HomeMy WebLinkAboutMO-5325_18450_CA_CAPR_20240405_Monitoring Report
Via Email April 5, 2024
North Carolina Department of Environmental Quality
Mooresville Regional Office 610 East Center Ave. Mooresville, NC 28115
Attention: Mr. Brad Newton
Re: Monitoring Report General Store of Denver Sherrils Ford, North Carolina
NCDENR Incident No. 18450
H&H Project No. GSD-050 Dear Mr. Newton:
Please find attached a Monitoring Report for the General Store of Denver. Please feel free to
contact me with any questions and/or comments.
Sincerely,
Hart & Hickman, PC
Stephen R. Libbey, PG
Project Manager Attachments
Monitoring Report
General Store of Denver
6360 NC Highway 150 East
Sherrills Ford, North Carolina
DEQ Incident Number: 18450 H&H Job No. GSD-050
April 5, 2024
#C-1269 Engineering
#245 Geology
Title Page
Site Information:
General Store of Denver 6360 NC Highway 150 East Sherrills Ford, NC 28673 Facility ID Number: 0-002395
NC DEQ Incident Number: 18450
Latitude/Longitude: N35°34’20” W81°02’28” Risk Classification: High Risk H596E – Water Supply Wells within 1,000 ft
Land Use: Residential UST Owner & Operator:
General Store of Denver, Inc.
6360 NC Highway 150 East Sherrills Ford, NC 28673 Attn: Frank Craven (704) 483-2686
Property Owner: FMC Properties, LLC 6360 NC Highway 150 East Sherrills Ford, NC 28673
(704) 483-2686 Consultant: Hart & Hickman, PC 2923 South Tryon Street, Suite 100
Charlotte, NC 28203
Attn: Mr. Stephen Libbey, PG and Matt Bramblett, PE (704) 586-0007 Release Information:
Release Discovery Date: March 1998
Estimated Quantity of Release: Unknown Cause/Source of Release: Suspected to be kerosene and gasoline UST systems Laboratory:
Pace Analytical Services, Inc., NC Certification Nos. 12/37706
Waypoint Analytical, NC Certification Nos. 402/37735
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Monitoring Report General Store of Denver
Sherrills Ford, North Carolina H&H Job No. GSD-050
Table of Contents
Section Page No.
1.0 Introduction .............................................................................................................................1
2.0 Site History ..............................................................................................................................2
3.0 Groundwater Sampling ..........................................................................................................4
3.1 Water Levels .........................................................................................................................4
3.2 Monitoring Well Sampling ...................................................................................................4
4.0 Water Supply Well Sampling ................................................................................................5
5.0 Remediation System................................................................................................................6
5.1 General Description ..............................................................................................................6
5.2 Groundwater Recovery .........................................................................................................6
5.3 Groundwater Treatment ........................................................................................................7
5.4 Operating Status ....................................................................................................................8
5.5 Groundwater Treatment System Sampling ...........................................................................8
5.6 Cleanup Progress Milestones ................................................................................................9
6.0 Conclusions and Recommendations ....................................................................................12
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List of Tables
Table 1 Water Supply Well Inventory
Table 2 Monitoring Well Water Level Data
Table 3 Monitoring Well Groundwater Analytical Detections
Table 4 Summary of Water Supply Well Sample Results
Table 5 Summary of Influent and Effluent Sample Results
Table 6 Summary of Mass Removal – Groundwater Remediation System
Table 7 Evaluation of Change in Contaminant Mass
List of Figures
Figure 1 Site Location Map
Figure 2 Site Layout
Figure 3 Water Supply Well Survey Map
Figure 4 Deep Well Groundwater Elevations (August 2023)
Figure 5 Benzene and MTBE Concentrations in Groundwater (February 2024)
Figure 6 Treatment System Schematic
Figure 7 Estimated Extent of Benzene and MTBE Groundwater Impacts Prior to
Remediation
Figure 8 Estimated Extent of Current Benzene and MTBE Groundwater Impacts
List of Appendices
Appendix A Laboratory Analytical Reports and Chain-of-Custody Forms
Appendix B Concentrations versus Time Graph (MW-3D, MW-5D, and Influent)
Appendix C Evaluation of Change in Contaminant Mass Calculations
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Monitoring Report General Store of Denver
Sherrills Ford, North Carolina H&H Job No. GSD-050
1.0 Introduction
On behalf of FMC Properties, LLC, Hart & Hickman, PC (H&H) has completed a Monitoring
Report for the General Store of Denver (GSD) facility located at 6360 NC Highway 150 East in
Sherrills Ford, Catawba County, North Carolina. The GSD facility is a grocery and retail
petroleum distribution facility. A hardware store is also located at the site. The North Carolina
Department of Environmental Quality (DEQ) groundwater incident number is 18450, and DEQ
has assigned the site a high-risk classification due to the presence of nearby water supply wells.
A site location map is included as Figure 1, and a site map is included as Figure 2.
During the current six-month reporting period, H&H operated the pump and treat system
between September 2023 and December 2023. As recommended in the December 2023
Corrective Action Performance Report (CAPR) that DEQ approved in a subsequent
Acknowledgment of Receipt letter dated December 20, 2023, the treatment system was shut
down on December 29, 2023. Monitored Natural Attenuation (MNA) closure sampling was
initiated at that time.
This report documents the performance of the remediation system operation and maintenance
(O&M) activities for the period of September 2023 through December 2023 and the first semi-
annual MNA closure sampling event conducted in February 2024.
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2.0 Site History
A kerosene UST was removed from the site in March 1998 and impacted soil was detected. Two
other surface releases of petroleum also are documented at the site. At the time of assessment
and corrective action planning, municipal water was not available. However, a waterline has
since been installed adjacent to the site, and municipal water is available in the vicinity of the
site.
Assessment conducted at the site since 1998 indicated on-site groundwater is impacted with
benzene and MTBE at levels above the North Carolina groundwater standards but below DEQ-
defined Gross Contamination Level (GCLs). The impacted groundwater is primarily detected
within the fractured bedrock underlying the site. Additionally, benzene and MTBE were
historically detected in six off-site water supply wells. The impacted wells are oriented along a
north-northeast trend coincident with the dominant fracture trend in the area. The furthest
historically impacted water supply well from the site is located approximately 1,500 ft from the
source area.
A Corrective Action Plan (CAP) was submitted to DEQ on November 27, 2002 recommending
active remediation of the soil by vapor extraction coupled with a groundwater remedy involving
lowering the site risk by means of alternate water supply. DEQ requested that an aquifer test be
conducted and requested additional information regarding potential implementation of active
remediation using groundwater pump and treat. An addendum with the supplemental
information was submitted to DEQ on May 5, 2003 and approved in a Notice of Regulatory
Requirement (NORR) dated May 19, 2003. Soil remediation by vapor extraction was not
approved by DEQ.
Design and other tasks required to implement the remedial option began immediately. However,
the installation and operation of the treatment system was delayed due to requirements for the
National Pollutant Discharge Elimination System (NPDES) discharge permit and required access
agreement from the North Carolina Department of Transportation for discharge to a dry
stormwater conveyance swale located north and adjacent to the site. The installation of the
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groundwater recovery and treatment system was completed in August 2004, and system
operation commenced on August 13, 2004. The groundwater recovery and treatment system
operated until July 29, 2005 at which time the system was deactivated per DEQ’s July 2005
NORR indicating the work at the site was no longer directed.
Municipal water was extended to the site in late 2004 and early 2005. At DEQ’s request, H&H
conducted a limited water supply well survey in June 2005 to determine the status of municipal
water connections at that time. Based partially on the data in the well survey, on July 15, 2005
DEQ issued a NORR indicating the site did not meet the requirements for further assessment or
corrective action. Therefore, the system was shut down pending further direction from DEQ.
DEQ issued another NORR on January 26, 2006, indicating the site was of sufficiently high
priority to allow funding by the State Trust Fund Program and that work indicated in the NORR
dated May 19, 2003 was directed to proceed.
H&H completed a water supply well survey update for the area within a 1,500-ft radius of the
former UST basin in 2020. H&H identified the presence of 29 water supply wells within 1,500
ft of the UST basin (Figure 3). Of these 29 water supply wells, 18 are used for drinking water
and one is used for non-drinking water purposes only. The remaining 10 water supply wells are
not active. Municipal water is provided to the site and is available to properties within a 1,500-ft
radius of the site. Water supply well owner information is presented in Table 1.
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3.0 Groundwater Sampling
3.1 Water Levels
The first semi-annual MNA closure sampling event was conducted on February 6, 2024. During
the event, H&H inadvertently neglected to collect water levels in the site wells. Water levels
will be collected from site wells during the next semi-annual sampling event. Historical water
level measurements are summarized on Table 2. A potentiometric map based on data collected
from the deep wells in September 2023, along with knowledge of prior data, is presented as
Figure 4. Historical potentiometric data indicate that groundwater flow at the site is generally to
the northeast.
3.2 Monitoring Well Sampling
Deep recovery wells MW-3D and MW-5D were sampled on February 6, 2024. Groundwater
samples were poured in laboratory supplied containers, marked with identifying labels, and
placed in an iced cooler for shipment under chain-of-custody to a certified laboratory for
analyses. Groundwater samples were analyzed for volatile organic compounds (VOCs)
including methyl tertiary butyl ether (MTBE), isopropyl ether (IPE), and xylenes by EPA
Method 6200B (Table 3). The laboratory analytical reports are provided in Appendix A.
During the February 2024 sampling event, benzene was not detected above the laboratory
detection limit and MTBE (616 µg/l) was detected at a concentration above the North Carolina
Administrative Code, Subchapter 2L Groundwater Standards (2L Standard) in MW-3D. The
detected MTBE concentration was not above the GCL. Additionally, benzene and MTBE were
not detected above the laboratory detection limits in monitoring well MW-5D. A graph showing
the benzene and MTBE concentrations with time for MW-3D, MW-5D, and the system influent
is presented in Appendix B. Due to the nature of the petroleum impacts in fractured rock and the
limited extent of VOC groundwater detections, isoconcentration maps cannot be prepared.
However, benzene and MTBE concentrations for the February 2024 groundwater sampling event
are presented on Figure 5.
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4.0 Water Supply Well Sampling
H&H collected samples from the Former Daycare Well (Map ID 16) and Keller/Rawlings #2
water supply well (Map ID 37) on November 20, 2023 and February 6, 2024. The former
Daycare Well is not used for drinking water and bottled water is provided, as needed. The
property using the Former Daycare Well for non-potable water is occupied by a musician that
uses the building for instrument sales and instrument lessons. Samples collected were submitted
to a North Carolina certified laboratory for analysis of VOCs by EPA Method 6200B. The
analytical data reports for the water supply well sampling events are included in Appendix A.
No target compounds were detected above the laboratory detection limits in the Former Daycare
well and the Keller/Rawlings #2 well in November 2023 and February 2024. Historical supply
well sampling data are presented in Table 4. The recent results are also provided on Figure 3.
Based on approval from DEQ, the Christenbury water supply well has not been sampled since
October 2006 because of the prior consistent absence of petroleum compounds in the water well
samples. The Rawlings/Abernathy well was not sampled because the well has been inoperable
since the October 2006 sampling event. The trailer home at the Rawlings/Abernathy well
property is currently vacant, and the property has been connected to city water. The Bach/Innes
well has been decommissioned due to extension of the municipal waterline to the area. As such,
the multiple prior users of this well have been connected to municipal water.
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5.0 Remediation System
5.1 General Description
The recovery/treatment system is comprised of groundwater recovery via pneumatic pumps and
treatment via air stripping and carbon polishing. Treated groundwater is discharged via NPDES
General Permit NCG510000 under Certificate of Coverage NCG510500.
As directed by DEQ, groundwater is recovered from two existing bedrock monitoring wells and
treatment of the recovered groundwater is conducted using a low-profile air stripper and carbon
polishing located within a dedicated 10 ft x 10 ft treatment building. The treated groundwater is
then discharged to a stormwater swale located approximately 140 ft away and topographically
downgradient of the system under the NPDES General Permit NCG510000. The locations of the
system components are indicated on Figure 2. A schematic of the recovery and treatment system
components is indicated on Figure 6.
5.2 Groundwater Recovery
The system utilizes two pre-existing bedrock monitoring wells (MW-3D and MW-5D) for
groundwater recovery per DEQ’s requirements in their May 19, 2003 CAP approval letter.
These wells are two-inch diameter PVC monitoring wells. MW-3D is 85 ft deep and MW-5D is
95 ft deep. These wells have historically contained the highest concentrations of petroleum-
related constituents at the site.
Groundwater was previously recovered from each well using controllerless, top-loading,
pneumatic pumps (CEE Model AP-2). The pumps were discovered to be malfunctioning in June
2018. As a result, 2-inch diameter 48-inch long pneumatic pumps (QED Model Genie Pumps)
were installed in each well on July 2, 2018.
The air supply for the pneumatic pumps is from a 1.5 horsepower (hp), industrial duty,
reciprocating, two stage, splash lubricated, Saylor-Beall air compressor. This compressor is
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designed to deliver 7.3 standard cubic ft per minute (scfm) of air at 100 pounds per square inch
(psi).
5.3 Groundwater Treatment
Figure 2 indicates the layout of the treatment system. Groundwater recovered from the
monitoring/recovery wells is pumped via sub-grade piping to the treatment system housed in a
dedicated treatment building located east of the hardware store. The system contains a surge
tank, an air stripper, a blower, two carbon canisters installed in series, and associated controls.
Recovered groundwater is pumped to a 220-gallon, molded polyethylene surge tank equipped
with high-high-, high-, and low-level switches. When the high-level switch is tripped, the
groundwater is pumped to the air stripper via a ½ hp centrifugal transfer pump (American
Stainless Model #SSPC1) through an Amtek #PBH polypropylene vessel containing a 25-micron
filter bag.
The air stripper is a Northeast Environmental Products (NEEP) ShallowTray Model 2331-P
constructed of three Series 2300 polyethylene trays. After treatment via air stripping, the
effluent is pumped through a carbon-polishing unit. Two 300-pound carbon vessels (TetraSolv
Model AFD#85) are set up in series and filled with 8 x 30-mesh carbon. The carbon is used as a
polishing step and, due to the efficiency of the air stripping, it is not expected that breakthrough
of petroleum constituents will occur within the project life. Sampling ports are installed prior to
the surge tank, after the air stripper but before carbon polishing, between carbon vessels, and
after the carbon vessels.
A dedicated control panel is part of the treatment system. The controls prevent discharge of
untreated water by shutting off the recovery pumps when the surge tank is full and/or in the
event of an air stripper malfunction. A flow meter is installed at the system discharge to measure
the treated effluent volume.
The system was initially activated in August 2004 and was deactivated in July 2005 per DEQ’s
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July 2005 NORR indicating the work at the site was no longer directed. At the time of
deactivation, 101,581 gallons of groundwater had been recovered and treated. The system was
reactivated on May 19, 2006. On that date, H&H revisited the site, installed new carbon drums
due to leakage developing during system inactivity, and restarted the system. During the system
shutdown, the internal flow meter battery had discharged and the flow meter reset to zero.
On August 18, 2017, H&H discovered that the treatment system carbon drums were leaking. As
a result, the system was shut down in order to replace the drums. In September 2017, DEQ Trust
Fund requested that the system be repaired and remain off until its effectiveness could be further
evaluated. The system carbon drums were replaced on November 17, 2017. In late 2017, DEQ
requested that the treatment system be restarted. As a result, the system was reactivated on
March 20, 2018. As stated above, new 2-inch diameter 48-inch long pneumatic pumps (QED
Model Genie Pumps) were installed in each recovery well on July 2, 2018.
5.4 Operating Status
The treatment system operated as designed between September 2023 and December 2024.
Because the treatment system has reached asymptotic levels and continued operation of the
system to achieve 2L Standards is no longer cost-effective nor feasible, H&H recommended
discontinuing active groundwater remediation and initiating MNA closure sampling in the
December 2023 CAPR. DEQ approved system shutdown and MNA closure sampling in the
Acknowledgment of Receipt letter dated December 20, 2023. Based on DEQ approval, the
system was shut down on December 29, 2023.
5.5 Groundwater Treatment System Sampling
During the current reporting period, influent and effluent samples were collected on August 16,
2023 and November 20, 2023 and analyzed for oil and grease, total phenolics, total suspended
solids (TSS), lead, and VOCs. The VOCs analytes included benzene, ethylbenzene, toluene,
xylenes, MTBE, naphthalene, and 1,2-dichloroethane as required by the NPDES permit.
Laboratory analytical data are provided in Appendix A. Table 5 summarizes the analytical
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results and the historical influent and effluent sampling results. Select target VOCs were
detected in the influent samples. The August and November 2023 effluent results indicated no
detectable concentrations of VOCs.
Table 6 summarizes the mass removal for benzene and MTBE using the remediation system.
During the current reporting period, approximately 0.07 lb of MTBE was removed from the
groundwater. Based on the influent sampling results, no benzene was removed from
groundwater during the current reporting period. Overall, approximately 0.3 lb of benzene and
11 lbs of MTBE were removed from groundwater during the treatment system operation (Table
6).
5.6 Cleanup Progress Milestones
As previously indicated, a CAP was submitted to DEQ in November 27, 2002 recommending
active remediation of the soil by vapor extraction coupled with a ground water remedy involving
lowering the site risk by means of alternate water supply. On March 31, 2003, DEQ issued
correspondence to the General Store requesting additional activities in response to the CAP
submitted on November 27, 2002. The DEQ correspondence indicated that the CAP would not
be approved as DEQ believed pump and treat was the only acceptable remedial method.
Due to the uncertainty in implementing an active remedy of this type in the complex fracture
rock environment at the General Store, H&H has conducted ongoing evaluation of system
performance and applicability in meeting the project objectives outlined in the November 2002
CAP. Additionally, the General Store has periodically evaluated lowering the site risk to low by
providing a long-term alternate water supply to surrounding water supply users. Several
connections have been completed during the historical remediation period; however, active
drinking water wells still exist surrounding the site.
In an attempt to expedite site closure, in April 2021 DEQ requested that H&H evaluate
connecting the remaining drinking water wells within a 1,000 ft radius of the site to the
municipal water supply. A total of six water supply wells would need to be abandoned to lower
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the site risk. Currently, only the owner of the Former Daycare Well (Map ID 16) has agreed to
connect to the municipal water supply. H&H has received a Task Authorization (TA) from the
State Trust Fund for the estimated costs to connect this well user to the municipal water supply.
Hickory Water and Sewer requires that the land owner sign the water connection application in
person at their office. To date, H&H has been unable to schedule a day to meet with the well
owner at Hickory Water and Sewer based on their current work schedule.
Current remediation performance monitoring requires milestones be established for the site.
Remediation milestones were not originally included in the CAP because pump and treat
technology was not the H&H selected remedial alternative and based on the requirements at the
time when the CAP was prepared. However, during H&H’s evaluation of treatment alternatives,
pump and treat combined with soil vapor extraction was estimated to take approximately 5 to 10
years to achieve site closure. Because soil vapor extraction was not approved by DEQ, the time
for cleanup was extended. Based on historical groundwater system operation and sampling data
from the site, in 2017 H&H re-evaluated the anticipated time to achieve site closure and
estimated the cleanup progress milestones as presented in Table 7. Because benzene and MTBE
are the only compounds present at concentrations above groundwater standards, only mass
milestones for these compounds (combined) were calculated and included in the table.
The initial step was to calculate the initial plume mass where benzene and MTBE concentrations
exceeded groundwater standards. Using pre-pumping data from October 2003, initial plume
mass in two areas were calculated: for the plume center (Figure 4) and the remainder of the
plume (Figure 5). The average benzene and MTBE concentrations for MW-3D and MW-5D
were utilized for the central portion of the plume where more substantial contaminant mass is
present, and the average benzene and MTBE concentrations for two water supply wells
(Rawlings/Abernathy and Former Daycare) were utilized for the remainder of the plume. The
plume mass was calculated by Area of Water (v) x Plume Thickness (d) x Average
Concentrations of Benzene and MTBE (c) x Porosity of Aquifer (n) using the following
assumptions:
• Porosity (n) of 0.1 for fractured bedrock;
• Plume thickness (d) of 30 ft based on CAP;
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• Initial area of plume center near MW-3D/5D (v) of 11,232 ft2; and,
• Initial area of remaining plume (v) = 389,637 ft2.
Then, a mass concentration for the plume at site closure was calculated using the above formula
and based on the groundwater standards of 1 µg/l for benzene and 20 µg/l for MTBE.
Current/closure remaining plume areas (v) of 11,232 ft2 (plume source area) and 37,142 ft2
(remaining plume area) were utilized to estimate the alternate allowable plume mass at site
closure. The plume center area discussed above was utilized in the calculations. The estimated
extent of the central plume area is depicted on Figure 5, and pre-pumping and current plumes are
depicted on Figures 7 and 8, respectively.
Using the initial plume mass, H&H calculated mass reduction milestones until the plume mass
corresponding to the DEQ groundwater standards for benzene and MTBE would be achieved.
As presented in Table 7, H&H anticipated that the remediation system would take at least 25
years to achieve DEQ groundwater standards and site closure. When the system was shut down
in December 2023, it had operated for approximately 19.5 years.
The average groundwater concentrations for MW-3D, MW-5D, and supply wells
Rawlings/Abernathy and Former Daycare (if detections identified) were utilized to estimate the
mass reduction rates. The most recent sampling data from February 2024 indicate the system
had achieved an estimated mass reduction of approximately 89% from the baseline mass of 7.13
lbs to 0.77 lbs. H&H will continue to evaluate and update the milestone table during the MNA
closure sampling events.
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6.0 Conclusions and Recommendations
The General Store of Denver is a high-risk site due to water supply wells within 1,000 ft of the
source area. H&H collected samples from the Former Daycare and Keller/Rawlings #2 water
supply wells in November 2023 and February 2024. No target compounds were detected in
samples collected from these wells during the sampling events.
As approved in the DEQ Acknowledgment of Receipt letter dated December 20, 2023, the
treatment system was shut down and an MNA closure sampling period was initiated on
December 29, 2023. No treatment system shutdowns were encountered during the final system
operational period from September to December 2023. At the end of the time period described
in this report, the system had completed approximately 19.5 years of active remediation since
startup in 2004. The milestone for 19.5 years of active remediation indicates an estimated mass
reduction of approximately 81.5% from the initial estimate. The current estimate, based on
February 2024 groundwater data, indicates a mass reduction of approximately 89% from the
initial mass estimate. While the mass reduction has been variable during system operation, these
data show that the system and natural attenuation have potentially been effective at slowly
removing VOCs at the site and the current milestone criteria have been met.
Monitoring wells/recovery wells MW-3D and MW-5D were sampled as part of the first MNA
closure sampling event in February 2024. MTBE was detected at a concentration above the 2L
Standard in MW-3D, and benzene and MTBE were not detected above the laboratory detection
limits in monitoring well MW-5D.
The groundwater plume appears to be shrinking and the potential for site groundwater to impact
surrounding water supply wells appears to be low. H&H recommends continuing the MNA
closure sampling plan consisting of semi-annual water supply well and monitoring well sampling
events. The next semi-annual MNA closure sampling event will be conducted in August 2024
with reporting in September 2024. As part of the next semi-annual reporting, H&H will evaluate
plume stability for groundwater impacts at the site. The evaluation will include performing a
Mann-Kendall statistical analysis of the VOC data in site wells. Should the results of the
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statistical analysis continue to indicate decreasing or stable VOC trends and water supply well
results remain non-detect, risk-based closure for the site should be considered. However, some
ongoing water supply well sampling may be warranted. During the MNA closure sampling
period, H&H will continue to pursue connecting the Former Daycare water supply well user to
the municipal water supply.
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Certification:
1. This report is submitted on-time.
2.This report meets the template requirements for information.
3.There are no other suspected source zone soils or free product outside of the assessed
areas.
4.There has not been an unexpected increase in contaminant mass to suggest a new release
or separate source.
I, Stephen Libbey, PG for Hart & Hickman, PC do certify that the information contained in this
report is correct and accurate to the best of my knowledge.
Hart & Hickman, PC is licensed to practice geology and engineering in North Carolina. The
certification numbs are C-245 and C-1269, respectively.
04/05/24
3 Unnamed Well 6267 NC Hwy 150 East 369606394241 6255 NC Hwy 150 East, Denver, NC 28037
12 Robinson Well 6445 NC Hwy 150 East 369607580239 Sue Christenbury 6375 NC Hwy 150 East, Sherrills Ford, NC 28673
16 Daycare Well 6367 NC Hwy 150 East 369606491471 Carlos Siega Revocable Trust 2242 Perth Road, Mooresville, NC 28117 historically supplied by the General
18 (Drum Well #2) @ Shop 6321 NC Hwy 150 East 369606398341 Evelyn Stutts 6022 NC Hwy 150 East, Sherrills Ford, NC 28037 Inactive potable wells; Restaurant connected to City water
35 Rescue Squad Well 4385 Mt. Pleasant Road 369718406047 PO Box 51, Sherrills Ford, NC 28673 Inactive potable well
37 Keller/Rawlings #1/#2 4295 Mt. Pleasant Road 369719504852 Julie Harwath 4295 Mt. Pleasant Road, Sherrills Ford, NC 28673
40 Gregory Well 6545 Emerald Isle Drive 369607591817 Lonnie Gregory 4356 Bach Drive, Sherrills Ford, NC 28673 6530 Emerald Isle and 4338 Mt.
