MO-28208_47470_CA_MRP_20240331

SOUTHEASTERN GEOLOGICAL SERVICES
PO Box 441
Shelby, NC 28151
704 481 8558
TRANSMITTAL LETTER
JIM’S GROCERY
The following report is issued in pdf format:
-) MO_28208_47470_CA_MRP_20240331.PDF
-) Jim’s Grocery
-) Incident #: 47470
-) Monitoring Report
-) 3-31-24
-) Facility ID: 0-015988
Richard Kelly
Geologist
1
B. EXECUTIVE SUMMARY
A groundwater sampling event was conducted on March 19, 2024. Groundwater contamination
is restricted to MW-1, the source well. Benzene and MTBE decreased significantly;
ethylbenzene, toluene, and xylenes remained at minor levels. The alcohols were mixed: TAA
increased but TBA decreased. The other monitor wells and the site water supply well are non-
detect.
C. TABLE OF CONTENTS
Section D Site History 1
Section E Site Assessment 1
Section F Free Product 2
Section G Soil Remediation 2
Section H Groundwater Remediation 2
Section I Conclusions 3
Section J Figures 3
Section K Tables 3
Section L Appendices 3
D. SITE HISTORY and CHARACTERIZATION
An environmental assessment discovered groundwater contamination around the site’s UST
basin. The assessment was performed by Geologic Resources in November 2020 for United
Bank of Raleigh. A Site Check performed in April 2021 determined that the release occurred
through the fill bucket of UST-4. A phase 2 LSA, with a vertical extent well, determined that the
groundwater contamination is restricted to the upper portion of the unconfined aquifer at the
UST basin – MW-1.
.
E. SITE ASSESSMENT INFORMATION
1.0 GROUNDWATER SAMPLING
1.1 General
The following wells were sampled: (1) the site water supply well (WSW-1), and (2) MWs 1-2-3-
4, and the vertical extent well (VMW-1). The groundwater samples were collected
March 19, 2014 and the samples were analyzed by method 6200B with oxygenates. The results
are presented in Table B-4, Table 1 is an analysis history, and individual MTBE, TAA, and TBA
contaminant concentration maps are attached.
2
1.2 Sampling Results
1.2.1 Water Supply Well (WSW-1)
WSW-1 was non detect, same as the prior sampling events.
1.2.2 Monitor Wells
Compounds were only detected in MW-1, the source well. MTBE, tert-Amyl Alcohol, and tert-
Butyl Alcohol were detected above their groundwater standards, but well below their gross
contaminant levels. A summary follows:
MW-1: MTBE, tert-Amyl Alcohol, and tert-Butyl Alcohol > standard, but < GCL,
MW-2: non detect,
MW-3: non detect,
MW-4: non detect, and
VMW-1: non-detect.
A comparison with the last sampling event (9-23) follows.
MW-1: benzene and MTBE decreased significantly (benzene to non detect (<2.5 ppb)),
ethylbenzene, toluene, and xylenes remain at trace levels
TAA increase approximately 40% but TBA decrease approximately 30%,
MW-2: remain non detect,
MW-3: remain non detect,
MW-4: remain non detect, and
VMW-1: remain non detect.
1.3 Sampling Protocol
The monitor wells were sampled with new, disposable bailers after purging three well casing
volumes. The samples were placed in laboratory provided vials, fixed with a chain of custody,
and placed on ice for shipment between the field, office, and laboratory. They were refrigerated
at our office and picked up by a PACE Analytical courier the following day. The water supply
well was sampled from an outside tap after running the water for fifteen minutes. It was handled
as described above.
F. FREE PRODUCT - not applicable
G. SOIL REMEDIATION – not applicable
H. GROUNDWATER REMEDIATION
Currently the site is ranked Intermediate and natural attenuation is being utilized.
3
I. CONCUSIONS
The groundwater contamination remains concentrated at the source area. MTBE,
tert-Amyl Alcohol, and tert-Butyl Alcohol are present in MW-1 above their standards, but the
levels are well below their GCLs. Benzene and MTBE have now had consecutive fall to spring
decreases. The reason is unclear as the water levels are not significantly different. The plume
has not migrated into the down gradient wells
J. FIGURES
USGS Topographic Map
Groundwater Flow Map
MTBE Iso-Concentration Map – large and small scale
Tert-Amyl Alcohol Iso-Concentration Map – large and small scale
Tert-Butyl Alcohol Iso-Concentration Map – large and small scale
Cross Section
K. TABLES
Table B-4 Summary of Groundwater Sampling Results
Table 1 Historical Groundwater Sampling
Table B-7 Well Construction Information
Table B-9 Current Groundwater Elevations
Table B-9 Historical Groundwater Elevations: MWs 1-2-3-4
L. APPENDICES
MW-1: Time/Concentration Graph
Laboratory Analysis/Chain of Custody
Table B-4: Summary of Groundwater and Surface Water Sampling Results
Revision Date: Incident Number and Name: 47470 Jim’s Grocery Facility ID#:
Analytical Method (e.g., VOC by SM6000B) or
Field Measurement (FM)6200B 6200B 6200B` 6200B 6200B 6200B 6200B 6200B 6200B 504.1
Contaminant of Concern/ Field Measurement
Benzene
Toluene
Ethylbenzene
Xylenes
MTBE
IPE
Naphthalene
1,2
DCE
EDB
Well or
SW ID
Date
Collected
Sample
ID
Incident
Phase
MW-1 3-19-24 MW-1 Monitor <2.5 <2.5 <2.5 <5 649 <2.5 <10 <2.5 <2.5
MW-2 “ MW-2 “ <1 <1 <1 <2 <1 <1 <2 <1 <1
MW-3 “ MW-3 “ <1 <1 <1 <2 <1 <1 <2 <1 <1
MW-4 “ MW-4 “ <1 <1 <1 <2 <1 <1 <2 <1 <1
VMW-1 “ VMW-1 “ <1 <1 <1 <2 <1 <1 <2 <1 <1
WSW-1 “ WSW-1 “ <1 <1 <1 <2 <1 <1 <2 <1 <1
Minimum Reporting Limit (ug/l)
2L Standard (ug/l)1 600 600 500 20 70 6 0.4 0.02
GCL (ug/l)5000 260000 84500 85500 20000 70000 6000 400 50
NC 2B Standard or EPA National Criteria
(ug/l)
Results in ug/l
Results rounded to whole numbers
Table B-4: Summary of Groundwater and Surface Water Sampling Results
Revision Date: Incident Number and Name: 47470 Jim’s Grocery Facility ID#:
Analytical Method (e.g., VOC by SM6000B) or
Field Measurement (FM)6200B 6200B 6200B 6200B` 6200B` 6200B 6200B 6200B 3030C
Contaminant of Concern/ Field Measurement
n-Butlybenzene
Sec-
Butylbenzene
Tert-
Butylbenzene
Isopropyl
benzene
n-Propylbenzene
Styrene
1,2,4
Trimethyl
benzene
1,3,5
Trimethyl
benzene
Tert-Amyl
Alcohol
Tert-Butyl
Alcohol
Well or
SW ID
Date
Collected
Sample
ID
Incident
Phase
MW-1 3-19-24 MW-1 Monitor <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 2400 467
MW-2 “ MW-2 “ <1 <1 <1 <2 <1 <1 <2 <1 <100 <50
MW-3 “ MW-3 “ <1 <1 <1 <2 <1 <1 <2 <1 <100 <50
MW-4 “ MW-4 “ <1 <1 <1 <2 <1 <1 <2 <1 <100 <50
VMW-1 “ VMW-1 “ <1 <1 <1 <2 <1 <1 <2 <1 <100 <50
WSW-1 “ WSW-1 “ <1 <1 <1 <1 <1 <1 <1 <1 <100 <50
Minimum Reporting Limit (ug/l)
2L Standard (ug/l)70 70 70 70 70 70 400 400 40 10
GCL (ug/l)6900 8500 15000 25000 30000 70000 28500 25000 40000 10000
NC 2B Standard or EPA National Criteria
(ug/l)
Results reported in ug/l
Results rounded to whole numbers
TABLE 1: HISTORICAL GROUNDWATER SAMPLING
tert tert
Benzene Toluene Ethtlb.Xylenes MTBE Naphth.AmylAlc.ButylAl.
