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HomeMy WebLinkAboutWS-9069_44302_CA_MRP_20161005 Transmittal Letter Incident Manager: Linda Estkowski Incident Name: Pagetown Exxon Incident Number: 44302 Facility ID: 0-004296 Document: Pre-CAP Monitoring Report Document Date: 10/5/16 Jeff Ballsieper Progress Environmental, Inc. P.O. Box 5884 Winston-Salem, North Carolina 27113 Phone (336) 722-9999 Fax (336) 722-9998 TABLE OF CONTENTS A. SITE IDENTIFICATION ............................................................................................................... 1 B. SITE HISTORY, CHARACTERIZATION AND PURPOSE ................................................... 2 C. HISTORIC FREE PRODUCT GAUGING ................................................................................. 2 D. GROUNDWATER ASSESSMENT ACTIVITIES ..................................................................... 3 E. REGIONAL GEOLOGY AND HYDROGEOLOGY ................................................................ 4 F. SITE GEOLOGY AND HYDROGEOLOGY ............................................................................. 4 G. DETERMINATION OF GROUNDWATER FLOW DIRECTION ........................................ 4 H. CONCLUSIONS .............................................................................................................................. 5 I. RECOMMENDATIONS ................................................................................................................ 5 FIGURES Figure 1 – Topographic Site Map Figure 2 – Site Map Figure 3 – Potentiometric Surface Map Figure 4 – Water-Supply Well Location Map Figure 5 – Groundwater Analytical Results Map Figure 6 – Benzene Isoconcentration Map Figure 7 – Total BTEX Isoconcentration Map Figure 8 – MTBE Isoconcentration Map TABLES Table B-1 – Site History, UST/AST System Information Table B-2 – Site History, UST Owner/Operator Information Table B-4 – Summary of Groundwater Analytical Results Table B-7 – Well Construction Information and Historical Groundwater Elevations APPENDIX BTEX and MTBE versus Time Graphs Groundwater Monitoring Well Sampling Data Sheets Laboratory Analytical Reports and Chain-of-Custody Records Pre-CAP Monitoring Report October 5, 2016 Pagetown Exxon, Reidsville, North Carolina Progress Project 1016066.002 - 2 - B. SITE HISTORY, CHARACTERIZATION AND PURPOSE The site is located at 8035 Cherry Grove Road in Reidsville, Caswell County, North Carolina (Figures 1 and 2). The site consists of a convenience store which stores petroleum products in underground storage tanks (USTs) and aboveground storage tanks (ASTs) for retail sale. Formerly kerosene and diesel fuel were stored in USTs. The kerosene and diesel fuel USTs were removed following the discovery of a release in 2014. Three active USTs are present at the site and used to store gasoline. The site is located in a commercial and residential area of rural Caswell County. The surrounding properties are served by water-supply wells within 1,500 feet of the source area. Progress previously completed an Initial Abatement Action Report, dated July 24, 2014; a Phase II Limited Site Assessment (LSA), dated November 26, 2014; a Free Product Recovery and Water- Supply Sampling Report dated May 8, 2015; and, a Water-Supply Well Sampling Report, dated July 31, 2015. The NCDEQ issued a Notice of Regulatory Requirements (NORR), dated December 4, 2014, requiring that a Comprehensive Site Assessment (CSA) be completed for the site. Following discussions with the NCDEQ, it was determined that prior to completing a CSA, free product recovery activities were to be performed and the nearby water-supply wells sampled. A revised CSA was submitted to the NCDEQ on June 2, 2016. A description of the former UST systems is listed in Table B-1 below. Figure 2 depicts the site and the location of the monitoring wells. Table B-1 Site History, UST/AST System Information Tank No. Installation Date Capacity (gallons) Construction Materials Dimensions (inches) Removal Date Contents Previous Contents 1 4/30/1989 6,000 Steel 63” x 216” Present Gasoline Gasoline 2 4/30/1989 8,000 Steel 63” x 216” Present Gasoline Gasoline 3 4/30/1989 4,000 Steel 63” x 216” Present Gasoline Gasoline 4 4/30/1989 2,000 Steel (STP-3) 64” x 12’ 6/16/14 Diesel Diesel 5 