MO-9367_40819_CA_MRP_20240201

CORRECTIVE ACTION PERFORMANCE REPORT

CIRCLE K NO. 2720828
10329 Park Road
Charlotte, North Carolina

NCDEQ UST Facility No. 33712
NCDEQ Incident No. 40819
ATC Project No. CIRK082808

Submitted On:
January 31, 2024

Prepared for:
Mr. Brent Puzak
Environmental Manager

Circle K Stores Inc.
1100 Situs Court
Suite 100
Raleigh, North Carolina 27606

Prepared by:

ATC Associates of North Carolina, P.C.

7606 Whitehall Executive Center Drive
Charlotte, North Carolina 28273
tel [phone]
fax [phone]
www.atcassociates.com

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EXECUTIVE SUMMARY

ATC has completed an Annual Monitoring Report at the Circle K Store 2720828, located at 10329
Park Road, in Charlotte, Mecklenburg County, North Carolina. Assessment activities conducted
from October through December 2023 included the installation of one Type III well (TW-2)
monitoring well, two air sparge wells (AS-1 and AS-2), and two recovery wells (RW-2 and RW-3).
Two 96-hour Mobile Multi-Phase Extraction (MMPE) events, a groundwater sampling event, and
Top of Casing elevation (TOC) measurements in accordance with the Pre-Approval Task
Authorization (PATA) number 40819-07, approved on September 5, 2023.

The site is currently an active convenience store and gas station with petroleum retail and
operates two 10,000-gallon gasoline underground storage tanks (USTs) and one 10,000-gallon
diesel UST. A release from the UST system was reported on May 4, 2018. Water supply wells
have not been identified within 1,500-feet of the property. ATC has conducted multiple phases of
assessment and remediation activities since that time.

Results of previous and current assessment activities indicate the following:
 The nearest surface water body is an unnamed tributary of McMullen Creek, located
approximately 1,000 feet to the east of the source area.
 Light nonaqueous phase liquid (LNAPL) is present on site.
 Atlas supervised the installation of one Type III well (TW-2) monitoring well, two air sparge
wells (AS-1 and AS-2), and two recovery wells (RW-2 and RW-3).
 On October 30, 2023 and November 6, 2023, two 96-hour MMPE events were conducted
using MW-5, MW-8, MW-10, RW-1, RW-2, and AS-2 as target extraction wells in the first
MMPE event and MW-1, MW-5, MW-9, MW-10, RW-1, and RW-3 in the subsequent
MMPE event.
o The October 2023 MMPE event generated approximately 5,468 gallons of fluid,
including 30 gallons of free -phase LNAPL, and recovered approximately 52.95
gallons of volatile organic compounds (VOCs) as vapor emissions.
o The November 2023 MMPE event generated approximately 6,268 gallons of fluid,
including 11 gallons of free-phase LNAPL, and recovered approximately 45.17
gallons of volatile organic compounds (VOCs) as vapor emissions.
 On December 7, 2023, monitoring wells MW-1 through MW-14, TW-1, TW-2, RW-1 RW-
2, and AS-1 were gauged for liquid levels and total well depths. LNAPL thickness was
measured in wells MW-1 at 0.20 feet, MW-5 at 0.03 feet, MW-7 at 0.58 feet, MW-8 at 0.40
feet, MW-9 at 0.60 feet, MW-10 at 0.49 feet, MW-11 at 3.00 feet, MW-13 at 0.01 feet, RW-
1 at 0.47 feet, RW-2 at 0.02 feet, RW-3 at 0.69 feet.
 On December 7 and 8, 2023, ATC sampled monitoring wells MW-2, MW-3, MW-4, MW-
6, MW-12, MW-14, TW-1, TW-2, AS-1, and AS-2. Monitoring wells MW-1, MW-5, MW-7,
MW-8, MW-9, MW-10, MW-11, MW-13, RW-1, RW-2, and RW-3 were not sampled due
to the presence of measurable LNAPL.
 Dry-cleaning solvent tetrachlorethylene (PCE) was detected above the North Carolina 2L
Groundwater Quality Standards as defined in Title 15A, NCAC, Subchapter 2L, Part .0202
(2L Standard) in eight monitoring wells (AS-2, MW-2, MW-3, MW-6, MW-12, MW-14, TW-
1, and TW-2), and PCE was detected with levels above the North Carolina Gross
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Contamination Standards in MW-3. Trichloroethylene (TCE) was detected above the 2L
Standards in seven wells (AS-2, MW-2, MW-3, MW-12, MW-14, TW-1, and TW-2).
 Monitoring wells AS-1, AS-2, MW-2, MW-3, MW-6, MW-12, MW-14, TW-1, and TW-2
contained multiple petroleum constituents in excess of the 2L Standards.
 Petroleum constituents were not detected above the laboratory detection limits in well
MW-4.

TCE and PCE are chemicals typically detected in solvent releases. ATC does not have any
evidence of a solvent release on the Circle K Store 2720828 property. Therefore, any TCE or
PCE detected in the groundwater samples collected at the Circle K Store 2720828 are assumed
to not be related to the UST release.

Dissolved-phase petroleum contamination in groundwater has not been horizontally delineated,
with the exception of the western portion of the site as indicated by the analytical results of MW-
4.

Based on the findings of the current and previous site activities, ATC recommends the following:

 Conduct an MMPE/AS event, the first utilizing MW-1, MW-8, MW-9, MW-11,and
RW-3 as target extraction wells.

 Complete a comprehensive groundwater monitoring event approximately 30 days
after the MMPE/AS events and report findings in a Corrective Action Performance
Report.

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TABLE OF CONTENTS
SITE INFORMATION ................................................................................................................. III
EXECUTIVE SUMMARY .......................................................................................................... IV
1.0 INTRODUCTION ............................................................................................................. 7
2.0 SITE CHARACTERIZATION AND HISTORY ................................................................. 7
2.1 Receptor Survey 7
2.2 Site History 8
3.0 GEOLOGIC FRAMEWORK .......................................................................................... 10
3.1 Site and Regional Geology 10
3.2 Site and Regional Hydrogeology 10
3.3 Hydrogeologic Investigation 11
4.0 CORRECTIVE ACTION AND ASSESSMENT .............................................................. 11
4.1 Monitoring and Recovery Well Installation 11
4.2 Mobile Multi-Phase Extraction Event 12
4.3 Liquid Level Measurements 13
4.3 Groundwater Sampling Results 14
5.0 CONCLUSIONS AND RECOMMENDATIONS ............................................................. 15
6.0 LIMITATIONS ............................................................................................................... 16
7.0 REFERENCES .............................................................................................................. 16
TABLES
Table 1: Site History - UST System and Other Release Information
Table 2: Site History – UST Owner/Operator Information
Table 3: Adjoining Property Owners
Table 4: Water Supply Wells & Other Receptor Information
Table 5: Monitoring Well Construction Information
Table 6: Groundwater Elevation Data
Table 7: Groundwater Analytical Results
Table 8: LNAPL Recovery Information
FIGURES
Figure 1: Site Vicinity Map
Figure 2: Site Map
Figure 3: Groundwater Elevation Map
Figure 4: Benzene Isoconcentration Map
Figure 5: LNAPL Map
Figure 6: Contaminants of Concern Map

APPENDICES
Appendix A: Soil Boring Logs and Well Construction Records
Appendix B: MMPE Data & Emissions Calculations and Manifests
Appendix C: Laboratory Analytical Report

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1.0 INTRODUCTION
This Corrective Action Performance Report presents a summary of activities conducted at the site
by ATC Associates of North Carolina, PC (ATC) from October through December 2023. The
Circle K 2720828 facility is located at 10329 Park Road, Charlotte, Mecklenburg County, North
Carolina (site). Summaries of UST system and owner/operator information are included in Table
1 and Table 2. A site vicinity map with topographic features is included as Figure 1.

The site is currently operated by Circle K Stores, Inc. as a convenience store and gas station with
petroleum retail. During field activities, the site was observed to be developed with one single-
story building, three active underground storage tanks (USTs), and one fuel canopy with three
dispenser islands. Site features are illustrated on Figure 2.

These assessment activities were conducted in accordance with the Pre-Approval Task
Authorization (PATA) number 40819-07, approved on September 5, 2023.
2.0 SITE CHARACTERIZATION AND HISTORY
The site is currently utilized as an active convenience store and gas station. The majority of the
site is covered by impervious surfacing (i.e. buildings, asphalt, concrete, etc.). Adjoining to the
north is Park Road and medical offices, with Park Cedar Drive and a CVS store bounding the
property toward the east. To the south and west is a commercial shopping center. Adjoining
property owners are summarized in Table 3.

The UST system consists of two 10,000-gallon gasoline USTs and one 10,000-gallon diesel UST,
with three associated dispensing islands. According to information obtained from the NCDEQ
“UST Registry Database”, the USTs were installed in 1989.

The site is at an elevation of approximately 608-feet above mean sea level. The general
topography of the site is relatively flat. Surface drainage generally follows the grade of the site
and ultimately discharges to a storm sewer system and/or swales.

2.1 Receptor Survey
During previous assessment activities, ATC conducted a receptor survey to identify water supply
wells, surface water bodies, and other potential receptors within 1,500-feet of the source area.
The receptor survey included reviewing a United States Geological Survey (USGS) 7.5-Minute
Quadrangle Topographic Map (Figure 1) to identify possible surface water bodies in the vicinity,
issuing questionnaires to property owners within 500 feet of the source area, and conducing a
vehicular reconnaissance. During the receptor survey, ATC did not identify water supply wells
within 1,500 feet of the property.

According to the topographic map, the nearest surface water body is an unnamed tributary of
McMullen Creek, located approximately 1,000 feet to the east of the source area, and an unnamed
tributary of Little Sugar Creek was depicted approximately 1,700 feet to the northwest of the
source area. However, these surface water bodies were not identified during the visual
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reconnaissance. Results of the receptor survey and vehicular reconnaissance are summarized in
Table 4.

2.2 Site History
In April 2018, ATC completed limited site check activities associated with the Unleaded and Diesel
spill buckets, which reportedly failed hydrostatic testing and were suspected to have contributed
to a release at the site. Soil sampling associated with the Diesel spill bucket indicated Total
Petroleum Hydrocarbons - Gasoline Range Organics (TPH-GRO) and TPH - Diesel Range
Organics (DRO) were detected at concentrations in excess of the applicable NCDEQ Action
Levels. A release was reported associated with the diesel fuel spill bucket.

In July 2018, ATC completed a Phase I Limited Site Assessment (LSA), and installed monitoring
well, MW-1, adjacent to the diesel spill bucket. When ATC returned to the site to collect a
groundwater sample, light non-aqueous phase liquid (LNAPL) was measured at a thickness of
6.45 feet, and no groundwater sample was collected. Depth to water was measured to be
approximately 28 feet below ground surface (ft-bgs).

ATC completed a Comprehensive Site Assessment (CSA) and installed six monitoring wells (MW-
2 through MW-6, and TW-1) between November 19, 2018, and January 24, 2019. LNAPL was
measured in both MW-1 and MW-5. Soil samples collected from the monitoring well borings
indicated that soil contamination had been delineated in the horizontal direction and that vertical
contamination extended to the groundwater table. Groundwater samples collected during the CSA
indicated multiple petroleum constituents in excess of the North Carolina 2L Groundwater Quality
Standards as defined in Title 15A, NCAC, Subchapter 2L, Part .0202 (2L Standard). Additionally,
dry cleaner solvent constituents were reported above the applicable Gross Contamination Level
(GCL) and are presumed to be associated with an unrelated release in the vicinity of the site.

In November 2019, ATC conducted a 96-hour Mobile Multi-Phase Extraction (MMPE) event using
monitoring wells MW-1 and MW-5 as target extraction wells. Approximately 5,348 gallons of total
fluids, including 107 gallons of free-phase LNAPL, and approximately 340.7 gallons of VOCs as
vapor were removed from the subsurface. Approximately 30 days after the MMPE event, ATC
conducted a groundwater sampling event. LNAPL was measured in monitoring wells MW-1 and
MW-5. The laboratory analysis indicated Tetrachloroethylene (PCE) was detected in well MW-3
in excess of the GCL. Multiple other petroleum constituents were detected at concentrations
exceeding 2L Standards in monitoring wells MW-2, MW-3, MW-6, and TW-1.

In September 2020, ATC conducted a MMPE event, which generated approximately 5,417
gallons of fluids, including 92 gallons of free-phase LNAPL, and recovered approximately 402.74
gallons of VOCs as vapor. In October 2020, ATC conducted a subsequent groundwater sampling
event. LNAPL was measured in monitoring wells MW-1 and MW-5 at a thickness of 0.94 feet and
0.37 feet, respectively. PCE was detected above the GCL in monitoring well MW-3. Monitoring
wells MW-2, MW-3, MW-6, and TW-1 contained multiple VOCs above 2L Standards. ATC
recommended installing shallow monitoring wells to the north and east of the source area and a
recovery well in the vicinity of the UST pit and using the recovery well during a MMPE.

In March 2021, ATC supervised the installation of monitoring wells MW-7, MW-8, and recovery
well RW-1, to evaluate the contaminant plume to the northeast of the source area and assist in
recovering LNAPL and impacted groundwater during extraction events. Following installation of
the monitoring wells, ATC conducted an MMPE event using monitoring wells MW-1, MW-5, and
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RW-1 as target extraction wells. The MMPE event recovered approximately total 10,000 gallons
of fluids, including 67 gallons of free-phase LNAPL, and 187.46 gallons as vapor. During the
subsequent groundwater monitoring event, LNAPL was measured in wells MW-1, MW-5, MW-8,
and RW-1 ranging from 1.71 feet to 0.43 feet in thickness. PCE was detected above the GCL in
monitoring well MW-3. Monitoring wells MW-2, MW-3, MW-6, MW-7, and TW-1 contained multiple
petroleum constituents at concentrations over 2L Standards. Based on these results, ATC
recommended the installation of three additional shallow monitoring wells and conducting a
MMPE event.

In November 2021, ATC supervised the installation of monitoring wells MW-9, MW-10, and MW-
11 to evaluate the contaminant plume to the northeast and east of the source area and assist in
recovering LNAPL and impacted groundwater during extraction events.

Following installation of the monitoring wells, on December 6, 2021, ATC conducted an MMPE
event using monitoring wells MW-1, MW-5, MW-8 through MW-11, and RW-1 as target extraction
wells. The MMPE event recovered approximately total 5,456 gallons of fluids, including 21 gallons
of free-phase LNAPL, and 129.0 gallons as vapor.

On January 4, 2022, ATC conducted a subsequent groundwater sampling event to evaluate the
effectiveness of the MMPE event. Monitoring wells MW-1 through MW-11,TW-1,and RW-1 were
gauged for liquid levels and total well depths prior to sampling activities using an oil/water interface
probe (IP). LNAPL thickness was measured in wells MW-1 at 0.54feet, MW-5 at 2.01 feet, MW-7
at 2.39 feet. MW-8 at 0.43 feet, MW-10 at 0.37 feet, MW-11 at 0.35 feet, and RW-1 at 0.17 feet.

PCE was detected in well MW-3 in excess of the GCL, along with TCE, in MW-2, MW-3, and TW-
1. Monitoring wells MW-2, MW-6, MW-9, and TW-1 contained multiple petroleum constituents at
concentrations over 2L Standards. Based on these results, ATC recommended a tank and line
tightness testing for the entire system and the installation of three additional shallow monitoring
wells and conducting a MMPE event.
From November 2022 to February 2023 ATC conducted assessment activities which included the
installation of three Type II monitoring wells, a 96-hour MMPE event, a groundwater sampling
event, and water level gauging activities. Monitoring wells MW-12, MW-13, and MW-14 were
installed to evaluate the extents of LNAPL and GCL exceedances in the groundwater.
Prior to the MMPE event, LNAPL was measured in wells MW-1 (3.89 feet) and MW-5 (1.56 feet)
prior to starting the system. Approximately 4980-gallons of fluids were recovered from wells MW-
1, MW-5, and RW-1. At least 102 gallons of free-phase LNAPL was measured in the tanker at
shut down, with approximately 131.71 gallons of VOCs removed as vapor. The MMPE events
appear to be an effective method of LNAPL recovery. During the subsequent groundwater
monitoring event and gauging activities, LNAPL was measured in MW-1 (2.41 feet), in MW-5
(0.51 feet), in MW-8 (0.43 feet), and in RW-1 (0.86 feet). LNAPL thickness in wells MW-1 and
MW-5 has decreased significantly since detected in 2018. However, the presence of LNAPL in
MW-8 indicates the extent of LNAPL has not been fully delineated to the north-northeast of the
source area.
Groundwater samples collected after the MMPE event indicated PCE was detected in well MW-
3 in excess of the GCL, and over the 2L Standard, along with TCE, in MW-2, MW-3, MW-7, and
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TW-1. TCE and PCE are chemicals typically detected in solvent releases. ATC does not have
any evidence of a solvent release on the Circle K Store 2720828 property. Therefore, any TCE
or PCE detected in the groundwater samples collected at the Circle K Store 2720828 are assumed
to not be related to the UST release. Multiple other petroleum constituents were detected at
concentrations exceeding 2L Standards in monitoring wells MW-2, MW-3, MW-6, MW-7, and TW-
1. Petroleum constituents were not detected in well MW-4.

3.0 GEOLOGIC FRAMEWORK

3.1 Site and Regional Geology
According to the 1985 “Geologic Map of North Carolina”, the site lies in the Charlotte Belt of the
Piedmont Physiographic Province of North Carolina, which is composed of foliated to massive
granitic rock characterized by metagabbro, metadiorite, and mafic plutonic-volcanic complexes.
The unit is locally referred to as Metamorphosed Mafic Rock. The shallow subsurface in most areas
of the Piedmont contains residual soil overburden, including structure-free residuum, saprolite, and
partially weathered rock (PWR) that derive from in-place weathering of the crystalline bedrock.
Occasional areas containing recent deposits of alluvium in the uppermost subsurface are found near
streams and rivers. Saprolite and PWR typically contain some relict structures from the original rock
material.

The soils are typically saprolitic and are formed by in-place weathering of bedrock and the
subsequent breakdown of associated minerals. Surficial soils observed at the site by ATC during
drilling activities reportedly consisted of silty clay with sand to depths of approximately 10-feet below
grade. Partially weathered rock with dense silty sand was encountered from depths of approximately
10 to 38-feet below grade. Competent rock was encountered from approximately 38-feet to 60-feet
below grade, with water-producing fractures encountered between approximately 50 to 60-feet below
grade.

3.2 Site and Regional Hydrogeology
The shallow aquifer occurrence varies in depth from ground surface at springs, creeks, and rivers
to as deep as 50-feet or more beneath upland surfaces in some parts of the Piedmont. Water in
the alluvium or unconsolidated residual material, including saprolite and PWR, usually behaves
as an unconfined aquifer, or water table, and will yield water with head elevation equivalent to the
first elevation where water was encountered. Permeability varies with lithology and is typically
relatively low in residual soils, with higher permeability in saprolite or PWR due to relict rock
texture and variable susceptibility to weathering exhibited by different minerals in the rock.
Groundwater flow in residual soils or alluvium is usually in rough concurrence with local
topographic conditions and is toward local drainage features.

Depth to groundwater in site monitoring wells with no history of LNAPL has ranged from
approximately 13 to 26 ft-bgs. Depth to groundwater in the source area has ranged from
approximately 15.50 to 34.5 ft-bgs and is displaced by the presence of LNAPL ranging in
thickness from 0.12 feet to 14.15 feet, not including measurements recorded at the conclusion of
MMPE events.
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The bedrock fractures or other planar features of the Piedmont Physiographic Province generally
constitute the bedrock aquifer, with the surrounding rock material being effectively impermeable.
Along with fractures, contacts between rock bodies probably constitute zones of significant
groundwater occurrence in the bedrock. The surrounding material and overlying residuum tend
to make the bedrock aquifer a semi-confined aquifer. That is, the overlying water and soil weight
normally results in pressure that causes water in a borehole, which intersects a fracture or other
feature, to rise above the elevation of the fracture or feature. Modern water supply wells in the
Piedmont, likely including any which may be in the site vicinity, are typically installed with a surface
casing through the unconsolidated material, and an open borehole into the bedrock where water-
bearing fractures are encountered.

3.3 Hydrogeologic Investigation
During the CSA, three rising-head slug tests were performed in Type II monitoring wells MW-2
and MW-3, and Type III monitoring well TW-1. The hydraulic conductivity in the shallow aquifer
zone was calculated to range from 0.1953 feet/day to 0.7581 feet/day. Based on this data, the
average hydraulic conductivity in the shallow aquifer zone was calculated to be 0.4767 feet/day.
The hydraulic conductivity in the deep aquifer zone was calculated to be 0.254 feet/day.

Seepage velocity was calculated using the approximate horizontal hydraulic gradient between
monitoring wells MW-4 and MW-2 of 0.018 feet/foot and the calculated average shallow hydraulic
conductivity of 0.4767 feet/day. The assumed effective porosity value of 40% for a sandy silt
material with partially weathered rock was obtained from the AQTESOLV website. The calculated
seepage velocity was 7.83 feet/year.
4.0 CORRECTIVE ACTION AND ASSESSMENT

4.1 Monitoring Well, Recovery Well, and Air Sparge Well Installation
On October 9 and 10, 2023, ATC supervised the installation of two recovery wells (RW-2 and
RW-3) one Type III monitoring well (TW2) and two air sparge wells (AS-1 and AS-2). The recovery
and air sparge wells were installed to enhance the effectiveness of MMPE events and MMPE/Air
Sparge events. Telescoping well TW-2 was installed to evaluate the extent of the groundwater
plume at depth. ATC contracted with Environmental Drilling and Probing Services (EDPS), a
North Carolina certified well contractor, to drill the borings and install the monitoring wells.

Air sparge wells AS-1 and AS-2 were installed to depths of 30 and 41 ft-bgs respectively. Each
well was completed with two 28 and 39-foot lengths of a 2-inch diameter schedule-40 polyvinyl
chloride (PVC) riser with 2-feet of 0.010-inch slotted screen and solid riser to near ground surface.
The borehole annulus was filled with #2 sand filter pack to 2 feet above the top of the well screen
(26 and 37 ft-bgs respectively). Bentonite was placed from 24 to 35 ft-bgs, and grout to surface.
The well was completed at the ground surface with a flush-mounted traffic-bearing manhole set
in a concrete pad.

Recovery wells RW-2 and RW-3 were installed to depths of 40 and 35 ft-bgs respectively. Each
well was completed with two 5 and 10-foot lengths of a 2-inch diameter schedule-40 polyvinyl
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chloride (PVC) riser with 30-feet of 0.010-inch slotted screen and solid riser to near ground
surface. The borehole annulus was filled with #2 sand filter pack to 2 feet above the top of the
well screen (4 and 8 ft-bgs respectively). Bentonite was placed from 2 to 6 ft-bgs, and grout to
surface. The well was completed at the ground surface with a flush-mounted traffic-bearing
manhole set in a concrete pad.

The Telescopic well (TW-2) was installed to a depth of 60 ft-bgs respectively. The well was
completed with one 40-foot length of a 6-inch diameter schedule-40 polyvinyl chloride (PVC) riser,
and 60-foot length of a 20-inch diameter schedule-40 polyvinyl chloride (PVC) riser with 10-feet
of 0.010-inch slotted screen and solid riser to near ground surface. The borehole annulus was
filled with #2 sand filter pack to 48 feet above the top of the well screen (48 ft-bgs respectively).
Bentonite was placed from 46 ft-bgs, and grout to surface. The well was completed at the ground
surface with a flush-mounted traffic-bearing manhole set in a concrete pad.

The borings were drilled using air rotary drilling methodology. Well locations are depicted on
Figure 2.

Monitoring wells were installed by a North Carolina certified well contractor. They were installed
per the specifications required in North Carolina Administrative Code, Chapter 15A, Subchapter
2C, part .0108. (15A NCAC 2C .0108). The wells were completed with a 2-foot-by-2-foot concrete
pad, 8-inch diameter well vault, and capped with a lockable water-tight cap.

On October 12, 2023, following the completion of the wells, RW-2, RW-3, TW2, AS-1 and AS-2,
were measured for top-of-casing (TOC) elevation relative to the existing well network. Monitoring
well construction and TOC elevation details are summarized in Table 5 and Table 6. The well
construction records are included in Appendix A.

4.2 Mobile Multi-Phase Extraction Event
On October 30, 2023, Zava Industrial, Inc. (Zava) located in Graham, North Carolina, mobilized
to the site for performance of a 96-hour MMPE event, using monitoring wells MW-5, MW-8, MW-
10, and recovery wells RW-1 and RW-2 as target extraction wells. Air sparge well AS-1 was used
to introduce air into the formation. ATC was on site to record liquid level data from the extraction
wells and supervise system set up and initiation. Prior to starting the MMPE event, LNAPL was
measured in monitoring wells MW-5, MW-8, MW-10, and recovery wells RW-1 and RW-2 ranging
in thickness from 0.00 feet in MW-5 to 4.93 feet in MW-8. ATC personnel returned to the site on
November 3, 2023, to supervise the MMPE shut down activities and record liquid level
measurements from the extraction wells. After the MMPE event was completed, LNAPL was not
measured in the extraction wells A summary of current and historical groundwater elevation data
is included in Table 6.

The MMPE system actively recovered free-phase LNAPL, contaminated groundwater, and soil
vapors from monitoring wells MW-5, MW-8, MW-10, and recovery wells RW-1 and RW-2, for
approximately 96 hours. System monitoring was provided by Zava personnel. Over the course of
the 96-hour event, approximately 5,468 gallons of fluids were recovered from wells MW-5, MW-
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8, MW-10, and recovery wells RW-1 and RW- including approximately 30 gallons of free-phase
LNAPL, as measured in the tanker. Note that actual LNAPL recovered during the MMPE event is
likely greater than 30 gallons, as the product and water had not fully separated when the initial
measurements were made. Based on the emissions calculations provided by Zava, 285.40
pounds (52.95 equivalent gallons) of petroleum hydrocarbons were recovered as vapor. A copy
of the MMPE report provided by Zava, including the disposal manifest, is included in Appendix
B.

On November 6, 2023, Zava Industrial, Inc. (Zava) located in Graham, North Carolina, mobilized
to the site for performance of a 96-hour MMPE event, using monitoring wells MW-1, MW-5, MW-
9, MW-10, and recovery wells RW-1 and RW-3 as target extraction wells. ATC was on site to
record liquid level data from the extraction wells and supervise system set up and initiation. Prior
to starting the MMPE event, LNAPL was measured in wells MW-1 (1.20 feet), MW-5, MW-7, MW-
9, MW-11, and RW-1 ranging in thickness from 0.03 feet in MW-11 to 1.20 feet in MW-1. ATC
personnel returned to the site on November 10, 2023, to supervise the MMPE shut down activities
and record liquid level measurements from the extraction wells. After the MMPE event was
completed, LNAPL was measured in well MW-1, MW-5, and MW-9 at thicknesses of 0.02 feet,
0.05 feet, and 0.38 feet, respectively, and was not measured in wells MW-10, RW-1, or RW-3. A
summary of current and historical groundwater elevation data is included in Table 6.

The MMPE system actively recovered free-phase LNAPL, contaminated groundwater, and soil
vapors from monitoring wells MW-1, MW-5, MW-9, MW-10, and recovery wells RW-1 and RW-3,
for approximately 96 hours. System monitoring was provided by Zava personnel. Over the course
of the 96-hour event, approximately 6,268 gallons of fluids were recovered from wells MW-5, MW-
8, MW-10, and recovery wells RW-1 and RW- including approximately 11 gallons of free-phase
LNAPL, as measured in the tanker. Note that actual LNAPL recovered during the MMPE event is
likely greater than 11 gallons, as the product and water had not fully separated when the initial
measurements were made. Based on the emissions calculations provided by Zava, 243.49
pounds (45.17 equivalent gallons) of petroleum hydrocarbons were recovered as vapor. A copy
of the MMPE report provided by Zava, including the disposal manifest, is included in Appendix
B.

A summary of LNAPL recovery efforts at the site to date is provided in Table 8. Subsequent liquid
level gauging indicates LNAPL remains present at the locations of MW-1, MW-5, and MW-9.

