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HomeMy WebLinkAboutMO-5325_18450_CA_CAPR_20240405_Monitoring Report Via Email April 5, 2024 North Carolina Department of Environmental Quality Mooresville Regional Office 610 East Center Ave. Mooresville, NC 28115 Attention: Mr. Brad Newton Re: Monitoring Report General Store of Denver Sherrils Ford, North Carolina NCDENR Incident No. 18450 H&H Project No. GSD-050 Dear Mr. Newton: Please find attached a Monitoring Report for the General Store of Denver. Please feel free to contact me with any questions and/or comments. Sincerely, Hart & Hickman, PC Stephen R. Libbey, PG Project Manager Attachments Monitoring Report General Store of Denver 6360 NC Highway 150 East Sherrills Ford, North Carolina DEQ Incident Number: 18450 H&H Job No. GSD-050 April 5, 2024 #C-1269 Engineering #245 Geology Title Page Site Information: General Store of Denver 6360 NC Highway 150 East Sherrills Ford, NC 28673 Facility ID Number: 0-002395 NC DEQ Incident Number: 18450 Latitude/Longitude: N35°34’20” W81°02’28” Risk Classification: High Risk H596E – Water Supply Wells within 1,000 ft Land Use: Residential UST Owner & Operator: General Store of Denver, Inc. 6360 NC Highway 150 East Sherrills Ford, NC 28673 Attn: Frank Craven (704) 483-2686 Property Owner: FMC Properties, LLC 6360 NC Highway 150 East Sherrills Ford, NC 28673 (704) 483-2686 Consultant: Hart & Hickman, PC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 Attn: Mr. Stephen Libbey, PG and Matt Bramblett, PE (704) 586-0007 Release Information: Release Discovery Date: March 1998 Estimated Quantity of Release: Unknown Cause/Source of Release: Suspected to be kerosene and gasoline UST systems Laboratory: Pace Analytical Services, Inc., NC Certification Nos. 12/37706 Waypoint Analytical, NC Certification Nos. 402/37735 i https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Monitoring Report/MO-5325_18450_CA_MRP_20240405_Monitoring Report.doc Monitoring Report General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 Table of Contents Section Page No. 1.0 Introduction .............................................................................................................................1 2.0 Site History ..............................................................................................................................2 3.0 Groundwater Sampling ..........................................................................................................4 3.1 Water Levels .........................................................................................................................4 3.2 Monitoring Well Sampling ...................................................................................................4 4.0 Water Supply Well Sampling ................................................................................................5 5.0 Remediation System................................................................................................................6 5.1 General Description ..............................................................................................................6 5.2 Groundwater Recovery .........................................................................................................6 5.3 Groundwater Treatment ........................................................................................................7 5.4 Operating Status ....................................................................................................................8 5.5 Groundwater Treatment System Sampling ...........................................................................8 5.6 Cleanup Progress Milestones ................................................................................................9 6.0 Conclusions and Recommendations ....................................................................................12 ii https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Monitoring Report/MO-5325_18450_CA_MRP_20240405_Monitoring Report.doc List of Tables Table 1 Water Supply Well Inventory Table 2 Monitoring Well Water Level Data Table 3 Monitoring Well Groundwater Analytical Detections Table 4 Summary of Water Supply Well Sample Results Table 5 Summary of Influent and Effluent Sample Results Table 6 Summary of Mass Removal – Groundwater Remediation System Table 7 Evaluation of Change in Contaminant Mass List of Figures Figure 1 Site Location Map Figure 2 Site Layout Figure 3 Water Supply Well Survey Map Figure 4 Deep Well Groundwater Elevations (August 2023) Figure 5 Benzene and MTBE Concentrations in Groundwater (February 2024) Figure 6 Treatment System Schematic Figure 7 Estimated Extent of Benzene and MTBE Groundwater Impacts Prior to Remediation Figure 8 Estimated Extent of Current Benzene and MTBE Groundwater Impacts List of Appendices Appendix A Laboratory Analytical Reports and Chain-of-Custody Forms Appendix B Concentrations versus Time Graph (MW-3D, MW-5D, and Influent) Appendix C Evaluation of Change in Contaminant Mass Calculations 1 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Monitoring Report/MO-5325_18450_CA_MRP_20240405_Monitoring Report.doc Monitoring Report General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 1.0 Introduction On behalf of FMC Properties, LLC, Hart & Hickman, PC (H&H) has completed a Monitoring Report for the General Store of Denver (GSD) facility located at 6360 NC Highway 150 East in Sherrills Ford, Catawba County, North Carolina. The GSD facility is a grocery and retail petroleum distribution facility. A hardware store is also located at the site. The North Carolina Department of Environmental Quality (DEQ) groundwater incident number is 18450, and DEQ has assigned the site a high-risk classification due to the presence of nearby water supply wells. A site location map is included as Figure 1, and a site map is included as Figure 2. During the current six-month reporting period, H&H operated the pump and treat system between September 2023 and December 2023. As recommended in the December 2023 Corrective Action Performance Report (CAPR) that DEQ approved in a subsequent Acknowledgment of Receipt letter dated December 20, 2023, the treatment system was shut down on December 29, 2023. Monitored Natural Attenuation (MNA) closure sampling was initiated at that time. This report documents the performance of the remediation system operation and maintenance (O&M) activities for the period of September 2023 through December 2023 and the first semi- annual MNA closure sampling event conducted in February 2024. 2 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Monitoring Report/MO-5325_18450_CA_MRP_20240405_Monitoring Report.doc 2.0 Site History A kerosene UST was removed from the site in March 1998 and impacted soil was detected. Two other surface releases of petroleum also are documented at the site. At the time of assessment and corrective action planning, municipal water was not available. However, a waterline has since been installed adjacent to the site, and municipal water is available in the vicinity of the site. Assessment conducted at the site since 1998 indicated on-site groundwater is impacted with benzene and MTBE at levels above the North Carolina groundwater standards but below DEQ- defined Gross Contamination Level (GCLs). The impacted groundwater is primarily detected within the fractured bedrock underlying the site. Additionally, benzene and MTBE were historically detected in six off-site water supply wells. The impacted wells are oriented along a north-northeast trend coincident with the dominant fracture trend in the area. The furthest historically impacted water supply well from the site is located approximately 1,500 ft from the source area. A Corrective Action Plan (CAP) was submitted to DEQ on November 27, 2002 recommending active remediation of the soil by vapor extraction coupled with a groundwater remedy involving lowering the site risk by means of alternate water supply. DEQ requested that an aquifer test be conducted and requested additional information regarding potential implementation of active remediation using groundwater pump and treat. An addendum with the supplemental information was submitted to DEQ on May 5, 2003 and approved in a Notice of Regulatory Requirement (NORR) dated May 19, 2003. Soil remediation by vapor extraction was not approved by DEQ. Design and other tasks required to implement the remedial option began immediately. However, the installation and operation of the treatment system was delayed due to requirements for the National Pollutant Discharge Elimination System (NPDES) discharge permit and required access agreement from the North Carolina Department of Transportation for discharge to a dry stormwater conveyance swale located north and adjacent to the site. The installation of the 3 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Monitoring Report/MO-5325_18450_CA_MRP_20240405_Monitoring Report.doc groundwater recovery and treatment system was completed in August 2004, and system operation commenced on August 13, 2004. The groundwater recovery and treatment system operated until July 29, 2005 at which time the system was deactivated per DEQ’s July 2005 NORR indicating the work at the site was no longer directed. Municipal water was extended to the site in late 2004 and early 2005. At DEQ’s request, H&H conducted a limited water supply well survey in June 2005 to determine the status of municipal water connections at that time. Based partially on the data in the well survey, on July 15, 2005 DEQ issued a NORR indicating the site did not meet the requirements for further assessment or corrective action. Therefore, the system was shut down pending further direction from DEQ. DEQ issued another NORR on January 26, 2006, indicating the site was of sufficiently high priority to allow funding by the State Trust Fund Program and that work indicated in the NORR dated May 19, 2003 was directed to proceed. H&H completed a water supply well survey update for the area within a 1,500-ft radius of the former UST basin in 2020. H&H identified the presence of 29 water supply wells within 1,500 ft of the UST basin (Figure 3). Of these 29 water supply wells, 18 are used for drinking water and one is used for non-drinking water purposes only. The remaining 10 water supply wells are not active. Municipal water is provided to the site and is available to properties within a 1,500-ft radius of the site. Water supply well owner information is presented in Table 1. 4 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Monitoring Report/MO-5325_18450_CA_MRP_20240405_Monitoring Report.doc 3.0 Groundwater Sampling 3.1 Water Levels The first semi-annual MNA closure sampling event was conducted on February 6, 2024. During the event, H&H inadvertently neglected to collect water levels in the site wells. Water levels will be collected from site wells during the next semi-annual sampling event. Historical water level measurements are summarized on Table 2. A potentiometric map based on data collected from the deep wells in September 2023, along with knowledge of prior data, is presented as Figure 4. Historical potentiometric data indicate that groundwater flow at the site is generally to the northeast. 3.2 Monitoring Well Sampling Deep recovery wells MW-3D and MW-5D were sampled on February 6, 2024. Groundwater samples were poured in laboratory supplied containers, marked with identifying labels, and placed in an iced cooler for shipment under chain-of-custody to a certified laboratory for analyses. Groundwater samples were analyzed for volatile organic compounds (VOCs) including methyl tertiary butyl ether (MTBE), isopropyl ether (IPE), and xylenes by EPA Method 6200B (Table 3). The laboratory analytical reports are provided in Appendix A. During the February 2024 sampling event, benzene was not detected above the laboratory detection limit and MTBE (616 µg/l) was detected at a concentration above the North Carolina Administrative Code, Subchapter 2L Groundwater Standards (2L Standard) in MW-3D. The detected MTBE concentration was not above the GCL. Additionally, benzene and MTBE were not detected above the laboratory detection limits in monitoring well MW-5D. A graph showing the benzene and MTBE concentrations with time for MW-3D, MW-5D, and the system influent is presented in Appendix B. Due to the nature of the petroleum impacts in fractured rock and the limited extent of VOC groundwater detections, isoconcentration maps cannot be prepared. However, benzene and MTBE concentrations for the February 2024 groundwater sampling event are presented on Figure 5. 5 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Monitoring Report/MO-5325_18450_CA_MRP_20240405_Monitoring Report.doc 4.0 Water Supply Well Sampling H&H collected samples from the Former Daycare Well (Map ID 16) and Keller/Rawlings #2 water supply well (Map ID 37) on November 20, 2023 and February 6, 2024. The former Daycare Well is not used for drinking water and bottled water is provided, as needed. The property using the Former Daycare Well for non-potable water is occupied by a musician that uses the building for instrument sales and instrument lessons. Samples collected were submitted to a North Carolina certified laboratory for analysis of VOCs by EPA Method 6200B. The analytical data reports for the water supply well sampling events are included in Appendix A. No target compounds were detected above the laboratory detection limits in the Former Daycare well and the Keller/Rawlings #2 well in November 2023 and February 2024. Historical supply well sampling data are presented in Table 4. The recent results are also provided on Figure 3. Based on approval from DEQ, the Christenbury water supply well has not been sampled since October 2006 because of the prior consistent absence of petroleum compounds in the water well samples. The Rawlings/Abernathy well was not sampled because the well has been inoperable since the October 2006 sampling event. The trailer home at the Rawlings/Abernathy well property is currently vacant, and the property has been connected to city water. The Bach/Innes well has been decommissioned due to extension of the municipal waterline to the area. As such, the multiple prior users of this well have been connected to municipal water. 6 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Monitoring Report/MO-5325_18450_CA_MRP_20240405_Monitoring Report.doc 5.0 Remediation System 5.1 General Description The recovery/treatment system is comprised of groundwater recovery via pneumatic pumps and treatment via air stripping and carbon polishing. Treated groundwater is discharged via NPDES General Permit NCG510000 under Certificate of Coverage NCG510500. As directed by DEQ, groundwater is recovered from two existing bedrock monitoring wells and treatment of the recovered groundwater is conducted using a low-profile air stripper and carbon polishing located within a dedicated 10 ft x 10 ft treatment building. The treated groundwater is then discharged to a stormwater swale located approximately 140 ft away and topographically downgradient of the system under the NPDES General Permit NCG510000. The locations of the system components are indicated on Figure 2. A schematic of the recovery and treatment system components is indicated on Figure 6. 5.2 Groundwater Recovery The system utilizes two pre-existing bedrock monitoring wells (MW-3D and MW-5D) for groundwater recovery per DEQ’s requirements in their May 19, 2003 CAP approval letter. These wells are two-inch diameter PVC monitoring wells. MW-3D is 85 ft deep and MW-5D is 95 ft deep. These wells have historically contained the highest concentrations of petroleum- related constituents at the site. Groundwater was previously recovered from each well using controllerless, top-loading, pneumatic pumps (CEE Model AP-2). The pumps were discovered to be malfunctioning in June 2018. As a result, 2-inch diameter 48-inch long pneumatic pumps (QED Model Genie Pumps) were installed in each well on July 2, 2018. The air supply for the pneumatic pumps is from a 1.5 horsepower (hp), industrial duty, reciprocating, two stage, splash lubricated, Saylor-Beall air compressor. This compressor is 7 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Monitoring Report/MO-5325_18450_CA_MRP_20240405_Monitoring Report.doc designed to deliver 7.3 standard cubic ft per minute (scfm) of air at 100 pounds per square inch (psi). 5.3 Groundwater Treatment Figure 2 indicates the layout of the treatment system. Groundwater recovered from the monitoring/recovery wells is pumped via sub-grade piping to the treatment system housed in a dedicated treatment building located east of the hardware store. The system contains a surge tank, an air stripper, a blower, two carbon canisters installed in series, and associated controls. Recovered groundwater is pumped to a 220-gallon, molded polyethylene surge tank equipped with high-high-, high-, and low-level switches. When the high-level switch is tripped, the groundwater is pumped to the air stripper via a ½ hp centrifugal transfer pump (American Stainless Model #SSPC1) through an Amtek #PBH polypropylene vessel containing a 25-micron filter bag. The air stripper is a Northeast Environmental Products (NEEP) ShallowTray Model 2331-P constructed of three Series 2300 polyethylene trays. After treatment via air stripping, the effluent is pumped through a carbon-polishing unit. Two 300-pound carbon vessels (TetraSolv Model AFD#85) are set up in series and filled with 8 x 30-mesh carbon. The carbon is used as a polishing step and, due to the efficiency of the air stripping, it is not expected that breakthrough of petroleum constituents will occur within the project life. Sampling ports are installed prior to the surge tank, after the air stripper but before carbon polishing, between carbon vessels, and after the carbon vessels. A dedicated control panel is part of the treatment system. The controls prevent discharge of untreated water by shutting off the recovery pumps when the surge tank is full and/or in the event of an air stripper malfunction. A flow meter is installed at the system discharge to measure the treated effluent volume. The system was initially activated in August 2004 and was deactivated in July 2005 per DEQ’s 8 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Monitoring Report/MO-5325_18450_CA_MRP_20240405_Monitoring Report.doc July 2005 NORR indicating the work at the site was no longer directed. At the time of deactivation, 101,581 gallons of groundwater had been recovered and treated. The system was reactivated on May 19, 2006. On that date, H&H revisited the site, installed new carbon drums due to leakage developing during system inactivity, and restarted the system. During the system shutdown, the internal flow meter battery had discharged and the flow meter reset to zero. On August 18, 2017, H&H discovered that the treatment system carbon drums were leaking. As a result, the system was shut down in order to replace the drums. In September 2017, DEQ Trust Fund requested that the system be repaired and remain off until its effectiveness could be further evaluated. The system carbon drums were replaced on November 17, 2017. In late 2017, DEQ requested that the treatment system be restarted. As a result, the system was reactivated on March 20, 2018. As stated above, new 2-inch diameter 48-inch long pneumatic pumps (QED Model Genie Pumps) were installed in each recovery well on July 2, 2018. 5.4 Operating Status The treatment system operated as designed between September 2023 and December 2024. Because the treatment system has reached asymptotic levels and continued operation of the system to achieve 2L Standards is no longer cost-effective nor feasible, H&H recommended discontinuing active groundwater remediation and initiating MNA closure sampling in the December 2023 CAPR. DEQ approved system shutdown and MNA closure sampling in the Acknowledgment of Receipt letter dated December 20, 2023. Based on DEQ approval, the system was shut down on December 29, 2023. 5.5 Groundwater Treatment System Sampling During the current reporting period, influent and effluent samples were collected on August 16, 2023 and November 20, 2023 and analyzed for oil and grease, total phenolics, total suspended solids (TSS), lead, and VOCs. The VOCs analytes included benzene, ethylbenzene, toluene, xylenes, MTBE, naphthalene, and 1,2-dichloroethane as required by the NPDES permit. Laboratory analytical data are provided in Appendix A. Table 5 summarizes the analytical 9 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Monitoring Report/MO-5325_18450_CA_MRP_20240405_Monitoring Report.doc results and the historical influent and effluent sampling results. Select target VOCs were detected in the influent samples. The August and November 2023 effluent results indicated no detectable concentrations of VOCs. Table 6 summarizes the mass removal for benzene and MTBE using the remediation system. During the current reporting period, approximately 0.07 lb of MTBE was removed from the groundwater. Based on the influent sampling results, no benzene was removed from groundwater during the current reporting period. Overall, approximately 0.3 lb of benzene and 11 lbs of MTBE were removed from groundwater during the treatment system operation (Table 6). 5.6 Cleanup Progress Milestones As previously indicated, a CAP was submitted to DEQ in November 27, 2002 recommending active remediation of the soil by vapor extraction coupled with a ground water remedy involving lowering the site risk by means of alternate water supply. On March 31, 2003, DEQ issued correspondence to the General Store requesting additional activities in response to the CAP submitted on November 27, 2002. The DEQ correspondence indicated that the CAP would not be approved as DEQ believed pump and treat was the only acceptable remedial method. Due to the uncertainty in implementing an active remedy of this type in the complex fracture rock environment at the General Store, H&H has conducted ongoing evaluation of system performance and applicability in meeting the project objectives outlined in the November 2002 CAP. Additionally, the General Store has periodically evaluated lowering the site risk to low by providing a long-term alternate water supply to surrounding water supply users. Several connections have been completed during the historical remediation period; however, active drinking water wells still exist surrounding the site. In an attempt to expedite site closure, in April 2021 DEQ requested that H&H evaluate connecting the remaining drinking water wells within a 1,000 ft radius of the site to the municipal water supply. A total of six water supply wells would need to be abandoned to lower 10 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Monitoring Report/MO-5325_18450_CA_MRP_20240405_Monitoring Report.doc the site risk. Currently, only the owner of the Former Daycare Well (Map ID 16) has agreed to connect to the municipal water supply. H&H has received a Task Authorization (TA) from the State Trust Fund for the estimated costs to connect this well user to the municipal water supply. Hickory Water and Sewer requires that the land owner sign the water connection application in person at their office. To date, H&H has been unable to schedule a day to meet with the well owner at Hickory Water and Sewer based on their current work schedule. Current remediation performance monitoring requires milestones be established for the site. Remediation milestones were not originally included in the CAP because pump and treat technology was not the H&H selected remedial alternative and based on the requirements at the time when the CAP was prepared. However, during H&H’s evaluation of treatment alternatives, pump and treat combined with soil vapor extraction was estimated to take approximately 5 to 10 years to achieve site closure. Because soil vapor extraction was not approved by DEQ, the time for cleanup was extended. Based on historical groundwater system operation and sampling data from the site, in 2017 H&H re-evaluated the anticipated time to achieve site closure and estimated the cleanup progress milestones as presented in Table 7. Because benzene and MTBE are the only compounds present at concentrations above groundwater standards, only mass milestones for these compounds (combined) were calculated and included in the table. The initial step was to calculate the initial plume mass where benzene and MTBE concentrations exceeded groundwater standards. Using pre-pumping data from October 2003, initial plume mass in two areas were calculated: for the plume center (Figure 4) and the remainder of the plume (Figure 5). The average benzene and MTBE concentrations for MW-3D and MW-5D were utilized for the central portion of the plume where more substantial contaminant mass is present, and the average benzene and MTBE concentrations for two water supply wells (Rawlings/Abernathy and Former Daycare) were utilized for the remainder of the plume. The plume mass was calculated by Area of Water (v) x Plume Thickness (d) x Average Concentrations of Benzene and MTBE (c) x Porosity of Aquifer (n) using the following assumptions: • Porosity (n) of 0.1 for fractured bedrock; • Plume thickness (d) of 30 ft based on CAP; 11 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Monitoring Report/MO-5325_18450_CA_MRP_20240405_Monitoring Report.doc • Initial area of plume center near MW-3D/5D (v) of 11,232 ft2; and, • Initial area of remaining plume (v) = 389,637 ft2. Then, a mass concentration for the plume at site closure was calculated using the above formula and based on the groundwater standards of 1 µg/l for benzene and 20 µg/l for MTBE. Current/closure remaining plume areas (v) of 11,232 ft2 (plume source area) and 37,142 ft2 (remaining plume area) were utilized to estimate the alternate allowable plume mass at site closure. The plume center area discussed above was utilized in the calculations. The estimated extent of the central plume area is depicted on Figure 5, and pre-pumping and current plumes are depicted on Figures 7 and 8, respectively. Using the initial plume mass, H&H calculated mass reduction milestones until the plume mass corresponding to the DEQ groundwater standards for benzene and MTBE would be achieved. As presented in Table 7, H&H anticipated that the remediation system would take at least 25 years to achieve DEQ groundwater standards and site closure. When the system was shut down in December 2023, it had operated for approximately 19.5 years. The average groundwater concentrations for MW-3D, MW-5D, and supply wells Rawlings/Abernathy and Former Daycare (if detections identified) were utilized to estimate the mass reduction rates. The most recent sampling data from February 2024 indicate the system had achieved an estimated mass reduction of approximately 89% from the baseline mass of 7.13 lbs to 0.77 lbs. H&H will continue to evaluate and update the milestone table during the MNA closure sampling events. 