HomeMy WebLinkAbout19054_VIMS Upfit Report Rev. 1_Centro Railyard Space 12_20211129
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VIMS Upfit Inspection and Sampling Report – Revision 1
Commercial Space 12
HD Supply Brownfields Property/Centro Railyard Apartments
1425 Winnifred Street
Charlotte, Mecklenburg County, North Carolina
Brownfields Project No. 19054-15-060
H&H Job No. CTT-001
Table of Contents
Section Page No.
1.0 Introduction and Background ...............................................................................................1
2.0 Vapor Intrusion Mitigation System Installation ..................................................................3
2.1 VIMS Inspections ..................................................................................................................3
3.0 Indoor Air Assessment Activities ..........................................................................................5
3.1 Building Survey Activities ....................................................................................................5
3.2 April 2021 Indoor Air Sampling ...........................................................................................5
3.3 April 2021 Indoor Air Sampling Results ...............................................................................6
3.4 August 2021 Indoor Air Sampling ........................................................................................7
3.5 August 2021 Indoor Air Sampling Results ...........................................................................9
4.0 Sub-Slab Vapor Assessment Activities................................................................................10
4.1 Sub-Slab Vapor Sampling ...................................................................................................10
4.3 Sub-Slab Vapor Sampling Results ......................................................................................11
5.0 Vapor Intrusion Evaluation .................................................................................................13
6.0 Summary and Conclusions ..................................................................................................15
List of Tables
Table 1 Summary of Chemicals from Safety Data Sheets
Table 2 Site-Specific Indoor Air VOC List
Table 3 Summary of Indoor Air Analytical Results
Table 4 Summary of Sub-Slab Vapor Analytical Results
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List of Figures
Figure 1 Site Location Map
Figure 2 Site Map
Figure 3 Sample Location Map
List of Appendices
Appendix A VIMS As-Built Drawing (VM-1)
Appendix B Photo Log
Appendix C Field Forms
Appendix D Safety Data Sheets for Products Used During Construction
Appendix E Laboratory Analytical Reports
Appendix F DEQ Risk Calculator Input/Output Forms
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VIMS Upfit Inspection and Sampling Report – Revision 1
Commercial Space 12
HD Supply Brownfields Property/Centro Railyard Apartments
1425 Winnifred Street
Charlotte, Mecklenburg County, North Carolina
Brownfields Project No. 19054-15-060
H&H Job No. CTT-001
1.0 Introduction and Background
Hart & Hickman, PC (H&H) has prepared this report to document vapor intrusion mitigation
system (VIMS) upfit inspections and post-upfit indoor air sampling activities completed for
Commercial Space 12 at the Centro Railyard Apartments at the HD Supply Brownfields property
(Brownfields Project No. 19054-15-060). The Centro Railyard Apartments are located at 1425
Winnifred Street in Charlotte, Mecklenburg County, North Carolina (Site or subject Site). A Site
location map is provided as Figure 1.
The Brownfields property was previously comprised of one approximately 3.38-acre parcel of
land owned by RailYard, LLC (formerly Beacon MPI, LLC). However, RailYard, LLC sold an
approximately 0.74-acre area in the western portion of the Site to Centro RailYard, LLC on
November 27, 2018. Currently, the HD Supply Brownfields property is comprised of two
parcels. The eastern approximately 2.77-acre parcel (Parcel No. 07309204) was developed by
RailYard, LLC with two multi-purpose high-rise towers (north tower and south tower) which
consist of commercial offices, retail spaces and a parking deck. RailYard, LLC subsequently
sold the property to Cousins RailYard LP in December 2020. The western approximately 0.74-
acre parcel (Parcel No. 07309217) was developed by Centro RailYard, LLC with a multi-story
building including retail units on the ground floor with multi-family residential apartment units
above. Centro RailYard, LLC sold the western parcel in December 2020, and it is currently
owned by 1425 Winnifred NC Property LLC (1425 Winnifred). A Site map is provided as
Figure 2.
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The ground floor of the Centro Railyard Apartments, located on the smaller parcel owned by
1425 Winnifred, contains a leasing office, several commercial spaces, and amenities such as a
fitness center. Upper floors contain residential and amenity spaces.
Results of previous assessment activities indicated that vapor mitigation was warranted for the
southern wing of the apartment building. As such, a Vapor Intrusion Mitigation Plan –
Revision 1 (VIMP) was prepared and submitted to the North Carolina Department of
Environmental Quality (DEQ) on May 30, 2019 for the southern wing of the apartment building
to address the potential vapor intrusion concern. The VIMP was subsequently approved by DEQ
in a letter dated June 6, 2019. VIMS installation activities for the southern wing of the apartment
building are documented in H&H’s Vapor Intrusion Mitigation System Installation Report dated
May 26, 2020.
In March 2021, upfit activities began in Commercial Space 12, a commercial retail space located
in the northwest corner of the apartment building’s southern wing, to retrofit the space for a new
retail tenant. H&H submitted to DEQ a Request for VIMP Modifications dated March 11, 2021,
which was subsequently approved on March 18, 2021 that described proposed modifications to
the approved VIMP to accommodate the installation of new utilities in Commercial Space 12.
The modifications included the removal and replacement of portions of the existing concrete
slab, slight modifications to the sub-slab piping, and replacement of the vapor barrier.
This report only documents upfit activities and post-upfit indoor air sampling in Commercial
Space 12. A report documenting the annual post-occupancy indoor air sampling titled Post-
Occupancy Indoor Air Sampling Report, dated May 14, 2021, was submitted to DEQ under
separate cover. A brief summary of the VIMS and upfit inspections is provided in Section 2.0, a
discussion of post-upfit indoor air sampling activities is provided in Section 3.0, and a summary
and conclusions based on the sampling results are provided in Section 4.0.
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2.0 Vapor Intrusion Mitigation System Installation
As detailed in the DEQ-approved VIMP, the VIMS in the southern wing of the apartment
building is a passive sub-slab vapor extraction system that extends under the southern wing of
the Centro Railyard Apartments building. The system is constructed with 3-inch and 4-inch
diameter slotted horizontal poly-vinyl chloride (PVC) pipe installed in approximately 5 inches of
high permeability stone/gravel (#57 stone). The stone layer is overlain with a 20-mil Drago-
Wrap vapor barrier manufactured by Stego Industries, LLC (Stego). The horizontal PVC pipes
in the apartment building are connected to one 3-inch diameter riser pipe and one 4-inch
diameter riser pipe which extend approximately 2 ft above the roofline. Wind driven turbine
fans are installed on each of the two riser pipes to enhance the passive VIMS. A turned-down
slab is installed along the northeastern termination of the vapor barrier between Commercial
Space 10 and Commercial Space 11 (see Figure 3) to prevent air communication between the
VIMS and the remaining portion of the building. Additional details regarding the VIMS
components and specifications were provided in the VIMP.
In the area of the modified VIMS in Commercial Space 12, the layout of the 4-inch horizontal
piping was slightly modified in order to maintain connectivity of the vent pipe, gravel layer, and
VIMS riser pipes while allowing for installation of new sub-slab utilities. Raven Industries
VaporBlock®-20 Plus (VBP-20) 20-mil vapor barrier was installed below the area of removed
and replaced concrete, and was connected to the existing Drago-Wrap with appropriate overlaps
and sealing methods as specified in the manufacturers’ installation instructions. A VIMS as-built
drawing (VM-1) dated May 28, 2021 depicts the completed modifications to the VIMS in
Commercial Space 12 and is included as Appendix A.
2.1 VIMS Inspections
For quality assurance and quality control (QA/QC) purposes, inspections of the area of the
modified VIMS were conducted by H&H at the direction of a North Carolina Professional
Engineer (PE) during each phase of the VIMS re-installation including:
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upon installation of the new sub-slab piping layout and the placement of clean #57 stone
(inspection completed on March 9, 2021); and
after placement of the vapor barrier on top of the vent piping and stone (inspection
completed on March 11, 2021).
After the inspections, H&H concluded that the area of the modified VIMS in Commercial Space
12 was properly installed in general accordance with the DEQ-approved VIMP and Request for
VIMP Modifications. A photographic log of the VIMS modifications is included as Appendix B,
and field inspection forms from H&H are included in Appendix C.
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3.0 Indoor Air Assessment Activities
Indoor air sampling was performed in Commercial Space 12 to evaluate effectiveness of the
VIMS under following the commercial tenant upfit activities. The indoor air assessment
activities were conducted in accordance with the DEQ Division of Waste Management’s (DWM)
Vapor Intrusion Guidance (Guidance) dated March 2018. A description of the sampling
activities and results is provided below.
3.1 Building Survey Activities
Prior to collecting indoor air samples, H&H completed the Indoor Air Building Survey and
Sampling Form to document conditions within Commercial Space 12 and help identify potential
background sources of volatile organic compounds (VOCs). The survey form is provided in
Appendix C. Furthermore, Safety Data Sheets (SDSs) for products used during previous
building construction are provided as Appendix D. A table summarizing chemicals present
within the SDSs is attached as Table 1.
3.2 April 2021 Indoor Air Sampling
On April 7, 2021, H&H collected one indoor air sample, IAS-1, approximately two weeks after
installation of the repaired concrete slab in Commercial Space 12. An exterior, upwind
background air sample, BAS-1, was collected concurrently with the indoor air sample to evaluate
compound concentrations in ambient outdoor air. Additionally, for QA/QC purposes, one
duplicate indoor air sample, IAS-DUP, was collected along with indoor air sample IAS-1
utilizing a laboratory supplied stainless-steel sampling “T” which allows for the simultaneous
collection of two indoor air samples from a single location. The sample locations are depicted
on Figure 3.
The indoor air samples were collected with the windows of Commercial Space 12 closed and
ingress and egress activities minimized. Due to on-going above slab upfit activities, the heating,
ventilation, and air conditioning (HVAC) equipment in this space were not fully installed and
thus were not operational during the sampling event. The samples were collected using
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laboratory-supplied individually certified 6-liter stainless steel Summa canisters connected to in-
line flow controllers with a vacuum gauge. The flow controllers were calibrated by the
laboratory to allow for sample collection over an approximately 8-hour period. Summa canisters
were placed in positions such that the sample intake point was positioned approximately 5 ft
above grade (typical breathing zone height) when the sample canister was set on its base.
During sampling activities, indoor/outdoor air pressure differential was measured near the start,
middle, and end of the 8-hour sampling period using a manometer sensitive to 0.001 inches of
water. In addition, barometric pressure, exterior wind speed, exterior wind direction, and
indoor/outdoor temperature were recorded near the start, middle, and end of the sampling period.
For quality assurance purposes, H&H personnel periodically monitored the sample canisters to
prevent tampering or damage during the sampling event. Vacuum was measured in each of the
Summa canisters prior to and after sampling activities. Per laboratory standard operating
procedures, a vacuum of at least 5 inches of mercury was maintained within the canisters at the
conclusion of the sampling event. A summary of the field measurement data collected at the
time of the indoor air sampling event is provided in indoor air sampling forms included in
Appendix C.
Upon completion of the indoor air sampling event, the Summa canisters were properly labeled
with the sample identification, date, time, starting and ending vacuums, and requested analysis
and were placed in a laboratory-supplied shipping container. The samples were shipped under
standard chain-of-custody protocols to Waypoint Analytical (Waypoint) for analysis of select
VOCs by EPA Method TO-15. The target analyte list for the indoor air samples included each
compound that was detected above laboratory reporting limits during previous soil gas sampling
completed at the Site. The Site-specific list of VOCs is provided as Table 2.
3.3 April 2021 Indoor Air Sampling Results
A tabular summary of the indoor air sampling results is provided as Table 3. The indoor air
analytical results were compared to the DEQ DWM Non-Residential and Residential Vapor
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Intrusion Indoor Air Screening Levels (IASLs) dated June 2021. Copies of the laboratory
analytical report and chain-of-custody record are provided in Appendix E.
Laboratory analytical results indicate the presence of chloroform at estimated concentrations
(laboratory J flag values) of 1.03 µg/m3 and 1.06 µg/m3 in indoor air sample IAS-1 and duplicate
sample IAS-DUP, respectively. These concentrations are slightly above the Non-Residential
IASL of 0.53 µg/m3. Results also indicate the presence of 1,2,4-trimethylbenzene at a
concentration of 54.4 µg/m3 in IAS-DUP, which is slightly above its Non-Residential IASL of
53 µg/m3.
Several other VOCs were detected at concentrations above laboratory method detection limits
but below Non-Residential IASLs. For comparison purposes, several compounds were also
detected above the Residential IASLs, but below the Non-Residential IASLs. These specific
compounds are identified in Table 3. Trichloroethene (TCE), which was previously detected in a
sample during pre-occupancy indoor air screening, was not detected above laboratory method
detection limits in any sample. In addition, tetrachloroethene (PCE), a main contaminant of
concern from previous Brownfields assessment activities, was only detected in the duplicate
sample at a low estimated concentration that is below the Residential and Non-Residential
IASLs.
3.4 August 2021 Indoor Air Sampling
On August 24, 2021, H&H collected one indoor air sample, IAS-1, approximately 5 months after
installation of the repaired concrete slab in Commercial Space 12. An exterior, upwind
background air sample, BAS-1, was collected concurrently with the indoor air sample to evaluate
compound concentrations in ambient outdoor air. Additionally, for QA/QC purposes, one
duplicate indoor air sample, IAS-DUP, was collected along with indoor air sample IAS-1
utilizing a laboratory supplied stainless-steel sampling “T” which allows for the simultaneous
collection of two indoor air samples from a single location. The sample locations, which are
consistent with the April 2021 sampling event, are depicted on Figure 3. In addition, indoor air
sampling methodology and laboratory analysis were consistent with the April 2021 sampling
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event. A summary of the field measurement data collected during the August 2021 indoor air
sampling event are provided in indoor air sampling forms included in Appendix C.
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3.5 August 2021 Indoor Air Sampling Results
A tabular summary of the indoor air sampling results is provided as Table 3. The indoor air
analytical results were compared to the DEQ DWM Non-Residential and Residential IASLs
dated June 2021. Copies of the laboratory analytical report and chain-of-custody record are
provided in Appendix E.
Laboratory analytical results indicate the presence of benzene at concentrations of 1.95 µg/m3
and 1.91 µg/m3 in indoor air sample IAS-1 and duplicate sample IAS-DUP, respectively. These
concentrations are slightly above the Non-Residential IASL of 1.60 µg/m3. Results also indicate
the presence of chloroform at a concentration of 2.59 µg/m3 and 2.53 µg/m3 in samples IAS-1
and IAS-DUP, respectively. These concentrations are slightly higher than the Non-Residential
IASL of 0.53 µg/m3.
Unlike the sampling completed in April 2021, results did not indicate the presence of 1,2,4-
trimethylbenzene at a concentration above the Non-Residential IASL. The concentrations found
in samples IAS-1 and IAS-DUP were 17.7 µg/m3 and 16.3 µg/m3 compared to the Non-
Residential IASL of 53 µg/m3. However, these concentrations are slightly greater than the
Residential IASL of 13 µg/m3.
Several other VOCs were detected at concentrations above the Residential IASLs but below the
Non-Residential IASLs. These specific compounds are identified in Table 3. Trichloroethene
(TCE), which was previously detected in a sample during pre-occupancy indoor air screening,
was detected above laboratory method detection limits but as an estimated concentration lower
than the Non-Residential IASL. In addition, tetrachloroethene (PCE), a main contaminant of
concern from previous Brownfields assessment activities, was detected at a low estimated
concentration that is below the Residential and Non-Residential IASLs.
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4.0 Sub-Slab Vapor Assessment Activities
Sub-slab vapor sampling was performed in Commercial Space 12 to evaluate effectiveness of the
VIMS under following the commercial tenant upfit activities. The indoor air assessment
activities were conducted in accordance with the DEQ Division of Waste Management’s (DWM)
Vapor Intrusion Guidance (Guidance) dated March 2018. A description of the sampling
activities and results is provided below.
4.1 Sub-Slab Vapor Sampling
On August 24, 2021, H&H collected one sub-slab vapor sample, SS-OP-1, approximately 5
months after installation of the repaired concrete slab in Commercial Space 12. Additionally, for
QA/QC purposes, one duplicate sub-slab vapor sample, SS-DUP, was collected along with sub-
slab vapor sample SS-OP-1 utilizing a laboratory supplied stainless-steel sampling “T” which
allows for the simultaneous collection of two sub-slab vapor samples from a single location. The
sample locations are depicted on Figure 3.
At the sub-slab vapor sample location, a temporary expandable plug with a quick connect
sampling port was placed within the monitoring point to create an air-tight seal. Teflon sample
tubing was then secured to the sampling port and connected to an airflow regulator and
laboratory-supplied batch-certified 1-liter stainless steel Summa canister. The air flow regulator
was preset by the laboratory to collect a soil gas sample at a flow rate no greater than
approximately 200 milliliters per minute.
Prior to sample collection, H&H conducted a leak test at each monitoring point by placing a
shroud around the monitoring point and sampling train including the Summa canister. The air
within the shroud was flooded with helium gas and concentrations were measured with a
calibrated helium detector. Helium concentrations within the shroud were maintained between
approximately 15% and 20%. A syringe was connected to the sample tubing outside of the
shroud and used to purge a minimum of three sample train volumes into a Tedlar® bag at each
sampling point. The helium gas detector was used to measure helium concentrations within the
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Tedlar® bag sample to confirm helium concentrations in the sample were less than 10% of that
measured within the shroud. Results of the helium leak checks indicate that short-circuiting at
the monitoring points or within the sampling train was not present. Sub-slab soil gas sample
field forms completed by sampling personnel are included in Appendix C.
Following a successful leak check, the Summa canister air flow regulators were opened to allow
collection of the sub-slab soil gas samples. Vacuum in the Summa canisters was monitored
during the sampling event to confirm adequate sample volume was collected at each monitoring
point. Upon completion of sample collection, the Summa canister air flow regulator was closed.
Upon completion of the sub-slab vapor sampling event, the Summa canisters were properly
labeled with the sample identification, date, time, starting and ending vacuums, and requested
analysis and were placed in a laboratory-supplied shipping container. The samples were shipped
under standard chain-of-custody protocols to Waypoint Analytical (Waypoint) for analysis of
select VOCs by EPA Method TO-15. The target analyte list for the sub-slab vapor samples
included each compound that was detected above laboratory reporting limits during previous soil
gas sampling completed at the Site. The Site-specific list of VOCs is provided as Table 2.
4.3 Sub-Slab Vapor Sampling Results
A tabular summary of the sub-slab vapor sampling results is provided as Table 4. The sub-slab
vapor analytical results were compared to the DEQ DWM Non-Residential and Residential
Vapor Intrusion Sub-slab and Exterior Soil Gas Screening Levels (SGSLs) dated June 2021.
Copies of the laboratory analytical report and chain-of-custody record are provided in Appendix
E.
Laboratory analytical results indicate the presence of 1,2,4-trimethylbenzene at concentrations of
10,400 µg/m3 and 9,980 µg/m3 in sub-slab vapor sample SS-OP-1 and duplicate sample SS-DUP,
respectively. These concentrations are above the Non-Residential SGSL of 5,300 µg/m3.
Results also indicated the presence of 1,3,5-trimethylbenzene at concentrations of 3,530 µg/m3
and
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3,460 µg/m3 in samples SS-OP-1 and SS-DUP, respectively. These concentrations exceed the
Residential SGSL of 420 µg/m3 but are less than the Non-Residential SGSL of 5,300 µg/m3 .
PCE, a main contaminant of concern from previous Brownfields assessment activities, was not
detected above the laboratory method detection limit. In addition, TCE was not detected above
the laboratory method detection limit in sub-slab vapor samples but was detected in indoor air
samples IAS-1/IAS-DUP as noted above.
Several other VOCs were detected at concentrations above laboratory method detection limits
but below Residential and Non-Residential SGSLs. These specific compounds are identified in
Table 3.
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5.0 Vapor Intrusion Evaluation
Commercial Space 12 is located on the ground floor of the Centro Railyard Apartments building.
The HVAC units in this space are separate from the HVAC units on the upper floor residential
spaces. Therefore, direct air exchange between the ground floor and upper floors is not likely to
occur, and the samples collected in this space are representative of commercial conditions and
are likely not representative of the upper floor residential conditions.
The detections of chloroform and 1,2,4-trimethylbenzene in indoor air sample IAS-1 and
duplicate indoor air sample IAS-DUP may be partially attributable to background indoor air
sources due to the VOC off-gassing of building materials from initial building construction and
the recent renovation activities. The compound 1,2,4-trimethylbenzene is a common component
of building materials that can be present in products containing petroleum distillates.
Furthermore, chloroform, while not specifically identified in the SDSs that were provided during
construction, is a compound commonly found in cleaning products. Table 1 summarizes
chemicals found in the SDSs for products used during the building’s construction that were
provided by the construction contractors.
To evaluate the potential health risks associated with the compounds detected in the indoor air
samples, H&H used DEQ’s Risk Calculator dated June 2021. H&H input the highest
concentration of each compound that was detected in sample IAS-1 and its duplicate sample
(IAS-DUP) into the DEQ Risk Calculator. The DEQ DWM Vapor Intrusion IASLs used for
comparison to the laboratory analytical results are conservative and based upon a target
carcinogenic risk (TCR) of 1.0 x 10-6 and a non-carcinogenic hazard quotient (HQ) of 0.2.
DEQ’s acceptable level for potential carcinogenic risks is a cumulative lifetime incremental
cancer risk (LICR) of 1.0 x 10-4 or less, and the acceptable level for non-carcinogenic risks is a
cumulative hazard index (HI) of 1.0 or less. The HI is the sum of HQs for each detected target
analyte.
Results of the risk calculations using April 2021 indoor air data indicate a calculated cumulative
LICR of 3.2 x 10-6 and a calculated cumulative HI of 0.47. Results of the risk calculations using
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August 2021 indoor air data indicate a calculated cumulative LICR of 7.6 x 10-6 and a calculated
cumulative HI of 0.53. Therefore, the calculated carcinogenic and non-carcinogenic risks using
both datasets are below the DEQ acceptable level of 1 x 10-4 for the cumulative LICR and 1.0 for
the cumulative HI.
While Commercial Space 12 is to be used for commercial retail use only, risk calculations were
also performed for a residential use scenario for comparison. The results using April 2021 data
indicate a calculated cumulative LICR of 1.4 x 10-5 and a calculated cumulative HI of 2.0. The
results using August 2021 data indicate a calculated cumulative LICR of 3.4 x 10-5 and a
calculated cumulative HI of 2.2. Results using both datasets indicate that carcinogenic risks are
below the DEQ acceptable level of 1 x 10-4, but non-carcinogenic risks exceed the acceptable
threshold of 1.0. Drivers for the residential use HI exceedance include ethyl acetate,
isopropanol, TCE, and 1,2,4-trimethylbenzene. Ethyl acetate is present in spray paint used at the
Site (see Appendix D) and was also detected in the background sample collected in April 2021.
Isopropanol (rubbing alcohol) is a common cleaning agent and is present in alcohol-based
cleaners and hand sanitizers, and this compound was also detected in the background air samples
collected in April and August 2021. 1,2,4-trimethylbenzene is commonly found in building
products containing petroleum distillates. As noted below in Section 4.3, TCE was not detected
in sub-slab vapor samples
SS-OP-1/SS-DUP, which were collected immediately following the indoor air sampling in
August 2021. Therefore, the presence of these compounds may be partially attributable to off-
gassing from building materials during prior construction and recent renovation activities,
cleaning products, or the presence of background concentrations. The DEQ Risk Calculator
input/output forms for both sampling events are provided as Appendix F.
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6.0 Summary and Conclusions
In accordance with the DEQ-approved Request for VIMP Modifications and DEQ-approved
VIMP, H&H has completed upfit inspection and post-upfit indoor air assessment activities in
Commercial Space 12 in the Centro Railyard Apartments at the HD Supply Brownfields Site
(Brownfields Project No. 19054-15-060). The activities are summarized as follows:
In March 2021, H&H completed inspections of the VIMS components during upfit
activities and determined the modified VIMS was installed in general accordance DEQ-
approved VIMP. On April 7, 2021, following completion of the concrete slab, H&H
collected indoor air sample IAS-1 and associated duplicate sample IAS-DUP from within
Commercial Space 12, and background air sample BAS-1 from an exterior, upwind
location. Per the request of DEQ, H&H performed an additional sampling event in
August 2021 which included the collection of a sub-slab vapor sample, a duplicate sub-
slab vapor sample, and a follow-up indoor air sample and duplicate.
Laboratory analytical results indicated the presence of multiple VOCs in sub-slab vapor
and indoor air samples at concentrations above the DEQ Vapor Intrusion Screening
Levels. The presence of compounds such as ethyl acetate, isopropanol, TCE, and
1,2,4-trimethylbenzene (primary drivers of potential health risk at the Site) in indoor air
samples collected at the Site are likely partially attributable to off-gassing from building
materials during prior construction and recent renovation activities, cleaning products, or
the presence of background concentrations.
Commercial Space 12 is located on the ground floor of the Centro Railyard Apartments
building. The HVAC units in this space are separate from the HVAC units on the upper
floor residential spaces. Therefore, direct air exchange between the ground floor and
upper floors is not likely to occur, and the samples collected in this space are
representative of commercial conditions and are likely not representative of the upper
floor residential conditions.
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H&H performed cumulative risk calculations for a non-residential exposure scenario
using April and August 2021 indoor air data. The calculated carcinogenic and non-
carcinogenic risks using both datasets are below the DEQ acceptable level of 1 x 10-4 for
the cumulative LICR and 1.0 for the cumulative HI.
Results of the indoor air sampling activities indicate that the detected concentrations in the newly
upfitted tenant space do not appear to cause an unacceptable risk to current and anticipated future
commercial-use occupants within Commercial Space 12 on the ground floor Centro Railyard
Apartments. An additional ground floor indoor air sampling event across the ground floor
commercial and amenity spaces is proposed for first quarter 2022, and a summary of the indoor
air sampling and results will be reported to DEQ.
Table 1
Summary of Chemicals on Safety Data Sheets
HD Supply Brownfields Property/Centro Railyard Apartments
1425 Winnifred Street
Charlotte, North Carolina
H&H Job No. CTT-001
Product Compound CAS No.
2-Butox ethanol 111-76-2
Eth l Alcohol 64-17-5
Butane 106-97-8
Propane 74-98-6
Limestone 1317-65-3
Meth lvin l bis N-th lacetamido silane 87855-59-2
Dimethyl, methylhydrogen siloxane, dehydrogenated, reaction
with hydroxydiethylamine 68953-53-4
Ma nesium carbonate 546-93-0
Quart 14808-60-7
N-eth lacetamide 625-50-3
Octameth lc clotetrasiloxane 556-67-2
Impurities in meth lvin lbis N-eth lacetamido silane Not assi ned
Titanium dioxide 13463-67-7
Carbon Black 1333-86-4
cetone 67-64-1
Ethox lated Alcohol 68439-46-3
Water 7732-18-5
Sodium Citrate 68-04-2
Tetrasodium N,N-bis carbox meth l -L-lutamate 51981-21-6
Sodium Carbonate 497-19-8
Citric Acid 77-92-9
Isothiazolinone mixture 55965-84-9
Fra rance Proprietar Mixture
Colorant Proprietar Mixture
liphatic H drocarbon 64742-47-8
No Chemcial Component
Proprietar Calcium Compound
Proprietar Aluminum H drate
Proprietar Terephthalic Acid Ester
Proprietary Triphenyl Phosphate (is a byproduct of the above
com ound
Proprietar Or anophosphorus Compound
Proprietary Petroleum Alkylate (contains less than 0.1%
benzene
Proprietar Pol ether Pol ol
Vin ltrimethox silane 2768-02-7
Titanium Dioxide 13463-67-7
Isophorone Diisoc anate 4098-71-9
Proprietar Copol mer
luminum Trih drate 21645-51-2
Titanium Dioxide 13463-67-7
Cr stalline Silica 14808-60-7
Iron 7439-89-6
Carbon 7440-44-0
Ma anese 7439-96-5
Phosphorus 7723-14-0
Sulfur 7704-34-9
Copper 7440-02-0
Nickel 7440-02-0
Chromium 7440-47-3
Mol bdenum 7439-98-7
Vanadium 7440-62-2
Niobium Columbium 7440-03-1
Titanium 7440-32-6
Galvanized (Per ASTM A653)
Zinc 7440-66-6
luminum 7429-90-5
Nickel (Ni)
ZnNi EG 7440-02-0
Galvalume Mixture
Zincroplex Coatin Mixture
Zincrometal SL Mixture
Barium Chromate 10-2944-03
Chem Phos 2007 Varies
Chem Treat - Chromium VI 18540-29-9
Epox Resin Varies
Phosphate Treat 7664-38-2
Silicates Varies
Zinc Potassium Chromate 11103-86-9
DiamnondPlus Mixture
Calcium Sulfate Dih drate 13397-24-5
Cellulose 9004-34-6
Mixture-calcium, aluminum silicates, amorphous silica 65997-17-3
Glass, oxide, chemicals 65997-17-3
Petroleum asphalt, oxidized 64742-93-4
ceric acid, vin l ester, pol mer 9003-20-7
Green Binder Proprietar
cetic acid ethen l ester, pol mer with thene 24937-78-8
Mineral oil, petroleum distillates, solvent-dewaxed
heavy paraffinic (severe solvent-refiningand/or
h drotreatment
64742-65-0
Hydrotreated heeavy paraffinic petroleum distillate
hi hl refined 64742-54-7
Fiber lass wool 65997-17-3
Fiber lass wool 65997-17-3
Glazing Products
Firestop Products
Framing_and Drywall Products
Fiberglass Insulation Made with PureFiber Technology
Faced Products
Fiberglass Insulation Made with PureFiber Technology
Unfaced Products
Coated Steel Sheet
Base Metal Coating
Other Coatings
Gypsum Board Products
Commercial Insulation-Sustainable Instulation CT10161-4
WD-40 Multi-Use Product Aerosol
Bonded Mineral Wool
SpecSeal® Fast Tack Firestop Spray
SpecSeal® AS200 Elastomeric Spray
CRL S 50 Sprayway Glass Cleaner
Dow Corning® 790 Silicone Building Sealant Gray
Dow Corning® 995 Silicone Structural Sealant, Black
Klean-Strip Acetone
Simple Green Industrial Cleaner & Degreaser
S:\AAA-Master Projects\Centro CityWorks CCW\CCW-002 RailYard VMP\Occupancy Request\Tables\SDS for Nathan
3/23/2020
Table 1 (Page 1 of 4)
Hart & Hickman, PC
Table 1
Summary of Chemicals on Safety Data SheetsHD Supply Brownfields Property/Centro Railyard Apartments
1425 Winnifred Street
Charlotte, North Carolina
H&H Job No. FZR-001
Product Compound CAS No.
Silicon Dioxide 14808-60-7
Calcium Carbonate 1317-65-3
Mixture-calcium, aluminum silicates 65997-15-1
Mixture-silicates, aluminates 68131-74-8
Mixture-calcium, aluminates 65997-16-2
Mixture-calcium, aluminum silicates, amorphous silica 65997-17-3
Calcium H droxide 1305-62-0
Wood None
Monosodium Phosphate
sodium Phosphate (monobasic)
Sodium Dihydrogen Phospate
Dih dro en Sodium Phos ate
7558-80-7
Sodium Tetraborate Decahydrate
10 Mol Bora 1303-96-4
Boric Acid 10043-35-3
Urea Phophate 4861-19-2
Tetrachloroisophthalonitrile
Chlorothalonil
Daconil
1897-45-6
5-Chloro-2-methly-4-Isothiazolin-3-one
meth lisothiazolinone 2682-20-4
Magnesium Nitrate 10377-60-3
luminum oxide 1344-28-1
silicon carbide 409-21-2
zirconium VI oxide 1314-3-4
p rite FeS2 1309-36-0
cr olite 15096-52-3
calcium oxide 1305-78-8
potassiumtetrafluoroborate 14075-53-7
calcium fluoride 7789-75-5
baruim sulfate 7727-43-7
Calcium Carbonate 471-34-1
potassium sulfate 7778-80-5
raphite 7782-42-5
trisodium hexafluoroaluminate 13775-53-6
Fiber lass wool 65997-17-3
l cerol trinitrate 55-63-0
lead st phnate 15245-44-0
Barium nitrate 10022-31-8
diphen lamine 122-39-4
Tetrazen 109-27-3
Nitro l cerin 00055-63-0
Nitrocellulose 09004-70-0
Lead st phnate 15245-44-0
Barium nitrate 10022-31-8
Tetracene 00109-27-3
Propane-1, 2-diol 57-55-6
Titanium dioxide 13463-67-7
Titanium dioxide 13463-67-7
2-2-butox ethox ethanol 112-34-5
2-2-methox ethox ethanol 111-77-3
Tetrah drofuran THF 109-99-9
Meth l Eth l Ketone MEK 78-93-3
cetone 67-64-1
C clohexanone 108-94-1
Calcium Carbonate 1317-65-3
Water 7732-18-5
Pol mer NJTS Re . No. 04499600-7314 Trade Secret*
Zinc Borate 2335 138265-88-0
Sodium Silicate 1344-09-8
2-Aminoisobutanol 124-68-5
Quartz Silica 14808-60-7
CUMENE HYDROPEROXIDE 80-15-9
X lenes 1330-20-7
Resins, 2-meth l-1-propanol 78-83-1
Bronze Powder 7440-66-6, 7440-50-8
Mineral Oil Confidential
Talc 14807-96-6
Kaolin 1332-58-7
Mica 12001-26-2
Titanium Dioxide 13463-67-7
Pol tetrafluoroeth lene 9002-84-0
Proprietar Lubricit Enhancers TSRN 0210
Water 7782-13-5
Mixed Sodium & Potassium Salts of tall oil (soap)68606-06-4 EINECS 271-
723-9
Carbon 7440-44-0
Chromium Cr 7440-47-3
Copper Cu 7440-50-8
Iron Fe 7439-89-6
Man anese Mn 7439-96-5
Nickel Ni 7440-02-0
Silicon Si 7440-21-3
Tin Sn 7440-31-5
TFP-500 RED Low VOC Cement for CPVC Plastic Pipe
3M FireBarrier™ Sealant IC 15 WB+
Permabond LH050
Uni- Paint Markers Fine, Medium, Bold
RIDGID Dark Thread Cutting Oil
TUF-GLIDE™ Thread Seal Paste with PTFE
Thread Tape PTFE Tape
Tuf-Lube™ Coupling Grease
Plumbing Products
GRAY IRON CASTINGS
Sprinkler and Fire Surpression
PermaBase Brand Cement Board Products
Pyro-Guard
AB-Z. AC-D, AF-D
DX-Cartridge
Safety Boosters
hilti Forestop Acrylic Sealant CFS-S ACR CP 606
Paint Products
Finish Paint (1412-0100G Pittsburg Paints Ultra-Hide 150
Interior Eggshell White
Hollow Metal (Pitt-Tech Plus SG 4216 HP White Base)
S:\AAA-Master Projects\Centro CityWorks CCW\CCW-002 RailYard VMP\Occupancy Request\Tables\SDS for Nathan
3/23/2020
Table 1 (Page 2 of 4)
Hart & Hickman, PC
Table 1Summary of Chemicals on Safety Data Sheets
HD Supply Brownfields Property/Centro Railyard Apartments
1425 Winnifred Street
Charlotte, North CarolinaH&H Job No. FZR-001
Product Compound CAS No.