4.3 Liquid Level Measurements
On December 7, 2023, ATC conducted a groundwater sampling event to evaluate the
effectiveness of the MMPE event. Monitoring wells MW-1 through MW-14, TW-1, TW-2 and RW-
1 through RW-3 and AS-1 and AS-2 were gauged for liquid levels and total well depths prior to
sampling activities using an oil/water interface probe (IP) or water level indicator. LNAPL
thickness was measured in wells MW-1 (0.20 feet), MW-5 (0.03 feet), MW-7 (0.58 feet), MW-8
(0.40 feet), MW-9 (0.60 feet), MW-10 (0.49 feet), MW-11 (3.00 feet), MW-13 (0.01 feet), RW-1
(0.47 feet) RW-2 (0.02 feet) and RW-3 (0.69 feet). Monitoring well construction information is
included in Table 5. Current and historical liquid level information is summarized in Table 6.

Corrective Action Performance Report
Circle K 2720828
Page 14

The horizontal hydraulic gradient was calculated to be 0.121 feet/foot between monitoring wells
MW-12 and MW-11. The horizontal hydraulic gradient was calculated to be 0.036 feet/foot
between monitoring wells MW-14 and MW-13. The horizontal hydraulic gradient was calculated
to be 0.096 feet/foot between monitoring wells MW-12 and MW-13.

The vertical hydraulic gradient between Type II monitoring well MW-1 and Type III monitoring well
TW-1 was calculated to be approximately 0.01173 feet/foot in the upward direction. A
groundwater elevation map depicting groundwater flow to the north-northeast is included as
Figure 3. The distribution of LNAPL at the site, based on the December 7, 2023, measurements
is depicted on Figure 5.

4.3 Groundwater Sampling Results
On December 7, 2023, ATC conducted a monitoring well sampling event on wells MW-2, MW-3,
MW-4, MW-6, MW-12, MW-14, TW-1, TW-2, AS-1 and AS-2. Monitoring wells MW-1, MW-5, MW-
7, MW-8, MW-9, MW-10, MW-11, MW-13, RW-1, RW-2, and RW-3 were not sampled on
December 7, 2023, due to the presence of measurable LNAPL. The wells were purged prior to
sample collection using new, disposable PVC bailers or a decontaminated submersible pump and
new tubing, while wearing new, disposable nitrile gloves. Purging was accomplished by removing
approximately three well volumes or until the well was purged dry and allowed to recharge. Upon
sample collection, water quality parameters were measured and recorded in the field notes.

Groundwater samples were placed into laboratory provided containers, sealed and labeled,
placed into an ice-filled cooler and submitted under chain of custody protocol to Pace for analysis
by Standard Method 6200B for VOCs and oxygenates.

Groundwater analytical results were compared to GCLs and 2L Standards. Results from the
sampling events indicated the following:
 LNAPL thickness was measured in wells MW-1 (0.20 feet), MW-5 (0.03 feet), MW-7 (0.58
feet), MW-8 (0.40 feet), MW-9 (0.60 feet), MW-10 (0.49 feet), MW-11 (3.00 feet), MW-13
(0.01 feet) RW-1 (0.47 feet), RW-2 (0.02 feet), and RW-3 (0.69 feet).
 Dry-cleaning solvent tetrachlorethylene (PCE) was detected above the North Carolina 2L
Groundwater Quality Standards as defined in Title 15A, NCAC, Subchapter 2L, Part .0202
(2L Standard) in eight monitoring wells (AS-2, MW-2, MW-3, MW-6, MW-12, MW-14, TW-
1, and TW-2), and PCE was detected with levels above the North Carolina Gross
Contamination Standards in MW-3. Trichloroethylene (TCE) was detected above the 2L
Standards in seven wells (AS-2, MW-2, MW-3, MW-12, MW-14, TW-1, and TW-2).
 Monitoring wells AS-1, AS-2, MW-2, MW-3, MW-6, MW-12, MW-14, TW-1, and TW-2
contained multiple petroleum constituents at concentrations over 2L Standards,
specifically benzene, ethylbenzene, xylenes, MTBE, naphthalene, isopropyl benzene, and
1,2,4-trimethylbenzene.
 Oxygenates were detected in multiple monitoring wells but were not over the 2L
Standards.
 Well MW-4 did not contain VOCs above the laboratory method detection level.

Corrective Action Performance Report
Circle K 2720828
Page 15

A summary of current and historical groundwater analytical data is provided in Table 7. A benzene
isoconcentration contour map is included as Figure 4, a map depicting LNAPL thickness is
included as Figure 5, and a map depicting petroleum constituents detected above the 2L
Standard is included as Figure 6. The laboratory analytical report is included as Appendix D.
5.0 CONCLUSIONS AND RECOMMENDATIONS
From October to November 2023 ATC conducted assessment activities for the Circle K Store
2720828, located at 10329 Park Road, in Charlotte, Mecklenburg County, North Carolina.
Assessment activities included the installation of four Type II monitoring wells and one Type III
well, two 96-hour MMPE events, a groundwater sampling event, and water level gauging
activities.
Prior to the MMPE event, LNAPL was measured in wells MW-8 (4.93 feet), MW-10 (0.49 feet),
and RW-2 (0.02 feet) prior to starting the system. Approximately 5,468-gallons of fluids were
recovered from wells MW-1, MW-5, and RW-1. At least 30 gallons of free-phase LNAPL was
measured in the tanker at shut down, with approximately 52.95 gallons of VOCs removed as
vapor for the first MMPE event. After the second MMPE event, LNAPL was measured in wells
MW-1 MW-5, MW-7, MW-9, MW-11, and RW-1 ranging in thickness from 0.03 feet to 1.20 feet
prior to starting the system. At least 11 gallons of free-phase LNAPL was measured in the tanker
at shut down, with approximately 45.17 gallons of VOCs removed as vapor for the first MMPE
event. The MMPE events appear to be an effective method of LNAPL recovery.
During the subsequent groundwater monitoring event and gauging activities, LNAPL thickness
was measured in wells MW-1 (0.20 feet), MW-5 (0.03 feet), MW-7 (0.58 feet), MW-8 (0.40 feet),
MW-9 (0.60 feet), MW-10 (0.49 feet), MW-11 (3.00 feet), MW-13 (0.01 feet), RW-1 (0.47 feet)
RW-2 (0.02 feet) and RW-3 (0.69 feet). LNAPL thickness in wells MW-1 and MW-5 has decreased
significantly since detected in 2018. However, the presence of LNAPL in MW-13 indicates the
extent of LNAPL has not been fully delineated to the south-southeast of the source area.
Groundwater samples collected after the MMPE event indicated PCE was detected in well MW-
3 in excess of the GCL, and over the 2L Standard in wells AS-1, AS-2, MW-2, MW-6, MW-12,
MW-14, TW-1, and TW-2, along with TCE, in AS-2, MW-2, MW-3, MW-12, MW-14, TW-1, and
TW-2. TCE and PCE are chemicals typically detected in solvent releases. ATC does not have
any evidence of a solvent release on the Circle K Store 2720828 property. Therefore, any TCE
or PCE detected in the groundwater samples collected at the Circle K Store 2720828 are assumed
to not be related to the UST release.
Multiple other petroleum constituents were detected at concentrations exceeding 2L Standards in
monitoring wells AS-1, AS-2, MW-2, MW-3, MW-6, MW-12, MW-14, TW-1, and TW-2. Petroleum
constituents were not detected in well MW-4.

Dissolved-phase petroleum contamination in groundwater has not been horizontally delineated,
with the exception of the western portion of the site as indicated by the analytical results of MW-
4.

Corrective Action Performance Report
Circle K 2720828
Page 16

Based on the findings of the current and previous site activities, ATC recommends the following:

 Conduct an MMPE/AS event, the first utilizing MW-1, MW-8, MW-9, MW-11, and
RW-3 as target extraction wells.

 Complete a comprehensive groundwater monitoring event approximately 30 days
after the MMPE/AS events and report findings in a Corrective Action Performance
Report.

6.0 LIMITATIONS
This report has been prepared for the exclusive use of Circle K Stores Inc. for specific application
to the referenced site in Charlotte, North Carolina. The assessment was conducted based on the
scope-of-work and level of effort requested by the NCDEQ and with resources adequate only for
that scope-of-work. Our findings have been developed in accordance with generally accepted
standards of geology and hydrogeology practices in the State of North Carolina, available
information, and our professional judgment. No other warranty is expressed or implied.

The data that are presented in this report are indicative of conditions that existed at the precise
locations sampled and at the time the samples were collected. Additionally, the data obtained
from samples would be interpreted as being meaningful with respect to parameters indicated in
the laboratory report. No additional information can logically be inferred from these data.
Conclusions and recommendations set forth herein are applicable only to the facts and conditions
described at the time of this report.
7.0 REFERENCES
“Guidelines for Assessment and Corrective Action for UST Releases” completed by the UST
Section of the NCDEQ, Division of Waste Management dated December 1, 2008, with
subsequent revisions.

North Carolina Administrative Code, Title 15A, Chapter 2L.

“Guidelines for Sampling” completed by the UST Section of the NCDEQ, Division of Waste
Management dated July 15, 2008, with subsequent revisions.

TABLES
TABLE 1
UST SYSTEM AND RELEASE INFORMATION
CIRCLE K STORE NO. 2720828
10329 Park Road, Charlotte, NC
NCDEQ Incident #40819
Capacity Release Associated
(gallons)w/ UST System
1 Premium Gasoline 10,000 1/1/1989 Currently in Use No
2 Regular Gasoline 10,000 1/1/1989 Currently in Use No
3 Diesel 10,000 1/1/1989 Currently in Use Yes
TABLE 2
UST OWNER/OPERATOR INFORMATION
1, 2, 3 33712
State Zip
NC 27606
State Zip
NC 27606
UST ID
Number Contents Date Tank Installed Status of UST
Telephone Number
Dates of Operation
1100 Situs Ct, Suite 100
Raleigh
Dates of Operation
(mm/dd/yy to mm/dd/yy)
City Telephone Number
Raleigh [phone]
Circle K Stores, Inc.01/01/89 to present
1101 Situs Ct
Street Address
[phone]
Name of Operator
Facility ID Number
Name of Owner
Circle K Stores, Inc.01/01/89 to present
UST ID Number
(mm/dd/yy to mm/dd/yy)
Street Address
City
TABLE 3
ADJOINING PROPERTY OWNERS
CIRCLE K STORE NO. 2720828
10329 Park Road, Charlotte, NC
NCDEQ Incident #40819
Tax Parcel
Identification
Number (PIN)
Owner Name Owner Address Property Address
20729151 TKC Park Crossings
4500 Carmeron Valley
Parkway, Suite 400,
Charlotte, NC 28211
10340 Park Road
20728111 Kimberly A. Brueckner 10329 John's Towne Drive,
Charlotte, NC 28210
10329 John's Towne
Drive
22119402 Davis Investments, LLC 2401 South College Drive,
High Point, NC 27260
9915 Park Cedar
Drive
22119219 BVB Properties / 1415
Watermark LLC
204-C West Woodlawn
Road, Charlotte, NC 28217 10405 Park Road
TABLE 4
WATER SUPPLY WELLS AND OTHER RECEPTOR INFORMATION
CIRCLE K STORE NO. 2720828
10329 Park Road, Charlotte, NC
NCDEQ Incident #40819
Well Well Owners / Well Users Property Address Owner Address Well Use
(P/I/N)
Distance
From
Source
Area (feet)
Municipal
Water
Connection
(Y/N)
Notes:
P / I / N = Potable water supply / Irrigation / Not in use
Other Receptors (Surface Water)
Receptor ID Description Location Usage Up or Down
Gradient
1 Unnamed tributary -
McMullen Creek East of site NA Down
Gradient
2 Unnamed tributary - Little
Sugar Creek Northwest of site NA Up Gradient
NONE IDENTIFIED
Distance from
Source Area of
Release (ft)
1,000
1,300

TABLE 5
MONITORING WELL CONSTRUCTION INFORMATION
CIRCLE K STORE NO. 2720828
10329 Park Road, Charlote, NC
NCDEQ Incident #40819
Well ID Date
Installed
Well
Diameter (in)
Casing
Depth
(ft, BGS)
Screened
Interval (ft)
Depth of Well
(ft, BGS)
Top of
Casing
Elevation (ft)
Well Status
MW-1 07/16/18 2 20 20 - 35 35 100.00 Active
MW-2 11/19/18 2 20 20 - 35 35 101.23 Active
MW-3 11/19/18 2 19 19 - 34 34 99.12 Active
MW-4 11/19/18 2 17 17 - 32 32 98.68 Active
MW-5 11/20/18 2 18 18 - 33 33 99.34 Active
MW-6 03/04/21 2 18 17 - 32 32 96.96 Active
MW-7 03/04/21 2 30 15 - 30 30 99.72 Active
MW-8 03/04/21 2 30 15 - 30 30 100.80 Active
MW-9 11/12/21 2 15 15 - 30 30 99.68 Active
MW-10 11/12/21 2 20 20 - 35 35 102.92 Active
MW-11 11/12/21 2 15 15 - 30 30 100.52 Active
MW-12 11/04/22 2 15 15-30 30 102.79 Active
MW-13 11/03/22 2 15 15-30 30 100.03 Active
MW-14 11/03/22 2 15 15-30 30 99.59 Active
RW-1 01/24/19 4 40 10 - 40 40 100.36 Active
RW-2 10/09/23 4 10 10- 40 40 100.72 Active
RW-3 10/09/23 4 5 5-35 35 100.49 Active
TW-1 11/21/18 2 40 / 50 50 - 60 60 100.28 Active
TW-2 10/10/23 2 50 50-60 60 101.85 Active
AS-1 10/09/23 2 28 28-30 30 100.12 Active
As-2 10/09/23 2 28 28-30 30 102.64 Active
Notes:
Top of casing elevations relative to benchmark assigned an arbitrary elevation of 100.00-feet (MW-1)
MW = Type II monitoring well
TW = Type III (telescoping) monitoring well
Well ID
Date
Liquid Level
Measured
Screen
Interval
(ft)
Top of
Casing
Elevation (ft)
Depth
to Product
(ft, BGS)
Depth
to Water
(ft, BGS)
Free Product
Thickness
(ft)
Water
Table
Elevation (ft)
Notes
07/17/18 21.65 28.10 6.45 76.74
12/03/18 20.03 30.72 10.69 77.30
01/31/19 16.06 30.21 14.15 80.40
11/18/19 20.05 31.15 11.10 77.18
11/22/19 23.56 24.02 0.46 76.33
12/12/19 21.25 22.69 1.44 78.39
09/14/20 18.62 23.22 4.60 80.23
09/18/20 20.74 21.76 1.02 79.01
10/22/20 19.69 20.63 0.94 80.08
03/15/21 15.82 19.71 3.89 83.21
03/19/21 18.64 18.71 0.07 81.34
4/6/2021 16.10 18.51 2.41 83.30
6/11/2021 18.29 20.00 1.71 81.28
11/11/2021 22.16 24.1 1.94 77.36
12/6/2021 21.81 24.17 2.36 77.60
12/10/2021 --24.41 --75.59
1/4/2022 22.90 23.44 0.54 76.97
12/5/2022 --25.54 2.94 76.67
12/9/2022 22.60 27.33 --72.67
2/13/2023 19.48 19.66 0.18 80.48
11/6/2023 22.70 23.9 1.20 77.00
11/10/2023 26.47 26.49 0.02 73.53
12/7/2023 23.10 23.3 0.20 76.85
12/03/18 --23.20 --78.03
01/31/19 --19.81 --81.42
12/12/19 --22.92 --78.31
10/22/20 --21.27 --79.96
4/6/2021 --18.09 --83.14
11/11/2021 --24.15 --77.08
1/4/2022 --24.78 --76.45
2/13/2023 --21.20 --80.03
12/7/2023 --24.88 --76.35
12/03/18 --20.05 --79.07
01/31/19 --16.57 --82.55
12/12/19 --19.69 --79.43
10/22/20 --17.57 --81.55
4/6/2021 --14.53 --84.59
1/4/2022 --21.22 --77.90
2/13/2023 --17.82 --81.30
12/7/2023 --23.34 --75.78
12/03/18 --18.45 --80.23
01/31/19 --14.80 --83.88
12/12/19 --17.78 --80.90
10/22/20 --15.68 --83.00
4/6/2021 --12.70 --85.98
1/4/2022 --19.54 --79.14
2/13/2023 --16.18 --82.50
12/7/2023 --19.89 --78.79
MMPE 11/18 -
11/22 2019
MMPE 9/14-
9/18 2020
MMPE 3/15-
3/19 2020
MMPE 12/6/21-
12/10/21
MMPE 12/5-
12/9 2022
MMPE 11/6 -
11/10 2023
99.12MW-3
TABLE 6
GROUNDWATER ELEVATION DATA
CIRCLE K STORE NO. 2720828
10326 Park Road, Charlotte, NC
NCDEQ Incident #40819
19 - 34
20 - 35 100.00MW-1
MW-2 20 - 35 101.23
MW-4 17 - 32 98.68
Page 1 of 4
Well ID
Date
Liquid Level
Measured
Screen
Interval
(ft)
Top of
Casing
Elevation (ft)
Depth
to Product
(ft, BGS)
Depth
to Water
(ft, BGS)
Free Product
Thickness
(ft)
Water
Table
Elevation (ft)
Notes
TABLE 6
GROUNDWATER ELEVATION DATA
CIRCLE K STORE NO. 2720828
10326 Park Road, Charlotte, NC
NCDEQ Incident #40819
12/03/18 19.72 28.56 8.84 77.41
01/31/19 15.96 27.11 11.15 80.59
11/18/19 19.97 26.65 6.68 77.70
11/22/19 24.02 24.08 0.06 75.31
12/12/19 20.58 21.11 0.53 78.63
09/14/20 --17.78 --81.56
09/18/20 20.56 20.70 0.14 78.75
10/22/20 18.81 19.18 0.37 80.44
03/15/21 15.62 17.18 1.56 83.33
03/19/21 18.63 18.64 0.01 80.71
4/6/2021 15.65 15.66 0.01 83.69
6/11/2021 17.74 18.25 0.51 81.47
11/11/2021 21.85 22.50 0.65 77.33
12/6/2021 22.89 23.39 0.50 76.33
12/10/2021 23.01 23.61 0.60 76.18
1/4/2022 22.18 24.19 2.01 76.66
12/5/2022 22.11 25.47 3.36 76.39
12/9/2022 --29.77 --69.57
2/13/2023 18.88 19.09 0.21 80.41
10/30/2023 --21.69 --77.65
11/3/2023 --28.32 --71.02
11/6/2023 22.30 22.98 0.68 76.87
11/10/2023 26.40 26.55 0.15 72.90
12/7/2023 22.56 22.59 0.03 76.77
01/31/19 --15.69 --81.27
12/12/19 --18.74 --78.22
10/22/20 --16.97 --79.99
4/6/2021 --13.92 --83.04
1/4/2022 --20.35 --76.61
2/13/2023 --16.85 --80.11
12/7/2023 --20.47 --76.49
4/6/2021 --15.69 --84.03
1/4/2022 21.94 24.33 2.39 77.18
12/5/2022 22.06 24.49 2.43 77.05
12/9/2022 --29.31 --70.41
2/13/2023 18.90 19.13 0.23 80.76
11/6/2023 22.10 22.65 0.55 77.48
12/7/2023 22.37 22.95 0.58 77.21
3/15/2021 --17.24 --83.56
3/19/2021 --20.66 --80.14
4/6/2021 17.14 17.15 0.01 83.66
6/11/2021 19.26 19.69 0.43 81.43
11/11/2021 22.61 26.93 4.32 77.11
12/6/2021 27.11 29.71 2.60 73.04
12/10/2021 --24.74 --76.06
1/4/2022 23.85 24.28 0.43 76.84
12/5/2022 23.26 27.59 4.33 76.46
12/9/2022 --29.71 --71.09
2/13/2023 20.30 20.75 0.45 80.39
10/30/2023 22.35 27.28 4.93 77.22
11/3/2023 --29.71 --71.09
11/6/2023 --23.79 --77.01
12/7/2023 23.96 24.36 0.40 76.44
MMPE 3/15-
3/19 2020
MMPE 11/6 -
11/10 2023
MMPE 12/5/22-
12/9/22
MMPE 12/6/21-
12/10/21
99.72
MMPE 12/5/22-
12/9/22
MMPE 12/6/21-
12/10/21
MMPE 12/5/22-
12/9/22
MMPE 10/30-
11/3 2023
96.96
99.34
MW-6
MW-7 15 - 30
MW-5 18 - 33
17 - 32
MW-8 15 - 30 100.80
MMPE 9/14-
9/18 2020
MMPE 3/15-
3/19 2020
MMPE 10/30-
11/3 2023
Page 2 of 4
Well ID
Date
Liquid Level
Measured
Screen
Interval
(ft)
Top of
Casing
Elevation (ft)
Depth
to Product
(ft, BGS)
Depth
to Water
(ft, BGS)
Free Product
Thickness
(ft)
Water
Table
Elevation (ft)
Notes
TABLE 6
GROUNDWATER ELEVATION DATA
CIRCLE K STORE NO. 2720828
10326 Park Road, Charlotte, NC
NCDEQ Incident #40819
12/6/2021 22.95 23.08 0.13 76.70
12/10/2021 --24.03 --75.65
1/4/2022 --22.87 --76.81
2/13/2023 19.00 21.02 2.02 80.18
11/3/2023 --29.96 --69.72
11/6/2023 22.80 23.11 0.31 76.80
11/10/2023 26.12 26.50 0.38 73.47
12/7/2023 22.91 23.51 0.60 76.62
12/6/2021 26.29 27.13 0.84 76.42
12/10/2021 --28.93 --73.99
1/4/2022 26.19 26.56 0.37 76.64
12/5/2022 26.14 26.71 0.57 76.64
12/9/2022 --30.71 --72.21
2/13/2023 22.51 22.90 0.39 80.31
10/30/2023 25.26 26.00 0.74 77.48
11/3/2023 --34.62 --68.30
11/6/2023 --26.01 --76.91
11/10/2023 --28.62 --74.30
12/7/2023 26.21 26.70 0.49 76.78
12/6/2021 19.88 26.58 6.70 78.97
12/10/2021 --25.93 --74.59
1/4/2022 23.51 23.86 0.35 76.92
12/5/2022 22.85 27.34 4.49 76.55
12/9/2022 29.59 29.61 0.02 70.93
2/13/2023 19.89 20.70 0.81 80.43
11/6/2023 22.85 22.88 0.03 77.66
12/7/2023 23.14 26.14 3.00 76.63
2/13/2023 --23.35 --79.44
12/7/2023 --20.71 --82.08
2/13/2023 --21.25 --78.78
12/7/2023 24.62 24.63 0.01 75.41
2/13/2023 --19.11 --80.48
12/7/2023 --22.59 --77.00
12/03/18 --22.00 --78.28
01/31/19 --18.63 --81.65
12/12/19 --21.58 --78.70
10/22/20 --19.91 --80.37
03/15/21 --16.75 --83.53
03/19/21 --19.11 --81.17
4/6/2021 --16.60 --83.68
12/6/2021 23.00 23.12 0.12 77.25
1/4/2022 --23.39 --76.89
2/13/2023 --20.01 --80.27
12/7/2023 --23.28 --77.00
10/12/2023 --25.45 --74.83
12/7/2023 --26.82 --75.03
3/15/2021 --16.76 --83.52
3/19/2021 --19.24 --81.04
4/6/2021 16.60 16.61 0.01 83.68
06/11/21 18.70 19.56 0.86 81.37
11/11/2021 22.63 24.32 1.69 77.23
12/6/2021 24.86 25.70 0.84 75.21
12/10/2021 --24.69 --75.59
1/4/2022 23.38 23.55 0.17 76.86
12/5/2022 27.64 28.70 1.06 72.38
12/9/2022 33.53 33.55 0.02 66.75
2/13/2023 19.47 21.00 1.53 80.43
10/30/2023 --22.03 --78.25
11/3/2023 --30.31 --69.97
11/6/2023 23.20 23.76 0.56 76.94
11/10/2023 --27.21 --73.07
12/7/2023 23.45 23.92 0.47 76.36
MMPE 11/6 -
11/10 2023
MMPE 10/30-
11/3 2023
MMPE 12/5/22-
12/9/22
MMPE 12/6/21-
12/10/21
MMPE 3/15/21-
3/19/21
MMPE 12/6/21-
12/10/21
MMPE 12/6/21-
12/10/21
MMPE 3/15/21-
3/19/21
MMPE 12/5/22-
12/9/22
MMPE 12/6/21-
12/10/21
MW-10 20 - 35 102.92
MW-11
100.03
MMPE 11/6 -
11/10 2023
15 - 30 100.52
MMPE 10/30-
11/3 2023
MMPE 11/6 -
11/10 2023
TW-1 50 - 60 100.28
MW-12 15 - 30 102.79
MW-13 15 - 30
MW-14 15 - 30 99.59
TW-2 50-60 101.85
MMPE 12/5/22-
12/9/22
MW-9 15 - 30 99.68
RW-1 10 - 40 100.28
Page 3 of 4
Well ID
Date
Liquid Level
Measured
Screen
Interval
(ft)
Top of
Casing
Elevation (ft)
Depth
to Product
(ft, BGS)
Depth
to Water
(ft, BGS)
Free Product
Thickness
(ft)
Water
Table
Elevation (ft)
Notes
TABLE 6
GROUNDWATER ELEVATION DATA
CIRCLE K STORE NO. 2720828
10326 Park Road, Charlotte, NC
NCDEQ Incident #40819
10/12/2023 --22.73 --
10/30/2023 23.15 23.52 0.37 77.04
11/3/2023 --27.65 --73.07
11/6/2023 --23.85 --76.87
12/7/2023 24.04 24.06 0.02 76.66
10/12/2023 --22.20 --75.76
11/6/2023 23.18 24.73 1.55 76.71
11/10/2023 --27.21 --73.28
12/7/2023 23.54 24.23 0.69 76.26
10/12/2023 --23.24 --76.88
12/7/2023 --24.70 --75.42
10/12/2023 --24.68 --77.96
12/7/2023 --26.03 --76.61
Notes:
Water table elevation adjusted for the presence of LNAPL using an assumed density of 0.75.
MMPE 11/6 -
11/10 2023
MMPE 10/30-
11/3 2023
AS-1 28-30 100.12
10-40 100.72
AS-2 39-41 102.64 MMPE 10/30 -
11/3 2023
100.49RW-3 5-35
RW-2
Page 4 of 4
TABLE 7
HISTORICAL GROUNDWATER ANALYTICAL RESULTS
CIRCLE K STORE NO. 2720828
10329 Park Road, Charlotte, NC
NCDEQ Incident #40819
SM 6200B Oxygenates
Well ID Sample
Date
Be
n
z
e
n
e
To
l
u
e
n
e
Et
h
y
l
b
e
n
z
e
n
e
To
t
a
l

X
y
l
e
n
e
s
Me
t
h
y
l

T
e
r
t

B
u
t
y
l

E
t
h
e
r
Na
p
h
t
h
a
l
e
n
e
2-
B
u
t
a
n
o
n
e

(
M
E
K
)
n-
B
u
t
y
l
b
e
n
z
e
n
e
se
c
-
B
u
t
y
l
b
e
n
z
e
n
e
Ch
l
o
r
o
f
o
r
m
o-
C
h
l
o
r
o
t
o
l
u
e
n
e
1,
1
-
D
i
c
h
l
o
r
o
e
t
h
y
l
e
n
e
ci
s
-
1
,
2
-

D
i
c
h
l
o
r
o
e
t
h
y
l
e
n
e
tr
a
n
s
-
1
,
2

Di
c
h
l
o
r
o
e
t
h
y
l
e
n
e
Di
-
I
s
o
p
r
o
p
y
l

E
t
h
e
r
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e
p-
I
s
o
p
r
o
p
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Me
t
h
y
l

C
h
l
o
r
i
d
e
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
n-
P
r
o
p
y
l
b
e
n
z
e
n
e
St
y
r
e
n
e
Te
t
r
a
c
h
l
o
r
o
e
t
h
y
l
e
n
e

