AS-3664_28800_CA_TCR_20221221

UST CLOSURE REPORT

For The
SAMIR’S # 6
8065 US Hwy 221 North Marion, McDowell County
North Carolina 28752 Facility # 00-0-0000029436

December 21, 2022

Singleton Environmental, Inc. Project # SEI-1274

Singleton Environmental, Inc.

INITIAL ACTIONS & ABATEMENT REPORT WITH UST CLOSURE December 21, 2022 UST Incident Number: N/A Facility ID Number: 00-0-0000029436
Site Name: Samir’s #6 8065 US Hwy 221 North Marion, NC 28752 UST Owner / Operator: My Wife, LLC.
PO Box 1272 Old Fort, NC 28762 Telephone: [phone]
Consultant / Contractor: Singleton Environmental, Inc.
PO Box 604 Fletcher, NC 28732 Telephone: [phone] Date Release Discovered: October 24, 2022
Estimated Quantity of Release: Unknown/unquantified Cause/Source of Release: Diesel Dispenser.

Latitude: (35.7862° North)
Longitude: (-82.0404° West) Location Method: GPS Signature and Seal of Certifying Professional Geologist: I, Christopher D. Singleton, a North Carolina Professional Geologist, do certify that the information contained in this report is correct and accurate to the best of my knowledge.

____________________________________ Christopher D. Singleton, P.G. #1928 Singleton Environmental, Inc. is licensed to practice geology in North Carolina. The certification number of the company is C-443.

Table of Contents
Introduction ................................................................................................................................1
Site History…......................…………......................................... .................................................1 Brief Description of the Site…………......................................... .................................................1 Closure Procedures..............…………............................................................................................2 Source Investigation…......................…………......................................... ....................................2
Initial Abatement Activities…......................…………......................................... .........................3
Conclusions and Recommendations…..................…………......................................... ................3 Table Table 1. Soil Analytical Results – Closure Samples
Table 2. Soil Analytical Results – Risk Based Analysis Table 3. Groundwater Analytical Results Figures

Figure 1. Site Vicinity Map 7.5’ USGS Topo Figure 2. Site Map – Sample Locations Appendices
Appendix A: Soil Disposal Manifests Appendix B: Laboratory Analytical Results

Introduction This report summarizes the UST system closure and initial actions & abatement activities
for the removal of four underground storage tanks (UST) at Samir’s #6 located at 8065 US Highway 221 North in Marion, McDowell County, North Carolina. The property is owned and operated by My Wife, LLC. Figure 1 shows the site location on a USGS topography map, and Figure 2 presents site maps showing the location of the former USTs and corresponding soil sampling locations. Site History

The following tables summarize information about the USTs at the site:
Tank No. Volume Contents
Tank Material Use Date last used removed or closed in
permanent closure
release detected?
1 4000 Diesel Steel Resale 10/23/2022 Removed 10/24/2022 Yes
2 8200 Gas Steel Resale 10/23/2022 Removed 10/24/2022 Yes
3 8200 Gas Steel Resale 10/23/2022 Removed 10/24/2022 Yes
4 8200 Gas Steel Resale 10/23/2022 Removed 10/24/022 Yes
Ownership of Tanks: My Wife, LLC.
PO Box 1272 Old Fort, NC 28762 Telephone: [phone]
Brief Description of the Site

Land use at the site is commercial, and the surrounding properties are also commercial and residential properties. The closest surface water body is Limekiln Creek located
approximately 315 feet to the north of the site. Groundwater was encountered underneath the USTs at a depth of 6 to 7 feet during the soil removal activities. No bedrock was encountered during the UST removal activities.
Closure Procedures

From October 24 to November 1, 2022, the tank and dispenser removal activities commenced. The USTs were located on the eastern side of the property as shown in Figure 2. Prior to the UST removal, the contents of the tanks were removed by Petroleum Specialty, Inc. (PSI) and the vapors were purged from the tanks using a large
quantity of dry ice. An excavator was used to remove the USTs from their respective tank

cavity, and they were delivered to My County Metals in Marion, North Carolina. The
disposal manifest is in Appendix A. Upon removal, soil samples were collected in the sidewalls surrounding the USTs due to shallow groundwater. Samples were also collected underneath the dispensers at the site.
Line samples were not collected due to the dispensers being located on top of the western sidewall of the excavation. All the samples were analyzed for Gasoline Range Organics (GRO) and/or Diesel Range Organics (DRO).
The closure soil analytical results are summarized in Table 1 and corresponding soil
sampling locations can be found in Figure 2. Elevated petroleum odors were detected in
most of the soil samples collected at the site, however, the PID levels were low, and the resulting laboratory analysis confirmed the low PID results except for the Dispenser #4 (D-4) sample.
Source Investigation

Sixteen soil samples (see Figure 2) were collected along the sidewalls of the USTs and
the dispensers between October 24, 2022, and September 1, 2022. Samples T-1 through
T-12 were collected in the sidewall of the excavation at a depth of approximately 5 feet. Samples D-1 through D-4 were collected underneath each dispenser at a depth of approximately 2 feet. None of the soil samples detected concentrations above the MSCCs of 50/100 mg/kg except for soil sample D-4 (506 mg/kg DRO). The soil
analytical results are summarized in Table 1. Initial Abatement Activities
Due to shallow groundwater and one soil sample exceeding the MSCCs, one monitoring well (MW-1R) was installed by Mountain Environmental, Inc. to a depth of 15 feet in the vicinity of soil sample D-4 on December 9, 2022. A soil sample was collected using push probe technology at a depth of 5 feet (highest PID). The depth to groundwater was 6.81
feet. The sample (MW-1R-soil) was analyzed for risk-based methods using EPA Method 8260, 8270 and EPH/VPH. The analytical results did not detect any compounds exceeding the soil-to-groundwater MSCCs.
A groundwater sample was also collected from MW-1R and analyzed for EPA Methods
6200B and 625. The sample was collected after the monitoring well was developed and purged of three well volumes using a new clear PVC bailer and put into new EPA approved containers, placed on ice, and delivered to the laboratory. The analytical results detected concentrations of benzene and naphthalene exceeding the NCAC 2L MCLs, however, none of the detected compounds exceeded the NCAC 2L GCLs.
Refer to Table 3 for a summary of each groundwater constituent and the detected contamination level. A copy of the laboratory analytical report is included in Appendix B. The monitoring well log is located in Appendix A.

Conclusions and Recommendations
From October 24 to September 1, 2022, the USTs were removed from the site. The results of this investigation indicate the groundwater around the former gasoline USTs located at the site contains concentrations exceeding the NCAC 2L MCLs, however, none
of the soil samples collected exceeded the soil-to-groundwater MSCCs. A previous LSA was performed at the site that established a low-risk ranking, therefore, SEI recommends a No-Further-Action with a groundwater notice of residual petroleum (NoRP).

TABLE
EPA
8015C by
EPA
8015C by
Diesel
Range
Organic
s(C10-
C28)
Gas
Range
Organic
s (C6-
C10)
Collected Depth mg/kg mg/kg
T-1 10/24/2022 N/A ND
T-10 10/25/2022 15.8 ND
T-11 10/25/2022 25.5 44.4
T-12 10/25/2022 30.6 47.4
T-2 10/24/2022 N/A ND
T-3 10/24/2022 N/A 9.5
T-4 10/24/2022 N/A ND
T-5 10/24/2022 N/A ND
T-6 10/24/2022 N/A 17.4
T-7 10/24/2022 N/A 19.0
T-8 10/24/2022 N/A ND
T-9 10/25/2022 7.5 6.7
D-1 11/01/2022 N/A ND
D-2 11/01/2022 N/A ND
D-3 11/01/2022 N/A ND
D-4 11/01/2022 506 ND
100 50
Table # 1
Summary of Analytical Results - Solid Samples
Samirs #6 Tanks and Dispensers
NOTES:
ND = Not Detected
Analytical Method
Sample ID
Constituent of Concern
MSCCs
MSCC = Maximum Soil Contamination Concentration
ft. BGS = feet below ground surface
mg/kg = milligrams per kilogram
ug/kg = micrograms per kilogram
1,2,4-
Trimeth
ylbenze
ne
1,3,5-
Trimeth
ylbenze
ne
Chlorob
enzene
Ethylbe
nzene
Isoprop
ylbenze
ne
(Cumen
e)
Naphth
alene Toluene Xylene
(Total)
n-
Butylbe
nzene
n-
Propylb
enzene
Naphth
alene
Pentach
lorophe
nol
Phenant
hrene Phenol Pyrene
bis(2-
Chloroe
thyl)
ether
bis(2-
Ethylhe
xyl)phth
alate
Aliphati
c (C09-
C18)
Aliphati
c (C19-
C36)
Aromati
c (C11-
C22)
Collected Depth mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg
MW-1R SOIL (D-4)12/09/2022 0.24 0.040 0.016 0.013 0.13 0.025 0.0074 0.055 0.18 0.42 ND ND ND ND ND ND ND ND ND ND
782 782 312 1560 1560 313 1200 3130 626 626 313 5 469 4690 469 0.58 46 1500 31000 N/A
20400 20400 8180 40000 40900 8180 32000 81800 16400 16400 8180 48 12300 123000 12300 5.2 410 40000 810000 N/A
Bold data above the 2L Class GA Standard
Analytical Method EPA Method 8260 EPA Method 8270 MADEP EPH/VPH
Sample ID
Constituent of Concern
Table # 2
Summary of Analytical Results - Solid Samples
SAMIR'S #6 - D-4 - Risk Based Analysis
Acenap
hthene
Benzo(a
)anthrac
ene
Benzo(a
)pyrene
Chrysen
e
Fluorant
hene
Fluoren
e
Naphth
alene Pyrene
bis(2-
Ethylhe
xyl)phth
alate
1,2,4-
Trimeth
ylbenze
ne
1,3,5-
Trimeth
ylbenze
ne
Benzen
e
Ethylbe
nzene
Isoprop
ylbenze
ne
(Cumen
e)
Naphth
alene Toluene m&p-
Xylene
n-
Butylbe
nzene
n-
Propylb
enzene
o-
Xylene
Collected Depth ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L
MW-1R 12/09/2022 ND ND ND ND ND ND 22.8 ND ND 125 19.0 12.6 116 21.2 49.1 13.8 183 13.9 59.2 3.0
500 70 70 500
2120 4.7 0.81 5 300 990 6000 200 170 28500 25000 5000 84500 25000 6000 260000 50000 6900 30000 50000
Table # 3
Summary of Analytical Results - Water Samples
SAMIR'S #6 12/9/22
Analytical Method EPA Method 625 EPA Method 6200B
Sample ID
Constituent of Concern
ft. BGS = feet below ground surface
mg/L = milligrams per liter
ug/L = micrograms per liter
2L Class GA Standards
2L Class GCL Standards
NOTES:
ND = Not Detected

FIGURES
LITTLE SWITZERLAND QUADRANGLE
NORTH CAROLINA 7.5 MINUTE SERIES (TOPOGRAPHIC)
Figure 1
Site Map
Singleton Environmental, Inc
Samir's #6
T-9
T-2
T-1
T-3
T-4
T-8
T-7
T-6
MW-1R/D-4
D-1
D-2
D-3
T-10
T-12 T-11

APPENDIX A

UST DISPOSAL MANIFEST
' Tank Location and OwneriAuthorized Representative Certification:
Tank Location:
Physical Address:
Samir's #6
8065 US Hwy 221 N Tank Owner or
Authorized Representati ve :Mv Wife, LLC.
Mariorq NC 28752 Phone No:828-668-4272
Description of Contents:,
GaqS-rls.
4000
Contents
Diesel
aq&lSCnls
8200 Gas
8200 Gas t
8200 Gas
Transporters:
The undersigned transporters certifu that the above listed contents have been transported to:
W
Printed Name:
Signalure:
Date:
Cleaning and Demolition Certification:
The undersigned certifies that the above listed tanks have been cleaned and demolished according to Amcrican Pctroleum
Institute (API) Recommended Practice 1604, "Removal and Disposal of Used Underground Petroleum Storage Tanks", and
API Publication 2015, "Cleaning Petroleum Storage Tanlis".{)ow ,=/r, /r-Priiteliame
Disposal Certifi cation:
-Wi-T-Date
The undersigned certifies that the contents listed above have been disposed ofproperly.
Disposal Faciliqv:
Prinled Name Date
$
WELL CONSTRUCTION RECORD (GW-1) For Internal Use Only:
Form GW-1 North Carolina Department of Environmental Quality - Division of Water Resources Revised 2-22-2016
1. Well Contractor Information:
Well Contractor Name
NC Well Contractor Certification Number
Company Name
2. Well Construction Permit #:
List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.)
3. Well Use (check well use):
Water Supply Well:
□Agricultural □Municipal/Public
□Geothermal (Heating/Cooling Supply)□Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared)
□Irrigation
Non-Water Supply Well:
□Monitoring □Recovery
Injection Well:
□Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier
□Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop)□Tracer
□Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
Well ID#

Facility/Owner Name Facility ID# (if applicable)
County Parcel Identification No. (PIN)
5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees:
N W
6. Is(are) the well(s):□Permanent or □Temporary
7. Is this a repair to an existing well:□Yes or □No
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8. For Geoprobe/DPT or Closed-Loop Geothermal Wells having the same
construction, only 1 GW-1 is needed. Indicate TOTAL NUMBER of wells
drilled:
9. Total well depth below land surface: (ft.)
For multiple wells list all depths if different (example- 3@200’ and 2@100′)
10. Static water level below top of casing: (ft.)
If water level is above casing, use “+”
11. Borehole diameter: (in.)
12. Well construction method:
(i.e. auger, rotary, cable, direct push, etc.)
FOR WATER SUPPLY WELLS ONLY:
13a. Yield (gpm) Method of test:
13b. Disinfection type: Amount:
22. Certification:
Signature of Certified Well Contractor Date
By signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a
copy of this record has been provided to the well owner.
23. Site diagram or additional well details:
You may use the back of this page to provide additional well site details or well
construction details. You may also attach additional pages if necessary.
SUBMITTAL INSTRUCTIONS
24a. For All Wells: Submit this form within 30 days of completion of well
construction to the following:
Division of Water Resources, Information Processing Unit,
1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells: In addition to sending the form to the address in 24a
above, also submit one copy of this form within 30 days of completion of well
construction to the following:
Division of Water Resources, Underground Injection Control Program,
1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells: In addition to sending the form to
the address(es) above, also submit one copy of this form within 30 days of
completion of well construction to the county health department of the county
where constructed.
2.Certif at n:
ignature of Certified Well Contrac
BRIAN C BAUER
4179-B
MOUNTAIN ENVIRONMENTAL SERVICES, INC.
NA
MW-1R4. Date Well(s) Completed: 12/9/2022
5a. Well Location: NA
8065 US Highway 221 Marion, NC
Physical Address, City, and Zip Mcdowell
15
8
6
HSA
12/9/2022
8 15 GRAY/BLUE CLAY
0 5 2 SCH40 PVC
NA
5 15 2 0.0010 SCH40 PVC
0
4 15 #2 SILICA SAND POUR
0
0.5
0.5
4
CONCRETE/GRAVEL/FILL
TAN/ORANGE SILTY CLAY
BENTONITE SEAL FROM 3-4'.
Print Form
(if well field, one lat/long is sufficient)
35.786299 82.040531
3 PORTLAND CEMENT POUR
4 15 BROWN SILTY CLAY.

