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HomeMy WebLinkAbout4101_Guilford_CityHighPoint_Riverdale_MSWLF_Seaboard_RemedialProgressReport_FID1834504_20240419SEABOARD GROUP II AND THE CITY OF HIGH POINT April 19, 2024 Mr. Kim Caulk, Supervisor Facility Management Branch North Carolina Department of Environmental Quality Division of Waste Management 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Re: Remedial Action Progress Report, 2024 First Quarter Former Seaboard Chemical and Riverdale Drive Landfill Site Jamestown, Guilford County, North Carolina Dear Mr. Caulk: The Seaboard Group II and the City of High Point are providing this 2024 First Quarter Remedial Action Progress Report for the former Seaboard Chemical Corporation facility and the closed Riverdale Drive Landfill located in Jamestown, Guilford County, North Carolina. During the first quarter of 2024, the mechanical and phytoremediation treatment systems processed 3,961,849 gallons of extracted groundwater and leachate. Based on the average influent contaminant concentrations, approximately 498 pounds of volatile organic compounds and 32 pounds of 1,4-dioxane were recovered from the groundwater extraction wells and leachate collection systems. The system was operational for the entire month however was offline for two events. The first related to freezing of the phytoremediation zone valves (2.7 days) and second as a result of routine citric acid cleaning of the effluent conveyance lines (7 days). There were no other significant shutdowns during this reporting period. As recommended in the October 2023 Technical Memorandum 11 Final Summary Report, a quarterly groundwater and surface water monitoring program has been implemented. This monitoring program includes the on -site surface water monitoring locations (SW-1, SW-2, SW- 3, SW-4, and SW-5) and two groundwater monitoring wells at the SIS Basin Area (AW-3/AWB- 4). These sampling locations are shown on Figure 1 of this report. The quarterly groundwater and surface water samples were collected on March 26, 2024. A summary of the laboratory analytical results are provided on Table 1 (groundwater) and Table 2 (surface water) which is included with this report. These tables also provide the applicable NC Groundwater Standards and Surface Water Standards/In-Stream Target Values. The Eurofins laboratory report is included as an attachment to this report. In addition to the data summary tables, groundwater potentiometric maps for the Pond 3 area at the former Seaboard Chemical property and the SIS Basin area on the landfill property are provided on Figure 2 which is also included with this report. Please contact Craig Coslett (610/435-1151) or Gary Babb (919/605-4719) if there are any questions or comments regarding this update. Seaboard Group 11 and City of High Point Gary D. Babb, P.G. ""caR... Babb & Associates, P.A. :�Q.�GE"sfoli SEAL \ i 488 Enclosures cc: Craig Coslett — Project Oversight Coordinator Jackie Drummond - NCDEQ Division of Solid Waste Mr. Eric Aufderhaar - NCDEQ FIGURES Sample Location Map Potentiometric Maps Randleman Reservoir PTRWA Property Line OW .�-DR - p 680 , JQ RI1 SIS8 �,�.���••� SW-4 Surface Water Sample Location r s RVI -SIS7 _ era _�— AW 4 �j'-S _ r �� ;{ • ,4,. ,�. AW-2 672.95 ` • -� AW-3 683.03 AW-4 684.45 681.82 4-. AWB-4 {Y' a W-SIS1 W-DR1 676.67 63 637.85 Pre -Pumping Groundwater Contour p 9 - �_ •,,,�FIW-S -DR1 637.85 Intervals Shown in Yellow` IS7 672.81 RW-SIS8 649.62 07 Observation Well'- n -_� Extraction Well 700 Stream ern rm\ttert - SoUth \nte _____?05 SIS Pipe Inlet SW-3 PW=3D o •/ ar,'`��,, w-14 6a�OW-SF1 6 ♦ ;. W-18 MW-7B 1 i 1 I �� 6 x 1 �♦ ; ,� _ ® W-112 R-1 t-r: 3 00Y Former Seaboard -.. Processing Area W-8A 690.95 -- W-12 697.25 W-14 707.22 - W-18 714.79 re -Pumping Groundwater Contour W-30 723.84 Intervals Shown in Yellow MW-7B 685.16 . OW-SF1 674.80 PW-31D 686.04 Scale: 1" = 90' PW-SF1 �-l 667.45 681.82 Observation Well _ Riverdale Drwe_- -- - Extraction Well -_ TABLES Quarterly Groundwater Data Quarterly Surface Water Data Table 1 Former Seaboard and Riverdale Drive Landfill Quarterly Groundwater Monitoring Data 1 Sample I.D. Date 0 v � 0 (7 (n 0 0 5 v 7 (D N 0 � 0 0 � N 7 CD 0 � 0 O cD 3 v (D 0 0 � 0 O m (D 7 (D jV 0 � 0 0 m v 7 CD N 0 - O - 0 -O N 7 CD � p 0 X v 7 CD > O 7 (D M N (D 7 (D v O m - v 0 �_ O M. (D n 0 3 o Cr � N (D (D n � o 0 m v 7 (D n 0 o O n 0 o � N 7 CD Q. N o o o S (D 7 (D m < N (D 7 (D CD CD Z m (� �_ 0 Q CD 0 o � (D 7 CD o_ C CD 7 (D N o 3 a m 3 (p CD (D F), � 0 o m CD (D (D < Z) C� � O - Q CD N v - 0 m < (7 Vj NC 2L Groundwater Standard (ug/1) 200 0.6 6 350 0.4 0.6 3 6000 1 0.3 50 3000 70 3 70 600 5 0.7 600 100 3 0.03 500 AW- Background 3/22/2022 1754 <20 <20 250 20 <20 <20 810 <400 <20 <20 1100 65 <20 <20 130 <20 <20 <20 <20 <20 <20 170 <60 19 6/30/2022 New Extraction Wells Online 9/27/2022 879 <5 <5 97 6 <5 <5 739" <50 6.3 <5 630 39 •+ <5 <5 47 <5 <5 <5 <5 <5 <5 54 <5 7.5 J 1 /5/2023 1660 <20 <20 180 15 J <20 <20 480 <200 9.8 J <20 1200 21 <20 <20 96 <20 <20 <20 <20 <20 <20 130 <20 8.5 J 4/6/2023 1175 <20 <20 170 8.8 J <20 <20 470 <200 8.2 J <20 830 <20 <20 <20 76 <20 <20 <20 <20 <20 <20 82 <20 ND 7/6/2023 759 <10 <10 78 5.9 J <10 <10 280 <200 7.2 J <10 580 <10 <10 <10 46 <10 <10 <10 <10 <10 <10 41 1.2 JB ND 1/3/2024 670 <1 <1 1 79 6.9 1.8 <1 270 <20 5.1 <1 490 <1 <1 <1 38 <1 <1 <1 0.73 J 0.35 J 0.30 J 45 0.51 J 2.4 3/26/2024 726 <1 <1 85 6.8 1.8 <1 370 <20 6.8 <1 510 19 <1 <1 45 <1 <1 <1 0.91 J 0.39 J 0.44 J 48 0.46 J 1.8 AWB-4 Background 3/22/2022 4119 <50 <50 550 21 J 120 <50 1200 <1000 <50 <50 3000 48 <50 <50 150 <50 <50 <50 <50 <50 <50 230 <150 ND 6/30/2022 New Extraction Wells Online 9/27/2022 3632 <25 <25 490 11 J 170 <25 1,230RS <250 35 <25 2700 <25 <25 <25 86 <25 <25 <25 <25 <25 <25 140 <25 ND 1 /5/2023 4271 <50 <50 450 <50 130 <50 920 <50 33 J <50 3300 78 <50 <50 90 <50 <50 <50 <50 <50 <50 190 <50 N D 4/6/2023 2653 <10 <10 310 <10 130 <10 880 <100 <10 <10 2100 <10 <10 <10 39 J <10 <10 <10 <10 <10 <10 74 <10 ND 7/6/2023 2874 <50 <50 300 <50 130 <50 860 <1000 <50 <50 2300 <50 <50 <50 60 <50 <50 <50 <50 <50 <50 77 6.8 JB ND 1/3/2024 1841 <1 <1 1 250 6.7 95 <1 840 <20 23 <1 1300 27 <1 <1 43 0.23 J <1 0.88 J 1.7 1 1.9 83 1.4 J 5.7 3/26/2024 1812 <1 <1 220 5.9 77 <1 990 <20 21 <1 1300 55 <1 <1 47 0.22 J <1 0.81 J 1.5 0.77 J 2.2 75 1.2 J 4.2 ND = Not Detected 'All results are in ug/I (ppb) RS = Resampled B = Compound found in blank and sample *+ = LCS and/or LCSD is outside acceptance limits, high biased J = Estimated concentration, result is between MDL and MRL E = Result exceeds calibration range Table 2 Former Seaboard and Riverdale Drive Landfill Quarterly Surface Water Monitoring Data' Sample I.D. Date ° v 0C n (n M.0 O O CD S v CD N N O O (D 3 W C (D N O O CD S CD C CD W N 0 O O (D 3 tv C (D W p O X v C (D N D n O O C (D N p0 N CD C CD A n 3 Q 0-0 � N CD C (D A O 'O-. Sv C CD n 3 Q B (D 3 tv C (D N6 2. N 0 O O m S CD C CD N O < O C� 3_ O C Q (D W (D v O O m S CD C CD A o_ C CD C CD A N 3 ° (D CD N O o CD S CD C (D A < G C) O C Q CD A G C O v - N W 7 O C CD N Surface Water Standard (ug/I) 2500 6 300 9.9 0.35 3100 1.19 488 NE 2. 60 20 0.7 11 290 2.5 0.025 6200 20000 SW-1 10/21/2021 6/30/2022 Dry New Extraction Wells Online Dry 10/19/2022 11/30/2023 Dry 1/3/2024 3 <1 <1 <1 <1 9.4 <20 <1 3.4 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 <1 3/26/2024 0 <1 <1 <1 <1 5.8 <20 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 <1 10/21/2021 Dry 6/30/2022 New Extraction Wells Online 10/19/2022 0 <1 <1 <1 <1 14 <20 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 <5 11/30/2023 Dry 1/3/2024 1 <1 <1 <1 <1 6.8 <20 <1 1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 <1 3/26/2024 0 <1 <1 <1 <1 3 <20 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 <1 SW-3 10/21/2021 6 0.95 J 2.1 <1 <1 4.6 <20 <1 <1 <1 <1 2.6 <1 <1 <1 <1 <1 <1 <2 <5 6/30/2022 New Extraction Wells Online 9/6/2022 2 <1 0.55 J <1 <1 2.8 <20 <1 <1 <1 <1 1.9 <1 <1 <1 <1 <1 <1 <3 <5 9/26/2022 1 <1 0.48 J <1 <1 2 <20 <1 <1 <1 <1 0.63 J <1 <1 <1 <1 <1 <1 <3 <5 10/19/2022 2 <1 0.88 J <1 <1 2.1 <20 <1 <1 <1 <1 1.2 <1 <1 <1 <1 <1 <1 <3 <5 11/21/2022 1 <1 0.45 J <1 <1 4.7 <20 <1 <1 <1 <1 0.85 J <1 <1 <1 <1 <1 <1 <3 <5 12/12/2022 1 <1 0.44 J <1 <1 19 <20 <1 <1 <1 <1 0.91 J <1 <1 <1 <1 <1 <1 <3 <5 1/9/2023 1 <1 <1 <1 <1 14 <20 <1 <1 <1 <1 0.92 J <1 <1 <1 <1 <1 <1 <3 <5 2/15/2023 2 <1 0.64 J 0.27 J <1 5.4 <20 <1 <1 <1 <1 1.5 <1 <1 <1 <1 <1 <1 <3 <5 3/13/2023 1 <1 <1 <1 <1 4 <20 <1 <1 <1 <1 0.76 J <1 <1 <1 <1 <1 <1 <3 <5 4/13/2023 4 <1 0.36 J <1 0.26 J 3.7 <20 <1 <1 <1 <1 0.91 J 0.57 J 0.98 J 0.58 J <1 <1 <1 0.44 J <5 6/5/2023 1 <1 <1 <1 <1 4.3 <20 <1 <1 <1 <1 1.1 <1 <1 <1 <1 <1 <1 <3 <5 7/5/2023 1 <1 0.35 J <1 <1 2.4 <20 <1 <1 <1 <1 0.64 J <1 <1 <1 <1 <1 <1 <3 <5 8/3/2023 0 <1 <1 <1 <1 1 <20 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 <5 11/30/2023 1 <1 <1 <1 <1 2.5 <20 <1 <1 <1 <1 0.59 J <1 <1 <1 <1 <1 <1 <3 <5 1/3/2024 1 <1 0.35 J <1 <1 11 <20 <1 <1 <1 <1 0.53 J <1 <1 <1 <1 <1 <1 <3 <5 3/26/2024 0 <1 <1 <1 <1 6.5 <20 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 <5 ND = Not Detected * Total VOCs does not include 1,4-dioxane values J = Estimated concentration NS = Not Sampled *+ = LCS and/or LCSD is outside acceptance limits, high biased. E = Result exceeds calibration range All results are in ug/I (ppb) 2 In -Stream Target Value 3 EPA National Recommended Water Quality Criteria 4 NC 2B Surface Water Quality Standards for Surface Water Table 2 Former Seaboard and Riverdale Drive Landfill Quarterly Surface Water Monitoring Data' Sample I.D. Date ° v 0C n (n M.0 O O CD S v CD N O O (D S W C (D N O O CD S CD C CD N 0 O O (D S tv C (D p O X v C (D D n O O C (D p0 N CD C CD n 3 Q 0-0 � N CD C (D A O 'O-. Sv C CD n 3 Q 3 (D S tv C (D 2. N 0 O O m S CD C CD N O < O n 3_ O C Q (D W (D v O O m S CD C CD o_ C CD C CD N 3 ° (D CD O o CD S CD C (D < G C) O C Q (D G C O v - W 7 O C CD Water Standard (ug/I) 25N00 6 9W 0.N35 31N00 1A9 488 NE 2N6 60Surface 0A7 1A 29N02030W0 2.5 0.0A25 6200N 20000 SW-4 10/21/2021 1100 670 120 1500 <20 0.41J 1700 100 <1 3300 <1 18 11 <1 <1 1500 <3 <5 8689 170 6/30/2022 New Extraction Wells Online 9/6/2022 3 <1 1.1 <1 <1 2.6 <1 <1 <1 <1 <1 1.5 <1 <1 <1 <1 <1 <1 <3 <5 9/26/2022 68 0.82 J 9.7 3.9 0.87 J 18 17 <1 9.5 <1 <1 15 <1 <1 <1 <1 <1 11 <3 <5 10/19/2022 58 1.4 12 4.2 1.1 14 <20 <1 1.8 <1 <1 18 <1 <1 <1 <1 <1 19 <3 <5 11/21/2022 272 3.9 50 11 4.9 68 <20 <1 73 2.6 <1 60 <1 <1 <1 <1 <1 67 <3 <5 12/12/2022 56 <1 12 5.4 <1 37 <20 <1 <1 <1 <1 22 <1 <1 <1 <1 <1 17 <3 <5 1/9/2023 74 1.4 12 5.9 0.95 J 20 <20 <1 11 <1 <1 23 <1 <1 <1 <1 <1 20 <3 <5 2/15/2023 165 3.1 26 13 2.5 22 <20 0.45 J 35 <1 <1 49 <1 0.51 J <1 <1 <1 35 0.71 J <5 3/13/2023 74 1.1 13 5.6 1.1 15 <20 <1 13 <1 <1 22 <1 <1 <1 <1 0.37 J 18 <3 <5 4/13/2023 178 2.8 28 12 2.5 34 <20 0.44 J 28 1.7 <1 61 0.52 J 0.46 J 0.25 J <1 1.2 39 <3 <5 6/5/2023 232 <1 38 18 3.5 51 <20 0.37 J 33 9.6 <1 73 <1 <1 <1 <1 0.72 J 56 <3 <5 7/5/2023 96 1.5 21 6.2 1.4 26 <20 <1 15 <1 0.15 J 30 <1 <1 0.26 J <1 <1 20 <3 <5 8/3/2023 2362 30 370 160 39 470 <20 7.7 520 39 <1 680 <1 2.3 3.8 2.2 1.7 500 6.4 <5 11/30/2023 1492 25 250 90 27 300 <20 8.8 400 73 <1 330 <1 2.3 3.2 2 2.3 270 8.1 <5 1/3/2024 61 1.7 14 0.45 J 1.1 19 <20 0.35 J 28 <1 <1 3.4 <1 <1 <1 <1 <1 12 0.49 J <5 3/26/2024 23 <1 4.4 0.83 J 0.43 J 30 <20 <1 3.5 6.9 <1 4.6 <1 <1 <1 <1 <1 2 <3 <5 10/21/2021 0 <1 <1 <1 <1 2.2 <20 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 <5 6/30/2022 New Extraction Wells Online 9/6/2022 0 <1 <1 <1 <1 9.6 <20 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 <5 9/26/2022 0 <1 <1 <1 <1 3.2 <20 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 <5 10/19/2022 0 <1 <1 <1 <1 1.6 <20 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 <5 11/21/2022 0 <1 <1 <1 <1 2.8 <20 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 <5 12/12/2022 0 <1 <1 <1 <1 24 <20 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 <5 1/9/2023 30 <1 <1 <1 <1 22 18 J <1 <1 <1 <1 0.61 J <1 <1 <1 <1 <1 <1 <3 11 2/15/2023 1 <1 <1 <1 <1 11 <20 <1 <1 <1 <1 1.2 <1 <1 <1 <1 <1 <1 <3 <5 3/13/2023 5 <1 <1 <1 <1 3.6 5.4 J <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 <5 4/13/2023 1 <1 <1 <1 <1 3.9 <20 <1 0.45 J <1 0.14 J 0.52 J 0.34 J <1 <1 <1 <1 <1 <3 <5 6/5/2023 0 <1 <1 <1 <1 2.9 <20 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 <5 7/5/2023 0 <1 <1 <1 <1 1.8 <20 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 <5 8/3/2023 0 <1 <1 <1 <1 2.1 <20 <1 <1 <1 0.15 J <1 <1 <1 <1 <1 <1 <1 <3 <5 11/30/2023 0 <1 <1 <1 <1 7.6 <20 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 <5 1/3/2024 0 <1 <1 <1 <1 18 <20 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 <5 3/26/2024 0 <1 <1 <1 <1 11 <20 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 <5 L I I I I I ND = Not Detected All results are in ug/I (ppb) 2 In -Stream Target Value * Total VOCs does not include 1,4-dioxane values *+ = LCS and/or LCSD is outside acceptance limits, high biased. 