12 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Monitoring Report/MO-5325_18450_CA_MRP_20240405_Monitoring Report.doc 6.0 Conclusions and Recommendations The General Store of Denver is a high-risk site due to water supply wells within 1,000 ft of the source area. H&H collected samples from the Former Daycare and Keller/Rawlings #2 water supply wells in November 2023 and February 2024. No target compounds were detected in samples collected from these wells during the sampling events. As approved in the DEQ Acknowledgment of Receipt letter dated December 20, 2023, the treatment system was shut down and an MNA closure sampling period was initiated on December 29, 2023. No treatment system shutdowns were encountered during the final system operational period from September to December 2023. At the end of the time period described in this report, the system had completed approximately 19.5 years of active remediation since startup in 2004. The milestone for 19.5 years of active remediation indicates an estimated mass reduction of approximately 81.5% from the initial estimate. The current estimate, based on February 2024 groundwater data, indicates a mass reduction of approximately 89% from the initial mass estimate. While the mass reduction has been variable during system operation, these data show that the system and natural attenuation have potentially been effective at slowly removing VOCs at the site and the current milestone criteria have been met. Monitoring wells/recovery wells MW-3D and MW-5D were sampled as part of the first MNA closure sampling event in February 2024. MTBE was detected at a concentration above the 2L Standard in MW-3D, and benzene and MTBE were not detected above the laboratory detection limits in monitoring well MW-5D. The groundwater plume appears to be shrinking and the potential for site groundwater to impact surrounding water supply wells appears to be low. H&H recommends continuing the MNA closure sampling plan consisting of semi-annual water supply well and monitoring well sampling events. The next semi-annual MNA closure sampling event will be conducted in August 2024 with reporting in September 2024. As part of the next semi-annual reporting, H&H will evaluate plume stability for groundwater impacts at the site. The evaluation will include performing a Mann-Kendall statistical analysis of the VOC data in site wells. Should the results of the 13 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Monitoring Report/MO-5325_18450_CA_MRP_20240405_Monitoring Report.doc statistical analysis continue to indicate decreasing or stable VOC trends and water supply well results remain non-detect, risk-based closure for the site should be considered. However, some ongoing water supply well sampling may be warranted. During the MNA closure sampling period, H&H will continue to pursue connecting the Former Daycare water supply well user to the municipal water supply. 14 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Monitoring Report/MO-5325_18450_CA_MRP_20240405_Monitoring Report.doc Certification: 1. This report is submitted on-time. 2.This report meets the template requirements for information. 3.There are no other suspected source zone soils or free product outside of the assessed areas. 4.There has not been an unexpected increase in contaminant mass to suggest a new release or separate source. I, Stephen Libbey, PG for Hart & Hickman, PC do certify that the information contained in this report is correct and accurate to the best of my knowledge. Hart & Hickman, PC is licensed to practice geology and engineering in North Carolina. The certification numbs are C-245 and C-1269, respectively. 04/05/24 3 Unnamed Well 6267 NC Hwy 150 East 369606394241 6255 NC Hwy 150 East, Denver, NC 28037 12 Robinson Well 6445 NC Hwy 150 East 369607580239 Sue Christenbury 6375 NC Hwy 150 East, Sherrills Ford, NC 28673 16 Daycare Well 6367 NC Hwy 150 East 369606491471 Carlos Siega Revocable Trust 2242 Perth Road, Mooresville, NC 28117 historically supplied by the General 18 (Drum Well #2) @ Shop 6321 NC Hwy 150 East 369606398341 Evelyn Stutts 6022 NC Hwy 150 East, Sherrills Ford, NC 28037 Inactive potable wells; Restaurant connected to City water 35 Rescue Squad Well 4385 Mt. Pleasant Road 369718406047 PO Box 51, Sherrills Ford, NC 28673 Inactive potable well 37 Keller/Rawlings #1/#2 4295 Mt. Pleasant Road 369719504852 Julie Harwath 4295 Mt. Pleasant Road, Sherrills Ford, NC 28673 40 Gregory Well 6545 Emerald Isle Drive 369607591817 Lonnie Gregory 4356 Bach Drive, Sherrills Ford, NC 28673 6530 Emerald Isle and 4338 Mt. 49 Newell Well 4425 Tuttlewood Drive 369607594127 4425 Tuttlewood Drive, Sherrills Ford, NC 28673 Active potable well 57 Seagle/Humphries Well 6562 Emerald Isle Drive 369607595912 Robert Humphries 6562 Emerald Isle Drive, Sherrills Ford, NC 28673 59 Crutchfield Well 6552 Emerald Isle Drive 369719504195 Lawson Starnes 6552 Emerald Isle Drive, Sherrills Ford, NC 28673 6554 and 6548 Emerald Isle (both 62 Rawlings / Abernathy Well 369719506498 Jerome Bolick PO Box 402, Conover, NC 28613 Inactive potable well Potable Water Information 1/2 Bach / Innes Well, Unnamed Well No Address Listing 369606496587 Massey Holdings LLC PO Box 1114, Cornelius, NC 28031 Two inactive community wells formerly served multiple residence Map ID Well Name Property Address Tax ID Property Owner 369606380720 Joey Byrd PO Box 234, Moravian Falls, NC 28654 Owner Address Property owner information from 9/2020 receptor survey and Catawba County GIS website data Table 1 Water Supply Well Inventory The General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 Active potable well 32 6254 NC Hwy 150 East 369606390898 6254 Hwy 150 East, Denver, NC 28037 Active potable wells for campground 24 4464 Grassy Creek Road Hart & Hickman, PC Total TOC DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW Well Depth Elevation*(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft) ID (ft)(ft)04/01/98 07/19/99 04/03/00 12/14/00 09/18/01 08/20/02 04/23/03 08/12/04 01/21/05 04/27/05 04/28/06 TYPE II WELLS MW-1 55 88.35 49.35 39.00 43.45 44.90 42.36 45.99 MW-2 58 88.80 NI NI 43.30 45.50 42.22 46.58 44.80 44.00 55.29 33.51 46.48 42.32 42.92 45.88 43.03 45.77 NM NM NM NM NM NM MW-3 60 91.28 NI NI 52.10 39.18 51.05 40.23 51.30 39.98 59.45 31.83 55.71 35.57 49.91 41.37 51.69 39.59 NM NM NM NM NM NM MW-4 60 86.96 NI NI 50.60 36.36 49.28 37.68 51.54 35.42 55.38 31.58 53.55 33.41 46.97 39.99 48.91 38.05 NM NM NM NM NM NM MW-5 62 90.60 NI NI NI NI NI NI NI NI NI NI 53.54 37.06 48.00 42.60 50.22 40.38 NM NM NM NM NM NM TYPE III WELLS MW-1D 85 89.28 NI NI NI NI NI NI NI NI 51.70 37.58 52.72 36.56 46.96 42.32 49.42 39.86 49.07 40.21 48.75 40.53 48.84 40.44 MW-2D 85 91.07 NI NI NI NI NI NI NI NI 54.32 36.75 55.57 35.50 49.66 41.41 51.24 39.83 51.79 39.28 51.52 39.55 50.95 40.12 MW-3D 95 90.70 NI NI NI NI NI NI NI NI NI NI 55.45 35.25 49.28 41.42 51.02 39.68 MW-4D 100 93.26 NI NI NI NI NI NI NI NI NI NI 59.78 33.48 56.66 36.60 54.09 39.17 55.54 37.72 55.40 37.86 54.38 38.88 MW-5D 85 92.72 NI NI NI NI NI NI NI NI NI NI 61.38 31.34 58.81 33.91 55.30 37.42 MW-6D 89 85.18 NI NI NI NI NI NI NI NI NI NI 55.48 29.70 51.91 33.27 49.82 35.36 50.64 34.54 50.09 35.09 49.28 35.90 Notes: *TOC = Top of Casing elevation based on arbitrary datum assigned by Kimbrell & AssociatesMW-5, 4D, 5D, and 6D surveyed by H&H on 8/22/02 Table 2 Monitoring Well Water Level Data General Store of Denver Sherrills Ford, North Carolina Abandoned H&H Job No. GSD-050 Pumping PumpingPumping Pumping Pumping Pumping Hart & Hickman, PC Total TOC DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW Well Depth Elevation*(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft) ID (ft)(ft)07/31/06 10/27/06 04/20/07 10/30/2007 5/6/2008 10/10/2008 4/6/2009 10/2/2009 10/29/2010 4/27/2011 TYPE II WELLS MW-1 55 88.35 MW-2 58 88.80 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM MW-3 60 91.28 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM MW-4 60 86.96 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM MW-5 62 90.60 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM TYPE III WELLS MW-1D 85 89.28 49.77 39.51 50.05 39.23 49.10 40.18 51.57 37.71 51.62 37.66 53.35 35.93 49.92 39.36 47.97 41.31 45.85 43.43 49.05 40.23 49.38 39.90 49.47 39.81 MW-2D 85 91.07 52.11 38.96 52.73 38.34 51.32 39.75 51.46 39.61 54.66 36.41 54.66 36.41 53.23 37.84 50.39 40.68 49.36 41.71 51.10 39.97 57.70 33.37 52.18 38.89 MW-3D 95 90.70 MW-4D 100 93.26 55.15 38.11 55.93 37.33 54.96 38.30 56.95 36.31 58.69 34.57 59.05 34.21 58.24 35.02 56.09 37.17 52.86 40.40 53.71 39.55 55.05 38.21 55.00 38.26 MW-5D 85 92.72 MW-6D 89 85.18 49.95 35.23 50.68 34.50 49.71 35.47 52.07 33.11 53.63 31.55 54.00 31.18 52.71 32.47 49.34 35.84 47.41 37.77 48.48 36.70 50.03 35.15 50.61 34.57 Notes: *TOC = Top of Casing elevation based on arbitrary datum assigned by Kimbrell & AssociatesMW-5, 4D, 5D, and 6D surveyed by H&H on 8/22/02 Pumping 10/26/2011 Sherrills Ford, North Carolina H&H Job No. GSD-050 PumpingPumpingPumping Pumping PumpingPumping Abandoned Pumping Table 2 Monitoring Well Water Level Data General Store of Denver 4/21/2010 PumpingPumpingPumpingPumping Pumping Pumping Pumping Pumping Pumping PumpingPumpingPumpingPumpingPumpingPumpingPumping Hart & Hickman, PC Total TOC DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW Well Depth Elevation*(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft) ID (ft)(ft) TYPE II WELLS MW-1 55 88.35 MW-2 58 88.80 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM MW-3 60 91.28 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM MW-4 60 86.96 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM MW-5 62 90.60 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM TYPE III WELLS MW-1D 85 89.28 48.97 40.31 49.88 39.40 49.43 39.85 49.09 40.19 47.34 41.94 48.97 40.31 49.15 40.13 50.66 38.62 48.20 41.08 50.85 38.43 50.91 38.37 MW-2D 85 91.07 51.32 39.75 52.48 38.59 52.18 38.89 51.23 39.84 49.44 41.63 51.10 39.97 51.29 39.78 53.03 38.04 50.36 40.71 53.27 37.80 53.32 37.75 MW-3D 95 90.70 MW-4D 100 93.26 54.75 38.51 55.73 37.53 56.14 37.12 54.70 38.56 53.18 40.08 53.65 39.61 54.72 38.54 55.90 37.36 53.77 39.49 56.09 37.17 56.10 37.16 MW-5D 85 92.72 MW-6D 89 85.18 49.53 35.65 50.44 34.74 50.75 34.43 49.14 36.04 47.83 37.35 48.42 36.76 49.20 35.98 50.68 34.50 48.31 36.87 50.90 34.28 50.85 34.33 Notes: MW-5, 4D, 5D, and 6D surveyed by H&H on 8/22/02 4/22/2015 10/15/201510/31/2014 4/27/2016 4/28/201710/26/2016 Table 2 Monitoring Well Water Level Data General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 Pumping 5/29/201410/31/2012 Pumping PumpingPumping Pumping Pumping Pumping Pumping Pumping 4/30/20134/30/2012 11/21/2013 Abandoned Pumping Pumping Pumping Pumping PumpingPumping Pumping Pumping Pumping Pumping Pumping Pumping Pumping Hart & Hickman, PC Total TOC DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW DTW GW Well Depth Elevation*(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft)(ft)Elev (ft) ID (ft)(ft) TYPE II WELLS MW-1 55 88.35 MW-2 58 88.80 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM MW-3 60 91.28 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM MW-4 60 86.96 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM MW-5 62 90.60 NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM NM TYPE III WELLS MW-1D 85 89.28 49.90 39.38 49.23 40.05 49.16 40.12 45.43 43.85 48.53 40.75 45.90 43.38 45.00 44.28 46.38 42.90 49.92 39.36 51.43 37.85 49.62 39.66 48.42 40.86 MW-2D 85 91.07 52.34 38.73 51.44 39.63 51.25 39.82 46.95 44.12 50.48 40.59 47.55 43.52 46.93 44.14 47.90 43.17 52.11 38.96 53.68 37.39 52.62 38.45 50.64 40.43 MW-3D 95 90.70 59.30 31.40 MW-4D 100 93.26 55.79 37.47 54.82 38.44 53.60 39.66 49.85 43.41 52.55 40.71 50.84 42.42 49.63 43.63 49.13 44.13 53.32 39.94 55.00 38.26 55.85 37.41 53.86 39.40 MW-5D 85 92.72 56.80 35.92 MW-6D 89 85.18 50.27 34.91 49.33 35.85 48.70 36.48 44.18 41.00 47.40 37.78 44.63 40.55 43.75 41.43 44.05 41.13 48.64 36.54 50.08 35.10 50.55 34.63 48.54 36.64 Notes: MW-5, 4D, 5D, and 6D surveyed by H&H on 8/22/02 Abandoned Table 2 Monitoring Well Water Level Data General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 Pumping Pumping Pumping Pumping PumpingPumping Pumping Pumping Pumping Pumping Pumping PumpingPumping Pumping Pumping Pumping Pumping Pumping Pumping Pumping Pumping Pumping Hart & Hickman, PC Table 3Monitoring Well Groundwater Analytical Detections General Store of DenverSherrills Ford, North CarolinaH&H Project GSD-050 Benzene Carbon Disulfide Chloroform Ethylbenzene Isopropyl-benzene Isopropyl-ether MTBE Naphthalene n-propyl-benzene Toluene 1,2,4- Trimethyl- benzene 1,3,5- Trimethyl- benzene Xylenes Semi- Volatiles (µg/l) VPH C5-C8 Aliphatics VPH C9-C12 Aliphatics VPH C9-C10 Aromatics C9-C18 Aliphatic Hydrocarbon C19-C36 Aliphatic Hydrocarbon C11-C22 Aromatic Hydrocarbon 9/13/2001 <1.00 NA <1.0 <1.00 NA <1.00 <1.00 <13.5 NA <1.00 NA NA <1.00 ND <100 <100 <100 <111 <111 <111 NA NA 2/19/2002 <0.4 <0.4 <0.4 <0.4 <0.4 <2.0 <0.4 <1.0 <0.4 <0.4 <0.4 <0.4 <0.4 ND <100 <100 <100 <102 <102 <102 NA NA 8/13/2004 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 NA NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA 1/21/2005 <1.0 NA <1.0 <1.0 <1.0 <1.0 <1.0 <2.0 NA <1.0 <1.0 <1.0 <1.0 NA NA NA NA NA NA NA NA NA 4/27/2005 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA 4/28/2006 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA 7/31/2006 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 NA NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA 10/27/2006 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <1.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA 4/20/2007 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <1.0 NA <1.0 NA NA <3.0 NA NA NA NA NA NA NA NA NA 10/30/2007 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <1.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA 5/6/2008 <0.50 NA <1.0 <1.0 NA <5.0 <5.0 <1.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA 10/10/2008 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA 4/6/2009 <0.50 NA 1.6 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/2/2009 <0.50 NA 0.78 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/21/2010 <0.50 NA 1.1 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/19/2010 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/27/2011 <0.50 NA <0.50 0.66 <0.50 <0.50 <0.50 7.3 <0.50 3.4 2.6 0.84 5.5 NA NA NA NA NA NA NA NA NA 10/26/2011 <0.50 NA <0.50 0.66 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 0.83 1.9 NA NA NA NA NA NA NA NA NA 4/30/2012 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 0.56 <0.50 0.71 NA NA NA NA NA NA NA NA NA 10/31/2012 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/30/2013 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 11/21/2013 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 5/29/2014 <0.50 NA <0.50 <0.50 <0.50 <0.50 <1.0 <1.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/31/2014 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/22/2015 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/15/2015 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/27/2016 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 9/13/2001 <1.00 NA <1.0 <1.00 NA <1.00 46.2 <10.0 NA <1.00 NA NA <1.00 ND <100 <100 <100 <111 <111 <111 NA NA 2/19/2002 <0.4 <0.4 <0.4 <0.4 <0.4 <2.0 54.9 <1.0 <0.4 <0.4 <0.4 <0.4 <0.4 ND <100 <100 <100 <102 <102 <102 NA NA 8/13/2004 <1.0 NA <1.0 <1.0 NA <1.0 3.8 NA NA 1.4 NA NA <1.0 NA NA NA NA NA NA NA NA NA 1/21/2005 <1.0 NA <1.0 <1.0 <1.0 <1.0 76 <2.0 NA 5.4 <1.0 <1.0 <1.0 NA NA NA NA NA NA NA NA NA 4/27/2005 <5.0 NA <5.0 <5.0 NA <5.0 91 <10 NA <5.0 NA NA <5.0 NA NA NA NA NA NA NA NA NA 4/28/2006 <2.0 NA <2.0 <2.0 NA <2.0 66 <4.0 NA <2.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA 7/31/2006 <2.0 NA <2.0 <2.0 NA <2.0 65 NA NA <2.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA 10/27/2006 <1.0 NA <1.0 <1.0 NA <1.0 36 <1.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA 4/20/2007 <1.0 NA <1.0 <1.0 NA <1.0 14 <2.0 NA <1.0 NA NA <3.0 NA NA NA NA NA NA NA NA NA 10/30/2007 <1.0 NA <1.0 <1.0 NA <1.0 8.6 <2.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA 5/6/2008 <0.5 NA <1.1 <1.0 NA <5.0 <5.0 <1.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA 10/10/2008 <1.0 NA <1.2 <1.0 NA <1.0 3.3 <2.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA 4/6/2009 <0.50 NA <1.3 <0.50 <0.50 <0.50 1.3 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/2/2009 <0.50 NA <1.4 <0.50 <0.50 <0.50 3.5 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/21/2010 <0.50 NA <1.5 <0.50 <0.50 <0.50 3.1 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/19/2010 <0.50 NA <1.6 <0.50 <0.50 <0.50 66.2 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/27/2011 1.7 NA <1.7 <0.50 <0.50 <0.50 47.5 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/26/2011 0.76 NA <1.8 <0.50 <0.50 <0.50 26.8 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/30/2012 <0.50 NA <1.9 <0.50 <0.50 <0.50 20.8 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/31/2012 3.3 NA <1.10 <0.50 <0.50 <0.50 100 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/30/2013 <0.50 NA <1.11 <0.50 <0.50 <0.50 5.9 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 11/21/2013 <0.50 NA <1.12 <0.50 <0.50 <0.50 16.9 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 5/29/2014 0.52 NA <0.50 <0.50 <0.50 <0.50 21 <1.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/31/2014 <0.50 NA <0.50 <0.50 <0.50 <0.50 9.0 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/22/2015 <0.50 NA <0.50 <0.50 <0.50 <0.50 9.6 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/15/2015 <0.50 NA <0.50 <0.50 <0.50 <0.50 6.0 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA MW-2D MW-1D Lead (µg/l)Well ID Sample Date Phenol (µg/l) https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsxDeep T-24/5/2024 Table 3 (Page 1 of 4)Hart & Hickman, PC Table 3Monitoring Well Groundwater Analytical Detections General Store of DenverSherrills Ford, North CarolinaH&H Project GSD-050 Benzene Carbon Disulfide Chloroform Ethylbenzene Isopropyl-benzene Isopropyl-ether MTBE Naphthalene n-propyl-benzene Toluene 1,2,4- Trimethyl- benzene 1,3,5- Trimethyl- benzene Xylenes Semi- Volatiles (µg/l) VPH C5-C8 Aliphatics VPH C9-C12 Aliphatics VPH C9-C10 Aromatics C9-C18 Aliphatic Hydrocarbon C19-C36 Aliphatic Hydrocarbon C11-C22 Aromatic Hydrocarbon Lead (µg/l)Well ID Sample Date Phenol (µg/l) 2/19/2002 316 2.7 <0.4 <0.4 2.4 10.0 1,760 4.4 <0.4 <0.4 <0.4 <0.4 50 ND 2,410 <100 <100 NA <102 <102 NA NA 10/16/2003 40 NA <5 <5 <5 7.6 990 <5 <5 <5 <5 <0.4 <5 NA NA NA NA NA NA NA 12 <5 8/13/2004 100 NA <1.0 <1.0 NA 1.1 76 NA NA <1.0 NA NA 1.1 NA NA NA NA NA NA NA NA NA 1/21/2005 3.0 NA <0.50 <0.50 <0.50 9.6 1,400 <2.0 NA <0.5 <0.5 <0.5 <0.5 NA NA NA NA NA NA NA NA NA 4/27/2005 100 NA <1.0 <1.0 NA 13 1,800 <2.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA 4/28/2006 190 NA <50 <50 NA <50 2,700 <100 NA <50 NA NA <50 NA NA NA NA NA NA NA NA NA 7/31/2006 130 NA <50 <50 NA <50 2,900 NA NA <50 NA NA <50 NA NA NA NA NA NA NA NA NA 10/27/2006 <50 NA <50 <50 NA <50 2,800 <100 NA <50 NA NA <50 NA NA NA NA NA NA NA NA NA 4/20/2007 100 NA <100 <100 NA <100 4,200 <200 NA <100 NA NA <300 NA NA NA NA NA NA NA NA NA 11/6/2007 <100 NA <100 <100 NA <100 3,870 <200 NA <100 NA NA <200 NA NA NA NA NA NA NA NA NA 5/6/2008 150 NA <10 <10 NA <50 4,500 <10 NA <10 NA NA <20 NA NA NA NA NA NA NA NA NA 10/10/2008 <100 NA <100 <100 NA <100 4,230 <200 NA <100 NA NA <200 NA NA NA NA NA NA NA NA NA 4/6/2009 <10.0 NA <10.0 <10.0 <10.0 15.0 3,430 <40.0 <10.0 <10.0 <10.0 <10.0 <30.0 NA NA NA NA NA NA NA NA NA 10/2/2009 290 NA <5.0 <5.0 <5.0 15 4,400 <20 <5.0 <5.0 <5.0 <5.0 <15.0 NA NA NA NA NA NA NA NA NA 4/21/2010 118 NA <12.5 <12.5 <12.5 <12.5 3,490 <50 <12.5 <12.5 <12.5 <12.5 <37.5 NA NA NA NA NA NA NA NA NA 10/29/2010 246 NA <12.5 <12.5 <12.5 29 5,410 <50 <12.5 <12.5 <12.5 <12.5 <37.5 NA NA NA NA NA NA NA NA NA 4/27/2011 <12.5 NA <12.5 <12.5 <12.5 14 3,480 <50 <12.5 <12.5 23.5 <12.5 <37.5 NA NA NA NA NA NA NA NA NA 10/26/2011 188 NA <0.50 <0.50 2.3 27.7 5,980 5.5 <0.50 <0.50 <0.50 <0.50 2.4 NA NA NA NA NA NA NA NA NA 4/30/2012 <25.0 NA <25.0 <25.0 <25.0 <25.0 4,480 <100 <0.50 <0.50 <0.50 <0.50 <75.0 NA NA NA NA NA NA NA NA NA 10/31/2012 <12.5 NA <12.5 <12.5 <12.5 29.1 6,360 <50 <12.5 <12.5 <12.5 <12.5 <37.5 NA NA NA NA NA NA NA NA NA 4/30/2013 26.0 NA <25.0 <25.0 <25.0 32.5 6,720 <100 <25.0 <25.0 <25.0 <25.0 <75.0 NA NA NA NA NA NA NA NA NA 11/21/2013 59.3 NA <25.0 <25.0 <25.0 28.3 6,610 <100 <25.0 <25.0 <25.0 <25.0 <75.0 NA NA NA NA NA NA NA NA NA 5/29/2014 640 NA <0.50 <0.50 11 49 7,000 24 1.3 <0.50 1.1 0.64 7.6 NA NA NA NA NA NA NA NA NA 10/31/2014 <1.2 NA <1.2 <1.2 <1.2 <1.2 692 <5.0 <1.2 <1.2 <1.2 <1.2 <3.7 NA NA NA NA NA NA NA NA NA 4/22/2015 <2.5 NA <2.5 <2.5 <2.5 26.1 5,170 <10.0 <2.5 <2.5 <2.5 <2.5 <7.5 NA NA NA NA NA NA NA NA NA 10/15/2015 4.4 NA <2.5 <2.5 <2.5 <2.5 747 <10.0 <2.5 <2.5 <2.5 <2.5 <7.5 NA NA NA NA NA NA NA NA NA 4/27/2016 <5.0 NA <5.0 <5.0 <5.0 8.7 1,960 <20.0 <5.0 <5.0 <5.0 <5.0 <15.0 NA NA NA NA NA NA NA NA NA 10/28/2016 <10.0 NA <10.0 <10.0 <10.0 16.2 3,040 <40.0 <10.0 <10.0 <10.0 <10.0 <30.0 NA NA NA NA NA NA NA NA NA 4/28/2017 2.6 NA <1.2 <5.0 <1.2 <1.2 417 <5.0 <1.2 <1.2 <1.2 <1.2 <3.7 NA NA NA NA NA NA NA NA NA 11/17/2017 244 NA <20.0 <20.0 <20.0 32.8 5,570 <80.0 <20.0 <20.0 <20.0 <20.0 <60.0 NA NA NA NA NA NA NA NA NA 6/19/2018 55.1 NA <20.0 <20.0 <20.0 22.6 3,880 <80.0 <20.0 <20.0 <20.0 <20.0 <60.0 NA NA NA NA NA NA NA NA NA 12/20/2018 473 NA <12.5 <12.5 <12.5 24.5 3,990 <50.0 <12.5 <12.5 <12.5 <12.5 <37.5 NA NA NA NA NA NA NA NA NA 6/21/2019 111 NA <62.5 <6.2 <6.2 7.6 1,710 <25.0 <6.2 <6.2 <6.2 <6.2 <18.7 NA NA NA NA NA NA NA NA NA 1/15/2020 206 NA <12.5 <12.5 <12.5 20.8 3,210 <50.0 <12.5 <12.5 <12.5 <12.5 <27.5 NA NA NA NA NA NA NA NA NA 7/14/2020 391 NA <12.5 <12.5 <12.5 14.3 2,410 <50.0 <12.5 18.2 <12.5 <12.5 <27.5 NA NA NA NA NA NA NA NA NA 1/18/2021 283 NA <10.0 <10.0 <10.0 11.1 1,990 92.5 <10.0 <10.0 27.1 <10.0 37.5 NA NA NA NA NA NA NA NA NA 7/30/2021 186 NA <6.2 <6.2 <6.2 12.7 1,730 <25.0 <6.2 <6.2 <6.2 <6.2 <18.7 NA NA NA NA NA NA NA NA NA 1/27/2022 212 NA <5.0 <5.0 <5.0 13.2 1,620 <20.0 <5.0 <5.0 <5.0 <5.0 <15.0 NA NA NA NA NA NA NA NA NA 7/21/2022 <5.0 NA <5.0 <5.0 <5.0 10.8 1,350 <20.0 <5.0 <5.0 <5.0 <5.0 <15.0 NA NA NA NA NA NA NA NA NA 1/27/2023 <5.0 NA <5.0 <5.0 <5.0 10.2 1,480 <20.0 <5.0 <5.0 <5.0 <5.0 <15.0 NA NA NA NA NA NA NA NA NA 8/16/2023 95.1 NA <5.0 <5.0 <5.0 12.7 1,680 <20.0 <5.0 <5.0 <5.0 <5.0 <15.0 NA NA NA NA NA NA NA NA NA 2/6/2024 <0.500 NA <0.500 <0.500 <0.500 10.6 616 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500 NA NA NA NA NA NA NA NA NA 2/19/2002 0.6 1.0 0.7 0.4 <0.4 <2.0 8.0 <1.0 <0.4 <0.4 1.7 0.5 3.6 ND <100 <100 <100 <102 <102 <102 NA NA 8/13/2004 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 NA NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA 1/21/2005 <1.0 NA <1.0 <1.0 <1.0 <1.0 <1.0 <2.0 NA <1.0 <1.0 <1.0 <1.0 NA NA NA NA NA NA NA NA NA 4/27/2005 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA 4/28/2006 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA 7/31/2006 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 NA NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA 10/27/2006 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <1.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA 4/20/2007 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <1.0 NA <1.0 NA NA <3.0 NA NA NA NA NA NA NA NA NA 10/30/2007 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA 5/6/2008 <0.5 NA <1.0 <1.0 NA <5.0 <5.0 <1.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA 10/10/2008 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA 4/6/2009 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/2/2009 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/21/2010 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/29/2010 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/27/2011 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/26/2011 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/30/2012 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/31/2012 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/30/2013 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 11/21/2013 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 5/29/2014 <0.50 NA <0.50 <0.50 <0.50 <0.50 <1.0 <1.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/31/2014 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/22/2015 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/15/2015 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA MW-4D MW-3D(1) https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsxDeep T-24/5/2024 Table 3 (Page 2 of 4)Hart & Hickman, PC Table 3Monitoring Well Groundwater Analytical Detections General Store of DenverSherrills Ford, North CarolinaH&H Project GSD-050 Benzene Carbon Disulfide Chloroform Ethylbenzene Isopropyl-benzene Isopropyl-ether MTBE Naphthalene n-propyl-benzene Toluene 1,2,4- Trimethyl- benzene 1,3,5- Trimethyl- benzene Xylenes Semi- Volatiles (µg/l) VPH C5-C8 Aliphatics VPH C9-C12 Aliphatics VPH C9-C10 Aromatics C9-C18 Aliphatic Hydrocarbon C19-C36 Aliphatic Hydrocarbon C11-C22 Aromatic Hydrocarbon Lead (µg/l)Well ID Sample Date Phenol (µg/l) 2/19/2002 217 <0.4 <0.4 <0.4 3.8 3.0 257 7.1 0.4 0.6 <0.4 <0.4 38.7 ND 988 <100 <100 <102 <102 <102 NA NA 10/16/2003 480 NA <5 <5 <5 11.0 1,700 12 <5 <5 <5 <5 85 NA NA NA NA NA NA NA 240 <5 8/13/2004 520 NA <1.0 <1.0 NA 7.5 1,100 NA NA <1.0 NA NA 23 NA NA NA NA NA NA NA NA NA 1/17/2005 95 NA <5.0 <5.0 <5.0 8.2 1,500 <20 <5.0 <5.0 <5.0 <5.0 <0.5 NA NA NA NA NA NA NA NA NA 4/27/2005 76 NA <1.0 <1.0 NA 7.7 1,100 <2.0 NA <2.0 NA NA 15 NA NA NA NA NA NA NA NA NA 4/28/2006 140 NA <20 <20 NA <20 660 <40 NA <20 NA NA <20 NA NA NA NA NA NA NA NA NA 7/31/2006 160 NA <20 <20 NA <20 1,200 NA NA <20 NA NA <20 NA NA NA NA NA NA NA NA NA 10/27/2006 150 NA <25 <25 <25 <25 1,100 <40 NA <25 NA NA <25 NA NA NA NA NA NA NA NA NA 4/20/2007 310 NA <25 <25 NA <25 1,300 <50 NA <25 NA NA <75 NA NA NA NA NA NA NA NA NA 11/6/2007 <25.0 NA <25.0 <25.0 NA <25.0 908 <50.0 NA <25.0 NA NA <50.0 NA NA NA NA NA NA NA NA NA 5/6/2008 45 NA <1.0 <1.0 NA 12 580 3.6 NA 2.6 NA NA 9 NA NA NA NA NA NA NA NA NA 10/10/2008 <25.0 NA <25.0 <25.0 NA <25.0 962 <50.0 NA <25.0 NA NA <50.0 NA NA NA NA NA NA NA NA NA 4/6/2009 <2.5 NA <2.5 <2.5 <2.5 7.5 1,042 <10.0 <2.5 <2.5 <2.5 <2.5 <7.5 NA NA NA NA NA NA NA NA NA 10/2/2009 1.3 NA <0.50 <0.50 3.2 6.4 900 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/21/2010 113 NA <5.0 <5.0 <5.0 <5.0 762 <20.0 <5.0 6.6 <5.0 <5.0 5.2 NA NA NA NA NA NA NA NA NA 10/29/2010 <2.5 NA <2.5 <2.5 <2.5 <2.5 935 <10.0 <2.5 <2.5 <2.5 <2.5 <7.5 NA NA NA NA NA NA NA NA NA 4/27/2011 3.7 NA <2.5 <2.5 <2.5 <2.5 255 <10.0 <2.5 <2.5 4.4 <2.5 <7.5 NA NA NA NA NA NA NA NA NA 10/26/2011 10.9 NA <0.50 <0.50 2.0 1.5 285 5.4 <0.50 1.6 3.2 1.8 2.1 NA NA NA NA NA NA NA NA NA 4/30/2012 33.6 NA <5.0 <5.0 <5.0 8.9 1,610 <20.0 <5.0 <5.0 6.9 <5.0 <15.0 NA NA NA NA NA NA NA NA NA 10/31/2012 <5.0 NA <5.0 <5.0 <5.0 5.7 891 <20.0 <5.0 <5.0 7.8 <5.0 <15.0 NA NA NA NA NA NA NA NA NA 4/30/2013 <2.5 NA <2.5 <2.5 <2.5 5.4 822 <10.0 <2.5 <2.5 <10.0 <2.5 <7.5 NA NA NA NA NA NA NA NA NA 11/21/2013 <2.5 NA <2.5 <2.5 <2.5 6.4 831 <10.0 <2.5 <2.5 <10.0 <2.5 <7.5 NA NA NA NA NA NA NA NA NA 5/29/2014 490 NA <0.50 <0.50 13 8.7 1,300 28 <0.50 <0.50 5.3 1.8 23 NA NA NA NA NA NA NA NA NA 10/31/2014 <2.5 NA <2.5 <2.5 <2.5 4.4 791 <10.0 <2.5 <2.5 <2.5 <2.5 <7.5 NA NA NA NA NA NA NA NA NA 4/22/2015 <2.5 NA <2.5 <2.5 <2.5 4.5 672 <10.0 <2.5 <2.5 <2.5 <2.5 <7.5 NA NA NA NA NA NA NA NA NA 10/15/2015 5.2 NA <2.5 <2.5 <2.5 4.0 619 <10.0 <2.5 <2.5 <2.5 <2.5 <7.5 NA NA NA NA NA NA NA NA NA 4/27/2016 <2.5 NA <2.5 <2.5 <2.5 4.8 651 <10.0 <2.5 <2.5 <2.5 <2.5 <7.5 NA NA NA NA NA NA NA NA NA 10/28/2016 <2.5 NA <2.5 <2.5 <2.5 5.1 661 <10.0 <2.5 <2.5 <2.5 <2.5 <7.5 NA NA NA NA NA NA NA NA NA 4/28/2017 2.4 NA <1.0 <1.0 1.5 2.8 350 <4.0 <1.0 <1.0 1.2 <1.0 <3.0 NA NA NA NA NA NA NA NA NA 11/17/2017 4.6 NA <0.50 <0.50 <0.50 1.2 130 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 6/19/2018 9.5 NA <0.50 <0.50 2.3 4.9 568 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 12/20/2018 225 NA <2.5 <2.5 8.0 5.7 769 19.7 <2.5 <2.5 7.1 3.2 5.4 NA NA NA NA NA NA NA NA NA 6/21/2019 27.6 NA <25.0 <2.5 <2.5 3.4 539 <10.0 <2.5 <2.5 <2.5 <2.5 <7.5 NA NA NA NA NA NA NA NA NA 1/15/2020 125 NA <2.5 <2.5 3.5 6.0 800 <10.0 <2.5 <2.5 <2.5 <2.5 <7.5 NA NA NA NA NA NA NA NA NA 7/14/2020 3.4 NA <1.2 <1.2 <1.2 2.9 417 <5.0 <1.2 <1.2 <1.2 <1.2 <3.7 NA NA NA NA NA NA NA NA NA 1/18/2021 <2.0 NA <2.0 <2.0 <2.0 3.2 400 <8.0 <2.0 <2.0 <2.0 <2.0 <6.0 NA NA NA NA NA NA NA NA NA 7/30/2021 <1.2 NA <1.2 <1.2 <1.2 2.0 328 <5.0 <1.2 <1.2 <1.2 <1.2 <3.7 NA NA NA NA NA NA NA NA NA 1/27/2022 <0.50 NA <0.50 <0.50 <0.50 0.54 17.9 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 7/21/2022 <0.50 NA <0.50 <0.50 <0.50 <0.50 6.5 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 1/27/2023 <0.50 NA <0.50 <0.50 <0.50 <0.50 1.5 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 8/16/2023 <0.50 NA <0.50 <0.50 <0.50 <0.50 5.7 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 2/6/2024 <0.500 NA <0.500 <0.500 <0.500 <0.500 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500 NA NA NA NA NA NA NA NA NA 4/19/2002 <0.40 <0.40 <0.40 <0.40 <0.40 <2.00 <0.40 <1.00 <0.40 <0.40 <0.40 <0.40 <0.40 ND <100 <100 <100 <100 <100 <100 NA NA 8/13/2004 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 9.5 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA 1/21/2005 <1.0 NA <1.0 <1.0 <1.0 <1.0 <1.0 <2.