49 Newell Well 4425 Tuttlewood Drive 369607594127 4425 Tuttlewood Drive, Sherrills Ford, NC 28673 Active potable well
57 Seagle/Humphries Well 6562 Emerald Isle Drive 369607595912 Robert Humphries 6562 Emerald Isle Drive, Sherrills Ford, NC 28673
59 Crutchfield Well 6552 Emerald Isle Drive 369719504195 Lawson Starnes 6552 Emerald Isle Drive, Sherrills Ford, NC 28673 6554 and 6548 Emerald Isle (both
62 Rawlings / Abernathy Well 369719506498 Jerome Bolick PO Box 402, Conover, NC 28613 Inactive potable well
Potable Water Information
1/2
Bach / Innes Well, Unnamed
Well No Address Listing 369606496587
Massey Holdings
LLC PO Box 1114, Cornelius, NC 28031
Two inactive community wells
formerly served multiple residence
Map ID Well Name Property Address Tax ID Property Owner
369606380720 Joey Byrd PO Box 234, Moravian Falls, NC 28654
Owner Address
Property owner information from 9/2020 receptor survey and Catawba County GIS website data
Table 1
Water Supply Well Inventory
The General Store of Denver
Sherrills Ford, North Carolina
H&H Job No. GSD-050
Active potable well
32 6254 NC Hwy 150 East 369606390898 6254 Hwy 150 East, Denver, NC 28037 Active potable wells for campground
24 4464 Grassy Creek Road
Hart & Hickman, PC
Total TOC DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW
Well Depth Elevation*(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)
ID (ft)(ft)04/01/98 07/19/99 04/03/00 12/14/00 09/18/01 08/20/02 04/23/03 08/12/04 01/21/05 04/27/05 04/28/06
TYPE II WELLS
MW-1 55 88.35 49.35 39.00 43.45 44.90 42.36 45.99
MW-2 58 88.80 NI NI 43.30 45.50 42.22 46.58 44.80 44.00 55.29 33.51 46.48 42.32 42.92 45.88 43.03 45.77 NM NM NM NM NM NM
MW-3 60 91.28 NI NI 52.10 39.18 51.05 40.23 51.30 39.98 59.45 31.83 55.71 35.57 49.91 41.37 51.69 39.59 NM NM NM NM NM NM
MW-4 60 86.96 NI NI 50.60 36.36 49.28 37.68 51.54 35.42 55.38 31.58 53.55 33.41 46.97 39.99 48.91 38.05 NM NM NM NM NM NM
MW-5 62 90.60 NI NI NI NI NI NI NI NI NI NI 53.54 37.06 48.00 42.60 50.22 40.38 NM NM NM NM NM NM
TYPE III WELLS
MW-1D 85 89.28 NI NI NI NI NI NI NI NI 51.70 37.58 52.72 36.56 46.96 42.32 49.42 39.86 49.07 40.21 48.75 40.53 48.84 40.44
MW-2D 85 91.07 NI NI NI NI NI NI NI NI 54.32 36.75 55.57 35.50 49.66 41.41 51.24 39.83 51.79 39.28 51.52 39.55 50.95 40.12
MW-3D 95 90.70 NI NI NI NI NI NI NI NI NI NI 55.45 35.25 49.28 41.42 51.02 39.68
MW-4D 100 93.26 NI NI NI NI NI NI NI NI NI NI 59.78 33.48 56.66 36.60 54.09 39.17 55.54 37.72 55.40 37.86 54.38 38.88
MW-5D 85 92.72 NI NI NI NI NI NI NI NI NI NI 61.38 31.34 58.81 33.91 55.30 37.42
MW-6D 89 85.18 NI NI NI NI NI NI NI NI NI NI 55.48 29.70 51.91 33.27 49.82 35.36 50.64 34.54 50.09 35.09 49.28 35.90
Notes:
*TOC = Top of Casing elevation based on arbitrary datum assigned by Kimbrell & AssociatesMW-5, 4D, 5D, and 6D surveyed by H&H on 8/22/02
Table 2
Monitoring Well Water Level Data
General Store of Denver
Sherrills Ford, North Carolina
Abandoned
H&H Job No. GSD-050
Pumping
PumpingPumping
Pumping
Pumping
Pumping
Hart & Hickman, PC
Total TOC DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW
Well Depth Elevation*(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)
ID (ft)(ft)07/31/06 10/27/06 04/20/07 10/30/2007 5/6/2008 10/10/2008 4/6/2009 10/2/2009 10/29/2010 4/27/2011
TYPE II WELLS
MW-1 55 88.35
MW-2 58 88.80 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM
MW-3 60 91.28 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM
MW-4 60 86.96 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM
MW-5 62 90.60 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM
TYPE III WELLS
MW-1D 85 89.28 49.77 39.51 50.05 39.23 49.10 40.18 51.57 37.71 51.62 37.66 53.35 35.93 49.92 39.36 47.97 41.31 45.85 43.43 49.05 40.23 49.38 39.90 49.47 39.81
MW-2D 85 91.07 52.11 38.96 52.73 38.34 51.32 39.75 51.46 39.61 54.66 36.41 54.66 36.41 53.23 37.84 50.39 40.68 49.36 41.71 51.10 39.97 57.70 33.37 52.18 38.89
MW-3D 95 90.70
MW-4D 100 93.26 55.15 38.11 55.93 37.33 54.96 38.30 56.95 36.31 58.69 34.57 59.05 34.21 58.24 35.02 56.09 37.17 52.86 40.40 53.71 39.55 55.05 38.21 55.00 38.26
MW-5D 85 92.72
MW-6D 89 85.18 49.95 35.23 50.68 34.50 49.71 35.47 52.07 33.11 53.63 31.55 54.00 31.18 52.71 32.47 49.34 35.84 47.41 37.77 48.48 36.70 50.03 35.15 50.61 34.57
Notes:
*TOC = Top of Casing elevation based on arbitrary datum assigned by Kimbrell & AssociatesMW-5, 4D, 5D, and 6D surveyed by H&H on 8/22/02
Pumping
10/26/2011
Sherrills Ford, North Carolina
H&H Job No. GSD-050
PumpingPumpingPumping Pumping PumpingPumping
Abandoned
Pumping
Table 2
Monitoring Well Water Level Data
General Store of Denver
4/21/2010
PumpingPumpingPumpingPumping
Pumping
Pumping
Pumping Pumping Pumping
PumpingPumpingPumpingPumpingPumpingPumpingPumping
Hart & Hickman, PC
Total TOC DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW
Well Depth Elevation*(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)
ID (ft)(ft)
TYPE II WELLS
MW-1 55 88.35
MW-2 58 88.80 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM
MW-3 60 91.28 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM
MW-4 60 86.96 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM
MW-5 62 90.60 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM
TYPE III WELLS
MW-1D 85 89.28 48.97 40.31 49.88 39.40 49.43 39.85 49.09 40.19 47.34 41.94 48.97 40.31 49.15 40.13 50.66 38.62 48.20 41.08 50.85 38.43 50.91 38.37
MW-2D 85 91.07 51.32 39.75 52.48 38.59 52.18 38.89 51.23 39.84 49.44 41.63 51.10 39.97 51.29 39.78 53.03 38.04 50.36 40.71 53.27 37.80 53.32 37.75
MW-3D 95 90.70
MW-4D 100 93.26 54.75 38.51 55.73 37.53 56.14 37.12 54.70 38.56 53.18 40.08 53.65 39.61 54.72 38.54 55.90 37.36 53.77 39.49 56.09 37.17 56.10 37.16
MW-5D 85 92.72
MW-6D 89 85.18 49.53 35.65 50.44 34.74 50.75 34.43 49.14 36.04 47.83 37.35 48.42 36.76 49.20 35.98 50.68 34.50 48.31 36.87 50.90 34.28 50.85 34.33
Notes:
MW-5, 4D, 5D, and 6D surveyed by H&H on 8/22/02
4/22/2015 10/15/201510/31/2014 4/27/2016 4/28/201710/26/2016
Table 2
Monitoring Well Water Level Data
General Store of Denver
Sherrills Ford, North Carolina
H&H Job No. GSD-050
Pumping
5/29/201410/31/2012
Pumping
PumpingPumping
Pumping Pumping Pumping
Pumping
Pumping
4/30/20134/30/2012 11/21/2013
Abandoned
Pumping Pumping
Pumping
Pumping
PumpingPumping
Pumping
Pumping
Pumping
Pumping
Pumping Pumping
Pumping
Hart & Hickman, PC
Total TOC DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW
Well Depth Elevation*(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)
ID (ft)(ft)
TYPE II WELLS
MW-1 55 88.35
MW-2 58 88.80 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM
MW-3 60 91.28 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM
MW-4 60 86.96 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM
MW-5 62 90.60 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM
TYPE III WELLS
MW-1D 85 89.28 49.90 39.38 49.23 40.05 49.16 40.12 45.43 43.85 48.53 40.75 45.90 43.38 45.00 44.28 46.38 42.90 49.92 39.36 51.43 37.85 49.62 39.66 48.42 40.86
MW-2D 85 91.07 52.34 38.73 51.44 39.63 51.25 39.82 46.95 44.12 50.48 40.59 47.55 43.52 46.93 44.14 47.90 43.17 52.11 38.96 53.68 37.39 52.62 38.45 50.64 40.43
MW-3D 95 90.70 59.30 31.40
MW-4D 100 93.26 55.79 37.47 54.82 38.44 53.60 39.66 49.85 43.41 52.55 40.71 50.84 42.42 49.63 43.63 49.13 44.13 53.32 39.94 55.00 38.26 55.85 37.41 53.86 39.40
MW-5D 85 92.72 56.80 35.92
MW-6D 89 85.18 50.27 34.91 49.33 35.85 48.70 36.48 44.18 41.00 47.40 37.78 44.63 40.55 43.75 41.43 44.05 41.13 48.64 36.54 50.08 35.10 50.55 34.63 48.54 36.64
Notes:
MW-5, 4D, 5D, and 6D surveyed by H&H on 8/22/02
Abandoned
Table 2
Monitoring Well Water Level Data
General Store of Denver
Sherrills Ford, North Carolina
H&H Job No. GSD-050
Pumping
Pumping
Pumping Pumping
PumpingPumping
Pumping
Pumping
Pumping
Pumping
Pumping
PumpingPumping
Pumping
Pumping
Pumping Pumping
Pumping
Pumping
Pumping
Pumping
Pumping
Hart & Hickman, PC
Table 3Monitoring Well Groundwater Analytical Detections
General Store of DenverSherrills Ford, North CarolinaH&H Project GSD-050
Benzene Carbon Disulfide Chloroform Ethylbenzene Isopropyl-benzene Isopropyl-ether MTBE Naphthalene n-propyl-benzene Toluene 1,2,4-
Trimethyl-
benzene
1,3,5-
Trimethyl-
benzene
Xylenes
Semi-
Volatiles
(µg/l)
VPH C5-C8 Aliphatics VPH C9-C12 Aliphatics VPH C9-C10 Aromatics
C9-C18 Aliphatic Hydrocarbon
C19-C36 Aliphatic Hydrocarbon
C11-C22 Aromatic Hydrocarbon
9/13/2001 <1.00 NA <1.0 <1.00 NA <1.00 <1.00 <13.5 NA <1.00 NA NA <1.00 ND <100 <100 <100 <111 <111 <111 NA NA
2/19/2002 <0.4 <0.4 <0.4 <0.4 <0.4 <2.0 <0.4 <1.0 <0.4 <0.4 <0.4 <0.4 <0.4 ND <100 <100 <100 <102 <102 <102 NA NA
8/13/2004 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 NA NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA
1/21/2005 <1.0 NA <1.0 <1.0 <1.0 <1.0 <1.0 <2.0 NA <1.0 <1.0 <1.0 <1.0 NA NA NA NA NA NA NA NA NA
4/27/2005 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA
4/28/2006 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA
7/31/2006 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 NA NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA
10/27/2006 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <1.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA
4/20/2007 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <1.0 NA <1.0 NA NA <3.0 NA NA NA NA NA NA NA NA NA
10/30/2007 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <1.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA
5/6/2008 <0.50 NA <1.0 <1.0 NA <5.0 <5.0 <1.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA
10/10/2008 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA
4/6/2009 <0.50 NA 1.6 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/2/2009 <0.50 NA 0.78 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/21/2010 <0.50 NA 1.1 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/19/2010 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/27/2011 <0.50 NA <0.50 0.66 <0.50 <0.50 <0.50 7.3 <0.50 3.4 2.6 0.84 5.5 NA NA NA NA NA NA NA NA NA
10/26/2011 <0.50 NA <0.50 0.66 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 0.83 1.9 NA NA NA NA NA NA NA NA NA
4/30/2012 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 0.56 <0.50 0.71 NA NA NA NA NA NA NA NA NA
10/31/2012 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/30/2013 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
11/21/2013 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
5/29/2014 <0.50 NA <0.50 <0.50 <0.50 <0.50 <1.0 <1.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/31/2014 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/22/2015 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/15/2015 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/27/2016 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
9/13/2001 <1.00 NA <1.0 <1.00 NA <1.00 46.2 <10.0 NA <1.00 NA NA <1.00 ND <100 <100 <100 <111 <111 <111 NA NA
2/19/2002 <0.4 <0.4 <0.4 <0.4 <0.4 <2.0 54.9 <1.0 <0.4 <0.4 <0.4 <0.4 <0.4 ND <100 <100 <100 <102 <102 <102 NA NA
8/13/2004 <1.0 NA <1.0 <1.0 NA <1.0 3.8 NA NA 1.4 NA NA <1.0 NA NA NA NA NA NA NA NA NA
1/21/2005 <1.0 NA <1.0 <1.0 <1.0 <1.0 76 <2.0 NA 5.4 <1.0 <1.0 <1.0 NA NA NA NA NA NA NA NA NA
4/27/2005 <5.0 NA <5.0 <5.0 NA <5.0 91 <10 NA <5.0 NA NA <5.0 NA NA NA NA NA NA NA NA NA
4/28/2006 <2.0 NA <2.0 <2.0 NA <2.0 66 <4.0 NA <2.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA
7/31/2006 <2.0 NA <2.0 <2.0 NA <2.0 65 NA NA <2.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA
10/27/2006 <1.0 NA <1.0 <1.0 NA <1.0 36 <1.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA
4/20/2007 <1.0 NA <1.0 <1.0 NA <1.0 14 <2.0 NA <1.0 NA NA <3.0 NA NA NA NA NA NA NA NA NA
10/30/2007 <1.0 NA <1.0 <1.0 NA <1.0 8.6 <2.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA
5/6/2008 <0.5 NA <1.1 <1.0 NA <5.0 <5.0 <1.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA
10/10/2008 <1.0 NA <1.2 <1.0 NA <1.0 3.3 <2.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA
4/6/2009 <0.50 NA <1.3 <0.50 <0.50 <0.50 1.3 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/2/2009 <0.50 NA <1.4 <0.50 <0.50 <0.50 3.5 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/21/2010 <0.50 NA <1.5 <0.50 <0.50 <0.50 3.1 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/19/2010 <0.50 NA <1.6 <0.50 <0.50 <0.50 66.2 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/27/2011 1.7 NA <1.7 <0.50 <0.50 <0.50 47.5 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/26/2011 0.76 NA <1.8 <0.50 <0.50 <0.50 26.8 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/30/2012 <0.50 NA <1.9 <0.50 <0.50 <0.50 20.8 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/31/2012 3.3 NA <1.10 <0.50 <0.50 <0.50 100 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/30/2013 <0.50 NA <1.11 <0.50 <0.50 <0.50 5.9 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
11/21/2013 <0.50 NA <1.12 <0.50 <0.50 <0.50 16.9 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
5/29/2014 0.52 NA <0.50 <0.50 <0.50 <0.50 21 <1.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/31/2014 <0.50 NA <0.50 <0.50 <0.50 <0.50 9.0 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/22/2015 <0.50 NA <0.50 <0.50 <0.50 <0.50 9.6 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/15/2015 <0.50 NA <0.50 <0.50 <0.50 <0.50 6.0 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
MW-2D
MW-1D
Lead (µg/l)Well ID Sample Date Phenol (µg/l)
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsxDeep T-24/5/2024
Table 3 (Page 1 of 4)Hart & Hickman, PC
Table 3Monitoring Well Groundwater Analytical Detections
General Store of DenverSherrills Ford, North CarolinaH&H Project GSD-050
Benzene Carbon Disulfide Chloroform Ethylbenzene Isopropyl-benzene Isopropyl-ether MTBE Naphthalene n-propyl-benzene Toluene 1,2,4-
Trimethyl-
benzene
1,3,5-
Trimethyl-
benzene
Xylenes
Semi-
Volatiles
(µg/l)
VPH C5-C8 Aliphatics VPH C9-C12 Aliphatics VPH C9-C10 Aromatics
C9-C18 Aliphatic Hydrocarbon
C19-C36 Aliphatic Hydrocarbon
C11-C22 Aromatic Hydrocarbon Lead (µg/l)Well ID Sample Date Phenol (µg/l)
2/19/2002 316 2.7 <0.4 <0.4 2.4 10.0 1,760 4.4 <0.4 <0.4 <0.4 <0.4 50 ND 2,410 <100 <100 NA <102 <102 NA NA
10/16/2003 40 NA <5 <5 <5 7.6 990 <5 <5 <5 <5 <0.4 <5 NA NA NA NA NA NA NA 12 <5
8/13/2004 100 NA <1.0 <1.0 NA 1.1 76 NA NA <1.0 NA NA 1.1 NA NA NA NA NA NA NA NA NA
1/21/2005 3.0 NA <0.50 <0.50 <0.50 9.6 1,400 <2.0 NA <0.5 <0.5 <0.5 <0.5 NA NA NA NA NA NA NA NA NA
4/27/2005 100 NA <1.0 <1.0 NA 13 1,800 <2.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA
4/28/2006 190 NA <50 <50 NA <50 2,700 <100 NA <50 NA NA <50 NA NA NA NA NA NA NA NA NA
7/31/2006 130 NA <50 <50 NA <50 2,900 NA NA <50 NA NA <50 NA NA NA NA NA NA NA NA NA
10/27/2006 <50 NA <50 <50 NA <50 2,800 <100 NA <50 NA NA <50 NA NA NA NA NA NA NA NA NA
4/20/2007 100 NA <100 <100 NA <100 4,200 <200 NA <100 NA NA <300 NA NA NA NA NA NA NA NA NA
11/6/2007 <100 NA <100 <100 NA <100 3,870 <200 NA <100 NA NA <200 NA NA NA NA NA NA NA NA NA
5/6/2008 150 NA <10 <10 NA <50 4,500 <10 NA <10 NA NA <20 NA NA NA NA NA NA NA NA NA
10/10/2008 <100 NA <100 <100 NA <100 4,230 <200 NA <100 NA NA <200 NA NA NA NA NA NA NA NA NA
4/6/2009 <10.0 NA <10.0 <10.0 <10.0 15.0 3,430 <40.0 <10.0 <10.0 <10.0 <10.0 <30.0 NA NA NA NA NA NA NA NA NA
10/2/2009 290 NA <5.0 <5.0 <5.0 15 4,400 <20 <5.0 <5.0 <5.0 <5.0 <15.0 NA NA NA NA NA NA NA NA NA
4/21/2010 118 NA <12.5 <12.5 <12.5 <12.5 3,490 <50 <12.5 <12.5 <12.5 <12.5 <37.5 NA NA NA NA NA NA NA NA NA
10/29/2010 246 NA <12.5 <12.5 <12.5 29 5,410 <50 <12.5 <12.5 <12.5 <12.5 <37.5 NA NA NA NA NA NA NA NA NA
4/27/2011 <12.5 NA <12.5 <12.5 <12.5 14 3,480 <50 <12.5 <12.5 23.5 <12.5 <37.5 NA NA NA NA NA NA NA NA NA
10/26/2011 188 NA <0.50 <0.50 2.3 27.7 5,980 5.5 <0.50 <0.50 <0.50 <0.50 2.4 NA NA NA NA NA NA NA NA NA
4/30/2012 <25.0 NA <25.0 <25.0 <25.0 <25.0 4,480 <100 <0.50 <0.50 <0.50 <0.50 <75.0 NA NA NA NA NA NA NA NA NA
10/31/2012 <12.5 NA <12.5 <12.5 <12.5 29.1 6,360 <50 <12.5 <12.5 <12.5 <12.5 <37.5 NA NA NA NA NA NA NA NA NA
4/30/2013 26.0 NA <25.0 <25.0 <25.0 32.5 6,720 <100 <25.0 <25.0 <25.0 <25.0 <75.0 NA NA NA NA NA NA NA NA NA
11/21/2013 59.3 NA <25.0 <25.0 <25.0 28.3 6,610 <100 <25.0 <25.0 <25.0 <25.0 <75.0 NA NA NA NA NA NA NA NA NA
5/29/2014 640 NA <0.50 <0.50 11 49 7,000 24 1.3 <0.50 1.1 0.64 7.6 NA NA NA NA NA NA NA NA NA
10/31/2014 <1.2 NA <1.2 <1.2 <1.2 <1.2 692 <5.0 <1.2 <1.2 <1.2 <1.2 <3.7 NA NA NA NA NA NA NA NA NA
4/22/2015 <2.5 NA <2.5 <2.5 <2.5 26.1 5,170 <10.0 <2.5 <2.5 <2.5 <2.5 <7.5 NA NA NA NA NA NA NA NA NA
10/15/2015 4.4 NA <2.5 <2.5 <2.5 <2.5 747 <10.0 <2.5 <2.5 <2.5 <2.5 <7.5 NA NA NA NA NA NA NA NA NA
4/27/2016 <5.0 NA <5.0 <5.0 <5.0 8.7 1,960 <20.0 <5.0 <5.0 <5.0 <5.0 <15.0 NA NA NA NA NA NA NA NA NA
10/28/2016 <10.0 NA <10.0 <10.0 <10.0 16.2 3,040 <40.0 <10.0 <10.0 <10.0 <10.0 <30.0 NA NA NA NA NA NA NA NA NA
4/28/2017 2.6 NA <1.2 <5.0 <1.2 <1.2 417 <5.0 <1.2 <1.2 <1.2 <1.2 <3.7 NA NA NA NA NA NA NA NA NA
11/17/2017 244 NA <20.0 <20.0 <20.0 32.8 5,570 <80.0 <20.0 <20.0 <20.0 <20.0 <60.0 NA NA NA NA NA NA NA NA NA
6/19/2018 55.1 NA <20.0 <20.0 <20.0 22.6 3,880 <80.0 <20.0 <20.0 <20.0 <20.0 <60.0 NA NA NA NA NA NA NA NA NA
12/20/2018 473 NA <12.5 <12.5 <12.5 24.5 3,990 <50.0 <12.5 <12.5 <12.5 <12.5 <37.5 NA NA NA NA NA NA NA NA NA
6/21/2019 111 NA <62.5 <6.2 <6.2 7.6 1,710 <25.0 <6.2 <6.2 <6.2 <6.2 <18.7 NA NA NA NA NA NA NA NA NA
1/15/2020 206 NA <12.5 <12.5 <12.5 20.8 3,210 <50.0 <12.5 <12.5 <12.5 <12.5 <27.5 NA NA NA NA NA NA NA NA NA
7/14/2020 391 NA <12.5 <12.5 <12.5 14.3 2,410 <50.0 <12.5 18.2 <12.5 <12.5 <27.5 NA NA NA NA NA NA NA NA NA
1/18/2021 283 NA <10.0 <10.0 <10.0 11.1 1,990 92.5 <10.0 <10.0 27.1 <10.0 37.5 NA NA NA NA NA NA NA NA NA
7/30/2021 186 NA <6.2 <6.2 <6.2 12.7 1,730 <25.0 <6.2 <6.2 <6.2 <6.2 <18.7 NA NA NA NA NA NA NA NA NA
1/27/2022 212 NA <5.0 <5.0 <5.0 13.2 1,620 <20.0 <5.0 <5.0 <5.0 <5.0 <15.0 NA NA NA NA NA NA NA NA NA
7/21/2022 <5.0 NA <5.0 <5.0 <5.0 10.8 1,350 <20.0 <5.0 <5.0 <5.0 <5.0 <15.0 NA NA NA NA NA NA NA NA NA
1/27/2023 <5.0 NA <5.0 <5.0 <5.0 10.2 1,480 <20.0 <5.0 <5.0 <5.0 <5.0 <15.0 NA NA NA NA NA NA NA NA NA
8/16/2023 95.1 NA <5.0 <5.0 <5.0 12.7 1,680 <20.0 <5.0 <5.0 <5.0 <5.0 <15.0 NA NA NA NA NA NA NA NA NA
2/6/2024 <0.500 NA <0.500 <0.500 <0.500 10.6 616 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500 NA NA NA NA NA NA NA NA NA
2/19/2002 0.6 1.0 0.7 0.4 <0.4 <2.0 8.0 <1.0 <0.4 <0.4 1.7 0.5 3.6 ND <100 <100 <100 <102 <102 <102 NA NA
8/13/2004 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 NA NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA
1/21/2005 <1.0 NA <1.0 <1.0 <1.0 <1.0 <1.0 <2.0 NA <1.0 <1.0 <1.0 <1.0 NA NA NA NA NA NA NA NA NA
4/27/2005 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA
4/28/2006 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA
7/31/2006 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 NA NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA
10/27/2006 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <1.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA
4/20/2007 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <1.0 NA <1.0 NA NA <3.0 NA NA NA NA NA NA NA NA NA
10/30/2007 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA
5/6/2008 <0.5 NA <1.0 <1.0 NA <5.0 <5.0 <1.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA
10/10/2008 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA
4/6/2009 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/2/2009 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/21/2010 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/29/2010 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/27/2011 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/26/2011 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/30/2012 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/31/2012 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/30/2013 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
11/21/2013 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
5/29/2014 <0.50 NA <0.50 <0.50 <0.50 <0.50 <1.0 <1.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/31/2014 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/22/2015 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/15/2015 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
MW-4D
MW-3D(1)
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsxDeep T-24/5/2024
Table 3 (Page 2 of 4)Hart & Hickman, PC
Table 3Monitoring Well Groundwater Analytical Detections
General Store of DenverSherrills Ford, North CarolinaH&H Project GSD-050
Benzene Carbon Disulfide Chloroform Ethylbenzene Isopropyl-benzene Isopropyl-ether MTBE Naphthalene n-propyl-benzene Toluene 1,2,4-
Trimethyl-
benzene
1,3,5-
Trimethyl-
benzene
Xylenes
Semi-
Volatiles
(µg/l)
VPH C5-C8 Aliphatics VPH C9-C12 Aliphatics VPH C9-C10 Aromatics
C9-C18 Aliphatic Hydrocarbon
C19-C36 Aliphatic Hydrocarbon
C11-C22 Aromatic Hydrocarbon Lead (µg/l)Well ID Sample Date Phenol (µg/l)
2/19/2002 217 <0.4 <0.4 <0.4 3.8 3.0 257 7.1 0.4 0.6 <0.4 <0.4 38.7 ND 988 <100 <100 <102 <102 <102 NA NA
10/16/2003 480 NA <5 <5 <5 11.0 1,700 12 <5 <5 <5 <5 85 NA NA NA NA NA NA NA 240 <5
8/13/2004 520 NA <1.0 <1.0 NA 7.5 1,100 NA NA <1.0 NA NA 23 NA NA NA NA NA NA NA NA NA
1/17/2005 95 NA <5.0 <5.0 <5.0 8.2 1,500 <20 <5.0 <5.0 <5.0 <5.0 <0.5 NA NA NA NA NA NA NA NA NA
4/27/2005 76 NA <1.0 <1.0 NA 7.7 1,100 <2.0 NA <2.0 NA NA 15 NA NA NA NA NA NA NA NA NA
4/28/2006 140 NA <20 <20 NA <20 660 <40 NA <20 NA NA <20 NA NA NA NA NA NA NA NA NA
7/31/2006 160 NA <20 <20 NA <20 1,200 NA NA <20 NA NA <20 NA NA NA NA NA NA NA NA NA
10/27/2006 150 NA <25 <25 <25 <25 1,100 <40 NA <25 NA NA <25 NA NA NA NA NA NA NA NA NA
4/20/2007 310 NA <25 <25 NA <25 1,300 <50 NA <25 NA NA <75 NA NA NA NA NA NA NA NA NA
11/6/2007 <25.0 NA <25.0 <25.0 NA <25.0 908 <50.0 NA <25.0 NA NA <50.0 NA NA NA NA NA NA NA NA NA
5/6/2008 45 NA <1.0 <1.0 NA 12 580 3.6 NA 2.6 NA NA 9 NA NA NA NA NA NA NA NA NA
10/10/2008 <25.0 NA <25.0 <25.0 NA <25.0 962 <50.0 NA <25.0 NA NA <50.0 NA NA NA NA NA NA NA NA NA
4/6/2009 <2.5 NA <2.5 <2.5 <2.5 7.5 1,042 <10.0 <2.5 <2.5 <2.5 <2.5 <7.5 NA NA NA NA NA NA NA NA NA
10/2/2009 1.3 NA <0.50 <0.50 3.2 6.4 900 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/21/2010 113 NA <5.0 <5.0 <5.0 <5.0 762 <20.0 <5.0 6.6 <5.0 <5.0 5.2 NA NA NA NA NA NA NA NA NA
10/29/2010 <2.5 NA <2.5 <2.5 <2.5 <2.5 935 <10.0 <2.5 <2.5 <2.5 <2.5 <7.5 NA NA NA NA NA NA NA NA NA
4/27/2011 3.7 NA <2.5 <2.5 <2.5 <2.5 255 <10.0 <2.5 <2.5 4.4 <2.5 <7.5 NA NA NA NA NA NA NA NA NA
10/26/2011 10.9 NA <0.50 <0.50 2.0 1.5 285 5.4 <0.50 1.6 3.2 1.8 2.1 NA NA NA NA NA NA NA NA NA
4/30/2012 33.6 NA <5.0 <5.0 <5.0 8.9 1,610 <20.0 <5.0 <5.0 6.9 <5.0 <15.0 NA NA NA NA NA NA NA NA NA
10/31/2012 <5.0 NA <5.0 <5.0 <5.0 5.7 891 <20.0 <5.0 <5.0 7.8 <5.0 <15.0 NA NA NA NA NA NA NA NA NA
4/30/2013 <2.5 NA <2.5 <2.5 <2.5 5.4 822 <10.0 <2.5 <2.5 <10.0 <2.5 <7.5 NA NA NA NA NA NA NA NA NA
11/21/2013 <2.5 NA <2.5 <2.5 <2.5 6.4 831 <10.0 <2.5 <2.5 <10.0 <2.5 <7.5 NA NA NA NA NA NA NA NA NA
5/29/2014 490 NA <0.50 <0.50 13 8.7 1,300 28 <0.50 <0.50 5.3 1.8 23 NA NA NA NA NA NA NA NA NA
10/31/2014 <2.5 NA <2.5 <2.5 <2.5 4.4 791 <10.0 <2.5 <2.5 <2.5 <2.5 <7.5 NA NA NA NA NA NA NA NA NA
4/22/2015 <2.5 NA <2.5 <2.5 <2.5 4.5 672 <10.0 <2.5 <2.5 <2.5 <2.5 <7.5 NA NA NA NA NA NA NA NA NA
10/15/2015 5.2 NA <2.5 <2.5 <2.5 4.0 619 <10.0 <2.5 <2.5 <2.5 <2.5 <7.5 NA NA NA NA NA NA NA NA NA
4/27/2016 <2.5 NA <2.5 <2.5 <2.5 4.8 651 <10.0 <2.5 <2.5 <2.5 <2.5 <7.5 NA NA NA NA NA NA NA NA NA
10/28/2016 <2.5 NA <2.5 <2.5 <2.5 5.1 661 <10.0 <2.5 <2.5 <2.5 <2.5 <7.5 NA NA NA NA NA NA NA NA NA
4/28/2017 2.4 NA <1.0 <1.0 1.5 2.8 350 <4.0 <1.0 <1.0 1.2 <1.0 <3.0 NA NA NA NA NA NA NA NA NA
11/17/2017 4.6 NA <0.50 <0.50 <0.50 1.2 130 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
6/19/2018 9.5 NA <0.50 <0.50 2.3 4.9 568 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
12/20/2018 225 NA <2.5 <2.5 8.0 5.7 769 19.7 <2.5 <2.5 7.1 3.2 5.4 NA NA NA NA NA NA NA NA NA
6/21/2019 27.6 NA <25.0 <2.5 <2.5 3.4 539 <10.0 <2.5 <2.5 <2.5 <2.5 <7.5 NA NA NA NA NA NA NA NA NA
1/15/2020 125 NA <2.5 <2.5 3.5 6.0 800 <10.0 <2.5 <2.5 <2.5 <2.5 <7.5 NA NA NA NA NA NA NA NA NA
7/14/2020 3.4 NA <1.2 <1.2 <1.2 2.9 417 <5.0 <1.2 <1.2 <1.2 <1.2 <3.7 NA NA NA NA NA NA NA NA NA
1/18/2021 <2.0 NA <2.0 <2.0 <2.0 3.2 400 <8.0 <2.0 <2.0 <2.0 <2.0 <6.0 NA NA NA NA NA NA NA NA NA
7/30/2021 <1.2 NA <1.2 <1.2 <1.2 2.0 328 <5.0 <1.2 <1.2 <1.2 <1.2 <3.7 NA NA NA NA NA NA NA NA NA
1/27/2022 <0.50 NA <0.50 <0.50 <0.50 0.54 17.9 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
7/21/2022 <0.50 NA <0.50 <0.50 <0.50 <0.50 6.5 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