Standard 1 600 600 500 20 6
GCL 5000 260000 84500 85500 20000 6000
MW-1
8/26/2021 113 7 95 372 <1 25
5/31/2022 40 <2 <2 <6 481 <8 1100 352
8/30/2022 625 54 13 91 1230 <20 2090 942
3/16/2023 349 8 4 14 931 <20 2300 719
9/1/2023 389 3 <3 10 969 <10 1680 642
3/19/2024 <2.5 <2.5 <2.5 <5 649 <10 2400 467
MWs 2-3-4 & VMW-1 non-detect
Table B-7: Monitoring and Remediation Well Construction Information
Revision Date: 7-17-17 Incident Number and Name: Jim’s Grocery Facility ID#:
Well ID
Date
Installed
(m/dd/yy
)
Date
Water
Level
Measured
(m/dd/yy)
Well
Casing
Diameter
(in.)
Well
Casing
Depth
(ft.
BGS)
Screened
Interval
(x to y
ft. BGS)
Depth
of Well
(ft.
BGS)
Top of
Casing
Elevation*
(ft.)
Depth to
Water
from Top
of Casing
(ft.)
Free
Product
Thickness
**(ft.)
Groundwater
Elevation*
(ft.)
Latitude/
Longitude
(decimal
degrees)***
1 8-25-21 3-19-24 2 20 20-40 40 100.00 30.42 0 69.58 35.20159
-81.02346
2 “ “ 2 20 20-40 40 100.82 30.68 0 70.14 35.20180
-81.02355
3 “ , 2 20 20-40 40 102.68 33.38 0 69.30 35.20157
-81.02331
4 “ “ 2 20 20-40 40 102.27 33.01 0 69.26 35.20153
-81.02340
VMW-1 2-15-22 “ 2 67 67 70 100.13 31.11 0 69.02 35.20155
-80.02346
Ft BGS = feet below ground surface
* Reference Point for Elevation MeasurementsMW-100 , Assumed Elevation: 100.00 ft.
** If free product is present in a well, groundwater elevation is calculated by: [Top of Casing Elevation - Depth to Water] + [free product thickness x 0.8581]
***The location must be sufficiently accurate and precise to allow easy recovery of lost or damaged wells.
Table B-9: Current and Historical Groundwater Elevations and Free Product Thickness
Revision Date: 9-28-22 Incident Number and Name: 47470 Jim’s Grocery Facility ID#: 0-015988
Well ID
#Date
Screened Interval
(top of screen,
bottom of screen)
Depth to Water*
Uncorrected
(feet)
Free
Product
Thickness
(feet)
Depth to Water*
Corrected
for Free Product
Thickness(feet)
Top of
Casing
Elevation
(MSL)
Groundwater
Surface
Elevation
(MSL)
1 3-19-24 20 - 40 30.42 0 30.42 100.00 69.58
2 ““30.68 "30.68 99.95 70.14
3 ““33.38 "33.38 101.83 69.30
4 "“33.01 "33.01 102.03 69.26
VMW-1 “67-70 31.11 “ 31.11 100.13 69.02
*Depth to Water is measured from Top of Casing
Table B-9: Current and Historical Groundwater Elevations and Free Product Thickness
Revision Date: 9-28-222-29-19 Incident Number and Name: 47470 Jim’s Grocery Facility ID#: 0-015988
Well ID
#Date
Screened Interval
(top of screen,
bottom of screen)
Depth to Water*
Uncorrected
(feet)
Free
Product
Thickness
(feet)
Depth to Water*
Corrected
for Free Product
Thickness(feet)
Top of
Casing
Elevation
(MSL)
Groundwater
Surface
Elevation
(MSL)
1 3-19-24 20-40 30.42 0 30.42 100.00 69.58
1 9-1-23 “ 30.56 0 30.56 “ 69.44
1 3-16-23 “ 30.08 0 30.08 “ 69.92
1 8-30-22 “ 30.72 0 30.72 “ 69.28
1 5-31-22 “ 31.44 0 31.44 “ 68.56
1 8-26-21 “ 31.11 0 31.11 “ 68.89
Table B-9: Current and Historical Groundwater Elevations and Free Product Thickness
Revision Date: 9-28-22 Incident Number and Name: 47470 Jim’s Grocery Facility ID#: 0-015988
Well ID
#Date
Screened Interval
(top of screen,
bottom of screen)
Depth to Water*
Uncorrected
(feet)
Free
Product
Thickness
(feet)
Depth to Water*
Corrected
for Free Product
Thickness(feet)
Top of
Casing
Elevation
(MSL)
Groundwater
Surface
Elevation
(MSL)
2 3-19-24 20-40 30.68 0 30.68 100.82 70.14
2 9-1-23 “ 30.79 0 30.79 “ 70.03
2 3-16-23 “ 30.41 0 30.41 “ 70.41
2 8-30-22 “ 30.14 0 30.14 “69.81
2 5-31-22 “ 30.66 0 30.66 “ 69.29
2 8-25-21 “ 31.29 0 31.29 “ 69.53
Table B-9: Current and Historical Groundwater Elevations and Free Product Thickness
Revision Date: 2-29-19 Incident Number and Name: 14609 Ray’s Country Store Facility ID#:
Well ID
#Date
Screened Interval
(top of screen,
bottom of screen)
Depth to Water*
Uncorrected
(feet)
Free
Product
Thickness
(feet)
Depth to Water*
Corrected
for Free Product
Thickness(feet)
Top of
Casing
Elevation
(MSL)
Groundwater
Surface
Elevation
(MSL)
3 3-19-24 20-40 33.38 0 33.38 102.68 69.30
3 9-1-23 “ 33.54 0 33.54 “ 69.14
3 3-16-23 “ 33.07 0 33.07 “ 69.61
3 8-30-22 “ 32.89 0 32.89 “ 68.94
3 5-31-22 “ 33.61 0 33.61 101.83 68.22
3 8-26-21 “ 33.94 0 33.94 “ 68.74
Table B-9: Current and Historical Groundwater Elevations and Free Product Thickness
Revision Date: 9-28-22 Incident Number and Name: 47470 Jim’s Grocery Facility ID#: 0.015988
Well ID
#Date
Screened Interval
(top of screen,
bottom of screen)
Depth to Water*
Uncorrected
(feet)
Free
Product
Thickness
(feet)
Depth to Water*
Corrected
for Free Product
Thickness(feet)
Top of
Casing
Elevation
(MSL)
Groundwater
Surface
Elevation
(MSL)
4 3-19-24 20-40 33.01 0 33.01 102.27 69.26
4 9-1-23 “ 33.12 0 33.12 “ 69.18
4 3-16-23 “ 32.61 0 32.61 “ 69.66
4 8-30-22 “ 33.06 0 33.06 “ 68.97
4 5-31-22 “ 33.78 0 33.78 102.03 68.25
4 8-26-21 “ 33.60 0 33.60 “ 68.67
0
200
400
600
800
1000
1200
1400
8/26/2021 5/31/2022 8/30/2022 3/16/2023 9/1/2023 3/19/2024
MW-1
B T E X MTBE
0
500
1000
1500
2000
2500
3000
5/31/2022 8/30/2022 3/16/2023 9/1/2023 3/19/2024
MW-1: alcohols
TAA TBA
#=CL#
March 26, 2024
LIMS USE: FR - RICHARD KELLY
LIMS OBJECT ID: 92720084
92720084
Project:
Pace Project No.:
RE:
Mr. Richard Kelly
SE Geologic
301 Windsor Dr.
Shelby, NC 28150
JIM'S GROCERY
Dear Mr. Kelly:
Enclosed are the analytical results for sample(s) received by the laboratory on March 20, 2024. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Matthew Brainard
[e-mail]
Project Manager
704-977-0942
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 25
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92720084
JIM'S GROCERY
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 25
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92720084
JIM'S GROCERY
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92720084001 WSW-1 SM 6200B 69 PASI-CJJK
92720084002 MW-1 SM 6200B 69 PASI-CJJK
92720084003 MW-2 SM 6200B 69 PASI-CJJK
92720084004 MW-3 SM 6200B 69 PASI-CJJK
92720084005 MW-4 SM 6200B 69 PASI-CJJK
92720084006 VMW-1 SM 6200B 69 PASI-CJJK
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92720084
JIM'S GROCERY
Sample:WSW-1 Lab ID:92720084001 Collected:03/19/24 13:00 Received:03/20/24 08:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol ND ug/L 03/21/24 09:17 75-85-41001
tert-Amylmethyl ether ND ug/L 03/21/24 09:17 994-05-810.0 1
Benzene ND ug/L 03/21/24 09:17 71-43-20.50 1
Bromobenzene ND ug/L 03/21/24 09:17 108-86-10.50 1
Bromochloromethane ND ug/L 03/21/24 09:17 74-97-50.50 1
Bromodichloromethane ND ug/L 03/21/24 09:17 75-27-40.50 1
Bromoform ND ug/L 03/21/24 09:17 75-25-20.50 1
Bromomethane ND ug/L 03/21/24 09:17 74-83-95.0 1
tert-Butyl Alcohol ND ug/L 03/21/24 09:17 75-65-050.0 1
n-Butylbenzene ND ug/L 03/21/24 09:17 104-51-80.50 1
sec-Butylbenzene ND ug/L 03/21/24 09:17 135-98-80.50 1
tert-Butylbenzene ND ug/L 03/21/24 09:17 98-06-60.50 1
tert-Butyl Formate ND ug/L 03/21/24 09:17 762-75-450.0 1
Carbon tetrachloride ND ug/L 03/21/24 09:17 56-23-50.50 1
Chlorobenzene ND ug/L 03/21/24 09:17 108-90-70.50 1
Chloroethane ND ug/L 03/21/24 09:17 75-00-31.0 1
Chloroform ND ug/L 03/21/24 09:17 67-66-30.50 1
Chloromethane ND ug/L 03/21/24 09:17 74-87-31.0 1
2-Chlorotoluene ND ug/L 03/21/24 09:17 95-49-80.50 1
4-Chlorotoluene ND ug/L 03/21/24 09:17 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 03/21/24 09:17 96-12-81.0 1
Dibromochloromethane ND ug/L 03/21/24 09:17 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 03/21/24 09:17 106-93-40.50 1
Dibromomethane ND ug/L 03/21/24 09:17 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 03/21/24 09:17 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 03/21/24 09:17 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 03/21/24 09:17 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 03/21/24 09:17 75-71-80.50 1
1,1-Dichloroethane ND ug/L 03/21/24 09:17 75-34-30.50 1
1,2-Dichloroethane ND ug/L 03/21/24 09:17 107-06-20.50 1
1,1-Dichloroethene ND ug/L 03/21/24 09:17 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 03/21/24 09:17 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 03/21/24 09:17 156-60-50.50 1
1,2-Dichloropropane ND ug/L 03/21/24 09:17 78-87-50.50 1
1,3-Dichloropropane ND ug/L 03/21/24 09:17 142-28-90.50 1
2,2-Dichloropropane ND ug/L 03/21/24 09:17 594-20-70.50 1
1,1-Dichloropropene ND ug/L 03/21/24 09:17 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 03/21/24 09:17 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 03/21/24 09:17 10061-02-60.50 1
Diisopropyl ether ND ug/L 03/21/24 09:17 108-20-30.50 1
Ethanol ND ug/L 03/21/24 09:17 64-17-52001
Ethylbenzene ND ug/L 03/21/24 09:17 100-41-40.50 1
Ethyl-tert-butyl ether ND ug/L 03/21/24 09:17 637-92-310.0 1
Hexachloro-1,3-butadiene ND ug/L 03/21/24 09:17 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 03/21/24 09:17 98-82-80.50 1
Methylene Chloride ND ug/L 03/21/24 09:17 75-09-22.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/26/2024 10:58 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92720084
JIM'S GROCERY
Sample:WSW-1 Lab ID:92720084001 Collected:03/19/24 13:00 Received:03/20/24 08:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methyl-tert-butyl ether ND ug/L 03/21/24 09:17 1634-04-40.50 1
Naphthalene ND ug/L 03/21/24 09:17 91-20-32.0 1
n-Propylbenzene ND ug/L 03/21/24 09:17 103-65-10.50 1
Styrene ND ug/L 03/21/24 09:17 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 03/21/24 09:17 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 03/21/24 09:17 79-34-50.50 1
Tetrachloroethene ND ug/L 03/21/24 09:17 127-18-40.50 1
Toluene ND ug/L 03/21/24 09:17 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 03/21/24 09:17 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 03/21/24 09:17 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 03/21/24 09:17 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 03/21/24 09:17 79-00-50.50 1
Trichloroethene ND ug/L 03/21/24 09:17 79-01-60.50 1
Trichlorofluoromethane ND ug/L 03/21/24 09:17 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 03/21/24 09:17 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 03/21/24 09:17 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 03/21/24 09:17 108-67-80.50 1
Vinyl chloride ND ug/L 03/21/24 09:17 75-01-41.0 1
m&p-Xylene ND ug/L 03/21/24 09:17 179601-23-11.0 1
o-Xylene ND ug/L 03/21/24 09:17 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)80 %03/21/24 09:17 17060-07-070-130 1
4-Bromofluorobenzene (S)92 %03/21/24 09:17 460-00-470-130 1
Toluene-d8 (S)98 %03/21/24 09:17 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/26/2024 10:58 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92720084
JIM'S GROCERY
Sample:MW-1 Lab ID:92720084002 Collected:03/19/24 13:00 Received:03/20/24 08:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol 2400 ug/L 03/21/24 11:24 75-85-45005
tert-Amylmethyl ether ND ug/L 03/21/24 11:24 994-05-850.0 5
Benzene ND ug/L 03/21/24 11:24 71-43-22.5 5
Bromobenzene ND ug/L 03/21/24 11:24 108-86-12.5 5
Bromochloromethane ND ug/L 03/21/24 11:24 74-97-52.5 5
Bromodichloromethane ND ug/L 03/21/24 11:24 75-27-42.5 5
Bromoform ND ug/L 03/21/24 11:24 75-25-22.5 5
Bromomethane ND ug/L 03/21/24 11:24 74-83-925.0 5
tert-Butyl Alcohol 467 ug/L 03/21/24 11:24 75-65-02505
n-Butylbenzene ND ug/L 03/21/24 11:24 104-51-82.5 5
sec-Butylbenzene ND ug/L 03/21/24 11:24 135-98-82.5 5
tert-Butylbenzene ND ug/L 03/21/24 11:24 98-06-62.5 5
tert-Butyl Formate ND ug/L 03/21/24 11:24 762-75-42505
Carbon tetrachloride ND ug/L 03/21/24 11:24 56-23-52.5 5
Chlorobenzene ND ug/L 03/21/24 11:24 108-90-72.5 5
Chloroethane ND ug/L 03/21/24 11:24 75-00-35.0 5
Chloroform 38.0 ug/L 03/21/24 11:24 67-66-32.5 5
Chloromethane ND ug/L 03/21/24 11:24 74-87-35.0 5
2-Chlorotoluene ND ug/L 03/21/24 11:24 95-49-82.5 5
4-Chlorotoluene ND ug/L 03/21/24 11:24 106-43-42.5 5
1,2-Dibromo-3-chloropropane ND ug/L 03/21/24 11:24 96-12-85.0 5
Dibromochloromethane ND ug/L 03/21/24 11:24 124-48-12.5 5
1,2-Dibromoethane (EDB)ND ug/L 03/21/24 11:24 106-93-42.5 5
