MO-30256_00000_CA_SCH_20240219

Murphy Oil USA, Inc.

Site Check Report
Murphy USA Store #7498
1209 1st Avenue North
Conover, NC 28613

February 19, 2024

Site Check Report
Murphy USA Store #7498
1209 1st Avenue North
Conover, NC 28613

Page i

Site Check Report
Murphy USA Store #7498
1209 1st Avenue North
Conover, NC 28613
Prepared for:
Murphy Oil USA, Inc.
200 E. Peach Street
PO Box 7300
El Dorado, AR 71731
Prepared by:
Groundwater & Environmental Services, Inc.
104 Corporate Boulevard - Suite 411
West Columbia, SC 29169
TEL: [phone]
www.gesonline.com

GES Project:
2702082
Date:
February 19, 2024

Daniel Dabkowski
Senior Project Manager
This document is intended only for the use or the
individual or entity for which it was prepared and may
contain information that is privileged, confidential, and
exempt from disclosure under applicable law. Any
dissemination, distribution, or copying of this document is
strictly prohibited.

Mary Arnold
Project Scientist

Site Check Report
Murphy USA Store #7498
1209 1st Avenue North
Conover, NC 28613

Page ii

Figures
Figure 1 – Site Location Map
Figure 2 – Site Map
Figure 3 – Soil Sample Location Map
Figure 4 – Soil Analytical Data Map

Tables
Table 1 – Site History – UST Owner Information
Table 2 – UST System and Other Release Information
Table 3 – Summary of Analytical Results

Appendices
Appendix A – NCDEQ Correspondence
Appendix B – UST Spill Bucket Integrity Testing Form
Appendix C – Soil Boring Logs
Appendix D – Analytical Laboratory Report

Site Check Report
Murphy USA Store #7498
1209 1st Avenue North
Conover, NC 28613

Page 1

Introduction
Groundwater and Environmental Services, Inc. (GES), on behalf of Murphy Oil USA, Inc. (Murphy)
is pleased to provide this Site Check Report summarizing the site check activities completed at
Murphy USA Store #7498, located at 1209 1st Avenue North, in Conover, North Carolina, 28613.
A Site Location Map is included as Figure 1. A map of the site is included as Figure 2.
Site assessment activities were performed in response to the Notice of Regulatory Requirements
(NORR) issued by the North Carolina Department of Environmental Quality (NCDEQ) on
November 29, 2023, for the suspected petroleum release that was originally reported on
September 28, 2023. The NORR directing is included in Appendix A.

Background Information
The site is identified as NCDEQ underground storage tank (UST) Facility ID 00-0-0000038050.
No prior releases have been reported for this site. The site is an active Murphy USA retail
petroleum station distributing gasoline and diesel fuel. One (1) 20,000-gallon regular unleaded
gasoline UST and one (1) compartmentalized 20,000-gallon (8,000-gallon premium, 12,000-
gallon diesel) UST are present at the site. Owner information and UST system information is
summarized in Table 1 and Table 2.
A suspected release was reported for the site on September 28, 2023, after the premium gasoline
spill bucket was found damaged. Guardian Fueling Technologies of Charlotte, North Carolina
subsequently replaced the premium spill bucket, and on December 29, 2023, the newly installed
premium spill bucket passed UST Spill Bucket Hydrostatic/Vacuum Integrity Testing. The
completed NCDEQ UST6D/23A Form is included as Appendix B.

Soil Boring/Site Check Activities
On January 12, 2024, GES provided subcontractor oversight while Taylor Wiseman & Taylor, Inc.
(TWT) performed a private utility locate in the vicinity of the UST system and proposed boring
locations. A North Carolina licensed well drilling contractor, Versatile Environmental Resource
Company, Inc. (VERCO) was also onsite to advance the proposed soil borings with a Geoprobe
Direct Push Technology (DPT) drill rig, but due to a damaged hydraulic line they were unable to
use the Geoprobe. Using stainless-steel hand augers, VERCO personnel hand-cleared three (3)
soil borings to 8-feet below ground surface (bgs) as close as reasonably possible to the
UST/sumps. A site map depicting the boring locations is provided as Figure 3.

On January 15, 2024, GES personnel and VERCO mobilized back to the site with the repaired
Geoprobe to complete site check activities. Three (3) soil borings (SB-1 through SB-3) were
advanced in the previously hand-cleared soil boring locations. In general, the soil borings were
located within the grass along the outer perimeter of the UST pit and advanced into native material
to a terminal depth of approximately 15-ft bgs in SB-2 and SB-3, and to a terminal depth of 30-ft
bgs in SB-1. Soil samples were collected at select intervals for classification, field screening,
and potential laboratory analysis.
Site Check Report
Murphy USA Store #7498
1209 1st Avenue North
Conover, NC 28613

Page 2

Recovered soils were split for field screening and laboratory analysis. The portion utilized for field
screening was placed in a sealable air-tight bag with head space and allowed to volatilize for
approximately 15-minutes at an ambient temperature of approximately 68 degrees Fahrenheit
(°F). Field screening was accomplished by using a Honeywell MiniRAE 3000+ photo-ionization
detector (PID) calibrated to a 100-parts per million (ppm) isobutylene standard. The tip of the PID
was used to pierce the bag and the maximum response was recorded as the headspace was
withdrawn.

The portion of recovered soils utilized for laboratory analysis was placed into laboratory provided
sample containers, labeled with indelible ink, entered into chain-of-custody, and immediately
placed into a cooler maintained at approximately 4 degrees Celsius (°C). The samples were
transported under standard chain-of-custody protocol to SGS Labs North America Inc. (SGS) of
Scott, Louisiana.

The native soil type encountered was sandy clay and groundwater was not encountered within
any of the soil borings. One (1) soil sample for laboratory analysis was collected from both soil
borings SB-2 and SB-3. Since groundwater was not encountered in any of the soil borings, SB-1
was advanced to a terminal depth of 30-ft bgs. Two (2) soil samples for laboratory analysis were
collected from soil boring SB-1. Soil boring logs are provided in Appendix C.

The soil samples were analyzed for volatile organic compounds (VOCs) via US Environmental
Protection Agency (EPA) Method 8260D and Polycyclic Aromatic Hydrocarbons (PAHs) via EPA
Method 8015. The analytical results were below NCDEQ action levels. The analytical results are
summarized in Table 3. A copy of the laboratory analytical report and chain-of-custody
documentation is included in Appendix D and the analytical data with respect to the soil sample
locations is included on Figure 4.
Please contact me at [phone] extension 4523 if you have any questions or concerns.

Sincerely,

Groundwater and Environmental Services, Inc.
Class I Site Rehabilitation Contractor No. 330

Daniel Dabkowski
Senior Project Manager

Site Check Report
Murphy USA Store #7498
1209 1st Avenue North
Conover, NC 28613

Page 3

Site Information
Site Identification
Facility I.D.: 00-0-0000038050
Site Name: Murphy USA Store #7498
Risk Classification: Not Assigned
Land Use Classification: Commercial
Address: 1209 1st Avenue North, Conover, NC 28613
State: North Carolina
County: Catawba
Latitude: 35.725028º (For Official Use Only)
Longitude: -81.210816º (For Official Use Only)

Contact Information Associated with the Release
Site Contact:
Ryan Pederson, P.G.
Remediation and Environmental Risk Manager
200 E Peach Street
PO Box 7300
El Dorado, AR 71731
303-817-9262
Tank Owner:
Murphy Oil USA, Inc.
200 E. Peach Street
PO Box 7300
El Dorado, AR 71731
870-875-7600

Property Owner:
Murphy Oil USA, Inc.
Site Check Report
Murphy USA Store #7498
1209 1st Avenue North
Conover, NC 28613

Page 4

200 E. Peach Street
PO Box 7300
El Dorado, AR 71731
870-875-7600
Consultant/Contractor:
Groundwater & Environmental Services, Inc.
104 Corporate Boulevard - Suite 411
West Columbia, SC 29169
866-765-4851

Site Check Report
Murphy USA Store #7498
1209 1st Avenue North
Conover, NC 28613

Figures

Site Location Map
Quadrangle Location
SITE
Source:
USGS 7.5 Minute Series
Topographic Quadrangle,
Newton, North Carolina
Contour Interval =
1993
20'
Designed
Approved
Scale In Feet
0 2000
Drawn
N
Figure 1
Date
Groundwater & Environmental Services, Inc.
North Carolina
E.V.02/02/24
Murphy Oil USA, Inc. MUSA Store #74981209 1st Avenue North Conover, NC 28613
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Site Map
Scale In Feet (Approximate)
0 30
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Groundwater & Environmental Services, Inc.
Designed
Approved
E.V.
Drawn
Figure 2
02/02/24
Date
Murphy Oil USA, Inc.MUSA Store #74981209 1st Avenue North Conover, NC 28613
Source:
GreenbergFarrow, Site Plan, Date: 12-07-11.
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Soil Sample Location Map
Scale In Feet (Approximate)
0 30
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Groundwater & Environmental Services, Inc.
Designed
Approved
E.V.
Drawn
Figure 3
02/02/24
Date
Murphy Oil USA, Inc.MUSA Store #74981209 1st Avenue North Conover, NC 28613
Source:
GreenbergFarrow, Site Plan, Date: 12-07-11.
SB-3
SB-2
SB-1
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Scale In Feet (Approximate)
0 30
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Groundwater & Environmental Services, Inc.
Designed
Approved
E.V.
Drawn
Figure 4
02/02/24
Date
Murphy Oil USA, Inc.
MUSA Store #74981209 1st Avenue North Conover, NC 28613
Source:
GreenbergFarrow, Site Plan, Date: 12-07-11.
SB-3
SB-2
SB-1
Soil Analytical Data Map
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Site Check Report
Murphy USA Store #7498
1209 1st Avenue North
Conover, NC 28613

Tables

Site Check Report
Murphy USA Store #7498
1209 1st Avenue North, Conover, NC 28613
UST ID Number 1, 2A & 2B Facility ID Number 00-0-0000038050
City State Zip Telephone Number
El Dorado AR 71730 [phone]
City State Zip Telephone Number
El Dorado AR 71730 [phone]
Incident Number None Date Incident Occurred N/A
Date Incident Report N/A
Date Incident Closed N/A
TABLE 1
SITE HISTORY - UST OWNER / OPERATOR & OTHER RESPONSIBLE PARTY INFORMATION
Name of Owner Dates of Operation (MM/DD/YY to MM/DD/YY)
Street Address
Name of Operator Dates of Operation (MM/DD/YY to MM/DD/YY)
Street Address
Other Incidents Onsite or Commingled/In Close Proximity
N/A
Street Address
Privileged and Confidential Page 1 of 3
Site Check Report
Murphy USA Store #7498
1209 1st Avenue North, Conover, NC 28613
UST ID
Number
Current/Last
Contents
Previous
Contents
Capacity
(gallons)
Construction
Details
Tank
Dimensions
(feet)
Description of
Associated Piping
and Pumps Installed*UST
Was Release
Associated with
the UST
System?
1 Gasoline (Regular)N/A 20,000 DW FRP Unknown DW Poly/Pressure 12/2012 Active No
2A Gasoline (Premium)N/A 8,000 DW FRP Unknown DW Poly/Pressure 12/2012 Active Yes
2B Diesel N/A 12,000 DW FRP Unknown DW Poly/Pressure 12/2012 Active No
AST ID
Number
Current/Last
Contents
Previous
Contents
Capacity
(gallons)
Construction
Details
Tank
Dimensions
Description of
Associated Piping
and Pumps Installed AST
Was Release
Associated with
the AST System?
Number Material Released Date of Release
N/A N/A 9/26/2023
Notes:
FRP = Fiberglass Reinforced Plastic
DW = Double Wall
TABLE 2
UST SYSTEM AND OTHER RELEASE INFORMATION
Descrtiption of Release
09/28/23: Suspected release reported due to the premium spill bucket being in active alarm mode from a
damaged liner.
Privileged and Confidential Page 2 of 3
Site Check Report
Murphy USA Store #7498
1209 1st Avenue North, Conover, NC 28613
Sample ID
Sample
(ft BGS)
Sample
Date
SB-1 12-14'1/15/2024 <5.3 2.45 J 0.0360 J <0.00038 0.0066 J <0.00050 <0.00035 <0.00020 <0.0011 <0.0022
SB-1 30'1/15/2024 <4.6 2.00 J <0.22 <0.020 <0.076 <0.026 0.0324 J <0.010 <0.057 <0.11
SB-2 12-14'1/15/2024 <5.0 <1.9 <0.23 <0.020 <0.079 <0.027 0.0205 J <0.011 <0.059 <0.12
NOTES:
Units are milligrams per kilogram (mg/kg = parts per million) unless otherwise noted
MSCC = Maximum Soil Contaminant Concentration per NCDEQ DWM UST Section Corrective Action Guidelines Tables
BGS = Below Ground Surface
TPH = Total Petroleum Hydrocarbons
GRO = Gasoline Range Organics
DRO = Diesel Range Organics
COC = Contaminant of Concern
J = Indicates an estimated value
Table 3
Summary of Soil Analytical Results
Analytical Method →EPA 8015 EPA 8260
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Residential MSCC
Commercial/Industrial MSCC
COC →
TP
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Soil-to-Water MSCC
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Privileged and Confidential Page 3 of 3
Site Check Report
Murphy USA Store #7498
1209 1st Avenue North
Conover, NC 28613