4/30/1989 1,000 Steel (STP-3) 64” x 6’ 6/16/14 Kerosene Kerosene 6 2014 (AST) 500 Steel 64” x 12’ Present Kerosene Kerosene 7 2014 (AST) 1,500 Diesel Diesel 8 Unknown 2,000 Steel Unknown 1989 Gasoline Gasoline 9 Unknown 2,000 Steel Unknown 1989 Gasoline Gasoline 10 Unknown 1,000 Steel Unknown 1989 Gasoline Gasoline Table B-2 Site History, UST Owner/Operator Information Owner’s Name Address Phone Number Dates of Ownership Eden Oil Company, Inc. P.O. Box 1375 Reidsville, NC 27323 (336) 349-8228 1989-Present C. HISTORIC FREE PRODUCT GAUGING Approximately 0.69 feet of free product were measured in monitoring well MW-1 during the LSA sampling event on November 11, 2014. Pre-CAP Monitoring Report October 5, 2016 Pagetown Exxon, Reidsville, North Carolina Progress Project 1016066.002 - 3 - On March 9, 2015, Progress gauged free product in monitoring well MW-1 prior to the MMPE event. Approximately 2.92 feet of free product were measured in monitoring well MW-1. On April 13, 2015 Progress returned to the site to sample the surrounding water-supply wells and gauge groundwater/free product levels in monitoring well MW-1, as appropriate. Approximately 1.71 feet of free product were measured in monitoring well MW-1. Approximately 5.10 feet of free product were measured in monitoring well MW-1 during a water- supply well sampling event on July 6, 2015. Approximately 5.55 feet of free product were measured in monitoring well MW-1 during the CSA sampling event on August 3, 2015, and 0.80 feet on March 15, 2016. On September 8, 2016 Progress returned to the site to sample the existing monitoring wells and gauge water/free product levels in the monitoring wells, as appropriate. Approximately 0.44 feet of free product was identified in monitoring well MW-1. D. GROUNDWATER ASSESSMENT ACTIVITIES On September 8, 2016 Progress returned to the site to sample the existing monitoring and recovery wells and to gauge water/free product levels, as appropriate. Approximately 0.44 feet of free product was detected in monitoring well MW-1. Groundwater samples were collected from monitoring wells MW-2 through MW-8, DW-1 and DW-2. Groundwater samples were also collected from water-supply wells 1, 5, 6, 7, 12, 14, 15, 16, 20, and 22. Prior to sampling, the wells were developed until the development water ran relatively clear, and the wells were purged of an additional three casing volumes of water prior to sampling. The groundwater depths in the wells were measured prior to well purging using a decontaminated electric sounder. The wells were previously surveyed to an accuracy of 0.01 foot referenced to an arbitrarily assigned benchmark (top of casing of monitoring well MW-3), which was assigned an elevation of 100 feet above mean sea level. The elevations of the monitoring wells and the water table are both relative to that benchmark. A groundwater elevation map depicting the measured depths to the water table as measured in each of the wells was constructed and is provided as Figure 3. The map depicts the estimated groundwater flow beneath the site to be generally towards the south-southwest. The groundwater samples were decanted into laboratory-supplied bottles and placed into a cooler packed with ice. The cooler was delivered under chain-of-custody to Research & Analytical Laboratories (R&A) for testing. R&A analyzed the groundwater samples collected from monitoring wells MW-2 through MW-6 and DW-1 for volatile organic compounds (VOCs) by Standard Method 6200B plus isopropyl ether (IPE), ethylene dibromide (EDB), and methyl tert- butyl ether (MTBE) and for EDB using EPA Method 504.1. The groundwater samples collected from monitoring wells MW-7, MW-8, and DW-2 were analyzed using Standard Method 6200B only. Groundwater sample analytical results are included in Table B-4 and Figure 4. Laboratory analysis of the groundwater sample collected from monitoring wells MW-3, MW-6, MW-7, MW-8, DW-1, and DW-2 and water-supply wells 1, 5, 6, 7, 12, 15, 16, 20, and 22 did not Pre-CAP Monitoring Report October 5, 2016 Pagetown Exxon, Reidsville, North Carolina Progress Project 1016066.002 - 4 - detect targeted compounds above the their respective North Carolina 2L Groundwater Quality Standards (NC2LGWQS). Laboratory analysis of the groundwater samples collected from monitoring