LSA: Limited Site Assessment
MAC: Maximum Allowable Concentration as
specified in T15A NCAC 2L.0202
MADEP: Massachusetts Department of
Environmental Protection
MCC: Maximum Contaminant Concentrations
MMPE: Mobile Multi-Phase Extraction
NAPL: Non-Aqueous Phase Liquid, “Free
Product”
NCDEQ: North Carolina Department of
Environmental Quality
NCDOT: North Carolina Department of
Transportation
NFA: Notice of No Further Action
NORR: Notice of Regulatory Requirements
NOV: Notice of Violation
NPDES: National Pollutant Discharge
Elimination System
NRP: Notice of Residual Petroleum
O&M: Operation and Maintenance
PAHs: Polynuclear Aromatic Hydrocarbons
PCA: Pre-Construction Assessment
RAL: Regulatory Action Level
SCLs: Soil Cleanup Level
SPCC: Spill Prevention Control and
Countermeasures
SVE: Soil Vapor Extraction
SVOCs: Semi-Volatile Organic Compounds
SWAP: Source Water Assessment and
Protection
SWPPP: Stormwater Pollution Prevention Plan
TCLP: Toxicity Characteristic Leaching
Procedure (EPA Method SW-846 1311)
TOC: Top of Casing
TPH: Total Petroleum Hydrocarbons
USGS: United States Geological Survey
UST: Underground Storage Tank
UVF: Ultraviolet Fluorescence
VOCs: Volatile Organic Compounds
VPH: Volatile Petroleum Hydrocarbons

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: July 28, 2023 Cruz N Mart
Project Manager: Scott Driscoll GRI Project No. 3787

TABLE OF CONTENTS
SITE INFORMATION ............................................................................................................................ i
EXECUTIVE SUMMARY ....................................................................................................................... ii
ACRONYMS ....................................................................................................................................... iii
1.0 SITE HISTORY AND CHARACTERIZATION ...................................................................................1
2.0 PRESENTATION OF CURRENT SITE ASSESSMENT INFORMATION/ COMPARISON TO HISTORICAL
ASSESSMENT INFORMATION ...................................................................................................2
3.0 FREE PRODUCT REMOVAL ........................................................................................................4
4.0 NATURAL ATTENUATION / NATURAL SOURCE ZONE DEPLETION STATUS ..................................4
5.0 CONCLUSIONS .........................................................................................................................4
6.0 LIMITATIONS ...........................................................................................................................5
7.0 STATEMENTS AND CERTIFICATION ...........................................................................................5

FIGURES
Figure 1: Site Location Map
Figure 2: Site Map
Figure 3: Site Vicinity Map
Figure 4: Water Table Surface Map
Figure 5: Ground Water Quality Map
Figure 6: Estimated Contaminant Mass Area Map

TABLES
Table 1: UST Owner and Operator Information
Table 2: UST System Information
Table 3: Water Supply Well Information
Table 4: Adjacent Property Owner Information
Table 5: Well Construction and Gauging Information
Table 6: Summary of Ground Water Sample Analytical Results

APPENDICES
Appendix A: State Correspondence
Appendix B: Laboratory Report – Ground Water Samples
Appendix C: Contaminant Mass Calculations
Appendix D: Right to Enter Agreement

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: July 28, 2023 Cruz N Mart
Project Manager: Scott Driscoll GRI Project No. 3787
1
1.0 SITE HISTORY AND CHARACTERIZATION
GRI presents the results of the June 2023 ground water sampling event at the Cruz N Mart site; located at
6500 Andrew Jackson Highway in Laurel Hill, Scotland County, North Carolina. A topographic map showing
the general site location and the surrounding area is included as Figure 1. These activities were conducted
in accordance with GRI Proposal No. 23-196, which was submitted to NCDEQ on March 14, 2023, and was
approved as Task Authorization No. 42006-12 on March 16, 2023. State correspondence is included as
Appendix A.

The site is currently owned and operated by Teddy D. Norton as a petroleum retail facility. Currently, one
6,000-gallon gasoline UST and one 20,000-gallon compartmentalized gasoline UST (compartments sized
14,000 and 6,000-gallon) are active at the site. Two 4,000-gallon gasoline USTs and one 550-gallon
kerosene UST were removed from the site on September 16, 2016. A release was discovered during the
September 2016 UST closure activities. UST owner/operator information and UST system information are
included as Table 1 and Table 2, respectively. The Registered Tank Report is shown below:

The site and surrounding area are a mixture of commercial and residential properties. The site contains
one building and is primarily capped with concrete and asphalt. The overall topography at the site is
relatively flat. No surface water bodies were identified within a 500-foot radius of the site. Eleven Type
II monitoring wells (MW-1 through MW-11) were installed at the site during previous ground water
assessment activities. A Site Map showing the locations of the monitoring wells and the structures on-
site is included as Figure 2.

On December 12, 2016, GRI personnel conducted a receptor survey at the site. Eleven potable water
supply wells were identified within a 1,000-foot radius of the source area. An additional water supply well
within a 1,000-foot radius of the source area, WSW-OX, was identified on May 31, 2022, when GRI

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: July 28, 2023 Cruz N Mart
Project Manager: Scott Driscoll GRI Project No. 3787
2
received a well survey from the property owner in response to the December 2016 receptor survey. Of
the twelve water supply wells, there are three potable wells located within 250 feet of the source area.
Municipal water is available to the site and surrounding properties. No surface water bodies were
identified within a 500-foot radius of the site. Water supply well information is included in Table 3.
Adjacent property owner information is included in Table 4. A Site Vicinity Map showing the locations of
water supply wells and adjacent properties is included as Figure 3.

A CSA was completed between February and April 2018 and an additional phase of the CSA was completed
in October 2019. The CSA concluded that the groundwater contaminant plume remains undefined to the
south and southeast and the site is classified as High Risk. A CAP has not been developed and no projected
milestones have been established.

In February 2020, an attempt to lower the risk ranking of the site was made by obtaining permission to
connect users of potable water supply wells located within a 1,000-foot radius of site to municipal water.
Water connection agreements were obtained from the owner of WSW-1, WSW-2 and WSW-9; however,
the owner of WSW-3 did not grant permission for switching over to municipal water. A well agreement
to connect WSW-OX is incomplete pending additional discussion with the property owner.
2.0 PRESENTATION OF CURRENT SITE ASSESSMENT INFORMATION/ COMPARISON TO HISTORICAL
ASSESSMENT INFORMATION
On June 27, 2023, six Type II monitoring wells (MW-1 through MW-6) were gauged, purged and sampled.
Depths to ground water in the Type II monitoring wells ranged from 2.16 feet to 40.74 feet below the tops
of well casings. Ground water elevations in the Type II monitoring wells ranged from 58.62 feet to 97.71
feet. Please note, MW-1, MW-2 and MW-4 were drilled to total depths of 25 feet, each and appear to be
set in a perched water bearing zone that differs from the water table depths in other portions of the
assessed area. The septic drain field is located adjacent to the area of these wells and just south of the
UST basin. The possibility exists that drain field may be contributing and/or influencing the shallow water
bearing zone around these wells. Ground water flow for the deeper Type II monitoring wells (MW-3,
MW-5 and MW-6) was generally toward the east with an average horizontal hydraulic gradient of
approximately 0.01 feet per foot. Well construction and gauging information is included in Table 5. A
Water Table Surface Map based on June 2023, data is included as Figure 4. A summary of the current
ground water gauging data is shown below:

Well ID
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(feet)
Free
Product
Thickness
(ft.)
Ground
Water
Elevation
(ft.)
MW-1 10 - 20 20 100.00 17.54 --- 82.46
MW-2 10 - 25 25 99.66 17.46 --- 82.20
MW-3 25 - 50 50 99.82 40.74 --- 59.08
MW-4 2 - 22 22 99.87 2.16 --- 97.71
MW-5 20 - 40 40 98.82 31.31 --- 67.51
MW-6 25 - 50 50 98.14 39.52 --- 58.62

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: July 28, 2023 Cruz N Mart
Project Manager: Scott Driscoll GRI Project No. 3787
3
Ground water samples collected from the monitoring wells were submitted for laboratory analyses using
EPA Method 6200B. No free product was observed at the site. Concentrations of benzene, toluene,
ethylbenzene, xylenes, naphthalene, tert-amyl alcohol (TAA), tert-butyl alcohol (TBA), isopropylbenzene,
n-propylbenzene, 1,2,4-trimethylbenzene and/or 1,3,5-trimethylbenzene that exceeded the MACs were
reported in the ground water samples collected from MW-1, MW-2, MW-3, and MW-5. All the reported
contaminant concentrations were less than the GCLs. A summary of the analytical results for ground water
samples collected on June 27, 2023 are presented in Table 6. A Ground Water Quality Map based on the
June 2023 data is included as Figure 5. A complete report of laboratory analyses of the ground water
samples collected from the monitoring wells during the June 2023 sampling event is included as Appendix
B. An abbreviated summary of the current ground water analytical data is shown below:

Contaminant
of Concern

Be
n
z
e
n
e

To
l
u
e
n
e

Et
h
y
l
b
e
n
z
e
n
e

Xy
l
e
n
e
s

MT
B
E

Na
p
h
t
h
a
l
e
n
e

Well ID
MAC (µg/l) 1 600 600 500 20 6
GCL (µg/l) 5,000 260,000 80,000 50,000 20,000 6,000
MW-1 169 16.5 88.1 160 <1.40 41.0
MW-2 810 1,090 782 3,820 <14.0 548
MW-3 7.59 <0.220 <0.170 <0.210 0.523 J <0.470
MW-4 0.498 J 54.2 <0.170 <0.210 <0.140 <0.470
MW-5 1,010 2,730 789 2,780 <14.0 352
MW-6 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470
WSW-OX <0.180 <0.220 <0.170 <0.210 <0.140 <0.470

The baseline contaminant mass at the site was determined based on the total BTEX, MTBE and
naphthalene concentrations from the October 2019 ground water sampling event, as well as the
maximum historical water column height observed in each area. The contaminant mass has been reduced
by 26% between October 2019 and June 2023. Contaminant mass calculations are included as Appendix
C. A map of the contaminant mass areas is included as Figure 6.

A chart depicting the overall declining trend in contaminant mass is shown below:

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: July 28, 2023 Cruz N Mart
Project Manager: Scott Driscoll GRI Project No. 3787
4

The site is located in the Coastal Plain Physiographic Province of North Carolina. The water table for wells
installed to 40 to 50 feet below grade has a seasonal high depth to water of approximately 25 feet BGS.
3.0 FREE PRODUCT REMOVAL
Free product has not been observed at the site.
4.0 NATURAL ATTENUATION / NATURAL SOURCE ZONE DEPLETION STATUS
No natural attenuation monitoring plan is currently in place at the site.
5.0 CONCLUSIONS
 On June 27, 2023, six Type II monitoring wells were gauged, purged, and sampled. There appears
to be a perched water zone in the vicinity of MW-1, MW-2 and MW-4. Ground water flow for the
deeper Type II monitoring wells was generally toward the east horizontal hydraulic gradient of
approximately 0.01 feet per foot.
 Concentrations of benzene, toluene, ethylbenzene, xylenes, naphthalene, tert-amyl alcohol
(TAA), tert-butyl alcohol (TBA), isopropylbenzene, n-propylbenzene, 1,2,4-trimethylbenzene
and/or 1,3,5-trimethylbenzene that exceeded the MACs were reported in the ground water
samples collected from MW-1, MW-2, MW-3, and MW-5. All the reported contaminant
concentrations were less than the GCLs.
0.00
1.00
2.00
3.00
4.00
5.00
6.00
7.00
8.00
9.00
10.00
0
100
200
300
400
500
600
700
800
900
Av
e
r
a
g
e

W
a
t
e
r

C
o
l
u
m
n

H
e
i
g
h
t

(
f
t
)
Co
n
t
a
m
i
n
a
n
t

M
a
s
s

(
g
r
a
m
s
)
Time
Total Contaminant Mass vs. Time
Cruz N Mart (Incident No. 42006)
Contaminant Mass (grams)Water Column Height (ft)Linear (Contaminant Mass (grams))

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: July 28, 2023 Cruz N Mart
Project Manager: Scott Driscoll GRI Project No. 3787
5
 Contaminant mass has decreased by 26% between October 2019 and June 2023.
 Based on the information, the previously submitted TA for connecting WSW-1, WSW-2 and WSW-
9 to the municipal water supply and/or abandonment should proceed. Contaminant Fate &
Transport modelling should be completed in relation to WSW-3 to determine if the well is at risk
as the well is located outside of 250 feet and cross-gradient from the source area.
 Semi-annual ground water sampling should also continue at the site with the next sampling event
tentatively scheduled for December 2023.
6.0 LIMITATIONS
This report has been prepared for the exclusive use of Teddy D. Norton for specific application to the
referenced site in Scotland County, North Carolina. The assessment was conducted based on the scope
of work and level of effort desired by NCDEQ and with resources adequate only for that scope of work.
Our findings have been developed in accordance with generally accepted standards of environmental
practices in the State of North Carolina, available information, and our professional judgment. No other
warranty is expressed or implied.

The data that are presented in this report are indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would
be interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from these data.
7.0 STATEMENTS AND CERTIFICATION
1 Enter the date the monitoring report was due. N/A Will this report be submitted after the
established due date?
YES NO
2 Was any required information from the above template missing from this report? YES NO
IF the answer to question #1 or# 2 is “YES”, please provide additional information in this cell to explain
what was missing and why.
3 If applicable, will any of the proposed attenuation milestones under the schedule approved
in the Corrective Action Plan not be met? (within a reasonable margin of error)
YES NO
IF the answer to question #3 is “NO”, skip to the certification under #8 below.
IF the answer to question #3 is “YES”, please generally describe in this cell the possible reason(s) and
outline proposed remedies. (This should be described in more detail in the report text above.)

N/A
4 Does any known or suspected source zone soil contamination or free product remain
outside of the assessed area that could be inhibiting natural attenuation?
YES NO
5 Has there been an unexpected increase in contaminant mass sufficient to suggest a
potential new release from a separate onsite or offsite source?
YES NO

___________________________________________________________________________________________
Preparedby:GeologicalResources,Inc.GroundWaterMonitoringReport
Preparedon:July28,2023CruzNMart
ProjectManager:ScottDriscollGRIProjectNo.3787
6
IF the answer to either question #4 or #5 is “YES”, generally describe in this cell any actions
recommendedtofurtherassessorcleanupthisknownorsuspectedsource.(Thisshouldbedescribed
inmoredetailinthereporttextabove.)

6Certification:
I,SamuelL.McKay,III,aLicensedGeologistforGeologicalResources,Inc.,docertifythattheinformation
containedinthisreportiscorrectandaccuratetothebestofmyknowledge.

GeologicalResources, Inc.is licensed to practiceengineering and geologyin North Carolina. The
certificationnumberofthecompanyorcorporationisC-2727/C-127.

