FA-819_15274_CA_MRP_20231002

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
October 2, 2023

Mr. Mike Haseltine
NCDEQ-UST Section
Fayetteville Regional Office
Systel Building
225 Green Street, Suite 714
Fayetteville, NC 28301-5043

Re: Ground Water Monitoring Report
July 2023
Former D. W. Tatum Grocery
7381 Taylor’s Bridge Highway
Clinton, Sampson County
North Carolina
Facility ID Number: 00-0-0000008167
Incident Number: 15274
GRI Project Number: 2081

Dear Mr. Haseltine,

Please find enclosed the referenced report for the abovementioned site.
If you have any questions, please contact Rae Brown at 704-845-4010.

Sincerely,
Geological Resources, Inc.

Leslie Maxtone-Graham
Administrative Assistant

Enclosure

Cc: Wellman Oil Company, Inc., file

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Ground Water Monitoring Report
July 2023
Former D.W. Tatum Grocery
7381 Taylor’s Bridge Highway
Clinton, Sampson County
North Carolina
Facility ID Number: 00-0-000008167
Incident Number: 15274
GRI Project Number: 2081

Prepared for:

Wellman Oil Company, Inc.
Post Office Box 780
Clinton, North Carolina 28329

October 2, 2023

Rae Troiano Brown, P. G.
Project Manager
Sharon Lowther
Report Writer

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: October 2, 2023 Former D.W. Tatum Grocery
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 2081
i
SITE INFORMATION
1. Site Identification
 Former D.W. Tatum Grocery (Facility ID 00-0-000008167)
 Incident Number 15274 – High Risk (H185R)
 Location of Source Area: 7381 Taylor’s Bridge Highway
Clinton, NC 28314
Sampson County
34.8655280°N, 78.2630560°W (Topographical Map)

2. Information about Contacts Associated with the Leaking UST System

UST/AST Owner
Wellman Oil Company, Inc.
Post Office Box 780
Clinton, NC 28329
[e-mail]
910-592-4135

UST/AST Operator
Wellman Oil Company, Inc.
Post Office Box 780
Clinton, NC 28329
[e-mail]
910-592-4135

Property Owner
Wanda B. Tatum
7335 Taylor’s Bridge Highway
Clinton, NC 28329
Email Unknown
Phone No. Unknown

Property Occupant
M&R Sales
7381 Taylor’s Bridge Highway
Clinton, NC 28314
Email Unknown
910-590-8436

Consultant/Contractor
Geological Resources, Inc.
3502 Hayes Road
Monroe, NC 28110
[e-mail]
704-845-4010

Analytical Laboratory
Waypoint Analytical, LLC
449 Springbrook Road
Charlotte, NC 28217
State Certification No. 402
704-529-6364
3. Information about Release
 Release was discovered on October 24, 1994.
 An unknown amount of product was released from the leaking UST System.
 Two 1,000-gallon gasoline, one 2,000-gallon gasoline, one 1,000-gallon diesel, and one 280-gallon
kerosene USTs were removed from the site in October 1994.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: October 2, 2023 Former D.W. Tatum Grocery
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 2081
ii
ACRONYMS
ACM: Asbestos Containing Materials
AFVR: Aggressive Fluid-Vapor Recovery
ARR: Acknowledgement of Report Receipt
AS: Air Sparging
AST: Aboveground Storage Tank
ASTM: American Society for Testing and
Materials
BGS: Below Ground Surface
CAP: Corrective Action Plan
CFR: Code of Federal Regulations
CSA: Comprehensive Site Assessment
DPE: Dual Phase Extraction
DRO: Total Petroleum Hydrocarbons Diesel
Range Organics
DWM: Division of Waste Management
DWR: Department of Water Resources
EPA: Environmental Protection Agency
EPH: Extractible Petroleum Hydrocarbons
ESA: Environmental Site Assessment
GCL: Gross Contamination Level
GRI: Geological Resources, Inc.
GRO: Total Petroleum Hydrocarbons
Gasoline Range Organics
LSA: Limited Site Assessment
MAC: Maximum Allowable Concentration
as specified in T15A NCAC 2L.0202
MADEP: Massachusetts Department of
Environmental Protection
MCC: Maximum Contaminant
Concentrations
MMPE: Mobile Multi-Phase Extraction
NAPL: Non-Aqueous Phase Liquid, “Free
Product”

NCDEQ: North Carolina Department of
Environmental Quality
NCDOT: North Carolina Department of
Transportation
NFA: Notice of No Further Action
NORR: Notice of Regulatory Requirements
NOV: Notice of Violation
NPDES: National Pollutant Discharge
Elimination System
NRP: Notice of Residual Petroleum
O&M: Operation and Maintenance
PAHs: Polynuclear Aromatic Hydrocarbons
PCA: Pre-Construction Assessment
RAL: Regulatory Action Level
SCLs: Soil Cleanup Level
SPCC: Spill Prevention Control and
Countermeasures
SVE: Soil Vapor Extraction
SVOCs: Semi-Volatile Organic Compounds
SWAP: Source Water Assessment and
Protection
SWPPP: Stormwater Pollution Prevention
Plan
TCLP: Toxicity Characteristic Leaching
Procedure (EPA Method SW-846
1311)
TOC: Top of Casing
TPH: Total Petroleum Hydrocarbons
USGS: United States Geological Survey
UST: Underground Storage Tank
UVF: Ultraviolet Fluorescence
VOCs: Volatile Organic Compounds
VPH: Volatile Petroleum Hydrocarbons

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: October 2, 2023 Former D.W. Tatum Grocery
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 2081
iii
EXECUTIVE SUMMARY
Former D.W. Tatum Grocery is located at 7381 Taylor’s Bridge Highway in Clinton, Sampson County, North
Carolina. The site is owned by Wanda B. Tatum and is currently vacant; there are two single-family
residences on the property. One 2,000-gallon gasoline, two 1,000-gallon gasoline, one 1,000-gallon diesel
and one 280-gallon kerosene USTs, associated dispensers, and product piping were removed from the site
in October 1994. A release was discovered during the October 1994 UST closure activities. The release
was assigned a risk classification of High due to the presence of two potable water supply wells within a
1,000-foot radius of the contaminant plume edge.

A Comprehensive Site Assessment was completed for the incident in between 2001 and 2004. A
Corrective Action Plan has not been developed for this incident.

An updated receptor survey was completed in spring 2021. According to the Sampson County GIS website,
municipal water is available to the site and surrounding area. Well surveys were sent to water supply
owners of WSW-3 and WSW-5. According to the survey response, the property at 327 Union School Road
(WSW-5) is connected to municipal water; and, WSW-5 is used for non-potable purposes. No response
was received from the property owner for WSW-3.

On July 31, 2023, nine shallow monitoring wells, eight intermediate monitoring wells, and two deep
monitoring wells were gauged, purged, and sampled. No free product was observed in the monitoring
wells prior to sampling. Concentrations of benzene, MTBE, and /or naphthalene that exceeded MACs
were reported in the ground water samples collected from MW-1, MW-24, and MW-25. All of the
reported contaminant concentrations were below the GCLs.

Based on this information, monitoring activities should continue at the site and a fate and transport model
should be included in the next ground water assessment report.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: October 2, 2023 Former D.W. Tatum Grocery
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 2081

TABLE OF CONTENTS
SITE INFORMATION ............................................................................................................................ i
ACRONYMS ........................................................................................................................................ ii
EXECUTIVE SUMMARY ...................................................................................................................... iii
1.0 SITE HISTORY AND CHARACTERIZATION ...................................................................................1
2.0 UPDATED RECEPTOR INFORMATION ........................................................................................1
3.0 PRESENTATION OF CURRENT SITE ASSESSMENT INFORMATION/ COMPARISON TO HISTORICAL
ASSESSMENT INFORMATION ...................................................................................................2
4.0 FREE PRODUCT REMOVAL ........................................................................................................3
5.0 NATURAL ATTENUATION / NATURAL SOURCE ZONE DEPLETION STATUS ..................................3
6.0 CONCLUSIONS .........................................................................................................................4
7.0 LIMITATIONS ...........................................................................................................................4
8.0 STATEMENTS AND CERTIFICATION ...........................................................................................4

FIGURES
Figure 1: Site Location Map
Figure 2: Site Vicinity Map
Figure 3: Site Map
Figure 4: Water Table Surface Map – Shallow Wells
Figure 5: Water Table Surface Map – Intermediate Wells
Figure 6: Ground Water Quality Map

TABLES
Table 1: Adjacent Property Owner Information
Table 2: Water Supply Well Information
Table 3: Well Construction and Gauging Information
Table 4: Summary of Ground Water Sample Analytical Results
Table 5: Summary of Field Parameters

APPENDICES
Appendix A: State Correspondence
Appendix B: Right-of-Access Documentation
Appendix D: Laboratory Report – Ground Water Samples

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: October 2, 2023 Former D.W. Tatum Grocery
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 2081
1
1.0 SITE HISTORY AND CHARACTERIZATION
Geological Resources, Inc. (GRI) presents the results of the July 2023 ground water sampling event. The
site is located at 7381 Taylor’s Bridge Highway in Clinton, Sampson County, North Carolina (Figure 1).
These activities were conducted in accordance with GRI Proposal No. 23-034, which was submitted to the
NCDEQ on March 9, 2023, and was approved as Task Authorization No. 15274-20 on March 14, 2023.
NCDEQ correspondence associated with the incident is included as Appendix A.

The site is owned by Wanda B. Tatum. The business is currently vacant; however, there are two single-
family residences on the property. According to available information, two 1,000-gallon gasoline, one
2,000-gallon gasoline, one 1,000-gallon diesel, and one 280-gallon kerosene USTs were removed from the
site on October 24, 1994. The Registered Tank Report is shown below:

Fifteen Type II monitoring wells, fourteen intermediate Type II monitoring wells, and three Type III
monitoring wells were installed at the site during previous ground water assessment and corrective action
activities. A Site Map showing the locations of the monitoring wells and the structures on-site has been
included as Figure 3. A Comprehensive Site Assessment was completed in 1995. To date, a CAP has not
been developed for this incident.
2.0 UPDATED RECEPTOR INFORMATION
An updated receptor survey was completed in spring 2021. According to the Sampson County GIS website,
municipal water is available to the site and surrounding area. Well surveys were sent to water supply
owners of WSW-3 and WSW-5. According to the survey response, the property at 327 Union School Road
(WSW-5) is connected to municipal water; and, WSW-5 is used for non-potable purposes. No response
was received from the property owner for WSW-3. A table summarizing the adjacent property owner

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: October 2, 2023 Former D.W. Tatum Grocery
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 2081
2
information is included as Table 1. Water Supply Well owner information is included as Table 2. A Site
Vicinity Map showing the locations of the water supply wells has been included as Figure 2.

Per the direction of NCDEQ, installation of monitoring wells in the former locations of MW-13 and MW-
16 was pursued which required site access from the current property owner for the well permit. However,
site access was denied. Therefore, no replacement wells were installed, and the requested scope of work
was reduced to ground water monitoring. A copy of the property denial is included in Appendix B.
3.0 PRESENTATION OF CURRENT SITE ASSESSMENT INFORMATION/ COMPARISON TO HISTORICAL
ASSESSMENT INFORMATION
On July 31, 2023, fourteen Type II monitoring wells (MW-1, MW-4, MW-5, MW-6, MW-9, MW-12, MW-
14, MW-15, MW-19, MW-21, MW-22, MW-23, MW-24, and MW-25) and three Type III monitoring wells
(TW-1 through TW-3) were gauged, purged, and sampled. Please note that MW-8, MW-11, MW-16
through MW-18 and MW-20 have been destroyed. MW-26 and MW-27 could not be located. Depths to
ground water in the Type II monitoring wells ranged from 5.09 feet to 11.51 feet. Ground water elevations
in the Type II monitoring wells ranged from 87.53 feet to 93.92 feet. Well construction and gauging
information is presented in Table 3. Ground water flow across the site was generally toward the
southwest in the shallow monitoring wells and generally toward the west in the intermediate monitoring
wells. Water Table Surface maps for the shallow and intermediate wells are included as Figures 4 and 5,
respectively. A summary of the current ground water gauging data is shown below:

Well ID
Screened
Interval
(x to y ft.
BGS)
Bottom of
Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(ft.)
Ground Water
Elevation
(ft.)
MW-1 4-14 14 99.04 5.72 93.32
MW-4 3-13 13 100.44 7.01 93.43
MW-5 4-14 14 100.16 6.49 93.67
MW-6 2-12 12 98.23 5.09 93.14
MW-9 3-13 13 100.08 6.71 93.37
MW-12 5-15 15 98.91 6.44 92.47
MW-14 5-15 15 99.48 5.56 93.92
MW-15 5-15 15 98.91 6.86 92.05
MW-19 25-30 30 98.52 8.61 89.91
MW-21 25-30 30 99.44 9.81 89.63
MW-22 5-15 15 100.07 9.36 90.71
MW-23 25-30 30 100.36 11.51 88.85
MW-24 25-30 30 97.82 6.64 91.18
MW-25 25-30 30 95.35 7.82 87.53
T-1 25-30 30 99.18 9.13 90.05
T-2 55-60 60 99.08 11.16 87.92
T-3 50-55 55 97.91 12.45 85.46

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: October 2, 2023 Former D.W. Tatum Grocery
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 2081
3
Ground water samples collected from the monitoring wells were submitted for laboratory analyses using
EPA Method 6200B. Concentrations of benzene, MTBE, and /or naphthalene that exceeded MACs were
reported in the ground water samples collected from MW-1, MW-24, and MW-25. All of the reported
contaminant concentrations were below the GCLs. A summary of the analytical results for ground water
samples collected on July 31, 2023 is presented in Table 4. A Ground Water Quality Map based on the
July 2023 data is included as Figure 6. A summary of the field parameters for ground water samples
collected in July 2023 is presented in Table 5. A complete report of laboratory analyses of the ground
water samples collected from the monitoring wells during the July 2023 sampling event has been included
as Appendix D. A summary of the current ground water analytical data is shown below:

Contaminant of
Concern 
Be
n
z
e
n
e

To
l
u
e
n
e

Et
h
y
l
b
e
n
z
e
n
e

Xy
l
e
n
e
s

MT
B
E

Na
p
h
t
h
a
l
e
n
e

Well ID
2L Standard (µg/l) 1 600 600 500 20 6
GCL (µg/l) 5,000 260,000 80,000 50,000 20,000 6,000
MW-1 0.916 2.62 40.7 24.1 <0.140 24.1
MW-4 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470
MW-5 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470
MW-6 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470
MW-9 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470
MW-12 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470
MW-14 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470
MW-15 <0.180 <0.220 <0.170 <0.210 <0.140 4.87
MW-19 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470
MW-21 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470
MW-22 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470
MW-23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470
MW-24 <0.180 0.266 J 0.549 <0.210 220 <0.470
MW-25 15.4 <2.20 <1.70 <2.10 4,440 <4.70
T-1 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470
T-2 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470
T-3 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470

The site is located in the Coastal Plain Physiographic Province of North Carolina. The water table has a
seasonal high depth to water of approximately one to five feet BGS. Since a CAP has not been developed
for the site, baseline contaminant mass calculations and milestones have not been established.
4.0 FREE PRODUCT REMOVAL
Free product has not been observed at the site.
5.0 NATURAL ATTENUATION / NATURAL SOURCE ZONE DEPLETION STATUS
No natural attenuation monitoring plan is currently in place at the site.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: October 2, 2023 Former D.W. Tatum Grocery
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 2081
4
6.0 CONCLUSIONS
 An updated receptor survey was completed in Spring 2021. According to the Sampson County
GIS website, municipal water is available to the site and surrounding area. One potable well
(WSW-3) remains in use.
 July 31, 2023, fourteen Type II monitoring and three Type III monitoring were gauged, purged,
and sampled. MW-8, MW-11, MW-16 through MW-18 and MW-20 have been destroyed. MW-
26 and MW-27 could not be located. Ground water flow across the site was generally toward the
southwest in the shallow monitoring wells and generally toward the west in the intermediate
monitoring wells.
 Concentrations of benzene, MTBE, and /or naphthalene that exceeded MACs were reported in
the ground water samples collected from MW-1, MW-24, and MW-25. All of the reported
contaminant concentrations were below the GCLs.
 Based on this information, ground water monitoring activities should continue at the site on an
annual basis. A fate and transport model should be included in the next ground water assessment
report.
7.0 LIMITATIONS
This report has been prepared for the exclusive use of Wellman Oil Company, Inc. for specific application
to the referenced site in Sampson County, North Carolina. The assessment was conducted based on the
scope of work and level of effort desired by NCDEQ and with resources adequate only for that scope of
work. Our findings have been developed in accordance with generally accepted standards of
environmental practices in the State of North Carolina, available information, and our professional
judgment. No other warranty is expressed or implied.

The data that are presented in this report are indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would
be interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from these data.
8.0 STATEMENTS AND CERTIFICATION
1 Enter the date the monitoring report was due. N/A Will this report be submitted after the
established due date? N/A
YES NO
2 Was any required information from the above template missing from this report? YES NO
IF the answer to question #1 or# 2 is “YES”, please provide additional information in this cell to explain
what was missing and why.
3 If applicable, will any of the proposed attenuation milestones under the schedule approved
in the Corrective Action Plan not be met? (within a reasonable margin of error)
YES NO

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: October 2, 2023 Former D.W. Tatum Grocery
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 2081
5
IF the answer to question #3 is “NO”, skip to the certification under #8 below.
IF the answer to question #3 is “YES”, please generally describe in this cell the possible reason(s) and
outline proposed remedies. (This should be described in more detail in the report text above.)

N/A
4 Does any known or suspected source zone soil contamination or free product remain
outside of the assessed area that could be inhibiting natural attenuation?
YES NO
5 Has there been an unexpected increase in contaminant mass sufficient to suggest a
potential new release from a separate onsite or offsite source?
YES NO
IF the answer to either question #4 or #5 is “YES”, generally describe in this cell any actions
recommended to further assess or clean up this known or suspected source. (This should be described
in more detail in the report text above.)

6 Certification:
I, Rae Troiano Brown, a Licensed Geologist for Geological Resources, Inc., do certify that the information
contained in this report is correct and accurate to the best of my knowledge.

Geological Resources, Inc. is licensed to practice engineering and geology in North Carolina. The
certification number of the company or corporation is C-2727/C-127.

FIGURES
"J S
S
S
S
S
S
S
S
S
S
SITE
17064772003
17079204001
17011150203
17015405802
17064660008
17064660010
17099282001
17002774001
17018033002
WSW-9
WSW-8
WSW-7
WSW-6
WSW-5
WSW-4
WSW-2
WSW-1
WSW-11
WSW-10
WSW-3
RIVER RD
UNION SCHOOL RD
TAYLORS BRIDGE HWY
FIGURE 2: SITE VICINITY MAPD.W.TATUM GROCERY7381 TAYLORS BRIDGE HIGHWAYCLINTON, SAMPSON COUNTYNORTH CAROLINAINCIDENT NO. 15274GRI NO. 2081
PREPARED BY:GEOLOGICAL RESOURCES, INC.ORIGINAL DATE: MARCH 7, 2017JULY 7, 2021
³
0 300150Feet1 inch = 300 feet
1,500-FOOT RADIUS
1,000-FOOT RADIUS 250-FOOT RADIUS
500-FOOT RADIUS
LEGEND
S Inactive Water Supply Well
"J Potable Water Supply Well
Water Line
Centerlines
Adjacent Properties and Well Owners
nc_sampson_parcels_poly

