FA-3338_29463_CA_RPTS_20230725_Additional Risk Assessment

100 East Ruffin Street, Mebane, North Carolina 27302
Telephone [phone] ·Facsimile [phone]
www.terraquestpc.com

ADDITIONAL RISK ASSESSMENT REPORT

(May 2023 Assessment)

J.D.’s COUNTRY STORE
4549 WILSON’S MILLS ROAD
SMITHFIELD, JOHNSTON COUNTY, NC 27577

Latitude: 35.5820 N Longitude: -78.3578 W

Facility ID No. 0-013454
NCDWM-UST Incident No. 29463
NCDWM-UST Risk Ranking: INTERMEDIATE I-175-A

Release Information:

Date Release Discovered: July 9, 2007
Estimated Release Quantity: Unknown
Release Cause/Source: Commercial Underground Storage Tank System
UST Capacities: 1, 12,000-gallon Gasoline, 1, 8,000-gallon Gasoline, 1, 5,000-gallon Diesel, and
1, 6,000-gallon Gasoline/4,000-gallon Diesel (Compartmentalized)

Responsible Party/Property Owner:
Anthony W. Southerland
J.D.’s Country Store
Post Office Box 102
Wilson’s Mills, NC 27593

Terraquest Project No. 01205

July 25, 2023

Additional Risk Assessment Report (5/2023 assessment) Anthony W. Southerland
By: Terraquest Environmental Consultants, P.C. J.D.’s Country Store
Report Prepared: July 25, 2023 i 4549 Wilson’s Mills Road, Smithfield, NC
CERTIFICATION FOR THE SUBMITTAL
OF AN ENVIRONMENTAL / GEOLOGICAL ASSESSMENT

Attached is the Additional Risk Assessment Report for:

Responsible Party: J.D.’s Country Store, Inc.
Address: 1105 Southerland Rd
City: Clayton State: NC Zip Code: 27527

Site Name: J.D.’s Country Store
Address: 4549 Wilson Mills Rd
City: Smithfield State: NC Zip Code: 27577

I, Michael J. Brown, a Licensed Geologist in the State of North Carolina for TERRAQUEST
ENVIRONMENTAL CONSULTANTS, P.C. do hereby certify that I am familiar with and have
reviewed all material including figures within this report and that to the best of my knowledge
the data, site assessment, figures, and other associated materials are correct and accurate. All
work was performed under my direct supervision. My seal and signature are affixed below.

Terraquest Environmental Consultants, P.C. is licensed to practice geology and engineering in
North Carolina. The geology certification number of the corporation is C-291. The engineering
certification number of the corporation is C-4634. Engineering is practiced out of the Cary, NC
office.

TERRAQUEST ENVIRONMENTAL CONSULTANTS, P.C.

Ryan D. Kerins Michael J. Brown, P.G.
Project Manager President

Additional Risk Assessment Report (5/2023 assessment) Anthony W. Southerland
By: Terraquest Environmental Consultants, P.C. J.D.’s Country Store
Report Prepared: July 25, 2023 ii 4549 Wilson’s Mills Road, Smithfield, NC
TABLE OF CONTENTS
ENVIRONMENTAL ACRONYMS ..................................................................................................................... iv
EXECUTIVE SUMMARY .................................................................................................................................. v
1.0 INTRODUCTION ................................................................................................................................ 1
2.0 SITE HISTORY AND SOURCE CHARACTERIZATION ............................................................................ 1
3.0 RECEPTOR INFORMATION ............................................................................................................... 2
4.0 REGIONAL GEOLOGY AND HYDROGEOLOGY ................................................................................... 4
5.0 SITE GEOLOGY AND HYDROGEOLOGY ............................................................................................. 5
6.0 SOIL ASSESSMENT ............................................................................................................................ 9
6.1 UST Closure and Excavation ........................................................................................................ 9
6.2 Extent of Capillary Zone Impact ................................................................................................ 10
7.0 Contaminant Mass Assessment ..................................................................................................... 10
8.0 GROUNDWATER QUALTIY .............................................................................................................. 14
8.2 Groundwater Flow Data ............................................................................................................ 14
8.2 New Well Installation ................................................................................................................ 14
8.3 Groundwater Sampling .............................................................................................................. 15
9.0 CONCLUSIONS / RECOMMENDATIONS.......................................................................................... 16
10.0 LIMITATIONS .................................................................................................................................. 16
REFERENCES .................................................................................................................................................. 1

TABLES:

1. Site History (UST/AST System Information)
2. Surrounding Property Owners
3. Water Supply Well Information
4. Summary of Soil Sampling Results – Excavation 2007
5. Contaminant Mass Assessment
6. Monitoring Well Construction Information
7. Summary of Groundwater Sampling Results

FIGURES:

1. Site Location Map
2. Site Vicinity Map
3. Site Layout Map
4. Limit of Excavation Samples
5. Contaminant Mass Assessment Boring Locations
6. Potentiometric Surface Map (5/17/23)
7. Groundwater Analytical Results (5/17/23)
8. Benzene Isoconcentration Map (5/17/23)
9. Toluene Isoconcentration Map (5/17/23)
10. Ethylbenzene Isoconcentration Map (5/17/23)
11. Xylenes Isoconcentration Map (5/17/23)

Additional Risk Assessment Report (5/2023 assessment) Anthony W. Southerland
By: Terraquest Environmental Consultants, P.C. J.D.’s Country Store
Report Prepared: July 25, 2023 iii 4549 Wilson’s Mills Road, Smithfield, NC
TABLE OF CONTENTS (CONTINUED)

APPENDICES:

A. Technical Methods / Standard Procedures
B. Chronological Site History
C. Soil Boring Logs and Well Construction Record
D. Historical Groundwater Data
E. Analytical Reports
ENVIRONMENTAL ACRONYMS

Monitoring Report (June 2022 sampling event) Anthony W. Southerland
By: Terraquest Environmental Consultants, P.C. J.D.’s Country Store
Report Prepared: July 25, 2023 iv 4549 Wilson’s Mills Road, Smithfield, NC
2L Standard Groundwater Standards Title 15A NCAC 2L
0.0202(g)
2B Standard Surface Water Standards Title 15A NCAC 2B
AFVR Aggressive Fluid-Vapor Recovery
AST Aboveground Storage Tank
BGL Below Ground Level
BTEX Benzene, toluene, ethylbenzene, xylenes
C&D Construction and Demolition
CAP Corrective Action Plan
CAPR Corrective Action Performance Report
CADR Corrective Action Design Report
CSA Comprehensive Site Assessment
DPE Dual-phase Extraction
EPA Environmental Protection Agency
ePATA Electronic Pre-Approval Task Authorization
EPH Extractable Petroleum Hydrocarbons
ESA Environmental Site Assessment
GCL Gross Contamination Level
LEL Lower Explosive Limit
LSA Limited Site Assessment
IPE di-Isopropyl Ether
ISCO In-situ Chemical Oxidation
MADEP Massachusetts Department of Environmental
Protection
MDL Method Detection Limit
MNA Monitored Natural Attenuation
MMPE Mobile Multi Phase Extraction
MSCC Maximum Soil Contaminant
Concentration
MSL Mean Sea Level
MSW Municipal Solid Waste
MTBE Methyl tertiary-Butyl Ether
NC North Carolina
NCAC NC Administrative Code
NCDENR NC Department of Environment and Natural
Resources
NCDEQ NC Department of Environmental
Quality
NCDOT NC Department of Transportation
NCDWM-SW NC Division of Waste Management’s Solid
Waste Section
NCDWM-UST NC Division of Waste Management’s UST
Section
NCDWQ NC Division of Water Quality
NFA No Further Action
NORR Notice of Regulatory Requirements
NORP Notice of Residual Petroleum
NOV Notice of Violation
NPDES National Pollutant Discharge
Elimination System
OVM Organic Vapor Meter
PID Photoionization Detector
PLC Programmable Logic Controller
POE Point of Entry (water treatment system)
POTW Publicly Owned Treatment Works
RBCA Risk Based Corrective Action
RDL Reporting Detection Limit
RP Responsible Party
SCFM Standard Cubic Feet per Minute
SVE Soil Vapor Extraction
STF Leaking UST State Trust Fund
STG Soil to Groundwater
TA Task Authorization
TCC Target Cleanup Concentrations
Terraquest Terraquest Environmental Consultants,
P.C.
TPH Total Petroleum Hydrocarbon
UST Underground Storage Tank
VOA Volatile Organic Analysis
VOC Volatile Organic Compound
VPH Volatile Petroleum Hydrocarbons
XP Explosion Proof

Monitoring Report (June 2022 sampling event) Anthony W. Southerland
By: Terraquest Environmental Consultants, P.C. J.D.’s Country Store
Report Prepared: July 25, 2023 v 4549 Wilson’s Mills Road, NC
EXECUTIVE SUMMARY

On behalf of Anthony Southerland of J.D.’s Country store, Terraquest Environmental Consultants, P.C.
is reporting the results of environmental assessment efforts associated with the UST petroleum
release at the J.D.’s Country Store facility. Recent groundwater analytical results have reported GCL
and 2L Standard violations similar to those from 2015 and 2022. MNA alone has not worked to reduce
concentrations to a level where the incident can be closed. Terraquest recommends investigating
corrective actions to move this release incident toward closure.

Comprehensive Site Assessment Report Anthony W. Southerland
Prepared by Terraquest Environmental Consultants, P.C. J.D.’s Country Store
Report Prepared: July 25, 2023 1 Wilson’s Mills, NC
1.0 INTRODUCTION

On behalf of the responsible party, Anthony W. Southerland/J.D.’s Country Store, Terraquest
Environmental Consultants, P.C. has prepared this Additional Risk Assessment Report for the
J.D.’s Country Store facility located in Smithfield, Johnston County, North Carolina. This report
relates to the previous release of petroleum from the onsite underground storage tank system
and details the May 2023 soil and groundwater assessment activities. Activities detailed herein
were pre-approved on ePATA 29463-006.

The site location and surrounding cultural features are depicted in Figure 1. The site vicinity map
is depicted in Figure 2. The site layout and monitoring well network are depicted in Figure 3.
Appendix A provides a summary of the technical methods and standard procedures generally
used by Terraquest personnel.

2.0 SITE HISTORY AND SOURCE CHARACTERIZATION

A chronological summary of site events is provided in Appendix B. A summary is provided here.

According to information supplied by Mr. Southerland, Superior Industrial Maintenance
Company performed an internal inspection of the subject UST (T1/T1B) on November 28, 2006.
The subject UST consisted of a 6,000-gallon and a 3,000-gallon gasoline compartment. The
inspection of the first compartment by Superior revealed a failure and further inspection was not
conducted. Prior to the inspection, P&W Oil Services, Inc. removed 940 gallons of residual fuel
and water from the tank. November 28, 2006 was the last date of use for the UST.

Following the failed inspection, Mr. Southerland requested the removal of the subject UST. On
July 6, 2007, Terraquest personnel submitted a UST-3 Notice of Intent form to the NCDWM-UST.
Terraquest personnel supervised the removal of the subject UST on July 9, 2007. Mr. Bob Heath
of the NCDWM-UST Fayetteville Regional Office was also onsite during the removal of the subject

Comprehensive Site Assessment Report Anthony W. Southerland
Prepared by Terraquest Environmental Consultants, P.C. J.D.’s Country Store
Report Prepared: July 25, 2023 2 Wilson’s Mills, NC
UST. Per Mr. Heath, soil samples were not collected beneath the UST or along the product lines
or at the dispensers. Soil exhibiting characteristics of contamination was detected beneath the
subject UST. Based upon the presence of contamination soil, Terraquest personnel supervised
the excavation of 518.66 tons of contaminated soil. The soil was removed and transported offsite
for disposal at a permitted facility.

Analytical results for soil samples collected at the limits of the excavation revealed the presence
of petroleum-type contaminants at concentration in excess of the STG-MSCCs. Based upon these
results, Terraquest personnel submitted a 24-Hour Release and UST Reporting form on August 7,
2007.

On April 14, 2008, the NCDWM-UST issued a Notice of Regulatory Requirements (NORR)
indicating that in accordance with NCGS 143-215.94E(e4) the release did not meet the
requirements for further assessment or corrective action and work at the site was halted. On
April 1, 2014, the NCDWM-UST issued an NORR indicating that the subject incident had been
determined by the Department to be of sufficient high priority to allow funding from the State
Trust Fund Program and directed to proceed with assessment or remediation activities. A July
21, 2022 NORR acknowledged the July 2022 Monitoring Report and requested additional
assessment. This report details that assessment.

Following the removal of the subject UST and the subsequent excavation, a new UST (T5/T5B)
was installed in the former UST basin. Information regarding former and current USTs and ASTs
present at the site is contained in Table 1.

3.0 RECEPTOR INFORMATION

As part of the LSA, Terraquest personnel performed a reconnaissance of properties within a
1,500-foot radius of the source area, in order to determine the risk ranking of the site. The

Comprehensive Site Assessment Report Anthony W. Southerland
Prepared by Terraquest Environmental Consultants, P.C. J.D.’s Country Store
Report Prepared: July 25, 2023 3 Wilson’s Mills, NC
reconnaissance effort consisted of obtaining tax department and local zoning information on
properties and conducting door-to-door visits of certain properties within 1,500-feet of the
source area, in addition to collecting other pertinent information from the appropriate local and
state officials.

Terraquest personnel inspected all properties within 1,500 feet of the site and attempted to
contact all of the property owners within 1,000 feet in person. Property owners were
questioned, if available, as to the source of their water and if any water supply wells were located
on their property. If owners/occupants were not home, a survey form was left at their residence
or forwarded to the property owners through the mail. In all cases, Terraquest also conducted a
visual survey of the property. A less detailed reconnaissance effort was conducted for all
properties located 1,000 to 1,500 feet away from the site. Through the reconnaissance efforts,
a total of twenty (20) potable wells were identified within a 1,500-foot radius of the site. Of the
identified potable wells, two wells within 1,000 feet of the release area were identified as being
active. Potable well PW20 was identified as a secondary source well whereas potable well PW14
was identified as a sole-source potable well. PW14 was the only potable well within 1,000 feet
of the release area to be identified as sole-source (note that PW14 is currently identified as a
secondary source well). Based upon information acquired during the LSA, the site was ranked a
High Risk (H148D). Surrounding property owners/occupants are detailed in Table 2. Water
supply well information is provided in Table 3.

As part of the reconnaissance effort, Terraquest also searched for any surface water bodies
within a 500-foot radius of the site. A small creek is located adjacent to the site along the western
property boundary. This pond is not identified by NCDEQ on their online NC Surface Water
Classifications map. There is also a pond located approximately 500 feet southwest of the site.

In 2009, it was discovered that the house that potable well PW14 had served had burned down
and that there were no immediate plans to rebuild. Based upon this information the NCDWM-

Comprehensive Site Assessment Report Anthony W. Southerland
Prepared by Terraquest Environmental Consultants, P.C. J.D.’s Country Store
Report Prepared: July 25, 2023 4 Wilson’s Mills, NC
UST issued an NORR dated September 21, 2009 indicating that the release incident had been
reclassified by the Department as intermediate (I140D). During later assessment it was
discovered that a barn had been constructed on the property and the well was being used to
supply water to horses that were on the property. This classified the well as secondary source.

In an NORR dated August 12, 2014, the NCDWM-UST again reclassified the site as High Risk
(H132D) and requested the completion of a Comprehensive Site Assessment Report. That report
was completed and is on file with the NCDWM-UST.

In an NORR dated May 25, 2022, the NCDWM-UST ranked the site and Intermediate I-175-A and
requested the completion of a sampling event and a recon update. Those activities were detailed
in the July 2022 report.

A sensitive receptor survey update was conducted by Terraquest on June 30, 2022. Terraquest
spoke with property owners and surveyed properties for water use. Results of this update have
been incorporated into Tables 2 and 3. The noted changes include the connection to city water
at the PW3, PW4, PW6, and PW7 properties. These properties are beyond 1,000 feet from the
release incident.

Land usage in the vicinity of the site is chiefly residential, small business, and office and
institution. The subject property is zoned Community Business District. Wilson’s Mills Elementary
is located to the north-northwest across Wilson’s Mills Road. The closest residence is located
approximately 350 feet north of the site.

4.0 REGIONAL GEOLOGY AND HYDROGEOLOGY

According to the Geologic Map of North Carolina, the site lies in the Piedmont physiographic
province (Brown, et al., 1985). On a regional scale, the Piedmont is characterized by land with

Comprehensive Site Assessment Report Anthony W. Southerland
Prepared by Terraquest Environmental Consultants, P.C. J.D.’s Country Store
Report Prepared: July 25, 2023 5 Wilson’s Mills, NC
moderate relief and some areas of low relief hills and valleys. Groundwater in the immediate
area is directed toward the small creek that runs along the western property boundary and
eventually to Poplar Creek to the south.

5.0 SITE GEOLOGY AND HYDROGEOLOGY

The site has been mapped as located within the Eastern Slate Belt. In this area, most of the
metamorphic rocks of the Eastern Slate Belt are covered by Tertiary terrace deposits. The site
geology is mapped as Yorktown and Duplin Formations (undivided). These Tertiary deposits
consist of fossiliferous to shelly clays with varying amounts of fine grained to coarse grained sand
(Brown, et al., 1985).

ENCOUNTERED LITHOLOGY

The following lithologies were encountered at the site during the installation of the monitoring
well network:

0' – 8' below ground level (BGL):
Sand (SC)
Mostly dense, gray/black/yellow fine grained sand with few to trace clay

8’ – 35’ BGL:
Fat Clay (CH)
Mostly soft, yellowish orange/brown to grayish blue clay with trace fine grain sand

Comprehensive Site Assessment Report Anthony W. Southerland
Prepared by Terraquest Environmental Consultants, P.C. J.D.’s Country Store
Report Prepared: July 25, 2023 6 Wilson’s Mills, NC
Geologic cross sections of the site follow:

Comprehensive Site Assessment Report Anthony W. Southerland
Prepared by Terraquest Environmental Consultants, P.C. J.D.’s Country Store
Report Prepared: July 25, 2023 7 Wilson’s Mills, NC
LOCAL TOPOGRAPHY
The local topography is characterized by relatively flat topography with little relief. The entire
area surrounding 1,000 feet of the site is mapped at approximately 200 feet above sea level.
Local topography is depicted in Figure 1.

LAND COVER/SURFACE DRAINAGE
The release area in overlain by an asphalt and concrete parking lot. Precipitation which falls on
the uncovered potions of the site infiltrates the underlying soil. Excess runoff and shallow soil
drainage is directed toward the creek located along the western edge of the property either by
the slope of the land or the drainage ditch located along the northern edge of the property.

HYRDOLOGY
The groundwater elevation measurements collected during the CSA reveal that the hydraulic
head within the shallow phreatic aquifer ranged from a relative value of approximately 95.59 feet
in monitoring wells MW5 and MW6 to approximately 97.29 feet in monitoring well MW4 as
measured on January 28, 2015. As measured parallel to groundwater flow, these results indicate
that flow in the phreatic aquifer is in a westerly direction under an average hydraulic gradient of
approximately 0.017. Note that the plume geometry indicates a westerly-southwesterly flow.

Water level data from the Type III monitoring well (MW8) and the interpreted groundwater
elevation in the phreatic aquifer in the vicinity of the Type III well (interpreted based on contour
lines shown on Figure 9) were used to determine if a vertical head gradient existed in the phreatic
aquifer. The vertical gradient was calculated using the following equation and groundwater
elevation data collected on January 28, 2015:

Comprehensive Site Assessment Report Anthony W. Southerland
Prepared by Terraquest Environmental Consultants, P.C. J.D.’s Country Store
Report Prepared: July 25, 2023 8 Wilson’s Mills, NC
Type III monitoring well MW8

where:

Vg = Vertical head gradient
Hphreatic = Water elevation in the shallow aquifer near MW8 = 95.70’
HMW10 = Water elevation in deep well MW8 = 96.12’
D = The difference in elevation between the shallow water table and the
middle of the well screen in MW10 = (95.70’ – 66.77’) = 28.93’

therefore:

The presence of a small creek located along the western property boundary along with the
vertical head gradient suggests a discharging hydraulic flow gradient. With increasing depth and
distance from the recharge area, the flow lines flatten out and become more horizontal than
vertical. Eventually, as the flow lines near lower elevations, the flow lines curve upward toward
the ground surface into areas of discharge such as streams and rivers.

To provide preliminary estimates of hydraulic conductivity (K) and groundwater flow velocity (v)
for the phreatic aquifer, Terraquest personnel performed slug tests on monitoring wells MW3,
MW4, and MW6 on January 28, 2015. Hydraulic conductivity estimates were determined using
Aquifer Test Pro 2010.1, a computer model developed by Waterloo Hydrogeologic. The data was
reduced using the Bouwer and Rice Method (Bouwer and Rice 1976, Bouwer 1989). The hydraulic
conductivity estimates range from 0.0209 to 0.0432 feet per day. These values for hydraulic
conductivity fall within the range expected of silt (Heath, 1983). The lithologies logged in the
D=V 10g
hhMWphreatic−

015.0 =28.93'
12'95.70'-96.=Vg −

Comprehensive Site Assessment Report Anthony W. Southerland
Prepared by Terraquest Environmental Consultants, P.C. J.D.’s Country Store
Report Prepared: July 25, 2023 9 Wilson’s Mills, NC
saturated zones of the slug tested monitoring wells were noted to include sand with few to trace
clay.

Using an average hydraulic conductivity value of 0.0319 feet per day, an average groundwater
seepage velocity value was determined to be 0.011 feet per day or 3.88 feet per year. An
effective porosity of 0.15 and a hydraulic gradient of 0.05 (based upon 1/28/15 data) were used
for calculating the groundwater flow velocity (Sanders, 1998 and Heath, 1983). Given the length
of time that may have lapsed until the release began, the depth to groundwater, and the current
plum size, the calculated seepage velocity appears reasonable. However, the velocity does not
consider the effects of retardation, adsorption, and biodegradation of the plume which will slow
plume advancement. Additional heterogeneities across the site will also affect the plume’s
migration speed.

6.0 SOIL ASSESSMENT

6.1 UST Closure and Excavation

As indicated above, Terraquest personnel supervised the removal of the subject UST on July 9,
2007. Per Mr. Bob Heath of the NCDWM-UST soil samples were not collected beneath the UST
or along the product lines or at the dispensers. Soil samples collected at the limits of the
excavation revealed the presence of petroleum-type contaminants at concentrations in excess
of the STG-MSCCs. Analytical results for soil samples collected at the limits of the excavation are
summarized in Table 4. Locations of the limit of excavation soil samples are displayed on Figure
4.

As part of Phase I LSA activities, Terraquest personnel supervised the installation of monitoring
well MW1 in the T1/T1B UST basin. Due to the shallow nature of groundwater, a soil sample was

Comprehensive Site Assessment Report Anthony W. Southerland
Prepared by Terraquest Environmental Consultants, P.C. J.D.’s Country Store
Report Prepared: July 25, 2023 10 Wilson’s Mills, NC
not collected from the monitoring well. Groundwater elevation data for monitoring well MW1
indicates that water has been measured as shallow as 3.79 feet BGL.

As the release point associated with this release incident is the former 6,000-gallon and 3,000-
gallon compartment UST, and given the shallow nature of groundwater, it is likely that petroleum
released from the subject UST impacted groundwater directly. Review of the soil analytical data
indicates that the limit-of-excavation soil samples were all collected well below the water table.
Based upon this information, Terraquest believes that soil contamination documented at the site
is the result of dissolved-phase groundwater contamination and that no true soil contamination
exists at the site.

6.2 Extent of Capillary Zone Impact

Due to the presence of dissolved-phase groundwater contamination, a zone of soil contamination
may exist at the soil water interface. This contamination is the result of petroleum compounds
in or on the groundwater being retained on the surface of the soil in the capillary zone. This zone
is usually found in areas with higher concentrations of groundwater contamination that are
located chiefly downgradient of the contaminant source area. It may not be a continuous zone
due to variations in soil lithologies and petroleum concentrations in the groundwater. In
addition, fluctuations in the water table elevation may affect the thickness of this zone. The
thickness of the capillary zone at this site is thought to moderate by a few feet seasonally. Depths
to water in the phreatic aquifer have been gauged as shallow as 1.93 feet BGL to as deep as 9.40
feet BGL. Lithologies reported at the vadose/saturated zone border include sand with trace clay.
Historical groundwater elevation data is provided in Appendix D.

7.0 Contaminant Mass Assessment

At the direction of the NCDWM-UST, Terraquest supervised the advancement of soil borings SB1-
SB4 at the locations shown on Figure 5 on May 16, 2023. Each boring was advanced into the

Comprehensive Site Assessment Report Anthony W. Southerland
Prepared by Terraquest Environmental Consultants, P.C. J.D.’s Country Store
Report Prepared: July 25, 2023 11 Wilson’s Mills, NC
water table to a depth of 15 feet BGL. The NCDWM-UST requested the collection of both vadose
zone and saturated samples that were analyzed using UVF technology for Gasoline Range
Organics and Diesel Range Organics (GRO DRO) using ultraviolet fluorescence (UVF). The goal
was to gather data that could provide a general understanding of where contamination was
located.

Prior to advancing borings, East Coast Geophysics was employed to locate utilities at the site.
Many, many utilities were identified between monitoring well MW2 and Wilson’s Mills Road.
None of the planned borings or wells were installed in that area. The identified utilities are shown
in the following Terraquest drone picture that has been enhanced with colored lines:

Comprehensive Site Assessment Report Anthony W. Southerland
Prepared by Terraquest Environmental Consultants, P.C. J.D.’s Country Store
Report Prepared: July 25, 2023 12 Wilson’s Mills, NC
Soil borings SB1-SB4 were advanced by a NC-licensed driller operating a Geoprobe 7822DT
drilling unit. Drilling was supervised by Terraquest’s licensed geologist. Each boring was
advanced to 15 feet BGL. Soil tubes were retrieved and logged for lithology and VOC/SVOCs with
a PID. Boring logs are provided in Appendix C. Samples from the following depths were collected
and analyzed for GRO and DRO UVF: 3-5’, 5-7’, 8-10’, 13-15’.

The results of the vadose zone and aquifer material from SB1-SB4 are shown in Table 5 and on
Figure 5. As noted on both Table 5 and Figure 5, all sample locations were either in the water
table or subject to capillary fringe contamination. That is, these were not true vadose zone soil
samples. The samples are helpful to understand if there is contamination present or not.
However, there are not standards to apply to the results as the STG MSCCs are intended for
vadose zone soil and do not apply to aquifer material.

Overall, the UVF results indicate larger concentrations of VOC/GRO results than SVOC/DRO
results as is expected with a gasoline release. The results also show higher concentrations for
SB1, SB2, and SB3 in the 3-5’ BGL range than the 5-7’, 8-10’, and 13-15’ ranges. The sample from
SB4 had a larger 5-7’ BGL concentration than the other intervals.

The full analytical report for the SB1 through SB4 UVF analyses is provided in Appendix E.

Comprehensive Site Assessment Report Anthony W. Southerland
Prepared by Terraquest Environmental Consultants, P.C. J.D.’s Country Store
Report Prepared: July 25, 2023 13 Wilson’s Mills, NC
The results are presented in cross-sectional view as follows with concentrations listed in mg/kg:

Comprehensive Site Assessment Report Anthony W. Southerland
Prepared by Terraquest Environmental Consultants, P.C. J.D.’s Country Store
Report Prepared: July 25, 2023 14 Wilson’s Mills, NC
8.0 GROUNDWATER QUALITY

8.1 Groundwater Flow Data

On May 17, 2023, Terraquest personnel measured the depth to water in each monitoring well to
determine the location of the phreatic aquifer and to determine the direction of its flow.
Groundwater elevation measurements have been reduced to a common datum by surveying the
relative elevations of the top of the casings for each monitoring well. The calculated water table
elevations were plotted on a plan of the site and used to create a contour map of the water table
surface as shown on Figure 6. The potentiometric surface map shows that the groundwater head
is decreasing toward the west in the direction of the creek. Similar trends in groundwater flow
have been noted during previous sampling events. Elevation data collected on May 17, 2023 is
summarized in Table 6. Historical groundwater data is summarized in Appendix C.

8.2 New Well Installation

On May 16, 2023, Terraquest personnel supervised the installation of two additional Type II
monitoring wells, MW9 and MW10, at the locations shown on Figure 3. Additional wells could
not be installed due to the presence of utilities and lack of offsite access. Monitoring wells MW9
and MW10 were installed by an NC-licensed driller operating a Geoprobe 7822DT drilling unit.
The wells were constructed of three feet of 2”-diameter, Schedule 40 PVC casing attached to
twelve feet of 2”-diameter, Schedule 40 PVC screen with a 0.010” slot size for a total well depth
of fifteen feet. Well construction information is detailed in Table 6 and on the well record
provided in Appendix D. Appendix D also contains soil boring logs for the wells.

Comprehensive Site Assessment Report Anthony W. Southerland
Prepared by Terraquest Environmental Consultants, P.C. J.D.’s Country Store
Report Prepared: July 25, 2023 15 Wilson’s Mills, NC
8.3 Groundwater Sampling

On May 17, 2023, Terraquest personnel collected groundwater samples from the entire
monitoring well network. Prior to sampling, each well was purged of at least three well volumes
of water using a new disposable bailer. The same bailers were then used to retrieve
representative groundwater samples and place them into the appropriate laboratory-prepared
containers. The containers were labeled and packed on ice pending shipment to an NC-certified
laboratory. Each sample was analyzed for VOCs per 6200B + 5 oxygenates and 504.1 targeting
EDB. The new wells, MW9 and MW10, were also analyzed for lead and MADEP VPH.

The groundwater analytical results of the May 17, 2023, groundwater sampling event revealed
the following regarding petroleum-type compounds:

Free product: none gauged
>GCL: MW2, MW9, MW10
>2L Standards: MW1, MW3, MW5, MW6 and MW7
<2L Standards: MW4 and MW8

GCL violations persist at this site causing the continued Intermediate Risk ranking. 2L Standard
violations are also present. The plume shape and size are similar to those reported for 2015 and
2022. The 2L violation plume measures 140 feet long by 90 feet wide and covers an area of 9,300
square feet. The GCL violation plume measures 40 feet by 40 feet and covers an area of 1,300
square feet. Note that the GCLs are the cleanup standard for this Intermediate Risk site. They
are present in three monitoring wells downgradient of the gasoline dispensers.

The groundwater analytical results are summarized in Table 7 and on Figure 7. Isoconcentration
maps for benzene, toluene, ethylbenzene, and xylenes are presented as Figures 8-11. Historical

Comprehensive Site Assessment Report Anthony W. Southerland
Prepared by Terraquest Environmental Consultants, P.C. J.D.’s Country Store
Report Prepared: July 25, 2023 16 Wilson’s Mills, NC
groundwater data is summarized in Appendix D. The full analytical report is provided in Appendix
E.

9.0 CONCLUSIONS / RECOMMENDATIONS

Recent groundwater analytical results have reported GCL and 2L Standard violations similar to
those from 2015 and 2022. MNA alone has not worked to reduce concentrations to a level where
the incident can be closed. Terraquest recommends investigating corrective actions to move this
release incident toward closure.

10.0 LIMITATIONS

This report is limited to the investigation of petroleum-type compounds and does not imply that
other unforeseen adverse impacts to the environment are not present at the facility. In addition,
subsurface heterogeneities not identified during the current study may influence the migration
of groundwater or contaminants in unpredicted ways. The limited amount of sampling and
testing conducted during this study cannot practically reveal all subsurface heterogeneities.
Furthermore, the subsurface conditions, particularly groundwater flow, elevations, and water
quality may very through time. The opinions and conclusions arrived at in this report are in
accordance with industry-accepted geologic and hydrogeologic practices at this time and
location. No warranty is implied or intended.

Comprehensive Site Assessment Report Anthony W. Southerland
Prepared by Terraquest Environmental Consultants, P.C. J.D.’s Country Store
Report Prepared: July 25, 2023 1 Wilson’s Mills, NC
REFERENCES

Brown, et al., 1985. Geologic Map of North Carolina, North Carolina. Department of Natural
Resources and Community Development, 1:500,000 scale.

Bouwer, H., and R.C. Rice 1976. A slug test for determining hydraulic conductivity of unconfined
aquifers with completely or partially penetrating well. Water Resources Research 12, no.
3: 423 – 428.

Bouwer, H. 1989. The Bouwer and Rice slug test – an update. Ground Water. 27, no. 3: 304 –
309.

Heath C. Ralph. 1983. Basic Groundwater Hydrology, US Geological Survey Water-Supply Paper
2220, US Government Printing Office: 13.

Sanders, Laura L. 1998. A Manual of Field Hydrogeology. Upper Saddle River, New Jersey: Prentice
Hall Inc.: 196.