wells MW-2, MW-4, MW-5 and water-supply well 14 detect various targeted compounds above the their respective NC2LGWQS; however, the concentrations do not exceed the applicable North Carolina risk-based Gross Contamination Levels (GCLs) except for the concentration of benzene detected in monitoring well MW-5. A summary of the groundwater results is included as Table B-4 and Figure 5. Isoconentration maps for benzene, MTBE and total BTEX are included as Figures 6 through 8, respectively. A groundwater contamination plume location map is included as Figure 8. BTEX and MTBE versus Time graphs are included in the Appendix. E. REGIONAL GEOLOGY AND HYDROGEOLOGY According to the Geologic Map of North Carolina, the subject site is located in the Carolina Stale Belt of North Carolina. The rocks beneath the site have been characterized as metamorphosed granitic rocks. Groundwater generally is stored in the pore space between individual grains of residual soil and in the fractures within the underlying parent rock. Due to the intense shearing associated with the thrust faulting in the area and the relatively shallow depths to bedrock, it can be expected that the fractures play a major role in the flow of groundwater in the subsurface. Recharge to the water table is primarily by precipitation infiltrating the upper soils and percolating downward, under the influence of gravity, to the groundwater table. Typically, the water table is not a level surface, but a subdued reflection of the land surface. However, the depth to the water table is not constant, and depends on many factors, which include the amount of rainfall, the permeability of the soil, and the amount of groundwater being pumped in the area. F. SITE GEOLOGY AND HYDROGEOLOGY Based on our review of the topographic map and on-site observation, the site is located on an east- west trending ridge. Groundwater generally flows in directions sub-parallel to the ground surface slopes and under the influence of gravity toward points of discharge such as creeks, swamps, drainage swales, or pumped groundwater wells. Based on topographic inference, groundwater beneath the site most likely flows to the south-southwest toward an intermittent tributary of Stony Creek (Figure 1). Based on the excavation and drilling activities at the site, the soil beneath the site consists predominately of a silty to sandy clay material. G. DETERMINATION OF GROUNDWATER FLOW DIRECTION The depth to the groundwater surface in each of the monitoring and recovery wells was measured prior to the monitoring well purging using a decontaminated electric sounder. The wells were surveyed by Progress using a relative benchmark (top of casing for monitoring well MW-3) that was arbitrarily given an elevation of 100 feet. The elevations of the monitoring wells and the groundwater surface are both relative to that benchmark. The relative groundwater elevations are shown in Table B-7. Pre-CAP Monitoring Report October 5, 2016 Pagetown Exxon, Reidsville, North Carolina Progress Project 1016066.002 - 5 - Groundwater elevations are depicted on Figure 3. Based on information collected during the most recent sampling event, the groundwater flow direction appears to be generally to the south- southwest, beneath the site. H. CONCLUSIONS Based on the results of the groundwater sampling event, Progress makes the following conclusions:  Laboratory analysis of the groundwater sample collected from monitoring wells MW-3, MW-6, MW-7, MW-8, DW-1, and DW-2 and water-supply wells 1, 5, 6, 7, 12, 15, 16, 20, and 22 did not detect targeted compounds above the their respective NC2LGWQS.  Laboratory analysis of the groundwater samples collected from monitoring wells MW-2, MW-4, MW-5 and water-supply well 14 detect various targeted compounds above the their respective NC2LGWQS; however, the concentrations do not exceed the applicable North Carolina risk-based GCLs except for the concentration of benzene detected in monitoring well MW-5.  