APPENDIX B

#=CL#
November 01, 2022
LIMS USE: FR - CHRIS SINGLETON
LIMS OBJECT ID: 92632885
92632885
Project:
Pace Project No.:
RE:
Chris Singleton
Singleton Environmental
105 Charlotte Highway
Asheville, NC 28803
Samirs #6 Tanks 10/24
Dear Chris Singleton:
Enclosed are the analytical results for sample(s) received by the laboratory on October 25, 2022. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
Project Manager
1(828)254-7176
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 1 of 23
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92632885
Samirs #6 Tanks 10/24
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 23
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92632885
Samirs #6 Tanks 10/24
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92632885001 T-1 EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
92632885002 T-2 EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
92632885003 T-3 EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
92632885004 T-4 EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
92632885005 T-5 EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
92632885006 T-6 EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
92632885007 T-7 EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
92632885008 T-8 EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
92632885009 T-9 EPA 8015C 2 PASI-CAP2
EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
92632885010 T-10 EPA 8015C 2 PASI-CAP2
EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
92632885011 T-11 EPA 8015C 2 PASI-CAP2
EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
92632885012 T-12 EPA 8015C 2 PASI-CAP2
EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 3 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92632885
Samirs #6 Tanks 10/24
Sample:T-1 Lab ID:92632885001 Collected:10/24/22 13:15 Received:10/25/22 13:15 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 10/26/22 15:3010/26/22 11:129.4 1
Surrogates
4-Bromofluorobenzene (S)101 %10/26/22 15:30 460-00-410/26/22 11:1266-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 19.6 %10/26/22 16:41 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/01/2022 01:27 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 4 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92632885
Samirs #6 Tanks 10/24
Sample:T-2 Lab ID:92632885002 Collected:10/24/22 13:20 Received:10/25/22 13:15 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 10/26/22 15:5510/26/22 11:125.1 1
Surrogates
4-Bromofluorobenzene (S)99 %10/26/22 15:55 460-00-410/26/22 11:1266-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 1.6 %10/26/22 16:41 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/01/2022 01:27 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 5 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92632885
Samirs #6 Tanks 10/24
Sample:T-3 Lab ID:92632885003 Collected:10/24/22 13:30 Received:10/25/22 13:15 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)9.5 mg/kg 10/26/22 16:2110/26/22 11:127.3 1
Surrogates
4-Bromofluorobenzene (S)100 %10/26/22 16:21 460-00-410/26/22 11:1266-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 10.9 %10/26/22 16:41 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/01/2022 01:27 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 6 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92632885
Samirs #6 Tanks 10/24
Sample:T-4 Lab ID:92632885004 Collected:10/24/22 13:40 Received:10/25/22 13:15 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 10/26/22 16:4710/26/22 11:128.0 1
Surrogates
4-Bromofluorobenzene (S)99 %10/26/22 16:47 460-00-410/26/22 11:1266-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 17.0 %10/26/22 16:41 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/01/2022 01:27 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 7 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92632885
Samirs #6 Tanks 10/24
Sample:T-5 Lab ID:92632885005 Collected:10/24/22 14:25 Received:10/25/22 13:15 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 10/26/22 17:1210/26/22 11:127.2 1
Surrogates
4-Bromofluorobenzene (S)99 %10/26/22 17:12 460-00-410/26/22 11:1266-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 14.5 %10/26/22 16:41 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/01/2022 01:27 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 8 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92632885
Samirs #6 Tanks 10/24
Sample:T-6 Lab ID:92632885006 Collected:10/24/22 14:35 Received:10/25/22 13:15 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)17.4 mg/kg 10/26/22 17:3810/26/22 11:127.1 1
Surrogates
4-Bromofluorobenzene (S)101 %10/26/22 17:38 460-00-410/26/22 11:1266-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 12.2 %10/26/22 16:41 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/01/2022 01:27 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 9 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92632885
Samirs #6 Tanks 10/24
Sample:T-7 Lab ID:92632885007 Collected:10/24/22 15:41 Received:10/25/22 13:15 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)19.0 mg/kg 10/26/22 18:0410/26/22 11:127.9 1
Surrogates
4-Bromofluorobenzene (S)102 %10/26/22 18:04 460-00-410/26/22 11:1266-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 12.3 %10/26/22 16:41 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/01/2022 01:27 PM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 10 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92632885
Samirs #6 Tanks 10/24
Sample:T-8 Lab ID:92632885008 Collected:10/24/22 16:20 Received:10/25/22 13:15 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 10/26/22 18:3010/26/22 11:128.7 1
Surrogates
4-Bromofluorobenzene (S)97 %10/26/22 18:30 460-00-410/26/22 11:1266-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 21.8 %10/26/22 16:42 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/01/2022 01:27 PM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 11 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92632885
Samirs #6 Tanks 10/24
Sample:T-9 Lab ID:92632885009 Collected:10/25/22 10:00 Received:10/25/22 13:15 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8015 GCS THC-Diesel
Diesel Range Organics(C10-C28)7.5 mg/kg 11/01/22 12:1310/28/22 11:355.5 1
Surrogates
n-Pentacosane (S)81 %11/01/22 12:13 629-99-210/28/22 11:3510-130 1
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)6.7 mg/kg 10/26/22 18:5510/26/22 11:126.0 1
Surrogates
4-Bromofluorobenzene (S)103 %10/26/22 18:55 460-00-410/26/22 11:1266-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 9.1 %10/26/22 16:42 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/01/2022 01:27 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 12 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92632885
Samirs #6 Tanks 10/24
Sample:T-10 Lab ID:92632885010 Collected:10/25/22 10:10 Received:10/25/22 13:15 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8015 GCS THC-Diesel
Diesel Range Organics(C10-C28)15.8 mg/kg 11/01/22 12:1310/28/22 11:355.9 1
Surrogates
n-Pentacosane (S)68 %11/01/22 12:13 629-99-210/28/22 11:3510-130 1
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 10/26/22 19:2110/26/22 11:127.8 1
Surrogates
4-Bromofluorobenzene (S)108 %10/26/22 19:21 460-00-410/26/22 11:1266-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 15.3 %10/26/22 16:42 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/01/2022 01:27 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 13 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92632885
Samirs #6 Tanks 10/24
Sample:T-11 Lab ID:92632885011 Collected:10/25/22 10:20 Received:10/25/22 13:15 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8015 GCS THC-Diesel
Diesel Range Organics(C10-C28)25.5 mg/kg 11/01/22 12:3010/28/22 11:356.5 1
Surrogates
n-Pentacosane (S)75 %11/01/22 12:30 629-99-210/28/22 11:3510-130 1
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)44.4 mg/kg 10/26/22 19:4710/26/22 11:129.1 1
Surrogates
4-Bromofluorobenzene (S)103 %10/26/22 19:47 460-00-410/26/22 11:1266-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 22.0 %10/26/22 16:42 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/01/2022 01:27 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 14 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92632885
Samirs #6 Tanks 10/24
Sample:T-12 Lab ID:92632885012 Collected:10/25/22 10:30 Received:10/25/22 13:15 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8015 GCS THC-Diesel
Diesel Range Organics(C10-C28)30.6 mg/kg 11/01/22 12:3010/28/22 11:356.5 1
Surrogates
n-Pentacosane (S)63 %11/01/22 12:30 629-99-210/28/22 11:3510-130 1
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)47.4 mg/kg 10/26/22 20:1310/26/22 11:129.4 1
Surrogates
4-Bromofluorobenzene (S)103 %10/26/22 20:13 460-00-410/26/22 11:1266-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 23.1 %10/26/22 16:42 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/01/2022 01:27 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 15 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92632885
Samirs #6 Tanks 10/24
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
732858
EPA 5030B
EPA 8015C
Gasoline Range Organics
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92632885001, 92632885002, 92632885003, 92632885004, 92632885005, 92632885006, 92632885007,
92632885008, 92632885009, 92632885010, 92632885011, 92632885012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3814347
Associated Lab Samples:92632885001, 92632885002, 92632885003, 92632885004, 92632885005, 92632885006, 92632885007,
92632885008, 92632885009, 92632885010, 92632885011, 92632885012
Matrix:Solid
Analyzed
Gas Range Organics (C6-C10)mg/kg ND 6.0 10/26/22 13:47
4-Bromofluorobenzene (S)%98 66-130 10/26/22 13:47
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3814348LABORATORY CONTROL SAMPLE:
LCSSpike
Gas Range Organics (C6-C10)mg/kg 45.050.1 90 70-130
4-Bromofluorobenzene (S)%100 66-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3814350MATRIX SPIKE SAMPLE:
MSSpike
Result
92632621002
Gas Range Organics (C6-C10)mg/kg 56.661.7 91 65-146ND
4-Bromofluorobenzene (S)%105 66-130
Parameter Units
Dup
Result QualifiersRPDResult
92632621001
3814349SAMPLE DUPLICATE:
Gas Range Organics (C6-C10)mg/kg NDND
4-Bromofluorobenzene (S)%9799
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 11/01/2022 01:27 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 16 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92632885
Samirs #6 Tanks 10/24
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
733380
EPA 3546
EPA 8015C
8015 Solid GCSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92632885009, 92632885010, 92632885011, 92632885012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3817124
Associated Lab Samples:92632885009, 92632885010, 92632885011, 92632885012
Matrix:Solid
Analyzed
Diesel Range Organics(C10-C28)mg/kg ND 5.0 11/01/22 10:30
n-Pentacosane (S)%66 10-130 11/01/22 10:30
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3817125LABORATORY CONTROL SAMPLE:
LCSSpike
Diesel Range Organics(C10-C28)mg/kg 47.967.6 71 44-130
n-Pentacosane (S)%69 10-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3817126MATRIX SPIKE SAMPLE:
MSSpike
Result
92632871001
Diesel Range Organics(C10-C28)mg/kg 55.983.1 64 10-130ND
n-Pentacosane (S)%67 10-130
Parameter Units
Dup
Result QualifiersRPDResult
92632871001
3817127SAMPLE DUPLICATE:
Diesel Range Organics(C10-C28)mg/kg NDND
n-Pentacosane (S)%6867
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 11/01/2022 01:27 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 17 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92632885
Samirs #6 Tanks 10/24
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
732982
SW-846
SW-846
Dry Weight/Percent Moisture
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92632885001, 92632885002, 92632885003, 92632885004, 92632885005, 92632885006, 92632885007,
92632885008, 92632885009, 92632885010, 92632885011, 92632885012
Parameter Units
Dup
Result QualifiersRPDResult
92632725001
3815134SAMPLE DUPLICATE:
Percent Moisture %11.9 N2011.8
Parameter Units
Dup
Result QualifiersRPDResult
92632730003
3815135SAMPLE DUPLICATE:
Percent Moisture %87.2 N2087.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/01/2022 01:27 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 18 of 23
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92632885
Samirs #6 Tanks 10/24
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.N2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 11/01/2022 01:27 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 19 of 23
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92632885
Samirs #6 Tanks 10/24
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92632885009 733380 733735T-9 EPA 3546 EPA 8015C
92632885010 733380 733735T-10 EPA 3546 EPA 8015C
92632885011 733380 733735T-11 EPA 3546 EPA 8015C
92632885012 733380 733735T-12 EPA 3546 EPA 8015C
92632885001 732858 732906T-1 EPA 5030B EPA 8015C
92632885002 732858 732906T-2 EPA 5030B EPA 8015C
92632885003 732858 732906T-3 EPA 5030B EPA 8015C
92632885004 732858 732906T-4 EPA 5030B EPA 8015C
92632885005 732858 732906T-5 EPA 5030B EPA 8015C
92632885006 732858 732906T-6 EPA 5030B EPA 8015C
92632885007 732858 732906T-7 EPA 5030B EPA 8015C
92632885008 732858 732906T-8 EPA 5030B EPA 8015C
92632885009 732858 732906T-9 EPA 5030B EPA 8015C
92632885010 732858 732906T-10 EPA 5030B EPA 8015C
92632885011 732858 732906T-11 EPA 5030B EPA 8015C
92632885012 732858 732906T-12 EPA 5030B EPA 8015C
92632885001 732982T-1 SW-846
92632885002 732982T-2 SW-846
92632885003 732982T-3 SW-846
92632885004 732982T-4 SW-846
92632885005 732982T-5 SW-846
92632885006 732982T-6 SW-846
92632885007 732982T-7 SW-846
92632885008 732982T-8 SW-846
92632885009 732982T-9 SW-846
92632885010 732982T-10 SW-846
92632885011 732982T-11 SW-846
92632885012 732982T-12 SW-846
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 11/01/2022 01:27 PM
Pace Analytical Services, LLC
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Asheville, NC 28804
[phone]
Page 20 of 23
Page 21 of 23
Page 22 of 23
Page 23 of 23
#=CL#
November 09, 2022
LIMS USE: FR - CHRIS SINGLETON
LIMS OBJECT ID: 92634270
92634270
Project:
Pace Project No.:
RE:
Chris Singleton
Singleton Environmental
105 Charlotte Highway
Asheville, NC 28803
SAMIR'S #6 11/1/22
Dear Chris Singleton:
Enclosed are the analytical results for sample(s) received by the laboratory on November 02, 2022. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor Dyson for
[e-mail]
Project Manager
Lorri Patton
1(828)254-7176
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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2225 Riverside Dr.
Asheville, NC 28804
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Page 1 of 16
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92634270
SAMIR'S #6 11/1/22
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 16
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92634270
SAMIR'S #6 11/1/22
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92634270001 D-1 EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
92634270002 D-2 EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
92634270003 D-3 EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
92634270004 D-4 EPA 8015C 2 PASI-CAP2
EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 3 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92634270
SAMIR'S #6 11/1/22
Sample:D-1 Lab ID:92634270001 Collected:11/01/22 09:00 Received:11/02/22 12:36 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 11/07/22 15:5711/07/22 09:538.4 1
Surrogates
4-Bromofluorobenzene (S)94 %11/07/22 15:57 460-00-411/07/22 09:5366-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 19.8 %11/03/22 17:52 N20.10 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 11/09/2022 10:48 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 4 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92634270
SAMIR'S #6 11/1/22
Sample:D-2 Lab ID:92634270002 Collected:11/01/22 09:30 Received:11/02/22 12:36 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 11/04/22 17:4111/04/22 13:357.7 1
Surrogates
4-Bromofluorobenzene (S)93 %11/04/22 17:41 460-00-411/04/22 13:3566-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 17.0 %11/03/22 17:52 N20.10 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 11/09/2022 10:48 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 5 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92634270