TABLES

Table 1
Date: 7/20/23
Capacity
UST Product (Gallons)Release Discovered
T1 Gasoline 6,000 12/5/71 7/9/07 Yes
T1b Gasoline 3,000 12/5/71 7/9/07 Yes
T2 Gasoline 12,000 1/1/02 N/A No
T3 Gasoline 8,000 1/1/02 N/A No
T4 Diesel 5,000 1/1/02 N/A No
T5 Gasoline 6,000 7/12/07 N/A N/A
T5b Diesel 4,000 7/12/07 N/A N/A
Capacity
AST Product (Gallons)Release Discovered
AST1 Kerosene 550 6/01 in-use No
AST2 Off-Road Diesel 550 6/01 in-use No
AST3 Off-Road Diesel 1,000 6/01 in-use No
AST4 Kerosene 550 1/81 6/01 No
Notes:
1. Information obtained from the NC UST Database Records, onsite observations, and responsible party.
2. No release from the other USTs or ASTs has been discovered.
3. Installation and closure dates for the ASTs are approximate. The ASTs are owned by Stancil Oil Company.
Table 2
Date: 7/20/23 Facility ID No. 0-026046
Tax Parcel Number
(Map ID Number)Property Owner Property Owner Address Property Address
REYES-CAMARILLO, RAFAEL PO BOX 113 21A Fire Department Rd
FRAIRE, PATRICIA WILSONS MILLS, NC 27593-0113 Clayton, NC 27527
Wilson 1995 Family LMTD 101 East Johnston St Wilson's Mills Rd.
Wilson 1995 Family LMTD 101 East Johnston St 22 Fire Department Rd
2. Last 5 digits of MAP ID numbers correspond with those displayed on Figure 2. updated 7/14/22
SURROUNDING PROPERTY OWNERS
SITE
Table 3
Date: 7/20/23 Facility ID No. 0-026046
Well Depth Type Casing Depth Screen Interval Distance from Source
Well ID No. Well Owner/Address Well Address Well Use (feet BGS)of Well (feet BGS)(feet BGS)Area of Release (feet)
MARSH, WILLIAM C. and PATTY H.on city water
PW1 91 SWIFT CREEK RD 33 SWIFT CREEK RD not in use unknown unknown unknown unknown 703
SMITHFIELD, NC 27577-9320 SMITHFIELD, NC 27577 abandoned
HERNANDEZ, ISAAC R.
PW2 40 Powhatan Road 40 Powhatan Road sole source uknown uknown uknown uknown 1,446
Clayton, NC 27257 Clayton, NC 27257
Kenneth R. Jones on city water
PW3 PO Box 208 744 MAIN ST not in use uknown uknown uknown uknown 1,116
Wilsons Mills, NC 27593 SMITHFIELD, NC 27577
Ronald D. Foxworth on city water
PW4 PO Box 337 104 Railroad Street not in use unknown unknown uknown uknown 1,127
Wilson Mills, NC 27593 Smithfield, NC 27577
MCCASKILL, ROD 17K07021D
PW5 110 RAILROAD ST 110 RAILROAD ST sole source uknown uknown uknown uknown 1,447
SELMA, NC 27576 SMITHFIELD, NC 27577-
BAGWELL, JASON M. AND MANDY H.17J06012A on city water
PW6 508 SOUTHMEAD DR 508 SOUTHMEAD DR not in use uknown uknown uknown uknown 1,363
CLAYTON, NC 27527-6670 SMITHFIELD, NC 27577-
Bobby Ray Creech on city water
PW7 4306 Wilsons Mills Road 4306 Wilsons Mills Road not in use uknown uknown uknown uknown 1,497
Wilsons Mills, NC 27593 Wilsons Mills NC 27593
Ronald D. Foxworth on city water
PW8 PO BOX 337 17K07021F secondary unknown unknown unknown unknown 1,262
Wilson Mills, NC 27593 source
Touch From Above Faith Center on city water
PW9 1571 A Market Street 654 Main Street secondary uknown uknown uknown uknown 1,308
Smithfield, NC 27577 Smithfield, NC 27577 source
Wilson Mills Advent Church
PW10 PO Box 98 17Q99033O sole source uknown uknown uknown uknown 1,417
Wilson Mills, NC 27593
WILSON COMPANY LLC on city water
PW11 PO BOX 24 688 Main Street secondary unknown unknown unknown unknown 1,364
WILSONS MILLS, NC 27593-0024 Smithfield, NC 27577 source washing
Kenneth R. Jones on city water
PW12 PO Box 208 17K07020K secondary uknown uknown uknown uknown 1,339
Wilsons Mills, NC 27593 source
Wilson 1995 LMTD PRTSHP on city water
PW13 101 East Johnstan St.22 Fire Department Rd not in use 100 uknown uknown uknown 299
Smithfield, NC 27577 Clayton, NC 27257 abandoned
MARSH, WILLIAM C. and PATTY H.on city water
PW14 91 SWIFT CREEK RD 33 SWIFT CREEK RD secondary uknown uknown uknown uknown 832
SMITHFIELD, NC 27577-9320 SMITHFIELD, NC 27577 source water horses
GRANT, ROBIN W on city water
PW15 94 SWIFT CREEK RD 94 SWIFT CREEK RD secondary uknown uknown uknown uknown 1,114
SMITHFIELD, NC 27577-9321 SMITHFIELD, NC 27577 source
GARDNER, MICHAEL ANTHONY AND PATRICIA on city water
PW16 120 SWIFT CREEK RD 120 SWIFT CREEK RD secondary uknown uknown uknown uknown 1,162
SMITHFIELD, NC 27577-9390 SMITHFIELD, NC 27577-9390 source
DUFFIELD, JEFFREY AND STACEY Aqua
PW17 4399 WILSONS MILLS RD 4399 WILSONS MILLS RD community unknown unknown unknown unknown 1,148
SMITHFIELD, NC 27577-5587 SMITHFIELD, NC 27577-5587 well
Edward Sasser on city water
PW18 PO Box 115 4386 Wilsons Mills Rd not in use unknown unknown unknown unknown 1,043
Wilsons Mills, NC 27593 Smithfield, NC 27577 abandoned
Kenneth R. Jones on city water
PW19 PO Box 208 17K08008K not in use unknown unknown unknown unknown 638
Wilson Mills, NC 27593 abandon
DUFFIELD, JEFFREY AND STACEY on city water
PW20 4399 WILSONS MILLS RD 4399 WILSONS MILLS RD secondary 100 unknown unknown unknown 921
SMITHFIELD, NC 27577-5587 SMITHFIELD, NC 27577-5587 source washing
Notes:
1. "BGS" = feet below ground surface, "NA" = not applicable.
2. Information obtained from TerraQuest field interviews.
3. Well ID numbers are displayed on Figure 2. updated 7/5/22
Table 4
Date: 7/20/23 Facility ID No. 0-027378
82
6
0
+
M
t
B
E
+
I
P
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82
6
0
+
M
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B
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82
6
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+
M
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82
6
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+
M
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B
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+
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82
6
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+
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82
6
0
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M
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+
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82
6
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+
M
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+
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82
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82
6
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/
8
2
7
0
82
6
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M
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B
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+
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82
6
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+
M
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B
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82
6
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+
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82
6
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82
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82
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82
6
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+
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+
I
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MA
D
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P

V
P
H
MA
D
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P

V
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MA
D
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P

V
P
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50
3
0
Sample ID
Date Sample Depth
Be
n
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h
y
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0

A
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o
m
a
t
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c
s
0.64 5.2 22 25 0.96 <0.0014 19 4.7 2.9 0.18 0.017 0.10 2.4 0.091 0.041 0.11 72.0 110 63 -
0.0041 <0.0011 <0.0011 <0.0011 <0.00055 <0.055 <0.0011 <0.0011 <0.0011 0.0014 <0.0011 <0.011 8.5 12.0 5.9 -
0.0070 0.20 0.16 0.54 <0.0011 <0.0011 0.98 0.20 0.092 <0.056 0.013 0.036 0.14 0.044 0.022 0.012 5.2 8.6 5.1 -
0.045 0.033 0.53 0.16 0.038 <0.0015 0.044 0.015 0.026 <0.074 <0.0015 0.0024 0.0074 0.0024 <0.0015 <0.015 <7.0 <7.0 <7.0 -
0.0048 0.091 0.20 0.36 0.0036 <0.0012 1.1 0.17 0.11 0.060 0.0099 0.022 0.086 0.034 0.016 0.016 8.6 18 10 -
0.15 0.16 0.77 0.84 1.8 <0.021 0.47 0.16 0.23 1.3 <0.021 0.024 0.082 0.029 <0.021 0.25 88 28 16 -
0.0027 <0.0012 <0.0012 <0.0012 <0.0063 <0.063 <0.0012 <0.0012 <0.0012 <0.0012 <0.0012 <0.012 <5.4 <5.4 <5.4 -
0.015 <0.0061 0.016 <0.0012 <0.0012 0.031 0.0061 <0.0061 <0.061 <0.0012 0.0027 0.0088 0.0025 <0.0012 <0.012 <5.5 <5.5 <5.5 -
0.56 2.8 9.3 9.4 <0.0013 <0.0013 9.8 2.9 2.6 0.41 0.050 0.23 2.6 0.87 0.10 0.11 110 180 110 -
88.0
38.0
Bold denotes a compound detection.
Table 5
Date: 7/21/23 Facility ID No. 0-027378
Tr
i
l
o
g
y

U
V
F
Tr
i
l
o
g
y

U
V
F
Sample ID GR
O
DR
O
764 9.46
499 86
355 86
1.84 0.78
802 91
304 32
580 193
2.9 2.1957106
13.88 7.32
563 201
1.36 0.58
1.86 0.8
804 195
9.3 2.443.2 0.72
269 17
Bold denotes a compound detection.
Table 6
Date: 7/24/23 Facility ID No. 0-026046
Screened Depth to Water
Date Water Interval Bottom of Top of Casing From Top of Free Product Groundwater
Level (x to y Well Elevation Casing Thickness Elevation
Well ID Date Installed Measured feet BGS)(feet BGS)(feet)(feet)(feet)(feet)Comments
MW1 2/4/2008 5/17/2023 3 - 13 13 100.35 4.43 -95.92 2"-diameter Type II monitoring well
MW2 3/24/2008 5/17/2023 3 - 13 13 99.91 4.98 -94.93 2"-diameter Type II monitoring well
MW3 3/24/2008 5/17/2023 3 - 13 13 99.68 4.93 -94.75 2"-diameter Type II monitoring well
MW4 3/24/2008 5/17/2023 3 - 13 13 100.25 2.41 -97.84 2"-diameter Type II monitoring well
MW5 1/5/2015 5/17/2023 3 - 13 13 99.49 5.51 -93.98 2"-diameter Type II monitoring well
MW6 1/5/2015 5/17/2023 3 - 13 13 99.07 4.60 -94.47 2"-diameter Type II monitoring well
MW7 1/8/2015 5/17/2023 3 - 13 13 98.77 4.61 -94.16 2"-diameter Type II monitoring well
MW8 1/6/2015 5/17/2023 OC: 20 IC: 30 30 - 35 35 99.27 5.39 -93.88 2"-diameter Type III monitoring well
MW9 5/16/2023 5/17/2023 3-15 15 99.68 4.34 -95.34 2"-diameter Type III monitoring well
MW10 5/16/2023 5/17/2023 3-15 15 100.09 5.50 -94.59 2"-diameter Type III monitoring well
Notes:
1. All units in feet.
2. "-" = no detection of free product in the well, "BGS" = below ground surface, "OC" = outer casing, "IC" = inner casing.
MONITORING WELL CONSTRUCTION INFORMATION
Incident Name: J.D's Country Store Incident No. 29463
Well Casing
Depth
(feet BGS)
3
3
3
3
3
3
3
3
3
62
0
0
B
62
0
0
B
62
0
0
B
62
0
0
B
62
0
0
B
62
0
0
B
62
0
0
B
62
0
0
B
62
0
0
B
62
0
0
B
62
0
0
B
62
0
0
B
62
0
0
B
62
0
0
B
62
0
0
B
62
0
0
B
62
0
0
B
50
4
.
1
60
1
0
D
MA
D
E
P

V
P
H
MA
D
E
P

V
P
H
MA
D
E
P

V
P
H
Well ID
MW1 5/17/23 484 9.31 1,990 950 35.7 3.29 < 100 1,210 12.5 < 26.0 < 1.90 46.9 388 183 399 23.6 < 2.30 < 2.30 ----
7,130 608 1,030 1,880 3,710 201 < 500 34,900 < 38.0 < 130 < 9.50 35.5 238 109 998 111 < 11.5 < 11.5 ----
2,470 353 452 280 2,710 46.8 < 200 4,380 < 15.2 < 52.0 < 3.80 15.7 146 40.5 72.3 48.0 < 4.60 < 4.60 ----
26.9 < 4.50 < 0.760 6.71 < 0.190 < 0.530 < 3.00 < 0.690 < 0.820 < 0.560 < 0.230 < 0.230 ----
1,600 < 18.0 99.0 140 1,590 73.0 < 200 4,400 < 15.2 < 52.0 < 3.80 13.7 73.5 34.0 42.4 12.5 < 4.60 < 4.60 ----
1,080 301 196 517 596 34.3 < 100 2,090 7.86 < 26.0 < 1.90 22.1 125 60.8 217 74.0 3.27 < 2.30 ----
4.48 < 0.900 0.715 < 1.60 116 2.88 < 10.0 245 < 0.760 < 2.60 1.04 < 0.530 < 3.00 < 0.690 < 0.820 < 0.560 0.347 < 0.230 ----
13,000 28,100 2,270 13,100 9,590 189 < 2000 7,880 < 152 < 520 < 38.0 < 106 < 600 178 1,510 455 < 46.0 < 0.0148 0.519 123,000 14,200 27,600
7,500 30,200 749 3,310 11,900 253 < 5000 48,400 < 380 < 1300 852 < 265 < 1500 < 345 485 < 280 < 115 0.932 < 0.00200 204,000 13,300 10,100
Italics indicates a GCL violation

FIGURES

SITE

APPENDIX A

Page 1 of 8 
 TECHNICAL METHODS/STANDARD PROCEDURES 

Equipment Decontamination 

All soil sampling equipment utilized during site assessment activities is decontaminated according 
to standard and accepted protocol.  Cleaning solutions range from clean potable water to acidic 
solutions or organic solvents depending on the contaminants present at the site.  Equipment 
utilized at sites, such as hand augers, contaminated with petroleum hydrocarbons, is generally 
decontaminated with a low‐sudsing detergent such as Luiquinox® and triple rinsed with distilled 
water.   Larger equipment, such as drill rigs and associated tools, is steam cleaned.   All 
decontamination procedures are completed within an established decontamination area which is 
located away from the active study area.  Frequency of equipment decontamination depends on 
the nature of work being performed, but in no case is decontamination performed less frequently 
than once per test (i.e., soil boring, well installation, sample collection, etc.).  Equipment blanks are 
collected as a quality control measure when required by job specifications. 

Soil Boring Installation 

Soil borings are completed using hand‐operated sampling tools, truck‐mounted drills, or 
Geoprobe® drilling rigs depending on the depth of sample collection and other site‐specific 
conditions.  Hand operated stainless‐steel bucket augers are utilized to collect soil samples at 
regular intervals to determine site stratigraphy and to test for the presence of volatile organic 
compounds.  Samples retrieved from the hand auger are necessarily disturbed during the augering 
process, but can provide accurate information on soil type and contaminant concentrations when 
properly interpreted.  Soil samples from hand augered borings are generally retrieved at one to 
two foot intervals. 

Truck‐mounted or Geoprobe® drilling equipment is often utilized when sample retrieval depths 
exceed twenty feet or subsurface conditions prevent utilization of hand augers (i.e., buried rocks, 
wood, bricks or other materials occur in the subsurface).  Truck‐mounted drilling rigs usually 
retrieve soil via a hollow‐stem auger/split spoon collection method.  Geoprobe® rigs usually employ 
a Macro‐Core® tube retrieval system.   

Hollow stem augers provide relatively undisturbed 2‐foot cores of soil samples.  Soil samples are 
generally collected at five foot intervals utilizing standard penetration test procedures as defined 
by the American Society for Testing and Materials (ASTM) or are pushed to the desired depth using 
the head of the drill rig.  The standard penetration test involves driving a 2" outside diameter by 1‐
3/8" inside diameter split‐spoon sampler a minimum distance of one foot with a 340‐lb. slide 
hammer falling a distance of 30 inches.   

A Geoprobe® rig is a hydraulically‐powered soil probing machine.  The probe utilizes static force 
and percussion to advance a small diameter sampling device into the subsurface.  The sampling 
apparatus provides relatively undisturbed 5‐foot cores of soil samples.  Soil samples are collected 
Page 2 of 8 
continuously.  The Macro‐Core® tube contains an inserted poly‐vinyl chloride (PVC) liner which 
retains the soil sample as the tube is driven into the ground.   The Macro‐Core® tube is 
decontaminated between each 5‐foot sample interval in a soil boring using a Liquinox and tap‐
water mixture.  A new PVC liner is used to collect soil from each sample interval in a soil boring.    

Soil samples retrieved from the hollow‐stem augers or Geoprobe are then carefully described 
according to the Unified Soil Classification System.  Soil descriptions are recorded on a soil 
boring log. 

Soil Sampling 

Soils to be analyzed by a North Carolina‐certified laboratory are prepared according to the specified 
analytical method.  Initially, soil samples are removed from the ground using either a hand auger, 
backhoe bucket, spilt spoon auger, or a Macro‐Core® sampling tube.  During the removal, care is 
taken to keep the disturbance of the soil structure to a minimum to reduce the loss of 
contaminants.  Once removed, the samples are placed in the proper sample container for the 
specified analytical method.  For samples collected for the MADEP VPH and EPA Method 8260, a 
TerraCore® sampler is used to collect one 5‐gram allotment of soil.  The allotment is placed in 
methanol‐preserved 40 mL vials.  Also, one 5‐gram allotment of soil is placed into sodium bisulfate‐
preserved 40 mL vials (one 5‐gram allotment per vial, 2 vials per sample) for the 8260 low 
concentration method.  A 250‐mL glass jar of the sampled soil is also collected to provide moisture 
content information.  Soils sampled for MADEP EPH, EPA Method 8270 and TPH 5030 and 3550 are 
placed in a 250‐mL glass jar (for MADEP EPH analysis an amber jar is required).  TPH 5030 samples 
are preserved in methanol similar to the 8260 analysis.  Field personnel wear new, disposable 
nitrile gloves during the collection of each sample.  

The soil samples are labeled with the sample location, sample identification, date and time of 
collection, and the analytical method.  The samples are placed on ice, sent to a laboratory, and 
analyzed before the expiration of an analytical method’s prescribed holding time.  Chain‐of‐custody 
documentation is maintained for each sample collected in the field. 

If the soil is being sampled for volatile or semi‐volatile compounds, a portion of the collected soil is 
placed in a sealable bag and screened for volatile organic vapors.  Head screening procedures are 
described in the following paragraph.  

Headspace Screening 

Collected soil samples are routinely tested for the presence of volatile organic compounds (VOCs).  
After retrieval from the ground, a portion of a soil sample is placed in a sealable plastic bag.  The 
soil samples are then set aside for approximately five minutes so that volatile constituents present 
in the sample can reach equilibrium concentrations with headspace gases in the bag.  Once a 
suitable time period has passed, the probe of the sampling instrument, typically an Organic Vapor 
Monitor (OVM) or a Photo Ionization Detector (PID), is inserted into the bag and the relative 
concentration of total VOCs is measured and permanently recorded in a field note book.  VOC 
Page 3 of 8 
concentrations are measured using either a Thermo Electron Corp. Innova Series catalytic OVM or 
an Ion Science PhoCheck PID.  Both the OVM and PID instrumentation are periodically calibrated 
according to the manufacturer’s recommended procedures. 

The OVM and PID are qualitative tools employed to detect and estimate the concentration of 
organic or hydrocarbon vapors.  A thin probe is inserted through a small break in the seal of a 
bagged soil sample.  For the OVM, an air sample from the headspace of the bag is drawn through 
the probe into an internal chamber where the vapors are catalyzed.  The concentration of the VOCs 
is registered on a digital scale in parts per million (ppm).  For the PID, an air sample from the 
headspace of the bag is drawn across the face of a lamp causing the sample to emit photons, the 
presence of which are converted into a VOC ppm reading that is displayed.  Oxygen levels are field 
calibrated prior to each use.  VOC calibration occurs periodically depending upon use by using a 
span gas of known concentration in a process recommended by the manufacturer.   

Well Installation/Construction 

Monitoring wells are installed using hand‐operated sampling tools, a truck‐mounted drill rig, or a 
Geoprobe drilling rig depending on the depth of well and other site‐specific conditions. All 
monitoring wells are installed according to the requirements of 15A NCAC 2C‐Well Construction 
Standards.  Specifically, individual monitoring wells are constructed of 2‐inch diameter, schedule 40 
PVC casing riser and screen.  The screen interval is generally 10 to 15 feet of machine slotted PVC 
with a slot size of 0.010".  Only flush threaded joints are used.  The annulus space around the 
screen is filled with washed filter pack No. 2 sand.  The filter pack extends one to two feet above 
the top of the screen.  A one to two foot‐thick bentonite pellet seal is then placed above the filter 
pack.  The remainder of the well annulus is completely filled with a Portland (Type I/II) cement 
grout mixture.  A protective outer steel manhole, locking cap, and concrete pad is installed for each 
well. 

Type II Monitoring Well Construction  

Single‐cased monitoring wells are generally used in delineation of groundwater quality within the 
surficial aquifer.  The wells are constructed of 2‐inch diameter, schedule 40 PVC casing and screen.  
The screen interval is generally 10 to 15 feet of machine slotted PVC with a slot size of 0.010".  Only 
flush threaded joints are used.  The annulus space around the screen is filled with washed filter 
pack No. 2 sand.  The filter pack extends one to two feet above the top of the screen.  A one to two 
foot‐thick bentonite pellet seal is then placed above the filter pack.  The remainder of the well 
annulus is completely filled with a Portland (Type I/II) cement grout mixture.  A protective outer 
steel manhole, locking cap, and concrete pad are installed for each well. 

Type III Monitoring Well Construction 

Double‐cased monitoring wells are used in the delineation of groundwater quality within a deeper 
portion of the surficial aquifer or an additional aquifer (e.g. aquitard, bedrock).  A four to six‐inch 
outer casing is installed through the surficial aquifer until a sufficient depth or until the deeper 
Page 4 of 8 
aquifer is encountered.  The casing is secured with a Portland‐grout collar that is tremmied into the 
annular spaced from the bottom of the bore hole to the surface.  Once the grout has sufficiently 
cured, the bore hole is continued through the bottom of the outer casing to a depth approximately 
15 ‐ 20 feet beneath the outer casing.  The inner casing is constructed of 2‐inch diameter, schedule 
40 PVC casing riser and screen.  The screen interval is generally 5 to 10 feet of machine slotted PVC 
with a slot size of 0.010".  Only flush threaded joints are used.  The annulus space around the 
screen is filled with washed filter pack No. 2 sand.  The filter pack extends one to two feet above 
the top of the screen.  A one to two foot‐thick bentonite pellet seal is then placed above the filter 
pack.  The remainder of the well annulus is completely filled with the same Portland grout mixture 
used in the outer casing.  A protective outer steel manhole, locking cap, and concrete pad are 
installed for each well. 

Well Development 

Following installation of each well, surging and pumping or bailing techniques will be used to 
remove fines from the screened interval.  Groundwater is removed from each well until clear water 
is retrieved or a noticeable reduction in the amount of silt is achieved.  Purged groundwater is 
disposed of in an environmentally safe manner. 

Groundwater Sampling 

Petroleum Sites 

Groundwater samples are collected from temporary or permanent monitoring wells according to 
established sampling protocol.  When multiple monitoring wells or sampling points are sampled, 
sampling is completed beginning with the least contaminated well to the most contaminated well, 
if it is known.  When permanent monitoring wells for petroleum sites are sampled, the well is 
purged of a minimum of three well‐bore volumes prior to sample collection in order to assure that 
sampled water is representative of aquifer conditions.  In temporary wells, the first water which 
migrates into the open borehole is sampled.  Samples from both temporary and permanent 
monitoring wells are collected using individually wrapped disposable polyethylene bailers by field 
personnel wearing disposable nitrile gloves.  Only one well is sampled with a given bailer in order to 
prevent sample cross‐contamination.  During both well purging and sampling, proper protective 
clothing and equipment is used and is dependent upon the type and level of contaminants present. 
Also, field personnel change gloves between different samples to reduce the chance of cross‐
contamination. Water samples are transferred from the bailer to laboratory‐prepared sampling 
containers using slow emptying devices to reduce the chance of contamination loss through 
volatilization.   Preservatives, such as acids, are provided by the laboratory in pre‐prepared 
containers in which collected samples are placed if in‐field preservation is necessary.  The samples 
are labeled with the project name, project number, sample identification, required analysis, and 
date and time of collection.  The samples are placed on ice, shipped to a certified laboratory, and 
analyzed before the expiration of an analytical method’s prescribed holding time.  Chain‐of‐custody 
documentation is maintained for each sample collected in the field.   

Page 5 of 8 

Other Groundwater Sampling Protocols 

When required by state or federal regulations, low‐flow groundwater sampling procedures are 
instituted.  Groundwater samples collected in low‐flow situations are collected using a peristaltic 
pump. A peristaltic pump is a type of positive displacement pump. The fluid is contained within a 
flexible tube fitted inside a circular pump casing.  A rotor with a number of rollers attached to the 
external circumference compresses the flexible tube. As the rotor turns, the part of tube under 
compression closes thus forcing the fluid to be pumped to move through the tube.  Groundwater 
parameters such as water level drawdown, pH, conductivity, dissolved oxygen (DO) and turbidity. 
Pumping rate, drawdown, and the time or volume required to obtain stabilization of parameter 
readings can be used as a future guide to purge the well. Measurements are collected at a pre‐
pumping established interval (typically five to ten minutes). Once all or a majority of the 
parameters have stabilized for three successive readings, stabilization has been achieved. In lieu of 
measuring all five parameters, a minimum subset would include pH, conductivity, and turbidity or 
DO. Three successive readings should be within ± 0.1 for pH, ± 3% for conductivity, and ± 10% for 
turbidity and DO.  

Upon parameter stabilization, sampling is initiated. Sampling flow rate is maintained at the estab‐
lished purge rate or is adjusted slightly to minimize aeration, bubble formation, turbulent filling of 
sample bottles, or loss of volatiles due to extended residence time in tubing. The same device used 
for purging is used to collect the groundwater sample. Generally, volatile parameters are sampled 
first. The sequence in which samples for inorganic parameters are collected is not determined 
unless filtered (dissolved) samples are collected. Preservatives, such as acids, are provided by the 
laboratory in pre‐prepared containers in which collected samples are placed if in‐field preservation 
is necessary.   The samples are labeled with the project name, project number, sample 
identification, required analysis, and date and time of collection.  The samples are placed on ice, 
shipped to a certified laboratory, and analyzed before the expiration of an analytical method’s 
prescribed holding time.  Chain‐of‐custody documentation is maintained for each sample collected 
in the field.   

During both well purging and sampling, proper protective clothing and equipment is used and is 
dependent upon the type and level of contaminants present.   Also, field personnel change gloves 
between different monitoring wells or sampling points to reduce the chance of cross‐
contamination.  When multiple monitoring wells or sampling points are sampled, sampling is 
completed beginning with the least contaminated well to the most contaminated well, if it is 
known. 

Stockpile Sampling 

The number of composite samples collected from a stockpile or a total quantity of excavated soil is 
based upon the cubic yardage.  One composite sample is collected for every 100 cubic yards of 
contaminated soil excavated.  The volume of a stockpile or total quantity of excavated soil is 
calculated by approximating the general geometry of a stockpile or estimating the capacity of the 
Page 6 of 8 
dump trucks used for hauling.  If a stockpile is sampled, a grid pattern is laid out on the stockpile, 
dividing the stockpile into segments of approximately 200 cubic yards.  Two soil borings are 
advanced within a grid and three soil samples are collected from each soil boring at various depths. 
 The six soil samples are mixed into a composite sample by a trained TerraQuest technician.  If truck 
loads are sampled, an aliquot sample is collected from the hauling trucks at a frequency based 
upon the capacity of the hauling trucks.   

Aliquots are gently mixed into a composite sample by a trained TerraQuest technician. Every effort 
is made to minimize the loss of contaminants through volatilization.  The composited soil samples 
are jarred in the appropriate laboratory‐prepared containers, labeled with the sample location, 
sample identification, date of collection, time of collection, the analytical method, and the 
preservative.  The samples are placed on ice, shipped to a laboratory, and analyzed before the 
expiration of an analytical method’s prescribed holding time.  Chain‐of‐custody documentation is 
maintained for each sample collected in the field. 

Surface Water Sampling 

Surface water samples, specifically samples from creeks or streams, are collected from a 
moving/flowing portion of the creek or stream to ensure that stagnant water is not collected.  Field 
personnel are careful to collect samples from flowing areas that are not so turbulent as to cause a 
loss of volatile contaminants which might have been contained in the creek’s/stream’s water.  
Samples are collected by field personnel wearing disposable nitrile gloves.  Field personnel change 
gloves between different locations to reduce the chance of cross‐contamination.  Samples are 
collected directly from the appropriate creek or stream location and placed into the appropriate 
laboratory‐prepared containers.  Preservatives, such as acids, are provided by the laboratory in pre‐
prepared containers in which collected samples are placed if in‐field preservation is necessary. The 
samples are labeled with the project name, project number, sample identification, required 
analysis, and date and time of collection.  The samples are cooled on ice to approximately four 
degrees centigrade, shipped to a certified laboratory, and analyzed before the expiration of an 
analytical method’s prescribed holding time.  Chain‐of‐custody documentation is maintained for 
each sample collected in the field.    

Potable Well Sampling 

Groundwater samples from potable wells are collected from sampling points, typically spigots, 
located in the closest proximity to the potable well pump house as possible.  Prior to sample 
collection, the water is run for a sufficient amount of time to purge the bladder tank and assure 
that sampled water is representative of aquifer conditions.  Once purged, the flow rate is reduced 
and samples are placed in the appropriate laboratory prepared containers with the appropriate 
acid preservatives added if preservation of the sample is necessary.  The samples are labeled with 
the project name, project number, sample identification, required analysis, and date and time of 
collection.  The samples are placed on ice, shipped to a laboratory, and analyzed before the 
expiration of an analytical method’s prescribed holding time.  Chain‐of‐custody documentation is 
maintained for each sample collected in the field.  
Page 7 of 8 
Public Water Supply Line Sampling 

Groundwater samples from public water supply lines are collected from sampling points, typically 
spigots.  To sample the spigot, the flow rate is reduced and samples are placed in the appropriate 
laboratory prepared containers.   The samples are labeled with the sample location, sample 
identification, date of collection, time of collection, and required analytical method.  The samples 
are placed on ice, shipped to a laboratory, and analyzed before the expiration of an analytical 
method’s prescribed holding time.  Chain‐of‐custody documentation is maintained for each sample 
collected in the field.  

Air Sampling 

Air samples are collected with the aide of a manually operated MityVac® pump manufactured by 
Pristech, Inc.  The air sampling process begins by connecting a length of rubber hose from the 
MityVac® pump to the port to be sampled, or by hanging the hose inside of an emissions stack in 
such a manner as to ensure no outside air causes dilution.  Another length of hose is fixed to the 
outlet port of the pump and is connected to a new Tedlar bag.  Once the pump is hooked up, a 
valve on the Tedlar collection bag is opened and air is manually forced into the bag by the pumping 
action of sampling personnel.   

Field Measurements 

Field measurements taken to determine the pH, conductivity, temperature, and dissolved oxygen 
concentration of a particular groundwater sample are taken directly after a particular monitoring 
well has been adequately purged.  This ensures that the groundwater parameter data collected is 
representative of the aquifer conditions at a given location.  Once purging of the monitoring well is 
complete, the decontaminated probe head and cord of the appropriate unit is lowered into the 
required monitoring well.  If the depth to water in a specific monitoring well is greater than the 
length of cord for a particular unit, a new, disposable bailer is slowly lowered into the appropriate 
monitoring well and a representative groundwater sample is retrieved.  A slow pouring device is 
fitted onto the end of the disposable bailer and the sample is slowly poured into a new, disposable 
plastic cup.  Groundwater parameter data are then collected from the groundwater in the cup 
using the required unit.   

For pH, conductivity, and temperature, a Hanna Instruments Model 991300 portable meter is 
utilized.  This unit is periodically calibrated and maintained in accordance with the unit’s operations 
manual by field personnel.  Prior to data collection, the unit is properly decontaminated to prevent 
cross‐contamination.  The unit is decontaminated between each sample.  The procedure used for 
sample measurement involves lowering the meter’s probe into the new, disposable cup containing 
the groundwater sample to be measured and slowly stirring the probe to force groundwater across 
the probe’s membrane.  The measurements displayed by the meter are then recorded.   

