AS-9868_9868_CA_MRP_20230512

ALPHA

Geotechnical Engineering, Environmental Consulting, and
Construction Materials QC/QA

Groundwater Monitoring Report

Mull Oil Bulk Plant
500 West Fleming Drive, Morganton, NC
Burke County

UST Incident # 9868
Alpha Project # 23001.01 TF

Prepared For:

Mull, Inc.
PO Box 8309
Morganton, NC 28680

Ms. Katie Bernal
NC DEQ - Division of Waste Management - UST Section
Asheville Regional Office
2090 US Highway 70
Swannanoa, NC 28778

Prepared By:

Alpha Environmental
P.O. Box 2155
Asheville, NC 28802

May 12, 2023
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B. EXECUTIVE SUMMARY

1. Source Information/Free Product

The source of the release is from a gasoline AST system formerly located on the site. The
release was discovered in 1993 when a petroleum sheen was observed in a small creek
located to the south of the site. The sizes and contents of each of the tanks is not well
documented. Historically, free product has been detected in monitoring well MW-2, MW-3 and
MW-4 and passive free product recovery system was installed in MW-4 in 1995. It is not well
documented the amount of free product that was recovered from this well. Free product was
detected in MW-2 during this sampling event.

2. Maximum Groundwater Contaminant Concentrations and Current Extent of
Groundwater Contamination

Two sampling events took place during this monitoring period. In January 2023 and April 2023
monitoring wells MW-4, MW-5, MW-6, MW-7, MW-10, MW-11 and were sampled. Contaminant
levels are highest in MW-2 and MW-11, in proximity to and downgradient of the former AST
tank locations. Four of the seven wells that were gauged for these sampling events are located
in the free product or dissolved contaminant plume. The groundwater at the site appears to
flow towards the southeast. MW-5 is the farthest downgradient well to the southwest and is
located within the dissolved contaminant plume. MW-6 and MW-7 are cross gradient of MW-
5 and located farther to the northeast of the release area. These wells lie outside of the
dissolved contaminant plume.

4. Maximum Soil Contaminant Concentrations

Soil samples were not collected during this sampling event. Based on soil sampling conducted
for the Comprehensive Site Assessment (CSA), hydrocarbon impacted soil exists across the
property with varying contamination levels. Areas upgradient of the former AST area did not
appear to be impacted.
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C. TABLE OF CONTENTS

A. Site Information 2
B. Executive Summary 3
C. Table of Contents 4
D. Site History and Characterization 5
E. Summary of Current and Historical Assessment Information 6
F. Free Product 8
G. Conclusions 8

Figures 10
1. Site Topographic Map
2. Site Base Map
3. Benzene Concentration Map
4. Groundwater Contour Map

Tables 11
1. AST Owner/Operator Information
2. Surrounding Property Owners
3. Summary of Groundwater Analytical Results (February 2000 to present)
4. Monitoring Well Construction Data
5. Groundwater Level and Elevation Data
6. Free Product Recovery Information

Appendices 12
A. Field Data Sheets (January & April)
B. Laboratory Analytical Results (January & April)

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D. SITE HISTORY AND CHARACTERIZATION

1. Historical reporting shows six above ground storage tanks (ASTs) located on the subject
site. The sizes and contents of each specific tank are not stated in the historical reports
made available to Alpha. All ASTs were removed from the site in 2013. There are no known
underground storage tanks located on the subject site.

2. Table 1 provides the owner/operator information for all USTs and ASTs currently or
previously located at the Site.

3. There are no known spills associated with this site from other ASTs or USTs.

4. A release was discovered in 1993 when a petroleum sheen was discovered in the small
creek located to the south of the subject site, across Fleming Drive. The subject site
operated as bulk storage facility for gasoline, diesel fuel, kerosene and heating oil. In
response, NCDEQ directed a site investigation of the subject site at which time all piping
associated with the ASTs on the subject site was uncovered and visually inspected. All
ASTs were also visually inspected for signs of leaking. It was discovered that a union of
the piping from one of the ASTs that transports product to the dispensers was leaking. The
leak was repaired, piping replaced and a small amount of soil was excavated only in the
area of the leak. The historical reporting provided to Alpha does not specify the contents
of the AST associated with the leaking piping.

Following the discovery of the release, a recovery trench was installed to intercept free
product and seven monitoring wells were installed on the subject site and on the property
across Fleming Drive to the south, between the creek and Fleming Drive. Two additional
monitoring wells were installed in July 1993 as part of the Comprehensive Site Assessment
and two were installed in October 1995 following the submittal of the Corrective Action Plan
and Revised Corrective Action Plan.

The information obtained from the Initial Site Characterization and the Comprehensive Site
Assessment shows that more than one contamination plume existed on the site. Analyses
indicated the presence of constituents associated with middle grade and lighter grade
distillates. At the time of the release, the site had operated as a bulk storage petroleum
facility for over 50 years and it is likely that more than one release had occurred on the
property over this time period.

5. The property currently is occupied by Nebo Rentals, a company that rents excavation and
construction equipment. There is a warehouse/office building and storage/workshop sheds
located on the property. The remainder of the property is asphalt, gravel or grass covered.
The property is mostly flat with some sloping gradient along the northern boundary of the
property, sloping towards the south. The surrounding properties include residential,
commercial and industrial properties.

6. The most recent receptor survey update was conducted during the March 2022 sampling
period. The Burke County Environmental Health Department was contacted for information
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regarding water supply well permits within a radius of 1,500 feet of the release area. No
water supply wells were identified through this search, however permitting records for
private wells are only available from 2008 to present. A site reconnaissance was conducted
by Alpha on March 3, 2022 for properties located within 1,500 feet of the release location.
No private water wells were observed during the site reconnaissance.

The City of Morganton services drinking water to the subject site as well as the properties
located within 1,500 feet of the release.

Potential surface water receptors include an unnamed creek/waterway that lies
approximately 175 feet south of the southern boundary of the subject site and
approximately 250 feet south of the former AST storage location. The creek flows in an
easterly direction at this location.

7. The original (CAP), dated March 10, 1995, was followed by a revised CAP, dated January
15, 1996 which proposed active groundwater remediation by pump-and-treat. The pump-
and-treat system was installed and started up in February 1999 and originally consisted of
one recovery well RW-1. A second recovery well, RW-2, was added to the system in
September 1999. It is not documented when operation of the system was stopped. As of
the last monitoring event for this site in June 2006, the system was in operation, however
RW-1 was not pumping.

E. SUMMARY OF CURRENT AND HISTORICAL ASSESSMENT INFORMATION

1. Present Water Level and Free Product Information
Current water levels and relative groundwater elevations are shown in Table 5. The depth to
water at the subject site varied from approximately 5 to 10 feet below top of casing for both of
the January and April monitoring events. Free product was detected in MW-2 with a thickness
of 0.01 feet at the time of the January and April monitoring events.

2. Groundwater Monitoring Events

On January 24, 2023 and April 13, 2023, monitoring wells MW-4, MW-5, MW-6, MW-7, MW-
10D and MW-11 were purged and sampled. Monitoring well MW-2 contained free product and
was not sampled. Groundwater level readings were collected from monitoring wells MW-8 and
MW-9, but groundwater samples were not collected from these wells, at the direction of
NCDEQ. All samples were analyzed for volatile organic compounds (VOCs) by EPA Method
6200. One duplicate sample was collected and was identified as Dup-1. This sample was
collected from monitoring well MW-11 for both monitoring events and was submitted for VOC
analysis. A summary of the analytical results is provided in Table 3.

The redevelopment of monitoring wells MW-4, MW-5, MW-8 and MW-9 to remove
accumulated silt was scheduled to take place during this monitoring period, but due to an
oversight by Alpha, these wells were not redeveloped following the initial redevelopment in
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July 2022. These wells will be redeveloped prior to the next sampling event using methods
other than hand bailing.

3. Surface Water Monitoring
One surface water sample was collected from the unnamed waterway that is located south of
the subject site, across Fleming Drive. The surface water sample collection was requested by
NCDEQ after residual petroleum was observed by NCDEQ personnel during a site visit in
response to a spill unrelated to the Mull Oil Bulk Plant release. The section of stream where
the residual petroleum was observed was in an area near the confluence of the unnamed
waterway and Huntington Creek. The surface water sample, SS-3, was collected in the area
where the residual petroleum was identified, approximately 940 feet downgradient of surface
sample location SS-2, or approximately 180 feet upgradient of the confluence of the unnamed
waterway and Huntington Creek.

The surface water sample was submitted for analysis of VOCs by EPA Method 6200. VOCs
were not detected above laboratory detection limits in the surface water sample.

4. Soil Contamination Monitoring
No soil contamination monitoring was performed.

5. Summary of Groundwater Monitoring
Three of the seven wells monitored during the January and April sampling events have
detectable levels of VOCs and one well had detectable free product. Contaminant levels that
exceeded the 2L groundwater standard levels include benzene in MW-4, and benzene, MTBE,
naphthalene, and diisopropyl ether in MW-11. MTBE and diisopropyl ether were detected in
MW-5 at levels that did not exceed the groundwater standard. No contaminants were detected
above laboratory detection limits in MW-6, MW-7 and MW-10. MW-10 was installed as a deep
well with a total depth of 35 feet bgs.

Contaminant levels in all of the wells do appear to be decreasing overall, however free product
continues to be detected in MW-2. Containment levels were either below the groundwater
standard or below detection limits in the three most downgradient wells.

6. Geology and Hydrogeology of the Region and the Site
The subject site is located within the Inner Piedmont Physiographic Province of Western North
Carolina. According to the Geologic Map of North Carolina (NC Geologic Survey, 1985) the
Site is underlain by Cambrian to Ordovician migmatitic granitic gneiss, described as foliated to
massive, granitic to quartz dioritic; biotite gneiss and amphibolite common.

Soil type underlying the site is not well documented in the historical reports provided to Alpha.
The CAP states that a soil sample collect at 12 feet bgs from the location of MW-10 was
classified through grain size analysis as a silty sand. Groundwater is encountered at a depth
of approximately 5-6 feet below ground surface throughout most the site north of West Fleming
Drive and approximately 8 feet below ground surface in the well to the south of West Fleming
Drive.

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Groundwater beneath the site appears to flow in a southeasterly direction from the source area
of the release. As reported in the revised CAP, slug testing performed on monitoring well MW-
10 shows hydraulic conductivity to be 1.3523 x 10-4 cm/sec.

7. Summary of Assessment for Soil and Groundwater
Soil sampling last took place for the CSA. Samples were collected across the property at two
separate depth intervals, 3-5 feet and 8-10 feet. Current levels of soil contamination are not
known as soil assessment was not part of the scope of work for this sampling period.

The groundwater contamination consists of a small free product plume and a dissolved
contaminant plume caused from at least one release on the site. The dissolved contaminant
plume extends outside of the property to the farthest southern downgradient well associated
with this release, MW-5, approximately 130 feet southeast of the area of highest
contamination. Contamination levels in MW-5 have increased in the last two monitoring
events. Monitoring wells MW-6 and MW-7 are also downgradient of the release and across
West Fleming Drive. These wells are outside of the current extents of the dissolved
contaminant plume.

F. FREE PRODUCT

Historically, free product has been detected in wells MW-2, MW-3 and MW-4. Free product
was detected in MW-2 during this monitoring event. Free product had not been detected in this
well since the February 2000 monitoring event. Free product was last detected in MW-3 during
the June 2001 monitoring event and has not been detected in MW-4 in any recent monitoring
events.

On January 24, 1995, a passive free product recovery system was installed in MW-4. The
total amount of free product recovered through the passive recovery system is unknown.

Free product recovery, changing absorbent booms on a monthly basis in MW-2, was initiated
following the March 2022 monitoring event. Following the submittal of a Free Product
Recovery Report, dated August 9, 2022, DEQ reduced the absorbent boom recovery and
replacement to a quarterly basis. The absorbent sock was changed out as part of the January
and April monitoring event. A total of 0.48 gallons of free product has been removed since
implementation of the current free product recovery plan.

G. CONCLUSIONS

Based on the results of this round of sampling and assessment, Alpha makes the following
recommendations:

 Attempt to redevelop wells MW-4, MW-5, MW-8 and MW-9 with different methods due
to unsuccessful redevelopment using only bailers.
 Continue quarterly replacement of absorbent booms in MW-2 for free product recovery.
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 Reduce groundwater monitoring of MW-2, MW-4, MW-5, MW-6, MW-7, MW-10 and
MW-11 from quarterly to semi-annually.

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6
3
10
5
4
.
5
2
1061
1055
1056
1057
1058
1059
1060
MW
-
6
MW
-
7
1063
FI
G
U
R
E

4
In
c
i
d
e
n
t

#

9
8
6
8
Gr
o
u
n
d
w
a
t
e
r

C
o
n
t
o
u
r

M
a
p
Mo
r
g
a
n
t
o
n
,

N
C
Mu
l
l

B
u
l
k

S
t
o
r
a
g
e

F
a
c
i
l
i
t
y
Env
i
r
o
n
m
e
n
t
a
l

S
c
i
e
n
c
e
s
,

I
n
c
.
AL
P
H
A
DA
T
E
:

0
5
/
1
2
/
2
3
DR
A
W
N

B
Y
:

S
R
SC
A
L
E
:
1
"
=
5
0
'
+
/
-
0
25
50
Su
r
f
a
c
e

w
a
t
e
r

s
a
m
p
l
e

S
S
-
3

w
a
s

c
o
l
l
e
c
t
e
d

ap
p
r
o
x
.

9
4
0

f
t

d
o
w
n
g
r
a
d
i
e
n
t

o
f

S
S
-
2
Ap
r
i
l

w
a
t
e
r

l
e
v
e
l

d
a
t
a

s
h
o
w
n

o
n

t
h
i
s

m
a
p
No
t
e
:
ALPHA Mull Oil Bulk Plant - GW Monitoring Report

11

TABLES

AST ID Number Unknown
State Zip
NC 28680
State Zip
NC 28680Morganton 828-433-6412
TABLE 1
AST Owner/Operator Information
Mull Oil Bulk Plant
Alpha Project #23001.02 TF
PO Box 8309
City Telephone Number
Mull Oil. Inc. unknown
Street Address
Morganton 828-433-6412
Name of Operator Dates of Operation
(mm/dd/yy to mm/dd/yy)
Mull Oil. Inc. unknown
Street Address
PO Box 8309
City Telephone Number
NA Facility ID Number
Name of Owner Dates of Operation
(mm/dd/yy to mm/dd/yy)
ALPHA
TA
X

P
A
R
C
E
L

N
U
M
B
E
R

/

MA
P

I
D
OW
N
E
R

/

O
C
C
U
P
A
N
T

N
A
M
E

(
L
a
s
t
,

F
i
r
s
t
,

M
I
)
AD
D
R
E
S
S
27
0
2
0
9
8
7
1
8

(
A
c
r
o
s
s

W

Fl
e
m
i
n
g

D
r
)

St
a
t
e

o
f

N
C

S
c
h
o
o
l

f
o
r

D
e
a
f
Ru
t
h
e
r
f
o
r
d
t
o
n

R
d
,

M
o
r
g
a
n
t
o
n
,

N
C

2
8
6
5
5
27
0
3
3
2
0
7
9
8

(
A
c
r
o
s
s

W

Fl
e
m
i
n
g

D
r
)
So
u
t
h
e
r
n

M
e
d
i
c
a
l

A
s
s
o
c
i
a
t
e
s
,

P
L
L
C
34
5
4

B
l
a
n
k
e
n
s
h
i
p

D
r
,

M
o
r
g
a
n
t
o
n
,

N
C

2
8
6
5
5
27
0
3
3
3
0
0
2
8
Ai
r
l
i
e

I
n
c
10
5

I
n
d
e
p
e
n
d
e
n
c
e

B
l
v
d

M
o
r
g
a
n
t
o
n
,

N
C

2
8
6
5
5
27
0
3
2
3
8
1
3
0
Ai
r
l
i
e

I
n
c
10
5

I
n
d
e
p
e
n
d
e
n
c
e

B
l
v
d

M
o
r
g
a
n
t
o
n
,

N
C

2
8
6
5
5
27
0
3
2
2
7
9
3
8
Mu
l
l

I
n
c
PO

B
o
x

8
3
0
9

M
o
r
g
a
n
t
o
n
,

N
C

2
8
6
5
5
27
0
3
2
2
5
9
8
2
Mu
l
l

I
n
c
PO

B
o
x

8
3
0
9

M
o
r
g
a
n
t
o
n
,

N
C

2
8
6
5
5
TA
B
L
E

2
Su
r
r
o
u
n
d
i
n
g

P
r
o
p
e
r
t
y

O
w
n
e
r
s
Mu
l
l

O
i
l

B
u
l
k

P
l
a
n
t
Al
p
h
a

P
r
o
j
e
c
t

#
2
3
0
0
1
.
0
2

T
F
ALP
H
A
Pb

2
0
0
.
7
Sa
m
p
l
e

I
D
Da
t
e

C
o
l
l
e
c
t
e
d

2/2
2
/
2
0
0
0
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/1
4
/
2
0
0
1
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/2
2
/
2
0
0
1
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
10
/
1
6
/
2
0
0
2
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4/2
0
/
2
0
0
4
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/2
2
/
2
0
0
0
2/
1
4
/
2
0
0
1
31
0
81
17
0
45
NA
NA
24
0
NA
16
0
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/
2
2
/
2
0
0
1
BD
L
BD
L
BD
L
<1
NA
NA
BD
L
NA
78
0
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
10
/
1
6
/
2
0
0
2
1,2
0
0
<2
5
0
24
0
<1
5
0
NA
NA
1,3
0
0
NA
78
0
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4/
2
0
/
2
0
0
4
48
8
22
43
27
.
5
NA
NA
61
0
NA
34
2
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/
2
2
/
2
0
0
6
22
.
3
<5
<5
32
.
2
NA
NA
23
7
NA
10
5
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3/2
/
2
0
2
2
7/7
/
2
0
2
2
10
/
3
/
2
0
2
2
1/
2
4
/
2
0
2
3
4/
1
3
/
2
0
2
3
2/
2
2
/
2
0
0
0
2/
1
4
/
2
0
0
1
14
0
17
18
18
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/
2
2
/
2
0
0
1
10
/
1
6
/
2
0
0
2
61
0
75
10
0
15
0
NA
NA
<5
0
NA
<5
0
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4/
2
0
/
2
0
0
4
48
.
4
4.3
5.
7
10
.
9
NA
NA
18
NA
5
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/
2
2
/
2
0
0
6
24
.
8
BD
L
BD
L
3.6
8
NA
NA
8.0
5
NA
3.1
5
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/
2
2
/
2
0
0
0
51
8
10
2
69
NA
NA
57
NA
14
6
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/
1
4
/
2
0
0
1
32
BD
L
16
0
12
0
NA
NA
BD
L
NA
19
0
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/
2
2
/
2
0
0
1
BD
L
BD
L
11
0
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
10
/
1
6
/
2
0
0
2
16
<5
0
30
<3
0
NA
NA
<5
0
NA
68
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4/
2
0
/
2
0
0
4
7
BD
L
BD
L
1.5
NA
NA
8.9
NA
11
2
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/
2
2
/
2
0
0
6
3.0
8
BD
L
BD
L
<3
NA
NA
4.3
8
NA
72
.
3
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3/2
/
2
0
2
2
16
.
5
1.4
BD
L
4.1
2.1
BD
L
BD
L
BD
L
3.0
2.9
0.8
2
BD
L
BD
L
BD
L
6.0
BD
L
BD
L
6.2
33
.
0
89
3
16
6
18
3
7/7
/
2
0
2
2
16
.
5
1.6
0.9
2
5.5
6
2.5
BD
L
BD
L
BD
L
2.7
4.5
2.3
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
10
/
3
/
2
0
2
2
10
.
3
1.2
BD
L
4.2
2.9
BD
L
BD
L
BD
L
3.2
2.6
0.9
5
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
1/
2
4
/
2
0
2
3
15
.
7
1.3
BD
L
3.3
2.0
BD
L
BD
L
BD
L
3.2
1.8
0.5
8
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
4/
1
3
/
2
0
2
3
13
.
4
1.2
BD
L
3.8
0
2.0
BD
L
BD
L
BD
L
2.3
2.6
1.1
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/
2
2
/
2
0
0
0
BD
L
BD
L
BD
L
BD
L
NA
NA
9.3
NA
4.0
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/
1
4
/
2
0
0
1
BD
L
BD
L
BD
L
BD
L
NA
NA
10
0
NA
54
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/
2
2
/
2
0
0
1
2.9
BD
L
BD
L
BD
L
NA
NA
16
0
NA
47
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
10
/
1
6
/
2
0
0
2
BD
L
BD
L
BD
L
BD
L
NA
NA
22
NA
15
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4/
2
0
/
2
0
0
4
20
.
6
BD
L
BD
L
BD
L
NA
NA
24
6
NA
19
6
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/
2
2
/
2
0
0
6
38
BD
L
BD
L
BD
L
NA
NA
31
8
NA
26
2
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3/2
/
2
0
2
2
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
4.9
BD
L
9.6
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
38
.
8
BD
L
BD
L
BD
L
7/7
/
2
0
2
2
17
.
8
BD
L
BD
L
BD
L
BD
L
BD
L
39
.
6
BD
L
74
.
5
BD
L
BD
L
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
10
/
3
/
2
0
2
2
14
.
1
BD
L
BD
L
BD
L
BD
L
BD
L
48
.
5
BD
L
93
.
9
0.8
5
0.6
4
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
1/
2
4
/
2
0
2
3
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
5.1
BD
L
12
.
8
BD
L
BD
L
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
4/
1
3
/
2
0
2
3
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
6.9
BD
L
17
.
1
BD
L
BD
L
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/
2
2
/
2
0
0
0
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/
1
4
/
2
0
0
1
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/
2
2
/
2
0
0
1
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
10
/
1
6
/
2
0
0
2
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4/
2
0
/
2
0
0
4
2.9
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
2.4
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/
2
2
/
2
0
0
6
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
7/7
/
2
0
2
2
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
10
/
3
/
2
0
2
2
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
1/
2
4
/
2
0
2
3
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
4/
1
3
/
2
0
2
3
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
Mu
l
l

O
i
l

B
u
l
k

P
l
a
n
t
EP
A

6
2
5
bis (2-Ethylhexyl)phthalate
Naaphthalene
Phenanthrene
tert-Butylbenzene
Alp
h
a