FIGURES
SITE LOCATION
Figure 1
Site Location
Cruz N Mart ( Ole Time General Store)
6500 Andrew Jackson Highway
Laurel Hill, North Carolina
Scotland County
Incident No. 42006
GRI Project No. 3787
500 M
2000 FT
Date: 05/15/2022 Location: 34.827313° N -79.591042° W
D
a
d
JULY 24, 2023

TABLES
UST ID Number 1 - 3 Facility ID Number
Owner or Operator?
Owner/Operator
UST ID Number 1-3 Facility ID Number
Owner or Operator?
Owner/Operator
UST ID Number 5, A1A and A1B Facility ID Number
Owner or Operator?
Owner/Operator
12820 Pinewood Trail, Laurinburg, NC 28352 910-610-5149
00-0-0000009383
Name of Owner or Operator Dates of Ownership / Operation
Teddy D. Norton 9/15/16 - Current
Address Telephone Number
12820 Pinewood Trail, Laurinburg, NC 28352 910-610-5149
Address Telephone Number
Gibson Oil & Gas Company, Inc.4/9/1984 - 10/27/2010
Address Telephone Number
9340 Morgan Street, Laurel Hill, NC 28351 910-462-2155
00-0-0000009383
Name of Owner or Operator Dates of Ownership / Operation
Teddy D. Norton 10/27/2010 - 9/16/2016
Name of Owner or Operator Dates of Ownership / Operation
TABLE 1
UST OWNER/OPERATOR INFORMATION
CRUZ N MART (INCIDENT NO. 42006)
00-0-0000009383
Page 1 of 1
Date: 4/10/17
Was Release
Associated
with UST
System?
(Yes / No)
1 Gasoline Gasoline 4,000 Single Wall
Steel 64" x 24'Single Wall
Steel Yes
2 Gasoline Gasoline 4,000 Single Wall
Steel 64" x 24'Single Wall
Steel Yes
3 Kerosene Kerosene 550 Single Wall
Steel 46" x 74"Single Wall
Steel Yes
5 Gasoline Gasoline 6,000 Unknown 8' x 16'Unknown Active
A1A Gasoline Gasoline 14,000 Active
A1B Gasoline Gasoline 6,000 Active
Removed
(9/16/16)
9/15/2016
4/9/1984
Unknown10' 6" x 30' 11.5"Unknown
Tank
Dimensions
Description of
Associated
Product Piping
and
Pumps
Status
of
UST
TABLE 2
UST SYSTEM INFORMATION
CRUZ N MART (INCIDENT NO. 42006)
Facility ID #: 00-0-0000009383
UST
ID
No.
Current
or Most
Recent
Contents
Previous
Contents
Capacity
(gallons)
Date
Installed
Construction
Details
Page 1 of 1
Well No.PIN Well Owner Mailing Address Well Location Address Phone Number
Public
Water
Available
Reading
Well Use
(Potable/
Agricultural,
etc.)
Well
Depth
(ft BGS)
Type of
Well
(Drilled/
Bored)
Well
Casing
Depth
(ft. BGS)
Well
Screen
Interval
(x to y ft.
BGS)
Approximate
Distance from
source area
(ft.)
WSW-1 4017802008 Teddy D. Norton 12820 Pinewood Trail
Laurinburg, NC 28352
6440 Andrew Jackson Highway
Laurel Hill, NC 28351 910-610-5149 Yes No Potable Unk Unk Unk Unk 190' W
WSW-2 04017803012 Teddy D. Norton 12820 Pinewood Trail
Laurinburg, NC 28352
19421 Corbitt Road
Laurel Hill, NC 28351 910-610-5149 Yes No Potable 110 Unk 90 20 290' S
WSW-3 4017803014 Charles A. &
Elizabeth Morgan
19381 Corbitt Road
Laurel Hill, NC 28351
19381 Corbitt Road
Laurel Hill, NC 28351 910-462-4294 Yes No Potable Unk Unk Unk Unk 350' S
WSW-4 4017802026 Charles Morgan 6741 Andrew Jackson Highway
Laurel Hill, NC 28351
6421 Marsh Road
Laurel Hill, NC 28351 910-462-2993 Yes No Potable Unk Unk Unk Unk 510' W
WSW-5 4017802016 Gary Woodard 6361 Marsh Road
Laurel Hill, NC 28351
6361 Marsh Road
Laurel Hill, NC 28351 Unk Yes No Potable Unk Unk Unk Unk 750' NW
WSW-6 4017802018 Carolyn Denise Hewitt 18001 Poplar Street
Laurinburg, NC 28352
6260 Marsh Road
Laurel Hill, NC 28351 Unk Yes No Potable Unk Unk Unk Unk 940' W
WSW-7 4017801007 Ricardo Alberto Huerta 19801 Old Hundred Road
Laurel Hill, NC 28351
19801 Old Hundred Road
Laurel Hill, NC 28351 Unk Yes No Potable Unk Unk Unk Unk 600' N
WSW-8 4017802007 Amber Charity Locklear
& Betty K. Covington
19500 Corbitt Road
Laurel Hill, NC 28351
6460 Andrew Jackson Highway
Laurel Hill, NC 28351 Unk Yes No Potable Unk Unk Unk Unk 350' NW
WSW-9 4017802027 Teddy D. Norton 12820 Pinewood Trail
Laurinburg, NC 28352
19460 Corbitt Road
Laurel Hill, NC 28351 910-610-5149 Yes No Potable 120 Unk Unk Unk 230' W
WSW-10 4017801004 Eugene W.
Blackwelder, Jr.
6360 Peeles Chapel Road
Laurel Hill, NC 28351
19760 Old Hundred Road & 6881
Andrew Jackson Highway
Laurel Hill, NC 28351
910-217-0359 Yes No Potable 100 Unk Unk Unk 570' N
WSW-11 4017801033 Freddie Davis 6361 Peele's Chapel Road
Laurel Hill, NC 28351
19742 & 19762 Old Hundred Road
Laurel Hill, NC 28351 910-462-2346 Yes No Potable 120 Unk Unk Unk 650' NW
WSW-OX 4017803002 Sybil Oxendine & Jillian
Wright
6540 Andrew Jackson Highway
Lauren Hill, NC 28351
6540 Andrew Jackson Highway
Lauren Hill, NC 28351 910-434-3594 No No Potable Unk Unk Unk Unk 127' SW
Notes:
• Water supply wells are shown on Figure 3.
• Reading: Residence subscribes to municipal water.
• n/a: not applicable.
• UK: Unknown.
TABLE 3
WATER SUPPLY WELL INFORMATION
CRUZ N MART (INCIDENT NO. 42006)
Date : 04/10/17 Facility ID #: 00-0-0000009383
Page 1 of 1
Date: 04/10/17 Facility ID #: 00-0-0000009383
Pin Number Property Owner Name Address
04017803001 (site)Teddy D. and Patricia K Norton 12820 Pinewood Trail
Laurinburg, NC 28352
04017803019 Teddy D. Norton 12820 Pinewood Trail
Laurinburg, NC 28352
4017803002 Sybil Oxendine and Jillian Wright 6540 Andrew Jackson Highway
Lauren Hill, NC 28351
4015701014 Pate Z V Inc.P.O. Box 159
Laurel Hill, NC 28351
4017802008 Teddy D. Norton 12820 Pinewood Trail
Laurinburg, NC 28352
Note:
• Properties are keyed to Figure 3.
TABLE 4
ADJACENT PROPERTY OWNER INFORMATION
CRUZ N MART (INCIDENT NO. 42006)
Page 1 of 1
Date: 07/14/2023
06/27/23 17.54 ---82.46
06/27/23 17.46 ---82.20
06/27/23 40.74 ---59.08
06/27/23 2.16 ---97.71
06/27/23 31.31 ---67.51
06/27/23 39.52 ---58.62
MW-1
99.662510 - 251003/09/17MW-2
100.002010 - 201012/12/16
TABLE 5
WELL CONSTRUCTION AND GAUGING INFORMATION
CRUZ N MART (INCIDENT NO. 42006)
Facility ID #: 0-009383
Well ID
Date
Installed
(mm/dd/yy)
Date Water Level
Measured
(mm/dd/yy)
Well Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation*
(ft.)
Depth to
Water from
Top of
Casing
Free Product
Thickness
(ft.)
Ground
Water
Elevation
(ft.)
Comments
98.82
5025 - 50MW-3 99.822503/23/18
203/09/17MW-4 99.87222 - 22
40
MW-6 25 - 502503/02/18
2002/14/18MW-5
98.1450
20 - 40
Page 1 of 1
Date: 07/21/2023 Facility ID #: 00-0-0000009383
SW846
6010D
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 40 10 70 70 3 100 6 70 25 70 400 400 0.98 1 30 15 400 700 200 700 10,000 200
5,000 260,000 80,000 50,000 20,000 6,000 40,000 10,000 6,900 8,500 3,000 NE 6,000 25,000 11,700 30,000 28,500 25,000 980 1,000 12,500 15,000 NE NE NE NE NE NE
06/27/23 169 16.5 88.1 160 <1.40 41.0 <19.0 39.2 J <1.80 6.75 <2.20 <2.00 <2.10 13.1 18.0 49.3 297 112 NR NR NR NR NR NR NR NR NR NR
06/27/23 810 1,090 782 3,820 <14.0 548 2,340 225 J <18.0 <20.0 <22.0 <20.0 <21.0 72.9 <8.90 176 1,580 436 NR NR NR NR NR NR NR NR NR NR
06/27/23 7.59 <0.220 <0.170 <0.210 0.523 J <0.470 <1.90 <1.60 <0.180 <0.200 <0.220 <0.200 <0.210 <0.180 <0.089 <0.190 <0.190 <0.180 NR NR NR NR NR NR NR NR NR NR
06/27/23 0.498 J 54.2 <0.170 <0.210 <0.140 <0.470 <1.90 <1.60 <0.180 <0.200 <0.220 <0.200 1.91 <0.180 1.77 <0.190 0.329 J <0.180 NR NR NR NR NR NR NR NR NR NR
06/27/23 1,010 2,730 789 2,780 <14.0 352 1,480 <1.60 <18.0 <20.0 <22.0 <20.0 <21.0 60.1 <8.90 168 1,450 372 NR NR NR NR NR NR NR NR NR NR
06/27/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <1.90 <1.60 <0.180 <0.200 <0.220 <0.200 <0.210 <0.180 <0.089 <0.190 0.478 J <0.180 NR NR NR NR NR NR NR NR NR NR
WSW-OX 06/27/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <1.90 <1.60 <0.180 <0.200 <0.220 <0.200 <0.210 <0.180 <0.089 <0.190 <0.190 <0.180 NR NR NR NR NR NR NR NR NR NR
06/27/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 NS NS <0.180 <0.200 <0.220 <0.200 <0.210 <0.180 <0.089 <0.190 <0.190 <0.180 NR NR NR NR NR NR NR NR NR NRTRIP BLANK
EPA 625 MADEP EPHMADEP VPH REV 1.1
C9
-
C
1
8

A
l
i
p
h
a
t
i
c
s
C1
9
-
C
3
6

A
l
i
p
h
a
t
i
c
s
C1
1
-
C
2
2

A
r
o
m
a
t
i
c
s
C5
-
C
8

A
l
i
p
h
a
t
i
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s
C9
-
C
1
2

A
l
i
p
h
a
t
i
c
s
C9
-
C
1
0

A
r
o
m
a
t
i
c
s
Le
a
d
1-
M
e
t
h
y
l
n
a
p
h
t
h
a
l
e
n
e
2-
M
e
t
h
y
l
n
a
p
h
t
h
a
l
e
n
e
2,
4
-
D
i
c
h
l
o
r
o
p
h
e
n
o
l
1,
3
,
5
-
Tr
i
m
e
t
h
y
l
b
e
n
z
e
n
e
1,
2
,
4
-
Tr
i
m
e
t
h
y
l
b
e
n
z
e
n
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n-
P
r
o
p
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b
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n
z
e
n
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Is
o
p
r
o
p
y
l
b
e
n
z
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n
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p-
I
s
o
p
r
o
p
y
l
t
o
l
u
e
n
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Ch
l
o
r
o
m
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t
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a
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(M
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t
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l

C
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)
2-
C
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n
e
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
TABLE 6
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
CRUZ N MART (INCIDENT NO. 42006)
Analytical Method SM 6200B
MT
B
E
Na
p
h
t
h
a
l
e
n
e
n-
B
u
t
y
l
b
e
n
z
e
n
e
se
c
-
B
u
t
y
l
b
e
n
z
e
n
e
MAC (µg/l)
Contaminant of Concern 
Be
n
z
e
n
e
To
l
u
e
n
e
Et
h
y
l
b
e
n
z
e
n
e
Xy
l
e
n
e
s
te
r
t
-
A
m
y
l

a
l
c
o
h
o
l

(
T
A
A
)
te
r
t
-
B
u
t
y
l

a
l
c
o
h
o
l

(
T
B
A
)
GCL (µg/l)
MW-6
MW-5
MW-4
MW-3
MW-1
MW-2
Page 1 of 1

APPENDICES

APPENDIX A
State Correspondence
3787 Received MAR 17 2023

APPENDIX B
Laboratory Report – Ground Water Samples

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

7/11/2023
Geological Resources, Inc. Scott Driscoll
113 W. Firetower Road, Suite G Winterville, NC, 28590
Ref: Analytical Testing
Lab Report Number: 23-181-0001 Client Project Description: Cruz N Mart
GRI #3787
Dear Scott Driscoll:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 6/29/2023 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love Project Manager
Page 1 of 65
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2023402State ProgramNorth Carolina
07/31/202399012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/23-181-0001
Page 2 of 65
Report Number:
Sample Summary Table
Client Project Description:
23-181-0001
Cruz N Mart
GRI #3787
Lab No Client Sample ID Matrix Date Collected Date Received
06/27/2023 09:26Aqueous 99540 MW-1 06/29/2023 15:17
06/27/2023 09:20Aqueous 99541 MW-2 06/29/2023 15:17
06/27/2023 09:38Aqueous 99542 MW-3 06/29/2023 15:17
06/27/2023 09:31Aqueous 99543 MW-4 06/29/2023 15:17
06/27/2023 09:12Aqueous 99544 MW-5 06/29/2023 15:17
06/27/2023 09:05Aqueous 99545 MW-6 06/29/2023 15:17
06/27/2023 10:00Aqueous 99546 WSW-OX 06/29/2023 15:17
06/27/2023 08:30Aqueous 99547 Trip Blank 06/29/2023 15:17
Page 3 of 65
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-181-0001
Report Limit
Project:Cruz N Mart
V 99540MW-1
155 07/07/2023 20:426200BAcetoneµg/L 18.0
169 07/07/2023 20:426200BBenzeneµg/L 1.80
6.75 07/07/2023 20:426200Bsec-Butyl benzene µg/L 2.00
88.1 07/07/2023 20:426200BEthylbenzeneµg/L 1.70
13.1 07/07/2023 20:426200BIsopropylbenzeneµg/L 1.80
18.0 07/07/2023 20:426200B4-Isopropyl toluene µg/L 0.890
41.0 07/07/2023 20:426200BNaphthaleneµg/L 4.70
49.3 07/07/2023 20:426200Bn-Propylbenzene µg/L 1.90
J39.2 07/07/2023 20:426200Btert-Butyl Alcohol (TBA)µg/L 16.0
16.5 07/07/2023 20:426200BTolueneµg/L 2.20
297 07/07/2023 20:426200B1,2,4-Trimethylbenzene µg/L 1.90
112 07/07/2023 20:426200B1,3,5-Trimethylbenzene µg/L 1.80
78.5 07/07/2023 20:426200Bo-Xylene µg/L 2.10
81.2 07/07/2023 20:426200Bm,p-Xylene µg/L 4.20
160 07/07/2023 20:426200BXylene (Total)µg/L 2.10
V 99541MW-2
810 07/07/2023 09:476200BBenzeneµg/L 18.0
782 07/07/2023 09:476200BEthylbenzeneµg/L 17.0
72.9 07/07/2023 09:476200BIsopropylbenzeneµg/L 18.0
548 07/07/2023 09:476200BNaphthaleneµg/L 47.0
176 07/07/2023 09:476200Bn-Propylbenzene µg/L 19.0
J22507/07/2023 09:476200Btert-Butyl Alcohol (TBA)µg/L 160
2340 07/07/2023 09:476200Btert-Amyl Alcohol (TAA)µg/L 190
1090 07/07/2023 09:476200BTolueneµg/L 22.0
1580 07/07/2023 09:476200B1,2,4-Trimethylbenzene µg/L 19.0
436 07/07/2023 09:476200B1,3,5-Trimethylbenzene µg/L 18.0
1140 07/07/2023 09:476200Bo-Xylene µg/L 21.0
2680 07/07/2023 09:476200Bm,p-Xylene µg/L 42.0
3820 07/07/2023 09:476200BXylene (Total)µg/L 21.0
V 99542MW-3
J2.24 07/07/2023 05:396200BAcetoneµg/L 1.80
7.59 07/07/2023 05:396200BBenzeneµg/L 0.180
J0.523 07/07/2023 05:396200BMethyl tert-butyl ether (MTBE)µg/L 0.140
V 99543MW-4
J6.52 07/10/2023 14:366200BAcetoneµg/L 1.80
Page 4 of 65
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-181-0001
Report Limit
Project:Cruz N Mart
V 99543MW-4
J0.498 07/10/2023 14:366200BBenzeneµg/L 0.180
3.88 07/10/2023 14:366200BChlorobenzeneµg/L 0.190
1.91 07/10/2023 14:366200B1,4-Dichlorobenzene µg/L 0.210
1.77 07/10/2023 14:366200B4-Isopropyl toluene µg/L 0.089
54.2 07/10/2023 14:366200BTolueneµg/L 0.220
J0.329 07/10/2023 14:366200B1,2,4-Trimethylbenzene µg/L 0.190
V 99544MW-5
1010 07/07/2023 10:376200BBenzeneµg/L 18.0
789 07/07/2023 10:376200BEthylbenzeneµg/L 17.0
60.1 07/07/2023 10:376200BIsopropylbenzeneµg/L 18.0
352 07/07/2023 10:376200BNaphthaleneµg/L 47.0
168 07/07/2023 10:376200Bn-Propylbenzene µg/L 19.0
1480 07/07/2023 10:376200Btert-Amyl Alcohol (TAA)µg/L 190
2730 07/07/2023 10:376200BTolueneµg/L 22.0
1450 07/07/2023 10:376200B1,2,4-Trimethylbenzene µg/L 19.0
372 07/07/2023 10:376200B1,3,5-Trimethylbenzene µg/L 18.0
1230 07/07/2023 10:376200Bo-Xylene µg/L 21.0
1550 07/07/2023 10:376200Bm,p-Xylene µg/L 42.0
2780 07/07/2023 10:376200BXylene (Total)µg/L 21.0
V 99545MW-6
J0.478 07/07/2023 06:036200B1,2,4-Trimethylbenzene µg/L 0.190
V 99547Trip Blank
J2.05 07/07/2023 04:246200BAcetoneµg/L 1.80
Page 5 of 65

Client: Geological Resources, Inc. CASE NARRATIVE
Project: Cruz N Mart Lab Report Number: 23-181-0001
Date: 7/11/2023
Volatile Organic Compounds - GC/MS Method 6200B Analyte: Ethanol QC Batch No: V35085/V35178
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.