Appendix A – NCDEQ Correspondence

North Carolina Department of Environmental Quality | Division of Waste Management Mooresville Regional Office | 610 East Center Avenue | Suite 301 | Mooresville, NC 28115 | [phone]
November 29, 2023
Murphy USA
200 East Peach Street
El Dorado, Arkansas 71731
Attention: Stephen Powlus
Re: Notice of Regulatory Requirements 15A NCAC 02N .0601 and .0603
Investigation and Confirmation of a Suspected
Release from an Underground Storage Tank
Murphy Express 7498
1209 North Carolina Highway 16
Catawba County
Facility ID#: 00-0-0000038050
Dear Mr. Powlus:
The information received by the Mooresville Regional Office of the UST Section, Division of Waste
Management, on November 27, 2023 indicates the potential for a suspected release onsite based upon
monitoring results from an approved release detection method that indicate a release may have occurred.
Records indicate that you are the owner or operator of this UST system. Therefore, you must immediately
investigate to confirm the suspected release pursuant to Title 15A NCAC 02N .0603. To achieve
compliance with this rule, you must collect a soil sample beneath the spill bucket, if possible. Otherwise,
a groundwater sample must be collected as close to the spill bucket as possible.
The results of the site check must be received by this office within 30 days of the date of this notice.
If a release or discharge is confirmed, a Licensed Geologist or a Professional Engineer, certified by the
State of North Carolina, is required to prepare, and certify all reports submitted to the Department of
Environmental Quality in accordance with Title 15A NCAC 02L .0103(e) and 02L .0111(e).
Failure to comply in the manner and time specified may result in the assessment of civil penalties
and/or the use of other enforcement mechanisms.
Please note that the aforementioned site investigation efforts described above are routine leak detection
procedures required by rule and are not eligible for reimbursement from the Commercial Leaking Petroleum
Underground Storage Tank Cleanup Fund (Trust Fund) reimbursement under North Carolina General
Statute (G.S.) 143-205.94B(b)(8), (except for portions that are applicable for incorporation into a separate,
eligible phase of work, such as an Initial Abatement Action or Limited Site Assessment, etc.). If you have
any questions regarding Trust Fund eligibility or reimbursement, please contact the UST Section Trust Fund
Branch at [phone].
Page 2 of 2 November 29, 2023
North Carolina Department of Environmental Quality | Division of Waste Management Mooresville Regional Office | 610 East Center Avenue | Suite 301 | Mooresville, NC 28115 | [phone]
If you have any questions regarding the actions that must be taken or the rules mentioned in this letter,
please contact me at the address or telephone number listed below.
Sincerely,
Brad C. Newton, P.G.
Hydrogeologist Mooresville Regional Office
UST Section, Division of Waste Management, NCDEQ
cc: Catawba County Health Department
Mary Arnold – GES (via e-mail)
Site Check Report
Murphy USA Store #7498
1209 1st Avenue North
Conover, NC 28613

Appendix B - UST Spill Bucket Integrity Testing Form

UST-6D/23A Triennial UST Spill Bucket Integrity Testing
NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY, DIVISION OF WASTE MANAGEMENT, UST SECTION
1646 MAIL SERVICE CENTER, RALEIGH, NC 27699-1646 PHONE [phone] FAX [phone] http://www.wastenotnc.org/11/2022
Page 1 (Hydrostatic/Vacuum Test)
· If any periodic test fails, a suspected release report must be submitted on a UST-17A form, UST Suspected Release 24 Hour Notice. The suspected
release must be investigated, in accordance with 15A NCAC 2N .0603, and defective equipment repaired or replaced in accordance with 15A NCAC 2N .0404/.0900. Results of the investigation must be submitted on a UST-17B form, UST Suspected Release 7 Day Notice.
· The primary containment and interstitial space of the spill bucket shall be tested in accordance with the manufacturer's written guidelines, PEI/RP100
“Recommended Practices for Installation of Underground Liquid Storage Systems” and/or PEI/RP1200 “Recommended Practices for the Testing and Verification of Spill, Overfill, Leak Detection and Secondary Containment Equipment at UST Facilities.”
· The primary and secondary walls are both considered to be tested at the same time if vacuum is used to test the interstice.
UST FACILITY
Owner / Operator Name Facility IDFacility Name
Facility Street Address Facility City County
TESTING CONTRACTOR INFORMATION
Company Name Phone Email address
I certify, under penalty of law, that the testing data provided on this form documents the UST system equipment was tested in accordance with the manufacturer's guidelines and the applicable national industry standards listed in 15A NCAC 2N .406 and/or 15A NCAC 2N .0900.
Print Name of person conducting inspection Signature of person conducting inspection Test Date
Identify Spill Bucket (By Tank Number, Stored Product, etc.)Tank #Tank #Tank #Tank #Tank #
Tank Size
Product
Indicate units for all measurements
Bucket Manufacturer/Model
Bucket Depth
Construction SW DW SW DW SW DW SW DW SW DW
Bucket Installation Type
Direct Bury
Direct Bury w/Liner
Containment sump
Direct Bury
Direct Bury w/Liner
Containment sump
Direct Bury
Direct Bury w/Liner
Containment sump
Direct Bury
Direct Bury w/Liner
Containment sump
Direct Bury
Direct Bury w/Liner
Containment sump
Test Type Hydrostatic
Vacuum
Hydrostatic
Vacuum
Hydrostatic
Vacuum
Hydrostatic
Vacuum
Hydrostatic
Vacuum
Liquid and debris removed from spill
bucket?Yes No Yes No Yes No Yes No Yes No
Visual inspection (No cracks, loose parts or separation of the bucket from the fill pipe.)Pass Fail Pass Fail Pass Fail Pass Fail Pass Fail
Tank riser cap included in test?Yes No
N/A
Yes No
N/A
Yes No
N/A
Yes No
N/A
Yes No
N/A
Drain valve included in test?Yes No
N/A
Yes No
N/A
Yes No
N/A
Yes No
N/A
Yes No
N/A
Wait time between applying vacuum/water and start of test
Primary Section Test Hydrostatic: Water level must be within 1.5 inches of top of bucket Vacuum: Apply vacuum of 30 inches WC
Begin End Test Time
Begin End Reading
Secondary Interstice Test Vacuum: Apply vacuum of 15 inches WC Gauge Range (with units):
Begin End Test Time
Begin End Reading
Pass/fail criteria: Must pass visual inspection. Pass if: Hydrostatic: Water level drop of less than 1/8 inch in 1 hour; Vacuum single-walled only:
Maintain at least 26 inches water column for 1 minute; Vacuum double-walled: Maintain at least 12 inches water column for 1 minute
Test Results Pass Fail Pass Fail Pass Fail Pass Fail Pass Fail
Comments - (include information on repairs made prior to testing, and recommended follow-up for failed tests)
Date next Spill Bucket integrity test due (required every 3 years)
MURPHY OIL USA, INC.MURPHY EXPRESS 7498 00-0-0000038050
1209 NC 16 Highway CONOVER Catawba
Guardian Fueling Technologies 704-394-3178 [e-mail]
Zachary Coley 12/29/2023
3
8,000 gallons
Premium
EMCO A1004EVR
13"
XX
X
X
X
X
X
1 minute
2:09pm 2:10pm
15"13"
x
12/29/2026
Site Check Report
Murphy USA Store #7498
1209 1st Avenue North
Conover, NC 28613

Appendix C – Soil Boring Logs

Split Spoon/Acetate Sleeve Length:
Logged By:
Completion Date:
Split Spoon/Acetate Sleeve Dia:
Drill Operator: Drilling Method:
Drill Rig Type: Sampling Method:
Soil Classification System:
Field Screening:
Address:
County:
Surface Elevation: Abandonment Method:
Total Depth: Depth to Water: Backfill Material:
Refusal Depth: Well Diameter: Abandonment Completion Date:
(inches)
Depth
(feet)
Sample
Interval
Recovery Field Screen(ppm)Detail
Blow Counts
Drilling Company:
Borehole Diameter:
CommentsGeologic Description
Project:
Client:
GES Project Mgr:
SOIL BORING LOG
ID NO.Page 1 of 1Groundwater & Environmental Services, Inc.SB-1
Murphy Station #7498
1209 North Carolina Highway 16, Conover, North Carolina
Catawba County
Murphy USA
Daniel Dabkowski
Lauren Jenkins/Baker West
VERCO Management Co.
Jason Chiorazzi
Geoprobe
01/15/2024
Direct Push
Macro-Core
1.875"
24"
USCS
PID 10.6 eV Lamp (ppm)
6 in.
30 fbg N/A
NA
Backfilled
#1 Sand
01/15/2024
Abandonment
501
N/A
N/A
Dates Drilled:01/12/2024
100000
GES Job Number:2702082
Symbol Legend
Lab Sample Location
Apparent Water Level
Blow Count Pentration Resistance:Proportions Used:
Consistency (M&C) Density (G&S)Notes:
SB-1 p. 1 of 1
4-10 = Loose
0-4 = Very Loose
10-30 = Medium
30-50 = Dense
50> = Very Dense
NA = not available; fbg = feet below grade
in. = inches; ft.= feet; ppm = parts per million <2 = Very Soft
2-4 = Soft
4-8 = Medium
8-15 = Stiff
15-30 = Very Stiff
>30 = Hard
Trace = <5%
Few = 5-10%
Little = 10-20%
Some = 20-30%
Adjective = 30-40%
And = >40%
N/A = not applicable; EOB = end of boring
Soil lithology based on field observations only.
Sampled From
12-14'
Sampled at 30'EOB at 30'
SB-1
(12-14')
SB-1 (30')
0.0
0.0
2.0
0.0
0.0
0.0
0.1
0.2
0.0
0.0
0.0
0.0
1 2650
Top Soil: (0.0-2.0"): Top Soil
Sand: (2.0"-2.0'): Reddish brown, fine to coarseSAND, trace gravel
Fill: (2.0-6.0'): FILL - pea gravel
Sand: (6.0-8.0'): Reddish brown, fine to
medium-graned SAND, some silt, trace gravel;
moist
Sandy Clay: (8.0-10'): SANDY CLAY
Sand: (10.0-12.0'): Brown SAND
Sandy Clay: (12.0-15.0'): SANDY CLAY
Clay: (15.0-17.0'): Orange CLAY
Sandy Clay: (17.0-19.0'): SANDY CLAY
Clay: (19.0-21.0'):Orange CLAY
Sandy Clay: (21.0-25.0'): SANDY CLAY
Sand: (25.0-30.0'): Brown SAND
0
5
10
15
20
25
30
#1 Sand
Split Spoon/Acetate Sleeve Length:
Logged By:
Completion Date:
Split Spoon/Acetate Sleeve Dia:
Drill Operator: Drilling Method:
Drill Rig Type: Sampling Method:
Soil Classification System:
Field Screening:
Address:
County:
Surface Elevation: Abandonment Method:
Total Depth: Depth to Water: Backfill Material:
Refusal Depth: Well Diameter: Abandonment Completion Date:
(inches)
Depth
(feet)
Sample
Interval
Recovery Field Screen(ppm)Detail
Blow Counts
Drilling Company:
Borehole Diameter:
CommentsGeologic Description
Project:
Client:
GES Project Mgr:
SOIL BORING LOG
ID NO.Page 1 of 1Groundwater & Environmental Services, Inc.SB-2
Murphy Station #7498
1209 North Carolina Highway 16, Conover, North Carolina
Catawba County
Murphy USA
Daniel Dabkowski
Lauren Jenkins/Baker West
VERCO Management Co.
Jason Chiorazzi
Geoprobe
01/15/2024
Direct Push
Macro-Core
1.875"
24"
USCS
PID 10.6 eV Lamp (ppm)
6 in.
15 fbg N/A
NA
Backfilled
#1 Sand
01/15/2024
Abandonment
501
N/A
N/A
Dates Drilled:01/12/2024
100000
GES Job Number:2702082
Symbol Legend
Lab Sample Location
Apparent Water Level
Blow Count Pentration Resistance:Proportions Used:
Consistency (M&C) Density (G&S)Notes:
SB-2 p. 1 of 1
4-10 = Loose
0-4 = Very Loose
10-30 = Medium
30-50 = Dense
50> = Very Dense
NA = not available; fbg = feet below grade
in. = inches; ft.= feet; ppm = parts per million <2 = Very Soft
2-4 = Soft
4-8 = Medium
8-15 = Stiff
15-30 = Very Stiff
>30 = Hard
Trace = <5%
Few = 5-10%
Little = 10-20%
Some = 20-30%
Adjective = 30-40%
And = >40%
N/A = not applicable; EOB = end of boring
Soil lithology based on field observations only.
Sampled From
12-14'
EOB at 15'
SB-2
(12-14')
0.0
0.2
0.8
1.0
1 2650
Top Soil: (0.0-2.0"): TOP SOIL
Sand: (2.0"-4.5'): Reddish brown, fine to medium-grained SAND, some silt, trace fine to
medium-grained gravel; moist
Fill: (4.5-8.0'): FILL - pea gravel
Sandy Clay: (8.0-10'): SANDY CLAY
Sand: (10.0-14.0'): Brown SAND
Clay: (14.0-15.0'): CLAY
0
5
10
15
#1 Sand
Split Spoon/Acetate Sleeve Length:
Logged By:
Completion Date:
Split Spoon/Acetate Sleeve Dia:
Drill Operator: Drilling Method:
Drill Rig Type: Sampling Method:
Soil Classification System:
Field Screening:
Address:
County:
Surface Elevation: Abandonment Method:
Total Depth: Depth to Water: Backfill Material:
Refusal Depth: Well Diameter: Abandonment Completion Date:
(inches)
Depth
(feet)
Sample
Interval
Recovery Field Screen(ppm)Detail
Blow Counts
Drilling Company:
Borehole Diameter:
CommentsGeologic Description
Project:
Client:
GES Project Mgr:
SOIL BORING LOG
ID NO.Page 1 of 1Groundwater & Environmental Services, Inc.SB-3
Murphy Station #7498
1209 North Carolina Highway 16, Conover, North Carolina
Catawba County
Murphy USA
Daniel Dabkowski
Lauren Jenkins/Baker West
VERCO Management Co.
Jason Chiorazzi
Geoprobe
01/15/2024
Direct Push
Macro-Core
1.875"
24"
USCS
PID 10.6 eV Lamp (ppm)
6 in.
15 fbg N/A
NA
Backfilled
#1 Sand
01/15/2024
Abandonment
501
N/A
N/A
Dates Drilled:01/12/2024
100000
GES Job Number:2702082
Symbol Legend
Lab Sample Location
Apparent Water Level
Blow Count Pentration Resistance:Proportions Used:
Consistency (M&C) Density (G&S)Notes:
SB-3 p. 1 of 1
4-10 = Loose
0-4 = Very Loose
10-30 = Medium
30-50 = Dense
50> = Very Dense
NA = not available; fbg = feet below grade
in. = inches; ft.= feet; ppm = parts per million <2 = Very Soft
2-4 = Soft
4-8 = Medium
8-15 = Stiff
15-30 = Very Stiff
>30 = Hard
Trace = <5%
Few = 5-10%
Little = 10-20%
Some = 20-30%
Adjective = 30-40%
And = >40%
N/A = not applicable; EOB = end of boring
Soil lithology based on field observations only.
Sampled From 10-12'
EOB at 15'
SB-3 (10-12')
0.0
0.0
1.1
0.2
0.0
1 2650
Top Soil: (0.0-2.0"): TOP SOIL
Sand: (2.0"-2.0'): Reddish brown, fine to medium-grained SAND, some silt, trace fine
gravel; moist
Fill: (2.0-8.0'): FILL - pea gravel
Sandy Clay: (8.0-10'): SANDY CLAY
Sand: (10.0-14.0'): Brown SAND
Clay: (12.0-14.0'): Orange CLAY
Sandy Clay: (14.0-15.0'): SANDY CLAY
0
5
10
15
#1 Sand
Site Check Report
Murphy USA Store #7498
1209 1st Avenue North
Conover, NC 28613