Approximately 0.44 feet of free product was detected in monitoring well MW-1. I. RECOMMENDATIONS Based on the remaining concentrations in select groundwater samples exceeding their respective NC2LGWQS and the GCLs, and free product persisting Progress recommends the following:  Progress recommends having discussions with the NCDEQ to determine corrective action goals and acceptable remediation strategies. Progress will not complete additional activities at the site unless pre-approved by the NCDEQ. FIGURES Figure 1 Topographic Site Map Pagetown Exxon 8035 Cherry Grove Road Reidsville, Caswell County, North Carolina P.O. Box 5884 Winston-Salem, NC 27113 Telephone: (336) 722-9999 Fax: (336) 722-9998 www.progressenvironmental.com United States Department of the Interior USGS 7.5 Minute Series Topographic Map Contour Interval: 10 feet Scale: 1”=2000’ Cherry Grove, North Carolina Date: 1997 Project: Pagetown Exxon Client: Eden Oil Company Progress Job #: 1016066.002 Date: October 2016 SITE Site LEGEND Approximate Monitoring Well Location Product Dispenser MW-1 MW-4 MW-3 MW-2 MW-4 MW-5 MW-6 Approximate R-O-W Approximate Subsurface Utility Location DW-1 G A SG A SG A SK -1/Dies DIESEL K-1 Approximate UST LocationDIESEL K-1/Dies Approximate AST Location DW-2 MW-7 MW-8 H O GRAPHIC SCALE 1" = 30' 30'0'30'60' CHERRY GROVE ROAD PAGETOWN ROADN EW ProgressENVIRONMENTAL, INC.JAB1016066.002OCT 2016JTRAS SHOW NOCT 2016Figure 2.SKFP.O. Box 5884W INSTON-SALEM, NORTH CAROLINA 27113PHONE 336.722.9999 FAX 336.722.9998FIG URE 2SITE M AP8035 CHERRRY G RO VE RO ADREIDSVILLE, N O RTH CARO LINAPROJECT MW-6 LEGEND Approximate Monitoring Well Location & Groundwater Elevation Product Dispenser MW-1 MW-4 MW-3 MW-4 MW-5 Approximate R-O-W Approximate Subsurface Utility Location DW-1 G A SG A SG A SK -1/Dies DIESEL K-1 Approximate UST LocationDIESEL K-1/Dies Approximate AST Location DW-2 MW-7 MW-8 H O GRAPHIC SCALE 1" = 30' 30'0'30'60' CHERRY GROVE ROAD PAGETOWN ROADN EW MW-2 (77.90) (77.91) (79.16) (79.42) (78.70)82.00(82.35) (82.08) Please note: MW-1 was not used in the calculation due to the presence of free product. The Type III wells were also not used in the calculation. Groundwater Contour and Elevation Calculated Groundwater Flow Direction Contour Interval = 1.00 feet 82.00 Inferred Groundwater Contour Elevation (79.90) (FP)81.0080.0079.0078.00 ProgressENVIRONMENTAL, INC.JAB1016066.002OCT 2016JTRAS SHOW NOCT 2016Figure 3.SKFP.O. Box 5884W INSTON-SALEM, NORTH CAROLINA 27113PHONE 336.722.9999 FAX 336.722.9998FIG URE 3PO TENTIO M ETR IC SUR FACE M AP8035 CHERRRY G RO VE RO ADREIDSVILLE, N O RTH CARO LINAPROJECT GRAPHIC SCALE 1" = 300' 300'0'300'600'ProgressENVIRONMENTAL, INC.JAB1016066.002OCT 2016JTRAS SHOW NOCT 2016Figure 4.SKFP.O. Box 5884W INSTON-SALEM, NORTH CAROLINA 27113PHONE 336.722.9999 FAX 336.722.9998FIG URE 4W ATER-SU PPLY W ELL LO C ATIO N M AP8035 CHERRRY G RO VE RO ADREIDSVILLE, N O RTH CARO LINAPROJECTAPPROXIMATE OBSERVED WATER-SUPPLY WELL LOCATION 1 2 3 22 5 6 7 9 10 11 1 2 13 14 15 16 17 20 23 24 18 19 1,000'500'250'750' BQL LEGEND Approximate Monitoring Well Location Product Dispenser MW-1 MW-4 MW-3 MW-2 MW-4 MW-5 MW-6 Approximate R-O-W Approximate Subsurface Utility Location DW-1 G A SG A SG A SK -1/Dies DIESEL K-1 Approximate UST LocationDIESEL K-1/Dies Approximate AST Location DW-2 MW-7 MW-8 H O GRAPHIC SCALE 1" = 30' 30'0'30'60' CHERRY GROVE ROAD PAGETOWN ROADN EW Benzene 34.5 ppb Chloroform 3.99 ppb Ethylbenzene 98.5 ppb I-Propylbenzene 20.3 ppb Naphthalene 115 ppb N-Butylbenzene 7.40 ppb N-Propylbenzene 28.5 ppb P-Isopropyltoluene 10.2 ppb Sec-Butylbenzene 9.48 ppb Toluene 32 ppb 1,2,4-Trimethylbenzene 385 ppb 1,3,5-Trimetylbenzene 97.8 ppb Total Xylenes 810 ppb Benzene 0.95 ppb Ethylbenzene 27.7 ppb I-Propylbenzene 6.99 ppb Naphthalene 27.4 ppb N-Butylbenzene 1.33 ppb N-Propylbenzene 8.17 ppb P-Isopropyltoluene 4.99 ppb sec-Butylbenzene 3.34 ppb Toluene 10.9 ppb 1,2,4-Trimethylbenzene 115 ppb 1,3,5-Trimethylbenzene 49.3 ppb Total Xylenes 193 ppb Below Quantitation Limits Naphthalene 0.69 ppb 1,2,4-Trimetylbenzene 0.82 ppb 1,3,5-Trimethylbenzene 1.26 ppb Total Xylenes 1.27 ppb MTBE 18.3 ppb IPE 0.95 ppb MTBE 10.7 ppb IPE 2.38 ppb Chloroform 3.94 ppb Benzene 5,070 ppb 1,2-Dichloroethane 66 ppb Ethylbenzene 2,960 ppb I-Propylbenzene 148 ppb Naphthalene 585 ppb N-Propylbenzene 330 ppb Toluene 30,400 ppb 1,2,4-Trimethylbenzene 2,500 ppb 1,3,5-Trimethylbenzene 601 ppb Total Xylenes 17,700 ppb MTBE 7,060 ppb IPE 1,050 ppb EDB 31.4 ppb Free Product ProgressENVIRONMENTAL, INC.JAB1016066.002SEP 2016JTRAS SHOW NSEP 2016Figure 5.SKFP.O. Box 5884W INSTON-SALEM, NORTH