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HomeMy WebLinkAbout24007_Wright's Executive Sales II_Vapor Mitigation Design_20220930C ECS SOUTHEAST, LLP "Setting the Standard for Service" Geotechnical • Construction Materials • Environmental • Facilities NC Registered Engineering Firm F-1078 NC Registered Geologists Finn C-553 SC Registered Engineering Firm 3239 September 30, 2022 Brownfields Property Management Unit North Carolina Department of Environmental Quality Division of Waste Management — Brownfields Program 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Reference: Vapor Intrusion Mitigation Design Wright's Executive Sales 721 and 723 Rigsbee Avenue; 620 and 616 Foster Street Durham, Durham County, North Carolina Brownfields Project No. 24007-20-032 ECS Project No. 49:10039-B To Whom it May Concern: ECS Southeast, LLP (ECS) has facilitated the preparation of the attached Vapor Intrusion Mitigation Design for the proposed multi -family development at the above -referenced site. Except as described in the enclosed Vapor Intrusion Mitigation Design, the remainder of the proposed development for the above -referenced site does not require vapor mitigation. This design has been developed at the request of GeerHouse Owner, LLC, as required by the North Carolina Department of Environmental Quality (NCDEQ) Division of Waste Management (DWM) Brownfields Program (the Program). ECS appreciates the opportunity to work with the Program. If there are questions regarding this report, or a need for further information, please contact us. Respectfully submitted, ECS SOUTHEAST, LLP Samantha M. Sz asits, G.I.T. Staff Environmental Project Manager sszakasits@ecslimited.com 919-861-9910 t Tom Longo Senior Designer tlongo@ecslimited.com 404-329-9006 James C. Bevers, P.E. Environmental Project Manager ibevers@ecslimited.com 828-785-4179 Scott M. Werley, P.G. Environmental Principal swerlev@ecslimited.com 919-861-9846 cc: Mr. John Sunter; GeerHouse Owner, LLC; 1805 7" Street NW Suite 800, Washington, D.C. 20001; jsunter@fourpointsllc.com ECS Capitol Services, PLLC • ECS Florida, LLC • ECS Mid -Atlantic, LLC • ECS Midwest, LLC • ECS Southeast, LLP • ECS Southwest, LLP www.ecslimited.com 7M VAPOR INTRUSION MITIGATION DESIGN WRIGHT'S EXECUTIVE SALES 721 AND 723 RIGSBEE AVENUE; 620 AND 616 FOSTER STREET DURHAM, DURHAM COUNTY, NORTH CAROLINA BROWNFIELDS PROJECT NUMBER 24007-20-032 ECS SOUTHEAST, LLP PROJECT 49:10039-B PREPARED FOR: GEERHOUSE OWNER, LLC September 30, 2022 Vapor Intrusion Mitigation Design Durham, Durham County, North Carolina Brownfields Project Number 24007-20-032 ECS Project No. 49:10039-B September 30, 2022 TABLE OF CONTENTS 1.0 INTRODUCTION....................................................................................................................................... 1 2.0 DESIGN BASIS..........................................................................................................................................4 3.0 QUALITY ASSURANCE/QUALITY CONTROL.............................................................................................. 6 4.0 POST-CONSTRUCTION/PRE-OCCUPANCY SYSTEM EFFECTIVENESS TESTING.........................................7 5.0 POST -OCCUPANCY EFFECTIVENESS TESTING..........................................................................................9 6.0 FUTURE TENANTS & BUILDING USES.................................................................................................... 10 7.0 REPORTING........................................................................................................................................... 10 8.0 DESIGN SUBMITTAL EXHIBITS...............................................................................................................11 9.0 SPECIAL CONSIDERATIONS FOR RETROFITS.......................................................................................... 11 MAPS Map 1 Site Topographic Location Map Map 2 Site Features Map Map 3 Sample Location Map Map 4 Soil Sample Location Map with Proposed Development Overlay Map 5 Groundwater Sample Location Map with Proposed Development Overlay Map 6 Soil Gas Sample Location Map with Proposed Development Overlay TABLES Table 1 Summary of Soil Analytical Results Table 2 Summary of Groundwater Analytical Results Table 3 Summary of Soil Gas Analytical Results APPENDICES Appendix A Vapor Mitigation Design Sheets Appendix B Technical and Safety Data Sheets Vapor Intrusion Mitigation Design Durham, Durham County, North Carolina Brownfields Project Number 24007-20-032 ECS Project No. 49:10039-B September 30, 2022 1.0 INTRODUCTION The subject site is located in Durham, Durham County, North Carolina. The site is currently in the North Carolina Brownfields Program (the Program) and is identified as Brownfields Project Number 24007-20- 032. The subject site formerly consisted of five parcels that have later been consolidated into two parcels identified as Durham County Parcel Identification Numbers (PINs) 0822-90-31-8262 and 0821-99-29-7413. The site consists of approximately 2.37 acres of land (Maps 1 and 2). The northeastern portion of the site was originally developed with a commercial building in 1937 for the Moss Bread Company. Records indicate that two underground storage tanks (USTs) were located on the south side of the building for fueling delivery vehicles and below -grade hydraulic lifts were located on the eastern side of the building. The property was then developed and operated as a Lincoln/Mercury Auto Dealership in the 1950s which included a showroom along West Geer Street, automotive repair bays along Rigsbee Avenue, and a wash bay, body shop, spray booth, and greasing bay on the western portion of the property. The western portion of the site was owned by Acme Properties of Durham, LLC. This portion of the site was historically occupied by Uzzle Motor Co, Bobby Insco Realty, and Wings of Eagles Church. Automotive repair activities occurred on this portion of the property and the property was used as a used car lot and developed with a building for office space. An UST was associated with these operations. Future planned redevelopment of the subject site will occur in multiple phases. Phase 1 is currently under construction and includes building infrastructure and streetscape improvements on the northern portion of the site (620 Foster Street and 721 Rigsbee Avenue) including a new mid -rise mixed -use building with residential, retail, restaurant(s), and parking. Phase 1 will also include a community corridor plaza, decks, ramps, paving on the north side of the corridor, and terrace and streetscape improvements at the existing Motorco building. Phase 2 includes building, infrastructure, and streetscape improvements to the southern portion of the property (616 and 620 Foster Street) including a new high-rise mixed -use building with residential, retail, restaurant(s), and parking. Phase 2 will also include paving on the south side of the community corridor and a bridge over the community corridor which will connect the two mixed -use buildings. The planned redevelopment of Phase 1 of the subject site will consist of approximately 203,000 square feet of multifamily space, 13,000 square feet of retail and/or restaurant space, 6,600 square feet of the existing Motorco building, and 90,000 square feet of structured parking space. There will be approximately 220 apartment units in total. Soil, groundwater, and soil gas sampling activities were conducted at the site in October and November 2020. The results of the sampling activities identified volatile organic compounds (VOCs) in excess of the Residential and Non -Residential Vapor Groundwater Screening Level (GWSL) for Vapor Intrusion (VI) in groundwater and above Residential and Non - Residential Vapor Intrusion Screening Levels (VISLs) in exterior and sub -slab soil gas within the footprint of the existing and proposed building footprints. Specifically, following are the results of the soil gas sampling: • Benzene and chloroform were detected at concentrations exceeding their respective Residential VISLs and 1,3-butadiene at a concentration exceeding its Residential and Non -Residential VISLs in exterior soil gas sample SG-1, collected at the location of the proposed northern stairwell and elevator. Vapor Intrusion Mitigation Design Durham, Durham County, North Carolina Brownfields Project Number 24007-20-032 ECS Project No. 49:10039-B September 30, 2022 • Benzene was detected at a concentration exceeding its Residential VISL in exterior soil gas sample SG- 2, collected at the location of the proposed easter stairwell. • Chloroform, ethylbenzene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, and m&p xylenes were detected at concentrations exceeding their respective Residential VISLs in sub -slab soil gas sample SG- 8, collected within the building in the northeast corner of the project footprint. • Benzene was detected at a concentration exceeding its Residential VISL in sub -slab soil gas sample SG-9, collected within the building in the northeast corner of the project footprint. Based on the results, the Program determined that a limited vapor intrusion mitigation system (VIMS) would be required. Maps 3 through 6 depict the sample locations. The results associated with analysis of these samples are provided in Tables 1 through 3. Information regarding potential vapor migration pathways, vapor source areas, and general characteristics are discussed below. The contents of this document contain VIMS design specifications as they relate to the northern elevator of the mixed -use building. Building • The proposed mixed -use building includes a nine -story apartment building and one floor of associated subgrade parking. The subgrade floor (Level 1 on the Vapor Venting Design, Appendix A) will consist primarily of parking area with retail on the western portion of Phase 1. The ground level (Level 2) will consist of parking to the south and central portions and mechanical, electrical, storage, lobby, mail, loading/unloading, and trash areas to the north and west portions of Phase 1. Level 3 will consist of parking, retail, and amenities areas. Level four includes conference rooms, various amenities, parking, and four apartment units. Levels five through nine will consist of apartment units along the perimeter of the proposed building with open-air space in the center of the proposed building. Appendix A includes VIMS design drawings prepared by ECS Southeast, LLP. Figures 11 through 13 of these drawings depict the proposed use of each level. • The building includes a northern elevator and associated stairwell, a set of two western elevators and associated stairwell, and an eastern stairwell. The elevators and stairwells provide access to the residential levels except the stairwell associated with the northern elevator. This stairwell exits on the ground floor for fire code purposes and does not connect to the residential levels. • The building does not include utility shafts that connect to the residential spaces or other enclosed sub -grade spaces. Various portions of Levels 1 through 3 of the building are proposed to be in contact with soils. These areas are depicted on Figures 11 through 13 of the VIMS design drawings. • The foundation of the building will include a 6-inch concrete slab. • Appendix A includes VIMS design drawings prepared by ECS Southeast, LLP. Figure 4 of these drawings shows the area where the VIMS will be installed. See Design Sheet Figure 2 of these drawings for an example of how the vapor barrier of the VIMS will be installed around the elevator's foundation walls. 2 Vapor Intrusion Mitigation Design Durham, Durham County, North Carolina Brownfields Project Number 24007-20-032 ECS Project No. 49:10039-B September 30, 2022 Source Area • Data indicated the presence of 1,3-butadiene, benzene, chloroform, ethylbenzene, 1,2,4- tri methyl benzene, 1,3,5-trimethyl benzene, and xylenes at concentrations above their respective VISLs in the vicinity of the northern most elevator of the proposed mixed -use structure based on the soil gas samples collected during a previous Environmental Assessment conducted by ECS (Report 49:10039-A) dated April 16, 2021. Site Characteristics • Soil gas exceedances were reported near the northern proposed elevator of the future mixed -use building during the October through November 2020 sampling event. Contact Information • Developer GeerHouse Owner, LLC Mr. John Sunter 1805 7t" Street NW, Suite 800 Washington, District of Columbia 20001 jsunter@fourpointsllc.com 301-367-0506 • Consultant ECS Southeast, LLP Mr. James C. Bevers, P.E. 1900 Hendersonville Road, Suite 10 Asheville, North Carolina 28803 Environmental Protect Manager jbevers@ecslimited.com 828-665-2307 • VIMS Installation Contractor Clancy and Theys Construction Company Mr. John Hyzak 421 North Harrington Street, Suite 200 Raleigh, North Carolina 27603 johnhyzak@clancytheys.com 919-834-3601 • Brownfields Project Manager Ms. Holly Samaha-Smith, P.E. 217 West Jones Street Raleigh, North Carolina 27603 holly.samaha@ncdenr.gov 919-707-8238 3 Vapor Intrusion Mitigation Design Durham, Durham County, North Carolina Brownfields Project Number 24007-20-032 ECS Project No. 49:10039-B September 30, 2022 The VIMS detailed herein is designed to mitigate intrusion of subsurface vapors into the subject building from known Brownfields Property contaminants in a manner that is in accordance with the most recent and applicable guidelines including, but not limited to, DWM Vapor Intrusion Guidance, Interstate Technology & Regulatory Council (ITRC) guidance, and American National Standards Institute (ANSI)/American Association of Radon Scientists and Technologists (AARST) standards. The sealing Professional Engineer (PE) below is satisfied that the design81fkilly,prgtective of public health from known Brownfields Property contaminants. ®\��°�N C,ARO<7 ® ,I✓ ••'�SS10 • 9 _ 0 Ny ' PE Signature �e�� SEAL PE Name James C. Bevers 044440 ° � NGIPA Registration Number 044440 ®®�!9q .... .. J����\ State North Carolina Date 2.0 DESIGN BASIS Based on the structural design of the mixed -use structure, a Vapor Mitigation Plan (VMP) has been developed for the site. The VMP is discussed in detail below and the VIMS Design is provided as Appendix A. As stated at the end of Section 1.0 above, the sealing professional engineer is satisfied that the design is fully protective of public health from known Brownfields Property contaminants. The vapor barrier is designed to cover the known site contaminants. The VIMS design was completed in general accordance with applicable portions of ANSI/AARST CC-1000 Soil Gas Control Systems in New Construction of Buildings. Vapor Intrusion Mitigation System Design The VIMS Design includes a combination of a passive mitigation system utilizing an 8-inch wind turbine, 20-mil vapor barrier rated for petroleum hydrocarbons and chlorinated solvents and a passive sub -slab venting system embedded in a minimum 6-inch gas permeable aggregate layer. The passive VIMS will have roof access electrical connections in the event future active service is suggested. Based on the building design details, the building will be a slab -below -grade construction with the slab being approximately six inches thick. The vapor barrier will be installed above the gas permeable aggregate layer immediately beneath and on all four sides of the northern elevator footer only with a direct pathway to occupied space. See Figures 2 and 5 of the VIMS design drawings (Appendix A) for examples of how the VIMS will be installed. In addition, a passive sub -slab venting system will be installed that will be comprised of 4-inch plain- and bell -end Schedule (Sch.) 40 polyvinyl chloride (PVC) 0.010" slotted well screen pipe will be embedded in the stone aggregate around the elevator shaft. The piping around the elector shaft will be connected to a and 4-inch plain- and bell -end Sch. 40 solid PVC vent riser piping via a 4-inch tee. The vent riser will terminate with an 8-inch galvanized wind -driven turbine ventilator. An electrical junction box and a %-inch conduit to a breaker board will be located within 5 feet of the vent riser roof penetration so electric fans may be added to make it an active system should conditions necessitate such a change in the future. Additionally, thirteen (13) sub -slab monitoring points (VaporPins°) will be installed Vapor Intrusion Mitigation Design Durham, Durham County, North Carolina Brownfields Project Number 24007-20-032 ECS Project No. 49:10039-8 September 30, 2022 through the slab to allow for monitoring and system performance measurements without puncturing the vapor barrier. Figure 6 of the VIMS design drawings (Appendix A) show the locations of the VaporPins°. Contaminants of concern at the Brownfields Property will not be utilized in the building materials for the vapor mitigation system with the exception of low-VOC PVC glue. The low-VOC PVC glue will not contain trichloroethylene (TCE) or tetrachloroethylene (PCE). Passive Sub -Slab Venting System The passive sub -slab venting system proposed for use includes a system of 4-inch plain- and bell -end Sch. 40 slotted PVC well screen to be constructed within the gas permeable aggregate beneath the building slab prior to the installation of the vapor barrier. Based on the design specifications, a minimum of 6- inches of a gas permeable aggregate layer (No. 57 stone and free of fines) is to be used as the sub -base beneath and around the elevator shaft. The 4-inch plain- and bell -end Sch. 40 PVC slotted well screen would be embedded within the aggregate layer around the elevator shaft. Appendix B includes technical data for the 4-inch plain- and bell -end Sch. 40 PVC 0.010" slotted well screen components. The purpose of the slotted screen is to allow volatile organic vapors potentially emanating from the surrounding soils to be intercepted and ventilated through the roof vents (Design Sheet Figure 10). The piping will be labeled along the piping runs at intervals no greater than 10 linear feet that state the purpose of the system along with contact information for questions or repairs. The vent pipes will be constructed of 4- inch plain- and bell -end Sch. 40 solid PVC pipe terminating with an 8-inch wind -driven turbine ventilator (or approved alternate) installed on the discharge end of the exhaust stacks above the roof line. After their construction, penetrations of the roof will be sealed to the manufacturer's specifications and local codes. Vapor Barrier A vapor barrier system consisting of VaporBlock° PlusT" 20, a 20-mil seven -layer co -extruded barrier made from polyethylene and ethylene vinyl alcohol copolymer (EVOH) resins to provide impact strength and resistance to gas and moisture transmission. VaporBlock° PlusT" 20 is an underslab/vertical wall barrier designed to restrict naturally occurring gases such as VOCs, radon, and/or methane from migrating through the ground and concrete slab. The vapor barrier will be sealed at the seams, footings, and penetrations with VaporSeal 4-inch Tape (Product Name 5450-66) and Butyl Seal 2-Sided Tape (Common Name TP2BR). Appendix B includes technical and safety data sheets for the vapor barrier and mitigation components. The vapor barrier is to be installed in general accordance with the manufacturer's specifications (Appendix B). Pipe boots will be placed around all penetrations to seal the opening around the pipe penetrations through the floor slab. Pipe boots will be installed in general accordance with the manufacturer's specifications (Appendix B). Contaminants of concern will not be used during the VIMS construction activities, both above and below the slab, with the exception of low-VOC containing PVC glue. The low-VOC PVC glue will not contain TCE or PCE. Please note: If another material is proposed to be used than specified in this section, the PE will need to approve the proposed material and the NCDEQ will be notified of the change. 5 Vapor Intrusion Mitigation Design Durham, Durham County, North Carolina Brownfields Project Number 24007-20-032 ECS Project No. 49:10039-B September 30, 2022 3.0 QUALITY ASSURANCE/QUALITY CONTROL Construction oversight will take place and include observations of the aggregate base, well screen, riser, and vapor barrier installation. Following the installation of the vapor barrier, a System Effectiveness Work Plan describing associated testing will be submitted within 30 days of vapor barrier installation for review and approval by the North Carolina Brownfields Program. The System Effectiveness Work Plan will include the procedure for conducting a pressure field extension (PFE) and a smoke test, using non -toxic smoke underneath the vapor barrier, in general conformance with the manufacturer's recommendations. The test will be conducted to confirm a vapor -tight installation and show areas that may need to be repaired. Inspections, consisting of observations and documentation, of the completed vapor barrier installation (and subsequently checked) by the environmental consultant, will be conducted by a project professional, under the supervision of the PE responsible for the VIMS design, after the gravel/piping has been installed and before pouring the concrete slab. Concrete will not be placed above the VIMS without inspection under the supervision of the design engineer, and NCDEQwill be provided 48-hour (minimum) notice prior to scheduling inspection activities. Observation notes will be recorded in a field log and will include details regarding the barrier installation and sealing at the seams, footings, and penetrations, observations from the smoke testing and documentation of repairs, as needed, and a photographic log. The inspections records consisting of observations and documentation will be submitted to the NCDEQ as part of a VMP report. The differential pressure measurements will be collected between each measurement point and the interior space after the installation of the vapor barrier and upon completion of the building construction to evaluate if conversion to an active system is warranted at a later date. The measurements will be collected during moderate weather conditions using a handheld micro -manometer capable of collecting measurements to the nearest 0.001 inches of water (in-1-12O). The goal of the active system (if warranted) is to create a minimum differential pressure of 0.016 in-H2O or 4 pascals (Pa) across the slab. If differential pressure measurements as outlined above indicate that sub -slab venting is creating less than or equivalent to the target differential across the slab (0.016 inches of water), the deficiency will be discussed with the NCDEQ. A plan to deploy data loggers to continuously monitor differential pressure between indoor air and sub -slab may be required to be submitted to the NCDEQ for review and approval and/or modification of the active sub -slab venting system. The sub -slab venting system's thirteen (13) sub -slab vapor monitoring points (based on the design) will be installed as permanent VaporPins® and will double as pressure measurement and vapor sample points. If subsequent differential pressure testing, indoor air, and/or sub -slab soil gas sample results indicate that the passive mitigation system is not effectively preventing the subsurface vapors from entering the building, the NCDEQ will be consulted to determine if the system is to be switched from passive to active. For example, if the permanent monitoring point sampling detects increasing concentration trends or does not meet the minimum negative pressure differential, the system may be transitioned to active service. 