6004_McGuireLF1_Q12024_GWMR_FID1836676_20240506

DUKE
ENERGY
May 6, 2024
North Carolina Department of Environmental Quality
Division of Waste Management
Solid Waste Section
1646 Mail Service Center
Raleigh, North Carolina 28778
Attn: Ms. Sarah Moutos (submitted electronically)
Re: Semi -Annual Water Quality Monitoring Report — January 2024
Duke Energy Carolinas, LLC
McGuire Nuclear Station
Landfill No. 1 (Unlined), Permit #60-04
Dear Ms. Moutos:
Duke Energy
McGuire Nuclear Station
12700 Hagers Ferry Road
Huntersville, NC 28078
Duke Energy is providing the result of semi-annual water quality monitoring for the Duke Energy Carolinas, McGuire,
Landfill No. 1 (Unlined), located near Huntersville, North Carolina.
On January 8-10, 2024, groundwater and surface water samples were collected in accordance with the McGuire Landfill
No. 1 Sampling and Analysis Plan.
A summary of the field data is presented in Table 3. The groundwater sampling field and analytical results are summarized
in Table 4. The analytical results for the constituents are compared to the groundwater standards found in Title 15A NCAC
02L .0202 (2L Standards). Results with values that attain or exceed the 2L Standards (or outside of 2L Standard range for
pH) are indicated on Table 4 by yellow highlighting. A summary of the analytical results that attain or exceed the 2L
Standards (or outside of 2L Standard range for pH) and a preliminary analysis of the cause and significance of such
occurrences are presented in Table 5.
The surface water field and analytical results are summarized in Table 6. The surface water analytical results for the
constituents are compared to the surface water standards found in Title 15A NCAC 02B .0211 (26 Standard) for Class C
WS-IV waters. No 2B Standards were exceeded during the January 2024 monitoring event.
Duke Energy personnel sample designated groundwater and surface water locations at McGuire Landfill No. 1 (Unlined)
semi-annually during January and July. The next water quality monitoring event is planned for July 2024 with a report of
monitoring results to follow.
If you need additional information regarding this submittal, please contact Ashley Healy at Ashley. Healv(CDduke-energy.com
or [phone].
Sincerely
Brent Bare
Duke Energy
McGuire Nuclear Station
Plant Manager
www.duke-energy.com Page 1 of 1

�R USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #:
NC DENR I IEnvironmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
S&ME, Inc. (Consultant for Duke Energy)
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Julie P. Robertson, P.G. Phone: [phone]
E-mail: [e-mail]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Duke Energy Carolinas, LLC 12700 Hagers Ferry Road 6004 .0500 January 8-10, 2024
McGuire, Landfill No. 1 (Unlined) Huntersville, NC 28078
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring x❑ Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells ❑
Leachate monitoring data
Surface water monitoring data ❑
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
RX Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Julie P. Robertson, P.G. Principal Geologist 704-523-4726
/J Title (Area Code) Telephone Number
April 29, 2024 Affix NC Licensed/ Professional Geologist Seal
Signature Date
2016 Ayrsley Town Blvd., Suite 2-A, Charlotte, North Carolina 28273
Facility Representative Address
S&ME Engineering License # F-0176, S&ME Geology License# C-145
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009

Semi -Annual Water Quality Monitoring Report
January 2024 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 1
(Unlined) Permit No. 6004
Mecklenburg County, North Carolina
S&ME Project No. 23350793, Ph.775A

REPORT VERIFICATION
PROJECT: SEMI-ANNUAL WATER QUALITY MONITORING REPORT
DUKE ENERGY CAROLINAS, MCGUIRE, LANDFILL NO. 1
(UNLINED) PERMIT NO. 6004
S&ME PROJECT NO. 23350793, PH. 775A
TITLE: JANUARY 2024 SAMPLING EVENT
This document has been reviewed for accuracy and quality commensurate with the intended
application.
Prepared by:
Approved bv. Zz_
Project Manager: Julie P. Robertson, PG
Date: 4/29/2024
Date: 4/29/2024
Licensed Geologist Seal:
Ryrytil�F`;�d:�af
t9R� . ' n ?d,•
.�� 7
4 •c.�
"- L =
•�T M' V i � ��.: i
S&ME, Inc.
2016 Ayrsley Town Blvd., Suite 2-A
Charlotte, North Carolina 28273
North Carolina Geological Corporation Number C-145
S&ME, Inc. 12016 Ayrsley Town Blvd., Suite 2-A I Charlotte, NC 282731 p 704.523.4726 1 www.smeinc.com

Semi -Annual Water Quality Monitoring Report — January 2024 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 1
(Unlined) Permit No. 6004 I I
S&ME Project No. 23350793, Ph. 775A
Table of Contents
1.0 Background........................................................................................................................1
1.1 Site Description...............................................................................................................................1
1.2 Hydrologic Setting.........................................................................................................................1
1.3 Monitoring Program......................................................................................................................1
2.0 Methods..............................................................................................................................2
2.1 Sampling and Analysis Methods.................................................................................................2
2.1.1 Groundwater and Surface Water......................................................................................................2
2.1.2 Radiological Samples.........................................................................................................................3
2.2 Statement of Work..........................................................................................................................3
3.0 Results.................................................................................................................................4
3.1 Site Groundwater Flow.................................................................................................................4
3.2 Analytical Results...........................................................................................................................4
3.2.1 Groundwater.....................................................................................................................................4
3.2.2 Surface Water....................................................................................................................................5
3.2.3 Radiological Samples.........................................................................................................................5
3.2.4 Quality Assurance / Quality Control..............................................................................................5
April 29, 2024 ii

Semi -Annual Water Quality Monitoring Report — January 2024 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 1
(Unlined) Permit No. 6004
S&ME Project No. 23350793, Ph. 775A
Appendices
Appendix I — Figures
Figure 1
Figure 2
Figure 3
Appendix II — Tables
Table 1
Table 2
Table 3
Table 4
Table 5
Table 6
Table 7
Site Location Map
Sample Locations
Shallow Groundwater Contour Map
Well Construction Information
Groundwater Flow Velocities
Field Data Parameters
Groundwater Field and Analytical Results
Results that Equal or Exceed 15A NCAC 2L Groundwater Standards
Surface Water Field and Analytical Results
Radiological Analytical Results
Appendix III — Field Sampling Forms
Appendix IV — Laboratory Reports and Chain -of -Custody Forms
s
0
April 29, 2024

Semi -Annual Water Quality Monitoring Report — January 2024 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 1
(Unlined) Permit No. 6004 I s
S&ME Project No. 23350793, Ph. 775A
1.0 Background
1.1 Site Description
The Duke Energy Carolinas, McGuire, Landfill #1 (Unlined)' (hereafter, landfill) is located at the McGuire Nuclear
Station in Mecklenburg County, North Carolina. The landfill is permitted under North Carolina Department of
Environmental Quality (NCDEQ) Solid Waste Permit No. 6004-INDUS and is closed and no longer accepts waste.
The landfill and surrounding areas are shown on Figure 1 in Appendix I. The approximate limit of waste is shown
in Figures 2 and 3 in Appendix I.
1.2 Hydrologic Setting
The closed landfill is located south of North Carolina (NC) Highway 73, east of the Catawba River, and northwest
of Cashion Road as shown on Figures 1 and 2 in Appendix I. Cashion Road runs along a topographic divide with
topography sloping away from the road to the northwest and to the southeast. There is one surface water
drainage feature north of the landfill that drains northwest to the Catawba River as depicted on Figure 2 in
Appendix I. The Catawba River is classified as a Class C Water Supply -IV source (WS-IV).
1.3 Monitoring Program
As described in the Sampling and Analysis Plan (SAP) dated May 13, 2022, the current monitoring system at the
landfill consists of the following:
Monitoring Wells: MW-1
MW-4R
MW-1 D
MW-4DR
MW-2A
MW-413RR
MW-2D
MW-11
MW-3
MW-11 D
MW-3D
MW-11 BR
MW-313R
MW-12
MW-4
MW-12D
MW-4D
MW-13D
MW-413R
MW-13BR
Surface Water Sample Location: SW-1
' In response to the North Carolina Division of Public Health, Radiation Protection Section, November 77, 2006 letter to Duke
Energy, LLC, Duke Energy offered to indicate the landfill as unlined in reports.
April 29, 2024 1

Semi -Annual Water Quality Monitoring Report — January 2024 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 1 �r
(Unlined) Permit No. 6004
S&ME Project No. 23350793, Ph. 775A
Monitoring wells were originally installed as well pairs, consisting of one shallow well and one deep well (with the
exception of monitoring well MW-13D, which is accompanied by a bedrock well rather than a shallow well).
Shallow wells were installed with screened intervals set to bracket the water table at the time of installation. Deep
wells were constructed so that the bottom of the screen is located within residual soils just above auger refusal
and are designated with "D" to represent the deeper well within each well pair. Wells designated with "BR"
represent wells constructed so that the bottom of the screen is located within fractured bedrock.
Monitoring wells MW-4R and MW-4DR ("R" designation indicates replacement wells) were installed in 2013 near
the landfill review boundary to replace wells MW-4 and MW-4D, which are approximately 15 feet outside of the
limits of waste for the landfill. At the request of NCDEQ Solid Waste Section (NCDEQ-SWS), monitoring wells MW-
4 and MW-41D continue to be sampled along with the replacement wells.
In late 2020, six deep and bedrock monitoring wells (MW-3BR, MW-413R, MW-4BRR, MW-11 BR, MW-13D, and
MW-13BR) were installed as part of a site characterization study, and have been included with the semi-annual
sampling regime since the July 2022 sampling event. Monitoring well construction information is summarized in
Table 1 in Appendix II and monitoring well locations are shown on Figure 2 in Appendix I.
Surface water sample location SW-1 is collected from the unnamed stream (north of the landfill), upstream of the
confluence with the surface water drainage feature that ultimately discharges to the Catawba River as shown on
Figure 2 in Appendix I. SW-1 is the designated background sampling location for this monitoring program.
2.0 Methods
2.1 Sampling and Analysis Methods
Groundwater and surface water sampling activities were performed by Duke Energy Groundwater Science Group
(Duke Energy Carolinas Field Certification #99046001), in general accordance with the North Carolina Solid Waste
Management Guidelines. Copies of the January 2024 field sampling forms are included in Appendix III. The
parameters and constituents reported were selected in accordance with the SAP and the NCDEQ Division of Waste
Management, Solid Waste Section Guidelines. Groundwater and surface water samples were analyzed by the Duke
Energy Analytical Laboratory (North Carolina Laboratory Certification #248), Pace Analytical Services (North
Carolina Laboratory Certification #329), and EnRad Laboratories. The laboratory reports and chain -of -custody
forms are included in Appendix IV.
2.1.1 Groundwater and Surface Water
The groundwater and surface water samples were analyzed for the following parameters using the following
analytical methods in accordance with the SAP:
Barium, calcium, magnesium, potassium, and sodium using SW-846 EPA Test Method 6010D
Arsenic, cadmium, chromium, lead, selenium, and silver using SW-846 EPA Test Method 6020B
Mercury using SW-846 EPA Test Method 7470A
April 29, 2024

Semi -Annual Water Quality Monitoring Report — January 2024 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 1
(Unlined) Permit No. 6004
S&ME Project No. 23350793, Ph. 775A
• Chloride and Sulfate using SW-846 EPA Test Method 9056A
• Alkalinity using Standard Method (SM) 2320B
• 1,4-Dioxane using SW-846 EPA Test Method 8260D (SIM)
• Volatile organic compounds (VOCs) using SW-846 EPA Test Method 8260DI
The surface water sample was also field -filtered using a 0.45-micron in -line filter and dissolved analyses were
performed for the following constituents:
• Arsenic, cadmium, chromium, lead, and silver using SW-846 Method 6020B
2.1.2 Radiological Samples
In accordance with the requirements of the Radioactive Materials License No. 060-0379-7 issued by the North
Carolina Department of Health and Human Services Radiation Protection Section, the following radiological
analyses were performed on groundwater and surface water samples:
• Gross alpha and beta radioactivity using ASTM Method D7283-173
• Tritium using ASTM Method D4107-084
• Gamma radioactivity for select isotopes using EPA Method 901.1
2.2 Statement of Work
S&ME completed the following tasks:
Received field sampling data from Duke Energy (performed by Duke Energy Groundwater Sciences Group)
for monitoring wells MW-1, MW-1 D, MW-2A, MW-2D, MW-3, MW-3D, MW-313R, MW-4, MW-4D, MW-4R,
MW-4DR, MW-4BRR, MW-11, MW-11 D, MW-12, MW12D, MW-13D, MW-1313R, and surface water sample
location SW-1. The samples were collected on January 81" and 101", 2024, and S&ME received the data
from Duke Energy via e-mail correspondence from Ashley Healy (Duke Energy) to Jasmine Tayouga
(S&ME) on February 201", 2024.
• Reviewed the laboratory analytical results and the Electronic Data Deliverables (EDDs) provided by Duke
Energy for the samples noted above.
z Laboratory analytical methods for VOCs have changed from SW-846 EPA Test Method 8260E to SW-846 EPA Test Method
8260D.
3 Laboratory analytical methods for gross alpha and beta radioactivity have changed from EPA 900ISM71108 to ASTM D7283-17.
4 Laboratory analytical methods for Tritium have changed from EPA 906.0 Modified to ASTM D4707-0&
April 29, 2024

Semi -Annual Water Quality Monitoring Report — January 2024 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 1
(Unlined) Permit No. 6004 s
S&ME Project No. 23350793, Ph. 775A
• Developed a shallow groundwater contour map and calculated groundwater flow velocities using survey
data and groundwater levels measured by Duke Energy Groundwater Sciences Group.
3.0 Results
3.1 Site Groundwater Flow
Shallow groundwater surface contours and groundwater flow direction in the vicinity of the landfill are shown on
Figure 3 in Appendix I. These contours were developed using the depth to groundwater measurements in the
shallow wells' on the date of sampling and top of well casing elevations. Calculated groundwater flow velocities
are presented on Table 2 in Appendix II.
Based on groundwater elevations calculated for the January 2024 sampling event, groundwater flow is generally
from the southeast to the northwest toward the Catawba River.
3.2 Analytical Results
3.2.1 Groundwater
Laboratory results for groundwater samples were compared to the Title 15A NCAC Subchapter 2L Standards (2L
Standards) to evaluate compliance with NCDEQ groundwater quality standards. In one or more wells, pH
measurements were reported outside of the 2L Standard range. Concentrations greater than their respective 2L
Standards were reported in one or more wells for the following constituents: methylene chloride,
tetrachloroethylene (PCE), trichloroethene (TCE), sulfate, and vinyl chloride.
The concentrations greater than the 2L Standard (with the exception of pH) were detected in MW-3D, MW-3BR,
MW-4, MW-4D, MW-4BR, MW-4R, and MW-4BRR. It should be noted that MW-4, MW-4D, and MW-4BR are
located adjacent to the landfill limits of waste boundary; while MW-3D, MW-3BR, MW-4R, and MW-4BRR are
located adjacent to the landfill review boundary.
A summary of field data parameters recorded prior to sample collection is presented in Table 3 in Appendix II. A
summary of groundwater analytical results for the current sampling event is presented in Table 4 in Appendix II.
A summary of the groundwater analytical results that equal or exceed the 2L Standards and a comparison to
historical concentration ranges are presented in Table 5 in Appendix II.
' Please note that periodically, shallow monitoring well MW-72 is not used to produce groundwater contours. MW-72
was used to produce groundwater contours for the July 2022, January 2023, and July 2023 Sampling Events. MW-12
was not used to produce groundwater contours in this January 2024 report. Historically, MW-72 has experienced
water level elevation fluctuations not typical of normal seasonal variations. Duke Energy is currently evaluating the
water level data and the need for future abandonment and/or replacement.
April 29, 2024 4

Semi -Annual Water Quality Monitoring Report — January 2024 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 1 �r
(Unlined) Permit No. 6004
S&ME Project No. 23350793, Ph. 775A
3.2.2 Surface Water
Laboratory results for the surface water sample (SW-1) were compared to the Title 15A NCAC Subchapter 2B
Standards (213 Standards) for Class C WS-IV waters to evaluate compliance with established criteria. No
constituents exceeded 2B Standards in the surface water sample SW-1 collected during the January 2024 sampling
event. A summary of field data parameters recorded prior to surface water sample collection is presented in Table
3 in Appendix II. A summary of surface water analytical results for the January 2024 sampling event is presented
in Table 6 in Appendix II.
3.2.3 Radiological Samples
The results of the radiological analyses are presented in Table 7 in Appendix II. A copy of the laboratory report
has been submitted to the North Carolina Department of Health and Human Services Radiation Protection Section
for reference and is also included in this report in Appendix IV. S&ME did not evaluate this data.
3.2.4 Quality Assurance / Quality Control
Field -performed quality assurance and quality control (QA/QC) consisted of the collection and analysis of two field
blanks (one on each day of sampling) to evaluate if contamination was imparted to the samples by the sample
container, preservative, or other exogenous sources. One field duplicate sample per day was also collected as a
measure of sampling and analytical precision. Samples for the monitoring wells and surface water locations were
submitted to Duke Energy Analytical Laboratories on January 9t" and 111", 2024.
One trip blank was transported with each set of samples to evaluate the effects of shipping and laboratory sources
of contamination for Volatile Organic Compounds (VOCs). No VOCs were detected at concentrations above the
laboratory Method Reporting Limit (MRL) in the trip blank samples, nor in either of the field blank samples.
Select samples were diluted, as is normal laboratory practice, to bring samples within the calibrated range of the
analysis. Specifics regarding the samples that were diluted, including the dilution amount, are reported in the
laboratory report. Additional QA/QC data, laboratory analyses, and chain -of -custody forms are included in
Appendix IV.
April 29, 2024

Appendices

Appendix I - Figures

/ MW-13D
MW-13BR MW-3
MW-3BR
--" MW-4R MW-4
MW-4DR MW-4D
MW-4BRR MW-4BR
MRwillbidEbak
LANDFILL
NO. 1
MW-11BR e
MW-11 ., o
MW-11D
O
�, MW-lD
Henry Harrison
Stillwell Dr
0
h
O
qj
��' 3 1
NOTES:
GIS BASE LAYERS WERE OBTAINED FROM THE OWNER AND ESRI. THIS MAP IS FOR 0
INFORMATIONAL PURPOSES ONLY. ALL FEATURE LOCATIONS DISPLAYED ARE
APPROXIMATED. THEY ARE NOT BASED ON CIVIL SURVEY INFORMATION, UNLESS STATED
OTHERWISE.
GRAPHIC SCALE
400 800
(IN FEET)
Is
LANDFILL
NO.2
SW-1
i
LEGEND
GROUNDWATER MONITORING WELL LOCATIONS
0 SURFACE WATER SAMPLE LOCATION
1110-110—►STREAMS WITH FLOW DIRECTION
0 WATERBODIES
LANDFILL NO. 1 COMPLIANCE BOUNDARY
LANDFILL NO. 1 LIMITS OF WASTE
LANDFILL NO. 1 REVIEW BOUNDARY
DUKE ENERGY PROPERTY BOUNDARY
LANDFILL NO. 2
STREETS
2' CONTOURS
10' CONTOURS
y �
O
z
c~
y G
W Q
� z
O
O V
�z J
0
U Q Z
(� J
LLI
W O
j U
' Q m
z z
' O Lu
i CL U
Q W
U
w
w
Lu
SCALE:
1 " = 400 '
DATE:
4-18-2024
PROJECT NUMBER:
23350793, PH. 775A
FIGURE NO
2

kM-o 8,
i�'rol ,o
c�
MW-111 *>/ 672.33'
672.07'/ 000
$yam-- O MW-2A'.
' // /6 685.77'
/
1000,
- i /® LANDFILL
/ NO.1100,
10000,
/ /
0
- � � 1
0.10' '
�IW-1
/ / 697.94'
692.25'
Now
MW-12
.10 720.72' J
►0
LEGEND
�s " O SHALLOW GROUNDWATER MONITORING LOCATION
Stillwell r
►—►—►STREAMS WITH FLOW DIRECTION
—► GROUNDWATER FLOW DIRECTION
SCALE:
• GROUNDWATER CONTOUR - JANUARY 2024 1 " = 200 '
\' LANDFILL NO. 1 COMPLIANCE BOUNDARY DATE:
4-18-2024
- ' — LANDFILL NO. 1 LIMITS OF WASTE PROJECT NUMBER:
NOTES: LANDFILL NO. 1 REVIEW BOUNDARY
GIS BASE LAYERS WERE OBTAINED FROM THE OWNER AND ESRI. THIS MAP IS FOR INFORMATIONAL PURPOSES ONLY. ALL FEATURE 0 200 400 DUKE ENERGY PROPERTY BOUNDARY 23350793, PH. 775A
LOCATIONS DISPLAYED ARE APPROXIMATED. THEY ARE NOT BASED ON CIVIL SURVEY INFORMATION, UNLESS STATED OTHERWISE. STREETS FIGURE NO.
MW-12 WAS NOT USED TO PRODUCE GROUNDWATER CONTOURS IN THIS JANUARY 2024 REPORT. HISTORICALLY, MW-12 HAS GRAPHIC SCALE (IN FEET) 2' CONTOURS
EXPERIENCED WATER LEVEL ELEVATION FLUCTUATIONS NOT TYPICAL OF NORMAL SEASONAL VARIATIONS. 3
10' CONTOURS

Appendix II - Tables

Table 1: Well Construction Information
Landfill No. 1 (Unlined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
S&ME Project No: 23350793, Ph.775A
Well ID
MW-1
Install Date 16
..
07/18/89
GPS Coordinates
JALM
Latitude L���
35.41146°-80.94761 °
Survey Elevations
•
729.58 730.23
Stick-u
Height
Above
Groun
11
0.65
January 8
_DTW-TOC
32.29
- 10, 2024
GWELEV.
697.94
Total Well
Depth
Below
Top of
Casing
68.55
Screen Interval
0.010 Slot, Sch. 4A
•
Geology in
Screen
Interval
SAP
DiameterWell
Well
2
Casing
Sch. 40 PVC
58.55
to 68.55
MW-1 D
07/20/89
35.41147'
-80.94760'
729.75
730.61
0.86
33.18
697.43
88.22
78.22
to 88.22
SAP
2
Sch. 40 PVC
MW-2A
07/21/89
35.41306°
-80.94905'
736.96
739.67
2.71
53.90
685.77
77.57
67.57
to 77.57
SAP
2
Sch. 40 PVC
MW-2D
07/20/89
35.41308'
-80.94909'
737.41
740.77
3.36
55.09
685.68
108.82
98.82
to 108.82
PWR
2
Sch. 40 PVC
MW-3
07/10/89
35.41407'
-80.95049'
724.98
728.43
3.45
57.65
670.78
73.64
63.64
to 73.64
SAP
2
Sch. 40 PVC
MW-3D
07/10/89
35.41407'
-80.95050'
724.98
728.39
1 3.41
57.62
670.77
90.19
80.19
to 90.19
PWR
2
Sch. 40 PVC
MW-313R
10/13/20
35.41395'
-080.95069°
732.94
735.94
3.00
64.99
670.95
133.93
128.93
to 133.93
PWR
2
Sch. 40 PVC
MW-4
07/06/89
35.41349'
-80.95115'
738.40
741.13
2.73
68.80
672.33
74.15
64.15
to 74.15
SAP
2
Sch. 40 PVC
MW-4D
07/06/89
35.41348'
-80.95117'
738.25
740.58
2.33
67.64
672.94
102.24
92.24
to 102.24
SAP/PWR
2
Sch. 40 PVC
MW-4R
12/04/13
35.41341 °
-80.95161 °
711.15
713.87
2.72
41.80
672.07
45.73
30.73
to 45.73
SAP
2
Sch. 40 PVC
MW-413R
10/16/20
35.41348'
-80.95113
739.09
741.97
2.88
71.34
670.63
179.08
174.08
to 179.08
PWR
2
Sch. 40 PVC
MW-4DR
12/04/13
35.41340'
-80.95162'
711.15
1 713.75
2.60
40.96
672.79
90.40
75.40
to 90.40
SAP
2
Sch. 40 PVC
MW-413RR
10/13/20
35.41343°
-80.95161'
710.82
713.94
3.12
51.80
662.14
156.56
151.56
to 156.56
PWR
2
Sch. 40 PVC
MW-11
12/15/04
35.41138'
-80.95050'
720.10
722.60
2.50
30.35
692.25
38.45
23.45
to 38.45
SAP
2
Sch. 40 PVC
MW-11 D
12/15/04
35.41139°
-80.95047'
720.84
723.14
2.30
31.00
692.14
101.55
91.55
to 101.55
SAP
2
Sch. 40 PVC
MW-11 BR
10/28/20
35.41146°
-80.95042'
723.65
726.66
3.01
36.28
690.38
1 205.13
200.13
to 205.13
PWR
2
Sch. 40 PVC
MW-12
12/15/04
35.41100'
-80.94917'
722.21
724.81
1 2.60
4.09
720.72
29.49
14.49
to 29.49
SAP
2
Sch. 40 PVC
MW-12D
12/15/04
35.41101'
-80.94921'
722.21
1 724.77
2.56
28.55
696.22
68.42
58.42
to 68.42
PWR
2
Sch. 40 PVC
MW-13D
09/22/20
35.41390'
-80.95136'
712.40
715.36
2.96
46.02
669.34
95.00
85.00
to 95.00
PWR
2
Sch. 40 PVC
MW-13BR
10/12/20
35.41387'
-80.95136'
711.49
1 714.40
2.91
50.97
663.43
164.45
159.45
to 164.45
PWR
2
Sch. 40 PVC
Notes.
(1)
0.010 Slot
0.010-Inch Machine -Slotted Pipe
(2)
DTW
Depth to Water
(3)
Ground
Ground Surface
(4)
GW ELEV.
Groundwater Elevation
(5)
PVC
Polyvinyl Chloride
(6)
PWR
Partially Weathered Rock
(7)
TOC
Top of Casing
(8)
SAP
Saprolite
(9)
Sch. 40
Schedule 40 Pipe
(10) Total well depths from 2015 and 2020 well depth confirmations
(11) Elevations based on NAVD88 vertical datum.
(12) Horizontal coordinates based on NAD83 datum.
(13) Top of casing and ground surface elevations from 2015 re -survey by Providence Land Group and
2020 survey by Wood.

Table 2: Groundwater Flow Velocities
Landfill No. 1 (Unlined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
S&ME Project No: 23350793, Ph.775A
Notes•
(1) Hydraulic gradient calculated by measuring linear distance through monitoring wells (generally perpendicular) from selected
groundwater contours.
(2) Hydraulic gradients and groundwater velocities are approximate.
(3) Hydraulic Conductivity and effective porosity are mean values for soil/saprolite taken from "Groundwater Protection Initiative Site
Characterization Report" for McGuire Nuclear Station dated June 30, 2008 by S&ME, Inc.
(4) Seepage velocity equation used to calculate groundwater flow velocity v = (K*i)/ne

Table 3: Field Data Parameters
Landfill No. 1 (Unlined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
S&ME Project No: 23350793, Ph.775A
s
Well ID
MW-1
Date
1/8/2024
Well
Depth
Below
68.55
Depth to
Water
Below TOC
32.29
so
Groundwater Purge
Elevation ppearance Odor
Method
697.94 Normal None LF
Average
Pump Rate
400
i
Well
Volume
..
5.91
EVAC
Volume
..
3.70
EVAC
No
Temperature Specific
Conductivity
15.40 105
PH
6.21
TurbidityORP
6.1
231
Dissolved
Oxygen
0.54
MW-1 D
1/8/2024
88.22
33.18
697.43
Normal
None
LF
360
8.98
4.15
No
15.13
97
6.24
9.1
237
0.75
MW-2A
1/8/2024
77.57
53.90
685.77
Normal
None
LF
280
3.86
2.45
No
15.75
160
6.44
2.5
430
2.97
MW-21D
1/8/2024
108.82
55.09
685.68
Normal
None
EOP
360
8.76
0.75
No
15.44
57
6.46
7.7
410
6.47
MW-3
1/10/2024
73.64
57.65
670.78
Normal
None
LF
300
2.61
2.00
No
15.53
106
6.32
2.1
436
5.31
MW-31D
1/10/2024
90.19
57.62
670.77
Normal
None
LF
360
5.31
2.10
No
15.24
157
6.61
1.9
275
0.79
MW-3BR
1/8/2024
133.93
64.99
670.95
Normal
None
LF
200
11.24
1.15
No
11.38
209
7.57
2.8
90
1.36
MW-4
1/8/2024
74.15
68.80
672.33
Normal
None
EOP
200
0.87
0.55
No
14.62
119
6.01
0.8
284
1.14
MW-41D
1/8/2024
102.24
67.64
672.94
Normal
None
LF
150
5.64
0.85
No
14.67
238
6.63
1.2
123
1.55
MW-4R
1/8/2024
45.73
41.80
672.07
Normal
None
LF
200.00
0.64
1.05
No
13.35
106
6.47
0.6
248
3.44
MW-4BR
1/8/2024
179.08
71.34
670.63
Normal
None
LF
100
17.57
2.45
No
16.34
252
10.25
1.0
136
1.32
MW-4DR
1/8/2024
90.40
40.96
672.79
Normal
None
LF
200
8.06
0.85
No
10.88
115
7.66
0.4
238
4.07
MW-4BRR
1/8/2024
156.56
51.80
662.14
Normal
None
LF
150
17.09
3.25
No
13.32
3,701
11.99
1.4
-3
2.31
MW-11
1/10/20241
38.45
30.35
692.25
Normal
None
EOP
360.00
1.32
0.35
No
14.28
30
5.68
9.7
403
1.81
MW-11 D
1/10/2024
101.55
31.00
692.14
Normal
None
LF
500
11.51
8.20
No
14.26
27
5.96
37.6
449
5.71
MW-11 BR
1/10/2024
205.13
36.28
690.38
Normal
None
LF
200
27.54
2.35
No
14.41
117
8.42
4.6
313
2.93
MW-12
1/10/2024
29.49
4.09
720.72
Normal
None
LF
200
4.14
4.25
No
12.43
17
5.34
23.9
473
9.10
MW-12D
1/10/2024
68.42
28.55
696.22
Normal
None
LF
210
6.50
1.85
No
14.41
83
6.41
5.9
418
6.09
MW-13D
1/8/2024
95.00
46.02
669.34
Normal
None
LF
400
7.99
2.65
No
15.76
88
6.69
2.1
362
7.50
MW-13BR
1/8/2024
164.45
50.97
663.43
Normal
None
LF
100
18.51
0.45
No
16.83
163
8.22
0.9
82
0.59
SW-1
1/8/2024
NA
NA
NA
Normal
None
SWS
NA
NA
NA
NA
11.82
73
6.65
35.7
344
8.83
Notes:
(1)
°C
degrees Celsius
(2)
ft
feet
(3)
gal
gallons
(4)
µu/cm
micromhos per centimeter
(5)
mg/L
milligrams per liter
(6)
mL/min
milliliters per minute
(7)
mV-NHE
millivolts - normal hydrogen electrode
(8)
NA
not applicable
(9)
NTU
nephelometric turbidity unit
(10)
SU
standard units
(11)
TOC
top of casing
(12) Elevations based on NAVD88 vertical datum
(13) Purge methods: LF = Low Flow (average pump rate applicable to LF purging only); EOP = Equipment Only Purge; SWS = Surface Water Sample.
(14) EVAC indicates whether the water level in the well was drawn down to the level of the pump during purging and also the total amount purged from the well.
(15) Field sampling performed by Duke Energy Groundwater Science Group.

Table 4: Groundwater Field and Analytical Results
Landfill No. 1 (Unlined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
S&ME Project No: 23350793, Ph.775A
WTI
9
Field pH
SU
6.21
6.24
6.44
6.46
6.32
6.61
7.57
6.01
6.63
10.25
6.47
7.66
11.99
5.68 5.96 8.42 5.34 6.41 6.69 8.22
- - - NE
6.5 - 8.5
6.5 - 8.5*
Specific Conductance
µz5/cm
105
97
160
57
106
157
209
119
238
252
106
115
3,701
30 27 117 17 83 88 163
- - - NE
NE
NE
Temperature
°C
15
15
16
15
16
15
11
15
15
16
13
11
13
14 14 14 12 14 16 17
- -- NE
NE
NE
K41•
.6•
.1•
1,1-Dichloroethane
pg/L
0.40 U
0.40 U
0.37 J
0A0 U
0.40 U
0.38 J
1.20
0.40 U
0.40 U
0.78 J
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40
NE
6
NE
cis-1,2,-Dichloroethylene
µg/L
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
5.20
6.20
0.40 U
38.6
12.1
0.40 U
1.9
1.0
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
5.1
0.40
NE
70
NE
Acetone
µg/L
5.0U
5.0U
5.0U
5.0U
5.0U
5.0U
5.0U
5.0U
5.0U
5.0U
5.0U
5.0U
65.0
5.0U
5.0U
5.0U
5.0U
5.0U
5.0U
5.0U
5.0
NE
6,000
NE
Benzene
µg/L
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.53 J
0.40 U
0.40 U
0.81 J
0.94 J
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40
NE
1
NE
Carbon Disulfide
µg/L
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
12.8
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40
NE
700
NE
Methylene Chloride
µg/L
0.40 U
0.40 U
0.40
0.40 U
6.10
16.90
0.40 U
5.5
11.4
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
3.0 J
0.40
NE
5
NE
Tetrachloroethylene
µg/L
0.40 U
0.40 U
0.40
0.40 U
0.51 J
0.69 J
1.6
0.99 J
0.41 J
0.97 J
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.45 J
0.40
NE
0.7
NE
Toluene
µg/L
0.40 U
0.40 U
0.40
0.40 U
0.40 U
0.40 U
0.40 U
0.27 J
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40
NE
600
NE
Trichloroethylene
µg/L
0.40 U
0.40 U
0.40
tO.40
0.40 U
1.50
1.90
0.40 U
5.5
2.1
0.74 J
0.74 J
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
1.20
0.40
NE
3
NE
Vinyl Chloride
µg/L
0.40 U
0.40 U
0.40
0.40 U
0.40 U
0.40 U
0.40 U
0.78 J
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40
NE
0.03
NE
Xylenes (total)
1111
µg/L
da
040 U
040 U
040
0.40 U
4.80
101
0.40 U
25.8
49.3
Method
0.40 U
EPA •.
0.40 U
0.65 J
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
0.40 U
43.1
0.40
NE
500
NE
Mercury
Ng/L
0.01 U
0.01 U
0.01 U
0.01 U
0.01 U
0.01 U
0.01 U 0.01 U 0.01 U
0.01 Ug067,000
U
0.02 J
0.01 U
0.01 U 0.01 U 0.01 U
0.01 U 0.01 U 0.01 U 0.01
NE
1 NE
Alkalinity (CaCO3) µg/L 47,000 42,000 79,000 1700 U 53,000 79,000 110,000 82,000 140,000
1 00,000
600,000 8,320 10,300 51,000 1700 U 36,000 42,000 87,000 1700 NE NE NE
Chloride
µg/L
2,700 2,300 1,400
1,200
1,400 1,700
2,000
1,500
1,800
2,6000
32,000
2,400 1,300
1,500 3,100 3,900
1,400
3,200
15.4
NE 250,000
250,000*
Sulfate
Arsenic
pg/L
µg/L
430 440 780
0.124 J 0.212 J 0.111 U
340
0.111 U
660 1,100
1WT
0.111 U 0.117 J
2,700
0.540 J
750
Total
0.111 U
290
Recoverable
0.211 J
14,000
Metals
0.311 J
Method SW
0.111 U
i is
0.111 U
910,000
4.19
710 480
0.122 J 0.111 U
2,500 1 830 1 42.8 U
0.189 J 0.225 J 0.111 U
300
0.120 J
6,700
0.115 J
42.8
0.111
NE 250,000
NE 10
250,000*
10
Cadmium
µg/L 0.032 U
0.032 U
0.034 J
0.032 U
0.037 J
0.032 U
0.032 U
0.519 J
0.039 J
0.032 U
0.032 U
0.032 U
0.032 U
0.036 J
0.032 U
0.032 U
0.032 U
0.032 U
0.076 J
0.064 J
0.032
NE
2
5
Chromium
µg/L 0.22 J
0.185 U
0.546 J
1.09
0.374 J
0.185 U
0.236 J
0.185 U
0.185 U
0.620 J
0.646 J
1.35
0.186 J
0.305 J
0.580 J
0.789 J
0.716 J
0.308 J
0.505 J
0.185 U
0.185
NE
10
100
Lead
µg/L 0.037 U
0.04 J
1.28
0.152 J
8.02
0.037 U
0.056 J
0.037 U
0.075 J
0.037 U
0.095 J
0.044 J
0.038 J
0.103 J
0.232 J
0.037 U
0.438 J
0.045 J
0.073 J
0.119 J
0.037
NE
15
15
Selenium
µg/L 0.193 U
0.193 U
0.193 U
0.193 U
0.193 U
0.193 U
0.193 U
0.193 U
0.193 U
0.193 U
0.193 U
0.193 U
0.332 J
0.193 U
0.193 U
0.193 U
0.193 U
0.193 U
0.193 U
0.193 U
0.193
NE
20
50
Silver
µg/L 0,035 U
0.035 U
0.035 U
0,035 U
0.035 U
0,035 U
0.035 U
0.035 U
0.035 U
0.035 U
0.035 U
0.035 U
0.035 U
0.035 U
0,035 U
0.035 U
0.035 U
0.035 U
0.035 U
0.035 U
0.035
NE
20
100*
Barium µg/L 229 112
58 15 59
41
89 89
59
18
11
15
75
18 28 9
9
11
17
2 J 2 NE 700 2,000
Calcium
µg/L
7,350
7,890
20,400
5,320
11,500
19,500
28,900
15,200
28,900
9,050
11,500
16,900
2,210
967
1,970
8,290
721
10,300
9,820
27,000
12
NE
NE
NE
Magnesium
µg/L
3,310
2,690
5,450
1,550
4,560
6,210
6,710
13,800
15,600
1,780
9,010
5,050
10.1
751
1,390
2,190
414
1,520
3,650
5,430
8
NE
NE
NE
Potassium
µg/L
1,250
1,180
1,690
348
3,130
1,130
8,020
690
822
34,700
286
758
218,000
118
334
3,380
354
301
584
2,460
31
NE
NE
NE
Sodium
µg/L
6,030
6,540
8,290
5,190
5,420
7,800
11,600
2,330
3,970
38,900
2,730
7,150
646,000
3,550
3,140
12,300
1,440
7,310
5,050
8,670
17
NE
NE
NE
Notes:
(1) Samples were collected by Duke Energy Groundwater Sciences Group.
(2) MDL refers to the laboratory Method Detection Limit.
(3) SWS Groundwater Protection Standard (GWPS) refers to the North Carolina Groundwater Protected Standards calculated by North Carolina Department of Environmental Quality (NCDEQ), Solid Waste Section (SWS) for constituents with no established 15A NCAC 2L Standard (last amended on October 15, 2018).
(4) 15A NCAC 2L Standard refers to Class GA Standards as found in 15A NCAC 02L .0202 Groundwater Quality Standards (last amended on April 1, 2022).
(5) Federal Maximum Contaminant Level (MCL) as found in National Primary Drinking Water Regulations, 40 CFR, Subpart G, §141.62.
(6) * Concentration listed is a secondary MCL (MCL) as found in National Secondary Drinking Water Regulations, 40 CFR, Subpart A, §143.3.
(7) NE = Not Established.
(8) Yellow highlighted cells indicate concentrations equal to or greater than the 15A NCAC 2L Standard (for pH yellow highlighting indicates a measurement outside the 15A NCAC 2L range).
(9) Bolded values indicate concentrations equal to or greater than the Federal MCL (for PH bolded values indicate a measurement outside of the Federal MCL range).
(10) J = estimated concentrations which are greater than the MDL but are less than the laboratory Method Reporting Limit (MRL).
(11) U = constituent detected at or below the laboratory MDL.
(12) Sulfate concentrations at MW-4BR and MW-4BRR were analyzed at dilution.
(13) Chloride concentrations at MW-4, MW-4D, MW-4BR, and MW-4BRR were analyzed at dilution.
(14) Potassium concentrations at MW-4BR and MW-4BRR were analyzed at dilution.
(15) Sodium concentrations at MW-4BRR were analyzed at dilution.
(16) SU = Standard Units.
(17) µU/cm = micromhos per centimeter.
(18) °C = degrees Celsius.
(19) µg/L = micrograms per liter.

Table 5: Results that Equal or Exceed 15A NCAC 2L Groundwater Standards
Landfill No. 1 (Unlined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
S&ME Project No: 23350793, Ph.775A
Field pH
MW-1
6.21
SU
6.5 - 8.5
5.88 - 7.00
pH in MW-1 is consistent with the historical concentration range at monitoring well.
MW-1 D
6.24
5.90 - 7.00
pH in MW-1 D is consistent with the historical concentration range at monitoring well.
MW-2A
6.44
6.12 - 6.50
pH in MW-2A is consistent with the historical concentration range at monitoring well.
MW-2D
6.46
6.20 - 7.60
pH in MW-2D is consistent with the historical concentration range at monitoring well.
MW-3
6.32
5.70 - 7.50
pH in MW-3 is consistent with historical concentration range at monitoring well.
MW-4
6.01
5.30 - 8.10
pH in MW- 4 is consistent with historical concentration range at monitoring well.
MW-4R
6.47
5.90 - 6.88
pH in MW-4R is consistent with historical concentration range at monitoring well.
MW-4BR
10.25
8.75 - 10.46
pH in MW-4BR is consistent with historical concentration range at monitoring well.
MW-4BRR
11.99
11.29 - 12.28
pH in MW-4BRR is consistent with historical concentration range at monitoring well.
MW-11
5.68
5.13 - 8.10
pH in MW-11 is consistent with historical concentration range at monitoring well.
MW-11 D
5.96
5.48 - 5.73
pH in MW-11 D is higher than the historical concentration range at monitoring well.
MW-12
5.34
4.71 -5.5
H in MW-12 is consistent with historical concentration range at monitoring well.
MW-12D
6.41
6.00 - 6.35
H in MW 12D is higher than the historical concentration range at monitoring well.
Methylene Chloride
MW-3D
6.10
Ng/L
5
1.00 - 6.45
Methylene Chloride in MW-3D is consistent with historical concentration range at monitoring well.
MW-3BR
16.90
pg/L
8.8 - 11
Methylene Chloride in MW-3BR is higher than historical concentration range at monitoring well.
MW-4D
5.5
Ng/L
0.53 - 9.53
Methylene Chloride in MW-4D is consistent with historical concentration range at monitoring well.
MW-4BR
11.4
ug/L
4.5 - 8.1
Methylene Chloride in MW-4BR is higher than historical concentration range at monitoring well.
Tetrachloroethylene
MW-4
1.6
pg/L
0.7
0.88 - 2.5
Tetrachloroethylene in MW-4 is consistent with historical concentration range at monitoring well.
MW-4D
0.99 J
pg/L
0.52 - 2.0
Tetrachloroethylene in MW-4D is consistent with historical concentration range at monitoring well.
MW-4R
0.97 J
pg/L
0.38 - 1.10
Tetrachloroethylene in MW-4R is consistent with historical concentration range at monitoring well.
Trichloroethene
MW-4D
5.5
pg/L
1 3
1 0.58 - 5.88
ITrichloroethene in MW-4D is consistent with historical concentration range at monitoring well.
Sulfate
MW-4BRR
910,000
ug/L
250,000
1 710,000 - 1,400,000
JSulfate in MW-4BRR is consistent with historical concentration range at monitoring well
Vinvl Chloride
MW-4D
0.78 J
ua/L
0.03
1 0.45 - 0.9
IVinvl Chloride in MW-4D is consistent with historical concentration ranae at monitorina well.
Notes:
(1) 15A NCAC 2L Standard refers to Class GA Standards as found in 15A NCAC 02L .0202 Groundwater Quality Standards (last amended on April 1, 2022).
(2) Historical Concentration Range based on data in Duke Energy Carolinas, LLC (Duke Energy) analytical results database.
(3) SU = Standard units.
(4) pg/L = micrograms per liter.

Table 6: Surface Water Field and Analytical Results
Landfill No. 1 (Unlined) Permit No. 6004-INDUS _
Duke Energy Carolinas McGuire Nuclear Station III S
S&ME Project No: 23350793, Ph.775A
Parameter
Field pH
Units
SU
January 8, 2024
SW_ I
6.65
MDL 15A
- - -
NCAC 2B
Standard
6.0 - 9.0
Federal MC
6.5 - 8.5*
Specific Conductance
µu/cm
73
- - -
NE
NE
Dissolved Oxygen
mg/L
8.83
- - -
> 4.0
NE
Temperature
°C
11.82
-
32
NE
Volatile Organic Compounds were not detected during the January 2024 Sampling Event
2 4-111
Alkalinity (CaCO3)
µg/L
32,000
1,700
NE
NE
Chloride
µg/L
2,500
15.4
250,000
250,000*
Sulfate
µg/L 2,200 42.8
-Mercury Method EPA 7470A'
Mercury was not detected during the January 2024 Sampling Event
250,000
250,000*
Arsenic
��otal Recoverable
Metals
µg/L
Method SW i 0:
0.129 J 0.111
10
10
Chromium
µg/L
0.487 J
0.185
183A
100
Lead
µg/L
0.222 J
0.037
14A
15
Lead, dissolved
Recoverable
µg/L
Metals
0.186 J
MethodTotal SW .0
0.037
0.
0.54^
15
Barium
µg/L
27
2
1,000
2,000
Calcium
µg/L
7,820
12
NE
NE
Magnesium
µg/L
3,290
8
NE
NE
Potassium
µg/L
1,120
31
NE
NE
Sodium
µ /L
4,480
17
NE
NE
Notes:
(1) Samples were collected by Duke Energy Groundwater Sciences Group.
(2) MDL refers to the laboratory Method Detection Limit.
(3) 15A NCAC 2B Standard (last amended on September 1, 2022) refers to 15A NCAC 02B 0.0211 Fresh Surface Water Quality
Standards for Class C Waters, and 15A NCAC 02B 0.0216 - Fresh Surface Water Quality Standards for Class WS-IV Waters.
(4) Federal Maximum Contaminant Level (MCL) as found in National Primary Drinking Water Regulations, 40 CFR, Subpart G,
§ 141.62.
(5) * Concentration listed is a secondary MCL (MCL) as found in National Secondary Drinking Water Regulations, 40 CFR, Subpart
A, §143.3.
(6) ^ = Hardness -dependent 15A NCAC 2B Standards derived using equations specified in the 15 NCAC 02B Standards Table (last
amended on July 26, 2021). The values shown rely upon an assumed in -stream default hardness of 25 milligrams per liter (mg/L)
for the chronic standard. An exceedance of the criterion shown does not establish that an in -stream exceedance has occurred.
(7) NE = Not Established.
(8) J = estimated concentrations which are greater than the MDL but are less than the laboratory Method Reporting Limit (MRL).
(9) U = constituent detected at or below the laboratory MDL.
(10) SU = Standard Units.
(11) µU/cm = micromhos per centimeter.
(12) °C = degrees Celsius.
(13) µg/L = micrograms per liter.

Table 7: Radiological Analytical Results
Landfill No. 1 (Unlined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
S&ME Project No: 23350793, Ph.775A
0
III
Radiological Data
Measured in
icocuries per
Liter (pCi/Q
-law
-!Armrw-
< 4.65E-01
1 D
< 4.66E-01
MW-2A
< 4.66E-01
MW-2D
< 4.96E-01
MW-3
< 4.97E-01
< 4.97E-01
< 5.00E-01
< 4.97E-01
MW-4D
k-
< 4.97E-01
<
January
MW-4BR
5.10E-01
8 - 10, 2024
MW-4RJ[MW-4DR
< 4.96E-01
< 4.97E-01
MW-4BRR
1.97E+00
M
M
< 4.64E-01
MW-11D
< 4.65E-01
MW-11BR
< 4.67E-01
I
MW-
A
< 4.65E-01
W-12D
LM
< 4.65E-01
<
MW-13D
4.66E-01
MW-13BR
<
4.66E-01
I
Sw4d
< 4.96E-01
Alpha
Ba-La-140
< 9.07E+00
< 1.18E+01
< 5.46E+00
< 1.30E+01
< 7.27E+00
< 9.95E+00
< 6.24E+00
< 1.08E+01
< 9.79E+00
<
1.30E+01
< 8.43E+00
< 1.05E+01
< 9.53E+00
< 1.17E+01
< 9.75E+00
< 6.76E+00
< 1.00E+01
< 9.63E+00
<
9.90E+00
<
7.52E+00
< 1.29E+01
Be-7
< 4.89E+01
< 5.45E+01
< 4.79E+01
< 5.02E+01
< 4.62E+01
< 4.09E+01
< 3.53E+01
< 5.90E+01
< 3.94E+01
<
4.81E+01
< 4.99E+01
< 5.53E+01
< 5.02E+01
< 4.99E+01
< 4.42E+01
< 5.29E+01
< 5.19E+01
< 4.65E+01
<
4.67E+01
<
5.21E+01
< 5.47E+01
Beta
< 3.21 E+00
< 3.21 E+00
< 3.21 E+00
< 3.18E+00
< 3.18E+00
< 3.18E+00
7.15E+00
< 3.18E+00
< 3.18E+00
2.65E+01
< 3.18E+00
< 3.18E+00
1.33E+02
< 3.21 E+00
< 3.21 E+00
3.47E+00
< 3.21 E+00
< 3.21 E+00
<
3.21 E+00
<
3.21 E+00
< 3.18E+00
Co-58
< 5.88E+00
< 6.23E+00
< 5.66E+00
< 5.45E+00
< 5.68E+00
< 5.88E+00
< 6.32E+00
< 5.92E+00
< 5.46E+00
<1
6.24E+00
< 5.78E+00
< 7.26E+00
< 6.13E+00
< 6.67E+00
< 6.00E+00
< 7.35E+00
< 5.38E+00
< 5.89E+00
<
6.83E+00
<
4.67E+00
< 7.46E+00
CO-60
< 5.66E+00
< 6.05E+00
< 7.60E+00
< 6.70E+00
< 6.54E+00
< 7.50E+00
< 5.79E+00
< 6.17E+00
< 6.41E+00
<
8.13E+00
< 8.22E+00
< 8.28E+00
< 8.33E+00
< 7.48E+00
< 7.89E+00
< 7.88E+00
< 7.01E+00
< 6.74E+00
<
I 5.95E+00
<
6.26E+00
< 5.91E+00
Cs-134
< 7.54E+00
< 8.21 E+00
< 6.65E+00
< 5.82E+00
< 6.40E+00
< 8.34E+00
< 7.43E+00
< 7.61 E+00
< 7.02E+00
<
7.98E+00
< 7.84E+00
< 8.02E+00
< 6.42E+00
< 6.75E+00
< 5.70E+00
< 8.30E+00
< 7.19E+00
< 7.32E+00
<
5.76E+00
<
6.67E+00
< 8.30E+00
Cs-137
< 5.63E+00
< 5.77E+00
< 5.40E+00
< 6.33E+00
< 6.86E+00
< 5.75E+00
< 4.45E+00
< 5.28E+00
< 5.03E+00
<
6.38E+00
< 7.23E+00
< 5.66E+00
< 7.21E+00
< 6.88E+00
< 6.26E+00
< 6.92E+00
< 7.01E+00
< 4.60E+00
<
5.91E+00
<
5.12E+00
< 6.44E+00
Fe-59
< 1.32E+01
< 1.24E+01
< 1.56E+01
< 1.42E+01
< 1.10E+01
< 1.20E+01
< 1.19E+01
< 9.32E+00
< 9.90E+00
<
1.49E+01
< 1.18E+01
< 1.62E+01
< 1.18E+01
< 1.38E+01
< 1.21E+01
< 1.40E+01
< 1.02E+01
< 6.96E+00
<
1.18E+01
<
1.22E+01
< 9.50E+00
1-131
< 1.12E+01
< 1.23E+01
< 1.02E+01
< 1.19E+01
< 8.58E+00
< 9.19E+00
< 9.51E+00
< 1.26E+01
< 1.30E+01
<
1.28E+01
< 9.49E+00
< 1.10E+01
< 1.07E+01
< 9.63E+00
< 9.07E+00
< 1.03E+01
< 8.81E+00
< 8.56E+00
<
1.03E+01
<
1.16E+01
< 9.92E+00
K-40
1.38E+02
2.74E+02
1.84E+02
1.30E+02
< 1.25E+02
1.44E+02
1.56E+02
< 1.18E+02
< 1.10E+02
2.75E+02
1.28E+02
1.34E+02
2.58E+02
1.74E+02
1.80E+02
1.77E+02
1.33E+02
< 1.27E+02
<
I 1.30E+02
I
9.05E+01
1.52E+02
Mn-54
< 5.73E+00
< 7.81E+00
< 5.79E+00
< 5.43E+00
< 5.91E+00
< 5.92E+00
< 6.79E+00
< 6.52E+00
< 6.46E+00
<
6.59E+00
< 5.41E+00
< 7.18E+00
< 6.93E+00
< 6.27E+00
< 6.05E+00
< 7.42E+00
< 5.98E+00
< 6.73E+00
<
5.42E+00
<
6.38E+00
< 6.83E+00
Nb-95
< 6.91E+00
< 8.26E+00
< 6.80E+00
< 8.85E+00
< 5.95E+00
< 7.90E+00
< 6.22E+00
< 5.70E+00
< 6.64E+00
<
7.11E+00
< 7.64E+00
< 7.73E+00
< 7.39E+00
< 6.97E+00
< 6.52E+00
< 9.20E+00
< 6.45E+00
< 5.72E+00
<
7.46E+00
<
5.42E+00
< 6.71E+00
Tritium (H3GW)
< 4.79E+01
< -7.22E+01
< 3.99E+01
< 2.65E+00
< -5.50E+01
< -1.20E+02
< 3.10E+01
< -7.40E+01
< -1.10E+02
<
-7.40E+01
< -5.50E+01
I < -8.10E+01
< -1.20E+02
< 1.60E+01
< 6.65E+01
< 2.41E+01
< 4.26E+01
< 2.93E+01
<
5.61E+01
<
-2.10E+01
< -4.30E+01
Zn-65
< 1.28E+01
< 1.28E+01
< 1.41E+01
< 1.60E+01
< 1.10E+01
< 9.99E+00
I < 8.73E+00
< 1.33E+01
< 1.08E+01
I <
1.49E+01
< 1.30E+01
< 1.68E+01
< 1.25E+01
< 1.33E+01
< 1.21E+01
< 1.65E+01
< 1.24E+01
< 1.50E+01
<
1.29E+01
<
9.52E+00
< 1.35E+01
Zr-95
< 1.23E+01
< 1.25E+01
< 9.89E+00
< 1.17E+01
< 8.78E+00
< 1.13E+01
I < 1.01E+01
< 7.49E+00
< 1.12E+01
I <
1.23E+01
< 1.04E+01
< 1.31E+01
< 1.36E+01
< 1.27E+01
< 1.29E+01
< 1.23E+01
< 9.85E+00
< 8.50E+00
I <
1.23E+01
I <
6.96E+00
< 1.33E+01
Notes:
(1) pCi/L = picocuries per liter
(2) < = less than