3 EPA National Recommended Water Quality Criteria J = Estimated concentration E = Result exceeds calibration range 4 NC 2B Surface Water Quality Standards for Surface Water LABORATORY REPORT • % eurofins Environment Testing I ANALYTICAL REPORT C PREPARED FOR Attn: Gary Babb Babb & Associates 5506 Bradford Pear Court Raleigh, North Carolina 27606 Generated 4/8/2024 1:29:16 PM JOB DESCRIPTION Seaboard- Quarterly Surface Waters JOB NUMBER 680-248614-1 This report may not be reproduced except in full, and with written approval from the laboratory. The results relate only to the samples tested. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written approval of the laboratory. All questions should be directed to the Eurofins Environment Testing Southeast, LLC Project Manager. Generated 4/8/2024 1:29:16 PM Authorized for release by John Andros, Project Manager I John.AndrosCa).et.eurofinsus.com (404)944-4744 Eurofins Savannah is a laboratory within Eurofins Environment Testing Southeast, LLC, a company within Eurofins Environment Testing Group of Companies Page 2 of 49 4/8/2024 Sample Summary Client: Babb & Associates Project/Site: Seaboard- Quarterly Surface Waters Lab Sample ID Client Sample ID Matrix Collected Received 680-248614-1 AW-3 Surface Water 03/26/24 10:20 03/27/24 10:17 680-248614-2 AWB-4 Surface Water 03/26/24 09:55 03/27/24 10:17 680-248614-3 SW-1 Surface Water 03/26/24 07:50 03/27/24 10:17 680-248614-4 SW-2 Surface Water 03/26/24 08:05 03/27/24 10:17 680-248614-5 SW-3 Surface Water 03/26/24 08:30 03/27/24 10:17 680-248614-6 SW-4 Surface Water 03/26/24 09:15 03/27/24 10:17 680-248614-7 SW-5 Surface Water 03/26/24 08:20 03/27/24 10:17 680-248614-8 Trip Blank Water 03/26/24 00:00 03/27/24 10:17 680-248614-9 Trip Blank Water 03/26/24 00:00 03/27/24 10:17 Job ID: 680-248614-1 Eurofins Savannah Page 3 of 49 4/8/2024 Method Summary Client: Babb & Associates Project/Site: Seaboard- Quarterly Surface Waters Job ID: 680-248614-1 Method Method Description Protocol Laboratory 8260D Volatile Organic Compounds by GC/MS SW846 EET SAV 8260D SIM 14D Volatile Organic Compounds (GC/MS) SW846 EET SAV 5030B Purge and Trap SW846 EET SAV 5030C Purge and Trap SW846 EET SAV Protocol References: SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. Laboratory References: EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL (912)354-7858 Eurofins Savannah Page 4 of 49 4/8/2024 Definitions/Glossary Client: Babb & Associates Job ID: 680-248614-1 Project/Site: Seaboard- Quarterly Surface Waters U Qualifiers GUMS VOA Qualifier Qualifier Description J Indicates an estimated value. J2 Estimated value; value may not be accurate. U Indicates that the compound was analyzed for but not detected. Glossary Abbreviation These commonly used abbreviations may or may not be present in this report. Listed under the "Y column to designate that the result is reported on a dry weight basis %R Percent Recovery CFL Contains Free Liquid CFU Colony Forming Unit CNF Contains No Free Liquid DER Duplicate Error Ratio (normalized absolute difference) Dil Fac Dilution Factor DL Detection Limit (DoD/DOE) DL, RA, RE, IN Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample DLC Decision Level Concentration (Radiochemistry) EDL Estimated Detection Limit (Dioxin) LOD Limit of Detection (DoD/DOE) LOQ Limit of Quantitation (DoD/DOE) MCL EPA recommended "Maximum Contaminant Level' MDA Minimum Detectable Activity (Radiochemistry) MDC Minimum Detectable Concentration (Radiochemistry) MDL Method Detection Limit ML Minimum Level (Dioxin) MPN Most Probable Number MQL Method Quantitation Limit NC Not Calculated ND Not Detected at the reporting limit (or MDL or EDL if shown) NEG Negative / Absent POS Positive / Present PQL Practical Quantitation Limit PRES Presumptive QC Quality Control RER Relative Error Ratio (Radiochemistry) RL Reporting Limit or Requested Limit (Radiochemistry) RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin) TEQ Toxicity Equivalent Quotient (Dioxin) TNTC Too Numerous To Count Eurofins Savannah Page 5 of 49 4/8/2024 Case Narrative Client: Babb & Associates Job ID: 680-248614-1 Project: Seaboard- Quarterly Surface Waters Job ID: 680-248614-1 Eurofins Savannah Job Narrative 680-248614-1 Receipt L The samples were received on 3/27/2024 10:17 AM. Unless otherwise noted below, the samples arrived in good condition, and, where required, properly preserved and on ice. The temperature of the cooler at receipt time was 1.1 °C. GC/MS VOA No additional analytical or quality issues were noted, other than those described above or in the Definitions/ Glossary page. Page 6 of 49 Eurofins Savannah 4/8/2024 Detection Summary Client: Babb & Associates Project/Site: Seaboard- Quarterly Surface Waters Job ID: 680-248614-1 Client Sample ID: AW-3 Lab Sample ID: 680-248614-1 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 370 25 16 ug/L 50 8260D SIM 14D Total/NA 1,1-Dichloroethane 85 1.0 0.33 ug/L 1 8260D Total/NA 1,1-Dichloroethene 6.8 1.0 0.33 ug/L 1 8260D Total/NA 1,2-Dichlorobenzene 0.67 J 1.0 0.31 ug/L 1 8260D Total/NA 1,2-Dichloroethane 1.8 1.0 0.25 ug/L 1 8260D Total/NA 1,4-Dichlorobenzene 1.1 1.0 0.31 ug/L 1 8260D Total/NA Benzene 6.8 1.0 0.27 ug/L 1 8260D Total/NA Chloroethane 19 5.0 4.6 ug/L 1 8260D Total/NA cis-1,2-Dichloroethene 45 1.0 0.25 ug/L 1 8260D Total/NA o-Xylene 0.46 J 1.0 0.26 ug/L 1 8260D Total/NA Toluene 0.91 J 1.0 0.25 ug/L 1 8260D Total/NA trans- 1,2-Dichloroethene 0.39 J 1.0 0.34 ug/L 1 8260D Total/NA Trichloroethene 0.44 J 1.0 0.20 ug/L 1 8260D Total/NA Vinyl chloride 48 1.0 0.40 ug/L 1 8260D Total/NA Xylenes (total) 0.46 J 3.0 0.23 ug/L 1 8260D Total/NA Chlorobenzene - DL 510 5.0 0.75 ug/L 5 8260D Total/NA Client Sample ID: AWB-4 Lab Sample ID: 680-248614-2 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 990 50 32 ug/L 100 8260D SIM 14D Total/NA 1,1-Dichloroethene 5.9 1.0 0.33 ug/L 1 8260D Total/NA 1,2-Dichlorobenzene 1.2 1.0 0.31 ug/L 1 8260D Total/NA 1,2-Dichloroethane 77 1.0 0.25 ug/L 1 8260D Total/NA 1,4-Dichlorobenzene 3.0 1.0 0.31 ug/L 1 8260D Total/NA Benzene 21 1.0 0.27 ug/L 1 8260D Total/NA Chloroethane 55 50 46 ug/L 10 8260D Total/NA cis-1,2-Dichloroethene 47 1.0 0.25 ug/L 1 8260D Total/NA Ethylbenzene 0.22 J 1.0 0.20 ug/L 1 8260D Total/NA o-Xylene 1.2 1.0 0.26 ug/L 1 8260D Total/NA Tetrachloroethene 0.81 J 1.0 0.35 ug/L 1 8260D Total/NA Toluene 1.5 1.0 0.25 ug/L 1 8260D Total/NA trans- 1,2-Dichloroethene 0.77 J 1.0 0.34 ug/L 1 8260D Total/NA Trichloroethene 2.2 1.0 0.20 ug/L 1 8260D Total/NA Vinyl chloride 75 1.0 0.40 ug/L 1 8260D Total/NA Xylenes (total) 1.2 J 3.0 0.23 ug/L 1 8260D Total/NA 1,1-Dichloroethane - DL 220 10 3.3 ug/L 10 8260D Total/NA Chlorobenzene - DL 1300 10 1.5 ug/L 10 8260D Total/NA Client Sample ID: SW-1 Lab Sample ID: 680-248614-3 1 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 5.8 0.50 0.32 ug/L 1 8260D SIM 14D Total/NA Client Sample ID: SW-2 Lab Sample ID: 680-248614-4 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 3.0 0.50 0.32 ug/L 1 8260D SIM 14D Total/NA Client Sample ID: SW-3 Lab Sample ID: 680-248614-5 Analyte 1,4-Dioxane Result Qualifier RL 6.5 0.50 This Detection Summary does not include radiochemical test results. MDL Unit Dil Fac D Method Prep Type 0.32 ug/L 1 8260D SIM 14D Total/NA 0 L Eurofins Savannah Page 7 of 49 4/8/2024 Detection Summary Client: Babb & Associates Job ID: 680-248614-1 Project/Site: Seaboard- Quarterly Surface Waters Client Sample ID: SW-4 Lab Sample ID: 680-248614-6 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 30 25 16 ug/L 50 8260D SIM 14D Total/NA ' 1,1-Dichloroethane 4.4 1.0 0.33 ug/L 1 8260D Total/NA 1,1-Dichloroethene 0.83 J 1.0 0.33 ug/L 1 8260D Total/NA 1,2-Dichloroethane 0.43 J 1.0 0.25 ug/L 1 8260D Total/NA Chlorobenzene 3.5 1.0 0.15 ug/L 1 8260D Total/NA Chloroethane 6.9 5.0 4.6 ug/L 1 8260D Total/NA cis- 1,2-Dichloroethene 4.6 1.0 0.25 ug/L 1 8260D Total/NA Vinyl chloride 2.0 1.0 0.40 ug/L 1 8260D Total/NA Client Sample ID: SW-5 Lab Sample ID: 680-248614-7 [Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type C 1,4-Dioxane 11 0.50 0.32 ug/L 1 8260D SIM 14D Total/NA Client Sample ID: Trip Blank Lab Sample ID: 680-248614-8 1 No Detections. Client Sample ID: Trip Blank Lab Sample ID: 680-248614-9 ENo Detections This Detection Summary does not include radiochemical test results. Page 8 of 49 Eurofins Savannah 4/8/2024 Client Sample Results Client: Babb & Associates Project/Site: Seaboard- Quarterly Surface Waters Job ID: 680-248614-1 Client Sample ID: AW-3 Lab Sample ID: 680-248614-1 Date Collected: 03/26/24 10:20 Matrix: Surface Water Date Received: 03/27/24 10:17 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane 370 25 16 ug/L 04/07/24 03:03 50 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 102 46 - 154 04107124 03:03 50 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane 1.0 U 1.0 0.36 ug/L 04/03/24 19:48 1 1,1,1-Trichloroethane 1.0 U 1.0 0.21 ug/L 04/03/24 19:48 1 1,1,2,2-Tetrachloroethane 1.0 U 1.0 0.40 ug/L 04/03/24 19:48 1 1,1,2-Trichloroethane 1.0 U 1.0 0.32 ug/L 04/03/24 19:48 1 1,1-Dichloroethane 85 1.0 0.33 ug/L 04/03/24 19:48 1 1,1-Dichloroethene 6.8 1.0 0.33 ug/L 04/03/24 19:48 1 1,2,3-Trichloropropane 1.0 U 1.0 0.48 ug/L 04/03/24 19:48 1 1,2-Dibromo-3-Chloropropane 5.0 U 5.0 1.8 ug/L 04/03/24 19:48 1 1,2-Dibromoethane 1.0 U 1.0 0.33 ug/L 04/03/24 19:48 1 1,2-Dichlorobenzene 0.67 J 1.0 0.31 ug/L 04/03/24 19:48 1 1,2-Dichloroethane 1.8 1.0 0.25 ug/L 04/03/24 19:48 1 1,2-Dichloropropane 1.0 U 1.0 0.22 ug/L 04/03/24 19:48 1 1,4-Dichlorobenzene 1.1 1.0 0.31 ug/L 04/03/24 19:48 1 2-Butanone 10 U 10 6.4 ug/L 04/03/24 19:48 1 2-Hexanone 10 U J2 10 3.2 ug/L 04/03/24 19:48 1 4-Methyl-2-pentanone 10 U J2 10 2.7 ug/L 04/03/24 19:48 1 Acetone 20 U 20 3.7 ug/L 04/03/24 19:48 1 Acrylonitrile 20 U 20 5.5 ug/L 04/03/24 19:48 1 Benzene 6.8 1.0 0.27 ug/L 04/03/24 19:48 1 Bromochloromethane 1.0 U 1.0 0.34 ug/L 04/03/24 19:48 1 Bromodichloromethane 1.0 U 1.0 0.25 ug/L 04/03/24 19:48 1 Bromoform 1.0 U 1.0 0.59 ug/L 04/03/24 19:48 1 Bromomethane 5.0 U 5.0 3.7 ug/L 04/03/24 19:48 1 Carbon disulfide 5.0 U 5.0 0.43 ug/L 04/03/24 19:48 1 Carbon tetrachloride 1.0 U 1.0 0.30 ug/L 04/03/24 19:48 1 Chloroethane 19 5.0 4.6 ug/L 04/03/24 19:48 1 Chloroform 1.0 U 1.0 0.27 ug/L 04/03/24 19:48 1 Chloromethane 1.0 U 1.0 0.54 ug/L 04/03/24 19:48 1 cis-1,2-Dichloroethene 45 1.0 0.25 ug/L 04/03/24 19:48 1 cis-1,3-Dichloropropene 1.0 U 1.0 0.26 ug/L 04/03/24 19:48 1 Dibromochloromethane 1.0 U 1.0 0.39 ug/L 04/03/24 19:48 1 Dibromomethane 1.0 U 1.0 0.34 ug/L 04/03/24 19:48 1 Ethylbenzene 1.0 U 1.0 0.20 ug/L 04/03/24 19:48 1 lodomethane 10 U 10 3.9 ug/L 04/03/24 19:48 1 m,p-Xylenes 2.0 U 2.0 0.49 ug/L 04/03/24 19:48 1 Methylene Chloride 5.0 U 5.0 3.2 ug/L 04/03/24 19:48 1 o-Xylene 0.46 J 1.0 0.26 ug/L 04/03/24 19:48 1 Styrene 1.0 U 1.0 0.27 ug/L 04/03/24 19:48 1 Tetrachloroethene 1.0 U 1.0 0.35 ug/L 04/03/24 19:48 1 Toluene 0.91 J 1.0 0.25 ug/L 04/03/24 19:48 1 trans-1,2-Dichloroethene 0.39 J 1.0 0.34 ug/L 04/03/24 19:48 1 trans- 1,3-Dichloropropene 1.0 U 1.0 0.23 ug/L 04/03/24 19:48 1 trans- 1,4-Dichloro-2-butene 2.0 U 2.0 1.3 ug/L 04/03/24 19:48 1 Eurofins Savannah Page 9 of 49 4/8/2024 Client Sample Results Client: Babb & Associates Project/Site: Seaboard- Quarterly Surface Waters Client Sample ID: AW-3 Date Collected: 03/26/24 10:20 Date Received: 03/27/24 10:17 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit Trichloroethene 0.44 J 1.0 0.20 ug/L Trichlorofluoromethane 1.0 U 1.0 0.33 ug/L Vinyl acetate 5.0 U J2 5.0 0.69 ug/L Vinyl chloride 48 1.0 0.40 ug/L Xylenes (total) 0.46 J 3.0 0.23 ug/L Surrogate %Recovery Qualifier Limits 1,2-Dichloroethane-d4 (Surr) 75 60- 124 4-Bromofluorobenzene (Surr) 101 70 - 130 Dibromofluoromethane (Surr) 84 70 - 130 Toluene-d8 (Surr) 96 70 - 130 Method: SW846 8260D - Volatile Organic Compounds by GC/MS - DL Analyte Result Qualifier RL MDL Unit Chlorobenzene 510 5.0 0.75 ug/L Surrogate %Recovery Qualifier Limits 1,2-Dichloroethane-d4 (Surr) 80 60- 124 4-Bromofluorobenzene (Surr) 99 70 - 130 Dibromofluoromethane (Surr) 91 70 - 130 Toluene-d8 (Surr) 104 70 - 130 Job ID: 680-248614-1 Lab Sample ID: 680-248614-1 Matrix: Surface Water D Prepared Analyzed Dil Fac 04/03/24 19:48 1 04/03/24 19:48 1 04/03/24 19:48 1 04/03/24 19:48 1 04/03/24 19:48 1 Prepared Analyzed Dil Fac 04/03/24 19:48 1 04103124 19:48 1 04103124 19:48 1 04103124 19:48 1 D Prepared Analyzed Dil Fac 04/04/2418:50 5 Prepared Analyzed Dil Fac 04104124 18:50 5 04104124 18:50 5 04104124 18:50 5 04104124 18:50 5 Eurofins Savannah Page 10 of 49 4/8/2024 Client Sample Results Client: Babb & Associates Project/Site: Seaboard- Quarterly Surface Waters Job ID: 680-248614-1 Client Sample ID: AWB-4 Lab Sample ID: 680-248614-2 Date Collected: 03/26/24 09:55 Matrix: Surface Water Date Received: 03/27/24 10:17 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit 1,4-Dioxane 990 50 32 ug/L Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 