1.1 Vapor Intrusion Mitigation Design Durham, Durham County, North Carolina Brownfields Project Number 24007-20-032 ECS Project No. 49:10039-B September 30, 2022 4.0 POST-CONSTRUCTION/PRE-OCCUPANCY SYSTEM EFFECTIVENESS TESTING Pilot Testing A pilot test will be performed on the VIMS after the vapor barrier and passive sub -slab venting system have been installed and the concrete slab has been poured in order to demonstrate that areas below the slab can be effectively influenced by the piping network. Permanent pressure monitoring points will be installed throughout the piping network prior to pouring of the slab. The location of pressure monitoring points will include, but are not limited to, the remote extents of the system, in areas near the horizontal piping, areas of potential reduced effectiveness based on plumbing piping, near each suction point, and other utilities and/or wall layouts. Based on the results of the pilot test, and with Program approval, the final number of monitoring points may be reduced. The pilot test will consist of using a rated blower to apply a vacuum to the vertical risers while measuring the pressure differential within the permanent vapor monitoring points installed within the interior, as well as the remote extents of the system. The pilot testing activities and findings will be documented, and modifications will be made if the testing indicates additional monitoring or vacuum points are needed to document influence across the targeted area. In the event that a portion of the concrete slab is cut and removed or if a portion of the slab is left open to be poured at a later time (to permit future upfits), communication testing will be performed as described in Section 3.0. This communication testing will be performed after the following events: (1) after the vapor barrier is installed, (2) following completion of up -fit activities, (3) prior to pouring of the concrete pad, and (4) following repair of damage (if any). NCDEQ will be provided 48-hour (minimum) notice priorto scheduling inspection activities. Portions of the system exposed by removal of the concrete and aggregate either for repair of the system or inadvertently exposed due to other repairs or installation of utility lines, the system will be protected from damage from foot traffic and equipment by placing protective plywood sheeting or equal in such areas to prevent damage to the exposed system. While the system is exposed, a scheduled inspection will be conducted. Smoke testing will be performed prior to pouring concrete. If perforations are noted, repairs will be made and the tests will be repeated until a passing test is achieved. In an effort to reduce impacts from potential vapors while this area is exposed and the building is occupied, the time the area is exposed will be limited to the extent practicable and the area will be vented using fans or other means. The area will also be periodically field screened with a photo -ionization detector (PID) calibrated in accordance with the manufacturer's instructions while the system is exposed. If vapors are detected, additional venting will be provided. If portions of the system are damaged, the damaged area will be isolated by capping/sealing to allow for the remainder of the system to continue to operate without short circuiting. Performance Monitoring — Soil Gas and/or Indoor Air Sampling Sub -Slab Soil Gas Sampling Following the completion of the pilot testing and prior to occupancy of the building, three (3) sub -slab soil gas samples will be collected from the thirteen (13) VaporPins° located in the closest proximity to the northern elevator shaft. Figure 6 of the VIMS design drawings in Appendix A show the locations of the VaporPins°. At each location, the concrete slab will be penetrated using a hammer drill and a new flush mount VaporPin° with a new silicon sleeve will be inserted in the concrete slab. The sampling barb of each VaporPin° will be protected/sealed with a silicone cap prior to being sampled. Each sub -slab 7 Vapor Intrusion Mitigation Design Durham, Durham County, North Carolina Brownfields Project Number 24007-20-032 ECS Project No. 49:10039-B September 30, 2022 monitoring point will be equipped with a protective stainless steel threaded cover that screws onto the VaporPin°. The sub -slab monitoring points (VaporPins°) will be installed in general accordance with the manufacturer's recommendations. Assessment activities will be conducted in general accordance with the North Carolina Division of Waste Management (DWM) Vapor Intrusion Guidance. The sub -slab soil gas samples will be collected at a flow rate of 200 milliliters per minute (mL/min) or less using individually certified 1-Liter (L) Summa canisters and paired flow regulators. One duplicate sample will be collected for laboratory analysis for the same parameters as the record samples. Prior to collecting the sub -slab soil gas samples, laboratory grade helium gas will be used as a quality assurance/quality control (QA/QC) measure to confirm the integrity of the probe seal and sampling train (tubing and fittings). A plastic shroud will be placed and sealed over the sampling point and sampling train and purged with helium. The probe point tubing and tracer gas tubing will be placed through the shroud wall via rubber grommets. The shroud will be placed on a foam/rubber gasket and held securely to the slab with a heavy weight. During the purging stage (three volumes of void space [tubing, probe, etc.]), the shroud will be flooded with helium gas via the hose placed through the shroud wall. After the shroud is flooded with helium, a soil vapor sample will be collected in a Tedlar® bag. The concentration of helium in the Tedlar° bag will be measured using a Model MGD-2002 Multi -Gas Leak detector or similar device The measurement will be recorded for each purge volume. The Tedlar® bag will be evacuated during each asdhelium measurement. A helium concentration of less than ten percent of the helium within the shroud will be considered acceptable. If concentrations greater than ten percent helium are measured, the probe tube seal will be re -sealed, and the leak detection process will be repeated. A successful seal will be determined by three consecutive acceptable helium measurements. During the sampling process, Summa canister vacuum will be maintained above five inches of mercury, and canister vacuums will be recorded by field personnel during sample collection as well as by the laboratory prior to analysis. Measurements of sub -slab vacuum will be collected from the sub -slab monitoring points using a using a handheld manometer capable of collecting measurements to the nearest ±0.001 inches of water. The sub -slab vapor samples will be submitted to a certified laboratory for analysis for VOCs using EPA Method TO-15. ECS will communicate the regulatory screening levels to the laboratory prior to analysis to verify laboratory reporting limits are consistent with these comparison criteria to the extent possible. In addition, ECS will request the laboratory report the "J" flagged detections, if present. The results will be compared to applicable NCDEQ screening criteria. Indoor Air Sampling Following the completion of the pilot testing and prior to occupancy of the building, and if required by Brownfields, three (3) indoor air samples will be collected from the vicinities of the VaporPins® located in the closest proximity to the northern elevator shaft. These sample locations are depicted on Figure 6 of the plans. The samples will be collected using individually certified 6-L Summa canisters equipped with 24-hour flow restrictors. The samples will be collected by placing each Summa canister at a height of approximately 5 feet above the floor during sampling. One duplicate sample will be collected and one exterior (ambient) E-1 Vapor Intrusion Mitigation Design Durham, Durham County, North Carolina Brownfields Project Number 24007-20-032 ECS Project No. 49:10039-B September 30, 2022 air sample will be collected for laboratory analysis for the same parameters as the record samples. During the sampling process, Summa canister vacuum will be maintained above five inches of mercury, and canister vacuums will be recorded by field personnel during sample collection as well as by the laboratory prior to analysis. The indoor air samples will be submitted to a certified laboratory for analysis for VOCs using EPA Method TO-15. ECS will communicate the regulatory screening levels to the laboratory prior to analysis to verify laboratory reporting limits are consistent with these comparison criteria to the extent possible. In addition, ECS will request the laboratory report the "J" flagged detections, if present. The results will be compared to applicable NCDEQ screening criteria. Other Notes The analytical data and vacuum measurements will be provided to NCDEQ promptly after receipt and validation of the data. Sampling reports will be submitted to NCDEQ within approximately 60 days of completion of the sampling. The reports must be submitted to the Brownfields Program for conditional occupancy considerations as per standard Brownfields VI provisions. In the event that impacts are identified above applicable criteria, resampling will be conducted to verify the results. Under no circumstance shall any portion of the building be occupied in any capacity without prior approval of NCDEQ Brownfields Program based on analytical results. This is wholly separate from any local, state, federal requirements/permits. Prior to conducting the above sampling, a work plan will be prepared and approved by the NCDEQ. The information specified in the July 2021 VI Assessment Work Plan & Report Checklist will be included. 5.0 POST -OCCUPANCY EFFECTIVENESS TESTING Sub -Slab Soil Gas Sampling In order to verify the long-term performance and continued effectiveness of the mitigation system, pressure testing will be conducted in accordance with the DWM Vapor Intrusion Guidance using NCDEQ approved vacuum monitoring points installed within the system radius of influence. The measurements will be collected using a handheld manometer capable of collecting measurements to the nearest ±0.001 inches of water. The soil gas sampling will be conducted per the method as described in Section 3.0, performance monitoring. Based on the data collected, recommendations will be made and discussed with the NCDEQ regarding future sampling. Indoor Air Sampling If required by Brownfields, indoor air samples will be collected immediately prior to the collection of post - occupancy soil gas samples in order to minimize the potential for soil gas extracted during sampling to interfere with indoor air analytical results. The locations of the indoor air sampling will be determined in consultation with the NCDEQ Brownfields Program. The indoor air sampling will be conducted per the method as described in Section 3.0, performance monitoring. If an abbreviated target analyte list is desired to be reported by the laboratory, the selected list will need to be approved by the NCDEQ Brownfields Program and will be based on previous detections in soil, groundwater, and soil vapor sample results. 9 Vapor Intrusion Mitigation Design Durham, Durham County, North Carolina Brownfields Project Number 24007-20-032 ECS Project No. 49:10039-B September 30, 2022 Other Notes Prior to conducting the above sampling, a work plan will be prepared and approved by the NCDEQ. The information specified in the July 2021 VI Assessment Work Plan & Report Checklist will be included. 6.0 FUTURE TENANTS & BUILDING USES Based on the floor plan provided, the vent risers for the VIMS are planned to be constructed within the CMU walls (Figures 5 through 9). The vent riser will be properly secured to the wall every 8 feet or as per local building codes. If piping is exposed to the occupants then exposed pipes will be labeled with a label stating "Vapor Intrusion Mitigation System" along with the contact information provided above should the occupants have questions, concerns, or would like information regarding VIMS. If the property is sold or undergoes a use change, then the prospective new owners and/or tenants will be informed of the VIMS at the time of negotiations. The prospective new owners and/or tenants will be made aware that the VIMS is not to be exposed without the oversight of a qualified PE and if the VIMS is damaged, then repairs are to be conducted under the oversight of a qualified PE. If the VIMS is exposed, the same inspection requirements and reporting is required as for the initial installation as provided in Section 3.0 of this Vapor Intrusion Mitigation Design document. The portion of the system accessible on the roof will be visually inspected annually and the inspection results will be reported in the annual Land Use Restriction Update (LURU). 7.0 REPORTING Following confirmation that the mitigation system is installed, effective, and operating properly and completion of initial post -construction testing as outlined in Sections 4.0 and 5.0, a report documenting installation of the mitigation system will be submitted to the Program within 60 days and will be certified a North Carolina PE. The report will include the following: • A summary of the QA/QC measures and post-construction/pre-occupancy system effectiveness testing. • A statement from the PE providing an opinion of whether the VIMS was delivered in a condition consistent with the VIMS design and objectives. Deviations from this Design will be documented in the statement. Certain components, including pressure measurements, soil gas sampling, and indoor air sampling, can be conducted and reported under a NC licensed Professional Geolgist seal. • Appendices to include at a minimum: as -build drawings signed and sealed by the PE, inspection logs including photographs and field logs, and an index of, and individual safety data sheets for, any materials used during construction that could contribute to background indoor air contamination. • PE sealed statement regarding the system effectiveness verbatim as follows: "The Vapor Intrusion Mitigation System (VIMS) detailed herein is designed to mitigate intrusion of subsurface vapors into the subject building from known Brownfields Property contaminants in a manner that is in accordance with the most recent and applicable guidelines including, but not limited to, DWM Vapor Intrusion Guidance, Interstate Technology & Regulatory Council (ITRC) guidance, and American National Standards Institute (ANSI)/American Association of Radon Scientists and Technologists (AARST) 10 Vapor Intrusion Mitigation Design Durham, Durham County, North Carolina Brownfields Project Number 24007-20-032 ECS Project No. 49:10039-B September 30, 2022 standards. The sealing professional engineer below is satisfied that the design [add "and its installation" for use in an installation report] is [are] fully protective of public health from known Brownfields Property contaminants." Note that observations of the mitigation system (installed and initially checked by the environmental consultant) will be performed by or under supervision of the PE certifying the report. The Program will be notified a minimum of 48-hours' notice prior to each site visit performed to observe the completed installation of the VIMS. Observation notes for portions of the mitigation system installation in each area, including field logs, installer certification, Safety Data Sheets for components of the vapor mitigation system, results of the smoke testing, and photographic documentation will be included as appendices to the installation report. The installation report and the initial sampling report will be submitted to the Program for review and approval in order to obtain conditional occupancy determination. 8.0 DESIGN SUBMITTAL EXHIBITS The design submittal exhibits are included in Appendix A and Appendix B. 9.0 SPECIAL CONSIDERATIONS FOR RETROFITS This section is not applicable to this as the design is for a new building. 11 MAPS i 5-rt� Cft Lw APPROXIMATE BROWNFIELD PROPERTY BOUNDARY SOURCE: NMAP 1 USGS TOPOGRAPHIC MAP SITE TOPOGRAPHIC LOCATION MAP 7.5 MINUTE SERIES NORTHWEST DURHAM, NC (TOP) Wright's Executive Sales SOUTHWEST DURHAM, NC (BOTTOM) Brownfields Project Number 24007-20-032 DATED: 2019 721 & 723 Rigsbee Ave; 620 & 616 Foster St. SCALE: 1 : 24,000 Durham, Durham County, North Carolina CONTOUR INVERVAL = 10 feet TM ECS Project Number: 49-10039-B Retail & Restaurant Properties i' 1;� • Retail & Restaurant Properties The Mothership & Motorco GEER STREET Retail & Restaurant VL Properties r .r ACME Plumbing r & Heating F. L r 7r e Auto Base Yoga Repair _ Studio w co i I ui U) O W CORPORATION STREET i rr T a_ r. 4 — r Retail & Restaurant ` Properties Lew w w m U LEGEND ' SITE PROPERTY BOUNDARY ^ SOURCE: MAP 2 SITE FEATURES MAP GOOGLE EARTH 2O21 AERIAL PHOTOGRAPH Wright's Executive Sales Brownfields Project Number 24007-20-032 APPROXIMATE SCALE: 721 & 723 Rigsbee Ave; 620 & 616 Foster St. = 100 feet Durham, Durham County, North Carolina TM ECS Project Number: 49-10039-B � T 1�• 1 J r Apx 8-1 lo{ a91c, . Apx hwrOorFrq WeILs Ali _ sS• r' '� .� r r r_� • �.r : r , � 1� } 1� SG-1 ® — ® r SS-7 , r 55-9 ,! SG-9 i 55-8 f xr ® SG-7 SS-10 +� r 1 • � rend 1 � i ,• '� � � SG-6 d : s �. ® SG-2 Arks f i # # SS-2/Gb � ' # ' SS-5/GW-5 • ® { — -10 ,. SS-4/G W-4 •{ SG-11 � 1' J 4 _ SG-5 • SG-4 SG-3 — {T SS-3/GW-3 LEGEND SITE PROPERTY BOUNDARY 1 SUB -SLAB SOIL GAS SAMPLE LOCATION 0 ® SOIL GAS SAMPLE LOCATION _ F'�ad '� ® GROUNDWATER & SOIL SAMPLE LOCATION ' Lea- : r:: '-: _ _)1t3KMbu. GeaEro,icutea_ ® SOIL SAMPLE LOCATION GROUNDWATER SAMPLE LOCATION N MAP 3 SOURCE: SAMPLE LOCATION MAP ECS Southeast, LLP Phase I ESA, December 6, 2019 Wright's Executive Sales Brownfields Project Number 24007-20-032 APPROXIMATE SCALE: 721 & 723 Rigsbee Ave; 620 & 616 Foster St. SO FT. Durham, Durham County, North Carolina TM ECS Project Number: 49-10039-B 1 i J r Apx g-1 lo{ a91� . — + � - � ,�px hwrr�torFr� WeILs 4,-r- "7 J li r' .� r r r_r • r• IF. y- rr U t'x -. F I■+ I l ' ss- r Bf x RC F and �' � 4• -- i �, � ,LLB.. _ � � �� • ss 4 . �` 1 1 • e II I •rL � �. L�U L # f,:,rQ Irrl��, ' LEGEND .II SITE PROPERTY BOUNDARY Lao- :: r:: 7, _ '-)wJb1GbbU. G2a#EpO, icuteff- SOIL SAMPLE LOCATION N MAP 4 SOURCE: SOIL SAMPLE LOCATION MAP WITH ECS Southeast, LLP PROPOSED DEVELOPMENT OVERLAY Phase I ESA, December 6, 2019 Wright's Executive Sales Brownfields Project Number 24007-20-032 APPROXIMATE SCALE: 721 & 723 Rigsbee Ave; 620 & 616 Foster St. SO FT. Durham, Durham County, North Carolina TM ECS Project Number: 49-10039-B 1 J 4 r Apx g-1 lo{ a91c . + 4 'r + - Apx hWntorFrlq WeILs f 7.- P0 +' 1 tooAli sS r' .� r r r_� •.r : r , i Y r, t -- -------- fT .. X(M r andIII Law— It AF MUM �, -- GW-7 R G — i—p r I ' ! 4 II A' F . .•x � rJ �•� _ 4m a M LEGEND• SITE PROPERTY BOUNDARY _.. III ��.. :. r:: •�. _ ' �-al�ua+�. ��+.�70riCil�#- ® GROUNDWATER SAMPLE LOCATION MAP 5 SOURCE: GROUNDWATER SAMPLE LOCATION MAP ECS Southeast, LLP WITH PROPOSED DEVELOPMENT OVERLAY Phase I ESA, December 6, 2019 Wright's Executive Sales Brownfields Project Number 24007-20-032 APPROXIMATE SCALE: 721 & 723 Rigsbee Ave; 620 & 616 Foster St. SO FT. Durham, Durham County, North Carolina TM ECS Project Number: 49-10039-B I J q r rA?xM7Zr 1 lo{ a91c . - r�tOrFr1q WeILs Alf • ` i U } LJ ti r i Y SG-8Al — +Y f S92 li Arks f .. yam" A k .4p 1 i SG JJ7{ 1 f•- -+� � rr 7 . �? LEGEND F _•.,11 # `' SITE PROPERTY BOUNDARY �y�r SUB -SLAB SOIL GAS SAMPLE LOCATION L3�.. :: r:: •�: _ ' �'allauaJ�. �2�}Ej'O,iCilb9ff- SOIL GAS SAMPLE LOCATION MAP 6 SOURCE: SOIL GAS SAMPLE LOCATION MAP WITH ECS Southeast, LLP PROPOSED DEVELOPMENT OVERLAY Phase I ESA, December 6, 2019 Wright's Executive Sales Brownfields Project Number 24007-20-032 APPROXIMATE SCALE: 721 & 723 Rigsbee Ave; 620 & 616 Foster St. SO FT. Durham, Durham County, North Carolina TM ECS Project Number: 49-10039-B TABLES TABLE 1: SUMMARY OF SOIL ANALYTICAL RESULTS Environmental Assessment - Wrights Executive Sales Brownfields Program Site No. 24007-20-032 721 and 723 Rigsbee Avenue; 620 and 616 Foster Street, Durham, Durham County, North Carolina ECS Project No. 49:10039-A Sample Identification SS-1 SS-2 SS-3 SS-4 SS-5 SS-6 SS-7 SS-8 SS-9 SS-10 DUP-1 DUP-6 IHSB Protection of Groundwater PSRG IHSB Residential Health Based PSRG IHSB Industrial/Commercial Health Based PSRG Sample Date 11/2/2020 10/28/2020 10/27/2020 10/27/2020 10/28/2020 10/27/2020 10/28/2020 10/28/2020 10/27/2020 10/27/2020 10/27/2020 11/2/2020 Sample Depth (feet) 0-5 0-5 0-5 15-20 5-10 10-15 0-5 5-10 0-5 0-5 15-20 0-5 VOCs by EPA 8260 Acetone <0.0088 0.015 0.018 J 0.0093 J 0.031 J 0.011 J 0.033 J <0.0075 <0.0086 <0.0086 <0.0084 0.019 J 25 14,000 210,000 sec -Butyl benzene <0.00084 <0.00077 <0.00078 <0.00074 <0.00076 0.0011 J <0.0022 <0.00071 <0.00082 <0.00082 <0.00080 <0.00086 4.1 1,600 23,000 p-Isopropyltoluene (p-Cymene) <0.00052 <0.00048 <0.00049 <0.00046 <0.00047 0.002 <0.0022 <0.00044 <0.00051 <0.00051 <0.00050 <0.00054 NS NS NS Methylene Chloride <0.0010 <0.00096 <0.00097 <0.00092 <0.00095 <0.00092 <0.022 <0.00089 <0.0010 <0.0010 0.0011 J <0.0011 0.025 58 650 Naphthalene <0.00042 <0.00038 <0.00039 <0.00037 0.0014 J <0.00037 <0.0044 <0.00036 <0.00041 <0.00041 <0.00040 <0.00043 0.39 2.1 8.8 SVOCs by EPA 8270 Benzo(a)anthracene <0.12 <0.1 <0.13 0.17 J <0.12 <0.13 <0.1' <0. -I 0.35 1.1 21 Benzo(a)pyrene <0.1 ` <0.13 <0.1 " 0.20 J <0.12 <0.13 <0.13 <0.13 0.12 0.11 2.1 Benzo(b)fluoranthene <0.12 <0.13 <0.13 0.23 <0.1' <0.13 <0.1 <0.13 1.2 1.1 21 Benzo(g,h,i)perylene <0.12 <0.12 <0.1 ' 0.12 J <0.12 J1 l <0.12 <0.12 <0.1; <0.13 NS NS NS Bis(2- Ethyl hexyl)phthaIate 0.16 J <0.12 14 39 160 Chrysene 0.17 J <0.13 36 110 2,100 Fluoranthene 0.37 <0.12 670 480 6,000 Phenanthrene 0.27 <0.1 ' NS NS NS Pyrene 0.3 <U. l <U. 'l z <U. 'l <0.13 <U. l <U. l J 440 360 4,500 Metals Arsenic 1.4 2.0 0.84 0.94 0.91 0.60 1.0 1.4 1.3 1.6 1.1 0.73 5.8 0.68 3.0 Barium 160 200 160 160 100 300 160 120 45 80 260 100 580 3,100 47,000 Cadmium 0.069 J <O.OF <0.05, <0.0F <0.056 <0.0F 3.0 1.4 20 Chromium (III) as Total 20 36 23 23 18 35 20 25 14 19 41 14 360,000 23,000 350,000 Chromium (VI) 0.41 0.19 J 0.48 0.22 J 0.23 J 0.35 J 0.52 0.43 J 0.40 J 0.13 J 0.30 J 0.12 J 3.8 0.31 6.5 Lead 17 13 15 14 12 12 11 17 11 24 17 7.2 270 NS NS Selenium <0.40 <0.40 <0.39 2.1 78 1,200 Silver 0.062 J 0.054 J 0.054 J 0.041 J 0.047 J 0.050 J 0.058 J 0.068 J <0.035 0.050 J 0.058 J 3.4 78 1,200 Mercury 0.0083 J 0.011 J 0.011 J 0.027 J <0.0081 '0.0089 0.035 0.020 J <0.009^ <0.0096 1.0 2.3 9.7 Notes: mg/Kg = milligrams per kilogram = ppm (parts per million) <0.0088 = Less than the method Detection Limit (DL) as shown on the associated analytical report NS denotes no published standard Soil sample results are compared to the NCDEQ PSRGs dated January 2022 IHSB = Inactive Hazardous Sites Branch PSRG = Preliminary Soil Remediation Goal Bold conentration on sample result indicates and exceedance of the Protection of Groundwater PSRG Underlined conentration on sample result indicates and exceedance of the Residential Health Based PSRG J Flag denotes an estimated concentration between the laboratory Reporting Limit (RL) and the DL DUP-1 is duplicate of SS-4; DUP-6 is duplicate of SS-1 Table 2: Summary of Groundwater Analytical Results Environmental Assessment - Wrights Executive Sales Brownfields Program Site No. 24007-20-032 721 and 723 Rigsbee Avenue; 620 and 616 Foster Street, Durham, Durham County, North Carolina ECS Project No. 49:10039-A Parameter I ANALYTICAL RESULTS Sample ID GW-1 DUP-3 GW-2 GW-3 GW-4 GW-5 GW-6 GW-7 Trip Blank NCAC 2L Groundwater Standards Residential Vapor Intrusion Groundwater Screening Levels Non -Residential Vapor Intrusion Groundwater Screening Levels Collection Date 11/4/2020 11/3/2020 11/16/2020 11/4/2020 METHOD 8260 VOLATILE ORGANIC COMPOUNDS (VOCs) Acetone 12J 14J 33J 4.7 14J 16J 28J 5.9J <0.52 6,000 NS NS tert-Amyl Methyl Ether (TAME) <0.14 <0.14 <0.14 <0.14 <0.14 0.54 <0.14 <0.14 <0.14 128 1,100 4,700 2-Butanone (MEK) <1.9 <1.9 2.8J <1.9 <1.9 2AJ 6.6J <1.9 <1.9 4,000 450,000 1,900,000 tert-Butyl Alcohol (TBA) <4.2 <4.2 <4.2 <4.2 <4.2 <4.2 22 <4.2 <4.2 10 2,800,000 12,000,000 n-Butylbenzene <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 0.30J <0.21 <0.21 70 NS NS sec-Butylbenzene <0.16 <0.16 <0.16 <0.16 <0.16 <0.16 0.38J <0.16 <0.16 70 NS NS tert-Butylbenzene <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.31J <0.17 <0.17 70 NS NS Chlorobenzene <0.15 <0.15 <0.15 2.7 <0.15 <0.15 <0.15 1.0 <0.15 50 82 340 1,3-Dichlorobenzene <0.12 <0.12 0.13J <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 200 NS NS 1,4-Dichlorobenzene <0.13 <0.13 <0.13 0.27J <0.13 <0.13 <0.13 0.15 <0.13 6 2.6 11 1,2-Dichloroethane <0.41 <0.41 <0.41 <0.41 <0.41 2.2 <0.41 <0.41 <0.41 0.4 2.2 9.8 cis-1,2-Dichloroethylene <0.13 <0.13 0.17J <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 70 NS NS Diisopropyl Ether (DIPE) <0.17 <0.17 <0.17 <0.17 0.46J 0.90 0.21J <0.17 <0.17 70 1,400 5,900 Isopropylbenzene (Cumene) <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 1.5 <0.17 <0.17 70 180 750 p-Isopropyltoluene (p-Cymene) <0.20 <0.20 <0.20 <0.20 <0.20 <0.20 0.60J <0.20 <0.20 25 NS NS Methyl tert-Butyl Ether (MTBE) 0.54J 0.61J 0.34J <0.25 <0.25 5.6 <0.25 <0.25 <0.25 20 450 2,000 n-Propylbenzene <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.19J <0.13 <0.13 70 490 2,000 Tetrahydrofuran 1.1 1.1 <0.51 <0.51 <0.51 <0.51 <0.51 <0.51 <0.51 NS 140,000 610,000 Toluene 0.5 0.46 <0.14 <0.14 <0.14 0.70 <0.14 <0.14 <0.14 600 3,800 16,000 Trichloroethylene (TCE) <0.24 <0.24 0.58J <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 3 1.0 4.4 No other targeted VOCs analyzed were detected above their respective method detection limits METHOD 8270D SEMI -VOLATILE ORGANIC COMPOUNDS (SVOCs) Acenaphthene (SIM) <0.034 <0.035 <0.035 0.111 0.039J <0.035 <0.035 <0.034 NA 80 NS NS Anthracene (SIM) <0.033 <0.034 <0.034 <0.033 0.040J <0.034 <0.034 <0.033 NA 2,000 NS NS Di-n-butylphthalate 0.61J 0.51J <0.48 <0.48 <0.49 <0.49 <0.49 <0.47 NA 700 NS NS 1,2-Dichlorobenzene <0.47 <0.48 <0.48 <0.48 <0.49 <0.49 0.50J <0.47 NA 20 530 2,200 Diethylphthalate 5.9J 5.8J <0.24 <0.23 <0.24 1.7J 0.34J <0.23 NA 6,000 NS NS Fluorene (SIM) <0.035 <0.036 <0.036 <0.035 0.044J <0.036 <0.036 <0.035 NA 300 NS NS 3,4-Methylphenol <0.21 <0.21 1.1J 0.50J 1.1J <0.22 <0.22 <0.21 NA NS NS NS Phenanthrene (SIM) <O031 <0.032 <0.032 <0.031 0.04J <0032 0.032J <00031 NA 00 NS NS Phenol <0.20 <0.21 <0.21 <0.21 <0.21 J <0.21 <.20 NA 30 NS NS No other targeted SVOCs analyzed were detected above their respective method detection limits DISSOLVED METALS Arsenic 2.8 2.7 1.6 4.0 4.2 <0.64 <0.64 4.3 NA 10 NS NS Barium 140 140 130 210 520 61 340 170 NA 700 NS NS Cadmium <0.038 <0.038 <0.038 <0.038 <0.038 0.15J <0.038 <0.038 NA 2 NS NS Chromium (III) as Total 0.991 1.3 1.0 2.0 <0.92 1.2 1.6 <0.92 NA 10 NS NS Chromium (VI) <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 NA 10 NS NS Lead <0.085 <0.085 0.11J 0.89 <0.085 0.12J 0.25J 0.13J NA 15 NS NS Selenium 2.7J 2.8J 2.9J <1.6 7.3 <1.6 <0.16 2.5J NA 20 NS NS Silver <0.18 <0.18 <0.18 <0.18 <0.18 <0.18 <0.18 <0.18 NA 20 NS NS Mercu <0.000034 1 <0.000034 1 <0.000034 1 <0.000034 1 <0.000034 <0.000034 <0.000034 <0.000034 1 NA 1 0.18 0.75 Notes: NCAC 2L Groundwater Standards = North Carolina Administrative Code, Title 15A Subchapter 02L Groundwater Standards, April 2022. Residential & Non -Residential Vapor Intrusion Groundwater Screening Levels (GWSLs) , NCDEQ, January 2022. All concentrations are shown in pg/L (micrograms per Liter). NS