Appendix D – Laboratory Analytical Report

01/31/24
Technical Report for
Murphy Oil USA, Inc.
GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
SGS Job Number: LA97464
Sampling Date: 01/15/24
Report to:
GES
104 Corporate Blvd Suite 411
West Columbia, SC
[e-mail]; [e-mail]
ATTN: Daniel Dabkowski, Tom Chmura
Total number of pages in report:
Certifications: LDEQ(2048), LDHH(LA150012), AR(14-045-04), AZ(AZ0805), FL(E87657), IL(200082), KY(#31),
NC(487), SC(73004001), NJ(LA007), TX(T104704186-18-16), WV(257)
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc.  500 Ambassador Caffery  Scott, LA 70583  tel: [phone]
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable unless noted
in the narrative, comments or footnotes.
Client Service contact: Suzanne Junkin 337-237-4775
Kesavalu Bagawandoss
Tech. Director North America
Scott, LA 01/31/24
e-Hardcopy 2.0
Automated Report
51
SGS is the sole authority for authorizing edits or modifications to this document.
Unauthorized modification of this report is strictly prohibited.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions
The results set forth herein are provided by SGS North America Inc.
Please share your ideas about
how we can serve you better at:
[e-mail]
1 of 51
LA97464
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................5
3.1: LA97464-1: SB-1 12-14' ..............................................................................................6
3.2: LA97464-2: SB-1 30' ....................................................................................................11
3.3: LA97464-3: SB-2 12-14' ..............................................................................................16
3.4: LA97464-4: SB-3 10-12' ..............................................................................................21
Section 4: Misc. Forms ............................................................................................................26
4.1: Chain of Custody ...........................................................................................................27
Section 5: MS Volatiles - QC Data Summaries .....................................................................30
5.1: Method Blank Summary ................................................................................................31
5.2: Blank Spike/Blank Spike Duplicate Summary ..............................................................35
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................39
Section 6: GC Volatiles - QC Data Summaries .....................................................................42
6.1: Method Blank Summary ................................................................................................43
6.2: Blank Spike/Blank Spike Duplicate Summary ..............................................................45
6.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................47
Section 7: GC/LC Semi-volatiles - QC Data Summaries .....................................................48
7.1: Method Blank Summary ................................................................................................49
7.2: Blank Spike/Blank Spike Duplicate Summary ..............................................................50
7.3: Matrix Spike Summary ..................................................................................................51
1
2
3
4
5
6
7
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LA97464
SGS North America Inc.
Sample Summary
Murphy Oil USA, Inc.
Job No:LA97464
GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
LA97464-1 01/15/24 13:15 01/23/24 SO Soil SB-1 12-14'
LA97464-2 01/15/24 13:40 01/23/24 SO Soil SB-1 30'
LA97464-3 01/15/24 12:50 01/23/24 SO Soil SB-2 12-14'
LA97464-4 01/15/24 12:30 01/23/24 SO Soil SB-3 10-12'
Soil samples reported on a dry weight basis unless otherwise indicated on result page.
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LA97464
1
Summary of Hits Page 1 of 1
Job Number:LA97464
Account:Murphy Oil USA, Inc.
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
Collected:01/15/24
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
LA97464-1 SB-1 12-14'
Acetone 0.0360 J 0.096 0.0043 mg/kg SW846 8260D
Methyl Ethyl Ketone 0.0066 J 0.024 0.0015 mg/kg SW846 8260D
TPH-DRO (C10-C28)2.45 J 6.7 1.9 mg/kg SW846 8015C
LA97464-2 SB-1 30'
Toluene a 0.0324 J 0.50 0.018 mg/kg SW846 8260D
TPH-DRO (C10-C28)2.00 J 6.5 1.9 mg/kg SW846 8015C
LA97464-3 SB-2 12-14'
Toluene a 0.0205 J 0.51 0.019 mg/kg SW846 8260D
LA97464-4 SB-3 10-12'
Toluene a 0.0335 J 0.53 0.019 mg/kg SW846 8260D
(a) Sample analyzed beyond hold time.
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Sample Results
Report of Analysis
Scott, LA
Section 3
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3
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Report of Analysis Page 1 of 3
Client Sample ID:SB-1 12-14'
Lab Sample ID:LA97464-1 Date Sampled:01/15/24
Matrix:SO - Soil Date Received:01/23/24
Method:SW846 8260D SW846 5035 Percent Solids:74.6
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1I110209.D 1 01/25/24 18:57 JY 01/24/24 12:49 n/a V1I4078
Run #2
Initial Weight
Run #1 3.5 g
Run #2
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone 0.0360 0.096 0.0043 mg/kg J
71-43-2 Benzene 0.00038 U 0.00096 0.00038 mg/kg
108-86-1 Bromobenzene 0.00058 U 0.0019 0.00058 mg/kg
74-97-5 Bromochloromethane 0.00052 U 0.0019 0.00052 mg/kg
75-27-4 Bromodichloromethane 0.00061 U 0.0019 0.00061 mg/kg
75-25-2 Bromoform 0.0015 U 0.0019 0.0015 mg/kg
104-51-8 n-Butylbenzene a 0.00062 U 0.0096 0.00062 mg/kg
135-98-8 sec-Butylbenzene 0.00063 U 0.0096 0.00063 mg/kg
98-06-6 tert-Butylbenzene 0.00055 U 0.0019 0.00055 mg/kg
56-23-5 Carbon Tetrachloride 0.00075 U 0.0019 0.00075 mg/kg
108-90-7 Chlorobenzene 0.00047 U 0.0019 0.00047 mg/kg
75-00-3 Chloroethane 0.00065 U 0.0019 0.00065 mg/kg
67-66-3 Chloroform 0.00050 U 0.0019 0.00050 mg/kg
95-49-8 o-Chlorotoluene 0.00094 U 0.0096 0.00094 mg/kg
106-43-4 p-Chlorotoluene 0.00012 U 0.0096 0.00012 mg/kg
124-48-1 Dibromochloromethane 0.00055 U 0.0019 0.00055 mg/kg
106-93-4 1,2-Dibromoethane 0.0011 U 0.0019 0.0011 mg/kg
75-71-8 Dichlorodifluoromethane 0.0013 U 0.0019 0.0013 mg/kg
541-73-1 m-Dichlorobenzene 0.00061 U 0.0019 0.00061 mg/kg
95-50-1 o-Dichlorobenzene 0.00037 U 0.0019 0.00037 mg/kg
106-46-7 p-Dichlorobenzene 0.00050 U 0.0019 0.00050 mg/kg
75-34-3 1,1-Dichloroethane 0.00043 U 0.0019 0.00043 mg/kg
107-06-2 1,2-Dichloroethane 0.00042 U 0.0019 0.00042 mg/kg
75-35-4 1,1-Dichloroethylene 0.00078 U 0.0019 0.00078 mg/kg
156-59-2 cis-1,2-Dichloroethylene 0.00060 U 0.0019 0.00060 mg/kg
156-60-5 trans-1,2-Dichloroethylene 0.00039 U 0.0019 0.00039 mg/kg
78-87-5 1,2-Dichloropropane 0.00024 U 0.0019 0.00024 mg/kg
142-28-9 1,3-Dichloropropane 0.00045 U 0.0019 0.00045 mg/kg
594-20-7 2,2-Dichloropropane 0.00066 U 0.0019 0.00066 mg/kg
563-58-6 1,1-Dichloropropene 0.00063 U 0.0019 0.00063 mg/kg
10061-01-5 cis-1,3-Dichloropropene 0.00045 U 0.0019 0.00045 mg/kg
10061-02-6 trans-1,3-Dichloropropene 0.00050 U 0.0019 0.00050 mg/kg
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 of 51
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Report of Analysis Page 2 of 3
Client Sample ID:SB-1 12-14'
Lab Sample ID:LA97464-1 Date Sampled:01/15/24
Matrix:SO - Soil Date Received:01/23/24
Method:SW846 8260D SW846 5035 Percent Solids:74.6
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 0.00028 U 0.0019 0.00028 mg/kg
64-17-5 Ethyl Alcohol 0.047 U 0.77 0.047 mg/kg
100-41-4 Ethylbenzene 0.00050 U 0.0019 0.00050 mg/kg
591-78-6 2-Hexanone 0.0013 U 0.024 0.0013 mg/kg
98-82-8 Isopropylbenzene 0.00054 U 0.0096 0.00054 mg/kg
99-87-6 p-Isopropyltoluene 0.00065 U 0.0096 0.00065 mg/kg
74-83-9 Methyl Bromide 0.0030 U 0.019 0.0030 mg/kg
74-87-3 Methyl Chloride 0.00057 U 0.0096 0.00057 mg/kg
75-09-2 Methylene Chloride 0.0011 U 0.0096 0.0011 mg/kg
78-93-3 Methyl Ethyl Ketone 0.0066 0.024 0.0015 mg/kg J
108-10-1 4-Methyl-2-pentanone 0.00099 U 0.024 0.00099 mg/kg
1634-04-4 Methyl Tert Butyl Ether 0.00020 U 0.0019 0.00020 mg/kg
91-20-3 Naphthalene 0.0011 U 0.0096 0.0011 mg/kg
103-65-1 n-Propylbenzene 0.00082 U 0.0096 0.00082 mg/kg
100-42-5 Styrene 0.00028 U 0.0019 0.00028 mg/kg
630-20-6 1,1,1,2-Tetrachloroethane 0.00037 U 0.0019 0.00037 mg/kg
79-34-5 1,1,2,2-Tetrachloroethane 0.00029 U 0.0019 0.00029 mg/kg
127-18-4 Tetrachloroethylene 0.00066 U 0.0019 0.00066 mg/kg
108-88-3 Toluene 0.00035 U 0.0096 0.00035 mg/kg
87-61-6 1,2,3-Trichlorobenzene 0.00062 U 0.0096 0.00062 mg/kg
120-82-1 1,2,4-Trichlorobenzene 0.00039 U 0.0096 0.00039 mg/kg
71-55-6 1,1,1-Trichloroethane 0.00067 U 0.0019 0.00067 mg/kg
79-00-5 1,1,2-Trichloroethane 0.00029 U 0.0019 0.00029 mg/kg
79-01-6 Trichloroethylene 0.00096 U 0.0019 0.00096 mg/kg
75-69-4 Trichlorofluoromethane 0.00069 U 0.0019 0.00069 mg/kg
96-18-4 1,2,3-Trichloropropane 0.00048 U 0.0096 0.00048 mg/kg
95-63-6 1,2,4-Trimethylbenzene 0.00073 U 0.0096 0.00073 mg/kg
108-67-8 1,3,5-Trimethylbenzene 0.00048 U 0.0096 0.00048 mg/kg
108-05-4 Vinyl Acetate 0.00068 U 0.0096 0.00068 mg/kg
75-01-4 Vinyl Chloride 0.00050 U 0.0019 0.00050 mg/kg
m,p-Xylene 0.00086 U 0.0038 0.00086 mg/kg
95-47-6 o-Xylene 0.00049 U 0.0019 0.00049 mg/kg
1330-20-7 Xylene (total)0.0022 U 0.0038 0.0022 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 91%59-143%
2037-26-5 Toluene-D8 96%52-159%
460-00-4 4-Bromofluorobenzene 100%38-183%
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
7 of 51
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Report of Analysis Page 3 of 3
Client Sample ID:SB-1 12-14'
Lab Sample ID:LA97464-1 Date Sampled:01/15/24
Matrix:SO - Soil Date Received:01/23/24
Method:SW846 8260D SW846 5035 Percent Solids:74.6
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
(a) Associated CCV outside of control limits high, sample was ND.
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
8 of 51
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3.
1
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-1 12-14'
