6004_McGuireLF2_2023_Q4_GWMR_FID1833511_20240325

('DUKE
ENERGT.
March 25, 2024
North Carolina Department of Environmental Quality
Division of Waste Management
Solid Waste Section
1646 Mail Service Center
Raleigh, North Carolina 28778
Attn: Ms. Sarah Moutos (submitted electronically)
Re: Semi -Annual Water Quality Monitoring Report — December 2023
Duke Energy Carolinas, LLC
McGuire Nuclear Station
Landfill No. 2 (Synthetically Lined), Permit #60-04
Dear Ms. Moutos:
Duke Energy
McGuire Nuclear Station
12700 Hagers Ferry Road
Huntersville, NC 28078
Duke Energy is providing the result of the second 2023 semi-annual groundwater monitoring for the Duke Energy Carolinas
McGuire Landfill No. 2 (Synthetically Lined), located near Huntersville, North Carolina.
On December 4-5, 2023, groundwater, surface water, and leachate samples were collected in accordance with the McGuire
Landfill No. 2 Sampling and Analysis Plan.
The groundwater sampling field and analytical results are summarized in Table 4. The analytical results for the constituents
are compared to the groundwater standards found in Title 15A NCAC 02L .0202 (21- Standards). Groundwater results with
values that attain or exceed the 2L Standards (or outside of 2L Standard range for pH) are indicated on Table 4 by yellow
highlighting. A summary of the groundwater analytical results that attain or exceed the 2L Standards (or outside of 2L
Standard range for pH) and a preliminary analysis of the cause and significance of such occurrences are presented in
Table 5. In one or more wells, pH measurements were reported outside of the 2L Standard pH range, but no other 2L
exceedances were reported for the December 2023 monitoring event.
The surface water field and analytical results are summarized in Table 6. The surface water analytical results for the
constituents are compared to the surface water standards found in Title 15A NCAC 02B .0211 (213 Standard) for Class C
WS IV waters. No 2B Standards were exceeded during the December 2023 monitoring event.
The leachate field and analytical results are summarized in Table 7. The leachate sample was collected from the in -flow
pipe which conveys leachate from the landfill into the leachate pond.
Duke Energy personnel sample designated locations for groundwater, surface water, and leachate at the McGuire Landfill
No. 2 (Synthetically Lined) semi-annually during June and December. The next water quality monitoring event for Landfill
No. 2 is planned for June 2024 with a report of monitoring results to follow.
If you need additional information regarding this submittal, please contact Ashley Healy at Ashley.Healyeduke-energy.com
or [phone].
Sincere)
✓1��`��%'` - "tom
Brent Bare
Duke Energy
McGuire Nuclear Station
Plant Manager
www.duke-energy.com Page 1 of 1

�R USE ONLY ❑Paper Report ❑Electronic Data -Email CD (data loaded: Yes / No Doc/Event #:
NC DENR Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
S&ME, Inc. (Consultant for Duke Energy)
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Julie P. Robertson, P.G. Phone: [phone]
E-mail: [e-mail]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Duke Energy Carolinas, LLC 12700 Hagers Ferry Road
McGuire, Landfill No. 2 Huntersville, NC 28078 6004 .0500 December 4-5, 2023
(Synthetically Lined)
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring x❑ Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells ❑
Leachate monitoring data
Surface water monitoring data ❑
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
RX Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Julie P. Robertson, P.G. Senior Geologist 704-523-4726
Facilitv Representative Name (Print) Title (Area Code) Telephone Number
loxes` - 3/21/2024 Affix NC Licensed/ Professional Geologist Seal
Signature Date
2016 Ayrsley Town Blvd., Suite 2-A, Charlotte, NC 28273
Facility Representative Address
S&ME Engineering License # F-0176, S&ME Geology License # C-145
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009

Semi -Annual Water Quality Monitoring Report
December 2023 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 2
(Synthetically Lined) Permit No. 6004-INDUS
Mecklenburg County, North Carolina
S&ME Project No. 23350793, Ph. 775C

REPORT VERIFICATION
PROJECT: SEMI-ANNUAL WATER QUALITY MONITORING REPORT
DUKE ENERGY CAROLINAS, MCGUIRE, LANDFILL NO. 2
(SYNTHETICALLY LINED) PERMIT NO. 6004-INDUS
S&ME PROJECT NO. 22350793, PH. 775C
TITLE: DECEMBER 2023 SAMPLING EVENT
This document has been reviewed for accuracy and quality commensurate with the intended
application.
Prepared by:
Approved by,--
Date: 3/21 /2024
Date: 3/21 /2024
Licensed Geologist Seal:
err
S&ME, Inc.
2016 Ayrsley Town Blvd., Suite 2-A
Charlotte, North Carolina 28273
North Carolina Geological Corporation Number C-145
S&ME, Inc. 12016 Ayrsley Town Blvd., Suite 2-A I Charlotte, NC 28273 1 p 704.523.4726 1 www.smeinc.com

Semi -Annual Water Quality Monitoring Report — December 2023 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 2
(Synthetically Lined) Permit No. 6004-INDUS I s
S&ME Project No. 22350793, Ph. 775C
Table of Contents
1.0 Background........................................................................................................................1
1.1 Site Description...............................................................................................................................1
1.2 Hydrologic Setting.........................................................................................................................1
1.3 Monitoring Program......................................................................................................................1
2.0 Methods..............................................................................................................................1
2.1 Sampling and Analysis Methods.................................................................................................1
2.1.1 Groundwater, Surface Water, and Leachate.....................................................................................1
2.1.2 Radiological Samples.........................................................................................................................2
2.2 Statement of Work..........................................................................................................................2
2.3 Site Groundwater Flow.................................................................................................................3
2.4 Analytical Results...........................................................................................................................3
2.4.1 Groundwater.....................................................................................................................................3
2.4.2 Surface Water....................................................................................................................................3
2.4.3 Leachate.............................................................................................................................................4
2.4.4 Radiological Samples.........................................................................................................................4
2.4.5 Quality Assurance / Quality Control...............................................................................................4
Appendices
Appendix I — Figures
Appendix II — Tables
Appendix III — Field Sampling Forms
Appendix IV — Laboratory Reports and Chain -of -Custody Forms
Appendix V — Rainfall Data and Leachate Generation Rates (July 2023 through December 2023)
March 21, 2024 ii