denotes no published standard NA denotes Not Analyzed Bold denotes concentration that equals or exceeds the NC 2L Groundwater Standards. Underlined concentration on sample result indicated an exceedance of the Residential GWSLs, January 2021. J-Flag = Reported Concentrations are Estimated DUP-3 = Duplicate of GW-1 TABLE 3: SUMMARY OF SOIL GAS ANALYTICAL RESULTS Environmental Assessment- Wrights Executive Sales Brownfelds Program Site No. 24007-20-032 721 and 723 Rigsbee Avenue; 620 and 616 Foster Street, Durham, Durham County, North Carolina ECS Project No. 49:10039-A Parameter ANALYTICAL RESULTS Acceptable Residential Vapor Intrusion Screening Levels Acceptable Non - Residential Vapor Intrusion Screening Levels Location Exterior Sub -Slab Sample ID SGA SG-2 DUP-5 SG-3 I SG-4 I SG-5 I DUP-4 SG-6 I SG-7 SG-8 SG-9 SG-10 SG-11 SG-12 Date Sampled 10/28/2020 11/2/2020 10/29/2020 11/3/2020 10/29/2020 10/28/2020 Acetone 570 400 430 100 140 45 55 24 33 120J 170 38 31 87 NS NS Benzene 25 12 12 1.5 1.5 0.37J <0.19 0.37J <0.19 3.2J 15 0.64 <0.19 0.38J 12 160 1,3-Butadiene 58 <1.6 <1.6 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <2.4 <0.32 <0.32 <0.32 <0.32 3.1 41 2-Butanone MEK 12J 22J 24J 8.81 20J 3.6J 4.6J 5.OJ 5AJ <15 26 5.51 2.8 4.7J 35,000 440,000 Chloroform 13 7.7 7.6 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 13 <0.24 <0.24 <0.24 <0.24 4.1 53 C clohexane 22 <1.7 <1.7 <0.34 12 <0.34 <0.34 10 9.6 200 <0.34 7.9 9.2 14 42,000 530,000 cis-1,2-Dichloroeth Iene 13 <1.3 <1.3 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <2.0 <0.27 <0.27 <0.27 <0.27 NS NS Ethanol 62 64J 69J 19 20 18 18 71 60.0 67J 270 150 81 500 NS NS Eth (benzene 17 17 17 0.78J 0.75J 0.47J <0.18 1.4 1.1 180 5.6 2.6 0.82J 0.63J 37 490 4-Eth (toluene <0.30 <1.5 <1.5 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <2.3 <0.30 2.6 <0.30 <0.30 NS NS He tane 31 23 24 8.0 3.6 1.5 <0.35 <0.35 1.5 81 110 12 <0.35 <0.35 2,800 35,000 Hexane 46 <6.4 <6.4 <1.3 <1.3 <1.3 <1.3 <1.3 25J <9.6 150 15J <1.3 <1.3 4,900 61,000 Iso ro anol <4.5 <23 <23 <4.5 <4.5 <4.5 <4.5 7AJ <4.5 <34 <4.5 21 <4.5 <4.5 1,400 18,000 Methylene Chloride <1.6 <8.0 <8.0 2.1J <1.6 <1.6 <1.6 <1.6 <1.6 <12 3.6J <1.6 <1.6 2.1J 3,400 53,000 Propene, <1.2 <5.8 <5.8 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <8.7 120 <1.2 <1.2 <1.2 21,000 260,000 Styrene <0.24 <1.2 <1.2 0.75J <0.24 <0.24 <0.24 2.4 1.6 <1.8 3.8 1.7 1.4 0.83J 7,000 88,000 Tetrachloroethene PCE 120 <2.2 <2.2 <0.44 <0.44 <0.44 <0.44 0.60J 2.9 <3.3 1.8 0.71J <0.44 2.8 280 3,500 Tetrah drofuran <1.5 <7.3 <7.3 <1.5 <1.5 <1.5 <1.5 <1.5 4.1J <11 <1.5 3.9J <1.5 <1.5 14,000 180,000 Toluene 230 <1.1 180 2.4 4.4 1.1 <0.22 2.8 2.1 <1.6 15 42 1.4 1.5 35,000 440,000 Trichloroethene TCE 13 <2.0 <2.0 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <3.0 <0.40 <0.40 <0.40 <0.40 14 180 Trichlorofluoromethane Freon 11 <0.85 <4.3 <4.3 1 AJ 1.2J 1.5J 1.5J 1.6J I AJ <6.4 <0.85 1.51 <0.85 1.51 NS NS 1,2,4-Trimeth (benzene <0.22 <1.1 <1.1 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 750 <0.22 12 <0.22 <0.22 420 5,300 1,3,5-Trimeth (benzene <0.26 <1.3 <1.3 <0.26 <0.26 <0.26 <0.26 <0.26 <0.26 610 <0.26 4.1 <0.26 <0.26 420 5,300 Vinyl Acetate <2.0 <9.9 <9.9 130 66 <0.20 <2.0 <2.0 <0.20 <15 <2.0 <0.20 12J <2.0 1,400 18,000 m& X Iene 49 54 58 2.0 <0.30 1.4J <0.30 3.9 3.0 830 6.0 9.0 1.9 1.6J 700 8,800 o-Xylene <0.23 <1.2 <1.2 1.3 0.97 0.85J <0.23 1.8 1.3 310 3.5 5.6 0.90 <0.23 700 8,800 Notes: Concentrations are presented in micrograms per cubic meter (pg/m') Bold conentration on sample result indicates and exceedance of the Residential Vapor Intrustion Screening Levels (VISLs), January 2022. Underlined concentration on sample result indicated an exceedance of the Non -Residential VISLs, January 2022. Red Shaded Cells indicate Maximum Laboratory Reported Detection for the Compound. NS = No Standard DUP-4 = Duplicate of Sample SG-5 DUP-5 = Duplicate of Sample SG-2 J Flag denotes an estimated concentration between the laboratory Reporting Limit (RL) and the DL APPENDIX A Vapor Mitigation Design Sheets a Dacian Ave -r� - .. , - �_ wMARKHAM�AVE, o ��� � r� o� (D ELEVATOR 1 / i' V41�Geer St r a uRaaNAVIL E ^� �i _ y � DACIANAYE ` EM, �n v Monmouth Ave SHAFT � s LOCATION: 321- ����Z� 0 W Trinity Ave !!!- �74s 401 � 723 � ' ' � - �ii ""' iF s T •,) W'TRINITY AYE C i MINE !YkAYE �� o j"`� "- WGEERST .� E 55 � J a Ave PROJECT LOCATION �5-„ �id�L _ .�, n 740 _ y� 1 Sur Mgr _ 728 70 t WCORQOR N 619 0 w�6_20 PROJECT '- 721a'' 1726 �. T � y CDDWD STD m � _ ���- V S LOCATION J � �; 6 N _ 70 ) CANALST J l` AYL 98CH _ MALLARD AVE ,., 55 % o B ro a dwa ysf t Hun St : 609 w , 1}' APPROXIMATE PROPERTY BOUNDARY \I 01 o 'V I •y� 10 1 -�?11i Topographic Map Site Vicinity Vapor Venting Design Prepared For: Geerhouse Owner, LLC Site Location: Wright's Executive Sales 721 and 723 Rigsbee Avenue; 620 and 616 Foster Street Durham, Durham County, NC 24007 Brownfields Project Number: 24007-20-032 Date: September 29, 2022 Prepared By: ECS Southeast 5260 Greens Dairy Rd. Raleigh, NC 27616 Aerial Photo DRAFT NOT FOR CONSTRUCTION DRAWING LIST FIGURE DESCRIPTION 0 COVER 1 NOTES 2 DETAILS 3 VAPOR PIN DETAIL/NOTES 4 FOUNDATION PLAN - System Location 5 FOUNDATION -System Layout 6 Vapor Pin Locations 7 LEVEL 2 NORTHEAST - Riser Location 8 LEVEL 3 NORTHEAST - Riser Location 9 LEVEL 4 NORTHEAST - Riser Location 10 LEVEL 5-9 NORTHEAST - Riser Location 11 ROOF NORTHEAST - Riser Location 12 LEVEL 1 AREAS 13 LEVEL 2 AREAS 14 LEVEL 3 AREAS WRIGHT'S EXECUTIVE SALES II VAPOR INTRUSION MITIGATION SYSTEM DESIGN 1. GENERAL 1.1. SUMMARY A. Furnish and install a passive vapor intrusion mitigation system as specified and as shown on the Engineering Drawings. The Contractor shall supply materials required for the installation of a passive vapor intrusion mitigation system capable of being activated at a future time if necessary. The passive vapor intrusion mitigation system shall vent the stone aggregate beneath the elevator footing (as shown of the Engineering Drawings). B. Furnish and install minimum 6" thick stone aggregate layer, free of fines, beneath and on all 4 sides of the elevator shaft. 4"0 plain -and bell -ended slotted schedule 40 PVC piping (well screen) shall be embedded in the stone aggregate around the elevator shaft. The piping around the elevator shaft shall connect to a 4" 0 schedule 40 sanitary tee connecting to a 4" 0 schedule 40 PVC riser. Riser to be mounted to interior wall of the trash chute as depicted in drawings and end above roof line. Riser pipe to terminate at a coupling leading to an 8" galvanized wind drive turbine ventilator. C. Permanent sub -slab vapor monitoring points (Vapor Pins) shall be installed to facilitate future sub -slab soil gas sampling and to monitor sub -slab vacuum with a handheld micro -manometer. D. Install an electrical junction box within 5 feet of the potential in -line fan location and 3/4" conduit to breaker board in the event that an active system is deemed necessary in the future. Outlets and breaker board circuit shall be labeled accordingly. All electrical work shall be completed by a licensed electrical contractor. E. Materials and equipment furnished shall be in new condition and installed in accordance with the manufacturer's recommendations. F. Conduct post -construction testing and certify results of inspections and tests as specified. Sampling reports will be submitted to NCDEQ within approximately 60 days of completion of the sampling. The reports must be submitted to the Brownfields Program for conditional occupancy considerations as per standard Brownfields VI provisions. 1.2 STANDARDS AND REGULATIONS A. Comply with applicable portions of the Building Code of the city of Durham, NC. Where requirements for products, materials, equipment, methods and other portions of the work specified herein exceed minimum requirements of Building Code, Contractor shall comply with such requirements specified herein, unless specifically approved otherwise by the Engineer. 1.3 SUBMITTALS A. Product Data: Submit manufacturer's product data, including installation instructions, for: i. Vapor barrier (VaporBlock Plus 20) ii. Pipes and fittings iii. Slotted well screen iv. Seam tape V. Turbine vi. Pipe boots B. Shop Drawings: Submit shop drawings showing vapor intrusion mitigation system layout, sub -slab vapor monitoring point locations (Vapor Pins), riser locations and termination, and penetration details. Include construction materials and schematic for sub -slab vapor monitoring points. C. Pipe Schedule: Itemize pipe and fitting materials for each specified application. D. Product Samples: Submit representative samples of the following for approval: i. Vapor Barrier VaporBlock Plus 20. 1.4 DELIVERY, STORAGE, AND HANDLING A. Deliver materials to site in good new condition, with labels identifying products and manufacturer. B. Store materials in a clean, dry, UV free area in accordance with manufacturers' instructions. C. Protect materials during handling and installation to prevent damage. D. Properly protect piping to prevent damage to the pipe and the introduction of foreign material into the pipe. E. Inspect vapor barrier, seam tape, pipe, and fittings before installing. Do not install if found to be defective. 2. PRODUCTS 2.1. MATERIALS A. Gas Permeable Aggregate Layer i. Stone aggregate layer shall be No. S7 stone, or equivalent with no more than 5% fines passing through #200 sieve. B. Pipe and Related Accessories i Pipe, fittings, unions, cleanouts, sleeves, supports, and related accessories shall be furnished in accordance with the requirements of the State of North Carolina. ii. Riser pipe shall be 4" schedule 40 PVC. iii. Horizontal pipe shall be 4" schedule 40 PVC plain and slotted well screen. C. Wind -Driven Turbine Ventilator shall be an 8" galvanized wind -driven ventilator. i. Provide additional installation accessories as necessary for a complete passive vapor intrusion mitigation system, ready for future activation if necessary. 3. EXECUTION 2.1. SURFACE PREPARATION A. Prior to installation of the passive vapor intrusion mitigation system, surfaces should be properly prepared and proof -rolled in the presence of an ECS representative.. A. The passive vapor intrusion mitigation system for Geerhouse site shall be installed as specified as shown on the Engineering Drawings. B. Installation of gravel substrate and sub -slab mitigation system: i. The sub -slab slotted well screen vent piping shall be installed as shown on the Engineering Drawings. ii. The layer of gravel surrounding the elevator shaft and around the well screen piping system shall be placed and compacted as shown on the Engineering Drawings. iii. Install the 20mil thick vapor barrier (VaporBlock Plus 20) as shown on the Engineering Drawings and the manufacture specifications. iv. Use products specific to the Engineering Drawings and seal piping at penetrations through the floor slab. Follow Engineering Drawings for connecting sub -slab well screen to vent risers. v. Install Vapor Pins in accordance with the Engineering Drawings. C. Installation of piping/venting: i. The Engineering Drawings and requirements by the State of North Carolina shall be followed with regards to installation of the sub -slab and above slab piping. ii. Pipe fittings shall be as airtight and straight as possible. iii. Non -exposed pipes will be labeled at no greater than 10 foot intervals. F��9 TiS�xiylC�li< A. Protection of the passive vapor intrusion mitigation system is reliant upon the general contractor. No damage or unsealed punctures may occur to the mitigation system throughout the construction process. 3.4 FIELD QUALITY CONTROL A. Under no circumstance shall any portion of the VIMS be covered (piping, gravel, barrier) without an inspection under direction of the Engineer of Record and notification to DEQ. B. NCDEQ will be provided 48-hour (minimum) notice prior to scheduling inspection activities. Inspections of the mitigation system will be performed by or under supervision of Engineer of Record and the party responsible for installation. The installation contractor shall assure the proper coverage and thickness are achieved across the entire area shown in the Engineering Drawings. C. Upon completion of the vapor barrier, sub -slab piping, and concrete slab, a pressure field extension (PFE) test will be performed in order to confirm that necessary areas under the slab can be properly influenced by the vapor intrusion mitigation system. Vapor Pins will be installed throughout the slab to help facilitate the PFE testing. D. Upon completion of the construction of the structure, and as required by the Brownfields Program, soil gas and/or indoor air sampling will be conducted at Vapor Pin locations under the supervision of the Engineer of Record or a Professional Geologist. The number of samples and Vapor Pin locations is to be decided later in conjunction with the environmental consultant and the Brownfields Program. 4. VAPOR BARRIER GENERAL 4.1 SUMMARY A. VaporBlock Plus 20, 20mil thick vapor barrier providing adequate protection from VOC Constituents vapor intrusion. B. VaporBlock Plus 20 vapor barrier is a seven -layer co -extruded barrier made using high quality, virgin -grade polyethylene and EVOH resins, providing adequate protection from VOC constituents vapor intrusion. 4.2 DELIVERY, STORAGE, AND HANDLING A. Deliver materials to site in good new condition, with labels identifying products and manufacturer. B. Store materials in a clean, dry, UV free area in accordance with manufacturers' instructions. C. Protect materials during handling and installation to prevent damage. D. Inspect vapor barrier before installing. Do not install if found to be defective. 4.3 SUBMITTALS A. Submit Safety Data Sheets (SDS) and manufacturer installation instructions. SDS must confirm that VOCs shall not be used in any of the construction materials. B. Laboratory test results showing compliance with ASTM & ACI Standards shall be submitted. Vapor barrier manufacturer's samples, literature, and installation instructions for placement, seaming and penetration repair shall be submitted. C. Warranties i. To be determined by the product used and the manufacturer's warranty, if applicable. 4.4 CA/QC A. Vapor barrier installation contractor shall be properly trained in the installation procedures for the vapor barrier selected. B. General Contractor is responsible for ensuring that vapor intrusion mitigation system (VIMS) is installed as designed. The VIMS will be inspected periodically and on a scheduled basis by either the Engineer of Record or someone directly under his/her supervision. NCDEQ will be provided 48-hour (minimum) notice prior to scheduling inspection activities. S. PRODUCTS 5.1 MATERIALS A. VaporBlock Plus 20 for mitigating tetrachloroethylene and trichloroethylene vapor intrusion. 6. EXECUTION 6.1 EXAMINATION A. Surfaces to receive vapor barrier shall be inspected and approved by the vapor barrier installation contractor at least one day prior to commencing work. Vapor barrier installation contractor shall verify with Owner's Representative the areas for application of vapor barrier. Notify the General Contractor, in writing, of circumstances detrimental to the proper completion of the work. Do not proceed with work until unsatisfactory conditions are corrected and are acceptable for compliance with manufacturer's requirements. 6.2 SURFACE PREPARATION A. Surface preparation shall be conducted in accordance with the manufacturer's specifications. B. Gravel surface below elevator footing shall be compacted and maintain a consistent minimum thickness of 6", in accordance with the Engineering Drawings. Finished gravel surface shall be free from any sharp edges that could damage the vapor barrier. 6.3 INSTALLATION A. General i. Vapor barrier shall be installed after surface preparation has been completed per section 3.2.A and prior to the placement of reinforcing steel or the placing of the concrete slab. Reinforcing steel or other materials such as stakes shall not penetrate the vapor barrier. Steel rebar on top of moisture and vapor barriers shall be installed on chairs that rest on the membranes without damaging them. ii. Vapor barrier shall be installed beneath the elevator footing and immediately adjacent to the side walls as shown in the Engineering Drawings. Vapor barrier shall be sealed to the using VaporSeal 4-inch Tape (Product Name 5450-66) Penetration Sealing iii. Penetrations shall be cleaned. The vapor barrier rolled out onto the compacted sub -grade shall overlap by a minimum of 12". The seam shall be sealed with manufacturer's suggested barrier material, such as specific tapes or mastics. iv. Seal penetrations made through the vapor barrier with manufacturer approved materials or products, with a thickness suitable by the manufacturer. Seals should continue for a minimum of 4" on each side of the penetration to ensure proper sealing. Conduits/utility lines shall be encapsulated by a PVC fitting filled with an appropriate form of VOC-free sealant to ensure migrations of soil gas through the conduit do not occur. Lap vapor barrier over foundations and seal to the vertical stem wall with VaporSeal 4-inch Tape (Product Name 5450-66) and Butyl Seal 2-Sided Tape (Common Name TP2BR). v. All opening, gaps, and joints in floor and wall assemblies in contact with soil or gaps around pipes, toilets, or drains penetrating these assemblies shall be filled or closed with materials that provide a permanent air -tight seal. vi. Repair damaged areas by applying VaporSeal 4-inch Tape directly over the center of the hole or tear until a width of 12 inches is obtained. Apply pressure to create a seal. 6.4 CA/QC A. Inspections of the mitigation system will be performed by or under supervision of the Engineer of Record. NCDEQ will be provided 48-hour (minimum) notice prior to scheduling inspection activities. The installation contractor shall assure the proper coverage and workmanship are achieved across the entire area shown in the Engineering Drawings. If inspections conducted by the Engineer of Record discover inadequate installation, the faults must be rectified prior to continuing work in that area. B. Testing barrier integrity i. Confirmation/Smoke testing ii. Smoke testing shall be conducted by prior to the concrete slab being placed to ensure that the vapor barrier is leak free and will work effectively. The PE shall supervise the smoke testing and NCDEQ will be provided 48-hour (minimum) notice prior to scheduling smoke testing. NOTE: 1. RISER SHALL NOT BE LESS THAN 10 FEET FROM WIND -DRIVEN ANY EXHAUST OR AIR INTAKE FANS URBINE TURBINE VENTILATOR T 2. ADD ROOFTOP BRACING AS REQUIRED 4"0 TO 8"0 RUBBER COUPLING JUNCTION BOX TO ELECTRIC PANEL FOR POSSIBLE SEAL ROOF PENETRATION PER ROOFING z CONVERSION TO ACTIVE SYSTEM MANUFACTURER'S SPECIFICATION - - - -- -- --- -- ci FINISHED ROOF i'cuu'o:.ocaouau boc. :,booaaab000e 00000400000:'a 'o ;r +]O oc=. ,�01, OaC ,o:�ooci�ooa�o:. <oe0000000bba )a0000000a0o< --u000aao aooe"'aooaeooal ;000000000000 0 oP OO00000O0000OGv 00000000000000, O¢: 0000- -00000- 'O0000000000c 00000000000i- JOOO Do000o001 100: ooc n0000000b00000a 00 'o 000e -. ;.i n000a00000an `000000000000 a0000aooaaol )OD'. 000000000000001 ]P OaP=-- .%OOo00000000t. 0O000P0 � 000000004000000b )00 �0"' 0O 00000004040! 0�0000000000vOOC�aL0" %004004tl040000 00O00aO00 0000(4 '': Y04 OOP048POOPOr, , f 1"0.( 0 < n00000000c; p00000000 00000000000001 ?+J0 Oo Goo 00000000000� i0"'0)0000000000(1 0+ 0`0^0^011 00000000C 00000000 0 7000000000001 00000000000 `:000000000u <)4400000004P kA '0'". 00P000000040000000P0000001 1 a00P00PP00''000b000004a0tl00040, "'C0000000 PI PIPING TO BE LABELED ALONG THE PIPING RUNS AT INTERVALS NO GREATER THAN 10 LINEAR FEET THAT STATE "VAPOR MITIGATION SYSTEM" WITH CONTACT INFORMATION FOR QUESTIONS OR REPAIRS. SECURE RISER TO WALL EVERY 8' OR AS PER LOCAL BUILDING CODE (TYPICAL) ELEVATOR WALL FIRE SUPPRESSION COLLAR IN ACCORDANCE WITH LOCAL BUILDING CODES (TYPICAL EACH FLOOR) 4"0 SOLID SCH. 40 PVC PLAIN -AND BELL -END SOIL VAPOR VENT RISER 9TH FLOOR a Soil Gas Vent Riser at Roof 2 4"0 SOLID SCH. 40 PVC PLAIN -AND BELL -END SOIL VAPOR VENT RISER WALL TRASH CHUTE TRASH CHUTE WALL \SECURE RISER TO WALL EVERY 8' OR AS PER LOCAL BUILDING CODE (TYPICAL) c Soil Gas Vent Riser in Trash Chute 2 0 1.25' 2.5' 1/2" = V-0" B Soil Gas Vent Detail 2 V'0 SOLID SCH. 40 'VC PLAIN -AND 3ELL-END SOIL VAPOR ✓ENT RISER VO SCH. 40 PVC TEE ✓APOR BARRIER VAPORBLOCK PLUS 20) TEAL TO ELEVATOR SHAFT WITH MANUFACTURER 4PPROVED MASTIC 6" MIN. GAS PERMEABLE AGGREGATE SUB -BASE _Secure Cover 'rotectiv. Cover Vapor Pin° Silicone Sleeve d iQjn ,Crete i a Slab .' e DCVO c D ODo Oi O D O O O IPB C O pC> i Oho 0 O 0000 OC o Don 0 o 0 c CDO< C) O Do 01 o C-,6 C 0 OCo0 OC 0 0 O 0 CO o O c Do0Do0cDODo0 0 0 o O Co G> O C o 00 O, 00 O 0 O O O O 000000P0Do0 00 o c 0 0 o O co O Oo OC Oo O D D O D O C OD OC >O OC 0 0 0 0 co 00 �o � � �n0 0 0 c Standard Operating Procedure Installation and Extraction of the Vapor Pin® Updated March 16, 2018 Scope: This standard operating procedure describes the installation and extraction of the VAPOR PIN° for use in sub -slab soil -gas sampling. Purpose: The purpose of this procedure is to assure good quality control in field operations and uniformity between field personnel in the use of the VAPOR PIN° for the collection of sub -slab soil -gas samples or pressure readings. Equipment Needed: • Assembled VAPOR PIN® [VAPOR PIN® and silicone sleeve (Figure 1)]; Because of sharp edges, gloves are recommended for sleeve installation; • Hammer drill; • 5/8-inch (16mm) diameter hammer bit (hole must be 5/8-inch (16mm) diameter to ensure seal. It is recommended that you use the drill guide). (HiltiTm TE-YX 5/8" x 22" (400 mm) #00206514 or equivalent); • 1 %-inch (38mm) diameter hammer bit (HiltiTM TE-YX 1 %" x 23" #00293032 or equivalent) for flush mount applications; • %-inch (19mm) diameter bottle brush; • Wet/Dry vacuum with HEPA filter (optional); • VAPOR PIN° installation/extraction tool; • Dead blow hammer; • VAPOR PIN° flush mount cover, if desired; • VAPOR PIN° drilling guide, if desired; • VAPOR PIN° protective cap; and • VOC-free hole patching material (hydraulic cement) and putty knife or trowel for repairing the hole following the extraction of the VAPOR PIN°. Installation Procedure: 1. Check for buried obstacles (pipes, electrical lines, etc.) prior to proceeding. 2. Set up wet/dry vacuum to collect drill cuttings. 3. If a flush mount installation is required, drill a 1 %-inch (38mm) diameter hole at least 1 %-inches (45mm) into the slab. Use of a VAPOR PIN® drilling guide is recommended. 4. Drill a 5/8-inch (16mm) diameter hole through the slab and approximately 1-inch (25mm) into the underlying soil to form a void. Hole must be 5/8-inch (16mm) in diameter to ensure seal. It is recommended that you use the drill guide. 5. Remove the drill bit, brush the hole with the bottle brush, and remove the loose cuttings with the vacuum. 6. Place the lower end of VAPOR PIN° assembly into the drilled hole. Place the small hole located in the handle of the installation/extraction tool over the vapor pin to protect the barb fitting, and tap the vapor pin into place using a dead blow hammer. Make sure the installation/extraction tool is aligned parallel to the vapor pin to avoid damaging the barb fitting. During installation, the silicone sleeve will form a slight bulge between the slab and the VAPOR PIN® shoulder. Place the protective cap on VAPOR PIN® to prevent vapor loss prior to sampling. 7. For flush mount installations, cover the vapor pin with a flush mount cover, using either the plastic cover or the optional stainless -steel Secure Cover. 8. Allow 20 minutes or more (consult applicable guidance for your situation) for the sub -slab soil -gas conditions to re -equilibrate prior to sampling. 9. Remove protective cap and connect sample tubing to the barb fitting of the VAPOR PIN. This connection can be made using a short piece of TygonTM tubing to join the VAPOR PIN° with the Nylaflow tubing. Put the Nylaflow tubing as close to the VAPOR PIN® as possible to minimize contact between soil gas and TygonTM tubing. 10. Conduct leak tests in accordance with applicable guidance. If the method of leak testing is not specified, an alternative can be the use of a water dam and vacuum pump, as described in SOP Leak Testing the VAPOR PIN® via Mechanical Means. For flush -mount installations, distilled water can be poured directly into the 11 /2-inch (38mm) hole. 11. Collect sub -slab soil gas sample or pressure reading. When finished, replace the protective cap and flush mount cover until the next event. If the sampling is complete, extract the VAPOR PIN°. Extraction Procedure: 1. Remove the protective cap, and thread the installation/extraction tool onto the barrel of the VAPOR PIN°. Turn the tool clockwise continuously, don't stop turning, the VAPOR PIN® will feed into the bottom of the installation/extraction tool and will extract from the hole like a wine cork, DO NOT PULL. 2. Fill the void with hydraulic cement and smooth with a trowel or putty knife. • Prior to reuse, remove the silicone sleeve and protective cap and discard. Decontaminate the VAPOR PIN® in a hot water and Alconox° wash, then heat in an oven to a temperature of 265' F (130' C) for 15 to 30 minutes. For both steps, STAINLESS - % hour, BRASS 8 minutes. -2.2 Cb. 71- 71-311 71-81 ­M­ ----- -------- Lr) ------------ 14 Lr) TOC= 343.90' 13 0 CO q ------ F7 L Ce) Ce) ILL LL. IV-77-7 21011 FS 10 -21- TJ$oli T _j 7 SV Q F-7 (4\ I� • 2 9 &) 12 L 12 F, T.11 L -2.1 . . . . . . . . .. . 