Dibromomethane ND ug/L 03/21/24 11:24 74-95-32.5 5
1,2-Dichlorobenzene ND ug/L 03/21/24 11:24 95-50-12.5 5
1,3-Dichlorobenzene ND ug/L 03/21/24 11:24 541-73-12.5 5
1,4-Dichlorobenzene ND ug/L 03/21/24 11:24 106-46-72.5 5
Dichlorodifluoromethane ND ug/L 03/21/24 11:24 75-71-82.5 5
1,1-Dichloroethane ND ug/L 03/21/24 11:24 75-34-32.5 5
1,2-Dichloroethane ND ug/L 03/21/24 11:24 107-06-22.5 5
1,1-Dichloroethene ND ug/L 03/21/24 11:24 75-35-42.5 5
cis-1,2-Dichloroethene ND ug/L 03/21/24 11:24 156-59-22.5 5
trans-1,2-Dichloroethene ND ug/L 03/21/24 11:24 156-60-52.5 5
1,2-Dichloropropane ND ug/L 03/21/24 11:24 78-87-52.5 5
1,3-Dichloropropane ND ug/L 03/21/24 11:24 142-28-92.5 5
2,2-Dichloropropane ND ug/L 03/21/24 11:24 594-20-72.5 5
1,1-Dichloropropene ND ug/L 03/21/24 11:24 563-58-62.5 5
cis-1,3-Dichloropropene ND ug/L 03/21/24 11:24 10061-01-52.5 5
trans-1,3-Dichloropropene ND ug/L 03/21/24 11:24 10061-02-62.5 5
Diisopropyl ether 22.3 ug/L 03/21/24 11:24 108-20-32.5 5
Ethanol ND ug/L 03/21/24 11:24 64-17-510005
Ethylbenzene ND ug/L 03/21/24 11:24 100-41-42.5 5
Ethyl-tert-butyl ether ND ug/L 03/21/24 11:24 637-92-350.0 5
Hexachloro-1,3-butadiene ND ug/L 03/21/24 11:24 87-68-310.0 5
Isopropylbenzene (Cumene)ND ug/L 03/21/24 11:24 98-82-82.5 5
Methylene Chloride ND ug/L 03/21/24 11:24 75-09-210.0 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/26/2024 10:58 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92720084
JIM'S GROCERY
Sample:MW-1 Lab ID:92720084002 Collected:03/19/24 13:00 Received:03/20/24 08:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methyl-tert-butyl ether 649 ug/L 03/21/24 11:24 1634-04-42.5 5
Naphthalene ND ug/L 03/21/24 11:24 91-20-310.0 5
n-Propylbenzene ND ug/L 03/21/24 11:24 103-65-12.5 5
Styrene ND ug/L 03/21/24 11:24 100-42-52.5 5
1,1,1,2-Tetrachloroethane ND ug/L 03/21/24 11:24 630-20-62.5 5
1,1,2,2-Tetrachloroethane ND ug/L 03/21/24 11:24 79-34-52.5 5
Tetrachloroethene ND ug/L 03/21/24 11:24 127-18-42.5 5
Toluene ND ug/L 03/21/24 11:24 108-88-32.5 5
1,2,3-Trichlorobenzene ND ug/L 03/21/24 11:24 87-61-610.0 5
1,2,4-Trichlorobenzene ND ug/L 03/21/24 11:24 120-82-110.0 5
1,1,1-Trichloroethane ND ug/L 03/21/24 11:24 71-55-62.5 5
1,1,2-Trichloroethane ND ug/L 03/21/24 11:24 79-00-52.5 5
Trichloroethene ND ug/L 03/21/24 11:24 79-01-62.5 5
Trichlorofluoromethane ND ug/L 03/21/24 11:24 75-69-45.0 5
1,2,3-Trichloropropane ND ug/L 03/21/24 11:24 96-18-42.5 5
1,2,4-Trimethylbenzene ND ug/L 03/21/24 11:24 95-63-62.5 5
1,3,5-Trimethylbenzene ND ug/L 03/21/24 11:24 108-67-82.5 5
Vinyl chloride ND ug/L 03/21/24 11:24 75-01-45.0 5
m&p-Xylene ND ug/L 03/21/24 11:24 179601-23-15.0 5
o-Xylene ND ug/L 03/21/24 11:24 95-47-62.5 5
Surrogates
1,2-Dichloroethane-d4 (S)81 %03/21/24 11:24 17060-07-070-130 5
4-Bromofluorobenzene (S)93 %03/21/24 11:24 460-00-470-130 5
Toluene-d8 (S)98 %03/21/24 11:24 2037-26-570-130 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/26/2024 10:58 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92720084
JIM'S GROCERY
Sample:MW-2 Lab ID:92720084003 Collected:03/19/24 13:00 Received:03/20/24 08:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol ND ug/L 03/21/24 09:35 75-85-41001
tert-Amylmethyl ether ND ug/L 03/21/24 09:35 994-05-810.0 1
Benzene ND ug/L 03/21/24 09:35 71-43-20.50 1
Bromobenzene ND ug/L 03/21/24 09:35 108-86-10.50 1
Bromochloromethane ND ug/L 03/21/24 09:35 74-97-50.50 1
Bromodichloromethane ND ug/L 03/21/24 09:35 75-27-40.50 1
Bromoform ND ug/L 03/21/24 09:35 75-25-20.50 1
Bromomethane ND ug/L 03/21/24 09:35 74-83-95.0 1
tert-Butyl Alcohol ND ug/L 03/21/24 09:35 75-65-050.0 1
n-Butylbenzene ND ug/L 03/21/24 09:35 104-51-80.50 1
sec-Butylbenzene ND ug/L 03/21/24 09:35 135-98-80.50 1
tert-Butylbenzene ND ug/L 03/21/24 09:35 98-06-60.50 1
tert-Butyl Formate ND ug/L 03/21/24 09:35 762-75-450.0 1
Carbon tetrachloride ND ug/L 03/21/24 09:35 56-23-50.50 1
Chlorobenzene ND ug/L 03/21/24 09:35 108-90-70.50 1
Chloroethane ND ug/L 03/21/24 09:35 75-00-31.0 1
Chloroform ND ug/L 03/21/24 09:35 67-66-30.50 1
Chloromethane ND ug/L 03/21/24 09:35 74-87-31.0 1
2-Chlorotoluene ND ug/L 03/21/24 09:35 95-49-80.50 1
4-Chlorotoluene ND ug/L 03/21/24 09:35 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 03/21/24 09:35 96-12-81.0 1
Dibromochloromethane ND ug/L 03/21/24 09:35 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 03/21/24 09:35 106-93-40.50 1
Dibromomethane ND ug/L 03/21/24 09:35 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 03/21/24 09:35 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 03/21/24 09:35 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 03/21/24 09:35 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 03/21/24 09:35 75-71-80.50 1
1,1-Dichloroethane ND ug/L 03/21/24 09:35 75-34-30.50 1
1,2-Dichloroethane ND ug/L 03/21/24 09:35 107-06-20.50 1
1,1-Dichloroethene ND ug/L 03/21/24 09:35 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 03/21/24 09:35 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 03/21/24 09:35 156-60-50.50 1
1,2-Dichloropropane ND ug/L 03/21/24 09:35 78-87-50.50 1
1,3-Dichloropropane ND ug/L 03/21/24 09:35 142-28-90.50 1
2,2-Dichloropropane ND ug/L 03/21/24 09:35 594-20-70.50 1
1,1-Dichloropropene ND ug/L 03/21/24 09:35 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 03/21/24 09:35 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 03/21/24 09:35 10061-02-60.50 1
Diisopropyl ether ND ug/L 03/21/24 09:35 108-20-30.50 1
Ethanol ND ug/L 03/21/24 09:35 64-17-52001
Ethylbenzene ND ug/L 03/21/24 09:35 100-41-40.50 1
Ethyl-tert-butyl ether ND ug/L 03/21/24 09:35 637-92-310.0 1
Hexachloro-1,3-butadiene ND ug/L 03/21/24 09:35 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 03/21/24 09:35 98-82-80.50 1
Methylene Chloride ND ug/L 03/21/24 09:35 75-09-22.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/26/2024 10:58 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92720084
JIM'S GROCERY
Sample:MW-2 Lab ID:92720084003 Collected:03/19/24 13:00 Received:03/20/24 08:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methyl-tert-butyl ether ND ug/L 03/21/24 09:35 1634-04-40.50 1
Naphthalene ND ug/L 03/21/24 09:35 91-20-32.0 1
n-Propylbenzene ND ug/L 03/21/24 09:35 103-65-10.50 1
Styrene ND ug/L 03/21/24 09:35 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 03/21/24 09:35 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 03/21/24 09:35 79-34-50.50 1
Tetrachloroethene ND ug/L 03/21/24 09:35 127-18-40.50 1
Toluene ND ug/L 03/21/24 09:35 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 03/21/24 09:35 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 03/21/24 09:35 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 03/21/24 09:35 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 03/21/24 09:35 79-00-50.50 1