Semi -Annual Water Quality Monitoring Report — December 2023 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 2
(Synthetically Lined) Permit No. 6004-INDUS I s
S&ME Project No. 22350793, Ph. 775C
1.0 Background
1.1 Site Description
The Duke Energy Carolinas, McGuire, Landfill #2 (Synthetically Lined)' (hereafter, landfill) is located at the McGuire
Nuclear Station in Mecklenburg County, North Carolina. The landfill is permitted under North Carolina
Department of Environmental Quality (NCDEQ) Solid Waste Permit No. 6004-INDUS and currently accepts waste.
The landfill was constructed with a high -density polyethylene (HDPE) synthetic liner and leachate collection and
removal system. Leachate and contact stormwater are collected in a synthetically lined leachate collection pond
and pumped to the McGuire Nuclear Station wastewater treatment system. The landfill and surrounding areas are
shown on Figure 1 in Appendix I.
1.2 Hydrologic Setting
The landfill is located south of North Carolina (NC) Highway 73, north of Cashion Road and west of Lindeman
Road as shown on Figures 1 and 2 in Appendix I. Cashion Road runs along a surface water divide, with surface
flow draining to the northwest and the southeast. A surface water drainage feature located northeast of the
landfill drains towards the northwest to an unnamed perennial stream, which discharges into the Catawba River.
The Catawba River is classified as a Class C Water Supply -IV water source, (WS-IV).
1.3 Monitoring Program
As described in the Sampling and Analysis Plan (SAP) dated May 19, 2022, the current monitoring system at the
landfill consists of the following:
Monitoring Wells:
Surface Water Sample Locations:
Leachate Sample Location:
MW-5R2
MW-8
MW-5A
MW-8A
MW-6
MW-9
MW-6A
MW-9A
MW-7R2
MW-10A
MW-7A
SW-1
SW-2
Leachate Pond (in -flow pipe)
' In response to the North Carolina Division of Public Health, Radiation Protection Section, November 17, 2006 letter to Duke
Energy, LLC, Duke Energy offered to indicate the landfill as synthetically lined in reports.
z Replacement monitoring wells MW-5R and MW-7R were installed on October 10th and 11th, 2076 (respectively). The original
MW-5 and MW-7 wells did not consistently produce enough water for groundwater sampling. Each of these replacement wells
were installed deeper than the original wells, with a 15-foot screened interval, per approval from NCDEQ (Approval Replacement
Monitoring Wells MW-5 and MW-7 signed by Elizabeth Werner, Permitting Hydrogeologist dated July 27, 2076).
March 21, 2024

Semi -Annual Water Quality Monitoring Report — December 2023 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 2 .�
(Synthetically Lined) Permit No. 6004-INDUS
S&ME Project No. 22350793, Ph. 775C
Monitoring wells were installed as well pairs consisting of one shallow well and one deep well (with the exception
of monitoring well MW-10A, which does not have an accompanying shallow well). Wells with "A" designations
represent the deeper well within each well pair. Wells with "R" designations represent replacement wells. As
designated in the SAP, monitoring well location MW-5R is upgradient and considered to represent background
conditions for the landfill. Well pair MW-9 and MW-9A were installed adjacent to and downgradient from the
leachate pond. The remaining wells were installed adjacent to the landfill review and compliance boundaries. Well
construction information is summarized in Table 1 in Appendix II.
Surface water samples are collected from two locations, SW-1 and SW-2, as shown on Figure 2 in Appendix I.
Surface water sample location SW-1 is collected from an unnamed perennial stream northeast of the landfill and
serves as the background surface water sample location for this monitoring program. Surface water sample
location SW-2 is also collected from an unnamed perennial steam, downstream from surface water sample
location SW-1 and west of the landfill.
The leachate sample is collected from the end of the in -flow pipe, which conveys leachate from the landfill to the
synthetically lined leachate collection pond. The leachate pond resumed permanent operational status in February
2021 after the synthetic liner system was replaced at the end of 2020. The locations of the monitoring wells,
surface water sample locations, and the leachate pond sample location are shown on Figure 2 in Appendix I.
2.0 Methods
2.1 Sampling and Analysis Methods
Groundwater, surface water, and leachate sampling activities were performed by Duke Energy Groundwater
Science Group (Duke Energy Carolinas Field Certification #99046001), in general accordance with the North
Carolina Solid Waste Management Guidelines. Copies of the December 2023 field sampling forms are included in
Appendix III. The parameters and constituents reported were selected in accordance with the SAP and the
NCDEQ Division of Waste Management, Solid Waste Section and were analyzed by the Duke Energy Analytical
Laboratory (North Carolina Laboratory Certification #248), Pace Analytical Services (North Carolina Laboratory
Certification #329), and EnRad Laboratories. Each of the laboratory reports and chain -of -custody forms are
included in Appendix IV.
2.1.1 Groundwater, Surface Water, and Leachate
The groundwater, surface water, and leachate samples were analyzed for the following parameters using the
following analytical methods in accordance with the SAP:
• Barium, calcium, magnesium, potassium, and sodium using SW-846 EPA Test Method 6010D
• Arsenic, cadmium, chromium, lead, selenium, and silver using SW-846 EPA Test Method 6020B
• Mercury using SW-846 EPA Test Method 7470A
• Sulfate and Chloride using SW-846 EPA Test Method 9056A
March 21, 2024

Semi -Annual Water Quality Monitoring Report — December 2023 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 2
(Synthetically Lined) Permit No. 6004-INDUS
S&ME Project No. 22350793, Ph. 775C
• Alkalinity using Standard Method (SM) 2320B
• TPH Diesel Range Organics (TPH-DRO) using SW-846 EPA Test Method 8015C
• 1,4-Dioxane using SW-846 EPA Test Method 8260D (SIM)
• Volatile organic compounds (VOCs) using SW-846 EPA Test Method 8260D3
The surface water samples were also field -filtered using a 0.45-micron in -line filter and dissolved analyses were
performed for the following constituents:
Arsenic, cadmium, chromium, lead, and silver using SW-846 EPA Test 6020B
2.1.2 Radiological Samples
In accordance with the requirements of the Radioactive Materials License No. 060-0379-7 issued by the North
Carolina Department of Health and Human Services Radiation Protection Section, the following radiological
analyses were performed on groundwater and surface water samples:
• Gross alpha and beta radioactivity using ASTM Method D7283-171
• Tritium using ASTM Method D4107-085
• Gamma radioactivity for select isotopes using EPA Method 901.1
2.2 Statement of Work
S&ME completed the following tasks:
Received field sampling data from Duke Energy for monitoring wells MW-5R, MW-5A, MW-6, MW-6A,
MW-7R, MW-7A, MW-8, MW-8A, MW-9, MW-9A, and MW-10A. Field sampling data was also received for
surface water sample locations SW-1 and SW-2 and the leachate pond. Each of the samples were
collected by the Duke Energy Groundwater Sciences Group on December 41" and 5t", 2023. S&ME received
the field data from Duke Energy via e-mail correspondence from Ashley Healy (Duke Energy) to Jasmine
Tayouga (S&ME) on January 8t", 2024, and the laboratory analytical results were received on February 201n
2024.
• Reviewed the laboratory analytical results and the Electronic Data Deliverables (EDDs) provided by Duke
Energy for the samples noted above.
• Developed a shallow groundwater contour map and calculated groundwater flow velocities using survey
data and groundwater levels measured by Duke Energy Groundwater Sciences Group.
3Laboratory analytical methods for VOCs have changed from SW-846 EPA Test Method 8260B to SW-846 EPA Test Method
8260D.
°Laboratory analytical methods for gross alpha and beta radioactivity have changed from EPA 900ISM7110B to ASTM D7283-77.
5Laboratory analytical methods for Tritium have changed from EPA 906.0 Modified to ASTM D4107-08.
March 21, 2024