2 4 (P�s I IIT See Figure 5 L �7, _v-1 I Lj F--- L IF 1 ­0 /L t, : - - ----------- L cl P 17- EP, I F� -1 7 11LA _1 /r\ A 7 7 Z­ L _F 0 E - — 5 94E_ F, _1!Z I L II F,) 1,2 h TF i F -J.— F-1 F f j . L L 1 1 21 1.ff CF El 2 �241111T Lp 1� F� j ----------- --------------------- ................................ - — ----- �2 J ------ 77 86 8 9 8 0 20 7"4� PROJECT #: 49-10039-B Client: Geerhouse Owner, LLC DRAWN BY: TLongo Site Location: Wright's Executive Sales CHECKED BY: SSzakasits 721 and 723 Rigsbee Avenue; 620 and 616 Foster Street PROJECT MGR: SWerley Durham, Durham County, NC 24007 Cos DATE: September 29, 2022 FOUNDATION PLAN Figure REVISED: ---- System Location SCALE: 1"=40' 1 4 PRINTED: 9/29/2022 4:56 PM IC:\OneDrive - ECS Corporate Se"ices\DWG\Projects\49\10039-BWrights\Vap.r MitigationPlan-v4 I _j *y3• _ ,i, 1 S-2.2 F7 F-7 r 71-811 �r 1 13 TOC= 343.90' 1 FOOTING - uuuiru,uuuui ELEVATOR f SHAFT }iy00 L - i 2 uuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuu FOOTING 19 12 -N- 0 2.5' 5' 1/4" = V-0" 14 I b b U-) U-) -VAPOR BARRIER (VAPORBLOCK PLUS 20) (SEAL TO ELEVATOR SHAFT WITH 1►' MANUFACTURER APPROVED MASTIC) co co �4"0 SCH. 40 ELBOW 4 0 SCH. i0 PVC SLOTTED SCREEN 2 -0 1 FS , 4" 0 SCH. 40 PVC TEE I 4" 0 SCH. 40 PVC (VENT RISER) Q (F8) ::1� 20 II ---------------------------------------------------------------� I . _ - - --- -- -- EASi1NG MOfffCC01ERRACi ,. 1 -- - i ElECRiIC NEIOW LOApNGEMRY 1 .BELOW / ❑ = I \ ` � I-TI GMORrCOO—NG � ELEVATORSHAFT 1 1 M=°a �LGw 1 ° 1 PRE -OCCUPANCY SUB -SLAB - - i• SAMPLING LOCATIONS � - w �°° 1 iG 1 ` — — 0 . cl LEVEL 1 UNDERGROUND PARKING 1 - - - - - I w ............... -------•—•— Q. •— ----------0 --•—•-------�------------�-r— -•—•—•—•---------- v m ,^� o REFERrOA-11 Y N —_ • FMiNIFY ; ®Li p I 3 m m V11Y 0 2 I M _ �7 121r 1P��3' ' VAPOR PIN TYPICAL S 8 8 s 3 ( 1 I - a A 1.J LEVEL 1 RETAIL j I b 1 ' R' s s s s s nx ,y3szse L oesv _ _ _ _ _ _ _I S hIR I 201 3i6 s' I . 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BELOW S3 Ix 1 1 uu 'L I / r / 1 1 \ 1 � \ LOBBY BELOW LOADING ENTRY BELOW —iBELOW— — - � i II 1 / \ � 1 , rE31,R R Al 11 _ 2 A 6.7 N 358.00 L8 )4 o C C C- C C C C C 07 �C " 4" 0 SCH. 40 PVC VENT RISER 3 / (IN TRASH CHUTE) 362.70 04 A-3.3 — — 35'-2" 7 - 20'-6" 09 3'-0" 11'-8" ` - 354.56 t9Q 1:21 Ssa 4.85% UP 04 � C C C 0 362.7� 0 25 50 -T- I \ YW 0UP \ I� ST-2 TYPE B Cw 2 CON [HD --------------- HID UP w w VJB - A \ A �\ \ mil I W I "V 2" 1 2 W WB 1p CW 3'W 4"W CW-' �HD UP UP UP Cw I 3'W I � �LLL�-' UP, �'w QJ KS'2"W —2"V KS UP 2" V UP F rs� up-�- -_ _ \ \ v 4"W 4UW 113-2.6 JP- 4UP UP p TYPE B 4v \ it \ If 6" W L v w �-j L 4 1 F 2W 4- I 4"W UP f up _ \ I�\ \ \ - Lj 47W 8W DNUP UP CORRIDOR U� `\ \ \ PC302 NI m no ME' 1, ME" MEM EEI 4' STORAGE MECH STAIR —11 � � EZIFIVATOR U'r LD� III \ �\ �\ �r7911 I)N V 3 = ST03 -YV UP ME I mill III III ill!ml!l No I lillin I lillimill 11 Eli 34 OW- D N HB C 4"0 SCH. 40 PVC VENT RISER S.1 3 (IN TRASH CHUTE) Pam' P - K' Li Lj 1-4 0 25 50 3 � H.2 - H.2 H.z _ 1.1 H.2 H.2 F71 - - - - -2 Q a o Q m II II O 130 ST-2.1 496 SF - - 132 6 0- 2B-2.4 SEE 1 / A-7.6 SIM. SEE 1 / A-7.2 SIM. TYPE 8 i SEE 1 ! A-7.11 SIM. - - -1 -, - - - SEE 1 ! A-7.2 -SIM. 1 Ll SEE 1 ! n 7.11 Sill. Q 10 010 d ob 1284 12M 12".1 1 132-6.1 132-5 132-4 128-6.2 128-1.1 �I Q ® 131-21 130-2 129-2 m m 1 132-62 - - I- m --- 2 - - - Y -1 - 1 • SIM m Y --lr-_l }�_�- - - ® -- 2 0106 - - A�.B - CO RIDOR 4 -67- - A-6.4 - - O 127A `-lf - - l�� - -' 1'-21/2" 26$ 2 33'-11 1/2' • 11 112" 8-7112" 6'-21/2" • _ - 2 I l l l l I 149 TRAS Ab 15 33-6 2 0 • 134-21 � I i I ST03 I I I I I I I I I I I I I 3 I i I 3 STAIR 0 - - - 133-4 �IFTI O O Ll III I�� 133-6.1 133-5 • J n0 2 �� ➢� III YI - - - - - - 7 F_ �I 0 C 4"0 SCH. 40 PVC VENT RISER - r m M M , 3 (IN TRASH CHUTE) 727 ST�.1 590 SF I 0 1 EM RM TYPE B D.2 - I 0 12- SEE 1 /A_7.4 SIM. , 137 135-22 g 2B-1.1 1062 TYPE .1 S I CORRIDOR I 1I I 134 1 B 1.1 720 SF _= I, 135 iB3.T 751 SF z I 1 - m I i I I TYPE B I i TYPE A --- -- ....... D.6 -- -- l(----• �• I ( _ _ I • SEE 1 /A-7.7 SIM. • • 4'-11" 6'-2112" 8'0 1R" 4'-2114" • 135-0.2 135-0.1 135-4 • t I I I 16-0114" i I i 9'-1 12" L 14'-2 3/4" I- • i N 135 � ' 126-2.3 126-3 I M I I 3'-5" g-p^ 3'-714' • All 7 m �' 136-3 136-22 - 126 1.2 I --.-. -- - - .-. - .- - - - - - 0 • 126-0 126-5 � 126 126fi.1 _ 126 2B-6.1 1046 S I O - - - - TYPE B 1 126-6.2 126A I 3 �• I -7.5 136-1 m ' _ _ 126-17 6'-7 112" 4-10 314" 5'-0" 4'-2 1/4" 2'-3" 5'-0" 3-11 314" 5'-8114" 6'-9114" _N - - ----=-=--:- - - - - - - -. - 1364 136 -5 13&6 136 i • 126 -2.2 II 0 2.5 50 I I 23 33'-8114" 24' 0" + _ _ - i i / IDS D� DS i� IDS El- I--- o--- 0--- --��---------�- i i i i aL TPO ROOF MEMBRANE SYSTEM 111 f j lVJ l{'Jl lVJ lV) lV) IVJ lVJ lVJ lV) lVJ lVJ lVl� PIPE VENT THROUGH W Im 4"0SCH. 40 PVC VENT RISER 3 (IN TRASH CHUTE) i O 0 L O 0 � I - DS TYPCA DaWNSPOUT TYPICAL CONDENDER UNIT SEE MEP DRAWINGS TWO LAYERS OF TPO AT WALKING PATH AND UNDER CONDENSING UNITS. e TRASH CHUTE VENTS 1 A-3.3 7 LS.1 DS I 0 25 50 APPROXIMATE AREAS PARKING 24,594 SQ. FT. CORRIDORS STORAGE UTILITY ELEVATORS STAIRS 2, 987 SQ. FT. RETAIL 4,918 SQ. FT. VAPOR MITIGATION AREA 240 SQ. FT. BUILDING IN CONTACT WIT) 33,539 SQ. FT. ELEVATOR SHAFT STAIRWELL APPROXIMATE REAS PARKIN 28,202.90 SQ. FT STORAGE UTILITY ELEVATORS STAIRS 5,503.73 SQ. FT., RETAIL 1, 325.84 SQ. FT. TO BELOW ®OPEN 5,859.E SQ. FT. BUILDI G IN COIN 8519.68 SQ, FT. AREA OF VAPOR BENEATq ELEVAT — — — — EXISTINO MORTC 6,643.6$ SQ. FT. ELEVATOR SHA STAIRWEL& P7 l P9 ail rU P75 I ftEC NiILRYRCGM S ,Q INIERI..'1H 4000R,{SCYRIN SERVICE, I&WRY 1. CGNOGRS[0 B I]YAYJSOYRRV iPANSFgiMER �Bii er SFTPMj 3 RS.i M1t2N 0.]2 I R53 M1 I � 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I 1 1 ❑ I 1 1 I 1 0 1 1 1 � I — 1 0 15 30 APPROXIMATE AREAS PARK/Ng 28,202.90 S . FT ELEVATORS STAIRS 823.84 SQ. T. vvvvvvv AMENITIES vvvv vv 6,555.275 . FT. RETAIL 5,690.72 S . FT. ®OPEN TO BELOW 5,977.44 S . FT. BUILDING 1 CONTACT WITH SOIL 5430.79 SQ.FT. AREA OF V POR MITIGATION BENEATH E EVATOR ON 1ST FLOOR) ELEVATOR HAFT STAIRWELL F.. <<= r-----�--- ------------ ------------------ 11 i �j 1 ` 1 1 1 1 - 1 1 - 1 1 r� 1 _ 1 - - - - - APPENDIX B Technical and Safety Data Sheets VAPORBLOCK! PLUS TM . . VBP20 UNDER -SLAB VAPOR / GAS BARRIER PRODUCT DESCRIPTION VaporBlock® PIusTI is a seven -layer co -extruded barrier made using high quality virgin -grade polyethylene and EVOH resins to provide unmatched impact strength as well as superior resistance to gas and moisture transmission. VaporBlock® PIusTI 20 is more than 100 times less permeable than typical high-performance polyethylene vapor retarders against Methane, Radon, and other harmful VOCs. Tested and verified for unsurpassed protection against BTEX, HS, TCE, PCE, methane, radon, other toxic chemicals and odors. VaporBlock® PIusT'" 20 multi -layer gas barrier is manufactured with the latest EVOH barrier technology to mitigate hazardous vapor intrusion from damaging indoor air quality, and the safety and health of building occupants. VBP20 is one of the most effective underslab gas barriers in the building industry today far exceeding ASTM E-1745 (Plastic Water Vapor Retarders Used in Contact with Soil or Granular Fill Under Concrete Slabs) Class A, B and C requirements. Available in a 20 (Class A) mil thicknesses designed to meet the most stringent requirements. VaporBlock® PIusT'" 20 is produced within the strict guidelines of our ISO 9001 Certified Management System. Ri111111039 VaporBlock® PIusTm 20 resists gas and moisture migration into the building envelop when properly installed to provide protection from toxic/harmful chemicals. It can be installed as part of a passive or active control system extending across the entire building including floors, walls and crawl spaces. When installed as a passive system it is recommended to also include a ventilated system with sump(s) that could be converted to an active control system with properly designed ventilation fans. VaporBlock® PIusTm 20 works to protect your flooring and other moisture -sensitive furnishings in the building's interior from moisture and water vapor migration, greatly reducing condensation, mold and degradation. SIZE & PACKAGING VaporBlock® PIusTm 20 is available in 10' x 150' rolls to maximize coverage. All rolls are folded on heavy-duty cores for ease in handling and installation. Other custom sizes with factory welded seams are available based on minimum volume requirements. Installation instructions and ASTM E-1745 classifications accompany each roll. Under -Slab Vapor/Gas Retarder PRODUCT PART # VaporBlock® PIusT"^ 20................................................................ VBP20 APPLICATIONS Radon Barrier Vapor Intrusion Barrier Methane Barrier Under -Slab Vapor Retarder VOC Barrier Foundation Wall Vapor Retarder Brownfields Barrier ��GJoP g VAPOR lock' T1E ��" UNDERSLA 0 2018 RAVEN INDUSTRIES INC. All rights reserved. VAPORBLOCr PLUS TM vePzo APPEARANCE White/Gold THICKNESS, NOMINAL 20 mil 0.51 mm WEIGHT 102 Ibs/MSF 498 g/m2 CLASSIFICATION ASTM E 1745 CLASS A, B & C ASTM E 154 3 TENSILE STRENGTH Section 9 58 Ibf 102 N (D-882) IMPACT RESISTANCE ASTM D 1709 2600 g ASTM E 154 Section 7 0.0098 Perms 0.0064 Perms PERMEANCE (NEW MATERIAL) ASTM E 96 grain s/(ft2-hr-imHg) g/(24hr•m2•mm Hg) Procedure B ASTM E 154 PERMEANCE (AFTER CONDITIONING) Section 8, E96 0.0079 0.0052 Section 11, E96 0.0079 0.0052 (SAME MEASUREMENT AS ABOVE PERMEANCE) Section 12, E96 0.0097 0.0064 Section 13, E96 0.0113 0.0074 WVTR 0.0040 grains/hr-ft2 0.0028 gm/hr-m2 Procedure B BENZENE PERMEANCE See Note 6 1.13 x 10-10 m2/Sec or 3.62 x 10-13 m/s TOLUENE PERMEANCE See Note 6 1.57 x 10-10 m2/sec or 1.46 x 10-13 m/5 ETHYLBENZENE PERMEANCE See Note 6 1.23 x 10-10 m2/sec or 3.34 x 10-14 m/s M & P-XYLENES PERMEANCE See Note 6 1.17 x 10-10 m2/sec or 3.81 x 10-14 m/5 O-XYLENE PERMEANCE See Note 6 1.10 x 10-10 m2/sec or 3.43 x 10-14 m/s HYDROGEN SULFIDE See Note 9 1.92E-09 m/s TRICHLOROETHYLENE (TCE) See Note 6 7.66 x 10-11 m2/sec or 1.05 x 10-14 m/5 PERCH LOROETHYLENE (PCE) See Note 6 7.22 x 10-11 m2/sec or 1.04 x 10-14 m/s RADON DIFFUSION COEFFIECIENT K124/02/95 < 1.1 x 10-13 m2/s 3.68E-12 m/s METHANE PERMEANCE ASTM D 1434 Gas Transmission Rate (GTR): 0.32 mL/m2•dayatm MAXIMUM STATIC USE TEMPERATURE 180' F 82' C MINIMUM STATIC USE TEMPERATURE - 70' F - 57' C 3 Tests are an average of machine and transverse directions. VaporBlock® PlusTM' Placement 5 Raven Industries performs seam testing at 20" per minute. 6 Aqueous Phase Film Permeance. All instructions on architectural or structural drawings should be reviewed and followed. Permeation of volatile organi, Cump... ds through EvoH Thin Film Membranes and C ... n,ded LDPE/EvoH/ Detailed installation instructions accompany each roll of VaporBlocke Plus'" and can also LLDPE Geumembranes, Mawatters and Rowe, Journal of Geutechnical and Ge.-i--tal September 2015. (Permeation is the Permeation Coefficient adjusted to adual film thickness . Engineering® ASCE/ calculated at 1 kg/m'.) be located at www.ravenefd.com. Thestudy used to determine PCE and TCE is tiled: Ey.1-i not dirtu:ion of PCE& TCE through high pedurmance geumembranes by Di ASTM E-1643 also provides general installation information for vapor retarders. Battista and Rowe, Queens University 8 Feb 2018, 8 The study used to determine diffusion coefficients is titled: Hydroggen Sulfide (H,S) Transport through Simulated Interim Covers with Conventional and Co -Extruded Ethylene -Vinyl Alcohol (EVCH) Geomembranes. W7[7pOC B 1ock@ APOR RETARDER / GAS BARRIER �OCa�M VaporBlock® PIUSTM is a seven -layer co -extruded barrier made using high quality virgin -grade polyethylene and EVOH resins to provide unmatched impact strength as well as superior resistance to gas and moisture transmission. Note: To the best of our knowledge, unless otherwise stated, these are typical property values and are intended as guides only, not as specification W.� limits. Chemical resistance, odor transmission, longevity as well as other performance criteria is not implied or given and actual testing must be performed for applicability in specific applications and/or conditions. RAVEN INDUSTRIES MAKES NO WARRANTIES AS TO THE FITNESS FOR A SPECIFIC USE OR MERCHANTABILITY OF PRODUCTS REFERRED TO, no guarantee of satisfactory results from reliance upon contained information or recommendations and disclaims all liability for resulting loss or damage. Limited Warranty available at www.RavenEFD.com L.t.Y ti RAVEN ENGINEERED FILMS Scan QR Code to download P.O. Box 5107 Sioux Falls, SD 57117-5107 efdsales@ravenind.com current technical data sheets Ph: +1 (605) 335-0174 • TF: +1 (800) 635-3456 www.ravenefd.com Via the Raven website. 0 2018 RAVEN INDUSTRIES INC. All rights reserved. 061318 EFD 1125 TM \V7 o�k7 Pdm��3 PoCDTtsl DERSI_AB VAPOR RETARDER f GAS BARRIER Please Note: Read these instructions thoroughly before installation to ensure proper use of VaporBlock® Fftvb.-M =_ PlusT". ASTM E 1465, ASTM E 2121 and, ASTM E :'_ '•wc 1643 also provide valuable information regarding the""°' .'.z t installation of vapor / gas barriers. When installing this product, contractors shall conform to all applicable wok'h' local, state and federal regulations and laws pertaining to residential and commercial building construction. • When VaporBlock® PIUSTM gas barrier is used as part of an active control system for radon or F � other gas, a ventilation system will be required. `°''„"' c • Ifdesigned as a passive system, it is recommended z, bxu, , v.•rru_ , ' to install a ventilation system that could be converted to an active system if needed. i 'N"""" Materials List:, VaporBlock® PlusT"" Vapor / Gas Barrier FEW M� ^�++� VaporSeall* 4" Seaming Tape 9'"0" � VaporSealTM*12"Seaming/Repair Tape a-F Butyl Seal 2-Sided Tape c«brr.0 �� VaporBoot Plus Pipe Boots 12/Box (recommended) okwM , � �,ba °"°°"'p ��+" nitlUbI*m k"" *x + +� + ° VaporBoot Tape (optional) 1'rvo-�atl c* + f.*h r. 73 � I. � 1 WNIAbAbN W9 �Id*a"'"°f l POUR-N-SEALT"' (optional) 1" Foam Weather Stripping (optional) Elements of a moisture/gas-resistant floor system. General illustration only. Mako® Screed Supports (optional) (Note: This example shows multiple options for waterstop placement. Level and tamp or roll granular base as specified. A base for a gas - reduction system may require a 4" to 6" gas permeable layer of clean coarse aggregate as specified by your architectural or structural drawings after installation of the recommended gas collection system. In this situation, a cushion layer consisting of a non -woven geotextile fabric placed directly under VaporBlock® PlusTM' will help protect the barrier from damage due to possible sharp coarse aggregate. 1.2. Unroll VaporBlock® Plus'" running the longest dimension parallel with the direction of the pour and pull open all folds to full width. (Fig. 1) 1.3. Lap VaporBlock® Plus'" over the footings and seal with Raven Butyl Seal tape at the footing -wall connection. Prime concrete surfaces, when necessary, and assure they are dry and clean prior to applying Raven Butyl Seal Tape. Apply even and firm pressure with a rubber roller. Overlap joints a minimum of 6" and seal overlap with 4" VaporSeal" Tape. When used as a gas barrier, overlap joints a minimum of 12" and seal in-between overlap with an optional 2-sided Raven Butyl Seal Tape. Then seal with 4" VaporSeal'" Tape centered on the overlap seam. (Fig. 2) Fig. 1: VaporBlock® Plus'" Overlapping Roll -out Method VaporSeal-4"Tape Optional Butyl Seal VaporSeal"" 2-Sided Tape 4"Tape 12" —� VaporRelainderApplirgions Gas Barrier Applications Fig. 2: VaporBlock® Plus'" Overlap Joint Sealing Methods FOf Page 1 of 4 1.4. Seal around all plumbing, conduit, support columns or other penetrations that come through the VaporBlock® Plus'" membrane. 1.4a. Method 1: Pipes four inches or smaller can be sealed with Raven VaporBoot Plus preformed pipe boots. VaporBoot Plus preformed pipe boots are formed in steps for 1", 2", 3" and 4" PVC pipe or IPS size and are sold in units of 12 per box (Fig. 3 & 5). Pipe boots may also be fabricated from excess VaporBlock® Plus - membrane (Fig. 4 & 6) and sealed with VaporBoot Tape or VaporSeal'" Tape (sold separately). 1.4b. Method 2: To fabricate pipe boots from VaporBlock® Plus'"" excess material (see Fig. 4 & 6 for A-F): A) Cut a square large enough to overlap 12" in all directions. B) Mark where to cut opening on the center of the square and cut four to eight slices about 3/8" less than the diameter of the pipe. C) Force the square over the pipe leaving the tightly stretched cut area around the bottom of the pipe with approximately a 1/2" of the boot material running vertically up the pipe. (no more than a 112" of stretched boot material is recommended) D) Once boot is positioned, seal the perimeter to the membrane by applying 2-sided Raven Butyl Seal Tape in between the two layers. Secure boot down firmly over the membrane taking care not to have any large folds or creases. E) Use VaporBoot Tape or VaporSealT" Tape to secure the boot to the pipe. VaporBoot Tape (option) — fold tape in half lengthwise, remove half of the release liner and wrap around the pipe allowing 1" extra for overlap sealing. Peel off the second half of the release liner and work the tape outward gradually forming a complete seal. VaporSeaTMT°" Tape (option) - Tape completely around pipe overlapping the VaporBlock® Plus- square to create a tight seal against the pipe. F) Complete the process by taping over the boot perimeter edge with VaporSeal- Tape to create a monolithic membrane between the surface of the slab and gas/moisture sources below and at the slab perimeter. (Fig. 4 & 6) VaporSealT"^ 4" T, Preformed Pipe Boot da VaporBoot Plus Performed Boot Raven Butyl Seal 2-sided Tape C*.— c 1. Cut out one of the preformed boot steps (V to 4"). 2. Tape the underside boot perimeter with 2-sided Butyl Seal Tape. 3. Force the boot over Ad. r- pipe and press tape firmly in place. 4. Use VaporSeal- Tape to secure boot to the pipe. 5. Tape around entire boot ' edge with VaporSealT"" Tape. Method 1 1. Cut a square of VaporBlock® 2. Cut four to eight slices about 3/8" Plus'"" barrier to extend at least less than the diameter of the pipe. 12" from the pipe in all directions. 3. Force over pipe and tape the underside boot perimeter to existing barrier with 2-sided Butyl Seal Tape. 4. Tape over the boot perimeter edge with AMW VaporSealT"" Tape. 5. Use Raven VaporBoot or VaporSealTM' Tape and overlap 1" at the seam. Method 2 Fin_ d Square Material Pipe Boot VaporBoot Flexible Tape VaporSeal- or VaporSealT" 4" Tape 4" Tape 12" LZ VaporBlock& (minimum) JI Material Raven Butyl Seal 2-sided Tape Ci- A Page 2 of 4 1.5. Sealing side -by -side multiple penetrations (option 1); A) Cut a patch large enough to overlap 12" in all directions (Fig. 7) of penetrations. B) Mark where to cut openings and cut four to eight slices about 3/8" less than the diameter of the penetration for each. C) Force patch material over penetration to achieve a tight fit and form a lip. D) Once patch is positioned, seal the perimeter to the membrane by applying 2-sided Raven Butyl Seal Tape in-between the two layers. (Fig. 8) E) After applying Raven Butyl Seal Tape between the patch and membrane, tape around each of the penetrations and the patch with VaporSeal'" 4" tape. (Fig. 9) For additional protection apply POUR-N-SEAL'" or an acceptable polyurethane elastomeric sealant around the penetrations. (Fig. 10) Cut a patch large enough to overlap 12" in all directions and slide over penetrations (Make openings as tight as possible.) CL. 7 After applying Raven Butyl Seal Tape between the patch and membrane, tape around the perimeter of the penetration and the patch with VaporSeal- 4" Tape. ru ru ru ru Fin_ 9 Option 1 Raven Butyl Seal 2-sided Tape Fin A Once the overlay patch is positioned, seal the perimeter to the membrane by applying 2-sided Raven Butyl Seal Tape in-between the two layers. ,r For additional protection apply POUR-N-SEAL'"' or an acceptable polyurethane elastomeric sealant around the penetrations. Fin R Fin 1 n Page 3 of 4 Option 2 1.6. POUR-N-SEALT" method of sealing side -by -side multiple penetrations (option 2); A) Install the vapor barrier as closely as possible to pipe penetrations to minimize the amount of POUR-N-SEAL'' necessary to seal around all penetrations. B) Once barrier is in place, remove soil or other particles with a dry cloth or a fine broom to allow for improved adhesion to the POUR-N- SEALT" liquid. C) Create a dam around the penetration area approximately 2" away from the pipe or other vertical penetrations by removing the release liner from the back of a 1" weather stripping foam and adhere to the vapor barrier. Form a complete circle to contain the POUR-N-SEALT" materials (Fig.11). D) Once mixed, pour contents around the pipe penetrations. If needed, a brush or a flat wooden stick can be used to direct the sealant completely around penetrations creating a complete seal (Fig.12-13). E) DO NOT leave excess POUR-N-SEALT" in plastic container for longer than the time it takes to pour sealant. Fig. 12 1.7. Proper installation requires all holes and openings are repaired prior to placing concrete. When patching small holes, simply cut a 12" long piece of 12" wide VaporSealT" tape. Remove release liner and center over the opening. Apply pressure to create a seal (Fig. 14-15). 1.8. When installing VaporBlock® Plus' around pipe penetrations, vertical columns, electrical ducts and other obstructions, you will find it necessary to cut it to the nearest outside edge. This cut can be easily sealed with 12" wide VaporSeal- tape, by simply centering it over the cut, 6" on either side. Once the tape is placed correctly, apply pressure to assure a complete seal (Fig. 16). Reminder Note: All holes or penetrations through the membrane will need to be patched with 12" VaporSealTM' Tape. C*.- 11 Fig. 13 r;- 1 d E*.- 7 Page 4 of 5 2.1. When installing reinforcing steel and utilities, in addition to the placement of concrete, take precaution to protect VaporBlock® Plus". Carelessness during installation can damage the most puncture —resistant membrane. Sheets of plywood cushioned with geotextile fabric temporarily placed on VaporBlock® Plus- provide for additional protection in high traffic areas including concrete buggies. 2.2. Use only brick -type or chair -type reinforcing bar supports to protect VaporBlock® Plus" from puncture. 2.3. Avoid driving stakes through VaporBlock® PIUSTM. If this cannot be avoided, each individual hole must be repaired per section 1.7. 2.4. To avoid penetrating VaporBlock® PlusTM' when installing screed supports, utilize non -penetrating support, such as the Mako® Screed Support System (Fig. 17). Avoid driving stakes through VaporBlock® PlusT". If this cannot be avoided, each individual hole must be repaired per figures 14-15. 2.5. If a cushion or blotter layer is required in the design between VaporBlock® PIusTm and the slab, additional care should be given if sharp crushed rock is used. Washed rock will provide less chance of damage during placement. Care must be taken to protect blotter layer from precipitation before concrete is placed. VaporBlock® PlusT' Gas & Moisture Barrier can be identified on site as gold/white in color printed in black ink with following logo and classification listing (Fig. 18) VaporBlock® PlusT"" Gas & Moisture Barrier * Patent Pending C;_ 14 ri- 17 Vapor B lock° Plus" Fig. 18 Note: To the best of our knowledge, unless otherwise stated, these are typical property values and are intended as guides only, not as specification limits. Chemical resistance, odor transmission, longevity as well as other performance criteria is not implied or given and actual testing must be performed for applicability in specific applications and/or conditions. RAVEN INDUSTRIES MAKES NO WARRANTIES AS TO THE FITNESS FOR A SPECIFIC USE OR MERCHANTABILITY OF PRODUCTS REFERRED TO, no guarantee of satisfactory results from reliance upon contained information or recommendations and disclaims all liability for resulting loss or damage. Limited Warranty available at wwww.RavenEFD.com ENGINEERED FILMS P.O. Box 5107 Sioux Falls, SD 57117-5107 Ph: +1 (605) 335-0174 • TF: +1 (800) 635-3456 efdsales@ravenind.com www.ravenefd.com © Raven 2016. All Rights Reserved. Page 5 of 5 020316 EFD 1127 ACCESSORIES SEAMING TAPES & OTHER ACCESSORIES FOR PLASTIC SHEETING From tie -down fasteners to field seaming tape, Raven Industries has the accessories you need to maximize your film's versatility and minimize installation time on the job. VaporBondT"' Tape (TVB4) VaporBond'" Tape is a white single -sided tape that combines a heavy-duty, weather - resistant polyethylene backing with an aggressive rubber adhesive. VaporBond'" Tape offers excellent seaming capabilities for our materials with an "Easy Tear' feature to reduce installation time. TVB4 has a WVTR of 0.18 perms per ASTM D3833. Typical applications include vapor retarders, covers and liners. Available in 4" x 210' roll. R25B Tape (112513) R25B Tape is a single -sided aggressive synthetic elastomeric adhesive that bonds instantly to properly prepared polyethylene and polypropylene. The black polymer backing and adhesive is specially formulated to provide years of performance even in direct sunlight. A poly release liner provides for ease of installation. Available in 4" x 100' roll. VaporSeaIT" Tape (TVSP4/TVSP12) Butyl Seal Tape (TP2BR / TP6BR) VaporSeaIT" Tape is a patent pending single- Butyl Seal is a double -sided reinforced sided 7-layer gas barrier tape with a release aggressive black butyl rubber tape used to liner for ease of installation. The backing join panels of polyethylene and polypropylene contains a layer of highly impermeable together by overlapping the edges and EVOH designed to block migration of radon, applying Butyl Seal in between. It is also methane, and VOC's. An aggressive acrylic used to adhere to concrete walls and footings adhesive provides outstanding adhesion to when properly prepared. Butyl Seal is non - polyethylene over a wide temperature range. hardening and flexible. Typical uses include joining, repairing and Available in 2" x 50' and 6" x 50' rolls. sealing gas/moisture barriers. Available in 4" x 160' and 12" x 50' rolls. VaporBootT" Tape (TBOOT) POUR-N-SEAU- (PNS1G) VaporBootT" Tape is a single -sided elastomeric POUR-N-SEAL'"' is a gray two part epoxy butyl tape used to complete pipe boot used to seal around multi -pipe penetrations installations (sealing the boot to the pipe). in areas where pipe boots are not practical, The 100% stretchable butyl adhesive features when installing underslab barriers. The POUR - excellent adhesion values and 3-D stretching N-SEAL'" system installation guide references that can be easily molded to multiple surfaces a 1" x 25 lineal feet adhesive -backed foam to without any creases and folds. form a dam around multi -pipe penetrations Available in 2" x 16.4' roll. to contain POUR-N-SEAL'" during the setting process. The 1 " x 25 ft. adhesive -backed foam is sold seperately as FOAM25. VaporBootTM System (VBOOT) The VaporBootT" System is designed to assist in securing pipe and other penetrations that run vertically through the vapor retarder material. The VaporBootT1 System offers a quick solution and is delivered to the jobsite in a complete package. VaporBoots are produced from high performance VaporBlock® material. Package Contents: 25 - VaporBoots (18" x 18", w/precut center marker) 1 - roll of VaporBoot Tape VaporBootT1 Plus Preformed Pipe Boots (VBPBT) VaporBoot'"' Plus Preformed Pipe Boots are produced from heavy 40 mil co -extruded polyethylene and barrier resins for excellent strength and durability. The preformed boots are stepped to fit 1" to 4" wide pipe penetrations. VaporBootT"" Plus Preformed Pipe Boots are available in quantities of 12 per box. 0 2021 RAVEN INDUSTRIES INC. All rights reserved. ACCESSORIES Dura+Skrim° Reinforced Sandbags Dura*Skrim® reinforced sandbags are used to secure large covers and liners to prevent wind damage. Sandbags are produced with strong Dura*Skrim® 8 & 12 mil reinforced polyethylene. These 15" wide x 24" long bags are designed to hold 35 lbs. Sandbags are also available in other Raven reinforced materials with minimum order requirements. 