TABLES
Date: 06/16/2021
1709-928-2001 (Site)
1706-477-2003
1700-277-4001
1706-466-0008
1706-466-0010
1701-540-5802
Note:
• Properties are keyed to Figure 2
Mark A. Tatum 7324 Taylors Bridge Highway
Clinton, North Carolina 28328
Christine E. Matthis 1120 Union School Road
Clinton, North Carolina 28328
Christopher K. Matthis 161 Raven Lane
Clinton, North Carolina 28328
Hazelyn D. Williams 1730 Bass Lake Road
Roseboro, North Carolina 28382
7335 Taylors Bridge Highway
Clinton, North Carolina 28328
TABLE 1
ADJACENT PROPERTY OWNERS/OCCUPANTS
DW TATUM GROCERY (INCIDENT NO. 15274)
Facility ID # : 00-0-0000008167
Tax Parcel Number/
Map ID Owner/ Occupant Name Address
Wanda B. Tatum
Date : 06/16/2021 Facility ID #: 00-0-0000008167
Well ID PIN Number Well Owner/ User
(indicate which)Owner Address Well Address Well Use (Potable/
Agricultural, etc.)
Well Depth
(ft BGS)
Type of Well
(Drilled/Bored)
Well Casing
Depth
(ft. BGS)
Well Screen
Interval
(x to y ft. BGS)
Distance from
source area of
release
(ft.)
WSW-2 1709-928-2001 Wanda B. Tatum 7335 Taylors Bridge Road
Clinton, North Carolina 28328
7381 Taylors Bridge Road
Clinton, North Carolina 28328 Not in use/well caved in Unknown Unknown Unknown Unknown ~210'
WSW-3 1706-477-2003 Wanda B. Tatum 7335 Taylors Bridge Road
Clinton, North Carolina 28328
7414 Taylors Bridge Road
Clinton, North Carolina 28328 Potable/Unconfirmed 110' Unknown Unknown Unknown ~700'
WSW-4 1700-277-4001 Mark A. Tatum 7630 Taylors Bridge Road
Clinton, North Carolina 28328
7324 Taylors Bridge Road
Clinton, North Carolina 28328 Capped off/ not in use 40' Unknown Unknown Unknown ~570
WSW-5 1707-920-4001 Billy R. Peterson 327 Union School Road
Clinton, North Carolina 28328
327 Union School Road
Clinton, North Carolina 28328 Irrigation 300' Unknown Unknown Unknown ~940'
Notes:
• Water supply wells are keyed to Figure 2.
• Ft. BGS : Feet below ground surface
~105'Unknown Unknown
TABLE 2
WATER SUPPLY WELL INFORMATION
DW TATUM GROCEY (INCIDENT NO. 15274)
WSW-1 1709-928-2001 Wanda B. Tatum 7335 Taylors Bridge Road
Clinton, North Carolina 28328
7381 Taylors Bridge Road
Clinton, North Carolina 28328 Not in use/disconnected 157' Unknown
Page 1 of 1
Date: 08/07/2023 Facility ID#: 00-0-000008167
06/02/03 1.44 97.60
06/03/04 3.93 95.11
10/17/07 9.42 89.62
04/30/08 3.44 95.60
12/04/08 3.95 95.09
10/06/09 8.72 90.32
12/28/10 6.12 92.92
07/06/11 7.89 91.15
07/06/12 7.33 91.71
07/10/13 1.97 97.07
12/05/13 8.24 90.80
06/04/14 5.07 93.97
12/04/14 5.26 93.78
05/06/15 2.47 96.57
07/14/16 5.70 93.34
02/21/17 3.62 95.42
07/10/19 4.91 94.13
03/09/21 1.51 97.53
07/31/23 5.72 93.32
06/02/03 0.83 96.67
06/03/04 2.82 94.68
10/17/07 NM NM
04/30/08 NM NM
12/04/08 2.66 94.84
10/06/09 7.45 90.05
12/28/10 4.58 92.92
07/06/11 NM NM
07/10/13 NM NM
12/05/13 NM NM
07/14/16 NM NM
06/02/03 0.82 96.87
06/03/04 3.12 94.57
10/17/07 7.95 89.74
04/30/08 2.65 95.04
12/04/08 2.84 94.85
10/06/09 7.62 90.07
12/28/10 4.74 92.95
07/06/11 NM NM
07/10/13 NM NM
12/05/13 NM NM
07/14/16 NM NM
06/02/03 2.32 98.12
06/03/04 5.04 95.40
10/17/07 NM NM
04/30/08 NM NM
12/04/08 NM NM
10/06/09 NM NM
12/28/10 NM NM
07/06/11 NM NM
07/10/13 NM NM
12/05/13 NM NM
07/14/16 6.88 93.56
02/21/17 4.84 95.60
07/10/19 6.24 94.20
07/31/23 7.01 93.43
06/02/03 1.35 98.81
06/03/04 NM NM
10/17/07 NM NM
04/30/08 NM NM
12/04/08 NM NM
10/06/09 NM NM
12/28/10 NM NM
07/06/11 NM NM
07/10/13 NM NM
12/05/13 NM NM
07/14/16 6.56 93.60
02/21/17 4.16 96.00
07/10/19 5.97 94.19
07/31/23 6.49 93.67
3-13 13 100.44
MW-5 08/02/01 4 4-14 14 100.16
Destroyed
Destroyed
99.04144-144
2-122MW-2 08/01/01
MW-4 08/02/01 3
TABLE 3
WELL CONSTRUCTION AND GAUGING INFORMATION
D.W. TATUM GROCERY (INCIDENT NO. 15274)
NotesWell ID
Bottom of
Well
(ft. BGS)
Depth to Water
from Top of
Casing
(ft.)
Ground Water
Elevation*
(ft.)
Date Installed
(mm/dd/yy)
Date Water
Level Measured
(mm/dd/yy)
Well Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft. BGS)
Top of Casing
Elevation*
(ft.)
08/01/01 2 122-12
06/27/01MW-1
MW-3
12 97.50
97.69
Page 1 of 8
Date: 08/07/2023 Facility ID#: 00-0-000008167
TABLE 3
WELL CONSTRUCTION AND GAUGING INFORMATION
D.W. TATUM GROCERY (INCIDENT NO. 15274)
NotesWell ID
Bottom of
Well
(ft. BGS)
Depth to Water
from Top of
Casing
(ft.)
Ground Water
Elevation*
(ft.)
Date Installed
(mm/dd/yy)
Date Water
Level Measured
(mm/dd/yy)
Well Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft. BGS)
Top of Casing
Elevation*
(ft.)
06/02/03 0.88 97.35
06/03/04 3.14 95.09
10/17/07 NM NM
04/30/08 NM NM
12/04/08 NM NM
10/06/09 NM NM
12/28/10 NM NM
07/06/11 NM NM
07/06/12 6.43 91.80
07/10/13 1.31 96.92
12/05/13 7.29 90.94
06/04/14 4.29 93.94
12/04/14 4.29 93.94
05/06/15 1.72 96.51
07/14/16 4.82 93.41
02/21/17 2.77 95.46
07/10/19 4.13 94.10
07/31/23 5.09 93.14
06/02/03 0.40 96.44
06/03/04 2.17 94.67
10/18/07 5.63 91.21
04/30/08 NM NM
12/04/08 NM NM
10/06/09 NM NM
12/28/10 NM NM
07/06/11 NM NM
07/10/13 NM NM
12/05/13 NM NM
07/14/16 NM NM
06/02/03 0.20 95.54
06/03/04 1.93 93.81
10/17/07 NM NM
04/30/08 NM NM
12/04/08 1.52 94.22
10/06/09 6.34 89.40
12/28/10 3.21 92.53
07/06/11 NM NM
07/31/23 NM NM
06/02/03 2.32 97.76
06/03/04 NM NM
10/17/07 NM NM
04/30/08 NM NM
12/04/08 NM NM
10/06/09 NM NM
12/28/10 NM NM
07/06/11 NM NM
07/10/13 NM NM
12/05/13 NM NM
07/14/16 6.62 93.46
02/21/17 4.66 95.42
07/10/19 5.92 94.16
07/31/23 6.71 93.37
06/02/03 1.02 94.87
06/03/04 1.94 93.95
10/18/07 5.81 90.08
04/30/08 NM NM
Destroyed
122-12
MW-6 11/13/01 2 2-12 12 98.23
Destroyed
MW-8 11/13/01 2 2-12 12 95.74
MW-9 11/14/01 3
Destroyed
3-13 13 100.08
MW-10
11/13/01MW-7
01/30/02
2
2 95.89
2-12 96.8412
Page 2 of 8
Date: 08/07/2023 Facility ID#: 00-0-000008167
TABLE 3
WELL CONSTRUCTION AND GAUGING INFORMATION
D.W. TATUM GROCERY (INCIDENT NO. 15274)
NotesWell ID
Bottom of
Well
(ft. BGS)
Depth to Water
from Top of
Casing
(ft.)
Ground Water
Elevation*
(ft.)
Date Installed
(mm/dd/yy)
Date Water
Level Measured
(mm/dd/yy)
Well Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft. BGS)
Top of Casing
Elevation*
(ft.)
06/02/03 0.62 94.73
06/03/04 2.52 92.83
10/17/07 NM NM
04/30/08 NM NM
12/04/08 NM NM
10/06/09 NM NM
12/28/10 NM NM
07/06/11 NM NM
07/10/13 NM NM
12/05/13 NM NM
07/14/16 NM NM
02/21/17 NM NM
07/10/19 NM NM
03/09/21 0.50 94.85
07/31/23 NM NM
06/02/03 2.58 96.33
06/03/04 NM NM
10/17/07 NM NM
04/30/08 NM NM
12/04/08 NM NM
10/06/09 9.40 89.51
12/28/10 6.33 92.58
07/06/11 8.11 90.80
07/06/12 7.94 90.97
07/10/13 3.73 95.18
12/05/13 8.77 90.14
06/04/14 5.72 93.19
12/04/14 5.78 93.13
05/06/15 3.55 95.36
07/14/16 6.35 92.56
02/21/17 4.54 94.37
07/10/19 5.61 93.30
07/31/23 6.44 92.47
06/02/03 0.98 95.42
06/03/04 4.35 92.05
10/17/07 8.92 87.48
04/30/08 3.98 92.42
12/04/08 4.55 91.85
10/06/09 8.31 88.09
12/29/10 NM NM
06/02/03 1.70 97.78
06/03/04 4.31 95.17
10/17/07 NM NM
04/30/08 NM NM
12/04/08 NM NM
10/06/09 NM NM
12/28/10 NM NM
07/06/11 NM NM
07/10/13 NM NM
12/05/13 NM NM
07/14/16 6.04 93.44
02/21/17 4.25 95.23
07/10/19 4.90 94.58
07/31/23 5.56 93.92
Destroyed
DestroyedMW-13 01/31/02
MW-14
MW-12 01/30/02 5
25
15 98.91
5-15 15 99.48
96.4025-30
01/31/02 5
5-15
30
95.35122-12201/30/02MW-11
Page 3 of 8
Date: 08/07/2023 Facility ID#: 00-0-000008167
TABLE 3
WELL CONSTRUCTION AND GAUGING INFORMATION
D.W. TATUM GROCERY (INCIDENT NO. 15274)
NotesWell ID
Bottom of
Well
(ft. BGS)
Depth to Water
from Top of
Casing
(ft.)
Ground Water
Elevation*
(ft.)
Date Installed
(mm/dd/yy)
Date Water
Level Measured
(mm/dd/yy)
Well Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft. BGS)
Top of Casing
Elevation*
(ft.)
06/02/03 3.02 95.89
06/03/04 4.98 93.93
10/17/07 NM NM
04/30/08 NM NM
12/04/08 NM NM
10/06/09 NM NM
12/28/10 NM NM
07/06/11 NM NM
07/06/12 7.70 91.21
07/10/13 3.33 95.58
12/05/13 8.13 90.78
06/04/14 5.81 93.10
12/04/14 5.53 93.38
05/06/15 3.77 95.14
07/14/16 6.41 92.50
02/21/17 4.54 94.37
07/10/19 5.73 93.18
03/09/21 3.12 95.79
07/31/23 6.86 92.05
06/02/03 1.32 94.40
06/03/04 4.62 91.10
10/17/07 9.00 86.72
04/30/08 4.22 91.50
12/04/08 4.69 91.03
10/06/09 8.34 87.38
12/28/10 6.16 89.56
07/06/11 NM NM
07/10/13 NM NM
12/05/13 NM NM
07/14/16 NM NM
07/31/23 NM NM
06/02/03 2.87 94.83
06/03/04 6.15 91.55
10/17/07 10.61 87.09
04/30/08 5.64 92.06
12/04/08 6.14 91.56
10/06/09 9.79 87.91
12/28/10 NM NM
07/06/11 NM NM
07/10/13 NM NM
12/05/13 NM NM
07/14/16 NM NM
07/31/23 NM NM
06/02/03 1.17 95.63
06/03/04 NM NM
10/17/07 9.24 87.56
04/30/08 4.25 92.55
12/04/08 4.94 91.86
10/06/09 8.63 88.17
12/29/10 NM NM
07/06/11 NM NM
07/10/13 NM NM
12/05/13 NM NM
07/14/16 NM NM
07/31/23 NM NM
Destroyed
98.91
Destroyed
Destroyed
MW-15
MW-16 02/01/02 25
MW-17 02/01/02
MW-18
30 97.70
25-30 30 96.80
155-15
25-30 30 95.72
25
501/31/02
04/30/02 25
25-30
Page 4 of 8
Date: 08/07/2023 Facility ID#: 00-0-000008167
TABLE 3
WELL CONSTRUCTION AND GAUGING INFORMATION
D.W. TATUM GROCERY (INCIDENT NO. 15274)
NotesWell ID
Bottom of
Well
(ft. BGS)
Depth to Water
from Top of
Casing
(ft.)
Ground Water
Elevation*
(ft.)
Date Installed
(mm/dd/yy)
Date Water
Level Measured
(mm/dd/yy)
Well Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft. BGS)
Top of Casing
Elevation*
(ft.)
06/02/03 2.43 96.09
06/03/04 6.15 92.37
10/17/07 9.91 88.61
04/30/08 5.80 92.72
12/04/08 6.52 92.00
10/06/09 10.17 88.35
12/29/10 7.50 91.02
07/06/11 9.49 89.03
07/06/12 9.03 89.49
07/10/13 4.57 93.95
12/05/13 9.69 88.83
06/04/14 7.29 91.23
12/04/14 7.36 91.16
05/06/15 4.44 94.08
07/14/16 7.70 90.82
02/21/17 5.94 92.58
07/10/19 7.48 91.04
07/31/23 8.61 89.91
06/02/03 1.45 95.45
06/03/04 4.90 92.00
10/17/07 NM NM
04/30/08 NM NM
12/04/08 NM NM
10/06/09 NM NM
12/29/10 6.74 90.16
07/06/11 8.18 88.72
07/06/12 7.78 89.12
07/10/13 3.17 93.73
12/05/13 8.41 88.49
06/04/14 6.08 90.82
12/04/14 6.00 90.90
05/06/15 3.27 93.63
01/19/16 2.51 94.39
07/14/16 NM NM
02/21/17 NM NM
07/10/19 NM NM
07/31/23 NM NM
06/02/03 5.19 94.25
06/03/04 7.67 91.77
10/17/07 11.11 88.33
04/30/08 7.94 91.50
12/04/08 8.00 91.44
10/06/09 11.51 87.93
12/28/10 8.23 91.21
07/06/11 10.51 88.93
07/06/12 NM NM
07/10/13 6.13 93.31
12/05/13 11.77 87.67
06/04/14 8.23 91.21
12/04/14 8.70 90.74
05/06/15 6.29 93.15
07/14/16 9.35 90.09
02/21/17 7.69 91.75
07/10/19 8.39 91.05
07/31/23 9.81 89.63
06/02/03 3.33 96.74
06/03/04 5.99 94.08
10/17/07 NM NM
04/30/08 NM NM
12/04/08 NM NM
10/06/09 NM NM
12/28/10 NM NM
07/06/11 NM NM
07/10/13 NM NM
12/05/13 NM NM
07/14/16 7.55 92.52
02/21/17 NM NM
07/10/19 6.88 93.19
07/31/23 9.36 90.71
MW-22 05/03/02 5 5-15 15 100.07
Destroyed
25-30 30 98.52
25
MW-21 05/02/02 25 25-30 30 99.44
MW-20 05/01/02
MW-19 05/01/02 25
96.9025-30 30
Page 5 of 8
Date: 08/07/2023 Facility ID#: 00-0-000008167
TABLE 3
WELL CONSTRUCTION AND GAUGING INFORMATION
D.W. TATUM GROCERY (INCIDENT NO. 15274)
NotesWell ID
Bottom of
Well
(ft. BGS)
Depth to Water
from Top of
Casing
(ft.)
Ground Water
Elevation*
(ft.)
Date Installed
(mm/dd/yy)
Date Water
Level Measured
(mm/dd/yy)
Well Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft. BGS)
Top of Casing
Elevation*
(ft.)
06/02/03 6.65 93.71
06/03/04 9.84 90.52
10/17/07 14.02 86.34
04/30/08 9.39 90.97
12/04/08 NM NM
10/06/09 13.23 87.13
12/29/10 11.23 89.13
07/06/11 9.37 90.99
07/06/12 12.00 88.36
07/10/13 7.90 92.46
12/05/13 12.82 87.54
06/04/14 10.84 89.52
12/04/14 10.60 89.76
05/06/15 8.34 92.02
07/14/16 11.30 89.06
02/21/17 NM NM
07/10/19 10.82 89.54
03/09/21 6.83 93.53
07/31/23 11.51 88.85
06/02/03 4.64 93.18
06/03/04 7.66 90.16
10/17/07 11.85 85.97
04/30/08 7.25 90.57
12/04/08 7.64 90.18
10/06/09 11.07 86.75
12/29/10 9.06 88.76
07/06/11 10.37 87.45
07/06/12 9.90 87.92
07/10/13 5.61 92.21
12/05/13 10.67 87.15
06/04/14 8.52 89.30
12/04/14 8.30 89.52
05/06/15 6.13 91.69
01/19/16 5.52 92.30
07/14/16 9.10 88.72
02/21/17 10.18 87.64
07/10/19 8.58 89.24
03/09/21 4.57 93.25
07/31/23 6.64 91.18
06/02/03 2.61 92.74
06/03/04 6.01 89.34
10/18/07 10.14 85.21
04/30/08 5.68 89.67
12/04/08 6.17 89.18
10/06/09 9.40 85.95
12/29/10 7.57 87.78
07/06/11 8.68 86.67
07/06/12 8.25 87.10
07/10/13 NM NM
12/05/13 NM NM
06/04/14 NM NM
12/04/14 6.76 88.59
05/06/15 4.53 90.82
01/19/16 4.86 90.49
07/14/16 7.46 87.89
02/21/17 2.95 92.40
07/10/19 NM NM
03/09/21 2.85 92.50
07/31/23 7.82 87.53
25-30
MW-25
MW-24
95.35
100.363025-30MW-23
05/07/02 25
2505/07/02
30 97.82
3025-302511/19/02
Page 6 of 8
Date: 08/07/2023 Facility ID#: 00-0-000008167
TABLE 3
WELL CONSTRUCTION AND GAUGING INFORMATION
D.W. TATUM GROCERY (INCIDENT NO. 15274)
NotesWell ID
Bottom of
Well
(ft. BGS)
Depth to Water
from Top of
Casing
(ft.)
Ground Water
Elevation*
(ft.)
Date Installed
(mm/dd/yy)
Date Water
Level Measured
(mm/dd/yy)
Well Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft. BGS)
Top of Casing
Elevation*
(ft.)
06/02/03 2.28 96.07
06/03/04 NM NM
10/17/07 10.59 87.76
04/30/08 5.50 92.85
12/04/08 6.32 92.03
10/06/09 9.98 88.37
12/29/10 8.03 90.32
07/06/11 9.32 89.03
07/06/12 8.86 89.49
07/10/13 4.35 94.00
12/05/13 9.53 88.82
06/04/14 7.15 91.20
12/04/14 7.20 91.15
05/06/15 4.20 94.15
07/14/16 7.48 90.87
02/21/17 5.69 92.66
07/10/19 7.20 91.15
07/31/23 NM NM
06/02/03 4.72 92.68
06/03/04 8.26 89.14
10/17/07 NM NM
04/30/08 NM NM
12/04/08 NM NM
10/06/09 11.48 85.92
12/29/10 9.76 87.64
07/06/11 11.11 86.29
07/06/12 10.60 86.80
07/10/13 5.80 91.60
12/05/13 NM NM
06/04/14 9.44 87.96
12/04/14 8.98 88.42
05/06/15 6.86 90.54
01/19/16 6.03 91.37
07/14/16 9.95 87.45
02/21/17 8.18 89.22
07/10/19 NM NM
07/31/23 NM NM
06/03/04 6.69 88.65
10/17/07 NM NM
04/30/08 NM NM
12/04/08 NM NM
10/06/09 NM NM
10/28/10 NM NM
07/06/11 NM NM
07/10/13 NM NM
12/05/13 NM NM
06/03/04 5.82 89.05
10/17/07 NM NM
04/30/08 NM NM
12/04/08 NM NM
10/06/09 NM NM
12/29/10 NM NM
07/06/11 NM NM
07/10/13 NM NM
12/05/13 NM NM
07/14/16 NM NM
98.35
MW-27 05/16/03 25.5 25.5-30.5 30.5 97.40
MW-29 20
30 95.34MW-28 06/07/04 20
MW-26
20-30
06/07/04
25-3003/05/03 25
Destroyed
30
94.873020-30
Page 7 of 8
Date: 08/07/2023 Facility ID#: 00-0-000008167
TABLE 3
WELL CONSTRUCTION AND GAUGING INFORMATION
D.W. TATUM GROCERY (INCIDENT NO. 15274)
NotesWell ID
Bottom of
Well
(ft. BGS)
Depth to Water
from Top of
Casing
(ft.)
Ground Water
Elevation*
(ft.)
Date Installed
(mm/dd/yy)
Date Water
Level Measured
(mm/dd/yy)
Well Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft. BGS)
Top of Casing
Elevation*
(ft.)
06/02/03 3.55 95.63
06/03/04 5.88 93.30
10/17/07 11.52 87.66
04/30/08 6.55 92.63
12/04/08 7.15 92.03
10/06/09 10.82 88.36
12/28/10 8.56 90.62
07/06/11 10.08 89.10
07/06/12 9.74 89.44
07/10/13 5.23 93.95
12/05/13 10.38 88.80
06/04/14 7.98 91.20
12/04/14 8.03 91.15
05/06/15 5.33 93.85
07/14/16 8.45 90.73
02/21/17 6.72 92.46
07/10/19 8.09 91.09
07/31/23 9.13 90.05
06/02/03 6.32 92.76
06/03/04 9.62 89.46
10/17/07 NM NM
04/30/08 NM NM
12/04/08 NM NM
10/06/09 NM NM
12/28/10 NM NM
07/06/11 NM NM
07/10/13 NM NM
12/05/13 NM NM
07/14/16 11.42 87.66
02/21/17 10.48 88.60
07/10/19 10.20 88.88
07/31/23 11.16 87.92
06/02/03 6.90 91.01
06/03/04 10.17 87.74
10/17/07 13.79 84.12
04/30/08 10.35 87.56
12/04/08 10.77 87.14
10/06/09 13.31 84.60
12/29/10 12.02 85.89
07/06/11 13.25 84.66
07/06/12 12.71 85.20
07/10/13 8.37 89.54
12/05/13 12.34 85.57
06/04/14 13.36 84.55
12/04/14 11.28 86.63
05/06/15 8.76 89.15
07/14/16 11.76 86.15
02/21/17 7.47 90.44
07/10/19 11.55 86.36
07/31/23 12.45 85.46
Notes:
• * : Reference point for elevation measurements, elevations relative to a temporary benchmark with an assumed elevation 100.00 ft.
• ** : If free product is present in a well, ground water should be calculated by: [Top of Casing Elevation - Depth to Water] +
[free product thickness x 0.8581]
• ft. BGS : feet below ground surface
• NM: Not measured.
55 97.91T-3 11/15/02 50 50-55
T-2 11/15/01 55 55-60 60 99.08
T-1 08/01/01 25 25-30 30 99.18
Page 8 of 8
Facility ID#: 00-0-000008167
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 70 70 70 25 70 400 400
5,000 260,000 80,000 50,000 20,000 6,000 5,900 30,500 70,000 11,700 26,100 28,500 24,100
06/29/01 4,500 22,000 2,900 14,100 <800 860 NR NR <400 NR NR NR NR
06/03/04 95 2,300 2,400 14,200 <50 1,800 NR NR <50 NR NR NR NR
10/17/07 1,820 43,700 2,860 12,000 <25.0 1,190 47.5 176 <25.0 <25.0 400 3,740 1,060
04/30/08 52.5 837 1,070 6,890 <50 1,250 48.5 I 125 <250 95.0 300 4,210 1,080
12/04/08 11 J 410 930 4,800 <5.0 1200 B <8.5 110 <10 <10 310 4,100 1,000
10/06/09 952 12,300 2,620 11,300 <25.0 1,010 <18.0 136 <20.0 <20.0 327 3,580 957
12/28/10 195 2,540 1,100 4,090 <25.0 1,280 311 95.6 J <20.0 <20.0 292 3,120 853
07/06/11 788 12,800 1,440 5,460 <65 663 <50 <50 <54 <50 118 J 1,320 335
07/06/12 316 3,600 2,230 11,610 <13 1,150 26.5 J 88.1 <11 <10 228 3,030 761
07/10/13 0.25 J 0.43 J 1.8 4.2 <0.10 2.8 0.70 0.40 J <0.10 0.19 J 1.9 15.5 4.9
12/05/13 308 3,130 317 1,130 <0.10 194 25.9 17.4 <0.10 7.6 49.9 J 367 99.9
06/04/14 0.97 8.1 10.9 39.0 <0.10 16.5 1.1 1.1 <0.10 0.26 J 3.6 27.6 5.2
12/04/14 12 111 27.5 74.7 <0.10 68.3 2.4 3.7 <0.10 0.6 10 133 7.9
05/06/15 <0.17 <0.17 <0.15 <0.43 <0.16 0.19 J <0.14 <0.12 <0.16 <0.12 <0.16 0.34 J <0.14
07/14/16 30.7 417 422 2,070 <1.3 590 2.6 J 35.5 <1.3 1.5 J 71.4 953 183
02/21/17 <0.13 0.17 J <0.13 1.3 J <0.13 1.4 <0.13 <0.13 <0.13 <0.13 <0.13 0.82 <0.13
07/10/19 5.4 88.7 81.7 130 <0.13 69.1 0.89 4.4 <0.13 0.30 J 10.7 118 4.1
03/09/21 122 18.7 18.9 34.2 <0.31 2.1 3.9 37.4 <0.31 <0.31 98.6 0.80 J 1.0 J
07/31/23 0.916 2.62 40.7 24.1 <0.140 24.1 0.862 5.32 <0.500 0.549 8.66 93.7 5.59
08/03/01 320 580 610 750 <40 300 NR NR <20 NR NR NR NR
06/03/04 22 65 140 380 <10 110 NR NR <10 NR NR NR NR
10/17/07 NS NS NS NS NS NS NS NS NS NS NS NS NS
04/30/08 NS NS NS NS NS NS NS NS NS NS NS NS NS
12/04/08 2.3 J 0.73 J 2.4 J 8.0 J <0.50 8.6 B <0.85 0.73 J <1.0 <1.0 1.2 J 12 6.7
10/06/09 42.0 2.20 70.4 42.4 <0.250 73.9 <0.180 23.5 <0.200 0.715 J 24.4 60.4 9.55
12/28/10 25.0 7.12 96.2 22.9 <0.500 182 1.22 J 12.5 <0.400 <0.400 20.4 38.8 0.485 J
07/06/11 NS NS NS NS NS NS NS NS NS NS NS NS NS
08/03/01 660 3,400 660 5,400 260 440 NR NR <50 NR NR NR NR
06/03/04 850 5,000 930 4,900 <50 510 NR NR <50 NR NR NR NR
10/17/07 126 17.7 112 40.9 0.510 33.0 <0.500 7.21 <0.500 1.09 11.6 26.6 <0.500
04/30/08 1.50 13.3 5.25 19.4 <1.0 2.89 0.520 I 0.920 I <5.0 0.750 I 2.21 13.1 3.98
12/04/08 <0.60 <0.70 <0.50 <1.0 <0.50 2.0 JB <0.85 <0.55 <1.0 <1.0 <0.75 <0.70 <0.50
10/06/09 189 557 260 505 <2.50 146 <1.80 28.1 <2.00 <2.00 41.7 535 50.9
12/28/10 2.02 2.66 28.9 0.760 J <0.250 25.6 5.30 2.34 <0.200 <0.200 2.43 9.70 <0.180
07/06/11 NS NS NS NS NS NS NS NS NS NS NS NS NS
08/03/01 <1 <1 <1 <4 <2 <1 NR NR <1 NR NR NR NR
06/03/04 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 NR NR <1.0 NR NR NR NR
10/17/07 NS NS NS NS NS NS NS NS NS NS NS NS NS
07/14/16 <0.13 <0.13 <0.13 <0.31 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
02/21/17 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/10/19 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/31/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.180 <0.180 <0.500 <0.089 <0.190 <0.190 <0.180
08/03/01 <1 <1 <1 <4 <2 <1 NR NR <1 NR NR NR NR
06/03/04 NS NS NS NS NS NS NR NR NS NR NR NR NR
07/14/16 <0.13 <0.13 <0.13 <0.31 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
02/21/17 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/10/19 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/31/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.180 <0.180 <0.500 <0.089 <0.190 <0.190 <0.180
MW-5
Analytical Method EPA Methods 601/602, 6210D or 6200B
1,
3
,
5
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
Et
h
y
l
b
e
n
z
e
n
e
Be
n
z
e
n
e
1,
2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
p-
I
s
o
p
r
o
p
y
l
t
o
l
u
e
n
e
To
l
u
e
n
e
Na
p
h
t
h
a
l
e
n
e
MT
B
E
MAC (mg/l)
GCL (mg/l)
Xy
l
e
n
e
s
TABLE 4
GROUND WATER SAMPLE ANALYTICAL RESULTS
D.W. TATUM GROCERY (INCIDENT NO. 15274)
Date: 08/10/2023
Contaminant of
Concern
IP
E
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e
n-
B
u
t
y
l
b
e
n
z
e
n
e
n-
P
r
o
p
y
l
b
e
n
z
e
n
e
MW-1
MW-2
MW-3
MW-4
Page 1 of 9
Facility ID#: 00-0-000008167
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 70 70 70 25 70 400 400
5,000 260,000 80,000 50,000 20,000 6,000 5,900 30,500 70,000 11,700 26,100 28,500 24,100
Analytical Method EPA Methods 601/602, 6210D or 6200B
1,
3
,
5
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
Et
h
y
l
b
e
n
z
e
n
e
Be
n
z
e
n
e
1,
2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
p-
I
s
o
p
r
o
p
y
l
t
o
l
u
e
n
e
To
l
u
e
n
e
Na
p
h
t
h
a
l
e
n
e
MT
B
E
MAC (mg/l)
GCL (mg/l)
Xy
l
e
n
e
s
TABLE 4
GROUND WATER SAMPLE ANALYTICAL RESULTS
D.W. TATUM GROCERY (INCIDENT NO. 15274)
Date: 08/10/2023
Contaminant of
Concern
IP
E
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e
n-
B
u
t
y
l
b
e
n
z
e
n
e
n-
P
r
o
p
y
l
b
e
n
z
e
n
e
11/16/01 <0.5 <0.5 <0.5 <1.5 <0.5 <0.5 NR NR <0.5 NR NR NR NR
06/03/04 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 NR NR <1.0 NR NR NR NR
10/17/07 NS NS NS NS NS NS NS NS NS NS NS NS NS
07/06/12 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.10 <0.10 <0.11 <0.10 <0.11 <0.10 <0.10
07/10/13 <0.10 <0.10 <0.10 <0.22 <0.10 <0.15 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
12/05/13 <0.10 <0.10 <0.10 <0.22 <0.10 <0.15 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
06/04/14 <0.10 <0.10 <0.10 <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
12/04/14 <0.10 <0.10 <0.10 <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
05/06/15 <0.17 <0.17 <0.15 <0.43 <0.16 <0.12 <0.14 <0.12 <0.16 <0.12 <0.16 <0.14 <0.14
07/14/16 <0.13 <0.13 <0.13 <0.31 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
02/21/17 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/10/19 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/31/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.180 <0.180 <0.500 <0.089 <0.190 <0.190 <0.180
11/16/01 <0.5 <0.5 <0.5 <1.5 <0.5 <0.5 NR NR <0.5 NR NR NR NR
06/03/04 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 NR NR <1.0 NR NR NR NR
10/17/07 NS NS NS NS NS NS NS NS NS NS NS NS NS
11/16/01 1,600 280 1,300 3,130 290 240 NR NR 9 NR NR NR NR
06/03/04 1,700 1,300 1,000 4,300 110 360 NR NR <50 NR NR NR NR
10/17/07 NS NS NS NS NS NS NS NS NS NS NS NS NS
12/04/08 <0.60 <0.70 <0.50 <1.0 <0.50 <0.60 <0.85 <0.55 <1.0 <1.0 <0.75 <0.70 <0.50
10/06/09 1.84 <0.190 21.1 1.34 <0.250 7.26 <0.180 3.32 <0.200 <0.200 2.85 1.80 <0.180
12/28/10 <0.140 <0.190 0.261 J <0.220 <0.250 0.990 J <0.180 <0.150 <0.200 <0.200 <0.220 0.235 J <0.180
07/06/11 NS NS NS NS NS NS NS NS NS NS NS NS NS
11/16/01 <0.5 94 91 970 <0.5 29 NR NR <0.5 NR NR NR NR
06/03/04 NS NS NS NS NS NS NR NR NS NR NR NR NR
07/14/16 <0.13 <0.13 <0.13 <0.31 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
02/21/17 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/10/19 <0.13 <0.13 1.2 <0.25 <0.13 1.5 0.19 J 0.6 <0.13 <0.13 2.1 3.7 1.5
07/31/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.180 <0.180 <0.500 <0.089 <0.190 <0.190 <0.180
02/06/02 <0.5 <0.5 <0.5 <1.5 <0.5 <0.5 NR NR <0.5 NR NR NR NR
06/03/04 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 NR NR <1.0 NR NR NR NR
10/18/07 <0.500 <0.500 <0.500 <1.00 <0.500 <5.00 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500
07/10/13 NS NS NS NS NS NS NS NS NS NS NS NS NS
02/06/02 <0.5 <0.5 <0.5 <1.5 <0.5 <0.5 NR NR <0.5 NR NR NR NR
06/04/04 <1.0 <1.0 <1.0 <2.0 <1.0 <1.0 NR NR <1.0 NR NR NR NR
10/17/07 NS NS NS NS NS NS NS NS NS NS NS NS NS
02/11/17 NS NS NS NS NS NS NS NS NS NS NS NS NS
03/09/21 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
02/06/02 3 <0.5 <0.5 <1.5 10 <0.5 NR NR <0.5 NR NR NR NR
06/03/04 NS NS NS NS NS NS NS NS NS NS NS NS NS
10/06/09 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 <0.180 <0.150 <0.200 <0.200 <0.220 <0.150 <0.180
12/28/10 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 <0.180 <0.150 <0.200 <0.200 <0.220 <0.150 <0.180
07/06/11 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.10 <0.10 <0.11 <0.10 <0.11 <0.10 <0.10
07/06/12 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.10 <0.10 <0.11 <0.10 <0.11 <0.10 <0.10
07/10/13 <0.10 <0.10 <0.10 <0.22 <0.10 <0.15 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
12/05/13 <0.10 <0.10 <0.10 <0.22 <0.10 <0.15 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
06/04/14 <0.10 <0.10 <0.10 <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
12/04/14 <0.10 <0.10 <0.10 <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
05/06/15 <0.17 <0.17 <0.15 <0.43 <0.16 <0.12 <0.14 <0.12 <0.16 <0.12 <0.16 <0.14 <0.14
07/14/16 <0.13 <0.13 <0.13 <0.31 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
02/21/17 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/10/19 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/31/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.180 <0.180 <0.500 <0.089 <0.190 <0.190 <0.180
MW-10
MW-11
MW-12
MW-6
MW-7
MW-8
MW-9
Page 2 of 9
Facility ID#: 00-0-000008167
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 70 70 70 25 70 400 400
5,000 260,000 80,000 50,000 20,000 6,000 5,900 30,500 70,000 11,700 26,100 28,500 24,100
Analytical Method EPA Methods 601/602, 6210D or 6200B
1,
3
,
5
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
Et
h
y
l
b
e
n
z
e
n
e
Be
n
z
e
n
e
1,
2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
p-
I
s
o
p
r
o
p
y
l
t
o
l
u
e
n
e
To
l
u
e
n
e
Na
p
h
t
h
a
l
e
n
e
MT
B
E
MAC (mg/l)
GCL (mg/l)
Xy
l
e
n
e
s
TABLE 4
GROUND WATER SAMPLE ANALYTICAL RESULTS
D.W. TATUM GROCERY (INCIDENT NO. 15274)
Date: 08/10/2023
Contaminant of
Concern
IP
E
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e
n-
B
u
t
y
l
b
e
n
z
e
n
e
n-
P
r
o
p
y
l
b
e
n
z
e
n
e
02/06/02 3,500 35 17 720 3,500 160 NR NR 55 NR NR NR NR
06/03/04 3,500 <100 <100 630 1,900 250 NR NR <100 NR NR NR NR
10/17/07 1,960 27.4 198 1,300 484 329 13.4 79.1 8.03 1.69 41.5 431 213
05/01/08 2,330 38.1 382 2,310 236 337 10.4 84.9 5.26 11.8 73.6 686 252
12/04/08 96 1.8 J 16 120 58 1.6 JB <0.85 2.7 J 2.6 J <1.0 2.2 J 12 11
10/06/09 3,300 58.3 774 2,740 <6.25 369 <4.50 105 <5.00 <5.00 131 845 258
07/10/13 NS NS NS NS NS NS NS NS NS NS NS NS NS
02/06/02 <0.5 <0.5 <0.5 <1.5 <0.50 <0.5 NR NR <0.5 NR NR NR NR
06/03/04 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 NR NR <1.0 NR NR NR NR
10/17/07 NS NS NS NS NS NS NS NS NS NS NS NS NS
07/14/16 <0.13 <0.13 <0.13 <0.31 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
02/21/17 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/10/19 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/31/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.180 <0.180 <0.500 <0.089 <0.190 <0.190 <0.180