Page 6 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-1
99540 Matrix:
6/27/2023 9:26
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0 1003,3-Dimethyl-1-butanol 10 07/07/23 20:42 6200BENM
Surrogate: 4-Bromofluorobenzene 91.8 Limits: 70-130%07/07/23 20:4210 ENM V35186
Surrogate: Dibromofluoromethane 96.4 Limits: 70-130%07/07/23 20:4210 ENM V35186
Surrogate: 1,2-Dichloroethane - d4 92.4 Limits: 70-130%07/07/23 20:4210 ENM V35186
Surrogate: Toluene-d8 93.8 Limits: 70-130%07/07/23 20:4210 ENM V35186
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 7 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-1
99540 Matrix:
6/27/2023 9:26
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35178 07/07/23 09:00
155 µg/L 18.0 100Acetone 10 07/07/23 20:42 V35186ENM
169 µg/L 1.80 5.00Benzene 10 07/07/23 20:42 V35186ENM
<2.10 µg/L 2.10 5.00Bromobenzene 10 07/07/23 20:42 V35186ENM
<4.20 µg/L 4.20 10.0Bromochloromethane 10 07/07/23 20:42 V35186ENM
<1.60 µg/L 1.60 5.00Bromodichloromethane 10 07/07/23 20:42 V35186ENM
<15.0 µg/L 15.0 50.0Bromoform 10 07/07/23 20:42 V35186ENM
<2.80 µg/L 2.80 10.0Bromomethane 10 07/07/23 20:42 V35186ENM
<1.80 µg/L 1.80 5.00n-Butylbenzene 10 07/07/23 20:42 V35186ENM
6.75 µg/L 2.00 5.00sec-Butyl benzene 10 07/07/23 20:42 V35186ENM
<9.20 µg/L 9.20 20.0tert-Butyl benzene 10 07/07/23 20:42 V35186ENM
<1.80 µg/L 1.80 5.00Carbon Tetrachloride 10 07/07/23 20:42 V35186ENM
<1.90 µg/L 1.90 5.00Chlorobenzene 10 07/07/23 20:42 V35186ENM
<1.90 µg/L 1.90 5.00Chlorodibromomethane 10 07/07/23 20:42 V35186ENM
<4.30 µg/L 4.30 10.0Chloroethane 10 07/07/23 20:42 V35186ENM
<2.20 µg/L 2.20 5.00Chloroform 10 07/07/23 20:42 V35186ENM
<2.20 µg/L 2.20 5.00Chloromethane 10 07/07/23 20:42 V35186ENM
<2.00 µg/L 2.00 5.002-Chlorotoluene 10 07/07/23 20:42 V35186ENM
<2.00 µg/L 2.00 5.004-Chlorotoluene 10 07/07/23 20:42 V35186ENM
<5.00 µg/L 5.00 5.00Di-Isopropyl Ether (DIPE)10 07/07/23 20:42 V35186ENM
<11.0 µg/L 11.0 20.01,2-Dibromo-3-Chloropropane 10 07/07/23 20:42 V35186ENM
<2.00 µg/L 2.00 5.001,2-Dibromoethane 10 07/07/23 20:42 V35186ENM
<2.30 µg/L 2.30 5.00Dibromomethane 10 07/07/23 20:42 V35186ENM
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 8 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-1
99540 Matrix:
6/27/2023 9:26
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35178 07/07/23 09:00
<2.20 µg/L 2.20 5.001,2-Dichlorobenzene 10 07/07/23 20:42 V35186ENM
<1.90 µg/L 1.90 5.001,3-Dichlorobenzene 10 07/07/23 20:42 V35186ENM
<2.10 µg/L 2.10 5.001,4-Dichlorobenzene 10 07/07/23 20:42 V35186ENM
<12.0 µg/L 12.0 50.0Dichlorodifluoromethane 10 07/07/23 20:42 V35186ENM
<2.40 µg/L 2.40 5.001,1-Dichloroethane 10 07/07/23 20:42 V35186ENM
<1.50 µg/L 1.50 5.001,2-Dichloroethane 10 07/07/23 20:42 V35186ENM
<1.50 µg/L 1.50 5.001,1-Dichloroethene 10 07/07/23 20:42 V35186ENM
<2.00 µg/L 2.00 5.00cis-1,2-Dichloroethene 10 07/07/23 20:42 V35186ENM
<1.80 µg/L 1.80 5.00trans-1,2-Dichloroethene 10 07/07/23 20:42 V35186ENM
<1.90 µg/L 1.90 5.001,2-Dichloropropane 10 07/07/23 20:42 V35186ENM
<1.30 µg/L 1.30 5.001,3-Dichloropropane 10 07/07/23 20:42 V35186ENM
<2.10 µg/L 2.10 20.02,2-Dichloropropane 10 07/07/23 20:42 V35186ENM
<2.00 µg/L 2.00 5.001,1-Dichloropropene 10 07/07/23 20:42 V35186ENM
<2.10 µg/L 2.10 5.00cis-1,3-Dichloropropene 10 07/07/23 20:42 V35186ENM
<1.50 µg/L 1.50 5.00trans-1,3-Dichloropropene 10 07/07/23 20:42 V35186ENM
<420 µg/L 420 2000Ethanol 10 07/07/23 20:42 V35186ENM
88.1 µg/L 1.70 5.00Ethylbenzene 10 07/07/23 20:42 V35186ENM
<3.50 µg/L 3.50 30.0Hexachlorobutadiene 10 07/07/23 20:42 V35186ENM
<3.80 µg/L 3.80 10.02-Hexanone 10 07/07/23 20:42 V35186ENM
13.1 µg/L 1.80 5.00Isopropylbenzene 10 07/07/23 20:42 V35186ENM
18.0 µg/L 0.890 5.004-Isopropyl toluene 10 07/07/23 20:42 V35186ENM
<7.10 µg/L 7.10 50.0Methyl Ethyl Ketone (MEK)10 07/07/23 20:42 V35186ENM
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 9 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-1
99540 Matrix:
6/27/2023 9:26
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35178 07/07/23 09:00
<1.40 µg/L 1.40 10.0Methyl tert-butyl ether (MTBE)10 07/07/23 20:42 V35186ENM
<0.780 µg/L 0.780 10.04-Methyl-2-Pentanone 10 07/07/23 20:42 V35186ENM
<3.30 µg/L 3.30 20.0Methylene Chloride 10 07/07/23 20:42 V35186ENM
41.0 µg/L 4.70 10.0Naphthalene 10 07/07/23 20:42 V35186ENM
49.3 µg/L 1.90 5.00n-Propylbenzene 10 07/07/23 20:42 V35186ENM
<2.20 µg/L 2.20 5.00Styrene 10 07/07/23 20:42 V35186ENM
39.2 J µg/L 16.0 100tert-Butyl Alcohol (TBA)10 07/07/23 20:42 V35186ENM
<3.50 µg/L 3.50 100tert-Butyl formate (TBF)10 07/07/23 20:42 V35186ENM
<19.0 µg/L 19.0 100tert-Amyl Alcohol (TAA)10 07/07/23 20:42 V35186ENM
<2.80 µg/L 2.80 100tert-Amyl Methyl Ether (TAME)10 07/07/23 20:42 V35186ENM
<1.60 µg/L 1.60 5.001,1,1,2-Tetrachloroethane 10 07/07/23 20:42 V35186ENM
<1.60 µg/L 1.60 5.001,1,2,2-Tetrachloroethane 10 07/07/23 20:42 V35186ENM
<2.20 µg/L 2.20 5.00Tetrachloroethene 10 07/07/23 20:42 V35186ENM
16.5 µg/L 2.20 5.00Toluene 10 07/07/23 20:42 V35186ENM
<3.80 µg/L 3.80 5.001,2,3-Trichlorobenzene 10 07/07/23 20:42 V35186ENM
<3.10 µg/L 3.10 5.001,2,4-Trichlorobenzene 10 07/07/23 20:42 V35186ENM
<1.60 µg/L 1.60 5.001,1,1-Trichloroethane 10 07/07/23 20:42 V35186ENM
<0.960 µg/L 0.960 5.001,1,2-Trichloroethane 10 07/07/23 20:42 V35186ENM
<1.80 µg/L 1.80 5.00Trichloroethene 10 07/07/23 20:42 V35186ENM
<1.80 µg/L 1.80 5.00Trichlorofluoromethane 10 07/07/23 20:42 V35186ENM
<2.70 µg/L 2.70 5.001,2,3-Trichloropropane 10 07/07/23 20:42 V35186ENM
297 µg/L 1.90 5.001,2,4-Trimethylbenzene 10 07/07/23 20:42 V35186ENM
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 10 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-1
99540 Matrix:
6/27/2023 9:26
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35178 07/07/23 09:00
112 µg/L 1.80 5.001,3,5-Trimethylbenzene 10 07/07/23 20:42 V35186ENM
<10.0 µg/L 10.0 50.0Vinyl Acetate 10 07/07/23 20:42 V35186ENM
<1.70 µg/L 1.70 5.00Vinyl Chloride 10 07/07/23 20:42 V35186ENM
78.5 µg/L 2.10 5.00o-Xylene 10 07/07/23 20:42 V35186ENM
81.2 µg/L 4.20 10.0m,p-Xylene 10 07/07/23 20:42 V35186ENM
160 µg/L 2.10 5.00Xylene (Total)10 07/07/23 20:42 V35186
Surrogate: 4-Bromofluorobenzene 91.8 Limits: 70-130%07/07/23 20:4210 ENM V35186
Surrogate: Dibromofluoromethane 96.4 Limits: 70-130%07/07/23 20:4210 ENM V35186
Surrogate: 1,2-Dichloroethane - d4 92.4 Limits: 70-130%07/07/23 20:4210 ENM V35186
Surrogate: Toluene-d8 93.8 Limits: 70-130%07/07/23 20:4210 ENM V35186
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 11 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-2
99541 Matrix:
6/27/2023 9:20
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<100 µg/L 100 10003,3-Dimethyl-1-butanol 100 07/07/23 09:47 6200BMSA
Surrogate: 4-Bromofluorobenzene 102 Limits: 70-130%07/07/23 09:47100 MSA V35085
Surrogate: Dibromofluoromethane 94.0 Limits: 70-130%07/07/23 09:47100 MSA V35085
Surrogate: 1,2-Dichloroethane - d4 95.2 Limits: 70-130%07/07/23 09:47100 MSA V35085
Surrogate: Toluene-d8 94.0 Limits: 70-130%07/07/23 09:47100 MSA V35085
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 12 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-2
99541 Matrix:
6/27/2023 9:20
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35084 07/06/23 14:00
<180 µg/L 180 1000Acetone 100 07/07/23 09:47 V35085MSA
810 µg/L 18.0 50.0Benzene 100 07/07/23 09:47 V35085MSA
<21.0 µg/L 21.0 50.0Bromobenzene 100 07/07/23 09:47 V35085MSA
<42.0 µg/L 42.0 100Bromochloromethane 100 07/07/23 09:47 V35085MSA
<16.0 µg/L 16.0 50.0Bromodichloromethane 100 07/07/23 09:47 V35085MSA
<150 µg/L 150 500Bromoform 100 07/07/23 09:47 V35085MSA
<28.0 µg/L 28.0 100Bromomethane 100 07/07/23 09:47 V35085MSA
<18.0 µg/L 18.0 50.0n-Butylbenzene 100 07/07/23 09:47 V35085MSA
<20.0 µg/L 20.0 50.0sec-Butyl benzene 100 07/07/23 09:47 V35085MSA
<92.0 µg/L 92.0 200tert-Butyl benzene 100 07/07/23 09:47 V35085MSA
<18.0 µg/L 18.0 50.0Carbon Tetrachloride 100 07/07/23 09:47 V35085MSA
<19.0 µg/L 19.0 50.0Chlorobenzene 100 07/07/23 09:47 V35085MSA
<19.0 µg/L 19.0 50.0Chlorodibromomethane 100 07/07/23 09:47 V35085MSA
<43.0 µg/L 43.0 100Chloroethane 100 07/07/23 09:47 V35085MSA
<22.0 µg/L 22.0 50.0Chloroform 100 07/07/23 09:47 V35085MSA
<22.0 µg/L 22.0 50.0Chloromethane 100 07/07/23 09:47 V35085MSA
<20.0 µg/L 20.0 50.02-Chlorotoluene 100 07/07/23 09:47 V35085MSA
<20.0 µg/L 20.0 50.04-Chlorotoluene 100 07/07/23 09:47 V35085MSA
<50.0 µg/L 50.0 50.0Di-Isopropyl Ether (DIPE)100 07/07/23 09:47 V35085MSA
<110 µg/L 110 2001,2-Dibromo-3-Chloropropane 100 07/07/23 09:47 V35085MSA
<20.0 µg/L 20.0 50.01,2-Dibromoethane 100 07/07/23 09:47 V35085MSA
<23.0 µg/L 23.0 50.0Dibromomethane 100 07/07/23 09:47 V35085MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 13 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-2
99541 Matrix:
6/27/2023 9:20
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35084 07/06/23 14:00
<22.0 µg/L 22.0 50.01,2-Dichlorobenzene 100 07/07/23 09:47 V35085MSA
<19.0 µg/L 19.0 50.01,3-Dichlorobenzene 100 07/07/23 09:47 V35085MSA
<21.0 µg/L 21.0 50.01,4-Dichlorobenzene 100 07/07/23 09:47 V35085MSA
<120 µg/L 120 500Dichlorodifluoromethane 100 07/07/23 09:47 V35085MSA
<24.0 µg/L 24.0 50.01,1-Dichloroethane 100 07/07/23 09:47 V35085MSA
<15.0 µg/L 15.0 50.01,2-Dichloroethane 100 07/07/23 09:47 V35085MSA
<15.0 µg/L 15.0 50.01,1-Dichloroethene 100 07/07/23 09:47 V35085MSA
<20.0 µg/L 20.0 50.0cis-1,2-Dichloroethene 100 07/07/23 09:47 V35085MSA
<18.0 µg/L 18.0 50.0trans-1,2-Dichloroethene 100 07/07/23 09:47 V35085MSA
<19.0 µg/L 19.0 50.01,2-Dichloropropane 100 07/07/23 09:47 V35085MSA
<13.0 µg/L 13.0 50.01,3-Dichloropropane 100 07/07/23 09:47 V35085MSA
<21.0 µg/L 21.0 2002,2-Dichloropropane 100 07/07/23 09:47 V35085MSA
<20.0 µg/L 20.0 50.01,1-Dichloropropene 100 07/07/23 09:47 V35085MSA
<21.0 µg/L 21.0 50.0cis-1,3-Dichloropropene 100 07/07/23 09:47 V35085MSA
<15.0 µg/L 15.0 50.0trans-1,3-Dichloropropene 100 07/07/23 09:47 V35085MSA
<4200 µg/L 4200 20000Ethanol 100 07/07/23 09:47 V35085MSA
782 µg/L 17.0 50.0Ethylbenzene 100 07/07/23 09:47 V35085MSA
<35.0 µg/L 35.0 300Hexachlorobutadiene 100 07/07/23 09:47 V35085MSA
<38.0 µg/L 38.0 1002-Hexanone 100 07/07/23 09:47 V35085MSA
72.9 µg/L 18.0 50.0Isopropylbenzene 100 07/07/23 09:47 V35085MSA
<8.90 µg/L 8.90 50.04-Isopropyl toluene 100 07/07/23 09:47 V35085MSA
<71.0 µg/L 71.0 500Methyl Ethyl Ketone (MEK)100 07/07/23 09:47 V35085MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 14 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-2
99541 Matrix:
6/27/2023 9:20
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35084 07/06/23 14:00
<14.0 µg/L 14.0 100Methyl tert-butyl ether (MTBE)100 07/07/23 09:47 V35085MSA
<7.80 µg/L 7.80 1004-Methyl-2-Pentanone 100 07/07/23 09:47 V35085MSA
<33.0 µg/L 33.0 200Methylene Chloride 100 07/07/23 09:47 V35085MSA
548 µg/L 47.0 100Naphthalene 100 07/07/23 09:47 V35085MSA
176 µg/L 19.0 50.0n-Propylbenzene 100 07/07/23 09:47 V35085MSA
<22.0 µg/L 22.0 50.0Styrene 100 07/07/23 09:47 V35085MSA
225 J µg/L 160 1000tert-Butyl Alcohol (TBA)100 07/07/23 09:47 V35085MSA
<35.0 µg/L 35.0 1000tert-Butyl formate (TBF)100 07/07/23 09:47 V35085MSA
2340 µg/L 190 1000tert-Amyl Alcohol (TAA)100 07/07/23 09:47 V35085MSA
<28.0 µg/L 28.0 1000tert-Amyl Methyl Ether (TAME)100 07/07/23 09:47 V35085MSA
<16.0 µg/L 16.0 50.01,1,1,2-Tetrachloroethane 100 07/07/23 09:47 V35085MSA
<16.0 µg/L 16.0 50.01,1,2,2-Tetrachloroethane 100 07/07/23 09:47 V35085MSA
<22.0 µg/L 22.0 50.0Tetrachloroethene 100 07/07/23 09:47 V35085MSA
1090 µg/L 22.0 50.0Toluene 100 07/07/23 09:47 V35085MSA
<38.0 µg/L 38.0 50.01,2,3-Trichlorobenzene 100 07/07/23 09:47 V35085MSA
<31.0 µg/L 31.0 50.01,2,4-Trichlorobenzene 100 07/07/23 09:47 V35085MSA
<16.0 µg/L 16.0 50.01,1,1-Trichloroethane 100 07/07/23 09:47 V35085MSA
<9.60 µg/L 9.60 50.01,1,2-Trichloroethane 100 07/07/23 09:47 V35085MSA
<18.0 µg/L 18.0 50.0Trichloroethene 100 07/07/23 09:47 V35085MSA
<18.0 µg/L 18.0 50.0Trichlorofluoromethane 100 07/07/23 09:47 V35085MSA
<27.0 µg/L 27.0 50.01,2,3-Trichloropropane 100 07/07/23 09:47 V35085MSA
1580 µg/L 19.0 50.01,2,4-Trimethylbenzene 100 07/07/23 09:47 V35085MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 15 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-2
99541 Matrix:
6/27/2023 9:20
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35084 07/06/23 14:00
436 µg/L 18.0 50.01,3,5-Trimethylbenzene 100 07/07/23 09:47 V35085MSA
<100 µg/L 100 500Vinyl Acetate 100 07/07/23 09:47 V35085MSA
<17.0 µg/L 17.0 50.0Vinyl Chloride 100 07/07/23 09:47 V35085MSA
1140 µg/L 21.0 50.0o-Xylene 100 07/07/23 09:47 V35085MSA
2680 µg/L 42.0 100m,p-Xylene 100 07/07/23 09:47 V35085MSA
3820 µg/L 21.0 50.0Xylene (Total)100 07/07/23 09:47 V35085
Surrogate: 4-Bromofluorobenzene 102 Limits: 70-130%07/07/23 09:47100 MSA V35085
Surrogate: Dibromofluoromethane 94.0 Limits: 70-130%07/07/23 09:47100 MSA V35085
Surrogate: 1,2-Dichloroethane - d4 95.2 Limits: 70-130%07/07/23 09:47100 MSA V35085
Surrogate: Toluene-d8 94.0 Limits: 70-130%07/07/23 09:47100 MSA V35085
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 16 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-3
99542 Matrix:
6/27/2023 9:38
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 07/07/23 05:39 6200BMSA
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%07/07/23 05:391 MSA V35085
Surrogate: Dibromofluoromethane 95.4 Limits: 70-130%07/07/23 05:391 MSA V35085
Surrogate: 1,2-Dichloroethane - d4 97.2 Limits: 70-130%07/07/23 05:391 MSA V35085
Surrogate: Toluene-d8 93.6 Limits: 70-130%07/07/23 05:391 MSA V35085
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 17 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-3
99542 Matrix:
6/27/2023 9:38
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35084 07/06/23 14:00
2.24 J µg/L 1.80 10.0Acetone 1 07/07/23 05:39 V35085MSA
7.59 µg/L 0.180 0.500Benzene 1 07/07/23 05:39 V35085MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 07/07/23 05:39 V35085MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 07/07/23 05:39 V35085MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 07/07/23 05:39 V35085MSA
<1.50 µg/L 1.50 5.00Bromoform 1 07/07/23 05:39 V35085MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 07/07/23 05:39 V35085MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 07/07/23 05:39 V35085MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 07/07/23 05:39 V35085MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 07/07/23 05:39 V35085MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 07/07/23 05:39 V35085MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 07/07/23 05:39 V35085MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 07/07/23 05:39 V35085MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 07/07/23 05:39 V35085MSA
<0.220 µg/L 0.220 0.500Chloroform 1 07/07/23 05:39 V35085MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 07/07/23 05:39 V35085MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 07/07/23 05:39 V35085MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 07/07/23 05:39 V35085MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 07/07/23 05:39 V35085MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 07/07/23 05:39 V35085MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 07/07/23 05:39 V35085MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 07/07/23 05:39 V35085MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 18 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-3
99542 Matrix:
6/27/2023 9:38
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35084 07/06/23 14:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 07/07/23 05:39 V35085MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 07/07/23 05:39 V35085MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 07/07/23 05:39 V35085MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 07/07/23 05:39 V35085MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 07/07/23 05:39 V35085MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 07/07/23 05:39 V35085MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 07/07/23 05:39 V35085MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 07/07/23 05:39 V35085MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 07/07/23 05:39 V35085MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 07/07/23 05:39 V35085MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 07/07/23 05:39 V35085MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 07/07/23 05:39 V35085MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 07/07/23 05:39 V35085MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 07/07/23 05:39 V35085MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 07/07/23 05:39 V35085MSA
<42.0 µg/L 42.0 200Ethanol 1 07/07/23 05:39 V35085MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 07/07/23 05:39 V35085MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 07/07/23 05:39 V35085MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 07/07/23 05:39 V35085MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 07/07/23 05:39 V35085MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 07/07/23 05:39 V35085MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 07/07/23 05:39 V35085MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 19 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-3