(P
C
E
)
Tr
i
c
h
l
o
r
o
e
t
h
y
l
e
n
e

(T
C
E
)
1,
2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
1,
3
,
5
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
Vi
n
y
l

c
h
l
o
r
i
d
e
te
r
t
-
A
m
y
l

a
l
c
o
h
o
l
(T
A
A
)
te
r
t
-
A
m
y
l

m
e
t
h
y
l

e
t
h
e
r
(T
A
M
E
)
te
r
t
-
B
u
t
y
l

a
l
c
o
h
o
l
(T
B
A
)
1 600 600 500 20 6 4,000 70 70 70 70 350 70 100 70 70 25 3 5 70 70 0.7 3 400 400 0.03 40 128 10
5,000 260,000 80,000 50,000 20,000 6,000 4 x 106 5,900 8,800 70,000 70,000 350,000 70,000 100,000 70,000 30,500 11,700 3,000 5,000 26,100 70,000 700 3,000 28,500 24,100 30 40,000 ######10,000
7/17/2018
12/3/2018
12/12/2019
10/22/2020
3/17/2021 742 456 446 1,766 38.3 76.3 ----------------78.5 --------------------------
4/6/2021
6/11/2021
1/4/2022
2/13/2023
12/7/2023
12/3/2018 498 139 10.6 555 103 14.8 13.3 J <5.0 1.6 J --5.0 --2.6 J <5.0 190 12.0 2.1 J 16.1 --3.5 --366 14.6 84.4 41.1 --------
12/12/2019 1,100 80 228 78 226 28.3 <31 4.9 J 8.1 J 6.1 J <3.1 --<3.1 <3.1 324 86.5 <3.1 <5.0 36.0 J 31.7 --39.9 37.4 53.1 22.6 --839 40.3 <50
10/22/2020 1,550 96.6 242 159 170 38.3 <44.9 <4.4 <3.1 <4.4 <2.6 --24.9 <3.2 320 78.9 ----<18.8 <3.0 --16 9.6 78 <2.8 --1,200J <37.0 <220
4/6/2021 2,980 148 513 442 170 67.4 <99 14.8 <10 12.4J <8.0 --50.6 <9.9 315 104 <10.4 --<48.8 <8.5 --<7.3 <9.6 241 <8.3 --1,380J <66.5 <670
1/4/2022 847 38.1 193 155 162 30.1 <19.8 8.5 <2.0 <1.8 <1.6 --70.3 <2.0 289 61.8 <2.1 --<9.8 27.8 --2.8 13.9 110 <1.7 <1.9 972 48.1J <134
2/13/2023 216 1.3 44.7 6.9 134 13.2 <1.3 5.5 7.7 <0.13 <0.13 <0.13 161 3.2 257 32.9 1.4 <0.20 <1.0 15.9 <0.13 45.8 36.8 32.1 8.6 <0.13 759 37.7 <2.0
12/7/2023 203 1.9 27.3 5.9 138 8.7 --<0.13 5.3 <0.14 --<0.16 50.7 1.0 303 17.2 ----<3.8 6.0 <0.27 3.5 15.5 8.9 2.3 <0.30 1,300 41.8 79.6J
12/3/2018 8.4 J <25 <25 <75 <25 <25 <130 <25 <25 --<25 --<25 <25 <25 <25 <25 <25 --<25 --1,590 8.2 J <25 <25 --------
12/12/2019 6.6 J <6.3 <6.3 <13 <6.3 <6.3 <63 <6.3 <6.3 <6.3 <6.3 --<6.3 <6.3 <6.3 <6.3 <6.3 <10 72.1 J <6.3 --1,160 9.5 J <6.3 <6.3 --<100 <10 <100
10/22/2020 <2.4 <2.3 <2.4 24.9 <4.4 30.2 <35.9 <3.5 <2.5 3.6J <2.1 --2.2J <2.6 <3.3 4.5J ----<15.0 4.9J --911 5.5 41.6 10.2 --<405 <29.6 <176
4/6/2021 <1.7 <2.4 <1.5 <1.7 <2.1 <3.2 <19.8 <2.4 <2.0 <1.8 <1.6 --2.4J <2.0 <1.5 <1.7 <2.1 --<9.8 <1.7 --913 5.2 <3.2 < 1.7 --<182 <13.3 <134
1/4/2022 <1.7 <2.4 <1.5 <1.7 <2.1 <3.2 <19.8 <2.4 <2.0 <1.8 <1.6 --2.7 <2.0 <1.5 <1.7 <2.1 --<9.8 <1.7 --805 4.6 <2.5 <1.7 <1.9 <182 <13.3 <134
2/13/2023 <6.3 <6.3 <6.3 <13.0 <6.3 <6.3 <63.0 <6.3 <6.3 <6.3 <6.3 <6.3 7.6 J <6.3 <6.3 <6.3 <6.3 <10.0 <50 <6.3 <6.3 1,390 10.4 J <6.3 <6.3 <6.3 <100 <10.0 <100
12/7/2023 3.5J <0.90 <0.81 <1.4 <0.53 5.0J --<0.66 <0.85 <0.69 --<0.79 9.9 <1.0 <0.72 <1.1 ----<18.9 <1.0 <1.4 910 8.2 <0.31 <0.71 <1.5 <74.4 <1.2 <40.9
MW-2
Not Sampled - LNAPL Thickness 0.18'
Not Sampled - LNAPL Thickness 10.69'
Not Sampled - LNAPL Thickness 1.46'
Not Sampled - LNAPL Thickness 0.94'
Not Sampled - LNAPL Thickness 2.41'
Not Sampled - LNAPL Thickness 0.54'
Not Sampled - LNAPL Thickness 0.20'
MW-1
GCL
Analytical Method
Not Sampled - LNAPL Thickness 1.71'
2L Standard
Not Sampled - LNAPL Thickness 6.45'
MW-3
Page 1 of 4
TABLE 7
HISTORICAL GROUNDWATER ANALYTICAL RESULTS
CIRCLE K STORE NO. 2720828
10329 Park Road, Charlotte, NC
NCDEQ Incident #40819
SM 6200B Oxygenates
Well ID Sample
Date
Be
n
z
e
n
e
To
l
u
e
n
e
Et
h
y
l
b
e
n
z
e
n
e
To
t
a
l

X
y
l
e
n
e
s
Me
t
h
y
l

T
e
r
t

B
u
t
y
l

E
t
h
e
r
Na
p
h
t
h
a
l
e
n
e
2-
B
u
t
a
n
o
n
e

(
M
E
K
)
n-
B
u
t
y
l
b
e
n
z
e
n
e
se
c
-
B
u
t
y
l
b
e
n
z
e
n
e
Ch
l
o
r
o
f
o
r
m
o-
C
h
l
o
r
o
t
o
l
u
e
n
e
1,
1
-
D
i
c
h
l
o
r
o
e
t
h
y
l
e
n
e
ci
s
-
1
,
2
-

D
i
c
h
l
o
r
o
e
t
h
y
l
e
n
e
tr
a
n
s
-
1
,
2

Di
c
h
l
o
r
o
e
t
h
y
l
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n
e
Di
-
I
s
o
p
r
o
p
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t
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r
Is
o
p
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o
p
y
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b
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n
z
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p-
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s
o
p
r
o
p
y
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t
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Me
t
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l

C
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l
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Me
t
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l
e
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e

C
h
l
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d
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P
r
o
p
y
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b
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St
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Te
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c
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r
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t
h
y
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e

(P
C
E
)
Tr
i
c
h
l
o
r
o
e
t
h
y
l
e
n
e

(T
C
E
)
1,
2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
1,
3
,
5
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
Vi
n
y
l

c
h
l
o
r
i
d
e
te
r
t
-
A
m
y
l

a
l
c
o
h
o
l
(T
A
A
)
te
r
t
-
A
m
y
l

m
e
t
h
y
l

e
t
h
e
r
(T
A
M
E
)
te
r
t
-
B
u
t
y
l

a
l
c
o
h
o
l
(T
B
A
)
1 600 600 500 20 6 4,000 70 70 70 70 350 70 100 70 70 25 3 5 70 70 0.7 3 400 400 0.03 40 128 10
5,000 260,000 80,000 50,000 20,000 6,000 4 x 106 5,900 8,800 70,000 70,000 350,000 70,000 100,000 70,000 30,500 11,700 3,000 5,000 26,100 70,000 700 3,000 28,500 24,100 30 40,000 ######10,000GCL
Analytical Method
2L Standard
12/3/2018 <0.50 <0.50 <0.50 <1.5 <0.50 <0.50 <2.5 <0.50 <0.50 --<0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 --0.79 <0.50 <0.50 <0.50 --------
12/12/2019 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <1.3 <0.13 <0.13 <0.13 <0.13 --<0.13 <0.13 0.13 J <0.13 <0.13 <0.20 <1.0 <0.13 --<0.13 <0.13 <0.13 <0.13 --<2.0 <0.20 <2.0
10/22/2020 <0.24 <0.23 <0.24 <0.50 <0.44 <0.66 <3.6 <0.35 <0.25 <0.35 <0.21 --<0.21 <0.26 <0.33 <0.24 ----<1.5 <0.24 --<0.23 <0.23 <0.19 <0.23 --<40.5 <3.0 <17.6
4/6/2021 <0.34 <0.48 <0.30 <0.34 <0.42 <0.64 <4.0 <0.49 <0.40 <0.35 <0.32 --<0.38 <0.40 <0.31 <0.33 <0.41 --<2.0 <0.34 --<0.29 <0.38 <0.50 <0.33 --<36.4 <2.7 <26.8
1/4/2022 <0.34 <0.48 <0.30 <0.34 <0.42 <0.64 <4.0 <0.49 <0.40 <0.35 <0.32 --<0.38 <0.40 <0.31 <0.33 <0.41 --<2.0 <0.34 --<0.29 <0.38 <0.50 <0.33 <0.39 <36.4 <2.7 <26.8
2/13/2023 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <1.3 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.20 <1.0 <0.13 <0.13 0.38 J <0.13 <0.13 <0.13 <0.13 <2.0 <0.20 <2.0
12/7/2023 <0.079 <0.090 <0.081 <1.4 <0.053 <0.10 --<0.066 <0.085 <0.069 --<0.079 <0.11 <0.10 <0.072 <0.11 ----<1.9 <0.10 <0.14 <0.086 <0.17 <0.031 <0.071 <0.15 <7.4 <0.12 <4.1
12/3/2018
12/12/2019
10/22/2020
3/17/2021 331 117 357 1,219 89.9 76.6 ------------------51.7 ------------------------
4/6/2021
6/11/2021
1/4/2022
2/13/2023
12/7/2023
1/31/2019 310 1,260 125 1,280 10.9 J 44.6 <130 <25 <25 --<25 --<25 <25 34.0 12.0 J <25 <25 --10.5 J --<25 7.6 J 197 49.9 --------
12/12/2019 500 56.5 105 142 6.6 70.8 <13 5.0 3.9 J 7.1 <1.3 --<1.3 <1.3 23.6 62.7 3.3 J <2.0 14.3 J 34.6 --2.0 J <1.3 372 130 --302 2.6 J <20
10/22/2020 473 54.6 89.9 832 <1.8 138 28.6 12.8 <0.98 <1.4 <0.83 --<0.83 <1.0 12.6 106 ----<6.0 74.2 --<0.93 <0.93 567 174 --286J <11.8 <70.4
4/6/2021 347 32.4 40.5 1,060 <1.7 87.6 16.7J <2.0 <1.6 <1.4 <1.3 --<1.5 <1.6 <1.2 48.2 <1.7 --<7.8 <1.4 --<1.2 <1.5 454 <1.3 --<146 <10.6 <107
1/4/2022 50 1.0 30.6 2.7 <0.42 43.1 8.4 <0.49 3.5 <0.35 <0.32 --<0.38 <0.40 14 41.2 2.3 --<2.0 26.5 --<0.29 <0.38 98 <0.33 <0.39 224 <2.7 63.1
2/13/2023 7.9 0.8 5.5 5.5 11 4.8 <1.3 0.33 J 2.2 <0.13 <0.13 <0.13 1.2 <0.13 21.4 11.7 0.16 J <0.20 <1.0 9 <0.13 2.9 2.4 9.6 0.73 <0.13 315 2.6 161
12/7/2023 7.8 <0.090 2.7 0.78 11.0 2.8 --<0.066 0.67 <0.069 --<0.079 1.1 <0.10 23.4 2.3 ----<1.9 1.5 <0.14 2.0 1.7 1.9 <0.071 <0.15 161 2.7J 136
4/6/2021 510 532 902 3,760 <4.2 262 <39.6 217 <4.0 <3.5 <3.2 --<3.8 <3.6 27.9 173 132 --<19.5 <3.4 --394 50.9 1,810 <3.3 --<364 <26.6 <268
1/4/2022
2/13/2023
12/7/2023
MW-4
MW-6
Not Sampled - LNAPL Thickness 0.01'
Not Sampled - LNAPL Thickness 0.03'
Not Sampled - LNAPL Thickness 0.58'
Not Sampled - LNAPL Thickness 0.21'
Not Sampled - LNAPL Thickness 2.01'
Not Sampled - LNAPL Thickness 2.39'
Not Sampled - LNAPL Thickness 0.51'
Not Sampled - LNAPL Thickness 0.23'
Not Sampled - LNAPL Thickness 0.53'
Not Sampled - LNAPL Thickness 0.37'
MW-5
MW-7
Not Sampled - LNAPL Thickness 8.84'
Page 2 of 4
TABLE 7
HISTORICAL GROUNDWATER ANALYTICAL RESULTS
CIRCLE K STORE NO. 2720828
10329 Park Road, Charlotte, NC
NCDEQ Incident #40819
SM 6200B Oxygenates
Well ID Sample
Date
Be
n
z
e
n
e
To
l
u
e
n
e
Et
h
y
l
b
e
n
z
e
n
e
To
t
a
l

X
y
l
e
n
e
s
Me
t
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l

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t

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u
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p
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a
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2-
B
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a
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(
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)
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B
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b
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1,
2
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1,
3
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5
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l
(T
B
A
)
1 600 600 500 20 6 4,000 70 70 70 70 350 70 100 70 70 25 3 5 70 70 0.7 3 400 400 0.03 40 128 10
5,000 260,000 80,000 50,000 20,000 6,000 4 x 106 5,900 8,800 70,000 70,000 350,000 70,000 100,000 70,000 30,500 11,700 3,000 5,000 26,100 70,000 700 3,000 28,500 24,100 30 40,000 ######10,000GCL
Analytical Method
2L Standard
4/6/2021
6/11/2021
1/4/2022
2/13/2023
12/7/2023
1/4/2022 1,490 361 574 2,390 31.6 185 <39.6 79.2 <4.0 <3.5 <3.2 --<3.8 <4.0 116 120 64.1 --<19.5 115 --<2.9 <3.8 819 208 <3.9 1,240 <26.6 479J
2/13/2023
12/7/2023
1/4/2022
2/13/2023
12/7/2023
1/4/2022
2/13/2023
12/7/2023
Not Sampled - LNAPL Thickness 0.60'
MW-10
Not Sampled - LNAPL Thickness 0.37'
Not Sampled - LNAPL Thickness 0.45'
Not Sampled - LNAPL Thickness 0.01'
MW-9
Not Sampled - LNAPL Thickness 0.49'
Not Sampled - LNAPL Thickness 3.00'
MW-11
Not Sampled - LNAPL Thickness 0.40'
MW-8 Not Sampled - LNAPL Thickness 0.43'
Not Sampled - LNAPL Thickness 2.01'
Not Sampled - LNAPL Thickness 0.39'
Not Sampled - LNAPL Thickness 0.81'
Not Sampled - LNAPL Thickness 0.35'
Not Sampled - LNAPL Thickness 0.43'
Page 3 of 4
TABLE 7
HISTORICAL GROUNDWATER ANALYTICAL RESULTS
CIRCLE K STORE NO. 2720828
10329 Park Road, Charlotte, NC
NCDEQ Incident #40819
SM 6200B Oxygenates
Well ID Sample
Date
Be
n
z
e
n
e
To
l
u
e
n
e
Et
h
y
l
b
e
n
z
e
n
e
To
t
a
l

X
y
l
e
n
e
s
Me
t
h
y
l

T
e
r
t

B
u
t
y
l

E
t
h
e
r
Na
p
h
t
h
a
l
e
n
e
2-
B
u
t
a
n
o
n
e

(
M
E
K
)
n-
B
u
t
y
l
b
e
n
z
e
n
e
se
c
-
B
u
t
y
l
b
e
n
z
e
n
e
Ch
l
o
r
o
f
o
r
m
o-
C
h
l
o
r
o
t
o
l
u
e
n
e
1,
1
-
D
i
c
h
l
o
r
o
e
t
h
y
l
e
n
e
ci
s
-
1
,
2
-

D
i
c
h
l
o
r
o
e
t
h
y
l
e
n
e
tr
a
n
s
-
1
,
2

Di
c
h
l
o
r
o
e
t
h
y
l
e
n
e
Di
-
I
s
o
p
r
o
p
y
l

E
t
h
e
r
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e
p-
I
s
o
p
r
o
p
y
l
t
o
l
u
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n
e
Me
t
h
y
l

C
h
l
o
r
i
d
e
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
n-
P
r
o
p
y
l
b
e
n
z
e
n
e
St
y
r
e
n
e
Te
t
r
a
c
h
l
o
r
o
e
t
h
y
l
e
n
e

(P
C
E
)
Tr
i
c
h
l
o
r
o
e
t
h
y
l
e
n
e

(T
C
E
)
1,
2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
1,
3
,
5
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
Vi
n
y
l

c
h
l
o
r
i
d
e
te
r
t
-
A
m
y
l

a
l
c
o
h
o
l
(T
A
A
)
te
r
t
-
A
m
y
l

m
e
t
h
y
l

e
t
h
e
r
(T
A
M
E
)
te
r
t
-
B
u
t
y
l

a
l
c
o
h
o
l
(T
B
A
)
1 600 600 500 20 6 4,000 70 70 70 70 350 70 100 70 70 25 3 5 70 70 0.7 3 400 400 0.03 40 128 10
5,000 260,000 80,000 50,000 20,000 6,000 4 x 106 5,900 8,800 70,000 70,000 350,000 70,000 100,000 70,000 30,500 11,700 3,000 5,000 26,100 70,000 700 3,000 28,500 24,100 30 40,000 ######10,000GCL
Analytical Method
2L Standard
2/13/2023 <1.3 <1.3 3.5 J 6.7 J <1.3 <1.3 <13.0 <1.3 <1.3 <1.3 <1.3 <1/3 1.7 J <1.3 1.6 J <1.3 <1.3 <2.0 <10.0 2.0 J <1.3 242 3.4 J 9 3.6 J <1.3 <20 <2.0 <20.0
12/7/2023 186 47.8 156 287 67.5 85.8 --<0.17 <0.21 <0.17 --<0.20 168 4.0 141 95.7 ----<4.7 54.1 1.1J 7.5 22.7 399 112 <0.37 1170 18.9J 115J
2/13/2023 582 975 260 2,140 59 107 <13.0 14 10 <1.3 <1.3 <1.3 2.4 J <1.3 196 75 6 <2.0 <10.0 93 2.3 J 123 17 699 186 <1.3 581 <2.0 <20.0
12/7/2023
2/13/2023 92 40 269 460 102 80 <13.0 17 13 <1.3 <1.3 <1.3 216 2.3 J 187 139 8 <2.0 <10.0 83 <1.3 19 26 482 146 <1.3 661 26 <20.0
12/7/2023 2.5 <0.18 <0.16 <0.29 <0.11 <0.20 --<0.13 0.88J <0.14 --<0.16 31.4 <0.20 0.94J 1.2 ----<3.8 <0.21 <0.27 206 37.1 <0.061 <0.14 <0.30 <14.9 <0.25 <8.2
12/3/2018 5.5 3.2 J 1.6 J 11.4 J 24.0 3.3 J <25 2.0 J 1.4 J --<5.0 --4.1 J 1.7 J 43.7 <5.0 <5.0 <5.0 --1.8 J --545 28.8 14.0 3.5 J --------
12/12/2019 5.8 <1.3 <1.3 <2.5 37.3 <1.3 <13 <1.3 <1.3 <1.3 <1.3 --18.5 3.4 J 40.4 <1.3 <1.3 <2.0 14.8 J <1.3 --492 46.9 <1.3 <1.3 --978 4.4 J 387
10/22/2020 45.9 <0.57 8.4 3.6 34.7 <1.6 <9.0 <0.88 <0.62 <0.88 <0.52 --24.4 4.7 45.8 1.2J ----<3.8 <0.60 --393 50.2 5.9 <0.57 --1,290 <7.4 472
4/6/2021 101 23.1 14.9 39.7 36.6 5.3 <9.9 <1.2 <1.0 <0.88 <0.80 --34.1 <0.91 48.4 2.2 <1.0 --<4.9 <0.85 --270 87.4 13.8 <0.83 --1,200 <6.6 474
1/4/2022 49.1 <1.2 12.4 5.6 31.5 2.7J <9.9 <1.2 <1.0 <0.88 <0.80 --29.8 6.8 48.7 1.2J <1.0 --<4.9 0.86J --327 101 3.6 <0.83 3.4 1,210 <6.6 564
2/13/2023 34.7 <1.3 10.9 <2.5 38 1.6 J <13.0 <1.3 <1.3 <1.3 <1.3 1.6 J 54.7 9.6 54 1.4 J <1.3 <2.0 <10.0 <1.3 <1.3 228 86.7 <1.3 <1.3 20.4 1,380 7.6 J 586
12/7/2023 6.0 <0.18 2.5 <0.29 33.5 <0.20 --<0.13 <0.17 <0.14 --4.5 32.6 7.8 50.5 <0.21 ----<3.8 <0.21 <0.27 257 79.3 <0.061 <0.14 11.4 966 7.7J 548
TW-2 12/7/2023 4.6 <0.22 <0.20 <0.36 13.6 <0.25 --<0.17 <0.21 <0.17 --<0.20 11.5 2.4 33.8 <0.26 ----<4.7 <0.26 <0.34 331 27.4 <0.077 <0.18 <0.37 <18.6 5.6J 29.5J
3/17/2021 479 617 249 937 42.9 --------------------53 --------------------------
4/6/2021
6/11/2021
1/4/2022
2/13/2023
12/7/2023
RW-2 12/7/2023
RW-3 12/7/2023
AS-1 12/7/2023 5,080 6,850 1,200 11,300 109 308 --<3.3 <4.3 <3.5 --<3.9 <5.6 <5.0 309 195 ----<94.5 262 <6.8 <4.3 <8.6 2,020 441 <7.4 <372 <6.2 <204
AS-2 12/7/2023 11.6 1.3J 1.6J 37.3 73.1 7.7J --<0.27 <0.34 <0.28 --<0.31 6.7 <0.40 92.9 3.8 ----<7.6 3.3 <0.55 382 22.2 46.9 15.4 <0.60 418 13.3J 145J
Notes:J = Estimated value between method detection limit and laboratory reporting limit.
All values reported in micrograms per liter (µg/L)Underlined values indicate detection limit is above 2L Standard due to dilution.
2L Standard as defined in North Carolina Groundwater Standards, Title 15A, NCAC, Subchapter 2L, Part .0202 Values in BOLD print indicate levels above 2L Standards
GCL = Gross Contamination Level Values that are Bold and Underlined indicate levels above GCLs
NSE = No Standard Established -- = Not analyzed or not previously reported
Not Sampled - LNAPL Thickness 0.47'
Not Sampled - LNAPL Thickness 0.86'
Not Sampled - LNAPL Thickness 2.13'
Not Sampled - LNAPL Thickness 0.02'
Not Sampled - LNAPL Thickness 0.69'
Not Sampled - LNAPL Thickness 0.01'
RW-1
MW-13
MW-12
MW-14
Not Sampled - LNAPL Thickness 0.01'
TW-1
Not Sampled - LNAPL Thickness 0.17'
Page 4 of 4
TABLE 8
LNAPL RECOVERY INFORMATION
CIRCLE K STORE NO. 2720828
10326 Park Road, Charlotte, NC
NCDEQ Incident #40819
Date(s) of
Recovery
Event
Well ID
Product
Type
(gas, diesel, etc.)
LNAPL
Recovery
Method
Depth to
LNAPL
(ft BTOC)
Depth to
Water
(ft BTOC)
LNAPL
Thickness
Before
Recovery
(ft)
LNAPL
Thickness
After
Recovery
(ft)
LNAPL
Recovered
(gal)
Volatilized
LNAPL
(gal)
Liquid
Recovered
(gal)
11/01/18 MW-1 AFVR 21.48 33.56 12.08 0.00 --0.53 820
MW-1 20.05 31.15 11.10 0.46
MW-5 19.97 26.65 6.68 0.06
MW-1 18.62 23.22 4.60 1.02
MW-5 NM 17.78 0.00 0.14
MW-1 15.82 19.71 3.89 0.07
MW-5 15.62 17.18 1.56 0.01
RW-1 ND 16.76 0.00 0.00
MW-1 21.81 24.17 2.36 0.00
MW-5 22.89 23.39 0.50 0.60
MW-8 27.11 29.71 2.60 0.00
MW-9 22.95 23.08 0.13 0.00
MW-10 26.29 27.13 0.84 0.00
MW-11 19.88 26.58 6.70 0.00
RW-1 24.86 25.70 0.84 0.00
MW-1 22.60 25.54 2.94 0.00
MW-5 22.11 25.47 3.36 0.00
MW-7 22.06 24.49 2.43 0.00
MW-8 23.26 27.59 4.33 0.00
MW-10 26.14 26.71 0.57 0.00
MW-11 22.85 27.34 4.49 0.06
RW-1 22.70 27.64 4.94 0.02
MW-5 0.00 21.69 0.00 0.00
MW-8 23.35 27.28 3.93 0.00
MW-10 25.26 26.00 0.74 0.00
RW-1 0.00 22.03 0.00 0.00
RW-2 23.15 23.52 0.37 0.00
MW-1 22.70 23.90 1.20 0.00
MW-5 22.30 22.98 0.68 0.15
MW-9 22.80 23.11 0.31 0.38
MW-10 0.00 26.01 0.00 0.00
RW-1 23.20 23.76 0.56 0.00
RW-3 23.18 24.73 1.55 0.00
430 1290 43,650
NOTES:
ft - Feet
BTOC - Below top of casing
LNAPL = Light Non-Aqueous Phase Liquid
gal - gallons
AFVR - Aggressive Fluid-Vapor Recovery (8-hours)
MMPE - Mobile Multi-Phase Extraction (96-hours)
45.17 6,268Diesel / Gasoline MMPE
MMPE 102 131.71 4,980
10/30/23-
11/3/23 Diesel / Gasoline MMPE 30 52.95 5,468
5,417
5,241
Cumulative Volume Recovered:
11/18/19 -
11/22/19 MMPE 107 340.7
9/14/20 -
9/18/20
187.46 10,000
402.74
Diesel
MMPE
3/15/21-
3/19/21 Diesel / Gasoline MMPE 67
92
11/6/23-
11/10/23
MMPEDiesel / Gasoline12/6/21-
12/10/21 5,45612921
Diesel / Gasoline12/5/2022-
12/9/2022
11

FIGURES
CIRCLE K STORE NO. 2720828
10329 PARK ROAD
CHARLOTTE, NORTH CAROLINA 28210 1
FIGURE TITLE:
ADDRESS:PROJECT NO.:
CIRK082803
SITE LOCATION MAP
FIGURE:
DATE:
11-20-18
MW-6
MW-4
MW-1
TW-1
MW-2
MW-3
MW-5
RW-1
MW-8
MW-7
CIRCLE K #2720828
STORE
DISPE
N
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A
N
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BASIN
MW-9
MW-10
MW-11
MW-14
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STORE
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78.79
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[75.03]
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[75.41]
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[TW-1]
[MW-2]
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MW-8
MW-7
CIRCLE K #2720828
STORE
DISPE
N
S
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R

C
A
N
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MW-10
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2
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-
1

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G
2.3
7.8
203LNAPL
3.5
NE
LNAPL
LNAPL
6.0
LNAPL
186
2.5
LNAPL
10
0

µ
g
/
L
LNAPL
LNAPL
1
µ
g
/
L
10

µ
g
/
L
4.6
LNAPL
LNAPL
LNAPL
11.6
NE
LNAPL
5,080
LNAPL
LNAPL
1,
0
0
0

µ
g
/
L
MW-6
MW-4
MW-1
[TW-1]
[MW-2]
MW-3
MW-5
RW-1
MW-8
MW-7
CIRCLE K #2720828
STORE
DISPE
N
S
E
R

C
A
N
O
P
Y
UST
BASIN
MW-9
MW-10
MW-11
MW-14
MW-13
MW-12
AS-1
TW-2
AS-2
RW-2
RW-3
AS
S
O
C
I
A
T
E
S

O
F

N
O
R
T
H

C
A
R
O
L
I
N
A
,

P
.
C
.
(7
0
4
)

5
2
9
-
3
2
0
0

F
A
X

(
7
0
4
)

5
2
9
-
3
2
7
2
PR
O
J
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C
T

N
O
.
Ch
a
r
l
o
t
t
e
,

N
o
r
t
h

C
a
r
o
l
i
n
a

2
8
2
7
3
NO
T
E
S
:
DA
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TI
T
L
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SC
A
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RE
V
.

