FA-3487_29522_CA_MRP_20230517

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
May 17, 2023

Mr. Ken Currie
NCDEQ-UST Section
Fayetteville Regional Office
Systel Building
225 Green Street, Suite 714
Fayetteville, NC 28301-5043

Re: Ground Water Monitoring Report
May 2023
Nic’s Pic Kwik #4
564 N. Patterson Street
Maxton, Robeson County
North Carolina
Facility ID Number: 0-00-0000019341
Incident Number: 29522/42236
GRI Project Number: 3024

Dear Mr. Currie,

Please find attached the referenced report for the abovementioned site.
If you have any questions, please contact William Regenthal at 704-845-4010.

Sincerely,
Geological Resources, Inc.

Leslie Maxtone-Graham
Administrative Assistant

Enclosure

Cc: Quality Oil & Gas Company, file

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Ground Water Monitoring Report
May 2023
Nic’s Pic Kwik #4
564 N. Patterson Street
Maxton, Robeson County
North Carolina
Facility ID Number: 0-00-0000019341
Incident Number: 29522/42236
GRI Project Number: 3024

Prepared for:

Quality Oil & Gas Company
203 West Broad Avenue
Rockingham, North Carolina 28379

May 17, 2023

William Regenthal, P.G.
Project Manager
Blake Butcher
Staff Scientist

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: May 17, 2023 Nic’s Pic Kwik #4
Project Manager: William Regenthal, P.G. GRI Project No. 3024
i

SITE INFORMATION
1. Site Identification
2. Nic’s Pic Kwik #4 (Facility ID 0-00-0000019341)
3. Incident Number 29522/42236 – Intermediate Risk (I220A)
4. Location of Source Area: 564 N. Patterson Street
Maxton, NC 28364
Robeson County
34.7434722°N, 79.3456666°W (Topographical Map)
2. Information about Contacts Associated with the Leaking UST System

UST Owner
Quality Oil Company
203 W Broad Ave
Rockingham, NC 28379
[e-mail]
910-997-3101

UST Operator
Quality Oil Company
203 W Broad Ave
Rockingham, NC 28379
[e-mail]
910-997-3101

Property Owner
Quality Oil Company
203 W Broad Ave
Rockingham, NC 28379
[e-mail]
910-997-3101

Property Occupant
Nic’s Pic Kwik #4
564 N. Patterson Street
Maxton, NC 28364
Email unknown
910-844-5173

Consultant/Contractor
Geological Resources, Inc.
3502 Hayes Road
Monroe, NC 28110
[e-mail]
704-845-4010

Analytical Laboratory
SGS North America, Inc.
4405 Vineland Road, Suite C-15
Orlando, FL 32811
State Certification No. 573
407-425-6700
3. Information about Release
 Release was confirmed in June 2008, and a second release on September 13, 2019
 An unknown amount of product was released from the leaking UST System
 Two 6,000-gallon gasoline USTs, one 4,000-gallon gasoline UST, one 4,000-gallon diesel UST, one 8,000-
gallon diesel UST and one 4,000-gallon kerosene UST are in use at the site

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: May 17, 2023 Nic’s Pic Kwik #4
Project Manager: William Regenthal, P.G. GRI Project No. 3024
ii
EXECUTIVE SUMMARY
Nic’s Pic Kwik #4 is located at 564 N. Patterson Street in Maxton, Robeson County, North Carolina. The
site is currently owned by Quality Oil Company and is operated by Nic’s Pic Kwik as a convenience store
and petroleum retail facility. A release was documented during a Site Check conducted in June 2008.
There are two 6,000-gallon gasoline, one 4,000-gallon gasoline, one 8,000-gallon diesel, one 4,000-gallon
diesel and one 4,000-gallon kerosene USTs currently in use at the site with ten associated dispenser
islands. The adjoining properties are a mixture of single family residential and commercial properties.
According to the information determined during receptor survey activities, no potable water supply wells
were identified within 1,000 feet of the site. Public water is available to the site and surrounding
properties within a 1,500-foot radius of the site.

On February 26, 2019, during annual compliance testing activities, a non-passing spill bucket was reported
for the 8,000-gallon diesel UST. A site check was conducted on September 4, 2019, confirming a release
at the 8,000-gallon UST spill bucket. The release was assigned incident number 42236. The contaminant
plumes for Incident Numbers 29522 and 42236 are commingled, and Incident Number 42236 was closed
by NCDEQ in January 2020.

A MMPE event was conducted from March 6 to March 10, 2023, at the site on monitoring wells MW-7,
MW-16 and RW-1. A total of 1,890 gallons of affected ground water was recovered during the MMPE
event. No measurable liquid free product was recovered during this MMPE event. The average fluid
recovery rate was 19.69 gallons per hour. Based on mass-removal calculations an additional 99.58 pounds
or 167.50 gallons of vapor phase hydrocarbons were removed at an average rate of 1.74 gallons per hour.

On April 25, 2023, two monitoring wells (MW-7 and MW-16) and one recovery well (RW-1) were gauged,
purged and sampled. Concentrations of requested method constituents that exceeded the MACs were
reported in the ground water samples collected from MW-7, MW-16 and RW-1. The concentration of
benzene reported in MW-16 exceeded the GCL.

Contaminant mass at the site has decreased by 68% since the July 2020 sampling event

Based on this information, the risk classification for the site should remain intermediate risk. It appears
that the MMPE event was successful in removing vapor-phase hydrocarbons from the site. The MMPE
event likely drew contaminants from beneath the dispenser island into the extraction wells. Additional
AFVR or MMPE events should be conducted at the site in order to continue to recover free product and
reduce the contaminant mass at the site. Semi-annual ground water monitoring should be continued at
the site until ground water concentrations decrease to less than the GCLs. Following the continued
reduction of contaminant mass in the vicinity of MW-7 and MW-16, a Feasibility Study for the use of
continued ground water extraction and/or the introduction of surfactant injection could be completed.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: May 17, 2023 Nic’s Pic Kwik #4
Project Manager: William Regenthal, P.G. GRI Project No. 3024
iii
ACRONYMS
ACM: Asbestos Containing Materials
AFVR: Aggressive Fluid-Vapor Recovery
ARR: Acknowledgement of Report Receipt
AS: Air Sparging
AST: Aboveground Storage Tank
ASTM: American Society for Testing and
Materials
BGS: Below Ground Surface
CAP: Corrective Action Plan
CFR: Code of Federal Regulations
CSA: Comprehensive Site Assessment
DPE: Dual Phase Extraction
DRO: Total Petroleum Hydrocarbons Diesel
Range Organics
DWM: Division of Waste Management
DWR: Department of Water Resources
EPA: Environmental Protection Agency
EPH: Extractible Petroleum Hydrocarbons
ESA: Environmental Site Assessment
GCL: Gross Contamination Level
GRI: Geological Resources, Inc.
GRO: Total Petroleum Hydrocarbons
Gasoline Range Organics
HERR: HAZMAT Emergency Response and
Remediation, Inc.
LSA: Limited Site Assessment
MAC: Maximum Allowable Concentration as
specified in T15A NCAC 2L.0202
MADEP: Massachusetts Department of
Environmental Protection
MCC: Maximum Contaminant Concentrations
MMPE: Mobile Multi-Phase Extraction
NAPL: Non-Aqueous Phase Liquid, “Free
Product”
NCDEQ: North Carolina Department of
Environmental Quality
NCDOT: North Carolina Department of
Transportation
NFA: Notice of No Further Action
NORR: Notice of Regulatory Requirements
NOV: Notice of Violation
NPDES: National Pollutant Discharge
Elimination System
NRP: Notice of Residual Petroleum
O&M: Operation and Maintenance
PAHs: Polynuclear Aromatic Hydrocarbons
PCA: Pre-Construction Assessment
RAL: Regulatory Action Level
SCLs: Soil Cleanup Level
SPCC: Spill Prevention Control and
Countermeasures
SVE: Soil Vapor Extraction
SVOCs: Semi-Volatile Organic Compounds
SWPPP: Stormwater Pollution Prevention Plan
TCLP: Toxicity Characteristic Leaching
Procedure (EPA Method SW-846 1311)
TOC: Top of Casing
TPH: Total Petroleum Hydrocarbons
USGS: United States Geological Survey
UST: Underground Storage Tank
UVF: Ultraviolet Fluorescence
VOCs: Volatile Organic Compounds
VPH: Volatile Petroleum Hydrocarbons

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: May 17, 2023 Nic’s Pic Kwik #4
Project Manager: William Regenthal, P.G. GRI Project No. 3024
TABLE OF CONTENTS
SITE INFORMATION ............................................................................................................................ i
EXECUTIVE SUMMARY ....................................................................................................................... ii
ACRONYMS ....................................................................................................................................... iii
1.0 SITE HISTORY AND CHARACTERIZATION ...................................................................................1
2.0 PRESENTATION OF CURRENT SITE ASSESSMENT INFORMATION/ COMPARISON TO HISTORICAL
ASSESSMENT INFORMATION ...................................................................................................2
3.0 FREE PRODUCT REMOVAL ........................................................................................................4
4.0 NATURAL ATTENUATION / NATURAL SOURCE ZONE DEPLETION STATUS ..................................4
5.0 CONCLUSIONS .........................................................................................................................5
6.0 LIMITATIONS ...........................................................................................................................5
7.0 STATEMENTS AND CERTIFICATION ...........................................................................................6

FIGURES
Figure 1: Site Location Map
Figure 2: Site Map
Figure 3: Water Table Surface Map
Figure 4: Ground Water Quality Map
Figure 5: Contaminant Mass Area Map

TABLES
Table 1: UST Owner and Operator Information
Table 2: UST System Information
Table 3: Well Construction and Gauging Information
Table 4: Summary of Ground Water Sample Analytical Results
APPENDICES
Appendix A: State Correspondence
Appendix B: Laboratory Report – Ground Water Samples
Appendix C: Contaminant Mass Calculations

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: May 17, 2023 Nic’s Pic Kwik #4
Project Manager: William Regenthal, P.G. GRI Project No. 3024
1
1.0 SITE HISTORY AND CHARACTERIZATION
GRI presents the results of the April 2023 ground water sampling event at the Nic’s Pic Kwik #4 site;
located at 564 N. Patterson Street in Maxton, Robeson County, North Carolina (Figure 1). These activities
were conducted in accordance with GRI Proposal No. 23-248, which was submitted to NCDEQ on April 12,
2023, and was approved as Task Authorization No. 29522-21, on April 13, 2023. State correspondence
has been included as Appendix A.

The site is currently owned by Quality Oil Company and is operated by Nic’s Pic Kwik as a convenience
store and petroleum retail facility. There are two 6,000-gallon gasoline, one 4,000-gallon gasoline, one
8,000-gallon diesel, one 4,000-gallon diesel and one 4,000-gallon kerosene USTs currently in use at the
site. UST owner/operator information and UST system information are included as Tables 1 and 2,
respectively. The Registered Tank Report is shown below:

The site and surrounding area are a mixture of single family residential, and commercial properties. The
site contains two buildings (the store and a car wash) and is primarily capped with concrete and asphalt.
The overall topography at the site is relatively flat.

A site compliance inspection conducted on January 18, 2006, found that the site’s USTs were not being
operated in compliance with North Carolina rules and statutes. A NORR dated February 12, 2007, required
the existing USTs be abandoned or internally inspected to determine compliance. The tanks were
internally inspected on February 28, 2007, and found to have pits and holes. The tanks were reportedly
repaired and re-lined. In accordance with a NOV dated December 27, 2007, Environmental
Hydrogeological Consultants (EHC) conducted a Site Check on June 9, 2008. Results indicated a release

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: May 17, 2023 Nic’s Pic Kwik #4
Project Manager: William Regenthal, P.G. GRI Project No. 3024
2
had occurred at the site. EHC completed a LSA on November 30, 2009. The receptor survey conducted
as part of the LSA did not identify any water supply wells within 250 feet of the source area and identified
three non-potable water supply wells within 1,500 feet of the site. Municipal water is available to
properties in the area. The site was classified as intermediate risk based on groundwater contamination
exceeding GCLs. A CSA was completed by Environ-Pro, P.C. on June 5, 2014. A Site Map showing the
locations of the monitoring wells and the structures on-site has been included as Figure 2.

A total of sixteen Type II monitoring wells (MW-1 through MW-16) and one Type III monitoring well (DW-
1) were installed at the site during previous ground water assessment activities. Three 96-hour MMPE
events and three 8-hour AFVR events were conducted at the site between December 2014 and March
2023, to reduce dissolved contaminant concentrations in site ground water, as well as vapor-phase
hydrocarbons in soil at the site.

Annual compliance testing activities on February 26, 2019, identified a non-passing spill bucket associated
with the 8,000-gallon diesel UST. A site check was completed by GRI on September 4, 2019, which
confirmed a release had occurred at the diesel spill bucket. The release was assigned the incident number
42236. The contaminant plumes for Incident Numbers 29522 and 42236 are commingled, and Incident
Number 42236 was closed by NCDEQ in January 2020.
2.0 PRESENTATION OF CURRENT SITE ASSESSMENT INFORMATION/ COMPARISON TO HISTORICAL
ASSESSMENT INFORMATION
On April 25, 2023, two Type II monitoring wells (MW-7 and MW-16) and one recovery well (RW-1) were
gauged, purged and sampled in accordance with NCDEQ guidelines. Depths to ground water in the Type
II monitoring wells ranged from 4.53 feet to 4.60 feet below the tops of well casings. Ground water
elevations in the Type II monitoring wells relative to a temporary benchmark with an assumed datum of
100.00 feet ranged from 94.51 to 95.64 feet. Ground water flow direction and horizontal hydraulic
gradient were not calculated during the April 2023 sampling event. Historically, ground water flow was
generally toward the northeast. Well construction and gauging information is presented in Table 3. A
Water Table Surface Map based on the Type II monitoring wells is included as Figure 3. A summary of
the current ground water gauging data is shown below:

Well ID
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(ft)
Free
Product
Thickness
(ft.)
Ground
Water
Elevation
(ft.)
MW-7 5 - 15 15 99.11 4.60 --- 94.51
MW-16 2 - 15 15 100.17 4.53 --- 95.64
RW-1 5 -15 15 98.86 4.32 --- 94.54

Ground water samples collected from the monitoring wells during the April 2023 sampling event were
submitted for laboratory analyses of VOCs plus oxygenates using EPA Method 6200B. Concentrations of
individual BTEX constituents, MTBE, naphthalene, TAA, TAME, TBA, n-propylbenzene, 1,2,4-
trimethylbenzene and/or 1,3,5-trimethylbenzene that exceeded the MACs were reported in the ground

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: May 17, 2023 Nic’s Pic Kwik #4
Project Manager: William Regenthal, P.G. GRI Project No. 3024
3
water samples collected from MW-7, MW-16 and RW-1. The concentration of benzene reported in MW-
16 exceeded the GCL. A summary of the analytical results for ground water samples collected on April 25,
2023, is presented in Table 4. A Ground Water Quality Map based on the April 2023 data is included as
Figure 4. A complete report of laboratory analyses of the ground water samples collected from the
monitoring wells during the April 2023 sampling event has been included as Appendix B. A summary of
the current ground water analytical data is shown below:
Contaminant
of Concern →
Be
n
z
e
n
e

To
l
u
e
n
e

Et
h
y
l
b
e
n
z
e
n
e

Xy
l
e
n
e
s

MT
B
E

Na
p
h
t
h
a
l
e
n
e

Well
ID
MACs (mg/l) 1 600 600 500 20 6
GCL (mg/l) 5,000 260,000 84,500 85,500 20,000 6,000
MW-7 4,500 7,580 898 7,750 514 579
MW-16 11,000 17,800 1,720 8,510 1,130 326
RW-1 3,060 4,640 708 3,540 416 178

The baseline contaminant mass at the site was determined based on the total benzene, toluene,
ethylbenzene, xylenes, MTBE and naphthalene concentrations from the July 2020 ground water sampling
event. The contaminant plume consists of one area (Area 1) based on the benzene concentrations during
the July 2020 ground water sampling event. The contaminant mass has been reduced by 67.8% in Area 1
since July 2020. Contaminant mass calculations have been included as Appendix C. A map of the
contaminant mass areas has been included as Figure 5. A chart depicting the overall declining trend in
contaminant mass is shown below:

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: May 17, 2023 Nic’s Pic Kwik #4
Project Manager: William Regenthal, P.G. GRI Project No. 3024
4

A CSA was completed in June 2014. A CAP has not been developed for this incident.