P
r
o
j
e
c
t

#
2
3
0
0
1
.
0
2

T
F
Fr
e
e

P
r
o
d
u
c
t
Fr
e
e

P
r
o
d
u
c
t

Fr
e
e

P
r
o
d
u
c
t
Ta
b
l
e

3
An
a
l
y
t
i
c
a
l

M
e
t
h
o
d

C
o
n
t
a
m
i
n
a
n
t

o
f

C
o
n
c
e
r
n

Benzene
MW
-
1
Fr
e
e

P
r
o
d
u
c
t
Su
m
m
a
r
y

o
f

G
r
o
u
n
d
w
a
t
e
r

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s

(
2
0
0
0

t
o

p
r
e
s
e
n
t
)
All

r
e
s
u
l
t
s

s
h
o
w
n

i
n

µ
g
/
L
(
p
p
b
)

u
n
l
e
s
s

o
t
h
e
r
w
i
s
e

n
o
t
e
d
MA
D
E
P

V
P
H
Fluorene
Pyrene
Xylenes
1,2,4-Trimethylbenzene
EP
A

6
2
0
0
*
*
sec-Butylbenzene
Toluene
C5-C8 Aliphatic
1,3,5-Trimethylbenzene
Fr
e
e

P
r
o
d
u
c
t
n-Propylbenzene
Lead
Ethylbenzene
diisopropyl ether
Naphthalene
C9-C10 Aromatic
C9-C12 Aliphatic
MW
-
3
MTBE
Fr
e
e

P
r
o
d
u
c
t
Isopropylbenzene
MW
-
2
Fr
e
e

P
r
o
d
u
c
t
Fr
e
e

P
r
o
d
u
c
t
MW
-
4
MW
-
5
MW
-
6
ALP
H
A
Pb

2
0
0
.
7
Sa
m
p
l
e

I
D
Da
t
e

C
o
l
l
e
c
t
e
d

Mu
l
l

O
i
l

B
u
l
k

P
l
a
n
t
EP
A

6
2
5
bis (2-Ethylhexyl)phthalate
Naaphthalene
Phenanthrene
tert-Butylbenzene
Alp
h
a

P
r
o
j
e
c
t

#
2
3
0
0
1
.
0
2

T
F
Ta
b
l
e

3
An
a
l
y
t
i
c
a
l

M
e
t
h
o
d

C
o
n
t
a
m
i
n
a
n
t

o
f

C
o
n
c
e
r
n

Benzene
MW
-
1
Su
m
m
a
r
y

o
f

G
r
o
u
n
d
w
a
t
e
r

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s

(
2
0
0
0

t
o

p
r
e
s
e
n
t
)
All

r
e
s
u
l
t
s

s
h
o
w
n

i
n

µ
g
/
L
(
p
p
b
)

u
n
l
e
s
s

o
t
h
e
r
w
i
s
e

n
o
t
e
d
MA
D
E
P

V
P
H
Fluorene
Pyrene
Xylenes
1,2,4-Trimethylbenzene
EP
A

6
2
0
0
*
*
sec-Butylbenzene
Toluene
C5-C8 Aliphatic
1,3,5-Trimethylbenzene
n-Propylbenzene
Lead
Ethylbenzene
diisopropyl ether
Naphthalene
C9-C10 Aromatic
C9-C12 Aliphatic
MTBE
Isopropylbenzene
ALP
H
A
2/
2
2
/
2
0
0
0
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/
1
4
/
2
0
0
1
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/
2
2
/
2
0
0
1
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
10
/
1
6
/
2
0
0
2
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4/
2
0
/
2
0
0
4
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
7/7
/
2
0
2
2
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
10
/
3
/
2
0
2
2
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
1/
2
4
/
2
0
2
3
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
4/
1
3
/
2
0
2
3
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/
2
2
/
2
0
0
0
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/
1
4
/
2
0
0
1
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/
2
2
/
2
0
0
1
BD
l
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
10
/
1
6
/
2
0
0
2
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4/
2
0
/
2
0
0
4
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3/2
/
2
0
2
2
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
20
.
7
BD
L
BD
L
BD
L
2/
2
2
/
2
0
0
0
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/
1
4
/
2
0
0
1
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/
2
2
/
2
0
0
1
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
10
/
1
6
/
2
0
0
2
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4/
2
0
/
2
0
0
4
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3/2
/
2
0
2
2
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
38
.
9
BD
L
BD
L
BD
L
2/
2
2
/
2
0
0
0
BD
L
BD
L
BD
L
BD
L
NA
NA
1.8
NA
2
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/
1
4
/
2
0
0
1
BD
L
BD
L
BD
L
BD
L
NA
NA
1
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/
2
2
/
2
0
0
1
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
10
/
1
6
/
2
0
0
2
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4/
2
0
/
2
0
0
4
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/
2
2
/
2
0
0
6
BD
L
BD
L
BD
L
BD
L
NA
NA
BD
L
NA
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3/2
/
2
0
2
2
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
7/7
/
2
0
2
2
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
10
/
3
/
2
0
2
2
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
1/
2
4
/
2
0
2
3
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
4/
1
3
/
2
0
2
3
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/
2
2
/
2
0
0
0
2,2
2
0
95
16
0
<5
0
NA
NA
2,3
3
0
NA
1,4
2
0
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/
1
4
/
2
0
0
1
1,9
0
0
77
11
0
3
NA
NA
2,1
0
0
NA
1,3
0
0
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/
2
2
/
2
0
0
1
3,3
0
0
BD
L
BD
L
BD
L
NA
NA
3,2
0
0
NA
1,7
0
0
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
10
/
1
6
/
2
0
0
2
39
0
BD
L
1.
7
5.1
NA
NA
41
0
NA
27
0
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4/
2
0
/
2
0
0
4
2,6
8
0
95
30
0
<5
0
NA
NA
1,4
6
0
NA
1,2
6
0
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/
2
2
/
2
0
0
6
1,8
0
0
<2
0
43
.
6
30
.
8
NA
NA
1,3
2
0
NA
93
0
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3/2
/
2
0
2
2
17
1
5.4
1.
8
16
.
4
2.9
BD
L
60
.
7
24
.
8
77
.
2
3.4
1.8
BD
L
BD
L
4.5
4.2
17
.
0
5.2
BD
L
11
.
6
3,7
5
0
35
1
42
5
7/7
/
2
0
2
2
17
7
5.8
3.
3
20
.
8
7
4.5
1
54
.
9
36
.
7
91
.
3
5.8
3.9
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
10
/
3
/
2
0
2
2
14
7
4.8
1.
4
16
.
1
3.8
0.9
3
51
.
3
14
.
2
79
.
6
4.1
1.5
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
1/
2
4
/
2
0
2
3
20
2
10
.
2
3.
1
23
.
3
BD
L
BD
L
93
.
3
38
.
2
13
9
5.7
3.2
BD
L
6.8
NA
NA
NA
NA
NA
NA
NA
NA
NA
4/
1
3
/
2
0
2
3
27
9
9.7
5.
5
28
.
5
BD
L
BD
L
71
.
8
50
.
2
12
5
8.1
5.4
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
RW
-
1
7/6
/
2
0
2
2
1
BD
L
BD
L
BD
L
1.3
BD
L
5.4
BD
L
24
.
2
0.6
BD
L
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
RW
-
2
7/7
/
2
0
2
2
1
BD
L
BD
L
BD
L
0.6
9
BD
L
3.7
BD
L
2.4
1.1
0.5
7
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
SS
-
1
3/2
/
2
0
2
2
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
NA
NA
NA

NA
NA
NA
NA
NA
NA
SS
-
2
3/2
/
2
0
2
2
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
SS
-
3
4/
2
6
/
2
0
2
3
3/2
/
2
0
2
2
13
8
4.7
1.
4
15
.
2
9
3.2
0.8
1
62
.
2
16
.
1
92
.
3
4.0
1.5
BD
L
BD
L
BD
L
BD
L
19
.
2
BD
L
BD
L
11
.
8
2,7
8
0
29
3
35
6
7/7
/
2
0
2
2
17
4
5.9
3.
2
19
.
9
2
4.3
0.9
6
51
.
4
33
.
3
89
.
1
5.5
3.8
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
10
/
3
/
2
0
2
2
15
1
5.0
1.
4
16
.
1
7
3.8
0.9
6
52
.
8
14
.
5
83
.
2
4.1
1.5
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
1/
2
4
/
2
0
2
3
20
7
10
.
1
3.
1
24
.
0
BD
L
BD
L
92
.
0
36
.
9
13
9
5.9
3.1
BD
L
7.0
NA
NA
NA
NA
NA
NA
NA
NA
NA
4/
1
3
/
2
0
2
3
30
8
11
.
1
7.
9
44
.
7
BD
L
BD
L
74
.
7
52
.
5
13
1
8.5
5.9
3.2
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
Tri
p

B
l
a
n
k
7/7
/
2
0
2
2
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
BD
L
NA
NA
NA
NA
NA
NA
NA
NA
NA
1
60
0
60
0
50
0
70
70
20
6
70
70
70
40
0
40
0
3
30
0
6
20
0
20
0
15
40
0
70
0
20
0
5,0
0
0
26
0
,
0
0
0
80
,
0
0
0
50
,
0
0
0
8,8
0
0
14
,
7
5
0
20
,
0
0
0
6,0
0
0
70
,
0
0
0
30
,
5
0
0
26
,
1
0
0
28
,
5
0
0
24
,
1
0
0
13
5
84
5
60
0
0
55
0
20
0
15
,
0
0
0
NL
NL
NL
Ke
y
Bo
l
d

n
u
m
b
e
r
s

i
n
d
i
c
a
t
e

r
e
s
u
l
t

e
x
c
e
e
d
s

s
t
a
n
d
a
r
d
*
i
n
d
i
c
a
t
e
s

i
n
c
r
e
a
s
e
d

l
a
b
o
r
a
t
o
r
y

r
e
p
o
r
t
i
n
g

l
i
m
i
t
**

a
n
a
l
y
t
i
c
a
l

m
e
t
h
o
d

f
o
r

s
a
m
p
l
e
s

c
o
l
l
e
c
t
e
d

p
r
i
o
r

t
o

M
a
r
c
h

2
0
2
2

i
s

E
P
A

6
0
1
/
6
0
2
ND
/
B
D
L

-

N
o
t

D
e
t
e
c
t
e
d

A
b
o
v
e

L
a
b
o
r
a
t
o
r
y

D
e
t
e
c
t
i
o
n

L
i
m
i
t
s
NA

-

N
o
t

A
n
a
l
y
z
e
d
NL

-

N
o
t

L
i
s
t
e
d
Red

n
u
m
b
e
r
s

i
n
d
i
c
a
t
e

r
e
s
u
l
t

e
x
c
e
e
d
s

G
r
o
s
s

C
o
n
t
a
m
i
n
a
t
i
o
n

L
e
v
e
l
s

(
G
C
L
s
)
MW
-
8
MW
-
9
Du
p
-
1
MW
-
7
MW
-
1
0
D
NC
A
C

2
L

S
t
a
n
d
a
r
d

Gro
s
s

C
o
n
t
a
m
i
n
a
t
i
o
n

L
e
v
e
l
MW
-
1
1
3/31/1993 2"NF NF 10'5'-15'18'
3/31/1993 2"35.73402660 -81.68650760 10'5'-15'18'
4/1/1993 2"NF NF 10'5'-15'18'
4/1/1993 2"35.73410721 -81.68596292 10'5'-15'18'
4/18/1993 2"35.73382790 -81.68605866 10'5'-15'18'
4/18/1993 2"NF NF 10'5'-15'18'
4/18/1993 2"NF NF 10'5'-15'18'
7/22/1993 2"35.73425411 -81.68577828 10'7'-17'20'
7/23/1993 2"35.73434363 -81.68605991 10'7'-17'20'
10/10/1995 2"35.73408663 -81.68625030 30'30'-35'35'
10/10/1995 2"35.73408222 -81.68623718 3'3'-23'23'
February 1999*4"35.73406049 -81.68617476 5'5'-22'22'
9/27/1999 4"35.73401919 -81.68649064 5'5'-22'22'
Notes:
benchmark are 35.73412713, -81.6857662
*Construction date of this well is not well documented
NF - Well not found for most recent well survey
RW-1
MW-4
MW-7
MW-9
Lo
n
g
i
t
u
d
e
Da
t
e

I
n
s
t
a
l
l
e
d

(m
/
d
d
/
y
y
)
RW-2
MW-10
MW-2
MW-11
MW-5
We
l
l

D
i
a
m
e
t
e
r

(
i
n
c
h
e
s
)
We
l
l

C
a
s
i
n
g

D
e
p
t
h

(
f
t
.

BG
S
)
We
l
l

I
D
MW-8
MW-6
MW-3
Monitoring well survey took place on February 24, 2022 to replace previous survey data. Coordinates for the survey
TABLE 4
Monitoring Well Construction Data
Mull Oil Bulk Plant
Alpha Project #23001.02 TF
Bo
t
t
o
m

o
f

W
e
l
l

(
f
t
.

BG
S
)
La
t
i
t
u
d
e
Sc
r
e
e
n
e
d

I
n
t
e
r
v
a
l

(
x

t
o

y
f
t
.

B
G
S
)
MW-1
ALPHA
We
l
l

I
D
Da
t
e

W
a
t
e
r

L
e
v
e
l

Me
a
s
u
r
e
d

(
m
/
d
d
/
y
y
)
To
p

o
f

C
a
s
i
n
g

El
e
v
a
t
i
o
n
*

(
f
t
.
)
De
p
t
h

t
o

W
a
t
e
r

(
f
t
.

BS
G
)
Fr
e
e

P
r
o
d
u
c
t

Th
i
c
k
n
e
s
s

*
*

(
f
t
.
)
Gr
o
u
n
d
w
a
t
e
r

El
e
v
a
t
i
o
n
*

(
f
t
.
)
2/22/2002 4.82 --98.28
2/14/2001 5.40 --97.70
6/22/2001 4.90 --98.20
10/16/2002 4.90 --98.20
4/20/2004 5.54 --97.56
6/22/2006 5.06 --98.04
2/22/2002 7.12 --94.56
2/14/2001 5.24 --96.36
6/22/2001 3.90 0.09 97.70
10/16/2002 6.75 --94.85
4/20/2004 4.09 --97.51
6/22/2006 6.99 --94.61
3/2/2022 4.69*0.42 1066.49
7/7/2022 5.52*0.33 1065.66
8/4/2022 5.54*0.01 1065.64
10/3/2022 5.43*0.01 1065.75
1/24/2023 4.55*0.01 1066.63
4/13/2023 5.65*0.01 1065.53
2/22/2002 5.77 0.09 95.11
2/14/2001 6.09 --94.71
6/22/2001 4.02 0.06 96.83
10/16/2002 5.70 --95.10
4/20/2004 4.80 --96.00
6/22/2006 5.98 --94.82
2/22/2002 5.72 --93.98
2/14/2001 6.23 --93.47
6/22/2001 4.92 --94.78
10/16/2002 5.50 --94.20
4/20/2004 4.88 --94.82
6/22/2006 5.89 --93.81
3/2/2022 5.54 --1063.94
7/7/2022 6.21 --1063.27
10/3/2022 6.05 -1063.43
1/24/2023 5.44 -1064.04
4/13/2023 5.44 -1064.04
2/22/2002 7.80 --92.60
2/14/2001 7.96 --92.44
6/22/2001 7.10 --93.30
10/16/2002 7.68 --92.72
4/20/2004 7.16 --93.24
6/22/2006 7.68 --92.72
3/2/2022 7.95 --1062.19
7/7/2022 8.63 --1061.51
10/3/2022 8.50 -1061.64
1/24/2023 8.12 -1062.02
4/13/2023 8.05 -1062.09
MW5
1070.14
MW1
MW3
100.40
103.10
TABLE 5
Groundwater Level and Elevation Data
Mull Oil Bulk Plant
Alpha Project #23001.02 TF
100.80
MW4
1069.48
MW2
1071.18
101.60
99.70
ALPH
We
l
l

I
D
Da
t
e

W
a
t
e
r

L
e
v
e
l

Me
a
s
u
r
e
d

(
m
/
d
d
/
y
y
)
To
p

o
f

C
a
s
i
n
g

El
e
v
a
t
i
o
n
*

(
f
t
.
)
De
p
t
h

t
o

W
a
t
e
r

(
f
t
.

BS
G
)
Fr
e
e

P
r
o
d
u
c
t

Th
i
c
k
n
e
s
s

*
*

(
f
t
.
)
Gr
o
u
n
d
w
a
t
e
r

El
e
v
a
t
i
o
n
*

(
f
t
.
)
MW1 103.10
TABLE 5
Groundwater Level and Elevation Data
Mull Oil Bulk Plant
Alpha Project #23001.02 TF
ALPH
2/22/2002 7.06 --92.14
2/14/2001 7.26 --91.94
6/22/2001 6.74 --92.46
10/16/2002 6.70 --92.50
4/20/2004 6.38 --92.82
6/22/2006 7.19 --92.01
7/7/2022 7.58 --1057.14
10/3/2022 7.27 -1056.34
1/24/2023 6.33 -1057.28
4/13/2023 6.98 -1056.63
2/22/2002 10.24 --90.06
2/14/2001 10.35 --89.95
6/22/2001 10.18 --90.12
10/16/2002 10.00 --90.30
4/20/2004 10.15 --90.15
6/22/2006 NM NM NM
7/7/2022 10.34 -1054.38
10/3/2022 10.07 -1054.65
1/24/2023 10.08 -1054.64
4/13/2023 10.20 -1054.52
2/22/2002 4.76 --93.63
2/14/2001 5.04 --93.35
6/22/2001 4.10 --94.29
10/16/2002 4.50 --93.89
4/20/2004 4.03 --94.36
6/22/2006 4.91 --93.48
3/2/2022 4.44 --1063.70
10/3/2022 4.98 -1063.16
4/13/2023 4.40 -1063.74
2/22/2002 6.12 --94.40
2/14/2001 6.46 --94.06
6/22/2001 4.95 --95.57
10/16/2002 5.89 --94.63
4/20/2004 5.22 --95.30
6/22/2006 6.46 --94.06
3/2/2022 5.66 --1064.96
10/3/2022 6.42 -1064.20
4/13/2023 5.64 -1064.98
MW7
1064.72
MW6
98.39
1063.61
99.20
100.30
MW9
1070.62
100.52
MW8
1068.14
We
l
l

I
D
Da
t
e

W
a
t
e
r

L
e
v
e
l

Me
a
s
u
r
e
d

(
m
/
d
d
/
y
y
)
To
p

o
f

C
a
s
i
n
g

El
e
v
a
t
i
o
n
*

(
f
t
.
)
De
p
t
h

t
o

W
a
t
e
r

(
f
t
.

BS
G
)
Fr
e
e

P
r
o
d
u
c
t

Th
i
c
k
n
e
s
s

*
*

(
f
t
.
)
Gr
o
u
n
d
w
a
t
e
r

El
e
v
a
t
i
o
n
*

(
f
t
.
)
MW1 103.10
TABLE 5
Groundwater Level and Elevation Data
Mull Oil Bulk Plant
Alpha Project #23001.02 TF
ALPH
2/22/2002 6.03 --94.00
2/14/2001 5.77 --94.26
6/22/2001 5.30 --94.73
10/16/2002 5.90 --94.13
4/20/2004 4.66 --95.37
6/22/2006 6.04 --93.99
3/2/2022 5.56 --1065.00
7/7/2022 6.35 --1064.21
10/3/2022 6.21 -1064.35
1/24/2023 5.54 -1065.02
4/13/2023 6.27 -1064.29
2/22/2002 5.49 --94.45
2/14/2001 5.82 --94.12
6/22/2001 5.90 --94.04
10/16/2002 5.94 --94.00
4/20/2004 4.64 --95.30
6/22/2006 5.73 --94.21
3/2/2022 5.23 --1064.93
7/7/2022 6.10 --1064.06
10/3/2022 5.90 -1064.26
1/24/2023 5.25 -1064.91
4/13/2023 5.25 -1064.91
RW-1 7/6/2022 1001.00 8.67 --992.33
RW-2 7/7/2022 1081.00 6.47 --1074.53
of 0.729
MW11
1070.16
MW10D
1070.56
*Water level corrected for free product using specific gravity
99.94
100.03
Da
t
e
Co
n
t
r
a
c
t
o
r
We
l
l

I
D
Pr
o
u
d
u
c
t

Ty
p
e
Fr
e
e

Pr
o
u
d
u
c
t

Re
c
o
v
e
r
y

Me
t
h
o
d

Pr
o
d
u
c
t

Th
i
c
k
n
e
s
s

Be
f
o
r
e

R
e
c
o
v
e
r
y

(f
t
)
Pr
o
d
u
c
t

Th
i
c
k
n
e
s
s

Af
t
e
r

Re
c
o
v
e
r
y

(
f
t
)
Am
o
u
n
t

o
f

Li
q
u
i
d

Pr
o
d
u
c
t

(g
a
l
l
o
n
s
)
To
t
a
l

A
m
o
u
n
t

o
f

Pr
o
d
u
c
t

Re
c
o
v
e
r
e
d

(g
a
l
l
o
n
s
)
10
/
3
/
2
0
2
2
Al
p
h
a
MW
-
2
Ga
s
o
l
i
n
e
Ab
s
o
r
b
e
n
t
0.
0
1
0.
0
1
0.
0
5
0.
0
5
1/
2
4
/
2
0
2
3
Al
p
h
a
MW
-
2
Ga
s
o
l
i
n
e
Ab
s
o
r
b
e
n
t
0.
0
1
0.
0
1
0.
0
9
0.
0
9
4/
1
3
/
2
0
2
3
Al
p
h
a
MW
-
2
Ga
s
o
l
i
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Ab
s
o
r
b
e
n
t
0.
0
1
0.
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1
0.
1
3
0.
1
3
0.
0
9
0.
3
5
1/
2
4
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2
0
2
3
Ga
s
o
l
i
n
e
Ab
s
o
r
b
e
n
t
10
/
3
/
2
0
2
2
0.
0
5
0.
2
6
MW
-
2
Cu
m
u
l
a
t
i
v
e

T
o
t
a
l

o
f

V
o
l
u
m
e

R
e
c
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v
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r
e
d

t
o

Da
t
e

f
r
o
m

a
l
l

R
e
c
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v
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r
y

E
v
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n
t
s

(
g
a
l
l
o
n
s
)
To
t
a
l

V
o
l
u
m
e

R
e
c
o
v
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r
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d

f
r
o
m

S
i
t
e

D
u
r
i
n
g

Cu
r
r
e
n
t

R
e
c
o
v
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r
y

E
v
e
n
t

(
g
a
l
l
o
n
s
)
0.
2
1
0.
2
1
TA
B
L
E

6
FR
E
E

P
R
O
D
U
C
T

R
E
C
O
V
E
R
Y

I
N
F
O
R
M
A
T
I
O
N
Mu
l
l

O
i
l

B
u
l
k

P
l
a
n
t
Al
p
h
a

P
r
o
j
e
c
t

#

2
3
0
0
1
.
0
2

T
F
0.
4
2
4/
1
3
/
2
0
2
3
0.
1
3
0.
4
8
Da
t
e

o
f

R
e
c
o
v
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r
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E
v
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n
t
5/
2
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/
2
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-