B
Y
PR
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.

B
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CA
D

F
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DC
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A

I
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\
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R
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!
\
A
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L
o
g
o

-

2
0
1
5
\
A
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L
o
g
o
_
F
u
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l

C
o
l
o
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_
C
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K
.
j
p
g
1.
GR
O
U
N
D
W
A
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R

S
A
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P
L
E
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T
A
K
E
N

1
2
/
0
7
/
2
0
2
3
AN
D

1
2
/
0
8
/
2
0
2
3
2.
TH
E

W
E
L
L

S
C
R
E
E
N

O
F

T
W
-
1

A
N
D

T
W
-
2

D
O
E
S
NO
T

I
N
T
E
R
S
E
C
T

T
H
E

W
A
T
E
R

T
A
B
L
E
0.69'
LNAPL
0.40'
0.60'
0.03'
0.49'
0.58'
3.00'
0.20'
0.01'
0.69'
0.47'
0.02'
1.0'
0.5'
0.0'
0.5'
MW-6
MW-4
MW-1
TW-1
MW-2
MW-3
MW-5
RW-1
MW-8
MW-7
CIRCLE K #2720828
STORE
DISPE
N
S
E
R

C
A
N
O
P
Y
UST
BASIN
MW-9
MW-10
MW-11
MW-14
MW-13
MW-12
AS-1
TW-2
AS-2
RW-2
RW-3
AS
S
O
C
I
A
T
E
S

O
F

N
O
R
T
H

C
A
R
O
L
I
N
A
,

P
.
C
.
(7
0
4
)

5
2
9
-
3
2
0
0

F
A
X

(
7
0
4
)

5
2
9
-
3
2
7
2
PR
O
J
E
C
T

N
O
.
Ch
a
r
l
o
t
t
e
,

N
o
r
t
h

C
a
r
o
l
i
n
a

2
8
2
7
3
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S
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DA
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A
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V
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PR
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CA
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a
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U
R
N
S
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\
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0
1
5
\
A
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j
p
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1.
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P
O
R
T
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D

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N
C
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N
T
R
A
T
I
O
N
S

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X
C
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D
2L

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T
A
N
D
A
R
D
S
2.
UN
D
E
R
L
I
N
E
D

V
A
L
U
E
S

E
X
C
E
E
D

G
C
L
3.
SA
M
P
L
E
S

C
O
L
L
E
C
T
E
D
O
N

D
A
T
E

S
H
O
W
N
LNAPL

APPENDIX A
SOIL BORING LOGS AND WELL CONSTRUCTION RECORDS
10
-
2
5
-
2
0
2
3

C
:
\
U
s
e
r
s
\
j
o
h
n
.
c
o
o
p
e
r
\
D
e
s
k
t
o
p
\
W
e
l
l

L
o
g
s
\
8
2
8

A
S
2
.
b
o
r
Circle K 2720828
10329 Park Road
Charlotte, Meckenburg County, North Carolina
ATC Project Number: CIRK082809
EDPS= Environmental Drilling and Probing Services
BGS = Below Ground Surface.
TWD= Total Well Depth
PID = Photoionization Detector.
PPM = Parts Per Million.
PID readings were collected every 5 feet BGS.
MONITORING WELL: AS-2
(Page 1 of 1)
Date(s) Drilled : 10/09/2023
Drilling Contractor : EDPS
Drilling Method : Hand Auger (HA)
: Air Rotary
Boring Diameter : 6 inches
Sampling Method : HA / Air Rotary
Sampling Interval : Every 5 feet
Logged by : JAC
De
p
t
h

I
n

F
e
e
t

(
B
G
S
)
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
GR
A
P
H
I
C
DESCRIPTION
Top Soil Dry
Red Clay Dry
Partially Weatherd Rock
End Of Boring
PID Screening
Interval
(Feet BGS)
0-5
5-10
10-15
15-20
20-25
25-30
30-35
Organic Vapor
Analysis
(PPM)
0.5
0.1
1.0
109.0
113.3
67
13.5
Elev.: 102.64
Well: AS2
Grout
Bentonite
Sand Pack
Cover
Casing
Screen
10
-
2
5
-
2
0
2
3

C
:
\
U
s
e
r
s
\
j
o
h
n
.
c
o
o
p
e
r
\
D
e
s
k
t
o
p
\
W
e
l
l

L
o
g
s
\
8
2
8

A
S
3
.
b
o
r
Circle K 2720828
10329 Park Road
Charlotte, Meckenburg County, North Carolina
ATC Project Number: CIRK082809
EDPS= Environmental Drilling and Probing Services
BGS = Below Ground Surface.
TWD= Total Well Depth
PID = Photoionization Detector.
PPM = Parts Per Million.
PID readings were collected every 5 feet BGS.
MONITORING WELL: AS-1
(Page 1 of 1)
Date(s) Drilled : 10/09/2023
Drilling Contractor : EDPS
Drilling Method : Hand Auger (HA)
: Air Rotary
Boring Diameter : 6 inches
Sampling Method : HA / Air Rotary
Sampling Interval : Every 5 feet
Logged by : JAC
De
p
t
h

I
n

F
e
e
t

(
B
G
S
)
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
GR
A
P
H
I
C
DESCRIPTION
Top Soil Dry
Red Clay Dry
Partially Weatherd Rock
End Of Boring
PID Screening
Interval
(Feet BGS)
0-5
5-10
10-15
15-20
20-25
25-30
Organic Vapor
Analysis
(PPM)
0.5
1.1
3.6
0.5
147.0
3.0
Elev.: 100.49
Well: AS-1
Grout
Bentonite
Sand Pack
Cover
Casing
Screen
10
-
2
5
-
2
0
2
3

C
:
\
U
s
e
r
s
\
j
o
h
n
.
c
o
o
p
e
r
\
D
e
s
k
t
o
p
\
W
e
l
l

L
o
g
s
\
8
2
8

R
W
-
2
.
b
o
r
Circle K 2720828
10329 Park Road
Charlotte, Meckenburg County, North Carolina
ATC Project Number: CIRK082809
EDPS= Environmental Drilling and Probing Services
BGS = Below Ground Surface.
TWD= Total Well Depth
PID = Photoionization Detector.
PPM = Parts Per Million.
PID readings were collected every 5 feet BGS.
MONITORING WELL: RW-2
(Page 1 of 1)
De
p
t
h

I
n

F
e
e
t

(
B
G
S
)
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
GR
A
P
H
I
C
DESCRIPTION
Top Soil Dry
Red Clay Dry
Partially Weatherd Rock
End Of Boring
Elev.: 100.72
Well: RW-2
Grout
Bentonite
Sand Pack
Cover
Casing
Screen
TWD
PID Screening
Interval
(Feet BGS)
0-5
5-10
10-15
15-20
20-25
25-30
30-35
35-40
Organic Vapor
Analysis
(PPM)
0.0
0.1
0.0
3.0
949.2
98
13.0
7.8
Date(s) Drilled : 10/09/2023
Drilling Contractor : EDPS
Drilling Method : Hand Auger (HA)
: Air Rotary
Boring Diameter : 10 inches
Sampling Method : HA / Air Rotary
Sampling Interval : Every 5 feet
Logged by : JAC
10
-
2
6
-
2
0
2
3

C
:
\
U
s
e
r
s
\
j
o
h
n
.
c
o
o
p
e
r
\
D
e
s
k
t
o
p
\
W
e
l
l

L
o
g
s
\
8
2
8

R
W
-
3
.
b
o
r
Circle K 2720828
10329 Park Road
Charlotte, Meckenburg County, North Carolina
ATC Project Number: CIRK082809
EDPS= Environmental Drilling and Probing Services
BGS = Below Ground Surface.
TWD= Total Well Depth
PID = Photoionization Detector.
PPM = Parts Per Million.
PID readings were collected every 5 feet BGS.
MONITORING WELL: RW-3
(Page 1 of 1)
Date(s) Drilled : 10/09/2023
Drilling Contractor : EDPS
Drilling Method : Hand Auger (HA)
: Air Rotary
Boring Diameter : 10 inches
Sampling Method : HA / Air Rotary
Sampling Interval : Every 5 feet
Logged by : JAC
De
p
t
h

I
n

F
e
e
t

(
B
G
S
)
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
GR
A
P
H
I
C
DESCRIPTION
Top Soil Dry
Red Clay Dry
Partially Weatherd Rock
End Of Boring
PID Screening
Interval
(Feet BGS)
0-5
5-10
10-15
15-20
20-25
25-30
30-35
Organic Vapor
Analysis
(PPM)
0.5
0.1
1.0
109.0
113.3
67
13.5
Elev.: 100.49
Well: RW-3
Grout
Bentonite
Sand Pack
Cover
Casing
Screen
TWD
10
-
2
6
-
2
0
2
3

C
:
\
U
s
e
r
s
\
j
o
h
n
.
c
o
o
p
e
r
\
D
e
s
k
t
o
p
\
W
e
l
l

L
o
g
s
\
T
W
-
2

(
2
)
.
b
o
r
Circle K 2720828
10329 Park Road
Charlotte, Meckenburg County, North Carolina
ATC Project Number: CIRK082809
EDPS= Environmental Drilling and Probing Services
BGS = Below Ground Surface.
TWD= Total Well Depth
PID = Photoionization Detector.
PPM = Parts Per Million.
PID readings were collected every 5 feet BGS.
MONITORING WELL: TW-2
(Page 1 of 1)
De
p
t
h

I
n

F
e
e
t

(
B
G
S
)
012
345
678
91011121314
1516171819
202122
2324252627282930313233
343536
373839
4041424344
454647
484950
5152535455565758
596061
GR
A
P
H
I
C
DESCRIPTION
Top Soil Dry
Red Clay Dry
Partially Weatherd Rock
End Of Boring
PID Screening
Interval
(Feet BGS)
0-5
5-10
10-15
15-20
20-25
25-30
30-35
35-40
40-45
45-50
50-55
55-60
Organic Vapor
Analysis
(PPM)
0.0
0.0
0.0
0.0
0.0
11.0
5.7
6.0
0.0
0.0
0.0
0.0
Date(s) Drilled : 10/09-10/2023
Drilling Contractor : EDPS
Drilling Method : Hand Auger (HA)
: Air Rotary
Outer Boring : 10 iIches
Inner Boring : 6 Inches
Drilling Method : HA/ Air Rotery
Sampling Interval : Every 5 feet
Logged by : JAC
101.85
Well: Tw-2
Outer Casing
Grout
OuterCasing
Cover
Inner Casing
Grout
Bentonite
Sand
Screen
TWD

