FA-753_13439_CA_MRP_20230628

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
June 29, 2023

Mr. Mike Haseltine
NCDEQ-UST Section
Fayetteville Regional Office
Systel Building
225 Green Street, Suite 714
Fayetteville, NC 28301-5043

Re: Ground Water Monitoring Report
June 2023
Gray’s Creek Superette
6353 NC 87 Highway
Fayetteville, Cumberland County
North Carolina
Facility ID Number: 00-0-0000011672
Incident Number: 13439
GRI Project Number: 5408

Dear Mr. Haseltine,

Please find enclosed the referenced report for the abovementioned site.
If you have any questions, please contact William Regenthal at 704-845-4010.

Sincerely,
Geological Resources, Inc.

Leslie Maxtone-Graham
Administrative Assistant

Enclosure

Cc: Mrs. Deborah Taylor; D. K. Taylor Oil Company, file

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Engineering Certification: C-2727 • Geology Certification: C-127
Ground Water Monitoring Report
June 2023
Gray’s Creek Superette
6353 S NC 87 Highway
Fayetteville, Cumberland County
North Carolina
Facility ID Number: 00-0-0000011672
Incident Number: 13439
GRI Project Number: 5408

Prepared for:

Mrs. Deborah Taylor
D. K. Taylor Oil Company
202 Cumberland St
Fayetteville, NC 28301

June 28, 2023

William Regenthal P. G.
Project Manager
Colton Coolbaugh GIT
Staff Scientist

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: June 28, 2023 Gray’s Creek Superette
Project Manager: William Regenthal P. G. GRI Project No. 5408
i
SITE INFORMATION
1. Site Identification
 Gray’s Creek Superette (Facility ID 00-0-0000011672)
 Incident Number 13439 – High Risk (H185D)
 Location of Source Area: 6353 S NC 87 Highway
Fayetteville, NC 28677
Cumberland County
34.90112°N, 78.852486°W (Topographical Map)
2. Information about Contacts Associated with the Leaking UST System

UST Owner
D. K. Taylor Oil Company, Inc.
Post Office Box 723
Fayetteville, NC 28302
[e-mail]
910-483-1306

UST Operator
D. K. Taylor Oil Company, Inc.
Post Office Box 723
Fayetteville, NC 28302
[e-mail]
910-483-1306

Property Owner
Alhobishi Conv. Stores & Rentals, Inc.
Post Office Box 807
St. Pauls, NC 28384
Email Unknown
Phone No. Unknown

Property Occupant
Vacant

Consultant/Contractor
Geological Resources, Inc.
3502 Hayes Road
Monroe, NC 28110
[e-mail]
704-845-4010

Analytical Laboratory
SGS North America, Inc.
4405 Vineland Road, Suite C-15
Orlando, FL 32811
State Certification No. 96038001
407-425-6700
3. Information about Release
 Release was discovered on June 1994
 An unknown amount of product was released from the leaking UST System
 Two 6,000-gallon gasoline, two 2,000-gallon gasoline and one 550-gallon kerosene USTs and
associated pumps and product piping were removed from the site in June 1994

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: June 28, 2023 Gray’s Creek Superette
Project Manager: William Regenthal P. G. GRI Project No. 5408
ii
EXECUTIVE SUMMARY
Gray’s Creek Superette is located at 6353 S NC 87 Highway in Fayetteville, Cumberland County, North
Carolina. The site is currently owned by Alhobishi Convenience Stores and was operated by D.K Taylor Oil
Company, Inc. as a petroleum retail facility. The site is currently vacant. A release was discovered
following the removal of two 6,000-gallon gasoline, two 2,000-gallon gasoline and one 550-gallon
kerosene USTs. There is currently one temporarily closed 10,000-gallon compartmentalized UST located
in a separate UST basin to the south of the site building. This UST is recognized under a separate facility
ID number 00-0-0000036605 and is not currently associated with UST Incident Number 13439. The
adjoining properties are a mixture of single family residential, commercial and agricultural properties.

A CAP has not been developed for the incident.

Receptor information was updated for the site on October 30, 2020. Thirty-six water supply wells were
identified within 1,500 feet of the site. The former on-site water supply well appears to have been
destroyed. The well house associated with the former on-site water supply well remains, and has been
overgrown with brush. No water supply wells were identified within a 250-foot radius of the site. A
tributary to Long’s Branch was identified within a 500-foot radius of the site. Public water is not available
to the site or surrounding properties within a 1,500-foot radius of the site.

On June 5, 2023, nine monitoring wells and two water supply wells were gauged, purged and/or sampled.
Please note, MW-1R, MW-4, MW-7, MW-8, MW-11 and MW-12 lacked sufficient well volume to be
sampled after gauging. No concentrations of requested method constituents that exceeded the MACs
were reported in the ground water samples collected during the June 2023 sampling event. None of the
reported contaminant concentrations exceeded the GCLs.

A GSI Mann-Kendall Toolkit for Plume Stability Analysis was completed for individual BTEX constituents
and naphthalene for MW-1/MW-1R and naphthalene for MW-2/MW-2R. The plume stability analysis
indicates that concentrations of benzene and toluene were decreasing for MW-1/MW-1R. The remaining
constituents in MW-1/MW-1R and naphthalene in MW-2/2R show no trend currently.

Based on this information, site conditions should be monitored and sampling re-attempted when
sufficient recharge has occurred. It appears that contamination associated with the site may be confined
to a surficial perched water zone and may not be indicative of actual ground water quality in the vicinity
of the site. The horizontal contaminant plume is reasonably defined for this incident. The site risk
classification should be re-evaluated for this incident since sufficient sample volume has not been able to
be observed. If the site risk classification can be lowered, a NRP for ground water should be filed on the
deed of the subject property.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: June 28, 2023 Gray’s Creek Superette
Project Manager: William Regenthal P. G. GRI Project No. 5408
iii
ACRONYMS
ACM: Asbestos Containing Materials
AFVR: Aggressive Fluid-Vapor Recovery
ARR: Acknowledgement of Report Receipt
AS: Air Sparging
AST: Aboveground Storage Tank
ASTM: American Society for Testing and
Materials
BGS: Below Ground Surface
CAP: Corrective Action Plan
CFR: Code of Federal Regulations
CSA: Comprehensive Site Assessment
DPE: Dual Phase Extraction
DRO: Total Petroleum Hydrocarbons Diesel
Range Organics
DWM: Division of Waste Management
DWR: Department of Water Resources
EPA: Environmental Protection Agency
EPH: Extractible Petroleum Hydrocarbons
ESA: Environmental Site Assessment
GCL: Gross Contamination Level
GRI: Geological Resources, Inc.
GRO: Total Petroleum Hydrocarbons
Gasoline Range Organics
LSA: Limited Site Assessment
MAC: Maximum Allowable Concentration as
specified in T15A NCAC 2L.0202
MADEP: Massachusetts Department of
Environmental Protection
MCC: Maximum Contaminant Concentrations
MMPE: Mobile Multi-Phase Extraction
NAPL: Non-Aqueous Phase Liquid, “Free
Product”
NCDEQ: North Carolina Department of
Environmental Quality
NCDOT: North Carolina Department of
Transportation
NFA: Notice of No Further Action
NORR: Notice of Regulatory Requirements
NOV: Notice of Violation
NPDES: National Pollutant Discharge
Elimination System
NRP: Notice of Residual Petroleum
O&M: Operation and Maintenance
PAHs: Polynuclear Aromatic Hydrocarbons
PCA: Pre-Construction Assessment
RAL: Regulatory Action Level
SCLs: Soil Cleanup Level
SPCC: Spill Prevention Control and
Countermeasures
SVE: Soil Vapor Extraction
SVOCs: Semi-Volatile Organic Compounds
SWPPP: Stormwater Pollution Prevention Plan
TCLP: Toxicity Characteristic Leaching
Procedure (EPA Method SW-846 1311)
TOC: Top of Casing
TPH: Total Petroleum Hydrocarbons
USGS: United States Geological Survey
UST: Underground Storage Tank
UVF: Ultraviolet Fluorescence
VOCs: Volatile Organic Compounds
VPH: Volatile Petroleum Hydrocarbons

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: June 28, 2023 Gray’s Creek Superette
Project Manager: William Regenthal P. G. GRI Project No. 5408
TABLE OF CONTENTS
SITE INFORMATION ............................................................................................................................ i
EXECUTIVE SUMMARY ....................................................................................................................... ii
ACRONYMS ....................................................................................................................................... iii
1.0 SITE HISTORY AND CHARACTERIZATION ...................................................................................1
2.0 PRESENTATION OF CURRENT SITE ASSESSMENT INFORMATION/ COMPARISON TO HISTORICAL
ASSESSMENT INFORMATION ...................................................................................................2
3.0 NATURAL ATTENUATION / NATURAL SOURCE ZONE DEPLETION STATUS ..................................4
4.0 CONCLUSIONS .........................................................................................................................4
5.0 LIMITATIONS ...........................................................................................................................5
6.0 STATEMENTS AND CERTIFICATION ...........................................................................................5

FIGURES
Figure 1: Site Location Map
Figure 2: Site Vicinity Map
Figure 3: Site Map
Figure 4: Water Table Surface Map
Figure 5: Ground Water Quality Map
Figure 6: Estimated Contaminant Mass Area Map

TABLES
Table 1: UST Owner and Operator Information
Table 2: UST System Information
Table 3: Water Supply Well Information
Table 4: Adjacent Property Owner Information
Table 5: Well Construction and Gauging Information
Table 6: Summary of Ground Water Sample Analytical Results
Table 6A: Summary of Field Parameter Results
APPENDICES
Appendix A: State Correspondence
Appendix B: CSA Cross Section Maps
Appendix C: Laboratory Report – Ground Water Samples
Appendix D: GSI Mann-Kendall Calculations

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: June 28, 2023 Gray’s Creek Superette
Project Manager: William Regenthal P. G. GRI Project No. 5408
1
1.0 SITE HISTORY AND CHARACTERIZATION
GRI presents the results of the June 2023 ground water sampling event at the Gray’s Creek Superette site;
located at 6353 S NC 87 Highway in Fayetteville, Cumberland County, North Carolina (Figure 1). These
activities were conducted in accordance with GRI Proposal No. 23-326, which was submitted to NCDEQ
on May 26, 2023, and was approved as Task Authorization No. 13439-06 on May 26, 2023. State
correspondence has been included as Appendix A.

The site is currently owned by Alhobishi Convenience Stores and Rentals, Inc. and was operated by D. K.
Taylor Oil Company as a petroleum retail facility. The site is currently vacant. A release was discovered
in June 1994 following the removal of two 6,000-gallon gasoline, two 2,000-gallon gasoline and one 550-
gallon kerosene USTs. Please note, a new UST system consisting of one 10,000-gallon compartmentalized
UST and assosiated piping was installed in 2004 under facility ID number 00-0-0000036605. This system
is currently under temporary closure. This UST system is not currently associated with UST Incident
Number 13439. UST owner/operator information and UST system information for Facility ID 00-0-
0000011672 are included as Tables 1 and 2, respectively. The Registered Tank Reports for both facility
IDs are shown below:

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: June 28, 2023 Gray’s Creek Superette
Project Manager: William Regenthal P. G. GRI Project No. 5408
2

The site and surrounding area are a mixture of single family residential, commercial and agricultural
properties. The site contains one building and is primarily capped with concrete and asphalt. The overall
topography at the site is relatively flat. A tributary to Long’s Branch is located within a 500-foot radius of
the site. Twelve Type II monitoring wells (MW-1 through MW-6) were installed at the site during previous
ground water assessment activities. Please note, MW-1, MW-2, MW-3, MW-5 and MW-6 have not been
located and are assumed to have been destroyed. Monitoring wells MW-1R and MW-2R were installed
as replacements for MW-1 and MW-2. Cross section maps from the previous consultant’s CSA Report are
included as Appendix B.

On October 30, 2020, GRI personnel conducted an updated receptor survey at the site. Thirty-six potable
water supply wells (WSW-1 through WSW-36) were identified within a 1,500-foot radius of the site. Of
the identified water supply wells, ten (WSW-1 through WSW-5, WSW-11, WSW-12, WSW-13 and WSW-
33) were located within a 1,000-foot radius of the site. No water supply wells were identified within a
250-foot radius of the site. The former on-site water supply well appears to have been destroyed. Only
the well house remains, and is overgrown with brush. Municipal water is not available to the site or
surrounding properties. The site does not lie within a designated wellhead protection area. Water supply
well information is presented in Table 3. Adjacent property owner information is presented in Table 4. A
Site Vicinity Map showing the adjacent properties has been included as Figure 2. A Site Map showing the
locations of the monitoring wells and the structures on-site has been included as Figure 3.