Appendix III - Field Sampling Forms

FIELD SAMPLING CALIBRATION FORM
STUDY:
MCGUIRE NUCLEAR STATION - NUCLEAR LANDFILL 1 GROUNDWATER MONITORING
PROGRAM
DATE (s):
January 8 and 10, 2024
SURFACE UNIT READER: EHS
COLLECTORS: EHS
SURFACE UNIT SERIAL #: 950
ANALYZER MODEL#: ST MP
ANALYZER SERIAL #: 877813
OTHER EQUIPMENT: TURBIDIMETER NO.3 - WR-00070
WEATHER CONDITIONS:
30s-50s, partly cloudy
EHS 1/11/24
HYDROLAB PROCEDURE #:
3210.7
VALIDATED BY:
Calibration Date / Time
DATE: 8-Jan-24
TIME: 7:15
DATE: 10-Jan-24
TIME: 5:45
CALIBRATION BP (mmHg)
725.18
CALIBRATION BP (mmHg)
727.65
Calibation
Instrument
Standard
Instrument
Standard
Parameter
Calibration Results
Calibration Results
Standard
Value
Value
Value
Value
SS
0.0 -►
0.0
INSTRUMENT ZEROED
0.0 -/-►
0.0
INSTRUMENT ZEROED
SPEC. COND.
SS
734.2 -►
720
CALIBRATION ACCEPTED
731.2 -/-►
720
CALIBRATION ACCEPTED
(US/cm)
SS
229.7 -/-►
227
1 CALIBRATION ACCEPTED
227.7 -/-►
227
1 CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
SS
-/-►
1410
-/-►
1410
CHECK (uS/cm)
SS
B (7.00)
7.09 -►
7.04
CALIBRATION ACCEPTED
7.05 -/-►
7.02
CALIBRATION ACCEPTED
pH
B (4.00)
4.04 -►
3.99
CALIBRATION ACCEPTED
4.05 -/-►
4.00
CALIBRATION ACCEPTED
(units)
B (10.00)
10.18 -/-►
10.09
CALIBRATION ACCEPTED
10.13 -/-►
10.07
CALIBRATION ACCEPTED
Buffer Temp.
17.24
Buffer Temp.
18.69
pH Check
B (7.00)
-►
Buffer Temp.
7.13
0.00
Time:
El
442 -►
446
CALIBRATION ACCEPTED
441 -/-►
445
CALIBRATION ACCEPTED
ORP
N/A -/-►
N/A
N/A -/-►
N/A
Zobell's
ORP Temp.
17.89
ORP Temp.
18.34
0
TEMP (Co)
20.12
19.34
BP (mmHg)
725.18
727.65
COND
0.00
0.00
DO
100 % mg/L
8.71 -►
8.65
CALIBRATION ACCEPTED
8.90 -/-►
8.81
CALIBRATION ACCEPTED
(mg/L)
After Cal
8.68
100.40
After Cal % SAT
8.88
100.77
After Cal % SAT
LCS
8.68
100.40
CALIBRATION PASS
8.88
100.77
CALIBRATION PASS
LCSD
8.68
0.00
CALIBRATION PASS
8.88
0.00
CALIBRATION PASS
0 TURB
(ntu)
SS
10.1 -/-►
10.0
CALIBRATION ACCEPTED
10.0 -/-►
10.0
CALIBRATION ACCEPTED
Temp Cert Device #
TEMP
NISI
N/A -/-►
N/A
Adjustment Not Available
N/A -/-►
N/A
Adjustment Not Available
(deg C)
INSTRUMENT MAINTENANCE
DATE / TIME
Conductance Subsystem
pH Subsystem
❑
Cleaned Electrodes
❑ Cleaned Electrodes
❑
Tested - OK
❑ Replaced ref Electrode KCL
❑
See Notes
❑ Replaced Ref. Electrode Tip
❑ Tested - OK
❑ See Notes
Oxidation Reduction Subsystem
Temperature Subsystem
❑
Cleaned Electrode
❑ Cleaned Electrode
❑
Tested - OK ❑
See Notes
❑ Tested - OK ❑
See Notes
Dissolved Oxygen Subsystem
❑
Replaced Teflon Membrane
❑ Cleaned Electrode
❑
Replaced DO electrolyte
❑ See Notes
Field Barometric Pressure
Beginning BP
(mmHg)
Ending BP
(mmHg)
KEY
B = Butter
= Lab ControlStandard -► _ Adjusted To
SS = Standard solution
LCSD = Lab Control Standard Duplicate -/-►= Not Adjusted To
N/A = Not Applicable
W = Winkler
BP = Barometric Pressure
AW = Average Winkler
NOTES:

FIELD SAMPLING CALIBRATION FORM
STUDY:
MCGUIRE NUCLEAR STATION - NUCLEAR LANDFILL 1 GROUNDWATER MONITORING
PROGRAM
DATE (s):
January 8 - 10, 2024
SURFACE UNIT READER: JAS
COLLECTORS:
EHS
SURFACE UNIT SERIAL #: 950
ANALYZER MODEL#:
ST MP
ANALYZER SERIAL #: 878759
OTHER EQUIPMENT:
TURBIDIMETER NO.3 - WR-00070
WEATHER CONDITIONS:
30s-50s, partly cloudy
EHS 1/11/24
HYDROLAB PROCEDURE #:
3210.7
VALIDATED BY:
Calibration Date / Time
DATE: 8-Jan-24
TIME: 8:00
DATE: 10-Jan-24
TIME: 10:00
CALIBRATION BP (mmHg)
749.67
CALIBRATION BP (mmHg)
749.11
Calibation
Instrument
Standard
Instrument
Standard
Parameter
Calibration Results
Calibration Results
Standard
Value
Value
Value
Value
SS
0.0 -►
0.0
INSTRUMENT ZEROED
0.0 -/-►
0.0
INSTRUMENT ZEROED
SPEC. COND.
SS
722.4 -►
720
CALIBRATION ACCEPTED
723.1 -/-►
720
CALIBRATION ACCEPTED
(US/cm)
SS
227.4 -/-►
227
1 CALIBRATION ACCEPTED
228.3 -/-►
227
1 CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
SS
-/-►
1410
-/-►
1410
CHECK (uS/cm)
SS
B (7.00)
7.03 -►
7.02
CALIBRATION ACCEPTED
7.00 -/-►
7.02
CALIBRATION ACCEPTED
pH
B (4.00)
4.03 -►
4.00
CALIBRATION ACCEPTED
4.01 -/-►
4.00
CALIBRATION ACCEPTED
(units)
B (10.00)
10.05 -/-►
10.06
CALIBRATION ACCEPTED
10.05 -/-►
10.07
CALIBRATION ACCEPTED
Buffer Temp.
19.72
Buffer Temp.
19.43
pH Check
B (7.00)
7.02 -►
Buffer Temp.
7.02
19.72
Calibration Accepted
Time:
F1
413 -►
441
CALIBRATION ACCEPTED
422 -/-►
441
CALIBRATION ACCEPTED
ORP
N/A -/-►
N/A
N/A -/-►
N/A
Zobell's
ORP Temp.
20.12
ORP Temp.
20.02
0
TEMP (Co)
18.43
18.32
BP (mmHg)
749.67
749.11
COND
0.00
0.00
DO
100 % mg/L
9.15 -►
9.25
CALIBRATION ACCEPTED
9.21 -►
9.27
CALIBRATION ACCEPTED
(mg/L)
After Cal
9.15
98.88
After Cal % SAT
8.90
96.03
After Cal % SAT
LCS
9.15
98.88
CALIBRATION PASS
8.90
96.03
CALIBRATION FAIL
LCSD
9.15
0.00
CALIBRATION PASS
8.90
0.00
CALIBRATION PASS
Ei TURB
(ntu)
SS
10.0 -/-►
10.0
CALIBRATION ACCEPTED
10.0 -/-►
10.0
CALIBRATION ACCEPTED
Temp Cert Device #
TEMP
NISI
N/A -/-►
N/A
Adjustment Not Available
N/A -/-►
N/A
Adjustment Not Available
(deg C)
INSTRUMENT MAINTENANCE
DATE / TIME
Conductance Subsystem
pH Subsystem
❑
Cleaned Electrodes
❑ Cleaned Electrodes
❑
Tested - OK
❑ Replaced ref Electrode KCL
❑
See Notes
❑ Replaced Ref. Electrode Tip
❑ Tested - OK
❑ See Notes
Oxidation Reduction Subsystem
Temperature Subsystem
❑
Cleaned Electrode
❑ Cleaned Electrode
❑
Tested - OK
❑
See Notes
❑ Tested - OK ❑
See Notes
Dissolved Oxygen Subsystem
❑
Replaced Teflon Membrane
❑ Cleaned Electrode
❑
Replaced DO electrolyte
❑ See Notes
Field Barometric Pressure
Beginning BP
(mmHg)
Ending BP
(mmHg)
KEY
B = Butter
= Lab ControlStandard -► _ Adjusted To
SS = Standard solution
LCSD = Lab Control Standard Duplicate -/-►= Not Adjusted To
N/A = Not Applicable
W = Winkler
BP = Barometric Pressure
AW = Average Winkler
NOTES:

FIELD SAMPLING CALIBRATION FORM
STUDY:
MCGUIRE NUCLEAR STATION - NUCLEAR LANDFILL 1 GROUNDWATER MONITORING
PROGRAM
DATE (s):
January 8 and 10, 2024
SURFACE UNIT READER: EHS
COLLECTORS: EHS
SURFACE UNIT SERIAL #: 950
ANALYZER MODEL#: ST MP
ANALYZER SERIAL #: 877813
OTHER EQUIPMENT: TURBIDIMETER NO.3 - WR-00070
WEATHER CONDITIONS:
30s-40s, overcast
EHS 1/11/24
HYDROLAB PROCEDURE #:
3210.7
VALIDATED BY:
Calibration Date / Time
DATE: I 10-Jan-24
TIME: 7:00
DATE: 10-Jan-24
TIME: 6:15
CALIBRATION BP (mmHg)
731.12
CALIBRATION BP (mmHg)
730.54
Calibation
Instrument
Standard
Instrument
Standard
Parameter
Calibration Results
Calibration Results
Standard
Value
Value
Value
Value
SS
0.0 -/-►
0.0
INSTRUMENT ZEROED
0.0 -/-►
0.0
INSTRUMENT ZEROED
SPEC. COND.
SS
727.6 -►
720
CALIBRATION ACCEPTED
724.4 -/-►
720
CALIBRATION ACCEPTED
(US/cm)
SS
1 225.5 -/-►
227
1 CALIBRATION ACCEPTED
227.8 -/-►
227
1 CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
SS
-/-►
1410
-/-►
1410
CHECK (uS/cm)
SS
B (7.00)
7.07 -►
7.02
CALIBRATION ACCEPTED
7.05 -/-►
7.02
CALIBRATION ACCEPTED
pH
B (4.00)
4.05 -►
4.00
CALIBRATION ACCEPTED
4.04 -/-►
4.00
CALIBRATION ACCEPTED
(units)
B (10.00)
10.11 -/-►
10.07
CALIBRATION ACCEPTED
10.10 -/-►
10.07
CALIBRATION ACCEPTED
Buffer Temp.
19.11
Buffer Temp.
19.24
pH Check
B (7.00)
-►
Buffer Temp.
7.13
0.00
Time:
El
439 -►
443
CALIBRATION ACCEPTED
447 -/-►
444
CALIBRATION ACCEPTED
ORP
N/A -/-►
N/A
N/A -/-►
N/A
Zobell's
ORP Temp.
19.01
ORP Temp.
18.69
0
TEMP (Co)
20.11
19.43
BP (mmHg)
731.12
730.54
COND
0.00
0.00
DO
100 % mg/L
8.70 -►
8.72
CALIBRATION ACCEPTED
8.79 -/-►
8.83
CALIBRATION ACCEPTED
(mg/L)
After Cal
8.69
99.66
After Cal % SAT
8.77
99.30
After Cal % SAT
LCS
8.69
99.66
CALIBRATION PASS
8.77
99.30
CALIBRATION PASS
LCSD
8.69
0.00
CALIBRATION PASS
8.77
0.00
CALIBRATION PASS
0 TURB
(ntu)
SS
10.0 -/-►
10.0
CALIBRATION ACCEPTED
10.1 -/-►
10.0
CALIBRATION ACCEPTED
Temp Cert Device #
TEMP
NISI
N/A -/-0-N/A
Adjustment Not Available
N/A -/-►
N/A
Adjustment Not Available
(deg C)
INSTRUMENT MAINTENANCE
DATE / TIME
Conductance Subsystem
pH Subsystem
❑
Cleaned Electrodes
❑ Cleaned Electrodes
❑
Tested - OK
❑ Replaced ref Electrode KCL
❑
See Notes
❑ Replaced Ref. Electrode Tip
❑ Tested - OK
❑ See Notes
Oxidation Reduction Subsystem
Temperature Subsystem
❑
Cleaned Electrode
❑ Cleaned Electrode
❑
Tested - OK ❑
See Notes
❑ Tested - OK ❑
See Notes
Dissolved Oxygen Subsystem
❑
Replaced Teflon Membrane
❑ Cleaned Electrode
❑
Replaced DO electrolyte
❑ See Notes
Field Barometric Pressure
Beginning BP
(mmHg)
Ending BP
(mmHg)
KEY
B = Butter
= Lab ControlStandard -► _ Adjusted To
SS = Standard solution
LCSD = Lab Control Standard Duplicate -/-►= Not Adjusted To
N/A = Not Applicable
W = Winkler
BP = Barometric Pressure
AW = Average Winkler
NOTES:

FIELD SAMPLING CALIBRATION FORM
STUDY:
MCGUIRE NUCLEAR STATION - NUCLEAR LANDFILL 1 GROUNDWATER MONITORING
PROGRAM
DATE (s):
January 8 - 10, 2024
SURFACE UNIT READER: JAS
COLLECTORS:
EHS
SURFACE UNIT SERIAL #: 950
ANALYZER MODEL#:
ST MP
ANALYZER SERIAL #: 878759
OTHER EQUIPMENT:
TURBIDIMETER NO.3 - WR-00070
WEATHER CONDITIONS:
30s-50s, overcast
EHS 1/11/24
HYDROLAB PROCEDURE #:
3210.7
VALIDATED BY:
Calibration Date / Time
DATE: I 10-Jan-24
TIME: 800
DATE: 10-Jan-24
TIME: 1700
CALIBRATION BP (mmHg)
749.10
CALIBRATION BP (mmHg)
749.32
Calibation
Instrument
Standard
Instrument
Standard
Parameter
Calibration Results
Calibration Results
Standard
Value
Value
Value
Value
SS
0.0 -/-►
0.0
INSTRUMENT ZEROED
0.0 -/-►
0.0
INSTRUMENT ZEROED
SPEC. COND.
SS
711.3 -►
720
CALIBRATION ACCEPTED
717.3 -/-►
720
CALIBRATION ACCEPTED
(US/cm)
SS
224.5 -/-►
227
1 CALIBRATION ACCEPTED
223.1 -/-►
227
CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
SS
-/-►
1410
-/-►
1410
CHECK (uS/cm)
SS
B (7.00)
7.09 -►
7.02
CALIBRATION ACCEPTED
7.08 -/-►
7.02
CALIBRATION ACCEPTED
pH
B (4.00)
4.00 -►
4.00
CALIBRATION ACCEPTED
3.99 -/-►
4.00
CALIBRATION ACCEPTED
(units)
B (10.00)
10.04 -/-►
10.06
CALIBRATION ACCEPTED
10.08 -/-►
10.06
CALIBRATION ACCEPTED
Buffer Temp.
20.14
Buffer Temp.
20.42
pH Check
B (7.00)
7.02 -►
Buffer Temp.
7.02
20.46
Calibration Accepted
Time:
2
435 -►
440
CALIBRATION ACCEPTED
431 -/-►
439
CALIBRATION ACCEPTED
ORP
N/A -/-►
N/A
N/A -/-►
N/A
Zobell's
ORP Temp.
20.23
ORP Temp.
20.89
0
TEMP (Co)
19.97
20.32
BP (mmHg)
749.10
749.32
COND
0.00
0.00
DO
100 % mg/L
8.90 -►
8.96
CALIBRATION ACCEPTED
8.87 -/-►
8.91
CALIBRATION ACCEPTED
(mg/L)
After Cal
8.90
99.28
After Cal % SAT
8.87
99.61
After Cal % SAT
LCS
8.90
99.28
CALIBRATION PASS
8.87
99.61
CALIBRATION PASS
LCSD
8.90
0.00
CALIBRATION PASS
8.87
0.00
CALIBRATION PASS
o TURB
(ntu)
SS
10.0 -/-►
10.0
CALIBRATION ACCEPTED
10.0 -/-►
10.0
CALIBRATION ACCEPTED
Temp Cert Device #
TEMP
NISI
N/A -/-►
N/A
Adjustment Not Available
N/A -/-►
N/A
Adjustment Not Available
(deg C)
INSTRUMENT MAINTENANCE
DATE / TIME
Conductance Subsystem
pH Subsystem
❑
Cleaned Electrodes
❑ Cleaned Electrodes
❑
Tested - OK
❑ Replaced ref Electrode KCL
❑
See Notes
❑ Replaced Ref. Electrode Tip
❑ Tested - OK
❑ See Notes
Oxidation Reduction Subsystem
Temperature Subsystem
❑
Cleaned Electrode
❑ Cleaned Electrode
❑
Tested - OK
❑
See Notes
❑ Tested - OK ❑
See Notes
Dissolved Oxygen Subsystem
❑
Replaced Teflon Membrane
❑ Cleaned Electrode
❑
Replaced DO electrolyte
❑ See Notes
Field Barometric Pressure
Beginning BP
(mmHg)
Ending BP
(mmHg)
KEY
B = Butter
= Lab ControlStandard -► _ Adjusted To
SS = Standard solution
LCSD = Lab Control Standard Duplicate -/-►= Not Adjusted To
N/A = Not Applicable
W = Winkler
BP = Barometric Pressure
AW = Average Winkler
NOTES:

DUKE DUKE ENERGY DUKE
ENERGY- GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) 8-Jan-2024 10-Jan-2024
WELL/LOCATION NAME
mW-1
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
730.23
MIDDLE OF WETTED SCREEN (ft toc) 63.55
WELL DEPTH (ft TOC)
68.55
GS ELEV (ft msl)
729.58
PUMP INTAKE DEPTH (ft TOC) 68.05
SCREEN LENGTH (ft)
10
ELEV REF
I NAVD 88
SCREEN INTERVAL (ft TOC) 58.55 TO 68.55
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE 1 9 (sec) I DISCHARGE 6 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL 11
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
32.29
WATER COLUMN (ft)
36.26
WATER ELEVATION (ft msl)
697.94
WELL VOLUME (gal)
5.91
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
DRIP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELLVOL
(recalculates on
current water level)
12:29
34.19
400
15.49
103
6.20
35.2
238
0.53
N/A
12:39
1 34.19
400
15.40
103
6.21
35.2
233
0.58
N/A
1:08
34.19
400
15.32
105
6.21
8.2
229
0.55
N/A
1:11
34.19
400
15.31
105
6.21
6.9
229
0.55
N/A
1:14
34.19
400
15.40
105
6.21
6.1
231
0.54
N/A
DRAW -DOWN
1.90
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
2.00
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
3.70
(gal)
1/8/2024 @ 1320
0
Samp a EHS 1/11/24 preservation verified to pH
QC By: < ?
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA O1-13 ❑BORON ❑SR 89/90 EIGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 []IODINE 131 0504,CL ❑ALPHA SPEC
OMETALS 3F_ALK ❑CO2 ❑RSK 175 OVOC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting: I NO
VVELL CAPS
Well cap in good conditon
VVELL CASING
Good Condition
4CCESS TO WELLS
Access cleared into well
PROTECTIVE CASING
Casing in good condition
FLUSH MOUNT WELLS
VVELL TAG
4CCESS AROUND WELL
VVELL SECURITY
VVELL LOCK CONDITION
Well tag in good condition
Access cleared around well
Well found locked
Lock in good condition
SAMPLING NOTES

IIIDUKE DUKE ENERGY vu�cE
ENERGY- GROUNDWATER MONITORING DATA SHEET ENERGY.
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) 8-Jan-2024 10-Jan-2024
WELL/LOCATION NAME
MW-101
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
730.61
MIDDLE OF WETTED SCREEN (ft toc) 83.22
WELL DEPTH (ft TOC)
88.22
GS ELEV (ft msl)
729.75
PUMP INTAKE DEPTH (ft TOC) 87.72
SCREEN LENGTH (ft)
10
ELEV REF
NAVD 88
F SCREEN INTERVAL (ft TOC) 78.22 TO 88.22
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE 1 42 (psi) RECHARGE 1 8 (sec) I DISCHARGE 7 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
I WELL USE
PURGE METHOD
STICK UP WELL Ell
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOG)
33.18
WATER COLUMN (ft)
55.04
WATER ELEVATION (ft msl)
697.43
WELL VOLUME (gal)
8.98
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
DRIP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELLVOL
(recalculates on
current water level)
12:43
34.94
360
15.28
97
6.24
14.3
242
3.23
N/A
12:46
1 34.94
360
15.18
97
6.25
12.0
236
1.13
N/A
12:49
34.94
360
15.09
97
6.24
10.7
238
0.84
N/A
12:52
34.94
360
15.13
97
6.24
9.3
238
0.78
N/A
12:55
34.94
360
15.13
97
6.24
9.1
237
0.75
N/A
DRAW -DOWN
1.76
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
3.00
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
4.15
(gal)
1/8/2024 @ 1300
0
Samp a EHS 1/11/24 preservation verified to pH
QC By: < ?
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA O1-13 ❑BORON ❑SR 89/90 EIGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 []IODINE 131 0504,CL ❑ALPHA SPEC
OMETALS 3F_ALK ❑CO2 ❑RSK 175 OVOC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting: I NO
VVELL CAPS
Well cap in good conditon
VVELL CASING
Good Condition
4CCESS TO WELLS
Access cleared into well
PROTECTIVE CASING
Casing in good condition
FLUSH MOUNT WELLS
VVELL TAG
4CCESS AROUND WELL
VVELL SECURITY
VVELL LOCK CONDITION
Well tag in good condition
Access cleared around well
Well found locked
Lock in good condition
SAMPLING NOTES

III DUKE
DUKE DUKE ENERGY
ENERGY- GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) 8-Jan-2024 10-Jan-2024
WELL/LOCATION NAME
MW-2A
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
739.67
MIDDLE OF WETTED SCREEN (ft toc) 72.57
WELL DEPTH (ft TOC)
77.57
GS ELEV (ft msl)
736.96
PUMP INTAKE DEPTH (ft TOC) 77.07
SCREEN LENGTH (ft)
10
ELEV REF
I NAVD 88
SCREEN INTERVAL (ft TOC) 67.57 TO 77.57
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
MNS FD-20240108-1
PRESSURE 1 48 (psi) RECHARGE 1 10 (sec) I DISCHARGE 10 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL 11
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
53.90
WATER COLUMN (ft)
23.67
WATER ELEVATION (ft msl)
685.77
WELL VOLUME (gal)
3.86
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELLVOL
(recalculates on
current water level)
10:30
60.29
280
15.50
160
6.45
3.0
432
3.13
N/A
10:33
1 60.29
280
15.65
160
6.44
2.8
432
3.05
N/A
10:36
60.29
280
15.75
160
6.44
2.5
430
2.97
N/A
DRAW -DOWN
6.39
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
2.00
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
2.45
(gal)
1/8/2024 @ 1040
0
Samp a EHS 1/11/24 preservation verified to pH
QC By: < ?
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA O1-13 ❑BORON ❑SR 89/90 EIGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 []IODINE 131 0504,CL ❑ALPHA SPEC
OMETALS 3F_ALK ❑CO2 ❑RSK 175 OVOC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting: I NO
VVELL CAPS
Well cap in good conditon
VVELL CASING
Good Condition
4CCESS TO WELLS
Access cleared into well
PROTECTIVE CASING
Casing in good condition
FLUSH MOUNT WELLS
VVELL TAG
4CCESS AROUND WELL
VVELL SECURITY
VVELL LOCK CONDITION
Well tag in good condition
Access cleared around well
Well found locked
Lock in good condition
SAMPLING NOTES

DUKE DUKE ENERGY
ENERGY GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR EQUIPMENT PURGE ONLY SAMPLING
4' DUKE
NP ENERGY
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) 8-Jan-2024 10-Jan-2024
WELL/LOCATION NAME
MW-2D
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
740.77
MIDDLE OF WETTED SCREEN (ft toc)
103.82
WELL DEPTH (ft TOC)
108.82
GS ELEV (ft msl)
737.41
PUMP INTAKE DEPTH (ft TOC)
108.32
SCREEN LENGTH (ft)
10
ELEV REF
NAVD 88
SCREEN INTERVAL (ft TOC) 98.82 TO 108.82
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT
QED T1200
TUBING DIAMETER (in)
1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) DISCHARGE (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL Ell
—NUCLEAR LANDFILL
Equip. Only Purge
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
55.09
WATER COLUMN (ft)
53.7311
WATER ELEVATION (ft msl)
685.68
11WELLVOLUME
(gal)
1 8.76 11
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
INITIAL
WATER LEVEL
(ft)
FLOW
RATE
(ml/min)
FINAL
WATER LEVEL
(ft)
61 61
TEMP SPECIFIC
COND.
(deg C) (umho/cm)
61
pH
(SU)
ICI
TURBIDITY
(NTU)
n
ORP
(mV -NEH)
I I
DISSOLVED
OXYGEN
(mg/L)
I I
55.09
360
60.95
15.44 57
6.46
7.7
410
6.47
N/A
If Evacuated And It Is Requiered To Return To Sample, Enter The Date, Time, And
Water Level To The Right Before Sampling to Determine Recharge.
DATE:
TIME:
WATER LEVEL:
Well Vol.:
Evacuated:
N/A
N/A
Sample:
Tubing Volume
2353
(ml) INITIAL PURGE VOL. EQUIPMENT PURGE ONLY SAMPLE
Pump (Bladder) Volume
495
(ml) 0.75 SAMPLE COLLECTED BY
(ml) — 0.75 (gal) EHS
DATE TIME
CHLORINE (mg/1)
Total Purge Volume
2848
1/8/2024 @ 0940
1 0
::IF-- EHS 1/11/24
Sample preservation verified to pH
(units) 11
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA 2H3 ❑BORON ❑SR 89/90 OGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 OSO4,CL ❑ALPHA SPEC
OMETALS OF_ALK ❑CO2 ❑RSK 175 OVOC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION
.L PAD
Good Condition
.L CAPS
Well cap in good conditon
.L CASING
Good Condition
ESS TO WELLS
Access cleared into well
TECTIVE CASING
Casing in good condition
iH MOUNT WELLS
.L TAG
Well tag in good condition
ESS AROUND WELL
Access cleared around well
.L SECURITY
Well found locked
.L LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION NOTES
Impacted By Silting: I NO

111 DUKE DUKE ENERGYDUKE
ENERGY- GROUNDWATER MONITORING DATA SHEET ENERGY.
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) 8-Jan-2024 10-Jan-2024
WELL/LOCATION NAME
MW-3
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
728.43
MIDDLE OF WETTED SCREEN (ft toc)
68.64
WELL DEPTH (ft TOC)
73.64
GS ELEV (ft msl)
724.98
PUMP INTAKE DEPTH (ft TOC)
73.14
SCREEN LENGTH (ft)
10
ELEV REF
NAVD 88
F SCREEN INTERVAL (ft TOC) 63.64 I TO 73.64
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE 1 10 (sec) I DISCHARGE 10 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL 11
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
57.65
WATER COLUMN (ft)
15.99
WATER ELEVATION (ft msl)
670.78
WELL VOLUME (gal)
2.61
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
DRIP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELLVOL
(recalculates on
current water level)
2:48
60.31
300
15.64
110
6.29
8.8
445
5.49
N/A
2:51
60.31
300
15.61
108
6.30
3.5
440
5.37
N/A
2:54
60.31
300
15.53
106
6.32
2.1
436
5.31
N/A
DRAW -DOWN
2.66
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
1.50
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
2.00
(gal)
1/10/2024 @ 1500
0
Samp a EHS 1/11/24 preservation verified to pH
QC By: < ?
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA O1-13 ❑BORON ❑SR 89/90 EIGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 21SO4,CL ❑ALPHA SPEC
OMETALS 3F_ALK ❑CO2 ❑RSK 175 OVOC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting: I NO
VVELL CAPS
Well cap in good conditon
VVELL CASING
Good Condition
4CCESS TO WELLS
Access cleared into well
PROTECTIVE CASING
Casing in good condition
FLUSH MOUNT WELLS
VVELL TAG
4CCESS AROUND WELL
VVELL SECURITY
VVELL LOCK CONDITION
Well tag in good condition
Access cleared around well
Well found locked
Lock in good condition
SAMPLING NOTES

111 DUKE DUKE ENERGYDUKE
ENERGY- GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) 8-Jan-2024 10-Jan-2024
WELL/LOCATION NAME
MW-301
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
728.39
MIDDLE OF WETTED SCREEN (ft toc) 85.19
WELL DEPTH (ft TOC)
90.19
GS ELEV (ft msl)
724.98
PUMP INTAKE DEPTH (ft TOC) 89.69
SCREEN LENGTH (ft)
10
ELEV REF
NAVD 88
F SCREEN INTERVAL (ft TOC) 80.19 TO 90.19
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE 1 48 (psi) RECHARGE 1 14 (sec) I DISCHARGE 6 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL 11
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
57.62
WATER COLUMN (ft)
32.57
WATER ELEVATION (ft msl)
670.77
WELL VOLUME (gal)
5.31
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (ga0
WELLVOL
(recalculates on
current water level)
3:27
59.00
360
15.31
160
6.59
2.4
278
0.82
N/A
3:30
59.00
360
15.27
159
6.60
2.2
277
0.85
N/A
3:33
59.00
360
15.24
157
6.61
1.9
275
0.79
N/A
DRAW -DOWN
1.38
Itt)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
1.50
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
2.10
(gal)
1 1/10/2024 @ 1535
0
Samp a EHS 1/11/24 preservation verified to pH
QC By: < ?
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA O1-13 ❑BORON ❑SR 89/90 EIGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 []IODINE 131 05O4,CL ❑ALPHA SPEC
OMETALS 3F_ALK ❑CO2 ❑RSK 175 OVOC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, 5O4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting: I NO
VVELL CAPS
Well cap in good conditon
VVELL CASING
Good Condition
4CCESS TO WELLS
Access cleared into well
PROTECTIVE CASING
Casing in good condition
FLUSH MOUNT WELLS
VVELL TAG
4CCESS AROUND WELL
VVELL SECURITY
VVELL LOCK CONDITION
Well tag in good condition
Access cleared around well
Well found locked
Lock in good condition
SAMPLING NOTES

III DUKE
DUKE DUKE ENERGY
ENERGY- GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) 8-Jan-2024 10-Jan-2024
WELL/LOCATION NAME
MW-3BR
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
735.94
MIDDLE OF WETTED SCREEN (ft toc) 131.43
WELL DEPTH (ft TOC)
133.93
GS ELEV (ft msl)
732.94
PUMP INTAKE DEPTH (ft TOC) 130.00
SCREEN LENGTH (ft)
5
ELEV REF
I NAVD 88
SCREEN INTERVAL (ft TOC) 128.93 1 TO 133.93
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QEDT1250 TUBING DIAMETER (in) 1/40D
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE I #N/A (psi) RECHARGE I #N/A (sec) I DISCHARGE I #N/A (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL 11
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
64.99
WATER COLUMN (ft)
68.94
WATER ELEVATION (ft msl)
670.95
WELL VOLUME (gal)
11.24
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
DRIP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELLVOL
(recalculates on
current water level)
15:00
65.35
200
12.58
219
7.67
9.1
99
0.85
N/A
15:10
1 65.35
200
12.44
218
7.65
6.3
72
0.90
N/A
15:15
65.35
200
11.75
211
7.58
4.0
84
1.08
N/A
15:20
65.35
200
11.38
209
7.57
2.8
90
1.36
N/A
DRAW -DOWN
0.36
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
0.05
(gal)
SAMPLE COLLECTED BY
JAS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
1.15
(gal)
b/10/2024 @ 1530
0
Samp a EHS 1/11/24 preservation verified to pH
QC By: < ?
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA O1-13 ❑BORON ❑SR 89/90 EIGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 21SO4,CL ❑ALPHA SPEC
OMETALS 3F_ALK ❑CO2 ❑RSK 175 OVOC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting: I NO
VVELL CAPS
Well cap in good conditon
VVELL CASING
Good Condition
4CCESS TO WELLS
Access cleared into well
PROTECTIVE CASING
Casing in good condition
FLUSH MOUNT WELLS
VVELL TAG
4CCESS AROUND WELL
VVELL SECURITY
VVELL LOCK CONDITION
Well tag in good condition
Access cleared around well
Well found locked
Lock in good condition
SAMPLING NOTES

DUKE DUKE ENERGY
ENERGY GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR EQUIPMENT PURGE ONLY SAMPLING
DUKE
ENERGY
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
a a p
SAMPLING DATE(s) 8-Jan-2024 € 10-Jan-2024
WELL/LOCATION NAME
MW-4
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
741.13
MIDDLE OF WETTED SCREEN (ft toc)
71.48
WELL DEPTH (ft TOC)
74.15
GS ELEV (ft msl)
738.40
PUMP INTAKE DEPTH (ft TOC)
73.65
SCREEN LENGTH (ft)
10
ELEV REF
NAVD 88
SCREEN INTERVAL (ft TOC) 64.15 TO 74.15
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT
QED T1200
TUBING DIAMETER (in)
i/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE 1 45 (psi) RECHARGE 1 45 1 (sec) I DISCHARGE 15 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICKUP WELL
MONITORING WELL Ell
NUCLEAR LANDFILL
Equip. Only Purge
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ftTOC)
68.80
WATER COLUMN (ft)
5.35
WATER ELEVATION (ft msl)
672.33
11WELL
VOLUME (gal)
1 0.87
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
INITIAL
WATER LEVEL
(ft)
FLOW
RATE
(ml/min)
FINAL
WATER LEVEL
(ft)
❑
TEMP
(degC)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
o
TURBIDITY
(NTU)
0
ORP
(mV-NEH)
0
DISSOLVED
OXYGEN
(mg/L)
❑
68.80
200
70.50
14.62
119
6.01
0.8
284
1.14
N/A
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE:
TIME:
WATER LEVEL:
Well Vol.:
Evacuated:
N/A
N/A
Sampled:
Tubing Volume
1600
(ml) INITIAL PURGE VOL. EQUIPMENT PURGE ONLY SAMPLE
CHLORINE (mg/1)
Pump (Bladder) Volume
495
(ml) 0.55 SAMPLE COLLECTED BY
(ml) — 0.55 I (gal) I JAS
DATE TIME
Total Purge Volume
2095
1/8/2024 -F--@--F 0950
1 0
:CtC:By]F--
EHS 1/11/24
Sample preservation verified to pH
< 2.0
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA 21-13 ❑BORON ❑SR 89/90 OGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 OSO4,CL ❑ALPHA SPEC
OMETALS ❑F_ALK 00O2 ❑RSK 175 OVOC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, 504, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION
.L PAD
Good Condition
.L CAPS
Well cap in good conditon
.L CASING
Good Condition
ESS TO WELLS
Access cleared into well
TECTIVE CASING
Casing in good condition
iH MOUNT WELLS
.L TAG
Well tag in good condition
ESS AROUND WELL
Access cleared around well
.L SECURITY
Well found locked
.L LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION NOTES
Iting: I NO

DUKE DUKE ENERGY DUKE
ENERGY- GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
d d d
SAMPLING DATE(s) 8-Jan-2024 10-Jan-2024
WELL/LOCATION NAME
MWAD
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
740.58
MIDDLE OF WETTED SCREEN (ft toc) 97.24
WELL DEPTH (ft TOC)
102.24
GS ELEV (ft msl)
738.25
PUMP INTAKE DEPTH (ft TOC) 101.74
SCREEN LENGTH (ft)
10
ELEV REF
NAVD 88
F SCREEN INTERVAL (ft TOC) 92.24 TO 102.24
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE 1 10 (sec) I DISCHARGE 10 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL 11
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
67.64
WATER COLUMN (ft)
34.60
WATER ELEVATION (ft msl)
672.94
WELL VOLUME (gal)
5.64
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
DRIP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELLVOL
(recalculates on
current water level)
10:00
67.92
150
14.63
235
6.73
6.4
132
2.46
N/A
10:05
1 68.25
150
14.73
226
6.67
3.1
122
1.93
N/A
10:10
68.25
150
14.79
234
6.66
2.1
122
1.53
N/A
10:15
68.25
150
14.69
235
6.65
1.3
122
1.46
N/A
10:20
68.25
150
14.67
238
6.63
1.2
123
1.55
N/A
DRAW -DOWN
0.61
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
0.05
(gal)
SAMPLE COLLECTED BY
JAS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
0.85
(gal)
1/8/2024 @ 10:40
0
Samp a EHS 1/11/24 preservation verified to pH
QC By: < ?
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA O1-13 ❑BORON ❑SR 89/90 EIGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 21SO4,CL ❑ALPHA SPEC
OMETALS 3F_ALK ❑CO2 ❑RSK 175 OVOC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting: I NO
VVELL CAPS
Well cap in good conditon
VVELL CASING
Good Condition
4CCESS TO WELLS
Access cleared into well
PROTECTIVE CASING
Casing in good condition
FLUSH MOUNT WELLS
VVELL TAG
4CCESS AROUND WELL
VVELL SECURITY
VVELL LOCK CONDITION
Well tag in good condition
Access cleared around well
Well found locked
Lock in good condition
SAMPLING NOTES

III DUKE
DUKE DUKE ENERGY
ENERGY- GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) 8-Jan-2024 10-Jan-2024
WELL/LOCATION NAME
MW-4BR
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
741.97
MIDDLE OF WETTED SCREEN (ft toc) 176.58
WELL DEPTH (ft TOC)
179.08
GS ELEV (ft msl)
739.09
PUMP INTAKE DEPTH (ft TOC) 175.00
SCREEN LENGTH (ft)
5
ELEV REF
I NAVD 88
SCREEN INTERVAL (ft TOC) 174.08 1 TO 179.08
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QEDT1250 TUBING DIAMETER (in) 1/40D
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE I #N/A (psi) RECHARGE I #N/A (sec) I DISCHARGE I #N/A (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
I WELL USE
PURGE METHOD
STICK UP WELL Ell
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER If TOC)
71.34
WATER COLUMN (ft)
107.74
WATER ELEVATION (ft msl)
670.63
WELL VOLUME (gal)
17.57
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELLVOL
(recalculates on
current water level)
11:30
71.80
100
16.56
724
11.66
2.5
121
1.74
N/A
11:40
1 71.80
100
16.38
540
11.45
1.9
141
1.51
N/A
12:00
71.80
100
16.60
378
11.09
1.4
146
1.09
N/A
12:40
71.80
100
16.34
272
10.34
1.1
143
1.30
N/A
12:50
71.80
100
16.46
264
10.27
1.2
139
1.10
N/A
13:00
71.80
100
16.34
252
10.25
1.0
136
1.32
N/A
DRAW -DOWN
0.46
(ft)
INITIAL PURGE VOLUME
0.05
(gal)
SAMPLE COLLECTED BY
JAS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
2.45
(gal)
1/8/2024 @ 1310
0
Samp a EHS 1/11/24 preservation verified to pH
QC By: < ?
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA O1-13 ❑BORON ❑SR 89/90 EIGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 21SO4,CL ❑ALPHA SPEC
OMETALS 3F_ALK ❑CO2 ❑RSK 175 OVOC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting: I NO
VVELL CAPS
Well cap in good conditon
VVELL CASING
Good Condition
4CCESS TO WELLS
Access cleared into well
PROTECTIVE CASING
Casing in good condition
FLUSH MOUNT WELLS
VVELL TAG
4CCESS AROUND WELL
VVELL SECURITY
VVELL LOCK CONDITION
Well tag in good condition
Access cleared around well
Well found locked
Lock in good condition
SAMPLING NOTES

DUKE DUKE ENERGY DUKE
ENERGY- GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) 8-Jan-2024 10-Jan-2024
WELL/LOCATION NAME
MWAR
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
713.87
MIDDLE OF WETTED SCREEN (ft toc)
43.77
WELL DEPTH (ft TOC)
45.73
GS ELEV (ft msl)
711.15
PUMP INTAKE DEPTH (ft TOC)
45.23
SCREEN LENGTH (ft)
15
ELEV REF
NAVD 88
F SCREEN INTERVAL (ft TOC) 30.73 TO 45.73
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE 1 13 (sec) I DISCHARGE 7 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL 11
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
41.80
WATER COLUMN (ft)
1 3.93
WATER ELEVATION (ft msl)
672.07
1 (gal)
1 0.64
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
DRIP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELLVOL
(recalculates on
current water level)
11:00
42.20
200
10.49
108
7.49
0.9
230
10.16
N/A
11:05
1 42.20
200
1 13.67
106
6.67
0.8
232
3.30
N/A
11:10
42.20
200
13.42
107
6.49
0.8
240
3.41
N/A
11:15
42.20
200
13.51
106
6.48
0.8
242
3.47
N/A
11:18
42.20
200
13.35
106
6.47
0.6
248
3.44
N/A
DRAW -DOWN
0.40
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
0.05
(gal)
SAMPLE COLLECTED BY
JAS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
1.05
(gal)
1 1/10/2024 @ 11:20
0
Samp a EHS 1/11/24 preservation verified to pH
QC By: < ?
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA O1-13 ❑BORON ❑SR 89/90 EIGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 21SO4,CL ❑ALPHA SPEC
OMETALS 3F_ALK ❑CO2 ❑RSK 175 OVOC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting: I NO
VVELL CAPS
Well cap in good conditon
VVELL CASING
Good Condition
4CCESS TO WELLS
Access cleared into well
PROTECTIVE CASING
Casing in good condition
FLUSH MOUNT WELLS
VVELL TAG
4CCESS AROUND WELL
VVELL SECURITY
VVELL LOCK CONDITION
Well tag in good condition
Access cleared around well
Well found locked
Lock in good condition
SAMPLING NOTES

DUKE DUKE ENERGY DUKE
ENERGY- GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) 8-Jan-2024 10-Jan-2024
WELL/LOCATION NAME
MWADR
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
713.75
MIDDLE OF WETTED SCREEN (ft toc) 82.90
WELL DEPTH (ft TOC)
90.40
GS ELEV (ft msl)
711.15
PUMP INTAKE DEPTH (ft TOC) 89.90
SCREEN LENGTH (ft)
15
ELEV REF
NAVD 88
F SCREEN INTERVAL (ft TOC) 75.40 TO 90.40
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE 1 10 (sec) I DISCHARGE 5 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL 11
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
40.96
WATER COLUMN (ft)
49.44
WATER ELEVATION (ft msl)
672.79
WELL VOLUME (gal)
8.06
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
DRIP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELLVOL
(recalculates on
current water level)
12:30
41.44
200
12.19
123
8.41
1.3
209
4.11
N/A
12:35
1 41.44
200
11.38
118
7.74
1.1
234
4.03
N/A
12:40
41.44
200
11.09
116
7.69
0.8
237
4.01
N/A
12:45
41.44
200
10.88
115
7.66
0.4
238
4.07
N/A
DRAW -DOWN
0.48
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
0.05
(gal)
SAMPLE COLLECTED BY
JAS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
0.85
(gal)
b/10/2024 @ 1250
0
Samp a EHS 1/11/24 preservation verified to pH
QC By: < ?
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA O1-13 ❑BORON ❑SR 89/90 EIGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 21SO4,CL ❑ALPHA SPEC
OMETALS 3F_ALK ❑CO2 ❑RSK 175 OVOC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting: I NO
VVELL CAPS
Well cap in good conditon
VVELL CASING
Good Condition
4CCESS TO WELLS
Access cleared into well
PROTECTIVE CASING
Casing in good condition
FLUSH MOUNT WELLS
VVELL TAG
4CCESS AROUND WELL
VVELL SECURITY
VVELL LOCK CONDITION
Well tag in good condition
Access cleared around well
Well found locked
Lock in good condition
SAMPLING NOTES

DUKE DUKE ENERGY I DUKE
ENERGY GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) 8-Jan-2024 10-Jan-2024
WELL/LOCATION NAME
MW-4BRR
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
713.94
MIDDLE OF WETTED SCREEN (ft toc)
154.06
WELL DEPTH (ftTOC)
156.56
GS ELEV (ft msl)
710.82
PUMP INTAKE DEPTH (ft TOC)
152.00
SCREEN LENGTH (ft)
5
ELEV REF
NAVD 88
SCREEN INTERVAL (ft TOC) 151.56 TO 156.56
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1250 TUBING DIAMETER (in) 1/40D
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE I #N/A (psi) RECHARGE I #N/A (sec) I DISCHARGE #N/A (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL 11
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
51.80
WATER COLUMN (ft)
104.76
WATER ELEVATION (ft msl)
662.14
WELL VOLUME (gal)
17.09
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
10:50
53.00
150
11.17
3767
12.37
1.5
64
1.78
N/A
11:20
53.00
150
13.00
2474
12.33
1.2
-17
2.07
N/A
12:20
53.00
150
11.77
3698
12.67
1.2
34
2.41
N/A
13:40
53.00
150
12.76
3770
12.26
1.4
8
1.64
N/A
13:50
53.00
150
13.63
3711
12.17
1.2
14
2.35
N/A
14:00
53.00
150
13.57
3708
12.08
1.5
4
2.29
N/A
14:05
53.00
150
13.46
3711
12.02
1.2
-1
2.51
N/A
14:10
53.00
150
13.32
3701
11.99
1.4
-3
2.31
N/A
DRAW -DOWN
1.20
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
0.05
(gal)
SAMPLE COLLECTED BY
JAS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
3.25
(gal)
1/10/2024 @ 1415
0
Sample preservation verified to pH
Ed
EHS 1/11/24 (units) � 2.0
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA OH3 ❑BORON ❑SR 89/90 OGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 OSO4,CL ❑ALPHA SPEC
OMETALS OF ALK ❑CO2 ❑RSK 175 OVOC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS 7NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
PAD
Good Condition
CAPS
Well cap in good conditon
CASING
Good Condition
iS TO WELLS
Access cleared into well
ECTIVE CASING
Casing in good condition
I MOUNT WELLS
TAG
Well tag in good condition
iS AROUND WELL
Access cleared around well
SECURITY
Well found locked
LOCK CONDITION
Lock in good condition
NO
SAMPLING NOTES

DUKE DUKE ENERGY
ENERGY GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR EQUIPMENT PURGE ONLY SAMPLING
DUKE
ENERGY
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(S) 8-Jan-2024 10-Jan-2024
WELL/LOCATION NAME
MW-11
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
722.60
MIDDLE OF WETTED SCREEN (ft toc)
34.40
WELL DEPTH (ft TOC)
38.45
GS ELEV (ft msl)
720.10
PUMP INTAKE DEPTH (ft TOC)
37.95
SCREEN LENGTH (ft)
15
ELEV REF
NAVD 88
SCREEN INTERVAL (ft TOC) 23.45 TO 38.45
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT
QED T1200
TUBING DIAMETER (in)
1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) DISCHARGE (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL Ell
—NUCLEAR LANDFILL
Equip. Only Purge
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
30.35
WATER COLUMN (ft)
8.10
WATER ELEVATION (ft msl)
692.25
11WELLVOLUME
(gal)
1 1.32
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
INITIAL
WATER LEVEL
(ft)
FLOW
RATE
(ml/min)
FINAL
WATER LEVEL
(ft)
ICI ICI
TEMP SPECIFIC
COND.
(deg C) (umho/cm)
ICI
pH
(SU)
PI
TURBIDITY
(NTU)
n
ORP
(mV -NEH)
I I
DISSOLVED
OXYGEN
(mg/L)
I I
30.35
360
33.29
14.28 30
5.68
9.7
403
1.81
N/A
If Evacuated And It Is Requiered To Return To Sample, Enter The Date, Time, And
Water Level To The Right Before Sampling to Determine Recharge.
DATE:
TIME:
WATER LEVEL:
Well Vol.:
Evacuated:
N/A
N/A
Sample:
Tubing Volume
824
(ml) INITIAL PURGE VOL. EQUIPMENT PURGE ONLY SAMPLE
Pump (Bladder) Volume
495
(ml) 0.35 SAMPLE COLLECTED BY
(ml) — 0.35 (gal) EHS
DATE TIME
CHLORINE (mg/I)
Total Purge Volume
1319
1/10/2024 1 @ 1120
0
::IF-- EHS 1/11/24
Sample preservation verified to pH
(units) 11
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA 2H3 ❑BORON ❑SR 89/90 OGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 0SO4,CL ❑ALPHA SPEC
OMETALS OF_ALK ❑CO2 ❑RSK 175 OVOC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION
.L PAD
Good Condition
.L CAPS
Well cap in good conditon
.L CASING
Good Condition
ESS TO WELLS
Access cleared into well
TECTIVE CASING
Casing in good condition
iH MOUNT WELLS
.L TAG
Well tag in good condition
ESS AROUND WELL
Access cleared around well
.L SECURITY
Well found locked
.L LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION NOTES
Impacted By Silting: I NO

IIIDUKE DUKE ENERGY vu�cE
ENERGY- GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) 8-Jan-2024 I 10-Jan-2024 I
WELL/LOCATION NAME
MW-11D
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
723.14
MIDDLE OF WETTED SCREEN (ft toc)
96.55
WELL DEPTH (ft TOC)
101.55
GS ELEV (ft msl)
720.84
PUMP INTAKE DEPTH (ft TOC)
101.05
SCREEN LENGTH (ft)
10
ELEV REF
NAVD 88
F SCREEN INTERVAL (ft TOC) 91.55 TO 101.55
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE 1 8 (sec) I DISCHARGE 7 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
I WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
I NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER If TOC)
31.00
WATER COLUMN (ft)
70.55
WATER ELEVATION (ft msl)
692.14
WELL VOLUME (gal)
11.51
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
DRIP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (ga0
WELLVOL
(recalculates on
current water level)
10:43
39.80
500
12.73
28
5.92
36.9
445
6.81
N/A
10:46
1 39.80
500
13.91
27
6.00
34.6
455
5.81
N/A
10:49
39.80
500
14.14
27
6.02
35.7
456
5.76
N/A
10:52
39.80
500
14.26
27
5.96
37.6
449
5.71
N/A
DRAW -DOWN
8.80
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
7.00
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
8.20
(gal)
h/10/2024 @ 1055
1 0
Samp a EHS 1/11/24 preservation verified to pH
QC By: < ?
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA O1-13 ❑BORON ❑SR 89/90 EIGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 21SO4,CL ❑ALPHA SPEC
OMETALS 3F_ALK ❑CO2 ❑RSK 175 OVOC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, 504, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting: I NO
VVELL CAPS
Well cap in good conditon
VVELL CASING
Good Condition
4CCESS TO WELLS
Access cleared into well
PROTECTIVE CASING
Casing in good condition
FLUSH MOUNT WELLS
VVELL TAG
4CCESS AROUND WELL
VVELL SECURITY
VVELL LOCK CONDITION
Well tag in good condition
Access cleared around well
Well found locked
Lock in good condition
SAMPLING NOTES
After initial well volume is removed - WL drops to 65 ft - recalculate well volume and use for subsequent readings.