For dissolved oxygen concentration measurements, a YSI® Model 55 Handheld Dissolved Oxygen 
System is utilized.  This unit is periodically calibrated and maintained in accordance with the unit’s 
Page 8 of 8 
operations manual by field personnel.  Prior to data collection, the unit is properly decontaminated 
to prevent cross‐contamination.  The unit is decontaminated between each sample.  The procedure 
used for sample measurement involves adjusting the unit for the correct altitude where the 
sampling will take place and adjusting the reported units desired.  Once this is done, the unit’s 
probe is inserted into the groundwater sample to be measured and the probe is slowly stirred to 
force the groundwater across the probe’s membrane.  The measurements displayed by the unit are 
then recorded.   

For turbidity measurements, a Hach 2100P Portable Turbidity meter or equal equivalent is utilized.  
The unit is calibrated prior to use in accordance with the unit’s operations manual by field 
personnel.  Groundwater samples are collected in glass containers for measurement by the 
instrument.  The glass containers are washed with bottled‐water between each measurement 
collection.  Once the sample is collected and inserted into the instrument, the measurements 
displayed by the instrument are then recorded.   

APPENDIX B

CHRONOLOGICAL SITE HISTORY
J.D.’s COUNTRY STORE
4549 WILSON’S MILLS ROAD
SMITHFIELD, JOHNSTON COUNTY, NC 27577
Latitude: 35.5820 N Longitude: -78.3578 W
Facility ID No. 0-013454
NCDWM-UST Incident No. 29463
NCDWM-UST Risk Ranking: INTERMEDIATE I-175-A

November 28, 2006 According to information supplied by Mr. Southerland, Superior
Industrial Maintenance Company performed an internal inspection
of the subject UST (T1/T1B) on. The subject UST consisted of a
6,000-gallon and a 3,000-gallon gasoline compartment. The
inspection of the first compartment by Superior revealed a failure
and further inspection was not conducted. Prior to the inspection,
P&W Oil Services, Inc. removed 940 gallons of residual fuel and
water from the tank. November 28, 2006 was the last date of use
for the UST.

July 6, 2007 Terraquest personnel submitted a UST-3 Notice of Intent form to
the NCDWM-UST.

July 9, 2007 Terraquest personnel supervised the removal of the subject UST
on. Mr. Bob Heath of the NCDWM-UST Fayetteville Regional Office
was also onsite during the removal of the subject UST.

July 9, 2007 Date release confirmed.

August 7, 2007 Terraquest personnel submitted a 24-Hour Release and UST
Reporting form.

January 29, 2008 Terraquest submitted a 20-Day Report.

January 29, 2008 Terraquest submitted an Initial Abatement Action Report.

Page 2 of 4
CHRONOLOGICAL SITE HISTORY
# 29463 J.D.’s COUNTRY STORE

April 14, 2008 The NCDWM-UST issued an NORR indicating that in accordance
with NCGS 143-215.94E(e4) the release did not meet the
requirements for further assessment or corrective action and work
at the site was halted.

2009 The house that potable well PW14 had served burned down and
that there were no immediate plans to rebuild. Based upon this
information the NCDWM-UST issued an NORR dated September
21, 2009 indicating that the release incident had been reclassified
by the Department as intermediate (I140D). During later
assessment it was discovered that a barn had been constructed on
the property and the well was being used to supply water to horses
that were on the property. This classified the well as secondary
source.

April 1, 2014 The NCDWM-UST issued an NORR indicating that the subject
incident had been determined by the Department to be of
sufficient high priority to allow funding from the State Trust Fund
Program and directed to proceed with assessment or remediation
activities.

July 17, 2014 Terraquest submitted a Pre-CAP Groundwater Monitoring Report.

August 12, 2014 In an NORR, the NCDWM-UST again reclassified the site as High Risk
(H132D) and requested the completion of a Comprehensive Site
Assessment Report.

January 28, 2015 To provide preliminary estimates of hydraulic conductivity (K) and
groundwater flow velocity (v) for the phreatic aquifer, Terraquest
personnel performed slug tests on monitoring wells MW3, MW4,
and MW6. The hydraulic conductivity estimates range from 0.0209
to 0.0432 feet per day. These values for hydraulic conductivity fall
within the range expected of silt. The lithologies logged in the
saturated zones of the slug tested monitoring wells were noted to
include sand with few to trace clay.

March 13, 2015 Terraquest submitted a CSA Report

May 25, 2022 In an NORR the NCDWM-UST ranked the site and Intermediate I-
175-A and requested the completion of a sampling event and a
recon update.

Page 3 of 4
CHRONOLOGICAL SITE HISTORY
# 29463 J.D.’s COUNTRY STORE

June 30, 2022 A sensitive receptor survey update was conducted by Terraquest.
The noted changes include the connection to city water at the PW3,
PW4, PW6, and PW7 properties. These properties are beyond
1,000 feet from the release incident.

Terraquest personnel collected groundwater samples from the
entire monitoring well network.

July 21, 2022 The NCDWM-UST issued an NORR requesting additional
assessment.

August 29, 2022 Terraquest emailed the NCDWM-UST with proposed assessment
locations. The NCDWM-UST returns an email with additional
thoughts.

September 1, 2022 Terraquest submitted an ePATA for the requested work.

September 23, 2022 The NCDWM-UST emailed Terraquest with further clarifications on
the required assessment and alterations to the submitted ePATA.

September 27, 2022 Terraquest and the NCDWM-UST had a phone call to discuss the
requested assessment. Terraquest emails a revised ePATA to the
NCDWM-UST following the phone call.

October 7, 2022 The NCDWM-UST emailed Terraquest with requested changes to
the ePATA. Terraquest returned the ePATA with corrections that
day.

October 20, 2022 The NCDWM-UST returned a signed ePATA to Terraquest.

October 27, 2022 Terraquest sends client Basis of Charges for NORR-requested work.

November 21, 2022 Terraquest checked on Bais of Charges status with client.

December 7, 2022 Terraquest emailed Basis of Charges to client.

December 19, 2022 Terraquest checked on Basis of Charges with client.

December 21, 2022 Client returns signed Basis of Charges authorizing work.

January 9, 2023 Terraquest requested property drill access from the offsite
property owner, Johnston County.

Page 4 of 4
CHRONOLOGICAL SITE HISTORY
# 29463 J.D.’s COUNTRY STORE

January 9 and 16 weeks Terraquest called Emma at the Johnston County office regarding
property drill access twice and left messages. She did not return
the calls.

February 14, 2023 Terraquest receives signed NCDOT Right-of-Way Encroachment
Contract from client and submits to NCDOT.

February 28, 2023 The NCDOT issued Encroachment Contract Number: E043-051-23-
00044.

March 14, 2023 Terraquest informs the NCDWM-UST that Johnston County may be
calling them regarding Terraquest’s drilling access request.

March 17, 2023 Terraquest asked the NCDWM-UST if Johnston County had
contacted them requiring property drilling access.

March 20, 2023 The NCDWM-UST emailed Terraquest to state that they had not
been contacted by Johnston County regarding property drilling
access.

Not having heard from Johnston County regarding offsite access, Terraquest scraps those offsite
wells and schedules remaining work:
May 2, 2023 Terraquest scheduled a private utility locator for upcoming
assessment work. Locator emailed back confirming work.
Terraquest also submitted an application for a Monitoring Well
Construction Permit.

May 10, 2023 The NCDEQ issued a Monitoring Well Construction Permit.

May 16-17, 2023 Terraquest supervised the installation of two Type II monitoring
wells, MW9 and MW10 to further delineate GCL violations and four
soil borings to investigate contaminant mass location. A utility
location survey revealed the presence of significant utilities from
Wilson’s Mills Road onto the property that prevented further
investigation as desired. All monitoring wells were sampled.

APPENDIX C

5
10
15

CLAY (CL)
Brown, tan, cream, medium plastic clay with medium-grained sand.
CLAY (CL)
Gray, tan mottled, medium-plastic clay with medium-grained sand.
CLAY (CL)
Brown, tan, medium-plastic clay with medium-grained sand.
Boring terminated 15 feet BGL.

NA
NA
NA

1399
3244
135
BORING LOG
5/16/23
03107
Date Started:
Logged by:
Contractor:
Equipment:
Site:
Project No.:1
Boring Number:
Sa
m
p
l
e
Blow
Counts
Depth Lithology DescriptionFeet
Terraquest
C. Ryan Poythress
JD's Country Store4549 Wilson's Mills Rd.Wilson's Mills, NC
Wes Sorrells SB1
Scale as shown: Hatch pattern denotes soil sample depth;
Driller:
Date Finished:
Page
OVM
(ppm)
Client:Tony SoutherlandPO Box 102Wilson's Mills , NC 27593
Geoprobe 7822DT 5/16/23
Solid denotes lab sample depth; Lithology hatch pattern legend is attached;
NA - Not Applicable; BGL - Below Groundlevel

5
10
15

CLAY (CL)
Brown, tan, cream, medium plastic clay with medium-grained sand.
CLAY (CL)
Gray, tan mottled, medium-plastic clay with medium-grained sand.
CLAY (CL)
Brown, tan, medium-plastic clay with medium-grained sand.
Boring terminated 15 feet BGL.

NA
NA
NA

NA
399
4807
BORING LOG
5/16/23
03107
Date Started:
Logged by:
Contractor:
Equipment:
Site:
Project No.:1
Boring Number:
Sa
m
p
l
e
Blow
Counts
Depth Lithology DescriptionFeet
Terraquest
C. Ryan Poythress
JD's Country Store4549 Wilson's Mills Rd.Wilson's Mills, NC
Wes Sorrells SB2
Scale as shown: Hatch pattern denotes soil sample depth;
Driller:
Date Finished:
Page
OVM
(ppm)
Client:Tony SoutherlandPO Box 102Wilson's Mills , NC 27593
Geoprobe 7822DT 5/16/23
Solid denotes lab sample depth; Lithology hatch pattern legend is attached;
NA - Not Applicable; BGL - Below Groundlevel

5
10
15

CLAY (CL)
Brown, tan, cream, medium plastic clay with medium-grained sand.
CLAY (CL)
Gray, tan mottled, medium-plastic clay with medium-grained sand.
CLAY (CL)
Brown, tan, medium-plastic clay with medium-grained sand.
Boring terminated 15 feet BGL.

NA
NA
NA

4870
4958
245
BORING LOG
5/16/23
03107
Date Started:
Logged by:
Contractor:
Equipment:
Site:
Project No.:1
Boring Number:
Sa
m
p
l
e
Blow
Counts
Depth Lithology DescriptionFeet
Terraquest
C. Ryan Poythress
JD's Country Store4549 Wilson's Mills Rd.Wilson's Mills, NC
Wes Sorrells sB3
Scale as shown: Hatch pattern denotes soil sample depth;
Driller:
Date Finished:
Page
OVM
(ppm)
Client:Tony SoutherlandPO Box 102Wilson's Mills , NC 27593
Geoprobe 7822DT 5/16/23
Solid denotes lab sample depth; Lithology hatch pattern legend is attached;
NA - Not Applicable; BGL - Below Groundlevel

5
10
15

CLAY (CL)
Brown, tan, cream, medium plastic clay with medium-grained sand.
CLAY (CL)
Gray, tan mottled, medium-plastic clay with medium-grained sand.
CLAY (CL)
Brown, tan, medium-plastic clay with medium-grained sand.
Boring terminated 15 feet BGL.

NA
NA
NA

324
324
4.4
BORING LOG
5/16/23
03107
Date Started:
Logged by:
Contractor:
Equipment:
Site:
Project No.:1
Boring Number:
Sa
m
p
l
e
Blow
Counts
Depth Lithology DescriptionFeet
Terraquest
C. Ryan Poythress
JD's Country Store4549 Wilson's Mills Rd.Wilson's Mills, NC
Wes Sorrells SB4
Scale as shown: Hatch pattern denotes soil sample depth;
Driller:
Date Finished:
Page
OVM
(ppm)
Client:Tony SoutherlandPO Box 102Wilson's Mills , NC 27593
Geoprobe 7822DT 5/16/23
Solid denotes lab sample depth; Lithology hatch pattern legend is attached;
NA - Not Applicable; BGL - Below Groundlevel

5
10
15

CLAY (CL)
Brown, tan, cream, medium plastic clay with medium-grained
sand.
CLAY (CL)
Gray, tan mottled, medium-plastic clay with medium-grained
sand.
CLAY (CL)
Brown, tan, medium-plastic clay with medium-grained sand.
Boring terminated 15 feet BGL.

485
3445
304.7
605.9

NA
NA
NA
NA
BORING LOG/MONITORING WELL INSTALLATION DETAIL
5/16/23
03107
Date Started:
Logged by:
Contractor:
Drill Method:
Site:
Project No.:1
Boring Number:
Sa
m
p
l
e
Blow
Counts Completion Depth Lithology DescriptionFeet
C. Ryan Poythress
JD's Country Store4549 Wilson's Mills Rd.Wilson's Mills, NC 27593
MW9
Scale as shown; Hatch pattern denotes soil sample depth;
5/16/23
Solid denotes lab sample depth; Lithology hatch pattern legend is attached;
Page
OVM
(ppm)
Client:Tony SoutherlandPO Box 102Wilson's Mills , NC 27593
Well Construction
2" diameter Sch. 40 PVC; .010" slotted screen
Sand: no. 2 sand; Grout: poured portland; Bentonite: poured pellets
Finished with 8"-diameter metal bolt down manhole.
Driller:
Date Finished:
Terraquest
solid stem auger
Wes Sorrells
NA - Not Applicable; BGL - Below Ground Level

5
10
15

CLAY (CL)
Brown, tan, cream, medium plastic clay with medium-grained
sand.
CLAY (CL)
Gray, tan mottled, medium-plastic clay with medium-grained
sand.
CLAY (CL)
Brown, tan, medium-plastic clay with medium-grained sand.
Boring terminated 15 feet BGL.

84
577
312
236

NA
NA
NA
NA
BORING LOG/MONITORING WELL INSTALLATION DETAIL
5/16/23
03107
Date Started:
Logged by:
Contractor:
Drill Method:
Site:
Project No.:1
Boring Number:
Sa
m
p
l
e
Blow
Counts Completion Depth Lithology DescriptionFeet
C. Ryan Poythress
JD's Country Store4549 Wilson's Mills Rd.Wilson's Mills, NC 27593
MW10
Scale as shown; Hatch pattern denotes soil sample depth;
5/16/23
Solid denotes lab sample depth; Lithology hatch pattern legend is attached;
Page
OVM
(ppm)
Client:Tony SoutherlandPO Box 102Wilson's Mills , NC 27593
Well Construction
2" diameter Sch. 40 PVC; .010" slotted screen
Sand: no. 2 sand; Grout: poured portland; Bentonite: poured pellets
Finished with 8"-diameter metal bolt down manhole.
Driller:
Date Finished:
Terraquest
solid stem auger
Wes Sorrells
NA - Not Applicable; BGL - Below Ground Level
WELL CONSTRUCTION RECORD (GW-1) For Internal Use Only:
Form GW-1 North Carolina Department of Environmental Quality - Division of Water Resources Revised 2-22-2016
1. Well Contractor Information:
Well Contractor Name
NC Well Contractor Certification Number
Company Name
2. Well Construction Permit #:
List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.)
3. Well Use (check well use):
Water Supply Well:
□Agricultural □Municipal/Public
□Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared)
□Irrigation
Non-Water Supply Well:
□Monitoring □Recovery
Injection Well:
□Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier
□Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer
□Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: Well ID#
5a. Well Location:

Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip

County Parcel Identification No. (PIN)
5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees:
(if well field, one lat/long is sufficient)
N W
6. Is(are) the well(s): □Permanent or □Temporary
7. Is this a repair to an existing well: □Yes or □No
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8. For Geoprobe/DPT or Closed-Loop Geothermal Wells having the same
construction, only 1 GW-1 is needed. Indicate TOTAL NUMBER of wells
drilled:
9. Total well depth below land surface: (ft.)
For multiple wells list all depths if different (example- 3@200’ and 2@100′)
10. Static water level below top of casing: (ft.)
If water level is above casing, use “+”
11. Borehole diameter: (in.)
12. Well construction method:
(i.e. auger, rotary, cable, direct push, etc.)
FOR WATER SUPPLY WELLS ONLY:
13a. Yield (gpm) Method of test:
13b. Disinfection type: Amount:
22. Certification:
Signature of Certified Well Contractor Date
By signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a
copy of this record has been provided to the well owner.
23. Site diagram or additional well details:
You may use the back of this page to provide additional well site details or well
construction details. You may also attach additional pages if necessary.
SUBMITTAL INSTRUCTIONS
24a. For All Wells: Submit this form within 30 days of completion of well
construction to the following:
Division of Water Resources, Information Processing Unit,
1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells: In addition to sending the form to the address in 24a
above, also submit one copy of this form within 30 days of completion of well
construction to the following:
Division of Water Resources, Underground Injection Control Program,
1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells: In addition to sending the form to
the address(es) above, also submit one copy of this form within 30 days of
completion of well construction to the county health department of the county
where constructed.
2.Certif at n:
ignature of Certified Well Contractor
Wesley J. Sorrells
3577
Terraquest Environmental Consultants
5/16/23 MW9,Mw10
JD's Country Store 0-013454
4945 Wilson's Mill Rd. Wilson's Mill 27593
Johnston 169609-07-9370
78.3579 35.5820
15
4.34,5.50
6.25
Solid Stem Auger
5/18/23
3 15 2 10Slot Schd.4 PVC
0.5
1
2
1
2
15
Portland
Bentonite
No.2 Sand Pour
Pour
0
0.5
5
0.5
1
5
15
sphalt
Gravel
Sand Cla minor silt
Cla
Print Form
Pour

APPENDIX D

2/8/2008 3/25/2008 7/1/2014 1/28/2015 6/30/2022
Depth to Water Depth to Water Depth to Water Depth to Water Depth to Water
Top of Casing From Top of Free Product Groundwater From Top of Free Product Groundwater From Top of Free Product Groundwater From Top of Free Product Groundwater From Top of Free Product Groundwater
Elevation Casing Thickness Elevation Casing Thickness Elevation Casing Thickness Elevation Casing Thickness Elevation Casing Thickness Elevation
Well ID (feet)(feet)(feet)(feet)(feet)(feet)(feet)(feet)(feet)(feet)(feet)(feet)(feet)(feet)(feet)(feet)
MW1 100.35 7.74 -92.61 3.84 -96.51 4.68 -95.67 3.79 -96.56 6.03 -94.32
MW2 99.93 ---7.06 -92.97 5.45 -94.58 3.70 -96.23 6.89 -93.04
MW3 99.68 ---4.89 -94.79 5.78 -93.90 3.82 -95.86 6.85 -92.83
MW4 100.25 ---9.40 -90.85 3.75 -96.50 2.96 -97.29 5.68 -94.57
MW5 99.49 ---------3.90 -95.59 6.23 -93.26
MW6 99.07 ---------3.48 -95.59 5.51 -93.56
MW7 98.77 ---------1.93 -96.84 6.20 -92.57
MW8 99.27 ---------3.15 -96.12 5.99 -93.28
Average Type II 7.74 6.30 4.92 3.37 6.20
Depth to Water Depth to Water Depth to Water Depth to Water Depth to Water
Top of Casing From Top of Free Product Groundwater From Top of Free Product Groundwater From Top of Free Product Groundwater From Top of Free Product Groundwater From Top of Free Product Groundwater
Elevation Casing Thickness Elevation Casing Thickness Elevation Casing Thickness Elevation Casing Thickness Elevation Casing Thickness Elevation
Well ID (feet)(feet)(feet)(feet)(feet)(feet)(feet)(feet)(feet)(feet)(feet)(feet)(feet)(feet)(feet)(feet)
MW1 100.35 4.43 -95.92
MW2 99.93 4.98 -94.93
MW3 99.68 4.93 -94.75
MW4 100.25 2.41 -97.84
MW5 99.49 5.51 -93.98
MW6 99.07 4.60 -94.47
MW7 98.77 4.61 -94.16
MW8 99.27 5.39 -93.88
MW9 99.68 4.34 -95.34
MW10 100.09 5.5 -94.59
Average Type II 4.59
Incident Name: J.D's Country Store Incident No. 29463
HISTORICAL GROUNDWATER ELEVATION DATA
62
1
0
D
/
6
2
0
0
B
62
1
0
D
/
6
2
0
0
B
62
1
0
D
/
6
2
0
0
B
62
1
0
D
/
6
2
0
0
B
62
1
0
D
/
6
2
0
0
B
62
1
0
D
/
6
2
0
0
B
62
1
0
D
/
6
2
0
0
B
62
1
0
D
/
6
2
0
0
B
62
1
0
D
/
6
2
0
0
B
62
1
0
D
/
6
2
0
0
B
62
1
0
D
/
6
2
0
0
B
62
1
0
D
/
6
2
0
0
B
62
1
0
D
/
6
2
0
0
B
62
0
0
B
62
0
0
B
62
1
0
D
/
6
2
0
0
B
62
1
0
D
/
6
2
0
0
B
62
1
0
D
/
6
2
0
0
B
62
0
0
B
62
0
0
B
MA
D
E
P

V
P
H
MA
D
E
P

V
P
H
MA
D
E
P

V
P
H
60
1
0
B

(
3
0
3
0
c
)
50
4
.
1
Well ID
5,500 49,000 2,200 14,500 700 <50.1,700 <50 480 50 280 <<180 <50 --66,000 19,000 <10,000 9.8 0.33
433 D 3,150 D 597 D 1,145 D 34.5 1.39 276 D <0.0900 86.4 D <0.352 <0.172 31.7 162 D <<77.9 D 5.22 <0.0920 -------
1,360 D 2,210 D 189 D 1,106 D 309 D 27.6 89 <42.8 <0.352 <0.172 3.4 15.5 <<8.21 0.67 0.340 J --2,830 1,690 D 1,470 D --
384 8 1,160 225 41.8 < 2.00 51.2 < 1.90 < 5.60 < 100 62.5 286 <<168 9.63 1,050 -1,710 1590 1440
484 9.31 1,990 950 35.7 3.29 399 <23.6 <<46.9 388 12.5 <183 <<1,210 -----
11,000 71,000 2,200 10,500 2,600 <1,000 1,800 <1,000 <1,000 <1,000 <5,000 <<<1,000 <1,000 --170,000 25,000 <25,000 5.5 <0.010
709 D 3,900 D 84.1 D 526 D 142 10.5 78.5 9.86 28 <0.352 <0.172 2.59 14.8 <<6.46 0.980 <0.0920 -------
445 D 2,490 D 617 D 2,051 D 45.3 2.01 467 D <141 D <0.352 <0.172 23.7 150 JD <<75 4.66 4.21 --1,820 291 474 --
11,900 113 3,110 3,380 3570 234 2800 < 19.0 56.9 < 1000 137 496 <<355 < 70.0 30,400 -36,200 6,860 19,200
7,130 608 1,030 1,880 3,710 201 998 <111 <<35.5 238 <<109 <<34,900 -----
2,400 690 360 1,790 2,700 100 84 180 <50 89 <250 <<120 <50 --16,000 4,200 <2,500 6.4 <0.010
10,000 D 1,870 D 1,580 D 4,055 D 7,870 D 95.2 D 1,260 D <0.0900 247 D <0.352 1.05 69.7 406 D <<127 D 10.3 6.57 -------
9,190 D 1,710 D 1,020 D 2,895 D 7,970 D 121 918 D <204 <1.76 <0.860 55.2 227 <<105 4.65 7.5 --9,770 2,040 D 2,480 D --
2,240 28 380 111 2190 37.4 39.2 < 3.80 23.7 < 200 22.1 128 <<46 < 14.0 2840 -5,960 400 562
2,470 353 452 280 2,710 46.8 72.3 <48.0 <<15.7 146 <<40.5 <<4,380 -----
13 11 6.6 9.8 3.3 <1 6.9 <1 6.3 4.2 <5 <<8.7 1.5 --200 150 <100 30 <0.010
0.510 <0.0570 <0.0920 <0.298 0.650 <0.0980 <0.103 <0.0900 <0.0870 <0.352 <0.172 <0.0980 <0.0940 <<<0.0650 <0.0890 <0.0920 -------
18.2 11.4 X 9.28 --
93.3 < 11.0 46.7
26.9 <<<<6.71 <<<------
789 D 483 D 71.4 294 D 1,280 38.9 71.7 <34.4 46.7 <0.172 11.2 15.4 <<21.8 4.18 1.91 --1,410 609 D 542 <3.30 <0.00606
2,190 14 53.9 155 1,450 79.7 < 16.4 < 3.80 < 11.2 < 200 49.8 156 <<108 < 14.0 3150 -5,540 < 55.0 910
1,600 < 18.0 99.0 140 1,590 73.0 42.4 <12.5 <<13.7 73.5 <<34.0 <<4,400 -----
124 D 23.6 5.26 31.8 394 D 11.9 8.13 <4.63 3.27 <0.172 1.74 2.08 <<2.75 <0.0890 0.270 J --402 39.5 74.8 <3.30 <0.00600
745 2.93 8.67 76.5 464 30.9 < 4.10 < 0.950 8.24 < 50.0 31.2 68.8 <<63.6 5.94 1170 -2,980 125 574
1,080 301 196 517 596 <217 <74.0 <<22.1 125 7.86 <60.8 <<2,090 3.27 -----
41 1.33 8.76 26.97 31.3 0.92 34.9 <15.6 <0.352 <0.172 1.05 6.11 <<1.97 0.420 J 0.370 J --105 98.8 118 4.20 J <0.00608
< 1.00 < 3.20 282 7 < 1.64 2.19 < 1.12 20.4 < 1.06 < 6.00 <<< 1.38 < 1.40 517 -363 18.6 77.5
4.48 < 0.900 0.715 < 1.60 116 2.88 <1.04 <<<<<<<<<<245 0.347 -----
0.260 J <0.0920 <0.298 <0.169 <0.0920 <0.103 <<0.0870 <0.352 0.67 <0.0980 0.540 J <<<0.0650 <0.0890 <0.0920 --<0.0150 <0.00500 <0.0150 <3.30 <0.00598
< 3.00 <<< 0.690 < 0.700 < 4.50 -< 26.0 < 11.0 < 7.00
13,000 28,100 2,270 13,100 9,590 189 1,510 <455 <<<<<<178 <<7,880 -123,000 27,600 14,200 0.519 <
7,500 30,200 749 3,310 11,900 253 485 852 <<<<<<<<<<48,400 -204,000 10,100 13,300 <0.932
1.03 J <0.172 <0.0980 <0.0940 <<<0.0650 <0.0890 <0.0920 -------
0.670 <0.0920 <0.103 <<0.0870 <0.352 <0.172 <0.0980 <0.0940 <<<0.0650 <0.0890 <0.0920 --<0.0150 <0.00500 <0.0150 --
0.440 J <0.0920 <0.298 0.560 <0.0980 <0.103 <0.0900 <0.0870 2.01 <0.172 <0.0980 <0.0940 <<<0.0650 <0.0890 <0.0920 -------
0.580 <0.0920 <0.103 <<0.0870 <0.352 <0.172 <0.0980 <0.0940 <<<0.0650 <0.0890 <0.0920 --<0.0150 <0.00500 <0.0150 --

APPENDIX E

0
UVF TRILOGY ANALYTICAL REPORT
Project Name: J.Ds Country Store
Project Number: 03107
Date: 5/31/2023
Standard Technical Procedures

The UVF TRILOGY instrument is a fixed-wavelength fluorometer but uses deep UV LEDS to detect
monoaromatic and polyaromatic hydrocarbons.
SITELAB’s CAL-025 GRO Module is used to detect volatile petroleum hydrocarbons in the C6 to C10 range.
This test matches well to EPA Methods for GRO, BTEX, BPH or VOC’s using GC/FID instrumentation.
SITELAB’s CAL-042 EDRO Module is used to detect petroleum hydrocarbons in the C10 to C36 diesel and
oil range. This test matches well to EPA methods for TPH, EPH, DRO, and others using GC-FID
instrumentation.
Prior to field usage, the UVF TRILOGY is calibrated with five calibration standard solutions per targeted
analyte.
Soil samples are weighed to the nearest gram (i.e. 5.0 g) and added to a 1-ounce HDPE Nalgene bottle
with a measured amount of laboratory grade methanol to the nearest mL (i.e. 10 mL) to create a sample
extract. After addition of both the soil and methanol, the bottle is agitated for several minutes. Next, the
sample rests for several minutes allowing for the soil and methanol extract to separate.
After ample resting time, the methanol extract is collected with a syringe. A filter is connected to the end
of the syringe and dispensed into a clean sample test tube. The test tube is labeled with sample ID and
extract dilution factor (i.e. 2X).
Known amounts of extract are pipetted into a second test tube and diluted with methanol. The sample
ID and dilution factor are labeled on the test tube (i.e. 100X).
Samples are placed into a clean cuvette and carefully inserted into the selected UV Module. Prior to
analyzing the sample, the stored calibration that matches the UV Module being used, is selected. The
UVF TRILOGY produces a result that when multiplied to the dilution factor equals the true TPH value.
Quenching occurs when the detector is swamped by too many or certain type of hydrocarbons, producing
low or negative concentrations. The sample is tested at multiple dilutions to confirm the results are linear
and accurate.
Solvent blank samples are periodically analyzed to confirm the solvent is clean and the calibration of the
machine is maintained.