95 46 - 154 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL 1,1,1,2-Tetrachloroethane 1.0 U 1.0 1,1,1-Trichloroethane 1.0 U 1.0 1,1,2,2-Tetrachloroethane 1.0 U 1.0 1,1,2-Trichloroethane 1.0 U 1.0 1,1-Dichloroethene 5.9 1.0 1,2,3-Trichloropropane 1.0 U 1.0 1,2-Dibromo-3-Chloropropane 5.0 U 5.0 1,2-Dibromoethane 1.0 U 1.0 1,2-Dichlorobenzene 1.2 1.0 1,2-Dichloroethane 77 1.0 1,2-Dichloropropane 1.0 U 1.0 1,4-Dichlorobenzene 3.0 1.0 2-Butanone 10 U 10 2-Hexanone 10 U J2 10 4-Methyl-2-pentanone 10 U J2 10 Acetone 20 U 20 Acrylonitrile 20 U 20 Benzene 21 1.0 Bromochloromethane 1.0 U 1.0 Bromodichloromethane 1.0 U 1.0 Bromoform 1.0 U 1.0 Bromomethane 5.0 U 5.0 Carbon disulfide 5.0 U 5.0 Carbon tetrachloride 1.0 U 1.0 Chloroethane 55 50 Chloroform 1.0 U 1.0 Chloromethane 1.0 U 1.0 cis-1,2-Dichloroethene 47 1.0 cis-1,3-Dichloropropene 1.0 U 1.0 Dibromochloromethane 1.0 U 1.0 Dibromomethane 1.0 U 1.0 Ethylbenzene 0.22 J 1.0 lodomethane 10 U 10 m,p-Xylenes 2.0 U 2.0 Methylene Chloride 5.0 U 5.0 o-Xylene 1.2 1.0 Styrene 1.0 U 1.0 Tetrachloroethene 0.81 J 1.0 Toluene 1.5 1.0 trans-1,2-Dichloroethene 0.77 J 1.0 trans- 1,3-Dichloropropene 1.0 U 1.0 trans- 1,4-Dichloro-2-butene 2.0 U 2.0 Trichloroethene 2.2 1.0 D Prepared Analyzed Dil Fac 04/07/24 03:29 100 Prepared Analyzed Dil Fac 04107124 03:29 100 MDL Unit D Prepared Analyzed Dil Fac 0.36 ug/L 04/03/24 20:10 1 0.21 ug/L 04/03/24 20:10 1 0.40 ug/L 04/03/24 20:10 1 0.32 ug/L 04/03/24 20:10 1 0.33 ug/L 04/03/24 20:10 1 0.48 ug/L 04/03/24 20:10 1 1.8 ug/L 04/03/24 20:10 1 0.33 ug/L 04/03/24 20:10 1 0.31 ug/L 04/03/24 20:10 1 0.25 ug/L 04/03/24 20:10 1 0.22 ug/L 04/03/24 20:10 1 0.31 ug/L 04/03/24 20:10 1 6.4 ug/L 04/03/24 20:10 1 3.2 ug/L 04/03/24 20:10 1 2.7 ug/L 04/03/24 20:10 1 3.7 ug/L 04/03/24 20:10 1 5.5 ug/L 04/03/24 20:10 1 0.27 ug/L 04/03/24 20:10 1 0.34 ug/L 04/03/24 20:10 1 0.25 ug/L 04/03/24 20:10 1 0.59 ug/L 04/03/24 20:10 1 3.7 ug/L 04/03/24 20:10 1 0.43 ug/L 04/03/24 20:10 1 0.30 ug/L 04/03/24 20:10 1 46 ug/L 04/05/2418:29 10 0.27 ug/L 04/03/24 20:10 1 0.54 ug/L 04/03/24 20:10 1 0.25 ug/L 04/03/24 20:10 1 0.26 ug/L 04/03/24 20:10 1 0.39 ug/L 04/03/24 20:10 1 0.34 ug/L 04/03/24 20:10 1 0.20 ug/L 04/03/24 20:10 1 3.9 ug/L 04/03/24 20:10 1 0.49 ug/L 04/03/24 20:10 1 3.2 ug/L 04/03/24 20:10 1 0.26 ug/L 04/03/24 20:10 1 0.27 ug/L 04/03/24 20:10 1 0.35 ug/L 04/03/24 20:10 1 0.25 ug/L 04/03/24 20:10 1 0.34 ug/L 04/03/24 20:10 1 0.23 ug/L 04/03/24 20:10 1 1.3 ug/L 04/03/24 20:10 1 0.20 ug/L 04/03/24 20:10 1 Eurofins Savannah Page 11 of 49 4/8/2024 Client Sample Results Client: Babb & Associates Project/Site: Seaboard- Quarterly Surface Waters Job ID: 680-248614-1 Client Sample ID: AWB-4 Lab Sample ID: 680-248614-2 Date Collected: 03/26/24 09:55 Matrix: Surface Water Date Received: 03/27/24 10:17 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichlorofluoromethane 1.0 U 1.0 0.33 ug/L 04/03/24 20:10 1 Vinyl acetate 5.0 U J2 5.0 0.69 ug/L 04/03/24 20:10 1 Vinyl chloride 75 1.0 0.40 ug/L 04/03/24 20:10 1 Xylenes (total) 1.2 J 3.0 0.23 ug/L 04/03/24 20:10 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 71 60- 124 04103124 20:10 1 1,2-Dichloroethane-d4 (Surr) 87 60- 124 04105124 18:29 10 4-Bromofluorobenzene (Surr) 98 70 - 130 04103124 20:10 1 4-Bromofluorobenzene (Surr) 87 70 - 130 04105124 18:29 10 Dibromofluoromethane (Surr) 85 70 - 130 04103124 20:10 1 Dibromofluoromethane (Surr) 109 70 - 130 04105124 18:29 10 Toluene-d8 (Surr) 95 70 - 130 04103124 20:10 1 Toluene-d8 (Surr) 103 70 - 130 04105124 18:29 10 Method: SW846 8260D - Volatile Organic Compounds by GC/MS - DL Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1-Dichloroethane 220 10 3.3 ug/L 04/04/2419:42 10 Chlorobenzene 1300 10 1.5 ug/L 04/04/2419:42 10 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 109 60- 124 04104124 19:42 10 4-Bromofluorobenzene (Surr) 121 70 - 130 04104124 19:42 10 Dibromofluoromethane (Surr) 90 70 - 130 04104124 19:42 10 Toluene-d8 (Surr) 98 70 - 130 04104124 19:42 10 Eurofins Savannah Page 12 of 49 4/8/2024 Client Sample Results Client: Babb & Associates Project/Site: Seaboard- Quarterly Surface Waters Job ID: 680-248614-1 Client Sample ID: SW-1 Lab Sample ID: 680-248614-3 Date Collected: 03/26/24 07:50 Matrix: Surface Water Date Received: 03/27/24 10:17 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane 5.8 0.50 0.32 ug/L 04/06/24 20:14 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 119 46 - 154 04106124 20:14 1 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane 1.0 U 1.0 0.36 ug/L 04/03/24 20:32 1 1,1,1-Trichloroethane 1.0 U 1.0 0.21 ug/L 04/03/24 20:32 1 1,1,2,2-Tetrachloroethane 1.0 U 1.0 0.40 ug/L 04/03/24 20:32 1 1,1,2-Trichloroethane 1.0 U 1.0 0.32 ug/L 04/03/24 20:32 1 1,1-Dichloroethane 1.0 U 1.0 0.33 ug/L 04/03/24 20:32 1 1,1-Dichloroethene 1.0 U 1.0 0.33 ug/L 04/03/24 20:32 1 1,2,3-Trichloropropane 1.0 U 1.0 0.48 ug/L 04/03/24 20:32 1 1,2-Dibromo-3-Chloropropane 5.0 U 5.0 1.8 ug/L 04/03/24 20:32 1 1,2-Dibromoethane 1.0 U 1.0 0.33 ug/L 04/03/24 20:32 1 1,2-Dichlorobenzene 1.0 U 1.0 0.31 ug/L 04/03/24 20:32 1 1,2-Dichloroethane 1.0 U 1.0 0.25 ug/L 04/03/24 20:32 1 1,2-Dichloropropane 1.0 U 1.0 0.22 ug/L 04/03/24 20:32 1 1,4-Dichlorobenzene 1.0 U 1.0 0.31 ug/L 04/03/24 20:32 1 2-Butanone 10 U 10 6.4 ug/L 04/03/24 20:32 1 2-Hexanone 10 U J2 10 3.2 ug/L 04/03/24 20:32 1 4-Methyl-2-pentanone 10 U J2 10 2.7 ug/L 04/03/24 20:32 1 Acetone 20 U 20 3.7 ug/L 04/03/24 20:32 1 Acrylonitrile 20 U 20 5.5 ug/L 04/03/24 20:32 1 Benzene 1.0 U 1.0 0.27 ug/L 04/03/24 20:32 1 Bromochloromethane 1.0 U 1.0 0.34 ug/L 04/03/24 20:32 1 Bromodichloromethane 1.0 U 1.0 0.25 ug/L 04/03/24 20:32 1 Bromoform 1.0 U 1.0 0.59 ug/L 04/03/24 20:32 1 Bromomethane 5.0 U 5.0 3.7 ug/L 04/03/24 20:32 1 Carbon disulfide 5.0 U 5.0 0.43 ug/L 04/03/24 20:32 1 Carbon tetrachloride 1.0 U 1.0 0.30 ug/L 04/03/24 20:32 1 Chlorobenzene 1.0 U 1.0 0.15 ug/L 04/05/2413:54 1 Chloroethane 5.0 U 5.0 4.6 ug/L 04/03/24 20:32 1 Chloroform 1.0 U 1.0 0.27 ug/L 04/03/24 20:32 1 Chloromethane 1.0 U 1.0 0.54 ug/L 04/03/24 20:32 1 cis-1,2-Dichloroethene 1.0 U 1.0 0.25 ug/L 04/03/24 20:32 1 cis-1,3-Dichloropropene 1.0 U 1.0 0.26 ug/L 04/03/24 20:32 1 Dibromochloromethane 1.0 U 1.0 0.39 ug/L 04/03/24 20:32 1 Dibromomethane 1.0 U 1.0 0.34 ug/L 04/03/24 20:32 1 Ethylbenzene 1.0 U 1.0 0.20 ug/L 04/03/24 20:32 1 lodomethane 10 U 10 3.9 ug/L 04/03/24 20:32 1 m,p-Xylenes 2.0 U 2.0 0.49 ug/L 04/03/24 20:32 1 Methylene Chloride 5.0 U 5.0 3.2 ug/L 04/03/24 20:32 1 o-Xylene 1.0 U 1.0 0.26 ug/L 04/03/24 20:32 1 Styrene 1.0 U 1.0 0.27 ug/L 04/03/24 20:32 1 Tetrachloroethene 1.0 U 1.0 0.35 ug/L 04/03/24 20:32 1 Toluene 1.0 U 1.0 0.25 ug/L 04/03/24 20:32 1 trans- 1,2-Dichloroethene 1.0 U 1.0 0.34 ug/L 04/03/24 20:32 1 trans- 1,3-Dichloropropene 1.0 U 1.0 0.23 ug/L 04/03/24 20:32 1 Eurofins Savannah Page 13 of 49 4/8/2024 Client Sample Results Client: Babb & Associates Job ID: 680-248614-1 Project/Site: Seaboard- Quarterly Surface Waters Client Sample ID: SW-1 Lab Sample ID: 680-248614-3 Date Collected: 03/26/24 07:50 Matrix: Surface Water Date Received: 03/27/24 10:17 Method: SW846 8260D - Volatile Organic Compounds by GUMS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac trans- 1,4-Dichloro-2-butene 2.0 U 2.0 1.3 ug/L 04/03/24 20:32 1 Trichloroethene 1.0 U 1.0 0.20 ug/L 04/03/24 20:32 1 Trichlorofluoromethane 1.0 U 1.0 0.33 ug/L 04/03/24 20:32 1 Vinyl acetate 5.0 U J2 5.0 0.69 ug/L 04/03/24 20:32 1 Vinyl chloride 1.0 U 1.0 0.40 ug/L 04/03/24 20:32 1 Xylenes (total) 3.0 U 3.0 0.23 ug/L 04/03/24 20:32 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed DU Fac 1,2-Dichloroethane-d4 (Surr) 77 60- 124 04103124 20:32 1 1,2-Dichloroethane-d4 (Surr) 90 60- 124 04105124 13:54 1 4-Bromofluorobenzene (Surr) 104 70 - 130 04103124 20:32 1 4-Bromofluorobenzene (Surr) 97 70 - 130 04105124 13:54 1 Dibromofluoromethane (Surr) 87 70 - 130 04103124 20:32 1 Dibromofluoromethane (Surr) 95 70 - 130 04105124 13:54 1 Toluene-d8 (Surr) 102 70 - 130 04103124 20:32 1 Toluene-d8 (Surr) 109 70 - 130 04105124 13:54 1 Eurofins Savannah Page 14 of 49 4/8/2024 Client Sample Results Client: Babb & Associates Project/Site: Seaboard- Quarterly Surface Waters Job ID: 680-248614-1 Client Sample ID: SW-2 Lab Sample ID: 680-248614-4 Date Collected: 03/26/24 08:05 Matrix: Surface Water Date Received: 03/27/24 10:17 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane 3.0 0.50 0.32 ug/L 04/07/2413:30 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 131 46 - 154 04107124 13:30 1 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane 1.0 U 1.0 0.36 ug/L 04/04/24 14:19 1 1,1,1-Trichloroethane 1.0 U 1.0 0.21 ug/L 04/04/24 14:19 1 1,1,2,2-Tetrachloroethane 1.0 U 1.0 0.40 ug/L 04/04/24 14:19 1 1,1,2-Trichloroethane 1.0 U 1.0 0.32 ug/L 04/04/24 14:19 1 1,1-Dichloroethane 1.0 U 1.0 0.33 ug/L 04/04/24 14:19 1 1,1-Dichloroethene 1.0 U 1.0 0.33 ug/L 04/04/24 14:19 1 1,2,3-Trichloropropane 1.0 U 1.0 0.48 ug/L 04/04/24 14:19 1 1,2-Dibromo-3-Chloropropane 5.0 U 5.0 1.8 ug/L 04/04/24 14:19 1 1,2-Dibromoethane 1.0 U 1.0 0.33 ug/L 04/04/24 14:19 1 1,2-Dichlorobenzene 1.0 U 1.0 0.31 ug/L 04/04/24 14:19 1 1,2-Dichloroethane 1.0 U 1.0 0.25 ug/L 04/04/24 14:19 1 1,2-Dichloropropane 1.0 U 1.0 0.22 ug/L 04/04/24 14:19 1 1,4-Dichlorobenzene 1.0 U 1.0 0.31 ug/L 04/04/24 14:19 1 2-Butanone 10 U 10 6.4 ug/L 04/04/24 14:19 1 2-Hexanone 10 U 10 3.2 ug/L 04/04/24 14:19 1 4-Methyl-2-pentanone 10 U 10 2.7 ug/L 04/04/24 14:19 1 Acetone 20 U 20 3.7 ug/L 04/04/24 14:19 1 Acrylonitrile 20 U 20 5.5 ug/L 04/04/24 14:19 1 Benzene 1.0 U 1.0 0.27 ug/L 04/04/24 14:19 1 Bromochloromethane 1.0 U 1.0 0.34 ug/L 04/04/24 14:19 1 Bromodichloromethane 1.0 U 1.0 0.25 ug/L 04/04/24 14:19 1 Bromoform 1.0 U 1.0 0.59 ug/L 04/04/24 14:19 1 Bromomethane 5.0 U 5.0 3.7 ug/L 04/04/24 14:19 1 Carbon disulfide 5.0 U 5.0 0.43 ug/L 04/04/24 14:19 1 Carbon tetrachloride 1.0 U 1.0 0.30 ug/L 04/04/24 14:19 1 Chlorobenzene 1.0 U 1.0 0.15 ug/L 04/04/24 14:19 1 Chloroethane 5.0 U 5.0 4.6 ug/L 04/04/24 14:19 1 Chloroform 1.0 U 1.0 0.27 ug/L 04/04/24 14:19 1 Chloromethane 1.0 U 1.0 0.54 ug/L 04/04/24 14:19 1 cis-1,2-Dichloroethene 1.0 U 1.0 0.25 ug/L 04/04/24 14:19 1 cis-1,3-Dichloropropene 1.0 U 1.0 0.26 ug/L 04/04/24 14:19 1 Dibromochloromethane 1.0 U 1.0 0.39 ug/L 04/04/24 14:19 1 Dibromomethane 1.0 U 1.0 0.34 ug/L 04/04/24 14:19 1 Ethylbenzene 1.0 U 1.0 0.20 ug/L 04/04/24 14:19 1 lodomethane 10 U 10 3.9 ug/L 04/04/24 14:19 1 m,p-Xylenes 2.0 U 2.0 0.49 ug/L 04/04/24 14:19 1 Methylene Chloride 5.0 U 5.0 3.2 ug/L 04/04/24 14:19 1 o-Xylene 1.0 U 1.0 0.26 ug/L 04/04/24 14:19 1 Styrene 1.0 U 1.0 0.27 ug/L 04/04/24 14:19 1 Tetrachloroethene 1.0 U 1.0 0.35 ug/L 04/04/24 14:19 1 Toluene 1.0 U 1.0 0.25 ug/L 04/04/24 14:19 1 trans- 1,2-Dichloroethene 1.0 U 1.0 0.34 ug/L 04/04/24 14:19 1 trans- 1,3-Dichloropropene 1.0 U 1.0 0.23 ug/L 04/04/24 14:19 1 Eurofins Savannah Page 15 of 49 4/8/2024 Client Sample Results Client: Babb & Associates Job ID: 680-248614-1 Project/Site: Seaboard- Quarterly Surface Waters Client Sample ID: SW-2 Lab Sample ID: 680-248614-4 Date Collected: 03/26/24 08:05 Matrix: Surface Water Date Received: 03/27/24 10:17 Method: SW846 8260D - Volatile Organic Compounds by GUMS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac trans- 1,4-Dichloro-2-butene 2.0 U 2.0 1.3 ug/L 04/04/24 14:19 1 Trichloroethene 1.0 U 1.0 0.20 ug/L 04/04/24 14:19 1 Trichlorofluoromethane 1.0 U 1.0 0.33 ug/L 04/04/24 14:19 1 Vinyl acetate 5.0 U 5.0 0.69 ug/L 04/04/24 14:19 1 Vinyl chloride 1.0 U 1.0 0.40 ug/L 04/04/24 14:19 1 Xylenes (total) 3.0 U 3.0 0.23 ug/L 04/04/24 14:19 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed DU Fac 1,2-Dichloroethane-d4 (Surr) 78 60- 124 04104124 14:19 1 4-Bromofluorobenzene (Surr) 100 70 - 130 04104124 14:19 1 Dibromofluoromethane (Surr) 89 70 - 130 04104124 14:19 1 Toluene-d8 (Surr) 106 70 - 130 04104124 14:19 1 Eurofins Savannah Page 16 of 49 4/8/2024 Client Sample Results Client: Babb & Associates Project/Site: Seaboard- Quarterly Surface Waters Job ID: 680-248614-1 Client Sample ID: SW-3 Lab Sample ID: 680-248614-5 Date Collected: 03/26/24 08:30 Matrix: Surface Water Date Received: 03/27/24 10:17 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane 6.5 0.50 0.32 ug/L 04/08/24 05:56 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 85 46 - 154 04108124 05:56 1 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane 1.0 U 1.0 0.36 ug/L 04/04/24 14:42 1 1,1,1-Trichloroethane 1.0 U 1.0 0.21 ug/L 04/04/24 14:42 1 1,1,2,2-Tetrachloroethane 1.0 U 1.0 0.40 ug/L 04/04/24 14:42 1 1,1,2-Trichloroethane 1.0 U 1.0 0.32 ug/L 04/04/24 14:42 1 1,1-Dichloroethane 1.0 U 1.0 0.33 ug/L 04/04/24 14:42 1 1,1-Dichloroethene 1.0 U 1.0 0.33 ug/L 04/04/24 14:42 1 1,2,3-Trichloropropane 1.0 U 1.0 0.48 ug/L 04/04/24 14:42 1 1,2-Dibromo-3-Chloropropane 5.0 U 5.0 1.8 ug/L 04/04/24 14:42 1 1,2-Dibromoethane 1.0 U 1.0 0.33 ug/L 04/04/24 14:42 1 1,2-Dichlorobenzene 1.0 U 1.0 0.31 ug/L 04/04/24 14:42 1 1,2-Dichloroethane 1.0 