A CSA was completed by a past consultant on June 25, 1995. A CAP has not been completed for this
incident.
2.0 PRESENTATION OF CURRENT SITE ASSESSMENT INFORMATION/ COMPARISON TO HISTORICAL
ASSESSMENT INFORMATION
On June 5, 2023, nine Type II monitoring wells (MW-1R, MW-2R, MW-4 and/or MW-7 through MW-12)
and two water supply wells (WSW-1 and WSW-2) were gauged, purged and/or sampled in accordance

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: June 28, 2023 Gray’s Creek Superette
Project Manager: William Regenthal P. G. GRI Project No. 5408
3
with NCDEQ guidelines. Please note, MW-1R, MW-4, MW-7, MW-8, MW-11 and MW-12 contained
insufficient water volume and were not sampled. Depths to ground water in the Type II monitoring wells
ranged from 5.41 feet to 14.22 feet below the tops of well casings. Ground water elevations in the Type
II monitoring wells ranged from 85.50 feet to 94.83 feet. Ground water flow was generally to the
northeast with a horizontal gradient of approximately 0.20 feet per foot. Well construction and gauging
information is presented in Table 5. A Water Table Surface Map is included as Figure 4. A summary of
the current ground water gauging data is shown below:
Well ID
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(feet)
Free
Product
Thickness
(ft.)
Ground
Water
Elevation
(ft.)
MW-1R 5 – 15 15 100.00 Dry Dry Dry
MW-2R 5 – 15 15 100.06 13.49 --- 86.57
MW-4 5 - 20 20 99.49 Dry Dry Dry
MW-7 5 - 15 15 100.31 Dry Dry Dry
MW-8 5 - 15 15 99.92 Dry Dry Dry
MW-9 10 - 20 20 99.72 14.22 --- 85.50
MW-10 5 - 15 15 100.24 5.41 --- 94.83
MW-11 5 - 15 15 99.81 Dry Dry Dry
MW-12 5 - 15 15 99.96 Dry Dry Dry

Ground water samples collected from the monitoring wells were submitted for laboratory analyses using
EPA Method 6200B and for natural attenuation parameters (nitrate, ferrous iron, sulfate and methane).
Field parameters (dissolved oxygen, oxidation reduction potential, pH, conductivity and temperature)
were measured during sample collection. Ground water samples collected from the water supply wells
were submitted for laboratory analyses of VOCs All reported contaminant concentrations were less than
the MACs. A summary of the analytical results for ground water samples collected in June 2023 is
presented in Table 6. A Ground Water Quality Map based on the June 2023 data is included as Figure 5.
A complete report of laboratory analyses of the ground water samples collected from the monitoring wells
during the June 2023 sampling event has been included as Appendix C. A summary of the current ground
water analytical data is shown below:

Contaminant
of Concern →
Be
n
z
e
n
e

To
l
u
e
n
e

Et
h
y
l
b
e
n
z
e
n
e

Xy
l
e
n
e
s

MT
B
E

Na
p
h
t
h
a
l
e
n
e

Well
ID
MACs (mg/l) 1 600 600 500 20 6
GCL (mg/l) 5,000 260,000 84,500 85,500 20,000 6,000
MW-1R NS NS NS NS NS NS
MW-2R <0.13 <0.13 <0.13 <0.25 <0.13 <0.13
MW-4 NS NS NS NS NS NS
MW-7 NS NS NS NS NS NS
MW-8 NS NS NS NS NS NS
MW-9 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13
MW-10 <0.13 <0.13 0.14 J <0.25 <0.13 0.32 J
MW-11 NS NS NS NS NS NS
MW-12 NS NS NS NS NS NS

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: June 28, 2023 Gray’s Creek Superette
Project Manager: William Regenthal P. G. GRI Project No. 5408
4

The site is located in the Coastal Plain Physiographic Province of North Carolina. The water table has a
seasonal high depth to water of approximately 8 to 14.5 feet bgs.
3.0 NATURAL ATTENUATION / NATURAL SOURCE ZONE DEPLETION STATUS
During the June 2023 sampling event, natural attenuation parameters were collected from monitoring
wells MW-2R, MW-9 and MW-10. A summary of field and natural attenuation parameters collected
during the June 2023 sampling event are summarized in Table 6A.

Free product has not been observed at the site. A CAP has not been completed for this incident. No
contaminant reduction milestones have been established.

In June 2023, a Mann-Kendall Toolkit for Plume Stability Analysis was prepared for individual BTEX
constituents and naphthalene for MW-1/MW-1R and naphthalene for MW-2/MW-2R. The results of the
analysis indicate that benzene and toluene concentrations observed in MW-1/MW-1R are decreasing. No
trend could currently be established for the remaining constituents in MW-1/MW-1R or naphthalene in
MW-2/MW-2R. A copy of the Mann-Kendall Toolkit for Plume Stability Analysis is included as Appendix
D.
4.0 CONCLUSIONS
• On June 5, 2023, nine Type II monitoring wells were gauged, purged and/or sampled.
• Six Type II monitoring wells (MW-1R, MW-4, MW-7, MW-8, MW-11 and MW-12) lacked sufficient
well volume for lab analysis.
• Ground water flow was generally toward the northeast with an average horizontal hydraulic
gradient of approximately 0.20 feet per foot.
• No concentrations of requested method constituents that exceeded the MACs were reported in
the ground water samples collected from during the June 2023 sampling event. None of the
reported contaminant concentrations exceeded the GCLs.
• A GSI Mann-Kendall Toolkit for Plume Stability Analysis was completed for individual BTEX
constituents and naphthalene for MW-1/MW-1R and naphthalene for MW-2/MW-2R. The plume
stability analysis indicates that concentrations of benzene and toluene were decreasing for MW-
1/MW-1R. The remaining constituents in MW-1/MW-1R and naphthalene in MW-2/2R show no
trend currently.
• Based on this information, site conditions should be monitored and sampling re-attempted when
sufficient recharge has occurred. It appears that contamination associated with the site may be
Contaminant
of Concern →
Be
n
z
e
n
e

To
l
u
e
n
e

Et
h
y
l
b
e
n
z
e
n
e

Xy
l
e
n
e
s

MT
B
E

Na
p
h
t
h
a
l
e
n
e

Well
ID
MACs (mg/l) 1 600 600 500 20 6
GCL (mg/l) 5,000 260,000 84,500 85,500 20,000 6,000
WSW-1 <0.13 0.33 J <0.13 <0.25 <0.13 <0.13
WSW-11 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: June 28, 2023 Gray’s Creek Superette
Project Manager: William Regenthal P. G. GRI Project No. 5408
5
confined to a surficial perched water zone and may not be indicative of actual ground water
quality in the vicinity of the site. The horizontal contaminant plume is reasonably defined for this
incident. The site risk classification should be re-evaluated for this incident since sufficient sample
volume has not been able to be observed. If the site risk classification can be lowered, a NRP for
ground water should be filed on the deed of the subject property.
5.0 LIMITATIONS
This report has been prepared for the exclusive use of D. K. Taylor Oil Company for specific application to
the referenced site in Cumberland County, North Carolina. The assessment was conducted based on the
scope of work and level of effort desired by NCDEQ and with resources adequate only for that scope of
work. Our findings have been developed in accordance with generally accepted standards of
environmental practices in the State of North Carolina, available information, and our professional
judgment. No other warranty is expressed or implied.

The data that are presented in this report are indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would
be interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from these data.
6.0 STATEMENTS AND CERTIFICATION
1 Enter the date the monitoring report was due. n/a Will this report be submitted after the
established due date?
YES NO
2 Was any required information from the above template missing from this report? YES NO
IF the answer to question #1 or# 2 is “YES”, please provide additional information in this cell to explain
what was missing and why.
3 If applicable, will any of the proposed attenuation milestones under the schedule approved
in the Corrective Action Plan not be met? (within a reasonable margin of error)
YES NO
IF the answer to question #3 is “NO”, skip to the certification under #8 below.
IF the answer to question #3 is “YES”, please generally describe in this cell the possible reason(s) and
outline proposed remedies. (This should be described in more detail in the report text above.)

N/A
4 Does any known or suspected source zone soil contamination or free product remain
outside of the assessed area that could be inhibiting natural attenuation?
YES NO
5 Has there been an unexpected increase in contaminant mass sufficient to suggest a
potential new release from a separate onsite or offsite source?
YES NO

FIGURES
SITE LOCATION
Figure 1
Site Location
Gray’s Creek Superette
6353 NC Highway 87 South
Fayetteville, Cumberland County, NC
Incident No. 13439
GRI Project No. 5408
500 M
2000 FT
Date: 12/16/2020 Location: 34.901120° N -78.852486° W
D
a
d
"J
"J
"J
"J
"J
"J "J
"J
"J
"J
"J
"J
"J
"J
"J
"J "J
"J "J
"J "J "J
"J "J
"J
"J
"J"J"J
"J
"J "J
"J
"J
"J
"J
SITE
0441-38-5515
0441-39-3260
0441-58-3144
0441-48-4813
0441-49-1427
0441-58-3548
0441-48-1127
0441-59-2298
0441-59-1274
0441-59-0260
0441-49-9155
0441-49-8132
0441-49-7019
0441-49-5095
0441-49-4072
0441-38-8678
0441-39-1728
0441-37-6600
0441-47-0950
0441-37-8714
0441-49-0722
0441-37-9843
0441-47-2858
0441-47-3644
0441-28-8457
0441-28-7688
0441-47-1567
0441-48-2904
0442-30-7247 0442-30-8383
0442-40-5397
0442-40-4373
0442-40-3268
0442-40-2254
0442-40-1240
0442-40-0126
0442-40-0460
0442-40-1466
0442-40-3408
WSW-9
WSW-8
WSW-7WSW-6
WSW-5
WSW-4WSW-3
WSW-2
WSW-1
WSW-36
WSW-35
WSW-34
WSW-33
WSW-32WSW-31
WSW-30
WSW-29
WSW-28
WSW-26
WSW-25
WSW-24
WSW-22WSW-21 WSW-19
WSW-17
WSW-15
WSW-14
WSW-13
WSW-12
WSW-11
WSW-10
Longs Branch
NC HWY 87 S
ALDERMAN RD
GRAYS CREEK CHURCH RD
THROWER RD
RIDDLE FARM RD
FARMALL DR
ALLY RAYVEN DR
STRATA DR
BREE BRIDGE RD
HUB JOHNSON RD
DOCK ST
SUNSET VIEW RD
NC HWY 87 S
WSW-27
WSW-23
WSW-20
WSW-18
WSW-16
FIGURE 2: SITE VICINITY MAPGRAY'S CREEK SUPERETTER6353 NC HIGHWAY 87 SFAYETTEVILLE, CUMBERLAND COUNTYNORTH CAROLINAINCIDENT NO. 13439GRI NO. 5408
PREPARED BY:GEOLOGICAL RESOURCES, INC.OCTOBER 16, 2020
1,500-FOOT RADIUS
1,000-FOOT RADIUS
250-FOOT RADIUS
³
0 300150Feet
1 inch = 300 feet
500-FOOT RADIUS
LEGEND
"J Water Supply Well
Centerlines
Surface Water Body
Hydropolygons
Well Owners and Adjacent Properties
Tax_Parcels
X
X
X
X
X
X
X
X
X
X
X
X
X
X X
X
X
X
X
X
X
X
X
X
X
X
X
X
X X
X
X
X
X
X
X
X
X
X
X
X
X
X
X X