11.8" Cable Ties are also available. Tie -Down Buttons (BUTI) & Tarp Grabbers (BUTEZ) ®Tie -Down Buttons and Tarp Grabbers help keep plastic sheeting securely in place. Tie -Down Buttons are designed to eliminate traditional grommets in olksheeting up to 10 mil thick and are reusable plastic fittings that are easy to install in any Position. Tarp Grabbers are up to 4 times stronger than a brass grommet and are typically used in heavier plastic sheeting from 10 mil to 30 mil thick. Great for equipment covers, large storage covers and truck tarps. Dura-ClipTM (CLIP11) Raven Welding Rod These full size clips are 11" long and fit most commercial scaffolding. Dura- ClipTM' will securely fasten your poly sheeting to scaffolding, reducing wind whip and increasing the life of your enclosure. The Dura-ClipT" is normally placed about every Tonto the enclosure. Raven Welding Rod is used for field seaming, repairs and detail work, such as installing pipe boots. Packaged in 25 lb spools, it is available in 4mm and 5mm sizes to fit most brands of extrusion guns. Raven Welding Rod is made from a thermally UV stabilized LLDPE resin and is available in both black and white to correspond with the color of geomembranes being utilized. BACKING 6.7 mil Polyethylene 7 mil EVOH/LLDPE 30 mil EPDM 8 mil Multi -Polymer N/A ADHESIVE 3.3 mil Rubber Based 2 mil Acrylic Adhesive 20 mil 17 mil 40 mil Pressure -Sensitive Pressure -Sensitive Butyl Rubber Synthetic Elastomeric Butyl Rubber COLOR White Silver Black Black Black TYPE SIZE ROLLS PER CASE WEIGHT PER CASE ADHESION VALUES PERMS SERVICE TEMP. MIN. APPLICATION TEMP. IDEAL STORAGE TEMP. / HUMIDITY Single Sided 4" x 210' 12 45 Ibs 35 oz. / in. (to steel) 0.081 g/(24h*100 in') -40' F to +180* F 50' F Single Sided 4" x 160' / 12" x 50' 12/4 50 Ibs / 18 Ibs 80 oz. / in. (to steel) 0.014 g/(24h*100 in') -40' F to +190* F 50° F 70* F w/ 40-50 % 60°-80° F w/ 40-60 % Single Sided 2" x 16.4' 64 45 Ibs 145 oz. / in. (to steel) N/A +14' F to +122* F 14' F 70° F w/ 70 % Single Sided 4" x 100' 6 33 Ibs 144 oz. / in. (to steel) <0.005 g/(24h*100 in 2) +20' F to +180* F 35° F 70° F w/ 40-50 % Double Sided 2" x 50'/ 6" x 50' 16/4 47 Ibs / 20 Ibs 88 oz. / in. (to steel) 0.82 g/(24h*100 in 2) 0° F to +170* F 35' F 70* F w/ 40-50 % R r —{• ti r Note: To the best of our knowledge, unless otherwise stated, these are typical property values and are intended as guides only, not as specification �'!: 1• limits. Chemical resistance, odor transmission, longevity as well as other performance criteria is not implied or given and actual testing must ;•_ be performed for applicability in specific applications and/or conditions. RAVEN INDUSTRIES MAKES NO WARRANTIES AS TO THE FITNESS .ti FOR A SPECIFIC USE OR MERCHANTABILITY OF PRODUCTS REFERRED TO, no guarantee of satisfactory results from reliance upon contained information or recommendations and disclaims all liability for resulting loss or damage. Limited Warranty available at www.RavenEFD.com ❑i■ 1 RAVEN ENGINEERED FILMS Scan QR Code to download P.O. Box 5107 Sioux Falls, SD 57117-5107 efdsales@ravenind.com current technical data sheets Ph: +1 (605) 335-0174 • TF: +1 (800) 635-3456 www.ravenefd.com via the Raven website. © 2021 RAVEN INDUSTRIES INC. All rights reserved. 012021 EFD 1103 IDENTIFICATION Product Name Recommended use of the chemical and restrictions on use Identified uses Restrictions on use Company Identification Customer Information Number Emergency Telephone Number SAFETY DATA SHEET 5450-66 5450-66 Pressure Sensitive Adhesive See product data sheet. Raven Industries, Inc — Engineered Films P.O. Box 5107 Sioux Falls, SD 57117-5107 (800) 635-3456 (Monday— Friday 8:00 am to 5:00 pm) http://ravenefd.com/products/accessories CHEMTREC Number Within USA and Canada: +1 (800) 635-3456 Outside USA and Canada: +1 (605) 335-0174 Issue Date March 11, 2016 Supersedes Date This is the first issue. Safety Data Sheet prepared in accordance with OSHA's Hazard Communication Standard (29 CFR 1910.1200) and the Globally Harmonized System of Classification and Labelling of Chemicals (GHS) HAZARD IDENTIFICATION Hazard Classification This product is classified as not hazardous in accordance with the Globally Harmonized System of Classification and Labelling (GHS). Label Elements Hazard Symbols None Signal Word: None Hazard Statements None Precautionary Statements Prevention None Response None Storage None Disposal None Other Hazards None Revision Date: March 11, 2016 Page 1 of 6 Raven Industries, Inc Safety Data Sheet 5450-66 HAZARD IDENTIFICATION Specific Concentration Limits The values listed below represent the percentages of ingredients of unknown toxicity. Acute oral toxicity <10% Acute dermal toxicity <10% Acute inhalation toxicity <10% Acute aquatic toxicity >90% 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms: This product is a mixture. Component CAS Number Concentration Polymers and resins N.A. 10 - 20% 4. FIRST- AID MEASURES Description of necessary first -aid measures Eyes Immediately flood the eye with plenty of water. Obtain medical attention if symptoms persist. Skin Wash skin thoroughly with soap and water. Obtain medical attention if symptoms persist. Ingestion Obtain medical attention immediately. Inhalation Remove person to fresh air if symptoms occur. Seek medical attention if symptoms persist. Most important symptoms/effects, acute and delayed Aside from the information found under Description of necessary first aid measures (above) and Indication of immediate medical attention and special treatment needed, no additional symptoms and effects are anticipated. Indication of immediate medical attention and special treatment needed Notes to Physicians Treat symptomatically. 5. FIRE - FIGHTING MEASURES Suitable Extinguishing Media Water spray, carbon dioxide and dry chemical. Specific hazards arising from the chemical May release hazardous vapors during a fire. Special Protective Actions for Fire -Fighters Wear full protective clothing and self-contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Wear appropriate protective clothing. Revision Date: March 11, 2016 Page 2 of 6 Raven Industries, Inc Safety Data Sheet 5450-66 6. ACCIDENTAL RELEASE MEASURES Environmental Precautions Prevent the material from entering drains or watercourses. Methods and materials for containment and cleaning up Pick up and transfer into suitable containers for recovery or disposal. 7. HANDLING AND STORAGE Precautions for safe handling Wear appropriate protective clothing. Conditions for safe storage Store away from sources of heat or ignition. Storage area should be: cool - dry - well ventilated - out of direct sunlight - away from sources of ignition(heat, sparks, flames, pilot lights) - away from incompatible materials (see Section 10) 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure limits are listed below, if they exist. Appropriate engineering controls No specific measures necessary. Good general room ventilation is expected to be adequate to control airborne levels. Individual protection measures Respiratory Protection Not required under normal conditions of use. Skin Protection Gloves Eye/Face Protection Safety glasses Body Protection Normal work wear. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical State Color Odor Odor Threshold pH Density (g/yd2) Boiling Range/Point (°C/F) Melting Point (°C/F) Flash Point (PMCC) (°C/F) Vapor Pressure Evaporation Rate (BuAc=1) Solubility in Water Solid: Pressure sensitive adhesive coated on a polymer film protected by a release liner Black/Silver None No data available Not applicable No data available Not applicable Not applicable Not applicable Not applicable Not applicable Negligible Revision Date: March 11, 2016 Page 3 of 6 Raven Industries, Inc 9. PHYSICAL AND CHEMICAL PROPERTIES Vapor Density (Air = 1) Not applicable VOC (%) Negligible Partition coefficient (n- Not applicable octanol/water) Viscosity Not applicable Auto -ignition Temperature No data available Decomposition Temperature No data available Upper explosive limit No data available Lower explosive limit No data available Flammability (solid, gas) No data available 10. STABILITY AND REACTIVITY Reactivity Data is not available. Chemical Stability Stable under normal conditions. Possibility of hazardous reactions Hazardous polymerization will not occur. Conditions to Avoid Heat - high temperatures Incompatible Materials Acids — bases — oxidizers Hazardous Decomposition Products Oxides of carbon — asphyxiants 11. TOXICOLOGICAL INFORMATION Acute Toxicity Available data indicates this product is not expected to be acutely toxic Safety Data Sheet 5450-66 Specific Target Organ Toxicity (STOT) — single exposure Available data indicates this product is not expected to cause target organ effects after a single exposure. Specific Target Organ Toxicity (STOT) — repeat exposure Available data indicates this product is not expected to cause target organ effects after repeated exposure. Serious Eye damage/Irritation Available data indicates this product is not expected to cause eye irritation. Skin Corrosion/Irritation Available data indicates this product is not expected to cause skin irritation. Respiratory or Skin Sensitization No relevant studies identified. Revision Date: March 11, 2016 Page 4 of 6 Raven Industries, Inc Safety Data Sheet 5450-66 11. TOXICOLOGICAL INFORMATION Carcinogenicity Not considered carcinogenic by NTP, IARC, and OSHA. Germ Cell Mutagenicity Available data indicates this product is not expected to be mutagenic. Reproductive Toxicity Available data indicates this product is not expected to cause reproductive toxicity or birth defects Aspiration Hazard Not an aspiration hazard. 12. ECOLOGICAL INFORMATION Ecotoxicity No relevant studies identified. Mobility in soil No relevant studies identified. Persistence/Degradability No relevant studies identified. Bioaccumulative Potential No relevant studies identified. Other adverse effects No relevant studies identified. 13. DISPOSAL CONSIDERATIONS Disposal Methods Dispose of in accordance with all applicable local and national regulations. 14. TRANSPORT INFORMATION DOT CFR 172.101 Data Not Regulated UN Proper Shipping Name Not Regulated UN Class None UN Number None UN Packaging Group None Classification for AIR Consult current IATA Regulations prior to shipping by air. Transportation (IATA) Environmental Hazards Not a marine pollutant 15. REGULATORY INFORMATION United States TSCA Inventory All components of this product are in compliance or are exempt from inventory listing requirements of the US Toxic Substance Control Act (TSCA) Chemical Substance Inventory. Revision Date: March 11, 2016 Page 5 of 6 Raven Industries, Inc 15. REGULATORY INFORMATION Safety Data Sheet 5450-66 Canada DSL Inventory All ingredients in this product are listed on or are exempt from listing on the Domestic Substance List (DSL). California Proposition 65 This product contains materials which the State of California has found to cause cancer, birth defects or other reproductive harm. SARA Title III Sect. 311/312 Categorization None SARA Title III Sect. 313 This product contains the following chemicals that are listed in Section 313 at or above de minimis concentrations: None 16. OTHER INFORMATION Legend ACGIH: American Conference of Governmental Industrial Hygienists CAS: Chemical Abstracts Service ECHA: European Chemicals Agency IARC: International Agency for Research on Cancer N/A: Denotes no applicable information found or available NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration PEL: Permissible Exposure Limit SDS: Safety Data Sheet STEL: Short Term Exposure Limit TLV: Threshold Limit Value VOC: Volatile Organic Compounds Revision Date: March 11, 2016 Replaces: This is the first issue. Changes made: Not applicable. Information Source and References This SDS is prepared by Hazard Communication Specialists based on information provided by internal company references. Prepared By: EnviroNet LLC The information and recommendations presented in this SDS are based on sources believed to be accurate. Raven Industries, Inc assumes no liability for the accuracy or completeness of this information. It is the user's responsibility to determine the suitability of the material for their particular purposes. In particular, we make NO WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, with respect to such information, and we assume no liability resulting from its use. Users should ensure that any use or disposal of the material is in accordance with applicable Federal, State, and local laws and regulations. Revision Date: March 11, 2016 Page 6 of 6 QUICK IDENTIFIER (In Plant Common Name) MATERIAL SAFETY DATA SHEET Butyl Seal Tape TP2BR Manufacturer's Emergency 800-635-3456 Name RAVEN INDUSTRIES INC. Telephone Numbers 605-335-0174 Address Other P.O. Box 5107 Sioux Falls, SD 57117 Signature of Person Responsible for Prei Information Common Name: (Used on Label) Butyl Seal Tape CAS (Trade Name Synonyms) TP2BR Numbers Chemical Chemical Name Butyl Rubber Adheasive Family Formula NA Principal Hazardous Component(s) - Chemical and Common Nan Vone Known 1813 "E" Avenue Sioux Falls, SD 57104 September 30, 2005 N/A Isobutylene-Isoprene copolymers Threshold Limit Value (units) Boiling Not Applicable (N/A) Specific N/A Vapor N/A Point Gravity Pressure, mmHg Percent Volatile N/A Vapor N/A Evaporation N/A by Volume (%) Density Rate Solubility in Insoluble in Water Reactivity N/A Water In water Appearance Black, odorless tape, paper release liner and Odor Flash N/A Flammability Limits Lower Upper Auto Ignition N/A Point in Air, by Volume (%) N/A N/A Temperature Extinguisher Media Use water spray, dry chemical or carbon dioxide Special Fire Fighting Proced. Fire fighters should wear a self-contained breathing apparatus when there is a possibility of exposure to smoke, fumes or hazardous decomposition products. If possible, water should be applied as a spray from a fogging nozzle since this material is a surface burning material. Unusual Fire and Explosion Hazards None known Stability Unstable Incompatibility None Known (Materials to Avoid) Hazardous None Known Decomposition Products Hazardous May Occur Conditions N/A Polvmerization Will not Occur X to Avoid Page 2 Part Number: TP2BR Threshold N/A Limit Value Signs and Symptoms of Exposure 1. Acute N/A 2. Chronic Not Determined Overexposure Overexposure Medical Conditions Generally There is a risk of inflammation on the skin for long term continuious contact. Aggravated by Exposure Chemical Listed as Carcinogen National Toxicology Not L.A.R. C. Not OSHA Not or Potential Carcinogen Program Listed Monographs Listed Listed OSHA Permissible None ACGIH Threshold None Other Expos. None Exposure Limit Limit Value Limit Used Emergency and N/A First Aid Procedures 1. Inhalation N/A 2. Eyes N/A 3. Skin Avoid prolonged or repeated skin contact 4. Ingestion N/A SectionPROTECTION INFORMATION Respiratory Protection (Specify Type) N/A Ventilation Local Exhaust Mechanical (General) Special Other N/A N/A N/A N/A N/A Protective None Eye None Gloves Protection Other Protective N/A Clothing or Equipment Section 7 - SPECIAL PRECAUTIONS ANDSPILL LEAK PROCEDURES Precautions to be Taken in Handling and Storage Store in a cool, dry area. Other Precautions None Steps to be Taken in Case Material is Released or Spilled N/A Waste Disposal Methods Observe all federal, state and local laws concerning health and environment. IMPORTANT - Do not leave blank spaces. If information is unavailable, unknown or does not apply, so indicate VAPORBOOT PLUS p/n: VBPBT package contents: 12-each VaporBoot Plus Pipe Boots Check your pipe size and cut the hole size required in the prefabricated VaporBoot Plus Boot. The formed steps are for 1", 2", 3" and 4" S P PVC pipe or IPS size. This will allow the pipe to fit tightly in the hole and the VaporSeaIT" Tap (sold separately) to stretch tightly around the pipe. STEP Turn the boot over and apply 2-sided Raven Butyl Seal Tape (sold separately) to the perimeter of the bottom side. Once the entire perimeter is taped; remove all the release liner. Force the VaporBoot Plus Boot over the penetration and apply pressure to the taped area around the entire perimeter to secure in place. INSTALLATION INSTRUCTIONS 11 Peel off the paper release liner and tape the entire perimeter with VaporSeal- Tape. *FjTo finish boot installation take VaporSeal- Tape and wrap tightly around to seal the boot to the penetration. VaporSealT"� 1111 11I VaporBoot Plus Preformed Boot Butyl Seal 2-Sided Tape Note: To the best of our knowledge, unless otherwise stated, these are typical property values and are intended as guides only, not as specification limits. Chemical resistance, odor transmission, longevity as well as other performance criteria is not implied or given and actual testing must be performed for applicability in specific applications and/or conditions. RAVEN INDUSTRIES MAKES NO WARRANTIES AS TO THE FITNESS FOR A SPECIFIC USE OR MERCHANTABILITY OF PRODUCTS REFERRED TO, no guarantee of satisfactory results from reliance upon contained information or recommendations and disclaims all liability for resulting loss or damage. Limited Warranty available at wwww.RavenEFD.com ENGINEERED FILMS P.O. Box 5107 Sioux Falls, SD 57117-5107 Ph: +1 (605) 335-0174 • TF: +1 (800) 635-3456 efdsales@ravenind.com www.ravenefd.com 020416 EFD 1480 POUR-N-SEAL TM HIGH -STRENGTH EPDXY BONDINGADHESIVE PRODUCT NAME POUR-N-SEAL'"" (P/N: PNS1G) MANUFACTURER Raven Industries, Inc. 821 W. Algonquin Street Sioux Falls, SD 57104 PRODUCT DESCRIPTION POUR-N-SEALT"' is a gray two-part medium viscosity high strength epoxy used to seal around multiple pipe penetrations in tight areas where pipe boots are not practical, when installing VaporBlock® moisture and gas barriers. TECHNICAL DATA Applicable Standards: • ASTM (American Society for Testing and Materials) • ASTM C881 Standard Specification for Epoxy -Resin -Base Bonding Systems for Concrete • ASTM D695 Standard Test Method for Compressive Properties of Rigid Plastics • ASTM D638 Standard Test Method for Tensile Properties of Plastics • ASTM C882 Standard Test method for Bond Strength of Epoxy -Resin Systems Used with Concrete by Slant Shear • ASTM Standard Test Method for Deflection Temperature of Plastics Under Flexural Load in the Edgewise Position • ASTM D570 Standard Test Method for Water Absorption of Plastics MATERIAL PREPARATION Store material overnight to precondition at a temperature between 70' F to 80' F prior to use. INSTALLATION 1. POUR-N-SEALTM is used to seal moisture and gas barriers to multiple pipe penetrations in situations where pipe boots are not able to be installed due to the tight concentration of the pipe penetrations. 2. Install the vapor/gas barrier as close as possible to the penetrations by making a small opening. Effort should be given to minimize large gaps in the barrier next to the penetrations, this will also reduce the amount of POUR-N-SEALTM necessary to complete an acceptable seal. 3. To help concentrate the sealant around the pipe penetration, a dam can be formed around the pipe grouping with an adhesive backed weather stripping foam. One gallon covers 80 sq. ft. at a thickness of 20 mils. 4. Only mix the amount of material that can be used within the pot life of the epoxy, approximately 36 minutes at 73' F. Premix each component prior to combining. Pour "A' and "B" components together and thoroughly mix using a low speed drill with a mixing paddle. Scrape the sides and bottom to assure a consistent blend. 5. Once mixed, pour contents around the pipe penetrations, if needed a brush or flat wooden stick can be used to direct the sealant completely around all penetrations and overlap the moisture/gas barrierto form a continuous seal. Avoid Contact with skin (see SIDS for complete safety precautions). Immediately dispose of any remaining mixed POUR-N-SEALT" epoxy left in th container to avoid excessive heat buildup. 6. Depending upon the temperature. POUR- N-SEAL should be tack free in approximately 5 hours. STORAGE/SHELF LIFE Store in dry environment between 400 F and 80° F (4° C-27° Q. Do not allow product to freeze. Shelf Life: 12 months from date of manufacture in unopened containers properly stored. Protect from moisture. AVAILABILITY Please call your local construction supply distributor for availability of POUR-N-SEALTM or call our toll free number at 800-635-3456. SAFETY POUR-N-SEALT" "B" component contains amines and may cause severe burns upon skin contact for any length of time. Use OSHA -approved personal protective equipment (PPE), including safety glasses, gloves and confined space equipment/ POUR-N-SEAU procedures if applicable. Avoid skin contact; do not ingest. See SIDS for complete safety precautions. For professional use only. WARRANTY Raven Industries, Inc. warrants its products to be free from manufacturing defects and that products meet the published characteristics when tested in accordance with ASTM standards. No other warranties by Raven Industries, Inc. are expressed or implied, including no warranty of merchantability or fitness for a particular purpose. Raven Industries, Inc. will not be liable for damages of any sort resulting from any claimed breach of warranty. Raven Industries' liability under this warranty is limited to replacement of material or refund of sales price of the material. There are no warranties on any product that has exceeded the "shelf life" or "expiration date" printed on the package label. TEST DATA Compressive Strength ASTM D-695 11,070 Compressive Modulus of Elasticity ASTM D-695 370,000 Tensile Strength ASTM D-638 3,480 Tensile Modulus of Elasticity ASTM D-638 429,000 Tensile Elongation ASTM D-638 1.2 % Bond Strength (dry cure) - 2 day ASTM C-882 3,390 Bond Strength (dry cure) - 14 day ASTM C-882 3,600 Shore Hardness D scale 86 D Heat Deflection ASTM D-648 120° F (49° C) Water Absorption ASTM D-570 < 1 % ENGINEERED FILMS P.O. Box 5107 Sioux Falls, SD 57117-5107 Ph: +1 (605) 335-0174 • TF: +1 (800) 635-3456 efdsales@ravenind.com www.ravenefd.com 012116 EFD 1319 POUR- N -S EA LTM p/n: PNS1G INSTALLATION INSTRUCTIONS NOTE: Store in dry environment between 400 F and 801 F (40 C-270 Q. Do not allow product to freeze. Prior to use, keep overnight to precondition at a temperature between 70' F to 80' F. Protect from moisture. STEP 111 Prepare penetration areas that require sealing by cutting VaporBlock® barrier as close to the penetration(s) as possible. Effort should be given to minimize large gaps, this will also reduce the amount of POUR-N-SEALTM' necessary to complete an acceptable seal. To help concentrate the sealant around the pipe penetration, a dam can be formed 2" away from the pipe grouping with an adhesive backed 1" weather stripping foam. Complete the preparation of all areas requiring sealant to maximize the pot life of POUR-N-SEALTM' epoxy, prior to mixing the two components. Once mixed, pour contents around the pipe penetrations, if needed a brush or flat wooden stick can be used to direct the sealant completely around all penetrations and overlap the moisture/gas barrier to form a continuous seal. Immediately dispose of any remaining mixed POUR-N-SEALTM epoxy left in the container to avoid excessive heat buildup. Depending upon the temperature, POUR-N-SEAL'" should be tack free in approximately 5 hours. [STEP Seal any cut openings that were required to install VaporBlock8 around the penetrations with 12" wide VaporSeal'" gas / moisture barrier tape or by overlaying a piece of VaporBlock® centered over the cut and taped around the perimeter. Clean the area to be sealed by removing any debris. Avoid Contact with skin by wearing protective gloves and clothing. Only mix the amount of material that can be used within the pot life of the epoxy, approximately 36 minutes at 73° F. Premix each component prior to combining. Pour "A" and "B" components together and thoroughly mix using a low speed drill with a mixing paddle. Scrape the sides and bottom to assure a consistent blend. If not thoroughly mixed, the set time will be greatly extended. Penetrations should be sealed, once filled, covering the entire surface inside the foam dam. Allow to cure prior to pouring concrete to assure a continuous seal without displacing the POUR-N-SEAL'm epoxy. Leave foam dam in place. See SDS for complete safety precautions. For professional use only. Note: To the best of our knowledge, unless otherwise stated, these are typical property values and are intended as guides only, not as specification limits. Chemical resistance, odor transmission, longevityaswell as other performance criteria is notimplied orgiven and actual testing mustbe performed forapplicability in specific applications and/or conditions. RAVEN INDUSTRIES MAKES NO WARRANTIES AS TO THE FITNESS FOR A SPECIFIC USE OR MERCHANTABILITY OF PRODUCTS REFERRED TO, no guarantee of satisfactory results from reliance upon contained information or recommendations and disclaims all liability for resulting loss or damage. Limited Warranty available at wwww.RavenEFD.com ENGINEERED FILMS P.O. Box 5107 Sioux Falls, SD 57117-5107 Ph: +1 (605) 335-0174 • TF: +1 (800) 635-3456 efdsales@ravenind.com www.ravenefd.com 020516 EFD 1322 Safety Data Sheet POUR-N-SEAL Component A SDS Revision Date: 5/4/2015 1. Identification 1.1. Product identifier Product Identity POUR-N-SEAL Component A Alternate Names Pour-N-Seal Component A 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use See Technical Data Sheet. Application Method See Technical Data Sheet. 