U 1.0 0.25 ug/L 04/04/24 14:42 1 1,2-Dichloropropane 1.0 U 1.0 0.22 ug/L 04/04/24 14:42 1 1,4-Dichlorobenzene 1.0 U 1.0 0.31 ug/L 04/04/24 14:42 1 2-Butanone 10 U 10 6.4 ug/L 04/04/24 14:42 1 2-Hexanone 10 U 10 3.2 ug/L 04/04/24 14:42 1 4-Methyl-2-pentanone 10 U 10 2.7 ug/L 04/04/24 14:42 1 Acetone 20 U 20 3.7 ug/L 04/04/24 14:42 1 Acrylonitrile 20 U 20 5.5 ug/L 04/04/24 14:42 1 Benzene 1.0 U 1.0 0.27 ug/L 04/04/24 14:42 1 Bromochloromethane 1.0 U 1.0 0.34 ug/L 04/04/24 14:42 1 Bromodichloromethane 1.0 U 1.0 0.25 ug/L 04/04/24 14:42 1 Bromoform 1.0 U 1.0 0.59 ug/L 04/04/24 14:42 1 Bromomethane 5.0 U 5.0 3.7 ug/L 04/04/24 14:42 1 Carbon disulfide 5.0 U 5.0 0.43 ug/L 04/04/24 14:42 1 Carbon tetrachloride 1.0 U 1.0 0.30 ug/L 04/04/24 14:42 1 Chlorobenzene 1.0 U 1.0 0.15 ug/L 04/04/24 14:42 1 Chloroethane 5.0 U 5.0 4.6 ug/L 04/04/24 14:42 1 Chloroform 1.0 U 1.0 0.27 ug/L 04/04/24 14:42 1 Chloromethane 1.0 U 1.0 0.54 ug/L 04/04/24 14:42 1 cis-1,2-Dichloroethene 1.0 U 1.0 0.25 ug/L 04/04/24 14:42 1 cis-1,3-Dichloropropene 1.0 U 1.0 0.26 ug/L 04/04/24 14:42 1 Dibromochloromethane 1.0 U 1.0 0.39 ug/L 04/04/24 14:42 1 Dibromomethane 1.0 U 1.0 0.34 ug/L 04/04/24 14:42 1 Ethylbenzene 1.0 U 1.0 0.20 ug/L 04/04/24 14:42 1 lodomethane 10 U 10 3.9 ug/L 04/04/24 14:42 1 m,p-Xylenes 2.0 U 2.0 0.49 ug/L 04/04/24 14:42 1 Methylene Chloride 5.0 U 5.0 3.2 ug/L 04/04/24 14:42 1 o-Xylene 1.0 U 1.0 0.26 ug/L 04/04/24 14:42 1 Styrene 1.0 U 1.0 0.27 ug/L 04/04/24 14:42 1 Tetrachloroethene 1.0 U 1.0 0.35 ug/L 04/04/24 14:42 1 Toluene 1.0 U 1.0 0.25 ug/L 04/04/24 14:42 1 trans- 1,2-Dichloroethene 1.0 U 1.0 0.34 ug/L 04/04/24 14:42 1 trans- 1,3-Dichloropropene 1.0 U 1.0 0.23 ug/L 04/04/24 14:42 1 Eurofins Savannah Page 17 of 49 4/8/2024 Client Sample Results Client: Babb & Associates Job ID: 680-248614-1 Project/Site: Seaboard- Quarterly Surface Waters Client Sample ID: SW-3 Lab Sample ID: 680-248614-5 Date Collected: 03/26/24 08:30 Matrix: Surface Water Date Received: 03/27/24 10:17 Method: SW846 8260D - Volatile Organic Compounds by GUMS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac trans- 1,4-Dichloro-2-butene 2.0 U 2.0 1.3 ug/L 04/04/24 14:42 1 Trichloroethene 1.0 U 1.0 0.20 ug/L 04/04/24 14:42 1 Trichlorofluoromethane 1.0 U 1.0 0.33 ug/L 04/04/24 14:42 1 Vinyl acetate 5.0 U 5.0 0.69 ug/L 04/04/24 14:42 1 Vinyl chloride 1.0 U 1.0 0.40 ug/L 04/04/24 14:42 1 Xylenes (total) 3.0 U 3.0 0.23 ug/L 04/04/24 14:42 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 76 60- 124 04104124 14:42 1 4-Bromofluorobenzene (Surr) 103 70 - 130 04104124 14:42 1 Dibromofluoromethane (Surr) 87 70 - 130 04104124 14:42 1 Toluene-d8 (Surr) 103 70 - 130 04104124 14:42 1 Eurofins Savannah Page 18 of 49 4/8/2024 Client Sample Results Client: Babb & Associates Project/Site: Seaboard- Quarterly Surface Waters Job ID: 680-248614-1 Client Sample ID: SW-4 Lab Sample ID: 680-248614-6 Date Collected: 03/26/24 09:15 Matrix: Surface Water Date Received: 03/27/24 10:17 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane 30 25 16 ug/L 04/06/24 21:31 50 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 91 46 - 154 04106124 21:31 50 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane 1.0 U 1.0 0.36 ug/L 04/04/24 15:04 1 1,1,1-Trichloroethane 1.0 U 1.0 0.21 ug/L 04/04/24 15:04 1 1,1,2,2-Tetrachloroethane 1.0 U 1.0 0.40 ug/L 04/04/24 15:04 1 1,1,2-Trichloroethane 1.0 U 1.0 0.32 ug/L 04/04/24 15:04 1 1,1-Dichloroethane 4.4 1.0 0.33 ug/L 04/04/24 15:04 1 1,1-Dichloroethene 0.83 J 1.0 0.33 ug/L 04/04/24 15:04 1 1,2,3-Trichloropropane 1.0 U 1.0 0.48 ug/L 04/04/24 15:04 1 1,2-Dibromo-3-Chloropropane 5.0 U 5.0 1.8 ug/L 04/04/24 15:04 1 1,2-Dibromoethane 1.0 U 1.0 0.33 ug/L 04/04/24 15:04 1 1,2-Dichlorobenzene 1.0 U 1.0 0.31 ug/L 04/04/24 15:04 1 1,2-Dichloroethane 0.43 J 1.0 0.25 ug/L 04/04/24 15:04 1 1,2-Dichloropropane 1.0 U 1.0 0.22 ug/L 04/04/24 15:04 1 1,4-Dichlorobenzene 1.0 U 1.0 0.31 ug/L 04/04/24 15:04 1 2-Butanone 10 U 10 6.4 ug/L 04/04/24 15:04 1 2-Hexanone 10 U 10 3.2 ug/L 04/04/24 15:04 1 4-Methyl-2-pentanone 10 U 10 2.7 ug/L 04/04/24 15:04 1 Acetone 20 U 20 3.7 ug/L 04/04/24 15:04 1 Acrylonitrile 20 U 20 5.5 ug/L 04/04/24 15:04 1 Benzene 1.0 U 1.0 0.27 ug/L 04/04/24 15:04 1 Bromochloromethane 1.0 U 1.0 0.34 ug/L 04/04/24 15:04 1 Bromodichloromethane 1.0 U 1.0 0.25 ug/L 04/04/24 15:04 1 Bromoform 1.0 U 1.0 0.59 ug/L 04/04/24 15:04 1 Bromomethane 5.0 U 5.0 3.7 ug/L 04/04/24 15:04 1 Carbon disulfide 5.0 U 5.0 0.43 ug/L 04/04/24 15:04 1 Carbon tetrachloride 1.0 U 1.0 0.30 ug/L 04/04/24 15:04 1 Chlorobenzene 3.5 1.0 0.15 ug/L 04/04/24 15:04 1 Chloroethane 6.9 5.0 4.6 ug/L 04/04/24 15:04 1 Chloroform 1.0 U 1.0 0.27 ug/L 04/04/24 15:04 1 Chloromethane 1.0 U 1.0 0.54 ug/L 04/04/24 15:04 1 cis-1,2-Dichloroethene 4.6 1.0 0.25 ug/L 04/04/24 15:04 1 cis-1,3-Dichloropropene 1.0 U 1.0 0.26 ug/L 04/04/24 15:04 1 Dibromochloromethane 1.0 U 1.0 0.39 ug/L 04/04/24 15:04 1 Dibromomethane 1.0 U 1.0 0.34 ug/L 04/04/24 15:04 1 Ethylbenzene 1.0 U 1.0 0.20 ug/L 04/04/24 15:04 1 lodomethane 10 U 10 3.9 ug/L 04/04/24 15:04 1 m,p-Xylenes 2.0 U 2.0 0.49 ug/L 04/04/24 15:04 1 Methylene Chloride 5.0 U 5.0 3.2 ug/L 04/04/24 15:04 1 o-Xylene 1.0 U 1.0 0.26 ug/L 04/04/24 15:04 1 Styrene 1.0 U 1.0 0.27 ug/L 04/04/24 15:04 1 Tetrachloroethene 1.0 U 1.0 0.35 ug/L 04/04/24 15:04 1 Toluene 1.0 U 1.0 0.25 ug/L 04/04/24 15:04 1 trans- 1,2-Dichloroethene 1.0 U 1.0 0.34 ug/L 04/04/24 15:04 1 trans- 1,3-Dichloropropene 1.0 U 1.0 0.23 ug/L 04/04/24 15:04 1 Eurofins Savannah Page 19 of 49 4/8/2024 Client Sample Results Client: Babb & Associates Job ID: 680-248614-1 Project/Site: Seaboard- Quarterly Surface Waters Client Sample ID: SW-4 Lab Sample ID: 680-248614-6 Date Collected: 03/26/24 09:15 Matrix: Surface Water Date Received: 03/27/24 10:17 Method: SW846 8260D - Volatile Organic Compounds by GUMS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac trans- 1,4-Dichloro-2-butene 2.0 U 2.0 1.3 ug/L 04/04/24 15:04 1 Trichloroethene 1.0 U 1.0 0.20 ug/L 04/04/24 15:04 1 Trichlorofluoromethane 1.0 U 1.0 0.33 ug/L 04/04/24 15:04 1 Vinyl acetate 5.0 U 5.0 0.69 ug/L 04/04/24 15:04 1 Vinyl chloride 2.0 1.0 0.40 ug/L 04/04/24 15:04 1 Xylenes (total) 3.0 U 3.0 0.23 ug/L 04/04/24 15:04 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed DU Fac 1,2-Dichloroethane-d4 (Surr) 76 60- 124 04104124 15:04 1 4-Bromofluorobenzene (Surr) 101 70 - 130 04104124 15:04 1 Dibromofluoromethane (Surr) 86 70 - 130 04104124 15:04 1 Toluene-d8 (Surr) 109 70 - 130 04104124 15:04 1 Eurofins Savannah Page 20 of 49 4/8/2024 Client Sample Results Client: Babb & Associates Project/Site: Seaboard- Quarterly Surface Waters Job ID: 680-248614-1 Client Sample ID: SW-5 Lab Sample ID: 680-248614-7 Date Collected: 03/26/24 08:20 Matrix: Surface Water Date Received: 03/27/24 10:17 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane 11 0.50 0.32 ug/L 04/08/24 06:21 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 81 46 - 154 04108124 06:21 1 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane 1.0 U 1.0 0.36 ug/L 04/04/24 15:26 1 1,1,1-Trichloroethane 1.0 U 1.0 0.21 ug/L 04/04/24 15:26 1 1,1,2,2-Tetrachloroethane 1.0 U 1.0 0.40 ug/L 04/04/24 15:26 1 1,1,2-Trichloroethane 1.0 U 1.0 0.32 ug/L 04/04/24 15:26 1 1,1-Dichloroethane 1.0 U 1.0 0.33 ug/L 04/04/24 15:26 1 1,1-Dichloroethene 1.0 U 1.0 0.33 ug/L 04/04/24 15:26 1 1,2,3-Trichloropropane 1.0 U 1.0 0.48 ug/L 04/04/24 15:26 1 1,2-Dibromo-3-Chloropropane 5.0 U 5.0 1.8 ug/L 04/04/24 15:26 1 1,2-Dibromoethane 1.0 U 1.0 0.33 ug/L 04/04/24 15:26 1 1,2-Dichlorobenzene 1.0 U 1.0 0.31 ug/L 04/04/24 15:26 1 1,2-Dichloroethane 1.0 U 1.0 0.25 ug/L 04/04/24 15:26 1 1,2-Dichloropropane 1.0 U 1.0 0.22 ug/L 04/04/24 15:26 1 1,4-Dichlorobenzene 1.0 U 1.0 0.31 ug/L 04/04/24 15:26 1 2-Butanone 10 U 10 6.4 ug/L 04/04/24 15:26 1 2-Hexanone 10 U 10 3.2 ug/L 04/04/24 15:26 1 4-Methyl-2-pentanone 10 U 10 2.7 ug/L 04/04/24 15:26 1 Acetone 20 U 20 3.7 ug/L 04/04/24 15:26 1 Acrylonitrile 20 U 20 5.5 ug/L 04/04/24 15:26 1 Benzene 1.0 U 1.0 0.27 ug/L 04/04/24 15:26 1 Bromochloromethane 1.0 U 1.0 0.34 ug/L 04/04/24 15:26 1 Bromodichloromethane 1.0 U 1.0 0.25 ug/L 04/04/24 15:26 1 Bromoform 1.0 U 1.0 0.59 ug/L 04/04/24 15:26 1 Bromomethane 5.0 U 5.0 3.7 ug/L 04/04/24 15:26 1 Carbon disulfide 5.0 U 5.0 0.43 ug/L 04/04/24 15:26 1 Carbon tetrachloride 1.0 U 1.0 0.30 ug/L 04/04/24 15:26 1 Chlorobenzene 1.0 U 1.0 0.15 ug/L 04/04/24 15:26 1 Chloroethane 5.0 U 5.0 4.6 ug/L 04/04/24 15:26 1 Chloroform 1.0 U 1.0 0.27 ug/L 04/04/24 15:26 1 Chloromethane 1.0 U 1.0 0.54 ug/L 04/04/24 15:26 1 cis-1,2-Dichloroethene 1.0 U 1.0 0.25 ug/L 04/04/24 15:26 1 cis-1,3-Dichloropropene 1.0 U 1.0 0.26 ug/L 04/04/24 15:26 1 Dibromochloromethane 1.0 U 1.0 0.39 ug/L 04/04/24 15:26 1 Dibromomethane 1.0 U 1.0 0.34 ug/L 04/04/24 15:26 1 Ethylbenzene 1.0 U 1.0 0.20 ug/L 04/04/24 15:26 1 lodomethane 10 U 10 3.9 ug/L 04/04/24 15:26 1 m,p-Xylenes 2.0 U 2.0 0.49 ug/L 04/04/24 15:26 1 Methylene Chloride 5.0 U 5.0 3.2 ug/L 04/04/24 15:26 1 o-Xylene 1.0 U 1.0 0.26 ug/L 04/04/24 15:26 1 Styrene 1.0 U 1.0 0.27 ug/L 04/04/24 15:26 1 Tetrachloroethene 1.0 U 1.0 0.35 ug/L 04/04/24 15:26 1 Toluene 1.0 U 1.0 0.25 ug/L 04/04/24 15:26 1 trans- 1,2-Dichloroethene 1.0 U 1.0 0.34 ug/L 04/04/24 15:26 1 trans- 1,3-Dichloropropene 1.0 U 1.0 0.23 ug/L 04/04/24 15:26 1 Eurofins Savannah Page 21 of 49 4/8/2024 Client Sample Results Client: Babb & Associates Job ID: 680-248614-1 Project/Site: Seaboard- Quarterly Surface Waters Client Sample ID: SW-5 Lab Sample ID: 680-248614-7 Date Collected: 03/26/24 08:20 Matrix: Surface Water Date Received: 03/27/24 10:17 Method: SW846 8260D - Volatile Organic Compounds by GUMS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac trans- 1,4-Dichloro-2-butene 2.0 U 2.0 1.3 ug/L 04/04/24 15:26 1 Trichloroethene 1.0 U 1.0 0.20 ug/L 04/04/24 15:26 1 Trichlorofluoromethane 1.0 U 1.0 0.33 ug/L 04/04/24 15:26 1 Vinyl acetate 5.0 U 5.0 0.69 ug/L 04/04/24 15:26 1 Vinyl chloride 1.0 U 1.0 0.40 ug/L 04/04/24 15:26 1 Xylenes (total) 3.0 U 3.0 0.23 ug/L 04/04/24 15:26 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed DU Fac 1,2-Dichloroethane-d4 (Surr) 77 60- 124 04104124 15:26 1 4-Bromofluorobenzene (Surr) 100 70 - 130 04104124 15:26 1 Dibromofluoromethane (Surr) 89 70 - 130 04104124 15:26 1 Toluene-d8 (Surr) 103 70 - 130 04104124 15:26 1 Eurofins Savannah Page 22 of 49 4/8/2024 Client Sample Results Client: Babb & Associates Project/Site: Seaboard- Quarterly Surface Waters Job ID: 680-248614-1 Client Sample ID: Trip Blank Lab Sample ID: 680-248614-8 Date Collected: 03/26/24 00:00 Matrix: Water Date Received: 03/27/24 10:17 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL 1,1,1,2-Tetrachloroethane 1.0 U 1.0 1,1,1-Trichloroethane 1.0 U 1.0 1,1,2,2-Tetrachloroethane 1.0 U 1.0 1,1,2-Trichloroethane 1.0 U 1.0 1,1-Dichloroethane 1.0 U 1.0 1,1-Dichloroethene 1.0 U 1.0 1,2,3-Trichloropropane 1.0 U 1.0 1,2-Dibromo-3-Chloropropane 5.0 U 5.0 1,2-Dibromoethane 1.0 U 1.0 1,2-Dichlorobenzene 1.0 U 1.0 1,2-Dichloroethane 1.0 U 1.0 1,2-Dichloropropane 1.0 U 1.0 1,4-Dichlorobenzene 1.0 U 1.0 2-Butanone 10 U 10 2-Hexanone 10 U J2 10 4-Methyl-2-pentanone 10 U J2 10 Acetone 20 U 20 Acrylonitrile 20 U 20 Benzene 1.0 U 1.0 Bromochloromethane 1.0 U 1.0 Bromodichloromethane 1.0 U 1.0 Bromoform 1.0 U 1.0 Bromomethane 5.0 U 5.0 Carbon disulfide 5.0 U 5.0 Carbon tetrachloride 1.0 U 1.0 Chlorobenzene 1.0 U 1.0 Chloroethane 5.0 U 5.0 Chloroform 1.0 U 1.0 Chloromethane 1.0 U 1.0 cis-1,2-Dichloroethene 1.0 U 1.0 cis-1,3-Dichloropropene 1.0 U 1.0 Dibromochloromethane 1.0 U 1.0 Dibromomethane 1.0 U 1.0 Ethylbenzene 1.0 U 1.0 lodomethane 10 U 10 m,p-Xylenes 2.0 U 2.0 Methylene Chloride 5.0 U 5.0 o-Xylene 1.0 U 1.0 Styrene 1.0 U 1.0 Tetrachloroethene 1.0 U 1.0 Toluene 1.0 U 1.0 trans- 1,2-Dichloroethene 1.0 U 1.0 trans- 1,3-Dichloropropene 1.0 U 1.0 trans- 1,4-Dichloro-2-butene 2.0 U 2.0 Trichloroethene 1.0 U 1.0 Trichlorofluoromethane 1.0 U 1.0 Vinyl acetate 5.0 U J2 5.0 Vinyl chloride 1.0 U 1.0 Xylenes (total) 3.0 U 3.0 MDL Unit D Prepared Analyzed Dil Fac 0.36 ug/L 04/03/2416:26 1 0.21 ug/L 04/03/2416:26 1 0.40 ug/L 04/03/2416:26 1 0.32 ug/L 04/03/2416:26 1 0.33 ug/L 04/03/2416:26 1 0.33 ug/L 04/03/2416:26 1 0.48 ug/L 04/03/2416:26 1 1.8 ug/L 04/03/2416:26 1 0.33 ug/L 04/03/2416:26 1 0.31 ug/L 04/03/2416:26 1 0.25 ug/L 04/03/2416:26 1 0.22 ug/L 04/03/2416:26 1 0.31 ug/L 04/03/2416:26 1 6.4 ug/L 04/03/2416:26 1 3.2 ug/L 04/03/2416:26 1 2.7 ug/L 04/03/2416:26 1 3.7 ug/L 04/03/2416:26 1 5.5 ug/L 04/03/2416:26 1 0.27 ug/L 04/03/2416:26 1 0.34 ug/L 04/03/2416:26 1 0.25 ug/L 04/03/2416:26 1 0.59 ug/L 04/03/2416:26 1 3.7 ug/L 04/03/2416:26 1 0.43 ug/L 04/03/2416:26 1 0.30 ug/L 04/03/2416:26 1 0.15 ug/L 04/03/2416:26 1 4.6 ug/L 04/03/2416:26 1 0.27 ug/L 04/03/2416:26 1 0.54 ug/L 04/03/2416:26 1 0.25 ug/L 04/03/2416:26 1 0.26 ug/L 04/03/2416:26 1 0.39 ug/L 04/03/2416:26 1 0.34 ug/L 04/03/2416:26 1 0.20 ug/L 04/03/2416:26 1 3.9 ug/L 04/03/2416:26 1 0.49 ug/L 04/03/2416:26 1 3.2 ug/L 