Mixed sodium and potassium salts of tall oil (soap)68606-06-4 EINECS 271-
723-9
Pol vin l chloride 9002-86-2
Titanium dioxide 13463-67-7
Tetrah drofuran THF 109-99-9
Meth l Eth l Ketone MEK 78-93-3
C clohexanone 108-94-1
cetone 67-64-1
Chlorinated pol vin l chloride 68648-82-8
Titanium dioxide 13463-67-7
Tetrah drofuran THF 109-99-9
Meth l Eth l Ketone MEK 78-93-3
C clohexanone 108-94-1
Ethanol 64-17-5
Distillates petroleum , h drotreated li ht naphthenic 64742-53-6
Distillates petroleum , h drotreated heav naphthenic 64742-52-5
PTFE 9002-84-0
No hazardous components
Slack Wa 64742-61-6
Propane -1,2 -diol 57-55-6
Water 7732-18-5
cetone 67-64-1
Toluene 108-88-3
Propane 74-98-6
Butane 106-97-8
Medium Aromatic H drocarbons 64742-94-5
Naphthalene 91-20-3
Limestone 1317-65-3
Distillates petroleum , h drotreated heav naphthenic 64742-52-5
Cr stalline silica Quartz 14808-60-7
Copper 7440-50-8
Silver 7440-22-4
Tin 7440-31-5
Petrolatum 8009-03-8
Zinc chloride 7646-85-7
Water 7732-18-5
mmonium chloride 12125-02-9
propane-1,2-diol 57-55-6
HT stone wool 90%287922-11-6
prop lene 115-07-1
meth l acet lene 74-99-7
1,2-propadiene 463-49-0
isobutane 75-28-5
N-Butane 106-97-8
Propane 74-98-6
acet lene 74-86-2
ox en 7782-44-7
CARBON 7440-44-0
IRON 7439-89-6
MANGANESE 7439-96-5
SILICON 7440-21-3
COPPER 7440-50-8
Graphite 7782-42-5
Man anese Dioxide 1313-13-9
Potassium H droxide 1310-58-3
Zinc 7440-66-6
Cadmium
as cadmium metal 7440-43-9
as cadmium oxide 1306-19-0
as cadmium h droxide 21041-95-2
Cobalt
as cobalt metal 7440-48-4
as cobalt oxide 1307-96-6
as cobalt h droxide 21041-93-0
Lithium H droxide 1310-65-2
Nickel
as nickel metal 7440-02-0
as nickel oxide 1313-99-1
as nickel h droxide 12054-48-7
Potassium H droxide 1310-58-3
Sodium H droxide 1310-73-2
Fuel, diesel 68476-34-6
Distillates petroleum , h drodesulfurized middle 64742-80-9
Distillates petroleum , strai ht-run middle 64741-44-2
Distillates petroleum , li ht catal tic cracked 64741-59-9
Kerosene 8008-20-6
Kerosine petroleum , h drodesulfurized 64742-81-0
Naphthalene 91-20-3
Hilti Speed Plug CP 777
MAPP GAS (Petroleum Gas, MAPD)
Acetylene
Oxygen
RAD64001571
Eveready / Energizer Battery
Oatey Leak Detector
KRYLON® Lacquer Spray Clear Gloss
Oatey Plumber's Putty
Silver-Copper-Tin Brazing Alloys
Oatey No. 5 Paste Flux
ENERGIZER ACCU Rechargeable Battery
DIESEL FUEL No. 2
FS-ONE MAX Hilti Firestop Filler Mastic CFS-FIL
WELD-ON® P-68™ /Weld-On® 700™/WELD-ON®
702™/Weld-On® 710™/WELD-ON® 711™/WELD-ON®
717™/WELD-ON® 719™ Low VOC PVC Plastic Pipe
Cements
CPVC Pipe and Fittings
WELD-ON® 713™/WELD-ON® 714™/WELD-ON®
724™/WELD-ON® 729™ Low VOC Cement for CPVC
Plastic Pipe
Slic-Tite® Paste with PTFE
PIPE THREAD SEAL TAPE; Slic-tite® PTFE PIPE THREAD
TAPE; CORD OF PTFE
Harvey Wax Bowl Rings
PVC Pipe and Fittings
Ease On Water Dispersible Pipe Joint Lubricant
S:\AAA-Master Projects\Centro CityWorks CCW\CCW-002 RailYard VMP\Occupancy Request\Tables\SDS for Nathan
3/23/2020
Table 1 (Page 3 of 4)
Hart & Hickman, PC
Table 1Summary of Chemicals on Safety Data Sheets
HD Supply Brownfields Property/Centro Railyard Apartments
1425 Winnifred Street
Charlotte, North CarolinaH&H Job No. FZR-001
Product Compound CAS No.
Gasoline 86290-81-5
X lene 1330-20-7
Toluene 108-88-3
Eth l Alcohol 64-17-5
n-Hexane 110-54-3
Benzene 71-43-2
1,2,4-Trimeth lbenzene 95-63-6
Eth lbenzene 100-41-4
Naphthalene 91-20-3
Lubricant Base Oil (Petroleum) Highly refined mineral
oils C15-C50 Various
2-C cle En ine Oil Additives Mixture Proprietar
Lead 7436-92-1
ntimon 7440-36-0
Iron Fe 7439-89-6
Copper Cu 7440-50-8
Zinc 7440-66-6
Nitrocellulose 9004-70-0
Nitro l cerin 55-63-0
Lead st phnate 15245-44-0
1-butane but lene 106-98-9
propene prop lene 115-07-1
Eth lene dimethacr late 97-90-5
Methacr lic acid, monoester with Propan-1, -diole 27813-02-1
Quartz 14808-60-7
1,1'-p-Tol limino dipropan-2-ol 38668-48-3
Dibenzo l peroxide 94-36-0
Eth lhex l benzoate 5444-75-7
Quart 14808-60-7
Calcium Sulfate, Hemih drate 26499-65-0
Vermiculite 1318-00-9
Cellulose 065996-61-4
Calcium Carbonate 1317-65-3
Cr stalline Silica 14808-60-7
mmonium Pol phosphate 68333-79-9
Pentaer thritol 115-77-5
Melamine 108-78-1
Titanium Dioxide 13463-67-7
Glass wool fibers 65997-17-3
mmonium Pol phosphate 68333-79-9
Pentaer thritol 115-77-5
Melamine 108-78-1
Titanium Dioxide 13463-67-7
Glass wool fibers 65997-17-3
luminum Trih droxide 21645-51-2
Eth lene Gl col, But l Ether 111-76-2
mmonium Pol phosphate 68333-79-9
Pentaer thritol 115-77-5
Melamine 108-78-1
Titanium Dioxide 13463-67-7
Glass wool fibers 65997-17-3
luminum Trih droxide 21645-51-2
Eth lene Gl col, But l Ether 111-76-2
4,4’-Isoprop lidenediphenol-Epichloroh drin 25068-38-6
lk l Gl cid l Ether 68609-97-2
Kaolin 1332-58-7
Titanium Dioxide 13463-67-7
Pol amine Pol mer 61790-69-0
Tetraethylene Pentamine 112-57-2
CAFCO® SprayFilm® WB 5
CAFCO® SprayFilm® WB 4
CAFCO® SprayFilm® WB 3
CAFCO® SprayFilm® Topseal® Part A
CAFCO® SprayFilm® Topseal® Part B
Cartridges for tools, blank
Cordless Fuel Cell
AC 100+, Comp A
AC100+, Comp B
Fire Retardant and Insulation Products
CAFCO® 300 HS
Western Refining Gasoline (All Grades)
STIHL HO (High Performance) 2-Cycle Engine Oil
Electrical Supplies
2%-4% Antimonial Lead used in anchors:calk-in (anchor
sleeve) fiberplug (liner), SCRU-lean (anchor Body)
S:\AAA-Master Projects\Centro CityWorks CCW\CCW-002 RailYard VMP\Occupancy Request\Tables\SDS for Nathan
3/23/2020
Table 1 (Page 4 of 4)
Hart & Hickman, PC
Table 2
Site-Specific Indoor Air VOC List
HD Supply Brownfields Property/Centro Railyard Apartments
1425 Winnifred Street
Charlotte, North Carolina
H&H Job No. CTT-001
Select VOCs by TO-15
Acetone
Benzene
1,3-Butadiene
2-Butanone
Carbon Disulfide
Carbon Tetrachloride
Chloroethane
Chloroform
Chloromethane
Cyclohexane
1,3-Dichlorobenzene
Dichlorodifluoromethane
1,2-Dichloropropane
Ethanol
Ethyl Acetate
Ethylbenzene
4-Ethyltoluene
Heptane
Hexane
Isopropanol
Methylene Chloride
4-Methyl-2-pentanone
Naphthalene
Propene
Styrene
Tetrachloroethene
Toluene
Trichloroethene
Trichlorofluoromethane
1,1,2-Trichloro-1,2,2-trifluoroethane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Chloride
m&p-Xylene
o-Xylene
M:\AAA-Master Projects\Collett Capital - CTT\CTT-001 Centro Railyard\Post Occupancy IAS\Tables\Table 2 - Site-Specific Indoor Air VOC List.xlsm
5/5/2021
Table 2 (Page 1 of 1)
Hart & Hickman, PC
Table 3
Summary of Indoor Air Analytical Results
Centro Railyard Apartments
1425 Winnifred Street
Charlotte, North Carolina
H&H Job No. CTT-001
Sample ID
Sample Date 4/7/2021 8/24/2021
Location
Units
Select VOCs (TO-15)
Acetone 149 146 184 172 132 252 6,500 27,000
Benzene 1.27 J 1.32 J 1.95 1.91 0.645 J 0.505 J 0.36 1.6
1,3-Butadiene <0.195 <0.195 <0.328 <0.328 <0.195 <0.328 0.094 0.41
2-Butanone (MEK) 56.7 50.0 20.5 21.7 42.6 13.8 1,000 4,400
Carbon disulfide <1.56 <1.56 1.08 J 1.10 J <1.56 <0.0608 150 610
Carbon tetrachloride <0.239 <0.239 0.717 J 0.742 J <0.239 <0.155 0.47 2.0
Chloroethane <0.396 <0.396 <0.164 <0.164 <0.396 <0.164 2,100 8,800
Chloroform 1.03 J 1.06 J 2.59 2.53 <0.264 <0.0864 0.12 0.53
Chloromethane 2.25 <0.268 2.06 2.12 <0.268 1.22 19 79
Cyclohexane 1.43 J 1.38 J <0.161 <0.161 <0.861 <0.161 1,300 5,300
1,3-Dichlorobenzene <0.217 <0.217 <0.174 <0.174 <0.217 <0.174 NE NE
Dichlorodifluoromethane 5.87 5.51 <0.134 <0.134 5.95 3.13 21 88
1,2-Dichloropropane <0.402 <0.402 <0.205 <0.205 <0.402 <0.205 0.76 3.3
Ethanol 523 525 817 780 50.8 68.2 NE NE
Ethyl Acetate 7.78 7.12 21.1 22.0 5.30 <0.136 15 61
Ethylbenzene 1.45 J 1.52 J 2.94 3.00 <0.187 <0.106 1.1 4.9
4-Ethyltoluene <0.266 <0.266 2.99 7.76 <0.266 <0.128 NE NE
Heptane 2.11 1.89 J 8.98 8.96 <0.193 <0.143 83 350
Hexane <0.254 <0.254 <0.0472 <0.0472 <0.254 <0.0472 150 610
Methylene Chloride 3.38 3.47 2.37 2.51 <0.383 1.29 J 100 530
4-Methyl-2-pentanone (MIBK) 4.99 4.85 0.963 J 1.04 J 6.43 <0.121 630 2,600
Naphthalene <0.386 <0.386 <0.183 <0.183 <0.386 <0.183 0.083 0.36
Isopropyl Alcohol 75.0 J 77.9 J 99.5 90.0 J 30.0 10.0 42 180
Propylene <0.139 <0.139 <0.242 <0.242 12.1 <0.242 630 2,600
Styrene 2.19 2.39 76.2 76.3 <0.149 <0.124 210 880
Tetrachloroethylene <0.441 1.91 J 1.58 J 1.96 J <0.441 <0.181 8.3 35
Toluene 43.0 43.0 24.5 24.5 4.98 2.48 1,000 4,400
Trichloroethylene <0.274 <0.274 1.39 J 1.46 J <0.274 <0.199 0.42 1.8
Trichlorofluoromethane <0.433 <0.433 1.88 J 1.83 J <0.433 2.29 J NE NE
1,1,2-Trichloro-1,2,2-trifluoroethane <0.529 <0.529 0.644 J 0.613 J <0.529 <0.561 1,000 4,400
1,2,4-Trimethylbenzene 43.8 54.4 17.7 16.3 <0.295 <0.110 13 53
1,3,5-Trimethylbenzene 16.1 19.9 5.76 4.16 <0.261 <0.236 13 53
Vinyl chloride <0.282 <0.282 <0.127 <0.127 <0.282 <0.127 0.17 2.8
m&p-Xylene 5.52 J 5.71 7.66 7.76 2.95 J <0.217 21 88
o-Xylene 2.42 2.59 3.53 3.63 <0.182 <0.157 21 88
LICR (Residential)-- --
Non-Carcinogenic HI (Residential)-- --
LICR (Non-Residential)-- --
Non-Carcinogenic HI (Non-Residential)-- --
Notes:
1) NC Department of Environmental Quality (DEQ) Division of Waste Management (DWM) Indoor Air Screening Levels (IASLs) dated June 2021 and based upon TCR = 1 x 10-6 and THQ = 0.2.
2) Health risks calculated using the NC DEQ DWM Cumulative Risk Calculator dated June 2021.
Only compounds included in the Site-specific list of compounds are included.
Compound concentrations are reported in micrograms per cubic meter (μg/m3).
Compound concentrations are reported to the laboratory method detection limits.
Samples were collected into individually-certified 6-L Summa canisters and analyzed by EPA Method TO-15.
Bold values exceed Residential IASLs or the DEQ acceptable Hazard Index.
Underlined values exceed Non-Residential IASLs.
VOCs = Volatile Organic Compounds; NE = Not Established.
TCR = Target Cancer Risk; THQ = Target Hazard Quotient; LICR = Lifetime Incremental Carcinogenic Risk; HI = Hazard Index.
Cumulative LICR and HI calculated using the higest detection of each compound in the indoor air samples and duplicate samples.
J = Estimated concentration above the laboratory method detection limit but below the laboratory reporting limit.
<1.0
<1.0 x 10-4
<1.0
<1.0 x 10-4
0.53
7.6 x 10-6
2.2
3.4 x 10-5
0.47
3.2 x 10-6
2.0
1.4 x 10-5
IAS-1 / IAS-DUP BAS-1
4/7/2021
µg/m3
BackgroundCommercial Space 12
Non-Residential
IASLs(1)8/24/2021 Residential IASLs(1)
DEQ Risk Calculations(2)Acceptable Risk Levels
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Collett Capital - CTT/CTT-001 Centro Railyard/VIMS Upfit Inspection and Sampling Report Revision1/Tables/Table 3 - Analytical Data.xlsx
11/28/2021
Table 3
Hart & Hickman, PC
Table 4
Summary of Sub-Slab Vapor Analytical Results
Centro Railyard Apartments
1425 Winnifred Street
Charlotte, North Carolina
H&H Job No. CTT-001
Sample ID
Sample Date
Location
Units
Select VOCs (TO-15)
Acetone 19,700 17,600 220,000 2,700,000
Benzene <1.46 <1.46 12 160
1,3-Butadiene <6.53 <6.53 3.1 41
2-Butanone (MEK) 3,870 3,730 35,000 440,000
Carbon disulfide 16.6 J 16.5 J 4,900 61,000
Carbon tetrachloride <3.10 <3.10 16 200
Chloroethane <3.28 <3.28 70,000 880,000
Chloroform <1.73 <1.73 4.1 53
Chloromethane 14.5 J 13.7 J 630 7,900
Cyclohexane <3.22 <3.22 42,000 530,000
1,3-Dichlorobenzene <3.48 <3.48 NE NE
Dichlorodifluoromethane <2.68 <2.68 700 8,800
1,2-Dichloropropane <4.10 <4.10 25 330
Ethanol 188 184 NE NE
Ethyl Acetate <2.72 <2.72 490 6,100
Ethylbenzene 10.2 J 10.4 J 37 490
4-Ethyltoluene 3,530 3,440 NE NE
Heptane <2.86 <2.86 2,800 35,000
Hexane <0.943 <0.943 4,900 61,000
Methylene Chloride <9.75 <9.75 3,400 53,000
4-Methyl-2-pentanone (MIBK) 29.0 J 29.0 J 21,000 260,000
Naphthalene <3.66 <3.66 2.8 36
Isopropyl Alchohol 125 125 1,400 18,000
Propylene <4.84 <4.84 21,000 260,000
Styrene 160 156 7,000 88,000
Tetrachloroethylene <3.62 <3.62 280 3,500
Toluene 9.04 J 9.27 J 35,000 440,000
Trichloroethylene <3.98 <3.98 14 180
Trichlorofluoromethane <2.60 <2.60 NE NE
1,1,2-Trichloro-1,2,2-trifluoroethane <11.2 <11.2 35,000 440,000
1,2,4-Trimethylbenzene 10,400 9,980 420 5,300
1,3,5-Trimethylbenzene 3,530 3,460 420 5,300
Vinyl chloride <2.54 <2.54 5.60 280
m&p-Xylene 102 J 101 J 700 8,800
o-Xylene 490 476 700 8,800
LICR (Residential)
Non-Carcinogenic HI (Residential)
LICR (Non-Residential)
Non-Carcinogenic HI (Non-Residentiall)
Notes:
1) NC Department of Environmental Quality (DEQ) Division of Waste Management (DWM) Sub-slab and Exterior Soil Gas Screening Levels (SGSLs)
dated June 2021 and based upon TCR = 1 x 10-6 and THQ = 0.2.
2) Risk calculations performed using the NC DEQ DWM Cumulative Risk Calculator dated June 2021.
Only compounds included in the site-specific list of compounds are included.
Compound concentrations are reported in micrograms per cubic meter (μg/m3).
Compound concentrations are reported to the laboratory method detection limits.
Laboratory analytical method is shown in parentheses.
Bold values exceed Residential IASLs.
Underlined values exceed Non-Residential IASLs.
VOCs = Volatile Organic Compounds; NE = Not Established.
TCR = Target Cancer Risk; THQ = Target Hazard Quotient; LICR = Lifetime Incremental Carcinogenic Risk; HI = Hazard Index.
Cumulative LICR and HI calculated using the highest detection of each compound in sample SS-OP-1 and SS-DUP.
J = Estimated concentration above the laboratory method detection limit but below the laboratory reporting limit.
2.1 x 10-8 <1.0 x 10-4
0.56 <1.0
DEQ Risk Calculations(2)Acceptable Risk Levels
2.8 x 10-7 <1.0 x 10-4
7.0 <1.0
µg/m3
SS-OP-1 / SS-DUP
Residential SGSLs(1)Non-Residential
SGSLs(1)8/24/2021
Commercial Space 12
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Collett Capital - CTT/CTT-001 Centro Railyard/VIMS Upfit Inspection and Sampling Report Revision1/Tables/Table 3 - Analytical Data.xlsx11/28/2021
Table 4
Hart & Hickman, PC
USGS The National Map: National Boundaries Dataset, 3DEP ElevationProgram, Geographic Names Information System, National HydrographyDataset, National Land Cover Database, National Structures Dataset,and National Transportation Dataset; USGS Global Ecosystems; U.S.Census Bureau TIGER/Line data; USFS Road Data; Natural Earth Data;U.S. Department of State Humanitarian Information Unit; and NOAANational Centers for Environmental Information, U.S. Coastal ReliefModel. Data refreshed May, 2020.
SITE LOCATION MAP
CENTRO RAILYARD1425 WINNIFRED STREETCHARLOTTE, NORTH CAROLINA
DATE: 9-15-21
JOB NO: CTT.001
REVISION NO: 0
FIGURE NO: 1
2923 South Tryon Street - Suite 100Charlotte, North Carolina 28203704-586-0007 (p) 704-586-0373 (f)License # C-1269 / # C-245 Geology
TITLE
PROJECT
0 2,000 4,000
SCALE IN FEET
SITE
Path: \\HHFS01\Redirectedfolders\sperry\My Documents\ArcGIS\PROJECTS\CTT-001\Figure-1.mxd
N
U.S.G.S. QUADRANGLE MAP
CHARLOTTE EAST, NORTH CAROLINA 2013
QUADRANGLE7.5 MINUTE SERIES (TOPOGRAPHIC)
VACANT OFFICE SPACE
(120 W. BLAND STREET)
DMC BUYERS SCRAP METAL
AND RECYCLING
(130 W. BLAND STREET)
RESIDENTIAL CONDO
(204 W. BLAND STREET)
APPROXIMATE LOCATION
OF FORMER DRYCLEANER
MULTI-TENANT
COMMERCIAL BUILDING
(1426 S. TRYON STREET &
105-125 WINONA STREET)
MULTI-TENANT
COMMERCIAL BUILDING
(1422-1438 WINNIFRED STREET)
COMMERCIAL BUILDING
(1402 WINNIFRED STREET)
S. T
R
Y
O
N
S
T
R
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E
T
W. B
L
A
N
D
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T
WIN
N
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WINO
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A
S
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E
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1425 WINNIFRED STREET
FORMER HEATING
OIL UST
MULTI-TENANT COMMERCIAL BUILDINGS
(1414 & 1422 S. TRYON STREET)
HARKER INTERIORS
(122 W. BLAND STREET)
TRASH ROOM
PAD-MOUNTED
TRANSFORMERS
PAD-MOUNTED
TRANSFORMERS
ABOVEGROUND
STORAGE TANK
(ON GROUND LEVEL)
REVISION NO. 0
JOB NO. CTT.001
DATE: 9-15-21
FIGURE NO. 2
CENTRO RAILYARD
1425 WINNIFRED STREET
CHARLOTTE, NORTH CAROLINA
SITE MAP
LEGEND
SITE PROPERTY BOUNDARY
PARCEL BOUNDARY LINE
EXTENT OF VAPOR BARRIER AND
PASSIVE VAPOR INTRUSION
MITIGATION SYSTEM
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
NOTES
1.BASE DATA OBTAINED FROM MECKLENBURG
COUNTY GIS, 2020.
2.AERIAL IMAGERY OBTAINED FROM NC
ONEMAPS GEOGRAPHIC DATA SERVICE, 2019.
S:
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UP
UP
DN
STAIR #2
LOBBY
ELEC.
COMMERCIAL
07
COMMERCIAL
08
COMMERCIAL
09
COMMERCIAL
10
COMMERCIAL
11
COMMERCIAL
12
COMMERCIAL
13
COMMERCIAL
14
COMMERCIAL
15
ELECTRICAL
PUMP
ELEV
#2
VESTIBULE STORAGE
DATA
MECH.
WOMEN'S
MEN'S
750.50'
F-1
F-2
OP-2
SS-OP-1/SS-DUP
OP-3
OP-4
OP-5
IAS-1/IAS-DUP
BAS-1
COMMERCIACIA
121
UP UP
UP
UP DN
UP
STAIR #1 STAIR #2
TRASH
FITNESS
LEASING
COMMERCIAL01
COMMERCIAL02 COMMERCIAL03 COMMERCIAL04 COMMERCIAL05 COMMERCIAL06
PACKAGE
MAIL LOBBY
ELEC.
COMMERCIAL07 COMMERCIAL08 COMMERCIAL09 COMMERCIAL10 COMMERCIAL11 COMMERCIAL12
COMMERCIAL13
COMMERCIAL14
COMMERCIAL15
ELECTRICAL
PUMP
ELEV#1 ELEV#2
VESTIBULE VESTIBULE
DATA
MECH.
STORAGE
DATA
MECH.
WOMEN'S
MEN'S
WOMEN'S
MEN'S
750.50'750.50'
F-1
F-2
OP-2
SS-OP-1/SS-DUP
OP-3
OP-4
OP-5
IAS-1/IAS-DUP
BAS-1
CIACOMMERCIACICO12
REVISION NO. 0
JOB NO. CTT-001
DATE: 9-15-21
FIGURE NO. 3
CENTRO RAILYARD
1425 WINNIFRED STREET
CHARLOTTE, NORTH CAROLINA
SAMPLE LOCATION MAP
LEGEND
EXTENT OF VAPOR BARRIER
SLOTTED 3" DIA SCH 40 PVC PIPE
SOLID SCH 40 PVC PIPE (3" OR 4" DIA, REFER
TO VIMS LAYOUT)
LOCATION OF VERTICAL RISER AND
APPROXIMATE LOCATION OF TURBINE FAN
ON ROOFTOP
LOCATION OF PRESSURE MONITORING
POINT
LOCATION OF INDOOR AIR SAMPLE
LOCATION OF BACKGROUND AIR SAMPLE
SUB-SLAB VAPOR SAMPLE LOCATION
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 Geology
NOTES:
1. LAYOUT SHOWS GROUND FLOOR OF SOUTHWESTERN
APARTMENTS ONLY.
2. VIMS MODIFICATIONS TO SUB-SLAB PIPING AND VAPOR
BARRIER IN AREA OF COMMERCIAL SPACE 12
DOCUMENTED IN "REQUEST FOR VIMP MODIFICATIONS"
DATED MARCH 1, 2021.
3. SAMPLES COLLECTED AUGUST 24, 2021.
SEE NOTE 2
S:
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Appendix A
VIMS As-Built Drawing (VM-1)
UP
STAIR #2
COMMERCIAL
06
PACKAGE
MAIL
LOBBY
ELEC.
COMMERCIAL
07
COMMERCIAL
08
COMMERCIAL
09
COMMERCIAL
10
COMMERCIAL
11
COMMERCIAL
12
COMMERCIAL
13
COMMERCIAL
14
COMMERCIAL
15
ELECTRICAL
PUMP
ELEV
#2
VESTIBULE STORAGE
DATA
MECH.
WOMEN'S
MEN'SF-1
F-2
OP-2
OP-1
OP-3
OP-4
OP-5
VIMS VAPOR LINER AND BASE COURSE (TYP)1
VIMS SLOTTED COLLECTION PIPE (TYP)2
BASE COARSE - CLEAN #57 (SEE SPECIFICATION #1)
MIN 5" THICK BENEATH VMS VAPOR LINER
VAPOR LINER (SEE SPECIFICATION #1)
3" or 4" SCH 40 THREADED FLUSH JOINT SLOTTED PVC
PIPE (0.020" SLOT WIDTH, 1/8" SLOT SPACING) WITH
FILTER SOCK SET WITHIN MIN 5" BASE COURSE.
INSTALL BASE COURSE APPROX. 1-INCH ABOVE AND
BELOW THE COLLECTION PIPE.
VAPOR LINER (SEE SPECIFICATION #1)
CONCRETE FLOOR SLAB
SUB-BASE
SUBBASE
NTS
NTS
VM1
VM1
VMS TURBINE VENTILATOR FAN & EXHAUST (TYPICAL)8
VM1 NTS
TURBINE FAN
(EMPIRE MODEL TV04SS OR APPROVED EQUIVALENT)
ELECTRICAL JUNCTION BOX FOR POTENTIAL
FUTURE VACUUM FAN (RADONAWAY RP145
FAN OR APPROVED EQUIVALENT)
SCH 40 PVC PIPE THROUGH ROOF. REFER
TO VIMS LAYOUT FOR RISER PIPE SIZE. (FOR
3" PIPE, USE 4" TO 3" REDUCER FOR AT FAN
CONNECTION)
FLASHING
ROOFTOP
FLOOR CLEANOUT, ADJUSTABLE,
2" DIA ZURN INDUSTRIES
MODEL #CO2450-PV2 (OR EQUIVALENT)
WITH VANDAL PROOF SCREWS
VAPOR LINER PENETRATION
SEALED TO PIPE PER
MANUFACTURER INSTRUCTIONS
2" PVC 90 DEGREE ELBOW
2" VENT PIPE
PROTECTION SCREEN
BASE COARSE
(SEE SPECIFICATION #1)
VMS PRESSURE MEASURING POINT (2")5
NTSVM1
VERTICAL RISER PIPE AT SLAB PENETRATION
NTS
4"x4"x4" SCH
40 PVC TEE
4" SCH 40 PVC RISER DUCT PIPE
(SEE SPECIFICATION #2 AND #4)
BASE COARSE
(SEE SPECIFICATION #1)
SOLID TO SLOTTED 3" SCH 40
PVC PIPE TRANSITION (SLIP
COUPLING OR THREADED JOINT)
4" SCH 40 PVC SLOTTED PIPE
4
VM1
TENANT WALL
(NOT PRESENT IN ALL LOCATIONS)
SOLID 2" SCH 40 PVC
TYPICAL VMS LINER AT ELEVATOR PIT6
NTSVM1
VAPOR LINER SEALED PER
MANUFACTURER INSTRUCTIONS
VAPOR LINER TERMINATION AT TURNED DOWN SLAB7
NTSVM1
BASE COARSE
(SEE SPECIFICATION #1)
VAPOR LINER SEALED TO
CONCRETE PER MANUFACTURER
INSTRUCTIONS
SUB-BASE
(CREATE SEPARATION OF GRAVEL
BASE AT TURNED DOWN SLAB)
EXPANSION JOINT BETWEEN
SOUTH TOWER AND
CONNECTOR BUILDING
CONCRETE FOOTER
VAPOR LINER SEALED PER
MANUFACTURER INSTRUCTIONS
WATERPROOFING (XYPEX
PARGE COAT) INSTALLED PER
MANUFACTURER INSTRUCTIONS
ELEVATOR SUMP
BASE COARSE
(SEE SPECIFICATION #1)
3" SCH 40 PVC RISER DUCT PIPE. POSITION
RISER WITHIN TENANT STUD WALL ON UPPER
FLOORS (SEE SPECIFICATION #2)
SOLID TO SLOTTED 3" SCH 40 PVC PIPE
TRANSITION (SLIP COUPLING OR
THREADED JOINT)
CMU WALL (GROUND FLOOR)
3" SCH 40 PVC TEE
SLAB STEP (SEE STRUCTURAL PLANS)
3" SCH 40 PVC 90
DEGREE ELBOW
3" SOLID SCH 40 PVC
(SEE SPECIFICATION #5)
VERTICAL RISER AT SLAB STEP (CMU WALL)3
NTSVM1
MECHANICAL ROOM
VAPOR LINER SEALED TO PIPE AND
CONCRETE PER MANUFACTURER
INSTRUCTIONS
PUMP ROOMELECTRICAL ROOM
VIMS PRESSURE MONITORING POINT - DETAIL VIEW
NTSVM1
9
VAPOR LINER PENETRATION SEALED TO
PIPE PER MANUFACTURER INSTRUCTIONS
FINISHED FLOOR VENEER
FINISHED FLOOR SLAB
2" SCH 40 PVC
2" DRAIN EXPANSION TEST PLUG
FLOOR CLEANOUT, ADJUSTABLE,
2" DIA ZURN INDUSTRIES
MODEL #CO2450-PV2 (OR EQUIVALENT)
BASE COARSE
(SEE SPECIFICATION #1)
REFER TO DETAIL 9 FOR
CLEAN-OUT DETAILS
UP UPSTAIR #1 STAIR #2
TRASH
FITNESS
LEASING
COMMERCIAL01
COMMERCIAL
02
COMMERCIAL
03
COMMERCIAL
04
COMMERCIAL
05
COMMERCIAL
06
PACKAGE
MAIL LOBBY
ELEC.
COMMERCIAL
07
COMMERCIAL
08
COMMERCIAL
09
COMMERCIAL
10
COMMERCIAL
11
COMMERCIAL
12
COMMERCIAL13
COMMERCIAL
14
COMMERCIAL
15
ELECTRICAL
PUMP
ELEV#1 ELEV#2
VESTIBULE VESTIBULE
DATA
MECH.