1/27/2023 <0.50 NA <0.50 <0.50 <0.50 <0.50 1.5 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
8/16/2023 <0.50 NA <0.50 <0.50 <0.50 <0.50 5.7 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
2/6/2024 <0.500 NA <0.500 <0.500 <0.500 <0.500 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500 NA NA NA NA NA NA NA NA NA
4/19/2002 <0.40 <0.40 <0.40 <0.40 <0.40 <2.00 <0.40 <1.00 <0.40 <0.40 <0.40 <0.40 <0.40 ND <100 <100 <100 <100 <100 <100 NA NA
8/13/2004 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 9.5 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA
1/21/2005 <1.0 NA <1.0 <1.0 <1.0 <1.0 <1.0 <2.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA NA NA NA NA NA NA NA NA
4/27/2005 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA
4/28/2006 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA
7/31/2006 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 NA NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA
7/31/2006 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 NA NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA
4/20/2007 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <3.0 NA NA NA NA NA NA NA NA NA
10/30/2007 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA
5/6/2008 <0.50 NA <1.0 <1.0 NA <5.0 <5.0 <1.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA
10/10/2008 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA
4/6/2009 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/2/2009 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/21/2010 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/29/2010 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/27/2011 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/26/2011 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/30/2012 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/31/2012 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/30/2013 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
11/21/2013 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
5/29/2014 <0.50 NA <0.50 <0.50 <0.50 <0.50 <1.0 <1.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/31/2014 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/22/2015 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/15/2015 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
MW-6D
MW-5D(2,3)
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsxDeep T-24/5/2024
Table 3 (Page 3 of 4)Hart & Hickman, PC
Table 3Monitoring Well Groundwater Analytical Detections
General Store of DenverSherrills Ford, North CarolinaH&H Project GSD-050
Benzene Carbon Disulfide Chloroform Ethylbenzene Isopropyl-benzene Isopropyl-ether MTBE Naphthalene n-propyl-benzene Toluene 1,2,4-
Trimethyl-
benzene
1,3,5-
Trimethyl-
benzene
Xylenes
Semi-
Volatiles
(µg/l)
VPH C5-C8 Aliphatics VPH C9-C12 Aliphatics VPH C9-C10 Aromatics
C9-C18 Aliphatic Hydrocarbon
C19-C36 Aliphatic Hydrocarbon
C11-C22 Aromatic Hydrocarbon Lead (µg/l)Well ID Sample Date Phenol (µg/l)
DENR MW-05D 4/19/2002 <0.40 <0.40 <0.40 <0.40 <0.40 <2.00 <0.40 <1.00 <0.40 <0.40 <0.40 <0.40 <0.40 ND <100 <100 <100 <100 <100 <100 NA NA
4/19/2002 <0.40 <0.40 <0.40 <0.40 <0.40 <2.00 <0.40 <1.00 <0.40 <0.40 <0.40 <0.40 <0.40 ND <100 <100 <100 <100 <100 <100 NA NA
1/21/2005 <1.0 NA <1.0 <1.0 <1.0 <1.0 <1.0 <2.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA NA NA NA NA NA NA NA NA
4/27/2005 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA
4/28/2006 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA
4/28/2006 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA
10/27/2006 <1.0 NA <1.0 <1.0 NA <1.0 1.6 <2.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA
4/20/2007 <1.0 NA <1.0 <1.0 NA <1.0 1.6 <2.0 NA <1.0 NA NA <3.0 NA NA NA NA NA NA NA NA NA
10/30/2007 <1.0 NA <1.0 <1.0 NA <1.0 1.5 <2.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA
5/6/2008 <0.50 NA <1.0 <1.0 NA <5.0 <5.0 <1.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA
10/10/2008 <1.0 NA <1.0 <1.0 NA <1.0 3.2 <2.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA
4/6/2009 <0.50 NA <0.50 <0.50 <0.50 <0.50 3.3 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/2/2009 <0.50 NA <0.50 <0.50 <0.50 <0.50 3.1 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/21/2010 <0.50 NA <0.50 <0.50 <0.50 <0.50 2.5 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/29/2010 <0.50 NA <0.50 <0.50 <0.50 <0.50 2.7 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/27/2011 <0.50 NA <0.50 <0.50 <0.50 <0.50 0.79 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/26/2011 <0.50 NA <0.50 <0.50 <0.50 <0.50 0.60 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/30/2012 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/31/2012 <0.50 NA 0.72 <0.50 <0.50 <0.50 1.20 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/30/2013 <0.50 NA 0.66 <0.50 <0.50 <0.50 1.0 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
11/21/2013 <0.50 NA 0.76 <0.50 <0.50 <0.50 0.75 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
5/29/2014 <0.50 NA 0.83 <0.50 <0.50 <0.50 1.1 <1.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/31/2014 <0.50 NA 0.99 <0.50 <0.50 <0.50 0.52 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/22/2015 <0.50 NA 0.98 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
10/15/2015 <0.50 NA 0.91 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
4/27/2016 <0.50 NA 1.1 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA
DENR No Name 4/19/2002 <0.40 <0.40 <0.40 <0.40 <0.40 <2.00 <0.40 <1.00 <0.40 <0.40 <0.40 <0.40 <0.40 ND <100 <100 <100 <100 <100 <100 NA NA
2L Groundwater
Standard 1 700 70 600 70 70 20 6 70 600 400 400 500 NS 420 NS NS 4,200 42,000 210 30 15
Notes:Bold indicates concentration exceeds the Groundwater standard
NS = No Standard, NA = Not Analyzed, ND = Not Detected; VPH = Volatile Petroleum Hydrocarbons; EPH = Extractable Petroleum Hydrocarbons
DENR MW-06D
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsxDeep T-24/5/2024
Table 3 (Page 4 of 4)Hart & Hickman, PC
Volatile Organics
Benzene MTBE PCE
13.4 <2 <1
3.3 <2 <1
9.9 <2 <1
7/18/2003 1.4 15 <2 <1
10/16/2003 1.9 16 <2 <1
1/15/2004 1.8 20 <2 <1
4/30/2004 1.5 13 <2 <1
7/30/2004 1.3 9.1 <2 <1
10/27/2004 1.1 11 <2 <1
1/21/2005 1.1 9.6 <2 <1
4/27/2005
6/26/2002 1.4 49.2 <2 <1
10/10/2002 1.1 14.6 <2 <1
1/30/2003 4.4 35 <2 <1
4/22/2003 5.6 25 <2 <1
7/18/2003 <1 <1 <2 1.6
10/16/2003 <1 <1 <2 1.3
1/15/2004 <1 <1 <2 1.7
4/30/2004 <1 <1 <2 1.8
7/30/2004 <1 <1 <2 2.1
10/27/2004 <1 <1 <2 1.5
1/21/2005 <1 <1 <2 <1
4/27/2005 <1 <1 <2 1.2
7/29/2005 <1 <1 <2 1.2
10/28/2005 <1 <1 <2 1.1
1/30/2006 <1 <1 <2 <1
4/28/2006 <1 <1 <2 <1
7/31/2006 <1 <1 <2 <1
10/27/2006 <1 <1 <2 1.1
8/1/2002 <1 20.8 <2 <1
10/10/2002 6.1 65.8 <2 <1
1/30/2003 <1 20 <2 <1
4/22/2003 <1 24 <2 <1
7/18/2003 <1 30 3.5 <1
10/16/2003 10 75 <2.0 <1
1/15/2004 2.6 68 <2.0 <1
4/30/2004 9.2 85 5.3 <1
7/30/2004 10 110 <2 <1
10/27/2004 20 140 <2 <1
1/21/2005 17 140 <2 <1
4/27/2005 <5 110 <10 <5
7/29/2005 <5 160 <10 <5
10/28/2005 <5 81 <10 <5
16 <2 <1
4/28/2006 <1 44 <2 <1
7/31/2006 1.0 29 <2 <1
10/27/2006 <1.0 44 <2 <1
1/25/2007 <1.0 22 <2.0 <1.0
4/20/2007 <1.0 17 <2.0 <1.0
7/18/2007 <1.0 35 <2.0 <1.0
Community
Well Property
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Table 4
Summary of Water Supply Well Sample Results
The General Store of Denver
Sherrills Ford, North Carolina
H&H Job No. GSD-050
Well Inactive
14
Well Map ID Well Name Well Address
1
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsx WSW Results T-34/5/2024
Table 4 (Page 1 of 4)
Hart & Hickman, PC
Volatile Organics
Benzene MTBE PCE
Table 4
Summary of Water Supply Well Sample Results
The General Store of Denver
Sherrills Ford, North Carolina
H&H Job No. GSD-050
Well Map ID Well Name Well Address
10/30/2007 <1.0 11.1 <2.0 <1.0
1/11/2008 <1.0 47.6 <2.0 <1.0
5/6/2008 <0.5 12 <1.0 <1.0
18.7 <2.0 <1.0
10/10/2008 <1.0 26.8 <2.0 <1.0
1/29/2009 <5.0 118 <10.0 <5.0
4/6/2009 <1.0 80.2 <2.0 <1.0
7/31/2009 <0.50 55.4 <2.0 <0.50
1.3 160 <1.0 <1.0
153 <1.0 <1.0
4/21/2010 <0.50 4.7 <2.0 <0.50
7/22/2010 <1.0 3.1 <2.0 <1.0
10/29/2010 <1.0 3.3 <2.0 <1.0
1/11/2011 <1.0 4.3 <2.0 <1.0
4/27/2011 <1.0 27.9 <2.0 <1.0
7/8/2011 <0.50 40.7 <2.0 <0.50
10/26/2011 <0.50 3.0 <2.0 <0.50
1/27/2012 <0.50 19.4 <2.0 <1.0
4/30/2012 <0.50 4.5 <2.0 <0.50
7/31/2012 <0.50 3.0 <2.0 <0.50
10/31/2012 <0.50 1.5 <2.0 <0.50
3/6/2013 <0.50 1.5 <2.0 <0.50
4/30/2013 <0.50 25.8 <2.0 <0.50
7/30/2013 <0.50 2.7 <2.0 <0.50
11/21/2013 <0.50 52.3 <2.0 <0.50
2/10/2014 <0.50 12.6 <2.0 <0.50
5/29/2014 <0.50 5.7 <2.0 <0.50
8/15/2014 <0.50 2.3 <2.0 <0.50
10/31/2014 <0.50 1.4 <2.0 <0.50
1/23/2015 <0.50 1.0 <2.0 <0.50
4/22/2015 1.9 234 <2.0 <0.50
8/21/2015 <0.50 1.2 <2.0 <0.50
10/15/2015 <0.50 1.8 <2.0 <0.50
199 <2.0 <0.50
4/27/2016 <0.50 0.86 <2.0 <0.50
8/18/2016 <0.50 0.92 <2.0 <0.50
10/28/2016 <0.50 0.90 <2.0 <0.50
2/9/2017 <0.50 0.60 <2.0 <0.50
4/28/2017 <0.50 0.50 <2.0 <0.50
8/15/2017 <0.50 <0.50 <2.0 <0.50
11/17/2017 <0.50 1.1 <2.0 <0.50
3/6/2018 <0.50 <0.50 <2.0 <0.50
6/15/2018 <0.50 0.59 <2.0 <0.50
9/26/2018 <0.50 0.69 <2.0 <0.50
12/20/2018 <0.50 37.4 <2.0 <0.50
3/22/2019 <0.50 <0.50 <2.0 <0.50
6/21/2019 <0.50 <0.50 <2.0 <0.50
9/13/2019 <0.50 0.55 <2.0 <0.50
1/15/2020 <0.50 <0.50 <2.0 <0.50
4/16/2020 <0.50 <0.50 <2.0 <0.50
7/14/2020 <0.50 <0.50 <2.0 <0.50
10/19/2020 <0.50 <0.50 <2.0 <0.50
1/21/2021 <0.50 <0.50 <2.0 <0.50
4/23/2021 <0.50 <0.50 <2.0 <0.50
11/19/2021 <0.50 1.1 <2.0 <0.50
1/27/2022 <0.50 <0.50 <2.0 <0.50
4/22/2022 <0.50 59.4 <2.0 <0.50
7/21/2022 <0.50 0.85 <2.0 <0.50
10/27/2022 <0.50 <0.50 <2.0 <0.50
1/27/2023 <0.50 0.70 <2.0 <0.50
5/25/2023 <0.50 <0.50 <2.0 <0.50
8/16/2023 <0.50 <0.50 <2.0 <0.50
11/20/2023 <0.50 <0.50 <2.0 <0.50
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https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsx WSW Results T-34/5/2024
Table 4 (Page 2 of 4)
Hart & Hickman, PC
Volatile Organics
Benzene MTBE PCE
Table 4
Summary of Water Supply Well Sample Results
The General Store of Denver
Sherrills Ford, North Carolina
H&H Job No. GSD-050
Well Map ID Well Name Well Address
7/2/2002 <1 1.1 <2 <1
10/10/2002 <1 <1 <2 <1
1/30/2003 <1 2.1 <2 <1
4/22/2003 <1 2.2 <2 <1
7/18/2003 <1 <1 <2 <1
10/16/2003 <1 1.5 <2 <1
1/15/2004 <1 <1.0 <2 <1
4/30/2004 <1 3.0 <2 <1
7/30/2004 <1 <1 <2 <1
10/27/2004 <1 2.0 <2 <1
1/21/2005 <1 2.0 <2 <1
4/27/2005 <1 2.1 <2 <1
7/29/2005 <1 1.5 <2 <1
10/28/2005 <1 1.3 <2 <1
1/30/2006 <1 1.4 <2 <1
4/28/2006 <1 1.5 <2 <1
7/31/2006 <1 2.1 <2 <1
10/27/2006 <1 2.7 <2 <1
1/25/2007 <1.0 2.5 <2.0 <1.0
5/11/2007 <1.0 2.8 <2.0 <1.0
7/18/2007 <1 2.5 <2 <1
10/30/2007 <1.0 2.2 <2.0 <1.0
1/11/2008 <1.0 2.8 <2.0 <1.0
5/6/2008 <0.50 <5.0 <1.0 <1.0
7/31/2008 <1.0 2.2 <2.0 <1.0
10/10/2008 <1.0 3.0 <2.0 <1.0
1/29/2009 <1.0 1.7 <2.0 <1.0
7/31/2009 <0.50 2.1 <2.0 <0.50
4/21/2010 <0.50 1.5 <2.0 <0.50
7/22/2010 <1.0 2.1 <2.0 <1.0
10/29/2010 <1.0 2.1 <2.0 <1.0
1/11/2011 <1.0 2.4 <2.0 <1.0
4/27/2011 <1.0 1.8 <2.0 <1.0
7/8/2011 <0.50 1.8 <2.0 <0.50
10/26/2011 <0.50 1.7 <2.0 <0.50
1/27/2012 <1.0 1.7 <2.0 <1.0
4/30/2012 <0.50 1.6 <2.0 <0.50
7/31/2012 <0.50 1.6 <2.0 <0.50
10/31/2012 <0.50 1.3 <2.0 <0.50
3/6/2013 <0.50 1.3 <2.0 <0.50
4/30/2013 <0.50 1.2 <2.0 <0.50
7/30/2013 <0.50 0.53 <2.0 <0.50
2/10/2014 <0.50 <0.50 <2.0 <0.50
10/31/2014 <0.50 <0.50 <2.0 <0.50
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https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsx WSW Results T-34/5/2024
Table 4 (Page 3 of 4)
Hart & Hickman, PC
Volatile Organics
Benzene MTBE PCE
Table 4
Summary of Water Supply Well Sample Results
The General Store of Denver
Sherrills Ford, North Carolina
H&H Job No. GSD-050
Well Map ID Well Name Well Address
1/23/2015 <0.50 <0.50 <2.0 <0.50
4/22/2015 <0.50 <0.50 <2.0 <0.50
8/21/2015 <0.50 <0.50 <2.0 <0.50
10/15/2015 <0.50 <0.50 <2.0 <0.50
1/26/2016 <0.50 <0.50 <2.0 <0.50
4/27/2016 <0.50 <0.50 <2.0 <0.50
8/18/2016 <0.50 <0.50 <2.0 <0.50
10/28/2016 <0.50 <0.50 <2.0 <0.50
2/9/2017 <0.50 <0.50 <2.0 <0.50
4/28/2017 <0.50 <0.50 <2.0 <0.50
8/15/2017 <0.50 <0.50 <2.0 <0.50
11/27/2017 <0.50 <0.50 <2.0 <0.50
3/6/2018 <0.50 <0.50 <2.0 <0.50
1/15/2020
10/10/2002 <1 1.6 <2 <1
1/30/2003 <1 <1 <2 <1
4/22/2003 <1 <1 <2 <1
7/18/2003 <1 <1 <2 <1
10/16/2003 <1 <1 <2 <1
1/15/2004 <1 <1 <2 <1
4/30/2004 <1 <1 <2 <1
7/30/2004 <1 <1 <2 <1
10/27/2004 Well Inactive
1/15/2020 <0.50 <0.50 <2.0 <0.50
4/16/2020 <0.50 <0.50 <2.0 <0.50
7/14/2020 <0.50 <0.50 <2.0 <0.50
10/19/2020 <0.50 <0.50 <2.0 <0.50
1/21/2021 <0.50 <0.50 <2.0 <0.50
4/23/2021 <0.50 <0.50 <2.0 <0.50
7/30/2021 <0.50 <0.50 <2.0 <0.50
11/19/2021 <0.50 <0.50 <2.0 <0.50
1/27/2022 <0.50 <0.50 <2.0 <0.50
4/22/2022 <0.50 <0.50 <2.0 <0.50
7/21/2022 <0.50 <0.50 <2.0 <0.50
10/27/2022 <0.50 <0.50 <2.0 <0.50
1/27/2023 <0.50 <0.50 <2.0 <0.50
5/25/2023 <0.50 <0.50 <2.0 <0.50
8/16/2023 <0.50 <0.50 <2.0 <0.50
11/20/2023 <0.50 <0.50 <2.0 <0.50
2/6/2024 <0.500 <1.00 <2.00 <0.500
7/2/2002 6.3 46.2 <2 <1
10/10/2002 <1 9.1 <2 <1
1/30/2003 3.0 21 <2 <1
4/22/2003 4.1 25 <2 <1
7/18/2003 5.7 21 2.4 <1
10/16/2003 4.9 16 <2 <1
1/15/2004 3.1 11 <2 <1
4/30/2004 <1 3.3 <2 <1
7/30/2004 <1 <1 <2 <1
10/27/2004 <1 9.1 <2 <1
1/21/2005 6.0 25 <2 <1
4/27/2005 11 22 <2 <1
7/29/2005 8.0 44 <2 <1
10/28/2005 20 52 <2 <1
1/30/2006 4.0 17 <2 <1
4/28/2006 <1 <1 <2 <1
4/20/2007
Notes:
All analytical results reported in units of micrograms per liter; Bold indicates compound detected.
1 - Sampled from spigot at General Store because owner refused access to wellhead.
2 - Chloromethane also detected at a concentration of 9.7 µg/l on 1/30/06.
3 - Naphthalene also detected at a concentration of 3.1 µg/l on 7/31/08 and 1.0 µg/l on 10/2/09.
4 - IPE also detected at a concentration of 1.0 µg/l on 1/7/10 and 1.2 µg/l on 1/26/16.
5 - Toluene also detected at a concentration of 3.0 µg/l on 8/15/14.
37 (cont.)4309 Mt. Pleasant Road
Well Inactive
MTBE = Methyl-tert-butyl ether; VPH = Volatile Petroleum Hydrocarbons, EPH = Extractable Petroleum Hydrocarbons; PCE = tetrachloroethylene; NA =
Not Analyzed; NS = Not Sampled; BDL = All Compounds Below Laboratory Detection Limits.
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Table 4 (Page 4 of 4)
Hart & Hickman, PC
Table 5
Summary of Influent and Effluent Sample Results
General Store of Denver
Sherrills Ford, North Carolina
H&H Job No. GSD-050
Sample ID In042705 Eff042705 Inf073106 EFF073106 Inf102706 EFF102706 INF012507 EFF012507 INFLUENT042007 INFLUENT 071807 Daily
Sample Location Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Discharge
Date 4/27/2005 4/27/2005 7/31/2006 7/31/2006 10/27/2006 10/27/2006 1/25/2007 1/25/2007 4/20/2007 4/20/2007 7/18/2007 7/18/2007 Limit (µg/l)
Laboratory Parameters
Oil and Grease (1664) [mg/l]<5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NS
Phenolics (420.1) [mg/l]<0.010 <0.010 0.098 <0.010 0.029 0.010 <0.010 <0.010 0.044 <0.010 0.019 0.011 300
Lead (200.7) [mg/l]<0.005 <0.005 <0.005 <0.005 NA NA <5.0 <5.0 <0.005 <5.0 <0.005 <5.0 25
TSS [mg/l]<3.3 <3.3 9.5 <1.7 4.8 <1.1 22 <1.1 9.0 1.5 56 <1.7 30,000
VOCs (6230D) Units = µg/l
Benzene 13 <0.5 27 <0.5 100 <0.5 <5.0 <0.50 160 <0.50 6.6 <0.50 1.19
n-Butylbenzene <5 <0.5 <2.5 <0.5 <2.5 <0.5 <5.0 <0.50 <5.0 <0.50 <5.0 <0.50 NS
sec-Butylbenzene <5 <0.5 <2.5 <0.5 <2.5 <0.5 <5.0 <0.50 <5.0 <0.50 <5.0 <0.50 NS
Chloroform <5 <0.5 <2.5 <0.5 3.4 <0.5 <5.0 <0.50 <5.0 <0.50 <5.0 <0.50 NS
Isopropylbenzene <5 <0.5 <2.5 <0.5 4.5 <0.5 <5.0 <0.50 <5.0 <0.50 <5.0 <0.50 NS
Isopropyl ether (IPE)5.3 <0.5 4.3 <0.5 11 <0.5 5.4 <0.50 8.7 <0.50 5.7 <0.50 NS
Methyl t-butyl Ether (MTBE)870 <0.5 800 <0.5 1,500 <0.5 1,300 <0.50 1,600 <0.50 1,200 <0.50 30
Naphthalene <5 <2 <2.5 <2 <2.5 <2 <20 <2.0 <20 <2.0 <20 <2.0 78
1,2,4-Trimethylbenzene <5 <0.5 <2.5 <0.5 9.7 <0.5 <5.0 <0.50 <5.0 <0.50 <5.0 <0.50 NS
m,p-Xylenes <10 <0.5 <2.5 <0.5 <2.5 <0.5 <10 <1.0 <10 <1.0 <10 <1.0 NS
o-xylene <5 <0.5 <2.5 <0.5 <2.5 <0.5 <5.0 <0.50 7.9 <0.50 <5.0 <0.50 NS
Total Xylenes <0.5 <0.50 2.6 <0.50 12 <0.50 <15 <1.5 7.9 <1.5 <15 <1.5 780
Notes:
EPA Method number follows parameter in parenthesis
VOC = Volatile Organic Compound
NS= Not Specified
All BDL = Target analytes below detection limit
Bold indicates exceeds standard
J= estimated value between reporting limit and detection limit
July 20071
6
April 2005 July 2006 October 2006 January 2007 April 2007
Hart & Hickman, PC
Sample ID INFLUENT 110607 INFLUENT 020508 INFLUENT 050608 INFLUENT 073108 INFLUENT 101008 INFLUENT 012909 Daily
Sample Location Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Discharge
Date 11/6/2007 11/6/2007 2/5/2008 2/5/2008 5/6/2008 5/6/2008 7/31/2008 7/31/2008 10/10/2008 10/10/2008 1/29/2009 1/29/2009 Limit (µg/l)
Laboratory Parameters
Oil and Grease (1664) [mg/l]<5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 8.0 <5.0 <5.0 <5.0 <5.0 NS
Phenolics (420.1) [mg/l]0.015 <0.010 <0.010 <0.010 <0.016 <0.010 0.029 <0.010 <0.010 <0.010 0.010 <0.010 300
Lead (200.7) [mg/l]<0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 25
TSS [mg/l]<3.3 <1.1 <1.7 <1.7 4.3 2.9 18 5.9 <1.4 <1.4 29.5 <1.1 30,000
VOCs (6230D) Units = µg/l
Benzene 12.6 <0.50 <0.50 <0.5 <5.0 <0.5 <0.5 <0.5 <0.5 <0.5 93.8 <0.50 1.19
n-Butylbenzene <5.0 <0.50 <0.50 <0.5 <5.0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.50 <0.50 NS
sec-Butylbenzene <5.0 <0.50 <0.50 <0.5 <5.0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.50 <0.50 NS
Chloroform <5.0 <0.50 <0.50 <0.5 <5.0 <0.5 <1000 <1000 <0.5 <0.5 <0.50 <0.50 NS
Isopropylbenzene <5.0 <0.50 <0.50 <0.5 <5.0 <0.5 <0.5 <0.5 <0.5 <0.5 1.1 <0.50 NS
Isopropyl ether (IPE)8.8 <0.50 11.8 <0.5 6.9 <0.5 0.97 <0.5 11.4 <0.5 10.2 <0.50 NS
Methyl t-butyl Ether (MTBE)1,910 <0.50 1,960 <0.5 1,390 <0.5 144 <0.5 1,870 <0.5 1,990 <0.50 30
Naphthalene <20.0 <2.0 <2.0 <2.0 <20.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 78
1,2,4-Trimethylbenzene <5.0 <0.50 <0.50 <0.5 <5.0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.50 <0.50 NS
m,p-Xylenes <10.0 <1.0 <0.50 <0.5 <10.0 <0.5 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NS
o-xylene <5.0 <0.50 <0.50 <0.5 <5.0 <0.5 <0.5 <0.5 <0.5 <0.5 0.55 <0.50 NS
Total Xylenes <10.0 <1.0 <0.50 <0.5 <5.0 <0.5 <1.5 <1.5 <1.5 <1.5 0.55 <1.50 780
Notes:
EPA Method number follows parameter in parenthesis
VOC = Volatile Organic Compound
NS= Not Specified
All BDL = Target analytes below detection limit
Bold indicates exceeds standard
J= estimated value between reporting limit and detection limit
January 2009
6
Table 5
Summary of Influent and Effluent Sample Results
General Store of Denver
Sherrills Ford, North Carolina
H&H Job No. GSD-050
November 20072 February 2008 May 2008 July 2008 October 2008
Hart & Hickman, PC
Sample ID INFLUENT 042609 INFLUENT 073109 INFLUENT 100209 INFLUENT 010710 INFLUENT 042110 Daily
Sample Location Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Discharge
Date 4/6/2009 4/6/2009 7/31/2009 7/31/2009 10/2/2009 10/2/2009 1/7/2010 1/7/2010 4/21/2010 4/21/2010 Limit (µg/l)
Laboratory Parameters
Oil and Grease (1664) [mg/l]<5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NS
Phenolics (420.1) [mg/l]<0.010 <0.010 <0.010 <0.010 <0.050 0.074 <0.010 <0.010 <0.010 <0.010 300
Lead (200.7) [mg/l]<0.005 <0.005 <0.005 <5.0 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 25
TSS [mg/l]<1.0 <1.0 <7.1 19.7 <5.0 <5.0 <8.3 <8.3 <5.6 <5.6 30,000
VOCs (6230D) Units = µg/l
Benzene <5.0 <0.50 0.75 <0.50 17 <0.50 <0.50 <0.50 <2.5 <0.50 1.19
n-Butylbenzene <5.0 <0.50 <0.50 <1.0 <20 <1.0 <0.50 <0.50 <2.5 <0.50 NS
sec-Butylbenzene <5.0 <0.50 <0.50 <0.50 <10 <0.50 <0.50 <0.50 <2.5 <0.50 NS
Chloroform <5.0 <0.50 <0.50 <0.50 <10 <0.50 <0.50 <0.50 <2.5 <0.50 NS
Isopropylbenzene <5.0 <0.50 <0.50 <0.50 <10 <0.50 1.1 <0.50 <2.5 <0.50 NS
Isopropyl ether (IPE)7.8 <0.50 0.60 <0.50 <10 <0.50 11.3 <0.50 3.6 <0.50 NS
Methyl t-butyl Ether (MTBE)1,590 <0.50 126 <0.50 1,100 <0.50 1,820 <0.50 750 <0.50 30
Naphthalene <20.0 <2.0 <2.0 <2.0 <40 <2.0 <2.0 <2.0 <2.5 <2.0 78
1,2,4-Trimethylbenzene <5.0 <0.50 <0.50 <0.50 <10 <0.50 <0.50 <0.50 <2.5 <0.50 NS
m,p-Xylenes <10.0 <1.0 <1.0 <1.0 <10 <1.0 <1.0 <1.0 <5.0 <1.0 NS
o-xylene <5.0 <0.50 <0.50 <0.50 <10 <0.50 <0.50 <0.50 <2.5 <0.50 NS
Total Xylenes <10.0 <1.50 <1.50 <1.50 <30 <1.50 <1.50 <1.50 <7.5 <1.50 780
Notes:
EPA Method number follows parameter in parenthesis
VOC = Volatile Organic Compound
NS= Not Specified
All BDL = Target analytes below detection limit
Bold indicates exceeds standard
J= estimated value between reporting limit and detection limit
6
Table 5
Summary of Influent and Effluent Sample Results
General Store of Denver
Sherrills Ford, North Carolina
H&H Job No. GSD-050
April 2009 July 20093 October 2009 January 2010 April 2010
Hart & Hickman, PC
November 2010
Sample ID INFLUENT 073109 INFLUENT 102910 INFLUENT 012411 INFLUENT 042711 INFLUENT 070811 Daily
Sample Location Influent Effluent Influent Effluent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Discharge
Date 7/29/2010 7/29/2010 10/29/2010 10/29/2010 11/19/2010 1/24/2011 1/24/2011 4/27/2011 4/27/2011 7/8/2011 7/8/2011 10/26/2011 10/26/2011 Limit (µg/l)
Laboratory Parameters
Oil and Grease (1664) [mg/l]<5.0 <5.0 <5.0 <5.0 NA <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NS
Phenolics (420.1) [mg/l]0.035 <0.010 0.016 <0.010 NA <0.010 0.059 0.016 <0.010 <0.010 <0.010 0.023 <0.010 300
Lead (200.7) [mg/l]<0.005 <5.0 <0.005 <0.005 NA <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 0.0122 25
TSS [mg/l]50.7 11.2 26.7 <2.5 NA <5.6 <2.8 5.6 <2.5 <2.7 <2.5 20.3 <2.7 30,000
VOCs (6230D/6200B) Units = µg/l
Benzene 8.5 <0.50 11.5 <0.50 <0.50 20.6 <0.50 <2.5 <0.50 <25.0 <0.50 20.2 <0.50 1.19
Bromodichloromethane <2.5 <0.50 <2.5 3.3 2.36 <5.0 <0.50 <2.5 <0.50 NA NA <0.50 <0.50 NS
n-Butylbenzene <2.5 <0.50 <2.5 <1.0 <0.50 <5.0 <0.50 <2.5 <0.50 NA NA <0.50 <0.50 NS
sec-Butylbenzene <2.5 <0.50 <2.5 <0.50 <0.50 <5.0 <0.50 <2.5 <0.50 NA NA <0.50 <0.50 NS
Chlorodibromomethane <2.5 <0.50 <2.5 1.80 1.54 <5.0 <0.50 <2.5 <0.50 NA NA <0.50 <0.50 NS
Chloroform <2.5 <0.50 <2.5 3.7 2.38 <5.0 <0.50 <2.5 <0.50 NA NA <0.50 <0.50 NS
Isopropylbenzene <2.5 <0.50 <2.5 <0.50 <0.50 9.8 <0.50 <2.5 <0.50 NA NA <0.50 <0.50 NS
Isopropyl ether (IPE)4.5 <0.50 9.1 <0.50 <0.50 12.9 <0.50 3.4 <0.50 NA NA 5.7 <0.50 NS
Methyl t-butyl Ether (MTBE)945 <0.50 1,110 <0.50 <0.50 2,450 <0.50 753 <0.50 5,280 <0.50 1,220 <0.50 30
Naphthalene <10.0 <2.0 <10.0 <2.0 <5.0 <10.0 <2.0 <10.0 <2.0 <100 <2.0 <2.0 <2.0 78
1,2,4-Trimethylbenzene <2.5 <0.50 <2.5 <0.50 <0.50 <5.0 <0.50 <2.5 <0.50 NA NA <0.50 <0.50 NS
m,p-Xylenes <5.0 <1.0 <5.0 <1.0 NA <5.0 <1.0 <5.0 <1.0 <50.0 <1.0 <1.0 <1.0 NS
o-xylene <2.5 <0.50 <2.5 <0.50 NA <5.0 <0.50 <2.5 <0.50 <25.0 <0.50 <0.50 <0.50 NS
Total Xylenes <7.5 <1.50 <7.5 <1.50 <1.0 14.40 <1.50 <7.5 <1.50 <75.0 <1.50 <1.50 <1.50 780
Notes:
EPA Method number follows parameter in parenthesis
VOC = Volatile Organic Compound
NS = Not Specified; NA = Not Analyzed
All BDL = Target analytes below detection limit
Bold indicates exceeds standard
J= estimated value between reporting limit and detection limit
October 2011
6
Table 5
Summary of Influent and Effluent Sample Results
General Store of Denver
Sherrills Ford, North Carolina
H&H Job No. GSD-050
July 2010 October 2010 January 2011 April 2011 July 2011
Hart & Hickman, PC
Sample ID INFLUENT 012712 INFLUENT 043012 INFLUENT 073112 INFLUENT 103112 INFLUENT 043013 INFLUENT 073013 Daily
Sample Location Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Discharge
Date 1/27/2012 1/27/2012 4/30/2012 4/30/2012 7/31/2012 7/31/2012 10/31/2012 10/31/2012 4/30/2013 4/30/2013 7/30/2013 7/30/2013 Limit (µg/l)
Laboratory Parameters
Oil and Grease (1664) [mg/l]<5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NS
Phenolics (420.1) [mg/l]0.011 <0.010 0.036 <0.010 0.056 0.092 0.0093 0.006 0.037 0.020 0.0120 0.0080 300
Lead (200.7) [mg/l]<0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 0.011 0.0276 <0.0050 <0.005 0.0235 25
TSS [mg/l]7.2 <2.5 10.2 <5.0 <5.0 <5.0 8.2 <2.5 4.96 <2.6 47.0 <2.5 30,000
VOCs (6230D/6200B) Units = µg/l
Benzene 5.0 <0.50 85.9 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 1.19
Bromodichloromethane <5.0 <0.50 <12.5 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 NS
n-Butylbenzene <5.0 <0.50 <12.5 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 NS
sec-Butylbenzene <5.0 <0.50 <12.5 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 NS
Chlorodibromomethane <5.0 <0.50 <12.5 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 NS
Chloroform <5.0 <0.50 <12.5 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 NS
Isopropylbenzene <5.0 <0.50 <12.5 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 NS
Isopropyl ether (IPE)<5.0 <0.50 13.1 <0.50 <10.0 <0.50 13.6 <0.50 10.20 <0.50 12.5 <0.50 NS
Methyl t-butyl Ether (MTBE)916 <0.50 2,930 <0.50 2,500 <0.50 2,870 <0.50 2042.00 <0.50 2,160 <0.50 30