04/03/2416:26 1 0.26 ug/L 04/03/2416:26 1 0.27 ug/L 04/03/2416:26 1 0.35 ug/L 04/03/2416:26 1 0.25 ug/L 04/03/2416:26 1 0.34 ug/L 04/03/2416:26 1 0.23 ug/L 04/03/2416:26 1 1.3 ug/L 04/03/2416:26 1 0.20 ug/L 04/03/2416:26 1 0.33 ug/L 04/03/2416:26 1 0.69 ug/L 04/03/2416:26 1 0.40 ug/L 04/03/2416:26 1 0.23 ug/L 04/03/2416:26 1 Eurofins Savannah Page 23 of 49 4/8/2024 Client Sample Results Client: Babb & Associates Job ID: 680-248614-1 Project/Site: Seaboard- Quarterly Surface Waters Client Sample ID: Trip Blank Lab Sample ID: 680-248614-8 Date Collected: 03/26/24 00:00 Matrix: Water Date Received: 03/27/24 10:17 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 75 60- 124 04103124 16:26 1 4-Bromofluorobenzene (Surr) 105 70 - 130 04103124 16:26 1 Dibromofluoromethane (Surr) 84 70 - 130 04103124 16:26 1 Toluene-d8 (Surr) 94 70 - 130 04103124 16:26 1 Eurofins Savannah Page 24 of 49 4/8/2024 Client Sample Results Client: Babb & Associates Job ID: 680-248614-1 Project/Site: Seaboard- Quarterly Surface Waters Client Sample ID: Trip Blank Lab Sample ID: 680-248614-9 Date Collected: 03/26/24 00:00 Matrix: Water Date Received: 03/27/24 10:17 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane 0.50 U 0.50 0.32 ug/L 04/06/2418:16 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed DU Fac 4-Bromofluorobenzene (Surr) 104 46 - 154 04106124 18:16 1 F F Eurofins Savannah Page 25 of 49 4/8/2024 QC Sample Results Client: Babb & Associates Job ID: 680-248614-1 Project/Site: Seaboard- Quarterly Surface Waters Method: 8260D - Volatile Organic Compounds by GUMS Lab Sample ID: MB 680-831101/8 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 831101 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane 1.0 U 1.0 0.36 ug/L 04/03/24 14:28 1 1,1,1-Trichloroethane 1.0 U 1.0 0.21 ug/L 04/03/24 14:28 1 1,1,2,2-Tetrachloroethane 1.0 U 1.0 0.40 ug/L 04/03/24 14:28 1 1,1,2-Trichloroethane 1.0 U 1.0 0.32 ug/L 04/03/24 14:28 1 1,1-Dichloroethane 1.0 U 1.0 0.33 ug/L 04/03/24 14:28 1 1,1-Dichloroethene 1.0 U 1.0 0.33 ug/L 04/03/24 14:28 1 1,2,3-Trichloropropane 1.0 U 1.0 0.48 ug/L 04/03/24 14:28 1 1,2-Dibromo-3-Chloropropane 5.0 U 5.0 1.8 ug/L 04/03/24 14:28 1 1,2-Dibromoethane 1.0 U 1.0 0.33 ug/L 04/03/24 14:28 1 1,2-Dichlorobenzene 1.0 U 1.0 0.31 ug/L 04/03/24 14:28 1 1,2-Dichloroethane 1.0 U 1.0 0.25 ug/L 04/03/24 14:28 1 1,2-Dichloropropane 1.0 U 1.0 0.22 ug/L 04/03/24 14:28 1 1,4-Dichlorobenzene 1.0 U 1.0 0.31 ug/L 04/03/24 14:28 1 2-Butanone 10 U 10 6.4 ug/L 04/03/24 14:28 1 2-Hexanone 10 U 10 3.2 ug/L 04/03/24 14:28 1 4-Methyl-2-pentanone 10 U 10 2.7 ug/L 04/03/24 14:28 1 Acetone 20 U 20 3.7 ug/L 04/03/24 14:28 1 Acrylonitrile 20 U 20 5.5 ug/L 04/03/24 14:28 1 Benzene 1.0 U 1.0 0.27 ug/L 04/03/24 14:28 1 Bromochloromethane 1.0 U 1.0 0.34 ug/L 04/03/24 14:28 1 Bromodichloromethane 1.0 U 1.0 0.25 ug/L 04/03/24 14:28 1 Bromoform 1.0 U 1.0 0.59 ug/L 04/03/24 14:28 1 Bromomethane 5.0 U 5.0 3.7 ug/L 04/03/24 14:28 1 Carbon disulfide 5.0 U 5.0 0.43 ug/L 04/03/24 14:28 1 Carbon tetrachloride 1.0 U 1.0 0.30 ug/L 04/03/24 14:28 1 Chlorobenzene 1.0 U 1.0 0.15 ug/L 04/03/24 14:28 1 Chloroethane 5.0 U 5.0 4.6 ug/L 04/03/24 14:28 1 Chloroform 1.0 U 1.0 0.27 ug/L 04/03/24 14:28 1 Chloromethane 1.0 U 1.0 0.54 ug/L 04/03/24 14:28 1 cis-1,2-Dichloroethene 1.0 U 1.0 0.25 ug/L 04/03/24 14:28 1 cis-1,3-Dichloropropene 1.0 U 1.0 0.26 ug/L 04/03/24 14:28 1 Dibromochloromethane 1.0 U 1.0 0.39 ug/L 04/03/24 14:28 1 Dibromomethane 1.0 U 1.0 0.34 ug/L 04/03/24 14:28 1 Ethylbenzene 1.0 U 1.0 0.20 ug/L 04/03/24 14:28 1 lodomethane 10 U 10 3.9 ug/L 04/03/24 14:28 1 m,p-Xylenes 2.0 U 2.0 0.49 ug/L 04/03/24 14:28 1 Methylene Chloride 5.0 U 5.0 3.2 ug/L 04/03/24 14:28 1 o-Xylene 1.0 U 1.0 0.26 ug/L 04/03/24 14:28 1 Styrene 1.0 U 1.0 0.27 ug/L 04/03/24 14:28 1 Tetrachloroethene 1.0 U 1.0 0.35 ug/L 04/03/24 14:28 1 Toluene 1.0 U 1.0 0.25 ug/L 04/03/24 14:28 1 trans- 1,2-Dichloroethene 1.0 U 1.0 0.34 ug/L 04/03/24 14:28 1 trans- 1,3-Dichloropropene 1.0 U 1.0 0.23 ug/L 04/03/24 14:28 1 trans- 1,4-Dichloro-2-butene 2.0 U 2.0 1.3 ug/L 04/03/24 14:28 1 Trichloroethene 1.0 U 1.0 0.20 ug/L 04/03/24 14:28 1 Trichlorofluoromethane 1.0 U 1.0 0.33 ug/L 04/03/24 14:28 1 Vinyl acetate 5.0 U 5.0 0.69 ug/L 04/03/24 14:28 1 Vinyl chloride 1.0 U 1.0 0.40 ug/L 04/03/24 14:28 1 0 Eurofins Savannah Page 26 of 49 4/8/2024 QC Sample Results Client: Babb & Associates Job ID: 680-248614-1 Project/Site: Seaboard- Quarterly Surface Waters Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: MB 680-831101/8 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 831101 Analyte Xylenes (total) MB MB Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 3.0 U 3.0 0.23 ug/L 04/03/2414:28 1 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 74 60- 124 04103124 14:28 1 4-Bromofluorobenzene (Surr) 107 70 - 130 04103124 14:28 1 Dibromofluoromethane (Surr) 83 70 - 130 04103124 14:28 1 Toluene-d8 (Surr) 94 70 - 130 04103124 14:28 1 Lab Sample ID: LCS 680-831101/4 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 831101 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 1,1,1,2-Tetrachloroethane 50.0 44.9 ug/L 90 70-130 1,1,1-Trichloroethane 50.0 57.9 ug/L 116 70-130 1,1,2,2-Tetrachloroethane 50.0 54.6 ug/L 109 70-130 1,1,2-Trichloroethane 50.0 50.5 ug/L 101 70-130 1,1-Dichloroethane 50.0 49.1 ug/L 98 70-130 1,1-Dichloroethene 50.0 48.7 ug/L 97 70-130 1,2,3-Trichloropropane 50.0 51.7 ug/L 103 70-130 1,2-Dibromo-3-Chloropropane 50.0 58.4 ug/L 117 70-130 1,2-Dibromoethane 50.0 52.0 ug/L 104 70-130 1,2-Dichlorobenzene 50.0 53.4 ug/L 107 70 -130 1,2-Dichloroethane 50.0 51.9 ug/L 104 70 -130 1,2-Dichloropropane 50.0 54.4 ug/L 109 70 -130 1,4-Dichlorobenzene 50.0 51.9 ug/L 104 70 -130 2-Butanone 250 257 ug/L 103 69-120 2-Hexanone 250 307 ug/L 123 70-130 4-Methyl-2-pentanone 250 299 ug/L 120 68 -120 Acetone 250 235 ug/L 94 67-120 Acrylonitrile 500 516 ug/L 103 70 -130 Benzene 50.0 52.9 ug/L 106 70-130 Bromochloromethane 50.0 48.5 ug/L 97 70 -130 Bromodichloromethane 50.0 52.9 ug/L 106 70 -130 Bromoform 50.0 49.4 ug/L 99 69 -129 Bromomethane 50.0 48.5 ug/L 97 28 -192 Carbon disulfide 50.0 46.9 ug/L 94 70 -130 Carbon tetrachloride 50.0 57.1 ug/L 114 70 -130 Chlorobenzene 50.0 52.8 ug/L 106 70 -130 Chloroethane 50.0 43.7 ug/L 87 31 - 213 Chloroform 50.0 48.9 ug/L 98 70 -130 Chloromethane 50.0 48.5 ug/L 97 59 -127 cis-1,2-Dichloroethene 50.0 50.6 ug/L 101 70 -130 cis-1,3-Dichloropropene 50.0 52.1 ug/L 104 70 -130 Dibromochloromethane 50.0 49.4 ug/L 99 70 -130 Dibromomethane 50.0 50.0 ug/L 100 70 -130 Ethylbenzene 50.0 52.0 ug/L 104 70 -130 lodomethane 50.0 47.3 ug/L 95 52 -129 Eurofins Savannah Page 27 of 49 4/8/2024 QC Sample Results Client: Babb & Associates Job ID: 680-248614-1 Project/Site: Seaboard- Quarterly Surface Waters Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: LCS 680-831101/4 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 831101 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits m,p-Xylenes 50.0 51.2 ug/L 102 70 -130 Methylene Chloride 50.0 44.7 ug/L 89 70 -130 o-Xylene 50.0 50.5 ug/L 101 70 -130 Styrene 50.0 50.6 ug/L 101 70 -130 Tetrachloroethene 50.0 52.2 ug/L 104 70 -130 Toluene 50.0 49.8 ug/L 100 70 -130 trans- 1,2-Dichloroethene 50.0 51.2 ug/L 102 70-130 trans- 1,3-Dichloropropene 50.0 49.9 ug/L 100 70-130 trans- 1,4-Dichloro-2-butene 50.0 49.8 ug/L 100 67-120 Trichloroethene 50.0 51.6 ug/L 103 70 -130 Trichlorofluoromethane 50.0 49.1 ug/L 98 63 -142 Vinyl acetate 100 160 J2 ug/L 160 67 -135 Vinyl chloride 50.0 45.7 ug/L 91 66 -129 Xylenes (total) 100 102 ug/L 102 70 -130 LCS LCS Surrogate %Recovery Qualifier Limits 1,2-Dichloroethane-d4 (Surr) 98 60- 124 4-Bromofluorobenzene (Surr) 98 70 - 130 Dibromofluoromethane (Surr) 98 70 - 130 Toluene-d8 (Surr) 97 70 - 130 Lab Sample ID: LCSD 680-831101/5 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 831101 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit 1,1,1,2-Tetrachloroethane 50.0 43.8 ug/L 88 70-130 2 30 1,1,1-Trichloroethane 50.0 58.7 ug/L 117 70-130 1 30 1,1,2,2-Tetrachloroethane 50.0 55.1 ug/L 110 70-130 1 30 1,1,2-Trichloroethane 50.0 52.4 ug/L 105 70-130 4 30 1,1-Dichloroethane 50.0 52.2 ug/L 104 70-130 6 30 1,1-Dichloroethene 50.0 50.6 ug/L 101 70-130 4 20 1,2,3-Trichloropropane 50.0 53.4 ug/L 107 70-130 3 30 1,2-Dibromo-3-Chloropropane 50.0 62.3 ug/L 125 70-130 6 30 1,2-Dibromoethane 50.0 54.1 ug/L 108 70-130 4 30 1,2-Dichlorobenzene 50.0 53.9 ug/L 108 70 -130 1 30 1,2-Dichloroethane 50.0 56.0 ug/L 112 70 -130 8 50 1,2-Dichloropropane 50.0 55.2 ug/L 110 70 -130 2 20 1,4-Dichlorobenzene 50.0 52.3 ug/L 105 70 -130 1 30 2-Butanone 250 272 ug/L 109 69 -120 6 30 2-Hexanone 250 332 J2 ug/L 133 70-130 8 20 4-Methyl-2-pentanone 250 317 J2 ug/L 127 68 -120 6 30 Acetone 250 250 ug/L 100 67 -120 6 30 Acrylonitrile 500 560 ug/L 112 70 -130 8 30 Benzene 50.0 52.9 ug/L 106 70 -130 0 30 Bromochloromethane 50.0 51.4 ug/L 103 70 -130 6 30 Bromodichloromethane 50.0 54.5 ug/L 109 70 -130 3 30 Bromoform 50.0 49.7 ug/L 99 69 -129 1 30 Eurofins Savannah Page 28 of 49 4/8/2024 QC Sample Results Client: Babb & Associates Job ID: 680-248614-1 Project/Site: Seaboard- Quarterly Surface Waters Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: LCSD 680-831101/5 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 831101 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit Bromomethane 50.0 51.2 ug/L 102 28 -192 5 30 Carbon disulfide 50.0 47.6 ug/L 95 70 -130 2 30 Carbon tetrachloride 50.0 56.7 ug/L 113 70 -130 1 30 Chlorobenzene 50.0 53.4 ug/L 107 70 -130 1 30 Chloroethane 50.0 44.2 ug/L 88 31 - 213 1 30 Chloroform 50.0 51.6 ug/L 103 70 -130 5 30 Chloromethane 50.0 50.5 ug/L 101 59 -127 4 30 cis-1,2-Dichloroethene 50.0 53.3 ug/L 107 70 -130 5 30 cis-1,3-Dichloropropene 50.0 53.0 ug/L 106 70 -130 2 20 Dibromochloromethane 50.0 50.2 ug/L 100 70 -130 2 30 Dibromomethane 50.0 54.7 ug/L 109 70 -130 9 30 Ethylbenzene 50.0 51.9 ug/L 104 70 -130 0 20 lodomethane 50.0 47.8 ug/L 96 52 -129 1 30 m,p-Xylenes 50.0 50.3 ug/L 101 70 -130 2 30 Methylene Chloride 50.0 46.5 ug/L 93 70 -130 4 30 o-Xylene 50.0 49.6 ug/L 99 70 -130 2 30 Styrene 50.0 50.0 ug/L 100 70 -130 1 30 Tetrachloroethene 50.0 53.0 ug/L 106 70 -130 1 30 Toluene 50.0 51.5 ug/L 103 70 -130 4 30 trans- 1,2-Dichloroethene 50.0 52.9 ug/L 106 70-130 3 30 trans- 1,3-Dichloropropene 50.0 51.1 ug/L 102 70-130 2 30 trans- 1,4-Dichloro-2-butene 50.0 51.6 ug/L 103 67-120 3 30 Trichloroethene 50.0 50.8 ug/L 102 70 -130 2 30 Trichlorofluoromethane 50.0 51.2 ug/L 102 63 -142 4 30 Vinyl acetate 100 164 J2 ug/L 164 67 -135 2 30 Vinyl chloride 50.0 46.3 ug/L 93 66 -129 1 30 Xylenes (total) 100 99.9 ug/L 100 70 -130 2 30 LCSD LCSD Surrogate %Recovery Qualifier Limits 1, 2-Dichloroethane-d4 (Surr) 105 60 -124 4-Bromofluorobenzene (Surr) 99 70 -130 Dibromofluoromethane (Surr) 106 70 -130 Toluene-d8 (Surr) 99 70 - 130 Lab Sample ID: MB 680-831273/8 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 831273 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane 1.0 U 1.0 0.36 ug/L 04/04/2411:50 1 1,1,1-Trichloroethane 1.0 U 1.0 0.21 ug/L 04/04/2411:50 1 1,1,2,2-Tetrachloroethane 1.0 U 1.0 0.40 ug/L 04/04/2411:50 1 1,1,2-Trichloroethane 1.0 U 1.0 0.32 ug/L 04/04/2411:50 1 1,1-Dichloroethane 1.0 U 1.0 0.33 ug/L 04/04/2411:50 1 1,1-Dichloroethene 1.0 U 1.0 0.33 ug/L 04/04/2411:50 1 1,2,3-Trichloropropane 1.0 U 1.0 0.48 ug/L 04/04/2411:50 1 1,2-Dibromo-3-Chloropropane 5.0 U 5.0 1.8 ug/L 04/04/2411:50 1 1,2-Dibromoethane 1.0 U 1.0 0.33 ug/L 04/04/2411:50 1 Eurofins Savannah Page 29 of 49 4/8/2024 QC Sample Results Client: Babb & Associates Job ID: 680-248614-1 Project/Site: Seaboard- Quarterly Surface Waters Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: MB 680-831273/8 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 831273 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,2-Dichlorobenzene 1.0 U 1.0 0.31 ug/L 04/04/24 11:50 1 1,2-Dichloroethane 1.0 U 1.0 0.25 ug/L 04/04/24 11:50 1 1,2-Dichloropropane 1.0 U 1.0 0.22 ug/L 04/04/24 11:50 1 1,4-Dichlorobenzene 1.0 U 1.0 0.31 ug/L 04/04/24 11:50 1 2-Butanone 10 U 10 6.4 ug/L 04/04/24 11:50 1 2-Hexanone 10 U 10 3.2 ug/L 04/04/24 11:50 1 4-Methyl-2-pentanone 10 U 10 2.7 ug/L 04/04/24 11:50 1 Acetone 20 U 20 3.7 ug/L 04/04/24 11:50 1 Acrylonitrile 20 U 20 5.5 ug/L 04/04/24 11:50 1 Benzene 1.0 U 1.0 0.27 ug/L 04/04/24 11:50 1 Bromochloromethane 1.0 U 1.0 0.34 ug/L 04/04/24 11:50 1 Bromodichloromethane 1.0 U 1.0 0.25 ug/L 04/04/24 11:50 1 Bromoform 1.0 U 1.0 0.59 ug/L 04/04/24 11:50 1 Bromomethane 5.0 U 5.0 3.7 ug/L 04/04/24 11:50 1 Carbon disulfide 5.0 U 5.0 0.43 ug/L 04/04/24 11:50 1 Carbon tetrachloride 1.0 U 1.0 0.30 ug/L 04/04/24 11:50 1 Chlorobenzene 1.0 U 1.0 0.15 ug/L 04/04/24 11:50 1 Chloroethane 5.0 U 5.0 4.6 ug/L 04/04/24 11:50 1 Chloroform 1.0 U 1.0 0.27 ug/L 04/04/24 11:50 1 Chloromethane 1.0 U 1.0 0.54 ug/L 04/04/24 11:50 1 cis-1,2-Dichloroethene 1.0 U 1.0 0.25 ug/L 04/04/24 11:50 1 cis-1,3-Dichloropropene 1.0 U 1.0 0.26 ug/L 04/04/24 11:50 