The site is located in the Coastal Plain Physiographic Province of North Carolina. The water table has a
seasonal high depth to water of approximately 3 to 11 feet bgs.
3.0 FREE PRODUCT REMOVAL
No free product was observed during the April 2023 groundwater sampling event. A MMPE event was
conducted from March 6 to March 10, 2023, at the site on monitoring wells MW-7, MW-16 and RW-1. A
total of 1,890 gallons of affected ground water was recovered during the MMPE event. No measurable
liquid free product was recovered during this MMPE event. The average fluid recovery rate was 19.69
gallons per hour. Based on mass-removal calculations an additional 99.58 pounds or 167.50 gallons of
vapor phase hydrocarbons were removed at an average rate of 1.74 gallons per hour.
4.0 NATURAL ATTENUATION / NATURAL SOURCE ZONE DEPLETION STATUS
Due to the site being in an active assessment phase, no natural attenuation monitoring plan is currently
in place at the site. A CAP has not yet been developed for this incident. The site risk classification is
currently ranked as intermediate since benzene concentrations remain above the GCL in MW-16. If
contaminant concentrations are reduced to less than the GCLs, then the site risk classification can be
lowered.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: May 17, 2023 Nic’s Pic Kwik #4
Project Manager: William Regenthal, P.G. GRI Project No. 3024
5
The contaminant mass at the site was reduced by 0.4% following the completion of the MMPE event in
March 2023. However, approximately 167.50 gallons of vapor-phase hydrocarbons were removed during
the March 2023 MMPE event. It appears that the MMPE event drew contaminants from beneath the
dispenser island into the extraction wells. Additional recovery wells could be installed within the benzene
GCL contaminant plume to continue to maximize the reduction of vapor-phase hydrocarbons in the soil
in the vicinity of the dispensers. Significant reductions in the benzene concentrations and the removal of
free product should occur prior to the implementation of surfactant injection or the introduction of other
contaminant reducing media. Once contaminant concentrations are significantly reduced, only then will
injection be a viable remedial option for this incident. A Feasibility Study exploring the above referenced
remedial options should be conducted.
5.0 CONCLUSIONS
 On April 25, 2023, a ground water sampling event was conducted. Two monitoring wells and one
recovery were gauged, purged and sampled.
 Concentrations individual BTEX constituents, MTBE, naphthalene, TAA, TAME, TBA, n-
propylbenzene, 1,2,4-trimethylbenzene and/or 1,3,5-trimethylbenzene that exceeded the MACs
were reported in the ground water samples collected from MW-7, MW-16 and RW-1.
 A concentration of benzene that exceeded the GCL was reported in the ground water sample
collected from MW-16.
 The contaminant mass has been reduced by 67.8% in Area 1 since July 2020. Contaminant mass
at the site was reduced by approximately 0.4% following the completion of the March 2023 MMPE
activities
 The March 2023 MMPE event removed approximately 167.50 gallons of vapor-phase
hydrocarbons from the extraction wells and surrounding soil.
 Based on this information, the risk classification for the site should remain intermediate risk. It
appears that the MMPE event was successful in removing vapor-phase hydrocarbons from the
site. The MMPE event likely drew contaminants from beneath the dispenser island into the
extraction wells. Additional AFVR or MMPE events should be conducted at the site in order to
continue to recover free product and reduce the contaminant mass at the site. Semi-annual
ground water monitoring should be continued at the site until ground water concentrations
decrease to less than the GCLs. Following the continued reduction of contaminant mass in the
vicinity of MW-7 and MW-16, a Feasibility Study for the use of continued ground water extraction
and/or the introduction of surfactant injection could be completed.
6.0 LIMITATIONS
This report has been prepared for the exclusive use of Quality Oil & Gas Company and the NCDEQ for
specific application to the referenced site in Robeson County, North Carolina. The assessment was
conducted based on the scope of work and level of effort desired by NCDEQ and with resources adequate
only for that scope of work. Our findings have been developed in accordance with generally accepted
standards of environmental practices in the State of North Carolina, available information, and our
professional judgment. No other warranty is expressed or implied.

FIGURES
Figure 1 Nic's Pic Kwik #4564 North Patterson Street Maxton, North Carolina Incident No. 29522/42236 GRI Project No. 3024