Semi -Annual Water Quality Monitoring Report — December 2023 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 2
(Synthetically Lined) Permit No. 6004-INDUS s
S&ME Project No. 22350793, Ph. 775C
• Duke Energy also provided S&ME (via e-mail correspondence) with the monthly rainfall data for McGuire
Nuclear Station and monthly leachate generation rates (for July 2023 through December 2023). This data
was received by S&ME on February 19, 2024.
2.3 Site Groundwater Flow
Shallow groundwater surface contours and groundwater flow direction in the vicinity of the landfill are shown on
Figure 3 in Appendix I. These contours were developed using the depth to groundwater measurements in the
shallow wells on the date of sampling and top of well casing elevations. Calculated groundwater flow velocities are
presented on Table 2 in Appendix II.
Based on groundwater elevations calculated for the December 2023 sampling event, groundwater flow is
generally from the southeast to the north and northwest toward the Catawba River.
2.4 Analytical Results
2.4.1 Groundwater
Laboratory results for groundwater samples were compared to the Title 15A NCAC Subchapter 2L Standards (2L
Standards) to evaluate compliance with NCDEQ groundwater quality standards. In one or more wells, pH
measurements were reported outside of the 2L Standard pH range. No other exceedances of 2L Standards were
reported for groundwater samples collected during the December 2023 sampling event.
A summary of field data parameters recorded prior to sample collection is presented in Table 3 in Appendix II. A
summary of groundwater analytical results for the December 2023 sampling event is presented in Table 4 in
Appendix II. A summary of the groundwater analytical results that equal or exceed the 2L Standards and a
comparison to historical concentration ranges are presented in Table 5 in Appendix II.
2.4.2 Surface Water
Laboratory results for the surface water samples (SW-1 and SW-2) were compared to the Title 15A NCAC
Subchapter 2B Standards (213 Standards) for Class C, WS-IV waters to evaluate compliance with NCDEQ surface
water quality standards. It should be noted that Mercury was detected in both surface water samples at
concentrations that exceeded the 2B Standard; however, both concentrations were noted with a 'J' flag by the
laboratory, indicating these concentrations are estimates as they fall between the laboratory Method Detection
Limit (MDL) and the laboratory Method Reporting Limit (MRL). No other constituents exceeded 2B Standards in
the surface water samples collected during the December 2023 sampling event.
A summary of field data parameters recorded prior to sample collection is presented in Table 3 in Appendix II. A
summary of surface water analytical results for the December 2023 sampling event is presented in Table 6 in
Appendix II. A summary of the surface water analytical results that equal or exceed the 2B Standards and a
comparison to historical concentration ranges are presented in Table 7 in Appendix II.
March 21, 2024

Semi -Annual Water Quality Monitoring Report — December 2023 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 2 �r
(Synthetically Lined) Permit No. 6004-INDUS
S&ME Project No. 22350793, Ph. 775C
2.4.3 Leachate
The leachate sample was collected from the in -flow pipe which conveys leachate from the landfill into the leachate
pond. A summary of field data parameters recorded at the time of sample collection is presented in Table 3 in
Appendix II. A summary of analytical results for the December 2023 sampling event is presented in Table 8 in
Appendix II. Monthly rainfall data for McGuire Nuclear Station and leachate generation rates (for July 2023
through December 2023) were provided by Duke Energy and are located in Appendix V. S&ME did not evaluate
the leachate analytical results, nor the monthly rainfall and leachate generation data.
2.4.4 Radiological Samples
The results of the radiological analyses for the groundwater, surface water, and leachate samples are presented in
Table 9 in Appendix II. A copy of the laboratory report has been submitted to the North Carolina Department of
Health and Human Services Radiation Protection Section for reference and is also included in this report in
Appendix IV. S&ME did not evaluate this data.
2.4.5 Quality Assurance / Quality Control
Field -performed quality assurance and quality control (QA/QC) consisted of the collection and analysis of two field
blanks (one on each day of sampling) to evaluate if contamination was imparted to the samples by the sample
container, preservative, or other exogenous sources. One field duplicate sample was also collected as a measure of
sampling and analytical precision. Samples for the monitoring wells, surface water locations, and leachate were
submitted to Duke Energy Analytical Laboratories on December 5t", 2023.
Additional QA/QC data, laboratory analyses, and chain -of -custody forms are included in Appendix IV.
March 21, 2024 4

Appendices

Appendix I - Figures

z
LL f
r _ .
cd
0
LEACHATE POND
SAMPLE LOCATION
MW-9R/MW-9A O MW-7R/MW-7A
O `'000
f%V-8/MW-8A
MW-6/MW-6A
LANDFILL '
`�'• NO. 1
NOTES: 0
GIS BASE LAYERS WERE OBTAINED FROM THE OWNER. 2022 AERIAL IMAGERY WAS
OBTAINED FROM MECKLENBURG COUNTY. THIS MAP IS FOR INFORMATIONAL PURPOSES
ONLY. ALL FEATURE LOCATIONS DISPLAYED ARE APPROXIMATE. THEY ARE NOT BASED ON
CIVIL SURVEY INFORMATION, UNLESS STATED OTHERWISE. GRAPHIC SCALE
300 600 v
(IN FEET)
LANDFILL
NO. 2
�. MW-10A
MW-5R/MW-5A
SW-1
0 �
Uu
Q U
W �
W p
W
r
� C
cn
LEGEND
GROUNDWATER MONITORING WELL LOCATIONS
SURFACE WATER SAMPLE LOCATION
LEACHATE POND SAMPLE LOCATION
►—►—►STREAMS WITH FLOW DIRECTION
LANDFILL NO. 2 COMPLIANCE BOUNDARY
LANDFILL NO. 2 LIMITS OF WASTE
LANDFILL NO. 2 REVIEW BOUNDARY
DUKE ENERGY PROPERTY BOUNDARY
STREETS
LEACHATE POND BOUNDARY
LANDFILL NO. 1
2' CONTOURS
10' CONTOURS
N
] <
Z Z
+ � J
OO
O cl::
] �.o <
< U
Z Z
{ OHO
� � z
U
] cv
j w O p
Z Z U
W J
W J
L
� o m
0 Z Z
< w
J J
U
w
V
SCALE:
1=300'
DATE:
2-14-2024
PROJECT NUMBER:
23350793, PH.775C
FIGURE NO
2