STORAGE
DATA
MECH.
WOMEN'S
MEN'S
WOMEN'S
MEN'S
A
C
O
L
L
E
T
T
C
A
P
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A
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P
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O
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Y
-
B
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O
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N
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L
D
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N
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1
8
0
1
5
-
1
5
-
0
6
0
14
2
5
W
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s
VAPOR INTRUSION MITIGATION PLAN PREPARED BY:
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
H&H NO. CTT-001
VAPOR INTRUSION
MITIGATION
SYSTEM PLAN
MAY 28, 2021
VM-1
LEGEND
SLOTTED 3" or 4" DIA SCHEDULE 40 PVC PIPING
SOLID SCHEDULE 40 PVC PIPING (3" OR 4", REFER TO VIMS LAYOUT)
EXTENT OF VAPOR BARRIER
LOCATION OF TURNED DOWN SLAB
LOCATION OF VERTICAL RISER AND APPROXIMATE LOCATION OF TURBINE FAN ON ROOFTOP
LOCATION OF PRESSURE MEASURING POINT (SEE DETAIL 5).
NOTE:
1.LAYOUT OF GROUND FLOOR SHOWN IN DRAWING. THIS VAPOR MITIGATION SYSTEM IS FOR THE
SOUTHWESTERN APARTMENTS ONLY.
SITE PLAN LAYOUT
1" = 40'
OPEN AIR
PARKING DECK
PROFESSIONAL
APPROVAL
GENERAL LOCATION OF
VAPOR LINER AND EXTENT
OF VIMS
VAPOR INTRUSION MITIGATION SYSTEM (VIMS) LAYOUT
1" = 10'
VAPOR INTRUSION MITIGATION SYSTEM (VIMS) SPECIFICATIONS
1.VIMS VAPOR LINER IS DRAGO WRAP 20-MIL VAPOR BARRIER MANUFACTURED BY STEGO INDUSTRIES LLC (OR
RAVEN INDUSTRIES VAPORBLOCK 20).
THE VAPOR LINER IS INSTALLED AS SPECIFIED HEREIN AND PER MANUFACTURER INSTALLATION
INSTRUCTIONS TO CREATE A CONTINUOUS LINER BELOW GROUND FLOOR SLABS. A MINIMUM 5-INCH THICK
BASE COURSE CONSISTING OF CLEAN #57 IS INSTALLED BENEATH THE VIMS VAPOR LINER.
2.VIMS PIPING IS NOT TRAPPED AND IS SLOPED A MINIMUM OF 18 UNIT VERTICAL IN 12 UNITS HORIZONTAL (1%
SLOPE) TO GRAVITY DRAIN. SOLID SECTIONS OF HORIZONTAL COLLECTION PIPE IS SUPPORTED TO PREVENT PIPE
SAG OR LOW POINTS AND MAINTAIN 1% SLOPE TOWARD SLOTTED SECTIONS. HORIZONTAL COLLECTION PIPE
CONSISTS OF 3" SCH 40 PVC (OR OTHERWISE NOTED IN THE DRAWINGS). PVC PIPE JOINTS ARE CONNECTED
USING PVC SOCKET COUPLINGS AND PVC GLUE. SUB-SLAB SLOTTED VAPOR COLLECTION PIPE ARE THREADED
FLUSH JOINT 3" OR 4" SCH 40 PVC PIPE WITH 0.020" SLOT WIDTH AND 18" SLOT SPACING. FABRIC FILTER SOCK IS
INSTALLED OVER SLOTTED PIPE SECTIONS EXCEPT IN COMMERCIAL SPACE 12 UPFIT AREA.
3.SCH 40 PVC RISER DUCT PIPING IS INSTALLED TO CONNECT EACH SLAB PENETRATION LOCATION TO A ROOFTOP
EXHAUST DISCHARGE POINT WITH TURBINE FAN (SEE SPECIFICATION #4). A 4" RISER PIPE IS INSTALLED AT RISER
LOCATION F-1, AND A 3" RISER PIPE IS INSTALLED AT RISER LOCATION F-2. ABOVE-SLAB RISER DUCT PIPE RUNS
BETWEEN THE SLAB PENETRATION AND THE ROOFTOP EXHAUST DISCHARGE ARE INSTALLED PER APPLICABLE
BUILDING CODE AND AS SPECIFIED IN THE CONSTRUCTION DOCUMENTS AND DRAWINGS.
4.SCH 40 PVC RISER DUCT PIPING EXTENDS IN A VERTICAL ORIENTATION THROUGH THE BUILDING ROOF AND
TERMINATE A MINIMUM OF 2 FT ABOVE THE BUILDING ROOF LINE. EMPIRE MODEL TV04SS STAINLESS STEEL
TURBINE VENTILATOR FANS (OR APPROVED ALTERNATE) ARE INSTALLED ON THE EXHAUST DISCHARGE END OF
EACH RISER DUCT PIPE. EXHAUST DISCHARGE LOCATIONS ARE A MINIMUM OF 10 FT FROM ANY OPERABLE
OPENING OR AIR INTAKE INTO THE BUILDING. AN ELECTRICAL JUNCTION BOX (120V, 60Hz AC REQUIRED) IS
INSTALLED NEAR THE FAN LOCATION ON THE ROOFTOP FOR CONVERSION TO ELECTRIC FANS, IF REQUIRED. ALL
FUTURE WIRING AND ELECTRICAL TO BE INSTALLED WITH APPLICABLE ELECTRICAL CODES.
5.ABOVE-SLAB ACCESSIBLE RISER DUCT PIPING IS PERMANENTLY IDENTIFIED BY MEANS OF A TAG OR STENCIL AT A
MINIMUM OF ONCE EVERY 10-LINEAR FT WITH "VAPOR MITIGATION - CONTACT MAINTENANCE DEPT". LABELS ARE
ALSO BE FIXED TO THE TURBINE VENTILATOR FANS IN AN ACCESSIBLE LOCATION ON THE ROOFTOP.
6.THE INTAKE SCREEN OF THE PRESSURE MONITORING POINTS ARE POSITIONED TO BE MINIMUM 5-FT AWAY FROM
EXTERNAL WALLS.
7.THIS VAPOR MITIGATION PLAN IS INTENDED TO BE USED FOR DIRECTION OF VIMS COMPONENT INSTALLATION
ONLY AND IS NOT INTENDED TO GUIDE CONSTRUCTION OF STRUCTURAL COMPONENTS NOT RELATED TO THE
VIMS. CONSTRUCTION CONTRACTOR SHALL VERIFY CONSISTENCY OF VIMS DETAILS WITH APPLICABLE
STRUCTURAL, ARCHITECTURAL, MECHANICAL, & PLUMBING PLANS AND RESOLVE ANY INCONSISTENCIES PRIOR
TO VIMS INSTALLATION.
OPEN AIR
PARKING DECK
SOUTH TRYON
STREET
WINNIFRED
STREET
4
VM1
5
VM1
5
VM1
5
VM1
3
VM1
4" SCH 40 PVC
RISER
3" SCH 40 PVC
RISER
7
VM1
INSTALL TURNED DOWN
SLAB TO SEAL VAPOR
LINER (SEE DETAIL 7)
3" SCH 40 PVC
TEE (TYP.)
4" SCH 40 PVC 90
DEGREE ELBLOW (TYP.)
2
VM1
1
1
VM1
VM1
SEAL VAPOR LINER TO CONCRETE
FOOTERS AND SLABS PER
MANUFACTURER INSTRUCTIONS (TYP.)
8
VM1
6
VM1
8
VM1
INSTALL 3" VENT CAP AT
THE ENDS OF PIPE (TYP.)
SLAB STEP; REFER TO
STRUCTURAL DRAWINGS
WI
N
O
N
A
S
T
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E
T
BL
A
N
D
S
T
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E
T
POSITION CLEAN-OUT IN HALLWAY AND
PIPE INTAKE UNDERNEATH
COMMERCIAL SPACE
5
VM1
5
VM1
7
VM1
4" SCH 40 PVC
SLOTTED
PIPE
4" SCH 40 PVC SLOTTED
PIPE
HATCHED AREA REPRESENTS
APPROXIMATE EXTENT OF
CONCRETE REPLACEMENT AND
VAPOR BARRIER REPAIR WITH
RAVEN VAPORBLOCK-20 PLUS
VIMP MODIFICATION
COMMERCIAL
SPACE 12
AS-BUILT
05/28/21
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8
/
2
0
2
1
1
1
:
4
0
:
1
0
A
M
Appendix B
Photo Log
2923 S. Tryon Street, Suite 100
Charlotte, NC 28203704.586.0007(p) 704.586.0373(f)
Photograph 1: View of sub-slab vent piping and gravel in the area of tenant upfit.
HD SUPPLY BROWNFIELDS SITECENTRO RAILYARD APARTMENTSCHARLOTTE, NORTH CAROLINA
Photograph 2: View of vapor barrier prior to concrete pour in the area of tenant upfit.
2923 S. Tryon Street, Suite 100
Charlotte, NC 28203704.586.0007(p) 704.586.0373(f)
Photograph 3: View of indoor air sampling following completion of tenant upfit activities.
HD SUPPLY BROWNFIELDS SITECENTRO RAILYARD APARTMENTSCHARLOTTE, NORTH CAROLINA
Appendix C
Field Forms
Vapor Intrusion Mitigation Inspection Log HD
Supply Brownfields Property
Centro Railyard Apartments
1425 Winnifred Street
Charlotte, Mecklenburg County, North Carolina
FZR-001
Lot Number______________Unit Number Commercial Space 12
Date 3/9/2021
Yes Needs
Work Comments / Repairs / Modifications
X
X
X
X
X
Date 3/11/21
Yes Needs
Work Comments / Repairs / Modifications
Date
Yes Needs
Work Comments / Repairs / Modifications
Date
Yes Needs
Work Comments / Repairs / Modifications
General Notes :
Inspector ACB
Inspector ACB
Inspector
Inspector
Follow‐Up Inspection Notes:
(if required)None Required
Follow‐Up Inspection Notes:
(if required)None Required
Proper labels at fan location:
Sub‐Slab Piping and Gravel
Fan operational:
Fans
Riser Piping
Vapor Block 20 Vapor Barrier
Proper installation of vertical mitigation piping:
Proper mitigation pipe labels:
Correct fan type:
Proper installation of electric fan:
Proper seals around penetrations and vertical riser(s):
Good condition of vapor barrier:
Proper placement of mitigation vent piping:
Follow‐Up Inspection Notes:
(if required)
Nones Required
Proper placement of monitoring points:
Proper placement of riser pipes:
Proper gravel depth and type:
Proper placement of piping through footings:
Proper seals around edges, concrete:
None Required Follow‐Up Inspection Notes:
(if required)
X
X
X
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Inspection form is for the tenant up-fit space in Commercial Space 12. An inspection form was previously completed for the entirety of the vapor intrusion
mitigation system in the Railyard Apartments. This form is for the area of the modified VIMS which saw changes to the originally approved sub-slab piping
layout and vapor barrier cover.
NA
NA NA
NA
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IAS-1 / IAS-DUP 0850 -29 0.000 -- -- 70 506 L36103 / 28744 (DUP)4/7/21 8 1304 -17 0.000 -- -- 70 50
13129 (DUP)0.0125 L/min 1641 -7 0.000 -- -- 70 50
BAS-1 0857 -29 -- 59 70 -- --6 L37240 4/7/21 8 1302 -17 -- 81 28 -- --
13127 0.0125 L/min 1638 -7 -- 84 23 -- --
0823 1300 1635 Pressure readings taken using the positive
0.00 0.00 0.00 terminal on the manometer.
30.04 29.99 29.92
SSE E ENE
1 4 4
INDOOR AIR BUILDING SURVEY
and SAMPLING FORM
Site Name: ____________________________________ DSCAID#: ______________________
Preparer’s name: ________________________________ Date: __________________________
Preparer’s affiliation: ____________________________ Phone #: _______________________
Part I - Occupants
Building Address: ____________________________________________________________________
Property Contact: _______________________________ Owner / Renter / other: ______________
Contact’s Phone: home ( )__________ work ( )______________ cell ( )____________
# of Building occupants: Children under age 13 _____ Children age 13-18 ______ Adults _____
Part II – Building Characteristics
Building type: residential / multi-family residential / office / strip mall / commercial / industrial
Describe building: ________________________________________ Year constructed: _________
Sensitive population: day care / nursing home / hospital / school / other (specify): _______________
Number of floors below grade: ______ (full basement / crawl space / slab on grade)
Number of floors at or above grade: ______
Depth of basement below grade surface: ______ ft. Basement size: _______ ft2
Basement floor construction: concrete / dirt / floating / stone / other (specify): ________________
Foundation walls: poured concrete / cinder blocks / stone / other (specify) ________________
Basement sump present? Yes / No Sump pump? Yes / No Water in sump? Yes / No
Type of heating system (circle all that apply):
hot air circulation hot air radiation wood steam radiation
heat pump hot water radiation kerosene heater electric baseboard
other (specify): ________________________
Type of ventilation system (circle all that apply):
central air conditioning mechanical fans bathroom ventilation fans
individual air conditioning units kitchen range hood fan outside air intake
other (specify): _________________
Type of fuel utilized (circle all that apply):
Natural gas / electric / fuel oil / wood / coal / solar / kerosene
Are the basement walls or floor sealed with waterproof paint or epoxy coatings? Yes / No
multi-family residential
heat pump
ndividual air conditioning units
No
HD Supply - Railyard Apartments N/A
Amir Stewart 4/7/21
Hart & Hickman, PC (704) 586-0007
1425 Winnifred Street, Charlotte, NC
Robert Maintenance
803 577-9325
Apartment building containing multiple ground floor commercial spaces 2020
N/A
0
8
N/A
N/A
Is there a whole house fan? Yes / No
Septic system? Yes / Yes (but not used) / No
Irrigation/private well? Yes / Yes (but not used) / No
Type of ground cover outside of building: grass / concrete / asphalt / other (specify) _____________
Existing subsurface depressurization (radon) system in place? Yes / No active / passive
Sub-slab vapor/moisture barrier in place? Yes / No
Type of barrier: ____________________________
Part III - Outside Contaminant Sources
Other stationary sources nearby (gas stations, emission stacks, etc.): _____________________________
Heavy vehicular traffic nearby (or other mobile sources): ______________________________________
Part IV – Indoor Contaminant Sources
Identify all potential indoor sources found in the building (including attached garages), the location of the
source (floor and room), and whether the item was removed from the building 48 hours prior to indoor air
sampling event. Any ventilation implemented after removal of the items should be completed at least 24
hours prior to the commencement of the indoor air sampling event.
Potential Sources Location(s)Removed
(Yes / No / NA)
Gasoline storage cans
Gas-powered equipment
Kerosene storage cans
Paints / thinners / strippers
Cleaning solvents
Oven cleaners
Carpet / upholstery cleaners
Other house cleaning products
Moth balls
Polishes / waxes
Insecticides
Furniture / floor polish
Nail polish / polish remover
Hairspray
Cologne / perfume
Air fresheners
Fuel tank (inside building) NA
Wood stove or fireplace NA
New furniture / upholstery
New carpeting / flooring NA
Hobbies - glues, paints, etc.
No
No
Yes
No
Yes / passive
Stego's Drago Wrap and Raven's VaporBlock-20 Plus
None located
Yes
No
No
No
Possible, none located N/A
Possible, none located N/A
Possible, none located N/A
Possible, none located N/A
Possible, none located N/A
No
Possible, none located N/A
Possible, none located N/A
Possible, none located N/A
No
No
No
Possible, none located
No
No
No
No
Possible, none located
Part V – Miscellaneous Items
Do any occupants of the building smoke? Yes / No How often? ______________
Last time someone smoked in the building? ____________ hours / days ago
Does the building have an attached garage directly connected to living space? Yes / No
If so, is a car usually parked in the garage? Yes / No
Are gas-powered equipment or cans of gasoline/fuels stored in the garage? Yes / No
Do the occupants of the building have their clothes dry cleaned? Yes / No
If yes, how often? weekly / monthly / 3-4 times a year
Do any of the occupants use solvents in work? Yes / No
If yes, what types of solvents are used? _______________________________________
If yes, are their clothes washed at work? Yes / No
Have any pesticides/herbicides been applied around the building or in the yard? Yes / No
If so, when and which chemicals? _________________________________________________
Has there ever been a fire in the building? Yes / No If yes, when? _____________
Has painting or staining been done in the building in the last 6 months? Yes / No
If yes, when __________________ and where? ____________________________
Part VI – Sampling Information
Sample Technician: ____________________________ Phone number: ( ) _______ - __________
Sample Source: Indoor Air / Crawlspace Air / Sub-Slab / Near Slab Soil Gas / Exterior Soil Gas
Sampler Type: Tedlar bag / Sorbent / Stainless Steel Canister / Other (specify): _________________
Analytical Method: TO-15 / TO-17 / other: _________ Cert. Laboratory: _________________
Sample locations (floor, room):
Field ID # _____ - ________________________ Field ID # _____ - __________________________
Field ID # _____ - ________________________ Field ID # _____ - __________________________
Were “Instructions for Occupants” followed? Yes / No
If not, describe modifications: __________________________________________________________
Yes
Yes
Yes
No
No
Yes
No
No
No
es
3-22-21 - Onslaught FastCap and ADVION INSECT GRA
Amir Stewart 704 586 0007
Waypoint Analytical
IAS-1 /
IAS-DUP Tenant Space BAS-1 Background
Provide Drawing of Sample Location(s) in Building
Part VII - Meteorological Conditions
Was there significant precipitation within 12 hours prior to (or during) the sampling event? Yes / No
Describe the general weather conditions: ___________________________________________________
_____________________________________________________________________________________
Part VIII – General Observations
Provide any information that may be pertinent to the sampling event and may assist in the data
interpretation process (e.g., observed that drycleaner operated with door or windows propped open for
ventilation).
(Adapted from the NJDEP Vapor Intrusion Guidance, October 2005)
Yes
Sunny, 50's
INDOOR AIR BUILDING SURVEY
and SAMPLING FORM
Site Name: ____________________________________ DSCAID#: ______________________
Preparer’s name: ________________________________ Date: __________________________
Preparer’s affiliation: ____________________________ Phone #: _______________________
Part I - Occupants
Building Address: ____________________________________________________________________
Property Contact: _______________________________ Owner / Renter / other: ______________
Contact’s Phone: home ( )__________ work ( )______________ cell ( )____________
# of Building occupants: Children under age 13 _____ Children age 13-18 ______ Adults _____
Part II – Building Characteristics
Building type: residential / multi-family residential / office / strip mall / commercial / industrial
Describe building: ________________________________________ Year constructed: _________
Sensitive population: day care / nursing home / hospital / school / other (specify): _______________
Number of floors below grade: ______ (full basement / crawl space / slab on grade)
Number of floors at or above grade: ______
Depth of basement below grade surface: ______ ft. Basement size: _______ ft2
Basement floor construction: concrete / dirt / floating / stone / other (specify): ________________
Foundation walls: poured concrete / cinder blocks / stone / other (specify) ________________
Basement sump present? Yes / No Sump pump? Yes / No Water in sump? Yes / No
Type of heating system (circle all that apply):
hot air circulation hot air radiation wood steam radiation
heat pump hot water radiation kerosene heater electric baseboard
other (specify): ________________________
Type of ventilation system (circle all that apply):
central air conditioning mechanical fans bathroom ventilation fans
individual air conditioning units kitchen range hood fan outside air intake
other (specify): _________________
Type of fuel utilized (circle all that apply):
Natural gas / electric / fuel oil / wood / coal / solar / kerosene
Are the basement walls or floor sealed with waterproof paint or epoxy coatings? Yes / No
multi-family residential
heat pump
ndividual air conditioning units
No
HD Supply - Railyard Apartments N/A
Joe Gentilcore 8/24/21
Hart & Hickman, PC (704) 586-0007
1425 Winnifred Street, Charlotte, NC
Robert Maintenance
803 577-9325
residential and commercial tenant spaces 2020
N/A
0
8
N/A
N/A
Is there a whole house fan? Yes / No
Septic system? Yes / Yes (but not used) / No
Irrigation/private well? Yes / Yes (but not used) / No
Type of ground cover outside of building: grass / concrete / asphalt / other (specify) _____________
Existing subsurface depressurization (radon) system in place? Yes / No active / passive
Sub-slab vapor/moisture barrier in place? Yes / No
Type of barrier: ____________________________
Part III - Outside Contaminant Sources
Other stationary sources nearby (gas stations, emission stacks, etc.): _____________________________
Heavy vehicular traffic nearby (or other mobile sources): ______________________________________
Part IV – Indoor Contaminant Sources
Identify all potential indoor sources found in the building (including attached garages), the location of the
source (floor and room), and whether the item was removed from the building 48 hours prior to indoor air
sampling event. Any ventilation implemented after removal of the items should be completed at least 24
hours prior to the commencement of the indoor air sampling event.
Potential Sources Location(s)Removed
(Yes / No / NA)
Gasoline storage cans
Gas-powered equipment
Kerosene storage cans
Paints / thinners / strippers
Cleaning solvents
Oven cleaners
Carpet / upholstery cleaners
Other house cleaning products
Moth balls
Polishes / waxes
Insecticides
Furniture / floor polish
Nail polish / polish remover
Hairspray
Cologne / perfume
Air fresheners
Fuel tank (inside building) NA
Wood stove or fireplace NA
New furniture / upholstery
New carpeting / flooring NA
Hobbies - glues, paints, etc.
No
No
Yes
No
Yes / passive
Stego - Drago 20 mil vapor barrier
None
Yes
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Yes
Yes
N/A
Part V – Miscellaneous Items
Do any occupants of the building smoke? Yes / No How often? ______________
Last time someone smoked in the building? ____________ hours / days ago
Does the building have an attached garage directly connected to living space? Yes / No
If so, is a car usually parked in the garage? Yes / No
Are gas-powered equipment or cans of gasoline/fuels stored in the garage? Yes / No
Do the occupants of the building have their clothes dry cleaned? Yes / No
If yes, how often? weekly / monthly / 3-4 times a year
Do any of the occupants use solvents in work? Yes / No
If yes, what types of solvents are used? _______________________________________
If yes, are their clothes washed at work? Yes / No
Have any pesticides/herbicides been applied around the building or in the yard? Yes / No
If so, when and which chemicals? _________________________________________________
Has there ever been a fire in the building? Yes / No If yes, when? _____________
Has painting or staining been done in the building in the last 6 months? Yes / No
If yes, when __________________ and where? ____________________________
Part VI – Sampling Information
Sample Technician: ____________________________ Phone number: ( ) _______ - __________
Sample Source: Indoor Air / Crawlspace Air / Sub-Slab / Near Slab Soil Gas / Exterior Soil Gas
Sampler Type: Tedlar bag / Sorbent / Stainless Steel Canister / Other (specify): _________________
Analytical Method: TO-15 / TO-17 / other: _________ Cert. Laboratory: _________________
Sample locations (floor, room):
Field ID # _____ - ________________________ Field ID # _____ - __________________________
Field ID # _____ - ________________________ Field ID # _____ - __________________________
Were “Instructions for Occupants” followed? Yes / No
If not, describe modifications: __________________________________________________________
Yes
Yes
Yes
No
Yes
No
No
No
es
Yes
unknown commercial space 12
Joe Gentilcore 704 586 0007
Waypoint Analytical
IAS-1/DUP Commercial Space 12 BAS-1 Background Ambient Air
SS-OP-1 Commercial Space 12
Provide Drawing of Sample Location(s) in Building
Part VII - Meteorological Conditions
Was there significant precipitation within 12 hours prior to (or during) the sampling event? Yes / No
Describe the general weather conditions: ___________________________________________________
_____________________________________________________________________________________
Part VIII – General Observations
Provide any information that may be pertinent to the sampling event and may assist in the data
interpretation process (e.g., observed that drycleaner operated with door or windows propped open for
ventilation).
(Adapted from the NJDEP Vapor Intrusion Guidance, October 2005)
IAS-1 / IAS-DUP
BAS-1
No
Clear, 80s - 90s
Commercial space 12 has recently been upfitted with new flooring, fixtures, furniture, and paint.
H&H will request SDS for all building materials from the builder.
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Appendix D
Safety Data Sheets for Products Used During Construction
SAFETY DATA SHEET
1. Identification
Product identifier SHEETROCK® Brand EASY SAND™ Lightweight Setting-Type Joint Compound, 5, 20, 45,
90, 210
Other means of identification
SDS number 61000030002
Synonyms Joint Compound, Finishing Compound, Taping Compound, Mud
Recommended use Interior use.
Recommended restrictions Use in accordance with manufacturer's recommendations.
Manufacturer / Importer / Supplier / Distributor information
Company name United States Gypsum Company
Address 550 West Adams Street
Chicago, Illinois 60661-3637
Telephone 1-800-874-4968
Website www.usg.com
Emergency phone number 1-800-507-8899
2. Hazard(s) identification
Not classified.Physical hazards
Category 1ACarcinogenicityHealth hazards
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement May cause cancer by inhalation.
Precautionary statement
Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Wear protective gloves/protective clothing/eye protection/face protection.
Response If exposed or concerned: Get medical advice/attention.
Storage Store locked up.
Disposal Dispose of in accordance with local, state, and federal regulations.
Not classified.Hazard(s) not otherwise
classified (HNOC)
3. Composition/information on ingredients
Mixtures
26499-65-0 > 60Plaster of Paris (Calcium
sulfate hemihydrate CAS
10034-76-1)
CAS number %Chemical name
1317-65-3 < 40Limestone
12174-11-7 < 10Attapulgite
13397-24-5 < 10Calcium sulfate dihydrate
(Alternative CAS 10101-41-4)
12001-26-2 < 10Mica
93763-70-3 < 10Perlite
SHEETROCK® Brand EASY SAND™ Lightweight Setting-Type Joint Compound, 5, 20, 45, 90, 210 SDS US
916564 Version #: 01 Revision date: - Issue date: 31-December-2013 1 / 8
Impurities
CAS number %Chemical name
Crystalline silica (Quartz) 14808-60-7 < 1
Composition comments All concentrations are in percent by weight unless ingredient is a gas.
Raw materials in this product contain respirable crystalline silica as an impurity. The weight
percent of respirable crystalline silica found in this product is <1.0%. Exposures to respirable
crystalline silica during the normal use of this product must be determined by workplace hygiene
testing.
4. First-aid measures
Inhalation Dust irritates the respiratory system, and may cause coughing and difficulties in breathing. Move
injured person into fresh air and keep person calm under observation. Get medical attention if
symptoms persist.
Skin contact Contact with dust: Rinse area with plenty of water. Get medical attention if irritation develops or
persists.
Eye contact Dust in the eyes: Do not rub eyes. Flush thoroughly with water. If irritation occurs, get medical
assistance.
Ingestion Plaster of Paris hardens and if ingested may result in stomach and intestinal blockage. Drinking
gelatin solutions or large volumes of water may delay setting.
Most important
symptoms/effects, acute and
delayed
Under normal conditions of intended use, this product is not expected to be a health risk. Dust may
irritate throat and respiratory system and cause coughing.
Indication of immediate
medical attention and special
treatment needed
Provide general supportive measures and treat symptomatically.
General information Ensure that medical personnel are aware of the material(s) involved.
5. Fire-fighting measures
Suitable extinguishing media Use fire-extinguishing media appropriate for surrounding materials.
Unsuitable extinguishing
media
Not applicable.
Specific hazards arising from
the chemical
Not a fire hazard.
Special protective equipment
and precautions for firefighters
Selection of respiratory protection for firefighting: follow the general fire precautions indicated in
the workplace. Self-contained breathing apparatus and full protective clothing must be worn in
case of fire.
Fire-fighting
equipment/instructions
Use standard firefighting procedures and consider the hazards of other involved materials.
Specific methods Cool material exposed to heat with water spray and remove it if no risk is involved.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
See Section 8 of the SDS for Personal Protective Equipment.
Methods and materials for
containment and cleaning up
Vacuum up the spilled material. Vacuums used for this purpose should be equipped with HEPA
filters. Containers must be labeled. Collect in approved containers and seal securely. For waste
disposal, see Section 13 of the SDS.
Environmental precautions Avoid discharge to drains, sewers, and other water systems.
7. Handling and storage
Precautions for safe handling Minimize dust production when mixing, sanding, or opening and closing bags. Avoid inhalation of
dust. Wear appropriate personal protective equipment. Wash hands after handling. Observe good
industrial hygiene practices and use appropriate lifting techniques.
Conditions for safe storage,
including any incompatibilities
Store in a cool, dry, well-ventilated place. Store away from incompatible materials. Avoid contact
with acids, water, and moisture.
SHEETROCK® Brand EASY SAND™ Lightweight Setting-Type Joint Compound, 5, 20, 45, 90, 210 SDS US
916564 Version #: 01 Revision date: - Issue date: 31-December-2013 2 / 8
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueType FormComponents
PEL 5 mg/m3 Respirable fraction.Calcium sulfate dihydrate
(Alternati ve CAS
10101-41-4 ) (CAS
13397-24-5)
15 mg/m3 Total dust.
PEL 5 mg/m3 Respirable fraction.Limestone (CAS 1317-65-3)
15 mg/m3 Total dust.
PEL 5 mg/m3 Respirable fraction.Plaster of Paris (Calcium
sulfate hemihydrat e CAS
10034-76-1 ) (CAS
26499-65-0)
15 mg/m3 Total dust.
US. OSHA Table Z-3 (29 CFR 1910.1000)
ValueTypeComponents
TWA 20 mppcfMica (CAS 12001-26-2)
ValueType FormImpurities
TWA 0.3 mg/m3 Total dust.Crystallin e silica (Quartz)
(CAS 14808-60-7)
0.1 mg/m3 Respirable.
2.4 mppcf Respirable.
US. ACGIH Threshold Limit Values
ValueType FormComponents
TWA 10 mg/m3 Inhalable fraction.Calcium sulfate dihydrate
(Alternati ve CAS
10101-41-4 ) (CAS
13397-24-5)
TWA 3 mg/m3 Respirable fraction.Mica (CAS 12001-26-2)
TWA 10 mg/m3 Inhalable fraction.Plaster of Paris (Calcium
sulfate hemihydrat e CAS
10034-76-1 ) (CAS
26499-65-0)
ValueType FormImpurities
TWA 0.025 mg/m3 Respirable fraction.Crystallin e silica (Quartz)
(CAS 14808-60-7)
US NIOSH Pocket Guide to Chemical Hazards: Recommended exposure limit (REL)
ValueType FormComponents
TWA 5 mg/m3 Respirable.Calcium sulfate dihydrate
(Alternati ve CAS
10101-41-4 ) (CAS
13397-24-5)
10 mg/m3 Total
TWA 5 mg/m3 Respirable.Limestone (CAS 1317-65-3)
10 mg/m3 Total
TWA 3 mg/m3 Respirable.Mica (CAS 12001-26-2)
TWA 5 mg/m3 Respirable.Perlite (CAS 93763-70-3)
10 mg/m3 Total
TWA 5 mg/m3 Respirable.Plaster of Paris (Calcium
sulfate hemihydrat e CAS
10034-76-1 ) (CAS
26499-65-0)
10 mg/m3 Total
ValueType FormImpurities
TWA 0.05 mg/m3 Respirable dust.Crystallin e silica (Quartz)
(CAS 14808-60-7)
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering
controls
Provide sufficient ventilation for operations causing dust formation. Observe occupational
exposure limits and minimize the risk of exposure.
SHEETROCK® Brand EASY SAND™ Lightweight Setting-Type Joint Compound, 5, 20, 45, 90, 210 SDS US
916564 Version #: 01 Revision date: - Issue date: 31-December-2013 3 / 8
Individual protection measures, such as personal protective equipment
Eye/face protection Wear approved safety goggles.
Skin protection
Hand protection It is a good industrial hygiene practice to minimize skin contact. For prolonged or repeated skin
contact use suitable protective gloves.
Other Normal work clothing (long sleeved shirts and long pants) is recommended.
Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn. Use a NIOSH/MSHA approved air
purifying respirator as needed to control exposure. Consult with respirator manufacturer to
determine respirator selection, use, and limitations. Use positive pressure, air-supplied respirator
for uncontrolled releases or when air purifying respirator limitations may be exceeded. Follow
respirator protection program requirements (OSHA 1910.134 and ANSI Z88.2) for all respirator
use.
Thermal hazards None.
General hygiene
considerations
Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment separately from regular wash. Observe any medical surveillance requirements.
9. Physical and chemical properties
Appearance
Physical state Solid.
Form Powder.
Color White to off-white.
Odor Low to no odor.
Odor threshold Not applicable.
pH 7.5 - 9.9
Melting point/freezing point Not applicable.
Initial boiling point and boiling
range
212 °F (100 °C)
Flash point Not applicable.
Evaporation rate Not applicable.
Flammability (solid, gas)Not applicable.
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Not applicable.
Flammability limit - upper
(%)
Not applicable.
Explosive limit - lower (%)Not applicable.
Explosive limit - upper (%)Not applicable.
Vapor pressure Not applicable.
Vapor density Not applicable.
Relative density 0.6 - 0.7 (H2O=1)
Solubility(ies)Soluble in water.
Partition coefficient
(n-octanol/water)
Not applicable.
Auto-ignition temperature Not applicable.
Decomposition temperature Not applicable.
Viscosity Not applicable.
Other information
Bulk density
VOC (Weight %)
35 - 45 lbs/ft³
None detected.
10. Stability and reactivity
Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
SHEETROCK® Brand EASY SAND™ Lightweight Setting-Type Joint Compound, 5, 20, 45, 90, 210 SDS US
916564 Version #: 01 Revision date: - Issue date: 31-December-2013 4 / 8
Possibility of hazardous
reactions
Hazardous polymerization does not occur.