TABLES
UST ID Number 1-5 Facility ID Number
Owner or Operator?
Owner/Operator
Address
Post Office Box 723, Fayetteville, NC 28302 910-483-1306
Telephone Number
TABLE 1
UST OWNER/OPERATOR INFORMATION
GRAY'S CREEK SUPERETTE (INCIDENT NO. 13439)
00-0-0000011672
Name of Owner or Operator Dates of Ownership / Operation
DK Taylor Oil Company 05/08/1977 - 06/30/1994
Page 1 of 1
Date: 11/23/2020
Was Release
Associated
with UST
System?
(Yes / No)
1 Gasoline,
Gas Mix 6,000 5/8/1977 Single Wall Steel 8' x 16'Single Wall Steel Removed Yes
2 Gasoline,
Gas Mix 6,000 5/8/1977 Single Wall Steel 8' x 16'Single Wall Steel Removed Yes
3 Gasoline,
Gas Mix 2,000 5/8/1977 Single Wall Steel 64'' x 12'Single Wall Steel Removed Yes
4 Gasoline,
Gas Mix 2,000 5/8/1977 Single Wall Steel 64'' x 12'Single Wall Steel Removed Yes
5 Kerosene,
Kero Mix 550 5/8/1977 Single Wall Steel 45.5'' x 76''Single Wall Steel Removed Yes
Notes:
• FRP: Fiberglass reinforced plastic.
TABLE 2
UST SYSTEM INFORMATION
GRAY'S CREEK SUPERETTE (INCIDENT NO. 13439)
Status
of
UST
UST
ID
No.
Current
or Most
Recent
Contents
Capacity
(gallons)
Date
Installed
Construction
Details
Tank
Dimensions
Description of
Associated
Product Piping
and
Pumps
Facility ID # : 00-0-0000011672
Page 1 of 1
Facility ID # : 00-0-0000011672
Well ID.Parcel ID No.Well Owner Mailing Address Well Address
Well Use
(Potable / Non-
Potable
etc.)
Connected to
Municipal Water
Yes/No
Distance from
source area of
release
(ft.)
WSW-1 0441-49-4072 Job Jr. & Iris James 5246 Grays Creek Church Rd, Hope
Mills, NC 28348
5246 Grays Creek Church Rd, Hope
Mills, NC 28348 Potable No ~300 E
WSW-2 0441-49-5095 Eric B. & Marcella Bostic 5232 Gray's Creek Church Rd, Hope
Mills, NC 28348
5232 Gray's Creek Church Rd, Hope
Mills, NC 28348 Potable No ~560 SE
WSW-3 0441-49-7019 Matthew S. & Arlene I. Konopatski 5218 Grays Creek Church Rd, Hope
Mills, NC 28348
5218 Grays Creek Church Rd, Hope
Mills, NC 28348 Potable No ~540 E
WSW-4 0441-49-8132 Jonell & Vatashia J. Wells 5204 Grays Creek Church Rd, Hope
Mills, NC 28348
5204 Grays Creek Church Rd, Hope
Mills, NC 28348 Potable No ~660 E
WSW-5 0441-49-9155 Katisha & Donald McCullough 5192 Grays Creek Church Rd, Hope
Mills, NC 28348
5192 Grays Creek Church Rd, Hope
Mills, NC 28348 Potable No ~830 E
WSW-6 0441-59-0260 Dwight P. Thompson 5180 Grays Creek Church Rd, Hope
Mills, NC 28348
5180 Grays Creek Church Rd, Hope
Mills, NC 28348 Potable No ~1,080 SE
WSW-7 0441-59-1274 Adrian B. & Marsha L. Ellison 5166 Grays Creek Church Rd, Hope
Mills, NC 28348
5166 Grays Creek Church Rd, Hope
Mills, NC 28348 Potable No ~1,110 SE
WSW-8 0441-59-2298 Rebecca J. & Johnathan S. Radcliffe 5152 Grays Creek Church Rd, Hope
Mills, NC 28348
5152 Grays Creek Church Rd, Hope
Mills, NC 28348 Potable No ~1,240 SE
WSW-9 0441-58-3548 Leonard D. Jernigan 2905 Strata Dr, Hope Mills, NC
28348
2905 Strata Dr, Hope Mills, NC
28348 Potable No ~1,300 SE
WSW-10 0441-58-3144 Terrence J White, Trustee 2910 Strata Dr, Hope Mills, NC
28348
2910 Strata Dr, Hope Mills, NC
28348 Potable No ~1,470' SE
WSW-11 0441-49-1427 Rebecca D. Tyson; Elizabeth R.
Thomas
4295 S NC 87 Hwy, Fayetteville, NC
28306
6309 S NC 87 Hwy
Fayetteville, NC 28306 Potable No ~370 N
WSW-12 0441-49-0722 Jacqueline H. & Melvin W. Jr.
McAllister
6275 S NC 87 Hwy, Fayetteville, NC
28306
6275 S NC 87 Hwy
Fayetteville, NC 28306 Potable No ~810 N
WSW-13 0441-39-3260 Shondell A. & Tasha Y. Lloyd
Trustees 7319 Ave T, Brooklyn, NY 11234 6300 S NC 87 Hwy
Fayetteville, NC 28306 Potable No ~590 NW
WSW-14 0442-30-8150 Amanda L Mooney 2704 Ally Raven Dr, Hope Mills, NC
28348
2704 Ally Raven Dr, Hope Mills, NC
28348 Potable No ~1,160 N
WSW-15 0442-40-0126 Michael A. & Ashley R. Metz 2708 Ally Raven Dr, Fayetteville, NC
28306
2708 Ally Rayven Dr, Fayettville NC
28306 Potable No ~1,250 NE
WSW-16 0442-40-1240 Steven L Rickets Jr.2712 Ally Rayven Dr, Fayetteville, NC
28306
2712 Ally Rayven Dr, Fayetteville, NC
28306 Potable No ~1,330 NE
WSW-17 0442-40-2254 Ronnie Lee Tew Jr.2716 Ally Rayven Dr, Fayetteville, NC
28306
2716 Ally Rayven Dr, Fayetteville, NC
28306 Potable No ~1,360 NE
WSW-18 0442-40-3268 Johnathan G. & Hannah Bumbales 2720 Ally Rayven Dr, Fayetteville, NC 2720 Ally Rayven Dr, Fayetteville, NC Potable No ~1,440 NE
WSW-19 0442-40-4373 Michael D. Massarelli 2724 Ally Rayven Dr, Fayetteville, NC
28306
2724 Ally Rayven Dr, Fayetteville, NC
28306 Potable No ~1,470 NE
WSW-20 0442-30-7247 Shekita, Jones 2701 Ally Rayven Rd, Fayetteville,
NC 28306
2701 Ally Rayven Rd, Fayetteville,
NC 28306 Potable No ~1,420 N
TABLE 3
WATER SUPPLY WELL INFORMATION
GRAY'S CREEK SUPERETTE (INCIDENT NO. 13439)
Date: 11/23/2020
Page 1 of 2
Facility ID # : 00-0-0000011672
Well ID.Parcel ID No.Well Owner Mailing Address Well Address
Well Use
(Potable / Non-
Potable
etc.)
Connected to
Municipal Water
Yes/No
Distance from
source area of
release
(ft.)
TABLE 3
WATER SUPPLY WELL INFORMATION
GRAY'S CREEK SUPERETTE (INCIDENT NO. 13439)
Date: 11/23/2020
WSW-21 0442-30-8383 Sandra D. Clemmons 4914 Dock St, Fayetteville, NC 28306 4914 Dock St, Fayetteville, NC 28306 Potable No ~1,430 N
WSW-22 0442-40-0460 Rene & Elizabeth Gonzalez 2713 Ally Rayven Dr, Fayetteville, NC
28306
2713 Ally Rayven Dr, Fayetteville, NC
28306 Potable No ~1,390 NE
WSW-23 0442-40-1466 Chad A. & Carrie A. Waleisky 2717 Ally Rayven Dr, Fayetteville, NC
28306
2717 Ally Rayven Dr, Fayetteville, NC
28306 Potable No ~1,450 NE
WSW-24 0442-40-3408 Latonya N. Mason 2721 Ally Rayven Dr, Fayetteville, NC
28306
2721 Ally Rayven Dr, Fayetteville, NC
28306 Potable No ~1,470 NE
WSW-25 0441-47-2858 Robert K. & Kimberly H. Mitchell 5204 Farmall Dr, Fayetteville, NC
28306
5204 Farmall Dr, Fayetteville, NC
28306 Potable No ~1,090 SW
WSW-26 0441-48-1127 Brian A. & Jaime S. Simmons 5208 Farmall Dr, Fayetteville, NC
28306
5208 Farmall Dr, Fayetteville, NC
28306 Potable No ~730 SW
WSW-27 0441-47-0950 Leon White; Sharon-Daniels White 5212 Farmall Dr, Fayetteville, NC
28306
5212 Farmall Dr, Fayetteville, NC
28306 Potable No ~1,050 SW
WSW-28 0441-37-9843 Thomas S. & Sally A. Yannotti 5 Hackberry Pl, Cameron, NC 28326 5216 Farmall Dr, Fayetteville, NC
28306 Potable No ~1,110 SW
WSW-29 0441-37-8714 Pedro J. Ortiz Feliciano; Denise M.
Ortiz Feliciano
5222 Farmall Dr, Fayetteville, NC
28306
5222 Farmall Dr, Fayetteville, NC
28306 Potable No ~1,150 SW
WSW-30 0441-37-6600 Christopher Waylon James & Tabitha
Marie James
5232 Farmall Dr, Fayetteville, NC
28306
5232 Farmall Dr, Fayetteville, NC
28306 Potable No ~1,360 SW
WSW-31 0441-47-1567 Terry L. Hulen Jr.; Khari R. Hulen 5211 Farmall Dr, Fayetteville, NC
28306
5211 Farmall Dr, Fayetteville, NC
28306 Potable No ~1,400 SW
WSW-32 0441-47-3644 John Glenn Briggs; Amanda Farrell III 5205 Farmall Dr, Fayetteville, NC
28306
5205 Farmall Dr, Fayetteville, NC
28306 Potable No ~1,380 SW
WSW-33 0441-38-8678 The Launer Properties, LLC 639 Adelaide Dr, Santa Monica, CA
90402 3151 Alderman Rd, Fayetteville, NC Potable No ~530 SW
WSW-34 0441-28-8457 Carter Lee Bryant 5220 Sunset View Rd, Fayetteville,
NC 28306
5220 Sunset View Rd, Fayetteville,
NC 28306 Potable No ~1,450 W
WSW-35 0441-28-7688 Willie & Bonnie J. Joyce 5219 Sunset View, Fayetteville, NC
28306
5219 Sunset View, Fayetteville, NC
28306 Potable No ~1,490 W
WSW-36 0441-37-9581 Scot G. & Jill H. Smith 5219 Farmall Dr, Fayetteville, NC
28306
5219 Farmall Dr, Fayetteville, NC
28306 Potable No ~1,460 NW
Page 2 of 2
Date: 06/28/2023
Parcel Number Owner Name Address
0441-48-2904
(Site)
0441-49-2092
0441-38-8678 The Launer Properties, LLC 639 Adelade Drive
Santa Monica, CA 90402
0441-38-7953 The Shondell Lloyd Revocable Living
Trust
6300 NC Highway 87 S
Fayetteville, NC 28306
Note:
• Properties are keyed to Figure 2.
TABLE 4
ADJACENT PROPERTY OWNER INFORMATION
GRAY'S CREEK SUPERETTE (INCIDENT NO. 13439)
Facility ID # : 00-0-0000011672
Post Office Box 807
St Pauls, NC 28384
Alhobishi Convenience Stores &
Rentals, Inc.
Page 1 of 1
Date: 06/16/2023
Well ID
Date
Installed
(m/dd/yy)
Date Water
Level
Measured
(m/dd/yy)
Well
Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(feet)
Free Product
Thickness
(ft.)
Ground
Water
Elevation (ft.)
Comments
10/28/20 9.63 ---90.37
05/25/21 10.39 ---89.61
12/07/21 14.26 ---85.74
09/14/22 Dry Dry Dry
06/05/23 Dry Dry Dry
10/28/20 8.61 ---91.45
05/25/21 9.82 ---90.24
12/07/21 13.74 ---86.32
09/14/22 Dry Dry Dry
06/05/23 13.49 ---86.57
06/16/20 6.91 ---92.58
10/28/20 9.16 ---90.33
05/25/21 9.92 ---89.57
12/07/21 14.17 ---85.32
09/14/22 Dry Dry Dry
06/05/23 Dry Dry Dry
05/25/21 10.69 ---89.62
12/07/21 14.53 ---85.78
09/14/22 Dry Dry Dry
06/05/23 Dry Dry Dry
05/25/21 10.24 ---89.68
12/07/21 14.38 ---85.54
09/14/22 Dry Dry Dry
06/05/23 Dry Dry Dry
05/25/21 11.60 ---88.12
12/07/21 14.01 ---85.71
09/14/22 16.31 ---83.41
06/05/23 14.22 ---85.50
05/25/21 6.46 ---93.78
12/07/21 7.38 ---92.86
09/14/22 5.11 ---95.13
06/05/23 5.41 ---94.83
05/25/21 10.20 ---89.61
12/07/21 14.29 ---85.52
09/14/22 Dry Dry Dry
06/05/23 Dry Dry Dry
05/25/21 10.40 ---89.56
12/07/21 14.56 ---85.40
09/14/22 14.94 ---85.02
06/05/23 Dry Dry Dry
Notes:
• NM : Not measured.
• Elevation relative to mean sea level.
TABLE 5
WELL CONSTRUCTION AND GAUGING INFORMATION
GRAY'S CREEK SUPERETTE (INCIDENT NO. 13439)
Facility ID # : 00-0-0000011672
• ft BGS : feet below ground surface.
100.24155-155
99.722010-2010
99.4920 5- 205
05/24/21
10/28/20MW-2R
10/28/20MW-1R
12/30/94MW-4
MW-9
05/24/21MW-8
05/24/21MW-7
05/25/21MW-12
05/25/21MW-11
05/24/21MW-10
100.06155 - 155
100.00155 - 155
99.92155-155
100.31155-155
99.96155-155
99.81155-155
Page 1 of 1
Well
ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 3 70 70 400 400
5,000 260,000 80,000 50,000 20,000 6,000 3,000 30,500 26,100 28,500 24,100
10/29/20 38.7 3,170 4,410 12,300 <6.3 1,560 NS NS NS NS NS
05/25/21 26.4 2,060 1,190 4,410 <6.3 372 <10 80.5 294 2,020 618
12/07/21 NS NS NS NS NS NS NS NS NS NS NS
09/14/22 NS NS NS NS NS NS NS NS NS NS NS
06/05/23 NS NS NS NS NS NS NS NS NS NS NS
10/29/20 <0.25 <0.25 26.4 44.1 <0.25 19.8 NS NS NS NS NS
05/25/21 <0.13 <0.13 35.3 56.8 <0.13 47.5 0.61 7.1 8.9 39.7 0.49 J
12/07/21 <0.13 0.30 J 0.37 J 0.13 J <0.13 3.5 1.8 0.91 0.61 0.15 J <0.13
09/14/22 NS NS NS NS NS NS NS NS NS NS NS
06/05/23 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.20 <0.13 <0.13 <0.13
06/16/20 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 NS NS NS NS NS
10/29/20 <0.13 0.14 J <0.13 <0.25 <0.13 <0.13 NS NS NS NS NS
05/25/21 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.20 <0.13 <0.13 <0.13 <0.13
12/07/21 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.20 <0.13 <0.13 <0.13 <0.13
09/14/22 NS NS NS NS NS NS NS NS NS NS NS
06/05/23 NS NS NS NS NS NS NS NS NS NS NS
05/25/21 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.20 <0.13 <0.13 <0.13 <0.13
12/07/21 NS NS NS NS NS NS NS NS NS NS NS
09/14/22 NS NS NS NS NS NS NS NS NS NS NS
06/05/23 NS NS NS NS NS NS NS NS NS NS NS
05/25/21 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 0.28 J <0.13 <0.13 <0.13 <0.13
12/07/21 <0.63 <0.63 <0.63 <1.26 <0.63 <0.63 <1.0 <0.63 <0.63 <0.63 <0.63
09/14/22 NS NS NS NS NS NS NS NS NS NS NS
06/05/23 NS NS NS NS NS NS NS NS NS NS NS
05/25/21 0.20 J <0.13 <0.13 <0.25 0.42 J <0.13 <0.20 <0.13 <0.13 <0.13 <0.13
12/07/21 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 3.4 <0.13 <0.13 <0.13 <0.13
09/14/22 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 2.8 B <0.13 <0.13 <0.13 <0.13
06/05/23 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 0.26 J <0.13 <0.13 <0.13
05/25/21 <0.25 <0.25 <0.25 <0.50 <0.25 0.65 J 0.76 J 2.4 3.6 0.43 J <0.25
12/07/21 <0.25 <0.25 <0.25 <0.50 <0.25 <0.25 <0.40 0.71 J 1.0 <0.25 <0.25
09/14/22 <0.13 <0.13 <0.13 <0.25 <0.13 0.50 2.8 B 0.35 J 0.40 J <0.13 <0.13
06/05/23 <0.13 <0.13 0.14 J <0.25 <0.13 0.32 J 0.19 J <0.20 0.19 J 0.27 J <0.13
MW-1R
MW-10
MW-9
MW-8
MW-7
MW-2R
MW-4
TABLE 6
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
GRAY'S CREEK SUPERETTE (INCIDENT NO. 13439)
Facility ID: 00-0-0000011672
MT
B
E
1,
3
,
5
-
Tr
i
m
e
t
h
y
l
b
e
n
z
e
n
e
1,
2
,
4
-
Tr
i
m
e
t
h
y
l
b
e
n
z
e
n
e
n-
P
r
o
p
y
l
b
e
n
z
e
n
e
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e
Date: 06/16/2023
Analytical Method
EPA Method 6200B
Me
t
h
y
l