IIIDUKE DUKE ENERGY vu�cE
ENERGY- GROUNDWATER MONITORING DATA SHEET ENERGY.
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) 8-Jan-2024 I 10-Jan-2024 I
WELL/LOCATION NAME
MW-11BR
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
726.66
MIDDLE OF WETTED SCREEN (ft toc) 202.63
WELL DEPTH (ft TOC)
205.13
GS ELEV (ft msl)
723.65
PUMP INTAKE DEPTH (ft TOC) 202.00
SCREEN LENGTH (ft)
5
ELEV REF
NAVD 88
F SCREEN INTERVAL (ft TOC) 200.13 TO 205.13
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QEDT1250 TUBING DIAMETER (in) 1/4OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
FD-20240110-1 taken
PRESSURE I #N/A (psi) RECHARGE I #N/A (sec) I DISCHARGE I #N/A (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
I WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
I NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER If TOG)
36.28
WATER COLUMN (ft)
168.85
WATER ELEVATION (ft msl)
690.38
WELL VOLUME (gal)
27.54
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
DRIP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELLVOL
(recalculates on
current water level)
11:55
37.09
200
14.41
119
8.48
12.5
306
2.74
N/A
11:58
37.09
200
14.41
118
8.43
5.4
305
2.80
N/A
12:01
37.09
200
14.41
117
8.42
4.6
313
2.93
N/A
DRAW -DOWN
0.81
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
2.00
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
2.35
(gal)
b1/10/2024 @ 1205
0
Samp a EHS 1/11/24 preservation verified to pH
QC By: < ?
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA O1-13 ❑BORON ❑SR 89/90 EIGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 21SO4,CL ❑ALPHA SPEC
OMETALS 3F_ALK ❑CO2 ❑RSK 175 OVOC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting: I NO
VVELL CAPS
Well cap in good conditon
VVELL CASING
Good Condition
4CCESS TO WELLS
Access cleared into well
PROTECTIVE CASING
Casing in good condition
FLUSH MOUNT WELLS
VVELL TAG
4CCESS AROUND WELL
VVELL SECURITY
VVELL LOCK CONDITION
Well tag in good condition
Access cleared around well
Well found locked
Lock in good condition
SAMPLING NOTES

IIIDUKE DUKE ENERGY vu�cE
ENERGY- GROUNDWATER MONITORING DATA SHEET ENERGY.
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) 8-Jan-2024 10-Jan-2024
WELL/LOCATION NAME
MW-12
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
724.81
MIDDLE OF WETTED SCREEN (ft toc)
21.99
WELL DEPTH (ft TOC)
29.49
GS ELEV (ft msl)
722.21
PUMP INTAKE DEPTH (ft TOC)
28.99
SCREEN LENGTH (ft)
15
ELEV REF
NAVD 88
F SCREEN INTERVAL (ft TOC) 14.49 TO 29.49
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE 1 14 (sec) I DISCHARGE 6 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
I WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
I NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER If TOG)
4.09
WATER COLUMN (ft)
1 25.40
WATER ELEVATION (ft msl)
720.72
1 (gal)
1 4.14
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
DRIP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELLVOL
(recalculates on
current water level)
1:04
5.17
200
11.67
18
5.55
27.7
384
9.69
N/A
1:20
5.17
200
12.41
17
5.46
25.3
445
9.21
1 N/A
1:30
5.17
200
12.35
17
5.37
24.1
455
9.12
N/A
1:50
5.17
200
12.45
17
5.35
23.4
467
9.13
N/A
1:53
5.17
200
12.45
17
5.34
23.7
473
9.11
N/A
1:56
5.17
200
12.43
17
5.34
23.9
473
9.10
N/A
DRAW -DOWN
1.08
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
1.50
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
4.25
(gal)
b/10/2024 @ 1400
0
Samp a EHS 1/11/24 preservation verified to pH
QC By: < ?
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA O1-13 ❑BORON ❑SR 89/90 EIGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 21SO4,CL ❑ALPHA SPEC
OMETALS 3F_ALK ❑CO2 ❑RSK 175 OVOC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting: I NO
VVELL CAPS
Well cap in good conditon
VVELL CASING
Good Condition
4CCESS TO WELLS
Access cleared into well
PROTECTIVE CASING
Casing in good condition
FLUSH MOUNT WELLS
VVELL TAG
4CCESS AROUND WELL
VVELL SECURITY
VVELL LOCK CONDITION
Well tag in good condition
Access cleared around well
Well found locked
Lock in good condition
SAMPLING NOTES

IIIDUKE DUKE ENERGY vu�cE
ENERGY- GROUNDWATER MONITORING DATA SHEET ENERGY.
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) 8-Jan-2024 I 10-Jan-2024 I
WELL/LOCATION NAME
MW-12D
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
724.77
MIDDLE OF WETTED SCREEN (ft toc)
63.42
WELL DEPTH (ft TOC)
68.42
GS ELEV (ft msl)
722.21
PUMP INTAKE DEPTH (ft TOC)
67.92
SCREEN LENGTH (ft)
10
ELEV REF
NAVD 88
F SCREEN INTERVAL (ft TOC) 58.42 TO 68.42
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE 1 10 (sec) I DISCHARGE 10 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL 11
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOG)
28.55
WATER COLUMN (ft)
39.87
WATER ELEVATION (ft msl)
696.22
WELL VOLUME (gal)
6.50
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELLVOL
(recalculates on
current water level)
1:32
30.60
210
14.35
83
6.36
7.7
417
6.11
N/A
1:35
30.60
210
14.39
83
6.38
6.6
418
1 6.09
N/A
1:38
30.60
210
14.41
83
6.41
5.9
418
6.09
N/A
DRAW -DOWN
2.05
Itt)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
1.50
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
1.85
(gal)
1/10/2024 @ 1340
0
Samp a EHS 1/11/24 preservation verified to pH
QC By: < ?
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA O1-13 ❑BORON ❑SR 89/90 EIGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 21SO4,CL ❑ALPHA SPEC
OMETALS 3F_ALK ❑CO2 ❑RSK 175 OVOC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting: I NO
VVELL CAPS
Well cap in good conditon
VVELL CASING
Good Condition
4CCESS TO WELLS
Access cleared into well
PROTECTIVE CASING
Casing in good condition
FLUSH MOUNT WELLS
VVELL TAG
4CCESS AROUND WELL
VVELL SECURITY
VVELL LOCK CONDITION
Well tag in good condition
Access cleared around well
Well found locked
Lock in good condition
SAMPLING NOTES

IIIDUKE DUKE ENERGY vu�cE
ENERGY- GROUNDWATER MONITORING DATA SHEET ENERGY.
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) 8-Jan-2024 10-Jan-2024
WELL/LOCATION NAME
MW-13D
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
715.36
MIDDLE OF WETTED SCREEN (ft toc) 90.00
WELL DEPTH (ft TOC)
95.00
GS ELEV (ft msl)
712.40
PUMP INTAKE DEPTH (ft TOC) 90.00
SCREEN LENGTH (ft)
10
ELEV REF
NAVD 88
F SCREEN INTERVAL (ft TOC) 85.00 1 TO 95.00
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1250 TUBING DIAMETER (in) 1/4 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE I #N/A (psi) RECHARGE I #N/A (sec) I DISCHARGE I #N/A (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
I WELL USE
PURGE METHOD
STICK UP WELL Ell
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOG)
46.02
WATER COLUMN (ft)
48.98
WATER ELEVATION (ft msl)
669.34
WELL VOLUME (gal)
7.99
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELLVOL
(recalculates on
current water level)
3:21
47.40
400
15.78
88
6.70
6.4
355
7.57
N/A
3:24
47.40
400
15.76
88
6.69
3.0
358
1 7.52
N/A
3:27
47.40
400
15.76
88
6.69
2.1
362
7.50
N/A
DRAW -DOWN
1.38
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
2.00
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
2.65
(gal)
1/8/2024 @ 1530
0
Samp a EHS 1/11/24 preservation verified to pH
QC By: < ?
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA O1-13 ❑BORON ❑SR 89/90 EIGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 21SO4,CL ❑ALPHA SPEC
OMETALS 3F_ALK ❑CO2 ❑RSK 175 OVOC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting: I NO
VVELL CAPS
Well cap in good conditon
VVELL CASING
Good Condition
4CCESS TO WELLS
Access cleared into well
PROTECTIVE CASING
Casing in good condition
FLUSH MOUNT WELLS
VVELL TAG
4CCESS AROUND WELL
VVELL SECURITY
VVELL LOCK CONDITION
Well tag in good condition
Access cleared around well
Well found locked
Lock in good condition
SAMPLING NOTES

III DUKE
DUKE DUKE ENERGY
ENERGY- GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) 8-Jan-2024 I 10-Jan-2024 I
WELL/LOCATION NAME
MW-13BR
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
714.40
MIDDLE OF WETTED SCREEN (ft toc) 161.95
WELL DEPTH (ft TOC)
164.45
GS ELEV (ft msl)
711.49
PUMP INTAKE DEPTH (ft TOC) 161.00
SCREEN LENGTH (ft)
5
ELEV REF
NAVD 88
F SCREEN INTERVAL (ft TOC) 159.45 TO 164.45
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1250 TUBING DIAMETER (in) 1/4 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE I #N/A (psi) RECHARGE I #N/A (sec) I DISCHARGE I #N/A (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
I WELL USE
PURGE METHOD
STICK UP WELL Ell
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER If TOC)
50.97
WATER COLUMN (ft)
113.48
WATER ELEVATION (ft msl)
663.43
WELL VOLUME (gal)
18.51
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
DRIP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELLVOL
(recalculates on
current water level)
14:10
50.97
100
16.41
161
8.28
1.3
243
9.52
N/A
14:15
1 51.80
100
16.83
162
8.24
1.1
82
0.59
N/A
14:20
51.80
100
16.78
164
8.22
1.0
82
0.61
N/A
14:25
51.80
100
16.83
163
8.22
0.9
82
0.59
N/A
DRAW -DOWN
0.83
Itt)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
0.05
(gal)
SAMPLE COLLECTED BY
JAS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
0.45
(gal)
1/8/2024 @ 1430
0
Samp a EHS 1/11/24 preservation verified to pH
QC By: < ?
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA O1-13 ❑BORON ❑SR 89/90 EIGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 21SO4,CL ❑ALPHA SPEC
OMETALS 3F_ALK ❑CO2 ❑RSK 175 OVOC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting: I NO
VVELL CAPS
Well cap in good conditon
VVELL CASING
Good Condition
4CCESS TO WELLS
Access cleared into well
PROTECTIVE CASING
Casing in good condition
FLUSH MOUNT WELLS
VVELL TAG
4CCESS AROUND WELL
VVELL SECURITY
VVELL LOCK CONDITION
Well tag in good condition
Access cleared around well
Well found locked
Lock in good condition
SAMPLING NOTES

DUKE DUKE ENERGY f DUKE
ENERGY SURFACE WATER MONITORING DATA SHEET E N E R Y
SAMPLING PROCEDURE NO. 3175.4
FOR SURFACE WATER SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) 8-Jan-2024 € 10-Jan-2024
WELL/LOCATION NAME
SW-1
SURFACE WATER LOCATION
INFORMATION
LOCATION TYPE:
I STREAM
IWAS WATER PRESENT:
I YES
IWAS THERE A NOTICABLE FLOW:
YES
SAMPLING METHOD:
PERISTALTIC PUMP
ILOCATION ENVIRONMENT:
I WOODED
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
Surface Water Sample
SAMPLING INFORMATION
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
DEPTH OF
INTAKE
(METERS)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(Su)
❑
TURBIDITY
(NTU)
❑
ORP
(mV -NEH)
❑
DISSOLVED
OXYGEN
(mg/L)
❑
0.01
11.82
73
6.65
35.7
344
8.83
N/A
FLOW
CONDITIONS:
Flowing, 3.00 gallons purged
SURFACE WATER SAMPLE
CHLORINE (mg/1)
0
SAMPLE COLLECTED BY
DATE TIME
EHS
1/8/2024 @ 1400
QC By: EHS 1/11/24
Sample preservation verified to pH
< 2.0
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA OH3 ❑BORON ❑SR 89/90 OGROSS ALPH/BETA [:]Fe 55 ❑Ni 63 ❑IODINE 131 0SO4,CL ❑ALPHA SPEC
OMETALS OF_ALK ❑CO2 ❑RSK 175 OVOC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, 504, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
PAD
CAPS
CASING
iS TO WELLS Access cleared into well
ECTIVE CASING
I MOUNT WELLS
TAG
iS AROUND WELL Access cleared around well
SECURITY
LOCK CONDITION
SAMPLING NOTES

NORTH CAROLINA GROUNDWATER SAMPLING SITE CHECK LIST
SITE: MCGUIRE NUCLEAR STATION SAMPLE DATE January 8 and 10, 2024
PROJECT: NUCLEAR LANDFILL 1 GROUNDWATER MONITORING PROGRAM FIELD CREW EHS
SITE CONTACT John Ballard
WEATHER 1/8/2024 30s-50s, partly cloudy 1/10/2024 30s-40s, overcast
PAGE 1 OF 1
MW-1
MW-11)
MW-2A
MW-21)
MW-3
MW-31)
MW-4
MW-4D
MW-411
MW-4DR
MW-11
MW-111)
MW-12
MW-12D
SW-1
ACCESS TO WELLS
Access cleared into well
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
Access cleared around well
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
Tall grass or weeds - needs mowing
Road washing out / muddy / needs grading
Fallen tree blocking access
WELL DEPTH
Well impacted by silting
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
N/A
WELL SECURITY
Well found locked
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
Well found unlocked
WELL LOCK CONDITION
Lock in good condition
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
Lock rusted, difficult to open / needs replacing
Replaced damaged lock
WELL CASINGS
Casing in good condition
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
Damaged casing / still functional
Damaged casing / repair required
CONCRETE PADS
Pad in good condition
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
Minor cracks
Major cracks / broken / repair required
Undermined / washing out
Fire ants around concrete pad
WELL PROTECTIVE CASINGS
Casing in good condition
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
Damaged casing / still functional
Damaged casing / repair required
Broken hinge on protective lid
Wasp nest inside protective casing
Ants inside protective casing
WELL CAPS
Well cap in good conditon
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
Damaged / needs replacement
Replaced damaged well cap
FLUSH MOUNT WELLS
Vault in good condition
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Water inside vault
Vault bolt holes broken or stripped
Bolts stripped
Vault lid cracked or broken
WELL ID TAGS
Well tag in good condition
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
Well tag missing
Well tag damaged / illegible
Lacks required information - Driller Reg #
Lacks required information -Completion date
Lacks required information -Total well depth
Lacks required information - Depth to screen
Lacks required info - Casing depth / diam.
Lacks required information -Screen interval
Lacks required information - Static WL/date
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Lacks required information - Non potable tag
NOTE:

MCGUIRE NUCLEAR STATION
NUCLEAR
LANDFILL 1 GROUNDWATER
MONITORING PROGRAM
GROUNDWATER MONITORING
FIELD DATA
PERMIT # 60-04
Purge Methods
LF = Low Flow
C = Connventional
EOP = Equip.
Only Purge
LO = Level Only
NP = No Purge
LF(M) = Low Flow (Mod.)
' = Applicable
to LF &
LF(M) Purging
Only
WELL
DEPTH TO
WATER
PUMP
WELL
EVAC
SPECIFIC
DATE
WELL
DEPTH
WATER
ELEV.
APPEARANCE
ODOR
PURGE RATE
VOL.
VOL.
EVAC
TEMP.
CONDUCTANCE
pH
TURBIDITY
ORP
DO
NO
(n -Toc)
(ft -TOC)
(ft)
METHOD (mVmin)
(gal)
(gal)
(YES/NO)
(deg. C)
(umho/cm)
(units)
(NTU's)
(mV-NHE)
(mg/L)
1/8/2024
MW-1
68.55
32.29
697.94
Normal
None
LF 400.00
5.91
3.70
N/A
15.40
105
6.21
6.1
231
0.54
1/8/2024
MW-1D
88.22
33.18
697.43
Normal
None
LF 360.00
8.98
4.15
N/A
15.13
97
6.24
9.1
237
0.75
1/8/2024
MW-2A
77.57
53.90
685.77
Normal
None
LF 280.00
3.86
2.45
N/A
15.75
160
6.44
2.5
430
2.97
1/8/2024
MW-2D
108.82
55.09
685.68
Normal
None
EOP N/A
8.76
0.75
N/A
15.44
57
6.46
7.7
410
6.47
1/10/2024
MW-3
73.64
57.65
670.78
Normal
None
LF 300.00
2.61
2.00
N/A
15.53
106
6.32
2.1
436
5.31
1/10/2024
MW-3D
90.19
57.62
670.77
Normal
None
LF 360.00
5.31
2.10
N/A
15.24
157
6.61
1.9
275
0.79
1/8/2024
MW4
74.15
68.80
672.33
Normal
None
EOP N/A
0.87
0.55
N/A
14.62
119
6.01
0.8
284
1.14
1/8/2024
MW-4D
102.24
67.64
672.94
Normal
None
LF 150.00
5.64
0.85
N/A
14.67
238
6.63
1.2
123
1.55
1/8/2024
MW-4R
45.73
41.80
672.07
Normal
None
LF 200.00
0.64
1.05
N/A
13.35
106
6.47
0.6
248
3.44
1/8/2024
MW4DR
90.40
40.96
672.79
Normal
None
LF 200.00
8.06
0.85
N/A
10.88
115
7.66
0.4
238
4.07
1/10/2024
MW-11
38.45
30.35
692.25
Normal
None
EOP N/A
1.32
0.35
N/A
14.28
30
5.68
9.7
403
1.81
1/10/2024
MW-11D
101.55
31.00
692.14
Normal
None
LF 500.00
11.51
8.20
N/A
14.26
27
5.96
37.6
449
5.71
1/10/2024
MW-12
29.49
4.09
720.72
Normal
None
LF 200.00
4.14
4.25
N/A
12.43
17
5.34
23.9
473
9.10
1/10/2024
MW-12D
68.42
28.55
696.22
Normal
None
LF 210.00
6.50
1.85
N/A
14.41
83
6.41
5.9
418
6.09
1/8/2024
SW-1
0.00
Normal
None
SWS N/A
N/A
N/A
11.82
73
6.65
35.7
344
8.83
1/10/2024
MW-313R
133.93
64.99
670.95
Normal
None
LF 200.00
11.24
1.15
N/A
11.38
209
7.57
2.8
90
1.36
1/8/2024
MW-413R
179.08
71.34
670.63
Normal
None
LF 100.00
17.57
2.45
N/A
16.34
252
10.25
1.0
136
1.32
1/10/2024
MW-413RR
156.56
51.80
662.14
Normal
None
LF 150.00
17.09
3.25
N/A
13.32
3701
11.99
1.4
-3
2.31
1/10/2024
MW-11BR
205.13
36.28
690.38
Normal
None
LF 200.00
27.54
2.35
N/A
14.41
117
8.42
4.6
313
2.93
1/8/2024
MW-13D
95.00
46.02
669.34
Normal
None
LF 400.00
7.99
2.65
N/A
15.76
88
6.69
2.1
362
7.50
1/8/2024
MW-13BR
164.45
50.97
663.43
Normal
None
LF 100.00
18.51
0.45
N/A
16.83
163
8.22
0.9
82
0.59

Appendix IV - Laboratory Reports and Chain -of -Custody Forms

• DUKE Analytical Laboratory Page 1 of 149
ENERGY,
Order Number:
Project Name:
Task Code:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
J23120380
MCGUIRE - GW LF1
LF
C Murphy, B Moeller,D Obrien,J Stowe, E Smith
McGuire Nuclear Station
13225 Hagers Ferry Rd
Mail Code: MG01CH
Huntersville, NC 28078-8985
Peggy Kendall
Pegg endall F4
Phone: [phone]
1 /29/2024
Program Comments:
QC Note:
The 8260 continuing calibration was below method acceptance limits for MIBK, lodomethane, trans-1-3-dichloropropane for the
samples collected 1-8; all samples were non -detect for these compounds.
The 8260 continuing calibration was below method acceptance limits for Bromomethane for the samples collected 1-10; all
samples were non -detect for this compound.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions: Page 2 of 149
Sample ID
Plant/Station
Collection
Date and Time
Collected By
Sample Description
2023031274
MCGUIRE
O8-Jan-24
1:20 PM
Ethan Smith
MNS MW-1
2023031275
MCGUIRE
O8-Jan-24
1:00 PM
Ethan Smith
MNS MW-1D
2023031276
MCGUIRE
08-Jan-24
10:40 AM
Ethan Smith
MNS MW-2A
2023031277
MCGUIRE
O8-Jan-24
9:40 AM
Ethan Smith
MNS MW-2D
2023031278
MCGUIRE
10-Jan-24
3:00 PM
Ethan Smith
MNS MW-3
2023031279
MCGUIRE
10-Jan-24
3:35 PM
Ethan Smith
MNS MW-3D
2023031280
MCGUIRE
08-Jan-24
9:50 AM
JOSH STOWE
MNS MW-4
2023031281
MCGUIRE
O8-Jan-24
10:40 AM
JOSH STOWE
MNS MW-4D
2023031282
MCGUIRE
10-Jan-24
11:20 AM
Ethan Smith
MNS MW-11
2023031283
MCGUIRE
10-Jan-24
10:55 AM
Ethan Smith
MNS MW-11 D
2023031284
MCGUIRE
10-Jan-24
2:00 PM
Ethan Smith
MNS MW-12
2023031285
MCGUIRE
10-Jan-24
1:40 PM
Ethan Smith
MNS MW-12D
2023031286
MCGUIRE
O8-Jan-24
2:00 PM
Ethan Smith
MNS SW-1
2023031287
MCGUIRE
10-Jan-24
11:20 AM
JOSH STOWE
MNS MW-4R
2023031288
MCGUIRE
10-Jan-24
12:50 PM
JOSH STOWE
MNS MW-4DR
2023031289
MCGUIRE
10-Jan-24
3:30 PM
JOSH STOWE
MNS MW-3BR
2023031290
MCGUIRE
08-Jan-24
1:10 PM
JOSH STOWE
MNS MW-4BR
2023031291
MCGUIRE
10-Jan-24
2:15 PM
JOSH STOWE
MNS MW-4BRR
2023031292
MCGUIRE
10-Jan-24
12:05 PM
Ethan Smith
MNS MW-11BR
2023031293
MCGUIRE
08-Jan-24
3:30 PM
Ethan Smith
MNS MW-13D
2023031294
MCGUIRE
O8-Jan-24
2:30 PM
JOSH STOWE
MNS MW-13BR
2023031295
MCGUIRE
10-Jan-24
8:00 AM
Ethan Smith
MNS TB-20240110-0800
2023031297
MCGUIRE
O8-Jan-24
8:00 AM
Ethan Smith
MNS TB-20240108-0800
2023031300
MCGUIRE
08-Jan-24
11:30 AM
Ethan Smith
MNS FB-20240108-1130
2023031301
MCGUIRE
10-Jan-24
10:20 AM
Ethan Smith
MNS FB-20240110-1020
2023031303
MCGUIRE
10-Jan-24
Ethan Smith
MNS FD-20240110-1
2023031304
MCGUIRE
O8-Jan-24
Ethan Smith
MNS FD-20240108-1
27 Total Samples

Page 3 of 149
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals❑ Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
❑d Job Summary Report
❑� Sample Identification
❑� Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
❑� Analytical Laboratory QC Report
❑d Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑� Chain of Custody
❑� Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 1/29/2024

Certificate of Laboratory Analysis Page 4 of 149
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS MW-1 Sample #: 2023031274
Collection Date: 01/08/2024 01:20 PM Loc code: MNS MW-1 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
ALKALINITY (FIXED END POINT 4.5) - 024010176
Total Alkalinity as CaCO3 47 mg/L 20 1.7 1 SM 2320B 01/11/2024 10:08 SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24010111
Chloride
2.7
mg/L
0.1
0.0154
1
EPA 9056A
01/10/2024 16:59
BGN9034
Sulfate
0.43
mg/L
0.1
0.0428
1
EPA 9056A
01/10/2024 16:59
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24010118
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
01/10/2024 09:35
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24010121
Barium (Ba)
0.229
mg/L
0.005
0.002
1
SW 601OD
01/11/2024 14:04
CELLI06
Calcium (Ca)
7.35
mg/L
0.05
0.012
1
SW 601OD
01/11/2024 14:04
CELLI06
Magnesium (Mg)
3.31
mg/L
0.02
0.008
1
SW 601OD
01/11/2024 14:04
CELLI06
Potassium (K)
1.25
mg/L
0.1
0.031
1
SW 601OD
01/11/2024 14:04
CELLI06
Sodium (Na)
6.03
mg/L
0.05
0.017
1
SW 601OD
01/11/2024 14:04
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010126
Arsenic (As)
0.124 J
ug/L
1
0.111
1
SW 6020B
01/12/2024 16:54
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
01/12/2024 16:54
MHALL3
Chromium (Cr)
0.22 J
ug/L
1
0.185
1
SW 6020E
01/12/2024 16:54
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
01/12/2024 16:54
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020E
01/12/2024 16:54
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
01/12/2024 16:54
MHALL3
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS MW-1 D
Collection Date: 01/08/2024 01:00 PM Loc code: MNS MW-1 D
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24010176
Total Alkalinity as CaCO3 42 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24010111
Chloride
2.3
mg/L
0.1
0.0154
1
Sulfate
0.44
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q24010118
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q24010121
Barium (Ba)
0.112
mg/L
0.005
0.002
1
Calcium (Ca)
7.89
mg/L
0.05
0.012
1
Magnesium (Mg)
2.69
mg/L
0.02
0.008
1
Potassium (K)
1.18
mg/L
0.1
0.031
1
Sodium (Na)
6.54
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010126
Arsenic (As)
0.212 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
Lead (Pb)
0.04 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Sample #: 2023031275
Matrix: GW RCRA
Page 5 of 149
Method Analysis Date/Time Analyst
SM 2320B 01/11/2024 10:22 SNEGLIA
EPA 9056A 01/10/2024 17:46 BGN9034
EPA 9056A 01/10/2024 17:46 BGN9034
EPA 7470A 01/10/2024 09:42 SNEGLIA
SW 601OD
01/11/2024 14:18
CELL106
SW 601OD
01/11/2024 14:18
CELL106
SW 601OD
01/11/2024 14:18
CELL106
SW 601OD
01/11/2024 14:18
CELL106
SW 601OD
01/11/2024 14:18
CELL106
SW 6020B
01/12/2024 16:12
MHALL3
SW 6020B
01/12/2024 16:12
MHALL3
SW 6020E
01/12/2024 16:12
MHALL3
SW 6020B
01/12/2024 16:12
MHALL3
SW 6020E
01/12/2024 16:12
MHALL3
SW 6020B
01/12/2024 16:12
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS MW-2A
Collection Date: 01/08/2024 10:40 AM Loc code: MNS MW-2A
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24010176
Total Alkalinity as CaCO3 79 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24010111
Chloride
1.4
mg/L
0.1
0.0154
1
Sulfate
0.78
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q24010118
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q24010121
Barium (Ba)
0.058
mg/L
0.005
0.002
1
Calcium (Ca)
20.4
mg/L
0.05
0.012
1
Magnesium (Mg)
5.45
mg/L
0.02
0.008
1
Potassium (K)
1.69
mg/L
0.1
0.031
1
Sodium (Na)
8.29
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010126
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Cadmium (Cd)
0.034 J
ug/L
1
0.032
1
Chromium (Cr)
0.546 J
ug/L
1
0.185
1
Lead (Pb)
1.28
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Sample #: 2023031276
Matrix: GW RCRA
Page 6 of 149
Method Analysis Date/Time Analyst
SM 2320B 01/11/2024 10:26 SNEGLIA
EPA 9056A 01/10/2024 18:02 BGN9034
EPA 9056A 01/10/2024 18:02 BGN9034
EPA 7470A 01/10/2024 09:49 SNEGLIA
SW 601OD
01/11/2024 14:23
CELL106
SW 601OD
01/11/2024 14:23
CELL106
SW 601OD
01/11/2024 14:23
CELL106
SW 601OD
01/11/2024 14:23
CELL106
SW 601OD
01/11/2024 14:23
CELL106
SW 6020B
01/12/2024 17:02
MHALL3
SW 6020B
01/12/2024 17:02
MHALL3
SW 6020E
01/12/2024 17:02
MHALL3
SW 6020B
01/12/2024 17:02
MHALL3
SW 6020E
01/12/2024 17:02
MHALL3
SW 6020B
01/12/2024 17:02
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS MW-2D
Collection Date: 01/08/2024 09:40 AM Loc code: MNS MW-2D
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q24010210
Total Alkalinity as CaCO3 1.7 U mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24010111
Chloride
1.2
mg/L
0.1
0.0154
1
Sulfate
0.34
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q24010118
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q24010121
Barium (Ba)
0.015
mg/L
0.005
0.002
1
Calcium (Ca)
5.32
mg/L
0.05
0.012
1
Magnesium (Mg)
1.55
mg/L
0.02
0.008
1
Potassium (K)
0.348
mg/L
0.1
0.031
1
Sodium (Na)
5.19
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010126
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
1.09
ug/L
1
0.185
1
Lead (Pb)
0.152 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Sample #: 2023031277
Matrix: GW RCRA
Page 7 of 149
Method Analysis Date/Time Analyst
SM 2320134d 01/16/2024 13:53 CEIlio6
EPA 9056A
01/10/2024 18:17
BGN9034
EPA 9056A
01/10/2024 18:17
BGN9034
EPA 7470A
01/10/2024 09:52
SNEGLIA
SW 601OD
01/11/2024 14:27
CELL106
SW 601OD
01/11/2024 14:27
CELL106
SW 601OD
01/11/2024 14:27
CELL106
SW 601OD
01/11/2024 14:27
CELL106
SW 601OD
01/11/2024 14:27
CELL106
SW 6020B
01/12/2024 17:10
MHALL3
SW 6020B
01/12/2024 17:10
MHALL3
SW 6020E
01/12/2024 17:10
MHALL3
SW 6020B
01/12/2024 17:10
MHALL3
SW 6020E
01/12/2024 17:10
MHALL3
SW 6020B
01/12/2024 17:10
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS MW-3
Collection Date: 01/10/2024 03:00 PM Loc code: MNS MW-3
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24010176
Total Alkalinity as CaCO3 53 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24010209
Chloride
1.4
mg/L
0.1
0.0154
1
Sulfate
0.66
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q24010240
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q24010140
Barium (Ba)
0.059
mg/L
0.005
0.002
1
Calcium (Ca)
11.5
mg/L
0.05
0.012
1
Magnesium (Mg)
4.56
mg/L
0.02
0.008
1
Potassium (K)
3.13
mg/L
0.1
0.031
1
Sodium (Na)
5.42
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010144
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Cadmium (Cd)
0.037 J
ug/L
1
0.032
1
Chromium (Cr)
0.374 J
ug/L
1
0.185
1
Lead (Pb)
8.02
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Sample #: 2023031278
Matrix: GW RCRA
Page 8 of 149
Method Analysis Date/Time Analyst
SM 2320B 01/11/2024 10:30 SNEGLIA
EPA 9056A
01/17/2024 10:26
BGN9034
EPA 9056A
01/17/2024 10:26
BGN9034
EPA 7470A
01/18/2024 11:51
SNEGLIA
SW 601OD
01/12/2024 12:47
CELL106
SW 601OD
01/12/2024 12:47
CELL106
SW 601OD
01/12/2024 12:47
CELL106
SW 601OD
01/12/2024 12:47
CELL106
SW 601OD
01/12/2024 12:47
CELL106
SW 6020B
01/12/2024 19:05
MHALL3
SW 6020B
01/12/2024 19:05
MHALL3
SW 6020E
01/12/2024 19:05
MHALL3
SW 6020B
01/12/2024 19:05
MHALL3
SW 6020E
01/12/2024 19:05
MHALL3
SW 6020B
01/12/2024 19:05
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS MW-3D
Collection Date: 01/10/2024 03:35 PM Loc code: MNS MW-3D
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24010176
Total Alkalinity as CaCO3 79 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24010209
Chloride
1.7
mg/L
0.1
0.0154
1
Sulfate
1.1
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q24010240
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q24010140
Barium (Ba)
0.041
mg/L
0.005
0.002
1
Calcium (Ca)
19.5
mg/L
0.05
0.012
1
Magnesium (Mg)
6.21
mg/L
0.02
0.008
1
Potassium (K)
1.13
mg/L
0.1
0.031
1
Sodium (Na)
7.80
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010144
Arsenic (As)
0.117 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
Lead (Pb)
0.037 U
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Sample #: 2023031279
Matrix: GW RCRA
Page 9 of 149
Method Analysis Date/Time Analyst
SM 2320B 01/11/2024 10:34 SNEGLIA
EPA 9056A 01/17/2024 11:29 BGN9034
EPA 9056A 01/17/2024 11:29 BGN9034
EPA 7470A 01/18/2024 11:53 SNEGLIA
SW 601OD
01/12/2024 12:58
CELL106
SW 601OD
01/12/2024 12:58
CELL106
SW 601OD
01/12/2024 12:58
CELL106
SW 601OD
01/12/2024 12:58
CELL106
SW 601OD
01/12/2024 12:58
CELL106
SW 6020B
01/12/2024 18:36
MHALL3
SW 6020B
01/12/2024 18:36
MHALL3
SW 6020E
01/12/2024 18:36
MHALL3
SW 6020B
01/12/2024 18:36
MHALL3
SW 6020E
01/12/2024 18:36
MHALL3
SW 6020B
01/12/2024 18:36
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 10 of 149
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS MW-4 Sample #: 2023031280
Collection Date: 01/08/2024 09:50 AM Loc code: MNS MW-4 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
ALKALINITY (FIXED END POINT 4.5) - 024010176
Total Alkalinity as CaCO3 82 mg/L 20 1.7 1 SM 2320B 01/11/2024 10:38 SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24010111
Chloride
1.5
mg/L
0.5
0.0154
5
EPA 9056A
01/10/2024 18:49
BGN9034
Sulfate
0.75
mg/L
0.1
0.0428
1
EPA 9056A
01/10/2024 18:49
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24010118
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
01/10/2024 09:54
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24010121
Barium (Ba)
0.089
mg/L
0.005
0.002
1
SW 601OD
01/11/2024 14:32
CELLI06
Calcium (Ca)
15.2
mg/L
0.05
0.012
1
SW 601OD
01/11/2024 14:32
CELLI06
Magnesium (Mg)
13.8
mg/L
0.02
0.008
1
SW 601OD
01/11/2024 14:32
CELLI06
Potassium (K)
0.690
mg/L
0.1
0.031
1
SW 601OD
01/11/2024 14:32
CELLI06
Sodium (Na)
2.33
mg/L
0.05
0.017
1
SW 601OD
01/11/2024 14:32
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010126
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
01/12/2024 17:19
MHALL3
Cadmium (Cd)
0.519 J
ug/L
1
0.032
1
SW 6020B
01/12/2024 17:19
MHALL3
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
SW 6020E
01/12/2024 17:19
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
01/12/2024 17:19
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020E
01/12/2024 17:19
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
01/12/2024 17:19
MHALL3
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS MW-4D
Collection Date: 01/08/2024 10:40 AM Loc code: MNS MW-4D
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24010176
Total Alkalinity as CaCO3 140 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24010111
Chloride
1.8
mg/L
0.5
0.0154
5
Sulfate
0.29
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q24010118
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q24010121
Barium (Ba)
0.059
mg/L
0.005
0.002
1
Calcium (Ca)
28.9
mg/L
0.05
0.012
1
Magnesium (Mg)
15.6
mg/L
0.02
0.008
1
Potassium (K)
0.822
mg/L
0.1
0.031
1
Sodium (Na)
3.97
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010126
Arsenic (As)
0.211 J
ug/L
1
0.111
1
Cadmium (Cd)
0.039 J
ug/L
1
0.032
1
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
Lead (Pb)
0.075 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 11 of 149
Sample #: 2023031281
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320B 01/11/2024 10:42 SNEGLIA
EPA 9056A 01/10/2024 19:20 BGN9034
EPA 9056A 01/10/2024 19:20 BGN9034
EPA 7470A 01/10/2024 09:57 SNEGLIA
SW 601OD
01/11/2024 14:37
CELL106
SW 601OD
01/11/2024 14:37
CELL106
SW 601OD
01/11/2024 14:37
CELL106
SW 601OD
01/11/2024 14:37
CELL106
SW 601OD
01/11/2024 14:37
CELL106
SW 6020B
01/12/2024 17:27
MHALL3
SW 6020B
01/12/2024 17:27
MHALL3
SW 6020E
01/12/2024 17:27
MHALL3
SW 6020B
01/12/2024 17:27
MHALL3
SW 6020E
01/12/2024 17:27
MHALL3
SW 6020B
01/12/2024 17:27
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS MW-11
Collection Date: 01/10/2024 11:20 AM Loc code: MNS MW-11
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q24010210
Total Alkalinity as CaCO3 8.32 mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24010209
Chloride
2.4
mg/L
0.1
0.0154
1
Sulfate
0.71
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q24010240
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q24010140
Barium (Ba)
0.018
mg/L
0.005
0.002
1
Calcium (Ca)
0.967
mg/L
0.05
0.012
1
Magnesium (Mg)
0.751
mg/L
0.02
0.008
1
Potassium (K)
0.118
mg/L
0.1
0.031
1
Sodium (Na)
3.55
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010144
Arsenic (As)
0.122 J
ug/L
1
0.111
1
Cadmium (Cd)
0.036 J
ug/L
1
0.032
1
Chromium (Cr)
0.305 J
ug/L
1
0.185
1
Lead (Pb)
0.103 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 12 of 149
Sample #: 2023031282
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320134d 01/16/2024 14:06 CEIlio6
EPA 9056A
01/17/2024 11:45
BGN9034
EPA 9056A
01/17/2024 11:45
BGN9034
EPA 7470A
01/18/2024 11:55
SNEGLIA
SW 601OD
01/12/2024 13:02
CELL106
SW 601OD
01/12/2024 13:02
CELL106
SW 601OD
01/12/2024 13:02
CELL106
SW 601OD
01/12/2024 13:02
CELL106
SW 601OD
01/12/2024 13:02
CELL106
SW 6020B
01/12/2024 19:14
MHALL3
SW 6020B
01/12/2024 19:14
MHALL3
SW 6020E
01/12/2024 19:14
MHALL3
SW 6020B
01/12/2024 19:14
MHALL3
SW 6020E
01/12/2024 19:14
MHALL3
SW 6020B
01/12/2024 19:14
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS MW-11 D
Collection Date: 01/10/2024 10:55 AM Loc code: MNS MW-11 D
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q24010210
Total Alkalinity as CaCO3 10.3 mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24010209
Chloride
1.3
mg/L
0.1
0.0154
1
Sulfate
0.48
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q24010240
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q24010140
Barium (Ba)
0.028
mg/L
0.005
0.002
1
Calcium (Ca)
1.97
mg/L
0.05
0.012
1
Magnesium (Mg)
1.39
mg/L
0.02
0.008
1
Potassium (K)
0.334
mg/L
0.1
0.031
1
Sodium (Na)
3.14
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010144
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.58 J
ug/L
1
0.185
1
Lead (Pb)
0.232 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 13 of 149
Sample #: 2023031283
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320134d 01/16/2024 14:12 CEIlio6
EPA 9056A
01/17/2024 12:01
BGN9034
EPA 9056A
01/17/2024 12:01
BGN9034
EPA 7470A
01/18/2024 11:58
SNEGLIA
SW 601OD
01/12/2024 13:14
CELL106
SW 601OD
01/12/2024 13:14
CELL106
SW 601OD
01/12/2024 13:14
CELL106
SW 601OD
01/12/2024 13:14
CELL106
SW 601OD
01/12/2024 13:14
CELL106
SW 6020B
01/12/2024 19:24
MHALL3
SW 6020B
01/12/2024 19:24
MHALL3
SW 6020E
01/12/2024 19:24
MHALL3
SW 6020B
01/12/2024 19:24
MHALL3
SW 6020E
01/12/2024 19:24
MHALL3
SW 6020B
01/12/2024 19:24
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS MW-12
Collection Date: 01/10/2024 02:00 PM Loc code: MNS MW-12
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q24010210
Total Alkalinity as CaCO3 1.7 U mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24010209
Chloride
3.1
mg/L
0.1
0.0154
1
Sulfate
0.83
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q24010240
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q24010140
Barium (Ba)
0.009
mg/L
0.005
0.002
1
Calcium (Ca)
0.721
mg/L
0.05
0.012
1
Magnesium (Mg)
0.414
mg/L
0.02
0.008
1
Potassium (K)
0.354
mg/L
0.1
0.031
1
Sodium (Na)
1.44
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010144
Arsenic (As)
0.225 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.716 J
ug/L
1
0.185
1
Lead (Pb)
0.438 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 14 of 149
Sample #: 2023031284
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320134d 01/16/2024 14:19 CEIlio6
EPA 9056A
01/17/2024 12:17
BGN9034
EPA 9056A
01/17/2024 12:17
BGN9034
EPA 7470A
01/18/2024 12:00
SNEGLIA
SW 601OD
01/12/2024 13:17
CELL106
SW 601OD
01/12/2024 13:17
CELL106
SW 601OD
01/12/2024 13:17
CELL106
SW 601OD
01/12/2024 13:17
CELL106
SW 601OD
01/12/2024 13:17
CELL106
SW 6020B
01/12/2024 19:33
MHALL3
SW 6020B
01/12/2024 19:33
MHALL3
SW 6020E
01/12/2024 19:33
MHALL3
SW 6020B
01/12/2024 19:33
MHALL3
SW 6020E
01/12/2024 19:33
MHALL3
SW 6020B
01/12/2024 19:33
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS MW-12D
Collection Date: 01/10/2024 01:40 PM Loc code: MNS MW-12D
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24010176
Total Alkalinity as CaCO3 36 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24010209
Chloride
3.9
mg/L
0.1
0.0154
1
Sulfate
0.0428 U
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q24010240
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q24010140
Barium (Ba)
0.011
mg/L
0.005
0.002
1
Calcium (Ca)
10.3
mg/L
0.05
0.012
1
Magnesium (Mg)
1.52
mg/L
0.02
0.008
1
Potassium (K)
0.301
mg/L
0.1
0.031
1
Sodium (Na)
7.31
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010144
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.308 J
ug/L
1
0.185
1
Lead (Pb)
0.045 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 15 of 149
Sample #: 2023031285
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320B 01/11/2024 10:46 SNEGLIA
EPA 9056A 01/17/2024 12:32 BGN9034
EPA 9056A 01/17/2024 12:32 BGN9034
EPA 7470A 01/18/2024 12:02 SNEGLIA
SW 601OD
01/12/2024 13:21
CELL106
SW 601OD
01/12/2024 13:21
CELL106
SW 601OD
01/12/2024 13:21
CELL106
SW 601OD
01/12/2024 13:21
CELL106
SW 601OD
01/12/2024 13:21
CELL106
SW 6020B
01/12/2024 19:42
MHALL3
SW 6020B
01/12/2024 19:42
MHALL3
SW 6020E
01/12/2024 19:42
MHALL3
SW 6020B
01/12/2024 19:42
MHALL3
SW 6020E
01/12/2024 19:42
MHALL3
SW 6020B
01/12/2024 19:42
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS SW-1
Collection Date: 01/08/2024 02:00 PM Loc code: MNS SW-1
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24010176
Total Alkalinity as CaCO3 32 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24010111
Chloride
2.5
mg/L
0.1
0.0154
1
Sulfate
2.2
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q24010118
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED) - Q24010138
Barium (Ba)
0.026
mg/L
0.005
0.002
1
TOTAL RECOVERABLE METALS BY ICP - Q24010121
Barium (Ba)
0.027
mg/L
0.005
0.002
1
Calcium (Ca)
7.82
mg/L
0.05
0.012
1
Magnesium (Mg)
3.29
mg/L
0.02
0.008
1
Potassium (K)
1.12
mg/L
0.1
0.031
1
Sodium (Na)
4.48
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
- Q24010141
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.421 J
ug/L
1
0.185
1
Lead (Pb)
0.186 J
ug/L
1
0.037
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010126
Arsenic (As)
0.129 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.487 J
ug/L
1
0.185
1
Lead (Pb)
0.222 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed
by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 16 of 149
Sample #: 2023031286
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320B 01/11/2024 10:50 SNEGLIA
EPA 9056A
01/10/2024 19:35
BGN9034
EPA 9056A
01/10/2024 19:35
BGN9034
EPA 7470A
01/10/2024 09:59
SNEGLIA
SW 601OD
01/12/2024 12:16
CELL106
SW 601OD
01/11/2024 14:41
CELL106
SW 601OD
01/11/2024 14:41
CELL106
SW 601OD
01/11/2024 14:41
CELL106
SW 601OD
01/11/2024 14:41
CELL106
SW 601OD
01/11/2024 14:41
CELL106
SW 6020B
01/12/2024 21:38
MHALL3
SW 6020B
01/12/2024 21:38
MHALL3
SW 6020E
01/12/2024 21:38
MHALL3
SW 6020E
01/12/2024 21:38
MHALL3
SW 6020B
01/12/2024 21:38
MHALL3
SW 6020B
01/12/2024 17:35
MHALL3
SW 6020B
01/12/2024 17:35
MHALL3
SW 6020E
01/12/2024 17:35
MHALL3
SW 6020B
01/12/2024 17:35
MHALL3
SW 6020E
01/12/2024 17:35
MHALL3
SW 6020B
01/12/2024 17:35
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS MW-4R
Collection Date: 01/10/2024 11:20 AM Loc code: MNS MW-4R
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24010176
Total Alkalinity as CaCO3 58 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24010209
Chloride
2.9
mg/L
0.1
0.0154
1
Sulfate
0.24
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q24010240
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q24010140
Barium (Ba)
0.011
mg/L
0.005
0.002
1
Calcium (Ca)
11.5
mg/L
0.05
0.012
1
Magnesium (Mg)
9.01
mg/L
0.02
0.008
1
Potassium (K)
0.286
mg/L
0.1
0.031
1
Sodium (Na)
2.73
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010144
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.646 J
ug/L
1
0.185
1
Lead (Pb)
0.095 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 17 of 149
Sample #: 2023031287
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320B 01/11/2024 10:54 SNEGLIA
EPA 9056A 01/17/2024 12:48 BGN9034
EPA 9056A 01/17/2024 12:48 BGN9034
EPA 7470A 01/18/2024 12:04 SNEGLIA
SW 601OD
01/12/2024 13:25
CELL106
SW 601OD
01/12/2024 13:25
CELL106
SW 601OD
01/12/2024 13:25
CELL106
SW 601OD
01/12/2024 13:25
CELL106
SW 601OD
01/12/2024 13:25
CELL106
SW 6020B
01/12/2024 19:52
MHALL3
SW 6020B
01/12/2024 19:52
MHALL3
SW 6020E
01/12/2024 19:52
MHALL3
SW 6020B
01/12/2024 19:52
MHALL3
SW 6020E
01/12/2024 19:52
MHALL3
SW 6020B
01/12/2024 19:52
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS MW-4DR
Collection Date: 01/10/2024 12:50 PM Loc code: MNS MW-4DR
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24010176
Total Alkalinity as CaCO3 67 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24010209
Chloride
1.9
mg/L
0.1
0.0154
1
Sulfate
0.98
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q24010240
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q24010140
Barium (Ba)
0.015
mg/L
0.005
0.002
1
Calcium (Ca)
16.9
mg/L
0.05
0.012
1
Magnesium (Mg)
5.05
mg/L
0.02
0.008
1
Potassium (K)
0.758
mg/L
0.1
0.031
1
Sodium (Na)
7.15
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010144
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
1.35
ug/L
1
0.185
1
Lead (Pb)
0.044 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 18 of 149
Sample #: 2023031288
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320B 01/11/2024 10:58 SNEGLIA
EPA 9056A
01/17/2024 13:04
BGN9034
EPA 9056A
01/17/2024 13:04
BGN9034
EPA 7470A
01/18/2024 12:11
SNEGLIA
SW 601OD
01/12/2024 13:29
CELL106
SW 601OD
01/12/2024 13:29
CELL106
SW 601OD
01/12/2024 13:29
CELL106
SW 601OD
01/12/2024 13:29
CELL106
SW 601OD
01/12/2024 13:29
CELL106
SW 6020B
01/12/2024 20:29
MHALL3
SW 6020B
01/12/2024 20:29
MHALL3
SW 6020E
01/12/2024 20:29
MHALL3
SW 6020B
01/12/2024 20:29
MHALL3
SW 6020E
01/12/2024 20:29
MHALL3
SW 6020B
01/12/2024 20:29
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS MW-3BR
Collection Date: 01/10/2024 03:30 PM Loc code: MNS MW-3BR
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24010176
Total Alkalinity as CaCO3 110 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24010209
Chloride
2.0
mg/L
0.1
0.0154
1
Sulfate
2.7
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q24010240
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q24010140
Barium (Ba)
0.089
mg/L
0.005
0.002
1
Calcium (Ca)
28.9
mg/L
0.05
0.012
1
Magnesium (Mg)
6.71
mg/L
0.02
0.008
1
Potassium (K)
8.02
mg/L
0.1
0.031
1
Sodium (Na)
11.6
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010144
Arsenic (As)
0.54 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.236 J
ug/L
1
0.185
1
Lead (Pb)
0.056 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 19 of 149
Sample #: 2023031289
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320B 01/11/2024 11:02 SNEGLIA
EPA 9056A 01/17/2024 13:20 BGN9034
EPA 9056A 01/17/2024 13:20 BGN9034
EPA 7470A 01/18/2024 12:18 SNEGLIA
SW 601OD
01/12/2024 13:33
CELL106
SW 601OD
01/12/2024 13:33
CELL106
SW 601OD
01/12/2024 13:33
CELL106
SW 601OD
01/12/2024 13:33
CELL106
SW 601OD
01/12/2024 13:33
CELL106
SW 6020B
01/12/2024 20:39
MHALL3
SW 6020B
01/12/2024 20:39
MHALL3
SW 6020E
01/12/2024 20:39
MHALL3
SW 6020B
01/12/2024 20:39
MHALL3
SW 6020E
01/12/2024 20:39
MHALL3
SW 6020B
01/12/2024 20:39
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS MW-4BR
Collection Date: 01/08/2024 01:10 PM Loc code: MNS MW-4BR
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24010176
Total Alkalinity as CaCO3 130 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24010111
Chloride
2.6
mg/L
0.5
0.0154
5
Sulfate
14
mg/L
0.5
0.0428
5
MERCURY (COLD VAPOR) IN WATER - Q24010118
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q24010121
Barium (Ba)
0.018
mg/L
0.005
0.002
1
Calcium (Ca)
9.05
mg/L
0.05
0.012
1
Magnesium (Mg)
1.78
mg/L
0.02
0.008
1
Potassium (K)
34.7
mg/L
1
0.031
10
Sodium (Na)
38.9
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010126
Arsenic (As)
0.311 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.62 J
ug/L
1
0.185
1
Lead (Pb)
0.037 U
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 20 of 149
Sample #: 2023031290
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320B 01/11/2024 11:06 SNEGLIA
EPA 9056A
01/10/2024 19:51
BGN9034
EPA 9056A
01/10/2024 19:51
BGN9034
EPA 7470A
01/10/2024 10:01
SNEGLIA
SW 601OD
01/11/2024 14:46
CELL106
SW 601OD
01/11/2024 14:46
CELL106
SW 601OD
01/11/2024 14:46
CELL106
SW 601OD
01/11/2024 14:46
CELL106
SW 601OD
01/11/2024 14:46
CELL106
SW 6020B
01/12/2024 17:44
MHALL3
SW 6020B
01/12/2024 17:44
MHALL3
SW 6020E
01/12/2024 17:44
MHALL3
SW 6020B
01/12/2024 17:44
MHALL3
SW 6020E
01/12/2024 17:44
MHALL3
SW 6020B
01/12/2024 17:44
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS MW-4BRR
Collection Date: 01/10/2024 02:15 PM Loc code: MNS MW-4BRR
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24010176
Total Alkalinity as CaCO3 600 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24010209
Chloride
32
mg/L
2
0.0154
20
Sulfate
910
mg/L
20
0.0428
200
MERCURY (COLD VAPOR) IN WATER - Q24010240
Mercury (Hg)
0.02 J
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q24010140
Barium (Ba)
0.075
mg/L
0.005
0.002
1
Calcium (Ca)
2.21
mg/L
0.05
0.012
1
Magnesium (Mg)
0.01 J
mg/L
0.02
0.008
1
Potassium (K)
218
mg/L
10
0.031
100
Sodium (Na)
646
mg/L
0.5
0.017
10
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010144
Arsenic (As)
4.19
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.186 J
ug/L
1
0.185
1
Lead (Pb)
0.038 J
ug/L
1
0.037
1
Selenium (Se)
0.332 J
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 21 of 149
Sample #: 2023031291
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320B 01/11/2024 11:11 SNEGLIA
EPA 9056A 01/17/2024 15:24 BGN9034
EPA 9056A 01/17/2024 15:24 BGN9034
EPA 7470A 01/18/2024 12:20 SNEGLIA
SW 601OD
01/12/2024 13:37
CELL106
SW 601OD
01/12/2024 13:37
CELL106
SW 601OD
01/12/2024 13:37
CELL106
SW 601OD
01/12/2024 13:37
CELL106
SW 601OD
01/12/2024 13:37
CELL106
SW 6020B
01/12/2024 20:48
MHALL3
SW 6020B
01/12/2024 20:48
MHALL3
SW 6020E
01/12/2024 20:48
MHALL3
SW 6020B
01/12/2024 20:48
MHALL3
SW 6020E
01/12/2024 20:48
MHALL3
SW 6020B
01/12/2024 20:48
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 22 of 149
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS MW-11 BR Sample #: 2023031292
Collection Date: 01/10/2024 12:05 PM Loc code: MNS MW-11BR Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
ALKALINITY (FIXED END POINT 4.5) - Q24010176
Total Alkalinity as CaCO3 51 mg/L 20 1.7 1 SM 2320B 01/11/2024 11:17 SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q24010209
Chloride
1.5
mg/L
0.1
0.0154
1
EPA 9056A
01/17/2024 14:37
BGN9034
Sulfate
2.5
mg/L
0.1
0.0428
1
EPA 9056A
01/17/2024 14:37
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24010240
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
01/18/2024 12:22
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24010140
Barium (Ba)
0.009
mg/L
0.005
0.002
1
SW 601OD
01/12/2024 13:41
CELLI06
Calcium (Ca)
8.26
mg/L
0.05
0.012
1
SW 601OD
01/12/2024 13:41
CELLI06
Magnesium (Mg)
2.19
mg/L
0.02
0.008
1
SW 601OD
01/12/2024 13:41
CELLI06
Potassium (K)
3.38
mg/L
0.1
0.031
1
SW 601OD
01/12/2024 13:41
CELLI06
Sodium (Na)
12.3
mg/L
0.05
0.017
1
SW 601OD
01/12/2024 13:41
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010144
Arsenic (As)
0.189 J
ug/L
1
0.111
1
SW 6020B
01/12/2024 20:58
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
01/12/2024 20:58
MHALL3
Chromium (Cr)
0.789 J
ug/L
1
0.185
1
SW 6020E
01/12/2024 20:58
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
01/12/2024 20:58
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020E
01/12/2024 20:58
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
01/12/2024 20:58
MHALL3
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS MW-13D
Collection Date: 01/08/2024 03:30 PM Loc code: MNS MW-13D
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24010176
Total Alkalinity as CaCO3 42 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24010111
Chloride
1.4
mg/L
0.1
0.0154
1
Sulfate
0.30
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q24010118
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q24010121
Barium (Ba)
0.017
mg/L
0.005
0.002
1
Calcium (Ca)
9.82
mg/L
0.05
0.012
1
Magnesium (Mg)
3.65
mg/L
0.02
0.008
1
Potassium (K)
0.584
mg/L
0.1
0.031
1
Sodium (Na)
5.05
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010126
Arsenic (As)
0.12 J
ug/L
1
0.111
1
Cadmium (Cd)
0.076 J
ug/L
1
0.032
1
Chromium (Cr)
0.505 J
ug/L
1
0.185
1
Lead (Pb)
0.073 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 23 of 149
Sample #: 2023031293
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320B 01/11/2024 11:20 SNEGLIA
EPA 9056A 01/10/2024 20:07 BGN9034
EPA 9056A 01/10/2024 20:07 BGN9034
EPA 7470A 01/10/2024 10:04 SNEGLIA
SW 601OD
01/11/2024 14:54
CELL106
SW 601OD
01/11/2024 14:54
CELL106
SW 601OD
01/11/2024 14:54
CELL106
SW 601OD
01/11/2024 14:54
CELL106
SW 601OD
01/11/2024 14:54
CELL106
SW 6020B
01/12/2024 17:52
MHALL3
SW 6020B
01/12/2024 17:52
MHALL3
SW 6020E
01/12/2024 17:52
MHALL3
SW 6020B
01/12/2024 17:52
MHALL3
SW 6020E
01/12/2024 17:52
MHALL3
SW 6020B
01/12/2024 17:52
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS MW-13BR
Collection Date: 01/08/2024 02:30 PM Loc code: MNS MW-13BR
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q24010176
Total Alkalinity as CaCO3 87 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q24010111
Chloride
3.2
mg/L
0.1
0.0154
1
Sulfate
6.7
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q24010118
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q24010121
Barium (Ba)
0.002 J
mg/L
0.005
0.002
1
Calcium (Ca)
27.0
mg/L
0.05
0.012
1
Magnesium (Mg)
5.43
mg/L
0.02
0.008
1
Potassium (K)
2.46
mg/L
0.1
0.031
1
Sodium (Na)
8.67
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010126
Arsenic (As)
0.115 J
ug/L
1
0.111
1
Cadmium (Cd)
0.064 J
ug/L
1
0.032
1
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
Lead (Pb)
0.119 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 24 of 149
Sample #: 2023031294
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320B 01/11/2024 11:24 SNEGLIA
EPA 9056A 01/10/2024 20:22 BGN9034
EPA 9056A 01/10/2024 20:22 BGN9034
EPA 7470A 01/10/2024 10:13 SNEGLIA
SW 601OD
01/11/2024 14:58
CELL106
SW 601OD
01/11/2024 14:58
CELL106
SW 601OD
01/11/2024 14:58
CELL106
SW 601OD
01/11/2024 14:58
CELL106
SW 601OD
01/11/2024 14:58
CELL106
SW 6020B
01/12/2024 18:01
MHALL3
SW 6020B
01/12/2024 18:01
MHALL3
SW 6020E
01/12/2024 18:01
MHALL3
SW 6020B
01/12/2024 18:01
MHALL3
SW 6020E
01/12/2024 18:01
MHALL3
SW 6020B
01/12/2024 18:01
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS_TB-20240110-0800 Trip Blank
Collection Date: 01/10/2024 08:00 AM Loc code: MNS TB
Analyte Result Units Qualifiers RDL MDL DF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 25 of 149
Sample #: 2023031295
Matrix: GW RCRA
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS_TB-20240108-0800 Trip Blank
Collection Date: 01/08/2024 08:00 AM Loc code: MNS TB
Analyte Result Units Qualifiers RDL MDL DF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 26 of 149
Sample #: 2023031297
Matrix: GW RCRA
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis Page 27 of 149
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS FB-20240108-1130 Field Blank Sample #: 2023031300
Collection Date: 01/08/2024 11:30 AM Loc code: MNS QA Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
LOW LEVEL ALKALINITY (FIXED END POINT) - Q24010210
Total Alkalinity as CaCO3 1.7 U mg/L 5 1.7 1 SM 2320134d 01/16/2024 14:26 CEIlio6
(CaCO3)
INORGANIC IONS BY IC - Q24010111
Chloride
0.03 J
mg/L
0.1
0.0154
1
EPA 9056A
01/10/2024 21:24
BGN9034
Sulfate
0.0428 U
mg/L
0.1
0.0428
1
EPA 9056A
01/10/2024 21:24
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24010118
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
01/10/2024 10:06
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24010121
Barium (Ba)
0.002 U
mg/L
0.005
0.002
1
SW 601OD
01/11/2024 15:10
CELLI06
Calcium (Ca)
0.012 U
mg/L
0.05
0.012
1
SW 601OD
01/11/2024 15:10
CELLI06
Magnesium (Mg)
0.008 U
mg/L
0.02
0.008
1
SW 601OD
01/11/2024 15:10
CELLI06
Potassium (K)
0.031 U
mg/L
0.1
0.031
1
SW 601OD
01/11/2024 15:10
CELLI06
Sodium (Na)
0.017 U
mg/L
0.05
0.017
1
SW 601OD
01/11/2024 15:10
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010126
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
01/12/2024 18:34
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
01/12/2024 18:34
MHALL3
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
SW 6020E
01/12/2024 18:34
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
01/12/2024 18:34
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020E
01/12/2024 18:34
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
01/12/2024 18:34
MHALL3
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 28 of 149
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS FB-20240110-1020 Field Blank Sample #: 2023031301
Collection Date: 01/10/2024 10:20 AM Loc code: MNS QA Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
LOW LEVEL ALKALINITY (FIXED END POINT) - Q24010210
Total Alkalinity as CaCO3 1.7 U mg/L 5 1.7 1 SM 2320134d 01/16/2024 14:32 CEIlio6
(CaCO3)
INORGANIC IONS BY IC - Q24010209
Chloride
0.03 J
mg/L
0.1
0.0154
1
EPA 9056A
01/17/2024 14:52
BGN9034
Sulfate
0.0428 U
mg/L
0.1
0.0428
1
EPA 9056A
01/17/2024 14:52
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24010240
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
01/18/2024 12:24
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24010140
Barium (Ba)
0.002 U
mg/L
0.005
0.002
1
SW 601OD
01/12/2024 13:45
CELLI06
Calcium (Ca)
0.012 U
mg/L
0.05
0.012
1
SW 601OD
01/12/2024 13:45
CELLI06
Magnesium (Mg)
0.008 U
mg/L
0.02
0.008
1
SW 601OD
01/12/2024 13:45
CELLI06
Potassium (K)
0.031 U
mg/L
0.1
0.031
1
SW 601OD
01/12/2024 13:45
CELLI06
Sodium (Na)
0.017 U
mg/L
0.05
0.017
1
SW 601OD
01/12/2024 13:45
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010144
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
01/12/2024 21:07
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
01/12/2024 21:07
MHALL3
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
SW 6020E
01/12/2024 21:07
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
01/12/2024 21:07
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020E
01/12/2024 21:07
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
01/12/2024 21:07
MHALL3
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 29 of 149
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS_FD-20240110-1 Duplicate Sample #: 2023031303
Collection Date: 01/10/2024 Loc code: MNS FD Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
LOW LEVEL ALKALINITY (FIXED END POINT) - Q24010210
Total Alkalinity as CaCO3 50.9 mg/L 5 1.7 1 SM 2320134d 01/16/2024 14:38 CEIlio6
(CaCO3)
INORGANIC IONS BY IC - Q24010209
Chloride
1.5
mg/L
0.1
0.0154
1
EPA 9056A
01/17/2024 11:14
BGN9034
Sulfate
2.5
mg/L
0.1
0.0428
1
EPA 9056A
01/17/2024 11:14
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24010240
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
01/18/2024 12:27
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24010140
Barium (Ba)
0.009
mg/L
0.005
0.002
1
SW 601OD
01/12/2024 13:48
CELLI06
Calcium (Ca)
8.29
mg/L
0.05
0.012
1
SW 601OD
01/12/2024 13:48
CELLI06
Magnesium (Mg)
2.20
mg/L
0.02
0.008
1
SW 601OD
01/12/2024 13:48
CELLI06
Potassium (K)
3.19
mg/L
0.1
0.031
1
SW 601OD
01/12/2024 13:48
CELLI06
Sodium (Na)
11.9
mg/L
0.05
0.017
1
SW 601OD
01/12/2024 13:48
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010144
Arsenic (As)
0.177 J
ug/L
1
0.111
1
SW 6020B
01/12/2024 21:16
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
01/12/2024 21:16
MHALL3
Chromium (Cr)
0.702 J
ug/L
1
0.185
1
SW 6020E
01/12/2024 21:16
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
01/12/2024 21:16
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020E
01/12/2024 21:16
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
01/12/2024 21:16
MHALL3
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 30 of 149
This report shall not be reproduced, except in full.
Order # J23120380
Site: MNS_FD-20240108-1 Duplicate Sample #: 2023031304
Collection Date: 01/08/2024 Loc code: MNS FD Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
LOW LEVEL ALKALINITY (FIXED END POINT) - Q24010210
Total Alkalinity as CaCO3 82.6 mg/L 5 1.7 1 SM 2320134d 01/16/2024 14:45 CEIlio6
(CaCO3)
INORGANIC IONS BY IC - Q24010111
Chloride
1.4
mg/L
0.1
0.0154
1
EPA 9056A
01/10/2024 21:40
BGN9034
Sulfate
0.77
mg/L
0.1
0.0428
1
EPA 9056A
01/10/2024 21:40
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q24010118
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
01/10/2024 10:20
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q24010121
Barium (Ba)
0.056
mg/L
0.005
0.002
1
SW 601OD
01/11/2024 15:15
CELLI06
Calcium (Ca)
20.0
mg/L
0.05
0.012
1
SW 601OD
01/11/2024 15:15
CELLI06
Magnesium (Mg)
5.33
mg/L
0.02
0.008
1
SW 601OD
01/11/2024 15:15
CELLI06
Potassium (K)
1.67
mg/L
0.1
0.031
1
SW 601OD
01/11/2024 15:15
CELLI06
Sodium (Na)
8.14
mg/L
0.05
0.017
1
SW 601OD
01/11/2024 15:15
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q24010126
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
01/12/2024 18:43
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
01/12/2024 18:43
MHALL3
Chromium (Cr)
0.5 J
ug/L
1
0.185
1
SW 6020E
01/12/2024 18:43
MHALL3
Lead (Pb)
1.43
ug/L
1
0.037
1
SW 6020B
01/12/2024 18:43
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020E
01/12/2024 18:43
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
01/12/2024 18:43
MHALL3
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an estimate.