1 Dibromochloromethane 1.0 U 1.0 0.39 ug/L 04/04/24 11:50 1 Dibromomethane 1.0 U 1.0 0.34 ug/L 04/04/24 11:50 1 Ethylbenzene 1.0 U 1.0 0.20 ug/L 04/04/24 11:50 1 lodomethane 10 U 10 3.9 ug/L 04/04/24 11:50 1 m,p-Xylenes 2.0 U 2.0 0.49 ug/L 04/04/24 11:50 1 Methylene Chloride 5.0 U 5.0 3.2 ug/L 04/04/24 11:50 1 o-Xylene 1.0 U 1.0 0.26 ug/L 04/04/24 11:50 1 Styrene 1.0 U 1.0 0.27 ug/L 04/04/24 11:50 1 Tetrachloroethene 1.0 U 1.0 0.35 ug/L 04/04/24 11:50 1 Toluene 1.0 U 1.0 0.25 ug/L 04/04/24 11:50 1 trans- l,2-Dichloroethene 1.0 U 1.0 0.34 ug/L 04/04/24 11:50 1 trans- 1,3-Dichloropropene 1.0 U 1.0 0.23 ug/L 04/04/24 11:50 1 trans- 1,4-Dichloro-2-butene 2.0 U 2.0 1.3 ug/L 04/04/24 11:50 1 Trichloroethene 1.0 U 1.0 0.20 ug/L 04/04/24 11:50 1 Trichlorofluoromethane 1.0 U 1.0 0.33 ug/L 04/04/24 11:50 1 Vinyl acetate 5.0 U 5.0 0.69 ug/L 04/04/24 11:50 1 Vinyl chloride 1.0 U 1.0 0.40 ug/L 04/04/24 11:50 1 Xylenes (total) 3.0 U 3.0 0.23 ug/L 04/04/24 11:50 1 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 75 60- 124 04104124 11:50 1 4-Bromofluorobenzene (Surr) 102 70 - 130 04104124 11:50 1 Dibromofluoromethane (Surr) 84 70 - 130 04104124 11:50 1 Toluene-d8 (Surr) 103 70 - 130 04104124 11:50 1 Eurofins Savannah Page 30 of 49 4/8/2024 QC Sample Results Client: Babb & Associates Job ID: 680-248614-1 Project/Site: Seaboard- Quarterly Surface Waters Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: LCS 680-831273/4 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 831273 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 1,1,1,2-Tetrachloroethane 50.0 45.1 ug/L 90 70-130 1,1,1-Trichloroethane 50.0 54.7 ug/L 109 70-130 1,1,2,2-Tetrachloroethane 50.0 49.8 ug/L 100 70-130 1,1,2-Trichloroethane 50.0 47.7 ug/L 95 70-130 1,1-Dichloroethane 50.0 45.7 ug/L 91 70-130 1,1-Dichloroethene 50.0 44.8 ug/L 90 70-130 1,2,3-Trichloropropane 50.0 47.8 ug/L 96 70-130 1,2-Dibromo-3-Chloropropane 50.0 48.1 ug/L 96 70-130 1,2-Dibromoethane 50.0 48.2 ug/L 96 70-130 1,2-Dichlorobenzene 50.0 53.0 ug/L 106 70 -130 1,2-Dichloroethane 50.0 48.3 ug/L 97 70 -130 1,2-Dichloropropane 50.0 53.2 ug/L 106 70 -130 1,4-Dichlorobenzene 50.0 52.8 ug/L 106 70 -130 2-Butanone 250 207 ug/L 83 69 -120 2-Hexanone 250 259 ug/L 103 70-130 4-Methyl-2-pentanone 250 252 ug/L 101 68 -120 Acetone 250 199 ug/L 79 67 -120 Acrylonitrile 500 430 ug/L 86 70 -130 Benzene 50.0 51.6 ug/L 103 70-130 Bromochloromethane 50.0 44.5 ug/L 89 70 -130 Bromodichloromethane 50.0 49.9 ug/L 100 70 -130 Bromoform 50.0 47.5 ug/L 95 69 -129 Bromomethane 50.0 52.2 ug/L 104 28 -192 Carbon disulfide 50.0 44.4 ug/L 89 70 -130 Carbon tetrachloride 50.0 53.5 ug/L 107 70 -130 Chlorobenzene 50.0 53.6 ug/L 107 70 -130 Chloroethane 50.0 43.5 ug/L 87 31 - 213 Chloroform 50.0 45.9 ug/L 92 70 -130 Chloromethane 50.0 50.6 ug/L 101 59 -127 cis-1,2-Dichloroethene 50.0 47.4 ug/L 95 70 -130 cis-1,3-Dichloropropene 50.0 50.5 ug/L 101 70 -130 Dibromochloromethane 50.0 47.2 ug/L 94 70 -130 Dibromomethane 50.0 45.5 ug/L 91 70 -130 Ethylbenzene 50.0 53.6 ug/L 107 70 -130 lodomethane 50.0 49.8 ug/L 100 52 -129 m,p-Xylenes 50.0 53.9 ug/L 108 70 -130 Methylene Chloride 50.0 45.0 ug/L 90 70 -130 o-Xylene 50.0 53.7 ug/L 107 70 -130 Styrene 50.0 54.0 ug/L 108 70 -130 Tetrachloroethene 50.0 50.6 ug/L 101 70 -130 Toluene 50.0 48.7 ug/L 97 70 -130 trans- 1,2-Dichloroethene 50.0 48.2 ug/L 96 70-130 trans- 1,3-Dichloropropene 50.0 48.0 ug/L 96 70-130 trans- 1,4-Dichloro-2-butene 50.0 46.0 ug/L 92 67-120 Trichloroethene 50.0 51.9 ug/L 104 70 -130 Trichlorofluoromethane 50.0 44.9 ug/L 90 63 -142 Vinyl acetate 100 133 ug/L 133 67 -135 Vinyl chloride 50.0 47.4 ug/L 95 66 -129 0 Eurofins Savannah Page 31 of 49 4/8/2024 QC Sample Results Client: Babb & Associates Project/Site: Seaboard- Quarterly Surface Waters Job ID: 680-248614-1 Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: LCS 680-831273/4 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 831273 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Xylenes (total) 100 108 ug/L 108 70 -130 • LCS LCS Surrogate %Recovery Qualifier Limits 1,2-Dichloroethane-d4 (Surr) 89 60- 124 4-Bromofluorobenzene (Surr) 93 70 - 130 Dibromofluoromethane (Surr) 92 70 - 130 Toluene-d8 (Surr) 93 70 - 130 Lab Sample ID: LCSD 680-831273/5 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 831273 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit 1,1,1,2-Tetrachloroethane 50.0 45.7 ug/L 91 70-130 1 30 1,1,1-Trichloroethane 50.0 54.1 ug/L 108 70-130 1 30 1,1,2,2-Tetrachloroethane 50.0 50.8 ug/L 102 70-130 2 30 1,1,2-Trichloroethane 50.0 48.7 ug/L 97 70-130 2 30 1,1-Dichloroethane 50.0 44.6 ug/L 89 70-130 3 30 1,1-Dichloroethene 50.0 43.3 ug/L 87 70-130 4 20 1,2,3-Trichloropropane 50.0 49.0 ug/L 98 70-130 2 30 1,2-Dibromo-3-Chloropropane 50.0 49.5 ug/L 99 70-130 3 30 1,2-Dibromoethane 50.0 49.7 ug/L 99 70-130 3 30 1,2-Dichlorobenzene 50.0 53.4 ug/L 107 70 -130 1 30 1,2-Dichloroethane 50.0 47.8 ug/L 96 70 -130 1 50 1,2-Dichloropropane 50.0 53.8 ug/L 108 70 -130 1 20 1,4-Dichlorobenzene 50.0 53.1 ug/L 106 70 -130 0 30 2-Butanone 250 217 ug/L 87 69 -120 5 30 2-Hexanone 250 273 ug/L 109 70-130 5 20 4-Methyl-2-pentanone 250 263 ug/L 105 68 -120 5 30 Acetone 250 206 ug/L 83 67 -120 4 30 Acrylonitrile 500 448 ug/L 90 70 -130 4 30 Benzene 50.0 51.4 ug/L 103 70 -130 0 30 Bromochloromethane 50.0 45.3 ug/L 91 70 -130 2 30 Bromodichloromethane 50.0 49.9 ug/L 100 70 -130 0 30 Bromoform 50.0 48.3 ug/L 97 69 -129 2 30 Bromomethane 50.0 51.4 ug/L 103 28 -192 2 30 Carbon disulfide 50.0 44.2 ug/L 88 70 -130 0 30 Carbon tetrachloride 50.0 53.1 ug/L 106 70 -130 1 30 Chlorobenzene 50.0 53.5 ug/L 107 70 -130 0 30 Chloroethane 50.0 43.9 ug/L 88 31 - 213 1 30 Chloroform 50.0 44.4 ug/L 89 70 -130 3 30 Chloromethane 50.0 49.8 ug/L 100 59 -127 2 30 cis-1,2-Dichloroethene 50.0 46.4 ug/L 93 70 -130 2 30 cis-1,3-Dichloropropene 50.0 50.9 ug/L 102 70 -130 1 20 Dibromochloromethane 50.0 47.4 ug/L 95 70 -130 0 30 Dibromomethane 50.0 45.8 ug/L 92 70 -130 1 30 Ethylbenzene 50.0 53.8 ug/L 108 70 -130 1 20 lodomethane 50.0 49.6 ug/L 99 52 -129 0 30 Eurofins Savannah Page 32 of 49 4/8/2024 QC Sample Results Client: Babb & Associates Job ID: 680-248614-1 Project/Site: Seaboard- Quarterly Surface Waters Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: LCSD 680-831273/5 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 831273 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit m,p-Xylenes 50.0 55.0 ug/L 110 70 -130 2 30 • Methylene Chloride 50.0 45.6 ug/L 91 70 -130 1 30 o-Xylene 50.0 54.3 ug/L 109 70 -130 1 30 Styrene 50.0 55.1 ug/L 110 70 -130 2 30 Tetrachloroethene 50.0 50.7 ug/L 101 70 -130 0 30 Toluene 50.0 48.1 ug/L 96 70 -130 1 30 trans- 1,2-Dichloroethene 50.0 46.8 ug/L 94 70-130 3 30 trans- 1,3-Dichloropropene 50.0 48.9 ug/L 98 70-130 2 30 trans- 1,4-Dichloro-2-butene 50.0 47.6 ug/L 95 67-120 3 30 Trichloroethene 50.0 51.8 ug/L 104 70 -130 0 30 Trichlorofluoromethane 50.0 44.1 ug/L 88 63 -142 2 30 Vinyl acetate 100 132 ug/L 132 67 -135 1 30 Vinyl chloride 50.0 46.5 ug/L 93 66 -129 2 30 Xylenes (total) 100 109 ug/L 109 70 -130 2 30 LCSD LCSD Surrogate %Recovery Qualifier Limits 1,2-Dichloroethane-d4 (Surr) 89 60- 124 4-Bromofluorobenzene (Surr) 94 70 - 130 Dibromofluoromethane (Surr) 90 70 - 130 Toluene-d8 (Surr) 92 70 - 130 Lab Sample ID: MB 680-831278/8 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 831278 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane 1.0 U 1.0 0.36 ug/L 04/04/2411:51 1 1,1,1-Trichloroethane 1.0 U 1.0 0.21 ug/L 04/04/2411:51 1 1,1,2,2-Tetrachloroethane 1.0 U 1.0 0.40 ug/L 04/04/2411:51 1 1,1,2-Trichloroethane 1.0 U 1.0 0.32 ug/L 04/04/2411:51 1 1,1-Dichloroethane 1.0 U 1.0 0.33 ug/L 04/04/2411:51 1 1,1-Dichloroethene 1.0 U 1.0 0.33 ug/L 04/04/2411:51 1 1,2,3-Trichloropropane 1.0 U 1.0 0.48 ug/L 04/04/2411:51 1 1,2-Dibromo-3-Chloropropane 5.0 U 5.0 1.8 ug/L 04/04/2411:51 1 1,2-Dibromoethane 1.0 U 1.0 0.33 ug/L 04/04/2411:51 1 1,2-Dichlorobenzene 1.0 U 1.0 0.31 ug/L 04/04/2411:51 1 1,2-Dichloroethane 1.0 U 1.0 0.25 ug/L 04/04/2411:51 1 1,2-Dichloropropane 1.0 U 1.0 0.22 ug/L 04/04/2411:51 1 1,4-Dichlorobenzene 1.0 U 1.0 0.31 ug/L 04/04/2411:51 1 2-Butanone 10 U 10 6.4 ug/L 04/04/2411:51 1 2-Hexanone 10 U 10 3.2 ug/L 04/04/2411:51 1 4-Methyl-2-pentanone 10 U 10 2.7 ug/L 04/04/2411:51 1 Acetone 20 U 20 3.7 ug/L 04/04/2411:51 1 Acrylonitrile 20 U 20 5.5 ug/L 04/04/2411:51 1 Benzene 1.0 U 1.0 0.27 ug/L 04/04/2411:51 1 Bromochloromethane 1.0 U 1.0 0.34 ug/L 04/04/2411:51 1 Bromodichloromethane 1.0 U 1.0 0.25 ug/L 04/04/2411:51 1 Bromoform 1.0 U 1.0 0.59 ug/L 04/04/2411:51 1 Eurofins Savannah Page 33 of 49 4/8/2024 QC Sample Results Client: Babb & Associates Job ID: 680-248614-1 Project/Site: Seaboard- Quarterly Surface Waters Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: MB 680-831278/8 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 831278 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Bromomethane 5.0 U 5.0 3.7 ug/L 04/04/24 11:51 1 Carbon disulfide 5.0 U 5.0 0.43 ug/L 04/04/24 11:51 1 Carbon tetrachloride 1.0 U 1.0 0.30 ug/L 04/04/24 11:51 1 Chlorobenzene 1.0 U 1.0 0.15 ug/L 04/04/24 11:51 1 Chloroethane 5.0 U 5.0 4.6 ug/L 04/04/24 11:51 1 Chloroform 1.0 U 1.0 0.27 ug/L 04/04/24 11:51 1 Chloromethane 1.0 U 1.0 0.54 ug/L 04/04/24 11:51 1 cis-1,2-Dichloroethene 1.0 U 1.0 0.25 ug/L 04/04/24 11:51 1 cis-1,3-Dichloropropene 1.0 U 1.0 0.26 ug/L 04/04/24 11:51 1 Dibromochloromethane 1.0 U 1.0 0.39 ug/L 04/04/24 11:51 1 Dibromomethane 1.0 U 1.0 0.34 ug/L 04/04/24 11:51 1 Ethylbenzene 1.0 U 1.0 0.20 ug/L 04/04/24 11:51 1 lodomethane 10 U 10 3.9 ug/L 04/04/24 11:51 1 m,p-Xylenes 2.0 U 2.0 0.49 ug/L 04/04/24 11:51 1 Methylene Chloride 5.0 U 5.0 3.2 ug/L 04/04/24 11:51 1 o-Xylene 1.0 U 1.0 0.26 ug/L 04/04/24 11:51 1 Styrene 1.0 U 1.0 0.27 ug/L 04/04/24 11:51 1 Tetrachloroethene 1.0 U 1.0 0.35 ug/L 04/04/24 11:51 1 Toluene 1.0 U 1.0 0.25 ug/L 04/04/24 11:51 1 trans- 1,2-Dichloroethene 1.0 U 1.0 0.34 ug/L 04/04/24 11:51 1 trans- 1,3-Dichloropropene 1.0 U 1.0 0.23 ug/L 04/04/24 11:51 1 trans- 1,4-Dichloro-2-butene 2.0 U 2.0 1.3 ug/L 04/04/24 11:51 1 Trichloroethene 1.0 U 1.0 0.20 ug/L 04/04/24 11:51 1 Trichlorofluoromethane 1.0 U 1.0 0.33 ug/L 04/04/24 11:51 1 Vinyl acetate 5.0 U 5.0 0.69 ug/L 04/04/24 11:51 1 Vinyl chloride 1.0 U 1.0 0.40 ug/L 04/04/24 11:51 1 Xylenes (total) 3.0 U 3.0 0.23 ug/L 04/04/24 11:51 1 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 100 60- 124 04104124 11:51 1 4-Bromofluorobenzene (Surr) 125 70 - 130 04104124 11:51 1 Dibromofluoromethane (Surr) 88 70 - 130 04104124 11:51 1 Toluene-d8 (Surr) 92 70 - 130 04104124 11:51 1 Lab Sample ID: LCS 680-831278/4 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 831278 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 1,1,1,2-Tetrachloroethane 50.0 54.4 ug/L 109 70-130 1,1,1-Trichloroethane 50.0 49.3 ug/L 99 70-130 1,1,2,2-Tetrachloroethane 50.0 53.9 ug/L 108 70-130 1,1,2-Trichloroethane 50.0 52.6 ug/L 105 70-130 1,1-Dichloroethane 50.0 49.3 ug/L 99 70-130 1,1-Dichloroethene 50.0 49.2 ug/L 98 70-130 1,2,3-Trichloropropane 50.0 47.8 ug/L 96 70-130 1,2-Dibromo-3-Chloropropane 50.0 50.2 ug/L 100 70-130 1,2-Dibromoethane 50.0 46.9 ug/L 94 70-130 Eurofins Savannah Page 34 of 49 4/8/2024 QC Sample Results Client: Babb & Associates Job ID: 680-248614-1 Project/Site: Seaboard- Quarterly Surface Waters Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: LCS 680-831278/4 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 831278 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 1,2-Dichlorobenzene 50.0 52.6 ug/L 105 70 -130 1,2-Dichloroethane 50.0 52.4 ug/L 105 70 -130 1,2-Dichloropropane 50.0 51.8 ug/L 104 70 -130 1,4-Dichlorobenzene 50.0 52.4 ug/L 105 70 -130 2-Butanone 250 253 ug/L 101 69-120 2-Hexanone 250 212 ug/L 85 70-130 4-Methyl-2-pentanone 250 250 ug/L 100 68 -120 Acetone 250 270 ug/L 108 67-120 Acrylonitrile 500 501 ug/L 100 70 -130 Benzene 50.0 58.2 ug/L 116 70-130 Bromochloromethane 50.0 46.1 ug/L 92 70 -130 Bromodichloromethane 50.0 43.8 ug/L 88 70 -130 Bromoform 50.0 46.0 ug/L 92 69 -129 Bromomethane 50.0 61.7 ug/L 123 28 -192 Carbon disulfide 50.0 56.7 ug/L 113 70 -130 Carbon tetrachloride 50.0 50.8 ug/L 102 70 -130 Chlorobenzene 50.0 49.8 ug/L 100 70 -130 Chloroethane 50.0 76.8 ug/L 154 31 - 213 Chloroform 50.0 50.1 ug/L 100 70 -130 Chloromethane 50.0 52.6 ug/L 105 59 -127 cis-1,2-Dichloroethene 50.0 52.9 ug/L 106 70 -130 cis-1,3-Dichloropropene 50.0 48.2 ug/L 96 70 -130 Dibromochloromethane 50.0 45.5 ug/L 91 70 -130 Dibromomethane 50.0 47.0 ug/L 94 70 -130 Ethylbenzene 50.0 57.0 ug/L 114 70 -130 lodomethane 50.0 45.5 ug/L 91 52 -129 m,p-Xylenes 50.0 55.3 ug/L ill 70-130 Methylene Chloride 50.0 45.3 ug/L 91 70 -130 o-Xylene 50.0 55.3 ug/L 111 70 -130 Styrene 50.0 53.8 ug/L 108 70 -130 Tetrachloroethene 50.0 42.5 ug/L 85 70 -130 Toluene 50.0 48.0 ug/L 96 70 -130 trans- l,2-Dichloroethene 50.0 50.1 ug/L 100 70-130 trans- 1,3-Dichloropropene 50.0 49.1 ug/L 98 70-130 trans- 1,4-Dichloro-2-butene 