Naphthalene <20.0 <2.0 <50.0 <2.0 <40 <2.0 <40.0 <2.0 <40.0 <2.0 <40.0 <2.0 78
1,2,4-Trimethylbenzene <5.0 <0.50 <12.5 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 NS
m,p-Xylenes <10.0 <1.0 <25.0 <1.0 <20.0 <1.0 <20.0 <1.0 <20.0 <1.0 <20.0 <1.0 NS
o-xylene <5.0 <0.50 <12.5 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 NS
Total Xylenes <15.0 <1.50 <37.5 <1.50 <30.0 <1.50 <30.0 <1.50 <30.0 <1.50 <30.0 <1.50 780
Notes:
EPA Method number follows parameter in parenthesis
VOC = Volatile Organic Compound
NS = Not Specified; NA = Not Analyzed
All BDL = Target analytes below detection limit
Bold indicates exceeds standard
J= estimated value between reporting limit and detection limit
July 20135
6
Table 5
Summary of Influent and Effluent Sample Results
General Store of Denver
Sherrills Ford, North Carolina
H&H Job No. GSD-050
January 2012 April 2012 July 20124 Ocotber 2012 April 2013
Hart & Hickman, PC
Sample ID INFLUENT 112113 INFLUENT 021014 INFLUENT 081514 INFLUENT 103114 INFLUENT 012315 INFLUENT 042215 Daily
Sample Location Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Discharge
Date 11/21/2013 11/21/2013 2/10/2014 2/10/2014 8/15/2014 8/15/2014 10/31/2014 10/31/2014 1/23/2015 1/23/2015 4/22/2015 4/22/2015 Limit (µg/l)
Laboratory Parameters
Oil and Grease (1664) [mg/l]<5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NS
Phenolics (420.1) [mg/l]0.0160 0.0057 0.24 0.074 <0.010 0.014 0.014 0.010 0.012 <0.010 <0.010 <0.010 300
Lead (200.7) [mg/l]<0.005 <0.005 <0.005 <0.005 <0.005 0.0081 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 25
TSS [mg/l]6.0 <2.7 41.0 <2.6 9.1 <2.5 <2.5 <2.5 <2.5 <5.0 <2.5 <5.0 30,000
VOCs (6230D/6200B) Units = µg/l
Benzene 18.4 <0.50 173 <0.50 8.5 <0.50 3.3 <0.50 <5.0 <0.50 <2.5 <0.50 1.19
Bromodichloromethane <10.0 <0.50 <5.0 <0.50 <2.5 <0.50 <2.5 <0.50 <5.0 <0.50 <2.5 <0.50 NS
n-Butylbenzene <10.0 <0.50 <5.0 <0.50 <2.5 <0.50 <2.5 <0.50 <5.0 <0.50 <2.5 <0.50 NS
sec-Butylbenzene <10.0 <0.50 <5.0 <0.50 <2.5 <0.50 <2.5 <0.50 <5.0 <0.50 <2.5 <0.50 NS
Chlorodibromomethane <10.0 <0.50 <5.0 <0.50 <2.5 <0.50 <2.5 <0.50 <5.0 <0.50 <2.5 <0.50 NS
Chloroform <10.0 <0.50 <5.0 <0.50 <2.5 <0.50 <2.5 <0.50 <5.0 <0.50 <2.5 <0.50 NS
Isopropylbenzene <10.0 <0.50 7.0 <0.50 <2.5 <0.50 <2.5 <0.50 <5.0 <0.50 <2.5 <0.50 NS
Isopropyl ether (IPE)13.5 <0.50 6.7 <0.50 3.2 <0.50 3.3 <0.50 <5.0 <0.50 2.5 <0.50 NS
Methyl t-butyl Ether (MTBE)3,350 <0.50 1,066 <0.50 714 <0.50 1,042 0.55 674 <0.50 444 <0.50 30
Naphthalene <40.0 <2.0 <20.0 <2.0 <10.0 <2.0 <10.0 <2.0 <20.0 <2.0 <10.0 <2.0 78
1,2,4-Trimethylbenzene <10.0 <0.50 12.9 <0.50 <2.5 <0.50 <2.5 <0.50 <5.0 <0.50 <2.5 <0.50 NS
m,p-Xylenes <20.0 <1.0 <10.0 <1.0 <5.0 <1.0 <5.0 <1.0 <10.0 <1.0 <5.0 <1.0 NS
o-xylene <10.0 <0.50 11.9 <0.50 <2.5 <0.50 <2.5 <0.50 <5.0 <0.50 <2.5 <0.50 NS
Total Xylenes <30.0 <1.50 11.9 <1.50 <7.5 <1.50 <7.5 <1.50 <15.0 <1.50 <7.5 <1.50 780
Notes:
EPA Method number follows parameter in parenthesis
VOC = Volatile Organic Compound
NS = Not Specified; NA = Not Analyzed
All BDL = Target analytes below detection limit
Bold indicates exceeds standard
J= estimated value between reporting limit and detection limit
April 2015
6
Table 5
Summary of Influent and Effluent Sample Results
General Store of Denver
Sherrills Ford, North Carolina
H&H Job No. GSD-050
November 2013 February 20146 August 2014 October 2014 January 2015
Hart & Hickman, PC
Sample ID INFLUENT 082115 INFLUENT 101515 INFLUENT 012616 INFLUENT 042716 INFLUENT 081816 INFLUENT 102816 Daily
Sample Location Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Discharge
Date 8/21/2015 8/21/2015 10/15/2015 10/15/2015 1/26/2016 1/26/2016 4/27/2016 4/27/2016 8/18/2016 8/18/2016 10/28/2016 10/28/2016 Limit (µg/l)
Laboratory Parameters
Oil and Grease (1664) [mg/l]<5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NS
Phenolics (420.1) [mg/l]<0.010 <0.010 0.014 <0.010 0.013 0.013 0.012 0.011 0.014 0.012 <0.010 0.011 300
Lead (200.7) [mg/l]<0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 25
TSS [mg/l]<5.0 <5.0 7.1 <2.5 <2.5 <2.5 <2.5 <2.5 13.2 <2.5 <2.5 <2.5 30,000
VOCs (6230D/6200B) Units = µg/l
Benzene <2.5 <0.50 3.1 <0.50 <1.0 <0.50 <5.0 <0.50 1.8 <0.50 <2.5 <0.50 1.19
Bromodichloromethane <2.5 <0.50 <2.5 <0.50 <1.0 <0.50 <5.0 <0.50 <1.0 <0.50 <2.5 <0.50 NS
n-Butylbenzene <2.5 <0.50 <2.5 <0.50 <1.0 <0.50 <5.0 <0.50 <1.0 <0.50 <2.5 <0.50 NS
sec-Butylbenzene <2.5 <0.50 <2.5 <0.50 <1.0 <0.50 <5.0 <0.50 <1.0 <0.50 <2.5 <0.50 NS
Chlorodibromomethane <2.5 <0.50 <2.5 <0.50 <1.0 <0.50 <5.0 <0.50 <1.0 <0.50 <2.5 <0.50 NS
Chloroform <2.5 <0.50 <2.5 <0.50 <1.0 <0.50 <5.0 <0.50 <1.0 <0.50 <2.5 <0.50 NS
Isopropylbenzene <2.5 <0.50 <2.5 <0.50 <1.0 <0.50 <5.0 <0.50 1.1 <0.50 <2.5 <0.50 NS
Isopropyl ether (IPE)3.3 <0.50 4.4 <0.50 2.2 <0.50 <5.0 <0.50 1.3 <0.50 4.9 <0.50 NS
Methyl t-butyl Ether (MTBE)530 <0.50 1,130 <0.50 239 <0.50 509 <0.50 199 <0.50 591 <0.50 30
Naphthalene <10.0 <2.0 <10.0 <2.0 <4.0 <2.0 <20.0 <2.0 <4.0 <2.0 <10.0 <2.0 78
1,2,4-Trimethylbenzene <2.5 <0.50 <2.5 <0.50 <1.0 <0.50 <5.0 <0.50 2.3 <0.50 <2.5 <0.50 NS
m,p-Xylenes <5.0 <1.0 <5.0 <1.0 <2.0 <1.0 <10.0 <1.0 <2.0 <1.0 <5.0 <1.0 NS
o-xylene <2.5 <0.50 <2.5 <0.50 <1.0 <0.50 <5.0 <0.50 <1.0 <0.50 <2.5 <0.50 NS
Total Xylenes <7.5 <1.50 <7.5 <1.50 <3.0 <1.50 <15.0 <1.50 <3.0 <1.50 <7.5 <1.50 780
Notes:
EPA Method number follows parameter in parenthesis
VOC = Volatile Organic Compound
NS = Not Specified; NA = Not Analyzed
All BDL = Target analytes below detection limit
Bold indicates exceeds standard
J= estimated value between reporting limit and detection limit
October 2016
6
Table 5
Summary of Influent and Effluent Sample Results
General Store of Denver
Sherrills Ford, North Carolina
H&H Job No. GSD-050
August 2015 Ocotber 2015 January 2016 April 2016 August 2016
Hart & Hickman, PC
Sample ID INFLUENT 020917 INFLUENT 042817 INFLUENT 070218 INFLUENT 090218 INFLUENT 120218 Daily
Sample Location Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Discharge
Date 2/9/2017 2/9/2017 4/28/2017 4/28/2017 7/2/2018 7/2/2018 9/26/2018 9/26/2018 12/20/2018 12/20/2018 Limit (µg/l)
Laboratory Parameters
Oil and Grease (1664) [mg/l]<5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 47.5 <5.0 <5.0 NS
Phenolics (420.1) [mg/l]<0.010 <0.010 <0.010 <0.010 0.011 <0.010 0.018 <0.010 0.010 <0.010 300
Lead (200.7) [mg/l]<0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 25
TSS [mg/l]<2.5 <2.5 4.9 <2.5 <10.0 <2.5 3.2 <2.5 14.9 <2.5 30,000
VOCs (6230D/6200B) Units = µg/l
Benzene <2.0 <0.50 <0.50 <0.50 8.6 <0.50 167 <0.50 253 <0.50 1.19
Bromodichloromethane <2.0 <0.50 <0.50 <0.50 <2.5 <0.50 <0.50 <0.50 <12.5 <0.50 NS
n-Butylbenzene <2.0 <0.50 <0.50 <0.50 <2.5 <0.50 <0.50 <0.50 <12.5 <0.50 NS
sec-Butylbenzene <2.0 <0.50 <0.50 <0.50 <2.5 <0.50 0.83 <0.50 <12.5 <0.50 NS
Chlorodibromomethane <2.0 <0.50 <0.50 <0.50 <2.5 <0.50 <0.50 <0.50 <12.5 <0.50 NS
Chloroform <2.0 <0.50 <0.50 <0.50 <2.5 <0.50 <0.50 <0.50 <12.5 <0.50 NS
Isopropylbenzene <2.0 <0.50 <0.50 <0.50 <2.5 <0.50 4.1 <0.50 <12.5 <0.50 NS
Isopropyl ether (IPE)3.9 <0.50 1.7 <0.50 5.2 <0.50 16.3 <0.50 <12.5 <0.50 NS
Methyl t-butyl Ether (MTBE)507 <0.50 131 <0.50 976 <0.50 <0.50 0.79 1,890 <0.50 30
Naphthalene <8.0 <2.0 <2.0 <2.0 <10.0 <2.0 7.4 <2.0 <50.0 <2.0 78
1,2,4-Trimethylbenzene <2.0 <0.50 <0.50 <0.50 <2.5 <0.50 0.61 <0.50 <12.5 <0.50 NS
m,p-Xylenes <4.0 <1.0 <1.0 <1.0 <5.0 <1.0 1.1 <1.0 <25.0 <1.0 NS
o-xylene <2.0 <0.50 <0.50 <0.50 <2.5 <0.50 2.4 <0.50 <12.5 <0.50 NS
Total Xylenes <6.0 <1.50 <1.50 <1.50 <7.5 <1.50 3.5 <1.50 <37.5 <1.50 780
Notes:
EPA Method number follows parameter in parenthesis
VOC = Volatile Organic Compound
NS = Not Specified; NA = Not Analyzed
All BDL = Target analytes below detection limit
Bold indicates exceeds standard
J= estimated value between reporting limit and detection limit
6
Table 5
Summary of Influent and Effluent Sample Results
General Store of Denver
Sherrills Ford, North Carolina
H&H Job No. GSD-050
February 2017 April 2017 July 2018 September 2018 December 2018
Hart & Hickman, PC
Sample ID INFLUENT EFFLUENT INFLUENT EFFLUENT INFLUENT EFFLUENT INFLUENT EFFLUENT INFLUENT EFFLUENT Daily
Sample Location Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Discharge
Date 3/22/2019 3/22/2019 6/21/2019 6/21/19 / 8/1/2019 9/13/2019 9/13/2019 1/15/2020 1/15/2020 4/16/2020 4/16/2020 Limit (µg/l)
Laboratory Parameters
Oil and Grease (1664) [mg/l]<5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <4.8 <5.0 <5.0 NS
Phenolics (420.1) [mg/l]<0.020 <0.020 <0.020 <0.20 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 300
Lead (200.7) [mg/l]<0.005 <0.005 0.0919 <0.005 0.007 <0.005 <0.005 <0.005 <0.005 <0.005 25
TSS [mg/l]<5.0 <2.5 <2.5 102/<2.5 25.2 <2.5 <10.0 <2.5 11.8 <2.5 30,000
VOCs (6230D/6200B) Units = µg/l
Benzene 489 <0.50 93.5 <0.50 47.1 <0.50 123 <0.50 38.9 <0.50 1.19
Bromodichloromethane <12.5 <0.50 <12.5 <0.50 <2.5 <0.50 <2.5 <0.50 <6.2 <0.50 NS
n-Butylbenzene <12.5 <0.50 <12.5 <0.50 <2.5 <0.50 <2.5 <0.50 <6.2 <0.50 NS
sec-Butylbenzene <12.5 <0.50 <12.5 <0.50 <2.5 <0.50 <2.5 <0.50 <6.2 <0.50 NS
Chlorodibromomethane <12.5 <0.50 <12.5 <0.50 <2.5 <0.50 <2.5 <0.50 <6.2 <0.50 NS
Chloroform <12.5 <0.50 <12.5 <0.50 <25.0 <5.0 <2.5 <0.50 <6.2 <0.50 NS
Isopropylbenzene <12.5 <0.50 <12.5 <0.50 <2.5 <0.50 2.7 <0.50 <6.2 <0.50 NS
Isopropyl ether (IPE)17.7 <0.50 <12.5 <0.50 4.9 <0.50 17.7 <0.50 14.5 <0.50 NS
Methyl t-butyl Ether (MTBE)2,840 <0.50 1,450 <0.50 817 <0.50 2,480 <0.50 2,160 <0.50 30
Naphthalene <50.0 <2.0 <25.0 <2.0 <10.0 <2.0 <10.0 <2.0 <25.0 <2.0 78
1,2,4-Trimethylbenzene <12.5 <0.50 <6.2 <0.50 <2.5 <0.50 <2.5 <0.50 <6.2 <0.50 NS
m,p-Xylenes <25.0 <1.0 <12.5 <1.0 <5.0 <1.0 <5.0 <1.0 <12.5 <1.0 NS
o-xylene <12.5 <0.50 <6.2 <0.50 <2.5 <0.50 <2.5 <0.50 <6.2 <0.50 NS
Total Xylenes <37.5 <1.50 <18.7 <1.50 <7.5 <1.50 <7.5 <1.50 <18.7 <1.50 780
Notes:
EPA Method number follows parameter in parenthesis
VOC = Volatile Organic Compound
NS = Not Specified; NA = Not Analyzed
All BDL = Target analytes below detection limit
Bold indicates exceeds standard
J= estimated value between reporting limit and detection limit
Table 5
Summary of Influent and Effluent Sample Results
General Store of Denver
Sherrills Ford, North Carolina
H&H Job No. GSD-050
March 2019 June 2019/August 20197 September 2019 January 2020 April 2020
Hart & Hickman, PC
Sample ID INFLUENT EFFLUENT INFLUENT EFFLUENT INFLUENT EFFLUENT INFLUENT EFFLUENT INFLUENT EFFLUENT
Sample Location Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent
Date 7/14/2020 7/14/2020 10/19/2020 10/19/2020 1/19/2021 1/19/2021 4/23/2021 4/23/2021 7/30/2021 7/30/2021
Laboratory Parameters
Oil and Grease (1664) [mg/l]<5.0 <5.0 <4.8 <4.9 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0
Phenolics (420.1) [mg/l]<0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020
Lead (200.7) [mg/l]<0.005 <0.005 <0.005 <0.005 8.1 <0.005 <0.005 <0.005 <0.005 <0.005
TSS [mg/l]<5.0 <2.5 5.1 <2.5 <5.0 <2.5 44.6 <2.5 7.4 <2.5
VOCs (6230D/6200B) Units = µg/l
Benzene 239 <0.50 160 <0.50 171 <0.50 14.5 <0.50 95 <0.50
Bromodichloromethane <5.0 <0.50 <5.0 <0.50 <5.0 <0.50 <6.2 <0.50 <6.2 <0.50
n-Butylbenzene <5.0 <0.50 <5.0 <0.50 <5.0 <0.50 <6.2 <0.50 <6.2 <0.50
sec-Butylbenzene <5.0 <0.50 <5.0 <0.50 <5.0 <0.50 <6.2 <0.50 <6.2 <0.50
Chlorodibromomethane <5.0 <0.50 <5.0 <0.50 <5.0 <0.50 <6.2 <0.50 <6.2 <0.50
Chloroform <5.0 <0.50 <5.0 <0.50 <5.0 <0.50 <6.2 <0.50 <6.2 <0.50
Isopropylbenzene <5.0 <0.50 <5.0 <0.50 <5.0 <0.50 <6.2 <0.50 <6.2 <0.50
Isopropyl ether (IPE)10.2 <0.50 10.6 <0.50 10.0 <0.50 11.0 <0.50 8.3 <0.50
Methyl t-butyl Ether (MTBE)1,620 <0.50 1,480 <0.50 1,390 <0.50 1,710 <0.50 1,220 <0.50
Naphthalene <20.0 <2.0 43.5 <2.0 <20.0 <2.0 <25.0 <2.0 <25.0 <2.0
1,2,4-Trimethylbenzene <5.0 <0.50 43.4 <0.50 <5.0 <0.50 <6.2 <0.50 <6.2 <0.50
m,p-Xylenes 10.4 <1.0 35.7 <1.0 <10.0 <1.0 <12.5 <1.0 <12.5 <1.0
o-xylene 6.0 <0.50 24.7 <0.50 <5.0 <0.50 <6.2 <0.50 <6.2 <0.50
Total Xylenes 16.4 <1.50 60.4 <1.50 <10.5 <1.50 <18.7 <1.50 <18.7 <1.50
Notes:
EPA Method number follows parameter in parenthesis
VOC = Volatile Organic Compound
NS = Not Specified; NA = Not Analyzed
All BDL = Target analytes below detection limit
Bold indicates exceeds standard
J= estimated value between reporting limit and detection limit
July 2020
Summary of Influent and Effluent Sample Results
Table 5
General Store of Denver
Sherrills Ford, North Carolina
H&H Job No. GSD-050
October 2020 January 2021 April 2021 July 2021
Hart & Hickman, PC
Sample ID INFLUENT EFFLUENT INFLUENT EFFLUENT INFLUENT EFFLUENT INFLUENT EFFLUENT INFLUENT EFFLUENT Daily
Sample Location Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Discharge
Date 11/19/2021 11/19/2021 1/27/2022 1/27/2022 4/22/2022 4/22/2022 7/21/2022 7/21/2022 10/27/2022 10/27/2022 Limit (µg/l)
Laboratory Parameters
Oil and Grease (1664) [mg/l]<4.9 <4.8 <4.8 <4.9 <4.8 <4.9 <4.9 <4.8 <4.9 <4.8 NS
Phenolics (420.1) [mg/l]<0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 300
Lead (200.7) [mg/l]0.0382 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 25
TSS [mg/l]16.0 <2.5 5.2 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 30,000
VOCs (6230D/6200B) Units = µg/l
Benzene 43.6 <0.50 96.9 <0.50 <2.5 <0.50 <2.5 <0.50 94.2 <0.50 1.19
Bromodichloromethane <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS
n-Butylbenzene <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS
sec-Butylbenzene <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS
Chlorodibromomethane <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS
Chloroform <2.5 <0.50 <2.5 <0.50 6.0 <0.50 <2.5 <0.50 <2.5 <0.50 NS
Isopropylbenzene <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS
Isopropyl ether (IPE)7.4 <0.50 6.1 <0.50 7.1 <0.50 4.8 <0.50 7.5 <0.50 NS
Methyl t-butyl Ether (MTBE)938 <0.50 798 <0.50 859 <0.50 653 <0.50 962 <0.50 30
Naphthalene <10.0 <2.0 <10.0 <2.0 <10.0 <2.0 <10.0 <2.0 <10.0 <2.0 78
1,2,4-Trimethylbenzene <2.5 <0.50 6.7 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS
m,p-Xylenes <5.0 <1.0 <5.0 <1.0 <5.0 <1.0 <5.0 <1.0 <5.0 <1.0 NS
o-xylene <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS
Total Xylenes <7.5 <1.50 <7.5 <1.50 <17.5 <1.50 <7.5 <1.50 <7.5 <1.50 780
Notes:
EPA Method number follows parameter in parenthesis
VOC = Volatile Organic Compound
NS = Not Specified; NA = Not Analyzed
All BDL = Target analytes below detection limit
Bold indicates exceeds standard
J= estimated value between reporting limit and detection limit
April 2022January 2022November 2021
Table 5
Summary of Influent and Effluent Sample Results
General Store of Denver
Sherrills Ford, North Carolina
H&H Job No. GSD-050
July 2022 October 2022
Hart & Hickman, PC
Sample ID INFLUENT EFFLUENT INFLUENT EFFLUENT INFLUENT EFFLUENT INFLUENT EFFLUENT Daily
Sample Location Influent Effluent Influent Effluent Influent Effluent Influent Effluent Discharge
Date 1/27/2023 1/27/2023 5/25/2023 5/25/2023 8/16/2023 8/16/2023 11/20/2023 11/20/2023 Limit (µg/l)
Laboratory Parameters
Oil and Grease (1664) [mg/l]<4.9 <4.8 <4.9 <4.9 <4.8 <4.8 <4.8 <4.9 NS
Phenolics (420.1) [mg/l]<0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 300
Lead (200.7) [mg/l]<0.005 <0.005 <0.025 <0.025 <0.025 <0.025 <5.0 <5.0 25
TSS [mg/l]<2.5 <2.5 7.1 <2.5 12.0 <2.5 6.5 <2.5 30,000
VOCs (6230D/6200B) Units = µg/l
Benzene <2.5 <0.50 76.0 <0.50 <2.5 <0.50 <2.5 <0.50 1.19
Bromodichloromethane <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS
n-Butylbenzene <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS
sec-Butylbenzene <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS
Chlorodibromomethane <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS
Chloroform <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS
Isopropylbenzene <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS
Isopropyl ether (IPE)5.9 <0.50 6.7 <0.50 6.8 <0.50 4.8 <0.50 NS
Methyl t-butyl Ether (MTBE)864 <0.50 922 <0.50 860 <0.50 621 <0.50 30
Naphthalene <10.0 <2.0 <10.0 <2.0 <10.0 <2.0 <10.0 <2.0 78
1,2,4-Trimethylbenzene <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 4.3 <0.50 NS
m,p-Xylenes <5.0 <1.0 <5.0 <1.0 <5.0 <1.0 <5.0 <1.0 NS
o-xylene <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS
Total Xylenes <7.5 <1.50 <7.5 <1.50 <7.5 <1.50 <7.5 <1.50 780
Notes:
EPA Method number follows parameter in parenthesis
VOC = Volatile Organic Compound
NS = Not Specified; NA = Not Analyzed
All BDL = Target analytes below detection limit
Bold indicates exceeds standard
J= estimated value between reporting limit and detection limit
January 2023/February 2023 May 2023
Table 5
Summary of Influent and Effluent Sample Results
General Store of Denver
Sherrills Ford, North Carolina
H&H Job No. GSD-050
August 2023 November 2023
Hart & Hickman, PC
Summary of Mass Removal - Groundwater Remediation System
General Store of Denver
Sherrills Ford, North Carolina
Benzene MTBE Benzene MTBE Benzene MTBE Benzene MTBE
8/13/2004 0 0 0 NA NA NA NA NA NA NA NA
10/15/2004 13,029.5 13,030 207 180 880 <1.0 <1.0 0.020 0.096 0.00031 0.0015
1/17/2005 32,960.0 19,931 212 20 1,400 <1.0 <1.0 0.0033 0.23 0.000035 0.0025
4/27/2005 73,990.5 41,031 410 13 870 <1.0 <1.0 0.0045 0.30 0.000045 0.0030
7/29/2005 101,581.0 27,591 297 NA NA NA NA 0.0030 0.20 0.000032 0.0022 Assumes same concentration as in April.
Sampling not conducted as system was
deactivated.
5/19/2006 0.0 0 0 NA NA <1.0 <1.0 NA NA NA NA System restarted and meter reset
7/31/2006 24,858.4 24,858 341 27 800 <1.0 <1.0 0.0056 0.17 0.000077 0.0023
10/27/2006 46,640.0 21,782 248 100 1,500 <1.0 <1.0 0.018 0.27 0.00021 0.0031
1/25/2007 78,791.4 32,151 357 <5.0 1,300 <0.50 <0.50 NA 0.35 NA 0.0039
4/20/2007 104,435.0 25,644 302 160 1,600 <0.50 <0.50 0.034 0.34 0.00040 0.0040
7/18/2007 129,696.0 25,261 284 6.6 1,200 <0.50 <0.50 0.0014 0.25 0.00002 0.0028
11/6/2007 147,570.0 17,874 161 12.6 1,910 <0.50 <0.50 0.0019 0.29 0.000017 0.0026
2/5/2008 0.0 22,750 250 <0.5 1,960 <0.5 <0.5 0.00 0.37 0.00 0.0041 meter reset to zero. Previous flow
5/6/2008 27,005.0 27,005 297 <5.0 1,390 <0.5 <0.5 0.00 0.31 0.00 0.0035
7/31/2008 43,514.8 16,510 192 <0.5 144 <0.5 <0.5 0.00 0.020 0.00 0.00023 power outage. System restarted.
10/10/2008 64,765.3 21,251 299 <0.5 1,870 <0.5 <0.5 0.00 0.33 0.00 0.0047
Comment
Surge tank transfer pump malfunctioning
during September O&M visit - system
down from approximately 09/26/07
through 11/02/07. Transfer pump motor
- system restarted that same day.
Table 6
H&H Job No. GSD-050
Date Reading
(gal)
Flow Since Previous
Date (gal)
Discharge
Rate (gpd)
Influent (µg/l)Effluent (µg/l)Pounds Removed Since
Previous Sample
Daily Removal Rate
(pounds)
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsxTable 64/5/2024
Table 6 (Page 1 of 6)
Hart & Hickman, PC
Summary of Mass Removal - Groundwater Remediation System
General Store of Denver
Sherrills Ford, North Carolina
Benzene MTBE Benzene MTBE Benzene MTBE Benzene MTBE
Comment
Table 6
H&H Job No. GSD-050
Date Reading
(gal)
Flow Since Previous
Date (gal)
Discharge
Rate (gpd)
Influent (µg/l)Effluent (µg/l)Pounds Removed Since
Previous Sample
Daily Removal Rate
(pounds)
1/29/2009 92,510.0 27,745 250 93.8 1,990 <0.5 <0.5 0.022 0.46 0.00020 0.0042
4/6/2009 103,640.0 11,130 166 <5.0 1,590 <0.5 <0.5 0.00 0.15 0.00 0.0022
7/31/2009 129,243.0 25,603 221 0.75 126 <0.5 <0.5 0.00016 0.027 0.0000014 0.00023
10/2/2009 152,601.0 23,358 244 17 1,100 <0.5 <0.5 0.0033 0.21 0.000053 0.0034 power outage. System restarted.
1/7/2010 2,869.6 22,000 220 <0.5 1,820 <0.5 <0.5 0.00 0.34 0.00 0.0035 December 2009, meter reset to zero. Previous flow estimated to be 220 gpd.
4/21/2010 26,567.0 23,697 228 <0.5 750 <0.5 <0.5 0.00 0.15 0.00 0.0014
7/22/2010 39,921.1 13,354 145 8.5 945 <0.5 <0.5 0.00095 0.11 0.000010 0.0011
likely due to a power outage; system
restarted that same day. System
restarted on August 8, 2010.
10/29/2010 48,582.0 8,661 87 17.0 1,100 <0.5 <0.5 0.0012 0.080 0.000012 0.00081 influent analytical results indicating new
1/11/2011 55,450.9 6,869 93 20.6 2,450 <0.5 <0.5 0.0012 0.14 0.000016 0.0019
4/29/2011 61,227.8 5,777 53 <2.5 753 <0.5 <0.5 0.00 0.036 0.00 0.00034 replaced in March 2011.
7/8/2011 68,814.5 7,587 108 <25.0 5,280 <0.50 <0.50 0.00 0.34 0.00 0.0048 meter reset to zero on 9/16/11
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsxTable 64/5/2024
Table 6 (Page 2 of 6)
Hart & Hickman, PC
Summary of Mass Removal - Groundwater Remediation System
General Store of Denver
Sherrills Ford, North Carolina
Benzene MTBE Benzene MTBE Benzene MTBE Benzene MTBE
Comment
Table 6
H&H Job No. GSD-050
Date Reading
(gal)
Flow Since Previous
Date (gal)
Discharge
Rate (gpd)
Influent (µg/l)Effluent (µg/l)Pounds Removed Since
Previous Sample
Daily Removal Rate
(pounds)
10/28/2011 202.4 8,886 89 20.2 1,220 <0.50 <0.50 0.0015 0.091 0.000013 0.00081 power outage - reset and restarted. Flow
1/27/2012 6,547.0 6,345 70 <5.0 916 <0.50 <0.50 0.00 0.049 0.000 0.00053 power outage - reset and restarted.
4/27/2012 15,364.3 8,817 85.9 2,930 <0.50 <0.50 0.0063 0.22 0.000070 0.0024
7/31/2012 39,056.4 23,692 249 <10.0 2,500 <0.50 <0.50 0.00 0.50 0.00 0.0052
10/31/2012 54,981.9 15,926 173 <10.0 2,870 <0.50 <0.50 0.00 0.38 0.00 0.0042
4/30/2013 79,565.2 24,583 136 <10.0 2,042 <0.50 <0.50 0.00 0.42 0.00 0.0023
to a power outage - reset and restarted. System shutdown on February 21, 2013
due to leaking carbon drums. Drums
2013.
7/30/2013 88,979.8 9,415 103 <10.0 2,160 <0.50 <0.50 0.00 0.17 0.00 0.0019 troubleshooted and restarted.
11/21/2013 9,705.2 18,500 162 18.4 3,350 <0.50 <0.50 0.0028 0.52 0.000025 0.0045
August 2013, meter reset to zero.
Previous flow estimated to be 164 gpd.
System off on arrival in November 2013
due to tripped breaker - breaker reset and
3/26/2014 33,272.0 23,567 189 18.4 3,350 <0.50 <0.50 0.0036 0.66 0.000029 0.0053 to leaking carbon drum. November 2013
effluent data utilized for removal rates.
8/15/2014 41,070.4 7,798 55 8.5 714 <0.50 <0.50 0.00055 0.047 0.0000039 0.00033 30, 2014. System restarted at that time.
10/31/2014 58,687.7 17,617 229 3.3 1,042 <0.50 <0.50 0.00049 0.15 0.0000063 0.0020
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsxTable 64/5/2024
Table 6 (Page 3 of 6)
Hart & Hickman, PC
Summary of Mass Removal - Groundwater Remediation System
General Store of Denver
Sherrills Ford, North Carolina
Benzene MTBE Benzene MTBE Benzene MTBE Benzene MTBE
Comment
Table 6
H&H Job No. GSD-050
Date Reading
(gal)
Flow Since Previous
Date (gal)
Discharge
Rate (gpd)
Influent (µg/l)Effluent (µg/l)Pounds Removed Since
Previous Sample
Daily Removal Rate
(pounds)
1/23/2015 68,443.6 9,756 116 <5.0 674 <0.50 <0.50 0.00 0.055 0.00 0.00065
4/22/2015 78,407.3 9,964 112 <2.5 444 <0.50 <0.50 0.00 0.037 0.00 0.00021
8/21/2015 0.0 7,516 62 <2.5 530 <0.50 <0.50 0.00 0.033 0.00 0.00028
July 2015, meter reset to zero. Previous
flow estimated to be 55 gpd. System off in 06/15, 07/15, & 8/15 likely due to a
power outage - reset and restarted.
10/12/2015 5,728.3 5,728 110 3.1 1,130 <0.50 <0.50 0.00015 0.054 0.0000029 0.0010
belt tightened and system restarted.
1/23/2016 17,269.0 11,541 112 <5.0 674 0.0 <0.50 0.00 0.065 0.00 0.00063
power outage - reset and restarted.
System off on arrival (2/8/16) due to a
dislodged fernco coupler on the air stripper - fernco coupler replaced and
4/14/2016 28,251.2 10,982 134 <5.0 509 <0.50 <0.50 0.00 0.047 0.00 0.00057
8/18/2016 40,163.9 11,913 95 1.8 199 <0.50 <0.50 0.00018 0.020 0.00000086 0.00016 and restarted.
10/28/2016 43,956.5 3,793 53 <2.5 591 <0.50 <0.50 0.00 0.019 0.00 0.00026
2/9/2017 47,335.0 3,379 32 <2.0 507 <0.50 <0.50 0.00 0.014 0.00 0.00014
likely due to a power outage System
restarted.
4/28/2017 54,297.3 6,962 89 <0.50 131 <0.50 <0.50 0.00 0.0076 0.00 0.00010
8/15/2017 66,737.0 12,440 114 <0.50 131 <0.50 <0.50 0.00 0.014 0.00 0.00013
leaking drums. DEQ requested in
September 2017 to shutdown system
pending further review. System
winterized and carbon replaced on
11/17/17.
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsxTable 64/5/2024
Table 6 (Page 4 of 6)
Hart & Hickman, PC
Summary of Mass Removal - Groundwater Remediation System
General Store of Denver
Sherrills Ford, North Carolina
Benzene MTBE Benzene MTBE Benzene MTBE Benzene MTBE
Comment
Table 6
H&H Job No. GSD-050
Date Reading
(gal)
Flow Since Previous
Date (gal)
Discharge
Rate (gpd)
Influent (µg/l)Effluent (µg/l)Pounds Removed Since
Previous Sample
Daily Removal Rate
(pounds)
7/2/2018 435.0 435 1.4 8.6 976 <0.50 <0.50 0.000031 0.0036 0.000000051 0.000011
electrician installed new surge tank floats
for malfunctioning floats on 6/12/18. Replaced malfunctioning flow meter on
7/2/18. Due to malfunctioning pumps,
new extraction pumps installed 7/2/18.