SAMIR'S #6 11/1/22
Sample:D-3 Lab ID:92634270003 Collected:11/01/22 09:40 Received:11/02/22 12:36 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 11/04/22 18:0611/04/22 13:358.4 1
Surrogates
4-Bromofluorobenzene (S)94 %11/04/22 18:06 460-00-411/04/22 13:3566-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 16.1 %11/03/22 17:52 N20.10 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 11/09/2022 10:48 AM
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2225 Riverside Dr.
Asheville, NC 28804
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Page 6 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92634270
SAMIR'S #6 11/1/22
Sample:D-4 Lab ID:92634270004 Collected:11/01/22 09:50 Received:11/02/22 12:36 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8015 GCS THC-Diesel
Diesel Range Organics(C10-C28)506 mg/kg 11/08/22 11:4511/07/22 10:2311.9 2
Surrogates
n-Pentacosane (S)82 %11/08/22 11:45 629-99-211/07/22 10:2310-130 2
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 11/07/22 16:2311/07/22 09:537.4 1
Surrogates
4-Bromofluorobenzene (S)95 %11/07/22 16:23 460-00-411/07/22 09:5366-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 15.2 %11/03/22 17:52 N20.10 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 11/09/2022 10:48 AM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 7 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92634270
SAMIR'S #6 11/1/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
735016
EPA 5030B
EPA 8015C
Gasoline Range Organics
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92634270002, 92634270003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3825614
Associated Lab Samples:92634270002, 92634270003
Matrix:Solid
Analyzed
Gas Range Organics (C6-C10)mg/kg ND 6.0 11/04/22 13:49
4-Bromofluorobenzene (S)%95 66-130 11/04/22 13:49
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3825615LABORATORY CONTROL SAMPLE:
LCSSpike
Gas Range Organics (C6-C10)mg/kg 47.450 95 70-130
4-Bromofluorobenzene (S)%96 66-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3825617MATRIX SPIKE SAMPLE:
MSSpike
Result
92633504007
Gas Range Organics (C6-C10)mg/kg 55.172.7 73 65-146ND
4-Bromofluorobenzene (S)%94 66-130
Parameter Units
Dup
Result QualifiersRPDResult
92634411016
3825616SAMPLE DUPLICATE:
Gas Range Organics (C6-C10)mg/kg NDND
4-Bromofluorobenzene (S)%9493
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 11/09/2022 10:48 AM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 8 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92634270
SAMIR'S #6 11/1/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
735280
EPA 5030B
EPA 8015C
Gasoline Range Organics
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92634270001, 92634270004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3826756
Associated Lab Samples:92634270001, 92634270004
Matrix:Solid
Analyzed
Gas Range Organics (C6-C10)mg/kg ND 6.0 11/07/22 12:31
4-Bromofluorobenzene (S)%94 66-130 11/07/22 12:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3826757LABORATORY CONTROL SAMPLE:
LCSSpike
Gas Range Organics (C6-C10)mg/kg 47.449.9 95 70-130
4-Bromofluorobenzene (S)%93 66-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3826759MATRIX SPIKE SAMPLE:
MSSpike
Result
92633504011
Gas Range Organics (C6-C10)mg/kg 10267 108 65-14629.2
4-Bromofluorobenzene (S)%94 66-130
Parameter Units
Dup
Result QualifiersRPDResult
92633504008
3826758SAMPLE DUPLICATE:
Gas Range Organics (C6-C10)mg/kg 4.4J4.4J
4-Bromofluorobenzene (S)%9393
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 11/09/2022 10:48 AM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 9 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92634270
SAMIR'S #6 11/1/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
735240
EPA 3546
EPA 8015C
8015 Solid GCSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92634270004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3826629
Associated Lab Samples:92634270004
Matrix:Solid
Analyzed
Diesel Range Organics(C10-C28)mg/kg ND 4.9 11/08/22 08:44
n-Pentacosane (S)%76 10-130 11/08/22 08:44
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3826630LABORATORY CONTROL SAMPLE:
LCSSpike
Diesel Range Organics(C10-C28)mg/kg 45.367.3 67 44-130
n-Pentacosane (S)%65 10-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3826631MATRIX SPIKE SAMPLE:
MSSpike
Result
92633504003
Diesel Range Organics(C10-C28)mg/kg 62.176.5 74 10-1305.7J
n-Pentacosane (S)%75 10-130
Parameter Units
Dup
Result QualifiersRPDResult
92633504004
3826632SAMPLE DUPLICATE:
Diesel Range Organics(C10-C28)mg/kg 60.7 1570.4
n-Pentacosane (S)%7073
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/09/2022 10:48 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 10 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92634270
SAMIR'S #6 11/1/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
734757
SW-846
SW-846
Dry Weight/Percent Moisture
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92634270001, 92634270002, 92634270003, 92634270004
Parameter Units
Dup
Result QualifiersRPDResult
92634202001
3824198SAMPLE DUPLICATE:
Percent Moisture %13.3 N2013.2
Parameter Units
Dup
Result QualifiersRPDResult
92634517001
3824591SAMPLE DUPLICATE:
Percent Moisture %12.7 N2213.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/09/2022 10:48 AM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 11 of 16
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92634270
SAMIR'S #6 11/1/22
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.N2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/09/2022 10:48 AM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 12 of 16
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92634270
SAMIR'S #6 11/1/22
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92634270004 735240 735421D-4 EPA 3546 EPA 8015C
92634270001 735280 735297D-1 EPA 5030B EPA 8015C
92634270002 735016 735038D-2 EPA 5030B EPA 8015C
92634270003 735016 735038D-3 EPA 5030B EPA 8015C
92634270004 735280 735297D-4 EPA 5030B EPA 8015C
92634270001 734757D-1 SW-846
92634270002 734757D-2 SW-846
92634270003 734757D-3 SW-846
92634270004 734757D-4 SW-846
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/09/2022 10:48 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 13 of 16
Page 14 of 16
Page 15 of 16
Page 16 of 16
#=CL#
December 20, 2022
LIMS USE: FR - CHRIS SINGLETON
LIMS OBJECT ID: 92641136
92641136
Project:
Pace Project No.:
RE:
Chris Singleton
Singleton Environmental
105 Charlotte Highway
Asheville, NC 28803
SAMIR'S #6 12/9/22
Dear Chris Singleton:
Enclosed are the analytical results for sample(s) received by the laboratory on December 09, 2022. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
Project Manager
1(828)254-7176
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 1 of 51
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 51
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92641136001 MW-1R SOIL MADEP EPH 7 PASI-CBAJ
EPA 8270E 72 PASI-CBPJ
EPA 8260D 70 PASI-CLMB
SW-846 1 PASI-CKDF
92641136002 MW-1R EPA 625.1 58 PASI-CPKS
SM 6200B 63 PASI-CSAS
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 3 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Sample:MW-1R SOIL Lab ID:92641136001 Collected:12/09/22 10:00 Received:12/09/22 14:51 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Pace Analytical Services - Charlotte
MADEP EPH NC Soil
Aliphatic (C09-C18)ND mg/kg 12/15/22 10:41 N212/14/22 11:0312.8 1
Aliphatic (C19-C36)ND mg/kg 12/15/22 10:41 N212/14/22 11:0312.8 1
Aromatic (C11-C22)ND mg/kg 12/14/22 19:59 N212/14/22 11:0312.8 1
Surrogates
1-Chlorooctadecane (S)64 %12/15/22 10:41 3386-33-212/14/22 11:0340-140 1
o-Terphenyl (S)85 %12/14/22 19:59 84-15-112/14/22 11:0340-140 1
2-Fluorobiphenyl (S)113 %12/14/22 19:59 321-60-812/14/22 11:0340-140 1
2-Bromonaphthalene (S)121 %12/14/22 19:59 580-13-212/14/22 11:0340-140 1
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Acenaphthene ND mg/kg 12/18/22 10:36 83-32-912/16/22 12:490.43 1
Acenaphthylene ND mg/kg 12/18/22 10:36 208-96-812/16/22 12:490.43 1
Anthracene ND mg/kg 12/18/22 10:36 120-12-712/16/22 12:490.43 1
Benzo(a)anthracene ND mg/kg 12/18/22 10:36 56-55-312/16/22 12:490.43 1
Benzo(a)pyrene ND mg/kg 12/18/22 10:36 50-32-812/16/22 12:490.43 1
Benzo(b)fluoranthene ND mg/kg 12/18/22 10:36 205-99-212/16/22 12:490.43 1
Benzo(g,h,i)perylene ND mg/kg 12/18/22 10:36 191-24-212/16/22 12:490.43 1
Benzo(k)fluoranthene ND mg/kg 12/18/22 10:36 207-08-912/16/22 12:490.43 1
Benzoic Acid ND mg/kg 12/18/22 10:36 65-85-012/16/22 12:492.1 1
Benzyl alcohol ND mg/kg 12/18/22 10:36 100-51-612/16/22 12:490.85 1
4-Bromophenylphenyl ether ND mg/kg 12/18/22 10:36 101-55-312/16/22 12:490.43 1
Butylbenzylphthalate ND mg/kg 12/18/22 10:36 85-68-712/16/22 12:490.43 1
4-Chloro-3-methylphenol ND mg/kg 12/18/22 10:36 59-50-712/16/22 12:490.85 1
4-Chloroaniline ND mg/kg 12/18/22 10:36 106-47-812/16/22 12:490.85 1
bis(2-Chloroethoxy)methane ND mg/kg 12/18/22 10:36 111-91-112/16/22 12:490.43 1
bis(2-Chloroethyl) ether ND mg/kg 12/18/22 10:36 111-44-412/16/22 12:490.43 1
2-Chloronaphthalene ND mg/kg 12/18/22 10:36 91-58-712/16/22 12:490.43 1
2-Chlorophenol ND mg/kg 12/18/22 10:36 95-57-812/16/22 12:490.43 1
4-Chlorophenylphenyl ether ND mg/kg 12/18/22 10:36 7005-72-312/16/22 12:490.43 1
Chrysene ND mg/kg 12/18/22 10:36 218-01-912/16/22 12:490.43 1
Dibenz(a,h)anthracene ND mg/kg 12/18/22 10:36 53-70-312/16/22 12:490.43 1
Dibenzofuran ND mg/kg 12/18/22 10:36 132-64-912/16/22 12:490.43 1
1,2-Dichlorobenzene ND mg/kg 12/18/22 10:36 95-50-112/16/22 12:490.43 1
1,3-Dichlorobenzene ND mg/kg 12/18/22 10:36 541-73-112/16/22 12:490.43 1
1,4-Dichlorobenzene ND mg/kg 12/18/22 10:36 106-46-712/16/22 12:490.43 1
3,3'-Dichlorobenzidine ND mg/kg 12/18/22 10:36 91-94-112/16/22 12:490.85 1
2,4-Dichlorophenol ND mg/kg 12/18/22 10:36 120-83-212/16/22 12:490.43 1
Diethylphthalate ND mg/kg 12/18/22 10:36 84-66-212/16/22 12:490.43 1
2,4-Dimethylphenol ND mg/kg 12/18/22 10:36 105-67-912/16/22 12:490.43 1
Dimethylphthalate ND mg/kg 12/18/22 10:36 131-11-312/16/22 12:490.43 1
Di-n-butylphthalate ND mg/kg 12/18/22 10:36 84-74-2 v112/16/22 12:490.43 1
4,6-Dinitro-2-methylphenol ND mg/kg 12/18/22 10:36 534-52-112/16/22 12:490.85 1
2,4-Dinitrophenol ND mg/kg 12/18/22 10:36 51-28-512/16/22 12:492.1 1
2,4-Dinitrotoluene ND mg/kg 12/18/22 10:36 121-14-212/16/22 12:490.43 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Sample:MW-1R SOIL Lab ID:92641136001 Collected:12/09/22 10:00 Received:12/09/22 14:51 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
2,6-Dinitrotoluene ND mg/kg 12/18/22 10:36 606-20-212/16/22 12:490.43 1
Di-n-octylphthalate ND mg/kg 12/18/22 10:36 117-84-012/16/22 12:490.43 1
bis(2-Ethylhexyl)phthalate ND mg/kg 12/18/22 10:36 117-81-712/16/22 12:490.43 1
Fluoranthene ND mg/kg 12/18/22 10:36 206-44-012/16/22 12:490.43 1
Fluorene ND mg/kg 12/18/22 10:36 86-73-712/16/22 12:490.43 1
Hexachloro-1,3-butadiene ND mg/kg 12/18/22 10:36 87-68-312/16/22 12:490.43 1
Hexachlorobenzene ND mg/kg 12/18/22 10:36 118-74-112/16/22 12:490.43 1
Hexachlorocyclopentadiene ND mg/kg 12/18/22 10:36 77-47-412/16/22 12:490.43 1
Hexachloroethane ND mg/kg 12/18/22 10:36 67-72-112/16/22 12:490.43 1
Indeno(1,2,3-cd)pyrene ND mg/kg 12/18/22 10:36 193-39-512/16/22 12:490.43 1
Isophorone ND mg/kg 12/18/22 10:36 78-59-112/16/22 12:490.43 1
1-Methylnaphthalene ND mg/kg 12/18/22 10:36 90-12-012/16/22 12:490.43 1
2-Methylnaphthalene ND mg/kg 12/18/22 10:36 91-57-612/16/22 12:490.43 1
2-Methylphenol(o-Cresol)ND mg/kg 12/18/22 10:36 95-48-712/16/22 12:490.43 1
3&4-Methylphenol(m&p Cresol)ND mg/kg 12/18/22 10:36 15831-10-412/16/22 12:490.43 1
Naphthalene ND mg/kg 12/18/22 10:36 91-20-312/16/22 12:490.43 1
2-Nitroaniline ND mg/kg 12/18/22 10:36 88-74-412/16/22 12:492.1 1
3-Nitroaniline ND mg/kg 12/18/22 10:36 99-09-212/16/22 12:492.1 1
4-Nitroaniline ND mg/kg 12/18/22 10:36 100-01-612/16/22 12:490.85 1
Nitrobenzene ND mg/kg 12/18/22 10:36 98-95-312/16/22 12:490.43 1
2-Nitrophenol ND mg/kg 12/18/22 10:36 88-75-512/16/22 12:490.43 1
4-Nitrophenol ND mg/kg 12/18/22 10:36 100-02-712/16/22 12:492.1 1
N-Nitrosodimethylamine ND mg/kg 12/18/22 10:36 62-75-912/16/22 12:490.43 1
N-Nitroso-di-n-propylamine ND mg/kg 12/18/22 10:36 621-64-712/16/22 12:490.43 1
N-Nitrosodiphenylamine ND mg/kg 12/18/22 10:36 86-30-612/16/22 12:490.43 1
Pentachlorophenol ND mg/kg 12/18/22 10:36 87-86-512/16/22 12:490.85 1
Phenanthrene ND mg/kg 12/18/22 10:36 85-01-812/16/22 12:490.43 1
Phenol ND mg/kg 12/18/22 10:36 108-95-212/16/22 12:490.43 1
Pyrene ND mg/kg 12/18/22 10:36 129-00-012/16/22 12:490.43 1
1,2,4-Trichlorobenzene ND mg/kg 12/18/22 10:36 120-82-112/16/22 12:490.43 1
2,4,5-Trichlorophenol ND mg/kg 12/18/22 10:36 95-95-412/16/22 12:490.43 1
2,4,6-Trichlorophenol ND mg/kg 12/18/22 10:36 88-06-212/16/22 12:490.43 1
Surrogates
Nitrobenzene-d5 (S)55 %12/18/22 10:36 4165-60-012/16/22 12:4910-130 1
2-Fluorobiphenyl (S)32 %12/18/22 10:36 321-60-812/16/22 12:4910-130 1
Terphenyl-d14 (S)53 %12/18/22 10:36 1718-51-012/16/22 12:4910-130 1
Phenol-d6 (S)52 %12/18/22 10:36 13127-88-312/16/22 12:4910-130 1
2-Fluorophenol (S)53 %12/18/22 10:36 367-12-412/16/22 12:4910-130 1
2,4,6-Tribromophenol (S)48 %12/18/22 10:36 118-79-612/16/22 12:4910-131 1
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone ND mg/kg 12/12/22 22:31 67-64-112/12/22 17:360.14 1
Benzene ND mg/kg 12/12/22 22:31 71-43-212/12/22 17:360.0070 1
Bromobenzene ND mg/kg 12/12/22 22:31 108-86-112/12/22 17:360.0070 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
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[phone]
Page 5 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Sample:MW-1R SOIL Lab ID:92641136001 Collected:12/09/22 10:00 Received:12/09/22 14:51 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Bromochloromethane ND mg/kg 12/12/22 22:31 74-97-512/12/22 17:360.0070 1
Bromodichloromethane ND mg/kg 12/12/22 22:31 75-27-412/12/22 17:360.0070 1
Bromoform ND mg/kg 12/12/22 22:31 75-25-212/12/22 17:360.0070 1
Bromomethane ND mg/kg 12/12/22 22:31 74-83-9 v112/12/22 17:360.014 1
2-Butanone (MEK)ND mg/kg 12/12/22 22:31 78-93-312/12/22 17:360.14 1
n-Butylbenzene 0.18 mg/kg 12/12/22 22:31 104-51-812/12/22 17:360.0070 1
sec-Butylbenzene ND mg/kg 12/12/22 22:31 135-98-812/12/22 17:360.0070 1
tert-Butylbenzene ND mg/kg 12/12/22 22:31 98-06-612/12/22 17:360.0070 1
Carbon tetrachloride ND mg/kg 12/12/22 22:31 56-23-512/12/22 17:360.0070 1
Chlorobenzene 0.016 mg/kg 12/12/22 22:31 108-90-712/12/22 17:360.0070 1
Chloroethane ND mg/kg 12/12/22 22:31 75-00-312/12/22 17:360.014 1
Chloroform ND mg/kg 12/12/22 22:31 67-66-312/12/22 17:360.0070 1
Chloromethane ND mg/kg 12/12/22 22:31 74-87-312/12/22 17:360.014 1
2-Chlorotoluene ND mg/kg 12/12/22 22:31 95-49-812/12/22 17:360.0070 1
4-Chlorotoluene ND mg/kg 12/12/22 22:31 106-43-412/12/22 17:360.0070 1
1,2-Dibromo-3-chloropropane ND mg/kg 12/12/22 22:31 96-12-812/12/22 17:360.0070 1
Dibromochloromethane ND mg/kg 12/12/22 22:31 124-48-112/12/22 17:360.0070 1
1,2-Dibromoethane (EDB)ND mg/kg 12/12/22 22:31 106-93-412/12/22 17:360.0070 1
Dibromomethane ND mg/kg 12/12/22 22:31 74-95-312/12/22 17:360.0070 1
1,2-Dichlorobenzene ND mg/kg 12/12/22 22:31 95-50-112/12/22 17:360.0070 1
1,3-Dichlorobenzene ND mg/kg 12/12/22 22:31 541-73-112/12/22 17:360.0070 1
1,4-Dichlorobenzene ND mg/kg 12/12/22 22:31 106-46-712/12/22 17:360.0070 1
Dichlorodifluoromethane ND mg/kg 12/12/22 22:31 75-71-812/12/22 17:360.014 1
1,1-Dichloroethane ND mg/kg 12/12/22 22:31 75-34-312/12/22 17:360.0070 1
1,2-Dichloroethane ND mg/kg 12/12/22 22:31 107-06-212/12/22 17:360.0070 1
1,1-Dichloroethene ND mg/kg 12/12/22 22:31 75-35-412/12/22 17:360.0070 1
cis-1,2-Dichloroethene ND mg/kg 12/12/22 22:31 156-59-212/12/22 17:360.0070 1
trans-1,2-Dichloroethene ND mg/kg 12/12/22 22:31 156-60-512/12/22 17:360.0070 1
1,2-Dichloropropane ND mg/kg 12/12/22 22:31 78-87-512/12/22 17:360.0070 1
1,3-Dichloropropane ND mg/kg 12/12/22 22:31 142-28-912/12/22 17:360.0070 1
2,2-Dichloropropane ND mg/kg 12/12/22 22:31 594-20-712/12/22 17:360.0070 1
1,1-Dichloropropene ND mg/kg 12/12/22 22:31 563-58-612/12/22 17:360.0070 1
cis-1,3-Dichloropropene ND mg/kg 12/12/22 22:31 10061-01-512/12/22 17:360.0070 1
trans-1,3-Dichloropropene ND mg/kg 12/12/22 22:31 10061-02-612/12/22 17:360.0070 1
Diisopropyl ether ND mg/kg 12/12/22 22:31 108-20-312/12/22 17:360.0070 1
Ethylbenzene 0.013 mg/kg 12/12/22 22:31 100-41-412/12/22 17:360.0070 1
Hexachloro-1,3-butadiene ND mg/kg 12/12/22 22:31 87-68-312/12/22 17:360.014 1
2-Hexanone ND mg/kg 12/12/22 22:31 591-78-612/12/22 17:360.070 1