c
h
l
o
r
i
d
e
(C
h
l
o
r
o
m
e
t
h
a
n
e
)
MACs (μg/l)
GCL (μg/l)
Na
p
h
t
h
a
l
e
n
e
Contaminant of Concern

Be
n
z
e
n
e
To
l
u
e
n
e
Et
h
y
l
b
e
n
z
e
n
e
Xy
l
e
n
e
s
Page 1 of 2
Well
ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 3 70 70 400 400
5,000 260,000 80,000 50,000 20,000 6,000 3,000 30,500 26,100 28,500 24,100
TABLE 6
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
GRAY'S CREEK SUPERETTE (INCIDENT NO. 13439)
Facility ID: 00-0-0000011672
MT
B
E
1,
3
,
5
-
Tr
i
m
e
t
h
y
l
b
e
n
z
e
n
e
1,
2
,
4
-
Tr
i
m
e
t
h
y
l
b
e
n
z
e
n
e
n-
P
r
o
p
y
l
b
e
n
z
e
n
e
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e
Date: 06/16/2023
Analytical Method
EPA Method 6200B
Me
t
h
y
l

c
h
l
o
r
i
d
e
(C
h
l
o
r
o
m
e
t
h
a
n
e
)
MACs (μg/l)
GCL (μg/l)
Na
p
h
t
h
a
l
e
n
e
Contaminant of Concern

Be
n
z
e
n
e
To
l
u
e
n
e
Et
h
y
l
b
e
n
z
e
n
e
Xy
l
e
n
e
s
05/25/21 7.5 14.4 1,050 1,247.9 <0.25 492 5.6 89.2 135 760 338
12/07/21 NS NS NS NS NS NS NS NS NS NS NS
09/14/22 NS NS NS NS NS NS NS NS NS NS NS
06/05/23 NS NS NS NS NS NS NS NS NS NS NS
05/25/21 0.49 J 1.8 60.4 23.47 J <0.31 13.3 1.5 16.9 23.1 24.2 11.5
12/07/21 0.61 1.7 41.6 32.21 <0.13 18.2 <0.20 10.7 6.0 26.3 2.2
09/14/22 NS NS NS NS NS NS NS NS NS NS NS
06/05/23 NS NS NS NS NS NS NS NS NS NS NS
WSW-1 06/05/23 <0.13 0.33 J <0.13 <0.25 <0.13 <0.13 <0.13 0.58 <0.13 <0.13 <0.13
WSW-11 06/05/23 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 0.35 J <0.13 <0.13 <0.13
12/07/21 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.20 <0.13 <0.13 <0.13 <0.13
09/14/22 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 3.3 B <0.13 <0.13 <0.13 <0.13
06/05/23 <0.13 9.0 <0.13 <0.25 <0.13 <0.13 <0.13 0.35 J <0.13 <0.13 <0.13
Notes:
Trip Blank
MW-11
MW-12
• Concentrations in bold face type exceeded the MACs .
• J: Estimated value.
• Results reported in µg/l (micrograms per liter)
• MAC: Maximum Allowable Concenration as specified in T15A NCAC 2L.0202.
• GCL: Gross contamination level.
• NE: Standard not established.
• < : Less than the method detection limit specified in the laboratory report.
Page 2 of 2
Well No.Sampled Date
(mm/dd/yy)
DO
(mg/L)Temp (oC)pH ORP
(mv)
Methane
(μg/L)
Nitrate
(μg/L)
Sulfate
(μg/L)
Ferrous Iron
(μg/L)
MW-2R 06/05/23 1.62 LV LV 195.6 0.41 J 250 12,600 <100
MW-9 06/05/23 1.95 18.48 4.21 253.1 <0.16 3,500 11,900 <100
MW-10 06/05/23 2.08 19.89 5.34 236.5 116 190 6,200 2,200
Notes:
• LV: Limited volume.
TABLE 6A
SUMMARY OF FIELD PARAMETER RESULTS
GRAY'S CREEK SUPERETTE (INCIDENT NO. 13439)
Date: 06/16/2023 Facility ID # : 00-0-0000011672
• NR: Not requested.
• FP: Free Product.
• Analyses for nitrate and sulfate by Method SW846/9056; analyses for methane by Method RSK 175; analyses for ferrous iron by EPA Method SM
3500 Fe-D. Field measurements of dissolved oxygen, temperature, pH and ORP were collected during sampling using a field meter.
• <: Less than the method detection limit specified in the laboratory report.
• J: Estimated concentration.

APPENDICES

APPENDIX A
State Correspondence

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FF:LOOLDP5HHQWKDO5,
5408 Received MAY 24 2023
5408 Received MAY 30 2023