CAROLINA 27113PHONE 336.722.9999 FAX 336.722.9998FIG URE 5G R O UNDW ATER ANALYTICAL RESULTS M AP8035 CHERRRY G RO VE RO ADREIDSVILLE, N O RTH CARO LINAPROJECT K-1 LEGEND Approximate Monitoring Well Location and benzene concentration (ppb) Product Dispenser MW-1 MW-3 MW-5 MW-5 MW-6 Approximate R-O-W Approximate Subsurface Utility Location G A SG A SG A SK -1/Dies DIESEL Approximate UST LocationDIESEL K-1/Dies Approximate AST Location MW-7 MW-8 H O GRAPHIC SCALE 1" = 30' 30'0'30'60' CHERRY GROVE ROAD PAGETOWN ROADN EW MW-4 (BQL) (BQL) (5,070) MW-2 (0.95) (BQL) (5,070) (34.5) 1,000 (FP) 100 BQL DW-1 (BQL)DW-2 (BQL) (BQL) Please note: The type III monitoring wells were not utilized in the isoconcentration maps.ProgressENVIRONMENTAL, INC.JAB1016066.002OCT 2016JTRAS SHOW NOCT 2016Figure 6.SKFP.O. Box 5884W INSTON-SALEM, NORTH CAROLINA 27113PHONE 336.722.9999 FAX 336.722.9998FIG URE 6BENZENE ISO C O NCENTRATIO N M AP8035 CHERRRY G RO VE RO ADREIDSVILLE, N O RTH CARO LINAPROJECT BQL LEGEND Approximate Monitoring Well Location Product Dispenser MW-1 MW-4 MW-3 MW-2 MW-4 MW-5 MW-6 Approximate R-O-W Approximate Subsurface Utility Location DW-1 G A SG A SG A SK -1/Dies DIESEL K-1 Approximate UST LocationDIESEL K-1/Dies Approximate AST Location DW-2 MW-7 MW-8 H O GRAPHIC SCALE 1" = 30' 30'0'30'60' CHERRY GROVE ROAD PAGETOWN ROADN EW Benzene 34.5 ppb Chloroform 3.99 ppb Ethylbenzene 98.5 ppb I-Propylbenzene 20.3 ppb Naphthalene 115 ppb N-Butylbenzene 7.40 ppb N-Propylbenzene 28.5 ppb P-Isopropyltoluene 10.2 ppb Sec-Butylbenzene 9.48 ppb Toluene 32 ppb 1,2,4-Trimethylbenzene 385 ppb 1,3,5-Trimetylbenzene 97.8 ppb Total Xylenes 810 ppb Benzene 0.95 ppb Ethylbenzene 27.7 ppb I-Propylbenzene 6.99 ppb Naphthalene 27.4 ppb N-Butylbenzene 1.33 ppb N-Propylbenzene 8.17 ppb P-Isopropyltoluene 4.99 ppb sec-Butylbenzene 3.34 ppb Toluene 10.9 ppb 1,2,4-Trimethylbenzene 115 ppb 1,3,5-Trimethylbenzene 49.3 ppb Total Xylenes 193 ppb Below Quantitation Limits Naphthalene 0.69 ppb 1,2,4-Trimetylbenzene 0.82 ppb 1,3,5-Trimethylbenzene 1.26 ppb Total Xylenes 1.27 ppb MTBE 18.3 ppb IPE 0.95 ppb MTBE 10.7 ppb IPE 2.38 ppb Chloroform 3.94 ppb Benzene 5,070 ppb 1,2-Dichloroethane 66 ppb Ethylbenzene 2,960 ppb I-Propylbenzene 148 ppb Naphthalene 585 ppb N-Propylbenzene 330 ppb Toluene 30,400 ppb 1,2,4-Trimethylbenzene 2,500 ppb 1,3,5-Trimethylbenzene 601 ppb Total Xylenes 17,700 ppb MTBE 7,060 ppb IPE 1,050 ppb EDB 31.4 ppb Free Product ProgressENVIRONMENTAL, INC.JAB1016066.002OCT 2016JTRAS SHOW NOCT 2016Figure 5.SKFP.O. Box 5884W INSTON-SALEM, NORTH CAROLINA 27113PHONE 336.722.9999 FAX 336.722.9998FIG URE 5G R O UNDW ATER ANALYTICAL RESULTS M AP8035 CHERRRY G RO VE RO ADREIDSVILLE, N O RTH CARO LINAPROJECT K-1 LEGEND Approximate Monitoring Well Location and Total BTEX concentration (ppb) Product Dispenser MW-1 MW-3 MW-4 MW-5 MW-6 Approximate R-O-W Approximate Subsurface Utility Location G A SG A SG A SK -1/Dies DIESEL Approximate UST LocationDIESEL K-1/Dies Approximate AST Location MW-7 MW-8 H O GRAPHIC SCALE 1" = 30' 30'0'30'60' CHERRY GROVE ROAD PAGETOWN ROADN EW MW-4 MW-2 (232.55) (56,130) (975) 20,000 (FP) 1,000 BQL DW-1 (1.27)DW-2 (BQL) (BQL) (BQL) (BQL) (BQL) (232.55) Please note: The type III monitoring wells were not utilized in the isoconcentration maps.ProgressENVIRONMENTAL, INC.JAB1016066.002OCT 2016JTRAS SHOW NOCT 2016Figure 7.SKFP.O. Box 5884W INSTON-SALEM, NORTH CAROLINA 27113PHONE 336.722.9999 FAX 336.722.9998FIG URE 7TO TAL BTEX ISO CO N CENTR ATIO N M AP8035 CHERRRY G RO VE RO ADREIDSVILLE, N O RTH CARO LINAPROJECT K-1 LEGEND Approximate Monitoring Well Location and MTBE concentration (ppb) Product Dispenser MW-1 MW-3 MW-7 MW-5 MW-6 Approximate R-O-W Approximate Subsurface Utility Location G A SG A SG A SK -1/Dies DIESEL Approximate UST LocationDIESEL K-1/Dies Approximate AST Location MW-7 MW-8 H O GRAPHIC SCALE 1" = 30' 30'0'30'60' CHERRY GROVE ROAD PAGETOWN ROADN EW MW-4 (BQL) (38.9) MW-2 (BQL) (BQL) DW-1 DW-2 (BQL) (10.7) 5,000 BQL (18.3) Please note: The type III monitoring wells were not utilized in the isoconcentration maps. (BQL) (7,060) 100 ProgressENVIRONMENTAL, INC.JAB1016066.002OCT 2016JTRAS SHOW NOCT 2016Figure 8.SKFP.O. Box 5884W INSTON-SALEM, NORTH CAROLINA 27113PHONE 336.722.9999 FAX 336.722.9998FIG URE 8M TBE ISO CO NC