APPENDIX B
MMPE DATA & EMISSIONS CALCULATIONS

APPENDIX C
LABORATORY ANALYTICAL REPORT

#=CL#
December 15, 2023
LIMS USE: FR - NOELLE FRANCE
LIMS OBJECT ID: 92702751
92702751
Project:
Pace Project No.:
RE:
Noelle France
ATC Group Services LLC- South Charlotte
7606 Whitehall Exe Center Dr
Suite 800
Charlotte, NC 28273
CK 0828 CHARLOTTE, NC
Dear Noelle France:
Enclosed are the analytical results for sample(s) received by the laboratory on December 08, 2023. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor M Cannon
[e-mail]
Project Manager
704-977-0943
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 44
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 44
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Lab ID Sample ID Matrix Date Collected Date Received
92702751001 MW-2 Water 12/07/23 12:30 12/08/23 12:55
92702751002 MW-3 Water 12/07/23 11:45 12/08/23 12:55
92702751003 MW-4 Water 12/08/23 10:50 12/08/23 12:55
92702751004 MW-6 Water 12/08/23 09:35 12/08/23 12:55
92702751005 MW-12 Water 12/07/23 13:10 12/08/23 12:55
92702751006 MW-14 Water 12/07/23 11:55 12/08/23 12:55
92702751007 TW-1 Water 12/08/23 10:30 12/08/23 12:55
92702751008 TW-2 Water 12/08/23 11:45 12/08/23 12:55
92702751009 AS-1 Water 12/07/23 13:10 12/08/23 12:55
92702751010 AS-2 Water 12/07/23 12:50 12/08/23 12:55
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 44
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92702751001 MW-2 SM 6200B 69 PASI-CLMB
92702751002 MW-3 SM 6200B 69 PASI-CSAS
92702751003 MW-4 SM 6200B 69 PASI-CSAS
92702751004 MW-6 SM 6200B 69 PASI-CSAS
92702751005 MW-12 SM 6200B 69 PASI-CSAS
92702751006 MW-14 SM 6200B 69 PASI-CSAS
92702751007 TW-1 SM 6200B 69 PASI-CSAS
92702751008 TW-2 SM 6200B 69 PASI-CSAS
92702751009 AS-1 SM 6200B 69 PASI-CSAS
92702751010 AS-2 SM 6200B 69 PASI-CSAS
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 44
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Sample:MW-2 Lab ID:92702751001 Collected:12/07/23 12:30 Received:12/08/23 12:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol 1300 ug/L 12/15/23 06:24 75-85-420014.9 2
tert-Amylmethyl ether 41.8 ug/L 12/15/23 06:24 994-05-820.0 0.25 2
Benzene 203 ug/L 12/15/23 06:24 71-43-21.0 0.16 2
Bromobenzene <0.27 ug/L 12/15/23 06:24 108-86-11.0 0.27 2
Bromochloromethane <0.19 ug/L 12/15/23 06:24 74-97-51.0 0.19 2
Bromodichloromethane <0.34 ug/L 12/15/23 06:24 75-27-41.0 0.34 2
Bromoform <0.39 ug/L 12/15/23 06:24 75-25-21.0 0.39 2
Bromomethane <0.44 ug/L 12/15/23 06:24 74-83-910.0 0.44 2
tert-Butyl Alcohol 79.6J ug/L 12/15/23 06:24 75-65-01008.2 2
n-Butylbenzene <0.13 ug/L 12/15/23 06:24 104-51-81.0 0.13 2
sec-Butylbenzene 5.3 ug/L 12/15/23 06:24 135-98-81.0 0.17 2
tert-Butylbenzene <0.17 ug/L 12/15/23 06:24 98-06-61.0 0.17 2
tert-Butyl Formate <0.60 ug/L 12/15/23 06:24 762-75-41000.60 2
Carbon tetrachloride <0.34 ug/L 12/15/23 06:24 56-23-51.0 0.34 2
Chlorobenzene <0.17 ug/L 12/15/23 06:24 108-90-71.0 0.17 2
Chloroethane <0.35 ug/L 12/15/23 06:24 75-00-32.0 0.35 2
Chloroform <0.14 ug/L 12/15/23 06:24 67-66-31.0 0.14 2
Chloromethane <0.35 ug/L 12/15/23 06:24 74-87-32.0 0.35 2
2-Chlorotoluene <0.26 ug/L 12/15/23 06:24 95-49-81.0 0.26 2
4-Chlorotoluene <0.19 ug/L 12/15/23 06:24 106-43-41.0 0.19 2
1,2-Dibromo-3-chloropropane <0.36 ug/L 12/15/23 06:24 96-12-82.0 0.36 2
Dibromochloromethane <0.30 ug/L 12/15/23 06:24 124-48-11.0 0.30 2
1,2-Dibromoethane (EDB)<0.29 ug/L 12/15/23 06:24 106-93-41.0 0.29 2
Dibromomethane <0.37 ug/L 12/15/23 06:24 74-95-31.0 0.37 2
1,2-Dichlorobenzene <0.19 ug/L 12/15/23 06:24 95-50-11.0 0.19 2
1,3-Dichlorobenzene <0.20 ug/L 12/15/23 06:24 541-73-11.0 0.20 2
1,4-Dichlorobenzene <0.18 ug/L 12/15/23 06:24 106-46-71.0 0.18 2
Dichlorodifluoromethane <0.25 ug/L 12/15/23 06:24 75-71-81.0 0.25 2
1,1-Dichloroethane <0.11 ug/L 12/15/23 06:24 75-34-31.0 0.11 2
1,2-Dichloroethane <0.21 ug/L 12/15/23 06:24 107-06-21.0 0.21 2
1,1-Dichloroethene <0.16 ug/L 12/15/23 06:24 75-35-41.0 0.16 2
cis-1,2-Dichloroethene 50.7 ug/L 12/15/23 06:24 156-59-21.0 0.22 2
trans-1,2-Dichloroethene 1.0 ug/L 12/15/23 06:24 156-60-51.0 0.20 2
1,2-Dichloropropane <0.27 ug/L 12/15/23 06:24 78-87-51.0 0.27 2
1,3-Dichloropropane <0.17 ug/L 12/15/23 06:24 142-28-91.0 0.17 2
2,2-Dichloropropane <0.24 ug/L 12/15/23 06:24 594-20-71.0 0.24 2
1,1-Dichloropropene <0.13 ug/L 12/15/23 06:24 563-58-61.0 0.13 2
cis-1,3-Dichloropropene <0.18 ug/L 12/15/23 06:24 10061-01-51.0 0.18 2
trans-1,3-Dichloropropene <0.26 ug/L 12/15/23 06:24 10061-02-61.0 0.26 2
Diisopropyl ether 303 ug/L 12/15/23 06:24 108-20-31.0 0.14 2
Ethanol <10.1 ug/L 12/15/23 06:24 64-17-540010.1 2
Ethylbenzene 27.3 ug/L 12/15/23 06:24 100-41-41.0 0.16 2
Ethyl-tert-butyl ether <0.22 ug/L 12/15/23 06:24 637-92-320.0 0.22 2
Hexachloro-1,3-butadiene <0.70 ug/L 12/15/23 06:24 87-68-34.0 0.70 2
Isopropylbenzene (Cumene)17.2 ug/L 12/15/23 06:24 98-82-81.0 0.21 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 44
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Sample:MW-2 Lab ID:92702751001 Collected:12/07/23 12:30 Received:12/08/23 12:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <3.8 ug/L 12/15/23 06:24 75-09-24.0 3.8 2
Methyl-tert-butyl ether 138 ug/L 12/15/23 06:24 1634-04-41.0 0.11 2
Naphthalene 8.7 ug/L 12/15/23 06:24 91-20-34.0 0.20 2
n-Propylbenzene 6.0 ug/L 12/15/23 06:24 103-65-11.0 0.21 2
Styrene <0.27 ug/L 12/15/23 06:24 100-42-51.0 0.27 2
1,1,1,2-Tetrachloroethane <0.18 ug/L 12/15/23 06:24 630-20-61.0 0.18 2
1,1,2,2-Tetrachloroethane <0.15 ug/L 12/15/23 06:24 79-34-51.0 0.15 2
Tetrachloroethene 3.5 ug/L 12/15/23 06:24 127-18-41.0 0.17 2
Toluene 1.9 ug/L 12/15/23 06:24 108-88-31.0 0.18 2
1,2,3-Trichlorobenzene <0.24 ug/L 12/15/23 06:24 87-61-64.0 0.24 2
1,2,4-Trichlorobenzene <0.31 ug/L 12/15/23 06:24 120-82-14.0 0.31 2
1,1,1-Trichloroethane <0.21 ug/L 12/15/23 06:24 71-55-61.0 0.21 2
1,1,2-Trichloroethane <0.19 ug/L 12/15/23 06:24 79-00-51.0 0.19 2
Trichloroethene 15.5 ug/L 12/15/23 06:24 79-01-61.0 0.34 2
Trichlorofluoromethane <0.29 ug/L 12/15/23 06:24 75-69-42.0 0.29 2
1,2,3-Trichloropropane <0.35 ug/L 12/15/23 06:24 96-18-41.0 0.35 2
1,2,4-Trimethylbenzene 8.9 ug/L 12/15/23 06:24 95-63-61.0 0.061 2
1,3,5-Trimethylbenzene 2.3 ug/L 12/15/23 06:24 108-67-81.0 0.14 2
Vinyl chloride <0.30 ug/L 12/15/23 06:24 75-01-42.0 0.30 2
m&p-Xylene 4.7 ug/L 12/15/23 06:24 179601-23-12.0 0.19 2
o-Xylene 1.2 ug/L 12/15/23 06:24 95-47-61.0 0.29 2
Surrogates
1,2-Dichloroethane-d4 (S)106 %12/15/23 06:24 17060-07-070-130 2
4-Bromofluorobenzene (S)101 %12/15/23 06:24 460-00-470-130 2
Toluene-d8 (S)101 %12/15/23 06:24 2037-26-570-130 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 44
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Sample:MW-3 Lab ID:92702751002 Collected:12/07/23 11:45 Received:12/08/23 12:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <74.4 ug/L 12/14/23 16:48 75-85-4100074.4 10
tert-Amylmethyl ether <1.2 ug/L 12/14/23 16:48 994-05-81001.2 10
Benzene 3.5J ug/L 12/14/23 16:48 71-43-25.0 0.79 10
Bromobenzene <1.4 ug/L 12/14/23 16:48 108-86-15.0 1.4 10
Bromochloromethane <0.94 ug/L 12/14/23 16:48 74-97-55.0 0.94 10
Bromodichloromethane <1.7 ug/L 12/14/23 16:48 75-27-45.0 1.7 10
Bromoform <2.0 ug/L 12/14/23 16:48 75-25-25.0 2.0 10
Bromomethane <2.2 ug/L 12/14/23 16:48 74-83-950.0 2.2 10
tert-Butyl Alcohol <40.9 ug/L 12/14/23 16:48 75-65-050040.9 10
n-Butylbenzene <0.66 ug/L 12/14/23 16:48 104-51-85.0 0.66 10
sec-Butylbenzene <0.85 ug/L 12/14/23 16:48 135-98-85.0 0.85 10
tert-Butylbenzene <0.86 ug/L 12/14/23 16:48 98-06-65.0 0.86 10
tert-Butyl Formate <3.0 ug/L 12/14/23 16:48 762-75-45003.0 10
Carbon tetrachloride <1.7 ug/L 12/14/23 16:48 56-23-55.0 1.7 10
Chlorobenzene <0.85 ug/L 12/14/23 16:48 108-90-75.0 0.85 10
Chloroethane <1.7 ug/L 12/14/23 16:48 75-00-310.0 1.7 10
Chloroform <0.69 ug/L 12/14/23 16:48 67-66-35.0 0.69 10
Chloromethane <1.8 ug/L 12/14/23 16:48 74-87-310.0 1.8 10
2-Chlorotoluene <1.3 ug/L 12/14/23 16:48 95-49-85.0 1.3 10
4-Chlorotoluene <0.96 ug/L 12/14/23 16:48 106-43-45.0 0.96 10
1,2-Dibromo-3-chloropropane <1.8 ug/L 12/14/23 16:48 96-12-810.0 1.8 10
Dibromochloromethane <1.5 ug/L 12/14/23 16:48 124-48-15.0 1.5 10
1,2-Dibromoethane (EDB)<1.5 ug/L 12/14/23 16:48 106-93-45.0 1.5 10
Dibromomethane <1.9 ug/L 12/14/23 16:48 74-95-35.0 1.9 10
1,2-Dichlorobenzene <0.94 ug/L 12/14/23 16:48 95-50-15.0 0.94 10
1,3-Dichlorobenzene <0.98 ug/L 12/14/23 16:48 541-73-15.0 0.98 10
1,4-Dichlorobenzene <0.90 ug/L 12/14/23 16:48 106-46-75.0 0.90 10
Dichlorodifluoromethane <1.2 ug/L 12/14/23 16:48 75-71-85.0 1.2 10
1,1-Dichloroethane <0.56 ug/L 12/14/23 16:48 75-34-35.0 0.56 10
1,2-Dichloroethane <1.1 ug/L 12/14/23 16:48 107-06-25.0 1.1 10
1,1-Dichloroethene <0.79 ug/L 12/14/23 16:48 75-35-45.0 0.79 10
cis-1,2-Dichloroethene 9.9 ug/L 12/14/23 16:48 156-59-25.0 1.1 10
trans-1,2-Dichloroethene <1.0 ug/L 12/14/23 16:48 156-60-55.0 1.0 10
1,2-Dichloropropane <1.4 ug/L 12/14/23 16:48 78-87-55.0 1.4 10
1,3-Dichloropropane <0.85 ug/L 12/14/23 16:48 142-28-95.0 0.85 10
2,2-Dichloropropane <1.2 ug/L 12/14/23 16:48 594-20-75.0 1.2 10
1,1-Dichloropropene <0.66 ug/L 12/14/23 16:48 563-58-65.0 0.66 10
cis-1,3-Dichloropropene <0.90 ug/L 12/14/23 16:48 10061-01-55.0 0.90 10
trans-1,3-Dichloropropene <1.3 ug/L 12/14/23 16:48 10061-02-65.0 1.3 10
Diisopropyl ether <0.72 ug/L 12/14/23 16:48 108-20-35.0 0.72 10
Ethanol <50.5 ug/L 12/14/23 16:48 64-17-5200050.5 10
Ethylbenzene <0.81 ug/L 12/14/23 16:48 100-41-45.0 0.81 10
Ethyl-tert-butyl ether <1.1 ug/L 12/14/23 16:48 637-92-31001.1 10
Hexachloro-1,3-butadiene <3.5 ug/L 12/14/23 16:48 87-68-320.0 3.5 10
Isopropylbenzene (Cumene)<1.1 ug/L 12/14/23 16:48 98-82-85.0 1.1 10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 44
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Sample:MW-3 Lab ID:92702751002 Collected:12/07/23 11:45 Received:12/08/23 12:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <18.9 ug/L 12/14/23 16:48 75-09-220.0 18.9 10
Methyl-tert-butyl ether <0.53 ug/L 12/14/23 16:48 1634-04-45.0 0.53 10
Naphthalene 5.0J ug/L 12/14/23 16:48 91-20-320.0 1.0 10
n-Propylbenzene <1.0 ug/L 12/14/23 16:48 103-65-15.0 1.0 10
Styrene <1.4 ug/L 12/14/23 16:48 100-42-55.0 1.4 10
1,1,1,2-Tetrachloroethane <0.91 ug/L 12/14/23 16:48 630-20-65.0 0.91 10
1,1,2,2-Tetrachloroethane <0.74 ug/L 12/14/23 16:48 79-34-55.0 0.74 10
Tetrachloroethene 910 ug/L 12/14/23 16:48 127-18-45.0 0.86 10
Toluene <0.90 ug/L 12/14/23 16:48 108-88-35.0 0.90 10
1,2,3-Trichlorobenzene <1.2 ug/L 12/14/23 16:48 87-61-620.0 1.2 10
1,2,4-Trichlorobenzene <1.6 ug/L 12/14/23 16:48 120-82-120.0 1.6 10
1,1,1-Trichloroethane <1.1 ug/L 12/14/23 16:48 71-55-65.0 1.1 10
1,1,2-Trichloroethane <0.96 ug/L 12/14/23 16:48 79-00-55.0 0.96 10
Trichloroethene 8.2 ug/L 12/14/23 16:48 79-01-65.0 1.7 10
Trichlorofluoromethane <1.4 ug/L 12/14/23 16:48 75-69-410.0 1.4 10
1,2,3-Trichloropropane <1.7 ug/L 12/14/23 16:48 96-18-45.0 1.7 10
1,2,4-Trimethylbenzene <0.31 ug/L 12/14/23 16:48 95-63-65.0 0.31 10
1,3,5-Trimethylbenzene <0.71 ug/L 12/14/23 16:48 108-67-85.0 0.71 10
Vinyl chloride <1.5 ug/L 12/14/23 16:48 75-01-410.0 1.5 10
m&p-Xylene <0.94 ug/L 12/14/23 16:48 179601-23-110.0 0.94 10
o-Xylene <1.4 ug/L 12/14/23 16:48 95-47-65.0 1.4 10
Surrogates
1,2-Dichloroethane-d4 (S)117 %12/14/23 16:48 17060-07-070-130 10
4-Bromofluorobenzene (S)104 %12/14/23 16:48 460-00-470-130 10
Toluene-d8 (S)101 %12/14/23 16:48 2037-26-570-130 10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 44
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Sample:MW-4 Lab ID:92702751003 Collected:12/08/23 10:50 Received:12/08/23 12:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <7.4 ug/L 12/14/23 12:52 75-85-41007.4 1
tert-Amylmethyl ether <0.12 ug/L 12/14/23 12:52 994-05-810.0 0.12 1
Benzene <0.079 ug/L 12/14/23 12:52 71-43-20.50 0.079 1
Bromobenzene <0.14 ug/L 12/14/23 12:52 108-86-10.50 0.14 1
Bromochloromethane <0.094 ug/L 12/14/23 12:52 74-97-50.50 0.094 1
Bromodichloromethane <0.17 ug/L 12/14/23 12:52 75-27-40.50 0.17 1
Bromoform <0.20 ug/L 12/14/23 12:52 75-25-20.50 0.20 1
Bromomethane <0.22 ug/L 12/14/23 12:52 74-83-95.0 0.22 1
tert-Butyl Alcohol <4.1 ug/L 12/14/23 12:52 75-65-050.0 4.1 1
n-Butylbenzene <0.066 ug/L 12/14/23 12:52 104-51-80.50 0.066 1
sec-Butylbenzene <0.085 ug/L 12/14/23 12:52 135-98-80.50 0.085 1
tert-Butylbenzene <0.086 ug/L 12/14/23 12:52 98-06-60.50 0.086 1
tert-Butyl Formate <0.30 ug/L 12/14/23 12:52 762-75-450.0 0.30 1
Carbon tetrachloride <0.17 ug/L 12/14/23 12:52 56-23-50.50 0.17 1
Chlorobenzene <0.085 ug/L 12/14/23 12:52 108-90-70.50 0.085 1
Chloroethane <0.17 ug/L 12/14/23 12:52 75-00-31.0 0.17 1
Chloroform <0.069 ug/L 12/14/23 12:52 67-66-30.50 0.069 1
Chloromethane <0.18 ug/L 12/14/23 12:52 74-87-31.0 0.18 1
2-Chlorotoluene <0.13 ug/L 12/14/23 12:52 95-49-80.50 0.13 1
4-Chlorotoluene <0.096 ug/L 12/14/23 12:52 106-43-40.50 0.096 1
1,2-Dibromo-3-chloropropane <0.18 ug/L 12/14/23 12:52 96-12-81.0 0.18 1
Dibromochloromethane <0.15 ug/L 12/14/23 12:52 124-48-10.50 0.15 1
1,2-Dibromoethane (EDB)<0.15 ug/L 12/14/23 12:52 106-93-40.50 0.15 1
Dibromomethane <0.19 ug/L 12/14/23 12:52 74-95-30.50 0.19 1
1,2-Dichlorobenzene <0.094 ug/L 12/14/23 12:52 95-50-10.50 0.094 1
1,3-Dichlorobenzene <0.098 ug/L 12/14/23 12:52 541-73-10.50 0.098 1
1,4-Dichlorobenzene <0.090 ug/L 12/14/23 12:52 106-46-70.50 0.090 1
Dichlorodifluoromethane <0.12 ug/L 12/14/23 12:52 75-71-80.50 0.12 1
1,1-Dichloroethane <0.056 ug/L 12/14/23 12:52 75-34-30.50 0.056 1
1,2-Dichloroethane <0.11 ug/L 12/14/23 12:52 107-06-20.50 0.11 1
1,1-Dichloroethene <0.079 ug/L 12/14/23 12:52 75-35-40.50 0.079 1
cis-1,2-Dichloroethene <0.11 ug/L 12/14/23 12:52 156-59-20.50 0.11 1
trans-1,2-Dichloroethene <0.10 ug/L 12/14/23 12:52 156-60-50.50 0.10 1
1,2-Dichloropropane <0.14 ug/L 12/14/23 12:52 78-87-50.50 0.14 1
1,3-Dichloropropane <0.085 ug/L 12/14/23 12:52 142-28-90.50 0.085 1
2,2-Dichloropropane <0.12 ug/L 12/14/23 12:52 594-20-70.50 0.12 1
1,1-Dichloropropene <0.066 ug/L 12/14/23 12:52 563-58-60.50 0.066 1
cis-1,3-Dichloropropene <0.090 ug/L 12/14/23 12:52 10061-01-50.50 0.090 1
trans-1,3-Dichloropropene <0.13 ug/L 12/14/23 12:52 10061-02-60.50 0.13 1
Diisopropyl ether <0.072 ug/L 12/14/23 12:52 108-20-30.50 0.072 1
Ethanol <5.0 ug/L 12/14/23 12:52 64-17-52005.0 1
Ethylbenzene <0.081 ug/L 12/14/23 12:52 100-41-40.50 0.081 1
Ethyl-tert-butyl ether <0.11 ug/L 12/14/23 12:52 637-92-310.0 0.11 1
Hexachloro-1,3-butadiene <0.35 ug/L 12/14/23 12:52 87-68-32.0 0.35 1
Isopropylbenzene (Cumene)<0.11 ug/L 12/14/23 12:52 98-82-80.50 0.11 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 44
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Sample:MW-4 Lab ID:92702751003 Collected:12/08/23 10:50 Received:12/08/23 12:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <1.9 ug/L 12/14/23 12:52 75-09-22.0 1.9 1
Methyl-tert-butyl ether <0.053 ug/L 12/14/23 12:52 1634-04-40.50 0.053 1
Naphthalene <0.10 ug/L 12/14/23 12:52 91-20-32.0 0.10 1
n-Propylbenzene <0.10 ug/L 12/14/23 12:52 103-65-10.50 0.10 1
Styrene <0.14 ug/L 12/14/23 12:52 100-42-50.50 0.14 1
1,1,1,2-Tetrachloroethane <0.091 ug/L 12/14/23 12:52 630-20-60.50 0.091 1
1,1,2,2-Tetrachloroethane <0.074 ug/L 12/14/23 12:52 79-34-50.50 0.074 1
Tetrachloroethene <0.086 ug/L 12/14/23 12:52 127-18-40.50 0.086 1
Toluene <0.090 ug/L 12/14/23 12:52 108-88-30.50 0.090 1
1,2,3-Trichlorobenzene <0.12 ug/L 12/14/23 12:52 87-61-62.0 0.12 1
1,2,4-Trichlorobenzene <0.16 ug/L 12/14/23 12:52 120-82-12.0 0.16 1
1,1,1-Trichloroethane <0.11 ug/L 12/14/23 12:52 71-55-60.50 0.11 1
1,1,2-Trichloroethane <0.096 ug/L 12/14/23 12:52 79-00-50.50 0.096 1
Trichloroethene <0.17 ug/L 12/14/23 12:52 79-01-60.50 0.17 1
Trichlorofluoromethane <0.14 ug/L 12/14/23 12:52 75-69-41.0 0.14 1
1,2,3-Trichloropropane <0.17 ug/L 12/14/23 12:52 96-18-40.50 0.17 1
1,2,4-Trimethylbenzene <0.031 ug/L 12/14/23 12:52 95-63-60.50 0.031 1
1,3,5-Trimethylbenzene <0.071 ug/L 12/14/23 12:52 108-67-80.50 0.071 1
Vinyl chloride <0.15 ug/L 12/14/23 12:52 75-01-41.0 0.15 1
m&p-Xylene <0.094 ug/L 12/14/23 12:52 179601-23-11.0 0.094 1
o-Xylene <0.14 ug/L 12/14/23 12:52 95-47-60.50 0.14 1
Surrogates
1,2-Dichloroethane-d4 (S)116 %12/14/23 12:52 17060-07-070-130 1
4-Bromofluorobenzene (S)101 %12/14/23 12:52 460-00-470-130 1
Toluene-d8 (S)100 %12/14/23 12:52 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 44
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Sample:MW-6 Lab ID:92702751004 Collected:12/08/23 09:35 Received:12/08/23 12:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol 161 ug/L 12/14/23 13:46 75-85-41007.4 1
tert-Amylmethyl ether 2.7J ug/L 12/14/23 13:46 994-05-810.0 0.12 1
Benzene 7.8 ug/L 12/14/23 13:46 71-43-20.50 0.079 1
Bromobenzene <0.14 ug/L 12/14/23 13:46 108-86-10.50 0.14 1
Bromochloromethane <0.094 ug/L 12/14/23 13:46 74-97-50.50 0.094 1
Bromodichloromethane <0.17 ug/L 12/14/23 13:46 75-27-40.50 0.17 1
Bromoform <0.20 ug/L 12/14/23 13:46 75-25-20.50 0.20 1
Bromomethane <0.22 ug/L 12/14/23 13:46 74-83-95.0 0.22 1
tert-Butyl Alcohol 136 ug/L 12/14/23 13:46 75-65-050.0 4.1 1
n-Butylbenzene <0.066 ug/L 12/14/23 13:46 104-51-80.50 0.066 1
sec-Butylbenzene 0.67 ug/L 12/14/23 13:46 135-98-80.50 0.085 1
tert-Butylbenzene <0.086 ug/L 12/14/23 13:46 98-06-60.50 0.086 1
tert-Butyl Formate <0.30 ug/L 12/14/23 13:46 762-75-450.0 0.30 1
Carbon tetrachloride <0.17 ug/L 12/14/23 13:46 56-23-50.50 0.17 1
Chlorobenzene <0.085 ug/L 12/14/23 13:46 108-90-70.50 0.085 1
Chloroethane <0.17 ug/L 12/14/23 13:46 75-00-31.0 0.17 1
Chloroform <0.069 ug/L 12/14/23 13:46 67-66-30.50 0.069 1
Chloromethane <0.18 ug/L 12/14/23 13:46 74-87-31.0 0.18 1
2-Chlorotoluene <0.13 ug/L 12/14/23 13:46 95-49-80.50 0.13 1
4-Chlorotoluene <0.096 ug/L 12/14/23 13:46 106-43-40.50 0.096 1
1,2-Dibromo-3-chloropropane <0.18 ug/L 12/14/23 13:46 96-12-81.0 0.18 1
Dibromochloromethane <0.15 ug/L 12/14/23 13:46 124-48-10.50 0.15 1
1,2-Dibromoethane (EDB)<0.15 ug/L 12/14/23 13:46 106-93-40.50 0.15 1
Dibromomethane <0.19 ug/L 12/14/23 13:46 74-95-30.50 0.19 1
1,2-Dichlorobenzene <0.094 ug/L 12/14/23 13:46 95-50-10.50 0.094 1
1,3-Dichlorobenzene <0.098 ug/L 12/14/23 13:46 541-73-10.50 0.098 1
1,4-Dichlorobenzene <0.090 ug/L 12/14/23 13:46 106-46-70.50 0.090 1
Dichlorodifluoromethane <0.12 ug/L 12/14/23 13:46 75-71-80.50 0.12 1
1,1-Dichloroethane <0.056 ug/L 12/14/23 13:46 75-34-30.50 0.056 1
1,2-Dichloroethane <0.11 ug/L 12/14/23 13:46 107-06-20.50 0.11 1
1,1-Dichloroethene <0.079 ug/L 12/14/23 13:46 75-35-40.50 0.079 1
cis-1,2-Dichloroethene 1.1 ug/L 12/14/23 13:46 156-59-20.50 0.11 1
trans-1,2-Dichloroethene <0.10 ug/L 12/14/23 13:46 156-60-50.50 0.10 1
1,2-Dichloropropane <0.14 ug/L 12/14/23 13:46 78-87-50.50 0.14 1
1,3-Dichloropropane <0.085 ug/L 12/14/23 13:46 142-28-90.50 0.085 1
2,2-Dichloropropane <0.12 ug/L 12/14/23 13:46 594-20-70.50 0.12 1
1,1-Dichloropropene <0.066 ug/L 12/14/23 13:46 563-58-60.50 0.066 1
cis-1,3-Dichloropropene <0.090 ug/L 12/14/23 13:46 10061-01-50.50 0.090 1
trans-1,3-Dichloropropene <0.13 ug/L 12/14/23 13:46 10061-02-60.50 0.13 1
Diisopropyl ether 23.4 ug/L 12/14/23 13:46 108-20-30.50 0.072 1
Ethanol <5.0 ug/L 12/14/23 13:46 64-17-52005.0 1
Ethylbenzene 2.7 ug/L 12/14/23 13:46 100-41-40.50 0.081 1
Ethyl-tert-butyl ether <0.11 ug/L 12/14/23 13:46 637-92-310.0 0.11 1
Hexachloro-1,3-butadiene <0.35 ug/L 12/14/23 13:46 87-68-32.0 0.35 1
Isopropylbenzene (Cumene)2.3 ug/L 12/14/23 13:46 98-82-80.50 0.11 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 44
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Sample:MW-6 Lab ID:92702751004 Collected:12/08/23 09:35 Received:12/08/23 12:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <1.9 ug/L 12/14/23 13:46 75-09-22.0 1.9 1
Methyl-tert-butyl ether 11.0 ug/L 12/14/23 13:46 1634-04-40.50 0.053 1
Naphthalene 2.8 ug/L 12/14/23 13:46 91-20-32.0 0.10 1
n-Propylbenzene 1.5 ug/L 12/14/23 13:46 103-65-10.50 0.10 1
Styrene <0.14 ug/L 12/14/23 13:46 100-42-50.50 0.14 1
1,1,1,2-Tetrachloroethane <0.091 ug/L 12/14/23 13:46 630-20-60.50 0.091 1
1,1,2,2-Tetrachloroethane <0.074 ug/L 12/14/23 13:46 79-34-50.50 0.074 1
Tetrachloroethene 2.0 ug/L 12/14/23 13:46 127-18-40.50 0.086 1
Toluene <0.090 ug/L 12/14/23 13:46 108-88-30.50 0.090 1
1,2,3-Trichlorobenzene <0.12 ug/L 12/14/23 13:46 87-61-62.0 0.12 1
1,2,4-Trichlorobenzene <0.16 ug/L 12/14/23 13:46 120-82-12.0 0.16 1
1,1,1-Trichloroethane <0.11 ug/L 12/14/23 13:46 71-55-60.50 0.11 1
1,1,2-Trichloroethane <0.096 ug/L 12/14/23 13:46 79-00-50.50 0.096 1
Trichloroethene 1.7 ug/L 12/14/23 13:46 79-01-60.50 0.17 1
Trichlorofluoromethane <0.14 ug/L 12/14/23 13:46 75-69-41.0 0.14 1
1,2,3-Trichloropropane <0.17 ug/L 12/14/23 13:46 96-18-40.50 0.17 1
1,2,4-Trimethylbenzene 1.9 ug/L 12/14/23 13:46 95-63-60.50 0.031 1
1,3,5-Trimethylbenzene <0.071 ug/L 12/14/23 13:46 108-67-80.50 0.071 1
Vinyl chloride <0.15 ug/L 12/14/23 13:46 75-01-41.0 0.15 1
m&p-Xylene 0.57J ug/L 12/14/23 13:46 179601-23-11.0 0.094 1
o-Xylene 0.21J ug/L 12/14/23 13:46 95-47-60.50 0.14 1
Surrogates
1,2-Dichloroethane-d4 (S)116 %12/14/23 13:46 17060-07-070-130 1
4-Bromofluorobenzene (S)101 %12/14/23 13:46 460-00-470-130 1
Toluene-d8 (S)101 %12/14/23 13:46 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 44
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Sample:MW-12 Lab ID:92702751005 Collected:12/07/23 13:10 Received:12/08/23 12:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol 1170 ug/L 12/14/23 15:36 75-85-425018.6 2.5
tert-Amylmethyl ether 18.9J ug/L 12/14/23 15:36 994-05-825.0 0.31 2.5
Benzene 186 ug/L 12/14/23 15:36 71-43-21.2 0.20 2.5
Bromobenzene <0.34 ug/L 12/14/23 15:36 108-86-11.2 0.34 2.5
Bromochloromethane <0.24 ug/L 12/14/23 15:36 74-97-51.2 0.24 2.5
Bromodichloromethane <0.42 ug/L 12/14/23 15:36 75-27-41.2 0.42 2.5
Bromoform <0.49 ug/L 12/14/23 15:36 75-25-21.2 0.49 2.5