99542 Matrix:
6/27/2023 9:38
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35084 07/06/23 14:00
0.523 J µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 07/07/23 05:39 V35085MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 07/07/23 05:39 V35085MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 07/07/23 05:39 V35085MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 07/07/23 05:39 V35085MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 07/07/23 05:39 V35085MSA
<0.220 µg/L 0.220 0.500Styrene 1 07/07/23 05:39 V35085MSA
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 07/07/23 05:39 V35085MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 07/07/23 05:39 V35085MSA
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 07/07/23 05:39 V35085MSA
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 07/07/23 05:39 V35085MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 07/07/23 05:39 V35085MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 07/07/23 05:39 V35085MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 07/07/23 05:39 V35085MSA
<0.220 µg/L 0.220 0.500Toluene 1 07/07/23 05:39 V35085MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 07/07/23 05:39 V35085MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 07/07/23 05:39 V35085MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 07/07/23 05:39 V35085MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 07/07/23 05:39 V35085MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 07/07/23 05:39 V35085MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 07/07/23 05:39 V35085MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 07/07/23 05:39 V35085MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 07/07/23 05:39 V35085MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 20 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-3
99542 Matrix:
6/27/2023 9:38
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35084 07/06/23 14:00
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 07/07/23 05:39 V35085MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 07/07/23 05:39 V35085MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 07/07/23 05:39 V35085MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 07/07/23 05:39 V35085MSA
<0.420 µg/L 0.420 1.00m,p-Xylene 1 07/07/23 05:39 V35085MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 07/07/23 05:39 V35085
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%07/07/23 05:391 MSA V35085
Surrogate: Dibromofluoromethane 95.4 Limits: 70-130%07/07/23 05:391 MSA V35085
Surrogate: 1,2-Dichloroethane - d4 97.2 Limits: 70-130%07/07/23 05:391 MSA V35085
Surrogate: Toluene-d8 93.6 Limits: 70-130%07/07/23 05:391 MSA V35085
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 21 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-4
99543 Matrix:
6/27/2023 9:31
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 07/10/23 14:36 6200BMSA
Surrogate: 4-Bromofluorobenzene 94.4 Limits: 70-130%07/10/23 14:361 MSA V35200
Surrogate: Dibromofluoromethane 95.0 Limits: 70-130%07/10/23 14:361 MSA V35200
Surrogate: 1,2-Dichloroethane - d4 91.2 Limits: 70-130%07/10/23 14:361 MSA V35200
Surrogate: Toluene-d8 93.0 Limits: 70-130%07/10/23 14:361 MSA V35200
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 22 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-4
99543 Matrix:
6/27/2023 9:31
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35199 07/10/23 09:00
6.52 J µg/L 1.80 10.0Acetone 1 07/10/23 14:36 V35200MSA
0.498 J µg/L 0.180 0.500Benzene 1 07/10/23 14:36 V35200MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 07/10/23 14:36 V35200MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 07/10/23 14:36 V35200MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 07/10/23 14:36 V35200MSA
<1.50 µg/L 1.50 5.00Bromoform 1 07/10/23 14:36 V35200MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 07/10/23 14:36 V35200MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 07/10/23 14:36 V35200MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 07/10/23 14:36 V35200MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 07/10/23 14:36 V35200MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 07/10/23 14:36 V35200MSA
3.88 µg/L 0.190 0.500Chlorobenzene 1 07/10/23 14:36 V35200MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 07/10/23 14:36 V35200MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 07/10/23 14:36 V35200MSA
<0.220 µg/L 0.220 0.500Chloroform 1 07/10/23 14:36 V35200MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 07/10/23 14:36 V35200MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 07/10/23 14:36 V35200MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 07/10/23 14:36 V35200MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 07/10/23 14:36 V35200MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 07/10/23 14:36 V35200MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 07/10/23 14:36 V35200MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 07/10/23 14:36 V35200MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 23 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-4
99543 Matrix:
6/27/2023 9:31
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35199 07/10/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 07/10/23 14:36 V35200MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 07/10/23 14:36 V35200MSA
1.91 µg/L 0.210 0.5001,4-Dichlorobenzene 1 07/10/23 14:36 V35200MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 07/10/23 14:36 V35200MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 07/10/23 14:36 V35200MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 07/10/23 14:36 V35200MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 07/10/23 14:36 V35200MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 07/10/23 14:36 V35200MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 07/10/23 14:36 V35200MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 07/10/23 14:36 V35200MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 07/10/23 14:36 V35200MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 07/10/23 14:36 V35200MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 07/10/23 14:36 V35200MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 07/10/23 14:36 V35200MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 07/10/23 14:36 V35200MSA
<42.0 µg/L 42.0 200Ethanol 1 07/10/23 14:36 V35200MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 07/10/23 14:36 V35200MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 07/10/23 14:36 V35200MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 07/10/23 14:36 V35200MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 07/10/23 14:36 V35200MSA
1.77 µg/L 0.089 0.5004-Isopropyl toluene 1 07/10/23 14:36 V35200MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 07/10/23 14:36 V35200MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 24 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-4
99543 Matrix:
6/27/2023 9:31
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35199 07/10/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 07/10/23 14:36 V35200MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 07/10/23 14:36 V35200MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 07/10/23 14:36 V35200MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 07/10/23 14:36 V35200MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 07/10/23 14:36 V35200MSA
<0.220 µg/L 0.220 0.500Styrene 1 07/10/23 14:36 V35200MSA
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 07/10/23 14:36 V35200MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 07/10/23 14:36 V35200MSA
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 07/10/23 14:36 V35200MSA
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 07/10/23 14:36 V35200MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 07/10/23 14:36 V35200MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 07/10/23 14:36 V35200MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 07/10/23 14:36 V35200MSA
54.2 µg/L 0.220 0.500Toluene 1 07/10/23 14:36 V35200MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 07/10/23 14:36 V35200MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 07/10/23 14:36 V35200MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 07/10/23 14:36 V35200MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 07/10/23 14:36 V35200MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 07/10/23 14:36 V35200MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 07/10/23 14:36 V35200MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 07/10/23 14:36 V35200MSA
0.329 J µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 07/10/23 14:36 V35200MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 25 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-4
99543 Matrix:
6/27/2023 9:31
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35199 07/10/23 09:00
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 07/10/23 14:36 V35200MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 07/10/23 14:36 V35200MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 07/10/23 14:36 V35200MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 07/10/23 14:36 V35200MSA
<0.420 µg/L 0.420 1.00m,p-Xylene 1 07/10/23 14:36 V35200MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 07/10/23 14:36 V35200
Surrogate: 4-Bromofluorobenzene 94.4 Limits: 70-130%07/10/23 14:361 MSA V35200
Surrogate: Dibromofluoromethane 95.0 Limits: 70-130%07/10/23 14:361 MSA V35200
Surrogate: 1,2-Dichloroethane - d4 91.2 Limits: 70-130%07/10/23 14:361 MSA V35200
Surrogate: Toluene-d8 93.0 Limits: 70-130%07/10/23 14:361 MSA V35200
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 26 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-5
99544 Matrix:
6/27/2023 9:12
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<100 µg/L 100 10003,3-Dimethyl-1-butanol 100 07/07/23 10:37 6200BMSA
Surrogate: 4-Bromofluorobenzene 102 Limits: 70-130%07/07/23 10:37100 MSA V35085
Surrogate: Dibromofluoromethane 96.4 Limits: 70-130%07/07/23 10:37100 MSA V35085
Surrogate: 1,2-Dichloroethane - d4 98.8 Limits: 70-130%07/07/23 10:37100 MSA V35085
Surrogate: Toluene-d8 94.0 Limits: 70-130%07/07/23 10:37100 MSA V35085
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 27 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-5
99544 Matrix:
6/27/2023 9:12
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35084 07/06/23 14:00
<180 µg/L 180 1000Acetone 100 07/07/23 10:37 V35085MSA
1010 µg/L 18.0 50.0Benzene 100 07/07/23 10:37 V35085MSA
<21.0 µg/L 21.0 50.0Bromobenzene 100 07/07/23 10:37 V35085MSA
<42.0 µg/L 42.0 100Bromochloromethane 100 07/07/23 10:37 V35085MSA
<16.0 µg/L 16.0 50.0Bromodichloromethane 100 07/07/23 10:37 V35085MSA
<150 µg/L 150 500Bromoform 100 07/07/23 10:37 V35085MSA
<28.0 µg/L 28.0 100Bromomethane 100 07/07/23 10:37 V35085MSA
<18.0 µg/L 18.0 50.0n-Butylbenzene 100 07/07/23 10:37 V35085MSA
<20.0 µg/L 20.0 50.0sec-Butyl benzene 100 07/07/23 10:37 V35085MSA
<92.0 µg/L 92.0 200tert-Butyl benzene 100 07/07/23 10:37 V35085MSA
<18.0 µg/L 18.0 50.0Carbon Tetrachloride 100 07/07/23 10:37 V35085MSA
<19.0 µg/L 19.0 50.0Chlorobenzene 100 07/07/23 10:37 V35085MSA
<19.0 µg/L 19.0 50.0Chlorodibromomethane 100 07/07/23 10:37 V35085MSA
<43.0 µg/L 43.0 100Chloroethane 100 07/07/23 10:37 V35085MSA
<22.0 µg/L 22.0 50.0Chloroform 100 07/07/23 10:37 V35085MSA
<22.0 µg/L 22.0 50.0Chloromethane 100 07/07/23 10:37 V35085MSA
<20.0 µg/L 20.0 50.02-Chlorotoluene 100 07/07/23 10:37 V35085MSA
<20.0 µg/L 20.0 50.04-Chlorotoluene 100 07/07/23 10:37 V35085MSA
<50.0 µg/L 50.0 50.0Di-Isopropyl Ether (DIPE)100 07/07/23 10:37 V35085MSA
<110 µg/L 110 2001,2-Dibromo-3-Chloropropane 100 07/07/23 10:37 V35085MSA
<20.0 µg/L 20.0 50.01,2-Dibromoethane 100 07/07/23 10:37 V35085MSA
<23.0 µg/L 23.0 50.0Dibromomethane 100 07/07/23 10:37 V35085MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 28 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-5
99544 Matrix:
6/27/2023 9:12
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35084 07/06/23 14:00
<22.0 µg/L 22.0 50.01,2-Dichlorobenzene 100 07/07/23 10:37 V35085MSA
<19.0 µg/L 19.0 50.01,3-Dichlorobenzene 100 07/07/23 10:37 V35085MSA
<21.0 µg/L 21.0 50.01,4-Dichlorobenzene 100 07/07/23 10:37 V35085MSA
<120 µg/L 120 500Dichlorodifluoromethane 100 07/07/23 10:37 V35085MSA
<24.0 µg/L 24.0 50.01,1-Dichloroethane 100 07/07/23 10:37 V35085MSA
<15.0 µg/L 15.0 50.01,2-Dichloroethane 100 07/07/23 10:37 V35085MSA
<15.0 µg/L 15.0 50.01,1-Dichloroethene 100 07/07/23 10:37 V35085MSA
<20.0 µg/L 20.0 50.0cis-1,2-Dichloroethene 100 07/07/23 10:37 V35085MSA
<18.0 µg/L 18.0 50.0trans-1,2-Dichloroethene 100 07/07/23 10:37 V35085MSA
<19.0 µg/L 19.0 50.01,2-Dichloropropane 100 07/07/23 10:37 V35085MSA
<13.0 µg/L 13.0 50.01,3-Dichloropropane 100 07/07/23 10:37 V35085MSA
<21.0 µg/L 21.0 2002,2-Dichloropropane 100 07/07/23 10:37 V35085MSA
<20.0 µg/L 20.0 50.01,1-Dichloropropene 100 07/07/23 10:37 V35085MSA
<21.0 µg/L 21.0 50.0cis-1,3-Dichloropropene 100 07/07/23 10:37 V35085MSA
<15.0 µg/L 15.0 50.0trans-1,3-Dichloropropene 100 07/07/23 10:37 V35085MSA
<4200 µg/L 4200 20000Ethanol 100 07/07/23 10:37 V35085MSA
789 µg/L 17.0 50.0Ethylbenzene 100 07/07/23 10:37 V35085MSA
<35.0 µg/L 35.0 300Hexachlorobutadiene 100 07/07/23 10:37 V35085MSA
<38.0 µg/L 38.0 1002-Hexanone 100 07/07/23 10:37 V35085MSA
60.1 µg/L 18.0 50.0Isopropylbenzene 100 07/07/23 10:37 V35085MSA
<8.90 µg/L 8.90 50.04-Isopropyl toluene 100 07/07/23 10:37 V35085MSA
<71.0 µg/L 71.0 500Methyl Ethyl Ketone (MEK)100 07/07/23 10:37 V35085MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 29 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-5
99544 Matrix:
6/27/2023 9:12
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35084 07/06/23 14:00
<14.0 µg/L 14.0 100Methyl tert-butyl ether (MTBE)100 07/07/23 10:37 V35085MSA
<7.80 µg/L 7.80 1004-Methyl-2-Pentanone 100 07/07/23 10:37 V35085MSA
<33.0 µg/L 33.0 200Methylene Chloride 100 07/07/23 10:37 V35085MSA
352 µg/L 47.0 100Naphthalene 100 07/07/23 10:37 V35085MSA
168 µg/L 19.0 50.0n-Propylbenzene 100 07/07/23 10:37 V35085MSA
<22.0 µg/L 22.0 50.0Styrene 100 07/07/23 10:37 V35085MSA
<160 µg/L 160 1000tert-Butyl Alcohol (TBA)100 07/07/23 10:37 V35085MSA
<35.0 µg/L 35.0 1000tert-Butyl formate (TBF)100 07/07/23 10:37 V35085MSA
1480 µg/L 190 1000tert-Amyl Alcohol (TAA)100 07/07/23 10:37 V35085MSA
<28.0 µg/L 28.0 1000tert-Amyl Methyl Ether (TAME)100 07/07/23 10:37 V35085MSA
<16.0 µg/L 16.0 50.01,1,1,2-Tetrachloroethane 100 07/07/23 10:37 V35085MSA
<16.0 µg/L 16.0 50.01,1,2,2-Tetrachloroethane 100 07/07/23 10:37 V35085MSA
<22.0 µg/L 22.0 50.0Tetrachloroethene 100 07/07/23 10:37 V35085MSA
2730 µg/L 22.0 50.0Toluene 100 07/07/23 10:37 V35085MSA
<38.0 µg/L 38.0 50.01,2,3-Trichlorobenzene 100 07/07/23 10:37 V35085MSA
<31.0 µg/L 31.0 50.01,2,4-Trichlorobenzene 100 07/07/23 10:37 V35085MSA
<16.0 µg/L 16.0 50.01,1,1-Trichloroethane 100 07/07/23 10:37 V35085MSA
<9.60 µg/L 9.60 50.01,1,2-Trichloroethane 100 07/07/23 10:37 V35085MSA
<18.0 µg/L 18.0 50.0Trichloroethene 100 07/07/23 10:37 V35085MSA
<18.0 µg/L 18.0 50.0Trichlorofluoromethane 100 07/07/23 10:37 V35085MSA
<27.0 µg/L 27.0 50.01,2,3-Trichloropropane 100 07/07/23 10:37 V35085MSA
1450 µg/L 19.0 50.01,2,4-Trimethylbenzene 100 07/07/23 10:37 V35085MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 30 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-5
99544 Matrix:
6/27/2023 9:12
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35084 07/06/23 14:00
372 µg/L 18.0 50.01,3,5-Trimethylbenzene 100 07/07/23 10:37 V35085MSA
<100 µg/L 100 500Vinyl Acetate 100 07/07/23 10:37 V35085MSA
<17.0 µg/L 17.0 50.0Vinyl Chloride 100 07/07/23 10:37 V35085MSA
1230 µg/L 21.0 50.0o-Xylene 100 07/07/23 10:37 V35085MSA
1550 µg/L 42.0 100m,p-Xylene 100 07/07/23 10:37 V35085MSA
2780 µg/L 21.0 50.0Xylene (Total)100 07/07/23 10:37 V35085
Surrogate: 4-Bromofluorobenzene 102 Limits: 70-130%07/07/23 10:37100 MSA V35085
Surrogate: Dibromofluoromethane 96.4 Limits: 70-130%07/07/23 10:37100 MSA V35085
Surrogate: 1,2-Dichloroethane - d4 98.8 Limits: 70-130%07/07/23 10:37100 MSA V35085
Surrogate: Toluene-d8 94.0 Limits: 70-130%07/07/23 10:37100 MSA V35085
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 31 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-6
99545 Matrix:
6/27/2023 9:05
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 07/07/23 06:03 6200BMSA
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%07/07/23 06:031 MSA V35085
Surrogate: Dibromofluoromethane 94.6 Limits: 70-130%07/07/23 06:031 MSA V35085
Surrogate: 1,2-Dichloroethane - d4 96.6 Limits: 70-130%07/07/23 06:031 MSA V35085
Surrogate: Toluene-d8 94.6 Limits: 70-130%07/07/23 06:031 MSA V35085
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 32 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-6
99545 Matrix:
6/27/2023 9:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35084 07/06/23 14:00
<1.80 µg/L 1.80 10.0Acetone 1 07/07/23 06:03 V35085MSA