8
/
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0
2
2
0.
0
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0.
2
1
0.
2
1
5/
2
0
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2
0
2
2
-
8/
4
/
2
0
2
2
Al
p
h
a
ALP
H
A
ALPHA Mull Oil Bulk Plant - GW Monitoring Report

12

APPENDICES

#=CL#
February 01, 2023
LIMS USE: FR - SARA ROSE
LIMS OBJECT ID: 92648469
92648469
Project:
Pace Project No.:
RE:
Ms. Sara Rose
Alpha Environmental Sciences
P.O. Box 2155
Asheville, NC 28801
MULL BULK OIL 23001.01
Dear Ms. Rose:
Enclosed are the analytical results for sample(s) received by the laboratory on January 24, 2023. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Sara Poulson
[e-mail]
Project Manager
[phone]
Enclosures
cc:Ms. Sara Rose, Alpha Environmental
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 1 of 31
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 31
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92648469001 MW-4 SM 6200B 63 PASI-CSAS
92648469002 MW-5 SM 6200B 63 PASI-CSAS
92648469003 MW-6 SM 6200B 63 PASI-CSAS
92648469004 MW-7 SM 6200B 63 PASI-CSAS
92648469005 MW-10D SM 6200B 63 PASI-CSAS
92648469006 MW-11 SM 6200B 63 PASI-CCL
92648469007 DUP-1 SM 6200B 63 PASI-CCL
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 3 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Sample:MW-4 Lab ID:92648469001 Collected:01/24/23 13:18 Received:01/24/23 16:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 15.7 ug/L 01/26/23 15:03 71-43-20.50 1
Bromobenzene ND ug/L 01/26/23 15:03 108-86-10.50 1
Bromochloromethane ND ug/L 01/26/23 15:03 74-97-50.50 1
Bromodichloromethane ND ug/L 01/26/23 15:03 75-27-40.50 1
Bromoform ND ug/L 01/26/23 15:03 75-25-20.50 1
Bromomethane ND ug/L 01/26/23 15:03 74-83-95.0 1
n-Butylbenzene ND ug/L 01/26/23 15:03 104-51-80.50 1
sec-Butylbenzene 2.0 ug/L 01/26/23 15:03 135-98-80.50 1
tert-Butylbenzene ND ug/L 01/26/23 15:03 98-06-60.50 1
Carbon tetrachloride ND ug/L 01/26/23 15:03 56-23-50.50 1
Chlorobenzene ND ug/L 01/26/23 15:03 108-90-70.50 1
Chloroethane ND ug/L 01/26/23 15:03 75-00-31.0 1
Chloroform ND ug/L 01/26/23 15:03 67-66-30.50 1
Chloromethane ND ug/L 01/26/23 15:03 74-87-31.0 1
2-Chlorotoluene ND ug/L 01/26/23 15:03 95-49-80.50 1
4-Chlorotoluene ND ug/L 01/26/23 15:03 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 01/26/23 15:03 96-12-81.0 1
Dibromochloromethane ND ug/L 01/26/23 15:03 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 01/26/23 15:03 106-93-40.50 1
Dibromomethane ND ug/L 01/26/23 15:03 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 01/26/23 15:03 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 01/26/23 15:03 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 01/26/23 15:03 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 01/26/23 15:03 75-71-80.50 1
1,1-Dichloroethane ND ug/L 01/26/23 15:03 75-34-30.50 1
1,2-Dichloroethane ND ug/L 01/26/23 15:03 107-06-20.50 1
1,1-Dichloroethene ND ug/L 01/26/23 15:03 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 01/26/23 15:03 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 01/26/23 15:03 156-60-50.50 1
1,2-Dichloropropane ND ug/L 01/26/23 15:03 78-87-50.50 1
1,3-Dichloropropane ND ug/L 01/26/23 15:03 142-28-90.50 1
2,2-Dichloropropane ND ug/L 01/26/23 15:03 594-20-70.50 1
1,1-Dichloropropene ND ug/L 01/26/23 15:03 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 01/26/23 15:03 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 01/26/23 15:03 10061-02-60.50 1
Diisopropyl ether 3.2 ug/L 01/26/23 15:03 108-20-30.50 1
Ethylbenzene ND ug/L 01/26/23 15:03 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 01/26/23 15:03 87-68-32.0 1
Isopropylbenzene (Cumene)1.8 ug/L 01/26/23 15:03 98-82-80.50 1
Methylene Chloride ND ug/L 01/26/23 15:03 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 01/26/23 15:03 1634-04-40.50 1
Naphthalene ND ug/L 01/26/23 15:03 91-20-32.0 1
n-Propylbenzene 0.58 ug/L 01/26/23 15:03 103-65-10.50 1
Styrene ND ug/L 01/26/23 15:03 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 01/26/23 15:03 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 01/26/23 15:03 79-34-50.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 4 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Sample:MW-4 Lab ID:92648469001 Collected:01/24/23 13:18 Received:01/24/23 16:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Tetrachloroethene ND ug/L 01/26/23 15:03 127-18-40.50 1
Toluene 1.3 ug/L 01/26/23 15:03 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 01/26/23 15:03 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 01/26/23 15:03 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 01/26/23 15:03 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 01/26/23 15:03 79-00-50.50 1
Trichloroethene ND ug/L 01/26/23 15:03 79-01-60.50 1
Trichlorofluoromethane ND ug/L 01/26/23 15:03 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 01/26/23 15:03 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 01/26/23 15:03 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 01/26/23 15:03 108-67-80.50 1
Vinyl chloride ND ug/L 01/26/23 15:03 75-01-41.0 1
m&p-Xylene 2.6 ug/L 01/26/23 15:03 179601-23-11.0 1
o-Xylene 0.70 ug/L 01/26/23 15:03 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)97 %01/26/23 15:03 17060-07-070-130 1
4-Bromofluorobenzene (S)100 %01/26/23 15:03 460-00-470-130 1
Toluene-d8 (S)101 %01/26/23 15:03 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 5 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Sample:MW-5 Lab ID:92648469002 Collected:01/24/23 13:55 Received:01/24/23 16:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 01/26/23 15:21 71-43-20.50 1
Bromobenzene ND ug/L 01/26/23 15:21 108-86-10.50 1
Bromochloromethane ND ug/L 01/26/23 15:21 74-97-50.50 1
Bromodichloromethane ND ug/L 01/26/23 15:21 75-27-40.50 1
Bromoform ND ug/L 01/26/23 15:21 75-25-20.50 1
Bromomethane ND ug/L 01/26/23 15:21 74-83-95.0 1
n-Butylbenzene ND ug/L 01/26/23 15:21 104-51-80.50 1
sec-Butylbenzene ND ug/L 01/26/23 15:21 135-98-80.50 1
tert-Butylbenzene ND ug/L 01/26/23 15:21 98-06-60.50 1
Carbon tetrachloride ND ug/L 01/26/23 15:21 56-23-50.50 1
Chlorobenzene ND ug/L 01/26/23 15:21 108-90-70.50 1
Chloroethane ND ug/L 01/26/23 15:21 75-00-31.0 1
Chloroform ND ug/L 01/26/23 15:21 67-66-30.50 1
Chloromethane ND ug/L 01/26/23 15:21 74-87-31.0 1
2-Chlorotoluene ND ug/L 01/26/23 15:21 95-49-80.50 1
4-Chlorotoluene ND ug/L 01/26/23 15:21 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 01/26/23 15:21 96-12-81.0 1
Dibromochloromethane ND ug/L 01/26/23 15:21 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 01/26/23 15:21 106-93-40.50 1
Dibromomethane ND ug/L 01/26/23 15:21 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 01/26/23 15:21 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 01/26/23 15:21 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 01/26/23 15:21 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 01/26/23 15:21 75-71-80.50 1
1,1-Dichloroethane ND ug/L 01/26/23 15:21 75-34-30.50 1
1,2-Dichloroethane ND ug/L 01/26/23 15:21 107-06-20.50 1
1,1-Dichloroethene ND ug/L 01/26/23 15:21 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 01/26/23 15:21 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 01/26/23 15:21 156-60-50.50 1
1,2-Dichloropropane ND ug/L 01/26/23 15:21 78-87-50.50 1
1,3-Dichloropropane ND ug/L 01/26/23 15:21 142-28-90.50 1
2,2-Dichloropropane ND ug/L 01/26/23 15:21 594-20-70.50 1
1,1-Dichloropropene ND ug/L 01/26/23 15:21 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 01/26/23 15:21 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 01/26/23 15:21 10061-02-60.50 1
Diisopropyl ether 12.8 ug/L 01/26/23 15:21 108-20-30.50 1
Ethylbenzene ND ug/L 01/26/23 15:21 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 01/26/23 15:21 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 01/26/23 15:21 98-82-80.50 1
Methylene Chloride ND ug/L 01/26/23 15:21 75-09-22.0 1
Methyl-tert-butyl ether 5.1 ug/L 01/26/23 15:21 1634-04-40.50 1
Naphthalene ND ug/L 01/26/23 15:21 91-20-32.0 1
n-Propylbenzene ND ug/L 01/26/23 15:21 103-65-10.50 1
Styrene ND ug/L 01/26/23 15:21 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 01/26/23 15:21 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 01/26/23 15:21 79-34-50.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 6 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Sample:MW-5 Lab ID:92648469002 Collected:01/24/23 13:55 Received:01/24/23 16:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Tetrachloroethene ND ug/L 01/26/23 15:21 127-18-40.50 1
Toluene ND ug/L 01/26/23 15:21 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 01/26/23 15:21 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 01/26/23 15:21 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 01/26/23 15:21 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 01/26/23 15:21 79-00-50.50 1
Trichloroethene ND ug/L 01/26/23 15:21 79-01-60.50 1
Trichlorofluoromethane ND ug/L 01/26/23 15:21 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 01/26/23 15:21 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 01/26/23 15:21 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 01/26/23 15:21 108-67-80.50 1
Vinyl chloride ND ug/L 01/26/23 15:21 75-01-41.0 1
m&p-Xylene ND ug/L 01/26/23 15:21 179601-23-11.0 1
o-Xylene ND ug/L 01/26/23 15:21 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)92 %01/26/23 15:21 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %01/26/23 15:21 460-00-470-130 1
Toluene-d8 (S)101 %01/26/23 15:21 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 7 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Sample:MW-6 Lab ID:92648469003 Collected:01/24/23 14:20 Received:01/24/23 16:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 01/26/23 15:39 71-43-20.50 1
Bromobenzene ND ug/L 01/26/23 15:39 108-86-10.50 1
Bromochloromethane ND ug/L 01/26/23 15:39 74-97-50.50 1
Bromodichloromethane ND ug/L 01/26/23 15:39 75-27-40.50 1
Bromoform ND ug/L 01/26/23 15:39 75-25-20.50 1
Bromomethane ND ug/L 01/26/23 15:39 74-83-95.0 1
n-Butylbenzene ND ug/L 01/26/23 15:39 104-51-80.50 1
sec-Butylbenzene ND ug/L 01/26/23 15:39 135-98-80.50 1
tert-Butylbenzene ND ug/L 01/26/23 15:39 98-06-60.50 1
Carbon tetrachloride ND ug/L 01/26/23 15:39 56-23-50.50 1
Chlorobenzene ND ug/L 01/26/23 15:39 108-90-70.50 1
Chloroethane ND ug/L 01/26/23 15:39 75-00-31.0 1
Chloroform ND ug/L 01/26/23 15:39 67-66-30.50 1
Chloromethane ND ug/L 01/26/23 15:39 74-87-31.0 1
2-Chlorotoluene ND ug/L 01/26/23 15:39 95-49-80.50 1
4-Chlorotoluene ND ug/L 01/26/23 15:39 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 01/26/23 15:39 96-12-81.0 1
Dibromochloromethane ND ug/L 01/26/23 15:39 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 01/26/23 15:39 106-93-40.50 1
Dibromomethane ND ug/L 01/26/23 15:39 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 01/26/23 15:39 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 01/26/23 15:39 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 01/26/23 15:39 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 01/26/23 15:39 75-71-80.50 1
1,1-Dichloroethane ND ug/L 01/26/23 15:39 75-34-30.50 1
1,2-Dichloroethane ND ug/L 01/26/23 15:39 107-06-20.50 1
1,1-Dichloroethene ND ug/L 01/26/23 15:39 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 01/26/23 15:39 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 01/26/23 15:39 156-60-50.50 1
1,2-Dichloropropane ND ug/L 01/26/23 15:39 78-87-50.50 1
1,3-Dichloropropane ND ug/L 01/26/23 15:39 142-28-90.50 1
2,2-Dichloropropane ND ug/L 01/26/23 15:39 594-20-70.50 1
1,1-Dichloropropene ND ug/L 01/26/23 15:39 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 01/26/23 15:39 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 01/26/23 15:39 10061-02-60.50 1
Diisopropyl ether ND ug/L 01/26/23 15:39 108-20-30.50 1
Ethylbenzene ND ug/L 01/26/23 15:39 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 01/26/23 15:39 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 01/26/23 15:39 98-82-80.50 1
Methylene Chloride ND ug/L 01/26/23 15:39 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 01/26/23 15:39 1634-04-40.50 1
Naphthalene ND ug/L 01/26/23 15:39 91-20-32.0 1
n-Propylbenzene ND ug/L 01/26/23 15:39 103-65-10.50 1
Styrene ND ug/L 01/26/23 15:39 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 01/26/23 15:39 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 01/26/23 15:39 79-34-50.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 8 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Sample:MW-6 Lab ID:92648469003 Collected:01/24/23 14:20 Received:01/24/23 16:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Tetrachloroethene ND ug/L 01/26/23 15:39 127-18-40.50 1
Toluene ND ug/L 01/26/23 15:39 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 01/26/23 15:39 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 01/26/23 15:39 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 01/26/23 15:39 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 01/26/23 15:39 79-00-50.50 1
Trichloroethene ND ug/L 01/26/23 15:39 79-01-60.50 1
Trichlorofluoromethane ND ug/L 01/26/23 15:39 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 01/26/23 15:39 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 01/26/23 15:39 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 01/26/23 15:39 108-67-80.50 1
Vinyl chloride ND ug/L 01/26/23 15:39 75-01-41.0 1
m&p-Xylene ND ug/L 01/26/23 15:39 179601-23-11.0 1
o-Xylene ND ug/L 01/26/23 15:39 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)97 %01/26/23 15:39 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %01/26/23 15:39 460-00-470-130 1
Toluene-d8 (S)109 %01/26/23 15:39 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 9 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Sample:MW-7 Lab ID:92648469004 Collected:01/24/23 14:45 Received:01/24/23 16:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 01/26/23 15:57 71-43-20.50 1
Bromobenzene ND ug/L 01/26/23 15:57 108-86-10.50 1
Bromochloromethane ND ug/L 01/26/23 15:57 74-97-50.50 1
Bromodichloromethane ND ug/L 01/26/23 15:57 75-27-40.50 1
Bromoform ND ug/L 01/26/23 15:57 75-25-20.50 1
Bromomethane ND ug/L 01/26/23 15:57 74-83-95.0 1
n-Butylbenzene ND ug/L 01/26/23 15:57 104-51-80.50 1
sec-Butylbenzene ND ug/L 01/26/23 15:57 135-98-80.50 1
tert-Butylbenzene ND ug/L 01/26/23 15:57 98-06-60.50 1
Carbon tetrachloride ND ug/L 01/26/23 15:57 56-23-50.50 1
Chlorobenzene ND ug/L 01/26/23 15:57 108-90-70.50 1
Chloroethane ND ug/L 01/26/23 15:57 75-00-31.0 1
Chloroform ND ug/L 01/26/23 15:57 67-66-30.50 1
Chloromethane ND ug/L 01/26/23 15:57 74-87-31.0 1
2-Chlorotoluene ND ug/L 01/26/23 15:57 95-49-80.50 1
4-Chlorotoluene ND ug/L 01/26/23 15:57 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 01/26/23 15:57 96-12-81.0 1
Dibromochloromethane ND ug/L 01/26/23 15:57 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 01/26/23 15:57 106-93-40.50 1
Dibromomethane ND ug/L 01/26/23 15:57 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 01/26/23 15:57 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 01/26/23 15:57 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 01/26/23 15:57 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 01/26/23 15:57 75-71-80.50 1
1,1-Dichloroethane ND ug/L 01/26/23 15:57 75-34-30.50 1
1,2-Dichloroethane ND ug/L 01/26/23 15:57 107-06-20.50 1
1,1-Dichloroethene ND ug/L 01/26/23 15:57 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 01/26/23 15:57 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 01/26/23 15:57 156-60-50.50 1
1,2-Dichloropropane ND ug/L 01/26/23 15:57 78-87-50.50 1
1,3-Dichloropropane ND ug/L 01/26/23 15:57 142-28-90.50 1
2,2-Dichloropropane ND ug/L 01/26/23 15:57 594-20-70.50 1
1,1-Dichloropropene ND ug/L 01/26/23 15:57 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 01/26/23 15:57 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 01/26/23 15:57 10061-02-60.50 1
Diisopropyl ether ND ug/L 01/26/23 15:57 108-20-30.50 1
Ethylbenzene ND ug/L 01/26/23 15:57 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 01/26/23 15:57 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 01/26/23 15:57 98-82-80.50 1
Methylene Chloride ND ug/L 01/26/23 15:57 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 01/26/23 15:57 1634-04-40.50 1
Naphthalene ND ug/L 01/26/23 15:57 91-20-32.0 1
n-Propylbenzene ND ug/L 01/26/23 15:57 103-65-10.50 1
Styrene ND ug/L 01/26/23 15:57 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 01/26/23 15:57 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 01/26/23 15:57 79-34-50.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 10 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Sample:MW-7 Lab ID:92648469004 Collected:01/24/23 14:45 Received:01/24/23 16:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Tetrachloroethene ND ug/L 01/26/23 15:57 127-18-40.50 1
Toluene ND ug/L 01/26/23 15:57 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 01/26/23 15:57 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 01/26/23 15:57 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 01/26/23 15:57 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 01/26/23 15:57 79-00-50.50 1
Trichloroethene ND ug/L 01/26/23 15:57 79-01-60.50 1
Trichlorofluoromethane ND ug/L 01/26/23 15:57 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 01/26/23 15:57 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 01/26/23 15:57 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 01/26/23 15:57 108-67-80.50 1
Vinyl chloride ND ug/L 01/26/23 15:57 75-01-41.0 1
m&p-Xylene ND ug/L 01/26/23 15:57 179601-23-11.0 1
o-Xylene ND ug/L 01/26/23 15:57 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)98 %01/26/23 15:57 17060-07-070-130 1
4-Bromofluorobenzene (S)100 %01/26/23 15:57 460-00-470-130 1
Toluene-d8 (S)106 %01/26/23 15:57 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 11 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Sample:MW-10D Lab ID:92648469005 Collected:01/24/23 11:15 Received:01/24/23 16:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 01/26/23 16:15 71-43-20.50 1
Bromobenzene ND ug/L 01/26/23 16:15 108-86-10.50 1
Bromochloromethane ND ug/L 01/26/23 16:15 74-97-50.50 1
Bromodichloromethane ND ug/L 01/26/23 16:15 75-27-40.50 1
Bromoform ND ug/L 01/26/23 16:15 75-25-20.50 1
Bromomethane ND ug/L 01/26/23 16:15 74-83-9 M1,R15.0 1
n-Butylbenzene ND ug/L 01/26/23 16:15 104-51-80.50 1
sec-Butylbenzene ND ug/L 01/26/23 16:15 135-98-80.50 1
tert-Butylbenzene ND ug/L 01/26/23 16:15 98-06-60.50 1