Bromomethane <0.56 ug/L 12/14/23 15:36 74-83-912.5 0.56 2.5
tert-Butyl Alcohol 115J ug/L 12/14/23 15:36 75-65-012510.2 2.5
n-Butylbenzene <0.17 ug/L 12/14/23 15:36 104-51-81.2 0.17 2.5
sec-Butylbenzene <0.21 ug/L 12/14/23 15:36 135-98-81.2 0.21 2.5
tert-Butylbenzene <0.21 ug/L 12/14/23 15:36 98-06-61.2 0.21 2.5
tert-Butyl Formate <0.75 ug/L 12/14/23 15:36 762-75-41250.75 2.5
Carbon tetrachloride <0.42 ug/L 12/14/23 15:36 56-23-51.2 0.42 2.5
Chlorobenzene <0.21 ug/L 12/14/23 15:36 108-90-71.2 0.21 2.5
Chloroethane <0.43 ug/L 12/14/23 15:36 75-00-32.5 0.43 2.5
Chloroform <0.17 ug/L 12/14/23 15:36 67-66-31.2 0.17 2.5
Chloromethane <0.44 ug/L 12/14/23 15:36 74-87-32.5 0.44 2.5
2-Chlorotoluene <0.32 ug/L 12/14/23 15:36 95-49-81.2 0.32 2.5
4-Chlorotoluene <0.24 ug/L 12/14/23 15:36 106-43-41.2 0.24 2.5
1,2-Dibromo-3-chloropropane <0.45 ug/L 12/14/23 15:36 96-12-82.5 0.45 2.5
Dibromochloromethane <0.37 ug/L 12/14/23 15:36 124-48-11.2 0.37 2.5
1,2-Dibromoethane (EDB)<0.37 ug/L 12/14/23 15:36 106-93-41.2 0.37 2.5
Dibromomethane <0.47 ug/L 12/14/23 15:36 74-95-31.2 0.47 2.5
1,2-Dichlorobenzene <0.24 ug/L 12/14/23 15:36 95-50-11.2 0.24 2.5
1,3-Dichlorobenzene <0.24 ug/L 12/14/23 15:36 541-73-11.2 0.24 2.5
1,4-Dichlorobenzene <0.22 ug/L 12/14/23 15:36 106-46-71.2 0.22 2.5
Dichlorodifluoromethane <0.31 ug/L 12/14/23 15:36 75-71-81.2 0.31 2.5
1,1-Dichloroethane <0.14 ug/L 12/14/23 15:36 75-34-31.2 0.14 2.5
1,2-Dichloroethane <0.26 ug/L 12/14/23 15:36 107-06-21.2 0.26 2.5
1,1-Dichloroethene <0.20 ug/L 12/14/23 15:36 75-35-41.2 0.20 2.5
cis-1,2-Dichloroethene 168 ug/L 12/14/23 15:36 156-59-21.2 0.28 2.5
trans-1,2-Dichloroethene 4.0 ug/L 12/14/23 15:36 156-60-51.2 0.25 2.5
1,2-Dichloropropane <0.34 ug/L 12/14/23 15:36 78-87-51.2 0.34 2.5
1,3-Dichloropropane <0.21 ug/L 12/14/23 15:36 142-28-91.2 0.21 2.5
2,2-Dichloropropane <0.30 ug/L 12/14/23 15:36 594-20-71.2 0.30 2.5
1,1-Dichloropropene <0.16 ug/L 12/14/23 15:36 563-58-61.2 0.16 2.5
cis-1,3-Dichloropropene <0.22 ug/L 12/14/23 15:36 10061-01-51.2 0.22 2.5
trans-1,3-Dichloropropene <0.33 ug/L 12/14/23 15:36 10061-02-61.2 0.33 2.5
Diisopropyl ether 141 ug/L 12/14/23 15:36 108-20-31.2 0.18 2.5
Ethanol <12.6 ug/L 12/14/23 15:36 64-17-550012.6 2.5
Ethylbenzene 156 ug/L 12/14/23 15:36 100-41-41.2 0.20 2.5
Ethyl-tert-butyl ether <0.28 ug/L 12/14/23 15:36 637-92-325.0 0.28 2.5
Hexachloro-1,3-butadiene <0.88 ug/L 12/14/23 15:36 87-68-35.0 0.88 2.5
Isopropylbenzene (Cumene)95.7 ug/L 12/14/23 15:36 98-82-81.2 0.26 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 44
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Sample:MW-12 Lab ID:92702751005 Collected:12/07/23 13:10 Received:12/08/23 12:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <4.7 ug/L 12/14/23 15:36 75-09-25.0 4.7 2.5
Methyl-tert-butyl ether 67.5 ug/L 12/14/23 15:36 1634-04-41.2 0.13 2.5
Naphthalene 85.8 ug/L 12/14/23 15:36 91-20-35.0 0.25 2.5
n-Propylbenzene 54.1 ug/L 12/14/23 15:36 103-65-11.2 0.26 2.5
Styrene 1.1J ug/L 12/14/23 15:36 100-42-51.2 0.34 2.5
1,1,1,2-Tetrachloroethane <0.23 ug/L 12/14/23 15:36 630-20-61.2 0.23 2.5
1,1,2,2-Tetrachloroethane <0.18 ug/L 12/14/23 15:36 79-34-51.2 0.18 2.5
Tetrachloroethene 7.5 ug/L 12/14/23 15:36 127-18-41.2 0.21 2.5
Toluene 47.8 ug/L 12/14/23 15:36 108-88-31.2 0.22 2.5
1,2,3-Trichlorobenzene <0.30 ug/L 12/14/23 15:36 87-61-65.0 0.30 2.5
1,2,4-Trichlorobenzene <0.39 ug/L 12/14/23 15:36 120-82-15.0 0.39 2.5
1,1,1-Trichloroethane <0.27 ug/L 12/14/23 15:36 71-55-61.2 0.27 2.5
1,1,2-Trichloroethane <0.24 ug/L 12/14/23 15:36 79-00-51.2 0.24 2.5
Trichloroethene 22.7 ug/L 12/14/23 15:36 79-01-61.2 0.43 2.5
Trichlorofluoromethane <0.36 ug/L 12/14/23 15:36 75-69-42.5 0.36 2.5
1,2,3-Trichloropropane <0.43 ug/L 12/14/23 15:36 96-18-41.2 0.43 2.5
1,2,4-Trimethylbenzene 399 ug/L 12/14/23 15:36 95-63-61.2 0.077 2.5
1,3,5-Trimethylbenzene 112 ug/L 12/14/23 15:36 108-67-81.2 0.18 2.5
Vinyl chloride <0.37 ug/L 12/14/23 15:36 75-01-42.5 0.37 2.5
m&p-Xylene 184 ug/L 12/14/23 15:36 179601-23-12.5 0.23 2.5
o-Xylene 103 ug/L 12/14/23 15:36 95-47-61.2 0.36 2.5
Surrogates
1,2-Dichloroethane-d4 (S)118 %12/14/23 15:36 17060-07-070-130 2.5
4-Bromofluorobenzene (S)103 %12/14/23 15:36 460-00-470-130 2.5
Toluene-d8 (S)102 %12/14/23 15:36 2037-26-570-130 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 44
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Sample:MW-14 Lab ID:92702751006 Collected:12/07/23 11:55 Received:12/08/23 12:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <14.9 ug/L 12/14/23 14:59 75-85-420014.9 2
tert-Amylmethyl ether <0.25 ug/L 12/14/23 14:59 994-05-820.0 0.25 2
Benzene 2.5 ug/L 12/14/23 14:59 71-43-21.0 0.16 2
Bromobenzene <0.27 ug/L 12/14/23 14:59 108-86-11.0 0.27 2
Bromochloromethane <0.19 ug/L 12/14/23 14:59 74-97-51.0 0.19 2
Bromodichloromethane <0.34 ug/L 12/14/23 14:59 75-27-41.0 0.34 2
Bromoform <0.39 ug/L 12/14/23 14:59 75-25-21.0 0.39 2
Bromomethane <0.44 ug/L 12/14/23 14:59 74-83-910.0 0.44 2
tert-Butyl Alcohol <8.2 ug/L 12/14/23 14:59 75-65-01008.2 2
n-Butylbenzene <0.13 ug/L 12/14/23 14:59 104-51-81.0 0.13 2
sec-Butylbenzene 0.88J ug/L 12/14/23 14:59 135-98-81.0 0.17 2
tert-Butylbenzene <0.17 ug/L 12/14/23 14:59 98-06-61.0 0.17 2
tert-Butyl Formate <0.60 ug/L 12/14/23 14:59 762-75-41000.60 2
Carbon tetrachloride <0.34 ug/L 12/14/23 14:59 56-23-51.0 0.34 2
Chlorobenzene <0.17 ug/L 12/14/23 14:59 108-90-71.0 0.17 2
Chloroethane <0.35 ug/L 12/14/23 14:59 75-00-32.0 0.35 2
Chloroform <0.14 ug/L 12/14/23 14:59 67-66-31.0 0.14 2
Chloromethane <0.35 ug/L 12/14/23 14:59 74-87-32.0 0.35 2
2-Chlorotoluene <0.26 ug/L 12/14/23 14:59 95-49-81.0 0.26 2
4-Chlorotoluene <0.19 ug/L 12/14/23 14:59 106-43-41.0 0.19 2
1,2-Dibromo-3-chloropropane <0.36 ug/L 12/14/23 14:59 96-12-82.0 0.36 2
Dibromochloromethane <0.30 ug/L 12/14/23 14:59 124-48-11.0 0.30 2
1,2-Dibromoethane (EDB)<0.29 ug/L 12/14/23 14:59 106-93-41.0 0.29 2
Dibromomethane <0.37 ug/L 12/14/23 14:59 74-95-31.0 0.37 2
1,2-Dichlorobenzene <0.19 ug/L 12/14/23 14:59 95-50-11.0 0.19 2
1,3-Dichlorobenzene <0.20 ug/L 12/14/23 14:59 541-73-11.0 0.20 2
1,4-Dichlorobenzene <0.18 ug/L 12/14/23 14:59 106-46-71.0 0.18 2
Dichlorodifluoromethane <0.25 ug/L 12/14/23 14:59 75-71-81.0 0.25 2
1,1-Dichloroethane <0.11 ug/L 12/14/23 14:59 75-34-31.0 0.11 2
1,2-Dichloroethane <0.21 ug/L 12/14/23 14:59 107-06-21.0 0.21 2
1,1-Dichloroethene <0.16 ug/L 12/14/23 14:59 75-35-41.0 0.16 2
cis-1,2-Dichloroethene 31.4 ug/L 12/14/23 14:59 156-59-21.0 0.22 2
trans-1,2-Dichloroethene <0.20 ug/L 12/14/23 14:59 156-60-51.0 0.20 2
1,2-Dichloropropane <0.27 ug/L 12/14/23 14:59 78-87-51.0 0.27 2
1,3-Dichloropropane <0.17 ug/L 12/14/23 14:59 142-28-91.0 0.17 2
2,2-Dichloropropane <0.24 ug/L 12/14/23 14:59 594-20-71.0 0.24 2
1,1-Dichloropropene <0.13 ug/L 12/14/23 14:59 563-58-61.0 0.13 2
cis-1,3-Dichloropropene <0.18 ug/L 12/14/23 14:59 10061-01-51.0 0.18 2
trans-1,3-Dichloropropene <0.26 ug/L 12/14/23 14:59 10061-02-61.0 0.26 2
Diisopropyl ether 0.94J ug/L 12/14/23 14:59 108-20-31.0 0.14 2
Ethanol <10.1 ug/L 12/14/23 14:59 64-17-540010.1 2
Ethylbenzene <0.16 ug/L 12/14/23 14:59 100-41-41.0 0.16 2
Ethyl-tert-butyl ether <0.22 ug/L 12/14/23 14:59 637-92-320.0 0.22 2
Hexachloro-1,3-butadiene <0.70 ug/L 12/14/23 14:59 87-68-34.0 0.70 2
Isopropylbenzene (Cumene)1.2 ug/L 12/14/23 14:59 98-82-81.0 0.21 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 44
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Sample:MW-14 Lab ID:92702751006 Collected:12/07/23 11:55 Received:12/08/23 12:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <3.8 ug/L 12/14/23 14:59 75-09-24.0 3.8 2
Methyl-tert-butyl ether <0.11 ug/L 12/14/23 14:59 1634-04-41.0 0.11 2
Naphthalene <0.20 ug/L 12/14/23 14:59 91-20-34.0 0.20 2
n-Propylbenzene <0.21 ug/L 12/14/23 14:59 103-65-11.0 0.21 2
Styrene <0.27 ug/L 12/14/23 14:59 100-42-51.0 0.27 2
1,1,1,2-Tetrachloroethane <0.18 ug/L 12/14/23 14:59 630-20-61.0 0.18 2
1,1,2,2-Tetrachloroethane <0.15 ug/L 12/14/23 14:59 79-34-51.0 0.15 2
Tetrachloroethene 206 ug/L 12/14/23 14:59 127-18-41.0 0.17 2
Toluene <0.18 ug/L 12/14/23 14:59 108-88-31.0 0.18 2
1,2,3-Trichlorobenzene <0.24 ug/L 12/14/23 14:59 87-61-64.0 0.24 2
1,2,4-Trichlorobenzene <0.31 ug/L 12/14/23 14:59 120-82-14.0 0.31 2
1,1,1-Trichloroethane <0.21 ug/L 12/14/23 14:59 71-55-61.0 0.21 2
1,1,2-Trichloroethane <0.19 ug/L 12/14/23 14:59 79-00-51.0 0.19 2
Trichloroethene 37.1 ug/L 12/14/23 14:59 79-01-61.0 0.34 2
Trichlorofluoromethane <0.29 ug/L 12/14/23 14:59 75-69-42.0 0.29 2
1,2,3-Trichloropropane <0.35 ug/L 12/14/23 14:59 96-18-41.0 0.35 2
1,2,4-Trimethylbenzene <0.061 ug/L 12/14/23 14:59 95-63-61.0 0.061 2
1,3,5-Trimethylbenzene <0.14 ug/L 12/14/23 14:59 108-67-81.0 0.14 2
Vinyl chloride <0.30 ug/L 12/14/23 14:59 75-01-42.0 0.30 2
m&p-Xylene <0.19 ug/L 12/14/23 14:59 179601-23-12.0 0.19 2
o-Xylene <0.29 ug/L 12/14/23 14:59 95-47-61.0 0.29 2
Surrogates
1,2-Dichloroethane-d4 (S)117 %12/14/23 14:59 17060-07-070-130 2
4-Bromofluorobenzene (S)101 %12/14/23 14:59 460-00-470-130 2
Toluene-d8 (S)100 %12/14/23 14:59 2037-26-570-130 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 44
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Sample:TW-1 Lab ID:92702751007 Collected:12/08/23 10:30 Received:12/08/23 12:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol 966 ug/L 12/14/23 15:17 75-85-420014.9 2
tert-Amylmethyl ether 7.7J ug/L 12/14/23 15:17 994-05-820.0 0.25 2
Benzene 6.0 ug/L 12/14/23 15:17 71-43-21.0 0.16 2
Bromobenzene <0.27 ug/L 12/14/23 15:17 108-86-11.0 0.27 2
Bromochloromethane <0.19 ug/L 12/14/23 15:17 74-97-51.0 0.19 2
Bromodichloromethane <0.34 ug/L 12/14/23 15:17 75-27-41.0 0.34 2
Bromoform <0.39 ug/L 12/14/23 15:17 75-25-21.0 0.39 2
Bromomethane <0.44 ug/L 12/14/23 15:17 74-83-910.0 0.44 2
tert-Butyl Alcohol 548 ug/L 12/14/23 15:17 75-65-01008.2 2
n-Butylbenzene <0.13 ug/L 12/14/23 15:17 104-51-81.0 0.13 2
sec-Butylbenzene <0.17 ug/L 12/14/23 15:17 135-98-81.0 0.17 2
tert-Butylbenzene <0.17 ug/L 12/14/23 15:17 98-06-61.0 0.17 2
tert-Butyl Formate <0.60 ug/L 12/14/23 15:17 762-75-41000.60 2
Carbon tetrachloride <0.34 ug/L 12/14/23 15:17 56-23-51.0 0.34 2
Chlorobenzene <0.17 ug/L 12/14/23 15:17 108-90-71.0 0.17 2
Chloroethane <0.35 ug/L 12/14/23 15:17 75-00-32.0 0.35 2
Chloroform <0.14 ug/L 12/14/23 15:17 67-66-31.0 0.14 2
Chloromethane <0.35 ug/L 12/14/23 15:17 74-87-32.0 0.35 2
2-Chlorotoluene <0.26 ug/L 12/14/23 15:17 95-49-81.0 0.26 2
4-Chlorotoluene <0.19 ug/L 12/14/23 15:17 106-43-41.0 0.19 2
1,2-Dibromo-3-chloropropane <0.36 ug/L 12/14/23 15:17 96-12-82.0 0.36 2
Dibromochloromethane <0.30 ug/L 12/14/23 15:17 124-48-11.0 0.30 2
1,2-Dibromoethane (EDB)<0.29 ug/L 12/14/23 15:17 106-93-41.0 0.29 2
Dibromomethane <0.37 ug/L 12/14/23 15:17 74-95-31.0 0.37 2
1,2-Dichlorobenzene <0.19 ug/L 12/14/23 15:17 95-50-11.0 0.19 2
1,3-Dichlorobenzene <0.20 ug/L 12/14/23 15:17 541-73-11.0 0.20 2
1,4-Dichlorobenzene <0.18 ug/L 12/14/23 15:17 106-46-71.0 0.18 2
Dichlorodifluoromethane <0.25 ug/L 12/14/23 15:17 75-71-81.0 0.25 2
1,1-Dichloroethane <0.11 ug/L 12/14/23 15:17 75-34-31.0 0.11 2
1,2-Dichloroethane <0.21 ug/L 12/14/23 15:17 107-06-21.0 0.21 2
1,1-Dichloroethene 4.5 ug/L 12/14/23 15:17 75-35-41.0 0.16 2
cis-1,2-Dichloroethene 32.6 ug/L 12/14/23 15:17 156-59-21.0 0.22 2
trans-1,2-Dichloroethene 7.8 ug/L 12/14/23 15:17 156-60-51.0 0.20 2
1,2-Dichloropropane <0.27 ug/L 12/14/23 15:17 78-87-51.0 0.27 2
1,3-Dichloropropane <0.17 ug/L 12/14/23 15:17 142-28-91.0 0.17 2
2,2-Dichloropropane <0.24 ug/L 12/14/23 15:17 594-20-71.0 0.24 2
1,1-Dichloropropene <0.13 ug/L 12/14/23 15:17 563-58-61.0 0.13 2
cis-1,3-Dichloropropene <0.18 ug/L 12/14/23 15:17 10061-01-51.0 0.18 2
trans-1,3-Dichloropropene <0.26 ug/L 12/14/23 15:17 10061-02-61.0 0.26 2
Diisopropyl ether 50.5 ug/L 12/14/23 15:17 108-20-31.0 0.14 2
Ethanol <10.1 ug/L 12/14/23 15:17 64-17-540010.1 2
Ethylbenzene 2.5 ug/L 12/14/23 15:17 100-41-41.0 0.16 2
Ethyl-tert-butyl ether <0.22 ug/L 12/14/23 15:17 637-92-320.0 0.22 2
Hexachloro-1,3-butadiene <0.70 ug/L 12/14/23 15:17 87-68-34.0 0.70 2
Isopropylbenzene (Cumene)<0.21 ug/L 12/14/23 15:17 98-82-81.0 0.21 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 44
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Sample:TW-1 Lab ID:92702751007 Collected:12/08/23 10:30 Received:12/08/23 12:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <3.8 ug/L 12/14/23 15:17 75-09-24.0 3.8 2
Methyl-tert-butyl ether 33.5 ug/L 12/14/23 15:17 1634-04-41.0 0.11 2
Naphthalene <0.20 ug/L 12/14/23 15:17 91-20-34.0 0.20 2
n-Propylbenzene <0.21 ug/L 12/14/23 15:17 103-65-11.0 0.21 2
Styrene <0.27 ug/L 12/14/23 15:17 100-42-51.0 0.27 2
1,1,1,2-Tetrachloroethane <0.18 ug/L 12/14/23 15:17 630-20-61.0 0.18 2
1,1,2,2-Tetrachloroethane <0.15 ug/L 12/14/23 15:17 79-34-51.0 0.15 2
Tetrachloroethene 257 ug/L 12/14/23 15:17 127-18-41.0 0.17 2
Toluene <0.18 ug/L 12/14/23 15:17 108-88-31.0 0.18 2
1,2,3-Trichlorobenzene <0.24 ug/L 12/14/23 15:17 87-61-64.0 0.24 2
1,2,4-Trichlorobenzene <0.31 ug/L 12/14/23 15:17 120-82-14.0 0.31 2
1,1,1-Trichloroethane <0.21 ug/L 12/14/23 15:17 71-55-61.0 0.21 2
1,1,2-Trichloroethane <0.19 ug/L 12/14/23 15:17 79-00-51.0 0.19 2
Trichloroethene 79.3 ug/L 12/14/23 15:17 79-01-61.0 0.34 2
Trichlorofluoromethane <0.29 ug/L 12/14/23 15:17 75-69-42.0 0.29 2
1,2,3-Trichloropropane <0.35 ug/L 12/14/23 15:17 96-18-41.0 0.35 2
1,2,4-Trimethylbenzene <0.061 ug/L 12/14/23 15:17 95-63-61.0 0.061 2
1,3,5-Trimethylbenzene <0.14 ug/L 12/14/23 15:17 108-67-81.0 0.14 2
Vinyl chloride 11.4 ug/L 12/14/23 15:17 75-01-42.0 0.30 2
m&p-Xylene <0.19 ug/L 12/14/23 15:17 179601-23-12.0 0.19 2
o-Xylene <0.29 ug/L 12/14/23 15:17 95-47-61.0 0.29 2
Surrogates
1,2-Dichloroethane-d4 (S)121 %12/14/23 15:17 17060-07-070-130 2
4-Bromofluorobenzene (S)101 %12/14/23 15:17 460-00-470-130 2
Toluene-d8 (S)99 %12/14/23 15:17 2037-26-570-130 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 44
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Sample:TW-2 Lab ID:92702751008 Collected:12/08/23 11:45 Received:12/08/23 12:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <18.6 ug/L 12/15/23 14:04 75-85-425018.6 2.5
tert-Amylmethyl ether 5.6J ug/L 12/15/23 14:04 994-05-825.0 0.31 2.5
Benzene 4.6 ug/L 12/15/23 14:04 71-43-21.2 0.20 2.5
Bromobenzene <0.34 ug/L 12/15/23 14:04 108-86-11.2 0.34 2.5
Bromochloromethane <0.24 ug/L 12/15/23 14:04 74-97-51.2 0.24 2.5
Bromodichloromethane <0.42 ug/L 12/15/23 14:04 75-27-41.2 0.42 2.5
Bromoform <0.49 ug/L 12/15/23 14:04 75-25-21.2 0.49 2.5
Bromomethane <0.56 ug/L 12/15/23 14:04 74-83-912.5 0.56 2.5
tert-Butyl Alcohol 29.5J ug/L 12/15/23 14:04 75-65-012510.2 2.5
n-Butylbenzene <0.17 ug/L 12/15/23 14:04 104-51-81.2 0.17 2.5
sec-Butylbenzene <0.21 ug/L 12/15/23 14:04 135-98-81.2 0.21 2.5
tert-Butylbenzene <0.21 ug/L 12/15/23 14:04 98-06-61.2 0.21 2.5
tert-Butyl Formate <0.75 ug/L 12/15/23 14:04 762-75-41250.75 2.5
Carbon tetrachloride <0.42 ug/L 12/15/23 14:04 56-23-51.2 0.42 2.5
Chlorobenzene <0.21 ug/L 12/15/23 14:04 108-90-71.2 0.21 2.5
Chloroethane <0.43 ug/L 12/15/23 14:04 75-00-32.5 0.43 2.5
Chloroform <0.17 ug/L 12/15/23 14:04 67-66-31.2 0.17 2.5
Chloromethane <0.44 ug/L 12/15/23 14:04 74-87-32.5 0.44 2.5
2-Chlorotoluene <0.32 ug/L 12/15/23 14:04 95-49-81.2 0.32 2.5
4-Chlorotoluene <0.24 ug/L 12/15/23 14:04 106-43-41.2 0.24 2.5
1,2-Dibromo-3-chloropropane <0.45 ug/L 12/15/23 14:04 96-12-82.5 0.45 2.5
Dibromochloromethane <0.37 ug/L 12/15/23 14:04 124-48-11.2 0.37 2.5
1,2-Dibromoethane (EDB)<0.37 ug/L 12/15/23 14:04 106-93-41.2 0.37 2.5
Dibromomethane <0.47 ug/L 12/15/23 14:04 74-95-31.2 0.47 2.5
1,2-Dichlorobenzene <0.24 ug/L 12/15/23 14:04 95-50-11.2 0.24 2.5
1,3-Dichlorobenzene <0.24 ug/L 12/15/23 14:04 541-73-11.2 0.24 2.5
1,4-Dichlorobenzene <0.22 ug/L 12/15/23 14:04 106-46-71.2 0.22 2.5
Dichlorodifluoromethane <0.31 ug/L 12/15/23 14:04 75-71-81.2 0.31 2.5
1,1-Dichloroethane <0.14 ug/L 12/15/23 14:04 75-34-31.2 0.14 2.5
1,2-Dichloroethane <0.26 ug/L 12/15/23 14:04 107-06-21.2 0.26 2.5
1,1-Dichloroethene <0.20 ug/L 12/15/23 14:04 75-35-41.2 0.20 2.5
cis-1,2-Dichloroethene 11.5 ug/L 12/15/23 14:04 156-59-21.2 0.28 2.5
trans-1,2-Dichloroethene 2.4 ug/L 12/15/23 14:04 156-60-51.2 0.25 2.5
1,2-Dichloropropane <0.34 ug/L 12/15/23 14:04 78-87-51.2 0.34 2.5
1,3-Dichloropropane <0.21 ug/L 12/15/23 14:04 142-28-91.2 0.21 2.5
2,2-Dichloropropane <0.30 ug/L 12/15/23 14:04 594-20-71.2 0.30 2.5
1,1-Dichloropropene <0.16 ug/L 12/15/23 14:04 563-58-61.2 0.16 2.5
cis-1,3-Dichloropropene <0.22 ug/L 12/15/23 14:04 10061-01-51.2 0.22 2.5
trans-1,3-Dichloropropene <0.33 ug/L 12/15/23 14:04 10061-02-61.2 0.33 2.5
Diisopropyl ether 33.8 ug/L 12/15/23 14:04 108-20-31.2 0.18 2.5
Ethanol <12.6 ug/L 12/15/23 14:04 64-17-550012.6 2.5
Ethylbenzene <0.20 ug/L 12/15/23 14:04 100-41-41.2 0.20 2.5
Ethyl-tert-butyl ether <0.28 ug/L 12/15/23 14:04 637-92-325.0 0.28 2.5
Hexachloro-1,3-butadiene <0.88 ug/L 12/15/23 14:04 87-68-35.0 0.88 2.5
Isopropylbenzene (Cumene)<0.26 ug/L 12/15/23 14:04 98-82-81.2 0.26 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 44
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Sample:TW-2 Lab ID:92702751008 Collected:12/08/23 11:45 Received:12/08/23 12:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <4.7 ug/L 12/15/23 14:04 75-09-25.0 4.7 2.5
Methyl-tert-butyl ether 13.6 ug/L 12/15/23 14:04 1634-04-41.2 0.13 2.5
Naphthalene <0.25 ug/L 12/15/23 14:04 91-20-35.0 0.25 2.5
n-Propylbenzene <0.26 ug/L 12/15/23 14:04 103-65-11.2 0.26 2.5
Styrene <0.34 ug/L 12/15/23 14:04 100-42-51.2 0.34 2.5
1,1,1,2-Tetrachloroethane <0.23 ug/L 12/15/23 14:04 630-20-61.2 0.23 2.5
1,1,2,2-Tetrachloroethane <0.18 ug/L 12/15/23 14:04 79-34-51.2 0.18 2.5
Tetrachloroethene 331 ug/L 12/15/23 14:04 127-18-41.2 0.21 2.5
Toluene <0.22 ug/L 12/15/23 14:04 108-88-31.2 0.22 2.5
1,2,3-Trichlorobenzene <0.30 ug/L 12/15/23 14:04 87-61-65.0 0.30 2.5
1,2,4-Trichlorobenzene <0.39 ug/L 12/15/23 14:04 120-82-15.0 0.39 2.5
1,1,1-Trichloroethane <0.27 ug/L 12/15/23 14:04 71-55-61.2 0.27 2.5
1,1,2-Trichloroethane <0.24 ug/L 12/15/23 14:04 79-00-51.2 0.24 2.5
Trichloroethene 27.4 ug/L 12/15/23 14:04 79-01-61.2 0.43 2.5
Trichlorofluoromethane <0.36 ug/L 12/15/23 14:04 75-69-42.5 0.36 2.5
1,2,3-Trichloropropane <0.43 ug/L 12/15/23 14:04 96-18-41.2 0.43 2.5
1,2,4-Trimethylbenzene <0.077 ug/L 12/15/23 14:04 95-63-61.2 0.077 2.5
1,3,5-Trimethylbenzene <0.18 ug/L 12/15/23 14:04 108-67-81.2 0.18 2.5
Vinyl chloride <0.37 ug/L 12/15/23 14:04 75-01-42.5 0.37 2.5
m&p-Xylene <0.23 ug/L 12/15/23 14:04 179601-23-12.5 0.23 2.5
o-Xylene <0.36 ug/L 12/15/23 14:04 95-47-61.2 0.36 2.5
Surrogates
1,2-Dichloroethane-d4 (S)118 %12/15/23 14:04 17060-07-070-130 2.5
4-Bromofluorobenzene (S)101 %12/15/23 14:04 460-00-470-130 2.5
Toluene-d8 (S)99 %12/15/23 14:04 2037-26-570-130 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 44
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Sample:AS-1 Lab ID:92702751009 Collected:12/07/23 13:10 Received:12/08/23 12:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <372 ug/L 12/14/23 17:24 75-85-4500037250
tert-Amylmethyl ether <6.2 ug/L 12/14/23 17:24 994-05-85006.2 50
Benzene 5080 ug/L 12/14/23 17:24 71-43-225.0 3.9 50
Bromobenzene <6.8 ug/L 12/14/23 17:24 108-86-125.0 6.8 50
Bromochloromethane <4.7 ug/L 12/14/23 17:24 74-97-525.0 4.7 50
Bromodichloromethane <8.5 ug/L 12/14/23 17:24 75-27-425.0 8.5 50
Bromoform <9.8 ug/L 12/14/23 17:24 75-25-225.0 9.8 50
Bromomethane <11.1 ug/L 12/14/23 17:24 74-83-925011.1 50
tert-Butyl Alcohol <204 ug/L 12/14/23 17:24 75-65-0250020450
n-Butylbenzene <3.3 ug/L 12/14/23 17:24 104-51-825.0 3.3 50
sec-Butylbenzene <4.3 ug/L 12/14/23 17:24 135-98-825.0 4.3 50
tert-Butylbenzene <4.3 ug/L 12/14/23 17:24 98-06-625.0 4.3 50
tert-Butyl Formate <15.0 ug/L 12/14/23 17:24 762-75-4250015.0 50
Carbon tetrachloride <8.4 ug/L 12/14/23 17:24 56-23-525.0 8.4 50
Chlorobenzene <4.2 ug/L 12/14/23 17:24 108-90-725.0 4.2 50
Chloroethane <8.6 ug/L 12/14/23 17:24 75-00-350.0 8.6 50
Chloroform <3.5 ug/L 12/14/23 17:24 67-66-325.0 3.5 50
Chloromethane <8.8 ug/L 12/14/23 17:24 74-87-350.0 8.8 50
2-Chlorotoluene <6.4 ug/L 12/14/23 17:24 95-49-825.0 6.4 50
4-Chlorotoluene <4.8 ug/L 12/14/23 17:24 106-43-425.0 4.8 50
1,2-Dibromo-3-chloropropane <9.0 ug/L 12/14/23 17:24 96-12-850.0 9.0 50
Dibromochloromethane <7.4 ug/L 12/14/23 17:24 124-48-125.0 7.4 50
1,2-Dibromoethane (EDB)<7.4 ug/L 12/14/23 17:24 106-93-425.0 7.4 50
Dibromomethane <9.4 ug/L 12/14/23 17:24 74-95-325.0 9.4 50
1,2-Dichlorobenzene <4.7 ug/L 12/14/23 17:24 95-50-125.0 4.7 50
1,3-Dichlorobenzene <4.9 ug/L 12/14/23 17:24 541-73-125.0 4.9 50
1,4-Dichlorobenzene <4.5 ug/L 12/14/23 17:24 106-46-725.0 4.5 50
Dichlorodifluoromethane <6.2 ug/L 12/14/23 17:24 75-71-825.0 6.2 50
1,1-Dichloroethane <2.8 ug/L 12/14/23 17:24 75-34-325.0 2.8 50
1,2-Dichloroethane <5.3 ug/L 12/14/23 17:24 107-06-225.0 5.3 50
1,1-Dichloroethene <3.9 ug/L 12/14/23 17:24 75-35-425.0 3.9 50
cis-1,2-Dichloroethene <5.6 ug/L 12/14/23 17:24 156-59-225.0 5.6 50
trans-1,2-Dichloroethene <5.0 ug/L 12/14/23 17:24 156-60-525.0 5.0 50
1,2-Dichloropropane <6.8 ug/L 12/14/23 17:24 78-87-525.0 6.8 50
1,3-Dichloropropane <4.3 ug/L 12/14/23 17:24 142-28-925.0 4.3 50
2,2-Dichloropropane <6.1 ug/L 12/14/23 17:24 594-20-725.0 6.1 50
1,1-Dichloropropene <3.3 ug/L 12/14/23 17:24 563-58-625.0 3.3 50
cis-1,3-Dichloropropene <4.5 ug/L 12/14/23 17:24 10061-01-525.0 4.5 50
trans-1,3-Dichloropropene <6.6 ug/L 12/14/23 17:24 10061-02-625.0 6.6 50
Diisopropyl ether 309 ug/L 12/14/23 17:24 108-20-325.0 3.6 50
Ethanol <252 ug/L 12/14/23 17:24 64-17-51000025250
Ethylbenzene 1200 ug/L 12/14/23 17:24 100-41-425.0 4.1 50
Ethyl-tert-butyl ether <5.6 ug/L 12/14/23 17:24 637-92-35005.6 50
Hexachloro-1,3-butadiene <17.6 ug/L 12/14/23 17:24 87-68-310017.6 50