APPENDIX B
CSA Cross Section Maps

APPENDIX C
Laboratory Report – Ground Water Samples

06/13/23
Technical Report for
GRI (Geological Resources Inc.)
Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
5408
SGS Job Number: FC6620
Sampling Date: 06/05/23
Report to:
GRI
3502 Hayes Rd
Monroe, NC 28110
[e-mail]; [e-mail];
[e-mail]
ATTN: William Regenthall
Total number of pages in report:
Certifications: FL(E83510), LA(03051), KS(E-10327), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AL, AK, AR, CT, IA, KY, MA, MI. MS, ND, NH, NV, OK, OR, IL, UT, VT, WA, WI, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc.  4405 Vineland Road  Suite C-15  Orlando, FL 32811  tel: [phone]  fax: [phone]
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Muna Mohammed 407-425-6700
Norm Farmer
Technical Director
Orlando, FL 06/13/23
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Automated Report
61
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FC6620
Table of Contents
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Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................6
3.1: FC6620-1: TRIP BLANK .............................................................................................7
3.2: FC6620-2: MW-2R .......................................................................................................9
3.3: FC6620-3: MW-9 ..........................................................................................................14
3.4: FC6620-4: MW-10 ........................................................................................................19
3.5: FC6620-5: WSW-11 .....................................................................................................24
3.6: FC6620-6: WSW-1 .......................................................................................................27
Section 4: Misc. Forms ............................................................................................................30
4.1: Chain of Custody ...........................................................................................................31
Section 5: MS Volatiles - QC Data Summaries .....................................................................33
5.1: Method Blank Summary ................................................................................................34
5.2: Blank Spike Summary ...................................................................................................40
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................46
Section 6: GC Volatiles - QC Data Summaries .....................................................................52
6.1: Method Blank Summary ................................................................................................53
6.2: Blank Spike/Blank Spike Duplicate Summary ..............................................................54
6.3: Matrix Spike Summary ..................................................................................................55
6.4: Duplicate Summary .......................................................................................................56
Section 7: General Chemistry - QC Data Summaries ..........................................................57
7.1: Method Blank and Spike Results Summary ..................................................................58
7.2: Duplicate Results Summary ..........................................................................................59
7.3: Matrix Spike Results Summary .....................................................................................60
7.4: Matrix Spike Duplicate Results Summary ....................................................................61
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Sample Summary
GRI (Geological Resources Inc.)
Job No:FC6620
Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Project No: 5408
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
This report contains results reported as ND = Not detected. The following applies:
Organics ND = Not detected above the MDL
FC6620-1 06/05/23 08:47 JB 06/06/23 AQ Trip Blank Water TRIP BLANK
FC6620-2 06/05/23 08:57 JB 06/06/23 AQ Ground Water MW-2R
FC6620-3 06/05/23 10:23 JB 06/06/23 AQ Ground Water MW-9
FC6620-4 06/05/23 10:51 JB 06/06/23 AQ Ground Water MW-10
FC6620-5 06/05/23 11:12 JB 06/06/23 AQ Ground Water WSW-11
FC6620-6 06/05/23 11:25 JB 06/06/23 AQ Ground Water WSW-1
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Summary of Hits Page 1 of 2
Job Number:FC6620
Account:GRI (Geological Resources Inc.)
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Collected:06/05/23
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FC6620-1 TRIP BLANK
Methyl Chloride 0.35 J 0.50 0.20 ug/l SM 6200B
Toluene 9.0 0.50 0.13 ug/l SM 6200B
FC6620-2 MW-2R
Ethyl Alcohol 274 100 65 ug/l SM 6200B
Methyl Bromide 0.60 0.50 0.20 ug/l SM 6200B
Methane 0.41 J 0.50 0.16 ug/l RSKSOP-147/175
Nitrogen, Nitrate 0.25 0.10 mg/l EPA 300/SW846 9056A
Sulfate 12.6 2.0 mg/l EPA 300/SW846 9056A
FC6620-3 MW-9
Methyl Chloride 0.26 J 0.50 0.20 ug/l SM 6200B
Nitrogen, Nitrate 3.5 0.10 mg/l EPA 300/SW846 9056A
Sulfate 11.9 2.0 mg/l EPA 300/SW846 9056A
FC6620-4 MW-10
sec-Butylbenzene 1.2 0.50 0.13 ug/l SM 6200B
tert-Butylbenzene 0.23 J 0.50 0.13 ug/l SM 6200B
Ethyl Alcohol 257 100 65 ug/l SM 6200B
Ethylbenzene 0.14 J 0.50 0.13 ug/l SM 6200B
Isopropylbenzene 0.19 J 0.50 0.13 ug/l SM 6200B
p-Isopropyltoluene 0.13 J 0.50 0.13 ug/l SM 6200B
Naphthalene 0.32 J 0.50 0.13 ug/l SM 6200B
n-Propylbenzene 0.19 J 0.50 0.13 ug/l SM 6200B
1,2,4-Trimethylbenzene 0.27 J 0.50 0.13 ug/l SM 6200B
Methane 116 0.50 0.16 ug/l RSKSOP-147/175
Iron, Ferrous a 2.2 0.50 mg/l SM3500FE B-11
Nitrogen, Nitrate 0.19 0.10 mg/l EPA 300/SW846 9056A
Sulfate 6.2 2.0 mg/l EPA 300/SW846 9056A
FC6620-5 WSW-11
Ethyl Alcohol 222 100 65 ug/l SM 6200B
Methyl Chloride 0.35 J 0.50 0.20 ug/l SM 6200B
FC6620-6 WSW-1
Ethyl Alcohol 162 100 65 ug/l SM 6200B
Methyl Bromide 0.48 J 0.50 0.20 ug/l SM 6200B
Methyl Chloride 0.58 0.50 0.20 ug/l SM 6200B
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Summary of Hits Page 2 of 2
Job Number:FC6620
Account:GRI (Geological Resources Inc.)
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Collected:06/05/23
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
Toluene 0.33 J 0.50 0.13 ug/l SM 6200B
(a) Field analysis required. Received out of hold time and analyzed by request.
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Sample Results
Report of Analysis
Orlando, FL
Section 3
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Report of Analysis Page 1 of 2
Client Sample ID:TRIP BLANK
Lab Sample ID:FC6620-1 Date Sampled:06/05/23
Matrix:AQ - Trip Blank Water Date Received:06/06/23
Method:SM 6200B Percent Solids:n/a
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A1492.D 1 06/09/23 14:03 TD n/a n/a V3A74
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane a ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 2
Client Sample ID:TRIP BLANK
Lab Sample ID:FC6620-1 Date Sampled:06/05/23
Matrix:AQ - Trip Blank Water Date Received:06/06/23
Method:SM 6200B Percent Solids:n/a
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride 0.35 0.50 0.20 ug/l J
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene 9.0 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 99%70-130%
17060-07-0 1,2-Dichloroethane-D4 109%70-130%
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 101%70-130%
(a) Associated ICV and BS outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 3
Client Sample ID:MW-2R
Lab Sample ID:FC6620-2 Date Sampled:06/05/23
Matrix:AQ - Ground Water Date Received:06/06/23
Method:SM 6200B Percent Solids:n/a
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A1491.D 1 06/09/23 13:39 TD n/a n/a V3A74
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane a ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 3
Client Sample ID:MW-2R
Lab Sample ID:FC6620-2 Date Sampled:06/05/23
Matrix:AQ - Ground Water Date Received:06/06/23
Method:SM 6200B Percent Solids:n/a
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
64-17-5 Ethyl Alcohol 274 100 65 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide 0.60 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND 10 2.0 ug/l
762-75-4 Tert-Butyl Formate b ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 101%70-130%
17060-07-0 1,2-Dichloroethane-D4 111%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 3 of 3
Client Sample ID:MW-2R
Lab Sample ID:FC6620-2 Date Sampled:06/05/23
Matrix:AQ - Ground Water Date Received:06/06/23
Method:SM 6200B Percent Solids:n/a
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 100%70-130%
(a) Associated ICV and BS outside control limits high, sample is ND.
(b) Associated BS recovery outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 1
Client Sample ID:MW-2R
Lab Sample ID:FC6620-2 Date Sampled:06/05/23
Matrix:AQ - Ground Water Date Received:06/06/23
Method:RSKSOP-147/175 Percent Solids:n/a
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LL82852.D 1 06/07/23 12:09 SS n/a n/a GLL2878
Run #2
Initial Volume Headspace Volume Volume Injected Temperature
Run #1 38.0 ml 5.0 ml 500 ul 21 Deg. C
Run #2
CAS No.Compound Result RL MDL Units Q
74-82-8 Methane 0.41 0.50 0.16 ug/l J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 1
Client Sample ID:MW-2R
Lab Sample ID:FC6620-2 Date Sampled:06/05/23
Matrix:AQ - Ground Water Date Received:06/06/23
Percent Solids:n/a
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
General Chemistry
Analyte Result RL Units DF Analyzed By Method
Iron, Ferrous a <0.10 0.10 mg/l 1 06/07/23 16:20 FN SM3500FE B-11
Nitrogen, Nitrate 0.25 0.10 mg/l 1 06/07/23 00:02 JB EPA 300/SW846 9056A
Sulfate 12.6 2.0 mg/l 1 06/07/23 00:02 JB EPA 300/SW846 9056A
(a) Field analysis required. Received out of hold time and analyzed by request.
RL = Reporting Limit
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Client Sample ID:MW-9
Lab Sample ID:FC6620-3 Date Sampled:06/05/23
Matrix:AQ - Ground Water Date Received:06/06/23
Method:SM 6200B Percent Solids:n/a
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A1464.D 1 06/08/23 11:48 TD n/a n/a V3A73
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane a ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 3
Client Sample ID:MW-9
Lab Sample ID:FC6620-3 Date Sampled:06/05/23
Matrix:AQ - Ground Water Date Received:06/06/23
Method:SM 6200B Percent Solids:n/a
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
64-17-5 Ethyl Alcohol ND 100 65 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride 0.26 0.50 0.20 ug/l J
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND 10 2.0 ug/l
762-75-4 Tert-Butyl Formate b ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 99%70-130%
17060-07-0 1,2-Dichloroethane-D4 107%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Client Sample ID:MW-9
Lab Sample ID:FC6620-3 Date Sampled:06/05/23
Matrix:AQ - Ground Water Date Received:06/06/23
Method:SM 6200B Percent Solids:n/a
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 100%70-130%
(a) Associated ICV and BS outside control limits high, sample is ND.
(b) Associated BS recovery outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Client Sample ID:MW-9
Lab Sample ID:FC6620-3 Date Sampled:06/05/23
Matrix:AQ - Ground Water Date Received:06/06/23
Method:RSKSOP-147/175 Percent Solids:n/a
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LL82853.D 1 06/07/23 12:17 SS n/a n/a GLL2878
Run #2
Initial Volume Headspace Volume Volume Injected Temperature
Run #1 38.0 ml 5.0 ml 500 ul 21 Deg. C
Run #2
CAS No.Compound Result RL MDL Units Q
74-82-8 Methane ND 0.50 0.16 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Client Sample ID:MW-9
Lab Sample ID:FC6620-3 Date Sampled:06/05/23
Matrix:AQ - Ground Water Date Received:06/06/23
Percent Solids:n/a
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
General Chemistry
Analyte Result RL Units DF Analyzed By Method
Iron, Ferrous a <0.10 0.10 mg/l 1 06/07/23 16:20 FN SM3500FE B-11
Nitrogen, Nitrate 3.5 0.10 mg/l 1 06/07/23 00:24 JB EPA 300/SW846 9056A
Sulfate 11.9 2.0 mg/l 1 06/07/23 00:24 JB EPA 300/SW846 9056A
(a) Field analysis required. Received out of hold time and analyzed by request.
RL = Reporting Limit
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Client Sample ID:MW-10
Lab Sample ID:FC6620-4 Date Sampled:06/05/23
Matrix:AQ - Ground Water Date Received:06/06/23
Method:SM 6200B Percent Solids:n/a
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A1465.D 1 06/08/23 12:12 TD n/a n/a V3A73
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene 1.2 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene 0.23 0.50 0.13 ug/l J
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane a ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Client Sample ID:MW-10