Conditions to avoid When mixed with water this product can become very hot. Encasing or making moulds of any body
part can cause serious burns that may require surgical removal of affected tissue and even
amputation of encased body part.
Incompatible materials Acids. Exposure to water and acids must be supervised because the reactions are vigorous and
produce large amounts of heat. Crystalline silica in contact with powerful oxidizing agents, such as
fluorine, chlorine trifluoride and oxygen difluoride, may cause fires. Crystalline silica will dissolve in
hydrofluoric acid and produce a corrosive gas, silicon tetrafluoride.
Hazardous decomposition
products
Calcium oxides. Sulfur oxides. Silicon oxides. Above 1472°F (800°C) limestone (CaCO3) can
decompose to lime (CaO) and release carbon dioxide (CO2).
11. Toxicological information
Information on likely routes of exposure
Ingestion Ingestion may cause irritation and stomach discomfort.
Inhalation Inhalation of dusts may cause respiratory irritation. Prolonged and repeated exposure to airborne
respirable crystalline silica can cause silicosis and/or lung cancer.
Skin contact Under normal conditions of intended use, this product does not pose a skin hazard.
Eye contact Direct contact with airborne particulates may cause temporary irritation.
Symptoms related to the
physical, chemical and
toxicological characteristics
Dust may irritate eyes and mucous membranes of the nose, throat and upper respiratory system
causing sneezing and/or coughing.
Information on toxicological effects
Acute toxicity Not expected to be a hazard under normal conditions of intended use.
Skin corrosion/irritation Prolonged or repeated skin contact may cause drying, cracking, or irritation.
Serious eye damage/eye
irritation
Direct contact with eyes may cause temporary irritation.
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization Not a skin sensitizer. Plaster of Paris has displayed little sensitization potential.
Germ cell mutagenicity Data does not suggest that this product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity Repeated and prolonged exposure to high levels of respirable crystalline silica may cause cancer.
IARC Monographs. Overall Evaluation of Carcinogenicity
Attapulgite (CAS 12174-11-7) 2B Possibly carcinogenic to humans.
3 Not classifiable as to carcinogenicity to humans.
Crystalline silica (Quartz) (CAS 14808-60-7) 1 Carcinogenic to humans.
NTP Report on Carcinogens
Crystalline silica (Quartz) (CAS 14808-60-7) Known To Be Human Carcinogen.
Reproductive toxicity Not expected to be a reproductive hazard.
Specific target organ toxicity -
single exposure
No data available, but none expected.
Specific target organ toxicity -
repeated exposure
Not classified. For detailed information, see section 16.
Aspiration hazard Due to the physical form of the product it is not an aspiration hazard.
Chronic effects Prolonged and routine inhalation of high levels of respirable crystalline silica particles can lead to
the lung disease known as silicosis. Some studies show excess numbers of cases of scleroderma,
connective tissue disorders, lupus, rheumatoid arthritis, chronic kidney diseases and end-stage
kidney disease in workers exposed to respirable crystalline silica. Pre-existing skin and respiratory
conditions including dermatitis, asthma and chronic lung disease might be aggravated by
exposure. Occupational exposure to respirable dust and respirable crystalline silica should be
monitored and controlled.
12. Ecological information
Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Components Test ResultsSpecies
Calcium sulfate dihydrate (Alternative CAS 10101-41-4) (CAS 13397-24-5)
Aquatic
LC50Fish > 1970 mg/l, 96 hoursFathead minnow (Pimephales promelas)
SHEETROCK® Brand EASY SAND™ Lightweight Setting-Type Joint Compound, 5, 20, 45, 90, 210 SDS US
916564 Version #: 01 Revision date: - Issue date: 31-December-2013 5 / 8
Components Test ResultsSpecies
Plaster of Paris (Calcium sulfate hemihydrate CAS 10034-76-1) (CAS 26499-65-0)
Aquatic
LC50Fish > 1970 mg/l, 96 hoursFathead minnow (Pimephales promelas)
Persistence and degradability Calcium sulfate dissolves in water forming calcium and sulfate ions.
Bioaccumulative potential Bioaccumulation is not expected.
Mobility in soil No data available.
Other adverse effects None expected.
13. Disposal considerations
Disposal instructions Dispose in accordance with applicable federal, state, and local regulations. Recycle responsibly.
Local disposal regulations Dispose of in accordance with local regulations.
Hazardous waste code Not regulated.
Waste from residues / unused
products
Dispose of in accordance with local regulations.
Contaminated packaging Dispose of in accordance with local regulations.
14. Transport information
DOT
Not regulated as a hazardous material by DOT.
IATA
Not regulated as a dangerous good.
IMDG
Not regulated as a dangerous good.
Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
Not applicable.
15. Regulatory information
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely
hazardous substance
No
SARA 311/312 Hazardous
chemical
Yes
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
(SDWA)
Not regulated.
Food and Drug
Administration (FDA)
Not regulated.
SHEETROCK® Brand EASY SAND™ Lightweight Setting-Type Joint Compound, 5, 20, 45, 90, 210 SDS US
916564 Version #: 01 Revision date: - Issue date: 31-December-2013 6 / 8
US state regulations
US. Massachusetts RTK - Substance List
Calcium sulfate dihydrate (Alternative CAS 10101-41-4) (CAS 13397-24-5)
Crystalline silica (Quartz) (CAS 14808-60-7)
Limestone (CAS 1317-65-3)
Mica (CAS 12001-26-2)
Perlite (CAS 93763-70-3)
Plaster of Paris (Calcium sulfate hemihydrate CAS 10034-76-1) (CAS 26499-65-0)
US. New Jersey Worker and Community Right-to-Know Act
Not regulated.
US. Pennsylvania RTK - Hazardous Substances
Calcium sulfate dihydrate (Alternative CAS 10101-41-4) (CAS 13397-24-5)
Crystalline silica (Quartz) (CAS 14808-60-7)
Limestone (CAS 1317-65-3)
Mica (CAS 12001-26-2)
Perlite (CAS 93763-70-3)
Plaster of Paris (Calcium sulfate hemihydrate CAS 10034-76-1) (CAS 26499-65-0)
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
WARNING: This product contains a chemical known to the State of California to cause cancer.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Attapulgite (CAS 12174-11-7)
Crystalline silica (Quartz) (CAS 14808-60-7)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
Toxic Substances Control Act (TSCA) Inventory NoUnited States & Puerto Rico
16. Other information, including date of preparation or last revision
Issue date 31-December-2013
Revision date -
Version #01
Further information Crystalline silica: Raw materials in this product may contain respirable crystalline silica. Exposures
to respirable crystalline silica are not expected during the normal use of this product. However,
actual levels must be determined by workplace hygiene testing. Prolonged and repeated exposure
to airborne free respirable crystalline silica can result in lung disease (i.e., silicosis) and/or lung
cancer.
Attapulgite: Carcinogenic to experimental animals via a route of exposure not relevant to human
exposure.
Plaster of Paris: Is classified as a hazardous substance but is generally considered a safe material
for routine use. When plaster of Paris is used responsibly it is not considered as a dangerous
material. However, when mixed with water this product can become very hot. DO NOT attempt to
make a cast enclosing any part of the body. Encasing any body part can cause serious burns and
even amputation of the encased body part.
NFPA Ratings:
Health: 1
Flammability: 0
Physical hazard: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
NFPA Ratings
0
0
1
SHEETROCK® Brand EASY SAND™ Lightweight Setting-Type Joint Compound, 5, 20, 45, 90, 210 SDS US
916564 Version #: 01 Revision date: - Issue date: 31-December-2013 7 / 8
Disclaimer This information is provided without warranty. The information is believed to be correct. This
information should be used to make an independent determination of the methods to safeguard
workers and the environment.
SHEETROCK® Brand EASY SAND™ Lightweight Setting-Type Joint Compound, 5, 20, 45, 90, 210 SDS US
916564 Version #: 01 Revision date: - Issue date: 31-December-2013 8 / 8
Safety Data Sheet SDS No. GB-5002 Ready Mix Joint Compounds
Product Name
Product Identifiers
Easy Finish Topping
Easy Finish All Purpose
ProForm All Purpose Heavy Viscosity
ProForm All Purpose Export EX 70
ProForm Multi-Use
ProForm Taping
ProForm Taping Lite
ProForm Lite Blue
ProForm Texture Grade
ProForm Tinted Lite
ProForm Pre-Blend 50 lb. bag
ProForm Lite
ProForm Lite with Dust-Tech
ProForm Ultra Lite All Purpose
ProForm Topping
ProForm XP with Dust-Tech
ProForm XP Lite with Dust-Tech
Advantage
Advantage Lite
Advantage Topping
ProForm Concrete-Cover Compound
Other means of identification
Joint Compound, Taping Compound, Gypsum Board Finishing Compound
Recommended Use
All-purpose drying-type compounds used for finishing gypsum board products. Use per manufacturer’s recommendations
Restrictions on Use
Use in well-ventilated area and avoid breathing dust.
Avoid skin contact.
Manufacturer/Supplier Details
National Gypsum Company
2001 Rexford Road
Charlotte, NC 28211
Emergency Telephone Number
Director Quality Services
(704) 551-5820 - 24 Hour Emergency Response
Website: www.nationalgypsum.com
United States (US)
According to OSHA 29CFR 1910.1200 (HCS)
GHS Classification of the substance or mixture
Carcinogenicity - Category 1A - (H-350)
Specific target organ toxicity, repeated exposure – Category 1 (H-372)
Acute toxicity, inhalation - Category 4 (H-332)
Skin corrosion/irritation Category 2 (H315)
GHS Label Elements
Pictogram
Signal Word Danger
Hazard Statements
H-350 May cause cancer.
H-332, 372 Harmful if inhaled. Causes damage to organs (lungs) through prolonged or repeated
exposure.
H-315 Causes skin corrosion/irritation
Section 1: Product and Company Identification
Section 2: Hazards Identification
Page 1 of 7
SDS No. GB-5002
Safety Data Sheet Ready Mix Joint Compounds
H-315 Causes skin corrosion/irritation
Precautionary Statements
Prevention
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not breathe dust.
Use personal protective equipment as required. (See Section 8)
Use engineering controls and wet methods to minimize dust.
Response
If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
If on skin, wash with plenty of soap and water.
If in eyes, rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Get medical attention if exposed or concerned.
Storage
Store material in a cool, dry, ventilated area, away from excessive heat or sunlight.
Disposal
Dispose of material in accordance with federal, state, and local regulations
Common name/ Identifiers
Chemical Name Synonym CAS Number % (weight) Impurities
Calcium/Magnesium Limestone or 1317-65-3 <50 Crystalline silica
And may contain one or more of the following:
Mixture-silicates and
aluminates Mica 12001-26-2 <10 Crystalline silica
Hydrated magnesium Talc (non-asbestiform) 14807-96-6 <5 Crystalline silica
Mixture-various metal Perlite 93763-70-3 <10 Crystalline silica
magnesium aluminum Attapulgite Clay 12174-11-7 <5 Crystalline silica
Magnesium silicate Sepiolite Clay 63800-37-3 <5 Crystalline silica
Magnesium aluminum Smectite Clay 1302-78-9 <5 Crystalline silica
Polyvinyl Acetate Latex 9003-20-7 <5
Ethylene Vinyl Acetate
Latex 24937-78-8 <5
Section 3: Composition/Information on Ingredients
Section 2: Hazards Identification (Continued)
Page 2 of 7
SDS No. GB-5002
Safety Data Sheet Ready Mix Joint Compounds
Inhalation Remove exposed individual to fresh air immediately. If breathing difficulty persists, seek medical attention.
Eye contact Do not rub or scratch eyes. Immediately flush eyes with water for 15 minutes.
Remove contact lenses (if applicable). Seek medical attention if irritation persists.
Skin contact Flush and wash skin with soap and water. Utilize lotions to alleviate dryness if present. Seek medical
attention if irritation persists.
Ingestion This product is not expected to be hazardous and no harmful effects are expected upon ingestion of small
amounts. Larger amounts may cause abdominal discomfort or possible obstruction of the digestive tract.
Seek medical attention if problems persist.
Medical Conditions aggravated by exposure
Pre-existing upper respiratory and lung diseases such as, but not limited to, bronchitis, emphysema and asthma. Pre-existing skin
diseases such as, but not limited to, rashes and dermatitis.
Extinguishing Media
Dry chemical, foam, water, or extinguishing media appropriate for surrounding fire.
Unusual Fire and Explosion Hazards
Mixture poses no fire-related hazard.
Special hazards arising from the mixture
None known
Special Protective Equipment and Precautions for Firefighters
A SCBA is recommended to limit exposures to combustion products when fighting any fire.
Personal precautions, protective equipment and emergency procedures
No special precautions required.
General recommendations:
Wear appropriate Personal Protective Equipment. (See Section 8)
Maintain proper ventilation.
Environmental precautions
This product does not present an ecological hazard to the environment.
Dispose of in accordance with applicable federal, state, and local regulations.
Methods and materials for containment and cleaning up
Shovel or scoop spilled material back into container for use, if possible, or disposal.
Maintain proper ventilation to minimize dust.
Avoid washing material down drains. This material will eventually set and can cause clogs.
Precautions for safe handling
Avoid breathing vapors when opening container.
Avoid breathing dust.
Minimize generation of dust.
Provide appropriate exhaust ventilation at places where dust is formed.
Avoid contact with eyes, skin and clothing.
Wear recommended personal protective equipment when handling. (See Section 8)
Conditions for safe storage, including any incompatibilities
Store material in a cool, dry, ventilated area, away from excessive heat or sunlight.
Keep from freezing to preserve usefulness.
Keep containers closed when not in use.
Avoid contact with strong acids.
Section 4: First-Aid Measures
Section 5: Fire-Fighting Measures
Section 6: Accidental Release Measures
Section 7: Handling and Storage
Page 3 of 7
SDS No. GB-5002
Safety Data Sheet Ready Mix Joint Compounds
Control Parameters
Component (mg/m3) (mg/m3)
Calcium Carbonate or Dolomite (limestone)
15 (T)
5 (R)10 (T)
20 mppcf 3
(R)10 (T)
(R)
(R)
(R)
(T)0.025(R)
NE NE
NE NE
1 – Present as an impurity in raw materials NE- None Established
Exposure Controls
Appropriate Engineering Controls
Work/Hygiene Practices: Utilize methods to minimize dust production. Use sanders equipped with vacuum capabilities
whenever possible. Utilize a light water spray when feasible.
Ventilation: Provide local and general exhaust ventilation sufficient to maintain a dust level below the PEL/TLV.
Personal Protective Equipment
Respiratory Protection
A NIOSH approved particulate respirator is recommended in poorly ventilated areas or if the PEL/TLV is exceeded. OSHA's 29
CFR 1910.134 (Respiratory Protection Standard) must be followed whenever work conditions require respirator use.
Eye Protection
Safety glasses or goggles.
Skin
Gloves, protective clothing and/or barrier creams may be utilized if conditions warrant.
(a) Appearance: A white to gray paste
(b) Odor: Mild latex initially, Low to none after opening
(c) Odor threshold: Not available
(d) pH : 7-9
(e) Melting point/freezing point: Not Available
(f) Initial boiling point and boiling range: Not Available
(g) Flash point: Not available
(h) Evaporation rate: Not available
(i) Flammability (solid, gas): Not flammable
Not available
Section 8: Exposure Controls/Personal Protection
Section 9: Physical and Chemical Properties
Page 4 of 7
SDS No. GB-5002
Safety Data Sheet Ready Mix Joint Compounds
(k) Vapor pressure:
(l) Vapor density: Not available
(m) Relative density: ~1.0-1.8
(n) Solubility(ies): slightly soluble in water
(o) Partition coefficient: n-octanol/water: Not available
(p) Auto-ignition temperature: Not available
(q) Decomposition temperature: 825oC
(r) Viscosity: Not available
(s) Volatile organic compound (VOC) content: <2 g/l
(a) Reactivity: No data available
(b) Chemical stability: Stable in dry environments
(c) Possibility of hazardous reactions: None known
(d) Conditions to avoid (e.g., static discharge, shock, or vibration): None known
(e) Incompatible materials: Strong acids
(f) Hazardous decomposition products: None known. Above 825o C limestone (CaCO3)
decomposes to calcium oxide (CaO) and carbon dioxide.(CO2)
Information on Toxicological effects
Information on likely routes of exposure
Ingestion Possible abdominal obstruction.
Inhalation Dust may irritate respiratory system. Chronic exposure may result in lung disease. (See below)
Skin contact May cause irritation, rash, itching, or dermatitis.
Eye contact Dust may cause mechanical irritation.
Symptoms related to the physical, chemical and toxicological characteristics
Acute exposure to airborne dust concentrations in excess of the PEL/TLV may result in coughing, dyspnea, wheezing, and a
burning irritation of the nose, throat, and upper respiratory tract, along with possible impaired pulmonary function. Chronic
exposures may result in lung disease. (Silicosis and/or lung cancer)
Toxicological data
No toxicological data is available for this product. Toxicological information for components of this product listed below.
Acute toxicity Not available
Skin corrosion/irritation Not available
Serious eye damage/eye irritation Not available
Skin sensitization Not available
Respiratory sensitization Not available
Sensitization Not available
Mutagenicity Not available
Carcinogenicity Not available
Agency for Research on Cancer (IARC) classifies crystalline silica inhaled in the form of quartz or cristobalite from occupational sources
as carcinogenic to humans, Group 1. The National Toxicology Program (NTP) classifies respirable crystalline silica as a substance which
may be reasonably anticipated to be a carcinogen. OSHA does not regulate crystalline silica as a human carcinogen.
Some products may contain attapulgite clay. IARC classifies attapulgite (long fiber) carcinogenic to humans, Group 2B. Attapulgite is
not classified as a carcinogen by NTP or OSHA.
Exposures to respirable crystalline silica are not expected during the recommended use of this product. However, actual levels must
Reproductive effects Not available
Specific target organ toxicity –
single exposure Not available
Aspiration toxicity Not available
Section 10: Stability and Reactivity
Section 11: Toxicological Information
Page 5 of 7
SDS No. GB-5002
Safety Data Sheet Ready Mix Joint Compounds
(a) Ecotoxicity (aquatic and terrestrial, where available): This product does not present an ecological
hazard to the environment.
(b) Persistence and degradability: Unknown
(c) Bioaccumulative potential: Limestone is a naturally occurring mineral. Biodegradation and/or
bioaccumulation potential is not applicable.
(d) Mobility in soil: Unknown
(e) Other adverse effects (such as hazardous to the ozone layer): None known
This material is not considered a hazardous waste. Dispose of according to Local, State, Federal, and Provincial Environmental
Regulations.
This product is not a DOT hazardous material
Shipping Name: Same as product name
ICAO/IATA/IMO: Not applicable
All ingredients are included on the TSCA inventory.
Federal Regulations
SARA Title III: Not listed under Sections 302, 304, and 313
CERCLA: Not listed
RCRA: Not listed
OSHA: Dust and potential respirable crystalline silica generated during product use may be hazardous.
State Regulations
California Prop 65: Respirable crystalline silica is known to the state of California to cause cancer. Industrial hygiene monitoring
during recommended use of this product failed to identify any respirable crystalline silica.
Canada WHMIS
All components of this product are included in the Canadian Domestic Substances List (DSL).
Crystalline silica: WHMIS Classification D2A
SDS Prepared by: National Gypsum Company
2001 Rexford Road
Charlotte, NC 28211
Phone Number: (704) 551-5820
Date of Preparation: March 3, 2015
Revision indicators and Date
Effective Date Change: 4/8/2016 Supersedes: 6/1/2015
Format Changes: Added ProForm XP Lite with Dust-Tech
Section 12: Ecological Information
Section 13: Disposal Considerations
Section 14: Transport Information
Section 15: Regulatory Information
Section 16: Other Information
Page 6 of 7
SDS No. GB-5002
Safety Data Sheet Ready Mix Joint Compounds
Key to Abbreviations
ACGIH American Conference of Governmental Industrial Hygienists
CAS Chemical Abstract Services Number
CFR Code of Federal Regulations
DOT Department of Transportation EPA Environmental Protection Agency
HEPA High Efficiency Particulate Air
HCS Hazard Communications Standard
HMIS Hazardous Material Identification System
IARC International Agency for Research on Cancer
IATA International Air Transport Association
ICAO International Civil Aviation Organization
IMO International Maritime Organization
NIOSH National Institute for Occupational Safety and Health
NFPA National Fire Protection Association
NTP National Toxicology Program
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
PPE Personal Protective Equipment
TLV Threshold Limit Value
TSCA Toxic Substance Control Act
TWA Time Weighted Average
WHMIS Workplace Hazardous Materials Information System
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee
or warranty of any kind expressed or implied is made with respect to the information contained herein. This safety data sheet
was prepared to comply with the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Disclaimer of Liability:
As the conditions or methods of use are beyond our control, we do not assume any responsibility and expressly
disclaim any liability for any use of the material. Information contained herein is believed to be true and accurate,
but all statements or suggestions are made without any warranty, express or implied, regarding accuracy of the
information, the hazards connected with the use of the material, or the results to be obtained for the use thereof.
Section 16: Other Information (Continued)
Page 7 of 7
Page 1/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 24.03.2015 Revision: 24.03.2015Version number 4
40.1.3
* SECTION 1: Identification of the substance/mixture and of the company/undertaking
· 1.1 Product identifier
· Trade name: MONTANA GOLD Spray Paint all colors, fluo and shock
· Article number:
283604 - 285844, 285899, 285905, 285929, 364945, 419331, 419348, 419355, 419362, 419379, 419386,
419393, 419409, 419416, 419423, 419430, 419447, 419454, 419461, 419478
· 1.2 Relevant identified uses of the substance or mixture and uses advised against --
· Application of the substance / the mixture Lacquer
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
MONTANA CANS
Häusserstr. 36
D-69115 Heidelberg
Tel. +49-6221-36333-30
Fax +49-6221-36333-33
info@montana-cans.de
www.montana-cans.com
· Further information obtainable from:Department Product Safety
· 1.4 Emergency telephone number:
Tel.:+49 6266-75-310
Fax +49 6266-75-362
(Mo - Th 08:00 am - 04:00 pm, Fr 08:00 am - 00:30 pm)
* SECTION 2: Hazards identification
· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Aerosol 1 H222-H229 Extremely flammable aerosol. Pressurised container: May burst if heated.
GHS07
Eye Irrit. 2 H319 Causes serious eye irritation.
STOT SE 3 H336 May cause drowsiness or dizziness.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Xi; Irritant
R36: Irritating to eyes.
F+; Extremely flammable
R12: Extremely flammable.
R66-67: Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and
dizziness.
· Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
At long or repeated contact with skin it may cause dermatitis due to the degreasing effect of the solvent.
Warning! Pressurised container.
Has a narcotising effect.
· Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
(Contd. on page 2)
GB
Page 2/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 24.03.2015 Revision: 24.03.2015Version number 4
Trade name: MONTANA GOLD Spray Paint all colors, fluo and shock
(Contd. of page 1)
40.1.3
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms
GHS02 GHS07
· Signal word Danger
· Hazard-determining components of labelling:
ethyl acetate
acetone
· Hazard statements
H222-H229 Extremely flammable aerosol. Pressurised container: May burst if heated.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
· Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P260 Do not breathe spray.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
P501 Dispose of contents / container in accordance with regional regulations.
· Additional information:
EUH066 Repeated exposure may cause skin dryness or cracking.
Buildup of explosive mixtures possible without sufficient ventilation.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT:Not applicable.
· vPvB:Not applicable.
* SECTION 3: Composition/information on ingredients
· 3.2 Chemical characterisation: Mixtures
· Description:Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
CAS: 115-10-6
EINECS: 204-065-8
Index number: 603-019-00-8
Reg.nr.: 01-2119472128-37
dimethyl ether
F+ R12
Flam. Gas 1, H220; Press. Gas C, H280
12.5-<20%
CAS: 141-78-6
EINECS: 205-500-4
Index number: 607-022-00-5
Reg.nr.: 01-2119475103-46
ethyl acetate
Xi R36; F R11
R66-67
Flam. Liq. 2, H225; Eye Irrit. 2, H319; STOT SE 3,H336
12.5-<20%
(Contd. on page 3)
GB
Page 3/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 24.03.2015 Revision: 24.03.2015Version number 4
Trade name: MONTANA GOLD Spray Paint all colors, fluo and shock
(Contd. of page 2)
40.1.3
CAS: 67-64-1
EINECS: 200-662-2
Index number: 606-001-00-8
Reg.nr.: 01-2119471330-49
acetone
Xi R36; F R11
R66-67
Flam. Liq. 2, H225; Eye Irrit. 2, H319; STOT SE 3,H336
5-<10%
CAS: 74-98-6
EINECS: 200-827-9
Index number: 601-003-00-5
Reg.nr.: 01-2119486944-21
propane
F+ R12
Flam. Gas 1, H220; Press. Gas C, H280
5-<10%
CAS: 106-97-8
EINECS: 203-448-7
Index number: 601-004-00-0
Reg.nr.: 01-2119474691-32
butane
F+ R12
Flam. Gas 1, H220; Press. Gas C, H280
5-<10%
CAS: 64742-94-5
EINECS: 265-198-5
Index number: 649-424-00-3
Reg.nr.: 01-2119510128-50
Solvent naphtha (petroleum), heavy arom.
Xn R65
Asp. Tox. 1, H304
2.5-<5.0%
CAS: 108-65-6
EINECS: 203-603-9
Index number: 607-195-00-7
Reg.nr.: 01-2119475791-29
2-methoxy-1-methylethyl acetate
R10
Flam. Liq. 3, H226
2.5-<5.0%
CAS: 9004-70-0
Index number: 603-037-00-6
cellulose nitrate
E R3
Expl. 1.1, H201
2.5-<5.0%
CAS: 1330-20-7
EINECS: 215-535-7
Index number: 601-022-00-9
Reg.nr.: 01-2119488216-32
xylene, mixture of isomers
Xn R20/21; Xi R38
R10
Flam. Liq. 3, H226; Acute Tox. 4, H312; Acute Tox. 4,H332; Skin Irrit. 2, H315
2.5-<5.0%
CAS: 75-28-5
EINECS: 200-857-2
Index number: 601-004-00-0
Reg.nr.: 01-2119485395-27
isobutane
F+ R12
Flam. Gas 1, H220; Press. Gas C, H280
<2.5%
CAS: 67-63-0
EINECS: 200-661-7
Index number: 603-117-00-0
Reg.nr.: 01-2119457558-25
propan-2-ol
Xi R36; F R11
R67
Flam. Liq. 2, H225; Eye Irrit. 2, H319; STOT SE 3,H336
<2.5%
EC number: 918-668-5
Reg.nr.: 01-2119455851-35
Hydrocarbons
Xn R65; Xi R37; N R51/53
R10-66-67
Flam. Liq. 3, H226; Asp. Tox. 1, H304; AquaticChronic 2, H411; STOT SE 3, H335-H336
<1.0%
· Additional information:
The content of Benzene (EINECS-Nr. 200-753-7) in the ingredients is less than 0,1% (Note P Annex 1 67/548
EU), so the classification as carcinogen need not to apply.
For the wording of the listed risk phrases refer to section 16.
* SECTION 4: First aid measures
· 4.1 Description of first aid measures
· After inhalation:Supply fresh air; consult doctor in case of complaints.
· After skin contact:Generally the product does not irritate the skin.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
(Contd. on page 4)
GB
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(Contd. of page 3)
40.1.3
· After swallowing:Drink plenty of water and provide fresh air. Call for a doctor immediately.
· 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
* SECTION 5: Firefighting measures
· 5.1 Extinguishing media
· Suitable extinguishing agents:
CO2, bluspoeder of waterstraal. Grotere brand met waterstraal of met schuim.
Vaten met water afkoelen.
· For safety reasons unsuitable extinguishing agents:Water with full jet
· 5.2 Special hazards arising from the substance or mixture No further relevant information available.
· 5.3 Advice for firefighters -
* SECTION 6: Accidental release measures
· 6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
· 6.2 Environmental precautions:Do not allow product to reach sewage system or any water course.
· 6.3 Methods and material for containment and cleaning up:Ensure adequate ventilation.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
* SECTION 7: Handling and storage
· 7.1 Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Store in a cool location.
Observe official regulations on storing packagings with pressurised containers.
· Information about storage in one common storage facility:Not required.
· Further information about storage conditions:
Store in cool, dry conditions in well sealed receptacles.
Protect from heat and direct sunlight.
· Storage class:2B
· 7.3 Specific end use(s)No further relevant information available.
* SECTION 8: Exposure controls/personal protection
· Additional information about design of technical facilities:No further data; see item 7.
(Contd. on page 5)
GB
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Printing date 24.03.2015 Revision: 24.03.2015Version number 4
Trade name: MONTANA GOLD Spray Paint all colors, fluo and shock
(Contd. of page 4)
40.1.3
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
115-10-6 dimethyl ether
WEL Short-term value: 958 mg/m³, 500 ppm
Long-term value: 766 mg/m³, 400 ppm
141-78-6 ethyl acetate
WEL Short-term value: 400 ppm
Long-term value: 200 ppm
67-64-1 acetone
WEL Short-term value: 3620 mg/m³, 1500 ppm
Long-term value: 1210 mg/m³, 500 ppm
106-97-8 butane
WEL Short-term value: 1810 mg/m³, 750 ppm
Long-term value: 1450 mg/m³, 600 ppm
Carc (if more than 0.1% of buta-1.3-diene)
108-65-6 2-methoxy-1-methylethyl acetate
WEL Short-term value: 548 mg/m³, 100 ppm
Long-term value: 274 mg/m³, 50 ppm
Sk
1330-20-7 xylene, mixture of isomers
WEL Short-term value: 441 mg/m³, 100 ppm
Long-term value: 220 mg/m³, 50 ppm
Sk; BMGV
67-63-0 propan-2-ol
WEL Short-term value: 1250 mg/m³, 500 ppm
Long-term value: 999 mg/m³, 400 ppm
· Ingredients with biological limit values:
1330-20-7 xylene, mixture of isomers
BMGV 650 mmol/mol creatinine
Medium: urine
Sampling time: post shift
Parameter: methyl hippuric acid
· Additional information:The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes and skin.
· Respiratory protection:
Not necessary if room is well-ventilated.
Otherwise, filter class A / P2 or self contained.
· Protection of hands:
Protective gloves
Solvent resistant gloves
In case of contact with spray dust protective gloves made of butyl shoud be used (min. 0.4 mm thick), e.g.
KCL Camatril, article no. 898 or similar products
(Contd. on page 6)
GB
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Printing date 24.03.2015 Revision: 24.03.2015Version number 4
Trade name: MONTANA GOLD Spray Paint all colors, fluo and shock
(Contd. of page 5)
40.1.3
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves Butyl rubber, BR
· Penetration time of glove material
Butyl rubber gloves with a thickness of 0.4 mm are resistant to:
Acetone: 480 min
Butyl acetate: 60 min
Ethyl acetate: 170 min
Xylene: 42 min
· Eye protection:Safety glasses
* SECTION 9: Physical and chemical properties
· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form:Aerosol
Colour:According to product specification
· Odour:Characteristic
· Odour threshold:Not determined.
· pH-value:Not determined.
· Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:Not applicable, as aerosol.
· Flash point:Not applicable, as aerosol.
· Flammability (solid, gaseous):Not applicable.
· Ignition temperature:235 °C
· Decomposition temperature:Not determined.
· Self-igniting:Product is not selfigniting.
· Danger of explosion:In use, may form flammable/explosive vapour-air mixture.
· Explosion limits:
Lower:2.1 Vol %
Upper:18.6 Vol %
· Vapour pressure at 20 °C:5200 hPa
· Density at 20 °C:0.96 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not applicable.
· Solubility in / Miscibility with
water:Not miscible or difficult to mix.
· Partition coefficient (n-octanol/water):Not determined.
· Viscosity:
Dynamic:Not determined.
Kinematic:Not determined.
· Solvent content:
VOC-(EU)---
692.1 g/l
· VOC-EU% 71.78 %
(Contd. on page 7)
GB
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(Contd. of page 6)
40.1.3
· Solids content:36.2 %
· 9.2 Other information No further relevant information available.
* SECTION 10: Stability and reactivity
· 10.1 Reactivity
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials:No further relevant information available.
· 10.6 Hazardous decomposition products:No dangerous decomposition products known.
* SECTION 11: Toxicological information
· 11.1 Information on toxicological effects
· Acute toxicity:
· LD/LC50 values relevant for classification:
141-78-6 ethyl acetate
Oral LD50 5620 mg/kg (rabbit)
Inhalative LC50/4 h 1600 mg/l (rat)
· Primary irritant effect:
· on the skin:No irritant effect.
· on the eye:Irritating effect.
· Sensitisation:No sensitising effects known.
· Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version:
Irritant
Vapours have narcotic effect.
* SECTION 12: Ecological information
· 12.1 Toxicity
· Aquatic toxicity:No further relevant information available.
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
· 12.5 Results of PBT and vPvB assessment
· PBT:Not applicable.
· vPvB:Not applicable.
· 12.6 Other adverse effects No further relevant information available.
GB
(Contd. on page 8)
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(Contd. of page 7)
40.1.3
* SECTION 13: Disposal considerations
· 13.1 Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· European waste catalogue
08 01 11* waste paint and varnish containing organic solvents or other dangerous substances
15 01 04 metallic packaging
15 01 11* metallic packaging containing a dangerous solid porous matrix (for example asbestos), including
empty pressure containers
· Uncleaned packaging:
· Recommendation:Disposal must be made according to official regulations.