Lab Sample ID:LA97464-1 Date Sampled:01/15/24
Matrix:SO - Soil Date Received:01/23/24
Method:SW846 8015C SW846 5035 Percent Solids:74.6
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LA431056.D 1 01/26/24 17:50 BC 01/24/24 12:49 n/a GLA4146
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 3.70 g 5.0 ml 100 ul
Run #2
CAS No.Compound Result RL MDL Units Q
TPH-GRO (C6-C10)5.3 U 11 5.3 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 103%64-128%
540-36-3 1,4-Difluorobenzene 110%80-122%
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 1
Client Sample ID:SB-1 12-14'
Lab Sample ID:LA97464-1 Date Sampled:01/15/24
Matrix:SO - Soil Date Received:01/23/24
Method:SW846 8015C SW846 3546 Percent Solids:74.6
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 X0026436.D 1 01/24/24 16:24 JT 01/24/24 08:00 OP24466 GLB2627
Run #2
Initial Weight Final Volume
Run #1 20.1 g 1.0 ml
Run #2
CAS No.Compound Result RL MDL Units Q
TPH-DRO (C10-C28)2.45 6.7 1.9 mg/kg J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
84-15-1 o-Terphenyl 81%31-127%
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 3
Client Sample ID:SB-1 30'
Lab Sample ID:LA97464-2 Date Sampled:01/15/24
Matrix:SO - Soil Date Received:01/23/24
Method:SW846 8260D SW846 5035 Percent Solids:77.5
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a 1J2140561.D 1 01/30/24 12:38 JY 01/24/24 12:49 n/a V1J5220
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 3.8 g 5.0 ml 100 ul
Run #2
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone 0.22 U 5.0 0.22 mg/kg
71-43-2 Benzene 0.020 U 0.050 0.020 mg/kg
108-86-1 Bromobenzene 0.030 U 0.099 0.030 mg/kg
74-97-5 Bromochloromethane 0.027 U 0.099 0.027 mg/kg
75-27-4 Bromodichloromethane 0.032 U 0.099 0.032 mg/kg
75-25-2 Bromoform 0.080 U 0.099 0.080 mg/kg
104-51-8 n-Butylbenzene 0.032 U 0.50 0.032 mg/kg
135-98-8 sec-Butylbenzene 0.033 U 0.50 0.033 mg/kg
98-06-6 tert-Butylbenzene 0.029 U 0.099 0.029 mg/kg
56-23-5 Carbon Tetrachloride 0.039 U 0.099 0.039 mg/kg
108-90-7 Chlorobenzene 0.025 U 0.099 0.025 mg/kg
75-00-3 Chloroethane 0.034 U 0.099 0.034 mg/kg
67-66-3 Chloroform 0.026 U 0.099 0.026 mg/kg
95-49-8 o-Chlorotoluene 0.049 U 0.50 0.049 mg/kg
106-43-4 p-Chlorotoluene 0.0065 U 0.50 0.0065 mg/kg
124-48-1 Dibromochloromethane 0.029 U 0.099 0.029 mg/kg
106-93-4 1,2-Dibromoethane 0.057 U 0.099 0.057 mg/kg
75-71-8 Dichlorodifluoromethane 0.065 U 0.099 0.065 mg/kg
541-73-1 m-Dichlorobenzene 0.032 U 0.099 0.032 mg/kg
95-50-1 o-Dichlorobenzene 0.019 U 0.099 0.019 mg/kg
106-46-7 p-Dichlorobenzene 0.026 U 0.099 0.026 mg/kg
75-34-3 1,1-Dichloroethane 0.023 U 0.099 0.023 mg/kg
107-06-2 1,2-Dichloroethane 0.022 U 0.099 0.022 mg/kg
75-35-4 1,1-Dichloroethylene 0.040 U 0.099 0.040 mg/kg
156-59-2 cis-1,2-Dichloroethylene 0.031 U 0.099 0.031 mg/kg
156-60-5 trans-1,2-Dichloroethylene 0.020 U 0.099 0.020 mg/kg
78-87-5 1,2-Dichloropropane 0.013 U 0.099 0.013 mg/kg
142-28-9 1,3-Dichloropropane 0.024 U 0.099 0.024 mg/kg
594-20-7 2,2-Dichloropropane 0.034 U 0.099 0.034 mg/kg
563-58-6 1,1-Dichloropropene 0.033 U 0.099 0.033 mg/kg
10061-01-5 cis-1,3-Dichloropropene 0.024 U 0.099 0.024 mg/kg
10061-02-6 trans-1,3-Dichloropropene 0.026 U 0.099 0.026 mg/kg
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 3
Client Sample ID:SB-1 30'
Lab Sample ID:LA97464-2 Date Sampled:01/15/24
Matrix:SO - Soil Date Received:01/23/24
Method:SW846 8260D SW846 5035 Percent Solids:77.5
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 0.014 U 0.099 0.014 mg/kg
64-17-5 Ethyl Alcohol 2.5 U 40 2.5 mg/kg
100-41-4 Ethylbenzene 0.026 U 0.099 0.026 mg/kg
591-78-6 2-Hexanone 0.065 U 1.2 0.065 mg/kg
98-82-8 Isopropylbenzene 0.028 U 0.50 0.028 mg/kg
99-87-6 p-Isopropyltoluene 0.034 U 0.50 0.034 mg/kg
74-83-9 Methyl Bromide 0.16 U 0.99 0.16 mg/kg
74-87-3 Methyl Chloride 0.030 U 0.50 0.030 mg/kg
75-09-2 Methylene Chloride 0.055 U 0.50 0.055 mg/kg
78-93-3 Methyl Ethyl Ketone 0.076 U 1.2 0.076 mg/kg
108-10-1 4-Methyl-2-pentanone 0.051 U 1.2 0.051 mg/kg
1634-04-4 Methyl Tert Butyl Ether 0.010 U 0.099 0.010 mg/kg
91-20-3 Naphthalene 0.057 U 0.50 0.057 mg/kg
103-65-1 n-Propylbenzene 0.042 U 0.50 0.042 mg/kg
100-42-5 Styrene 0.014 U 0.099 0.014 mg/kg
630-20-6 1,1,1,2-Tetrachloroethane 0.019 U 0.099 0.019 mg/kg
79-34-5 1,1,2,2-Tetrachloroethane 0.015 U 0.099 0.015 mg/kg
127-18-4 Tetrachloroethylene 0.034 U 0.099 0.034 mg/kg
108-88-3 Toluene 0.0324 0.50 0.018 mg/kg J
87-61-6 1,2,3-Trichlorobenzene 0.032 U 0.50 0.032 mg/kg
120-82-1 1,2,4-Trichlorobenzene 0.020 U 0.50 0.020 mg/kg
71-55-6 1,1,1-Trichloroethane 0.035 U 0.099 0.035 mg/kg
79-00-5 1,1,2-Trichloroethane 0.015 U 0.099 0.015 mg/kg
79-01-6 Trichloroethylene 0.050 U 0.099 0.050 mg/kg
75-69-4 Trichlorofluoromethane 0.036 U 0.099 0.036 mg/kg
96-18-4 1,2,3-Trichloropropane 0.025 U 0.50 0.025 mg/kg
95-63-6 1,2,4-Trimethylbenzene 0.038 U 0.50 0.038 mg/kg
108-67-8 1,3,5-Trimethylbenzene 0.025 U 0.50 0.025 mg/kg
108-05-4 Vinyl Acetate 0.035 U 0.50 0.035 mg/kg
75-01-4 Vinyl Chloride 0.026 U 0.099 0.026 mg/kg
m,p-Xylene 0.045 U 0.20 0.045 mg/kg
95-47-6 o-Xylene 0.026 U 0.099 0.026 mg/kg
1330-20-7 Xylene (total)0.11 U 0.20 0.11 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 89%59-143%
2037-26-5 Toluene-D8 96%52-159%
460-00-4 4-Bromofluorobenzene 100%38-183%
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 3 of 3
Client Sample ID:SB-1 30'
Lab Sample ID:LA97464-2 Date Sampled:01/15/24
Matrix:SO - Soil Date Received:01/23/24
Method:SW846 8260D SW846 5035 Percent Solids:77.5
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
(a) Sample analyzed beyond hold time.
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 1
Client Sample ID:SB-1 30'
Lab Sample ID:LA97464-2 Date Sampled:01/15/24
Matrix:SO - Soil Date Received:01/23/24
Method:SW846 8015C SW846 5035 Percent Solids:77.5
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LA431058.D 1 01/26/24 18:08 BC 01/24/24 12:49 n/a GLA4146
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 4.10 g 5.0 ml 100 ul
Run #2
CAS No.Compound Result RL MDL Units Q
TPH-GRO (C6-C10)4.6 U 9.3 4.6 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 104%64-128%
540-36-3 1,4-Difluorobenzene 111%80-122%
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 1
Client Sample ID:SB-1 30'
Lab Sample ID:LA97464-2 Date Sampled:01/15/24
Matrix:SO - Soil Date Received:01/23/24
Method:SW846 8015C SW846 3546 Percent Solids:77.5
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 X0026437.D 1 01/24/24 16:51 JT 01/24/24 08:00 OP24466 GLB2627
Run #2
Initial Weight Final Volume
Run #1 20.0 g 1.0 ml
Run #2
CAS No.Compound Result RL MDL Units Q
TPH-DRO (C10-C28)2.00 6.5 1.9 mg/kg J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
84-15-1 o-Terphenyl 84%31-127%
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Client Sample ID:SB-2 12-14'
Lab Sample ID:LA97464-3 Date Sampled:01/15/24
Matrix:SO - Soil Date Received:01/23/24
Method:SW846 8260D SW846 5035 Percent Solids:75.9
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a 1J2140563.D 1 01/30/24 13:48 JY 01/24/24 12:49 n/a V1J5220
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 3.8 g 5.0 ml 100 ul
Run #2
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone 0.23 U 5.1 0.23 mg/kg
71-43-2 Benzene 0.020 U 0.051 0.020 mg/kg
108-86-1 Bromobenzene 0.031 U 0.10 0.031 mg/kg
74-97-5 Bromochloromethane 0.028 U 0.10 0.028 mg/kg
75-27-4 Bromodichloromethane 0.033 U 0.10 0.033 mg/kg
75-25-2 Bromoform 0.082 U 0.10 0.082 mg/kg
104-51-8 n-Butylbenzene 0.033 U 0.51 0.033 mg/kg
135-98-8 sec-Butylbenzene 0.034 U 0.51 0.034 mg/kg
98-06-6 tert-Butylbenzene 0.030 U 0.10 0.030 mg/kg
56-23-5 Carbon Tetrachloride 0.040 U 0.10 0.040 mg/kg
108-90-7 Chlorobenzene 0.025 U 0.10 0.025 mg/kg
75-00-3 Chloroethane 0.035 U 0.10 0.035 mg/kg
67-66-3 Chloroform 0.027 U 0.10 0.027 mg/kg
95-49-8 o-Chlorotoluene 0.050 U 0.51 0.050 mg/kg
106-43-4 p-Chlorotoluene 0.0067 U 0.51 0.0067 mg/kg
124-48-1 Dibromochloromethane 0.030 U 0.10 0.030 mg/kg
106-93-4 1,2-Dibromoethane 0.059 U 0.10 0.059 mg/kg
75-71-8 Dichlorodifluoromethane 0.067 U 0.10 0.067 mg/kg
541-73-1 m-Dichlorobenzene 0.033 U 0.10 0.033 mg/kg
95-50-1 o-Dichlorobenzene 0.020 U 0.10 0.020 mg/kg
106-46-7 p-Dichlorobenzene 0.027 U 0.10 0.027 mg/kg
75-34-3 1,1-Dichloroethane 0.023 U 0.10 0.023 mg/kg
107-06-2 1,2-Dichloroethane 0.022 U 0.10 0.022 mg/kg
75-35-4 1,1-Dichloroethylene 0.042 U 0.10 0.042 mg/kg
156-59-2 cis-1,2-Dichloroethylene 0.032 U 0.10 0.032 mg/kg
156-60-5 trans-1,2-Dichloroethylene 0.021 U 0.10 0.021 mg/kg
78-87-5 1,2-Dichloropropane 0.013 U 0.10 0.013 mg/kg
142-28-9 1,3-Dichloropropane 0.024 U 0.10 0.024 mg/kg
594-20-7 2,2-Dichloropropane 0.035 U 0.10 0.035 mg/kg
563-58-6 1,1-Dichloropropene 0.034 U 0.10 0.034 mg/kg
10061-01-5 cis-1,3-Dichloropropene 0.024 U 0.10 0.024 mg/kg
10061-02-6 trans-1,3-Dichloropropene 0.027 U 0.10 0.027 mg/kg
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 3
Client Sample ID:SB-2 12-14'
Lab Sample ID:LA97464-3 Date Sampled:01/15/24
Matrix:SO - Soil Date Received:01/23/24
Method:SW846 8260D SW846 5035 Percent Solids:75.9
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 0.015 U 0.10 0.015 mg/kg
64-17-5 Ethyl Alcohol 2.5 U 41 2.5 mg/kg
100-41-4 Ethylbenzene 0.027 U 0.10 0.027 mg/kg
591-78-6 2-Hexanone 0.067 U 1.3 0.067 mg/kg
98-82-8 Isopropylbenzene 0.029 U 0.51 0.029 mg/kg
99-87-6 p-Isopropyltoluene 0.035 U 0.51 0.035 mg/kg
74-83-9 Methyl Bromide 0.16 U 1.0 0.16 mg/kg
74-87-3 Methyl Chloride 0.031 U 0.51 0.031 mg/kg
75-09-2 Methylene Chloride 0.057 U 0.51 0.057 mg/kg
78-93-3 Methyl Ethyl Ketone 0.079 U 1.3 0.079 mg/kg
108-10-1 4-Methyl-2-pentanone 0.053 U 1.3 0.053 mg/kg
1634-04-4 Methyl Tert Butyl Ether 0.011 U 0.10 0.011 mg/kg
91-20-3 Naphthalene 0.059 U 0.51 0.059 mg/kg
103-65-1 n-Propylbenzene 0.044 U 0.51 0.044 mg/kg
100-42-5 Styrene 0.015 U 0.10 0.015 mg/kg
630-20-6 1,1,1,2-Tetrachloroethane 0.020 U 0.10 0.020 mg/kg
79-34-5 1,1,2,2-Tetrachloroethane 0.015 U 0.10 0.015 mg/kg
127-18-4 Tetrachloroethylene 0.035 U 0.10 0.035 mg/kg
108-88-3 Toluene 0.0205 0.51 0.019 mg/kg J