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA NA NA NA NA NA NA NA NA 4/27/2005 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA 4/28/2006 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA 7/31/2006 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 NA NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA 7/31/2006 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 NA NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA 4/20/2007 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <3.0 NA NA NA NA NA NA NA NA NA 10/30/2007 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA 5/6/2008 <0.50 NA <1.0 <1.0 NA <5.0 <5.0 <1.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA 10/10/2008 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA 4/6/2009 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/2/2009 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/21/2010 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/29/2010 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/27/2011 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/26/2011 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/30/2012 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/31/2012 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/30/2013 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 11/21/2013 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 5/29/2014 <0.50 NA <0.50 <0.50 <0.50 <0.50 <1.0 <1.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/31/2014 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/22/2015 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/15/2015 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA MW-6D MW-5D(2,3) https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsxDeep T-24/5/2024 Table 3 (Page 3 of 4)Hart & Hickman, PC Table 3Monitoring Well Groundwater Analytical Detections General Store of DenverSherrills Ford, North CarolinaH&H Project GSD-050 Benzene Carbon Disulfide Chloroform Ethylbenzene Isopropyl-benzene Isopropyl-ether MTBE Naphthalene n-propyl-benzene Toluene 1,2,4- Trimethyl- benzene 1,3,5- Trimethyl- benzene Xylenes Semi- Volatiles (µg/l) VPH C5-C8 Aliphatics VPH C9-C12 Aliphatics VPH C9-C10 Aromatics C9-C18 Aliphatic Hydrocarbon C19-C36 Aliphatic Hydrocarbon C11-C22 Aromatic Hydrocarbon Lead (µg/l)Well ID Sample Date Phenol (µg/l) DENR MW-05D 4/19/2002 <0.40 <0.40 <0.40 <0.40 <0.40 <2.00 <0.40 <1.00 <0.40 <0.40 <0.40 <0.40 <0.40 ND <100 <100 <100 <100 <100 <100 NA NA 4/19/2002 <0.40 <0.40 <0.40 <0.40 <0.40 <2.00 <0.40 <1.00 <0.40 <0.40 <0.40 <0.40 <0.40 ND <100 <100 <100 <100 <100 <100 NA NA 1/21/2005 <1.0 NA <1.0 <1.0 <1.0 <1.0 <1.0 <2.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA NA NA NA NA NA NA NA NA 4/27/2005 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA 4/28/2006 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA 4/28/2006 <1.0 NA <1.0 <1.0 NA <1.0 <1.0 <2.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA 10/27/2006 <1.0 NA <1.0 <1.0 NA <1.0 1.6 <2.0 NA <1.0 NA NA <1.0 NA NA NA NA NA NA NA NA NA 4/20/2007 <1.0 NA <1.0 <1.0 NA <1.0 1.6 <2.0 NA <1.0 NA NA <3.0 NA NA NA NA NA NA NA NA NA 10/30/2007 <1.0 NA <1.0 <1.0 NA <1.0 1.5 <2.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA 5/6/2008 <0.50 NA <1.0 <1.0 NA <5.0 <5.0 <1.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA 10/10/2008 <1.0 NA <1.0 <1.0 NA <1.0 3.2 <2.0 NA <1.0 NA NA <2.0 NA NA NA NA NA NA NA NA NA 4/6/2009 <0.50 NA <0.50 <0.50 <0.50 <0.50 3.3 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/2/2009 <0.50 NA <0.50 <0.50 <0.50 <0.50 3.1 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/21/2010 <0.50 NA <0.50 <0.50 <0.50 <0.50 2.5 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/29/2010 <0.50 NA <0.50 <0.50 <0.50 <0.50 2.7 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/27/2011 <0.50 NA <0.50 <0.50 <0.50 <0.50 0.79 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/26/2011 <0.50 NA <0.50 <0.50 <0.50 <0.50 0.60 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/30/2012 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/31/2012 <0.50 NA 0.72 <0.50 <0.50 <0.50 1.20 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/30/2013 <0.50 NA 0.66 <0.50 <0.50 <0.50 1.0 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 11/21/2013 <0.50 NA 0.76 <0.50 <0.50 <0.50 0.75 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 5/29/2014 <0.50 NA 0.83 <0.50 <0.50 <0.50 1.1 <1.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/31/2014 <0.50 NA 0.99 <0.50 <0.50 <0.50 0.52 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/22/2015 <0.50 NA 0.98 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 10/15/2015 <0.50 NA 0.91 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA 4/27/2016 <0.50 NA 1.1 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <1.50 NA NA NA NA NA NA NA NA NA DENR No Name 4/19/2002 <0.40 <0.40 <0.40 <0.40 <0.40 <2.00 <0.40 <1.00 <0.40 <0.40 <0.40 <0.40 <0.40 ND <100 <100 <100 <100 <100 <100 NA NA 2L Groundwater Standard 1 700 70 600 70 70 20 6 70 600 400 400 500 NS 420 NS NS 4,200 42,000 210 30 15 Notes:Bold indicates concentration exceeds the Groundwater standard NS = No Standard, NA = Not Analyzed, ND = Not Detected; VPH = Volatile Petroleum Hydrocarbons; EPH = Extractable Petroleum Hydrocarbons DENR MW-06D https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsxDeep T-24/5/2024 Table 3 (Page 4 of 4)Hart & Hickman, PC Volatile Organics Benzene MTBE PCE 13.4 <2 <1 3.3 <2 <1 9.9 <2 <1 7/18/2003 1.4 15 <2 <1 10/16/2003 1.9 16 <2 <1 1/15/2004 1.8 20 <2 <1 4/30/2004 1.5 13 <2 <1 7/30/2004 1.3 9.1 <2 <1 10/27/2004 1.1 11 <2 <1 1/21/2005 1.1 9.6 <2 <1 4/27/2005 6/26/2002 1.4 49.2 <2 <1 10/10/2002 1.1 14.6 <2 <1 1/30/2003 4.4 35 <2 <1 4/22/2003 5.6 25 <2 <1 7/18/2003 <1 <1 <2 1.6 10/16/2003 <1 <1 <2 1.3 1/15/2004 <1 <1 <2 1.7 4/30/2004 <1 <1 <2 1.8 7/30/2004 <1 <1 <2 2.1 10/27/2004 <1 <1 <2 1.5 1/21/2005 <1 <1 <2 <1 4/27/2005 <1 <1 <2 1.2 7/29/2005 <1 <1 <2 1.2 10/28/2005 <1 <1 <2 1.1 1/30/2006 <1 <1 <2 <1 4/28/2006 <1 <1 <2 <1 7/31/2006 <1 <1 <2 <1 10/27/2006 <1 <1 <2 1.1 8/1/2002 <1 20.8 <2 <1 10/10/2002 6.1 65.8 <2 <1 1/30/2003 <1 20 <2 <1 4/22/2003 <1 24 <2 <1 7/18/2003 <1 30 3.5 <1 10/16/2003 10 75 <2.0 <1 1/15/2004 2.6 68 <2.0 <1 4/30/2004 9.2 85 5.3 <1 7/30/2004 10 110 <2 <1 10/27/2004 20 140 <2 <1 1/21/2005 17 140 <2 <1 4/27/2005 <5 110 <10 <5 7/29/2005 <5 160 <10 <5 10/28/2005 <5 81 <10 <5 16 <2 <1 4/28/2006 <1 44 <2 <1 7/31/2006 1.0 29 <2 <1 10/27/2006 <1.0 44 <2 <1 1/25/2007 <1.0 22 <2.0 <1.0 4/20/2007 <1.0 17 <2.0 <1.0 7/18/2007 <1.0 35 <2.0 <1.0 Community Well Property Ch r i s t e n b u r y W e l l 6375 NC Hwy 150 East 16 Fo r m e r D a y c a r e W e l l 6367 NC Hwy 150 East Table 4 Summary of Water Supply Well Sample Results The General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 Well Inactive 14 Well Map ID Well Name Well Address 1 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsx WSW Results T-34/5/2024 Table 4 (Page 1 of 4) Hart & Hickman, PC Volatile Organics Benzene MTBE PCE Table 4 Summary of Water Supply Well Sample Results The General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 Well Map ID Well Name Well Address 10/30/2007 <1.0 11.1 <2.0 <1.0 1/11/2008 <1.0 47.6 <2.0 <1.0 5/6/2008 <0.5 12 <1.0 <1.0 18.7 <2.0 <1.0 10/10/2008 <1.0 26.8 <2.0 <1.0 1/29/2009 <5.0 118 <10.0 <5.0 4/6/2009 <1.0 80.2 <2.0 <1.0 7/31/2009 <0.50 55.4 <2.0 <0.50 1.3 160 <1.0 <1.0 153 <1.0 <1.0 4/21/2010 <0.50 4.7 <2.0 <0.50 7/22/2010 <1.0 3.1 <2.0 <1.0 10/29/2010 <1.0 3.3 <2.0 <1.0 1/11/2011 <1.0 4.3 <2.0 <1.0 4/27/2011 <1.0 27.9 <2.0 <1.0 7/8/2011 <0.50 40.7 <2.0 <0.50 10/26/2011 <0.50 3.0 <2.0 <0.50 1/27/2012 <0.50 19.4 <2.0 <1.0 4/30/2012 <0.50 4.5 <2.0 <0.50 7/31/2012 <0.50 3.0 <2.0 <0.50 10/31/2012 <0.50 1.5 <2.0 <0.50 3/6/2013 <0.50 1.5 <2.0 <0.50 4/30/2013 <0.50 25.8 <2.0 <0.50 7/30/2013 <0.50 2.7 <2.0 <0.50 11/21/2013 <0.50 52.3 <2.0 <0.50 2/10/2014 <0.50 12.6 <2.0 <0.50 5/29/2014 <0.50 5.7 <2.0 <0.50 8/15/2014 <0.50 2.3 <2.0 <0.50 10/31/2014 <0.50 1.4 <2.0 <0.50 1/23/2015 <0.50 1.0 <2.0 <0.50 4/22/2015 1.9 234 <2.0 <0.50 8/21/2015 <0.50 1.2 <2.0 <0.50 10/15/2015 <0.50 1.8 <2.0 <0.50 199 <2.0 <0.50 4/27/2016 <0.50 0.86 <2.0 <0.50 8/18/2016 <0.50 0.92 <2.0 <0.50 10/28/2016 <0.50 0.90 <2.0 <0.50 2/9/2017 <0.50 0.60 <2.0 <0.50 4/28/2017 <0.50 0.50 <2.0 <0.50 8/15/2017 <0.50 <0.50 <2.0 <0.50 11/17/2017 <0.50 1.1 <2.0 <0.50 3/6/2018 <0.50 <0.50 <2.0 <0.50 6/15/2018 <0.50 0.59 <2.0 <0.50 9/26/2018 <0.50 0.69 <2.0 <0.50 12/20/2018 <0.50 37.4 <2.0 <0.50 3/22/2019 <0.50 <0.50 <2.0 <0.50 6/21/2019 <0.50 <0.50 <2.0 <0.50 9/13/2019 <0.50 0.55 <2.0 <0.50 1/15/2020 <0.50 <0.50 <2.0 <0.50 4/16/2020 <0.50 <0.50 <2.0 <0.50 7/14/2020 <0.50 <0.50 <2.0 <0.50 10/19/2020 <0.50 <0.50 <2.0 <0.50 1/21/2021 <0.50 <0.50 <2.0 <0.50 4/23/2021 <0.50 <0.50 <2.0 <0.50 11/19/2021 <0.50 1.1 <2.0 <0.50 1/27/2022 <0.50 <0.50 <2.0 <0.50 4/22/2022 <0.50 59.4 <2.0 <0.50 7/21/2022 <0.50 0.85 <2.0 <0.50 10/27/2022 <0.50 <0.50 <2.0 <0.50 1/27/2023 <0.50 0.70 <2.0 <0.50 5/25/2023 <0.50 <0.50 <2.0 <0.50 8/16/2023 <0.50 <0.50 <2.0 <0.50 11/20/2023 <0.50 <0.50 <2.0 <0.50 16 Fo r m e r D a y c a r e W e l l 6367 NC Hwy 150 East https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsx WSW Results T-34/5/2024 Table 4 (Page 2 of 4) Hart & Hickman, PC Volatile Organics Benzene MTBE PCE Table 4 Summary of Water Supply Well Sample Results The General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 Well Map ID Well Name Well Address 7/2/2002 <1 1.1 <2 <1 10/10/2002 <1 <1 <2 <1 1/30/2003 <1 2.1 <2 <1 4/22/2003 <1 2.2 <2 <1 7/18/2003 <1 <1 <2 <1 10/16/2003 <1 1.5 <2 <1 1/15/2004 <1 <1.0 <2 <1 4/30/2004 <1 3.0 <2 <1 7/30/2004 <1 <1 <2 <1 10/27/2004 <1 2.0 <2 <1 1/21/2005 <1 2.0 <2 <1 4/27/2005 <1 2.1 <2 <1 7/29/2005 <1 1.5 <2 <1 10/28/2005 <1 1.3 <2 <1 1/30/2006 <1 1.4 <2 <1 4/28/2006 <1 1.5 <2 <1 7/31/2006 <1 2.1 <2 <1 10/27/2006 <1 2.7 <2 <1 1/25/2007 <1.0 2.5 <2.0 <1.0 5/11/2007 <1.0 2.8 <2.0 <1.0 7/18/2007 <1 2.5 <2 <1 10/30/2007 <1.0 2.2 <2.0 <1.0 1/11/2008 <1.0 2.8 <2.0 <1.0 5/6/2008 <0.50 <5.0 <1.0 <1.0 7/31/2008 <1.0 2.2 <2.0 <1.0 10/10/2008 <1.0 3.0 <2.0 <1.0 1/29/2009 <1.0 1.7 <2.0 <1.0 7/31/2009 <0.50 2.1 <2.0 <0.50 4/21/2010 <0.50 1.5 <2.0 <0.50 7/22/2010 <1.0 2.1 <2.0 <1.0 10/29/2010 <1.0 2.1 <2.0 <1.0 1/11/2011 <1.0 2.4 <2.0 <1.0 4/27/2011 <1.0 1.8 <2.0 <1.0 7/8/2011 <0.50 1.8 <2.0 <0.50 10/26/2011 <0.50 1.7 <2.0 <0.50 1/27/2012 <1.0 1.7 <2.0 <1.0 4/30/2012 <0.50 1.6 <2.0 <0.50 7/31/2012 <0.50 1.6 <2.0 <0.50 10/31/2012 <0.50 1.3 <2.0 <0.50 3/6/2013 <0.50 1.3 <2.0 <0.50 4/30/2013 <0.50 1.2 <2.0 <0.50 7/30/2013 <0.50 0.53 <2.0 <0.50 2/10/2014 <0.50 <0.50 <2.0 <0.50 10/31/2014 <0.50 <0.50 <2.0 <0.50 Ke l l e r / R a w l i n g s N o . 1 4309 Mt. Pleasant Road37 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsx WSW Results T-34/5/2024 Table 4 (Page 3 of 4) Hart & Hickman, PC Volatile Organics Benzene MTBE PCE Table 4 Summary of Water Supply Well Sample Results The General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 Well Map ID Well Name Well Address 1/23/2015 <0.50 <0.50 <2.0 <0.50 4/22/2015 <0.50 <0.50 <2.0 <0.50 8/21/2015 <0.50 <0.50 <2.0 <0.50 10/15/2015 <0.50 <0.50 <2.0 <0.50 1/26/2016 <0.50 <0.50 <2.0 <0.50 4/27/2016 <0.50 <0.50 <2.0 <0.50 8/18/2016 <0.50 <0.50 <2.0 <0.50 10/28/2016 <0.50 <0.50 <2.0 <0.50 2/9/2017 <0.50 <0.50 <2.0 <0.50 4/28/2017 <0.50 <0.50 <2.0 <0.50 8/15/2017 <0.50 <0.50 <2.0 <0.50 11/27/2017 <0.50 <0.50 <2.0 <0.50 3/6/2018 <0.50 <0.50 <2.0 <0.50 1/15/2020 10/10/2002 <1 1.6 <2 <1 1/30/2003 <1 <1 <2 <1 4/22/2003 <1 <1 <2 <1 7/18/2003 <1 <1 <2 <1 10/16/2003 <1 <1 <2 <1 1/15/2004 <1 <1 <2 <1 4/30/2004 <1 <1 <2 <1 7/30/2004 <1 <1 <2 <1 10/27/2004 Well Inactive 1/15/2020 <0.50 <0.50 <2.0 <0.50 4/16/2020 <0.50 <0.50 <2.0 <0.50 7/14/2020 <0.50 <0.50 <2.0 <0.50 10/19/2020 <0.50 <0.50 <2.0 <0.50 1/21/2021 <0.50 <0.50 <2.0 <0.50 4/23/2021 <0.50 <0.50 <2.0 <0.50 7/30/2021 <0.50 <0.50 <2.0 <0.50 11/19/2021 <0.50 <0.50 <2.0 <0.50 1/27/2022 <0.50 <0.50 <2.0 <0.50 4/22/2022 <0.50 <0.50 <2.0 <0.50 7/21/2022 <0.50 <0.50 <2.0 <0.50 10/27/2022 <0.50 <0.50 <2.0 <0.50 1/27/2023 <0.50 <0.50 <2.0 <0.50 5/25/2023 <0.50 <0.50 <2.0 <0.50 8/16/2023 <0.50 <0.50 <2.0 <0.50 11/20/2023 <0.50 <0.50 <2.0 <0.50 2/6/2024 <0.500 <1.00 <2.00 <0.500 7/2/2002 6.3 46.2 <2 <1 10/10/2002 <1 9.1 <2 <1 1/30/2003 3.0 21 <2 <1 4/22/2003 4.1 25 <2 <1 7/18/2003 5.7 21 2.4 <1 10/16/2003 4.9 16 <2 <1 1/15/2004 3.1 11 <2 <1 4/30/2004 <1 3.3 <2 <1 7/30/2004 <1 <1 <2 <1 10/27/2004 <1 9.1 <2 <1 1/21/2005 6.0 25 <2 <1 4/27/2005 11 22 <2 <1 7/29/2005 8.0 44 <2 <1 10/28/2005 20 52 <2 <1 1/30/2006 4.0 17 <2 <1 4/28/2006 <1 <1 <2 <1 4/20/2007 Notes: All analytical results reported in units of micrograms per liter; Bold indicates compound detected. 1 - Sampled from spigot at General Store because owner refused access to wellhead. 2 - Chloromethane also detected at a concentration of 9.7 µg/l on 1/30/06. 3 - Naphthalene also detected at a concentration of 3.1 µg/l on 7/31/08 and 1.0 µg/l on 10/2/09. 4 - IPE also detected at a concentration of 1.0 µg/l on 1/7/10 and 1.2 µg/l on 1/26/16. 5 - Toluene also detected at a concentration of 3.0 µg/l on 8/15/14. 37 (cont.)4309 Mt. Pleasant Road Well Inactive MTBE = Methyl-tert-butyl ether; VPH = Volatile Petroleum Hydrocarbons, EPH = Extractable Petroleum Hydrocarbons; PCE = tetrachloroethylene; NA = Not Analyzed; NS = Not Sampled; BDL = All Compounds Below Laboratory Detection Limits. 37 Ke l l e r / R a w l i n g s N o . 2 4309 Mt. Pleasant Road 62 4330 Mt. Pleasant Road Well Inactive https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsx WSW Results T-34/5/2024 Table 4 (Page 4 of 4) Hart & Hickman, PC Table 5 Summary of Influent and Effluent Sample Results General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 Sample ID In042705 Eff042705 Inf073106 EFF073106 Inf102706 EFF102706 INF012507 EFF012507 INFLUENT042007 INFLUENT 071807 Daily Sample Location Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Discharge Date 4/27/2005 4/27/2005 7/31/2006 7/31/2006 10/27/2006 10/27/2006 1/25/2007 1/25/2007 4/20/2007 4/20/2007 7/18/2007 7/18/2007 Limit (µg/l) Laboratory Parameters Oil and Grease (1664) [mg/l]<5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NS Phenolics (420.1) [mg/l]<0.010 <0.010 0.098 <0.010 0.029 0.010 <0.010 <0.010 0.044 <0.010 0.019 0.011 300 Lead (200.7) [mg/l]<0.005 <0.005 <0.005 <0.005 NA NA <5.0 <5.0 <0.005 <5.0 <0.005 <5.0 25 TSS [mg/l]<3.3 <3.3 9.5 <1.7 4.8 <1.1 22 <1.1 9.0 1.5 56 <1.7 30,000 VOCs (6230D) Units = µg/l Benzene 13 <0.5 27 <0.5 100 <0.5 <5.0 <0.50 160 <0.50 6.6 <0.50 1.19 n-Butylbenzene <5 <0.5 <2.5 <0.5 <2.5 <0.5 <5.0 <0.50 <5.0 <0.50 <5.0 <0.50 NS sec-Butylbenzene <5 <0.5 <2.5 <0.5 <2.5 <0.5 <5.0 <0.50 <5.0 <0.50 <5.0 <0.50 NS Chloroform <5 <0.5 <2.5 <0.5 3.4 <0.5 <5.0 <0.50 <5.0 <0.50 <5.0 <0.50 NS Isopropylbenzene <5 <0.5 <2.5 <0.5 4.5 <0.5 <5.0 <0.50 <5.0 <0.50 <5.0 <0.50 NS Isopropyl ether (IPE)5.3 <0.5 4.3 <0.5 11 <0.5 5.4 <0.50 8.7 <0.50 5.7 <0.50 NS Methyl t-butyl Ether (MTBE)870 <0.5 800 <0.5 1,500 <0.5 1,300 <0.50 1,600 <0.50 1,200 <0.50 30 Naphthalene <5 <2 <2.5 <2 <2.5 <2 <20 <2.0 <20 <2.0 <20 <2.0 78 1,2,4-Trimethylbenzene <5 <0.5 <2.5 <0.5 9.7 <0.5 <5.0 <0.50 <5.0 <0.50 <5.0 <0.50 NS m,p-Xylenes <10 <0.5 <2.5 <0.5 <2.5 <0.5 <10 <1.0 <10 <1.0 <10 <1.0 NS o-xylene <5 <0.5 <2.5 <0.5 <2.5 <0.5 <5.0 <0.50 7.9 <0.50 <5.0 <0.50 NS Total Xylenes <0.5 <0.50 2.6 <0.50 12 <0.50 <15 <1.5 7.9 <1.5 <15 <1.5 780 Notes: EPA Method number follows parameter in parenthesis VOC = Volatile Organic Compound NS= Not Specified All BDL = Target analytes below detection limit Bold indicates exceeds standard J= estimated value between reporting limit and detection limit July 20071 6 April 2005 July 2006 October 2006 January 2007 April 2007 Hart & Hickman, PC Sample ID INFLUENT 110607 INFLUENT 020508 INFLUENT 050608 INFLUENT 073108 INFLUENT 101008 INFLUENT 012909 Daily Sample Location Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Discharge Date 11/6/2007 11/6/2007 2/5/2008 2/5/2008 5/6/2008 5/6/2008 7/31/2008 7/31/2008 10/10/2008 10/10/2008 1/29/2009 1/29/2009 Limit (µg/l) Laboratory Parameters Oil and Grease (1664) [mg/l]<5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 8.0 <5.0 <5.0 <5.0 <5.0 NS Phenolics (420.1) [mg/l]0.015 <0.010 <0.010 <0.010 <0.016 <0.010 0.029 <0.010 <0.010 <0.010 0.010 <0.010 300 Lead (200.7) [mg/l]<0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 25 TSS [mg/l]<3.3 <1.1 <1.7 <1.7 4.3 2.9 18 5.9 <1.4 <1.4 29.5 <1.1 30,000 VOCs (6230D) Units = µg/l Benzene 12.6 <0.50 <0.50 <0.5 <5.0 <0.5 <0.5 <0.5 <0.5 <0.5 93.8 <0.50 1.19 n-Butylbenzene <5.0 <0.50 <0.50 <0.5 <5.0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.50 <0.50 NS sec-Butylbenzene <5.0 <0.50 <0.50 <0.5 <5.0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.50 <0.50 NS Chloroform <5.0 <0.50 <0.50 <0.5 <5.0 <0.5 <1000 <1000 <0.5 <0.5 <0.50 <0.50 NS Isopropylbenzene <5.0 <0.50 <0.50 <0.5 <5.0 <0.5 <0.5 <0.5 <0.5 <0.5 1.1 <0.50 NS Isopropyl ether (IPE)8.8 <0.50 11.8 <0.5 6.9 <0.5 0.97 <0.5 11.4 <0.5 10.2 <0.50 NS Methyl t-butyl Ether (MTBE)1,910 <0.50 1,960 <0.5 1,390 <0.5 144 <0.5 1,870 <0.5 1,990 <0.50 30 Naphthalene <20.0 <2.0 <2.0 <2.0 <20.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 78 1,2,4-Trimethylbenzene <5.0 <0.50 <0.50 <0.5 <5.0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.50 <0.50 NS m,p-Xylenes <10.0 <1.0 <0.50 <0.5 <10.0 <0.5 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NS o-xylene <5.0 <0.50 <0.50 <0.5 <5.0 <0.5 <0.5 <0.5 <0.5 <0.5 0.55 <0.50 NS Total Xylenes <10.0 <1.0 <0.50 <0.5 <5.0 <0.5 <1.5 <1.5 <1.5 <1.5 0.55 <1.50 780 Notes: EPA Method number follows parameter in parenthesis VOC = Volatile Organic Compound NS= Not Specified All BDL = Target analytes below detection limit Bold indicates exceeds standard J= estimated value between reporting limit and detection limit January 2009 6 Table 5 Summary of Influent and Effluent Sample Results General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 November 20072 February 2008 May 2008 July 2008 October 2008 Hart & Hickman, PC Sample ID INFLUENT 042609 INFLUENT 073109 INFLUENT 100209 INFLUENT 010710 INFLUENT 042110 Daily Sample Location Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Discharge Date 4/6/2009 4/6/2009 7/31/2009 7/31/2009 10/2/2009 10/2/2009 1/7/2010 1/7/2010 4/21/2010 4/21/2010 Limit (µg/l) Laboratory Parameters Oil and Grease (1664) [mg/l]<5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NS Phenolics (420.1) [mg/l]<0.010 <0.010 <0.010 <0.010 <0.050 0.074 <0.010 <0.010 <0.010 <0.010 300 Lead (200.7) [mg/l]<0.005 <0.005 <0.005 <5.0 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 25 TSS [mg/l]<1.0 <1.0 <7.1 19.7 <5.0 <5.0 <8.3 <8.3 <5.6 <5.6 30,000 VOCs (6230D) Units = µg/l Benzene <5.0 <0.50 0.75 <0.50 17 <0.50 <0.50 <0.50 <2.5 <0.50 1.19 n-Butylbenzene <5.0 <0.50 <0.50 <1.0 <20 <1.0 <0.50 <0.50 <2.5 <0.50 NS sec-Butylbenzene <5.0 <0.50 <0.50 <0.50 <10 <0.50 <0.50 <0.50 <2.5 <0.50 NS Chloroform <5.0 <0.50 <0.50 <0.50 <10 <0.50 <0.50 <0.50 <2.5 <0.50 NS Isopropylbenzene <5.0 <0.50 <0.50 <0.50 <10 <0.50 1.1 <0.50 <2.5 <0.50 NS Isopropyl ether (IPE)7.8 <0.50 0.60 <0.50 <10 <0.50 11.3 <0.50 3.6 <0.50 NS Methyl t-butyl Ether (MTBE)1,590 <0.50 126 <0.50 1,100 <0.50 1,820 <0.50 750 <0.50 30 Naphthalene <20.0 <2.0 <2.0 <2.0 <40 <2.0 <2.0 <2.0 <2.5 <2.0 78 1,2,4-Trimethylbenzene <5.0 <0.50 <0.50 <0.50 <10 <0.50 <0.50 <0.50 <2.5 <0.50 NS m,p-Xylenes <10.0 <1.0 <1.0 <1.0 <10 <1.0 <1.0 <1.0 <5.0 <1.0 NS o-xylene <5.0 <0.50 <0.50 <0.50 <10 <0.50 <0.50 <0.50 <2.5 <0.50 NS Total Xylenes <10.0 <1.50 <1.50 <1.50 <30 <1.50 <1.50 <1.50 <7.5 <1.50 780 Notes: EPA Method number follows parameter in parenthesis VOC = Volatile Organic Compound NS= Not Specified All BDL = Target analytes below detection limit Bold indicates exceeds standard J= estimated value between reporting limit and detection limit 6 Table 5 Summary of Influent and Effluent Sample Results General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 April 2009 July 20093 October 2009 January 2010 April 2010 Hart & Hickman, PC November 2010 Sample ID INFLUENT 073109 INFLUENT 102910 INFLUENT 012411 INFLUENT 042711 INFLUENT 070811 Daily Sample Location Influent Effluent Influent Effluent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Discharge Date 7/29/2010 7/29/2010 10/29/2010 10/29/2010 11/19/2010 1/24/2011 1/24/2011 4/27/2011 4/27/2011 7/8/2011 7/8/2011 10/26/2011 10/26/2011 Limit (µg/l) Laboratory Parameters Oil and Grease (1664) [mg/l]<5.0 <5.0 <5.0 <5.0 NA <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NS Phenolics (420.1) [mg/l]0.035 <0.010 0.016 <0.010 NA <0.010 0.059 0.016 <0.010 <0.010 <0.010 0.023 <0.010 300 Lead (200.7) [mg/l]<0.005 <5.0 <0.005 <0.005 NA <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 0.0122 25 TSS [mg/l]50.7 11.2 26.7 <2.5 NA <5.6 <2.8 5.6 <2.5 <2.7 <2.5 20.3 <2.7 30,000 VOCs (6230D/6200B) Units = µg/l Benzene 8.5 <0.50 11.5 <0.50 <0.50 20.6 <0.50 <2.5 <0.50 <25.0 <0.50 20.2 <0.50 1.19 Bromodichloromethane <2.5 <0.50 <2.5 3.3 2.36 <5.0 <0.50 <2.5 <0.50 NA NA <0.50 <0.50 NS n-Butylbenzene <2.5 <0.50 <2.5 <1.0 <0.50 <5.0 <0.50 <2.5 <0.50 NA NA <0.50 <0.50 NS sec-Butylbenzene <2.5 <0.50 <2.5 <0.50 <0.50 <5.0 <0.50 <2.5 <0.50 NA NA <0.50 <0.50 NS Chlorodibromomethane <2.5 <0.50 <2.5 1.80 1.54 <5.0 <0.50 <2.5 <0.50 NA NA <0.50 <0.50 NS Chloroform <2.5 <0.50 <2.5 3.7 2.38 <5.0 <0.50 <2.5 <0.50 NA NA <0.50 <0.50 NS Isopropylbenzene <2.5 <0.50 <2.5 <0.50 <0.50 9.8 <0.50 <2.5 <0.50 NA NA <0.50 <0.50 NS Isopropyl ether (IPE)4.5 <0.50 9.1 <0.50 <0.50 12.9 <0.50 3.4 <0.50 NA NA 5.7 <0.50 NS Methyl t-butyl Ether (MTBE)945 <0.50 1,110 <0.50 <0.50 2,450 <0.50 753 <0.50 5,280 <0.50 1,220 <0.50 30 Naphthalene <10.0 <2.0 <10.0 <2.0 <5.0 <10.0 <2.0 <10.0 <2.0 <100 <2.0 <2.0 <2.0 78 1,2,4-Trimethylbenzene <2.5 <0.50 <2.5 <0.50 <0.50 <5.0 <0.50 <2.5 <0.50 NA NA <0.50 <0.50 NS m,p-Xylenes <5.0 <1.0 <5.0 <1.0 NA <5.0 <1.0 <5.0 <1.0 <50.0 <1.0 <1.0 <1.0 NS o-xylene <2.5 <0.50 <2.5 <0.50 NA <5.0 <0.50 <2.5 <0.50 <25.0 <0.50 <0.50 <0.50 NS Total Xylenes <7.5 <1.50 <7.5 <1.50 <1.0 14.40 <1.50 <7.5 <1.50 <75.0 <1.50 <1.50 <1.50 780 Notes: EPA Method number follows parameter in parenthesis VOC = Volatile Organic Compound NS = Not Specified; NA = Not Analyzed All BDL = Target analytes below detection limit Bold indicates exceeds standard J= estimated value between reporting limit and detection limit October 2011 6 Table 5 Summary of Influent and Effluent Sample Results General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 July 2010 October 2010 January 2011 April 2011 July 2011 Hart & Hickman, PC Sample ID INFLUENT 012712 INFLUENT 043012 INFLUENT 073112 INFLUENT 103112 INFLUENT 043013 INFLUENT 073013 Daily Sample Location Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Discharge Date 1/27/2012 1/27/2012 4/30/2012 4/30/2012 7/31/2012 7/31/2012 10/31/2012 10/31/2012 4/30/2013 4/30/2013 7/30/2013 7/30/2013 Limit (µg/l) Laboratory Parameters Oil and Grease (1664) [mg/l]<5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NS Phenolics (420.1) [mg/l]0.011 <0.010 0.036 <0.010 0.056 0.092 0.0093 0.006 0.037 0.020 0.0120 0.0080 300 Lead (200.7) [mg/l]<0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 0.011 0.0276 <0.0050 <0.005 0.0235 25 TSS [mg/l]7.2 <2.5 10.2 <5.0 <5.0 <5.0 8.2 <2.5 4.96 <2.6 47.0 <2.5 30,000 VOCs (6230D/6200B) Units = µg/l Benzene 5.0 <0.50 85.9 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 1.19 Bromodichloromethane <5.0 <0.50 <12.5 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 NS n-Butylbenzene <5.0 <0.50 <12.5 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 NS sec-Butylbenzene <5.0 <0.50 <12.5 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 NS Chlorodibromomethane <5.0 <0.50 <12.5 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 NS Chloroform <5.0 <0.50 <12.5 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 NS Isopropylbenzene <5.0 <0.50 <12.5 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 NS Isopropyl ether (IPE)<5.0 <0.50 13.1 <0.50 <10.0 <0.50 13.6 <0.50 10.20 <0.50 12.5 <0.50 NS Methyl t-butyl Ether (MTBE)916 <0.50 2,930 <0.50 2,500 <0.50 2,870 <0.50 2042.00 <0.50 2,160 <0.50 30 Naphthalene <20.0 <2.0 <50.0 <2.0 <40 <2.0 <40.0 <2.0 <40.0 <2.0 <40.0 <2.0 78 1,2,4-Trimethylbenzene <5.0 <0.50 <12.5 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 NS m,p-Xylenes <10.0 <1.0 <25.0 <1.0 <20.0 <1.0 <20.0 <1.0 <20.0 <1.0 <20.0 <1.0 NS o-xylene <5.0 <0.50 <12.5 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 <10.0 <0.50 NS Total Xylenes <15.0 <1.50 <37.5 <1.50 <30.0 <1.50 <30.0 <1.50 <30.0 <1.50 <30.0 <1.50 780 Notes: EPA Method number follows parameter in parenthesis VOC = Volatile Organic Compound NS = Not Specified; NA = Not Analyzed All BDL = Target analytes below detection limit Bold indicates exceeds standard J= estimated value between reporting limit and detection limit July 20135 6 Table 5 Summary of Influent and Effluent Sample Results General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 January 2012 April 2012 July 20124 Ocotber 2012 April 2013 Hart & Hickman, PC Sample ID INFLUENT 112113 INFLUENT 021014 INFLUENT 081514 INFLUENT 103114 INFLUENT 012315 INFLUENT 042215 Daily Sample Location Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Discharge Date 11/21/2013 11/21/2013 2/10/2014 2/10/2014 8/15/2014 8/15/2014 10/31/2014 10/31/2014 1/23/2015 1/23/2015 4/22/2015 4/22/2015 Limit (µg/l) Laboratory Parameters Oil and Grease (1664) [mg/l]<5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NS Phenolics (420.1) [mg/l]0.0160 0.0057 0.24 0.074 <0.010 0.014 0.014 0.010 0.012 <0.010 <0.010 <0.010 300 Lead (200.7) [mg/l]<0.005 <0.005 <0.005 <0.005 <0.005 0.0081 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 25 TSS [mg/l]6.0 <2.7 41.0 <2.6 9.1 <2.5 <2.5 <2.5 <2.5 <5.0 <2.5 <5.0 30,000 VOCs (6230D/6200B) Units = µg/l Benzene 18.4 <0.50 173 <0.50 8.5 <0.50 3.3 <0.50 <5.0 <0.50 <2.5 <0.50 1.19 Bromodichloromethane <10.0 <0.50 <5.0 <0.50 <2.5 <0.50 <2.5 <0.50 <5.0 <0.50 <2.5 <0.50 NS n-Butylbenzene <10.0 <0.50 <5.0 <0.50 <2.5 <0.50 <2.5 <0.50 <5.0 <0.50 <2.5 <0.50 NS sec-Butylbenzene <10.0 <0.50 <5.0 <0.50 <2.5 <0.50 <2.5 <0.50 <5.0 <0.50 <2.5 <0.50 NS Chlorodibromomethane <10.0 <0.50 <5.0 <0.50 <2.5 <0.50 <2.5 <0.50 <5.0 <0.50 <2.5 <0.50 NS Chloroform <10.0 <0.50 <5.0 <0.50 <2.5 <0.50 <2.5 <0.50 <5.0 <0.50 <2.5 <0.50 NS Isopropylbenzene <10.0 <0.50 7.0 <0.50 <2.5 <0.50 <2.5 <0.50 <5.0 <0.50 <2.5 <0.50 NS Isopropyl ether (IPE)13.5 <0.50 6.7 <0.50 3.2 <0.50 3.3 <0.50 <5.0 <0.50 2.5 <0.50 NS Methyl t-butyl Ether (MTBE)3,350 <0.50 1,066 <0.50 714 <0.50 1,042 0.55 674 <0.50 444 <0.50 30 Naphthalene <40.0 <2.0 <20.0 <2.0 <10.0 <2.0 <10.0 <2.0 <20.0 <2.0 <10.0 <2.0 78 1,2,4-Trimethylbenzene <10.0 <0.50 12.9 <0.50 <2.5 <0.50 <2.5 <0.50 <5.0 <0.50 <2.5 <0.50 NS m,p-Xylenes <20.0 <1.0 <10.0 <1.0 <5.0 <1.0 <5.0 <1.0 <10.0 <1.0 <5.0 <1.0 NS o-xylene <10.0 <0.50 11.9 <0.50 <2.5 <0.50 <2.5 <0.50 <5.0 <0.50 <2.5 <0.50 NS Total Xylenes <30.0 <1.50 11.9 <1.50 <7.5 <1.50 <7.5 <1.50 <15.0 <1.50 <7.5 <1.50 780 Notes: EPA Method number follows parameter in parenthesis VOC = Volatile Organic Compound NS = Not Specified; NA = Not Analyzed All BDL = Target analytes below detection limit Bold indicates exceeds standard J= estimated value between reporting limit and detection limit April 2015 6 Table 5 Summary of Influent and Effluent Sample Results General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 November 2013 February 20146 August 2014 October 2014 January 2015 Hart & Hickman, PC Sample ID INFLUENT 082115 INFLUENT 101515 INFLUENT 012616 INFLUENT 042716 INFLUENT 081816 INFLUENT 102816 Daily Sample Location Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Discharge Date 8/21/2015 8/21/2015 10/15/2015 10/15/2015 1/26/2016 1/26/2016 4/27/2016 4/27/2016 8/18/2016 8/18/2016 10/28/2016 10/28/2016 Limit (µg/l) Laboratory Parameters Oil and Grease (1664) [mg/l]<5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NS Phenolics (420.1) [mg/l]<0.010 <0.010 0.014 <0.010 0.013 0.013 0.012 0.011 0.014 0.012 <0.010 0.011 300 Lead (200.7) [mg/l]<0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 25 TSS [mg/l]<5.0 <5.0 7.1 <2.5 <2.5 <2.5 <2.5 <2.5 13.2 <2.5 <2.5 <2.5 30,000 VOCs (6230D/6200B) Units = µg/l Benzene <2.5 <0.50 3.1 <0.50 <1.0 <0.50 <5.0 <0.50 1.8 <0.50 <2.5 <0.50 1.19 Bromodichloromethane <2.5 <0.50 <2.5 <0.50 <1.0 <0.50 <5.0 <0.50 <1.0 <0.50 <2.5 <0.50 NS n-Butylbenzene <2.5 <0.50 <2.5 <0.50 <1.0 <0.50 <5.0 <0.50 <1.0 <0.50 <2.5 <0.50 NS sec-Butylbenzene <2.5 <0.50 <2.5 <0.50 <1.0 <0.50 <5.0 <0.50 <1.0 <0.50 <2.5 <0.50 NS Chlorodibromomethane <2.5 <0.50 <2.5 <0.50 <1.0 <0.50 <5.0 <0.50 <1.0 <0.50 <2.5 <0.50 NS Chloroform <2.5 <0.50 <2.5 <0.50 <1.0 <0.50 <5.0 <0.50 <1.0 <0.50 <2.5 <0.50 NS Isopropylbenzene <2.5 <0.50 <2.5 <0.50 <1.0 <0.50 <5.0 <0.50 1.1 <0.50 <2.5 <0.50 NS Isopropyl ether (IPE)3.3 <0.50 4.4 <0.50 2.2 <0.50 <5.0 <0.50 1.3 <0.50 4.9 <0.50 NS Methyl t-butyl Ether (MTBE)530 <0.50 1,130 <0.50 239 <0.50 509 <0.50 199 <0.50 591 <0.50 30 Naphthalene <10.0 <2.0 <10.0 <2.0 <4.0 <2.0 <20.0 <2.0 <4.0 <2.0 <10.0 <2.0 78 1,2,4-Trimethylbenzene <2.5 <0.50 <2.5 <0.50 <1.0 <0.50 <5.0 <0.50 2.3 <0.50 <2.5 <0.50 NS m,p-Xylenes <5.0 <1.0 <5.0 <1.0 <2.0 <1.0 <10.0 <1.0 <2.0 <1.0 <5.0 <1.0 NS o-xylene <2.5 <0.50 <2.5 <0.50 <1.0 <0.50 <5.0 <0.50 <1.0 <0.50 <2.5 <0.50 NS Total Xylenes <7.5 <1.50 <7.5 <1.50 <3.0 <1.50 <15.0 <1.50 <3.0 <1.50 <7.5 <1.50 780 Notes: EPA Method number follows parameter in parenthesis VOC = Volatile Organic Compound NS = Not Specified; NA = Not Analyzed All BDL = Target analytes below detection limit Bold indicates exceeds standard J= estimated value between reporting limit and detection limit October 2016 6 Table 5 Summary of Influent and Effluent Sample Results General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 August 2015 Ocotber 2015 January 2016 April 2016 August 2016 Hart & Hickman, PC Sample ID INFLUENT 020917 INFLUENT 042817 INFLUENT 070218 INFLUENT 090218 INFLUENT 120218 Daily Sample Location Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Discharge Date 2/9/2017 2/9/2017 4/28/2017 4/28/2017 7/2/2018 7/2/2018 9/26/2018 9/26/2018 12/20/2018 12/20/2018 Limit (µg/l) Laboratory Parameters Oil and Grease (1664) [mg/l]<5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 47.5 <5.0 <5.0 NS Phenolics (420.1) [mg/l]<0.010 <0.010 <0.010 <0.010 0.011 <0.010 0.018 <0.010 0.010 <0.010 300 Lead (200.7) [mg/l]<0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 25 TSS [mg/l]<2.5 <2.5 4.9 <2.5 <10.0 <2.5 3.2 <2.5 14.9 <2.5 30,000 VOCs (6230D/6200B) Units = µg/l Benzene <2.0 <0.50 <0.50 <0.50 8.6 <0.50 167 <0.50 253 <0.50 1.19 Bromodichloromethane <2.0 <0.50 <0.50 <0.50 <2.5 <0.50 <0.50 <0.50 <12.5 <0.50 NS n-Butylbenzene <2.0 <0.50 <0.50 <0.50 <2.5 <0.50 <0.50 <0.50 <12.5 <0.50 NS sec-Butylbenzene <2.0 <0.50 <0.50 <0.50 <2.5 <0.50 0.83 <0.50 <12.5 <0.50 NS Chlorodibromomethane <2.0 <0.50 <0.50 <0.50 <2.5 <0.50 <0.50 <0.50 <12.5 <0.50 NS Chloroform <2.0 <0.50 <0.50 <0.50 <2.5 <0.50 <0.50 <0.50 <12.5 <0.50 NS Isopropylbenzene <2.0 <0.50 <0.50 <0.50 <2.5 <0.50 4.1 <0.50 <12.5 <0.50 NS Isopropyl ether (IPE)3.9 <0.50 1.7 <0.50 5.2 <0.50 16.3 <0.50 <12.5 <0.50 NS Methyl t-butyl Ether (MTBE)507 <0.50 131 <0.50 976 <0.50 <0.50 0.79 1,890 <0.50 30 Naphthalene <8.0 <2.0 <2.0 <2.0 <10.0 <2.0 7.4 <2.0 <50.0 <2.0 78 1,2,4-Trimethylbenzene <2.0 <0.50 <0.50 <0.50 <2.5 <0.50 0.61 <0.50 <12.5 <0.50 NS m,p-Xylenes <4.0 <1.0 <1.0 <1.0 <5.0 <1.0 1.1 <1.0 <25.0 <1.0 NS o-xylene <2.0 <0.50 <0.50 <0.50 <2.5 <0.50 2.4 <0.50 <12.5 <0.50 NS Total Xylenes <6.0 <1.50 <1.50 <1.50 <7.5 <1.50 3.5 <1.50 <37.5 <1.50 780 Notes: EPA Method number follows parameter in parenthesis VOC = Volatile Organic Compound NS = Not Specified; NA = Not Analyzed All BDL = Target analytes below detection limit Bold indicates exceeds standard J= estimated value between reporting limit and detection limit 6 Table 5 Summary of Influent and Effluent Sample Results General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 February 2017 April 2017 July 2018 September 2018 December 2018 Hart & Hickman, PC Sample ID INFLUENT EFFLUENT INFLUENT EFFLUENT INFLUENT EFFLUENT INFLUENT EFFLUENT INFLUENT EFFLUENT Daily Sample Location Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Discharge Date 3/22/2019 3/22/2019 6/21/2019 6/21/19 / 8/1/2019 9/13/2019 9/13/2019 1/15/2020 1/15/2020 4/16/2020 4/16/2020 Limit (µg/l) Laboratory Parameters Oil and Grease (1664) [mg/l]<5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <4.8 <5.0 <5.0 NS Phenolics (420.1) [mg/l]<0.020 <0.020 <0.020 <0.20 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 300 Lead (200.7) [mg/l]<0.005 <0.005 0.0919 <0.005 0.007 <0.005 <0.005 <0.005 <0.005 <0.005 25 TSS [mg/l]<5.0 <2.5 <2.5 102/<2.5 25.2 <2.5 <10.0 <2.5 11.8 <2.5 30,000 VOCs (6230D/6200B) Units = µg/l Benzene 489 <0.50 93.5 <0.50 47.1 <0.50 123 <0.50 38.9 <0.50 1.19 Bromodichloromethane <12.5 <0.50 <12.5 <0.50 <2.5 <0.50 <2.5 <0.50 <6.2 <0.50 NS n-Butylbenzene <12.5 <0.50 <12.5 <0.50 <2.5 <0.50 <2.5 <0.50 <6.2 <0.50 NS sec-Butylbenzene <12.5 <0.50 <12.5 <0.50 <2.5 <0.50 <2.5 <0.50 <6.2 <0.50 NS Chlorodibromomethane <12.5 <0.50 <12.5 <0.50 <2.5 <0.50 <2.5 <0.50 <6.2 <0.50 NS Chloroform <12.5 <0.50 <12.5 <0.50 <25.0 <5.0 <2.5 <0.50 <6.2 <0.50 NS Isopropylbenzene <12.5 <0.50 <12.5 <0.50 <2.5 <0.50 2.7 <0.50 <6.2 <0.50 NS Isopropyl ether (IPE)17.7 <0.50 <12.5 <0.50 4.9 <0.50 17.7 <0.50 14.5 <0.50 NS Methyl t-butyl Ether (MTBE)2,840 <0.50 1,450 <0.50 817 <0.50 2,480 <0.50 2,160 <0.50 30 Naphthalene <50.0 <2.0 <25.0 <2.0 <10.0 <2.0 <10.0 <2.0 <25.0 <2.0 78 1,2,4-Trimethylbenzene <12.5 <0.50 <6.2 <0.50 <2.5 <0.50 <2.5 <0.50 <6.2 <0.50 NS m,p-Xylenes <25.0 <1.0 <12.5 <1.0 <5.0 <1.0 <5.0 <1.0 <12.5 <1.0 NS o-xylene <12.5 <0.50 <6.2 <0.50 <2.5 <0.50 <2.5 <0.50 <6.2 <0.50 NS Total Xylenes <37.5 <1.50 <18.7 <1.50 <7.5 <1.50 <7.5 <1.50 <18.7 <1.50 780 Notes: EPA Method number follows parameter in parenthesis VOC = Volatile Organic Compound NS = Not Specified; NA = Not Analyzed All BDL = Target analytes below detection limit Bold indicates exceeds standard J= estimated value between reporting limit and detection limit Table 5 Summary of Influent and Effluent Sample Results General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 March 2019 June 2019/August 20197 September 2019 January 2020 April 2020 Hart & Hickman, PC Sample ID INFLUENT EFFLUENT INFLUENT EFFLUENT INFLUENT EFFLUENT INFLUENT EFFLUENT INFLUENT EFFLUENT Sample Location Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Date 7/14/2020 7/14/2020 10/19/2020 10/19/2020 1/19/2021 1/19/2021 4/23/2021 4/23/2021 7/30/2021 7/30/2021 Laboratory Parameters Oil and Grease (1664) [mg/l]<5.0 <5.0 <4.8 <4.9 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Phenolics (420.1) [mg/l]<0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 Lead (200.7) [mg/l]<0.005 <0.005 <0.005 <0.005 8.1 <0.005 <0.005 <0.005 <0.005 <0.005 TSS [mg/l]<5.0 <2.5 5.1 <2.5 <5.0 <2.5 44.6 <2.5 7.4 <2.5 VOCs (6230D/6200B) Units = µg/l Benzene 239 <0.50 160 <0.50 171 <0.50 14.5 <0.50 95 <0.50 Bromodichloromethane <5.0 <0.50 <5.0 <0.50 <5.0 <0.50 <6.2 <0.50 <6.2 <0.50 n-Butylbenzene <5.0 <0.50 <5.0 <0.50 <5.0 <0.50 <6.2 <0.50 <6.2 <0.50 sec-Butylbenzene <5.0 <0.50 <5.0 <0.50 <5.0 <0.50 <6.2 <0.50 <6.2 <0.50 Chlorodibromomethane <5.0 <0.50 <5.0 <0.50 <5.0 <0.50 <6.2 <0.50 <6.2 <0.50 Chloroform <5.0 <0.50 <5.0 <0.50 <5.0 <0.50 <6.2 <0.50 <6.2 <0.50 Isopropylbenzene <5.0 <0.50 <5.0 <0.50 <5.0 <0.50 <6.2 <0.50 <6.2 <0.50 Isopropyl ether (IPE)10.2 <0.50 10.6 <0.50 10.0 <0.50 11.0 <0.50 8.3 <0.50 Methyl t-butyl Ether (MTBE)1,620 <0.50 1,480 <0.50 1,390 <0.50 1,710 <0.50 1,220 <0.50 Naphthalene <20.0 <2.0 43.5 <2.0 <20.0 <2.0 <25.0 <2.0 <25.0 <2.0 1,2,4-Trimethylbenzene <5.0 <0.50 43.4 <0.50 <5.0 <0.50 <6.2 <0.50 <6.2 <0.50 m,p-Xylenes 10.4 <1.0 35.7 <1.0 <10.0 <1.0 <12.5 <1.0 <12.5 <1.0 o-xylene 6.0 <0.50 24.7 <0.50 <5.0 <0.50 <6.2 <0.50 <6.2 <0.50 Total Xylenes 16.4 <1.50 60.4 <1.50 <10.5 <1.50 <18.7 <1.50 <18.7 <1.50 Notes: EPA Method number follows parameter in parenthesis VOC = Volatile Organic Compound NS = Not Specified; NA = Not Analyzed All BDL = Target analytes below detection limit Bold indicates exceeds standard J= estimated value between reporting limit and detection limit July 2020 Summary of Influent and Effluent Sample Results Table 5 General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 October 2020 January 2021 April 2021 July 2021 Hart & Hickman, PC Sample ID INFLUENT EFFLUENT INFLUENT EFFLUENT INFLUENT EFFLUENT INFLUENT EFFLUENT INFLUENT EFFLUENT Daily Sample Location Influent Effluent Influent Effluent Influent Effluent Influent Effluent Influent Effluent Discharge Date 11/19/2021 11/19/2021 1/27/2022 1/27/2022 4/22/2022 4/22/2022 7/21/2022 7/21/2022 10/27/2022 10/27/2022 Limit (µg/l) Laboratory Parameters Oil and Grease (1664) [mg/l]<4.9 <4.8 <4.8 <4.9 <4.8 <4.9 <4.9 <4.8 <4.9 <4.8 NS Phenolics (420.1) [mg/l]<0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 300 Lead (200.7) [mg/l]0.0382 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 25 TSS [mg/l]16.0 <2.5 5.2 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 30,000 VOCs (6230D/6200B) Units = µg/l Benzene 43.6 <0.50 96.9 <0.50 <2.5 <0.50 <2.5 <0.50 94.2 <0.50 1.19 Bromodichloromethane <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS n-Butylbenzene <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS sec-Butylbenzene <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS Chlorodibromomethane <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS Chloroform <2.5 <0.50 <2.5 <0.50 6.0 <0.50 <2.5 <0.50 <2.5 <0.50 NS Isopropylbenzene <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS Isopropyl ether (IPE)7.4 <0.50 6.1 <0.50 7.1 <0.50 4.8 <0.50 7.5 <0.50 NS Methyl t-butyl Ether (MTBE)938 <0.50 798 <0.50 859 <0.50 653 <0.50 962 <0.50 30 Naphthalene <10.0 <2.0 <10.0 <2.0 <10.0 <2.0 <10.0 <2.0 <10.0 <2.0 78 1,2,4-Trimethylbenzene <2.5 <0.50 6.7 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS m,p-Xylenes <5.0 <1.0 <5.0 <1.0 <5.0 <1.0 <5.0 <1.0 <5.0 <1.0 NS o-xylene <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS Total Xylenes <7.5 <1.50 <7.5 <1.50 <17.5 <1.50 <7.5 <1.50 <7.5 <1.50 780 Notes: EPA Method number follows parameter in parenthesis VOC = Volatile Organic Compound NS = Not Specified; NA = Not Analyzed All BDL = Target analytes below detection limit Bold indicates exceeds standard J= estimated value between reporting limit and detection limit April 2022January 2022November 2021 Table 5 Summary of Influent and Effluent Sample Results General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 July 2022 October 2022 Hart & Hickman, PC Sample ID INFLUENT EFFLUENT INFLUENT EFFLUENT INFLUENT EFFLUENT INFLUENT EFFLUENT Daily Sample Location Influent Effluent Influent Effluent Influent Effluent Influent Effluent Discharge Date 1/27/2023 1/27/2023 5/25/2023 5/25/2023 8/16/2023 8/16/2023 11/20/2023 11/20/2023 Limit (µg/l) Laboratory Parameters Oil and Grease (1664) [mg/l]<4.9 <4.8 <4.9 <4.9 <4.8 <4.8 <4.8 <4.9 NS Phenolics (420.1) [mg/l]<0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 300 Lead (200.7) [mg/l]<0.005 <0.005 <0.025 <0.025 <0.025 <0.025 <5.0 <5.0 25 TSS [mg/l]<2.5 <2.5 7.1 <2.5 12.0 <2.5 6.5 <2.5 30,000 VOCs (6230D/6200B) Units = µg/l Benzene <2.5 <0.50 76.0 <0.50 <2.5 <0.50 <2.5 <0.50 1.19 Bromodichloromethane <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS n-Butylbenzene <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS sec-Butylbenzene <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS Chlorodibromomethane <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS Chloroform <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS Isopropylbenzene <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS Isopropyl ether (IPE)5.9 <0.50 6.7 <0.50 6.8 <0.50 4.8 <0.50 NS Methyl t-butyl Ether (MTBE)864 <0.50 922 <0.50 860 <0.50 621 <0.50 30 Naphthalene <10.0 <2.0 <10.0 <2.0 <10.0 <2.0 <10.0 <2.0 78 1,2,4-Trimethylbenzene <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 4.3 <0.50 NS m,p-Xylenes <5.0 <1.0 <5.0 <1.0 <5.0 <1.0 <5.0 <1.0 NS o-xylene <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 <2.5 <0.50 NS Total Xylenes <7.5 <1.50 <7.5 <1.50 <7.5 <1.50 <7.5 <1.50 780 Notes: EPA Method number follows parameter in parenthesis VOC = Volatile Organic Compound NS = Not Specified; NA = Not Analyzed All BDL = Target analytes below detection limit Bold indicates exceeds standard J= estimated value between reporting limit and detection limit January 2023/February 2023 May 2023 Table 5 Summary of Influent and Effluent Sample Results General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 August 2023 November 2023 Hart & Hickman, PC Summary of Mass Removal - Groundwater Remediation System General Store of Denver Sherrills Ford, North Carolina Benzene MTBE Benzene MTBE Benzene MTBE Benzene MTBE 8/13/2004 0 0 0 NA NA NA NA NA NA NA NA 10/15/2004 13,029.5 13,030 207 180 880 <1.0 <1.0 0.020 0.096 0.00031 0.0015 1/17/2005 32,960.0 19,931 212 20 1,400 <1.0 <1.0 0.0033 0.23 0.000035 0.0025 4/27/2005 73,990.5 41,031 410 13 870 <1.0 <1.0 0.0045 0.30 0.000045 0.0030 7/29/2005 101,581.0 27,591 297 NA NA NA NA 0.0030 0.20 0.000032 0.0022 Assumes same concentration as in April. Sampling not conducted as system was deactivated. 5/19/2006 0.0 0 0 NA NA <1.0 <1.0 NA NA NA NA System restarted and meter reset 7/31/2006 24,858.4 24,858 341 27 800 <1.0 <1.0 0.0056 0.17 0.000077 0.0023 10/27/2006 46,640.0 21,782 248 100 1,500 <1.0 <1.0 0.018 0.27 0.00021 0.0031 1/25/2007 78,791.4 32,151 357 <5.0 1,300 <0.50 <0.50 NA 0.35 NA 0.0039 4/20/2007 104,435.0 25,644 302 160 1,600 <0.50 <0.50 0.034 0.34 0.00040 0.0040 7/18/2007 129,696.0 25,261 284 6.6 1,200 <0.50 <0.50 0.0014 0.25 0.00002 0.0028 11/6/2007 147,570.0 17,874 161 12.6 1,910 <0.50 <0.50 0.0019 0.29 0.000017 0.0026 2/5/2008 0.0 22,750 250 <0.5 1,960 <0.5 <0.5 0.00 0.37 0.00 0.0041 meter reset to zero. Previous flow 5/6/2008 27,005.0 27,005 297 <5.0 1,390 <0.5 <0.5 0.00 0.31 0.00 0.0035 7/31/2008 43,514.8 16,510 192 <0.5 144 <0.5 <0.5 0.00 0.020 0.00 0.00023 power outage. System restarted. 10/10/2008 64,765.3 21,251 299 <0.5 1,870 <0.5 <0.5 0.00 0.33 0.00 0.0047 Comment Surge tank transfer pump malfunctioning during September O&M visit - system down from approximately 09/26/07 through 11/02/07. Transfer pump motor - system restarted that same day. Table 6 H&H Job No. GSD-050 Date Reading (gal) Flow Since Previous Date (gal) Discharge Rate (gpd) Influent (µg/l)Effluent (µg/l)Pounds Removed Since Previous Sample Daily Removal Rate (pounds) https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsxTable 64/5/2024 Table 6 (Page 1 of 6) Hart & Hickman, PC Summary of Mass Removal - Groundwater Remediation System General Store of Denver Sherrills Ford, North Carolina Benzene MTBE Benzene MTBE Benzene MTBE Benzene MTBE Comment Table 6 H&H Job No. GSD-050 Date Reading (gal) Flow Since Previous Date (gal) Discharge Rate (gpd) Influent (µg/l)Effluent (µg/l)Pounds Removed Since Previous Sample Daily Removal Rate (pounds) 1/29/2009 92,510.0 27,745 250 93.8 1,990 <0.5 <0.5 0.022 0.46 0.00020 0.0042 4/6/2009 103,640.0 11,130 166 <5.0 1,590 <0.5 <0.5 0.00 0.15 0.00 0.0022 7/31/2009 129,243.0 25,603 221 0.75 126 <0.5 <0.5 0.00016 0.027 0.0000014 0.00023 10/2/2009 152,601.0 23,358 244 17 1,100 <0.5 <0.5 0.0033 0.21 0.000053 0.0034 power outage. System restarted. 1/7/2010 2,869.6 22,000 220 <0.5 1,820 <0.5 <0.5 0.00 0.34 0.00 0.0035 December 2009, meter reset to zero. Previous flow estimated to be 220 gpd. 4/21/2010 26,567.0 23,697 228 <0.5 750 <0.5 <0.5 0.00 0.15 0.00 0.0014 7/22/2010 39,921.1 13,354 145 8.5 945 <0.5 <0.5 0.00095 0.11 0.000010 0.0011 likely due to a power outage; system restarted that same day. System restarted on August 8, 2010. 10/29/2010 48,582.0 8,661 87 17.0 1,100 <0.5 <0.5 0.0012 0.080 0.000012 0.00081 influent analytical results indicating new 1/11/2011 55,450.9 6,869 93 20.6 2,450 <0.5 <0.5 0.0012 0.14 0.000016 0.0019 4/29/2011 61,227.8 5,777 53 <2.5 753 <0.5 <0.5 0.00 0.036 0.00 0.00034 replaced in March 2011. 7/8/2011 68,814.5 7,587 108 <25.0 5,280 <0.50 <0.50 0.00 0.34 0.00 0.0048 meter reset to zero on 9/16/11 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsxTable 64/5/2024 Table 6 (Page 2 of 6) Hart & Hickman, PC Summary of Mass Removal - Groundwater Remediation System General Store of Denver Sherrills Ford, North Carolina Benzene MTBE Benzene MTBE Benzene MTBE Benzene MTBE Comment Table 6 H&H Job No. GSD-050 Date Reading (gal) Flow Since Previous Date (gal) Discharge Rate (gpd) Influent (µg/l)Effluent (µg/l)Pounds Removed Since Previous Sample Daily Removal Rate (pounds) 10/28/2011 202.4 8,886 89 20.2 1,220 <0.50 <0.50 0.0015 0.091 0.000013 0.00081 power outage - reset and restarted. Flow 1/27/2012 6,547.0 6,345 70 <5.0 916 <0.50 <0.50 0.00 0.049 0.000 0.00053 power outage - reset and restarted. 4/27/2012 15,364.3 8,817 85.9 2,930 <0.50 <0.50 0.0063 0.22 0.000070 0.0024 7/31/2012 39,056.4 23,692 249 <10.0 2,500 <0.50 <0.50 0.00 0.50 0.00 0.0052 10/31/2012 54,981.9 15,926 173 <10.0 2,870 <0.50 <0.50 0.00 0.38 0.00 0.0042 4/30/2013 79,565.2 24,583 136 <10.0 2,042 <0.50 <0.50 0.00 0.42 0.00 0.0023 to a power outage - reset and restarted. System shutdown on February 21, 2013 due to leaking carbon drums. Drums 2013. 7/30/2013 88,979.8 9,415 103 <10.0 2,160 <0.50 <0.50 0.00 0.17 0.00 0.0019 troubleshooted and restarted. 11/21/2013 9,705.2 18,500 162 18.4 3,350 <0.50 <0.50 0.0028 0.52 0.000025 0.0045 August 2013, meter reset to zero. Previous flow estimated to be 164 gpd. System off on arrival in November 2013 due to tripped breaker - breaker reset and 3/26/2014 33,272.0 23,567 189 18.4 3,350 <0.50 <0.50 0.0036 0.66 0.000029 0.0053 to leaking carbon drum. November 2013 effluent data utilized for removal rates. 8/15/2014 41,070.4 7,798 55 8.5 714 <0.50 <0.50 0.00055 0.047 0.0000039 0.00033 30, 2014. System restarted at that time. 10/31/2014 58,687.7 17,617 229 3.3 1,042 <0.50 <0.50 0.00049 0.15 0.0000063 0.0020 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsxTable 64/5/2024 Table 6 (Page 3 of 6) Hart & Hickman, PC Summary of Mass Removal - Groundwater Remediation System General Store of Denver Sherrills Ford, North Carolina Benzene MTBE Benzene MTBE Benzene MTBE Benzene MTBE Comment Table 6 H&H Job No. GSD-050 Date Reading (gal) Flow Since Previous Date (gal) Discharge Rate (gpd) Influent (µg/l)Effluent (µg/l)Pounds Removed Since Previous Sample Daily Removal Rate (pounds) 1/23/2015 68,443.6 9,756 116 <5.0 674 <0.50 <0.50 0.00 0.055 0.00 0.00065 4/22/2015 78,407.3 9,964 112 <2.5 444 <0.50 <0.50 0.00 0.037 0.00 0.00021 8/21/2015 0.0 7,516 62 <2.5 530 <0.50 <0.50 0.00 0.033 0.00 0.00028 July 2015, meter reset to zero. Previous flow estimated to be 55 gpd. System off in 06/15, 07/15, & 8/15 likely due to a power outage - reset and restarted. 10/12/2015 5,728.3 5,728 110 3.1 1,130 <0.50 <0.50 0.00015 0.054 0.0000029 0.0010 belt tightened and system restarted. 1/23/2016 17,269.0 11,541 112 <5.0 674 0.0 <0.50 0.00 0.065 0.00 0.00063 power outage - reset and restarted. System off on arrival (2/8/16) due to a dislodged fernco coupler on the air stripper - fernco coupler replaced and 4/14/2016 28,251.2 10,982 134 <5.0 509 <0.50 <0.50 0.00 0.047 0.00 0.00057 8/18/2016 40,163.9 11,913 95 1.8 199 <0.50 <0.50 0.00018 0.020 0.00000086 0.00016 and restarted. 10/28/2016 43,956.5 3,793 53 <2.5 591 <0.50 <0.50 0.00 0.019 0.00 0.00026 2/9/2017 47,335.0 3,379 32 <2.0 507 <0.50 <0.50 0.00 0.014 0.00 0.00014 likely due to a power outage System restarted. 4/28/2017 54,297.3 6,962 89 <0.50 131 <0.50 <0.50 0.00 0.0076 0.00 0.00010 8/15/2017 66,737.0 12,440 114 <0.50 131 <0.50 <0.50 0.00 0.014 0.00 0.00013 leaking drums. DEQ requested in September 2017 to shutdown system pending further review. System winterized and carbon replaced on 11/17/17. https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsxTable 64/5/2024 Table 6 (Page 4 of 6) Hart & Hickman, PC Summary of Mass Removal - Groundwater Remediation System General Store of Denver Sherrills Ford, North Carolina Benzene MTBE Benzene MTBE Benzene MTBE Benzene MTBE Comment Table 6 H&H Job No. GSD-050 Date Reading (gal) Flow Since Previous Date (gal) Discharge Rate (gpd) Influent (µg/l)Effluent (µg/l)Pounds Removed Since Previous Sample Daily Removal Rate (pounds) 7/2/2018 435.0 435 1.4 8.6 976 <0.50 <0.50 0.000031 0.0036 0.000000051 0.000011 electrician installed new surge tank floats for malfunctioning floats on 6/12/18. Replaced malfunctioning flow meter on 7/2/18. Due to malfunctioning pumps, new extraction pumps installed 7/2/18. 9/26/2018 12,118.2 11,683 136 167 <0.50 <0.50 0.79 0.016 0.00 0.00019 0.00 12/20/2018 24,975.0 12,857 151 253 1,890 <0.50 <0.50 0.027 0.20 0.00032 0.0024 level alarm (1/25/19). System restarted 12/18. Faulty contactor replaced and system restarted 2/15/19. 3/22/2019 36,410.5 11,436 124 489 2,840 <0.50 <0.50 0.047 0.27 0.00051 0.0030 6/21/2019 49,331.2 12,921 142 93.5 1,450 <0.50 <0.50 0.010 0.16 0.00011 0.0017 & 8/27/19) likely due to a power outage. 9/13/2019 55,444.4 6,113 73 47.1 817 <0.50 <0.50 0.0024 0.042 0.000029 0.00050 disruption. Duke power called and meter 1/15/2020 69,649.9 14,206 115 123 2,480 <0.50 <0.50 0.015 0.29 0.00012 0.0024 2/13/20) likely due to a power outage. System restarted each time. Electrician contacted to troubleshoot for potential electrical component malfunctions. 4/15/2020 71,859.5 2,210 24 38.9 2,160 <0.50 <0.50 0.00072 0.040 0.0000079 0.00044 7/14/2020 78,202.0 6,343 70 239 1,620 <0.50 <0.50 0.013 0.086 0.00014 0.0010 8/15/20) likely due to a power outage. System restarted. Electrician troubleshooted system for potential electrical component malfunctions. No malfunctions noted. Uninteruptable power supply recommended by https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsxTable 64/5/2024 Table 6 (Page 5 of 6) Hart & Hickman, PC Summary of Mass Removal - Groundwater Remediation System General Store of Denver Sherrills Ford, North Carolina Benzene MTBE Benzene MTBE Benzene MTBE Benzene MTBE Comment Table 6 H&H Job No. GSD-050 Date Reading (gal) Flow Since Previous Date (gal) Discharge Rate (gpd) Influent (µg/l)Effluent (µg/l)Pounds Removed Since Previous Sample Daily Removal Rate (pounds) 10/19/2020 83,490.1 5,288 55 160 1,480 <0.50 <0.50 0.0071 0.065 0.000073 0.00068 10/19/20) likely due to a power outage. System restarted. Uninteruptable power supply installed on system by electrician. 1/19/2021 100,544.0 17,054 185 171 1,390 <0.50 <0.50 0.024 0.20 0.00027 0.0022 4/23/2021 115,280.0 14,736 157 14.5 1,710 <0.50 <0.50 0.0018 0.21 0.000019 0.0022 7/30/2021 125,241.0 9,961 102 95 1,220 <0.50 <0.50 0.0079 0.10 0.000081 0.0010 blown fuse in the control panel. Fuse 11/19/2021 138,691.0 13,450 120 43.6 938 <0.50 <0.50 0.0049 0.11 0.000044 0.00094 1/27/2022 145,422.0 6,731 98 96.9 798 <0.50 <0.50 0.0055 0.045 0.000079 0.00065 4/22/2022 153,101.0 7,679 90 0.0 859 <0.50 <0.50 0.00 0.055 0.00 0.00065 7/21/2022 160,652.0 7,551 84 0.0 653 <0.50 <0.50 0.00 0.041 0.00 0.00046 10/27/2022 167,352.0 6,700 68 94.2 962 <0.50 <0.50 0.0053 0.054 0.000054 0.00055 1/27/2023 172,430.0 5,078 55 0.0 864 <0.50 <0.50 0.00 0.037 0.00 0.00040 5/25/2023 179,934.0 7,504 64 76.0 922 <0.50 <0.50 0.0048 0.058 0.000040 0.00049 8/16/2023 185,488.0 5,554 67 0.0 860 <0.50 <0.50 0.00 0.040 0.00 0.00048 11/20/2023 191,932.0 6,444 67 0.0 621 <0.50 <0.50 0.00 0.033 0.00 0.00035 System shutdown on 12/29/23 to begin MNA closure sampling period.Total ----963,498 NA NA NA NA 0.33 11.29 NA NA Notes: https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Tables.xlsxTable 64/5/2024 Table 6 (Page 6 of 6) Hart & Hickman, PC Active Y5 Active Y10 Active Y11 Active Y12 Active Y13 Active Y13.5 Active Y14 Active Y14.5 Active Y15 Active Y15.5 Active Y16 Active Y16.5 Active Y17 Active Y17.5 Active Y18 Active Y18.5 Active Y19 Inactive Y19.5 Inactive Y20 Inactive Y20.5 Inactive Y21 Inactive Y21.5 Inactive Y22 Inactive Y22.5 Inactive Y23 Inactive Y23.5 Inactive Y24 Inactive Y24.5 Inactive Y25 Projected Mass Reduction (%):0%10.0%20.0%30.0%40.0%50.0%52.5%55.0%57.5%60.0%62.5%65.0%67.5%70.0%72.5%75.0%77.5%80.0%81.5%83.0%84.5%86.0%87.5%89.0%90.5%92.0%93.5%95.0%96.0%97.0%97.9% Soil Source Zone Mass (lbs):N/A1 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A Smear Source Zone Mass (lbs):1 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A Groundwater Zone Mass (lbs):7.13 6.42 5.70 4.99 4.28 3.57 3.05 3.21 3.03 2.85 2.67 2.50 2.32 2.14 1.96 1.78 1.60 1.43 1.32 1.21 1.11 1.00 0.89 0.78 0.68 0.57 0.46 0.36 0.29 0.21 0.15 Total Mass: Baseline/Milestone 7.13 6.42 5.70 4.99 4.28 3.57 3.05 3.21 3.03 2.85 2.67 2.50 2.32 2.14 1.96 1.78 1.60 1.43 1.32 1.21 1.11 1.00 0.89 0.78 0.68 0.57 0.46 0.36 0.29 0.21 0.15 Initial 10/2009 10/2014 10/2015 10/2016 4/2017 11/2017 6/2018 12/2018 6/2019 1/2020 7/2020 1/2021 7/2021 1/2022 7/2022 1/2023 8/2023 2/2024 End / Measured Mass 2 Soil Source Zone:1 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A Smear Source Zone:N/A1 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A Groundwater Zone:7.13 11.08 5.84 3.90 3.42 0.91 6.36 4.85 5.84 2.61 4.67 3.49 2.92 2.46 2.05 1.55 1.69 1.90 0.77 Removed Mass 3 - Excavated from Soil/Smear:N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A Extracted as Vapor/Gas:N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A Extracted as Liquid:0 4.51 4.40 0.18 0.02 0.02 0.01 0.14 0.25 0.48 0.36 0.14 0.29 0.32 0.16 0.10 0.10 0.10 0.07 Total Mass Removed (est ):0 4.51 4.40 0.18 0.02 0.02 0.01 0.14 0.25 0.48 0.36 0.14 0.29 0.32 0.16 0.10 0.10 0.10 0.07 Revised Total Mass (est.)2 7.13 11.08 5.84 3.90 3.42 0.91 6.36 4.85 5.84 2.61 4.67 3.49 2.92 2.46 2.05 1.55 1.69 1.90 0.77 4 0%-55%47%33%12%73%-596%24%-20%55%-79%25%16%16%17%24%-9%-12%59% Reference Milestone (label from above)Baseline Active Y5 Active Y10 Active Y11 Active Y12 Active Y13 Active Y13.5 Active Y14 Active Y14.5 Active Y15 Active Y15.5 Active Y16 Active Y16.5 Active Y17 Active Y17.5 Active Y18 Active Y18.5 Active Y19 Inactive Y19.5 Inactive Y20 Inactive Y20.5 Inactive Y21 Inactive Y21.5 Inactive Y22 Inactive Y22.5 Inactive Y23 Inactive Y23.5 Inactive Y24 Inactive Y24.5 Inactive Y25 Closure Reference Milestone (value from above)7.13 6.42 5.70 4.99 4.28 3.57 3.05 3.21 3.03 2.85 2.67 2.50 2.32 2.14 1.96 1.78 1.60 1.43 1.32 1.21 1.11 1.00 0.89 0.78 0.68 0.57 0.46 0.36 0.29 0.21 0.15 Reduction Progress vs Milestone5 0%-73%-2%22%20%74%-109%-51%-93%8%-75%-40%-26%-15%-5%13%-5%-33%42% 1. Remediation of soil not required by DEQ due to low levels remaining in soil; therefore, soil mass not included in total mass milestones. Approved Corrective Action Plan for groundwater remediation of fractured bedrock only. 2. Mass calculated by multiplying the analytical results by the representative volume using: Area of Water (v) x Plume Thickness (d) x Average Concentrations of Benzene and MTBE (c) x Porosity of Aquifer (n) (see below for assumptions). 