Isopropylbenzene (Cumene)195 ug/L 12/14/23 17:24 98-82-825.0 5.3 50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 44
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Sample:AS-1 Lab ID:92702751009 Collected:12/07/23 13:10 Received:12/08/23 12:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <94.5 ug/L 12/14/23 17:24 75-09-210094.5 50
Methyl-tert-butyl ether 109 ug/L 12/14/23 17:24 1634-04-425.0 2.7 50
Naphthalene 308 ug/L 12/14/23 17:24 91-20-31005.0 50
n-Propylbenzene 262 ug/L 12/14/23 17:24 103-65-125.0 5.2 50
Styrene <6.8 ug/L 12/14/23 17:24 100-42-525.0 6.8 50
1,1,1,2-Tetrachloroethane <4.6 ug/L 12/14/23 17:24 630-20-625.0 4.6 50
1,1,2,2-Tetrachloroethane <3.7 ug/L 12/14/23 17:24 79-34-525.0 3.7 50
Tetrachloroethene <4.3 ug/L 12/14/23 17:24 127-18-425.0 4.3 50
Toluene 6850 ug/L 12/14/23 17:24 108-88-325.0 4.5 50
1,2,3-Trichlorobenzene <6.0 ug/L 12/14/23 17:24 87-61-61006.0 50
1,2,4-Trichlorobenzene <7.8 ug/L 12/14/23 17:24 120-82-11007.8 50
1,1,1-Trichloroethane <5.4 ug/L 12/14/23 17:24 71-55-625.0 5.4 50
1,1,2-Trichloroethane <4.8 ug/L 12/14/23 17:24 79-00-525.0 4.8 50
Trichloroethene <8.6 ug/L 12/14/23 17:24 79-01-625.0 8.6 50
Trichlorofluoromethane <7.2 ug/L 12/14/23 17:24 75-69-450.0 7.2 50
1,2,3-Trichloropropane <8.6 ug/L 12/14/23 17:24 96-18-425.0 8.6 50
1,2,4-Trimethylbenzene 2020 ug/L 12/14/23 17:24 95-63-625.0 1.5 50
1,3,5-Trimethylbenzene 441 ug/L 12/14/23 17:24 108-67-825.0 3.6 50
Vinyl chloride <7.4 ug/L 12/14/23 17:24 75-01-450.0 7.4 50
m&p-Xylene 7330 ug/L 12/14/23 17:24 179601-23-150.0 4.7 50
o-Xylene 3970 ug/L 12/14/23 17:24 95-47-625.0 7.2 50
Surrogates
1,2-Dichloroethane-d4 (S)117 %12/14/23 17:24 17060-07-070-130 50
4-Bromofluorobenzene (S)103 %12/14/23 17:24 460-00-470-130 50
Toluene-d8 (S)102 %12/14/23 17:24 2037-26-570-130 50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 44
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Sample:AS-2 Lab ID:92702751010 Collected:12/07/23 12:50 Received:12/08/23 12:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol 418 ug/L 12/14/23 16:12 75-85-440029.8 4
tert-Amylmethyl ether 13.3J ug/L 12/14/23 16:12 994-05-840.0 0.50 4
Benzene 11.6 ug/L 12/14/23 16:12 71-43-22.0 0.31 4
Bromobenzene <0.54 ug/L 12/14/23 16:12 108-86-12.0 0.54 4
Bromochloromethane <0.38 ug/L 12/14/23 16:12 74-97-52.0 0.38 4
Bromodichloromethane <0.68 ug/L 12/14/23 16:12 75-27-42.0 0.68 4
Bromoform <0.79 ug/L 12/14/23 16:12 75-25-22.0 0.79 4
Bromomethane <0.89 ug/L 12/14/23 16:12 74-83-920.0 0.89 4
tert-Butyl Alcohol 145J ug/L 12/14/23 16:12 75-65-020016.4 4
n-Butylbenzene <0.27 ug/L 12/14/23 16:12 104-51-82.0 0.27 4
sec-Butylbenzene <0.34 ug/L 12/14/23 16:12 135-98-82.0 0.34 4
tert-Butylbenzene <0.34 ug/L 12/14/23 16:12 98-06-62.0 0.34 4
tert-Butyl Formate <1.2 ug/L 12/14/23 16:12 762-75-42001.2 4
Carbon tetrachloride <0.68 ug/L 12/14/23 16:12 56-23-52.0 0.68 4
Chlorobenzene <0.34 ug/L 12/14/23 16:12 108-90-72.0 0.34 4
Chloroethane <0.69 ug/L 12/14/23 16:12 75-00-34.0 0.69 4
Chloroform <0.28 ug/L 12/14/23 16:12 67-66-32.0 0.28 4
Chloromethane <0.70 ug/L 12/14/23 16:12 74-87-34.0 0.70 4
2-Chlorotoluene <0.52 ug/L 12/14/23 16:12 95-49-82.0 0.52 4
4-Chlorotoluene <0.38 ug/L 12/14/23 16:12 106-43-42.0 0.38 4
1,2-Dibromo-3-chloropropane <0.72 ug/L 12/14/23 16:12 96-12-84.0 0.72 4
Dibromochloromethane <0.59 ug/L 12/14/23 16:12 124-48-12.0 0.59 4
1,2-Dibromoethane (EDB)<0.59 ug/L 12/14/23 16:12 106-93-42.0 0.59 4
Dibromomethane <0.75 ug/L 12/14/23 16:12 74-95-32.0 0.75 4
1,2-Dichlorobenzene <0.38 ug/L 12/14/23 16:12 95-50-12.0 0.38 4
1,3-Dichlorobenzene <0.39 ug/L 12/14/23 16:12 541-73-12.0 0.39 4
1,4-Dichlorobenzene <0.36 ug/L 12/14/23 16:12 106-46-72.0 0.36 4
Dichlorodifluoromethane <0.49 ug/L 12/14/23 16:12 75-71-82.0 0.49 4
1,1-Dichloroethane <0.22 ug/L 12/14/23 16:12 75-34-32.0 0.22 4
1,2-Dichloroethane <0.42 ug/L 12/14/23 16:12 107-06-22.0 0.42 4
1,1-Dichloroethene <0.31 ug/L 12/14/23 16:12 75-35-42.0 0.31 4
cis-1,2-Dichloroethene 6.7 ug/L 12/14/23 16:12 156-59-22.0 0.44 4
trans-1,2-Dichloroethene <0.40 ug/L 12/14/23 16:12 156-60-52.0 0.40 4
1,2-Dichloropropane <0.54 ug/L 12/14/23 16:12 78-87-52.0 0.54 4
1,3-Dichloropropane <0.34 ug/L 12/14/23 16:12 142-28-92.0 0.34 4
2,2-Dichloropropane <0.49 ug/L 12/14/23 16:12 594-20-72.0 0.49 4
1,1-Dichloropropene <0.26 ug/L 12/14/23 16:12 563-58-62.0 0.26 4
cis-1,3-Dichloropropene <0.36 ug/L 12/14/23 16:12 10061-01-52.0 0.36 4
trans-1,3-Dichloropropene <0.53 ug/L 12/14/23 16:12 10061-02-62.0 0.53 4
Diisopropyl ether 92.9 ug/L 12/14/23 16:12 108-20-32.0 0.29 4
Ethanol <20.2 ug/L 12/14/23 16:12 64-17-580020.2 4
Ethylbenzene 1.6J ug/L 12/14/23 16:12 100-41-42.0 0.32 4
Ethyl-tert-butyl ether <0.45 ug/L 12/14/23 16:12 637-92-340.0 0.45 4
Hexachloro-1,3-butadiene <1.4 ug/L 12/14/23 16:12 87-68-38.0 1.4 4
Isopropylbenzene (Cumene)3.8 ug/L 12/14/23 16:12 98-82-82.0 0.42 4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 44
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Sample:AS-2 Lab ID:92702751010 Collected:12/07/23 12:50 Received:12/08/23 12:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <7.6 ug/L 12/14/23 16:12 75-09-28.0 7.6 4
Methyl-tert-butyl ether 73.1 ug/L 12/14/23 16:12 1634-04-42.0 0.21 4
Naphthalene 7.7J ug/L 12/14/23 16:12 91-20-38.0 0.40 4
n-Propylbenzene 3.3 ug/L 12/14/23 16:12 103-65-12.0 0.42 4
Styrene <0.55 ug/L 12/14/23 16:12 100-42-52.0 0.55 4
1,1,1,2-Tetrachloroethane <0.36 ug/L 12/14/23 16:12 630-20-62.0 0.36 4
1,1,2,2-Tetrachloroethane <0.30 ug/L 12/14/23 16:12 79-34-52.0 0.30 4
Tetrachloroethene 382 ug/L 12/14/23 16:12 127-18-42.0 0.34 4
Toluene 1.3J ug/L 12/14/23 16:12 108-88-32.0 0.36 4
1,2,3-Trichlorobenzene <0.48 ug/L 12/14/23 16:12 87-61-68.0 0.48 4
1,2,4-Trichlorobenzene <0.62 ug/L 12/14/23 16:12 120-82-18.0 0.62 4
1,1,1-Trichloroethane <0.43 ug/L 12/14/23 16:12 71-55-62.0 0.43 4
1,1,2-Trichloroethane <0.38 ug/L 12/14/23 16:12 79-00-52.0 0.38 4
Trichloroethene 22.2 ug/L 12/14/23 16:12 79-01-62.0 0.68 4
Trichlorofluoromethane <0.58 ug/L 12/14/23 16:12 75-69-44.0 0.58 4
1,2,3-Trichloropropane <0.69 ug/L 12/14/23 16:12 96-18-42.0 0.69 4
1,2,4-Trimethylbenzene 46.9 ug/L 12/14/23 16:12 95-63-62.0 0.12 4
1,3,5-Trimethylbenzene 15.4 ug/L 12/14/23 16:12 108-67-82.0 0.29 4
Vinyl chloride <0.60 ug/L 12/14/23 16:12 75-01-44.0 0.60 4
m&p-Xylene 23.0 ug/L 12/14/23 16:12 179601-23-14.0 0.37 4
o-Xylene 14.3 ug/L 12/14/23 16:12 95-47-62.0 0.58 4
Surrogates
1,2-Dichloroethane-d4 (S)116 %12/14/23 16:12 17060-07-070-130 4
4-Bromofluorobenzene (S)104 %12/14/23 16:12 460-00-470-130 4
Toluene-d8 (S)100 %12/14/23 16:12 2037-26-570-130 4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 44
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
819293
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92702751002, 92702751003, 92702751004, 92702751005, 92702751006, 92702751007, 92702751009,
92702751010
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4241044
Associated Lab Samples:92702751002, 92702751003, 92702751004, 92702751005, 92702751006, 92702751007, 92702751009,
92702751010
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L <0.091 0.50 12/14/23 12:150.091
1,1,1-Trichloroethane ug/L <0.11 0.50 12/14/23 12:150.11
1,1,2,2-Tetrachloroethane ug/L <0.074 0.50 12/14/23 12:150.074
1,1,2-Trichloroethane ug/L <0.096 0.50 12/14/23 12:150.096
1,1-Dichloroethane ug/L <0.056 0.50 12/14/23 12:150.056
1,1-Dichloroethene ug/L <0.079 0.50 12/14/23 12:150.079
1,1-Dichloropropene ug/L <0.066 0.50 12/14/23 12:150.066
1,2,3-Trichlorobenzene ug/L <0.12 2.0 12/14/23 12:150.12
1,2,3-Trichloropropane ug/L <0.17 0.50 12/14/23 12:150.17
1,2,4-Trichlorobenzene ug/L <0.16 2.0 12/14/23 12:150.16
1,2,4-Trimethylbenzene ug/L <0.031 0.50 12/14/23 12:150.031
1,2-Dibromo-3-chloropropane ug/L <0.18 1.0 12/14/23 12:150.18
1,2-Dibromoethane (EDB)ug/L <0.15 0.50 12/14/23 12:150.15
1,2-Dichlorobenzene ug/L <0.094 0.50 12/14/23 12:150.094
1,2-Dichloroethane ug/L <0.11 0.50 12/14/23 12:150.11
1,2-Dichloropropane ug/L <0.14 0.50 12/14/23 12:150.14
1,3,5-Trimethylbenzene ug/L <0.071 0.50 12/14/23 12:150.071
1,3-Dichlorobenzene ug/L <0.098 0.50 12/14/23 12:150.098
1,3-Dichloropropane ug/L <0.085 0.50 12/14/23 12:150.085
1,4-Dichlorobenzene ug/L <0.090 0.50 12/14/23 12:150.090
2,2-Dichloropropane ug/L <0.12 0.50 12/14/23 12:150.12
2-Chlorotoluene ug/L <0.13 0.50 12/14/23 12:150.13
4-Chlorotoluene ug/L <0.096 0.50 12/14/23 12:150.096
Benzene ug/L <0.079 0.50 12/14/23 12:150.079
Bromobenzene ug/L <0.14 0.50 12/14/23 12:150.14
Bromochloromethane ug/L <0.094 0.50 12/14/23 12:150.094
Bromodichloromethane ug/L <0.17 0.50 12/14/23 12:150.17
Bromoform ug/L <0.20 0.50 12/14/23 12:150.20
Bromomethane ug/L <0.22 5.0 12/14/23 12:150.22
Carbon tetrachloride ug/L <0.17 0.50 12/14/23 12:150.17
Chlorobenzene ug/L <0.085 0.50 12/14/23 12:150.085
Chloroethane ug/L <0.17 1.0 12/14/23 12:150.17
Chloroform ug/L <0.069 0.50 12/14/23 12:150.069
Chloromethane ug/L <0.18 1.0 12/14/23 12:150.18
cis-1,2-Dichloroethene ug/L <0.11 0.50 12/14/23 12:150.11
cis-1,3-Dichloropropene ug/L <0.090 0.50 12/14/23 12:150.090
Dibromochloromethane ug/L <0.15 0.50 12/14/23 12:150.15
Dibromomethane ug/L <0.19 0.50 12/14/23 12:150.19
Dichlorodifluoromethane ug/L <0.12 0.50 12/14/23 12:150.12
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 44
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4241044
Associated Lab Samples:92702751002, 92702751003, 92702751004, 92702751005, 92702751006, 92702751007, 92702751009,
92702751010
Matrix:Water
AnalyzedMDL
Diisopropyl ether ug/L <0.072 0.50 12/14/23 12:150.072
Ethanol ug/L <5.0 200 12/14/23 12:155.0
Ethyl-tert-butyl ether ug/L <0.11 10.0 12/14/23 12:150.11
Ethylbenzene ug/L <0.081 0.50 12/14/23 12:150.081
Hexachloro-1,3-butadiene ug/L <0.35 2.0 12/14/23 12:150.35
Isopropylbenzene (Cumene)ug/L <0.11 0.50 12/14/23 12:150.11
m&p-Xylene ug/L <0.094 1.0 12/14/23 12:150.094
Methyl-tert-butyl ether ug/L <0.053 0.50 12/14/23 12:150.053
Methylene Chloride ug/L <1.9 2.0 12/14/23 12:151.9
n-Butylbenzene ug/L <0.066 0.50 12/14/23 12:150.066
n-Propylbenzene ug/L <0.10 0.50 12/14/23 12:150.10
Naphthalene ug/L <0.10 2.0 12/14/23 12:150.10
o-Xylene ug/L <0.14 0.50 12/14/23 12:150.14
sec-Butylbenzene ug/L <0.085 0.50 12/14/23 12:150.085
Styrene ug/L <0.14 0.50 12/14/23 12:150.14
tert-Amyl Alcohol ug/L <7.4 100 12/14/23 12:157.4
tert-Amylmethyl ether ug/L <0.12 10.0 12/14/23 12:150.12
tert-Butyl Alcohol ug/L <4.1 50.0 12/14/23 12:154.1
tert-Butyl Formate ug/L <0.30 50.0 12/14/23 12:150.30
tert-Butylbenzene ug/L <0.086 0.50 12/14/23 12:150.086
Tetrachloroethene ug/L <0.086 0.50 12/14/23 12:150.086
Toluene ug/L <0.090 0.50 12/14/23 12:150.090
trans-1,2-Dichloroethene ug/L <0.10 0.50 12/14/23 12:150.10
trans-1,3-Dichloropropene ug/L <0.13 0.50 12/14/23 12:150.13
Trichloroethene ug/L <0.17 0.50 12/14/23 12:150.17
Trichlorofluoromethane ug/L <0.14 1.0 12/14/23 12:150.14
Vinyl chloride ug/L <0.15 1.0 12/14/23 12:150.15
1,2-Dichloroethane-d4 (S)%117 70-130 12/14/23 12:15
4-Bromofluorobenzene (S)%101 70-130 12/14/23 12:15
Toluene-d8 (S)%100 70-130 12/14/23 12:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4241045LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 19.920 99 60-140
1,1,1-Trichloroethane ug/L 22.520 112 60-140
1,1,2,2-Tetrachloroethane ug/L 22.320 112 60-140
1,1,2-Trichloroethane ug/L 22.220 111 60-140
1,1-Dichloroethane ug/L 23.420 117 60-140
1,1-Dichloroethene ug/L 23.920 120 60-140
1,1-Dichloropropene ug/L 25.320 127 60-140
1,2,3-Trichlorobenzene ug/L 17.920 90 60-140
1,2,3-Trichloropropane ug/L 21.420 107 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 44
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4241045LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 18.820 94 60-140
1,2,4-Trimethylbenzene ug/L 22.320 111 60-140
1,2-Dibromo-3-chloropropane ug/L 19.320 96 60-140
1,2-Dibromoethane (EDB)ug/L 21.620 108 60-140
1,2-Dichlorobenzene ug/L 20.720 103 60-140
1,2-Dichloroethane ug/L 24.620 123 60-140
1,2-Dichloropropane ug/L 22.820 114 60-140
1,3,5-Trimethylbenzene ug/L 21.820 109 60-140
1,3-Dichlorobenzene ug/L 20.520 103 60-140
1,3-Dichloropropane ug/L 21.620 108 60-140
1,4-Dichlorobenzene ug/L 20.520 102 60-140
2,2-Dichloropropane ug/L 22.220 111 60-140
2-Chlorotoluene ug/L 21.920 110 60-140
4-Chlorotoluene ug/L 22.420 112 60-140
Benzene ug/L 21.720 109 60-140
Bromobenzene ug/L 20.020 100 60-140
Bromochloromethane ug/L 22.820 114 60-140
Bromodichloromethane ug/L 21.020 105 60-140
Bromoform ug/L 17.820 89 60-140
Bromomethane ug/L 18.620 93 60-140
Carbon tetrachloride ug/L 19.720 99 60-140
Chlorobenzene ug/L 20.320 102 60-140
Chloroethane ug/L 25.020 125 60-140
Chloroform ug/L 22.820 114 60-140
Chloromethane ug/L 22.720 114 60-140
cis-1,2-Dichloroethene ug/L 24.220 121 60-140
cis-1,3-Dichloropropene ug/L 21.220 106 60-140
Dibromochloromethane ug/L 19.820 99 60-140
Dibromomethane ug/L 19.120 96 60-140
Dichlorodifluoromethane ug/L 21.220 106 60-140
Diisopropyl ether ug/L 22.620 113 60-140
Ethanol ug/L 938800 117 60-140
Ethyl-tert-butyl ether ug/L 44.140 110 60-140
Ethylbenzene ug/L 21.120 105 60-140
Hexachloro-1,3-butadiene ug/L 17.820 89 60-140
Isopropylbenzene (Cumene)ug/L 21.220 106 60-140
m&p-Xylene ug/L 42.940 107 60-140
Methyl-tert-butyl ether ug/L 21.820 109 60-140
Methylene Chloride ug/L 25.020 125 60-140
n-Butylbenzene ug/L 23.020 115 60-140
n-Propylbenzene ug/L 21.720 109 60-140
Naphthalene ug/L 20.120 100 60-140
o-Xylene ug/L 20.820 104 60-140
sec-Butylbenzene ug/L 21.620 108 60-140
Styrene ug/L 21.520 107 60-140
tert-Amyl Alcohol ug/L 383400 96 60-140
tert-Amylmethyl ether ug/L 41.440 104 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 44
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4241045LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butyl Alcohol ug/L 180200 90 60-140
tert-Butyl Formate ug/L 136160 85 60-140
tert-Butylbenzene ug/L 17.120 85 60-140
Tetrachloroethene ug/L 18.620 93 60-140
Toluene ug/L 20.720 103 60-140
trans-1,2-Dichloroethene ug/L 24.620 123 60-140
trans-1,3-Dichloropropene ug/L 21.020 105 60-140
Trichloroethene ug/L 20.320 102 60-140
Trichlorofluoromethane ug/L 21.320 106 60-140
Vinyl chloride ug/L 20.920 105 60-140
1,2-Dichloroethane-d4 (S)%117 70-130
4-Bromofluorobenzene (S)%105 70-130
Toluene-d8 (S)%103 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4241046MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92703564002
4241047
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 121 60-140123 1 3020<0.091 24.2 24.5
1,1,1-Trichloroethane ug/L M12014360-140142 1 3020<0.11 28.6 28.4
1,1,2,2-Tetrachloroethane ug/L 20 129 60-140135 5 3020<0.074 25.9 27.1
1,1,2-Trichloroethane ug/L 20 124 60-140132 7 3020<0.096 24.7 26.4
1,1-Dichloroethane ug/L M12015160-140149 1 3020<0.056 30.2 29.8
1,1-Dichloroethene ug/L M12015460-140153 1 3020<0.079 30.9 30.5
1,1-Dichloropropene ug/L M12016660-140163 2 3020<0.066 33.2 32.6
1,2,3-Trichlorobenzene ug/L 20 104 60-140115 10 3020<0.12 20.9 23.0
1,2,3-Trichloropropane ug/L 20 124 60-140130 4 3020<0.17 24.8 25.9
1,2,4-Trichlorobenzene ug/L 20 107 60-140110 3 3020<0.16 21.5 22.0
1,2,4-Trimethylbenzene ug/L 20 135 60-140137 2 3020<0.031 27.0 27.5
1,2-Dibromo-3-
chloropropane ug/L 20 109 60-140115 5 3020<0.18 21.8 23.0
1,2-Dibromoethane (EDB)ug/L 20 125 60-140131 5 3020<0.15 25.1 26.3
1,2-Dichlorobenzene ug/L 20 120 60-140124 4 3020<0.094 23.9 24.9
1,2-Dichloroethane ug/L M12014560-140148 2 3020<0.11 29.0 29.5
1,2-Dichloropropane ug/L M12013860-140142 3 3020<0.14 27.5 28.4
1,3,5-Trimethylbenzene ug/L 20 134 60-140136 1 3020<0.071 26.8 27.2
1,3-Dichlorobenzene ug/L 20 122 60-140126 3 3020<0.098 24.3 25.2
1,3-Dichloropropane ug/L 20 127 60-140132 4 3020<0.085 25.5 26.4
1,4-Dichlorobenzene ug/L 20 120 60-140123 3 3020<0.090 24.0 24.7
2,2-Dichloropropane ug/L M12014360-140143 0 3020<0.12 28.6 28.6
2-Chlorotoluene ug/L 20 133 60-140137 3 3020<0.13 26.6 27.3
4-Chlorotoluene ug/L 20 136 60-140140 3 3020<0.096 27.1 27.9
Benzene ug/L 20 132 60-140135 2 3020<0.079 26.4 26.9
Bromobenzene ug/L 20 117 60-140122 4 3020<0.14 23.4 24.3
Bromochloromethane ug/L 20 137 60-140137 1 3020<0.094 27.5 27.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 44
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4241046MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92703564002
4241047
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Bromodichloromethane ug/L 20 126 60-140130 3 3020<0.17 25.2 26.0
Bromoform ug/L 20 102 60-140106 4 3020<0.20 20.5 21.3
Bromomethane ug/L 20 114 60-140114 0 3020<0.22 22.8 22.8
Carbon tetrachloride ug/L 20 124 60-140125 1 3020<0.17 24.9 25.0
Chlorobenzene ug/L 20 122 60-140126 3 3020<0.085 24.4 25.2
Chloroethane ug/L M12015560-140151 3 3020<0.17 31.1 30.2
Chloroform ug/L M12014160-140145 3 3020<0.069 28.2 29.0
Chloromethane ug/L M12014160-140141 0 3020<0.18 28.2 28.2
cis-1,2-Dichloroethene ug/L M12014960-140149 0 3020<0.11 29.8 29.8
cis-1,3-Dichloropropene ug/L 20 124 60-140127 2 3020<0.090 24.8 25.3
Dibromochloromethane ug/L 20 117 60-140123 4 3020<0.15 23.5 24.5
Dibromomethane ug/L 20 109 60-140113 4 3020<0.19 21.8 22.6
Dichlorodifluoromethane ug/L 20 127 60-140124 3 3020<0.12 25.5 24.8
Diisopropyl ether ug/L M12014160-140143 2 3020<0.072 28.2 28.6
Ethanol ug/L M180013660-140145 7 30800<5.0 1090 1160
Ethyl-tert-butyl ether ug/L 40 134 60-140138 3 3040<0.11 53.5 55.2
Ethylbenzene ug/L 20 129 60-140130 1 3020<0.081 25.8 26.0
Hexachloro-1,3-butadiene ug/L 20 119 60-140114 5 3020<0.35 23.9 22.7
Isopropylbenzene
(Cumene)ug/L 20 132 60-140131 0 3020<0.11 26.3 26.2
m&p-Xylene ug/L 40 130 60-140134 3 3040<0.094 52.0 53.5
Methyl-tert-butyl ether ug/L 20 131 60-140136 4 30200.79 27.0 27.9
Methylene Chloride ug/L 20 139 60-140138 1 3020<1.9 27.8 27.7
n-Butylbenzene ug/L M12015160-140146 3 3020<0.066 30.2 29.3
n-Propylbenzene ug/L 20 137 60-140136 0 3020<0.10 27.3 27.2
Naphthalene ug/L 20 109 60-140122 11 3020<0.10 21.7 24.3
o-Xylene ug/L 20 124 60-140126 2 3020<0.14 24.8 25.2
sec-Butylbenzene ug/L 20 139 60-140138 1 3020<0.085 27.9 27.5
Styrene ug/L 20 128 60-140132 3 3020<0.14 25.5 26.3
tert-Amyl Alcohol ug/L 400 104 60-140116 11 30400<7.4 414 462
tert-Amylmethyl ether ug/L 40 119 60-140127 6 3040<0.12 47.7 50.8
tert-Butyl Alcohol ug/L 200 110 60-140131 17 30200<4.1 220 262
tert-Butyl Formate ug/L 160 92 60-14082 12 30160<0.30 147 131
tert-Butylbenzene ug/L 20 106 60-140106 0 3020<0.086 21.2 21.1
Tetrachloroethene ug/L 20 115 60-140115 1 3020<0.086 22.9 23.0
Toluene ug/L 20 123 60-140129 4 3020<0.090 24.7 25.7
trans-1,2-Dichloroethene ug/L M12016160-140158 2 3020<0.10 32.1 31.7
trans-1,3-Dichloropropene ug/L 20 123 60-140129 4 3020<0.13 24.7 25.8
Trichloroethene ug/L 20 123 60-140125 2 3020<0.17 24.6 25.1
Trichlorofluoromethane ug/L 20 135 60-140135 1 3020<0.14 27.1 26.9
Vinyl chloride ug/L 20 134 60-140131 3 3020<0.15 26.9 26.1
1,2-Dichloroethane-d4 (S)%118 70-130118
4-Bromofluorobenzene (S)%107 70-130106
Toluene-d8 (S)%101 70-130102
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 44
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
819707
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92702751001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4243177
Associated Lab Samples:92702751001
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L <0.091 0.50 12/15/23 03:590.091
1,1,1-Trichloroethane ug/L <0.11 0.50 12/15/23 03:590.11
1,1,2,2-Tetrachloroethane ug/L <0.074 0.50 12/15/23 03:590.074
1,1,2-Trichloroethane ug/L <0.096 0.50 12/15/23 03:590.096
1,1-Dichloroethane ug/L <0.056 0.50 12/15/23 03:590.056
1,1-Dichloroethene ug/L <0.079 0.50 12/15/23 03:590.079
1,1-Dichloropropene ug/L <0.066 0.50 12/15/23 03:590.066
1,2,3-Trichlorobenzene ug/L <0.12 2.0 12/15/23 03:590.12
1,2,3-Trichloropropane ug/L <0.17 0.50 12/15/23 03:590.17
1,2,4-Trichlorobenzene ug/L <0.16 2.0 12/15/23 03:590.16
1,2,4-Trimethylbenzene ug/L <0.031 0.50 12/15/23 03:590.031
1,2-Dibromo-3-chloropropane ug/L <0.18 1.0 12/15/23 03:590.18
1,2-Dibromoethane (EDB)ug/L <0.15 0.50 12/15/23 03:590.15
1,2-Dichlorobenzene ug/L <0.094 0.50 12/15/23 03:590.094
1,2-Dichloroethane ug/L <0.11 0.50 12/15/23 03:590.11
1,2-Dichloropropane ug/L <0.14 0.50 12/15/23 03:590.14
1,3,5-Trimethylbenzene ug/L <0.071 0.50 12/15/23 03:590.071
1,3-Dichlorobenzene ug/L <0.098 0.50 12/15/23 03:590.098
1,3-Dichloropropane ug/L <0.085 0.50 12/15/23 03:590.085
1,4-Dichlorobenzene ug/L <0.090 0.50 12/15/23 03:590.090
2,2-Dichloropropane ug/L <0.12 0.50 12/15/23 03:590.12
2-Chlorotoluene ug/L <0.13 0.50 12/15/23 03:590.13
4-Chlorotoluene ug/L <0.096 0.50 12/15/23 03:590.096
Benzene ug/L <0.079 0.50 12/15/23 03:590.079
Bromobenzene ug/L <0.14 0.50 12/15/23 03:590.14
Bromochloromethane ug/L <0.094 0.50 12/15/23 03:590.094
Bromodichloromethane ug/L <0.17 0.50 12/15/23 03:590.17
Bromoform ug/L <0.20 0.50 12/15/23 03:590.20
Bromomethane ug/L <0.22 5.0 12/15/23 03:590.22
Carbon tetrachloride ug/L <0.17 0.50 12/15/23 03:590.17
Chlorobenzene ug/L <0.085 0.50 12/15/23 03:590.085
Chloroethane ug/L <0.17 1.0 12/15/23 03:590.17
Chloroform ug/L <0.069 0.50 12/15/23 03:590.069
Chloromethane ug/L <0.18 1.0 12/15/23 03:590.18
cis-1,2-Dichloroethene ug/L <0.11 0.50 12/15/23 03:590.11
cis-1,3-Dichloropropene ug/L <0.090 0.50 12/15/23 03:590.090
Dibromochloromethane ug/L <0.15 0.50 12/15/23 03:590.15
Dibromomethane ug/L <0.19 0.50 12/15/23 03:590.19
Dichlorodifluoromethane ug/L <0.12 0.50 12/15/23 03:590.12
Diisopropyl ether ug/L <0.072 0.50 12/15/23 03:590.072
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 44
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4243177
Associated Lab Samples:92702751001
Matrix:Water
AnalyzedMDL
Ethanol ug/L <5.0 200 12/15/23 03:595.0
Ethyl-tert-butyl ether ug/L <0.11 10.0 12/15/23 03:590.11
Ethylbenzene ug/L <0.081 0.50 12/15/23 03:590.081
Hexachloro-1,3-butadiene ug/L <0.35 2.0 12/15/23 03:590.35
Isopropylbenzene (Cumene)ug/L <0.11 0.50 12/15/23 03:590.11