Lab Sample ID:FC6620-4 Date Sampled:06/05/23
Matrix:AQ - Ground Water Date Received:06/06/23
Method:SM 6200B Percent Solids:n/a
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
64-17-5 Ethyl Alcohol 257 100 65 ug/l
100-41-4 Ethylbenzene 0.14 0.50 0.13 ug/l J
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene 0.19 0.50 0.13 ug/l J
99-87-6 p-Isopropyltoluene 0.13 0.50 0.13 ug/l J
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene 0.32 0.50 0.13 ug/l J
103-65-1 n-Propylbenzene 0.19 0.50 0.13 ug/l J
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND 10 2.0 ug/l
762-75-4 Tert-Butyl Formate b ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene 0.27 0.50 0.13 ug/l J
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 98%70-130%
17060-07-0 1,2-Dichloroethane-D4 105%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Client Sample ID:MW-10
Lab Sample ID:FC6620-4 Date Sampled:06/05/23
Matrix:AQ - Ground Water Date Received:06/06/23
Method:SM 6200B Percent Solids:n/a
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
2037-26-5 Toluene-D8 102%70-130%
460-00-4 4-Bromofluorobenzene 102%70-130%
(a) Associated ICV and BS outside control limits high, sample is ND.
(b) Associated BS recovery outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 1
Client Sample ID:MW-10
Lab Sample ID:FC6620-4 Date Sampled:06/05/23
Matrix:AQ - Ground Water Date Received:06/06/23
Method:RSKSOP-147/175 Percent Solids:n/a
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LL82854.D 1 06/07/23 12:25 SS n/a n/a GLL2878
Run #2
Initial Volume Headspace Volume Volume Injected Temperature
Run #1 38.0 ml 5.0 ml 500 ul 21 Deg. C
Run #2
CAS No.Compound Result RL MDL Units Q
74-82-8 Methane 116 0.50 0.16 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Client Sample ID:MW-10
Lab Sample ID:FC6620-4 Date Sampled:06/05/23
Matrix:AQ - Ground Water Date Received:06/06/23
Percent Solids:n/a
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
General Chemistry
Analyte Result RL Units DF Analyzed By Method
Iron, Ferrous a 2.2 0.50 mg/l 5 06/07/23 16:20 FN SM3500FE B-11
Nitrogen, Nitrate 0.19 0.10 mg/l 1 06/07/23 00:46 JB EPA 300/SW846 9056A
Sulfate 6.2 2.0 mg/l 1 06/07/23 00:46 JB EPA 300/SW846 9056A
(a) Field analysis required. Received out of hold time and analyzed by request.
RL = Reporting Limit
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Client Sample ID:WSW-11
Lab Sample ID:FC6620-5 Date Sampled:06/05/23
Matrix:AQ - Ground Water Date Received:06/06/23
Method:SM 6200B Percent Solids:n/a
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A1466.D 1 06/08/23 12:36 TD n/a n/a V3A73
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane a ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Client Sample ID:WSW-11
Lab Sample ID:FC6620-5 Date Sampled:06/05/23
Matrix:AQ - Ground Water Date Received:06/06/23
Method:SM 6200B Percent Solids:n/a
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
64-17-5 Ethyl Alcohol 222 100 65 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride 0.35 0.50 0.20 ug/l J
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND 10 2.0 ug/l
762-75-4 Tert-Butyl Formate b ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 97%70-130%
17060-07-0 1,2-Dichloroethane-D4 105%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Client Sample ID:WSW-11
Lab Sample ID:FC6620-5 Date Sampled:06/05/23
Matrix:AQ - Ground Water Date Received:06/06/23
Method:SM 6200B Percent Solids:n/a
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 101%70-130%
(a) Associated ICV and BS outside control limits high, sample is ND.
(b) Associated BS recovery outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Client Sample ID:WSW-1
Lab Sample ID:FC6620-6 Date Sampled:06/05/23
Matrix:AQ - Ground Water Date Received:06/06/23
Method:SM 6200B Percent Solids:n/a
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A1485.D 1 06/09/23 11:14 TD n/a n/a V3A74
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane a ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Client Sample ID:WSW-1
Lab Sample ID:FC6620-6 Date Sampled:06/05/23
Matrix:AQ - Ground Water Date Received:06/06/23
Method:SM 6200B Percent Solids:n/a
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
64-17-5 Ethyl Alcohol 162 100 65 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide 0.48 0.50 0.20 ug/l J
74-87-3 Methyl Chloride 0.58 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND 10 2.0 ug/l
762-75-4 Tert-Butyl Formate b ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene 0.33 0.50 0.13 ug/l J
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 99%70-130%
17060-07-0 1,2-Dichloroethane-D4 108%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Client Sample ID:WSW-1
Lab Sample ID:FC6620-6 Date Sampled:06/05/23
Matrix:AQ - Ground Water Date Received:06/06/23
Method:SM 6200B Percent Solids:n/a
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 101%70-130%
(a) Associated ICV and BS outside control limits high, sample is ND.
(b) Associated BS recovery outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
 Chain of Custody
Orlando, FL
Section 4
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FC6620: Chain of Custody
Page 1 of 2
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Job Number:FC6620 Client:GRI
Date / Time Received:6/6/2023 9:30:00 AM Delivery Method:FED EX
Project:5408
Airbill #'s:5707 9050 6889
Cooler Information
1. Custody Seals Present
2. Custody Seals Intact
4. Cooler temp verification
3. Temp criteria achieved
5. Cooler media
IR Gun
Ice (Bag)
Trip Blank Information
1. Trip Blank present / cooler
2. Trip Blank listed on COC
2. Samples preserved properly
Sample Information
1. Sample labels present on bottles
5. Sample recvd within HT
4. Condition of sample
3. Sufficient volume/containers recvd for analysis:
Intact
Comments
SM001Rev. Date 05/24/17
SGS Sample Receipt Summary
Cooler Temps (Raw Measured) °C:
Cooler Temps (Corrected) °C:
Cooler 1: (2.1);
Cooler 1: (2.0);
3. Type Of TB Received
W or S N/A
6. Dates/Times/IDs on COC match Sample Label
7. VOCs have headspace
8. Bottles received for unspecified tests
9. Compositing instructions clear
10. Voa Soil Kits/Jars received past 48hrs?
11. % Solids Jar received?
Misc. Information
25-Gram 5-GramNumber of Encores:Number of 5035 Field Kits:Number of Lab Filtered Metals:
Test Strip Lot #s:pH 0-3 230320 pH 10-12 Other: (Specify)pH 1.0 - 12.0 222221
Y or N N/A
Y or N
Therm ID:IR 1; Therm CF:-0.1; # of Coolers:1
Y or N N/A
12. Residual Chlorine Present?
Residual Chlorine Test Strip Lot #:
Technician:Reviewer:SHAYLAP Date:Date:6/6/2023 9:30:00 AM
FC6620: Chain of Custody
Page 2 of 2
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MS Volatiles
QC Data Summaries
Includes the following where applicable:
 Method Blank Summaries
 Blank Spike Summaries
 Matrix Spike and Duplicate Summaries
Orlando, FL
Section 5
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Method Blank Summary Page 1 of 3
Job Number:FC6620
Account:GRINCC GRI (Geological Resources Inc.)
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A73-MB 3A1462.D 1 06/08/23 TD n/a n/a V3A73
The QC reported here applies to the following samples:Method: SM 6200B
FC6620-3, FC6620-4, FC6620-5
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
64-17-5 Ethyl Alcohol ND 100 65 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
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Job Number:FC6620
Account:GRINCC GRI (Geological Resources Inc.)
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A73-MB 3A1462.D 1 06/08/23 TD n/a n/a V3A73
The QC reported here applies to the following samples:Method: SM 6200B
FC6620-3, FC6620-4, FC6620-5
CAS No.Compound Result RL MDL Units Q
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide 0.67 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND 10 2.0 ug/l
762-75-4 Tert-Butyl Formate ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 99%70-130%
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Job Number:FC6620
Account:GRINCC GRI (Geological Resources Inc.)
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A73-MB 3A1462.D 1 06/08/23 TD n/a n/a V3A73
The QC reported here applies to the following samples:Method: SM 6200B
FC6620-3, FC6620-4, FC6620-5
CAS No.Surrogate Recoveries Limits
17060-07-0 1,2-Dichloroethane-D4 106%70-130%
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 100%70-130%
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Job Number:FC6620
Account:GRINCC GRI (Geological Resources Inc.)
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A74-MB 3A1484.D 1 06/09/23 TD n/a n/a V3A74
The QC reported here applies to the following samples:Method: SM 6200B
FC6620-1, FC6620-2, FC6620-6
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
64-17-5 Ethyl Alcohol ND 100 65 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
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Method Blank Summary Page 2 of 3
Job Number:FC6620
Account:GRINCC GRI (Geological Resources Inc.)
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A74-MB 3A1484.D 1 06/09/23 TD n/a n/a V3A74
The QC reported here applies to the following samples:Method: SM 6200B
FC6620-1, FC6620-2, FC6620-6
CAS No.Compound Result RL MDL Units Q
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND 10 2.0 ug/l
762-75-4 Tert-Butyl Formate ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 98%70-130%
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Job Number:FC6620
Account:GRINCC GRI (Geological Resources Inc.)
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A74-MB 3A1484.D 1 06/09/23 TD n/a n/a V3A74
The QC reported here applies to the following samples:Method: SM 6200B
FC6620-1, FC6620-2, FC6620-6
CAS No.Surrogate Recoveries Limits
17060-07-0 1,2-Dichloroethane-D4 108%70-130%
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 100%70-130%
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Blank Spike Summary Page 1 of 3
Job Number:FC6620
Account:GRINCC GRI (Geological Resources Inc.)
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A73-BS 3A1460.D 1 06/08/23 TD n/a n/a V3A73
The QC reported here applies to the following samples:Method: SM 6200B
FC6620-3, FC6620-4, FC6620-5
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 10.5 105 70-130
108-86-1 Bromobenzene 10 11.1 111 70-130
74-97-5 Bromochloromethane 10 10.4 104 70-130
75-27-4 Bromodichloromethane 10 10.1 101 70-130
75-25-2 Bromoform 10 9.2 92 70-130
104-51-8 n-Butylbenzene 10 10.5 105 70-130
135-98-8 sec-Butylbenzene 10 9.8 98 70-130
98-06-6 tert-Butylbenzene 10 9.9 99 70-130
56-23-5 Carbon Tetrachloride 10 10.6 106 70-130
108-90-7 Chlorobenzene 10 10.4 104 70-130
75-00-3 Chloroethane 10 11.5 115 60-140
67-66-3 Chloroform 10 10.4 104 70-130
95-49-8 o-Chlorotoluene 10 11.0 110 70-130
106-43-4 p-Chlorotoluene 10 11.1 111 70-130
124-48-1 Dibromochloromethane 10 9.8 98 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 9.7 97 70-130
106-93-4 1,2-Dibromoethane 10 9.3 93 70-130
75-71-8 Dichlorodifluoromethane 10 14.9 149*60-140
95-50-1 1,2-Dichlorobenzene 10 10.7 107 70-130
541-73-1 1,3-Dichlorobenzene 10 10.6 106 70-130
106-46-7 1,4-Dichlorobenzene 10 10.4 104 70-130
75-34-3 1,1-Dichloroethane 10 10 100 70-130
107-06-2 1,2-Dichloroethane 10 10.2 102 70-130
75-35-4 1,1-Dichloroethylene 10 10.3 103 70-130
156-59-2 cis-1,2-Dichloroethylene 10 10.2 102 70-130
156-60-5 trans-1,2-Dichloroethylene 10 10.4 104 70-130
78-87-5 1,2-Dichloropropane 10 10.8 108 70-130
142-28-9 1,3-Dichloropropane 10 11.2 112 70-130
594-20-7 2,2-Dichloropropane 10 11.3 113 70-130
563-58-6 1,1-Dichloropropene 10 11.0 110 70-130
10061-01-5 cis-1,3-Dichloropropene 10 9.9 99 70-130
10061-02-6 trans-1,3-Dichloropropene 10 9.2 92 70-130
108-20-3 Di-Isopropyl Ether 10 10.5 105 70-130
64-17-5 Ethyl Alcohol 500 381 76 70-130
100-41-4 Ethylbenzene 10 10.6 106 70-130
637-92-3 Ethyl Tert Butyl Ether 10 9.6 96 70-130
* = Outside of Control Limits.
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Job Number:FC6620
Account:GRINCC GRI (Geological Resources Inc.)
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A73-BS 3A1460.D 1 06/08/23 TD n/a n/a V3A73
The QC reported here applies to the following samples:Method: SM 6200B
FC6620-3, FC6620-4, FC6620-5
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
87-68-3 Hexachlorobutadiene 10 11.3 113 70-130
98-82-8 Isopropylbenzene 10 10.1 101 70-130
99-87-6 p-Isopropyltoluene 10 10 100 70-130
74-83-9 Methyl Bromide 10 11.2 112 60-140
74-87-3 Methyl Chloride 10 12.3 123 60-140
74-95-3 Methylene Bromide 10 10.2 102 70-130
75-09-2 Methylene Chloride 10 10.4 104 70-130
1634-04-4 Methyl Tert Butyl Ether 10 10.9 109 70-130
91-20-3 Naphthalene 10 9.8 98 70-130
103-65-1 n-Propylbenzene 10 10 100 70-130
100-42-5 Styrene 10 9.7 97 70-130
75-85-4 Tert-Amyl Alcohol 100 85.4 85 70-130
994-05-8 Tert-Amyl Methyl Ether 10 9.4 94 70-130
75-65-0 Tert-Butyl Alcohol 100 102 102 70-130