3. Removed mass calculated by system effluent monitoring, multiplied by total volume extracted by the system during that period. 4. Reduction rate equals the % reduction from the prior mass (current Total Mass ÷ prior Total Mass). 5. Reduction progress vs milestone equals the current mass reduction % progress (1 - (Revised Total Mass ÷ Applicable Milestone)). Zero or positive values indicate that the associated milestone has been reached. Assumptions: Porosity (n) = 0.1 for fractured bedrock Plume thickness (d) = 30 ft Initial Average Concentrations (c): Benzene Source Area = 260 ppb (avg. of MW-3D/5D on 10/16/03) MTBE Source Area = 1,345 ppb (avg. of MW-3D/5D on 10/16/03) Benzene Remaining Plume Area = 7.45 ppb (avg. of supply wells 16/62 on 10/16/03) MTBE Remaining Plume Area = 45.5 ppb (avg. of supply wells 16/62 on 10/16/03) Table 7 Evaluation of Change in Contaminant Mass General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 Initial Mass Estimate / Projected Milestones (from CAP/Calculated) Initial Baseline Milestones1 End / Closure Measured / Calculated Change in Contaminant Mass (from sampling) Milestone Sampling / Measurement Event Dates1 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/General Store of Denver - GSD/GSD-050/032024/Monitoring Report/Table 7 Milestone.xlsx4/5/2024 Table 7 (Page 1 of 1) Hart & Hickman, PC USGS The National Map: National Boundaries Dataset, 3DEP ElevationProgram, Geographic Names Information System, National HydrographyDataset, National Land Cover Database, National Structures Dataset,and National Transportation Dataset; USGS Global Ecosystems; U.S.Census Bureau TIGER/Line data; USFS Road Data; Natural Earth Data;U.S. Department of State Humanitarian Information Unit; and NOAANational Centers for Environmental Information, U.S. Coastal ReliefModel. Data refreshed May, 2020. SITE LOCATION MAP GENERAL STORE OF DENVERSHERRILLS FORD, NORTH CAROLINA DATE: 4-5-24 JOB NO: GSD-050 REVISION NO: 0 FIGURE NO: 1 2923 South Tryon Street - Suite 100Charlotte, North Carolina 28203704-586-0007 (p) 704-586-0373 (f)License # C-1269 / # C-245 Geology TITLE PROJECT 0 2,000 4,000 SCALE IN FEET SITE Pa t h : S : \ A A A - M a s t e r P r o j e c t s \ G e n e r a l S t o r e o f D e n v e r - G S D \ G S D - 0 5 0 \ F i g u r e s \ F i g u r e - 1 . m x d N U.S.G.S. QUADRANGLE MAP DENVER, NORTH CAROLINA 2019 QUADRANGLE7.5 MINUTE SERIES (TOPOGRAPHIC) MW-2D MW-2 MW-3 MW-4D MW-6D MW-4 MT. PLEASA N T R D . NC H I G H W A Y # 1 5 0 MW-1 (ABANDONED) CAN O P Y ALUMINUM BUILDINGS BACH WELL HOUSE THE GENERAL STORE OF DENVER HARDWARE STORE ASPHALT CONCRETE DRIVEFORMER 1,000 GALLON KEROSENE UST WSW MW-5D PROPANE TANK EMERALD ISLE TRAILER PARK DIESEL DISPENSER MW-5 DENR MW-06D DENR MW-05 HAI R S A L O N (for m e r d a y c a r e ) RES I D E N C E RESCUE SQUAD DENR (NO NAME) OVE R H A N G SW A L E SW A L E TREATMENT SYSTEM BUILDING RECOVERY WELL TRENCH DISCHARGE TRENCH SYSTEM DISCHARGE LOCATION WITH RIPRAP DRAINAGE BASIN STORMWATER SWALE LIGHT SIGN CHRISTENBURY WATER SUPPLY WELL FORMER DAYCARE WATER SUPPLY WELL MW-3D MW-1D e w REVISION NO. 0 JOB NO. GSD-050 DATE: 4-5-24 FIGURE NO. 2 GENERAL STORE OF DENVER SHERRILLS FORD, NORTH CAROLINA SITE LAYOUT 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology LEGEND PROPERTY LINE STORMWATER PIPING SUBSURFACE WATER LINE SUBSURFACE ELECTRICAL LINE GROUNDWATER TREATMENT TRENCH 2x2-IN STEEL ACCESS VAULT NCDENR WELL MONITORING WELL WATER SUPPLY WELL POWER POLE UST INCLUDING SIZE OF TANK (GALLONS) KEROSENE DIESEL GASOLINE STORMWATER CATCH BASIN CULVERT GRASS GRASS GRASS GRASS GRASS GRASS S: \ A A A - M a s t e r P r o j e c t s \ G e n e r a l S t o r e o f D e n v e r - G S D \ G S D - 0 5 0 \ 0 9 2 0 2 2 \ R e m e d i a t i o n R e p o r t \ F i g u r e s \ G S D . 0 5 0 - F i g u r e s - 2 3 0 3 0 7 . d w g , F I G 2 , 3 / 7 / 2 0 2 3 1 2 : 4 3 : 5 0 P M , k m c k i n n e y 13 12 11 14 15 16 1718 5 3 6 31 4 30 24 23 22 21 20 19 25 26 27 28 29 34 35 33 37 36 32 61 60 5859 57 62 56 54 5552 5150 494546 44 43 48 47 53 9 8 10 1 2 42 39 38 40 741 BACH WELL INACTIVE 1500' RADIUS REVISION NO. 0 JOB NO. GSD-050 DATE: 4-5-24 FIGURE NO. 3 GENERAL STORE OF DENVER SHERRILLS FORD, NORTH CAROLINA WATER SUPPLY WELL SURVEY MAP 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology LEGEND PROPERTY LINE CREEK WATER SUPPLY WELL LOCATION COMMUNITY WATER SUPPLY WELL LOCATION RED SYMBOLS INDICATE INACTIVE WELL LAND TRACT # MONITORING WELL (APPROXIMATELY 50 FT) DEEP MONITORING WELL (APPROXIMATELY 85 FT) 2 NOTES: 1. MTBE = METHYL tert-BUTYL ETHER NS = NOT SAMPLED DATE 11/23 2/24 BENZENE <0.50 <0.50 MTBE <0.50 <0.50 SAMPLE DATE CONCENTRATION (ųg/L)CONSTITUENT DATE 11/23 2/24 BENZENE NS NS MTBE NS NS DATE 11/23 2/24 BENZENE <0.50 <0.500 MTBE <0.50 <1.00 DATE 11/23 2/24 BENZENE <0.50 <0.500 MTBE <0.50 <1.00 NS S: \ A A A - M a s t e r P r o j e c t s \ G e n e r a l S t o r e o f D e n v e r - G S D \ G S D - 0 5 0 \ 0 9 2 0 2 2 \ R e m e d i a t i o n R e p o r t \ F i g u r e s \ G S D . 0 5 0 - F i g u r e s - 2 3 0 3 0 7 . d w g , F I G 3 , 3 / 7 / 2 0 2 3 1 : 0 4 : 4 4 P M , k m c k i n n e y MW-2D MW-2 MW-3 MW-4D MW-6D MW-4 MT. PLEASA N T R D . NC H I G H W A Y # 1 5 0 MW-1 (ABANDONED) CAN O P Y ALUMINUM BUILDINGS BACH WELL HOUSE THE GENERAL STORE OF DENVER HARDWARE STORE ASPHALT CONCRETE DRIVEFORMER 1,000 GALLON KEROSENE UST WSW MW-5D PROPANE TANK EMERALD ISLE TRAILER PARK DIESEL DISPENSER MW-5 DENR MW-06D DENR MW-05 HAI R S A L O N (for m e r d a y c a r e ) RES I D E N C E RESCUE SQUAD DENR (NO NAME) OVE R H A N G SW A L E SW A L E TREATMENT SYSTEM BUILDING RECOVERY WELL TRENCH DISCHARGE TRENCH SYSTEM DISCHARGE LOCATION WITH RIPRAP DRAINAGE BASIN STORMWATER SWALE LIGHT SIGN CHRISTENBURY WATER SUPPLY WELL FORMER DAYCARE WATER SUPPLY WELL (37.41) (38.45) 37 35 37 36 MW-3D 35 36 MW-1D (39.66) (34.63) 38 38 39 39 e w (38.45) NOTES: 1. ELEVATION BASED ON ARBITRARY DATUM. 2. * = GROUNDWATER ELEVATION NOT USED FOR CONTOURING.REVISION NO. 0 JOB NO. GSD-050 DATE: 4-5-24 FIGURE NO. 4 GENERAL STORE OF DENVER SHERRILLS FORD, NORTH CAROLINA DEEP WELL GROUNDWATER ELEVATIONS (AUGUST 2023) 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology LEGEND PROPERTY LINE STORMWATER PIPING SUBSURFACE WATER LINE SUBSURFACE ELECTRICAL LINE GROUNDWATER TREATMENT TRENCH 2x2-IN STEEL ACCESS VAULT NCDENR WELL MONITORING WELL WATER SUPPLY WELL POWER POLE UST INCLUDING SIZE OF TANK (GALLONS) KEROSENE DIESEL GASOLINE STORMWATER CATCH BASIN CULVERT GROUNDWATER ELEVATION CONTOUR GROUNDWATER ELEVATION (FT) GRASS GRASS GRASS GRASS GRASS GRASS 39 S: \ A A A - M a s t e r P r o j e c t s \ G e n e r a l S t o r e o f D e n v e r - G S D \ G S D - 0 5 0 \ 0 9 2 0 2 2 \ R e m e d i a t i o n R e p o r t \ F i g u r e s \ G S D . 0 5 0 - F i g u r e s - 2 3 0 3 0 7 . d w g , F I G 4 , 3 / 7 / 2 0 2 3 1 : 2 1 : 2 9 P M , k m c k i n n e y MW-2D MW-2 MW-3 MW-4D MW-6D MW-4 MT. PLEASA N T R D . NC H I G H W A Y # 1 5 0 MW-1 (ABANDONED) CAN O P Y ALUMINUM BUILDINGS BACH WELL HOUSE THE GENERAL STORE OF DENVER HARDWARE STORE ASPHALT CONCRETE DRIVEFORMER 1,000 GALLON KEROSENE UST WSW MW-5D PROPANE TANK EMERALD ISLE TRAILER PARK DIESEL DISPENSER MW-5 DENR MW-06D DENR MW-05 HAI R S A L O N (for m e r d a y c a r e ) RES I D E N C E RESCUE SQUAD DENR (NO NAME) OVE R H A N G SW A L E SW A L E TREATMENT SYSTEM BUILDING RECOVERY WELL TRENCH DISCHARGE TRENCH SYSTEM DISCHARGE LOCATION WITH RIPRAP DRAINAGE BASIN STORMWATER SWALE LIGHT SIGN CHRISTENBURY WATER SUPPLY WELL FORMER DAYCARE WATER SUPPLY WELL MW-3D MW-1D e w NOTES: 1. MTBE = METHYL tert-BUTYL ETHER REVISION NO. 0 JOB NO. GSD-050 DATE: 4-5-24 FIGURE NO. 5 GENERAL STORE OF DENVER SHERRILLS FORD, NORTH CAROLINA BENZENE AND MTBE IN GROUNDWATER (FEBRUARY 2024) 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology LEGEND ESTIMATED SOURCE AREA BENZENE/MTBE PLUME UTILIZED IN MASS CALCULATIONS PROPERTY LINE STORMWATER PIPING SUBSURFACE WATER LINE SUBSURFACE ELECTRICAL LINE GROUNDWATER TREATMENT TRENCH 2x2-IN STEEL ACCESS VAULT NCDENR WELL MONITORING WELL WATER SUPPLY WELL POWER POLE UST INCLUDING SIZE OF TANK (GALLONS) KEROSENE DIESEL GASOLINE STORMWATER CATCH BASIN CULVERT GRASS GRASS GRASS GRASS GRASS GRASS MW-3D BENZENE <5.0 MTBE 1,480 SAMPLE ID CONCENTRATION (µg/L)CONSTITUENT MW-3D BENZENE <5.00 MTBE 616 MW-5D BENZENE <0.500 MTBE <1.00 S: \ A A A - M a s t e r P r o j e c t s \ G e n e r a l S t o r e o f D e n v e r - G S D \ G S D - 0 5 0 \ 0 9 2 0 2 2 \ R e m e d i a t i o n R e p o r t \ F i g u r e s \ G S D . 0 5 0 - F i g u r e s - 2 3 0 3 0 7 . d w g , F I G 5 , 3 / 7 / 2 0 2 3 1 : 2 1 : 4 0 P M , k m c k i n n e y GENERAL STORE OF DENVER SHERRILLS FORD, NORTH CAROLINA REVISION NO. 0 JOB NO. GSD-050 DATE: 4-5-24 FIGURE NO. 6 TREATMENT SYSTEM SCHEMATIC 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology S: \ A A A - M a s t e r P r o j e c t s \ G e n e r a l S t o r e o f D e n v e r - G S D \ G S D - 0 5 0 \ 0 9 2 0 2 2 \ R e m e d i a t i o n R e p o r t \ F i g u r e s \ F I G - 0 6 . d w g , M o d e l , 3 / 7 / 2 0 2 3 1 : 2 2 : 2 6 P M , k m c k i n n e y ESTIMATED EXTENT OF BENZENE AND MTBE GROUNDWATER IMPACTS PRIOR TO REMEDIATION GENERAL STORE OF DENVER SHERRILLS FORD, NORTH CAROLINA REVISION NO. 0 JOB NO. GSD-050 DATE: 4-5-24 FIGURE NO. 7 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology S: \ A A A - M a s t e r P r o j e c t s \ G e n e r a l S t o r e o f D e n v e r - G S D \ G S D - 0 5 0 \ 0 9 2 0 2 2 \ R e m e d i a t i o n R e p o r t \ F i g u r e s \ F i g u r e 7 . d w g , M o d e l , 3 / 7 / 2 0 2 3 1 : 2 7 : 2 6 P M , k m c k i n n e y ESTIMATED EXTENT OF CURRENT BENZENE AND MTBE GROUNDWATER IMPACTS GENERAL STORE OF DENVER SHERRILLS FORD, NORTH CAROLINA REVISION NO. 0 JOB NO. GSD-050 DATE: 4-5-24 FIGURE NO. 8 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology S: \ A A A - M a s t e r P r o j e c t s \ G e n e r a l S t o r e o f D e n v e r - G S D \ G S D - 0 5 0 \ 0 9 2 0 2 2 \ R e m e d i a t i o n R e p o r t \ F i g u r e s \ F i g u r e 8 . d w g , M o d e l , 3 / 7 / 2 0 2 3 1 : 2 6 : 2 8 P M , k m c k i n n e y 4 4 Appendix A Laboratory Analytical Reports and Chain-of-Custody Forms #=CL# December 04, 2023 LIMS USE: FR - STEVE LIBBEY LIMS OBJECT ID: 92699610 92699610 Project: Pace Project No.: RE: Steve Libbey Hart & Hickman 2923 South Tryon Street Charlotte, NC 28203 GSD.050 Dear Steve Libbey: Enclosed are the analytical results for sample(s) received by the laboratory on November 20, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Taylor M Cannon taylor.cannon@pacelabs.com Project Manager 704-977-0943 Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 31 #=CP# CERTIFICATIONS Pace Project No.: Project: 92699610 GSD.050 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 31 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92699610 GSD.050 Lab ID Sample ID Matrix Date Collected Date Received 92699610001 INFLUENT Water 11/20/23 14:00 11/20/23 15:30 92699610002 EFFLUENT Water 11/20/23 13:30 11/20/23 15:30 92699610003 WSW-16 Water 11/20/23 14:25 11/20/23 15:30 92699610004 WSW-KR2 Water 11/20/23 14:45 11/20/23 15:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 31 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92699610 GSD.050 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92699610001 INFLUENT EPA 1664B 1 PASI-CDVR EPA 6010D 1 PASI-ADBB1 SM 6200B 63 PASI-CJJK SM 2540D-2015 1 PASI-AJAY EPA 420.4 Rev 1.0 1993 1 PASI-AARJ 92699610002 EFFLUENT EPA 1664B 1 PASI-CDVR EPA 6010D 1 PASI-ADBB1 SM 6200B 63 PASI-CSAS SM 2540D-2015 1 PASI-AJAY EPA 420.4 Rev 1.0 1993 1 PASI-AARJ 92699610003 WSW-16 SM 6200B 63 PASI-CSAS 92699610004 WSW-KR2 SM 6200B 63 PASI-CSAS PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92699610 GSD.050 Sample:INFLUENT Lab ID:92699610001 Collected:11/20/23 14:00 Received:11/20/23 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 1664B Pace Analytical Services - Charlotte HEM, Oil and Grease Oil and Grease ND mg/L 11/29/23 11:154.8 1 Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services - Asheville 6010 MET ICP Lead ND ug/L 12/01/23 16:45 7439-92-111/21/23 12:005.0 1 Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV Benzene ND ug/L 11/28/23 16:34 71-43-22.5 5 Bromobenzene ND ug/L 11/28/23 16:34 108-86-12.5 5 Bromochloromethane ND ug/L 11/28/23 16:34 74-97-52.5 5 Bromodichloromethane ND ug/L 11/28/23 16:34 75-27-42.5 5 Bromoform ND ug/L 11/28/23 16:34 75-25-22.5 5 Bromomethane ND ug/L 11/28/23 16:34 74-83-925.0 5 n-Butylbenzene ND ug/L 11/28/23 16:34 104-51-82.5 5 sec-Butylbenzene ND ug/L 11/28/23 16:34 135-98-82.5 5 tert-Butylbenzene ND ug/L 11/28/23 16:34 98-06-62.5 5 Carbon tetrachloride ND ug/L 11/28/23 16:34 56-23-52.5 5 Chlorobenzene ND ug/L 11/28/23 16:34 108-90-72.5 5 Chloroethane ND ug/L 11/28/23 16:34 75-00-35.0 5 Chloroform ND ug/L 11/28/23 16:34 67-66-32.5 5 Chloromethane ND ug/L 11/28/23 16:34 74-87-35.0 5 2-Chlorotoluene ND ug/L 11/28/23 16:34 95-49-82.5 5 4-Chlorotoluene ND ug/L 11/28/23 16:34 106-43-42.5 5 1,2-Dibromo-3-chloropropane ND ug/L 11/28/23 16:34 96-12-85.0 5 Dibromochloromethane ND ug/L 11/28/23 16:34 124-48-12.5 5 1,2-Dibromoethane (EDB)ND ug/L 11/28/23 16:34 106-93-42.5 5 Dibromomethane ND ug/L 11/28/23 16:34 74-95-32.5 5 1,2-Dichlorobenzene ND ug/L 11/28/23 16:34 95-50-12.5 5 1,3-Dichlorobenzene ND ug/L 11/28/23 16:34 541-73-12.5 5 1,4-Dichlorobenzene ND ug/L 11/28/23 16:34 106-46-72.5 5 Dichlorodifluoromethane ND ug/L 11/28/23 16:34 75-71-82.5 5 1,1-Dichloroethane ND ug/L 11/28/23 16:34 75-34-32.5 5 1,2-Dichloroethane ND ug/L 11/28/23 16:34 107-06-22.5 5 1,1-Dichloroethene ND ug/L 11/28/23 16:34 75-35-42.5 5 cis-1,2-Dichloroethene ND ug/L 11/28/23 16:34 156-59-22.5 5 trans-1,2-Dichloroethene ND ug/L 11/28/23 16:34 156-60-52.5 5 1,2-Dichloropropane ND ug/L 11/28/23 16:34 78-87-52.5 5 1,3-Dichloropropane ND ug/L 11/28/23 16:34 142-28-92.5 5 2,2-Dichloropropane ND ug/L 11/28/23 16:34 594-20-72.5 5 1,1-Dichloropropene ND ug/L 11/28/23 16:34 563-58-62.5 5 cis-1,3-Dichloropropene ND ug/L 11/28/23 16:34 10061-01-52.5 5 trans-1,3-Dichloropropene ND ug/L 11/28/23 16:34 10061-02-62.5 5 Diisopropyl ether 4.8 ug/L 11/28/23 16:34 108-20-32.5 5 Ethylbenzene ND ug/L 11/28/23 16:34 100-41-42.5 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92699610 GSD.050 Sample:INFLUENT Lab ID:92699610001 Collected:11/20/23 14:00 Received:11/20/23 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV Hexachloro-1,3-butadiene ND ug/L 11/28/23 16:34 87-68-310.0 5 Isopropylbenzene (Cumene)ND ug/L 11/28/23 16:34 98-82-82.5 5 Methylene Chloride ND ug/L 11/28/23 16:34 75-09-210.0 5 Methyl-tert-butyl ether 621 ug/L 11/28/23 16:34 1634-04-42.5 5 Naphthalene ND ug/L 11/28/23 16:34 91-20-310.0 5 n-Propylbenzene ND ug/L 11/28/23 16:34 103-65-12.5 5 Styrene ND ug/L 11/28/23 16:34 100-42-52.5 5 1,1,1,2-Tetrachloroethane ND ug/L 11/28/23 16:34 630-20-62.5 5 1,1,2,2-Tetrachloroethane ND ug/L 11/28/23 16:34 79-34-52.5 5 Tetrachloroethene ND ug/L 11/28/23 16:34 127-18-42.5 5 Toluene ND ug/L 11/28/23 16:34 108-88-32.5 5 1,2,3-Trichlorobenzene ND ug/L 11/28/23 16:34 87-61-610.0 5 1,2,4-Trichlorobenzene ND ug/L 11/28/23 16:34 120-82-110.0 5 1,1,1-Trichloroethane ND ug/L 11/28/23 16:34 71-55-62.5 5 1,1,2-Trichloroethane ND ug/L 11/28/23 16:34 79-00-52.5 5 Trichloroethene ND ug/L 11/28/23 16:34 79-01-62.5 5 Trichlorofluoromethane ND ug/L 11/28/23 16:34 75-69-45.0 5 1,2,3-Trichloropropane ND ug/L 11/28/23 16:34 96-18-42.5 5 1,2,4-Trimethylbenzene 4.3 ug/L 11/28/23 16:34 95-63-62.5 5 1,3,5-Trimethylbenzene ND ug/L 11/28/23 16:34 108-67-82.5 5 Vinyl chloride ND ug/L 11/28/23 16:34 75-01-45.0 5 m&p-Xylene ND ug/L 11/28/23 16:34 179601-23-15.0 5 o-Xylene ND ug/L 11/28/23 16:34 95-47-62.5 5 Surrogates 1,2-Dichloroethane-d4 (S)95 %11/28/23 16:34 17060-07-070-130 5 4-Bromofluorobenzene (S)96 %11/28/23 16:34 460-00-470-130 5 Toluene-d8 (S)98 %11/28/23 16:34 2037-26-570-130 5 Analytical Method: SM 2540D-2015 Pace Analytical Services - Asheville 2540D Total Suspended Solids Total Suspended Solids 6.5 mg/L 11/22/23 10:492.5 1 Analytical Method: EPA 420.4 Rev 1.0 1993 Preparation Method: EPA 420.4 Rev 1.0 1993 Pace Analytical Services - Asheville 420.4 Phenolics, Total Phenolics, Total Recoverable ND mg/L 11/29/23 16:01 64743-03-911/29/23 12:580.020 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92699610 GSD.050 Sample:EFFLUENT Lab ID:92699610002 Collected:11/20/23 13:30 Received:11/20/23 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 1664B Pace Analytical Services - Charlotte HEM, Oil and Grease Oil and Grease ND mg/L 11/29/23 11:154.9 1 Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services - Asheville 6010 MET ICP Lead ND ug/L 12/01/23 17:07 7439-92-111/21/23 12:005.0 1 Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV Benzene ND ug/L 11/30/23 00:37 71-43-20.50 1 Bromobenzene ND ug/L 11/30/23 00:37 108-86-10.50 1 Bromochloromethane ND ug/L 11/30/23 00:37 74-97-50.50 1 Bromodichloromethane ND ug/L 11/30/23 00:37 75-27-40.50 1 Bromoform ND ug/L 11/30/23 00:37 75-25-20.50 1 Bromomethane ND ug/L 11/30/23 00:37 74-83-95.0 1 n-Butylbenzene ND ug/L 11/30/23 00:37 104-51-80.50 1 sec-Butylbenzene ND ug/L 11/30/23 00:37 135-98-80.50 1 tert-Butylbenzene ND ug/L 11/30/23 00:37 98-06-60.50 1 Carbon tetrachloride ND ug/L 11/30/23 00:37 56-23-50.50 1 Chlorobenzene ND ug/L 11/30/23 00:37 108-90-70.50 1 Chloroethane ND ug/L 11/30/23 00:37 75-00-31.0 1 Chloroform ND ug/L 11/30/23 00:37 67-66-30.50 1 Chloromethane ND ug/L 11/30/23 00:37 74-87-31.0 1 2-Chlorotoluene ND ug/L 11/30/23 00:37 95-49-80.50 1 4-Chlorotoluene ND ug/L 11/30/23 00:37 106-43-40.50 1 1,2-Dibromo-3-chloropropane ND ug/L 11/30/23 00:37 96-12-81.0 1 Dibromochloromethane ND ug/L 11/30/23 00:37 124-48-10.50 1 1,2-Dibromoethane (EDB)ND ug/L 11/30/23 00:37 106-93-40.50 1 Dibromomethane ND ug/L 11/30/23 00:37 74-95-30.50 1 1,2-Dichlorobenzene ND ug/L 11/30/23 00:37 95-50-10.50 1 1,3-Dichlorobenzene ND ug/L 11/30/23 00:37 541-73-10.50 1 1,4-Dichlorobenzene ND ug/L 11/30/23 00:37 106-46-70.50 1 Dichlorodifluoromethane ND ug/L 11/30/23 00:37 75-71-80.50 1 1,1-Dichloroethane ND ug/L 11/30/23 00:37 75-34-30.50 1 1,2-Dichloroethane ND ug/L 11/30/23 00:37 107-06-20.50 1 1,1-Dichloroethene ND ug/L 11/30/23 00:37 75-35-40.50 1 cis-1,2-Dichloroethene ND ug/L 11/30/23 00:37 156-59-20.50 1 trans-1,2-Dichloroethene ND ug/L 11/30/23 00:37 156-60-50.50 1 1,2-Dichloropropane ND ug/L 11/30/23 00:37 78-87-50.50 1 1,3-Dichloropropane ND ug/L 11/30/23 00:37 142-28-90.50 1 2,2-Dichloropropane ND ug/L 11/30/23 00:37 594-20-70.50 1 1,1-Dichloropropene ND ug/L 11/30/23 00:37 563-58-60.50 1 cis-1,3-Dichloropropene ND ug/L 11/30/23 00:37 10061-01-50.50 1 trans-1,3-Dichloropropene ND ug/L 11/30/23 00:37 10061-02-60.50 1 Diisopropyl ether ND ug/L 11/30/23 00:37 108-20-30.50 1 Ethylbenzene ND ug/L 11/30/23 00:37 100-41-40.50 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92699610 GSD.050 Sample:EFFLUENT Lab ID:92699610002 Collected:11/20/23 13:30 Received:11/20/23 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV Hexachloro-1,3-butadiene ND ug/L 11/30/23 00:37 87-68-32.0 1 Isopropylbenzene (Cumene)ND ug/L 11/30/23 00:37 98-82-80.50 1 Methylene Chloride ND ug/L 11/30/23 00:37 75-09-22.0 1 Methyl-tert-butyl ether ND ug/L 11/30/23 00:37 1634-04-40.50 1 Naphthalene ND ug/L 11/30/23 00:37 91-20-32.0 1 n-Propylbenzene ND ug/L 11/30/23 00:37 103-65-10.50 1 Styrene ND ug/L 11/30/23 00:37 100-42-50.50 1 1,1,1,2-Tetrachloroethane ND ug/L 11/30/23 00:37 630-20-60.50 1 1,1,2,2-Tetrachloroethane ND ug/L 11/30/23 00:37 79-34-50.50 1 Tetrachloroethene ND ug/L 11/30/23 00:37 127-18-40.50 1 Toluene ND ug/L 11/30/23 00:37 108-88-30.50 1 1,2,3-Trichlorobenzene ND ug/L 11/30/23 00:37 87-61-62.0 1 1,2,4-Trichlorobenzene ND ug/L 11/30/23 00:37 120-82-12.0 1 1,1,1-Trichloroethane ND ug/L 11/30/23 00:37 71-55-60.50 1 1,1,2-Trichloroethane ND ug/L 11/30/23 00:37 79-00-50.50 1 Trichloroethene ND ug/L 11/30/23 00:37 79-01-60.50 1 Trichlorofluoromethane ND ug/L 11/30/23 00:37 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 11/30/23 00:37 96-18-40.50 1 1,2,4-Trimethylbenzene ND ug/L 11/30/23 00:37 95-63-60.50 1 1,3,5-Trimethylbenzene ND ug/L 11/30/23 00:37 108-67-80.50 1 Vinyl chloride ND ug/L 11/30/23 00:37 75-01-41.0 1 m&p-Xylene ND ug/L 11/30/23 00:37 179601-23-11.0 1 o-Xylene ND ug/L 11/30/23 00:37 95-47-60.50 1 Surrogates 1,2-Dichloroethane-d4 (S)95 %11/30/23 00:37 17060-07-070-130 1 4-Bromofluorobenzene (S)96 %11/30/23 00:37 460-00-470-130 1 Toluene-d8 (S)99 %11/30/23 00:37 2037-26-570-130 1 Analytical Method: SM 2540D-2015 Pace Analytical Services - Asheville 2540D Total Suspended Solids Total Suspended Solids ND mg/L 11/22/23 10:492.5 1 Analytical Method: EPA 420.4 Rev 1.0 1993 Preparation Method: EPA 420.4 Rev 1.0 1993 Pace Analytical Services - Asheville 420.4 Phenolics, Total Phenolics, Total Recoverable ND mg/L 11/29/23 16:02 64743-03-911/29/23 12:580.020 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92699610 GSD.050 Sample:WSW-16 Lab ID:92699610003 Collected:11/20/23 14:25 Received:11/20/23 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV Benzene ND ug/L 11/30/23 00:55 71-43-20.50 1 Bromobenzene ND ug/L 11/30/23 00:55 108-86-10.50 1 Bromochloromethane ND ug/L 11/30/23 00:55 74-97-50.50 1 Bromodichloromethane ND ug/L 11/30/23 00:55 75-27-40.50 1 Bromoform ND ug/L 11/30/23 00:55 75-25-20.50 1 Bromomethane ND ug/L 11/30/23 00:55 74-83-95.0 1 n-Butylbenzene ND ug/L 11/30/23 00:55 104-51-80.50 1 sec-Butylbenzene ND ug/L 11/30/23 00:55 135-98-80.50 1 tert-Butylbenzene ND ug/L 11/30/23 00:55 98-06-60.50 1 Carbon tetrachloride ND ug/L 11/30/23 00:55 56-23-50.50 1 Chlorobenzene ND ug/L 11/30/23 00:55 108-90-70.50 1 Chloroethane ND ug/L 11/30/23 00:55 75-00-31.0 1 Chloroform ND ug/L 11/30/23 00:55 67-66-30.50 1 Chloromethane ND ug/L 11/30/23 00:55 74-87-31.0 1 2-Chlorotoluene ND ug/L 11/30/23 00:55 95-49-80.50 1 4-Chlorotoluene ND ug/L 11/30/23 00:55 106-43-40.50 1 1,2-Dibromo-3-chloropropane ND ug/L 11/30/23 00:55 96-12-81.0 1 Dibromochloromethane ND ug/L 11/30/23 00:55 124-48-10.50 1 1,2-Dibromoethane (EDB)ND ug/L 11/30/23 00:55 106-93-40.50 1 Dibromomethane ND ug/L 11/30/23 00:55 74-95-30.50 1 1,2-Dichlorobenzene ND ug/L 11/30/23 00:55 95-50-10.50 1 1,3-Dichlorobenzene ND ug/L 11/30/23 00:55 541-73-10.50 1 1,4-Dichlorobenzene ND ug/L 11/30/23 00:55 106-46-70.50 1 Dichlorodifluoromethane ND ug/L 11/30/23 00:55 75-71-80.50 1 1,1-Dichloroethane ND ug/L 11/30/23 00:55 75-34-30.50 1 1,2-Dichloroethane ND ug/L 11/30/23 00:55 107-06-20.50 1 1,1-Dichloroethene ND ug/L 11/30/23 00:55 75-35-40.50 1 cis-1,2-Dichloroethene ND ug/L 11/30/23 00:55 156-59-20.50 1 trans-1,2-Dichloroethene ND ug/L 11/30/23 00:55 156-60-50.50 1 1,2-Dichloropropane ND ug/L 11/30/23 00:55 78-87-50.50 1 1,3-Dichloropropane ND ug/L 11/30/23 00:55 142-28-90.50 1 2,2-Dichloropropane ND ug/L 11/30/23 00:55 594-20-70.50 1 1,1-Dichloropropene ND ug/L 11/30/23 00:55 563-58-60.50 1 cis-1,3-Dichloropropene ND ug/L 11/30/23 00:55 10061-01-50.50 1 trans-1,3-Dichloropropene ND ug/L 11/30/23 00:55 10061-02-60.50 1 Diisopropyl ether ND ug/L 11/30/23 00:55 108-20-30.50 1 Ethylbenzene ND ug/L 11/30/23 00:55 100-41-40.50 1 Hexachloro-1,3-butadiene ND ug/L 11/30/23 00:55 87-68-32.0 1 Isopropylbenzene (Cumene)ND ug/L 11/30/23 00:55 98-82-80.50 1 Methylene Chloride ND ug/L 11/30/23 00:55 75-09-22.0 1 Methyl-tert-butyl ether ND ug/L 11/30/23 00:55 1634-04-40.50 1 Naphthalene ND ug/L 11/30/23 00:55 91-20-32.0 1 n-Propylbenzene ND ug/L 11/30/23 00:55 103-65-10.50 1 Styrene ND ug/L 11/30/23 00:55 100-42-50.50 1 1,1,1,2-Tetrachloroethane ND ug/L 11/30/23 00:55 630-20-60.50 1 1,1,2,2-Tetrachloroethane ND ug/L 11/30/23 00:55 79-34-50.50 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92699610 GSD.050 Sample:WSW-16 Lab ID:92699610003 Collected:11/20/23 14:25 Received:11/20/23 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV Tetrachloroethene ND ug/L 11/30/23 00:55 127-18-40.50 1 Toluene ND ug/L 11/30/23 00:55 108-88-30.50 1 1,2,3-Trichlorobenzene ND ug/L 11/30/23 00:55 87-61-62.0 1 1,2,4-Trichlorobenzene ND ug/L 11/30/23 00:55 120-82-12.0 1 1,1,1-Trichloroethane ND ug/L 11/30/23 00:55 71-55-60.50 1 1,1,2-Trichloroethane ND ug/L 11/30/23 00:55 79-00-50.50 1 Trichloroethene ND ug/L 11/30/23 00:55 79-01-60.50 1 Trichlorofluoromethane ND ug/L 11/30/23 00:55 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 11/30/23 00:55 96-18-40.50 1 1,2,4-Trimethylbenzene ND ug/L 11/30/23 00:55 95-63-60.50 1 1,3,5-Trimethylbenzene ND ug/L 11/30/23 00:55 108-67-80.50 1 Vinyl chloride ND ug/L 11/30/23 00:55 75-01-41.0 1 m&p-Xylene ND ug/L 11/30/23 00:55 179601-23-11.0 1 o-Xylene ND ug/L 11/30/23 00:55 95-47-60.50 1 Surrogates 1,2-Dichloroethane-d4 (S)95 %11/30/23 00:55 17060-07-070-130 1 4-Bromofluorobenzene (S)97 %11/30/23 00:55 460-00-470-130 1 Toluene-d8 (S)99 %11/30/23 00:55 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92699610 GSD.050 Sample:WSW-KR2 Lab ID:92699610004 Collected:11/20/23 14:45 Received:11/20/23 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV Benzene ND ug/L 11/30/23 01:13 71-43-20.50 1 Bromobenzene ND ug/L 11/30/23 01:13 108-86-10.50 1 Bromochloromethane ND ug/L 11/30/23 01:13 74-97-50.50 1 Bromodichloromethane ND ug/L 11/30/23 01:13 75-27-40.50 1 Bromoform ND ug/L 11/30/23 01:13 75-25-20.50 1 Bromomethane ND ug/L 11/30/23 01:13 74-83-95.0 1 n-Butylbenzene ND ug/L 11/30/23 01:13 104-51-80.50 1 sec-Butylbenzene ND ug/L 11/30/23 01:13 135-98-80.50 1 tert-Butylbenzene ND ug/L 11/30/23 01:13 98-06-60.50 1 Carbon tetrachloride ND ug/L 11/30/23 01:13 56-23-50.50 1 Chlorobenzene ND ug/L 11/30/23 01:13 108-90-70.50 1 Chloroethane ND ug/L 11/30/23 01:13 75-00-31.0 1 Chloroform ND ug/L 11/30/23 01:13 67-66-30.50 1 Chloromethane ND ug/L 11/30/23 01:13 74-87-31.0 1 