ENTRATIO N M AP8035 CHERRRY G RO VE RO ADREIDSVILLE, N O RTH CARO LINAPROJECT TABLES 504.1 Well ID Date Collected (m/dd/yy) Depth to Water (Ft. Below TOC) 11/11/2014 FP (0.69')FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP NM NM NM NM NM NM 4/13/2015 FP (1.71')FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP NM NM NM NM NM NM 7/6/2015 FP (5.10')FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP NM NM NM NM NM NM 8/3/2015 FP (5.55')FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP NM NM NM NM NM NM 3/23/2016 FP (0.80')FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP NM NM NM NM NM NM 9/9/2016 FP (0.44')FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP NM NM NM NM NM NM 11/12/2014 21.61 BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL See Data NA NA BQL BQL 111 BQL 5.31 18.5 78.9 NM NM NM 8/3/2015 21.18 33.3 NA NA NA 90.6 NA NA NA NA NA NA 292 NA NA 1,120 BQL BQL 17.8 17.6 39.7 See Data NA NA NA NA NA NA 7.36 18.5 74.3 NM NM NM 3/23/2016 17.65 4.71 BQL 2.72 BQL 13.4 2.38 9.61 0.55 2.98 1.15 0.94 2.97 35.8 12.8 74.3 BQL BQL NA NA NA NA NA NA NA NA NA NA 5.91 19.3 72.9 NM NM NM 9/9/2016 20.43 34.5 BQL 3.99 BQL 98.5 20.3 115 7.40 28.5 10.2 9.48 32 385 97.8 810 BQL BQL NA NA NA NA BQL NA NA NA NA NA 5.91 19.3 72.9 NM NM NM 11/12/2014 22.54 BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL See Data NA NA BQL BQL BQL BQL 5.25 17.4 57.5 NM NM NM 8/3/2015 22.24 BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA 8.12 17.4 53.8 NM NM NM 3/23/2016 18.75 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NA NA NA 5.60 17.6 52.1 NM NM NM 9/9/2016 21.30 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL NA NA NA NA BQL NA NA NA NA NA 5.60 17.6 52.1 NM NM NM 11/12/2014 23.15 BQL NA NA NA 1.94 NA NA NA NA NA NA 2.15 NA NA 12.3 BQL BQL BQL BQL BQL See Data NA NA BQL 402 109 BQL 5.31 17.5 59.5 NM NM NM 8/3/2015 22.65 BQL NA NA NA 1.14 NA NA NA NA NA NA 1.31 NA NA 13.1 BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA 5.32 16.9 48.1 NM NM NM 3/23/2016 19.75 BQL BQL BQL BQL 2.49 BQL 14.5 BQL BQL 1.17 BQL 5.62 7.78 15.3 41.9 BQL BQL NA NA NA NA NA NA NA NA NA NA 5.56 17.4 50.3 NM NM NM 9/9/2016 21.20 0.95 BQL BQL BQL 27.7 6.99 27.4 1.33 8.17 4.99 3.34 10.9 115 49.3 193 BQL BQL NA NA NA NA BQL NA NA NA NA NA 5.56 17.4 50.3 NM NM NM 8/3/2015 21.74 6,610 NA NA NA 4,970 NA NA NA NA NA NA 54,800 NA NA 44,900 11,600 1,580 132 67.6 621 See Data NA NA 79,700 68,730 62,049 BQL 4.93 19.0 101.9 NM NM NM 3/23/2016 17.51 1,370 BQL BQL BQL 2,120 153 497 BQL 311 BQL BQL 14,100 2,280 608 12,300 BQL 97 NA NA NA NA NA NA NA NA NA NA 5.81 19.1 193 NM NM NM 9/9/2016 19.95 5,070 BQL BQL 66 2,960 148 585 BQL 330 BQL BQL 30,400 2,500 601 17,700 7,060 1,050 NA NA NA NA 31.4 NA NA NA NA NA 5.81 19.1 193 NM NM NM 8/3/2015 20.53 BQL NA NA NA BQL NA NA NA NA NA NA 2.69 NA NA 6.83 BQL BQL BQL BQL BQL BQL NA NA 183 260 260 BQL 4.63 18.3 414 NM NM NM 3/23/2016 15.17 BQL 2.71 60.7 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NA NA NA 5.35 18.4 807 NM NM NM 9/9/2016 19.62 BQL BQL 3.94 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL NA NA NA NA BQL NA NA NA NA NA 5.35 18.4 807 NM NM NM 3/23/2016 16.00 BQL BQL 0.84 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 38.9 1.43 BQL BQL BQL BQL BQL 28.5 187 BQL BQL BQL 7.44 18.1 156.6 NM NM NM 9/9/2016 19.50 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 18.3 0.95 BQL BQL BQL BQL NA NA 187 BQL BQL BQL 7.44 18.1 156.6 NM NM NM 3/23/2016 17.29 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 8.40 BQL BQL BQL BQL 9.20 17.8 42.4 NM NM NM 9/9/2016 20.91 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL NA NA BQL BQL BQL BQL 9.20 17.8 42.4 NM NM NM 8/3/2015 NM BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA 2.66 BQL BQL BQL BQL BQL See Data NA NA BQL BQL 132 BQL 9.56 18.1 328 NM NM NM 3/23/2016 19.18 BQL BQL 0.63 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL NA NA NA NA NA BQL NA NA NA NA 7.35 17.4 203 NM NM NM 9/9/2016 22.20 BQL BQL BQL BQL BQL BQL 0.69 BQL BQL BQL BQL BQL 0.82 1.26 1.27 BQL BQL NA NA NA NA BQL NA NA NA NA NA NM NM NM NM NM NM 3/23/2016 18.06 7.22 BQL BQL BQL 1.18 0.57 1.72 BQL BQL BQL BQL 5.94 7.98 BQL 29.7 15.6 3.38 BQL BQL BQL See Data 0.122 NA 155 184 BQL BQL 5.81 19.1 251 NM NM NM 9/9/2016 21.29 