Project Name J.D's Country Store
Project Number 03107
Method UVF Trilogy
Sample Name Sample Depth Sample Date Analyte Name Dilution Result MDL Units
SB1 13-15 5/16/2023 DRO 2 .78 0.2 mg/kg
SB1 13-15 5/16/2023 GRO 2 1.84 1 mg/kg
SB1 3-5 5/16/2023 DRO 2 9.46 0.2 mg/kg
SB1 3-5 5/16/2023 GRO 400 764 200 mg/kg
SB1 5-7 5/16/2023 DRO 100 86 10 mg/kg
SB1 5-7 5/16/2023 GRO 100 499 50 mg/kg
SB1 8-10 5/16/2023 DRO 100 86 0.1 mg/kg
SB1 8-10 5/16/2023 GRO 100 355 50 mg/kg
Wednesday, May 31, 2023 Page 1 of 6
Project Name J.D's Country Store
Project Number 03107
Method UVF Trilogy
Sample Name Sample Depth Sample Date Analyte Name Dilution Result MDL Units
SB2 13-15 5/16/2023 DRO 2 2.1 0.2 mg/kg
SB2 13-15 5/16/2023 GRO 2 2.9 2 mg/kg
SB2 3-5 5/16/2023 DRO 100 91 10 mg/kg
SB2 3-5 5/16/2023 GRO 100 802 50 mg/kg
SB2 5-7 5/16/2023 DRO 100 32 10 mg/kg
SB2 5-7 5/16/2023 GRO 100 304 50 mg/kg
SB2 8-10 5/16/2023 DRO 100 193 10 mg/kg
SB2 8-10 5/16/2023 GRO 100 580 50 mg/kg
Wednesday, May 31, 2023 Page 2 of 6
Project Name J.D's Country Store
Project Number 03107
Method UVF Trilogy
Sample Name Sample Depth Sample Date Analyte Name Dilution Result MDL Units
SB3 13-15 5/16/2023 DRO 2 .58 0.2 mg/kg
SB3 13-15 5/16/2023 GRO 2 1.36 1 mg/kg
SB3 3-5 5/16/2023 DRO 100 106 10 mg/kg
SB3 3-5 5/16/2023 GRO 100 957 50 mg/kg
SB3 5-7 5/16/2023 DRO 100 7.32 10 mg/kg
SB3 5-7 5/16/2023 GRO 100 13.88 50 mg/kg
SB3 8-10 5/16/2023 DRO 100 201 10 mg/kg
SB3 8-10 5/16/2023 GRO 100 563 50 mg/kg
Wednesday, May 31, 2023 Page 3 of 6
Project Name J.D's Country Store
Project Number 03107
Method UVF Trilogy
Sample Name Sample Depth Sample Date Analyte Name Dilution Result MDL Units
SB4 13-15 5/16/2023 DRO 2 .72 0.2 mg/kg
SB4 13-15 5/16/2023 GRO 2 3.2 1 mg/kg
SB4 3-5 5/16/2023 DRO 2 .80 0.2 mg/kg
SB4 3-5 5/16/2023 GRO 2 1.86 1 mg/kg
SB4 5-7 5/16/2023 DRO 100 195 10 mg/kg
SB4 5-7 5/16/2023 GRO 400 804 200 mg/kg
SB4 8-10 5/16/2023 DRO 2 2.44 0.2 mg/kg
SB4 8-10 5/16/2023 GRO 2 9.3 1 mg/kg
Wednesday, May 31, 2023 Page 4 of 6
Project Name J.D's Country Store
Project Number 03107
Method UVF Trilogy
Sample Name Sample Depth Sample Date Analyte Name Dilution Result MDL Units
MW9 8-10 5/16/2023 DRO 100 17 10 mg/kg
MW9 8-10 5/16/2023 GRO 100 269 50 mg/kg
Wednesday, May 31, 2023 Page 5 of 6
UVF Analytical Report
Project Name J.D's Country Store
Project Number 03107
Method UVF Trilogy
Sample Name Sample Depth Sample Date Analyte Name Dilution Result MDL Units
MW10 8-10 5/16/2023 DRO 2 4.42 0.2 mg/kg
MW10 8-10 5/16/2023 GRO 2 7.12 1 mg/kg
Wednesday, May 31, 2023 Page 6 of 6
ANALYTICAL REPORT
PREPARED FOR
Attn: Ryan Kerins
Terraquest Environmental Consultants, PC
100 E. Ruffin Street
Mebane, North Carolina 27302
Generated 6/5/2023 2:45:00 PM
JOB DESCRIPTION
JD's Country Store
JOB NUMBER
400-237880-1
See page two for job notes and contact information.
Pensacola FL 32514
3355 McLemore Drive
Eurofins Pensacola
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Eurofins Pensacola
Eurofins Pensacola is a laboratory within Eurofins Environment Testing Southeast, LLC, a company within Eurofins Environment Testing Group of Companies
Job Notes
This report may not be reproduced except in full, and with written approval from the laboratory. The results relate only to the
samples tested. For questions please contact the Project Manager at the e-mail address or telephone number listed on this
page.
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the
methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written
approval of the laboratory. All questions should be directed to the Eurofins Environment Testing Southeast, LLC Project
Manager.
Authorization
Generated
6/5/2023 2:45:00 PM
Authorized for release by
Chad Bechtold, Project Manager
[e-mail]
[phone]
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Table of Contents
Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Laboratory Job ID: 400-237880-1
Page 3 of 58 Eurofins Pensacola6/5/2023
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4
Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .8
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .9
Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .29
Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .30
QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .32
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .34
Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .50
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .55
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .56
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .57
Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .58
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Case Narrative
Client: Terraquest Environmental Consultants, PC Job ID: 400-237880-1
Project/Site: JD's Country Store
Job ID: 400-237880-1
Laboratory: Eurofins Pensacola
Narrative
Job Narrative
400-237880-1
Receipt
The samples were received on 5/18/2023 8:26 AM. Unless otherwise noted below, the samples arrived in good condition, and, where
required, properly preserved and on ice. The temperature of the cooler at receipt time was 4.1°C
GC/MS VOA
Method SM6200_B: The following sample was diluted to bring the concentration of target analytes within the calibration range: MW1
(400-237880-1). Elevated reporting limits (RLs) are provided.
Method SM6200_B: The laboratory control sample (LCS) for analytical batch 400-626874 recovered outside control limits for the following
analytes: 2-Hexanone, Vinyl chloride, Ethanol, Chloromethane and 3,3-Dimethyl-1-butanol. These analytes were biased high in the LCS
and were not detected in the associated samples; therefore, the data have been reported.
Method SM6200_B: The laboratory control sample (LCS) for analytical batch 400-626908 recovered outside control limits for the following
analytes: Bromomethane and Trichlorofluoromethane. These analytes were biased high in the LCS and were not detected in the
associated samples; therefore, the data have been reported.
Method SM6200_B: The following samples were diluted to bring the concentration of target analytes within the calibration range: MW5
(400-237880-5), MW6 (400-237880-6) and MW9 (400-237880-9). Elevated reporting limits (RLs) are provided.
Method SM6200_B: The following sample was diluted to bring the concentration of target analytes within the calibration range: MW3
(400-237880-3). Elevated reporting limits (RLs) are provided.
Method SM6200_B: The following sample was diluted to bring the concentration of target analytes within the calibration range: MW2
(400-237880-2). Elevated reporting limits (RLs) are provided.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/ Glossary page.
Hydrocarbons
Method MAVPH: The following sample was diluted to bring the concentration of target analytes within the calibration range: MW10
(400-237880-10). Elevated reporting limits (RLs) are provided.
Method MAVPH: The following sample was diluted to bring the concentration of target analytes within the calibration range: MW9
(400-237880-9). Elevated reporting limits (RLs) are provided.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/ Glossary page.
GC Semi VOA
Method 504.1: The continuing calibration verification (CCV) associated with batch 400-625961 recovered above the upper control limit for
1,2-Dibromoethane (EDB). The samples associated with this CCV were non-detects for the affected analytes; therefore, the data have
been reported.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/ Glossary page.
Metals
No additional analytical or quality issues were noted, other than those described above or in the Definitions/ Glossary page.
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Detection Summary
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Client Sample ID: MW1 Lab Sample ID: 400-237880-1
1,2,4-Trimethylbenzene
RL
10.0 ug/L
MDL
8.20
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA10399SM6200-B
1,3,5-Trimethylbenzene 10.0 ug/L5.60 Total/NA1023.6 SM6200-B
Benzene 10.0 ug/L5.00 Total/NA10484SM6200-B
Diisopropyl ether 10.0 ug/L2.00 Total/NA103.29 J SM6200-B
Ethylbenzene 10.0 ug/L5.00 Total/NA101990SM6200-B
Isopropylbenzene 10.0 ug/L5.30 Total/NA1046.9 SM6200-B
Methyl tert-butyl ether 10.0 ug/L2.20 Total/NA1035.7 SM6200-B
m-Xylene & p-Xylene 50.0 ug/L6.30 Total/NA10945SM6200-B
Naphthalene 50.0 ug/L30.0 Total/NA10388SM6200-B
n-Butylbenzene 10.0 ug/L7.60 Total/NA1012.5 SM6200-B
N-Propylbenzene 10.0 ug/L6.90 Total/NA10183SM6200-B
t-Amyl alcohol 100 ug/L45.0 Total/NA101210SM6200-B
Toluene 10.0 ug/L9.00 Total/NA109.31 J SM6200-B
Xylenes, Total 100 ug/L16.0 Total/NA10950SM6200-B
Client Sample ID: MW2 Lab Sample ID: 400-237880-2
1,2,4-Trimethylbenzene
RL
50.0 ug/L
MDL
41.0
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA50998SM6200-B
1,3,5-Trimethylbenzene 50.0 ug/L28.0 Total/NA50111SM6200-B
Benzene 50.0 ug/L25.0 Total/NA507130SM6200-B
Diisopropyl ether 50.0 ug/L10.0 Total/NA50201SM6200-B
Ethylbenzene 50.0 ug/L25.0 Total/NA501030SM6200-B
Isopropylbenzene 50.0 ug/L26.5 Total/NA5035.5 J SM6200-B
Methyl tert-butyl ether 50.0 ug/L11.0 Total/NA503710SM6200-B
m-Xylene & p-Xylene 250 ug/L31.5 Total/NA501790SM6200-B
Naphthalene 250 ug/L150 Total/NA50238JSM6200-B
N-Propylbenzene 50.0 ug/L34.5 Total/NA50109SM6200-B
o-Xylene 250 ug/L30.0 Total/NA5090.4 J SM6200-B
t-Amyl alcohol 500 ug/L225 Total/NA5034900SM6200-B
Toluene 50.0 ug/L45.0 Total/NA50608SM6200-B
Xylenes, Total 500 ug/L80.0 Total/NA501880SM6200-B
Client Sample ID: MW3 Lab Sample ID: 400-237880-3
1,2,4-Trimethylbenzene
RL
20.0 ug/L
MDL
16.4
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA2072.3 SM6200-B
1,3,5-Trimethylbenzene 20.0 ug/L11.2 Total/NA2048.0 SM6200-B
Benzene 20.0 ug/L10.0 Total/NA202470SM6200-B
Diisopropyl ether 20.0 ug/L4.00 Total/NA2046.8 SM6200-B
Ethylbenzene 20.0 ug/L10.0 Total/NA20452SM6200-B
Isopropylbenzene 20.0 ug/L10.6 Total/NA2015.7 J SM6200-B
Methyl tert-butyl ether 20.0 ug/L4.40 Total/NA202710SM6200-B
m-Xylene & p-Xylene 100 ug/L12.6 Total/NA20183SM6200-B
Naphthalene 100 ug/L60.0 Total/NA20146SM6200-B
N-Propylbenzene 20.0 ug/L13.8 Total/NA2040.5 SM6200-B
o-Xylene 100 ug/L12.0 Total/NA2096.0 J SM6200-B
t-Amyl alcohol 200 ug/L90.0 Total/NA204380SM6200-B
Toluene 20.0 ug/L18.0 Total/NA20353SM6200-B
Xylenes, Total 200 ug/L32.0 Total/NA20280SM6200-B
Eurofins Pensacola
This Detection Summary does not include radiochemical test results.
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Detection Summary
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Client Sample ID: MW4 Lab Sample ID: 400-237880-4
2-Butanone (MEK)
RL
25.0 ug/L
MDL
2.60
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1J6.71 SM6200-B
Acetone 25.0 ug/L10.0 Total/NA126.9 SM6200-B
Client Sample ID: MW5 Lab Sample ID: 400-237880-5
1,2,4-Trimethylbenzene
RL
20.0 ug/L
MDL
16.4
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA2042.4 SM6200-B
1,3,5-Trimethylbenzene 20.0 ug/L11.2 Total/NA2012.5 J SM6200-B
Benzene 20.0 ug/L10.0 Total/NA201600SM6200-B
Diisopropyl ether 20.0 ug/L4.00 Total/NA2073.0 SM6200-B
Ethylbenzene 20.0 ug/L10.0 Total/NA2099.0 SM6200-B
Isopropylbenzene 20.0 ug/L10.6 Total/NA2013.7 J SM6200-B
Methyl tert-butyl ether 20.0 ug/L4.40 Total/NA201590SM6200-B
m-Xylene & p-Xylene 100 ug/L12.6 Total/NA20134SM6200-B
Naphthalene 100 ug/L60.0 Total/NA2073.5 J SM6200-B
N-Propylbenzene 20.0 ug/L13.8 Total/NA2034.0 SM6200-B
t-Amyl alcohol 200 ug/L90.0 Total/NA204400SM6200-B
Xylenes, Total 200 ug/L32.0 Total/NA20140JSM6200-B
Client Sample ID: MW6 Lab Sample ID: 400-237880-6
1,2,4-Trimethylbenzene
RL
10.0 ug/L
MDL
8.20
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA10217SM6200-B
1,3,5-Trimethylbenzene 10.0 ug/L5.60 Total/NA1074.0 SM6200-B
Benzene 10.0 ug/L5.00 Total/NA101080SM6200-B
Diisopropyl ether 10.0 ug/L2.00 Total/NA1034.3 SM6200-B
Ethylbenzene 10.0 ug/L5.00 Total/NA10196SM6200-B
Isopropylbenzene 10.0 ug/L5.30 Total/NA1022.1 SM6200-B
Methyl tert-butyl ether 10.0 ug/L2.20 Total/NA10596SM6200-B
m-Xylene & p-Xylene 50.0 ug/L6.30 Total/NA10451SM6200-B
Naphthalene 50.0 ug/L30.0 Total/NA10125SM6200-B
n-Butylbenzene 10.0 ug/L7.60 Total/NA107.86 J SM6200-B
N-Propylbenzene 10.0 ug/L6.90 Total/NA1060.8 SM6200-B
o-Xylene 50.0 ug/L6.00 Total/NA1066.4 SM6200-B
t-Amyl alcohol 100 ug/L45.0 Total/NA102090SM6200-B
Tert-amyl methyl ether 10.0 ug/L2.30 Total/NA103.27 J SM6200-B
Toluene 10.0 ug/L9.00 Total/NA10301SM6200-B
Xylenes, Total 100 ug/L16.0 Total/NA10517SM6200-B
Client Sample ID: MW7 Lab Sample ID: 400-237880-7
1,2-Dichloroethane
RL
1.00 ug/L
MDL
0.190
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA11.04 SM6200-B
Benzene 1.00 ug/L0.500 Total/NA14.48 SM6200-B
Diisopropyl ether 1.00 ug/L0.200 Total/NA12.88 SM6200-B
Ethylbenzene 1.00 ug/L0.500 Total/NA10.715 J SM6200-B
Methyl tert-butyl ether 1.00 ug/L0.220 Total/NA1116SM6200-B
t-Amyl alcohol 10.0 ug/L4.50 Total/NA1245SM6200-B
Tert-amyl methyl ether 1.00 ug/L0.230 Total/NA10.347 J SM6200-B
Client Sample ID: MW8 Lab Sample ID: 400-237880-8
No Detections.
Eurofins Pensacola
This Detection Summary does not include radiochemical test results.
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Detection Summary
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Client Sample ID: MW9 Lab Sample ID: 400-237880-9
1,2,4-Trimethylbenzene
RL
200 ug/L
MDL
164
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA2001510SM6200-B
1,3,5-Trimethylbenzene 200 ug/L112 Total/NA200455SM6200-B
Benzene 200 ug/L100 Total/NA20013000SM6200-B
Diisopropyl ether 200 ug/L40.0 Total/NA200189JSM6200-B
Ethylbenzene 200 ug/L100 Total/NA2002270SM6200-B
Methyl tert-butyl ether 200 ug/L44.0 Total/NA2009590SM6200-B
m-Xylene & p-Xylene 1000 ug/L126 Total/NA2009090SM6200-B
N-Propylbenzene 200 ug/L138 Total/NA200178JSM6200-B
o-Xylene 1000 ug/L120 Total/NA2003970SM6200-B
t-Amyl alcohol 2000 ug/L900 Total/NA2007880SM6200-B
Toluene 200 ug/L180 Total/NA20028100SM6200-B
Xylenes, Total 2000 ug/L320 Total/NA20013100SM6200-B
C5-C8 Aliphatics 5200 ug/L5200 Total/NA200123000MAVPH
C9-C12 Aliphatics 2200 ug/L2200 Total/NA20027600MAVPH
C9-C10 Aromatics 1400 ug/L1400 Total/NA20014200MAVPH
Lead 0.0100 mg/L0.00200 Total/NA10.519 6010D
Client Sample ID: MW10 Lab Sample ID: 400-237880-10
1,2,4-Trimethylbenzene
RL
500 ug/L
MDL
410
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA500J485SM6200-B
1,2-Dichloroethane 500 ug/L95.0 Total/NA500852SM6200-B
Benzene 500 ug/L250 Total/NA5007500SM6200-B
Diisopropyl ether 500 ug/L100 Total/NA500253JSM6200-B
Ethylbenzene 500 ug/L250 Total/NA500749SM6200-B
Methyl tert-butyl ether 500 ug/L110 Total/NA50011900SM6200-B
m-Xylene & p-Xylene 2500 ug/L315 Total/NA5002020JSM6200-B
o-Xylene 2500 ug/L300 Total/NA5001300JSM6200-B
t-Amyl alcohol 5000 ug/L2250 Total/NA50048400SM6200-B
Toluene 500 ug/L450 Total/NA50030200SM6200-B
Xylenes, Total 5000 ug/L800 Total/NA5003310JSM6200-B
C5-C8 Aliphatics 13000 ug/L13000 Total/NA500204000MAVPH
C9-C12 Aliphatics 5500 ug/L5500 Total/NA50010100MAVPH
C9-C10 Aromatics 3500 ug/L3500 Total/NA50013300MAVPH
1,2-Dibromoethane (EDB)0.0190 ug/L0.0143 Total/NA10.932 504.1
Eurofins Pensacola
This Detection Summary does not include radiochemical test results.
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Sample Summary
Client: Terraquest Environmental Consultants, PC Job ID: 400-237880-1
Project/Site: JD's Country Store
Lab Sample ID Client Sample ID Matrix Collected Received
400-237880-1 MW1 Water 05/17/23 10:37 05/18/23 08:26
400-237880-2 MW2 Water 05/17/23 10:42 05/18/23 08:26
400-237880-3 MW3 Water 05/17/23 10:55 05/18/23 08:26
400-237880-4 MW4 Water 05/17/23 10:50 05/18/23 08:26
400-237880-5 MW5 Water 05/17/23 11:00 05/18/23 08:26
400-237880-6 MW6 Water 05/17/23 11:07 05/18/23 08:26
400-237880-7 MW7 Water 05/17/23 11:15 05/18/23 08:26
400-237880-8 MW8 Water 05/17/23 11:21 05/18/23 08:26
400-237880-9 MW9 Water 05/17/23 11:27 05/18/23 08:26
400-237880-10 MW10 Water 05/17/23 11:33 05/18/23 08:26
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Client Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Lab Sample ID: 400-237880-1Client Sample ID: MW1
Matrix: WaterDate Collected: 05/17/23 10:37
Date Received: 05/18/23 08:26
Method: SM6200-B - Volatile Organic Compounds
RL MDL
1.60 U 10.0 1.60 ug/L 05/28/23 20:33 10
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1,2-Tetrachloroethane
10.0 1.80 ug/L 05/28/23 20:33 101.80 U1,1,1-Trichloroethane
10.0 5.00 ug/L 05/28/23 20:33 105.00 U1,1,2,2-Tetrachloroethane
50.0 2.10 ug/L 05/28/23 20:33 102.10 U1,1,2-Trichloroethane
10.0 5.00 ug/L 05/28/23 20:33 105.00 U1,1-Dichloroethane
10.0 5.00 ug/L 05/28/23 20:33 105.00 U1,1-Dichloroethene
10.0 5.00 ug/L 05/28/23 20:33 105.00 U1,1-Dichloropropene
10.0 9.00 ug/L 05/28/23 20:33 109.00 U1,2,3-Trichlorobenzene
50.0 8.40 ug/L 05/28/23 20:33 108.40 U1,2,3-Trichloropropane
10.0 8.20 ug/L 05/28/23 20:33 108.20 U1,2,4-Trichlorobenzene
10.0 8.20 ug/L 05/28/23 20:33 103991,2,4-Trimethylbenzene
10.0 2.30 ug/L 05/28/23 20:33 102.30 U1,2-Dibromoethane (EDB)
10.0 5.00 ug/L 05/28/23 20:33 105.00 U1,2-Dichlorobenzene
10.0 1.90 ug/L 05/28/23 20:33 101.90 U1,2-Dichloroethane
10.0 5.00 ug/L 05/28/23 20:33 105.00 U1,2-Dichloropropane
10.0 5.60 ug/L 05/28/23 20:33 1023.61,3,5-Trimethylbenzene
10.0 5.40 ug/L 05/28/23 20:33 105.40 U1,3-Dichlorobenzene
10.0 5.00 ug/L 05/28/23 20:33 105.00 U1,3-Dichloropropane
10.0 6.40 ug/L 05/28/23 20:33 106.40 U1,4-Dichlorobenzene
10.0 5.00 ug/L 05/28/23 20:33 105.00 U2,2-Dichloropropane
250 26.0 ug/L 05/28/23 20:33 1026.0 U2-Butanone (MEK)
10.0 5.70 ug/L 05/28/23 20:33 105.70 U2-Chlorotoluene
250 14.0 ug/L 05/28/23 20:33 1014.0 U *+2-Hexanone
200 120 ug/L 05/28/23 20:33 10120U *+3,3-Dimethyl-1-butanol
10.0 5.60 ug/L 05/28/23 20:33 105.60 U4-Chlorotoluene
250 18.0 ug/L 05/28/23 20:33 1018.0 U4-Methyl-2-pentanone (MIBK)
250 100 ug/L 05/28/23 20:33 10100UAcetone
10.0 5.00 ug/L 05/28/23 20:33 10484Benzene
10.0 5.40 ug/L 05/28/23 20:33 105.40 UBromobenzene
10.0 2.10 ug/L 05/28/23 20:33 102.10 UBromochloromethane
10.0 5.00 ug/L 05/28/23 20:33 105.00 UBromodichloromethane
50.0 2.50 ug/L 05/28/23 20:33 102.50 UBromoform
10.0 9.80 ug/L 05/28/23 20:33 109.80 UBromomethane
10.0 1.90 ug/L 05/28/23 20:33 101.90 UCarbon tetrachloride
10.0 1.50 ug/L 05/28/23 20:33 101.50 UChlorobenzene
10.0 7.60 ug/L 05/28/23 20:33 107.60 UChloroethane
10.0 9.00 ug/L 05/28/23 20:33 109.00 UChloroform
10.0 9.00 ug/L 05/28/23 20:33 109.00 U *+Chloromethane
10.0 2.00 ug/L 05/28/23 20:33 102.00 Ucis-1,2-Dichloroethene
50.0 5.00 ug/L 05/28/23 20:33 105.00 Ucis-1,3-Dichloropropene
10.0 2.40 ug/L 05/28/23 20:33 102.40 UDibromochloromethane
10.0 8.50 ug/L 05/28/23 20:33 108.50 UDichlorodifluoromethane
10.0 2.00 ug/L 05/28/23 20:33 103.29 JDiisopropyl ether
1000 240 ug/L 05/28/23 20:33 10240U *+Ethanol
10.0 2.80 ug/L 05/28/23 20:33 102.80 UEthyl tert-butyl ether
10.0 5.00 ug/L 05/28/23 20:33 101990Ethylbenzene
10.0 5.30 ug/L 05/28/23 20:33 1046.9Isopropylbenzene
10.0 2.20 ug/L 05/28/23 20:33 1035.7Methyl tert-butyl ether
50.0 30.0 ug/L 05/28/23 20:33 1030.0 UMethylene Chloride
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Client Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Lab Sample ID: 400-237880-1Client Sample ID: MW1
Matrix: WaterDate Collected: 05/17/23 10:37
Date Received: 05/18/23 08:26
Method: SM6200-B - Volatile Organic Compounds (Continued)
RL MDL
945 50.0 6.30 ug/L 05/28/23 20:33 10
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
m-Xylene & p-Xylene
50.0 30.0 ug/L 05/28/23 20:33 10388Naphthalene
10.0 7.60 ug/L 05/28/23 20:33 1012.5n-Butylbenzene
10.0 6.90 ug/L 05/28/23 20:33 10183N-Propylbenzene
50.0 6.00 ug/L 05/28/23 20:33 106.00 Uo-Xylene
10.0 7.10 ug/L 05/28/23 20:33 107.10 Up-Cymene (p-Isopropyltoluene)
10.0 7.00 ug/L 05/28/23 20:33 107.00 Usec-Butylbenzene
10.0 10.0 ug/L 05/28/23 20:33 1010.0 UStyrene
100 45.0 ug/L 05/28/23 20:33 101210t-Amyl alcohol
10.0 2.30 ug/L 05/28/23 20:33 102.30 UTert-amyl methyl ether
100 24.0 ug/L 05/28/23 20:33 1024.0 Utert-Butyl Formate
10.0 6.30 ug/L 05/28/23 20:33 106.30 Utert-Butylbenzene
10.0 9.00 ug/L 05/28/23 20:33 109.00 UTetrachloroethene
10.0 9.00 ug/L 05/28/23 20:33 109.31 JToluene
10.0 5.00 ug/L 05/28/23 20:33 105.00 Utrans-1,2-Dichloroethene
50.0 2.00 ug/L 05/28/23 20:33 102.00 Utrans-1,3-Dichloropropene
10.0 1.50 ug/L 05/28/23 20:33 101.50 UTrichloroethene
10.0 5.20 ug/L 05/28/23 20:33 105.20 UTrichlorofluoromethane
250 9.30 ug/L 05/28/23 20:33 109.30 UVinyl acetate
10.0 5.00 ug/L 05/28/23 20:33 105.00 U *+Vinyl chloride
100 16.0 ug/L 05/28/23 20:33 10950Xylenes, Total
4-Bromofluorobenzene 99 72-130 05/28/23 20:33 10
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane 109 05/28/23 20:33 1075-126
Toluene-d8 (Surr)120 05/28/23 20:33 1064-132
Eurofins Pensacola
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Client Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Lab Sample ID: 400-237880-2Client Sample ID: MW2
Matrix: WaterDate Collected: 05/17/23 10:42
Date Received: 05/18/23 08:26
Method: SM6200-B - Volatile Organic Compounds
RL MDL
8.00 U 50.0 8.00 ug/L 05/31/23 19:37 50
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1,2-Tetrachloroethane
50.0 9.00 ug/L 05/31/23 19:37 509.00 U1,1,1-Trichloroethane
50.0 25.0 ug/L 05/31/23 19:37 5025.0 U1,1,2,2-Tetrachloroethane
250 10.5 ug/L 05/31/23 19:37 5010.5 U1,1,2-Trichloroethane
50.0 25.0 ug/L 05/31/23 19:37 5025.0 U1,1-Dichloroethane
50.0 25.0 ug/L 05/31/23 19:37 5025.0 U1,1-Dichloroethene
50.0 25.0 ug/L 05/31/23 19:37 5025.0 U1,1-Dichloropropene
50.0 45.0 ug/L 05/31/23 19:37 5045.0 U1,2,3-Trichlorobenzene
250 42.0 ug/L 05/31/23 19:37 5042.0 U1,2,3-Trichloropropane
50.0 41.0 ug/L 05/31/23 19:37 5041.0 U1,2,4-Trichlorobenzene
50.0 41.0 ug/L 05/31/23 19:37 509981,2,4-Trimethylbenzene
50.0 11.5 ug/L 05/31/23 19:37 5011.5 U1,2-Dibromoethane (EDB)
50.0 25.0 ug/L 05/31/23 19:37 5025.0 U1,2-Dichlorobenzene
50.0 9.50 ug/L 05/31/23 19:37 509.50 U1,2-Dichloroethane
50.0 25.0 ug/L 05/31/23 19:37 5025.0 U1,2-Dichloropropane
50.0 28.0 ug/L 05/31/23 19:37 501111,3,5-Trimethylbenzene
50.0 27.0 ug/L 05/31/23 19:37 5027.0 U1,3-Dichlorobenzene
50.0 25.0 ug/L 05/31/23 19:37 5025.0 U1,3-Dichloropropane
50.0 32.0 ug/L 05/31/23 19:37 5032.0 U1,4-Dichlorobenzene
50.0 25.0 ug/L 05/31/23 19:37 5025.0 U2,2-Dichloropropane
1250 130 ug/L 05/31/23 19:37 50130U2-Butanone (MEK)
50.0 28.5 ug/L 05/31/23 19:37 5028.5 U2-Chlorotoluene
1250 70.0 ug/L 05/31/23 19:37 5070.0 U2-Hexanone
1000 600 ug/L 05/31/23 19:37 50600U3,3-Dimethyl-1-butanol
50.0 28.0 ug/L 05/31/23 19:37 5028.0 U4-Chlorotoluene
1250 90.0 ug/L 05/31/23 19:37 5090.0 U4-Methyl-2-pentanone (MIBK)
1250 500 ug/L 05/31/23 19:37 50500UAcetone
50.0 25.0 ug/L 05/31/23 19:37 507130Benzene
50.0 27.0 ug/L 05/31/23 19:37 5027.0 UBromobenzene
50.0 10.5 ug/L 05/31/23 19:37 5010.5 UBromochloromethane
50.0 25.0 ug/L 05/31/23 19:37 5025.0 UBromodichloromethane
250 12.5 ug/L 05/31/23 19:37 5012.5 UBromoform
50.0 49.0 ug/L 05/31/23 19:37 5049.0 UBromomethane
50.0 9.50 ug/L 05/31/23 19:37 509.50 UCarbon tetrachloride
50.0 7.50 ug/L 05/31/23 19:37 507.50 UChlorobenzene
50.0 38.0 ug/L 05/31/23 19:37 5038.0 UChloroethane
50.0 45.0 ug/L 05/31/23 19:37 5045.0 UChloroform
50.0 45.0 ug/L 05/31/23 19:37 5045.0 UChloromethane
50.0 10.0 ug/L 05/31/23 19:37 5010.0 Ucis-1,2-Dichloroethene
250 25.0 ug/L 05/31/23 19:37 5025.0 Ucis-1,3-Dichloropropene
50.0 12.0 ug/L 05/31/23 19:37 5012.0 UDibromochloromethane
50.0 42.5 ug/L 05/31/23 19:37 5042.5 UDichlorodifluoromethane
50.0 10.0 ug/L 05/31/23 19:37 50201Diisopropyl ether
5000 1200 ug/L 05/31/23 19:37 501200UEthanol
50.0 14.0 ug/L 05/31/23 19:37 5014.0 UEthyl tert-butyl ether
50.0 25.0 ug/L 05/31/23 19:37 501030Ethylbenzene
50.0 26.5 ug/L 05/31/23 19:37 5035.5 JIsopropylbenzene
50.0 11.0 ug/L 05/31/23 19:37 503710Methyl tert-butyl ether
250 150 ug/L 05/31/23 19:37 50150UMethylene Chloride
Eurofins Pensacola
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Client Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Lab Sample ID: 400-237880-2Client Sample ID: MW2
Matrix: WaterDate Collected: 05/17/23 10:42
Date Received: 05/18/23 08:26
Method: SM6200-B - Volatile Organic Compounds (Continued)
RL MDL
1790 250 31.5 ug/L 05/31/23 19:37 50
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
m-Xylene & p-Xylene
250 150 ug/L 05/31/23 19:37 50238JNaphthalene
50.0 38.0 ug/L 05/31/23 19:37 5038.0 Un-Butylbenzene
50.0 34.5 ug/L 05/31/23 19:37 50109N-Propylbenzene
250 30.0 ug/L 05/31/23 19:37 5090.4 Jo-Xylene