87-61-6 1,2,3-Trichlorobenzene 0.033 U 0.51 0.033 mg/kg
120-82-1 1,2,4-Trichlorobenzene 0.021 U 0.51 0.021 mg/kg
71-55-6 1,1,1-Trichloroethane 0.036 U 0.10 0.036 mg/kg
79-00-5 1,1,2-Trichloroethane 0.015 U 0.10 0.015 mg/kg
79-01-6 Trichloroethylene 0.051 U 0.10 0.051 mg/kg
75-69-4 Trichlorofluoromethane 0.037 U 0.10 0.037 mg/kg
96-18-4 1,2,3-Trichloropropane 0.026 U 0.51 0.026 mg/kg
95-63-6 1,2,4-Trimethylbenzene 0.039 U 0.51 0.039 mg/kg
108-67-8 1,3,5-Trimethylbenzene 0.026 U 0.51 0.026 mg/kg
108-05-4 Vinyl Acetate 0.036 U 0.51 0.036 mg/kg
75-01-4 Vinyl Chloride 0.027 U 0.10 0.027 mg/kg
m,p-Xylene 0.046 U 0.21 0.046 mg/kg
95-47-6 o-Xylene 0.026 U 0.10 0.026 mg/kg
1330-20-7 Xylene (total)0.12 U 0.21 0.12 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 85%59-143%
2037-26-5 Toluene-D8 94%52-159%
460-00-4 4-Bromofluorobenzene 78%38-183%
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 3 of 3
Client Sample ID:SB-2 12-14'
Lab Sample ID:LA97464-3 Date Sampled:01/15/24
Matrix:SO - Soil Date Received:01/23/24
Method:SW846 8260D SW846 5035 Percent Solids:75.9
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
(a) Sample analyzed beyond hold time.
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 1
Client Sample ID:SB-2 12-14'
Lab Sample ID:LA97464-3 Date Sampled:01/15/24
Matrix:SO - Soil Date Received:01/23/24
Method:SW846 8015C Percent Solids:75.9
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LA430954.D 1 01/24/24 13:38 BC n/a n/a GLA4143
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 3.80 g 5.0 ml 100 ul
Run #2
CAS No.Compound Result RL MDL Units Q
TPH-GRO (C6-C10)5.0 U 10 5.0 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 107%64-128%
540-36-3 1,4-Difluorobenzene 98%80-122%
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 1
Client Sample ID:SB-2 12-14'
Lab Sample ID:LA97464-3 Date Sampled:01/15/24
Matrix:SO - Soil Date Received:01/23/24
Method:SW846 8015C SW846 3546 Percent Solids:75.9
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 X0026438.D 1 01/24/24 17:18 JT 01/24/24 08:00 OP24466 GLB2627
Run #2
Initial Weight Final Volume
Run #1 20.1 g 1.0 ml
Run #2
CAS No.Compound Result RL MDL Units Q
TPH-DRO (C10-C28)1.9 U 6.6 1.9 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
84-15-1 o-Terphenyl 82%31-127%
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 3
Client Sample ID:SB-3 10-12'
Lab Sample ID:LA97464-4 Date Sampled:01/15/24
Matrix:SO - Soil Date Received:01/23/24
Method:SW846 8260D SW846 5035 Percent Solids:73.5
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a 1J2140565.D 1 01/30/24 14:17 JY 01/24/24 12:49 n/a V1J5220
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 3.9 g 5.0 ml 100 ul
Run #2
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone 0.23 U 5.3 0.23 mg/kg
71-43-2 Benzene 0.021 U 0.053 0.021 mg/kg
108-86-1 Bromobenzene 0.032 U 0.11 0.032 mg/kg
74-97-5 Bromochloromethane 0.029 U 0.11 0.029 mg/kg
75-27-4 Bromodichloromethane 0.033 U 0.11 0.033 mg/kg
75-25-2 Bromoform 0.084 U 0.11 0.084 mg/kg
104-51-8 n-Butylbenzene 0.034 U 0.53 0.034 mg/kg
135-98-8 sec-Butylbenzene 0.034 U 0.53 0.034 mg/kg
98-06-6 tert-Butylbenzene 0.030 U 0.11 0.030 mg/kg
56-23-5 Carbon Tetrachloride 0.041 U 0.11 0.041 mg/kg
108-90-7 Chlorobenzene 0.026 U 0.11 0.026 mg/kg
75-00-3 Chloroethane 0.036 U 0.11 0.036 mg/kg
67-66-3 Chloroform 0.028 U 0.11 0.028 mg/kg
95-49-8 o-Chlorotoluene 0.052 U 0.53 0.052 mg/kg
106-43-4 p-Chlorotoluene 0.0068 U 0.53 0.0068 mg/kg
124-48-1 Dibromochloromethane 0.030 U 0.11 0.030 mg/kg
106-93-4 1,2-Dibromoethane 0.060 U 0.11 0.060 mg/kg
75-71-8 Dichlorodifluoromethane 0.069 U 0.11 0.069 mg/kg
541-73-1 m-Dichlorobenzene 0.033 U 0.11 0.033 mg/kg
95-50-1 o-Dichlorobenzene 0.020 U 0.11 0.020 mg/kg
106-46-7 p-Dichlorobenzene 0.027 U 0.11 0.027 mg/kg
75-34-3 1,1-Dichloroethane 0.024 U 0.11 0.024 mg/kg
107-06-2 1,2-Dichloroethane 0.023 U 0.11 0.023 mg/kg
75-35-4 1,1-Dichloroethylene 0.043 U 0.11 0.043 mg/kg
156-59-2 cis-1,2-Dichloroethylene 0.033 U 0.11 0.033 mg/kg
156-60-5 trans-1,2-Dichloroethylene 0.021 U 0.11 0.021 mg/kg
78-87-5 1,2-Dichloropropane 0.013 U 0.11 0.013 mg/kg
142-28-9 1,3-Dichloropropane 0.025 U 0.11 0.025 mg/kg
594-20-7 2,2-Dichloropropane 0.036 U 0.11 0.036 mg/kg
563-58-6 1,1-Dichloropropene 0.035 U 0.11 0.035 mg/kg
10061-01-5 cis-1,3-Dichloropropene 0.025 U 0.11 0.025 mg/kg
10061-02-6 trans-1,3-Dichloropropene 0.027 U 0.11 0.027 mg/kg
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 3
Client Sample ID:SB-3 10-12'
Lab Sample ID:LA97464-4 Date Sampled:01/15/24
Matrix:SO - Soil Date Received:01/23/24
Method:SW846 8260D SW846 5035 Percent Solids:73.5
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 0.015 U 0.11 0.015 mg/kg
64-17-5 Ethyl Alcohol 2.6 U 42 2.6 mg/kg
100-41-4 Ethylbenzene 0.027 U 0.11 0.027 mg/kg
591-78-6 2-Hexanone 0.069 U 1.3 0.069 mg/kg
98-82-8 Isopropylbenzene 0.030 U 0.53 0.030 mg/kg
99-87-6 p-Isopropyltoluene 0.036 U 0.53 0.036 mg/kg
74-83-9 Methyl Bromide 0.16 U 1.1 0.16 mg/kg
74-87-3 Methyl Chloride 0.031 U 0.53 0.031 mg/kg
75-09-2 Methylene Chloride 0.058 U 0.53 0.058 mg/kg
78-93-3 Methyl Ethyl Ketone 0.081 U 1.3 0.081 mg/kg
108-10-1 4-Methyl-2-pentanone 0.054 U 1.3 0.054 mg/kg
1634-04-4 Methyl Tert Butyl Ether 0.011 U 0.11 0.011 mg/kg
91-20-3 Naphthalene 0.060 U 0.53 0.060 mg/kg
103-65-1 n-Propylbenzene 0.045 U 0.53 0.045 mg/kg
100-42-5 Styrene 0.015 U 0.11 0.015 mg/kg
630-20-6 1,1,1,2-Tetrachloroethane 0.021 U 0.11 0.021 mg/kg
79-34-5 1,1,2,2-Tetrachloroethane 0.016 U 0.11 0.016 mg/kg
127-18-4 Tetrachloroethylene 0.036 U 0.11 0.036 mg/kg
108-88-3 Toluene 0.0335 0.53 0.019 mg/kg J
87-61-6 1,2,3-Trichlorobenzene 0.034 U 0.53 0.034 mg/kg
120-82-1 1,2,4-Trichlorobenzene 0.022 U 0.53 0.022 mg/kg
71-55-6 1,1,1-Trichloroethane 0.037 U 0.11 0.037 mg/kg
79-00-5 1,1,2-Trichloroethane 0.016 U 0.11 0.016 mg/kg
79-01-6 Trichloroethylene 0.053 U 0.11 0.053 mg/kg
75-69-4 Trichlorofluoromethane 0.038 U 0.11 0.038 mg/kg
96-18-4 1,2,3-Trichloropropane 0.026 U 0.53 0.026 mg/kg
95-63-6 1,2,4-Trimethylbenzene 0.040 U 0.53 0.040 mg/kg
108-67-8 1,3,5-Trimethylbenzene 0.027 U 0.53 0.027 mg/kg
108-05-4 Vinyl Acetate 0.037 U 0.53 0.037 mg/kg
75-01-4 Vinyl Chloride 0.028 U 0.11 0.028 mg/kg
m,p-Xylene 0.047 U 0.21 0.047 mg/kg
95-47-6 o-Xylene 0.027 U 0.11 0.027 mg/kg
1330-20-7 Xylene (total)0.12 U 0.21 0.12 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 91%59-143%
2037-26-5 Toluene-D8 97%52-159%
460-00-4 4-Bromofluorobenzene 100%38-183%
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 3 of 3
Client Sample ID:SB-3 10-12'
Lab Sample ID:LA97464-4 Date Sampled:01/15/24
Matrix:SO - Soil Date Received:01/23/24
Method:SW846 8260D SW846 5035 Percent Solids:73.5
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
(a) Sample analyzed beyond hold time.
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
23 of 51
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Report of Analysis Page 1 of 1
Client Sample ID:SB-3 10-12'
Lab Sample ID:LA97464-4 Date Sampled:01/15/24
Matrix:SO - Soil Date Received:01/23/24
Method:SW846 8015C Percent Solids:73.5
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LA430956.D 1 01/24/24 13:57 BC n/a n/a GLA4143
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 3.90 g 5.0 ml 100 ul
Run #2
CAS No.Compound Result RL MDL Units Q
TPH-GRO (C6-C10)5.1 U 11 5.1 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 110%64-128%
540-36-3 1,4-Difluorobenzene 99%80-122%
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
24 of 51
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SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-3 10-12'
Lab Sample ID:LA97464-4 Date Sampled:01/15/24
Matrix:SO - Soil Date Received:01/23/24
Method:SW846 8015C SW846 3546 Percent Solids:73.5
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 X0026439.D 1 01/24/24 17:45 JT 01/24/24 08:00 OP24466 GLB2627
Run #2
Initial Weight Final Volume
Run #1 20.1 g 1.0 ml
Run #2
CAS No.Compound Result RL MDL Units Q
TPH-DRO (C10-C28)2.0 U 6.8 2.0 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
84-15-1 o-Terphenyl 82%31-127%
U = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
25 of 51
LA97464
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SGS North America Inc.
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
 Chain of Custody
Scott, LA
Section 4
26 of 51
LA97464
4
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LA97464: Chain of Custody
Page 2 of 3
28 of 51
LA97464
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1
Job Number:LA97464 Client:GROUNDWATER & ENVIRONMENTAL S
Date / Time Received:1/23/2024 10:25:00 AM Delivery Method:FEDEX
Project:MPURPH EXPRESS # 7498
4. No. Coolers:1
Airbill #'s:631058420368
Cooler Security
1. Custody Seals Present:
Y or N
2. Custody Seals Intact:
3. COC Present:
4. Smpl Dates/Time OK
2. Cooler temp verification:
Cooler Temperature Y or N
1. Temp criteria achieved:
3. Cooler media:Ice (direct contact)
Quality Control Preservatio Y or N N/A
1. Trip Blank present / cooler:
2. Trip Blank listed on COC:
3. Samples preserved properly:
4. VOCs headspace free:
Sample Integrity - Documentation Y or N
1. Sample labels present on bottles:
2. Container labeling complete:
3. Sample container label / COC agree:
Sample Integrity - Condition Y or N
1. Sample recvd within HT:
3. Condition of sample:
2. All containers accounted for:
Sample Integrity - Instructions
1. Analysis requested is clear:
2. Bottles received for unspecified tests
3. Sufficient volume recvd for analysis:
4. Compositing instructions clear:
5. Filtering instructions clear:
Intact
Y or N
Comments
Y or N N/A
Cooler Temps (Raw Measured) °C:
Cooler Temps (Corrected) °C:
Cooler 1: (3.6);
Cooler 1: (3.6);
SM089-03Rev. Date 12/7/17
SGS Sample Receipt Summary
Test Strip Lot #s:pH 1-12:pH 12+:Other: (Specify)
LA97464: Chain of Custody
Page 3 of 3
29 of 51
LA97464
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SGS North America Inc.
MS Volatiles
QC Data Summaries
Includes the following where applicable:
 Method Blank Summaries
 Blank Spike Summaries