Appendix II - Tables

Table 1: Well Construction Information
Landfill No. 2 (Synthetically Lined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station III E
S&ME Project No: 23350793, Ph. 775C
Well ID
MW-5R
Install Date
..TOC)
10/10/16
Latitude Longitude
35.41504-80.94525
Ground •C
764.93 767.38
Well
Ground
Surface
2.45
December
DTW - TOC
GW ELEV.
705.50
Total Well
Depth
Top of
Casing
76.35
0.010 Slot, Sch. 40
59.35 to 76.35
Interval
SAP
(inches)
2
Type
Sch. 40 PVC
61.88
MW-5A
01/14/92
35.41518
-80.94505
766.45
768.42
1.97
63.55
704.87
96.00
82.00
to
96.00
NR
2
Sch. 40 PVC
MW-6
02/21/92
35.41691
-80.94505
726.79
728.45
1.66
32.33
696.12
37.20
23.20
to
37.20
SAP
2
Sch. 40 PVC
MW-6A
02/20/92
35.41692
-80.94510
727.54
728.98
1.44
31.50
697.48
47.90
33.90
to
47.90
SAP
2
Sch. 40 PVC
MW-7R
10/11/16
35.41635
-80.94729
723.53
726.16
2.63
35.22
690.94
48.89
33.89
to
48.89
SAP
2
Sch. 40 PVC
MW-7A
1 02/12/92
35.416.26
-80.94732
722.74
724.66
1 1.92
32.97
691.69
59.40
1 45.40
to
59.40
SAP
2
Sch. 40 PV
MW-8
02/03/92
35.41687
-80.94626
757.30
759.60
2.30
62.29
697.31
71.50
57.50
to
71.50
SAP
2
Sch. 40 PVC
MW-8A
02/11/92
35.41684
-80.94622
757.61
759.68
2.07
62.39
697.29
84.40
70.40
to
84.40
SAP
2
Sch. 40 PVC
MW-9
02/19/92
35.41590
-80.94793
710.27
711.87
1.60
26.61
685.26
30.80
16.80
to 30.80
SAP
2
Sch. 40 PVC
MW-9A
02/18/92
35.41586
-80.94794
710.30
712.13
1.83
27.00
685.13
47.80
33.80
to 47.80
SAP
2
Sch. 40 PVC
MW-10A
01/16/01
1 35.441609
-80.94448
753.87
1 755.78
1.91
52.72
703.06 1
59.23
44.23
to 59.23
SAP
2
Sch. 40 PVC
Notes•
(1)
0.010 Slot
0.010-Inch Machine -Slotted Pipe
(2)
DTW
Depth to Water
(3)
Ground
Ground Surface
(4)
GW ELEV.
Groundwater Elevation
(5)
NR
Not Reported
(6)
PVC
Polyvinyl Chloride
(7)
PWR
Partially Weathered Rock
(8)
TOC
Top of Casing
(9)
SAP
Saprolite
(10)
Sch. 40
Schedule 40 Pipe
(11) Elevations based on NAVD88 vertical datum.
(12) Horizontal coordinates based on NAD27 datum.
(13) Survey and well construction data provided by Duke Energy.

Table 2: Groundwater Flow Velocities
s
Landfill No. 2 (Synthetically Lined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
S&ME Project No: 23350793, Ph. 775C
MW-5R
705.5
705
20
0.03
0.44
0.22
12
MW-6
700
695
470
0.01
0.44
0.22
5
MW-7R
695
690
210
0.02
0.44
0.22
11
MW-8
700
695
480
0.01
0.44
0.22
4
MW-9 1
690 1
685
1 170
1 0.03 1
0.44
1 0.22 1
10
Notes•
(1) Hydraulic gradient calculated by measuring linear distance through monitoring wells (generally perpendicular) from selected
groundwater contours.
(2) Monitoring wells are not listed where insufficient groundwater contour information is available to calculate velocity.
(3) Hydraulic gradients and groundwater velocities are approximate.
(4) Hydraulic Conductivity and effective porosity are mean values for soil/saprolite taken from "Groundwater Protection Initiative Site
Characterization Report" for McGuire Nuclear Station dated June 30, 2008 by S&ME, Inc.
(5) Seepage velocity equation used to calculate groundwater flow velocity v = (K*i)/ne