Isopropylbenzene (Cumene)0.13 mg/kg 12/12/22 22:31 98-82-812/12/22 17:360.0070 1
p-Isopropyltoluene ND mg/kg 12/12/22 22:31 99-87-612/12/22 17:360.0070 1
Methylene Chloride ND mg/kg 12/12/22 22:31 75-09-212/12/22 17:360.028 1
4-Methyl-2-pentanone (MIBK)ND mg/kg 12/12/22 22:31 108-10-112/12/22 17:360.070 1
Methyl-tert-butyl ether ND mg/kg 12/12/22 22:31 1634-04-412/12/22 17:360.0070 1
Naphthalene 0.025 mg/kg 12/12/22 22:31 91-20-312/12/22 17:360.0070 1
n-Propylbenzene 0.42 mg/kg 12/12/22 22:31 103-65-112/12/22 17:360.0070 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 6 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Sample:MW-1R SOIL Lab ID:92641136001 Collected:12/09/22 10:00 Received:12/09/22 14:51 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Styrene ND mg/kg 12/12/22 22:31 100-42-512/12/22 17:360.0070 1
1,1,1,2-Tetrachloroethane ND mg/kg 12/12/22 22:31 630-20-612/12/22 17:360.0070 1
1,1,2,2-Tetrachloroethane ND mg/kg 12/12/22 22:31 79-34-512/12/22 17:360.0070 1
Tetrachloroethene ND mg/kg 12/12/22 22:31 127-18-412/12/22 17:360.0070 1
Toluene 0.0074 mg/kg 12/12/22 22:31 108-88-312/12/22 17:360.0070 1
1,2,3-Trichlorobenzene ND mg/kg 12/12/22 22:31 87-61-612/12/22 17:360.0070 1
1,2,4-Trichlorobenzene ND mg/kg 12/12/22 22:31 120-82-112/12/22 17:360.0070 1
1,1,1-Trichloroethane ND mg/kg 12/12/22 22:31 71-55-612/12/22 17:360.0070 1
1,1,2-Trichloroethane ND mg/kg 12/12/22 22:31 79-00-512/12/22 17:360.0070 1
Trichloroethene ND mg/kg 12/12/22 22:31 79-01-612/12/22 17:360.0070 1
Trichlorofluoromethane ND mg/kg 12/12/22 22:31 75-69-412/12/22 17:360.0070 1
1,2,3-Trichloropropane ND mg/kg 12/12/22 22:31 96-18-412/12/22 17:360.0070 1
1,2,4-Trimethylbenzene 0.24 mg/kg 12/12/22 22:31 95-63-612/12/22 17:360.0070 1
1,3,5-Trimethylbenzene 0.040 mg/kg 12/12/22 22:31 108-67-812/12/22 17:360.0070 1
Vinyl acetate ND mg/kg 12/12/22 22:31 108-05-412/12/22 17:360.070 1
Vinyl chloride ND mg/kg 12/12/22 22:31 75-01-412/12/22 17:360.014 1
Xylene (Total)0.055 mg/kg 12/12/22 22:31 1330-20-712/12/22 17:360.014 1
m&p-Xylene 0.043 mg/kg 12/12/22 22:31 179601-23-112/12/22 17:360.014 1
o-Xylene 0.012 mg/kg 12/12/22 22:31 95-47-612/12/22 17:360.0070 1
Surrogates
Toluene-d8 (S)105 %12/12/22 22:31 2037-26-512/12/22 17:3670-130 1
4-Bromofluorobenzene (S)106 %12/12/22 22:31 460-00-412/12/22 17:3670-130 1
1,2-Dichloroethane-d4 (S)111 %12/12/22 22:31 17060-07-012/12/22 17:3670-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 21.8 %12/12/22 14:44 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 7 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Sample:MW-1R Lab ID:92641136002 Collected:12/09/22 13:45 Received:12/09/22 14:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Acenaphthene ND ug/L 12/16/22 04:31 83-32-912/14/22 10:574.2 1
Acenaphthylene ND ug/L 12/16/22 04:31 208-96-812/14/22 10:574.2 1
Anthracene ND ug/L 12/16/22 04:31 120-12-712/14/22 10:574.2 1
Benzo(a)anthracene ND ug/L 12/16/22 04:31 56-55-312/14/22 10:574.2 1
Benzo(a)pyrene ND ug/L 12/16/22 04:31 50-32-812/14/22 10:574.2 1
Benzo(b)fluoranthene ND ug/L 12/16/22 04:31 205-99-212/14/22 10:574.2 1
Benzo(g,h,i)perylene ND ug/L 12/16/22 04:31 191-24-212/14/22 10:574.2 1
Benzo(k)fluoranthene ND ug/L 12/16/22 04:31 207-08-912/14/22 10:574.2 1
4-Bromophenylphenyl ether ND ug/L 12/16/22 04:31 101-55-312/14/22 10:574.2 1
Butylbenzylphthalate ND ug/L 12/16/22 04:31 85-68-712/14/22 10:574.2 1
4-Chloro-3-methylphenol ND ug/L 12/16/22 04:31 59-50-712/14/22 10:574.2 1
bis(2-Chloroethoxy)methane ND ug/L 12/16/22 04:31 111-91-112/14/22 10:578.3 1
bis(2-Chloroethyl) ether ND ug/L 12/16/22 04:31 111-44-412/14/22 10:574.2 1
2-Chloronaphthalene ND ug/L 12/16/22 04:31 91-58-712/14/22 10:574.2 1
2-Chlorophenol ND ug/L 12/16/22 04:31 95-57-812/14/22 10:574.2 1
4-Chlorophenylphenyl ether ND ug/L 12/16/22 04:31 7005-72-312/14/22 10:574.2 1
Chrysene ND ug/L 12/16/22 04:31 218-01-912/14/22 10:574.2 1
Dibenz(a,h)anthracene ND ug/L 12/16/22 04:31 53-70-312/14/22 10:574.2 1
3,3'-Dichlorobenzidine ND ug/L 12/16/22 04:31 91-94-112/14/22 10:578.3 1
2,4-Dichlorophenol ND ug/L 12/16/22 04:31 120-83-212/14/22 10:574.2 1
Diethylphthalate ND ug/L 12/16/22 04:31 84-66-212/14/22 10:574.2 1
2,4-Dimethylphenol ND ug/L 12/16/22 04:31 105-67-9 L112/14/22 10:578.3 1
Dimethylphthalate ND ug/L 12/16/22 04:31 131-11-312/14/22 10:574.2 1
Di-n-butylphthalate ND ug/L 12/16/22 04:31 84-74-212/14/22 10:574.2 1
4,6-Dinitro-2-methylphenol ND ug/L 12/16/22 04:31 534-52-112/14/22 10:578.3 1
2,4-Dinitrophenol ND ug/L 12/16/22 04:31 51-28-512/14/22 10:5741.7 1
2,4-Dinitrotoluene ND ug/L 12/16/22 04:31 121-14-212/14/22 10:574.2 1
2,6-Dinitrotoluene ND ug/L 12/16/22 04:31 606-20-212/14/22 10:574.2 1
Di-n-octylphthalate ND ug/L 12/16/22 04:31 117-84-012/14/22 10:574.2 1
bis(2-Ethylhexyl)phthalate ND ug/L 12/16/22 04:31 117-81-712/14/22 10:574.2 1
Fluoranthene ND ug/L 12/16/22 04:31 206-44-012/14/22 10:574.2 1
Fluorene ND ug/L 12/16/22 04:31 86-73-712/14/22 10:574.2 1
Hexachloro-1,3-butadiene ND ug/L 12/16/22 04:31 87-68-312/14/22 10:574.2 1
Hexachlorobenzene ND ug/L 12/16/22 04:31 118-74-112/14/22 10:574.2 1
Hexachlorocyclopentadiene ND ug/L 12/16/22 04:31 77-47-412/14/22 10:578.3 1
Hexachloroethane ND ug/L 12/16/22 04:31 67-72-112/14/22 10:574.2 1
Indeno(1,2,3-cd)pyrene ND ug/L 12/16/22 04:31 193-39-512/14/22 10:574.2 1
Isophorone ND ug/L 12/16/22 04:31 78-59-112/14/22 10:578.3 1
Naphthalene 22.8 ug/L 12/16/22 04:31 91-20-312/14/22 10:574.2 1
Nitrobenzene ND ug/L 12/16/22 04:31 98-95-312/14/22 10:574.2 1
2-Nitrophenol ND ug/L 12/16/22 04:31 88-75-512/14/22 10:574.2 1
4-Nitrophenol ND ug/L 12/16/22 04:31 100-02-712/14/22 10:578.3 1
N-Nitrosodimethylamine ND ug/L 12/16/22 04:31 62-75-912/14/22 10:574.2 1
N-Nitroso-di-n-propylamine ND ug/L 12/16/22 04:31 621-64-712/14/22 10:574.2 1
N-Nitrosodiphenylamine ND ug/L 12/16/22 04:31 86-30-612/14/22 10:578.3 1
2,2'-Oxybis(1-chloropropane)ND ug/L 12/16/22 04:31 108-60-112/14/22 10:574.2 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 8 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Sample:MW-1R Lab ID:92641136002 Collected:12/09/22 13:45 Received:12/09/22 14:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Pentachlorophenol ND ug/L 12/16/22 04:31 87-86-512/14/22 10:578.3 1
Phenanthrene ND ug/L 12/16/22 04:31 85-01-812/14/22 10:574.2 1
Phenol ND ug/L 12/16/22 04:31 108-95-212/14/22 10:574.2 1
Pyrene ND ug/L 12/16/22 04:31 129-00-012/14/22 10:574.2 1
1,2,4-Trichlorobenzene ND ug/L 12/16/22 04:31 120-82-112/14/22 10:574.2 1
2,4,6-Trichlorophenol ND ug/L 12/16/22 04:31 88-06-212/14/22 10:578.3 1
Surrogates
Nitrobenzene-d5 (S)52 %12/16/22 04:31 4165-60-012/14/22 10:5710-120 1
2-Fluorobiphenyl (S)44 %12/16/22 04:31 321-60-812/14/22 10:5715-120 1
Terphenyl-d14 (S)72 %12/16/22 04:31 1718-51-012/14/22 10:5711-131 1
Phenol-d6 (S)42 %12/16/22 04:31 13127-88-312/14/22 10:5710-120 1
2-Fluorophenol (S)43 %12/16/22 04:31 367-12-412/14/22 10:5710-120 1
2,4,6-Tribromophenol (S)62 %12/16/22 04:31 118-79-612/14/22 10:5710-137 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 12.6 ug/L 12/14/22 18:53 71-43-20.50 1
Bromobenzene ND ug/L 12/14/22 18:53 108-86-10.50 1
Bromochloromethane ND ug/L 12/14/22 18:53 74-97-50.50 1
Bromodichloromethane ND ug/L 12/14/22 18:53 75-27-40.50 1
Bromoform ND ug/L 12/14/22 18:53 75-25-20.50 1
Bromomethane ND ug/L 12/14/22 18:53 74-83-95.0 1
n-Butylbenzene 13.9 ug/L 12/14/22 18:53 104-51-80.50 1
sec-Butylbenzene ND ug/L 12/14/22 18:53 135-98-80.50 1
tert-Butylbenzene ND ug/L 12/14/22 18:53 98-06-60.50 1
Carbon tetrachloride ND ug/L 12/14/22 18:53 56-23-50.50 1
Chlorobenzene ND ug/L 12/14/22 18:53 108-90-70.50 1
Chloroethane ND ug/L 12/14/22 18:53 75-00-31.0 1
Chloroform ND ug/L 12/14/22 18:53 67-66-30.50 1
Chloromethane ND ug/L 12/14/22 18:53 74-87-31.0 1
2-Chlorotoluene ND ug/L 12/14/22 18:53 95-49-80.50 1
4-Chlorotoluene ND ug/L 12/14/22 18:53 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 12/14/22 18:53 96-12-81.0 1
Dibromochloromethane ND ug/L 12/14/22 18:53 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 12/14/22 18:53 106-93-40.50 1
Dibromomethane ND ug/L 12/14/22 18:53 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 12/14/22 18:53 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 12/14/22 18:53 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 12/14/22 18:53 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 12/14/22 18:53 75-71-80.50 1
1,1-Dichloroethane ND ug/L 12/14/22 18:53 75-34-30.50 1
1,2-Dichloroethane ND ug/L 12/14/22 18:53 107-06-20.50 1
1,1-Dichloroethene ND ug/L 12/14/22 18:53 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 12/14/22 18:53 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 12/14/22 18:53 156-60-50.50 1
1,2-Dichloropropane ND ug/L 12/14/22 18:53 78-87-50.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 9 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Sample:MW-1R Lab ID:92641136002 Collected:12/09/22 13:45 Received:12/09/22 14:51 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,3-Dichloropropane ND ug/L 12/14/22 18:53 142-28-90.50 1
2,2-Dichloropropane ND ug/L 12/14/22 18:53 594-20-70.50 1
1,1-Dichloropropene ND ug/L 12/14/22 18:53 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 12/14/22 18:53 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 12/14/22 18:53 10061-02-60.50 1
Diisopropyl ether ND ug/L 12/14/22 18:53 108-20-30.50 1
Ethylbenzene 116 ug/L 12/14/22 18:53 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 12/14/22 18:53 87-68-32.0 1
Isopropylbenzene (Cumene)21.2 ug/L 12/14/22 18:53 98-82-80.50 1
Methylene Chloride ND ug/L 12/14/22 18:53 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 12/14/22 18:53 1634-04-40.50 1
Naphthalene 49.1 ug/L 12/14/22 18:53 91-20-32.0 1
n-Propylbenzene 59.2 ug/L 12/14/22 18:53 103-65-10.50 1
Styrene ND ug/L 12/14/22 18:53 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 12/14/22 18:53 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 12/14/22 18:53 79-34-50.50 1
Tetrachloroethene ND ug/L 12/14/22 18:53 127-18-40.50 1
Toluene 13.8 ug/L 12/14/22 18:53 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 12/14/22 18:53 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 12/14/22 18:53 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 12/14/22 18:53 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 12/14/22 18:53 79-00-50.50 1
Trichloroethene ND ug/L 12/14/22 18:53 79-01-60.50 1
Trichlorofluoromethane ND ug/L 12/14/22 18:53 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 12/14/22 18:53 96-18-40.50 1
1,2,4-Trimethylbenzene 125 ug/L 12/14/22 18:53 95-63-60.50 1
1,3,5-Trimethylbenzene 19.0 ug/L 12/14/22 18:53 108-67-80.50 1
Vinyl chloride ND ug/L 12/14/22 18:53 75-01-41.0 1
m&p-Xylene 183 ug/L 12/14/22 18:53 179601-23-11.0 1
o-Xylene 3.0 ug/L 12/14/22 18:53 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)100 %12/14/22 18:53 17060-07-070-130 1
4-Bromofluorobenzene (S)100 %12/14/22 18:53 460-00-470-130 1
Toluene-d8 (S)99 %12/14/22 18:53 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 10 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
743441
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92641136002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3867874
Associated Lab Samples:92641136002
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 12/14/22 16:28
1,1,1-Trichloroethane ug/L ND 0.50 12/14/22 16:28
1,1,2,2-Tetrachloroethane ug/L ND 0.50 12/14/22 16:28
1,1,2-Trichloroethane ug/L ND 0.50 12/14/22 16:28
1,1-Dichloroethane ug/L ND 0.50 12/14/22 16:28
1,1-Dichloroethene ug/L ND 0.50 12/14/22 16:28
1,1-Dichloropropene ug/L ND 0.50 12/14/22 16:28
1,2,3-Trichlorobenzene ug/L ND 2.0 12/14/22 16:28
1,2,3-Trichloropropane ug/L ND 0.50 12/14/22 16:28
1,2,4-Trichlorobenzene ug/L ND 2.0 12/14/22 16:28
1,2,4-Trimethylbenzene ug/L ND 0.50 12/14/22 16:28
1,2-Dibromo-3-chloropropane ug/L ND 1.0 12/14/22 16:28
1,2-Dibromoethane (EDB)ug/L ND 0.50 12/14/22 16:28
1,2-Dichlorobenzene ug/L ND 0.50 12/14/22 16:28
1,2-Dichloroethane ug/L ND 0.50 12/14/22 16:28
1,2-Dichloropropane ug/L ND 0.50 12/14/22 16:28
1,3,5-Trimethylbenzene ug/L ND 0.50 12/14/22 16:28
1,3-Dichlorobenzene ug/L ND 0.50 12/14/22 16:28
1,3-Dichloropropane ug/L ND 0.50 12/14/22 16:28
1,4-Dichlorobenzene ug/L ND 0.50 12/14/22 16:28
2,2-Dichloropropane ug/L ND 0.50 12/14/22 16:28
2-Chlorotoluene ug/L ND 0.50 12/14/22 16:28
4-Chlorotoluene ug/L ND 0.50 12/14/22 16:28
Benzene ug/L ND 0.50 12/14/22 16:28
Bromobenzene ug/L ND 0.50 12/14/22 16:28
Bromochloromethane ug/L ND 0.50 12/14/22 16:28
Bromodichloromethane ug/L ND 0.50 12/14/22 16:28
Bromoform ug/L ND 0.50 12/14/22 16:28
Bromomethane ug/L ND 5.0 12/14/22 16:28
Carbon tetrachloride ug/L ND 0.50 12/14/22 16:28
Chlorobenzene ug/L ND 0.50 12/14/22 16:28
Chloroethane ug/L ND 1.0 12/14/22 16:28
Chloroform ug/L ND 0.50 12/14/22 16:28
Chloromethane ug/L ND 1.0 12/14/22 16:28
cis-1,2-Dichloroethene ug/L ND 0.50 12/14/22 16:28
cis-1,3-Dichloropropene ug/L ND 0.50 12/14/22 16:28
Dibromochloromethane ug/L ND 0.50 12/14/22 16:28
Dibromomethane ug/L ND 0.50 12/14/22 16:28
Dichlorodifluoromethane ug/L ND 0.50 12/14/22 16:28
Diisopropyl ether ug/L ND 0.50 12/14/22 16:28
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 11 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3867874
Associated Lab Samples:92641136002
Matrix:Water
Analyzed
Ethylbenzene ug/L ND 0.50 12/14/22 16:28
Hexachloro-1,3-butadiene ug/L ND 2.0 12/14/22 16:28
Isopropylbenzene (Cumene)ug/L ND 0.50 12/14/22 16:28
m&p-Xylene ug/L ND 1.0 12/14/22 16:28
Methyl-tert-butyl ether ug/L ND 0.50 12/14/22 16:28
Methylene Chloride ug/L ND 2.0 12/14/22 16:28
n-Butylbenzene ug/L ND 0.50 12/14/22 16:28
n-Propylbenzene ug/L ND 0.50 12/14/22 16:28
Naphthalene ug/L ND 2.0 12/14/22 16:28
o-Xylene ug/L ND 0.50 12/14/22 16:28
sec-Butylbenzene ug/L ND 0.50 12/14/22 16:28
Styrene ug/L ND 0.50 12/14/22 16:28
tert-Butylbenzene ug/L ND 0.50 12/14/22 16:28
Tetrachloroethene ug/L ND 0.50 12/14/22 16:28
Toluene ug/L ND 0.50 12/14/22 16:28
trans-1,2-Dichloroethene ug/L ND 0.50 12/14/22 16:28
trans-1,3-Dichloropropene ug/L ND 0.50 12/14/22 16:28
Trichloroethene ug/L ND 0.50 12/14/22 16:28
Trichlorofluoromethane ug/L ND 1.0 12/14/22 16:28
Vinyl chloride ug/L ND 1.0 12/14/22 16:28
1,2-Dichloroethane-d4 (S)%96 70-130 12/14/22 16:28
4-Bromofluorobenzene (S)%98 70-130 12/14/22 16:28
Toluene-d8 (S)%103 70-130 12/14/22 16:28
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3867875LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 57.250 114 60-140
1,1,1-Trichloroethane ug/L 53.450 107 60-140
1,1,2,2-Tetrachloroethane ug/L 52.750 105 60-140
1,1,2-Trichloroethane ug/L 52.350 105 60-140
1,1-Dichloroethane ug/L 46.650 93 60-140
1,1-Dichloroethene ug/L 50.650 101 60-140
1,1-Dichloropropene ug/L 57.250 114 60-140
1,2,3-Trichlorobenzene ug/L 58.350 117 60-140
1,2,3-Trichloropropane ug/L 48.650 97 60-140
1,2,4-Trichlorobenzene ug/L 54.250 108 60-140
1,2,4-Trimethylbenzene ug/L 52.950 106 60-140
1,2-Dibromo-3-chloropropane ug/L 57.350 115 60-140
1,2-Dibromoethane (EDB)ug/L 56.650 113 60-140
1,2-Dichlorobenzene ug/L 54.950 110 60-140
1,2-Dichloroethane ug/L 49.750 99 60-140
1,2-Dichloropropane ug/L 54.350 109 60-140
1,3,5-Trimethylbenzene ug/L 54.250 108 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 12 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3867875LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 54.950 110 60-140
1,3-Dichloropropane ug/L 54.850 110 60-140
1,4-Dichlorobenzene ug/L 50.250 100 60-140
2,2-Dichloropropane ug/L 51.350 103 60-140
2-Chlorotoluene ug/L 57.350 115 60-140
4-Chlorotoluene ug/L 54.050 108 60-140
Benzene ug/L 49.450 99 60-140
Bromobenzene ug/L 54.950 110 60-140
Bromochloromethane ug/L 49.450 99 60-140
Bromodichloromethane ug/L 52.150 104 60-140
Bromoform ug/L 57.850 116 60-140
Bromomethane ug/L 44.350 89 60-140
Carbon tetrachloride ug/L 53.650 107 60-140
Chlorobenzene ug/L 53.150 106 60-140
Chloroethane ug/L 41.250 82 60-140
Chloroform ug/L 45.050 90 60-140
Chloromethane ug/L 45.550 91 60-140
cis-1,2-Dichloroethene ug/L 49.350 99 60-140
cis-1,3-Dichloropropene ug/L 55.550 111 60-140
Dibromochloromethane ug/L 50.150 100 60-140
Dibromomethane ug/L 55.150 110 60-140
Dichlorodifluoromethane ug/L 39.350 79 60-140
Diisopropyl ether ug/L 52.850 106 60-140
Ethylbenzene ug/L 51.550 103 60-140
Hexachloro-1,3-butadiene ug/L 54.450 109 60-140
Isopropylbenzene (Cumene)ug/L 51.350 103 60-140
m&p-Xylene ug/L 103100 103 60-140
Methyl-tert-butyl ether ug/L 47.550 95 60-140
Methylene Chloride ug/L 42.450 85 60-140
n-Butylbenzene ug/L 54.550 109 60-140