 Matrix Spike and Duplicate Summaries
Scott, LA
Section 5
30 of 51
LA97464
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Method Blank Summary Page 1 of 2
Job Number:LA97464
Account:MURPHY Murphy Oil USA, Inc.
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V1I4078-MB1 1I110195.D 1 01/25/24 JY n/a n/a V1I4078
The QC reported here applies to the following samples:Method: SW846 8260D
LA97464-1
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone 4.5 50 2.2 ug/kg J
71-43-2 Benzene ND 0.50 0.20 ug/kg
108-86-1 Bromobenzene ND 1.0 0.30 ug/kg
74-97-5 Bromochloromethane ND 1.0 0.27 ug/kg
75-27-4 Bromodichloromethane ND 1.0 0.32 ug/kg
75-25-2 Bromoform ND 1.0 0.80 ug/kg
104-51-8 n-Butylbenzene ND 5.0 0.32 ug/kg
135-98-8 sec-Butylbenzene ND 5.0 0.33 ug/kg
98-06-6 tert-Butylbenzene ND 1.0 0.29 ug/kg
56-23-5 Carbon Tetrachloride ND 1.0 0.39 ug/kg
108-90-7 Chlorobenzene ND 1.0 0.25 ug/kg
75-00-3 Chloroethane ND 1.0 0.34 ug/kg
67-66-3 Chloroform ND 1.0 0.26 ug/kg
95-49-8 o-Chlorotoluene ND 5.0 0.49 ug/kg
106-43-4 p-Chlorotoluene ND 5.0 0.065 ug/kg
124-48-1 Dibromochloromethane ND 1.0 0.29 ug/kg
106-93-4 1,2-Dibromoethane ND 1.0 0.57 ug/kg
75-71-8 Dichlorodifluoromethane ND 1.0 0.65 ug/kg
541-73-1 m-Dichlorobenzene ND 1.0 0.32 ug/kg
95-50-1 o-Dichlorobenzene ND 1.0 0.19 ug/kg
106-46-7 p-Dichlorobenzene ND 1.0 0.26 ug/kg
75-34-3 1,1-Dichloroethane ND 1.0 0.23 ug/kg
107-06-2 1,2-Dichloroethane ND 1.0 0.22 ug/kg
75-35-4 1,1-Dichloroethylene ND 1.0 0.41 ug/kg
156-59-2 cis-1,2-Dichloroethylene ND 1.0 0.31 ug/kg
156-60-5 trans-1,2-Dichloroethylene ND 1.0 0.20 ug/kg
78-87-5 1,2-Dichloropropane ND 1.0 0.13 ug/kg
142-28-9 1,3-Dichloropropane ND 1.0 0.24 ug/kg
594-20-7 2,2-Dichloropropane ND 1.0 0.34 ug/kg
563-58-6 1,1-Dichloropropene ND 1.0 0.33 ug/kg
10061-01-5 cis-1,3-Dichloropropene ND 1.0 0.24 ug/kg
10061-02-6 trans-1,3-Dichloropropene ND 1.0 0.26 ug/kg
108-20-3 Di-Isopropyl Ether ND 1.0 0.15 ug/kg
64-17-5 Ethyl Alcohol ND 400 25 ug/kg
100-41-4 Ethylbenzene ND 1.0 0.26 ug/kg
591-78-6 2-Hexanone 1.5 13 0.66 ug/kg J
31 of 51
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Method Blank Summary Page 2 of 2
Job Number:LA97464
Account:MURPHY Murphy Oil USA, Inc.
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V1I4078-MB1 1I110195.D 1 01/25/24 JY n/a n/a V1I4078
The QC reported here applies to the following samples:Method: SW846 8260D
LA97464-1
CAS No.Compound Result RL MDL Units Q
98-82-8 Isopropylbenzene ND 5.0 0.28 ug/kg
99-87-6 p-Isopropyltoluene ND 5.0 0.34 ug/kg
74-83-9 Methyl Bromide ND 10 1.6 ug/kg
74-87-3 Methyl Chloride ND 5.0 0.30 ug/kg
75-09-2 Methylene Chloride ND 5.0 0.56 ug/kg
78-93-3 Methyl Ethyl Ketone ND 13 0.77 ug/kg
108-10-1 4-Methyl-2-pentanone ND 13 0.52 ug/kg
1634-04-4 Methyl Tert Butyl Ether ND 1.0 0.10 ug/kg
91-20-3 Naphthalene ND 5.0 0.57 ug/kg
103-65-1 n-Propylbenzene ND 5.0 0.43 ug/kg
100-42-5 Styrene ND 1.0 0.15 ug/kg
630-20-6 1,1,1,2-Tetrachloroethane ND 1.0 0.20 ug/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.15 ug/kg
127-18-4 Tetrachloroethylene ND 1.0 0.34 ug/kg
108-88-3 Toluene ND 5.0 0.18 ug/kg
87-61-6 1,2,3-Trichlorobenzene ND 5.0 0.33 ug/kg
120-82-1 1,2,4-Trichlorobenzene ND 5.0 0.21 ug/kg
71-55-6 1,1,1-Trichloroethane ND 1.0 0.35 ug/kg
79-00-5 1,1,2-Trichloroethane ND 1.0 0.15 ug/kg
79-01-6 Trichloroethylene ND 1.0 0.50 ug/kg
75-69-4 Trichlorofluoromethane ND 1.0 0.36 ug/kg
96-18-4 1,2,3-Trichloropropane ND 5.0 0.25 ug/kg
95-63-6 1,2,4-Trimethylbenzene ND 5.0 0.38 ug/kg
108-67-8 1,3,5-Trimethylbenzene ND 5.0 0.25 ug/kg
108-05-4 Vinyl Acetate ND 5.0 0.35 ug/kg
75-01-4 Vinyl Chloride ND 1.0 0.26 ug/kg
m,p-Xylene ND 2.0 0.45 ug/kg
95-47-6 o-Xylene ND 1.0 0.26 ug/kg
1330-20-7 Xylene (total)ND 2.0 1.2 ug/kg
CAS No.Surrogate Recoveries Limits
17060-07-0 1,2-Dichloroethane-D4 88%59-143%
2037-26-5 Toluene-D8 96%52-159%
460-00-4 4-Bromofluorobenzene 95%38-183%
32 of 51
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Method Blank Summary Page 1 of 2
Job Number:LA97464
Account:MURPHY Murphy Oil USA, Inc.
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V1J5220-MB1 1J2140557.D 1 01/30/24 JY n/a n/a V1J5220
The QC reported here applies to the following samples:Method: SW846 8260D
LA97464-2, LA97464-3, LA97464-4
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 2500 110 ug/kg
71-43-2 Benzene ND 25 9.9 ug/kg
108-86-1 Bromobenzene ND 50 15 ug/kg
74-97-5 Bromochloromethane ND 50 14 ug/kg
75-27-4 Bromodichloromethane ND 50 16 ug/kg
75-25-2 Bromoform ND 50 40 ug/kg
104-51-8 n-Butylbenzene ND 250 16 ug/kg
135-98-8 sec-Butylbenzene ND 250 16 ug/kg
98-06-6 tert-Butylbenzene ND 50 14 ug/kg
56-23-5 Carbon Tetrachloride ND 50 20 ug/kg
108-90-7 Chlorobenzene ND 50 12 ug/kg
75-00-3 Chloroethane ND 50 17 ug/kg
67-66-3 Chloroform ND 50 13 ug/kg
95-49-8 o-Chlorotoluene ND 250 24 ug/kg
106-43-4 p-Chlorotoluene ND 250 3.3 ug/kg
124-48-1 Dibromochloromethane ND 50 14 ug/kg
106-93-4 1,2-Dibromoethane ND 50 29 ug/kg
75-71-8 Dichlorodifluoromethane ND 50 33 ug/kg
541-73-1 m-Dichlorobenzene ND 50 16 ug/kg
95-50-1 o-Dichlorobenzene ND 50 9.7 ug/kg
106-46-7 p-Dichlorobenzene ND 50 13 ug/kg
75-34-3 1,1-Dichloroethane ND 50 11 ug/kg
107-06-2 1,2-Dichloroethane ND 50 11 ug/kg
75-35-4 1,1-Dichloroethylene ND 50 20 ug/kg
156-59-2 cis-1,2-Dichloroethylene ND 50 16 ug/kg
156-60-5 trans-1,2-Dichloroethylene ND 50 10 ug/kg
78-87-5 1,2-Dichloropropane ND 50 6.3 ug/kg
142-28-9 1,3-Dichloropropane ND 50 12 ug/kg
594-20-7 2,2-Dichloropropane ND 50 17 ug/kg
563-58-6 1,1-Dichloropropene ND 50 17 ug/kg
10061-01-5 cis-1,3-Dichloropropene ND 50 12 ug/kg
10061-02-6 trans-1,3-Dichloropropene ND 50 13 ug/kg
108-20-3 Di-Isopropyl Ether ND 50 7.3 ug/kg
64-17-5 Ethyl Alcohol ND 20000 1200 ug/kg
100-41-4 Ethylbenzene ND 50 13 ug/kg
591-78-6 2-Hexanone ND 630 33 ug/kg
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Method Blank Summary Page 2 of 2
Job Number:LA97464
Account:MURPHY Murphy Oil USA, Inc.
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V1J5220-MB1 1J2140557.D 1 01/30/24 JY n/a n/a V1J5220
The QC reported here applies to the following samples:Method: SW846 8260D
LA97464-2, LA97464-3, LA97464-4
CAS No.Compound Result RL MDL Units Q
98-82-8 Isopropylbenzene ND 250 14 ug/kg
99-87-6 p-Isopropyltoluene ND 250 17 ug/kg
74-83-9 Methyl Bromide ND 500 78 ug/kg
74-87-3 Methyl Chloride ND 250 15 ug/kg
75-09-2 Methylene Chloride ND 250 28 ug/kg
78-93-3 Methyl Ethyl Ketone ND 630 38 ug/kg
108-10-1 4-Methyl-2-pentanone ND 630 26 ug/kg
1634-04-4 Methyl Tert Butyl Ether ND 50 5.2 ug/kg
91-20-3 Naphthalene ND 250 29 ug/kg
103-65-1 n-Propylbenzene ND 250 21 ug/kg
100-42-5 Styrene ND 50 7.3 ug/kg
630-20-6 1,1,1,2-Tetrachloroethane ND 50 9.8 ug/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 50 7.4 ug/kg
127-18-4 Tetrachloroethylene ND 50 17 ug/kg
108-88-3 Toluene ND 250 9.0 ug/kg
87-61-6 1,2,3-Trichlorobenzene ND 250 16 ug/kg
120-82-1 1,2,4-Trichlorobenzene ND 250 10 ug/kg
71-55-6 1,1,1-Trichloroethane ND 50 18 ug/kg
79-00-5 1,1,2-Trichloroethane ND 50 7.5 ug/kg
79-01-6 Trichloroethylene ND 50 25 ug/kg
75-69-4 Trichlorofluoromethane ND 50 18 ug/kg
96-18-4 1,2,3-Trichloropropane ND 250 12 ug/kg
95-63-6 1,2,4-Trimethylbenzene ND 250 19 ug/kg
108-67-8 1,3,5-Trimethylbenzene ND 250 13 ug/kg
108-05-4 Vinyl Acetate ND 250 18 ug/kg
75-01-4 Vinyl Chloride ND 50 13 ug/kg
m,p-Xylene ND 100 23 ug/kg
95-47-6 o-Xylene ND 50 13 ug/kg
1330-20-7 Xylene (total)ND 100 58 ug/kg
CAS No.Surrogate Recoveries Limits
17060-07-0 1,2-Dichloroethane-D4 84%59-143%
2037-26-5 Toluene-D8 95%52-159%
460-00-4 4-Bromofluorobenzene 99%38-183%
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Blank Spike/Blank Spike Duplicate Summary Page 1 of 2
Job Number:LA97464
Account:MURPHY Murphy Oil USA, Inc.
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V1I4078-BS1 1I110192.D 1 01/25/24 JY n/a n/a V1I4078
V1I4078-BSD1 1I110193.D 1 01/25/24 JY n/a n/a V1I4078
The QC reported here applies to the following samples:Method: SW846 8260D
LA97464-1
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/kg ug/kg %ug/kg %RPD Rec/RPD
67-64-1 Acetone 50 39.6 79 40.2 80 2 40-153/30
71-43-2 Benzene 20 19.0 95 18.8 94 1 67-135/30
108-86-1 Bromobenzene 20 20.7 104 19.6 98 5 54-144/30
74-97-5 Bromochloromethane 20 17.2 86 17.0 85 1 50-147/30
75-27-4 Bromodichloromethane 20 17.3 87 17.1 86 1 54-146/30
75-25-2 Bromoform 20 18.3 92 18.7 94 2 49-145/30
104-51-8 n-Butylbenzene 20 23.7 119 22.1 111 7 47-160/30
135-98-8 sec-Butylbenzene 20 22.5 113 21.3 107 5 51-155/30
98-06-6 tert-Butylbenzene 20 21.3 107 20.7 104 3 53-152/30
56-23-5 Carbon Tetrachloride 20 17.1 86 16.7 84 2 50-152/30
108-90-7 Chlorobenzene 20 19.6 98 18.9 95 4 57-144/30
75-00-3 Chloroethane 20 19.8 99 18.7 94 6 38-176/30
67-66-3 Chloroform 20 16.8 84 16.5 83 2 53-147/30
95-49-8 o-Chlorotoluene 20 21.3 107 20.4 102 4 52-151/30
106-43-4 p-Chlorotoluene 20 21.6 108 20.7 104 4 52-150/30
124-48-1 Dibromochloromethane 20 18.4 92 18.1 91 2 54-146/30
106-93-4 1,2-Dibromoethane 20 17.8 89 17.7 89 1 55-145/30
75-71-8 Dichlorodifluoromethane 20 16.3 82 16.0 80 2 24-179/30
541-73-1 m-Dichlorobenzene 20 21.9 110 21.2 106 3 54-147/30
95-50-1 o-Dichlorobenzene 20 20.8 104 20.3 102 2 55-144/30
106-46-7 p-Dichlorobenzene 20 21.9 110 21.0 105 4 54-147/30
75-34-3 1,1-Dichloroethane 20 17.0 85 16.6 83 2 53-148/30
107-06-2 1,2-Dichloroethane 20 17.7 89 17.3 87 2 55-144/30
75-35-4 1,1-Dichloroethylene 20 17.4 87 16.9 85 3 49-153/30
156-59-2 cis-1,2-Dichloroethylene 20 16.8 84 16.6 83 1 52-147/30
156-60-5 trans-1,2-Dichloroethylene 20 17.9 90 17.5 88 2 51-152/30
78-87-5 1,2-Dichloropropane 20 18.5 93 18.3 92 1 56-145/30
142-28-9 1,3-Dichloropropane 20 18.6 93 18.4 92 1 53-145/30
594-20-7 2,2-Dichloropropane 20 17.1 86 17.3 87 1 35-176/30
563-58-6 1,1-Dichloropropene 20 18.1 91 18.0 90 1 49-157/30
10061-01-5 cis-1,3-Dichloropropene 20 18.6 93 18.3 92 2 54-148/30
10061-02-6 trans-1,3-Dichloropropene 20 19.0 95 18.6 93 2 53-151/30
108-20-3 Di-Isopropyl Ether 20 17.2 86 17.1 86 1 85-120/30
64-17-5 Ethyl Alcohol 400 351 88 342 86 3 31-164/30