50.0 35.5 ug/L 05/31/23 19:37 5035.5 Up-Cymene (p-Isopropyltoluene)
50.0 35.0 ug/L 05/31/23 19:37 5035.0 Usec-Butylbenzene
50.0 50.0 ug/L 05/31/23 19:37 5050.0 UStyrene
500 225 ug/L 05/31/23 19:37 5034900t-Amyl alcohol
50.0 11.5 ug/L 05/31/23 19:37 5011.5 UTert-amyl methyl ether
500 120 ug/L 05/31/23 19:37 50120Utert-Butyl Formate
50.0 31.5 ug/L 05/31/23 19:37 5031.5 Utert-Butylbenzene
50.0 45.0 ug/L 05/31/23 19:37 5045.0 UTetrachloroethene
50.0 45.0 ug/L 05/31/23 19:37 50608Toluene
50.0 25.0 ug/L 05/31/23 19:37 5025.0 Utrans-1,2-Dichloroethene
250 10.0 ug/L 05/31/23 19:37 5010.0 Utrans-1,3-Dichloropropene
50.0 7.50 ug/L 05/31/23 19:37 507.50 UTrichloroethene
50.0 26.0 ug/L 05/31/23 19:37 5026.0 UTrichlorofluoromethane
1250 46.5 ug/L 05/31/23 19:37 5046.5 UVinyl acetate
50.0 25.0 ug/L 05/31/23 19:37 5025.0 UVinyl chloride
500 80.0 ug/L 05/31/23 19:37 501880Xylenes, Total
4-Bromofluorobenzene 99 72-130 05/31/23 19:37 50
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane 101 05/31/23 19:37 5075-126
Toluene-d8 (Surr)97 05/31/23 19:37 5064-132
Eurofins Pensacola
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Client Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Lab Sample ID: 400-237880-3Client Sample ID: MW3
Matrix: WaterDate Collected: 05/17/23 10:55
Date Received: 05/18/23 08:26
Method: SM6200-B - Volatile Organic Compounds
RL MDL
3.20 U 20.0 3.20 ug/L 05/31/23 13:00 20
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1,2-Tetrachloroethane
20.0 3.60 ug/L 05/31/23 13:00 203.60 U1,1,1-Trichloroethane
20.0 10.0 ug/L 05/31/23 13:00 2010.0 U1,1,2,2-Tetrachloroethane
100 4.20 ug/L 05/31/23 13:00 204.20 U1,1,2-Trichloroethane
20.0 10.0 ug/L 05/31/23 13:00 2010.0 U1,1-Dichloroethane
20.0 10.0 ug/L 05/31/23 13:00 2010.0 U1,1-Dichloroethene
20.0 10.0 ug/L 05/31/23 13:00 2010.0 U1,1-Dichloropropene
20.0 18.0 ug/L 05/31/23 13:00 2018.0 U1,2,3-Trichlorobenzene
100 16.8 ug/L 05/31/23 13:00 2016.8 U1,2,3-Trichloropropane
20.0 16.4 ug/L 05/31/23 13:00 2016.4 U1,2,4-Trichlorobenzene
20.0 16.4 ug/L 05/31/23 13:00 2072.31,2,4-Trimethylbenzene
20.0 4.60 ug/L 05/31/23 13:00 204.60 U1,2-Dibromoethane (EDB)
20.0 10.0 ug/L 05/31/23 13:00 2010.0 U1,2-Dichlorobenzene
20.0 3.80 ug/L 05/31/23 13:00 203.80 U1,2-Dichloroethane
20.0 10.0 ug/L 05/31/23 13:00 2010.0 U1,2-Dichloropropane
20.0 11.2 ug/L 05/31/23 13:00 2048.01,3,5-Trimethylbenzene
20.0 10.8 ug/L 05/31/23 13:00 2010.8 U1,3-Dichlorobenzene
20.0 10.0 ug/L 05/31/23 13:00 2010.0 U1,3-Dichloropropane
20.0 12.8 ug/L 05/31/23 13:00 2012.8 U1,4-Dichlorobenzene
20.0 10.0 ug/L 05/31/23 13:00 2010.0 U2,2-Dichloropropane
500 52.0 ug/L 05/31/23 13:00 2052.0 U2-Butanone (MEK)
20.0 11.4 ug/L 05/31/23 13:00 2011.4 U2-Chlorotoluene
500 28.0 ug/L 05/31/23 13:00 2028.0 U2-Hexanone
400 240 ug/L 05/31/23 13:00 20240U3,3-Dimethyl-1-butanol
20.0 11.2 ug/L 05/31/23 13:00 2011.2 U4-Chlorotoluene
500 36.0 ug/L 05/31/23 13:00 2036.0 U4-Methyl-2-pentanone (MIBK)
500 200 ug/L 05/31/23 13:00 20200UAcetone
20.0 10.0 ug/L 05/31/23 13:00 202470Benzene
20.0 10.8 ug/L 05/31/23 13:00 2010.8 UBromobenzene
20.0 4.20 ug/L 05/31/23 13:00 204.20 UBromochloromethane
20.0 10.0 ug/L 05/31/23 13:00 2010.0 UBromodichloromethane
100 5.00 ug/L 05/31/23 13:00 205.00 UBromoform
20.0 19.6 ug/L 05/31/23 13:00 2019.6 UBromomethane
20.0 3.80 ug/L 05/31/23 13:00 203.80 UCarbon tetrachloride
20.0 3.00 ug/L 05/31/23 13:00 203.00 UChlorobenzene
20.0 15.2 ug/L 05/31/23 13:00 2015.2 UChloroethane
20.0 18.0 ug/L 05/31/23 13:00 2018.0 UChloroform
20.0 18.0 ug/L 05/31/23 13:00 2018.0 UChloromethane
20.0 4.00 ug/L 05/31/23 13:00 204.00 Ucis-1,2-Dichloroethene
100 10.0 ug/L 05/31/23 13:00 2010.0 Ucis-1,3-Dichloropropene
20.0 4.80 ug/L 05/31/23 13:00 204.80 UDibromochloromethane
20.0 17.0 ug/L 05/31/23 13:00 2017.0 UDichlorodifluoromethane
20.0 4.00 ug/L 05/31/23 13:00 2046.8Diisopropyl ether
2000 480 ug/L 05/31/23 13:00 20480UEthanol
20.0 5.60 ug/L 05/31/23 13:00 205.60 UEthyl tert-butyl ether
20.0 10.0 ug/L 05/31/23 13:00 20452Ethylbenzene
20.0 10.6 ug/L 05/31/23 13:00 2015.7 JIsopropylbenzene
20.0 4.40 ug/L 05/31/23 13:00 202710Methyl tert-butyl ether
100 60.0 ug/L 05/31/23 13:00 2060.0 UMethylene Chloride
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Client Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Lab Sample ID: 400-237880-3Client Sample ID: MW3
Matrix: WaterDate Collected: 05/17/23 10:55
Date Received: 05/18/23 08:26
Method: SM6200-B - Volatile Organic Compounds (Continued)
RL MDL
183 100 12.6 ug/L 05/31/23 13:00 20
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
m-Xylene & p-Xylene
100 60.0 ug/L 05/31/23 13:00 20146Naphthalene
20.0 15.2 ug/L 05/31/23 13:00 2015.2 Un-Butylbenzene
20.0 13.8 ug/L 05/31/23 13:00 2040.5N-Propylbenzene
100 12.0 ug/L 05/31/23 13:00 2096.0 Jo-Xylene
20.0 14.2 ug/L 05/31/23 13:00 2014.2 Up-Cymene (p-Isopropyltoluene)
20.0 14.0 ug/L 05/31/23 13:00 2014.0 Usec-Butylbenzene
20.0 20.0 ug/L 05/31/23 13:00 2020.0 UStyrene
200 90.0 ug/L 05/31/23 13:00 204380t-Amyl alcohol
20.0 4.60 ug/L 05/31/23 13:00 204.60 UTert-amyl methyl ether
200 48.0 ug/L 05/31/23 13:00 2048.0 Utert-Butyl Formate
20.0 12.6 ug/L 05/31/23 13:00 2012.6 Utert-Butylbenzene
20.0 18.0 ug/L 05/31/23 13:00 2018.0 UTetrachloroethene
20.0 18.0 ug/L 05/31/23 13:00 20353Toluene
20.0 10.0 ug/L 05/31/23 13:00 2010.0 Utrans-1,2-Dichloroethene
100 4.00 ug/L 05/31/23 13:00 204.00 Utrans-1,3-Dichloropropene
20.0 3.00 ug/L 05/31/23 13:00 203.00 UTrichloroethene
20.0 10.4 ug/L 05/31/23 13:00 2010.4 UTrichlorofluoromethane
500 18.6 ug/L 05/31/23 13:00 2018.6 UVinyl acetate
20.0 10.0 ug/L 05/31/23 13:00 2010.0 UVinyl chloride
200 32.0 ug/L 05/31/23 13:00 20280Xylenes, Total
4-Bromofluorobenzene 98 72-130 05/31/23 13:00 20
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane 98 05/31/23 13:00 2075-126
Toluene-d8 (Surr)97 05/31/23 13:00 2064-132
Eurofins Pensacola
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Client Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Lab Sample ID: 400-237880-4Client Sample ID: MW4
Matrix: WaterDate Collected: 05/17/23 10:50
Date Received: 05/18/23 08:26
Method: SM6200-B - Volatile Organic Compounds
RL MDL
0.160 U 1.00 0.160 ug/L 05/29/23 13:17 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1,2-Tetrachloroethane
1.00 0.180 ug/L 05/29/23 13:17 10.180 U1,1,1-Trichloroethane
1.00 0.500 ug/L 05/29/23 13:17 10.500 U1,1,2,2-Tetrachloroethane
5.00 0.210 ug/L 05/29/23 13:17 10.210 U1,1,2-Trichloroethane
1.00 0.500 ug/L 05/29/23 13:17 10.500 U1,1-Dichloroethane
1.00 0.500 ug/L 05/29/23 13:17 10.500 U1,1-Dichloroethene
1.00 0.500 ug/L 05/29/23 13:17 10.500 U1,1-Dichloropropene
1.00 0.900 ug/L 05/29/23 13:17 10.900 U1,2,3-Trichlorobenzene
5.00 0.840 ug/L 05/29/23 13:17 10.840 U1,2,3-Trichloropropane
1.00 0.820 ug/L 05/29/23 13:17 10.820 U1,2,4-Trichlorobenzene
1.00 0.820 ug/L 05/29/23 13:17 10.820 U1,2,4-Trimethylbenzene
1.00 0.230 ug/L 05/29/23 13:17 10.230 U1,2-Dibromoethane (EDB)
1.00 0.500 ug/L 05/29/23 13:17 10.500 U1,2-Dichlorobenzene
1.00 0.190 ug/L 05/29/23 13:17 10.190 U1,2-Dichloroethane
1.00 0.500 ug/L 05/29/23 13:17 10.500 U1,2-Dichloropropane
1.00 0.560 ug/L 05/29/23 13:17 10.560 U1,3,5-Trimethylbenzene
1.00 0.540 ug/L 05/29/23 13:17 10.540 U1,3-Dichlorobenzene
1.00 0.500 ug/L 05/29/23 13:17 10.500 U1,3-Dichloropropane
1.00 0.640 ug/L 05/29/23 13:17 10.640 U1,4-Dichlorobenzene
1.00 0.500 ug/L 05/29/23 13:17 10.500 U2,2-Dichloropropane
25.0 2.60 ug/L 05/29/23 13:17 16.71 J2-Butanone (MEK)
1.00 0.570 ug/L 05/29/23 13:17 10.570 U2-Chlorotoluene
25.0 1.40 ug/L 05/29/23 13:17 11.40 U2-Hexanone
20.0 12.0 ug/L 05/29/23 13:17 112.0 U3,3-Dimethyl-1-butanol
1.00 0.560 ug/L 05/29/23 13:17 10.560 U4-Chlorotoluene
25.0 1.80 ug/L 05/29/23 13:17 11.80 U4-Methyl-2-pentanone (MIBK)
25.0 10.0 ug/L 05/29/23 13:17 126.9Acetone
1.00 0.500 ug/L 05/29/23 13:17 10.500 UBenzene
1.00 0.540 ug/L 05/29/23 13:17 10.540 UBromobenzene
1.00 0.210 ug/L 05/29/23 13:17 10.210 UBromochloromethane
1.00 0.500 ug/L 05/29/23 13:17 10.500 UBromodichloromethane
5.00 0.250 ug/L 05/29/23 13:17 10.250 UBromoform
1.00 0.980 ug/L 05/29/23 13:17 10.980 U *+Bromomethane
1.00 0.190 ug/L 05/29/23 13:17 10.190 UCarbon tetrachloride
1.00 0.150 ug/L 05/29/23 13:17 10.150 UChlorobenzene
1.00 0.760 ug/L 05/29/23 13:17 10.760 UChloroethane
1.00 0.900 ug/L 05/29/23 13:17 10.900 UChloroform
1.00 0.900 ug/L 05/29/23 13:17 10.900 UChloromethane
1.00 0.200 ug/L 05/29/23 13:17 10.200 Ucis-1,2-Dichloroethene
5.00 0.500 ug/L 05/29/23 13:17 10.500 Ucis-1,3-Dichloropropene
1.00 0.240 ug/L 05/29/23 13:17 10.240 UDibromochloromethane
1.00 0.850 ug/L 05/29/23 13:17 10.850 UDichlorodifluoromethane
1.00 0.200 ug/L 05/29/23 13:17 10.200 UDiisopropyl ether
100 24.0 ug/L 05/29/23 13:17 124.0 UEthanol
1.00 0.280 ug/L 05/29/23 13:17 10.280 UEthyl tert-butyl ether
1.00 0.500 ug/L 05/29/23 13:17 10.500 UEthylbenzene
1.00 0.530 ug/L 05/29/23 13:17 10.530 UIsopropylbenzene
1.00 0.220 ug/L 05/29/23 13:17 10.220 UMethyl tert-butyl ether
5.00 3.00 ug/L 05/29/23 13:17 13.00 UMethylene Chloride
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Client Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Lab Sample ID: 400-237880-4Client Sample ID: MW4
Matrix: WaterDate Collected: 05/17/23 10:50
Date Received: 05/18/23 08:26
Method: SM6200-B - Volatile Organic Compounds (Continued)
RL MDL
0.630 U 5.00 0.630 ug/L 05/29/23 13:17 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
m-Xylene & p-Xylene
5.00 3.00 ug/L 05/29/23 13:17 13.00 UNaphthalene
1.00 0.760 ug/L 05/29/23 13:17 10.760 Un-Butylbenzene
1.00 0.690 ug/L 05/29/23 13:17 10.690 UN-Propylbenzene
5.00 0.600 ug/L 05/29/23 13:17 10.600 Uo-Xylene
1.00 0.710 ug/L 05/29/23 13:17 10.710 Up-Cymene (p-Isopropyltoluene)
1.00 0.700 ug/L 05/29/23 13:17 10.700 Usec-Butylbenzene
1.00 1.00 ug/L 05/29/23 13:17 11.00 UStyrene
10.0 4.50 ug/L 05/29/23 13:17 14.50 Ut-Amyl alcohol
1.00 0.230 ug/L 05/29/23 13:17 10.230 UTert-amyl methyl ether
10.0 2.40 ug/L 05/29/23 13:17 12.40 Utert-Butyl Formate
1.00 0.630 ug/L 05/29/23 13:17 10.630 Utert-Butylbenzene
1.00 0.900 ug/L 05/29/23 13:17 10.900 UTetrachloroethene
1.00 0.900 ug/L 05/29/23 13:17 10.900 UToluene
1.00 0.500 ug/L 05/29/23 13:17 10.500 Utrans-1,2-Dichloroethene
5.00 0.200 ug/L 05/29/23 13:17 10.200 Utrans-1,3-Dichloropropene
1.00 0.150 ug/L 05/29/23 13:17 10.150 UTrichloroethene
1.00 0.520 ug/L 05/29/23 13:17 10.520 U *+Trichlorofluoromethane
25.0 0.930 ug/L 05/29/23 13:17 10.930 UVinyl acetate
1.00 0.500 ug/L 05/29/23 13:17 10.500 UVinyl chloride
10.0 1.60 ug/L 05/29/23 13:17 11.60 UXylenes, Total
4-Bromofluorobenzene 95 72-130 05/29/23 13:17 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane 110 05/29/23 13:17 175-126
Toluene-d8 (Surr)95 05/29/23 13:17 164-132
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Client Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Lab Sample ID: 400-237880-5Client Sample ID: MW5
Matrix: WaterDate Collected: 05/17/23 11:00
Date Received: 05/18/23 08:26
Method: SM6200-B - Volatile Organic Compounds
RL MDL
3.20 U 20.0 3.20 ug/L 05/29/23 19:05 20
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1,2-Tetrachloroethane
20.0 3.60 ug/L 05/29/23 19:05 203.60 U1,1,1-Trichloroethane
20.0 10.0 ug/L 05/29/23 19:05 2010.0 U1,1,2,2-Tetrachloroethane
100 4.20 ug/L 05/29/23 19:05 204.20 U1,1,2-Trichloroethane
20.0 10.0 ug/L 05/29/23 19:05 2010.0 U1,1-Dichloroethane
20.0 10.0 ug/L 05/29/23 19:05 2010.0 U1,1-Dichloroethene
20.0 10.0 ug/L 05/29/23 19:05 2010.0 U1,1-Dichloropropene
20.0 18.0 ug/L 05/29/23 19:05 2018.0 U1,2,3-Trichlorobenzene
100 16.8 ug/L 05/29/23 19:05 2016.8 U1,2,3-Trichloropropane
20.0 16.4 ug/L 05/29/23 19:05 2016.4 U1,2,4-Trichlorobenzene
20.0 16.4 ug/L 05/29/23 19:05 2042.41,2,4-Trimethylbenzene
20.0 4.60 ug/L 05/29/23 19:05 204.60 U1,2-Dibromoethane (EDB)
20.0 10.0 ug/L 05/29/23 19:05 2010.0 U1,2-Dichlorobenzene
20.0 3.80 ug/L 05/29/23 19:05 203.80 U1,2-Dichloroethane
20.0 10.0 ug/L 05/29/23 19:05 2010.0 U1,2-Dichloropropane
20.0 11.2 ug/L 05/29/23 19:05 2012.5 J1,3,5-Trimethylbenzene
20.0 10.8 ug/L 05/29/23 19:05 2010.8 U1,3-Dichlorobenzene
20.0 10.0 ug/L 05/29/23 19:05 2010.0 U1,3-Dichloropropane
20.0 12.8 ug/L 05/29/23 19:05 2012.8 U1,4-Dichlorobenzene
20.0 10.0 ug/L 05/29/23 19:05 2010.0 U2,2-Dichloropropane
500 52.0 ug/L 05/29/23 19:05 2052.0 U2-Butanone (MEK)
20.0 11.4 ug/L 05/29/23 19:05 2011.4 U2-Chlorotoluene
500 28.0 ug/L 05/29/23 19:05 2028.0 U2-Hexanone
400 240 ug/L 05/29/23 19:05 20240U3,3-Dimethyl-1-butanol
20.0 11.2 ug/L 05/29/23 19:05 2011.2 U4-Chlorotoluene
500 36.0 ug/L 05/29/23 19:05 2036.0 U4-Methyl-2-pentanone (MIBK)
500 200 ug/L 05/29/23 19:05 20200UAcetone
20.0 10.0 ug/L 05/29/23 19:05 201600Benzene
20.0 10.8 ug/L 05/29/23 19:05 2010.8 UBromobenzene
20.0 4.20 ug/L 05/29/23 19:05 204.20 UBromochloromethane
20.0 10.0 ug/L 05/29/23 19:05 2010.0 UBromodichloromethane
100 5.00 ug/L 05/29/23 19:05 205.00 UBromoform
20.0 19.6 ug/L 05/29/23 19:05 2019.6 U *+Bromomethane
20.0 3.80 ug/L 05/29/23 19:05 203.80 UCarbon tetrachloride
20.0 3.00 ug/L 05/29/23 19:05 203.00 UChlorobenzene
20.0 15.2 ug/L 05/29/23 19:05 2015.2 UChloroethane
20.0 18.0 ug/L 05/29/23 19:05 2018.0 UChloroform
20.0 18.0 ug/L 05/29/23 19:05 2018.0 UChloromethane
20.0 4.00 ug/L 05/29/23 19:05 204.00 Ucis-1,2-Dichloroethene
100 10.0 ug/L 05/29/23 19:05 2010.0 Ucis-1,3-Dichloropropene
20.0 4.80 ug/L 05/29/23 19:05 204.80 UDibromochloromethane
20.0 17.0 ug/L 05/29/23 19:05 2017.0 UDichlorodifluoromethane
20.0 4.00 ug/L 05/29/23 19:05 2073.0Diisopropyl ether
2000 480 ug/L 05/29/23 19:05 20480UEthanol
20.0 5.60 ug/L 05/29/23 19:05 205.60 UEthyl tert-butyl ether
20.0 10.0 ug/L 05/29/23 19:05 2099.0Ethylbenzene
20.0 10.6 ug/L 05/29/23 19:05 2013.7 JIsopropylbenzene
20.0 4.40 ug/L 05/29/23 19:05 201590Methyl tert-butyl ether
100 60.0 ug/L 05/29/23 19:05 2060.0 UMethylene Chloride
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Client Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Lab Sample ID: 400-237880-5Client Sample ID: MW5
Matrix: WaterDate Collected: 05/17/23 11:00
Date Received: 05/18/23 08:26
Method: SM6200-B - Volatile Organic Compounds (Continued)
RL MDL
134 100 12.6 ug/L 05/29/23 19:05 20
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
m-Xylene & p-Xylene
100 60.0 ug/L 05/29/23 19:05 2073.5 JNaphthalene
20.0 15.2 ug/L 05/29/23 19:05 2015.2 Un-Butylbenzene
20.0 13.8 ug/L 05/29/23 19:05 2034.0N-Propylbenzene
100 12.0 ug/L 05/29/23 19:05 2012.0 Uo-Xylene
20.0 14.2 ug/L 05/29/23 19:05 2014.2 Up-Cymene (p-Isopropyltoluene)
20.0 14.0 ug/L 05/29/23 19:05 2014.0 Usec-Butylbenzene
20.0 20.0 ug/L 05/29/23 19:05 2020.0 UStyrene
200 90.0 ug/L 05/29/23 19:05 204400t-Amyl alcohol
20.0 4.60 ug/L 05/29/23 19:05 204.60 UTert-amyl methyl ether
200 48.0 ug/L 05/29/23 19:05 2048.0 Utert-Butyl Formate
20.0 12.6 ug/L 05/29/23 19:05 2012.6 Utert-Butylbenzene
20.0 18.0 ug/L 05/29/23 19:05 2018.0 UTetrachloroethene
20.0 18.0 ug/L 05/29/23 19:05 2018.0 UToluene
20.0 10.0 ug/L 05/29/23 19:05 2010.0 Utrans-1,2-Dichloroethene
100 4.00 ug/L 05/29/23 19:05 204.00 Utrans-1,3-Dichloropropene
20.0 3.00 ug/L 05/29/23 19:05 203.00 UTrichloroethene
20.0 10.4 ug/L 05/29/23 19:05 2010.4 U *+Trichlorofluoromethane
500 18.6 ug/L 05/29/23 19:05 2018.6 UVinyl acetate
20.0 10.0 ug/L 05/29/23 19:05 2010.0 UVinyl chloride
200 32.0 ug/L 05/29/23 19:05 20140JXylenes, Total
4-Bromofluorobenzene 99 72-130 05/29/23 19:05 20
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane 105 05/29/23 19:05 2075-126
Toluene-d8 (Surr)99 05/29/23 19:05 2064-132
Eurofins Pensacola
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Client Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Lab Sample ID: 400-237880-6Client Sample ID: MW6
Matrix: WaterDate Collected: 05/17/23 11:07
Date Received: 05/18/23 08:26
Method: SM6200-B - Volatile Organic Compounds
RL MDL
1.60 U 10.0 1.60 ug/L 05/29/23 18:12 10
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1,2-Tetrachloroethane
10.0 1.80 ug/L 05/29/23 18:12 101.80 U1,1,1-Trichloroethane
10.0 5.00 ug/L 05/29/23 18:12 105.00 U1,1,2,2-Tetrachloroethane
50.0 2.10 ug/L 05/29/23 18:12 102.10 U1,1,2-Trichloroethane
10.0 5.00 ug/L 05/29/23 18:12 105.00 U1,1-Dichloroethane
10.0 5.00 ug/L 05/29/23 18:12 105.00 U1,1-Dichloroethene
10.0 5.00 ug/L 05/29/23 18:12 105.00 U1,1-Dichloropropene
10.0 9.00 ug/L 05/29/23 18:12 109.00 U1,2,3-Trichlorobenzene
50.0 8.40 ug/L 05/29/23 18:12 108.40 U1,2,3-Trichloropropane
10.0 8.20 ug/L 05/29/23 18:12 108.20 U1,2,4-Trichlorobenzene
10.0 8.20 ug/L 05/29/23 18:12 102171,2,4-Trimethylbenzene
10.0 2.30 ug/L 05/29/23 18:12 102.30 U1,2-Dibromoethane (EDB)
10.0 5.00 ug/L 05/29/23 18:12 105.00 U1,2-Dichlorobenzene
10.0 1.90 ug/L 05/29/23 18:12 101.90 U1,2-Dichloroethane
10.0 5.00 ug/L 05/29/23 18:12 105.00 U1,2-Dichloropropane
10.0 5.60 ug/L 05/29/23 18:12 1074.01,3,5-Trimethylbenzene
10.0 5.40 ug/L 05/29/23 18:12 105.40 U1,3-Dichlorobenzene
10.0 5.00 ug/L 05/29/23 18:12 105.00 U1,3-Dichloropropane
10.0 6.40 ug/L 05/29/23 18:12 106.40 U1,4-Dichlorobenzene
10.0 5.00 ug/L 05/29/23 18:12 105.00 U2,2-Dichloropropane
250 26.0 ug/L 05/29/23 18:12 1026.0 U2-Butanone (MEK)
10.0 5.70 ug/L 05/29/23 18:12 105.70 U2-Chlorotoluene
250 14.0 ug/L 05/29/23 18:12 1014.0 U2-Hexanone
200 120 ug/L 05/29/23 18:12 10120U3,3-Dimethyl-1-butanol
10.0 5.60 ug/L 05/29/23 18:12 105.60 U4-Chlorotoluene
250 18.0 ug/L 05/29/23 18:12 1018.0 U4-Methyl-2-pentanone (MIBK)
250 100 ug/L 05/29/23 18:12 10100UAcetone
10.0 5.00 ug/L 05/29/23 18:12 101080Benzene
10.0 5.40 ug/L 05/29/23 18:12 105.40 UBromobenzene
10.0 2.10 ug/L 05/29/23 18:12 102.10 UBromochloromethane
10.0 5.00 ug/L 05/29/23 18:12 105.00 UBromodichloromethane
50.0 2.50 ug/L 05/29/23 18:12 102.50 UBromoform
10.0 9.80 ug/L 05/29/23 18:12 109.80 U *+Bromomethane
10.0 1.90 ug/L 05/29/23 18:12 101.90 UCarbon tetrachloride
10.0 1.50 ug/L 05/29/23 18:12 101.50 UChlorobenzene
10.0 7.60 ug/L 05/29/23 18:12 107.60 UChloroethane
10.0 9.00 ug/L 05/29/23 18:12 109.00 UChloroform
10.0 9.00 ug/L 05/29/23 18:12 109.00 UChloromethane
10.0 2.00 ug/L 05/29/23 18:12 102.00 Ucis-1,2-Dichloroethene
50.0 5.00 ug/L 05/29/23 18:12 105.00 Ucis-1,3-Dichloropropene
10.0 2.40 ug/L 05/29/23 18:12 102.40 UDibromochloromethane
10.0 8.50 ug/L 05/29/23 18:12 108.50 UDichlorodifluoromethane
10.0 2.00 ug/L 05/29/23 18:12 1034.3Diisopropyl ether
1000 240 ug/L 05/29/23 18:12 10240UEthanol
10.0 2.80 ug/L 05/29/23 18:12 102.80 UEthyl tert-butyl ether
10.0 5.00 ug/L 05/29/23 18:12 10196Ethylbenzene
10.0 5.30 ug/L 05/29/23 18:12 1022.1Isopropylbenzene
10.0 2.20 ug/L 05/29/23 18:12 10596Methyl tert-butyl ether
50.0 30.0 ug/L 05/29/23 18:12 1030.0 UMethylene Chloride
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Client Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Lab Sample ID: 400-237880-6Client Sample ID: MW6
Matrix: WaterDate Collected: 05/17/23 11:07
Date Received: 05/18/23 08:26
Method: SM6200-B - Volatile Organic Compounds (Continued)
RL MDL
451 50.0 6.30 ug/L 05/29/23 18:12 10
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
m-Xylene & p-Xylene
50.0 30.0 ug/L 05/29/23 18:12 10125Naphthalene
10.0 7.60 ug/L 05/29/23 18:12 107.86 Jn-Butylbenzene
10.0 6.90 ug/L 05/29/23 18:12 1060.8N-Propylbenzene
50.0 6.00 ug/L 05/29/23 18:12 1066.4o-Xylene
10.0 7.10 ug/L 05/29/23 18:12 107.10 Up-Cymene (p-Isopropyltoluene)
10.0 7.00 ug/L 05/29/23 18:12 107.00 Usec-Butylbenzene
10.0 10.0 ug/L 05/29/23 18:12 1010.0 UStyrene
100 45.0 ug/L 05/29/23 18:12 102090t-Amyl alcohol
10.0 2.30 ug/L 05/29/23 18:12 103.27 JTert-amyl methyl ether
100 24.0 ug/L 05/29/23 18:12 1024.0 Utert-Butyl Formate
10.0 6.30 ug/L 05/29/23 18:12 106.30 Utert-Butylbenzene
10.0 9.00 ug/L 05/29/23 18:12 109.00 UTetrachloroethene
10.0 9.00 ug/L 05/29/23 18:12 10301Toluene
10.0 5.00 ug/L 05/29/23 18:12 105.00 Utrans-1,2-Dichloroethene
50.0 2.00 ug/L 05/29/23 18:12 102.00 Utrans-1,3-Dichloropropene
10.0 1.50 ug/L 05/29/23 18:12 101.50 UTrichloroethene
10.0 5.20 ug/L 05/29/23 18:12 105.20 U *+Trichlorofluoromethane
250 9.30 ug/L 05/29/23 18:12 109.30 UVinyl acetate
10.0 5.00 ug/L 05/29/23 18:12 105.00 UVinyl chloride
100 16.0 ug/L 05/29/23 18:12 10517Xylenes, Total
4-Bromofluorobenzene 95 72-130 05/29/23 18:12 10
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane 107 05/29/23 18:12 1075-126
Toluene-d8 (Surr)97 05/29/23 18:12 1064-132
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Client Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Lab Sample ID: 400-237880-7Client Sample ID: MW7
Matrix: WaterDate Collected: 05/17/23 11:15
Date Received: 05/18/23 08:26
Method: SM6200-B - Volatile Organic Compounds
RL MDL
0.160 U 1.00 0.160 ug/L 05/29/23 13:44 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1,2-Tetrachloroethane
1.00 0.180 ug/L 05/29/23 13:44 10.180 U1,1,1-Trichloroethane
1.00 0.500 ug/L 05/29/23 13:44 10.500 U1,1,2,2-Tetrachloroethane
5.00 0.210 ug/L 05/29/23 13:44 10.210 U1,1,2-Trichloroethane
1.00 0.500 ug/L 05/29/23 13:44 10.500 U1,1-Dichloroethane
1.00 0.500 ug/L 05/29/23 13:44 10.500 U1,1-Dichloroethene
1.00 0.500 ug/L 05/29/23 13:44 10.500 U1,1-Dichloropropene
1.00 0.900 ug/L 05/29/23 13:44 10.900 U1,2,3-Trichlorobenzene
5.00 0.840 ug/L 05/29/23 13:44 10.840 U1,2,3-Trichloropropane
1.00 0.820 ug/L 05/29/23 13:44 10.820 U1,2,4-Trichlorobenzene
1.00 0.820 ug/L 05/29/23 13:44 10.820 U1,2,4-Trimethylbenzene
1.00 0.230 ug/L 05/29/23 13:44 10.230 U1,2-Dibromoethane (EDB)
1.00 0.500 ug/L 05/29/23 13:44 10.500 U1,2-Dichlorobenzene
1.00 0.190 ug/L 05/29/23 13:44 11.041,2-Dichloroethane
1.00 0.500 ug/L 05/29/23 13:44 10.500 U1,2-Dichloropropane
1.00 0.560 ug/L 05/29/23 13:44 10.560 U1,3,5-Trimethylbenzene
1.00 0.540 ug/L 05/29/23 13:44 10.540 U1,3-Dichlorobenzene
1.00 0.500 ug/L 05/29/23 13:44 10.500 U1,3-Dichloropropane
1.00 0.640 ug/L 05/29/23 13:44 10.640 U1,4-Dichlorobenzene
1.00 0.500 ug/L 05/29/23 13:44 10.500 U2,2-Dichloropropane
25.0 2.60 ug/L 05/29/23 13:44 12.60 U2-Butanone (MEK)
1.00 0.570 ug/L 05/29/23 13:44 10.570 U2-Chlorotoluene
25.0 1.40 ug/L 05/29/23 13:44 11.40 U2-Hexanone
20.0 12.0 ug/L 05/29/23 13:44 112.0 U3,3-Dimethyl-1-butanol
1.00 0.560 ug/L 05/29/23 13:44 10.560 U4-Chlorotoluene
25.0 1.80 ug/L 05/29/23 13:44 11.80 U4-Methyl-2-pentanone (MIBK)
25.0 10.0 ug/L 05/29/23 13:44 110.0 UAcetone
1.00 0.500 ug/L 05/29/23 13:44 14.48Benzene
1.00 0.540 ug/L 05/29/23 13:44 10.540 UBromobenzene
1.00 0.210 ug/L 05/29/23 13:44 10.210 UBromochloromethane
1.00 0.500 ug/L 05/29/23 13:44 10.500 UBromodichloromethane
5.00 0.250 ug/L 05/29/23 13:44 10.250 UBromoform
1.00 0.980 ug/L 05/29/23 13:44 10.980 U *+Bromomethane
1.00 0.190 ug/L 05/29/23 13:44 10.190 UCarbon tetrachloride
1.00 0.150 ug/L 05/29/23 13:44 10.150 UChlorobenzene
1.00 0.760 ug/L 05/29/23 13:44 10.760 UChloroethane
1.00 0.900 ug/L 05/29/23 13:44 10.900 UChloroform
1.00 0.900 ug/L 05/29/23 13:44 10.900 UChloromethane
1.00 0.200 ug/L 05/29/23 13:44 10.200 Ucis-1,2-Dichloroethene
5.00 0.500 ug/L 05/29/23 13:44 10.500 Ucis-1,3-Dichloropropene
1.00 0.240 ug/L 05/29/23 13:44 10.240 UDibromochloromethane
1.00 0.850 ug/L 05/29/23 13:44 10.850 UDichlorodifluoromethane
1.00 0.200 ug/L 05/29/23 13:44 12.88Diisopropyl ether
100 24.0 ug/L 05/29/23 13:44 124.0 UEthanol
1.00 0.280 ug/L 05/29/23 13:44 10.280 UEthyl tert-butyl ether
1.00 0.500 ug/L 05/29/23 13:44 10.715 JEthylbenzene
1.00 0.530 ug/L 05/29/23 13:44 10.530 UIsopropylbenzene
1.00 0.220 ug/L 05/29/23 13:44 1116Methyl tert-butyl ether
5.00 3.00 ug/L 05/29/23 13:44 13.00 UMethylene Chloride
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Client Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Lab Sample ID: 400-237880-7Client Sample ID: MW7
Matrix: WaterDate Collected: 05/17/23 11:15
Date Received: 05/18/23 08:26
Method: SM6200-B - Volatile Organic Compounds (Continued)
RL MDL
0.630 U 5.00 0.630 ug/L 05/29/23 13:44 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
m-Xylene & p-Xylene
5.00 3.00 ug/L 05/29/23 13:44 13.00 UNaphthalene
1.00 0.760 ug/L 05/29/23 13:44 10.760 Un-Butylbenzene
1.00 0.690 ug/L 05/29/23 13:44 10.690 UN-Propylbenzene
5.00 0.600 ug/L 05/29/23 13:44 10.600 Uo-Xylene
1.00 0.710 ug/L 05/29/23 13:44 10.710 Up-Cymene (p-Isopropyltoluene)
1.00 0.700 ug/L 05/29/23 13:44 10.700 Usec-Butylbenzene
1.00 1.00 ug/L 05/29/23 13:44 11.00 UStyrene
10.0 4.50 ug/L 05/29/23 13:44 1245t-Amyl alcohol
1.00 0.230 ug/L 05/29/23 13:44 10.347 JTert-amyl methyl ether
10.0 2.40 ug/L 05/29/23 13:44 12.40 Utert-Butyl Formate
1.00 0.630 ug/L 05/29/23 13:44 10.630 Utert-Butylbenzene