02/06/02 <0.5 <0.5 <0.5 <1.5 <0.5 <0.5 NR NR <0.5 NR NR NR NR
06/03/04 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 NR NR <1.0 NR NR NR NR
10/17/07 NS NS NS NS NS NS NS NS NS NS NS NS NS
07/06/12 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.10 <0.10 <0.11 <0.10 <0.11 <0.10 <0.10
07/10/13 <0.10 <0.10 <0.10 <0.22 <0.10 <0.15 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
12/05/13 <0.10 <0.10 <0.10 <0.22 <0.10 <0.15 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
06/04/14 <0.10 <0.10 <0.10 <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
12/04/14 <0.10 <0.10 <0.10 <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
05/06/15 <0.17 <0.17 <0.15 <0.43 <0.16 <0.12 <0.14 <0.12 <0.16 <0.12 <0.16 <0.14 <0.14
07/14/16 <0.13 <0.13 <0.13 <0.31 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
02/21/17 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/10/19 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
03/09/21 0.25 J <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/31/23 <0.180 <0.220 <0.170 <0.210 <0.140 4.87 <0.180 <0.180 <0.500 <0.089 <0.190 0.372 J <0.180
02/06/02 6,600 200 660 4,600 17,000 260 NR NR 160 NR NR NR NR
06/03/04 5,600 120 700 3,080 3,700 710 NR NR <50 NR NR NR NR
10/17/07 2,110 42.5 765 1,660 554 394 25.5 72.2 12.4 4.73 123 919 397
05/01/08 2,800 41.4 370 1,430 652 297 7.07 68.3 8.11 11.8 84.6 784 299
12/04/08 43 <0.70 0.95 J 3.0 J 320 <0.60 <0.85 <0.55 5.2 J <1.0 <0.75 0.70 J <0.50
10/06/09 2,200 30.6 253 1,220 424 250 <4.50 77.3 <5.00 <5.00 76.0 600 228
12/28/10 2,360 26.4 J 236 737 247 271 16.9 J 69.1 <10.0 <10.0 77.2 409 171
07/06/11 NS NS NS NS NS NS NS NS NS NS NS NS NS
02/06/02 510 34 37 203 560 43 NR NR 9 NR NR NR NR
06/03/04 610 6.4 76 87.2 100 63 NR NR 7.5 NR NR NR NR
10/17/07 196 1.00 89.1 <1.00 2.63 18.2 4.40 15.4 <0.500 0.750 23.2 3.91 58.4
04/30/08 166 1.10 69.7 3.22 2.22 22.9 1.42 12.4 0.240 I 0.960 I 16.4 3.02 27.0
12/04/08 <0.60 <0.70 <0.50 <1.0 <0.50 <0.60 <0.85 <0.55 <1.0 <1.0 <0.75 <0.70 <0.50
10/06/09 836 12.1 349 104 <2.50 116 <1.80 37.5 <2.00 <2.00 58.6 79.5 97.9
12/05/13 NS NS NS NS NS NS NS NS NS NS NS NS NS
MW-16
MW-17
MW-13
MW-14
MW-15
Page 3 of 9
Facility ID#: 00-0-000008167
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 70 70 70 25 70 400 400
5,000 260,000 80,000 50,000 20,000 6,000 5,900 30,500 70,000 11,700 26,100 28,500 24,100
Analytical Method EPA Methods 601/602, 6210D or 6200B
1,
3
,
5
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
Et
h
y
l
b
e
n
z
e
n
e
Be
n
z
e
n
e
1,
2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
p-
I
s
o
p
r
o
p
y
l
t
o
l
u
e
n
e
To
l
u
e
n
e
Na
p
h
t
h
a
l
e
n
e
MT
B
E
MAC (mg/l)
GCL (mg/l)
Xy
l
e
n
e
s
TABLE 4
GROUND WATER SAMPLE ANALYTICAL RESULTS
D.W. TATUM GROCERY (INCIDENT NO. 15274)
Date: 08/10/2023
Contaminant of
Concern
IP
E
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e
n-
B
u
t
y
l
b
e
n
z
e
n
e
n-
P
r
o
p
y
l
b
e
n
z
e
n
e
05/24/02 9 <0.5 <0.5 1 9 <0.5 NR NR <0.5 NR NR NR NR
06/03/04 NS NS NS NS NS NS NS NS NS NS NS NS NS
10/17/07 0.730 <0.500 <0.500 <1.00 <0.500 <5.00 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500
05/01/08 16.4 <1.0 <1.0 4.17 2.16 0.940 I <1.0 1.61 <5.0 <1.0 <1.0 1.99 2.25
12/04/08 2.0 J <0.70 <0.50 1.9 J <0.50 <0.60 <0.85 <0.55 <1.0 <1.0 <0.75 <0.70 <0.50
10/06/09 29.4 <0.190 <0.150 3.58 <0.250 <0.500 <0.180 1.54 <0.200 <0.200 <0.220 2.00 0.841 J
12/05/13 NS NS NS NS NS NS NS NS NS NS NS NS NS
05/24/02 <0.5 <0.5 <0.5 <1.5 <0.5 <0.5 NR NR <0.5 NR NR NR NR
06/03/04 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 NR NR <1.0 NR NR NR NR
10/17/07 <0.500 <0.500 <0.500 <1.00 <0.500 <5.00 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500
04/30/08 <1.0 <1.0 <1.0 <3.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0
12/04/08 <0.60 <0.70 <0.50 <1.0 <0.50 <0.60 <0.85 <0.55 <1.0 <1.0 <0.75 <0.70 <0.50
10/06/09 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 <0.180 <0.150 <0.200 <0.200 <0.220 <0.150 <0.180
12/29/10 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 <0.180 <0.150 <0.200 <0.200 <0.220 <0.150 <0.180
07/06/11 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.10 <0.10 <0.11 <0.10 <0.11 <0.10 <0.10
07/06/12 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.10 <0.10 <0.11 <0.10 <0.11 <0.10 <0.10
07/10/13 <0.10 <0.10 <0.10 <0.22 <0.10 <0.15 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
12/05/13 <0.10 <0.10 <0.10 <0.22 <0.10 <0.15 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
06/04/14 <0.10 <0.10 <0.10 <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
12/04/14 <0.10 <0.10 <0.10 <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
05/06/15 <0.17 <0.17 <0.15 <0.43 <0.16 <0.12 <0.14 <0.12 <0.16 <0.12 <0.16 <0.14 <0.14
07/14/16 <0.13 <0.13 <0.13 <0.31 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
02/21/17 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/10/19 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/31/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.180 <0.180 <0.500 <0.089 <0.190 <0.190 <0.180
05/24/02 36 <0.5 <0.5 9 95 <0.5 NR NR 0.6 NR NR NR NR
06/03/04 27 <1.0 <1.0 5.5 12 <2.0 NR NR <1.0 NR NR NR NR
10/17/07 NS NS NS NS NS NS NS NS NS NS NS NS NS
12/29/10 359 <0.950 <0.750 38.6 42.4 17.3 1.54 J 9.58 <1.00 <1.00 <1.10 26.4 14.4
07/06/11 348 0.52 <0.15 41 46 22.2 1.5 8.9 0.7 <0.10 0.21 J 24.9 8.5
07/06/12 311 <1.3 <1.5 15.9 J 44.4 25.3 <1.0 8.8 <1.1 <1.0 <1.1 13.8 6.3
07/10/13 59.3 <0.10 <0.10 0.60 J 9.5 4.9 0.17 J 1.8 0.18 J <0.10 <0.10 0.31 J <0.10
12/05/13 13.1 <0.10 <0.10 <0.22 2.8 1.5 <0.10 0.36 J <0.10 <0.10 <0.10 0.43 J <0.10
06/04/14 550 0.83 0.21 J 17.9 57.5 41.1 2.6 22.8 1.3 <0.10 0.27 J 17.7 12.8
12/04/14 2.8 0.16 J <0.10 <0.20 0.31 J 0.27 J <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
05/06/15 163 0.25 J <0.15 6.7 21.6 24.5 1.7 8.9 0.42 J <0.12 <0.16 7.3 3.4
01/19/16 85.1 0.15 J <0.13 4.2 13.5 19.6 1 4.1 0.24 J <0.13 <0.13 4.6 2.3
02/21/17 NS NS NS NS NS NS NS NS NS NS NS NS NS
MW-20
MW-18
MW-19
Page 4 of 9
Facility ID#: 00-0-000008167
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 70 70 70 25 70 400 400
5,000 260,000 80,000 50,000 20,000 6,000 5,900 30,500 70,000 11,700 26,100 28,500 24,100
Analytical Method EPA Methods 601/602, 6210D or 6200B
1,
3
,
5
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
Et
h
y
l
b
e
n
z
e
n
e
Be
n
z
e
n
e
1,
2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
p-
I
s
o
p
r
o
p
y
l
t
o
l
u
e
n
e
To
l
u
e
n
e
Na
p
h
t
h
a
l
e
n
e
MT
B
E
MAC (mg/l)
GCL (mg/l)
Xy
l
e
n
e
s
TABLE 4
GROUND WATER SAMPLE ANALYTICAL RESULTS
D.W. TATUM GROCERY (INCIDENT NO. 15274)
Date: 08/10/2023
Contaminant of
Concern
IP
E
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e
n-
B
u
t
y
l
b
e
n
z
e
n
e
n-
P
r
o
p
y
l
b
e
n
z
e
n
e
05/24/02 <0.5 <0.5 <0.5 <1.5 <0.5 <0.5 NR NR <0.5 NR NR NR NR
06/03/04 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 NR NR <1.0 NR NR NR NR
10/17/07 <0.500 <0.500 <0.500 <1.00 <0.500 <5.00 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500
04/30/08 <1.0 <1.0 <1.0 <3.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0
12/04/08 <0.60 <0.70 <0.50 <1.0 <0.50 0.75 JB <0.85 <0.55 <1.0 <1.0 <0.75 <0.70 <0.50
10/06/09 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 <0.180 <0.150 <0.200 <0.200 <0.220 <0.150 <0.180
12/28/10 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 <0.180 <0.150 <0.200 <0.200 <0.220 <0.150 <0.180
07/06/11 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.10 <0.10 <0.11 <0.10 <0.11 <0.10 <0.10
07/10/13 <0.10 <0.10 <0.10 <0.22 <0.10 <0.15 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
12/05/13 <0.10 <0.10 <0.10 <0.22 <0.10 <0.15 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
06/04/14 <0.10 <0.10 <0.10 <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
12/04/14 <0.10 <0.10 <0.10 <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
05/06/15 <0.17 <0.17 <0.15 <0.43 <0.16 <0.12 <0.14 <0.12 <0.16 <0.12 <0.16 <0.14 <0.14
07/14/16 <0.13 <0.13 <0.13 <0.31 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
02/21/17 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/10/19 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/31/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.180 <0.180 <0.500 <0.089 <0.190 <0.190 <0.180
05/24/02 <0.5 <0.5 <0.5 <1.5 <0.5 <0.5 NR NR <0.5 NR NR NR NR
06/04/04 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 NR NR <1.0 NR NR NR NR
10/17/07 NS NS NS NS NS NS NS NS NS NS NS NS NS
07/14/16 <0.13 <0.13 <0.13 <0.31 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
02/21/17 NS NS NS NS NS NS NS NS NS NS NS NS NS
07/10/19 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/31/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.180 <0.180 <0.500 <0.089 <0.190 <0.190 <0.180
05/24/02 <0.5 <0.5 <0.5 <1.5 <0.5 <0.5 NR NR <0.5 NR NR NR NR
06/04/04 <1.0 <1.0 <1.0 <2.0 5.7 <2.0 NR NR <1.0 NR NR NR NR
10/17/07 <0.500 <0.500 <0.500 <1.00 2.46 <5.00 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500
05/01/08 <1.0 <1.0 <1.0 <3.0 3.07 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0
12/04/08 NS NS NS NS NS NS NS NS NS NS NS NS NS
10/06/09 <0.140 <0.190 <0.150 <0.220 2.23 <0.500 <0.180 <0.150 <0.200 <0.200 <0.220 <0.150 <0.180
12/29/10 <0.140 <0.190 <0.150 <0.220 1.30 <0.500 <0.180 <0.150 <0.200 <0.200 <0.220 <0.150 <0.180
07/06/11 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.10 <0.10 <0.11 <0.10 <0.11 <0.10 <0.10
07/06/12 <0.13 <0.13 <0.15 <0.30 0.99 <0.10 <0.10 <0.10 <0.11 <0.10 <0.11 <0.10 <0.10
07/10/13 <0.10 <0.10 <0.10 <0.22 <0.10 <0.15 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
12/05/13 <0.10 <0.10 <0.10 <0.22 0.87 <0.15 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
06/04/14 <0.10 <0.10 <0.10 <0.20 0.67 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
12/04/14 <0.10 <0.10 <0.10 <0.20 0.41 J <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
05/06/15 <0.17 <0.17 <0.15 <0.43 0.56 <0.12 <0.14 <0.12 <0.16 <0.12 <0.16 <0.14 <0.14
07/14/16 <0.13 <0.13 <0.13 <0.31 0.37 J <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
02/21/17 NS NS NS NS NS NS NS NS NS NS NS NS NS
07/10/19 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
03/09/21 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/31/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.180 <0.180 <0.500 <0.089 <0.190 <0.190 <0.180
MW-21
MW-22
MW-23
Page 5 of 9
Facility ID#: 00-0-000008167
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 70 70 70 25 70 400 400
5,000 260,000 80,000 50,000 20,000 6,000 5,900 30,500 70,000 11,700 26,100 28,500 24,100
Analytical Method EPA Methods 601/602, 6210D or 6200B
1,
3
,
5
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
Et
h
y
l
b
e
n
z
e
n
e
Be
n
z
e
n
e
1,
2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
p-
I
s
o
p
r
o
p
y
l
t
o
l
u
e
n
e
To
l
u
e
n
e
Na
p
h
t
h
a
l
e
n
e
MT
B
E
MAC (mg/l)
GCL (mg/l)
Xy
l
e
n
e
s
TABLE 4
GROUND WATER SAMPLE ANALYTICAL RESULTS
D.W. TATUM GROCERY (INCIDENT NO. 15274)
Date: 08/10/2023
Contaminant of
Concern
IP
E
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e
n-
B
u
t
y
l
b
e
n
z
e
n
e
n-
P
r
o
p
y
l
b
e
n
z
e
n
e
05/24/02 4,800 27 4 240 36,000 190 NR NR 77 NR NR NR NR
06/04/04 2,200 <100 <100 <200 6,900 <40 NR NR <100 NR NR NR NR
10/17/07 800 <0.500 <0.500 <1.00 14,800 6.04 <0.500 2.85 22.4 <0.500 <0.500 <0.500 <0.500
05/01/08 11.8 <1.0 <1.0 <3.0 253 <1.0 <1.0 <1.0 0.410 I <1.0 <1.0 <1.0 <1.0
12/04/08 2.0 J <0.70 <0.50 <1.0 8.2 <0.60 <0.85 <0.55 <1.0 <1.0 <0.75 <0.70 <0.50
10/06/09 676 70.6 J <15.0 <22.0 6,830 <50.0 <18.0 <15.0 <20.0 <20.0 <22.0 33.2 J <18.0
12/29/10 47.5 0.302 J <0.150 0.854 J 90.7 6.34 0.212 J 6.41 2.16 <0.200 <0.220 0.214 J <0.180
07/06/11 189 <6.4 <7.3 <15.0 1,240 <5.0 <5.0 <5.0 <5.4 <5.0 <5.4 <5.0 <5.0
07/06/12 204 2.3 J <1.5 <3.0 1,170 3.6 J <1.0 2.6 J 3.8 J <1.0 <1.1 <1.0 <1.0
07/10/13 35.6 0.87 <0.10 <0.22 237 1.1 <0.10 1.0 1.0 <0.10 <0.10 <0.10 <0.10
12/05/13 <0.10 <0.10 <0.10 <0.22 2.3 <0.15 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
06/04/14 349 <0.10 0.35 J <0.20 1,760 3.0 0.20 J 3.8 7.3 <0.10 0.19 J 1.2 <0.10
12/04/14 <0.10 <0.10 <0.10 <0.20 9.7 <0.10 <0.10 <0.10 0.32 J <0.10 <0.10 <0.10 <0.10
05/06/15 645 <17 <15 <43 3,060 <12 <14 <12 <16 <12 <16 <14 <14
01/19/16 773 0.18 J 0.64 0.44 J 2,490 3.6 0.16 J 3.8 10.6 <0.13 0.45 J 2.3 0.17 J
07/14/16 515 <6.3 <6.3 <15 1,460 <6.3 <6.3 <6.3 <6.3 <6.3 <6.3 <6.3 <6.3
02/21/17 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/10/19 12.2 <0.13 <0.13 <0.25 40.8 <0.13 <0.13 <0.13 0.14 J <0.13 <0.13 <0.13 <0.13
03/09/21 459 <6.3 <6.3 <13 1,500 <6.3 <6.3 <6.3 <6.3 <6.3 <6.3 <6.3 <6.3
07/31/23 <0.180 0.266 J 0.549 <0.210 220 <0.470 <0.180 2.81 2.22 <0.089 0.5 <0.190 <0.180
12/04/02 110 <50 <50 <150 3,900 <50 NR NR <50 NR NR NR NR
06/04/04 140 <1.0 <1.0 <2.0 3,500 <2.0 NR NR 2.6 NR NR NR NR
10/18/07 220 <0.500 <0.500 1.72 7,520 <5.00 <0.500 <0.500 9.87 <0.500 <0.500 <0.500 <0.500
05/01/08 1.65 <1.0 <1.0 <3.0 8,610 <1.0 <1.0 <1.0 7.11 <1.0 <1.0 <1.0 <1.0
12/04/08 <12 <14 20 J 96 J 6,400 94 JB <17 <11 <20 <20 <15 88 J 26 J
10/06/09 303 <19.0 <15.0 <22.0 15,600 <50.0 <18.0 <15.0 <20.0 <20.0 <22.0 <15.0 <18.0
12/29/10 216 <19.0 <15.0 <22.0 9,160 169 <18.0 <15.0 <20.0 <20.0 <22.0 <15.0 <18.0
07/06/11 193 <26 <29 <60 9,240 <20 <20 <20 <21 <20 <21 <20 <20
07/06/12 159 <26 <29 <60 8,550 <20 <20 <20 <21 <20 <21 <20 <20
07/10/13 NS NS NS NS NS NS NS NS NS NS NS NS NS
12/05/13 NS NS NS NS NS NS NS NS NS NS NS NS NS
06/04/14 NS NS NS NS NS NS NS NS NS NS NS NS NS
12/04/14 <25 <25 <25 <50 6,800 <25 <25 <25 <25 <25 <25 36.3 J <25
05/06/15 331 <4.2 <3.8 <11 6,260 <3.1 <3.6 <3.0 12.2 J <3.1 <3.9 <3.4 <3.4
01/19/16 <3.1 <3.1 <3.1 <7.7 6,690 <3.1 <3.1 <3.1 8.6 J <3.1 <3.1 <3.1 <3.1
07/14/16 304 <25 <25 <62 6,620 <25 <25 <25 <25 <25 <25 <25 <25
02/21/17 31.9 J <25 <25 <50 6,050 <25 <25 <25 <25 <25 <25 <25 <25
03/09/21 <13 <13 <13 <25 4,890 <13 <13 <13 <13 <13 <13 <13 <13
07/31/23 15.4 <2.20 <1.70 <2.10 4,440 <4.70 <1.80 <1.80 6.74 <0.890 <1.90 <1.90 <1.80
MW-25
MW-24
Page 6 of 9
Facility ID#: 00-0-000008167
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 70 70 70 25 70 400 400
5,000 260,000 80,000 50,000 20,000 6,000 5,900 30,500 70,000 11,700 26,100 28,500 24,100
Analytical Method EPA Methods 601/602, 6210D or 6200B
1,
3
,
5
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
Et
h
y
l
b
e
n
z
e
n
e
Be
n
z
e
n
e
1,
2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
p-
I
s
o
p
r
o
p
y
l
t
o
l
u
e
n
e
To
l
u
e
n
e
Na
p
h
t
h
a
l
e
n
e
MT
B
E
MAC (mg/l)
GCL (mg/l)
Xy
l
e
n
e
s
TABLE 4
GROUND WATER SAMPLE ANALYTICAL RESULTS
D.W. TATUM GROCERY (INCIDENT NO. 15274)
Date: 08/10/2023
Contaminant of
Concern
IP
E
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e
n-
B
u
t
y
l
b
e
n
z
e
n
e
n-
P
r
o
p
y
l
b
e
n
z
e
n
e
06/02/03 <0.5 <0.5 <0.5 <1.5 <0.5 <0.5 NR NR <0.5 NR NR NR NR
06/03/04 NS NS NS NS NS NS NR NR NS NR NR NR NR
10/17/07 <0.500 <0.500 <0.500 <1.00 <0.500 <5.00 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500
04/30/08 <1.0 <1.0 <1.0 <3.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0
12/04/08 <0.60 <0.70 <0.50 <1.0 <0.50 <0.60 <0.85 <0.55 <1.0 <1.0 <0.75 <0.70 <0.50
10/06/09 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 <0.180 <0.150 <0.200 <0.200 <0.220 <0.150 <0.180
12/29/10 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 <0.180 <0.150 <0.200 <0.200 <0.220 <0.150 <0.180
07/06/11 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.10 <0.10 <0.11 <0.10 <0.11 <0.10 <0.10
07/06/12 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.10 <0.10 <0.11 <0.10 <0.11 <0.10 <0.10
07/10/13 <0.10 <0.10 <0.10 <0.22 <0.10 <0.15 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
12/05/13 <0.10 <0.10 <0.10 <0.22 <0.10 <0.15 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
06/04/14 <0.10 <0.10 <0.10 <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
12/04/14 <0.10 <0.10 <0.10 <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
05/06/15 <0.17 <0.17 <0.15 <0.43 <0.16 <0.12 <0.14 <0.12 <0.16 <0.12 <0.16 <0.14 <0.14
07/14/16 <0.13 <0.13 <0.13 <0.31 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
02/21/17 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/10/19 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
06/02/03 <10 <10 <10 <30 280 <10 NR NR <10 NR NR NR NR
06/04/04 <1.0 <1.0 <1.0 <2.0 570 <2.0 NR NR <1.0 NR NR NR NR
10/17/07 NS NS NS NS NS NS NS NS NS NS NS NS NS
10/06/09 8.63 <1.90 <1.50 <2.20 896 <5.00 <1.80 <1.50 <2.00 <2.00 <2.20 <1.50 <1.80
12/29/10 1.12 <0.190 <0.150 <0.220 896 <0.500 <0.180 <0.150 0.831 J <0.200 <0.220 <0.150 <0.180
07/06/11 1.1 <0.13 <0.15 <0.30 1,390 <0.10 <0.10 <0.10 1.6 <0.10 <0.11 <0.10 <0.10
07/06/12 <6.5 <6.4 <7.3 <15 2,050 <5.0 <5.0 <5.0 <5.4 <5.0 <5.4 <5.0 <5.0
07/10/13 0.54 <0.10 <0.10 <0.22 1,170 <0.15 <0.10 <0.10 2.1 <0.10 <0.10 <0.10 <0.10
12/05/13 NS NS NS NS NS NS NS NS NS NS NS NS NS
06/04/14 9.6 J <5.0 6.7 J <10 2,770 <5.0 <5.0 <5.0 11.5 J <5.0 <5.0 <5.0 <5.0
12/04/14 0.13 J <0.10 <0.10 <0.20 27.3 <0.10 <0.10 <0.10 1.5 <0.10 <0.10 <0.10 <0.10
05/06/15 <8.6 <8.3 <7.6 <22 1,850 <6.1 <7.2 <5.9 <8.0 <6.1 <7.8 <6.8 <6.8
01/19/16 <3.1 <3.1 <3.1 <7.7 1,430 <3.1 <3.1 <3.1 <3.1 <3.1 <3.1 <3.1 <3.1
07/14/16 <0.13 <0.13 <0.13 <0.31 168 <0.13 <0.13 <0.13 0.24 J <0.13 <0.13 <0.13 <0.13
02/21/17 <0.13 <0.13 <0.13 <0.25 10.7 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
06/07/04 <1.0 <1.0 <1.0 <2.0 12 <2.0 NR NR <1.0 NR NR NR NR
10/17/07 NS NS NS NS NS NS NS NS NS NS NS NS NS
06/07/04 <1.0 <1.0 <1.0 <2.0 350 <2.0 NR NR <1.0 NR NR NR NR
10/17/07 NS NS NS NS NS NS NS NS NS NS NS NS NS
MW-26
MW-27
MW-28
MW-29
Page 7 of 9
Facility ID#: 00-0-000008167
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 70 70 70 25 70 400 400
5,000 260,000 80,000 50,000 20,000 6,000 5,900 30,500 70,000 11,700 26,100 28,500 24,100
Analytical Method EPA Methods 601/602, 6210D or 6200B
1,
3
,
5
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
Et
h
y
l
b
e
n
z
e
n
e
Be
n
z
e
n
e
1,
2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
p-
I
s
o
p
r
o
p
y
l
t
o
l
u
e
n
e
To
l
u
e
n
e
Na
p
h
t
h
a
l
e
n
e
MT
B
E
MAC (mg/l)
GCL (mg/l)
Xy
l
e
n
e
s
TABLE 4
GROUND WATER SAMPLE ANALYTICAL RESULTS
D.W. TATUM GROCERY (INCIDENT NO. 15274)
Date: 08/10/2023
Contaminant of
Concern
IP
E
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e
n-
B
u
t
y
l
b
e
n
z
e
n
e
n-
P
r
o
p
y
l
b
e
n
z
e
n
e
08/03/01 11 110 23 85 <8 <4 NR NR <4 NR NR NR NR
06/03/04 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 NR NR <1.0 NR NR NR NR
10/17/07 <0.500 <0.500 <0.500 <1.00 <0.500 <5.00 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500
04/30/08 <1.0 <1.0 <1.0 <3.0 <1.0 <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0
12/04/08 0.66 J <0.70 0.76 J 2.2 J <0.50 0.93 JB 1.1 J 0.93 J <1.0 <1.0 0.95 J 0.73 J 0.94 J
10/06/09 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 <0.180 <0.150 <0.200 <0.200 <0.220 <0.150 <0.180
12/28/10 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 <0.180 <0.150 <0.200 <0.200 <0.220 <0.150 <0.180
07/06/11 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.10 <0.10 <0.11 <0.10 <0.11 <0.10 <0.10
07/06/12 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.10 <0.10 <0.11 <0.10 <0.11 <0.10 <0.10
07/10/13 <0.10 <0.10 <0.10 <0.22 0.34 J <0.15 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
12/05/13 <0.10 <0.10 <0.10 <0.22 <0.10 <0.15 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
06/04/14 <0.10 <0.10 <0.10 <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
12/04/14 <0.10 <0.10 <0.10 <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
05/06/15 <0.17 <0.17 <0.15 <0.43 <0.16 0.16 J <0.14 <0.12 <0.16 <0.12 <0.16 <0.14 <0.14
07/14/16 <0.13 <0.13 <0.13 <0.31 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
02/21/17 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/10/19 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/31/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.180 <0.180 <0.500 <0.089 <0.190 <0.190 <0.180
11/16/01 <0.5 <0.5 <0.5 <1.5 <0.5 <0.5 NR NR <0.5 NR NR NR NR
06/03/04 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 NR NR <1.0 NR NR NR NR
10/17/07 NS NS NS NS NS NS NS NS NS NS NS NS NS
07/14/16 <0.13 <0.13 <0.13 <0.31 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
02/21/17 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/10/19 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/31/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.180 <0.180 <0.500 <0.089 <0.190 <0.190 <0.180
12/04/02 1 0.7 <0.5 0.6 <0.5 <0.5 NR NR <0.5 NR NR NR NR
06/04/04 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 NR NR <1.0 NR NR NR NR
10/17/07 <0.500 <0.500 <0.500 <1.00 <0.500 <5.00 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500
05/01/08 <1.0 <1.0 <1.0 <3.0 0.600 I <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0
12/04/08 <0.60 <0.70 <0.50 <1.0 <0.50 <0.60 <0.85 <0.55 <1.0 <1.0 <0.75 <0.70 <0.50
10/6/09 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 <0.180 <0.150 <0.200 <0.200 <0.220 <0.150 <0.180
12/29/10 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 <0.180 <0.150 <0.200 <0.200 <0.220 <0.150 <0.180
07/06/11 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.10 <0.10 <0.11 <0.10 <0.11 <0.10 <0.10
07/06/12 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.10 <0.10 <0.11 <0.10 <0.11 <0.10 <0.10
07/10/13 <0.10 <0.10 <0.10 <0.22 <0.10 <0.15 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
12/05/13 <0.10 <0.10 <0.10 <0.22 <0.10 <0.15 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
06/04/14 <0.10 <0.10 <0.10 <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
12/04/14 <0.10 <0.10 <0.10 <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
05/06/15 <0.17 <0.17 <0.15 <0.43 <0.16 <0.12 <0.14 <0.12 <0.16 <0.12 <0.16 <0.14 <0.14
07/14/16 <0.13 <0.13 <0.13 <0.31 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
02/21/17 6.2 <0.13 <0.13 <0.25 243 <0.13 <0.13 <0.13 2.5 <0.13 <0.13 <0.13 <0.13
07/10/19 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/31/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.180 <0.180 <0.500 <0.089 <0.190 <0.190 <0.180
06/02/03 <0.5 <0.5 <0.5 <1.5 <0.5 <0.5 NR NR <0.5 NR NR NR NR
06/04/04 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 NR NR <1.0 NR NR NR NR
10/17/07 NS NS NS NS NS NS NS NS NS NS NS NS NS
06/02/03 <0.5 <0.5 <0.5 <1.5 <0.5 <0.5 NR NR <0.5 NR NR NR NR
06/04/04 <1.0 <1.0 <2.0 <1.0 <1.0 <2.0 NR NR <1.0 NR NR NR NR
10/17/07 NS NS NS NS NS NS NS NS NS NS NS NS NS
T-1
T-2
T-3
WSW-2
WSW-1
Page 8 of 9
Facility ID#: 00-0-000008167
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 70 70 70 25 70 400 400
5,000 260,000 80,000 50,000 20,000 6,000 5,900 30,500 70,000 11,700 26,100 28,500 24,100
Analytical Method EPA Methods 601/602, 6210D or 6200B
1,
3
,
5
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
Et
h
y
l
b
e
n
z
e
n
e
Be
n
z
e
n
e
1,
2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
p-
I
s
o
p
r
o
p
y
l
t
o
l
u
e
n
e
To
l
u
e
n
e
Na
p
h
t
h
a
l
e
n
e
MT
B
E
MAC (mg/l)
GCL (mg/l)
Xy
l
e
n
e
s
TABLE 4
GROUND WATER SAMPLE ANALYTICAL RESULTS
D.W. TATUM GROCERY (INCIDENT NO. 15274)
Date: 08/10/2023
Contaminant of
Concern
IP
E
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e
n-
B
u
t
y
l
b
e
n
z
e
n
e
n-
P
r
o
p
y
l
b
e
n
z
e
n
e
10/18/07 <0.500 <0.500 <0.500 <1.00 <0.500 <5.00 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500
05/01/08 <1.0 <1.0 <1.0 <3.0 0.200 I <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0
12/04/08 <0.60 <0.70 <0.50 <1.0 <0.50 <0.60 <0.85 <0.55 <1.0 <1.0 <0.75 <0.70 <0.50
10/06/09 NS NS NS NS NS NS NS NS NS NS NS NS NS
12/29/10 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 <0.180 <0.150 <0.200 <0.200 <0.220 <0.150 <0.180
07/06/11 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.10 <0.10 <0.11 <0.10 <0.11 <0.10 <0.10
07/06/12 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.10 <0.10 <0.11 <0.10 <0.11 <0.10 <0.10
07/10/13 <0.10 <0.10 <0.10 <0.22 <0.10 <0.15 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
12/05/13 <0.10 <0.10 <0.10 <0.22 <0.10 <0.15 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
06/04/14 <0.10 <0.10 <0.10 <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
12/04/14 <0.10 <0.10 <0.10 <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
05/06/15 <0.17 <0.17 <0.15 <0.43 <0.16 <0.12 <0.14 <0.12 <0.16 <0.12 <0.16 <0.14 <0.14
10/18/07 <0.500 <0.500 <0.500 <1.00 <0.500 <5.00 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500
05/01/08 <1.0 <1.0 <1.0 <3.0 0.120 I <1.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0
12/04/08 <0.60 <0.70 <0.50 <1.0 <0.50 <0.60 <0.85 <0.55 <1.0 <1.0 <0.75 <0.70 <0.50
10/06/09 NS NS NS NS NS NS NS NS NS NS NS NS NS
10/18/07 <0.500 <0.500 <0.500 <1.00 <0.500 <5.00 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500
12/05/13 NS NS NS NS NS NS NS NS NS NS NS NS NS
Notes:
• < : Less than the method detection limit specified in the laboratory report
• MAC: Maximum allowable concentrations as specified in T15A NCAC 2L.0202 .
• GCL: Gross contamination level.
• Results in bold face type exceeded the MACs.
• NS: Not sampled
• NR: Not requested.
• Refer to laboratory report for other compounds detected which did not exceed the MACs.
• I or J: Estimated value.
• V or B: Present in laboratory blank.
WSW-4
WSW-5
WSW-3
Page 9 of 9
Date: 08/07/23 Facility ID #: 00-0-000008167
Well No.Sample
Date
DO
(mg/L)pH Temp(oC)Conductivity
Oxidation-
Reduction
Potential
(mV)
T-1 07/31/23 1.44 7.76 22.95 15 139.9
T-2 07/31/23 2.01 7.78 21.73 124 165.9
T-3 07/31/23 1.70 6.39 21.20 87 63.8
MW-1 07/31/23 1.92 7.02 23.21 336 27.1
MW-4 07/31/23 2.12 7.11 23.79 119 88.7
MW-5 07/31/23 2.14 6.57 24.68 61 125.4
MW-6 07/31/23 1.48 6.04 22.33 95 162.6
MW-9 07/31/23 2.12 6.76 25.69 124 143.1
MW-12 07/31/23 2.05 6.10 24.45 140 186.6
MW-14 07/31/23 2.11 6.49 24.80 174 171.4
MW-15 07/31/23 1.17 5.36 22.96 92 66.2
MW-19 07/31/23 1.45 5.77 22.41 38 73.0
MW-21 07/31/23 1.86 5.36 22.90 69 129.6
MW-24 07/31/23 1.05 5.96 22.15 219 -8.4
MW-22 07/31/23 2.16 6.25 23.30 92 48.6
MW-23 07/31/23 2.03 5.92 22.38 42 98.8
MW-25 07/31/23 1.72 4.96 21.61 67 157.4
**Use intial readings from field work for: DO & ORP
Use Final readings for - ph Temp Cond
TABLE 5
SUMMARY OF GROUND WATER FIELD PARAMETERS
D.W. TATUM GROCERY (INCIDENT NO. 15274)