Carbon tetrachloride ND ug/L 01/26/23 16:15 56-23-50.50 1
Chlorobenzene ND ug/L 01/26/23 16:15 108-90-70.50 1
Chloroethane ND ug/L 01/26/23 16:15 75-00-31.0 1
Chloroform ND ug/L 01/26/23 16:15 67-66-30.50 1
Chloromethane ND ug/L 01/26/23 16:15 74-87-31.0 1
2-Chlorotoluene ND ug/L 01/26/23 16:15 95-49-80.50 1
4-Chlorotoluene ND ug/L 01/26/23 16:15 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 01/26/23 16:15 96-12-81.0 1
Dibromochloromethane ND ug/L 01/26/23 16:15 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 01/26/23 16:15 106-93-4 M10.50 1
Dibromomethane ND ug/L 01/26/23 16:15 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 01/26/23 16:15 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 01/26/23 16:15 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 01/26/23 16:15 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 01/26/23 16:15 75-71-80.50 1
1,1-Dichloroethane ND ug/L 01/26/23 16:15 75-34-30.50 1
1,2-Dichloroethane ND ug/L 01/26/23 16:15 107-06-20.50 1
1,1-Dichloroethene ND ug/L 01/26/23 16:15 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 01/26/23 16:15 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 01/26/23 16:15 156-60-50.50 1
1,2-Dichloropropane ND ug/L 01/26/23 16:15 78-87-50.50 1
1,3-Dichloropropane ND ug/L 01/26/23 16:15 142-28-9 M10.50 1
2,2-Dichloropropane ND ug/L 01/26/23 16:15 594-20-70.50 1
1,1-Dichloropropene ND ug/L 01/26/23 16:15 563-58-6 M10.50 1
cis-1,3-Dichloropropene ND ug/L 01/26/23 16:15 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 01/26/23 16:15 10061-02-60.50 1
Diisopropyl ether ND ug/L 01/26/23 16:15 108-20-30.50 1
Ethylbenzene ND ug/L 01/26/23 16:15 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 01/26/23 16:15 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 01/26/23 16:15 98-82-8 M10.50 1
Methylene Chloride ND ug/L 01/26/23 16:15 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 01/26/23 16:15 1634-04-40.50 1
Naphthalene ND ug/L 01/26/23 16:15 91-20-32.0 1
n-Propylbenzene ND ug/L 01/26/23 16:15 103-65-10.50 1
Styrene ND ug/L 01/26/23 16:15 100-42-5 M10.50 1
1,1,1,2-Tetrachloroethane ND ug/L 01/26/23 16:15 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 01/26/23 16:15 79-34-50.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 12 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Sample:MW-10D Lab ID:92648469005 Collected:01/24/23 11:15 Received:01/24/23 16:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Tetrachloroethene ND ug/L 01/26/23 16:15 127-18-4 M10.50 1
Toluene ND ug/L 01/26/23 16:15 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 01/26/23 16:15 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 01/26/23 16:15 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 01/26/23 16:15 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 01/26/23 16:15 79-00-50.50 1
Trichloroethene ND ug/L 01/26/23 16:15 79-01-60.50 1
Trichlorofluoromethane ND ug/L 01/26/23 16:15 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 01/26/23 16:15 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 01/26/23 16:15 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 01/26/23 16:15 108-67-80.50 1
Vinyl chloride ND ug/L 01/26/23 16:15 75-01-41.0 1
m&p-Xylene ND ug/L 01/26/23 16:15 179601-23-11.0 1
o-Xylene ND ug/L 01/26/23 16:15 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)96 %01/26/23 16:15 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %01/26/23 16:15 460-00-470-130 1
Toluene-d8 (S)106 %01/26/23 16:15 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 13 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Sample:MW-11 Lab ID:92648469006 Collected:01/24/23 12:00 Received:01/24/23 16:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 202 ug/L 01/31/23 04:07 71-43-21.0 2
Bromobenzene ND ug/L 01/31/23 04:07 108-86-11.0 2
Bromochloromethane ND ug/L 01/31/23 04:07 74-97-51.0 2
Bromodichloromethane ND ug/L 01/31/23 04:07 75-27-41.0 2
Bromoform ND ug/L 01/31/23 04:07 75-25-21.0 2
Bromomethane ND ug/L 01/31/23 04:07 74-83-910.0 2
n-Butylbenzene ND ug/L 01/31/23 04:07 104-51-81.0 2
sec-Butylbenzene ND ug/L 01/31/23 04:07 135-98-81.0 2
tert-Butylbenzene ND ug/L 01/31/23 04:07 98-06-61.0 2
Carbon tetrachloride ND ug/L 01/31/23 04:07 56-23-51.0 2
Chlorobenzene ND ug/L 01/31/23 04:07 108-90-71.0 2
Chloroethane ND ug/L 01/31/23 04:07 75-00-32.0 2
Chloroform ND ug/L 01/31/23 04:07 67-66-31.0 2
Chloromethane ND ug/L 01/31/23 04:07 74-87-32.0 2
2-Chlorotoluene ND ug/L 01/31/23 04:07 95-49-81.0 2
4-Chlorotoluene ND ug/L 01/31/23 04:07 106-43-41.0 2
1,2-Dibromo-3-chloropropane ND ug/L 01/31/23 04:07 96-12-82.0 2
Dibromochloromethane ND ug/L 01/31/23 04:07 124-48-11.0 2
1,2-Dibromoethane (EDB)ND ug/L 01/31/23 04:07 106-93-41.0 2
Dibromomethane ND ug/L 01/31/23 04:07 74-95-31.0 2
1,2-Dichlorobenzene ND ug/L 01/31/23 04:07 95-50-11.0 2
1,3-Dichlorobenzene ND ug/L 01/31/23 04:07 541-73-11.0 2
1,4-Dichlorobenzene ND ug/L 01/31/23 04:07 106-46-71.0 2
Dichlorodifluoromethane ND ug/L 01/31/23 04:07 75-71-81.0 2
1,1-Dichloroethane ND ug/L 01/31/23 04:07 75-34-31.0 2
1,2-Dichloroethane ND ug/L 01/31/23 04:07 107-06-21.0 2
1,1-Dichloroethene ND ug/L 01/31/23 04:07 75-35-41.0 2
cis-1,2-Dichloroethene ND ug/L 01/31/23 04:07 156-59-21.0 2
trans-1,2-Dichloroethene ND ug/L 01/31/23 04:07 156-60-51.0 2
1,2-Dichloropropane ND ug/L 01/31/23 04:07 78-87-51.0 2
1,3-Dichloropropane ND ug/L 01/31/23 04:07 142-28-91.0 2
2,2-Dichloropropane ND ug/L 01/31/23 04:07 594-20-71.0 2
1,1-Dichloropropene ND ug/L 01/31/23 04:07 563-58-61.0 2
cis-1,3-Dichloropropene ND ug/L 01/31/23 04:07 10061-01-51.0 2
trans-1,3-Dichloropropene ND ug/L 01/31/23 04:07 10061-02-61.0 2
Diisopropyl ether 139 ug/L 01/31/23 04:07 108-20-31.0 2
Ethylbenzene 3.1 ug/L 01/31/23 04:07 100-41-41.0 2
Hexachloro-1,3-butadiene ND ug/L 01/31/23 04:07 87-68-34.0 2
Isopropylbenzene (Cumene)5.7 ug/L 01/31/23 04:07 98-82-81.0 2
Methylene Chloride ND ug/L 01/31/23 04:07 75-09-24.0 2
Methyl-tert-butyl ether 93.3 ug/L 01/31/23 04:07 1634-04-41.0 2
Naphthalene 38.2 ug/L 01/31/23 04:07 91-20-34.0 2
n-Propylbenzene 3.2 ug/L 01/31/23 04:07 103-65-11.0 2
Styrene ND ug/L 01/31/23 04:07 100-42-51.0 2
1,1,1,2-Tetrachloroethane ND ug/L 01/31/23 04:07 630-20-61.0 2
1,1,2,2-Tetrachloroethane ND ug/L 01/31/23 04:07 79-34-51.0 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 14 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Sample:MW-11 Lab ID:92648469006 Collected:01/24/23 12:00 Received:01/24/23 16:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Tetrachloroethene ND ug/L 01/31/23 04:07 127-18-41.0 2
Toluene 10.2 ug/L 01/31/23 04:07 108-88-31.0 2
1,2,3-Trichlorobenzene ND ug/L 01/31/23 04:07 87-61-64.0 2
1,2,4-Trichlorobenzene ND ug/L 01/31/23 04:07 120-82-14.0 2
1,1,1-Trichloroethane ND ug/L 01/31/23 04:07 71-55-61.0 2
1,1,2-Trichloroethane ND ug/L 01/31/23 04:07 79-00-51.0 2
Trichloroethene ND ug/L 01/31/23 04:07 79-01-61.0 2
Trichlorofluoromethane ND ug/L 01/31/23 04:07 75-69-42.0 2
1,2,3-Trichloropropane ND ug/L 01/31/23 04:07 96-18-41.0 2
1,2,4-Trimethylbenzene ND ug/L 01/31/23 04:07 95-63-61.0 2
1,3,5-Trimethylbenzene 6.8 ug/L 01/31/23 04:07 108-67-81.0 2
Vinyl chloride ND ug/L 01/31/23 04:07 75-01-42.0 2
m&p-Xylene 22.3 ug/L 01/31/23 04:07 179601-23-12.0 2
o-Xylene 1.0 ug/L 01/31/23 04:07 95-47-61.0 2
Surrogates
1,2-Dichloroethane-d4 (S)114 %01/31/23 04:07 17060-07-070-130 2
4-Bromofluorobenzene (S)102 %01/31/23 04:07 460-00-470-130 2
Toluene-d8 (S)97 %01/31/23 04:07 2037-26-570-130 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 15 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Sample:DUP-1 Lab ID:92648469007 Collected:01/24/23 12:00 Received:01/24/23 16:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 207 ug/L 01/31/23 04:44 71-43-21.0 2
Bromobenzene ND ug/L 01/31/23 04:44 108-86-11.0 2
Bromochloromethane ND ug/L 01/31/23 04:44 74-97-51.0 2
Bromodichloromethane ND ug/L 01/31/23 04:44 75-27-41.0 2
Bromoform ND ug/L 01/31/23 04:44 75-25-21.0 2
Bromomethane ND ug/L 01/31/23 04:44 74-83-910.0 2
n-Butylbenzene ND ug/L 01/31/23 04:44 104-51-81.0 2
sec-Butylbenzene ND ug/L 01/31/23 04:44 135-98-81.0 2
tert-Butylbenzene ND ug/L 01/31/23 04:44 98-06-61.0 2
Carbon tetrachloride ND ug/L 01/31/23 04:44 56-23-51.0 2
Chlorobenzene ND ug/L 01/31/23 04:44 108-90-71.0 2
Chloroethane ND ug/L 01/31/23 04:44 75-00-32.0 2
Chloroform ND ug/L 01/31/23 04:44 67-66-31.0 2
Chloromethane ND ug/L 01/31/23 04:44 74-87-32.0 2
2-Chlorotoluene ND ug/L 01/31/23 04:44 95-49-81.0 2
4-Chlorotoluene ND ug/L 01/31/23 04:44 106-43-41.0 2
1,2-Dibromo-3-chloropropane ND ug/L 01/31/23 04:44 96-12-82.0 2
Dibromochloromethane ND ug/L 01/31/23 04:44 124-48-11.0 2
1,2-Dibromoethane (EDB)ND ug/L 01/31/23 04:44 106-93-41.0 2
Dibromomethane ND ug/L 01/31/23 04:44 74-95-31.0 2
1,2-Dichlorobenzene ND ug/L 01/31/23 04:44 95-50-11.0 2
1,3-Dichlorobenzene ND ug/L 01/31/23 04:44 541-73-11.0 2
1,4-Dichlorobenzene ND ug/L 01/31/23 04:44 106-46-71.0 2
Dichlorodifluoromethane ND ug/L 01/31/23 04:44 75-71-81.0 2
1,1-Dichloroethane ND ug/L 01/31/23 04:44 75-34-31.0 2
1,2-Dichloroethane ND ug/L 01/31/23 04:44 107-06-21.0 2
1,1-Dichloroethene ND ug/L 01/31/23 04:44 75-35-41.0 2
cis-1,2-Dichloroethene ND ug/L 01/31/23 04:44 156-59-21.0 2
trans-1,2-Dichloroethene ND ug/L 01/31/23 04:44 156-60-51.0 2
1,2-Dichloropropane ND ug/L 01/31/23 04:44 78-87-51.0 2
1,3-Dichloropropane ND ug/L 01/31/23 04:44 142-28-91.0 2
2,2-Dichloropropane ND ug/L 01/31/23 04:44 594-20-71.0 2
1,1-Dichloropropene ND ug/L 01/31/23 04:44 563-58-61.0 2
cis-1,3-Dichloropropene ND ug/L 01/31/23 04:44 10061-01-51.0 2
trans-1,3-Dichloropropene ND ug/L 01/31/23 04:44 10061-02-61.0 2
Diisopropyl ether 139 ug/L 01/31/23 04:44 108-20-31.0 2
Ethylbenzene 3.1 ug/L 01/31/23 04:44 100-41-41.0 2
Hexachloro-1,3-butadiene ND ug/L 01/31/23 04:44 87-68-34.0 2
Isopropylbenzene (Cumene)5.9 ug/L 01/31/23 04:44 98-82-81.0 2
Methylene Chloride ND ug/L 01/31/23 04:44 75-09-24.0 2
Methyl-tert-butyl ether 92.0 ug/L 01/31/23 04:44 1634-04-41.0 2
Naphthalene 36.9 ug/L 01/31/23 04:44 91-20-34.0 2
n-Propylbenzene 3.1 ug/L 01/31/23 04:44 103-65-11.0 2
Styrene ND ug/L 01/31/23 04:44 100-42-51.0 2
1,1,1,2-Tetrachloroethane ND ug/L 01/31/23 04:44 630-20-61.0 2
1,1,2,2-Tetrachloroethane ND ug/L 01/31/23 04:44 79-34-51.0 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 16 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Sample:DUP-1 Lab ID:92648469007 Collected:01/24/23 12:00 Received:01/24/23 16:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Tetrachloroethene ND ug/L 01/31/23 04:44 127-18-41.0 2
Toluene 10.1 ug/L 01/31/23 04:44 108-88-31.0 2
1,2,3-Trichlorobenzene ND ug/L 01/31/23 04:44 87-61-64.0 2
1,2,4-Trichlorobenzene ND ug/L 01/31/23 04:44 120-82-14.0 2
1,1,1-Trichloroethane ND ug/L 01/31/23 04:44 71-55-61.0 2
1,1,2-Trichloroethane ND ug/L 01/31/23 04:44 79-00-51.0 2
Trichloroethene ND ug/L 01/31/23 04:44 79-01-61.0 2
Trichlorofluoromethane ND ug/L 01/31/23 04:44 75-69-42.0 2
1,2,3-Trichloropropane ND ug/L 01/31/23 04:44 96-18-41.0 2
1,2,4-Trimethylbenzene ND ug/L 01/31/23 04:44 95-63-61.0 2
1,3,5-Trimethylbenzene 7.0 ug/L 01/31/23 04:44 108-67-81.0 2
Vinyl chloride ND ug/L 01/31/23 04:44 75-01-42.0 2
m&p-Xylene 22.9 ug/L 01/31/23 04:44 179601-23-12.0 2
o-Xylene 1.1 ug/L 01/31/23 04:44 95-47-61.0 2
Surrogates
1,2-Dichloroethane-d4 (S)114 %01/31/23 04:44 17060-07-070-130 2
4-Bromofluorobenzene (S)101 %01/31/23 04:44 460-00-470-130 2
Toluene-d8 (S)97 %01/31/23 04:44 2037-26-570-130 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 17 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
751933
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92648469001, 92648469002, 92648469003, 92648469004, 92648469005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3907105
Associated Lab Samples:92648469001, 92648469002, 92648469003, 92648469004, 92648469005
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 01/26/23 13:33
1,1,1-Trichloroethane ug/L ND 0.50 01/26/23 13:33
1,1,2,2-Tetrachloroethane ug/L ND 0.50 01/26/23 13:33
1,1,2-Trichloroethane ug/L ND 0.50 01/26/23 13:33
1,1-Dichloroethane ug/L ND 0.50 01/26/23 13:33
1,1-Dichloroethene ug/L ND 0.50 01/26/23 13:33
1,1-Dichloropropene ug/L ND 0.50 01/26/23 13:33
1,2,3-Trichlorobenzene ug/L ND 2.0 01/26/23 13:33
1,2,3-Trichloropropane ug/L ND 0.50 01/26/23 13:33
1,2,4-Trichlorobenzene ug/L ND 2.0 01/26/23 13:33
1,2,4-Trimethylbenzene ug/L ND 0.50 01/26/23 13:33
1,2-Dibromo-3-chloropropane ug/L ND 1.0 01/26/23 13:33
1,2-Dibromoethane (EDB)ug/L ND 0.50 01/26/23 13:33
1,2-Dichlorobenzene ug/L ND 0.50 01/26/23 13:33
1,2-Dichloroethane ug/L ND 0.50 01/26/23 13:33
1,2-Dichloropropane ug/L ND 0.50 01/26/23 13:33
1,3,5-Trimethylbenzene ug/L ND 0.50 01/26/23 13:33
1,3-Dichlorobenzene ug/L ND 0.50 01/26/23 13:33
1,3-Dichloropropane ug/L ND 0.50 01/26/23 13:33
1,4-Dichlorobenzene ug/L ND 0.50 01/26/23 13:33
2,2-Dichloropropane ug/L ND 0.50 01/26/23 13:33
2-Chlorotoluene ug/L ND 0.50 01/26/23 13:33
4-Chlorotoluene ug/L ND 0.50 01/26/23 13:33
Benzene ug/L ND 0.50 01/26/23 13:33
Bromobenzene ug/L ND 0.50 01/26/23 13:33
Bromochloromethane ug/L ND 0.50 01/26/23 13:33
Bromodichloromethane ug/L ND 0.50 01/26/23 13:33
Bromoform ug/L ND 0.50 01/26/23 13:33
Bromomethane ug/L ND 5.0 01/26/23 13:33
Carbon tetrachloride ug/L ND 0.50 01/26/23 13:33
Chlorobenzene ug/L ND 0.50 01/26/23 13:33
Chloroethane ug/L ND 1.0 01/26/23 13:33
Chloroform ug/L ND 0.50 01/26/23 13:33
Chloromethane ug/L ND 1.0 01/26/23 13:33
cis-1,2-Dichloroethene ug/L ND 0.50 01/26/23 13:33
cis-1,3-Dichloropropene ug/L ND 0.50 01/26/23 13:33
Dibromochloromethane ug/L ND 0.50 01/26/23 13:33
Dibromomethane ug/L ND 0.50 01/26/23 13:33
Dichlorodifluoromethane ug/L ND 0.50 01/26/23 13:33
Diisopropyl ether ug/L ND 0.50 01/26/23 13:33
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 18 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3907105
Associated Lab Samples:92648469001, 92648469002, 92648469003, 92648469004, 92648469005
Matrix:Water
Analyzed
Ethylbenzene ug/L ND 0.50 01/26/23 13:33
Hexachloro-1,3-butadiene ug/L ND 2.0 01/26/23 13:33
Isopropylbenzene (Cumene)ug/L ND 0.50 01/26/23 13:33
m&p-Xylene ug/L ND 1.0 01/26/23 13:33
Methyl-tert-butyl ether ug/L ND 0.50 01/26/23 13:33
Methylene Chloride ug/L ND 2.0 01/26/23 13:33
n-Butylbenzene ug/L ND 0.50 01/26/23 13:33
n-Propylbenzene ug/L ND 0.50 01/26/23 13:33
Naphthalene ug/L ND 2.0 01/26/23 13:33
o-Xylene ug/L ND 0.50 01/26/23 13:33
sec-Butylbenzene ug/L ND 0.50 01/26/23 13:33
Styrene ug/L ND 0.50 01/26/23 13:33
tert-Butylbenzene ug/L ND 0.50 01/26/23 13:33
Tetrachloroethene ug/L ND 0.50 01/26/23 13:33
Toluene ug/L ND 0.50 01/26/23 13:33
trans-1,2-Dichloroethene ug/L ND 0.50 01/26/23 13:33
trans-1,3-Dichloropropene ug/L ND 0.50 01/26/23 13:33
Trichloroethene ug/L ND 0.50 01/26/23 13:33
Trichlorofluoromethane ug/L ND 1.0 01/26/23 13:33
Vinyl chloride ug/L ND 1.0 01/26/23 13:33
1,2-Dichloroethane-d4 (S)%91 70-130 01/26/23 13:33
4-Bromofluorobenzene (S)%99 70-130 01/26/23 13:33
Toluene-d8 (S)%108 70-130 01/26/23 13:33
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3907106LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 20.020 100 60-140
1,1,1-Trichloroethane ug/L 20.320 101 60-140
1,1,2,2-Tetrachloroethane ug/L 19.620 98 60-140
1,1,2-Trichloroethane ug/L 19.420 97 60-140
1,1-Dichloroethane ug/L 20.020 100 60-140
1,1-Dichloroethene ug/L 20.220 101 60-140
1,1-Dichloropropene ug/L 22.320 111 60-140
1,2,3-Trichlorobenzene ug/L 21.420 107 60-140
1,2,3-Trichloropropane ug/L 19.120 95 60-140
1,2,4-Trichlorobenzene ug/L 21.320 107 60-140
1,2,4-Trimethylbenzene ug/L 20.620 103 60-140
1,2-Dibromo-3-chloropropane ug/L 18.920 94 60-140
1,2-Dibromoethane (EDB)ug/L 20.320 102 60-140
1,2-Dichlorobenzene ug/L 20.520 103 60-140
1,2-Dichloroethane ug/L 17.920 90 60-140
1,2-Dichloropropane ug/L 19.920 99 60-140
1,3,5-Trimethylbenzene ug/L 21.420 107 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 19 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3907106LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 20.820 104 60-140
1,3-Dichloropropane ug/L 20.320 101 60-140
1,4-Dichlorobenzene ug/L 19.520 97 60-140
2,2-Dichloropropane ug/L 21.220 106 60-140
2-Chlorotoluene ug/L 21.420 107 60-140
4-Chlorotoluene ug/L 20.520 103 60-140
Benzene ug/L 19.420 97 60-140
Bromobenzene ug/L 19.520 97 60-140
Bromochloromethane ug/L 19.220 96 60-140
Bromodichloromethane ug/L 18.720 93 60-140
Bromoform ug/L 18.020 90 60-140
Bromomethane ug/L 17.920 90 60-140
Carbon tetrachloride ug/L 18.820 94 60-140
Chlorobenzene ug/L 20.020 100 60-140
Chloroethane ug/L 19.420 97 60-140
Chloroform ug/L 22.320 112 60-140
Chloromethane ug/L 15.520 77 60-140
cis-1,2-Dichloroethene ug/L 19.720 98 60-140
cis-1,3-Dichloropropene ug/L 21.320 106 60-140
Dibromochloromethane ug/L 19.820 99 60-140
Dibromomethane ug/L 18.220 91 60-140
Dichlorodifluoromethane ug/L 13.420 67 60-140
Diisopropyl ether ug/L 19.820 99 60-140
Ethylbenzene ug/L 19.920 99 60-140
Hexachloro-1,3-butadiene ug/L 20.620 103 60-140
Isopropylbenzene (Cumene)ug/L 19.520 97 60-140
m&p-Xylene ug/L 40.240 100 60-140
Methyl-tert-butyl ether ug/L 19.920 100 60-140
Methylene Chloride ug/L 15.220 76 60-140
n-Butylbenzene ug/L 22.620 113 60-140
n-Propylbenzene ug/L 20.520 102 60-140
Naphthalene ug/L 22.220 111 60-140
o-Xylene ug/L 19.420 97 60-140
sec-Butylbenzene ug/L 21.020 105 60-140
Styrene ug/L 20.520 103 60-140
tert-Butylbenzene ug/L 17.120 86 60-140
Tetrachloroethene ug/L 20.020 100 60-140
Toluene ug/L 18.420 92 60-140
trans-1,2-Dichloroethene ug/L 19.920 100 60-140
trans-1,3-Dichloropropene ug/L 19.620 98 60-140
Trichloroethene ug/L 20.520 102 60-140
Trichlorofluoromethane ug/L 16.220 81 60-140
Vinyl chloride ug/L 17.920 89 60-140
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%98 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 20 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3907107MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92648469005
3907108
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 108 60-140117 820ND21.6 23.3
1,1,1-Trichloroethane ug/L 20 122 60-140127 420ND24.3 25.3
1,1,2,2-Tetrachloroethane ug/L 20 112 60-140137 2020ND22.5 27.5
1,1,2-Trichloroethane ug/L 20 111 60-140114 320ND22.2 22.8
1,1-Dichloroethane ug/L 20 124 60-140111 1120ND24.7 22.1
1,1-Dichloroethene ug/L 20 114 60-140123 820ND22.7 24.6
1,1-Dichloropropene ug/L M12013560-140142 520ND27.0 28.4
1,2,3-Trichlorobenzene ug/L 20 118 60-140127 720ND23.7 25.5
1,2,3-Trichloropropane ug/L 20 114 60-140136 1820ND22.7 27.2
1,2,4-Trichlorobenzene ug/L 20 118 60-140121 320ND23.6 24.2
1,2,4-Trimethylbenzene ug/L 20 129 60-140128 120ND25.9 25.6
1,2-Dibromo-3-chloropropane ug/L 20 103 60-140105 220ND20.7 21.0