1.00 0.900 ug/L 05/29/23 13:44 10.900 UTetrachloroethene
1.00 0.900 ug/L 05/29/23 13:44 10.900 UToluene
1.00 0.500 ug/L 05/29/23 13:44 10.500 Utrans-1,2-Dichloroethene
5.00 0.200 ug/L 05/29/23 13:44 10.200 Utrans-1,3-Dichloropropene
1.00 0.150 ug/L 05/29/23 13:44 10.150 UTrichloroethene
1.00 0.520 ug/L 05/29/23 13:44 10.520 U *+Trichlorofluoromethane
25.0 0.930 ug/L 05/29/23 13:44 10.930 UVinyl acetate
1.00 0.500 ug/L 05/29/23 13:44 10.500 UVinyl chloride
10.0 1.60 ug/L 05/29/23 13:44 11.60 UXylenes, Total
4-Bromofluorobenzene 96 72-130 05/29/23 13:44 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane 105 05/29/23 13:44 175-126
Toluene-d8 (Surr)98 05/29/23 13:44 164-132
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Client Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Lab Sample ID: 400-237880-8Client Sample ID: MW8
Matrix: WaterDate Collected: 05/17/23 11:21
Date Received: 05/18/23 08:26
Method: SM6200-B - Volatile Organic Compounds
RL MDL
0.160 U 1.00 0.160 ug/L 05/29/23 14:11 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1,2-Tetrachloroethane
1.00 0.180 ug/L 05/29/23 14:11 10.180 U1,1,1-Trichloroethane
1.00 0.500 ug/L 05/29/23 14:11 10.500 U1,1,2,2-Tetrachloroethane
5.00 0.210 ug/L 05/29/23 14:11 10.210 U1,1,2-Trichloroethane
1.00 0.500 ug/L 05/29/23 14:11 10.500 U1,1-Dichloroethane
1.00 0.500 ug/L 05/29/23 14:11 10.500 U1,1-Dichloroethene
1.00 0.500 ug/L 05/29/23 14:11 10.500 U1,1-Dichloropropene
1.00 0.900 ug/L 05/29/23 14:11 10.900 U1,2,3-Trichlorobenzene
5.00 0.840 ug/L 05/29/23 14:11 10.840 U1,2,3-Trichloropropane
1.00 0.820 ug/L 05/29/23 14:11 10.820 U1,2,4-Trichlorobenzene
1.00 0.820 ug/L 05/29/23 14:11 10.820 U1,2,4-Trimethylbenzene
1.00 0.230 ug/L 05/29/23 14:11 10.230 U1,2-Dibromoethane (EDB)
1.00 0.500 ug/L 05/29/23 14:11 10.500 U1,2-Dichlorobenzene
1.00 0.190 ug/L 05/29/23 14:11 10.190 U1,2-Dichloroethane
1.00 0.500 ug/L 05/29/23 14:11 10.500 U1,2-Dichloropropane
1.00 0.560 ug/L 05/29/23 14:11 10.560 U1,3,5-Trimethylbenzene
1.00 0.540 ug/L 05/29/23 14:11 10.540 U1,3-Dichlorobenzene
1.00 0.500 ug/L 05/29/23 14:11 10.500 U1,3-Dichloropropane
1.00 0.640 ug/L 05/29/23 14:11 10.640 U1,4-Dichlorobenzene
1.00 0.500 ug/L 05/29/23 14:11 10.500 U2,2-Dichloropropane
25.0 2.60 ug/L 05/29/23 14:11 12.60 U2-Butanone (MEK)
1.00 0.570 ug/L 05/29/23 14:11 10.570 U2-Chlorotoluene
25.0 1.40 ug/L 05/29/23 14:11 11.40 U2-Hexanone
20.0 12.0 ug/L 05/29/23 14:11 112.0 U3,3-Dimethyl-1-butanol
1.00 0.560 ug/L 05/29/23 14:11 10.560 U4-Chlorotoluene
25.0 1.80 ug/L 05/29/23 14:11 11.80 U4-Methyl-2-pentanone (MIBK)
25.0 10.0 ug/L 05/29/23 14:11 110.0 UAcetone
1.00 0.500 ug/L 05/29/23 14:11 10.500 UBenzene
1.00 0.540 ug/L 05/29/23 14:11 10.540 UBromobenzene
1.00 0.210 ug/L 05/29/23 14:11 10.210 UBromochloromethane
1.00 0.500 ug/L 05/29/23 14:11 10.500 UBromodichloromethane
5.00 0.250 ug/L 05/29/23 14:11 10.250 UBromoform
1.00 0.980 ug/L 05/29/23 14:11 10.980 U *+Bromomethane
1.00 0.190 ug/L 05/29/23 14:11 10.190 UCarbon tetrachloride
1.00 0.150 ug/L 05/29/23 14:11 10.150 UChlorobenzene
1.00 0.760 ug/L 05/29/23 14:11 10.760 UChloroethane
1.00 0.900 ug/L 05/29/23 14:11 10.900 UChloroform
1.00 0.900 ug/L 05/29/23 14:11 10.900 UChloromethane
1.00 0.200 ug/L 05/29/23 14:11 10.200 Ucis-1,2-Dichloroethene
5.00 0.500 ug/L 05/29/23 14:11 10.500 Ucis-1,3-Dichloropropene
1.00 0.240 ug/L 05/29/23 14:11 10.240 UDibromochloromethane
1.00 0.850 ug/L 05/29/23 14:11 10.850 UDichlorodifluoromethane
1.00 0.200 ug/L 05/29/23 14:11 10.200 UDiisopropyl ether
100 24.0 ug/L 05/29/23 14:11 124.0 UEthanol
1.00 0.280 ug/L 05/29/23 14:11 10.280 UEthyl tert-butyl ether
1.00 0.500 ug/L 05/29/23 14:11 10.500 UEthylbenzene
1.00 0.530 ug/L 05/29/23 14:11 10.530 UIsopropylbenzene
1.00 0.220 ug/L 05/29/23 14:11 10.220 UMethyl tert-butyl ether
5.00 3.00 ug/L 05/29/23 14:11 13.00 UMethylene Chloride
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Client Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Lab Sample ID: 400-237880-8Client Sample ID: MW8
Matrix: WaterDate Collected: 05/17/23 11:21
Date Received: 05/18/23 08:26
Method: SM6200-B - Volatile Organic Compounds (Continued)
RL MDL
0.630 U 5.00 0.630 ug/L 05/29/23 14:11 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
m-Xylene & p-Xylene
5.00 3.00 ug/L 05/29/23 14:11 13.00 UNaphthalene
1.00 0.760 ug/L 05/29/23 14:11 10.760 Un-Butylbenzene
1.00 0.690 ug/L 05/29/23 14:11 10.690 UN-Propylbenzene
5.00 0.600 ug/L 05/29/23 14:11 10.600 Uo-Xylene
1.00 0.710 ug/L 05/29/23 14:11 10.710 Up-Cymene (p-Isopropyltoluene)
1.00 0.700 ug/L 05/29/23 14:11 10.700 Usec-Butylbenzene
1.00 1.00 ug/L 05/29/23 14:11 11.00 UStyrene
10.0 4.50 ug/L 05/29/23 14:11 14.50 Ut-Amyl alcohol
1.00 0.230 ug/L 05/29/23 14:11 10.230 UTert-amyl methyl ether
10.0 2.40 ug/L 05/29/23 14:11 12.40 Utert-Butyl Formate
1.00 0.630 ug/L 05/29/23 14:11 10.630 Utert-Butylbenzene
1.00 0.900 ug/L 05/29/23 14:11 10.900 UTetrachloroethene
1.00 0.900 ug/L 05/29/23 14:11 10.900 UToluene
1.00 0.500 ug/L 05/29/23 14:11 10.500 Utrans-1,2-Dichloroethene
5.00 0.200 ug/L 05/29/23 14:11 10.200 Utrans-1,3-Dichloropropene
1.00 0.150 ug/L 05/29/23 14:11 10.150 UTrichloroethene
1.00 0.520 ug/L 05/29/23 14:11 10.520 U *+Trichlorofluoromethane
25.0 0.930 ug/L 05/29/23 14:11 10.930 UVinyl acetate
1.00 0.500 ug/L 05/29/23 14:11 10.500 UVinyl chloride
10.0 1.60 ug/L 05/29/23 14:11 11.60 UXylenes, Total
4-Bromofluorobenzene 95 72-130 05/29/23 14:11 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane 113 05/29/23 14:11 175-126
Toluene-d8 (Surr)96 05/29/23 14:11 164-132
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Client Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Lab Sample ID: 400-237880-9Client Sample ID: MW9
Matrix: WaterDate Collected: 05/17/23 11:27
Date Received: 05/18/23 08:26
Method: SM6200-B - Volatile Organic Compounds
RL MDL
32.0 U 200 32.0 ug/L 05/29/23 19:32 200
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1,2-Tetrachloroethane
200 36.0 ug/L 05/29/23 19:32 20036.0 U1,1,1-Trichloroethane
200 100 ug/L 05/29/23 19:32 200100U1,1,2,2-Tetrachloroethane
1000 42.0 ug/L 05/29/23 19:32 20042.0 U1,1,2-Trichloroethane
200 100 ug/L 05/29/23 19:32 200100U1,1-Dichloroethane
200 100 ug/L 05/29/23 19:32 200100U1,1-Dichloroethene
200 100 ug/L 05/29/23 19:32 200100U1,1-Dichloropropene
200 180 ug/L 05/29/23 19:32 200180U1,2,3-Trichlorobenzene
1000 168 ug/L 05/29/23 19:32 200168U1,2,3-Trichloropropane
200 164 ug/L 05/29/23 19:32 200164U1,2,4-Trichlorobenzene
200 164 ug/L 05/29/23 19:32 20015101,2,4-Trimethylbenzene
200 46.0 ug/L 05/29/23 19:32 20046.0 U1,2-Dibromoethane (EDB)
200 100 ug/L 05/29/23 19:32 200100U1,2-Dichlorobenzene
200 38.0 ug/L 05/29/23 19:32 20038.0 U1,2-Dichloroethane
200 100 ug/L 05/29/23 19:32 200100U1,2-Dichloropropane
200 112 ug/L 05/29/23 19:32 2004551,3,5-Trimethylbenzene
200 108 ug/L 05/29/23 19:32 200108U1,3-Dichlorobenzene
200 100 ug/L 05/29/23 19:32 200100U1,3-Dichloropropane
200 128 ug/L 05/29/23 19:32 200128U1,4-Dichlorobenzene
200 100 ug/L 05/29/23 19:32 200100U2,2-Dichloropropane
5000 520 ug/L 05/29/23 19:32 200520U2-Butanone (MEK)
200 114 ug/L 05/29/23 19:32 200114U2-Chlorotoluene
5000 280 ug/L 05/29/23 19:32 200280U2-Hexanone
4000 2400 ug/L 05/29/23 19:32 2002400U3,3-Dimethyl-1-butanol
200 112 ug/L 05/29/23 19:32 200112U4-Chlorotoluene
5000 360 ug/L 05/29/23 19:32 200360U4-Methyl-2-pentanone (MIBK)
5000 2000 ug/L 05/29/23 19:32 2002000UAcetone
200 100 ug/L 05/29/23 19:32 20013000Benzene
200 108 ug/L 05/29/23 19:32 200108UBromobenzene
200 42.0 ug/L 05/29/23 19:32 20042.0 UBromochloromethane
200 100 ug/L 05/29/23 19:32 200100UBromodichloromethane
1000 50.0 ug/L 05/29/23 19:32 20050.0 UBromoform
200 196 ug/L 05/29/23 19:32 200196U *+Bromomethane
200 38.0 ug/L 05/29/23 19:32 20038.0 UCarbon tetrachloride
200 30.0 ug/L 05/29/23 19:32 20030.0 UChlorobenzene
200 152 ug/L 05/29/23 19:32 200152UChloroethane
200 180 ug/L 05/29/23 19:32 200180UChloroform
200 180 ug/L 05/29/23 19:32 200180UChloromethane
200 40.0 ug/L 05/29/23 19:32 20040.0 Ucis-1,2-Dichloroethene
1000 100 ug/L 05/29/23 19:32 200100Ucis-1,3-Dichloropropene
200 48.0 ug/L 05/29/23 19:32 20048.0 UDibromochloromethane
200 170 ug/L 05/29/23 19:32 200170UDichlorodifluoromethane
200 40.0 ug/L 05/29/23 19:32 200189JDiisopropyl ether
20000 4800 ug/L 05/29/23 19:32 2004800UEthanol
200 56.0 ug/L 05/29/23 19:32 20056.0 UEthyl tert-butyl ether
200 100 ug/L 05/29/23 19:32 2002270Ethylbenzene
200 106 ug/L 05/29/23 19:32 200106UIsopropylbenzene
200 44.0 ug/L 05/29/23 19:32 2009590Methyl tert-butyl ether
1000 600 ug/L 05/29/23 19:32 200600UMethylene Chloride
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Client Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Lab Sample ID: 400-237880-9Client Sample ID: MW9
Matrix: WaterDate Collected: 05/17/23 11:27
Date Received: 05/18/23 08:26
Method: SM6200-B - Volatile Organic Compounds (Continued)
RL MDL
9090 1000 126 ug/L 05/29/23 19:32 200
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
m-Xylene & p-Xylene
1000 600 ug/L 05/29/23 19:32 200600UNaphthalene
200 152 ug/L 05/29/23 19:32 200152Un-Butylbenzene
200 138 ug/L 05/29/23 19:32 200178JN-Propylbenzene
1000 120 ug/L 05/29/23 19:32 2003970o-Xylene
200 142 ug/L 05/29/23 19:32 200142Up-Cymene (p-Isopropyltoluene)
200 140 ug/L 05/29/23 19:32 200140Usec-Butylbenzene
200 200 ug/L 05/29/23 19:32 200200UStyrene
2000 900 ug/L 05/29/23 19:32 2007880t-Amyl alcohol
200 46.0 ug/L 05/29/23 19:32 20046.0 UTert-amyl methyl ether
2000 480 ug/L 05/29/23 19:32 200480Utert-Butyl Formate
200 126 ug/L 05/29/23 19:32 200126Utert-Butylbenzene
200 180 ug/L 05/29/23 19:32 200180UTetrachloroethene
200 180 ug/L 05/29/23 19:32 20028100Toluene
200 100 ug/L 05/29/23 19:32 200100Utrans-1,2-Dichloroethene
1000 40.0 ug/L 05/29/23 19:32 20040.0 Utrans-1,3-Dichloropropene
200 30.0 ug/L 05/29/23 19:32 20030.0 UTrichloroethene
200 104 ug/L 05/29/23 19:32 200104U *+Trichlorofluoromethane
5000 186 ug/L 05/29/23 19:32 200186UVinyl acetate
200 100 ug/L 05/29/23 19:32 200100UVinyl chloride
2000 320 ug/L 05/29/23 19:32 20013100Xylenes, Total
4-Bromofluorobenzene 95 72-130 05/29/23 19:32 200
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane 107 05/29/23 19:32 20075-126
Toluene-d8 (Surr)96 05/29/23 19:32 20064-132
Method: MA DEP MAVPH - Massachusetts - Volatile Petroleum Hydrocarbons (GC)
RL MDL
123000 5200 5200 ug/L 05/26/23 16:05 200
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
C5-C8 Aliphatics
2200 2200 ug/L 05/26/23 16:05 20027600C9-C12 Aliphatics
1400 1400 ug/L 05/26/23 16:05 20014200C9-C10 Aromatics
a,a,a-Trifluorotoluene (fid)94 70-130 05/26/23 16:05 200
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
a,a,a-Trifluorotoluene (pid)89 05/26/23 16:05 20070-130
Method: EPA-DW 504.1 - EDB, DBCP and 1,2,3-TCP (GC)
RL MDL
0.0148 U 0.0198 0.0148 ug/L 05/22/23 11:29 05/22/23 15:27 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,2-Dibromoethane (EDB)
4-Bromofluorobenzene 65 p 56-150 05/22/23 11:29 05/22/23 15:27 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Method: SW846 6010D - Metals (ICP)
RL MDL
0.519 0.0100 0.00200 mg/L 05/19/23 07:10 05/24/23 00:09 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Lead
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Client Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Lab Sample ID: 400-237880-10Client Sample ID: MW10
Matrix: WaterDate Collected: 05/17/23 11:33
Date Received: 05/18/23 08:26
Method: SM6200-B - Volatile Organic Compounds
RL MDL
80.0 U 500 80.0 ug/L 05/29/23 19:59 500
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1,2-Tetrachloroethane
500 90.0 ug/L 05/29/23 19:59 50090.0 U1,1,1-Trichloroethane
500 250 ug/L 05/29/23 19:59 500250U1,1,2,2-Tetrachloroethane
2500 105 ug/L 05/29/23 19:59 500105U1,1,2-Trichloroethane
500 250 ug/L 05/29/23 19:59 500250U1,1-Dichloroethane
500 250 ug/L 05/29/23 19:59 500250U1,1-Dichloroethene
500 250 ug/L 05/29/23 19:59 500250U1,1-Dichloropropene
500 450 ug/L 05/29/23 19:59 500450U1,2,3-Trichlorobenzene
2500 420 ug/L 05/29/23 19:59 500420U1,2,3-Trichloropropane
500 410 ug/L 05/29/23 19:59 500410U1,2,4-Trichlorobenzene
500 410 ug/L 05/29/23 19:59 500485J1,2,4-Trimethylbenzene
500 115 ug/L 05/29/23 19:59 500115U1,2-Dibromoethane (EDB)
500 250 ug/L 05/29/23 19:59 500250U1,2-Dichlorobenzene
500 95.0 ug/L 05/29/23 19:59 5008521,2-Dichloroethane
500 250 ug/L 05/29/23 19:59 500250U1,2-Dichloropropane
500 280 ug/L 05/29/23 19:59 500280U1,3,5-Trimethylbenzene
500 270 ug/L 05/29/23 19:59 500270U1,3-Dichlorobenzene
500 250 ug/L 05/29/23 19:59 500250U1,3-Dichloropropane
500 320 ug/L 05/29/23 19:59 500320U1,4-Dichlorobenzene
500 250 ug/L 05/29/23 19:59 500250U2,2-Dichloropropane
12500 1300 ug/L 05/29/23 19:59 5001300U2-Butanone (MEK)
500 285 ug/L 05/29/23 19:59 500285U2-Chlorotoluene
12500 700 ug/L 05/29/23 19:59 500700U2-Hexanone
10000 6000 ug/L 05/29/23 19:59 5006000U3,3-Dimethyl-1-butanol
500 280 ug/L 05/29/23 19:59 500280U4-Chlorotoluene
12500 900 ug/L 05/29/23 19:59 500900U4-Methyl-2-pentanone (MIBK)
12500 5000 ug/L 05/29/23 19:59 5005000UAcetone
500 250 ug/L 05/29/23 19:59 5007500Benzene
500 270 ug/L 05/29/23 19:59 500270UBromobenzene
500 105 ug/L 05/29/23 19:59 500105UBromochloromethane
500 250 ug/L 05/29/23 19:59 500250UBromodichloromethane
2500 125 ug/L 05/29/23 19:59 500125UBromoform
500 490 ug/L 05/29/23 19:59 500490U *+Bromomethane
500 95.0 ug/L 05/29/23 19:59 50095.0 UCarbon tetrachloride
500 75.0 ug/L 05/29/23 19:59 50075.0 UChlorobenzene
500 380 ug/L 05/29/23 19:59 500380UChloroethane
500 450 ug/L 05/29/23 19:59 500450UChloroform
500 450 ug/L 05/29/23 19:59 500450UChloromethane
500 100 ug/L 05/29/23 19:59 500100Ucis-1,2-Dichloroethene
2500 250 ug/L 05/29/23 19:59 500250Ucis-1,3-Dichloropropene
500 120 ug/L 05/29/23 19:59 500120UDibromochloromethane
500 425 ug/L 05/29/23 19:59 500425UDichlorodifluoromethane
500 100 ug/L 05/29/23 19:59 500253JDiisopropyl ether
50000 12000 ug/L 05/29/23 19:59 50012000UEthanol
500 140 ug/L 05/29/23 19:59 500140UEthyl tert-butyl ether
500 250 ug/L 05/29/23 19:59 500749Ethylbenzene
500 265 ug/L 05/29/23 19:59 500265UIsopropylbenzene
500 110 ug/L 05/29/23 19:59 50011900Methyl tert-butyl ether
2500 1500 ug/L 05/29/23 19:59 5001500UMethylene Chloride
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Client Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Lab Sample ID: 400-237880-10Client Sample ID: MW10
Matrix: WaterDate Collected: 05/17/23 11:33
Date Received: 05/18/23 08:26
Method: SM6200-B - Volatile Organic Compounds (Continued)
RL MDL
2020 J 2500 315 ug/L 05/29/23 19:59 500
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
m-Xylene & p-Xylene
2500 1500 ug/L 05/29/23 19:59 5001500UNaphthalene
500 380 ug/L 05/29/23 19:59 500380Un-Butylbenzene
500 345 ug/L 05/29/23 19:59 500345UN-Propylbenzene
2500 300 ug/L 05/29/23 19:59 5001300Jo-Xylene
500 355 ug/L 05/29/23 19:59 500355Up-Cymene (p-Isopropyltoluene)
500 350 ug/L 05/29/23 19:59 500350Usec-Butylbenzene
500 500 ug/L 05/29/23 19:59 500500UStyrene
5000 2250 ug/L 05/29/23 19:59 50048400t-Amyl alcohol
500 115 ug/L 05/29/23 19:59 500115UTert-amyl methyl ether
5000 1200 ug/L 05/29/23 19:59 5001200Utert-Butyl Formate
500 315 ug/L 05/29/23 19:59 500315Utert-Butylbenzene
500 450 ug/L 05/29/23 19:59 500450UTetrachloroethene
500 450 ug/L 05/29/23 19:59 50030200Toluene
500 250 ug/L 05/29/23 19:59 500250Utrans-1,2-Dichloroethene
2500 100 ug/L 05/29/23 19:59 500100Utrans-1,3-Dichloropropene
500 75.0 ug/L 05/29/23 19:59 50075.0 UTrichloroethene
500 260 ug/L 05/29/23 19:59 500260U *+Trichlorofluoromethane
12500 465 ug/L 05/29/23 19:59 500465UVinyl acetate
500 250 ug/L 05/29/23 19:59 500250UVinyl chloride
5000 800 ug/L 05/29/23 19:59 5003310JXylenes, Total
4-Bromofluorobenzene 96 72-130 05/29/23 19:59 500
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane 113 05/29/23 19:59 50075-126
Toluene-d8 (Surr)96 05/29/23 19:59 50064-132
Method: MA DEP MAVPH - Massachusetts - Volatile Petroleum Hydrocarbons (GC)
RL MDL
204000 13000 13000 ug/L 05/22/23 21:07 500
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
C5-C8 Aliphatics
5500 5500 ug/L 05/22/23 21:07 50010100C9-C12 Aliphatics
3500 3500 ug/L 05/22/23 21:07 50013300C9-C10 Aromatics
a,a,a-Trifluorotoluene (fid)98 70-130 05/22/23 21:07 500
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
a,a,a-Trifluorotoluene (pid)101 05/22/23 21:07 50070-130
Method: EPA-DW 504.1 - EDB, DBCP and 1,2,3-TCP (GC)
RL MDL
0.932 0.0190 0.0143 ug/L 05/22/23 11:29 05/23/23 10:20 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,2-Dibromoethane (EDB)
4-Bromofluorobenzene 110 56-150 05/22/23 11:29 05/23/23 10:20 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Method: SW846 6010D - Metals (ICP)
RL MDL
0.00200 U 0.0100 0.00200 mg/L 05/19/23 07:10 05/24/23 00:14 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Lead
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Definitions/Glossary
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Qualifiers
GC/MS VOA
Qualifier Description
*+LCS and/or LCSD is outside acceptance limits, high biased.
Qualifier
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
U Indicates the analyte was analyzed for but not detected.
GC VOA
Qualifier Description
U Indicates the analyte was analyzed for but not detected.
Qualifier
GC Semi VOA
Qualifier Description
p The %RPD between the primary and confirmation column/detector is >40%. The lower value has been reported.
Qualifier
U Indicates the analyte was analyzed for but not detected.
Metals
Qualifier Description
U Indicates the analyte was analyzed for but not detected.
Qualifier
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
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Surrogate Summary
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Method: SM6200-B - Volatile Organic Compounds
Prep Type: Total/NAMatrix: Water
Lab Sample ID Client Sample ID (72-130)(75-126)(64-132)
BFB DBFM TOL
99 109 120400-237880-1
Percent Surrogate Recovery (Acceptance Limits)
MW1
99 101 97400-237880-2 MW2
98 98 97400-237880-3 MW3
95 110 95400-237880-4 MW4
99 105 99400-237880-5 MW5
95 107 97400-237880-6 MW6
96 105 98400-237880-7 MW7
95 113 96400-237880-8 MW8
95 107 96400-237880-9 MW9
96 113 96400-237880-10 MW10
110 99 105LCS 400-626874/1002 Lab Control Sample
96 101 97LCS 400-626908/1002 Lab Control Sample
98 96 100LCS 400-627151/1002 Lab Control Sample
101 94 100LCS 400-627257/1002 Lab Control Sample
109 104 111MB 400-626874/4 Method Blank
96 111 94MB 400-626908/4 Method Blank
98 104 98MB 400-627151/4 Method Blank
98 103 97MB 400-627257/4 Method Blank
Surrogate Legend
BFB = 4-Bromofluorobenzene
DBFM = Dibromofluoromethane
TOL = Toluene-d8 (Surr)
Method: MAVPH - Massachusetts - Volatile Petroleum Hydrocarbons (GC)
Prep Type: Total/NAMatrix: Water
Lab Sample ID Client Sample ID (70-130)(70-130)
TFT-F1 TFT-P1
94 89400-237880-9
Percent Surrogate Recovery (Acceptance Limits)
MW9
98 101400-237880-10 MW10
100 100LCS 400-625929/4 Lab Control Sample
93 92LCS 400-626667/4 Lab Control Sample
100 100LCSD 400-625929/5 Lab Control Sample Dup
95 94LCSD 400-626667/5 Lab Control Sample Dup
97 94MB 400-625929/3 Method Blank
89 90MB 400-626667/3 Method Blank
Surrogate Legend
TFT-F = a,a,a-Trifluorotoluene (fid)
TFT-P = a,a,a-Trifluorotoluene (pid)
Method: 504.1 - EDB, DBCP and 1,2,3-TCP (GC)
Prep Type: Total/NAMatrix: Water
Lab Sample ID Client Sample ID (56-150)
BFB1
65 p400-237880-9
Percent Surrogate Recovery (Acceptance Limits)
MW9
110400-237880-10 MW10
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Surrogate Summary
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Method: 504.1 - EDB, DBCP and 1,2,3-TCP (GC) (Continued)
Prep Type: Total/NAMatrix: Water
Lab Sample ID Client Sample ID (56-150)
BFB1
61 pLCS 400-625920/2-A
Percent Surrogate Recovery (Acceptance Limits)
Lab Control Sample
71 pLCSD 400-625920/3-A Lab Control Sample Dup
67 pMB 400-625920/1-A Method Blank
Surrogate Legend
BFB = 4-Bromofluorobenzene
Eurofins Pensacola
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QC Association Summary
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
GC/MS VOA
Analysis Batch: 626874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water SM6200-B400-237880-1 MW1 Total/NA
Water SM6200-BMB 400-626874/4 Method Blank Total/NA
Water SM6200-BLCS 400-626874/1002 Lab Control Sample Total/NA
Analysis Batch: 626908
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water SM6200-B400-237880-4 MW4 Total/NA
Water SM6200-B400-237880-5 MW5 Total/NA
Water SM6200-B400-237880-6 MW6 Total/NA
Water SM6200-B400-237880-7 MW7 Total/NA
Water SM6200-B400-237880-8 MW8 Total/NA
Water SM6200-B400-237880-9 MW9 Total/NA
Water SM6200-B400-237880-10 MW10 Total/NA
Water SM6200-BMB 400-626908/4 Method Blank Total/NA
Water SM6200-BLCS 400-626908/1002 Lab Control Sample Total/NA
Analysis Batch: 627151
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water SM6200-B400-237880-3 MW3 Total/NA
Water SM6200-BMB 400-627151/4 Method Blank Total/NA
Water SM6200-BLCS 400-627151/1002 Lab Control Sample Total/NA
Analysis Batch: 627257
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water SM6200-B400-237880-2 MW2 Total/NA
Water SM6200-BMB 400-627257/4 Method Blank Total/NA
Water SM6200-BLCS 400-627257/1002 Lab Control Sample Total/NA
GC VOA
Analysis Batch: 625929
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water MAVPH400-237880-10 MW10 Total/NA
Water MAVPHMB 400-625929/3 Method Blank Total/NA
Water MAVPHLCS 400-625929/4 Lab Control Sample Total/NA
Water MAVPHLCSD 400-625929/5 Lab Control Sample Dup Total/NA
Analysis Batch: 626667
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water MAVPH400-237880-9 MW9 Total/NA
Water MAVPHMB 400-626667/3 Method Blank Total/NA
Water MAVPHLCS 400-626667/4 Lab Control Sample Total/NA
Water MAVPHLCSD 400-626667/5 Lab Control Sample Dup Total/NA
GC Semi VOA
Prep Batch: 625920
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 504.1400-237880-9 MW9 Total/NA
Water 504.1400-237880-10 MW10 Total/NA
Water 504.1MB 400-625920/1-A Method Blank Total/NA
Water 504.1LCS 400-625920/2-A Lab Control Sample Total/NA
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QC Association Summary
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
GC Semi VOA (Continued)
Prep Batch: 625920 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 504.1LCSD 400-625920/3-A Lab Control Sample Dup Total/NA
Analysis Batch: 625961
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 504.1 625920400-237880-9 MW9 Total/NA
Water 504.1 625920MB 400-625920/1-A Method Blank Total/NA
Water 504.1 625920LCS 400-625920/2-A Lab Control Sample Total/NA
Water 504.1 625920LCSD 400-625920/3-A Lab Control Sample Dup Total/NA
Analysis Batch: 626155
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 504.1 625920400-237880-10 MW10 Total/NA
Metals
Prep Batch: 625508
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3010A400-237880-9 MW9 Total/NA
Water 3010A400-237880-10 MW10 Total/NA
Water 3010AMB 400-625508/1-A Method Blank Total/NA
Water 3010ALCS 400-625508/2-A Lab Control Sample Total/NA
Analysis Batch: 626305
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6010D 625508400-237880-9 MW9 Total/NA
Water 6010D 625508400-237880-10 MW10 Total/NA
Water 6010D 625508MB 400-625508/1-A Method Blank Total/NA
Water 6010D 625508LCS 400-625508/2-A Lab Control Sample Total/NA
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QC Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Method: SM6200-B - Volatile Organic Compounds
Client Sample ID: Method BlankLab Sample ID: MB 400-626874/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 626874
RL MDL
1,1,1,2-Tetrachloroethane 0.160 U 1.00 0.160 ug/L 05/28/23 12:51 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
0.180 U 0.1801.00 ug/L 05/28/23 12:51 11,1,1-Trichloroethane
0.500 U 0.5001.00 ug/L 05/28/23 12:51 11,1,2,2-Tetrachloroethane
0.210 U 0.2105.00 ug/L 05/28/23 12:51 11,1,2-Trichloroethane
0.500 U 0.5001.00 ug/L 05/28/23 12:51 11,1-Dichloroethane
0.500 U 0.5001.00 ug/L 05/28/23 12:51 11,1-Dichloroethene
0.500 U 0.5001.00 ug/L 05/28/23 12:51 11,1-Dichloropropene
0.900 U 0.9001.00 ug/L 05/28/23 12:51 11,2,3-Trichlorobenzene
0.840 U 0.8405.00 ug/L 05/28/23 12:51 11,2,3-Trichloropropane
0.820 U 0.8201.00 ug/L 05/28/23 12:51 11,2,4-Trichlorobenzene
0.820 U 0.8201.00 ug/L 05/28/23 12:51 11,2,4-Trimethylbenzene
0.230 U 0.2301.00 ug/L 05/28/23 12:51 11,2-Dibromoethane (EDB)