Certificate of Laboratory Analysis Page 31 of 149
This report shall not be reproduced, except in full.
Order # J23120380
Level II QC Summary
Q24010176 ALK FIX4.5 ALKALINITY (FIXED END POINT 4.5)
Duplicate # 1
Parameter Measured Final
Total Alkalinity as CaCO3 52.6
Duplicate # 2
Parameter Measured Final
Total Alkalinity as CaCO3 85.6
LCS # 1
Parameter Measured Final
Total Alkalinity as CaCO3 33.1
LCS # 2
Units Dil MDL
mg/L 1 1.7
(CaCO3)
Units Dil MDL
mg/L 1 1.7
(CaCO3)
Parent Sample: J23120380 -- 2023031278
RPD
1.3
Parent Sample: J23120380 -- 2023031279
RPD
7.67
Units Dil MDL Spike % Recovery LCL UCL
mg/L 1 1.7 31 107 85 115
(CaCO3)
Qualifier
Qualifier
Qualifier
Parameter Measured Final Units Dil MDL Spike % Recovery LCL UCL Qualifier
Total Alkalinity as CaCO3 29.5 mg/L 1 1.7 31 95.1 85 115
(CaCO3)

Certificate of Laboratory Analysis Page 32 of 149
This report shall not be reproduced, except in full.
Order # J23120380
Level II QC Summary
Q24010210 ALK LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Duplicate # 1
Parent Sample: J23120380 -- 2023031282
Parameter
Measured
Final
Units
Dil
MDL RPD Qualifier
Total Alkalinity as CaCO3
8.51
8.51
mg/L
1
1.7 2.26
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL Spike % Recovery LCL UCL Qualifier
Total Alkalinity as CaCO3
28.3
28.3
mg/L
1
1.7 31 91.4 85 115
(CaCO3)

Certificate of Laboratory Analysis Page 33 of 149
This report shall not be reproduced, except in full.
Order # J23120380
Level II QC Summary
Q24010111 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Sulfate
0.001
0.001
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S Ike
% Recovery
LCL
UCL
Chloride
5.02
5.02
mg/L
1
0.0154
5
100
80
120
Sulfate
5.11
5.11
mg/L
1
0.0428
5
102
80
120
MS # 1
Parent Sample:
J23120380 -- 2023031274
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Chloride
7.7
7.7
mg/L
1
0.0154
5
101
80
120
Sulfate
5.3
5.3
mg/L
1
0.0428
5
97.5
80
120
MSD # 1
Parent Sample:
J23120380 -- 2023031274
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Chloride
7.7
7.7
mg/L
1
0.0154
5
101
80
120 0.0397
Sulfate
5.32
5.32
mg/L
1
0.0428
5
97.8
80
120 0.328
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 34 of 149
This report shall not be reproduced, except in full.
Order # J23120380
Level II QC Summary
Q24010209 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Sulfate
0
0
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S Ike
% Recovery
LCL
UCL
Chloride
5.05
5.05
mg/L
1
0.0154
5
101
80
120
Sulfate
5.13
5.13
mg/L
1
0.0428
5
103
80
120
MS # 1
Parent Sample:
J23120380 -- 2023031278
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Chloride
6.4
6.4
mg/L
1
0.0154
5
99.3
80
120
Sulfate
5.72
5.72
mg/L
1
0.0428
5
101
80
120
MSD # 1
Parent Sample:
J23120380 -- 2023031278
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Chloride
6.39
6.39
mg/L
1
0.0154
5
99.3
80
120 0.0403
Sulfate
5.76
5.76
mg/L
1
0.0428
5
102
80
120 0.768
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 35 of 149
This report shall not be reproduced, except in full.
Order # J23120380
Level II QC Summary
Q24010118 HG 7470 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Mercury (Hg)
-0.008
-0.008
Blank # 2
Parameter
Measured
Final
Mercury (Hg)
-0.007
-0.007
LCS # 1
MS # 1
MSD # 1
MS # 2
MSD # 2
Parameter Measured Final
Mercury (Hg) 1.98 1.98
Parameter Measured Final
Mercury (Hg) 1.05 1.05
Parameter Measured Final
Mercury (Hg) 1.06 1.06
Parameter Measured Final
Mercury (Hg) 0.985 0.985
Parameter Measured Final
Mercury (Hg) 0.992 0.992
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
ug/L
1
0.01
0.05
< MDL
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
ug/L
1
0.01
0.05
< MDL
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
ug/L
1
0.01
2
98.9
85 115
Parent Sample:
J23120380 -- 2023031274
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
ug/L
1
0.01
1
105
75 125
Parent Sample:
J23120380 -- 2023031274
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
ug/L
1
0.01
1
106
75 125 0.947
Parent Sample:
J23120380 -- 2023031294
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
ug/L
1
0.01
1
98.5
75 125
Parent Sample:
J23120380 -- 2023031294
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
ug/L
1
0.01
1
99.2
75 125 0.708

Certificate of Laboratory Analysis Page 36 of 149
This report shall not be reproduced, except in full.
Order # J23120380
Level II QC Summary
Q24010240 HG 7470 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.024
-0.024
ug/L
1
0.01
0.05
< MDL
Blank # 2
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.023
-0.023
ug/L
1
0.01
0.05
< MDL
Blank # 3
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.016
-0.016
ug/L
1
0.01
0.05
< MDL
Blank # 4
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.016
-0.016
ug/L
1
0.01
0.05
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery LCL UCL
Qualifier
Mercury (Hg)
2.07
2.07
ug/L
1
0.01
2
103 85 115
LCS # 2
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
2.06
2.06
ug/L
1
0.01
2
103
85 115
MS # 1
Parent Sample:
J23120263 -- 2023030805
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL UCL
Qualifier
Mercury (Hg)
0.93
0.93
ug/L
1
0.01
1
93
75 125
MSD # 1
Parent Sample:
J23120263 -- 2023030805
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.947
0.947
ug/L
1
0.01
1
94.7
75 125 1.81
MS # 2
Parent Sample:
J23120380 -- 2023031288
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.03
1.03
ug/L
1
0.01
1
103
75 125
MSD # 2
Parent Sample:
J23120380 -- 2023031288
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.03
1.03
ug/L
1
0.01
1
103
75 125 0.388
MS # 3
Parent Sample:
J24010205 -- 2024000732
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.998
0.998
ug/L
1
0.01
1
99.8
75 125

Certificate of Laboratory Analysis Page 37 of 149
This report shall not be reproduced, except in full.
Order # J23120380
Level II QC Summary
Q24010240 HG 7470 MERCURY (COLD VAPOR) IN WATER
MSD # 3
Parent Sample:
J24010205
-- 2024000732
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD Qualifier
Mercury (Hg)
0.969
0.969
ug/L
1
0.01
1
96.9
75
125 2.95
MS # 4
Parent Sample:
J24010210
-- 2024000770
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL Qualifier
Mercury (Hg)
1.04
1.04
ug/L
1
0.01
1
104
75
125
MSD # 4
Parent Sample:
J24010210
-- 2024000770
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD Qualifier
Mercury (Hg)
1.02
1.02
ug/L
1
0.01
1
103
75
125 1.55

Certificate of Laboratory Analysis Page 38 of 149
This report shall not be reproduced, except in full.
Order # J23120380
Level II QC Summary
Q24010138 ICP_DIS_TRM TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
0.000186
0.000186
mg/L
1
0.002
0.005
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
5.02
5.02
mg/L
1
0.002
5
100
80
120
MS # 1
Parent Sample:
J23120380 -- 2023031286
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
4.76
4.76
mg/L
1
0.002
5
94.7
70
130
MSD # 1
Parent Sample:
J23120380 -- 2023031286
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Barium (Ba)
4.85
4.85
mg/L
1
0.002
5
96.5
70
130 1.87
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 39 of 149
This report shall not be reproduced, except in full.
Order # J23120380
Level II QC Summary
Q24010121 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
-0.000042
-0.000042
mg/L
1
0.002
0.005
< MDL
Calcium (Ca)
0.002
0.002
mg/L
1
0.012
0.05
< MDL
Magnesium (Mg)
0.00133
0.00133
mg/L
1
0.008
0.02
< MDL
Potassium (K)
0.000549
0.000549
mg/L
1
0.031
0.1
< MDL
Sodium (Na)
-0.00812
-0.00812
mg/L
1
0.017
0.05
< MDL
LCS # 1
MS # 1
Parameter
Measured
Final
Units
Barium (Ba)
5.17
5.17
mg/L
Calcium (Ca)
4.82
4.82
mg/L
Magnesium (Mg)
5
5
mg/L
Potassium (K)
5.09
5.09
mg/L
Sodium (Na)
4.94
4.94
mg/L
Parameter
Measured
Final
Units
Barium (Ba)
5.37
5.37
mg/L
Calcium (Ca)
12.4
12.4
mg/L
Magnesium (Mg)
8.14
8.14
mg/L
Potassium (K)
6.37
6.37
mg/L
Sodium (Na)
10.9
10.9
mg/L
MSD # 1
Parameter
Measured
Final
Units
Barium (Ba)
5.44
5.44
mg/L
Calcium (Ca)
12.5
12.5
mg/L
Magnesium (Mg)
8.23
8.23
mg/L
Potassium (K)
6.42
6.42
mg/L
Sodium (Na)
11
11
mg/L
Dil
MDL
Spike
% Recovery
LCL
UCL
1
0.002
5
103
80
120
1
0.012
5
96.5
80
120
1
0.008
5
100
80
120
1
0.031
5
102
80
120
1
0.017
5
98.7
80
120
Parent Sample:
J23120380
-- 2023031274
Dil
MDL
Spike
% Recovery
LCL
UCL
1
0.002
5
103
75
125
1
0.012
5
101
75
125
1
0.008
5
96.5
75
125
1
0.031
5
102
75
125
1
0.017
5
98
75
125
Parent Sample:
J23120380
-- 2023031274
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
1
0.002
5
104
75
125
1.41
1
0.012
5
104
75
125
1.16
1
0.008
5
98.5
75
125
1.2
1
0.031
5
103
75
125
0.798
1
0.017
5
100
75
125
1.02
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 40 of 149
This report shall not be reproduced, except in full.
Order # J23120380
Level II QC Summary
Q24010140 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
0.00007
0.00007
mg/L
1
0.002
0.005
< MDL
Calcium (Ca)
0.00563
0.00563
mg/L
1
0.012
0.05
< MDL
Magnesium (Mg)
0.00944
0.00944
mg/L
1
0.008
0.02
> MDL
Potassium (K)
-0.0215
-0.0215
mg/L
1
0.031
0.1
< MDL
Sodium (Na)
-0.0124
-0.0124
mg/L
1
0.017
0.05
< MDL
LCS # 1
MS # 1
Parameter
Measured
Final
Units
Barium (Ba)
4.99
4.99
mg/L
Calcium (Ca)
5.07
5.07
mg/L
Magnesium (Mg)
5.06
5.06
mg/L
Potassium (K)
5.05
5.05
mg/L
Sodium (Na)
5
5
mg/L
Parameter
Measured
Final
Units
Barium (Ba)
5.35
5.35
mg/L
Calcium (Ca)
17.3
17.3
mg/L
Magnesium (Mg)
10.1
10.1
mg/L
Potassium (K)
8.65
8.65
mg/L
Sodium (Na)
11
11
mg/L
MSD # 1
Parameter
Measured
Final
Units
Barium (Ba)
5.07
5.07
mg/L
Calcium (Ca)
16.4
16.4
mg/L
Magnesium (Mg)
9.64
9.64
mg/L
Potassium (K)
8.21
8.21
mg/L
Sodium (Na)
10.4
10.4
mg/L
Dil
MDL
Spike
% Recovery
LCL
UCL
1
0.002
5
99.8
80
120
1
0.012
5
101
80
120
1
0.008
5
101
80
120
1
0.031
5
101
80
120
1
0.017
5
100
80
120
Parent Sample:
J23120380
-- 2023031278
Dil
MDL
Spike
% Recovery
LCL
UCL
1
0.002
5
106
75
125
1
0.012
5
116
75
125
1
0.008
5
111
75
125
1
0.031
5
110
75
125
1
0.017
5
112
75
125
Parent Sample:
J23120380
-- 2023031278
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
1
0.002
5
100
75
125
5.37
1
0.012
5
98
75
125
5.34
1
0.008
5
102
75
125
4.66
1
0.031
5
102
75
125
5.22
1
0.017
5
99.6
75
125
5.61
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 41 of 149
This report shall not be reproduced, except in full.
Order # J23120380
Level II QC Summary
Q24010141 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Blank # 1
LCS # 1
MS # 1
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Arsenic (As)
-0.009
-0.009
ug/L
1
0.111
1
< MDL
Cadmium (Cd)
0.003
0.003
ug/L
1
0.032
1
< MDL
Chromium (Cr)
-0.031
-0.031
ug/L
1
0.185
1
< MDL
Lead (Pb)
-0.001
-0.001
ug/L
1
0.037
1
< MDL
Silver (Ag)
-0.002
-0.002
ug/L
1
0.035
1
< MDL
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Arsenic (As)
46.4
46.4
ug/L
1
0.111
50
92.8
80
120
Cadmium (Cd)
48
48
ug/L
1
0.032
50
96.1
80
120
Chromium (Cr)
49.2
49.2
ug/L
1
0.185
50
98.5
80
120
Lead (Pb)
48.8
48.8
ug/L
1
0.037
50
97.6
80
120
Silver (Ag)
49
49
ug/L
1
0.035
50
97.9
80
120
Parent Sample:
J24010178 -- 2024000654
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Arsenic (As)
46.5
46.5
ug/L
1
0.111
50
92.2
75
125
Cadmium (Cd)
48
48
ug/L
1
0.032
50
95.9
75
125
Chromium (Cr)
48.4
48.4
ug/L
1
0.185
50
96.5
75
125
Lead (Pb)
48.5
48.5
ug/L
1
0.037
50
96.4
75
125
Silver (Ag)
47.9
47.9
ug/L
1
0.035
50
95.8
75
125
Parent Sample:
J24010178 -- 2024000654
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Arsenic (As)
45.9
45.9
ug/L
1
0.111
50
91.1
75
125
1.14
Cadmium (Cd)
48
48
ug/L
1
0.032
50
95.9
75
125
0.0354
Chromium (Cr)
48.6
48.6
ug/L
1
0.185
50
97
75
125
0.484
Lead (Pb)
49.2
49.2
ug/L
1
0.037
50
97.8
75
125
1.36
Silver (Ag)
48
48
ug/L
1
0.035
50
95.9
75
125
0.117
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 42 of 149
This report shall not be reproduced, except in full.
Order # J23120380
Level II QC Summary
Q24010126 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
LCS # 1
MS # 1
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Arsenic (As)
0.001
0.001
ug/L
1
0.111
1
< MDL
Cadmium (Cd)
0.011
0.011
ug/L
1
0.032
1
< MDL
Chromium (Cr)
-0.039
-0.039
ug/L
1
0.185
1
< MDL
Lead (Pb)
0.104
0.104
ug/L
1
0.037
1
> MDL
Selenium (Se)
0.018
0.018
ug/L
1
0.193
1
< MDL
Silver (Ag)
0.002
0.002
ug/L
1
0.035
1
< MDL
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Arsenic (As)
48.4
48.4
ug/L
1
0.111
50
96.8
80
120
Cadmium (Cd)
48.7
48.7
ug/L
1
0.032
50
97.4
80
120
Chromium (Cr)
48.3
48.3
ug/L
1
0.185
50
96.7
80
120
Lead (Pb)
48.8
48.8
ug/L
1
0.037
50
97.6
80
120
Selenium (Se)
51.4
51.4
ug/L
1
0.193
50
103
80
120
Silver (Ag)
48.9
48.9
ug/L
1
0.035
50
97.7
80
120
Parent Sample:
J23120380
-- 2023031275
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
Arsenic (As)
47.8
47.8
ug/L
1
0.111
50
95.1
75
125
Cadmium (Cd)
49.2
49.2
ug/L
1
0.032
50
98.4
75
125
Chromium (Cr)
50.2
50.2
ug/L
1
0.185
50
100
75
125
Lead (Pb)
49.6
49.6
ug/L
1
0.037
50
99.2
75
125
Selenium (Se)
45.1
45.1
ug/L
1
0.193
50
90.1
75
125
Silver (Ag)
49.8
49.8
ug/L
1
0.035
50
99.7
75
125
Parent Sample:
J23120380
-- 2023031275
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
RPD
Arsenic (As)
46.3
46.3
ug/L
1
0.111
50
92.2
75
125
3.14
Cadmium (Cd)
48.4
48.4
ug/L
1
0.032
50
96.6
75
125
1.79
Chromium (Cr)
48.4
48.4
ug/L
1
0.185
50
96.8
75
125
3.64
Lead (Pb)
48.2
48.2
ug/L
1
0.037
50
96.3
75
125
2.94
Selenium (Se)
45.4
45.4
ug/L
1
0.193
50
90.7
75
125
0.622
Silver (Ag)
48
48
ug/L
1
0.035
50
96
75
125
3.78
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 43 of 149
This report shall not be reproduced, except in full.
Order # J23120380
Level II QC Summary
Q24010144 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
LCS # 1
MS # 1
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Arsenic (As)
0.008
0.008
ug/L
1
0.111
1
< MDL
Cadmium (Cd)
0.003
0.003
ug/L
1
0.032
1
< MDL
Chromium (Cr)
-0.013
-0.013
ug/L
1
0.185
1
< MDL
Lead (Pb)
-0.003
-0.003
ug/L
1
0.037
1
< MDL
Selenium (Se)
-0.011
-0.011
ug/L
1
0.193
1
< MDL
Silver (Ag)
0.001
0.001
ug/L
1
0.035
1
< MDL
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Arsenic (As)
47.8
47.8
ug/L
1
0.111
50
95.5
80
120
Cadmium (Cd)
48
48
ug/L
1
0.032
50
96
80
120
Chromium (Cr)
48.8
48.8
ug/L
1
0.185
50
97.6
80
120
Lead (Pb)
49
49
ug/L
1
0.037
50
98
80
120
Selenium (Se)
47.6
47.6
ug/L
1
0.193
50
95.3
80
120
Silver (Ag)
48.6
48.6
ug/L
1
0.035
50
97.3
80
120
Parent Sample:
J23120380
-- 2023031279
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
Arsenic (As)
48.1
48.1
ug/L
1
0.111
50
96
75
125
Cadmium (Cd)
48
48
ug/L
1
0.032
50
96
75
125
Chromium (Cr)
48.3
48.3
ug/L
1
0.185
50
96.3
75
125
Lead (Pb)
49
49
ug/L
1
0.037
50
97.9
75
125
Selenium (Se)
46.9
46.9
ug/L
1
0.193
50
93.8
75
125
Silver (Ag)
48.5
48.5
ug/L
1
0.035
50
97.1
75
125
Parent Sample:
J23120380
-- 2023031279
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
RPD
Arsenic (As)
47.6
47.6
ug/L
1
0.111
50
95.1
75
125
1.02
Cadmium (Cd)
47.8
47.8
ug/L
1
0.032
50
95.7
75
125
0.355
Chromium (Cr)
48.4
48.4
ug/L
1
0.185
50
96.4
75
125
0.0892
Lead (Pb)
49
49
ug/L
1
0.037
50
98.1
75
125
0.155
Selenium (Se)
46.8
46.8
ug/L
1
0.193
50
93.6
75
125
0.196
Silver (Ag)
48.4
48.4
ug/L
1
0.035
50
96.9
75
125
0.214
Qualifier
Qualifier
Qualifier
Qualifier

�ce-
January 15, 2024
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Dear Program Manager:
Pace Analytical Services, LLC
P98904 'irWYhe. Suite 100
Huntersville, NC 28078
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on January 09, 2024. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace National - Mt. Juliet
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
ga
Lord Patton
[e-mail]
828-417-6055
Project Manager
Enclosures
AC4R�rp .
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 48

ace
Pace Analytical Services, LLC
pRaR0Air6ry,fqe. Suite 100
Huntersville, NC 28078
[phone]
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Pace Analytical Services National
12065 Lebanon Road, Mt. Juliet, TN 37122
Alabama Certification #: 40660
Alaska Certification 17-026
Arizona Certification #: AZ0612
Arkansas Certification #: 88-0469
California Certification #: 2932
Canada Certification #: 1461.01
Colorado Certification #: TN00003
Connecticut Certification #: PH-0197
DOD Certification: #1461.01
EPA# TN00003
Florida Certification #: E87487
Georgia DW Certification #: 923
Georgia Certification: NELAP
Idaho Certification #: TN00003
Illinois Certification #: 200008
Indiana Certification #: C-TN-01
Iowa Certification #: 364
Kansas Certification #: E-10277
Kentucky UST Certification #: 16
Kentucky Certification #: 90010
Louisiana Certification #: A130792
Louisiana DW Certification #: LA180010
Maine Certification #: TN0002
Maryland Certification #: 324
Massachusetts Certification #: M-TNO03
Michigan Certification #: 9958
Minnesota Certification #: 047-999-395
Mississippi Certification #: TN00003
Missouri Certification #: 340
Montana Certification M CERT0086
Nebraska Certification #: NE-OS-15-05
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
CERTIFICATIONS
Nevada Certification #: TN-03-2002-34
New Hampshire Certification #: 2975
New Jersey Certification #: TNO02
New Mexico DW Certification
New York Certification #: 11742
North Carolina Aquatic Toxicity Certification #: 41
North Carolina Drinking Water Certification #: 21704
North Carolina Environmental Certificate #: 375
North Dakota Certification #: R-140
Ohio VAP Certification #: CL0069
Oklahoma Certification #: 9915
Oregon Certification #: TN200002
Pennsylvania Certification #: 68-02979
Rhode Island Certification #: LA000356
South Carolina Certification #: 84004
South Dakota Certification
Tennessee DW/Chem/Micro Certification #: 2006
Texas Certification #: T 104704245-17-14
Texas Mold Certification #: LAB0152
USDA Soil Permit #: P330-15-00234
Utah Certification #: TN00003
Virginia Certification #: VT2006
Vermont Dept. of Health: ID# VT-2006
Virginia Certification #: 460132
Washington Certification #: C847
West Virginia Certification #: 233
Wisconsin Certification #: 998093910
Wyoming UST Certification #: via A21LA 2926.01
A21-A-ISO 17025 Certification #: 1461.01
A21-A-ISO 17025 Certification #: 1461.02
AIHA-LAP/LLC EMLAP Certification #:100789
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water* LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 48

ace
Pace Analytical Services, LLC
PdaR041� yhe. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92707485001
MW-1
Water
01/08/24 13:20
01/09/24 14:16
92707485002
MW-1 D
Water
01/08/24 13:00
01/09/24 14:16
92707485003
MW-2A
Water
01/08/24 10:40
01/09/24 14:16
92707485004
MW-211)
Water
01/08/24 09:40
01/09/24 14:16
92707485005
MW-4
Water
01/08/24 09:50
01/09/24 14:16
92707485006
MW-413
Water
01/08/2410:40
01/09/24 14:16
92707485007
SW-1
Water
01/08/24 14:00
01/09/24 14:16
92707485008
MNS TB-20240108-0800
Water
01/08/24 08:00
01/09/24 14:16
92707485009
MNS FB-20240108-1130
Water
01/08/2411:30
01/09/24 14:16
92707485010
MNS FD-20240108-1
Water
01/08/24 00:00
01/09/24 14:16
92707485011
MW-4BR
Water
01/08/2413:10
01/09/24 14:16
92707485012
MW-13D
Water
01/08/2415:30
01/09/24 14:16
92707485013
MW-13BR
Water
01/08/2414:30
01/09/24 14:16
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 48

ace
Pace Analytical Services, LLC
P989041 WeYhe. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J23120380 MNS Landfill #1
92707485
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92707485001
MW-1
EPA 8260D by SIM
TJJ
2
PAN
EPA 8260D
JJK
50
PASI-C
92707485002
MW-1D
EPA 8260D by SIM
TJJ
2
PAN
EPA 8260D
JJK
50
PASI-C
92707485003
MW-2A
EPA 8260D by SIM
TJJ
2
PAN
EPA 8260D
JJK
50
PASI-C
92707485004
MW-2D
EPA 8260D by SIM
TJJ
2
PAN
EPA 8260D
JJK
50
PASI-C
92707485005
MW-4
EPA 8260D by SIM
TJJ
2
PAN
EPA 8260D
JJK
50
PASI-C
92707485006
MW-4D
EPA 8260D by SIM
TJJ
2
PAN
EPA 8260D
JJK
50
PASI-C
92707485007
SW-1
EPA 8260D by SIM
TJJ
2
PAN
EPA 8260D
JJK
50
PASI-C
92707485008
MNS_TB-20240108-0800
EPA 8260D by SIM
TJJ
2
PAN
EPA 8260D
JJK
50
PASI-C
92707485009
MNS_FB-20240108-1130
EPA 8260D by SIM
TJJ
2
PAN
EPA 8260D
JJK
50
PASI-C
92707485010
MNS_FD-20240108-1
EPA 8260D by SIM
TJJ
2
PAN
EPA 8260D
JJK
50
PASI-C
92707485011
MW-413R
EPA 8260D by SIM
TJJ
2
PAN
EPA 8260D
JJK
50
PASI-C
92707485012
MW-13D
EPA 8260D by SIM
TJJ
2
PAN
EPA 8260D
JJK
50
PASI-C
92707485013
MW-13BR
EPA 8260D by SIM
TJJ
2
PAN
EPA 8260D
JJK
50
PASI-C
PAN = Pace National - Mt. Juliet
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 48

ace
Pace Analytical Services, LLC
P98904t WeYhe. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
J23120380 MNS Landfill #1
92707485
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92707485003
MW-2A
EPA 8260D
1,1-Dichloroethane
0.37J
ug/L
1.0
01/10/2419:19
92707485005
MW-4
EPA 8260D
Tetrachloroethene
1.6
ug/L
1.0
01/10/24 20:13
92707485006
MW-411)
EPA 8260D
Benzene
0.81 J
ug/L
1.0
01/10/24 20:31
EPA 8260D
cis-1,2-Dichloroethene
38.6
ug/L
1.0
01/10/24 20:31
EPA 8260D
Methylene Chloride
5.5
ug/L
5.0
01/10/24 20:31 C9
EPA 8260D
Tetrachloroethene
0.991
ug/L
1.0
01/10/24 20:31
EPA 8260D
Toluene
0.27J
ug/L
1.0
01/10/24 20:31
EPA 8260D
Trichloroethene
5.5
ug/L
1.0
01/10/24 20:31
EPA 8260D
Vinyl chloride
0.78J
ug/L
1.0
01/10/24 20:31
EPA 8260D
Xylene (Total)
25.8
ug/L
1.0
01/10/24 20:31
92707485011
MW-4BR
EPA 8260D
Benzene
0.94J
ug/L
1.0
01/10/24 21:25
EPA 8260D
1,1-Dichloroethane
0.78J
ug/L
1.0
01/10/24 21:25
EPA 8260D
cis-1,2-Dichloroethene
12.1
ug/L
1.0
01/10/24 21:25
EPA 8260D
Methylene Chloride
11.4
ug/L
5.0
01/10/24 21:25
EPA 8260D
Tetrachloroethene
0.41 J
ug/L
1.0
01/10/24 21:25
EPA 8260D
Trichloroethene
2.1
ug/L
1.0
01/10/24 21:25
EPA 8260D
Xylene (Total)
49.3
ug/L
1.0
01/10/24 21:25
92707485013
MW-13BR
EPA 8260D
cis-1,2-Dichloroethene
5.1
ug/L
1.0
01/10/24 21:44
EPA 8260D
Methylene Chloride
3.OJ
ug/L
5.0
01/10/24 21:44 C9
EPA 8260D
Tetrachloroethene
0.45J
ug/L
1.0
01/10/24 21:44
EPA 8260D
Trichloroethene
1.2
ug/L
1.0
01/10/24 21:44
EPA 8260D
Xylene (Total)
43.1
ug/L
1.0
01/10/24 21:44
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 5 of 48

ace
Pace Analytical Services, LLC
P98904t WeYhe. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Method: EPA 8260D by SIM
Description: VOA (GC/MS) 8260D-SIM
Client: Duke Energy
Date: January 15, 2024
General Information:
13 samples were analyzed for EPA 8260D by SIM by Pace National Mt. Juliet. All samples were received in acceptable condition with
any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of
this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 6 of 48

ace
Pace Analytical Services, LLC
PO05t Wylie. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Method: EPA 8260D
Description: 8260D MSV Low Level
Client: Duke Energy
Date: January 15, 2024
General Information:
13 samples were analyzed for EPA 8260D by Pace Analytical Services Charlotte. All samples were received in acceptable condition
with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end
of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
QC Batch: 824408
v2: The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated
samples and the sensitivity of the instrument was verified with a reporting limit check standard.
• BLANK (Lab ID: 4264298)
• 4-Methyl-2-pentanone (MIBK)
• lodomethane
• trans- 1,3-Dichloropropene
• MNS_FB-20240108-1130 (Lab ID: 92707485009)
• 4-Methyl-2-pentanone (MIBK)
• lodomethane
• trans- 1,3-Dichloropropene
• MNS_FD-20240108-1 (Lab ID: 92707485010)
• 4-Methyl-2-pentanone (MIBK)
• lodomethane
• trans- 1,3-Dichloropropene
• MNS_TB-20240108-0800 (Lab ID: 92707485008)
• 4-Methyl-2-pentanone (MIBK)
• lodomethane
• trans- 1,3-Dichloropropene
• MW-1 (Lab ID: 92707485001)
• 4-Methyl-2-pentanone (MIBK)
• lodomethane
• trans- 1,3-Dichloropropene
• MW-13BR (Lab ID: 92707485013)
• 4-Methyl-2-pentanone (MIBK)
• lodomethane
• trans- 1,3-Dichloropropene
• MW-13D (Lab ID: 92707485012)
• 4-Methyl-2-pentanone (MIBK)
• lodomethane
• trans- 1,3-Dichloropropene
• MW-1D (Lab ID: 92707485002)
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 7 of 48

ace
Pace Analytical Services, LLC
Pdago5 rpyhe. Suite 100
�J Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Method: EPA 8260D
Description: 8260D MSV Low Level
Client: Duke Energy
Date: January 15, 2024
QC Batch: 824408
v2: The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated
samples and the sensitivity of the instrument was verified with a reporting limit check standard.
• 4-Methyl-2-pentanone (MIBK)
• lodomethane
• trans- 1,3-Dichloropropene
• MW-2A (Lab ID: 92707485003)
• 4-Methyl-2-pentanone (MIBK)
• lodomethane
• trans- 1,3-Dichloropropene
• MW-21D (Lab ID: 92707485004)
• 4-Methyl-2-pentanone (MIBK)
• lodomethane
• trans- 1,3-Dichloropropene
• MW-4 (Lab ID: 92707485005)
• 4-Methyl-2-pentanone (MIBK)
• lodomethane
• trans- 1,3-Dichloropropene
• MW-4BR (Lab ID: 92707485011)
• 4-Methyl-2-pentanone (MIBK)
• lodomethane
• trans- 1,3-Dichloropropene
• MW-41D (Lab ID: 92707485006)
• 4-Methyl-2-pentanone (MIBK)
• lodomethane
• trans- 1,3-Dichloropropene
• SW-1 (Lab ID: 92707485007)
• 4-Methyl-2-pentanone (MIBK)
• lodomethane
• trans- 1,3-Dichloropropene
v3: The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated
samples may have low bias.
• LCS (Lab ID: 4264299)
• 4-Methyl-2-pentanone (MIBK)
• lodomethane
• trans- 1,3-Dichloropropene
• MS (Lab ID: 4264300)
• lodomethane
• MSD (Lab ID: 4264301)
• lodomethane
• MW-1 (Lab ID: 92707485001)
• lodomethane
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 8 of 48

ace
Pace Analytical Services, LLC
PARYWYhe. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Method: EPA 8260D
Description: 8260D MSV Low Level
Client: Duke Energy
Date: January 15, 2024
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: 824408
C9: Common Laboratory Contaminant.
• MW-13BR (Lab ID: 92707485013)
• Methylene Chloride
• MW-41D (Lab ID: 92707485006)
• Methylene Chloride
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 9 of 48

ace
Pace Analytical Services, LLC
PAR%Ywyhe. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: MW-1 Lab ID: 92707485001 Collected: 01/08/24 13:20 Received: 01/09/24 14:16 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
1,4-Dioxane (p-Dioxane)
ND
ug/L
3.00
0.597
1 01/12/24 17:49
01/12/24 17:49
123-91-1
Surrogates
Toluene-d8 (S)
93.8
%
77.0-127
1 01/12/24 17:49
01/12/24 17:49
2037-26-5
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
01/10/24 18:42
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
01/10/24 18:42
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
01/10/24 18:42
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
01/10/24 18:42
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
01/10/24 18:42
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
01/10/24 18:42
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
01/10/24 18:42
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
01/10/24 18:42
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
01/10/24 18:42
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
01/10/24 18:42
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
01/10/24 18:42
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
01/10/24 18:42
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
01/10/24 18:42
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
01/10/24 18:42
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
01/10/24 18:42
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
01/10/24 18:42
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
01/10/24 18:42
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
01/10/24 18:42
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
01/10/24 18:42
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
01/10/24 18:42
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
01/10/24 18:42
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
01/10/24 18:42
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
01/10/24 18:42
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
01/10/24 18:42
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
01/10/24 18:42
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
01/10/24 18:42
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
01/10/24 18:42
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
01/10/24 18:42
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
01/10/24 18:42
10061-02-6 v2
Ethylbenzene
ND
ug/L
1.0
0.30
1
01/10/24 18:42
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
01/10/24 18:42
591-78-6
Iodomethane
ND
ug/L
20.0
9.7
1
01/10/24 18:42
74-88-4 v2,v3
Methylene Chloride
ND
ug/L
5.0
2.0
1
01/10/24 18:42
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
01/10/24 18:42
108-10-1 v2
Styrene
ND
ug/L
1.0
0.29
1
01/10/24 18:42
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
01/10/24 18:42
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
01/10/24 18:42
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
01/10/24 18:42
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
01/10/24 18:42
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/15/2024 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 48

ace
Pace Analytical Services, LLC
Pdag0Aiirpyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: MW-1
Lab ID:
92707485001
Collected:
01/08/24 13:20
Received: 01/09/24 14:16 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/10/24 18:42
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/10/24 18:42
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
01/10/24 18:42
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/10/24 18:42
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/10/24 18:42
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/10/24 18:42
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/10/24 18:42
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
01/10/24 18:42
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
98
%
70-130
1
01/10/24 18:42
460-00-4
1,2-Dichloroethane-d4 (S)
96
%
70-130
1
01/10/24 18:42
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
01/10/24 18:42
2037-26-5
Date: 01/15/2024 01:42 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 48

ace
Pace Analytical Services, LLC
POO Wylie. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: MW-11) Lab ID: 92707485002 Collected: 01/08/24 13:00 Received: 01/09/24 14:16 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
1,4-Dioxane (p-Dioxane)
ND
ug/L
3.00
0.597
1 01/12/24 18:10
01/12/24 18:10
123-91-1
Surrogates
Toluene-d8 (S)
93.9
%
77.0-127
1 01/12/24 18:10
01/12/24 18:10
2037-26-5
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
01/10/24 19:00
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
01/10/24 19:00
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
01/10/24 19:00
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
01/10/24 19:00
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
01/10/24 19:00
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
01/10/24 19:00
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
01/10/24 19:00
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
01/10/24 19:00
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
01/10/24 19:00
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
01/10/24 19:00
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
01/10/24 19:00
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
01/10/24 19:00
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
01/10/24 19:00
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
01/10/24 19:00
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
01/10/24 19:00
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
01/10/24 19:00
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
01/10/24 19:00
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
01/10/24 19:00
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
01/10/24 19:00
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
01/10/24 19:00
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
01/10/24 19:00
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
01/10/24 19:00
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
01/10/24 19:00
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
01/10/24 19:00
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
01/10/24 19:00
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
01/10/24 19:00
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
01/10/24 19:00
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
01/10/24 19:00
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
01/10/24 19:00
10061-02-6 v2
Ethylbenzene
ND
ug/L
1.0
0.30
1
01/10/24 19:00
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
01/10/24 19:00
591-78-6
Iodomethane
ND
ug/L
20.0
9.7
1
01/10/24 19:00
74-88-4 v2
Methylene Chloride
ND
ug/L
5.0
2.0
1
01/10/24 19:00
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
01/10/24 19:00
108-10-1 v2
Styrene
ND
ug/L
1.0
0.29
1
01/10/24 19:00
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
01/10/24 19:00
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
01/10/24 19:00
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
01/10/24 19:00
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
01/10/24 19:00
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/15/2024 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 48

ace
Pace Analytical Services, LLC
pdagVirpyhe. Suite 100
��JJ Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: MWAD
Lab ID:
92707485002
Collected:
01/08/24 13:00
Received: 01/09/24 14:16 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/10/24 19:00
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/10/24 19:00
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
01/10/24 19:00
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/10/24 19:00
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/10/24 19:00
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/10/24 19:00
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/10/24 19:00
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
01/10/24 19:00
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
01/10/24 19:00
460-00-4
1,2-Dichloroethane-d4 (S)
100
%
70-130
1
01/10/24 19:00
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
01/10/24 19:00
2037-26-5
Date: 01/15/2024 01:42 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 13 of 48

ace
Pace Analytical Services, LLC
PdagvrwYhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: MW-2A Lab ID: 92707485003 Collected: 01/08/24 10:40 Received: 01/09/24 14:16 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
1,4-Dioxane (p-Dioxane)
ND
ug/L
3.00
0.597
1 01/12/24 18:32
01/12/24 18:32
123-91-1
Surrogates
Toluene-d8 (S)
93.9
%
77.0-127
1 01/12/24 18:32
01/12/24 18:32
2037-26-5
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
01/10/24 19:19
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
01/10/24 19:19
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
01/10/24 19:19
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
01/10/24 19:19
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
01/10/24 19:19
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
01/10/24 19:19
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
01/10/24 19:19
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
01/10/24 19:19
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
01/10/24 19:19
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
01/10/24 19:19
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
01/10/24 19:19
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
01/10/24 19:19
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
01/10/24 19:19
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
01/10/24 19:19
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
01/10/24 19:19
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
01/10/24 19:19
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
01/10/24 19:19
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
01/10/24 19:19
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
01/10/24 19:19
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
01/10/24 19:19
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
01/10/24 19:19
110-57-6
1,1-Dichloroethane
0.37J
ug/L
1.0
0.37
1
01/10/24 19:19
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
01/10/24 19:19
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
01/10/24 19:19
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
01/10/24 19:19
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
01/10/24 19:19
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
01/10/24 19:19
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
01/10/24 19:19
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
01/10/24 19:19
10061-02-6 v2
Ethylbenzene
ND
ug/L
1.0
0.30
1
01/10/24 19:19
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
01/10/24 19:19
591-78-6
Iodomethane
ND
ug/L
20.0
9.7
1
01/10/24 19:19
74-88-4 v2
Methylene Chloride
ND
ug/L
5.0
2.0
1
01/10/24 19:19
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
01/10/24 19:19
108-10-1 v2
Styrene
ND
ug/L
1.0
0.29
1
01/10/24 19:19
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
01/10/24 19:19
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
01/10/24 19:19
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
01/10/24 19:19
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
01/10/24 19:19
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/15/2024 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 48

ace
Pace Analytical Services, LLC
P�B� nhe. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: MW-2A
Lab ID:
92707485003
Collected:
01/08/24 10:40
Received: 01/09/24 14:16 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/10/24 19:19
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/10/24 19:19
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
01/10/24 19:19
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/10/24 19:19
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/10/24 19:19
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/10/24 19:19
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/10/24 19:19
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
01/10/24 19:19
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
97
%
70-130
1
01/10/24 19:19
460-00-4
1,2-Dichloroethane-d4 (S)
97
%
70-130
1
01/10/24 19:19
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
01/10/24 19:19
2037-26-5
Date: 01/15/2024 01:42 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 15 of 48

ace
Pace Analytical Services, LLC
PAMrWyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: MW-21) Lab ID: 92707485004 Collected: 01/08/24 09:40 Received: 01/09/24 14:16 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
1,4-Dioxane (p-Dioxane)
ND
ug/L
3.00
0.597
1 01/12/24 18:53
01/12/24 18:53
123-91-1
Surrogates
Toluene-d8 (S)
91.3
%
77.0-127
1 01/12/24 18:53
01/12/24 18:53
2037-26-5
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
01/10/24 19:37
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
01/10/24 19:37
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
01/10/24 19:37
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
01/10/24 19:37
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
01/10/24 19:37
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
01/10/24 19:37
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
01/10/24 19:37
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
01/10/24 19:37
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
01/10/24 19:37
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
01/10/24 19:37
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
01/10/24 19:37
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
01/10/24 19:37
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
01/10/24 19:37
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
01/10/24 19:37
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
01/10/24 19:37
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
01/10/24 19:37
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
01/10/24 19:37
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
01/10/24 19:37
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
01/10/24 19:37
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
01/10/24 19:37
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
01/10/24 19:37
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
01/10/24 19:37
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
01/10/24 19:37
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
01/10/24 19:37
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
01/10/24 19:37
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
01/10/24 19:37
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
01/10/24 19:37
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
01/10/24 19:37
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
01/10/24 19:37
10061-02-6 v2
Ethylbenzene
ND
ug/L
1.0
0.30
1
01/10/24 19:37
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
01/10/24 19:37
591-78-6
Iodomethane
ND
ug/L
20.0
9.7
1
01/10/24 19:37
74-88-4 v2
Methylene Chloride
ND
ug/L
5.0
2.0
1
01/10/24 19:37
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
01/10/24 19:37
108-10-1 v2
Styrene
ND
ug/L
1.0
0.29
1
01/10/24 19:37
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
01/10/24 19:37
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
01/10/24 19:37
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
01/10/24 19:37
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
01/10/24 19:37
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/15/2024 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 48

ace
Pace Analytical Services, LLC
PdagvirwYhe. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: MW-211)
Lab ID:
92707485004
Collected:
01/08/24 09:40
Received: 01/09/24 14:16 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/10/24 19:37
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/10/24 19:37
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
01/10/24 19:37
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/10/24 19:37
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/10/24 19:37
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/10/24 19:37
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/10/24 19:37
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
01/10/24 19:37
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
97
%
70-130
1
01/10/24 19:37
460-00-4
1,2-Dichloroethane-d4 (S)
98
%
70-130
1
01/10/24 19:37
17060-07-0
Toluene-d8 (S)
98
%
70-130
1
01/10/24 19:37
2037-26-5
Date: 01/15/2024 01:42 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 17 of 48

ace
Pace Analytical Services, LLC
PdagmirpYh.. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: MW-4 Lab ID: 92707485005 Collected: 01/08/24 09:50 Received: 01/09/24 14:16 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
1,4-Dioxane (p-Dioxane)
ND
ug/L
3.00
0.597
1 01/12/24 19:15
01/12/24 19:15
123-91-1
Surrogates
Toluene-d8 (S)
95.4
%
77.0-127
1 01/12/24 19:15
01/12/24 19:15
2037-26-5
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
01/10/24 20:13
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
01/10/24 20:13
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
01/10/24 20:13
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
01/10/24 20:13
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
01/10/24 20:13
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
01/10/24 20:13
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
01/10/24 20:13
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
01/10/24 20:13
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
01/10/24 20:13
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
01/10/24 20:13
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
01/10/24 20:13
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
01/10/24 20:13
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
01/10/24 20:13
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
01/10/24 20:13
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
01/10/24 20:13
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
01/10/24 20:13
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
01/10/24 20:13
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
01/10/24 20:13
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
01/10/24 20:13
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
01/10/24 20:13
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
01/10/24 20:13
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
01/10/24 20:13
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
01/10/24 20:13
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
01/10/24 20:13
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
01/10/24 20:13
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
01/10/24 20:13
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
01/10/24 20:13
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
01/10/24 20:13
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
01/10/24 20:13
10061-02-6 v2
Ethylbenzene
ND
ug/L
1.0
0.30
1
01/10/24 20:13
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
01/10/24 20:13
591-78-6
Iodomethane
ND
ug/L
20.0
9.7
1
01/10/24 20:13
74-88-4 v2
Methylene Chloride
ND
ug/L
5.0
2.0
1
01/10/24 20:13
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
01/10/24 20:13
108-10-1 v2
Styrene
ND
ug/L
1.0
0.29
1
01/10/24 20:13
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
01/10/24 20:13
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
01/10/24 20:13
79-34-5
Tetrachloroethene
1.6
ug/L
1.0
0.29
1
01/10/24 20:13
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
01/10/24 20:13
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/15/2024 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 48

ace
Pace Analytical Services, LLC
PAR19rWyhe. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: MW-4
Lab ID:
92707485005
Collected:
01/08/24 09:50
Received: 01/09/24 14:16 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/10/24 20:13
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/10/24 20:13
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
01/10/24 20:13
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/10/24 20:13
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/10/24 20:13
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/10/24 20:13
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/10/24 20:13
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
01/10/24 20:13
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
92
%
70-130
1
01/10/24 20:13
460-00-4
1,2-Dichloroethane-d4 (S)
98
%
70-130
1
01/10/24 20:13
17060-07-0
Toluene-d8 (S)
98
%
70-130
1
01/10/24 20:13
2037-26-5
Date: 01/15/2024 01:42 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 19 of 48

ace
Pace Analytical Services, LLC
P98HISrWyhe. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: MW-41) Lab ID: 92707485006 Collected: 01/08/24 10:40 Received: 01/09/24 14:16 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
1,4-Dioxane (p-Dioxane)
ND
ug/L
3.00
0.597
1 01/12/24 19:37
01/12/24 19:37
123-91-1
Surrogates
Toluene-d8 (S)
96.9
%
77.0-127
1 01/12/24 19:37
01/12/24 19:37
2037-26-5
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
01/10/24 20:31
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
01/10/24 20:31
107-13-1
Benzene
0.81J
ug/L
1.0
0.34
1
01/10/24 20:31
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
01/10/24 20:31
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
01/10/24 20:31
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
01/10/24 20:31
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
01/10/24 20:31
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
01/10/24 20:31
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
01/10/24 20:31
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
01/10/24 20:31
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
01/10/24 20:31
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
01/10/24 20:31
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
01/10/24 20:31
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
01/10/24 20:31
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
01/10/24 20:31
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
01/10/24 20:31
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
01/10/24 20:31
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
01/10/24 20:31
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
01/10/24 20:31
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
01/10/24 20:31
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
01/10/24 20:31
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
01/10/24 20:31
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
01/10/24 20:31
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
01/10/24 20:31
75-35-4
cis-1,2-Dichloroethene
38.6
ug/L
1.0
0.38
1
01/10/24 20:31
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
01/10/24 20:31
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
01/10/24 20:31
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
01/10/24 20:31
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
01/10/24 20:31
10061-02-6
v2
Ethylbenzene
ND
ug/L
1.0
0.30
1
01/10/24 20:31
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
01/10/24 20:31
591-78-6
Iodomethane
ND
ug/L
20.0
9.7
1
01/10/24 20:31
74-88-4
v2
Methylene Chloride
5.5
ug/L
5.0
2.0
1
01/10/24 20:31
75-09-2
C9
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
01/10/24 20:31
108-10-1
v2
Styrene
ND
ug/L
1.0
0.29
1
01/10/24 20:31
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
01/10/24 20:31
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
01/10/24 20:31
79-34-5
Tetrachloroethene
0.991
ug/L
1.0
0.29
1
01/10/24 20:31
127-18-4
Toluene
0.27J
ug/L
1.0
0.24
1
01/10/24 20:31
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/15/2024 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 48

ace
Pace Analytical Services, LLC
pdagl pyhe. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: MW-411)
Lab ID:
92707485006
Collected:
01/08/24 10:40
Received: 01/09/24 14:16 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/10/24 20:31
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/10/24 20:31
79-00-5
Trichloroethene
5.5
ug/L
1.0
0.38
1
01/10/24 20:31
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/10/24 20:31
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/10/24 20:31
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/10/24 20:31
108-05-4
Vinyl chloride
0.78J
ug/L
1.0
0.39
1
01/10/24 20:31
75-01-4
Xylene (Total)
25.8
ug/L
1.0
0.34
1
01/10/24 20:31
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
01/10/24 20:31
460-00-4
1,2-Dichloroethane-d4 (S)
99
%
70-130
1
01/10/24 20:31
17060-07-0
Toluene-d8 (S)
98
%
70-130
1
01/10/24 20:31
2037-26-5
Date: 01/15/2024 01:42 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 21 of 48

ace
Pace Analytical Services, LLC
PAR18rWyhe. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: SW-1 Lab ID: 92707485007 Collected: 01/08/24 14:00 Received: 01/09/24 14:16 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
1,4-Dioxane (p-Dioxane)
ND
ug/L
3.00
0.597
1 01/12/24 19:58
01/12/24 19:58
123-91-1
Surrogates
Toluene-d8 (S)
94.4
%
77.0-127
1 01/12/24 19:58
01/12/24 19:58
2037-26-5
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
01/10/24 20:49
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
01/10/24 20:49
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
01/10/24 20:49
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
01/10/24 20:49
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
01/10/24 20:49
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
01/10/24 20:49
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
01/10/24 20:49
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
01/10/24 20:49
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
01/10/24 20:49
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
01/10/24 20:49
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
01/10/24 20:49
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
01/10/24 20:49
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
01/10/24 20:49
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
01/10/24 20:49
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
01/10/24 20:49
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
01/10/24 20:49
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
01/10/24 20:49
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
01/10/24 20:49
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
01/10/24 20:49
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
01/10/24 20:49
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
01/10/24 20:49
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
01/10/24 20:49
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
01/10/24 20:49
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
01/10/24 20:49
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
01/10/24 20:49
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
01/10/24 20:49
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
01/10/24 20:49
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
01/10/24 20:49
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
01/10/24 20:49
10061-02-6 v2
Ethylbenzene
ND
ug/L
1.0
0.30
1
01/10/24 20:49
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
01/10/24 20:49
591-78-6
Iodomethane
ND
ug/L
20.0
9.7
1
01/10/24 20:49
74-88-4 v2
Methylene Chloride
ND
ug/L
5.0
2.0
1
01/10/24 20:49
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
01/10/24 20:49
108-10-1 v2
Styrene
ND
ug/L
1.0
0.29
1
01/10/24 20:49
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
01/10/24 20:49
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
01/10/24 20:49
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
01/10/24 20:49
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
01/10/24 20:49
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/15/2024 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 48

ace
Pace Analytical Services, LLC
Pdag%larpyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: SW-1
Lab ID:
92707485007
Collected:
01/08/24 14:00
Received: 01/09/24 14:16 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/10/24 20:49
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/10/24 20:49
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
01/10/24 20:49
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/10/24 20:49
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/10/24 20:49
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/10/24 20:49
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/10/24 20:49
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
01/10/24 20:49
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
98
%
70-130
1
01/10/24 20:49
460-00-4
1,2-Dichloroethane-d4 (S)
98
%
70-130
1
01/10/24 20:49
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
01/10/24 20:49
2037-26-5
Date: 01/15/2024 01:42 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 23 of 48