APPENDICES

APPENDIX A
State Correspondence
Site Name City / County Sampson Incident #15274
Resp Pty Name / Contact Incident Mgr Region FAY
RP Type (Owner/Operator / Landowner / Attny‐in‐fact)Change Order? Prev. TA #19
Consultant / Project Mgr Rae Troiano Brown
Telephone / Fax Number Task Authorization Number:2 ChangeOrd:
Project Mgr Email Site Risk / Rank / Abatement:H 185 R RRA Date:9/23/2004
Proposal# / Scope Dates % Commercial (C=100%,  NC=0%,  Both=1%‐99%)
Has STF Eligibility Been Determined? (Y/N)Site Status (Active  or  NFA Date)
With Claim: [  ] All Main Consultant/Contractor invoices attached? [  ] Proof of payment attached directly to the front of each invoice?
 Important: The date of reimbursement is dependent on the Trust Fund balance. There may be a delay in the reimbursement of claims for work under this ePATA.
3r
d
 Pt
y
 De
d
?
Task #Lab / 
SubCode RO
 Au
t
h
Proposed 
Rate/Price
(Consultant)
TA
T
y
p
e
=
"
D
I
RE
C
T
E
D
 ‐

CA
B
 ON
L
Y
"
,

"R
O
 Su
p
v
.

Proposed Task 
Subtotal
(Consultant)
Final 
Preapproved 
Subtotal
(UST Section)
Claimed 
Amount3
(Consultant)
3.080 1 / permit Y $250.00 Y $250.00 $250.00 /
3.101 60 / feet Y $12.50 Y $750.00 $750.00 /
3.113 60 / feet Y $50.00 Y $3,000.00 $3,000.00 /
3.118 60 / feet Y $5.00 Y $300.00 $300.00 /
3.351 2 / wells Y $80.00 Y $160.00 $160.00 /
3.397 1 / Mobe Y $100.00 Y $100.00 $100.00 /
3.398 1 / Mobe Y $350.00 Y $350.00 $350.00 /
3.500 2 / nights Y $151.00 Y $302.00 $302.00 /
4.031 27 / wells Y $110.00 Y $2,970.00 $2,970.00 /
4.080 2 /sample pt.Y $45.00 Y $90.00 $90.00 /
4.090 #272 29 / samples Y $66.00 Y $1,914.00 $1,914.00 /
4.090 #409 1 / sample Y $84.00 Y $84.00 $84.00 /
4.090 #410 1 / sample Y $187.00 Y $187.00 $187.00 /
4.090 #421 1 / sample Y $58.00 Y $58.00 $58.00 /
4.090 #422 1 / sample Y $100.00 Y $100.00 $100.00 /
4.090 #441 27 / samples 0 $14.00 N $378.00 $0.00 /
4.090 #490 27 / samples 0 $20.00 N $540.00 $0.00 /
4.090 #510 27 / samples 0 $15.00 N $405.00 $0.00 /
4.090 #521 27 / samples 0 $70.00 N $1,890.00 $0.00 /
4.091 4 /shipments 2 $60.00 Y $240.00 $120.00 /
5.070 1 / event 0 $2,800.00 N $2,800.00 $0.00 /
6.090 1 / report Y $1,125.00 Y $1,125.00 $1,125.00 /
12.030 2 / nights 1 $151.00 Y $302.00 $151.00 /
12.050 2 / trips Y $250.00 Y $500.00 $500.00 /
12.055 2 / trips Y $50.00 Y $100.00 $100.00 /
//
//
Requested Preapproved Claimed 3
 TOTAL:$18,895.00 $12,611.00 TOTAL:
Total Standard Costs (Not Third Party)$18,895.00 $12,611.00 Total Standard Costs
Total applied as Third Party Deductible/Damage Costs $0.00 $0.00 Total Third Pty Costs
Process Tracking (Date)
TA Submittal: 3/9/23 by: (PM)(Reserved for RO)
RO Review: 3/12/23 by: (IM) Joint UST Preapproval Confirmed By: Date1 3/14/2023
CO Review: 3/14/23 by: (STF) RP or Designee Receipt Confirmation By: Date 4
1 ‐ This ePATA expires one year from the Joint UST Preapproval date.  This does not extend, alter, or supersede any regulatory deadlines (e.g., NORR's, NOV's, Enforcements, etc.)
2 ‐ THE ONE YEAR STATUTE OF LIMITATIONS APPLIES TO EACH INDIVIDUAL TASK. Costs must be claimed within one year of completion of that task to be reimbursable.
3 ‐ Only Tasks included on this ePATA may be claimed.  Do not include other Tasks or claimed costs (i.e., Claim preparation) that were not preapproved or the claim will be returned.
4 ‐ Preapproval is not valid (i.e., claimable) until receipt is signed as 'Confirmed' by the RP or their designee and returned to the Trust Fund within a week of approval. Signature
indicates acknowledgement of the tasks and amounts approved.  Any objections/appeals must be submitted via Change Order prior to work proceeding. Scope/cost
negotiations do not supersede other regulatory deadlines as described in #1 above.  Also, any ePATA that has been signed as 'Confirmed' by both the UST Section and RP
is not to be modified without written consent by all signatories.
5 ‐ Tasks approved on Directed ‐ CAB Only ePATAs must be performed in accordance with all applicable rules, statutes, and RRD Task Scopes of Work to be reimbursed in full.
DWM/UST ePATA 4/1/2022
DIRECTED COSTS
Clinton
(Must Complete with Claim Submittal)(See Instructions / RRD for Tasks requiring Preapproval / Task Authorization)
Owner/Operator
704‐845‐4010
(Reserved for Incident Manager)
PREAPPROVAL / TASK AUTHORIZATION
DW Tatum
Note: This Electronic Preapproval Task Authorization (ePATA) shall be used to receive preapproval from the UST Section. A proposal,including maps and figures,must be attached
to elaborate on the costs for the tasks listed below that describes the scope of work and the rationale for the proposed activities.If, following completion of this ePATA, you
discover that unexpected tasks must be performed, incurring costs for tasks not originally included with this form, you must complete and submit a separate ePATA request
designated as a "Change Order" in the provided space above prior to conducting those tasks. Include a copy of the prior ePATA form for confirmation. Please attach this form to
the cover of the corresponding claim when requesting reimbursement. IMPORTANT:Only one claim may be submitted per ePATA and all work on the ePATA must have been
completed within 12 months of the completion dateof the FIRST completed task to remain within theStatute of Limitations. All ePATAs submitted within a claim are closed with that
claim, and may not be re-used in a separate submittal, even for costs or tasks that were not originally claimed. Final reimbursement of costs associated with the Total Claimed
amount below may be affected by the eligibility status of the site (i.e., deductibles, apportionment, etc.), and the documentary validation of incurred costs as reasonable and
necessary expenses per 15A NCAC 2P .0402 and .0404.
FINAL REIMBURSEMENT
[e-mail]
Wellman Oil Company, Inc.
Geological Resources, Inc.
Liz Price
ActiveYES
23‐034 April 2023
704‐845‐4012
LP
WER
Proposed 
Units / Type
(Consultant)
Dates of Work
(Consultant)
Started1  /  Completed2
(Initials)
RTB
ELECTRONIC PREAPPROVAL TASK AUTHORIZATION FORM
Dept of Environmental Quality  ‐Division of Waste Management
Approval of  MW installation and sampling event as request in active site NORR, Fate & Transport modeling can be completed once/if all wells are below GCLs and no FP ‐LP
As Mobe was requested for Drilling and a Mobe was requested for sampling, assumed that overnights were for sampling.  As sampling reduced, also reduced overnight ‐LP 

February 3, 2023

Wellman Oil Co., Inc
Greg Owen
P.O. Box 780
Clinton, NC 28329

Re: Notice of Regulatory Requirements
15A NCAC 2L .0407(c)
Risk-based Assessment and Corrective Action
for Petroleum Underground Storage Tanks

DW Tatum Grocery
7381 Taylor’s Bridge Hwy
Sampson County
Incident Number: 15274
Risk Classification: High
Ranking: H 185 R

Dear Mr. Owen:

The subject incident has been reviewed by the UST Section and it has been determined by the
Department, in response to North Carolina General Statute (NCGS) 143-215.94E(e4), to be of sufficiently
high priority to allow funding by the State Trust Fund Program. Therefore, you are directed to proceed
with assessment or remediation activities as required in this Notice of Regulatory Requirements dated
February 3, 2023. Specifically, you are requested to complete the following:

Install monitoring wells in the former location of MW-13 and MW-16, conduct a
comprehensive groundwater sampling event, and submit a Groundwater Monitoring Report to
the Division no later than May 1, 2023.

Effective October 1, 2004, the Department requires that all work following the submittal of the
Limited Site Assessment Report (Title 15A NCAC 2L .0405) be preapproved if State Trust Fund
reimbursement is anticipated. To comply with this requirement, a completed Preapproval/Claim
Authorization Form, encompassing the required remedial activities, must be received in this office within
14 days of the date of this letter. Upon completion of the preapproved activities, you should submit your
claim promptly. Reimbursement funds are budgeted based on completed preapprovals, but lengthy delays
in reimbursement can occur if claims are not submitted immediately following work completion.

Please note that performing assessment and cleanup work that is not required under 15A NCAC 2L
.0400 is not reimbursable from the Commercial or Noncommercial Leaking Petroleum Underground
Storage Tank Cleanup Funds

If you have any questions regarding this letter, please contact me at the address or telephone number
listed below. If you have any questions regarding trust fund eligibility or reimbursement, please contact
the UST Section Trust Fund Branch at [phone].

Sincerely,
Liz Price
Hydrogeologist
Wilmington Regional Office
UST Section, Division of Waste Management, NCDEQ

cc: Rae Brown, GRI via email correspondence

Wilmington Regional Office | 127 Cardinal Drive Extension | Wilmington, NC 28405 | [phone]

1
Rae Brown
From:Haseltine, Mike <[e-mail]>
Sent:Friday, June 23, 2023 8:56 AM
To:Rae Brown
Subject:RE: [External] DW Tatum #15274 - NORR (GRI 2081) - Approved TA (GRI 2081)
Rae,

That’s fine, please provide a comprehensive monitoring report so all the stakeholders can evaluate the data and make
decisions. That includes information requested in the Comprehensive Appendices for Corrective Action
Guidelines (appendices)

Hold off on any change order for additional work.

Thanks,

Michael Haseltine, L.G.
Regional Supervisor Fayetteville/Wilmington Offices
Division of Waste Management, UST Section
North Carolina Department of Environmental Quality
Cell: [phone]
[e-mail]

DEQ is upda ng its email addresses to @deq.nc.gov in phases from May 1st to June 9th.
Employee email addresses may look different, but email performance will not be impacted
“Providing science-based environmental stewardship for the health and prosperity of ALL North
Carolinians.”

Wilmington Regional Office Fayetteville Regional Office

DWM Site Locator DWM UST Section Website DWM Laserfiche Public Search DWM UST Permitting and
Inspection

For spills or other environmental emergencies after hours:
NC DEQ DWM Duty Phone [phone]
NC State Emergency Management 1-800-858-0368
National Response Center 1-800-424-8802

2
From: Rae Brown <[e-mail]>
Sent: Thursday, June 22, 2023 3:23 PM
To: Haseltine, Mike <[e-mail]>
Subject: FW: [External] DW Tatum #15274 - NORR (GRI 2081) - Approved TA (GRI 2081)

CAUTION: External email. Do not click links or open attachments unless verified. Report suspicious emails with the Report Message
button located on your Outlook menu bar on the Home tab.

Hi Mike,

As the RTE was denied, I suggest moving forward with the sampling and monitoring report. I can submit a change order
of a model which was our original proposal. What do you think?

Thank you,
Rae

Rae Troiano Brown, P.G.
Project Manager
Geological Resources, Inc.
113 Firetower Road, Suite G
Winterville, NC 28590
Main [phone] Cell [phone]
www.geologicalresourcesinc.com

From: Price, Liz <[e-mail]>
Sent: Thursday, June 1, 2023 3:26 PM
To: Rae Brown <[e-mail]>
Cc: Haseltine, Mike <[e-mail]>; Price, Liz <[e-mail]>
Subject: RE: [External] DW Tatum #15274 - NORR (GRI 2081) - Approved TA (GRI 2081)

Rae,
That’s not good news.

Since I moved over to Trust Fund, I don’t have the time to send out access letters like I normally would in this instance. I
have copied Mike Hazeltine on this site so that he can reassign this incident and the new incident manager can know
that an access agreement was attempted.

Thank you for the information.

Liz Price
Hydrogeologist / Wilmington Regional Office
Division of Waste Management, UST Section
North Carolina Department of Environmental Quality
Office: [phone], Please Note New Phone Number and Email Address
[e-mail]

3

Wilmington Regional Office Fayetteville Regional Office

DWM Site Locator DWM UST Section Website DWM Laserfiche Public Search DWM UST Permitting and
Inspection

For spills or other environmental emergencies after hours:
NC DEQ DWM Duty Phone [phone]
NC State Emergency Management 1-800-858-0368
National Response Center 1-800-424-8802

From: Rae Brown <[e-mail]>
Sent: Thursday, May 25, 2023 3:06 PM
To: Price, Liz <[e-mail]>
Subject: RE: [External] DW Tatum #15274 - NORR (GRI 2081) - Approved TA (GRI 2081)

CAUTION: External email. Do not click links or open attachments unless verified. Report suspicious emails with the Report Message
button located on your Outlook menu bar on the Home tab.

Hi Liz,

I mailed several letters to the property owner – a few came back undeliverable and the rest were unanswered. I sent
staff by on Monday 5/22/23 and they spoke with the son. They refused to sign the RTE for us to install the wells.

Please let me know how you would like to proceed.

Rae

Rae Troiano Brown, P.G.
Project Manager
Geological Resources, Inc.
113 Firetower Road, Suite G
Winterville, NC 28590
Main [phone] Cell [phone]
www.geologicalresourcesinc.com

From: Price, Liz <[e-mail]>
Sent: Tuesday, March 14, 2023 10:57 AM
To: Rae Brown <[e-mail]>
4
Cc: Price, Liz <[e-mail]>
Subject: RE: [External] DW Tatum #15274 - NORR (GRI 2081) - Approved TA

Approved TA attached. I took off modeling until we see what’s in the new MW’s.

Thank you

Liz Price
Hydrogeologist / Wilmington Regional Office
Division of Waste Management, UST Section
North Carolina Department of Environmental Quality
Office: [phone]
[e-mail]

Wilmington Regional Office Fayetteville Regional Office

DWM Site Locator DWM UST Section Website DWM Laserfiche Public Search DWM UST Permitting and
Inspection

For spills or other environmental emergencies after hours:
NC DEQ DWM Duty Phone [phone]
NC State Emergency Management 1-800-858-0368
National Response Center 1-800-424-8802

From: Rae Brown <[e-mail]>
Sent: Thursday, March 9, 2023 2:52 PM
To: Price, Liz <[e-mail]>
Subject: RE: [External] DW Tatum #15274 - NORR (GRI 2081)

CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to
Report Spam.

Hey Liz,

William said you moved to Trust Fund – can you tell me to whom these should be sent?

Many thanks and best wishes in your new position!

5
Rae

Rae Troiano Brown, P.G.
Project Manager
Geological Resources, Inc.
Celebrating 50 years of serving our clients
113 Firetower Road, Suite G | Winterville, NC 28590 | website | facebook |
704-845-4010-office | 252-227-3005-cell | 252-321-6094-fax

From: Price, Liz <[e-mail]>
Sent: Friday, February 3, 2023 11:28 AM
To: Rae Brown <[e-mail]>
Cc: Price, Liz <[e-mail]>
Subject: RE: [External] DW Tatum #15274 - NORR

Rae,
NORR attached for replacement of MW-13 and MW-16.

Can you also plan to collect soil samples when installing these wells (run soil TPH in saturated smear zone for both
MW’s, and highest risk-based for highest TPH above water table…so 4 TPH soil samples and 1 risk-based).

Let me know if you have any questions.

Thank you.

Liz Price
Hydrogeologist / Wilmington Regional Office
Division of Waste Management, UST Section
North Carolina Department of Environmental Quality
Office: [phone]
[e-mail]

Wilmington Regional Office Fayetteville Regional Office

DWM Site Locator DWM UST Section Website DWM Laserfiche Public Search DWM UST Permitting and
Inspection

For spills or other environmental emergencies after hours:
6
NC DEQ DWM Duty Phone [phone]
NC State Emergency Management 1-800-858-0368
National Response Center 1-800-424-8802

From: Rae Brown <[e-mail]>
Sent: Thursday, February 2, 2023 4:28 PM
To: Price, Liz <[e-mail]>
Subject: RE: [External] DW Tatum #15274

CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to
Report Spam.

Hi Liz,

Thank you for reviewing the project. I understand your concerns with MW-13 and MW-16 and re-installing these wells
will help move the incident toward closure, then it is reasonable to install wells and sample them. We can confirm the
locations of WSW-1 and WSW-2 with GPS when we are back on-site.

Please direct the installation of wells in the vicinity of the highest historic concentrations.

Thank you for your patience and I regret the delayed response.

Yours,
Rae

Rae Troiano Brown, P.G.
Project Manager
Geological Resources, Inc.
Celebrating 50 years of serving our clients
113 Firetower Road, Suite G | Winterville, NC 28590 | website | facebook |
704-845-4010-office | 252-227-3005-cell | 252-321-6094-fax

From: Price, Liz <[e-mail]>
Sent: Friday, January 20, 2023 10:50 AM
To: Rae Brown <[e-mail]>
Cc: Price, Liz <[e-mail]>
Subject: RE: [External] DW Tatum #15274

Hi Rae,

Left you a VM on your cell about this one:

I took this site over from James and just had a chance to complete a quick review and this is what I came up with:

DWM File Notes 1/20/2023:
 GW:
o MW-13 and MW-16 had the highest Concentrations and these MW’s were reported as destroyed in
2012,
 Replace and sample MW-13 and 16?
7
 Model Out WSW-3
 Abandon on site WSW-1 and WSW-2 (I believe that WSW-1 and WSW-2 are within the 250 feet from source;
WSW-2 may be outside the 250 feet but would need to confirm distance/location and be sampled in order to be
potentially be permitted to remain onsite as a irrigation well only):
o The receptor map in the 2021 update shows WSW-1 and WSW-2 out of the 250 foot radius, however
the site map in the same report tells conflicting information (pages from the 2021 report attached)
 Soil: Per RRA completed by James Brown on 9/23/2004 states that soil is above residential MSCC’s but below
Industrial/Commercial MSCC’s
o If can abandon WSW-1 and WSW-2, Model out WSW-3, NRP site soil and GW (naming offsite property
w/ gw contamination) – than NFA

So what I am asking you is….do you agree that MW-13 and MW-16 (or any of the other MW’s in the area of the highest
contaminant concentrations, reported as destroyed in 2012) should be replaced and sampled prior to modeling?

If you have a chance to look this over, let me know what you think. I am in the office too if you want to talk. If you do
believe that MW’s need to be replaced, I can send a NORR for the work to the RP.

Thank you

Liz Price
Hydrogeologist / Wilmington Regional Office
Division of Waste Management, UST Section
North Carolina Department of Environmental Quality
Office: [phone]
[e-mail]

Wilmington Regional Office Fayetteville Regional Office

DWM Site Locator DWM UST Section Website DWM Laserfiche Public Search DWM UST Permitting and
Inspection

For spills or other environmental emergencies after hours:
NC DEQ DWM Duty Phone [phone]
NC State Emergency Management 1-800-858-0368
National Response Center 1-800-424-8802

8

From: Rae Brown <[e-mail]>
Sent: Tuesday, January 17, 2023 2:29 PM
To: Price, Liz <[e-mail]>
Subject: [External] DW Tatum (GRI 2081) EPATA

CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to
Report Spam.