0.500 U 0.5001.00 ug/L 05/28/23 12:51 11,2-Dichlorobenzene
0.190 U 0.1901.00 ug/L 05/28/23 12:51 11,2-Dichloroethane
0.500 U 0.5001.00 ug/L 05/28/23 12:51 11,2-Dichloropropane
0.560 U 0.5601.00 ug/L 05/28/23 12:51 11,3,5-Trimethylbenzene
0.540 U 0.5401.00 ug/L 05/28/23 12:51 11,3-Dichlorobenzene
0.500 U 0.5001.00 ug/L 05/28/23 12:51 11,3-Dichloropropane
0.640 U 0.6401.00 ug/L 05/28/23 12:51 11,4-Dichlorobenzene
0.500 U 0.5001.00 ug/L 05/28/23 12:51 12,2-Dichloropropane
2.60 U 2.6025.0 ug/L 05/28/23 12:51 12-Butanone (MEK)
0.570 U 0.5701.00 ug/L 05/28/23 12:51 12-Chlorotoluene
1.40 U 1.4025.0 ug/L 05/28/23 12:51 12-Hexanone
12.0 U 12.020.0 ug/L 05/28/23 12:51 13,3-Dimethyl-1-butanol
0.560 U 0.5601.00 ug/L 05/28/23 12:51 14-Chlorotoluene
1.80 U 1.8025.0 ug/L 05/28/23 12:51 14-Methyl-2-pentanone (MIBK)
10.0 U 10.025.0 ug/L 05/28/23 12:51 1Acetone
0.500 U 0.5001.00 ug/L 05/28/23 12:51 1Benzene
0.540 U 0.5401.00 ug/L 05/28/23 12:51 1Bromobenzene
0.210 U 0.2101.00 ug/L 05/28/23 12:51 1Bromochloromethane
0.500 U 0.5001.00 ug/L 05/28/23 12:51 1Bromodichloromethane
0.250 U 0.2505.00 ug/L 05/28/23 12:51 1Bromoform
0.980 U 0.9801.00 ug/L 05/28/23 12:51 1Bromomethane
0.190 U 0.1901.00 ug/L 05/28/23 12:51 1Carbon tetrachloride
0.150 U 0.1501.00 ug/L 05/28/23 12:51 1Chlorobenzene
0.760 U 0.7601.00 ug/L 05/28/23 12:51 1Chloroethane
0.900 U 0.9001.00 ug/L 05/28/23 12:51 1Chloroform
0.900 U 0.9001.00 ug/L 05/28/23 12:51 1Chloromethane
0.200 U 0.2001.00 ug/L 05/28/23 12:51 1cis-1,2-Dichloroethene
0.500 U 0.5005.00 ug/L 05/28/23 12:51 1cis-1,3-Dichloropropene
0.240 U 0.2401.00 ug/L 05/28/23 12:51 1Dibromochloromethane
0.850 U 0.8501.00 ug/L 05/28/23 12:51 1Dichlorodifluoromethane
0.200 U 0.2001.00 ug/L 05/28/23 12:51 1Diisopropyl ether
24.0 U 24.0100 ug/L 05/28/23 12:51 1Ethanol
0.280 U 0.2801.00 ug/L 05/28/23 12:51 1Ethyl tert-butyl ether
0.500 U 0.5001.00 ug/L 05/28/23 12:51 1Ethylbenzene
0.530 U 0.5301.00 ug/L 05/28/23 12:51 1Isopropylbenzene
0.220 U 0.2201.00 ug/L 05/28/23 12:51 1Methyl tert-butyl ether
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QC Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 400-626874/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 626874
RL MDL
Methylene Chloride 3.00 U 5.00 3.00 ug/L 05/28/23 12:51 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
0.630 U 0.6305.00 ug/L 05/28/23 12:51 1m-Xylene & p-Xylene
3.00 U 3.005.00 ug/L 05/28/23 12:51 1Naphthalene
0.760 U 0.7601.00 ug/L 05/28/23 12:51 1n-Butylbenzene
0.690 U 0.6901.00 ug/L 05/28/23 12:51 1N-Propylbenzene
0.600 U 0.6005.00 ug/L 05/28/23 12:51 1o-Xylene
0.710 U 0.7101.00 ug/L 05/28/23 12:51 1p-Cymene (p-Isopropyltoluene)
0.700 U 0.7001.00 ug/L 05/28/23 12:51 1sec-Butylbenzene
1.00 U 1.001.00 ug/L 05/28/23 12:51 1Styrene
4.50 U 4.5010.0 ug/L 05/28/23 12:51 1t-Amyl alcohol
0.230 U 0.2301.00 ug/L 05/28/23 12:51 1Tert-amyl methyl ether
2.40 U 2.4010.0 ug/L 05/28/23 12:51 1tert-Butyl Formate
0.630 U 0.6301.00 ug/L 05/28/23 12:51 1tert-Butylbenzene
0.900 U 0.9001.00 ug/L 05/28/23 12:51 1Tetrachloroethene
0.900 U 0.9001.00 ug/L 05/28/23 12:51 1Toluene
0.500 U 0.5001.00 ug/L 05/28/23 12:51 1trans-1,2-Dichloroethene
0.200 U 0.2005.00 ug/L 05/28/23 12:51 1trans-1,3-Dichloropropene
0.150 U 0.1501.00 ug/L 05/28/23 12:51 1Trichloroethene
0.520 U 0.5201.00 ug/L 05/28/23 12:51 1Trichlorofluoromethane
0.930 U 0.93025.0 ug/L 05/28/23 12:51 1Vinyl acetate
0.500 U 0.5001.00 ug/L 05/28/23 12:51 1Vinyl chloride
1.60 U 1.6010.0 ug/L 05/28/23 12:51 1Xylenes, Total
4-Bromofluorobenzene 109 72-130 05/28/23 12:51 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
104 05/28/23 12:51 1Dibromofluoromethane75-126
111 05/28/23 12:51 1Toluene-d8 (Surr)64-132
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-626874/1002
Matrix: Water Prep Type: Total/NA
Analysis Batch: 626874
1,1,1,2-Tetrachloroethane 50.0 48.57 ug/L 97 67 -131
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
1,1,1-Trichloroethane 50.0 44.53 ug/L 89 68 -130
1,1,2,2-Tetrachloroethane 50.0 49.30 ug/L 99 70 -131
1,1,2-Trichloroethane 50.0 51.45 ug/L 103 70 -130
1,1-Dichloroethane 50.0 48.14 ug/L 96 70 -130
1,1-Dichloroethene 50.0 39.56 ug/L 79 63 -134
1,1-Dichloropropene 50.0 43.80 ug/L 88 70 -130
1,2,3-Trichlorobenzene 50.0 50.78 ug/L 102 60 -138
1,2,3-Trichloropropane 50.0 53.01 ug/L 106 70 -130
1,2,4-Trichlorobenzene 50.0 50.00 ug/L 100 60 -140
1,2,4-Trimethylbenzene 50.0 47.06 ug/L 94 70 -130
1,2-Dibromoethane (EDB)50.0 51.49 ug/L 103 70 -130
1,2-Dichlorobenzene 50.0 45.83 ug/L 92 67 -130
1,2-Dichloroethane 50.0 49.99 ug/L 100 69 -130
1,2-Dichloropropane 50.0 50.98 ug/L 102 70 -130
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QC Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-626874/1002
Matrix: Water Prep Type: Total/NA
Analysis Batch: 626874
1,3,5-Trimethylbenzene 50.0 46.02 ug/L 92 69 -130
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
1,3-Dichlorobenzene 50.0 46.03 ug/L 92 70 -130
1,3-Dichloropropane 50.0 51.21 ug/L 102 70 -130
1,4-Dichlorobenzene 50.0 46.84 ug/L 94 70 -130
2,2-Dichloropropane 50.0 42.61 ug/L 85 52 -135
2-Butanone (MEK)200 214.0 ug/L 107 61 -145
2-Chlorotoluene 50.0 42.94 ug/L 86 70 -130
2-Hexanone 200 286.5 *+ug/L 143 65 -137
3,3-Dimethyl-1-butanol 125 208.7 *+ug/L 167 38 -144
4-Chlorotoluene 50.0 47.30 ug/L 95 70 -130
4-Methyl-2-pentanone (MIBK)200 267.2 ug/L 134 69 -138
Acetone 200 285.2 ug/L 143 43 -160
Benzene 50.0 41.72 ug/L 83 70 -130
Bromobenzene 50.0 46.47 ug/L 93 70 -132
Bromochloromethane 50.0 46.87 ug/L 94 70 -130
Bromodichloromethane 50.0 46.10 ug/L 92 67 -133
Bromoform 50.0 49.48 ug/L 99 57 -140
Bromomethane 25.0 16.10 ug/L 64 10 -160
Carbon tetrachloride 50.0 47.05 ug/L 94 61 -137
Chlorobenzene 50.0 47.40 ug/L 95 70 -130
Chloroethane 25.0 26.09 ug/L 104 55 -141
Chloroform 50.0 44.17 ug/L 88 69 -130
Chloromethane 25.0 43.22 *+ug/L 173 58 -137
cis-1,2-Dichloroethene 50.0 50.68 ug/L 101 68 -130
cis-1,3-Dichloropropene 50.0 47.99 ug/L 96 69 -132
Dibromochloromethane 50.0 51.52 ug/L 103 67 -135
Dichlorodifluoromethane 25.0 28.53 ug/L 114 41 -146
Diisopropyl ether 25.0 31.28 ug/L 125 64 -132
Ethanol 1000 1676 *+ug/L 168 20 -160
Ethyl tert-butyl ether 25.0 24.32 ug/L 97 55 -133
Ethylbenzene 50.0 44.21 ug/L 88 70 -130
Isopropylbenzene 50.0 43.91 ug/L 88 70 -130
Methyl tert-butyl ether 50.0 43.76 ug/L 88 66 -130
Methylene Chloride 50.0 44.19 ug/L 88 66 -135
m-Xylene & p-Xylene 50.0 45.48 ug/L 91 70 -130
Naphthalene 50.0 51.12 ug/L 102 47 -149
n-Butylbenzene 50.0 41.69 ug/L 83 67 -130
N-Propylbenzene 50.0 48.36 ug/L 97 70 -130
o-Xylene 50.0 44.31 ug/L 89 70 -130
p-Cymene (p-Isopropyltoluene)50.0 48.79 ug/L 98 65 -130
sec-Butylbenzene 50.0 44.27 ug/L 89 66 -130
Styrene 50.0 43.38 ug/L 87 70 -130
t-Amyl alcohol 250 293.4 ug/L 117 38 -139
Tert-amyl methyl ether 25.0 23.38 ug/L 94 52 -132
tert-Butyl Formate 125 103.7 ug/L 83 10 -160
tert-Butylbenzene 50.0 47.34 ug/L 95 64 -139
Tetrachloroethene 50.0 54.31 ug/L 109 65 -130
Toluene 50.0 46.06 ug/L 92 70 -130
trans-1,2-Dichloroethene 50.0 42.85 ug/L 86 70 -130
Eurofins Pensacola
Page 36 of 58 6/5/2023
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QC Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-626874/1002
Matrix: Water Prep Type: Total/NA
Analysis Batch: 626874
trans-1,3-Dichloropropene 50.0 50.64 ug/L 101 63 -130
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Trichloroethene 50.0 46.82 ug/L 94 70 -130
Trichlorofluoromethane 25.0 27.81 ug/L 111 65 -138
Vinyl acetate 50.0 52.89 ug/L 106 26 -160
Vinyl chloride 25.0 36.59 *+ug/L 146 59 -136
Xylenes, Total 100 89.79 ug/L 90 70 -130
4-Bromofluorobenzene 72 -130
Surrogate
110
LCS LCS
Qualifier Limits%Recovery
99Dibromofluoromethane 75 -126
105Toluene-d8 (Surr)64 -132
Client Sample ID: Method BlankLab Sample ID: MB 400-626908/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 626908
RL MDL
1,1,1,2-Tetrachloroethane 0.160 U 1.00 0.160 ug/L 05/29/23 10:10 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
0.180 U 0.1801.00 ug/L 05/29/23 10:10 11,1,1-Trichloroethane
0.500 U 0.5001.00 ug/L 05/29/23 10:10 11,1,2,2-Tetrachloroethane
0.210 U 0.2105.00 ug/L 05/29/23 10:10 11,1,2-Trichloroethane
0.500 U 0.5001.00 ug/L 05/29/23 10:10 11,1-Dichloroethane
0.500 U 0.5001.00 ug/L 05/29/23 10:10 11,1-Dichloroethene
0.500 U 0.5001.00 ug/L 05/29/23 10:10 11,1-Dichloropropene
0.900 U 0.9001.00 ug/L 05/29/23 10:10 11,2,3-Trichlorobenzene
0.840 U 0.8405.00 ug/L 05/29/23 10:10 11,2,3-Trichloropropane
0.820 U 0.8201.00 ug/L 05/29/23 10:10 11,2,4-Trichlorobenzene
0.820 U 0.8201.00 ug/L 05/29/23 10:10 11,2,4-Trimethylbenzene
0.230 U 0.2301.00 ug/L 05/29/23 10:10 11,2-Dibromoethane (EDB)
0.500 U 0.5001.00 ug/L 05/29/23 10:10 11,2-Dichlorobenzene
0.190 U 0.1901.00 ug/L 05/29/23 10:10 11,2-Dichloroethane
0.500 U 0.5001.00 ug/L 05/29/23 10:10 11,2-Dichloropropane
0.560 U 0.5601.00 ug/L 05/29/23 10:10 11,3,5-Trimethylbenzene
0.540 U 0.5401.00 ug/L 05/29/23 10:10 11,3-Dichlorobenzene
0.500 U 0.5001.00 ug/L 05/29/23 10:10 11,3-Dichloropropane
0.640 U 0.6401.00 ug/L 05/29/23 10:10 11,4-Dichlorobenzene
0.500 U 0.5001.00 ug/L 05/29/23 10:10 12,2-Dichloropropane
2.60 U 2.6025.0 ug/L 05/29/23 10:10 12-Butanone (MEK)
0.570 U 0.5701.00 ug/L 05/29/23 10:10 12-Chlorotoluene
1.40 U 1.4025.0 ug/L 05/29/23 10:10 12-Hexanone
12.0 U 12.020.0 ug/L 05/29/23 10:10 13,3-Dimethyl-1-butanol
0.560 U 0.5601.00 ug/L 05/29/23 10:10 14-Chlorotoluene
1.80 U 1.8025.0 ug/L 05/29/23 10:10 14-Methyl-2-pentanone (MIBK)
10.0 U 10.025.0 ug/L 05/29/23 10:10 1Acetone
0.500 U 0.5001.00 ug/L 05/29/23 10:10 1Benzene
0.540 U 0.5401.00 ug/L 05/29/23 10:10 1Bromobenzene
0.210 U 0.2101.00 ug/L 05/29/23 10:10 1Bromochloromethane
0.500 U 0.5001.00 ug/L 05/29/23 10:10 1Bromodichloromethane
Eurofins Pensacola
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QC Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 400-626908/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 626908
RL MDL
Bromoform 0.250 U 5.00 0.250 ug/L 05/29/23 10:10 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
0.980 U 0.9801.00 ug/L 05/29/23 10:10 1Bromomethane
0.190 U 0.1901.00 ug/L 05/29/23 10:10 1Carbon tetrachloride
0.150 U 0.1501.00 ug/L 05/29/23 10:10 1Chlorobenzene
0.760 U 0.7601.00 ug/L 05/29/23 10:10 1Chloroethane
0.900 U 0.9001.00 ug/L 05/29/23 10:10 1Chloroform
0.900 U 0.9001.00 ug/L 05/29/23 10:10 1Chloromethane
0.200 U 0.2001.00 ug/L 05/29/23 10:10 1cis-1,2-Dichloroethene
0.500 U 0.5005.00 ug/L 05/29/23 10:10 1cis-1,3-Dichloropropene
0.240 U 0.2401.00 ug/L 05/29/23 10:10 1Dibromochloromethane
0.850 U 0.8501.00 ug/L 05/29/23 10:10 1Dichlorodifluoromethane
0.200 U 0.2001.00 ug/L 05/29/23 10:10 1Diisopropyl ether
24.0 U 24.0100 ug/L 05/29/23 10:10 1Ethanol
0.280 U 0.2801.00 ug/L 05/29/23 10:10 1Ethyl tert-butyl ether
0.500 U 0.5001.00 ug/L 05/29/23 10:10 1Ethylbenzene
0.530 U 0.5301.00 ug/L 05/29/23 10:10 1Isopropylbenzene
0.220 U 0.2201.00 ug/L 05/29/23 10:10 1Methyl tert-butyl ether
3.00 U 3.005.00 ug/L 05/29/23 10:10 1Methylene Chloride
0.630 U 0.6305.00 ug/L 05/29/23 10:10 1m-Xylene & p-Xylene
3.00 U 3.005.00 ug/L 05/29/23 10:10 1Naphthalene
0.760 U 0.7601.00 ug/L 05/29/23 10:10 1n-Butylbenzene
0.690 U 0.6901.00 ug/L 05/29/23 10:10 1N-Propylbenzene
0.600 U 0.6005.00 ug/L 05/29/23 10:10 1o-Xylene
0.710 U 0.7101.00 ug/L 05/29/23 10:10 1p-Cymene (p-Isopropyltoluene)
0.700 U 0.7001.00 ug/L 05/29/23 10:10 1sec-Butylbenzene
1.00 U 1.001.00 ug/L 05/29/23 10:10 1Styrene
4.50 U 4.5010.0 ug/L 05/29/23 10:10 1t-Amyl alcohol
0.230 U 0.2301.00 ug/L 05/29/23 10:10 1Tert-amyl methyl ether
2.40 U 2.4010.0 ug/L 05/29/23 10:10 1tert-Butyl Formate
0.630 U 0.6301.00 ug/L 05/29/23 10:10 1tert-Butylbenzene
0.900 U 0.9001.00 ug/L 05/29/23 10:10 1Tetrachloroethene
0.900 U 0.9001.00 ug/L 05/29/23 10:10 1Toluene
0.500 U 0.5001.00 ug/L 05/29/23 10:10 1trans-1,2-Dichloroethene
0.200 U 0.2005.00 ug/L 05/29/23 10:10 1trans-1,3-Dichloropropene
0.150 U 0.1501.00 ug/L 05/29/23 10:10 1Trichloroethene
0.520 U 0.5201.00 ug/L 05/29/23 10:10 1Trichlorofluoromethane
0.930 U 0.93025.0 ug/L 05/29/23 10:10 1Vinyl acetate
0.500 U 0.5001.00 ug/L 05/29/23 10:10 1Vinyl chloride
1.60 U 1.6010.0 ug/L 05/29/23 10:10 1Xylenes, Total
4-Bromofluorobenzene 96 72-130 05/29/23 10:10 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
111 05/29/23 10:10 1Dibromofluoromethane75-126
94 05/29/23 10:10 1Toluene-d8 (Surr)64-132
Eurofins Pensacola
Page 38 of 58 6/5/2023
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QC Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-626908/1002
Matrix: Water Prep Type: Total/NA
Analysis Batch: 626908
1,1,1,2-Tetrachloroethane 50.0 50.92 ug/L 102 67 -131
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
1,1,1-Trichloroethane 50.0 51.42 ug/L 103 68 -130
1,1,2,2-Tetrachloroethane 50.0 45.91 ug/L 92 70 -131
1,1,2-Trichloroethane 50.0 48.23 ug/L 96 70 -130
1,1-Dichloroethane 50.0 45.35 ug/L 91 70 -130
1,1-Dichloroethene 50.0 48.64 ug/L 97 63 -134
1,1-Dichloropropene 50.0 48.01 ug/L 96 70 -130
1,2,3-Trichlorobenzene 50.0 53.68 ug/L 107 60 -138
1,2,3-Trichloropropane 50.0 49.71 ug/L 99 70 -130
1,2,4-Trichlorobenzene 50.0 53.63 ug/L 107 60 -140
1,2,4-Trimethylbenzene 50.0 51.99 ug/L 104 70 -130
1,2-Dibromoethane (EDB)50.0 48.36 ug/L 97 70 -130
1,2-Dichlorobenzene 50.0 50.92 ug/L 102 67 -130
1,2-Dichloroethane 50.0 55.09 ug/L 110 69 -130
1,2-Dichloropropane 50.0 47.44 ug/L 95 70 -130
1,3,5-Trimethylbenzene 50.0 50.74 ug/L 101 69 -130
1,3-Dichlorobenzene 50.0 49.78 ug/L 100 70 -130
1,3-Dichloropropane 50.0 49.49 ug/L 99 70 -130
1,4-Dichlorobenzene 50.0 50.21 ug/L 100 70 -130
2,2-Dichloropropane 50.0 48.49 ug/L 97 52 -135
2-Butanone (MEK)200 192.4 ug/L 96 61 -145
2-Chlorotoluene 50.0 50.28 ug/L 101 70 -130
2-Hexanone 200 196.4 ug/L 98 65 -137
3,3-Dimethyl-1-butanol 250 213.1 ug/L 85 38 -144
4-Chlorotoluene 50.0 51.04 ug/L 102 70 -130
4-Methyl-2-pentanone (MIBK)200 196.3 ug/L 98 69 -138
Acetone 200 241.0 ug/L 120 43 -160
Benzene 50.0 46.69 ug/L 93 70 -130
Bromobenzene 50.0 48.65 ug/L 97 70 -132
Bromochloromethane 50.0 49.38 ug/L 99 70 -130
Bromodichloromethane 50.0 51.95 ug/L 104 67 -133
Bromoform 50.0 49.17 ug/L 98 57 -140
Bromomethane 50.0 87.27 *+ug/L 175 10 -160
Carbon tetrachloride 50.0 54.66 ug/L 109 61 -137
Chlorobenzene 50.0 48.99 ug/L 98 70 -130
Chloroethane 50.0 57.58 ug/L 115 55 -141
Chloroform 50.0 49.45 ug/L 99 69 -130
Chloromethane 50.0 43.90 ug/L 88 58 -137
cis-1,2-Dichloroethene 50.0 47.50 ug/L 95 68 -130
cis-1,3-Dichloropropene 50.0 49.99 ug/L 100 69 -132
Dibromochloromethane 50.0 50.94 ug/L 102 67 -135
Dichlorodifluoromethane 50.0 53.82 ug/L 108 41 -146
Diisopropyl ether 50.0 43.29 ug/L 87 64 -132
Ethanol 2000 2458 ug/L 123 20 -160
Ethyl tert-butyl ether 50.0 44.96 ug/L 90 55 -133
Ethylbenzene 50.0 49.99 ug/L 100 70 -130
Isopropylbenzene 50.0 50.55 ug/L 101 70 -130
Methyl tert-butyl ether 50.0 48.54 ug/L 97 66 -130
Eurofins Pensacola
Page 39 of 58 6/5/2023
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QC Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-626908/1002
Matrix: Water Prep Type: Total/NA
Analysis Batch: 626908
Methylene Chloride 50.0 44.13 ug/L 88 66 -135
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
m-Xylene & p-Xylene 50.0 50.10 ug/L 100 70 -130
Naphthalene 50.0 50.79 ug/L 102 47 -149
n-Butylbenzene 50.0 53.11 ug/L 106 67 -130
N-Propylbenzene 50.0 49.84 ug/L 100 70 -130
o-Xylene 50.0 50.49 ug/L 101 70 -130
p-Cymene (p-Isopropyltoluene)50.0 51.68 ug/L 103 65 -130
sec-Butylbenzene 50.0 50.67 ug/L 101 66 -130
Styrene 50.0 48.94 ug/L 98 70 -130
t-Amyl alcohol 500 412.2 ug/L 82 38 -139
Tert-amyl methyl ether 50.0 44.67 ug/L 89 52 -132
tert-Butyl Formate 250 193.2 ug/L 77 10 -160
tert-Butylbenzene 50.0 51.75 ug/L 103 64 -139
Tetrachloroethene 50.0 48.72 ug/L 97 65 -130
Toluene 50.0 45.51 ug/L 91 70 -130
trans-1,2-Dichloroethene 50.0 44.09 ug/L 88 70 -130
trans-1,3-Dichloropropene 50.0 49.61 ug/L 99 63 -130
Trichloroethene 50.0 48.07 ug/L 96 70 -130
Trichlorofluoromethane 50.0 69.50 *+ug/L 139 65 -138
Vinyl acetate 100 104.1 ug/L 104 26 -160
Vinyl chloride 50.0 52.78 ug/L 106 59 -136
Xylenes, Total 100 100.6 ug/L 101 70 -130
4-Bromofluorobenzene 72 -130
Surrogate
96
LCS LCS
Qualifier Limits%Recovery
101Dibromofluoromethane 75 -126
97Toluene-d8 (Surr)64 -132
Client Sample ID: Method BlankLab Sample ID: MB 400-627151/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 627151
RL MDL
1,1,1,2-Tetrachloroethane 0.160 U 1.00 0.160 ug/L 05/31/23 09:25 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
0.180 U 0.1801.00 ug/L 05/31/23 09:25 11,1,1-Trichloroethane
0.500 U 0.5001.00 ug/L 05/31/23 09:25 11,1,2,2-Tetrachloroethane
0.210 U 0.2105.00 ug/L 05/31/23 09:25 11,1,2-Trichloroethane
0.500 U 0.5001.00 ug/L 05/31/23 09:25 11,1-Dichloroethane
0.500 U 0.5001.00 ug/L 05/31/23 09:25 11,1-Dichloroethene
0.500 U 0.5001.00 ug/L 05/31/23 09:25 11,1-Dichloropropene
0.900 U 0.9001.00 ug/L 05/31/23 09:25 11,2,3-Trichlorobenzene
0.840 U 0.8405.00 ug/L 05/31/23 09:25 11,2,3-Trichloropropane
0.820 U 0.8201.00 ug/L 05/31/23 09:25 11,2,4-Trichlorobenzene
0.820 U 0.8201.00 ug/L 05/31/23 09:25 11,2,4-Trimethylbenzene
0.230 U 0.2301.00 ug/L 05/31/23 09:25 11,2-Dibromoethane (EDB)
0.500 U 0.5001.00 ug/L 05/31/23 09:25 11,2-Dichlorobenzene
0.190 U 0.1901.00 ug/L 05/31/23 09:25 11,2-Dichloroethane
0.500 U 0.5001.00 ug/L 05/31/23 09:25 11,2-Dichloropropane
Eurofins Pensacola
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QC Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 400-627151/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 627151
RL MDL
1,3,5-Trimethylbenzene 0.560 U 1.00 0.560 ug/L 05/31/23 09:25 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
0.540 U 0.5401.00 ug/L 05/31/23 09:25 11,3-Dichlorobenzene
0.500 U 0.5001.00 ug/L 05/31/23 09:25 11,3-Dichloropropane
0.640 U 0.6401.00 ug/L 05/31/23 09:25 11,4-Dichlorobenzene
0.500 U 0.5001.00 ug/L 05/31/23 09:25 12,2-Dichloropropane
2.60 U 2.6025.0 ug/L 05/31/23 09:25 12-Butanone (MEK)
0.570 U 0.5701.00 ug/L 05/31/23 09:25 12-Chlorotoluene
1.40 U 1.4025.0 ug/L 05/31/23 09:25 12-Hexanone
12.0 U 12.020.0 ug/L 05/31/23 09:25 13,3-Dimethyl-1-butanol
0.560 U 0.5601.00 ug/L 05/31/23 09:25 14-Chlorotoluene
1.80 U 1.8025.0 ug/L 05/31/23 09:25 14-Methyl-2-pentanone (MIBK)
10.0 U 10.025.0 ug/L 05/31/23 09:25 1Acetone
0.500 U 0.5001.00 ug/L 05/31/23 09:25 1Benzene
0.540 U 0.5401.00 ug/L 05/31/23 09:25 1Bromobenzene
0.210 U 0.2101.00 ug/L 05/31/23 09:25 1Bromochloromethane
0.500 U 0.5001.00 ug/L 05/31/23 09:25 1Bromodichloromethane
0.250 U 0.2505.00 ug/L 05/31/23 09:25 1Bromoform
0.980 U 0.9801.00 ug/L 05/31/23 09:25 1Bromomethane
0.190 U 0.1901.00 ug/L 05/31/23 09:25 1Carbon tetrachloride
0.150 U 0.1501.00 ug/L 05/31/23 09:25 1Chlorobenzene
0.760 U 0.7601.00 ug/L 05/31/23 09:25 1Chloroethane
0.900 U 0.9001.00 ug/L 05/31/23 09:25 1Chloroform
0.900 U 0.9001.00 ug/L 05/31/23 09:25 1Chloromethane
0.200 U 0.2001.00 ug/L 05/31/23 09:25 1cis-1,2-Dichloroethene
0.500 U 0.5005.00 ug/L 05/31/23 09:25 1cis-1,3-Dichloropropene
0.240 U 0.2401.00 ug/L 05/31/23 09:25 1Dibromochloromethane
0.850 U 0.8501.00 ug/L 05/31/23 09:25 1Dichlorodifluoromethane
0.200 U 0.2001.00 ug/L 05/31/23 09:25 1Diisopropyl ether
24.0 U 24.0100 ug/L 05/31/23 09:25 1Ethanol
0.280 U 0.2801.00 ug/L 05/31/23 09:25 1Ethyl tert-butyl ether
0.500 U 0.5001.00 ug/L 05/31/23 09:25 1Ethylbenzene
0.530 U 0.5301.00 ug/L 05/31/23 09:25 1Isopropylbenzene
0.220 U 0.2201.00 ug/L 05/31/23 09:25 1Methyl tert-butyl ether
3.00 U 3.005.00 ug/L 05/31/23 09:25 1Methylene Chloride
0.630 U 0.6305.00 ug/L 05/31/23 09:25 1m-Xylene & p-Xylene
3.00 U 3.005.00 ug/L 05/31/23 09:25 1Naphthalene
0.760 U 0.7601.00 ug/L 05/31/23 09:25 1n-Butylbenzene
0.690 U 0.6901.00 ug/L 05/31/23 09:25 1N-Propylbenzene
0.600 U 0.6005.00 ug/L 05/31/23 09:25 1o-Xylene
0.710 U 0.7101.00 ug/L 05/31/23 09:25 1p-Cymene (p-Isopropyltoluene)
0.700 U 0.7001.00 ug/L 05/31/23 09:25 1sec-Butylbenzene
1.00 U 1.001.00 ug/L 05/31/23 09:25 1Styrene
4.50 U 4.5010.0 ug/L 05/31/23 09:25 1t-Amyl alcohol
0.230 U 0.2301.00 ug/L 05/31/23 09:25 1Tert-amyl methyl ether
2.40 U 2.4010.0 ug/L 05/31/23 09:25 1tert-Butyl Formate
0.630 U 0.6301.00 ug/L 05/31/23 09:25 1tert-Butylbenzene
0.900 U 0.9001.00 ug/L 05/31/23 09:25 1Tetrachloroethene
0.900 U 0.9001.00 ug/L 05/31/23 09:25 1Toluene
0.500 U 0.5001.00 ug/L 05/31/23 09:25 1trans-1,2-Dichloroethene
Eurofins Pensacola
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QC Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 400-627151/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 627151
RL MDL
trans-1,3-Dichloropropene 0.200 U 5.00 0.200 ug/L 05/31/23 09:25 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
0.150 U 0.1501.00 ug/L 05/31/23 09:25 1Trichloroethene
0.520 U 0.5201.00 ug/L 05/31/23 09:25 1Trichlorofluoromethane
0.930 U 0.93025.0 ug/L 05/31/23 09:25 1Vinyl acetate
0.500 U 0.5001.00 ug/L 05/31/23 09:25 1Vinyl chloride
1.60 U 1.6010.0 ug/L 05/31/23 09:25 1Xylenes, Total
4-Bromofluorobenzene 98 72-130 05/31/23 09:25 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
104 05/31/23 09:25 1Dibromofluoromethane75-126
98 05/31/23 09:25 1Toluene-d8 (Surr)64-132
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-627151/1002
Matrix: Water Prep Type: Total/NA
Analysis Batch: 627151
1,1,1,2-Tetrachloroethane 50.0 44.01 ug/L 88 67 -131
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
1,1,1-Trichloroethane 50.0 38.73 ug/L 77 68 -130
1,1,2,2-Tetrachloroethane 50.0 46.90 ug/L 94 70 -131
1,1,2-Trichloroethane 50.0 47.40 ug/L 95 70 -130
1,1-Dichloroethane 50.0 42.58 ug/L 85 70 -130
1,1-Dichloroethene 50.0 41.67 ug/L 83 63 -134
1,1-Dichloropropene 50.0 41.41 ug/L 83 70 -130
1,2,3-Trichlorobenzene 50.0 47.19 ug/L 94 60 -138
1,2,3-Trichloropropane 50.0 44.70 ug/L 89 70 -130
1,2,4-Trichlorobenzene 50.0 47.34 ug/L 95 60 -140
1,2,4-Trimethylbenzene 50.0 46.18 ug/L 92 70 -130
1,2-Dibromoethane (EDB)50.0 45.44 ug/L 91 70 -130
1,2-Dichlorobenzene 50.0 46.36 ug/L 93 67 -130
1,2-Dichloroethane 50.0 41.13 ug/L 82 69 -130
1,2-Dichloropropane 50.0 46.21 ug/L 92 70 -130
1,3,5-Trimethylbenzene 50.0 45.45 ug/L 91 69 -130
1,3-Dichlorobenzene 50.0 45.52 ug/L 91 70 -130
1,3-Dichloropropane 50.0 46.81 ug/L 94 70 -130
1,4-Dichlorobenzene 50.0 45.76 ug/L 92 70 -130
2,2-Dichloropropane 50.0 37.60 ug/L 75 52 -135
2-Butanone (MEK)200 181.0 ug/L 91 61 -145
2-Chlorotoluene 50.0 44.99 ug/L 90 70 -130
2-Hexanone 200 179.4 ug/L 90 65 -137
3,3-Dimethyl-1-butanol 250 209.9 ug/L 84 38 -144
4-Chlorotoluene 50.0 46.07 ug/L 92 70 -130
4-Methyl-2-pentanone (MIBK)200 175.5 ug/L 88 69 -138
Acetone 200 192.5 ug/L 96 43 -160
Benzene 50.0 43.32 ug/L 87 70 -130
Bromobenzene 50.0 45.31 ug/L 91 70 -132
Bromochloromethane 50.0 45.21 ug/L 90 70 -130
Bromodichloromethane 50.0 42.89 ug/L 86 67 -133
Eurofins Pensacola
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QC Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-627151/1002
Matrix: Water Prep Type: Total/NA
Analysis Batch: 627151
Bromoform 50.0 45.10 ug/L 90 57 -140
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Bromomethane 50.0 38.72 ug/L 77 10 -160
Carbon tetrachloride 50.0 39.20 ug/L 78 61 -137
Chlorobenzene 50.0 44.24 ug/L 88 70 -130
Chloroethane 50.0 32.40 ug/L 65 55 -141
Chloroform 50.0 40.73 ug/L 81 69 -130
Chloromethane 50.0 45.67 ug/L 91 58 -137
cis-1,2-Dichloroethene 50.0 41.84 ug/L 84 68 -130
cis-1,3-Dichloropropene 50.0 45.12 ug/L 90 69 -132
Dibromochloromethane 50.0 44.47 ug/L 89 67 -135
Dichlorodifluoromethane 50.0 40.19 ug/L 80 41 -146
Diisopropyl ether 50.0 43.05 ug/L 86 64 -132
Ethanol 2000 2318 ug/L 116 20 -160
Ethyl tert-butyl ether 50.0 40.45 ug/L 81 55 -133
Ethylbenzene 50.0 44.18 ug/L 88 70 -130
Isopropylbenzene 50.0 43.84 ug/L 88 70 -130
Methyl tert-butyl ether 50.0 41.62 ug/L 83 66 -130
Methylene Chloride 50.0 43.66 ug/L 87 66 -135
m-Xylene & p-Xylene 50.0 43.39 ug/L 87 70 -130
Naphthalene 50.0 45.18 ug/L 90 47 -149
n-Butylbenzene 50.0 47.46 ug/L 95 67 -130
N-Propylbenzene 50.0 45.46 ug/L 91 70 -130
o-Xylene 50.0 44.22 ug/L 88 70 -130
p-Cymene (p-Isopropyltoluene)50.0 45.74 ug/L 91 65 -130
sec-Butylbenzene 50.0 45.92 ug/L 92 66 -130
Styrene 50.0 44.72 ug/L 89 70 -130
t-Amyl alcohol 500 372.4 ug/L 74 38 -139
Tert-amyl methyl ether 50.0 40.11 ug/L 80 52 -132
tert-Butyl Formate 250 168.1 ug/L 67 10 -160
tert-Butylbenzene 50.0 43.98 ug/L 88 64 -139
Tetrachloroethene 50.0 41.79 ug/L 84 65 -130
Toluene 50.0 41.71 ug/L 83 70 -130
trans-1,2-Dichloroethene 50.0 41.46 ug/L 83 70 -130
trans-1,3-Dichloropropene 50.0 44.04 ug/L 88 63 -130