Table 3: Field Data Parameters
Landfill No. 2 (Synthetically Lined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
S&ME Project No: 23350793, Ph. 775C
Well •
MW-5R
•.
12/4/2023
Well
Depth
Below
76.35
Depthamp
Water
Below •
61.88
Groundwater
705.50
Normal
•. or
None
Purge
Method
LF
Average
Pump Rate
400
Well
Volume
2.36
EVAC
Volume
7.90
EVAC
(Yes/No)
NA
Temperature
CQ
17.10
Specific
Conductivity
17
PH
(SU)
5.32
Turbidity
(NTU)
19.9
ORP
(mV-NHE)
438
Dissolved
Oxyge
7.99
MW-5A
12/4/2023
96.00
63.55
704.87
Normal
None
LF
270
5.29
2.10
NA
17.69
49
6.61
4.0
364
7.36
MW-6
12/4/2023
37.20
32.33
696.12
Normal
None
EOP
210
0.79
0.34
NA
17.15
115
5.95
3.2
398
8.13
MW-6A
12/4/2023
47.90
31.50
697.48
Normal
None
LF
330
2.67
1.55
NA
16.88
54
5.58
4.0
410
7.87
MW-7R
12/5/2023
48.89
35.22
690.94
Normal
None
LF
240
2.23
1.40
NA
17.57
46
5.85
1.7
376
7.63
MW-7A
12/5/2023
59.40
32.97
691.69
Normal
None
LF
270
4.31
1.25
NA
17.32
101
6.53
7.7
335
7.40
MW-8
1 12/4/2023
71.50
62.29
697.31
Normal
None
EOP
360
1.50
0.54
NA
16.56
116
6.88
9.1
118
8.06
MW-8A
12/4/2023
84.40
62.39
697.29
Normal
None
LF
1 360
3.59
1.60
1 NA
16.41
1 100
6.71
2.5
1 351
7.69
MW-9
12/5/2023
30.80
26.61
685.26
Normal
None
EOP
240
0.68
0.30
NA
19.86
35
6.22
2.5
352
8.11
MW-9A
12/5/2023
47.80
27.00
685.13
Normal
None
LF
300
3.39
1.50
NA
17.77
105
6.21
1.9
359
4.11
MW-10A
12/4/2023
59.23
52.72
703.06
Normal
None
EOP
300
1.06
0.46
NA
19.82
17
5.52
5.7
410
7.69
SW-1
12/5/2023
NA
NA
NA
Normal
None
SWS
NA
NA
NA
NA
19.15
89
6.41
9.3
355
6.55
SW-2
12/5/2023
1 NA
NA
NA
Normal
None
SWS
NA
NA
NA
NA
16.67
99
6.48
16.8
337
6.19
Leachate
1 12/4/2023
1 NA
NA
NA
Normal
None
SWS
NA
NA
NA
NA
16.32
745
1 7.43
5.2
344
1 7.27
Notes:
(1)
°C
degrees Celsius
(2)
ft
feet
(3)
gal
gallons
(4)
µU/cm
micromhos per centimeter
(5)
mg/L
milligrams per liter
(6)
mL/min
milliliters per minute
(7)
mV-NHE
millivolts - normal hydrogen electrode
(8)
NA
not applicable
(9)
NTU
nephelometric turbidity unit
(10)
SU
standard units
(11)
TOC
top of casing
(12)
Elevations based on NAVD88 vertical datum.
(13) Purge methods: LF = Low Flow; CP = Conventional Purge (3-5 well volumes); EOP = Equipment Only Purge; SWS = Surface Water Sample; average pump rate applicable
to LF purging only.
(14) EVAC indicates whether the water level in the well was drawn down to the level of the pump during purging and also the total amount purged from the well.
(15) Field sampling performed by Duke Energy Groundwater Science Group.

Table 4: Groundwater Field and Analytical Results
Landfill No. 2 (Synthetically Lined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
S&ME Project No: 23350793, Ph. 775C
Parameter
Field Parameter
Field pH
Units
llswp�
SU
5.32
6.61
5.95
dAEVEEWE�w
5.58
5.85
6.53
6.88
6.71
6.22
6.21
5.52
MDL
SWS
Groundwater
Protection
Standard
(GWPS)
NE
1 SA NCAC
2L
6.5 - 8.5
Federal
MCL
6.5 - 8.5*
Specific Conductance
,U/cm
17
49
115
54
46
101
116
100
35
105
17
NE
NE
NE
Temperature
•
°C
17.10 17.69 17.15 16.88 17.57 17.32 16.56 16.41 19.86
i r
Volatile Organic Compounds were not detected during the December 2023 Sampling Event
17.77
19.82
NE
NE
NE
TPH-DRO
pg/L
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130
NE
NE
NE
r:
Alkalinity(CaCo3)
pg/L
4690J
21600
57700
13000
18600
56000
63000
49900
39200
53500
8050
1700
NE
NE
NE
.r
Chloride
pg/L
1100
1300
1300
5700
2500
1100
1300
2000
2300
1700
1300
15.4
NE
250000
250000*
Sulfate
pg/L
650
2300
2300
50J
50J
240
940
1200
140
180
430
42.8
NE
250000
250000*
Mercury
Yotal Recoverable Metals Method SW 0:
Arsenic
pg/L
pg/L
0.12 J
0.306 J
Mercury was not detected during the December 2023 Sampling Event
0.111 U 0.111 U 0.111 U I 0.138 J 0.111 U 0.111 U 0.111 U
0.111 U
0.111 U
0.01
0.111
NE
NE
1
10
2
10
Chromium
pg/L
1.20
0.586 J
1.96
0.696 J
0.5161
0.539 J
0.6751
0.533 J
1.29
1.96
0.7271
0.185
NE
10
100
Lead
pg/L
0.546 J
0.059 J
0.037 U
0.0371
0.058 J
0.037 U
0.037 U
0.037 U
0.037 U
0.037 U
0.224 J
0.037
NE
15
15
Silver
pg/L
0.035 U
0.217 J
0.035 U
0.035 U
0.035 U
0.045 J
0.035 U
0.035 U
0.035 U
0.035 U
0.035 U
0.035
NE
20
1 100"
Barium
pg/L
21
22
47
52
26
5J
14
32
20
11
24
2
NE
700
2000
Calcium
pg/L
873
3030
18800
5190
4030
14500
16100
12200
8730
11800
1630
12
NE
NE
NE
Magnesium
pg/L
810
1310
5930
1580
3100
3690
3160
3780
3830
4940
1440
8
NE
NE
NE
Potassium
pg/L
753
1010
1040
275
259
450
926
1430
434
554
801
31
NE
NE
NE
Sodium
pg/L
868
6400
6750
4010
1240
3640
6370
4950
3470
5100
1810
17
NE
NE
NE
Notes:
(1) Samples were collected by Duke Energy Groundwater Sciences Group.
(2) MDL refers to the laboratory Method Detection Limit.
(3) SWS Groundwater Protection Standard (GWPS) refers to the North Carolina Groundwater Protected Standards calculated by North Carolina Department of Environmental Quality (NCDEQ), Solid Waste Section (SWS) for constituents with no
established 15A NCAC 2L Standard (last amended on October 15, 2018).
(4) 15A NCAC 2L Standard refers to Class GA Standards as found in 15A NCAC 02L .0202 Groundwater Quality Standards (last amended on April 1, 2022).
(5) Federal Maximum Contaminant Level (MCL) as found in National Primary Drinking Water Regulations, 40 CFR, Subpart G, §141.62.
(6) * Concentration listed is a secondary MCL (MCL) as found in National Secondary Drinking Water Regulations, 40 CFR, Subpart A, §143.3.
(7) NE = Not Established.
(8) Yellow highlighted cells indicate concentrations equal to or greater than the 15A NCAC 2L Standard (for pH yellow highlighting indicates a measurement outside the 15A NCAC 2L range).
(9) Bolded values indicate concentrations equal to or greater than the Federal MCL (for PH bolded values indicate a measurement outside of the Federal MCL range)
(10)1 = estimated concentrations which are greater than the MDL but are less than the laboratory Method Reporting Limit (MRL).
(11) U = constituent detected at or below the laboratory MDL.
(12) SU = Standard Units.