Hi Liz,

Attached is the TA for the biannual sampling at the site. I would like to collect data and run a model to determine if the
receptors are really at risk.

Thanks
Rae

Rae Troiano Brown, P.G.
Project Manager
Geological Resources, Inc.
Celebrating 50 years of serving our clients
113 Firetower Road, Suite G | Winterville, NC 28590 | website | facebook |
704-845-4010-office | 252-227-3005-cell | 252-321-6094-fax

Email correspondence to and from this address may be subject to the North Carolina Public Records Law and may be disclosed to third parties by an authorized state official.
Site Name City / County Sampson Incident #15274
Resp Pty Name / Contact Incident Mgr Region FAY
RP Type (Owner/Operator / Landowner / Attny‐in‐fact)Change Order? Prev. TA #19
Consultant / Project Mgr Rae Troiano Brown
Telephone / Fax Number Task Authorization Number:2 ChangeOrd:
Project Mgr Email Site Risk / Rank / Abatement:H 185 R RRA Date:9/23/2004
Proposal# / Scope Dates % Commercial (C=100%,  NC=0%,  Both=1%‐99%)
Has STF Eligibility Been Determined? (Y/N)Site Status (Active  or  NFA Date)
With Claim: [  ] All Main Consultant/Contractor invoices attached? [  ] Proof of payment attached directly to the front of each invoice?
 Important: The date of reimbursement is dependent on the Trust Fund balance. There may be a delay in the reimbursement of claims for work under this ePATA.
3r
d
 Pt
y
 De
d
?
Task #Lab / 
SubCode RO
 Au
t
h
Proposed 
Rate/Price
(Consultant)
TA
T
y
p
e
=
"
D
I
RE
C
T
E
D
 ‐

CA
B
 ON
L
Y
"
,

"R
O
 Su
p
v
.

Proposed Task 
Subtotal
(Consultant)
Final 
Preapproved 
Subtotal
(UST Section)
Claimed 
Amount3
(Consultant)
3.080 1 / permit Y $250.00 Y $250.00 $250.00 /
3.101 60 / feet Y $12.50 Y $750.00 $750.00 /
3.113 60 / feet Y $50.00 Y $3,000.00 $3,000.00 /
3.118 60 / feet Y $5.00 Y $300.00 $300.00 /
3.351 2 / wells Y $80.00 Y $160.00 $160.00 /
3.397 1 / Mobe Y $100.00 Y $100.00 $100.00 /
3.398 1 / Mobe Y $350.00 Y $350.00 $350.00 /
3.500 2 / nights Y $151.00 Y $302.00 $302.00 /
4.031 27 / wells Y $110.00 Y $2,970.00 $2,970.00 /
4.080 2 /sample pt.Y $45.00 Y $90.00 $90.00 /
4.090 #272 29 / samples Y $66.00 Y $1,914.00 $1,914.00 /
4.090 #409 1 / sample Y $84.00 Y $84.00 $84.00 /
4.090 #410 1 / sample Y $187.00 Y $187.00 $187.00 /
4.090 #421 1 / sample Y $58.00 Y $58.00 $58.00 /
4.090 #422 1 / sample Y $100.00 Y $100.00 $100.00 /
4.090 #441 27 / samples 0 $14.00 N $378.00 $0.00 /
4.090 #490 27 / samples 0 $20.00 N $540.00 $0.00 /
4.090 #510 27 / samples 0 $15.00 N $405.00 $0.00 /
4.090 #521 27 / samples 0 $70.00 N $1,890.00 $0.00 /
4.091 4 /shipments 2 $60.00 Y $240.00 $120.00 /
5.070 1 / event 0 $2,800.00 N $2,800.00 $0.00 /
6.090 1 / report Y $1,125.00 Y $1,125.00 $1,125.00 /
12.030 2 / nights 1 $151.00 Y $302.00 $151.00 /
12.050 2 / trips Y $250.00 Y $500.00 $500.00 /
12.055 2 / trips Y $50.00 Y $100.00 $100.00 /
//
//
Requested Preapproved Claimed 3
 TOTAL:$18,895.00 $12,611.00 TOTAL:
Total Standard Costs (Not Third Party)$18,895.00 $12,611.00 Total Standard Costs
Total applied as Third Party Deductible/Damage Costs $0.00 $0.00 Total Third Pty Costs
Process Tracking (Date)
TA Submittal: 3/9/23 by: (PM)(Reserved for RO)
RO Review: 3/12/23 by: (IM) Joint UST Preapproval Confirmed By: Date1 3/14/2023
CO Review: 3/14/23 by: (STF) RP or Designee Receipt Confirmation By: Date 4
1 ‐ This ePATA expires one year from the Joint UST Preapproval date.  This does not extend, alter, or supersede any regulatory deadlines (e.g., NORR's, NOV's, Enforcements, etc.)
2 ‐ THE ONE YEAR STATUTE OF LIMITATIONS APPLIES TO EACH INDIVIDUAL TASK. Costs must be claimed within one year of completion of that task to be reimbursable.
3 ‐ Only Tasks included on this ePATA may be claimed.  Do not include other Tasks or claimed costs (i.e., Claim preparation) that were not preapproved or the claim will be returned.
4 ‐ Preapproval is not valid (i.e., claimable) until receipt is signed as 'Confirmed' by the RP or their designee and returned to the Trust Fund within a week of approval. Signature
indicates acknowledgement of the tasks and amounts approved.  Any objections/appeals must be submitted via Change Order prior to work proceeding. Scope/cost
negotiations do not supersede other regulatory deadlines as described in #1 above.  Also, any ePATA that has been signed as 'Confirmed' by both the UST Section and RP
is not to be modified without written consent by all signatories.
5 ‐ Tasks approved on Directed ‐ CAB Only ePATAs must be performed in accordance with all applicable rules, statutes, and RRD Task Scopes of Work to be reimbursed in full.
DWM/UST ePATA 4/1/2022
DIRECTED COSTS
Clinton
(Must Complete with Claim Submittal)(See Instructions / RRD for Tasks requiring Preapproval / Task Authorization)
Owner/Operator
704‐845‐4010
(Reserved for Incident Manager)
PREAPPROVAL / TASK AUTHORIZATION
DW Tatum
Note: This Electronic Preapproval Task Authorization (ePATA) shall be used to receive preapproval from the UST Section. A proposal,including maps and figures,must be attached
to elaborate on the costs for the tasks listed below that describes the scope of work and the rationale for the proposed activities.If, following completion of this ePATA, you
discover that unexpected tasks must be performed, incurring costs for tasks not originally included with this form, you must complete and submit a separate ePATA request
designated as a "Change Order" in the provided space above prior to conducting those tasks. Include a copy of the prior ePATA form for confirmation. Please attach this form to
the cover of the corresponding claim when requesting reimbursement. IMPORTANT:Only one claim may be submitted per ePATA and all work on the ePATA must have been
completed within 12 months of the completion dateof the FIRST completed task to remain within theStatute of Limitations. All ePATAs submitted within a claim are closed with that
claim, and may not be re-used in a separate submittal, even for costs or tasks that were not originally claimed. Final reimbursement of costs associated with the Total Claimed
amount below may be affected by the eligibility status of the site (i.e., deductibles, apportionment, etc.), and the documentary validation of incurred costs as reasonable and
necessary expenses per 15A NCAC 2P .0402 and .0404.
FINAL REIMBURSEMENT
[e-mail]
Wellman Oil Company, Inc.
Geological Resources, Inc.
Liz Price
ActiveYES
23‐034 April 2023
704‐845‐4012
LP
WER
Proposed 
Units / Type
(Consultant)
Dates of Work
(Consultant)
Started1  /  Completed2
(Initials)
RTB
ELECTRONIC PREAPPROVAL TASK AUTHORIZATION FORM
Dept of Environmental Quality  ‐Division of Waste Management
Approval of  MW installation and sampling event as request in active site NORR, Fate & Transport modeling can be completed once/if all wells are below GCLs and no FP ‐LP
As Mobe was requested for Drilling and a Mobe was requested for sampling, assumed that overnights were for sampling.  As sampling reduced, also reduced overnight ‐LP 
3/14/23
2081 Received MAR 14 2023

APPENDIX B
Right-of-Access Documentation

APPENDIX C
Laboratory Report – Ground Water Samples

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

8/8/2023
Geological Resources, Inc. Rae Brown
113 West Firetower Road, Suite G Winterville, NC, 28590
Ref: Analytical Testing
Lab Report Number: 23-213-0004 Client Project Description: DW Tatum
GRI #2081
Dear Rae Brown:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 8/1/2023 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love Project Manager
Page 1 of 94
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202437735State ProgramNorth Carolina
12/31/2023402State ProgramNorth Carolina
07/31/202399012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/23-213-0004
Page 2 of 94
Report Number:
Sample Summary Table
Client Project Description:
23-213-0004
DW Tatum
GRI #2081
Lab No Client Sample ID Matrix Date Collected Date Received
07/31/2023 08:04Aqueous 91144 Trip Blank 08/01/2023 10:30
07/31/2023 10:25Aqueous 91145 T-1 08/01/2023 10:30
07/31/2023 10:41Aqueous 91146 T-2 08/01/2023 10:30
07/31/2023 10:57Aqueous 91147 T-3 08/01/2023 10:30
07/31/2023 11:12Aqueous 91148 MW-1 08/01/2023 10:30
07/31/2023 11:26Aqueous 91149 MW-4 08/01/2023 10:30
07/31/2023 11:40Aqueous 91150 MW-5 08/01/2023 10:30
07/31/2023 11:54Aqueous 91151 MW-6 08/01/2023 10:30
07/31/2023 12:09Aqueous 91152 MW-9 08/01/2023 10:30
07/31/2023 12:24Aqueous 91153 MW-12 08/01/2023 10:30
07/31/2023 12:39Aqueous 91154 MW-14 08/01/2023 10:30
07/31/2023 12:56Aqueous 91155 MW-15 08/01/2023 10:30
07/31/2023 13:11Aqueous 91156 MW-19 08/01/2023 10:30
07/31/2023 13:25Aqueous 91157 MW-21 08/01/2023 10:30
07/31/2023 13:38Aqueous 91158 MW-24 08/01/2023 10:30
07/31/2023 13:51Aqueous 91159 MW-22 08/01/2023 10:30
07/31/2023 14:04Aqueous 91160 MW-23 08/01/2023 10:30
07/31/2023 14:20Aqueous 91161 MW-25 08/01/2023 10:30
Page 3 of 94
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-213-0004
Report Limit
Project:DW Tatum
V 91147T-3
J2.74 08/02/2023 20:436200BAcetoneµg/L 1.80
V 91148MW-1
0.916 08/02/2023 21:086200BBenzeneµg/L 0.180
0.862 08/02/2023 21:086200Bn-Butylbenzene µg/L 0.180
0.791 08/02/2023 21:086200Bsec-Butyl benzene µg/L 0.200
40.7 08/02/2023 21:086200BEthylbenzeneµg/L 0.170
5.32 08/02/2023 21:086200BIsopropylbenzeneµg/L 0.180
0.549 08/02/2023 21:086200B4-Isopropyl toluene µg/L 0.089
24.1 08/02/2023 21:086200BNaphthaleneµg/L 0.470
8.66 08/02/2023 21:086200Bn-Propylbenzene µg/L 0.190
2.62 08/02/2023 21:086200BTolueneµg/L 0.220
93.7 08/03/2023 19:146200B1,2,4-Trimethylbenzene µg/L 1.90
5.59 08/02/2023 21:086200B1,3,5-Trimethylbenzene µg/L 0.180
10.5 08/02/2023 21:086200Bo-Xylene µg/L 0.210
13.6 08/02/2023 21:086200Bm,p-Xylene µg/L 0.420
24.1 08/02/2023 21:086200BXylene (Total)µg/L 0.210
V 91155MW-15
4.87 08/02/2023 21:336200BNaphthaleneµg/L 0.470
J0.372 08/02/2023 21:336200B1,2,4-Trimethylbenzene µg/L 0.190
V 91158MW-24
J8.87 08/02/2023 19:296200BAcetoneµg/L 1.80
J0.271 08/02/2023 19:296200Bsec-Butyl benzene µg/L 0.200
2.22 08/02/2023 19:296200BDi-Isopropyl Ether (DIPE)µg/L 0.500
0.549 08/02/2023 19:296200BEthylbenzeneµg/L 0.170
J0.858 08/02/2023 19:296200B2-Hexanone µg/L 0.380
2.81 08/02/2023 19:296200BIsopropylbenzeneµg/L 0.180
220 08/03/2023 18:496200BMethyl tert-butyl ether (MTBE)µg/L 1.40
0.500 08/02/2023 19:296200Bn-Propylbenzene µg/L 0.190
J0.266 08/02/2023 19:296200BTolueneµg/L 0.220
V 91161MW-25
15.4 08/03/2023 09:596200BBenzeneµg/L 1.80
6.74 08/03/2023 09:596200BDi-Isopropyl Ether (DIPE)µg/L 5.00
4440 08/03/2023 21:186200BMethyl tert-butyl ether (MTBE)µg/L 14.0
Page 4 of 94

Client: Geological Resources, Inc. CASE NARRATIVE
Project: DW Tatum Lab Report Number: 23-213-0004
Date: 8/8/2023
Volatile Organic Compounds - GC/MS Method 6200B Analyte: 1,2,3-Trichlorobenzene QC Batch No: V36181/V36164
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: Vinyl acetate QC Batch No: V36181/V36164
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.