* SECTION 14: Transport information
· 14.1 UN-Number
· ADR, IMDG, IATA UN1950
· 14.2 UN proper shipping name
· ADR UN1950 AEROSOLS
· IMDG AEROSOLS
· IATA AEROSOLS, flammable
· 14.3 Transport hazard class(es)
· ADR
· Class 2 5F Gases.
· Label 2.1
· IMDG, IATA
· Class 2.1
· Label 2.1
· 14.4 Packing group
· ADR, IMDG, IATA Void
· 14.5 Environmental hazards:
· Marine pollutant:No
· 14.6 Special precautions for user Warning: Gases.
· Danger code (Kemler):-
· EMS Number:F-D,S-U
· 14.7 Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
(Contd. on page 9)
GB
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Printing date 24.03.2015 Revision: 24.03.2015Version number 4
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(Contd. of page 8)
40.1.3
· Transport/Additional information:
· ADR
· Limited quantities (LQ)1L
· Excepted quantities (EQ)Code: E0
Not permitted as Excepted Quantity
· Transport category 2
· Tunnel restriction code D
· IMDG
· Limited quantities (LQ)1L
· Excepted quantities (EQ)Code: E0
Not permitted as Excepted Quantity
· UN "Model Regulation":UN1950, AEROSOLS, 2.1
* SECTION 15: Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture .
· Waterhazard class:Water hazard class 1 (Self-assessment): slightly hazardous for water.
· 15.2 Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
* SECTION 16: Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H201 Explosive; mass explosion hazard.
H220 Extremely flammable gas.
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H280 Contains gas under pressure; may explode if heated.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.
R10 Flammable.
R11 Highly flammable.
R12 Extremely flammable.
R20/21 Harmful by inhalation and in contact with skin.
R3 Extreme risk of explosion by shock, friction, fire or other sources of ignition.
R36 Irritating to eyes.
R37 Irritating to respiratory system.
R38 Irritating to skin.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 Harmfull: may cause lung damage if swallowed
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
· Contact:Anwendungstechnik
· Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
(Contd. on page 10)
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(Contd. of page 9)
40.1.3
ICAO: International Civil Aviation Organisation
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical SubstancesELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
Expl. 1.1: Explosives, Division 1.1
Flam. Gas 1: Flammable gases, Hazard Category 1
Flam. Aerosol 1: Flammable aerosols, Hazard Category 1
Press. Gas C: Gases under pressure: Compressed gas
Flam. Liq. 2: Flammable liquids, Hazard Category 2
Flam. Liq. 3: Flammable liquids, Hazard Category 3
Acute Tox. 4: Acute toxicity, Hazard Category 4
Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2
Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2
STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3
Asp. Tox. 1: Aspiration hazard, Hazard Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2
GB
SDS Number: 00010011001 Revision Date: 12/6/2018SAP Number:
Safety Data Sheet
24 Hour Emergency Phone Numbers
Medical/Poison Control:
In U.S.: Call 1-800-222-1222
Outside U.S.: Call your local poison
control center
Transportation/National Response
Center:
1-800-535-5053
1-352-323-3500
NOTE: The National ResponseCenter emergencynumbers to be used only in the event of chemical
emergencies involving a spill, leak, fire, exposure or
accident involving chemicals.
IMPORTANT: Provide this information to employees, customers, and users of this product. Read this SDS before handling or disposing of this
product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard. All abbreviated terms used in this SDS are further described in Section 16.
1. Identification
This Safety Data Sheet is available in American Spanish upon request.Los Datos de Serguridad pueden obtenerse en Espanol si lo riquiere.
Product Name:Alex Painters Acrylic Latex Caulk Revision Date:12/6/2018
9/11/2018Product UPC Number:070798180659, 070798180949 Supercedes Date:
Product Use/Class:Caulking Compound SDS No:00010011001
Preparer:Manufacturer:DAP Products Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327-8477 (non - emergency matters)
SDS Coordinator: MSDS@dap.com
Emergency Telephone:
Transportation: 1-800-535 -5053
1-352-323-3500
Poison Control: 1-800-222-1222
Regulatory and Environmental
Affairs
2. Hazards Identification
GHS Classification
Not a hazardous substance or mixture.
Symbol(s) of Product
None
Signal Word
Not a hazardous substance or mixture.
Possible Hazards
19% of the mixture consists of ingredients of unknown acute toxicity
Page 1 / 6
SDS Number: 00010011001 Revision Date: 12/6/2018SAP Number:
3. Composition/Information on Ingredients
Chemical Name CAS-No.Wt. %GHS Symbols GHS Statements
Limestone 1317-65-3 30-60 No Information No Information
Lubricating petroleum oil 72623-86-0 5-10 GHS07 H332
Petroleum distillates 64741-88-4 1-5 No Information No Information
Diethylene glycol dibenzoate 120-55-8 0.5-1.5 GHS07 H312
Dipropylene glycol dibenzoate 27138-31-4 0.5-1.5 No Information No Information
Quartz 14808-60-7 0.1-1.0 GHS07 H302
Titanium dioxide 13463-67-7 0.1-1.0 No Information No Information
The text for GHS Hazard Statements shown above (if any) is given in the "Other information" Section.
4. First-aid Measures
FIRST AID -INHALATION:Material is not likely to present an inhalation hazard at ambient conditions. If you experience difficulty in
breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical attention immediately.
FIRST AID -SKIN CONTACT:In case of contact, wash skin immediately with soap and water.
FIRST AID -EYE CONTACT:In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes until
irritation subsides. Get medical attention immediately.
FIRST AID -INGESTION:If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
5. Fire-fighting Measures
UNUSUAL FIRE AND EXPLOSION HAZARDS:No Information
SPECIAL FIREFIGHTING PROCEDURES:Wear self-contained breathing apparatus pressure-demand (NIOSH approved or
equivalent) and full protective gear. Use water spray to cool exposed surfaces.
EXTINGUISHING MEDIA:Alcohol Foam, Carbon Dioxide, Dry Chemical, Foam, Water Fog
6. Accidental Release Measures
ENVIRONMENTAL MEASURES:No Information
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:Use personal protective equipment as necessary. In case of
spillage, absorb with inert material and dispose of in accordance with applicable regulations. Scrape up dried material and place into
containers.
7. Handling and Storage
HANDLING:KEEP OUT OF REACH OF CHILDREN!DO NOT TAKE INTERNALLY. Use only with adequate ventilation. Ensure fresh
air entry during application and drying. Wash thoroughly after handling.
STORAGE:Avoid excessive heat and freezing. Do not store at temperatures above 120 degrees F. Store away from caustics and
oxidizers.
8. Exposure Controls/Personal Protection
Ingredients with Occupational Exposure Limits
Chemical Name ACGIH TLV-TWA ACGIH-TLV STEL OSHA PEL-TWA OSHA PEL-CEILING
Limestone N.E.N.E.15 mg/m3 TWA
total dust, 5 mg/m3TWA respirable
fraction
N.E.
Lubricating petroleum oil N.E.N.E.N.E.N.E.
Petroleum distillates N.E.N.E.N.E.N.E.
Diethylene glycol dibenzoate N.E.N.E.N.E.N.E.Dipropylene glycol dibenzoate N.E.N.E.N.E.N.E.
Quartz 0.025 mg/m3 TWA
respirable
particulate matter
N.E.50 µg/m3 TWA
Respirable
crystalline silica
N.E.
Titanium dioxide 10 mg/m3 TWA N.E.15 mg/m3 TWAtotal dust N.E.
Page 2 / 6
SDS Number: 00010011001 Revision Date: 12/6/2018SAP Number:
Further Advice: MEL = Maximum Exposure Limit OES = Occupational Exposure Standard SUP = Supplier's Recommendation
Sk = Skin Sensitizer N.E. = Not Established
Personal Protection
RESPIRATORY PROTECTION:No personal respiratory protective equipment normally required. National Institute for
Occupational Safety and Health (NIOSH) has recommended that the permissible exposure limit be changed to 50
micrograms respirable free silica per cubic meter of air (0.05 mg/m3) as determined by a full shift sample up to 10-hour
work shift.
SKIN PROTECTION:Rubber gloves.
EYE PROTECTION:Goggles or safety glasses with side shields.
OTHER PROTECTIVE EQUIPMENT:Not required under normal use.
HYGIENIC PRACTICES:Wash hands before breaks and at the end of workday. Remove and wash contaminated
clothing before re-use.
9. Physical and Chemical Properties
Appearance:White to Off-White Physical State:Paste
Odor:Very Slight Ammonia Odor Threshold:Not Established
Density, g/cm3:1.52 - 1.61 pH:Between 7.0 and 12.0
Freeze Point, °C:Not Established Viscosity (mPa.s):Not EstablishedSolubility in Water:No Information Partition Coeff., n-octanol/water:Not Established
Decomposition Temperature, °C:Not Established Explosive Limits, %:N.E. - N.E.Boiling Range, °C:100 - 100 Auto-Ignition Temperature, °C Not Established
Minimum Flash Point, °C:100 Vapor Pressure, mmHg:Not Established
Evaporation Rate:Slower Than n-Butyl Acetate Flash Method:Seta Closed Cup
Vapor Density:Heavier Than Air Flammability, NFPA:Non-FlammableCombustibility:Does not support combustion
(See "Other information" Section for abbreviation legend)
(If product is an aerosol, the flash point stated above is that of the propellant.)
10. Stability and Reactivity
STABILITY:Stable under recommended storage conditions.
CONDITIONS TO AVOID:Excessive heat and freezing.
INCOMPATIBILITY:Incompatible with strong bases and oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS:Normal decomposition products, i.e., COx, NOx.
11. Toxicological Information
EFFECT OF OVEREXPOSURE -INHALATION:Under normal use conditions, this product is not expected to cause adverse health
effects. Inhalation of vapors in high concentration may cause mild irritation of respiratory system (nose, mouth, mucous membranes).
EFFECT OF OVEREXPOSURE -SKIN CONTACT:Under normal use conditions, this product is not expected to cause adverse
health effects. Prolonged or repeated contact with skin may cause mild irritation.
Page 3 / 6
SDS Number: 00010011001 Revision Date: 12/6/2018SAP Number:
EFFECT OF OVEREXPOSURE -EYE CONTACT:Under normal use conditions, this product is not expected to cause adverse
health effects. Direct eye contact may cause irritation.
EFFECT OF OVEREXPOSURE -INGESTION:Under normal use conditions, this product is not expected to cause adverse health
effects. Single dose oral toxicity is very low. Amounts ingested incidental to industrial handling are not likely to cause injury; however,
ingestion of large amounts may cause injury.
CARCINOGENICITY:No Information
EFFECT OF OVEREXPOSURE -CHRONIC HAZARDS:Repeated or prolonged exposure may cause mild irritation of eyes and skin. The International Agency for Research on Cancer (IARC) has determined that crystalline silica in the form of quartz or
cristobalite that is inhaled from occupational sources is carcinogenic to humans (Group 1-carcinogenic to humans). Refer to IARC
Monograph 68, Silica, Some Silicates and Organic Fibres (published in June 1997) in conjunction with the use of these materials. The
National Toxicology Program (NTP) classifies respirable crystalline silica as "known to be a human carcinogen". Refer to the 9th
Report on Carcinogens (2000). The American Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (Group A2). Breathing dust containing respirable crystalline silica may not cause
noticeable injury or illness even though permanent lung damage may be occurring. Inhalation of dust may have the following serious
chronic health effects: Excessive inhalation of respirable dust can cause pneumoconiosis, a respiratory disease, which can result in
delayed, progressive, disabling and sometimes fatal lung injury. Symptoms include cough, shortness of breath, wheezing, non-
specific chest illness and reduced pulmonary function. Smoking exacerbates this disease. Individuals with pneumoconiosis are predisposed to develop tuberculosis. There is some evidence that breathing respirable crystalline silica or the disease silicosis is
associated with an increased incidence of significant disease endpoints such as scleroderma (an immune system disorder manifested
by fibrosis of the lungs, skin and other internal organs) and kidney disease.
PRIMARY ROUTE(S) OF ENTRY:Skin Contact, Inhalation
Acute Toxicity Values
The acute effects of this product have not been tested. Data on individual components are tabulated below
CAS-No.Chemical Name Oral LD50 Dermal LD50 Vapor LC50
1317-65-3 Limestone 6450 mg/kg Rat >2000 mg/kg >20 mg/L
72623-86-0 Lubricating petroleum oil >5000 mg/kg Rat >2000 mg/kg Rabbit N.I.
64741-88-4 Petroleum distillates >5000 mg/kg Rat >2000 mg/kg Rabbit N.I.
120-55-8 Diethylene glycol dibenzoate 2830 mg/kg Rat 2000 mg/kg Rabbit >200 mg/L Rat
27138-31-4 Dipropylene glycol dibenzoate 5368 mg/kg Rat >2000 mg/kg Rabbit >200 mg/L Rat
14808-60-7 Quartz N.I.>2000 mg/kg >20 mg/L
13463-67-7 Titanium dioxide >10000 mg/kg Rat >5000 mg/kg Rabbit >20 mg/L
N.I. = No Information
12. Ecological Information
ECOLOGICAL INFORMATION:Ecological injuries are not known or expected under normal use.
13. Disposal Information
DISPOSAL INFORMATION:This product does not meet the definition of a hazardous waste according to U.S. EPA Hazardous
Waste Management Regulation, 40 CFR Section 261. Dispose as hazardous waste according to all local, state, federal and provincial
regulations. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper
waste disposal is with the owner of the waste.
14. Transport Information
SPECIAL TRANSPORT PRECAUTIONS:No Information
DOT UN/NA Number:N.A.
DOT Proper Shipping Name:Not RegulatedDOT Technical Name:N.A.
DOT Hazard Class:N.A.
Hazard SubClass:N.A.
Packing Group:N.A.
Page 4 / 6
SDS Number: 00010011001 Revision Date: 12/6/2018SAP Number:
15. Regulatory Information
SARA SECTION 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Sara 313 components exist in this product.
TOXIC SUBSTANCES CONTROL ACT:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported fromthe United States:
No TSCA 12(b) components exist in this product.
16. Other Information
Supersedes Date:9/11/2018Revision Date:12/6/2018
Reason for revision:Product Composition Changed
Substance and/or Product Properties Changed in Section(s):
05 - Flammability Information
08 - Exposure Controls/Personal Protection 09 - Physical & Chemical Information
11 - Toxicological Information
13 - Disposal Information
14 - Transportation Information
Datasheet produced by:Regulatory Department
HMIS Ratings:
Health:Flammability:Reactivity:Personal Protection:
1 0 0 X
VOC Less Water Less Exempt Solvent, g/L:57.8
VOC Material, g/L:37
1.0VOC as Defined by California Consumer Product Regulation, Wt/Wt%:
VOC Actual, Wt/Wt%:2.4
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H332 Harmful if inhaled.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS07
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
Page 5 / 6
SDS Number: 00010011001 Revision Date: 12/6/2018SAP Number:
DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this
document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly
trained person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific
context of the intended use and (ii) determine if they are appropriate.
Page 6 / 6
PrepRite® ProBlock® Interior/Exterior Latex Primer/Sealer
White
Not available.
Liquid.
US / Canada: (216) 566-2917
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
B51W620
B51W620Product code :
Product Information
Telephone Number
:US / Canada: 1-800-474-3794
Mexico: Not Available
Regulatory Information
Telephone Number
:US / Canada: (216) 566-2902
Mexico: Not Available
Transportation Emergency
Telephone Number
:US / Canada: (800) 424-9300
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
Section 2. Hazards identification
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (lungs) - Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard pictograms :
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Do not breathe vapor. Do not eat, drink or smoke when using
this product. Wash hands thoroughly after handling.
GHS label elements
General :Read label before use. Keep out of reach of children. If medical advice is needed,
have product container or label at hand.
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Suspected of causing cancer.
Causes damage to organs through prolonged or repeated exposure. (lungs)
:Hazard statements
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Section 2. Hazards identification
Response :Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention.
Storage :Store locked up.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
WARNING: This product contains chemicals known to the State of California to cause
cancer and birth defects or other reproductive harm. Adequate ventilation required when
sanding or abrading the dried film. If Adequate ventilation cannot be provided wear an
approved particulate respirator (NIOSH approved). Follow respirator manufacturer's
directions for respirator use. DELAYED EFFECTS FROM LONG TERM
OVEREXPOSURE. Abrading or sanding of the dry film may release Crystalline Silica
which has been shown to cause lung damage and cancer under long term exposure.
:
Section 3. Composition/information on ingredients
Titanium Dioxide ≥10 - ≤25 13463-67-7
Talc ≤10 14807-96-6
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place
in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
:
:
:
Description of necessary first aid measures
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Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Ingestion :
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
metal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
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Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination. See Section 10 for
incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not ingest. If during normal use the material presents a respiratory
hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Empty containers retain product residue and can be
hazardous. Do not reuse container.
:
Precautions for safe handling
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Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 3/2018).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 15 mg/m³ 8 hours. Form: Total dust
Talc 14807-96-6 NIOSH REL (United States, 10/2016).
TWA: 2 mg/m³ 10 hours. Form: Respirable
fraction
ACGIH TLV (United States, 3/2018).
TWA: 2 mg/m³ 8 hours. Form: Respirable
fraction
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada,
7/2018).
TWA: 3 mg/m³ 8 hours. Form: Respirable
dust
TWA: 10 mg/m³ 8 hours. Form: Total dust
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 10 mg/m³ 8 hours. Form: Total dust.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 10 mg/m³ 8 hours.
CA Ontario Provincial (Canada, 1/2018).
TWA: 10 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 20 mg/m³ 15 minutes.
TWA: 10 mg/m³ 8 hours.
Talc (none asbestiform)14807-96-6 CA British Columbia Provincial (Canada,
7/2018).
TWA: 2 mg/m³ 8 hours. Form: Respirable
TWA: 0.1 f/cc 8 hours.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 3 mg/m³ 8 hours. Form: Respirable
dust.
CA Ontario Provincial (Canada, 1/2018).
TWA: 2 mg/m³ 8 hours. Form: Respirable
fraction.
TWA: 2 f/cc 8 hours.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 2 mg/m³ 8 hours. Form:
Respirable particulate
CA Saskatchewan Provincial (Canada,
7/2013).
TWA: 2 mg/m³ 8 hours. Form: respirable
fraction
Ingredient name Exposure limits
Occupational exposure limits (Canada)
None.
Exposure limits
Occupational exposure limits (Mexico)
CAS #
CAS #
CAS #
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Environmental exposure
controls
:
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Liquid.
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate 0.09 (butyl acetate = 1)
Flash point Closed cup: >94°C (>201.2°F)
8.8
Not available.Odor threshold
:
:
:
:
:
:
:
:
Appearance
Boiling point/boiling range :100°C (212°F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
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Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
Solubility
1.31
1 [Air = 1]
2.3 kPa (17.5 mm Hg) [at 20°C]
Not available.
Auto-ignition temperature Not available.
Not available.
Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
Decomposition temperature :Not available.
Heat of combustion :0.514 kJ/g
Aerosol product
Molecular weight :Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Not available.
Carcinogenicity
Not available.
Mutagenicity
Not available.
Irritation/Corrosion
Titanium Dioxide Skin - Mild irritant Human -72 hours 300
Micrograms
Intermittent
-
Talc Skin - Mild irritant Human -72 hours 300
Micrograms
Intermittent
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
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Section 11. Toxicological information
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Name Category
Talc Category 1 Inhalation lungs
Aspiration hazard
Not available.
Route of
exposure
Target organs
Classification
Titanium Dioxide -2B -
Talc -3 -
Product/ingredient name NTPIARCOSHA
Not available.
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Causes damage to organs through prolonged or repeated exposure.General :
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects :Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects :Not available.
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Section 11. Toxicological information
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Section 12. Ecological information
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Not available.
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
:Disposal methods
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Section 14. Transport information
-
-
-
-
-
-
Not regulated.Not regulated.
--
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No.No.
Not available.
:
Proper shipping name :
Ship type :Not available.
Pollution category :Not available.
Not available.
:
TDG
Classification
Not regulated.
-
-
-
No.
-
Mexico
Classification
Not regulated.
-
-
-
No.
-
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
IATA
Not regulated.
-
-
-
No.
-
Section 15. Regulatory information
SARA 313
TSCA 5(a)2 proposed significant new use rules: 5-Chloro-2-methylisothiazolinone
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
Australia inventory (AICS): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
International regulations
International lists :
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Section 15. Regulatory information
Vietnam inventory: Not determined.
Section 16. Other information
10/7/2019
History
Date of printing
Date of issue/Date of
revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
Key to abbreviations :
10/7/2019
7/1/2019
17.01
Hazardous Material Information System (U.S.A.)
3
0
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
CARCINOGENICITY - Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (lungs) - Category
1
Calculation method
Procedure used to derive the classification
Classification Justification
Notice to reader
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Date of issue/Date of revision :10/7/2019 Date of previous issue :7/1/2019 Version :17.01 11/12
B51W620 PrepRite® ProBlock® Interior/Exterior Latex Primer/Sealer
White
SHW-85-NA-GHS-US
Section 16. Other information
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Date of issue/Date of revision :10/7/2019 Date of previous issue :7/1/2019 Version :17.01 12/12
B51W620 PrepRite® ProBlock® Interior/Exterior Latex Primer/Sealer
White
SHW-85-NA-GHS-US
CASHMERE® Interior Acrylic Latex Medium Lustre
Deep Base
Not available.
Liquid.
US / Canada: (216) 566-2917
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
D18W153
D18W153Product code :
Product Information
Telephone Number
:US / Canada: Not Available
Mexico: Not Available
Regulatory Information
Telephone Number
:US / Canada: (216) 566-2902
Mexico: Not Available
Transportation Emergency
Telephone Number
:US / Canada: (800) 424-9300
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
Section 2. Hazards identification
CARCINOGENICITY - Category 2Classification of the
substance or mixture
:
Signal word :Warning
Hazard pictograms :
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing.
Response :IF exposed or concerned: Get medical attention.
Storage :Store locked up.
GHS label elements
General :Read label before use. Keep out of reach of children. If medical advice is needed,
have product container or label at hand.
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Suspected of causing cancer.:Hazard statements
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Section 2. Hazards identification
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
WARNING: This product contains chemicals known to the State of California to cause
cancer.
:
Section 3. Composition/information on ingredients
Calcium Carbonate ≤5 1317-65-3
Titanium Dioxide ≤5 13463-67-7
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place
in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Potential acute health effects
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Section 4. First aid measures
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
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Section 6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination. See Section 10 for
incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not ingest.
Avoid breathing vapor or mist. If during normal use the material presents a respiratory
hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Empty containers retain product residue and can be
hazardous. Do not reuse container.
:
Precautions for safe handling
Calcium Carbonate 1317-65-3 OSHA PEL (United States, 5/2018).
TWA: 5 mg/m³ 8 hours. Form: Respirable
fraction
TWA: 15 mg/m³ 8 hours. Form: Total dust
NIOSH REL (United States, 10/2016).
TWA: 5 mg/m³ 10 hours. Form: Respirable
fraction
TWA: 10 mg/m³ 10 hours. Form: Total
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
CAS #
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Section 8. Exposure controls/personal protection
Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 3/2018).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 15 mg/m³ 8 hours. Form: Total dust
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Limestone 1317-65-3 CA British Columbia Provincial (Canada,
7/2018).
TWA: 3 mg/m³ 8 hours. Form: Respirable
dust
TWA: 10 mg/m³ 8 hours. Form: Total dust
STEL: 20 mg/m³ 15 minutes.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 10 mg/m³ 8 hours.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 10 mg/m³ 8 hours. Form: Total dust.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 20 mg/m³ 15 minutes.
TWA: 10 mg/m³ 8 hours.
Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada,
7/2018).
TWA: 3 mg/m³ 8 hours. Form: Respirable
dust
TWA: 10 mg/m³ 8 hours. Form: Total dust
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 10 mg/m³ 8 hours. Form: Total dust.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 10 mg/m³ 8 hours.
CA Ontario Provincial (Canada, 1/2018).
TWA: 10 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 20 mg/m³ 15 minutes.
TWA: 10 mg/m³ 8 hours.
Ingredient name Exposure limits
Occupational exposure limits (Canada)
Environmental exposure
controls
:
None.
Exposure limits
Occupational exposure limits (Mexico)
CAS #
CAS #
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.11
1 [Air = 1]
2.3 kPa (17.5 mm Hg) [at 20°C]
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate 0.09 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: >94°C (>201.2°F)
Not available.
9
Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point/boiling range :100°C (212°F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
Heat of combustion :1.476 kJ/g
Aerosol product
Molecular weight :Not applicable.
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Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Not available.
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Titanium Dioxide Skin - Mild irritant Human -72 hours 300
Micrograms
Intermittent
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Calcium Carbonate Category 3 Not applicable.Respiratory tract
irritation
Name Category
Not available.
Route of
exposure
Target organs
Information on toxicological effects
Classification
Titanium Dioxide -2B -
Product/ingredient name NTPIARCOSHA
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Section 11. Toxicological information
Aspiration hazard
Not available.
Not available.
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
No known significant effects or critical hazards.General :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Not available.
Acute toxicity estimates
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects :Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects :Not available.
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Section 12. Ecological information
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Not available.
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
:Disposal methods
Section 14. Transport information
-
-
-
-
-
-
Not regulated.Not regulated.
--
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
No.No.
TDG
Classification
Not regulated.
-
-
-
No.
-
Mexico
Classification
Not regulated.
-
-
-
No.
-
IATA
Not regulated.
-
-
-
No.
-
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Section 14. Transport information
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
Not available.
:
Proper shipping name :
Ship type :Not available.
Pollution category :Not available.
Not available.
:Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
Section 15. Regulatory information
SARA 313
TSCA 5(a)2 proposed significant new use rules: 5-Chloro-2-methylisothiazolinone
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer.
California Prop. 65
Australia inventory (AICS): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
International regulations
International lists :
Section 16. Other information
Hazardous Material Information System (U.S.A.)
2
0
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Procedure used to derive the classification
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Section 16. Other information
8/31/2019
History
Date of printing
Date of issue/Date of
revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
Key to abbreviations :
8/31/2019
6/22/2019
11
CARCINOGENICITY - Category 2 Calculation method
Classification Justification
Notice to reader
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
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3M Brand Fire Barrier CP-25WB+ 10/03/19
__________________________________________________________________________________________
Page 1 of 12
Safety Data Sheet
Copyright,2019,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:09-5451-1 Version Number:26.06
Issue Date:10/03/19 Supercedes Date:02/22/19
SECTION 1: Identification
1.1. Product identifier
3M Brand Fire Barrier CP-25WB+
Product Identification Numbers
ID Number UPC ID Number UPC
42-0016-4710-8 42-0016-4715-7
42-0016-4716-5 98-0400-5380-7 00-51115-11639-1
98-0400-5381-5 00-51115-11640-7 98-0400-5382-3 00-51115-11641-4
98-0400-5383-1 00-51115-11642-1 98-0400-5406-0 00-51115-16515-3
98-0400-5456-5 98-0400-5562-0 000-51115-11642-1
98-0400-5573-7 000-51115-16515-3 98-0400-5610-7
98-0400-5629-7
7100006311, 7000006379, 7000059394, 7000145569, 7100025518, 7000006383, 7010353050, 7100137423
1.2. Recommended use and restrictions on use
Recommended use
Fire Protection, Used as Firestop in buildings.
1.3. Supplier’s details
MANUFACTURER:3M
DIVISION:Industrial Adhesives and Tapes Division
ADDRESS:3M Center, St. Paul, MN 55144-1000, USA
Telephone:1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
2.1. Hazard classification
Serious Eye Damage/Irritation: Category 2A.
Reproductive Toxicity: Category 2.
2.2. Label elements
3M Brand Fire Barrier CP-25WB+ 10/03/19
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Signal word
Warning
Exclamation mark | Health Hazard |
Causes serious eye irritation.
Suspected of damaging fertility or the unborn child.
Keep out of reach of children.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Wear protective gloves and eye/face protection.
Wash thoroughly after handling.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF exposed or concerned: Get medical advice/attention.
Store locked up.
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
SECTION 3: Composition/information on ingredients
Water 7732-18-5 10 - 30 Trade Secret *
Zinc Borate 2335 138265-88-0 10 - 30 Trade Secret *
Polymer (NJTS Reg. No. 04499600-7270)Trade Secret* 10 - 30 Trade Secret *
Sodium Silicate 1344-09-8 10 - 19 Trade Secret *
Ethylhexyldiphenyl phosphate 1241-94-7 3 - 7 Trade Secret *
Iron oxide 1309-37-1 1 - 5 Trade Secret *
Oxide glass chemicals 65997-17-3 1 5 Trade Secret *
Polyethylene Glycol 25322-68-3 1 - 5 Trade Secret *
Quartz Silica 14808-60-7 < 1 Trade Secret *
NJTS or NJTSRN: New Jersey Trade Secret Registry Number.
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*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Skin Contact:
Eye Contact:
If Swallowed:
4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment required
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
5.2. Special hazards arising from the substance or mixture
Hazardous Decomposition or By-Products
Substance Condition
5.3. Special protective actions for fire-fighters
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.2. Environmental precautions
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6.3. Methods and material for containment and cleaning up
Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate
authorities. Clean up residue. Seal the container. Dispose of collected material as soon as possible in accordance with
applicable local/regional/national/international regulations.
SECTION 7: Handling and storage
Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Avoid breathing
dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this
product. Wash thoroughly after handling. Avoid release to the environment. Use personal protective equipment (gloves,
respirators, etc.) as required.
Keep cool. Store away from heat. Store away from areas where product may come into contact with food or
pharmaceuticals. Store in a dry place.
SECTION 8: Exposure controls/personal protection
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
DUST, INERT OR NUISANCE 1309-37-1 OSHA TWA(as total dust):15
mg/m3;TWA(as total dust):50
millions of particles/cu. ft.(15
mg/m3);TWA(respirable
fraction):15 millions of
particles/cu. ft.(5
mg/m3);TWA(respirable
fraction):5 mg/m3
Iron oxide 1309-37-1 ACGIH TWA(respirable fraction):5
mg/m3
A4: Not class. as human
carcin
Iron oxide 1309-37-1 OSHA TWA(as fume):10 mg/m3
ROUGE 1309-37-1 OSHA TWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
Quartz Silica 14808-60-7 ACGIH TWA(respirable
fraction):0.025 mg/m3
A2: Suspected human
carcin.
Quartz Silica 14808-60-7 OSHA TWA Table Z-
1(respirable):0.05
mg/m3;TWA Table Z-
3(respirable):0.1 mg/m3
Polyethylene Glycol 25322-68-3 AIHA TWA(as aerosol):10 mg/m3
Oxide glass chemicals 65997-17-3 Manufacturer
determined
TWA(as non-fibrous, inhalable
fraction)(8 hours):10
mg/m3;TWA(as non-fibrous,
respirable)(8 hours):3 mg/m3
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
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STEL: Short Term Exposure Limit
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Butyl Rubber
Neoprene
Nitrile Rubber
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
Physical state
Color
Solid
Red
Specific Physical Form: Paste
Odor Odorless
Odor threshold No Data Available
pH 7.5 - 8
Melting point No Data Available
Boiling Point 100 ºC
Flash Point No flash point
Evaporation rate 0.33 [Ref Std:BUOAC=1]
Flammability (solid, gas)Not Classified
Flammable Limits(LEL)Not Applicable
Flammable Limits(UEL)Not Applicable
Vapor Pressure 17.5 mmHg [@ 20 ºC]
Vapor Density No Data Available
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Density No Data Available
Specific Gravity 1.35 [Ref Std:WATER=1]
Solubility in Water Complete
Solubility- non-water No Data Available
Partition coefficient: n-octanol/ water No Data Available
Autoignition temperature Not Applicable
Decomposition temperature No Data Available
Viscosity No Data Available
Molecular weight No Data Available
Volatile Organic Compounds <=0.5 % weight [Test Method:tested per EPA method 24]
VOC Less H2O & Exempt Solvents <=6 g/l [Test Method:tested per EPA method 24]
SECTION 10: Stability and reactivity
10.1. Reactivity
This material is considered to be non reactive under normal use conditions.
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
None known.
10.5. Incompatible materials
None known.
10.6. Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
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Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Ingestion:
May be harmful if swallowed.
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May cause additional health effects (see below).