ace
Pace Analytical Services, LLC
PdagvrwYhe. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: MNS_TB-20240108-0800 Lab ID: 92707485008 Collected: 01/08/24 08:00 Received: 01/09/24 14:16 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 01/15/2024 01:42 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND
ug/L
3.00
0.597
1 01/12/24 20:20
01/12/24 20:20
123-91-1
93.5
%
77.0-127
1 01/12/24 20:20
01/12/24 20:20
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
01/10/2418:06
67-64-1
ND
ug/L
10.0
1.8
1
01/10/2418:06
107-13-1
ND
ug/L
1.0
0.34
1
01/10/2418:06
71-43-2
ND
ug/L
1.0
0.47
1
01/10/2418:06
74-97-5
ND
ug/L
1.0
0.31
1
01/10/2418:06
75-27-4
ND
ug/L
1.0
0.34
1
01/10/2418:06
75-25-2
ND
ug/L
2.0
1.7
1
01/10/2418:06
74-83-9
ND
ug/L
5.0
4.0
1
01/10/2418:06
78-93-3
ND
ug/L
2.0
0.36
1
01/10/2418:06
75-15-0
ND
ug/L
1.0
0.33
1
01/10/2418:06
56-23-5
ND
ug/L
1.0
0.28
1
01/10/2418:06
108-90-7
ND
ug/L
1.0
0.65
1
01/10/2418:06
75-00-3
ND
ug/L
1.0
0.43
1
01/10/2418:06
67-66-3
ND
ug/L
1.0
0.54
1
01/10/2418:06
74-87-3
ND
ug/L
2.0
0.34
1
01/10/2418:06
96-12-8
ND
ug/L
1.0
0.36
1
01/10/2418:06
124-48-1
ND
ug/L
1.0
0.27
1
01/10/2418:06
106-93-4
ND
ug/L
1.0
0.39
1
01/10/2418:06
74-95-3
ND
ug/L
1.0
0.34
1
01/10/2418:06
95-50-1
ND
ug/L
1.0
0.33
1
01/10/2418:06
106-46-7
ND
ug/L
1.0
0.56
1
01/10/2418:06
110-57-6
ND
ug/L
1.0
0.37
1
01/10/2418:06
75-34-3
ND
ug/L
1.0
0.32
1
01/10/2418:06
107-06-2
ND
ug/L
1.0
0.35
1
01/10/2418:06
75-35-4
ND
ug/L
1.0
0.38
1
01/10/2418:06
156-59-2
ND
ug/L
1.0
0.40
1
01/10/2418:06
156-60-5
ND
ug/L
1.0
0.36
1
01/10/2418:06
78-87-5
ND
ug/L
1.0
0.36
1
01/10/2418:06
10061-01-5
ND
ug/L
1.0
0.36
1
01/10/2418:06
10061-02-6 v2
ND
ug/L
1.0
0.30
1
01/10/2418:06
100-41-4
ND
ug/L
5.0
0.48
1
01/10/2418:06
591-78-6
ND
ug/L
20.0
9.7
1
01/10/2418:06
74-88-4 v2
ND
ug/L
5.0
2.0
1
01/10/2418:06
75-09-2
ND
ug/L
5.0
2.7
1
01/10/2418:06
108-10-1 v2
ND
ug/L
1.0
0.29
1
01/10/2418:06
100-42-5
ND
ug/L
1.0
0.31
1
01/10/2418:06
630-20-6
ND
ug/L
1.0
0.22
1
01/10/2418:06
79-34-5
ND
ug/L
1.0
0.29
1
01/10/2418:06
127-18-4
ND
ug/L
1.0
0.24
1
01/10/2418:06
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 24 of 48

ace
Pace Analytical Services, LLC
P9891618rwyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: MNS_TB-20240108-0800
Lab ID:
92707485008
Collected:
01/08/24
08:00
Received: 01/09/24 14:16 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/10/24 18:06
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/10/24 18:06
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
01/10/24 18:06
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/10/24 18:06
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/10/24 18:06
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/10/24 18:06
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/10/24 18:06
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
01/10/24 18:06
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
98
%
70-130
1
01/10/24 18:06
460-00-4
1,2-Dichloroethane-d4 (S)
96
%
70-130
1
01/10/24 18:06
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
01/10/24 18:06
2037-26-5
Date: 01/15/2024 01:42 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 25 of 48

ace
Pace Analytical Services, LLC
PAR16rWyhe. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: MNS_FB-20240108-1130 Lab ID: 92707485009 Collected: 01/08/24 11:30 Received: 01/09/24 14:16 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 01/15/2024 01:42 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND
ug/L
3.00
0.597
1 01/12/24 20:42
01/12/24 20:42
123-91-1
94.6
%
77.0-127
1 01/12/24 20:42
01/12/24 20:42
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
01/10/2418:24
67-64-1
ND
ug/L
10.0
1.8
1
01/10/2418:24
107-13-1
ND
ug/L
1.0
0.34
1
01/10/2418:24
71-43-2
ND
ug/L
1.0
0.47
1
01/10/2418:24
74-97-5
ND
ug/L
1.0
0.31
1
01/10/2418:24
75-27-4
ND
ug/L
1.0
0.34
1
01/10/2418:24
75-25-2
ND
ug/L
2.0
1.7
1
01/10/2418:24
74-83-9
ND
ug/L
5.0
4.0
1
01/10/2418:24
78-93-3
ND
ug/L
2.0
0.36
1
01/10/2418:24
75-15-0
ND
ug/L
1.0
0.33
1
01/10/2418:24
56-23-5
ND
ug/L
1.0
0.28
1
01/10/2418:24
108-90-7
ND
ug/L
1.0
0.65
1
01/10/2418:24
75-00-3
ND
ug/L
1.0
0.43
1
01/10/2418:24
67-66-3
ND
ug/L
1.0
0.54
1
01/10/2418:24
74-87-3
ND
ug/L
2.0
0.34
1
01/10/2418:24
96-12-8
ND
ug/L
1.0
0.36
1
01/10/2418:24
124-48-1
ND
ug/L
1.0
0.27
1
01/10/2418:24
106-93-4
ND
ug/L
1.0
0.39
1
01/10/2418:24
74-95-3
ND
ug/L
1.0
0.34
1
01/10/2418:24
95-50-1
ND
ug/L
1.0
0.33
1
01/10/2418:24
106-46-7
ND
ug/L
1.0
0.56
1
01/10/2418:24
110-57-6
ND
ug/L
1.0
0.37
1
01/10/2418:24
75-34-3
ND
ug/L
1.0
0.32
1
01/10/2418:24
107-06-2
ND
ug/L
1.0
0.35
1
01/10/2418:24
75-35-4
ND
ug/L
1.0
0.38
1
01/10/2418:24
156-59-2
ND
ug/L
1.0
0.40
1
01/10/2418:24
156-60-5
ND
ug/L
1.0
0.36
1
01/10/2418:24
78-87-5
ND
ug/L
1.0
0.36
1
01/10/2418:24
10061-01-5
ND
ug/L
1.0
0.36
1
01/10/2418:24
10061-02-6 v2
ND
ug/L
1.0
0.30
1
01/10/2418:24
100-41-4
ND
ug/L
5.0
0.48
1
01/10/2418:24
591-78-6
ND
ug/L
20.0
9.7
1
01/10/2418:24
74-88-4 v2
ND
ug/L
5.0
2.0
1
01/10/2418:24
75-09-2
ND
ug/L
5.0
2.7
1
01/10/2418:24
108-10-1 v2
ND
ug/L
1.0
0.29
1
01/10/2418:24
100-42-5
ND
ug/L
1.0
0.31
1
01/10/2418:24
630-20-6
ND
ug/L
1.0
0.22
1
01/10/2418:24
79-34-5
ND
ug/L
1.0
0.29
1
01/10/2418:24
127-18-4
ND
ug/L
1.0
0.24
1
01/10/2418:24
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 26 of 48

ace
Pace Analytical Services, LLC
P98907birwyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: MNS_FB-20240108-1130
Lab ID:
92707485009
Collected:
01/08/24
11:30
Received: 01/09/24 14:16 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/10/24 18:24
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/10/24 18:24
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
01/10/24 18:24
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/10/24 18:24
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/10/24 18:24
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/10/24 18:24
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/10/24 18:24
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
01/10/24 18:24
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
01/10/24 18:24
460-00-4
1,2-Dichloroethane-d4 (S)
97
%
70-130
1
01/10/24 18:24
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
01/10/24 18:24
2037-26-5
Date: 01/15/2024 01:42 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 27 of 48

ace
Pace Analytical Services, LLC
PdagoAirpyhe. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: MNS_FD-20240108-1 Lab ID: 92707485010 Collected: 01/08/24 00:00 Received: 01/09/24 14:16 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
1,4-Dioxane (p-Dioxane)
ND
ug/L
3.00
0.597
1 01/12/24 21:03
01/12/24 21:03
123-91-1
Surrogates
Toluene-d8 (S)
94.4
%
77.0-127
1 01/12/24 21:03
01/12/24 21:03
2037-26-5
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
01/10/24 21:07
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
01/10/24 21:07
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
01/10/24 21:07
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
01/10/24 21:07
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
01/10/24 21:07
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
01/10/24 21:07
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
01/10/24 21:07
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
01/10/24 21:07
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
01/10/24 21:07
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
01/10/24 21:07
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
01/10/24 21:07
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
01/10/24 21:07
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
01/10/24 21:07
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
01/10/24 21:07
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
01/10/24 21:07
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
01/10/24 21:07
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
01/10/24 21:07
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
01/10/24 21:07
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
01/10/24 21:07
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
01/10/24 21:07
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
01/10/24 21:07
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
01/10/24 21:07
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
01/10/24 21:07
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
01/10/24 21:07
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
01/10/24 21:07
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
01/10/24 21:07
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
01/10/24 21:07
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
01/10/24 21:07
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
01/10/24 21:07
10061-02-6 v2
Ethylbenzene
ND
ug/L
1.0
0.30
1
01/10/24 21:07
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
01/10/24 21:07
591-78-6
Iodomethane
ND
ug/L
20.0
9.7
1
01/10/24 21:07
74-88-4 v2
Methylene Chloride
ND
ug/L
5.0
2.0
1
01/10/24 21:07
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
01/10/24 21:07
108-10-1 v2
Styrene
ND
ug/L
1.0
0.29
1
01/10/24 21:07
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
01/10/24 21:07
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
01/10/24 21:07
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
01/10/24 21:07
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
01/10/24 21:07
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/15/2024 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 48

ace
Pace Analytical Services, LLC
Pdagohrwyhe. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: MNS_FD-20240108-1
Lab ID:
92707485010
Collected:
01/08/24
00:00
Received: 01/09/24 14:16 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/10/24 21:07
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/10/24 21:07
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
01/10/24 21:07
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/10/24 21:07
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/10/24 21:07
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/10/24 21:07
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/10/24 21:07
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
01/10/24 21:07
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
01/10/24 21:07
460-00-4
1,2-Dichloroethane-d4 (S)
99
%
70-130
1
01/10/24 21:07
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
01/10/24 21:07
2037-26-5
Date: 01/15/2024 01:42 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 29 of 48

ace
Pace Analytical Services, LLC
Pdago �irwyhe. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: MW-41BR Lab ID: 92707485011 Collected: 01/08/24 13:10 Received: 01/09/24 14:16 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
1,4-Dioxane (p-Dioxane)
ND
ug/L
3.00
0.597
1 01/12/24 21:25
01/12/24 21:25
123-91-1
Surrogates
Toluene-d8 (S)
93.6
%
77.0-127
1 01/12/24 21:25
01/12/24 21:25
2037-26-5
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
01/10/24 21:25
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
01/10/24 21:25
107-13-1
Benzene
0.94J
ug/L
1.0
0.34
1
01/10/24 21:25
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
01/10/24 21:25
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
01/10/24 21:25
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
01/10/24 21:25
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
01/10/24 21:25
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
01/10/24 21:25
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
01/10/24 21:25
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
01/10/24 21:25
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
01/10/24 21:25
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
01/10/24 21:25
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
01/10/24 21:25
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
01/10/24 21:25
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
01/10/24 21:25
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
01/10/24 21:25
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
01/10/24 21:25
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
01/10/24 21:25
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
01/10/24 21:25
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
01/10/24 21:25
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
01/10/24 21:25
110-57-6
1,1-Dichloroethane
0.78J
ug/L
1.0
0.37
1
01/10/24 21:25
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
01/10/24 21:25
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
01/10/24 21:25
75-35-4
cis-1,2-Dichloroethene
12.1
ug/L
1.0
0.38
1
01/10/24 21:25
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
01/10/24 21:25
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
01/10/24 21:25
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
01/10/24 21:25
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
01/10/24 21:25
10061-02-6 v2
Ethylbenzene
ND
ug/L
1.0
0.30
1
01/10/24 21:25
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
01/10/24 21:25
591-78-6
Iodomethane
ND
ug/L
20.0
9.7
1
01/10/24 21:25
74-88-4 v2
Methylene Chloride
11.4
ug/L
5.0
2.0
1
01/10/24 21:25
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
01/10/24 21:25
108-10-1 v2
Styrene
ND
ug/L
1.0
0.29
1
01/10/24 21:25
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
01/10/24 21:25
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
01/10/24 21:25
79-34-5
Tetrachloroethene
0.41J
ug/L
1.0
0.29
1
01/10/24 21:25
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
01/10/24 21:25
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/15/2024 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 48

ace
Pace Analytical Services, LLC
PdaRO�irpy4lje. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: MW-4BR
Lab ID:
92707485011
Collected:
01/08/24 13:10
Received: 01/09/24 14:16 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/10/24 21:25
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/10/24 21:25
79-00-5
Trichloroethene
2.1
ug/L
1.0
0.38
1
01/10/24 21:25
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/10/24 21:25
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/10/24 21:25
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/10/24 21:25
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/10/24 21:25
75-01-4
Xylene (Total)
49.3
ug/L
1.0
0.34
1
01/10/24 21:25
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
01/10/24 21:25
460-00-4
1,2-Dichloroethane-d4 (S)
99
%
70-130
1
01/10/24 21:25
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
01/10/24 21:25
2037-26-5
Date: 01/15/2024 01:42 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 31 of 48

ace
Pace Analytical Services, LLC
Pdagomrwyhe. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: MW-13D Lab ID: 92707485012 Collected: 01/08/24 15:30 Received: 01/09/24 14:16 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
1,4-Dioxane (p-Dioxane)
ND
ug/L
3.00
0.597
1 01/12/24 21:47
01/12/24 21:47
123-91-1
Surrogates
Toluene-d8 (S)
92.8
%
77.0-127
1 01/12/24 21:47
01/12/24 21:47
2037-26-5
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
01/10/24 19:55
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
01/10/24 19:55
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
01/10/24 19:55
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
01/10/24 19:55
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
01/10/24 19:55
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
01/10/24 19:55
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
01/10/24 19:55
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
01/10/24 19:55
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
01/10/24 19:55
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
01/10/24 19:55
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
01/10/24 19:55
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
01/10/24 19:55
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
01/10/24 19:55
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
01/10/24 19:55
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
01/10/24 19:55
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
01/10/24 19:55
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
01/10/24 19:55
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
01/10/24 19:55
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
01/10/24 19:55
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
01/10/24 19:55
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
01/10/24 19:55
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
01/10/24 19:55
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
01/10/24 19:55
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
01/10/24 19:55
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
01/10/24 19:55
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
01/10/24 19:55
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
01/10/24 19:55
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
01/10/24 19:55
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
01/10/24 19:55
10061-02-6 v2
Ethylbenzene
ND
ug/L
1.0
0.30
1
01/10/24 19:55
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
01/10/24 19:55
591-78-6
Iodomethane
ND
ug/L
20.0
9.7
1
01/10/24 19:55
74-88-4 v2
Methylene Chloride
ND
ug/L
5.0
2.0
1
01/10/24 19:55
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
01/10/24 19:55
108-10-1 v2
Styrene
ND
ug/L
1.0
0.29
1
01/10/24 19:55
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
01/10/24 19:55
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
01/10/24 19:55
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
01/10/24 19:55
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
01/10/24 19:55
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/15/2024 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 48

ace
Pace Analytical Services, LLC
pdaROMrpyhe. Suite 100
��JJ Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: MW-13D
Lab ID:
92707485012
Collected:
01/08/24 15:30
Received: 01/09/24 14:16 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/10/24 19:55
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/10/24 19:55
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
01/10/24 19:55
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/10/24 19:55
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/10/24 19:55
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/10/24 19:55
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/10/24 19:55
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
01/10/24 19:55
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
98
%
70-130
1
01/10/24 19:55
460-00-4
1,2-Dichloroethane-d4 (S)
98
%
70-130
1
01/10/24 19:55
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
01/10/24 19:55
2037-26-5
Date: 01/15/2024 01:42 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 33 of 48

ace
Pace Analytical Services, LLC
Pdago irwyhe. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: MW-13BR Lab ID: 92707485013 Collected: 01/08/24 14:30 Received: 01/09/24 14:16 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
1,4-Dioxane (p-Dioxane)
ND
ug/L
3.00
0.597
1 01/12/24 22:08
01/12/24 22:08
123-91-1
Surrogates
Toluene-d8 (S)
95.1
%
77.0-127
1 01/12/24 22:08
01/12/24 22:08
2037-26-5
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
01/10/24 21:44
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
01/10/24 21:44
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
01/10/24 21:44
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
01/10/24 21:44
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
01/10/24 21:44
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
01/10/24 21:44
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
01/10/24 21:44
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
01/10/24 21:44
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
01/10/24 21:44
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
01/10/24 21:44
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
01/10/24 21:44
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
01/10/24 21:44
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
01/10/24 21:44
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
01/10/24 21:44
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
01/10/24 21:44
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
01/10/24 21:44
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
01/10/24 21:44
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
01/10/24 21:44
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
01/10/24 21:44
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
01/10/24 21:44
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
01/10/24 21:44
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
01/10/24 21:44
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
01/10/24 21:44
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
01/10/24 21:44
75-35-4
cis-1,2-Dichloroethene
5.1
ug/L
1.0
0.38
1
01/10/24 21:44
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
01/10/24 21:44
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
01/10/24 21:44
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
01/10/24 21:44
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
01/10/24 21:44
10061-02-6
v2
Ethylbenzene
ND
ug/L
1.0
0.30
1
01/10/24 21:44
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
01/10/24 21:44
591-78-6
Iodomethane
ND
ug/L
20.0
9.7
1
01/10/24 21:44
74-88-4
v2
Methylene Chloride
3.OJ
ug/L
5.0
2.0
1
01/10/24 21:44
75-09-2
C9
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
01/10/24 21:44
108-10-1
v2
Styrene
ND
ug/L
1.0
0.29
1
01/10/24 21:44
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
01/10/24 21:44
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
01/10/24 21:44
79-34-5
Tetrachloroethene
0.45J
ug/L
1.0
0.29
1
01/10/24 21:44
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
01/10/24 21:44
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/15/2024 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 48

ace
Pace Analytical Services, LLC
Pdago �irwyhe. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
Sample: MW-13BR
Lab ID:
92707485013
Collected:
01/08/24 14:30
Received: 01/09/24 14:16 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/10/24 21:44
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/10/24 21:44
79-00-5
Trichloroethene
1.2
ug/L
1.0
0.38
1
01/10/24 21:44
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/10/24 21:44
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/10/24 21:44
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/10/24 21:44
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/10/24 21:44
75-01-4
Xylene (Total)
43.1
ug/L
1.0
0.34
1
01/10/24 21:44
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
01/10/24 21:44
460-00-4
1,2-Dichloroethane-d4 (S)
98
%
70-130
1
01/10/24 21:44
17060-07-0
Toluene-d8 (S)
98
%
70-130
1
01/10/24 21:44
2037-26-5
Date: 01/15/2024 01:42 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 35 of 48

ace
Pace Analytical Services, LLC
Pdagohrwyhe. Suite 100
�J Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
QC Batch: 2206058 Analysis Method: EPA 8260D by SIM
QC Batch Method: 8260B-SIM Analysis Description: VOA (GC/MS) 8260D-SIM
Laboratory: Pace National - Mt. Juliet
Associated Lab Samples: 92707485001, 92707485002, 92707485003, 92707485004, 92707485005, 92707485006, 92707485007,
92707485008,92707485009,92707485010,92707485011,92707485012,92707485013
METHOD BLANK: R4022938-2 Matrix: Water
Associated Lab Samples: 92707485001, 92707485002, 92707485003, 92707485004, 92707485005, 92707485006, 92707485007,
92707485008,92707485009,92707485010,92707485011,92707485012,92707485013
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane) ug/L ND 3.00 0.597 01/12/24 15:31
Toluene-d8 (S) % 92.8 77.0-127 01/12/24 15:31
LABORATORY CONTROL SAMPLE: R4022938-1
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 50.0 44.8 89.6 55.0-138
Toluene-d8 (S) % 102 77.0-127
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: R4022938-3
R4022938-4
MS
MSD
L1695565-01
Spike
Spike
MS MSD
MS
MSD % Rec Max
Parameter Units Result
Conc.
Conc.
Result Result
% Rec
% Rec Limits RPD RPD Qual
1,4-Dioxane (p-Dioxane) ug/L ND
50.0
50.0
44.9 44.9
89.8
89.8 13.0-160 0.00 31
Toluene-d8 (S) %
95.4
96.0 77.0-127
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /15/2024 01:42 PM without the written consent of Pace Analytical Services, LLC.
Page 36 of 48

ace
Pace Analytical Services, LLC
PdagvrwYhe. Suite 100
�J Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
QC Batch: 824408 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92707485001, 92707485002, 92707485003, 92707485004, 92707485005, 92707485006, 92707485007,
92707485008,92707485009,92707485010,92707485011,92707485012,92707485013
METHOD BLANK: 4264298 Matrix: Water
Associated Lab Samples: 92707485001, 92707485002, 92707485003, 92707485004, 92707485005, 92707485006, 92707485007,
92707485008,92707485009,92707485010,92707485011,92707485012,92707485013
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
01/10/24 12:22
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
01/10/24 12:22
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
01/10/24 12:22
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
01/10/24 12:22
1,1-Dichloroethane
ug/L
ND
1.0
0.37
01/10/24 12:22
1,1-Dichloroethene
ug/L
ND
1.0
0.35
01/10/24 12:22
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
01/10/24 12:22
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
01/10/24 12:22
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
01/10/24 12:22
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
01/10/24 12:22
1,2-Dichloroethane
ug/L
ND
1.0
0.32
01/10/24 12:22
1,2-Dichloropropane
ug/L
ND
1.0
0.36
01/10/24 12:22
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
01/10/24 12:22
2-Butanone (MEK)
ug/L
ND
5.0
4.0
01/10/24 12:22
2-Hexanone
ug/L
ND
5.0
0.48
01/10/24 12:22
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
01/10/24 12:22
Acetone
ug/L
ND
25.0
5.1
01/10/24 12:22
Acrylonitrile
ug/L
ND
10.0
1.8
01/10/24 12:22
Benzene
ug/L
ND
1.0
0.34
01/10/24 12:22
Bromochloromethane
ug/L
ND
1.0
0.47
01/10/24 12:22
Bromodichloromethane
ug/L
ND
1.0
0.31
01/10/24 12:22
Bromoform
ug/L
ND
1.0
0.34
01/10/24 12:22
Bromomethane
ug/L
ND
2.0
1.7
01/10/24 12:22
Carbon disulfide
ug/L
ND
2.0
0.36
01/10/24 12:22
Carbon tetrachloride
ug/L
ND
1.0
0.33
01/10/24 12:22
Chlorobenzene
ug/L
ND
1.0
0.28
01/10/24 12:22
Chloroethane
ug/L
ND
1.0
0.65
01/10/24 12:22
Chloroform
ug/L
ND
1.0
0.43
01/10/24 12:22
Chloromethane
ug/L
ND
1.0
0.54
01/10/24 12:22
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
01/10/24 12:22
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
01/10/24 12:22
Dibromochloromethane
ug/L
ND
1.0
0.36
01/10/24 12:22
Dibromomethane
ug/L
ND
1.0
0.39
01/10/24 12:22
Ethylbenzene
ug/L
ND
1.0
0.30
01/10/24 12:22
lodomethane
ug/L
ND
20.0
9.7
01/10/24 12:22
Methylene Chloride
ug/L
ND
5.0
2.0
01/10/24 12:22
Styrene
ug/L
ND
1.0
0.29
01/10/24 12:22
Tetrachloroethene
ug/L
ND
1.0
0.29
01/10/24 12:22
Toluene
ug/L
ND
1.0
0.24
01/10/24 12:22
v2
v2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/15/2024 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 48

ace
Pace Analytical Services, LLC
Pd8R0gfir6fyhe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
METHOD BLANK: 4264298 Matrix: Water
Associated Lab Samples: 92707485001, 92707485002, 92707485003, 92707485004, 92707485005, 92707485006, 92707485007,
92707485008,92707485009,92707485010,92707485011,92707485012,92707485013
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
01/10/24 12:22
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
01/10/24 12:22 v2
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
01/10/24 12:22
Trichloroethene
ug/L
ND
1.0
0.38
01/10/24 12:22
Trichlorofluoromethane
ug/L
ND
1.0
0.30
01/10/24 12:22
Vinyl acetate
ug/L
ND
2.0
1.3
01/10/24 12:22
Vinyl chloride
ug/L
ND
1.0
0.39
01/10/24 12:22
Xylene (Total)
ug/L
ND
1.0
0.34
01/10/24 12:22
1,2-Dichloroethane-d4 (S)
%
97
70-130
01/10/24 12:22
4-Bromofluorobenzene (S)
%
94
70-130
01/10/24 12:22
Toluene-d8 (S)
%
104
70-130
01/10/24 12:22
LABORATORY CONTROL SAMPLE:
Parameter
4264299
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
20
20.9
105
70-130
1,1,1-Trichloroethane
ug/L
20
19.9
99
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
20.6
103
70-130
1,1,2-Trichloroethane
ug/L
20
19.2
96
70-130
1,1-Dichloroethane
ug/L
20
18.8
94
70-130
1,1-Dichloroethene
ug/L
20
20.0
100
69-131
1,2,3-Trichloropropane
ug/L
20
19.0
95
70-130
1,2-Dibromo-3-chloropropane
ug/L
20
20.6
103
70-130
1,2-Dibromoethane (EDB)
ug/L
20
20.4
102
70-130
1,2-Dichlorobenzene
ug/L
20
20.8
104
70-130
1,2-Dichloroethane
ug/L
20
18.7
94
70-130
1,2-Dichloropropane
ug/L
20
18.9
95
70-130
1,4-Dichlorobenzene
ug/L
20
20.0
100
70-130
2-Butanone (MEK)
ug/L
40
35.3
88
67-133
2-Hexanone
ug/L
40
37.8
94
70-133
4-Methyl-2-pentanone (MIBK)
ug/L
40
33.7
84
70-130 v3
Acetone
ug/L
40
35.6
89
67-130
Acrylonitrile
ug/L
100
89.7
90
70-130
Benzene
ug/L
20
19.5
98
70-130
Bromochloromethane
ug/L
20
20.0
100
70-130
Bromodichloromethane
ug/L
20
19.2
96
70-130
Bromoform
ug/L
20
22.0
110
70-133
Bromomethane
ug/L
20
15.8
79
41-148
Carbon disulfide
ug/L
20
19.3
96
70-131
Carbon tetrachloride
ug/L
20
21.0
105
70-130
Chlorobenzene
ug/L
20
19.7
99
70-130
Chloroethane
ug/L
20
19.6
98
41-157
Chloroform
ug/L
20
19.4
97
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/15/2024 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 48

ace
Pace Analytical Services, LLC
PAR%Ywyhe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
LABORATORY CONTROL SAMPLE:
Parameter
4264299
Units
Spike
Conc.
LCS LCS
Result % Rec
Chloromethane
ug/L
20
17.8
cis-1,2-Dichloroethene
ug/L
20
19.0
cis-1,3-Dichloropropene
ug/L
20
17.9
Dibromochloromethane
ug/L
20
19.8
Dibromomethane
ug/L
20
20.6
Ethylbenzene
ug/L
20
19.4
lodomethane
ug/L
40
34.6
Methylene Chloride
ug/L
20
17.2
Styrene
ug/L
20
20.0
Tetrachloroethene
ug/L
20
19.4
Toluene
ug/L
20
17.9
trans-1,2-Dichloroethene
ug/L
20
19.4
trans- 1,3-Dichloropropene
ug/L
20
18.1
trans-1,4-Dichloro-2-butene
ug/L
20
19.9
Trichloroethene
ug/L
20
20.2
Trichlorofluoromethane
ug/L
20
20.5
Vinyl acetate
ug/L
40
37.2
Vinyl chloride
ug/L
20
17.0
Xylene (Total)
ug/L
60
58.7
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
% Rec
Limits Qualifiers
89
59-141
95
70-130
89
70-130
99
70-130
103
70-130
97
70-130
86
57-140 v3
86
62-130
100
70-130
97
70-130
90
70-130
97
70-130
91
70-130 v3
100
57-149
101
70-130
102
57-130
93
70-141
85
66-140
98
70-130
98
70-130
100
70-130
92
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4264300
MS
92707485001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
4264301
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
23.1
25.9
115
130
70-146
12
30
1,1,1-Trichloroethane
ug/L
ND
20
20
22.4
25.2
112
126
70-150
12
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
21.8
24.3
109
121
66-144
11
30
1,1,2-Trichloroethane
ug/L
ND
20
20
21.9
24.2
110
121
70-142
10
30
1,1-Dichloroethane
ug/L
ND
20
20
21.0
23.1
105
116
68-150
9
30
1,1-Dichloroethene
ug/L
ND
20
20
22.9
25.5
115
127
64-162
11
30
1,2,3-Trichloropropane
ug/L
ND
20
20
19.8
22.2
99
111
66-144
11
30
1,2-Dibromo-3-
ug/L
ND
20
20
21.0
23.0
105
115
62-146
9
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
22.2
24.5
111
122
70-143
10
30
1,2-Dichlorobenzene
ug/L
ND
20
20
22.4
24.0
112
120
70-142
7
30
1,2-Dichloroethane
ug/L
ND
20
20
20.2
22.2
101
111
68-145
10
30
1,2-Dichloropropane
ug/L
ND
20
20
21.3
23.2
107
116
70-144
8
30
1,4-Dichlorobenzene
ug/L
ND
20
20
21.3
23.9
107
119
70-140
11
30
2-Butanone (MEK)
ug/L
ND
40
40
37.7
42.2
94
106
57-156
11
30
2-Hexanone
ug/L
ND
40
40
39.3
44.1
98
110
62-153
11
30
4-Methyl-2-pentanone
ug/L
ND
40
40
38.8
43.0
97
108
65-144
10
30
(MIBK)
Acetone
ug/L
ND
40
40
37.2
41.6
91
102
49-162
11
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
Date: 01/15/2024 01:42 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 39 of 48

ace
Pace Analytical Services, LLC
PAR%Ywyhe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
4264300
4264301
MS
MSD
92707485001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Acrylonitrile
ug/L
ND
100
100
96.2
107
96
107
59-155
10
30
Benzene
ug/L
ND
20
20
21.6
24.0
108
120
68-144
11
30
Bromochloromethane
ug/L
ND
20
20
22.0
24.2
110
121
70-148
9
30
Bromodichloromethane
ug/L
ND
20
20
21.0
23.5
105
117
70-141
11
30
Bromoform
ug/L
ND
20
20
23.0
26.1
115
131
59-144
13
30
Bromomethane
ug/L
ND
20
20
20.8
22.4
104
112
23-190
7
30
Carbon disulfide
ug/L
ND
20
20
21.6
24.1
108
120
64-160
11
30
Carbon tetrachloride
ug/L
ND
20
20
24.6
27.2
123
136
70-147
10
30
Chlorobenzene
ug/L
ND
20
20
22.1
24.6
110
123
70-143
11
30
Chloroethane
ug/L
ND
20
20
21.7
23.9
109
120
55-190
10
30
Chloroform
ug/L
ND
20
20
21.8
23.9
109
119
67-148
9
30
Chloromethane
ug/L
ND
20
20
19.1
21.3
95
106
38-180
11
30
cis-1,2-Dichloroethene
ug/L
ND
20
20
20.9
23.3
104
116
67-151
11
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
21.1
23.6
106
118
70-142
11
30
Dibromochloromethane
ug/L
ND
20
20
22.7
25.2
114
126
68-140
10
30
Dibromomethane
ug/L
ND
20
20
22.2
24.9
111
124
70-142
11
30
Ethylbenzene
ug/L
ND
20
20
21.9
24.3
109
122
70-145
11
30
lodomethane
ug/L
ND
40
40
35.7
40.0
89
100
37-160
11
30 v3
Methylene Chloride
ug/L
ND
20
20
18.6
20.6
93
103
54-149
10
30
Styrene
ug/L
ND
20
20
22.1
24.4
110
122
70-147
10
30
Tetrachloroethene
ug/L
ND
20
20
22.9
25.1
115
126
70-145
9
30
Toluene
ug/L
ND
20
20
21.8
23.9
109
120
65-146
9
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
22.0
24.3
110
121
69-155
10
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
21.1
24.0
106
120
70-142
13
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
15.7
17.8
78
89
39-149
13
30
Trichloroethene
ug/L
ND
20
20
22.9
25.2
115
126
70-152
9
30
Trichlorofluoromethane
ug/L
ND
20
20
23.4
25.8
117
129
60-158
10
30
Vinyl acetate
ug/L
ND
40
40
37.4
41.4
94
104
56-157
10
30
Vinyl chloride
ug/L
ND
20
20
19.2
21.2
96
106
51-178
10
30
Xylene (Total)
ug/L
ND
60
60
65.3
73.1
109
122
70-146
11
30
1,2-Dichloroethane-d4 (S)
%
92
92
70-130
4-Bromofluorobenzene (S)
%
101
100
70-130
Toluene-d8 (S)
%
99
98
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /15/2024 01:42 PM without the written consent of Pace Analytical Services, LLC.
Page 40 of 48

ace
Pace Analytical Services, LLC
PAM,rwyhe. Suite 100
�J Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J23120380 MNS Landfill #1
Pace Project No.: 92707485
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
C9 Common Laboratory Contaminant.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/15/2024 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 48

ace
Pace Analytical Services, LLC
POO Wylie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
J23120380 MNS Landfill #1
Pace Project No.:
92707485
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92707485001
MW-1
8260D-SIM
2206058
EPA 8260D
by SIM
2206058
92707485002
MW-111)
8260D-SIM
2206058
EPA 8260D
by SIM
2206058
92707485003
MW-2A
8260D-SIM
2206058
EPA 8260D
by SIM
2206058
92707485004
MW-211)
8260D-SIM
2206058
EPA 8260D
by SIM
2206058
92707485005
MW-4
8260D-SIM
2206058
EPA 8260D
by SIM
2206058
92707485006
MW-411)
8260D-SIM
2206058
EPA 8260D
by SIM
2206058
92707485007
SW-1
8260D-SIM
2206058
EPA 8260D
by SIM
2206058
92707485008
MNS_TB-20240108-0800
8260D-SIM
2206058
EPA 8260D
by SIM
2206058
92707485009
MNS_FB-20240108-1130
8260D-SIM
2206058
EPA 8260D
by SIM
2206058
92707485010
MNS_FD-20240108-1
8260D-SIM
2206058
EPA 8260D
by SIM
2206058
92707485011
MW-4BR
8260D-SIM
2206058
EPA 8260D
by SIM
2206058
92707485012
MW-13D
8260D-SIM
2206058
EPA 8260D
by SIM
2206058
92707485013
MW-13BR
8260D-SIM
2206058
EPA 8260D
by SIM
2206058
92707485001
MW-1
EPA 8260D
824408
92707485002
MW-1 D
EPA 8260D
824408
92707485003
MW-2A
EPA 8260D
824408
92707485004
MW-211)
EPA 8260D
824408
92707485005
MW-4
EPA 8260D
824408
92707485006
MW-411)
EPA 8260D
824408
92707485007
SW-1
EPA 8260D
824408
92707485008
MNS_TB-20240108-0800
EPA 8260D
824408
92707485009
MNS_FB-20240108-1130
EPA 8260D
824408
92707485010
MNS_FD-20240108-1
EPA 8260D
824408
92707485011
MW-4BR
EPA 8260D
824408
92707485012
MW-13D
EPA 8260D
824408
92707485013
MW-13BR
EPA 8260D
824408
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/15/2024 01:42 PM without the written consent of Pace Analytical Services, LLC. Page 42 of 48

ace DC#_Title: ENV-FRM-HUN1-0083 v03_Sample Condition Upon Receipt
Effective Date: 11/29/2023 4:16:30 PM
86 of 149
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersvlllp.Fl
Client Name: WOW 92707485
.,�Receipt�Project t#:
10 b"Q �1 C�.�
Courier. Fed Ex cups U U5 5 Client
ElCommercial El pace ❑ Other: g27074BB 1 1 1 IIII
Custody Seal Present? ❑ Yes ❑ No Seals Intact? ❑ Yes ❑ No ❑ N/A
Date/initials Person Examining Contents:
Packing Material: ❑Bubble Wrap ❑ Bubble Bags ❑ None ❑ Other Biological Tissue Frozen?
Thermometer: ❑ Yes ❑ N o . ❑ N/A
❑ IR Gun ID: Type of Ice: OWet ❑Bltie ❑None
Correction Factor:
Cooler Temp: ' Add/Subtract (*Q Temp should be above freezing to 6"C
❑ Samples out of temp criteria. Samples on ice, cooling process
Cooler Temp Corrected J*Q: has begun
USDA Regulated Soil (,❑ N/A, water sample)
Did samples originate in p-quarantine zone within the United States: CA, NY, or SC Did samples originate from a foreign source (interrtatitgnally,
rrknr4 ,,,�.,d7l�lvP� 'Flmu includine Hawaii and Puerto Ricol? ❑Yes MN6
Comments/Discrepancy: i
Chain of Custody Present?
[]Yes
❑ No
:1 N/A
1.
Samples Arrived within Hold Time?
❑Yes
❑ No
❑ N/A
2.
Short Hold Time Analysis (<72 hr.)?
El Yes
_Z)No
[I N/A
3.
Rush Turn Around Time Requested?
❑ Yes
II.No
❑ N/A
4.
Sufficient Volume?
❑Yes
❑No
❑N/A
5.
Correct Containers Used?
-Pace Containers Used?
❑Yes
❑Yes
❑ No
❑No
❑ N/A
El N/A
6.
Containers Intact?
El Yes
❑ No
❑ N/A
7.
Dissolved analysis: Samples Field Filtered?
❑Yes
El No
❑N/A
8.
Sample Labels Match COC?
-Includes Date/Time/ID/Analysis Matrix:
El Yes
❑No
❑N/A
9.
Headspace in VOA Vials (55-6mm)?
❑Yes
—❑-No
❑N/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
❑Yes
❑Yes
.El No
❑No
❑N/A
13111/A
11.
COMMENTSISAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted;
Project Manager SCURF Review:
Project Manager SRF Review:
Lot ID of split containers:
Date/Time:
Date:
Date:
Field Data Required? LJ Yes tJ No
Qualtrax ID: 69614 Pane 1 of 2 Page 43 of 48

f u t-. u
--'L,
Effective Date: 11/14/2022
"Check mark top half of box if pH and/or dechlorination is verified and Project 4
within the acceptance range for preservation samples.
Exceptions: VOA, Cpliform, TOC, Oil and Grease, DR016015 (water) DOC. LLHg
"Bottom half of box is to list number of bottles
• •'Check all unpreserved Nitrates for chlorine
Page 87 of 149
WO#:92707485
PM: LJP Due Date: 01/22/24
CLIENT: 92-Duke Ener
U
Z
v
z
v
z Q
13
Pr d
a
Z iy a
n n
I
z
a
Z
y a
�,
4
"
z
z
J
`
?
Q
M
~
p
¢
y
is
C
CL-
L
c "�
C 4 N
O
z
y T
¢ l7
z ro
a
C
V
n er
rl
Q
is
x
=
z
=
2'
U
m0
N
M
ry
C
a
Q
m
`,'�-
4
?
zdi
M
rJ
d
z
^
9
I
S
z
c
]
c
Q
aZ
CL
C:
3
E
vt
E
C]
N
m n,
i
S J
O .. ,r5
itl1 rl
n
E
O
ry
Ga
�• a
v
,n ,n
C
a_
N
..a
E
a
Ge
.a
E
a E
a
E
o,
N
c
E
o
E
a
.�
O
a
O
7
.1
O
V
a
0
1
,T
<
O
>
J
O
7
G
0
>
J
'i
,,
v
2
OEM
I
a
'^
M
`v
N
O
N
ro
a
N
C
¢
E
O
c
O
N
E
a
4
V
a
V
V O.
= m
7
!,'1
0.
ro
.-+
7 ua
N H 1
d 0. d
m to m
2
M
CL
to
.rd
ry m LL
V V
& 6
m m
a
t'1
a
S
tD
a
.-a
L1
M r1
0 0
4 a
N
vi
M
0
4
t
O1
0
d
T
in
V'
r
Q1
\7
7
7
C,
V
7
dl
�
a
,P1
�
A
6
x
U
t�
1
7
rrA a
�:, .
v1
C
w
F:.
N
S
[V
K
M
0.
w
7
G
1,7
a
U'
W
>
V
cl
1
2
3
I
`n
!
\
��
\NNN
\
5
6 I
7
E-\I
9
N.
10
NN
I'l
pH Ad}'ustrnent Log for Preserved Samples
Sample ID Type of Preservative I pH upon receipt Date preservation adjusted Time preservation
adjusted
xnwurc ur rreseraacive
added
Lat ft 1
Note- Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this fame will beserlt to the North Carolina DENR Certification Office (r e
Out al hold, incorrect preservalive, out of leinp, rnCorreci tantainers.
Qualtrax ID. 69614 [ Page 2 of 2
Page 44 of 48

Effective Date: 11/14/2022
age 88 of 149
`Check mark top half of box if pH and/or dechlorination is verified and Project Ff W0 J��®��V�
within the acceptance range for preservation samples. PM: UP Due Date: 01/22/24
Exceptions: VOA, Col7orm, TOC. Oil and Grease, DRO180151waterl DOC. LLHC CLIENT: 92-Duk* Ener
**Bottom half of box is to list number of bottles
"'Check all unpreserved !Nitrates for chlorine
U
,a
L!
�!
`.}
V
fJ
'tl
V
CJ
ID=
y y
S
Q G
�
Z rr4 C
3
N A
n C
Z
-O I
VN
Z
U
_ a
7
V M
r!
y
r•J LJ
V —
= a
R z
`
Z
=
?
U
9
z
r
a
Z
x
M
A
Z
Mnt
Z
V
In
v
?
s
7
61
d
qi
C
L
C
N
C
.r4'i
n
_
`7' m
Z
_ _
01 r N
Q L.7
Z .�
N m
v
a
c
x
n a
U 7
z
.5�.
<
LA
rJ
x
(J
N v
x
z
Z
Lr
rl
�1
ry
'
?
c
O
a
m
?
i
a
d
m
a
C.,
Y
z
U
C
3
Qi
C
2
a
C
a
`
ui
rryl
d
E
o
N
a
E
O
V1
N
`a
=
ri
4 C
2 E
N p
ry
6
E E v
n n
ti '/
t
d
=
.r
C Q
m o
= ve
.�1 rV
C
_v
=
.r
`'+ E
E C
0
rnJ
Q
E
4
A
a
9 -.
E
b 0
CL
5
>
G
E
,n
4r
E
Q
4
E
0
Q
o12 f
o
y
In
f
E
O
7
L 0.
m
7
M
a
m
rV
a
m
.�
a
m
,r„i
Hl
V ill
rL d
0 m
N r0 LL
-`
1 I a
l m m 3
N
l7
a
N M
0 l7
a a
%6
to
a
M J7r
La 0
a o
T
C7
o
LT
L9
>
T
V
>
0 a
a le
rM
�
>
~ '
Un
y
,,
~
N i
a
4
M
a
m
'
G
0
¢
7
61
>
V
o
z
3
I
5
\\\I—
\
\
\
—
NN
-
N
I—
�
6
---
Ll
to
�
—
-\I\\
N
_S
—
—
pH Adjustment Log for Preserved Samples I
Sample ID Type cf Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot It
adjusted added
I I
Note- Whenever Lhere is a discrepancy alfecung Nort4 Carolina compliance samples, a copy of this form will he sent to the Ngftll Carolina DENR Certification Office i1 e
Out of hold, incorrect preservative, out of iernp, incorrect Containers.
Qualtrax ID, 69614 Page 2 of 2
Page 45 of 48

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM f
DUKE Duke Energy Analytical Laboratory i i
i
M.11 a-Moow tauiwma7.orl ! ;Order# J23120380
ENERGY. m1w vill" a. C.
Isola
! i
Nunl.rsrllla, N.C. uo7r
pwl ns.S2ra ! � �9� By Fp. w sraaasa
Project Name MNS LANDFILL #t Permit #60-04
�• n.:
Client Ethan Smith 1 Bryan Moeller!
CourtneyMurphy/ Ashley Heal
Operating Unit: 20036
Process: BLOFLGN
Accounl;
Project:
Activity ID:
Facility to:
Program f ECuiS Task Code: Sub-ProgMnVTask Code:
Sample Description or ID
MP LE ID i
UMBER i
3031274 ; IMNS_MW-1
3031275 � IMNS_MW-1D
3031276 ! IMNS_MW-2A
!3031277 !• IMNS_MW-2D
2023031280
2023031281
2023031282
202303i283
MNS MW-11
MNS_M W-11 D
MNS_MW-12
MNS_MW-12D
MNS_SW-1
MNS_M W-4R
MNS_MW-4DR
!Vendor: Pao. f/
i
PACE
PO 10624878
Use Only ------------------------ : Page890 149 00
':R NC_ ; Page _1— of 3_ O
Sc ION _ i DISTRIBUTtp
SAMPLE PROGRAM ! ORIGINAL to LAB, COPY 10 CLIEWIF
r
Ground Water X_ NPDES
a S Drinking Water_ UST_
RCRA Waste
er........ ................... ...................
ni 3 Unfiltered 3 Filtered
! Preservative lCr kcE
Container Volume 1mLj r 500 500 1
Container Type
Customer to
compfore all approprlarn non-shadod areas.
Collection Information
Date
1
Time
l32- "a
Printed Name
SrKHV\
Si
t Z
13 L)o
m I+t"
1/A/2`t
IC91
P:IdA l SrYfA4,
�r
f���/(jyJ y�J� r/J��jiv
V�"roll 5;1wx Y / � /V�D
y.v�r vr.
/ +
RoUnquishad By
DatetTime
Accepted By:
I
Relinqui
/ D ta�l�Tl'ym/a + c
1 �r
Accepted By:
ocked By
DalalTime
SealedfLock Opened By
Comments
0
Filtration f 0.45
TOTAL 9 CONTAINERS
h ma
S 0v2 W v
u
iKo6cnV r
dy Zi ~ a2 qiO pNp U
man
b�+wuJ V
d1
oa
N m u _N4 t`6 od fl � .0
to rL
5u
a
�` 5e^5ecm
N
rto�N
S G��ia
DOE
©©o©oMON01M:C
OF
IMMEN
MEN
©©©©-©
i
■
MEN
©©�©M--■
IN
a
MEMO
ME
EMINmMIMMEMEMI
1ME©�--■■—.
OME�Ewmwwmmmw
NEWSMEN
MOMINIMMINNIM
EME
r
._�__--■��.
J
a-
a.

1_ ........ _ CHAIN OF CUSTODY RECORD AND _A_NA_ ANALYSIS REQUEST FORM _ _._._______._,_._,_„ page 90 of 149
! Duke Energy Analytical Laboratory ._._._._ _._._._._._.. ................. ._._. Anatvtical La6orelory Uee Onlv_._._._._._._._._._._._._._._._...._._._._._ _. i
-&-fts"UNE: Mencor+slco2ru(aanalnatwel
ENERGY „a2r„e,r+r.n Rd
i
1101der/i J237 3$o
Matrix WATLR
s'"r ieb"'uer°"
NC—
Sc_
i
Page_2 of_,3_ p
D15TR16L1rlON I_
xam.r.,na+, n. C. 21078
pat rrsaus
! I�a,d er
1 i
P & TI /
SAMPLE PROGRAM
i
0R4GINAL to LAR, COPY to CLIEVT
I._._._._._ --- Fes: p°!i elsaa�a.-'-'-'-. j .
J
Gmund Water
NPDES_
Project Name Ynon. na:
1 MNS LANDFILL #1 Permit 3r60-OQ
PACE
dt
_x_
Ddnking Water RA
U57 —
Updated-, sr13123 a
Client Ethan Smith I Bryan Moeller 7
**
._.._.._coos.r.T.mP LQ}-•.--•-•
-.•-.--..-.--..-..-..-..-..--.-.--.-.---.-.---._.._.._.._.._.._.._
RCRA wash
Courtney Murphy I Ashley Healy.•,�
O� L���
i Filtration (D.45 um)
d
Unfiltered
0 Filtered
Operating Unit: 20036 process: BLDFLGN Account:
-=•
Preservative
ICE
ICE
Protect: Activity ID: Fac,llty ID•
Gonlainer Volume (mL)
- I
I t
300
300
0
Program! EGels Task Code: Sub-Pragrom7Task Cade:
Container Type
Q
C
Sample Description or 1D
re•
Customer to complete all approprlaro non -shaded aas. a
N
x
U
I_
W
X
a
n
» '
i SAMPLE ID i
Collection Information
-
n °
ytU
is
Jld
_
OJ
-X0.
i NUMBER i
Date Time Printed Name
SI naturo u I9
-
y.l _
a o
Y O
¢ m
a
e
F
2023031295 MNS_TB
X
3
3
NIA
6
2023031296
MKS TB
X
3
3
NIA
6
i 2023031297
MNS_TB-207. I0%-Ogbb
p if
N06
X
3
3
N/A
6
. 2023031298 !
MNS_TR
X
3
3
NIA
6
2023031299 !
ii
MNS_F8
X
3
1
3
1
NIA
8
1 2023031300 i
MNS_FB- z 02.g6j6 ,1 f 30
C(
O
�5f�
�uW 4
X
3
1
3
1
NIA
6
2023031301 i
MNS_FB
X
a
1
3
1
NIA
a
j 2023031302
MNS_FB
X
3
1
3
1
NIA
8
2023031303
MNS_FD
X
3
1
3
i
IJIA
8
•. 2023031304
MNS_FD-2o2�a Dg- (
—
X
3
1
3
1
NIA
a
a
D
ill
0
0
3 11
0
1 I
0
_
0
, 1
D
TOTAL#CONTAINERS
30
6 0
30
0
1 8
1 0
0
0
0
0
0
0
72
Relinquis d B
DatalT,me
Accepted By:
DaterTima
-a
5
q M
Requested Turnaround
21 Days
Relinquished By ^DatelTime
ccepted By: p 02ttotTTii !,(�s
2 /ql
7 orb
! + f I/
a a
$ m
"
14Days� �r
Rsllnquis Datatelf llme
Accepted ay: Daterrima +
Y
C
a m
Se By OatelT,me
SealedlLock Opened By DateR
'7 Days
E'+
-o
Comments
o
'O(her
"Add. Cost Will Apply
U
Total 72

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
DUKE
u e nergy Analytical Laboratory ! ! Analytical LaboratoryUse Only
Mtll Cod. Mf.Wgt 18WMIna iroi] ; i Matrix WATER s•a,nw•ai
ENERGY. 13339NapanFanyrld ; •Order# J23420380
aantenvua, N. c. zaarr ! !Lopped ay
pail ni s-stir
i._._._._._
............. F.. aulaay.aoM.___-_._._.�
F
C
Project Name MNS LANDFILL #1 Permit 960-04
Phone Ne:
Client Ethan Smith ! Bryan Moeller 7
Courtney Murphy ! Ashley Heal
Operating Unit: 20036
Process: BLOFLGN
Account:
Project:
Activity ID:
Facility ID:
Program I EQuiS Task Code:
Sub-Programansk Code:
_.___-_.__ Sample Description or ID
i SAMPLE ID i
i NUMBER i
2023031289 i MNS_MW-3BR
2023031290 MNS_MW-4BR
2023031291 ; MNS_MW-4BRR
2023031292 ' MNS_MW-11BR
2023031293 ! MNS_MW-13D
�� 2023~ 031294 MNS MW-13BR
�
PACE Qo Q �---�-�---_-J. rs
--�-..,"c�Lr.T_�T.2.14i_..--�-�--�-�---�
PO 10624818 Filtration {0.45UM) 11
Preservative
Container Volume jmLj
Container Type
Custamur to complete art appropriate non -shaded areas.
CoOection Information
Time Printed Name Sic
TOTAL C CONTAINERS
3
3
3
3
3
3
SAMPLE PROGRAM
Ground Water_?;__
NPI3ES_
DnnIdn9Water_
UST
iNO3
MCL, IC6
®®-
SOD
40
rt
tt
-
rn�
W V
ZvQ m
ni CO
V
oCi
NMI
U Cwti
N� to
©©©
EN
11
N
m
F"i
©
27
18 1 6 1 0 1 18 1 6 1 27 1 0
Page 91 of 149 00
Pages _3_ of _3_ p
DISTRIBUTION 00
ORIGINAL to LAB, COPY to CLIE '
a
a
Filtered
Reli ich y
Dale1T me
Accepted By:
teJTI
GT
z
is
c
a 1
m E
a n,
Requested Turnaround
21 Days
14 Days
ellnqulshed By DatelTime
A opted By: D errime
/�
] ! (,� tC f ib
! (
R.H. ad 1 �Dreto1T me �["
t
e2 9 "5V
Accepted By: DatelTime
E
• /
c
b�
o v
cked By Date/Time
Sealedll-ock Opened By DatelTime
a m
E "�
"o
E
0
'7 Days
'Other
Comments
li
Add. Cost Will Apply
•r
F
B
8
B
B
B
8
0
0
0
0
27
a
0
0
0
0
0
0
0 75
Total) 75