Trichloroethene ND ug/L 03/21/24 09:35 79-01-60.50 1
Trichlorofluoromethane ND ug/L 03/21/24 09:35 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 03/21/24 09:35 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 03/21/24 09:35 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 03/21/24 09:35 108-67-80.50 1
Vinyl chloride ND ug/L 03/21/24 09:35 75-01-41.0 1
m&p-Xylene ND ug/L 03/21/24 09:35 179601-23-11.0 1
o-Xylene ND ug/L 03/21/24 09:35 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)81 %03/21/24 09:35 17060-07-070-130 1
4-Bromofluorobenzene (S)92 %03/21/24 09:35 460-00-470-130 1
Toluene-d8 (S)98 %03/21/24 09:35 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/26/2024 10:58 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92720084
JIM'S GROCERY
Sample:MW-3 Lab ID:92720084004 Collected:03/19/24 13:00 Received:03/20/24 08:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol ND ug/L 03/21/24 09:53 75-85-41001
tert-Amylmethyl ether ND ug/L 03/21/24 09:53 994-05-810.0 1
Benzene ND ug/L 03/21/24 09:53 71-43-20.50 1
Bromobenzene ND ug/L 03/21/24 09:53 108-86-10.50 1
Bromochloromethane ND ug/L 03/21/24 09:53 74-97-50.50 1
Bromodichloromethane ND ug/L 03/21/24 09:53 75-27-40.50 1
Bromoform ND ug/L 03/21/24 09:53 75-25-20.50 1
Bromomethane ND ug/L 03/21/24 09:53 74-83-95.0 1
tert-Butyl Alcohol ND ug/L 03/21/24 09:53 75-65-050.0 1
n-Butylbenzene ND ug/L 03/21/24 09:53 104-51-80.50 1
sec-Butylbenzene ND ug/L 03/21/24 09:53 135-98-80.50 1
tert-Butylbenzene ND ug/L 03/21/24 09:53 98-06-60.50 1
tert-Butyl Formate ND ug/L 03/21/24 09:53 762-75-450.0 1
Carbon tetrachloride ND ug/L 03/21/24 09:53 56-23-50.50 1
Chlorobenzene ND ug/L 03/21/24 09:53 108-90-70.50 1
Chloroethane ND ug/L 03/21/24 09:53 75-00-31.0 1
Chloroform ND ug/L 03/21/24 09:53 67-66-30.50 1
Chloromethane ND ug/L 03/21/24 09:53 74-87-31.0 1
2-Chlorotoluene ND ug/L 03/21/24 09:53 95-49-80.50 1
4-Chlorotoluene ND ug/L 03/21/24 09:53 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 03/21/24 09:53 96-12-81.0 1
Dibromochloromethane ND ug/L 03/21/24 09:53 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 03/21/24 09:53 106-93-40.50 1
Dibromomethane ND ug/L 03/21/24 09:53 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 03/21/24 09:53 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 03/21/24 09:53 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 03/21/24 09:53 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 03/21/24 09:53 75-71-80.50 1
1,1-Dichloroethane ND ug/L 03/21/24 09:53 75-34-30.50 1
1,2-Dichloroethane ND ug/L 03/21/24 09:53 107-06-20.50 1
1,1-Dichloroethene ND ug/L 03/21/24 09:53 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 03/21/24 09:53 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 03/21/24 09:53 156-60-50.50 1
1,2-Dichloropropane ND ug/L 03/21/24 09:53 78-87-50.50 1
1,3-Dichloropropane ND ug/L 03/21/24 09:53 142-28-90.50 1
2,2-Dichloropropane ND ug/L 03/21/24 09:53 594-20-70.50 1
1,1-Dichloropropene ND ug/L 03/21/24 09:53 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 03/21/24 09:53 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 03/21/24 09:53 10061-02-60.50 1
Diisopropyl ether ND ug/L 03/21/24 09:53 108-20-30.50 1
Ethanol ND ug/L 03/21/24 09:53 64-17-52001
Ethylbenzene ND ug/L 03/21/24 09:53 100-41-40.50 1
Ethyl-tert-butyl ether ND ug/L 03/21/24 09:53 637-92-310.0 1
Hexachloro-1,3-butadiene ND ug/L 03/21/24 09:53 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 03/21/24 09:53 98-82-80.50 1
Methylene Chloride ND ug/L 03/21/24 09:53 75-09-22.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/26/2024 10:58 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92720084
JIM'S GROCERY
Sample:MW-3 Lab ID:92720084004 Collected:03/19/24 13:00 Received:03/20/24 08:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methyl-tert-butyl ether ND ug/L 03/21/24 09:53 1634-04-40.50 1
Naphthalene ND ug/L 03/21/24 09:53 91-20-32.0 1
n-Propylbenzene ND ug/L 03/21/24 09:53 103-65-10.50 1
Styrene ND ug/L 03/21/24 09:53 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 03/21/24 09:53 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 03/21/24 09:53 79-34-50.50 1
Tetrachloroethene ND ug/L 03/21/24 09:53 127-18-40.50 1
Toluene ND ug/L 03/21/24 09:53 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 03/21/24 09:53 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 03/21/24 09:53 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 03/21/24 09:53 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 03/21/24 09:53 79-00-50.50 1
Trichloroethene ND ug/L 03/21/24 09:53 79-01-60.50 1
Trichlorofluoromethane ND ug/L 03/21/24 09:53 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 03/21/24 09:53 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 03/21/24 09:53 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 03/21/24 09:53 108-67-80.50 1
Vinyl chloride ND ug/L 03/21/24 09:53 75-01-41.0 1
m&p-Xylene ND ug/L 03/21/24 09:53 179601-23-11.0 1
o-Xylene ND ug/L 03/21/24 09:53 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)81 %03/21/24 09:53 17060-07-070-130 1
4-Bromofluorobenzene (S)92 %03/21/24 09:53 460-00-470-130 1
Toluene-d8 (S)96 %03/21/24 09:53 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/26/2024 10:58 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92720084
JIM'S GROCERY
Sample:MW-4 Lab ID:92720084005 Collected:03/19/24 13:00 Received:03/20/24 08:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol ND ug/L 03/21/24 10:12 75-85-41001
tert-Amylmethyl ether ND ug/L 03/21/24 10:12 994-05-810.0 1
Benzene ND ug/L 03/21/24 10:12 71-43-20.50 1
Bromobenzene ND ug/L 03/21/24 10:12 108-86-10.50 1
Bromochloromethane ND ug/L 03/21/24 10:12 74-97-50.50 1
Bromodichloromethane ND ug/L 03/21/24 10:12 75-27-40.50 1
Bromoform ND ug/L 03/21/24 10:12 75-25-20.50 1
Bromomethane ND ug/L 03/21/24 10:12 74-83-95.0 1
tert-Butyl Alcohol ND ug/L 03/21/24 10:12 75-65-050.0 1
n-Butylbenzene ND ug/L 03/21/24 10:12 104-51-80.50 1
sec-Butylbenzene ND ug/L 03/21/24 10:12 135-98-80.50 1
tert-Butylbenzene ND ug/L 03/21/24 10:12 98-06-60.50 1
tert-Butyl Formate ND ug/L 03/21/24 10:12 762-75-450.0 1
Carbon tetrachloride ND ug/L 03/21/24 10:12 56-23-50.50 1
Chlorobenzene ND ug/L 03/21/24 10:12 108-90-70.50 1
Chloroethane ND ug/L 03/21/24 10:12 75-00-31.0 1
Chloroform ND ug/L 03/21/24 10:12 67-66-30.50 1
Chloromethane ND ug/L 03/21/24 10:12 74-87-31.0 1
2-Chlorotoluene ND ug/L 03/21/24 10:12 95-49-80.50 1
4-Chlorotoluene ND ug/L 03/21/24 10:12 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 03/21/24 10:12 96-12-81.0 1
Dibromochloromethane ND ug/L 03/21/24 10:12 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 03/21/24 10:12 106-93-40.50 1