Additional Health Effects:
Reproductive/Developmental Toxicity:
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
Carcinogenicity:
Ingredient CAS No.Class Description Regulation
SILICA, CRYS AIRRESP 14808-60-7 Known human carcinogen National Toxicology Program Carcinogens
Quartz Silica 14808-60-7 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Dermal No data available; calculated ATE >5,000 mg/kg
Overall product Ingestion No data available; calculated ATE2,000 - 5,000 mg/kg
Zinc Borate 2335 Dermal Rabbit LD50 > 5,000 mg/kg
Zinc Borate 2335 Inhalation-
Dust/Mist
Rat LC50 > 4.95 mg/l
Zinc Borate 2335 Ingestion Rat LD50 > 5,000 mg/kg
Polymer (NJTS Reg. No. 04499600-7270)Dermal LD50 estimated to be > 5,000 mg/kg
Polymer (NJTS Reg. No. 04499600-7270)Ingestion Rat LD50 > 2,000 mg/kg
Sodium Silicate Dermal Rabbit LD50 > 4,640 mg/kg
Sodium Silicate Ingestion Rat LD50 500 mg/kg
Ethylhexyldiphenyl phosphate Dermal Rabbit LD50 > 7,940 mg/kg
Ethylhexyldiphenyl phosphate Ingestion Rat LD50 > 24,000 mg/kg
Iron oxide Dermal Not
available
LD50 3,100 mg/kg
Iron oxide Ingestion Not
available
LD50 3,700 mg/kg
Polyethylene Glycol Dermal Rabbit LD50 > 20,000 mg/kg
Polyethylene Glycol Ingestion Rat LD50 32,770 mg/kg
Oxide glass chemicals Dermal LD50 estimated to be > 5,000 mg/kg
Oxide glass chemicals Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg
Quartz Silica Dermal LD50 estimated to be > 5,000 mg/kg
Quartz Silica Ingestion LD50 estimated to be > 5,000 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
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Zinc Borate 2335 Rabbit No significant irritation
Polymer (NJTS Reg. No. 04499600-7270)Rabbit Minimal irritation
Sodium Silicate Rabbit Corrosive
Iron oxide Rabbit No significant irritation
Polyethylene Glycol Rabbit Minimal irritation
Oxide glass chemicals Professio
nal
judgeme
nt
No significant irritation
Quartz Silica Professio
nal
judgeme
nt
No significant irritation
Serious Eye Damage/Irritation
Name Species Value
Zinc Borate 2335 Rabbit Severe irritant
Polymer (NJTS Reg. No. 04499600-7270)Professio
nal
judgeme
nt
Mild irritant
Sodium Silicate Rabbit Corrosive
Iron oxide Rabbit No significant irritation
Polyethylene Glycol Rabbit Mild irritant
Oxide glass chemicals Professio
nal
judgeme
nt
No significant irritation
Skin Sensitization
Name Species Value
Zinc Borate 2335 Guinea
pig
Not classified
Sodium Silicate Mouse Not classified
Iron oxide Human Not classified
Polyethylene Glycol Guinea
pig
Not classified
Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell Mutagenicity
Name Route Value
Zinc Borate 2335 In Vitro Some positive data exist, but the data are not
sufficient for classification
Sodium Silicate In Vitro Not mutagenic
Sodium Silicate In vivo Not mutagenic
Iron oxide In Vitro Not mutagenic
Polyethylene Glycol In Vitro Not mutagenic
Polyethylene Glycol In vivo Not mutagenic
Oxide glass chemicals In Vitro Some positive data exist, but the data are not
sufficient for classification
Quartz Silica In Vitro Some positive data exist, but the data are not
sufficient for classification
Quartz Silica In vivo Some positive data exist, but the data are not
sufficient for classification
Carcinogenicity
Name Route Species Value
Iron oxide Inhalation Human Some positive data exist, but the data are not
sufficient for classification
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Polyethylene Glycol Ingestion Rat Not carcinogenic
Oxide glass chemicals Inhalation Multiple
animal
species
Some positive data exist, but the data are not
sufficient for classification
Quartz Silica Inhalation Human
and
animal
Carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test Result Exposure
Duration
Zinc Borate 2335 Ingestion Toxic to male reproduction Rat NOAEL 100
mg/kg/day
92 days
Zinc Borate 2335 Ingestion Toxic to development Rat LOAEL 100
mg/kg/day
during
gestation
Sodium Silicate Ingestion Not classified for development Mouse NOAEL 200
mg/kg/day
during
gestation
Polyethylene Glycol Ingestion Not classified for female reproduction Rat NOAEL 1,125
mg/kg/day
during
gestation
Polyethylene Glycol Ingestion Not classified for male reproduction Rat NOAEL 5699
+/- 1341
mg/kg/day
5 days
Polyethylene Glycol Not
Specified
Not classified for reproduction and/or
development
NOEL N/A
Polyethylene Glycol Ingestion Not classified for development Mouse NOAEL 562
mg/animal/da
y
during
gestation
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s)Value Species Test Result Exposure
Duration
Zinc Borate 2335 Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
similar
health
hazards
NOAEL Not
available
Sodium Silicate Inhalation respiratory irritation May cause respiratory irritation official
classifica
tion
NOAEL Not
available
Polyethylene Glycol Inhalation respiratory irritation Not classified Rat NOAEL
1.008 mg/l
2 weeks
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s)Value Species Test Result Exposure
Duration
Zinc Borate 2335 Inhalation immune system |
respiratory system |
heart | endocrine
system |
hematopoietic
system | liver |
nervous system |
kidney and/or
bladder
Not classified Rat NOAEL 0.15
mg/l
2 weeks
Zinc Borate 2335 Ingestion endocrine system |
liver | kidney and/or
bladder | heart | skin
| bone, teeth, nails,
and/or hair |
hematopoietic
system | immune
system | nervous
system | eyes |
Not classified Rat NOAEL 375
mg/kg/day
92 days
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respiratory system |
vascular system
Sodium Silicate Ingestion kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Dog LOAEL
2,400
mg/kg/day
4 weeks
Sodium Silicate Ingestion endocrine system |
blood
Not classified Rat NOAEL 804
mg/kg/day
3 months
Sodium Silicate Ingestion heart | liver Not classified Rat NOAEL
1,259
mg/kg/day
8 weeks
Iron oxide Inhalation pulmonary fibrosis |
pneumoconiosis
Not classified Human NOAEL Not
available
occupational
exposure
Polyethylene Glycol Inhalation respiratory system Not classified Rat NOAEL
1.008 mg/l
2 weeks
Polyethylene Glycol Ingestion kidney and/or
bladder | heart |
endocrine system |
hematopoietic
system | liver |
nervous system
Not classified Rat NOAEL
5,640
mg/kg/day
13 weeks
Oxide glass chemicals Inhalation respiratory system Not classified Human NOAEL not
available
occupational
exposure
Quartz Silica Inhalation silicosis Causes damage to organs through
prolonged or repeated exposure
Human NOAEL Not
available
occupational
exposure
Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
Test Organism Test Type Result
Water flea, Daphnia magna 48 hours Aquatic Toxicity - Acute 27 mg/l
Green algae, Pseudokirchneriella subcapitata 72 hours Aquatic Toxicity - Chronic 2.6 mg/l
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste
incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty
drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations
classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes
unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the
available treatment and disposal facilities.
SECTION 14: Transport Information
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SECTION 15: Regulatory information
15.1. US Federal Regulations
EPCRA 311/312 Hazard Classifications:
Physical Hazards
Health Hazards
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
Zinc Borate 2335 (ZINC COMPOUNDS) 138265-88-0 10 - 30
15.2. State Regulations
15.3. Chemical Inventories
15.4. International Regulations
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 2 Flammability: 1 Instability: 0 Special Hazards: None
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the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
Document Group:Version Number:
Issue Date:Supercedes Date:
3M USA SDSs are available at www.3M.com
Appendix E
Laboratory Analytical Reports
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
5/4/2021
Hart & Hickman (Charlotte) Andrew Besu
2923 South Tryon St. Ste 100 Charlotte, NC, 28203
Ref: Analytical Testing
Revised Lab Report Number: 21-098-0043 Client Project Description: FZR-001
Dear Andrew Besu:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 4/8/2021 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2012) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely,
Angela D Overcash Senior Project Manager
Page 1 of 18
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202137735State ProgramNorth Carolina
12/31/2021402State ProgramNorth Carolina
07/31/202199012State ProgramSouth Carolina
12/31/202199012State ProgramSouth Carolina
Page 1 of 1 00016/21-098-0043
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Report Number:
Sample Summary Table
Client Project Description:
21-098-0043
FZR-001
Lab No Client Sample ID Matrix Date Collected Date Received
04/07/2021 08:57Air 96350 BAS-1 04/08/2021 16:40
04/07/2021 08:50Air 96351 IAS-1 04/08/2021 16:40
04/07/2021Air 96352 IAS-DUP 04/08/2021 16:40
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Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
21-098-0043
Report Limit
Project:FZR-001
V 96350BAS-1
132 04/13/2021 04:17TO-15 Acetone µg/m3 2.97
J0.645 04/10/2021 01:33TO-15 Benzene µg/m3 0.160
5.95 04/10/2021 01:33TO-15 Dichlorodifluoromethane µg/m3 0.410
50.8 04/10/2021 01:33TO-15 Ethanol µg/m3 2.50
5.30 04/10/2021 01:33TO-15 Ethyl Acetate µg/m3 0.249
30.0 04/10/2021 01:33TO-15 Isopropyl Alchohol µg/m3 0.167
42.6 04/10/2021 01:33TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.295
6.43 04/10/2021 01:33TO-15 4-Methyl-2-Pentanone µg/m3 0.254
12.1 04/10/2021 01:33TO-15 Propene µg/m3 0.139
4.98 04/10/2021 01:33TO-15 Toluene µg/m3 0.754
J2.95 04/10/2021 01:33TO-15 m,p-Xylene µg/m3 0.384
V 96351IAS-1
149 04/13/2021 04:53TO-15 Acetone µg/m3 11.9
J1.27 04/10/2021 02:18TO-15 Benzene µg/m3 0.160
J1.03 04/10/2021 02:18TO-15 Chloroform µg/m3 0.264
2.25 05/04/2021 10:39TO-15 Chloromethane µg/m3 0.268
J1.43 04/10/2021 02:18TO-15 Cyclohexane µg/m3 0.861
5.87 05/04/2021 10:39TO-15 Dichlorodifluoromethane µg/m3 0.410
523 04/13/2021 04:53TO-15 Ethanol µg/m3 6.39
7.78 05/04/2021 10:39TO-15 Ethyl Acetate µg/m3 0.249
J1.45 04/10/2021 02:18TO-15 Ethylbenzene µg/m3 0.187
2.11 05/04/2021 10:39TO-15 Heptane µg/m3 0.193
J75.0 04/13/2021 04:53TO-15 Isopropyl Alchohol µg/m3 3.34
56.7 05/04/2021 10:39TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.295
4.99 05/04/2021 10:39TO-15 4-Methyl-2-Pentanone µg/m3 0.254
3.38 05/04/2021 10:39TO-15 Methylene Chloride µg/m3 0.383
2.19 05/04/2021 10:39TO-15 Styrene µg/m3 0.149
43.0 05/04/2021 10:39TO-15 Toluene µg/m3 0.754
43.8 05/04/2021 10:39TO-15 1,2,4-Trimethylbenzene µg/m3 0.295
16.1 05/04/2021 10:39TO-15 1,3,5-Trimethylbenzene µg/m3 0.261
2.42 05/04/2021 10:39TO-15 o-Xylene µg/m3 0.182
J5.52 05/04/2021 10:39TO-15 m,p-Xylene µg/m3 0.384
V 96352IAS-DUP
146 04/13/2021 05:30TO-15 Acetone µg/m3 11.9
J1.32 04/10/2021 03:03TO-15 Benzene µg/m3 0.160
J1.06 04/10/2021 03:03TO-15 Chloroform µg/m3 0.264
Page 4 of 18
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
21-098-0043
Report Limit
Project:FZR-001
V 96352IAS-DUP
J1.38 04/10/2021 03:03TO-15 Cyclohexane µg/m3 0.861
5.51 04/10/2021 03:03TO-15 Dichlorodifluoromethane µg/m3 0.410
525 04/13/2021 05:30TO-15 Ethanol µg/m3 6.39
7.12 04/10/2021 03:03TO-15 Ethyl Acetate µg/m3 0.249
J1.52 04/10/2021 03:03TO-15 Ethylbenzene µg/m3 0.187
J1.89 04/10/2021 03:03TO-15 Heptane µg/m3 0.193
J77.9 04/13/2021 05:30TO-15 Isopropyl Alchohol µg/m3 3.34
50.0 04/10/2021 03:03TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.295
4.85 04/10/2021 03:03TO-15 4-Methyl-2-Pentanone µg/m3 0.254
3.47 04/10/2021 03:03TO-15 Methylene Chloride µg/m3 0.383
2.39 04/10/2021 03:03TO-15 Styrene µg/m3 0.149
J1.91 04/10/2021 03:03TO-15 Tetrachloroethene µg/m3 0.441
43.0 04/10/2021 03:03TO-15 Toluene µg/m3 0.754
54.4 04/10/2021 03:03TO-15 1,2,4-Trimethylbenzene µg/m3 0.295
19.9 04/10/2021 03:03TO-15 1,3,5-Trimethylbenzene µg/m3 0.261
2.59 04/10/2021 03:03TO-15 o-Xylene µg/m3 0.182
5.71 04/10/2021 03:03TO-15 m,p-Xylene µg/m3 0.384
Page 5 of 18
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
21-098-0043
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Andrew Besu
Charlotte
Received : 04/08/2021
FZR-001
Revised Report Date: 05/04/2021
Original Report Date : 04/15/2021
Sample ID :
Lab No :
Sampled:BAS-1
96350 Matrix:
4/7/2021 8:57
Air
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
TO-15 Prep
TO-15 Prep Batch(es):V2869 04/09/21 09:00 V3110 04/12/21 09:00
132 µg/m3 2.97 11.9Acetone 5 04/13/21 04:17 V3112CBM
0.645 J µg/m3 0.160 1.60Benzene 1 04/10/21 01:33 V2870CBM
<0.195 µg/m3 0.195 1.111,3-Butadiene 1 04/10/21 01:33 V2870CBM
<1.56 µg/m3 1.56 6.23Carbon Disulfide 1 04/10/21 01:33 V2870CBM
<0.239 µg/m3 0.239 3.15Carbon Tetrachloride 1 04/10/21 01:33 V2870CBM
<0.396 µg/m3 0.396 1.32Chloroethane 1 04/10/21 01:33 V2870CBM
<0.264 µg/m3 0.264 2.44Chloroform 1 04/10/21 01:33 V2870CBM
<0.268 µg/m3 0.268 1.03Chloromethane 1 04/10/21 01:33 V2870CBM
<0.861 µg/m3 0.861 3.44Cyclohexane 1 04/10/21 01:33 V2870CBM
<0.217 µg/m3 0.217 3.011,3-Dichlorobenzene 1 04/10/21 01:33 V2870CBM
5.95 µg/m3 0.410 2.47Dichlorodifluoromethane 1 04/10/21 01:33 V2870CBM
<0.402 µg/m3 0.402 2.311,2-Dichloropropane 1 04/10/21 01:33 V2870CBM
50.8 µg/m3 2.50 5.00Ethanol 1 04/10/21 01:33 V2870CBM
5.30 µg/m3 0.249 1.80Ethyl Acetate 1 04/10/21 01:33 V2870CBM
<0.187 µg/m3 0.187 2.17Ethylbenzene 1 04/10/21 01:33 V2870CBM
<0.266 µg/m3 0.266 2.464-Ethyltoluene 1 04/10/21 01:33 V2870CBM
<0.529 µg/m3 0.529 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 04/10/21 01:33 V2870CBM
<0.193 µg/m3 0.193 2.05Heptane 1 04/10/21 01:33 V2870CBM
<0.254 µg/m3 0.254 1.76n-Hexane 1 04/10/21 01:33 V2870CBM
30.0 µg/m3 0.167 4.92Isopropyl Alchohol 1 04/10/21 01:33 V2870CBM
42.6 µg/m3 0.295 1.47Methyl Ethyl Ketone (MEK)1 04/10/21 01:33 V2870CBM
6.43 µg/m3 0.254 2.054-Methyl-2-Pentanone 1 04/10/21 01:33 V2870CBM
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 6 of 18
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
21-098-0043
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Andrew Besu
Charlotte
Received : 04/08/2021
FZR-001
Revised Report Date: 05/04/2021
Original Report Date : 04/15/2021
Sample ID :
Lab No :
Sampled:BAS-1
96350 Matrix:
4/7/2021 8:57
Air
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
TO-15 Prep
TO-15 Prep Batch(es):V2869 04/09/21 09:00 V3110 04/12/21 09:00
<0.383 µg/m3 0.383 1.74Methylene Chloride 1 04/10/21 01:33 V2870CBM
<0.386 µg/m3 0.386 2.62Naphthalene 1 04/10/21 01:33 V2870CBM
12.1 µg/m3 0.139 0.861Propene 1 04/10/21 01:33 V2870CBM
<0.149 µg/m3 0.149 2.13Styrene 1 04/10/21 01:33 V2870CBM
<0.441 µg/m3 0.441 3.39Tetrachloroethene 1 04/10/21 01:33 V2870CBM
4.98 µg/m3 0.754 1.88Toluene 1 04/10/21 01:33 V2870CBM
<0.274 µg/m3 0.274 2.15Trichloroethene 1 04/10/21 01:33 V2870CBM
<0.433 µg/m3 0.433 2.81Trichlorofluoromethane 1 04/10/21 01:33 V2870CBM
<0.295 µg/m3 0.295 2.461,2,4-Trimethylbenzene 1 04/10/21 01:33 V2870CBM
<0.261 µg/m3 0.261 2.461,3,5-Trimethylbenzene 1 04/10/21 01:33 V2870CBM
<0.282 µg/m3 0.282 1.28Vinyl Chloride 1 04/10/21 01:33 V2870CBM
<0.182 µg/m3 0.182 2.17o-Xylene 1 04/10/21 01:33 V2870CBM
2.95 J µg/m3 0.384 5.65m,p-Xylene 1 04/10/21 01:33 V2870CBM
Surrogate: 4-Bromofluorobenzene 81.6 Limits: 70-130%04/10/21 01:331 CBM V2870
Surrogate: 4-Bromofluorobenzene 84.9 Limits: 70-130%04/13/21 04:175 CBM V3112
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 7 of 18
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
21-098-0043
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Andrew Besu
Charlotte
Received : 04/08/2021
FZR-001
Revised Report Date: 05/04/2021
Original Report Date : 04/15/2021
Sample ID :
Lab No :
Sampled:IAS-1
96351 Matrix:
4/7/2021 8:50
Air
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
TO-15 Prep
TO-15 Prep Batch(es):V2869 04/09/21 09:00 V3110 04/12/21 09:00
149 µg/m3 11.9 47.6Acetone 20 04/13/21 04:53 V3112CBM
1.27 J µg/m3 0.160 1.60Benzene 1 04/10/21 02:18 V2870CBM
<0.195 µg/m3 0.195 1.111,3-Butadiene 1 05/04/21 10:39 V2870CBM
<1.56 µg/m3 1.56 6.23Carbon Disulfide 1 05/04/21 10:39 V2870CBM
<0.239 µg/m3 0.239 3.15Carbon Tetrachloride 1 04/10/21 02:18 V2870CBM
<0.396 µg/m3 0.396 1.32Chloroethane 1 05/04/21 10:39 V2870CBM
1.03 J µg/m3 0.264 2.44Chloroform 1 04/10/21 02:18 V2870CBM
2.25 µg/m3 0.268 1.03Chloromethane 1 05/04/21 10:39 V2870CBM
1.43 J µg/m3 0.861 3.44Cyclohexane 1 04/10/21 02:18 V2870CBM
<0.217 µg/m3 0.217 3.011,3-Dichlorobenzene 1 04/10/21 02:18 V2870CBM
5.87 µg/m3 0.410 2.47Dichlorodifluoromethane 1 05/04/21 10:39 V2870CBM
<0.402 µg/m3 0.402 2.311,2-Dichloropropane 1 05/04/21 10:39 V2870CBM
523 µg/m3 6.39 18.8Ethanol 20 04/13/21 04:53 V3112CBM
7.78 µg/m3 0.249 1.80Ethyl Acetate 1 05/04/21 10:39 V2870CBM
1.45 J µg/m3 0.187 2.17Ethylbenzene 1 04/10/21 02:18 V2870CBM
<0.266 µg/m3 0.266 2.464-Ethyltoluene 1 05/04/21 10:39 V2870CBM
<0.529 µg/m3 0.529 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 05/04/21 10:39 V2870CBM
2.11 µg/m3 0.193 2.05Heptane 1 05/04/21 10:39 V2870CBM
<0.254 µg/m3 0.254 1.76n-Hexane 1 04/10/21 02:18 V2870CBM
75.0 J µg/m3 3.34 98.3Isopropyl Alchohol 20 04/13/21 04:53 V3112CBM
56.7 µg/m3 0.295 1.47Methyl Ethyl Ketone (MEK)1 05/04/21 10:39 V2870CBM
4.99 µg/m3 0.254 2.054-Methyl-2-Pentanone 1 05/04/21 10:39 V2870CBM
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 8 of 18
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
21-098-0043
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Andrew Besu
Charlotte
Received : 04/08/2021
FZR-001
Revised Report Date: 05/04/2021
Original Report Date : 04/15/2021
Sample ID :
Lab No :
Sampled:IAS-1
96351 Matrix:
4/7/2021 8:50
Air
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
TO-15 Prep
TO-15 Prep Batch(es):V2869 04/09/21 09:00 V3110 04/12/21 09:00
3.38 µg/m3 0.383 1.74Methylene Chloride 1 05/04/21 10:39 V2870CBM
<0.386 µg/m3 0.386 2.62Naphthalene 1 04/10/21 02:18 V2870CBM
<0.139 µg/m3 0.139 0.861Propene 1 04/10/21 02:18 V2870CBM
2.19 µg/m3 0.149 2.13Styrene 1 05/04/21 10:39 V2870CBM
<0.441 µg/m3 0.441 3.39Tetrachloroethene 1 04/10/21 02:18 V2870CBM
43.0 µg/m3 0.754 1.88Toluene 1 05/04/21 10:39 V2870CBM
<0.274 µg/m3 0.274 2.15Trichloroethene 1 04/10/21 02:18 V2870CBM
<0.433 µg/m3 0.433 2.81Trichlorofluoromethane 1 05/04/21 10:39 V2870CBM
43.8 µg/m3 0.295 2.461,2,4-Trimethylbenzene 1 05/04/21 10:39 V2870CBM
16.1 µg/m3 0.261 2.461,3,5-Trimethylbenzene 1 05/04/21 10:39 V2870CBM
<0.282 µg/m3 0.282 1.28Vinyl Chloride 1 04/10/21 02:18 V2870CBM
2.42 µg/m3 0.182 2.17o-Xylene 1 05/04/21 10:39 V2870CBM
5.52 J µg/m3 0.384 5.65m,p-Xylene 1 05/04/21 10:39 V2870CBM
Surrogate: 4-Bromofluorobenzene 98.3 Limits: 70-130%04/10/21 02:181 CBM V2870
Surrogate: 4-Bromofluorobenzene 91.3 Limits: 70-130%04/13/21 04:5320 CBM V3112
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 9 of 18
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
21-098-0043
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Andrew Besu
Charlotte
Received : 04/08/2021
FZR-001
Revised Report Date: 05/04/2021
Original Report Date : 04/15/2021
Sample ID :
Lab No :
Sampled:IAS-DUP
96352 Matrix:
4/7/2021 0:00
Air
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
TO-15 Prep
TO-15 Prep Batch(es):V2869 04/09/21 09:00 V3110 04/12/21 09:00
146 µg/m3 11.9 47.6Acetone 20 04/13/21 05:30 V3112CBM
1.32 J µg/m3 0.160 1.60Benzene 1 04/10/21 03:03 V2870CBM
<0.195 µg/m3 0.195 1.111,3-Butadiene 1 04/10/21 03:03 V2870CBM
<1.56 µg/m3 1.56 6.23Carbon Disulfide 1 04/10/21 03:03 V2870CBM
<0.239 µg/m3 0.239 3.15Carbon Tetrachloride 1 04/10/21 03:03 V2870CBM
<0.396 µg/m3 0.396 1.32Chloroethane 1 04/10/21 03:03 V2870CBM
1.06 J µg/m3 0.264 2.44Chloroform 1 04/10/21 03:03 V2870CBM
<0.268 µg/m3 0.268 1.03Chloromethane 1 04/10/21 03:03 V2870CBM
1.38 J µg/m3 0.861 3.44Cyclohexane 1 04/10/21 03:03 V2870CBM
<0.217 µg/m3 0.217 3.011,3-Dichlorobenzene 1 04/10/21 03:03 V2870CBM
5.51 µg/m3 0.410 2.47Dichlorodifluoromethane 1 04/10/21 03:03 V2870CBM
<0.402 µg/m3 0.402 2.311,2-Dichloropropane 1 04/10/21 03:03 V2870CBM
525 µg/m3 6.39 18.8Ethanol 20 04/13/21 05:30 V3112CBM
7.12 µg/m3 0.249 1.80Ethyl Acetate 1 04/10/21 03:03 V2870CBM
1.52 J µg/m3 0.187 2.17Ethylbenzene 1 04/10/21 03:03 V2870CBM
<0.266 µg/m3 0.266 2.464-Ethyltoluene 1 04/10/21 03:03 V2870CBM
<0.529 µg/m3 0.529 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 04/10/21 03:03 V2870CBM
1.89 J µg/m3 0.193 2.05Heptane 1 04/10/21 03:03 V2870CBM
<0.254 µg/m3 0.254 1.76n-Hexane 1 04/10/21 03:03 V2870CBM
77.9 J µg/m3 3.34 98.3Isopropyl Alchohol 20 04/13/21 05:30 V3112CBM
50.0 µg/m3 0.295 1.47Methyl Ethyl Ketone (MEK)1 04/10/21 03:03 V2870CBM
4.85 µg/m3 0.254 2.054-Methyl-2-Pentanone 1 04/10/21 03:03 V2870CBM
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 10 of 18
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
21-098-0043
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Andrew Besu
Charlotte
Received : 04/08/2021
FZR-001
Revised Report Date: 05/04/2021
Original Report Date : 04/15/2021
Sample ID :
Lab No :
Sampled:IAS-DUP
96352 Matrix:
4/7/2021 0:00
Air
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
TO-15 Prep
TO-15 Prep Batch(es):V2869 04/09/21 09:00 V3110 04/12/21 09:00
3.47 µg/m3 0.383 1.74Methylene Chloride 1 04/10/21 03:03 V2870CBM
<0.386 µg/m3 0.386 2.62Naphthalene 1 04/10/21 03:03 V2870CBM
<0.139 µg/m3 0.139 0.861Propene 1 04/10/21 03:03 V2870CBM
2.39 µg/m3 0.149 2.13Styrene 1 04/10/21 03:03 V2870CBM
1.91 J µg/m3 0.441 3.39Tetrachloroethene 1 04/10/21 03:03 V2870CBM
43.0 µg/m3 0.754 1.88Toluene 1 04/10/21 03:03 V2870CBM
<0.274 µg/m3 0.274 2.15Trichloroethene 1 04/10/21 03:03 V2870CBM
<0.433 µg/m3 0.433 2.81Trichlorofluoromethane 1 04/10/21 03:03 V2870CBM
54.4 µg/m3 0.295 2.461,2,4-Trimethylbenzene 1 04/10/21 03:03 V2870CBM
19.9 µg/m3 0.261 2.461,3,5-Trimethylbenzene 1 04/10/21 03:03 V2870CBM
<0.282 µg/m3 0.282 1.28Vinyl Chloride 1 04/10/21 03:03 V2870CBM
2.59 µg/m3 0.182 2.17o-Xylene 1 04/10/21 03:03 V2870CBM
5.71 µg/m3 0.384 5.65m,p-Xylene 1 04/10/21 03:03 V2870CBM
Surrogate: 4-Bromofluorobenzene 104 Limits: 70-130%04/10/21 03:031 CBM V2870
Surrogate: 4-Bromofluorobenzene 88.3 Limits: 70-130%04/13/21 05:3020 CBM V3112
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 11 of 18
Quality Control Data
21-098-0043Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
FZR-001
QC Prep Batch Method:
Volatile Organic Compounds in Air- GC/MS
TO-15
V2870QC Analytical Batch(es):
Analysis Method:
Analysis Description:
TO-15 Prep
QC Prep:V2869
Associated Lab Samples: 96350, 96351, 96352
LRB-V2869 Matrix: AIRLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/09/21 16:491.600.160<0.160µg/m3Benzene
04/09/21 16:491.110.195<0.195µg/m31,3-Butadiene
04/09/21 16:496.231.56<1.56µg/m3Carbon Disulfide
04/09/21 16:493.150.239<0.239µg/m3Carbon Tetrachloride
04/09/21 16:491.320.396<0.396µg/m3Chloroethane
04/09/21 16:492.440.264<0.264µg/m3Chloroform
04/09/21 16:491.030.268<0.268µg/m3Chloromethane
04/09/21 16:493.440.861<0.861µg/m3Cyclohexane
04/09/21 16:493.010.217<0.217µg/m31,3-Dichlorobenzene
04/09/21 16:492.470.410<0.410µg/m3Dichlorodifluoromethane
04/09/21 16:492.310.402<0.402µg/m31,2-Dichloropropane
04/09/21 16:495.002.50<2.50µg/m3Ethanol
04/09/21 16:491.800.249<0.249µg/m3Ethyl Acetate
04/09/21 16:492.170.187<0.187µg/m3Ethylbenzene
04/09/21 16:492.460.266<0.266µg/m34-Ethyltoluene
04/09/21 16:493.830.529<0.529µg/m31,1,2-Trichloro-1,2,2-trifluoroethane
04/09/21 16:492.050.193<0.193µg/m3Heptane
04/09/21 16:491.760.254<0.254µg/m3n-Hexane
04/09/21 16:494.920.167<0.167µg/m3Isopropyl Alchohol
04/09/21 16:491.470.295<0.295µg/m3Methyl Ethyl Ketone (MEK)
04/09/21 16:492.050.254<0.254µg/m34-Methyl-2-Pentanone
04/09/21 16:491.740.383<0.383µg/m3Methylene Chloride
04/09/21 16:492.620.386<0.386µg/m3Naphthalene
04/09/21 16:490.8610.139<0.139µg/m3Propene
04/09/21 16:492.130.149<0.149µg/m3Styrene
04/09/21 16:493.390.441<0.441µg/m3Tetrachloroethene
04/09/21 16:491.880.754<0.754µg/m3Toluene
Page 1 of 4Date:05/04/2021 10:06 AM
Page 12 of 18
Quality Control Data
21-098-0043Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
FZR-001
QC Prep Batch Method:
Volatile Organic Compounds in Air- GC/MS
TO-15
V2870QC Analytical Batch(es):
Analysis Method:
Analysis Description:
TO-15 Prep
QC Prep:V2869
Associated Lab Samples: 96350, 96351, 96352
LRB-V2869 Matrix: AIRLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/09/21 16:492.150.274<0.274µg/m3Trichloroethene
04/09/21 16:492.810.433<0.433µg/m3Trichlorofluoromethane
04/09/21 16:492.460.295<0.295µg/m31,2,4-Trimethylbenzene
04/09/21 16:492.460.261<0.261µg/m31,3,5-Trimethylbenzene
04/09/21 16:491.280.282<0.282µg/m3Vinyl Chloride
04/09/21 16:492.170.182<0.182µg/m3o-Xylene
04/09/21 16:495.650.384<0.384µg/m3m,p-Xylene
04/09/21 16:494-Bromofluorobenzene (S)91.0 70-130
LCS-V2869Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
11318.016.0µg/m3Benzene 70-130
12614.011.1µg/m31,3-Butadiene 70-130
12719.815.6µg/m3Carbon Disulfide 70-130
10131.931.5µg/m3Carbon Tetrachloride 70-130
11915.713.2µg/m3Chloroethane 70-130
11227.324.4µg/m3Chloroform 70-130
12613.010.3µg/m3Chloromethane 70-130
10117.317.2µg/m3Cyclohexane 70-130
12638.030.1µg/m31,3-Dichlorobenzene 70-130
12330.324.7µg/m3Dichlorodifluoromethane 70-130
11526.623.1µg/m31,2-Dichloropropane 70-130
12311.69.42µg/m3Ethanol 70-130
12322.118.0µg/m3Ethyl Acetate 70-130
12326.621.7µg/m3Ethylbenzene 70-130
13031.924.6µg/m34-Ethyltoluene 70-130
Page 2 of 4Date:05/04/2021 10:06 AM
Page 13 of 18
Quality Control Data
21-098-0043Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
FZR-001
QC Prep Batch Method:
Volatile Organic Compounds in Air- GC/MS
TO-15
V2870QC Analytical Batch(es):
Analysis Method:
Analysis Description:
TO-15 Prep
QC Prep:V2869
LCS-V2869Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
12246.638.3µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 70-130
11723.920.5µg/m3Heptane 70-130
11620.417.6µg/m3n-Hexane 70-130
12415.312.3µg/m3Isopropyl Alchohol 70-130
12117.914.8µg/m3Methyl Ethyl Ketone (MEK)70-130
12325.220.5µg/m34-Methyl-2-Pentanone 70-130
12121.117.4µg/m3Methylene Chloride 70-130
13034.026.2µg/m3Naphthalene 70-130
12510.88.61µg/m3Propene 70-130
11524.421.3µg/m3Styrene 70-130
11940.433.9µg/m3Tetrachloroethene 70-130
11922.418.8µg/m3Toluene 70-130
11230.126.9µg/m3Trichloroethene 70-130
12635.528.1µg/m3Trichlorofluoromethane 70-130
12029.624.6µg/m31,2,4-Trimethylbenzene 70-130
12931.724.6µg/m31,3,5-Trimethylbenzene 70-130
12315.712.8µg/m3Vinyl Chloride 70-130
12426.821.7µg/m3o-Xylene 70-130
12453.743.4µg/m3m,p-Xylene 70-130
98.34-Bromofluorobenzene (S)70-130
Page 3 of 4Date:05/04/2021 10:06 AM
Page 14 of 18
Quality Control Data
21-098-0043Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
FZR-001
QC Prep Batch Method:
Volatile Organic Compounds in Air- GC/MS
TO-15
V3112QC Analytical Batch(es):
Analysis Method:
Analysis Description:
TO-15 Prep
QC Prep:V3110
Associated Lab Samples: 96350, 96351, 96352
LRB-V3110 Matrix: AIRLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/13/21 03:362.380.594<0.594µg/m3Acetone
04/13/21 03:360.9420.320<0.320µg/m3Ethanol
04/13/21 03:364.920.167<0.167µg/m3Isopropyl Alchohol
04/13/21 03:364-Bromofluorobenzene (S)87.1 70-130
LCS-V3110Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
11113.211.9µg/m3Acetone 70-130
98.39.269.42µg/m3Ethanol 70-130
10813.312.3µg/m3Isopropyl Alchohol 70-130
97.74-Bromofluorobenzene (S)70-130
Page 4 of 4Date:05/04/2021 10:06 AM
Page 15 of 18
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:21-098-0043
Hart & Hickman (Charlotte)
01102
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Talon J Yelton Date & Time:04/08/2021 16:57:39
Special precautions or instructions included?