m&p-Xylene ug/L <0.094 1.0 12/15/23 03:590.094
Methyl-tert-butyl ether ug/L <0.053 0.50 12/15/23 03:590.053
Methylene Chloride ug/L <1.9 2.0 12/15/23 03:591.9
n-Butylbenzene ug/L <0.066 0.50 12/15/23 03:590.066
n-Propylbenzene ug/L <0.10 0.50 12/15/23 03:590.10
Naphthalene ug/L <0.10 2.0 12/15/23 03:590.10
o-Xylene ug/L <0.14 0.50 12/15/23 03:590.14
sec-Butylbenzene ug/L <0.085 0.50 12/15/23 03:590.085
Styrene ug/L <0.14 0.50 12/15/23 03:590.14
tert-Amyl Alcohol ug/L <7.4 100 12/15/23 03:597.4
tert-Amylmethyl ether ug/L <0.12 10.0 12/15/23 03:590.12
tert-Butyl Alcohol ug/L <4.1 50.0 12/15/23 03:594.1
tert-Butyl Formate ug/L <0.30 50.0 12/15/23 03:590.30
tert-Butylbenzene ug/L <0.086 0.50 12/15/23 03:590.086
Tetrachloroethene ug/L <0.086 0.50 12/15/23 03:590.086
Toluene ug/L <0.090 0.50 12/15/23 03:590.090
trans-1,2-Dichloroethene ug/L <0.10 0.50 12/15/23 03:590.10
trans-1,3-Dichloropropene ug/L <0.13 0.50 12/15/23 03:590.13
Trichloroethene ug/L <0.17 0.50 12/15/23 03:590.17
Trichlorofluoromethane ug/L <0.14 1.0 12/15/23 03:590.14
Vinyl chloride ug/L <0.15 1.0 12/15/23 03:590.15
1,2-Dichloroethane-d4 (S)%104 70-130 12/15/23 03:59
4-Bromofluorobenzene (S)%100 70-130 12/15/23 03:59
Toluene-d8 (S)%101 70-130 12/15/23 03:59
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4243178LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 20.320 101 60-140
1,1,1-Trichloroethane ug/L 19.420 97 60-140
1,1,2,2-Tetrachloroethane ug/L 21.820 109 60-140
1,1,2-Trichloroethane ug/L 20.520 103 60-140
1,1-Dichloroethane ug/L 20.820 104 60-140
1,1-Dichloroethene ug/L 21.020 105 60-140
1,1-Dichloropropene ug/L 21.720 109 60-140
1,2,3-Trichlorobenzene ug/L 19.120 96 60-140
1,2,3-Trichloropropane ug/L 21.020 105 60-140
1,2,4-Trichlorobenzene ug/L 18.820 94 60-140
1,2,4-Trimethylbenzene ug/L 20.620 103 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 44
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4243178LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dibromo-3-chloropropane ug/L 20.120 101 60-140
1,2-Dibromoethane (EDB)ug/L 20.620 103 60-140
1,2-Dichlorobenzene ug/L 20.120 100 60-140
1,2-Dichloroethane ug/L 20.120 100 60-140
1,2-Dichloropropane ug/L 21.620 108 60-140
1,3,5-Trimethylbenzene ug/L 20.420 102 60-140
1,3-Dichlorobenzene ug/L 20.020 100 60-140
1,3-Dichloropropane ug/L 20.720 103 60-140
1,4-Dichlorobenzene ug/L 19.820 99 60-140
2,2-Dichloropropane ug/L 18.520 93 60-140
2-Chlorotoluene ug/L 20.420 102 60-140
4-Chlorotoluene ug/L 20.220 101 60-140
Benzene ug/L 20.320 101 60-140
Bromobenzene ug/L 19.720 99 60-140
Bromochloromethane ug/L 20.520 102 60-140
Bromodichloromethane ug/L 19.020 95 60-140
Bromoform ug/L 19.420 97 60-140
Bromomethane ug/L 16.920 85 60-140
Carbon tetrachloride ug/L 19.020 95 60-140
Chlorobenzene ug/L 20.120 100 60-140
Chloroethane ug/L 22.720 114 60-140
Chloroform ug/L 20.420 102 60-140
Chloromethane ug/L 20.020 100 60-140
cis-1,2-Dichloroethene ug/L 21.120 105 60-140
cis-1,3-Dichloropropene ug/L 19.520 97 60-140
Dibromochloromethane ug/L 19.620 98 60-140
Dibromomethane ug/L 19.620 98 60-140
Dichlorodifluoromethane ug/L 20.520 102 60-140
Diisopropyl ether ug/L 21.020 105 60-140
Ethanol ug/L 982800 123 60-140
Ethyl-tert-butyl ether ug/L 39.540 99 60-140
Ethylbenzene ug/L 20.220 101 60-140
Hexachloro-1,3-butadiene ug/L 19.120 96 60-140
Isopropylbenzene (Cumene)ug/L 20.520 102 60-140
m&p-Xylene ug/L 40.440 101 60-140
Methyl-tert-butyl ether ug/L 19.020 95 60-140
Methylene Chloride ug/L 19.220 96 60-140
n-Butylbenzene ug/L 20.720 104 60-140
n-Propylbenzene ug/L 20.620 103 60-140
Naphthalene ug/L 20.320 101 60-140
o-Xylene ug/L 20.320 102 60-140
sec-Butylbenzene ug/L 20.020 100 60-140
Styrene ug/L 20.520 102 60-140
tert-Amyl Alcohol ug/L 443400 111 60-140
tert-Amylmethyl ether ug/L 39.640 99 60-140
tert-Butyl Alcohol ug/L 155200 78 60-140
tert-Butyl Formate ug/L 157160 98 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 44
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4243178LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butylbenzene ug/L 16.520 83 60-140
Tetrachloroethene ug/L 19.220 96 60-140
Toluene ug/L 19.720 98 60-140
trans-1,2-Dichloroethene ug/L 21.520 107 60-140
trans-1,3-Dichloropropene ug/L 19.420 97 60-140
Trichloroethene ug/L 20.120 100 60-140
Trichlorofluoromethane ug/L 19.120 95 60-140
Vinyl chloride ug/L 20.720 104 60-140
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4243179MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92702644001
4243180
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 130 60-140108 19 3020<0.091 26.1 21.6
1,1,1-Trichloroethane ug/L 20 130 60-140111 16 3020<0.11 25.9 22.1
1,1,2,2-Tetrachloroethane ug/L 20 136 60-140107 23 3020<0.074 27.1 21.4
1,1,2-Trichloroethane ug/L 20 132 60-140105 22 3020<0.096 26.4 21.1
1,1-Dichloroethane ug/L 20 136 60-140115 17 3020<0.056 27.3 23.1
1,1-Dichloroethene ug/L M12014360-140123 15 3020<0.079 28.5 24.6
1,1-Dichloropropene ug/L M12014860-140126 16 3020<0.066 29.5 25.2
1,2,3-Trichlorobenzene ug/L 20 116 60-14098 16 3020<0.12 23.2 19.6
1,2,3-Trichloropropane ug/L 20 130 60-140103 23 3020<0.17 25.9 20.5
1,2,4-Trichlorobenzene ug/L 20 114 60-14098 15 3020<0.16 22.7 19.6
1,2,4-Trimethylbenzene ug/L 20 138 60-140115 18 3020<0.031 27.5 22.9
1,2-Dibromo-3-
chloropropane ug/L 20 121 60-14092 27 3020<0.18 24.1 18.4
1,2-Dibromoethane (EDB)ug/L 20 129 60-140104 22 3020<0.15 25.8 20.8
1,2-Dichlorobenzene ug/L 20 126 60-140108 15 3020<0.094 25.1 21.6
1,2-Dichloroethane ug/L 20 127 60-140105 19 3020<0.11 25.4 21.0
1,2-Dichloropropane ug/L M12014160-140116 20 3020<0.14 28.2 23.1
1,3,5-Trimethylbenzene ug/L 20 134 60-140115 15 3020<0.071 26.7 23.0
1,3-Dichlorobenzene ug/L 20 127 60-140110 14 3020<0.098 25.3 21.9
1,3-Dichloropropane ug/L 20 130 60-140106 20 3020<0.085 26.0 21.1
1,4-Dichlorobenzene ug/L 20 125 60-140108 15 3020<0.090 25.0 21.6
2,2-Dichloropropane ug/L 20 137 60-140114 18 3020<0.12 27.3 22.8
2-Chlorotoluene ug/L 20 127 60-140112 13 3020<0.13 25.5 22.4
4-Chlorotoluene ug/L 20 130 60-140114 13 3020<0.096 25.9 22.8
Benzene ug/L 20 133 60-140111 18 3020<0.079 26.5 22.2
Bromobenzene ug/L 20 126 60-140108 15 3020<0.14 25.1 21.7
Bromochloromethane ug/L 20 132 60-140110 19 3020<0.094 26.5 21.9
Bromodichloromethane ug/L 20 124 60-140104 18 3020<0.17 24.8 20.7
Bromoform ug/L 20 120 60-14096 21 3020<0.20 23.9 19.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 44
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4243179MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92702644001
4243180
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Bromomethane ug/L 20 103 60-140106 2 3020<0.22 20.6 21.2
Carbon tetrachloride ug/L 20 126 60-140107 17 3020<0.17 25.3 21.4
Chlorobenzene ug/L 20 127 60-140108 16 3020<0.085 25.4 21.6
Chloroethane ug/L M12015160-140128 17 3020<0.17 30.1 25.5
Chloroform ug/L 20 132 60-140111 17 3020<0.069 26.5 22.3
Chloromethane ug/L 20 131 60-140110 17 3020<0.18 26.1 22.0
cis-1,2-Dichloroethene ug/L 20 137 60-140116 17 3020<0.11 27.4 23.1
cis-1,3-Dichloropropene ug/L 20 127 60-140105 19 3020<0.090 25.5 21.0
Dibromochloromethane ug/L 20 122 60-140101 18 3020<0.15 24.4 20.3
Dibromomethane ug/L 20 122 60-140100 20 3020<0.19 24.4 19.9
Dichlorodifluoromethane ug/L M12016460-140137 18 3020<0.12 32.7 27.4
Diisopropyl ether ug/L 20 136 60-140113 19 3020<0.072 27.2 22.6
Ethanol ug/L M1,R180015160-140110 32 30800<5.0 1210 880
Ethyl-tert-butyl ether ug/L 40 126 60-140104 19 3040<0.11 50.4 41.5
Ethylbenzene ug/L 20 132 60-140110 18 3020<0.081 26.4 21.9
Hexachloro-1,3-butadiene ug/L 20 128 60-140111 15 3020<0.35 25.6 22.2
Isopropylbenzene
(Cumene)ug/L 20 133 60-140112 17 3020<0.11 26.6 22.5
m&p-Xylene ug/L 40 130 60-140110 16 3040<0.094 51.8 43.9
Methyl-tert-butyl ether ug/L 20 122 60-14099 21 3020<0.053 24.5 19.8
Methylene Chloride ug/L 20 127 60-140102 22 3020<1.9 25.5 20.5
n-Butylbenzene ug/L 20 131 60-140114 14 3020<0.066 26.3 22.8
n-Propylbenzene ug/L 20 133 60-140115 14 3020<0.10 26.6 23.1
Naphthalene ug/L 20 129 60-14098 27 3020<0.10 25.7 19.6
o-Xylene ug/L 20 131 60-140110 17 3020<0.14 26.1 21.9
sec-Butylbenzene ug/L 20 130 60-140113 14 3020<0.085 26.0 22.5
Styrene ug/L 20 131 60-140108 19 3020<0.14 26.1 21.7
tert-Amyl Alcohol ug/L R140013760-14095 36 30400<7.4 546 379
tert-Amylmethyl ether ug/L 40 127 60-140103 20 3040<0.12 50.6 41.3
tert-Butyl Alcohol ug/L R12009560-14068 32 30200<4.1 190 137
tert-Butyl Formate ug/L M11604260-14034 22 30160<0.30 67.4 54.2
tert-Butylbenzene ug/L 20 107 60-14092 15 3020<0.086 21.4 18.5
Tetrachloroethene ug/L 20 124 60-140106 16 3020<0.086 24.8 21.3
Toluene ug/L 20 130 60-140108 19 3020<0.090 26.0 21.6
trans-1,2-Dichloroethene ug/L M12014260-140121 16 3020<0.10 28.3 24.1
trans-1,3-Dichloropropene ug/L 20 125 60-140103 19 3020<0.13 24.9 20.5
Trichloroethene ug/L 20 130 60-140109 17 3020<0.17 26.0 21.9
Trichlorofluoromethane ug/L M12014260-140120 17 3020<0.14 28.4 24.0
Vinyl chloride ug/L M12014260-140120 16 3020<0.15 28.3 24.0
1,2-Dichloroethane-d4 (S)%100 70-130100
4-Bromofluorobenzene (S)%102 70-13099
Toluene-d8 (S)%102 70-130101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 44
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
819828
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92702751008
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4243636
Associated Lab Samples:92702751008
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L <0.091 0.50 12/15/23 13:280.091
1,1,1-Trichloroethane ug/L <0.11 0.50 12/15/23 13:280.11
1,1,2,2-Tetrachloroethane ug/L <0.074 0.50 12/15/23 13:280.074
1,1,2-Trichloroethane ug/L <0.096 0.50 12/15/23 13:280.096
1,1-Dichloroethane ug/L <0.056 0.50 12/15/23 13:280.056
1,1-Dichloroethene ug/L <0.079 0.50 12/15/23 13:280.079
1,1-Dichloropropene ug/L <0.066 0.50 12/15/23 13:280.066
1,2,3-Trichlorobenzene ug/L <0.12 2.0 12/15/23 13:280.12
1,2,3-Trichloropropane ug/L <0.17 0.50 12/15/23 13:280.17
1,2,4-Trichlorobenzene ug/L <0.16 2.0 12/15/23 13:280.16
1,2,4-Trimethylbenzene ug/L <0.031 0.50 12/15/23 13:280.031
1,2-Dibromo-3-chloropropane ug/L <0.18 1.0 12/15/23 13:280.18
1,2-Dibromoethane (EDB)ug/L <0.15 0.50 12/15/23 13:280.15
1,2-Dichlorobenzene ug/L <0.094 0.50 12/15/23 13:280.094
1,2-Dichloroethane ug/L <0.11 0.50 12/15/23 13:280.11
1,2-Dichloropropane ug/L <0.14 0.50 12/15/23 13:280.14
1,3,5-Trimethylbenzene ug/L <0.071 0.50 12/15/23 13:280.071
1,3-Dichlorobenzene ug/L <0.098 0.50 12/15/23 13:280.098
1,3-Dichloropropane ug/L <0.085 0.50 12/15/23 13:280.085
1,4-Dichlorobenzene ug/L <0.090 0.50 12/15/23 13:280.090
2,2-Dichloropropane ug/L <0.12 0.50 12/15/23 13:280.12
2-Chlorotoluene ug/L <0.13 0.50 12/15/23 13:280.13
4-Chlorotoluene ug/L <0.096 0.50 12/15/23 13:280.096
Benzene ug/L <0.079 0.50 12/15/23 13:280.079
Bromobenzene ug/L <0.14 0.50 12/15/23 13:280.14
Bromochloromethane ug/L <0.094 0.50 12/15/23 13:280.094
Bromodichloromethane ug/L <0.17 0.50 12/15/23 13:280.17
Bromoform ug/L <0.20 0.50 12/15/23 13:280.20
Bromomethane ug/L <0.22 5.0 12/15/23 13:280.22
Carbon tetrachloride ug/L <0.17 0.50 12/15/23 13:280.17
Chlorobenzene ug/L <0.085 0.50 12/15/23 13:280.085
Chloroethane ug/L <0.17 1.0 12/15/23 13:280.17
Chloroform ug/L <0.069 0.50 12/15/23 13:280.069
Chloromethane ug/L <0.18 1.0 12/15/23 13:280.18
cis-1,2-Dichloroethene ug/L <0.11 0.50 12/15/23 13:280.11
cis-1,3-Dichloropropene ug/L <0.090 0.50 12/15/23 13:280.090
Dibromochloromethane ug/L <0.15 0.50 12/15/23 13:280.15
Dibromomethane ug/L <0.19 0.50 12/15/23 13:280.19
Dichlorodifluoromethane ug/L <0.12 0.50 12/15/23 13:280.12
Diisopropyl ether ug/L <0.072 0.50 12/15/23 13:280.072
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 44
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4243636
Associated Lab Samples:92702751008
Matrix:Water
AnalyzedMDL
Ethanol ug/L <5.0 200 12/15/23 13:285.0
Ethyl-tert-butyl ether ug/L <0.11 10.0 12/15/23 13:280.11
Ethylbenzene ug/L <0.081 0.50 12/15/23 13:280.081
Hexachloro-1,3-butadiene ug/L <0.35 2.0 12/15/23 13:280.35
Isopropylbenzene (Cumene)ug/L <0.11 0.50 12/15/23 13:280.11
m&p-Xylene ug/L <0.094 1.0 12/15/23 13:280.094
Methyl-tert-butyl ether ug/L <0.053 0.50 12/15/23 13:280.053
Methylene Chloride ug/L <1.9 2.0 12/15/23 13:281.9
n-Butylbenzene ug/L <0.066 0.50 12/15/23 13:280.066
n-Propylbenzene ug/L <0.10 0.50 12/15/23 13:280.10
Naphthalene ug/L <0.10 2.0 12/15/23 13:280.10
o-Xylene ug/L <0.14 0.50 12/15/23 13:280.14
sec-Butylbenzene ug/L <0.085 0.50 12/15/23 13:280.085
Styrene ug/L <0.14 0.50 12/15/23 13:280.14
tert-Amyl Alcohol ug/L <7.4 100 12/15/23 13:287.4
tert-Amylmethyl ether ug/L <0.12 10.0 12/15/23 13:280.12
tert-Butyl Alcohol ug/L <4.1 50.0 12/15/23 13:284.1
tert-Butyl Formate ug/L <0.30 50.0 12/15/23 13:280.30
tert-Butylbenzene ug/L <0.086 0.50 12/15/23 13:280.086
Tetrachloroethene ug/L <0.086 0.50 12/15/23 13:280.086
Toluene ug/L <0.090 0.50 12/15/23 13:280.090
trans-1,2-Dichloroethene ug/L <0.10 0.50 12/15/23 13:280.10
trans-1,3-Dichloropropene ug/L <0.13 0.50 12/15/23 13:280.13
Trichloroethene ug/L <0.17 0.50 12/15/23 13:280.17
Trichlorofluoromethane ug/L <0.14 1.0 12/15/23 13:280.14
Vinyl chloride ug/L <0.15 1.0 12/15/23 13:280.15
1,2-Dichloroethane-d4 (S)%119 70-130 12/15/23 13:28
4-Bromofluorobenzene (S)%104 70-130 12/15/23 13:28
Toluene-d8 (S)%100 70-130 12/15/23 13:28
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4243637LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 20.920 105 60-140
1,1,1-Trichloroethane ug/L 24.120 120 60-140
1,1,2,2-Tetrachloroethane ug/L 23.520 118 60-140
1,1,2-Trichloroethane ug/L 22.420 112 60-140
1,1-Dichloroethane ug/L 25.720 129 60-140
1,1-Dichloroethene ug/L 25.920 130 60-140
1,1-Dichloropropene ug/L 27.820 139 60-140
1,2,3-Trichlorobenzene ug/L 18.220 91 60-140
1,2,3-Trichloropropane ug/L 22.420 112 60-140
1,2,4-Trichlorobenzene ug/L 18.820 94 60-140
1,2,4-Trimethylbenzene ug/L 23.720 118 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 44
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4243637LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dibromo-3-chloropropane ug/L 19.820 99 60-140
1,2-Dibromoethane (EDB)ug/L 22.920 115 60-140
1,2-Dichlorobenzene ug/L 21.720 109 60-140
1,2-Dichloroethane ug/L 25.720 129 60-140
1,2-Dichloropropane ug/L 24.120 121 60-140
1,3,5-Trimethylbenzene ug/L 23.320 117 60-140
1,3-Dichlorobenzene ug/L 21.920 109 60-140
1,3-Dichloropropane ug/L 22.720 113 60-140
1,4-Dichlorobenzene ug/L 21.520 107 60-140
2,2-Dichloropropane ug/L 23.520 118 60-140
2-Chlorotoluene ug/L 23.820 119 60-140
4-Chlorotoluene ug/L 23.920 120 60-140
Benzene ug/L 22.720 114 60-140
Bromobenzene ug/L 21.020 105 60-140
Bromochloromethane ug/L 24.020 120 60-140
Bromodichloromethane ug/L 21.920 109 60-140
Bromoform ug/L 18.620 93 60-140
Bromomethane ug/L 17.920 90 60-140
Carbon tetrachloride ug/L 21.220 106 60-140
Chlorobenzene ug/L 21.520 107 60-140
Chloroethane ug/L 27.020 135 60-140
Chloroform ug/L 25.020 125 60-140
Chloromethane ug/L 24.920 124 60-140
cis-1,2-Dichloroethene ug/L 25.820 129 60-140
cis-1,3-Dichloropropene ug/L 21.920 109 60-140
Dibromochloromethane ug/L 20.820 104 60-140
Dibromomethane ug/L 19.420 97 60-140
Dichlorodifluoromethane ug/L 24.020 120 60-140
Diisopropyl ether ug/L 24.520 123 60-140
Ethanol ug/L 979800 122 60-140
Ethyl-tert-butyl ether ug/L 47.340 118 60-140
Ethylbenzene ug/L 22.620 113 60-140
Hexachloro-1,3-butadiene ug/L 19.320 97 60-140
Isopropylbenzene (Cumene)ug/L 22.520 113 60-140
m&p-Xylene ug/L 45.740 114 60-140
Methyl-tert-butyl ether ug/L 23.120 116 60-140
Methylene Chloride ug/L 24.620 123 60-140
n-Butylbenzene ug/L 24.920 124 60-140
n-Propylbenzene ug/L 23.420 117 60-140
Naphthalene ug/L 20.020 100 60-140
o-Xylene ug/L 21.920 110 60-140
sec-Butylbenzene ug/L 23.420 117 60-140
Styrene ug/L 22.620 113 60-140
tert-Amyl Alcohol ug/L 398400 100 60-140
tert-Amylmethyl ether ug/L 43.140 108 60-140
tert-Butyl Alcohol ug/L 194200 97 60-140
tert-Butyl Formate ug/L 144160 90 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 44
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4243637LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butylbenzene ug/L 18.220 91 60-140
Tetrachloroethene ug/L 19.620 98 60-140
Toluene ug/L 21.620 108 60-140
trans-1,2-Dichloroethene ug/L 26.720 134 60-140
trans-1,3-Dichloropropene ug/L 21.720 108 60-140
Trichloroethene ug/L 21.220 106 60-140
Trichlorofluoromethane ug/L 23.120 115 60-140
Vinyl chloride ug/L 23.020 115 60-140
1,2-Dichloroethane-d4 (S)%118 70-130
4-Bromofluorobenzene (S)%106 70-130
Toluene-d8 (S)%102 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4243638MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92703238004
4243639
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 110 60-140110 0 3020ND22.1 22.1
1,1,1-Trichloroethane ug/L 20 135 60-140133 1 3020ND26.9 26.5
1,1,2,2-Tetrachloroethane ug/L 20 122 60-140121 0 3020ND24.4 24.3
1,1,2-Trichloroethane ug/L 20 121 60-140119 2 3020ND24.2 23.8
1,1-Dichloroethane ug/L M12014360-140139 3 3020ND28.6 27.7
1,1-Dichloroethene ug/L M12014760-140142 3 3020ND29.4 28.4
1,1-Dichloropropene ug/L M12015660-140153 2 3020ND31.2 30.5
1,2,3-Trichlorobenzene ug/L 20 86 60-14087 0 3020ND17.3 17.3
1,2,3-Trichloropropane ug/L 20 116 60-140117 1 3020ND23.2 23.3
1,2,4-Trichlorobenzene ug/L 20 92 60-14094 2 3020ND18.4 18.8
1,2,4-Trimethylbenzene ug/L 20 127 60-140124 2 30202.1 27.5 26.9
1,2-Dibromo-3-
chloropropane ug/L 20 96 60-14098 2 3020ND19.2 19.6
1,2-Dibromoethane (EDB)ug/L 20 118 60-140118 1 3020ND23.7 23.5
1,2-Dichlorobenzene ug/L 20 112 60-140110 2 3020ND22.3 22.0
1,2-Dichloroethane ug/L 20 139 60-140136 2 3020ND27.9 27.2
1,2-Dichloropropane ug/L 20 130 60-140129 1 3020ND26.0 25.7
1,3,5-Trimethylbenzene ug/L 20 125 60-140120 4 30201.2 26.1 25.2
1,3-Dichlorobenzene ug/L 20 113 60-140111 2 3020ND22.5 22.1
1,3-Dichloropropane ug/L 20 120 60-140118 1 3020ND23.9 23.7
1,4-Dichlorobenzene ug/L 20 111 60-140110 1 3020ND22.2 22.0
2,2-Dichloropropane ug/L 20 133 60-140131 2 3020ND26.7 26.2
2-Chlorotoluene ug/L 20 124 60-140123 1 3020ND24.9 24.7
4-Chlorotoluene ug/L 20 123 60-140123 0 3020ND24.6 24.5
Benzene ug/L 20 126 60-140123 3 3020ND25.3 24.6
Bromobenzene ug/L 20 108 60-140108 1 3020ND21.7 21.5
Bromochloromethane ug/L 20 130 60-140129 1 3020ND25.9 25.8
Bromodichloromethane ug/L 20 118 60-140117 1 3020ND23.7 23.4
Bromoform ug/L 20 96 60-14096 0 3020ND19.2 19.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 44
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4243638MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92703238004
4243639
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Bromomethane ug/L 20 117 60-140114 2 3020ND23.4 22.9
Carbon tetrachloride ug/L 20 116 60-140114 2 3020ND23.2 22.8
Chlorobenzene ug/L 20 116 60-140114 2 3020ND23.2 22.8
Chloroethane ug/L M12014960-140143 4 3020ND29.9 28.6
Chloroform ug/L 20 138 60-140135 2 3020ND27.5 27.0
Chloromethane ug/L 20 132 60-140129 2 3020ND26.4 25.9
cis-1,2-Dichloroethene ug/L M12014260-140140 1 3020ND28.3 28.0
cis-1,3-Dichloropropene ug/L 20 116 60-140114 2 3020ND23.2 22.8
Dibromochloromethane ug/L 20 110 60-140109 1 3020ND22.0 21.8
Dibromomethane ug/L 20 103 60-140102 1 3020ND20.5 20.3
Dichlorodifluoromethane ug/L 20 121 60-140117 3 3020ND24.1 23.4
Diisopropyl ether ug/L 20 133 60-140130 2 3020ND26.5 26.0
Ethanol ug/L 800 125 60-140125 1 30800ND9971000
Ethyl-tert-butyl ether ug/L 40 127 60-140124 2 3040ND50.7 49.6
Ethylbenzene ug/L 20 121 60-140119 1 3020ND24.2 23.9
Hexachloro-1,3-butadiene ug/L 20 104 60-140102 2 3020ND20.9 20.4
Isopropylbenzene
(Cumene)ug/L 20 123 60-140121 2 3020ND24.7 24.2
m&p-Xylene ug/L 40 124 60-140122 1 3040ND49.6 48.9
Methyl-tert-butyl ether ug/L 20 123 60-140120 3 3020ND24.6 24.0
Methylene Chloride ug/L 20 134 60-140129 4 3020ND26.7 25.7
n-Butylbenzene ug/L 20 136 60-140132 3 3020ND27.2 26.4
n-Propylbenzene ug/L 20 125 60-140123 1 3020ND24.9 24.6
Naphthalene ug/L 20 92 60-14096 5 3020ND18.8 19.7
o-Xylene ug/L 20 116 60-140115 1 3020ND23.3 22.9
sec-Butylbenzene ug/L 20 127 60-140124 3 3020ND25.4 24.7
Styrene ug/L 20 119 60-140119 0 3020ND23.8 23.8
tert-Amyl Alcohol ug/L 400 98 60-14096 2 30400ND393386
tert-Amylmethyl ether ug/L 40 113 60-140111 2 3040ND45.4 44.5
tert-Butyl Alcohol ug/L 200 108 60-140114 6 30200ND216229
tert-Butyl Formate ug/L P51607160-14057 22 30160ND11391.1
tert-Butylbenzene ug/L 20 98 60-14095 3 3020ND19.5 19.0
Tetrachloroethene ug/L 20 107 60-140106 1 3020ND21.4 21.3
Toluene ug/L 20 118 60-140115 3 3020ND23.6 23.0
trans-1,2-Dichloroethene ug/L M12015160-140145 3 3020ND30.1 29.1
trans-1,3-Dichloropropene ug/L 20 117 60-140115 2 3020ND23.4 23.0
Trichloroethene ug/L 20 118 60-140114 3 3020ND23.6 22.8
Trichlorofluoromethane ug/L 20 131 60-140125 4 3020ND26.1 25.1
Vinyl chloride ug/L 20 126 60-140123 2 3020ND25.1 24.6
1,2-Dichloroethane-d4 (S)%121 70-130119
4-Bromofluorobenzene (S)%107 70-130108
Toluene-d8 (S)%102 70-130101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 44
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The EPA or method required sample preservation degrades this compound, therefore acceptable recoveries may not be
achieved in sample matrix spikes.P5
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92702751
CK 0828 CHARLOTTE, NC
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92702751001 819707MW-2 SM 6200B
92702751002 819293MW-3 SM 6200B
92702751003 819293MW-4 SM 6200B
92702751004 819293MW-6 SM 6200B
92702751005 819293MW-12 SM 6200B
92702751006 819293MW-14 SM 6200B
92702751007 819293TW-1 SM 6200B
92702751008 819828TW-2 SM 6200B
92702751009 819293AS-1 SM 6200B
92702751010 819293AS-2 SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/15/2023 04:00 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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