762-75-4 Tert-Butyl Formate 50 85.0 170*70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 9.5 95 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 10.4 104 70-130
127-18-4 Tetrachloroethylene 10 10.6 106 70-130
108-88-3 Toluene 10 10.6 106 70-130
87-61-6 1,2,3-Trichlorobenzene 10 11.1 111 70-130
120-82-1 1,2,4-Trichlorobenzene 10 9.6 96 70-130
71-55-6 1,1,1-Trichloroethane 10 10.4 104 70-130
79-00-5 1,1,2-Trichloroethane 10 10.5 105 70-130
79-01-6 Trichloroethylene 10 10.4 104 70-130
75-69-4 Trichlorofluoromethane 10 10 100 60-140
96-18-4 1,2,3-Trichloropropane 10 11.0 110 70-130
95-63-6 1,2,4-Trimethylbenzene 10 10.5 105 70-130
108-67-8 1,3,5-Trimethylbenzene 10 10.4 104 70-130
75-01-4 Vinyl Chloride 10 12.5 125 60-140
m,p-Xylene 20 22.3 112 70-130
95-47-6 o-Xylene 10 9.5 95 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 95%70-130%
* = Outside of Control Limits.
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Blank Spike Summary Page 3 of 3
Job Number:FC6620
Account:GRINCC GRI (Geological Resources Inc.)
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A73-BS 3A1460.D 1 06/08/23 TD n/a n/a V3A73
The QC reported here applies to the following samples:Method: SM 6200B
FC6620-3, FC6620-4, FC6620-5
CAS No.Surrogate Recoveries BSP Limits
17060-07-0 1,2-Dichloroethane-D4 100%70-130%
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 102%70-130%
* = Outside of Control Limits.
42 of 61
FC6620
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5.
2
.
1
Blank Spike Summary Page 1 of 3
Job Number:FC6620
Account:GRINCC GRI (Geological Resources Inc.)
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A74-BS 3A1482.D 1 06/09/23 TD n/a n/a V3A74
The QC reported here applies to the following samples:Method: SM 6200B
FC6620-1, FC6620-2, FC6620-6
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 10.0 100 70-130
108-86-1 Bromobenzene 10 10.6 106 70-130
74-97-5 Bromochloromethane 10 10.0 100 70-130
75-27-4 Bromodichloromethane 10 9.8 98 70-130
75-25-2 Bromoform 10 9.0 90 70-130
104-51-8 n-Butylbenzene 10 9.6 96 70-130
135-98-8 sec-Butylbenzene 10 9.0 90 70-130
98-06-6 tert-Butylbenzene 10 9.1 91 70-130
56-23-5 Carbon Tetrachloride 10 10.0 100 70-130
108-90-7 Chlorobenzene 10 10 100 70-130
75-00-3 Chloroethane 10 11.7 117 60-140
67-66-3 Chloroform 10 10.1 101 70-130
95-49-8 o-Chlorotoluene 10 10.4 104 70-130
106-43-4 p-Chlorotoluene 10 10.4 104 70-130
124-48-1 Dibromochloromethane 10 9.5 95 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 9.2 92 70-130
106-93-4 1,2-Dibromoethane 10 9.3 93 70-130
75-71-8 Dichlorodifluoromethane 10 14.5 145*60-140
95-50-1 1,2-Dichlorobenzene 10 10.2 102 70-130
541-73-1 1,3-Dichlorobenzene 10 10.0 100 70-130
106-46-7 1,4-Dichlorobenzene 10 9.9 99 70-130
75-34-3 1,1-Dichloroethane 10 9.6 96 70-130
107-06-2 1,2-Dichloroethane 10 10.2 102 70-130
75-35-4 1,1-Dichloroethylene 10 9.8 98 70-130
156-59-2 cis-1,2-Dichloroethylene 10 10.1 101 70-130
156-60-5 trans-1,2-Dichloroethylene 10 10.1 101 70-130
78-87-5 1,2-Dichloropropane 10 10.5 105 70-130
142-28-9 1,3-Dichloropropane 10 11.1 111 70-130
594-20-7 2,2-Dichloropropane 10 10.6 106 70-130
563-58-6 1,1-Dichloropropene 10 10.4 104 70-130
10061-01-5 cis-1,3-Dichloropropene 10 9.6 96 70-130
10061-02-6 trans-1,3-Dichloropropene 10 9.0 90 70-130
108-20-3 Di-Isopropyl Ether 10 10.3 103 70-130
64-17-5 Ethyl Alcohol 500 382 76 70-130
100-41-4 Ethylbenzene 10 10 100 70-130
637-92-3 Ethyl Tert Butyl Ether 10 9.4 94 70-130
* = Outside of Control Limits.
43 of 61
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2
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Blank Spike Summary Page 2 of 3
Job Number:FC6620
Account:GRINCC GRI (Geological Resources Inc.)
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A74-BS 3A1482.D 1 06/09/23 TD n/a n/a V3A74
The QC reported here applies to the following samples:Method: SM 6200B
FC6620-1, FC6620-2, FC6620-6
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
87-68-3 Hexachlorobutadiene 10 10.1 101 70-130
98-82-8 Isopropylbenzene 10 9.5 95 70-130
99-87-6 p-Isopropyltoluene 10 9.2 92 70-130
74-83-9 Methyl Bromide 10 11.2 112 60-140
74-87-3 Methyl Chloride 10 12.3 123 60-140
74-95-3 Methylene Bromide 10 10.2 102 70-130
75-09-2 Methylene Chloride 10 10.6 106 70-130
1634-04-4 Methyl Tert Butyl Ether 10 10.7 107 70-130
91-20-3 Naphthalene 10 9.4 94 70-130
103-65-1 n-Propylbenzene 10 9.2 92 70-130
100-42-5 Styrene 10 9.4 94 70-130
75-85-4 Tert-Amyl Alcohol 100 78.3 78 70-130
994-05-8 Tert-Amyl Methyl Ether 10 9.0 90 70-130
75-65-0 Tert-Butyl Alcohol 100 95.7 96 70-130
762-75-4 Tert-Butyl Formate 50 82.4 165*70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 9.0 90 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 9.9 99 70-130
127-18-4 Tetrachloroethylene 10 9.9 99 70-130
108-88-3 Toluene 10 10.1 101 70-130
87-61-6 1,2,3-Trichlorobenzene 10 10.5 105 70-130
120-82-1 1,2,4-Trichlorobenzene 10 9.0 90 70-130
71-55-6 1,1,1-Trichloroethane 10 9.9 99 70-130
79-00-5 1,1,2-Trichloroethane 10 10.4 104 70-130
79-01-6 Trichloroethylene 10 9.9 99 70-130
75-69-4 Trichlorofluoromethane 10 10.1 101 60-140
96-18-4 1,2,3-Trichloropropane 10 10.4 104 70-130
95-63-6 1,2,4-Trimethylbenzene 10 9.7 97 70-130
108-67-8 1,3,5-Trimethylbenzene 10 9.7 97 70-130
75-01-4 Vinyl Chloride 10 12.2 122 60-140
m,p-Xylene 20 21.2 106 70-130
95-47-6 o-Xylene 10 9.2 92 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 96%70-130%
* = Outside of Control Limits.
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Blank Spike Summary Page 3 of 3
Job Number:FC6620
Account:GRINCC GRI (Geological Resources Inc.)
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A74-BS 3A1482.D 1 06/09/23 TD n/a n/a V3A74
The QC reported here applies to the following samples:Method: SM 6200B
FC6620-1, FC6620-2, FC6620-6
CAS No.Surrogate Recoveries BSP Limits
17060-07-0 1,2-Dichloroethane-D4 103%70-130%
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 100%70-130%
* = Outside of Control Limits.
45 of 61
FC6620
5
5.
2
.
2
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 3
Job Number:FC6620
Account:GRINCC GRI (Geological Resources Inc.)
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC6620-2MS 3A1476.D 5 06/08/23 TD n/a n/a V3A73
FC6620-2MSD 3A1477.D 5 06/08/23 TD n/a n/a V3A73
The QC reported here applies to the following samples:Method: SM 6200B
FC6620-3, FC6620-4, FC6620-5
Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 50 51.3 103 50 51.8 104 1 70-130/20
108-86-1 Bromobenzene 50 52.6 105 50 53.7 107 2 70-130/20
74-97-5 Bromochloromethane 50 48.7 97 50 49.6 99 2 70-130/20
75-27-4 Bromodichloromethane 50 45.9 92 50 47.3 95 3 70-130/20
75-25-2 Bromoform 50 39.8 80 50 41.8 84 5 70-130/20
104-51-8 n-Butylbenzene 50 47.4 95 50 49.6 99 5 70-130/20
135-98-8 sec-Butylbenzene 50 45.8 92 50 47.2 94 3 70-130/20
98-06-6 tert-Butylbenzene 50 46.1 92 50 47.7 95 3 70-130/20
56-23-5 Carbon Tetrachloride 50 49.9 100 50 51.9 104 4 70-130/20
108-90-7 Chlorobenzene 50 49.2 98 50 50.1 100 2 70-130/20
75-00-3 Chloroethane 50 44.4 89 50 55.2 110 22*60-140/20
67-66-3 Chloroform 50 50.2 100 50 51.3 103 2 70-130/20
95-49-8 o-Chlorotoluene 50 51.8 104 50 53.5 107 3 70-130/20
106-43-4 p-Chlorotoluene 50 51.7 103 50 52.9 106 2 70-130/20
124-48-1 Dibromochloromethane 50 43.4 87 50 44.7 89 3 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane 50 41.8 84 50 43.3 87 4 70-130/20
106-93-4 1,2-Dibromoethane 50 43.3 87 50 44.3 89 2 70-130/20
75-71-8 Dichlorodifluoromethane 50 63.5 127 50 75.0 150*17 60-140/20
95-50-1 1,2-Dichlorobenzene 50 49.5 99 50 51.3 103 4 70-130/20
541-73-1 1,3-Dichlorobenzene 50 49.8 100 50 50.8 102 2 70-130/20
106-46-7 1,4-Dichlorobenzene 50 49.2 98 50 50.0 100 2 70-130/20
75-34-3 1,1-Dichloroethane 50 48.4 97 50 48.9 98 1 70-130/20
107-06-2 1,2-Dichloroethane 50 49.5 99 50 50.4 101 2 70-130/20
75-35-4 1,1-Dichloroethylene 50 51.4 103 50 52.4 105 2 70-130/20
156-59-2 cis-1,2-Dichloroethylene 50 49.8 100 50 50.6 101 2 70-130/20
156-60-5 trans-1,2-Dichloroethylene 50 50.8 102 50 52.0 104 2 70-130/20
78-87-5 1,2-Dichloropropane 50 52.1 104 50 52.5 105 1 70-130/20
142-28-9 1,3-Dichloropropane 50 52.8 106 50 53.4 107 1 70-130/20
594-20-7 2,2-Dichloropropane 50 53.7 107 50 54.3 109 1 70-130/20
563-58-6 1,1-Dichloropropene 50 53.9 108 50 55.4 111 3 70-130/20
10061-01-5 cis-1,3-Dichloropropene 50 43.6 87 50 44.8 90 3 70-130/20
10061-02-6 trans-1,3-Dichloropropene 50 41.7 83 50 43.0 86 3 70-130/20
108-20-3 Di-Isopropyl Ether 50 50.0 100 50 50.9 102 2 70-130/20
64-17-5 Ethyl Alcohol 2500 3080 111 2500 2790 99 10 70-130/20
100-41-4 Ethylbenzene 50 51.3 103 50 51.9 104 1 70-130/20
637-92-3 Ethyl Tert Butyl Ether 50 44.9 90 50 45.7 91 2 70-130/20
* = Outside of Control Limits.
46 of 61
FC6620
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5.
3
.
1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 3
Job Number:FC6620
Account:GRINCC GRI (Geological Resources Inc.)
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC6620-2MS 3A1476.D 5 06/08/23 TD n/a n/a V3A73
FC6620-2MSD 3A1477.D 5 06/08/23 TD n/a n/a V3A73
The QC reported here applies to the following samples:Method: SM 6200B
FC6620-3, FC6620-4, FC6620-5
Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
87-68-3 Hexachlorobutadiene 50 49.3 99 50 51.5 103 4 70-130/20
98-82-8 Isopropylbenzene 50 47.7 95 50 48.7 97 2 70-130/20
99-87-6 p-Isopropyltoluene 50 46.3 93 50 47.8 96 3 70-130/20
74-83-9 Methyl Bromide 50 40.0 79 50 48.6 96 19 60-140/20
74-87-3 Methyl Chloride 50 50.1 100 50 60.6 121 19 60-140/20
74-95-3 Methylene Bromide 50 48.0 96 50 48.9 98 2 70-130/20
75-09-2 Methylene Chloride 50 54.8 110 50 55.3 111 1 70-130/20
1634-04-4 Methyl Tert Butyl Ether 50 51.9 104 50 52.0 104 0 70-130/20
91-20-3 Naphthalene 50 42.9 86 50 44.4 89 3 70-130/20
103-65-1 n-Propylbenzene 50 47.2 94 50 48.6 97 3 70-130/20
100-42-5 Styrene 50 44.9 90 50 46.7 93 4 70-130/20
75-85-4 Tert-Amyl Alcohol 500 371 74 500 392 78 6 70-130/20
994-05-8 Tert-Amyl Methyl Ether 50 43.1 86 50 43.9 88 2 70-130/20
75-65-0 Tert-Butyl Alcohol 500 491 98 500 537 107 9 70-130/20
762-75-4 Tert-Butyl Formate 250 346 138*250 376 150*8 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane 50 42.7 85 50 44.5 89 4 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane 50 48.5 97 50 49.8 100 3 70-130/20
127-18-4 Tetrachloroethylene 50 51.2 102 50 52.9 106 3 70-130/20
108-88-3 Toluene 50 51.3 103 50 52.1 104 2 70-130/20
87-61-6 1,2,3-Trichlorobenzene 50 48.4 97 50 50.2 100 4 70-130/20
120-82-1 1,2,4-Trichlorobenzene 50 42.0 84 50 44.3 89 5 70-130/20
71-55-6 1,1,1-Trichloroethane 50 50.6 101 50 52.4 105 3 70-130/20
79-00-5 1,1,2-Trichloroethane 50 48.8 98 50 50.3 101 3 70-130/20
79-01-6 Trichloroethylene 50 49.6 99 50 50.9 102 3 70-130/20
75-69-4 Trichlorofluoromethane 50 39.3 79 50 48.2 96 20 60-140/20
96-18-4 1,2,3-Trichloropropane 50 50.9 102 50 52.6 105 3 70-130/20
95-63-6 1,2,4-Trimethylbenzene 50 49.4 99 50 50.1 100 1 70-130/20
108-67-8 1,3,5-Trimethylbenzene 50 48.9 98 50 50.8 102 4 70-130/20
75-01-4 Vinyl Chloride 50 50.5 101 50 60.0 120 17 60-140/20
m,p-Xylene 100 108 108 100 110 110 2 70-130/20
95-47-6 o-Xylene 50 45.1 90 50 46.4 93 3 70-130/20
CAS No.Surrogate Recoveries MS MSD Limits
1868-53-7 Dibromofluoromethane 95%96%70-130%
* = Outside of Control Limits.
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3
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Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number:FC6620
Account:GRINCC GRI (Geological Resources Inc.)
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC6620-2MS 3A1476.D 5 06/08/23 TD n/a n/a V3A73
FC6620-2MSD 3A1477.D 5 06/08/23 TD n/a n/a V3A73
The QC reported here applies to the following samples:Method: SM 6200B
FC6620-3, FC6620-4, FC6620-5
CAS No.Surrogate Recoveries MS MSD Limits
17060-07-0 1,2-Dichloroethane-D4 103%102%70-130%
2037-26-5 Toluene-D8 99%101%70-130%
460-00-4 4-Bromofluorobenzene 100%101%70-130%
* = Outside of Control Limits.
48 of 61
FC6620
5
5.
3
.
1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 3
Job Number:FC6620
Account:GRINCC GRI (Geological Resources Inc.)
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC6678-7MS 3A1495.D 200 06/09/23 TD n/a n/a V3A74
FC6678-7MSD 3A1496.D 200 06/09/23 TD n/a n/a V3A74
FC6678-7 3A1489.D 100 06/09/23 TD n/a n/a V3A74
FC6678-7 3A1494.D 200 06/09/23 TD n/a n/a V3A74
The QC reported here applies to the following samples:Method: SM 6200B
FC6620-1, FC6620-2, FC6620-6
FC6678-7 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 2200 2000 3880 84 2000 3910 86 1 70-130/20
108-86-1 Bromobenzene ND 2000 2210 111 2000 2150 108 3 70-130/20
74-97-5 Bromochloromethane ND 2000 1980 99 2000 1990 100 1 70-130/20
75-27-4 Bromodichloromethane ND 2000 1880 94 2000 1890 95 1 70-130/20
75-25-2 Bromoform ND 2000 1660 83 2000 1640 82 1 70-130/20
104-51-8 n-Butylbenzene ND 2000 1990 100 2000 2010 101 1 70-130/20