Comments:
Page 16 of 18
Page 17 of 18
Page 18 of 18
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
9/10/2021
Hart & Hickman (Charlotte) Andrew Besu
2923 South Tryon St. Ste 100 Charlotte, NC, 28203
Ref: Analytical Testing
Revised Lab Report Number: 21-239-0049 Client Project Description: CTT-001
Dear Andrew Besu:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 8/27/2021 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2012) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely,
Angela D Overcash Senior Project Manager
Page 1 of 24
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202237735State ProgramNorth Carolina
12/31/2021402State ProgramNorth Carolina
07/31/202299012State ProgramSouth Carolina
12/31/202199012State ProgramSouth Carolina
Page 1 of 1 00016/21-239-0049
Page 2 of 24
Report Number:
Sample Summary Table
Client Project Description:
21-239-0049
CTT-001
Lab No Client Sample ID Matrix Date Collected Date Received
08/24/2021 07:55Air 94539 BAS-1 08/27/2021 10:00
08/24/2021Air 94540 IAS-DUP 08/27/2021 10:00
08/24/2021 07:53Air 94541 IAS-1 08/27/2021 10:00
08/24/2021Air 94542 SS-DUP 08/27/2021 10:00
08/24/2021 16:10Air 94543 SS-OP-1 08/27/2021 10:00
Page 3 of 24
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
21-239-0049
Report Limit
Project:CTT-001
V 94539BAS-1
252 09/01/2021 02:40TO-15 Acetone µg/m3 0.202
J0.505 09/01/2021 02:40TO-15 Benzene µg/m3 0.0733
1.22 09/01/2021 02:40TO-15 Chloromethane µg/m3 0.0673
3.13 09/01/2021 02:40TO-15 Dichlorodifluoromethane µg/m3 0.134
68.2 09/01/2021 02:40TO-15 Ethanol µg/m3 0.169
10.0 09/01/2021 02:40TO-15 Isopropyl Alchohol µg/m3 0.139
13.8 09/01/2021 02:40TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224
J1.29 09/01/2021 02:40TO-15 Methylene Chloride µg/m3 0.489
2.48 09/01/2021 02:40TO-15 Toluene µg/m3 0.0901
J2.29 09/01/2021 02:40TO-15 Trichlorofluoromethane µg/m3 0.130
V 94540IAS-DUP
172 09/01/2021 15:04TO-15 Acetone µg/m3 4.04
1.91 09/01/2021 03:26TO-15 Benzene µg/m3 0.0733
J1.10 09/01/2021 03:26TO-15 Carbon Disulfide µg/m3 0.0608
J0.742 09/01/2021 03:26TO-15 Carbon Tetrachloride µg/m3 0.155
2.53 09/01/2021 03:26TO-15 Chloroform µg/m3 0.0864
2.12 09/01/2021 03:26TO-15 Chloromethane µg/m3 0.0673
780 09/01/2021 15:04TO-15 Ethanol µg/m3 3.38
22.0 09/01/2021 03:26TO-15 Ethyl Acetate µg/m3 0.136
3.00 09/01/2021 03:26TO-15 Ethylbenzene µg/m3 0.106
7.76 09/01/2021 03:26TO-15 4-Ethyltoluene µg/m3 0.128
J0.613 09/01/2021 03:26TO-15 1,1,2-Trichloro-1,2,2-trifluoroethane µg/m3 0.561
8.96 09/01/2021 03:26TO-15 Heptane µg/m3 0.143
J90.0 09/01/2021 15:04TO-15 Isopropyl Alchohol µg/m3 2.78
21.7 09/01/2021 03:26TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224
J1.04 09/01/2021 03:26TO-15 4-Methyl-2-Pentanone µg/m3 0.121
2.51 09/01/2021 03:26TO-15 Methylene Chloride µg/m3 0.489
76.3 09/01/2021 03:26TO-15 Styrene µg/m3 0.124
J1.96 09/01/2021 03:26TO-15 Tetrachloroethene µg/m3 0.181
24.5 09/01/2021 03:26TO-15 Toluene µg/m3 0.0901
J1.46 09/01/2021 03:26TO-15 Trichloroethene µg/m3 0.199
J1.83 09/01/2021 03:26TO-15 Trichlorofluoromethane µg/m3 0.130
16.3 09/01/2021 03:26TO-15 1,2,4-Trimethylbenzene µg/m3 0.110
4.16 09/01/2021 03:26TO-15 1,3,5-Trimethylbenzene µg/m3 0.236
3.63 09/01/2021 03:26TO-15 o-Xylene µg/m3 0.157
7.76 09/01/2021 03:26TO-15 m,p-Xylene µg/m3 0.217
Page 4 of 24
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
21-239-0049
Report Limit
Project:CTT-001
V 94541IAS-1
184 09/01/2021 15:41TO-15 Acetone µg/m3 4.04
1.95 09/01/2021 04:12TO-15 Benzene µg/m3 0.0733
J1.08 09/01/2021 04:12TO-15 Carbon Disulfide µg/m3 0.0608
J0.717 09/01/2021 04:12TO-15 Carbon Tetrachloride µg/m3 0.155
2.59 09/01/2021 04:12TO-15 Chloroform µg/m3 0.0864
2.06 09/01/2021 04:12TO-15 Chloromethane µg/m3 0.0673
817 09/01/2021 15:41TO-15 Ethanol µg/m3 3.38
21.1 09/01/2021 04:12TO-15 Ethyl Acetate µg/m3 0.136
2.94 09/01/2021 04:12TO-15 Ethylbenzene µg/m3 0.106
2.99 09/01/2021 04:12TO-15 4-Ethyltoluene µg/m3 0.128
J0.644 09/01/2021 04:12TO-15 1,1,2-Trichloro-1,2,2-trifluoroethane µg/m3 0.561
8.98 09/01/2021 04:12TO-15 Heptane µg/m3 0.143
99.5 09/01/2021 15:41TO-15 Isopropyl Alchohol µg/m3 2.78
20.5 09/01/2021 04:12TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224
J0.963 09/01/2021 04:12TO-15 4-Methyl-2-Pentanone µg/m3 0.121
2.37 09/01/2021 04:12TO-15 Methylene Chloride µg/m3 0.489
76.2 09/01/2021 04:12TO-15 Styrene µg/m3 0.124
J1.58 09/01/2021 04:12TO-15 Tetrachloroethene µg/m3 0.181
24.5 09/01/2021 04:12TO-15 Toluene µg/m3 0.0901
J1.39 09/01/2021 04:12TO-15 Trichloroethene µg/m3 0.199
J1.88 09/01/2021 04:12TO-15 Trichlorofluoromethane µg/m3 0.130
17.7 09/01/2021 04:12TO-15 1,2,4-Trimethylbenzene µg/m3 0.110
5.76 09/01/2021 04:12TO-15 1,3,5-Trimethylbenzene µg/m3 0.236
3.53 09/01/2021 04:12TO-15 o-Xylene µg/m3 0.157
7.66 09/01/2021 04:12TO-15 m,p-Xylene µg/m3 0.217
V 94542SS-DUP
17600 09/01/2021 16:54TO-15 Acetone µg/m3 40.4
J16.5 09/01/2021 01:06TO-15 Carbon Disulfide µg/m3 1.22
J13.7 09/01/2021 01:06TO-15 Chloromethane µg/m3 1.34
184 09/01/2021 01:06TO-15 Ethanol µg/m3 3.38
J10.4 09/01/2021 01:06TO-15 Ethylbenzene µg/m3 2.12
3440 09/01/2021 01:06TO-15 4-Ethyltoluene µg/m3 2.56
125 09/01/2021 01:06TO-15 Isopropyl Alchohol µg/m3 2.78
3730 09/01/2021 16:54TO-15 Methyl Ethyl Ketone (MEK)µg/m3 44.8
J29.0 09/01/2021 01:06TO-15 4-Methyl-2-Pentanone µg/m3 2.42
156 09/01/2021 01:06TO-15 Styrene µg/m3 2.48
Page 5 of 24
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
21-239-0049
Report Limit
Project:CTT-001
V 94542SS-DUP
J9.27 09/01/2021 01:06TO-15 Toluene µg/m3 1.80
9980 09/01/2021 16:54TO-15 1,2,4-Trimethylbenzene µg/m3 22.0
3460 09/01/2021 01:06TO-15 1,3,5-Trimethylbenzene µg/m3 4.72
476 09/01/2021 01:06TO-15 o-Xylene µg/m3 3.14
J10109/01/2021 01:06TO-15 m,p-Xylene µg/m3 4.34
V 94543SS-OP-1
19700 09/01/2021 17:31TO-15 Acetone µg/m3 40.4
J16.6 09/01/2021 01:44TO-15 Carbon Disulfide µg/m3 1.22
J14.5 09/01/2021 01:44TO-15 Chloromethane µg/m3 1.34
188 09/01/2021 01:44TO-15 Ethanol µg/m3 3.38
J10.2 09/01/2021 01:44TO-15 Ethylbenzene µg/m3 2.12
3530 09/01/2021 01:44TO-15 4-Ethyltoluene µg/m3 2.56
125 09/01/2021 01:44TO-15 Isopropyl Alchohol µg/m3 2.78
3870 09/01/2021 17:31TO-15 Methyl Ethyl Ketone (MEK)µg/m3 44.8
J29.0 09/01/2021 01:44TO-15 4-Methyl-2-Pentanone µg/m3 2.42
160 09/01/2021 01:44TO-15 Styrene µg/m3 2.48
J9.04 09/01/2021 01:44TO-15 Toluene µg/m3 1.80
10400 09/01/2021 17:31TO-15 1,2,4-Trimethylbenzene µg/m3 22.0
3530 09/01/2021 01:44TO-15 1,3,5-Trimethylbenzene µg/m3 4.72
490 09/01/2021 01:44TO-15 o-Xylene µg/m3 3.14
J10209/01/2021 01:44TO-15 m,p-Xylene µg/m3 4.34
Page 6 of 24
Client: Hart & Hickman (Charlotte) CASE NARRATIVE
Project: CTT-001 Lab Report Number: 21-239-0049
Date: 9/10/2021
Volatile Organic Compounds in Air- GC/MS Method TO-15 Sample 94539 (BAS-1) QC Batch No: V8639/V8638
One or more Internal Standards are outside method acceptance criteria. Re-analysis and/or sample dilutions are required.
Internal standard fails low due to matrix. A subsequent diution was run which saw the IS return to passing levels
Analyte: 4-Bromofluorobenzene QC Batch No: V8639/V8638
Surrogate was flagged for recovery outside QC limits in this project sample. This sample was re-analyzed for verification, at dilution with recovery within limits. Batch QC samples (method blank and laboratory control
samples) all showed surrogates within QC limits indicating that the recovery was due to sample matrix. The data was not affected.
Page 7 of 24
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
21-239-0049
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Andrew Besu
Charlotte
Received : 08/27/2021
CTT-001
Revised Report Date: 09/10/2021
Original Report Date : 09/03/2021
Sample ID :
Lab No :
Sampled:BAS-1
94539 Matrix:
8/24/2021 7:55
Air
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
TO-15 Prep
TO-15 Prep Batch(es):V8638 08/31/21 09:00
252 µg/m3 0.202 4.75Acetone 1 09/01/21 02:40 V8639ANG
0.505 J µg/m3 0.0733 1.60Benzene 1 09/01/21 02:40 V8639ANG
<0.328 µg/m3 0.328 1.111,3-Butadiene 1 09/01/21 02:40 V8639ANG
<0.0608 µg/m3 0.0608 6.23Carbon Disulfide 1 09/01/21 02:40 V8639ANG
<0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 09/01/21 02:40 V8639ANG
<0.164 µg/m3 0.164 1.32Chloroethane 1 09/01/21 02:40 V8639ANG
<0.0864 µg/m3 0.0864 2.44Chloroform 1 09/01/21 02:40 V8639ANG
1.22 µg/m3 0.0673 1.03Chloromethane 1 09/01/21 02:40 V8639ANG
<0.161 µg/m3 0.161 3.44Cyclohexane 1 09/01/21 02:40 V8639ANG
<0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 09/01/21 02:40 V8639ANG
3.13 µg/m3 0.134 2.47Dichlorodifluoromethane 1 09/01/21 02:40 V8639ANG
<0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 09/01/21 02:40 V8639ANG
68.2 µg/m3 0.169 5.00Ethanol 1 09/01/21 02:40 V8639ANG
<0.136 µg/m3 0.136 1.80Ethyl Acetate 1 09/01/21 02:40 V8639ANG
<0.106 µg/m3 0.106 2.17Ethylbenzene 1 09/01/21 02:40 V8639ANG
<0.128 µg/m3 0.128 2.464-Ethyltoluene 1 09/01/21 02:40 V8639ANG
<0.561 µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 09/01/21 02:40 V8639ANG
<0.143 µg/m3 0.143 2.05Heptane 1 09/01/21 02:40 V8639ANG
<0.0472 µg/m3 0.0472 1.76n-Hexane 1 09/01/21 02:40 V8639ANG
10.0 µg/m3 0.139 4.92Isopropyl Alchohol 1 09/01/21 02:40 V8639ANG
13.8 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 09/01/21 02:40 V8639ANG
<0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 09/01/21 02:40 V8639ANG
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 8 of 24
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
21-239-0049
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Andrew Besu
Charlotte
Received : 08/27/2021
CTT-001
Revised Report Date: 09/10/2021
Original Report Date : 09/03/2021
Sample ID :
Lab No :
Sampled:BAS-1
94539 Matrix:
8/24/2021 7:55
Air
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
TO-15 Prep
TO-15 Prep Batch(es):V8638 08/31/21 09:00
1.29 J µg/m3 0.489 1.74Methylene Chloride 1 09/01/21 02:40 V8639ANG
<0.183 µg/m3 0.183 2.62Naphthalene 1 09/01/21 02:40 V8639ANG
<0.242 µg/m3 0.242 0.861Propene 1 09/01/21 02:40 V8639ANG
<0.124 µg/m3 0.124 2.13Styrene 1 09/01/21 02:40 V8639ANG
<0.181 µg/m3 0.181 3.39Tetrachloroethene 1 09/01/21 02:40 V8639ANG
2.48 µg/m3 0.0901 1.88Toluene 1 09/01/21 02:40 V8639ANG
<0.199 µg/m3 0.199 2.15Trichloroethene 1 09/01/21 02:40 V8639ANG
2.29 J µg/m3 0.130 2.81Trichlorofluoromethane 1 09/01/21 02:40 V8639ANG
<0.110 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 09/01/21 02:40 V8639ANG
<0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 09/01/21 02:40 V8639ANG
<0.127 µg/m3 0.127 1.28Vinyl Chloride 1 09/01/21 02:40 V8639ANG
<0.157 µg/m3 0.157 2.17o-Xylene 1 09/01/21 02:40 V8639ANG
<0.217 µg/m3 0.217 5.65m,p-Xylene 1 09/01/21 02:40 V8639ANG
Surrogate: 4-Bromofluorobenzene 10.9 *Limits: 70-130%09/01/21 02:401 ANG V8639
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 9 of 24
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
21-239-0049
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Andrew Besu
Charlotte
Received : 08/27/2021
CTT-001
Revised Report Date: 09/10/2021
Original Report Date : 09/03/2021
Sample ID :
Lab No :
Sampled:IAS-DUP
94540 Matrix:
8/24/2021 0:00
Air
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
TO-15 Prep
TO-15 Prep Batch(es):V8638 08/31/21 09:00 V8648 09/01/21 09:00
172 µg/m3 4.04 95.0Acetone 20 09/01/21 15:04 V8649ANG
1.91 µg/m3 0.0733 1.60Benzene 1 09/01/21 03:26 V8639ANG
<0.328 µg/m3 0.328 1.111,3-Butadiene 1 09/01/21 03:26 V8639ANG
1.10 J µg/m3 0.0608 6.23Carbon Disulfide 1 09/01/21 03:26 V8639ANG
0.742 J µg/m3 0.155 3.15Carbon Tetrachloride 1 09/01/21 03:26 V8639ANG
<0.164 µg/m3 0.164 1.32Chloroethane 1 09/01/21 03:26 V8639ANG
2.53 µg/m3 0.0864 2.44Chloroform 1 09/01/21 03:26 V8639ANG
2.12 µg/m3 0.0673 1.03Chloromethane 1 09/01/21 03:26 V8639ANG
<0.161 µg/m3 0.161 3.44Cyclohexane 1 09/01/21 03:26 V8639ANG
<0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 09/01/21 03:26 V8639ANG
<0.134 µg/m3 0.134 2.47Dichlorodifluoromethane 1 09/01/21 03:26 V8639ANG
<0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 09/01/21 03:26 V8639ANG
780 µg/m3 3.38 100Ethanol 20 09/01/21 15:04 V8649ANG
22.0 µg/m3 0.136 1.80Ethyl Acetate 1 09/01/21 03:26 V8639ANG
3.00 µg/m3 0.106 2.17Ethylbenzene 1 09/01/21 03:26 V8639ANG
7.76 µg/m3 0.128 2.464-Ethyltoluene 1 09/01/21 03:26 V8639ANG
0.613 J µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 09/01/21 03:26 V8639ANG
8.96 µg/m3 0.143 2.05Heptane 1 09/01/21 03:26 V8639ANG
<0.0472 µg/m3 0.0472 1.76n-Hexane 1 09/01/21 03:26 V8639ANG
90.0 J µg/m3 2.78 98.3Isopropyl Alchohol 20 09/01/21 15:04 V8649ANG
21.7 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 09/01/21 03:26 V8639ANG
1.04 J µg/m3 0.121 2.054-Methyl-2-Pentanone 1 09/01/21 03:26 V8639ANG
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 10 of 24
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
21-239-0049
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Andrew Besu
Charlotte
Received : 08/27/2021
CTT-001
Revised Report Date: 09/10/2021
Original Report Date : 09/03/2021
Sample ID :
Lab No :
Sampled:IAS-DUP
94540 Matrix:
8/24/2021 0:00
Air
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
TO-15 Prep
TO-15 Prep Batch(es):V8638 08/31/21 09:00 V8648 09/01/21 09:00
2.51 µg/m3 0.489 1.74Methylene Chloride 1 09/01/21 03:26 V8639ANG
<0.183 µg/m3 0.183 2.62Naphthalene 1 09/01/21 03:26 V8639ANG
<0.242 µg/m3 0.242 0.861Propene 1 09/01/21 03:26 V8639ANG
76.3 µg/m3 0.124 2.13Styrene 1 09/01/21 03:26 V8639ANG
1.96 J µg/m3 0.181 3.39Tetrachloroethene 1 09/01/21 03:26 V8639ANG
24.5 µg/m3 0.0901 1.88Toluene 1 09/01/21 03:26 V8639ANG
1.46 J µg/m3 0.199 2.15Trichloroethene 1 09/01/21 03:26 V8639ANG
1.83 J µg/m3 0.130 2.81Trichlorofluoromethane 1 09/01/21 03:26 V8639ANG
16.3 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 09/01/21 03:26 V8639ANG
4.16 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 09/01/21 03:26 V8639ANG
<0.127 µg/m3 0.127 1.28Vinyl Chloride 1 09/01/21 03:26 V8639ANG
3.63 µg/m3 0.157 2.17o-Xylene 1 09/01/21 03:26 V8639ANG
7.76 µg/m3 0.217 5.65m,p-Xylene 1 09/01/21 03:26 V8639ANG
Surrogate: 4-Bromofluorobenzene 109 Limits: 70-130%09/01/21 03:261 ANG V8639
Surrogate: 4-Bromofluorobenzene 104 Limits: 70-130%09/01/21 15:0420 ANG V8649
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 11 of 24
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
21-239-0049
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Andrew Besu
Charlotte
Received : 08/27/2021
CTT-001
Revised Report Date: 09/10/2021
Original Report Date : 09/03/2021
Sample ID :
Lab No :
Sampled:IAS-1
94541 Matrix:
8/24/2021 7:53
Air
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
TO-15 Prep
TO-15 Prep Batch(es):V8638 08/31/21 09:00 V8648 09/01/21 09:00
184 µg/m3 4.04 95.0Acetone 20 09/01/21 15:41 V8649ANG
1.95 µg/m3 0.0733 1.60Benzene 1 09/01/21 04:12 V8639ANG
<0.328 µg/m3 0.328 1.111,3-Butadiene 1 09/01/21 04:12 V8639ANG
1.08 J µg/m3 0.0608 6.23Carbon Disulfide 1 09/01/21 04:12 V8639ANG
0.717 J µg/m3 0.155 3.15Carbon Tetrachloride 1 09/01/21 04:12 V8639ANG
<0.164 µg/m3 0.164 1.32Chloroethane 1 09/01/21 04:12 V8639ANG
2.59 µg/m3 0.0864 2.44Chloroform 1 09/01/21 04:12 V8639ANG
2.06 µg/m3 0.0673 1.03Chloromethane 1 09/01/21 04:12 V8639ANG
<0.161 µg/m3 0.161 3.44Cyclohexane 1 09/01/21 04:12 V8639ANG
<0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 09/01/21 04:12 V8639ANG
<0.134 µg/m3 0.134 2.47Dichlorodifluoromethane 1 09/01/21 04:12 V8639ANG
<0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 09/01/21 04:12 V8639ANG
817 µg/m3 3.38 100Ethanol 20 09/01/21 15:41 V8649ANG
21.1 µg/m3 0.136 1.80Ethyl Acetate 1 09/01/21 04:12 V8639ANG
2.94 µg/m3 0.106 2.17Ethylbenzene 1 09/01/21 04:12 V8639ANG
2.99 µg/m3 0.128 2.464-Ethyltoluene 1 09/01/21 04:12 V8639ANG
0.644 J µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 09/01/21 04:12 V8639ANG
8.98 µg/m3 0.143 2.05Heptane 1 09/01/21 04:12 V8639ANG
<0.0472 µg/m3 0.0472 1.76n-Hexane 1 09/01/21 04:12 V8639ANG
99.5 µg/m3 2.78 98.3Isopropyl Alchohol 20 09/01/21 15:41 V8649ANG
20.5 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 09/01/21 04:12 V8639ANG
0.963 J µg/m3 0.121 2.054-Methyl-2-Pentanone 1 09/01/21 04:12 V8639ANG
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 12 of 24
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
21-239-0049
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Andrew Besu
Charlotte
Received : 08/27/2021
CTT-001
Revised Report Date: 09/10/2021
Original Report Date : 09/03/2021
Sample ID :
Lab No :
Sampled:IAS-1
94541 Matrix:
8/24/2021 7:53
Air
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
TO-15 Prep
TO-15 Prep Batch(es):V8638 08/31/21 09:00 V8648 09/01/21 09:00
2.37 µg/m3 0.489 1.74Methylene Chloride 1 09/01/21 04:12 V8639ANG
<0.183 µg/m3 0.183 2.62Naphthalene 1 09/01/21 04:12 V8639ANG
<0.242 µg/m3 0.242 0.861Propene 1 09/01/21 04:12 V8639ANG
76.2 µg/m3 0.124 2.13Styrene 1 09/01/21 04:12 V8639ANG
1.58 J µg/m3 0.181 3.39Tetrachloroethene 1 09/01/21 04:12 V8639ANG
24.5 µg/m3 0.0901 1.88Toluene 1 09/01/21 04:12 V8639ANG
1.39 J µg/m3 0.199 2.15Trichloroethene 1 09/01/21 04:12 V8639ANG
1.88 J µg/m3 0.130 2.81Trichlorofluoromethane 1 09/01/21 04:12 V8639ANG
17.7 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 09/01/21 04:12 V8639ANG
5.76 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 09/01/21 04:12 V8639ANG
<0.127 µg/m3 0.127 1.28Vinyl Chloride 1 09/01/21 04:12 V8639ANG
3.53 µg/m3 0.157 2.17o-Xylene 1 09/01/21 04:12 V8639ANG
7.66 µg/m3 0.217 5.65m,p-Xylene 1 09/01/21 04:12 V8639ANG
Surrogate: 4-Bromofluorobenzene 105 Limits: 70-130%09/01/21 04:121 ANG V8639
Surrogate: 4-Bromofluorobenzene 104 Limits: 70-130%09/01/21 15:4120 ANG V8649
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 13 of 24
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
21-239-0049
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Andrew Besu
Charlotte
Received : 08/27/2021
CTT-001
Revised Report Date: 09/10/2021
Original Report Date : 09/03/2021
Sample ID :
Lab No :
Sampled:SS-DUP
94542 Matrix:
8/24/2021 0:00
Air
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
TO-15 Prep
TO-15 Prep Batch(es):V8638 08/31/21 09:00 V8648 09/01/21 09:00
17600 µg/m3 40.4 950Acetone 200 09/01/21 16:54 V8649ANG
<1.46 µg/m3 1.46 31.9Benzene 20 09/01/21 01:06 V8639ANG
<6.53 µg/m3 6.53 22.11,3-Butadiene 20 09/01/21 01:06 V8639ANG
16.5 J µg/m3 1.22 125Carbon Disulfide 20 09/01/21 01:06 V8639ANG
<3.10 µg/m3 3.10 62.9Carbon Tetrachloride 20 09/01/21 01:06 V8639ANG
<3.28 µg/m3 3.28 26.4Chloroethane 20 09/01/21 01:06 V8639ANG
<1.73 µg/m3 1.73 48.8Chloroform 20 09/01/21 01:06 V8639ANG
13.7 J µg/m3 1.34 20.6Chloromethane 20 09/01/21 01:06 V8639ANG
<3.22 µg/m3 3.22 68.8Cyclohexane 20 09/01/21 01:06 V8639ANG
<3.48 µg/m3 3.48 2411,3-Dichlorobenzene 20 09/01/21 01:06 V8639ANG
<2.68 µg/m3 2.68 49.4Dichlorodifluoromethane 20 09/01/21 01:06 V8639ANG
<4.10 µg/m3 4.10 46.21,2-Dichloropropane 20 09/01/21 01:06 V8639ANG
184 µg/m3 3.38 100Ethanol 20 09/01/21 01:06 V8639ANG
<2.72 µg/m3 2.72 36.0Ethyl Acetate 20 09/01/21 01:06 V8639ANG
10.4 J µg/m3 2.12 43.4Ethylbenzene 20 09/01/21 01:06 V8639ANG
3440 µg/m3 2.56 49.24-Ethyltoluene 20 09/01/21 01:06 V8639ANG
<11.2 µg/m3 11.2 76.61,1,2-Trichloro-1,2,2-trifluoroethane 20 09/01/21 01:06 V8639ANG
<2.86 µg/m3 2.86 41.0Heptane 20 09/01/21 01:06 V8639ANG
<0.943 µg/m3 0.943 35.2n-Hexane 20 09/01/21 01:06 V8639ANG
125 µg/m3 2.78 98.3Isopropyl Alchohol 20 09/01/21 01:06 V8639ANG
3730 µg/m3 44.8 295Methyl Ethyl Ketone (MEK)200 09/01/21 16:54 V8649ANG
29.0 J µg/m3 2.42 41.04-Methyl-2-Pentanone 20 09/01/21 01:06 V8639ANG
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 14 of 24
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
21-239-0049
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Andrew Besu
Charlotte
Received : 08/27/2021
CTT-001
Revised Report Date: 09/10/2021
Original Report Date : 09/03/2021
Sample ID :
Lab No :
Sampled:SS-DUP
94542 Matrix:
8/24/2021 0:00
Air
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
TO-15 Prep
TO-15 Prep Batch(es):V8638 08/31/21 09:00 V8648 09/01/21 09:00
<9.75 µg/m3 9.75 34.7Methylene Chloride 20 09/01/21 01:06 V8639ANG
<3.66 µg/m3 3.66 52.4Naphthalene 20 09/01/21 01:06 V8639ANG
<4.84 µg/m3 4.84 17.2Propene 20 09/01/21 01:06 V8639ANG
156 µg/m3 2.48 42.6Styrene 20 09/01/21 01:06 V8639ANG
<3.62 µg/m3 3.62 67.8Tetrachloroethene 20 09/01/21 01:06 V8639ANG
9.27 J µg/m3 1.80 37.7Toluene 20 09/01/21 01:06 V8639ANG
<3.98 µg/m3 3.98 43.0Trichloroethene 20 09/01/21 01:06 V8639ANG
<2.60 µg/m3 2.60 56.2Trichlorofluoromethane 20 09/01/21 01:06 V8639ANG
9980 µg/m3 22.0 4921,2,4-Trimethylbenzene 200 09/01/21 16:54 V8649ANG
3460 µg/m3 4.72 49.21,3,5-Trimethylbenzene 20 09/01/21 01:06 V8639ANG
<2.54 µg/m3 2.54 25.6Vinyl Chloride 20 09/01/21 01:06 V8639ANG
476 µg/m3 3.14 43.4o-Xylene 20 09/01/21 01:06 V8639ANG
101 J µg/m3 4.34 113m,p-Xylene 20 09/01/21 01:06 V8639ANG
Surrogate: 4-Bromofluorobenzene 111 Limits: 70-130%09/01/21 01:0620 ANG V8639
Surrogate: 4-Bromofluorobenzene 105 Limits: 70-130%09/01/21 16:54200 ANG V8649
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 15 of 24
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
21-239-0049
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Andrew Besu
Charlotte
Received : 08/27/2021
CTT-001
Revised Report Date: 09/10/2021
Original Report Date : 09/03/2021
Sample ID :
Lab No :
Sampled:SS-OP-1
94543 Matrix:
8/24/2021 16:10
Air
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
TO-15 Prep
TO-15 Prep Batch(es):V8638 08/31/21 09:00 V8648 09/01/21 09:00
19700 µg/m3 40.4 950Acetone 200 09/01/21 17:31 V8649ANG
<1.46 µg/m3 1.46 31.9Benzene 20 09/01/21 01:44 V8639ANG
<6.53 µg/m3 6.53 22.11,3-Butadiene 20 09/01/21 01:44 V8639ANG
16.6 J µg/m3 1.22 125Carbon Disulfide 20 09/01/21 01:44 V8639ANG
<3.10 µg/m3 3.10 62.9Carbon Tetrachloride 20 09/01/21 01:44 V8639ANG
<3.28 µg/m3 3.28 26.4Chloroethane 20 09/01/21 01:44 V8639ANG
<1.73 µg/m3 1.73 48.8Chloroform 20 09/01/21 01:44 V8639ANG
14.5 J µg/m3 1.34 20.6Chloromethane 20 09/01/21 01:44 V8639ANG
<3.22 µg/m3 3.22 68.8Cyclohexane 20 09/01/21 01:44 V8639ANG
<3.48 µg/m3 3.48 2411,3-Dichlorobenzene 20 09/01/21 01:44 V8639ANG
<2.68 µg/m3 2.68 49.4Dichlorodifluoromethane 20 09/01/21 01:44 V8639ANG
<4.10 µg/m3 4.10 46.21,2-Dichloropropane 20 09/01/21 01:44 V8639ANG
188 µg/m3 3.38 100Ethanol 20 09/01/21 01:44 V8639ANG
<2.72 µg/m3 2.72 36.0Ethyl Acetate 20 09/01/21 01:44 V8639ANG
10.2 J µg/m3 2.12 43.4Ethylbenzene 20 09/01/21 01:44 V8639ANG
3530 µg/m3 2.56 49.24-Ethyltoluene 20 09/01/21 01:44 V8639ANG
<11.2 µg/m3 11.2 76.61,1,2-Trichloro-1,2,2-trifluoroethane 20 09/01/21 01:44 V8639ANG
<2.86 µg/m3 2.86 41.0Heptane 20 09/01/21 01:44 V8639ANG
<0.943 µg/m3 0.943 35.2n-Hexane 20 09/01/21 01:44 V8639ANG
125 µg/m3 2.78 98.3Isopropyl Alchohol 20 09/01/21 01:44 V8639ANG
3870 µg/m3 44.8 295Methyl Ethyl Ketone (MEK)200 09/01/21 17:31 V8649ANG
29.0 J µg/m3 2.42 41.04-Methyl-2-Pentanone 20 09/01/21 01:44 V8639ANG
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 16 of 24
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
21-239-0049
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
Andrew Besu
Charlotte
Received : 08/27/2021
CTT-001
Revised Report Date: 09/10/2021
Original Report Date : 09/03/2021
Sample ID :
Lab No :
Sampled:SS-OP-1
94543 Matrix:
8/24/2021 16:10
Air
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
TO-15 Prep
TO-15 Prep Batch(es):V8638 08/31/21 09:00 V8648 09/01/21 09:00
<9.75 µg/m3 9.75 34.7Methylene Chloride 20 09/01/21 01:44 V8639ANG
<3.66 µg/m3 3.66 52.4Naphthalene 20 09/01/21 01:44 V8639ANG
<4.84 µg/m3 4.84 17.2Propene 20 09/01/21 01:44 V8639ANG
160 µg/m3 2.48 42.6Styrene 20 09/01/21 01:44 V8639ANG
<3.62 µg/m3 3.62 67.8Tetrachloroethene 20 09/01/21 01:44 V8639ANG
9.04 J µg/m3 1.80 37.7Toluene 20 09/01/21 01:44 V8639ANG
<3.98 µg/m3 3.98 43.0Trichloroethene 20 09/01/21 01:44 V8639ANG
<2.60 µg/m3 2.60 56.2Trichlorofluoromethane 20 09/01/21 01:44 V8639ANG
10400 µg/m3 22.0 4921,2,4-Trimethylbenzene 200 09/01/21 17:31 V8649ANG
3530 µg/m3 4.72 49.21,3,5-Trimethylbenzene 20 09/01/21 01:44 V8639ANG
<2.54 µg/m3 2.54 25.6Vinyl Chloride 20 09/01/21 01:44 V8639ANG
490 µg/m3 3.14 43.4o-Xylene 20 09/01/21 01:44 V8639ANG
102 J µg/m3 4.34 113m,p-Xylene 20 09/01/21 01:44 V8639ANG
Surrogate: 4-Bromofluorobenzene 112 Limits: 70-130%09/01/21 01:4420 ANG V8639
Surrogate: 4-Bromofluorobenzene 104 Limits: 70-130%09/01/21 17:31200 ANG V8649
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 17 of 24
Quality Control Data
21-239-0049Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
CTT-001
QC Prep Batch Method:
Volatile Organic Compounds in Air- GC/MS
TO-15
V8639QC Analytical Batch(es):
Analysis Method:
Analysis Description:
TO-15 Prep
QC Prep:V8638
Associated Lab Samples: 94539, 94540, 94541, 94542, 94543
LRB-V8638 Matrix: AIRLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/31/21 11:064.750.2020.482µg/m3Acetone
08/31/21 11:061.600.0733<0.0733µg/m3Benzene
08/31/21 11:061.110.328<0.328µg/m31,3-Butadiene
08/31/21 11:066.230.0608<0.0608µg/m3Carbon Disulfide
08/31/21 11:063.150.155<0.155µg/m3Carbon Tetrachloride
08/31/21 11:061.320.164<0.164µg/m3Chloroethane
08/31/21 11:062.440.0864<0.0864µg/m3Chloroform
08/31/21 11:061.030.0673<0.0673µg/m3Chloromethane
08/31/21 11:063.440.161<0.161µg/m3Cyclohexane
08/31/21 11:0612.00.174<0.174µg/m31,3-Dichlorobenzene
08/31/21 11:062.470.134<0.134µg/m3Dichlorodifluoromethane
08/31/21 11:062.310.205<0.205µg/m31,2-Dichloropropane
08/31/21 11:065.000.1690.588µg/m3Ethanol
08/31/21 11:061.800.136<0.136µg/m3Ethyl Acetate
08/31/21 11:062.170.106<0.106µg/m3Ethylbenzene
08/31/21 11:062.460.128<0.128µg/m34-Ethyltoluene
08/31/21 11:063.830.561<0.561µg/m31,1,2-Trichloro-1,2,2-trifluoroethane
08/31/21 11:062.050.143<0.143µg/m3Heptane
08/31/21 11:061.760.0472<0.0472µg/m3n-Hexane
08/31/21 11:064.920.1390.413µg/m3Isopropyl Alchohol
08/31/21 11:061.470.224<0.224µg/m3Methyl Ethyl Ketone (MEK)
08/31/21 11:062.050.121<0.121µg/m34-Methyl-2-Pentanone
08/31/21 11:061.740.489<0.489µg/m3Methylene Chloride
08/31/21 11:062.620.183<0.183µg/m3Naphthalene
08/31/21 11:060.8610.242<0.242µg/m3Propene
08/31/21 11:062.130.124<0.124µg/m3Styrene
08/31/21 11:063.390.181<0.181µg/m3Tetrachloroethene
Page 1 of 4Date:09/10/2021 02:40 PM
Page 18 of 24
Quality Control Data
21-239-0049Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
CTT-001
QC Prep Batch Method:
Volatile Organic Compounds in Air- GC/MS
TO-15
V8639QC Analytical Batch(es):
Analysis Method:
Analysis Description:
TO-15 Prep
QC Prep:V8638
Associated Lab Samples: 94539, 94540, 94541, 94542, 94543
LRB-V8638 Matrix: AIRLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/31/21 11:061.880.0901<0.0901µg/m3Toluene
08/31/21 11:062.150.199<0.199µg/m3Trichloroethene
08/31/21 11:062.810.130<0.130µg/m3Trichlorofluoromethane
08/31/21 11:062.460.110<0.110µg/m31,2,4-Trimethylbenzene
08/31/21 11:062.460.236<0.236µg/m31,3,5-Trimethylbenzene
08/31/21 11:061.280.127<0.127µg/m3Vinyl Chloride
08/31/21 11:062.170.157<0.157µg/m3o-Xylene
08/31/21 11:065.650.217<0.217µg/m3m,p-Xylene
08/31/21 11:064-Bromofluorobenzene (S)93.8 70-130
LCS-V8638Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
94.111.211.9µg/m3Acetone 70-130
98.715.816.0µg/m3Benzene 70-130
10011.111.1µg/m31,3-Butadiene 70-130
10416.315.6µg/m3Carbon Disulfide 70-130
95.530.131.5µg/m3Carbon Tetrachloride 70-130
94.612.513.2µg/m3Chloroethane 70-130
98.724.124.4µg/m3Chloroform 70-130
98.010.110.3µg/m3Chloromethane 70-130
87.715.117.2µg/m3Cyclohexane 70-130
95.328.730.1µg/m31,3-Dichlorobenzene 70-130
98.324.324.7µg/m3Dichlorodifluoromethane 70-130
98.722.823.1µg/m31,2-Dichloropropane 70-130
91.88.659.42µg/m3Ethanol 70-130
99.417.918.0µg/m3Ethyl Acetate 70-130
Page 2 of 4Date:09/10/2021 02:40 PM
Page 19 of 24
Quality Control Data
21-239-0049Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
CTT-001
QC Prep Batch Method:
Volatile Organic Compounds in Air- GC/MS
TO-15
V8639QC Analytical Batch(es):
Analysis Method:
Analysis Description:
TO-15 Prep
QC Prep:V8638
LCS-V8638Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
10121.921.7µg/m3Ethylbenzene 70-130
10225.024.6µg/m34-Ethyltoluene 70-130
96.637.038.3µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 70-130
10220.920.5µg/m3Heptane 70-130
99.417.517.6µg/m3n-Hexane 70-130
91.011.212.3µg/m3Isopropyl Alchohol 70-130
94.514.014.8µg/m3Methyl Ethyl Ketone (MEK)70-130
94.619.420.5µg/m34-Methyl-2-Pentanone 70-130
95.416.617.4µg/m3Methylene Chloride 70-130
10527.626.2µg/m3Naphthalene 70-130
93.68.068.61µg/m3Propene 70-130
99.021.121.3µg/m3Styrene 70-130
10334.833.9µg/m3Tetrachloroethene 70-130
10219.118.8µg/m3Toluene 70-130
98.826.626.9µg/m3Trichloroethene 70-130
10429.128.1µg/m3Trichlorofluoromethane 70-130
10024.724.6µg/m31,2,4-Trimethylbenzene 70-130
10225.124.6µg/m31,3,5-Trimethylbenzene 70-130
96.812.412.8µg/m3Vinyl Chloride 70-130
99.521.621.7µg/m3o-Xylene 70-130
98.842.943.4µg/m3m,p-Xylene 70-130
99.44-Bromofluorobenzene (S)70-130
Page 3 of 4Date:09/10/2021 02:40 PM
Page 20 of 24
Quality Control Data
21-239-0049Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
CTT-001
QC Prep Batch Method:
Volatile Organic Compounds in Air- GC/MS
TO-15
V8649QC Analytical Batch(es):
Analysis Method:
Analysis Description:
TO-15 Prep
QC Prep:V8648
Associated Lab Samples: 94540, 94541, 94542, 94543
LRB-V8648 Matrix: AIRLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/01/21 12:334.750.2020.354µg/m3Acetone
09/01/21 12:335.000.169<0.169µg/m3Ethanol
09/01/21 12:334.920.1390.391µg/m3Isopropyl Alchohol
09/01/21 12:331.470.224<0.224µg/m3Methyl Ethyl Ketone (MEK)
09/01/21 12:332.460.110<0.110µg/m31,2,4-Trimethylbenzene
09/01/21 12:334-Bromofluorobenzene (S)107 70-130
LCS-V8648Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
87.310.411.9µg/m3Acetone 70-130
93.88.849.42µg/m3Ethanol 70-130
87.810.812.3µg/m3Isopropyl Alchohol 70-130
90.513.414.8µg/m3Methyl Ethyl Ketone (MEK)70-130
11728.824.6µg/m31,2,4-Trimethylbenzene 70-130
1114-Bromofluorobenzene (S)70-130
Page 4 of 4Date:09/10/2021 02:40 PM
Page 21 of 24
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:21-239-0049
Hart & Hickman (Charlotte)
01102
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Stacy L Ortiz Date & Time:08/27/2021 16:16:19
Special precautions or instructions included?