2-Chlorotoluene ND ug/L 11/30/23 01:13 95-49-80.50 1 4-Chlorotoluene ND ug/L 11/30/23 01:13 106-43-40.50 1 1,2-Dibromo-3-chloropropane ND ug/L 11/30/23 01:13 96-12-81.0 1 Dibromochloromethane ND ug/L 11/30/23 01:13 124-48-10.50 1 1,2-Dibromoethane (EDB)ND ug/L 11/30/23 01:13 106-93-40.50 1 Dibromomethane ND ug/L 11/30/23 01:13 74-95-30.50 1 1,2-Dichlorobenzene ND ug/L 11/30/23 01:13 95-50-10.50 1 1,3-Dichlorobenzene ND ug/L 11/30/23 01:13 541-73-10.50 1 1,4-Dichlorobenzene ND ug/L 11/30/23 01:13 106-46-70.50 1 Dichlorodifluoromethane ND ug/L 11/30/23 01:13 75-71-80.50 1 1,1-Dichloroethane ND ug/L 11/30/23 01:13 75-34-30.50 1 1,2-Dichloroethane ND ug/L 11/30/23 01:13 107-06-20.50 1 1,1-Dichloroethene ND ug/L 11/30/23 01:13 75-35-40.50 1 cis-1,2-Dichloroethene ND ug/L 11/30/23 01:13 156-59-20.50 1 trans-1,2-Dichloroethene ND ug/L 11/30/23 01:13 156-60-50.50 1 1,2-Dichloropropane ND ug/L 11/30/23 01:13 78-87-50.50 1 1,3-Dichloropropane ND ug/L 11/30/23 01:13 142-28-90.50 1 2,2-Dichloropropane ND ug/L 11/30/23 01:13 594-20-70.50 1 1,1-Dichloropropene ND ug/L 11/30/23 01:13 563-58-60.50 1 cis-1,3-Dichloropropene ND ug/L 11/30/23 01:13 10061-01-50.50 1 trans-1,3-Dichloropropene ND ug/L 11/30/23 01:13 10061-02-60.50 1 Diisopropyl ether ND ug/L 11/30/23 01:13 108-20-30.50 1 Ethylbenzene ND ug/L 11/30/23 01:13 100-41-40.50 1 Hexachloro-1,3-butadiene ND ug/L 11/30/23 01:13 87-68-32.0 1 Isopropylbenzene (Cumene)ND ug/L 11/30/23 01:13 98-82-80.50 1 Methylene Chloride ND ug/L 11/30/23 01:13 75-09-22.0 1 Methyl-tert-butyl ether ND ug/L 11/30/23 01:13 1634-04-40.50 1 Naphthalene ND ug/L 11/30/23 01:13 91-20-32.0 1 n-Propylbenzene ND ug/L 11/30/23 01:13 103-65-10.50 1 Styrene ND ug/L 11/30/23 01:13 100-42-50.50 1 1,1,1,2-Tetrachloroethane ND ug/L 11/30/23 01:13 630-20-60.50 1 1,1,2,2-Tetrachloroethane ND ug/L 11/30/23 01:13 79-34-50.50 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92699610 GSD.050 Sample:WSW-KR2 Lab ID:92699610004 Collected:11/20/23 14:45 Received:11/20/23 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV Tetrachloroethene ND ug/L 11/30/23 01:13 127-18-40.50 1 Toluene ND ug/L 11/30/23 01:13 108-88-30.50 1 1,2,3-Trichlorobenzene ND ug/L 11/30/23 01:13 87-61-62.0 1 1,2,4-Trichlorobenzene ND ug/L 11/30/23 01:13 120-82-12.0 1 1,1,1-Trichloroethane ND ug/L 11/30/23 01:13 71-55-60.50 1 1,1,2-Trichloroethane ND ug/L 11/30/23 01:13 79-00-50.50 1 Trichloroethene ND ug/L 11/30/23 01:13 79-01-60.50 1 Trichlorofluoromethane ND ug/L 11/30/23 01:13 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 11/30/23 01:13 96-18-40.50 1 1,2,4-Trimethylbenzene ND ug/L 11/30/23 01:13 95-63-60.50 1 1,3,5-Trimethylbenzene ND ug/L 11/30/23 01:13 108-67-80.50 1 Vinyl chloride ND ug/L 11/30/23 01:13 75-01-41.0 1 m&p-Xylene ND ug/L 11/30/23 01:13 179601-23-11.0 1 o-Xylene ND ug/L 11/30/23 01:13 95-47-60.50 1 Surrogates 1,2-Dichloroethane-d4 (S)96 %11/30/23 01:13 17060-07-070-130 1 4-Bromofluorobenzene (S)96 %11/30/23 01:13 460-00-470-130 1 Toluene-d8 (S)100 %11/30/23 01:13 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92699610 GSD.050 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 815961 EPA 1664B EPA 1664B 1664 HEM, Oil and Grease Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92699610001, 92699610002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:4223338 Associated Lab Samples:92699610001, 92699610002 Matrix:Water Analyzed Oil and Grease mg/L ND 5.0 11/29/23 11:15 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 4223339LABORATORY CONTROL SAMPLE: LCSSpike Oil and Grease mg/L 33.440 84 78-114 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 4223340MATRIX SPIKE SAMPLE: MSSpike Result 92699247001 Oil and Grease mg/L 33.940 80 78-114ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92699247002 4223341SAMPLE DUPLICATE: Oil and Grease mg/L ND 30ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92699610 GSD.050 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 814729 EPA 3010A EPA 6010D 6010 MET Laboratory:Pace Analytical Services - Asheville Associated Lab Samples:92699610001, 92699610002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:4217869 Associated Lab Samples:92699610001, 92699610002 Matrix:Water Analyzed Lead ug/L ND 5.0 12/01/23 16:34 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 4217870LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 504500 101 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 4217871MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92699610001 4217872 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Lead ug/L 500 99 75-125101 2 20500ND495503 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92699610 GSD.050 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 815501 SM 6200B SM 6200B 6200B MSV Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92699610001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:4221380 Associated Lab Samples:92699610001 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 0.50 11/28/23 12:20 1,1,1-Trichloroethane ug/L ND 0.50 11/28/23 12:20 1,1,2,2-Tetrachloroethane ug/L ND 0.50 11/28/23 12:20 1,1,2-Trichloroethane ug/L ND 0.50 11/28/23 12:20 1,1-Dichloroethane ug/L ND 0.50 11/28/23 12:20 1,1-Dichloroethene ug/L ND 0.50 11/28/23 12:20 1,1-Dichloropropene ug/L ND 0.50 11/28/23 12:20 1,2,3-Trichlorobenzene ug/L ND 2.0 11/28/23 12:20 1,2,3-Trichloropropane ug/L ND 0.50 11/28/23 12:20 1,2,4-Trichlorobenzene ug/L ND 2.0 11/28/23 12:20 1,2,4-Trimethylbenzene ug/L ND 0.50 11/28/23 12:20 1,2-Dibromo-3-chloropropane ug/L ND 1.0 11/28/23 12:20 1,2-Dibromoethane (EDB)ug/L ND 0.50 11/28/23 12:20 1,2-Dichlorobenzene ug/L ND 0.50 11/28/23 12:20 1,2-Dichloroethane ug/L ND 0.50 11/28/23 12:20 1,2-Dichloropropane ug/L ND 0.50 11/28/23 12:20 1,3,5-Trimethylbenzene ug/L ND 0.50 11/28/23 12:20 1,3-Dichlorobenzene ug/L ND 0.50 11/28/23 12:20 1,3-Dichloropropane ug/L ND 0.50 11/28/23 12:20 1,4-Dichlorobenzene ug/L ND 0.50 11/28/23 12:20 2,2-Dichloropropane ug/L ND 0.50 11/28/23 12:20 2-Chlorotoluene ug/L ND 0.50 11/28/23 12:20 4-Chlorotoluene ug/L ND 0.50 11/28/23 12:20 Benzene ug/L ND 0.50 11/28/23 12:20 Bromobenzene ug/L ND 0.50 11/28/23 12:20 Bromochloromethane ug/L ND 0.50 11/28/23 12:20 Bromodichloromethane ug/L ND 0.50 11/28/23 12:20 Bromoform ug/L ND 0.50 11/28/23 12:20 Bromomethane ug/L ND 5.0 11/28/23 12:20 Carbon tetrachloride ug/L ND 0.50 11/28/23 12:20 Chlorobenzene ug/L ND 0.50 11/28/23 12:20 Chloroethane ug/L ND 1.0 11/28/23 12:20 Chloroform ug/L ND 0.50 11/28/23 12:20 Chloromethane ug/L ND 1.0 11/28/23 12:20 cis-1,2-Dichloroethene ug/L ND 0.50 11/28/23 12:20 cis-1,3-Dichloropropene ug/L ND 0.50 11/28/23 12:20 Dibromochloromethane ug/L ND 0.50 11/28/23 12:20 Dibromomethane ug/L ND 0.50 11/28/23 12:20 Dichlorodifluoromethane ug/L ND 0.50 11/28/23 12:20 Diisopropyl ether ug/L ND 0.50 11/28/23 12:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92699610 GSD.050 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:4221380 Associated Lab Samples:92699610001 Matrix:Water Analyzed Ethylbenzene ug/L ND 0.50 11/28/23 12:20 Hexachloro-1,3-butadiene ug/L ND 2.0 11/28/23 12:20 Isopropylbenzene (Cumene)ug/L ND 0.50 11/28/23 12:20 m&p-Xylene ug/L ND 1.0 11/28/23 12:20 Methyl-tert-butyl ether ug/L ND 0.50 11/28/23 12:20 Methylene Chloride ug/L ND 2.0 11/28/23 12:20 n-Butylbenzene ug/L ND 0.50 11/28/23 12:20 n-Propylbenzene ug/L ND 0.50 11/28/23 12:20 Naphthalene ug/L ND 2.0 11/28/23 12:20 o-Xylene ug/L ND 0.50 11/28/23 12:20 sec-Butylbenzene ug/L ND 0.50 11/28/23 12:20 Styrene ug/L ND 0.50 11/28/23 12:20 tert-Butylbenzene ug/L ND 0.50 11/28/23 12:20 Tetrachloroethene ug/L ND 0.50 11/28/23 12:20 Toluene ug/L ND 0.50 11/28/23 12:20 trans-1,2-Dichloroethene ug/L ND 0.50 11/28/23 12:20 trans-1,3-Dichloropropene ug/L ND 0.50 11/28/23 12:20 Trichloroethene ug/L ND 0.50 11/28/23 12:20 Trichlorofluoromethane ug/L ND 1.0 11/28/23 12:20 Vinyl chloride ug/L ND 1.0 11/28/23 12:20 1,2-Dichloroethane-d4 (S)%95 70-130 11/28/23 12:20 4-Bromofluorobenzene (S)%97 70-130 11/28/23 12:20 Toluene-d8 (S)%98 70-130 11/28/23 12:20 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 4221381LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 19.420 97 60-140 1,1,1-Trichloroethane ug/L 17.620 88 60-140 1,1,2,2-Tetrachloroethane ug/L 19.120 96 60-140 1,1,2-Trichloroethane ug/L 19.120 95 60-140 1,1-Dichloroethane ug/L 17.020 85 60-140 1,1-Dichloroethene ug/L 18.320 91 60-140 1,1-Dichloropropene ug/L 18.620 93 60-140 1,2,3-Trichlorobenzene ug/L 19.020 95 60-140 1,2,3-Trichloropropane ug/L 18.220 91 60-140 1,2,4-Trichlorobenzene ug/L 18.320 91 60-140 1,2,4-Trimethylbenzene ug/L 18.320 92 60-140 1,2-Dibromo-3-chloropropane ug/L 19.020 95 60-140 1,2-Dibromoethane (EDB)ug/L 19.020 95 60-140 1,2-Dichlorobenzene ug/L 18.820 94 60-140 1,2-Dichloroethane ug/L 17.620 88 60-140 1,2-Dichloropropane ug/L 16.420 82 60-140 1,3,5-Trimethylbenzene ug/L 18.620 93 60-140 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92699610 GSD.050 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 4221381LABORATORY CONTROL SAMPLE: LCSSpike 1,3-Dichlorobenzene ug/L 18.920 94 60-140 1,3-Dichloropropane ug/L 17.720 89 60-140 1,4-Dichlorobenzene ug/L 18.120 91 60-140 2,2-Dichloropropane ug/L 17.120 85 60-140 2-Chlorotoluene ug/L 18.320 92 60-140 4-Chlorotoluene ug/L 18.320 92 60-140 Benzene ug/L 17.820 89 60-140 Bromobenzene ug/L 17.820 89 60-140 Bromochloromethane ug/L 18.520 92 60-140 Bromodichloromethane ug/L 16.720 83 60-140 Bromoform ug/L 19.520 97 60-140 Bromomethane ug/L 17.420 87 60-140 Carbon tetrachloride ug/L 18.820 94 60-140 Chlorobenzene ug/L 18.220 91 60-140 Chloroethane ug/L 17.920 89 60-140 Chloroform ug/L 17.320 86 60-140 Chloromethane ug/L 18.020 90 60-140 cis-1,2-Dichloroethene ug/L 17.220 86 60-140 cis-1,3-Dichloropropene ug/L 16.720 84 60-140 Dibromochloromethane ug/L 18.520 93 60-140 Dibromomethane ug/L 20.120 101 60-140 Dichlorodifluoromethane ug/L 22.220 111 60-140 Diisopropyl ether ug/L 16.020 80 60-140 Ethylbenzene ug/L 17.720 89 60-140 Hexachloro-1,3-butadiene ug/L 19.120 95 60-140 Isopropylbenzene (Cumene)ug/L 18.520 93 60-140 m&p-Xylene ug/L 35.240 88 60-140 Methyl-tert-butyl ether ug/L 16.220 81 60-140 Methylene Chloride ug/L 16.920 84 60-140 n-Butylbenzene ug/L 18.320 92 60-140 n-Propylbenzene ug/L 17.720 89 60-140 Naphthalene ug/L 19.320 96 60-140 o-Xylene ug/L 17.920 90 60-140 sec-Butylbenzene ug/L 18.120 91 60-140 Styrene ug/L 18.620 93 60-140 tert-Butylbenzene ug/L 15.220 76 60-140 Tetrachloroethene ug/L 18.320 91 60-140 Toluene ug/L 17.620 88 60-140 trans-1,2-Dichloroethene ug/L 17.020 85 60-140 trans-1,3-Dichloropropene ug/L 17.420 87 60-140 Trichloroethene ug/L 18.120 91 60-140 Trichlorofluoromethane ug/L 18.620 93 60-140 Vinyl chloride ug/L 17.220 86 60-140 1,2-Dichloroethane-d4 (S)%91 70-130 4-Bromofluorobenzene (S)%98 70-130 Toluene-d8 (S)%97 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92699610 GSD.050 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 4221382MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92699343007 4221383 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 20 116 60-14095 19 3020ND23.1 19.0 1,1,1-Trichloroethane ug/L 20 109 60-14091 18 3020ND21.8 18.2 1,1,2,2-Tetrachloroethane ug/L 20 112 60-14091 21 3020ND22.5 18.2 1,1,2-Trichloroethane ug/L 20 114 60-14092 21 3020ND22.7 18.3 1,1-Dichloroethane ug/L 20 103 60-14087 17 3020ND20.7 17.3 1,1-Dichloroethene ug/L 20 114 60-14096 17 30200.41J 23.2 19.6 1,1-Dichloropropene ug/L 20 114 60-14095 19 3020ND22.9 18.9 1,2,3-Trichlorobenzene ug/L 20 107 60-14092 15 3020ND21.3 18.3 1,2,3-Trichloropropane ug/L 20 105 60-14087 18 3020ND20.9 17.4 1,2,4-Trichlorobenzene ug/L 20 104 60-14087 17 3020ND20.7 17.5 1,2,4-Trimethylbenzene ug/L 20 120 60-14093 25 3020ND23.9 18.7 1,2-Dibromo-3- chloropropane ug/L 20 110 60-14089 21 3020ND22.0 17.8 1,2-Dibromoethane (EDB)ug/L 20 115 60-14093 22 3020ND23.1 18.6 1,2-Dichlorobenzene ug/L 20 110 60-14092 18 3020ND22.0 18.3 1,2-Dichloroethane ug/L 20 95 60-14082 16 30200.13J 19.2 16.4 1,2-Dichloropropane ug/L 20 97 60-14082 16 3020ND19.4 16.5 1,3,5-Trimethylbenzene ug/L 20 112 60-14095 17 3020ND22.5 19.0 1,3-Dichlorobenzene ug/L 20 111 60-14094 17 3020ND22.2 18.8 1,3-Dichloropropane ug/L 20 109 60-14088 21 3020ND21.7 17.6 1,4-Dichlorobenzene ug/L 20 106 60-14089 17 3020ND21.1 17.7 2,2-Dichloropropane ug/L 20 110 60-14088 23 3020ND22.1 17.6 2-Chlorotoluene ug/L 20 106 60-14088 18 3020ND21.1 17.6 4-Chlorotoluene ug/L 20 108 60-14093 15 3020ND21.6 18.6 Benzene ug/L 20 111 60-14089 22 3020ND22.2 17.8 Bromobenzene ug/L 20 105 60-14091 15 3020ND21.1 18.2 Bromochloromethane ug/L 20 108 60-14087 21 3020ND21.6 17.5 Bromodichloromethane ug/L 20 99 60-14082 19 3020ND19.9 16.3 Bromoform ug/L 20 114 60-14092 21 3020ND22.9 18.5 Bromomethane ug/L 20 106 60-14090 16 3020ND21.2 18.0 Carbon tetrachloride ug/L 20 118 60-14098 16 30203.0 26.7 22.6 Chlorobenzene ug/L 20 112 60-14089 23 3020ND22.3 17.8 Chloroethane ug/L 20 113 60-14091 21 3020ND22.5 18.3 Chloroform ug/L 20 106 60-14086 17 30204.4 25.6 21.6 Chloromethane ug/L 20 108 60-14091 17 3020ND21.5 18.1 cis-1,2-Dichloroethene ug/L 20 103 60-14086 18 30200.11J 20.7 17.4 cis-1,3-Dichloropropene ug/L 20 105 60-14086 20 3020ND21.1 17.2 Dibromochloromethane ug/L 20 112 60-14091 21 3020ND22.3 18.1 Dibromomethane ug/L 20 117 60-14097 19 3020ND23.4 19.4 Dichlorodifluoromethane ug/L 20 139 60-140112 22 3020ND27.9 22.4 Diisopropyl ether ug/L 20 95 60-14081 16 3020ND19.0 16.1 Ethylbenzene ug/L 20 112 60-14089 22 3020ND22.4 17.9 Hexachloro-1,3-butadiene ug/L 20 114 60-14098 15 3020ND22.7 19.5 Isopropylbenzene (Cumene) ug/L 20 116 60-14093 21 3020ND23.1 18.7 m&p-Xylene ug/L 40 112 60-14089 22 30400.13J 44.8 35.8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92699610 GSD.050 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 4221382MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92699343007 4221383 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Methyl-tert-butyl ether ug/L 20 93 60-14076 20 30200.083J 18.7 15.3 Methylene Chloride ug/L 20 99 60-14085 15 3020ND19.8 17.0 n-Butylbenzene ug/L 20 109 60-14094 15 3020ND21.8 18.8 n-Propylbenzene ug/L 20 108 60-14091 17 3020ND21.7 18.3 Naphthalene ug/L 20 115 60-14092 22 3020ND22.9 18.4 o-Xylene ug/L 20 111 60-14090 21 3020ND22.2 18.0 sec-Butylbenzene ug/L 20 111 60-14094 17 3020ND22.1 18.7 Styrene ug/L 20 115 60-14092 22 3020ND23.0 18.5 tert-Butylbenzene ug/L 20 94 60-14079 17 3020ND18.8 15.9 Tetrachloroethene ug/L 20 110 60-14093 10 302012.9 34.9 31.6 Toluene ug/L 20 111 60-14089 22 3020ND22.2 17.8 trans-1,2-Dichloroethene ug/L 20 106 60-14089 17 3020ND21.3 17.9 trans-1,3-Dichloropropene ug/L 20 107 60-14087 20 3020ND21.3 17.5 Trichloroethene ug/L 20 118 60-14096 21 3020ND23.8 19.3 Trichlorofluoromethane ug/L 20 118 60-14095 21 3020ND23.5 19.0 Vinyl chloride ug/L 20 110 60-14089 20 3020ND22.0 17.9 1,2-Dichloroethane-d4 (S)%88 70-13088 4-Bromofluorobenzene (S)%99 70-13098 Toluene-d8 (S)%98 70-13097 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92699610 GSD.050 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 815503 SM 6200B SM 6200B 6200B MSV Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92699610002, 92699610003, 92699610004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:4221402 Associated Lab Samples:92699610002, 92699610003, 92699610004 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 0.50 11/30/23 00:19 1,1,1-Trichloroethane ug/L ND 0.50 11/30/23 00:19 1,1,2,2-Tetrachloroethane ug/L ND 0.50 11/30/23 00:19 1,1,2-Trichloroethane ug/L ND 0.50 11/30/23 00:19 1,1-Dichloroethane ug/L ND 0.50 11/30/23 00:19 1,1-Dichloroethene ug/L ND 0.50 11/30/23 00:19 1,1-Dichloropropene ug/L ND 0.50 11/30/23 00:19 1,2,3-Trichlorobenzene ug/L ND 2.0 11/30/23 00:19 1,2,3-Trichloropropane ug/L ND 0.50 11/30/23 00:19 1,2,4-Trichlorobenzene ug/L ND 2.0 11/30/23 00:19 1,2,4-Trimethylbenzene ug/L ND 0.50 11/30/23 00:19 1,2-Dibromo-3-chloropropane ug/L ND 1.0 11/30/23 00:19 1,2-Dibromoethane (EDB)ug/L ND 0.50 11/30/23 00:19 1,2-Dichlorobenzene ug/L ND 0.50 11/30/23 00:19 1,2-Dichloroethane ug/L ND 0.50 11/30/23 00:19 1,2-Dichloropropane ug/L ND 0.50 11/30/23 00:19 1,3,5-Trimethylbenzene ug/L ND 0.50 11/30/23 00:19 1,3-Dichlorobenzene ug/L ND 0.50 11/30/23 00:19 1,3-Dichloropropane ug/L ND 0.50 11/30/23 00:19 1,4-Dichlorobenzene ug/L ND 0.50 11/30/23 00:19 2,2-Dichloropropane ug/L ND 0.50 11/30/23 00:19 2-Chlorotoluene ug/L ND 0.50 11/30/23 00:19 4-Chlorotoluene ug/L ND 0.50 11/30/23 00:19 Benzene ug/L ND 0.50 11/30/23 00:19 Bromobenzene ug/L ND 0.50 11/30/23 00:19 Bromochloromethane ug/L ND 0.50 11/30/23 00:19 Bromodichloromethane ug/L ND 0.50 11/30/23 00:19 Bromoform ug/L ND 0.50 11/30/23 00:19 Bromomethane ug/L ND 5.0 11/30/23 00:19 Carbon tetrachloride ug/L ND 0.50 11/30/23 00:19 Chlorobenzene ug/L ND 0.50 11/30/23 00:19 Chloroethane ug/L ND 1.0 11/30/23 00:19 Chloroform ug/L ND 0.50 11/30/23 00:19 Chloromethane ug/L ND 1.0 11/30/23 00:19 cis-1,2-Dichloroethene ug/L ND 0.50 11/30/23 00:19 cis-1,3-Dichloropropene ug/L ND 0.50 11/30/23 00:19 Dibromochloromethane ug/L ND 0.50 11/30/23 00:19 Dibromomethane ug/L ND 0.50 11/30/23 00:19 Dichlorodifluoromethane ug/L ND 0.50 11/30/23 00:19 Diisopropyl ether ug/L ND 0.50 11/30/23 00:19 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92699610 GSD.050 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:4221402 Associated Lab Samples:92699610002, 92699610003, 92699610004 Matrix:Water Analyzed Ethylbenzene ug/L ND 0.50 11/30/23 00:19 Hexachloro-1,3-butadiene ug/L ND 2.0 11/30/23 00:19 Isopropylbenzene (Cumene)ug/L ND 0.50 11/30/23 00:19 m&p-Xylene ug/L ND 1.0 11/30/23 00:19 Methyl-tert-butyl ether ug/L ND 0.50 11/30/23 00:19 Methylene Chloride ug/L ND 2.0 11/30/23 00:19 n-Butylbenzene ug/L ND 0.50 11/30/23 00:19 n-Propylbenzene ug/L ND 0.50 11/30/23 00:19 Naphthalene ug/L ND 2.0 11/30/23 00:19 o-Xylene ug/L ND 0.50 11/30/23 00:19 sec-Butylbenzene ug/L ND 0.50 11/30/23 00:19 Styrene ug/L ND 0.50 11/30/23 00:19 tert-Butylbenzene ug/L ND 0.50 11/30/23 00:19 Tetrachloroethene ug/L ND 0.50 11/30/23 00:19 Toluene ug/L ND 0.50 11/30/23 00:19 trans-1,2-Dichloroethene ug/L ND 0.50 11/30/23 00:19 trans-1,3-Dichloropropene ug/L ND 0.50 11/30/23 00:19 Trichloroethene ug/L ND 0.50 11/30/23 00:19 Trichlorofluoromethane ug/L ND 1.0 11/30/23 00:19 Vinyl chloride ug/L ND 1.0 11/30/23 00:19 1,2-Dichloroethane-d4 (S)%95 70-130 11/30/23 00:19 4-Bromofluorobenzene (S)%96 70-130 11/30/23 00:19 Toluene-d8 (S)%98 70-130 11/30/23 00:19 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 4221403LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 21.620 108 60-140 1,1,1-Trichloroethane ug/L 21.220 106 60-140 1,1,2,2-Tetrachloroethane ug/L 21.720 109 60-140 1,1,2-Trichloroethane ug/L 21.620 108 60-140 1,1-Dichloroethane ug/L 20.820 104 60-140 1,1-Dichloroethene ug/L 22.220 111 60-140 1,1-Dichloropropene ug/L 22.020 110 60-140 1,2,3-Trichlorobenzene ug/L 23.120 116 60-140 1,2,3-Trichloropropane ug/L 20.820 104 60-140 1,2,4-Trichlorobenzene ug/L 21.020 105 60-140 1,2,4-Trimethylbenzene ug/L 20.920 105 60-140 1,2-Dibromo-3-chloropropane ug/L 20.820 104 60-140 1,2-Dibromoethane (EDB)ug/L 22.120 111 60-140 1,2-Dichlorobenzene ug/L 20.820 104 60-140 1,2-Dichloroethane ug/L 20.820 104 60-140 1,2-Dichloropropane ug/L 21.520 108 60-140 1,3,5-Trimethylbenzene ug/L 20.820 104 60-140 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92699610 GSD.050 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 4221403LABORATORY CONTROL SAMPLE: LCSSpike 1,3-Dichlorobenzene ug/L 20.720 104 60-140 1,3-Dichloropropane ug/L 20.420 102 60-140 1,4-Dichlorobenzene ug/L 20.420 102 60-140 2,2-Dichloropropane ug/L 19.220 96 60-140 2-Chlorotoluene ug/L 20.220 101 60-140 4-Chlorotoluene ug/L 20.520 103 60-140 Benzene ug/L 20.920 105 60-140 Bromobenzene ug/L 20.520 102 60-140 Bromochloromethane ug/L 21.320 106 60-140 Bromodichloromethane ug/L 20.620 103 60-140 Bromoform ug/L 20.720 104 60-140 Bromomethane ug/L 19.720 99 60-140 Carbon tetrachloride ug/L 20.820 104 60-140 Chlorobenzene ug/L 20.720 104 60-140 Chloroethane ug/L 22.320 112 60-140 Chloroform ug/L 20.520 102 60-140 Chloromethane ug/L 21.720 108 60-140 cis-1,2-Dichloroethene ug/L 20.920 104 60-140 cis-1,3-Dichloropropene ug/L 20.520 102 60-140 Dibromochloromethane ug/L 21.420 107 60-140 Dibromomethane ug/L 21.120 105 60-140 Dichlorodifluoromethane ug/L 19.620 98 60-140 Diisopropyl ether ug/L 20.020 100 60-140 Ethylbenzene ug/L 20.420 102 60-140 Hexachloro-1,3-butadiene ug/L 19.620 98 60-140 Isopropylbenzene (Cumene)ug/L 20.920 104 60-140 m&p-Xylene ug/L 41.540 104 60-140 Methyl-tert-butyl ether ug/L 20.020 100 60-140 Methylene Chloride ug/L 20.220 101 60-140 n-Butylbenzene ug/L 20.520 103 60-140 n-Propylbenzene ug/L 19.920 99 60-140 Naphthalene ug/L 23.120 116 60-140 o-Xylene ug/L 20.720 104 60-140 sec-Butylbenzene ug/L 20.120 100 60-140 Styrene ug/L 21.720 108 60-140 tert-Butylbenzene ug/L 16.720 83 60-140 Tetrachloroethene ug/L 20.220 101 60-140 Toluene ug/L 20.320 102 60-140 trans-1,2-Dichloroethene ug/L 21.420 107 60-140 trans-1,3-Dichloropropene ug/L 20.920 104 60-140 Trichloroethene ug/L 21.120 106 60-140 Trichlorofluoromethane ug/L 21.220 106 60-140 Vinyl chloride ug/L 19.420 97 60-140 1,2-Dichloroethane-d4 (S)%100 70-130 4-Bromofluorobenzene (S)%100 70-130 Toluene-d8 (S)%101 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92699610 GSD.050 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 4221404MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92699610002 4221405 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 20 115 60-140112 3 3020ND23.0 22.3 1,1,1-Trichloroethane ug/L 20 118 60-140114 3 3020ND23.5 22.8 1,1,2,2-Tetrachloroethane ug/L 20 112 60-140110 2 3020ND22.4 22.0 1,1,2-Trichloroethane ug/L 20 113 60-140110 2 3020ND22.6 22.0 1,1-Dichloroethane ug/L 20 112 60-140109 2 3020ND22.3 21.8 1,1-Dichloroethene ug/L 20 124 60-140116 6 3020ND24.8 23.2 1,1-Dichloropropene ug/L 20 128 60-140123 4 3020ND25.5 24.6 1,2,3-Trichlorobenzene ug/L 20 115 60-140109 6 3020ND23.1 21.8 1,2,3-Trichloropropane ug/L 20 108 60-140104 3 3020ND21.5 20.9 1,2,4-Trichlorobenzene ug/L 20 114 60-140107 6 3020ND22.7 21.5 1,2,4-Trimethylbenzene ug/L 20 116 60-140111 5 3020ND23.2 22.1 1,2-Dibromo-3- chloropropane ug/L 20 106 60-140104 2 3020ND21.1 20.7 1,2-Dibromoethane (EDB)ug/L 20 113 60-140111 1 3020ND22.6 22.3 1,2-Dichlorobenzene ug/L 20 112 60-140107 4 3020ND22.3 21.4 1,2-Dichloroethane ug/L 20 112 60-140109 3 3020ND22.4 21.7 1,2-Dichloropropane ug/L 20 116 60-140111 4 3020ND23.2 22.3 1,3,5-Trimethylbenzene ug/L 20 115 60-140110 4 3020ND23.0 22.1 1,3-Dichlorobenzene ug/L 20 112 60-140107 5 3020ND22.5 21.5 1,3-Dichloropropane ug/L 20 107 60-140106 1 3020ND21.4 21.2 1,4-Dichlorobenzene ug/L 20 110 60-140106 4 3020ND21.9 21.2 2,2-Dichloropropane ug/L 20 117 60-140113 3 3020ND23.5 22.7 2-Chlorotoluene ug/L 20 111 60-140108 3 3020ND22.2 21.6 4-Chlorotoluene ug/L 20 113 60-140109 4 3020ND22.6 21.7 Benzene ug/L 20 112 60-140109 2 3020ND22.3 21.8 Bromobenzene ug/L 20 111 60-140106 4 3020ND22.1 21.3 Bromochloromethane ug/L 20 118 60-140111 6 3020ND23.5 22.2 Bromodichloromethane ug/L 20 109 60-140107 2 3020ND21.8 21.4 Bromoform ug/L 20 107 60-140106 1 3020ND21.4 21.1 Bromomethane ug/L 20 105 60-140101 4 3020ND21.1 20.3 Carbon tetrachloride ug/L 20 117 60-140113 3 3020ND23.4 22.6 Chlorobenzene ug/L 20 111 60-140109 2 3020ND22.3 21.8 Chloroethane ug/L 20 117 60-140110 6 3020ND23.4 22.0 Chloroform ug/L 20 114 60-140104 9 3020ND22.8 20.8 Chloromethane ug/L 20 100 60-14096 4 3020ND19.9 19.2 cis-1,2-Dichloroethene ug/L 20 112 60-140110 3 3020ND22.5 21.9 cis-1,3-Dichloropropene ug/L 20 108 60-140107 2 3020ND21.7 21.3 Dibromochloromethane ug/L 20 111 60-140108 3 3020ND22.2 21.6 Dibromomethane ug/L 20 111 60-140108 3 3020ND22.2 21.5 Dichlorodifluoromethane ug/L 20 79 60-14075 5 3020ND15.8 15.0 Diisopropyl ether ug/L 20 106 60-140103 4 3020ND21.3 20.5 Ethylbenzene ug/L 20 110 60-140109 1 3020ND22.1 21.8 Hexachloro-1,3-butadiene ug/L 20 118 60-140116 2 3020ND23.6 23.2 Isopropylbenzene (Cumene) ug/L 20 115 60-140112 2 3020ND23.0 22.4 m&p-Xylene ug/L 40 113 60-140110 2 3040ND45.1 44.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92699610 GSD.050 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 4221404MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92699610002 4221405 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Methyl-tert-butyl ether ug/L 20 105 60-140103 3 3020ND21.1 20.5 Methylene Chloride ug/L 20 105 60-140101 3 3020ND21.0 20.3 n-Butylbenzene ug/L 20 123 60-140115 7 3020ND24.7 22.9 n-Propylbenzene ug/L 20 112 60-140107 4 3020ND22.4 21.5 Naphthalene ug/L 20 113 60-140111 2 3020ND22.5 22.2 o-Xylene ug/L 20 110 60-140108 2 3020ND22.0 21.6 sec-Butylbenzene ug/L 20 116 60-140111 5 3020ND23.3 22.2 Styrene ug/L 20 115 60-140113 2 3020ND23.0 22.5 tert-Butylbenzene ug/L 20 93 60-14090 4 3020ND18.7 18.0 Tetrachloroethene ug/L 20 111 60-140109 2 3020ND22.3 21.8 Toluene ug/L 20 110 60-140107 3 3020ND22.0 21.4 trans-1,2-Dichloroethene ug/L 20 120 60-140115 5 3020ND24.1 22.9 trans-1,3-Dichloropropene ug/L 20 111 60-140110 1 3020ND22.2 22.0 Trichloroethene ug/L 20 117 60-140112 4 3020ND23.4 22.4 Trichlorofluoromethane ug/L 20 118 60-140114 4 3020ND23.7 22.7 Vinyl chloride ug/L 20 97 60-14093 4 3020ND19.3 18.5 1,2-Dichloroethane-d4 (S)%101 70-13099 4-Bromofluorobenzene (S)%99 70-130101 Toluene-d8 (S)%99 70-13099 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92699610 GSD.050 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 815039 SM 2540D-2015 SM 2540D-2015 2540D Total Suspended Solids Laboratory:Pace Analytical Services - Asheville Associated Lab Samples:92699610001, 92699610002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:4219296 Associated Lab Samples:92699610001, 92699610002 Matrix:Water Analyzed Total Suspended Solids mg/L ND 2.5 11/22/23 10:44 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 4219297LABORATORY CONTROL SAMPLE: LCSSpike Total Suspended Solids mg/L 244250 97 90-110 Parameter Units Dup Result Max RPD QualifiersRPDResult 92699514003 4219489SAMPLE DUPLICATE: Total Suspended Solids mg/L 6500 20 255300 Parameter Units Dup Result Max RPD QualifiersRPDResult 92699695001 4219490SAMPLE DUPLICATE: Total Suspended Solids mg/L 274 7 25294 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92699610 GSD.050 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 815850 EPA 420.4 Rev 1.0 1993 EPA 420.4 Rev 1.0 1993 420.4 Phenolics Laboratory:Pace Analytical Services - Asheville Associated Lab Samples:92699610001, 92699610002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:4222904 Associated Lab Samples:92699610001, 92699610002 Matrix:Water Analyzed Phenolics, Total Recoverable mg/L ND 0.020 11/29/23 15:40 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 4222905LABORATORY CONTROL SAMPLE: LCSSpike Phenolics, Total Recoverable mg/L 0.0510.05 102 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 4222906MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92699266001 4222907 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Phenolics, Total Recoverable mg/L M10.05 -205 90-110-200 3 100.050.17 0.068 0.071 Parameter Units MS Result % Rec Limits Qual% RecConc. 