TABLES
UST ID Number 1 - 6 Facility ID Number
Owner or Operator?
Owner/OperatorQuality Oil Company 04/30/1985 to Present
Address Telephone Number
203 West Broad Avenue, Rockingham, NC 28379 910-997-3101
TABLE 1
UST OWNER/OPERATOR INFORMATION
NIC'S PIC KWIK #4 (INCIDENT NO. 29522/42236)
00-0-0000019341
Name of Owner or Operator Dates of Ownership / Operation
Page 1 of 1
Date: 9/16/19
Was Release
Associated
with UST
System?
(Yes / No)
1 Kerosene, Kero Mix NA 4,000 4/30/1985 Single Wall
Steel 64" x 24'Single Wall
FRP Current No
2 Diesel NA 4,000 4/30/1985 Single Wall
Steel 64" x 24'Single Wall
FRP Current No
3 Gasoline, Gas Mix NA 4,000 4/30/1985 Single Wall
Steel 64" x 24'Other Current No
4 Gasoline, Gas Mix NA 6,000 4/30/1985 Single Wall
Steel 8' x 16'Single Wall
FRP Current No
5 Gasoline, Gas Mix NA 6,000 4/30/1985 Single Wall
Steel 8' x 16'Single Wall
FRP Current No
6 Diesel NA 8,000 4/30/1985 Single Wall
Steel 8' x 21.3'Single Wall
FRP Current Yes
Capacity
(gallons)
Date
Installed
Construction
Details
Tank
Dimensions
Description of
Associated
Product Piping
Status
of
UST
UST SYSTEM INFORMATION
NIC'S PIC KWIK #4 (INCIDENT NO. 29522/42236)
Facility ID #: 0-0019341
UST
ID
No.
Current
or Most
Recent
Contents
Previous
Contents
Page 1 of 1
Date: 05/12/23 Facility ID#: 00-0-0000019341
04/17/13 5.83 0 93.64
01/19/15 5.13 0 94.34
05/18/15 4.62 0 94.85
05/10/16 3.79 0 95.68
05/01/17 4.24 0 95.23
05/21/18 6.76 0 92.71
11/28/18 2.68 0 96.79
11/20/19 NM NM NM Obstruction
05/04/21 NM NM NM Obstruction
04/17/13 7.11 0 92.72
01/19/15 4.34 0 95.49
05/18/15 6.09 0 93.74
11/28/18 3.79 0 96.04
11/20/19 10.40 0 89.43
05/04/21 5.78 0 94.05
12/06/21 11.95 0 87.88
06/08/22 12.21 0 87.62
12/06/22 11.80 0 88.03
04/17/13 3.28 0 95.29
01/19/15 2.39 0 96.18
05/18/15 3.98 0 94.59
11/28/18 2.40 0 96.17
11/20/19 7.90 0 90.67
04/17/13 5.34 0 94.11
01/19/15 5.74 0 93.71
05/18/15 4.43 0 95.02
11/28/18 2.70 0 96.75
11/20/19 8.77 0 90.68
05/04/21 3.68 0 95.77
12/06/21 10.95 0 88.50
06/08/22 10.51 0 88.94
12/06/22 9.72 0 89.73
04/17/13 7.52 0 92.81
01/19/15 NM NM NM Not found
05/18/15 6.73 0 93.60
05/10/16 4.99 0 95.34
05/01/17 5.56 0 94.77
05/21/18 7.25 0 93.08
11/28/18 NM NM NM Not found
11/20/19 NM NM NM Not found
04/17/13 4.76 0 94.57
01/19/15 4.73 0 94.60
05/18/15 4.11 0 95.22
05/10/16 4.42 0 94.91
11/28/18 2.71 0 96.62
11/20/19 6.99 0 92.34
04/17/13 4.95 0 94.16
12/15/14 7.42 0 91.69 Before MMPE Event
12/19/14 9.54 0 89.57 After MMPE Event
01/19/15 4.72 0 94.39
04/13/15 3.45 0 95.66 Before MMPE Event
04/17/15 7.00 0 92.11 After MMPE Event
05/18/15 4.44 0 94.67
05/10/16 4.22 0 94.89
05/01/17 4.44 0 94.67
05/21/18 6.16 0 92.95
10/23/18 4.31 0 94.80 Before AFVR Event
10/23/18 8.37 0 90.74 After AFVR Event
11/28/18 3.83 0 95.28
11/20/19 8.56 0 90.55
07/31/20 3.10 0 96.01
01/26/21 2.83 0 96.28 Before AFVR Event
01/26/21 5.08 0 94.03 After AFVR Event
05/04/21 3.27 0 95.84
12/06/21 12.55 0.10 86.65
03/17/22 9.70 0.00 89.41
06/08/22 11.52 0.02 87.61
12/06/22 11.31 0 87.80
03/06/23 5.73 0 93.38 Before MMPE Event
03/10/23 13.23 0 85.88 After MMPE Event
04/25/23 4.60 0 94.51
MW-3
99.45122 - 12206/07/11MW-4
MW-1 10/22/08 3 3 - 13 13 99.47
MW-2 02/23/11 2 2 - 12 99.8312
98.57122 - 12202/23/11
TABLE 3
WELL CONSTRUCTION AND GAUGING INFORMATION
NIC's PIC KWIK #4 (INCIDENT NO. 29522/42236)
Well ID Date Installed
(mm/dd/yy)
Date Water
Level
Measured
(mm/dd/yy)
Well Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
Bottom of
Well
(ft. BGS)
Top of Casing
Elevation*
(ft.)
Depth to Water
from Top of
Casing
(ft.)
Free Product
Thickness**
(ft.)
Ground Water
Elevation*
(ft.)
Comments
100.33205 - 20506/07/11MW-5
99.33205 - 20502/23/11MW-6
MW-7 04/11/13 5 5 - 15 15 99.11
Page 1 of 3
Date: 05/12/23 Facility ID#: 00-0-0000019341
TABLE 3
WELL CONSTRUCTION AND GAUGING INFORMATION
NIC's PIC KWIK #4 (INCIDENT NO. 29522/42236)
Well ID Date Installed
(mm/dd/yy)
Date Water
Level
Measured
Well Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
Bottom of
Well
(ft. BGS)
Top of Casing
Elevation*
(ft.)
Depth to Water
from Top of
Casing
Free Product
Thickness**
(ft.)
Ground Water
Elevation*
(ft.)
Comments
04/17/13 6.60 0 93.25
01/19/15 4.56 0 95.29
05/18/15 5.51 0 94.34
05/01/17 5.04 0 94.81
05/21/18 6.58 0 93.27
11/28/18 3.55 0 96.30
11/20/19 9.74 0 90.11
05/04/21 4.23 0 95.62
12/06/21 13.35 0 86.50
06/08/22 12.33 0 87.52
12/06/22 11.44 0 88.41
04/17/13 6.64 0 92.81
01/19/15 4.26 0 95.19
05/18/15 5.41 0 94.04
11/28/18 3.50 0 95.95
11/20/19 9.91 0 89.54
05/04/21 3.83 0 95.62
12/06/21 13.15 0 86.30
06/08/22 12.27 0 87.18
12/06/22 11.33 0 88.12
04/17/13 5.32 0 94.04
01/19/15 4.51 0 94.85
05/18/15 NM NM NM Destroyed
04/17/13 5.26 0 93.42
01/19/15 2.78 0 95.90
05/18/15 4.14 0 94.54
11/28/18 2.27 0 96.41
11/20/19 5.66 0 93.02
04/17/13 5.95 0 92.98
01/19/15 3.80 0 95.13
05/18/15 4.81 0 94.12
11/28/18 NM NM NM Inaccessible
11/20/19 9.60 0 89.33
05/04/21 3.88 0 95.05
12/06/21 NM NM NM Compromised
07/30/13 4.20 0 95.15
12/15/14 7.39 0 91.96 Before MMPE Event
12/19/14 10.08 0 89.27 After MMPE Event
01/19/15 3.69 0 95.66
04/13/15 4.00 0 95.35 Before MMPE Event
04/17/15 5.57 0 93.78 After MMPE Event
05/18/15 5.12 0 94.23
05/10/16 3.60 0 95.75
05/01/17 4.24 0 95.11
05/21/18 5.07 0 94.28
11/28/18 3.54 0 95.81
11/20/19 7.82 0 91.53
05/04/21 3.72 0 95.63
12/06/21 12.60 0 86.75
06/08/22 11.71 0 87.64
12/06/22 10.34 0 89.01
07/30/13 3.40 0 95.97
01/19/15 3.24 0 96.13
05/18/15 3.90 0 95.47
11/28/18 2.23 0 97.14
11/20/19 5.31 0 94.06
05/04/21 NM NM NM Damaged
11/20/19 11.44 0 87.53
05/04/21 4.11 0 94.86
12/06/21 12.70 0 86.27
06/08/22 10.90 0 88.07
12/06/22 10.88 0 88.09
01/26/21 2.81 0.45 97.75 Before AFVR Event
01/26/21 4.74 0 95.43 After AFVR Event
05/04/21 3.70 0 96.47
12/06/21 8.85 0 91.32
03/17/22 7.34 0 92.83
06/08/22 8.28 0 91.89
12/06/22 8.08 0 92.09
03/06/23 5.59 0 94.58 Before MMPE Event
03/10/23 Dry ---NM After MMPE Event
04/25/23 4.53 0 95.64
MW-8
99.45155 - 15504/11/13MW-9
98.97172 - 17211/20/19MW-15
99.85155 - 15504/11/13
5 - 15504/11/13
15 98.93
99.3515
MW-11
99.36
MW-12 04/11/13 5 5 - 15
MW-14 07/18/13 5 5 - 15 15
MW-16 01/11/21 2 2 - 15 15 100.17
MW-13
98.68155 - 15504/11/13
99.37
MW-10 04/11/13 5 5 - 15 15
Page 2 of 3
Date: 05/12/23 Facility ID#: 00-0-0000019341
TABLE 3
WELL CONSTRUCTION AND GAUGING INFORMATION
NIC's PIC KWIK #4 (INCIDENT NO. 29522/42236)
Well ID Date Installed
(mm/dd/yy)
Date Water
Level
Measured
Well Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
Bottom of
Well
(ft. BGS)
Top of Casing
Elevation*
(ft.)
Depth to Water
from Top of
Casing
Free Product
Thickness**
(ft.)
Ground Water
Elevation*
(ft.)
Comments
07/30/13 7.31 0 91.78
01/19/15 5.20 0 93.89
05/18/15 8.08 0 91.01
05/10/16 6.63 0 92.46
05/01/17 7.33 0 91.76
05/21/18 9.50 0 89.59
11/28/18 4.88 0 94.21
11/20/19 11.54 0 87.55
05/04/21 6.89 0 92.20
12/06/21 14.10 0 84.99
06/08/22 13.36 0 85.73
12/06/22 12.99 0 86.10
12/06/22 10.80 0 88.06
03/06/23 5.91 0 92.95 Before MMPE Event
03/10/23 Dry ---NM After MMPE Event
04/25/23 4.32 0 94.54
TMW-1 07/30/20 ---0 0 - 15 15 NM NM 0 NM Abandoned
TMW-2 07/30/20 ---0 0 - 15 15 NM NM 0 NM Abandoned
TMW-3 07/30/20 ---0 0 - 15 15 NM NM 0 NM Abandoned
TMW-4 07/30/20 ---0 0 - 15 15 NM NM 0 NM Abandoned
TMW-5 07/30/20 ---0 0 - 15 15 NM NM 0 NM Abandoned
TMW-6 07/30/20 ---0 0 - 15 15 NM NM 0 NM Abandoned
TMW-7 07/30/20 ---0 0 - 15 15 NM NM 0 NM Abandoned
Notes:
• * : Reference point for elevation measurements, elevations relative to a temporary benchmark with an assumed elevation 100.00 ft.
• ** : If free product is present in a well, ground water should be calculated by: [Top of Casing Elevation - Depth to Water] +
[free product thickness x 0.8581]
• ft. BGS : feet below ground surface
• NM: Not measured.
99.094540 - 454007/18/13DW-1
• Well construction information, well elevations and 2013 water levels from Table 4 in the Comprehensive Site Assessment Report, dated June 5, 2013, prepared by
Enviro-Pro, PC.
RW-1 09/20/22 5 5 - 15 15 98.86
Page 3 of 3
Facility ID #: 00-0-0000019341
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 40 128 10 70 0.4 70 70 400 400
5,000 260,000 80,000 50,000 20,000 6,000 40,000 12,800 10,000 5,900 400 30,500 26,100 28,500 24,100
04/17/13 1,000 36 190 232 180 120 NR NR NR BDL BDL 22 65 440 130
01/19/15 695 21.6 163 190.8 69.6 135 NR NR NR 11.1 J <2.5 27.3 82.7 427 122
05/19/15 743 22.9 164 146 86.2 149 NR NR NR 11.5 <0.82 30.5 77.7 256 91.9
05/10/16 811 21.2 145 117 60.2 132 NR NR NR 10.1 J <3.1 23.9 66.8 231 70.4
05/01/17 130 5.0 107 133 9.6 128 NR NR NR 13.3 <0.63 29.4 95.2 520 170
05/21/18 443 9.9 90.0 85.1 19.5 98.1 NR NR NR 12.9 <1.3 24.9 67.6 371 127
11/28/18 534 9.1 J 66.2 26.1 J 15.6 33.3 554 <4.0 122 J 2.5 J <2.5 9.1 J 19.3 39.3 19.8
11/20/19 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
04/17/13 BDL BDL BDL BDL BDL BDL NR NR NR BDL BDL BDL BDL BDL BDL
01/19/15 <0.10 <0.10 <0.10 <0.20 <0.10 <0.10 NR NR NR <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
05/19/15 <0.17 <0.17 <0.15 <0.43 <0.16 <0.12 NR NR NR <0.14 <0.16 <0.12 <0.16 <0.14 <0.14
11/28/18 0.18 J <0.13 <0.13 <0.25 0.40 J 1.1 <2.0 <0.20 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
11/20/19 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <2.0 <0.20 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
05/04/21 <0.13 0.20 J <0.13 <0.25 <0.13 <0.13 <2.0 <0.20 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
12/06/21 2.6 <0.16 5.8 0.16 J 0.17 J 17.8 <2.0 NR <2.0 0.45 J <0.13 2.3 2.8 0.15 J <0.13
06/08/22 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
12/06/22 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
04/17/13 BDL BDL BDL BDL BDL BDL NR NR NR BDL BDL BDL BDL BDL BDL
01/19/15 <0.10 <0.10 <0.10 <0.20 <0.10 <0.10 NR NR NR <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
05/19/15 <0.17 <0.17 <0.15 <0.43 <0.16 <0.12 NR NR NR <0.14 <0.16 <0.12 <0.16 <0.14 <0.14
11/28/18 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <2.0 <0.20 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
11/20/19 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <2.0 <0.20 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
04/17/13 1,900 1,100 1,100 1,500 500 600 NR NR NR 33 43 52 180 590 81
01/19/15 102 3.5 129 21.5 42.0 216 NR NR NR 2.4 J <0.50 13.1 31.6 12.6 1.8 J
05/19/15 15.8 1.0 17.5 3.6 32.7 122 NR NR NR 1.3 <0.16 3.2 5.9 4.3 1.2
05/10/16 NS NS NS NS NS NS NR NR NR NS NS NS NS NS NS
11/28/18 25.5 2.3 19.0 4.6 9.2 21.7 184 1.4 87.9 0.45 J <0.13 2.3 4.5 2.1 2.5
11/20/19 4.1 0.51 1.5 0.83 J 5.6 18.9 61 0.84 J 41.9 0.68 <0.13 0.53 0.97 0.20 J <0.13
05/04/21 0.88 2.5 0.24 J 0.36 J 5.7 1 17.7 0.61 J 28 <0.13 <0.13 0.21 J 0.28 J <0.13 <0.13
12/06/21 2.8 0.60 1.6 2.4 <0.13 4.5 57.2 NR 33.6 <0.13 <0.13 0.23 J 0.44 J <0.13 <0.13
06/08/22 1.34 1.63 1.03 2.84 1.60 2.72 25.4 NR 18.1 <0.180 <0.150 0.337 J 0.366 J 1.10 0.329 J
12/06/22 0.76 0.49 J 0.82 0.52 J 0.41 J 0.76 11.4 NR 14.2 <0.13 <0.13 0.32 J 0.40 J 0.14 J 0.49 J
TABLE 4
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
NIC's PIC KWIK #4 (INCIDENT NO. 29522/42236)
Date: 05/12/23
MAC (mg/l)
Analytical Methods →EPA Methods 6200B & 602
Contaminant of Concern
→
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To
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MW-2
MW-4
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MW-3
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GCL (mg/l)
1,
2
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4
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Page 1 of 6
Facility ID #: 00-0-0000019341
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 40 128 10 70 0.4 70 70 400 400
5,000 260,000 80,000 50,000 20,000 6,000 40,000 12,800 10,000 5,900 400 30,500 26,100 28,500 24,100
TABLE 4
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
NIC's PIC KWIK #4 (INCIDENT NO. 29522/42236)
Date: 05/12/23
MAC (mg/l)
Analytical Methods →EPA Methods 6200B & 602
Contaminant of Concern
→
Be
n
z
e
n
e
To
l
u
e
n
e
Et
h
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l
b
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n
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(T
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-
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1,
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GCL (mg/l)
1,
2
,
4
-
Tr
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b
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1,
3
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04/17/13 1.9 BDL BDL BDL 4.9 0.89 NR NR NR 1.1 BDL 0.97 BDL BDL BDL
01/19/15 NS NS NS NS NS NS NR NR NR NS NS NS NS NS NS
05/19/15 3.3 <0.17 0.50 <0.43 6.3 1.5 NR NR NR 1.9 <0.16 1.5 2.9 1.6 0.20 J
05/10/16 0.39 J <0.13 <0.13 <0.31 3.2 <0.13 NR NR NR 0.5 <0.13 0.37 J 0.22 J 0.22 J <0.13
05/01/17 0.5 <0.13 <0.13 <0.25 2.4 <0.13 NR NR NR 0.49 J <0.13 0.29 J 0.25 J <0.13 <0.13
05/21/18 <0.13 <0.13 <0.13 <0.26 1.3 <0.13 NR NR NR <0.13 <0.13 0.24 J <0.13 <0.13 <0.13
11/28/18 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
04/17/13 BDL BDL BDL BDL 0.62 BDL NR NR NR BDL BDL BDL BDL BDL BDL
01/19/15 <0.10 <0.10 <0.10 <0.20 0.19 J <0.10 NR NR NR <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
05/19/15 <0.17 <0.17 <0.15 <0.43 <0.16 <0.12 NR NR NR <0.14 <0.16 <0.12 <0.16 <0.14 <0.14
05/10/16 <0.13 <0.13 <0.13 <0.31 <0.13 <0.13 NR NR NR <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
11/28/18 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <2.0 <0.20 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
11/20/19 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <2.0 <0.20 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
04/17/13 15,000 31,000 2,800 14,700 9,300 370 NR NR NR 140 BDL 110 270 2,300 590
01/19/15 8,630 19,200 2,090 10,940 4,620 389 NR NR NR <50 <50 112 J 301 1,990 512
05/19/15 8,800 16,100 2,090 9,920 1,580 596 NR NR NR <72 <82 117 J 309 2,170 562
05/10/16 11,700 17,300 3,230 15,500 1,730 911 NR NR NR 109 J <31 194 596 4,250 1,110
05/01/17 9,640 13,700 2,390 11,400 731 2,560 NR NR NR <63 <63 97.3 J 322 2,580 626
05/21/18 11,200 24,100 6,110 28,300 1,490 1,870 NR NR NR 380 <31 503 1,740 10,800 3,280
11/28/18 10,500 22,400 2,820 14,300 1,160 632 11,200 326 J <1,000 <63 <63 112 J 357 2,810 705
11/20/19 12,800 24,300 3,450 16,200 1,670 854 24,400 439 J <1,000 <63 <63 142 J 404 3,150 867
07/31/20 9,160 17,700 3,090 15,700 623 779 NR NR NR NR NR NR NR NR NR
01/26/21 7,450 10,800 2,650 12,500 <31 662 NR NR NR NR NR NR NR NR NR
05/04/21 6,530 9,120 2,110 10,000 <63 562 6,110 143 J <1,000 <63 <63 98.0 J 272 2,260 645
12/06/21 FP FP FP FP FP FP FP NR FP FP FP FP FP FP FP
03/17/22 8,710 23,300 2,740 13,700 <130 547 NR NR NR NR NR NR NR NR NR
06/08/22 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
12/06/22 10,200 31,800 3,220 19,600 729 1,080 16,500 NR <1,000 96.4 J <63 153 J 451 4,060 1,060
03/06/23 7,550 13,900 1,970 17,400 474 961 9,680 297 <500 <31 <31 91.5 J 223 3,900 1,030
04/25/23 4,500 7,580 898 7,750 514 579 10,400 179 306 J 14.7 J <13 40.3 J 115 1800 470
MW-5
MW-6
MW-7
Page 2 of 6
Facility ID #: 00-0-0000019341
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 40 128 10 70 0.4 70 70 400 400
5,000 260,000 80,000 50,000 20,000 6,000 40,000 12,800 10,000 5,900 400 30,500 26,100 28,500 24,100
TABLE 4
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
NIC's PIC KWIK #4 (INCIDENT NO. 29522/42236)
Date: 05/12/23
MAC (mg/l)
Analytical Methods →EPA Methods 6200B & 602
Contaminant of Concern
→
Be
n
z
e
n
e
To
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GCL (mg/l)
1,
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04/17/13 BDL BDL BDL BDL BDL BDL NR NR NR BDL BDL BDL BDL BDL BDL
01/19/15 <0.10 <0.10 <0.10 <0.20 <0.10 <0.10 NR NR NR <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
05/19/15 <0.17 <0.17 <0.15 <0.43 <0.16 <0.12 NR NR NR <0.14 <0.16 <0.12 <0.16 <0.14 <0.14
05/01/17 <0.13 <0.13 <0.13 <0.25 <0.13 0.16 J NR NR NR <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
05/21/18 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 NR NR NR <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
11/28/18 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <2.0 <0.20 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
11/20/19 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <2.0 <0.20 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
05/04/21 <0.13 0.23 J <0.13 <0.25 <0.13 <0.13 <2.0 <0.20 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
12/06/21 0.7 3.4 0.99 3.8 <0.13 0.46 J <2.0 NR <2.0 <0.13 <0.13 <0.13 0.27 J 0.9 0.40 J
06/08/22 62.8 15.5 203 346 <1.40 88.6 157 NR <16.0 9.00 <1.50 17.8 64.5 363 115
12/06/22 0.21 J 1.3 0.45 J 1.87 <0.13 0.14 J <2.0 NR <2.0 <0.13 <0.13 <0.13 0.15 J 0.75 0.26 J
04/17/13 BDL BDL BDL BDL 1.0 BDL NR NR NR BDL BDL BDL BDL BDL BDL
01/19/15 <0.10 <0.10 <0.10 <0.20 1.0 0.19 J NR NR NR 0.11 J <0.10 0.38 J 0.27 J <0.10 <0.10
05/19/15 <0.17 <0.17 <0.15 <0.43 1.5 <0.12 NR NR NR <0.14 <0.16 <0.12 <0.16 <0.14 <0.14
11/28/18 <0.13 0.28 J <0.13 <0.25 0.67 <0.13 <2.0 <0.20 4.3 J <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
11/20/19 <0.13 0.15 J <0.13 <0.25 0.62 <0.13 <2.0 <0.20 <2.0 <0.13 <0.13 0.24 J <0.13 <0.13 <0.13
05/04/21 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <2.0 <0.20 <2.0 <0.13 <0.13 0.17 J <0.13 <0.13 <0.13
12/06/21 <0.13 0.40 J <0.13 0.14 J 0.46 J 0.30 J <2.0 NR <2.0 <0.13 <0.13 0.22 J <0.13 <0.13 <0.13
06/08/22 1.51 7.20 1.18 6.01 0.470 J 1.19 <1.90 NR <1.60 <0.180 <0.150 0.411 J 0.268 J 1.45 0.348 J
12/06/22 <0.13 0.54 <0.13 <0.25 <0.13 <0.13 <2.0 NR 5.1 J <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
04/17/13 280 810 580 4,000 82 160 NR NR NR BDL BDL 22 45 1,600 440
01/19/15 <0.10 0.37 J 0.19 J 1.23 J <0.10 0.26 J NR NR NR <0.10 <0.10 <0.10 0.14 J 0.73 0.25 J
05/19/15
04/17/13 BDL BDL BDL BDL 21 BDL NR NR NR BDL BDL BDL BDL BDL BDL
01/19/15 <0.10 <0.10 <0.10 <0.20 3.3 <0.10 NR NR NR <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
05/19/15 <0.17 <0.17 <0.15 <0.43 4.0 <0.12 NR NR NR <0.14 <0.16 <0.12 <0.16 <0.14 <0.14
11/28/18 <0.13 <0.13 <0.13 <0.25 0.16 J <0.13 <2.0 <0.20 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
11/20/19 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <2.0 <0.20 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
04/17/13 BDL BDL BDL BDL 2.2 BDL NR NR NR BDL BDL BDL BDL BDL BDL
01/19/15 <0.10 <0.10 <0.10 <0.20 1.1 <0.10 NR NR NR <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
05/19/15 <0.17 <0.17 <0.15 <0.43 1.1 <0.12 NR NR NR <0.14 <0.16 <0.12 <0.16 <0.14 <0.14
11/28/18 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
11/20/19 <0.13 <0.13 <0.13 <0.25 0.66 <0.13 <2.0 <0.20 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
05/04/21 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <2.0 <0.20 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
Destroyed
MW-10
MW-8
MW-9
MW-11
MW-12
Page 3 of 6
Facility ID #: 00-0-0000019341
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 40 128 10 70 0.4 70 70 400 400
5,000 260,000 80,000 50,000 20,000 6,000 40,000 12,800 10,000 5,900 400 30,500 26,100 28,500 24,100
TABLE 4
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
NIC's PIC KWIK #4 (INCIDENT NO. 29522/42236)
Date: 05/12/23
MAC (mg/l)
Analytical Methods →EPA Methods 6200B & 602
Contaminant of Concern
→
Be
n
z
e
n
e
To
l
u
e
n
e
Et
h
y
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b
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n
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Xy
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s
MT
B
E
te
r
t
-
A
m
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l