�ce-
January 22, 2024
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Dear Program Manager:
Pace Analytical Services, LLC
PARYWYhe. Suite 100
Huntersville, NC 28078
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on January 11, 2024. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace National - Mt. Juliet
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
ga
Lord Patton
[e-mail]
828-417-6055
Project Manager
Enclosures
AC4R�rp .
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 51

ace
Pace Analytical Services, LLC
PR8R1q9r6fy,fje. Suite 100
Huntersville, NC 28078
[phone]
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Pace Analytical Services National
12065 Lebanon Road, Mt. Juliet, TN 37122
Alabama Certification #: 40660
Alaska Certification 17-026
Arizona Certification #: AZ0612
Arkansas Certification #: 88-0469
California Certification #: 2932
Canada Certification #: 1461.01
Colorado Certification #: TN00003
Connecticut Certification #: PH-0197
DOD Certification: #1461.01
EPA# TN00003
Florida Certification #: E87487
Georgia DW Certification #: 923
Georgia Certification: NELAP
Idaho Certification #: TN00003
Illinois Certification #: 200008
Indiana Certification #: C-TN-01
Iowa Certification #: 364
Kansas Certification #: E-10277
Kentucky UST Certification #: 16
Kentucky Certification #: 90010
Louisiana Certification #: A130792
Louisiana DW Certification #: LA180010
Maine Certification #: TN0002
Maryland Certification #: 324
Massachusetts Certification #: M-TNO03
Michigan Certification #: 9958
Minnesota Certification #: 047-999-395
Mississippi Certification #: TN00003
Missouri Certification #: 340
Montana Certification M CERT0086
Nebraska Certification #: NE-OS-15-05
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
CERTIFICATIONS
Nevada Certification #: TN-03-2002-34
New Hampshire Certification #: 2975
New Jersey Certification #: TNO02
New Mexico DW Certification
New York Certification #: 11742
North Carolina Aquatic Toxicity Certification #: 41
North Carolina Drinking Water Certification #: 21704
North Carolina Environmental Certificate #: 375
North Dakota Certification #: R-140
Ohio VAP Certification #: CL0069
Oklahoma Certification #: 9915
Oregon Certification #: TN200002
Pennsylvania Certification #: 68-02979
Rhode Island Certification #: LA000356
South Carolina Certification #: 84004
South Dakota Certification
Tennessee DW/Chem/Micro Certification #: 2006
Texas Certification #: T 104704245-17-14
Texas Mold Certification #: LAB0152
USDA Soil Permit #: P330-15-00234
Utah Certification #: TN00003
Virginia Certification #: VT2006
Vermont Dept. of Health: ID# VT-2006
Virginia Certification #: 460132
Washington Certification #: C847
West Virginia Certification #: 233
Wisconsin Certification #: 998093910
Wyoming UST Certification #: via A21LA 2926.01
A21-A-ISO 17025 Certification #: 1461.01
A21-A-ISO 17025 Certification #: 1461.02
AIHA-LAP/LLC EMLAP Certification #:100789
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water* LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 51

ace
Pace Analytical Services, LLC
Pdag0Aiirpyhe. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92708030001
MW-3
Water
01/10/2415:00
01/11/24 14:00
92708030002
MW-311)
Water
01/10/2415:35
01/11/24 14:00
92708030003
MW-11
Water
01/10/2411:20
01/11/24 14:00
92708030004
MW-11D
Water
01/10/2410:55
01/11/24 14:00
92708030005
MW-12
Water
01/10/24 14:00
01/11/24 14:00
92708030006
MW-12D
Water
01/10/2413:40
01/11/24 14:00
92708030007
MW-4R
Water
01/10/2411:20
01/11/24 14:00
92708030008
MW-4DR
Water
01/10/2412:50
01/11/24 14:00
92708030009
MNS TB-20240110-0800
Water
01/10/24 08:00
01/11/24 14:00
92708030010
MNS FB-20240110-1020
Water
01/10/2410:20
01/11/24 14:00
92708030011
MNS FD-20240110-1
Water
01/10/24 00:00
01/11/24 14:00
92708030012
MW-3BR
Water
01/10/2415:30
01/11/24 14:00
92708030013
MW-4BRR
Water
01/10/2414:15
01/11/24 14:00
92708030014
MW-11BR
Water
01/10/2412:05
01/11/24 14:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 51

ace
Pace Analytical Services, LLC
P9890rwyhe. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J23120380 MNS Landfill
92708030
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92708030001
MW-3
EPA 8260D by SIM
JCP
2
PAN
EPA 8260D
SAS
50
PASI-C
92708030002
MW-3D
EPA 8260D by SIM
JCP
2
PAN
EPA 8260D
SAS
50
PASI-C
92708030003
MW-11
EPA 8260D by SIM
JCP
2
PAN
EPA 8260D
SAS
50
PASI-C
92708030004
MW-11D
EPA 8260D by SIM
JCP
2
PAN
EPA 8260D
SAS
50
PASI-C
92708030005
MW-12
EPA 8260D by SIM
JCP
2
PAN
EPA 8260D
SAS
50
PASI-C
92708030006
MW-12D
EPA 8260D by SIM
JCP
2
PAN
EPA 8260D
SAS
50
PASI-C
92708030007
MW-4R
EPA 8260D by SIM
JCP
2
PAN
EPA 8260D
SAS
50
PASI-C
92708030008
MW-4DR
EPA 8260D by SIM
JCP
2
PAN
EPA 8260D
SAS
50
PASI-C
92708030009
MNS_TB-20240110-0800
EPA 8260D by SIM
JCP
2
PAN
EPA 8260D
SAS
50
PASI-C
92708030010
MNS_FB-20240110-1020
EPA 8260D by SIM
JCP
2
PAN
EPA 8260D
SAS
50
PASI-C
92708030011
MNS_FD-20240110-1
EPA 8260D by SIM
JCP
2
PAN
EPA 8260D
SAS
50
PASI-C
92708030012
MW-3BR
EPA 8260D by SIM
JCP
2
PAN
EPA 8260D
SAS
50
PASI-C
92708030013
MW-4BRR
EPA 8260D by SIM
JCP
2
PAN
EPA 8260D
SAS
50
PASI-C
92708030014
MW-11BR
EPA 8260D by SIM
JCP
2
PAN
EPA 8260D
SAS
50
PASI-C
PAN = Pace National - Mt. Juliet
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 51

ace
Pace Analytical Services, LLC
PdagvirwYhe. Suite 100
�J Huntersville, NC 28078
[phone]
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Lab Sample ID
Method
Client Sample ID
Parameters
92708030002
MW-3113
EPA 8260D
Benzene
EPA 8260D
1,1-Dichloroethane
EPA 8260D
cis-1,2-Dichloroethene
EPA 8260D
Methylene Chloride
EPA 8260D
Tetrachloroethene
EPA 8260D
Trichloroethene
EPA 8260D
Xylene (Total)
92708030007
MW-4R
EPA 8260D
Tetrachloroethene
EPA 8260D
Trichloroethene
92708030008
MW-4DR
EPA 8260D
cis-1,2-Dichloroethene
EPA 8260D
Trichloroethene
92708030012
MW-3BR
EPA 8260D
1,1-Dichloroethane
EPA 8260D
cis-1,2-Dichloroethene
EPA 8260D
Methylene Chloride
EPA 8260D
Tetrachloroethene
EPA 8260D
Trichloroethene
EPA 8260D
Xylene (Total)
92708030013
MW-4BRR
EPA 8260D
Acetone
EPA 8260D
Carbon disulfide
EPA 8260D
cis-1,2-Dichloroethene
EPA 8260D
Xylene (Total)
SUMMARY OF DETECTION
Result
Units
Report Limit
Analyzed
0.53J
ug/L
1.0
01 /12/24 15:19
0.38J
ug/L
1.0
01 /12/24 15:19
5.2
ug/L
1.0
01 /12/24 15:19
6.1
ug/L
5.0
01 /12/24 15:19
0.511
ug/L
1.0
01 /12/24 15:19
1.5
ug/L
1.0
01 /12/24 15:19
4.8
ug/L
1.0
01 /12/24 15:19
0.97J
ug/L
1.0
01 /12/24 16:50
0.74J
ug/L
1.0
01 /12/24 16:50
1.9
ug/L
1.0
01 /12/24 17:08
0.78J
ug/L
1.0
01 /12/24 17:08
1.2
ug/L
1.0
01 /12/24 18:22
6.2
ug/L
1.0
01 /12/24 18:22
16.9
ug/L
5.0
01 /12/24 18:22
0.69J
ug/L
1.0
01 /12/24 18:22
1.9
ug/L
1.0
01 /12/24 18:22
101
ug/L
1.0
01 /12/24 18:22
65.0
ug/L
25.0
01 /12/24 18:40
12.8
ug/L
2.0
01 /12/24 18:40
1.0
ug/L
1.0
01 /12/24 18:40
0.65J
ug/L
1.0
01 /12/24 18:40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 51

ace
Pace Analytical Services, LLC
P9890*rwyhe. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Method: EPA 8260D by SIM
Description: VOA (GC/MS) 8260D-SIM
Client: Duke Energy
Date: January 22, 2024
General Information:
14 samples were analyzed for EPA 8260D by SIM by Pace National Mt. Juliet. All samples were received in acceptable condition with
any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of
this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 6 of 51

ace
Pace Analytical Services, LLC
PAROAirwyhe. Suite 100
�J Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Method: EPA 8260D
Description: 8260D MSV Low Level
Client: Duke Energy
Date: January 22, 2024
General Information:
14 samples were analyzed for EPA 8260D by Pace Analytical Services Charlotte. All samples were received in acceptable condition
with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end
of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
QC Batch: 824993
IK: The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be
considered an estimated value.
• DUP (Lab ID: 4267323)
• Bromoform
• Vinyl acetate
• cis-1,3-Dichloropropene
• trans- 1,3-Dichloropropene
• MS (Lab ID: 4267322)
• Bromoform
• Vinyl acetate
• cis-1,3-Dichloropropene
• trans- 1,3-Dichloropropene
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
QC Batch: 824993
v2: The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated
samples and the sensitivity of the instrument was verified with a reporting limit check standard.
• BLANK (Lab ID: 4267320)
• Bromomethane
- DUP (Lab ID: 4267323)
• lodomethane
• MNS_FB-20240110-1020 (Lab ID: 92708030010)
• Bromomethane
• MNS_FD-20240110-1 (Lab ID: 92708030011)
• Bromomethane
• MNS_TB-20240110-0800 (Lab ID: 92708030009)
• Bromomethane
• MW-11 (Lab ID: 92708030003)
• Bromomethane
• MW-11BR (Lab ID: 92708030014)
• Bromomethane
• MW-11D (Lab ID: 92708030004)
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 7 of 51

ace
Pace Analytical Services, LLC
P98906irwyhe. Suite 100
�J Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Method: EPA 8260D
Description: 8260D MSV Low Level
Client: Duke Energy
Date: January 22, 2024
QC Batch: 824993
v2: The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated
samples and the sensitivity of the instrument was verified with a reporting limit check standard.
• Bromomethane
• MW-12 (Lab ID: 92708030005)
• Bromomethane
• MW-12D (Lab ID: 92708030006)
• Bromomethane
• MW-3 (Lab ID: 92708030001)
• Bromomethane
• MW-3BR (Lab ID: 92708030012)
• Bromomethane
• MW-31D (Lab ID: 92708030002)
• Bromomethane
• MW-4BRR (Lab ID: 92708030013)
• Bromomethane
• MW-4DR (Lab ID: 92708030008)
• Bromomethane
• MW-4R (Lab ID: 92708030007)
• Bromomethane
v3: The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated
samples may have low bias.
• LCS (Lab ID: 4267321)
• Bromomethane
• MS (Lab ID: 4267322)
• lodomethane
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 8 of 51

ace
Pace Analytical Services, LLC
Padgwrwyhe. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Method: EPA 8260D
Description: 8260D MSV Low Level
Client: Duke Energy
Date: January 22, 2024
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 9 of 51

ace
Pace Analytical Services, LLC
Padgwirpyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MW-3 Lab ID: 92708030001 Collected: 01/10/24 15:00 Received: 01/11/24 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 01/22/2024 02:20 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND
ug/L
3.00
0.597
1 01 /20/24 15:37
01 /20/24 15:37
123-91-1
95.0
%
77.0-127
1 01 /20/24 15:37
01 /20/24 15:37
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
01/12/2415:00
67-64-1
ND
ug/L
10.0
1.8
1
01/12/2415:00
107-13-1
ND
ug/L
1.0
0.34
1
01/12/2415:00
71-43-2
ND
ug/L
1.0
0.47
1
01/12/2415:00
74-97-5
ND
ug/L
1.0
0.31
1
01/12/2415:00
75-27-4
ND
ug/L
1.0
0.34
1
01/12/2415:00
75-25-2
ND
ug/L
2.0
1.7
1
01/12/2415:00
74-83-9
ND
ug/L
5.0
4.0
1
01/12/2415:00
78-93-3
ND
ug/L
2.0
0.36
1
01/12/2415:00
75-15-0
ND
ug/L
1.0
0.33
1
01/12/2415:00
56-23-5
ND
ug/L
1.0
0.28
1
01/12/2415:00
108-90-7
ND
ug/L
1.0
0.65
1
01/12/2415:00
75-00-3
ND
ug/L
1.0
0.43
1
01/12/2415:00
67-66-3
ND
ug/L
1.0
0.54
1
01/12/2415:00
74-87-3
ND
ug/L
2.0
0.34
1
01/12/2415:00
96-12-8
ND
ug/L
1.0
0.36
1
01/12/2415:00
124-48-1
ND
ug/L
1.0
0.27
1
01/12/2415:00
106-93-4
ND
ug/L
1.0
0.39
1
01/12/2415:00
74-95-3
ND
ug/L
1.0
0.34
1
01/12/2415:00
95-50-1
ND
ug/L
1.0
0.33
1
01/12/2415:00
106-46-7
ND
ug/L
1.0
0.37
1
01/12/2415:00
75-34-3
ND
ug/L
1.0
0.32
1
01/12/2415:00
107-06-2
ND
ug/L
1.0
0.35
1
01/12/2415:00
75-35-4
ND
ug/L
1.0
0.38
1
01/12/2415:00
156-59-2
ND
ug/L
1.0
0.40
1
01/12/2415:00
156-60-5
ND
ug/L
1.0
0.36
1
01/12/2415:00
78-87-5
ND
ug/L
1.0
0.36
1
01/12/2415:00
10061-01-5
ND
ug/L
1.0
0.36
1
01/12/2415:00
10061-02-6
ND
ug/L
1.0
0.30
1
01/12/2415:00
100-41-4
ND
ug/L
5.0
0.48
1
01/12/2415:00
591-78-6
ND
ug/L
20.0
9.7
1
01/12/2415:00
74-88-4
ND
ug/L
5.0
2.0
1
01/12/2415:00
75-09-2
ND
ug/L
5.0
2.7
1
01/12/2415:00
108-10-1
ND
ug/L
1.0
0.42
1
01/12/2415:00
1634-04-4
ND
ug/L
1.0
0.29
1
01/12/2415:00
100-42-5
ND
ug/L
1.0
0.31
1
01/12/2415:00
630-20-6
ND
ug/L
1.0
0.22
1
01/12/2415:00
79-34-5
ND
ug/L
1.0
0.29
1
01/12/2415:00
127-18-4
ND
ug/L
1.0
0.24
1
01/12/2415:00
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
Page 10 of 51

ace
Pace Analytical Services, LLC
Padg iwyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MW-3
Lab ID:
92708030001
Collected:
01/10/24 15:00
Received: 01/11/24 14:00 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/12/24 15:00
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/12/24 15:00
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
01/12/24 15:00
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/12/24 15:00
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/12/24 15:00
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/12/24 15:00
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/12/24 15:00
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
01/12/24 15:00
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
96
%
70-130
1
01/12/24 15:00
460-00-4
1,2-Dichloroethane-d4 (S)
101
%
70-130
1
01/12/24 15:00
17060-07-0
Toluene-d8 (S)
98
%
70-130
1
01/12/24 15:00
2037-26-5
Date: 01/22/2024 02:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 51

ace
Pace Analytical Services, LLC
Padg rwYhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MW-31) Lab ID: 92708030002 Collected: 01/10/24 15:35 Received: 01/11/24 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 01/22/2024 02:20 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND
ug/L
3.00
0.597
1 01 /20/24 15:58
01 /20/24 15:58
123-91-1
95.9
%
77.0-127
1 01 /20/24 15:58
01 /20/24 15:58
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
01/12/2415:19
67-64-1
ND
ug/L
10.0
1.8
1
01/12/2415:19
107-13-1
0.53J
ug/L
1.0
0.34
1
01/12/2415:19
71-43-2
ND
ug/L
1.0
0.47
1
01/12/2415:19
74-97-5
ND
ug/L
1.0
0.31
1
01/12/2415:19
75-27-4
ND
ug/L
1.0
0.34
1
01/12/2415:19
75-25-2
ND
ug/L
2.0
1.7
1
01/12/2415:19
74-83-9
ND
ug/L
5.0
4.0
1
01/12/2415:19
78-93-3
ND
ug/L
2.0
0.36
1
01/12/2415:19
75-15-0
ND
ug/L
1.0
0.33
1
01/12/2415:19
56-23-5
ND
ug/L
1.0
0.28
1
01/12/2415:19
108-90-7
ND
ug/L
1.0
0.65
1
01/12/2415:19
75-00-3
ND
ug/L
1.0
0.43
1
01/12/2415:19
67-66-3
ND
ug/L
1.0
0.54
1
01/12/2415:19
74-87-3
ND
ug/L
2.0
0.34
1
01/12/2415:19
96-12-8
ND
ug/L
1.0
0.36
1
01/12/2415:19
124-48-1
ND
ug/L
1.0
0.27
1
01/12/2415:19
106-93-4
ND
ug/L
1.0
0.39
1
01/12/2415:19
74-95-3
ND
ug/L
1.0
0.34
1
01/12/2415:19
95-50-1
ND
ug/L
1.0
0.33
1
01/12/2415:19
106-46-7
0.38J
ug/L
1.0
0.37
1
01/12/2415:19
75-34-3
ND
ug/L
1.0
0.32
1
01/12/2415:19
107-06-2
ND
ug/L
1.0
0.35
1
01/12/2415:19
75-35-4
5.2
ug/L
1.0
0.38
1
01/12/2415:19
156-59-2
ND
ug/L
1.0
0.40
1
01/12/2415:19
156-60-5
ND
ug/L
1.0
0.36
1
01/12/2415:19
78-87-5
ND
ug/L
1.0
0.36
1
01/12/2415:19
10061-01-5
ND
ug/L
1.0
0.36
1
01/12/2415:19
10061-02-6
ND
ug/L
1.0
0.30
1
01/12/2415:19
100-41-4
ND
ug/L
5.0
0.48
1
01/12/2415:19
591-78-6
ND
ug/L
20.0
9.7
1
01/12/2415:19
74-88-4
6.1
ug/L
5.0
2.0
1
01/12/2415:19
75-09-2
ND
ug/L
5.0
2.7
1
01/12/2415:19
108-10-1
ND
ug/L
1.0
0.42
1
01/12/2415:19
1634-04-4
ND
ug/L
1.0
0.29
1
01/12/2415:19
100-42-5
ND
ug/L
1.0
0.31
1
01/12/2415:19
630-20-6
ND
ug/L
1.0
0.22
1
01/12/2415:19
79-34-5
0.51J
ug/L
1.0
0.29
1
01/12/2415:19
127-18-4
ND
ug/L
1.0
0.24
1
01/12/2415:19
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
Page 12 of 51

ace
Pace Analytical Services, LLC
Padgaffl�'WfYhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MW-311)
Lab ID:
92708030002
Collected:
01/10/24 15:35
Received: 01/11/24 14:00 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/12/24 15:19
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/12/24 15:19
79-00-5
Trichloroethene
1.5
ug/L
1.0
0.38
1
01/12/24 15:19
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/12/24 15:19
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/12/24 15:19
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/12/24 15:19
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/12/24 15:19
75-01-4
Xylene (Total)
4.8
ug/L
1.0
0.34
1
01/12/24 15:19
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
01/12/24 15:19
460-00-4
1,2-Dichloroethane-d4 (S)
101
%
70-130
1
01/12/24 15:19
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
01/12/24 15:19
2037-26-5
Date: 01/22/2024 02:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 13 of 51

ace
Pace Analytical Services, LLC
PadgamiwYhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MW-11 Lab ID: 92708030003 Collected: 01/10/24 11:20 Received: 01/11/24 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 01/22/2024 02:20 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND
ug/L
3.00
0.597
1 01 /20/24 16:20
01 /20/24 16:20
123-91-1
96.6
%
77.0-127
1 01 /20/24 16:20
01 /20/24 16:20
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
01/12/2415:55
67-64-1
ND
ug/L
10.0
1.8
1
01/12/2415:55
107-13-1
ND
ug/L
1.0
0.34
1
01/12/2415:55
71-43-2
ND
ug/L
1.0
0.47
1
01/12/2415:55
74-97-5
ND
ug/L
1.0
0.31
1
01/12/2415:55
75-27-4
ND
ug/L
1.0
0.34
1
01/12/2415:55
75-25-2
ND
ug/L
2.0
1.7
1
01/12/2415:55
74-83-9
ND
ug/L
5.0
4.0
1
01/12/2415:55
78-93-3
ND
ug/L
2.0
0.36
1
01/12/2415:55
75-15-0
ND
ug/L
1.0
0.33
1
01/12/2415:55
56-23-5
ND
ug/L
1.0
0.28
1
01/12/2415:55
108-90-7
ND
ug/L
1.0
0.65
1
01/12/2415:55
75-00-3
ND
ug/L
1.0
0.43
1
01/12/2415:55
67-66-3
ND
ug/L
1.0
0.54
1
01/12/2415:55
74-87-3
ND
ug/L
2.0
0.34
1
01/12/2415:55
96-12-8
ND
ug/L
1.0
0.36
1
01/12/2415:55
124-48-1
ND
ug/L
1.0
0.27
1
01/12/2415:55
106-93-4
ND
ug/L
1.0
0.39
1
01/12/2415:55
74-95-3
ND
ug/L
1.0
0.34
1
01/12/2415:55
95-50-1
ND
ug/L
1.0
0.33
1
01/12/2415:55
106-46-7
ND
ug/L
1.0
0.37
1
01/12/2415:55
75-34-3
ND
ug/L
1.0
0.32
1
01/12/2415:55
107-06-2
ND
ug/L
1.0
0.35
1
01/12/2415:55
75-35-4
ND
ug/L
1.0
0.38
1
01/12/2415:55
156-59-2
ND
ug/L
1.0
0.40
1
01/12/2415:55
156-60-5
ND
ug/L
1.0
0.36
1
01/12/2415:55
78-87-5
ND
ug/L
1.0
0.36
1
01/12/2415:55
10061-01-5
ND
ug/L
1.0
0.36
1
01/12/2415:55
10061-02-6
ND
ug/L
1.0
0.30
1
01/12/2415:55
100-41-4
ND
ug/L
5.0
0.48
1
01/12/2415:55
591-78-6
ND
ug/L
20.0
9.7
1
01/12/2415:55
74-88-4
ND
ug/L
5.0
2.0
1
01/12/2415:55
75-09-2
ND
ug/L
5.0
2.7
1
01/12/2415:55
108-10-1
ND
ug/L
1.0
0.42
1
01/12/2415:55
1634-04-4
ND
ug/L
1.0
0.29
1
01/12/2415:55
100-42-5
ND
ug/L
1.0
0.31
1
01/12/2415:55
630-20-6
ND
ug/L
1.0
0.22
1
01/12/2415:55
79-34-5
ND
ug/L
1.0
0.29
1
01/12/2415:55
127-18-4
ND
ug/L
1.0
0.24
1
01/12/2415:55
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
Page 14 of 51

ace
Pace Analytical Services, LLC
Padgaftrwyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MW-11
Lab ID:
92708030003
Collected:
01/10/24 11:20
Received: 01/11/24 14:00 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/12/24 15:55
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/12/24 15:55
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
01/12/24 15:55
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/12/24 15:55
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/12/24 15:55
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/12/24 15:55
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/12/24 15:55
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
01/12/24 15:55
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
98
%
70-130
1
01/12/24 15:55
460-00-4
1,2-Dichloroethane-d4 (S)
100
%
70-130
1
01/12/24 15:55
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
01/12/24 15:55
2037-26-5
Date: 01/22/2024 02:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 15 of 51

ace
Pace Analytical Services, LLC
Padg"ifyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MW-11D Lab ID: 92708030004 Collected: 01/10/24 10:55 Received: 01/11/24 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 01/22/2024 02:20 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND
ug/L
3.00
0.597
1 01 /20/24 16:42
01 /20/24 16:42
123-91-1
96.7
%
77.0-127
1 01 /20/24 16:42
01 /20/24 16:42
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
01/12/2415:37
67-64-1
ND
ug/L
10.0
1.8
1
01/12/2415:37
107-13-1
ND
ug/L
1.0
0.34
1
01/12/2415:37
71-43-2
ND
ug/L
1.0
0.47
1
01/12/2415:37
74-97-5
ND
ug/L
1.0
0.31
1
01/12/2415:37
75-27-4
ND
ug/L
1.0
0.34
1
01/12/2415:37
75-25-2
ND
ug/L
2.0
1.7
1
01/12/2415:37
74-83-9
ND
ug/L
5.0
4.0
1
01/12/2415:37
78-93-3
ND
ug/L
2.0
0.36
1
01/12/2415:37
75-15-0
ND
ug/L
1.0
0.33
1
01/12/2415:37
56-23-5
ND
ug/L
1.0
0.28
1
01/12/2415:37
108-90-7
ND
ug/L
1.0
0.65
1
01/12/2415:37
75-00-3
ND
ug/L
1.0
0.43
1
01/12/2415:37
67-66-3
ND
ug/L
1.0
0.54
1
01/12/2415:37
74-87-3
ND
ug/L
2.0
0.34
1
01/12/2415:37
96-12-8
ND
ug/L
1.0
0.36
1
01/12/2415:37
124-48-1
ND
ug/L
1.0
0.27
1
01/12/2415:37
106-93-4
ND
ug/L
1.0
0.39
1
01/12/2415:37
74-95-3
ND
ug/L
1.0
0.34
1
01/12/2415:37
95-50-1
ND
ug/L
1.0
0.33
1
01/12/2415:37
106-46-7
ND
ug/L
1.0
0.37
1
01/12/2415:37
75-34-3
ND
ug/L
1.0
0.32
1
01/12/2415:37
107-06-2
ND
ug/L
1.0
0.35
1
01/12/2415:37
75-35-4
ND
ug/L
1.0
0.38
1
01/12/2415:37
156-59-2
ND
ug/L
1.0
0.40
1
01/12/2415:37
156-60-5
ND
ug/L
1.0
0.36
1
01/12/2415:37
78-87-5
ND
ug/L
1.0
0.36
1
01/12/2415:37
10061-01-5
ND
ug/L
1.0
0.36
1
01/12/2415:37
10061-02-6
ND
ug/L
1.0
0.30
1
01/12/2415:37
100-41-4
ND
ug/L
5.0
0.48
1
01/12/2415:37
591-78-6
ND
ug/L
20.0
9.7
1
01/12/2415:37
74-88-4
ND
ug/L
5.0
2.0
1
01/12/2415:37
75-09-2
ND
ug/L
5.0
2.7
1
01/12/2415:37
108-10-1
ND
ug/L
1.0
0.42
1
01/12/2415:37
1634-04-4
ND
ug/L
1.0
0.29
1
01/12/2415:37
100-42-5
ND
ug/L
1.0
0.31
1
01/12/2415:37
630-20-6
ND
ug/L
1.0
0.22
1
01/12/2415:37
79-34-5
ND
ug/L
1.0
0.29
1
01/12/2415:37
127-18-4
ND
ug/L
1.0
0.24
1
01/12/2415:37
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
Page 16 of 51

ace
Pace Analytical Services, LLC
Padgifyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MW-11D
Lab ID:
92708030004
Collected:
01/10/24 10:55
Received: 01/11/24 14:00 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/12/24 15:37
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/12/24 15:37
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
01/12/24 15:37
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/12/24 15:37
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/12/24 15:37
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/12/24 15:37
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/12/24 15:37
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
01/12/24 15:37
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
100
%
70-130
1
01/12/24 15:37
460-00-4
1,2-Dichloroethane-d4 (S)
100
%
70-130
1
01/12/24 15:37
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
01/12/24 15:37
2037-26-5
Date: 01/22/2024 02:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 17 of 51

ace
Pace Analytical Services, LLC
Padg"rwyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MW-12 Lab ID: 92708030005 Collected: 01/10/24 14:00 Received: 01/11/24 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 01/22/2024 02:20 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND
ug/L
3.00
0.597
1 01 /20/24 17:03
01 /20/24 17:03
123-91-1
96.3
%
77.0-127
1 01/20/2417:03
01/20/2417:03
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
01/12/2416:13
67-64-1
ND
ug/L
10.0
1.8
1
01/12/2416:13
107-13-1
ND
ug/L
1.0
0.34
1
01/12/2416:13
71-43-2
ND
ug/L
1.0
0.47
1
01/12/2416:13
74-97-5
ND
ug/L
1.0
0.31
1
01/12/2416:13
75-27-4
ND
ug/L
1.0
0.34
1
01/12/2416:13
75-25-2
ND
ug/L
2.0
1.7
1
01/12/2416:13
74-83-9
ND
ug/L
5.0
4.0
1
01/12/2416:13
78-93-3
ND
ug/L
2.0
0.36
1
01/12/2416:13
75-15-0
ND
ug/L
1.0
0.33
1
01/12/2416:13
56-23-5
ND
ug/L
1.0
0.28
1
01/12/2416:13
108-90-7
ND
ug/L
1.0
0.65
1
01/12/2416:13
75-00-3
ND
ug/L
1.0
0.43
1
01/12/2416:13
67-66-3
ND
ug/L
1.0
0.54
1
01/12/2416:13
74-87-3
ND
ug/L
2.0
0.34
1
01/12/2416:13
96-12-8
ND
ug/L
1.0
0.36
1
01/12/2416:13
124-48-1
ND
ug/L
1.0
0.27
1
01/12/2416:13
106-93-4
ND
ug/L
1.0
0.39
1
01/12/2416:13
74-95-3
ND
ug/L
1.0
0.34
1
01/12/2416:13
95-50-1
ND
ug/L
1.0
0.33
1
01/12/2416:13
106-46-7
ND
ug/L
1.0
0.37
1
01/12/2416:13
75-34-3
ND
ug/L
1.0
0.32
1
01/12/2416:13
107-06-2
ND
ug/L
1.0
0.35
1
01/12/2416:13
75-35-4
ND
ug/L
1.0
0.38
1
01/12/2416:13
156-59-2
ND
ug/L
1.0
0.40
1
01/12/2416:13
156-60-5
ND
ug/L
1.0
0.36
1
01/12/2416:13
78-87-5
ND
ug/L
1.0
0.36
1
01/12/2416:13
10061-01-5
ND
ug/L
1.0
0.36
1
01/12/2416:13
10061-02-6
ND
ug/L
1.0
0.30
1
01/12/2416:13
100-41-4
ND
ug/L
5.0
0.48
1
01/12/2416:13
591-78-6
ND
ug/L
20.0
9.7
1
01/12/2416:13
74-88-4
ND
ug/L
5.0
2.0
1
01/12/2416:13
75-09-2
ND
ug/L
5.0
2.7
1
01/12/2416:13
108-10-1
ND
ug/L
1.0
0.42
1
01/12/2416:13
1634-04-4
ND
ug/L
1.0
0.29
1
01/12/2416:13
100-42-5
ND
ug/L
1.0
0.31
1
01/12/2416:13
630-20-6
ND
ug/L
1.0
0.22
1
01/12/2416:13
79-34-5
ND
ug/L
1.0
0.29
1
01/12/2416:13
127-18-4
ND
ug/L
1.0
0.24
1
01/12/2416:13
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
Page 18 of 51

ace
Pace Analytical Services, LLC
Padgop1biwyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MW-12
Lab ID:
92708030005
Collected:
01/10/24 14:00
Received: 01/11/24 14:00 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/12/24 16:13
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/12/24 16:13
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
01/12/24 16:13
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/12/24 16:13
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/12/24 16:13
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/12/24 16:13
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/12/24 16:13
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
01/12/24 16:13
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
01/12/24 16:13
460-00-4
1,2-Dichloroethane-d4 (S)
100
%
70-130
1
01/12/24 16:13
17060-07-0
Toluene-d8 (S)
98
%
70-130
1
01/12/24 16:13
2037-26-5
Date: 01/22/2024 02:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 19 of 51

ace
Pace Analytical Services, LLC
Padgop1ypyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MW-12D Lab ID: 92708030006 Collected: 01/10/24 13:40 Received: 01/11/24 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 01/22/2024 02:20 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND
ug/L
3.00
0.597
1 01 /20/24 17:25
01 /20/24 17:25
123-91-1
96.4
%
77.0-127
1 01/20/2417:25
01/20/2417:25
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
01/12/2416:32
67-64-1
ND
ug/L
10.0
1.8
1
01/12/2416:32
107-13-1
ND
ug/L
1.0
0.34
1
01/12/2416:32
71-43-2
ND
ug/L
1.0
0.47
1
01/12/2416:32
74-97-5
ND
ug/L
1.0
0.31
1
01/12/2416:32
75-27-4
ND
ug/L
1.0
0.34
1
01/12/2416:32
75-25-2
ND
ug/L
2.0
1.7
1
01/12/2416:32
74-83-9
ND
ug/L
5.0
4.0
1
01/12/2416:32
78-93-3
ND
ug/L
2.0
0.36
1
01/12/2416:32
75-15-0
ND
ug/L
1.0
0.33
1
01/12/2416:32
56-23-5
ND
ug/L
1.0
0.28
1
01/12/2416:32
108-90-7
ND
ug/L
1.0
0.65
1
01/12/2416:32
75-00-3
ND
ug/L
1.0
0.43
1
01/12/2416:32
67-66-3
ND
ug/L
1.0
0.54
1
01/12/2416:32
74-87-3
ND
ug/L
2.0
0.34
1
01/12/2416:32
96-12-8
ND
ug/L
1.0
0.36
1
01/12/2416:32
124-48-1
ND
ug/L
1.0
0.27
1
01/12/2416:32
106-93-4
ND
ug/L
1.0
0.39
1
01/12/2416:32
74-95-3
ND
ug/L
1.0
0.34
1
01/12/2416:32
95-50-1
ND
ug/L
1.0
0.33
1
01/12/2416:32
106-46-7
ND
ug/L
1.0
0.37
1
01/12/2416:32
75-34-3
ND
ug/L
1.0
0.32
1
01/12/2416:32
107-06-2
ND
ug/L
1.0
0.35
1
01/12/2416:32
75-35-4
ND
ug/L
1.0
0.38
1
01/12/2416:32
156-59-2
ND
ug/L
1.0
0.40
1
01/12/2416:32
156-60-5
ND
ug/L
1.0
0.36
1
01/12/2416:32
78-87-5
ND
ug/L
1.0
0.36
1
01/12/2416:32
10061-01-5
ND
ug/L
1.0
0.36
1
01/12/2416:32
10061-02-6
ND
ug/L
1.0
0.30
1
01/12/2416:32
100-41-4
ND
ug/L
5.0
0.48
1
01/12/2416:32
591-78-6
ND
ug/L
20.0
9.7
1
01/12/2416:32
74-88-4
ND
ug/L
5.0
2.0
1
01/12/2416:32
75-09-2
ND
ug/L
5.0
2.7
1
01/12/2416:32
108-10-1
ND
ug/L
1.0
0.42
1
01/12/2416:32
1634-04-4
ND
ug/L
1.0
0.29
1
01/12/2416:32
100-42-5
ND
ug/L
1.0
0.31
1
01/12/2416:32
630-20-6
ND
ug/L
1.0
0.22
1
01/12/2416:32
79-34-5
ND
ug/L
1.0
0.29
1
01/12/2416:32
127-18-4
ND
ug/L
1.0
0.24
1
01/12/2416:32
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
Page 20 of 51

ace
Pace Analytical Services, LLC
Padgom eyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MW-12D
Lab ID:
92708030006
Collected:
01/10/24 13:40
Received: 01/11/24 14:00 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/12/24 16:32
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/12/24 16:32
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
01/12/24 16:32
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/12/24 16:32
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/12/24 16:32
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/12/24 16:32
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/12/24 16:32
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
01/12/24 16:32
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
98
%
70-130
1
01/12/24 16:32
460-00-4
1,2-Dichloroethane-d4 (S)
100
%
70-130
1
01/12/24 16:32
17060-07-0
Toluene-d8 (S)
98
%
70-130
1
01/12/24 16:32
2037-26-5
Date: 01/22/2024 02:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 21 of 51

ace
Pace Analytical Services, LLC
Padgop1lsieyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MW-4R Lab ID: 92708030007 Collected: 01/10/24 11:20 Received: 01/11/24 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 01/22/2024 02:20 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND
ug/L
3.00
0.597
1 01 /20/24 17:46
01 /20/24 17:46
123-91-1
96.0
%
77.0-127
1 01 /20/24 17:46
01 /20/24 17:46
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
01/12/2416:50
67-64-1
ND
ug/L
10.0
1.8
1
01/12/2416:50
107-13-1
ND
ug/L
1.0
0.34
1
01/12/2416:50
71-43-2
ND
ug/L
1.0
0.47
1
01/12/2416:50
74-97-5
ND
ug/L
1.0
0.31
1
01/12/2416:50
75-27-4
ND
ug/L
1.0
0.34
1
01/12/2416:50
75-25-2
ND
ug/L
2.0
1.7
1
01/12/2416:50
74-83-9
ND
ug/L
5.0
4.0
1
01/12/2416:50
78-93-3
ND
ug/L
2.0
0.36
1
01/12/2416:50
75-15-0
ND
ug/L
1.0
0.33
1
01/12/2416:50
56-23-5
ND
ug/L
1.0
0.28
1
01/12/2416:50
108-90-7
ND
ug/L
1.0
0.65
1
01/12/2416:50
75-00-3
ND
ug/L
1.0
0.43
1
01/12/2416:50
67-66-3
ND
ug/L
1.0
0.54
1
01/12/2416:50
74-87-3
ND
ug/L
2.0
0.34
1
01/12/2416:50
96-12-8
ND
ug/L
1.0
0.36
1
01/12/2416:50
124-48-1
ND
ug/L
1.0
0.27
1
01/12/2416:50
106-93-4
ND
ug/L
1.0
0.39
1
01/12/2416:50
74-95-3
ND
ug/L
1.0
0.34
1
01/12/2416:50
95-50-1
ND
ug/L
1.0
0.33
1
01/12/2416:50
106-46-7
ND
ug/L
1.0
0.37
1
01/12/2416:50
75-34-3
ND
ug/L
1.0
0.32
1
01/12/2416:50
107-06-2
ND
ug/L
1.0
0.35
1
01/12/2416:50
75-35-4
ND
ug/L
1.0
0.38
1
01/12/2416:50
156-59-2
ND
ug/L
1.0
0.40
1
01/12/2416:50
156-60-5
ND
ug/L
1.0
0.36
1
01/12/2416:50
78-87-5
ND
ug/L
1.0
0.36
1
01/12/2416:50
10061-01-5
ND
ug/L
1.0
0.36
1
01/12/2416:50
10061-02-6
ND
ug/L
1.0
0.30
1
01/12/2416:50
100-41-4
ND
ug/L
5.0
0.48
1
01/12/2416:50
591-78-6
ND
ug/L
20.0
9.7
1
01/12/2416:50
74-88-4
ND
ug/L
5.0
2.0
1
01/12/2416:50
75-09-2
ND
ug/L
5.0
2.7
1
01/12/2416:50
108-10-1
ND
ug/L
1.0
0.42
1
01/12/2416:50
1634-04-4
ND
ug/L
1.0
0.29
1
01/12/2416:50
100-42-5
ND
ug/L
1.0
0.31
1
01/12/2416:50
630-20-6
ND
ug/L
1.0
0.22
1
01/12/2416:50
79-34-5
0.97J
ug/L
1.0
0.29
1
01/12/2416:50
127-18-4
ND
ug/L
1.0
0.24
1
01/12/2416:50
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
Page 22 of 51

ace
Pace Analytical Services, LLC
Pad8opoirwyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MW-4R
Lab ID:
92708030007
Collected:
01/10/24 11:20
Received: 01/11/24 14:00 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/12/24 16:50
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/12/24 16:50
79-00-5
Trichloroethene
0.74J
ug/L
1.0
0.38
1
01/12/24 16:50
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/12/24 16:50
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/12/24 16:50
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/12/24 16:50
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/12/24 16:50
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
01/12/24 16:50
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
98
%
70-130
1
01/12/24 16:50
460-00-4
1,2-Dichloroethane-d4 (S)
99
%
70-130
1
01/12/24 16:50
17060-07-0
Toluene-d8 (S)
98
%
70-130
1
01/12/24 16:50
2037-26-5
Date: 01/22/2024 02:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 23 of 51

ace
Pace Analytical Services, LLC
Padgom eyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MW-4DR Lab ID: 92708030008 Collected: 01/10/24 12:50 Received: 01/11/24 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 01/22/2024 02:20 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND
ug/L
3.00
0.597
1 01 /20/24 18:08
01 /20/24 18:08
123-91-1
96.2
%
77.0-127
1 01 /20/24 18:08
01 /20/24 18:08
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
01/12/2417:08
67-64-1
ND
ug/L
10.0
1.8
1
01/12/2417:08
107-13-1
ND
ug/L
1.0
0.34
1
01/12/2417:08
71-43-2
ND
ug/L
1.0
0.47
1
01/12/2417:08
74-97-5
ND
ug/L
1.0
0.31
1
01/12/2417:08
75-27-4
ND
ug/L
1.0
0.34
1
01/12/2417:08
75-25-2
ND
ug/L
2.0
1.7
1
01/12/2417:08
74-83-9
ND
ug/L
5.0
4.0
1
01/12/2417:08
78-93-3
ND
ug/L
2.0
0.36
1
01/12/2417:08
75-15-0
ND
ug/L
1.0
0.33
1
01/12/2417:08
56-23-5
ND
ug/L
1.0
0.28
1
01/12/2417:08
108-90-7
ND
ug/L
1.0
0.65
1
01/12/2417:08
75-00-3
ND
ug/L
1.0
0.43
1
01/12/2417:08
67-66-3
ND
ug/L
1.0
0.54
1
01/12/2417:08
74-87-3
ND
ug/L
2.0
0.34
1
01/12/2417:08
96-12-8
ND
ug/L
1.0
0.36
1
01/12/2417:08
124-48-1
ND
ug/L
1.0
0.27
1
01/12/2417:08
106-93-4
ND
ug/L
1.0
0.39
1
01/12/2417:08
74-95-3
ND
ug/L
1.0
0.34
1
01/12/2417:08
95-50-1
ND
ug/L
1.0
0.33
1
01/12/2417:08
106-46-7
ND
ug/L
1.0
0.37
1
01/12/2417:08
75-34-3
ND
ug/L
1.0
0.32
1
01/12/2417:08
107-06-2
ND
ug/L
1.0
0.35
1
01/12/2417:08
75-35-4
1.9
ug/L
1.0
0.38
1
01/12/2417:08
156-59-2
ND
ug/L
1.0
0.40
1
01/12/2417:08
156-60-5
ND
ug/L
1.0
0.36
1
01/12/2417:08
78-87-5
ND
ug/L
1.0
0.36
1
01/12/2417:08
10061-01-5
ND
ug/L
1.0
0.36
1
01/12/2417:08
10061-02-6
ND
ug/L
1.0
0.30
1
01/12/2417:08
100-41-4
ND
ug/L
5.0
0.48
1
01/12/2417:08
591-78-6
ND
ug/L
20.0
9.7
1
01/12/2417:08
74-88-4
ND
ug/L
5.0
2.0
1
01/12/2417:08
75-09-2
ND
ug/L
5.0
2.7
1
01/12/2417:08
108-10-1
ND
ug/L
1.0
0.42
1
01/12/2417:08
1634-04-4
ND
ug/L
1.0
0.29
1
01/12/2417:08
100-42-5
ND
ug/L
1.0
0.31
1
01/12/2417:08
630-20-6
ND
ug/L
1.0
0.22
1
01/12/2417:08
79-34-5
ND
ug/L
1.0
0.29
1
01/12/2417:08
127-18-4
ND
ug/L
1.0
0.24
1
01/12/2417:08
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
Page 24 of 51

ace
Pace Analytical Services, LLC
Pa8gom eyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MW-4DR
Lab ID:
92708030008
Collected:
01/10/24 12:50
Received: 01/11/24 14:00 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/12/24 17:08
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/12/24 17:08
79-00-5
Trichloroethene
0.78J
ug/L
1.0
0.38
1
01/12/24 17:08
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/12/24 17:08
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/12/24 17:08
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/12/24 17:08
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/12/24 17:08
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
01/12/24 17:08
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
98
%
70-130
1
01/12/24 17:08
460-00-4
1,2-Dichloroethane-d4 (S)
100
%
70-130
1
01/12/24 17:08
17060-07-0
Toluene-d8 (S)
98
%
70-130
1
01/12/24 17:08
2037-26-5
Date: 01/22/2024 02:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 25 of 51

ace
Pace Analytical Services, LLC
Padgom eyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MNS_TB-20240110-0800 Lab ID: 92708030009 Collected: 01/10/24 08:00 Received: 01/11/24 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 01/22/2024 02:20 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND
ug/L
3.00
0.597
1 01 /20/24 18:29
01 /20/24 18:29
123-91-1
95.9
%
77.0-127
1 01 /20/24 18:29
01 /20/24 18:29
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
01/12/2414:06
67-64-1
ND
ug/L
10.0
1.8
1
01/12/2414:06
107-13-1
ND
ug/L
1.0
0.34
1
01/12/2414:06
71-43-2
ND
ug/L
1.0
0.47
1
01/12/2414:06
74-97-5
ND
ug/L
1.0
0.31
1
01/12/2414:06
75-27-4
ND
ug/L
1.0
0.34
1
01/12/2414:06
75-25-2
ND
ug/L
2.0
1.7
1
01/12/2414:06
74-83-9
ND
ug/L
5.0
4.0
1
01/12/2414:06
78-93-3
ND
ug/L
2.0
0.36
1
01/12/2414:06
75-15-0
ND
ug/L
1.0
0.33
1
01/12/2414:06
56-23-5
ND
ug/L
1.0
0.28
1
01/12/2414:06
108-90-7
ND
ug/L
1.0
0.65
1
01/12/2414:06
75-00-3
ND
ug/L
1.0
0.43
1
01/12/2414:06
67-66-3
ND
ug/L
1.0
0.54
1
01/12/2414:06
74-87-3
ND
ug/L
2.0
0.34
1
01/12/2414:06
96-12-8
ND
ug/L
1.0
0.36
1
01/12/2414:06
124-48-1
ND
ug/L
1.0
0.27
1
01/12/2414:06
106-93-4
ND
ug/L
1.0
0.39
1
01/12/2414:06
74-95-3
ND
ug/L
1.0
0.34
1
01/12/2414:06
95-50-1
ND
ug/L
1.0
0.33
1
01/12/2414:06
106-46-7
ND
ug/L
1.0
0.37
1
01/12/2414:06
75-34-3
ND
ug/L
1.0
0.32
1
01/12/2414:06
107-06-2
ND
ug/L
1.0
0.35
1
01/12/2414:06
75-35-4
ND
ug/L
1.0
0.38
1
01/12/2414:06
156-59-2
ND
ug/L
1.0
0.40
1
01/12/2414:06
156-60-5
ND
ug/L
1.0
0.36
1
01/12/2414:06
78-87-5
ND
ug/L
1.0
0.36
1
01/12/2414:06
10061-01-5
ND
ug/L
1.0
0.36
1
01/12/2414:06
10061-02-6
ND
ug/L
1.0
0.30
1
01/12/2414:06
100-41-4
ND
ug/L
5.0
0.48
1
01/12/2414:06
591-78-6
ND
ug/L
20.0
9.7
1
01/12/2414:06
74-88-4
ND
ug/L
5.0
2.0
1
01/12/2414:06
75-09-2
ND
ug/L
5.0
2.7
1
01/12/2414:06
108-10-1
ND
ug/L
1.0
0.42
1
01/12/2414:06
1634-04-4
ND
ug/L
1.0
0.29
1
01/12/2414:06
100-42-5
ND
ug/L
1.0
0.31
1
01/12/2414:06
630-20-6
ND
ug/L
1.0
0.22
1
01/12/2414:06
79-34-5
ND
ug/L
1.0
0.29
1
01/12/2414:06
127-18-4
ND
ug/L
1.0
0.24
1
01/12/2414:06
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
Page 26 of 51

ace
Pace Analytical Services, LLC
Padgom eyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MNS_TB-20240110-0800
Lab ID:
92708030009
Collected:
01/10/24
08:00
Received: 01/11/24 14:00 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/12/24 14:06
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/12/24 14:06
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
01/12/24 14:06
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/12/24 14:06
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/12/24 14:06
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/12/24 14:06
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/12/24 14:06
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
01/12/24 14:06
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
01/12/24 14:06
460-00-4
1,2-Dichloroethane-d4 (S)
100
%
70-130
1
01/12/24 14:06
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
01/12/24 14:06
2037-26-5
Date: 01/22/2024 02:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 27 of 51

ace
Pace Analytical Services, LLC
Padgom eyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MNS_FB-20240110-1020 Lab ID: 92708030010 Collected: 01/10/24 10:20 Received: 01/11/24 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 01/22/2024 02:20 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND
ug/L
3.00
0.597
1 01 /20/24 18:51
01 /20/24 18:51
123-91-1
96.0
%
77.0-127
1 01 /20/24 18:51
01 /20/24 18:51
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
01/12/2414:24
67-64-1
ND
ug/L
10.0
1.8
1
01/12/2414:24
107-13-1
ND
ug/L
1.0
0.34
1
01/12/2414:24
71-43-2
ND
ug/L
1.0
0.47
1
01/12/2414:24
74-97-5
ND
ug/L
1.0
0.31
1
01/12/2414:24
75-27-4
ND
ug/L
1.0
0.34
1
01/12/2414:24
75-25-2
ND
ug/L
2.0
1.7
1
01/12/2414:24
74-83-9
ND
ug/L
5.0
4.0
1
01/12/2414:24
78-93-3
ND
ug/L
2.0
0.36
1
01/12/2414:24
75-15-0
ND
ug/L
1.0
0.33
1
01/12/2414:24
56-23-5
ND
ug/L
1.0
0.28
1
01/12/2414:24
108-90-7
ND
ug/L
1.0
0.65
1
01/12/2414:24
75-00-3
ND
ug/L
1.0
0.43
1
01/12/2414:24
67-66-3
ND
ug/L
1.0
0.54
1
01/12/2414:24
74-87-3
ND
ug/L
2.0
0.34
1
01/12/2414:24
96-12-8
ND
ug/L
1.0
0.36
1
01/12/2414:24
124-48-1
ND
ug/L
1.0
0.27
1
01/12/2414:24
106-93-4
ND
ug/L
1.0
0.39
1
01/12/2414:24
74-95-3
ND
ug/L
1.0
0.34
1
01/12/2414:24
95-50-1
ND
ug/L
1.0
0.33
1
01/12/2414:24
106-46-7
ND
ug/L
1.0
0.37
1
01/12/2414:24
75-34-3
ND
ug/L
1.0
0.32
1
01/12/2414:24
107-06-2
ND
ug/L
1.0
0.35
1
01/12/2414:24
75-35-4
ND
ug/L
1.0
0.38
1
01/12/2414:24
156-59-2
ND
ug/L
1.0
0.40
1
01/12/2414:24
156-60-5
ND
ug/L
1.0
0.36
1
01/12/2414:24
78-87-5
ND
ug/L
1.0
0.36
1
01/12/2414:24
10061-01-5
ND
ug/L
1.0
0.36
1
01/12/2414:24
10061-02-6
ND
ug/L
1.0
0.30
1
01/12/2414:24
100-41-4
ND
ug/L
5.0
0.48
1
01/12/2414:24
591-78-6
ND
ug/L
20.0
9.7
1
01/12/2414:24
74-88-4
ND
ug/L
5.0
2.0
1
01/12/2414:24
75-09-2
ND
ug/L
5.0
2.7
1
01/12/2414:24
108-10-1
ND
ug/L
1.0
0.42
1
01/12/2414:24
1634-04-4
ND
ug/L
1.0
0.29
1
01/12/2414:24
100-42-5
ND
ug/L
1.0
0.31
1
01/12/2414:24
630-20-6
ND
ug/L
1.0
0.22
1
01/12/2414:24
79-34-5
ND
ug/L
1.0
0.29
1
01/12/2414:24
127-18-4
ND
ug/L
1.0
0.24
1
01/12/2414:24
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
Page 28 of 51

ace
Pace Analytical Services, LLC
PadgaP28iWY441e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MNS_FB-20240110-1020
Lab ID:
92708030010
Collected:
01/10/24
10:20
Received: 01/11/24 14:00 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/12/24 14:24
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/12/24 14:24
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
01/12/24 14:24
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/12/24 14:24
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/12/24 14:24
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/12/24 14:24
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/12/24 14:24
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
01/12/24 14:24
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
01/12/24 14:24
460-00-4
1,2-Dichloroethane-d4 (S)
100
%
70-130
1
01/12/24 14:24
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
01/12/24 14:24
2037-26-5
Date: 01/22/2024 02:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 29 of 51

ace
Pace Analytical Services, LLC
Padg"Iirpyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MNS_FD-20240110-1 Lab ID: 92708030011 Collected: 01/10/24 00:00 Received: 01/11/24 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 01/22/2024 02:20 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND
ug/L
3.00
0.597
1 01 /20/24 19:12
01 /20/24 19:12
123-91-1
96.3
%
77.0-127
1 01 /20/24 19:12
01 /20/24 19:12
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
01/12/2417:27
67-64-1
ND
ug/L
10.0
1.8
1
01/12/2417:27
107-13-1
ND
ug/L
1.0
0.34
1
01/12/2417:27
71-43-2
ND
ug/L
1.0
0.47
1
01/12/2417:27
74-97-5
ND
ug/L
1.0
0.31
1
01/12/2417:27
75-27-4
ND
ug/L
1.0
0.34
1
01/12/2417:27
75-25-2
ND
ug/L
2.0
1.7
1
01/12/2417:27
74-83-9
ND
ug/L
5.0
4.0
1
01/12/2417:27
78-93-3
ND
ug/L
2.0
0.36
1
01/12/2417:27
75-15-0
ND
ug/L
1.0
0.33
1
01/12/2417:27
56-23-5
ND
ug/L
1.0
0.28
1
01/12/2417:27
108-90-7
ND
ug/L
1.0
0.65
1
01/12/2417:27
75-00-3
ND
ug/L
1.0
0.43
1
01/12/2417:27
67-66-3
ND
ug/L
1.0
0.54
1
01/12/2417:27
74-87-3
ND
ug/L
2.0
0.34
1
01/12/2417:27
96-12-8
ND
ug/L
1.0
0.36
1
01/12/2417:27
124-48-1
ND
ug/L
1.0
0.27
1
01/12/2417:27
106-93-4
ND
ug/L
1.0
0.39
1
01/12/2417:27
74-95-3
ND
ug/L
1.0
0.34
1
01/12/2417:27
95-50-1
ND
ug/L
1.0
0.33
1
01/12/2417:27
106-46-7
ND
ug/L
1.0
0.37
1
01/12/2417:27
75-34-3
ND
ug/L
1.0
0.32
1
01/12/2417:27
107-06-2
ND
ug/L
1.0
0.35
1
01/12/2417:27
75-35-4
ND
ug/L
1.0
0.38
1
01/12/2417:27
156-59-2
ND
ug/L
1.0
0.40
1
01/12/2417:27
156-60-5
ND
ug/L
1.0
0.36
1
01/12/2417:27
78-87-5
ND
ug/L
1.0
0.36
1
01/12/2417:27
10061-01-5
ND
ug/L
1.0
0.36
1
01/12/2417:27
10061-02-6
ND
ug/L
1.0
0.30
1
01/12/2417:27
100-41-4
ND
ug/L
5.0
0.48
1
01/12/2417:27
591-78-6
ND
ug/L
20.0
9.7
1
01/12/2417:27
74-88-4
ND
ug/L
5.0
2.0
1
01/12/2417:27
75-09-2
ND
ug/L
5.0
2.7
1
01/12/2417:27
108-10-1
ND
ug/L
1.0
0.42
1
01/12/2417:27
1634-04-4
ND
ug/L
1.0
0.29
1
01/12/2417:27
100-42-5
ND
ug/L
1.0
0.31
1
01/12/2417:27
630-20-6
ND
ug/L
1.0
0.22
1
01/12/2417:27
79-34-5
ND
ug/L
1.0
0.29
1
01/12/2417:27
127-18-4
ND
ug/L
1.0
0.24
1
01/12/2417:27
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
Page 30 of 51

ace
Pace Analytical Services, LLC
Padgaphrwyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MNS_FD-20240110-1
Lab ID:
92708030011
Collected:
01/10/24
00:00
Received: 01/11/24 14:00 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/12/24 17:27
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/12/24 17:27
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
01/12/24 17:27
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/12/24 17:27
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/12/24 17:27
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/12/24 17:27
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/12/24 17:27
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
01/12/24 17:27
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
97
%
70-130
1
01/12/24 17:27
460-00-4
1,2-Dichloroethane-d4 (S)
101
%
70-130
1
01/12/24 17:27
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
01/12/24 17:27
2037-26-5
Date: 01/22/2024 02:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 31 of 51

ace
Pace Analytical Services, LLC
Padg iwyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MW-3BR Lab ID: 92708030012 Collected: 01/10/24 15:30 Received: 01/11/24 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 01/22/2024 02:20 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND
ug/L
3.00
0.597
1 01 /20/24 19:34
01 /20/24 19:34
123-91-1
95.8
%
77.0-127
1 01 /20/24 19:34
01 /20/24 19:34
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
01/12/2418:22
67-64-1
ND
ug/L
10.0
1.8
1
01/12/2418:22
107-13-1
ND
ug/L
1.0
0.34
1
01/12/2418:22
71-43-2
ND
ug/L
1.0
0.47
1
01/12/2418:22
74-97-5
ND
ug/L
1.0
0.31
1
01/12/2418:22
75-27-4
ND
ug/L
1.0
0.34
1
01/12/2418:22
75-25-2
ND
ug/L
2.0
1.7
1
01/12/2418:22
74-83-9
ND
ug/L
5.0
4.0
1
01/12/2418:22
78-93-3
ND
ug/L
2.0
0.36
1
01/12/2418:22
75-15-0
ND
ug/L
1.0
0.33
1
01/12/2418:22
56-23-5
ND
ug/L
1.0
0.28
1
01/12/2418:22
108-90-7
ND
ug/L
1.0
0.65
1
01/12/2418:22
75-00-3
ND
ug/L
1.0
0.43
1
01/12/2418:22
67-66-3
ND
ug/L
1.0
0.54
1
01/12/2418:22
74-87-3
ND
ug/L
2.0
0.34
1
01/12/2418:22
96-12-8
ND
ug/L
1.0
0.36
1
01/12/2418:22
124-48-1
ND
ug/L
1.0
0.27
1
01/12/2418:22
106-93-4
ND
ug/L
1.0
0.39
1
01/12/2418:22
74-95-3
ND
ug/L
1.0
0.34
1
01/12/2418:22
95-50-1
ND
ug/L
1.0
0.33
1
01/12/2418:22
106-46-7
1.2
ug/L
1.0
0.37
1
01/12/2418:22
75-34-3
ND
ug/L
1.0
0.32
1
01/12/2418:22
107-06-2
ND
ug/L
1.0
0.35
1
01/12/2418:22
75-35-4
6.2
ug/L
1.0
0.38
1
01/12/2418:22
156-59-2
ND
ug/L
1.0
0.40
1
01/12/2418:22
156-60-5
ND
ug/L
1.0
0.36
1
01/12/2418:22
78-87-5
ND
ug/L
1.0
0.36
1
01/12/2418:22
10061-01-5
ND
ug/L
1.0
0.36
1
01/12/2418:22
10061-02-6
ND
ug/L
1.0
0.30
1
01/12/2418:22
100-41-4
ND
ug/L
5.0
0.48
1
01/12/2418:22
591-78-6
ND
ug/L
20.0
9.7
1
01/12/2418:22
74-88-4
16.9
ug/L
5.0
2.0
1
01/12/2418:22
75-09-2
ND
ug/L
5.0
2.7
1
01/12/2418:22
108-10-1
ND
ug/L
1.0
0.42
1
01/12/2418:22
1634-04-4
ND
ug/L
1.0
0.29
1
01/12/2418:22
100-42-5
ND
ug/L
1.0
0.31
1
01/12/2418:22
630-20-6
ND
ug/L
1.0
0.22
1
01/12/2418:22
79-34-5
0.69J
ug/L
1.0
0.29
1
01/12/2418:22
127-18-4
ND
ug/L
1.0
0.24
1
01/12/2418:22
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
Page 32 of 51