Page 5 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:Trip Blank
91144 Matrix:
7/31/2023 8:04
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 08/02/23 14:08 V36165MSA
<0.180 µg/L 0.180 0.500Benzene 1 08/02/23 14:08 V36165MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/02/23 14:08 V36165MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/02/23 14:08 V36165MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/02/23 14:08 V36165MSA
<1.50 µg/L 1.50 5.00Bromoform 1 08/02/23 14:08 V36165MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 08/02/23 14:08 V36165MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/02/23 14:08 V36165MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 08/02/23 14:08 V36165MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/02/23 14:08 V36165MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/02/23 14:08 V36165MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/02/23 14:08 V36165MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/02/23 14:08 V36165MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 08/02/23 14:08 V36165MSA
<0.220 µg/L 0.220 0.500Chloroform 1 08/02/23 14:08 V36165MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 08/02/23 14:08 V36165MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/02/23 14:08 V36165MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/02/23 14:08 V36165MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/02/23 14:08 V36165MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/02/23 14:08 V36165MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 08/02/23 14:08 V36165MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/02/23 14:08 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 6 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:Trip Blank
91144 Matrix:
7/31/2023 8:04
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/02/23 14:08 V36165MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/02/23 14:08 V36165MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/02/23 14:08 V36165MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/02/23 14:08 V36165MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/02/23 14:08 V36165MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/02/23 14:08 V36165MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/02/23 14:08 V36165MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/02/23 14:08 V36165MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/02/23 14:08 V36165MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 08/02/23 14:08 V36165MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/02/23 14:08 V36165MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/02/23 14:08 V36165MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/02/23 14:08 V36165MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/02/23 14:08 V36165MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/02/23 14:08 V36165MSA
<42.0 µg/L 42.0 200Ethanol 1 08/02/23 14:08 V36165MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 08/02/23 14:08 V36165MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/02/23 14:08 V36165MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 08/02/23 14:08 V36165MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 08/02/23 14:08 V36165MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/02/23 14:08 V36165MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/02/23 14:08 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 7 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:Trip Blank
91144 Matrix:
7/31/2023 8:04
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/02/23 14:08 V36165MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/02/23 14:08 V36165MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/02/23 14:08 V36165MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 08/02/23 14:08 V36165MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 08/02/23 14:08 V36165MSA
<0.220 µg/L 0.220 0.500Styrene 1 08/02/23 14:08 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/02/23 14:08 V36165MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/02/23 14:08 V36165MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/02/23 14:08 V36165MSA
<0.220 µg/L 0.220 0.500Toluene 1 08/02/23 14:08 V36165MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/02/23 14:08 V36165MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/02/23 14:08 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/02/23 14:08 V36165MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/02/23 14:08 V36165MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/02/23 14:08 V36165MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/02/23 14:08 V36165MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/02/23 14:08 V36165MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/02/23 14:08 V36165MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/02/23 14:08 V36165MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/02/23 14:08 V36165MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/02/23 14:08 V36165MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 08/02/23 14:08 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 8 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:Trip Blank
91144 Matrix:
7/31/2023 8:04
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 08/02/23 14:08 V36165MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 08/02/23 14:08 V36165
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%08/02/23 14:081 MSA V36165
Surrogate: Dibromofluoromethane 97.8 Limits: 70-130%08/02/23 14:081 MSA V36165
Surrogate: 1,2-Dichloroethane - d4 92.6 Limits: 70-130%08/02/23 14:081 MSA V36165
Surrogate: Toluene-d8 112 Limits: 70-130%08/02/23 14:081 MSA V36165
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 9 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:T-1
91145 Matrix:
7/31/2023 10:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 08/02/23 15:22 V36165MSA
<0.180 µg/L 0.180 0.500Benzene 1 08/02/23 15:22 V36165MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/02/23 15:22 V36165MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/02/23 15:22 V36165MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/02/23 15:22 V36165MSA
<1.50 µg/L 1.50 5.00Bromoform 1 08/02/23 15:22 V36165MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 08/02/23 15:22 V36165MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/02/23 15:22 V36165MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 08/02/23 15:22 V36165MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/02/23 15:22 V36165MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/02/23 15:22 V36165MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/02/23 15:22 V36165MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/02/23 15:22 V36165MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 08/02/23 15:22 V36165MSA
<0.220 µg/L 0.220 0.500Chloroform 1 08/02/23 15:22 V36165MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 08/02/23 15:22 V36165MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/02/23 15:22 V36165MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/02/23 15:22 V36165MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/02/23 15:22 V36165MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/02/23 15:22 V36165MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 08/02/23 15:22 V36165MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/02/23 15:22 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 10 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:T-1
91145 Matrix:
7/31/2023 10:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/02/23 15:22 V36165MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/02/23 15:22 V36165MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/02/23 15:22 V36165MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/02/23 15:22 V36165MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/02/23 15:22 V36165MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/02/23 15:22 V36165MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/02/23 15:22 V36165MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/02/23 15:22 V36165MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/02/23 15:22 V36165MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 08/02/23 15:22 V36165MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/02/23 15:22 V36165MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/02/23 15:22 V36165MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/02/23 15:22 V36165MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/02/23 15:22 V36165MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/02/23 15:22 V36165MSA
<42.0 µg/L 42.0 200Ethanol 1 08/02/23 15:22 V36165MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 08/02/23 15:22 V36165MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/02/23 15:22 V36165MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 08/02/23 15:22 V36165MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 08/02/23 15:22 V36165MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/02/23 15:22 V36165MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/02/23 15:22 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 11 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:T-1
91145 Matrix:
7/31/2023 10:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/02/23 15:22 V36165MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/02/23 15:22 V36165MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/02/23 15:22 V36165MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 08/02/23 15:22 V36165MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 08/02/23 15:22 V36165MSA
<0.220 µg/L 0.220 0.500Styrene 1 08/02/23 15:22 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/02/23 15:22 V36165MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/02/23 15:22 V36165MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/02/23 15:22 V36165MSA
<0.220 µg/L 0.220 0.500Toluene 1 08/02/23 15:22 V36165MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/02/23 15:22 V36165MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/02/23 15:22 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/02/23 15:22 V36165MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/02/23 15:22 V36165MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/02/23 15:22 V36165MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/02/23 15:22 V36165MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/02/23 15:22 V36165MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/02/23 15:22 V36165MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/02/23 15:22 V36165MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/02/23 15:22 V36165MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/02/23 15:22 V36165MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 08/02/23 15:22 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 12 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:T-1
91145 Matrix:
7/31/2023 10:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 08/02/23 15:22 V36165MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 08/02/23 15:22 V36165
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%08/02/23 15:221 MSA V36165
Surrogate: Dibromofluoromethane 98.6 Limits: 70-130%08/02/23 15:221 MSA V36165
Surrogate: 1,2-Dichloroethane - d4 93.4 Limits: 70-130%08/02/23 15:221 MSA V36165
Surrogate: Toluene-d8 110 Limits: 70-130%08/02/23 15:221 MSA V36165
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 13 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:T-2
91146 Matrix:
7/31/2023 10:41
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 08/02/23 15:46 V36165MSA
<0.180 µg/L 0.180 0.500Benzene 1 08/02/23 15:46 V36165MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/02/23 15:46 V36165MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/02/23 15:46 V36165MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/02/23 15:46 V36165MSA
<1.50 µg/L 1.50 5.00Bromoform 1 08/02/23 15:46 V36165MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 08/02/23 15:46 V36165MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/02/23 15:46 V36165MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 08/02/23 15:46 V36165MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/02/23 15:46 V36165MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/02/23 15:46 V36165MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/02/23 15:46 V36165MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/02/23 15:46 V36165MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 08/02/23 15:46 V36165MSA
<0.220 µg/L 0.220 0.500Chloroform 1 08/02/23 15:46 V36165MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 08/02/23 15:46 V36165MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/02/23 15:46 V36165MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/02/23 15:46 V36165MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/02/23 15:46 V36165MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/02/23 15:46 V36165MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 08/02/23 15:46 V36165MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/02/23 15:46 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 14 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:T-2
91146 Matrix:
7/31/2023 10:41
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/02/23 15:46 V36165MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/02/23 15:46 V36165MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/02/23 15:46 V36165MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/02/23 15:46 V36165MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/02/23 15:46 V36165MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/02/23 15:46 V36165MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/02/23 15:46 V36165MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/02/23 15:46 V36165MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/02/23 15:46 V36165MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 08/02/23 15:46 V36165MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/02/23 15:46 V36165MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/02/23 15:46 V36165MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/02/23 15:46 V36165MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/02/23 15:46 V36165MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/02/23 15:46 V36165MSA
<42.0 µg/L 42.0 200Ethanol 1 08/02/23 15:46 V36165MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 08/02/23 15:46 V36165MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/02/23 15:46 V36165MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 08/02/23 15:46 V36165MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 08/02/23 15:46 V36165MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/02/23 15:46 V36165MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/02/23 15:46 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 15 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:T-2
91146 Matrix:
7/31/2023 10:41
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/02/23 15:46 V36165MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/02/23 15:46 V36165MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/02/23 15:46 V36165MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 08/02/23 15:46 V36165MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 08/02/23 15:46 V36165MSA
<0.220 µg/L 0.220 0.500Styrene 1 08/02/23 15:46 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/02/23 15:46 V36165MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/02/23 15:46 V36165MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/02/23 15:46 V36165MSA
<0.220 µg/L 0.220 0.500Toluene 1 08/02/23 15:46 V36165MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/02/23 15:46 V36165MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/02/23 15:46 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/02/23 15:46 V36165MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/02/23 15:46 V36165MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/02/23 15:46 V36165MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/02/23 15:46 V36165MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/02/23 15:46 V36165MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/02/23 15:46 V36165MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/02/23 15:46 V36165MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/02/23 15:46 V36165MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/02/23 15:46 V36165MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 08/02/23 15:46 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 16 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:T-2
91146 Matrix:
7/31/2023 10:41
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 08/02/23 15:46 V36165MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 08/02/23 15:46 V36165
Surrogate: 4-Bromofluorobenzene 88.4 Limits: 70-130%08/02/23 15:461 MSA V36165
Surrogate: Dibromofluoromethane 99.4 Limits: 70-130%08/02/23 15:461 MSA V36165
Surrogate: 1,2-Dichloroethane - d4 98.0 Limits: 70-130%08/02/23 15:461 MSA V36165
Surrogate: Toluene-d8 115 Limits: 70-130%08/02/23 15:461 MSA V36165
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 17 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:T-3
91147 Matrix:
7/31/2023 10:57
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
2.74 J µg/L 1.80 10.0Acetone 1 08/02/23 20:43 V36165MSA
<0.180 µg/L 0.180 0.500Benzene 1 08/02/23 20:43 V36165MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/02/23 20:43 V36165MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/02/23 20:43 V36165MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/02/23 20:43 V36165MSA
<1.50 µg/L 1.50 5.00Bromoform 1 08/02/23 20:43 V36165MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 08/02/23 20:43 V36165MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/02/23 20:43 V36165MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 08/02/23 20:43 V36165MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/02/23 20:43 V36165MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/02/23 20:43 V36165MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/02/23 20:43 V36165MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/02/23 20:43 V36165MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 08/02/23 20:43 V36165MSA
<0.220 µg/L 0.220 0.500Chloroform 1 08/02/23 20:43 V36165MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 08/02/23 20:43 V36165MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/02/23 20:43 V36165MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/02/23 20:43 V36165MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/02/23 20:43 V36165MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/02/23 20:43 V36165MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 08/02/23 20:43 V36165MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/02/23 20:43 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 18 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:T-3
91147 Matrix:
7/31/2023 10:57
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/02/23 20:43 V36165MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/02/23 20:43 V36165MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/02/23 20:43 V36165MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/02/23 20:43 V36165MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/02/23 20:43 V36165MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/02/23 20:43 V36165MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/02/23 20:43 V36165MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/02/23 20:43 V36165MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/02/23 20:43 V36165MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 08/02/23 20:43 V36165MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/02/23 20:43 V36165MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/02/23 20:43 V36165MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/02/23 20:43 V36165MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/02/23 20:43 V36165MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/02/23 20:43 V36165MSA
<42.0 µg/L 42.0 200Ethanol 1 08/02/23 20:43 V36165MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 08/02/23 20:43 V36165MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/02/23 20:43 V36165MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 08/02/23 20:43 V36165MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 08/02/23 20:43 V36165MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/02/23 20:43 V36165MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/02/23 20:43 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 19 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:T-3
91147 Matrix:
7/31/2023 10:57
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/02/23 20:43 V36165MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/02/23 20:43 V36165MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/02/23 20:43 V36165MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 08/02/23 20:43 V36165MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 08/02/23 20:43 V36165MSA
<0.220 µg/L 0.220 0.500Styrene 1 08/02/23 20:43 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/02/23 20:43 V36165MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/02/23 20:43 V36165MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/02/23 20:43 V36165MSA
<0.220 µg/L 0.220 0.500Toluene 1 08/02/23 20:43 V36165MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/02/23 20:43 V36165MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/02/23 20:43 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/02/23 20:43 V36165MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/02/23 20:43 V36165MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/02/23 20:43 V36165MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/02/23 20:43 V36165MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/02/23 20:43 V36165MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/02/23 20:43 V36165MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/02/23 20:43 V36165MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/02/23 20:43 V36165MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/02/23 20:43 V36165MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 08/02/23 20:43 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 20 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:T-3
91147 Matrix:
7/31/2023 10:57
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 08/02/23 20:43 V36165MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 08/02/23 20:43 V36165
Surrogate: 4-Bromofluorobenzene 88.2 Limits: 70-130%08/02/23 20:431 MSA V36165
Surrogate: Dibromofluoromethane 100 Limits: 70-130%08/02/23 20:431 MSA V36165
Surrogate: 1,2-Dichloroethane - d4 99.0 Limits: 70-130%08/02/23 20:431 MSA V36165
Surrogate: Toluene-d8 109 Limits: 70-130%08/02/23 20:431 MSA V36165
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 21 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-1
91148 Matrix:
7/31/2023 11:12
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00 V36274 08/03/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 08/02/23 21:08 V36165MSA
0.916 µg/L 0.180 0.500Benzene 1 08/02/23 21:08 V36165MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/02/23 21:08 V36165MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/02/23 21:08 V36165MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/02/23 21:08 V36165MSA
<1.50 µg/L 1.50 5.00Bromoform 1 08/02/23 21:08 V36165MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 08/02/23 21:08 V36165MSA
0.862 µg/L 0.180 0.500n-Butylbenzene 1 08/02/23 21:08 V36165MSA
0.791 µg/L 0.200 0.500sec-Butyl benzene 1 08/02/23 21:08 V36165MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/02/23 21:08 V36165MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/02/23 21:08 V36165MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/02/23 21:08 V36165MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/02/23 21:08 V36165MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 08/02/23 21:08 V36165MSA
<0.220 µg/L 0.220 0.500Chloroform 1 08/02/23 21:08 V36165MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 08/02/23 21:08 V36165MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/02/23 21:08 V36165MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/02/23 21:08 V36165MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/02/23 21:08 V36165MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/02/23 21:08 V36165MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 08/02/23 21:08 V36165MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/02/23 21:08 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 22 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-1
91148 Matrix:
7/31/2023 11:12
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00 V36274 08/03/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/02/23 21:08 V36165MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/02/23 21:08 V36165MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/02/23 21:08 V36165MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/02/23 21:08 V36165MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/02/23 21:08 V36165MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/02/23 21:08 V36165MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/02/23 21:08 V36165MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/02/23 21:08 V36165MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/02/23 21:08 V36165MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 08/02/23 21:08 V36165MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/02/23 21:08 V36165MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/02/23 21:08 V36165MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/02/23 21:08 V36165MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/02/23 21:08 V36165MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/02/23 21:08 V36165MSA
<42.0 µg/L 42.0 200Ethanol 1 08/02/23 21:08 V36165MSA
40.7 µg/L 0.170 0.500Ethylbenzene 1 08/02/23 21:08 V36165MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/02/23 21:08 V36165MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 08/02/23 21:08 V36165MSA
5.32 µg/L 0.180 0.500Isopropylbenzene 1 08/02/23 21:08 V36165MSA
0.549 µg/L 0.089 0.5004-Isopropyl toluene 1 08/02/23 21:08 V36165MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/02/23 21:08 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 23 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-1
91148 Matrix:
7/31/2023 11:12
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00 V36274 08/03/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/02/23 21:08 V36165MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/02/23 21:08 V36165MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/02/23 21:08 V36165MSA
24.1 µg/L 0.470 1.00Naphthalene 1 08/02/23 21:08 V36165MSA
8.66 µg/L 0.190 0.500n-Propylbenzene 1 08/02/23 21:08 V36165MSA
<0.220 µg/L 0.220 0.500Styrene 1 08/02/23 21:08 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/02/23 21:08 V36165MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/02/23 21:08 V36165MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/02/23 21:08 V36165MSA
2.62 µg/L 0.220 0.500Toluene 1 08/02/23 21:08 V36165MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/02/23 21:08 V36165MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/02/23 21:08 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/02/23 21:08 V36165MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/02/23 21:08 V36165MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/02/23 21:08 V36165MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/02/23 21:08 V36165MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/02/23 21:08 V36165MSA
93.7 µg/L 1.90 5.001,2,4-Trimethylbenzene 10 08/03/23 19:14 V36275MSA
5.59 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/02/23 21:08 V36165MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/02/23 21:08 V36165MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/02/23 21:08 V36165MSA
10.5 µg/L 0.210 0.500o-Xylene 1 08/02/23 21:08 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 24 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-1
91148 Matrix:
7/31/2023 11:12
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00 V36274 08/03/23 09:00
13.6 µg/L 0.420 1.00m,p-Xylene 1 08/02/23 21:08 V36165MSA
24.1 µg/L 0.210 0.500Xylene (Total)1 08/02/23 21:08 V36165
Surrogate: 4-Bromofluorobenzene 95.6 Limits: 70-130%08/02/23 21:081 MSA V36165
Surrogate: Dibromofluoromethane 98.6 Limits: 70-130%08/02/23 21:081 MSA V36165
Surrogate: 1,2-Dichloroethane - d4 94.4 Limits: 70-130%08/02/23 21:081 MSA V36165
Surrogate: Toluene-d8 111 Limits: 70-130%08/02/23 21:081 MSA V36165
Surrogate: 4-Bromofluorobenzene 88.4 Limits: 70-130%08/03/23 19:1410 MSA V36275
Surrogate: Dibromofluoromethane 97.8 Limits: 70-130%08/03/23 19:1410 MSA V36275
Surrogate: 1,2-Dichloroethane - d4 92.8 Limits: 70-130%08/03/23 19:1410 MSA V36275
Surrogate: Toluene-d8 120 Limits: 70-130%08/03/23 19:1410 MSA V36275
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 25 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-4
91149 Matrix:
7/31/2023 11:26
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 08/02/23 16:11 V36165MSA
<0.180 µg/L 0.180 0.500Benzene 1 08/02/23 16:11 V36165MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/02/23 16:11 V36165MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/02/23 16:11 V36165MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/02/23 16:11 V36165MSA
<1.50 µg/L 1.50 5.00Bromoform 1 08/02/23 16:11 V36165MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 08/02/23 16:11 V36165MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/02/23 16:11 V36165MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 08/02/23 16:11 V36165MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/02/23 16:11 V36165MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/02/23 16:11 V36165MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/02/23 16:11 V36165MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/02/23 16:11 V36165MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 08/02/23 16:11 V36165MSA
<0.220 µg/L 0.220 0.500Chloroform 1 08/02/23 16:11 V36165MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 08/02/23 16:11 V36165MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/02/23 16:11 V36165MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/02/23 16:11 V36165MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/02/23 16:11 V36165MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/02/23 16:11 V36165MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 08/02/23 16:11 V36165MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/02/23 16:11 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 26 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-4
91149 Matrix:
7/31/2023 11:26
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/02/23 16:11 V36165MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/02/23 16:11 V36165MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/02/23 16:11 V36165MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/02/23 16:11 V36165MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/02/23 16:11 V36165MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/02/23 16:11 V36165MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/02/23 16:11 V36165MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/02/23 16:11 V36165MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/02/23 16:11 V36165MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 08/02/23 16:11 V36165MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/02/23 16:11 V36165MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/02/23 16:11 V36165MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/02/23 16:11 V36165MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/02/23 16:11 V36165MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/02/23 16:11 V36165MSA
<42.0 µg/L 42.0 200Ethanol 1 08/02/23 16:11 V36165MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 08/02/23 16:11 V36165MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/02/23 16:11 V36165MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 08/02/23 16:11 V36165MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 08/02/23 16:11 V36165MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/02/23 16:11 V36165MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/02/23 16:11 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 27 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-4
91149 Matrix:
7/31/2023 11:26
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/02/23 16:11 V36165MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/02/23 16:11 V36165MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/02/23 16:11 V36165MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 08/02/23 16:11 V36165MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 08/02/23 16:11 V36165MSA
<0.220 µg/L 0.220 0.500Styrene 1 08/02/23 16:11 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/02/23 16:11 V36165MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/02/23 16:11 V36165MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/02/23 16:11 V36165MSA
<0.220 µg/L 0.220 0.500Toluene 1 08/02/23 16:11 V36165MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/02/23 16:11 V36165MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/02/23 16:11 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/02/23 16:11 V36165MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/02/23 16:11 V36165MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/02/23 16:11 V36165MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/02/23 16:11 V36165MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/02/23 16:11 V36165MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/02/23 16:11 V36165MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/02/23 16:11 V36165MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/02/23 16:11 V36165MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/02/23 16:11 V36165MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 08/02/23 16:11 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 28 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-4
91149 Matrix:
7/31/2023 11:26
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 08/02/23 16:11 V36165MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 08/02/23 16:11 V36165
Surrogate: 4-Bromofluorobenzene 102 Limits: 70-130%08/02/23 16:111 MSA V36165
Surrogate: Dibromofluoromethane 98.2 Limits: 70-130%08/02/23 16:111 MSA V36165
Surrogate: 1,2-Dichloroethane - d4 92.0 Limits: 70-130%08/02/23 16:111 MSA V36165
Surrogate: Toluene-d8 113 Limits: 70-130%08/02/23 16:111 MSA V36165
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 29 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-5
91150 Matrix:
7/31/2023 11:40
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 08/02/23 16:36 V36165MSA
<0.180 µg/L 0.180 0.500Benzene 1 08/02/23 16:36 V36165MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/02/23 16:36 V36165MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/02/23 16:36 V36165MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/02/23 16:36 V36165MSA
<1.50 µg/L 1.50 5.00Bromoform 1 08/02/23 16:36 V36165MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 08/02/23 16:36 V36165MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/02/23 16:36 V36165MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 08/02/23 16:36 V36165MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/02/23 16:36 V36165MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/02/23 16:36 V36165MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/02/23 16:36 V36165MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/02/23 16:36 V36165MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 08/02/23 16:36 V36165MSA
<0.220 µg/L 0.220 0.500Chloroform 1 08/02/23 16:36 V36165MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 08/02/23 16:36 V36165MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/02/23 16:36 V36165MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/02/23 16:36 V36165MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/02/23 16:36 V36165MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/02/23 16:36 V36165MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 08/02/23 16:36 V36165MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/02/23 16:36 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 30 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-5
91150 Matrix:
7/31/2023 11:40
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/02/23 16:36 V36165MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/02/23 16:36 V36165MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/02/23 16:36 V36165MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/02/23 16:36 V36165MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/02/23 16:36 V36165MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/02/23 16:36 V36165MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/02/23 16:36 V36165MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/02/23 16:36 V36165MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/02/23 16:36 V36165MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 08/02/23 16:36 V36165MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/02/23 16:36 V36165MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/02/23 16:36 V36165MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/02/23 16:36 V36165MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/02/23 16:36 V36165MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/02/23 16:36 V36165MSA
<42.0 µg/L 42.0 200Ethanol 1 08/02/23 16:36 V36165MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 08/02/23 16:36 V36165MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/02/23 16:36 V36165MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 08/02/23 16:36 V36165MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 08/02/23 16:36 V36165MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/02/23 16:36 V36165MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/02/23 16:36 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 31 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-5
91150 Matrix:
7/31/2023 11:40
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/02/23 16:36 V36165MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/02/23 16:36 V36165MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/02/23 16:36 V36165MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 08/02/23 16:36 V36165MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 08/02/23 16:36 V36165MSA
<0.220 µg/L 0.220 0.500Styrene 1 08/02/23 16:36 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/02/23 16:36 V36165MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/02/23 16:36 V36165MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/02/23 16:36 V36165MSA
<0.220 µg/L 0.220 0.500Toluene 1 08/02/23 16:36 V36165MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/02/23 16:36 V36165MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/02/23 16:36 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/02/23 16:36 V36165MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/02/23 16:36 V36165MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/02/23 16:36 V36165MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/02/23 16:36 V36165MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/02/23 16:36 V36165MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/02/23 16:36 V36165MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/02/23 16:36 V36165MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/02/23 16:36 V36165MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/02/23 16:36 V36165MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 08/02/23 16:36 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 32 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-5
91150 Matrix:
7/31/2023 11:40
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 08/02/23 16:36 V36165MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 08/02/23 16:36 V36165
Surrogate: 4-Bromofluorobenzene 88.8 Limits: 70-130%08/02/23 16:361 MSA V36165
Surrogate: Dibromofluoromethane 98.8 Limits: 70-130%08/02/23 16:361 MSA V36165
Surrogate: 1,2-Dichloroethane - d4 95.4 Limits: 70-130%08/02/23 16:361 MSA V36165
Surrogate: Toluene-d8 110 Limits: 70-130%08/02/23 16:361 MSA V36165
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 33 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-6
91151 Matrix:
7/31/2023 11:54
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 08/02/23 17:01 V36165MSA
<0.180 µg/L 0.180 0.500Benzene 1 08/02/23 17:01 V36165MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/02/23 17:01 V36165MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/02/23 17:01 V36165MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/02/23 17:01 V36165MSA
<1.50 µg/L 1.50 5.00Bromoform 1 08/02/23 17:01 V36165MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 08/02/23 17:01 V36165MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/02/23 17:01 V36165MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 08/02/23 17:01 V36165MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/02/23 17:01 V36165MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/02/23 17:01 V36165MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/02/23 17:01 V36165MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/02/23 17:01 V36165MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 08/02/23 17:01 V36165MSA
<0.220 µg/L 0.220 0.500Chloroform 1 08/02/23 17:01 V36165MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 08/02/23 17:01 V36165MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/02/23 17:01 V36165MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/02/23 17:01 V36165MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/02/23 17:01 V36165MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/02/23 17:01 V36165MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 08/02/23 17:01 V36165MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/02/23 17:01 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 34 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-6