50.0 59.0 ug/L 118 67-120 Trichloroethene 50.0 46.2 ug/L 92 70 -130 Trichlorofluoromethane 50.0 66.0 ug/L 132 63 -142 Vinyl acetate 100 120 ug/L 120 67 -135 Vinyl chloride 50.0 59.4 ug/L 119 66 -129 Xylenes (total) 100 ill ug/L ill 70 -130 LCS LCS Surrogate %Recovery Qualifier Limits 1, 2-Dichloroethane-d4 (Surr) 105 60 -124 4-Bromofluorobenzene (Surr) 105 70 -130 Dibromofluoromethane (Surr) 96 70 -130 Toluene-d8 (Surr) 90 70 - 130 Eurofins Savannah Page 35 of 49 4/8/2024 QC Sample Results Client: Babb & Associates Job ID: 680-248614-1 Project/Site: Seaboard- Quarterly Surface Waters Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: LCSD 680-831278/5 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 831278 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit 1,1,1,2-Tetrachloroethane 50.0 54.1 ug/L 108 70-130 1 30 1,1,1-Trichloroethane 50.0 49.9 ug/L 100 70-130 1 30 1,1,2,2-Tetrachloroethane 50.0 54.5 ug/L 109 70-130 1 30 1,1,2-Trichloroethane 50.0 52.9 ug/L 106 70-130 0 30 1,1-Dichloroethane 50.0 49.2 ug/L 98 70-130 0 30 1,1-Dichloroethene 50.0 48.4 ug/L 97 70-130 2 20 1,2,3-Trichloropropane 50.0 49.8 ug/L 100 70-130 4 30 1,2-Dibromo-3-Chloropropane 50.0 50.6 ug/L 101 70-130 1 30 1,2-Dibromoethane 50.0 47.7 ug/L 95 70-130 2 30 1,2-Dichlorobenzene 50.0 52.7 ug/L 105 70 -130 0 30 1,2-Dichloroethane 50.0 53.7 ug/L 107 70 -130 3 50 1,2-Dichloropropane 50.0 52.5 ug/L 105 70 -130 1 20 1,4-Dichlorobenzene 50.0 52.6 ug/L 105 70 -130 0 30 2-Butanone 250 250 ug/L 100 69 -120 1 30 2-Hexanone 250 219 ug/L 88 70-130 3 20 4-Methyl-2-pentanone 250 259 ug/L 103 68 -120 3 30 Acetone 250 279 ug/L 112 67 -120 3 30 Acrylonitrile 500 513 ug/L 103 70 -130 3 30 Benzene 50.0 59.2 ug/L 118 70 -130 2 30 Bromochloromethane 50.0 45.8 ug/L 92 70 -130 0 30 Bromodichloromethane 50.0 45.2 ug/L 90 70 -130 3 30 Bromoform 50.0 47.3 ug/L 95 69 -129 3 30 Bromomethane 50.0 63.5 ug/L 127 28 -192 3 30 Carbon disulfide 50.0 55.7 ug/L 111 70 -130 2 30 Carbon tetrachloride 50.0 51.4 ug/L 103 70 -130 1 30 Chlorobenzene 50.0 50.6 ug/L 101 70 -130 2 30 Chloroethane 50.0 84.4 ug/L 169 31 - 213 9 30 Chloroform 50.0 50.4 ug/L 101 70 -130 1 30 Chloromethane 50.0 52.4 ug/L 105 59 -127 0 30 cis-1,2-Dichloroethene 50.0 53.4 ug/L 107 70 -130 1 30 cis-1,3-Dichloropropene 50.0 48.7 ug/L 97 70 -130 1 20 Dibromochloromethane 50.0 46.2 ug/L 92 70 -130 1 30 Dibromomethane 50.0 48.5 ug/L 97 70 -130 3 30 Ethylbenzene 50.0 56.7 ug/L 113 70 -130 0 20 lodomethane 50.0 45.8 ug/L 92 52 -129 0 30 m,p-Xylenes 50.0 54.7 ug/L 109 70 -130 1 30 Methylene Chloride 50.0 46.0 ug/L 92 70 -130 2 30 o-Xylene 50.0 54.6 ug/L 109 70 -130 1 30 Styrene 50.0 53.4 ug/L 107 70 -130 1 30 Tetrachloroethene 50.0 42.6 ug/L 85 70 -130 0 30 Toluene 50.0 48.6 ug/L 97 70 -130 1 30 trans- 1,2-Dichloroethene 50.0 50.2 ug/L 100 70-130 0 30 trans- 1,3-Dichloropropene 50.0 50.0 ug/L 100 70-130 2 30 trans- 1,4-Dichloro-2-butene 50.0 62.4 J2 ug/L 125 67-120 6 30 Trichloroethene 50.0 47.7 ug/L 95 70 -130 3 30 Trichlorofluoromethane 50.0 65.4 ug/L 131 63 -142 1 30 Vinyl acetate 100 120 ug/L 120 67 -135 0 30 Vinyl chloride 50.0 59.7 ug/L 119 66 -129 0 30 Eurofins Savannah Page 36 of 49 4/8/2024 QC Sample Results Client: Babb & Associates Project/Site: Seaboard- Quarterly Surface Waters Job ID: 680-248614-1 Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: LCSD 680-831278/5 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 831278 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit Xylenes (total) 100 109 ug/L 109 70 -130 1 30 • LCSD LCSD Surrogate %Recovery Qualifier Limits 1,2-Dichloroethane-d4 (Surr) 106 60- 124 4-Bromofluorobenzene (Surr) 106 70 - 130 Dibromofluoromethane (Surr) 96 70 - 130 Toluene-d8 (Surr) 91 70 - 130 Lab Sample ID: MB 680-831465/10 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 831465 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane 1.0 U 1.0 0.36 ug/L 04/05/24 12:12 1 1,1,1-Trichloroethane 1.0 U 1.0 0.21 ug/L 04/05/24 12:12 1 1,1,2,2-Tetrachloroethane 1.0 U 1.0 0.40 ug/L 04/05/24 12:12 1 1,1,2-Trichloroethane 1.0 U 1.0 0.32 ug/L 04/05/24 12:12 1 1,1-Dichloroethane 1.0 U 1.0 0.33 ug/L 04/05/24 12:12 1 1,1-Dichloroethene 1.0 U 1.0 0.33 ug/L 04/05/24 12:12 1 1,2,3-Trichloropropane 1.0 U 1.0 0.48 ug/L 04/05/24 12:12 1 1,2-Dibromo-3-Chloropropane 5.0 U 5.0 1.8 ug/L 04/05/24 12:12 1 1,2-Dibromoethane 1.0 U 1.0 0.33 ug/L 04/05/24 12:12 1 1,2-Dichlorobenzene 1.0 U 1.0 0.31 ug/L 04/05/24 12:12 1 1,2-Dichloroethane 1.0 U 1.0 0.25 ug/L 04/05/24 12:12 1 1,2-Dichloropropane 1.0 U 1.0 0.22 ug/L 04/05/24 12:12 1 1,4-Dichlorobenzene 1.0 U 1.0 0.31 ug/L 04/05/24 12:12 1 2-Butanone 10 U 10 6.4 ug/L 04/05/24 12:12 1 2-Hexanone 10 U 10 3.2 ug/L 04/05/24 12:12 1 4-Methyl-2-pentanone 10 U 10 2.7 ug/L 04/05/24 12:12 1 Acetone 11.5 J 20 3.7 ug/L 04/05/24 12:12 1 Acrylonitrile 20 U 20 5.5 ug/L 04/05/24 12:12 1 Benzene 1.0 U 1.0 0.27 ug/L 04/05/24 12:12 1 Bromochloromethane 1.0 U 1.0 0.34 ug/L 04/05/24 12:12 1 Bromodichloromethane 1.0 U 1.0 0.25 ug/L 04/05/24 12:12 1 Bromoform 1.0 U 1.0 0.59 ug/L 04/05/24 12:12 1 Bromomethane 5.0 U 5.0 3.7 ug/L 04/05/24 12:12 1 Carbon disulfide 5.0 U 5.0 0.43 ug/L 04/05/24 12:12 1 Carbon tetrachloride 1.0 U 1.0 0.30 ug/L 04/05/24 12:12 1 Chlorobenzene 1.03 1.0 0.15 ug/L 04/05/24 12:12 1 Chloroethane 5.0 U 5.0 4.6 ug/L 04/05/24 12:12 1 Chloroform 1.0 U 1.0 0.27 ug/L 04/05/24 12:12 1 Chloromethane 1.0 U 1.0 0.54 ug/L 04/05/24 12:12 1 cis-1,2-Dichloroethene 1.0 U 1.0 0.25 ug/L 04/05/24 12:12 1 cis-1,3-Dichloropropene 1.0 U 1.0 0.26 ug/L 04/05/24 12:12 1 Dibromochloromethane 1.0 U 1.0 0.39 ug/L 04/05/24 12:12 1 Dibromomethane 1.0 U 1.0 0.34 ug/L 04/05/24 12:12 1 Ethylbenzene 1.0 U 1.0 0.20 ug/L 04/05/24 12:12 1 lodomethane 10 U 10 3.9 ug/L 04/05/24 12:12 1 Eurofins Savannah Page 37 of 49 4/8/2024 QC Sample Results Client: Babb & Associates Job ID: 680-248614-1 Project/Site: Seaboard- Quarterly Surface Waters Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: MB 680-831465/10 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 831465 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac m,p-Xylenes 2.0 U 2.0 0.49 ug/L 04/05/24 12:12 1 Methylene Chloride 5.0 U 5.0 3.2 ug/L 04/05/24 12:12 1 o-Xylene 1.0 U 1.0 0.26 ug/L 04/05/24 12:12 1 Styrene 1.0 U 1.0 0.27 ug/L 04/05/24 12:12 1 Tetrachloroethene 1.0 U 1.0 0.35 ug/L 04/05/24 12:12 1 Toluene 1.0 U 1.0 0.25 ug/L 04/05/24 12:12 1 trans- 1,2-Dichloroethene 1.0 U 1.0 0.34 ug/L 04/05/24 12:12 1 trans- 1,3-Dichloropropene 1.0 U 1.0 0.23 ug/L 04/05/24 12:12 1 trans- 1,4-Dichloro-2-butene 2.0 U 2.0 1.3 ug/L 04/05/24 12:12 1 Trichloroethene 1.0 U 1.0 0.20 ug/L 04/05/24 12:12 1 Trichlorofluoromethane 1.0 U 1.0 0.33 ug/L 04/05/24 12:12 1 Vinyl acetate 5.0 U 5.0 0.69 ug/L 04/05/24 12:12 1 Vinyl chloride 1.0 U 1.0 0.40 ug/L 04/05/24 12:12 1 Xylenes (total) 3.0 U 3.0 0.23 ug/L 04/05/24 12:12 1 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 91 60- 124 04105124 12:12 1 4-Bromofluorobenzene (Surr) 92 70 - 130 04105124 12:12 1 Dibromofluoromethane (Surr) 97 70- 130 04105124 12:12 1 Toluene-d8 (Surr) 105 70 - 130 04105124 12:12 1 Lab Sample ID: LCS 680-831465/6 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 831465 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 1,1,1,2-Tetrachloroethane 50.0 53.6 ug/L 107 70-130 1,1,1-Trichloroethane 50.0 47.2 ug/L 94 70-130 1,1,2,2-Tetrachloroethane 50.0 46.3 ug/L 93 70-130 1,1,2-Trichloroethane 50.0 50.5 ug/L 101 70-130 1,1-Dichloroethane 50.0 46.3 ug/L 93 70-130 1,1-Dichloroethene 50.0 53.6 ug/L 107 70-130 1,2,3-Trichloropropane 50.0 55.3 ug/L 111 70-130 1,2-Dibromo-3-Chloropropane 50.0 38.7 ug/L 77 70-130 1,2-Dibromoethane 50.0 53.2 ug/L 106 70-130 1,2-Dichlorobenzene 50.0 49.5 ug/L 99 70 -130 1,2-Dichloroethane 50.0 45.2 ug/L 90 70 -130 1,2-Dichloropropane 50.0 48.7 ug/L 97 70 -130 1,4-Dichlorobenzene 50.0 51.5 ug/L 103 70 -130 2-Butanone 250 242 ug/L 97 69-120 2-Hexanone 250 219 ug/L 88 70-130 4-Methyl-2-pentanone 250 232 ug/L 93 68 -120 Acetone 250 231 ug/L 93 67-120 Acrylonitrile 500 452 ug/L 90 70 -130 Benzene 50.0 50.8 ug/L 102 70-130 Bromochloromethane 50.0 51.7 ug/L 103 70 -130 Bromodichloromethane 50.0 44.2 ug/L 88 70 -130 Bromoform 50.0 51.6 ug/L 103 69 -129 Eurofins Savannah Page 38 of 49 4/8/2024 QC Sample Results Client: Babb & Associates Job ID: 680-248614-1 Project/Site: Seaboard- Quarterly Surface Waters Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: LCS 680-831465/6 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 831465 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Bromomethane 50.0 62.4 ug/L 125 28 -192 Carbon disulfide 50.0 53.9 ug/L 108 70 -130 Carbon tetrachloride 50.0 48.6 ug/L 97 70 -130 Chlorobenzene 50.0 53.5 ug/L 107 70 -130 Chloroethane 50.0 55.2 ug/L 110 31 - 213 Chloroform 50.0 44.8 ug/L 90 70 -130 Chloromethane 50.0 46.2 ug/L 92 59 -127 cis-1,2-Dichloroethene 50.0 45.1 ug/L 90 70 -130 cis-1,3-Dichloropropene 50.0 49.5 ug/L 99 70 -130 Dibromochloromethane 50.0 50.7 ug/L 101 70 -130 Dibromomethane 50.0 48.1 ug/L 96 70 -130 Ethylbenzene 50.0 50.3 ug/L 101 70 -130 lodomethane 50.0 51.8 ug/L 104 52 -129 m,p-Xylenes 50.0 51.3 ug/L 103 70 -130 Methylene Chloride 50.0 45.9 ug/L 92 70 -130 o-Xylene 50.0 52.2 ug/L 104 70 -130 Styrene 50.0 56.4 ug/L 113 70 -130 Tetrachloroethene 50.0 56.7 ug/L 113 70 -130 Toluene 50.0 51.0 ug/L 102 70 -130 trans- 1,2-Dichloroethene 50.0 50.1 ug/L 100 70-130 trans- 1,3-Dichloropropene 50.0 49.9 ug/L 100 70-130 trans- 1,4-Dichloro-2-butene 50.0 47.9 ug/L 96 67-120 Trichloroethene 50.0 53.8 ug/L 108 70 -130 Trichlorofluoromethane 50.0 63.3 ug/L 127 63 -142 Vinyl acetate 100 74.8 ug/L 75 67 -135 Xylenes (total) 100 104 ug/L 104 70 -130 LCS LCS Surrogate %Recovery Qualifier Limits 1,2-Dichloroethane-d4 (Surr) 89 60- 124 4-Bromofluorobenzene (Surr) 94 70 - 130 Dibromofluoromethane (Surr) 100 70 - 130 Toluene-d8 (Surr) 102 70 -130 Lab Sample ID: LCSD 680-831465/7 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 831465 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit 1,1,1,2-Tetrachloroethane 50.0 53.6 ug/L 107 70-130 0 30 1,1,1-Trichloroethane 50.0 46.1 ug/L 92 70-130 2 30 1,1,2,2-Tetrachloroethane 50.0 46.8 ug/L 94 70-130 1 30 1,1,2-Trichloroethane 50.0 51.1 ug/L 102 70-130 1 30 1,1-Dichloroethane 50.0 46.8 ug/L 94 70-130 1 30 1,1-Dichloroethene 50.0 53.7 ug/L 107 70-130 0 20 1,2,3-Trichloropropane 50.0 56.4 ug/L 113 70-130 2 30 1,2-Dibromo-3-Chloropropane 50.0 39.4 ug/L 79 70-130 2 30 1,2-Dibromoethane 50.0 55.2 ug/L 110 70-130 4 30 1,2-Dichlorobenzene 50.0 50.0 ug/L 100 70 -130 1 30 0 Eurofins Savannah Page 39 of 49 4/8/2024 QC Sample Results Client: Babb & Associates Job ID: 680-248614-1 Project/Site: Seaboard- Quarterly Surface Waters Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: LCSD 680-831465/7 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 831465 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit 1,2-Dichloroethane 50.0 46.4 ug/L 93 70 -130 3 50 1,2-Dichloropropane 50.0 48.1 ug/L 96 70 -130 1 20 1,4-Dichlorobenzene 50.0 51.1 ug/L 102 70 -130 1 30 2-Butanone 250 242 ug/L 97 69-120 0 30 2-Hexanone 250 231 ug/L 92 70-130 5 20 4-Methyl-2-pentanone 250 240 ug/L 96 68 -120 3 30 Acetone 250 248 ug/L 99 67 -120 7 30 Acrylonitrile 500 476 ug/L 95 70 -130 5 30 Benzene 50.0 50.2 ug/L 100 70-130 1 30 Bromochloromethane 50.0 53.4 ug/L 107 70 -130 3 30 Bromodichloromethane 50.0 43.1 ug/L 86 70 -130 3 30 Bromoform 50.0 52.7 ug/L 105 69 -129 2 30 Bromomethane 50.0 63.3 ug/L 127 28 -192 1 30 Carbon disulfide 50.0 53.8 ug/L 108 70 -130 0 30 Carbon tetrachloride 50.0 47.8 ug/L 96 70 -130 2 30 Chlorobenzene 50.0 53.2 ug/L 106 70 -130 1 30 Chloroethane 50.0 54.8 ug/L 110 31 - 213 1 30 Chloroform 50.0 45.4 ug/L 91 70 -130 1 30 Chloromethane 50.0 47.3 ug/L 95 59 -127 2 30 cis-1,2-Dichloroethene 50.0 46.4 ug/L 93 70 -130 3 30 cis-1,3-Dichloropropene 50.0 49.5 ug/L 99 70 -130 0 20 Dibromochloromethane 50.0 51.0 ug/L 102 70 -130 1 30 Dibromomethane 50.0 50.2 ug/L 100 70 -130 4 30 Ethylbenzene 50.0 50.4 ug/L 101 70 -130 0 20 lodomethane 50.0 52.0 ug/L 104 52 -129 0 30 m,p-Xylenes 50.0 51.3 ug/L 103 70 -130 0 30 Methylene Chloride 50.0 47.2 ug/L 94 70 -130 3 30 o-Xylene 50.0 52.5 ug/L 105 70 -130 1 30 Styrene 50.0 56.5 ug/L 113 70 -130 0 30 Tetrachloroethene 50.0 56.2 ug/L 112 70 -130 1 30 Toluene 50.0 51.7 ug/L 103 70 -130 1 30 trans- 1,2-Dichloroethene 50.0 50.3 ug/L 101 70-130 1 30 trans- 1,3-Dichloropropene 50.0 50.0 ug/L 100 70-130 0 30 trans- l,4-Dichloro-2-butene 50.0 47.9 ug/L 96 67-120 0 30 Trichloroethene 50.0 53.3 ug/L 107 70 -130 1 30 Trichlorofluoromethane 50.0 63.6 ug/L 127 63 -142 1 30 Vinyl acetate 100 71.8 ug/L 72 67 -135 4 30 Xylenes (total) 100 104 ug/L 104 70 -130 0 30 LCSD LCSD Surrogate %Recovery Qualifier Limits 1,2-Dichloroethane-d4 (Surr) 98 60- 124 4-Bromofluorobenzene (Surr) 93 70 - 130 Dibromofluoromethane (Surr) 101 70 - 130 Toluene-d8 (Surr) 103 70 - 130 0 Eurofins Savannah Page 40 of 49 4/8/2024 QC Sample Results Client: Babb & Associates Project/Site: Seaboard- Quarterly