Dibromomethane ND ug/L 03/21/24 10:12 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 03/21/24 10:12 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 03/21/24 10:12 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 03/21/24 10:12 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 03/21/24 10:12 75-71-80.50 1
1,1-Dichloroethane ND ug/L 03/21/24 10:12 75-34-30.50 1
1,2-Dichloroethane ND ug/L 03/21/24 10:12 107-06-20.50 1
1,1-Dichloroethene ND ug/L 03/21/24 10:12 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 03/21/24 10:12 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 03/21/24 10:12 156-60-50.50 1
1,2-Dichloropropane ND ug/L 03/21/24 10:12 78-87-50.50 1
1,3-Dichloropropane ND ug/L 03/21/24 10:12 142-28-90.50 1
2,2-Dichloropropane ND ug/L 03/21/24 10:12 594-20-70.50 1
1,1-Dichloropropene ND ug/L 03/21/24 10:12 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 03/21/24 10:12 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 03/21/24 10:12 10061-02-60.50 1
Diisopropyl ether ND ug/L 03/21/24 10:12 108-20-30.50 1
Ethanol ND ug/L 03/21/24 10:12 64-17-52001
Ethylbenzene ND ug/L 03/21/24 10:12 100-41-40.50 1
Ethyl-tert-butyl ether ND ug/L 03/21/24 10:12 637-92-310.0 1
Hexachloro-1,3-butadiene ND ug/L 03/21/24 10:12 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 03/21/24 10:12 98-82-80.50 1
Methylene Chloride ND ug/L 03/21/24 10:12 75-09-22.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/26/2024 10:58 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92720084
JIM'S GROCERY
Sample:MW-4 Lab ID:92720084005 Collected:03/19/24 13:00 Received:03/20/24 08:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methyl-tert-butyl ether ND ug/L 03/21/24 10:12 1634-04-40.50 1
Naphthalene ND ug/L 03/21/24 10:12 91-20-32.0 1
n-Propylbenzene ND ug/L 03/21/24 10:12 103-65-10.50 1
Styrene ND ug/L 03/21/24 10:12 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 03/21/24 10:12 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 03/21/24 10:12 79-34-50.50 1
Tetrachloroethene ND ug/L 03/21/24 10:12 127-18-40.50 1
Toluene ND ug/L 03/21/24 10:12 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 03/21/24 10:12 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 03/21/24 10:12 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 03/21/24 10:12 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 03/21/24 10:12 79-00-50.50 1
Trichloroethene ND ug/L 03/21/24 10:12 79-01-60.50 1
Trichlorofluoromethane ND ug/L 03/21/24 10:12 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 03/21/24 10:12 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 03/21/24 10:12 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 03/21/24 10:12 108-67-80.50 1
Vinyl chloride ND ug/L 03/21/24 10:12 75-01-41.0 1
m&p-Xylene ND ug/L 03/21/24 10:12 179601-23-11.0 1
o-Xylene ND ug/L 03/21/24 10:12 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)82 %03/21/24 10:12 17060-07-070-130 1
4-Bromofluorobenzene (S)92 %03/21/24 10:12 460-00-470-130 1
Toluene-d8 (S)98 %03/21/24 10:12 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/26/2024 10:58 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92720084
JIM'S GROCERY
Sample:VMW-1 Lab ID:92720084006 Collected:03/19/24 13:00 Received:03/20/24 08:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol ND ug/L 03/21/24 10:30 75-85-41001
tert-Amylmethyl ether ND ug/L 03/21/24 10:30 994-05-810.0 1
Benzene ND ug/L 03/21/24 10:30 71-43-20.50 1
Bromobenzene ND ug/L 03/21/24 10:30 108-86-10.50 1
Bromochloromethane ND ug/L 03/21/24 10:30 74-97-50.50 1
Bromodichloromethane ND ug/L 03/21/24 10:30 75-27-40.50 1
Bromoform ND ug/L 03/21/24 10:30 75-25-20.50 1
Bromomethane ND ug/L 03/21/24 10:30 74-83-95.0 1
tert-Butyl Alcohol ND ug/L 03/21/24 10:30 75-65-050.0 1
n-Butylbenzene ND ug/L 03/21/24 10:30 104-51-80.50 1
sec-Butylbenzene ND ug/L 03/21/24 10:30 135-98-80.50 1
tert-Butylbenzene ND ug/L 03/21/24 10:30 98-06-60.50 1
tert-Butyl Formate ND ug/L 03/21/24 10:30 762-75-450.0 1
Carbon tetrachloride ND ug/L 03/21/24 10:30 56-23-50.50 1
Chlorobenzene ND ug/L 03/21/24 10:30 108-90-70.50 1
Chloroethane ND ug/L 03/21/24 10:30 75-00-31.0 1
Chloroform ND ug/L 03/21/24 10:30 67-66-30.50 1
Chloromethane ND ug/L 03/21/24 10:30 74-87-31.0 1
2-Chlorotoluene ND ug/L 03/21/24 10:30 95-49-80.50 1
4-Chlorotoluene ND ug/L 03/21/24 10:30 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 03/21/24 10:30 96-12-81.0 1
Dibromochloromethane ND ug/L 03/21/24 10:30 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 03/21/24 10:30 106-93-40.50 1
Dibromomethane ND ug/L 03/21/24 10:30 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 03/21/24 10:30 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 03/21/24 10:30 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 03/21/24 10:30 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 03/21/24 10:30 75-71-80.50 1
1,1-Dichloroethane ND ug/L 03/21/24 10:30 75-34-30.50 1
1,2-Dichloroethane ND ug/L 03/21/24 10:30 107-06-20.50 1
1,1-Dichloroethene ND ug/L 03/21/24 10:30 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 03/21/24 10:30 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 03/21/24 10:30 156-60-50.50 1
1,2-Dichloropropane ND ug/L 03/21/24 10:30 78-87-50.50 1
1,3-Dichloropropane ND ug/L 03/21/24 10:30 142-28-90.50 1
2,2-Dichloropropane ND ug/L 03/21/24 10:30 594-20-70.50 1
1,1-Dichloropropene ND ug/L 03/21/24 10:30 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 03/21/24 10:30 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 03/21/24 10:30 10061-02-60.50 1
Diisopropyl ether ND ug/L 03/21/24 10:30 108-20-30.50 1
Ethanol ND ug/L 03/21/24 10:30 64-17-52001
Ethylbenzene ND ug/L 03/21/24 10:30 100-41-40.50 1
Ethyl-tert-butyl ether ND ug/L 03/21/24 10:30 637-92-310.0 1
Hexachloro-1,3-butadiene ND ug/L 03/21/24 10:30 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 03/21/24 10:30 98-82-80.50 1
Methylene Chloride ND ug/L 03/21/24 10:30 75-09-22.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/26/2024 10:58 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92720084
JIM'S GROCERY
Sample:VMW-1 Lab ID:92720084006 Collected:03/19/24 13:00 Received:03/20/24 08:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methyl-tert-butyl ether ND ug/L 03/21/24 10:30 1634-04-40.50 1
Naphthalene ND ug/L 03/21/24 10:30 91-20-32.0 1
n-Propylbenzene ND ug/L 03/21/24 10:30 103-65-10.50 1
Styrene ND ug/L 03/21/24 10:30 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 03/21/24 10:30 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 03/21/24 10:30 79-34-50.50 1
Tetrachloroethene ND ug/L 03/21/24 10:30 127-18-40.50 1
Toluene ND ug/L 03/21/24 10:30 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 03/21/24 10:30 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 03/21/24 10:30 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 03/21/24 10:30 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 03/21/24 10:30 79-00-50.50 1