4222908MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 35841839002 4222909 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Phenolics, Total Recoverable mg/L M1,R10.05 -61 90-110-40 12 100.050.12 0.085 0.096 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 31 #=QL# QUALIFIERS Pace Project No.: Project: 92699610 GSD.050 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 RPD value was outside control limits.R1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 31 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92699610 GSD.050 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92699610001 815961INFLUENTEPA 1664B 92699610002 815961EFFLUENTEPA 1664B 92699610001 814729 814816INFLUENTEPA 3010A EPA 6010D 92699610002 814729 814816EFFLUENTEPA 3010A EPA 6010D 92699610001 815501INFLUENTSM 6200B 92699610002 815503EFFLUENTSM 6200B 92699610003 815503WSW-16 SM 6200B 92699610004 815503WSW-KR2 SM 6200B 92699610001 815039INFLUENTSM 2540D-2015 92699610002 815039EFFLUENTSM 2540D-2015 92699610001 815850 816094INFLUENTEPA 420.4 Rev 1.0 1993 EPA 420.4 Rev 1.0 1993 92699610002 815850 816094EFFLUENTEPA 420.4 Rev 1.0 1993 EPA 420.4 Rev 1.0 1993 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 10:54 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 31 Page 29 of 31 Page 30 of 31 Page 31 of 31   Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.   3/18/2024 Hart & Hickman (Charlotte) Steve Libbey 2923 South Tryon St. Ste 100 Charlotte, NC, 28203 Ref: Analytical Testing Revised Lab Report Number: 24-038-0014 Client Project Description: GSD.050 Dear Steve Libbey: Waypoint Analytical, LLC (Charlotte) received sample(s) on 2/7/2024 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Angela D Overcash Senior Project Manager Page 1 of 36 Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date 07/31/202437735State ProgramNorth Carolina 12/31/2024402State ProgramNorth Carolina 07/31/202499012State ProgramSouth Carolina 12/31/202399012State ProgramSouth Carolina Page 1 of 1 00016/24-038-0014 Page 2 of 36 Report Number: Sample Summary Table Client Project Description: 24-038-0014 GSD.050 Lab No Client Sample ID Matrix Date Collected Date Received 02/06/2024 11:30Aqueous 96058 WSW-KR2 02/07/2024 14:25 02/06/2024 11:45Aqueous 96059 WSW-16 02/07/2024 14:25 02/06/2024 12:00Aqueous 96060 MW-3R 02/07/2024 14:25 02/06/2024 12:15Aqueous 96061 MW-5R 02/07/2024 14:25 Page 3 of 36 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 24-038-0014 Report Limit Project:GSD.050 V 96060MW-3R 10.6 02/13/2024 18:056200BDi-Isopropyl Ether (DIPE)µg/L 0.500 616 02/15/2024 17:086200BMethyl tert-butyl ether (MTBE)µg/L 100 Page 4 of 36   Client: Hart & Hickman (Charlotte) CASE NARRATIVE Project: GSD.050 Lab Report Number: 24-038-0014 Date: 3/18/2024 Report Comments Revised Report: Revision 1 Samples have been updated to report to the MQL. Volatile Organic Compounds - GC/MS Method 6200B Analyte: Bromomethane QC Batch No: V44813 This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for a low bias. Analyte: 1,2,3-Trichlorobenzene QC Batch No: V44813/V43554 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: 1,2-Dibromo-3-chloropropane QC Batch No: V44813/V43554 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: Ethanol QC Batch No: V44814/V43554 This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for a low bias. Page 5 of 36 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-038-0014 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Steve Libbey Charlotte Received : 02/07/2024 GSD.050 Revised Report Date : 03/18/2024 Original Report Date : 02/22/2024 Sample ID : Lab No : Sampled:WSW-KR2 96058 Matrix: 2/6/2024 11:30 Aqueous Analytical Method: Prep Method: Test Results Units MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V43554 02/13/24 09:00 <10.0 µg/L 10.0Acetone 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500Benzene 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500Bromobenzene 1 02/13/24 17:16 V44939ENM <1.00 µg/L 1.00Bromochloromethane 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500Bromodichloromethane 1 02/13/24 17:16 V44939ENM <5.00 µg/L 5.00Bromoform 1 02/13/24 17:16 V44939ENM <1.00 µg/L 1.00Bromomethane 1 02/13/24 17:16 V44942ENM <0.500 µg/L 0.500n-Butylbenzene 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500sec-Butyl benzene 1 02/13/24 17:16 V44939ENM <2.00 µg/L 2.00tert-Butyl benzene 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500Carbon Tetrachloride 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500Chlorobenzene 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500Chlorodibromomethane 1 02/13/24 17:16 V44939ENM <1.00 µg/L 1.00Chloroethane 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500Chloroform 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500Chloromethane 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.5002-Chlorotoluene 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.5004-Chlorotoluene 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 02/13/24 17:16 V44939ENM <2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.5001,2-Dibromoethane 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500Dibromomethane 1 02/13/24 17:16 V44939ENM Qualifiers/ Definitions Beyond holding timeHDilution FactorDF Method Quantitation LimitMQL Page 6 of 36 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-038-0014 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Steve Libbey Charlotte Received : 02/07/2024 GSD.050 Revised Report Date : 03/18/2024 Original Report Date : 02/22/2024 Sample ID : Lab No : Sampled:WSW-KR2 96058 Matrix: 2/6/2024 11:30 Aqueous Analytical Method: Prep Method: Test Results Units MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V43554 02/13/24 09:00 <0.500 µg/L 0.5001,2-Dichlorobenzene 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.5001,3-Dichlorobenzene 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.5001,4-Dichlorobenzene 1 02/13/24 17:16 V44939ENM <5.00 µg/L 5.00Dichlorodifluoromethane 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.5001,1-Dichloroethane 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.5001,2-Dichloroethane 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.5001,1-Dichloroethene 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500cis-1,2-Dichloroethene 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500trans-1,2-Dichloroethene 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.5001,2-Dichloropropane 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.5001,3-Dichloropropane 1 02/13/24 17:16 V44939ENM <2.00 µg/L 2.002,2-Dichloropropane 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.5001,1-Dichloropropene 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500cis-1,3-Dichloropropene 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500trans-1,3-Dichloropropene 1 02/13/24 17:16 V44939ENM <200 µg/L 200Ethanol 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500Ethylbenzene 1 02/13/24 17:16 V44939ENM <3.00 µg/L 3.00Hexachlorobutadiene 1 02/13/24 17:16 V44939ENM <1.00 µg/L 1.002-Hexanone 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500Isopropylbenzene 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.5004-Isopropyl toluene 1 02/13/24 17:16 V44939ENM <5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 02/13/24 17:16 V44939ENM Qualifiers/ Definitions Beyond holding timeHDilution FactorDF Method Quantitation LimitMQL Page 7 of 36 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-038-0014 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Steve Libbey Charlotte Received : 02/07/2024 GSD.050 Revised Report Date : 03/18/2024 Original Report Date : 02/22/2024 Sample ID : Lab No : Sampled:WSW-KR2 96058 Matrix: 2/6/2024 11:30 Aqueous Analytical Method: Prep Method: Test Results Units MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V43554 02/13/24 09:00 <1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 02/13/24 17:16 V44939ENM <1.00 µg/L 1.004-Methyl-2-Pentanone 1 02/13/24 17:16 V44939ENM <2.00 µg/L 2.00Methylene Chloride 1 02/13/24 17:16 V44939ENM <1.00 µg/L 1.00Naphthalene 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500n-Propylbenzene 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500Styrene 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500Tetrachloroethene 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500Toluene 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.5001,1,1-Trichloroethane 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.5001,1,2-Trichloroethane 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500Trichloroethene 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500Trichlorofluoromethane 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.5001,2,3-Trichloropropane 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 02/13/24 17:16 V44939ENM <5.00 µg/L 5.00Vinyl Acetate 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500Vinyl Chloride 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500o-Xylene 1 02/13/24 17:16 V44939ENM Qualifiers/ Definitions Beyond holding timeHDilution FactorDF Method Quantitation LimitMQL Page 8 of 36 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-038-0014 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Steve Libbey Charlotte Received : 02/07/2024 GSD.050 Revised Report Date : 03/18/2024 Original Report Date : 02/22/2024 Sample ID : Lab No : Sampled:WSW-KR2 96058 Matrix: 2/6/2024 11:30 Aqueous Analytical Method: Prep Method: Test Results Units MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V43554 02/13/24 09:00 <1.00 µg/L 1.00m,p-Xylene 1 02/13/24 17:16 V44939ENM <0.500 µg/L 0.500Xylene (Total)1 02/13/24 17:16 V44939 Surrogate: 4-Bromofluorobenzene 93.4 Limits: 70-130%02/13/24 17:161 ENM V44939 Surrogate: Dibromofluoromethane 96.4 Limits: 70-130%02/13/24 17:161 ENM V44939 Surrogate: 1,2-Dichloroethane - d4 93.6 Limits: 70-130%02/13/24 17:161 ENM V44939 Surrogate: Toluene-d8 102 Limits: 70-130%02/13/24 17:161 ENM V44939 Surrogate: 4-Bromofluorobenzene 93.4 Limits: 70-130%02/13/24 17:161 ENM V44942 Surrogate: Dibromofluoromethane 96.4 Limits: 70-130%02/13/24 17:161 ENM V44942 Surrogate: 1,2-Dichloroethane - d4 93.6 Limits: 70-130%02/13/24 17:161 ENM V44942 Surrogate: Toluene-d8 102 Limits: 70-130%02/13/24 17:161 ENM V44942 Qualifiers/ Definitions Beyond holding timeHDilution FactorDF Method Quantitation LimitMQL Page 9 of 36 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-038-0014 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Steve Libbey Charlotte Received : 02/07/2024 GSD.050 Revised Report Date : 03/18/2024 Original Report Date : 02/22/2024 Sample ID : Lab No : Sampled:WSW-16 96059 Matrix: 2/6/2024 11:45 Aqueous Analytical Method: Prep Method: Test Results Units MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V43554 02/13/24 09:00 <10.0 µg/L 10.0Acetone 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500Benzene 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500Bromobenzene 1 02/13/24 17:40 V44939ENM <1.00 µg/L 1.00Bromochloromethane 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500Bromodichloromethane 1 02/13/24 17:40 V44939ENM <5.00 µg/L 5.00Bromoform 1 02/13/24 17:40 V44939ENM <1.00 µg/L 1.00Bromomethane 1 02/13/24 17:40 V44942ENM <0.500 µg/L 0.500n-Butylbenzene 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500sec-Butyl benzene 1 02/13/24 17:40 V44939ENM <2.00 µg/L 2.00tert-Butyl benzene 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500Carbon Tetrachloride 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500Chlorobenzene 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500Chlorodibromomethane 1 02/13/24 17:40 V44939ENM <1.00 µg/L 1.00Chloroethane 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500Chloroform 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500Chloromethane 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.5002-Chlorotoluene 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.5004-Chlorotoluene 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 02/13/24 17:40 V44939ENM <2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.5001,2-Dibromoethane 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500Dibromomethane 1 02/13/24 17:40 V44939ENM Qualifiers/ Definitions Beyond holding timeHDilution FactorDF Method Quantitation LimitMQL Page 10 of 36 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-038-0014 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Steve Libbey Charlotte Received : 02/07/2024 GSD.050 Revised Report Date : 03/18/2024 Original Report Date : 02/22/2024 Sample ID : Lab No : Sampled:WSW-16 96059 Matrix: 2/6/2024 11:45 Aqueous Analytical Method: Prep Method: Test Results Units MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V43554 02/13/24 09:00 <0.500 µg/L 0.5001,2-Dichlorobenzene 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.5001,3-Dichlorobenzene 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.5001,4-Dichlorobenzene 1 02/13/24 17:40 V44939ENM <5.00 µg/L 5.00Dichlorodifluoromethane 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.5001,1-Dichloroethane 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.5001,2-Dichloroethane 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.5001,1-Dichloroethene 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500cis-1,2-Dichloroethene 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500trans-1,2-Dichloroethene 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.5001,2-Dichloropropane 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.5001,3-Dichloropropane 1 02/13/24 17:40 V44939ENM <2.00 µg/L 2.002,2-Dichloropropane 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.5001,1-Dichloropropene 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500cis-1,3-Dichloropropene 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500trans-1,3-Dichloropropene 1 02/13/24 17:40 V44939ENM <200 µg/L 200Ethanol 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500Ethylbenzene 1 02/13/24 17:40 V44939ENM <3.00 µg/L 3.00Hexachlorobutadiene 1 02/13/24 17:40 V44939ENM <1.00 µg/L 1.002-Hexanone 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500Isopropylbenzene 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.5004-Isopropyl toluene 1 02/13/24 17:40 V44939ENM <5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 02/13/24 17:40 V44939ENM Qualifiers/ Definitions Beyond holding timeHDilution FactorDF Method Quantitation LimitMQL Page 11 of 36 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-038-0014 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Steve Libbey Charlotte Received : 02/07/2024 GSD.050 Revised Report Date : 03/18/2024 Original Report Date : 02/22/2024 Sample ID : Lab No : Sampled:WSW-16 96059 Matrix: 2/6/2024 11:45 Aqueous Analytical Method: Prep Method: Test Results Units MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V43554 02/13/24 09:00 <1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 02/13/24 17:40 V44939ENM <1.00 µg/L 1.004-Methyl-2-Pentanone 1 02/13/24 17:40 V44939ENM <2.00 µg/L 2.00Methylene Chloride 1 02/13/24 17:40 V44939ENM <1.00 µg/L 1.00Naphthalene 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500n-Propylbenzene 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500Styrene 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500Tetrachloroethene 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500Toluene 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.5001,1,1-Trichloroethane 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.5001,1,2-Trichloroethane 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500Trichloroethene 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500Trichlorofluoromethane 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.5001,2,3-Trichloropropane 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 02/13/24 17:40 V44939ENM <5.00 µg/L 5.00Vinyl Acetate 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500Vinyl Chloride 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500o-Xylene 1 02/13/24 17:40 V44939ENM Qualifiers/ Definitions Beyond holding timeHDilution FactorDF Method Quantitation LimitMQL Page 12 of 36 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-038-0014 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Steve Libbey Charlotte Received : 02/07/2024 GSD.050 Revised Report Date : 03/18/2024 Original Report Date : 02/22/2024 Sample ID : Lab No : Sampled:WSW-16 96059 Matrix: 2/6/2024 11:45 Aqueous Analytical Method: Prep Method: Test Results Units MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V43554 02/13/24 09:00 <1.00 µg/L 1.00m,p-Xylene 1 02/13/24 17:40 V44939ENM <0.500 µg/L 0.500Xylene (Total)1 02/13/24 17:40 V44939 Surrogate: 4-Bromofluorobenzene 95.2 Limits: 70-130%02/13/24 17:401 ENM V44939 Surrogate: Dibromofluoromethane 95.8 Limits: 70-130%02/13/24 17:401 ENM V44939 Surrogate: 1,2-Dichloroethane - d4 95.0 Limits: 70-130%02/13/24 17:401 ENM V44939 Surrogate: Toluene-d8 102 Limits: 70-130%02/13/24 17:401 ENM V44939 Surrogate: 4-Bromofluorobenzene 95.2 Limits: 70-130%02/13/24 17:401 ENM V44942 Surrogate: Dibromofluoromethane 95.8 Limits: 70-130%02/13/24 17:401 ENM V44942 Surrogate: 1,2-Dichloroethane - d4 95.0 Limits: 70-130%02/13/24 17:401 ENM V44942 Surrogate: Toluene-d8 102 Limits: 70-130%02/13/24 17:401 ENM V44942 Qualifiers/ Definitions Beyond holding timeHDilution FactorDF Method Quantitation LimitMQL Page 13 of 36 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-038-0014 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Steve Libbey Charlotte Received : 02/07/2024 GSD.050 Revised Report Date : 03/18/2024 Original Report Date : 02/22/2024 Sample ID : Lab No : Sampled:MW-3R 96060 Matrix: 2/6/2024 12:00 Aqueous Analytical Method: Prep Method: Test Results Units MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V43554 02/13/24 09:00 V43696 02/15/24 09:00 <10.0 µg/L 10.0Acetone 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500Benzene 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500Bromobenzene 1 02/13/24 18:05 V44939ENM <1.00 µg/L 1.00Bromochloromethane 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500Bromodichloromethane 1 02/13/24 18:05 V44939ENM <5.00 µg/L 5.00Bromoform 1 02/13/24 18:05 V44939ENM <1.00 µg/L 1.00Bromomethane 1 02/13/24 18:05 V44942ENM <0.500 µg/L 0.500n-Butylbenzene 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500sec-Butyl benzene 1 02/13/24 18:05 V44939ENM <2.00 µg/L 2.00tert-Butyl benzene 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500Carbon Tetrachloride 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500Chlorobenzene 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500Chlorodibromomethane 1 02/13/24 18:05 V44939ENM <1.00 µg/L 1.00Chloroethane 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500Chloroform 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500Chloromethane 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.5002-Chlorotoluene 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.5004-Chlorotoluene 1 02/13/24 18:05 V44939ENM 10.6 µg/L 0.500Di-Isopropyl Ether (DIPE)1 02/13/24 18:05 V44939ENM <2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.5001,2-Dibromoethane 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500Dibromomethane 1 02/13/24 18:05 V44939ENM Qualifiers/ Definitions Beyond holding timeHDilution FactorDF Method Quantitation LimitMQL Page 14 of 36 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-038-0014 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Steve Libbey Charlotte Received : 02/07/2024 GSD.050 Revised Report Date : 03/18/2024 Original Report Date : 02/22/2024 Sample ID : Lab No : Sampled:MW-3R 96060 Matrix: 2/6/2024 12:00 Aqueous Analytical Method: Prep Method: Test Results Units MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V43554 02/13/24 09:00 V43696 02/15/24 09:00 <0.500 µg/L 0.5001,2-Dichlorobenzene 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.5001,3-Dichlorobenzene 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.5001,4-Dichlorobenzene 1 02/13/24 18:05 V44939ENM <5.00 µg/L 5.00Dichlorodifluoromethane 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.5001,1-Dichloroethane 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.5001,2-Dichloroethane 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.5001,1-Dichloroethene 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500cis-1,2-Dichloroethene 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500trans-1,2-Dichloroethene 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.5001,2-Dichloropropane 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.5001,3-Dichloropropane 1 02/13/24 18:05 V44939ENM <2.00 µg/L 2.002,2-Dichloropropane 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.5001,1-Dichloropropene 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500cis-1,3-Dichloropropene 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500trans-1,3-Dichloropropene 1 02/13/24 18:05 V44939ENM <200 µg/L 200Ethanol 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500Ethylbenzene 1 02/13/24 18:05 V44939ENM <3.00 µg/L 3.00Hexachlorobutadiene 1 02/13/24 18:05 V44939ENM <1.00 µg/L 1.002-Hexanone 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500Isopropylbenzene 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.5004-Isopropyl toluene 1 02/13/24 18:05 V44939ENM <5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 02/13/24 18:05 V44939ENM Qualifiers/ Definitions Beyond holding timeHDilution FactorDF Method Quantitation LimitMQL Page 15 of 36 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-038-0014 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Steve Libbey Charlotte Received : 02/07/2024 GSD.050 Revised Report Date : 03/18/2024 Original Report Date : 02/22/2024 Sample ID : Lab No : Sampled:MW-3R 96060 Matrix: 2/6/2024 12:00 Aqueous Analytical Method: Prep Method: Test Results Units MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V43554 02/13/24 09:00 V43696 02/15/24 09:00 616 µg/L 100Methyl tert-butyl ether (MTBE)100 02/15/24 17:08 V44815ENM <1.00 µg/L 1.004-Methyl-2-Pentanone 1 02/13/24 18:05 V44939ENM <2.00 µg/L 2.00Methylene Chloride 1 02/13/24 18:05 V44939ENM <1.00 µg/L 1.00Naphthalene 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500n-Propylbenzene 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500Styrene 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500Tetrachloroethene 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500Toluene 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.5001,1,1-Trichloroethane 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.5001,1,2-Trichloroethane 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500Trichloroethene 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500Trichlorofluoromethane 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.5001,2,3-Trichloropropane 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 02/13/24 18:05 V44939ENM <5.00 µg/L 5.00Vinyl Acetate 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500Vinyl Chloride 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500o-Xylene 1 02/13/24 18:05 V44939ENM Qualifiers/ Definitions Beyond holding timeHDilution FactorDF Method Quantitation LimitMQL Page 16 of 36 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-038-0014 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Steve Libbey Charlotte Received : 02/07/2024 GSD.050 Revised Report Date : 03/18/2024 Original Report Date : 02/22/2024 Sample ID : Lab No : Sampled:MW-3R 96060 Matrix: 2/6/2024 12:00 Aqueous Analytical Method: Prep Method: Test Results Units MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V43554 02/13/24 09:00 V43696 02/15/24 09:00 <1.00 µg/L 1.00m,p-Xylene 1 02/13/24 18:05 V44939ENM <0.500 µg/L 0.500Xylene (Total)1 02/13/24 18:05 V44939 Surrogate: 4-Bromofluorobenzene 92.8 Limits: 70-130%02/13/24 18:051 ENM V44939 Surrogate: Dibromofluoromethane 95.2 Limits: 70-130%02/13/24 18:051 ENM V44939 Surrogate: 1,2-Dichloroethane - d4 93.2 Limits: 70-130%02/13/24 18:051 ENM V44939 Surrogate: Toluene-d8 102 Limits: 70-130%02/13/24 18:051 ENM V44939 Surrogate: 4-Bromofluorobenzene 92.8 Limits: 70-130%02/13/24 18:051 ENM V44942 Surrogate: Dibromofluoromethane 95.2 Limits: 70-130%02/13/24 18:051 ENM V44942 Surrogate: 1,2-Dichloroethane - d4 93.2 Limits: 70-130%02/13/24 18:051 ENM V44942 Surrogate: Toluene-d8 102 Limits: 70-130%02/13/24 18:051 ENM V44942 Surrogate: 4-Bromofluorobenzene 96.8 Limits: 70-130%02/15/24 17:08100 ENM V44815 Surrogate: Dibromofluoromethane 93.6 Limits: 70-130%02/15/24 17:08100 ENM V44815 Surrogate: 1,2-Dichloroethane - d4 91.2 Limits: 70-130%02/15/24 17:08100 ENM V44815 Surrogate: Toluene-d8 103 Limits: 70-130%02/15/24 17:08100 ENM V44815 Qualifiers/ Definitions Beyond holding timeHDilution FactorDF Method Quantitation LimitMQL Page 17 of 36 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-038-0014 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Steve Libbey Charlotte Received : 02/07/2024 GSD.050 Revised Report Date : 03/18/2024 Original Report Date : 02/22/2024 Sample ID : Lab No : Sampled:MW-5R 96061 Matrix: 2/6/2024 12:15 Aqueous Analytical Method: Prep Method: Test Results Units MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V43939 02/21/24 09:00 <10.0 H µg/L 10.0Acetone 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500Benzene 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500Bromobenzene 1 02/21/24 13:00 V44814ENM <1.00 H µg/L 1.00Bromochloromethane 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500Bromodichloromethane 1 02/21/24 13:00 V44814ENM <5.00 H µg/L 5.00Bromoform 1 02/21/24 13:00 V44814ENM <1.00 H µg/L 1.00Bromomethane 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500n-Butylbenzene 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500sec-Butyl benzene 1 02/21/24 13:00 V44814ENM <2.00 H µg/L 2.00tert-Butyl benzene 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500Carbon Tetrachloride 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500Chlorobenzene 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500Chlorodibromomethane 1 02/21/24 13:00 V44814ENM <1.00 H µg/L 1.00Chloroethane 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500Chloroform 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500Chloromethane 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.5002-Chlorotoluene 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.5004-Chlorotoluene 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500Di-Isopropyl Ether (DIPE)1 02/21/24 13:00 V44814ENM <2.00 H µg/L 2.001,2-Dibromo-3-Chloropropane 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.5001,2-Dibromoethane 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500Dibromomethane 1 02/21/24 13:00 V44814ENM Qualifiers/ Definitions Beyond holding timeHDilution FactorDF Method Quantitation LimitMQL Page 18 of 36 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-038-0014 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Steve Libbey Charlotte Received : 02/07/2024 GSD.050 Revised Report Date : 03/18/2024 Original Report Date : 02/22/2024 Sample ID : Lab No : Sampled:MW-5R 96061 Matrix: 2/6/2024 12:15 Aqueous Analytical Method: Prep Method: Test Results Units MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V43939 02/21/24 09:00 <0.500 H µg/L 0.5001,2-Dichlorobenzene 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.5001,3-Dichlorobenzene 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.5001,4-Dichlorobenzene 1 02/21/24 13:00 V44814ENM <5.00 H µg/L 5.00Dichlorodifluoromethane 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.5001,1-Dichloroethane 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.5001,2-Dichloroethane 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.5001,1-Dichloroethene 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500cis-1,2-Dichloroethene 