Trichloroethene 50.0 41.93 ug/L 84 70 -130
Trichlorofluoromethane 50.0 47.95 ug/L 96 65 -138
Vinyl acetate 100 93.98 ug/L 94 26 -160
Vinyl chloride 50.0 49.06 ug/L 98 59 -136
Xylenes, Total 100 87.61 ug/L 88 70 -130
4-Bromofluorobenzene 72 -130
Surrogate
98
LCS LCS
Qualifier Limits%Recovery
96Dibromofluoromethane 75 -126
100Toluene-d8 (Surr)64 -132
Eurofins Pensacola
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QC Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 400-627257/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 627257
RL MDL
1,1,1,2-Tetrachloroethane 0.160 U 1.00 0.160 ug/L 05/31/23 16:56 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
0.180 U 0.1801.00 ug/L 05/31/23 16:56 11,1,1-Trichloroethane
0.500 U 0.5001.00 ug/L 05/31/23 16:56 11,1,2,2-Tetrachloroethane
0.210 U 0.2105.00 ug/L 05/31/23 16:56 11,1,2-Trichloroethane
0.500 U 0.5001.00 ug/L 05/31/23 16:56 11,1-Dichloroethane
0.500 U 0.5001.00 ug/L 05/31/23 16:56 11,1-Dichloroethene
0.500 U 0.5001.00 ug/L 05/31/23 16:56 11,1-Dichloropropene
0.900 U 0.9001.00 ug/L 05/31/23 16:56 11,2,3-Trichlorobenzene
0.840 U 0.8405.00 ug/L 05/31/23 16:56 11,2,3-Trichloropropane
0.820 U 0.8201.00 ug/L 05/31/23 16:56 11,2,4-Trichlorobenzene
0.820 U 0.8201.00 ug/L 05/31/23 16:56 11,2,4-Trimethylbenzene
0.230 U 0.2301.00 ug/L 05/31/23 16:56 11,2-Dibromoethane (EDB)
0.500 U 0.5001.00 ug/L 05/31/23 16:56 11,2-Dichlorobenzene
0.190 U 0.1901.00 ug/L 05/31/23 16:56 11,2-Dichloroethane
0.500 U 0.5001.00 ug/L 05/31/23 16:56 11,2-Dichloropropane
0.560 U 0.5601.00 ug/L 05/31/23 16:56 11,3,5-Trimethylbenzene
0.540 U 0.5401.00 ug/L 05/31/23 16:56 11,3-Dichlorobenzene
0.500 U 0.5001.00 ug/L 05/31/23 16:56 11,3-Dichloropropane
0.640 U 0.6401.00 ug/L 05/31/23 16:56 11,4-Dichlorobenzene
0.500 U 0.5001.00 ug/L 05/31/23 16:56 12,2-Dichloropropane
2.60 U 2.6025.0 ug/L 05/31/23 16:56 12-Butanone (MEK)
0.570 U 0.5701.00 ug/L 05/31/23 16:56 12-Chlorotoluene
1.40 U 1.4025.0 ug/L 05/31/23 16:56 12-Hexanone
12.0 U 12.020.0 ug/L 05/31/23 16:56 13,3-Dimethyl-1-butanol
0.560 U 0.5601.00 ug/L 05/31/23 16:56 14-Chlorotoluene
1.80 U 1.8025.0 ug/L 05/31/23 16:56 14-Methyl-2-pentanone (MIBK)
10.0 U 10.025.0 ug/L 05/31/23 16:56 1Acetone
0.500 U 0.5001.00 ug/L 05/31/23 16:56 1Benzene
0.540 U 0.5401.00 ug/L 05/31/23 16:56 1Bromobenzene
0.210 U 0.2101.00 ug/L 05/31/23 16:56 1Bromochloromethane
0.500 U 0.5001.00 ug/L 05/31/23 16:56 1Bromodichloromethane
0.250 U 0.2505.00 ug/L 05/31/23 16:56 1Bromoform
0.980 U 0.9801.00 ug/L 05/31/23 16:56 1Bromomethane
0.190 U 0.1901.00 ug/L 05/31/23 16:56 1Carbon tetrachloride
0.150 U 0.1501.00 ug/L 05/31/23 16:56 1Chlorobenzene
0.760 U 0.7601.00 ug/L 05/31/23 16:56 1Chloroethane
0.900 U 0.9001.00 ug/L 05/31/23 16:56 1Chloroform
0.900 U 0.9001.00 ug/L 05/31/23 16:56 1Chloromethane
0.200 U 0.2001.00 ug/L 05/31/23 16:56 1cis-1,2-Dichloroethene
0.500 U 0.5005.00 ug/L 05/31/23 16:56 1cis-1,3-Dichloropropene
0.240 U 0.2401.00 ug/L 05/31/23 16:56 1Dibromochloromethane
0.850 U 0.8501.00 ug/L 05/31/23 16:56 1Dichlorodifluoromethane
0.200 U 0.2001.00 ug/L 05/31/23 16:56 1Diisopropyl ether
24.0 U 24.0100 ug/L 05/31/23 16:56 1Ethanol
0.280 U 0.2801.00 ug/L 05/31/23 16:56 1Ethyl tert-butyl ether
0.500 U 0.5001.00 ug/L 05/31/23 16:56 1Ethylbenzene
0.530 U 0.5301.00 ug/L 05/31/23 16:56 1Isopropylbenzene
0.220 U 0.2201.00 ug/L 05/31/23 16:56 1Methyl tert-butyl ether
Eurofins Pensacola
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QC Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 400-627257/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 627257
RL MDL
Methylene Chloride 3.00 U 5.00 3.00 ug/L 05/31/23 16:56 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
0.630 U 0.6305.00 ug/L 05/31/23 16:56 1m-Xylene & p-Xylene
3.00 U 3.005.00 ug/L 05/31/23 16:56 1Naphthalene
0.760 U 0.7601.00 ug/L 05/31/23 16:56 1n-Butylbenzene
0.690 U 0.6901.00 ug/L 05/31/23 16:56 1N-Propylbenzene
0.600 U 0.6005.00 ug/L 05/31/23 16:56 1o-Xylene
0.710 U 0.7101.00 ug/L 05/31/23 16:56 1p-Cymene (p-Isopropyltoluene)
0.700 U 0.7001.00 ug/L 05/31/23 16:56 1sec-Butylbenzene
1.00 U 1.001.00 ug/L 05/31/23 16:56 1Styrene
4.50 U 4.5010.0 ug/L 05/31/23 16:56 1t-Amyl alcohol
0.230 U 0.2301.00 ug/L 05/31/23 16:56 1Tert-amyl methyl ether
2.40 U 2.4010.0 ug/L 05/31/23 16:56 1tert-Butyl Formate
0.630 U 0.6301.00 ug/L 05/31/23 16:56 1tert-Butylbenzene
0.900 U 0.9001.00 ug/L 05/31/23 16:56 1Tetrachloroethene
0.900 U 0.9001.00 ug/L 05/31/23 16:56 1Toluene
0.500 U 0.5001.00 ug/L 05/31/23 16:56 1trans-1,2-Dichloroethene
0.200 U 0.2005.00 ug/L 05/31/23 16:56 1trans-1,3-Dichloropropene
0.150 U 0.1501.00 ug/L 05/31/23 16:56 1Trichloroethene
0.520 U 0.5201.00 ug/L 05/31/23 16:56 1Trichlorofluoromethane
0.930 U 0.93025.0 ug/L 05/31/23 16:56 1Vinyl acetate
0.500 U 0.5001.00 ug/L 05/31/23 16:56 1Vinyl chloride
1.60 U 1.6010.0 ug/L 05/31/23 16:56 1Xylenes, Total
4-Bromofluorobenzene 98 72-130 05/31/23 16:56 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
103 05/31/23 16:56 1Dibromofluoromethane75-126
97 05/31/23 16:56 1Toluene-d8 (Surr)64-132
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-627257/1002
Matrix: Water Prep Type: Total/NA
Analysis Batch: 627257
1,1,1,2-Tetrachloroethane 50.0 43.83 ug/L 88 67 -131
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
1,1,1-Trichloroethane 50.0 39.22 ug/L 78 68 -130
1,1,2,2-Tetrachloroethane 50.0 45.95 ug/L 92 70 -131
1,1,2-Trichloroethane 50.0 45.45 ug/L 91 70 -130
1,1-Dichloroethane 50.0 42.12 ug/L 84 70 -130
1,1-Dichloroethene 50.0 42.62 ug/L 85 63 -134
1,1-Dichloropropene 50.0 42.21 ug/L 84 70 -130
1,2,3-Trichlorobenzene 50.0 49.25 ug/L 98 60 -138
1,2,3-Trichloropropane 50.0 43.45 ug/L 87 70 -130
1,2,4-Trichlorobenzene 50.0 49.20 ug/L 98 60 -140
1,2,4-Trimethylbenzene 50.0 46.79 ug/L 94 70 -130
1,2-Dibromoethane (EDB)50.0 43.81 ug/L 88 70 -130
1,2-Dichlorobenzene 50.0 46.31 ug/L 93 67 -130
1,2-Dichloroethane 50.0 39.48 ug/L 79 69 -130
1,2-Dichloropropane 50.0 45.11 ug/L 90 70 -130
Eurofins Pensacola
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QC Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-627257/1002
Matrix: Water Prep Type: Total/NA
Analysis Batch: 627257
1,3,5-Trimethylbenzene 50.0 47.04 ug/L 94 69 -130
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
1,3-Dichlorobenzene 50.0 45.50 ug/L 91 70 -130
1,3-Dichloropropane 50.0 45.67 ug/L 91 70 -130
1,4-Dichlorobenzene 50.0 46.01 ug/L 92 70 -130
2,2-Dichloropropane 50.0 37.98 ug/L 76 52 -135
2-Butanone (MEK)200 169.4 ug/L 85 61 -145
2-Chlorotoluene 50.0 46.68 ug/L 93 70 -130
2-Hexanone 200 172.5 ug/L 86 65 -137
3,3-Dimethyl-1-butanol 250 170.6 ug/L 68 38 -144
4-Chlorotoluene 50.0 47.29 ug/L 95 70 -130
4-Methyl-2-pentanone (MIBK)200 166.9 ug/L 83 69 -138
Acetone 200 181.3 ug/L 91 43 -160
Benzene 50.0 43.28 ug/L 87 70 -130
Bromobenzene 50.0 45.87 ug/L 92 70 -132
Bromochloromethane 50.0 43.23 ug/L 86 70 -130
Bromodichloromethane 50.0 42.31 ug/L 85 67 -133
Bromoform 50.0 43.77 ug/L 88 57 -140
Bromomethane 50.0 40.98 ug/L 82 10 -160
Carbon tetrachloride 50.0 39.97 ug/L 80 61 -137
Chlorobenzene 50.0 44.15 ug/L 88 70 -130
Chloroethane 50.0 49.13 ug/L 98 55 -141
Chloroform 50.0 40.52 ug/L 81 69 -130
Chloromethane 50.0 46.16 ug/L 92 58 -137
cis-1,2-Dichloroethene 50.0 41.98 ug/L 84 68 -130
cis-1,3-Dichloropropene 50.0 43.69 ug/L 87 69 -132
Dibromochloromethane 50.0 43.27 ug/L 87 67 -135
Dichlorodifluoromethane 50.0 43.90 ug/L 88 41 -146
Diisopropyl ether 50.0 42.26 ug/L 85 64 -132
Ethanol 2000 1719 ug/L 86 20 -160
Ethyl tert-butyl ether 50.0 40.31 ug/L 81 55 -133
Ethylbenzene 50.0 45.18 ug/L 90 70 -130
Isopropylbenzene 50.0 44.79 ug/L 90 70 -130
Methyl tert-butyl ether 50.0 40.53 ug/L 81 66 -130
Methylene Chloride 50.0 43.65 ug/L 87 66 -135
m-Xylene & p-Xylene 50.0 44.57 ug/L 89 70 -130
Naphthalene 50.0 45.74 ug/L 91 47 -149
n-Butylbenzene 50.0 49.35 ug/L 99 67 -130
N-Propylbenzene 50.0 46.89 ug/L 94 70 -130
o-Xylene 50.0 45.05 ug/L 90 70 -130
p-Cymene (p-Isopropyltoluene)50.0 47.73 ug/L 95 65 -130
sec-Butylbenzene 50.0 47.39 ug/L 95 66 -130
Styrene 50.0 44.24 ug/L 88 70 -130
t-Amyl alcohol 500 352.9 ug/L 71 38 -139
Tert-amyl methyl ether 50.0 39.16 ug/L 78 52 -132
tert-Butyl Formate 250 162.0 ug/L 65 10 -160
tert-Butylbenzene 50.0 45.52 ug/L 91 64 -139
Tetrachloroethene 50.0 43.39 ug/L 87 65 -130
Toluene 50.0 42.43 ug/L 85 70 -130
trans-1,2-Dichloroethene 50.0 42.04 ug/L 84 70 -130
Eurofins Pensacola
Page 46 of 58 6/5/2023
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QC Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-627257/1002
Matrix: Water Prep Type: Total/NA
Analysis Batch: 627257
trans-1,3-Dichloropropene 50.0 43.18 ug/L 86 63 -130
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Trichloroethene 50.0 42.04 ug/L 84 70 -130
Trichlorofluoromethane 50.0 48.46 ug/L 97 65 -138
Vinyl acetate 100 97.79 ug/L 98 26 -160
Vinyl chloride 50.0 53.26 ug/L 107 59 -136
Xylenes, Total 100 89.62 ug/L 90 70 -130
4-Bromofluorobenzene 72 -130
Surrogate
101
LCS LCS
Qualifier Limits%Recovery
94Dibromofluoromethane 75 -126
100Toluene-d8 (Surr)64 -132
Method: MAVPH - Massachusetts - Volatile Petroleum Hydrocarbons (GC)
Client Sample ID: Method BlankLab Sample ID: MB 400-625929/3
Matrix: Water Prep Type: Total/NA
Analysis Batch: 625929
RL MDL
C5-C8 Aliphatics 26.0 U 26.0 26.0 ug/L 05/22/23 13:24 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
11.0 U 11.011.0 ug/L 05/22/23 13:24 1C9-C12 Aliphatics
7.00 U 7.007.00 ug/L 05/22/23 13:24 1C9-C10 Aromatics
a,a,a-Trifluorotoluene (fid)97 70-130 05/22/23 13:24 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
94 05/22/23 13:24 1a,a,a-Trifluorotoluene (pid)70-130
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-625929/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 625929
C5-C8 Aliphatics 300 321.9 ug/L 107 70 -130
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
C9-C12 Aliphatics 350 327.3 ug/L 94 70 -130
C9-C10 Aromatics 50.0 45.49 ug/L 91 70 -130
a,a,a-Trifluorotoluene (fid)70 -130
Surrogate
100
LCS LCS
Qualifier Limits%Recovery
100a,a,a-Trifluorotoluene (pid)70 -130
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 400-625929/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 625929
C5-C8 Aliphatics 300 324.3 ug/L 108 70 -130 1 25
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
C9-C12 Aliphatics 350 355.2 ug/L 101 70 -130 8 25
C9-C10 Aromatics 50.0 51.86 ug/L 104 70 -130 13 25
Eurofins Pensacola
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QC Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Method: MAVPH - Massachusetts - Volatile Petroleum Hydrocarbons (GC) (Continued)
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 400-625929/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 625929
a,a,a-Trifluorotoluene (fid)70 -130
Surrogate
100
LCSD LCSD
Qualifier Limits%Recovery
100a,a,a-Trifluorotoluene (pid)70 -130
Client Sample ID: Method BlankLab Sample ID: MB 400-626667/3
Matrix: Water Prep Type: Total/NA
Analysis Batch: 626667
RL MDL
C5-C8 Aliphatics 26.0 U 26.0 26.0 ug/L 05/26/23 11:25 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
11.0 U 11.011.0 ug/L 05/26/23 11:25 1C9-C12 Aliphatics
7.00 U 7.007.00 ug/L 05/26/23 11:25 1C9-C10 Aromatics
a,a,a-Trifluorotoluene (fid)89 70-130 05/26/23 11:25 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
90 05/26/23 11:25 1a,a,a-Trifluorotoluene (pid)70-130
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-626667/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 626667
C5-C8 Aliphatics 300 346.0 ug/L 115 70 -130
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
C9-C12 Aliphatics 350 379.4 ug/L 108 70 -130
C9-C10 Aromatics 50.0 56.51 ug/L 113 70 -130
a,a,a-Trifluorotoluene (fid)70 -130
Surrogate
93
LCS LCS
Qualifier Limits%Recovery
92a,a,a-Trifluorotoluene (pid)70 -130
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 400-626667/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 626667
C5-C8 Aliphatics 300 326.8 ug/L 109 70 -130 6 25
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
C9-C12 Aliphatics 350 357.4 ug/L 102 70 -130 6 25
C9-C10 Aromatics 50.0 53.05 ug/L 106 70 -130 6 25
a,a,a-Trifluorotoluene (fid)70 -130
Surrogate
95
LCSD LCSD
Qualifier Limits%Recovery
94a,a,a-Trifluorotoluene (pid)70 -130
Eurofins Pensacola
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QC Sample Results
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Method: 504.1 - EDB, DBCP and 1,2,3-TCP (GC)
Client Sample ID: Method BlankLab Sample ID: MB 400-625920/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 625961 Prep Batch: 625920
RL MDL
1,2-Dibromoethane (EDB)0.0150 U 0.0200 0.0150 ug/L 05/22/23 11:29 05/22/23 14:26 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
4-Bromofluorobenzene 67 p 56-150 05/22/23 14:26 1
MB MB
Surrogate
05/22/23 11:29
Dil FacPreparedAnalyzedQualifierLimits%Recovery
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-625920/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 625961 Prep Batch: 625920
1,2-Dibromoethane (EDB)0.101 0.07576 p ug/L 75 70 -130
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
4-Bromofluorobenzene p 56 -150
Surrogate
61
LCS LCS
Qualifier Limits%Recovery
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 400-625920/3-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 625961 Prep Batch: 625920
1,2-Dibromoethane (EDB)0.101 0.08405 p ug/L 83 70 -130 10 10
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
4-Bromofluorobenzene p 56 -150
Surrogate
71
LCSD LCSD
Qualifier Limits%Recovery
Method: 6010D - Metals (ICP)
Client Sample ID: Method BlankLab Sample ID: MB 400-625508/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 626305 Prep Batch: 625508
RL MDL
Lead 0.00200 U 0.0100 0.00200 mg/L 05/19/23 07:10 05/23/23 22:40 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-625508/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 626305 Prep Batch: 625508
Lead 1.00 0.9234 mg/L 92 80 -120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Eurofins Pensacola
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Lab Chronicle
Client: Terraquest Environmental Consultants, PC Job ID: 400-237880-1
Project/Site: JD's Country Store
Client Sample ID: MW1 Lab Sample ID: 400-237880-1
Matrix: WaterDate Collected: 05/17/23 10:37
Date Received: 05/18/23 08:26
Analysis SM6200-B BPO05/28/23 20:3310 EET PEN626874
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: MW2 Lab Sample ID: 400-237880-2
Matrix: WaterDate Collected: 05/17/23 10:42
Date Received: 05/18/23 08:26
Analysis SM6200-B AGW05/31/23 19:3750 EET PEN627257
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: MW3 Lab Sample ID: 400-237880-3
Matrix: WaterDate Collected: 05/17/23 10:55
Date Received: 05/18/23 08:26
Analysis SM6200-B AGW05/31/23 13:0020 EET PEN627151
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: MW4 Lab Sample ID: 400-237880-4
Matrix: WaterDate Collected: 05/17/23 10:50
Date Received: 05/18/23 08:26
Analysis SM6200-B AGW05/29/23 13:171 EET PEN626908
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: MW5 Lab Sample ID: 400-237880-5
Matrix: WaterDate Collected: 05/17/23 11:00
Date Received: 05/18/23 08:26
Analysis SM6200-B AGW05/29/23 19:0520 EET PEN626908
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: MW6 Lab Sample ID: 400-237880-6
Matrix: WaterDate Collected: 05/17/23 11:07
Date Received: 05/18/23 08:26
Analysis SM6200-B AGW05/29/23 18:1210 EET PEN626908
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: MW7 Lab Sample ID: 400-237880-7
Matrix: WaterDate Collected: 05/17/23 11:15
Date Received: 05/18/23 08:26
Analysis SM6200-B AGW05/29/23 13:441 EET PEN626908
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Eurofins Pensacola
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Lab Chronicle
Client: Terraquest Environmental Consultants, PC Job ID: 400-237880-1
Project/Site: JD's Country Store
Client Sample ID: MW8 Lab Sample ID: 400-237880-8
Matrix: WaterDate Collected: 05/17/23 11:21
Date Received: 05/18/23 08:26
Analysis SM6200-B AGW05/29/23 14:111 EET PEN626908
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: MW9 Lab Sample ID: 400-237880-9
Matrix: WaterDate Collected: 05/17/23 11:27
Date Received: 05/18/23 08:26
Analysis SM6200-B AGW05/29/23 19:32200 EET PEN626908
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Analysis MAVPH 200 626667 05/26/23 16:05 SAB EET PENTotal/NA 5 mL 5 mL
Prep 504.1 625920 05/22/23 11:29 PG EET PENTotal/NA 35.4 mL 35 mL
Analysis 504.1 1 625961 05/22/23 15:27 PG EET PENTotal/NA
Prep 3010A 625508 05/19/23 07:10 KWN EET PENTotal/NA 50 mL 50 mL
Completed:05/19/23 12:05 ¹
Analysis 6010D 1 626305 05/24/23 00:09 BAW EET PENTotal/NA
Client Sample ID: MW10 Lab Sample ID: 400-237880-10
Matrix: WaterDate Collected: 05/17/23 11:33
Date Received: 05/18/23 08:26
Analysis SM6200-B AGW05/29/23 19:59500 EET PEN626908
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Analysis MAVPH 500 625929 05/22/23 21:07 SAB EET PENTotal/NA 5 mL 5 mL
Prep 504.1 625920 05/22/23 11:29 PG EET PENTotal/NA 36.8 mL 35 mL
Analysis 504.1 1 626155 05/23/23 10:20 PG EET PENTotal/NA
Prep 3010A 625508 05/19/23 07:10 KWN EET PENTotal/NA 50 mL 50 mL
Completed:05/19/23 12:05 ¹
Analysis 6010D 1 626305 05/24/23 00:14 BAW EET PENTotal/NA
Client Sample ID: Method Blank Lab Sample ID: MB 400-625508/1-A
Matrix: WaterDate Collected: N/A
Date Received: N/A
Prep 3010A KWN05/19/23 07:10 EET PEN625508
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 50 mL 50 mL
Completed:05/19/23 12:05 ¹
Analysis 6010D 1 626305 05/23/23 22:40 BAW EET PENTotal/NA
Client Sample ID: Method Blank Lab Sample ID: MB 400-625920/1-A
Matrix: WaterDate Collected: N/A
Date Received: N/A
Prep 504.1 PG05/22/23 11:29 EET PEN625920
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 35 mL 35 mL
Analysis 504.1 1 625961 05/22/23 14:26 PG EET PENTotal/NA
Eurofins Pensacola
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Lab Chronicle
Client: Terraquest Environmental Consultants, PC Job ID: 400-237880-1
Project/Site: JD's Country Store
Client Sample ID: Method Blank Lab Sample ID: MB 400-625929/3
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis MAVPH SAB05/22/23 13:241 EET PEN625929
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: Method Blank Lab Sample ID: MB 400-626667/3
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis MAVPH SAB05/26/23 11:251 EET PEN626667
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: Method Blank Lab Sample ID: MB 400-626874/4
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis SM6200-B BPO05/28/23 12:511 EET PEN626874
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: Method Blank Lab Sample ID: MB 400-626908/4
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis SM6200-B AGW05/29/23 10:101 EET PEN626908
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: Method Blank Lab Sample ID: MB 400-627151/4
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis SM6200-B AGW05/31/23 09:251 EET PEN627151
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: Method Blank Lab Sample ID: MB 400-627257/4
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis SM6200-B AGW05/31/23 16:561 EET PEN627257
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 400-625508/2-A
Matrix: WaterDate Collected: N/A
Date Received: N/A
Prep 3010A KWN05/19/23 07:10 EET PEN625508
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 50 mL 50 mL
Completed:05/19/23 12:05 ¹
Analysis 6010D 1 626305 05/23/23 22:46 BAW EET PENTotal/NA
Eurofins Pensacola
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Lab Chronicle
Client: Terraquest Environmental Consultants, PC Job ID: 400-237880-1
Project/Site: JD's Country Store
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 400-625920/2-A
Matrix: WaterDate Collected: N/A
Date Received: N/A
Prep 504.1 PG05/22/23 11:29 EET PEN625920
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 35 mL 35 mL
Analysis 504.1 1 625961 05/22/23 14:47 PG EET PENTotal/NA
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 400-625929/4
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis MAVPH SAB05/22/23 14:031 EET PEN625929
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 400-626667/4
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis MAVPH SAB05/26/23 12:281 EET PEN626667
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 400-626874/1002
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis SM6200-B BPO05/28/23 10:561 EET PEN626874
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 400-626908/1002
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis SM6200-B AGW05/29/23 08:571 EET PEN626908
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 400-627151/1002
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis SM6200-B AGW05/31/23 08:241 EET PEN627151
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 400-627257/1002
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis SM6200-B AGW05/31/23 15:571 EET PEN627257
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Eurofins Pensacola
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Lab Chronicle
Client: Terraquest Environmental Consultants, PC Job ID: 400-237880-1
Project/Site: JD's Country Store
Client Sample ID: Lab Control Sample Dup Lab Sample ID: LCSD 400-625920/3-A
Matrix: WaterDate Collected: N/A
Date Received: N/A
Prep 504.1 PG05/22/23 11:29 EET PEN625920
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 35 mL 35 mL
Analysis 504.1 1 625961 05/22/23 15:07 PG EET PENTotal/NA
Client Sample ID: Lab Control Sample Dup Lab Sample ID: LCSD 400-625929/5
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis MAVPH SAB05/22/23 14:411 EET PEN625929
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: Lab Control Sample Dup Lab Sample ID: LCSD 400-626667/5
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis MAVPH SAB05/26/23 12:591 EET PEN626667
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
¹ This procedure uses a method stipulated length of time for the process. Both start and end times are displayed.
Laboratory References:
EET PEN = Eurofins Pensacola, 3355 McLemore Drive, Pensacola, FL 32514, TEL [phone]
Eurofins Pensacola
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Method Summary
Job ID: 400-237880-1Client: Terraquest Environmental Consultants, PC
Project/Site: JD's Country Store
Method Method Description LaboratoryProtocol
SMSM6200-B Volatile Organic Compounds EET PEN
MA DEPMAVPHMassachusetts - Volatile Petroleum Hydrocarbons (GC)EET PEN
EPA-DW504.1 EDB, DBCP and 1,2,3-TCP (GC)EET PEN
SW8466010DMetals (ICP)EET PEN
SW8463010APreparation, Total Metals EET PEN
SW8465030BPurge and Trap EET PEN
EPA-DW504.1 Microextraction EET PEN
Protocol References:
EPA-DW = "Methods For The Determination Of Organic Compounds In Drinking Water", EPA/600/4-88/039, December 1988 And Its Supplements.
MA DEP = Massachusetts Department Of Environmental Protection
SM = "Standard Methods For The Examination Of Water And Wastewater"
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
EET PEN = Eurofins Pensacola, 3355 McLemore Drive, Pensacola, FL 32514, TEL [phone]
Eurofins Pensacola
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Accreditation/Certification Summary
Client: Terraquest Environmental Consultants, PC Job ID: 400-237880-1
Project/Site: JD's Country Store
Laboratory: Eurofins Pensacola
Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.
Authority Program Identification Number Expiration Date
North Carolina (WW/SW)State 314 12-31-23
Eurofins Pensacola
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Pa
g
e

5
7

o
f

5
8
6/
5
/
2
0
2
3
123456789101112131415
Login Sample Receipt Checklist
Client: Terraquest Environmental Consultants, PC Job Number: 400-237880-1
Login Number: 237880
Question Answer Comment
Creator: Whitley, Adrian
List Source: Eurofins Pensacola
List Number: 1
N/ARadioactivity wasn't checked or is </= background as measured by a survey
meter.
N/AThe cooler's custody seal, if present, is intact.
N/ASample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or
tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.4.1°C IR11
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate
HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
TrueSample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
TrueContainers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
Eurofins Pensacola
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