Trichloroethene ND ug/L 03/21/24 10:30 79-01-60.50 1
Trichlorofluoromethane ND ug/L 03/21/24 10:30 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 03/21/24 10:30 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 03/21/24 10:30 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 03/21/24 10:30 108-67-80.50 1
Vinyl chloride ND ug/L 03/21/24 10:30 75-01-41.0 1
m&p-Xylene ND ug/L 03/21/24 10:30 179601-23-11.0 1
o-Xylene ND ug/L 03/21/24 10:30 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)81 %03/21/24 10:30 17060-07-070-130 1
4-Bromofluorobenzene (S)92 %03/21/24 10:30 460-00-470-130 1
Toluene-d8 (S)99 %03/21/24 10:30 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/26/2024 10:58 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92720084
JIM'S GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
840534
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92720084001, 92720084002, 92720084003, 92720084004, 92720084005, 92720084006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4341560
Associated Lab Samples:92720084001, 92720084002, 92720084003, 92720084004, 92720084005, 92720084006
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 03/21/24 02:20
1,1,1-Trichloroethane ug/L ND 0.50 03/21/24 02:20
1,1,2,2-Tetrachloroethane ug/L ND 0.50 03/21/24 02:20
1,1,2-Trichloroethane ug/L ND 0.50 03/21/24 02:20
1,1-Dichloroethane ug/L ND 0.50 03/21/24 02:20
1,1-Dichloroethene ug/L ND 0.50 03/21/24 02:20
1,1-Dichloropropene ug/L ND 0.50 03/21/24 02:20
1,2,3-Trichlorobenzene ug/L ND 2.0 03/21/24 02:20
1,2,3-Trichloropropane ug/L ND 0.50 03/21/24 02:20
1,2,4-Trichlorobenzene ug/L ND 2.0 03/21/24 02:20
1,2,4-Trimethylbenzene ug/L ND 0.50 03/21/24 02:20
1,2-Dibromo-3-chloropropane ug/L ND 1.0 03/21/24 02:20
1,2-Dibromoethane (EDB)ug/L ND 0.50 03/21/24 02:20
1,2-Dichlorobenzene ug/L ND 0.50 03/21/24 02:20
1,2-Dichloroethane ug/L ND 0.50 03/21/24 02:20
1,2-Dichloropropane ug/L ND 0.50 03/21/24 02:20
1,3,5-Trimethylbenzene ug/L ND 0.50 03/21/24 02:20
1,3-Dichlorobenzene ug/L ND 0.50 03/21/24 02:20
1,3-Dichloropropane ug/L ND 0.50 03/21/24 02:20
1,4-Dichlorobenzene ug/L ND 0.50 03/21/24 02:20
2,2-Dichloropropane ug/L ND 0.50 03/21/24 02:20
2-Chlorotoluene ug/L ND 0.50 03/21/24 02:20
4-Chlorotoluene ug/L ND 0.50 03/21/24 02:20
Benzene ug/L ND 0.50 03/21/24 02:20
Bromobenzene ug/L ND 0.50 03/21/24 02:20
Bromochloromethane ug/L ND 0.50 03/21/24 02:20
Bromodichloromethane ug/L ND 0.50 03/21/24 02:20
Bromoform ug/L ND 0.50 03/21/24 02:20
Bromomethane ug/L ND 5.0 03/21/24 02:20
Carbon tetrachloride ug/L ND 0.50 03/21/24 02:20
Chlorobenzene ug/L ND 0.50 03/21/24 02:20
Chloroethane ug/L ND 1.0 03/21/24 02:20
Chloroform ug/L ND 0.50 03/21/24 02:20
Chloromethane ug/L ND 1.0 03/21/24 02:20
cis-1,2-Dichloroethene ug/L ND 0.50 03/21/24 02:20
cis-1,3-Dichloropropene ug/L ND 0.50 03/21/24 02:20
Dibromochloromethane ug/L ND 0.50 03/21/24 02:20
Dibromomethane ug/L ND 0.50 03/21/24 02:20
Dichlorodifluoromethane ug/L ND 0.50 03/21/24 02:20
Diisopropyl ether ug/L ND 0.50 03/21/24 02:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/26/2024 10:58 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92720084
JIM'S GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4341560
Associated Lab Samples:92720084001, 92720084002, 92720084003, 92720084004, 92720084005, 92720084006
Matrix:Water
Analyzed
Ethanol ug/L ND 200 03/21/24 02:20
Ethyl-tert-butyl ether ug/L ND 10.0 03/21/24 02:20
Ethylbenzene ug/L ND 0.50 03/21/24 02:20
Hexachloro-1,3-butadiene ug/L ND 2.0 03/21/24 02:20
Isopropylbenzene (Cumene)ug/L ND 0.50 03/21/24 02:20
m&p-Xylene ug/L ND 1.0 03/21/24 02:20
Methyl-tert-butyl ether ug/L ND 0.50 03/21/24 02:20
Methylene Chloride ug/L ND 2.0 03/21/24 02:20
n-Butylbenzene ug/L ND 0.50 03/21/24 02:20
n-Propylbenzene ug/L ND 0.50 03/21/24 02:20
Naphthalene ug/L ND 2.0 03/21/24 02:20
o-Xylene ug/L ND 0.50 03/21/24 02:20
sec-Butylbenzene ug/L ND 0.50 03/21/24 02:20
Styrene ug/L ND 0.50 03/21/24 02:20
tert-Amyl Alcohol ug/L ND 100 03/21/24 02:20
tert-Amylmethyl ether ug/L ND 10.0 03/21/24 02:20
tert-Butyl Alcohol ug/L ND 50.0 03/21/24 02:20
tert-Butyl Formate ug/L ND 50.0 03/21/24 02:20
tert-Butylbenzene ug/L ND 0.50 03/21/24 02:20
Tetrachloroethene ug/L ND 0.50 03/21/24 02:20
Toluene ug/L ND 0.50 03/21/24 02:20
trans-1,2-Dichloroethene ug/L ND 0.50 03/21/24 02:20
trans-1,3-Dichloropropene ug/L ND 0.50 03/21/24 02:20
Trichloroethene ug/L ND 0.50 03/21/24 02:20
Trichlorofluoromethane ug/L ND 1.0 03/21/24 02:20
Vinyl chloride ug/L ND 1.0 03/21/24 02:20
1,2-Dichloroethane-d4 (S)%84 70-130 03/21/24 02:20
4-Bromofluorobenzene (S)%94 70-130 03/21/24 02:20
Toluene-d8 (S)%98 70-130 03/21/24 02:20
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4341561LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 22.320 112 60-140
1,1,1-Trichloroethane ug/L 20.620 103 60-140
1,1,2,2-Tetrachloroethane ug/L 19.820 99 60-140
1,1,2-Trichloroethane ug/L 21.320 107 60-140
1,1-Dichloroethane ug/L 19.320 96 60-140
1,1-Dichloroethene ug/L 18.520 93 60-140
1,1-Dichloropropene ug/L 19.020 95 60-140
1,2,3-Trichlorobenzene ug/L 20.620 103 60-140
1,2,3-Trichloropropane ug/L 19.620 98 60-140
1,2,4-Trichlorobenzene ug/L 20.820 104 60-140
1,2,4-Trimethylbenzene ug/L 20.520 102 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/26/2024 10:58 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92720084
JIM'S GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4341561LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dibromo-3-chloropropane ug/L 19.920 100 60-140
1,2-Dibromoethane (EDB)ug/L 21.920 110 60-140
1,2-Dichlorobenzene ug/L 21.520 107 60-140
1,2-Dichloroethane ug/L 18.420 92 60-140
1,2-Dichloropropane ug/L 20.220 101 60-140
1,3,5-Trimethylbenzene ug/L 20.420 102 60-140
1,3-Dichlorobenzene ug/L 21.520 108 60-140
1,3-Dichloropropane ug/L 20.020 100 60-140
1,4-Dichlorobenzene ug/L 21.020 105 60-140
2,2-Dichloropropane ug/L 19.220 96 60-140
2-Chlorotoluene ug/L 20.020 100 60-140
4-Chlorotoluene ug/L 19.920 99 60-140
Benzene ug/L 20.720 103 60-140
Bromobenzene ug/L 21.320 106 60-140
Bromochloromethane ug/L 20.020 100 60-140
Bromodichloromethane ug/L 20.620 103 60-140
Bromoform ug/L 19.920 100 60-140
Bromomethane ug/L 20.020 100 60-140
Carbon tetrachloride ug/L 21.920 109 60-140
Chlorobenzene ug/L 21.020 105 60-140
Chloroethane ug/L 20.520 103 60-140
Chloroform ug/L 19.920 99 60-140
Chloromethane ug/L 19.020 95 60-140
cis-1,2-Dichloroethene ug/L 18.720 94 60-140
cis-1,3-Dichloropropene ug/L 21.120 105 60-140
Dibromochloromethane ug/L 18.720 94 60-140
Dibromomethane ug/L 21.520 107 60-140
Dichlorodifluoromethane ug/L 23.020 115 60-140
Diisopropyl ether ug/L 17.120 86 60-140
Ethanol ug/L 668800 83 60-140
Ethyl-tert-butyl ether ug/L 35.540 89 60-140
Ethylbenzene ug/L 20.720 104 60-140
Hexachloro-1,3-butadiene ug/L 22.520 113 60-140