135-98-8 sec-Butylbenzene ND 2000 1880 94 2000 1890 95 1 70-130/20
98-06-6 tert-Butylbenzene ND 2000 1930 97 2000 1930 97 0 70-130/20
56-23-5 Carbon Tetrachloride ND 2000 2050 103 2000 2070 104 1 70-130/20
108-90-7 Chlorobenzene ND 2000 2000 100 2000 2020 101 1 70-130/20
75-00-3 Chloroethane ND 2000 1910 96 2000 2170 109 13 60-140/20
67-66-3 Chloroform ND 2000 2050 103 2000 2040 102 0 70-130/20
95-49-8 o-Chlorotoluene ND 2000 2190 110 2000 2190 110 0 70-130/20
106-43-4 p-Chlorotoluene ND 2000 2150 108 2000 2140 107 0 70-130/20
124-48-1 Dibromochloromethane ND 2000 1790 90 2000 1790 90 0 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 2000 1780 89 2000 1690 85 5 70-130/20
106-93-4 1,2-Dibromoethane ND 2000 1800 90 2000 1760 88 2 70-130/20
75-71-8 Dichlorodifluoromethane ND 2000 2260 113 2000 2570 129 13 60-140/20
95-50-1 1,2-Dichlorobenzene ND 2000 2050 103 2000 2020 101 1 70-130/20
541-73-1 1,3-Dichlorobenzene ND 2000 2040 102 2000 2020 101 1 70-130/20
106-46-7 1,4-Dichlorobenzene ND 2000 2020 101 2000 1990 100 1 70-130/20
75-34-3 1,1-Dichloroethane ND 2000 1980 99 2000 1980 99 0 70-130/20
107-06-2 1,2-Dichloroethane ND 2000 2000 100 2000 1970 99 2 70-130/20
75-35-4 1,1-Dichloroethylene ND 2000 2080 104 2000 2100 105 1 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 2000 1970 99 2000 2030 102 3 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 2000 2080 104 2000 2100 105 1 70-130/20
78-87-5 1,2-Dichloropropane ND 2000 2170 109 2000 2120 106 2 70-130/20
142-28-9 1,3-Dichloropropane ND 2000 2210 111 2000 2180 109 1 70-130/20
594-20-7 2,2-Dichloropropane ND 2000 2200 110 2000 2220 111 1 70-130/20
563-58-6 1,1-Dichloropropene ND 2000 2200 110 2000 2210 111 0 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 2000 1900 95 2000 1880 94 1 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 2000 1760 88 2000 1770 89 1 70-130/20
108-20-3 Di-Isopropyl Ether ND 2000 2080 104 2000 2060 103 1 70-130/20
64-17-5 Ethyl Alcohol ND 100000 96800 97 100000 89300 89 8 70-130/20
100-41-4 Ethylbenzene 990 2000 2910 96 2000 2920 97 0 70-130/20
637-92-3 Ethyl Tert Butyl Ether ND 2000 1880 94 2000 1860 93 1 70-130/20
* = Outside of Control Limits.
49 of 61
FC6620
5
5.
3
.
2
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 3
Job Number:FC6620
Account:GRINCC GRI (Geological Resources Inc.)
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC6678-7MS 3A1495.D 200 06/09/23 TD n/a n/a V3A74
FC6678-7MSD 3A1496.D 200 06/09/23 TD n/a n/a V3A74
FC6678-7 3A1489.D 100 06/09/23 TD n/a n/a V3A74
FC6678-7 3A1494.D 200 06/09/23 TD n/a n/a V3A74
The QC reported here applies to the following samples:Method: SM 6200B
FC6620-1, FC6620-2, FC6620-6
FC6678-7 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
87-68-3 Hexachlorobutadiene ND 2000 2100 105 2000 2100 105 0 70-130/20
98-82-8 Isopropylbenzene 44.5 J 2000 2010 98 2000 2020 99 0 70-130/20
99-87-6 p-Isopropyltoluene ND 2000 1900 95 2000 1910 96 1 70-130/20
74-83-9 Methyl Bromide ND 2000 1770 89 2000 1990 100 12 60-140/20
74-87-3 Methyl Chloride ND 2000 2030 102 2000 2310 116 13 60-140/20
74-95-3 Methylene Bromide ND 2000 1980 99 2000 1920 96 3 70-130/20
75-09-2 Methylene Chloride 122 J 2000 2200 104 2000 2210 104 0 70-130/20
1634-04-4 Methyl Tert Butyl Ether 382 2000 2470 104 2000 2460 104 0 70-130/20
91-20-3 Naphthalene 130 2000 2090 98 2000 2030 95 3 70-130/20
103-65-1 n-Propylbenzene 67.8 2000 2020 98 2000 2000 97 1 70-130/20
100-42-5 Styrene ND 2000 1900 95 2000 1900 95 0 70-130/20
75-85-4 Tert-Amyl Alcohol 1020 20000 16500 77 20000 16200 76 2 70-130/20
994-05-8 Tert-Amyl Methyl Ether 156 2000 1980 91 2000 1950 90 2 70-130/20
75-65-0 Tert-Butyl Alcohol ND 20000 19000 95 20000 19000 95 0 70-130/20
762-75-4 Tert-Butyl Formate ND 10000 18000 180*10000 19700 197*9 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 2000 1800 90 2000 1780 89 1 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 2000 2000 100 2000 1930 97 4 70-130/20
127-18-4 Tetrachloroethylene ND 2000 2080 104 2000 2100 105 1 70-130/20
108-88-3 Toluene 8910 a 2000 11100 110 2000 11100 110 0 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 2000 2090 105 2000 2070 104 1 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 2000 1820 91 2000 1830 92 1 70-130/20
71-55-6 1,1,1-Trichloroethane ND 2000 2070 104 2000 2080 104 0 70-130/20
79-00-5 1,1,2-Trichloroethane ND 2000 2030 102 2000 2020 101 0 70-130/20
79-01-6 Trichloroethylene ND 2000 2050 103 2000 2030 102 1 70-130/20
75-69-4 Trichlorofluoromethane ND 2000 1610 81 2000 1870 94 15 60-140/20
96-18-4 1,2,3-Trichloropropane ND 2000 2140 107 2000 2070 104 3 70-130/20
95-63-6 1,2,4-Trimethylbenzene 852 2000 2750 95 2000 2730 94 1 70-130/20
108-67-8 1,3,5-Trimethylbenzene 256 2000 2240 99 2000 2240 99 0 70-130/20
75-01-4 Vinyl Chloride ND 2000 1960 98 2000 2250 113 14 60-140/20
m,p-Xylene 4200 4000 7770 89 4000 7810 90 1 70-130/20
95-47-6 o-Xylene 2290 2000 3770 74 2000 3750 73 1 70-130/20
CAS No.Surrogate Recoveries MS MSD FC6678-7 FC6678-7 Limits
1868-53-7 Dibromofluoromethane 95%94%95%96%70-130%
* = Outside of Control Limits.
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Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number:FC6620
Account:GRINCC GRI (Geological Resources Inc.)
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC6678-7MS 3A1495.D 200 06/09/23 TD n/a n/a V3A74
FC6678-7MSD 3A1496.D 200 06/09/23 TD n/a n/a V3A74
FC6678-7 3A1489.D 100 06/09/23 TD n/a n/a V3A74
FC6678-7 3A1494.D 200 06/09/23 TD n/a n/a V3A74
The QC reported here applies to the following samples:Method: SM 6200B
FC6620-1, FC6620-2, FC6620-6
CAS No.Surrogate Recoveries MS MSD FC6678-7 FC6678-7 Limits
17060-07-0 1,2-Dichloroethane-D4 102%100%105%108%70-130%
2037-26-5 Toluene-D8 101%101%102%101%70-130%
460-00-4 4-Bromofluorobenzene 102%102%100%101%70-130%
(a) Result is from Run #2.
* = Outside of Control Limits.
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SGS North America Inc.
GC Volatiles
QC Data Summaries
Includes the following where applicable:
 Method Blank Summaries
 Blank Spike Summaries
 Matrix Spike and Duplicate Summaries
Orlando, FL
Section 6
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Method Blank Summary Page 1 of 1
Job Number:FC6620
Account:GRINCC GRI (Geological Resources Inc.)
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
GLL2878-MB LL82847.D 1 06/07/23 SS n/a n/a GLL2878
The QC reported here applies to the following samples:Method: RSKSOP-147/175
FC6620-2, FC6620-3, FC6620-4
CAS No.Compound Result RL MDL Units Q
74-82-8 Methane ND 0.50 0.16 ug/l
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Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:FC6620
Account:GRINCC GRI (Geological Resources Inc.)
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
GLL2878-BS LL82844.D 1 06/07/23 SS n/a n/a GLL2878
GLL2878-BSD LL82845.D 1 06/07/23 SS n/a n/a GLL2878
The QC reported here applies to the following samples:Method: RSKSOP-147/175
FC6620-2, FC6620-3, FC6620-4
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
74-82-8 Methane 108 134 124 127 118 5 62-139/30
* = Outside of Control Limits.
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Matrix Spike Summary Page 1 of 1
Job Number:FC6620
Account:GRINCC GRI (Geological Resources Inc.)
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC6586-8MS LL82863.D 1 06/07/23 SS n/a n/a GLL2878
FC6586-8 LL82849.D 1 06/07/23 SS n/a n/a GLL2878
The QC reported here applies to the following samples:Method: RSKSOP-147/175
FC6620-2, FC6620-3, FC6620-4
FC6586-8 Spike MS MS
CAS No.Compound ug/l Q ug/l ug/l %Limits
74-82-8 Methane 56.4 108 148 85 62-139
* = Outside of Control Limits.
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Duplicate Summary Page 1 of 1
Job Number:FC6620
Account:GRINCC GRI (Geological Resources Inc.)
Project:Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC6586-8DUP LL82862.D 1 06/07/23 SS n/a n/a GLL2878
FC6586-8 LL82849.D 1 06/07/23 SS n/a n/a GLL2878
The QC reported here applies to the following samples:Method: RSKSOP-147/175
FC6620-2, FC6620-3, FC6620-4
FC6586-8 DUP
CAS No.Compound ug/l Q ug/l Q RPD Limits
74-82-8 Methane 56.4 62.9 11 30
* = Outside of Control Limits.
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.
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SGS North America Inc.
General Chemistry
QC Data Summaries
Includes the following where applicable:
 Method Blank and Blank Spike Summaries
 Duplicate Summaries
 Matrix Spike Summaries
Orlando, FL
Section 7
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METHOD BLANK AND SPIKE RESULTS SUMMARY
GENERAL CHEMISTRY
Login Number: FC6620
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
MB Spike BSP BSP QC
Analyte Batch ID RL Result Units Amount Result %Recov Limits
Chloride GP38817/GN94361 2.0 0.0 mg/l 50 48.9 97.8 90-110%
Iron, Ferrous GN94377 0.10 0.0 mg/l 0.500 0.51 101.5 82-115%
Nitrogen, Nitrate GP38817/GN94361 0.10 0.0 mg/l 2.5 2.54 101.6 90-110%
Nitrogen, Nitrite GP38817/GN94361 0.10 0.0 mg/l 2.5 2.64 105.6 90-110%
Sulfate GP38817/GN94361 2.0 0.0 mg/l 50 49.7 99.4 90-110%
Associated Samples:
Batch GN94377: FC6620-2, FC6620-3, FC6620-4
Batch GP38817: FC6620-2, FC6620-3, FC6620-4
(*) Outside of QC limits
__________________________________________________________________________________________________________________________
Page 1
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DUPLICATE RESULTS SUMMARY
GENERAL CHEMISTRY
Login Number: FC6620
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
QC Original DUP QC
Analyte Batch ID Sample Units Result Result RPD Limits
Iron, Ferrous GN94377 FC6620-2 mg/l 0.038 0.047 20.9 0-31%
Associated Samples:
Batch GN94377: FC6620-2, FC6620-3, FC6620-4
(*) Outside of QC limits
__________________________________________________________________________________________________________________________
Page 1
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MATRIX SPIKE RESULTS SUMMARY
GENERAL CHEMISTRY
Login Number: FC6620
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
QC Original Spike MS QC
Analyte Batch ID Sample Units Result Amount Result %Rec Limits
Chloride GP38817/GN94361 FC6618-1 mg/l 2.4 50 52.6 100.4 90-110%
Nitrogen, Nitrate GP38817/GN94361 FC6618-1 mg/l 0.52 2.5 3.0 99.2 90-110%
Nitrogen, Nitrite GP38817/GN94361 FC6618-1 mg/l 0.046 2.5 2.7 106.2 90-110%
Sulfate GP38817/GN94361 FC6618-1 mg/l 7.6 50 58.3 101.4 90-110%
Associated Samples:
Batch GP38817: FC6620-2, FC6620-3, FC6620-4
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
__________________________________________________________________________________________________________________________
Page 1
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7.
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MATRIX SPIKE DUPLICATE RESULTS SUMMARY
GENERAL CHEMISTRY
Login Number: FC6620
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Gray's Creek Superette; 6309 NC Hwy 87 S, Fayetteville, NC
QC Original Spike MSD QC
Analyte Batch ID Sample Units Result Amount Result RPD Limit
Chloride GP38817/GN94361 FC6618-1 mg/l 2.4 50 52.6 0.0 15%
Nitrogen, Nitrate GP38817/GN94361 FC6618-1 mg/l 0.52 2.5 3.0 0.0 15%
Nitrogen, Nitrite GP38817/GN94361 FC6618-1 mg/l 0.046 2.5 2.7 0.0 15%
Sulfate GP38817/GN94361 FC6618-1 mg/l 7.6 50 58.3 0.0 15%
Associated Samples:
Batch GP38817: FC6620-2, FC6620-3, FC6620-4
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
__________________________________________________________________________________________________________________________
Page 1
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APPENDIX D
GSI Mann-Kendall Toolkit for Plume Stability Analysis
Evaluation Date:Job ID:
Facility Name:Constituent:
Conducted By:Concentration Units:μg/L
Sampling Point ID:Benzene Toluene Ethylbenzene Xylenes Naphthalene MW-2/2R Napth
Sampling Sampling
Event Date
1 5-Oct-94 9700 124000 4570 19800
2 19-Jan-95 1900 50000 11000 60000 351 0
3 26-Jan-96 32300 175000 29800 274000 9750
4 14-Aug-96 450 5000 270 1900 0
5 14-Feb-97 2700 28000 2100 13200
6 29-Aug-97 0 20000 8400 39400
7 29-Oct-20 38.7 3170 4410 12300 1560 19.8
8 25-May-21 26.4 2060 1190 4410 372 47.5
9 5-Jun-23 0
10
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:1.89 1.26 1.25 1.72 1.72 1.34
Mann-Kendall Statistic (S):-16 -20 -8 -10 0 1
Confidence Factor:96.9%99.3%80.1%86.2%40.8%50.0%
Concentration Trend:Decreasing Decreasing No Trend No Trend No Trend No Trend
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water, 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
GSI Environmental Inc., www.gsi-net.com
MW-1/1R CONCENTRATION (μg/L)
28-Jun-23
Gray's Creek Superette MW-1/1R
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
William Regenthal
13439
1
10
100
1000
10000
100000
1000000
01/00 09/13 05/27 01/41 10/54 06/68 02/82 10/95 07/09 03/23 11/36
Co
n
c
e
n
t
r
a
t
i
o
n

(
μg/
L
)
Sampling Date
Benzene
Toluene
Ethylbenzene
Xylenes
Naphthalene
MW-2/2R Napth