9/26/2018 12,118.2 11,683 136 167 <0.50 <0.50 0.79 0.016 0.00 0.00019 0.00
12/20/2018 24,975.0 12,857 151 253 1,890 <0.50 <0.50 0.027 0.20 0.00032 0.0024 level alarm (1/25/19). System restarted
12/18. Faulty contactor replaced and
system restarted 2/15/19.
3/22/2019 36,410.5 11,436 124 489 2,840 <0.50 <0.50 0.047 0.27 0.00051 0.0030
6/21/2019 49,331.2 12,921 142 93.5 1,450 <0.50 <0.50 0.010 0.16 0.00011 0.0017 & 8/27/19) likely due to a power outage.
9/13/2019 55,444.4 6,113 73 47.1 817 <0.50 <0.50 0.0024 0.042 0.000029 0.00050 disruption. Duke power called and meter
1/15/2020 69,649.9 14,206 115 123 2,480 <0.50 <0.50 0.015 0.29 0.00012 0.0024
2/13/20) likely due to a power outage.
System restarted each time. Electrician
contacted to troubleshoot for potential
electrical component malfunctions.
4/15/2020 71,859.5 2,210 24 38.9 2,160 <0.50 <0.50 0.00072 0.040 0.0000079 0.00044
7/14/2020 78,202.0 6,343 70 239 1,620 <0.50 <0.50 0.013 0.086 0.00014 0.0010
8/15/20) likely due to a power outage.
System restarted. Electrician
troubleshooted system for potential
electrical component malfunctions. No
malfunctions noted. Uninteruptable power supply recommended by
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsxTable 64/5/2024
Table 6 (Page 5 of 6)
Hart & Hickman, PC
Summary of Mass Removal - Groundwater Remediation System
General Store of Denver
Sherrills Ford, North Carolina
Benzene MTBE Benzene MTBE Benzene MTBE Benzene MTBE
Comment
Table 6
H&H Job No. GSD-050
Date Reading
(gal)
Flow Since Previous
Date (gal)
Discharge
Rate (gpd)
Influent (µg/l)Effluent (µg/l)Pounds Removed Since
Previous Sample
Daily Removal Rate
(pounds)
10/19/2020 83,490.1 5,288 55 160 1,480 <0.50 <0.50 0.0071 0.065 0.000073 0.00068 10/19/20) likely due to a power outage.
System restarted. Uninteruptable power supply installed on system by electrician.
1/19/2021 100,544.0 17,054 185 171 1,390 <0.50 <0.50 0.024 0.20 0.00027 0.0022
4/23/2021 115,280.0 14,736 157 14.5 1,710 <0.50 <0.50 0.0018 0.21 0.000019 0.0022
7/30/2021 125,241.0 9,961 102 95 1,220 <0.50 <0.50 0.0079 0.10 0.000081 0.0010 blown fuse in the control panel. Fuse
11/19/2021 138,691.0 13,450 120 43.6 938 <0.50 <0.50 0.0049 0.11 0.000044 0.00094
1/27/2022 145,422.0 6,731 98 96.9 798 <0.50 <0.50 0.0055 0.045 0.000079 0.00065
4/22/2022 153,101.0 7,679 90 0.0 859 <0.50 <0.50 0.00 0.055 0.00 0.00065
7/21/2022 160,652.0 7,551 84 0.0 653 <0.50 <0.50 0.00 0.041 0.00 0.00046
10/27/2022 167,352.0 6,700 68 94.2 962 <0.50 <0.50 0.0053 0.054 0.000054 0.00055
1/27/2023 172,430.0 5,078 55 0.0 864 <0.50 <0.50 0.00 0.037 0.00 0.00040
5/25/2023 179,934.0 7,504 64 76.0 922 <0.50 <0.50 0.0048 0.058 0.000040 0.00049
8/16/2023 185,488.0 5,554 67 0.0 860 <0.50 <0.50 0.00 0.040 0.00 0.00048
11/20/2023 191,932.0 6,444 67 0.0 621 <0.50 <0.50 0.00 0.033 0.00 0.00035 System shutdown on 12/29/23 to
begin MNA closure sampling period.Total ----963,498 NA NA NA NA 0.33 11.29 NA NA
Notes:
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsxTable 64/5/2024
Table 6 (Page 6 of 6)
Hart & Hickman, PC
Active
Y5
Active
Y10
Active
Y11
Active
Y12
Active
Y13
Active
Y13.5
Active
Y14
Active
Y14.5
Active
Y15
Active
Y15.5
Active
Y16
Active
Y16.5
Active
Y17
Active
Y17.5
Active
Y18
Active
Y18.5
Active
Y19
Inactive
Y19.5
Inactive
Y20
Inactive
Y20.5
Inactive
Y21
Inactive
Y21.5
Inactive
Y22
Inactive
Y22.5
Inactive
Y23
Inactive
Y23.5
Inactive
Y24
Inactive
Y24.5
Inactive
Y25
Projected Mass Reduction (%):0%10.0%20.0%30.0%40.0%50.0%52.5%55.0%57.5%60.0%62.5%65.0%67.5%70.0%72.5%75.0%77.5%80.0%81.5%83.0%84.5%86.0%87.5%89.0%90.5%92.0%93.5%95.0%96.0%97.0%97.9%
Soil Source Zone Mass (lbs):N/A1 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
Smear Source Zone Mass (lbs):1 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
Groundwater Zone Mass (lbs):7.13 6.42 5.70 4.99 4.28 3.57 3.05 3.21 3.03 2.85 2.67 2.50 2.32 2.14 1.96 1.78 1.60 1.43 1.32 1.21 1.11 1.00 0.89 0.78 0.68 0.57 0.46 0.36 0.29 0.21 0.15
Total Mass: Baseline/Milestone 7.13 6.42 5.70 4.99 4.28 3.57 3.05 3.21 3.03 2.85 2.67 2.50 2.32 2.14 1.96 1.78 1.60 1.43 1.32 1.21 1.11 1.00 0.89 0.78 0.68 0.57 0.46 0.36 0.29 0.21 0.15
Initial 10/2009 10/2014 10/2015 10/2016 4/2017 11/2017 6/2018 12/2018 6/2019 1/2020 7/2020 1/2021 7/2021 1/2022 7/2022 1/2023 8/2023 2/2024 End /
Measured Mass 2
Soil Source Zone:1 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
Smear Source Zone:N/A1 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
Groundwater Zone:7.13 11.08 5.84 3.90 3.42 0.91 6.36 4.85 5.84 2.61 4.67 3.49 2.92 2.46 2.05 1.55 1.69 1.90 0.77
Removed Mass 3 -
Excavated from Soil/Smear:N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
Extracted as Vapor/Gas:N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
Extracted as Liquid:0 4.51 4.40 0.18 0.02 0.02 0.01 0.14 0.25 0.48 0.36 0.14 0.29 0.32 0.16 0.10 0.10 0.10 0.07 Total Mass Removed
(est ):0 4.51 4.40 0.18 0.02 0.02 0.01 0.14 0.25 0.48 0.36 0.14 0.29 0.32 0.16 0.10 0.10 0.10 0.07
Revised Total Mass (est.)2 7.13 11.08 5.84 3.90 3.42 0.91 6.36 4.85 5.84 2.61 4.67 3.49 2.92 2.46 2.05 1.55 1.69 1.90 0.77
4 0%-55%47%33%12%73%-596%24%-20%55%-79%25%16%16%17%24%-9%-12%59%
Reference Milestone (label from
above)Baseline Active
Y5
Active
Y10
Active
Y11
Active
Y12
Active
Y13
Active
Y13.5
Active
Y14
Active
Y14.5
Active
Y15
Active
Y15.5
Active
Y16
Active
Y16.5
Active
Y17
Active
Y17.5
Active
Y18
Active
Y18.5
Active
Y19
Inactive
Y19.5
Inactive
Y20
Inactive
Y20.5
Inactive
Y21
Inactive
Y21.5
Inactive
Y22
Inactive
Y22.5
Inactive
Y23
Inactive
Y23.5
Inactive
Y24
Inactive
Y24.5
Inactive
Y25 Closure
Reference Milestone (value from
above)7.13 6.42 5.70 4.99 4.28 3.57 3.05 3.21 3.03 2.85 2.67 2.50 2.32 2.14 1.96 1.78 1.60 1.43 1.32 1.21 1.11 1.00 0.89 0.78 0.68 0.57 0.46 0.36 0.29 0.21 0.15
Reduction Progress vs
Milestone5 0%-73%-2%22%20%74%-109%-51%-93%8%-75%-40%-26%-15%-5%13%-5%-33%42%
1. Remediation of soil not required by DEQ due to low levels remaining in soil; therefore, soil mass not included in total mass milestones. Approved Corrective Action Plan for groundwater remediation of fractured bedrock only.
2. Mass calculated by multiplying the analytical results by the representative volume using: Area of Water (v) x Plume Thickness (d) x Average Concentrations of Benzene and MTBE (c) x Porosity of Aquifer (n) (see below for assumptions).
3. Removed mass calculated by system effluent monitoring, multiplied by total volume extracted by the system during that period.
4. Reduction rate equals the % reduction from the prior mass (current Total Mass ÷ prior Total Mass).
5. Reduction progress vs milestone equals the current mass reduction % progress (1 - (Revised Total Mass ÷ Applicable Milestone)). Zero or positive values indicate that the associated milestone has been reached.
Assumptions:
Porosity (n) = 0.1 for fractured bedrock
Plume thickness (d) = 30 ft
Initial Average Concentrations (c):
Benzene Source Area = 260 ppb (avg. of MW-3D/5D on 10/16/03)
MTBE Source Area = 1,345 ppb (avg. of MW-3D/5D on 10/16/03)
Benzene Remaining Plume Area = 7.45 ppb (avg. of supply wells 16/62 on 10/16/03)
MTBE Remaining Plume Area = 45.5 ppb (avg. of supply wells 16/62 on 10/16/03)
Table 7
Evaluation of Change in Contaminant Mass
General Store of Denver
Sherrills Ford, North Carolina
H&H Job No. GSD-050
Initial Mass Estimate /
Projected Milestones (from
CAP/Calculated)
Initial
Baseline
Milestones1 End /
Closure
Measured / Calculated
Change in Contaminant
Mass (from sampling)
Milestone Sampling / Measurement Event Dates1
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Monitoring Report/Table 7 Milestone.xlsx4/5/2024
Table 7 (Page 1 of 1)
Hart & Hickman, PC
USGS The National Map: National Boundaries Dataset, 3DEP ElevationProgram, Geographic Names Information System, National HydrographyDataset, National Land Cover Database, National Structures Dataset,and National Transportation Dataset; USGS Global Ecosystems; U.S.Census Bureau TIGER/Line data; USFS Road Data; Natural Earth Data;U.S. Department of State Humanitarian Information Unit; and NOAANational Centers for Environmental Information, U.S. Coastal ReliefModel. Data refreshed May, 2020.
SITE LOCATION MAP
GENERAL STORE OF DENVERSHERRILLS FORD, NORTH CAROLINA
DATE: 4-5-24
JOB NO: GSD-050
REVISION NO: 0
FIGURE NO: 1
2923 South Tryon Street - Suite 100Charlotte, North Carolina 28203704-586-0007 (p) 704-586-0373 (f)License # C-1269 / # C-245 Geology
TITLE
PROJECT
0 2,000 4,000
SCALE IN FEET
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U.S.G.S. QUADRANGLE MAP
DENVER, NORTH CAROLINA 2019
QUADRANGLE7.5 MINUTE SERIES (TOPOGRAPHIC)
MW-2D
MW-2
MW-3
MW-4D
MW-6D
MW-4
MT. PLEASA
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(ABANDONED)
CAN
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ALUMINUM
BUILDINGS
BACH WELL
HOUSE
THE GENERAL STORE OF
DENVER
HARDWARE
STORE
ASPHALT
CONCRETE
DRIVEFORMER 1,000 GALLON
KEROSENE UST
WSW
MW-5D
PROPANE
TANK
EMERALD ISLE
TRAILER PARK
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TREATMENT SYSTEM
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RECOVERY
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DISCHARGE TRENCH
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LOCATION WITH RIPRAP
DRAINAGE BASIN
STORMWATER SWALE
LIGHT
SIGN
CHRISTENBURY WATER
SUPPLY WELL
FORMER DAYCARE
WATER SUPPLY WELL
MW-3D
MW-1D
e
w
REVISION NO. 0
JOB NO. GSD-050
DATE: 4-5-24
FIGURE NO. 2
GENERAL STORE OF DENVER
SHERRILLS FORD, NORTH CAROLINA
SITE LAYOUT
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
LEGEND
PROPERTY LINE
STORMWATER PIPING
SUBSURFACE WATER LINE
SUBSURFACE ELECTRICAL LINE
GROUNDWATER TREATMENT TRENCH
2x2-IN STEEL ACCESS VAULT
NCDENR WELL
MONITORING WELL
WATER SUPPLY WELL
POWER POLE
UST INCLUDING SIZE OF TANK
(GALLONS)
KEROSENE
DIESEL
GASOLINE
STORMWATER CATCH BASIN
CULVERT
GRASS
GRASS
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BACH WELL INACTIVE
1500' RADIUS
REVISION NO. 0
JOB NO. GSD-050
DATE: 4-5-24
FIGURE NO. 3
GENERAL STORE OF DENVER
SHERRILLS FORD, NORTH CAROLINA
WATER SUPPLY WELL SURVEY MAP
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
LEGEND
PROPERTY LINE
CREEK
WATER SUPPLY WELL LOCATION
COMMUNITY WATER SUPPLY WELL
LOCATION
RED SYMBOLS INDICATE INACTIVE WELL
LAND TRACT #
MONITORING WELL
(APPROXIMATELY 50 FT)
DEEP MONITORING WELL
(APPROXIMATELY 85 FT)
2
NOTES:
1. MTBE = METHYL tert-BUTYL ETHER
NS = NOT SAMPLED
DATE 11/23 2/24
BENZENE <0.50 <0.50
MTBE <0.50 <0.50
SAMPLE DATE
CONCENTRATION
(ųg/L)CONSTITUENT
DATE 11/23 2/24
BENZENE NS NS
MTBE NS NS
DATE 11/23 2/24
BENZENE <0.50 <0.500
MTBE <0.50 <1.00
DATE 11/23 2/24
BENZENE <0.50 <0.500
MTBE <0.50 <1.00
NS
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(ABANDONED)
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O
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ALUMINUM
BUILDINGS
BACH WELL
HOUSE
THE GENERAL STORE OF
DENVER
HARDWARE
STORE
ASPHALT
CONCRETE
DRIVEFORMER 1,000 GALLON
KEROSENE UST
WSW
MW-5D
PROPANE
TANK
EMERALD ISLE
TRAILER PARK
DIESEL
DISPENSER
MW-5
DENR
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(NO NAME)
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SW
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L
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SW
A
L
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TREATMENT SYSTEM
BUILDING
RECOVERY
WELL TRENCH
DISCHARGE TRENCH
SYSTEM DISCHARGE
LOCATION WITH RIPRAP
DRAINAGE BASIN
STORMWATER SWALE
LIGHT
SIGN
CHRISTENBURY WATER
SUPPLY WELL
FORMER DAYCARE
WATER SUPPLY WELL
(37.41)
(38.45)
37
35
37
36
MW-3D
35
36
MW-1D
(39.66)
(34.63)
38
38
39
39
e
w
(38.45)
NOTES:
1. ELEVATION BASED ON ARBITRARY DATUM.
2. * = GROUNDWATER ELEVATION NOT USED FOR
CONTOURING.REVISION NO. 0
JOB NO. GSD-050
DATE: 4-5-24
FIGURE NO. 4
GENERAL STORE OF DENVER
SHERRILLS FORD, NORTH CAROLINA
DEEP WELL GROUNDWATER ELEVATIONS
(AUGUST 2023)
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
LEGEND
PROPERTY LINE
STORMWATER PIPING
SUBSURFACE WATER LINE
SUBSURFACE ELECTRICAL LINE
GROUNDWATER TREATMENT TRENCH
2x2-IN STEEL ACCESS VAULT
NCDENR WELL
MONITORING WELL
WATER SUPPLY WELL
POWER POLE
UST INCLUDING SIZE OF TANK
(GALLONS)
KEROSENE
DIESEL
GASOLINE
STORMWATER CATCH BASIN
CULVERT
GROUNDWATER ELEVATION CONTOUR
GROUNDWATER ELEVATION (FT)
GRASS
GRASS
GRASS
GRASS
GRASS
GRASS
39
S:
\
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MW-2D
MW-2
MW-3
MW-4D
MW-6D
MW-4
MT. PLEASA
N
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.
NC
H
I
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#
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0
MW-1
(ABANDONED)
CAN
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Y
ALUMINUM
BUILDINGS
BACH WELL
HOUSE
THE GENERAL STORE OF
DENVER
HARDWARE
STORE
ASPHALT
CONCRETE
DRIVEFORMER 1,000 GALLON
KEROSENE UST
WSW
MW-5D
PROPANE
TANK
EMERALD ISLE
TRAILER PARK
DIESEL
DISPENSER
MW-5
DENR
MW-06D
DENR
MW-05
HAI
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(for
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RES
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RESCUE
SQUAD
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(NO NAME)
OVE
R
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A
N
G
SW
A
L
E
SW
A
L
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TREATMENT SYSTEM
BUILDING
RECOVERY
WELL TRENCH
DISCHARGE TRENCH
SYSTEM DISCHARGE
LOCATION WITH RIPRAP
DRAINAGE BASIN
STORMWATER SWALE
LIGHT
SIGN
CHRISTENBURY WATER
SUPPLY WELL
FORMER DAYCARE
WATER SUPPLY WELL
MW-3D
MW-1D
e
w
NOTES:
1. MTBE = METHYL tert-BUTYL ETHER
REVISION NO. 0
JOB NO. GSD-050
DATE: 4-5-24
FIGURE NO. 5
GENERAL STORE OF DENVER
SHERRILLS FORD, NORTH CAROLINA
BENZENE AND MTBE IN GROUNDWATER
(FEBRUARY 2024)
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
LEGEND
ESTIMATED SOURCE AREA BENZENE/MTBE
PLUME UTILIZED IN MASS CALCULATIONS
PROPERTY LINE
STORMWATER PIPING
SUBSURFACE WATER LINE
SUBSURFACE ELECTRICAL LINE
GROUNDWATER TREATMENT TRENCH
2x2-IN STEEL ACCESS VAULT
NCDENR WELL
MONITORING WELL
WATER SUPPLY WELL
POWER POLE
UST INCLUDING SIZE OF TANK
(GALLONS)
KEROSENE
DIESEL
GASOLINE
STORMWATER CATCH BASIN
CULVERT
GRASS
GRASS
GRASS
GRASS
GRASS
GRASS
MW-3D
BENZENE <5.0
MTBE 1,480
SAMPLE ID
CONCENTRATION
(µg/L)CONSTITUENT
MW-3D
BENZENE <5.00
MTBE 616
MW-5D
BENZENE <0.500
MTBE <1.00
S:
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GENERAL STORE OF DENVER
SHERRILLS FORD, NORTH CAROLINA
REVISION NO. 0
JOB NO. GSD-050
DATE: 4-5-24
FIGURE NO. 6
TREATMENT SYSTEM SCHEMATIC
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
S:
\
A
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P
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ESTIMATED EXTENT OF BENZENE AND
MTBE GROUNDWATER IMPACTS PRIOR TO
REMEDIATION
GENERAL STORE OF DENVER
SHERRILLS FORD, NORTH CAROLINA
REVISION NO. 0
JOB NO. GSD-050
DATE: 4-5-24
FIGURE NO. 7
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
S:
\
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ESTIMATED EXTENT OF CURRENT BENZENE
AND MTBE GROUNDWATER IMPACTS
GENERAL STORE OF DENVER
SHERRILLS FORD, NORTH CAROLINA
REVISION NO. 0
JOB NO. GSD-050
DATE: 4-5-24
FIGURE NO. 8
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
S:
\
A
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4
4
Appendix A
Laboratory Analytical Reports and Chain-of-Custody Forms
#=CL#
December 04, 2023
LIMS USE: FR - STEVE LIBBEY
LIMS OBJECT ID: 92699610
92699610
Project:
Pace Project No.:
RE:
Steve Libbey
Hart & Hickman
2923 South Tryon Street
Charlotte, NC 28203
GSD.050
Dear Steve Libbey:
Enclosed are the analytical results for sample(s) received by the laboratory on November 20, 2023. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor M Cannon
taylor.cannon@pacelabs.com
Project Manager
704-977-0943
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 1 of 31
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92699610
GSD.050
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 2 of 31
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92699610
GSD.050
Lab ID Sample ID Matrix Date Collected Date Received
92699610001 INFLUENT Water 11/20/23 14:00 11/20/23 15:30
92699610002 EFFLUENT Water 11/20/23 13:30 11/20/23 15:30
92699610003 WSW-16 Water 11/20/23 14:25 11/20/23 15:30
92699610004 WSW-KR2 Water 11/20/23 14:45 11/20/23 15:30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 3 of 31
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92699610
GSD.050
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92699610001 INFLUENT EPA 1664B 1 PASI-CDVR
EPA 6010D 1 PASI-ADBB1
SM 6200B 63 PASI-CJJK
SM 2540D-2015 1 PASI-AJAY
EPA 420.4 Rev 1.0 1993 1 PASI-AARJ
92699610002 EFFLUENT EPA 1664B 1 PASI-CDVR
EPA 6010D 1 PASI-ADBB1
SM 6200B 63 PASI-CSAS
SM 2540D-2015 1 PASI-AJAY
EPA 420.4 Rev 1.0 1993 1 PASI-AARJ
92699610003 WSW-16 SM 6200B 63 PASI-CSAS
92699610004 WSW-KR2 SM 6200B 63 PASI-CSAS
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 4 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92699610
GSD.050
Sample:INFLUENT Lab ID:92699610001 Collected:11/20/23 14:00 Received:11/20/23 15:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 1664B
Pace Analytical Services - Charlotte
HEM, Oil and Grease
Oil and Grease ND mg/L 11/29/23 11:154.8 1
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services - Asheville
6010 MET ICP
Lead ND ug/L 12/01/23 16:45 7439-92-111/21/23 12:005.0 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 11/28/23 16:34 71-43-22.5 5
Bromobenzene ND ug/L 11/28/23 16:34 108-86-12.5 5
Bromochloromethane ND ug/L 11/28/23 16:34 74-97-52.5 5
Bromodichloromethane ND ug/L 11/28/23 16:34 75-27-42.5 5
Bromoform ND ug/L 11/28/23 16:34 75-25-22.5 5
Bromomethane ND ug/L 11/28/23 16:34 74-83-925.0 5
n-Butylbenzene ND ug/L 11/28/23 16:34 104-51-82.5 5
sec-Butylbenzene ND ug/L 11/28/23 16:34 135-98-82.5 5
tert-Butylbenzene ND ug/L 11/28/23 16:34 98-06-62.5 5
Carbon tetrachloride ND ug/L 11/28/23 16:34 56-23-52.5 5
Chlorobenzene ND ug/L 11/28/23 16:34 108-90-72.5 5
Chloroethane ND ug/L 11/28/23 16:34 75-00-35.0 5
Chloroform ND ug/L 11/28/23 16:34 67-66-32.5 5
Chloromethane ND ug/L 11/28/23 16:34 74-87-35.0 5
2-Chlorotoluene ND ug/L 11/28/23 16:34 95-49-82.5 5
4-Chlorotoluene ND ug/L 11/28/23 16:34 106-43-42.5 5
1,2-Dibromo-3-chloropropane ND ug/L 11/28/23 16:34 96-12-85.0 5
Dibromochloromethane ND ug/L 11/28/23 16:34 124-48-12.5 5
1,2-Dibromoethane (EDB)ND ug/L 11/28/23 16:34 106-93-42.5 5
Dibromomethane ND ug/L 11/28/23 16:34 74-95-32.5 5
1,2-Dichlorobenzene ND ug/L 11/28/23 16:34 95-50-12.5 5
1,3-Dichlorobenzene ND ug/L 11/28/23 16:34 541-73-12.5 5
1,4-Dichlorobenzene ND ug/L 11/28/23 16:34 106-46-72.5 5
Dichlorodifluoromethane ND ug/L 11/28/23 16:34 75-71-82.5 5
1,1-Dichloroethane ND ug/L 11/28/23 16:34 75-34-32.5 5
1,2-Dichloroethane ND ug/L 11/28/23 16:34 107-06-22.5 5
1,1-Dichloroethene ND ug/L 11/28/23 16:34 75-35-42.5 5
cis-1,2-Dichloroethene ND ug/L 11/28/23 16:34 156-59-22.5 5
trans-1,2-Dichloroethene ND ug/L 11/28/23 16:34 156-60-52.5 5
1,2-Dichloropropane ND ug/L 11/28/23 16:34 78-87-52.5 5
1,3-Dichloropropane ND ug/L 11/28/23 16:34 142-28-92.5 5
2,2-Dichloropropane ND ug/L 11/28/23 16:34 594-20-72.5 5
1,1-Dichloropropene ND ug/L 11/28/23 16:34 563-58-62.5 5
cis-1,3-Dichloropropene ND ug/L 11/28/23 16:34 10061-01-52.5 5
trans-1,3-Dichloropropene ND ug/L 11/28/23 16:34 10061-02-62.5 5
Diisopropyl ether 4.8 ug/L 11/28/23 16:34 108-20-32.5 5
Ethylbenzene ND ug/L 11/28/23 16:34 100-41-42.5 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 5 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92699610
GSD.050
Sample:INFLUENT Lab ID:92699610001 Collected:11/20/23 14:00 Received:11/20/23 15:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Hexachloro-1,3-butadiene ND ug/L 11/28/23 16:34 87-68-310.0 5
Isopropylbenzene (Cumene)ND ug/L 11/28/23 16:34 98-82-82.5 5
Methylene Chloride ND ug/L 11/28/23 16:34 75-09-210.0 5
Methyl-tert-butyl ether 621 ug/L 11/28/23 16:34 1634-04-42.5 5
Naphthalene ND ug/L 11/28/23 16:34 91-20-310.0 5
n-Propylbenzene ND ug/L 11/28/23 16:34 103-65-12.5 5
Styrene ND ug/L 11/28/23 16:34 100-42-52.5 5
1,1,1,2-Tetrachloroethane ND ug/L 11/28/23 16:34 630-20-62.5 5
1,1,2,2-Tetrachloroethane ND ug/L 11/28/23 16:34 79-34-52.5 5
Tetrachloroethene ND ug/L 11/28/23 16:34 127-18-42.5 5
Toluene ND ug/L 11/28/23 16:34 108-88-32.5 5
1,2,3-Trichlorobenzene ND ug/L 11/28/23 16:34 87-61-610.0 5
1,2,4-Trichlorobenzene ND ug/L 11/28/23 16:34 120-82-110.0 5
1,1,1-Trichloroethane ND ug/L 11/28/23 16:34 71-55-62.5 5
1,1,2-Trichloroethane ND ug/L 11/28/23 16:34 79-00-52.5 5
Trichloroethene ND ug/L 11/28/23 16:34 79-01-62.5 5
Trichlorofluoromethane ND ug/L 11/28/23 16:34 75-69-45.0 5
1,2,3-Trichloropropane ND ug/L 11/28/23 16:34 96-18-42.5 5
1,2,4-Trimethylbenzene 4.3 ug/L 11/28/23 16:34 95-63-62.5 5
1,3,5-Trimethylbenzene ND ug/L 11/28/23 16:34 108-67-82.5 5
Vinyl chloride ND ug/L 11/28/23 16:34 75-01-45.0 5
m&p-Xylene ND ug/L 11/28/23 16:34 179601-23-15.0 5
o-Xylene ND ug/L 11/28/23 16:34 95-47-62.5 5
Surrogates
1,2-Dichloroethane-d4 (S)95 %11/28/23 16:34 17060-07-070-130 5
4-Bromofluorobenzene (S)96 %11/28/23 16:34 460-00-470-130 5
Toluene-d8 (S)98 %11/28/23 16:34 2037-26-570-130 5
Analytical Method: SM 2540D-2015
Pace Analytical Services - Asheville
2540D Total Suspended Solids
Total Suspended Solids 6.5 mg/L 11/22/23 10:492.5 1
Analytical Method: EPA 420.4 Rev 1.0 1993 Preparation Method: EPA 420.4 Rev 1.0 1993
Pace Analytical Services - Asheville
420.4 Phenolics, Total
Phenolics, Total Recoverable ND mg/L 11/29/23 16:01 64743-03-911/29/23 12:580.020 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 6 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92699610
GSD.050
Sample:EFFLUENT Lab ID:92699610002 Collected:11/20/23 13:30 Received:11/20/23 15:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 1664B
Pace Analytical Services - Charlotte
HEM, Oil and Grease
Oil and Grease ND mg/L 11/29/23 11:154.9 1
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services - Asheville
6010 MET ICP
Lead ND ug/L 12/01/23 17:07 7439-92-111/21/23 12:005.0 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 11/30/23 00:37 71-43-20.50 1
Bromobenzene ND ug/L 11/30/23 00:37 108-86-10.50 1
Bromochloromethane ND ug/L 11/30/23 00:37 74-97-50.50 1
Bromodichloromethane ND ug/L 11/30/23 00:37 75-27-40.50 1
Bromoform ND ug/L 11/30/23 00:37 75-25-20.50 1
Bromomethane ND ug/L 11/30/23 00:37 74-83-95.0 1
n-Butylbenzene ND ug/L 11/30/23 00:37 104-51-80.50 1
sec-Butylbenzene ND ug/L 11/30/23 00:37 135-98-80.50 1
tert-Butylbenzene ND ug/L 11/30/23 00:37 98-06-60.50 1
Carbon tetrachloride ND ug/L 11/30/23 00:37 56-23-50.50 1
Chlorobenzene ND ug/L 11/30/23 00:37 108-90-70.50 1
Chloroethane ND ug/L 11/30/23 00:37 75-00-31.0 1
Chloroform ND ug/L 11/30/23 00:37 67-66-30.50 1
Chloromethane ND ug/L 11/30/23 00:37 74-87-31.0 1
2-Chlorotoluene ND ug/L 11/30/23 00:37 95-49-80.50 1
4-Chlorotoluene ND ug/L 11/30/23 00:37 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 11/30/23 00:37 96-12-81.0 1
Dibromochloromethane ND ug/L 11/30/23 00:37 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 11/30/23 00:37 106-93-40.50 1
Dibromomethane ND ug/L 11/30/23 00:37 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 11/30/23 00:37 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 11/30/23 00:37 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 11/30/23 00:37 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 11/30/23 00:37 75-71-80.50 1
1,1-Dichloroethane ND ug/L 11/30/23 00:37 75-34-30.50 1
1,2-Dichloroethane ND ug/L 11/30/23 00:37 107-06-20.50 1
1,1-Dichloroethene ND ug/L 11/30/23 00:37 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 11/30/23 00:37 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 11/30/23 00:37 156-60-50.50 1
1,2-Dichloropropane ND ug/L 11/30/23 00:37 78-87-50.50 1
1,3-Dichloropropane ND ug/L 11/30/23 00:37 142-28-90.50 1
2,2-Dichloropropane ND ug/L 11/30/23 00:37 594-20-70.50 1
1,1-Dichloropropene ND ug/L 11/30/23 00:37 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 11/30/23 00:37 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 11/30/23 00:37 10061-02-60.50 1
Diisopropyl ether ND ug/L 11/30/23 00:37 108-20-30.50 1
Ethylbenzene ND ug/L 11/30/23 00:37 100-41-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 7 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92699610
GSD.050
Sample:EFFLUENT Lab ID:92699610002 Collected:11/20/23 13:30 Received:11/20/23 15:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Hexachloro-1,3-butadiene ND ug/L 11/30/23 00:37 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 11/30/23 00:37 98-82-80.50 1
Methylene Chloride ND ug/L 11/30/23 00:37 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 11/30/23 00:37 1634-04-40.50 1
Naphthalene ND ug/L 11/30/23 00:37 91-20-32.0 1
n-Propylbenzene ND ug/L 11/30/23 00:37 103-65-10.50 1
Styrene ND ug/L 11/30/23 00:37 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 11/30/23 00:37 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 11/30/23 00:37 79-34-50.50 1
Tetrachloroethene ND ug/L 11/30/23 00:37 127-18-40.50 1
Toluene ND ug/L 11/30/23 00:37 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 11/30/23 00:37 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 11/30/23 00:37 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 11/30/23 00:37 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 11/30/23 00:37 79-00-50.50 1
Trichloroethene ND ug/L 11/30/23 00:37 79-01-60.50 1
Trichlorofluoromethane ND ug/L 11/30/23 00:37 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 11/30/23 00:37 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 11/30/23 00:37 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 11/30/23 00:37 108-67-80.50 1
Vinyl chloride ND ug/L 11/30/23 00:37 75-01-41.0 1
m&p-Xylene ND ug/L 11/30/23 00:37 179601-23-11.0 1
o-Xylene ND ug/L 11/30/23 00:37 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)95 %11/30/23 00:37 17060-07-070-130 1
4-Bromofluorobenzene (S)96 %11/30/23 00:37 460-00-470-130 1
Toluene-d8 (S)99 %11/30/23 00:37 2037-26-570-130 1
Analytical Method: SM 2540D-2015
Pace Analytical Services - Asheville
2540D Total Suspended Solids
Total Suspended Solids ND mg/L 11/22/23 10:492.5 1
Analytical Method: EPA 420.4 Rev 1.0 1993 Preparation Method: EPA 420.4 Rev 1.0 1993
Pace Analytical Services - Asheville
420.4 Phenolics, Total
Phenolics, Total Recoverable ND mg/L 11/29/23 16:02 64743-03-911/29/23 12:580.020 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 8 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92699610
GSD.050
Sample:WSW-16 Lab ID:92699610003 Collected:11/20/23 14:25 Received:11/20/23 15:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 11/30/23 00:55 71-43-20.50 1
Bromobenzene ND ug/L 11/30/23 00:55 108-86-10.50 1
Bromochloromethane ND ug/L 11/30/23 00:55 74-97-50.50 1
Bromodichloromethane ND ug/L 11/30/23 00:55 75-27-40.50 1
Bromoform ND ug/L 11/30/23 00:55 75-25-20.50 1
Bromomethane ND ug/L 11/30/23 00:55 74-83-95.0 1
n-Butylbenzene ND ug/L 11/30/23 00:55 104-51-80.50 1
sec-Butylbenzene ND ug/L 11/30/23 00:55 135-98-80.50 1
tert-Butylbenzene ND ug/L 11/30/23 00:55 98-06-60.50 1
Carbon tetrachloride ND ug/L 11/30/23 00:55 56-23-50.50 1
Chlorobenzene ND ug/L 11/30/23 00:55 108-90-70.50 1
Chloroethane ND ug/L 11/30/23 00:55 75-00-31.0 1
Chloroform ND ug/L 11/30/23 00:55 67-66-30.50 1
Chloromethane ND ug/L 11/30/23 00:55 74-87-31.0 1
2-Chlorotoluene ND ug/L 11/30/23 00:55 95-49-80.50 1
4-Chlorotoluene ND ug/L 11/30/23 00:55 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 11/30/23 00:55 96-12-81.0 1