ace
Pace Analytical Services, LLC
Padff4irwyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MW-313R
Lab ID:
92708030012
Collected:
01/10/24 15:30
Received: 01/11/24 14:00 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/12/24 18:22
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/12/24 18:22
79-00-5
Trichloroethene
1.9
ug/L
1.0
0.38
1
01/12/24 18:22
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/12/24 18:22
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/12/24 18:22
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/12/24 18:22
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/12/24 18:22
75-01-4
Xylene (Total)
101
ug/L
1.0
0.34
1
01/12/24 18:22
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
01/12/24 18:22
460-00-4
1,2-Dichloroethane-d4 (S)
98
%
70-130
1
01/12/24 18:22
17060-07-0
Toluene-d8 (S)
110
%
70-130
1
01/12/24 18:22
2037-26-5
Date: 01/22/2024 02:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 33 of 51

ace
Pace Analytical Services, LLC
Padg"rwyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MW-4BRR Lab ID: 92708030013 Collected: 01/10/24 14:15 Received: 01/11/24 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 01/22/2024 02:20 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND
ug/L
3.00
0.597
1 01 /20/24 19:55
01 /20/24 19:55
123-91-1
96.7
%
77.0-127
1 01 /20/24 19:55
01 /20/24 19:55
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
65.0
ug/L
25.0
5.1
1
01/12/2418:40
67-64-1
ND
ug/L
10.0
1.8
1
01/12/2418:40
107-13-1
ND
ug/L
1.0
0.34
1
01/12/2418:40
71-43-2
ND
ug/L
1.0
0.47
1
01/12/2418:40
74-97-5
ND
ug/L
1.0
0.31
1
01/12/2418:40
75-27-4
ND
ug/L
1.0
0.34
1
01/12/2418:40
75-25-2
ND
ug/L
2.0
1.7
1
01/12/2418:40
74-83-9
ND
ug/L
5.0
4.0
1
01/12/2418:40
78-93-3
12.8
ug/L
2.0
0.36
1
01/12/2418:40
75-15-0
ND
ug/L
1.0
0.33
1
01/12/2418:40
56-23-5
ND
ug/L
1.0
0.28
1
01/12/2418:40
108-90-7
ND
ug/L
1.0
0.65
1
01/12/2418:40
75-00-3
ND
ug/L
1.0
0.43
1
01/12/2418:40
67-66-3
ND
ug/L
1.0
0.54
1
01/12/2418:40
74-87-3
ND
ug/L
2.0
0.34
1
01/12/2418:40
96-12-8
ND
ug/L
1.0
0.36
1
01/12/2418:40
124-48-1
ND
ug/L
1.0
0.27
1
01/12/2418:40
106-93-4
ND
ug/L
1.0
0.39
1
01/12/2418:40
74-95-3
ND
ug/L
1.0
0.34
1
01/12/2418:40
95-50-1
ND
ug/L
1.0
0.33
1
01/12/2418:40
106-46-7
ND
ug/L
1.0
0.37
1
01/12/2418:40
75-34-3
ND
ug/L
1.0
0.32
1
01/12/2418:40
107-06-2
ND
ug/L
1.0
0.35
1
01/12/2418:40
75-35-4
1.0
ug/L
1.0
0.38
1
01/12/2418:40
156-59-2
ND
ug/L
1.0
0.40
1
01/12/2418:40
156-60-5
ND
ug/L
1.0
0.36
1
01/12/2418:40
78-87-5
ND
ug/L
1.0
0.36
1
01/12/2418:40
10061-01-5
ND
ug/L
1.0
0.36
1
01/12/2418:40
10061-02-6
ND
ug/L
1.0
0.30
1
01/12/2418:40
100-41-4
ND
ug/L
5.0
0.48
1
01/12/2418:40
591-78-6
ND
ug/L
20.0
9.7
1
01/12/2418:40
74-88-4
ND
ug/L
5.0
2.0
1
01/12/2418:40
75-09-2
ND
ug/L
5.0
2.7
1
01/12/2418:40
108-10-1
ND
ug/L
1.0
0.42
1
01/12/2418:40
1634-04-4
ND
ug/L
1.0
0.29
1
01/12/2418:40
100-42-5
ND
ug/L
1.0
0.31
1
01/12/2418:40
630-20-6
ND
ug/L
1.0
0.22
1
01/12/2418:40
79-34-5
ND
ug/L
1.0
0.29
1
01/12/2418:40
127-18-4
ND
ug/L
1.0
0.24
1
01/12/2418:40
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
Page 34 of 51

ace
Pace Analytical Services, LLC
Pad Arwyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MW-4BRR
Lab ID:
92708030013
Collected:
01/10/24 14:15
Received: 01/11/24 14:00 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/12/24 18:40
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/12/24 18:40
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
01/12/24 18:40
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/12/24 18:40
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/12/24 18:40
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/12/24 18:40
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/12/24 18:40
75-01-4
Xylene (Total)
0.65J
ug/L
1.0
0.34
1
01/12/24 18:40
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
101
%
70-130
1
01/12/24 18:40
460-00-4
1,2-Dichloroethane-d4 (S)
98
%
70-130
1
01/12/24 18:40
17060-07-0
Toluene-d8 (S)
98
%
70-130
1
01/12/24 18:40
2037-26-5
Date: 01/22/2024 02:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 35 of 51

ace
Pace Analytical Services, LLC
Padg"ifyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MW-11BR Lab ID: 92708030014 Collected: 01/10/24 12:05 Received: 01/11/24 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)
Surrogates
Toluene-d8 (S)
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 01/22/2024 02:20 PM
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
ND
ug/L
3.00
0.597
1 01 /20/24 20:17
01 /20/24 20:17
123-91-1
96.3
%
77.0-127
1 01 /20/24 20:17
01 /20/24 20:17
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
01/12/2417:45
67-64-1
ND
ug/L
10.0
1.8
1
01/12/2417:45
107-13-1
ND
ug/L
1.0
0.34
1
01/12/2417:45
71-43-2
ND
ug/L
1.0
0.47
1
01/12/2417:45
74-97-5
ND
ug/L
1.0
0.31
1
01/12/2417:45
75-27-4
ND
ug/L
1.0
0.34
1
01/12/2417:45
75-25-2
ND
ug/L
2.0
1.7
1
01/12/2417:45
74-83-9
ND
ug/L
5.0
4.0
1
01/12/2417:45
78-93-3
ND
ug/L
2.0
0.36
1
01/12/2417:45
75-15-0
ND
ug/L
1.0
0.33
1
01/12/2417:45
56-23-5
ND
ug/L
1.0
0.28
1
01/12/2417:45
108-90-7
ND
ug/L
1.0
0.65
1
01/12/2417:45
75-00-3
ND
ug/L
1.0
0.43
1
01/12/2417:45
67-66-3
ND
ug/L
1.0
0.54
1
01/12/2417:45
74-87-3
ND
ug/L
2.0
0.34
1
01/12/2417:45
96-12-8
ND
ug/L
1.0
0.36
1
01/12/2417:45
124-48-1
ND
ug/L
1.0
0.27
1
01/12/2417:45
106-93-4
ND
ug/L
1.0
0.39
1
01/12/2417:45
74-95-3
ND
ug/L
1.0
0.34
1
01/12/2417:45
95-50-1
ND
ug/L
1.0
0.33
1
01/12/2417:45
106-46-7
ND
ug/L
1.0
0.37
1
01/12/2417:45
75-34-3
ND
ug/L
1.0
0.32
1
01/12/2417:45
107-06-2
ND
ug/L
1.0
0.35
1
01/12/2417:45
75-35-4
ND
ug/L
1.0
0.38
1
01/12/2417:45
156-59-2
ND
ug/L
1.0
0.40
1
01/12/2417:45
156-60-5
ND
ug/L
1.0
0.36
1
01/12/2417:45
78-87-5
ND
ug/L
1.0
0.36
1
01/12/2417:45
10061-01-5
ND
ug/L
1.0
0.36
1
01/12/2417:45
10061-02-6
ND
ug/L
1.0
0.30
1
01/12/2417:45
100-41-4
ND
ug/L
5.0
0.48
1
01/12/2417:45
591-78-6
ND
ug/L
20.0
9.7
1
01/12/2417:45
74-88-4
ND
ug/L
5.0
2.0
1
01/12/2417:45
75-09-2
ND
ug/L
5.0
2.7
1
01/12/2417:45
108-10-1
ND
ug/L
1.0
0.42
1
01/12/2417:45
1634-04-4
ND
ug/L
1.0
0.29
1
01/12/2417:45
100-42-5
ND
ug/L
1.0
0.31
1
01/12/2417:45
630-20-6
ND
ug/L
1.0
0.22
1
01/12/2417:45
79-34-5
ND
ug/L
1.0
0.29
1
01/12/2417:45
127-18-4
ND
ug/L
1.0
0.24
1
01/12/2417:45
108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
Page 36 of 51

ace
Pace Analytical Services, LLC
Padgifyhe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
Sample: MW-11BR
Lab ID:
92708030014
Collected:
01/10/24 12:05
Received: 01/11/24 14:00 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
01/12/24 17:45
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
01/12/24 17:45
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
01/12/24 17:45
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
01/12/24 17:45
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
01/12/24 17:45
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
01/12/24 17:45
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
01/12/24 17:45
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
01/12/24 17:45
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
100
%
70-130
1
01/12/24 17:45
460-00-4
1,2-Dichloroethane-d4 (S)
99
%
70-130
1
01/12/24 17:45
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
01/12/24 17:45
2037-26-5
Date: 01/22/2024 02:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 37 of 51

ace
Pace Analytical Services, LLC
Padg"rwyhe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
QC Batch: 2209918 Analysis Method: EPA 8260D by SIM
QC Batch Method: 8260B-SIM Analysis Description: VOA (GC/MS) 8260D-SIM
Laboratory: Pace National - Mt. Juliet
Associated Lab Samples: 92708030001, 92708030002, 92708030003, 92708030004, 92708030005, 92708030006, 92708030007,
92708030008,92708030009,92708030010,92708030011,92708030012,92708030013,92708030014
METHOD BLANK: R4024857-3 Matrix: Water
Associated Lab Samples: 92708030001, 92708030002, 92708030003, 92708030004, 92708030005, 92708030006, 92708030007,
92708030008,92708030009,92708030010,92708030011,92708030012,92708030013,92708030014
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane) ug/L ND 3.00 0.597 01/20/24 11:40
Toluene-d8 (S) % 96.8 77.0-127 01/20/24 11:40
LABORATORY CONTROL SAMPLE & LCSD: R4024857-1
R4024857-2
Spike
LCS LCSD
LCS
LCSD
% Rec Max
Parameter Units Conc.
Result Result
% Rec
% Rec
Limits RPD RPD Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 50.0
47.4 40.3
94.8
80.6
55.0-138 16.2 24
Toluene-d8 (S) %
96.7
96.8
77.0-127
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /22/2024 02:20 PM without the written consent of Pace Analytical Services, LLC.
Page 38 of 51

ace
Pace Analytical Services, LLC
Pad9oplarwyhe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
QC Batch: 824993 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92708030001, 92708030002, 92708030003, 92708030004, 92708030005, 92708030006, 92708030007,
92708030008,92708030009,92708030010,92708030011,92708030012,92708030013,92708030014
METHOD BLANK: 4267320 Matrix: Water
Associated Lab Samples: 92708030001, 92708030002, 92708030003, 92708030004, 92708030005, 92708030006, 92708030007,
92708030008,92708030009,92708030010,92708030011,92708030012,92708030013,92708030014
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
01/12/24 13:29
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
01/12/24 13:29
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
01/12/24 13:29
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
01/12/24 13:29
1,1-Dichloroethane
ug/L
ND
1.0
0.37
01/12/24 13:29
1,1-Dichloroethene
ug/L
ND
1.0
0.35
01/12/24 13:29
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
01/12/24 13:29
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
01/12/24 13:29
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
01/12/24 13:29
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
01/12/24 13:29
1,2-Dichloroethane
ug/L
ND
1.0
0.32
01/12/24 13:29
1,2-Dichloropropane
ug/L
ND
1.0
0.36
01/12/24 13:29
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
01/12/24 13:29
2-Butanone (MEK)
ug/L
ND
5.0
4.0
01/12/24 13:29
2-Hexanone
ug/L
ND
5.0
0.48
01/12/24 13:29
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
01/12/24 13:29
Acetone
ug/L
ND
25.0
5.1
01/12/24 13:29
Acrylonitrile
ug/L
ND
10.0
1.8
01/12/24 13:29
Benzene
ug/L
ND
1.0
0.34
01/12/24 13:29
Bromochloromethane
ug/L
ND
1.0
0.47
01/12/24 13:29
Bromodichloromethane
ug/L
ND
1.0
0.31
01/12/24 13:29
Bromoform
ug/L
ND
1.0
0.34
01/12/24 13:29
Bromomethane
ug/L
ND
2.0
1.7
01/12/24 13:29
Carbon disulfide
ug/L
ND
2.0
0.36
01/12/24 13:29
Carbon tetrachloride
ug/L
ND
1.0
0.33
01/12/24 13:29
Chlorobenzene
ug/L
ND
1.0
0.28
01/12/24 13:29
Chloroethane
ug/L
ND
1.0
0.65
01/12/24 13:29
Chloroform
ug/L
ND
1.0
0.43
01/12/24 13:29
Chloromethane
ug/L
ND
1.0
0.54
01/12/24 13:29
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
01/12/24 13:29
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
01/12/24 13:29
Dibromochloromethane
ug/L
ND
1.0
0.36
01/12/24 13:29
Dibromomethane
ug/L
ND
1.0
0.39
01/12/24 13:29
Ethylbenzene
ug/L
ND
1.0
0.30
01/12/24 13:29
lodomethane
ug/L
ND
20.0
9.7
01/12/24 13:29
Methyl-tert-butyl ether
ug/L
ND
1.0
0.42
01/12/24 13:29
Methylene Chloride
ug/L
ND
5.0
2.0
01/12/24 13:29
Styrene
ug/L
ND
1.0
0.29
01/12/24 13:29
Tetrachloroethene
ug/L
ND
1.0
0.29
01/12/24 13:29
v2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /22/2024 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 39 of 51

ace
Pace Analytical Services, LLC
Padg"Iirpyhe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
METHOD BLANK: 4267320 Matrix: Water
Associated Lab Samples: 92708030001, 92708030002, 92708030003, 92708030004, 92708030005, 92708030006, 92708030007,
92708030008,92708030009,92708030010,92708030011,92708030012,92708030013,92708030014
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Toluene
ug/L
ND
1.0
0.24
01/12/24 13:29
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
01/12/24 13:29
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
01/12/24 13:29
Trichloroethene
ug/L
ND
1.0
0.38
01/12/24 13:29
Trichlorofluoromethane
ug/L
ND
1.0
0.30
01/12/24 13:29
Vinyl acetate
ug/L
ND
2.0
1.3
01/12/24 13:29
Vinyl chloride
ug/L
ND
1.0
0.39
01/12/24 13:29
Xylene (Total)
ug/L
ND
1.0
0.34
01/12/24 13:29
1,2-Dichloroethane-d4 (S)
%
98
70-130
01/12/24 13:29
4-Bromofluorobenzene (S)
%
99
70-130
01/12/24 13:29
Toluene-d8 (S)
%
99
70-130
01/12/24 13:29
LABORATORY CONTROL SAMPLE:
Parameter
4267321
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
20
19.9
100
70-130
1,1,1-Trichloroethane
ug/L
20
19.5
98
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
21.7
109
70-130
1,1,2-Trichloroethane
ug/L
20
20.4
102
70-130
1,1-Dichloroethane
ug/L
20
19.7
98
70-130
1,1-Dichloroethene
ug/L
20
19.9
100
69-131
1,2,3-Trichloropropane
ug/L
20
20.4
102
70-130
1,2-Dibromo-3-chloropropane
ug/L
20
20.6
103
70-130
1,2-Dibromoethane (EDB)
ug/L
20
20.4
102
70-130
1,2-Dichlorobenzene
ug/L
20
19.8
99
70-130
1,2-Dichloroethane
ug/L
20
20.0
100
70-130
1,2-Dichloropropane
ug/L
20
21.4
107
70-130
1,4-Dichlorobenzene
ug/L
20
19.8
99
70-130
2-Butanone (MEK)
ug/L
40
42.7
107
67-133
2-Hexanone
ug/L
40
45.2
113
70-133
4-Methyl-2-pentanone (MIBK)
ug/L
40
41.7
104
70-130
Acetone
ug/L
40
37.7
94
67-130
Acrylonitrile
ug/L
100
111
111
70-130
Benzene
ug/L
20
20.6
103
70-130
Bromochloromethane
ug/L
20
20.7
103
70-130
Bromodichloromethane
ug/L
20
19.1
95
70-130
Bromoform
ug/L
20
19.5
98
70-133
Bromomethane
ug/L
20
14.2
71
41-148 v3
Carbon disulfide
ug/L
20
19.7
99
70-131
Carbon tetrachloride
ug/L
20
18.9
94
70-130
Chlorobenzene
ug/L
20
19.9
100
70-130
Chloroethane
ug/L
20
19.8
99
41-157
Chloroform
ug/L
20
19.9
99
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /22/2024 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 51

Pace Analytical Services, LLC
/'� Padgifyhe. Suite 100
ace-
e - Huntersville, NC 28078
.+f LJ [phone]
QUALITY CONTROL DATA
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
LABORATORY CONTROL SAMPLE:
Parameter
4267321
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Chloromethane
ug/L
20
21.3
107
59-141
cis-1,2-Dichloroethene
ug/L
20
21.1
105
70-130
cis-1,3-Dichloropropene
ug/L
20
20.8
104
70-130
Dibromochloromethane
ug/L
20
19.6
98
70-130
Dibromomethane
ug/L
20
19.1
95
70-130
Ethylbenzene
ug/L
20
20.0
100
70-130
lodomethane
ug/L
40
34.8
87
57-140
Methyl-tert-butyl ether
ug/L
20
17.9
89
70-130
Methylene Chloride
ug/L
20
19.5
98
62-130
Styrene
ug/L
20
21.0
105
70-130
Tetrachloroethene
ug/L
20
18.6
93
70-130
Toluene
ug/L
20
19.6
98
70-130
trans-1,2-Dichloroethene
ug/L
20
19.9
100
70-130
trans- 1,3-Dichloropropene
ug/L
20
20.3
102
70-130
Trichloroethene
ug/L
20
19.2
96
70-130
Trichlorofluoromethane
ug/L
20
18.3
91
57-130
Vinyl acetate
ug/L
40
40.9
102
70-141
Vinyl chloride
ug/L
20
19.4
97
66-140
Xylene (Total)
ug/L
60
61.0
102
70-130
1,2-Dichloroethane-d4 (S)
%
101
70-130
4-Bromofluorobenzene (S)
%
102
70-130
Toluene-d8 (S)
%
100
70-130
MATRIX SPIKE SAMPLE:
Parameter
4267322
Units
92708030001
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
19.8
99
70-146
1,1,1-Trichloroethane
ug/L
ND
20
25.3
127
70-150
1,1,2,2-Tetrachloroethane
ug/L
ND
20
22.8
114
66-144
1,1,2-Trichloroethane
ug/L
ND
20
22.6
113
70-142
1,1-Dichloroethane
ug/L
ND
20
22.7
114
68-150
1,1-Dichloroethene
ug/L
ND
20
25.4
127
64-162
1,2,3-Trichloropropane
ug/L
ND
20
22.1
110
66-144
1,2-Dibromo-3-chloropropane
ug/L
ND
20
19.3
97
62-146
1,2-Dibromoethane (EDB)
ug/L
ND
20
23.0
115
70-143
1,2-Dichlorobenzene
ug/L
ND
20
23.1
115
70-142
1,2-Dichloroethane
ug/L
ND
20
22.9
114
68-145
1,2-Dichloropropane
ug/L
ND
20
24.0
120
70-144
1,4-Dichlorobenzene
ug/L
ND
20
23.9
119
70-140
2-Butanone (MEK)
ug/L
ND
40
43.8
109
57-156
2-Hexanone
ug/L
ND
40
45.0
113
62-153
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
43.4
109
65-144
Acetone
ug/L
ND
40
40.4
101
49-162
Acrylonitrile
ug/L
ND
100
111
111
59-155
Benzene
ug/L
ND
20
22.0
110
68-144
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /22/2024 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 51

ace
Pace Analytical Services, LLC
Padgifyhe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
MATRIX SPIKE SAMPLE:
4267322
92708030001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Bromochloromethane
ug/L
ND
20
24.2
121
70-148
Bromodichloromethane
ug/L
ND
20
22.2
111
70-141
Bromoform
ug/L
ND
20
20.1
101
59-1441K
Bromomethane
ug/L
ND
20
18.4
92
23-190
Carbon disulfide
ug/L
ND
20
21.7
108
64-160
Carbon tetrachloride
ug/L
ND
20
24.4
122
70-147
Chlorobenzene
ug/L
ND
20
22.7
114
70-143
Chloroethane
ug/L
ND
20
26.7
134
55-190
Chloroform
ug/L
ND
20
20.4
102
67-148
Chloromethane
ug/L
ND
20
25.5
128
38-180
cis-1,2-Dichloroethene
ug/L
ND
20
23.2
116
67-151
cis-1,3-Dichloropropene
ug/L
ND
20
19.9
100
70-142 IK
Dibromochloromethane
ug/L
ND
20
19.0
95
68-140
Dibromomethane
ug/L
ND
20
21.3
107
70-142
Ethylbenzene
ug/L
ND
20
22.9
115
70-145
Iodomethane
ug/L
ND
40
42.4
106
37-160 v3
Methyl-tert-butyl ether
ug/L
ND
20
21.9
109
64-146
Methylene Chloride
ug/L
ND
20
20.7
103
54-149
Styrene
ug/L
ND
20
22.7
114
70-147
Tetrachloroethene
ug/L
ND
20
23.9
119
70-145
Toluene
ug/L
ND
20
22.9
115
65-146
trans-1,2-Dichloroethene
ug/L
ND
20
24.5
122
69-155
trans- 1,3-Dichloropropene
ug/L
ND
20
19.4
97
70-142 IK
Trichloroethene
ug/L
ND
20
24.9
125
70-152
Trichlorofluoromethane
ug/L
ND
20
24.7
123
60-158
Vinyl acetate
ug/L
ND
40
36.0
90
56-157 IK
Vinyl chloride
ug/L
ND
20
22.9
114
51-178
Xylene (Total)
ug/L
ND
60
69.6
116
70-146
1,2-Dichloroethane-d4 (S)
%
102
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8 (S)
%
100
70-130
SAMPLE DUPLICATE: 4267323
Parameter
Units
92708030002
Result
Dup
Result RPD
Max
RPD Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,1-Trichloroethane
ug/L
ND
ND
30
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,2-Trichloroethane
ug/L
ND
ND
30
1,1-Dichloroethane
ug/L
0.38J
0.45J
30
1,1-Dichloroethene
ug/L
ND
ND
30
1,2,3-Trichloropropane
ug/L
ND
ND
30
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
30
1,2-Dibromoethane (EDB)
ug/L
ND
ND
30
1,2-Dichlorobenzene
ug/L
ND
ND
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /22/2024 02:20 PM without the written consent of Pace Analytical Services, LLC.
Page 42 of 51

ace
Pace Analytical Services, LLC
Pa88Qtir6fyhe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
SAMPLE DUPLICATE: 4267323
Parameter
Units
92708030002
Result
Dup
Result
Max
RPD RPD
1,2-Dichloroethane
ug/L
ND
ND
30
1,2-Dichloropropane
ug/L
ND
ND
30
1,4-Dichlorobenzene
ug/L
ND
ND
30
2-Butanone (MEK)
ug/L
ND
ND
30
2-Hexanone
ug/L
ND
ND
30
4-Methyl-2-pentanone (MIBK)
ug/L
ND
ND
30
Acetone
ug/L
ND
ND
30
Acrylonitrile
ug/L
ND
ND
30
Benzene
ug/L
0.53J
0.511
30
Bromochloromethane
ug/L
ND
ND
30
Bromodichloromethane
ug/L
ND
ND
30
Bromoform
ug/L
ND
ND
301K
Bromomethane
ug/L
ND
ND
30
Carbon disulfide
ug/L
ND
ND
30
Carbon tetrachloride
ug/L
ND
ND
30
Chlorobenzene
ug/L
ND
ND
30
Chloroethane
ug/L
ND
ND
30
Chloroform
ug/L
ND
ND
30
Chloromethane
ug/L
ND
ND
30
cis-1,2-Dichloroethene
ug/L
5.2
5.4
3 30
cis-1,3-Dichloropropene
ug/L
ND
ND
301K
Dibromochloromethane
ug/L
ND
ND
30
Dibromomethane
ug/L
ND
ND
30
Ethylbenzene
ug/L
ND
ND
30
lodomethane
ug/L
ND
ND
30 v2
Methyl-tert-butyl ether
ug/L
ND
ND
30
Methylene Chloride
ug/L
6.1
5.7
7 30
Styrene
ug/L
ND
ND
30
Tetrachloroethene
ug/L
0.511
0.62J
30
Toluene
ug/L
ND
ND
30
trans-1,2-Dichloroethene
ug/L
ND
ND
30
trans- 1,3-Dichloropropene
ug/L
ND
ND
301K
Trichloroethene
ug/L
1.5
1.5
4 30
Trichlorofluoromethane
ug/L
ND
0.31J
30
Vinyl acetate
ug/L
ND
ND
30 IK
Vinyl chloride
ug/L
ND
ND
30
Xylene (Total)
ug/L
4.8
5.3
11 30
1,2-Dichloroethane-d4 (S)
%
101
106
4-Bromofluorobenzene (S)
%
99
104
Toluene-d8 (S)
%
99
102
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /22/2024 02:20 PM without the written consent of Pace Analytical Services, LLC.
Page 43 of 51

ace
Pace Analytical Services, LLC
PaWiwyhe. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J23120380 MNS Landfill
Pace Project No.: 92708030
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /22/2024 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 51

ace
Pace Analytical Services, LLC
Padg iwyhe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
J23120380 MNS Landfill
Pace Project No.:
92708030
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92708030001
MW-3
8260D-SIM
2209918
EPA 8260D
by SIM
2209918
92708030002
MW-311)
8260D-SIM
2209918
EPA 8260D
by SIM
2209918
92708030003
MW-11
8260D-SIM
2209918
EPA 8260D
by SIM
2209918
92708030004
MW-11D
8260D-SIM
2209918
EPA 8260D
by SIM
2209918
92708030005
MW-12
8260D-SIM
2209918
EPA 8260D
by SIM
2209918
92708030006
MW-12D
8260D-SIM
2209918
EPA 8260D
by SIM
2209918
92708030007
MW-4R
8260D-SIM
2209918
EPA 8260D
by SIM
2209918
92708030008
MW-4DR
8260D-SIM
2209918
EPA 8260D
by SIM
2209918
92708030009
M NS_TB-20240110-0800
8260D-SIM
2209918
EPA 8260D
by SIM
2209918
92708030010
MNS_FB-20240110-1020
8260D-SIM
2209918
EPA 8260D
by SIM
2209918
92708030011
MNS_FD-20240110-1
8260D-SIM
2209918
EPA 8260D
by SIM
2209918
92708030012
MW-3BR
8260D-SIM
2209918
EPA 8260D
by SIM
2209918
92708030013
MW-4BRR
8260D-SIM
2209918
EPA 8260D
by SIM
2209918
92708030014
MW-11BR
8260D-SIM
2209918
EPA 8260D
by SIM
2209918
92708030001
MW-3
EPA 8260D
824993
92708030002
MW-311)
EPA 8260D
824993
92708030003
MW-11
EPA 8260D
824993
92708030004
MW-11D
EPA 8260D
824993
92708030005
MW-12
EPA 8260D
824993
92708030006
MW-12D
EPA 8260D
824993
92708030007
MW-4R
EPA 8260D
824993
92708030008
MW-4DR
EPA 8260D
824993
92708030009
MNS_TB-20240110-0800
EPA 8260D
824993
92708030010
MNS_FB-20240110-1020
EPA 8260D
824993
92708030011
M NS_FD-20240110-1
EPA 8260D
824993
92708030012
MW-3BR
EPA 8260D
824993
92708030013
MW-4BRR
EPA 8260D
824993
92708030014
MW-11BR
EPA 8260D
824993
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /22/2024 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 51

ace DC# Title: ENV-FRM-HUN1-0083 v03_Sample Condition Upon Receipt
Effective Date: 11/29/2023 4:16:30 PM
137 of 149
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville ®
Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersville❑
Client blame:
L�
r�Grf.c� G�tr
P roject#:
W0# . 7
92`®8030
Condition
Sample •�
p.
u
Ex
UPS
❑ commercial
Pace
El Other:
92708030II
Custody Seal Present?
WYes ❑ No Seals Intact? Yes
❑ No ❑ N/A
Date/Initials Person Examining Contents:AU f L+r�l-K
Packing Material:
❑ Bubble Wrap
Bubble Bags ❑ None
❑ Other Biological Tissue Frozen?
Thermometer:
❑ Yes ❑ No [ON/A
VIR Gun (D:
( 070
Type of ice: Wet El Blue ❑None
Correction Factor:
Cooler Temp: Add/Subtract (•C) r J• Temp should be above freezing to 6'C
} El Samples out of temp criteria. Samples on ice,cooling process
Cooler Temp Corrected (•C): !• Lr has begun
USDA Regulated Soil ( F N/A, water sample) `
Did samples originate in a quarantine zone within the United States: CA, NY, or SC Did samples originate from a foreign source (internationally,
lrhark mand? r7l Vac RNn including Hawaii and Puerto Mcol? ❑Yes 5ZNo
Comments/Discrepancy:
Chain of Custody Present?
Yes
❑ No
N/A
1.
Samples Arrived within Hold Time?
FkYes
❑ No
❑ N/A
2.
Short Hold Time Analysis (a7I hr.)?
❑ Yes
❑ No
9(N/A
3.
Rush Turn Around Time Requested?
❑ Yes
❑ No
0 NIA
4.
Sufficient Volume?
RlYes
❑ No
❑ N/A
5.
Correct Containers Used?
-Pace Containers Used?
®Yes
J4 Yes
❑No
❑ No
[I NIA
❑ N/A
6.
Containers Intact?
DYes
❑ No
❑ N/A
7.
Dissolved analysis: Samples Field Filtered?
El Yes
ID No
20N/A
$.
Sample Labels Match COC?
-includes Date/Time/ID/Analysis Matrix:
DYes
W
❑No
❑N/A
9.
Headspace in VOA Vials (>S-6mm)?
Yes
❑ No
❑ NIA
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
❑ Yes
❑ Yes
❑ No
© Na
QI N/A
LV NIA
11.
COMMENTS/SAMPLE DISCREPANCY
M AK- Iti W — tit
,Field Data Required? LJYes LJ No
�GGat � flcc �—
Lot ID of split containers-
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Project Manager SRF Review:
Date/Time:
Date:
Date:
Qualtrax ID: 69614 Page 1 of 2 Page 46 of 51

'f ULJU
Effective Dale: 11/14/2022 P4ige 138 of 149
`Check mark top half of box if pH and/or dechiorination is verified and
within the acceptance range for preservation samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO18015 Iwaterj DOC, LLHg
"Bottom half of box is to list number of bottles
* "Check all unpreserved Nitrates for chlorine
Project 9 TWO# : 92708030
PM: LJP Due Date: 01/18/24
CLIENT: 92-Duke Ener
W
a
2
4
_
u
i
u
zi
,`v
U
"
N
U
z
M
V
y
\
3
\
z
I
1
dyy
z
w
iZ
v
O
U
di
z
z
N
7!
CE
c
a
V
^wJ
c
>
C!
N
c
>
1'
u K
4 t_J
n `^
c z
M
z
s
u
¢
y'
Q
z
ry
t7
p
d
a
V
n
_
S
a
c
4
O
r,
Y
n
x
`y
Z
U
r
z
z
_
U
�
.
14
1
n
_
•r
L
sr
?
?
.2
Z
a
z
N
=�
tu
A
IL
E
N
rt7
a
E
u7
rJ
'a
E
0
«•
�a
c
= 'r^,
n
E
o
a
E
N
a
E
°
E
m
E
Cc
m
=
E
4
m
—
¢
a
E
q
V7
s
Q
m
=
q
E
vqj
E
4
a
o
00
>
E
4
>
J
E
p
O
>
g
o
a
>
c
a
4
a
o
v
CL
io
.y
M
n
E
,n
rl
m
vt
E
o
r
a
c
0
N
¢
E
o
ri
vt
a
E
E
o
E
v
_
a.
m
M
a
m
N
a
m
Q
c. a
m m
r.f
a
m
t
a I
m
M.LL
a
cc
t9
_
l5
tM7
Q
H
l7
4
L7
4
tL
7
O
T
�
!^
>
V
>
}
0
,
n
o.
tc
to
?
to
a
Zn
n
a
n
M
4
m
L5
2
lj
ut
}
L2
6
5
i
�—
—
j
\
6
I
\
\
IN
\I
Nr
I
101ZL
pH Adjustment log for Preserved Samples
Sample ID
Type of Preservative i pH upon receipt
i
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative T Lot #
added
rote Irrnenev,er inere Is a m5crepancy anecting;'+artn Lamina tompttance satnp!es. a copy at tits torm wu tic sent to, the Narth Carolina DENR Certllicatton Office (t s
Out of hold, incorrect preserv2tive, out el temp,:ntoriLCt Containers.
Qualtrax 10. 69614
Page 2 of 2
Page 47 of 51

Z%Ce.', � DC# Title: ENV FRM-HUN1-0083 02 Sample Condition Upon Receipt
139 of 149
Effective Date: 11/14/2022
*Check mark top half of box if pH and/or dechlorination is verified and
within the acceptance range for preservation samples.
Exceptions: VOA, Collform, TOC, Oil and Grease, iDRO/6015 (waterl DOC, LLHg
"Bottom half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine
Project
V
Z
a�i
Z
v
Z
9a,
v
_
V
rV
v
'v
y
O
Z
°if
w
n
a
=
W
v
U
�a
�'
v
v
z
z
J
=
2
it
Z
A
z
rn
O
U
?
v
Q
ro
Z
w
c
m
c
m
c
n
N
2
M
Z
u
a
a
N
s
Z
t7
a
a
�'
a
7
a
v
O
S
O
ry
x
a
Z
d
2
Vfac
a
rn
N
y
n
2
7
m
�,
0.
?
Y
u
a
w
2
v
M
c
O
y
M
a
N-1
a
foLn o
a
OVl
io
-ri
a
N
14
a
E
'n
N
a
a
°DC
E
a
rm♦
E
Q
r°-,
¢
.J
of�
E
Q
`
--d
¢
J
o
0
N
E
a
0
V
O
7
Q
1K
p
7
p
O
?
0
O�?y
0
>
O
ro
0.
p
M
roE
}'n
::
N
-
°
LA
E
O
N
°
C"
N
¢
J
o
O
VE
rE
0
E
¢
E
O
E
W
V
Co
m
m
rV
aft
N
ID
V
Go
M
m
%r
m
q
an
H
a
r!
a
M
to
a
r4
Q.)Q
a
M
d
M
V
a
Ch
Q
t7
M
Q
>
M
Q
7
m
0
d
r,
n.
Y
Y
t7
\
a
i-
ut
a
4n
N
ry
a
VI
OL
M
a
mE
0N
al
t.7
O
F
`
I/d
5
(i
\
7
8
\
9
10
\
it
12
-J\N1
pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot g
Note: whenever there is a discrepancy affecting North Carolina cumpliance salnples, a copy cf this form will be sent to the North Carolina DEN Ceftifitation Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 48 of 51
Qualtrax ID: 69614 Page 2 of 2

�! DUKE
'
Duke Energy Analytical Laboratory
Mall Code MG03a2 (auedlna 7401) I
'4 ENERGY
13334 Np+aFu 280 ;
HunlehlYah, N. G. ir07. i
p041 F73-5745 j
F. t754t 1754039 i
Project Name MNS LANDFILL 41 Permit #60.04
P6' . N.=
Client Ethan Smith I Bryan Moeller /
Courtney Murphy I Ashley Heal
Operating Unit: 20036 Process: BIDFLGN
Account;
Project; Activity ID:
Facility ID:
Mcoa
Program I EQuIS Task Coda:
Su"rogrsmrTaak Code:
i •• SAMPLE to i
i NUMBER i
2023031274
2023031275
202303127fi I.
1 2023031277
i 2023031278 F
i 2023031279
2023031280
2023031281
? 2023031282 •.
2023031283
2023031284
2023031 5
i 2023r 031288
j 2023031287
2023031288
Sample Description or ID
MNSMW-2A
MNS MW-2D
CHAIN OF CUSTODY RECORD AND ANALYSIS_ REQUEST FORM
- ----'-'-•-------'-
-•----•---•-'- -•--- '-•-•------Anal
-- -
•-- -
lcalLaboralo Use Only
J23120380
MatrixLa WATER
Srnplen e�lglnndnp
room
NC_
tr#
SC_
rd By
00t.1,Tlm
t 1 ,1 bl-!�5
SAMPLE PROGRAM
Ground Water
�)�,
NPOES_
""-""-'
�'�
Drinking Water_
UST_
PACE
RCIiA waste
PO
It ail v
M "24818
! Filtration (0.45 um)
b
Unfiltered
Preservative
ICE
ICE
Container Volume (mL)
r r
500
Soo
Container Type
v
Custom
Customer to carnp7ety al! Appropriate
arena.
w
vi
X U
W
Z.
Jl
O
Collection lnfonnstion
YI
Date
Time Printed Name
0e
Signature o
-
4 U
Q tnVin
U
x
3
1
3
1
x
3
i
3
1
x
3
1
3
1
x
3
1
3
1
�() Z
Soo
x
3
1
3
1
k
0
535
x
3
1
3
1
x
3
1
3
1
X
3
1
3
1
Page 140 of 149
Page -1 of 3_ o
DISTRIBUTION O)
ORIGINAL to LAB. COPY to CLIENT
N
Updated: e113123 li
{F Filtered
mm
ff
�==
ME
WMEW
*awl
0 �
I�.-.��
MI.I
n
I i i i I TOTAL#CONTAINERS I i i 45 1 15 1 0 1 45 i 11 i 4 i 0 10 I 0 I 0 i 0 i 1 i 121
Rell is tl y Dalernme
Accepted By,
DatelTime
w
/� )
o's (.1J1
/0 2 o
v
L
n
Requested Turnaround
21 Days
allnquished BDate/Time
/
Accepted By: Oat Rl a
Pfl
a�
14 Days
Rellnqul ad B D temina
Accepted By;
m v
o v
°�
5 atelTime
SealedlLock Opened By Dale Imo
Ix
-m
7 Qays
E
_ y
v
`m
Comments
o
'Olher
w
' Add. Cost Will Appiy
U

Duke Energy Analytical Laboratory
DUKE
ENERGY
Mall Cod. NGm247 (euUft 7406) r
14f3%nw.r. Fury Rd
Nu..r.tlee• N. C. ware
pwl a7532r6
1._._._._._._._.—._._._._._._._._._
............ F..;. LTe.t eral.ae _—_—•_._....J
Project Name MINIS LANDFILL #1 Permil N6D,04 Phoe. N.:
Client Ethan Smith I Bryan Moeller I
Courtne V Murphy I Ashley Heal
Operating Unit: 20036 Process: BLDFLGN Account:
Project: Activity ID: Facility ID:
=0_
Program! EQuiS Task Code: Sub-rograndTask Code:
_ _ Sample Description or ID
SAMPLEID
NUMBER
2023af MNS_TB • 20ZL f0t o ga a
2023034296 MNS_TR
2023031297 •. MNS_TB
2023031298 ! MNS_TB
2023031299 ! MNS_FB
2023031300 i MNS_FB
2023031301 MNS_FB _ ZOitt0 J,0 _JOLO
2023031302 MNS_FB
2023031303 i JMNS_FD_7d)4(IIIl)
CHAIN OF CUSTODY RECORD AND_A_NA_LYS_IS__ REQUEST FORM
._._._._._._._._. -.-._._._._._._._._._._.-._._._._._........_._._._._._.Anal Analytical Laboratory Use Only._.-.-.-.-._._._._._._._._._._._._._._._._._._._._._._._._._._._._..
Order# J23120380 Matrix WATER s.ma..wo� "r� sc_
it'O9ead By i C ..n a Tira � SAMPLE PROGRAM
1 I t 7_" 0.1 Ground Waler_X_ NPDES
i
:Vaedor: Pao. �' -
i Drinking Water _ UST
PACECedlef T.mp1CF_..__._. RCRA Waste
i
I PO 10624878
; Filtration (0.46 um) {} Unfiltered
i Preservative ICE ICE
...........
- -- - ---'._.... Container Volume ImLI • r r { • r 300 300
Container Type
Customer to complete off appropriate non -shaded areas.
Collection Information
Date Time Printed Name Sia
Oa)t�ofrime Accepted
/ ! { Y'd zy r'63s v
By DatelTim Accepted
talrime� Atceptad
By
TOTAL 0 CONTAINERS
``''jj
Page 141 of 149
Page _2_ of _3_ O
DISTRIBUTION CD
ORIGINAL to LAB, COPY to CLIFF
tea' .
b Filtered
al x W 9
U
bum
r�•oq
C
NCOy
xto�
ems
a43a^N
Oita
•
Omit u
3U dv `�"�
� � ��
•
7 C1
Toe-0 C�ci
rN�U1
x 3
3
NIA
6
X 3
3
NIA
6
X 3
3
NIA
6
x 3
3
NIA
6
X 3
1
3
1
NIA
8
X 3
1
3
1
NIA
e
X 3
i
3
1
NIA
8
X 3
1
3
1
NIA
8
X 3
i
3
1
NIA
8
X 3
i
3
1
NIA
8
0
0
0
0
0
0
0
0
30
6 0
30
0
6
0
0
0
0
0
0
0
72
latelTlme
faterTime
11,24
to lme
rl t �� J6
y
5
n o
�y
R
X a
CL
_ m
u
U
Requested Tumaround
21 Days
14 Days
7 Days
'Other
Add- Cost Will Apply
Total E7-
I.I. ime

CHAIN OF CUSTODY RECORD AND ANALYSIS RI
'DUKE Duke Energy Analytical Laboratory i i
1
/ MettCm.Moo,
4t 19-1ldlnar4eej I iordar# J23120380
ENERGY oaasaxa, N. C, yea ,
xnnla(7.1., N. C. zeole , , q� ay
pwlaT3-ez�e I I -T c
I._._.---------------------- ------ ------- -_._._._._.j
ProJect Name MNS LANDFILL #1 Permit il60-04 Ph —No: lu`^'"' 1+ar»
—
Client Ethan Smith! Bryan Moeller! PACE
Courtney Murphy t Ashley HealyPO 2g87p
€ Operating UnI 20036 Araces5:BLOFLGN Account: �! �O -
Project: Activity 1D: Facility 113:
Amgram l EOu1S Task Code: .111-1ramfTsak Dodo:
ial ical Laboratory Use On
Matrix WATER
. & Tlma
t 11 2K O�t35
0.5
....._.._ ._........ Cooler T�mP.
Filtration (0.45 um)
Preservative
Container Volume (mLj
Container Type
Sample Description or ID I
Customar ro complote all appropriate non -shaded areas
Collection Information
Data I Ti7m-T Printed Name Sig
l-36R i 1 ro/24' 1� 71 1 OS1 h l k wp
18R
TOTAL 0 CONTAINERS
me n
DatefTlme Accepted By:
Daternme Accepted By:
t Data me Sealedfl-ack Opened By
■SAMPLE
PROGRAM
NPIJES rLIST
all
., ICE HNO3 HCL, ICE
®®.
10 500 40
Ly
�mI
u tl
CD
X 1003
NMI
IVO
©�■©oar
©aa©�
18 6 0
DatelTime
1Ila1Zri i�-35'
DatefTlme
Ili �z�
Illy//7 lac;
27
16
6
I 27
0
F
.e
� C
d �
a2
mJ.
q
0
a
a�
E
0
U
Page 142 of 149
Page _3_ of _3_ o
DISTRIBUTION
ORIGINAL la LAU, COPY to CLIEI,t
sT
Updatad:6113123 d.
i� Filtered
D
27
0
0
0
D
0
0
0
0
0
e
0
0
D
75
Total F75
Requested Turnaround
21 Days
14 Days
'7 Days
"Other
Add. Cost Wilt Apply

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
Duke Energy AnatyUcal ui ratary j
------------
- --------------------------------------------------
An. ical Labo�Qto u- O� -----
---------
- --- - --- -
- -
i
Page 143 of 149
.('DUKE wacna.w3osu iav"meel E
J2312038U
Matrix WATER
NC
Page _1—of 3_
ENERGY. t771eHpw.NryRd I;arderr
HW.rrrWr. k. C. zwTa
sC_
DISTRIBUTION
IFNI e7a3Nf f iLMbft
ar
SAMPLE PRODRAM
!
ORIGINAL to LAB. COPY to CLIENT
I._._._._._._._.—_._._._._._...._.-.._-_-_-_.--F"=:-L?-k�7a.eoaa-----------•�'
Vwdw:
Ground Walsr
x_
NPDE8_
Peee
Project Name MNS LANDFILL 41 Permit 060.04
Client Ethan Smith I Bryan Moallerl t PACE
+ C
L3
.._._.._. _ ._. _.._S�1sr.Ie!nr.L41_.._.._.
Dnnking Waler UST
RCRA Waste
.._.-_.._.._.._.._.-_.-_--__._-____-_--_--�-_._._.._..�.._
Cou Murph 1 Ashle Healy
Aeceont:
w
P�
Ay
10624878
Filtration i11.4a uml
4Unuttered
b Filtered
Operating Unit: 200M Process: E LDFL43N
I---.-_.._-._------------
Preservative
I
Icfi
Icfi
Project: Aclivity 101 Faallhy, 10:
Container Volume {mL}
r
Soo
Soo
Program! la jS Task Cade: Sub-Progremrrask Cade:
Container Type
C
Cusromer IO te+llllQrP aii dpp+dpfiaf0 r10+1•Sr1AL7dtI
d+PAS 4 to �
%
LLI�
�
a
Sample Description or ID
4 ^
v
,I
SAMPLE 10^-- i
Collection Intgrmatlon
a s
E a
-
I [.r
:5
2 a
3
a
i NUMBER i
Bah
Time Printed Name
SV a re $ u
a i]
-Ce-
2023031274; MNS_MW-1
432-0 Gel
ft*+1,\
x
3
1
3
7
LYa
2023031275
MNs_Mw-10
1
BOO
l
x
3
3
1
a
2023031276
MNS MW-2A
f
c4-k
x
3
1
3
7�y
S
': 2023031277 ':
MNS_MW-2D
pqqo
x
3
1
3
1
y�
a
2023031273
MNS_MW-3
x
3
1
3
1
a
2023031279 i
MNS_MW-3D
x
3
1
3
1
8
2023031280 i
MNS_MW4
INN
050
Jok
„ram
x
3
1
3
1
s
2023031281
MNS_MW41)
040
x
3
1
3.
1
8
1 2023031282 ?
� I
MNS_MW-11
x
3
1
3
1
8
2023031283 `
bANS_MW-11❑
x
3
1
3
1
8
2023031284 i
MNS MW-12
x
3
1
3
1
a
i 2023031285 !
MNS_MW-12D
x
3
1
3
1
8
i 2023 6
MNS_SW-1
,
160
x
3
1
3
1
1
B
2023031287
MNS MW4R
%
3
1
3
1
8
1 20230312881
MNS_MW4DR
x
3
1
3
1
8
i i
a
i
ii
0
I i
I
P41
O
I I
TOTAL a CONTAINERS
45
15 0
45
11
O
1 G
I 0
0
0
1
121
Rell wished By
__-'_•••_' -_ -• •• _ _--_ ^_ DetalTime
�11 � _%� �,y,•,�
/(//0���
V
Awpwd By
' •fJ
1}atelTime
y
o
E
n
Requested Tumeround
21 Days
Y
Relinquished By �•+DaboMme
Accepted By:
c �
a
C
14 Days
Relinquished DrWTkm
Accepted By: Datarrime
c 3
0 m
SeaULockrd By DabrTlrcie
SuledlLock Opened By DatefTlrne
"7 Days
F n
— m
-
m
Comments
c
'Other
• Add- Cost Will Apply
O
Tatal 7 27

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
V Duke Emrey Ann lylfcal iabcramry ._
_._._____._._.........._._.------- .----------------- ._._._._.
_._-..____- Analytical l,abnrata- Use On _._._._.
_._._._. _. _._._. ......._
i Page 144 of 149
❑���
N.II IV rscasu F."Rd vans
Ia�ae Mn— r.Rr ae
' Order # J2312038U
Matrix WATER
—
f;,�„aiµ,wiry 8C
age
POISTRIBLIT10N
ENERGY.
1lunw..wr, H,c. zlo�r
i
i Ii�.day
Imp
! q#tIGINAi to LAB. COPY to CLIENT
txe41 Vs3t4x
!
J
SANPIE PROGRAM
1
nlaosx _ _ _ _,_,
�,�1
Ground Walerx NPOFS�
niecl Name INNS LAN QFJLL #1 Permit H60-04
Phc"•+'O=
PACE
1 C
Y
t)rinkirlg Water UST
RCRA Waste
.._.._.._.._
C
._.._..__.�L �. r.�nr.i�1_.._.._.
_.._.._.._.._.._.._.--.---.---...._.._.._.._
Client Ethan Smith 1 Bryan Meeiierl pp 4�� 4818
Cnurtnev Murohv IAshlev Healy i Filtration [0.45 um] a Unfiltered {1 F3ttered
): IFacilRy 10i
MCoo
Sub-PmgramITesk Codr.
Preservative ICE ICE
Container Volume imL] Soo '"Container
Container Type
m°r
eco ewe_ m �
� 6 �a'q O � 6 d
um v 4Y� pia O $m
amb
�. ■
—_�
.©©�©m--■■_�m
BI1r.%I�fa
Bl�'iL:i::1Ja1R�
■
--
.©©�©�-
♦fMEMMEMIn
■.�..-�
!,
OUNIMEEZEIZE
—lu
_
.©©�
Vie
MOME
"T
MINE
IN
MEN
IMMENOMINEM0
E011111110101
s■mm��mmmom
Emma
�110101
■■M
IMMOM
INIMMIMMEo
MON11111101MEN
IMEMMINEEMENS
nom-�=
IMMEME1
n.
��
���-�MM�MEM
MIN
��
■■mom
mm
mommomo
MEN
mmm�mmsommomon
MON11111101
�.Y��©0000000�
/� customer zo si n a Dare omaw
� PatWT �
�!y
��rJfl I �l! � i�
T I
Accepted 9y: �Se�
a
N 1
RaquOsted Turnaround
21 Oays�
Total 73
IBy Oatd7lme
Pied BY: DatelTimwa
r
G
.. o. n
14 Days
gy
pcoepled BY: Oatemnw
c E
�
a r
a k
`7 days
By Da[aiT3me
Seeia&I-ock Opened By Datamine
E N
i U
a
c
'Other
mW -��� -t�� C 1a.25
• Add. Cost Will Apply
f7

........... _ _ _ CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
� Duke Energy Analytical La;i-w toryi j Analytical Lahoratory Use Cnly-•_._._._. ..- _._._. _._._._._._._._.�_---�.
UL1RC
!17rderk J231 380
M trix WATER
"°aiiO pj"rr°"
rye—
rayCPN�� �i tt 3_
ENERGY.. ,staexe.,.r.rrxa i
>snrr�wN, x. c. aw•ra ;'J'—w
SC,
a1STRIBUTION
Rr+I nsaxa i h
It Ti
SAMPLE PROGRAM
ORIGINAL to LAB. COPY to CWENT
;
F!�:S?;IEHO?i._ _ _ -_-„i
1
_ /
Ground Water_%_
NPDES
Prgled Name MNS LANDFILL 01 Pern* ON-04 view aw TACE
Dunking Water _
RCR A Waste
UST
_
Coof•r T_�l1.1_--_--_-
- - --.,_.._.._.._..-•
_
-__-__-_-__-__--__-__-_
Client Ethan Smith I Bryan Moeller 1
unfiltered
Flltamd
Courtney Murphy I Ashley Healy
10624819
; Filtration 10.45uraj
J3-
a
OperaOng Drdl: 20039 Precees: BLDFLGN AacauM:
Preservative
10E
ICE
Project. Activity In: Faepity ID: _.�...-� �. ��__� Gontairter Volume {mLj 300 300
mcoo
Program I EOulB Task Coda: Sub-Pmgran4Tesk Code:
Container Type
of
a
p
y
W
c
.�
Casr r ra conm7ete art eppMprin re nane0aded Ames.
Sample Description or I❑
-
; SAMPLE ID ;
Collection Infarmetion
i NUMBER i
Data Time Printed Name
allinatium a n
-
-
C
8
2023031295 ; MNS TB R 3 3 NIA
2023031296
MNS_TB
x
3
3
NIA
a
2023031297
MNS_TB-ZaZ40( 0 -oVbb
9 4
0%0
awl rrfF
x
3
3
NIA
6
2023031298 !
MNS TB
x
3
3
NIA
6
2023031299
AdNS_FB
x
3
1
3
1
NIA
a
i 2023031300 i
MNS_FB-2G7-4b10 _ilk
Q
ekVO �,K
x
3
1
a
t
N/A
a
i 2023031301 i
IvINs FB
x
3
1
3
1
WA
a
2023031302 ;
MNS_FB
x
3
1
3
1
WA
B
2023031303
MNS_FD
x
3
1
3
1
WA
e
2023031304 i
MNS FO.292!}Q D�� (
—
x
3
1
3
1
WA
B
i
0
i
0
i
o
� !
0
i
11
E !
O
i i
i
n
E i
TOTAL F CONTAINERS
30
B 0
30
a
B
0
1 0
1 0
0
0
0
a
B
7g
Re inquis d B
•-, - . V VY'-c.OalaRims
Acsepted By:
DalelThne
(016
f
/
.o
u
v
c
Requested Turnaround
Rellnquiehad By DOWTima
jvvpted By: DatafTima
_
9 a
m �
a o
2 ; Bays
J
14 Days
Ralinquistied By DawTbne
Accepted By: DatinTime
--
c a
j
SeallLocked By DatefTirne
Seeladkock Opened By Daum la
'7 Days
- a
- a
`m
Comments
c
'Other
' Add- Cost Will Apply
V
Total 72