<0.180 µg/L 0.180 0.500Benzene 1 07/07/23 06:03 V35085MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 07/07/23 06:03 V35085MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 07/07/23 06:03 V35085MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 07/07/23 06:03 V35085MSA
<1.50 µg/L 1.50 5.00Bromoform 1 07/07/23 06:03 V35085MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 07/07/23 06:03 V35085MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 07/07/23 06:03 V35085MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 07/07/23 06:03 V35085MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 07/07/23 06:03 V35085MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 07/07/23 06:03 V35085MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 07/07/23 06:03 V35085MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 07/07/23 06:03 V35085MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 07/07/23 06:03 V35085MSA
<0.220 µg/L 0.220 0.500Chloroform 1 07/07/23 06:03 V35085MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 07/07/23 06:03 V35085MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 07/07/23 06:03 V35085MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 07/07/23 06:03 V35085MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 07/07/23 06:03 V35085MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 07/07/23 06:03 V35085MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 07/07/23 06:03 V35085MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 07/07/23 06:03 V35085MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 33 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-6
99545 Matrix:
6/27/2023 9:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35084 07/06/23 14:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 07/07/23 06:03 V35085MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 07/07/23 06:03 V35085MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 07/07/23 06:03 V35085MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 07/07/23 06:03 V35085MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 07/07/23 06:03 V35085MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 07/07/23 06:03 V35085MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 07/07/23 06:03 V35085MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 07/07/23 06:03 V35085MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 07/07/23 06:03 V35085MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 07/07/23 06:03 V35085MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 07/07/23 06:03 V35085MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 07/07/23 06:03 V35085MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 07/07/23 06:03 V35085MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 07/07/23 06:03 V35085MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 07/07/23 06:03 V35085MSA
<42.0 µg/L 42.0 200Ethanol 1 07/07/23 06:03 V35085MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 07/07/23 06:03 V35085MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 07/07/23 06:03 V35085MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 07/07/23 06:03 V35085MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 07/07/23 06:03 V35085MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 07/07/23 06:03 V35085MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 07/07/23 06:03 V35085MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 34 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-6
99545 Matrix:
6/27/2023 9:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35084 07/06/23 14:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 07/07/23 06:03 V35085MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 07/07/23 06:03 V35085MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 07/07/23 06:03 V35085MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 07/07/23 06:03 V35085MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 07/07/23 06:03 V35085MSA
<0.220 µg/L 0.220 0.500Styrene 1 07/07/23 06:03 V35085MSA
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 07/07/23 06:03 V35085MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 07/07/23 06:03 V35085MSA
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 07/07/23 06:03 V35085MSA
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 07/07/23 06:03 V35085MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 07/07/23 06:03 V35085MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 07/07/23 06:03 V35085MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 07/07/23 06:03 V35085MSA
<0.220 µg/L 0.220 0.500Toluene 1 07/07/23 06:03 V35085MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 07/07/23 06:03 V35085MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 07/07/23 06:03 V35085MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 07/07/23 06:03 V35085MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 07/07/23 06:03 V35085MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 07/07/23 06:03 V35085MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 07/07/23 06:03 V35085MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 07/07/23 06:03 V35085MSA
0.478 J µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 07/07/23 06:03 V35085MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 35 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:MW-6
99545 Matrix:
6/27/2023 9:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35084 07/06/23 14:00
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 07/07/23 06:03 V35085MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 07/07/23 06:03 V35085MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 07/07/23 06:03 V35085MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 07/07/23 06:03 V35085MSA
<0.420 µg/L 0.420 1.00m,p-Xylene 1 07/07/23 06:03 V35085MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 07/07/23 06:03 V35085
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%07/07/23 06:031 MSA V35085
Surrogate: Dibromofluoromethane 94.6 Limits: 70-130%07/07/23 06:031 MSA V35085
Surrogate: 1,2-Dichloroethane - d4 96.6 Limits: 70-130%07/07/23 06:031 MSA V35085
Surrogate: Toluene-d8 94.6 Limits: 70-130%07/07/23 06:031 MSA V35085
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 36 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:WSW-OX
99546 Matrix:
6/27/2023 10:00
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 07/07/23 06:28 6200BMSA
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%07/07/23 06:281 MSA V35085
Surrogate: Dibromofluoromethane 95.6 Limits: 70-130%07/07/23 06:281 MSA V35085
Surrogate: 1,2-Dichloroethane - d4 97.0 Limits: 70-130%07/07/23 06:281 MSA V35085
Surrogate: Toluene-d8 95.6 Limits: 70-130%07/07/23 06:281 MSA V35085
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 37 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:WSW-OX
99546 Matrix:
6/27/2023 10:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35084 07/06/23 14:00
<1.80 µg/L 1.80 10.0Acetone 1 07/07/23 06:28 V35085MSA
<0.180 µg/L 0.180 0.500Benzene 1 07/07/23 06:28 V35085MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 07/07/23 06:28 V35085MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 07/07/23 06:28 V35085MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 07/07/23 06:28 V35085MSA
<1.50 µg/L 1.50 5.00Bromoform 1 07/07/23 06:28 V35085MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 07/07/23 06:28 V35085MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 07/07/23 06:28 V35085MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 07/07/23 06:28 V35085MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 07/07/23 06:28 V35085MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 07/07/23 06:28 V35085MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 07/07/23 06:28 V35085MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 07/07/23 06:28 V35085MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 07/07/23 06:28 V35085MSA
<0.220 µg/L 0.220 0.500Chloroform 1 07/07/23 06:28 V35085MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 07/07/23 06:28 V35085MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 07/07/23 06:28 V35085MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 07/07/23 06:28 V35085MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 07/07/23 06:28 V35085MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 07/07/23 06:28 V35085MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 07/07/23 06:28 V35085MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 07/07/23 06:28 V35085MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 38 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:WSW-OX
99546 Matrix:
6/27/2023 10:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35084 07/06/23 14:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 07/07/23 06:28 V35085MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 07/07/23 06:28 V35085MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 07/07/23 06:28 V35085MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 07/07/23 06:28 V35085MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 07/07/23 06:28 V35085MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 07/07/23 06:28 V35085MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 07/07/23 06:28 V35085MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 07/07/23 06:28 V35085MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 07/07/23 06:28 V35085MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 07/07/23 06:28 V35085MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 07/07/23 06:28 V35085MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 07/07/23 06:28 V35085MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 07/07/23 06:28 V35085MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 07/07/23 06:28 V35085MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 07/07/23 06:28 V35085MSA
<42.0 µg/L 42.0 200Ethanol 1 07/07/23 06:28 V35085MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 07/07/23 06:28 V35085MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 07/07/23 06:28 V35085MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 07/07/23 06:28 V35085MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 07/07/23 06:28 V35085MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 07/07/23 06:28 V35085MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 07/07/23 06:28 V35085MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 39 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:WSW-OX
99546 Matrix:
6/27/2023 10:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35084 07/06/23 14:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 07/07/23 06:28 V35085MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 07/07/23 06:28 V35085MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 07/07/23 06:28 V35085MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 07/07/23 06:28 V35085MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 07/07/23 06:28 V35085MSA
<0.220 µg/L 0.220 0.500Styrene 1 07/07/23 06:28 V35085MSA
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 07/07/23 06:28 V35085MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 07/07/23 06:28 V35085MSA
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 07/07/23 06:28 V35085MSA
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 07/07/23 06:28 V35085MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 07/07/23 06:28 V35085MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 07/07/23 06:28 V35085MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 07/07/23 06:28 V35085MSA
<0.220 µg/L 0.220 0.500Toluene 1 07/07/23 06:28 V35085MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 07/07/23 06:28 V35085MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 07/07/23 06:28 V35085MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 07/07/23 06:28 V35085MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 07/07/23 06:28 V35085MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 07/07/23 06:28 V35085MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 07/07/23 06:28 V35085MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 07/07/23 06:28 V35085MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 07/07/23 06:28 V35085MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 40 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:WSW-OX
99546 Matrix:
6/27/2023 10:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35084 07/06/23 14:00
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 07/07/23 06:28 V35085MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 07/07/23 06:28 V35085MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 07/07/23 06:28 V35085MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 07/07/23 06:28 V35085MSA
<0.420 µg/L 0.420 1.00m,p-Xylene 1 07/07/23 06:28 V35085MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 07/07/23 06:28 V35085
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%07/07/23 06:281 MSA V35085
Surrogate: Dibromofluoromethane 95.6 Limits: 70-130%07/07/23 06:281 MSA V35085
Surrogate: 1,2-Dichloroethane - d4 97.0 Limits: 70-130%07/07/23 06:281 MSA V35085
Surrogate: Toluene-d8 95.6 Limits: 70-130%07/07/23 06:281 MSA V35085
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 41 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:Trip Blank
99547 Matrix:
6/27/2023 8:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35084 07/06/23 14:00
2.05 J µg/L 1.80 10.0Acetone 1 07/07/23 04:24 V35085MSA
<0.180 µg/L 0.180 0.500Benzene 1 07/07/23 04:24 V35085MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 07/07/23 04:24 V35085MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 07/07/23 04:24 V35085MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 07/07/23 04:24 V35085MSA
<1.50 µg/L 1.50 5.00Bromoform 1 07/07/23 04:24 V35085MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 07/07/23 04:24 V35085MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 07/07/23 04:24 V35085MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 07/07/23 04:24 V35085MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 07/07/23 04:24 V35085MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 07/07/23 04:24 V35085MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 07/07/23 04:24 V35085MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 07/07/23 04:24 V35085MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 07/07/23 04:24 V35085MSA
<0.220 µg/L 0.220 0.500Chloroform 1 07/07/23 04:24 V35085MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 07/07/23 04:24 V35085MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 07/07/23 04:24 V35085MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 07/07/23 04:24 V35085MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 07/07/23 04:24 V35085MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 07/07/23 04:24 V35085MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 07/07/23 04:24 V35085MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 07/07/23 04:24 V35085MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 42 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:Trip Blank
99547 Matrix:
6/27/2023 8:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35084 07/06/23 14:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 07/07/23 04:24 V35085MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 07/07/23 04:24 V35085MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 07/07/23 04:24 V35085MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 07/07/23 04:24 V35085MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 07/07/23 04:24 V35085MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 07/07/23 04:24 V35085MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 07/07/23 04:24 V35085MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 07/07/23 04:24 V35085MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 07/07/23 04:24 V35085MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 07/07/23 04:24 V35085MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 07/07/23 04:24 V35085MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 07/07/23 04:24 V35085MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 07/07/23 04:24 V35085MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 07/07/23 04:24 V35085MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 07/07/23 04:24 V35085MSA
<42.0 µg/L 42.0 200Ethanol 1 07/07/23 04:24 V35085MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 07/07/23 04:24 V35085MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 07/07/23 04:24 V35085MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 07/07/23 04:24 V35085MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 07/07/23 04:24 V35085MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 07/07/23 04:24 V35085MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 07/07/23 04:24 V35085MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 43 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:Trip Blank
99547 Matrix:
6/27/2023 8:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35084 07/06/23 14:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 07/07/23 04:24 V35085MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 07/07/23 04:24 V35085MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 07/07/23 04:24 V35085MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 07/07/23 04:24 V35085MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 07/07/23 04:24 V35085MSA
<0.220 µg/L 0.220 0.500Styrene 1 07/07/23 04:24 V35085MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 07/07/23 04:24 V35085MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 07/07/23 04:24 V35085MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 07/07/23 04:24 V35085MSA
<0.220 µg/L 0.220 0.500Toluene 1 07/07/23 04:24 V35085MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 07/07/23 04:24 V35085MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 07/07/23 04:24 V35085MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 07/07/23 04:24 V35085MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 07/07/23 04:24 V35085MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 07/07/23 04:24 V35085MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 07/07/23 04:24 V35085MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 07/07/23 04:24 V35085MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 07/07/23 04:24 V35085MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 07/07/23 04:24 V35085MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 07/07/23 04:24 V35085MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 07/07/23 04:24 V35085MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 07/07/23 04:24 V35085MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 44 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-181-0001
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #3787 Received : 06/29/2023
Cruz N Mart
Report Date : 07/11/2023
Sample ID :
Lab No :
Sampled:Trip Blank
99547 Matrix:
6/27/2023 8:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V35084 07/06/23 14:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 07/07/23 04:24 V35085MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 07/07/23 04:24 V35085
Surrogate: 4-Bromofluorobenzene 103 Limits: 70-130%07/07/23 04:241 MSA V35085
Surrogate: Dibromofluoromethane 95.4 Limits: 70-130%07/07/23 04:241 MSA V35085
Surrogate: 1,2-Dichloroethane - d4 95.8 Limits: 70-130%07/07/23 04:241 MSA V35085
Surrogate: Toluene-d8 94.6 Limits: 70-130%07/07/23 04:241 MSA V35085
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 45 of 65
Quality Control Data
23-181-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
Cruz N Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V35085QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V35084
Associated Lab Samples: 99541, 99542, 99544, 99545, 99546, 99547
LRB-V35084 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/07/23 04:0010.01.80<1.80µg/LAcetone
07/07/23 04:000.5000.180<0.180µg/LBenzene
07/07/23 04:000.5000.210<0.210µg/LBromobenzene
07/07/23 04:001.000.420<0.420µg/LBromochloromethane
07/07/23 04:000.5000.160<0.160µg/LBromodichloromethane
07/07/23 04:005.001.50<1.50µg/LBromoform
07/07/23 04:001.000.280<0.280µg/LBromomethane
07/07/23 04:000.5000.180<0.180µg/Ln-Butylbenzene
07/07/23 04:000.5000.200<0.200µg/Lsec-Butyl benzene
07/07/23 04:002.000.920<0.920µg/Ltert-Butyl benzene
07/07/23 04:000.5000.180<0.180µg/LCarbon Tetrachloride
07/07/23 04:000.5000.190<0.190µg/LChlorobenzene
07/07/23 04:000.5000.190<0.190µg/LChlorodibromomethane
07/07/23 04:001.000.430<0.430µg/LChloroethane
07/07/23 04:000.5000.220<0.220µg/LChloroform
07/07/23 04:000.5000.220<0.220µg/LChloromethane
07/07/23 04:000.5000.200<0.200µg/L2-Chlorotoluene
07/07/23 04:000.5000.200<0.200µg/L4-Chlorotoluene
07/07/23 04:000.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
07/07/23 04:002.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
07/07/23 04:000.5000.200<0.200µg/L1,2-Dibromoethane
07/07/23 04:000.5000.230<0.230µg/LDibromomethane
07/07/23 04:000.5000.220<0.220µg/L1,2-Dichlorobenzene
07/07/23 04:000.5000.190<0.190µg/L1,3-Dichlorobenzene
07/07/23 04:000.5000.210<0.210µg/L1,4-Dichlorobenzene
07/07/23 04:005.001.20<1.20µg/LDichlorodifluoromethane
07/07/23 04:000.5000.240<0.240µg/L1,1-Dichloroethane
Page 1 of 18Date:07/11/2023 05:26 PM
Page 46 of 65
Quality Control Data
23-181-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
Cruz N Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V35085QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V35084
Associated Lab Samples: 99541, 99542, 99544, 99545, 99546, 99547
LRB-V35084 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/07/23 04:000.5000.150<0.150µg/L1,2-Dichloroethane
07/07/23 04:000.5000.150<0.150µg/L1,1-Dichloroethene
07/07/23 04:000.5000.200<0.200µg/Lcis-1,2-Dichloroethene
07/07/23 04:000.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
07/07/23 04:000.5000.190<0.190µg/L1,2-Dichloropropane
07/07/23 04:000.5000.130<0.130µg/L1,3-Dichloropropane
07/07/23 04:002.000.210<0.210µg/L2,2-Dichloropropane
07/07/23 04:000.5000.200<0.200µg/L1,1-Dichloropropene
07/07/23 04:000.5000.210<0.210µg/Lcis-1,3-Dichloropropene
07/07/23 04:000.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
07/07/23 04:0020042.0<42.0µg/LEthanol
07/07/23 04:000.5000.170<0.170µg/LEthylbenzene
07/07/23 04:003.000.350<0.350µg/LHexachlorobutadiene
07/07/23 04:001.000.380<0.380µg/L2-Hexanone
07/07/23 04:000.5000.180<0.180µg/LIsopropylbenzene
07/07/23 04:000.5000.089<0.089µg/L4-Isopropyl toluene
07/07/23 04:005.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
07/07/23 04:001.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
07/07/23 04:001.000.078<0.078µg/L4-Methyl-2-Pentanone
07/07/23 04:002.000.330<0.330µg/LMethylene Chloride
07/07/23 04:001.000.470<0.470µg/LNaphthalene
07/07/23 04:000.5000.190<0.190µg/Ln-Propylbenzene
07/07/23 04:000.5000.220<0.220µg/LStyrene
07/07/23 04:0010.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
07/07/23 04:0010.00.350<0.350µg/Ltert-Butyl formate (TBF)
07/07/23 04:0010.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
07/07/23 04:0010.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
Page 2 of 18Date:07/11/2023 05:26 PM
Page 47 of 65
Quality Control Data
23-181-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
Cruz N Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V35085QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V35084
Associated Lab Samples: 99541, 99542, 99544, 99545, 99546, 99547
LRB-V35084 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/07/23 04:000.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
07/07/23 04:000.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
07/07/23 04:000.5000.220<0.220µg/LTetrachloroethene
07/07/23 04:000.5000.220<0.220µg/LToluene
07/07/23 04:000.5000.380<0.380µg/L1,2,3-Trichlorobenzene
07/07/23 04:000.5000.310<0.310µg/L1,2,4-Trichlorobenzene
07/07/23 04:000.5000.160<0.160µg/L1,1,1-Trichloroethane
07/07/23 04:000.5000.096<0.096µg/L1,1,2-Trichloroethane
07/07/23 04:000.5000.180<0.180µg/LTrichloroethene
07/07/23 04:000.5000.180<0.180µg/LTrichlorofluoromethane
07/07/23 04:000.5000.270<0.270µg/L1,2,3-Trichloropropane
07/07/23 04:000.5000.190<0.190µg/L1,2,4-Trimethylbenzene
07/07/23 04:000.5000.180<0.180µg/L1,3,5-Trimethylbenzene
07/07/23 04:005.001.00<1.00µg/LVinyl Acetate
07/07/23 04:000.5000.170<0.170µg/LVinyl Chloride
07/07/23 04:000.5000.210<0.210µg/Lo-Xylene
07/07/23 04:001.000.420<0.420µg/Lm,p-Xylene
07/07/23 04:0010.01.00<1.00µg/L3,3-Dimethyl-1-butanol
07/07/23 04:004-Bromofluorobenzene (S)99.0 70-130
07/07/23 04:00Dibromofluoromethane (S)95.6 70-130
07/07/23 04:001,2-Dichloroethane - d4 (S)96.8 70-130
07/07/23 04:00Toluene-d8 (S)94.4 70-130
Page 3 of 18Date:07/11/2023 05:26 PM
Page 48 of 65
Quality Control Data
23-181-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
Cruz N Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V35085QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V35084
LCS-V35084 LCSD-V35084Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
46.1 11512048.040.0µg/LAcetone 40-160 4.0 20.0
20.8 10410821.620.0µg/LBenzene 70-130 3.7 20.0
19.6 98.010320.520.0µg/LBromobenzene 70-130 4.4 20.0
22.2 11110821.620.0µg/LBromochloromethane 70-130 2.7 20.0
21.8 10911422.720.0µg/LBromodichloromethane 70-130 4.0 20.0
21.2 10611021.920.0µg/LBromoform 70-130 3.2 20.0
16.4 82.092.518.520.0µg/LBromomethane 60-140 12.0 20.0
19.6 98.010520.920.0µg/Ln-Butylbenzene 70-130 6.4 20.0
19.8 99.010621.120.0µg/Lsec-Butyl benzene 70-130 6.3 20.0
19.9 99.510420.820.0µg/Ltert-Butyl benzene 70-130 4.4 20.0
20.2 10110420.820.0µg/LCarbon Tetrachloride 70-130 2.9 20.0
20.8 10410721.420.0µg/LChlorobenzene 70-130 2.8 20.0
21.4 10710921.820.0µg/LChlorodibromomethane 70-130 1.8 20.0
19.4 97.011422.820.0µg/LChloroethane 60-140 16.1 20.0
21.0 10510921.820.0µg/LChloroform 70-130 3.7 20.0
17.7 88.510520.920.0µg/LChloromethane 60-140 16.5 20.0
20.4 10210721.420.0µg/L2-Chlorotoluene 70-130 4.7 20.0
20.0 10010420.720.0µg/L4-Chlorotoluene 70-130 3.4 20.0
21.2 10610821.620.0µg/LDi-Isopropyl Ether (DIPE)70-130 1.8 20.0
20.2 10198.519.720.0µg/L1,2-Dibromo-3-Chloropropane 70-130 2.5 20.0
21.6 10810821.520.0µg/L1,2-Dibromoethane 70-130 0.4 20.0
22.6 11311523.020.0µg/LDibromomethane 70-130 1.7 20.0
19.9 99.510320.620.0µg/L1,2-Dichlorobenzene 70-130 3.4 20.0
19.7 98.510420.720.0µg/L1,3-Dichlorobenzene 70-130 4.9 20.0
19.5 97.510320.520.0µg/L1,4-Dichlorobenzene 70-130 5.0 20.0
20.0 10011723.320.0µg/LDichlorodifluoromethane 60-140 15.2 20.0
Page 4 of 18Date:07/11/2023 05:26 PM
Page 49 of 65
Quality Control Data
23-181-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
Cruz N Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V35085QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V35084
LCS-V35084 LCSD-V35084Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.9 10510821.620.0µg/L1,1-Dichloroethane 70-130 3.2 20.0
21.9 11010921.820.0µg/L1,2-Dichloroethane 70-130 0.4 20.0
19.9 99.510721.320.0µg/L1,1-Dichloroethene 70-130 6.7 20.0
21.2 10611122.120.0µg/Lcis-1,2-Dichloroethene 70-130 4.1 20.0
20.3 10210621.220.0µg/Ltrans-1,2-Dichloroethene 70-130 4.3 20.0
21.7 10911122.220.0µg/L1,2-Dichloropropane 70-130 2.2 20.0
21.1 10610721.320.0µg/L1,3-Dichloropropane 70-130 0.9 20.0
16.9 84.590.018.020.0µg/L2,2-Dichloropropane 70-130 6.3 20.0
20.8 10410821.620.0µg/L1,1-Dichloropropene 70-130 3.7 20.0
21.5 10811022.020.0µg/Lcis-1,3-Dichloropropene 70-130 2.2 20.0
22.0 11011122.220.0µg/Ltrans-1,3-Dichloropropene 70-130 0.9 20.0
489 97.8128640500µg/LEthanol 60-140 26.7*20.0
20.5 10310621.220.0µg/LEthylbenzene 70-130 3.3 20.0
18.9 94.510120.120.0µg/LHexachlorobutadiene 70-130 6.1 20.0
20.6 10310521.020.0µg/L2-Hexanone 60-140 1.9 20.0
20.1 10110721.420.0µg/LIsopropylbenzene 70-130 6.2 20.0
19.9 99.510621.120.0µg/L4-Isopropyl toluene 70-130 5.8 20.0
20.4 10210120.220.0µg/LMethyl Ethyl Ketone (MEK)60-140 0.9 20.0
21.6 10810721.320.0µg/LMethyl tert-butyl ether (MTBE)70-130 1.3 20.0
22.4 11211222.320.0µg/L4-Methyl-2-Pentanone 60-140 0.4 20.0
21.5 10811122.120.0µg/LMethylene Chloride 70-130 2.7 20.0
21.0 10599.519.920.0µg/LNaphthalene 70-130 5.3 20.0
20.2 10110721.420.0µg/Ln-Propylbenzene 70-130 5.7 20.0
21.1 10610921.720.0µg/LStyrene 70-130 2.8 20.0
51.0 12811545.840.0µg/Ltert-Butyl Alcohol (TBA)40-140 10.7 20.0
38.4 96.091.236.540.0µg/Ltert-Butyl formate (TBF)40-140 5.0 20.0
Page 5 of 18* QC Fail Date:07/11/2023 05:26 PM
Page 50 of 65
Quality Control Data
23-181-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
Cruz N Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V35085QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V35084
LCS-V35084 LCSD-V35084Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
27.6 13813026.020.0µg/Ltert-Amyl Alcohol (TAA)40-140 5.9 20.0
44.3 11111244.740.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 0.8 20.0
20.5 10310821.520.0µg/L1,1,1,2-Tetrachloroethane 70-130 4.7 20.0
19.8 99.098.519.720.0µg/L1,1,2,2-Tetrachloroethane 70-130 0.5 20.0
20.2 10110420.820.0µg/LTetrachloroethene 70-130 2.9 20.0
21.3 10711122.220.0µg/LToluene 70-130 4.1 20.0
24.3 12210821.620.0µg/L1,2,3-Trichlorobenzene 70-130 11.7 20.0
20.2 10110220.320.0µg/L1,2,4-Trichlorobenzene 70-130 0.4 20.0
21.0 10510921.820.0µg/L1,1,1-Trichloroethane 70-130 3.7 20.0
22.8 11411422.720.0µg/L1,1,2-Trichloroethane 70-130 0.4 20.0
21.0 10511122.220.0µg/LTrichloroethene 70-130 5.5 20.0
19.7 98.511522.920.0µg/LTrichlorofluoromethane 60-140 15.0 20.0
21.1 10610721.420.0µg/L1,2,3-Trichloropropane 70-130 1.4 20.0
20.0 10010521.020.0µg/L1,2,4-Trimethylbenzene 70-130 4.8 20.0
20.1 10110621.220.0µg/L1,3,5-Trimethylbenzene 70-130 5.3 20.0
20.4 10294.518.920.0µg/LVinyl Acetate 60-140 7.6 20.0
18.8 94.011122.220.0µg/LVinyl Chloride 60-140 16.5 20.0
20.9 10510921.820.0µg/Lo-Xylene 70-130 4.2 20.0
44.1 11011546.040.0µg/Lm,p-Xylene 70-130 4.2 20.0
21.8 10999.519.920.0µg/L3,3-Dimethyl-1-butanol 70-130 9.1 20.0
99.41014-Bromofluorobenzene (S)70-130
95.494.8Dibromofluoromethane (S)70-130
1031011,2-Dichloroethane - d4 (S)70-130
95.294.6Toluene-d8 (S)70-130
Page 6 of 18Date:07/11/2023 05:26 PM
Page 51 of 65
Quality Control Data
23-181-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
Cruz N Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V35186QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V35178
Associated Lab Samples: 99540
LRB-V35178 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/07/23 14:4410.01.80<1.80µg/LAcetone
07/07/23 14:440.5000.180<0.180µg/LBenzene
07/07/23 14:440.5000.210<0.210µg/LBromobenzene
07/07/23 14:441.000.420<0.420µg/LBromochloromethane
07/07/23 14:440.5000.160<0.160µg/LBromodichloromethane
07/07/23 14:445.001.50<1.50µg/LBromoform
07/07/23 14:441.000.280<0.280µg/LBromomethane
07/07/23 14:440.5000.180<0.180µg/Ln-Butylbenzene
07/07/23 14:440.5000.200<0.200µg/Lsec-Butyl benzene
07/07/23 14:442.000.920<0.920µg/Ltert-Butyl benzene
07/07/23 14:440.5000.180<0.180µg/LCarbon Tetrachloride
07/07/23 14:440.5000.190<0.190µg/LChlorobenzene
07/07/23 14:440.5000.190<0.190µg/LChlorodibromomethane
07/07/23 14:441.000.430<0.430µg/LChloroethane
07/07/23 14:440.5000.220<0.220µg/LChloroform
07/07/23 14:440.5000.220<0.220µg/LChloromethane
07/07/23 14:440.5000.200<0.200µg/L2-Chlorotoluene
07/07/23 14:440.5000.200<0.200µg/L4-Chlorotoluene
07/07/23 14:440.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
07/07/23 14:442.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
07/07/23 14:440.5000.200<0.200µg/L1,2-Dibromoethane
07/07/23 14:440.5000.230<0.230µg/LDibromomethane
07/07/23 14:440.5000.220<0.220µg/L1,2-Dichlorobenzene
07/07/23 14:440.5000.190<0.190µg/L1,3-Dichlorobenzene
07/07/23 14:440.5000.210<0.210µg/L1,4-Dichlorobenzene
07/07/23 14:445.001.20<1.20µg/LDichlorodifluoromethane
07/07/23 14:440.5000.240<0.240µg/L1,1-Dichloroethane
Page 7 of 18Date:07/11/2023 05:26 PM
Page 52 of 65
Quality Control Data
23-181-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
Cruz N Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V35186QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V35178
Associated Lab Samples: 99540
LRB-V35178 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/07/23 14:440.5000.150<0.150µg/L1,2-Dichloroethane
07/07/23 14:440.5000.150<0.150µg/L1,1-Dichloroethene
07/07/23 14:440.5000.200<0.200µg/Lcis-1,2-Dichloroethene
07/07/23 14:440.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
07/07/23 14:440.5000.190<0.190µg/L1,2-Dichloropropane
07/07/23 14:440.5000.130<0.130µg/L1,3-Dichloropropane
07/07/23 14:442.000.210<0.210µg/L2,2-Dichloropropane
07/07/23 14:440.5000.200<0.200µg/L1,1-Dichloropropene
07/07/23 14:440.5000.210<0.210µg/Lcis-1,3-Dichloropropene
07/07/23 14:440.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
07/07/23 14:4420042.0<42.0µg/LEthanol
07/07/23 14:440.5000.170<0.170µg/LEthylbenzene
07/07/23 14:443.000.350<0.350µg/LHexachlorobutadiene
07/07/23 14:441.000.380<0.380µg/L2-Hexanone
07/07/23 14:440.5000.180<0.180µg/LIsopropylbenzene
07/07/23 14:440.5000.089<0.089µg/L4-Isopropyl toluene
07/07/23 14:445.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
07/07/23 14:441.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
07/07/23 14:441.000.078<0.078µg/L4-Methyl-2-Pentanone
07/07/23 14:442.000.330<0.330µg/LMethylene Chloride
07/07/23 14:441.000.470<0.470µg/LNaphthalene
07/07/23 14:440.5000.190<0.190µg/Ln-Propylbenzene
07/07/23 14:440.5000.220<0.220µg/LStyrene
07/07/23 14:4410.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
07/07/23 14:4410.00.350<0.350µg/Ltert-Butyl formate (TBF)
07/07/23 14:4410.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
07/07/23 14:4410.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
Page 8 of 18Date:07/11/2023 05:26 PM
Page 53 of 65
Quality Control Data
23-181-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
Cruz N Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V35186QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V35178
Associated Lab Samples: 99540
LRB-V35178 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/07/23 14:440.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
07/07/23 14:440.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
07/07/23 14:440.5000.220<0.220µg/LTetrachloroethene
07/07/23 14:440.5000.220<0.220µg/LToluene
07/07/23 14:440.5000.380<0.380µg/L1,2,3-Trichlorobenzene