Dibromochloromethane ND ug/L 11/30/23 00:55 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 11/30/23 00:55 106-93-40.50 1
Dibromomethane ND ug/L 11/30/23 00:55 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 11/30/23 00:55 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 11/30/23 00:55 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 11/30/23 00:55 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 11/30/23 00:55 75-71-80.50 1
1,1-Dichloroethane ND ug/L 11/30/23 00:55 75-34-30.50 1
1,2-Dichloroethane ND ug/L 11/30/23 00:55 107-06-20.50 1
1,1-Dichloroethene ND ug/L 11/30/23 00:55 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 11/30/23 00:55 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 11/30/23 00:55 156-60-50.50 1
1,2-Dichloropropane ND ug/L 11/30/23 00:55 78-87-50.50 1
1,3-Dichloropropane ND ug/L 11/30/23 00:55 142-28-90.50 1
2,2-Dichloropropane ND ug/L 11/30/23 00:55 594-20-70.50 1
1,1-Dichloropropene ND ug/L 11/30/23 00:55 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 11/30/23 00:55 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 11/30/23 00:55 10061-02-60.50 1
Diisopropyl ether ND ug/L 11/30/23 00:55 108-20-30.50 1
Ethylbenzene ND ug/L 11/30/23 00:55 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 11/30/23 00:55 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 11/30/23 00:55 98-82-80.50 1
Methylene Chloride ND ug/L 11/30/23 00:55 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 11/30/23 00:55 1634-04-40.50 1
Naphthalene ND ug/L 11/30/23 00:55 91-20-32.0 1
n-Propylbenzene ND ug/L 11/30/23 00:55 103-65-10.50 1
Styrene ND ug/L 11/30/23 00:55 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 11/30/23 00:55 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 11/30/23 00:55 79-34-50.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 9 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92699610
GSD.050
Sample:WSW-16 Lab ID:92699610003 Collected:11/20/23 14:25 Received:11/20/23 15:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Tetrachloroethene ND ug/L 11/30/23 00:55 127-18-40.50 1
Toluene ND ug/L 11/30/23 00:55 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 11/30/23 00:55 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 11/30/23 00:55 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 11/30/23 00:55 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 11/30/23 00:55 79-00-50.50 1
Trichloroethene ND ug/L 11/30/23 00:55 79-01-60.50 1
Trichlorofluoromethane ND ug/L 11/30/23 00:55 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 11/30/23 00:55 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 11/30/23 00:55 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 11/30/23 00:55 108-67-80.50 1
Vinyl chloride ND ug/L 11/30/23 00:55 75-01-41.0 1
m&p-Xylene ND ug/L 11/30/23 00:55 179601-23-11.0 1
o-Xylene ND ug/L 11/30/23 00:55 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)95 %11/30/23 00:55 17060-07-070-130 1
4-Bromofluorobenzene (S)97 %11/30/23 00:55 460-00-470-130 1
Toluene-d8 (S)99 %11/30/23 00:55 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 10 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92699610
GSD.050
Sample:WSW-KR2 Lab ID:92699610004 Collected:11/20/23 14:45 Received:11/20/23 15:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 11/30/23 01:13 71-43-20.50 1
Bromobenzene ND ug/L 11/30/23 01:13 108-86-10.50 1
Bromochloromethane ND ug/L 11/30/23 01:13 74-97-50.50 1
Bromodichloromethane ND ug/L 11/30/23 01:13 75-27-40.50 1
Bromoform ND ug/L 11/30/23 01:13 75-25-20.50 1
Bromomethane ND ug/L 11/30/23 01:13 74-83-95.0 1
n-Butylbenzene ND ug/L 11/30/23 01:13 104-51-80.50 1
sec-Butylbenzene ND ug/L 11/30/23 01:13 135-98-80.50 1
tert-Butylbenzene ND ug/L 11/30/23 01:13 98-06-60.50 1
Carbon tetrachloride ND ug/L 11/30/23 01:13 56-23-50.50 1
Chlorobenzene ND ug/L 11/30/23 01:13 108-90-70.50 1
Chloroethane ND ug/L 11/30/23 01:13 75-00-31.0 1
Chloroform ND ug/L 11/30/23 01:13 67-66-30.50 1
Chloromethane ND ug/L 11/30/23 01:13 74-87-31.0 1
2-Chlorotoluene ND ug/L 11/30/23 01:13 95-49-80.50 1
4-Chlorotoluene ND ug/L 11/30/23 01:13 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 11/30/23 01:13 96-12-81.0 1
Dibromochloromethane ND ug/L 11/30/23 01:13 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 11/30/23 01:13 106-93-40.50 1
Dibromomethane ND ug/L 11/30/23 01:13 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 11/30/23 01:13 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 11/30/23 01:13 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 11/30/23 01:13 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 11/30/23 01:13 75-71-80.50 1
1,1-Dichloroethane ND ug/L 11/30/23 01:13 75-34-30.50 1
1,2-Dichloroethane ND ug/L 11/30/23 01:13 107-06-20.50 1
1,1-Dichloroethene ND ug/L 11/30/23 01:13 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 11/30/23 01:13 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 11/30/23 01:13 156-60-50.50 1
1,2-Dichloropropane ND ug/L 11/30/23 01:13 78-87-50.50 1
1,3-Dichloropropane ND ug/L 11/30/23 01:13 142-28-90.50 1
2,2-Dichloropropane ND ug/L 11/30/23 01:13 594-20-70.50 1
1,1-Dichloropropene ND ug/L 11/30/23 01:13 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 11/30/23 01:13 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 11/30/23 01:13 10061-02-60.50 1
Diisopropyl ether ND ug/L 11/30/23 01:13 108-20-30.50 1
Ethylbenzene ND ug/L 11/30/23 01:13 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 11/30/23 01:13 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 11/30/23 01:13 98-82-80.50 1
Methylene Chloride ND ug/L 11/30/23 01:13 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 11/30/23 01:13 1634-04-40.50 1
Naphthalene ND ug/L 11/30/23 01:13 91-20-32.0 1
n-Propylbenzene ND ug/L 11/30/23 01:13 103-65-10.50 1
Styrene ND ug/L 11/30/23 01:13 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 11/30/23 01:13 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 11/30/23 01:13 79-34-50.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 11 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92699610
GSD.050
Sample:WSW-KR2 Lab ID:92699610004 Collected:11/20/23 14:45 Received:11/20/23 15:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Tetrachloroethene ND ug/L 11/30/23 01:13 127-18-40.50 1
Toluene ND ug/L 11/30/23 01:13 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 11/30/23 01:13 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 11/30/23 01:13 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 11/30/23 01:13 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 11/30/23 01:13 79-00-50.50 1
Trichloroethene ND ug/L 11/30/23 01:13 79-01-60.50 1
Trichlorofluoromethane ND ug/L 11/30/23 01:13 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 11/30/23 01:13 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 11/30/23 01:13 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 11/30/23 01:13 108-67-80.50 1
Vinyl chloride ND ug/L 11/30/23 01:13 75-01-41.0 1
m&p-Xylene ND ug/L 11/30/23 01:13 179601-23-11.0 1
o-Xylene ND ug/L 11/30/23 01:13 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)96 %11/30/23 01:13 17060-07-070-130 1
4-Bromofluorobenzene (S)96 %11/30/23 01:13 460-00-470-130 1
Toluene-d8 (S)100 %11/30/23 01:13 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 12 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699610
GSD.050
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815961
EPA 1664B
EPA 1664B
1664 HEM, Oil and Grease
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92699610001, 92699610002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4223338
Associated Lab Samples:92699610001, 92699610002
Matrix:Water
Analyzed
Oil and Grease mg/L ND 5.0 11/29/23 11:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4223339LABORATORY CONTROL SAMPLE:
LCSSpike
Oil and Grease mg/L 33.440 84 78-114
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
4223340MATRIX SPIKE SAMPLE:
MSSpike
Result
92699247001
Oil and Grease mg/L 33.940 80 78-114ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92699247002
4223341SAMPLE DUPLICATE:
Oil and Grease mg/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 13 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699610
GSD.050
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
814729
EPA 3010A
EPA 6010D
6010 MET
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92699610001, 92699610002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4217869
Associated Lab Samples:92699610001, 92699610002
Matrix:Water
Analyzed
Lead ug/L ND 5.0 12/01/23 16:34
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4217870LABORATORY CONTROL SAMPLE:
LCSSpike
Lead ug/L 504500 101 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4217871MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699610001
4217872
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Lead ug/L 500 99 75-125101 2 20500ND495503
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 14 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699610
GSD.050
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815501
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92699610001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4221380
Associated Lab Samples:92699610001
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 11/28/23 12:20
1,1,1-Trichloroethane ug/L ND 0.50 11/28/23 12:20
1,1,2,2-Tetrachloroethane ug/L ND 0.50 11/28/23 12:20
1,1,2-Trichloroethane ug/L ND 0.50 11/28/23 12:20
1,1-Dichloroethane ug/L ND 0.50 11/28/23 12:20
1,1-Dichloroethene ug/L ND 0.50 11/28/23 12:20
1,1-Dichloropropene ug/L ND 0.50 11/28/23 12:20
1,2,3-Trichlorobenzene ug/L ND 2.0 11/28/23 12:20
1,2,3-Trichloropropane ug/L ND 0.50 11/28/23 12:20
1,2,4-Trichlorobenzene ug/L ND 2.0 11/28/23 12:20
1,2,4-Trimethylbenzene ug/L ND 0.50 11/28/23 12:20
1,2-Dibromo-3-chloropropane ug/L ND 1.0 11/28/23 12:20
1,2-Dibromoethane (EDB)ug/L ND 0.50 11/28/23 12:20
1,2-Dichlorobenzene ug/L ND 0.50 11/28/23 12:20
1,2-Dichloroethane ug/L ND 0.50 11/28/23 12:20
1,2-Dichloropropane ug/L ND 0.50 11/28/23 12:20
1,3,5-Trimethylbenzene ug/L ND 0.50 11/28/23 12:20
1,3-Dichlorobenzene ug/L ND 0.50 11/28/23 12:20
1,3-Dichloropropane ug/L ND 0.50 11/28/23 12:20
1,4-Dichlorobenzene ug/L ND 0.50 11/28/23 12:20
2,2-Dichloropropane ug/L ND 0.50 11/28/23 12:20
2-Chlorotoluene ug/L ND 0.50 11/28/23 12:20
4-Chlorotoluene ug/L ND 0.50 11/28/23 12:20
Benzene ug/L ND 0.50 11/28/23 12:20
Bromobenzene ug/L ND 0.50 11/28/23 12:20
Bromochloromethane ug/L ND 0.50 11/28/23 12:20
Bromodichloromethane ug/L ND 0.50 11/28/23 12:20
Bromoform ug/L ND 0.50 11/28/23 12:20
Bromomethane ug/L ND 5.0 11/28/23 12:20
Carbon tetrachloride ug/L ND 0.50 11/28/23 12:20
Chlorobenzene ug/L ND 0.50 11/28/23 12:20
Chloroethane ug/L ND 1.0 11/28/23 12:20
Chloroform ug/L ND 0.50 11/28/23 12:20
Chloromethane ug/L ND 1.0 11/28/23 12:20
cis-1,2-Dichloroethene ug/L ND 0.50 11/28/23 12:20
cis-1,3-Dichloropropene ug/L ND 0.50 11/28/23 12:20
Dibromochloromethane ug/L ND 0.50 11/28/23 12:20
Dibromomethane ug/L ND 0.50 11/28/23 12:20
Dichlorodifluoromethane ug/L ND 0.50 11/28/23 12:20
Diisopropyl ether ug/L ND 0.50 11/28/23 12:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 15 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699610
GSD.050
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4221380
Associated Lab Samples:92699610001
Matrix:Water
Analyzed
Ethylbenzene ug/L ND 0.50 11/28/23 12:20
Hexachloro-1,3-butadiene ug/L ND 2.0 11/28/23 12:20
Isopropylbenzene (Cumene)ug/L ND 0.50 11/28/23 12:20
m&p-Xylene ug/L ND 1.0 11/28/23 12:20
Methyl-tert-butyl ether ug/L ND 0.50 11/28/23 12:20
Methylene Chloride ug/L ND 2.0 11/28/23 12:20
n-Butylbenzene ug/L ND 0.50 11/28/23 12:20
n-Propylbenzene ug/L ND 0.50 11/28/23 12:20
Naphthalene ug/L ND 2.0 11/28/23 12:20
o-Xylene ug/L ND 0.50 11/28/23 12:20
sec-Butylbenzene ug/L ND 0.50 11/28/23 12:20
Styrene ug/L ND 0.50 11/28/23 12:20
tert-Butylbenzene ug/L ND 0.50 11/28/23 12:20
Tetrachloroethene ug/L ND 0.50 11/28/23 12:20
Toluene ug/L ND 0.50 11/28/23 12:20
trans-1,2-Dichloroethene ug/L ND 0.50 11/28/23 12:20
trans-1,3-Dichloropropene ug/L ND 0.50 11/28/23 12:20
Trichloroethene ug/L ND 0.50 11/28/23 12:20
Trichlorofluoromethane ug/L ND 1.0 11/28/23 12:20
Vinyl chloride ug/L ND 1.0 11/28/23 12:20
1,2-Dichloroethane-d4 (S)%95 70-130 11/28/23 12:20
4-Bromofluorobenzene (S)%97 70-130 11/28/23 12:20
Toluene-d8 (S)%98 70-130 11/28/23 12:20
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4221381LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 19.420 97 60-140
1,1,1-Trichloroethane ug/L 17.620 88 60-140
1,1,2,2-Tetrachloroethane ug/L 19.120 96 60-140
1,1,2-Trichloroethane ug/L 19.120 95 60-140
1,1-Dichloroethane ug/L 17.020 85 60-140
1,1-Dichloroethene ug/L 18.320 91 60-140
1,1-Dichloropropene ug/L 18.620 93 60-140
1,2,3-Trichlorobenzene ug/L 19.020 95 60-140
1,2,3-Trichloropropane ug/L 18.220 91 60-140
1,2,4-Trichlorobenzene ug/L 18.320 91 60-140
1,2,4-Trimethylbenzene ug/L 18.320 92 60-140
1,2-Dibromo-3-chloropropane ug/L 19.020 95 60-140
1,2-Dibromoethane (EDB)ug/L 19.020 95 60-140
1,2-Dichlorobenzene ug/L 18.820 94 60-140
1,2-Dichloroethane ug/L 17.620 88 60-140
1,2-Dichloropropane ug/L 16.420 82 60-140
1,3,5-Trimethylbenzene ug/L 18.620 93 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 16 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699610
GSD.050
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4221381LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 18.920 94 60-140
1,3-Dichloropropane ug/L 17.720 89 60-140
1,4-Dichlorobenzene ug/L 18.120 91 60-140
2,2-Dichloropropane ug/L 17.120 85 60-140
2-Chlorotoluene ug/L 18.320 92 60-140
4-Chlorotoluene ug/L 18.320 92 60-140
Benzene ug/L 17.820 89 60-140
Bromobenzene ug/L 17.820 89 60-140
Bromochloromethane ug/L 18.520 92 60-140
Bromodichloromethane ug/L 16.720 83 60-140
Bromoform ug/L 19.520 97 60-140
Bromomethane ug/L 17.420 87 60-140
Carbon tetrachloride ug/L 18.820 94 60-140
Chlorobenzene ug/L 18.220 91 60-140
Chloroethane ug/L 17.920 89 60-140
Chloroform ug/L 17.320 86 60-140
Chloromethane ug/L 18.020 90 60-140
cis-1,2-Dichloroethene ug/L 17.220 86 60-140
cis-1,3-Dichloropropene ug/L 16.720 84 60-140
Dibromochloromethane ug/L 18.520 93 60-140
Dibromomethane ug/L 20.120 101 60-140
Dichlorodifluoromethane ug/L 22.220 111 60-140
Diisopropyl ether ug/L 16.020 80 60-140
Ethylbenzene ug/L 17.720 89 60-140
Hexachloro-1,3-butadiene ug/L 19.120 95 60-140
Isopropylbenzene (Cumene)ug/L 18.520 93 60-140
m&p-Xylene ug/L 35.240 88 60-140
Methyl-tert-butyl ether ug/L 16.220 81 60-140
Methylene Chloride ug/L 16.920 84 60-140
n-Butylbenzene ug/L 18.320 92 60-140
n-Propylbenzene ug/L 17.720 89 60-140
Naphthalene ug/L 19.320 96 60-140
o-Xylene ug/L 17.920 90 60-140
sec-Butylbenzene ug/L 18.120 91 60-140
Styrene ug/L 18.620 93 60-140
tert-Butylbenzene ug/L 15.220 76 60-140
Tetrachloroethene ug/L 18.320 91 60-140
Toluene ug/L 17.620 88 60-140
trans-1,2-Dichloroethene ug/L 17.020 85 60-140
trans-1,3-Dichloropropene ug/L 17.420 87 60-140
Trichloroethene ug/L 18.120 91 60-140
Trichlorofluoromethane ug/L 18.620 93 60-140
Vinyl chloride ug/L 17.220 86 60-140
1,2-Dichloroethane-d4 (S)%91 70-130
4-Bromofluorobenzene (S)%98 70-130
Toluene-d8 (S)%97 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 17 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699610
GSD.050
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4221382MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699343007
4221383
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 116 60-14095 19 3020ND23.1 19.0
1,1,1-Trichloroethane ug/L 20 109 60-14091 18 3020ND21.8 18.2
1,1,2,2-Tetrachloroethane ug/L 20 112 60-14091 21 3020ND22.5 18.2
1,1,2-Trichloroethane ug/L 20 114 60-14092 21 3020ND22.7 18.3
1,1-Dichloroethane ug/L 20 103 60-14087 17 3020ND20.7 17.3
1,1-Dichloroethene ug/L 20 114 60-14096 17 30200.41J 23.2 19.6
1,1-Dichloropropene ug/L 20 114 60-14095 19 3020ND22.9 18.9
1,2,3-Trichlorobenzene ug/L 20 107 60-14092 15 3020ND21.3 18.3
1,2,3-Trichloropropane ug/L 20 105 60-14087 18 3020ND20.9 17.4
1,2,4-Trichlorobenzene ug/L 20 104 60-14087 17 3020ND20.7 17.5
1,2,4-Trimethylbenzene ug/L 20 120 60-14093 25 3020ND23.9 18.7
1,2-Dibromo-3-
chloropropane ug/L 20 110 60-14089 21 3020ND22.0 17.8
1,2-Dibromoethane (EDB)ug/L 20 115 60-14093 22 3020ND23.1 18.6
1,2-Dichlorobenzene ug/L 20 110 60-14092 18 3020ND22.0 18.3
1,2-Dichloroethane ug/L 20 95 60-14082 16 30200.13J 19.2 16.4
1,2-Dichloropropane ug/L 20 97 60-14082 16 3020ND19.4 16.5
1,3,5-Trimethylbenzene ug/L 20 112 60-14095 17 3020ND22.5 19.0
1,3-Dichlorobenzene ug/L 20 111 60-14094 17 3020ND22.2 18.8
1,3-Dichloropropane ug/L 20 109 60-14088 21 3020ND21.7 17.6
1,4-Dichlorobenzene ug/L 20 106 60-14089 17 3020ND21.1 17.7
2,2-Dichloropropane ug/L 20 110 60-14088 23 3020ND22.1 17.6
2-Chlorotoluene ug/L 20 106 60-14088 18 3020ND21.1 17.6
4-Chlorotoluene ug/L 20 108 60-14093 15 3020ND21.6 18.6
Benzene ug/L 20 111 60-14089 22 3020ND22.2 17.8
Bromobenzene ug/L 20 105 60-14091 15 3020ND21.1 18.2
Bromochloromethane ug/L 20 108 60-14087 21 3020ND21.6 17.5
Bromodichloromethane ug/L 20 99 60-14082 19 3020ND19.9 16.3
Bromoform ug/L 20 114 60-14092 21 3020ND22.9 18.5
Bromomethane ug/L 20 106 60-14090 16 3020ND21.2 18.0
Carbon tetrachloride ug/L 20 118 60-14098 16 30203.0 26.7 22.6
Chlorobenzene ug/L 20 112 60-14089 23 3020ND22.3 17.8
Chloroethane ug/L 20 113 60-14091 21 3020ND22.5 18.3
Chloroform ug/L 20 106 60-14086 17 30204.4 25.6 21.6
Chloromethane ug/L 20 108 60-14091 17 3020ND21.5 18.1
cis-1,2-Dichloroethene ug/L 20 103 60-14086 18 30200.11J 20.7 17.4
cis-1,3-Dichloropropene ug/L 20 105 60-14086 20 3020ND21.1 17.2
Dibromochloromethane ug/L 20 112 60-14091 21 3020ND22.3 18.1
Dibromomethane ug/L 20 117 60-14097 19 3020ND23.4 19.4
Dichlorodifluoromethane ug/L 20 139 60-140112 22 3020ND27.9 22.4
Diisopropyl ether ug/L 20 95 60-14081 16 3020ND19.0 16.1
Ethylbenzene ug/L 20 112 60-14089 22 3020ND22.4 17.9
Hexachloro-1,3-butadiene ug/L 20 114 60-14098 15 3020ND22.7 19.5
Isopropylbenzene
(Cumene)
ug/L 20 116 60-14093 21 3020ND23.1 18.7
m&p-Xylene ug/L 40 112 60-14089 22 30400.13J 44.8 35.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 18 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699610
GSD.050
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4221382MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699343007
4221383
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methyl-tert-butyl ether ug/L 20 93 60-14076 20 30200.083J 18.7 15.3
Methylene Chloride ug/L 20 99 60-14085 15 3020ND19.8 17.0
n-Butylbenzene ug/L 20 109 60-14094 15 3020ND21.8 18.8
n-Propylbenzene ug/L 20 108 60-14091 17 3020ND21.7 18.3
Naphthalene ug/L 20 115 60-14092 22 3020ND22.9 18.4
o-Xylene ug/L 20 111 60-14090 21 3020ND22.2 18.0
sec-Butylbenzene ug/L 20 111 60-14094 17 3020ND22.1 18.7
Styrene ug/L 20 115 60-14092 22 3020ND23.0 18.5
tert-Butylbenzene ug/L 20 94 60-14079 17 3020ND18.8 15.9
Tetrachloroethene ug/L 20 110 60-14093 10 302012.9 34.9 31.6
Toluene ug/L 20 111 60-14089 22 3020ND22.2 17.8
trans-1,2-Dichloroethene ug/L 20 106 60-14089 17 3020ND21.3 17.9
trans-1,3-Dichloropropene ug/L 20 107 60-14087 20 3020ND21.3 17.5
Trichloroethene ug/L 20 118 60-14096 21 3020ND23.8 19.3
Trichlorofluoromethane ug/L 20 118 60-14095 21 3020ND23.5 19.0
Vinyl chloride ug/L 20 110 60-14089 20 3020ND22.0 17.9
1,2-Dichloroethane-d4 (S)%88 70-13088
4-Bromofluorobenzene (S)%99 70-13098
Toluene-d8 (S)%98 70-13097
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 19 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699610
GSD.050
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815503
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92699610002, 92699610003, 92699610004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4221402
Associated Lab Samples:92699610002, 92699610003, 92699610004
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 11/30/23 00:19
1,1,1-Trichloroethane ug/L ND 0.50 11/30/23 00:19
1,1,2,2-Tetrachloroethane ug/L ND 0.50 11/30/23 00:19
1,1,2-Trichloroethane ug/L ND 0.50 11/30/23 00:19
1,1-Dichloroethane ug/L ND 0.50 11/30/23 00:19
1,1-Dichloroethene ug/L ND 0.50 11/30/23 00:19
1,1-Dichloropropene ug/L ND 0.50 11/30/23 00:19
1,2,3-Trichlorobenzene ug/L ND 2.0 11/30/23 00:19
1,2,3-Trichloropropane ug/L ND 0.50 11/30/23 00:19
1,2,4-Trichlorobenzene ug/L ND 2.0 11/30/23 00:19
1,2,4-Trimethylbenzene ug/L ND 0.50 11/30/23 00:19
1,2-Dibromo-3-chloropropane ug/L ND 1.0 11/30/23 00:19
1,2-Dibromoethane (EDB)ug/L ND 0.50 11/30/23 00:19
1,2-Dichlorobenzene ug/L ND 0.50 11/30/23 00:19
1,2-Dichloroethane ug/L ND 0.50 11/30/23 00:19
1,2-Dichloropropane ug/L ND 0.50 11/30/23 00:19
1,3,5-Trimethylbenzene ug/L ND 0.50 11/30/23 00:19
1,3-Dichlorobenzene ug/L ND 0.50 11/30/23 00:19
1,3-Dichloropropane ug/L ND 0.50 11/30/23 00:19
1,4-Dichlorobenzene ug/L ND 0.50 11/30/23 00:19
2,2-Dichloropropane ug/L ND 0.50 11/30/23 00:19
2-Chlorotoluene ug/L ND 0.50 11/30/23 00:19
4-Chlorotoluene ug/L ND 0.50 11/30/23 00:19
Benzene ug/L ND 0.50 11/30/23 00:19
Bromobenzene ug/L ND 0.50 11/30/23 00:19
Bromochloromethane ug/L ND 0.50 11/30/23 00:19
Bromodichloromethane ug/L ND 0.50 11/30/23 00:19
Bromoform ug/L ND 0.50 11/30/23 00:19
Bromomethane ug/L ND 5.0 11/30/23 00:19
Carbon tetrachloride ug/L ND 0.50 11/30/23 00:19
Chlorobenzene ug/L ND 0.50 11/30/23 00:19
Chloroethane ug/L ND 1.0 11/30/23 00:19
Chloroform ug/L ND 0.50 11/30/23 00:19
Chloromethane ug/L ND 1.0 11/30/23 00:19
cis-1,2-Dichloroethene ug/L ND 0.50 11/30/23 00:19
cis-1,3-Dichloropropene ug/L ND 0.50 11/30/23 00:19
Dibromochloromethane ug/L ND 0.50 11/30/23 00:19
Dibromomethane ug/L ND 0.50 11/30/23 00:19
Dichlorodifluoromethane ug/L ND 0.50 11/30/23 00:19
Diisopropyl ether ug/L ND 0.50 11/30/23 00:19
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 20 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699610
GSD.050
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4221402
Associated Lab Samples:92699610002, 92699610003, 92699610004
Matrix:Water
Analyzed
Ethylbenzene ug/L ND 0.50 11/30/23 00:19
Hexachloro-1,3-butadiene ug/L ND 2.0 11/30/23 00:19
Isopropylbenzene (Cumene)ug/L ND 0.50 11/30/23 00:19
m&p-Xylene ug/L ND 1.0 11/30/23 00:19
Methyl-tert-butyl ether ug/L ND 0.50 11/30/23 00:19
Methylene Chloride ug/L ND 2.0 11/30/23 00:19
n-Butylbenzene ug/L ND 0.50 11/30/23 00:19
n-Propylbenzene ug/L ND 0.50 11/30/23 00:19
Naphthalene ug/L ND 2.0 11/30/23 00:19
o-Xylene ug/L ND 0.50 11/30/23 00:19
sec-Butylbenzene ug/L ND 0.50 11/30/23 00:19
Styrene ug/L ND 0.50 11/30/23 00:19
tert-Butylbenzene ug/L ND 0.50 11/30/23 00:19
Tetrachloroethene ug/L ND 0.50 11/30/23 00:19
Toluene ug/L ND 0.50 11/30/23 00:19
trans-1,2-Dichloroethene ug/L ND 0.50 11/30/23 00:19
trans-1,3-Dichloropropene ug/L ND 0.50 11/30/23 00:19
Trichloroethene ug/L ND 0.50 11/30/23 00:19
Trichlorofluoromethane ug/L ND 1.0 11/30/23 00:19
Vinyl chloride ug/L ND 1.0 11/30/23 00:19
1,2-Dichloroethane-d4 (S)%95 70-130 11/30/23 00:19
4-Bromofluorobenzene (S)%96 70-130 11/30/23 00:19
Toluene-d8 (S)%98 70-130 11/30/23 00:19
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4221403LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 21.620 108 60-140
1,1,1-Trichloroethane ug/L 21.220 106 60-140
1,1,2,2-Tetrachloroethane ug/L 21.720 109 60-140
1,1,2-Trichloroethane ug/L 21.620 108 60-140
1,1-Dichloroethane ug/L 20.820 104 60-140
1,1-Dichloroethene ug/L 22.220 111 60-140
1,1-Dichloropropene ug/L 22.020 110 60-140
1,2,3-Trichlorobenzene ug/L 23.120 116 60-140
1,2,3-Trichloropropane ug/L 20.820 104 60-140
1,2,4-Trichlorobenzene ug/L 21.020 105 60-140
1,2,4-Trimethylbenzene ug/L 20.920 105 60-140
1,2-Dibromo-3-chloropropane ug/L 20.820 104 60-140
1,2-Dibromoethane (EDB)ug/L 22.120 111 60-140
1,2-Dichlorobenzene ug/L 20.820 104 60-140
1,2-Dichloroethane ug/L 20.820 104 60-140
1,2-Dichloropropane ug/L 21.520 108 60-140
1,3,5-Trimethylbenzene ug/L 20.820 104 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 21 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699610
GSD.050
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4221403LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 20.720 104 60-140
1,3-Dichloropropane ug/L 20.420 102 60-140
1,4-Dichlorobenzene ug/L 20.420 102 60-140
2,2-Dichloropropane ug/L 19.220 96 60-140
2-Chlorotoluene ug/L 20.220 101 60-140
4-Chlorotoluene ug/L 20.520 103 60-140
Benzene ug/L 20.920 105 60-140
Bromobenzene ug/L 20.520 102 60-140
Bromochloromethane ug/L 21.320 106 60-140
Bromodichloromethane ug/L 20.620 103 60-140
Bromoform ug/L 20.720 104 60-140
Bromomethane ug/L 19.720 99 60-140
Carbon tetrachloride ug/L 20.820 104 60-140
Chlorobenzene ug/L 20.720 104 60-140
Chloroethane ug/L 22.320 112 60-140
Chloroform ug/L 20.520 102 60-140
Chloromethane ug/L 21.720 108 60-140
cis-1,2-Dichloroethene ug/L 20.920 104 60-140
cis-1,3-Dichloropropene ug/L 20.520 102 60-140
Dibromochloromethane ug/L 21.420 107 60-140
Dibromomethane ug/L 21.120 105 60-140
Dichlorodifluoromethane ug/L 19.620 98 60-140
Diisopropyl ether ug/L 20.020 100 60-140
Ethylbenzene ug/L 20.420 102 60-140
Hexachloro-1,3-butadiene ug/L 19.620 98 60-140
Isopropylbenzene (Cumene)ug/L 20.920 104 60-140
m&p-Xylene ug/L 41.540 104 60-140
Methyl-tert-butyl ether ug/L 20.020 100 60-140
Methylene Chloride ug/L 20.220 101 60-140
n-Butylbenzene ug/L 20.520 103 60-140
n-Propylbenzene ug/L 19.920 99 60-140
Naphthalene ug/L 23.120 116 60-140
o-Xylene ug/L 20.720 104 60-140
sec-Butylbenzene ug/L 20.120 100 60-140
Styrene ug/L 21.720 108 60-140
tert-Butylbenzene ug/L 16.720 83 60-140
Tetrachloroethene ug/L 20.220 101 60-140
Toluene ug/L 20.320 102 60-140
trans-1,2-Dichloroethene ug/L 21.420 107 60-140
trans-1,3-Dichloropropene ug/L 20.920 104 60-140
Trichloroethene ug/L 21.120 106 60-140
Trichlorofluoromethane ug/L 21.220 106 60-140
Vinyl chloride ug/L 19.420 97 60-140
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%101 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 22 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699610
GSD.050
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4221404MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699610002
4221405
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 115 60-140112 3 3020ND23.0 22.3
1,1,1-Trichloroethane ug/L 20 118 60-140114 3 3020ND23.5 22.8
1,1,2,2-Tetrachloroethane ug/L 20 112 60-140110 2 3020ND22.4 22.0
1,1,2-Trichloroethane ug/L 20 113 60-140110 2 3020ND22.6 22.0
1,1-Dichloroethane ug/L 20 112 60-140109 2 3020ND22.3 21.8
1,1-Dichloroethene ug/L 20 124 60-140116 6 3020ND24.8 23.2
1,1-Dichloropropene ug/L 20 128 60-140123 4 3020ND25.5 24.6
1,2,3-Trichlorobenzene ug/L 20 115 60-140109 6 3020ND23.1 21.8
1,2,3-Trichloropropane ug/L 20 108 60-140104 3 3020ND21.5 20.9
1,2,4-Trichlorobenzene ug/L 20 114 60-140107 6 3020ND22.7 21.5
1,2,4-Trimethylbenzene ug/L 20 116 60-140111 5 3020ND23.2 22.1
1,2-Dibromo-3-
chloropropane ug/L 20 106 60-140104 2 3020ND21.1 20.7
1,2-Dibromoethane (EDB)ug/L 20 113 60-140111 1 3020ND22.6 22.3
1,2-Dichlorobenzene ug/L 20 112 60-140107 4 3020ND22.3 21.4
1,2-Dichloroethane ug/L 20 112 60-140109 3 3020ND22.4 21.7
1,2-Dichloropropane ug/L 20 116 60-140111 4 3020ND23.2 22.3
1,3,5-Trimethylbenzene ug/L 20 115 60-140110 4 3020ND23.0 22.1
1,3-Dichlorobenzene ug/L 20 112 60-140107 5 3020ND22.5 21.5
1,3-Dichloropropane ug/L 20 107 60-140106 1 3020ND21.4 21.2
1,4-Dichlorobenzene ug/L 20 110 60-140106 4 3020ND21.9 21.2
2,2-Dichloropropane ug/L 20 117 60-140113 3 3020ND23.5 22.7