1,2-Dibromoethane (EDB)ug/L M12011760-140144 2020ND23.5 28.8
1,2-Dichlorobenzene ug/L 20 120 60-140121 120ND24.0 24.2
1,2-Dichloroethane ug/L 20 121 60-140125 320ND24.1 24.9
1,2-Dichloropropane ug/L 20 100 60-140124 2220ND20.0 24.9
1,3,5-Trimethylbenzene ug/L 20 127 60-140126 020ND25.4 25.3
1,3-Dichlorobenzene ug/L 20 121 60-140123 120ND24.3 24.5
1,3-Dichloropropane ug/L M12012160-140148 2020ND24.1 29.6
1,4-Dichlorobenzene ug/L 20 114 60-140115 120ND22.9 23.0
2,2-Dichloropropane ug/L 20 122 60-140128 520ND24.4 25.7
2-Chlorotoluene ug/L 20 126 60-140127 120ND25.2 25.3
4-Chlorotoluene ug/L 20 127 60-140127 020ND25.4 25.4
Benzene ug/L 20 107 60-140110 320ND21.3 22.1
Bromobenzene ug/L 20 118 60-140121 220ND23.7 24.2
Bromochloromethane ug/L 20 115 60-140120 520ND22.9 24.1
Bromodichloromethane ug/L 20 91 60-140107 1620ND18.2 21.4
Bromoform ug/L 20 90 60-140107 1720ND18.0 21.3
Bromomethane ug/L M1,R1204760-14065 3220ND9.5 13.0
Carbon tetrachloride ug/L 20 104 60-140113 820ND20.7 22.5
Chlorobenzene ug/L 20 117 60-140121 420ND23.4 24.2
Chloroethane ug/L 20 123 60-140129 520ND24.5 25.8
Chloroform ug/L 20 116 60-140121 420ND23.2 24.1
Chloromethane ug/L 20 83 60-14092 1120ND16.6 18.4
cis-1,2-Dichloroethene ug/L 20 124 60-140130 420ND24.8 25.9
cis-1,3-Dichloropropene ug/L 20 110 60-140114 420ND22.0 22.8
Dibromochloromethane ug/L 20 102 60-140125 2020ND20.4 24.9
Dibromomethane ug/L 20 90 60-140110 2020ND18.0 22.0
Dichlorodifluoromethane ug/L 20 78 60-14086 1020ND15.6 17.2
Diisopropyl ether ug/L 20 124 60-140107 1520ND24.9 21.4
Ethylbenzene ug/L 20 121 60-140126 520ND24.1 25.3
Hexachloro-1,3-butadiene ug/L 20 110 60-140115 420ND22.0 22.9
Isopropylbenzene (Cumene)ug/L M12011960-140148 2120ND23.9 29.6
m&p-Xylene ug/L 40 124 60-140129 440ND49.8 51.8
Methyl-tert-butyl ether ug/L 20 116 60-140102 1320ND23.3 20.4
Methylene Chloride ug/L 20 117 60-140111 620ND23.4 22.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 21 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3907107MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92648469005
3907108
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Butylbenzene ug/L 20 131 60-140131 020ND26.2 26.2
n-Propylbenzene ug/L 20 127 60-140127 020ND25.5 25.5
Naphthalene ug/L 20 131 60-140132 120ND26.2 26.5
o-Xylene ug/L 20 120 60-140138 1420ND24.1 27.6
sec-Butylbenzene ug/L 20 126 60-140128 220ND25.2 25.6
Styrene ug/L M12012260-140141 1520ND24.4 28.3
tert-Butylbenzene ug/L 20 103 60-140105 220ND20.6 20.9
Tetrachloroethene ug/L M12011960-140145 2020ND23.7 29.0
Toluene ug/L 20 112 60-140117 420ND22.4 23.3
trans-1,2-Dichloroethene ug/L 20 130 60-140116 1120ND26.0 23.2
trans-1,3-Dichloropropene ug/L 20 111 60-140114 320ND22.1 22.9
Trichloroethene ug/L 20 119 60-140125 520ND23.8 24.9
Trichlorofluoromethane ug/L 20 94 60-14097 320ND18.8 19.4
Vinyl chloride ug/L 20 89 60-14095 720ND17.8 19.1
1,2-Dichloroethane-d4 (S)%106 70-130105
4-Bromofluorobenzene (S)%99 70-130119
Toluene-d8 (S)%98 70-13098
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 22 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
752228
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92648469006, 92648469007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3908762
Associated Lab Samples:92648469006, 92648469007
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 01/31/23 00:45
1,1,1-Trichloroethane ug/L ND 0.50 01/31/23 00:45
1,1,2,2-Tetrachloroethane ug/L ND 0.50 01/31/23 00:45
1,1,2-Trichloroethane ug/L ND 0.50 01/31/23 00:45
1,1-Dichloroethane ug/L ND 0.50 01/31/23 00:45
1,1-Dichloroethene ug/L ND 0.50 01/31/23 00:45
1,1-Dichloropropene ug/L ND 0.50 01/31/23 00:45
1,2,3-Trichlorobenzene ug/L ND 2.0 01/31/23 00:45
1,2,3-Trichloropropane ug/L ND 0.50 01/31/23 00:45
1,2,4-Trichlorobenzene ug/L ND 2.0 01/31/23 00:45
1,2,4-Trimethylbenzene ug/L ND 0.50 01/31/23 00:45
1,2-Dibromo-3-chloropropane ug/L ND 1.0 01/31/23 00:45
1,2-Dibromoethane (EDB)ug/L ND 0.50 01/31/23 00:45
1,2-Dichlorobenzene ug/L ND 0.50 01/31/23 00:45
1,2-Dichloroethane ug/L ND 0.50 01/31/23 00:45
1,2-Dichloropropane ug/L ND 0.50 01/31/23 00:45
1,3,5-Trimethylbenzene ug/L ND 0.50 01/31/23 00:45
1,3-Dichlorobenzene ug/L ND 0.50 01/31/23 00:45
1,3-Dichloropropane ug/L ND 0.50 01/31/23 00:45
1,4-Dichlorobenzene ug/L ND 0.50 01/31/23 00:45
2,2-Dichloropropane ug/L ND 0.50 01/31/23 00:45
2-Chlorotoluene ug/L ND 0.50 01/31/23 00:45
4-Chlorotoluene ug/L ND 0.50 01/31/23 00:45
Benzene ug/L ND 0.50 01/31/23 00:45
Bromobenzene ug/L ND 0.50 01/31/23 00:45
Bromochloromethane ug/L ND 0.50 01/31/23 00:45
Bromodichloromethane ug/L ND 0.50 01/31/23 00:45
Bromoform ug/L ND 0.50 01/31/23 00:45
Bromomethane ug/L ND 5.0 01/31/23 00:45
Carbon tetrachloride ug/L ND 0.50 01/31/23 00:45
Chlorobenzene ug/L ND 0.50 01/31/23 00:45
Chloroethane ug/L ND 1.0 01/31/23 00:45
Chloroform ug/L ND 0.50 01/31/23 00:45
Chloromethane ug/L ND 1.0 01/31/23 00:45
cis-1,2-Dichloroethene ug/L ND 0.50 01/31/23 00:45
cis-1,3-Dichloropropene ug/L ND 0.50 01/31/23 00:45
Dibromochloromethane ug/L ND 0.50 01/31/23 00:45
Dibromomethane ug/L ND 0.50 01/31/23 00:45
Dichlorodifluoromethane ug/L ND 0.50 01/31/23 00:45
Diisopropyl ether ug/L ND 0.50 01/31/23 00:45
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 23 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3908762
Associated Lab Samples:92648469006, 92648469007
Matrix:Water
Analyzed
Ethylbenzene ug/L ND 0.50 01/31/23 00:45
Hexachloro-1,3-butadiene ug/L ND 2.0 01/31/23 00:45
Isopropylbenzene (Cumene)ug/L ND 0.50 01/31/23 00:45
m&p-Xylene ug/L ND 1.0 01/31/23 00:45
Methyl-tert-butyl ether ug/L ND 0.50 01/31/23 00:45
Methylene Chloride ug/L ND 2.0 01/31/23 00:45
n-Butylbenzene ug/L ND 0.50 01/31/23 00:45
n-Propylbenzene ug/L ND 0.50 01/31/23 00:45
Naphthalene ug/L ND 2.0 01/31/23 00:45
o-Xylene ug/L ND 0.50 01/31/23 00:45
sec-Butylbenzene ug/L ND 0.50 01/31/23 00:45
Styrene ug/L ND 0.50 01/31/23 00:45
tert-Butylbenzene ug/L ND 0.50 01/31/23 00:45
Tetrachloroethene ug/L ND 0.50 01/31/23 00:45
Toluene ug/L ND 0.50 01/31/23 00:45
trans-1,2-Dichloroethene ug/L ND 0.50 01/31/23 00:45
trans-1,3-Dichloropropene ug/L ND 0.50 01/31/23 00:45
Trichloroethene ug/L ND 0.50 01/31/23 00:45
Trichlorofluoromethane ug/L ND 1.0 01/31/23 00:45
Vinyl chloride ug/L ND 1.0 01/31/23 00:45
1,2-Dichloroethane-d4 (S)%114 70-130 01/31/23 00:45
4-Bromofluorobenzene (S)%100 70-130 01/31/23 00:45
Toluene-d8 (S)%102 70-130 01/31/23 00:45
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3908763LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 21.620 108 60-140
1,1,1-Trichloroethane ug/L 23.020 115 60-140
1,1,2,2-Tetrachloroethane ug/L 22.920 114 60-140
1,1,2-Trichloroethane ug/L 22.220 111 60-140
1,1-Dichloroethane ug/L 22.220 111 60-140
1,1-Dichloroethene ug/L 20.620 103 60-140
1,1-Dichloropropene ug/L 24.220 121 60-140
1,2,3-Trichlorobenzene ug/L 22.820 114 60-140
1,2,3-Trichloropropane ug/L 23.720 118 60-140
1,2,4-Trichlorobenzene ug/L 21.520 107 60-140
1,2,4-Trimethylbenzene ug/L 23.120 116 60-140
1,2-Dibromo-3-chloropropane ug/L 19.720 98 60-140
1,2-Dibromoethane (EDB)ug/L 23.620 118 60-140
1,2-Dichlorobenzene ug/L 22.220 111 60-140
1,2-Dichloroethane ug/L 24.820 124 60-140
1,2-Dichloropropane ug/L 23.120 116 60-140
1,3,5-Trimethylbenzene ug/L 22.920 115 60-140
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
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Page 24 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3908763LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 22.020 110 60-140
1,3-Dichloropropane ug/L 23.720 118 60-140
1,4-Dichlorobenzene ug/L 21.120 105 60-140
2,2-Dichloropropane ug/L 21.120 106 60-140
2-Chlorotoluene ug/L 22.620 113 60-140
4-Chlorotoluene ug/L 22.920 114 60-140
Benzene ug/L 19.320 97 60-140
Bromobenzene ug/L 21.420 107 60-140
Bromochloromethane ug/L 22.020 110 60-140
Bromodichloromethane ug/L 20.820 104 60-140
Bromoform ug/L 18.820 94 60-140
Bromomethane ug/L 15.920 79 60-140
Carbon tetrachloride ug/L 19.620 98 60-140
Chlorobenzene ug/L 22.820 114 60-140
Chloroethane ug/L 23.420 117 60-140
Chloroform ug/L 21.220 106 60-140
Chloromethane ug/L 17.320 87 60-140
cis-1,2-Dichloroethene ug/L 23.020 115 60-140
cis-1,3-Dichloropropene ug/L 21.620 108 60-140
Dibromochloromethane ug/L 20.420 102 60-140
Dibromomethane ug/L 20.920 104 60-140
Dichlorodifluoromethane ug/L 15.120 75 60-140
Diisopropyl ether ug/L 23.020 115 60-140
Ethylbenzene ug/L 23.120 115 60-140
Hexachloro-1,3-butadiene ug/L 19.620 98 60-140
Isopropylbenzene (Cumene)ug/L 23.020 115 60-140
m&p-Xylene ug/L 46.840 117 60-140
Methyl-tert-butyl ether ug/L 22.320 111 60-140
Methylene Chloride ug/L 21.620 108 60-140
n-Butylbenzene ug/L 23.220 116 60-140
n-Propylbenzene ug/L 22.520 112 60-140
Naphthalene ug/L 24.720 124 60-140
o-Xylene ug/L 23.520 118 60-140
sec-Butylbenzene ug/L 22.420 112 60-140
Styrene ug/L 23.920 120 60-140
tert-Butylbenzene ug/L 18.620 93 60-140
Tetrachloroethene ug/L 21.520 107 60-140
Toluene ug/L 21.320 107 60-140
trans-1,2-Dichloroethene ug/L 22.520 113 60-140
trans-1,3-Dichloropropene ug/L 22.320 112 60-140
Trichloroethene ug/L 22.120 111 60-140
Trichlorofluoromethane ug/L 17.020 85 60-140
Vinyl chloride ug/L 15.720 78 60-140
1,2-Dichloroethane-d4 (S)%114 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%98 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
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[phone]
Page 25 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3908764MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92648316002
3908765
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 108 60-140110 220ND21.6 22.0
1,1,1-Trichloroethane ug/L 20 122 60-140118 320ND24.3 23.7
1,1,2,2-Tetrachloroethane ug/L 20 115 60-140115 020ND22.9 22.9
1,1,2-Trichloroethane ug/L 20 118 60-140119 120ND23.6 23.8
1,1-Dichloroethane ug/L 20 114 60-140117 220ND22.8 23.4
1,1-Dichloroethene ug/L 20 101 60-14096 520ND20.1 19.2
1,1-Dichloropropene ug/L 20 134 60-140131 320ND26.8 26.1
1,2,3-Trichlorobenzene ug/L 20 106 60-140131 2220ND21.2 26.3
1,2,3-Trichloropropane ug/L 20 116 60-140114 220ND23.2 22.8
1,2,4-Trichlorobenzene ug/L 20 108 60-140124 1320ND21.7 24.7
1,2,4-Trimethylbenzene ug/L 20 126 60-140126 020ND25.3 25.3
1,2-Dibromo-3-chloropropane ug/L 20 104 60-140104 020ND20.9 20.8
1,2-Dibromoethane (EDB)ug/L 20 119 60-140118 120ND23.8 23.6
1,2-Dichlorobenzene ug/L 20 120 60-140120 020ND23.9 24.0
1,2-Dichloroethane ug/L 20 122 60-140118 320ND24.3 23.5
1,2-Dichloropropane ug/L 20 127 60-140127 020ND25.4 25.5
1,3,5-Trimethylbenzene ug/L 20 126 60-140127 120ND25.2 25.4
1,3-Dichlorobenzene ug/L 20 120 60-140121 120ND24.1 24.3
1,3-Dichloropropane ug/L 20 121 60-140121 020ND24.2 24.2
1,4-Dichlorobenzene ug/L 20 112 60-140114 220ND22.3 22.9
2,2-Dichloropropane ug/L 20 124 60-140122 220ND24.8 24.3
2-Chlorotoluene ug/L 20 123 60-140125 120ND24.6 24.9
4-Chlorotoluene ug/L 20 126 60-140125 120ND25.1 25.0
Benzene ug/L 20 107 60-140108 120ND21.4 21.5
Bromobenzene ug/L 20 117 60-140117 020ND23.4 23.4
Bromochloromethane ug/L 20 111 60-140111 020ND22.2 22.3
Bromodichloromethane ug/L 20 110 60-140109 020ND21.9 21.9
Bromoform ug/L 20 93 60-14092 120ND18.5 18.3
Bromomethane ug/L 20 61 60-14064 520ND12.2 12.8
Carbon tetrachloride ug/L 20 110 60-140107 320ND22.0 21.3
Chlorobenzene ug/L 20 119 60-140119 020ND23.9 23.8
Chloroethane ug/L 20 112 60-140110 220ND22.4 21.9
Chloroform ug/L 20 120 60-140116 320ND24.0 23.3
Chloromethane ug/L 20 80 60-14079 120ND15.9 15.8
cis-1,2-Dichloroethene ug/L 20 120 60-140121 120ND24.0 24.2
cis-1,3-Dichloropropene ug/L 20 118 60-140119 120ND23.5 23.7
Dibromochloromethane ug/L 20 103 60-140102 120ND20.6 20.4
Dibromomethane ug/L 20 113 60-140111 220ND22.6 22.1
Dichlorodifluoromethane ug/L 20 69 60-14065 620ND13.8 12.9
Diisopropyl ether ug/L 20 114 60-140120 520ND23.0 24.1
Ethylbenzene ug/L 20 125 60-140123 220ND24.9 24.5
Hexachloro-1,3-butadiene ug/L 20 104 60-140114 920ND20.8 22.9
Isopropylbenzene (Cumene)ug/L 20 124 60-140122 220ND24.8 24.3
m&p-Xylene ug/L 40 127 60-140124 240ND50.7 49.5
Methyl-tert-butyl ether ug/L 20 107 60-140107 0205.9 27.3 27.2
Methylene Chloride ug/L 20 101 60-14094 720ND20.1 18.8
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3908764MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92648316002
3908765
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Butylbenzene ug/L 20 132 60-140131 120ND26.3 26.2
n-Propylbenzene ug/L 20 126 60-140125 020ND25.1 25.1
Naphthalene ug/L 20 114 60-140136 1820ND22.9 27.3
o-Xylene ug/L 20 126 60-140123 320ND25.3 24.6
sec-Butylbenzene ug/L 20 126 60-140127 120ND25.1 25.3
Styrene ug/L 20 127 60-140124 220ND25.4 24.9
tert-Butylbenzene ug/L 20 103 60-140104 020ND20.7 20.7
Tetrachloroethene ug/L 20 111 60-140117 520ND22.3 23.4
Toluene ug/L 20 118 60-140117 120ND23.6 23.4
trans-1,2-Dichloroethene ug/L 20 111 60-140109 220ND22.2 21.8
trans-1,3-Dichloropropene ug/L 20 118 60-140118 020ND23.6 23.7
Trichloroethene ug/L 20 124 60-140117 520ND24.7 23.4
Trichlorofluoromethane ug/L 20 84 60-14087 320ND16.9 17.4
Vinyl chloride ug/L 20 77 60-14078 120ND15.4 15.5
1,2-Dichloroethane-d4 (S)%109 70-130107
4-Bromofluorobenzene (S)%103 70-130101
Toluene-d8 (S)%102 70-130103
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
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Page 27 of 31
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
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Page 28 of 31
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92648469
MULL BULK OIL 23001.01
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92648469001 751933MW-4 SM 6200B
92648469002 751933MW-5 SM 6200B
92648469003 751933MW-6 SM 6200B
92648469004 751933MW-7 SM 6200B
92648469005 751933MW-10D SM 6200B
92648469006 752228MW-11 SM 6200B
92648469007 752228DUP-1 SM 6200B
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/01/2023 02:43 PM
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Page 29 of 31
Page 30 of 31
Page 31 of 31
#=CL#
April 21, 2023
LIMS USE: FR - SARA ROSE
LIMS OBJECT ID: 92662255
92662255
Project:
Pace Project No.:
RE:
Ms. Sara Rose
Alpha Environmental Sciences
P.O. Box 2155
Asheville, NC 28801
MULL BULK OIL PLANK 22130.02
Dear Ms. Rose:
Enclosed are the analytical results for sample(s) received by the laboratory on April 14, 2023. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Sara Poulson
[e-mail]
Project Manager
[phone]
Enclosures
cc:Ms. Sara Rose, Alpha Environmental
Cecil Utterback
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 1 of 27
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92662255
MULL BULK OIL PLANK 22130.02
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Asheville, NC 28804
[phone]
Page 2 of 27
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92662255
MULL BULK OIL PLANK 22130.02
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92662255001 MW-4 SM 6200B 63 PASI-CSAS
92662255002 MW-5 SM 6200B 63 PASI-CSAS
92662255003 MW-6 SM 6200B 63 PASI-CSAS
92662255004 MW-7 SM 6200B 63 PASI-CSAS
92662255005 MW-10D SM 6200B 63 PASI-CSAS
92662255006 MW-11 SM 6200B 63 PASI-CSAS
92662255007 DUP-1 SM 6200B 63 PASI-CSAS
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 3 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92662255
MULL BULK OIL PLANK 22130.02
Sample:MW-4 Lab ID:92662255001 Collected:04/13/23 12:51 Received:04/14/23 08:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 13.4 ug/L 04/20/23 17:06 71-43-20.50 1
Bromobenzene ND ug/L 04/20/23 17:06 108-86-10.50 1
Bromochloromethane ND ug/L 04/20/23 17:06 74-97-50.50 1
Bromodichloromethane ND ug/L 04/20/23 17:06 75-27-40.50 1
Bromoform ND ug/L 04/20/23 17:06 75-25-20.50 1
Bromomethane ND ug/L 04/20/23 17:06 74-83-95.0 1
n-Butylbenzene ND ug/L 04/20/23 17:06 104-51-80.50 1
sec-Butylbenzene 2.0 ug/L 04/20/23 17:06 135-98-80.50 1
tert-Butylbenzene ND ug/L 04/20/23 17:06 98-06-60.50 1
Carbon tetrachloride ND ug/L 04/20/23 17:06 56-23-50.50 1
Chlorobenzene ND ug/L 04/20/23 17:06 108-90-70.50 1
Chloroethane ND ug/L 04/20/23 17:06 75-00-31.0 1
Chloroform ND ug/L 04/20/23 17:06 67-66-30.50 1
Chloromethane ND ug/L 04/20/23 17:06 74-87-31.0 1
2-Chlorotoluene ND ug/L 04/20/23 17:06 95-49-80.50 1
4-Chlorotoluene ND ug/L 04/20/23 17:06 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 04/20/23 17:06 96-12-81.0 1
Dibromochloromethane ND ug/L 04/20/23 17:06 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 04/20/23 17:06 106-93-40.50 1
Dibromomethane ND ug/L 04/20/23 17:06 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 04/20/23 17:06 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 04/20/23 17:06 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 04/20/23 17:06 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 04/20/23 17:06 75-71-80.50 1
1,1-Dichloroethane ND ug/L 04/20/23 17:06 75-34-30.50 1
1,2-Dichloroethane ND ug/L 04/20/23 17:06 107-06-20.50 1
1,1-Dichloroethene ND ug/L 04/20/23 17:06 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 04/20/23 17:06 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 04/20/23 17:06 156-60-50.50 1
1,2-Dichloropropane ND ug/L 04/20/23 17:06 78-87-50.50 1
1,3-Dichloropropane ND ug/L 04/20/23 17:06 142-28-90.50 1
2,2-Dichloropropane ND ug/L 04/20/23 17:06 594-20-70.50 1
1,1-Dichloropropene ND ug/L 04/20/23 17:06 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 04/20/23 17:06 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 04/20/23 17:06 10061-02-60.50 1
Diisopropyl ether 2.3 ug/L 04/20/23 17:06 108-20-30.50 1
Ethylbenzene ND ug/L 04/20/23 17:06 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 04/20/23 17:06 87-68-3 IH,L12.0 1
Isopropylbenzene (Cumene)2.6 ug/L 04/20/23 17:06 98-82-80.50 1
Methylene Chloride ND ug/L 04/20/23 17:06 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 04/20/23 17:06 1634-04-40.50 1
Naphthalene ND ug/L 04/20/23 17:06 91-20-32.0 1
n-Propylbenzene 1.1 ug/L 04/20/23 17:06 103-65-10.50 1
Styrene ND ug/L 04/20/23 17:06 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 04/20/23 17:06 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 04/20/23 17:06 79-34-50.50 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/21/2023 02:28 PM
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Page 4 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92662255
MULL BULK OIL PLANK 22130.02
Sample:MW-4 Lab ID:92662255001 Collected:04/13/23 12:51 Received:04/14/23 08:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Tetrachloroethene ND ug/L 04/20/23 17:06 127-18-40.50 1
Toluene 1.2 ug/L 04/20/23 17:06 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 04/20/23 17:06 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 04/20/23 17:06 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 04/20/23 17:06 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 04/20/23 17:06 79-00-50.50 1