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500trans-1,2-Dichloroethene 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.5001,2-Dichloropropane 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.5001,3-Dichloropropane 1 02/21/24 13:00 V44814ENM <2.00 H µg/L 2.002,2-Dichloropropane 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.5001,1-Dichloropropene 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500cis-1,3-Dichloropropene 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500trans-1,3-Dichloropropene 1 02/21/24 13:00 V44814ENM <200 H µg/L 200Ethanol 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500Ethylbenzene 1 02/21/24 13:00 V44814ENM <3.00 H µg/L 3.00Hexachlorobutadiene 1 02/21/24 13:00 V44814ENM <1.00 H µg/L 1.002-Hexanone 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500Isopropylbenzene 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.5004-Isopropyl toluene 1 02/21/24 13:00 V44814ENM <5.00 H µg/L 5.00Methyl Ethyl Ketone (MEK)1 02/21/24 13:00 V44814ENM Qualifiers/ Definitions Beyond holding timeHDilution FactorDF Method Quantitation LimitMQL Page 19 of 36 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-038-0014 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Steve Libbey Charlotte Received : 02/07/2024 GSD.050 Revised Report Date : 03/18/2024 Original Report Date : 02/22/2024 Sample ID : Lab No : Sampled:MW-5R 96061 Matrix: 2/6/2024 12:15 Aqueous Analytical Method: Prep Method: Test Results Units MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V43939 02/21/24 09:00 <1.00 H µg/L 1.00Methyl tert-butyl ether (MTBE)1 02/21/24 13:00 V44814ENM <1.00 H µg/L 1.004-Methyl-2-Pentanone 1 02/21/24 13:00 V44814ENM <2.00 H µg/L 2.00Methylene Chloride 1 02/21/24 13:00 V44814ENM <1.00 H µg/L 1.00Naphthalene 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500n-Propylbenzene 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500Styrene 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.5001,1,1,2-Tetrachloroethane 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.5001,1,2,2-Tetrachloroethane 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500Tetrachloroethene 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500Toluene 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.5001,2,3-Trichlorobenzene 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.5001,2,4-Trichlorobenzene 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.5001,1,1-Trichloroethane 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.5001,1,2-Trichloroethane 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500Trichloroethene 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500Trichlorofluoromethane 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.5001,2,3-Trichloropropane 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.5001,2,4-Trimethylbenzene 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.5001,3,5-Trimethylbenzene 1 02/21/24 13:00 V44814ENM <5.00 H µg/L 5.00Vinyl Acetate 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500Vinyl Chloride 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500o-Xylene 1 02/21/24 13:00 V44814ENM Qualifiers/ Definitions Beyond holding timeHDilution FactorDF Method Quantitation LimitMQL Page 20 of 36 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 24-038-0014 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Steve Libbey Charlotte Received : 02/07/2024 GSD.050 Revised Report Date : 03/18/2024 Original Report Date : 02/22/2024 Sample ID : Lab No : Sampled:MW-5R 96061 Matrix: 2/6/2024 12:15 Aqueous Analytical Method: Prep Method: Test Results Units MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V43939 02/21/24 09:00 <1.00 H µg/L 1.00m,p-Xylene 1 02/21/24 13:00 V44814ENM <0.500 H µg/L 0.500Xylene (Total)1 02/21/24 13:00 V44814 Surrogate: 4-Bromofluorobenzene 96.0 Limits: 70-130%02/21/24 13:001 ENM V44814 Surrogate: Dibromofluoromethane 98.6 Limits: 70-130%02/21/24 13:001 ENM V44814 Surrogate: 1,2-Dichloroethane - d4 92.6 Limits: 70-130%02/21/24 13:001 ENM V44814 Surrogate: Toluene-d8 97.8 Limits: 70-130%02/21/24 13:001 ENM V44814 Qualifiers/ Definitions Beyond holding timeHDilution FactorDF Method Quantitation LimitMQL Page 21 of 36 Quality Control Data 24-038-0014Report No: Project Description: Client ID:Hart & Hickman (Charlotte) GSD.050 QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V44939QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V43554 Associated Lab Samples: 96058, 96059, 96060 LRB-V43554 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLBlank ResultUnits % Recovery % Rec Limits 02/13/24 14:2510.0< 10.0µg/LAcetone 02/13/24 14:250.500< 0.500µg/LBenzene 02/13/24 14:250.500< 0.500µg/LBromobenzene 02/13/24 14:251.00< 1.00µg/LBromochloromethane 02/13/24 14:250.500< 0.500µg/LBromodichloromethane 02/13/24 14:255.00< 5.00µg/LBromoform 02/13/24 14:251.00< 1.00µg/LBromomethane 02/13/24 14:250.500< 0.500µg/Ln-Butylbenzene 02/13/24 14:250.500< 0.500µg/Lsec-Butyl benzene 02/13/24 14:252.00< 2.00µg/Ltert-Butyl benzene 02/13/24 14:250.500< 0.500µg/LCarbon Tetrachloride 02/13/24 14:250.500< 0.500µg/LChlorobenzene 02/13/24 14:250.500< 0.500µg/LChlorodibromomethane 02/13/24 14:251.00< 1.00µg/LChloroethane 02/13/24 14:250.500< 0.500µg/LChloroform 02/13/24 14:250.500< 0.500µg/LChloromethane 02/13/24 14:250.500< 0.500µg/L2-Chlorotoluene 02/13/24 14:250.500< 0.500µg/L4-Chlorotoluene 02/13/24 14:250.500< 0.500µg/LDi-Isopropyl Ether (DIPE) 02/13/24 14:252.00< 2.00µg/L1,2-Dibromo-3-Chloropropane 02/13/24 14:250.500< 0.500µg/L1,2-Dibromoethane 02/13/24 14:250.500< 0.500µg/LDibromomethane 02/13/24 14:250.500< 0.500µg/L1,2-Dichlorobenzene 02/13/24 14:250.500< 0.500µg/L1,3-Dichlorobenzene 02/13/24 14:250.500< 0.500µg/L1,4-Dichlorobenzene 02/13/24 14:255.00< 5.00µg/LDichlorodifluoromethane 02/13/24 14:250.500< 0.500µg/L1,1-Dichloroethane Page 1 of 13Date:03/18/2024 02:59 PM Page 22 of 36 Quality Control Data 24-038-0014Report No: Project Description: Client ID:Hart & Hickman (Charlotte) GSD.050 QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V44939QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V43554 Associated Lab Samples: 96058, 96059, 96060 LRB-V43554 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLBlank ResultUnits % Recovery % Rec Limits 02/13/24 14:250.500< 0.500µg/L1,2-Dichloroethane 02/13/24 14:250.500< 0.500µg/L1,1-Dichloroethene 02/13/24 14:250.500< 0.500µg/Lcis-1,2-Dichloroethene 02/13/24 14:250.500< 0.500µg/Ltrans-1,2-Dichloroethene 02/13/24 14:250.500< 0.500µg/L1,2-Dichloropropane 02/13/24 14:250.500< 0.500µg/L1,3-Dichloropropane 02/13/24 14:252.00< 2.00µg/L2,2-Dichloropropane 02/13/24 14:250.500< 0.500µg/L1,1-Dichloropropene 02/13/24 14:250.500< 0.500µg/Lcis-1,3-Dichloropropene 02/13/24 14:250.500< 0.500µg/Ltrans-1,3-Dichloropropene 02/13/24 14:25200< 200µg/LEthanol 02/13/24 14:250.500< 0.500µg/LEthylbenzene 02/13/24 14:253.00< 3.00µg/LHexachlorobutadiene 02/13/24 14:251.00< 1.00µg/L2-Hexanone 02/13/24 14:250.500< 0.500µg/LIsopropylbenzene 02/13/24 14:250.500< 0.500µg/L4-Isopropyl toluene 02/13/24 14:255.00< 5.00µg/LMethyl Ethyl Ketone (MEK) 02/13/24 14:251.00< 1.00µg/LMethyl tert-butyl ether (MTBE) 02/13/24 14:251.00< 1.00µg/L4-Methyl-2-Pentanone 02/13/24 14:252.00< 2.00µg/LMethylene Chloride 02/13/24 14:251.00< 1.00µg/LNaphthalene 02/13/24 14:250.500< 0.500µg/Ln-Propylbenzene 02/13/24 14:250.500< 0.500µg/LStyrene 02/13/24 14:250.500< 0.500µg/L1,1,1,2-Tetrachloroethane 02/13/24 14:250.500< 0.500µg/L1,1,2,2-Tetrachloroethane 02/13/24 14:250.500< 0.500µg/LTetrachloroethene 02/13/24 14:250.500< 0.500µg/LToluene Page 2 of 13Date:03/18/2024 02:59 PM Page 23 of 36 Quality Control Data 24-038-0014Report No: Project Description: Client ID:Hart & Hickman (Charlotte) GSD.050 QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V44939QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V43554 Associated Lab Samples: 96058, 96059, 96060 LRB-V43554 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLBlank ResultUnits % Recovery % Rec Limits 02/13/24 14:250.500< 0.500µg/L1,2,3-Trichlorobenzene 02/13/24 14:250.500< 0.500µg/L1,2,4-Trichlorobenzene 02/13/24 14:250.500< 0.500µg/L1,1,1-Trichloroethane 02/13/24 14:250.500< 0.500µg/L1,1,2-Trichloroethane 02/13/24 14:250.500< 0.500µg/LTrichloroethene 02/13/24 14:250.500< 0.500µg/LTrichlorofluoromethane 02/13/24 14:250.500< 0.500µg/L1,2,3-Trichloropropane 02/13/24 14:250.500< 0.500µg/L1,2,4-Trimethylbenzene 02/13/24 14:250.500< 0.500µg/L1,3,5-Trimethylbenzene 02/13/24 14:255.00< 5.00µg/LVinyl Acetate 02/13/24 14:250.500< 0.500µg/LVinyl Chloride 02/13/24 14:250.500< 0.500µg/Lo-Xylene 02/13/24 14:251.00< 1.00µg/Lm,p-Xylene 02/13/24 14:254-Bromofluorobenzene (S)92.6 70-130 02/13/24 14:25Dibromofluoromethane (S)96.6 70-130 02/13/24 14:251,2-Dichloroethane - d4 (S)96.2 70-130 02/13/24 14:25Toluene-d8 (S)101 70-130 LCS-V43554 LCSD-V43554Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 36.3 90.797.739.140.0µg/LAcetone 40-160 7.4 20.0 21.8 10910921.820.0µg/LBenzene 70-130 0.0 20.0 22.1 11111122.120.0µg/LBromobenzene 70-130 0.0 20.0 22.5 11311022.020.0µg/LBromochloromethane 70-130 2.2 20.0 21.6 10810721.320.0µg/LBromodichloromethane 70-130 1.3 20.0 Page 3 of 13Date:03/18/2024 02:59 PM Page 24 of 36 Quality Control Data 24-038-0014Report No: Project Description: Client ID:Hart & Hickman (Charlotte) GSD.050 QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V44939QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V43554 LCS-V43554 LCSD-V43554Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 23.2 11611322.620.0µg/LBromoform 70-130 2.6 20.0 9.69 48.4*44.7*8.9420.0µg/LBromomethane 60-140 8.0 20.0 21.6 10811022.020.0µg/Ln-Butylbenzene 70-130 1.8 20.0 23.4 11711522.920.0µg/Lsec-Butyl benzene 70-130 2.1 20.0 23.0 11511522.920.0µg/Ltert-Butyl benzene 70-130 0.4 20.0 22.3 11211122.120.0µg/LCarbon Tetrachloride 70-130 0.9 20.0 22.9 11511322.520.0µg/LChlorobenzene 70-130 1.7 20.0 23.1 11611522.920.0µg/LChlorodibromomethane 70-130 0.8 20.0 24.6 12311823.620.0µg/LChloroethane 60-140 4.1 20.0 21.0 10510520.920.0µg/LChloroform 70-130 0.4 20.0 16.3 81.580.516.120.0µg/LChloromethane 60-140 1.2 20.0 22.8 11411522.920.0µg/L2-Chlorotoluene 70-130 0.4 20.0 23.0 11511523.020.0µg/L4-Chlorotoluene 70-130 0.0 20.0 22.5 11311422.720.0µg/LDi-Isopropyl Ether (DIPE)70-130 0.8 20.0 24.1 121135*27.020.0µg/L1,2-Dibromo-3-Chloropropane 70-130 11.3 20.0 23.0 11511623.120.0µg/L1,2-Dibromoethane 70-130 0.4 20.0 21.7 10911222.420.0µg/LDibromomethane 70-130 3.1 20.0 21.8 10911122.220.0µg/L1,2-Dichlorobenzene 70-130 1.8 20.0 22.5 11311022.020.0µg/L1,3-Dichlorobenzene 70-130 2.2 20.0 22.8 11411422.720.0µg/L1,4-Dichlorobenzene 70-130 0.4 20.0 19.7 98.598.019.620.0µg/LDichlorodifluoromethane 60-140 0.5 20.0 21.2 10610520.920.0µg/L1,1-Dichloroethane 70-130 1.4 20.0 21.8 10910921.820.0µg/L1,2-Dichloroethane 70-130 0.0 20.0 20.9 10510320.520.0µg/L1,1-Dichloroethene 70-130 1.9 20.0 21.1 10610521.020.0µg/Lcis-1,2-Dichloroethene 70-130 0.4 20.0 20.6 10310220.420.0µg/Ltrans-1,2-Dichloroethene 70-130 0.9 20.0 Page 4 of 13* QC Fail Date:03/18/2024 02:59 PM Page 25 of 36 Quality Control Data 24-038-0014Report No: Project Description: Client ID:Hart & Hickman (Charlotte) GSD.050 QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V44939QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V43554 LCS-V43554 LCSD-V43554Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 21.3 10710520.920.0µg/L1,2-Dichloropropane 70-130 1.8 20.0 22.9 11511422.820.0µg/L1,3-Dichloropropane 70-130 0.4 20.0 21.6 10810721.320.0µg/L2,2-Dichloropropane 70-130 1.3 20.0 21.5 10810921.820.0µg/L1,1-Dichloropropene 70-130 1.3 20.0 21.3 10710721.420.0µg/Lcis-1,3-Dichloropropene 70-130 0.4 20.0 21.9 11011122.220.0µg/Ltrans-1,3-Dichloropropene 70-130 1.3 20.0 469 93.889.8449500µg/LEthanol 60-140 4.3 20.0 22.7 11411222.420.0µg/LEthylbenzene 70-130 1.3 20.0 22.7 11411923.820.0µg/LHexachlorobutadiene 70-130 4.7 20.0 23.6 11812925.720.0µg/L2-Hexanone 60-140 8.5 20.0 22.2 11111422.820.0µg/LIsopropylbenzene 70-130 2.6 20.0 22.6 11311222.420.0µg/L4-Isopropyl toluene 70-130 0.8 20.0 19.9 99.510921.820.0µg/LMethyl Ethyl Ketone (MEK)60-140 9.1 20.0 22.9 11511823.620.0µg/LMethyl tert-butyl ether (MTBE)70-130 3.0 20.0 23.0 11512925.820.0µg/L4-Methyl-2-Pentanone 60-140 11.4 20.0 21.2 10610521.020.0µg/LMethylene Chloride 70-130 0.9 20.0 21.2 10611723.420.0µg/LNaphthalene 70-130 9.8 20.0 23.1 11611623.220.0µg/Ln-Propylbenzene 70-130 0.4 20.0 23.3 11711422.720.0µg/LStyrene 70-130 2.6 20.0 23.0 11511523.020.0µg/L1,1,1,2-Tetrachloroethane 70-130 0.0 20.0 23.2 11612124.220.0µg/L1,1,2,2-Tetrachloroethane 70-130 4.2 20.0 22.0 11011022.020.0µg/LTetrachloroethene 70-130 0.0 20.0 22.2 11111022.020.0µg/LToluene 70-130 0.9 20.0 25.3 127134*26.820.0µg/L1,2,3-Trichlorobenzene 70-130 5.7 20.0 23.1 11612424.720.0µg/L1,2,4-Trichlorobenzene 70-130 6.6 20.0 21.2 10610621.120.0µg/L1,1,1-Trichloroethane 70-130 0.4 20.0 Page 5 of 13* QC Fail Date:03/18/2024 02:59 PM Page 26 of 36 Quality Control Data 24-038-0014Report No: Project Description: Client ID:Hart & Hickman (Charlotte) GSD.050 QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V44939QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V43554 LCS-V43554 LCSD-V43554Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 21.9 11011022.020.0µg/L1,1,2-Trichloroethane 70-130 0.4 20.0 21.9 11011022.020.0µg/LTrichloroethene 70-130 0.4 20.0 20.4 10210220.320.0µg/LTrichlorofluoromethane 60-140 0.4 20.0 21.9 11011923.720.0µg/L1,2,3-Trichloropropane 70-130 7.8 20.0 22.4 11211122.120.0µg/L1,2,4-Trimethylbenzene 70-130 1.3 20.0 22.9 11511322.620.0µg/L1,3,5-Trimethylbenzene 70-130 1.3 20.0 22.5 11311523.020.0µg/LVinyl Acetate 60-140 2.1 20.0 18.3 91.590.018.020.0µg/LVinyl Chloride 60-140 1.6 20.0 23.0 11511322.620.0µg/Lo-Xylene 70-130 1.7 20.0 48.9 12212148.240.0µg/Lm,p-Xylene 70-130 1.4 20.0 95.498.04-Bromofluorobenzene (S)70-130 96.096.0Dibromofluoromethane (S)70-130 97.499.01,2-Dichloroethane - d4 (S)70-130 103101Toluene-d8 (S)70-130 Page 6 of 13Date:03/18/2024 02:59 PM Page 27 of 36 Quality Control Data 24-038-0014Report No: Project Description: Client ID:Hart & Hickman (Charlotte) GSD.050 QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V44815QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V43696 Associated Lab Samples: 96060 LRB-V43696 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLBlank ResultUnits % Recovery % Rec Limits 02/15/24 12:131.00< 1.00µg/LMethyl tert-butyl ether (MTBE) 02/15/24 12:134-Bromofluorobenzene (S)97.4 70-130 02/15/24 12:13Dibromofluoromethane (S)96.0 70-130 02/15/24 12:131,2-Dichloroethane - d4 (S)94.4 70-130 02/15/24 12:13Toluene-d8 (S)103 70-130 LCS-V43696 LCSD-V43696Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 21.3 10710621.220.0µg/LMethyl tert-butyl ether (MTBE)70-130 0.4 20.0 96.497.04-Bromofluorobenzene (S)70-130 95.094.4Dibromofluoromethane (S)70-130 94.094.21,2-Dichloroethane - d4 (S)70-130 103103Toluene-d8 (S)70-130 Page 7 of 13Date:03/18/2024 02:59 PM Page 28 of 36 Quality Control Data 24-038-0014Report No: Project Description: Client ID:Hart & Hickman (Charlotte) GSD.050 QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V43946,V44814QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V43939 Associated Lab Samples: 96061 LRB-V43939 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLBlank ResultUnits % Recovery % Rec Limits 02/21/24 12:3610.0< 10.0µg/LAcetone 02/21/24 12:360.500< 0.500µg/LBenzene 02/21/24 12:360.500< 0.500µg/LBromobenzene 02/21/24 12:361.00< 1.00µg/LBromochloromethane 02/21/24 12:360.500< 0.500µg/LBromodichloromethane 02/21/24 12:365.00< 5.00µg/LBromoform 02/21/24 12:361.00< 1.00µg/LBromomethane 02/21/24 12:360.500< 0.500µg/Ln-Butylbenzene 02/21/24 12:360.500< 0.500µg/Lsec-Butyl benzene 02/21/24 12:362.00< 2.00µg/Ltert-Butyl benzene 02/21/24 12:360.500< 0.500µg/LCarbon Tetrachloride 02/21/24 12:360.500< 0.500µg/LChlorobenzene 02/21/24 12:360.500< 0.500µg/LChlorodibromomethane 02/21/24 12:361.00< 1.00µg/LChloroethane 02/21/24 12:360.500< 0.500µg/LChloroform 02/21/24 12:360.500< 0.500µg/LChloromethane 02/21/24 12:360.500< 0.500µg/L2-Chlorotoluene 02/21/24 12:360.500< 0.500µg/L4-Chlorotoluene 02/21/24 12:360.500< 0.500µg/LDi-Isopropyl Ether (DIPE) 02/21/24 12:362.00< 2.00µg/L1,2-Dibromo-3-Chloropropane 02/21/24 12:360.500< 0.500µg/L1,2-Dibromoethane 02/21/24 12:360.500< 0.500µg/LDibromomethane 02/21/24 12:360.500< 0.500µg/L1,2-Dichlorobenzene 02/21/24 12:360.500< 0.500µg/L1,3-Dichlorobenzene 02/21/24 12:360.500< 0.500µg/L1,4-Dichlorobenzene 02/21/24 12:365.00< 5.00µg/LDichlorodifluoromethane 02/21/24 12:360.500< 0.500µg/L1,1-Dichloroethane Page 8 of 13Date:03/18/2024 02:59 PM Page 29 of 36 Quality Control Data 24-038-0014Report No: Project Description: Client ID:Hart & Hickman (Charlotte) GSD.050 QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V43946,V44814QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V43939 Associated Lab Samples: 96061 LRB-V43939 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLBlank ResultUnits % Recovery % Rec Limits 02/21/24 12:360.500< 0.500µg/L1,2-Dichloroethane 02/21/24 12:360.500< 0.500µg/L1,1-Dichloroethene 02/21/24 12:360.500< 0.500µg/Lcis-1,2-Dichloroethene 02/21/24 12:360.500< 0.500µg/Ltrans-1,2-Dichloroethene 02/21/24 12:360.500< 0.500µg/L1,2-Dichloropropane 02/21/24 12:360.500< 0.500µg/L1,3-Dichloropropane 02/21/24 12:362.00< 2.00µg/L2,2-Dichloropropane 02/21/24 12:360.500< 0.500µg/L1,1-Dichloropropene 02/21/24 12:360.500< 0.500µg/Lcis-1,3-Dichloropropene 02/21/24 12:360.500< 0.500µg/Ltrans-1,3-Dichloropropene 02/21/24 12:36200< 200µg/LEthanol 02/21/24 12:360.500< 0.500µg/LEthylbenzene 02/21/24 12:363.00< 3.00µg/LHexachlorobutadiene 02/21/24 12:361.00< 1.00µg/L2-Hexanone 02/21/24 12:360.500< 0.500µg/LIsopropylbenzene 02/21/24 12:360.500< 0.500µg/L4-Isopropyl toluene 02/21/24 12:365.00< 5.00µg/LMethyl Ethyl Ketone (MEK) 02/21/24 12:361.00< 1.00µg/LMethyl tert-butyl ether (MTBE) 02/21/24 12:361.00< 1.00µg/L4-Methyl-2-Pentanone 02/21/24 12:362.00< 2.00µg/LMethylene Chloride 02/21/24 12:361.00< 1.00µg/LNaphthalene 02/21/24 12:360.500< 0.500µg/Ln-Propylbenzene 02/21/24 12:360.500< 0.500µg/LStyrene 02/21/24 12:360.500< 0.500µg/L1,1,1,2-Tetrachloroethane 02/21/24 12:360.500< 0.500µg/L1,1,2,2-Tetrachloroethane 02/21/24 12:360.500< 0.500µg/LTetrachloroethene 02/21/24 12:360.500< 0.500µg/LToluene Page 9 of 13Date:03/18/2024 02:59 PM Page 30 of 36 Quality Control Data 24-038-0014Report No: Project Description: Client ID:Hart & Hickman (Charlotte) GSD.050 QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V43946,V44814QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V43939 Associated Lab Samples: 96061 LRB-V43939 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLBlank ResultUnits % Recovery % Rec Limits 02/21/24 12:360.500< 0.500µg/L1,2,3-Trichlorobenzene 02/21/24 12:360.500< 0.500µg/L1,2,4-Trichlorobenzene 02/21/24 12:360.500< 0.500µg/L1,1,1-Trichloroethane 02/21/24 12:360.500< 0.500µg/L1,1,2-Trichloroethane 02/21/24 12:360.500< 0.500µg/LTrichloroethene 02/21/24 12:360.500< 0.500µg/LTrichlorofluoromethane 02/21/24 12:360.500< 0.500µg/L1,2,3-Trichloropropane 02/21/24 12:360.500< 0.500µg/L1,2,4-Trimethylbenzene 02/21/24 12:360.500< 0.500µg/L1,3,5-Trimethylbenzene 02/21/24 12:365.00< 5.00µg/LVinyl Acetate 02/21/24 12:360.500< 0.500µg/LVinyl Chloride 02/21/24 12:360.500< 0.500µg/Lo-Xylene 02/21/24 12:361.00< 1.00µg/Lm,p-Xylene 02/21/24 12:364-Bromofluorobenzene (S)99.4 70-130 02/21/24 12:36Dibromofluoromethane (S)98.4 70-130 02/21/24 12:361,2-Dichloroethane - d4 (S)89.2 70-130 02/21/24 12:36Toluene-d8 (S)98.0 70-130 LCS-V43939 LCSD-V43939Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 33.9 84.782.032.840.0µg/LAcetone 40-160 3.2 20.0 20.2 10110521.020.0µg/LBenzene 70-130 3.8 20.0 20.8 10410420.820.0µg/LBromobenzene 70-130 0.0 20.0 20.8 10410621.220.0µg/LBromochloromethane 70-130 1.9 20.0 19.3 96.510020.020.0µg/LBromodichloromethane 70-130 3.5 20.0 Page 10 of 13Date:03/18/2024 02:59 PM Page 31 of 36 Quality Control Data 24-038-0014Report No: Project Description: Client ID:Hart & Hickman (Charlotte) GSD.050 QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V43946,V44814QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V43939 LCS-V43939 LCSD-V43939Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 19.4 97.098.519.720.0µg/LBromoform 70-130 1.5 20.0 19.8 99.095.019.020.0µg/LBromomethane 60-140 4.1 20.0 20.3 10210220.320.0µg/Ln-Butylbenzene 70-130 0.0 20.0 21.1 10610721.320.0µg/Lsec-Butyl benzene 70-130 0.9 20.0 21.4 10710821.520.0µg/Ltert-Butyl benzene 70-130 0.4 20.0 20.4 10210521.020.0µg/LCarbon Tetrachloride 70-130 2.8 20.0 20.7 10410621.220.0µg/LChlorobenzene 70-130 2.3 20.0 20.5 10310420.720.0µg/LChlorodibromomethane 70-130 0.9 20.0 22.4 11211823.620.0µg/LChloroethane 60-140 5.2 20.0 19.5 97.510320.620.0µg/LChloroform 70-130 5.4 20.0 20.9 10510921.820.0µg/LChloromethane 60-140 4.2 20.0 21.1 10610621.220.0µg/L2-Chlorotoluene 70-130 0.4 20.0 21.2 10610721.420.0µg/L4-Chlorotoluene 70-130 0.9 20.0 20.2 10110420.720.0µg/LDi-Isopropyl Ether (DIPE)70-130 2.4 20.0 20.5 10398.019.620.0µg/L1,2-Dibromo-3-Chloropropane 70-130 4.4 20.0 20.2 10110120.120.0µg/L1,2-Dibromoethane 70-130 0.4 20.0 19.7 98.510020.020.0µg/LDibromomethane 70-130 1.5 20.0 21.6 10810621.120.0µg/L1,2-Dichlorobenzene 70-130 2.3 20.0 21.5 10810921.720.0µg/L1,3-Dichlorobenzene 70-130 0.9 20.0 21.7 10910721.420.0µg/L1,4-Dichlorobenzene 70-130 1.3 20.0 22.7 11411723.320.0µg/LDichlorodifluoromethane 60-140 2.6 20.0 20.3 10210621.120.0µg/L1,1-Dichloroethane 70-130 3.8 20.0 18.6 93.093.518.720.0µg/L1,2-Dichloroethane 70-130 0.5 20.0 19.2 96.010320.520.0µg/L1,1-Dichloroethene 70-130 6.5 20.0 19.4 97.010220.420.0µg/Lcis-1,2-Dichloroethene 70-130 5.0 20.0 19.7 98.510220.420.0µg/Ltrans-1,2-Dichloroethene 70-130 3.4 20.0 Page 11 of 13Date:03/18/2024 02:59 PM Page 32 of 36 Quality Control Data 24-038-0014Report No: Project Description: Client ID:Hart & Hickman (Charlotte) GSD.050 QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V43946,V44814QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V43939 LCS-V43939 LCSD-V43939Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 20.3 10210621.120.0µg/L1,2-Dichloropropane 70-130 3.8 20.0 20.3 10299.519.920.0µg/L1,3-Dichloropropane 70-130 1.9 20.0 19.9 99.510621.120.0µg/L2,2-Dichloropropane 70-130 5.8 20.0 20.7 10410821.620.0µg/L1,1-Dichloropropene 70-130 4.2 20.0 20.0 10010220.320.0µg/Lcis-1,3-Dichloropropene 70-130 1.4 20.0 19.3 96.598.519.720.0µg/Ltrans-1,3-Dichloropropene 70-130 2.0 20.0 806 161*155*774500µg/LEthanol 60-140 4.0 20.0 20.3 10210420.720.0µg/LEthylbenzene 70-130 1.9 20.0 22.9 11511322.520.0µg/LHexachlorobutadiene 70-130 1.7 20.0 18.4 92.088.517.720.0µg/L2-Hexanone 60-140 3.8 20.0 21.3 10710520.920.0µg/LIsopropylbenzene 70-130 1.8 20.0 20.6 10310621.120.0µg/L4-Isopropyl toluene 70-130 2.3 20.0 17.6 88.088.017.620.0µg/LMethyl Ethyl Ketone (MEK)60-140 0.0 20.0 19.3 96.597.519.520.0µg/LMethyl tert-butyl ether (MTBE)70-130 1.0 20.0 18.5 92.590.018.020.0µg/L4-Methyl-2-Pentanone 60-140 2.7 20.0 19.7 98.510220.420.0µg/LMethylene Chloride 70-130 3.4 20.0 20.0 10010220.420.0µg/LNaphthalene 70-130 1.9 20.0 21.0 10510621.220.0µg/Ln-Propylbenzene 70-130 0.9 20.0 20.7 10410420.820.0µg/LStyrene 70-130 0.4 20.0 20.9 10510621.220.0µg/L1,1,1,2-Tetrachloroethane 70-130 1.4 20.0 19.6 98.096.519.320.0µg/L1,1,2,2-Tetrachloroethane 70-130 1.5 20.0 21.1 10610821.620.0µg/LTetrachloroethene 70-130 2.3 20.0 20.1 10110520.920.0µg/LToluene 70-130 3.9 20.0 21.3 10711523.020.0µg/L1,2,3-Trichlorobenzene 70-130 7.6 20.0 22.2 11111422.820.0µg/L1,2,4-Trichlorobenzene 70-130 2.6 20.0 19.5 97.510220.320.0µg/L1,1,1-Trichloroethane 70-130 4.0 20.0 Page 12 of 13* QC Fail Date:03/18/2024 02:59 PM Page 33 of 36 Quality Control Data 24-038-0014Report No: Project Description: Client ID:Hart & Hickman (Charlotte) GSD.050 QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V43946,V44814QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V43939 LCS-V43939 LCSD-V43939Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 19.4 97.099.519.920.0µg/L1,1,2-Trichloroethane 70-130 2.5 20.0 20.5 10310721.320.0µg/LTrichloroethene 70-130 3.8 20.0 19.6 98.010220.320.0µg/LTrichlorofluoromethane 60-140 3.5 20.0 18.6 93.092.518.520.0µg/L1,2,3-Trichloropropane 70-130 0.5 20.0 20.4 10210320.620.0µg/L1,2,4-Trimethylbenzene 70-130 0.9 20.0 20.8 10410520.920.0µg/L1,3,5-Trimethylbenzene 70-130 0.4 20.0 19.5 97.599.519.920.0µg/LVinyl Acetate 60-140 2.0 20.0 20.2 10110721.320.0µg/LVinyl Chloride 60-140 5.3 20.0 20.7 10410520.920.0µg/Lo-Xylene 70-130 0.9 20.0 42.7 10710943.440.0µg/Lm,p-Xylene 70-130 1.6 20.0 10197.44-Bromofluorobenzene (S)70-130 99.699.6Dibromofluoromethane (S)70-130 92.093.01,2-Dichloroethane - d4 (S)70-130 10099.4Toluene-d8 (S)70-130 Page 13 of 13Date:03/18/2024 02:59 PM Page 34 of 36 Fed Ex UPS US Postal Client Lab Courier Other : Shipment Receipt Form Customer Number: Customer Name: Report Number:24-038-0014 Hart & Hickman (Charlotte) 01102 Shipping Method Shipping container/cooler uncompromised? Thermometer ID:IRT15 4.7C Chain of Custody (COC) present?Yes No Yes No Not Present Yes No Not Present Yes No COC agrees with sample label(s)? Yes No COC properly completed Samples in proper containers? Sample containers intact? Sufficient sample volume for indicated test(s)? All samples received within holding time? Cooler temperature in compliance? Yes No Yes No Yes No Yes No Yes No Yes NoCooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. Yes No Yes No N/A Yes No N/A Yes No N/ASoil VOA method 5035 – compliance criteria met Water - Sample containers properly preserved Water - VOA vials free of headspace Yes No N/A Trip Blanks received with VOAs Low concentration EnCore samplers (48 hr) High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d) High concentration container (48 hr) Custody seals intact on shipping container/cooler? Custody seals intact on sample bottles? Number of coolers/boxes received Yes No 1 Signature:Angelo Norvell Date & Time:02/07/2024 14:33:18 Special precautions or instructions included? Comments: Page 35 of 36 Page 36 of 36 Appendix B Concentrations versus Time Graph (MW-3D, MW-5D, and Influent) 0 1000 2000 3000 4000 5000 6000 7000 Co n c ( µ g / l ) Date Concentration vs. TimeGeneral Store of Denver Benzene - MW-3D MTBE MW-3D Benzene MW-5D MTBE MW-5D Influent Benzene Influent MTBE Pumping Starts Pumping Ceases Pumping Restarts Appendix C Evaluation of Change in Contaminant Mass Calculations Initial Aq. Thickness ft2 ft ft3 (plume/source)porosity lb/ug l/gal gal/ft3 lbs benzene 389637 30 11689110 11352150 0.1 7.45 2.20459E-09 3.79E+00 7.48E+00 0.53 a 1.07 (a+c) MTBE 389637 30 11689110 11352150 0.1 45.5 2.20459E-09 3.79E+00 7.48E+00 3.22 b 6.05 (b+d) benzene 11232 30 336960 336960 0.1 260 2.20459E-09 3.79E+00 7.48E+00 0.55 c 7.13 MTBE 11232 30 336960 336960 0.1 1345 2.20459E-09 3.79E+00 7.48E+00 2.83 d closure Aq. Thickness Date Years Aq. Thickness Aq. Thickness Aq. Thickness Aq. Thickness Aq. Thickness Evaluation of Change in Contaminant Mass Calculations General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 Evaluation of Change in Contaminant Mass Calculations General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 Date Years Aq. Thickness Aq. Thickness Aq. Thickness Aq. Thickness Aq. Thickness Aq. Thickness Aq. Thickness Evaluation of Change in Contaminant Mass Calculations General Store of Denver Sherrills Ford, North Carolina H&H Job No. GSD-050 Date Years Aq. Thickness Aq. Thickness Aq. Thickness Aq. Thickness totals Aq. Thickness totals Aq. Thickness totals