Surface Waters Method: 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Lab Sample ID: MB 680-831625/5 Matrix: Water Analysis Batch: 831625 MB MB Analyte Result Qualifier RL MDL Unit 1,4-Dioxane 0.50 U 0.50 0.32 ug/L MB MB Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 86 46 - 154 Lab Sample ID: LCS 680-831625/3 Matrix: Water Analysis Batch: 831625 F Job ID: 680-248614-1 Client Sample ID: Method Blank Prep Type: Total/NA D Prepared Analyzed Dil Fac 04/06/2417:51 1 Prepared Analyzed DU Fac 04106124 17:51 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 1,4-Dioxane 5.00 5.05 ug/L 101 70 - 130 LCS LCS Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 96 46-154 FLab Sample ID: LCSD 680-831625/4 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 831625 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit 1,4-Dioxane 5.00 4.62 ug/L 92 70-130 9 30 LCSD LCSD Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 89 46 -154 FLab Sample ID: MB 680-831709/5 Matrix: Water Analysis Batch: 831709 MB MB Analyte Result Qualifier RL MDL Unit 1,4-Dioxane 0.50 U 0.50 0.32 ug/L MB MB Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 96 46 - 154 Lab Sample ID: LCS 680-831709/4 Matrix: Water Analysis Batch: 831709 Spike Analyte Added 1,4-Dioxane 5.00 LCS LCS Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 107 46 - 154 Client Sample ID: Method Blank Prep Type: Total/NA D Prepared Analyzed Dil Fac 04/07/24 12:13 1 Prepared Analyzed DU Fac 04107124 12:13 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA LCS LCS Result Qualifier Unit 4.99 ug/L %Rec D %Rec Limits 100 70-130 Eurofins Savannah Page 41 of 49 4/8/2024 QC Sample Results Client: Babb & Associates Project/Site: Seaboard- Quarterly Surface Waters F Job ID: 680-248614-1 Method: 8260D SIM 14D - Volatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: LCSD 680-831709/6 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 831709 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit 1,4-Dioxane 5.00 4.91 ug/L 98 70-130 2 30 LCSD LCSD Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 98 46-154 F Lab Sample ID: MB 680-831722/6 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 831722 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane 0.50 U 0.50 0.32 ug/L 04/08/24 05:21 1 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 85 46 - 154 04108124 05:21 1 FLab Sample ID: LCS 680-831722/4 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 831722 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 1,4-Dioxane 5.00 4.63 ug/L 93 70-130 LCS LCS Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 95 46 -154 Eurofins Savannah Page 42 of 49 4/8/2024 QC Association Summary Client: Babb & Associates Project/Site: Seaboard- Quarterly Surface Waters GC/MS VOA Analysis Batch: 831101 Job ID: 680-248614-1 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 680-248614-1 AW-3 Total/NA Surface Water 8260D 680-248614-2 AWB-4 Total/NA Surface Water 8260D 680-248614-3 SW-1 Total/NA Surface Water 8260D 680-248614-8 Trip Blank Total/NA Water 8260D MB 680-831101/8 Method Blank Total/NA Water 8260D LCS 680-831101/4 Lab Control Sample Total/NA Water 8260D LCSD 680-831101/5 Lab Control Sample Dup Total/NA Water 8260D Analysis Batch: 831273 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 680-248614-1 - DL AW-3 Total/NA Surface Water 8260D 680-248614-4 SW-2 Total/NA Surface Water 8260D 680-248614-5 SW-3 Total/NA Surface Water 8260D 680-248614-6 SW-4 Total/NA Surface Water 8260D 680-248614-7 SW-5 Total/NA Surface Water 8260D MB 680-831273/8 Method Blank Total/NA Water 8260D LCS 680-831273/4 Lab Control Sample Total/NA Water 8260D LCSD 680-831273/5 Lab Control Sample Dup Total/NA Water 8260D Analysis Batch: 831278 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 680-248614-2 - DL AWB-4 Total/NA Surface Water 8260D MB 680-831278/8 Method Blank Total/NA Water 8260D LCS 680-831278/4 Lab Control Sample Total/NA Water 8260D LCSD 680-831278/5 Lab Control Sample Dup Total/NA Water 8260D Analysis Batch: 831465 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 680-248614-2 AWB-4 Total/NA Surface Water 8260D 680-248614-3 SW-1 Total/NA Surface Water 8260D MB 680-831465/10 Method Blank Total/NA Water 8260D LCS 680-831465/6 Lab Control Sample Total/NA Water 8260D LCSD 680-831465/7 Lab Control Sample Dup Total/NA Water 8260D Analysis Batch: 831625 Lab Sample ID Client Sample ID 680-248614-1 AW-3 680-248614-2 AWB-4 680-248614-3 SW-1 680-248614-6 SW-4 680-248614-9 Trip Blank MB 680-831625/5 Method Blank LCS 680-831625/3 Lab Control Sample LCSD 680-831625/4 Lab Control Sample Dup Analysis Batch: 831709 Lab Sample ID Client Sample ID 680-248614-4 SW-2 MB 680-831709/5 Method Blank LCS 680-831709/4 Lab Control Sample LCSD 680-831709/6 Lab Control Sample Dup Prep Type Matrix Total/NA Surface Water Total/NA Surface Water Total/NA Surface Water Total/NA Surface Water Total/NA Water Total/NA Water Total/NA Water Total/NA Water Prep Type Matrix Total/NA Surface Water Total/NA Water Total/NA Water Total/NA Water Method 8260D SIM 14D 8260D SIM 14D 8260D SIM 14D 8260D SIM 14D 8260D SIM 14D 8260D SIM 14D 8260D SIM 14D 8260D SIM 14D Method 8260D SIM 14D 8260D SIM 14D 8260D SIM 14D 8260D SIM 14D Prep Batch Prep Batch Page 43 of 49 Eurofins Savannah 4/8/2024 QC Association Summary Client: Babb & Associates Project/Site: Seaboard- Quarterly Surface Waters GC/MS VOA Analysis Batch: 831722 Lab Sample ID Client Sample ID 680-248614-5 SW-3 680-248614-7 SW-5 MB 680-831722/6 Method Blank LCS 680-831722/4 Lab Control Sample Prep Type Matrix Total/NA Surface Water Total/NA Surface Water Total/NA Water Total/NA Water Job ID: 680-248614-1 Method 8260D SIM 14D 8260D SIM 14D 8260D SIM 14D 8260D SIM 14D Prep Batch Page 44 of 49 Eurofins Savannah 4/8/2024 Lab Chronicle Client: Babb & Associates Project/Site: Seaboard- Quarterly Surface Waters Job ID: 680-248614-1 Client Sample ID: AW-3 Lab Sample ID: 680-248614-1 Date Collected: 03/26/24 10:20 Matrix: Surface Water Date Received: 03/27/24 10:17 Batch Batch Prep Type Type Method Total/NA Analysis 8260D Instrument ID: CMSC Total/NA Analysis 8260D Instrument ID: CMSC Total/NA Analysis 8260D SIM 14D Instrument ID: CMSAK Client Sample ID: AWB-4 Date Collected: 03/26/24 09:55 Date Received: 03/27/24 10:17 Dil Initial Run Factor Amount 1 5 mL DL 5 5 mL 50 10 mL Final Batch Prepared Amount Number or Analyzed Analyst Lab 5 mL 831101 04/03/24 19:48 Y1 S EET SAV 5 mL 831273 04/04/24 18:50 Y1 S EET SAV 10 mL 831625 04/07/24 03:03 AA EET SAV • Lab Sample ID: 680-248614-2 Matrix: Surface Water Prep Type Batch Batch Type Method Run Dil Factor Initial Amount Final Amount Batch Number Prepared or Analyzed Analyst Lab Total/NA Analysis 8260D 10 5 mL 5 mL 831465 04/05/24 18:29 MLL EET SAV Instrument ID: CMSAB Total/NA Analysis 8260D 1 5 mL 5 mL 831101 04/03/24 20:10 Y1 S EET SAV Instrument ID: CMSC Total/NA Analysis 8260D DL 10 5 mL 5 mL 831278 04/04/24 19:42 P1 C EET SAV Instrument ID: CMSU Total/NA Analysis 8260D SIM 14D 100 10 mL 10 mL 831625 04/07/24 03:29 AA EET SAV Instrument ID: CMSAK Client Sample ID: SW-1 Lab Sample ID: 680-248614-3 Date Collected: 03/26/24 07:50 Matrix: Surface Water Date Received: 03/27/24 10:17 Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 8260D 1 5 mL 5 mL 831465 04/05/24 13:54 MLL EET SAV Instrument ID: CMSAB Total/NA Analysis 8260D 1 5 mL 5 mL 831101 04/03/24 20:32 Y1 S EET SAV Instrument ID: CMSC Total/NA Analysis 8260D SIM 14D 1 10 mL 10 mL 831625 04/06/24 20:14 AA EET SAV Instrument ID: CMSAK Client Sample ID: SW-2 Lab Sample ID: 680-248614-4 Date Collected: 03/26/24 08:05 Matrix: Surface Water Date Received: 03/27/24 10:17 Batch Batch Prep Type Type Method Total/NA Analysis 8260D Instrument ID: CMSC Total/NA Analysis 8260D SIM 14D Instrument ID: CMSAK Dil Initial Run Factor Amount 1 5 mL 1 10 mL Final Batch Prepared Amount Number or Analyzed Analyst Lab 5 mL 831273 04/04/24 14:19 Y1 S EET SAV 10 mL 831709 04/07/24 13:30 AA EET SAV Page 45 of 49 Eurofins Savannah 4/8/2024 Lab Chronicle Client: Babb & Associates Job ID: 680-248614-1 Project/Site: Seaboard- Quarterly Surface Waters Client Sample ID: SW-3 Lab Sample ID: 680-248614-5 Date Collected: 03/26/24 08:30 Matrix: Surface Water Date Received: 03/27/24 10:17 Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 8260D 1 5 mL 5 mL 831273 04/04/24 14:42 Y1 S EET SAV Instrument ID: CMSC Total/NA Analysis 8260D SIM 14D 1 10 mL 10 mL 831722 04/08/24 05:56 AA EET SAV Instrument ID: CMSAK Client Sample ID: SW-4 Lab Sample ID: 680-248614-6 Date Collected: 03/26/24 09:15 Matrix: Surface Water Date Received: 03/27/24 10:17 Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 8260D 1 5 mL 5 mL 831273 04/04/24 15:04 Y1 S EET SAV Instrument ID: CMSC Total/NA Analysis 8260D SIM 14D 50 10 mL 10 mL 831625 04/06/24 21:31 AA EET SAV Instrument ID: CMSAK Client Sample ID: SW-5 Lab Sample ID: 680-248614-7 Date Collected: 03/26/24 08:20 Matrix: Surface Water Date Received: 03/27/24 10:17 Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 8260D 1 5 mL 5 mL 831273 04/04/24 15:26 Y1 S EET SAV Instrument ID: CMSC Total/NA Analysis 8260D SIM 14D 1 10 mL 10 mL 831722 04/08/24 06:21 AA EET SAV Instrument ID: CMSAK Client Sample ID: Trip Blank Lab Sample ID: 680-248614-8 Date Collected: 03/26/24 00:00 Matrix: Water Date Received: 03/27/24 10:17 Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 8260D 1 5 mL 5 mL 831101 04/03/24 16:26 Y1 S EET SAV Instrument ID: CMSC Client Sample ID: Trip Blank Lab Sample ID: 680-248614-9 Date Collected: 03/26/24 00:00 Matrix: Water Date Received: 03/27/24 10:17 Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 8260D SIM 14D 1 10 mL 10 mL 831625 04/06/24 18:16 AA EET SAV Instrument ID: CMSAK Laboratory References: EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL (912)354-7858 Page 46 of 49 Eurofins Savannah 4/8/2024 Eurofins Savannah 5102 LaRoche Avenue Savannah, GA 31404 Phone:912-354-7858 Fax:912-352-0165 Chain of Custody Record eurofins Environment Testing Client Informationa.ti.41 Sample 0� Lab PM Andros, John Carrier Tracking No(s): COC No'. 680-152304-55035.1 Client Contact: Gary Babb Phone- �$��y -3GX0-or E-Mail: John.Andros@et.eurofinsus.com State of Origin: Page: Page 1 of 1 Company: Babb 8 Associates PWSID: Analysis Requested Job #: Address 5506 Bradford Pear Court Due Date Requested: = ` o d, } „ r6 a m LL � ti o z `o m i✓ 47 ? E -t as u > K d a < °o a `m o o '- X — f Z c, v m :? O `m Z -a Preservation Codes: A - HCL M -Hexane B - NaOH N - None C • Zn Acetate O - Na204S 0 - Nitric Acid P • Na2043 O - Na2S03 E - NaHSO4 R - Na2S203 F•MeOH S-H2SO4 G • Amchlor H-AmchlCACId T- TSPDodecahydrate 1 - Ice -Acetone V - MCAA J-DI Water w-pHpH4- 4-5 K - EDTA Y - Trizma L - EDA Z-other (specify) Other: City Raleigh TAT Requested (days): State. Zip: NC, 27606 Compliance Project: .5 Yes a No Phone: 919-605-4713(Tel) PO #, Purchase Order not required Email gbabb@nc.rr.com W0 #- Project Name: Seaboard - Quarterly Surface Wa Project #: 68024012 Sit e: SSOW#: Sample Identification Sample Date Sample Time Sample Type (C=comp, G= rab) Matrix (w_w '. S-0d. o-...,,t,au. aT,T1.,uo,A,41r) Special Instructions/Note: Preservation Code: A A - 7 T-z&-Z JL zb G ` z! -z 07 v 680-248614 Chain of Custody i Possible Hazard Identification 0 Non -Hazard 0 Flammable Skin Irritant Poison B Unknown Radiological Sample Disposal (A fee may be assessed if samples are retained longer than 1 month) O Return To Client 0 Disposal By Lab Archive For Months Deliverable Requested: I, II, III, IV, Other (specify) Special Instructions/QC Requirements: Empty Kit Relinquished by: Date: Time: Method of shipment: Relinquished47 t�/ Date/Ti�m-�� v Company Received byi , / Date/ifine: _ J Company Relinquished by: Dater7ime Company Rew- d by>j Dat rrrriime:: Company Relinquished by: Daterrime- Company Received by: Date/Time: Company Custody Seals Intact: Custody Seal No.: e Yes 0 No I Cooler Temperature(s) °C and Other Remarks: I 0 Page 47 of 49 % Ver: 06/O"9/8/2024 Login Sample Receipt Checklist Client: Babb & Associates Job Number: 680-248614-1 Login Number: 248614 List Number: 1 Creator: Johnson, Corey M Question List Source: Eurofins Savannah Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey N/A meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True m Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? True There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. N/A There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is True <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. N/A Eurofins Savannah Page 48 of 49 4/8/2024 Accreditation/Certification Summary Client: Babb & Associates Job ID: 680-248614-1 Project/Site: Seaboard- Quarterly Surface Waters Laboratory: Eurofins Savannah The accreditations/certifications listed below are applicable to this report. Authority Program Identification Number Expiration Date North Carolina (WW/SW) State 269 12-31-24 Eurofins Savannah Page 49 of 49 4/8/2024