91151 Matrix:
7/31/2023 11:54
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/02/23 17:01 V36165MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/02/23 17:01 V36165MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/02/23 17:01 V36165MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/02/23 17:01 V36165MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/02/23 17:01 V36165MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/02/23 17:01 V36165MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/02/23 17:01 V36165MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/02/23 17:01 V36165MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/02/23 17:01 V36165MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 08/02/23 17:01 V36165MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/02/23 17:01 V36165MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/02/23 17:01 V36165MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/02/23 17:01 V36165MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/02/23 17:01 V36165MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/02/23 17:01 V36165MSA
<42.0 µg/L 42.0 200Ethanol 1 08/02/23 17:01 V36165MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 08/02/23 17:01 V36165MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/02/23 17:01 V36165MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 08/02/23 17:01 V36165MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 08/02/23 17:01 V36165MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/02/23 17:01 V36165MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/02/23 17:01 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 35 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-6
91151 Matrix:
7/31/2023 11:54
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/02/23 17:01 V36165MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/02/23 17:01 V36165MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/02/23 17:01 V36165MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 08/02/23 17:01 V36165MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 08/02/23 17:01 V36165MSA
<0.220 µg/L 0.220 0.500Styrene 1 08/02/23 17:01 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/02/23 17:01 V36165MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/02/23 17:01 V36165MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/02/23 17:01 V36165MSA
<0.220 µg/L 0.220 0.500Toluene 1 08/02/23 17:01 V36165MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/02/23 17:01 V36165MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/02/23 17:01 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/02/23 17:01 V36165MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/02/23 17:01 V36165MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/02/23 17:01 V36165MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/02/23 17:01 V36165MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/02/23 17:01 V36165MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/02/23 17:01 V36165MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/02/23 17:01 V36165MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/02/23 17:01 V36165MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/02/23 17:01 V36165MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 08/02/23 17:01 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 36 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-6
91151 Matrix:
7/31/2023 11:54
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 08/02/23 17:01 V36165MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 08/02/23 17:01 V36165
Surrogate: 4-Bromofluorobenzene 95.0 Limits: 70-130%08/02/23 17:011 MSA V36165
Surrogate: Dibromofluoromethane 101 Limits: 70-130%08/02/23 17:011 MSA V36165
Surrogate: 1,2-Dichloroethane - d4 99.6 Limits: 70-130%08/02/23 17:011 MSA V36165
Surrogate: Toluene-d8 109 Limits: 70-130%08/02/23 17:011 MSA V36165
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 37 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-9
91152 Matrix:
7/31/2023 12:09
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 08/02/23 17:25 V36165MSA
<0.180 µg/L 0.180 0.500Benzene 1 08/02/23 17:25 V36165MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/02/23 17:25 V36165MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/02/23 17:25 V36165MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/02/23 17:25 V36165MSA
<1.50 µg/L 1.50 5.00Bromoform 1 08/02/23 17:25 V36165MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 08/02/23 17:25 V36165MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/02/23 17:25 V36165MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 08/02/23 17:25 V36165MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/02/23 17:25 V36165MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/02/23 17:25 V36165MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/02/23 17:25 V36165MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/02/23 17:25 V36165MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 08/02/23 17:25 V36165MSA
<0.220 µg/L 0.220 0.500Chloroform 1 08/02/23 17:25 V36165MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 08/02/23 17:25 V36165MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/02/23 17:25 V36165MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/02/23 17:25 V36165MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/02/23 17:25 V36165MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/02/23 17:25 V36165MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 08/02/23 17:25 V36165MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/02/23 17:25 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 38 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-9
91152 Matrix:
7/31/2023 12:09
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/02/23 17:25 V36165MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/02/23 17:25 V36165MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/02/23 17:25 V36165MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/02/23 17:25 V36165MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/02/23 17:25 V36165MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/02/23 17:25 V36165MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/02/23 17:25 V36165MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/02/23 17:25 V36165MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/02/23 17:25 V36165MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 08/02/23 17:25 V36165MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/02/23 17:25 V36165MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/02/23 17:25 V36165MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/02/23 17:25 V36165MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/02/23 17:25 V36165MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/02/23 17:25 V36165MSA
<42.0 µg/L 42.0 200Ethanol 1 08/02/23 17:25 V36165MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 08/02/23 17:25 V36165MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/02/23 17:25 V36165MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 08/02/23 17:25 V36165MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 08/02/23 17:25 V36165MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/02/23 17:25 V36165MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/02/23 17:25 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 39 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-9
91152 Matrix:
7/31/2023 12:09
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/02/23 17:25 V36165MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/02/23 17:25 V36165MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/02/23 17:25 V36165MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 08/02/23 17:25 V36165MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 08/02/23 17:25 V36165MSA
<0.220 µg/L 0.220 0.500Styrene 1 08/02/23 17:25 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/02/23 17:25 V36165MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/02/23 17:25 V36165MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/02/23 17:25 V36165MSA
<0.220 µg/L 0.220 0.500Toluene 1 08/02/23 17:25 V36165MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/02/23 17:25 V36165MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/02/23 17:25 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/02/23 17:25 V36165MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/02/23 17:25 V36165MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/02/23 17:25 V36165MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/02/23 17:25 V36165MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/02/23 17:25 V36165MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/02/23 17:25 V36165MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/02/23 17:25 V36165MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/02/23 17:25 V36165MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/02/23 17:25 V36165MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 08/02/23 17:25 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 40 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-9
91152 Matrix:
7/31/2023 12:09
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 08/02/23 17:25 V36165MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 08/02/23 17:25 V36165
Surrogate: 4-Bromofluorobenzene 97.6 Limits: 70-130%08/02/23 17:251 MSA V36165
Surrogate: Dibromofluoromethane 99.2 Limits: 70-130%08/02/23 17:251 MSA V36165
Surrogate: 1,2-Dichloroethane - d4 93.8 Limits: 70-130%08/02/23 17:251 MSA V36165
Surrogate: Toluene-d8 111 Limits: 70-130%08/02/23 17:251 MSA V36165
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 41 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-12
91153 Matrix:
7/31/2023 12:24
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 08/02/23 17:50 V36165MSA
<0.180 µg/L 0.180 0.500Benzene 1 08/02/23 17:50 V36165MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/02/23 17:50 V36165MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/02/23 17:50 V36165MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/02/23 17:50 V36165MSA
<1.50 µg/L 1.50 5.00Bromoform 1 08/02/23 17:50 V36165MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 08/02/23 17:50 V36165MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/02/23 17:50 V36165MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 08/02/23 17:50 V36165MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/02/23 17:50 V36165MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/02/23 17:50 V36165MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/02/23 17:50 V36165MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/02/23 17:50 V36165MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 08/02/23 17:50 V36165MSA
<0.220 µg/L 0.220 0.500Chloroform 1 08/02/23 17:50 V36165MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 08/02/23 17:50 V36165MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/02/23 17:50 V36165MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/02/23 17:50 V36165MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/02/23 17:50 V36165MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/02/23 17:50 V36165MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 08/02/23 17:50 V36165MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/02/23 17:50 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 42 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-12
91153 Matrix:
7/31/2023 12:24
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/02/23 17:50 V36165MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/02/23 17:50 V36165MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/02/23 17:50 V36165MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/02/23 17:50 V36165MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/02/23 17:50 V36165MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/02/23 17:50 V36165MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/02/23 17:50 V36165MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/02/23 17:50 V36165MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/02/23 17:50 V36165MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 08/02/23 17:50 V36165MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/02/23 17:50 V36165MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/02/23 17:50 V36165MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/02/23 17:50 V36165MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/02/23 17:50 V36165MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/02/23 17:50 V36165MSA
<42.0 µg/L 42.0 200Ethanol 1 08/02/23 17:50 V36165MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 08/02/23 17:50 V36165MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/02/23 17:50 V36165MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 08/02/23 17:50 V36165MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 08/02/23 17:50 V36165MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/02/23 17:50 V36165MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/02/23 17:50 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 43 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-12
91153 Matrix:
7/31/2023 12:24
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/02/23 17:50 V36165MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/02/23 17:50 V36165MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/02/23 17:50 V36165MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 08/02/23 17:50 V36165MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 08/02/23 17:50 V36165MSA
<0.220 µg/L 0.220 0.500Styrene 1 08/02/23 17:50 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/02/23 17:50 V36165MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/02/23 17:50 V36165MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/02/23 17:50 V36165MSA
<0.220 µg/L 0.220 0.500Toluene 1 08/02/23 17:50 V36165MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/02/23 17:50 V36165MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/02/23 17:50 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/02/23 17:50 V36165MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/02/23 17:50 V36165MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/02/23 17:50 V36165MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/02/23 17:50 V36165MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/02/23 17:50 V36165MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/02/23 17:50 V36165MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/02/23 17:50 V36165MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/02/23 17:50 V36165MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/02/23 17:50 V36165MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 08/02/23 17:50 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 44 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-12
91153 Matrix:
7/31/2023 12:24
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 08/02/23 17:50 V36165MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 08/02/23 17:50 V36165
Surrogate: 4-Bromofluorobenzene 91.2 Limits: 70-130%08/02/23 17:501 MSA V36165
Surrogate: Dibromofluoromethane 98.8 Limits: 70-130%08/02/23 17:501 MSA V36165
Surrogate: 1,2-Dichloroethane - d4 92.8 Limits: 70-130%08/02/23 17:501 MSA V36165
Surrogate: Toluene-d8 111 Limits: 70-130%08/02/23 17:501 MSA V36165
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 45 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-14
91154 Matrix:
7/31/2023 12:39
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 08/02/23 18:15 V36165MSA
<0.180 µg/L 0.180 0.500Benzene 1 08/02/23 18:15 V36165MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/02/23 18:15 V36165MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/02/23 18:15 V36165MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/02/23 18:15 V36165MSA
<1.50 µg/L 1.50 5.00Bromoform 1 08/02/23 18:15 V36165MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 08/02/23 18:15 V36165MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/02/23 18:15 V36165MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 08/02/23 18:15 V36165MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/02/23 18:15 V36165MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/02/23 18:15 V36165MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/02/23 18:15 V36165MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/02/23 18:15 V36165MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 08/02/23 18:15 V36165MSA
<0.220 µg/L 0.220 0.500Chloroform 1 08/02/23 18:15 V36165MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 08/02/23 18:15 V36165MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/02/23 18:15 V36165MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/02/23 18:15 V36165MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/02/23 18:15 V36165MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/02/23 18:15 V36165MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 08/02/23 18:15 V36165MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/02/23 18:15 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 46 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-14
91154 Matrix:
7/31/2023 12:39
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/02/23 18:15 V36165MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/02/23 18:15 V36165MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/02/23 18:15 V36165MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/02/23 18:15 V36165MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/02/23 18:15 V36165MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/02/23 18:15 V36165MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/02/23 18:15 V36165MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/02/23 18:15 V36165MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/02/23 18:15 V36165MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 08/02/23 18:15 V36165MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/02/23 18:15 V36165MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/02/23 18:15 V36165MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/02/23 18:15 V36165MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/02/23 18:15 V36165MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/02/23 18:15 V36165MSA
<42.0 µg/L 42.0 200Ethanol 1 08/02/23 18:15 V36165MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 08/02/23 18:15 V36165MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/02/23 18:15 V36165MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 08/02/23 18:15 V36165MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 08/02/23 18:15 V36165MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/02/23 18:15 V36165MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/02/23 18:15 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 47 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-14
91154 Matrix:
7/31/2023 12:39
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/02/23 18:15 V36165MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/02/23 18:15 V36165MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/02/23 18:15 V36165MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 08/02/23 18:15 V36165MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 08/02/23 18:15 V36165MSA
<0.220 µg/L 0.220 0.500Styrene 1 08/02/23 18:15 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/02/23 18:15 V36165MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/02/23 18:15 V36165MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/02/23 18:15 V36165MSA
<0.220 µg/L 0.220 0.500Toluene 1 08/02/23 18:15 V36165MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/02/23 18:15 V36165MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/02/23 18:15 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/02/23 18:15 V36165MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/02/23 18:15 V36165MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/02/23 18:15 V36165MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/02/23 18:15 V36165MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/02/23 18:15 V36165MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/02/23 18:15 V36165MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/02/23 18:15 V36165MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/02/23 18:15 V36165MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/02/23 18:15 V36165MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 08/02/23 18:15 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 48 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-14
91154 Matrix:
7/31/2023 12:39
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 08/02/23 18:15 V36165MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 08/02/23 18:15 V36165
Surrogate: 4-Bromofluorobenzene 90.6 Limits: 70-130%08/02/23 18:151 MSA V36165
Surrogate: Dibromofluoromethane 98.8 Limits: 70-130%08/02/23 18:151 MSA V36165
Surrogate: 1,2-Dichloroethane - d4 95.4 Limits: 70-130%08/02/23 18:151 MSA V36165
Surrogate: Toluene-d8 111 Limits: 70-130%08/02/23 18:151 MSA V36165
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 49 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-15
91155 Matrix:
7/31/2023 12:56
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 08/02/23 21:33 V36165MSA
<0.180 µg/L 0.180 0.500Benzene 1 08/02/23 21:33 V36165MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/02/23 21:33 V36165MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/02/23 21:33 V36165MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/02/23 21:33 V36165MSA
<1.50 µg/L 1.50 5.00Bromoform 1 08/02/23 21:33 V36165MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 08/02/23 21:33 V36165MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/02/23 21:33 V36165MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 08/02/23 21:33 V36165MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/02/23 21:33 V36165MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/02/23 21:33 V36165MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/02/23 21:33 V36165MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/02/23 21:33 V36165MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 08/02/23 21:33 V36165MSA
<0.220 µg/L 0.220 0.500Chloroform 1 08/02/23 21:33 V36165MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 08/02/23 21:33 V36165MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/02/23 21:33 V36165MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/02/23 21:33 V36165MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/02/23 21:33 V36165MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/02/23 21:33 V36165MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 08/02/23 21:33 V36165MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/02/23 21:33 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 50 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-15
91155 Matrix:
7/31/2023 12:56
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/02/23 21:33 V36165MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/02/23 21:33 V36165MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/02/23 21:33 V36165MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/02/23 21:33 V36165MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/02/23 21:33 V36165MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/02/23 21:33 V36165MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/02/23 21:33 V36165MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/02/23 21:33 V36165MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/02/23 21:33 V36165MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 08/02/23 21:33 V36165MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/02/23 21:33 V36165MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/02/23 21:33 V36165MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/02/23 21:33 V36165MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/02/23 21:33 V36165MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/02/23 21:33 V36165MSA
<42.0 µg/L 42.0 200Ethanol 1 08/02/23 21:33 V36165MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 08/02/23 21:33 V36165MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/02/23 21:33 V36165MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 08/02/23 21:33 V36165MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 08/02/23 21:33 V36165MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/02/23 21:33 V36165MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/02/23 21:33 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 51 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-15
91155 Matrix:
7/31/2023 12:56
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/02/23 21:33 V36165MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/02/23 21:33 V36165MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/02/23 21:33 V36165MSA
4.87 µg/L 0.470 1.00Naphthalene 1 08/02/23 21:33 V36165MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 08/02/23 21:33 V36165MSA
<0.220 µg/L 0.220 0.500Styrene 1 08/02/23 21:33 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/02/23 21:33 V36165MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/02/23 21:33 V36165MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/02/23 21:33 V36165MSA
<0.220 µg/L 0.220 0.500Toluene 1 08/02/23 21:33 V36165MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/02/23 21:33 V36165MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/02/23 21:33 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/02/23 21:33 V36165MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/02/23 21:33 V36165MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/02/23 21:33 V36165MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/02/23 21:33 V36165MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/02/23 21:33 V36165MSA
0.372 J µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/02/23 21:33 V36165MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/02/23 21:33 V36165MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/02/23 21:33 V36165MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/02/23 21:33 V36165MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 08/02/23 21:33 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 52 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-15
91155 Matrix:
7/31/2023 12:56
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 08/02/23 21:33 V36165MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 08/02/23 21:33 V36165
Surrogate: 4-Bromofluorobenzene 97.6 Limits: 70-130%08/02/23 21:331 MSA V36165
Surrogate: Dibromofluoromethane 97.4 Limits: 70-130%08/02/23 21:331 MSA V36165
Surrogate: 1,2-Dichloroethane - d4 92.2 Limits: 70-130%08/02/23 21:331 MSA V36165
Surrogate: Toluene-d8 111 Limits: 70-130%08/02/23 21:331 MSA V36165
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 53 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-19
91156 Matrix:
7/31/2023 13:11
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 08/02/23 18:40 V36165MSA
<0.180 µg/L 0.180 0.500Benzene 1 08/02/23 18:40 V36165MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/02/23 18:40 V36165MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/02/23 18:40 V36165MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/02/23 18:40 V36165MSA
<1.50 µg/L 1.50 5.00Bromoform 1 08/02/23 18:40 V36165MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 08/02/23 18:40 V36165MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/02/23 18:40 V36165MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 08/02/23 18:40 V36165MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/02/23 18:40 V36165MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/02/23 18:40 V36165MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/02/23 18:40 V36165MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/02/23 18:40 V36165MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 08/02/23 18:40 V36165MSA
<0.220 µg/L 0.220 0.500Chloroform 1 08/02/23 18:40 V36165MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 08/02/23 18:40 V36165MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/02/23 18:40 V36165MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/02/23 18:40 V36165MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/02/23 18:40 V36165MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/02/23 18:40 V36165MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 08/02/23 18:40 V36165MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/02/23 18:40 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 54 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-19
91156 Matrix:
7/31/2023 13:11
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/02/23 18:40 V36165MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/02/23 18:40 V36165MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/02/23 18:40 V36165MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/02/23 18:40 V36165MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/02/23 18:40 V36165MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/02/23 18:40 V36165MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/02/23 18:40 V36165MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/02/23 18:40 V36165MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/02/23 18:40 V36165MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 08/02/23 18:40 V36165MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/02/23 18:40 V36165MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/02/23 18:40 V36165MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/02/23 18:40 V36165MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/02/23 18:40 V36165MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/02/23 18:40 V36165MSA
<42.0 µg/L 42.0 200Ethanol 1 08/02/23 18:40 V36165MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 08/02/23 18:40 V36165MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/02/23 18:40 V36165MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 08/02/23 18:40 V36165MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 08/02/23 18:40 V36165MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/02/23 18:40 V36165MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/02/23 18:40 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 55 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-19
91156 Matrix:
7/31/2023 13:11
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/02/23 18:40 V36165MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/02/23 18:40 V36165MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/02/23 18:40 V36165MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 08/02/23 18:40 V36165MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 08/02/23 18:40 V36165MSA
<0.220 µg/L 0.220 0.500Styrene 1 08/02/23 18:40 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/02/23 18:40 V36165MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/02/23 18:40 V36165MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/02/23 18:40 V36165MSA
<0.220 µg/L 0.220 0.500Toluene 1 08/02/23 18:40 V36165MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/02/23 18:40 V36165MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/02/23 18:40 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/02/23 18:40 V36165MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/02/23 18:40 V36165MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/02/23 18:40 V36165MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/02/23 18:40 V36165MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/02/23 18:40 V36165MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/02/23 18:40 V36165MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/02/23 18:40 V36165MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/02/23 18:40 V36165MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/02/23 18:40 V36165MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 08/02/23 18:40 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 56 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-19
91156 Matrix:
7/31/2023 13:11
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 08/02/23 18:40 V36165MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 08/02/23 18:40 V36165
Surrogate: 4-Bromofluorobenzene 90.6 Limits: 70-130%08/02/23 18:401 MSA V36165
Surrogate: Dibromofluoromethane 99.0 Limits: 70-130%08/02/23 18:401 MSA V36165
Surrogate: 1,2-Dichloroethane - d4 92.8 Limits: 70-130%08/02/23 18:401 MSA V36165
Surrogate: Toluene-d8 112 Limits: 70-130%08/02/23 18:401 MSA V36165
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 57 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-21
91157 Matrix:
7/31/2023 13:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 08/02/23 19:04 V36165MSA
<0.180 µg/L 0.180 0.500Benzene 1 08/02/23 19:04 V36165MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/02/23 19:04 V36165MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/02/23 19:04 V36165MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/02/23 19:04 V36165MSA
<1.50 µg/L 1.50 5.00Bromoform 1 08/02/23 19:04 V36165MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 08/02/23 19:04 V36165MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/02/23 19:04 V36165MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 08/02/23 19:04 V36165MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/02/23 19:04 V36165MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/02/23 19:04 V36165MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/02/23 19:04 V36165MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/02/23 19:04 V36165MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 08/02/23 19:04 V36165MSA
<0.220 µg/L 0.220 0.500Chloroform 1 08/02/23 19:04 V36165MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 08/02/23 19:04 V36165MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/02/23 19:04 V36165MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/02/23 19:04 V36165MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/02/23 19:04 V36165MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/02/23 19:04 V36165MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 08/02/23 19:04 V36165MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/02/23 19:04 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 58 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-21
91157 Matrix:
7/31/2023 13:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/02/23 19:04 V36165MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/02/23 19:04 V36165MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/02/23 19:04 V36165MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/02/23 19:04 V36165MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/02/23 19:04 V36165MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/02/23 19:04 V36165MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/02/23 19:04 V36165MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/02/23 19:04 V36165MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/02/23 19:04 V36165MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 08/02/23 19:04 V36165MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/02/23 19:04 V36165MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/02/23 19:04 V36165MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/02/23 19:04 V36165MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/02/23 19:04 V36165MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/02/23 19:04 V36165MSA
<42.0 µg/L 42.0 200Ethanol 1 08/02/23 19:04 V36165MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 08/02/23 19:04 V36165MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/02/23 19:04 V36165MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 08/02/23 19:04 V36165MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 08/02/23 19:04 V36165MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/02/23 19:04 V36165MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/02/23 19:04 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 59 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-21
91157 Matrix:
7/31/2023 13:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/02/23 19:04 V36165MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/02/23 19:04 V36165MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/02/23 19:04 V36165MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 08/02/23 19:04 V36165MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 08/02/23 19:04 V36165MSA
<0.220 µg/L 0.220 0.500Styrene 1 08/02/23 19:04 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/02/23 19:04 V36165MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/02/23 19:04 V36165MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/02/23 19:04 V36165MSA
<0.220 µg/L 0.220 0.500Toluene 1 08/02/23 19:04 V36165MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/02/23 19:04 V36165MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/02/23 19:04 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/02/23 19:04 V36165MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/02/23 19:04 V36165MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/02/23 19:04 V36165MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/02/23 19:04 V36165MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/02/23 19:04 V36165MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/02/23 19:04 V36165MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/02/23 19:04 V36165MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/02/23 19:04 V36165MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/02/23 19:04 V36165MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 08/02/23 19:04 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 60 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-21
91157 Matrix:
7/31/2023 13:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 08/02/23 19:04 V36165MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 08/02/23 19:04 V36165
Surrogate: 4-Bromofluorobenzene 93.0 Limits: 70-130%08/02/23 19:041 MSA V36165
Surrogate: Dibromofluoromethane 99.6 Limits: 70-130%08/02/23 19:041 MSA V36165
Surrogate: 1,2-Dichloroethane - d4 98.0 Limits: 70-130%08/02/23 19:041 MSA V36165
Surrogate: Toluene-d8 111 Limits: 70-130%08/02/23 19:041 MSA V36165
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 61 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-24
91158 Matrix:
7/31/2023 13:38
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00 V36274 08/03/23 09:00
8.87 J µg/L 1.80 10.0Acetone 1 08/02/23 19:29 V36165MSA
<0.180 µg/L 0.180 0.500Benzene 1 08/02/23 19:29 V36165MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/02/23 19:29 V36165MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/02/23 19:29 V36165MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/02/23 19:29 V36165MSA
<1.50 µg/L 1.50 5.00Bromoform 1 08/02/23 19:29 V36165MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 08/02/23 19:29 V36165MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/02/23 19:29 V36165MSA
0.271 J µg/L 0.200 0.500sec-Butyl benzene 1 08/02/23 19:29 V36165MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/02/23 19:29 V36165MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/02/23 19:29 V36165MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/02/23 19:29 V36165MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/02/23 19:29 V36165MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 08/02/23 19:29 V36165MSA
<0.220 µg/L 0.220 0.500Chloroform 1 08/02/23 19:29 V36165MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 08/02/23 19:29 V36165MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/02/23 19:29 V36165MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/02/23 19:29 V36165MSA
2.22 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/02/23 19:29 V36165MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/02/23 19:29 V36165MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 08/02/23 19:29 V36165MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/02/23 19:29 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 62 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-24
91158 Matrix:
7/31/2023 13:38
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00 V36274 08/03/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/02/23 19:29 V36165MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/02/23 19:29 V36165MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/02/23 19:29 V36165MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/02/23 19:29 V36165MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/02/23 19:29 V36165MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/02/23 19:29 V36165MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/02/23 19:29 V36165MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/02/23 19:29 V36165MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/02/23 19:29 V36165MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 08/02/23 19:29 V36165MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/02/23 19:29 V36165MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/02/23 19:29 V36165MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/02/23 19:29 V36165MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/02/23 19:29 V36165MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/02/23 19:29 V36165MSA
<42.0 µg/L 42.0 200Ethanol 1 08/02/23 19:29 V36165MSA
0.549 µg/L 0.170 0.500Ethylbenzene 1 08/02/23 19:29 V36165MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/02/23 19:29 V36165MSA
0.858 J µg/L 0.380 1.002-Hexanone 1 08/02/23 19:29 V36165MSA
2.81 µg/L 0.180 0.500Isopropylbenzene 1 08/02/23 19:29 V36165MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/02/23 19:29 V36165MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/02/23 19:29 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 63 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-24
91158 Matrix:
7/31/2023 13:38
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00 V36274 08/03/23 09:00
220 µg/L 1.40 10.0Methyl tert-butyl ether (MTBE)10 08/03/23 18:49 V36275MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/02/23 19:29 V36165MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/02/23 19:29 V36165MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 08/02/23 19:29 V36165MSA