1.3. Details of the supplier of the safety data sheet Company Name Company Contacts Raven Industries, Inc. — Engineered Films Division 821 W. Algonquin Street Sioux Falls, SD 57104 Raven Industries INC. Direct: (605) 335-0250 Cindy.heppler@ravenind.com 24 hour Emergency Telephone No. (605) 335-0250 If immediate assistance is not obtained, please call 911. 2. Hazard(s) identification 2.1. Classification of the substance or mixture Skin Irrit. 2;H315 Causes skin irritation. Eye Irrit. 2;H319 Causes serious eye irritation. Skin Sens. 1;H317 May cause an allergic skin reaction. Muta. 2;H341 Suspected of causing genetic defects. Aquatic Chronic 2;H411 Toxic to aquatic life with long lasting effects. 2.2. Label elements Using the Toxicity Data listed in section 11 and 12 the product is labeled as follows. Page 1 of 12 Safety Data Sheet POUR-N-SEAL Component A SDS Revision Date: 5/4/2015 >+< Warning H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H341 Suspected of causing genetic defects. H411 Toxic to aquatic life with long lasting effects. [Prevention]: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P261 Avoid breathing dust / fume / gas / mist / vapors / spray. P264 Wash thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves / eye protection / face protection. [Response]: P302+352 IF ON SKIN: Wash with plenty of soap and water. P305+351+338 IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P308+313 IF exposed or concerned: Get medical advice / attention. P321 Specific treatment (see information on this label). P333+313 If skin irritation or a rash occurs: Get medical advice / attention. P337+313 If eye irritation persists: Get medical advice / attention. P362 Take off contaminated clothing and wash before reuse. P363 Wash contaminated clothing before reuse. P391 Collect spillage. [Storage]: P405 Store locked up. [Disposal]: P501 Dispose of contents / container in accordance with local / national regulations. Page 2 of 12 Safety Data Sheet POUR-N-SEAL Component A SDS Revision Date: 5/4/2015 3. Composition/information on ingredients This product contains the following substances that present a hazard within the meaning of the relevant State and Federal Hazardous Substances regulations. Ingredient/Chemical Designations Weight % GHS Classification Diglycidyl ether of bisphenol A 50 - 75 Eye Irrit. 2;H319 CAS Number: 0025068-38-6 Skin Irrit. 2;H315 Skin Sens. 1;H317 Aquatic Chronic 2;H411 Bisphenol F epoxy resin 25 - 50 Skin Irrit. 2;H315 CAS Number: 0028064-14-4 Eye Irrit. 2;H319 Skin Sens. 1;H317 Aquatic Chronic 2;H411 Oxirane, (butoxymethyl)- 1.0 - 10 Flam. Liq. 3;H226 CAS Number: 0002426-08-6 Muta. 2;H341 Acute Tox. 4;H332 Acute Tox. 4;H302 STOT SE 3;H335 Skin Sens. 1;H317 Aquatic Chronic 3;H412 F— Notes I['] In accordance with paragraph (i) of §1910.1200, the specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. [1] Substance classified with a health or environmental hazard. [2] Substance with a workplace exposure limit. [3] PBT-substance or vPvB-substance. *The full texts of the phrases are shown in Section 16. 1 4. First aid measures 4.1. Description of first aid measures General In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificial respiration. If unconscious place in the recovery position and obtain immediate medical attention. Give nothing by mouth. Eyes Irrigate copiously with clean water for at least 15 minutes, holding the eyelids apart and seek medical attention. Skin Immediately take off all contaminated clothing. For skin contact, wash immediately with soap and water. If irritation persists, get medical attention. Ingestion If swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 4.2. Most important symptoms and effects, both acute and delayed Overview Eyes: Irritating to the eyes Skin: May cause skin irritation; potential sensitizer. Skin inflammation is characterized by itching, scaling and reddening. Page 3 of 12 Safety Data Sheet POUR-N-SEAL Component A SDS Revision Date: 5/4/2015 Inhalation: May cause lung irritation; potential sensitizer Ingestion: Swallowing small amounts of this material during normal handling is unlikely and is not likely to cause harmful effects. Swallowing large amounts may be harmful. Reproductive or genetic defect hazard. See section 2 for further details. Eyes Causes serious eye irritation. 5. Fire -fighting measures 5.1. Extinguishing media Water fog, Carbon Dioxide, Dry Chemical 5.2. Special hazards arising from the substance or mixture Hazardous decomposition: High heat and fire may produce carbon dioxide, carbon monoxide, and oxides of nitrogen. Avoid breathing dust / fume / gas / mist / vapors / spray. 5.3. Advice for fire-fighters Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask. ERG Guide No. ---- 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Put on appropriate personal protective equipment (see section 8). 6.2. Environmental precautions Do not allow spills to enter drains or waterways. Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse. 6.3. Methods and material for containment and cleaning up For major spills call Raven Industries (1-605-336-2750). Clean up should only be performed by trained personnel. People dealing with major spillages should wear full protective clothing including appropriate respiratory protection. Evacuate the area. Prevent further leakage, spillage or entry into drains. Page 4 of 12 Safety Data Sheet POUR-N-SEAL Component A SDS Revision Date: 5/4/2015 7. Handling and storage 7.1. Precautions for safe handling Avoid breathing aerosols, mists and vapors. Avoid contact with skin and eyes. See section 2 for further details. - [Prevention]: 7.2. Conditions for safe storage, including any incompatibilities Handle containers carefully to prevent damage and spillage. Incompatible materials: Water, amines, strong bases, alcohols, metal compounds and surface-active materials If container is exposed to high heat, it can be pressurized and possibly rupture explosively. Keep the container tightly closed and in a cool, well -ventilated place. See section 2 for further details. - [Storage]: 7.3. Specific end use(s) No data available. 8. Exposure controls and personal protection 8.1. Control parameters Exposure AS No. I Ingredient Source Value 0002426-08-6 Oxirane, (butoxymethyl)- OSHA JTWA 50 ppm (270 mg/m3) ACGIH TWA: 3 ppm Skin, S, R, Revised 2005, NIOSH IC 5.6 ppm (30 mg/m3) [15-minute] Supplier INo Established Limit 0025068-38-6 Dig lycidyl ether of bisphenol A OSHA INo Established Limit ACGIH INo Established Limit NIOSH INo Established Limit Supplier INo Established Limit 0028064-14-4 Bisphenol F epoxy resin OSHA INo Established Limit ACGIH No Established Limit NIOSH INo Established Limit Supplier INo Established Limit Page 5 of 12 Safety Data Sheet POUR-N-SEAL Component A SDS Revision Date: 5/4/2015 Carcinogen Data CAS No. Ingredient Source I Value ro_2426 08-6 Oxirane, (butoxymethyl)- OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC IGroup 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0025068-38-6 Diglycidyl ether of bisphenol A OSHA Select Carcinogen: No i NTP Known: No; Suspected: No IARC IGroup 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0028064-14-4 Bisphenol F epoxy resin OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC IGroup 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 8.2. Exposure controls Respiratory When the product is sprayed or heated without adequate ventilation, an approved MSHA/NIOSH positive -pressure, supplied -air respirator may be required. Eyes Wear safety glasses; chemical goggles (if splashing is possible). Skin Protective clothing should be selected. Gloves - neoprene, nitrile rubber, butyl rubber. Thin latex disposable gloves should be avoided for repeated or long-term use. Engineering Controls Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and any vapor below occupational exposure limits suitable respiratory protection must be worn. Other Work Practices Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse. See section 2 for further details. - [Prevention]: 9. Physical and chemical properties Appearance Odor Odor threshold pH Melting point / freezing point Initial boiling point and boiling range Flash Point Evaporation rate (Ether= 1) Flammability (solid, gas) Upper/lower flammability or explosive limits Clear Liquid Sweet Not Measured Not available Not available > 327°F > 200°C Pensky Martin Closed Cup Slower (Butyl Acetate = 1) Not Applicable Lower Explosive Limit: Not available Page 6 of 12 Safety Data Sheet POUR-N-SEAL Component A SDS Revision Date: 5/4/2015 Upper Explosive Limit: Not available Vapor pressure (Pa) Not determined Vapor Density Not available Specific Gravity 1.12 @ 77°F (H20 = 1) Solubility in Water Slight Partition coefficient n-octanol/water (Log Kow) Not Measured Auto -ignition temperature Not available Decomposition temperature Not available Viscosity (cst) Not available VOC Content None 9.2. Other information No other relevant information. 10. Stability and reactivity 10.1. Reactivity Polymerization may occur at elevated temperatures in the presence of alkalis, tertiary amines and metal compounds. 10.2. Chemical stability Stable under normal handling and storage conditions 10.3. Possibility of hazardous reactions No data available. 10.4. Conditions to avoid No data available. 10.5. Incompatible materials Water, amines, strong bases, alcohols, metal compounds and surface-active materials 10.6. Hazardous decomposition products High heat and fire may produce carbon dioxide, carbon monoxide, and oxides of nitrogen. Page 7 of 12 Safety Data Sheet POUR-N-SEAL Component A SDS Revision Date: 5/4/2015 11. Toxicological information Acute toxicity Based on the properties of the epoxy constituents and considering toxicological data on similar preparations this preparation may be an irritant and a skin and respiratory sensitizer. Low molecular weight epoxy constituents are irritating to eyes, mucous membranes and skin. Repeated skin contact may lead to irritation and sensitization, possibly with cross -sensitization to other epoxies. Skin contact with the preparation and exposure to spray mist and vapor should be avoided. Ingredient Oral LD50, Skin LD50, Inhalation Inhalation Inhalation mg/kg mg/kg Vapor LC50, Dust/Mist LC50, Gas LC50, mg/L/4hr mg/L/4hr ppm Diglycidyl ether of bisphenol A - (25068-38-6) > 5,000.00, Rat 20,000.00, No data No data No data - Category: Rabbit - available available available NA Category: NA Bisphenol F epoxy resin - (28064-14-4) 2,000.00, Rat - No data No data No data No data Category:4 available available available available Oxirane, (butoxymethyl)- - (2426-08-6) 1,660.00, Rat - No data No data No data No data Category:4 available available available available Note: When no route specific LD50 data is available for an acute toxin, the converted acute toxicity point estimate was used in the calculation of the product's ATE (Acute Toxicity Estimate). (Classification Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) I Category --- F_ --- F---- Hazard Description (Not Applicable INot Applicable Not Applicable Skin corrosion/irritation 1 2 Icauses skin irritation. Serious eye damage/irritation 2 Icauses serious eye irritation. Respiratory sensitization --- INot Applicable Skin sensitization 1 Imay cause an allergic skin reaction. Germ cell mutagenicity 2 Isuspected of causing genetic defects. Carcinogenicity --- INot Applicable Reproductive toxicity I --- INot Applicable STOT-single exposure --- INot Applicable STOT-repeated exposure --- INot Applicable Aspiration hazard F_____ Not Applicable Page 8 of 12 Safety Data Sheet POUR-N-SEAL Component A SDS Revision Date: 5/4/2015 12. Ecological information 12.1. Toxicity Toxic to aquatic life with long lasting effects. No additional information provided for this product. See Section 3 for chemical specific data. Aquatic Ecotoxicity FIngredient rDiglycidyl ether of bisphenol A - (25068-38-6) IBisphenol F epoxy resin - (28064-14-4) Oxirane, (butoxymethyl)- - (2426-08-6) 96 hr LC50 fish, 48 hr EC50 crustacea, Mg/1 mg/1 F 3.10, Pimephales 1.40, Daphnia magna promelas 12.2. Persistence and degradability There is no data available on the preparation itself. 12.3. Bioaccumulative potential Not Measured 12.4. Mobility in soil No data available. 12.5. Results of PBT and vPvB assessment This product contains no PBT/vPvB chemicals. 12.6. Other adverse effects No data available. 9.00, Oncorhynchus mykiss Not Available 9.00, Daphnia magna 3.90, Daphnia magna 13. Disposal considerations 13.1. Waste treatment methods Observe all federal, state and local regulations when disposing of this substance. 14. Transport information Page 9 of 12 ErC50 algae, mg/I Not Available Not Available Not Available Safety Data Sheet POUR-N-SEAL Component A SDS Revision Date: 5/4/2015 DOT (Domestic Surface IMO / IMDG (Ocean ICAO/IATA Transportation) Transportation) 14.1. UN number Not Applicable Not Regulated Not Regulated 14.2. UN proper shipping Not Regulated Not Regulated Not Regulated name 14.3. Transport hazard DOT Hazard Class: Not IMDG: Not Applicable Air Class: Not Applicable class(es) Applicable Sub Class: Not Applicable 14.4. Packing group Not Applicable Not Applicable Not Applicable 14.5. Environmental hazards IMDG Marine Pollutant: Yes ( Diglycidyl ether of bisphenol A ) 14.6. Special precautions for user No further information 15. Regulatory information Regulatory Overview The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are represented. Toxic Substance All components of this material are either listed or exempt from listing on the TSCA Control Act (TSCA) Inventory. WHMIS Classification D2A US EPA Tier II Hazards Fire: No Sudden Release of Pressure: No Reactive: No Immediate (Acute): Yes Delayed (Chronic): Yes EPCRA 311/312 Chemicals and RQs: To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. EPCRA 302 Extremely Hazardous: To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. EPCRA 313 Toxic Chemicals: To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Proposition 65 - Carcinogens (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Proposition 65 - Developmental Toxins (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Page 10 of 12 Safety Data Sheet POUR-N-SEAL Component A SDS Revision Date: 5/4/2015 Proposition 65 - Female Repro Toxins (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Proposition 65 - Male Repro Toxins (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. New Jersey RTK Substances (>1 %): Oxirane, (butoxymethyl)- Pennsylvania RTK Substances (>1%): Oxirane, (butoxymethyl)- 16. Other information The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and orders. The full text of the phrases appearing in section 3 is: H226 Flammable liquid and vapor. H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H341 Suspected of causing genetic defects. H351 Suspected of causing cancer. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. This is the first version in the GHS SDS format. Listings of changes from previous versions in other formats are not applicable. To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Page 11 of 12 Safety Data Sheet POUR-N-SEAL Component A SDS Revision Date: 5/4/2015 The information presented herein is based on data considered to be accurate as of the date of preparation of this Safety Data Sheet. However, SDS may not be used as a commercial specification sheet of manufacturer or seller, and no warranty or representation, expressed or implied, is made as to the accuracy or comprehensiveness of the foregoing data and safety information, nor is any authorization given or implied to practice any patented invention without a license. In addition, no responsibility can be assumed by vendor for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices, or from any hazards inherent in the nature of the product. End of Document Page 12 of 12 Safety Data Sheet POUR-N-SEAL Component B SDS Revision Date: 5/22/2015 1. Identification 1.1. Product identifier Product Identity POUR-N-SEAL Component B Alternate Names Pour-N-Seal Component B 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use Epoxy Resin Hardener Application Method See Technical Data Sheet. 1.3. Details of the supplier of the safety data sheet Company Name Company Contacts Raven Industries, Inc. — Engineered Films Division 821 W. Algonquin Street Sioux Falls, SD 57104 Raven Industries INC. Direct: (605) 335-0250 Cindy.heppler@ravenind.com 24 hour Emergency Telephone No. (605) 335-0250 If immediate assistance is not obtained, please call 911. 2. Hazard(s) identification 2.1. Classification of the substance or mixture Acute Tox. 4;H302 Harmful if swallowed. Acute Tox. 4;H312 Harmful in contact with skin. Skin Corr. 1B;H314 Causes severe skin burns and eye damage. Eye Dam. 1;H318 Causes serious eye damage. Skin Sens. 1;H317 May cause an allergic skin reaction. Repr. 2;H361 F Suspected of damaging fertility. Aquatic Chronic 2;H411 Toxic to aquatic life with long lasting effects. 2.2. Label elements Using the Toxicity Data listed in section 11 and 12 the product is labeled as follows. Page 1 of 13 Safety Data Sheet POUR-N-SEAL Component B SDS Revision Date: 5/22/2015 0000 Danger H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H361f Suspected of damaging fertility. H411 Toxic to aquatic life with long lasting effects. [Prevention]: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P261 Avoid breathing dust / fume / gas / mist / vapors / spray. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves / eye protection / face protection. [Response]: P301+312 IF SWALLOWED: Call a POISON CENTER or doctor / physician if you feel unwell. P302+352 IF ON SKIN: Wash with plenty of soap and water. P303+361+353 IF ON SKIN (or hair): Remove / Take off immediately all contaminated clothing. Rinse skin with water / shower. P304+312 IF INHALED: Call a POISON CENTER or doctor / physician if you feel unwell. P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P308+313 IF exposed or concerned: Get medical advice / attention. P310 Immediately call a POISON CENTER or doctor / physician. P321 Specific treatment (see information on this label). Page 2 of 13 Safety Data Sheet POUR-N-SEAL Component B SIDS Revision Date: 5/22/2015 P330 Rinse mouth. P331 Do NOT induce vomiting. P333+313 If skin irritation or a rash occurs: Get medical advice / attention. P340 Remove victim to fresh air and keep at rest in a position comfortable for breathing. P363 Wash contaminated clothing before reuse. P391 Collect spillage. [Storage]: P405 Store locked up. [Disposal]: P501 Dispose of contents / container in accordance with local / national regulations. 3. Composition/information on ingredients This product contains the following substances that present a hazard within the meaning of the relevant State and Federal Hazardous Substances regulations. Ingredient/Chemical Designations Weight % GHS Classification Notes Tetraethylenepentamine <2 Acute Tox. 4;H312 [1] CAS Number: 0000112-57-2 Acute Tox. 4;H302 Skin Corr. 1B;H314 Skin Sens. 1;H317 Aquatic Chronic 2;H411 Diethylenetriamine (DETA) 5-15 Acute Tox. 4;H312 [1][2] CAS Number: 0000111-40-0 Acute Tox. 4;H302 Skin Corr. 1B;H314 Skin Sens. 1;H317 TOFA, reaction product with TEPA 15-30 Eye Dam. 1;H318 [1] CAS Number: 0068953-36-6 lAquatic Chronic 2;H411 Diphenylol propane 1.0 -10 Repr. 2;H361f [1] CAS Number: 0000080-05-7 STOT SE 3;H335 Eye Dam. 1;H318 Skin Sens. 1;H317 Carbon black 1.0 -10 Not Classified r[2] CAS Number: 0001333-86-4 Titanium Dioxide r Not Classified rl�2] CAS Number: 13463-67-7 Amorphous silica, hydrophobic rl Not Classified [1] CAS Number: 67762-90-7 Synthetic Amorphous Silica 40-60 Not Classified [1] CAS Number: 112926-00-8 In accordance with paragraph (i) of §1910.1200, the specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. [1] Substance classified with a health or environmental hazard. [2] Substance with a workplace exposure limit. Page 3 of 13 Safety Data Sheet POUR-N-SEAL Component B SIDS Revision Date: 5/22/2015 [3] PBT-substance or vPvB-substance. *The full texts of the phrases are shown in Section 16. 4. First aid measures 4.1. Description of first aid measures General In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificial respiration. If unconscious place in the recovery position and obtain immediate medical attention. Give nothing by mouth. Eyes Irrigate copiously with clean water for at least 15 minutes, holding the eyelids apart and seek medical attention. Skin Immediately take off all contaminated clothing. For skin contact, wash immediately with soap and water. If irritation persists, get medical attention. Ingestion If conscious, give large amounts of water. If the material is swallowed, get immediate medical attention or advice. Do Not induce vomiting. 4.2. Most important symptoms and effects, both acute and delayed Overview Inhalation: May cause lung irritation; potential sensitizer See section 2 for further details. Eyes Causes serious eye damage. Skin Harmful in contact with skin. May cause an allergic skin reaction. Causes severe skin burns and eye damage. Ingestion Harmful if swallowed. 5. Fire -fighting measures 5.1. Extinguishing media Water spray, dry chemical, alcohol foam, carbon dioxide 5.2. Special hazards arising from the substance or mixture Hazardous decomposition: Oxides of carbon and nitrogen, Aldehydes Avoid breathing dust / fume / gas / mist / vapors / spray. 5.3. Advice for fire-fighters Page 4 of 13 Safety Data Sheet POUR-N-SEAL Component B SDS Revision Date: 5/22/2015 Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing, and face mask. ERG Guide No. ---- 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Put on appropriate personal protective equipment (see section 8). 6.2. Environmental precautions Do not allow spills to enter drains or waterways. Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse. 6.3. Methods and material for containment and cleaning up For major spills call Raven Industries (1-605-336-2750). Clean up should only be performed by trained personnel. People dealing with major spillages should wear full protective clothing including appropriate respiratory protection. Evacuate the area. Prevent further leakage, spillage or entry into drains. 