n-Propylbenzene ug/L 53.750 107 60-140
Naphthalene ug/L 60.950 122 60-140
o-Xylene ug/L 52.350 105 60-140
sec-Butylbenzene ug/L 52.450 105 60-140
Styrene ug/L 53.050 106 60-140
tert-Butylbenzene ug/L 44.650 89 60-140
Tetrachloroethene ug/L 54.150 108 60-140
Toluene ug/L 49.250 98 60-140
trans-1,2-Dichloroethene ug/L 50.050 100 60-140
trans-1,3-Dichloropropene ug/L 52.550 105 60-140
Trichloroethene ug/L 57.550 115 60-140
Trichlorofluoromethane ug/L 40.850 82 60-140
Vinyl chloride ug/L 44.950 90 60-140
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%97 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 13 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3867876MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92641049001
3867877
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 4000 124 60-140131 64000ND49605250
1,1,1-Trichloroethane ug/L 4000 117 60-140131 124000ND46805250
1,1,2,2-Tetrachloroethane ug/L 4000 111 60-140113 24000ND44304520
1,1,2-Trichloroethane ug/L 4000 110 60-140119 74000ND44104750
1,1-Dichloroethane ug/L 4000 105 60-140112 74000ND41804500
1,1-Dichloroethene ug/L 4000 115 60-140125 94000ND46005020
1,1-Dichloropropene ug/L 4000 124 60-140132 64000ND49605290
1,2,3-Trichlorobenzene ug/L 4000 107 60-140124 154000ND42904970
1,2,3-Trichloropropane ug/L 4000 108 60-140111 34000ND43204440
1,2,4-Trichlorobenzene ug/L 4000 109 60-140120 94000ND43704780
1,2,4-Trimethylbenzene ug/L 4000 113 60-140121 54000243069507280
1,2-Dibromo-3-chloropropane ug/L 4000 114 60-140117 34000ND45704700
1,2-Dibromoethane (EDB)ug/L 4000 120 60-140126 4400029951105330
1,2-Dichlorobenzene ug/L 4000 114 60-140122 74000ND45404880
1,2-Dichloroethane ug/L 4000 110 60-140117 6400020145904880
1,2-Dichloropropane ug/L 4000 119 60-140125 54000ND47405010
1,3,5-Trimethylbenzene ug/L 4000 114 60-140121 5400072953105580
1,3-Dichlorobenzene ug/L 4000 117 60-140123 54000ND46904910
1,3-Dichloropropane ug/L 4000 113 60-140120 64000ND45404810
1,4-Dichlorobenzene ug/L 4000 109 60-140118 84000ND43704710
2,2-Dichloropropane ug/L 4000 114 60-140126 104000ND45405020
2-Chlorotoluene ug/L 4000 108 60-140121 124000ND43104830
4-Chlorotoluene ug/L 4000 115 60-140121 64000ND45804850
Benzene ug/L 4000 109 60-140119 3400075001190012300
Bromobenzene ug/L 4000 115 60-140123 74000ND46104930
Bromochloromethane ug/L 4000 114 60-140125 94000ND45804990
Bromodichloromethane ug/L 4000 109 60-140117 74000ND43604680
Bromoform ug/L 4000 118 60-140121 24000ND47404850
Bromomethane ug/L 4000 68 60-14083 194000ND27303320
Carbon tetrachloride ug/L 4000 117 60-140127 84000ND46905070
Chlorobenzene ug/L 4000 115 60-140125 84000ND46005000
Chloroethane ug/L 4000 100 60-140113 124000ND39904520
Chloroform ug/L 4000 101 60-140109 74000ND41004410
Chloromethane ug/L 4000 89 60-14099 114000ND35803980
cis-1,2-Dichloroethene ug/L 4000 109 60-140119 94000ND43704760
cis-1,3-Dichloropropene ug/L 4000 113 60-140125 104000ND45204990
Dibromochloromethane ug/L 4000 105 60-140112 74000ND42004480
Dibromomethane ug/L 4000 116 60-140124 64000ND46604960
Dichlorodifluoromethane ug/L 4000 75 60-14083 104000ND30103340
Diisopropyl ether ug/L 4000 104 60-140113 8400013443104660
Ethylbenzene ug/L 4000 113 60-140120 44000206065906870
Hexachloro-1,3-butadiene ug/L 4000 116 60-140129 114000ND46405170
Isopropylbenzene (Cumene)ug/L 4000 113 60-140121 7400011346404970
m&p-Xylene ug/L 8000 113 60-140125 5800093701840019300
Methyl-tert-butyl ether ug/L 4000 98 60-140103 4400075646704870
Methylene Chloride ug/L 4000 96 60-140106 94000ND38404220
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 14 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3867876MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92641049001
3867877
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Butylbenzene ug/L 4000 118 60-140124 54000ND47004950
n-Propylbenzene ug/L 4000 113 60-140122 7400022847605090
Naphthalene ug/L 4000 114 60-140124 7400081653805760
o-Xylene ug/L 4000 115 60-140126 54000433089509370
sec-Butylbenzene ug/L 4000 112 60-140121 84000ND44704830
Styrene ug/L 4000 115 60-140122 6400010846904980
tert-Butylbenzene ug/L 4000 97 60-140104 74000ND38704150
Tetrachloroethene ug/L 4000 118 60-140126 74000ND47105040
Toluene ug/L 4000 70 60-14099 44000251002790029100
trans-1,2-Dichloroethene ug/L 4000 109 60-140122 114000ND43704900
trans-1,3-Dichloropropene ug/L 4000 111 60-140118 64000ND44304720
Trichloroethene ug/L 4000 122 60-140130 74000ND48605210
Trichlorofluoromethane ug/L 4000 92 60-140102 104000ND36804060
Vinyl chloride ug/L 4000 98 60-140108 104000ND39304330
1,2-Dichloroethane-d4 (S)%97 70-13097
4-Bromofluorobenzene (S)%102 70-130101
Toluene-d8 (S)%100 70-13098
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 15 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
742789
EPA 5035A/5030B
EPA 8260D
8260D 5035A 5030B
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92641136001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3864465
Associated Lab Samples:92641136001
Matrix:Solid
Analyzed
1,1,1,2-Tetrachloroethane mg/kg ND 0.0050 12/12/22 16:48
1,1,1-Trichloroethane mg/kg ND 0.0050 12/12/22 16:48
1,1,2,2-Tetrachloroethane mg/kg ND 0.0050 12/12/22 16:48
1,1,2-Trichloroethane mg/kg ND 0.0050 12/12/22 16:48
1,1-Dichloroethane mg/kg ND 0.0050 12/12/22 16:48
1,1-Dichloroethene mg/kg ND 0.0050 12/12/22 16:48
1,1-Dichloropropene mg/kg ND 0.0050 12/12/22 16:48
1,2,3-Trichlorobenzene mg/kg ND 0.0050 12/12/22 16:48
1,2,3-Trichloropropane mg/kg ND 0.0050 12/12/22 16:48
1,2,4-Trichlorobenzene mg/kg ND 0.0050 12/12/22 16:48
1,2,4-Trimethylbenzene mg/kg ND 0.0050 12/12/22 16:48
1,2-Dibromo-3-chloropropane mg/kg ND 0.0050 12/12/22 16:48
1,2-Dibromoethane (EDB)mg/kg ND 0.0050 12/12/22 16:48
1,2-Dichlorobenzene mg/kg ND 0.0050 12/12/22 16:48
1,2-Dichloroethane mg/kg ND 0.0050 12/12/22 16:48
1,2-Dichloropropane mg/kg ND 0.0050 12/12/22 16:48
1,3,5-Trimethylbenzene mg/kg ND 0.0050 12/12/22 16:48
1,3-Dichlorobenzene mg/kg ND 0.0050 12/12/22 16:48
1,3-Dichloropropane mg/kg ND 0.0050 12/12/22 16:48
1,4-Dichlorobenzene mg/kg ND 0.0050 12/12/22 16:48
2,2-Dichloropropane mg/kg ND 0.0050 12/12/22 16:48
2-Butanone (MEK)mg/kg ND 0.10 12/12/22 16:48
2-Chlorotoluene mg/kg ND 0.0050 12/12/22 16:48
2-Hexanone mg/kg ND 0.050 12/12/22 16:48
4-Chlorotoluene mg/kg ND 0.0050 12/12/22 16:48
4-Methyl-2-pentanone (MIBK)mg/kg ND 0.050 12/12/22 16:48
Acetone mg/kg ND 0.10 12/12/22 16:48
Benzene mg/kg ND 0.0050 12/12/22 16:48
Bromobenzene mg/kg ND 0.0050 12/12/22 16:48
Bromochloromethane mg/kg ND 0.0050 12/12/22 16:48
Bromodichloromethane mg/kg ND 0.0050 12/12/22 16:48
Bromoform mg/kg ND 0.0050 12/12/22 16:48
Bromomethane mg/kg ND 0.010 v112/12/22 16:48
Carbon tetrachloride mg/kg ND 0.0050 12/12/22 16:48
Chlorobenzene mg/kg ND 0.0050 12/12/22 16:48
Chloroethane mg/kg ND 0.010 12/12/22 16:48
Chloroform mg/kg ND 0.0050 12/12/22 16:48
Chloromethane mg/kg ND 0.010 12/12/22 16:48
cis-1,2-Dichloroethene mg/kg ND 0.0050 12/12/22 16:48
cis-1,3-Dichloropropene mg/kg ND 0.0050 12/12/22 16:48
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 16 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3864465
Associated Lab Samples:92641136001
Matrix:Solid
Analyzed
Dibromochloromethane mg/kg ND 0.0050 12/12/22 16:48
Dibromomethane mg/kg ND 0.0050 12/12/22 16:48
Dichlorodifluoromethane mg/kg ND 0.010 12/12/22 16:48
Diisopropyl ether mg/kg ND 0.0050 12/12/22 16:48
Ethylbenzene mg/kg ND 0.0050 12/12/22 16:48
Hexachloro-1,3-butadiene mg/kg ND 0.010 12/12/22 16:48
Isopropylbenzene (Cumene)mg/kg ND 0.0050 12/12/22 16:48
m&p-Xylene mg/kg ND 0.010 12/12/22 16:48
Methyl-tert-butyl ether mg/kg ND 0.0050 12/12/22 16:48
Methylene Chloride mg/kg ND 0.020 12/12/22 16:48
n-Butylbenzene mg/kg ND 0.0050 12/12/22 16:48
n-Propylbenzene mg/kg ND 0.0050 12/12/22 16:48
Naphthalene mg/kg ND 0.0050 12/12/22 16:48
o-Xylene mg/kg ND 0.0050 12/12/22 16:48
p-Isopropyltoluene mg/kg ND 0.0050 12/12/22 16:48
sec-Butylbenzene mg/kg ND 0.0050 12/12/22 16:48
Styrene mg/kg ND 0.0050 12/12/22 16:48
tert-Butylbenzene mg/kg ND 0.0050 12/12/22 16:48
Tetrachloroethene mg/kg ND 0.0050 12/12/22 16:48
Toluene mg/kg ND 0.0050 12/12/22 16:48
trans-1,2-Dichloroethene mg/kg ND 0.0050 12/12/22 16:48
trans-1,3-Dichloropropene mg/kg ND 0.0050 12/12/22 16:48
Trichloroethene mg/kg ND 0.0050 12/12/22 16:48
Trichlorofluoromethane mg/kg ND 0.0050 12/12/22 16:48
Vinyl acetate mg/kg ND 0.050 12/12/22 16:48
Vinyl chloride mg/kg ND 0.010 12/12/22 16:48
Xylene (Total)mg/kg ND 0.010 12/12/22 16:48
1,2-Dichloroethane-d4 (S)%114 70-130 12/12/22 16:48
4-Bromofluorobenzene (S)%96 70-130 12/12/22 16:48
Toluene-d8 (S)%102 70-130 12/12/22 16:48
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3864466LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane mg/kg 1.11.2 92 70-130
1,1,1-Trichloroethane mg/kg 1.21.2 95 70-130
1,1,2,2-Tetrachloroethane mg/kg 1.21.2 95 70-130
1,1,2-Trichloroethane mg/kg 1.11.2 90 70-130
1,1-Dichloroethane mg/kg 1.11.2 91 70-130
1,1-Dichloroethene mg/kg 1.21.2 100 70-130
1,1-Dichloropropene mg/kg 1.31.2 102 70-130
1,2,3-Trichlorobenzene mg/kg 1.41.2 109 70-130
1,2,3-Trichloropropane mg/kg 1.31.2 103 70-130
1,2,4-Trichlorobenzene mg/kg 1.21.2 97 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 17 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3864466LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trimethylbenzene mg/kg 1.21.2 97 70-130
1,2-Dibromo-3-chloropropane mg/kg 1.31.2 101 67-130
1,2-Dibromoethane (EDB)mg/kg 1.21.2 92 70-130
1,2-Dichlorobenzene mg/kg 1.21.2 93 70-130
1,2-Dichloroethane mg/kg 1.21.2 93 70-130
1,2-Dichloropropane mg/kg 1.21.2 92 70-130
1,3,5-Trimethylbenzene mg/kg 1.21.2 98 70-130
1,3-Dichlorobenzene mg/kg 1.21.2 96 70-130
1,3-Dichloropropane mg/kg 1.21.2 92 70-130
1,4-Dichlorobenzene mg/kg 1.11.2 92 70-130
2,2-Dichloropropane mg/kg 1.21.2 93 67-130
2-Butanone (MEK)mg/kg 2.52.5 100 66-130
2-Chlorotoluene mg/kg 1.21.2 96 70-130
2-Hexanone mg/kg 2.72.5 109 70-130
4-Chlorotoluene mg/kg 1.21.2 94 70-130
4-Methyl-2-pentanone (MIBK)mg/kg 2.52.5 101 70-130
Acetone mg/kg 2.32.5 93 67-130
Benzene mg/kg 1.11.2 85 70-130
Bromobenzene mg/kg 1.11.2 92 70-130
Bromochloromethane mg/kg 1.11.2 86 70-130
Bromodichloromethane mg/kg 1.11.2 91 70-130
Bromoform mg/kg 1.21.2 94 70-130
Bromomethane mg/kg 1.5 v11.2 123 53-175
Carbon tetrachloride mg/kg 1.21.2 93 70-130
Chlorobenzene mg/kg 1.21.2 94 70-130
Chloroethane mg/kg 1.31.2 106 70-135
Chloroform mg/kg 1.11.2 92 70-130
Chloromethane mg/kg 1.21.2 100 64-130
cis-1,2-Dichloroethene mg/kg 1.11.2 92 70-130
cis-1,3-Dichloropropene mg/kg 1.21.2 94 70-130
Dibromochloromethane mg/kg 1.21.2 94 70-130
Dibromomethane mg/kg 1.01.2 84 70-130
Dichlorodifluoromethane mg/kg 1.31.2 102 63-145
Diisopropyl ether mg/kg 1.21.2 95 68-130
Ethylbenzene mg/kg 1.11.2 89 70-130
Hexachloro-1,3-butadiene mg/kg 1.21.2 97 70-130
Isopropylbenzene (Cumene)mg/kg 1.21.2 98 70-130
m&p-Xylene mg/kg 2.42.5 97 70-130
Methyl-tert-butyl ether mg/kg 1.11.2 91 70-130
Methylene Chloride mg/kg 1.11.2 90 67-130
n-Butylbenzene mg/kg 1.31.2 100 70-130
n-Propylbenzene mg/kg 1.21.2 96 70-130
Naphthalene mg/kg 1.31.2 103 70-130
o-Xylene mg/kg 1.21.2 97 70-130
p-Isopropyltoluene mg/kg 1.31.2 102 70-130
sec-Butylbenzene mg/kg 1.21.2 100 70-130
Styrene mg/kg 1.31.2 101 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 18 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3864466LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butylbenzene mg/kg 1.21.2 96 64-130
Tetrachloroethene mg/kg 1.21.2 93 70-130
Toluene mg/kg 1.11.2 88 70-130
trans-1,2-Dichloroethene mg/kg 1.21.2 95 70-130
trans-1,3-Dichloropropene mg/kg 1.11.2 92 70-130
Trichloroethene mg/kg 1.21.2 92 70-130
Trichlorofluoromethane mg/kg 1.21.2 93 70-130
Vinyl acetate mg/kg 2.82.5 110 70-134
Vinyl chloride mg/kg 1.31.2 107 68-130
Xylene (Total)mg/kg 3.63.8 97 70-130
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3864467MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92640739003
3864468
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane mg/kg 0.58 99 58-14094 50.58ND 0.58 0.55
1,1,1-Trichloroethane mg/kg 0.58 99 58-14497 30.58ND 0.58 0.56
1,1,2,2-Tetrachloroethane mg/kg 0.58 102 52-139100 20.58ND 0.60 0.58
1,1,2-Trichloroethane mg/kg 0.58 100 56-14098 30.58ND 0.59 0.57
1,1-Dichloroethane mg/kg 0.58 94 58-14591 30.58ND 0.55 0.53
1,1-Dichloroethene mg/kg 0.58 96 57-15885 120.58ND 0.56 0.50
1,1-Dichloropropene mg/kg 0.58 103 58-15192 110.58ND 0.60 0.54
1,2,3-Trichlorobenzene mg/kg M10.58 33 48-14927 210.58ND 0.19 0.15
1,2,3-Trichloropropane mg/kg 0.58 110 54-132104 60.58ND 0.64 0.60
1,2,4-Trichlorobenzene mg/kg 0.58 63 51-15152 200.58ND 0.37 0.30
1,2,4-Trimethylbenzene mg/kg 0.58 91 38-17078 150.58ND 0.53 0.46
1,2-Dibromo-3-chloropropane mg/kg 0.58 81 44-13476 60.58ND 0.47 0.45
1,2-Dibromoethane (EDB)mg/kg 0.58 96 60-13897 00.58ND 0.56 0.57
1,2-Dichlorobenzene mg/kg 0.58 94 59-14786 90.58ND 0.55 0.50
1,2-Dichloroethane mg/kg 0.58 98 57-139104 70.58ND 0.57 0.61
1,2-Dichloropropane mg/kg 0.58 101 62-145100 10.58ND 0.59 0.58
1,3,5-Trimethylbenzene mg/kg 0.58 94 47-15981 150.58ND 0.55 0.47
1,3-Dichlorobenzene mg/kg 0.58 94 58-14481 150.58ND 0.55 0.47
1,3-Dichloropropane mg/kg 0.58 99 60-14298 20.58ND 0.58 0.57
1,4-Dichlorobenzene mg/kg 0.58 91 57-14378 150.58ND 0.53 0.46
2,2-Dichloropropane mg/kg 0.58 76 37-14472 50.58ND 0.44 0.42
2-Butanone (MEK)mg/kg 1.2 98 28-14695 41.2ND 1.1 1.1
2-Chlorotoluene mg/kg 0.58 95 55-15884 120.58ND 0.56 0.49
2-Hexanone mg/kg 1.2 104 44-14199 51.2ND 1.2 1.2
4-Chlorotoluene mg/kg 0.58 92 55-14680 130.58ND 0.54 0.47
4-Methyl-2-pentanone (MIBK)mg/kg 1.2 103 50-13899 41.2ND 1.2 1.2
Acetone mg/kg 1.2 88 20-13684 51.2ND 1.0 0.98
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 19 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3864467MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92640739003
3864468
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Benzene mg/kg 0.58 93 60-14588 50.58ND 0.54 0.52
Bromobenzene mg/kg 0.58 93 59-14584 110.58ND 0.55 0.49
Bromochloromethane mg/kg 0.58 91 57-14390 10.58ND 0.53 0.52
Bromodichloromethane mg/kg 0.58 99 53-13398 10.58ND 0.58 0.57
Bromoform mg/kg 0.58 101 48-13397 30.58ND 0.59 0.57
Bromomethane mg/kg 0.58 89 10-16787 20.58ND 0.52 0.51
Carbon tetrachloride mg/kg 0.58 89 57-14779 120.58ND 0.52 0.46
Chlorobenzene mg/kg 0.58 84 61-14472 120.58101
ug/kg 0.59 0.52
Chloroethane mg/kg 0.58 60 10-15362 20.58ND 0.35 0.36
Chloroform mg/kg 0.58 97 58-14198 10.58ND 0.57 0.57
Chloromethane mg/kg 0.58 95 54-16595 10.58ND 0.55 0.56
cis-1,2-Dichloroethene mg/kg 0.58 99 59-14496 30.58ND 0.58 0.56
cis-1,3-Dichloropropene mg/kg 0.58 97 56-13792 50.58ND 0.56 0.54
Dibromochloromethane mg/kg 0.58 100 53-13996 50.58ND 0.58 0.56
Dibromomethane mg/kg 0.58 89 60-13689 00.58ND 0.52 0.52
Dichlorodifluoromethane mg/kg 0.58 69 49-17760 150.58ND 0.40 0.35
Diisopropyl ether mg/kg 0.58 99 53-13698 10.58ND 0.58 0.57
Ethylbenzene mg/kg 0.58 93 53-15082 130.58ND 0.54 0.48
Hexachloro-1,3-butadiene mg/kg 0.58 87 42-18667 270.58ND 0.51 0.39
Isopropylbenzene (Cumene)mg/kg 0.58 102 62-15487 150.58ND 0.59 0.51
m&p-Xylene mg/kg 1.2 99 49-15686 141.2ND 1.2 1.0
Methyl-tert-butyl ether mg/kg 0.58 92 54-13395 30.58ND 0.54 0.55
Methylene Chloride mg/kg 0.58 91 50-15397 60.58ND 0.53 0.57
n-Butylbenzene mg/kg 0.58 93 44-17474 230.58ND 0.54 0.43
n-Propylbenzene mg/kg 0.58 93 52-15779 170.58ND 0.54 0.46
Naphthalene mg/kg M10.58 33 37-15031 70.58ND 0.19 0.18
o-Xylene mg/kg 0.58 102 54-15091 120.58ND 0.60 0.53
p-Isopropyltoluene mg/kg 0.58 98 50-16480 200.58ND 0.57 0.47
sec-Butylbenzene mg/kg 0.58 99 58-16182 190.58ND 0.58 0.48
Styrene mg/kg 0.58 104 60-14895 90.58ND 0.61 0.56
tert-Butylbenzene mg/kg 0.58 92 44-15182 120.58ND 0.54 0.48
Tetrachloroethene mg/kg 0.58 85 53-15167 240.58ND 0.49 0.39
Toluene mg/kg 0.58 93 52-14886 70.58ND 0.54 0.50
trans-1,2-Dichloroethene mg/kg 0.58 91 60-14883 90.58ND 0.53 0.49
trans-1,3-Dichloropropene mg/kg 0.58 94 55-13392 20.58ND 0.55 0.54
Trichloroethene mg/kg 0.58 96 60-14883 150.58ND 0.56 0.48
Trichlorofluoromethane mg/kg 0.58 71 10-15466 70.58ND 0.41 0.39
Vinyl acetate mg/kg 1.2 87 50-14990 31.2ND 1.0 1.0
Vinyl chloride mg/kg 0.58 92 57-15785 80.58ND 0.54 0.49
Xylene (Total)mg/kg 1.7 100 52-15388 131.7ND 1.7 1.5
1,2-Dichloroethane-d4 (S)%108 70-130114
4-Bromofluorobenzene (S)%107 70-130108
Toluene-d8 (S)%100 70-130101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 20 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
743192
EPA 625.1
EPA 625.1
625 MSS
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92641136002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3866628