1 ame S: Kesuns that tqual or txceea 7 SA NILA(. LL urou
Landfill No. 2 (Synthetically Lined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
S&ME Project No: 23350793, Ph. 775C
Parameter
ion
15A NCAC 2L
nits
Standard
Historical
Concentration
Range--A1116
Cause and Si
=jW
Field pH
MW-SR
5.32
5.17 - 5.63
pH in MW-5R is consistent with the historical concentration range at monitoring well.
MW-6
5.95
5.60 - 6.30
5.10 - 6.00
pH in MW-6 is consistent with the historical concentration range at monitoring well.
pH in MW-6A is consistent with the historical concentration range at monitoring well.
MW-6A
5.58
MW-7R
5.85
SU 6.5 - 8.5 5.53 - 5.95
4.71 - 6.41
pH in MW-7R is consistent with the historical concentration range at monitoring well.
pH in MW-9 is consistent with the historical concentration range at monitoring well.
MW-9
6.22
MW-9A
6.21
5.84 - 6.70
4.92 - 7.01
pH in MW-9A is consistent with the historical concentration range at monitoring well.
pH in MW-10A is consistent with the historical concentration range at monitoring well.
MW-10A
5.52
Notes•
(1) 15A NCAC 2L Standard refers to Class GA Standards as found in 15A NCAC 02L .0202 Groundwater Quality Standards (last amended on April 1, 2022).
(2) Historical Concentration Range based on data in Duke Energy Carolinas, LLC (Duke Energy) analytical results database.
(3) SU = Standard units.
(4) lag/L = micrograms per liter.

Table 6: Surface Water Field and Analytical Results
Landfill No. 2 (Synthetically Lined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station I 1
S&ME Project No: 23350793, Ph. 775C
Field Parameters Parameter ..Ah.Dece
lii,a_W_M�Mmm
Field pH SU
6.41
6.48
6.0 - 9.0
6.5 - 8.5*
Specific Conductance µZ5/cm
89
99
NE
NE
Temperature °C
19.15
16.67
NE
NE
•
Volatile Organic Compounds were not detected during the December 2023 Sampling Event
TPH-DRO µg/L 130 U 130 U 130 NE NE
Alkalinity (CaCo3) µg/L 50700 53300 1700
NE NE
Chloride
µg/L
2900 2500
15.4
230000 250000*
Sulfate
µg/L
1200 2100
42.8
250000 250000*
i
Mercury
kEtal Recoverable Metals Method SW .00:
Arsenic
pg/L
µg/L
0.01 J 0.01 J
0.142 J 0.224 J
0.01
0.111
0.012 2
10 10
Arsenic, dissolved
µg/L
0.118 J
0.153 J
0.111
150
10
Chromium
µg/L
0.185 U
0.322 J
0.185
183A
100
Chromium, dissolved
µg/L
0.275 J
0.210 J
0.185
24A
NE
Lead
µg/L
0.052 J
0.214 J
0.037
14A
15
Lead, dissolved
µg/L
0.037 U
0.037 U
0.037
0.54A
15
Barium
µg/L
23
34
2
1000
2000
Calcium
µg/L
11000
12000
12
NE
NE
Magnesium
µg/L
4370
4640
8
NE
NE
Potassium
µg/L
1470
1700
31
NE
NE
Sodium
µg/L
5750
5680
17
NE
NE
Notes:
(1) Samples were collected by Duke Energy Groundwater Sciences Group.
(2) MDL refers to the laboratory Method Detection Limit.
(3) 15A NCAC 2B Standard (last amended on September 1, 2022) refers to 15A NCAC 02B 0.0211 Fresh Surface Water
Quality Standards for Class C Waters, and 15A NCAC 02B 0.0216 - Fresh Surface Water Quality Standards for Class WS-IV
(4) Federal Maximum Contaminant Level (MCL) as found in National Primary Drinking Water Regulations, 40 CFR, Subpart
G, §141.62.
(5) * Concentration listed is a secondary MCL (MCL) as found in National Secondary Drinking Water Regulations, 40 CFR,
Subpart A, §143.3.
(6) A = Hardness -dependent 15A NCAC 2B Standards derived using equations specified in the 15 NCAC 02B Standards
Table (last amended on July 26, 2021). The values shown rely upon an assumed in -stream default hardness of 25
milligrams per liter (mg/L) for the chronic standard. An exceedance of the criterion shown does not establish that an in -
steam exceedance has occurred.
(7) NE = Not Established.
(8) J = estimated concentrations which are greater than the MDL but are less than the laboratory Method Reporting Limit
(MRL).
(9) U = constituent detected at or below the laboratory MDL.
(10) SU = Standard Units.
(11) µU/cm = micromhos per centimeter.
(12) °C = degrees Celsius.
(13) pg/L = micrograms per liter.

Table 7: Leachate Field and Analytical Results
Landfill No. 2 (Synthetically Lined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
S&ME Project No: 23350793, Ph. 775C
Parameter Units W11111F 'December 4,2023
Field pH SU 7.43
Specific Conductance µO/cm 745
Temperature °C 16.32
FWAAMppeWndix I Volatile Organic Compounds Method 8260B and 8260B SIM
Volatile Organic Compounds were not detected during the December 2023 Sampling Event
TPH-DRO
µg/L
4900
Alkalinity (CaCo3)
mg/L 313
. .. .i u- .. •�
Chloride
mg/L 52
Sulfate
mg/L 29
Mercury was not detected during the December 2023 Sampling Event
Arsenic
µg/L
0.249 J
Selenium
Total Recoverable Metals Meth ..
Barium
µg/L
mg/L
0.269 J
0.105
Calcium
mg/L
99.5
Magnesium
mg/L
17.6
Potassium
mg/L
12.8
Sodium
mg/L
1 53.5
Notes.•
(1) Samples were collected by Duke Energy Groundwater Sciences Group.
(2) J = estimated concentrations which are greater than the laboratory Method Detection Limit (MDL) but are less than
the laboratory Method Reporting Limit (MRL).
(3) C7 = analyte is a possible laboratory contaminant (not present in method blank).
(4) mg/L = milligrams per liter.
(5) pg/L = micrograms per liter.
(6) SU = Standard Units.