m
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t
h
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et
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r

(
T
A
M
E
)
te
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-
A
m
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a
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c
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o
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(T
A
A
)
Na
p
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t
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a
l
e
n
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te
r
t
-
B
u
t
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a
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c
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(T
B
A
)
n-
B
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b
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n
z
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1,
2
-
D
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t
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a
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Is
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o
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b
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n
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n-
P
r
o
p
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b
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n
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GCL (mg/l)
1,
2
,
4
-
Tr
i
m
e
t
h
y
l
b
e
n
z
e
n
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1,
3
,
5
-
Tr
i
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t
h
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l
b
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n
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n
e
07/30/13 6,600 21,000 3,000 14,800 440 520 NR NR NR 67 BDL 110 390 2,700 740
01/19/15 565 2,380 777 3,550 76.4 179 NR NR NR 32.5 <5.0 40.1 172 1,190 360
05/19/15 343 459 362 1,210 28.3 151 NR NR NR 20.3 <3.3 29.0 105 568 146
05/10/16 726 1,870 974 2,520 33.8 291 NR NR NR 21.4 J <6.3 46.2 206 1,130 300
05/01/17 633 1,410 808 2,140 16.8 J 203 NR NR NR 15.3 J <6.3 34.5 163 1,010 267
05/21/18 20.5 48.0 75.9 114 0.29 J 25.7 NR NR NR 8.6 <0.13 7.6 30.7 145 E 27.9
11/28/18 140 166 454 801 <1.3 133 <20 <2.0 <20 15.3 <1.3 24.9 108 462 136
11/20/19 199 179 563 1,190 <1.3 189 483 4.1 J <20 22.5 <1.3 33.5 143 813 232
05/04/21 668 688 955 2,250 <6.3 254 1,330 12.2 J <100 15.4 J <6.3 42.4 148 992 295
12/06/21 302 E 21.5 560 E 754 E <0.13 224 1,070 NR <2.0 17.3 <0.13 44.2 127 567 E 168
06/08/22 1.01 6.35 1.65 8.81 <0.140 1.44 <1.90 NR <1.60 <0.180 <0.150 <0.180 0.459 J 3.18 0.880
12/06/22 123 205 422 838 <1.3 116 <20 NR <20 12.3 <1.3 22.5 99.8 494 140
07/30/13 BDL BDL BDL BDL 4.4 BDL NR NR NR BDL BDL BDL BDL BDL BDL
01/19/15 <0.10 2.6 0.16 J <0.20 0.13 J <0.10 NR NR NR <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
05/19/15 <0.17 4.4 <0.15 <0.43 0.66 <0.12 NR NR NR <0.14 <0.16 <0.12 <0.16 <0.14 <0.14
11/28/18 <0.13 11.8 <0.13 <0.25 <0.13 <0.13 <2.0 <0.20 2.3 J <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
11/20/19 <0.13 0.87 0.13 J <0.25 <0.13 <0.13 <2.0 <0.20 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
11/20/19 19.2 0.23 J 1.5 0.95 J 0.87 74.8 NR NR NR NR NR NR NR NR NR
05/04/21 4.3 0.22 J 3.2 0.31 J <0.13 25.9 <2.0 <0.20 <2.0 0.58 <0.13 1.8 2.3 0.38 J <0.13
12/06/21 4.0 <0.13 9.3 0.70 J 0.27 J 39.9 11.1 NR <2.0 1.1 <0.13 4.4 5.4 0.6 0.18 J
06/08/22 8.04 26.9 14.2 34.1 0.912 J 49.7 12.8 NR <1.60 1.60 <0.150 6.29 7.88 14.5 3.53
12/06/22 6.0 0.23 J 10.1 1.2 J 0.49 J 94.1 <2.0 NR 5.0 J 1.8 <0.13 7.2 8.7 3.5 0.46 J
05/04/21 18,900 36,800 3,280 16,500 4,190 608 J 22,800 J 804 J <5,000 <310 <310 <310 <310 2,090 670 J
12/06/21 17,600 29,900 2,790 13,750 2,580 658 21,600 NR <2,000 <130 <130 <130 253 J 1,920 549
03/17/22 13.6 23.2 2.4 11.1 1.4 0.44 J NR NR NR NR NR NR NR NR NR
06/08/22 15,800 29,800 3,220 15,600 2,110 785 20,800 NR 745 J 35.7 J <15.0 126 405 2,860 745
12/06/22 11,200 25,200 3,280 16,200 838 977 <2,000 NR <2,000 <130 <130 171 J 630 4,330 1,190
03/06/23 13,400 18,500 2,270 10,700 2,190 506 24,200 1,060 <1,000 19.0 J <13 81.1 239 1,970 497
04/25/23 11,000 17,800 1,720 8,510 1,130 326 11,100 481 J <1000 <63 <63 <63 200 J 1130 316
12/06/22 9,490 25,100 2,550 14,200 809 548 11,900 NR <2,000 <130 <130 <130 300 J 2,530 767
03/06/23 9,890 16,100 2,170 11,100 2,370 521 23,500 350 <1,000 14.2 J <13 84.7 173 2,010 584
04/25/23 3,060 4,640 708 3,540 416 178 3,480 66.4 J <200 <13 <13 31.7 J 97.3 777 228
MW-14
MW-15
MW-16
RW-1
MW-13
Page 4 of 6
Facility ID #: 00-0-0000019341
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 40 128 10 70 0.4 70 70 400 400
5,000 260,000 80,000 50,000 20,000 6,000 40,000 12,800 10,000 5,900 400 30,500 26,100 28,500 24,100
TABLE 4
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
NIC's PIC KWIK #4 (INCIDENT NO. 29522/42236)
Date: 05/12/23
MAC (mg/l)
Analytical Methods →EPA Methods 6200B & 602
Contaminant of Concern
→
Be
n
z
e
n
e
To
l
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n
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Et
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b
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(T
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1,
2
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b
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z
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P
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b
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n
z
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GCL (mg/l)
1,
2
,
4
-
Tr
i
m
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t
h
y
l
b
e
n
z
e
n
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1,
3
,
5
-
Tr
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t
h
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l
b
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n
z
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07/30/13 1,500 5,500 700 3,500 660 190 NR NR NR 29 BDL 47 120 820 230
01/19/15 370 2.7 J 4.5 J 21.2 563 60.2 NR NR NR 9.5 J <2.0 9.5 J 3.3 J 15.2 3.9 J
05/19/15 311 2.7 J <1.5 9.8 J 312 63.8 NR NR NR <1.4 <1.6 1.8 J <1.6 10.9 1.8 J
05/10/16 45.8 0.69 0.87 1.8 162 21.9 NR NR NR 1.5 <0.13 3.8 0.70 2.5 0.22 J
05/01/17 10.6 0.22 J 0.24 J 1.2 J 70.5 15.5 NR NR NR 0.26 J <0.13 1.6 <0.13 0.26 J <0.13
05/21/18 238 1.4 J <0.63 5.1 J 282 18.6 NR NR NR <0.63 <0.63 0.71 J <0.63 <0.63 <0.63
11/28/18 487 5.3 J 3.1 J <5.0 469 35.6 1,510 26.6 <40 <2.5 <2.5 2.6 J <2.5 <2.5 <2.5
11/20/19 4.0 2 0.99 3.7 46.3 0.48 J 142 2.5 <2.0 <0.13 <0.13 <0.13 0.20 J 0.78 0.33 J
05/04/21 0.45 J 0.59 0.17 J 0.78 J 3.4 0.19 J <2.0 <0.20 <2.0 <0.13 <0.13 <0.13 <0.13 0.17 J <0.13
12/06/21 7.9 181 73.9 418 <1.3 35.5 <20 NR <20 3.0 J <1.3 5.9 18.9 172 47
06/08/22 1.44 17.1 14.8 104 0.381 J 61.3 <1.90 NR <1.60 5.26 <0.150 2.88 12.6 152 32.6
12/06/22 <0.13 <0.13 <0.13 <0.25 0.75 0.18 J <2.0 NR <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
TW-1 07/30/20 35,400 53,100 4,720 25,400 3,470 758 NR NR NR NR NR NR NR NR NR
TW-2 07/30/20 2,210 5,940 700 3,120 250 382 NR NR NR NR NR NR NR NR NR
TW-3 07/30/20 1,080 5,570 1,280 5,300 27.2 201 NR NR NR NR NR NR NR NR NR
TW-4 07/31/20 1,970 9,650 3,480 17,700 130 1,360 NR NR NR NR NR NR NR NR NR
TW-5 07/30/20 0.14 J <0.13 <0.13 <0.25 1.8 0.55 NR NR NR NR NR NR NR NR NR
TW-6 07/30/20 <0.13 <0.13 <0.13 <0.25 0.24 J 0.13 J NR NR NR NR NR NR NR NR NR
TW-7 07/31/20 0.18 J 0.26 J 0.23 J 0.67 J 2.0 0.87 NR NR NR NR NR NR NR NR NR
DW-1
Page 5 of 6
Facility ID #: 00-0-0000019341
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 40 128 10 70 0.4 70 70 400 400
5,000 260,000 80,000 50,000 20,000 6,000 40,000 12,800 10,000 5,900 400 30,500 26,100 28,500 24,100
TABLE 4
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
NIC's PIC KWIK #4 (INCIDENT NO. 29522/42236)
Date: 05/12/23
MAC (mg/l)
Analytical Methods →EPA Methods 6200B & 602
Contaminant of Concern
→
Be
n
z
e
n
e
To
l
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n
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Et
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b
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GCL (mg/l)
1,
2
,
4
-
Tr
i
m
e
t
h
y
l
b
e
n
z
e
n
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1,
3
,
5
-
Tr
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t
h
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l
b
e
n
z
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01/19/15 <0.10 <0.10 <0.10 <0.20 <0.10 <0.10 NR NR NR <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
05/19/15 <0.17 <0.17 <0.15 <0.43 <0.16 <0.12 NR NR NR <0.14 <0.16 <0.12 <0.16 <0.14 <0.14
05/10/16 <0.13 <0.13 <0.13 <0.31 <0.13 <0.13 NR NR NR <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
05/01/17 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 NR NR NR <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
05/21/18 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 NR NR NR <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
11/28/18 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <2.0 <0.20 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
11/20/19 <0.13 0.45 J <0.13 <0.25 <0.13 <0.13 <2.0 <0.20 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/30/20 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 NR NR NR NR NR NR NR NR NR
12/06/21 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 NR NR NR NR NR NR NR NR NR
03/17/22 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 NR NR NR NR NR NR NR NR NR
06/08/22 <0.180 <0.220 <0.170 <0.21 <0.140 <0.470 NR NR NR <0.180 <0.150 <0.180 <0.190 <0.190 <0.180
12/06/22 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 NR NR NR <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
03/06/23 <0.13 1.2 <0.13 <0.25 <0.13 <0.13 NR NR NR <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
04/25/23 <0.13 7.80 0.31 J <0.25 <0.13 0.20 J NR NR NR <0.13 <0.13 <0.13 0.19 J <0.13 <0.13
Notes:
• < : Less than the method detection limit specified in the laboratory report
• MAC: Maximum allowable concentrations specified in 15A NCAC 2L.0202.
• GCL: Gross contamination level.
• Results in bold face type exceeded the MACs.
• Results in italics type exceeded the GCLs.
• Results reported in µg/l (micrograms per liter).
• NS: Not sampled.
• NR: Analyses not requested.
• BDL: Concentration below laboratory detection limit.
• 2013 analytical data from Table 8 in the Cormprehensive Site Assessment Report, dated June 5, 2013, prepared by Enviro-Pro PC.
• Refer to the laboratory analytical report for other compounds detected which did not exceed the MAC.
• J: Estimated value.
• E: Value exeeds calibration range.
Trip Blank
Page 6 of 6

APPENDICES

APPENDIX A
State Correspondence
North Carolina Department of Environmental Quality | Division of Waste Management
Fayetteville Regional Office | 225 Green Street | Suite 714 | Systel Building | Fayetteville, NC 28301 | [phone]
April 10, 2023
DELIVERED BY EMAIL ATTACHMENT
Mr. Jimmy McDonald
Quality Oil Company, Inc.
203 West Broad Avenue
Rockingham, NC 28379
Re: Acknowledgment of Report Receipt
15A NCAC 2L .0407(d)
Risk-based Assessment and Corrective Action
for Petroleum Underground Storage Tanks
Nic’s Pic Kwik 4
564 N. Patterson Street
Maxton, Robeson County
Incident Number: 29522
Risk Classification: Intermediate
Rank: I-220-A
Dear Mr. McDonald:
The FreeProductRecovery Report dated April 4, 2023, has been reviewed and this office requests that
you conduct a follow up ground water sampling event using MW-7, MW-16 & RW-1 as soon as practical. This information should be used to evaluate the March 2023 MMPE event and make
decisions if additional recovery wells and another MMPE event should be considered for a combined
pilot test to be used in the preparation of a Feasibility Study following approval of the remedial effort by
UST Section staff.
If you have questions regarding the information contained in this letter, please contact me at the
Fayetteville Regional Office address below or at [phone].
Sincerely,
Kenneth E. Currie
Hydrogeologist
Fayetteville Regional Office
UST Section, Division of Waste Management
c: Mr. William Regenthal, L.G., Geological Resources, Inc., Winterville, NC (email copy)
FRO Electronic Incident File #29522
3024 Received APR 19 2023