Associated Lab Samples:92641136002
Matrix:Water
Analyzed
1,2,4-Trichlorobenzene ug/L ND 5.0 12/15/22 11:56
2,2'-Oxybis(1-chloropropane)ug/L ND 5.0 12/15/22 11:56
2,4,6-Trichlorophenol ug/L ND 10.0 12/15/22 11:56
2,4-Dichlorophenol ug/L ND 5.0 12/15/22 11:56
2,4-Dimethylphenol ug/L ND 10.0 12/15/22 11:56
2,4-Dinitrophenol ug/L ND 50.0 12/15/22 11:56
2,4-Dinitrotoluene ug/L ND 5.0 12/15/22 11:56
2,6-Dinitrotoluene ug/L ND 5.0 12/15/22 11:56
2-Chloronaphthalene ug/L ND 5.0 12/15/22 11:56
2-Chlorophenol ug/L ND 5.0 12/15/22 11:56
2-Nitrophenol ug/L ND 5.0 12/15/22 11:56
3,3'-Dichlorobenzidine ug/L ND 10.0 12/15/22 11:56
4,6-Dinitro-2-methylphenol ug/L ND 10.0 12/15/22 11:56
4-Bromophenylphenyl ether ug/L ND 5.0 12/15/22 11:56
4-Chloro-3-methylphenol ug/L ND 5.0 12/15/22 11:56
4-Chlorophenylphenyl ether ug/L ND 5.0 12/15/22 11:56
4-Nitrophenol ug/L ND 10.0 12/15/22 11:56
Acenaphthene ug/L ND 5.0 12/15/22 11:56
Acenaphthylene ug/L ND 5.0 12/15/22 11:56
Anthracene ug/L ND 5.0 12/15/22 11:56
Benzo(a)anthracene ug/L ND 5.0 12/15/22 11:56
Benzo(a)pyrene ug/L ND 5.0 12/15/22 11:56
Benzo(b)fluoranthene ug/L ND 5.0 12/15/22 11:56
Benzo(g,h,i)perylene ug/L ND 5.0 12/15/22 11:56
Benzo(k)fluoranthene ug/L ND 5.0 12/15/22 11:56
bis(2-Chloroethoxy)methane ug/L ND 10.0 12/15/22 11:56
bis(2-Chloroethyl) ether ug/L ND 5.0 12/15/22 11:56
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 12/15/22 11:56
Butylbenzylphthalate ug/L ND 5.0 12/15/22 11:56
Chrysene ug/L ND 5.0 12/15/22 11:56
Di-n-butylphthalate ug/L ND 5.0 12/15/22 11:56
Di-n-octylphthalate ug/L ND 5.0 12/15/22 11:56
Dibenz(a,h)anthracene ug/L ND 5.0 12/15/22 11:56
Diethylphthalate ug/L ND 5.0 12/15/22 11:56
Dimethylphthalate ug/L ND 5.0 12/15/22 11:56
Fluoranthene ug/L ND 5.0 12/15/22 11:56
Fluorene ug/L ND 5.0 12/15/22 11:56
Hexachloro-1,3-butadiene ug/L ND 5.0 12/15/22 11:56
Hexachlorobenzene ug/L ND 5.0 12/15/22 11:56
Hexachlorocyclopentadiene ug/L ND 10.0 12/15/22 11:56
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 21 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3866628
Associated Lab Samples:92641136002
Matrix:Water
Analyzed
Hexachloroethane ug/L ND 5.0 12/15/22 11:56
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 12/15/22 11:56
Isophorone ug/L ND 10.0 12/15/22 11:56
N-Nitroso-di-n-propylamine ug/L ND 5.0 12/15/22 11:56
N-Nitrosodimethylamine ug/L ND 5.0 12/15/22 11:56
N-Nitrosodiphenylamine ug/L ND 10.0 12/15/22 11:56
Naphthalene ug/L ND 5.0 12/15/22 11:56
Nitrobenzene ug/L ND 5.0 12/15/22 11:56
Pentachlorophenol ug/L ND 10.0 12/15/22 11:56
Phenanthrene ug/L ND 5.0 12/15/22 11:56
Phenol ug/L ND 5.0 12/15/22 11:56
Pyrene ug/L ND 5.0 12/15/22 11:56
2,4,6-Tribromophenol (S)%97 10-137 12/15/22 11:56
2-Fluorobiphenyl (S)%94 15-120 12/15/22 11:56
2-Fluorophenol (S)%76 10-120 12/15/22 11:56
Nitrobenzene-d5 (S)%107 10-120 12/15/22 11:56
Phenol-d6 (S)%62 10-120 12/15/22 11:56
Terphenyl-d14 (S)%112 11-131 12/15/22 11:56
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3866629LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 39.250 78 44-142
2,2'-Oxybis(1-chloropropane)ug/L 46.550 93 36-166
2,4,6-Trichlorophenol ug/L 50.550 101 37-144
2,4-Dichlorophenol ug/L 50.750 101 1-191
2,4-Dimethylphenol ug/L 60.2 L15012032-119
2,4-Dinitrophenol ug/L 293250 117 1-181
2,4-Dinitrotoluene ug/L 59.650 119 39-139
2,6-Dinitrotoluene ug/L 60.450 121 50-158
2-Chloronaphthalene ug/L 50.050 100 60-118
2-Chlorophenol ug/L 45.050 90 23-134
2-Nitrophenol ug/L 54.250 108 29-182
3,3'-Dichlorobenzidine ug/L 101100 101 1-262
4,6-Dinitro-2-methylphenol ug/L 117100 117 1-181
4-Bromophenylphenyl ether ug/L 47.150 94 53-127
4-Chloro-3-methylphenol ug/L 105100 105 22-147
4-Chlorophenylphenyl ether ug/L 46.950 94 25-158
4-Nitrophenol ug/L 170250 68 1-132
Acenaphthene ug/L 49.850 100 47-145
Acenaphthylene ug/L 50.850 102 33-145
Anthracene ug/L 47.050 94 1-166
Benzo(a)anthracene ug/L 54.550 109 33-143
Benzo(a)pyrene ug/L 52.150 104 17-163
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 22 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3866629LABORATORY CONTROL SAMPLE:
LCSSpike
Benzo(b)fluoranthene ug/L 50.450 101 24-159
Benzo(g,h,i)perylene ug/L 58.850 118 1-219
Benzo(k)fluoranthene ug/L 51.750 103 11-162
bis(2-Chloroethoxy)methane ug/L 51.350 103 33-184
bis(2-Chloroethyl) ether ug/L 49.050 98 12-158
bis(2-Ethylhexyl)phthalate ug/L 62.550 125 8-158
Butylbenzylphthalate ug/L 62.450 125 1-152
Chrysene ug/L 54.050 108 17-168
Di-n-butylphthalate ug/L 56.250 112 1-118
Di-n-octylphthalate ug/L 69.850 140 4-146
Dibenz(a,h)anthracene ug/L 58.450 117 1-227
Diethylphthalate ug/L 53.550 107 1-114
Dimethylphthalate ug/L 51.550 103 1-112
Fluoranthene ug/L 52.750 105 26-137
Fluorene ug/L 50.350 101 59-121
Hexachloro-1,3-butadiene ug/L 34.850 70 24-116
Hexachlorobenzene ug/L 46.250 92 1-152
Hexachlorocyclopentadiene ug/L 39.750 79 25-150
Hexachloroethane ug/L 29.550 59 40-113
Indeno(1,2,3-cd)pyrene ug/L 60.850 122 1-171
Isophorone ug/L 52.350 105 21-196
N-Nitroso-di-n-propylamine ug/L 53.050 106 1-230
N-Nitrosodimethylamine ug/L 45.850 92 25-150
N-Nitrosodiphenylamine ug/L 49.950 100 25-150
Naphthalene ug/L 42.450 85 21-133
Nitrobenzene ug/L 52.850 106 35-180
Pentachlorophenol ug/L 109100 109 14-176
Phenanthrene ug/L 50.550 101 54-120
Phenol ug/L 33.850 68 5-112
Pyrene ug/L 53.050 106 52-115
2,4,6-Tribromophenol (S)%107 10-137
2-Fluorobiphenyl (S)%97 15-120
2-Fluorophenol (S)%78 10-120
Nitrobenzene-d5 (S)%111 10-120
Phenol-d6 (S)%67 10-120
Terphenyl-d14 (S)%112 11-131
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3866630MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35765150001
3866631
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/L 50 57 44-14261 7501.7U 28.7 30.7
2,2'-Oxybis(1-chloropropane)ug/L 50 70 36-16672 3501.2U 35.1 36.1
2,4,6-Trichlorophenol ug/L 50 85 37-14488 3501.6U 42.7 44.0
2,4-Dichlorophenol ug/L 50 82 1-19187 6501.4U 40.8 43.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 23 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3866630MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35765150001
3866631
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
2,4-Dimethylphenol ug/L 50 99 32-119103 4501.7U 49.3 51.4
2,4-Dinitrophenol ug/L 250 97 1-181105 825026.0U 243 263
2,4-Dinitrotoluene ug/L 50 98 39-139104 7501.6U 48.9 52.2
2,6-Dinitrotoluene ug/L 50 102 50-158105 3501.7U 50.9 52.4
2-Chloronaphthalene ug/L 50 81 60-11886 6501.7U 40.5 43.1
2-Chlorophenol ug/L 50 74 23-13475 2501.2U 36.8 37.4
2-Nitrophenol ug/L 50 88 29-18292 5501.4U 44.1 46.2
3,3'-Dichlorobenzidine ug/L 100 81 1-26284 41008.1U 80.7 84.3
4,6-Dinitro-2-methylphenol ug/L 100 99 1-181100 11007.8U 98.7 99.8
4-Bromophenylphenyl ether ug/L 50 80 53-12780 1501.8U 39.8 40.0
4-Chloro-3-methylphenol ug/L 100 87 22-14790 31003.3U 87.1 89.6
4-Chlorophenylphenyl ether ug/L 50 77 25-15881 5502.0U 38.7 40.7
4-Nitrophenol ug/L 250 54 1-13259 92506.6U 134 147
Acenaphthene ug/L 50 83 47-14585 3502.0U 41.5 42.6
Acenaphthylene ug/L 50 83 33-14586 4502.0U 41.3 42.9
Anthracene ug/L 50 78 1-16680 2502.3U 38.9 39.8
Benzo(a)anthracene ug/L 50 84 33-14388 5502.7U 42.0 44.0
Benzo(a)pyrene ug/L 50 81 17-16386 6502.8U 40.5 42.9
Benzo(b)fluoranthene ug/L 50 78 24-15984 7502.6U 39.2 41.9
Benzo(g,h,i)perylene ug/L 50 94 1-21996 1502.8U 47.2 47.8
Benzo(k)fluoranthene ug/L 50 78 11-16285 8502.7U 39.2 42.4
bis(2-Chloroethoxy)methane ug/L 50 84 33-18485 2501.8U 41.8 42.7
bis(2-Chloroethyl) ether ug/L 50 73 12-15875 4501.9U 36.3 37.7
bis(2-Ethylhexyl)phthalate ug/L 50 98 8-158102 4503.7U 48.9 51.0
Butylbenzylphthalate ug/L 50 98 1-152104 7503.1U 48.8 52.2
Chrysene ug/L 50 83 17-16888 6502.8U 41.5 44.2
Di-n-butylphthalate ug/L 50 89 1-11895 6502.2U 44.6 47.3
Di-n-octylphthalate ug/L 50 110 4-146114 3503.9U 55.0 56.9
Dibenz(a,h)anthracene ug/L 50 91 1-22794 3503.0U 45.6 47.1
Diethylphthalate ug/L 50 89 1-11493 4502.0U 44.7 46.3
Dimethylphthalate ug/L 50 86 1-11289 3502.1U 43.2 44.6
Fluoranthene ug/L 50 85 26-13788 4502.2U 42.5 44.1
Fluorene ug/L 50 85 59-12187 2502.1U 42.6 43.7
Hexachloro-1,3-butadiene ug/L 50 45 24-11648 6501.8U 22.7 24.1
Hexachlorobenzene ug/L 50 79 1-15279 1502.2U 39.4 39.7
Hexachlorocyclopentadiene ug/L 50 60 25-15066 9501.6U 30.2 33.2
Hexachloroethane ug/L M1502640-11333 25501.4U 13.0 16.6
Indeno(1,2,3-cd)pyrene ug/L 50 94 1-17198 4502.9U 47.2 49.2
Isophorone ug/L 50 86 21-19689 4501.7U 43.0 44.6
N-Nitroso-di-n-propylamine ug/L 50 86 1-23090 4501.3U 43.2 45.0
N-Nitrosodimethylamine ug/L 50 70 25-15069 1501.9U 35.0 34.5
N-Nitrosodiphenylamine ug/L 50 82 25-15085 4503.0U 40.8 42.5
Naphthalene ug/L 50 65 21-13367 3502.1U 32.4 33.4
Nitrobenzene ug/L 50 82 35-18083 1501.9U 41.0 41.5
Pentachlorophenol ug/L 100 86 14-17691 61003.8U 85.7 91.1
Phenanthrene ug/L 50 83 54-12084 1502.0U 41.7 42.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 24 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3866630MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35765150001
3866631
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Phenol ug/L 50 53 5-11256 5501.4U 26.6 27.9
Pyrene ug/L 50 84 52-11586 2502.2U 41.8 42.8
2,4,6-Tribromophenol (S)%89 10-13787
2-Fluorobiphenyl (S)%82 15-12084
2-Fluorophenol (S)%63 10-12064
Nitrobenzene-d5 (S)%89 10-12087
Phenol-d6 (S)%53 10-12054
Terphenyl-d14 (S)%81 11-13186
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 25 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
743903
EPA 3546
EPA 8270E
8270E Solid MSSV Microwave
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92641136001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3870261
Associated Lab Samples:92641136001
Matrix:Solid
Analyzed
1,2,4-Trichlorobenzene mg/kg ND 0.33 12/18/22 08:46
1,2-Dichlorobenzene mg/kg ND 0.33 12/18/22 08:46
1,3-Dichlorobenzene mg/kg ND 0.33 12/18/22 08:46
1,4-Dichlorobenzene mg/kg ND 0.33 12/18/22 08:46
1-Methylnaphthalene mg/kg ND 0.33 12/18/22 08:46
2,4,5-Trichlorophenol mg/kg ND 0.33 12/18/22 08:46
2,4,6-Trichlorophenol mg/kg ND 0.33 12/18/22 08:46
2,4-Dichlorophenol mg/kg ND 0.33 12/18/22 08:46
2,4-Dimethylphenol mg/kg ND 0.33 12/18/22 08:46
2,4-Dinitrophenol mg/kg ND 1.6 12/18/22 08:46
2,4-Dinitrotoluene mg/kg ND 0.33 12/18/22 08:46
2,6-Dinitrotoluene mg/kg ND 0.33 12/18/22 08:46
2-Chloronaphthalene mg/kg ND 0.33 12/18/22 08:46
2-Chlorophenol mg/kg ND 0.33 12/18/22 08:46
2-Methylnaphthalene mg/kg ND 0.33 12/18/22 08:46
2-Methylphenol(o-Cresol)mg/kg ND 0.33 12/18/22 08:46
2-Nitroaniline mg/kg ND 1.6 12/18/22 08:46
2-Nitrophenol mg/kg ND 0.33 12/18/22 08:46
3&4-Methylphenol(m&p Cresol)mg/kg ND 0.33 12/18/22 08:46
3,3'-Dichlorobenzidine mg/kg ND 0.66 12/18/22 08:46
3-Nitroaniline mg/kg ND 1.6 12/18/22 08:46
4,6-Dinitro-2-methylphenol mg/kg ND 0.66 12/18/22 08:46
4-Bromophenylphenyl ether mg/kg ND 0.33 12/18/22 08:46
4-Chloro-3-methylphenol mg/kg ND 0.66 12/18/22 08:46
4-Chloroaniline mg/kg ND 0.66 12/18/22 08:46
4-Chlorophenylphenyl ether mg/kg ND 0.33 12/18/22 08:46
4-Nitroaniline mg/kg ND 0.66 12/18/22 08:46
4-Nitrophenol mg/kg ND 1.6 12/18/22 08:46
Acenaphthene mg/kg ND 0.33 12/18/22 08:46
Acenaphthylene mg/kg ND 0.33 12/18/22 08:46
Anthracene mg/kg ND 0.33 12/18/22 08:46
Benzo(a)anthracene mg/kg ND 0.33 12/18/22 08:46
Benzo(a)pyrene mg/kg ND 0.33 12/18/22 08:46
Benzo(b)fluoranthene mg/kg ND 0.33 12/18/22 08:46
Benzo(g,h,i)perylene mg/kg ND 0.33 12/18/22 08:46
Benzo(k)fluoranthene mg/kg ND 0.33 12/18/22 08:46
Benzoic Acid mg/kg ND 1.6 12/18/22 08:46
Benzyl alcohol mg/kg ND 0.66 12/18/22 08:46
bis(2-Chloroethoxy)methane mg/kg ND 0.33 12/18/22 08:46
bis(2-Chloroethyl) ether mg/kg ND 0.33 12/18/22 08:46
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 26 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3870261
Associated Lab Samples:92641136001
Matrix:Solid
Analyzed
bis(2-Ethylhexyl)phthalate mg/kg ND 0.33 12/18/22 08:46
Butylbenzylphthalate mg/kg ND 0.33 12/18/22 08:46
Chrysene mg/kg ND 0.33 12/18/22 08:46
Di-n-butylphthalate mg/kg ND 0.33 v112/18/22 08:46
Di-n-octylphthalate mg/kg ND 0.33 12/18/22 08:46
Dibenz(a,h)anthracene mg/kg ND 0.33 12/18/22 08:46
Dibenzofuran mg/kg ND 0.33 12/18/22 08:46
Diethylphthalate mg/kg ND 0.33 12/18/22 08:46
Dimethylphthalate mg/kg ND 0.33 12/18/22 08:46
Fluoranthene mg/kg ND 0.33 12/18/22 08:46
Fluorene mg/kg ND 0.33 12/18/22 08:46
Hexachloro-1,3-butadiene mg/kg ND 0.33 12/18/22 08:46
Hexachlorobenzene mg/kg ND 0.33 12/18/22 08:46
Hexachlorocyclopentadiene mg/kg ND 0.33 12/18/22 08:46
Hexachloroethane mg/kg ND 0.33 12/18/22 08:46
Indeno(1,2,3-cd)pyrene mg/kg ND 0.33 12/18/22 08:46
Isophorone mg/kg ND 0.33 12/18/22 08:46
N-Nitroso-di-n-propylamine mg/kg ND 0.33 12/18/22 08:46
N-Nitrosodimethylamine mg/kg ND 0.33 12/18/22 08:46
N-Nitrosodiphenylamine mg/kg ND 0.33 12/18/22 08:46
Naphthalene mg/kg ND 0.33 12/18/22 08:46
Nitrobenzene mg/kg ND 0.33 12/18/22 08:46
Pentachlorophenol mg/kg ND 0.66 12/18/22 08:46
Phenanthrene mg/kg ND 0.33 12/18/22 08:46
Phenol mg/kg ND 0.33 12/18/22 08:46
Pyrene mg/kg ND 0.33 12/18/22 08:46
2,4,6-Tribromophenol (S)%71 10-131 12/18/22 08:46
2-Fluorobiphenyl (S)%68 10-130 12/18/22 08:46
2-Fluorophenol (S)%72 10-130 12/18/22 08:46
Nitrobenzene-d5 (S)%73 10-130 12/18/22 08:46
Phenol-d6 (S)%73 10-130 12/18/22 08:46
Terphenyl-d14 (S)%78 10-130 12/18/22 08:46
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3870262LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene mg/kg 1.31.7 77 43-130
1,2-Dichlorobenzene mg/kg 1.31.7 76 43-130
1,3-Dichlorobenzene mg/kg 1.31.7 75 43-130
1,4-Dichlorobenzene mg/kg 1.31.7 75 44-130
1-Methylnaphthalene mg/kg 1.31.7 79 47-130
2,4,5-Trichlorophenol mg/kg 1.31.7 77 47-130
2,4,6-Trichlorophenol mg/kg 1.31.7 77 47-130
2,4-Dichlorophenol mg/kg 1.31.7 77 45-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 27 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3870262LABORATORY CONTROL SAMPLE:
LCSSpike
2,4-Dimethylphenol mg/kg 1.71.7 98 45-130
2,4-Dinitrophenol mg/kg 7.38.5 86 27-140
2,4-Dinitrotoluene mg/kg 1.41.7 85 46-130
2,6-Dinitrotoluene mg/kg 1.51.7 87 48-130
2-Chloronaphthalene mg/kg 1.31.7 78 46-130
2-Chlorophenol mg/kg 1.31.7 76 43-130
2-Methylnaphthalene mg/kg 1.31.7 76 47-130
2-Methylphenol(o-Cresol)mg/kg 1.31.7 78 42-130
2-Nitroaniline mg/kg 2.83.4 84 41-130
2-Nitrophenol mg/kg 1.41.7 81 48-130
3&4-Methylphenol(m&p Cresol)mg/kg 1.31.7 79 39-130
3,3'-Dichlorobenzidine mg/kg 2.53.4 75 41-130
3-Nitroaniline mg/kg 2.93.4 84 37-130
4,6-Dinitro-2-methylphenol mg/kg 2.93.4 84 38-141
4-Bromophenylphenyl ether mg/kg 1.21.7 74 47-130
4-Chloro-3-methylphenol mg/kg 2.73.4 79 44-130
4-Chloroaniline mg/kg 2.43.4 71 41-130
4-Chlorophenylphenyl ether mg/kg 1.31.7 77 45-130
4-Nitroaniline mg/kg 2.83.4 84 42-130
4-Nitrophenol mg/kg 6.88.5 80 39-131
Acenaphthene mg/kg 1.31.7 78 49-130
Acenaphthylene mg/kg 1.31.7 79 50-130
Anthracene mg/kg 1.31.7 76 49-130
Benzo(a)anthracene mg/kg 1.41.7 83 51-130
Benzo(a)pyrene mg/kg 1.31.7 78 51-130
Benzo(b)fluoranthene mg/kg 1.31.7 79 49-130
Benzo(g,h,i)perylene mg/kg 1.41.7 85 48-140
Benzo(k)fluoranthene mg/kg 1.31.7 78 51-130
Benzoic Acid mg/kg 5.98.5 69 22-130
Benzyl alcohol mg/kg 2.63.4 78 43-130
bis(2-Chloroethoxy)methane mg/kg 1.31.7 79 43-130
bis(2-Chloroethyl) ether mg/kg 1.31.7 76 42-130
bis(2-Ethylhexyl)phthalate mg/kg 1.51.7 88 43-130
Butylbenzylphthalate mg/kg 1.51.7 87 44-131
Chrysene mg/kg 1.41.7 82 51-130
Di-n-butylphthalate mg/kg 1.4 v11.7 85 46-130
Di-n-octylphthalate mg/kg 1.61.7 93 45-130
Dibenz(a,h)anthracene mg/kg 1.51.7 86 48-130
Dibenzofuran mg/kg 1.41.7 80 10-130
Diethylphthalate mg/kg 1.41.7 84 48-130
Dimethylphthalate mg/kg 1.41.7 83 48-130
Fluoranthene mg/kg 1.41.7 84 48-130
Fluorene mg/kg 1.41.7 80 48-130
Hexachloro-1,3-butadiene mg/kg 1.21.7 72 39-130
Hexachlorobenzene mg/kg 1.21.7 72 47-130
Hexachlorocyclopentadiene mg/kg 1.21.7 69 17-130
Hexachloroethane mg/kg 1.31.7 77 40-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 28 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3870262LABORATORY CONTROL SAMPLE:
LCSSpike
Indeno(1,2,3-cd)pyrene mg/kg 1.41.7 85 50-130
Isophorone mg/kg 1.41.7 80 41-130
N-Nitroso-di-n-propylamine mg/kg 1.31.7 79 36-130
N-Nitrosodimethylamine mg/kg 1.41.7 80 34-130
N-Nitrosodiphenylamine mg/kg 1.31.7 77 48-130
Naphthalene mg/kg 1.31.7 77 46-130
Nitrobenzene mg/kg 1.41.7 81 39-130
Pentachlorophenol mg/kg 2.53.4 73 42-130
Phenanthrene mg/kg 1.41.7 82 50-130
Phenol mg/kg 1.41.7 83 42-130
Pyrene mg/kg 1.31.7 80 50-130
2,4,6-Tribromophenol (S)%75 10-131
2-Fluorobiphenyl (S)%70 10-130
2-Fluorophenol (S)%74 10-130
Nitrobenzene-d5 (S)%76 10-130
Phenol-d6 (S)%76 10-130