2-Chlorotoluene ug/L 20 111 60-140108 3 3020ND22.2 21.6
4-Chlorotoluene ug/L 20 113 60-140109 4 3020ND22.6 21.7
Benzene ug/L 20 112 60-140109 2 3020ND22.3 21.8
Bromobenzene ug/L 20 111 60-140106 4 3020ND22.1 21.3
Bromochloromethane ug/L 20 118 60-140111 6 3020ND23.5 22.2
Bromodichloromethane ug/L 20 109 60-140107 2 3020ND21.8 21.4
Bromoform ug/L 20 107 60-140106 1 3020ND21.4 21.1
Bromomethane ug/L 20 105 60-140101 4 3020ND21.1 20.3
Carbon tetrachloride ug/L 20 117 60-140113 3 3020ND23.4 22.6
Chlorobenzene ug/L 20 111 60-140109 2 3020ND22.3 21.8
Chloroethane ug/L 20 117 60-140110 6 3020ND23.4 22.0
Chloroform ug/L 20 114 60-140104 9 3020ND22.8 20.8
Chloromethane ug/L 20 100 60-14096 4 3020ND19.9 19.2
cis-1,2-Dichloroethene ug/L 20 112 60-140110 3 3020ND22.5 21.9
cis-1,3-Dichloropropene ug/L 20 108 60-140107 2 3020ND21.7 21.3
Dibromochloromethane ug/L 20 111 60-140108 3 3020ND22.2 21.6
Dibromomethane ug/L 20 111 60-140108 3 3020ND22.2 21.5
Dichlorodifluoromethane ug/L 20 79 60-14075 5 3020ND15.8 15.0
Diisopropyl ether ug/L 20 106 60-140103 4 3020ND21.3 20.5
Ethylbenzene ug/L 20 110 60-140109 1 3020ND22.1 21.8
Hexachloro-1,3-butadiene ug/L 20 118 60-140116 2 3020ND23.6 23.2
Isopropylbenzene
(Cumene)
ug/L 20 115 60-140112 2 3020ND23.0 22.4
m&p-Xylene ug/L 40 113 60-140110 2 3040ND45.1 44.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 23 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699610
GSD.050
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4221404MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699610002
4221405
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methyl-tert-butyl ether ug/L 20 105 60-140103 3 3020ND21.1 20.5
Methylene Chloride ug/L 20 105 60-140101 3 3020ND21.0 20.3
n-Butylbenzene ug/L 20 123 60-140115 7 3020ND24.7 22.9
n-Propylbenzene ug/L 20 112 60-140107 4 3020ND22.4 21.5
Naphthalene ug/L 20 113 60-140111 2 3020ND22.5 22.2
o-Xylene ug/L 20 110 60-140108 2 3020ND22.0 21.6
sec-Butylbenzene ug/L 20 116 60-140111 5 3020ND23.3 22.2
Styrene ug/L 20 115 60-140113 2 3020ND23.0 22.5
tert-Butylbenzene ug/L 20 93 60-14090 4 3020ND18.7 18.0
Tetrachloroethene ug/L 20 111 60-140109 2 3020ND22.3 21.8
Toluene ug/L 20 110 60-140107 3 3020ND22.0 21.4
trans-1,2-Dichloroethene ug/L 20 120 60-140115 5 3020ND24.1 22.9
trans-1,3-Dichloropropene ug/L 20 111 60-140110 1 3020ND22.2 22.0
Trichloroethene ug/L 20 117 60-140112 4 3020ND23.4 22.4
Trichlorofluoromethane ug/L 20 118 60-140114 4 3020ND23.7 22.7
Vinyl chloride ug/L 20 97 60-14093 4 3020ND19.3 18.5
1,2-Dichloroethane-d4 (S)%101 70-13099
4-Bromofluorobenzene (S)%99 70-130101
Toluene-d8 (S)%99 70-13099
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 24 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699610
GSD.050
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815039
SM 2540D-2015
SM 2540D-2015
2540D Total Suspended Solids
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92699610001, 92699610002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4219296
Associated Lab Samples:92699610001, 92699610002
Matrix:Water
Analyzed
Total Suspended Solids mg/L ND 2.5 11/22/23 10:44
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4219297LABORATORY CONTROL SAMPLE:
LCSSpike
Total Suspended Solids mg/L 244250 97 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92699514003
4219489SAMPLE DUPLICATE:
Total Suspended Solids mg/L 6500 20 255300
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92699695001
4219490SAMPLE DUPLICATE:
Total Suspended Solids mg/L 274 7 25294
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 25 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699610
GSD.050
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815850
EPA 420.4 Rev 1.0 1993
EPA 420.4 Rev 1.0 1993
420.4 Phenolics
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92699610001, 92699610002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4222904
Associated Lab Samples:92699610001, 92699610002
Matrix:Water
Analyzed
Phenolics, Total Recoverable mg/L ND 0.020 11/29/23 15:40
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4222905LABORATORY CONTROL SAMPLE:
LCSSpike
Phenolics, Total Recoverable mg/L 0.0510.05 102 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4222906MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699266001
4222907
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Phenolics, Total
Recoverable mg/L M10.05 -205 90-110-200 3 100.050.17 0.068 0.071
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4222908MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35841839002
4222909
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Phenolics, Total
Recoverable mg/L M1,R10.05 -61 90-110-40 12 100.050.12 0.085 0.096
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 26 of 31
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92699610
GSD.050
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 27 of 31
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92699610
GSD.050
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92699610001 815961INFLUENTEPA 1664B
92699610002 815961EFFLUENTEPA 1664B
92699610001 814729 814816INFLUENTEPA 3010A EPA 6010D
92699610002 814729 814816EFFLUENTEPA 3010A EPA 6010D
92699610001 815501INFLUENTSM 6200B
92699610002 815503EFFLUENTSM 6200B
92699610003 815503WSW-16 SM 6200B
92699610004 815503WSW-KR2 SM 6200B
92699610001 815039INFLUENTSM 2540D-2015
92699610002 815039EFFLUENTSM 2540D-2015
92699610001 815850 816094INFLUENTEPA 420.4 Rev 1.0 1993 EPA 420.4 Rev 1.0 1993
92699610002 815850 816094EFFLUENTEPA 420.4 Rev 1.0 1993 EPA 420.4 Rev 1.0 1993
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 28 of 31
Page 29 of 31
Page 30 of 31
Page 31 of 31
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
3/18/2024
Hart & Hickman (Charlotte) Steve Libbey
2923 South Tryon St. Ste 100 Charlotte, NC, 28203
Ref: Analytical Testing
Revised Lab Report Number: 24-038-0014 Client Project Description: GSD.050
Dear Steve Libbey:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 2/7/2024 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely,
Angela D Overcash Senior Project Manager
Page 1 of 36
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202437735State ProgramNorth Carolina
12/31/2024402State ProgramNorth Carolina
07/31/202499012State ProgramSouth Carolina
12/31/202399012State ProgramSouth Carolina
Page 1 of 1 00016/24-038-0014
Page 2 of 36
Report Number:
Sample Summary Table
Client Project Description:
24-038-0014
GSD.050
Lab No Client Sample ID Matrix Date Collected Date Received
02/06/2024 11:30Aqueous 96058 WSW-KR2 02/07/2024 14:25
02/06/2024 11:45Aqueous 96059 WSW-16 02/07/2024 14:25
02/06/2024 12:00Aqueous 96060 MW-3R 02/07/2024 14:25
02/06/2024 12:15Aqueous 96061 MW-5R 02/07/2024 14:25
Page 3 of 36
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
24-038-0014
Report Limit
Project:GSD.050
V 96060MW-3R
10.6 02/13/2024 18:056200BDi-Isopropyl Ether (DIPE)µg/L 0.500
616 02/15/2024 17:086200BMethyl tert-butyl ether (MTBE)µg/L 100
Page 4 of 36
Client: Hart & Hickman (Charlotte) CASE NARRATIVE
Project: GSD.050 Lab Report Number: 24-038-0014
Date: 3/18/2024
Report Comments Revised Report: Revision 1 Samples have been updated to report to the MQL.
Volatile Organic Compounds - GC/MS Method 6200B
Analyte: Bromomethane QC Batch No: V44813
This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for
a low bias.
Analyte: 1,2,3-Trichlorobenzene QC Batch No: V44813/V43554
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: 1,2-Dibromo-3-chloropropane QC Batch No: V44813/V43554
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable.
Analyte: Ethanol QC Batch No: V44814/V43554
This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for
a low bias.
Page 5 of 36
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-038-0014
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Steve Libbey
Charlotte
Received : 02/07/2024
GSD.050
Revised Report Date : 03/18/2024
Original Report Date : 02/22/2024
Sample ID :
Lab No :
Sampled:WSW-KR2
96058 Matrix:
2/6/2024 11:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V43554 02/13/24 09:00
<10.0 µg/L 10.0Acetone 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500Benzene 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500Bromobenzene 1 02/13/24 17:16 V44939ENM
<1.00 µg/L 1.00Bromochloromethane 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500Bromodichloromethane 1 02/13/24 17:16 V44939ENM
<5.00 µg/L 5.00Bromoform 1 02/13/24 17:16 V44939ENM
<1.00 µg/L 1.00Bromomethane 1 02/13/24 17:16 V44942ENM
<0.500 µg/L 0.500n-Butylbenzene 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500sec-Butyl benzene 1 02/13/24 17:16 V44939ENM
<2.00 µg/L 2.00tert-Butyl benzene 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500Carbon Tetrachloride 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500Chlorobenzene 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500Chlorodibromomethane 1 02/13/24 17:16 V44939ENM
<1.00 µg/L 1.00Chloroethane 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500Chloroform 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500Chloromethane 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.5002-Chlorotoluene 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.5004-Chlorotoluene 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 02/13/24 17:16 V44939ENM
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.5001,2-Dibromoethane 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500Dibromomethane 1 02/13/24 17:16 V44939ENM
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQL
Page 6 of 36
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-038-0014
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Steve Libbey
Charlotte
Received : 02/07/2024
GSD.050
Revised Report Date : 03/18/2024
Original Report Date : 02/22/2024
Sample ID :
Lab No :
Sampled:WSW-KR2
96058 Matrix:
2/6/2024 11:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V43554 02/13/24 09:00
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 02/13/24 17:16 V44939ENM
<5.00 µg/L 5.00Dichlorodifluoromethane 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.5001,1-Dichloroethane 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.5001,2-Dichloroethane 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.5001,1-Dichloroethene 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.5001,2-Dichloropropane 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.5001,3-Dichloropropane 1 02/13/24 17:16 V44939ENM
<2.00 µg/L 2.002,2-Dichloropropane 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.5001,1-Dichloropropene 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 02/13/24 17:16 V44939ENM
<200 µg/L 200Ethanol 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500Ethylbenzene 1 02/13/24 17:16 V44939ENM
<3.00 µg/L 3.00Hexachlorobutadiene 1 02/13/24 17:16 V44939ENM
<1.00 µg/L 1.002-Hexanone 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500Isopropylbenzene 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.5004-Isopropyl toluene 1 02/13/24 17:16 V44939ENM
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 02/13/24 17:16 V44939ENM
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQL
Page 7 of 36
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-038-0014
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Steve Libbey
Charlotte
Received : 02/07/2024
GSD.050
Revised Report Date : 03/18/2024
Original Report Date : 02/22/2024
Sample ID :
Lab No :
Sampled:WSW-KR2
96058 Matrix:
2/6/2024 11:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V43554 02/13/24 09:00
<1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 02/13/24 17:16 V44939ENM
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 02/13/24 17:16 V44939ENM
<2.00 µg/L 2.00Methylene Chloride 1 02/13/24 17:16 V44939ENM
<1.00 µg/L 1.00Naphthalene 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500n-Propylbenzene 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500Styrene 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500Tetrachloroethene 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500Toluene 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500Trichloroethene 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500Trichlorofluoromethane 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 02/13/24 17:16 V44939ENM
<5.00 µg/L 5.00Vinyl Acetate 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500Vinyl Chloride 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500o-Xylene 1 02/13/24 17:16 V44939ENM
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQL
Page 8 of 36
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-038-0014
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Steve Libbey
Charlotte
Received : 02/07/2024
GSD.050
Revised Report Date : 03/18/2024
Original Report Date : 02/22/2024
Sample ID :
Lab No :
Sampled:WSW-KR2
96058 Matrix:
2/6/2024 11:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V43554 02/13/24 09:00
<1.00 µg/L 1.00m,p-Xylene 1 02/13/24 17:16 V44939ENM
<0.500 µg/L 0.500Xylene (Total)1 02/13/24 17:16 V44939
Surrogate: 4-Bromofluorobenzene 93.4 Limits: 70-130%02/13/24 17:161 ENM V44939
Surrogate: Dibromofluoromethane 96.4 Limits: 70-130%02/13/24 17:161 ENM V44939
Surrogate: 1,2-Dichloroethane - d4 93.6 Limits: 70-130%02/13/24 17:161 ENM V44939
Surrogate: Toluene-d8 102 Limits: 70-130%02/13/24 17:161 ENM V44939
Surrogate: 4-Bromofluorobenzene 93.4 Limits: 70-130%02/13/24 17:161 ENM V44942
Surrogate: Dibromofluoromethane 96.4 Limits: 70-130%02/13/24 17:161 ENM V44942
Surrogate: 1,2-Dichloroethane - d4 93.6 Limits: 70-130%02/13/24 17:161 ENM V44942
Surrogate: Toluene-d8 102 Limits: 70-130%02/13/24 17:161 ENM V44942
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQL
Page 9 of 36
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-038-0014
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Steve Libbey
Charlotte
Received : 02/07/2024
GSD.050
Revised Report Date : 03/18/2024
Original Report Date : 02/22/2024
Sample ID :
Lab No :
Sampled:WSW-16
96059 Matrix:
2/6/2024 11:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V43554 02/13/24 09:00
<10.0 µg/L 10.0Acetone 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500Benzene 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500Bromobenzene 1 02/13/24 17:40 V44939ENM
<1.00 µg/L 1.00Bromochloromethane 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500Bromodichloromethane 1 02/13/24 17:40 V44939ENM
<5.00 µg/L 5.00Bromoform 1 02/13/24 17:40 V44939ENM
<1.00 µg/L 1.00Bromomethane 1 02/13/24 17:40 V44942ENM
<0.500 µg/L 0.500n-Butylbenzene 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500sec-Butyl benzene 1 02/13/24 17:40 V44939ENM
<2.00 µg/L 2.00tert-Butyl benzene 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500Carbon Tetrachloride 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500Chlorobenzene 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500Chlorodibromomethane 1 02/13/24 17:40 V44939ENM
<1.00 µg/L 1.00Chloroethane 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500Chloroform 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500Chloromethane 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.5002-Chlorotoluene 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.5004-Chlorotoluene 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 02/13/24 17:40 V44939ENM
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.5001,2-Dibromoethane 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500Dibromomethane 1 02/13/24 17:40 V44939ENM
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQL
Page 10 of 36
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-038-0014
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Steve Libbey
Charlotte
Received : 02/07/2024
GSD.050
Revised Report Date : 03/18/2024
Original Report Date : 02/22/2024
Sample ID :
Lab No :
Sampled:WSW-16
96059 Matrix:
2/6/2024 11:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V43554 02/13/24 09:00
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 02/13/24 17:40 V44939ENM
<5.00 µg/L 5.00Dichlorodifluoromethane 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.5001,1-Dichloroethane 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.5001,2-Dichloroethane 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.5001,1-Dichloroethene 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.5001,2-Dichloropropane 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.5001,3-Dichloropropane 1 02/13/24 17:40 V44939ENM
<2.00 µg/L 2.002,2-Dichloropropane 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.5001,1-Dichloropropene 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 02/13/24 17:40 V44939ENM
<200 µg/L 200Ethanol 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500Ethylbenzene 1 02/13/24 17:40 V44939ENM
<3.00 µg/L 3.00Hexachlorobutadiene 1 02/13/24 17:40 V44939ENM
<1.00 µg/L 1.002-Hexanone 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500Isopropylbenzene 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.5004-Isopropyl toluene 1 02/13/24 17:40 V44939ENM
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 02/13/24 17:40 V44939ENM
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQL
Page 11 of 36
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-038-0014
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Steve Libbey
Charlotte
Received : 02/07/2024
GSD.050
Revised Report Date : 03/18/2024
Original Report Date : 02/22/2024
Sample ID :
Lab No :
Sampled:WSW-16
96059 Matrix:
2/6/2024 11:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V43554 02/13/24 09:00
<1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 02/13/24 17:40 V44939ENM
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 02/13/24 17:40 V44939ENM
<2.00 µg/L 2.00Methylene Chloride 1 02/13/24 17:40 V44939ENM
<1.00 µg/L 1.00Naphthalene 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500n-Propylbenzene 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500Styrene 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500Tetrachloroethene 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500Toluene 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500Trichloroethene 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500Trichlorofluoromethane 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 02/13/24 17:40 V44939ENM
<5.00 µg/L 5.00Vinyl Acetate 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500Vinyl Chloride 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500o-Xylene 1 02/13/24 17:40 V44939ENM
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQL
Page 12 of 36
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-038-0014
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Steve Libbey
Charlotte
Received : 02/07/2024
GSD.050
Revised Report Date : 03/18/2024
Original Report Date : 02/22/2024
Sample ID :
Lab No :
Sampled:WSW-16
96059 Matrix:
2/6/2024 11:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V43554 02/13/24 09:00
<1.00 µg/L 1.00m,p-Xylene 1 02/13/24 17:40 V44939ENM
<0.500 µg/L 0.500Xylene (Total)1 02/13/24 17:40 V44939
Surrogate: 4-Bromofluorobenzene 95.2 Limits: 70-130%02/13/24 17:401 ENM V44939
Surrogate: Dibromofluoromethane 95.8 Limits: 70-130%02/13/24 17:401 ENM V44939
Surrogate: 1,2-Dichloroethane - d4 95.0 Limits: 70-130%02/13/24 17:401 ENM V44939
Surrogate: Toluene-d8 102 Limits: 70-130%02/13/24 17:401 ENM V44939
Surrogate: 4-Bromofluorobenzene 95.2 Limits: 70-130%02/13/24 17:401 ENM V44942
Surrogate: Dibromofluoromethane 95.8 Limits: 70-130%02/13/24 17:401 ENM V44942
Surrogate: 1,2-Dichloroethane - d4 95.0 Limits: 70-130%02/13/24 17:401 ENM V44942
Surrogate: Toluene-d8 102 Limits: 70-130%02/13/24 17:401 ENM V44942
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQL
Page 13 of 36
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-038-0014
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Steve Libbey
Charlotte
Received : 02/07/2024
GSD.050
Revised Report Date : 03/18/2024
Original Report Date : 02/22/2024
Sample ID :
Lab No :
Sampled:MW-3R
96060 Matrix:
2/6/2024 12:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V43554 02/13/24 09:00 V43696 02/15/24 09:00
<10.0 µg/L 10.0Acetone 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500Benzene 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500Bromobenzene 1 02/13/24 18:05 V44939ENM
<1.00 µg/L 1.00Bromochloromethane 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500Bromodichloromethane 1 02/13/24 18:05 V44939ENM
<5.00 µg/L 5.00Bromoform 1 02/13/24 18:05 V44939ENM
<1.00 µg/L 1.00Bromomethane 1 02/13/24 18:05 V44942ENM
<0.500 µg/L 0.500n-Butylbenzene 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500sec-Butyl benzene 1 02/13/24 18:05 V44939ENM
<2.00 µg/L 2.00tert-Butyl benzene 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500Carbon Tetrachloride 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500Chlorobenzene 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500Chlorodibromomethane 1 02/13/24 18:05 V44939ENM
<1.00 µg/L 1.00Chloroethane 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500Chloroform 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500Chloromethane 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.5002-Chlorotoluene 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.5004-Chlorotoluene 1 02/13/24 18:05 V44939ENM
10.6 µg/L 0.500Di-Isopropyl Ether (DIPE)1 02/13/24 18:05 V44939ENM
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.5001,2-Dibromoethane 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500Dibromomethane 1 02/13/24 18:05 V44939ENM
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQL
Page 14 of 36
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-038-0014
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Steve Libbey
Charlotte
Received : 02/07/2024
GSD.050
Revised Report Date : 03/18/2024
Original Report Date : 02/22/2024
Sample ID :
Lab No :
Sampled:MW-3R
96060 Matrix:
2/6/2024 12:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V43554 02/13/24 09:00 V43696 02/15/24 09:00
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 02/13/24 18:05 V44939ENM
<5.00 µg/L 5.00Dichlorodifluoromethane 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.5001,1-Dichloroethane 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.5001,2-Dichloroethane 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.5001,1-Dichloroethene 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.5001,2-Dichloropropane 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.5001,3-Dichloropropane 1 02/13/24 18:05 V44939ENM
<2.00 µg/L 2.002,2-Dichloropropane 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.5001,1-Dichloropropene 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 02/13/24 18:05 V44939ENM
<200 µg/L 200Ethanol 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500Ethylbenzene 1 02/13/24 18:05 V44939ENM
<3.00 µg/L 3.00Hexachlorobutadiene 1 02/13/24 18:05 V44939ENM
<1.00 µg/L 1.002-Hexanone 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500Isopropylbenzene 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.5004-Isopropyl toluene 1 02/13/24 18:05 V44939ENM
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 02/13/24 18:05 V44939ENM
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQL
Page 15 of 36
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-038-0014
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Steve Libbey
Charlotte
Received : 02/07/2024
GSD.050
Revised Report Date : 03/18/2024
Original Report Date : 02/22/2024
Sample ID :
Lab No :
Sampled:MW-3R
96060 Matrix:
2/6/2024 12:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V43554 02/13/24 09:00 V43696 02/15/24 09:00
616 µg/L 100Methyl tert-butyl ether (MTBE)100 02/15/24 17:08 V44815ENM
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 02/13/24 18:05 V44939ENM
<2.00 µg/L 2.00Methylene Chloride 1 02/13/24 18:05 V44939ENM
<1.00 µg/L 1.00Naphthalene 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500n-Propylbenzene 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500Styrene 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500Tetrachloroethene 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500Toluene 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500Trichloroethene 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500Trichlorofluoromethane 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 02/13/24 18:05 V44939ENM
<5.00 µg/L 5.00Vinyl Acetate 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500Vinyl Chloride 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500o-Xylene 1 02/13/24 18:05 V44939ENM
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQL
Page 16 of 36
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-038-0014
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Steve Libbey
Charlotte
Received : 02/07/2024
GSD.050
Revised Report Date : 03/18/2024
Original Report Date : 02/22/2024
Sample ID :
Lab No :
Sampled:MW-3R
96060 Matrix:
2/6/2024 12:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V43554 02/13/24 09:00 V43696 02/15/24 09:00
<1.00 µg/L 1.00m,p-Xylene 1 02/13/24 18:05 V44939ENM
<0.500 µg/L 0.500Xylene (Total)1 02/13/24 18:05 V44939
Surrogate: 4-Bromofluorobenzene 92.8 Limits: 70-130%02/13/24 18:051 ENM V44939
Surrogate: Dibromofluoromethane 95.2 Limits: 70-130%02/13/24 18:051 ENM V44939
Surrogate: 1,2-Dichloroethane - d4 93.2 Limits: 70-130%02/13/24 18:051 ENM V44939
Surrogate: Toluene-d8 102 Limits: 70-130%02/13/24 18:051 ENM V44939
Surrogate: 4-Bromofluorobenzene 92.8 Limits: 70-130%02/13/24 18:051 ENM V44942
Surrogate: Dibromofluoromethane 95.2 Limits: 70-130%02/13/24 18:051 ENM V44942
Surrogate: 1,2-Dichloroethane - d4 93.2 Limits: 70-130%02/13/24 18:051 ENM V44942
Surrogate: Toluene-d8 102 Limits: 70-130%02/13/24 18:051 ENM V44942
Surrogate: 4-Bromofluorobenzene 96.8 Limits: 70-130%02/15/24 17:08100 ENM V44815
Surrogate: Dibromofluoromethane 93.6 Limits: 70-130%02/15/24 17:08100 ENM V44815
Surrogate: 1,2-Dichloroethane - d4 91.2 Limits: 70-130%02/15/24 17:08100 ENM V44815
Surrogate: Toluene-d8 103 Limits: 70-130%02/15/24 17:08100 ENM V44815
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQL
Page 17 of 36
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-038-0014
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Steve Libbey
Charlotte
Received : 02/07/2024
GSD.050
Revised Report Date : 03/18/2024
Original Report Date : 02/22/2024
Sample ID :
Lab No :
Sampled:MW-5R
96061 Matrix:
2/6/2024 12:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V43939 02/21/24 09:00
<10.0 H µg/L 10.0Acetone 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500Benzene 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500Bromobenzene 1 02/21/24 13:00 V44814ENM
<1.00 H µg/L 1.00Bromochloromethane 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500Bromodichloromethane 1 02/21/24 13:00 V44814ENM
<5.00 H µg/L 5.00Bromoform 1 02/21/24 13:00 V44814ENM
<1.00 H µg/L 1.00Bromomethane 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500n-Butylbenzene 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500sec-Butyl benzene 1 02/21/24 13:00 V44814ENM
<2.00 H µg/L 2.00tert-Butyl benzene 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500Carbon Tetrachloride 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500Chlorobenzene 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500Chlorodibromomethane 1 02/21/24 13:00 V44814ENM