APPENDIX B
Laboratory Report – Ground Water Samples

05/09/23
Technical Report for
GRI (Geological Resources Inc.)
Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
29522/3024
SGS Job Number: FC5611
Sampling Date: 04/25/23
Report to:
GRI (Geological Resources Inc.)
[e-mail]
ATTN: William Regenthal
Total number of pages in report:
Certifications: FL(E83510), LA(03051), KS(E-10327), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AL, AK, AR, CT, IA, KY, MA, MI. MS, ND, NH, NV, OK, OR, IL, UT, VT, WA, WI, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc.  4405 Vineland Road  Suite C-15  Orlando, FL 32811  tel: [phone]  fax: [phone]
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Muna Mohammed 407-425-6700
Norm Farmer
Technical Director
Orlando, FL 05/09/23
e-Hardcopy 2.0
Automated Report
39
SGS is the sole authority for authorizing edits or modifications to this document.
Unauthorized modification of this report is strictly prohibited.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions
The results set forth herein are provided by SGS North America Inc.
Please share your ideas about
how we can serve you better at:
[e-mail]
1 of 39
FC5611
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................6
3.1: FC5611-1: TRIP BLANK .............................................................................................7
3.2: FC5611-2: MW-16 ........................................................................................................9
3.3: FC5611-3: RW-1 ...........................................................................................................12
3.4: FC5611-4: MW-7 ..........................................................................................................15
Section 4: Misc. Forms ............................................................................................................18
4.1: Chain of Custody ...........................................................................................................19
Section 5: MS Volatiles - QC Data Summaries .....................................................................21
5.1: Method Blank Summary ................................................................................................22
5.2: Blank Spike Summary ...................................................................................................28
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................34
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Sample Summary
GRI (Geological Resources Inc.)
Job No:FC5611
Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
Project No: 29522/3024
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
This report contains results reported as ND = Not detected. The following applies:
Organics ND = Not detected above the MDL
FC5611-1 04/25/23 13:31 JB 04/27/23 AQ Trip Blank Water TRIP BLANK
FC5611-2 04/25/23 14:04 JB 04/27/23 AQ Ground Water MW-16
FC5611-3 04/25/23 14:21 JB 04/27/23 AQ Ground Water RW-1
FC5611-4 04/25/23 14:43 JB 04/27/23 AQ Ground Water MW-7
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Summary of Hits Page 1 of 2
Job Number:FC5611
Account:GRI (Geological Resources Inc.)
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
Collected:04/25/23
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FC5611-1 TRIP BLANK
Ethylbenzene 0.31 J 0.50 0.13 ug/l SM 6200B
Naphthalene 0.20 J 0.50 0.13 ug/l SM 6200B
n-Propylbenzene 0.19 J 0.50 0.13 ug/l SM 6200B
Toluene 7.8 0.50 0.13 ug/l SM 6200B
FC5611-2 MW-16
Benzene 11000 250 63 ug/l SM 6200B
Ethylbenzene 1720 250 63 ug/l SM 6200B
Methyl Tert Butyl Ether 1130 250 63 ug/l SM 6200B
Naphthalene 326 250 63 ug/l SM 6200B
n-Propylbenzene 200 J 250 63 ug/l SM 6200B
Tert-Amyl Alcohol 11100 5000 1000 ug/l SM 6200B
Tert-Amyl Methyl Ether 481 J 500 100 ug/l SM 6200B
Toluene 17800 250 63 ug/l SM 6200B
1,2,4-Trimethylbenzene 1130 250 63 ug/l SM 6200B
1,3,5-Trimethylbenzene 316 250 63 ug/l SM 6200B
m,p-Xylene 6020 500 63 ug/l SM 6200B
o-Xylene 2500 250 63 ug/l SM 6200B
Xylene (total)8510 750 130 ug/l SM 6200B
FC5611-3 RW-1
Benzene 3060 50 13 ug/l SM 6200B
Ethylbenzene 708 50 13 ug/l SM 6200B
Isopropylbenzene 31.7 J 50 13 ug/l SM 6200B
Methyl Tert Butyl Ether 416 50 13 ug/l SM 6200B
Naphthalene 178 50 13 ug/l SM 6200B
n-Propylbenzene 97.3 50 13 ug/l SM 6200B
Tert-Amyl Alcohol 3480 1000 200 ug/l SM 6200B
Tert-Amyl Methyl Ether 66.4 J 100 20 ug/l SM 6200B
Toluene 4640 50 13 ug/l SM 6200B
1,2,4-Trimethylbenzene 777 50 13 ug/l SM 6200B
1,3,5-Trimethylbenzene 228 50 13 ug/l SM 6200B
m,p-Xylene 2490 100 13 ug/l SM 6200B
o-Xylene 1050 50 13 ug/l SM 6200B
Xylene (total)3540 150 25 ug/l SM 6200B
FC5611-4 MW-7
Benzene 4500 50 13 ug/l SM 6200B
n-Butylbenzene 14.7 J 50 13 ug/l SM 6200B
o-Chlorotoluene 57.0 50 13 ug/l SM 6200B
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Summary of Hits Page 2 of 2
Job Number:FC5611
Account:GRI (Geological Resources Inc.)
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
Collected:04/25/23
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
Ethylbenzene 898 50 13 ug/l SM 6200B
Isopropylbenzene 40.3 J 50 13 ug/l SM 6200B
Methyl Tert Butyl Ether 514 50 13 ug/l SM 6200B
Naphthalene 579 50 13 ug/l SM 6200B
n-Propylbenzene 115 50 13 ug/l SM 6200B
Tert-Amyl Alcohol 10400 1000 200 ug/l SM 6200B
Tert-Amyl Methyl Ether 179 100 20 ug/l SM 6200B
Tert-Butyl Alcohol 306 J 1000 200 ug/l SM 6200B
Toluene 7580 130 31 ug/l SM 6200B
1,2,4-Trimethylbenzene 1800 50 13 ug/l SM 6200B
1,3,5-Trimethylbenzene 470 50 13 ug/l SM 6200B
m,p-Xylene 5150 100 13 ug/l SM 6200B
o-Xylene 2600 50 13 ug/l SM 6200B
Xylene (total)7750 150 25 ug/l SM 6200B
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Sample Results
Report of Analysis
Orlando, FL
Section 3
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Report of Analysis Page 1 of 2
Client Sample ID:TRIP BLANK
Lab Sample ID:FC5611-1 Date Sampled:04/25/23
Matrix:AQ - Trip Blank Water Date Received:04/27/23
Method:SM 6200B Percent Solids:n/a
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A936.D 1 05/03/23 13:58 TD n/a n/a V3A46
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Client Sample ID:TRIP BLANK
Lab Sample ID:FC5611-1 Date Sampled:04/25/23
Matrix:AQ - Trip Blank Water Date Received:04/27/23
Method:SM 6200B Percent Solids:n/a
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene 0.31 0.50 0.13 ug/l J
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene 0.20 0.50 0.13 ug/l J
103-65-1 n-Propylbenzene 0.19 0.50 0.13 ug/l J
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene 7.8 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 106%70-130%
17060-07-0 1,2-Dichloroethane-D4 107%70-130%
2037-26-5 Toluene-D8 97%70-130%
460-00-4 4-Bromofluorobenzene 102%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 3
Client Sample ID:MW-16
Lab Sample ID:FC5611-2 Date Sampled:04/25/23
Matrix:AQ - Ground Water Date Received:04/27/23
Method:SM 6200B Percent Solids:n/a
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A916.D 500 05/02/23 14:58 TD n/a n/a V3A45
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 11000 250 63 ug/l
108-86-1 Bromobenzene ND 250 63 ug/l
74-97-5 Bromochloromethane ND 250 63 ug/l
75-27-4 Bromodichloromethane ND 250 63 ug/l
75-25-2 Bromoform ND 250 63 ug/l
104-51-8 n-Butylbenzene ND 250 63 ug/l
135-98-8 sec-Butylbenzene ND 250 63 ug/l
98-06-6 tert-Butylbenzene ND 250 63 ug/l
56-23-5 Carbon Tetrachloride ND 250 63 ug/l
108-90-7 Chlorobenzene ND 250 63 ug/l
75-00-3 Chloroethane ND 250 100 ug/l
67-66-3 Chloroform ND 250 63 ug/l
95-49-8 o-Chlorotoluene ND 250 63 ug/l
106-43-4 p-Chlorotoluene ND 250 63 ug/l
124-48-1 Dibromochloromethane ND 250 63 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 250 120 ug/l
106-93-4 1,2-Dibromoethane ND 250 63 ug/l
75-71-8 Dichlorodifluoromethane ND 250 100 ug/l
95-50-1 1,2-Dichlorobenzene ND 250 63 ug/l
541-73-1 1,3-Dichlorobenzene ND 250 63 ug/l
106-46-7 1,4-Dichlorobenzene ND 250 63 ug/l
75-34-3 1,1-Dichloroethane ND 250 63 ug/l
107-06-2 1,2-Dichloroethane ND 250 63 ug/l
75-35-4 1,1-Dichloroethylene ND 250 63 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 250 63 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 250 63 ug/l
78-87-5 1,2-Dichloropropane ND 250 63 ug/l
142-28-9 1,3-Dichloropropane ND 250 63 ug/l
594-20-7 2,2-Dichloropropane ND 250 63 ug/l
563-58-6 1,1-Dichloropropene ND 250 63 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 250 63 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 250 63 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 3
Client Sample ID:MW-16
Lab Sample ID:FC5611-2 Date Sampled:04/25/23
Matrix:AQ - Ground Water Date Received:04/27/23
Method:SM 6200B Percent Solids:n/a
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 250 63 ug/l
64-17-5 Ethyl Alcohol a ND 50000 33000 ug/l
100-41-4 Ethylbenzene 1720 250 63 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 250 63 ug/l
87-68-3 Hexachlorobutadiene ND 250 63 ug/l
98-82-8 Isopropylbenzene ND 250 63 ug/l
99-87-6 p-Isopropyltoluene ND 250 63 ug/l
74-83-9 Methyl Bromide ND 250 100 ug/l
74-87-3 Methyl Chloride ND 250 100 ug/l
74-95-3 Methylene Bromide ND 250 63 ug/l
75-09-2 Methylene Chloride ND 1000 500 ug/l
1634-04-4 Methyl Tert Butyl Ether 1130 250 63 ug/l
91-20-3 Naphthalene 326 250 63 ug/l
103-65-1 n-Propylbenzene 200 250 63 ug/l J
100-42-5 Styrene ND 250 63 ug/l
75-85-4 Tert-Amyl Alcohol 11100 5000 1000 ug/l
994-05-8 Tert-Amyl Methyl Ether 481 500 100 ug/l J
75-65-0 Tert-Butyl Alcohol ND 5000 1000 ug/l
762-75-4 Tert-Butyl Formate a ND 5000 1000 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 250 63 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 250 63 ug/l
127-18-4 Tetrachloroethylene ND 250 63 ug/l
108-88-3 Toluene 17800 250 63 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 250 63 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 250 63 ug/l
71-55-6 1,1,1-Trichloroethane ND 250 63 ug/l
79-00-5 1,1,2-Trichloroethane ND 250 63 ug/l
79-01-6 Trichloroethylene ND 250 63 ug/l
75-69-4 Trichlorofluoromethane ND 250 100 ug/l
96-18-4 1,2,3-Trichloropropane ND 250 63 ug/l
95-63-6 1,2,4-Trimethylbenzene 1130 250 63 ug/l
108-67-8 1,3,5-Trimethylbenzene 316 250 63 ug/l
75-01-4 Vinyl Chloride ND 250 63 ug/l
m,p-Xylene 6020 500 63 ug/l
95-47-6 o-Xylene 2500 250 63 ug/l
1330-20-7 Xylene (total)8510 750 130 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 103%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 3 of 3
Client Sample ID:MW-16
Lab Sample ID:FC5611-2 Date Sampled:04/25/23
Matrix:AQ - Ground Water Date Received:04/27/23
Method:SM 6200B Percent Solids:n/a
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 105%70-130%
2037-26-5 Toluene-D8 98%70-130%
460-00-4 4-Bromofluorobenzene 99%70-130%
(a) Associated BS recovery outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 3
Client Sample ID:RW-1
Lab Sample ID:FC5611-3 Date Sampled:04/25/23
Matrix:AQ - Ground Water Date Received:04/27/23
Method:SM 6200B Percent Solids:n/a
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A937.D 100 05/03/23 14:24 TD n/a n/a V3A46
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 3060 50 13 ug/l
108-86-1 Bromobenzene ND 50 13 ug/l
74-97-5 Bromochloromethane ND 50 13 ug/l
75-27-4 Bromodichloromethane ND 50 13 ug/l
75-25-2 Bromoform ND 50 13 ug/l
104-51-8 n-Butylbenzene ND 50 13 ug/l
135-98-8 sec-Butylbenzene ND 50 13 ug/l
98-06-6 tert-Butylbenzene ND 50 13 ug/l
56-23-5 Carbon Tetrachloride ND 50 13 ug/l
108-90-7 Chlorobenzene ND 50 13 ug/l
75-00-3 Chloroethane ND 50 20 ug/l
67-66-3 Chloroform ND 50 13 ug/l
95-49-8 o-Chlorotoluene ND 50 13 ug/l
106-43-4 p-Chlorotoluene ND 50 13 ug/l
124-48-1 Dibromochloromethane ND 50 13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 50 25 ug/l
106-93-4 1,2-Dibromoethane ND 50 13 ug/l
75-71-8 Dichlorodifluoromethane ND 50 20 ug/l
95-50-1 1,2-Dichlorobenzene ND 50 13 ug/l
541-73-1 1,3-Dichlorobenzene ND 50 13 ug/l
106-46-7 1,4-Dichlorobenzene ND 50 13 ug/l
75-34-3 1,1-Dichloroethane ND 50 13 ug/l
107-06-2 1,2-Dichloroethane ND 50 13 ug/l