Terphenyl-d14 (S)%72 10-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3870263MATRIX SPIKE SAMPLE:
MSSpike
Result
92640979001
1,2,4-Trichlorobenzene mg/kg 1.52.1 71 16-130<408 ug/kg
1,2-Dichlorobenzene mg/kg 1.52.1 74 19-130<408 ug/kg
1,3-Dichlorobenzene mg/kg 1.52.1 73 19-130<408 ug/kg
1,4-Dichlorobenzene mg/kg 1.52.1 73 20-130<408 ug/kg
1-Methylnaphthalene mg/kg 1.52.1 72 19-130<408 ug/kg
2,4,5-Trichlorophenol mg/kg 1.62.1 77 19-130<408 ug/kg
2,4,6-Trichlorophenol mg/kg 1.52.1 75 18-130<408 ug/kg
2,4-Dichlorophenol mg/kg 1.52.1 73 16-130<408 ug/kg
2,4-Dimethylphenol mg/kg 1.92.1 91 10-130<408 ug/kg
2,4-Dinitrophenol mg/kg 4.510.3 43 10-143<2040 ug/kg
2,4-Dinitrotoluene mg/kg 1.72.1 83 19-130<408 ug/kg
2,6-Dinitrotoluene mg/kg 1.72.1 84 22-130<408 ug/kg
2-Chloronaphthalene mg/kg 1.52.1 73 18-130<408 ug/kg
2-Chlorophenol mg/kg 1.62.1 76 20-130<408 ug/kg
2-Methylnaphthalene mg/kg 1.42.1 69 18-130<408 ug/kg
2-Methylphenol(o-Cresol)mg/kg 1.62.1 78 13-130<408 ug/kg
2-Nitroaniline mg/kg 3.44.1 83 18-130<2040 ug/kg
2-Nitrophenol mg/kg 1.62.1 78 19-130<408 ug/kg
3&4-Methylphenol(m&p Cresol)mg/kg 1.62.1 77 13-130<408 ug/kg
3,3'-Dichlorobenzidine mg/kg 3.04.1 72 10-130<816 ug/kg
3-Nitroaniline mg/kg 3.44.1 82 22-130<2040 ug/kg
4,6-Dinitro-2-methylphenol mg/kg 3.24.1 77 10-144<816 ug/kg
4-Bromophenylphenyl ether mg/kg 1.42.1 68 18-130<408 ug/kg
4-Chloro-3-methylphenol mg/kg 3.14.1 74 16-130<816 ug/kg
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 29 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3870263MATRIX SPIKE SAMPLE:
MSSpike
Result
92640979001
4-Chloroaniline mg/kg 2.74.1 66 17-130<816 ug/kg
4-Chlorophenylphenyl ether mg/kg 1.42.1 68 17-130<408 ug/kg
4-Nitroaniline mg/kg 3.34.1 80 21-130<816 ug/kg
4-Nitrophenol mg/kg 7.710.3 74 13-131<2040 ug/kg
Acenaphthene mg/kg 1.52.1 74 20-130<408 ug/kg
Acenaphthylene mg/kg 1.62.1 76 21-130<408 ug/kg
Anthracene mg/kg 1.52.1 67 19-130<408 ug/kg
Benzo(a)anthracene mg/kg 1.82.1 71 17-130300J ug/kg
Benzo(a)pyrene mg/kg 1.62.1 66 14-130248J ug/kg
Benzo(b)fluoranthene mg/kg 1.72.1 62 11-134389J ug/kg
Benzo(g,h,i)perylene mg/kg 1.72.1 72 12-130185J ug/kg
Benzo(k)fluoranthene mg/kg 1.52.1 67 15-130<408 ug/kg
Benzoic Acid mg/kg ND M110.3 5 10-130<2040 ug/kg
Benzyl alcohol mg/kg 3.14.1 76 20-130<816 ug/kg
bis(2-Chloroethoxy)methane mg/kg 1.52.1 73 16-130<408 ug/kg
bis(2-Chloroethyl) ether mg/kg 1.62.1 77 18-130<408 ug/kg
bis(2-Ethylhexyl)phthalate mg/kg 1.72.1 81 11-130<408 ug/kg
Butylbenzylphthalate mg/kg 1.62.1 77 10-130<408 ug/kg
Chrysene mg/kg 1.82.1 68 17-130373J ug/kg
Di-n-butylphthalate mg/kg 1.6 v12.1 78 16-130<408 ug/kg
Di-n-octylphthalate mg/kg 1.82.1 86 16-130<408 ug/kg
Dibenz(a,h)anthracene mg/kg 1.62.1 76 13-130<408 ug/kg
Dibenzofuran mg/kg 1.52.1 75 19-130<408 ug/kg
Diethylphthalate mg/kg 1.62.1 80 22-130<408 ug/kg
Dimethylphthalate mg/kg 1.62.1 80 23-130<408 ug/kg
Fluoranthene mg/kg 2.12.1 65 14-130729 ug/kg
Fluorene mg/kg 1.52.1 75 19-130<408 ug/kg
Hexachloro-1,3-butadiene mg/kg 1.32.1 63 12-130<408 ug/kg
Hexachlorobenzene mg/kg 1.42.1 67 17-130<408 ug/kg
Hexachlorocyclopentadiene mg/kg 1.22.1 57 10-130<408 ug/kg
Hexachloroethane mg/kg 1.52.1 75 14-130<408 ug/kg
Indeno(1,2,3-cd)pyrene mg/kg 1.72.1 75 13-130165J ug/kg
Isophorone mg/kg 1.62.1 75 17-130<408 ug/kg
N-Nitroso-di-n-propylamine mg/kg 1.62.1 78 10-130<408 ug/kg
N-Nitrosodimethylamine mg/kg 1.62.1 78 16-130<408 ug/kg
N-Nitrosodiphenylamine mg/kg 1.52.1 75 19-130<408 ug/kg
Naphthalene mg/kg 1.52.1 72 18-130<408 ug/kg
Nitrobenzene mg/kg 1.62.1 77 15-130<408 ug/kg
Pentachlorophenol mg/kg 2.84.1 67 10-130<816 ug/kg
Phenanthrene mg/kg 1.82.1 66 17-130424 ug/kg
Phenol mg/kg 1.62.1 80 15-130<408 ug/kg
Pyrene mg/kg 1.82.1 62 31-130532 ug/kg
2,4,6-Tribromophenol (S)%69 10-131
2-Fluorobiphenyl (S)%48 10-130
2-Fluorophenol (S)%70 10-130
Nitrobenzene-d5 (S)%69 10-130
Phenol-d6 (S)%69 10-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 30 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3870263MATRIX SPIKE SAMPLE:
MSSpike
Result
92640979001
Terphenyl-d14 (S)%57 10-130
Parameter Units
Dup
Result QualifiersRPDResult
92641300001
3870264SAMPLE DUPLICATE:
1,2,4-Trichlorobenzene mg/kg NDND
1,2-Dichlorobenzene mg/kg NDND
1,3-Dichlorobenzene mg/kg NDND
1,4-Dichlorobenzene mg/kg NDND
1-Methylnaphthalene mg/kg NDND
2,4,5-Trichlorophenol mg/kg NDND
2,4,6-Trichlorophenol mg/kg NDND
2,4-Dichlorophenol mg/kg NDND
2,4-Dimethylphenol mg/kg NDND
2,4-Dinitrophenol mg/kg NDND
2,4-Dinitrotoluene mg/kg NDND
2,6-Dinitrotoluene mg/kg NDND
2-Chloronaphthalene mg/kg NDND
2-Chlorophenol mg/kg NDND
2-Methylnaphthalene mg/kg NDND
2-Methylphenol(o-Cresol)mg/kg NDND
2-Nitroaniline mg/kg NDND
2-Nitrophenol mg/kg NDND
3&4-Methylphenol(m&p Cresol)mg/kg NDND
3,3'-Dichlorobenzidine mg/kg NDND
3-Nitroaniline mg/kg NDND
4,6-Dinitro-2-methylphenol mg/kg NDND
4-Bromophenylphenyl ether mg/kg NDND
4-Chloro-3-methylphenol mg/kg NDND
4-Chloroaniline mg/kg NDND
4-Chlorophenylphenyl ether mg/kg NDND
4-Nitroaniline mg/kg NDND
4-Nitrophenol mg/kg NDND
Acenaphthene mg/kg NDND
Acenaphthylene mg/kg NDND
Anthracene mg/kg NDND
Benzo(a)anthracene mg/kg NDND
Benzo(a)pyrene mg/kg NDND
Benzo(b)fluoranthene mg/kg NDND
Benzo(g,h,i)perylene mg/kg NDND
Benzo(k)fluoranthene mg/kg NDND
Benzoic Acid mg/kg NDND
Benzyl alcohol mg/kg NDND
bis(2-Chloroethoxy)methane mg/kg NDND
bis(2-Chloroethyl) ether mg/kg NDND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 31 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result QualifiersRPDResult
92641300001
3870264SAMPLE DUPLICATE:
bis(2-Ethylhexyl)phthalate mg/kg NDND
Butylbenzylphthalate mg/kg NDND
Chrysene mg/kg NDND
Di-n-butylphthalate mg/kg ND v1ND
Di-n-octylphthalate mg/kg NDND
Dibenz(a,h)anthracene mg/kg NDND
Dibenzofuran mg/kg NDND
Diethylphthalate mg/kg NDND
Dimethylphthalate mg/kg NDND
Fluoranthene mg/kg NDND
Fluorene mg/kg NDND
Hexachloro-1,3-butadiene mg/kg NDND
Hexachlorobenzene mg/kg NDND
Hexachlorocyclopentadiene mg/kg NDND
Hexachloroethane mg/kg NDND
Indeno(1,2,3-cd)pyrene mg/kg NDND
Isophorone mg/kg NDND
N-Nitroso-di-n-propylamine mg/kg NDND
N-Nitrosodimethylamine mg/kg NDND
N-Nitrosodiphenylamine mg/kg NDND
Naphthalene mg/kg NDND
Nitrobenzene mg/kg NDND
Pentachlorophenol mg/kg NDND
Phenanthrene mg/kg NDND
Phenol mg/kg NDND
Pyrene mg/kg NDND
2,4,6-Tribromophenol (S)%8263
2-Fluorobiphenyl (S)%7042
2-Fluorophenol (S)%7870
Nitrobenzene-d5 (S)%8168
Phenol-d6 (S)%8171
Terphenyl-d14 (S)%8435
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 32 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
743261
MADEP EPH
MADEP EPH
MADEP EPH NC Soil
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92641136001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3866776
Associated Lab Samples:92641136001
Matrix:Solid
Analyzed
Aliphatic (C09-C18)mg/kg ND 10.0 N212/14/22 18:19
Aliphatic (C19-C36)mg/kg ND 10.0 N212/14/22 18:19
Aromatic (C11-C22)mg/kg ND 10.0 N212/14/22 18:19
1-Chlorooctadecane (S)%59 40-140 12/14/22 18:19
2-Bromonaphthalene (S)%103 40-140 12/14/22 18:19
2-Fluorobiphenyl (S)%97 40-140 12/14/22 18:19
o-Terphenyl (S)%77 40-140 12/14/22 18:19
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3866777LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
3866778
Aliphatic (C09-C18)mg/kg ND N29.9 50 40-14052ND 50
Aliphatic (C19-C36)mg/kg ND N213.2 71 40-14071ND 50
Aromatic (C11-C22)mg/kg 26.1 N228.1 93 40-1409626.9 3 50
1-Chlorooctadecane (S)%64 40-14063
2-Bromonaphthalene (S)%117 40-140119
2-Fluorobiphenyl (S)%110 40-140112
o-Terphenyl (S)%80 40-14082
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 33 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
742736
SW-846
SW-846
Dry Weight/Percent Moisture
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92641136001
Parameter Units
Dup
Result QualifiersRPDResult
92640971001
3864094SAMPLE DUPLICATE:
Percent Moisture %19.5 N2420.4
Parameter Units
Dup
Result QualifiersRPDResult
92641171007
3864095SAMPLE DUPLICATE:
Percent Moisture %19.3 N2119.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 34 of 51
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.L1
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.N2
The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.v1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 35 of 51
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92641136
SAMIR'S #6 12/9/22
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92641136001 743261 743461MW-1R SOIL MADEP EPH MADEP EPH
92641136002 743192 743647MW-1R EPA 625.1 EPA 625.1
92641136001 743903 744205MW-1R SOIL EPA 3546 EPA 8270E
92641136002 743441MW-1R SM 6200B
92641136001 742789 742813MW-1R SOIL EPA 5035A/5030B EPA 8260D
92641136001 742736MW-1R SOIL SW-846
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/20/2022 03:30 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 36 of 51
Page 37 of 51
Page 38 of 51
Page 39 of 51
ANALYTICAL REPORT
December 20, 2022
Pace Analytical - Asheville, NC
Sample Delivery Group:L1567934
Samples Received:12/15/2022
Project Number:92641136
Description:Samir's #6 12/9/22
Site:001
Report To:Lorri Patton
2225 Riverside Drive
Asheville, NC 28804
Entire Report Reviewed By:
December 20, 2022
[Preliminary Report]
Nancy McLain
Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be
reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace
Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and
ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided,
and as the samples are received.
Pace Analytical National
12065 Lebanon Rd Mount Juliet, TN 37122 615-758-5858 800-767-5859 www.pacenational.com
1 Cp
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3Ss
4Cn
5Sr
6Qc
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December 20, 2022
Nancy McLain
Project Manager
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Page 40 of 51
TABLE OF CONTENTS
Cp: Cover Page 1
Tc: Table of Contents 2
Ss: Sample Summary 3
Cn: Case Narrative 4
Sr: Sample Results 5
MW-1R SOIL L1567934-01 5
Qc: Quality Control Summary 6
Total Solids by Method 2540 G-2011 6
Volatile Petroleum Hydrocarbons by Method MADEPV 7
Gl: Glossary of Terms 8
Al: Accreditations & Locations 9
Sc: Sample Chain of Custody 10
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE SUMMARY
Collected by Collected date/time Received date/time
MW-1R SOIL L1567934-01 Solid 12/09/22 10:00 12/15/22 09:00
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time
Total Solids by Method 2540 G-2011 WG1975426 1 12/16/22 09:48 12/16/22 10:12 CMK Mt. Juliet, TN
Volatile Petroleum Hydrocarbons by Method MADEPV WG1976859 1 12/09/22 10:00 12/20/22 05:20 ADM Mt. Juliet, TN
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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Page 42 of 51
CASE NARRATIVE
All sample aliquots were received at the correct temperature, in the proper containers, with the
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data.
[Preliminary Report]
Nancy McLain
Project Manager
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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Nancy McLain
Project Manager
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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Page 43 of 51
SAMPLE RESULTS - 01
L1567934
MW-1R SOIL
Collected date/time: 12/09/22 10:00
Total Solids by Method 2540 G-2011
Result Qualifier Dilution Analysis Batch
Analyte %date / time
Total Solids 78.3 1 12/16/2022 10:12 WG1975426
Volatile Petroleum Hydrocarbons by Method MADEPV
Result (dry)Qualifier MDL (dry)RDL (dry)Dilution Analysis Batch
Analyte mg/kg mg/kg mg/kg date / time
Unadjusted C5-C8 Aliphatics 11.7 2.59 7.77 1 12/20/2022 05:20 WG1976859
Unadjusted C9-C12 Aliphatics 5.20 J 2.59 7.77 1 12/20/2022 05:20 WG1976859
Unadjusted C9-C10 Aromatics 8.59 2.59 7.77 1 12/20/2022 05:20 WG1976859
Total VPH 25.5 2.59 7.77 1 12/20/2022 05:20 WG1976859
(S) 2,5-Dibromotoluene(FID)96.0 70.0-130 12/20/2022 05:20 WG1976859
(S) 2,5-Dibromotoluene(PID)96.6 70.0-130 12/20/2022 05:20 WG1976859
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3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1975426
Total Solids by Method 2540 G-2011 L1567934-01
Method Blank (MB)
(MB) R3872960-1 12/16/22 10:12
MB Result MB Qualifier MB MDL MB RDL
Analyte %%%
Total Solids 0.00200
L1567972-03 Original Sample (OS) • Duplicate (DUP)
(OS) L1567972-03 12/16/22 10:12 • (DUP) R3872960-3 12/16/22 10:12
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte %%%%
Total Solids 98.0 98.0 1 0.0287 10
Laboratory Control Sample (LCS)
(LCS) R3872960-2 12/16/22 10:12
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte %%%%
Total Solids 50.0 50.0 100 85.0-115
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QUALITY CONTROL SUMMARYWG1976859
Volatile Petroleum Hydrocarbons by Method MADEPV L1567934-01
Method Blank (MB)
(MB) R3873765-3 12/19/22 22:49
MB Result MB Qualifier MB MDL MB RDL
Analyte mg/kg mg/kg mg/kg
Unadjusted C5-C8 Aliphatics U 1.67 5.00
Unadjusted C9-C12 Aliphatics U 1.67 5.00
Unadjusted C9-C10 Aromatics U 1.67 5.00
Total VPH U 1.67 5.00
(S) 2,5-Dibromotoluene(FID)95.2 70.0-130
(S) 2,5-Dibromotoluene(PID)96.4 70.0-130
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3873765-1 12/19/22 20:38 • (LCSD) R3873765-2 12/19/22 21:11
Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte mg/kg mg/kg mg/kg %%%%%
Unadjusted C5-C8 Aliphatics 60.0 51.2 51.6 85.3 86.0 70.0-130 0.778 25
Unadjusted C9-C12 Aliphatics 70.0 54.9 55.5 78.4 79.3 70.0-130 1.09 25
Unadjusted C9-C10 Aromatics 10.0 10.9 10.9 109 109 70.0-130 0.000 25
Total VPH 140 117 118 83.6 84.3 70.0-130 0.851 25
(S) 2,5-Dibromotoluene(FID) 101 98.5 70.0-130
(S) 2,5-Dibromotoluene(PID) 103 101 70.0-130
1 Cp
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3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
intended as a comprehensive explanation, and if you have additional questions please contact your project representative.
Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name, Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On-Site Data, Sampling Collection Dates/Times, and Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received.
Abbreviations and Definitions
(dry)Results are reported based on the dry weight of the sample. [this will only be present on a dry report basis for soils].
MDL Method Detection Limit.
MDL (dry)Method Detection Limit.
RDL Reported Detection Limit.
RDL (dry)Reported Detection Limit.
Rec.Recovery.
RPD Relative Percent Difference.
SDG Sample Delivery Group.
(S)
Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and
Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be
detected in all environmental media.
U Not detected at the Reporting Limit (or MDL where applicable).
Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
Dilution
If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
Limits
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges.
Original Sample The non-spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control
sample. The Original Sample may not be included within the reported SDG.
Qualifier
This column provides a letter and/or number designation that corresponds to additional information concerning the result
reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.
Result
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was
no measurable result returned for a specific analyte, the result in this column may state “ND” (Not Detected) or “BDL”
(Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)Confidence level of 2 sigma.
Case Narrative (Cn)
A brief discussion about the included sample results, including a discussion of any non-conformances to protocol
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control
Summary (Qc)
This section of the report includes the results of the laboratory quality control analyses required by procedure or
analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
Sample Chain of
Custody (Sc)
This is the document created in the field when your samples were initially collected. This is used to verify the time and
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the
samples from the time of collection until delivery to the laboratory for analysis.
Sample Results (Sr)
This section of your report will provide the results of all testing performed on your samples. These results are provided
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary (Ss)This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier Description
J The identification of the analyte is acceptable; the reported value is an estimate.
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Page 47 of 51

Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122
Alabama 40660 Nebraska NE-OS-15-05
Alaska 17-026 Nevada TN000032021-1
Arizona AZ0612 New Hampshire 2975
Arkansas 88-0469 New Jersey–NELAP TN002
California 2932 New Mexico ¹TN00003
Colorado TN00003 New York 11742
Connecticut PH-0197 North Carolina Env375
Florida E87487 North Carolina ¹DW21704
Georgia NELAP North Carolina ³41
Georgia ¹923 North Dakota R-140
Idaho TN00003 Ohio–VAP CL0069
Illinois 200008 Oklahoma 9915
Indiana C-TN-01 Oregon TN200002
Iowa 364 Pennsylvania 68-02979
Kansas E-10277 Rhode Island LAO00356
Kentucky ¹ ⁶KY90010 South Carolina 84004002
Kentucky ²16 South Dakota n/a
Louisiana AI30792 Tennessee ¹ ⁴2006
Louisiana LA018 Texas T104704245-20-18
Maine TN00003 Texas ⁵LAB0152
Maryland 324 Utah TN000032021-11
Massachusetts M-TN003 Vermont VT2006
Michigan 9958 Virginia 110033
Minnesota 047-999-395 Washington C847
Mississippi TN00003 West Virginia 233
Missouri 340 Wisconsin 998093910
Montana CERT0086 Wyoming A2LA
A2LA – ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789
A2LA – ISO 17025 ⁵1461.02 DOD 1461.01
Canada 1461.01 USDA P330-15-00234
EPA–Crypto TN00003
ACCREDITATIONS & LOCATIONS

¹ Drinking Water ² Underground Storage Tanks ³ Aquatic Toxicity ⁴ Chemical/Microbiological ⁵ Mold ⁶ Wastewater n/a Accreditation not applicable
* Not all certifications held by the laboratory are applicable to the results reported in the attached report.
* Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical.
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Pace Analytical - Asheville, NC 92641136 L1567934 12/20/22 12:02 9 of 12
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