Trichloroethene ND ug/L 04/20/23 17:06 79-01-60.50 1
Trichlorofluoromethane ND ug/L 04/20/23 17:06 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 04/20/23 17:06 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 04/20/23 17:06 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 04/20/23 17:06 108-67-80.50 1
Vinyl chloride ND ug/L 04/20/23 17:06 75-01-41.0 1
m&p-Xylene 3.2 ug/L 04/20/23 17:06 179601-23-11.0 1
o-Xylene 0.60 ug/L 04/20/23 17:06 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)97 %04/20/23 17:06 17060-07-070-130 1
4-Bromofluorobenzene (S)101 %04/20/23 17:06 460-00-470-130 1
Toluene-d8 (S)103 %04/20/23 17:06 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/21/2023 02:28 PM
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Page 5 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92662255
MULL BULK OIL PLANK 22130.02
Sample:MW-5 Lab ID:92662255002 Collected:04/13/23 13:30 Received:04/14/23 08:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 04/20/23 17:24 71-43-20.50 1
Bromobenzene ND ug/L 04/20/23 17:24 108-86-10.50 1
Bromochloromethane ND ug/L 04/20/23 17:24 74-97-50.50 1
Bromodichloromethane ND ug/L 04/20/23 17:24 75-27-40.50 1
Bromoform ND ug/L 04/20/23 17:24 75-25-20.50 1
Bromomethane ND ug/L 04/20/23 17:24 74-83-95.0 1
n-Butylbenzene ND ug/L 04/20/23 17:24 104-51-80.50 1
sec-Butylbenzene ND ug/L 04/20/23 17:24 135-98-80.50 1
tert-Butylbenzene ND ug/L 04/20/23 17:24 98-06-60.50 1
Carbon tetrachloride ND ug/L 04/20/23 17:24 56-23-50.50 1
Chlorobenzene ND ug/L 04/20/23 17:24 108-90-70.50 1
Chloroethane ND ug/L 04/20/23 17:24 75-00-31.0 1
Chloroform ND ug/L 04/20/23 17:24 67-66-30.50 1
Chloromethane ND ug/L 04/20/23 17:24 74-87-31.0 1
2-Chlorotoluene ND ug/L 04/20/23 17:24 95-49-80.50 1
4-Chlorotoluene ND ug/L 04/20/23 17:24 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 04/20/23 17:24 96-12-81.0 1
Dibromochloromethane ND ug/L 04/20/23 17:24 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 04/20/23 17:24 106-93-40.50 1
Dibromomethane ND ug/L 04/20/23 17:24 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 04/20/23 17:24 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 04/20/23 17:24 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 04/20/23 17:24 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 04/20/23 17:24 75-71-80.50 1
1,1-Dichloroethane ND ug/L 04/20/23 17:24 75-34-30.50 1
1,2-Dichloroethane ND ug/L 04/20/23 17:24 107-06-20.50 1
1,1-Dichloroethene ND ug/L 04/20/23 17:24 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 04/20/23 17:24 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 04/20/23 17:24 156-60-50.50 1
1,2-Dichloropropane ND ug/L 04/20/23 17:24 78-87-50.50 1
1,3-Dichloropropane ND ug/L 04/20/23 17:24 142-28-90.50 1
2,2-Dichloropropane ND ug/L 04/20/23 17:24 594-20-70.50 1
1,1-Dichloropropene ND ug/L 04/20/23 17:24 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 04/20/23 17:24 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 04/20/23 17:24 10061-02-60.50 1
Diisopropyl ether 17.1 ug/L 04/20/23 17:24 108-20-30.50 1
Ethylbenzene ND ug/L 04/20/23 17:24 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 04/20/23 17:24 87-68-3 IH,L12.0 1
Isopropylbenzene (Cumene)ND ug/L 04/20/23 17:24 98-82-80.50 1
Methylene Chloride ND ug/L 04/20/23 17:24 75-09-22.0 1
Methyl-tert-butyl ether 6.9 ug/L 04/20/23 17:24 1634-04-40.50 1
Naphthalene ND ug/L 04/20/23 17:24 91-20-32.0 1
n-Propylbenzene ND ug/L 04/20/23 17:24 103-65-10.50 1
Styrene ND ug/L 04/20/23 17:24 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 04/20/23 17:24 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 04/20/23 17:24 79-34-50.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/21/2023 02:28 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 6 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92662255
MULL BULK OIL PLANK 22130.02
Sample:MW-5 Lab ID:92662255002 Collected:04/13/23 13:30 Received:04/14/23 08:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Tetrachloroethene ND ug/L 04/20/23 17:24 127-18-40.50 1
Toluene ND ug/L 04/20/23 17:24 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 04/20/23 17:24 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 04/20/23 17:24 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 04/20/23 17:24 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 04/20/23 17:24 79-00-50.50 1
Trichloroethene ND ug/L 04/20/23 17:24 79-01-60.50 1
Trichlorofluoromethane ND ug/L 04/20/23 17:24 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 04/20/23 17:24 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 04/20/23 17:24 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 04/20/23 17:24 108-67-80.50 1
Vinyl chloride ND ug/L 04/20/23 17:24 75-01-41.0 1
m&p-Xylene ND ug/L 04/20/23 17:24 179601-23-11.0 1
o-Xylene ND ug/L 04/20/23 17:24 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)97 %04/20/23 17:24 17060-07-070-130 1
4-Bromofluorobenzene (S)102 %04/20/23 17:24 460-00-470-130 1
Toluene-d8 (S)103 %04/20/23 17:24 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/21/2023 02:28 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 7 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92662255
MULL BULK OIL PLANK 22130.02
Sample:MW-6 Lab ID:92662255003 Collected:04/13/23 13:55 Received:04/14/23 08:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 04/20/23 17:42 71-43-20.50 1
Bromobenzene ND ug/L 04/20/23 17:42 108-86-10.50 1
Bromochloromethane ND ug/L 04/20/23 17:42 74-97-50.50 1
Bromodichloromethane ND ug/L 04/20/23 17:42 75-27-40.50 1
Bromoform ND ug/L 04/20/23 17:42 75-25-20.50 1
Bromomethane ND ug/L 04/20/23 17:42 74-83-95.0 1
n-Butylbenzene ND ug/L 04/20/23 17:42 104-51-80.50 1
sec-Butylbenzene ND ug/L 04/20/23 17:42 135-98-80.50 1
tert-Butylbenzene ND ug/L 04/20/23 17:42 98-06-60.50 1
Carbon tetrachloride ND ug/L 04/20/23 17:42 56-23-50.50 1
Chlorobenzene ND ug/L 04/20/23 17:42 108-90-70.50 1
Chloroethane ND ug/L 04/20/23 17:42 75-00-31.0 1
Chloroform ND ug/L 04/20/23 17:42 67-66-30.50 1
Chloromethane ND ug/L 04/20/23 17:42 74-87-31.0 1
2-Chlorotoluene ND ug/L 04/20/23 17:42 95-49-80.50 1
4-Chlorotoluene ND ug/L 04/20/23 17:42 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 04/20/23 17:42 96-12-81.0 1
Dibromochloromethane ND ug/L 04/20/23 17:42 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 04/20/23 17:42 106-93-40.50 1
Dibromomethane ND ug/L 04/20/23 17:42 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 04/20/23 17:42 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 04/20/23 17:42 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 04/20/23 17:42 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 04/20/23 17:42 75-71-80.50 1
1,1-Dichloroethane ND ug/L 04/20/23 17:42 75-34-30.50 1
1,2-Dichloroethane ND ug/L 04/20/23 17:42 107-06-20.50 1
1,1-Dichloroethene ND ug/L 04/20/23 17:42 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 04/20/23 17:42 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 04/20/23 17:42 156-60-50.50 1
1,2-Dichloropropane ND ug/L 04/20/23 17:42 78-87-50.50 1
1,3-Dichloropropane ND ug/L 04/20/23 17:42 142-28-90.50 1
2,2-Dichloropropane ND ug/L 04/20/23 17:42 594-20-70.50 1
1,1-Dichloropropene ND ug/L 04/20/23 17:42 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 04/20/23 17:42 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 04/20/23 17:42 10061-02-60.50 1
Diisopropyl ether ND ug/L 04/20/23 17:42 108-20-30.50 1
Ethylbenzene ND ug/L 04/20/23 17:42 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 04/20/23 17:42 87-68-3 IH,L12.0 1
Isopropylbenzene (Cumene)ND ug/L 04/20/23 17:42 98-82-80.50 1
Methylene Chloride ND ug/L 04/20/23 17:42 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 04/20/23 17:42 1634-04-40.50 1
Naphthalene ND ug/L 04/20/23 17:42 91-20-32.0 1
n-Propylbenzene ND ug/L 04/20/23 17:42 103-65-10.50 1
Styrene ND ug/L 04/20/23 17:42 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 04/20/23 17:42 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 04/20/23 17:42 79-34-50.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/21/2023 02:28 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 8 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92662255
MULL BULK OIL PLANK 22130.02
Sample:MW-6 Lab ID:92662255003 Collected:04/13/23 13:55 Received:04/14/23 08:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Tetrachloroethene ND ug/L 04/20/23 17:42 127-18-40.50 1
Toluene ND ug/L 04/20/23 17:42 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 04/20/23 17:42 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 04/20/23 17:42 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 04/20/23 17:42 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 04/20/23 17:42 79-00-50.50 1
Trichloroethene ND ug/L 04/20/23 17:42 79-01-60.50 1
Trichlorofluoromethane ND ug/L 04/20/23 17:42 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 04/20/23 17:42 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 04/20/23 17:42 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 04/20/23 17:42 108-67-80.50 1
Vinyl chloride ND ug/L 04/20/23 17:42 75-01-41.0 1
m&p-Xylene ND ug/L 04/20/23 17:42 179601-23-11.0 1
o-Xylene ND ug/L 04/20/23 17:42 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)92 %04/20/23 17:42 17060-07-070-130 1
4-Bromofluorobenzene (S)99 %04/20/23 17:42 460-00-470-130 1
Toluene-d8 (S)105 %04/20/23 17:42 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/21/2023 02:28 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 9 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92662255
MULL BULK OIL PLANK 22130.02
Sample:MW-7 Lab ID:92662255004 Collected:04/13/23 14:22 Received:04/14/23 08:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 04/20/23 18:00 71-43-20.50 1
Bromobenzene ND ug/L 04/20/23 18:00 108-86-10.50 1
Bromochloromethane ND ug/L 04/20/23 18:00 74-97-50.50 1
Bromodichloromethane ND ug/L 04/20/23 18:00 75-27-40.50 1
Bromoform ND ug/L 04/20/23 18:00 75-25-20.50 1
Bromomethane ND ug/L 04/20/23 18:00 74-83-95.0 1
n-Butylbenzene ND ug/L 04/20/23 18:00 104-51-80.50 1
sec-Butylbenzene ND ug/L 04/20/23 18:00 135-98-80.50 1
tert-Butylbenzene ND ug/L 04/20/23 18:00 98-06-60.50 1
Carbon tetrachloride ND ug/L 04/20/23 18:00 56-23-50.50 1
Chlorobenzene ND ug/L 04/20/23 18:00 108-90-70.50 1
Chloroethane ND ug/L 04/20/23 18:00 75-00-31.0 1
Chloroform ND ug/L 04/20/23 18:00 67-66-30.50 1
Chloromethane ND ug/L 04/20/23 18:00 74-87-31.0 1
2-Chlorotoluene ND ug/L 04/20/23 18:00 95-49-80.50 1
4-Chlorotoluene ND ug/L 04/20/23 18:00 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 04/20/23 18:00 96-12-81.0 1
Dibromochloromethane ND ug/L 04/20/23 18:00 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 04/20/23 18:00 106-93-40.50 1
Dibromomethane ND ug/L 04/20/23 18:00 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 04/20/23 18:00 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 04/20/23 18:00 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 04/20/23 18:00 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 04/20/23 18:00 75-71-80.50 1
1,1-Dichloroethane ND ug/L 04/20/23 18:00 75-34-30.50 1
1,2-Dichloroethane ND ug/L 04/20/23 18:00 107-06-20.50 1
1,1-Dichloroethene ND ug/L 04/20/23 18:00 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 04/20/23 18:00 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 04/20/23 18:00 156-60-50.50 1
1,2-Dichloropropane ND ug/L 04/20/23 18:00 78-87-50.50 1
1,3-Dichloropropane ND ug/L 04/20/23 18:00 142-28-90.50 1
2,2-Dichloropropane ND ug/L 04/20/23 18:00 594-20-70.50 1
1,1-Dichloropropene ND ug/L 04/20/23 18:00 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 04/20/23 18:00 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 04/20/23 18:00 10061-02-60.50 1
Diisopropyl ether ND ug/L 04/20/23 18:00 108-20-30.50 1
Ethylbenzene ND ug/L 04/20/23 18:00 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 04/20/23 18:00 87-68-3 IH,L12.0 1
Isopropylbenzene (Cumene)ND ug/L 04/20/23 18:00 98-82-80.50 1
Methylene Chloride ND ug/L 04/20/23 18:00 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 04/20/23 18:00 1634-04-40.50 1
Naphthalene ND ug/L 04/20/23 18:00 91-20-32.0 1
n-Propylbenzene ND ug/L 04/20/23 18:00 103-65-10.50 1
Styrene ND ug/L 04/20/23 18:00 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 04/20/23 18:00 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 04/20/23 18:00 79-34-50.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/21/2023 02:28 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 10 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92662255
MULL BULK OIL PLANK 22130.02
Sample:MW-7 Lab ID:92662255004 Collected:04/13/23 14:22 Received:04/14/23 08:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Tetrachloroethene ND ug/L 04/20/23 18:00 127-18-40.50 1
Toluene ND ug/L 04/20/23 18:00 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 04/20/23 18:00 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 04/20/23 18:00 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 04/20/23 18:00 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 04/20/23 18:00 79-00-50.50 1
Trichloroethene ND ug/L 04/20/23 18:00 79-01-60.50 1
Trichlorofluoromethane ND ug/L 04/20/23 18:00 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 04/20/23 18:00 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 04/20/23 18:00 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 04/20/23 18:00 108-67-80.50 1
Vinyl chloride ND ug/L 04/20/23 18:00 75-01-41.0 1
m&p-Xylene ND ug/L 04/20/23 18:00 179601-23-11.0 1
o-Xylene ND ug/L 04/20/23 18:00 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)96 %04/20/23 18:00 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %04/20/23 18:00 460-00-470-130 1
Toluene-d8 (S)103 %04/20/23 18:00 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/21/2023 02:28 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 11 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92662255
MULL BULK OIL PLANK 22130.02
Sample:MW-10D Lab ID:92662255005 Collected:04/13/23 11:40 Received:04/14/23 08:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 04/20/23 18:18 71-43-20.50 1
Bromobenzene ND ug/L 04/20/23 18:18 108-86-10.50 1
Bromochloromethane ND ug/L 04/20/23 18:18 74-97-50.50 1
Bromodichloromethane ND ug/L 04/20/23 18:18 75-27-40.50 1
Bromoform ND ug/L 04/20/23 18:18 75-25-20.50 1
Bromomethane ND ug/L 04/20/23 18:18 74-83-95.0 1
n-Butylbenzene ND ug/L 04/20/23 18:18 104-51-80.50 1
sec-Butylbenzene ND ug/L 04/20/23 18:18 135-98-80.50 1
tert-Butylbenzene ND ug/L 04/20/23 18:18 98-06-60.50 1
Carbon tetrachloride ND ug/L 04/20/23 18:18 56-23-50.50 1
Chlorobenzene ND ug/L 04/20/23 18:18 108-90-70.50 1
Chloroethane ND ug/L 04/20/23 18:18 75-00-31.0 1
Chloroform ND ug/L 04/20/23 18:18 67-66-30.50 1
Chloromethane ND ug/L 04/20/23 18:18 74-87-31.0 1
2-Chlorotoluene ND ug/L 04/20/23 18:18 95-49-80.50 1
4-Chlorotoluene ND ug/L 04/20/23 18:18 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 04/20/23 18:18 96-12-81.0 1
Dibromochloromethane ND ug/L 04/20/23 18:18 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 04/20/23 18:18 106-93-40.50 1
Dibromomethane ND ug/L 04/20/23 18:18 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 04/20/23 18:18 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 04/20/23 18:18 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 04/20/23 18:18 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 04/20/23 18:18 75-71-80.50 1
1,1-Dichloroethane ND ug/L 04/20/23 18:18 75-34-30.50 1
1,2-Dichloroethane ND ug/L 04/20/23 18:18 107-06-20.50 1
1,1-Dichloroethene ND ug/L 04/20/23 18:18 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 04/20/23 18:18 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 04/20/23 18:18 156-60-50.50 1
1,2-Dichloropropane ND ug/L 04/20/23 18:18 78-87-50.50 1
1,3-Dichloropropane ND ug/L 04/20/23 18:18 142-28-90.50 1
2,2-Dichloropropane ND ug/L 04/20/23 18:18 594-20-70.50 1
1,1-Dichloropropene ND ug/L 04/20/23 18:18 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 04/20/23 18:18 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 04/20/23 18:18 10061-02-60.50 1
Diisopropyl ether ND ug/L 04/20/23 18:18 108-20-30.50 1
Ethylbenzene ND ug/L 04/20/23 18:18 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 04/20/23 18:18 87-68-3 IH,L12.0 1
Isopropylbenzene (Cumene)ND ug/L 04/20/23 18:18 98-82-80.50 1
Methylene Chloride ND ug/L 04/20/23 18:18 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 04/20/23 18:18 1634-04-40.50 1
Naphthalene ND ug/L 04/20/23 18:18 91-20-32.0 1
n-Propylbenzene ND ug/L 04/20/23 18:18 103-65-10.50 1
Styrene ND ug/L 04/20/23 18:18 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 04/20/23 18:18 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 04/20/23 18:18 79-34-50.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/21/2023 02:28 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 12 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92662255
MULL BULK OIL PLANK 22130.02
Sample:MW-10D Lab ID:92662255005 Collected:04/13/23 11:40 Received:04/14/23 08:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Tetrachloroethene ND ug/L 04/20/23 18:18 127-18-40.50 1
Toluene ND ug/L 04/20/23 18:18 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 04/20/23 18:18 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 04/20/23 18:18 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 04/20/23 18:18 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 04/20/23 18:18 79-00-50.50 1
Trichloroethene ND ug/L 04/20/23 18:18 79-01-60.50 1
Trichlorofluoromethane ND ug/L 04/20/23 18:18 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 04/20/23 18:18 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 04/20/23 18:18 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 04/20/23 18:18 108-67-80.50 1
Vinyl chloride ND ug/L 04/20/23 18:18 75-01-41.0 1
m&p-Xylene ND ug/L 04/20/23 18:18 179601-23-11.0 1
o-Xylene ND ug/L 04/20/23 18:18 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)96 %04/20/23 18:18 17060-07-070-130 1
4-Bromofluorobenzene (S)96 %04/20/23 18:18 460-00-470-130 1
Toluene-d8 (S)104 %04/20/23 18:18 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/21/2023 02:28 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 13 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92662255
MULL BULK OIL PLANK 22130.02
Sample:MW-11 Lab ID:92662255006 Collected:04/13/23 10:30 Received:04/14/23 08:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 279 ug/L 04/20/23 18:54 71-43-21.0 2