75-35-4 1,1-Dichloroethylene ND 50 13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 50 13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 50 13 ug/l
78-87-5 1,2-Dichloropropane ND 50 13 ug/l
142-28-9 1,3-Dichloropropane ND 50 13 ug/l
594-20-7 2,2-Dichloropropane ND 50 13 ug/l
563-58-6 1,1-Dichloropropene ND 50 13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 50 13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 50 13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 3
Client Sample ID:RW-1
Lab Sample ID:FC5611-3 Date Sampled:04/25/23
Matrix:AQ - Ground Water Date Received:04/27/23
Method:SM 6200B Percent Solids:n/a
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 50 13 ug/l
64-17-5 Ethyl Alcohol ND 10000 6500 ug/l
100-41-4 Ethylbenzene 708 50 13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 50 13 ug/l
87-68-3 Hexachlorobutadiene ND 50 13 ug/l
98-82-8 Isopropylbenzene 31.7 50 13 ug/l J
99-87-6 p-Isopropyltoluene ND 50 13 ug/l
74-83-9 Methyl Bromide ND 50 20 ug/l
74-87-3 Methyl Chloride ND 50 20 ug/l
74-95-3 Methylene Bromide ND 50 13 ug/l
75-09-2 Methylene Chloride ND 200 100 ug/l
1634-04-4 Methyl Tert Butyl Ether 416 50 13 ug/l
91-20-3 Naphthalene 178 50 13 ug/l
103-65-1 n-Propylbenzene 97.3 50 13 ug/l
100-42-5 Styrene ND 50 13 ug/l
75-85-4 Tert-Amyl Alcohol 3480 1000 200 ug/l
994-05-8 Tert-Amyl Methyl Ether 66.4 100 20 ug/l J
75-65-0 Tert-Butyl Alcohol ND 1000 200 ug/l
762-75-4 Tert-Butyl Formate a ND 1000 200 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 50 13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 50 13 ug/l
127-18-4 Tetrachloroethylene ND 50 13 ug/l
108-88-3 Toluene 4640 50 13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 50 13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 50 13 ug/l
71-55-6 1,1,1-Trichloroethane ND 50 13 ug/l
79-00-5 1,1,2-Trichloroethane ND 50 13 ug/l
79-01-6 Trichloroethylene ND 50 13 ug/l
75-69-4 Trichlorofluoromethane ND 50 20 ug/l
96-18-4 1,2,3-Trichloropropane ND 50 13 ug/l
95-63-6 1,2,4-Trimethylbenzene 777 50 13 ug/l
108-67-8 1,3,5-Trimethylbenzene 228 50 13 ug/l
75-01-4 Vinyl Chloride ND 50 13 ug/l
m,p-Xylene 2490 100 13 ug/l
95-47-6 o-Xylene 1050 50 13 ug/l
1330-20-7 Xylene (total)3540 150 25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 102%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 3 of 3
Client Sample ID:RW-1
Lab Sample ID:FC5611-3 Date Sampled:04/25/23
Matrix:AQ - Ground Water Date Received:04/27/23
Method:SM 6200B Percent Solids:n/a
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 104%70-130%
2037-26-5 Toluene-D8 97%70-130%
460-00-4 4-Bromofluorobenzene 99%70-130%
(a) Associated BS recovery outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 3
Client Sample ID:MW-7
Lab Sample ID:FC5611-4 Date Sampled:04/25/23
Matrix:AQ - Ground Water Date Received:04/27/23
Method:SM 6200B Percent Solids:n/a
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A918.D 100 05/02/23 15:46 TD n/a n/a V3A45
Run #2 3A938.D 250 05/03/23 14:48 TD n/a n/a V3A46
Purge Volume
Run #1 5.0 ml
Run #2 5.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 4500 50 13 ug/l
108-86-1 Bromobenzene ND 50 13 ug/l
74-97-5 Bromochloromethane ND 50 13 ug/l
75-27-4 Bromodichloromethane ND 50 13 ug/l
75-25-2 Bromoform ND 50 13 ug/l
104-51-8 n-Butylbenzene 14.7 50 13 ug/l J
135-98-8 sec-Butylbenzene ND 50 13 ug/l
98-06-6 tert-Butylbenzene ND 50 13 ug/l
56-23-5 Carbon Tetrachloride ND 50 13 ug/l
108-90-7 Chlorobenzene ND 50 13 ug/l
75-00-3 Chloroethane ND 50 20 ug/l
67-66-3 Chloroform ND 50 13 ug/l
95-49-8 o-Chlorotoluene 57.0 50 13 ug/l
106-43-4 p-Chlorotoluene ND 50 13 ug/l
124-48-1 Dibromochloromethane ND 50 13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 50 25 ug/l
106-93-4 1,2-Dibromoethane ND 50 13 ug/l
75-71-8 Dichlorodifluoromethane ND 50 20 ug/l
95-50-1 1,2-Dichlorobenzene ND 50 13 ug/l
541-73-1 1,3-Dichlorobenzene ND 50 13 ug/l
106-46-7 1,4-Dichlorobenzene ND 50 13 ug/l
75-34-3 1,1-Dichloroethane ND 50 13 ug/l
107-06-2 1,2-Dichloroethane ND 50 13 ug/l
75-35-4 1,1-Dichloroethylene ND 50 13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 50 13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 50 13 ug/l
78-87-5 1,2-Dichloropropane ND 50 13 ug/l
142-28-9 1,3-Dichloropropane ND 50 13 ug/l
594-20-7 2,2-Dichloropropane ND 50 13 ug/l
563-58-6 1,1-Dichloropropene ND 50 13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 50 13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 50 13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 3
Client Sample ID:MW-7
Lab Sample ID:FC5611-4 Date Sampled:04/25/23
Matrix:AQ - Ground Water Date Received:04/27/23
Method:SM 6200B Percent Solids:n/a
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 50 13 ug/l
64-17-5 Ethyl Alcohol a ND 10000 6500 ug/l
100-41-4 Ethylbenzene 898 50 13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 50 13 ug/l
87-68-3 Hexachlorobutadiene ND 50 13 ug/l
98-82-8 Isopropylbenzene 40.3 50 13 ug/l J
99-87-6 p-Isopropyltoluene ND 50 13 ug/l
74-83-9 Methyl Bromide ND 50 20 ug/l
74-87-3 Methyl Chloride ND 50 20 ug/l
74-95-3 Methylene Bromide ND 50 13 ug/l
75-09-2 Methylene Chloride ND 200 100 ug/l
1634-04-4 Methyl Tert Butyl Ether 514 50 13 ug/l
91-20-3 Naphthalene 579 50 13 ug/l
103-65-1 n-Propylbenzene 115 50 13 ug/l
100-42-5 Styrene ND 50 13 ug/l
75-85-4 Tert-Amyl Alcohol 10400 1000 200 ug/l
994-05-8 Tert-Amyl Methyl Ether 179 100 20 ug/l
75-65-0 Tert-Butyl Alcohol 306 1000 200 ug/l J
762-75-4 Tert-Butyl Formate a ND 1000 200 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 50 13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 50 13 ug/l
127-18-4 Tetrachloroethylene ND 50 13 ug/l
108-88-3 Toluene 7580 b 130 31 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 50 13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 50 13 ug/l
71-55-6 1,1,1-Trichloroethane ND 50 13 ug/l
79-00-5 1,1,2-Trichloroethane ND 50 13 ug/l
79-01-6 Trichloroethylene ND 50 13 ug/l
75-69-4 Trichlorofluoromethane ND 50 20 ug/l
96-18-4 1,2,3-Trichloropropane ND 50 13 ug/l
95-63-6 1,2,4-Trimethylbenzene 1800 50 13 ug/l
108-67-8 1,3,5-Trimethylbenzene 470 50 13 ug/l
75-01-4 Vinyl Chloride ND 50 13 ug/l
m,p-Xylene 5150 100 13 ug/l
95-47-6 o-Xylene 2600 50 13 ug/l
1330-20-7 Xylene (total)7750 150 25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 101%102%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 3 of 3
Client Sample ID:MW-7
Lab Sample ID:FC5611-4 Date Sampled:04/25/23
Matrix:AQ - Ground Water Date Received:04/27/23
Method:SM 6200B Percent Solids:n/a
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 102%102%70-130%
2037-26-5 Toluene-D8 98%98%70-130%
460-00-4 4-Bromofluorobenzene 99%100%70-130%
(a) Associated BS recovery outside control limits high, sample is ND.
(b) Result is from Run# 2
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
 Chain of Custody
Orlando, FL
Section 4
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FC5611: Chain of Custody
Page 1 of 2
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Job Number:FC5611 Client:GRI
Date / Time Received:4/27/2023 9:30:00 AM Delivery Method:FED EX
Project:3024
Airbill #'s:5707 9050 9877
Cooler Information
1. Custody Seals Present
2. Custody Seals Intact
4. Cooler temp verification
3. Temp criteria achieved
5. Cooler media
IR Gun
Ice (Bag)
Trip Blank Information
1. Trip Blank present / cooler
2. Trip Blank listed on COC
2. Samples preserved properly
Sample Information
1. Sample labels present on bottles
5. Sample recvd within HT
4. Condition of sample
3. Sufficient volume/containers recvd for analysis:
Intact
Comments
SM001Rev. Date 05/24/17
SGS Sample Receipt Summary
Cooler Temps (Raw Measured) °C:
Cooler Temps (Corrected) °C:
Cooler 1: (4.7);
Cooler 1: (4.6);
3. Type Of TB Received
W or S N/A
6. Dates/Times/IDs on COC match Sample Label
7. VOCs have headspace
8. Bottles received for unspecified tests
9. Compositing instructions clear
10. Voa Soil Kits/Jars received past 48hrs?
11. % Solids Jar received?
Misc. Information
25-Gram 5-GramNumber of Encores:Number of 5035 Field Kits:Number of Lab Filtered Metals:
Test Strip Lot #s:pH 0-3 230320 pH 10-12 25BDH07 Other: (Specify)pH 1.0 - 12.0 222221
Y or N N/A
Y or N
Therm ID:IR 1; Therm CF:-0.1; # of Coolers:1
Y or N N/A
12. Residual Chlorine Present?
Residual Chlorine Test Strip Lot #:
Technician:Reviewer:SHAYLAP Date:Date:4/27/2023 9:30:00 AM
FC5611: Chain of Custody
Page 2 of 2
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MS Volatiles
QC Data Summaries
Includes the following where applicable:
 Method Blank Summaries
 Blank Spike Summaries
 Matrix Spike and Duplicate Summaries
Orlando, FL
Section 5
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Method Blank Summary Page 1 of 3
Job Number:FC5611
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A45-MB 3A913.D 1 05/02/23 TD n/a n/a V3A45
The QC reported here applies to the following samples:Method: SM 6200B
FC5611-2, FC5611-4
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
64-17-5 Ethyl Alcohol ND 100 65 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
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Method Blank Summary Page 2 of 3
Job Number:FC5611
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A45-MB 3A913.D 1 05/02/23 TD n/a n/a V3A45
The QC reported here applies to the following samples:Method: SM 6200B
FC5611-2, FC5611-4
CAS No.Compound Result RL MDL Units Q
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND 10 2.0 ug/l
762-75-4 Tert-Butyl Formate ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
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Method Blank Summary Page 3 of 3
Job Number:FC5611
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A45-MB 3A913.D 1 05/02/23 TD n/a n/a V3A45
The QC reported here applies to the following samples:Method: SM 6200B
FC5611-2, FC5611-4
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 108%70-130%
17060-07-0 1,2-Dichloroethane-D4 108%70-130%
2037-26-5 Toluene-D8 97%70-130%
460-00-4 4-Bromofluorobenzene 99%70-130%
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Method Blank Summary Page 1 of 3
Job Number:FC5611
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A46-MB 3A928.D 1 05/03/23 TD n/a n/a V3A46
The QC reported here applies to the following samples:Method: SM 6200B
FC5611-1, FC5611-3, FC5611-4
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
64-17-5 Ethyl Alcohol ND 100 65 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
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Method Blank Summary Page 2 of 3
Job Number:FC5611
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A46-MB 3A928.D 1 05/03/23 TD n/a n/a V3A46
The QC reported here applies to the following samples:Method: SM 6200B
FC5611-1, FC5611-3, FC5611-4
CAS No.Compound Result RL MDL Units Q
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND 10 2.0 ug/l
762-75-4 Tert-Butyl Formate ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
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Method Blank Summary Page 3 of 3
Job Number:FC5611
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A46-MB 3A928.D 1 05/03/23 TD n/a n/a V3A46
The QC reported here applies to the following samples:Method: SM 6200B
FC5611-1, FC5611-3, FC5611-4
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 106%70-130%
17060-07-0 1,2-Dichloroethane-D4 105%70-130%
2037-26-5 Toluene-D8 97%70-130%
460-00-4 4-Bromofluorobenzene 102%70-130%
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Blank Spike Summary Page 1 of 3
Job Number:FC5611
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A45-BS 3A914.D 1 05/02/23 TD n/a n/a V3A45
The QC reported here applies to the following samples:Method: SM 6200B
FC5611-2, FC5611-4
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 10.9 109 70-130
108-86-1 Bromobenzene 10 9.8 98 70-130
74-97-5 Bromochloromethane 10 10.5 105 70-130
75-27-4 Bromodichloromethane 10 11.1 111 70-130
75-25-2 Bromoform 10 10.8 108 70-130
104-51-8 n-Butylbenzene 10 8.5 85 70-130
135-98-8 sec-Butylbenzene 10 8.5 85 70-130
98-06-6 tert-Butylbenzene 10 8.2 82 70-130
56-23-5 Carbon Tetrachloride 10 11.4 114 70-130
108-90-7 Chlorobenzene 10 9.5 95 70-130