100-41-4 Ethylbenzene 20 20.9 105 20.2 101 3 69-136/30
591-78-6 2-Hexanone 50 41.0 82 41.3 83 1 45-148/30
* = Outside of Control Limits.
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Blank Spike/Blank Spike Duplicate Summary Page 2 of 2
Job Number:LA97464
Account:MURPHY Murphy Oil USA, Inc.
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V1I4078-BS1 1I110192.D 1 01/25/24 JY n/a n/a V1I4078
V1I4078-BSD1 1I110193.D 1 01/25/24 JY n/a n/a V1I4078
The QC reported here applies to the following samples:Method: SW846 8260D
LA97464-1
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/kg ug/kg %ug/kg %RPD Rec/RPD
98-82-8 Isopropylbenzene 20 21.4 107 20.6 103 4 52-151/30
99-87-6 p-Isopropyltoluene 20 22.9 115 21.6 108 6 50-155/30
74-83-9 Methyl Bromide 20 18.5 93 17.8 89 4 40-170/30
74-87-3 Methyl Chloride 20 17.2 86 16.6 83 4 39-152/30
75-09-2 Methylene Chloride 20 18.3 92 17.6 88 4 51-142/30
78-93-3 Methyl Ethyl Ketone 50 51.2 102 51.2 102 0 48-150/30
108-10-1 4-Methyl-2-pentanone 50 46.9 94 46.7 93 0 50-151/30
1634-04-4 Methyl Tert Butyl Ether 20 16.6 83 16.6 83 0 61-142/30
91-20-3 Naphthalene 20 19.8 99 19.6 98 1 58-147/30
103-65-1 n-Propylbenzene 20 23.1 116 21.9 110 5 50-154/30
100-42-5 Styrene 20 21.0 105 20.4 102 3 56-145/30
630-20-6 1,1,1,2-Tetrachloroethane 20 18.4 92 17.9 90 3 56-147/30
79-34-5 1,1,2,2-Tetrachloroethane 20 18.0 90 18.1 91 1 55-141/30
127-18-4 Tetrachloroethylene 20 21.6 108 20.6 103 5 54-156/30
108-88-3 Toluene 20 19.3 97 18.9 95 2 71-135/30
87-61-6 1,2,3-Trichlorobenzene 20 21.3 107 20.6 103 3 51-157/30
120-82-1 1,2,4-Trichlorobenzene 20 22.4 112 20.8 104 7 48-163/30
71-55-6 1,1,1-Trichloroethane 20 17.5 88 17.1 86 2 52-153/30
79-00-5 1,1,2-Trichloroethane 20 18.8 94 18.4 92 2 55-144/30
79-01-6 Trichloroethylene 20 19.8 99 18.9 95 5 56-151/30
75-69-4 Trichlorofluoromethane 20 17.1 86 16.9 85 1 36-171/30
96-18-4 1,2,3-Trichloropropane 20 18.3 92 18.3 92 0 45-139/30
95-63-6 1,2,4-Trimethylbenzene 20 21.5 108 20.5 103 5 50-153/30
108-67-8 1,3,5-Trimethylbenzene 20 21.4 107 20.4 102 5 51-153/30
108-05-4 Vinyl Acetate 20 20.0 100 19.2 96 4 23-188/30
75-01-4 Vinyl Chloride 20 18.2 91 17.6 88 3 42-155/30
m,p-Xylene 40 41.9 105 40.4 101 4 70-140/30
95-47-6 o-Xylene 20 20.8 104 20.1 101 3 70-132/30
1330-20-7 Xylene (total)60 62.7 105 60.5 101 4 69-138/30
CAS No.Surrogate Recoveries BSP BSD Limits
17060-07-0 1,2-Dichloroethane-D4 90%90%59-143%
2037-26-5 Toluene-D8 98%98%52-159%
460-00-4 4-Bromofluorobenzene 100%98%38-183%
* = Outside of Control Limits.
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Blank Spike/Blank Spike Duplicate Summary Page 1 of 2
Job Number:LA97464
Account:MURPHY Murphy Oil USA, Inc.
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V1J5220-BS1 1J2140551.D 1 01/30/24 JY n/a n/a V1J5220
V1J5220-BSD1 1J2140553.D 1 01/30/24 JY n/a n/a V1J5220
The QC reported here applies to the following samples:Method: SW846 8260D
LA97464-2, LA97464-3, LA97464-4
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/kg ug/kg %ug/kg %RPD Rec/RPD
67-64-1 Acetone 2500 1690 68 1860 74 10 40-153/30
71-43-2 Benzene 1000 980 98 1000 100 2 67-135/30
108-86-1 Bromobenzene 1000 934 93 1010 101 8 54-144/30
74-97-5 Bromochloromethane 1000 910 91 944 94 4 50-147/30
75-27-4 Bromodichloromethane 1000 967 97 983 98 2 54-146/30
75-25-2 Bromoform 1000 992 99 1070 107 8 49-145/30
104-51-8 n-Butylbenzene 1000 1030 103 960 96 7 47-160/30
135-98-8 sec-Butylbenzene 1000 1030 103 1030 103 0 51-155/30
98-06-6 tert-Butylbenzene 1000 1030 103 985 99 4 53-152/30
56-23-5 Carbon Tetrachloride 1000 890 89 914 91 3 50-152/30
108-90-7 Chlorobenzene 1000 961 96 989 99 3 57-144/30
75-00-3 Chloroethane 1000 898 90 882 88 2 38-176/30
67-66-3 Chloroform 1000 856 86 897 90 5 53-147/30
95-49-8 o-Chlorotoluene 1000 1030 103 1050 105 2 52-151/30
106-43-4 p-Chlorotoluene 1000 978 98 991 99 1 52-150/30
124-48-1 Dibromochloromethane 1000 1020 102 1050 105 3 54-146/30
106-93-4 1,2-Dibromoethane 1000 989 99 1030 103 4 55-145/30
75-71-8 Dichlorodifluoromethane 1000 1100 110 1110 111 1 24-179/30
541-73-1 m-Dichlorobenzene 1000 1010 101 1010 101 0 54-147/30
95-50-1 o-Dichlorobenzene 1000 981 98 992 99 1 55-144/30
106-46-7 p-Dichlorobenzene 1000 1010 101 988 99 2 54-147/30
75-34-3 1,1-Dichloroethane 1000 889 89 913 91 3 53-148/30
107-06-2 1,2-Dichloroethane 1000 921 92 967 97 5 55-144/30
75-35-4 1,1-Dichloroethylene 1000 880 88 882 88 0 49-153/30
156-59-2 cis-1,2-Dichloroethylene 1000 871 87 886 89 2 52-147/30
156-60-5 trans-1,2-Dichloroethylene 1000 870 87 922 92 6 51-152/30
78-87-5 1,2-Dichloropropane 1000 989 99 1020 102 3 56-145/30
142-28-9 1,3-Dichloropropane 1000 997 100 1040 104 4 53-145/30
594-20-7 2,2-Dichloropropane 1000 874 87 890 89 2 35-176/30
563-58-6 1,1-Dichloropropene 1000 920 92 930 93 1 49-157/30
10061-01-5 cis-1,3-Dichloropropene 1000 990 99 1010 101 2 54-148/30
10061-02-6 trans-1,3-Dichloropropene 1000 1020 102 1040 104 2 53-151/30
108-20-3 Di-Isopropyl Ether 1000 895 90 917 92 2 85-120/30
64-17-5 Ethyl Alcohol 20000 20400 102 22500 113 10 31-164/30
100-41-4 Ethylbenzene 1000 985 99 988 99 0 69-136/30
591-78-6 2-Hexanone 2500 2310 92 2460 98 6 45-148/30
* = Outside of Control Limits.
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Blank Spike/Blank Spike Duplicate Summary Page 2 of 2
Job Number:LA97464
Account:MURPHY Murphy Oil USA, Inc.
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V1J5220-BS1 1J2140551.D 1 01/30/24 JY n/a n/a V1J5220
V1J5220-BSD1 1J2140553.D 1 01/30/24 JY n/a n/a V1J5220
The QC reported here applies to the following samples:Method: SW846 8260D
LA97464-2, LA97464-3, LA97464-4
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/kg ug/kg %ug/kg %RPD Rec/RPD
98-82-8 Isopropylbenzene 1000 999 100 1030 103 3 52-151/30
99-87-6 p-Isopropyltoluene 1000 1050 105 1020 102 3 50-155/30
74-83-9 Methyl Bromide 1000 791 79 965 97 20 40-170/30
74-87-3 Methyl Chloride 1000 942 94 965 97 2 39-152/30
75-09-2 Methylene Chloride 1000 836 84 869 87 4 51-142/30
78-93-3 Methyl Ethyl Ketone 2500 2080 83 2170 87 4 48-150/30
108-10-1 4-Methyl-2-pentanone 2500 2410 96 2460 98 2 50-151/30
1634-04-4 Methyl Tert Butyl Ether 1000 934 93 950 95 2 61-142/30
91-20-3 Naphthalene 1000 928 93 929 93 0 58-147/30
103-65-1 n-Propylbenzene 1000 1040 104 1010 101 3 50-154/30
100-42-5 Styrene 1000 1000 100 1040 104 4 56-145/30
630-20-6 1,1,1,2-Tetrachloroethane 1000 1000 100 1040 104 4 56-147/30
79-34-5 1,1,2,2-Tetrachloroethane 1000 1050 105 1020 102 3 55-141/30
127-18-4 Tetrachloroethylene 1000 973 97 1090 109 11 54-156/30
108-88-3 Toluene 1000 961 96 989 99 3 71-135/30
87-61-6 1,2,3-Trichlorobenzene 1000 941 94 987 99 5 51-157/30
120-82-1 1,2,4-Trichlorobenzene 1000 954 95 963 96 1 48-163/30
71-55-6 1,1,1-Trichloroethane 1000 881 88 893 89 1 52-153/30
79-00-5 1,1,2-Trichloroethane 1000 982 98 1020 102 4 55-144/30
79-01-6 Trichloroethylene 1000 932 93 973 97 4 56-151/30
75-69-4 Trichlorofluoromethane 1000 865 87 910 91 5 36-171/30
96-18-4 1,2,3-Trichloropropane 1000 975 98 1010 101 4 45-139/30
95-63-6 1,2,4-Trimethylbenzene 1000 1020 102 993 99 3 50-153/30
108-67-8 1,3,5-Trimethylbenzene 1000 1040 104 1040 104 0 51-153/30
108-05-4 Vinyl Acetate 1000 951 95 900 90 6 23-188/30
75-01-4 Vinyl Chloride 1000 977 98 992 99 2 42-155/30
m,p-Xylene 2000 2000 100 2080 104 4 70-140/30
95-47-6 o-Xylene 1000 970 97 1010 101 4 70-132/30
1330-20-7 Xylene (total)3000 2970 99 3100 103 4 69-138/30
CAS No.Surrogate Recoveries BSP BSD Limits
17060-07-0 1,2-Dichloroethane-D4 90%90%59-143%
2037-26-5 Toluene-D8 97%97%52-159%
460-00-4 4-Bromofluorobenzene 99%100%38-183%
* = Outside of Control Limits.
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Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 3
Job Number:LA97464
Account:MURPHY Murphy Oil USA, Inc.
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
LA97545-9MS 1J2140593.D 1 01/30/24 JY n/a n/a V1J5220
LA97545-9MSD 1J2140595.D 1 01/30/24 JY n/a n/a V1J5220
LA97545-9 1J2140575.D 1 01/30/24 JY n/a n/a V1J5220
The QC reported here applies to the following samples:Method: SW846 8260B
LA97464-2, LA97464-3, LA97464-4
LA97545-9 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/kg Q ug/kg ug/kg %ug/kg ug/kg %RPD Rec/RPD
67-64-1 Acetone ND 5320 4550 86 5320 4630 87 2 19-170/34
71-43-2 Benzene ND 2130 1920 90 2130 2100 99 9 15-162/33
108-86-1 Bromobenzene ND 2130 1910 90 2130 1990 94 4 28-151/33
74-97-5 Bromochloromethane ND 2130 1530 72 2130 1630 77 6 9-176/15
75-27-4 Bromodichloromethane ND 2130 1820 86 2130 1940 91 6 48-124/14
75-25-2 Bromoform ND 2130 1930 91 2130 1990 94 3 20-128/16
104-51-8 n-Butylbenzene ND 2130 2880 135 2130 2990 141 4 1-199/21
135-98-8 sec-Butylbenzene 202 2130 2140 91 2130 2290 98 7 16-172/16
98-06-6 tert-Butylbenzene ND 2130 1890 89 2130 1980 93 5 27-150/16
56-23-5 Carbon Tetrachloride ND 2130 1670 79 2130 1810 85 8 25-136/17
108-90-7 Chlorobenzene ND 2130 1890 89 2130 2010 95 6 31-153/12
75-00-3 Chloroethane ND 2130 664 31 2130 927 44 33 1-171/64
67-66-3 Chloroform ND 2130 1760 83 2130 1790 84 2 26-153/42
95-49-8 o-Chlorotoluene ND 2130 2030 95 2130 2140 101 5 47-138/16
106-43-4 p-Chlorotoluene ND 2130 1900 89 2130 1970 93 4 11-159/14
124-48-1 Dibromochloromethane ND 2130 1960 92 2130 2080 98 6 26-131/14
106-93-4 1,2-Dibromoethane ND 2130 2030 95 2130 2050 96 1 39-143/14
75-71-8 Dichlorodifluoromethane ND 2130 1460 69 2130 1730 81 17 1-149/18
541-73-1 m-Dichlorobenzene ND 2130 1900 89 2130 2020 95 6 22-152/15
95-50-1 o-Dichlorobenzene ND 2130 1890 89 2130 2000 94 6 27-150/12
106-46-7 p-Dichlorobenzene ND 2130 1870 88 2130 1980 93 6 19-154/12
75-34-3 1,1-Dichloroethane ND 2130 1640 77 2130 1830 86 11 31-147/13
107-06-2 1,2-Dichloroethane ND 2130 1830 86 2130 1950 92 6 31-147/13
75-35-4 1,1-Dichloroethylene ND 2130 1290 61 2130 1380 65 7 22-148/19
156-59-2 cis-1,2-Dichloroethylene ND 2130 1650 78 2130 1800 85 9 25-145/15
156-60-5 trans-1,2-Dichloroethylene ND 2130 1700 80 2130 1770 83 4 24-145/17
78-87-5 1,2-Dichloropropane ND 2130 1950 92 2130 2020 95 4 36-141/13