Comments:
Page 22 of 24
Page 23 of 24
Page 24 of 24
Appendix F
DEQ Risk Calculator Input/Output Forms
Version Date:
Basis:
Site Name:
Site Address:
DEQ Section:
Site ID:
Exposure Unit ID:
Submittal Date:
Reviewed By:
5/3/2021
Prepared By:Amir Stewart
Hart & Hickman
Worst Case Risk Calculation
Centro Railyard Apartments
1425 Winnifred Street, Charlotte, NC
Brownfields Program
19054-15-060
January 2021
November 2020 EPA RSL Table
North Carolina DEQ Risk Calculator
Table of Contents
Version Date: January 2021
Basis: November 2020 EPA RSL Table
Site ID: 19054-15-060
Exposure Unit ID: Worst Case Risk Calculation
Form No.
Input Form 1A Complete Exposure Pathways
Input Form 1B Exposure Factors and Target Risks
Input Form 1C Contaminant Migration Parameters
Input Form 1D Sample Statistics
Input Form 2A
Input Form 2B Groundwater Exposure Point Concentration Table
Input Form 2C Surface Water Exposure Point Concentration Table
Input Form 2D Soil Gas Exposure Point Concentration Table
Input Form 2E Indoor Air Exposure Point Concentration Table
Output Form 1A Risk for Individual Pathways
Output Form 1B Sitewide Risk
Output Form 2A Resident Soil
Output Form 2B Resident Groundwater Use
Output Form 2C Non-Residential Worker Soil
Output Form 2D Non-Residential Worker Groundwater Use
Output Form 2E Construction Worker Soil
Output Form 2F Recreator/Trespasser Soil
Output Form 2G Recreator/Trespasser Surface Water
Output Form 3A Resident Groundwater to Indoor Air
Output Form 3B Resident Soil Gas to Indoor Air
Output Form 3C Resident Indoor Air
Output Form 3D Non-Residential Worker Groundwater to Indoor Air
Output Form 3E Non-Residential Worker Soil Gas to Indoor Air
Output Form 3F Non-Residential Worker Indoor Air
Output Form 4A Soil to Groundwater - Forward Mode
Output Form 4B Groundwater to Groundwater - Forward Mode
Output Form 4C Soil to Surface Water - Forward Mode
Output Form 4D Groundwater to Surface Water - Forward Mode
Output Form 4E Soil to Groundwater - Backward Mode
Output Form 4F Groundwater to Groundwater - Backward Mode
Output Form 4G
Output Form 4H Groundwater to Surface Water - Backward Mode
Output Section 4 - Contaminant Migration to Worksheets
Output Section 3 - Vapor Intrusion Calculators
TOC
Description
North Carolina DEQ Risk Calculator
Complete Exposure Pathways
Version Date: January 2021
Basis: November 2020 EPA RSL Table
Site ID: 19054-15-060
Exposure Unit ID: Worst Case Risk Calculation
Note: Risk output will only be calculated for complete exposure pathways.
Receptor Pathway
Check box if
pathway
complete
Soil
Groundwater Use
Soil
Groundwater Use
Construction Worker Soil
Soil
Surface Water
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Source Soil
Source Groundwater
Source Soil
Source Groundwater
Input Form 1A
VAPOR INTRUSION PATHWAYS
DIRECT CONTACT SOIL AND WATER PATHWAYS
Resident
Non-Residential Worker
Recreator/Trespasser
Resident
Non-Residential Worker
CONTAMINANT MIGRATION PATHWAYS
Groundwater
Surface Water
North Carolina DEQ Risk Calculator
Exposure Point Concentrations
Version Date: January 2021
Basis: November 2020 EPA RSL Table
Site ID: 19054-15-060
Exposure Unit ID: Worst Case Risk Calculation
Description of Exposure Point Concentration Selection:
Exposure Point
Concentration
(ug/m3)
Notes:CAS Number Chemical Minimum Concentration (Qualifier)
Maximum Concentration (Qualifier)Units Location of Maximum Concentration
Detection Frequency
Range of Detection Limits
Concentration Used for Screening
Background Value
Screening Toxicity Value (Screening
Level) (n/c)
Potential ARAR/TBC Value
Potential ARAR/TBC Source
COPC Flag (Y/N)
Rationale for Selection or Deletion
149 67-64-1 Acetone
1.32 71-43-2 Benzene
0 106-99-0 Butadiene, 1,3-
0 75-15-0 Carbon Disulfide
0 56-23-5 Carbon Tetrachloride
1.06 67-66-3 Chloroform
2.25 74-87-3 Chloromethane
1.43 110-82-7 Cyclohexane
5.95 75-71-8 Dichlorodifluoromethane
0 78-87-5 Dichloropropane, 1,2-
7.78 141-78-6 Ethyl Acetate
0 75-00-3 Ethyl Chloride (Chloroethane)
1.52 100-41-4 Ethylbenzene
2.11 142-82-5 Heptane, N-
0 110-54-3 Hexane, N-
77.9 67-63-0 Isopropanol
56.7 78-93-3 Methyl Ethyl Ketone (2-Butanone)
6.43 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)
3.47 75-09-2 Methylene Chloride
0 91-20-3 ~Naphthalene
12.1 115-07-1 Propylene
2.39 100-42-5 Styrene
1.91 127-18-4 Tetrachloroethylene
43 108-88-3 Toluene
0 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-
0 79-01-6 Trichloroethylene
0 75-69-4 Trichlorofluoromethane
54.4 95-63-6 Trimethylbenzene, 1,2,4-
19.9 108-67-8 Trimethylbenzene, 1,3,5-
0 75-01-4 Vinyl Chloride
0 106-42-3 Xylene, P-
5.71 108-38-3 Xylene, m-
2.59 95-47-6 Xylene, o-
Input Form 2E
Indoor Air Exposure Point Concentration Table
Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion.
If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations
North Carolina DEQ Risk Calculator
Risk for Individual Pathways Output Form 1A
Version Date: January 2021
Basis: November 2020 EPA RSL Table
Site ID: 19054-15-060
Exposure Unit ID: Worst Case Risk Calculation
Receptor Pathway Hazard Index Risk exceeded?
Soil NC NC NC
Groundwater Use*NC NC NC
Soil NC NC NC
Groundwater Use*NC NC NC
Construction Worker Soil NC NC NC
Soil NC NC NC
Surface Water*NC NC NC
Receptor Pathway Hazard Index Risk exceeded?
Groundwater to Indoor Air NC NC NC
Soil Gas to Indoor Air NC NC NC
Indoor Air 1.4E-05 2.0E+00 YES
Groundwater to Indoor Air NC NC NC
Soil Gas to Indoor Air NC NC NC
Indoor Air 3.2E-06 4.7E-01 NO
Pathway Source
Source Soil NC
Source Groundwater NC
Source Soil NC
Source Groundwater NC
DIRECT CONTACT SOIL AND WATER CALCULATORS
Resident
Non-Residential Worker
Recreator/Trespasser
NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based
Surface Water
VAPOR INTRUSION CALCULATORS
Resident
Non-Residential Worker
CONTAMINANT MIGRATION CALCULATORS
Target Receptor Concentrations Exceeded?
Groundwater
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead
concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Vapor Intrusion - Resident Indoor Air
Version Date: January 2021
Basis: November 2020 EPA RSL Table
Site ID: 19054-15-060
Exposure Unit ID: Worst Case Risk Calculation
CAS #Chemical Name:
Indoor Air
Concentration
(ug/m3)
Target Indoor
Air Conc. for Carcinogens @
TCR = 1E-06
Conc. for Non-Carcinogens @
THQ = 0.2
Calculated
Risk
Calculated Non-
Hazard
67-64-171-43-2 3.7E-06 4.2E-02
106-99-075-15-0
56-23-567-66-3 8.7E-06 1.0E-02
74-87-3110-82-7
75-71-8
78-87-5
141-78-6
75-00-3
100-41-4 1.4E-06 1.5E-03
142-82-5
110-54-3
67-63-0 3.7E-01
78-93-3
108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)6.43 -6.3E+02 2.1E-03
75-09-2
91-20-3
115-07-1
100-42-5 Styrene 2.39 -2.1E+02 2.3E-03
127-18-4
108-88-3
76-13-1
79-01-6
75-69-4
95-63-6 8.7E-01
108-67-8 3.2E-01
75-01-4
106-42-3108-38-3
95-47-6
Cumulative:1.4E-05 2.0E+00
All concentrations are in ug/m3
** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate
carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3.
if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these
chemicals are likely not associated with vapor intrusion.
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air
Version Date: January 2021
Basis: November 2020 EPA RSL Table
Site ID: 19054-15-060
Exposure Unit ID: Worst Case Risk Calculation
CAS #Chemical Name:
Indoor Air
Concentration
(ug/m3)
Target Indoor
Air Conc. for
Carcinogens @ TCR = 1E-06
Conc. for Non-
Carcinogens @ THQ = 0.2
Calculated
Risk
Non-
Hazard
67-64-1
71-43-2
106-99-0
75-15-0
56-23-567-66-3 2.0E-06 2.5E-03
74-87-3
110-82-7
75-71-878-87-5
141-78-6
75-00-3100-41-4
142-82-5
110-54-3
67-63-078-93-3
108-10-1
75-09-291-20-3
115-07-1
100-42-5 Styrene 2.39 -8.8E+02 5.5E-04
127-18-4
108-88-3
76-13-179-01-6
75-69-4
95-63-6 2.1E-01
108-67-8
75-01-4
106-42-3
108-38-395-47-6
Cumulative:3.2E-06 4.7E-01
Output Form 3F
** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk
or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3.
air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not
associated with vapor intrusion.
North Carolina DEQ Risk Calculator
Version Date:
Basis:
Site Name:
Site Address:
DEQ Section:
Site ID:
Exposure Unit ID:
Submittal Date:
Reviewed By:
9/14/2021
Prepared By:H&H
IAS-1/IAS-DUP
North Carolina Department of Environmental Quality
Risk Calculator
Centro Railyard
1425 Winnifred Street
Brownfields
June 2021
May 2021 EPA RSL Table
North Carolina DEQ Risk Calculator
Complete Exposure Pathways
Version Date: June 2021
Basis: May 2021 EPA RSL Table
Site ID:
Exposure Unit ID: IAS-1/IAS-DUP
Note: Risk output will only be calculated for complete exposure pathways.
Receptor Pathway
Check box if
pathway
complete
Soil
Groundwater Use
Soil
Groundwater Use
Construction Worker Soil
Soil
Surface Water
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Source Soil
Source Groundwater
Source Soil
Source Groundwater
Input Form 1A
VAPOR INTRUSION PATHWAYS
DIRECT CONTACT SOIL AND WATER PATHWAYS
Resident
Non-Residential Worker
Recreator/Trespasser
Resident
Non-Residential Worker
CONTAMINANT MIGRATION PATHWAYS
Groundwater
Surface Water
North Carolina DEQ Risk Calculator
Exposure Point Concentrations
Version Date: June 2021
Basis: May 2021 EPA RSL Table
Site ID:
Exposure Unit ID: IAS-1/IAS-DUP
Description of Exposure Point Concentration Selection:
Exposure Point
Concentration
(ug/m3)
Notes: CAS Number Chemical
Minimum
Concentration
(Qualifier)
Maximum
Concentration
(Qualifier)
Units
Location of
Maximum
Concentration
Detection
Frequency
Range of
Detection
Limits
Concentration
Used for
Screening
Background
Value
Screening
Toxicity Value
(Screening
Level) (n/c)
Potential
ARAR/TBC
Value
Potential
ARAR/TBC
Source
COPC Flag
(Y/N)
Rationale for
Selection or
Deletion
19700 67-64-1 Acetone ug/m3
16.6 75-15-0 Carbon Disulfide ug/m3
14.5 74-87-3 Chloromethane ug/m3
10.4 100-41-4 Ethylbenzene ug/m3
5970 109-99-9 ~Tetrahydrofuran ug/m3
125 67-63-0 Isopropanol ug/m3
3870 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3
29 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3
160 100-42-5 Styrene ug/m3
9.27 108-88-3 Toluene ug/m3
10400 95-63-6 Trimethylbenzene, 1,2,4-ug/m3
3530 108-67-8 Trimethylbenzene, 1,3,5-ug/m3
592 1330-20-7 Xylenes ug/m3
Input Form 2D
Soil Gas Exposure Point Concentration Table
Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.
If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations
North Carolina DEQ Risk Calculator
Exposure Point Concentrations
Version Date: June 2021
Basis: May 2021 EPA RSL Table
Site ID:
Exposure Unit ID: IAS-1/IAS-DUP
Description of Exposure Point Concentration Selection:
Exposure Point
Concentration
(ug/m3)
Notes: CAS Number Chemical
Minimum
Concentration
(Qualifier)
Maximum
Concentration
(Qualifier)
Units
Location of
Maximum
Concentration
Detection
Frequency
Range of
Detection
Limits
Concentration
Used for
Screening
Background
Value
Screening
Toxicity Value
(Screening
Level) (n/c)
Potential
ARAR/TBC
Value
Potential
ARAR/TBC
Source
COPC Flag
(Y/N)
Rationale for
Selection or
Deletion
184 67-64-1 Acetone ug/m3
1.95 71-43-2 Benzene ug/m3
1.1 75-15-0 Carbon Disulfide ug/m3
0.742 56-23-5 Carbon Tetrachloride ug/m3
2.59 67-66-3 Chloroform ug/m3
2.12 74-87-3 Chloromethane ug/m3
22 141-78-6 Ethyl Acetate ug/m3
3 100-41-4 Ethylbenzene ug/m3
8.98 142-82-5 Heptane, N-ug/m3
99.5 67-63-0 Isopropanol ug/m3
21.7 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3
1.04 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3
2.51 75-09-2 Methylene Chloride ug/m3
76.3 100-42-5 Styrene ug/m3
1.96 127-18-4 Tetrachloroethylene ug/m3
24.5 108-88-3 Toluene ug/m3
0.644 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3
1.46 79-01-6 Trichloroethylene ug/m3
1.88 75-69-4 Trichlorofluoromethane ug/m3
17.7 95-63-6 Trimethylbenzene, 1,2,4-ug/m3
5.76 108-67-8 Trimethylbenzene, 1,3,5-ug/m3
11.39 1330-20-7 Xylenes ug/m3
Input Form 2E
Indoor Air Exposure Point Concentration Table
Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion.
If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations
North Carolina DEQ Risk Calculator
Risk for Individual Pathways Output Form 1A
Version Date: June 2021
Basis: May 2021 EPA RSL Table
Site ID:
Exposure Unit ID: IAS-1/IAS-DUP
Receptor Pathway Carcinogenic
Ris Hazard Index Risk exceeded?
Soil 0.0E+00 0.0E+00 NO
Groundwater Use* NC NC NC
Soil 0.0E+00 0.0E+00 NO
Groundwater Use* NC NC NC
Construction Worker Soil NC NC NC
Soil NC NC NC
Surface Water* NC NC NC
Receptor Pathway Carcinogenic
Ris Hazard Index Risk exceeded?
Groundwater to Indoor Air 0.0E+00 0.0E+00 NO
Soil Gas to Indoor Air 2.8E-07 7.0E+00 YES
Indoor Air 3.4E-05 2.2E+00 YES
Groundwater to Indoor Air 0.0E+00 0.0E+00 NO
Soil Gas to Indoor Air 2.1E-08 5.6E-01 NO
Indoor Air 7.6E-06 5.3E-01 NO
Pathway Source
Source Soil NM
Source Groundwater NM
Source Soil NM
Source Groundwater NM
3. NM = Not Modeled
4. NC = Pathway not calculated
DIRECT CONTACT SOIL AND WATER CALCULATORS
Resident
Non-Residential Worker
Recreator/Trespasser
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the
NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based
closure.
Surface Water Exceedence of 2B at Receptor?
Exceedence of 2B at Receptor?
VAPOR INTRUSION CALCULATORS
Resident
Non-Residential Worker
CONTAMINANT MIGRATION CALCULATORS
Target Receptor Concentrations Exceeded?
Groundwater Exceedence of 2L at Receptor?
Exceedence of 2L at Receptor?
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead
concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
Notes:
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Vapor Intrusion - Resident Indoor Air
Version Date: June 2021
Basis: May 2021 EPA RSL Table
Site ID:
Exposure Unit ID: IAS-1/IAS-DUP
CAS # Chemical Name:
Indoor Air
Concentration
(ug/m3)
Target Indoor
Air Conc. for
Carcinogens @
TCR = 1E-06
Target Indoor Air
Conc. for Non-
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non-
Carcinogenic
Hazard
Quotient
67-64-1 Acetone 184 - 6.5E+03 5.7E-03
71-43-2 Benzene 1.95 3.6E-01 6.3E+00 5.4E-06 6.2E-02
75-15-0 Carbon Disulfide 1.1 - 1.5E+02 1.5E-03
56-23-5 Carbon Tetrachloride 0.742 4.7E-01 2.1E+01 1.6E-06 7.1E-03
67-66-3 Chloroform 2.59 1.2E-01 2.0E+01 2.1E-05 2.5E-02
74-87-3 Chloromethane 2.12 - 1.9E+01 2.3E-02
141-78-6 Ethyl Acetate 22 - 1.5E+01 3.0E-01
100-41-4 Ethylbenzene 3 1.1E+00 2.1E+02 2.7E-06 2.9E-03
142-82-5 Heptane, N- 8.98 - 8.3E+01 2.2E-02
67-63-0 Isopropanol 99.5 - 4.2E+01 4.8E-01
78-93-3 Methyl Ethyl Ketone (2-Butanone) 21.7 - 1.0E+03 4.2E-03
108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone) 1.04 - 6.3E+02 3.3E-04
75-09-2 Methylene Chloride 2.51 1.0E+02 1.3E+02 2.5E-08 4.0E-03
100-42-5 Styrene 76.3 - 2.1E+02 7.3E-02
127-18-4 Tetrachloroethylene 1.96 1.1E+01 8.3E+00 1.8E-07 4.7E-02
108-88-3 Toluene 24.5 - 1.0E+03 4.7E-03
76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 0.644 - 1.0E+03 1.2E-04
79-01-6 Trichloroethylene 1.46 4.8E-01 4.2E-01 3.1E-06 7.0E-01
75-69-4 Trichlorofluoromethane 1.88 - -
95-63-6 Trimethylbenzene, 1,2,4- 17.7 - 1.3E+01 2.8E-01
108-67-8 Trimethylbenzene, 1,3,5- 5.76 - 1.3E+01 9.2E-02
1330-20-7 Xylenes 11.39 - 2.1E+01 1.1E-01
Cumulative: 3.4E-05 2.2E+00
All concentrations are in ug/m3
Output Form 3C
** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate
carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3.
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if
indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals
are likely not associated with vapor intrusion.
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air
Version Date: June 2021
Basis: May 2021 EPA RSL Table
Site ID:
Exposure Unit ID: IAS-1/IAS-DUP
CAS # Chemical Name:
Soil Gas
Concentration
(ug/m3)
Calculated
Indoor Air
Concentration
(ug/m3)
Target Indoor
Air Conc. for
Carcinogens @
TCR = 1E-06
Target Indoor Air
Conc. for Non-
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non-
Carcinogenic
Hazard
Quotient
67-64-1 Acetone 19700 591 - 6.5E+03 1.8E-02
75-15-0 Carbon Disulfide 16.6 0.498 - 1.5E+02 6.8E-04
74-87-3 Chloromethane 14.5 0.435 - 1.9E+01 4.6E-03
100-41-4 Ethylbenzene 10.4 0.312 1.1E+00 2.1E+02 2.8E-07 3.0E-04
109-99-9 ~Tetrahydrofuran 5970 179.1 - 4.2E+02 8.6E-02
67-63-0 Isopropanol 125 3.75 - 4.2E+01 1.8E-02
78-93-3 Methyl Ethyl Ketone (2-Butanone) 3870 116.1 - 1.0E+03 2.2E-02
108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone) 29 0.87 - 6.3E+02 2.8E-04
100-42-5 Styrene 160 4.8 - 2.1E+02 4.6E-03
108-88-3 Toluene 9.27 0.2781 - 1.0E+03 5.3E-05
95-63-6 Trimethylbenzene, 1,2,4- 10400 312 - 1.3E+01 5.0E+00
108-67-8 Trimethylbenzene, 1,3,5- 3530 105.9 - 1.3E+01 1.7E+00
1330-20-7 Xylenes 592 17.76 - 2.1E+01 1.7E-01
Cumulative: 2.8E-07 7.0E+00
All concentrations are in ug/m3
Output Form 3B
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion
risk, no risk values are calculated for these chemicals.
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air
Version Date: June 2021
Basis: May 2021 EPA RSL Table
Site ID:
Exposure Unit ID: IAS-1/IAS-DUP
CAS # Chemical Name:
Indoor Air
Concentration
(ug/m3)
Target Indoor
Air Conc. for
Carcinogens @
TCR = 1E-06
Target Indoor Air
Conc. for Non-
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non-
Carcinogenic
Hazard
Quotient
67-64-1 Acetone 184 - 2.7E+04 1.4E-03
71-43-2 Benzene 1.95 1.6E+00 2.6E+01 1.2E-06 1.5E-02
75-15-0 Carbon Disulfide 1.1 - 6.1E+02 3.6E-04
56-23-5 Carbon Tetrachloride 0.742 2.0E+00 8.8E+01 3.6E-07 1.7E-03
67-66-3 Chloroform 2.59 5.3E-01 8.6E+01 4.9E-06 6.0E-03
74-87-3 Chloromethane 2.12 - 7.9E+01 5.4E-03
141-78-6 Ethyl Acetate 22 - 6.1E+01 7.2E-02
100-41-4 Ethylbenzene 3 4.9E+00 8.8E+02 6.1E-07 6.8E-04
142-82-5 Heptane, N- 8.98 - 3.5E+02 5.1E-03
67-63-0 Isopropanol 99.5 - 1.8E+02 1.1E-01
78-93-3 Methyl Ethyl Ketone (2-Butanone) 21.7 - 4.4E+03 9.9E-04
108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone) 1.04 - 2.6E+03 7.9E-05
75-09-2 Methylene Chloride 2.51 1.2E+03 5.3E+02 2.0E-09 9.6E-04
100-42-5 Styrene 76.3 - 8.8E+02 1.7E-02
127-18-4 Tetrachloroethylene 1.96 4.7E+01 3.5E+01 4.2E-08 1.1E-02
108-88-3 Toluene 24.5 - 4.4E+03 1.1E-03
76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 0.644 - 4.4E+03 2.9E-05
79-01-6 Trichloroethylene 1.46 3.0E+00 1.8E+00 4.9E-07 1.7E-01
75-69-4 Trichlorofluoromethane 1.88 - -
95-63-6 Trimethylbenzene, 1,2,4- 17.7 - 5.3E+01 6.7E-02
108-67-8 Trimethylbenzene, 1,3,5- 5.76 - 5.3E+01 2.2E-02
1330-20-7 Xylenes 11.39 - 8.8E+01 2.6E-02
Cumulative: 7.6E-06 5.3E-01
All concentrations are in u /3
Output Form 3F
** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk
or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3.
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if
indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are
likely not associated with vapor intrusion.
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air
Version Date: June 2021
Basis: May 2021 EPA RSL Table
Site ID:
Exposure Unit ID: IAS-1/IAS-DUP
CAS # Chemical Name:
Soil Gas
Concentration
(ug/m3)
Calculated
Indoor Air
Concentration
(ug/m3)
Target Indoor
Air Conc. for
Carcinogens @
TCR = 1E-06
Target Indoor Air
Conc. for Non-
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non-
Carcinogenic
Hazard
Quotient
67-64-1 Acetone 19700 197 - 2.7E+04 1.5E-03
75-15-0 Carbon Disulfide 16.6 0.166 - 6.1E+02 5.4E-05
74-87-3 Chloromethane 14.5 0.145 - 7.9E+01 3.7E-04
100-41-4 Ethylbenzene 10.4 0.104 4.9E+00 8.8E+02 2.1E-08 2.4E-05
109-99-9 ~Tetrahydrofuran 5970 59.7 - 1.8E+03 6.8E-03
67-63-0 Isopropanol 125 1.25 - 1.8E+02 1.4E-03
78-93-3 Methyl Ethyl Ketone (2-Butanone) 3870 38.7 - 4.4E+03 1.8E-03
108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone) 29 0.29 - 2.6E+03 2.2E-05
100-42-5 Styrene 160 1.6 - 8.8E+02 3.7E-04
108-88-3 Toluene 9.27 0.0927 - 4.4E+03 4.2E-06
95-63-6 Trimethylbenzene, 1,2,4- 10400 104 - 5.3E+01 4.0E-01
108-67-8 Trimethylbenzene, 1,3,5- 3530 35.3 - 5.3E+01 1.3E-01
1330-20-7 Xylenes 592 5.92 - 8.8E+01 1.4E-02
Cumulative: 2.1E-08 5.6E-01
All concentrations are in ug/m3
Output For
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk,
no risk values are calculated for these chemicals.
North Carolina DEQ Risk Calculator