Isopropylbenzene (Cumene)ug/L 21.120 106 60-140
m&p-Xylene ug/L 41.140 103 60-140
Methyl-tert-butyl ether ug/L 17.820 89 60-140
Methylene Chloride ug/L 17.220 86 60-140
n-Butylbenzene ug/L 19.320 97 60-140
n-Propylbenzene ug/L 20.020 100 60-140
Naphthalene ug/L 20.320 101 60-140
o-Xylene ug/L 21.520 107 60-140
sec-Butylbenzene ug/L 20.420 102 60-140
Styrene ug/L 22.020 110 60-140
tert-Amyl Alcohol ug/L 357400 89 60-140
tert-Amylmethyl ether ug/L 37.740 94 60-140
tert-Butyl Alcohol ug/L 171200 86 60-140
tert-Butyl Formate ug/L 155160 97 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/26/2024 10:58 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92720084
JIM'S GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4341561LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butylbenzene ug/L 17.620 88 60-140
Tetrachloroethene ug/L 21.220 106 60-140
Toluene ug/L 20.820 104 60-140
trans-1,2-Dichloroethene ug/L 18.920 95 60-140
trans-1,3-Dichloropropene ug/L 17.620 88 60-140
Trichloroethene ug/L 23.020 115 60-140
Trichlorofluoromethane ug/L 20.420 102 60-140
Vinyl chloride ug/L 20.220 101 60-140
1,2-Dichloroethane-d4 (S)%83 70-130
4-Bromofluorobenzene (S)%96 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4341562MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92719614008
4341563
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 116 60-140118 220<0.091 23.2 23.7
1,1,1-Trichloroethane ug/L 20 120 60-140121 120<0.11 24.0 24.2
1,1,2,2-Tetrachloroethane ug/L 20 111 60-140112 120<0.074 22.2 22.4
1,1,2-Trichloroethane ug/L 20 113 60-140116 220<0.096 22.7 23.2
1,1-Dichloroethane ug/L 20 120 60-140120 020<0.056 24.1 24.1
1,1-Dichloroethene ug/L 20 128 60-140127 020<0.079 25.5 25.4
1,1-Dichloropropene ug/L 20 122 60-140124 220<0.066 24.4 24.8
1,2,3-Trichlorobenzene ug/L 20 108 60-140108 020<0.12 21.6 21.7
1,2,3-Trichloropropane ug/L 20 114 60-140117 320<0.17 22.7 23.4
1,2,4-Trichlorobenzene ug/L 20 105 60-140108 220<0.16 21.1 21.6
1,2,4-Trimethylbenzene ug/L 20 113 60-140115 220<0.031 22.5 23.0
1,2-Dibromo-3-chloropropane ug/L 20 103 60-140109 520<0.18 20.7 21.8
1,2-Dibromoethane (EDB)ug/L 20 114 60-140113 020<0.15 22.7 22.7
1,2-Dichlorobenzene ug/L 20 116 60-140120 320<0.094 23.3 23.9
1,2-Dichloroethane ug/L 20 115 60-140115 120<0.11 22.9 23.1
1,2-Dichloropropane ug/L 20 124 60-140123 120<0.14 24.9 24.6
1,3,5-Trimethylbenzene ug/L 20 116 60-140118 1200.13J 23.4 23.6
1,3-Dichlorobenzene ug/L 20 119 60-140119 020<0.098 23.8 23.8
1,3-Dichloropropane ug/L 20 116 60-140118 220<0.085 23.1 23.7
1,4-Dichlorobenzene ug/L 20 119 60-140119 020<0.090 23.7 23.8
2,2-Dichloropropane ug/L 20 118 60-140119 120<0.12 23.5 23.8
2-Chlorotoluene ug/L 20 120 60-140119 120<0.13 23.9 23.8
4-Chlorotoluene ug/L 20 122 60-140122 020<0.096 24.4 24.4
Benzene ug/L 20 126 60-140125 020<0.079 25.2 25.0
Bromobenzene ug/L 20 116 60-140118 220<0.14 23.2 23.7
Bromochloromethane ug/L 20 118 60-140121 220<0.094 23.6 24.2
Bromodichloromethane ug/L 20 119 60-140119 020<0.17 23.7 23.8
Bromoform ug/L 20 106 60-140108 220<0.20 21.3 21.7
Bromomethane ug/L 20 107 60-140111 420<0.22 21.4 22.3
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/26/2024 10:58 AM
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Page 19 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92720084
JIM'S GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4341562MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92719614008
4341563
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Carbon tetrachloride ug/L 20 126 60-140121 420<0.17 25.3 24.2
Chlorobenzene ug/L 20 119 60-140121 220<0.085 23.7 24.1
Chloroethane ug/L 20 135 60-140134 120<0.17 27.0 26.8
Chloroform ug/L 20 115 60-140118 220<0.069 23.1 23.6
Chloromethane ug/L 20 119 60-140117 120<0.18 23.7 23.4
cis-1,2-Dichloroethene ug/L 20 115 60-140116 120<0.11 22.9 23.2
cis-1,3-Dichloropropene ug/L 20 112 60-140113 120<0.090 22.5 22.6
Dibromochloromethane ug/L 20 115 60-140115 020<0.15 23.0 23.0
Dibromomethane ug/L 20 118 60-140120 120<0.19 23.6 23.9
Dichlorodifluoromethane ug/L 20 105 60-140106 120<0.12 21.1 21.2
Diisopropyl ether ug/L 20 107 60-140109 2200.35J 21.7 22.1
Ethanol ug/L 800 101 60-140105 4800<5.0 809 843
Ethyl-tert-butyl ether ug/L 40 101 60-140104 340<0.11 40.4 41.5
Ethylbenzene ug/L 20 120 60-140121 120<0.081 24.0 24.2
Hexachloro-1,3-butadiene ug/L 20 115 60-140119 320<0.35 23.0 23.7
Isopropylbenzene (Cumene)ug/L 20 119 60-140121 120<0.11 23.9 24.1
m&p-Xylene ug/L 40 121 60-140121 140<0.094 48.2 48.5
Methyl-tert-butyl ether ug/L 20 101 60-140104 320<0.053 20.2 20.8
Methylene Chloride ug/L 20 112 60-140112 120<1.9 22.3 22.5
n-Butylbenzene ug/L 20 118 60-140117 020<0.066 23.5 23.5
n-Propylbenzene ug/L 20 121 60-140122 120<0.10 24.2 24.5
Naphthalene ug/L 20 108 60-140110 220<0.10 21.6 22.1
o-Xylene ug/L 20 117 60-140118 120<0.14 23.4 23.6
sec-Butylbenzene ug/L 20 122 60-140122 120<0.085 24.3 24.5
Styrene ug/L 20 118 60-140119 120<0.14 23.5 23.9
tert-Amyl Alcohol ug/L 400 91 60-140100 9400<7.4 364 398
tert-Amylmethyl ether ug/L 40 101 60-140102 140<0.12 40.4 40.9
tert-Butyl Alcohol ug/L 200 102 60-140110 72007.7J 212 229
tert-Butyl Formate ug/L P5160860-1407160<0.30 12.3J 11J
tert-Butylbenzene ug/L 20 101 60-140103 120<0.086 20.3 20.5
Tetrachloroethene ug/L 20 118 60-140118 020<0.086 23.7 23.6
Toluene ug/L 20 120 60-140120 020<0.090 24.0 23.9
trans-1,2-Dichloroethene ug/L 20 122 60-140121 120<0.10 24.5 24.3
trans-1,3-Dichloropropene ug/L 20 112 60-140113 120<0.13 22.4 22.6
Trichloroethene ug/L 20 131 60-140128 220<0.17 26.2 25.7
Trichlorofluoromethane ug/L 20 130 60-140131 120<0.14 26.0 26.2
Vinyl chloride ug/L 20 135 60-140134 020<0.15 26.9 26.9
1,2-Dichloroethane-d4 (S)%99 70-13096
4-Bromofluorobenzene (S)%97 70-13098
Toluene-d8 (S)%99 70-13099
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/26/2024 10:58 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 25
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92720084
JIM'S GROCERY
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
The EPA or method required sample preservation degrades this compound, therefore acceptable recoveries may not be
achieved in sample matrix spikes.P5
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/26/2024 10:58 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 25
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92720084
JIM'S GROCERY
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92720084001 840534WSW-1 SM 6200B
92720084002 840534MW-1 SM 6200B
92720084003 840534MW-2 SM 6200B
92720084004 840534MW-3 SM 6200B
92720084005 840534MW-4 SM 6200B
92720084006 840534VMW-1 SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/26/2024 10:58 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 25
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