Bromobenzene ND ug/L 04/20/23 18:54 108-86-11.0 2
Bromochloromethane ND ug/L 04/20/23 18:54 74-97-51.0 2
Bromodichloromethane ND ug/L 04/20/23 18:54 75-27-41.0 2
Bromoform ND ug/L 04/20/23 18:54 75-25-21.0 2
Bromomethane ND ug/L 04/20/23 18:54 74-83-910.0 2
n-Butylbenzene ND ug/L 04/20/23 18:54 104-51-81.0 2
sec-Butylbenzene ND ug/L 04/20/23 18:54 135-98-81.0 2
tert-Butylbenzene ND ug/L 04/20/23 18:54 98-06-61.0 2
Carbon tetrachloride ND ug/L 04/20/23 18:54 56-23-51.0 2
Chlorobenzene ND ug/L 04/20/23 18:54 108-90-71.0 2
Chloroethane ND ug/L 04/20/23 18:54 75-00-32.0 2
Chloroform ND ug/L 04/20/23 18:54 67-66-31.0 2
Chloromethane ND ug/L 04/20/23 18:54 74-87-32.0 2
2-Chlorotoluene ND ug/L 04/20/23 18:54 95-49-81.0 2
4-Chlorotoluene ND ug/L 04/20/23 18:54 106-43-41.0 2
1,2-Dibromo-3-chloropropane ND ug/L 04/20/23 18:54 96-12-82.0 2
Dibromochloromethane ND ug/L 04/20/23 18:54 124-48-11.0 2
1,2-Dibromoethane (EDB)ND ug/L 04/20/23 18:54 106-93-41.0 2
Dibromomethane ND ug/L 04/20/23 18:54 74-95-31.0 2
1,2-Dichlorobenzene ND ug/L 04/20/23 18:54 95-50-11.0 2
1,3-Dichlorobenzene ND ug/L 04/20/23 18:54 541-73-11.0 2
1,4-Dichlorobenzene ND ug/L 04/20/23 18:54 106-46-71.0 2
Dichlorodifluoromethane ND ug/L 04/20/23 18:54 75-71-81.0 2
1,1-Dichloroethane ND ug/L 04/20/23 18:54 75-34-31.0 2
1,2-Dichloroethane ND ug/L 04/20/23 18:54 107-06-21.0 2
1,1-Dichloroethene ND ug/L 04/20/23 18:54 75-35-41.0 2
cis-1,2-Dichloroethene ND ug/L 04/20/23 18:54 156-59-21.0 2
trans-1,2-Dichloroethene ND ug/L 04/20/23 18:54 156-60-51.0 2
1,2-Dichloropropane ND ug/L 04/20/23 18:54 78-87-51.0 2
1,3-Dichloropropane ND ug/L 04/20/23 18:54 142-28-91.0 2
2,2-Dichloropropane ND ug/L 04/20/23 18:54 594-20-71.0 2
1,1-Dichloropropene ND ug/L 04/20/23 18:54 563-58-61.0 2
cis-1,3-Dichloropropene ND ug/L 04/20/23 18:54 10061-01-51.0 2
trans-1,3-Dichloropropene ND ug/L 04/20/23 18:54 10061-02-61.0 2
Diisopropyl ether 125 ug/L 04/20/23 18:54 108-20-31.0 2
Ethylbenzene 5.5 ug/L 04/20/23 18:54 100-41-41.0 2
Hexachloro-1,3-butadiene ND ug/L 04/20/23 18:54 87-68-3 IH,L14.0 2
Isopropylbenzene (Cumene)8.1 ug/L 04/20/23 18:54 98-82-81.0 2
Methylene Chloride ND ug/L 04/20/23 18:54 75-09-24.0 2
Methyl-tert-butyl ether 71.8 ug/L 04/20/23 18:54 1634-04-41.0 2
Naphthalene 50.2 ug/L 04/20/23 18:54 91-20-34.0 2
n-Propylbenzene 5.4 ug/L 04/20/23 18:54 103-65-11.0 2
Styrene ND ug/L 04/20/23 18:54 100-42-51.0 2
1,1,1,2-Tetrachloroethane ND ug/L 04/20/23 18:54 630-20-61.0 2
1,1,2,2-Tetrachloroethane ND ug/L 04/20/23 18:54 79-34-51.0 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/21/2023 02:28 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 14 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92662255
MULL BULK OIL PLANK 22130.02
Sample:MW-11 Lab ID:92662255006 Collected:04/13/23 10:30 Received:04/14/23 08:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Tetrachloroethene ND ug/L 04/20/23 18:54 127-18-41.0 2
Toluene 9.7 ug/L 04/20/23 18:54 108-88-31.0 2
1,2,3-Trichlorobenzene ND ug/L 04/20/23 18:54 87-61-64.0 2
1,2,4-Trichlorobenzene ND ug/L 04/20/23 18:54 120-82-14.0 2
1,1,1-Trichloroethane ND ug/L 04/20/23 18:54 71-55-61.0 2
1,1,2-Trichloroethane ND ug/L 04/20/23 18:54 79-00-51.0 2
Trichloroethene ND ug/L 04/20/23 18:54 79-01-61.0 2
Trichlorofluoromethane ND ug/L 04/20/23 18:54 75-69-42.0 2
1,2,3-Trichloropropane ND ug/L 04/20/23 18:54 96-18-41.0 2
1,2,4-Trimethylbenzene ND ug/L 04/20/23 18:54 95-63-61.0 2
1,3,5-Trimethylbenzene ND ug/L 04/20/23 18:54 108-67-81.0 2
Vinyl chloride ND ug/L 04/20/23 18:54 75-01-42.0 2
m&p-Xylene 27.0 ug/L 04/20/23 18:54 179601-23-12.0 2
o-Xylene 1.5 ug/L 04/20/23 18:54 95-47-61.0 2
Surrogates
1,2-Dichloroethane-d4 (S)100 %04/20/23 18:54 17060-07-070-130 2
4-Bromofluorobenzene (S)100 %04/20/23 18:54 460-00-470-130 2
Toluene-d8 (S)97 %04/20/23 18:54 2037-26-570-130 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/21/2023 02:28 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 15 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92662255
MULL BULK OIL PLANK 22130.02
Sample:DUP-1 Lab ID:92662255007 Collected:04/13/23 10:30 Received:04/14/23 08:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 308 ug/L 04/20/23 19:12 71-43-21.0 2
Bromobenzene ND ug/L 04/20/23 19:12 108-86-11.0 2
Bromochloromethane ND ug/L 04/20/23 19:12 74-97-51.0 2
Bromodichloromethane ND ug/L 04/20/23 19:12 75-27-41.0 2
Bromoform ND ug/L 04/20/23 19:12 75-25-21.0 2
Bromomethane ND ug/L 04/20/23 19:12 74-83-910.0 2
n-Butylbenzene ND ug/L 04/20/23 19:12 104-51-81.0 2
sec-Butylbenzene ND ug/L 04/20/23 19:12 135-98-81.0 2
tert-Butylbenzene ND ug/L 04/20/23 19:12 98-06-61.0 2
Carbon tetrachloride ND ug/L 04/20/23 19:12 56-23-51.0 2
Chlorobenzene ND ug/L 04/20/23 19:12 108-90-71.0 2
Chloroethane ND ug/L 04/20/23 19:12 75-00-32.0 2
Chloroform ND ug/L 04/20/23 19:12 67-66-31.0 2
Chloromethane ND ug/L 04/20/23 19:12 74-87-32.0 2
2-Chlorotoluene ND ug/L 04/20/23 19:12 95-49-81.0 2
4-Chlorotoluene ND ug/L 04/20/23 19:12 106-43-41.0 2
1,2-Dibromo-3-chloropropane ND ug/L 04/20/23 19:12 96-12-82.0 2
Dibromochloromethane ND ug/L 04/20/23 19:12 124-48-11.0 2
1,2-Dibromoethane (EDB)ND ug/L 04/20/23 19:12 106-93-41.0 2
Dibromomethane ND ug/L 04/20/23 19:12 74-95-31.0 2
1,2-Dichlorobenzene ND ug/L 04/20/23 19:12 95-50-11.0 2
1,3-Dichlorobenzene ND ug/L 04/20/23 19:12 541-73-11.0 2
1,4-Dichlorobenzene ND ug/L 04/20/23 19:12 106-46-71.0 2
Dichlorodifluoromethane ND ug/L 04/20/23 19:12 75-71-81.0 2
1,1-Dichloroethane ND ug/L 04/20/23 19:12 75-34-31.0 2
1,2-Dichloroethane ND ug/L 04/20/23 19:12 107-06-21.0 2
1,1-Dichloroethene ND ug/L 04/20/23 19:12 75-35-41.0 2
cis-1,2-Dichloroethene ND ug/L 04/20/23 19:12 156-59-21.0 2
trans-1,2-Dichloroethene ND ug/L 04/20/23 19:12 156-60-51.0 2
1,2-Dichloropropane ND ug/L 04/20/23 19:12 78-87-51.0 2
1,3-Dichloropropane ND ug/L 04/20/23 19:12 142-28-91.0 2
2,2-Dichloropropane ND ug/L 04/20/23 19:12 594-20-71.0 2
1,1-Dichloropropene ND ug/L 04/20/23 19:12 563-58-61.0 2
cis-1,3-Dichloropropene ND ug/L 04/20/23 19:12 10061-01-51.0 2
trans-1,3-Dichloropropene ND ug/L 04/20/23 19:12 10061-02-61.0 2
Diisopropyl ether 131 ug/L 04/20/23 19:12 108-20-31.0 2
Ethylbenzene 7.9 ug/L 04/20/23 19:12 100-41-41.0 2
Hexachloro-1,3-butadiene ND ug/L 04/20/23 19:12 87-68-3 IH,L14.0 2
Isopropylbenzene (Cumene)8.5 ug/L 04/20/23 19:12 98-82-81.0 2
Methylene Chloride ND ug/L 04/20/23 19:12 75-09-24.0 2
Methyl-tert-butyl ether 74.7 ug/L 04/20/23 19:12 1634-04-41.0 2
Naphthalene 52.5 ug/L 04/20/23 19:12 91-20-34.0 2
n-Propylbenzene 5.9 ug/L 04/20/23 19:12 103-65-11.0 2
Styrene ND ug/L 04/20/23 19:12 100-42-51.0 2
1,1,1,2-Tetrachloroethane ND ug/L 04/20/23 19:12 630-20-61.0 2
1,1,2,2-Tetrachloroethane ND ug/L 04/20/23 19:12 79-34-51.0 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/21/2023 02:28 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 16 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92662255
MULL BULK OIL PLANK 22130.02
Sample:DUP-1 Lab ID:92662255007 Collected:04/13/23 10:30 Received:04/14/23 08:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Tetrachloroethene ND ug/L 04/20/23 19:12 127-18-41.0 2
Toluene 11.1 ug/L 04/20/23 19:12 108-88-31.0 2
1,2,3-Trichlorobenzene ND ug/L 04/20/23 19:12 87-61-64.0 2
1,2,4-Trichlorobenzene ND ug/L 04/20/23 19:12 120-82-14.0 2
1,1,1-Trichloroethane ND ug/L 04/20/23 19:12 71-55-61.0 2
1,1,2-Trichloroethane ND ug/L 04/20/23 19:12 79-00-51.0 2
Trichloroethene ND ug/L 04/20/23 19:12 79-01-61.0 2
Trichlorofluoromethane ND ug/L 04/20/23 19:12 75-69-42.0 2
1,2,3-Trichloropropane ND ug/L 04/20/23 19:12 96-18-41.0 2
1,2,4-Trimethylbenzene 3.2 ug/L 04/20/23 19:12 95-63-61.0 2
1,3,5-Trimethylbenzene ND ug/L 04/20/23 19:12 108-67-81.0 2
Vinyl chloride ND ug/L 04/20/23 19:12 75-01-42.0 2
m&p-Xylene 38.2 ug/L 04/20/23 19:12 179601-23-12.0 2
o-Xylene 6.5 ug/L 04/20/23 19:12 95-47-61.0 2
Surrogates
1,2-Dichloroethane-d4 (S)105 %04/20/23 19:12 17060-07-070-130 2
4-Bromofluorobenzene (S)99 %04/20/23 19:12 460-00-470-130 2
Toluene-d8 (S)98 %04/20/23 19:12 2037-26-570-130 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/21/2023 02:28 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 17 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92662255
MULL BULK OIL PLANK 22130.02
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
768964
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92662255001, 92662255002, 92662255003, 92662255004, 92662255005, 92662255006, 92662255007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3992343
Associated Lab Samples:92662255001, 92662255002, 92662255003, 92662255004, 92662255005, 92662255006, 92662255007
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 04/20/23 13:47
1,1,1-Trichloroethane ug/L ND 0.50 04/20/23 13:47
1,1,2,2-Tetrachloroethane ug/L ND 0.50 04/20/23 13:47
1,1,2-Trichloroethane ug/L ND 0.50 04/20/23 13:47
1,1-Dichloroethane ug/L ND 0.50 04/20/23 13:47
1,1-Dichloroethene ug/L ND 0.50 04/20/23 13:47
1,1-Dichloropropene ug/L ND 0.50 04/20/23 13:47
1,2,3-Trichlorobenzene ug/L ND 2.0 04/20/23 13:47
1,2,3-Trichloropropane ug/L ND 0.50 04/20/23 13:47
1,2,4-Trichlorobenzene ug/L ND 2.0 04/20/23 13:47
1,2,4-Trimethylbenzene ug/L ND 0.50 04/20/23 13:47
1,2-Dibromo-3-chloropropane ug/L ND 1.0 04/20/23 13:47
1,2-Dibromoethane (EDB)ug/L ND 0.50 04/20/23 13:47
1,2-Dichlorobenzene ug/L ND 0.50 04/20/23 13:47
1,2-Dichloroethane ug/L ND 0.50 04/20/23 13:47
1,2-Dichloropropane ug/L ND 0.50 04/20/23 13:47
1,3,5-Trimethylbenzene ug/L ND 0.50 04/20/23 13:47
1,3-Dichlorobenzene ug/L ND 0.50 04/20/23 13:47
1,3-Dichloropropane ug/L ND 0.50 04/20/23 13:47
1,4-Dichlorobenzene ug/L ND 0.50 04/20/23 13:47
2,2-Dichloropropane ug/L ND 0.50 04/20/23 13:47
2-Chlorotoluene ug/L ND 0.50 04/20/23 13:47
4-Chlorotoluene ug/L ND 0.50 04/20/23 13:47
Benzene ug/L ND 0.50 04/20/23 13:47
Bromobenzene ug/L ND 0.50 04/20/23 13:47
Bromochloromethane ug/L ND 0.50 04/20/23 13:47
Bromodichloromethane ug/L ND 0.50 04/20/23 13:47
Bromoform ug/L ND 0.50 04/20/23 13:47
Bromomethane ug/L ND 5.0 04/20/23 13:47
Carbon tetrachloride ug/L ND 0.50 04/20/23 13:47
Chlorobenzene ug/L ND 0.50 04/20/23 13:47
Chloroethane ug/L ND 1.0 04/20/23 13:47
Chloroform ug/L ND 0.50 04/20/23 13:47
Chloromethane ug/L ND 1.0 04/20/23 13:47
cis-1,2-Dichloroethene ug/L ND 0.50 04/20/23 13:47
cis-1,3-Dichloropropene ug/L ND 0.50 04/20/23 13:47
Dibromochloromethane ug/L ND 0.50 04/20/23 13:47
Dibromomethane ug/L ND 0.50 04/20/23 13:47
Dichlorodifluoromethane ug/L ND 0.50 04/20/23 13:47
Diisopropyl ether ug/L ND 0.50 04/20/23 13:47
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/21/2023 02:28 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 18 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92662255
MULL BULK OIL PLANK 22130.02
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3992343
Associated Lab Samples:92662255001, 92662255002, 92662255003, 92662255004, 92662255005, 92662255006, 92662255007
Matrix:Water
Analyzed
Ethylbenzene ug/L ND 0.50 04/20/23 13:47
Hexachloro-1,3-butadiene ug/L ND 2.0 IH04/20/23 13:47
Isopropylbenzene (Cumene)ug/L ND 0.50 04/20/23 13:47
m&p-Xylene ug/L ND 1.0 04/20/23 13:47
Methyl-tert-butyl ether ug/L ND 0.50 04/20/23 13:47
Methylene Chloride ug/L ND 2.0 04/20/23 13:47
n-Butylbenzene ug/L ND 0.50 04/20/23 13:47
n-Propylbenzene ug/L ND 0.50 04/20/23 13:47
Naphthalene ug/L ND 2.0 04/20/23 13:47
o-Xylene ug/L ND 0.50 04/20/23 13:47
sec-Butylbenzene ug/L ND 0.50 04/20/23 13:47
Styrene ug/L ND 0.50 04/20/23 13:47
tert-Butylbenzene ug/L ND 0.50 04/20/23 13:47
Tetrachloroethene ug/L ND 0.50 04/20/23 13:47
Toluene ug/L ND 0.50 04/20/23 13:47
trans-1,2-Dichloroethene ug/L ND 0.50 04/20/23 13:47
trans-1,3-Dichloropropene ug/L ND 0.50 04/20/23 13:47
Trichloroethene ug/L ND 0.50 04/20/23 13:47
Trichlorofluoromethane ug/L ND 1.0 04/20/23 13:47
Vinyl chloride ug/L ND 1.0 04/20/23 13:47
1,2-Dichloroethane-d4 (S)%95 70-130 04/20/23 13:47
4-Bromofluorobenzene (S)%98 70-130 04/20/23 13:47
Toluene-d8 (S)%107 70-130 04/20/23 13:47
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3992344LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 21.220 106 60-140
1,1,1-Trichloroethane ug/L 24.720 124 60-140
1,1,2,2-Tetrachloroethane ug/L 24.520 122 60-140
1,1,2-Trichloroethane ug/L 23.920 119 60-140
1,1-Dichloroethane ug/L 23.620 118 60-140
1,1-Dichloroethene ug/L 23.620 118 60-140
1,1-Dichloropropene ug/L 23.520 118 60-140
1,2,3-Trichlorobenzene ug/L 27.020 135 60-140
1,2,3-Trichloropropane ug/L 23.320 117 60-140
1,2,4-Trichlorobenzene ug/L 24.720 123 60-140
1,2,4-Trimethylbenzene ug/L 24.420 122 60-140
1,2-Dibromo-3-chloropropane ug/L 21.720 108 60-140
1,2-Dibromoethane (EDB)ug/L 25.720 129 60-140
1,2-Dichlorobenzene ug/L 23.520 117 60-140
1,2-Dichloroethane ug/L 24.620 123 60-140
1,2-Dichloropropane ug/L 25.920 129 60-140
1,3,5-Trimethylbenzene ug/L 24.720 124 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/21/2023 02:28 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 19 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92662255
MULL BULK OIL PLANK 22130.02
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3992344LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 24.720 123 60-140
1,3-Dichloropropane ug/L 22.320 111 60-140
1,4-Dichlorobenzene ug/L 22.220 111 60-140
2,2-Dichloropropane ug/L 26.120 131 60-140
2-Chlorotoluene ug/L 23.120 115 60-140
4-Chlorotoluene ug/L 24.520 123 60-140
Benzene ug/L 23.620 118 60-140
Bromobenzene ug/L 23.820 119 60-140
Bromochloromethane ug/L 24.320 121 60-140
Bromodichloromethane ug/L 25.120 125 60-140
Bromoform ug/L 21.720 108 60-140
Bromomethane ug/L 23.520 117 60-140
Carbon tetrachloride ug/L 25.620 128 60-140
Chlorobenzene ug/L 23.720 119 60-140
Chloroethane ug/L 23.020 115 60-140
Chloroform ug/L 24.720 124 60-140
Chloromethane ug/L 25.720 128 60-140
cis-1,2-Dichloroethene ug/L 23.420 117 60-140
cis-1,3-Dichloropropene ug/L 25.120 125 60-140
Dibromochloromethane ug/L 24.620 123 60-140
Dibromomethane ug/L 24.120 120 60-140
Dichlorodifluoromethane ug/L 24.820 124 60-140
Diisopropyl ether ug/L 22.920 115 60-140
Ethylbenzene ug/L 23.220 116 60-140
Hexachloro-1,3-butadiene ug/L 28.4 IH,L12014260-140
Isopropylbenzene (Cumene)ug/L 24.520 122 60-140
m&p-Xylene ug/L 46.540 116 60-140
Methyl-tert-butyl ether ug/L 21.220 106 60-140
Methylene Chloride ug/L 22.420 112 60-140
n-Butylbenzene ug/L 27.120 136 60-140
n-Propylbenzene ug/L 23.920 120 60-140
Naphthalene ug/L 27.020 135 60-140
o-Xylene ug/L 23.420 117 60-140
sec-Butylbenzene ug/L 24.820 124 60-140
Styrene ug/L 24.320 122 60-140
tert-Butylbenzene ug/L 20.820 104 60-140
Tetrachloroethene ug/L 21.920 109 60-140
Toluene ug/L 23.420 117 60-140
trans-1,2-Dichloroethene ug/L 24.520 122 60-140
trans-1,3-Dichloropropene ug/L 22.420 112 60-140
Trichloroethene ug/L 22.220 111 60-140
Trichlorofluoromethane ug/L 22.120 110 60-140
Vinyl chloride ug/L 19.420 97 60-140
1,2-Dichloroethane-d4 (S)%105 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%99 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/21/2023 02:28 PM
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Page 20 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92662255
MULL BULK OIL PLANK 22130.02
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3992345MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92661785007
3992346
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 104 60-140110 520ND20.8 22.0
1,1,1-Trichloroethane ug/L 20 130 60-140131 120ND26.1 26.3
1,1,2,2-Tetrachloroethane ug/L 20 109 60-140115 520ND21.8 22.9
1,1,2-Trichloroethane ug/L 20 119 60-140125 520ND23.8 25.0
1,1-Dichloroethane ug/L 20 119 60-140118 120ND23.8 23.5
1,1-Dichloroethene ug/L 20 121 60-140124 320ND24.2 24.9
1,1-Dichloropropene ug/L 20 112 60-140117 420ND22.4 23.4
1,2,3-Trichlorobenzene ug/L 20 94 60-140114 2020ND18.7 22.9
1,2,3-Trichloropropane ug/L 20 107 60-140113 620ND21.4 22.7
1,2,4-Trichlorobenzene ug/L 20 106 60-140110 420ND21.1 21.9
1,2,4-Trimethylbenzene ug/L 20 116 60-140118 220ND23.1 23.6
1,2-Dibromo-3-chloropropane ug/L 20 92 60-140101 920ND18.5 20.1
1,2-Dibromoethane (EDB)ug/L 20 115 60-140123 620ND23.1 24.6
1,2-Dichlorobenzene ug/L 20 103 60-140112 920ND20.5 22.3
1,2-Dichloroethane ug/L 20 118 60-140122 420ND23.5 24.4
1,2-Dichloropropane ug/L 20 121 60-140129 720ND24.1 25.8
1,3,5-Trimethylbenzene ug/L 20 114 60-140117 320ND22.7 23.5
1,3-Dichlorobenzene ug/L 20 116 60-140117 020ND23.2 23.3
1,3-Dichloropropane ug/L 20 110 60-140109 120ND22.1 21.7
1,4-Dichlorobenzene ug/L 20 107 60-140111 320ND21.4 22.1
2,2-Dichloropropane ug/L 20 123 60-140123 020ND24.5 24.6
2-Chlorotoluene ug/L 20 105 60-140113 720ND21.0 22.5
4-Chlorotoluene ug/L 20 108 60-140117 820ND21.7 23.4
Benzene ug/L 20 116 60-140122 420ND23.3 24.3
Bromobenzene ug/L 20 113 60-140111 120ND22.5 22.2
Bromochloromethane ug/L 20 115 60-140115 020ND22.9 23.0
Bromodichloromethane ug/L 20 115 60-140129 1220ND22.9 25.8
Bromoform ug/L 20 100 60-140105 620ND19.9 21.1
Bromomethane ug/L 20 77 60-14093 1820ND15.5 18.5
Carbon tetrachloride ug/L M12013160-140148 1220ND26.3 29.5
Chlorobenzene ug/L 20 114 60-140115 120ND22.8 23.0
Chloroethane ug/L 20 116 60-140113 320ND23.3 22.7
Chloroform ug/L 20 118 60-140124 520ND23.5 24.7
Chloromethane ug/L 20 111 60-140108 320ND22.3 21.6
cis-1,2-Dichloroethene ug/L 20 118 60-140116 120ND23.6 23.3
cis-1,3-Dichloropropene ug/L 20 120 60-140127 520ND24.0 25.3
Dibromochloromethane ug/L 20 115 60-140121 520ND23.1 24.3
Dibromomethane ug/L 20 114 60-140127 1120ND22.9 25.4
Dichlorodifluoromethane ug/L 20 121 60-140136 1120ND24.2 27.1
Diisopropyl ether ug/L 20 105 60-140109 320ND21.1 21.8
Ethylbenzene ug/L 20 116 60-140115 020ND23.1 23.1
Hexachloro-1,3-butadiene ug/L IH2011360-140120 620ND22.6 24.1
Isopropylbenzene (Cumene)ug/L 20 118 60-140125 520ND23.6 24.9
m&p-Xylene ug/L 40 114 60-140112 140ND45.4 44.9
Methyl-tert-butyl ether ug/L 20 93 60-14097 320ND18.6 19.3
Methylene Chloride ug/L 20 112 60-140112 020ND22.5 22.4
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/21/2023 02:28 PM
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Page 21 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92662255
MULL BULK OIL PLANK 22130.02
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3992345MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92661785007
3992346
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Butylbenzene ug/L 20 111 60-140124 1120ND22.2 24.7
n-Propylbenzene ug/L 20 110 60-140116 520ND22.0 23.2
Naphthalene ug/L 20 100 60-140114 1320ND20.0 22.8
o-Xylene ug/L 20 113 60-140114 120ND22.6 22.8
sec-Butylbenzene ug/L 20 113 60-140120 620ND22.6 24.1