75-00-3 Chloroethane 10 9.1 91 60-140
67-66-3 Chloroform 10 10.9 109 70-130
95-49-8 o-Chlorotoluene 10 9.4 94 70-130
106-43-4 p-Chlorotoluene 10 9.5 95 70-130
124-48-1 Dibromochloromethane 10 9.4 94 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 8.3 83 70-130
106-93-4 1,2-Dibromoethane 10 8.6 86 70-130
75-71-8 Dichlorodifluoromethane 10 12.5 125 60-140
95-50-1 1,2-Dichlorobenzene 10 9.3 93 70-130
541-73-1 1,3-Dichlorobenzene 10 9.3 93 70-130
106-46-7 1,4-Dichlorobenzene 10 9.2 92 70-130
75-34-3 1,1-Dichloroethane 10 10.4 104 70-130
107-06-2 1,2-Dichloroethane 10 10.5 105 70-130
75-35-4 1,1-Dichloroethylene 10 10.8 108 70-130
156-59-2 cis-1,2-Dichloroethylene 10 10.2 102 70-130
156-60-5 trans-1,2-Dichloroethylene 10 10.8 108 70-130
78-87-5 1,2-Dichloropropane 10 11.0 110 70-130
142-28-9 1,3-Dichloropropane 10 10.1 101 70-130
594-20-7 2,2-Dichloropropane 10 11.6 116 70-130
563-58-6 1,1-Dichloropropene 10 11.3 113 70-130
10061-01-5 cis-1,3-Dichloropropene 10 10.0 100 70-130
10061-02-6 trans-1,3-Dichloropropene 10 8.2 82 70-130
108-20-3 Di-Isopropyl Ether 10 9.3 93 70-130
64-17-5 Ethyl Alcohol 500 665 133*70-130
100-41-4 Ethylbenzene 10 9.5 95 70-130
637-92-3 Ethyl Tert Butyl Ether 10 9.4 94 70-130
* = Outside of Control Limits.
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Job Number:FC5611
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A45-BS 3A914.D 1 05/02/23 TD n/a n/a V3A45
The QC reported here applies to the following samples:Method: SM 6200B
FC5611-2, FC5611-4
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
87-68-3 Hexachlorobutadiene 10 9.7 97 70-130
98-82-8 Isopropylbenzene 10 8.3 83 70-130
99-87-6 p-Isopropyltoluene 10 7.9 79 70-130
74-83-9 Methyl Bromide 10 8.8 88 60-140
74-87-3 Methyl Chloride 10 11.0 110 60-140
74-95-3 Methylene Bromide 10 10.7 107 70-130
75-09-2 Methylene Chloride 10 9.1 91 70-130
1634-04-4 Methyl Tert Butyl Ether 10 10.8 108 70-130
91-20-3 Naphthalene 10 7.4 74 70-130
103-65-1 n-Propylbenzene 10 9.5 95 70-130
100-42-5 Styrene 10 8.1 81 70-130
75-85-4 Tert-Amyl Alcohol 100 71.7 72 70-130
994-05-8 Tert-Amyl Methyl Ether 10 8.7 87 70-130
75-65-0 Tert-Butyl Alcohol 100 113 113 70-130
762-75-4 Tert-Butyl Formate 50 104 208*70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 9.1 91 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 8.4 84 70-130
127-18-4 Tetrachloroethylene 10 9.9 99 70-130
108-88-3 Toluene 10 9.5 95 70-130
87-61-6 1,2,3-Trichlorobenzene 10 9.5 95 70-130
120-82-1 1,2,4-Trichlorobenzene 10 9.3 93 70-130
71-55-6 1,1,1-Trichloroethane 10 11.2 112 70-130
79-00-5 1,1,2-Trichloroethane 10 9.5 95 70-130
79-01-6 Trichloroethylene 10 10.7 107 70-130
75-69-4 Trichlorofluoromethane 10 10.9 109 60-140
96-18-4 1,2,3-Trichloropropane 10 9.5 95 70-130
95-63-6 1,2,4-Trimethylbenzene 10 8.5 85 70-130
108-67-8 1,3,5-Trimethylbenzene 10 8.4 84 70-130
75-01-4 Vinyl Chloride 10 10.2 102 60-140
m,p-Xylene 20 19.4 97 70-130
95-47-6 o-Xylene 10 8.4 84 70-130
1330-20-7 Xylene (total)30 27.8 93 70-130
* = Outside of Control Limits.
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Job Number:FC5611
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A45-BS 3A914.D 1 05/02/23 TD n/a n/a V3A45
The QC reported here applies to the following samples:Method: SM 6200B
FC5611-2, FC5611-4
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 107%70-130%
17060-07-0 1,2-Dichloroethane-D4 107%70-130%
2037-26-5 Toluene-D8 95%70-130%
460-00-4 4-Bromofluorobenzene 97%70-130%
* = Outside of Control Limits.
30 of 39
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Blank Spike Summary Page 1 of 3
Job Number:FC5611
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A46-BS 3A926.D 1 05/03/23 TD n/a n/a V3A46
The QC reported here applies to the following samples:Method: SM 6200B
FC5611-1, FC5611-3, FC5611-4
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 10.8 108 70-130
108-86-1 Bromobenzene 10 9.9 99 70-130
74-97-5 Bromochloromethane 10 10.6 106 70-130
75-27-4 Bromodichloromethane 10 11.2 112 70-130
75-25-2 Bromoform 10 11.5 115 70-130
104-51-8 n-Butylbenzene 10 9.0 90 70-130
135-98-8 sec-Butylbenzene 10 9.0 90 70-130
98-06-6 tert-Butylbenzene 10 8.7 87 70-130
56-23-5 Carbon Tetrachloride 10 10.9 109 70-130
108-90-7 Chlorobenzene 10 9.8 98 70-130
75-00-3 Chloroethane 10 11.0 110 60-140
67-66-3 Chloroform 10 10.6 106 70-130
95-49-8 o-Chlorotoluene 10 9.7 97 70-130
106-43-4 p-Chlorotoluene 10 9.9 99 70-130
124-48-1 Dibromochloromethane 10 9.5 95 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 8.8 88 70-130
106-93-4 1,2-Dibromoethane 10 9.0 90 70-130
75-71-8 Dichlorodifluoromethane 10 12.8 128 60-140
95-50-1 1,2-Dichlorobenzene 10 9.7 97 70-130
541-73-1 1,3-Dichlorobenzene 10 9.5 95 70-130
106-46-7 1,4-Dichlorobenzene 10 9.4 94 70-130
75-34-3 1,1-Dichloroethane 10 10.2 102 70-130
107-06-2 1,2-Dichloroethane 10 10.3 103 70-130
75-35-4 1,1-Dichloroethylene 10 10.5 105 70-130
156-59-2 cis-1,2-Dichloroethylene 10 10.6 106 70-130
156-60-5 trans-1,2-Dichloroethylene 10 10.5 105 70-130
78-87-5 1,2-Dichloropropane 10 11.2 112 70-130
142-28-9 1,3-Dichloropropane 10 10.6 106 70-130
594-20-7 2,2-Dichloropropane 10 11.2 112 70-130
563-58-6 1,1-Dichloropropene 10 11.2 112 70-130
10061-01-5 cis-1,3-Dichloropropene 10 10.4 104 70-130
10061-02-6 trans-1,3-Dichloropropene 10 8.7 87 70-130
108-20-3 Di-Isopropyl Ether 10 10 100 70-130
64-17-5 Ethyl Alcohol 500 531 106 70-130
100-41-4 Ethylbenzene 10 9.9 99 70-130
637-92-3 Ethyl Tert Butyl Ether 10 10.2 102 70-130
* = Outside of Control Limits.
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Job Number:FC5611
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A46-BS 3A926.D 1 05/03/23 TD n/a n/a V3A46
The QC reported here applies to the following samples:Method: SM 6200B
FC5611-1, FC5611-3, FC5611-4
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
87-68-3 Hexachlorobutadiene 10 10.1 101 70-130
98-82-8 Isopropylbenzene 10 8.9 89 70-130
99-87-6 p-Isopropyltoluene 10 8.5 85 70-130
74-83-9 Methyl Bromide 10 11.1 111 60-140
74-87-3 Methyl Chloride 10 11.7 117 60-140
74-95-3 Methylene Bromide 10 10.7 107 70-130
75-09-2 Methylene Chloride 10 9.0 90 70-130
1634-04-4 Methyl Tert Butyl Ether 10 11.4 114 70-130
91-20-3 Naphthalene 10 8.3 83 70-130
103-65-1 n-Propylbenzene 10 9.8 98 70-130
100-42-5 Styrene 10 8.6 86 70-130
75-85-4 Tert-Amyl Alcohol 100 81.3 81 70-130
994-05-8 Tert-Amyl Methyl Ether 10 9.8 98 70-130
75-65-0 Tert-Butyl Alcohol 100 117 117 70-130
762-75-4 Tert-Butyl Formate 50 99.9 200*70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 9.3 93 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 8.7 87 70-130
127-18-4 Tetrachloroethylene 10 9.7 97 70-130
108-88-3 Toluene 10 9.9 99 70-130
87-61-6 1,2,3-Trichlorobenzene 10 10.1 101 70-130
120-82-1 1,2,4-Trichlorobenzene 10 10.1 101 70-130
71-55-6 1,1,1-Trichloroethane 10 10.9 109 70-130
79-00-5 1,1,2-Trichloroethane 10 10 100 70-130
79-01-6 Trichloroethylene 10 10.5 105 70-130
75-69-4 Trichlorofluoromethane 10 11.6 116 60-140
96-18-4 1,2,3-Trichloropropane 10 9.9 99 70-130
95-63-6 1,2,4-Trimethylbenzene 10 9.1 91 70-130
108-67-8 1,3,5-Trimethylbenzene 10 9.0 90 70-130
75-01-4 Vinyl Chloride 10 11.3 113 60-140
m,p-Xylene 20 20.7 104 70-130
95-47-6 o-Xylene 10 9.0 90 70-130
1330-20-7 Xylene (total)30 29.8 99 70-130
* = Outside of Control Limits.
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Job Number:FC5611
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A46-BS 3A926.D 1 05/03/23 TD n/a n/a V3A46
The QC reported here applies to the following samples:Method: SM 6200B
FC5611-1, FC5611-3, FC5611-4
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 101%70-130%
17060-07-0 1,2-Dichloroethane-D4 100%70-130%
2037-26-5 Toluene-D8 96%70-130%
460-00-4 4-Bromofluorobenzene 100%70-130%
* = Outside of Control Limits.
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Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 3
Job Number:FC5611
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC5611-2MS 3A920.D 500 05/02/23 TD n/a n/a V3A45
FC5611-2MSD 3A921.D 500 05/02/23 TD n/a n/a V3A45
FC5611-2 3A916.D 500 05/02/23 TD n/a n/a V3A45
The QC reported here applies to the following samples:Method: SM 6200B
FC5611-2, FC5611-4
FC5611-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 11000 5000 16100 102 5000 16200 104 1 70-130/20
108-86-1 Bromobenzene ND 5000 4700 94 5000 4870 97 4 70-130/20
74-97-5 Bromochloromethane ND 5000 4860 97 5000 5040 101 4 70-130/20
75-27-4 Bromodichloromethane ND 5000 5150 103 5000 5410 108 5 70-130/20
75-25-2 Bromoform ND 5000 5390 108 5000 5660 113 5 70-130/20
104-51-8 n-Butylbenzene ND 5000 4610 92 5000 4670 93 1 70-130/20
135-98-8 sec-Butylbenzene ND 5000 4770 95 5000 4920 98 3 70-130/20
98-06-6 tert-Butylbenzene ND 5000 4460 89 5000 4670 93 5 70-130/20
56-23-5 Carbon Tetrachloride ND 5000 5140 103 5000 5400 108 5 70-130/20
108-90-7 Chlorobenzene ND 5000 4860 97 5000 4990 100 3 70-130/20
75-00-3 Chloroethane ND 5000 3550 71 5000 4350 87 20 60-140/20
67-66-3 Chloroform ND 5000 5020 100 5000 5210 104 4 70-130/20
95-49-8 o-Chlorotoluene ND 5000 5080 102 5000 5220 104 3 70-130/20
106-43-4 p-Chlorotoluene ND 5000 4880 98 5000 5100 102 4 70-130/20
124-48-1 Dibromochloromethane ND 5000 4250 85 5000 4370 87 3 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 5000 4350 87 5000 4580 92 5 70-130/20
106-93-4 1,2-Dibromoethane ND 5000 4390 88 5000 4550 91 4 70-130/20
75-71-8 Dichlorodifluoromethane ND 5000 3810 76 5000 4440 89 15 60-140/20
95-50-1 1,2-Dichlorobenzene ND 5000 4710 94 5000 4930 99 5 70-130/20
541-73-1 1,3-Dichlorobenzene ND 5000 4820 96 5000 5060 101 5 70-130/20
106-46-7 1,4-Dichlorobenzene ND 5000 4600 92 5000 4800 96 4 70-130/20
75-34-3 1,1-Dichloroethane ND 5000 5080 102 5000 5320 106 5 70-130/20
107-06-2 1,2-Dichloroethane ND 5000 4830 97 5000 5010 100 4 70-130/20
75-35-4 1,1-Dichloroethylene ND 5000 5150 103 5000 5390 108 5 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 5000 5110 102 5000 5150 103 1 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 5000 5020 100 5000 5250 105 4 70-130/20
78-87-5 1,2-Dichloropropane ND 5000 5180 104 5000 5350 107 3 70-130/20
142-28-9 1,3-Dichloropropane ND 5000 4860 97 5000 4990 100 3 70-130/20
594-20-7 2,2-Dichloropropane ND 5000 5210 104 5000 5340 107 2 70-130/20
563-58-6 1,1-Dichloropropene ND 5000 5460 109 5000 5660 113 4 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 5000 4890 98 5000 4830 97 1 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 5000 4470 89 5000 4540 91 2 70-130/20
108-20-3 Di-Isopropyl Ether ND 5000 4870 97 5000 5050 101 4 70-130/20
64-17-5 Ethyl Alcohol ND 250000 305000 122 250000 302000 121 1 70-130/20
100-41-4 Ethylbenzene 1720 5000 8350 133*5000 7330 112 13 70-130/20
637-92-3 Ethyl Tert Butyl Ether ND 5000 4770 95 5000 4960 99 4 70-130/20
* = Outside of Control Limits.
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Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 3
Job Number:FC5611
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC5611-2MS 3A920.D 500 05/02/23 TD n/a n/a V3A45
FC5611-2MSD 3A921.D 500 05/02/23 TD n/a n/a V3A45
FC5611-2 3A916.D 500 05/02/23 TD n/a n/a V3A45
The QC reported here applies to the following samples:Method: SM 6200B
FC5611-2, FC5611-4
FC5611-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
87-68-3 Hexachlorobutadiene ND 5000 4800 96 5000 5040 101 5 70-130/20
98-82-8 Isopropylbenzene ND 5000 4820 96 5000 4850 97 1 70-130/20
99-87-6 p-Isopropyltoluene ND 5000 4430 89 5000 4630 93 4 70-130/20
74-83-9 Methyl Bromide ND 5000 3870 77 5000 4540 91 16 60-140/20
74-87-3 Methyl Chloride ND 5000 4380 88 5000 4290 86 2 60-140/20
74-95-3 Methylene Bromide ND 5000 4870 97 5000 5050 101 4 70-130/20
75-09-2 Methylene Chloride ND 5000 4030 81 5000 4190 84 4 70-130/20
1634-04-4 Methyl Tert Butyl Ether 1130 5000 6760 113 5000 6880 115 2 70-130/20
91-20-3 Naphthalene 326 5000 5830 110 5000 5180 97 12 70-130/20
103-65-1 n-Propylbenzene 200 J 5000 5690 110 5000 5560 107 2 70-130/20
100-42-5 Styrene ND 5000 4360 87 5000 4420 88 1 70-130/20
75-85-4 Tert-Amyl Alcohol 11100 50000 69200 116 50000 70400 119 2 70-130/20