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
Y Ouxe Ersorov JufalWcal L.noratary • i-'_._._._._._._._._._._._._._._._._._._._._._._._._._._._._._._—. Anal..... l.aharatory use t7nly -- -•-•- _.�_�...--.-.-.-.---__._-r_t- _-___-_--_-_-.- ____...I Page 146 Of 149
•,fts DUKE AUYC°deNtlu]Ad aRwn roost
order 0 J4312�3$Q
Matrix WATER
NC_
so
Page _1`of 3_
DiSTR18UTtCN
EIMERGY ,33]aHyv�—I". N.F7Rd
nvn c. nYra ; kLgpad �
owl a7642.6 F i
pay � TNa
$AMPLEr PRODRAM
!
ORIGINAL to LAB. CCPY to CLIENT
Fax: Iw a76d07a �'
1 ; t 7 A�
C,rovnd Wane
x
NPDES
Project: Mama MNS LANDFILL 07 Permit at>aD%iOA°a N0= "-'--^--•
i PA�iE
° � �
Drinlun Wale
_
Rcw, Waste_
MST
Client Ethan SmM 1 Bryan Moeller 1
Courtney Murphy 1 Ashley Hatx I PC
1062,1878
Filtration (0.45 um)
0
unfiltered
n Fikered
Op"ling Unit: 20036 Prooua: BLDFLGN Account: !
i_______
Preservative
ICE
10E
Project: Activity 10: Facility 10:
_________
__
Container Valume [mLI
r
Soo
Soo
Program + E4ui9 Task Code: Sup-AropramlTsak Cade:
Container Type
_
a:
j
Customer to Complete all appropriate rwn-srmdea amaa- a y "�
N
f
u. e,
LU
c
°
Sample Description or ID
-
p
SAMPLE 10 i
Collwgan Information
n
�
YlN
J
=
NUMBER Doh
t�
TLna
printed Name
Signature �
40
C
C
47 ....
2023031274 MNS_MW-1
x
3
1
3
1
8
2023031275 MNS_MW-1D
x
3
1
3
1
a
•. 2023031278 !.
MNS_MW-2A
x
3
1
3
1
8
! 2023031277 !
MNS_MW-2D
x
3
1
3
1
s
20M31278 !
MNS_MW-3
is
00
x
3
1
3
1
�'
8
2023031279 i
MNS MW-30
' Q
�5
5rn
c— _ --
x
3
1
3
1
8
i 2023 0
MNS_MW-4
x
3
1
3
1
a
2023031281
MNs_MW-4D
x
3
1
3
1
e
e 2023031282 i
MINIS MW-11
1 p
(to
x
3
1
3
1
a
2023031293 !
MNS MW-110
1 d ��
$
{��{
x
3
1
3
1
[3
2023031284 !
MNS_MW-12
(5
S
x
3
1
3
1
9
i 2023031 5 l
MNS_MW-120
3
x
3
1
3
1
e
20230312863
MNS_SW-1
x
3
1
3
1
1
9
20230�31287
MNS M!V4R
L Id
O
x
3
1
3
1
a
•
20231
MNS_MW4OR
�� ��
a5
x
3
1
a
1
s
�f
G
i i
43
D
i !
TOTAL 9 CONTAINERS
1a 0
45
1 11
4
0
0
L 0
0
0
1
121
usrnmvr v �tv ow
Ralf ■ d DatefTlme
Aceapted By:
��
DatelTme
}
2
Requested Turnaround
Total 121
4? 1&
Accepted By:
6� r
Bat
10
+��
a
c
21 Days
Ilrquished ay
Accepted 6yc
Dataffime
a
R
l ellnqu BDatill,1179114,
E
14 Days
A
r
o
SeallLookad By uaralTkne
SealadlLoak opened By QatalTlma
•7 Days
`
�
CommaMa
E
a
'Other
V
'Add COst WLII Apply

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
Duke Energy Analytical L&6mtmy
An I LaboratoryUse Onl
' Page d. 7 2f 14
P. f 3
• DUKE MWCaMMGWA2 i9a 7405} I
i IOrdera
J23120380
Matrix WATER
5an''"°"P""h0r'""
Nq—
sc
—
01STRIBUTI5NI
■,,,a,r,F
ENERGY nun,. rww, N. c. xwr■
pw1575.sx�5 I4a=
ay 1
�'.�I ■
O�Ni�
SAMPLE PROGRAM!
! ORIGINAL to LAB- COPY to CLIENT
,
'
-------------- '-'-'........... '-'--'----------F'-=-L7wtaysawe,_,_,_,_,__3
Project Nam■ MNS LANDFILL #1 Permit #6Q-04 % N. - ivn4or:'■a■
1
����
I It i Z+'V
0,
.......... ._.._.__coadr-It1ePL41_._.._.
Ground Walar
OtinWnglNaEsr
.._.._.._----- ._.._.._.._.._.._._..._..
W
NPUST
UST
OES
Dpdatod: W1 _
Client Ethan Smith I Bryan Moeller I !
Filtration;0.4jahw.
d
UnRitered
� Filtered
CauftnB Mu h 1Ash Hea
PO 110i24878
;
!
Operating Unit; 2a038 Proust: BLOFLGN Aoaourd:
�+
Presery
i
!cfl
ICE
Project: Activity ID: Facility W;
.,.,._,.,..r._.._.._
Container Volume
300
300
Program I E4ui5 Task Ccda_ Suh-ProgramfTask Code:
Container
ECustomer
ro complete aN approprlote noR hadad aSample
Description or IL1_op-
SAMPLE ID
Collection Information
J c7
sl
a.oNUMBER
~
{
Gala Th. Printed Nanw
tune c
4 V
4 N
0 Y
2023031 9 MNS TB * 2o1q o l i o- o So []
VICLi A I*
I %
3
3
NIA
s
2023031296 j
MNS TB
x
s
3
NA
6
is 2023031M is
MNS TB
x
3
3
WA
6
12023031298 !
MNS TB
x
3
3
WA
6
2023031299 !
NINS_FS
x
3
1
3
1
WA
e
2023031300 ;
MNS_FB
x
3
1
3
1
WA
a
i 2023 3130 0 ,li
MINIS 7-02, � � i(] O
1 Id
01 p
S� jt�
x
a
1
a
,
WA
e
2023031302 i
MNS_F8
x
3
1
3
1
NIA
A
2023031303
MNs_FD-2
>,
x
3
1
s
1
NIA
3
2023031304 !
MNS_I ❑
x
3
1
3
1
MIA
s
{
0
0
i
D
l i
a
i
0
TOTAL w CONTAINERS
i
70ta30
0
1 E
0
0
0
0
0
0
0
Tx
Rel uis d y ..._.._
��
.... _ �. D&W'nme
r
Acaaptad By:
Data me
m
Requested Turnaround
cjff9�.�r�
_ . , �� / a 35
�jry�,Jr y/
i ] I I O 1 ��
v
21 Days
elinqui5hed By DahfTi /
Accepted y: �tsrrme
mc
�
a
..
14 Days
flab Daternme
-
AauPled By: Datef imo
C E
a
n a
m
SeaULocksd By D&WrrbTta
SaaladlLoelt Opened By oataft'ima
a
E �
'7 Days
_ m
Comments
$
'Other
'Add Coat Will AWly
U
Total E

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
AneEvticsl Lab—t— Uae 6nW_._._._._._...-....-.._._____._. vi.. ._._._._._._._._._._._._.� Paae 148 of 149
DUKE x.kcaa.V-301: Wulkm"7"Sl Matrix WATER ,,,,a,„ !� NC_ ! Page _3Tof_3_
p,, , , !Ordare J23120380 °�°� ^� Sc_ i DISTRIBUTtON
ENERGY .-W u.. ILeeyedey p 4Thrna I ORIGINAL to LAB. COPY to CLIENT
iW 6]d•6213 SAMPLE PROGRAM
11
1 Z�'1 b'S3
Cx rid Water x NPDES
project Name MNS LANDFILL #1 permit #50.04 Pnene nv: ^'= ps'+s O •S Drinking Water UST_
PAVE Reeler 7mm C RCRA Waste_
..._.._.._.._ ._.._.._.._.._.._.. �C-1_.-_ _.._--_.._.__..__._..._.._..-..-.._.._.._.._.._.._.._.._.._.._._
Brya
Client Than by I A j ley H Moeller 1 PO106248718 Fillrrtian;0.45 um} is Unfiltered Filtered
Courtney Murphy 1 Ashley Healy P
Operating Unit: 20036 process: BLDFLGN Aeea nt: ! Praseivative ICE ICE
i
___________ ___ _ ___
pmjecs: AdjWityID, Facility: f e Contmine Volume(mL)I I 50o 500
MCGO
Program I Eauis Taek Coda; Sub-PmpremrTeek Ccda! Container Type
a
Y1• x to
Z
Cusft-w to ci mFklo a all appmpriafe nn hadedaroma LL =
M
[o!
_ Sampie description or I❑ —
SAMPLE 10 i Calfeaeart - Y c, 1 yp S d
a
r
NUMBER i Daps Time Printed Hareem Si as re u4 a ! U 49 L7
•3
r
E
2023031 9 MNS_MW-3BR ' �fl �,t} 530 Osk SH K 1 3 t
i 2023031290
MNS_MW43R
T
K
3
1
3
1
8
2023031291
MNS_MW4BRR
` +p
d
.y
K
3
7
3
s
12023031292 ;
MNS_MW-116R
I�
K
3
1
3
B
2023031293 ?
MNS-MW-13O
x
3
1
3
rl
8
i 2023031294 i
MNSjAVV-13i3R
X
3
1
3
8
I�
i I
0
f
0
' !
0
0
i
27
27
�—i
i i
i i
0
0
! !
0
�t
G
0
l
75
}
TOTAL a CONTAENERS
18
8 0
18
6
27
0
0
D
0
0
0
0
uslamar so 91 n aso no ow
Roll ad DatafTime
Accepted By: Datelrime
Requested Turnaround
Total 75
w is
21 Days
Relinq"hed OetelFime
Accap6®d 8y: 04ps1Tltrla
d�
a
p ufe1341amma
Accepped By: RahlTime
c
14 Days
m
c
Sea ULoeked By Date Time
Saetmdll-oak Opened By prielTlmrle
a.
7 Days
E n
- o
E 0
Other
gem r is TAlk — �i ��'� 'A
0
Add. Cost WilI Apply
V

Page 149 of 149
McGuire Landfill #1
COMPOUNDS REQUIRED FOR 8260 ANALYSES NC SWSL Std. Required MRL*
* MRL must meet or be
COMPOUND
CASSNo.
below the SWSL Std.
Acetone
67-64-1
100
Acrylonitrile
107-13-1
200
Benzene
71-43-2
1
Bromochleramethane
74-97-5
3
Bromodichloromethane
75-27-4
1
Bromotorm; Tribromomethane
75-25-2
3
Carbon disulfide
75-15-0
100
Carbon tetrachloride
56-23-5
1
Chlarobenzene
108-90-7
3
Chloroethane; Ethyl chloride
75-00-3
10
Chloroform; Trichloromethane
67-66-3
5
Dibromochlommethane; Chlorodibfomomethane
124-48-1
1
1,2-Dibromo-3-chiorpropane; DBCP
96-12-8
1
1,2-Dihromoethane; Ethylene dibromide; E06
106-93-4
1
o-Dichlorobenzene; 1,2-Dichlorobenzene
95-50-1
5
p-Dichlorobenzene; 1,4-Dichlorebenzene
106-46-7
1
trans-1 +0ichloro-2-butene
110-57-6
100
1,1-Dichloroethane; Ethyl idene chloride
75-34-3
5
1,2-Dichlorcethane; Ethyyene dichloride
107-06-2
1
1,1-Dichloroethylene; 1-1-Dichloroethene; Vinyl idene chloride
75-35-4
5
cis-12-Dichloroethylene; cis-1,2-Dichlaroethene
1 56-59-2
5
trans-1,2-Olchloroethylene; trans-1,2-Dichloroethene
156-60-5
5
1,2-1)ichlorpmpane; Propylene dichloride
78-87-5
1
cis-1,3-Dichlorpropene
1 0061-01 •
1
trans- 1,3-Dichlorpropene
1 0051-02•
1
Ethylbenzene
100-41-4
1
2-hexanone; Methyl butyl ketone
591-78-6
50
Methyl bromide; Bromomethane
74-83-9
10
Methyl chloride; Chloromethane
74-87-3
1
Methylene bromide Dibromomethane
74-95-3
10
Methylene chloride; Dichloromethane
75-09-2
1
Methyl ethyl ketone; MEK; 2-Butanone
78-93-3
100
Methyl iodide; lodomethane
74-88-4
10
4-Methyl-2-pentanone; Methyl isobutyl isobutyl ketone
108-10-1
100
Styrene
100-42-5
1
1, 1, 1,2-Tetrachlometh ane
630-2 0-6
5
1.1.2,2-Tetrachlareethane
79-34-5
1
Tetrachlemethylene; Tetracholorethene; Perchioroethylene
127-18-4
1
Toluene
108-88-3
1
1,1,1-Trochlorethane; Methylchloroform
71-55-6
1
1,1,2-Trichiamethane
79-00-5
5
Trichloroethylene; Thchicrethene
79-01-6
1
Trichlorefluoromethane; CFC-11
75-69-4
1
1,2,3-Trichloropropane
96-18-4
1
Vinyl acetate
108-05-4
50
Vinyl chloride
75-01-4
1
xylenes
1330-20-
4

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 602876
Location: MW-11BRML1
[ MNS Landfill 1 / MW-11BR (LANDFILL)]
Collection
Start: 1/10/2024
12:05:00
Job: MNSGW202348
Collection
End: 1/10/2024
12:05:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.67E-01
0.00E+00
4.67E-01
<3
LLD OK
Beta
3.47E+00
4.28E+00
3.21 E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<7.42E+00
0.00E+00
7.42E+00
<15
<1000
LLD OK
Co-58
<7.35E+00
0.00E+00
7.35E+00
<15
<1000
LLD OK
Fe-59
<1.40E+01
0.00E+00
1.40E+01
<30
<400
LLD OK
Co-60
<7.88E+00
0.00E+00
7.88E+00
<15
<300
LLD OK
Zn-65
<1.65E+01
0.00E+00
1.65E+01
<30
<300
LLD OK
Zr-95
<1.23E+01
0.00E+00
1.23E+01
<15
<400
LLD OK
Nb-95
<9.20E+00
0.00E+00
9.20E+00
<15
<400
LLD OK
1-131
<1.03E+01
0.00E+00
1.03E+01
<15
LLD OK
Cs-134
<8.30E+00
0.00E+00
8.30E+00
<15
<30
LLD OK
Cs-137
<6.92E+00
0.00E+00
6.92E+00
<18
<50
LLD OK
Bala-140
<6.76E+00
0.00E+00
6.76E+00
<15
<200
LLD OK
Be-7
<5.29E+01
0.00E+00
5.29E+01
K-40
1.77E+02
8.01 E+01
9.36E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<2.41 E+01
0.00E+00
1.92E+02
<250
<20000
LLD OK
Report Generated @ 2/15/2024 07:02:09 EnRad Laboratory Page 1 of 21
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 1 of 23 - 02/15/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 602877
Location: MW-11D_ML1
[ MNS Landfill
1 / MW-11D
(LANDFILL)]
Collection
Start: 1/10/2024
10:55:00
Job: MNSGW202348
Collection
End: 1/10/2024
10:55:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.65E-01
0.00E+00
4.65E-01
<3
LLD OK
Beta
<3.21 E+00
0.00E+00
3.21 E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.05E+00
0.00E+00
6.05E+00
<15
<1000
LLD OK
Co-58
<6.00E+00
0.00E+00
6.00E+00
<15
<1000
LLD OK
Fe-59
<1.21 E+01
0.00E+00
1.21E+01
<30
<400
LLD OK
Co-60
<7.89E+00
0.00E+00
7.89E+00
<15
<300
LLD OK
Zn-65
<1.21 E+01
0.00E+00
1.21 E+01
<30
<300
LLD OK
Zr-95
<1.29E+01
0.00E+00
1.29E+01
<15
<400
LLD OK
Nb-95
<6.52E+00
0.00E+00
6.52E+00
<15
<400
LLD OK
1-131
<9.07E+00
0.00E+00
9.07E+00
<15
LLD OK
Cs-134
<5.70E+00
0.00E+00
5.70E+00
<15
<30
LLD OK
Cs-137
<6.26E+00
0.00E+00
6.26E+00
<18
<50
LLD OK
Bala-140
<9.75E+00
0.00E+00
9.75E+00
<15
<200
LLD OK
Be-7
<4.42E+01
0.00E+00
4.42E+01
K-40
1.80E+02
7.48E+01
8.87E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<6.65E+01
0.00E+00
1.92E+02
<250
<20000
LLD OK
Report Generated @ 2/15/2024 07:02:09 EnRad Laboratory Page 2 of 21
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 2 of 23 - 02/15/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 602878
Location: MW-11_ML1
[MNS Landfill 1 / MW-11 (LANDFILL)]
Collection
Start: 1/10/2024
11:20:00
Job: MNSGW202348
Collection
End: 1/10/2024
11:20:00
GW Ground
Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.64E-01
0.00E+00
4.64E-01
<3
LLD OK
Beta
<3.21 E+00
0.00E+00
3.21 E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.27E+00
0.00E+00
6.27E+00
<15
<1000
LLD OK
Co-58
<6.67E+00
0.00E+00
6.67E+00
<15
<1000
LLD OK
Fe-59
<1.38E+01
0.00E+00
1.38E+01
<30
<400
LLD OK
Co-60
<7.48E+00
0.00E+00
7.48E+00
<15
<300
LLD OK
Zn-65
<1.33E+01
0.00E+00
1.33E+01
<30
<300
LLD OK
Zr-95
<1.27E+01
0.00E+00
1.27E+01
<15
<400
LLD OK
Nb-95
<6.97E+00
0.00E+00
6.97E+00
<15
<400
LLD OK
1-131
<9.63E+00
0.00E+00
9.63E+00
<15
LLD OK
Cs-134
<6.75E+00
0.00E+00
6.75E+00
<15
<30
LLD OK
Cs-137
<6.88E+00
0.00E+00
6.88E+00
<18
<50
LLD OK
Bala-140
<1.17E+01
0.00E+00
1.17E+01
<15
<200
LLD OK
Be-7
<4.99E+01
0.00E+00
4.99E+01
K-40
1.74E+02
8.45E+01
1.12E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<1.60E+01
0.00E+00
1.92E+02
<250
<20000
LLD OK
Report Generated @ 2/15/2024 07:02:09 EnRad Laboratory Page 3 of 21
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 3 of 23 - 02/15/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 602879
Location: MW-12D_ML1
[ MNS Landfill
1 / MW-12D (LANDFILL)]
Collection
Start: 1/10/2024
13:40:00
Job: MNSGW202348
Collection
End: 1/10/2024
13:40:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.65E-01
0.00E+00
4.65E-01
<3
LLD OK
Beta
<3.21 E+00
0.00E+00
3.21 E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.73E+00
0.00E+00
6.73E+00
<15
<1000
LLD OK
Co-58
<5.89E+00
0.00E+00
5.89E+00
<15
<1000
LLD OK
Fe-59
<6.96E+00
0.00E+00
6.96E+00
<30
<400
LLD OK
Co-60
<6.74E+00
0.00E+00
6.74E+00
<15
<300
LLD OK
Zn-65
<1.50E+01
0.00E+00
1.50E+01
<30
<300
LLD OK
Zr-95
<8.50E+00
0.00E+00
8.50E+00
<15
<400
LLD OK
Nb-95
<5.72E+00
0.00E+00
5.72E+00
<15
<400
LLD OK
1-131
<8.56E+00
0.00E+00
8.56E+00
<15
LLD OK
Cs-134
<7.32E+00
0.00E+00
7.32E+00
<15
<30
LLD OK
Cs-137
<4.60E+00
0.00E+00
4.60E+00
<18
<50
LLD OK
Bala-140
<9.63E+00
0.00E+00
9.63E+00
<15
<200
LLD OK
Be-7
<4.65E+01
0.00E+00
4.65E+01
K-40
<1.27E+02
0.00E+00
1.27E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<2.93E+01
0.00E+00
1.92E+02
<250
<20000
LLD OK
Report Generated @ 2/15/2024 07:02:09 EnRad Laboratory Page 4 of 21
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 4 of 23 - 02/15/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 602880
Location: MW-12_ML1 [ MNS Landfill 1 / MW-12 (LANDFILL)]
Collection
Start: 1/10/2024
14:00:00
Job: MNSGW202348
Collection
End: 1/10/2024
14:00:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.65E-01
0.00E+00
4.65E-01
<3
LLD OK
Beta
<3.21 E+00
0.00E+00
3.21 E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.98E+00
0.00E+00
5.98E+00
<15
<1000
LLD OK
Co-58
<5.38E+00
0.00E+00
5.38E+00
<15
<1000
LLD OK
Fe-59
<1.02E+01
0.00E+00
1.02E+01
<30
<400
LLD OK
Co-60
<7.01 E+00
0.00E+00
7.01 E+00
<15
<300
LLD OK
Zn-65
<1.24E+01
0.00E+00
1.24E+01
<30
<300
LLD OK
Zr-95
<9.85E+00
0.00E+00
9.85E+00
<15
<400
LLD OK
Nb-95
<6.45E+00
0.00E+00
6.45E+00
<15
<400
LLD OK
1-131
<8.81 E+00
0.00E+00
8.81 E+00
<15
LLD OK
Cs-134
<7.19E+00
0.00E+00
7.19E+00
<15
<30
LLD OK
Cs-137
<7.01 E+00
0.00E+00
7.01 E+00
<18
<50
LLD OK
Bala-140
<1.00E+01
0.00E+00
1.00E+01
<15
<200
LLD OK
Be-7
<5.19E+01
0.00E+00
5.19E+01
K-40
1.33E+02
7.10E+01
9.42E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<4.26E+01
0.00E+00
1.92E+02
<250
<20000
LLD OK
Report Generated @ 2/15/2024 07:02:09 EnRad Laboratory Page 5 of 21
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 5 of 23 - 02/15/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 602881
Location: MW-13BRML1
[ MNS Landfill 1 / MW-13BR (LANDFILL)]
Collection
Start: 1/8/2024
14:30:00
Job: MNSGW202348
Collection
End: 1/8/2024
14:30:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.66E-01
0.00E+00
4.66E-01
<3
LLD OK
Beta
<3.21 E+00
0.00E+00
3.21 E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.38E+00
0.00E+00
6.38E+00
<15
<1000
LLD OK
Co-58
<4.67E+00
0.00E+00
4.67E+00
<15
<1000
LLD OK
Fe-59
<1.22E+01
0.00E+00
1.22E+01
<30
<400
LLD OK
Co-60
<6.26E+00
0.00E+00
6.26E+00
<15
<300
LLD OK
Zn-65
<9.52E+00
0.00E+00
9.52E+00
<30
<300
LLD OK
Zr-95
<6.96E+00
0.00E+00
6.96E+00
<15
<400
LLD OK
Nb-95
<5.42E+00
0.00E+00
5.42E+00
<15
<400
LLD OK
1-131
<1.16E+01
0.00E+00
1.16E+01
<15
LLD OK
Cs-134
<6.67E+00
0.00E+00
6.67E+00
<15
<30
LLD OK
Cs-137
<5.12E+00
0.00E+00
5.12E+00
<18
<50
LLD OK
Bala-140
<7.52E+00
0.00E+00
7.52E+00
<15
<200
LLD OK
Be-7
<5.21 E+01
0.00E+00
5.21 E+01
K-40
9.05E+01
7.00E+01
1.06E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-2.1 E+01
0.00E+00
1.92E+02
<250
<20000
LLD OK
Report Generated @ 2/15/2024 07:02:09 EnRad Laboratory Page 6 of 21
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 6 of 23 - 02/15/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 602882
Location: MW-13D_ML1
[ MNS Landfill
1 / MW-13D (LANDFILL)]
Collection
Start: 1/8/2024
15:30:00
Job: MNSGW202348
Collection
End: 1/8/2024
15:30:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.66E-01
0.00E+00
4.66E-01
<3
LLD OK
Beta
<3.21 E+00
0.00E+00
3.21 E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.42E+00
0.00E+00
5.42E+00
<15
<1000
LLD OK
Co-58
<6.83E+00
0.00E+00
6.83E+00
<15
<1000
LLD OK
Fe-59
<1.18E+01
0.00E+00
1.18E+01
<30
<400
LLD OK
Co-60
<5.95E+00
0.00E+00
5.95E+00
<15
<300
LLD OK
Zn-65
<1.29E+01
0.00E+00
1.29E+01
<30
<300
LLD OK
Zr-95
<1.23E+01
0.00E+00
1.23E+01
<15
<400
LLD OK
Nb-95
<7.46E+00
0.00E+00
7.46E+00
<15
<400
LLD OK
1-131
<1.03E+01
0.00E+00
1.03E+01
<15
LLD OK
Cs-134
<5.76E+00
0.00E+00
5.76E+00
<15
<30
LLD OK
Cs-137
<5.91 E+00
0.00E+00
5.91 E+00
<18
<50
LLD OK
Bala-140
<9.90E+00
0.00E+00
9.90E+00
<15
<200
LLD OK
Be-7
<4.67E+01
0.00E+00
4.67E+01
K-40
<1.30E+02
0.00E+00
1.30E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<5.61 E+01
0.00E+00
1.92E+02
<250
<20000
LLD OK
Report Generated @ 2/15/2024 07:02:09 EnRad Laboratory Page 7 of 21
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 7 of 23 - 02/15/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 602883
Location: MW-1D_ML1 [ MNS Landfill
1 / MW-1D (LANDFILL)]
Collection
Start: 1/8/2024
13:00:00
Job: MNSGW202348
Collection
End: 1/8/2024
13:00:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.66E-01
0.00E+00
4.66E-01
<3
LLD OK
Beta
<3.21 E+00
0.00E+00
3.21 E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<7.81 E+00
0.00E+00
7.81 E+00
<15
<1000
LLD OK
Co-58
<6.23E+00
0.00E+00
6.23E+00
<15
<1000
LLD OK
Fe-59
<1.24E+01
0.00E+00
1.24E+01
<30
<400
LLD OK
Co-60
<6.05E+00
0.00E+00
6.05E+00
<15
<300
LLD OK
Zn-65
<1.28E+01
0.00E+00
1.28E+01
<30
<300
LLD OK
Zr-95
<1.25E+01
0.00E+00
1.25E+01
<15
<400
LLD OK
Nb-95
<8.26E+00
0.00E+00
8.26E+00
<15
<400
LLD OK
1-131
<1.23E+01
0.00E+00
1.23E+01
<15
LLD OK
Cs-134
<8.21 E+00
0.00E+00
8.21 E+00
<15
<30
LLD OK
Cs-137
<5.77E+00
0.00E+00
5.77E+00
<18
<50
LLD OK
Bala-140
<1.18E+01
0.00E+00
1.18E+01
<15
<200
LLD OK
Be-7
<5.45E+01
0.00E+00
5.46E+01
K-40
2.74E+02
8.51 E+01
8.65E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<7.22E+01
0.00E+00
1.93E+02
<250
<20000
LLD OK
Report Generated @ 2/15/2024 07:02:09 EnRad Laboratory Page 8 of 21
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 8 of 23 - 02/15/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 602884
Location: MW-1_ML1
[MNS Landfill 1 / MW-1 (LANDFILL)]
Collection
Start: 1/8/2024 13:20:00
Job: MNSGW202348
Collection
End: 1/8/2024 13:20:00
GW Ground
Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.65E-01
0.00E+00
4.65E-01
<3
LLD OK
Beta
<3.21 E+00
0.00E+00
3.21 E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.73E+00
0.00E+00
5.73E+00
<15
<1000
LLD OK
Co-58
<5.88E+00
0.00E+00
5.88E+00
<15
<1000
LLD OK
Fe-59
<1.32E+01
0.00E+00
1.32E+01
<30
<400
LLD OK
Co-60
<5.66E+00
0.00E+00
5.66E+00
<15
<300
LLD OK
Zn-65
<1.28E+01
0.00E+00
1.28E+01
<30
<300
LLD OK
Zr-95
<1.23E+01
0.00E+00
1.23E+01
<15
<400
LLD OK
Nb-95
<6.91 E+00
0.00E+00
6.91 E+00
<15
<400
LLD OK
1-131
<1.12E+01
0.00E+00
1.12E+01
<15
LLD OK
Cs-134
<7.54E+00
0.00E+00
7.54E+00
<15
<30
LLD OK
Cs-137
<5.63E+00
0.00E+00
5.63E+00
<18
<50
LLD OK
Bala-140
<9.07E+00
0.00E+00
9.07E+00
<15
<200
LLD OK
Be-7
<4.89E+01
0.00E+00
4.89E+01
K-40
1.38E+02
8.11 E+01
1.22E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<4.79E+01
0.00E+00
1.92E+02
<250
<20000
LLD OK
Report Generated @ 2/15/2024 07:02:09 EnRad Laboratory Page 9 of 21
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 9 of 23 - 02/15/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 602885
Location: MW-2A_ML1 [ MNS Landfill
1 / MW-2A (LANDFILL)]
Collection
Start: 1/8/2024 10:40:00
Job: MNSGW202348
Collection
End: 1/8/2024 10:40:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.66E-01
0.00E+00 4.66E-01
<3
LLD OK
Beta
<3.21 E+00
0.00E+00 3.21 E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.79E+00
0.00E+00 5.79E+00
<15
<1000 LLD OK
Co-58
<5.66E+00
0.00E+00 5.66E+00
<15
<1000 LLD OK
Fe-59
<1.56E+01
0.00E+00 1.56E+01
<30
<400 LLD OK
Co-60
<7.60E+00
0.00E+00 7.60E+00
<15
<300 LLD OK
Zn-65
<1.41 E+01
0.00E+00 1.41 E+01
<30
<300 LLD OK
Zr-95
<9.89E+00
0.00E+00 9.89E+00
<15
<400 LLD OK
Nb-95
<6.80E+00
0.00E+00 6.80E+00
<15
<400 LLD OK
1-131
<1.02E+01
0.00E+00 1.02E+01
<15
LLD OK
Cs-134
<6.65E+00
0.00E+00 6.65E+00
<15
<30 LLD OK
Cs-137
<5.40E+00
0.00E+00 5.40E+00
<18
<50 LLD OK
Bala-140
<5.46E+00
0.00E+00 5.46E+00
<15
<200 LLD OK
Be-7
<4.79E+01
0.00E+00 4.79E+01
K-40
1.84E+02
8.24E+01 1.10E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<3.99E+01
0.00E+00 1.92E+02
<250
<20000 LLD OK
Report Generated @ 2/15/2024 07:02:09
EnRad Laboratory
Page 10 of 21
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 10 of 23 - 02/15/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 602886
Location: MW-2D_ML1 [ MNS Landfill
1 / MW-2D (LANDFILL)]
Collection
Start: 1/8/2024 09:40:00
Job: MNSGW202348
Collection
End: 1/8/2024 09:40:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.96E-01
0.00E+00 4.96E-01
<3
LLD OK
Beta
<3.18E+00
0.00E+00 3.18E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.43E+00
0.00E+00 5.43E+00
<15
<1000 LLD OK
Co-58
<5.45E+00
0.00E+00 5.45E+00
<15
<1000 LLD OK
Fe-59
<1.42E+01
0.00E+00 1.42E+01
<30
<400 LLD OK
Co-60
<6.70E+00
0.00E+00 6.70E+00
<15
<300 LLD OK
Zn-65
<1.60E+01
0.00E+00 1.60E+01
<30
<300 LLD OK
Zr-95
<1.17E+01
0.00E+00 1.17E+01
<15
<400 LLD OK
Nb-95
<8.85E+00
0.00E+00 8.85E+00
<15
<400 LLD OK
1-131
<1.19E+01
0.00E+00 1.19E+01
<15
LLD OK
Cs-134
<5.82E+00
0.00E+00 5.82E+00
<15
<30 LLD OK
Cs-137
<6.33E+00
0.00E+00 6.33E+00
<18
<50 LLD OK
Bala-140
<1.30E+01
0.00E+00 1.30E+01
<15
<200 LLD OK
Be-7
<5.02E+01
0.00E+00 5.02E+01
K-40
1.30E+02
8.13E+01 1.20E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<2.65E+00
0.00E+00 1.91 E+02
<250
<20000 LLD OK
Report Generated @ 2/15/2024 07:02:09
EnRad Laboratory
Page 11 of 21
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 11 of 23 - 02/15/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 602887
Location: MW-3BR_ML1 [ MNS Landfill 1 / MW-3BR (LANDFILL)]
Collection
Start: 1/10/2024 15:30:00
Job: MNSGW202348
Collection
End: 1/10/2024 15:30:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<5.00E-01
0.00E+00 5.00E-01
<3
LLD OK
Beta
7.15E+00
4.33E+00 3.18E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.79E+00
0.00E+00 6.79E+00
<15
<1000 LLD OK
Co-58
<6.32E+00
0.00E+00 6.32E+00
<15
<1000 LLD OK
Fe-59
<1.19E+01
0.00E+00 1.19E+01
<30
<400 LLD OK
Co-60
<5.79E+00
0.00E+00 5.79E+00
<15
<300 LLD OK
Zn-65
<8.73E+00
0.00E+00 8.73E+00
<30
<300 LLD OK
Zr-95
<1.01 E+01
0.00E+00 1.01E+01
<15
<400 LLD OK
Nb-95
<6.22E+00
0.00E+00 6.22E+00
<15
<400 LLD OK
1-131
<9.51 E+00
0.00E+00 9.51 E+00
<15
LLD OK
Cs-134
<7.43E+00
0.00E+00 7.43E+00
<15
<30 LLD OK
Cs-137
<4.45E+00
0.00E+00 4.45E+00
<18
<50 LLD OK
Bala-140
<6.24E+00
0.00E+00 6.24E+00
<15
<200 LLD OK
Be-7
<3.53E+01
0.00E+00 3.53E+01
K-40
1.56E+02
6.60E+01 7.78E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-3.1 E+01
0.00E+00 1.87E+02
<250
<20000 LLD OK
Report Generated @ 2/15/2024 07:02:09
EnRad Laboratory
Page 12 of 21
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 12 of 23 - 02/15/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 602888
Location: MW-3D_ML1 [ MNS Landfill
1 / MW-3D (LANDFILL)]
Collection
Start: 1/10/2024 15:35:00
Job: MNSGW202348
Collection
End: 1/10/2024 15:35:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.97E-01
0.00E+00 4.97E-01
<3
LLD OK
Beta
<3.18E+00
0.00E+00 3.18E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.92E+00
0.00E+00 5.92E+00
<15
<1000 LLD OK
Co-58
<5.88E+00
0.00E+00 5.88E+00
<15
<1000 LLD OK
Fe-59
<1.20E+01
0.00E+00 1.20E+01
<30
<400 LLD OK
Co-60
<7.50E+00
0.00E+00 7.50E+00
<15
<300 LLD OK
Zn-65
<9.99E+00
0.00E+00 9.99E+00
<30
<300 LLD OK
Zr-95
<1.13E+01
0.00E+00 1.13E+01
<15
<400 LLD OK
Nb-95
<7.90E+00
0.00E+00 7.90E+00
<15
<400 LLD OK
1-131
<9.19E+00
0.00E+00 9.19E+00
<15
LLD OK
Cs-134
<8.34E+00
0.00E+00 8.34E+00
<15
<30 LLD OK
Cs-137
<5.75E+00
0.00E+00 5.75E+00
<18
<50 LLD OK
Bala-140
<9.95E+00
0.00E+00 9.95E+00
<15
<200 LLD OK
Be-7
<4.09E+01
0.00E+00 4.09E+01
K-40
1.44E+02
7.15E+01 9.40E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-1.2E+02
0.00E+00 1.87E+02
<250
<20000 LLD OK
Report Generated @ 2/15/2024 07:02:09
EnRad Laboratory
Page 13 of 21
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 13 of 23 - 02/15/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 602889
Location: MW-3_ML1 [ MNS Landfill 1 / MW-3 (LANDFILL)]
Collection
Start: 1/10/2024 15:00:00
Job: MNSGW202348
Collection
End: 1/10/2024 15:00:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.97E-01
0.00E+00 4.97E-01
<3
LLD OK
Beta
<3.18E+00
0.00E+00 3.18E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.91 E+00
0.00E+00 5.91 E+00
<15
<1000 LLD OK
Co-58
<5.68E+00
0.00E+00 5.68E+00
<15
<1000 LLD OK
Fe-59
<1.10E+01
0.00E+00 1.10E+01
<30
<400 LLD OK
Co-60
<6.54E+00
0.00E+00 6.54E+00
<15
<300 LLD OK
Zn-65
<1.10E+01
0.00E+00 1.10E+01
<30
<300 LLD OK
Zr-95
<8.78E+00
0.00E+00 8.78E+00
<15
<400 LLD OK
Nb-95
<5.95E+00
0.00E+00 5.95E+00
<15
<400 LLD OK
1-131
<8.58E+00
0.00E+00 8.58E+00
<15
LLD OK
Cs-134
<6.40E+00
0.00E+00 6.40E+00
<15
<30 LLD OK
Cs-137
<6.86E+00
0.00E+00 6.86E+00
<18
<50 LLD OK
Bala-140
<7.27E+00
0.00E+00 7.27E+00
<15
<200 LLD OK
Be-7
<4.62E+01
0.00E+00 4.62E+01
K-40
<1.25E+02
0.00E+00 1.25E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-5.5E+01
0.00E+00 1.88E+02
<250
<20000 LLD OK
Report Generated @ 2/15/2024 07:02:09
EnRad Laboratory
Page 14 of 21
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 14 of 23 - 02/15/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 602890
Location: MW-4BRRML1 [ MNS Landfill 1 / MW-4BRR (LANDFILL)]
Collection
Start: 1/10/2024 14:15:00
Job: MNSGW202348
Collection
End: 1/10/2024 14:15:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
1.97E+00
8.50E-01 5.82E-01
<3
LLD OK
Beta
1.33E+02
5.96E+00 3.88E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.93E+00
0.00E+00 6.93E+00
<15
<1000 LLD OK
Co-58
<6.13E+00
0.00E+00 6.13E+00
<15
<1000 LLD OK
Fe-59
<1.18E+01
0.00E+00 1.18E+01
<30
<400 LLD OK
Co-60
<8.33E+00
0.00E+00 8.33E+00
<15
<300 LLD OK
Zn-65
<1.25E+01
0.00E+00 1.25E+01
<30
<300 LLD OK
Zr-95
<1.36E+01
0.00E+00 1.36E+01
<15
<400 LLD OK
Nb-95
<7.39E+00
0.00E+00 7.39E+00
<15
<400 LLD OK
1-131
<1.07E+01
0.00E+00 1.07E+01
<15
LLD OK
Cs-134
<6.42E+00
0.00E+00 6.42E+00
<15
<30 LLD OK
Cs-137
<7.21 E+00
0.00E+00 7.21 E+00
<18
<50 LLD OK
Bala-140
<9.53E+00
0.00E+00 9.53E+00
<15
<200 LLD OK
Be-7
<5.02E+01
0.00E+00 5.02E+01
K-40
2.58E+02
8.21 E+01 8.13E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-1.2E+02
0.00E+00 1.88E+02
<250
<20000 LLD OK
Report Generated @ 2/15/2024 07:02:09
EnRad Laboratory
Page 15 of 21
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 15 of 23 - 02/15/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 602891
Location: MW-4BR_ML1 [ MNS Landfill 1 / MW-4BR (LANDFILL)]
Collection
Start: 1/8/2024 13:10:00
Job: MNSGW202348
Collection
End: 1/8/2024 13:10:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<5.10E-01
0.00E+00 5.10E-01
<3
LLD OK
Beta
2.65E+01
4.71 E+00 3.18E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.59E+00
0.00E+00 6.59E+00
<15
<1000 LLD OK
Co-58
<6.24E+00
0.00E+00 6.24E+00
<15
<1000 LLD OK
Fe-59
<1.49E+01
0.00E+00 1.49E+01
<30
<400 LLD OK
Co-60
<8.13E+00
0.00E+00 8.13E+00
<15
<300 LLD OK
Zn-65
<1.49E+01
0.00E+00 1.49E+01
<30
<300 LLD OK
Zr-95
<1.23E+01
0.00E+00 1.23E+01
<15
<400 LLD OK
Nb-95
<7.11 E+00
0.00E+00 7.11 E+00
<15
<400 LLD OK
1-131
<1.28E+01
0.00E+00 1.28E+01
<15
LLD OK
Cs-134
<7.98E+00
0.00E+00 7.98E+00
<15
<30 LLD OK
Cs-137
<6.38E+00
0.00E+00 6.38E+00
<18
<50 LLD OK
Bala-140
<1.30E+01
0.00E+00 1.30E+01
<15
<200 LLD OK
Be-7
<4.81 E+01
0.00E+00 4.81 E+01
K-40
2.75E+02
8.72E+01 9.81 E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-7.4E+01
0.00E+00 1.88E+02
<250
<20000 LLD OK
Report Generated @ 2/15/2024 07:02:09
EnRad Laboratory
Page 16 of 21
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 16 of 23 - 02/15/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 602892
Location: MW-4DR_ML1 [ MNS Landfill 1 / MW-4DR (LANDFILL)]
Collection
Start: 1/10/2024 12:50:00
Job: MNSGW202348
Collection
End: 1/10/2024 12:50:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.97E-01
0.00E+00 4.97E-01
<3
LLD OK
Beta
<3.18E+00
0.00E+00 3.18E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<7.18E+00
0.00E+00 7.18E+00
<15
<1000 LLD OK
Co-58
<7.26E+00
0.00E+00 7.26E+00
<15
<1000 LLD OK
Fe-59
<1.62E+01
0.00E+00 1.62E+01
<30
<400 LLD OK
Co-60
<8.28E+00
0.00E+00 8.28E+00
<15
<300 LLD OK
Zn-65
<1.68E+01
0.00E+00 1.68E+01
<30
<300 LLD OK
Zr-95
<1.31 E+01
0.00E+00 1.31 E+01
<15
<400 LLD OK
Nb-95
<7.73E+00
0.00E+00 7.73E+00
<15
<400 LLD OK
1-131
<1.10E+01
0.00E+00 1.10E+01
<15
LLD OK
Cs-134
<8.02E+00
0.00E+00 8.02E+00
<15
<30 LLD OK
Cs-137
<5.66E+00
0.00E+00 5.66E+00
<18
<50 LLD OK
Bala-140
<1.05E+01
0.00E+00 1.05E+01
<15
<200 LLD OK
Be-7
<5.53E+01
0.00E+00 5.53E+01
K-40
1.34E+02
8.61 E+01 1.30E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-8.1 E+01
0.00E+00 1.88E+02
<250
<20000 LLD OK
Report Generated @ 2/15/2024 07:02:09
EnRad Laboratory
Page 17 of 21
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 17 of 23 - 02/15/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 602893
Location: MW-4D_ML1 [ MNS Landfill
1 / MW-4D (LANDFILL)]
Collection
Start: 1/8/2024 10:40:00
Job: MNSGW202348
Collection
End: 1/8/2024 10:40:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.97E-01
0.00E+00 4.97E-01
<3
LLD OK
Beta
<3.18E+00
0.00E+00 3.18E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.46E+00
0.00E+00 6.46E+00
<15
<1000 LLD OK
Co-58
<5.46E+00
0.00E+00 5.46E+00
<15
<1000 LLD OK
Fe-59
<9.90E+00
0.00E+00 9.90E+00
<30
<400 LLD OK
Co-60
<6.41 E+00
0.00E+00 6.41 E+00
<15
<300 LLD OK
Zn-65
<1.08E+01
0.00E+00 1.08E+01
<30
<300 LLD OK
Zr-95
<1.12E+01
0.00E+00 1.12E+01
<15
<400 LLD OK
Nb-95
<6.64E+00
0.00E+00 6.64E+00
<15
<400 LLD OK
1-131
<1.30E+01
0.00E+00 1.30E+01
<15
LLD OK
Cs-134
<7.02E+00
0.00E+00 7.02E+00
<15
<30 LLD OK
Cs-137
<5.03E+00
0.00E+00 5.03E+00
<18
<50 LLD OK
Bala-140
<9.79E+00
0.00E+00 9.79E+00
<15
<200 LLD OK
Be-7
<3.94E+01
0.00E+00 3.94E+01
K-40
<1.10E+02
0.00E+00 1.10E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-1.1E+02
0.00E+00 1.88E+02
<250
<20000 LLD OK
Report Generated @ 2/15/2024 07:02:09
EnRad Laboratory
Page 18 of 21
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 18 of 23 - 02/15/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 602894
Location: MW-4R_ML1 [ MNS Landfill
1 / MW-4R (LANDFILL)]
Collection
Start: 1/10/2024 11:20:00
Job: MNSGW202348
Collection
End: 1/10/2024 11:20:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.96E-01
0.00E+00 4.96E-01
<3
LLD OK
Beta
<3.18E+00
0.00E+00 3.18E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.41 E+00
0.00E+00 5.41 E+00
<15
<1000 LLD OK
Co-58
<5.78E+00
0.00E+00 5.78E+00
<15
<1000 LLD OK
Fe-59
<1.18E+01
0.00E+00 1.18E+01
<30
<400 LLD OK
Co-60
<8.22E+00
0.00E+00 8.22E+00
<15
<300 LLD OK
Zn-65
<1.30E+01
0.00E+00 1.30E+01
<30
<300 LLD OK
Zr-95
<1.04E+01
0.00E+00 1.04E+01
<15
<400 LLD OK
Nb-95
<7.64E+00
0.00E+00 7.64E+00
<15
<400 LLD OK
1-131
<9.49E+00
0.00E+00 9.49E+00
<15
LLD OK
Cs-134
<7.84E+00
0.00E+00 7.84E+00
<15
<30 LLD OK
Cs-137
<7.23E+00
0.00E+00 7.23E+00
<18
<50 LLD OK
Bala-140
<8.43E+00
0.00E+00 8.43E+00
<15
<200 LLD OK
Be-7
<4.99E+01
0.00E+00 4.99E+01
K-40
1.28E+02
6.19E+01 7.67E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-5.5E+01
0.00E+00 1.87E+02
<250
<20000 LLD OK
Report Generated @ 2/15/2024 07:02:09
EnRad Laboratory
Page 19 of 21
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 19 of 23 - 02/15/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 602895
Location: MW-4_ML1 [ MNS Landfill 1 / MW-4 (LANDFILL)]
Collection
Start: 1/8/2024 09:50:00
Job: MNSGW202348
Collection
End: 1/8/2024 09:50:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.97E-01
0.00E+00 4.97E-01
<3
LLD OK
Beta
<3.18E+00
0.00E+00 3.18E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.52E+00
0.00E+00 6.52E+00
<15
<1000 LLD OK
Co-58
<5.92E+00
0.00E+00 5.92E+00
<15
<1000 LLD OK
Fe-59
<9.32E+00
0.00E+00 9.32E+00
<30
<400 LLD OK
Co-60
<6.17E+00
0.00E+00 6.17E+00
<15
<300 LLD OK
Zn-65
<1.33E+01
0.00E+00 1.33E+01
<30
<300 LLD OK
Zr-95
<7.49E+00
0.00E+00 7.49E+00
<15
<400 LLD OK
Nb-95
<5.70E+00
0.00E+00 5.70E+00
<15
<400 LLD OK
1-131
<1.26E+01
0.00E+00 1.26E+01
<15
LLD OK
Cs-134
<7.61 E+00
0.00E+00 7.61 E+00
<15
<30 LLD OK
Cs-137
<5.28E+00
0.00E+00 5.28E+00
<18
<50 LLD OK
Bala-140
<1.08E+01
0.00E+00 1.08E+01
<15
<200 LLD OK
Be-7
<5.90E+01
0.00E+00 5.90E+01
K-40
<1.18E+02
0.00E+00 1.18E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-7.4E+01
0.00E+00 1.88E+02
<250
<20000 LLD OK
Report Generated @ 2/15/2024 07:02:09
EnRad Laboratory
Page 20 of 21
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 20 of 23 - 02/15/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 602896
Location: SW-1_ML1
[MNS Landfill 1 / SW-1 (LANDFILL)]
Collection
Start: 1/8/2024 14:00:00
Job: MNSGW202348
Collection
End: 1/8/2024 14:00:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.96E-01
0.00E+00 4.96E-01
<3
LLD OK
Beta
<3.18E+00
0.00E+00 3.18E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.83E+00
0.00E+00 6.83E+00
<15
<1000 LLD OK
Co-58
<7.46E+00
0.00E+00 7.46E+00
<15
<1000 LLD OK
Fe-59
<9.50E+00
0.00E+00 9.50E+00
<30
<400 LLD OK
Co-60
<5.91 E+00
0.00E+00 5.91 E+00
<15
<300 LLD OK
Zn-65
<1.35E+01
0.00E+00 1.35E+01
<30
<300 LLD OK
Zr-95
<1.33E+01
0.00E+00 1.33E+01
<15
<400 LLD OK
Nb-95
<6.71 E+00
0.00E+00 6.71 E+00
<15
<400 LLD OK
1-131
<9.92E+00
0.00E+00 9.92E+00
<15
LLD OK
Cs-134
<8.30E+00
0.00E+00 8.30E+00
<15
<30 LLD OK
Cs-137
<6.44E+00
0.00E+00 6.44E+00
<18
<50 LLD OK
Bala-140
<1.29E+01
0.00E+00 1.29E+01
<15
<200 LLD OK
Be-7
<5.47E+01
0.00E+00 5.47E+01
K-40
1.52E+02
6.63E+01 7.93E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-4.3E+01
0.00E+00 1.88E+02
<250
<20000 LLD OK
Report Generated @ 2/15/2024 07:02:09
EnRad Laboratory
Page 21 of 21
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 21 of 23 - 02/15/2024

Z nl lvl~ CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
■ v v t tea" Duke Energy EnRad Laboratories
EnRad Laboratory Use Only
ENERGY Mail Code MG03A2 (Building 7406)
"Page 7 of t
Sarno
n
7339 Ha era Furry ryRd
LIMS# MNSGw202348
cxauNDwarE
Originating
-
D1STRIBLTIGId
Huneavtlle, N.C. 28076
ORIGINAL to LAB,
Logged By Amanda Pope
Cate 6 Time 12lIbIPS 06:24
jgi;C) S75-537i
SANP� PR06NAN
COPY to CLIENT
i Fax: I99a} 876.6569 _ _..j
Grouts Www_y_
NPbES,�
❑rinklry were!_
1)Project Name:
2)Phone No:
�r'd°r
Cooler Te
Tamp (CI
MWS LANDFILL #1 PERMIT # 60.04
980.876-6267
usr
RCRA waste
3)Client
4)Fax No:
pot
Bryan Moeller 1 Ethan Smith !Ashley Healy
"Praserv.:1-HCL
u7
m
x-H,So, 3wIHo,
4Nca 6•NOM
S)Husiness Unit_ 200M
G)Process:
7Wesp, To_
AIR a
.a
BLDFLGN
MC00
Volume
E
o
g
E
v
E
o
v
$)Task ID: 9)Actwlty ID; 10)Mall Code:
!
MG03A3
A �
•-
M
Customer to complete all appropriate NON.SKApE0 areas.
c c
4
to
Collection Information
LAB USE ONLY i
¢
g
�
rn
„ 13Sampie Description or ID
0
Lab ID
Date
Time
Signature
¢
&
w
10
F
1 0
602887 i
MNS_MW-3SR
10 2
Cj
x
1
1
1
3
602851 t
MNS_MW 48R
x
1
1
1
3
602890
MNS_MW-4BRR
10}5
x
1
1
1
3
602876
MNS MVV-11BR
Q$
S
X
1
1
1
3
602$82 ;
MNS_MW-130
l Zut
1,
x
11
1
1
3
602881 i g
MNS_MVV-13BR
11TIRY
+q j 0
JX5
x
1
1
1
3
12
i.
I.
6
12
q
IEE
o
ru
'o
I�
:3
i�
Customer to sign & date below
21)Relinquis d H Smith
Da tme Accepted
yiid
By: ,q
DateMme
pRuquested Tumaround
Z1t 1 (492
21Rill inqu shad By
Datetrime Accepted
By:
Daterrime
21Rol inquished By
DatsyTime Accepted
By:
DatefTlme
'I
a R.
pays
23)SeaVLocked By
Datelrime SaaleiVl-ock
Opened By
Daterrima
r a
n
a
•48Hr
24jCommema: SAMPLES NOT ACIDIFIED IN THE FIELD - EH Smith
C r 1 W` L�K h hI d q (I M
E
n
.Other
Add.
111 j 111
V
Cost Will Apply
EnRad Laboratories - Page 22 of 23 - 02/15/2024

!_ r%I Ivr- CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
V V 111.. Duke
:
EnRad LaboratoryUse Only
de M 3A2 (uildinLaboratories746
Meil Code MG03A2 [Building 74a6)
ENERGY !
Sam la Class:
P
rvc_ I
19Page 41 v[ '
Ferry
13889 H ere Fe Rd !
LIMS # iNN3Gw2023AB
GROt1NOWATER
odglnellnq Sc
From —
DiSTFUSUTION
! HYrdfrsVillf, hi. C. 28078 !
ORIGINAL to i.At3,
t-fggM By Rmfnda Pope
Irate A Time IM6123 e8;22
i [960] b]5�Sb71 I
3MIPL6 PROGRAM
COPY to CLIENT
i _ __ __ Fax_ MCI8TS_6659 ____ _ i
Ground Waler i
14POES_
DnriMngwelar_
i}Praject Name:
2}Phone No:
Vendor
Cooler Tenrp[C}
MNS LANDFILL.#1 PERMIT#60-04
960.375.6267
tjST
RCRA We
�--VisNn
3}Client
4}Fax No:
POO
Bryan Moeller 1 Ethan Smith 7 Ashley Healy
2�;tlH aso$Da 3=HNOa
4-Ice 64%o"
.
.
S}Business. Umf, 20M
6]Pracesa:
7}Reap. To:
MR 4
BLDFLGt4
MC00
Volume
E
o
o
E
E
o
o
g]Tash ID: 9]Actirlty ID: 10}Mall Code:
MG03A3
T
.
�y]Qmer to camnlete alJ aODrQprlate.HON-S]iAflEQ 8rea5.
m
-_
LAB USE ONLY!
Q
�4Collection information
tt ! 13Sample Description or ID
g
F
O
Lab ID
Date
Time
Signature
a
602884 i
MNS_MW-1
I G74
}
x
11
1
1 1
j
3
602883
MNS _MW-1 D
1 �Aq
x
i
1
1
3
602885
MNS_MW-2A
I ZLi
logo
Y&q5
x
1
1
1
3
602886
MNS MW-20
4
�+�
S
x
1
1
1
3
602889
MNS_MW-3
` Jb q
1500
5
x
1
1
1
3
602888 !
MNS_MW-3D
j 6 Z1(
x
1
1
1
3
602895 ! p
MNS_MW4
1 IC147 Llx
1
1
1
3
602894
MNS_MW-4R
11I6 Z4
1126
x
1
1
1
3
$0289.3 3
MNS_MYU-40
MNS_MW40R
Q d
x
x
1
1
1
1
1
1
3
3
602892 A
602878 2
MNS_MW-11
1/1�
x
1
1
1
3
602877 : �"
MNS_MW-11❑
r)
lobs
x
1
1
1
3
602880
MNS_MW-12
a Z
S
x
i
1
1
3
602879 i 3
0
MNS_MW-120
J
S
x
1
1
1
3
602896 I;
MNS SW-1
z
S
x
1
1
1
3
sA0a
s ray y
r
Customer to sign & date below
21}Retln is EH i!h
Dat Ime Avcvpt/�d]Sy:
n
DalefTEma
1 1f Zy (.27
3
p�
(�C.++L/` J _ �}yt, _
7�-' ' l+r'W
{ to, 9,4 l (G �r�
Requested Turnaround
21jRetlnquhhed By
DatefTime Acsephd
By:
DatelTime
4 Days J
c
a 2
21}Rolinquished By
DaWTlme Accepted
By:
DaWTlma
17 Gaya
�E
23}SeallLocked By
DatelTima SealedlLock
Opened BY
DatalTime
c �
PL
• 46 w
24}Com manes: SAMPLES NOT ACIDIFIED IN THE FIELD - EM Smith
-m
E
'other
U
Add. Cast WR Appry
EnRad Laboratories - Page 23 of 23 - 02/15/2024