<1.00 H µg/L 1.00Chloroethane 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500Chloroform 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500Chloromethane 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.5002-Chlorotoluene 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.5004-Chlorotoluene 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500Di-Isopropyl Ether (DIPE)1 02/21/24 13:00 V44814ENM
<2.00 H µg/L 2.001,2-Dibromo-3-Chloropropane 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.5001,2-Dibromoethane 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500Dibromomethane 1 02/21/24 13:00 V44814ENM
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQL
Page 18 of 36
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-038-0014
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Steve Libbey
Charlotte
Received : 02/07/2024
GSD.050
Revised Report Date : 03/18/2024
Original Report Date : 02/22/2024
Sample ID :
Lab No :
Sampled:MW-5R
96061 Matrix:
2/6/2024 12:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V43939 02/21/24 09:00
<0.500 H µg/L 0.5001,2-Dichlorobenzene 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.5001,3-Dichlorobenzene 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.5001,4-Dichlorobenzene 1 02/21/24 13:00 V44814ENM
<5.00 H µg/L 5.00Dichlorodifluoromethane 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.5001,1-Dichloroethane 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.5001,2-Dichloroethane 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.5001,1-Dichloroethene 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500cis-1,2-Dichloroethene 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500trans-1,2-Dichloroethene 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.5001,2-Dichloropropane 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.5001,3-Dichloropropane 1 02/21/24 13:00 V44814ENM
<2.00 H µg/L 2.002,2-Dichloropropane 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.5001,1-Dichloropropene 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500cis-1,3-Dichloropropene 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500trans-1,3-Dichloropropene 1 02/21/24 13:00 V44814ENM
<200 H µg/L 200Ethanol 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500Ethylbenzene 1 02/21/24 13:00 V44814ENM
<3.00 H µg/L 3.00Hexachlorobutadiene 1 02/21/24 13:00 V44814ENM
<1.00 H µg/L 1.002-Hexanone 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500Isopropylbenzene 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.5004-Isopropyl toluene 1 02/21/24 13:00 V44814ENM
<5.00 H µg/L 5.00Methyl Ethyl Ketone (MEK)1 02/21/24 13:00 V44814ENM
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQL
Page 19 of 36
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-038-0014
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Steve Libbey
Charlotte
Received : 02/07/2024
GSD.050
Revised Report Date : 03/18/2024
Original Report Date : 02/22/2024
Sample ID :
Lab No :
Sampled:MW-5R
96061 Matrix:
2/6/2024 12:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V43939 02/21/24 09:00
<1.00 H µg/L 1.00Methyl tert-butyl ether (MTBE)1 02/21/24 13:00 V44814ENM
<1.00 H µg/L 1.004-Methyl-2-Pentanone 1 02/21/24 13:00 V44814ENM
<2.00 H µg/L 2.00Methylene Chloride 1 02/21/24 13:00 V44814ENM
<1.00 H µg/L 1.00Naphthalene 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500n-Propylbenzene 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500Styrene 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.5001,1,1,2-Tetrachloroethane 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.5001,1,2,2-Tetrachloroethane 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500Tetrachloroethene 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500Toluene 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.5001,2,3-Trichlorobenzene 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.5001,2,4-Trichlorobenzene 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.5001,1,1-Trichloroethane 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.5001,1,2-Trichloroethane 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500Trichloroethene 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500Trichlorofluoromethane 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.5001,2,3-Trichloropropane 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.5001,2,4-Trimethylbenzene 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.5001,3,5-Trimethylbenzene 1 02/21/24 13:00 V44814ENM
<5.00 H µg/L 5.00Vinyl Acetate 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500Vinyl Chloride 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500o-Xylene 1 02/21/24 13:00 V44814ENM
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQL
Page 20 of 36
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
24-038-0014
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Steve Libbey
Charlotte
Received : 02/07/2024
GSD.050
Revised Report Date : 03/18/2024
Original Report Date : 02/22/2024
Sample ID :
Lab No :
Sampled:MW-5R
96061 Matrix:
2/6/2024 12:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V43939 02/21/24 09:00
<1.00 H µg/L 1.00m,p-Xylene 1 02/21/24 13:00 V44814ENM
<0.500 H µg/L 0.500Xylene (Total)1 02/21/24 13:00 V44814
Surrogate: 4-Bromofluorobenzene 96.0 Limits: 70-130%02/21/24 13:001 ENM V44814
Surrogate: Dibromofluoromethane 98.6 Limits: 70-130%02/21/24 13:001 ENM V44814
Surrogate: 1,2-Dichloroethane - d4 92.6 Limits: 70-130%02/21/24 13:001 ENM V44814
Surrogate: Toluene-d8 97.8 Limits: 70-130%02/21/24 13:001 ENM V44814
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQL
Page 21 of 36
Quality Control Data
24-038-0014Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
GSD.050
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V44939QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V43554
Associated Lab Samples: 96058, 96059, 96060
LRB-V43554 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/13/24 14:2510.0< 10.0µg/LAcetone
02/13/24 14:250.500< 0.500µg/LBenzene
02/13/24 14:250.500< 0.500µg/LBromobenzene
02/13/24 14:251.00< 1.00µg/LBromochloromethane
02/13/24 14:250.500< 0.500µg/LBromodichloromethane
02/13/24 14:255.00< 5.00µg/LBromoform
02/13/24 14:251.00< 1.00µg/LBromomethane
02/13/24 14:250.500< 0.500µg/Ln-Butylbenzene
02/13/24 14:250.500< 0.500µg/Lsec-Butyl benzene
02/13/24 14:252.00< 2.00µg/Ltert-Butyl benzene
02/13/24 14:250.500< 0.500µg/LCarbon Tetrachloride
02/13/24 14:250.500< 0.500µg/LChlorobenzene
02/13/24 14:250.500< 0.500µg/LChlorodibromomethane
02/13/24 14:251.00< 1.00µg/LChloroethane
02/13/24 14:250.500< 0.500µg/LChloroform
02/13/24 14:250.500< 0.500µg/LChloromethane
02/13/24 14:250.500< 0.500µg/L2-Chlorotoluene
02/13/24 14:250.500< 0.500µg/L4-Chlorotoluene
02/13/24 14:250.500< 0.500µg/LDi-Isopropyl Ether (DIPE)
02/13/24 14:252.00< 2.00µg/L1,2-Dibromo-3-Chloropropane
02/13/24 14:250.500< 0.500µg/L1,2-Dibromoethane
02/13/24 14:250.500< 0.500µg/LDibromomethane
02/13/24 14:250.500< 0.500µg/L1,2-Dichlorobenzene
02/13/24 14:250.500< 0.500µg/L1,3-Dichlorobenzene
02/13/24 14:250.500< 0.500µg/L1,4-Dichlorobenzene
02/13/24 14:255.00< 5.00µg/LDichlorodifluoromethane
02/13/24 14:250.500< 0.500µg/L1,1-Dichloroethane
Page 1 of 13Date:03/18/2024 02:59 PM
Page 22 of 36
Quality Control Data
24-038-0014Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
GSD.050
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V44939QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V43554
Associated Lab Samples: 96058, 96059, 96060
LRB-V43554 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/13/24 14:250.500< 0.500µg/L1,2-Dichloroethane
02/13/24 14:250.500< 0.500µg/L1,1-Dichloroethene
02/13/24 14:250.500< 0.500µg/Lcis-1,2-Dichloroethene
02/13/24 14:250.500< 0.500µg/Ltrans-1,2-Dichloroethene
02/13/24 14:250.500< 0.500µg/L1,2-Dichloropropane
02/13/24 14:250.500< 0.500µg/L1,3-Dichloropropane
02/13/24 14:252.00< 2.00µg/L2,2-Dichloropropane
02/13/24 14:250.500< 0.500µg/L1,1-Dichloropropene
02/13/24 14:250.500< 0.500µg/Lcis-1,3-Dichloropropene
02/13/24 14:250.500< 0.500µg/Ltrans-1,3-Dichloropropene
02/13/24 14:25200< 200µg/LEthanol
02/13/24 14:250.500< 0.500µg/LEthylbenzene
02/13/24 14:253.00< 3.00µg/LHexachlorobutadiene
02/13/24 14:251.00< 1.00µg/L2-Hexanone
02/13/24 14:250.500< 0.500µg/LIsopropylbenzene
02/13/24 14:250.500< 0.500µg/L4-Isopropyl toluene
02/13/24 14:255.00< 5.00µg/LMethyl Ethyl Ketone (MEK)
02/13/24 14:251.00< 1.00µg/LMethyl tert-butyl ether (MTBE)
02/13/24 14:251.00< 1.00µg/L4-Methyl-2-Pentanone
02/13/24 14:252.00< 2.00µg/LMethylene Chloride
02/13/24 14:251.00< 1.00µg/LNaphthalene
02/13/24 14:250.500< 0.500µg/Ln-Propylbenzene
02/13/24 14:250.500< 0.500µg/LStyrene
02/13/24 14:250.500< 0.500µg/L1,1,1,2-Tetrachloroethane
02/13/24 14:250.500< 0.500µg/L1,1,2,2-Tetrachloroethane
02/13/24 14:250.500< 0.500µg/LTetrachloroethene
02/13/24 14:250.500< 0.500µg/LToluene
Page 2 of 13Date:03/18/2024 02:59 PM
Page 23 of 36
Quality Control Data
24-038-0014Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
GSD.050
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V44939QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V43554
Associated Lab Samples: 96058, 96059, 96060
LRB-V43554 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/13/24 14:250.500< 0.500µg/L1,2,3-Trichlorobenzene
02/13/24 14:250.500< 0.500µg/L1,2,4-Trichlorobenzene
02/13/24 14:250.500< 0.500µg/L1,1,1-Trichloroethane
02/13/24 14:250.500< 0.500µg/L1,1,2-Trichloroethane
02/13/24 14:250.500< 0.500µg/LTrichloroethene
02/13/24 14:250.500< 0.500µg/LTrichlorofluoromethane
02/13/24 14:250.500< 0.500µg/L1,2,3-Trichloropropane
02/13/24 14:250.500< 0.500µg/L1,2,4-Trimethylbenzene
02/13/24 14:250.500< 0.500µg/L1,3,5-Trimethylbenzene
02/13/24 14:255.00< 5.00µg/LVinyl Acetate
02/13/24 14:250.500< 0.500µg/LVinyl Chloride
02/13/24 14:250.500< 0.500µg/Lo-Xylene
02/13/24 14:251.00< 1.00µg/Lm,p-Xylene
02/13/24 14:254-Bromofluorobenzene (S)92.6 70-130
02/13/24 14:25Dibromofluoromethane (S)96.6 70-130
02/13/24 14:251,2-Dichloroethane - d4 (S)96.2 70-130
02/13/24 14:25Toluene-d8 (S)101 70-130
LCS-V43554 LCSD-V43554Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
36.3 90.797.739.140.0µg/LAcetone 40-160 7.4 20.0
21.8 10910921.820.0µg/LBenzene 70-130 0.0 20.0
22.1 11111122.120.0µg/LBromobenzene 70-130 0.0 20.0
22.5 11311022.020.0µg/LBromochloromethane 70-130 2.2 20.0
21.6 10810721.320.0µg/LBromodichloromethane 70-130 1.3 20.0
Page 3 of 13Date:03/18/2024 02:59 PM
Page 24 of 36
Quality Control Data
24-038-0014Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
GSD.050
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V44939QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V43554
LCS-V43554 LCSD-V43554Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
23.2 11611322.620.0µg/LBromoform 70-130 2.6 20.0
9.69 48.4*44.7*8.9420.0µg/LBromomethane 60-140 8.0 20.0
21.6 10811022.020.0µg/Ln-Butylbenzene 70-130 1.8 20.0
23.4 11711522.920.0µg/Lsec-Butyl benzene 70-130 2.1 20.0
23.0 11511522.920.0µg/Ltert-Butyl benzene 70-130 0.4 20.0
22.3 11211122.120.0µg/LCarbon Tetrachloride 70-130 0.9 20.0
22.9 11511322.520.0µg/LChlorobenzene 70-130 1.7 20.0
23.1 11611522.920.0µg/LChlorodibromomethane 70-130 0.8 20.0
24.6 12311823.620.0µg/LChloroethane 60-140 4.1 20.0
21.0 10510520.920.0µg/LChloroform 70-130 0.4 20.0
16.3 81.580.516.120.0µg/LChloromethane 60-140 1.2 20.0
22.8 11411522.920.0µg/L2-Chlorotoluene 70-130 0.4 20.0
23.0 11511523.020.0µg/L4-Chlorotoluene 70-130 0.0 20.0
22.5 11311422.720.0µg/LDi-Isopropyl Ether (DIPE)70-130 0.8 20.0
24.1 121135*27.020.0µg/L1,2-Dibromo-3-Chloropropane 70-130 11.3 20.0
23.0 11511623.120.0µg/L1,2-Dibromoethane 70-130 0.4 20.0
21.7 10911222.420.0µg/LDibromomethane 70-130 3.1 20.0
21.8 10911122.220.0µg/L1,2-Dichlorobenzene 70-130 1.8 20.0
22.5 11311022.020.0µg/L1,3-Dichlorobenzene 70-130 2.2 20.0
22.8 11411422.720.0µg/L1,4-Dichlorobenzene 70-130 0.4 20.0
19.7 98.598.019.620.0µg/LDichlorodifluoromethane 60-140 0.5 20.0
21.2 10610520.920.0µg/L1,1-Dichloroethane 70-130 1.4 20.0
21.8 10910921.820.0µg/L1,2-Dichloroethane 70-130 0.0 20.0
20.9 10510320.520.0µg/L1,1-Dichloroethene 70-130 1.9 20.0
21.1 10610521.020.0µg/Lcis-1,2-Dichloroethene 70-130 0.4 20.0
20.6 10310220.420.0µg/Ltrans-1,2-Dichloroethene 70-130 0.9 20.0
Page 4 of 13* QC Fail Date:03/18/2024 02:59 PM
Page 25 of 36
Quality Control Data
24-038-0014Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
GSD.050
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V44939QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V43554
LCS-V43554 LCSD-V43554Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.3 10710520.920.0µg/L1,2-Dichloropropane 70-130 1.8 20.0
22.9 11511422.820.0µg/L1,3-Dichloropropane 70-130 0.4 20.0
21.6 10810721.320.0µg/L2,2-Dichloropropane 70-130 1.3 20.0
21.5 10810921.820.0µg/L1,1-Dichloropropene 70-130 1.3 20.0
21.3 10710721.420.0µg/Lcis-1,3-Dichloropropene 70-130 0.4 20.0
21.9 11011122.220.0µg/Ltrans-1,3-Dichloropropene 70-130 1.3 20.0
469 93.889.8449500µg/LEthanol 60-140 4.3 20.0
22.7 11411222.420.0µg/LEthylbenzene 70-130 1.3 20.0
22.7 11411923.820.0µg/LHexachlorobutadiene 70-130 4.7 20.0
23.6 11812925.720.0µg/L2-Hexanone 60-140 8.5 20.0
22.2 11111422.820.0µg/LIsopropylbenzene 70-130 2.6 20.0
22.6 11311222.420.0µg/L4-Isopropyl toluene 70-130 0.8 20.0
19.9 99.510921.820.0µg/LMethyl Ethyl Ketone (MEK)60-140 9.1 20.0
22.9 11511823.620.0µg/LMethyl tert-butyl ether (MTBE)70-130 3.0 20.0
23.0 11512925.820.0µg/L4-Methyl-2-Pentanone 60-140 11.4 20.0
21.2 10610521.020.0µg/LMethylene Chloride 70-130 0.9 20.0
21.2 10611723.420.0µg/LNaphthalene 70-130 9.8 20.0
23.1 11611623.220.0µg/Ln-Propylbenzene 70-130 0.4 20.0
23.3 11711422.720.0µg/LStyrene 70-130 2.6 20.0
23.0 11511523.020.0µg/L1,1,1,2-Tetrachloroethane 70-130 0.0 20.0
23.2 11612124.220.0µg/L1,1,2,2-Tetrachloroethane 70-130 4.2 20.0
22.0 11011022.020.0µg/LTetrachloroethene 70-130 0.0 20.0
22.2 11111022.020.0µg/LToluene 70-130 0.9 20.0
25.3 127134*26.820.0µg/L1,2,3-Trichlorobenzene 70-130 5.7 20.0
23.1 11612424.720.0µg/L1,2,4-Trichlorobenzene 70-130 6.6 20.0
21.2 10610621.120.0µg/L1,1,1-Trichloroethane 70-130 0.4 20.0
Page 5 of 13* QC Fail Date:03/18/2024 02:59 PM
Page 26 of 36
Quality Control Data
24-038-0014Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
GSD.050
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V44939QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V43554
LCS-V43554 LCSD-V43554Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.9 11011022.020.0µg/L1,1,2-Trichloroethane 70-130 0.4 20.0
21.9 11011022.020.0µg/LTrichloroethene 70-130 0.4 20.0
20.4 10210220.320.0µg/LTrichlorofluoromethane 60-140 0.4 20.0
21.9 11011923.720.0µg/L1,2,3-Trichloropropane 70-130 7.8 20.0
22.4 11211122.120.0µg/L1,2,4-Trimethylbenzene 70-130 1.3 20.0
22.9 11511322.620.0µg/L1,3,5-Trimethylbenzene 70-130 1.3 20.0
22.5 11311523.020.0µg/LVinyl Acetate 60-140 2.1 20.0
18.3 91.590.018.020.0µg/LVinyl Chloride 60-140 1.6 20.0
23.0 11511322.620.0µg/Lo-Xylene 70-130 1.7 20.0
48.9 12212148.240.0µg/Lm,p-Xylene 70-130 1.4 20.0
95.498.04-Bromofluorobenzene (S)70-130
96.096.0Dibromofluoromethane (S)70-130
97.499.01,2-Dichloroethane - d4 (S)70-130
103101Toluene-d8 (S)70-130
Page 6 of 13Date:03/18/2024 02:59 PM
Page 27 of 36
Quality Control Data
24-038-0014Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
GSD.050
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V44815QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V43696
Associated Lab Samples: 96060
LRB-V43696 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/15/24 12:131.00< 1.00µg/LMethyl tert-butyl ether (MTBE)
02/15/24 12:134-Bromofluorobenzene (S)97.4 70-130
02/15/24 12:13Dibromofluoromethane (S)96.0 70-130
02/15/24 12:131,2-Dichloroethane - d4 (S)94.4 70-130
02/15/24 12:13Toluene-d8 (S)103 70-130
LCS-V43696 LCSD-V43696Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.3 10710621.220.0µg/LMethyl tert-butyl ether (MTBE)70-130 0.4 20.0
96.497.04-Bromofluorobenzene (S)70-130
95.094.4Dibromofluoromethane (S)70-130
94.094.21,2-Dichloroethane - d4 (S)70-130
103103Toluene-d8 (S)70-130
Page 7 of 13Date:03/18/2024 02:59 PM
Page 28 of 36
Quality Control Data
24-038-0014Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
GSD.050
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V43946,V44814QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V43939
Associated Lab Samples: 96061
LRB-V43939 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/21/24 12:3610.0< 10.0µg/LAcetone
02/21/24 12:360.500< 0.500µg/LBenzene
02/21/24 12:360.500< 0.500µg/LBromobenzene
02/21/24 12:361.00< 1.00µg/LBromochloromethane
02/21/24 12:360.500< 0.500µg/LBromodichloromethane
02/21/24 12:365.00< 5.00µg/LBromoform
02/21/24 12:361.00< 1.00µg/LBromomethane
02/21/24 12:360.500< 0.500µg/Ln-Butylbenzene
02/21/24 12:360.500< 0.500µg/Lsec-Butyl benzene
02/21/24 12:362.00< 2.00µg/Ltert-Butyl benzene
02/21/24 12:360.500< 0.500µg/LCarbon Tetrachloride
02/21/24 12:360.500< 0.500µg/LChlorobenzene
02/21/24 12:360.500< 0.500µg/LChlorodibromomethane
02/21/24 12:361.00< 1.00µg/LChloroethane
02/21/24 12:360.500< 0.500µg/LChloroform
02/21/24 12:360.500< 0.500µg/LChloromethane
02/21/24 12:360.500< 0.500µg/L2-Chlorotoluene
02/21/24 12:360.500< 0.500µg/L4-Chlorotoluene
02/21/24 12:360.500< 0.500µg/LDi-Isopropyl Ether (DIPE)
02/21/24 12:362.00< 2.00µg/L1,2-Dibromo-3-Chloropropane
02/21/24 12:360.500< 0.500µg/L1,2-Dibromoethane
02/21/24 12:360.500< 0.500µg/LDibromomethane
02/21/24 12:360.500< 0.500µg/L1,2-Dichlorobenzene
02/21/24 12:360.500< 0.500µg/L1,3-Dichlorobenzene
02/21/24 12:360.500< 0.500µg/L1,4-Dichlorobenzene
02/21/24 12:365.00< 5.00µg/LDichlorodifluoromethane
02/21/24 12:360.500< 0.500µg/L1,1-Dichloroethane
Page 8 of 13Date:03/18/2024 02:59 PM
Page 29 of 36
Quality Control Data
24-038-0014Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
GSD.050
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V43946,V44814QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V43939
Associated Lab Samples: 96061
LRB-V43939 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/21/24 12:360.500< 0.500µg/L1,2-Dichloroethane
02/21/24 12:360.500< 0.500µg/L1,1-Dichloroethene
02/21/24 12:360.500< 0.500µg/Lcis-1,2-Dichloroethene
02/21/24 12:360.500< 0.500µg/Ltrans-1,2-Dichloroethene
02/21/24 12:360.500< 0.500µg/L1,2-Dichloropropane
02/21/24 12:360.500< 0.500µg/L1,3-Dichloropropane
02/21/24 12:362.00< 2.00µg/L2,2-Dichloropropane
02/21/24 12:360.500< 0.500µg/L1,1-Dichloropropene
02/21/24 12:360.500< 0.500µg/Lcis-1,3-Dichloropropene
02/21/24 12:360.500< 0.500µg/Ltrans-1,3-Dichloropropene
02/21/24 12:36200< 200µg/LEthanol
02/21/24 12:360.500< 0.500µg/LEthylbenzene
02/21/24 12:363.00< 3.00µg/LHexachlorobutadiene
02/21/24 12:361.00< 1.00µg/L2-Hexanone
02/21/24 12:360.500< 0.500µg/LIsopropylbenzene
02/21/24 12:360.500< 0.500µg/L4-Isopropyl toluene
02/21/24 12:365.00< 5.00µg/LMethyl Ethyl Ketone (MEK)
02/21/24 12:361.00< 1.00µg/LMethyl tert-butyl ether (MTBE)
02/21/24 12:361.00< 1.00µg/L4-Methyl-2-Pentanone
02/21/24 12:362.00< 2.00µg/LMethylene Chloride
02/21/24 12:361.00< 1.00µg/LNaphthalene
02/21/24 12:360.500< 0.500µg/Ln-Propylbenzene
02/21/24 12:360.500< 0.500µg/LStyrene
02/21/24 12:360.500< 0.500µg/L1,1,1,2-Tetrachloroethane
02/21/24 12:360.500< 0.500µg/L1,1,2,2-Tetrachloroethane
02/21/24 12:360.500< 0.500µg/LTetrachloroethene
02/21/24 12:360.500< 0.500µg/LToluene
Page 9 of 13Date:03/18/2024 02:59 PM
Page 30 of 36
Quality Control Data
24-038-0014Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
GSD.050
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V43946,V44814QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V43939
Associated Lab Samples: 96061
LRB-V43939 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/21/24 12:360.500< 0.500µg/L1,2,3-Trichlorobenzene
02/21/24 12:360.500< 0.500µg/L1,2,4-Trichlorobenzene
02/21/24 12:360.500< 0.500µg/L1,1,1-Trichloroethane
02/21/24 12:360.500< 0.500µg/L1,1,2-Trichloroethane
02/21/24 12:360.500< 0.500µg/LTrichloroethene
02/21/24 12:360.500< 0.500µg/LTrichlorofluoromethane
02/21/24 12:360.500< 0.500µg/L1,2,3-Trichloropropane
02/21/24 12:360.500< 0.500µg/L1,2,4-Trimethylbenzene
02/21/24 12:360.500< 0.500µg/L1,3,5-Trimethylbenzene
02/21/24 12:365.00< 5.00µg/LVinyl Acetate
02/21/24 12:360.500< 0.500µg/LVinyl Chloride
02/21/24 12:360.500< 0.500µg/Lo-Xylene
02/21/24 12:361.00< 1.00µg/Lm,p-Xylene
02/21/24 12:364-Bromofluorobenzene (S)99.4 70-130
02/21/24 12:36Dibromofluoromethane (S)98.4 70-130
02/21/24 12:361,2-Dichloroethane - d4 (S)89.2 70-130
02/21/24 12:36Toluene-d8 (S)98.0 70-130
LCS-V43939 LCSD-V43939Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
33.9 84.782.032.840.0µg/LAcetone 40-160 3.2 20.0
20.2 10110521.020.0µg/LBenzene 70-130 3.8 20.0
20.8 10410420.820.0µg/LBromobenzene 70-130 0.0 20.0
20.8 10410621.220.0µg/LBromochloromethane 70-130 1.9 20.0
19.3 96.510020.020.0µg/LBromodichloromethane 70-130 3.5 20.0
Page 10 of 13Date:03/18/2024 02:59 PM
Page 31 of 36
Quality Control Data
24-038-0014Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
GSD.050
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V43946,V44814QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V43939
LCS-V43939 LCSD-V43939Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.4 97.098.519.720.0µg/LBromoform 70-130 1.5 20.0
19.8 99.095.019.020.0µg/LBromomethane 60-140 4.1 20.0
20.3 10210220.320.0µg/Ln-Butylbenzene 70-130 0.0 20.0
21.1 10610721.320.0µg/Lsec-Butyl benzene 70-130 0.9 20.0
21.4 10710821.520.0µg/Ltert-Butyl benzene 70-130 0.4 20.0
20.4 10210521.020.0µg/LCarbon Tetrachloride 70-130 2.8 20.0
20.7 10410621.220.0µg/LChlorobenzene 70-130 2.3 20.0
20.5 10310420.720.0µg/LChlorodibromomethane 70-130 0.9 20.0
22.4 11211823.620.0µg/LChloroethane 60-140 5.2 20.0
19.5 97.510320.620.0µg/LChloroform 70-130 5.4 20.0
20.9 10510921.820.0µg/LChloromethane 60-140 4.2 20.0
21.1 10610621.220.0µg/L2-Chlorotoluene 70-130 0.4 20.0
21.2 10610721.420.0µg/L4-Chlorotoluene 70-130 0.9 20.0
20.2 10110420.720.0µg/LDi-Isopropyl Ether (DIPE)70-130 2.4 20.0
20.5 10398.019.620.0µg/L1,2-Dibromo-3-Chloropropane 70-130 4.4 20.0
20.2 10110120.120.0µg/L1,2-Dibromoethane 70-130 0.4 20.0
19.7 98.510020.020.0µg/LDibromomethane 70-130 1.5 20.0
21.6 10810621.120.0µg/L1,2-Dichlorobenzene 70-130 2.3 20.0
21.5 10810921.720.0µg/L1,3-Dichlorobenzene 70-130 0.9 20.0
21.7 10910721.420.0µg/L1,4-Dichlorobenzene 70-130 1.3 20.0
22.7 11411723.320.0µg/LDichlorodifluoromethane 60-140 2.6 20.0
20.3 10210621.120.0µg/L1,1-Dichloroethane 70-130 3.8 20.0
18.6 93.093.518.720.0µg/L1,2-Dichloroethane 70-130 0.5 20.0
19.2 96.010320.520.0µg/L1,1-Dichloroethene 70-130 6.5 20.0
19.4 97.010220.420.0µg/Lcis-1,2-Dichloroethene 70-130 5.0 20.0
19.7 98.510220.420.0µg/Ltrans-1,2-Dichloroethene 70-130 3.4 20.0
Page 11 of 13Date:03/18/2024 02:59 PM
Page 32 of 36
Quality Control Data
24-038-0014Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
GSD.050
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V43946,V44814QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V43939
LCS-V43939 LCSD-V43939Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.3 10210621.120.0µg/L1,2-Dichloropropane 70-130 3.8 20.0
20.3 10299.519.920.0µg/L1,3-Dichloropropane 70-130 1.9 20.0
19.9 99.510621.120.0µg/L2,2-Dichloropropane 70-130 5.8 20.0
20.7 10410821.620.0µg/L1,1-Dichloropropene 70-130 4.2 20.0
20.0 10010220.320.0µg/Lcis-1,3-Dichloropropene 70-130 1.4 20.0
19.3 96.598.519.720.0µg/Ltrans-1,3-Dichloropropene 70-130 2.0 20.0
806 161*155*774500µg/LEthanol 60-140 4.0 20.0
20.3 10210420.720.0µg/LEthylbenzene 70-130 1.9 20.0
22.9 11511322.520.0µg/LHexachlorobutadiene 70-130 1.7 20.0
18.4 92.088.517.720.0µg/L2-Hexanone 60-140 3.8 20.0
21.3 10710520.920.0µg/LIsopropylbenzene 70-130 1.8 20.0
20.6 10310621.120.0µg/L4-Isopropyl toluene 70-130 2.3 20.0
17.6 88.088.017.620.0µg/LMethyl Ethyl Ketone (MEK)60-140 0.0 20.0
19.3 96.597.519.520.0µg/LMethyl tert-butyl ether (MTBE)70-130 1.0 20.0
18.5 92.590.018.020.0µg/L4-Methyl-2-Pentanone 60-140 2.7 20.0
19.7 98.510220.420.0µg/LMethylene Chloride 70-130 3.4 20.0
20.0 10010220.420.0µg/LNaphthalene 70-130 1.9 20.0
21.0 10510621.220.0µg/Ln-Propylbenzene 70-130 0.9 20.0
20.7 10410420.820.0µg/LStyrene 70-130 0.4 20.0
20.9 10510621.220.0µg/L1,1,1,2-Tetrachloroethane 70-130 1.4 20.0
19.6 98.096.519.320.0µg/L1,1,2,2-Tetrachloroethane 70-130 1.5 20.0
21.1 10610821.620.0µg/LTetrachloroethene 70-130 2.3 20.0
20.1 10110520.920.0µg/LToluene 70-130 3.9 20.0
21.3 10711523.020.0µg/L1,2,3-Trichlorobenzene 70-130 7.6 20.0
22.2 11111422.820.0µg/L1,2,4-Trichlorobenzene 70-130 2.6 20.0
19.5 97.510220.320.0µg/L1,1,1-Trichloroethane 70-130 4.0 20.0
Page 12 of 13* QC Fail Date:03/18/2024 02:59 PM
Page 33 of 36
Quality Control Data
24-038-0014Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
GSD.050
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V43946,V44814QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V43939
LCS-V43939 LCSD-V43939Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.4 97.099.519.920.0µg/L1,1,2-Trichloroethane 70-130 2.5 20.0
20.5 10310721.320.0µg/LTrichloroethene 70-130 3.8 20.0
19.6 98.010220.320.0µg/LTrichlorofluoromethane 60-140 3.5 20.0
18.6 93.092.518.520.0µg/L1,2,3-Trichloropropane 70-130 0.5 20.0
20.4 10210320.620.0µg/L1,2,4-Trimethylbenzene 70-130 0.9 20.0
20.8 10410520.920.0µg/L1,3,5-Trimethylbenzene 70-130 0.4 20.0
19.5 97.599.519.920.0µg/LVinyl Acetate 60-140 2.0 20.0
20.2 10110721.320.0µg/LVinyl Chloride 60-140 5.3 20.0
20.7 10410520.920.0µg/Lo-Xylene 70-130 0.9 20.0
42.7 10710943.440.0µg/Lm,p-Xylene 70-130 1.6 20.0
10197.44-Bromofluorobenzene (S)70-130
99.699.6Dibromofluoromethane (S)70-130
92.093.01,2-Dichloroethane - d4 (S)70-130
10099.4Toluene-d8 (S)70-130
Page 13 of 13Date:03/18/2024 02:59 PM
Page 34 of 36
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:24-038-0014
Hart & Hickman (Charlotte)
01102
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 4.7C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:02/07/2024 14:33:18
Special precautions or instructions included?
Comments:
Page 35 of 36
Page 36 of 36
Appendix B
Concentrations versus Time Graph (MW-3D, MW-5D, and Influent)
0
1000
2000
3000
4000
5000
6000
7000
Co
n
c
(
µ
g
/
l
)
Date
Concentration vs. TimeGeneral Store of Denver
Benzene - MW-3D
MTBE MW-3D
Benzene MW-5D
MTBE MW-5D
Influent Benzene
Influent MTBE
Pumping Starts
Pumping Ceases
Pumping Restarts
Appendix C
Evaluation of Change in Contaminant Mass Calculations
Initial Aq. Thickness
ft2 ft ft3 (plume/source)porosity lb/ug l/gal gal/ft3 lbs
benzene 389637 30 11689110 11352150 0.1 7.45 2.20459E-09 3.79E+00 7.48E+00 0.53 a 1.07 (a+c)
MTBE 389637 30 11689110 11352150 0.1 45.5 2.20459E-09 3.79E+00 7.48E+00 3.22 b 6.05 (b+d)
benzene 11232 30 336960 336960 0.1 260 2.20459E-09 3.79E+00 7.48E+00 0.55 c 7.13
MTBE 11232 30 336960 336960 0.1 1345 2.20459E-09 3.79E+00 7.48E+00 2.83 d
closure Aq. Thickness
Date Years
Aq. Thickness
Aq. Thickness
Aq. Thickness
Aq. Thickness
Aq. Thickness
Evaluation of Change in Contaminant Mass Calculations
General Store of Denver
Sherrills Ford, North Carolina
H&H Job No. GSD-050
Evaluation of Change in Contaminant Mass Calculations
General Store of Denver
Sherrills Ford, North Carolina
H&H Job No. GSD-050
Date Years
Aq. Thickness
Aq. Thickness
Aq. Thickness
Aq. Thickness
Aq. Thickness
Aq. Thickness
Aq. Thickness
Evaluation of Change in Contaminant Mass Calculations
General Store of Denver
Sherrills Ford, North Carolina
H&H Job No. GSD-050
Date Years
Aq. Thickness
Aq. Thickness
Aq. Thickness
Aq. Thickness totals
Aq. Thickness totals
Aq. Thickness totals