0.500 µg/L 0.190 0.500n-Propylbenzene 1 08/02/23 19:29 V36165MSA
<0.220 µg/L 0.220 0.500Styrene 1 08/02/23 19:29 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/02/23 19:29 V36165MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/02/23 19:29 V36165MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/02/23 19:29 V36165MSA
0.266 J µg/L 0.220 0.500Toluene 1 08/02/23 19:29 V36165MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/02/23 19:29 V36165MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/02/23 19:29 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/02/23 19:29 V36165MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/02/23 19:29 V36165MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/02/23 19:29 V36165MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/02/23 19:29 V36165MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/02/23 19:29 V36165MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/02/23 19:29 V36165MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/02/23 19:29 V36165MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/02/23 19:29 V36165MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/02/23 19:29 V36165MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 08/02/23 19:29 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 64 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-24
91158 Matrix:
7/31/2023 13:38
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00 V36274 08/03/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 08/02/23 19:29 V36165MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 08/02/23 19:29 V36165
Surrogate: 4-Bromofluorobenzene 96.0 Limits: 70-130%08/02/23 19:291 MSA V36165
Surrogate: Dibromofluoromethane 98.2 Limits: 70-130%08/02/23 19:291 MSA V36165
Surrogate: 1,2-Dichloroethane - d4 92.8 Limits: 70-130%08/02/23 19:291 MSA V36165
Surrogate: Toluene-d8 113 Limits: 70-130%08/02/23 19:291 MSA V36165
Surrogate: 4-Bromofluorobenzene 84.2 Limits: 70-130%08/03/23 18:4910 MSA V36275
Surrogate: Dibromofluoromethane 98.2 Limits: 70-130%08/03/23 18:4910 MSA V36275
Surrogate: 1,2-Dichloroethane - d4 95.0 Limits: 70-130%08/03/23 18:4910 MSA V36275
Surrogate: Toluene-d8 112 Limits: 70-130%08/03/23 18:4910 MSA V36275
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 65 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-22
91159 Matrix:
7/31/2023 13:51
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 08/02/23 19:54 V36165MSA
<0.180 µg/L 0.180 0.500Benzene 1 08/02/23 19:54 V36165MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/02/23 19:54 V36165MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/02/23 19:54 V36165MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/02/23 19:54 V36165MSA
<1.50 µg/L 1.50 5.00Bromoform 1 08/02/23 19:54 V36165MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 08/02/23 19:54 V36165MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/02/23 19:54 V36165MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 08/02/23 19:54 V36165MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/02/23 19:54 V36165MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/02/23 19:54 V36165MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/02/23 19:54 V36165MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/02/23 19:54 V36165MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 08/02/23 19:54 V36165MSA
<0.220 µg/L 0.220 0.500Chloroform 1 08/02/23 19:54 V36165MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 08/02/23 19:54 V36165MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/02/23 19:54 V36165MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/02/23 19:54 V36165MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/02/23 19:54 V36165MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/02/23 19:54 V36165MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 08/02/23 19:54 V36165MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/02/23 19:54 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 66 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-22
91159 Matrix:
7/31/2023 13:51
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/02/23 19:54 V36165MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/02/23 19:54 V36165MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/02/23 19:54 V36165MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/02/23 19:54 V36165MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/02/23 19:54 V36165MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/02/23 19:54 V36165MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/02/23 19:54 V36165MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/02/23 19:54 V36165MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/02/23 19:54 V36165MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 08/02/23 19:54 V36165MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/02/23 19:54 V36165MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/02/23 19:54 V36165MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/02/23 19:54 V36165MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/02/23 19:54 V36165MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/02/23 19:54 V36165MSA
<42.0 µg/L 42.0 200Ethanol 1 08/02/23 19:54 V36165MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 08/02/23 19:54 V36165MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/02/23 19:54 V36165MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 08/02/23 19:54 V36165MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 08/02/23 19:54 V36165MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/02/23 19:54 V36165MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/02/23 19:54 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 67 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-22
91159 Matrix:
7/31/2023 13:51
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/02/23 19:54 V36165MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/02/23 19:54 V36165MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/02/23 19:54 V36165MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 08/02/23 19:54 V36165MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 08/02/23 19:54 V36165MSA
<0.220 µg/L 0.220 0.500Styrene 1 08/02/23 19:54 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/02/23 19:54 V36165MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/02/23 19:54 V36165MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/02/23 19:54 V36165MSA
<0.220 µg/L 0.220 0.500Toluene 1 08/02/23 19:54 V36165MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/02/23 19:54 V36165MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/02/23 19:54 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/02/23 19:54 V36165MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/02/23 19:54 V36165MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/02/23 19:54 V36165MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/02/23 19:54 V36165MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/02/23 19:54 V36165MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/02/23 19:54 V36165MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/02/23 19:54 V36165MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/02/23 19:54 V36165MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/02/23 19:54 V36165MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 08/02/23 19:54 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 68 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-22
91159 Matrix:
7/31/2023 13:51
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 08/02/23 19:54 V36165MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 08/02/23 19:54 V36165
Surrogate: 4-Bromofluorobenzene 91.8 Limits: 70-130%08/02/23 19:541 MSA V36165
Surrogate: Dibromofluoromethane 101 Limits: 70-130%08/02/23 19:541 MSA V36165
Surrogate: 1,2-Dichloroethane - d4 97.4 Limits: 70-130%08/02/23 19:541 MSA V36165
Surrogate: Toluene-d8 110 Limits: 70-130%08/02/23 19:541 MSA V36165
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 69 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-23
91160 Matrix:
7/31/2023 14:04
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 08/02/23 20:19 V36165MSA
<0.180 µg/L 0.180 0.500Benzene 1 08/02/23 20:19 V36165MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/02/23 20:19 V36165MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/02/23 20:19 V36165MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/02/23 20:19 V36165MSA
<1.50 µg/L 1.50 5.00Bromoform 1 08/02/23 20:19 V36165MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 08/02/23 20:19 V36165MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/02/23 20:19 V36165MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 08/02/23 20:19 V36165MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/02/23 20:19 V36165MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/02/23 20:19 V36165MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/02/23 20:19 V36165MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/02/23 20:19 V36165MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 08/02/23 20:19 V36165MSA
<0.220 µg/L 0.220 0.500Chloroform 1 08/02/23 20:19 V36165MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 08/02/23 20:19 V36165MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/02/23 20:19 V36165MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/02/23 20:19 V36165MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/02/23 20:19 V36165MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/02/23 20:19 V36165MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 08/02/23 20:19 V36165MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/02/23 20:19 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 70 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-23
91160 Matrix:
7/31/2023 14:04
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/02/23 20:19 V36165MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/02/23 20:19 V36165MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/02/23 20:19 V36165MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/02/23 20:19 V36165MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/02/23 20:19 V36165MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/02/23 20:19 V36165MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/02/23 20:19 V36165MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/02/23 20:19 V36165MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/02/23 20:19 V36165MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 08/02/23 20:19 V36165MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/02/23 20:19 V36165MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/02/23 20:19 V36165MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/02/23 20:19 V36165MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/02/23 20:19 V36165MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/02/23 20:19 V36165MSA
<42.0 µg/L 42.0 200Ethanol 1 08/02/23 20:19 V36165MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 08/02/23 20:19 V36165MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/02/23 20:19 V36165MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 08/02/23 20:19 V36165MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 08/02/23 20:19 V36165MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/02/23 20:19 V36165MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/02/23 20:19 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 71 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-23
91160 Matrix:
7/31/2023 14:04
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/02/23 20:19 V36165MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/02/23 20:19 V36165MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/02/23 20:19 V36165MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 08/02/23 20:19 V36165MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 08/02/23 20:19 V36165MSA
<0.220 µg/L 0.220 0.500Styrene 1 08/02/23 20:19 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/02/23 20:19 V36165MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/02/23 20:19 V36165MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/02/23 20:19 V36165MSA
<0.220 µg/L 0.220 0.500Toluene 1 08/02/23 20:19 V36165MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/02/23 20:19 V36165MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/02/23 20:19 V36165MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/02/23 20:19 V36165MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/02/23 20:19 V36165MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/02/23 20:19 V36165MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/02/23 20:19 V36165MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/02/23 20:19 V36165MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/02/23 20:19 V36165MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/02/23 20:19 V36165MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/02/23 20:19 V36165MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/02/23 20:19 V36165MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 08/02/23 20:19 V36165MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 72 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-23
91160 Matrix:
7/31/2023 14:04
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36164 08/02/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 08/02/23 20:19 V36165MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 08/02/23 20:19 V36165
Surrogate: 4-Bromofluorobenzene 93.0 Limits: 70-130%08/02/23 20:191 MSA V36165
Surrogate: Dibromofluoromethane 100 Limits: 70-130%08/02/23 20:191 MSA V36165
Surrogate: 1,2-Dichloroethane - d4 94.2 Limits: 70-130%08/02/23 20:191 MSA V36165
Surrogate: Toluene-d8 113 Limits: 70-130%08/02/23 20:191 MSA V36165
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 73 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-25
91161 Matrix:
7/31/2023 14:20
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36179 08/02/23 14:00 V36349 08/03/23 09:00
<18.0 µg/L 18.0 100Acetone 10 08/03/23 09:59 V36181MSA
15.4 µg/L 1.80 5.00Benzene 10 08/03/23 09:59 V36181MSA
<2.10 µg/L 2.10 5.00Bromobenzene 10 08/03/23 09:59 V36181MSA
<4.20 µg/L 4.20 10.0Bromochloromethane 10 08/03/23 09:59 V36181MSA
<1.60 µg/L 1.60 5.00Bromodichloromethane 10 08/03/23 09:59 V36181MSA
<15.0 µg/L 15.0 50.0Bromoform 10 08/03/23 09:59 V36181MSA
<2.80 µg/L 2.80 10.0Bromomethane 10 08/03/23 09:59 V36181MSA
<1.80 µg/L 1.80 5.00n-Butylbenzene 10 08/03/23 09:59 V36181MSA
<2.00 µg/L 2.00 5.00sec-Butyl benzene 10 08/03/23 09:59 V36181MSA
<9.20 µg/L 9.20 20.0tert-Butyl benzene 10 08/03/23 09:59 V36181MSA
<1.80 µg/L 1.80 5.00Carbon Tetrachloride 10 08/03/23 09:59 V36181MSA
<1.90 µg/L 1.90 5.00Chlorobenzene 10 08/03/23 09:59 V36181MSA
<1.90 µg/L 1.90 5.00Chlorodibromomethane 10 08/03/23 09:59 V36181MSA
<4.30 µg/L 4.30 10.0Chloroethane 10 08/03/23 09:59 V36181MSA
<2.20 µg/L 2.20 5.00Chloroform 10 08/03/23 09:59 V36181MSA
<2.20 µg/L 2.20 5.00Chloromethane 10 08/03/23 09:59 V36181MSA
<2.00 µg/L 2.00 5.002-Chlorotoluene 10 08/03/23 09:59 V36181MSA
<2.00 µg/L 2.00 5.004-Chlorotoluene 10 08/03/23 09:59 V36181MSA
6.74 µg/L 5.00 5.00Di-Isopropyl Ether (DIPE)10 08/03/23 09:59 V36181MSA
<11.0 µg/L 11.0 20.01,2-Dibromo-3-Chloropropane 10 08/03/23 09:59 V36181MSA
<2.00 µg/L 2.00 5.001,2-Dibromoethane 10 08/03/23 09:59 V36181MSA
<2.30 µg/L 2.30 5.00Dibromomethane 10 08/03/23 09:59 V36181MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 74 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-25
91161 Matrix:
7/31/2023 14:20
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36179 08/02/23 14:00 V36349 08/03/23 09:00
<2.20 µg/L 2.20 5.001,2-Dichlorobenzene 10 08/03/23 09:59 V36181MSA
<1.90 µg/L 1.90 5.001,3-Dichlorobenzene 10 08/03/23 09:59 V36181MSA
<2.10 µg/L 2.10 5.001,4-Dichlorobenzene 10 08/03/23 09:59 V36181MSA
<12.0 µg/L 12.0 50.0Dichlorodifluoromethane 10 08/03/23 09:59 V36181MSA
<2.40 µg/L 2.40 5.001,1-Dichloroethane 10 08/03/23 09:59 V36181MSA
<1.50 µg/L 1.50 5.001,2-Dichloroethane 10 08/03/23 09:59 V36181MSA
<1.50 µg/L 1.50 5.001,1-Dichloroethene 10 08/03/23 09:59 V36181MSA
<2.00 µg/L 2.00 5.00cis-1,2-Dichloroethene 10 08/03/23 09:59 V36181MSA
<1.80 µg/L 1.80 5.00trans-1,2-Dichloroethene 10 08/03/23 09:59 V36181MSA
<1.90 µg/L 1.90 5.001,2-Dichloropropane 10 08/03/23 09:59 V36181MSA
<1.30 µg/L 1.30 5.001,3-Dichloropropane 10 08/03/23 09:59 V36181MSA
<2.10 M µg/L 2.10 20.02,2-Dichloropropane 10 08/03/23 09:59 V36181MSA
<2.00 µg/L 2.00 5.001,1-Dichloropropene 10 08/03/23 09:59 V36181MSA
<2.10 µg/L 2.10 5.00cis-1,3-Dichloropropene 10 08/03/23 09:59 V36181MSA
<1.50 µg/L 1.50 5.00trans-1,3-Dichloropropene 10 08/03/23 09:59 V36181MSA
<420 µg/L 420 2000Ethanol 10 08/03/23 09:59 V36181MSA
<1.70 µg/L 1.70 5.00Ethylbenzene 10 08/03/23 09:59 V36181MSA
<3.50 µg/L 3.50 30.0Hexachlorobutadiene 10 08/03/23 09:59 V36181MSA
<3.80 µg/L 3.80 10.02-Hexanone 10 08/03/23 09:59 V36181MSA
<1.80 µg/L 1.80 5.00Isopropylbenzene 10 08/03/23 09:59 V36181MSA
<0.890 µg/L 0.890 5.004-Isopropyl toluene 10 08/03/23 09:59 V36181MSA
<7.10 µg/L 7.10 50.0Methyl Ethyl Ketone (MEK)10 08/03/23 09:59 V36181MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 75 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-25
91161 Matrix:
7/31/2023 14:20
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36179 08/02/23 14:00 V36349 08/03/23 09:00
4440 µg/L 14.0 100Methyl tert-butyl ether (MTBE)100 08/03/23 21:18 V36350MSA
<0.780 µg/L 0.780 10.04-Methyl-2-Pentanone 10 08/03/23 09:59 V36181MSA
<3.30 µg/L 3.30 20.0Methylene Chloride 10 08/03/23 09:59 V36181MSA
<4.70 µg/L 4.70 10.0Naphthalene 10 08/03/23 09:59 V36181MSA
<1.90 µg/L 1.90 5.00n-Propylbenzene 10 08/03/23 09:59 V36181MSA
<2.20 µg/L 2.20 5.00Styrene 10 08/03/23 09:59 V36181MSA
<1.60 µg/L 1.60 5.001,1,1,2-Tetrachloroethane 10 08/03/23 09:59 V36181MSA
<1.60 µg/L 1.60 5.001,1,2,2-Tetrachloroethane 10 08/03/23 09:59 V36181MSA
<2.20 µg/L 2.20 5.00Tetrachloroethene 10 08/03/23 09:59 V36181MSA
<2.20 µg/L 2.20 5.00Toluene 10 08/03/23 09:59 V36181MSA
<3.80 µg/L 3.80 5.001,2,3-Trichlorobenzene 10 08/03/23 09:59 V36181MSA
<3.10 µg/L 3.10 5.001,2,4-Trichlorobenzene 10 08/03/23 09:59 V36181MSA
<1.60 µg/L 1.60 5.001,1,1-Trichloroethane 10 08/03/23 09:59 V36181MSA
<0.960 µg/L 0.960 5.001,1,2-Trichloroethane 10 08/03/23 09:59 V36181MSA
<1.80 µg/L 1.80 5.00Trichloroethene 10 08/03/23 09:59 V36181MSA
<1.80 µg/L 1.80 5.00Trichlorofluoromethane 10 08/03/23 09:59 V36181MSA
<2.70 µg/L 2.70 5.001,2,3-Trichloropropane 10 08/03/23 09:59 V36181MSA
<1.90 µg/L 1.90 5.001,2,4-Trimethylbenzene 10 08/03/23 09:59 V36181MSA
<1.80 µg/L 1.80 5.001,3,5-Trimethylbenzene 10 08/03/23 09:59 V36181MSA
<10.0 µg/L 10.0 50.0Vinyl Acetate 10 08/03/23 09:59 V36181MSA
<1.70 µg/L 1.70 5.00Vinyl Chloride 10 08/03/23 09:59 V36181MSA
<2.10 µg/L 2.10 5.00o-Xylene 10 08/03/23 09:59 V36181MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 76 of 94
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-213-0004
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #2081 Received : 08/01/2023
DW Tatum
Report Date : 08/08/2023
Sample ID :
Lab No :
Sampled:MW-25
91161 Matrix:
7/31/2023 14:20
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V36179 08/02/23 14:00 V36349 08/03/23 09:00
<4.20 µg/L 4.20 10.0m,p-Xylene 10 08/03/23 09:59 V36181MSA
<2.1 µg/L 2.10 5.00Xylene (Total)10 08/03/23 09:59 V36181
Surrogate: 4-Bromofluorobenzene 93.6 Limits: 70-130%08/03/23 09:5910 MSA V36181
Surrogate: Dibromofluoromethane 98.8 Limits: 70-130%08/03/23 09:5910 MSA V36181
Surrogate: 1,2-Dichloroethane - d4 92.2 Limits: 70-130%08/03/23 09:5910 MSA V36181
Surrogate: Toluene-d8 111 Limits: 70-130%08/03/23 09:5910 MSA V36181
Surrogate: 4-Bromofluorobenzene 96.0 Limits: 70-130%08/03/23 21:18100 MSA V36350
Surrogate: Dibromofluoromethane 97.6 Limits: 70-130%08/03/23 21:18100 MSA V36350
Surrogate: 1,2-Dichloroethane - d4 92.6 Limits: 70-130%08/03/23 21:18100 MSA V36350
Surrogate: Toluene-d8 112 Limits: 70-130%08/03/23 21:18100 MSA V36350
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 77 of 94
Quality Control Data
23-213-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
DW Tatum
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V36165QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V36164
Associated Lab Samples: 91144, 91145, 91146, 91147, 91148, 91149, 91150, 91151, 91152, 91153, 91154, 91155, 91156, 91157, 91158,
91159, 91160
LRB-V36164 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/02/23 13:4310.01.80<1.80µg/LAcetone
08/02/23 13:430.5000.180<0.180µg/LBenzene
08/02/23 13:430.5000.210<0.210µg/LBromobenzene
08/02/23 13:431.000.420<0.420µg/LBromochloromethane
08/02/23 13:430.5000.160<0.160µg/LBromodichloromethane
08/02/23 13:435.001.50<1.50µg/LBromoform
08/02/23 13:431.000.280<0.280µg/LBromomethane
08/02/23 13:430.5000.180<0.180µg/Ln-Butylbenzene
08/02/23 13:430.5000.200<0.200µg/Lsec-Butyl benzene
08/02/23 13:432.000.920<0.920µg/Ltert-Butyl benzene
08/02/23 13:430.5000.180<0.180µg/LCarbon Tetrachloride
08/02/23 13:430.5000.190<0.190µg/LChlorobenzene
08/02/23 13:430.5000.190<0.190µg/LChlorodibromomethane
08/02/23 13:431.000.430<0.430µg/LChloroethane
08/02/23 13:430.5000.220<0.220µg/LChloroform
08/02/23 13:430.5000.220<0.220µg/LChloromethane
08/02/23 13:430.5000.200<0.200µg/L2-Chlorotoluene
08/02/23 13:430.5000.200<0.200µg/L4-Chlorotoluene
08/02/23 13:430.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
08/02/23 13:432.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
08/02/23 13:430.5000.200<0.200µg/L1,2-Dibromoethane
08/02/23 13:430.5000.230<0.230µg/LDibromomethane
08/02/23 13:430.5000.220<0.220µg/L1,2-Dichlorobenzene
08/02/23 13:430.5000.190<0.190µg/L1,3-Dichlorobenzene
08/02/23 13:430.5000.210<0.210µg/L1,4-Dichlorobenzene
08/02/23 13:435.001.20<1.20µg/LDichlorodifluoromethane
08/02/23 13:430.5000.240<0.240µg/L1,1-Dichloroethane
Page 1 of 14Date:08/08/2023 05:29 PM
Page 78 of 94
Quality Control Data
23-213-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
DW Tatum
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V36165QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V36164
Associated Lab Samples: 91144, 91145, 91146, 91147, 91148, 91149, 91150, 91151, 91152, 91153, 91154, 91155, 91156, 91157, 91158,
91159, 91160
LRB-V36164 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/02/23 13:430.5000.150<0.150µg/L1,2-Dichloroethane
08/02/23 13:430.5000.150<0.150µg/L1,1-Dichloroethene
08/02/23 13:430.5000.200<0.200µg/Lcis-1,2-Dichloroethene
08/02/23 13:430.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
08/02/23 13:430.5000.190<0.190µg/L1,2-Dichloropropane
08/02/23 13:430.5000.130<0.130µg/L1,3-Dichloropropane
08/02/23 13:432.000.210<0.210µg/L2,2-Dichloropropane
08/02/23 13:430.5000.200<0.200µg/L1,1-Dichloropropene
08/02/23 13:430.5000.210<0.210µg/Lcis-1,3-Dichloropropene
08/02/23 13:430.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
08/02/23 13:4320042.0<42.0µg/LEthanol
08/02/23 13:430.5000.170<0.170µg/LEthylbenzene
08/02/23 13:433.000.350<0.350µg/LHexachlorobutadiene
08/02/23 13:431.000.380<0.380µg/L2-Hexanone
08/02/23 13:430.5000.180<0.180µg/LIsopropylbenzene
08/02/23 13:430.5000.089<0.089µg/L4-Isopropyl toluene
08/02/23 13:435.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
08/02/23 13:431.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
08/02/23 13:431.000.078<0.078µg/L4-Methyl-2-Pentanone
08/02/23 13:432.000.330<0.330µg/LMethylene Chloride
08/02/23 13:431.000.470<0.470µg/LNaphthalene
08/02/23 13:430.5000.190<0.190µg/Ln-Propylbenzene
08/02/23 13:430.5000.220<0.220µg/LStyrene
08/02/23 13:430.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
08/02/23 13:430.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
08/02/23 13:430.5000.220<0.220µg/LTetrachloroethene
08/02/23 13:430.5000.220<0.220µg/LToluene
Page 2 of 14Date:08/08/2023 05:29 PM
Page 79 of 94
Quality Control Data
23-213-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
DW Tatum
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V36165QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V36164
Associated Lab Samples: 91144, 91145, 91146, 91147, 91148, 91149, 91150, 91151, 91152, 91153, 91154, 91155, 91156, 91157, 91158,
91159, 91160
LRB-V36164 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/02/23 13:430.5000.380<0.380µg/L1,2,3-Trichlorobenzene
08/02/23 13:430.5000.310<0.310µg/L1,2,4-Trichlorobenzene
08/02/23 13:430.5000.160<0.160µg/L1,1,1-Trichloroethane
08/02/23 13:430.5000.096<0.096µg/L1,1,2-Trichloroethane
08/02/23 13:430.5000.180<0.180µg/LTrichloroethene
08/02/23 13:430.5000.180<0.180µg/LTrichlorofluoromethane
08/02/23 13:430.5000.270<0.270µg/L1,2,3-Trichloropropane
08/02/23 13:430.5000.190<0.190µg/L1,2,4-Trimethylbenzene
08/02/23 13:430.5000.180<0.180µg/L1,3,5-Trimethylbenzene
08/02/23 13:435.001.00<1.00µg/LVinyl Acetate
08/02/23 13:430.5000.170<0.170µg/LVinyl Chloride
08/02/23 13:430.5000.210<0.210µg/Lo-Xylene
08/02/23 13:431.000.420<0.420µg/Lm,p-Xylene
08/02/23 13:434-Bromofluorobenzene (S)98.8 70-130
08/02/23 13:43Dibromofluoromethane (S)97.2 70-130
08/02/23 13:431,2-Dichloroethane - d4 (S)91.6 70-130
08/02/23 13:43Toluene-d8 (S)113 70-130
LCS-V36164 LCSD-V36164Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
24.8 62.063.225.340.0µg/LAcetone 40-160 1.9 20.0
17.0 85.085.517.120.0µg/LBenzene 70-130 0.5 20.0
19.9 99.510220.320.0µg/LBromobenzene 70-130 1.9 20.0
18.3 91.589.017.820.0µg/LBromochloromethane 70-130 2.7 20.0
16.4 82.081.516.320.0µg/LBromodichloromethane 70-130 0.6 20.0
Page 3 of 14Date:08/08/2023 05:29 PM
Page 80 of 94
Quality Control Data
23-213-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
DW Tatum
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V36165QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V36164
LCS-V36164 LCSD-V36164Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.8 10910921.720.0µg/LBromoform 70-130 0.4 20.0
15.3 76.577.015.420.0µg/LBromomethane 60-140 0.6 20.0
20.3 10210220.420.0µg/Ln-Butylbenzene 70-130 0.4 20.0
21.0 10510621.120.0µg/Lsec-Butyl benzene 70-130 0.4 20.0
21.6 10810721.320.0µg/Ltert-Butyl benzene 70-130 1.3 20.0
17.6 88.088.517.720.0µg/LCarbon Tetrachloride 70-130 0.5 20.0
20.8 10410420.820.0µg/LChlorobenzene 70-130 0.0 20.0
21.3 10710821.620.0µg/LChlorodibromomethane 70-130 1.3 20.0
18.1 90.594.018.820.0µg/LChloroethane 60-140 3.7 20.0
16.5 82.583.016.620.0µg/LChloroform 70-130 0.6 20.0
15.8 79.079.515.920.0µg/LChloromethane 60-140 0.6 20.0
20.1 10110220.320.0µg/L2-Chlorotoluene 70-130 0.9 20.0
20.6 10310320.620.0µg/L4-Chlorotoluene 70-130 0.0 20.0
14.2 71.071.014.220.0µg/LDi-Isopropyl Ether (DIPE)70-130 0.0 20.0
22.9 11510821.620.0µg/L1,2-Dibromo-3-Chloropropane 70-130 5.8 20.0
20.5 10310220.320.0µg/L1,2-Dibromoethane 70-130 0.9 20.0
15.9 79.583.016.620.0µg/LDibromomethane 70-130 4.3 20.0
21.4 10710821.520.0µg/L1,2-Dichlorobenzene 70-130 0.4 20.0
21.7 10910821.520.0µg/L1,3-Dichlorobenzene 70-130 0.9 20.0
21.0 10510521.020.0µg/L1,4-Dichlorobenzene 70-130 0.0 20.0
15.9 79.578.515.720.0µg/LDichlorodifluoromethane 60-140 1.2 20.0
17.2 86.084.516.920.0µg/L1,1-Dichloroethane 70-130 1.7 20.0
15.6 78.076.515.320.0µg/L1,2-Dichloroethane 70-130 1.9 20.0
16.7 83.585.517.120.0µg/L1,1-Dichloroethene 70-130 2.3 20.0
16.7 83.581.016.220.0µg/Lcis-1,2-Dichloroethene 70-130 3.0 20.0
17.1 85.586.517.320.0µg/Ltrans-1,2-Dichloroethene 70-130 1.1 20.0
Page 4 of 14Date:08/08/2023 05:29 PM
Page 81 of 94
Quality Control Data
23-213-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
DW Tatum
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V36165QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V36164
LCS-V36164 LCSD-V36164Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
16.9 84.584.516.920.0µg/L1,2-Dichloropropane 70-130 0.0 20.0
19.9 99.599.519.920.0µg/L1,3-Dichloropropane 70-130 0.0 20.0
16.6 83.087.517.520.0µg/L2,2-Dichloropropane 70-130 5.2 20.0
18.1 90.590.018.020.0µg/L1,1-Dichloropropene 70-130 0.5 20.0
17.1 85.586.517.320.0µg/Lcis-1,3-Dichloropropene 70-130 1.1 20.0
16.8 84.085.517.120.0µg/Ltrans-1,3-Dichloropropene 70-130 1.7 20.0
436 87.283.8419500µg/LEthanol 60-140 3.9 20.0
19.7 98.598.519.720.0µg/LEthylbenzene 70-130 0.0 20.0
23.8 11911923.720.0µg/LHexachlorobutadiene 70-130 0.4 20.0
15.2 76.076.515.320.0µg/L2-Hexanone 60-140 0.6 20.0
21.9 11011022.020.0µg/LIsopropylbenzene 70-130 0.4 20.0
22.2 11111122.120.0µg/L4-Isopropyl toluene 70-130 0.4 20.0
16.2 81.081.516.320.0µg/LMethyl Ethyl Ketone (MEK)60-140 0.6 20.0
16.7 83.585.517.120.0µg/LMethyl tert-butyl ether (MTBE)70-130 2.3 20.0
13.5 67.570.514.120.0µg/L4-Methyl-2-Pentanone 60-140 4.3 20.0
15.1 75.577.015.420.0µg/LMethylene Chloride 70-130 1.9 20.0
20.4 10210120.120.0µg/LNaphthalene 70-130 1.4 20.0
20.5 10310220.320.0µg/Ln-Propylbenzene 70-130 0.9 20.0
21.1 10610721.320.0µg/LStyrene 70-130 0.9 20.0
21.6 10810721.420.0µg/L1,1,1,2-Tetrachloroethane 70-130 0.9 20.0
19.5 97.599.019.820.0µg/L1,1,2,2-Tetrachloroethane 70-130 1.5 20.0
23.0 11511222.320.0µg/LTetrachloroethene 70-130 3.0 20.0
17.1 85.585.017.020.0µg/LToluene 70-130 0.5 20.0
23.3 11711222.420.0µg/L1,2,3-Trichlorobenzene 70-130 3.9 20.0
23.2 11611723.320.0µg/L1,2,4-Trichlorobenzene 70-130 0.4 20.0
16.7 83.584.516.920.0µg/L1,1,1-Trichloroethane 70-130 1.1 20.0
Page 5 of 14Date:08/08/2023 05:29 PM
Page 82 of 94
Quality Control Data
23-213-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
DW Tatum
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V36165QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V36164
LCS-V36164 LCSD-V36164Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
17.7 88.588.017.620.0µg/L1,1,2-Trichloroethane 70-130 0.5 20.0
18.2 91.089.017.820.0µg/LTrichloroethene 70-130 2.2 20.0
17.5 87.589.017.820.0µg/LTrichlorofluoromethane 60-140 1.6 20.0
19.1 95.595.019.020.0µg/L1,2,3-Trichloropropane 70-130 0.5 20.0
21.4 10710921.720.0µg/L1,2,4-Trimethylbenzene 70-130 1.3 20.0
21.9 11011022.020.0µg/L1,3,5-Trimethylbenzene 70-130 0.4 20.0
16.0 80.085.517.120.0µg/LVinyl Acetate 60-140 6.6 20.0
18.8 94.093.518.720.0µg/LVinyl Chloride 60-140 0.5 20.0
20.4 10210120.220.0µg/Lo-Xylene 70-130 0.9 20.0
42.5 10610642.340.0µg/Lm,p-Xylene 70-130 0.4 20.0
95.896.04-Bromofluorobenzene (S)70-130
96.897.0Dibromofluoromethane (S)70-130
93.694.61,2-Dichloroethane - d4 (S)70-130
112112Toluene-d8 (S)70-130
Page 6 of 14Date:08/08/2023 05:29 PM
Page 83 of 94
Quality Control Data
23-213-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
DW Tatum
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V36181QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V36179
Associated Lab Samples: 91161
LRB-V36179 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/03/23 02:0610.01.80<1.80µg/LAcetone
08/03/23 02:060.5000.180<0.180µg/LBenzene
08/03/23 02:060.5000.210<0.210µg/LBromobenzene
08/03/23 02:061.000.420<0.420µg/LBromochloromethane
08/03/23 02:060.5000.160<0.160µg/LBromodichloromethane
08/03/23 02:065.001.50<1.50µg/LBromoform
08/03/23 02:061.000.280<0.280µg/LBromomethane
08/03/23 02:060.5000.180<0.180µg/Ln-Butylbenzene
08/03/23 02:060.5000.200<0.200µg/Lsec-Butyl benzene
08/03/23 02:062.000.920<0.920µg/Ltert-Butyl benzene
08/03/23 02:060.5000.180<0.180µg/LCarbon Tetrachloride
08/03/23 02:060.5000.190<0.190µg/LChlorobenzene
08/03/23 02:060.5000.190<0.190µg/LChlorodibromomethane
08/03/23 02:061.000.430<0.430µg/LChloroethane
08/03/23 02:060.5000.220<0.220µg/LChloroform
08/03/23 02:060.5000.220<0.220µg/LChloromethane
08/03/23 02:060.5000.200<0.200µg/L2-Chlorotoluene
08/03/23 02:060.5000.200<0.200µg/L4-Chlorotoluene
08/03/23 02:060.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
08/03/23 02:062.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
08/03/23 02:060.5000.200<0.200µg/L1,2-Dibromoethane
08/03/23 02:060.5000.230<0.230µg/LDibromomethane
08/03/23 02:060.5000.220<0.220µg/L1,2-Dichlorobenzene
08/03/23 02:060.5000.190<0.190µg/L1,3-Dichlorobenzene
08/03/23 02:060.5000.210<0.210µg/L1,4-Dichlorobenzene
08/03/23 02:065.001.20<1.20µg/LDichlorodifluoromethane
08/03/23 02:060.5000.240<0.240µg/L1,1-Dichloroethane
Page 7 of 14Date:08/08/2023 05:29 PM
Page 84 of 94
Quality Control Data
23-213-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
DW Tatum
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V36181QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V36179
Associated Lab Samples: 91161
LRB-V36179 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/03/23 02:060.5000.150<0.150µg/L1,2-Dichloroethane
08/03/23 02:060.5000.150<0.150µg/L1,1-Dichloroethene
08/03/23 02:060.5000.200<0.200µg/Lcis-1,2-Dichloroethene
08/03/23 02:060.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
08/03/23 02:060.5000.190<0.190µg/L1,2-Dichloropropane
08/03/23 02:060.5000.130<0.130µg/L1,3-Dichloropropane
08/03/23 02:062.000.210<0.210µg/L2,2-Dichloropropane
08/03/23 02:060.5000.200<0.200µg/L1,1-Dichloropropene
08/03/23 02:060.5000.210<0.210µg/Lcis-1,3-Dichloropropene
08/03/23 02:060.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
08/03/23 02:0620042.0<42.0µg/LEthanol
08/03/23 02:060.5000.170<0.170µg/LEthylbenzene
08/03/23 02:063.000.350<0.350µg/LHexachlorobutadiene
08/03/23 02:061.000.380<0.380µg/L2-Hexanone
08/03/23 02:060.5000.180<0.180µg/LIsopropylbenzene
08/03/23 02:060.5000.089<0.089µg/L4-Isopropyl toluene
08/03/23 02:065.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
08/03/23 02:061.000.078<0.078µg/L4-Methyl-2-Pentanone
08/03/23 02:062.000.330<0.330µg/LMethylene Chloride
08/03/23 02:061.000.470<0.470µg/LNaphthalene
08/03/23 02:060.5000.190<0.190µg/Ln-Propylbenzene
08/03/23 02:060.5000.220<0.220µg/LStyrene
08/03/23 02:060.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
08/03/23 02:060.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
08/03/23 02:060.5000.220<0.220µg/LTetrachloroethene
08/03/23 02:060.5000.220<0.220µg/LToluene
08/03/23 02:060.5000.380<0.380µg/L1,2,3-Trichlorobenzene
Page 8 of 14Date:08/08/2023 05:29 PM
Page 85 of 94
Quality Control Data
23-213-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
DW Tatum
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V36181QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V36179
Associated Lab Samples: 91161
LRB-V36179 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/03/23 02:060.5000.310<0.310µg/L1,2,4-Trichlorobenzene
08/03/23 02:060.5000.160<0.160µg/L1,1,1-Trichloroethane
08/03/23 02:060.5000.096<0.096µg/L1,1,2-Trichloroethane
08/03/23 02:060.5000.180<0.180µg/LTrichloroethene
08/03/23 02:060.5000.180<0.180µg/LTrichlorofluoromethane
08/03/23 02:060.5000.270<0.270µg/L1,2,3-Trichloropropane
08/03/23 02:060.5000.190<0.190µg/L1,2,4-Trimethylbenzene
08/03/23 02:060.5000.180<0.180µg/L1,3,5-Trimethylbenzene
08/03/23 02:065.001.00<1.00µg/LVinyl Acetate
08/03/23 02:060.5000.170<0.170µg/LVinyl Chloride
08/03/23 02:060.5000.210<0.210µg/Lo-Xylene
08/03/23 02:061.000.420<0.420µg/Lm,p-Xylene
08/03/23 02:064-Bromofluorobenzene (S)96.4 70-130
08/03/23 02:06Dibromofluoromethane (S)98.0 70-130
08/03/23 02:061,2-Dichloroethane - d4 (S)92.4 70-130
08/03/23 02:06Toluene-d8 (S)111 70-130
LCS-V36179 LCSD-V36179Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
25.6 64.066.726.740.0µg/LAcetone 40-160 4.2 20.0
17.0 85.083.016.620.0µg/LBenzene 70-130 2.3 20.0
19.1 95.591.518.320.0µg/LBromobenzene 70-130 4.2 20.0
18.7 93.588.517.720.0µg/LBromochloromethane 70-130 5.4 20.0
16.0 80.080.016.020.0µg/LBromodichloromethane 70-130 0.0 20.0
22.0 11010721.420.0µg/LBromoform 70-130 2.7 20.0
Page 9 of 14Date:08/08/2023 05:29 PM
Page 86 of 94
Quality Control Data
23-213-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
DW Tatum
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V36181QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V36179
LCS-V36179 LCSD-V36179Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
15.1 75.563.012.620.0µg/LBromomethane 60-140 18.0 20.0
18.8 94.092.018.420.0µg/Ln-Butylbenzene 70-130 2.1 20.0
19.7 98.594.518.920.0µg/Lsec-Butyl benzene 70-130 4.1 20.0
19.9 99.597.019.420.0µg/Ltert-Butyl benzene 70-130 2.5 20.0
17.3 86.587.017.420.0µg/LCarbon Tetrachloride 70-130 0.5 20.0
20.1 10110120.120.0µg/LChlorobenzene 70-130 0.0 20.0
21.3 10710420.720.0µg/LChlorodibromomethane 70-130 2.8 20.0
19.2 96.092.518.520.0µg/LChloroethane 60-140 3.7 20.0
16.3 81.580.016.020.0µg/LChloroform 70-130 1.8 20.0
16.0 80.075.515.120.0µg/LChloromethane 60-140 5.7 20.0
18.9 94.590.518.120.0µg/L2-Chlorotoluene 70-130 4.3 20.0
19.7 98.595.519.120.0µg/L4-Chlorotoluene 70-130 3.0 20.0
14.2 71.070.014.020.0µg/LDi-Isopropyl Ether (DIPE)70-130 1.4 20.0
23.3 11711823.620.0µg/L1,2-Dibromo-3-Chloropropane 70-130 1.2 20.0
20.3 10210120.220.0µg/L1,2-Dibromoethane 70-130 0.4 20.0
16.5 82.582.016.420.0µg/LDibromomethane 70-130 0.6 20.0
21.2 10610521.020.0µg/L1,2-Dichlorobenzene 70-130 0.9 20.0
20.7 10499.519.920.0µg/L1,3-Dichlorobenzene 70-130 3.9 20.0
20.5 10310120.220.0µg/L1,4-Dichlorobenzene 70-130 1.4 20.0
15.8 79.078.015.620.0µg/LDichlorodifluoromethane 60-140 1.2 20.0
16.8 84.085.017.020.0µg/L1,1-Dichloroethane 70-130 1.1 20.0
15.6 78.076.515.320.0µg/L1,2-Dichloroethane 70-130 1.9 20.0
15.3 76.582.016.420.0µg/L1,1-Dichloroethene 70-130 6.9 20.0
16.2 81.079.515.920.0µg/Lcis-1,2-Dichloroethene 70-130 1.8 20.0
16.6 83.083.016.620.0µg/Ltrans-1,2-Dichloroethene 70-130 0.0 20.0
16.5 82.583.516.720.0µg/L1,2-Dichloropropane 70-130 1.2 20.0
Page 10 of 14Date:08/08/2023 05:29 PM
Page 87 of 94
Quality Control Data
23-213-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
DW Tatum
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V36181QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V36179
LCS-V36179 LCSD-V36179Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.9 99.598.019.620.0µg/L1,3-Dichloropropane 70-130 1.5 20.0
13.6 68.0*68.5*13.720.0µg/L2,2-Dichloropropane 70-130 0.7 20.0
17.7 88.588.517.720.0µg/L1,1-Dichloropropene 70-130 0.0 20.0
16.5 82.581.516.320.0µg/Lcis-1,3-Dichloropropene 70-130 1.2 20.0
16.6 83.080.516.120.0µg/Ltrans-1,3-Dichloropropene 70-130 3.0 20.0
383 76.683.6418500µg/LEthanol 60-140 8.7 20.0
18.9 94.593.018.620.0µg/LEthylbenzene 70-130 1.6 20.0
21.7 10911523.020.0µg/LHexachlorobutadiene 70-130 5.8 20.0
14.9 74.573.514.720.0µg/L2-Hexanone 60-140 1.3 20.0
20.4 10210420.720.0µg/LIsopropylbenzene 70-130 1.4 20.0
20.7 10498.519.720.0µg/L4-Isopropyl toluene 70-130 4.9 20.0
16.6 83.080.016.020.0µg/LMethyl Ethyl Ketone (MEK)60-140 3.6 20.0
14.1 70.568.513.720.0µg/L4-Methyl-2-Pentanone 60-140 2.8 20.0
14.9 74.574.514.920.0µg/LMethylene Chloride 70-130 0.0 20.0
21.8 10911522.920.0µg/LNaphthalene 70-130 4.9 20.0
18.9 94.592.518.520.0µg/Ln-Propylbenzene 70-130 2.1 20.0
20.9 10510020.020.0µg/LStyrene 70-130 4.4 20.0
21.1 10610420.820.0µg/L1,1,1,2-Tetrachloroethane 70-130 1.4 20.0
19.3 96.589.017.820.0µg/L1,1,2,2-Tetrachloroethane 70-130 8.0 20.0
21.6 10810921.820.0µg/LTetrachloroethene 70-130 0.9 20.0
16.6 83.083.016.620.0µg/LToluene 70-130 0.0 20.0
25.3 127133*26.620.0µg/L1,2,3-Trichlorobenzene 70-130 5.0 20.0
23.7 11912124.220.0µg/L1,2,4-Trichlorobenzene 70-130 2.0 20.0
16.7 83.581.516.320.0µg/L1,1,1-Trichloroethane 70-130 2.4 20.0
18.0 90.088.017.620.0µg/L1,1,2-Trichloroethane 70-130 2.2 20.0
18.3 91.591.518.320.0µg/LTrichloroethene 70-130 0.0 20.0
Page 11 of 14* QC Fail Date:08/08/2023 05:29 PM
Page 88 of 94
Quality Control Data
23-213-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
DW Tatum
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V36181QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V36179
LCS-V36179 LCSD-V36179Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
16.7 83.588.017.620.0µg/LTrichlorofluoromethane 60-140 5.2 20.0
19.5 97.593.518.720.0µg/L1,2,3-Trichloropropane 70-130 4.1 20.0
20.2 10199.019.820.0µg/L1,2,4-Trimethylbenzene 70-130 2.0 20.0
20.5 10399.019.820.0µg/L1,3,5-Trimethylbenzene 70-130 3.4 20.0
16.9 84.566.013.220.0µg/LVinyl Acetate 60-140 24.5*20.0
18.5 92.592.518.520.0µg/LVinyl Chloride 60-140 0.0 20.0
19.5 97.595.019.020.0µg/Lo-Xylene 70-130 2.5 20.0
40.8 10210040.140.0µg/Lm,p-Xylene 70-130 1.7 20.0
94.291.24-Bromofluorobenzene (S)70-130
99.098.4Dibromofluoromethane (S)70-130
95.697.21,2-Dichloroethane - d4 (S)70-130
111112Toluene-d8 (S)70-130
Page 12 of 14* QC Fail Date:08/08/2023 05:29 PM
Page 89 of 94
Quality Control Data
23-213-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
DW Tatum
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V36275QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V36274
Associated Lab Samples: 91148, 91158
LRB-V36274 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/03/23 15:311.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
08/03/23 15:310.5000.190<0.190µg/L1,2,4-Trimethylbenzene
08/03/23 15:314-Bromofluorobenzene (S)92.0 70-130
08/03/23 15:31Dibromofluoromethane (S)99.6 70-130
08/03/23 15:311,2-Dichloroethane - d4 (S)94.8 70-130
08/03/23 15:31Toluene-d8 (S)113 70-130
LCS-V36274 LCSD-V36274Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
17.4 87.081.516.320.0µg/LMethyl tert-butyl ether (MTBE)70-130 6.5 20.0
21.5 10810420.820.0µg/L1,2,4-Trimethylbenzene 70-130 3.3 20.0
96.693.64-Bromofluorobenzene (S)70-130
96.299.4Dibromofluoromethane (S)70-130
92.291.81,2-Dichloroethane - d4 (S)70-130
113111Toluene-d8 (S)70-130
Page 13 of 14Date:08/08/2023 05:29 PM
Page 90 of 94
Quality Control Data
23-213-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
DW Tatum
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V36350QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V36349
Associated Lab Samples: 91161
LRB-V36349 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/03/23 15:311.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
08/03/23 15:314-Bromofluorobenzene (S)92.0 70-130
08/03/23 15:31Dibromofluoromethane (S)99.6 70-130
08/03/23 15:311,2-Dichloroethane - d4 (S)94.8 70-130
08/03/23 15:31Toluene-d8 (S)113 70-130
LCS-V36349 LCSD-V36349Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
17.4 87.081.516.320.0µg/LMethyl tert-butyl ether (MTBE)70-130 6.5 20.0
96.693.64-Bromofluorobenzene (S)70-130
96.299.4Dibromofluoromethane (S)70-130
92.291.81,2-Dichloroethane - d4 (S)70-130
113111Toluene-d8 (S)70-130
Page 14 of 14Date:08/08/2023 05:29 PM
Page 91 of 94
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:23-213-0004
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 0.5C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:08/01/2023 10:41:55
Special precautions or instructions included?
Comments:
Page 92 of 94
Page 93 of 94
Page 94 of 94