994-05-8 Tert-Amyl Methyl Ether 481 J 5000 5400 98 5000 5450 99 1 70-130/20
75-65-0 Tert-Butyl Alcohol ND 50000 71900 144*50000 51800 104 32*70-130/20
762-75-4 Tert-Butyl Formate ND 25000 45400 182*25000 2320 9*181*70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 5000 4480 90 5000 4560 91 2 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 5000 4530 91 5000 4730 95 4 70-130/20
127-18-4 Tetrachloroethylene ND 5000 4980 100 5000 5080 102 2 70-130/20
108-88-3 Toluene 17800 5000 24700 138* a 5000 22700 98 8 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 5000 4730 95 5000 4980 100 5 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 5000 4850 97 5000 5050 101 4 70-130/20
71-55-6 1,1,1-Trichloroethane ND 5000 5210 104 5000 5520 110 6 70-130/20
79-00-5 1,1,2-Trichloroethane ND 5000 4920 98 5000 5110 102 4 70-130/20
79-01-6 Trichloroethylene ND 5000 5140 103 5000 5330 107 4 70-130/20
75-69-4 Trichlorofluoromethane ND 5000 4500 90 5000 5230 105 15 60-140/20
96-18-4 1,2,3-Trichloropropane ND 5000 4920 98 5000 5150 103 5 70-130/20
95-63-6 1,2,4-Trimethylbenzene 1130 5000 10100 179*5000 7370 125 31*70-130/20
108-67-8 1,3,5-Trimethylbenzene 316 5000 6000 114 5000 5380 101 11 70-130/20
75-01-4 Vinyl Chloride ND 5000 3960 79 5000 4770 95 19 60-140/20
m,p-Xylene 6020 10000 24800 188*10000 19000 130 26*70-130/20
95-47-6 o-Xylene 2500 5000 10700 164*5000 8210 114 26*70-130/20
1330-20-7 Xylene (total)8510 15000 35500 180*15000 27200 125 26*70-130/20
* = Outside of Control Limits.
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Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number:FC5611
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC5611-2MS 3A920.D 500 05/02/23 TD n/a n/a V3A45
FC5611-2MSD 3A921.D 500 05/02/23 TD n/a n/a V3A45
FC5611-2 3A916.D 500 05/02/23 TD n/a n/a V3A45
The QC reported here applies to the following samples:Method: SM 6200B
FC5611-2, FC5611-4
CAS No.Surrogate Recoveries MS MSD FC5611-2 Limits
1868-53-7 Dibromofluoromethane 98%99%103%70-130%
17060-07-0 1,2-Dichloroethane-D4 99%99%105%70-130%
2037-26-5 Toluene-D8 97%96%98%70-130%
460-00-4 4-Bromofluorobenzene 102%102%99%70-130%
(a) Outside control limits due to high level in sample relative to spike amount.
* = Outside of Control Limits.
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Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 3
Job Number:FC5611
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC5633-9MS 3A941.D 200 05/03/23 TD n/a n/a V3A46
FC5633-9MSD 3A942.D 200 05/03/23 TD n/a n/a V3A46
FC5633-9 3A932.D 100 05/03/23 TD n/a n/a V3A46
FC5633-9 3A940.D 200 05/03/23 TD n/a n/a V3A46
The QC reported here applies to the following samples:Method: SM 6200B
FC5611-1, FC5611-3, FC5611-4
FC5633-9 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 514 2000 2850 117 2000 2840 116 0 70-130/20
108-86-1 Bromobenzene ND 2000 1980 99 2000 2050 103 3 70-130/20
74-97-5 Bromochloromethane ND 2000 2110 106 2000 2090 105 1 70-130/20
75-27-4 Bromodichloromethane ND 2000 2190 110 2000 2210 111 1 70-130/20
75-25-2 Bromoform ND 2000 2140 107 2000 2200 110 3 70-130/20
104-51-8 n-Butylbenzene ND 2000 1900 95 2000 1930 97 2 70-130/20
135-98-8 sec-Butylbenzene ND 2000 1870 94 2000 1900 95 2 70-130/20
98-06-6 tert-Butylbenzene ND 2000 1830 92 2000 1860 93 2 70-130/20
56-23-5 Carbon Tetrachloride ND 2000 2230 112 2000 2280 114 2 70-130/20
108-90-7 Chlorobenzene ND 2000 1990 100 2000 2010 101 1 70-130/20
75-00-3 Chloroethane ND 2000 1830 92 2000 2060 103 12 60-140/20
67-66-3 Chloroform ND 2000 2210 111 2000 2210 111 0 70-130/20
95-49-8 o-Chlorotoluene ND 2000 2030 102 2000 2080 104 2 70-130/20
106-43-4 p-Chlorotoluene ND 2000 2020 101 2000 2030 102 0 70-130/20
124-48-1 Dibromochloromethane ND 2000 1820 91 2000 1850 93 2 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 2000 1630 82 2000 1720 86 5 70-130/20
106-93-4 1,2-Dibromoethane ND 2000 1820 91 2000 1830 92 1 70-130/20
75-71-8 Dichlorodifluoromethane ND 2000 2440 122 2000 2710 136 10 60-140/20
95-50-1 1,2-Dichlorobenzene ND 2000 1940 97 2000 1970 99 2 70-130/20
541-73-1 1,3-Dichlorobenzene ND 2000 1930 97 2000 1960 98 2 70-130/20
106-46-7 1,4-Dichlorobenzene ND 2000 1880 94 2000 1910 96 2 70-130/20
75-34-3 1,1-Dichloroethane ND 2000 2150 108 2000 2170 109 1 70-130/20
107-06-2 1,2-Dichloroethane ND 2000 2100 105 2000 2120 106 1 70-130/20
75-35-4 1,1-Dichloroethylene ND 2000 2260 113 2000 2280 114 1 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 2000 2140 107 2000 2200 110 3 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 2000 2240 112 2000 2220 111 1 70-130/20
78-87-5 1,2-Dichloropropane ND 2000 2330 117 2000 2330 117 0 70-130/20
142-28-9 1,3-Dichloropropane ND 2000 2140 107 2000 2160 108 1 70-130/20
594-20-7 2,2-Dichloropropane ND 2000 2420 121 2000 2410 121 0 70-130/20
563-58-6 1,1-Dichloropropene ND 2000 2430 122 2000 2440 122 0 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 2000 2080 104 2000 2140 107 3 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 2000 1750 88 2000 1730 87 1 70-130/20
108-20-3 Di-Isopropyl Ether ND 2000 2090 105 2000 2120 106 1 70-130/20
64-17-5 Ethyl Alcohol ND 100000 151000 151*100000 130000 130 15 70-130/20
100-41-4 Ethylbenzene 868 2000 3010 107 2000 3030 108 1 70-130/20
637-92-3 Ethyl Tert Butyl Ether ND 2000 2090 105 2000 2130 107 2 70-130/20
* = Outside of Control Limits.
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Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 3
Job Number:FC5611
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC5633-9MS 3A941.D 200 05/03/23 TD n/a n/a V3A46
FC5633-9MSD 3A942.D 200 05/03/23 TD n/a n/a V3A46
FC5633-9 3A932.D 100 05/03/23 TD n/a n/a V3A46
FC5633-9 3A940.D 200 05/03/23 TD n/a n/a V3A46
The QC reported here applies to the following samples:Method: SM 6200B
FC5611-1, FC5611-3, FC5611-4
FC5633-9 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
87-68-3 Hexachlorobutadiene ND 2000 2070 104 2000 2050 103 1 70-130/20
98-82-8 Isopropylbenzene 44.0 J 2000 1950 95 2000 1950 95 0 70-130/20
99-87-6 p-Isopropyltoluene ND 2000 1790 90 2000 1820 91 2 70-130/20
74-83-9 Methyl Bromide 39.8 2000 1690 83 2000 1970 97 15 60-140/20
74-87-3 Methyl Chloride ND 2000 2130 107 2000 2410 121 12 60-140/20
74-95-3 Methylene Bromide ND 2000 2160 108 2000 2180 109 1 70-130/20
75-09-2 Methylene Chloride ND 2000 1890 95 2000 1900 95 1 70-130/20
1634-04-4 Methyl Tert Butyl Ether 31.0 J 2000 2390 118 2000 2410 119 1 70-130/20
91-20-3 Naphthalene 99.3 2000 1930 92 2000 1940 92 1 70-130/20
103-65-1 n-Propylbenzene 110 2000 2170 103 2000 2210 105 2 70-130/20
100-42-5 Styrene ND 2000 1810 91 2000 1830 92 1 70-130/20
75-85-4 Tert-Amyl Alcohol ND 20000 16900 85 20000 18500 93 9 70-130/20
994-05-8 Tert-Amyl Methyl Ether ND 2000 1990 100 2000 2030 102 2 70-130/20
75-65-0 Tert-Butyl Alcohol ND 20000 24400 122 20000 26800 134*9 70-130/20
762-75-4 Tert-Butyl Formate ND 10000 22700 227*10000 23900 239*5 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 2000 1830 92 2000 1880 94 3 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 2000 1720 86 2000 1760 88 2 70-130/20
127-18-4 Tetrachloroethylene ND 2000 2040 102 2000 2050 103 0 70-130/20
108-88-3 Toluene 5380 a 2000 7370 110 2000 7300 107 1 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 2000 2030 102 2000 2040 102 0 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 2000 2080 104 2000 2080 104 0 70-130/20
71-55-6 1,1,1-Trichloroethane ND 2000 2270 114 2000 2320 116 2 70-130/20
79-00-5 1,1,2-Trichloroethane ND 2000 2020 101 2000 2020 101 0 70-130/20
79-01-6 Trichloroethylene ND 2000 2220 111 2000 2240 112 1 70-130/20
75-69-4 Trichlorofluoromethane ND 2000 2070 104 2000 2330 117 12 60-140/20
96-18-4 1,2,3-Trichloropropane ND 2000 1990 100 2000 2080 104 4 70-130/20
95-63-6 1,2,4-Trimethylbenzene 911 2000 2900 99 2000 2950 102 2 70-130/20
108-67-8 1,3,5-Trimethylbenzene 241 2000 2150 95 2000 2200 98 2 70-130/20
75-01-4 Vinyl Chloride ND 2000 2040 102 2000 2310 116 12 60-140/20
m,p-Xylene 3910 4000 8340 111 4000 8370 112 0 70-130/20
95-47-6 o-Xylene 1500 2000 3510 101 2000 3490 100 1 70-130/20
1330-20-7 Xylene (total)5410 6000 11800 107 6000 11900 108 1 70-130/20
* = Outside of Control Limits.
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Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number:FC5611
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Kwik Pic 4; 564 N Patterson St, Maxton, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC5633-9MS 3A941.D 200 05/03/23 TD n/a n/a V3A46
FC5633-9MSD 3A942.D 200 05/03/23 TD n/a n/a V3A46
FC5633-9 3A932.D 100 05/03/23 TD n/a n/a V3A46
FC5633-9 3A940.D 200 05/03/23 TD n/a n/a V3A46
The QC reported here applies to the following samples:Method: SM 6200B
FC5611-1, FC5611-3, FC5611-4
CAS No.Surrogate Recoveries MS MSD FC5633-9 FC5633-9 Limits
1868-53-7 Dibromofluoromethane 100%100%105%102%70-130%
17060-07-0 1,2-Dichloroethane-D4 100%99%105%104%70-130%
2037-26-5 Toluene-D8 96%96%96%96%70-130%
460-00-4 4-Bromofluorobenzene 101%100%100%101%70-130%
(a) Result is from Run #2.
* = Outside of Control Limits.
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APPENDIX C
Contaminant Mass Calculations
Area ID Well ID Area
(ft²)
Average Well
Depth
(ft.)
Average
Depth to
Water
(ft.)
Water Column
Height
(ft)
Volume
(ft³)
Volume
(L)
Effective
Porosity
Effective
Volume
(L)
MW-7 1,063.4
MW-16/TMW-1 11,518.1
Area Date Well Benzene
(μ/L)
Toluene
(μ/L)
Ethylbenzene
(μ/L)
Xylenes
(μ/L)
MTBE
(μ/L)
Naphthalene
(μ/L)
Total
(μ/L)
DTW
(ft.)
Average Water
Column Height
(ft.)
Total Average
Mass
(g)
Percent Red.To Date Red.
MW-7 9160.00 17700.00 3090.00 15700.00 623.00 779.00 47052.00 3.10
MW-16/TMW-1 35400.00 53100.00 4720.00 25400.00 3470.00 758.00 122848.00 ---
Avg.22280.00 35400.00 3905.00 20550.00 2046.50 768.50 84950.00 3.10
MW-7 6530.00 9120.00 2110.00 10000.00 0.00 562.00 28322.00 3.27
MW-16/TMW-1 18900.00 36800.00 3280.00 16500.00 4190.00 608.00 80278.00 3.70
Avg.12715.00 22960.00 2695.00 13250.00 2095.00 585.00 54300.00 3.49
MW-7 8710.00 23300.00 2740.00 13700.00 0.00 547.00 48997.00 9.70
MW-16/TMW-1 13.60 23.20 2.40 11.10 1.40 0.44 52.14 7.34
Avg.4361.80 11661.60 1371.20 6855.55 0.70 273.72 24524.57 8.52
MW-7 10200.00 31800.00 3220.00 19600.00 729.00 1080.00 66629.00 11.31
MW-16/TMW-1 11200.00 25200.00 3280.00 16200.00 838.00 977.00 57695.00 8.08
Avg.10700.00 28500.00 3250.00 17900.00 783.50 1028.50 62162.00 9.70
MW-7 4500.00 7580.00 898.00 7750.00 514.00 579.00 21821.00 4.60
MW-16/TMW-1 11000.00 17800.00 1720.00 3540.00 1130.00 326.00 35516.00 4.53
Avg.7750.00 12690.00 1309.00 5645.00 822.00 452.50 28668.50 4.57
Date
Average Water
Column Height
(ft.)
07/30/20 3.10
05/04/21 3.49
03/17/22 8.52
12/05/22 9.70
04/25/23 4.57
Notes:
• FP: Free Product
• Area of the contaminant plume is calculated from Figure 6
• Height of the water column is calculated by subtracting the average depth to water from the average well depth of the referenced monitoring wells
• Volume of the contaminant plume is calculated by multiplying the area of the plume by the average height of the water column during each sampling event
• Effective porosity is assumed based on the sub-surface soil profile obtained from well construction records and soil boring logs
• Total mass was calculated by multiplying the total contaminant concentrations for the sampling event with effective volume
• Contaminant mass cannot be calculated in wells containing FP; therefore, the total contaminant mass is based on the known concentrations in the area for each sampling event.
• When areas couldn’t be sampled, the last known concentrations were used in the calculations.
67.4%
2,284 -107.5%67%
Area 1
12/05/22 5.31 2,283.89 -107.5%
38.1%
38%38%4,330
------
84.3%74.6%03/17/22
07/30/20
1,100.63
7,001.24
6.48
11.90
05/04/21 11.52 4,330.40 38.1%
APPENDIX C
CONTAMINANT MASS CALCULATIONS
NIC'S PIC KWIK #4 (INCIDENT NO. 29522/42236)
Baseline Event
0.231 82,416358,33012,65411.903.115
2,071.87 9.3%70.4%
1,101
Percent Reduction Compared
to Previous Event
---
74.6%84%
Total Contaminant Mass
(g)
7,001
Percent Reduction To Date
---
2,072 9.3%70%
04/25/23 10.44