07/07/23 14:440.5000.310<0.310µg/L1,2,4-Trichlorobenzene
07/07/23 14:440.5000.160<0.160µg/L1,1,1-Trichloroethane
07/07/23 14:440.5000.096<0.096µg/L1,1,2-Trichloroethane
07/07/23 14:440.5000.180<0.180µg/LTrichloroethene
07/07/23 14:440.5000.180<0.180µg/LTrichlorofluoromethane
07/07/23 14:440.5000.270<0.270µg/L1,2,3-Trichloropropane
07/07/23 14:440.5000.190<0.190µg/L1,2,4-Trimethylbenzene
07/07/23 14:440.5000.180<0.180µg/L1,3,5-Trimethylbenzene
07/07/23 14:445.001.00<1.00µg/LVinyl Acetate
07/07/23 14:440.5000.170<0.170µg/LVinyl Chloride
07/07/23 14:440.5000.210<0.210µg/Lo-Xylene
07/07/23 14:441.000.420<0.420µg/Lm,p-Xylene
07/07/23 14:4410.01.00<1.00µg/L3,3-Dimethyl-1-butanol
07/07/23 14:444-Bromofluorobenzene (S)92.2 70-130
07/07/23 14:44Dibromofluoromethane (S)95.8 70-130
07/07/23 14:441,2-Dichloroethane - d4 (S)92.2 70-130
07/07/23 14:44Toluene-d8 (S)93.8 70-130
Page 9 of 18Date:07/11/2023 05:26 PM
Page 54 of 65
Quality Control Data
23-181-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
Cruz N Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V35186QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V35178
LCS-V35178 LCSD-V35178Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
43.4 10911646.540.0µg/LAcetone 40-160 6.8 20.0
18.3 91.596.019.220.0µg/LBenzene 70-130 4.8 20.0
17.3 86.589.017.820.0µg/LBromobenzene 70-130 2.8 20.0
19.4 97.098.519.720.0µg/LBromochloromethane 70-130 1.5 20.0
17.9 89.593.018.620.0µg/LBromodichloromethane 70-130 3.8 20.0
17.8 89.094.518.920.0µg/LBromoform 70-130 5.9 20.0
18.8 94.099.519.920.0µg/LBromomethane 60-140 5.6 20.0
17.2 86.091.018.220.0µg/Ln-Butylbenzene 70-130 5.6 20.0
17.1 85.590.518.120.0µg/Lsec-Butyl benzene 70-130 5.6 20.0
17.0 85.089.517.920.0µg/Ltert-Butyl benzene 70-130 5.1 20.0
17.7 88.592.518.520.0µg/LCarbon Tetrachloride 70-130 4.4 20.0
18.7 93.598.019.620.0µg/LChlorobenzene 70-130 4.6 20.0
17.9 89.593.018.620.0µg/LChlorodibromomethane 70-130 3.8 20.0
19.4 97.010420.820.0µg/LChloroethane 60-140 6.9 20.0
17.9 89.593.018.620.0µg/LChloroform 70-130 3.8 20.0
15.5 77.587.017.420.0µg/LChloromethane 60-140 11.5 20.0
16.9 84.587.017.420.0µg/L2-Chlorotoluene 70-130 2.9 20.0
16.7 83.587.517.520.0µg/L4-Chlorotoluene 70-130 4.6 20.0
16.8 84.086.017.220.0µg/LDi-Isopropyl Ether (DIPE)70-130 2.3 20.0
17.4 87.089.017.820.0µg/L1,2-Dibromo-3-Chloropropane 70-130 2.2 20.0
18.2 91.094.518.920.0µg/L1,2-Dibromoethane 70-130 3.7 20.0
18.9 94.594.518.920.0µg/LDibromomethane 70-130 0.0 20.0
18.3 91.594.518.920.0µg/L1,2-Dichlorobenzene 70-130 3.2 20.0
18.6 93.096.019.220.0µg/L1,3-Dichlorobenzene 70-130 3.1 20.0
17.7 88.594.518.920.0µg/L1,4-Dichlorobenzene 70-130 6.5 20.0
19.8 99.010420.820.0µg/LDichlorodifluoromethane 60-140 4.9 20.0
Page 10 of 18Date:07/11/2023 05:26 PM
Page 55 of 65
Quality Control Data
23-181-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
Cruz N Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V35186QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V35178
LCS-V35178 LCSD-V35178Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
17.6 88.092.518.520.0µg/L1,1-Dichloroethane 70-130 4.9 20.0
18.1 90.593.518.720.0µg/L1,2-Dichloroethane 70-130 3.2 20.0
18.3 91.593.518.720.0µg/L1,1-Dichloroethene 70-130 2.1 20.0
17.4 87.091.018.220.0µg/Lcis-1,2-Dichloroethene 70-130 4.4 20.0
17.8 89.091.518.320.0µg/Ltrans-1,2-Dichloroethene 70-130 2.7 20.0
17.9 89.593.018.620.0µg/L1,2-Dichloropropane 70-130 3.8 20.0
17.3 86.592.018.420.0µg/L1,3-Dichloropropane 70-130 6.1 20.0
17.5 87.596.519.320.0µg/L2,2-Dichloropropane 70-130 9.7 20.0
19.4 97.010220.420.0µg/L1,1-Dichloropropene 70-130 5.0 20.0
18.0 90.095.019.020.0µg/Lcis-1,3-Dichloropropene 70-130 5.4 20.0
17.5 87.590.518.120.0µg/Ltrans-1,3-Dichloropropene 70-130 3.3 20.0
515 103108538500µg/LEthanol 60-140 4.3 20.0
17.3 86.589.517.920.0µg/LEthylbenzene 70-130 3.4 20.0
18.5 92.510120.120.0µg/LHexachlorobutadiene 70-130 8.2 20.0
15.9 79.581.516.320.0µg/L2-Hexanone 60-140 2.4 20.0
17.1 85.591.018.220.0µg/LIsopropylbenzene 70-130 6.2 20.0
18.3 91.596.019.220.0µg/L4-Isopropyl toluene 70-130 4.8 20.0
14.5 72.571.514.320.0µg/LMethyl Ethyl Ketone (MEK)60-140 1.3 20.0
18.6 93.097.519.520.0µg/LMethyl tert-butyl ether (MTBE)70-130 4.7 20.0
15.1 75.581.016.220.0µg/L4-Methyl-2-Pentanone 60-140 7.0 20.0
17.8 89.092.018.420.0µg/LMethylene Chloride 70-130 3.3 20.0
14.0 70.074.514.920.0µg/LNaphthalene 70-130 6.2 20.0
16.7 83.589.017.820.0µg/Ln-Propylbenzene 70-130 6.3 20.0
18.5 92.598.019.620.0µg/LStyrene 70-130 5.7 20.0
27.1 67.768.227.340.0µg/Ltert-Butyl Alcohol (TBA)40-140 0.7 20.0
40.0 10010441.740.0µg/Ltert-Butyl formate (TBF)40-140 4.1 20.0
Page 11 of 18Date:07/11/2023 05:26 PM
Page 56 of 65
Quality Control Data
23-181-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
Cruz N Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V35186QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V35178
LCS-V35178 LCSD-V35178Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.5 97.510120.120.0µg/Ltert-Amyl Alcohol (TAA)40-140 3.0 20.0
37.2 93.095.738.340.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 2.9 20.0
18.7 93.595.019.020.0µg/L1,1,1,2-Tetrachloroethane 70-130 1.5 20.0
17.0 85.088.017.620.0µg/L1,1,2,2-Tetrachloroethane 70-130 3.4 20.0
18.8 94.010020.020.0µg/LTetrachloroethene 70-130 6.1 20.0
18.2 91.094.518.920.0µg/LToluene 70-130 3.7 20.0
18.5 92.595.019.020.0µg/L1,2,3-Trichlorobenzene 70-130 2.6 20.0
18.6 93.010220.320.0µg/L1,2,4-Trichlorobenzene 70-130 8.7 20.0
18.3 91.597.519.520.0µg/L1,1,1-Trichloroethane 70-130 6.3 20.0
18.8 94.097.519.520.0µg/L1,1,2-Trichloroethane 70-130 3.6 20.0
19.4 97.010120.120.0µg/LTrichloroethene 70-130 3.5 20.0
20.5 10310921.720.0µg/LTrichlorofluoromethane 60-140 5.6 20.0
17.2 86.091.018.220.0µg/L1,2,3-Trichloropropane 70-130 5.6 20.0
17.5 87.591.518.320.0µg/L1,2,4-Trimethylbenzene 70-130 4.4 20.0
17.3 86.590.518.120.0µg/L1,3,5-Trimethylbenzene 70-130 4.5 20.0
21.3 10711823.520.0µg/LVinyl Acetate 60-140 9.8 20.0
19.0 95.099.019.820.0µg/LVinyl Chloride 60-140 4.1 20.0
17.6 88.092.518.520.0µg/Lo-Xylene 70-130 4.9 20.0
37.7 94.298.239.340.0µg/Lm,p-Xylene 70-130 4.1 20.0
16.1 80.582.516.520.0µg/L3,3-Dimethyl-1-butanol 70-130 2.4 20.0
92.091.44-Bromofluorobenzene (S)70-130
95.495.0Dibromofluoromethane (S)70-130
93.894.81,2-Dichloroethane - d4 (S)70-130
94.295.8Toluene-d8 (S)70-130
Page 12 of 18Date:07/11/2023 05:26 PM
Page 57 of 65
Quality Control Data
23-181-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
Cruz N Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V35200QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V35199
Associated Lab Samples: 99543
LRB-V35199 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/10/23 14:0810.01.80<1.80µg/LAcetone
07/10/23 14:080.5000.180<0.180µg/LBenzene
07/10/23 14:080.5000.210<0.210µg/LBromobenzene
07/10/23 14:081.000.420<0.420µg/LBromochloromethane
07/10/23 14:080.5000.160<0.160µg/LBromodichloromethane
07/10/23 14:085.001.50<1.50µg/LBromoform
07/10/23 14:081.000.280<0.280µg/LBromomethane
07/10/23 14:080.5000.180<0.180µg/Ln-Butylbenzene
07/10/23 14:080.5000.200<0.200µg/Lsec-Butyl benzene
07/10/23 14:082.000.920<0.920µg/Ltert-Butyl benzene
07/10/23 14:080.5000.180<0.180µg/LCarbon Tetrachloride
07/10/23 14:080.5000.190<0.190µg/LChlorobenzene
07/10/23 14:080.5000.190<0.190µg/LChlorodibromomethane
07/10/23 14:081.000.430<0.430µg/LChloroethane
07/10/23 14:080.5000.220<0.220µg/LChloroform
07/10/23 14:080.5000.220<0.220µg/LChloromethane
07/10/23 14:080.5000.200<0.200µg/L2-Chlorotoluene
07/10/23 14:080.5000.200<0.200µg/L4-Chlorotoluene
07/10/23 14:080.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
07/10/23 14:082.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
07/10/23 14:080.5000.200<0.200µg/L1,2-Dibromoethane
07/10/23 14:080.5000.230<0.230µg/LDibromomethane
07/10/23 14:080.5000.220<0.220µg/L1,2-Dichlorobenzene
07/10/23 14:080.5000.190<0.190µg/L1,3-Dichlorobenzene
07/10/23 14:080.5000.210<0.210µg/L1,4-Dichlorobenzene
07/10/23 14:085.001.20<1.20µg/LDichlorodifluoromethane
07/10/23 14:080.5000.240<0.240µg/L1,1-Dichloroethane
Page 13 of 18Date:07/11/2023 05:26 PM
Page 58 of 65
Quality Control Data
23-181-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
Cruz N Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V35200QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V35199
Associated Lab Samples: 99543
LRB-V35199 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/10/23 14:080.5000.150<0.150µg/L1,2-Dichloroethane
07/10/23 14:080.5000.150<0.150µg/L1,1-Dichloroethene
07/10/23 14:080.5000.200<0.200µg/Lcis-1,2-Dichloroethene
07/10/23 14:080.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
07/10/23 14:080.5000.190<0.190µg/L1,2-Dichloropropane
07/10/23 14:080.5000.130<0.130µg/L1,3-Dichloropropane
07/10/23 14:082.000.210<0.210µg/L2,2-Dichloropropane
07/10/23 14:080.5000.200<0.200µg/L1,1-Dichloropropene
07/10/23 14:080.5000.210<0.210µg/Lcis-1,3-Dichloropropene
07/10/23 14:080.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
07/10/23 14:0820042.0<42.0µg/LEthanol
07/10/23 14:080.5000.170<0.170µg/LEthylbenzene
07/10/23 14:083.000.350<0.350µg/LHexachlorobutadiene
07/10/23 14:081.000.380<0.380µg/L2-Hexanone
07/10/23 14:080.5000.180<0.180µg/LIsopropylbenzene
07/10/23 14:080.5000.089<0.089µg/L4-Isopropyl toluene
07/10/23 14:085.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
07/10/23 14:081.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
07/10/23 14:081.000.078<0.078µg/L4-Methyl-2-Pentanone
07/10/23 14:082.000.330<0.330µg/LMethylene Chloride
07/10/23 14:081.000.470<0.470µg/LNaphthalene
07/10/23 14:080.5000.190<0.190µg/Ln-Propylbenzene
07/10/23 14:080.5000.220<0.220µg/LStyrene
07/10/23 14:0810.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
07/10/23 14:0810.00.350<0.350µg/Ltert-Butyl formate (TBF)
07/10/23 14:0810.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
07/10/23 14:0810.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
Page 14 of 18Date:07/11/2023 05:26 PM
Page 59 of 65
Quality Control Data
23-181-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
Cruz N Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V35200QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V35199
Associated Lab Samples: 99543
LRB-V35199 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/10/23 14:080.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
07/10/23 14:080.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
07/10/23 14:080.5000.220<0.220µg/LTetrachloroethene
07/10/23 14:080.5000.220<0.220µg/LToluene
07/10/23 14:080.5000.380<0.380µg/L1,2,3-Trichlorobenzene
07/10/23 14:080.5000.310<0.310µg/L1,2,4-Trichlorobenzene
07/10/23 14:080.5000.160<0.160µg/L1,1,1-Trichloroethane
07/10/23 14:080.5000.096<0.096µg/L1,1,2-Trichloroethane
07/10/23 14:080.5000.180<0.180µg/LTrichloroethene
07/10/23 14:080.5000.180<0.180µg/LTrichlorofluoromethane
07/10/23 14:080.5000.270<0.270µg/L1,2,3-Trichloropropane
07/10/23 14:080.5000.190<0.190µg/L1,2,4-Trimethylbenzene
07/10/23 14:080.5000.180<0.180µg/L1,3,5-Trimethylbenzene
07/10/23 14:085.001.00<1.00µg/LVinyl Acetate
07/10/23 14:080.5000.170<0.170µg/LVinyl Chloride
07/10/23 14:080.5000.210<0.210µg/Lo-Xylene
07/10/23 14:081.000.420<0.420µg/Lm,p-Xylene
07/10/23 14:0810.01.00<1.00µg/L3,3-Dimethyl-1-butanol
07/10/23 14:084-Bromofluorobenzene (S)93.2 70-130
07/10/23 14:08Dibromofluoromethane (S)96.2 70-130
07/10/23 14:081,2-Dichloroethane - d4 (S)93.6 70-130
07/10/23 14:08Toluene-d8 (S)93.0 70-130
Page 15 of 18Date:07/11/2023 05:26 PM
Page 60 of 65
Quality Control Data
23-181-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
Cruz N Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V35200QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V35199
LCS-V35199 LCSD-V35199Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
38.0 95.094.237.740.0µg/LAcetone 40-160 0.7 20.0
19.3 96.599.519.920.0µg/LBenzene 70-130 3.0 20.0
18.3 91.592.018.420.0µg/LBromobenzene 70-130 0.5 20.0
20.0 10010320.520.0µg/LBromochloromethane 70-130 2.4 20.0
19.2 96.098.519.720.0µg/LBromodichloromethane 70-130 2.5 20.0
19.8 99.010320.520.0µg/LBromoform 70-130 3.4 20.0
19.6 98.010721.420.0µg/LBromomethane 60-140 8.7 20.0
18.5 92.594.518.920.0µg/Ln-Butylbenzene 70-130 2.1 20.0
18.0 90.092.518.520.0µg/Lsec-Butyl benzene 70-130 2.7 20.0
18.2 91.092.018.420.0µg/Ltert-Butyl benzene 70-130 1.0 20.0
18.9 94.597.519.520.0µg/LCarbon Tetrachloride 70-130 3.1 20.0
19.9 99.510220.420.0µg/LChlorobenzene 70-130 2.4 20.0
18.6 93.095.019.020.0µg/LChlorodibromomethane 70-130 2.1 20.0
20.7 10411222.420.0µg/LChloroethane 60-140 7.8 20.0
19.2 96.097.019.420.0µg/LChloroform 70-130 1.0 20.0
17.4 87.092.018.420.0µg/LChloromethane 60-140 5.5 20.0
17.7 88.589.517.920.0µg/L2-Chlorotoluene 70-130 1.1 20.0
17.8 89.088.017.620.0µg/L4-Chlorotoluene 70-130 1.1 20.0
17.7 88.589.517.920.0µg/LDi-Isopropyl Ether (DIPE)70-130 1.1 20.0
19.4 97.010020.020.0µg/L1,2-Dibromo-3-Chloropropane 70-130 3.0 20.0
20.0 10099.019.820.0µg/L1,2-Dibromoethane 70-130 1.0 20.0
19.5 97.510220.420.0µg/LDibromomethane 70-130 4.5 20.0
19.7 98.597.019.420.0µg/L1,2-Dichlorobenzene 70-130 1.5 20.0
18.9 94.596.519.320.0µg/L1,3-Dichlorobenzene 70-130 2.0 20.0
18.6 93.095.519.120.0µg/L1,4-Dichlorobenzene 70-130 2.6 20.0
21.7 10911923.820.0µg/LDichlorodifluoromethane 60-140 9.2 20.0
Page 16 of 18Date:07/11/2023 05:26 PM
Page 61 of 65
Quality Control Data
23-181-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
Cruz N Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V35200QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V35199
LCS-V35199 LCSD-V35199Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
18.8 94.095.519.120.0µg/L1,1-Dichloroethane 70-130 1.5 20.0
19.0 95.097.519.520.0µg/L1,2-Dichloroethane 70-130 2.5 20.0
19.5 97.510320.620.0µg/L1,1-Dichloroethene 70-130 5.4 20.0
18.7 93.593.518.720.0µg/Lcis-1,2-Dichloroethene 70-130 0.0 20.0
19.5 97.596.019.220.0µg/Ltrans-1,2-Dichloroethene 70-130 1.5 20.0
18.7 93.595.019.020.0µg/L1,2-Dichloropropane 70-130 1.5 20.0
18.1 90.593.518.720.0µg/L1,3-Dichloropropane 70-130 3.2 20.0
19.3 96.510120.120.0µg/L2,2-Dichloropropane 70-130 4.0 20.0
20.2 10110420.820.0µg/L1,1-Dichloropropene 70-130 2.9 20.0
19.0 95.095.019.020.0µg/Lcis-1,3-Dichloropropene 70-130 0.0 20.0
19.2 96.092.018.420.0µg/Ltrans-1,3-Dichloropropene 70-130 4.2 20.0
506 101105526500µg/LEthanol 60-140 3.8 20.0
18.2 91.093.518.720.0µg/LEthylbenzene 70-130 2.7 20.0
20.5 10310120.120.0µg/LHexachlorobutadiene 70-130 1.9 20.0
15.9 79.579.515.920.0µg/L2-Hexanone 60-140 0.0 20.0
18.1 90.592.518.520.0µg/LIsopropylbenzene 70-130 2.1 20.0
18.8 94.095.019.020.0µg/L4-Isopropyl toluene 70-130 1.0 20.0
17.5 87.586.517.320.0µg/LMethyl Ethyl Ketone (MEK)60-140 1.1 20.0
19.7 98.598.519.720.0µg/LMethyl tert-butyl ether (MTBE)70-130 0.0 20.0
16.6 83.082.516.520.0µg/L4-Methyl-2-Pentanone 60-140 0.6 20.0
18.9 94.595.519.120.0µg/LMethylene Chloride 70-130 1.0 20.0
16.1 80.584.016.820.0µg/LNaphthalene 70-130 4.2 20.0
17.7 88.591.018.220.0µg/Ln-Propylbenzene 70-130 2.7 20.0
19.0 95.098.519.720.0µg/LStyrene 70-130 3.6 20.0
44.6 11211144.440.0µg/Ltert-Butyl Alcohol (TBA)40-140 0.4 20.0
44.8 11211345.040.0µg/Ltert-Butyl formate (TBF)40-140 0.4 20.0
Page 17 of 18Date:07/11/2023 05:26 PM
Page 62 of 65
Quality Control Data
23-181-0001Report No:
Project Description:
Client ID:Geological Resources, Inc.
Cruz N Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V35200QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V35199
LCS-V35199 LCSD-V35199Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
16.6 83.073.014.620.0µg/Ltert-Amyl Alcohol (TAA)40-140 12.8 20.0
39.1 97.797.238.940.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 0.5 20.0
20.1 10110120.220.0µg/L1,1,1,2-Tetrachloroethane 70-130 0.4 20.0
18.5 92.589.017.820.0µg/L1,1,2,2-Tetrachloroethane 70-130 3.8 20.0
20.0 10010420.820.0µg/LTetrachloroethene 70-130 3.9 20.0
19.4 97.094.518.920.0µg/LToluene 70-130 2.6 20.0
20.9 10510621.220.0µg/L1,2,3-Trichlorobenzene 70-130 1.4 20.0
21.2 10610721.320.0µg/L1,2,4-Trichlorobenzene 70-130 0.4 20.0
19.8 99.010020.020.0µg/L1,1,1-Trichloroethane 70-130 1.0 20.0
19.9 99.598.519.720.0µg/L1,1,2-Trichloroethane 70-130 1.0 20.0
20.5 10310621.120.0µg/LTrichloroethene 70-130 2.8 20.0
20.5 10310821.520.0µg/LTrichlorofluoromethane 60-140 4.7 20.0
18.3 91.593.018.620.0µg/L1,2,3-Trichloropropane 70-130 1.6 20.0
18.3 91.593.018.620.0µg/L1,2,4-Trimethylbenzene 70-130 1.6 20.0
18.1 90.594.018.820.0µg/L1,3,5-Trimethylbenzene 70-130 3.7 20.0
23.5 11811623.120.0µg/LVinyl Acetate 60-140 1.7 20.0
20.2 10110821.520.0µg/LVinyl Chloride 60-140 6.2 20.0
18.8 94.096.519.320.0µg/Lo-Xylene 70-130 2.6 20.0
39.9 99.710240.640.0µg/Lm,p-Xylene 70-130 1.7 20.0
18.0 90.088.017.620.0µg/L3,3-Dimethyl-1-butanol 70-130 2.2 20.0
93.092.24-Bromofluorobenzene (S)70-130
94.893.8Dibromofluoromethane (S)70-130
93.092.81,2-Dichloroethane - d4 (S)70-130
94.294.6Toluene-d8 (S)70-130
Page 18 of 18Date:07/11/2023 05:26 PM
Page 63 of 65
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:23-181-0001
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 1.5C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:06/30/2023 08:42:27
Special precautions or instructions included?
Comments:
Page 64 of 65
Page 65 of 65