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 10.7 2.38 BQL BQL BQL See Data NA NA BQL BQL BQL BQL NM NM NM NM NM NMDW-2 MW-3 MW-1 MW-5 MW-6 DW-1 MW-2 MW-7 MW-8 C9-C18 AliphaticsC5-C8 AliphaticsContaminant of Concern IPEMW-4 C9-C22 AromaticsEthylbenzeneTolueneC19-C36 AliphaticsTotal XylenesMTBE1-MethylnaphthaleneNaphthaleneTICs DetectedSec-Butylbenzene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneI-PropylbenzeneNaphthaleneN-Butylbenzenep-IsopropyltolueneEPH & VPHAnalytical Method Table B-4 Summary of Groundwater Analytical Results Pre-CAP Monitoring Report Pagetown Exxon Field Measurements EDBLead625BNA+10 TICs 2-Methylnaphthalene602 or 6200B BenzeneBromodichloromethaneChloroformN-Propylbenzene1,2-DichloroethanepHConductivity (mS/cm)ORPDO (mg/L)CO2Temperature (ºC) 504.1 Well ID Date Collected (m/dd/yy) Depth to Water (Ft. Below TOC)C9-C18 AliphaticsC5-C8 AliphaticsContaminant of Concern IPEC9-C22 AromaticsEthylbenzeneTolueneC19-C36 AliphaticsTotal XylenesMTBE1-MethylnaphthaleneNaphthaleneTICs DetectedSec-Butylbenzene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneI-PropylbenzeneNaphthaleneN-Butylbenzenep-IsopropyltolueneEPH & VPHAnalytical Method Field Measurements EDBLead625BNA+10 TICs 2-Methylnaphthalene602 or 6200B BenzeneBromodichloromethaneChloroformN-Propylbenzene1,2-DichloroethanepHConductivity (mS/cm)ORPDO (mg/L)CO2Temperature (ºC)3/23/2016 --BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NA NA NA NM NM NM NM NM NM 9/9/2016 --BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NA NA NA NM NM NM NM NM NM WSW-2 7/6/2015 --BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM WSW-3 7/6/2015 --BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM 4/13/2015 --BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM 7/6/2015 --BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM 3/23/2016 --BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NA NA NA NM NM NM NM NM NM 9/9/2016 --BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NA NA NA NM NM NM NM NM NM 4/13/2015 --NA NA NA NA BQL NA NA NA NA NA NA NA NA NA NA BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM 7/6/2015 --BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM 3/23/2016 --BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NA NA NA NM NM NM NM NM NM 9/9/2016 --BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NA NA NA NM NM NM NM NM NM 4/13/2015 --BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM 7/6/2015 --BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM 3/23/2016 --BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NA NA NA NM NM NM NM NM NM 9/9/2016 --BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NA NA NA NM NM NM NM NM NM WSW-9 7/6/2015 --BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM WSW-10 7/6/2015 --BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM 4/13/2015 --BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM 7/6/2015 --BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM 3/23/2016 --BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NA NA NA NM NM NM NM NM NM 9/9/2016 --BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NA NA NA NM NM NM NM NM NM WSW-13 7/6/2015 --BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM 4/13/2015 --21.7 NA NA NA BQL NA NA NA NA NA NA BQL NA NA 31.6 BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM 7/6/2015 --143 NA NA NA BQL NA NA NA NA NA NA BQL NA NA 225 BQL BQL BQL BQL 17.0 NA NA NA NA NA NA NA NM NM NM NM NM NM 3/23/2016 --BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NA NA NA NM NM NM NM NM NM 4/12/2016 --7.1 BQL BQL 3.4 9.5 1.3 5.6 BQL BQL BQL BQL BQL 21.6 4.8 17.2 BQL BQL NA NA NA NA NA NA NA NA NA NA NM NM NM NM NM NM 9/9/2016 --32.6 BQL BQL 8.93 20.4 2.13 9.49 BQL BQL BQL BQL BQL 38.5 6.11 34 BQL BQL NA NA NA NA NA NA NA NA NA NA NM NM NM NM NM NM 4/13/2015 --BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM 7/6/2015 --BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM 9/9/2016 --BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM WSW-16 7/6/2015 --BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM WSW-17 7/6/2015 --BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM 4/13/2015 --BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM 7/6/2015 --BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM 3/23/2016 --BQL BQL BQL BQL 0.86 BQL BQL BQL BQL BQL BQL BQL BQL BQL 1.45 BQL BQL NA NA NA NA NA NA NA NA NA NA NM NM NM NM NM NM 9/9/2016 --BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 1.47 BQL BQL NA NA NA NA NA NA NA NA NA NA NM NM NM NM NM NM 4/13/2015 --BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM 7/6/2015 --BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM 3/23/2016 --BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NA NA NA NM NM NM NM NM NM 9/9/2016 --BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NA NA NA NM NM NM NM NM NM WSW-23 7/6/2015 --BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM WSW-24 7/6/2015 --BQL NA NA NA BQL NA NA NA NA NA NA BQL NA NA BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NM NM NM NM NM NM 1 0.6 70 0.4 600 70 6 70 70 25 70 600 400 400 500 20 70 30 1 6 N/A 0.02 15 400 700 200 10,000 6.5-8.5 NS NS NS NS NS 5,000 N/A 70,000 400 84,500 25,000 6,000 6,900 30,000 11,700 8,500 260,000 28,500 25,000 85,500 20,000 70,000 12,500 1,000 5,000 N/A 50 15,000 NS NS NS NS NS NS NS NS NS NS 5 NS NS 5 700 NS NS NS NS NS NS 1,000 NS NS 10,000 NS NS NS NS NS N/A NS 15 NS NS NS NS NS NS NS NS NS NS = Detected Concentration Exceeds the North Carolina 2L Groundwater Quality Standards (NC2LGWQS) or the EPA Drinking Water Standard as Applicable = Detected Concentration Exceeds the GCL BQL = Below Quantitation Limits Results are reported in µg/l µg/L = micrograms per liter GCL = gross contamination level TOC = top of casing NS = No Standard N/A = Not Applicable EPH and VPH = Extractable and Volatile Petroleum Hydrocarbons FP = Free Product NA = Not Analyzed NM = Not Measured WSW-1 EPA Drinking Water Standard (µg/l) GCL (µg/l) WSW-14 WSW-15 WSW-12 WSW-20 NC2LGWQS Standard (µg/l) WSW-5 WSW-22 WSW-6 WSW-7 9/8/2016 MW-1 10/22/2014 2 35 20-35 21.54 99.66 FP (0.44)78.12 FP (0.80')80.66 FP (5.55')73.17 FP (5.10')NR FP (1.71')78.15 FP (0.69')76.45 MW-2 11/11/2014 2 30 15-30 20.43 99.85 MW-3 11/11/2014 2 30 15-30 21.30 100.00 MW-4 11/11/2014 2 30 15-30 21.20 99.10 MW-5 7/23/2015 2 30 15-30 19.95 99.11 MW-6 7/23/2015 2 30 15-30 19.62 97.53 MW-7 3/17/2016 2 30 15-30 19.50 101.85 MW-8 3/16/2016 2 30 15-30 20.91 102.99 DW-1 7/22 & 23/2015 2 45 (I) 55(O)50-55 22.20 99.94 DW-2 3/16 & 17/2016 2 45 (I) 55(O)50-55 21.29 99.94 ** - The top-of-casing elevation of each functioning well relative to a benchmark was established with an assumed elevation of 100 feet (MW-3 TOC). Please note: The depth to water measurement presented for MW-1 does not account for the presence of free product. NR = Not Reported NM NM NM NM Depth to Water (feet TOC) 78.24 77.46 75.95 NM NM NM NM NM NM NM NM NM NM NM 11/11/2014 Groundwater Elevation (feet) 4/13/2015 Groundwater Elevation (feet) NM NM NM NM NM NM NM NM NM NM 76.45 77.37 NM 77.00 78.67 77.76 NM NM 82.36 85.85 85.70 NM NM 82.20 81.25 79.35 81.60 Groundwater Elevation (feet) 3/23/2016 Table B-7 Well Construction Information and Historical Groundwater Elevations Pre-CAP Monitoring Report Pagetown Exxon Well Diameter (inches) Relative Elevation (feet TOC)Depth (feet) Screen Interval (feet) Installation DateMonitoring Well ID Groundwater Elevation (feet) 7/6/2015 Groundwater Elevation (feet) 8/3/2015 Groundwater Elevation (feet) 9/8/2016 79.42 78.70 77.90 78.65 79.16 77.91 82.35 82.08 77.74 APPENDIX 78.24 78.67 82.20 79.42 0 33.3 4.71 0 5 10 15 20 25 30 35 40 76 77 78 79 80 81 82 83 FEETDATE MW-2 Benzene vs. Groundwater Elevation Groundwater Elevation Benzene Concentration 78.24 78.67 82.20 79.42 0 0 0 0 0 10 20 30 40 50 60 70 80 90 FEETDATE MW-2 MTBE vs. Groundwater Elevation Groundwater Elevation MTBE Concentration 77.37 81.60 79.16 6,610 1,370 5,070 0 1000 2000 3000 4000 5000 6000 7000 75 76 77 78 79 80 81 82 8/1/2015 9/1/2015 10/1/2015 11/1/2015 12/1/2015 1/1/2016 2/1/2016 3/1/2016 4/1/2016 5/1/2016 6/1/2016 7/1/2016 8/1/2016 9/1/2016FEET DATE MW-5 Benzene vs. Groundwater Elevation Groundwater Elevation Benzene Concentration 77.37 81.60 79.16 11,600 0 7,060 0 2000 4000 6000 8000 10000 12000 14000 75 76 77 78 79 80 81 82 8/1/2015 9/1/2015 10/1/2015 11/1/2015 12/1/2015 1/1/2016 2/1/2016 3/1/2016 4/1/2016 5/1/2016 6/1/2016 7/1/2016 8/1/2016 9/1/2016FEET DATE MW-5 MTBE vs. Groundwater Elevation Groundwater Elevation MTBE Concentration