142-28-9 1,3-Dichloropropane ND 2130 2000 94 2130 2080 98 4 35-147/12
594-20-7 2,2-Dichloropropane ND 2130 1200 56 2130 1300 61 8 45-150/18
563-58-6 1,1-Dichloropropene ND 2130 1740 82 2130 1840 87 6 28-146/16
10061-01-5 cis-1,3-Dichloropropene ND 2130 1830 86 2130 1910 90 4 27-143/12
10061-02-6 trans-1,3-Dichloropropene ND 2130 1930 91 2130 1990 94 3 46-130/14
108-20-3 Di-Isopropyl Ether ND 2130 1650 78 2130 1790 84 8 34-149/13
64-17-5 Ethyl Alcohol ND 42500 28200 66 42500 26200 62 7 1-159/146
100-41-4 Ethylbenzene 105 2130 2050 91 2130 2170 97 6 14-168/13
591-78-6 2-Hexanone ND 5320 4880 92 5320 5190 98 6 16-169/26
* = Outside of Control Limits.
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Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 3
Job Number:LA97464
Account:MURPHY Murphy Oil USA, Inc.
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
LA97545-9MS 1J2140593.D 1 01/30/24 JY n/a n/a V1J5220
LA97545-9MSD 1J2140595.D 1 01/30/24 JY n/a n/a V1J5220
LA97545-9 1J2140575.D 1 01/30/24 JY n/a n/a V1J5220
The QC reported here applies to the following samples:Method: SW846 8260B
LA97464-2, LA97464-3, LA97464-4
LA97545-9 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/kg Q ug/kg ug/kg %ug/kg ug/kg %RPD Rec/RPD
98-82-8 Isopropylbenzene 203 2130 2190 93 2130 2300 99 5 12-186/18
99-87-6 p-Isopropyltoluene ND 2130 2020 95 2130 2130 100 5 15-171/18
74-83-9 Methyl Bromide ND 2130 1040 49 2130 1090 51 5 1-178/40
74-87-3 Methyl Chloride ND 2130 1760 83 2130 1900 89 8 1-151/37
75-09-2 Methylene Chloride ND 2130 1560 73 2130 1690 79 8 27-147/18
78-93-3 Methyl Ethyl Ketone ND 5320 4450 84 5320 4520 85 2 29-156/32
108-10-1 4-Methyl-2-pentanone ND 5320 4750 89 5320 5120 96 7 33-160/23
1634-04-4 Methyl Tert Butyl Ether ND 2130 1750 82 2130 1850 87 6 37-145/14
91-20-3 Naphthalene 906 2130 3100 103 2130 3090 103 0 1-192/73
103-65-1 n-Propylbenzene 633 2130 2590 92 2130 2710 98 5 8-170/17
100-42-5 Styrene ND 2130 1960 92 2130 2100 99 7 24-165/13
630-20-6 1,1,1,2-Tetrachloroethane ND 2130 2000 94 2130 2100 99 5 33-140/13
79-34-5 1,1,2,2-Tetrachloroethane ND 2130 325 15* a 2130 301 14* a 8 33-146/48
127-18-4 Tetrachloroethylene ND 2130 2330 110 2130 2480 117 6 21-149/18
108-88-3 Toluene 13.5 2130 1900 89 2130 2050 96 8 11-173/43
87-61-6 1,2,3-Trichlorobenzene ND 2130 1890 89 2130 1980 93 5 17-154/66
120-82-1 1,2,4-Trichlorobenzene ND 2130 1810 85 2130 1890 89 4 15-155/65
71-55-6 1,1,1-Trichloroethane ND 2130 1680 79 2130 1810 85 7 31-142/16
79-00-5 1,1,2-Trichloroethane ND 2130 1950 92 2130 2020 95 4 11-185/16
79-01-6 Trichloroethylene ND 2130 3240 152 2130 3420 161* a 5 21-154/15
75-69-4 Trichlorofluoromethane ND 2130 1030 48 2130 1090 51 6 1-163/27
96-18-4 1,2,3-Trichloropropane ND 2130 1960 92 2130 2090 98 6 33-157/18
95-63-6 1,2,4-Trimethylbenzene 185 2130 2190 94 2130 2260 98 3 90-183/15
108-67-8 1,3,5-Trimethylbenzene 90.2 2130 2060 93 2130 2170 98 5 10-179/14
108-05-4 Vinyl Acetate ND 2130 250 12* a 2130 275 13* a 10 14-146/16
75-01-4 Vinyl Chloride ND 2130 1320 62 2130 1930 91 38* a 32-153/15
m,p-Xylene 36.4 4250 3990 93 4250 4180 97 5 14-175/12
95-47-6 o-Xylene 33.8 2130 1970 91 2130 2110 98 7 19-167/13
1330-20-7 Xylene (total)70.2 6380 5960 92 6380 6280 97 5 14-172/12
CAS No.Surrogate Recoveries MS MSD LA97545-9 Limits
17060-07-0 1,2-Dichloroethane-D4 88%85%88%59-143%
2037-26-5 Toluene-D8 97%98%97%52-159%
460-00-4 4-Bromofluorobenzene 99%102%99%38-183%
* = Outside of Control Limits.
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Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number:LA97464
Account:MURPHY Murphy Oil USA, Inc.
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
LA97545-9MS 1J2140593.D 1 01/30/24 JY n/a n/a V1J5220
LA97545-9MSD 1J2140595.D 1 01/30/24 JY n/a n/a V1J5220
LA97545-9 1J2140575.D 1 01/30/24 JY n/a n/a V1J5220
The QC reported here applies to the following samples:Method: SW846 8260B
LA97464-2, LA97464-3, LA97464-4
(a) Outside control limits due to matrix interference. Blank Spike meets acceptance criteria.
* = Outside of Control Limits.
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1
SGS North America Inc.
GC Volatiles
QC Data Summaries
Includes the following where applicable:
 Method Blank Summaries
 Blank Spike Summaries
 Matrix Spike and Duplicate Summaries
Scott, LA
Section 6
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Method Blank Summary Page 1 of 1
Job Number:LA97464
Account:MURPHY Murphy Oil USA, Inc.
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
GLA4143-MB1 LA430936.D 1 01/24/24 BC n/a n/a GLA4143
The QC reported here applies to the following samples:Method: SW846 8015C
LA97464-3, LA97464-4
CAS No.Compound Result RL MDL Units Q
TPH-GRO (C6-C10)2.86 5.0 2.4 mg/kg J
CAS No.Surrogate Recoveries Limits
460-00-4 4-Bromofluorobenzene 108%64-128%
540-36-3 1,4-Difluorobenzene 98%80-122%
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1
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1
Method Blank Summary Page 1 of 1
Job Number:LA97464
Account:MURPHY Murphy Oil USA, Inc.
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
GLA4146-MB1 LA431032.D 1 01/26/24 BC n/a n/a GLA4146
The QC reported here applies to the following samples:Method: SW846 8015C
LA97464-1, LA97464-2
CAS No.Compound Result RL MDL Units Q
TPH-GRO (C6-C10)ND 5.0 2.4 mg/kg
CAS No.Surrogate Recoveries Limits
460-00-4 4-Bromofluorobenzene 99%64-128%
540-36-3 1,4-Difluorobenzene 103%80-122%
44 of 51
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1
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2
Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:LA97464
Account:MURPHY Murphy Oil USA, Inc.
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
GLA4143-BS1 LA430932.D 1 01/24/24 BC n/a n/a GLA4143
GLA4143-BSD1 LA430934.D 1 01/24/24 BC n/a n/a GLA4143
The QC reported here applies to the following samples:Method: SW846 8015C
LA97464-3, LA97464-4
Spike BSP BSP BSD BSD Limits
CAS No.Compound mg/kg mg/kg %mg/kg %RPD Rec/RPD
TPH-GRO (C6-C10)50 52.5 105 53.6 107 2 79-112/15
CAS No.Surrogate Recoveries BSP BSD Limits
460-00-4 4-Bromofluorobenzene 108%108%64-128%
540-36-3 1,4-Difluorobenzene 95%97%80-122%
* = Outside of Control Limits.
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6.
2
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1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:LA97464
Account:MURPHY Murphy Oil USA, Inc.
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
GLA4146-BS1 LA431028.D 1 01/26/24 BC n/a n/a GLA4146
GLA4146-BSD1 LA431030.D 1 01/26/24 BC n/a n/a GLA4146
The QC reported here applies to the following samples:Method: SW846 8015C
LA97464-1, LA97464-2
Spike BSP BSP BSD BSD Limits
CAS No.Compound mg/kg mg/kg %mg/kg %RPD Rec/RPD
TPH-GRO (C6-C10)50 48.5 97 48.3 97 0 79-112/15
CAS No.Surrogate Recoveries BSP BSD Limits
460-00-4 4-Bromofluorobenzene 97%97%64-128%
540-36-3 1,4-Difluorobenzene 100%98%80-122%
* = Outside of Control Limits.
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6.
2
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2
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1
Job Number:LA97464
Account:MURPHY Murphy Oil USA, Inc.
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
LA97449-9MS LA431088.D 1 01/26/24 BC n/a n/a GLA4146
LA97449-9MSD LA431090.D 1 01/26/24 BC n/a n/a GLA4146
LA97449-9 LA431080.D 1 01/26/24 BC n/a n/a GLA4146
The QC reported here applies to the following samples:Method: SW846 8015C
LA97464-1, LA97464-2
LA97449-9 Spike MS MS Spike MSD MSD Limits
CAS No.Compound mg/kg Q mg/kg mg/kg %mg/kg mg/kg %RPD Rec/RPD
TPH-GRO (C6-C10)7.4 U 148 132 89 148 136 92 3 60-118/16
CAS No.Surrogate Recoveries MS MSD LA97449-9 Limits
460-00-4 4-Bromofluorobenzene 93%97%97%64-128%
540-36-3 1,4-Difluorobenzene 108%108%111%80-122%
* = Outside of Control Limits.
47 of 51
LA97464
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6.
3
.
1
SGS North America Inc.
GC/LC Semi-volatiles
QC Data Summaries
Includes the following where applicable:
 Method Blank Summaries
 Blank Spike Summaries
 Matrix Spike and Duplicate Summaries
Scott, LA
Section 7
48 of 51
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Method Blank Summary Page 1 of 1
Job Number:LA97464
Account:MURPHY Murphy Oil USA, Inc.
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP24466-MB X0026432.D 1 01/24/24 JT 01/24/24 OP24466 GLB2627
The QC reported here applies to the following samples:Method: SW846 8015C
LA97464-1, LA97464-2, LA97464-3, LA97464-4
CAS No.Compound Result RL MDL Units Q
TPH-DRO (C10-C28)ND 5.0 1.5 mg/kg
CAS No.Surrogate Recoveries Limits
84-15-1 o-Terphenyl 79%31-127%
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1
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1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:LA97464
Account:MURPHY Murphy Oil USA, Inc.
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP24466-BS X0026433.D 1 01/24/24 JT 01/24/24 OP24466 GLB2627
OP24466-BSD X0026434.D 1 01/24/24 JT 01/24/24 OP24466 GLB2627
The QC reported here applies to the following samples:Method: SW846 8015C
LA97464-1, LA97464-2, LA97464-3, LA97464-4
Spike BSP BSP BSD BSD Limits
CAS No.Compound mg/kg mg/kg %mg/kg %RPD Rec/RPD
TPH-DRO (C10-C28)150 144 96 141 94 2 49-118/19
CAS No.Surrogate Recoveries BSP BSD Limits
84-15-1 o-Terphenyl 100%98%31-127%
* = Outside of Control Limits.
50 of 51
LA97464
7
7.
2
.
1
Matrix Spike Summary Page 1 of 1
Job Number:LA97464
Account:MURPHY Murphy Oil USA, Inc.
Project:GESSCWC: Murphy #7498, 1209 NC Hwy 16, Conover, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP24466-MS X0026435.D 1 01/24/24 JT 01/24/24 OP24466 GLB2627
LA97464-1 X0026436.D 1 01/24/24 JT 01/24/24 OP24466 GLB2627
The QC reported here applies to the following samples:Method: SW846 8015C
LA97464-1, LA97464-2, LA97464-3, LA97464-4
LA97464-1 Spike MS MS
CAS No.Compound mg/kg Q mg/kg mg/kg %Limits
TPH-DRO (C10-C28)2.45 J 200 185 91 23-150
CAS No.Surrogate Recoveries MS LA97464-1 Limits
84-15-1 o-Terphenyl 99%81%31-127%
* = Outside of Control Limits.
51 of 51
LA97464
7
7.
3
.
1