7. Handling and storage 7.1. Precautions for safe handling Avoid breathing aerosols, mists and vapors. Avoid contact with skin and eyes. See section 2 for further details. - [Prevention]: 7.2. Conditions for safe storage, including any incompatibilities Handle containers carefully to prevent damage and spillage. Incompatible materials: Strong oxidizing agents If container is exposed to high heat, it can be pressurized and possibly rupture explosively. Keep the container tightly closed and in a cool, well -ventilated place. See section 2 for further details. - [Storage]: 7.3. Specific end use(s) No data available. Page 5 of 13 Safety Data Sheet POUR-N-SEAL Component B SDS Revision Date: 5/22/2015 8. Exposure controls and personal protection 8.1. Control parameters Exposure CAS No. Ingredient Source I Value 0000080-05-7 Diphenylolpropane OSHA INo Established Limit ACGIH INo Established Limit NIOSH INo Established Limit Supplier INo Established Limit 0000111-40-0 Diethylenetriamine (DETA) OSHA INo Established Limit ACGIH TWA: 1 ppmSkin, S NIOSH ITWA 1 ppm (4 mg/m3) [skin] Supplier INo Established Limit 0000112-57-2 OSHA INo Established Limit �Tetraethylenepentamine ACGIH INo Established Limit NIOSH INo Established Limit Supplier INo Established Limit 0001333-86-4 [Carbon black OSHA ITWA 3.5 mg/m3 ACGIH TWA: 3 mg/m32B, Revised 2011, rF6�� TWA 3.5 mg/m3 Ca TWA 0.1 mg PAHs/m3 [in presence of polycyclic aromatic hydrocarbons (PAHs)] Supplier INo Established Limit 0068953-36-6 TOFA, reaction product with TEPA OSHA INo Established Limit ACGIH INo Established Limit NIOSH INo Established Limit Supplier INo Established Limit Page 6 of 13 Safety Data Sheet POUR-N-SEAL Component B SDS Revision Date: 5/22/2015 Carcinogen Data CAS No. Ingredient Source Value 0000080-05-7 Diphenylolpropane OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0000111-40-0 Diethylenetriamine (DETA) OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC IGroup 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0000112-57-2 Tetraethylenepentamine OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0001333-86-4 Carbon black OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC IGroup 1: No; Group 2a: No; Group 2b: Yes; Group 3: No; Group 4: No; 0068953-36-6 TOFA, reaction product with TEPA OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC IGroup 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 13463-67-7 Titanium Dioxide Not Established VHA P Not Established C Not Established 67762-90-7 Amorphous silica, hydrophobic OSHA Not Established NTP �IARC Not Established Not Established 112926-00-8 Synthetic Amorphous Silica OSHA Not Established NTP �IARC Not Established Not Established 8.2. Exposure controls Respiratory When the product is sprayed or heated without adequate ventilation, an approved MSHA/NIOSH positive -pressure, supplied -air respirator may be required. Eyes Wear safety glasses; chemical goggles (if splashing is possible). Page 7 of 13 Safety Data Sheet POUR-N-SEAL Component B SDS Revision Date: 5/22/2015 Skin Protective clothing should be selected. Gloves - neoprene, nitrile rubber, butyl rubber. Thin latex disposable gloves should be avoided for repeated or long-term use. Engineering Controls Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and any vapor below occupational exposure limits suitable respiratory protection must be worn. Other Work Practices Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse. See section 2 for further details. - [Prevention]: 9. Physical and chemical properties Appearance Odor Odor threshold pH Melting point / freezing point Initial boiling point and boiling range Flash Point Evaporation rate (Ether= 1) Flammability (solid, gas) Upper/lower flammability or explosive limits Vapor pressure (Pa) Vapor Density Specific Gravity Solubility in Water Partition coefficient n-octanol/water (Log Kow) Auto -ignition temperature Decomposition temperature Viscosity (cst) VOC Content 9.2. Other information No other relevant information. Slightly Viscous Liquid Sweet-smelling gel Not determined Not available Not available Not determined > 383°F Pensky Martin Closed Cup Not determined Not Applicable Lower Explosive Limit: Not available Upper Explosive Limit: Not available 1.0 mmHg @ 180°F Not available 1.20 @ 77°F Slight Not Measured Not available Not available Not available None Page 8 of 13 Safety Data Sheet POUR-N-SEAL Component B SIDS Revision Date: 5/22/2015 10. Stability and reactivity 10.1. Reactivity Hazardous Polymerization will not occur. 10.2. Chemical stability Stable under normal circumstances. 10.3. Possibility of hazardous reactions No data available. 10.4. Conditions to avoid Elevated temperatures; strong acids or bases in bulk 10.5. Incompatible materials Strong oxidizing agents 10.6. Hazardous decomposition products Oxides of carbon and nitrogen, Aldehydes 11. Toxicological information Acute toxicity Ingredient Oral LD50, Skin LD50, Inhalation Inhalation Inhalation mg/kg mg/kg Vapor LC50, Dust/Mist LC50, Gas LC50, mg/U4hr mg/U4hr ppm Tetra ethylenepentamine - (112-57-2) 2,140.00, Rat - No data No data No data No data Category: 5 available available available available Diethylenetriamine (DETA) - (111-40-0) 1,080.00, Rat - 1,090.00, No data No data No data Category: 4 Rabbit - available available available Category: 4 TOFA, reaction product with TEPA - (68953-36-6) 2,000.00, Rat - No data No data No data No data Category:4 available available available available Diphenylolpropane - (80-05-7) 5,000.00, Rat - 3,000.00, No data No data No data Category: 5 Rabbit - available available available Category: 5 Carbon black - (1333-86-4) 8,000.00, Rat - No data No data data No data Fo Category: NA available available available available Diglycidyl ether of bisphenol A (25068-38-6) > 5,000.00, Rat- 20,000.00 No Data No data No data Category: NA Rabbit- available available available Category: NA Titanium dioxide (13463-67-7) 10,OO.ORat- 10,000.00 — No data No data No data Category: NA Rabbit- available available available Category: NA Amorphous silica hydrophobic (67762-90-7) 1,000.00, Rat- Category:4 2,000.00, Rat- Category:4 No data available No data available No data available Page 9 of 13 Safety Data Sheet POUR-N-SEAL Component B SIDS Revision Date: 5/22/2015 Synthetic Amorphous Silica (112926-00-8) No data No data No data No data No data available Favailable available available available Note: When no route specific LD50 data is available for an acute toxin, the converted acute toxicity point estimate was used in the calculation of the product's ATE (Acute Toxicity Estimate). Classification F Category lHazard Description Acute toxicity (oral) 4 lHarmful if swallowed. Acute toxicity (dermal) 1 4 lHarmful in contact with skin. Acute toxicity (inhalation) --- INot Applicable Skin corrosion/irritation 1 B Icauses severe skin burns and eye damage. Serious eye damage/irritation 1 Icauses serious eye damage. Respiratory sensitization I --- Not Applicable Skin sensitization 1 Imay cause an allergic skin reaction. Germ cell mutagenicity --- Not Applicable Carcinogenicity --- INot Applicable Reproductive toxicity STOT-single exposure STOT-repeated exposure (Aspiration hazard 2 F---- F- --- Suspected of damaging fertility. Not Applicable Not Applicable Not Applicable 12. Ecological information 12.1. Toxicity Toxic to aquatic life with long lasting effects. No additional information provided for this product. See Section 3 for chemical specific data. Aquatic Ecotoxicity Ingredient 96 hr LC50 fish, 48 hr EC50 crustacea, ErC50 algae, Fmg/I mg/I mg/I Tetraethylenepentamine - (112-57-2) 420.00, Poecilia 24.00, Daphnia magna 2.00 (72 hr), Pseudokirchneriella reticulataF subcapitata Diethylenetriamine (DETA) - (111-40-0) F 1,014.00, Poecilia 53.50, Daphnia magna P45.60 (96 hr), Pseudokirchneriella reticulata subcapitata TOFA, reaction product with TEPA - (68953-36-6) F 9.00, Fish (Piscis) 9.00, Daphnia magna 9.00 (72 hr), Algae Diphenylolpropane - (80-05-7) 4.60, Pimephales F7.75, Daphnia magna 2.73 (96 hr), Pseudokirchneriella promelas subcapitata Page 10 of 13 Carbon black - (1333-86-4) Titanium dioxide (13463-67-7) Amorphous silica, hydrophobic (67762-90-7) Synthetic Amorphous Silica (112926-00-8) Safety Data Sheet POUR-N-SEAL Component B SDS Revision Date: 5/22/2015 1,000.00, Danio rerio 1,000.00, Fundulus heteroclitus Not available Not available 12.2. Persistence and degradability There is no data available on the preparation itself. 12.3. Bioaccumulative potential Not Measured 12.4. Mobility in soil No data available. 12.5. Results of PBT and vPvB assessment This product contains no PBT/vPvB chemicals. 12.6. Other adverse effects No data available. 5,600.00, Daphnia magna 5.50, Daphnia magna 10,000.00 (72 hr), Scenedesmus subspicatus 5.83 (72 hr), Pseudokirchneriella subcapitata Not available Not available Not available Not available 13. Disposal considerations 13.1. Waste treatment methods Observe all federal, state and local regulations when disposing of this substance. 14.1. UN number 14.2. UN proper shipping name 14.3. Transport hazard class(es) 14.4. Packing group 14.5. Environmental hazardE 14. Transport information DOT (Domestic Surface Transportation) Not Applicable Not Regulated DOT Hazard Class: Not Applicable Not Applicable IMO / IMDG (Ocean Transportation) Not Regulated Not Regulated IMDG: Not Applicable Sub Class: Not Applicable Not Applicable IMDG Marine Pollutant: Yes ( Tetraethylenepentamine ) 14.6. Special precautions for user No further information Page 11 of 13 ICAO/IATA Not Regulated Not Regulated Air Class: Not Applicable Not Applicable Safety Data Sheet POUR-N-SEAL Component B SDS Revision Date: 5/22/2015 15. Regulatory information Regulatory Overview The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are represented. Toxic Substance All components of this material are either listed or exempt from listing on the TSCA Control Act (TSCA) Inventory. WHMIS Classification D2A E US EPA Tier II Hazards Fire: No Sudden Release of Pressure: No Reactive: No Immediate (Acute): Yes Delayed (Chronic): No EPCRA 311/312 Chemicals and RQs: To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. EPCRA 302 Extremely Hazardous: To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. EPCRA 313 Toxic Chemicals: Diphenylolpropane Proposition 65 - Carcinogens (>0.0%): Carbon black Proposition 65 - Developmental Toxins (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Proposition 65 - Female Repro Toxins (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Proposition 65 - Male Repro Toxins (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. New Jersey RTK Substances (>1 %): Diphenylolpropane Carbon black Diethylenetriamine (DETA) Tetraethylenepentamine Synthetic Amorphous Silica Pennsylvania RTK Substances (>1%): Diphenylol propane Carbon black Page 12 of 13 Diethylenetriamine (DETA) Tetraethylenepentamine Synthetic Amorphous Silica Safety Data Sheet POUR-N-SEAL Component B SDS Revision Date: 5/22/2015 16. Other information The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and orders. The full text of the phrases appearing in section 3 is: H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H335 May cause respiratory irritation. H361f Suspected of damaging fertility. H411 Toxic to aquatic life with long lasting effects. This is the first version in the GHS SDS format. Listings of changes from previous versions in other formats are not applicable. To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. The information presented herein is based on data considered to be accurate as of the date of preparation of this Safety Data Sheet. However, SDS may not be used as a commercial specification sheet of manufacturer or seller, and no warranty or representation, expressed or implied, is made as to the accuracy or comprehensiveness of the foregoing data and safety information, nor is any authorization given or implied to practice any patented invention without a license. In addition, no responsibility can be assumed by vendor for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices, or from any hazards inherent in the nature of the product. End of Document Page 13 of 13 Flush Thread PVC Well Screens, Casings and Accessories A full line of PVC products that include: Vee-Wire® well screens, slotted well screens, casings and accessories for the water supply and environmental industries. In water supply applications PVC can offer an economical and long-lasting design option, especially when used with a Johnson Screens stainless steel screens. Polyvinyl chloride (PVC) - Is economical, light weight and its design flexibility makes it ideal for: ■ Water wells ■ Water monitoring wells ■ Soil vapor extraction ■ Sparging - air or oxygen ■ Bioremediation ■ Free product recovery ■ Groundwater extraction ■ Drainage and dewatering ■ Leachate collection ■ Degassing Among the fabricating options: ■ PVC casing and well screens from 0.50 to 18 in. diameter ■ Plain end, flush joint or NPT threaded ■ Threaded products supplied in laying lengths ■ Slot openings from 0.006 in. to 0.500 in. ■ Environmental products hermetically sealed in plastic ■ Round hole perforated pipe from 1 in. to 16 in. diameter More Design The flexibility to specify and design a wide variety of slot openings, diameters and wall thicknesses Options allows the well designer to create a well for a wide range of depths and applications. Johnson Screens' PVC well products are designed and manufactured to industry standards, with tolerances that meet or exceed customer needs. This results in a long-lasting well that requires less maintenance. Customer An experienced and knowledgeable customer service representatives, technical support staff and Support engineers, provide customers with solutions to a variety of issues, including screen and casing size recommendations, installation suggestions and sieve analysis. Locally With an extensive distributor network, the Johnson Screens brand is available to customers at a Available number of distributors throughout the world. Flush Threaded PVC Casing and Slotted Pipe Specifications All Johnson Screens Flush Threaded PVC pipe and screen products are manufactured from plastic of Type 1, Grade 1, PVC compound with a cell classification of 12454-B per ASTM D 1784. Pipe materials are NSF approved for potable water and are in strict compliance with ASTM D1785. To maintain the integrity of the slotting and threading process, the only coolant used is air. Physical Data For Common Size Pipe schedule 40, 80, 120 and large diameter SDR 17* 0.5 0.84 0.60 0.11 0.17 0.53 0.15 0.21 0.48 0.17 0.24 0.75 1.05 0.80 0.11 0.23 0.72 0.15 0.29 0.69 0.17 0.31 1 1.32 1.03 0.13 0.33 0.94 0.18 0.42 0.89 0.20 0.46 1.25 1.66 1.36 0.14 0.45 1.26 0.19 0.59 1.20 0.22 0.65 1.5 1.90 1.59 0.15 0.54 1.48 0.20 0.71 1.42 0.23 0.79 2 2.38 2.05 0.15 0.72 1.91 0.22 0.98 1.85 0.25 1.11 2.5 2.88 2.45 0.20 1.14 2.29 0.28 1.50 2.24 0.30 1.62 3 3.50 3.04 0.22 1.49 2.86 0.30 2.01 2.76 0.35 2.31 4 4.50 4.00 0.24 2.12 3.79 0.34 2.94 3.57 0.44 3.71 5 5.56 5.02 0.26 2.87 4.77 0.38 4.08 4.37 0.50 5.00 6 6.63 6.03 0.28 3.73 5.71 0.43 5.61 5.43 0.56 7.13 8 8.63 7.94 0.32 5.62 7.57 0.50 8.52 7.27 0.51 8.40 10 10.75 9.98 0.37 7.97 9.49 0.59 12.64 9.38 0.63 13.27 12 12.75 11.89 0.41 10.53 11.29 0.69 17.38 11.13 0.75 18.89 14 14.00 13.07 0.44 12.46 12.41 0.75 20.85 12.21 0.83 22.55 16 16.00 14.94 0.50 16.29 14.21 0.84 26.81 13.95 0.94 31.66 18 18.00 16.81 0.56 20.59 16.01 0.94 33.54 15.78 1.06 35.60 *Based on GF Harvel Engineering Guide Custom lengths up to 20 ft. can be provided on request. Laying (makeup) length is standard for commonly used materials such as 1, 2, 4, 6 in. diameter Schedule 40 and 80 PVC. Other sizes are end -to -end length unless specified. Standard threads per inch (TPI), for pipe sized .5 -1 in. is 8 TPI, 1.25 - 1.5 in. is 4 TPI, and 2 in. and up is 2 TPI. Customized screen products for special pipe lengths, slot sizes, slot spacing and thread types are available to meet specifications. All flush threaded material is supplied with an 0-ring. All environmental screens and casings, up to 8 in. diameter, are cleaned and bagged prior to shipment. Temperature De -Rating Table "" 'bUellItUl D-Factor 73 / 23 1.00 Curing of cement and grout generates sufficient heat to affect PVC strength and performance. When operating 80 / 27 0.88 at elevated temperatures, the actual values for Collapse 90 / 32 0.75 Pressure, Burst Pressure and Tensile Strength will be de -rated 100 / 38 0.62 according to the chart. 110 / 44 0.51 120 / 49 0.40 130 / 54 0.31 140 / 60 0.22 Page 2 Pressure and Strengths Testing methods and procedures used are in compliance with ASTM F480 standards for thermoplastic pipe in all applicable areas. 0.5 1,400 3,800 6,240 360 340 540 0.75 750 2,100 2,890 460 490 730 1 600 1,600 2,350 700 730 1,000 1.25 300 900 1,370 920 880 1,400 1.5 250 700 1,020 1200 1,200 1,700 2 150 450 700 1500 1,500 2,400 2.5 200 520 680 2,000 2,900 3,600 3 130 360 590 3,000 3,800 5,300 4 80 240 540 4,400 5,800 8,800 5 50 170 420 5,700 6,800 12,400 6 40 150 350 7,100 11,000 17,200 8 30 100 113 11,400 18,400 18,400 10 20 90 113 15,000 26,300 26,300 12 17 85 113 19,500 36,200 36,200 14 16 80 113 22,900 43,400 43,400 16 16 80 113 28,900 55,100 55,100 18 16 75 113 36,000 71,000 71,000 Notes: 1. Values noted with an asterisk (*) are based on minimum wall and include a 50% safety factor. These values are based on ASTM Standards where appropriate. Values noted with a double asterisk (**) are recommended dry hanging weights for threaded PVC. These values are calculated based on the minimum cross sectional area of either the box or pin thread portion of the joint after machining. The resulting minimal area was multiplied by 7,000 psi tensile strength per ASTM D-1784 to yield the recommended dry hanging weight. Safety factor: even though these calculated values are lower than actual Johnson Screens test data, Johnson Screens recommends not to exceed the above values for well construction. 2. All strength properties are based on 73' F Collapse Pressure Tensile Strength Pounds per The suspended square inch of weight the external threaded joint hydrostatic can sustain in a pressure that can vertical position be safely applied. without causing stretching or failure. Page 3 Slotted Screens and Open Area The following tables represent the standard open area of the Johnson Screens slotted PVC well screen. All calculations are based on the inside diameter of the pipe which represents the most accurate area and transmitting potential of the screen. The data presented in these tables is for standard product line. To calculate transmitting capacity in gpm at 0.1 ft/sec flow velocity, multiply the open area of square inches by 0.31. Slotted Screen Open Area in Square Inches Per Foot for Schedule 40 - Std. Construction Nominal Standard Slot Opening (in.) • , 11 1 11 11 1 11 11 1 M 1 1 1 11.1 1 11 1 0.5 0.8 1.1 1.5 0.75 0.8 1.2 1.6 1 1.1 1.7 2.2 2.7 3.1 3.1 3.8 4.4 6.4 5.6 1.25 1.7 2.5 3.3 4.0 4.7 4.7 5.6 6.5 9.6 8.4 1.5 2.1 3.0 3.9 4.8 5.6 5.6 6.8 7.8 11.6 10.1 2 3.6 5.1 6.6 8.0 9.3 6.6 8.0 9.3 13.7 11.3 2.5 4.2 6.1 7.9 9.5 11.0 7.9 9.5 11.0 16.3 14.3 3 4.7 6.8 8.7 10.5 12.2 9.9 12.0 13.9 20.6 18.0 4 6.0 8.7 11.2 13.5 15.7 11.2 13.5 15.7 23.1 18.0 5 6.3 9.2 11.8 14.3 16.6 13.0 15.8 18.3 27.0 23.6 6 6.2 9.0 11.6 13.1 15.4 19.9 24.0 27.9 41.1 36.0 8 6.5 9.5 12.4 15.3 18.0 23.2 28.0 32.5 48.0 42.0 10 14.2 17.5 20.6 26.5 32.0 37.2 54.9 48.0 12 18.3 22.5 26.5 34.1 41.3 47.9 70.7 61.9 14 27.5 33.5 39.3 60.0 71.3 16 36.2 42.4 64.7 76.9 18 45.9 53.8 82.1 97.5 Custom slot patterns and slot sizes available on request Among some of the fabricating options for casing and screen: ■ Plain end, flush joint or NPT threaded ■ Threaded products supplied in laying lengths ■ Slot openings from 0.006 to 0.500 in. Page 4 Slotted Screen Open Area in Square Inches Per Foot for Schedule 80 - Std. Construction Nominal Stcindccrd Slot Opening (in.) •- Size �MMMMMMMMMM 0.5 0.6 0.9 1.2 0.75 0.7 0.9 1.2 1 0.9 1.3 1.7 2.1 2.5 2.5 3.0 3.5 5.1 4.5 1.25 1.5 2.2 2.8 3.4 4.0 3.7 4.5 5.2 7.7 6.8 1.5 1.7 2.5 3.3 4.0 4.7 4.7 5.6 6.5 9.6 8.4 2 2.9 4.2 5.4 6.5 7.6 5.4 6.5 7.6 11.1 9.0 2.5 3.6 5.1 6.6 8.0 9.3 6.6 8.0 9.3 13.7 11.3 3 4.0 5.8 7.5 9.0 10.5 8.7 10.5 12.2 18.0 15.8 4 4.7 6.8 8.7 10.5 12.2 11.6 14.0 16.3 24.0 21.0 5 6.7 8.2 9.6 12.4 15.0 17.4 25.7 24.0 6 8.7 10.6 12.5 16.1 19.5 22.7 33.4 29.3 8 13.5 17.4 21.0 24.4 36.0 42.8 10 11.1 14.5 17.7 20.7 31.6 37.5 12 22.0 26.8 31.5 48.0 57.0 14 23.7 28.9 33.9 51.8 61.5 16 31.8 37.2 56.8 67.5 18 34.4 40.4 61.6 73.1 Custom slot patterns and slot sizes available on request Environmental Monitoring Application Manufacturing a complete line of PVC well screens, casings and accessories suited for groundwater monitoring and remediation, Johnson Screens products meet manufacturing techniques and process requirements of the environmental and remediation markets. Johnson Screens can provide the following: ■ No printing on screen or pipe ■ Cleaned and bagged ■ Flush thread connections ■ 0-rings that are pre -installed ■ Boxed or bulk package options Page 5 Safety Data Sheet Issue Date 01-Jun-2010 Revision Date: 02-Oct-2013 1. IDENTIFICATION Product Identifier Product Name Gorilla Multi -purpose Glue Low-VOC Solvent Cement for PVC/CPVC Plastic Pipe Other means of identification SDS # 04441, 08441, 16441, 32441 UN/ID No 04441, 08441, 16441, 32441 Product Code Recommended use of the chemical and restrictions on use Recommended Use Low-VOC solvent cement for PVC/CPVC plastic pipe Details of the suoolier of the safetv data sheet Manufacturer Address Gorilla PVC Cement LLC PO Box 530308 W Palm Beach, FL 33403 Emergency Telephone Number Company Phone Number 1-888-367-4583 Emergency Telephone (24 hr) INFOTRAC 1-800-535-5053 (North America) 1-352-323-3500 (International) Appearance Clear Liquid Classification 2. HAZARDS IDENTIFICATION Physical State Liquid Odor Ether -like Acute toxicity - Oral Category 4 Acute toxicity - Inhalation Dusts/Mists Category 4 Serious eye damage/eye irritation Category 2 Specific target organ toxicity (single exposure Category 3 Flammable Liquids Category 2 Hazards Not Otherwise Classified (HNOC) May be harmful in contact with skin Signal Word Danger Hazard Statements Harmful if swallowed Harmful if inhaled Causes serious eye irritation May cause respiratory irritation. May cause drowsiness or dizziness Highly flammable liquid and vapor Page 1 / 10 Revision Date: 02-Oct-2013 Precautionary Statements - Prevention Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well -ventilated area Keep away from heat/sparks/open flames/hot surfaces. — No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion -proof equipment Use only non -sparking tools Take precautionary measures against static discharge Wear protective gloves/protective clothing/eye protection/face protection Keep cool Precautionary Statements - Response If exposed or concerned: Get medical advice/attention IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth IN CASE OF FIRE: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage Store in a well -ventilated place. Keep container tightly closed Store locked up Keep cool Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant WHMIS Classification Class B-Division 2 Class D-Division 2A Class D-Division 2B 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight% Tetrah drofuran 109-99-9 Proprietary Methyl ethyl ketone 78-93-3 Proprietary C clohexanone 108-94-1 Proprietary Acetone 67-64-1 Proprietary CPVC Resin 68648-82-8 Proprietary " The exact percentage (concentration) of composition has been withheld as a trade secret Page 2 / 10 Revision Date: 02-Oct-2013 4. FIRST -AID MEASURES First Aid Measures General Advice If exposed or concerned: Get medical advice/attention. Eye Contact In case of irritation from airborne exposure, move to fresh air. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek immediate medical attention/advice. Skin Contact Take off contaminated clothing. Wash with soap and water. If symptoms persist, call a physician. Wash contaminated clothing before reuse. Inhalation Remove to fresh air. If symptoms persist, call a physician. If breathing is difficult, give oxygen. Seek immediate medical attention/advice. Ingestion Rinse mouth. Seek medical attention. If drowsy or unconscious, do not give anything by mouth; place individual on the left side with head down. Do not induce vomiting. Most important symptoms and effects Symptoms Exposed individuals may experience eye tearing, redness and discomfort. Prolonged or repeated skin contact may result in dermatitis (red, dry skin). May cause nose and throat irritation, with possible central nervous system effects. Fatigue and weakness. May cause drowsiness or dizziness. Long term overexposure may cause liver and kidney damage. Indication of anv immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. Individuals with chronic respiratory, skin, kidney, or liver disorders may be at increased risk from exposure. 5. FIRE -FIGHTING MEASURES Suitable Extinguishing Media Foam. Carbon dioxide (CO2). Dry chemical. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Class IB Flammable Liquid. Vapors may travel to source of ignition and flash back. Hazardous Combustion Products Carbon oxides. Various hydrocarbon vapors and toxic gases. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Persons not wearing proper personal protective equipment should be excluded from area of spill. Environmental Precautions Do not allow into any sewer, on the ground or into any body of water. Methods and material for containment and cleaning up Page 3 / 10 Revision Date: 02-Oct-2013 Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean -Up Pump or vacuum transfer spilled product to clean containers for recovery. Absorb unrecoverable product. Transfer contaminated absorbent, soil and other materials to containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handlin Advice on Safe Handling Wash thoroughly after handling. Use personal protection recommended in Section 8. Do not eat, drink or smoke when using this product. Avoid breathing vapors or mists. Use only in well -ventilated areas. Ground/bond container and receiving equipment. Keep away from heat/sparks/open flames/hot surfaces. — No smoking. Use spark -proof tools and explosion - proof equipment. Take precautionary measures against static discharges. Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, solid) all hazard precautions given in the data sheet must be observed. Avoid prolonged contact with eyes, skin, and clothing. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well -ventilated place. Store containers upright. Store away from heat, sparks, flame. Incompatible Materials Oxidizers. Acids. Bases. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Tetrahydrofuran STEL: 100 ppm TWA: 200 ppm IDLH: 2000 ppm 109-99-9 TWA: 50 ppm TWA: 590 mg/m3 TWA: 200 ppm S* (vacated) TWA: 200 ppm TWA: 590 mg/m3 (vacated) TWA: 590 mg/m3 STEL: 250 ppm (vacated) STEL: 250 ppm STEL: 735 mg/m3 vacated STEL: 735 m /m3 Acetone STEL: 750 ppm TWA: 1000 ppm IDLH: 2500 ppm 67-64-1 TWA: 500 ppm TWA: 2400 mg/m3 TWA: 250 ppm (vacated) TWA: 750 ppm TWA: 590 mg/m3 (vacated) TWA: 1800 mg/m3 (vacated) STEL: 2400 mg/m3 The acetone STEL does not apply to the cellulose acetate fiber industry. It is in effect for all other sectors (vacated) STEL: 1000 ppm Methyl ethyl ketone STEL: 300 ppm TWA: 200 ppm IDLH: 3000 ppm 78-93-3 TWA: 200 ppm TWA: 590 mg/m3 TWA: 200 ppm (vacated) TWA: 200 ppm TWA: 590 mg/m3 (vacated) TWA: 590 mg/m3 STEL: 300 ppm (vacated) STEL: 300 ppm STEL: 885 mg/m3 vacated STEL: 885 m /m3 Cyclohexanone STEL: 50 ppm TWA: 50 ppm IDLH: 700 ppm 108-94-1 TWA: 20 ppm TWA: 200 mg/m3 TWA: 25 ppm S" (vacated) TWA: 25 ppm TWA: 100 mg/m3 (vacated) TWA: 100 mg/m3 (vacated)S* Appropriate engineering controls Page 4 / 10 Revision Date: 02-Oct-2013 Engineering Controls Apply technical measures to comply with the occupational exposure limits. Ventilation systems. Eyewash stations. Showers. Mechanical exhaust (explosion proof) may be required. Individual protection measures, such as personal protective equipment Eye/Face Protection Splash goggles or safety glasses. Skin and Body Protection Rubber gloves. Use body protection appropriate for task. Respiratory Protection Not required under normal conditions. If recommended levels are exceeded, respiratory protection must be selected to assure compliance with OSHA Standard 29CFR 1910.134. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic Dhvsical and chemical Droperties Physical State Liquid Appearance Liquid Color Clear Property pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapour Pressure Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition Coefficient Auto -ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties VOC Content Values Not available -108 °C / -163 °F 56°C/133°F -20°C/-4°F > 1.0 n/a-liquid 12.8% 1.8% Odor Odor Threshold Remarks • Method (butyl acetate = 1) Ether -like 0.88 ppm 190 mm Hg @ 20°C (68°F) 2.5 (Air=1) 0.950 Negligible Not determined Not determined 321 °C / 610 °F Not determined Not determined Not determined Not determined Not determined Not determined Maximum VOC emissions when applied and tested per SCAQMD Rule 1168, Test Method 316A is <= 490 g/L 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions Possibilitv of Hazardous Reactions None under normal processing Hazardous Polymerization Hazardous polymerization does not occur. Page 5 / 10 Revision Date: 02-Oct-2013 Conditions to Avoid Avoid heat, sparks, open flames and other ignition sources. Incompatible Materials Oxidizers. Acids. Bases. Hazardous Decomposition Products Carbon oxides. Hydrogen chloride. Other various hydrocarbons. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact Skin Contact Inhalation Ingestion Component Information Causes serious eye irritation. May be harmful in contact with skin. Harmful if inhaled. Harmful if swallowed. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Tetrahydrofuran = 1650 mg/kg ( Rat) - = 53.9 mg/L ( Rat) 4 h = 180 mg/L 109-99-9 ( Rat) 1 h Acetone = 5800 mg/kg ( Rat) - 67-64-1 Methyl ethyl ketone = 2737 mg/kg ( Rat) = 6480 mg/kg ( Rabbit ) 78-93-3 Cyclohexanone = 800 mg/kg ( Rat) = 948 mg/kg ( Rabbit) = 10.7 mg/L ( Rat) 4 h = 8000 ppm 108-94-1 Rat 4 h Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SIDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. However, the product as a whole has not been tested. Chemical Name ACGIH IARC NTP OSHA Tetrahydrofuran A3 109-99-9 Cyclohexanone A3 Group 3 108-94-1 Legena ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 3 IARC components are "not classifiable as human carcinogens" STOT - single exposure Numerical measures of toxicity Not determined May cause respiratory irritation. May cause drowsiness or dizziness. Page 6 / 10 Revision Date: 02-Oct-2013 12. ECOLOGICAL INFORMATION Ecotoxicity Category IV Chemical Name Algae/aquatic plants Fish Toxicity to Crustacea microorganisms Tetrahydrofuran 1970 - 2360: 96 h 5930: 24 h Daphnia magna 109-99-9 Pimephales promelas mg/L mg/L EC50 LC50 flow -through 2700 - 3600: 96 h Pimephales promelas mg/L LC50 static Acetone 4.74 - 6.33: 96 h EC50 = 14500 mg/L 15 min 10294 - 17704: 48 h Daphnia 67-64-1 Oncorhynchus mykiss mL/L magna mg/L EC50 Static LC50 6210 - 8120: 96 h 12600 - 12700: 48 h Daphnia Pimephales promelas mg/L magna mg/L EC50 LC50 static 8300: 96 h Lepomis macrochirus mg/L LC50 Methyl ethyl ketone 3130 - 3320: 96 h EC50 = 3403 mg/L 30 min 520: 48 h Daphnia magna 78-93-3 Pimephales promelas mg/L EC50 = 3426 mg/L 5 min mg/L EC50 5091: 48 h LC50 flow -through Daphnia magna mg/L EC50 4025 - 6440: 48 h Daphnia magna mg/L EC50 Static Cyclohexanone 20: 96 h Chlorella vulgaris 481 - 578: 96 h Pimephales EC50 = 18.5 mg/L 5 min 860: 24 h Daphnia magna 108-94-1 mg/L EC50 promelas mg/L LC50 flow- EC50 = 21.3 mg/L 10 min mg/L EC50 through 8.9: 96 h EC50 = 25 mg/L 5 min Pimephales promelas mg/L LC50 Persistence/Degradabi lity Not determined. Bioaccumulation Not determined. Mobility Chemical Name Partition Coefficient Tetrahydrofuran 0.45 109-99-9 Methyl ethyl ketone 0.29 78-93-3 Cyclohexanone 0.86 108-94-1 Acetone -0.24 67-64-1 Other Adverse Effects Not determined 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Page 7 / 10 Revision Date: 02-Oct-2013 Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. US EPA Waste Number Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes Tetrahydrofuran U213 109-99-9 Acetone Included in waste stream: 0002 67-64-1 F039 Methyl ethyl ketone U159 Included in waste streams: 200.0 mg/L regulatory level U159 78-93-3 F005, F039 Cyclohexanone Included in waste stream: U057 108-94-1 F039 California Hazardous Waste Status Chemical Name California Hazardous Waste Status Tetrahydrofuran Toxic 109-99-9 Ignitable Methyl ethyl ketone Toxic 78-93-3 Ignitable Acetone Ignitable 67-64-1 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. Shipments of containers holding 5 Liters or less per inner packaging may qualify for a "Limited Quantity" exception. Refer to 49 CFR 173.150 for additional information. DOT UN/ID No UN1133 Proper Shipping Name Adhesives Hazard Class 3 Packing Group II IATA UN/ID No UN1133 Proper Shipping Name Adhesives Hazard Class 3 Packing Group II IMDG UN/ID No UN1133 Proper Shipping Name Adhesives Hazard Class 3 Packing Group II Marine Pollutant No International Inventories 15. REGULATORY INFORMATION Page 8 / 10 Revision Date: 02-Oct-2013 TSCA Listed Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSUNDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances US Federal Reaulations CERCLA Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) Tetrahydrofuran 1000 lb RQ 1000 lb final RQ 109-99-9 RQ 454 kg final RQ Methyl ethyl ketone 5000 lb RQ 5000 lb final RQ 78-93-3 RQ 2270 kg final RQ Cyclohexanone 5000 lb RQ 5000 lb final RQ 108-94-1 RQ 2270 kg final RQ Acetone 5000 lb RQ 5000 lb final RQ 67-64-1 RQ 2270 kg final RQ SARA 313 Not determined US State Regulations California Proposition 65 This product may contain trace levels of chemicals known to the State of California to cause cancer. Exposure to these chemicals above the State of California 'No Significant Risk Level' is unlikely under normal use conditions. U.S. State Right -to -Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania Tetrahydrofuran X X X 109-99-9 Acetone X X X 67-64-1 Methyl ethyl ketone X X X 78-93-3 Cyclohexanone X X X 108-94-1 Page 9 / 10 Revision Date: 02-Oct-2013 16. OTHER INFORMATION NFPA Health Hazards Flammability Instability Special Hazards 2 3 1 None HMIS Health Hazards Flammability Physical Hazards Personal Protection 2 3 1 G Issue Date 01-Jun-2010 Revision Date: 02-Oct-2013 Revision Note New format DicrlaimPr The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 10/10 1. Identification Product identifier Other means of identification SDS number Synonyms Recommended use Recommended restrictions SAFETY DATA SHEET Oatey PVC Heavy Duty Clear or Gray Cement 1102E Part Numbers: Clear 30850, 30863, 30876(TV), 30882, 31008(TV), 31011, 31950, 31951, 31952, 31953 Gray 30349, 31093, 31094, 31095, 31105, 31118, 31978, 31979, 31980, 31981, 32050, 32051,32052,32210,32211 Joining PVC Pipes None known. Manufacturer/Importer/Supplier/Distributor information Company Name Address Telephone E-mail Transport Emergency Emergency First Aid Contact person 2. Hazard(s) identification Physical hazards Health hazards OSHA defined hazards Label elements Signal word Hazard statement Precautionary statement Oatey Co. 4700 West 160th St. Cleveland, OH 44135 216-267-7100 info@oatey.com Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887) 1-877-740-5015 MSDS Coordinator Flammable liquids Category 2 Acute toxicity, oral Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Specific target organ toxicity, single exposure Category 3 respiratory tract irritation Specific target organ toxicity, single exposure Category 3 narcotic effects Aspiration hazard Category 1 Not classified. Ogg Danger Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only outdoors or in a well -ventilated area. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion -proof electrical/ventilating/lighting equipment. Use only non -sparking tools. Take precautionary measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. Response Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use appropriate media to extinguish. Storage Store in a well -ventilated place. Keep container tightly closed. Keep cool. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Oatey PVC Heavy Duty Clear or Gray Cement SIDS US 920700 Version #: 02 Revision date:12-5-2017 Issue date:8-4-2014 1 / 10 Hazard(s) not otherwise Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. classified (HNOC) May form explosive peroxides. Contains a chemical classified by the US EPA as a suspected possible carcinogen. Supplemental information Not applicable. 3. Composition/information on ingredients Mixtures Chemical name CAS number % Furan, Tetrahydro- 109-99-9 30-60 2-Propanone 67-64-1 10-30 Cyclohexanone 108-94-1 10-30 Polyvinyl chloride 9002-86-2 10-30 Methyl ethyl ketone 78-93-3 5-10 Colloidal silicon dioxide 112945-52-5 1-5 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First -aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may cause pulmonary edema and pneumonitis. Most important Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. symptoms/effects, acute and Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. May delayed cause redness and pain. Indication of immediate Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water medical attention and special immediately. While flushing, remove clothes which do not adhere to affected area. Call an treatment needed ambulance. Continue flushing during transport to hospital. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed. General information Take off all contaminated clothing immediately. IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. 5. Fire -fighting measures Suitable extinguishing media Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media Specific hazards arising from Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source the chemical of ignition and flash back. During fire, gases hazardous to health may be formed. Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire. and precautions for firefighters Fire fighting In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do equipment/instructions so without risk. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosive organic peroxide when exposed to air or light or with age. Oatey PVC Heavy Duty Clear or Gray Cement SIDS US 920700 Version #: 02 Revision date: 12-5-2017 Issue date: 8-4-2014 2 / 10 6. Accidental release measures Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of protective equipment and low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). emergency procedures Wear appropriate protective equipment and clothing during clean-up. Avoid inhalation of vapors or mists. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SIDS. Methods and materials for Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take containment and cleaning up precautionary measures against static discharge. Use only non -sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Use water spray to reduce vapors or divert vapor cloud drift. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re -use. For waste disposal, see section 13 of the SIDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non -sparking tools and explosion -proof equipment. Do not taste or swallow. Avoid breathing mist or vapor. Avoid contact with skin. Avoid contact with eyes. Avoid prolonged exposure. Avoid contact with clothing. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. When using, do not eat, drink or smoke. Wash hands thoroughly after handling. Conditions for safe storage, Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge including any incompatibilities build-up by using common bonding and grounding techniques. Store in original tightly closed container. Store in a cool, dry place out of direct sunlight. Store in a well -ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Keep in an area equipped with sprinklers. 8. Exposure controls/personal protection Occupational exposure limits U.S. - OSHA Components Type Value Form Colloidal silicon dioxide TWA 0.8 mg/m3 Unspecified. (CAS 112945-52-5) 20 mppcf Unspecified. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Components Type Value Polyvinyl chloride (CAS STEL 5 ppm 9002-86-2) TWA 1 ppm US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Form 2-Propanone (CAS 67-64-1) PEL 2400 mg/m3 1000 ppm Cyclohexanone (CAS PEL 200 mg/m3 108-94-1) 50 ppm Furan, Tetrahydro- (CAS PEL 590 mg/m3 109-99-9) 200 ppm Oatey PVC Heavy Duty Clear or Gray Cement SIDS US 920700 Version #: 02 Revision date: 12-5-2017 Issue date: 8-4-2014 3 / 10 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Form Methyl ethyl ketone (CAS PEL 590 mg/m3 78-93-3) 200 ppm Polyvinyl chloride (CAS PEL 5 mg/m3 Respirable fraction. 9002-86-2) 15 mg/m3 Total dust. US. OSHA Table Z-3 (29 CFR 1910.1000) Components Type Value Colloidal silicon dioxide TWA 0.8 mg/m3 (CAS 112945-52-5) 20 mppcf US. ACGIH Threshold Limit Values Components Type Value Form 2-Propanone (CAS 67-64-1) STEL 750 ppm TWA 500 ppm Cyclohexanone (CAS STEL 50 ppm 108-94-1) TWA 20 ppm Furan, Tetrahydro- (CAS STEL 100 ppm 109-99-9) TWA 50 ppm Methyl ethyl ketone (CAS STEL 300 ppm 78-93-3) TWA 200 ppm Polyvinyl chloride (CAS TWA 1 mg/m3 Respirable fraction. 9002-86-2) U.S. - NIOSH Components Type Value Form Colloidal silicon dioxide REL 6 mg/m3 Unspecified. (CAS 112945-52-5) US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value 2-Propanone (CAS 67-64-1) TWA 590 mg/m3 250 ppm Colloidal silicon dioxide TWA 6 mg/m3 (CAS 112945-52-5) Cyclohexanone (CAS TWA 100 mg/m3 108-94-1) 25 ppm Furan, Tetrahydro- (CAS STEL 735 mg/m3 109-99-9) 250 ppm TWA 590 mg/m3 200 ppm Methyl ethyl ketone (CAS STEL 885 mg/m3 78-93-3) 300 ppm TWA 590 mg/m3 200 ppm Oatey PVC Heavy Duty Clear or Gray Cement SIDS US 920700 Version #: 02 Revision date: 12-5-2014 Issue date: 8-4-2014 4 / 10 Biological limit values ACGIH Biological Exposure Indices Components Value Determinant Specimen Sampling Time 2-Propanone (CAS 67-64-1)50 mg/I Acetone Urine Cyclohexanone (CAS 80 mg/I 1,2-Cyclohexan Urine 108-94-1) ediol, with hydrolysis 8 mg/I Cyclohexanol, Urine with hydrolysis Furan, Tetrahydro- (CAS 2 mg/I Tetrahydrofura Urine 109-99-9) n Methyl ethyl ketone (CAS 2 mg/I MEK Urine 78-93-3) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies Cyclohexanone (CAS 108-94-1) Skin designation applies. US - Tennessee OELs: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. Furan, Tetrahydro- (CAS 109-99-9) Can be absorbed through the skin. US. NIOSH: Pocket Guide to Chemical Hazards Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin. Appropriate engineering Explosion -proof general and local exhaust ventilation. Good general ventilation (typically 10 air controls changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear appropriate chemical resistant gloves. Other Wear appropriate chemical resistant clothing. Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene When using, do not eat, drink or smoke. Wash hands after handling and before eating. considerations 9. Physical and chemical properties Appearance Opaque.or Translucent. Physical state Liquid. Form Color Odor Odor threshold pH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Liquid. Gray or Clear. Solvent. Not available. Not available. Not available. 151 °F (66.11 °C) 14.0 - 23.0 °F (-10.0 - -5.0 °C) 5.5-8 Oatey PVC Heavy Duty Clear or Gray Cement SIDS US 920700 Version #: 02 Revision date: 12-5-2017 Issue date: 8-4-2014 5 / 10 Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower Not available. (%) Flammability limit - upper Not available. (%) Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure Vapor density Relative density Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto -ignition temperature Decomposition temperature Viscosity Other information Bulk density VOC (Weight %) 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products 145mmHg@20C 2.5 0.88 - 0.92 Negligible Not available. Not available. Not available. 1200 - 2500 cP 7.5 lb/gal <510 g/I SQACMD 1168/M316A The product is stable and non -reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. No dangerous reaction known under conditions of normal use. Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics. No hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Inhalation May be fatal if swallowed and enters airways. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful. May cause irritation to the respiratory system. Skin contact Causes skin irritation. Eye contact Causes serious eye irritation. Ingestion May be fatal if swallowed and enters airways. Harmful if swallowed. Symptoms related to the Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May physical, chemical and cause redness and pain. Symptoms of overexposure may be headache, dizziness, tiredness, toxicological characteristics nausea and vomiting. Information on toxicological effects Acute toxicity May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation. Components Species Test Results Cyclohexanone (CAS 108-94-1) Acute Dermal LD50 Rabbit 948 mg/kg Inhalation LC50 Rat 8000 ppm, 4 hours Oatey PVC Heavy Duty Clear or Gray Cement SIDS US 920700 Version #: 02 Revision date: 12-5-2017 Issue date: 8-4-2014 6 / 10 Components Species Test Results Oral LD50 Rat 1540 mg/kg * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye Causes serious eye irritation. irritation Respiratory or skin sensitization Respiratory sensitization Not available. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1 % are mutagenic or genotoxic. Carcinogenicity Suspected of causing cancer. In 2012 USEPA Integrated Risk Information System (IRIS) reviewed a two species inhalation lifetime study on THE conducted by NTP (1998). Male rats developed renal tumors and female mice developed liver tumors while neither the female rats nor the male mice showed similar results. Because the carcinogenic mechanisms could not be identified clearly in either species for either tumor, the EPA determined that the male rat and female mouse findings are relevant to the assessment of carcinogenic potential in humans. Therefore, the IRIS review concludes that these data in aggregate indicate that there is "suggestive evidence of carcinogenic potential" following exposure to THE by all routes of exposure. This product contains polyvinyl chloride (PVC) that is not a fabricated product, and is therefore, defined and regulated as a toxic and hazardous substance under 29 C.F.R. § 1910.1017 due to the presumed presence of residual vinyl chloride monomer. The concentrations of residual vinyl chloride calculated to be contained in this product are well below the threshold for classification in accordance with 29 C.F.R. § 1910.1200. IARC Monographs. Overall Evaluation of Carcinogenicity Colloidal silicon dioxide (CAS 112945-52-5) 3 Not classifiable as to carcinogenicity to humans. Cyclohexanone (CAS 108-94-1) 3 Not classifiable as to carcinogenicity to humans. Polyvinyl chloride (CAS 9002-86-2) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Polyvinyl chloride (CAS 9002-86-2) Cancer Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - Respiratory tract irritation. Narcotic effects. single exposure Specific target organ toxicity - Not classified. repeated exposure Aspiration hazard May be fatal if swallowed and enters airways. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Components Species Test Results Cyclohexanone (CAS 108-94-1) Aquatic Fish LC50 Fathead minnow (Pimephales promelas) 481 - 578 mg/l, 96 hours Estimates for product may be based on additional component data not shown. Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) 2-Propanone (CAS 67-64-1) -0.24 Cyclohexanone (CAS 108-94-1) 0.81 Furan, Tetrahydro- (CAS 109-99-9) 0.46 Methyl ethyl ketone (CAS 78-93-3) 0.29 Mobility in soil No data available. Oatey PVC Heavy Duty Clear or Gray Cement SIDS US 920700 Version #: 02 Revision date: 12-5-2017 Issue date: 8-4-2014 7 / 10 Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some products product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT UN number UN1133 UN proper shipping name Adhesives Transport hazard class(es) Class 3 Subsidiary risk - Label(s) 3 Packing group II Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Special provisions T11, TP1, TP8, TP27 Packaging exceptions 150 Packaging non bulk 201 Packaging bulk 243 IATA UN number UN1133 UN proper shipping name Adhesives Transport hazard class(es) Class 3 Subsidiary risk - Packing group II Environmental hazards No. ERG Code 3L Special precautions for user Read safety instructions, SDS and emergency procedures before handling. IMDG UN number UN1133 UN proper shipping name ADHESIVES Transport hazard class(es) Class 3 Subsidiary risk - Packing group II Environmental hazards Marine pollutant No. EmS F-E, S-D Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Transport in bulk according to Not available. Annex II of MARPOL 73/78 and the IBC Code Oatey PVC Heavy Duty Clear or Gray Cement SIDS US 920700 Version #: 02 Revision date: 12-5-2017 Issue date: 8-4-2014 8 / 10 15. Regulatory information US federal regulations This product is a "Hazardous Chemical' as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Polyvinyl chloride (CAS 9002-86-2) Cancer Central nervous system Liver Blood Flammability CERCLA Hazardous Substance List (40 CFR 302.4) 2-Propanone (CAS 67-64-1) LISTED Cyclohexanone (CAS 108-94-1) LISTED Furan, Tetrahydro- (CAS 109-99-9) LISTED Methyl ethyl ketone (CAS 78-93-3) LISTED Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous No chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act Not regulated. (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number 2-Propanone (CAS 67-64-1) 6532 Methyl ethyl ketone (CAS 78-93-3) 6714 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) 2-Propanone (CAS 67-64-1) 35 %WV Methyl ethyl ketone (CAS 78-93-3) 35 %WV DEA Exempt Chemical Mixtures Code Number 2-Propanone (CAS 67-64-1) 6532 Methyl ethyl ketone (CAS 78-93-3) 6714 US state regulations US. Massachusetts RTK - Substance List 2-Propanone (CAS 67-64-1) Colloidal silicon dioxide (CAS 112945-52-5) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. New Jersey Worker and Community Right -to -Know Act 2-Propanone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) Oatey PVC Heavy Duty Clear or Gray Cement SIDS US 920700 Version #: 02 Revision date: 12-5-2017 Issue date: 8-4-2014 9 / 10 Polyvinyl chloride (CAS 9002-86-2) US. Pennsylvania Worker and Community Right -to -Know Law 2-Propanone (CAS 67-64-1) Colloidal silicon dioxide (CAS 112945-52-5) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. Rhode Island RTK 2-Propanone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Furan, Tetrahydro- (CAS 109-99-9) Methyl ethyl ketone (CAS 78-93-3) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. This product contains trace amounts of chemicals known to the state of California to cause cancer. Under normal use conditions, exposure to these chemicals at levels above the State of California "No significant Risk Level' (NSRL) are unlikely. The use of proper personal protective equipment (PPE) and ventilation guidelines noted in Section 8 will minimize exposure levels to these chemicals. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) Yes Canada Non -Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical No Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances Yes (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 04-August-2014 Revision date 15-December-2014 Version # 02 HMIS® ratings Health: 2 Flammability: 3 Physical hazard: 0 Disclaimer The information in the sheet was written based on the best knowledge and experience currently available. Oatey PVC Heavy Duty Clear or Gray Cement SIDS US 920700 Version #: 02 Revision date: 12-5-2017 Issue date: 8-4-2014 10 / 10