Styrene ug/L 20 115 60-140119 320ND23.0 23.7
tert-Butylbenzene ug/L 20 94 60-14098 420ND18.8 19.5
Tetrachloroethene ug/L 20 103 60-140114 1020ND20.6 22.7
Toluene ug/L 20 111 60-140121 920ND22.2 24.3
trans-1,2-Dichloroethene ug/L 20 123 60-140124 220ND24.5 24.9
trans-1,3-Dichloropropene ug/L 20 104 60-140113 920ND20.7 22.6
Trichloroethene ug/L 20 106 60-140119 1120ND21.3 23.8
Trichlorofluoromethane ug/L 20 116 60-140123 520ND23.3 24.6
Vinyl chloride ug/L 20 97 60-14097 120ND19.4 19.3
1,2-Dichloroethane-d4 (S)%109 70-130103
4-Bromofluorobenzene (S)%103 70-130102
Toluene-d8 (S)%98 70-130100
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/21/2023 02:28 PM
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Page 22 of 27
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92662255
MULL BULK OIL PLANK 22130.02
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be
considered an estimated value.IH
Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.L1
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/21/2023 02:28 PM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 23 of 27
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92662255
MULL BULK OIL PLANK 22130.02
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92662255001 768964MW-4 SM 6200B
92662255002 768964MW-5 SM 6200B
92662255003 768964MW-6 SM 6200B
92662255004 768964MW-7 SM 6200B
92662255005 768964MW-10D SM 6200B
92662255006 768964MW-11 SM 6200B
92662255007 768964DUP-1 SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/21/2023 02:28 PM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 24 of 27
Page 25 of 27
Page 26 of 27
Page 27 of 27
#=CL#
May 10, 2023
LIMS USE: FR - SARA ROSE
LIMS OBJECT ID: 92664397
92664397
Project:
Pace Project No.:
RE:
Ms. Sara Rose
Alpha Environmental Sciences
P.O. Box 2155
Asheville, NC 28801
MULL BULK PLANT/23001.02
Dear Ms. Rose:
Enclosed are the analytical results for sample(s) received by the laboratory on April 27, 2023. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Sara Poulson
[e-mail]
Project Manager
[phone]
Enclosures
cc:Ms. Sara Rose, Alpha Environmental
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 1 of 14
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92664397
MULL BULK PLANT/23001.02
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 14
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92664397
MULL BULK PLANT/23001.02
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92664397001 SS-3 SM 6200B 63 PASI-CSAS
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 3 of 14
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92664397
MULL BULK PLANT/23001.02
Sample:SS-3 Lab ID:92664397001 Collected:04/26/23 16:35 Received:04/27/23 09:12 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 05/10/23 03:49 71-43-20.50 1
Bromobenzene ND ug/L 05/10/23 03:49 108-86-10.50 1
Bromochloromethane ND ug/L 05/10/23 03:49 74-97-50.50 1
Bromodichloromethane ND ug/L 05/10/23 03:49 75-27-40.50 1
Bromoform ND ug/L 05/10/23 03:49 75-25-20.50 1
Bromomethane ND ug/L 05/10/23 03:49 74-83-95.0 1
n-Butylbenzene ND ug/L 05/10/23 03:49 104-51-80.50 1
sec-Butylbenzene ND ug/L 05/10/23 03:49 135-98-80.50 1
tert-Butylbenzene ND ug/L 05/10/23 03:49 98-06-60.50 1
Carbon tetrachloride ND ug/L 05/10/23 03:49 56-23-50.50 1
Chlorobenzene ND ug/L 05/10/23 03:49 108-90-70.50 1
Chloroethane ND ug/L 05/10/23 03:49 75-00-3 L11.0 1
Chloroform ND ug/L 05/10/23 03:49 67-66-30.50 1
Chloromethane ND ug/L 05/10/23 03:49 74-87-31.0 1
2-Chlorotoluene ND ug/L 05/10/23 03:49 95-49-80.50 1
4-Chlorotoluene ND ug/L 05/10/23 03:49 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 05/10/23 03:49 96-12-81.0 1
Dibromochloromethane ND ug/L 05/10/23 03:49 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 05/10/23 03:49 106-93-40.50 1
Dibromomethane ND ug/L 05/10/23 03:49 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 05/10/23 03:49 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 05/10/23 03:49 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 05/10/23 03:49 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 05/10/23 03:49 75-71-8 IH,L10.50 1
1,1-Dichloroethane ND ug/L 05/10/23 03:49 75-34-30.50 1
1,2-Dichloroethane ND ug/L 05/10/23 03:49 107-06-20.50 1
1,1-Dichloroethene ND ug/L 05/10/23 03:49 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 05/10/23 03:49 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 05/10/23 03:49 156-60-50.50 1
1,2-Dichloropropane ND ug/L 05/10/23 03:49 78-87-50.50 1
1,3-Dichloropropane ND ug/L 05/10/23 03:49 142-28-90.50 1
2,2-Dichloropropane ND ug/L 05/10/23 03:49 594-20-70.50 1
1,1-Dichloropropene ND ug/L 05/10/23 03:49 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 05/10/23 03:49 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 05/10/23 03:49 10061-02-60.50 1
Diisopropyl ether ND ug/L 05/10/23 03:49 108-20-30.50 1
Ethylbenzene ND ug/L 05/10/23 03:49 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 05/10/23 03:49 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 05/10/23 03:49 98-82-80.50 1
Methylene Chloride ND ug/L 05/10/23 03:49 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 05/10/23 03:49 1634-04-40.50 1
Naphthalene ND ug/L 05/10/23 03:49 91-20-32.0 1
n-Propylbenzene ND ug/L 05/10/23 03:49 103-65-10.50 1
Styrene ND ug/L 05/10/23 03:49 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 05/10/23 03:49 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 05/10/23 03:49 79-34-50.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/10/2023 01:52 PM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 4 of 14
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92664397
MULL BULK PLANT/23001.02
Sample:SS-3 Lab ID:92664397001 Collected:04/26/23 16:35 Received:04/27/23 09:12 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Tetrachloroethene ND ug/L 05/10/23 03:49 127-18-40.50 1
Toluene ND ug/L 05/10/23 03:49 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 05/10/23 03:49 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 05/10/23 03:49 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 05/10/23 03:49 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 05/10/23 03:49 79-00-50.50 1
Trichloroethene ND ug/L 05/10/23 03:49 79-01-60.50 1
Trichlorofluoromethane ND ug/L 05/10/23 03:49 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 05/10/23 03:49 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 05/10/23 03:49 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 05/10/23 03:49 108-67-80.50 1
Vinyl chloride ND ug/L 05/10/23 03:49 75-01-41.0 1
m&p-Xylene ND ug/L 05/10/23 03:49 179601-23-11.0 1
o-Xylene ND ug/L 05/10/23 03:49 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)113 %05/10/23 03:49 17060-07-070-130 1
4-Bromofluorobenzene (S)95 %05/10/23 03:49 460-00-470-130 1
Toluene-d8 (S)101 %05/10/23 03:49 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 05/10/2023 01:52 PM
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Page 5 of 14
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92664397
MULL BULK PLANT/23001.02
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
773002
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92664397001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4012402
Associated Lab Samples:92664397001
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 05/10/23 00:00
1,1,1-Trichloroethane ug/L ND 0.50 05/10/23 00:00
1,1,2,2-Tetrachloroethane ug/L ND 0.50 05/10/23 00:00
1,1,2-Trichloroethane ug/L ND 0.50 05/10/23 00:00
1,1-Dichloroethane ug/L ND 0.50 05/10/23 00:00
1,1-Dichloroethene ug/L ND 0.50 05/10/23 00:00
1,1-Dichloropropene ug/L ND 0.50 05/10/23 00:00
1,2,3-Trichlorobenzene ug/L ND 2.0 05/10/23 00:00
1,2,3-Trichloropropane ug/L ND 0.50 05/10/23 00:00
1,2,4-Trichlorobenzene ug/L ND 2.0 05/10/23 00:00
1,2,4-Trimethylbenzene ug/L ND 0.50 05/10/23 00:00
1,2-Dibromo-3-chloropropane ug/L ND 1.0 05/10/23 00:00
1,2-Dibromoethane (EDB)ug/L ND 0.50 05/10/23 00:00
1,2-Dichlorobenzene ug/L ND 0.50 05/10/23 00:00
1,2-Dichloroethane ug/L ND 0.50 05/10/23 00:00
1,2-Dichloropropane ug/L ND 0.50 05/10/23 00:00
1,3,5-Trimethylbenzene ug/L ND 0.50 05/10/23 00:00
1,3-Dichlorobenzene ug/L ND 0.50 05/10/23 00:00
1,3-Dichloropropane ug/L ND 0.50 05/10/23 00:00
1,4-Dichlorobenzene ug/L ND 0.50 05/10/23 00:00
2,2-Dichloropropane ug/L ND 0.50 05/10/23 00:00
2-Chlorotoluene ug/L ND 0.50 05/10/23 00:00
4-Chlorotoluene ug/L ND 0.50 05/10/23 00:00
Benzene ug/L ND 0.50 05/10/23 00:00
Bromobenzene ug/L ND 0.50 05/10/23 00:00
Bromochloromethane ug/L ND 0.50 05/10/23 00:00
Bromodichloromethane ug/L ND 0.50 05/10/23 00:00
Bromoform ug/L ND 0.50 05/10/23 00:00
Bromomethane ug/L ND 5.0 05/10/23 00:00
Carbon tetrachloride ug/L ND 0.50 05/10/23 00:00
Chlorobenzene ug/L ND 0.50 05/10/23 00:00
Chloroethane ug/L ND 1.0 05/10/23 00:00
Chloroform ug/L ND 0.50 05/10/23 00:00
Chloromethane ug/L ND 1.0 05/10/23 00:00
cis-1,2-Dichloroethene ug/L ND 0.50 05/10/23 00:00
cis-1,3-Dichloropropene ug/L ND 0.50 05/10/23 00:00
Dibromochloromethane ug/L ND 0.50 05/10/23 00:00
Dibromomethane ug/L ND 0.50 05/10/23 00:00
Dichlorodifluoromethane ug/L ND 0.50 IH05/10/23 00:00
Diisopropyl ether ug/L ND 0.50 05/10/23 00:00
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 05/10/2023 01:52 PM
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92664397
MULL BULK PLANT/23001.02
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4012402
Associated Lab Samples:92664397001
Matrix:Water
Analyzed
Ethylbenzene ug/L ND 0.50 05/10/23 00:00
Hexachloro-1,3-butadiene ug/L ND 2.0 05/10/23 00:00
Isopropylbenzene (Cumene)ug/L ND 0.50 05/10/23 00:00
m&p-Xylene ug/L ND 1.0 05/10/23 00:00
Methyl-tert-butyl ether ug/L ND 0.50 05/10/23 00:00
Methylene Chloride ug/L ND 2.0 05/10/23 00:00
n-Butylbenzene ug/L ND 0.50 05/10/23 00:00
n-Propylbenzene ug/L ND 0.50 05/10/23 00:00
Naphthalene ug/L ND 2.0 05/10/23 00:00
o-Xylene ug/L ND 0.50 05/10/23 00:00
sec-Butylbenzene ug/L ND 0.50 05/10/23 00:00
Styrene ug/L ND 0.50 05/10/23 00:00
tert-Butylbenzene ug/L ND 0.50 05/10/23 00:00
Tetrachloroethene ug/L ND 0.50 05/10/23 00:00
Toluene ug/L ND 0.50 05/10/23 00:00
trans-1,2-Dichloroethene ug/L ND 0.50 05/10/23 00:00
trans-1,3-Dichloropropene ug/L ND 0.50 05/10/23 00:00
Trichloroethene ug/L ND 0.50 05/10/23 00:00
Trichlorofluoromethane ug/L ND 1.0 05/10/23 00:00
Vinyl chloride ug/L ND 1.0 05/10/23 00:00
1,2-Dichloroethane-d4 (S)%110 70-130 05/10/23 00:00
4-Bromofluorobenzene (S)%97 70-130 05/10/23 00:00
Toluene-d8 (S)%100 70-130 05/10/23 00:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4012405LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 20.020 100 60-140
1,1,1-Trichloroethane ug/L 21.420 107 60-140
1,1,2,2-Tetrachloroethane ug/L 21.620 108 60-140
1,1,2-Trichloroethane ug/L 20.920 104 60-140
1,1-Dichloroethane ug/L 22.820 114 60-140
1,1-Dichloroethene ug/L 23.020 115 60-140
1,1-Dichloropropene ug/L 23.920 119 60-140
1,2,3-Trichlorobenzene ug/L 19.420 97 60-140
1,2,3-Trichloropropane ug/L 20.120 101 60-140
1,2,4-Trichlorobenzene ug/L 19.520 97 60-140
1,2,4-Trimethylbenzene ug/L 21.020 105 60-140
1,2-Dibromo-3-chloropropane ug/L 18.720 93 60-140
1,2-Dibromoethane (EDB)ug/L 21.220 106 60-140
1,2-Dichlorobenzene ug/L 20.320 102 60-140
1,2-Dichloroethane ug/L 21.920 109 60-140
1,2-Dichloropropane ug/L 21.820 109 60-140
1,3,5-Trimethylbenzene ug/L 20.920 104 60-140
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 05/10/2023 01:52 PM
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Asheville, NC 28804
[phone]
Page 7 of 14
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92664397
MULL BULK PLANT/23001.02
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4012405LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 20.720 104 60-140
1,3-Dichloropropane ug/L 20.820 104 60-140
1,4-Dichlorobenzene ug/L 19.820 99 60-140
2,2-Dichloropropane ug/L 21.020 105 60-140
2-Chlorotoluene ug/L 21.120 106 60-140
4-Chlorotoluene ug/L 21.320 107 60-140
Benzene ug/L 21.220 106 60-140
Bromobenzene ug/L 20.320 102 60-140
Bromochloromethane ug/L 22.020 110 60-140
Bromodichloromethane ug/L 19.120 96 60-140
Bromoform ug/L 17.420 87 60-140
Bromomethane ug/L 22.520 113 60-140
Carbon tetrachloride ug/L 18.920 94 60-140
Chlorobenzene ug/L 20.920 104 60-140
Chloroethane ug/L 31.6 L12015860-140
Chloroform ug/L 22.720 113 60-140
Chloromethane ug/L 25.720 128 60-140
cis-1,2-Dichloroethene ug/L 22.220 111 60-140
cis-1,3-Dichloropropene ug/L 20.020 100 60-140
Dibromochloromethane ug/L 19.320 97 60-140
Dibromomethane ug/L 19.920 100 60-140
Dichlorodifluoromethane ug/L 33.0 IH,L12016560-140
Diisopropyl ether ug/L 20.620 103 60-140
Ethylbenzene ug/L 20.520 102 60-140
Hexachloro-1,3-butadiene ug/L 19.520 97 60-140
Isopropylbenzene (Cumene)ug/L 20.620 103 60-140
m&p-Xylene ug/L 40.540 101 60-140
Methyl-tert-butyl ether ug/L 20.320 102 60-140
Methylene Chloride ug/L 20.220 101 60-140
n-Butylbenzene ug/L 21.420 107 60-140
n-Propylbenzene ug/L 21.120 105 60-140
Naphthalene ug/L 21.920 110 60-140
o-Xylene ug/L 20.220 101 60-140
sec-Butylbenzene ug/L 20.520 103 60-140
Styrene ug/L 20.620 103 60-140
tert-Butylbenzene ug/L 17.720 88 60-140
Tetrachloroethene ug/L 18.920 95 60-140
Toluene ug/L 19.720 98 60-140
trans-1,2-Dichloroethene ug/L 23.120 116 60-140
trans-1,3-Dichloropropene ug/L 19.220 96 60-140
Trichloroethene ug/L 21.120 106 60-140
Trichlorofluoromethane ug/L 22.220 111 60-140
Vinyl chloride ug/L 20.920 105 60-140
1,2-Dichloroethane-d4 (S)%107 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%99 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 05/10/2023 01:52 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 8 of 14
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92664397
MULL BULK PLANT/23001.02
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4012406MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92665324001
4012407
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 119 60-140111 720ND23.8 22.2
1,1,1-Trichloroethane ug/L 20 131 60-140121 720ND26.2 24.3
1,1,2,2-Tetrachloroethane ug/L 20 121 60-140115 520ND24.1 23.0
1,1,2-Trichloroethane ug/L 20 118 60-140111 720ND23.6 22.1
1,1-Dichloroethane ug/L 20 138 60-140128 820ND27.7 25.6
1,1-Dichloroethene ug/L M12014660-140134 920ND29.3 26.7
1,1-Dichloropropene ug/L M12015360-140140 820ND30.5 28.1
1,2,3-Trichlorobenzene ug/L 20 115 60-140107 720ND23.0 21.5
1,2,3-Trichloropropane ug/L 20 116 60-140104 1120ND23.1 20.8
1,2,4-Trichlorobenzene ug/L 20 121 60-140111 920ND24.2 22.2
1,2,4-Trimethylbenzene ug/L 20 131 60-140121 720ND26.1 24.3
1,2-Dibromo-3-chloropropane ug/L 20 98 60-14097 120ND19.7 19.5
1,2-Dibromoethane (EDB)ug/L 20 122 60-140114 620ND24.3 22.8
1,2-Dichlorobenzene ug/L 20 120 60-140111 720ND23.9 22.3
1,2-Dichloroethane ug/L 20 128 60-140119 720ND25.6 23.8
1,2-Dichloropropane ug/L 20 128 60-140120 620ND25.6 24.0
1,3,5-Trimethylbenzene ug/L 20 132 60-140122 720ND26.3 24.5
1,3-Dichlorobenzene ug/L 20 125 60-140119 520ND25.0 23.7
1,3-Dichloropropane ug/L 20 122 60-140114 720ND24.3 22.7
1,4-Dichlorobenzene ug/L 20 117 60-140112 420ND23.3 22.5
2,2-Dichloropropane ug/L M12014260-140133 720ND28.4 26.6
2-Chlorotoluene ug/L 20 129 60-140123 420ND25.7 24.6
4-Chlorotoluene ug/L 20 128 60-140121 620ND25.6 24.3
Benzene ug/L 20 126 60-140116 52014.5 39.6 37.7
Bromobenzene ug/L 20 118 60-140112 520ND23.6 22.4
Bromochloromethane ug/L 20 127 60-140116 920ND25.5 23.3
Bromodichloromethane ug/L 20 113 60-140105 7201.5 24.2 22.6
Bromoform ug/L 20 98 60-14092 620ND19.6 18.4
Bromomethane ug/L 20 113 60-140114 120ND22.5 22.8
Carbon tetrachloride ug/L 20 117 60-140109 720ND23.4 21.8
Chlorobenzene ug/L 20 125 60-140117 620ND24.9 23.4
Chloroethane ug/L M02019960-140184 720ND39.7 36.9
Chloroform ug/L 20 131 60-140121 6209.4 35.6 33.6
Chloromethane ug/L M12014860-140142 520ND29.7 28.3
cis-1,2-Dichloroethene ug/L 20 135 60-140123 920ND27.0 24.6
cis-1,3-Dichloropropene ug/L 20 116 60-140108 720ND23.1 21.5
Dibromochloromethane ug/L 20 114 60-140107 620ND22.8 21.5
Dibromomethane ug/L 20 113 60-140106 620ND22.5 21.2
Dichlorodifluoromethane ug/L IH,M02023360-140212 920ND46.5 42.3
Diisopropyl ether ug/L 20 124 60-140115 5209.9 34.6 32.8
Ethylbenzene ug/L 20 127 60-140118 720ND25.4 23.6
Hexachloro-1,3-butadiene ug/L 20 140 60-140124 1220ND27.9 24.8
Isopropylbenzene (Cumene)ug/L 20 130 60-140119 920ND26.0 23.8
m&p-Xylene ug/L 40 126 60-140117 740ND51.2 47.7
Methyl-tert-butyl ether ug/L 20 114 60-140108 620ND23.3 21.9
Methylene Chloride ug/L 20 122 60-140112 920ND24.4 22.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/10/2023 01:52 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 9 of 14
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92664397
MULL BULK PLANT/23001.02
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4012406MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92665324001
4012407
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Butylbenzene ug/L M12014760-140132 1120ND29.3 26.4
n-Propylbenzene ug/L 20 133 60-140124 720ND26.7 24.9
Naphthalene ug/L 20 123 60-140118 420ND24.6 23.6
o-Xylene ug/L 20 127 60-140117 7204.5 29.9 27.9
sec-Butylbenzene ug/L 20 135 60-140126 720ND26.9 25.2
Styrene ug/L 20 124 60-140115 720ND24.8 23.1
tert-Butylbenzene ug/L 20 109 60-14099 920ND21.8 19.9
Tetrachloroethene ug/L 20 121 60-140112 820ND24.2 22.4
Toluene ug/L 20 118 60-140111 620ND23.6 22.1
trans-1,2-Dichloroethene ug/L M12014560-140133 820ND28.9 26.7
trans-1,3-Dichloropropene ug/L 20 109 60-140104 520ND21.9 20.7
Trichloroethene ug/L 20 129 60-140119 820ND25.7 23.7
Trichlorofluoromethane ug/L M12014660-140134 820ND29.1 26.8
Vinyl chloride ug/L 20 132 60-140124 720ND26.4 24.7
1,2-Dichloroethane-d4 (S)%107 70-130106
4-Bromofluorobenzene (S)%98 70-130100
Toluene-d8 (S)%99 70-13098
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 05/10/2023 01:52 PM
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2225 Riverside Dr.
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[phone]
Page 10 of 14
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92664397
MULL BULK PLANT/23001.02
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be
considered an estimated value.IH
Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.L1
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 05/10/2023 01:52 PM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 11 of 14
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92664397
MULL BULK PLANT/23001.02
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92664397001 773002SS-3 SM 6200B
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 05/10/2023 01:52 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 12 of 14
Page 13 of 14
Page 14 of 14