APPENDIX C
Contaminant Mass Calculations

Area ID Well ID Area
(ft²)
Average Well
Depth
(ft.)
Average
Depth to
Water
(ft.)
Water Column
Height
(ft)
Volume
(ft³)
Volume
(L)
Effective
Porosity
Effective
Volume
(L)
MW-1
MW-2
MW-3
MW-4
MW-5
MW-6
MW-8
MW-11
Area Date Well Benzene
(μ/L)
Toluene
(μ/L)
Ethylbenzene
(μ/L)
Xylenes
(μ/L)
MTBE
(μ/L)
Naphthalene
(μ/L)
Total
(μ/L)
DTW
(ft.)
Average Water
Column Height
(ft.)
Total Average
Mass
(g)
Percent Red.To Date Red.
MW-1 460.00 264.00 417.00 1140.00 0.00 214.00 2495.00 18.14
MW-2 742.00 2530.00 814.00 4610.00 0.00 529.00 9225.00 17.83
MW-3 2.00 0.00 0.00 0.36 0.00 0.00 2.36 32.36
MW-4 7.30 22.10 0.73 9.70 0.15 0.00 39.98 14.83
MW-5 402.00 1580.00 162.00 568.00 0.00 143.00 2855.00 27.54
MW-6 221.00 127.00 53.30 268.00 0.22 96.70 766.22 31.84
MW-8 7.40 0.27 0.00 0.91 0.00 0.19 8.77 32.34
MW-11 43.60 0.68 1.30 3.10 0.00 4.70 53.38 27.18
Avg.235.66 565.51 181.04 825.01 0.05 123.45 1930.71 25.26
MW-1 522.00 367.00 219.00 905.00 0.00 77.90 2090.90 17.66
MW-2 291.00 906.00 476.00 2050.00 0.00 337.00 4060.00 17.47
MW-3 44.70 1.12 0.79 7.12 3.07 0.00 56.80 37.97
MW-4 0.56 94.90 0.26 0.81 0.00 2.38 98.91 2.48
MW-5 479.00 2130.00 537.00 2350.00 21.70 357.00 5874.70 28.47
MW-6 1.15 0.00 0.00 0.28 0.00 0.00 1.43 36.80
MW-8 0.00 0.00 0.00 0.00 0.00 0.00 0.00 38.33
MW-11 0.43 0.00 0.00 0.00 0.00 0.00 0.43 32.19
Avg.167.36 437.38 154.13 664.15 3.10 96.79 1522.90 26.42
MW-1 169.00 16.50 88.10 160.00 0.00 41.00 474.60 17.54
MW-2 810.00 1090.00 782.00 3820.00 0.00 548.00 7050.00 17.46
MW-3 7.59 0.00 0.00 0.00 0.52 0.00 8.11 40.74
MW-4 0.50 54.20 0.00 0.00 0.00 0.00 54.70 2.16
MW-5 1010.00 2730.00 789.00 2780.00 0.00 352.00 7661.00 31.31
MW-6 0.00 0.00 0.00 0.00 0.00 0.00 0.00 39.52
MW-8 0.00 0.00 0.00 0.00 0.00 0.00 0.00 38.33
MW-11 0.00 0.00 0.00 0.00 0.00 0.00 0.00 32.19
Avg 249.64 486.34 207.39 845.00 0.07 117.63 1906.05 27.41
Date
Average Water
Column Height
(ft.)
10/09/19 8.74
05/02/22 7.58
06/27/23 6.59
Notes:
• FP: Free Product
• Area of the contaminant plume is calculated from Figure 6.
• Height of the water column is calculated by subtracting the average depth to water from the average well depth of the referenced monitoring wells
• Volume of the contaminant plume is calculated by multiplying the area of the plume by the average height of the water column during each sampling event
• Effective porosity is assumed based on the sub-surface soil profile obtained from well construction records and soil boring logs
• Total mass was calculated by multiplying the total contaminant concentrations for the sampling event with effective volume
• Contaminant mass cannot be calculated in wells containing FP; therefore, the total contaminant mass is based on the known concentrations in the area for each sampling event.
• When areas couldn’t be sampled, the last known concentrations were used in the calculations.
1 10,649.3 34
APPENDIX C
PERCENTAGE REDUCTIONS
CRUZ N MART (INCIDENT NO. 42006)
Baseline Event
0.1625.26 8.74 93,102 2,636,337 421,814
606 -8.9%26%
Total Contaminant Mass
(g)
Percent Reduction Compared
to Previous Event Percent Reduction To Date
814 ------
557 46.2%32%
Area 1
06/27/23
7.58 31.6%
10/09/19
-8.9%606.396.59 25.5%
8.74
05/02/22 31.6%556.87
------814.40

APPENDIX D
Right To Enter Agreement