Table 8: Radiological Analytical Results
Landfill No. 2 (Synthetically Lined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
S&ME Project No: 23350793, Ph. 775C
Radiological D.
Picocuries per
Liter (pCi/L)
Alpha
M
-A�wk
< 0.440
< 0.439
< 0.438
W-6A
< 0.439
MW-7R
< 0.439
Mw-7AJLMW-8
< 0.439
< 0.439
MW-8A
< 0.439
M WA -A
< 0.439
MW-9A
< 0.467
MW-10A
< 0.543
sw-1
< 0.467
SW-2
< 0.467
Leachate
Pond
0.642
Ba-La-140
< 11.9
< 9.10
< 10.2
< 9.21
< 5.16
< 8.80
< 11.5
< 6.76
< 10.9
< 10.5
< 9.51
< 8.77
< 5.21
< 8.59
Be7
< 48.5
< 39.9
< 36.4
< 47.2
< 48.8
< 48.1
< 47.5
< 56.4
< 52.6
< 47.6
< 41.9
< 50.4
< 47.9
< 53.5
Beta
< 3.18
< 3.18
< 3.18
< 3.18
< 3.18
< 3.18
< 3.18
< 3.18
< 3.18
< 3.41
< 3.29
< 3.29
< 3.36
10.9
Co58
< 6.98
< 6.50
< 5.60
< 3.92
< 5.87
< 5.88
< 6.19
< 5.63
< 6.60
< 7.51
< 7.18
< 6.49
< 6.09
< 6.68
Co60
< 4.99
< 5.29
< 5.53
< 5.79
< 6.83
< 6.87
< 6.24
< 8.45
< 8.86
< 6.06
< 5.53
< 1.11
< 5.17
< 5.81
Cs134
< 7.36
< 5.81
< 7.49
< 6.30
< 7.25
< 6.40
< 7.76
< 7.51
< 8.20
< 7.36
< 6.95
< 6.08
< 6.84
< 5.48
Cs137
< 5.34
< 5.74
< 7.09
< 5.98
< 5.55
< 5.37
< 6.17
< 4.84
< 5.71
< 5.91
< 7.33
< 5.81
< 5.93
< 4.53
Fe59
< 10.6
< 11.5
< 11.9
< 11.6
< 10.8
< 11.0
< 9.93
< 11.9
< 11.0
< 11.8
< 11.6
< 12.8
< 11.4
< 11.2
Tritium (H3GW)
< 28.4
< -17.0
< 82.8
< 68.6
< 26.1
< 123
< 18.9
< 26.1
< 58.9
< 66.3
< 61.8
< 28.6
< 28.5
573
1131
< 10.5
< 7.87
< 8.84
< 10.9
< 8.37
< 9.06
< 9.36
< 11.5
< 11.3
< 9.16
< 10.1
< 9.33
< 8.48
< 10.4
K40
168
< 112
128
137
170
< 157
153
179
188
120
192
122
84.9
124
Mn54
< 6.43
< 5.77
< 6.37
< 5.64
< 5.06
< 5.53
< 4.76
< 6.72
< 7.05
< 5.58
< 6.22
< 5.81
< 5.72
< 5.34
Nb95
< 6.78
< 6.46
< 6.89
< 4.58
< 5.25
< 5.74
< 6.96
< 7.12
< 7.17
< 7.60
< 8.13
< 4.50
< 7.27
< 6.28
Zn65
< 12.9
< 12.5
< 12.5
< 10.9
< 10.7
< 11.6
< 13.8
< 13.0
< 16.5
< 14.0
< 13.1
< 13.7
< 14.4
< 12.2
Zr95
< 11.9
< 11.6
< 12.4
< 8.29
< 9.87
< 8.35
< 11.2
< 9.84
< 12.4
< 10.6
< 13.5
< 10.4
1< 11.3
< 9.67
Notes:
(1) pCi/L = picocuries per liter
(2) < = less than

Appendix III - Field Sampling Forms

FIELD SAMPLING CALIBRATION FORM
STUDY:
MCGUIRE
NUCLEAR STATION - NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
DATE (s):
December 4-5, 2023
SURFACE UNIT READER: EHS
COLLECTORS: EHS
SURFACE UNIT SERIAL #: 950
ANALYZER MODEL#: ST MP
ANALYZER SERIAL #: 877813
OTHER EQUIPMENT: TURBIDIMETER NO.3 - WR-00070
WEATHER CONDITIONS:
40s-60s, sunny
HYDROLAB PROCEDURE #:
3210.7 VALIDATED BY:
EHS 12/6/23
Calibration Date / Time
DATE:
4-Dec-23
TIME: 7:15
DATE: 5-Dec-23
TIME: 7:15
CALIBRATION BP (mmHg)
740.62
CALIBRATION BP (mmHg)
739.76
Calibation
Instrument
Standard
Instrument
Standard
Parameter
Calibration Results
Calibration Results
Standard
Value
Value
Value
Value
SS
0.0
-► 0.0
INSTRUMENT ZEROED
0.0 -/-►
0.0
INSTRUMENT ZEROED
SPEC. COND.
SS
710.2
-► 720
CALIBRATION ACCEPTED
722.2 -►
227
CALIBRATION ACCEPTED
(US/GM)
SS
225.2
-/-► 227
CALIBRATION ACCEPTED
229.1 -/-►
75
CALIBRATION FAILED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
SS
-/-► 1410
-/-►
1410
CHECK (uS/cm)
SS
B (7.00)
7.03
-► 7.02
CALIBRATION ACCEPTED
7.05 -►
7.02
CALIBRATION ACCEPTED
pH
B (4.00)
4.05
-► 4.00
CALIBRATION ACCEPTED
4.00 -►
4.00
CALIBRATION ACCEPTED
(units)
B (10.00)
10.11
-/-► 10.07
CALIBRATION ACCEPTED
10.11 -/-►
10.07
CALIBRATION ACCEPTED
Buffer Temp. 18.67
Buffer Temp.
19.01
pH Check
B (7.00)
-► 7.13
Buffer Temp. 0.00
Time:
0
442
-► 443
CALIBRATION ACCEPTED
442 -►
443
CALIBRATION ACCEPTED
ORP
N/A
_/-► N/A
N/A -/-►
N/A
Zobell's
ORP Temp. 18.99
ORP Temp.
18.99
0
TEMP (C°)
19.77
19.64
BP (mmHg)
740.62
739.76
COND
0.00
0.00
DO
100 % mg/L
8.81
-► 8.90
CALIBRATION ACCEPTED
9.00 -►
8.91
CALIBRATION ACCEPTED
(mg/L)
After Cal
8.87
99.71
After Cal % SAT
8.95
100.47
After Cal % SAT
LCS
8.87
99.71
CALIBRATION PASS
8.95
100.47
CALIBRATION PASS
LCSD
8.87
0.00
CALIBRATION PASS
8.95
0.00
CALIBRATION PASS
❑ TURB
(ntu)
SS
10.1
-/-► 10.0
CALIBRATION ACCEPTED
10.0 -/-►
10.0
CALIBRATION ACCEPTED
Temp Cert Device #
TEMP
NISI
N/A
-/-► N/A
Adjustment Not Available
N/A -/-►
N/A
Adjustment Not Available
(deg C)
INSTRUMENT MAINTENANCE
DATE / TIME
Conductance Subsystem
pH Subsystem
❑
Cleaned Electrodes
❑ Cleaned Electrodes
❑
Tested - OK
❑ Replaced ref Electrode KCL
❑
See Notes
❑ Replaced Ref. Electrode Tip
❑ Tested - OK
❑ See Notes
Oxidation Reduction Subsystem
Temperature Subsystem
❑
Cleaned Electrode
❑ Cleaned Electrode
❑
Tested - OK
❑ See Notes
❑ Tested - OK ❑
See Notes
Dissolved Oxygen Subsystem
❑
Replaced Teflon Membrane
❑ Cleaned Electrode
Replaced DO electrolyte
❑ See Notes
Field Barometric Pressure
Beginning BP
(mmHg)
Ending BP
(mmHg)
KEY:
B = butter
= Lab Contra z5tanoara -0- =Adjusted To
SS = Standard solution
LCSD = Lab Control Standard Duplicate -/-►= Not Adjusted To
N/A = Not Applicable
W = Winkler
BP = Barometric Pressure
AW = Average Winkler
NOTES:

FIELD SAMPLING CALIBRATION FORM
STUDY:
MCGUIRE
NUCLEAR STATION - NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
DATE (s):
December 4-5, 2023
SURFACE UNIT READER: EHS
COLLECTORS: EHS
SURFACE UNIT SERIAL #: 950
ANALYZER MODEL#: ST MP
ANALYZER SERIAL #: 877813
OTHER EQUIPMENT: TURBIDIMETER NO.3 - WR-00070
WEATHER CONDITIONS:
40s-60s, sunny
HYDROLAB PROCEDURE #:
3210.7 VALIDATED BY:
EHS 12/6/23
Calibration Date / Time
DATE:
5-Dec-23
TIME: 7:15
DATE: 5-Dec-23
TIME: 5:15
CALIBRATION BP (mmHg)
739.76
CALIBRATION BP (mmHg)
741.22
Calibation
Instrument
Standard
Instrument
Standard
Parameter
Calibration Results
Calibration Results
Standard
Value
Value
Value
Value
SS
0.0
-/-► 0.0
INSTRUMENT ZEROED
0.0 -/-►
0.0
INSTRUMENT ZEROED
SPEC. COND.
SS
722.2
-► 720
CALIBRATION ACCEPTED
726.0 -/-►
720
CALIBRATION ACCEPTED
(US/GM)
SS
229.1
-/-► 227
CALIBRATION ACCEPTED
231.9 -/-►
227
CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
SS
-/-► 1410
-/-►
1410
CHECK (uS/cm)
SS
B (7.00)
7.05
-► 7.02
CALIBRATION ACCEPTED
7.03 -/-►
7.02
CALIBRATION ACCEPTED
pH
B (4.00)
4.00
-► 4.00
CALIBRATION ACCEPTED
4.02 -/-►
4.00
CALIBRATION ACCEPTED
(units)
B (10.00)
10.11
-/-► 10.07
CALIBRATION ACCEPTED
10.04 -/-►
10.07
CALIBRATION ACCEPTED
Buffer Temp. 19.01
Buffer Temp.
19.21
pH Check
B (7.00)
-► 7.13
Buffer Temp. 0.00
Time:
0
442
-► 443
CALIBRATION ACCEPTED
440 -/-►
443
CALIBRATION ACCEPTED
ORP
N/A
_/-► N/A
N/A -/-►
N/A
Zobell's
ORP Temp. 18.99
ORP Temp.
19.25
0
TEMP (C°)
19.64
19.51
BP (mmHg)
739.76
741.22
COND
0.00
0.00
DO
100 % mg/L
9.00
-► 8.91
CALIBRATION ACCEPTED
9.00 -/-►
8.95
CALIBRATION ACCEPTED
(mg/L)
After Cal
8.95
100.47
After Cal % SAT
9.02
100.78
After Cal % SAT
LCS
8.95
100.47
CALIBRATION PASS
9.02
100.78
CALIBRATION PASS
LCSD
8.95
0.00
CALIBRATION PASS
9.02
0.00
CALIBRATION PASS
❑ TURB
(ntu)
SS
10.0
-/-► 10.0
CALIBRATION ACCEPTED
10.0 -/-►
10.0
CALIBRATION ACCEPTED
Temp Cert Device #
TEMP
NISI
N/A
-/-► N/A
Adjustment Not Available
N/A -/-►
N/A
Adjustment Not Available
(deg C)
INSTRUMENT MAINTENANCE
DATE / TIME
Conductance Subsystem
pH Subsystem
❑
Cleaned Electrodes
❑ Cleaned Electrodes
❑
Tested - OK
❑ Replaced ref Electrode KCL
❑
See Notes
❑ Replaced Ref. Electrode Tip
❑ Tested - OK
❑ See Notes
Oxidation Reduction Subsystem
Temperature Subsystem
❑
Cleaned Electrode
❑ Cleaned Electrode
❑
Tested - OK
❑ See Notes
❑ Tested - OK ❑
See Notes
Dissolved Oxygen Subsystem
❑
Replaced Teflon Membrane
❑ Cleaned Electrode
Replaced DO electrolyte
❑ See Notes
Field Barometric Pressure
Beginning BP
(mmHg)
Ending BP
(mmHg)
KEY:
B = butter
= Lab Contra z5tanoara -0- =Adjusted To
SS = Standard solution
LCSD = Lab Control Standard Duplicate -/-►= Not Adjusted To
N/A = Not Applicable
W = Winkler
BP = Barometric Pressure
AW = Average Winkler
NOTES:

DUKE DUKE ENERGY DUKE
ENERGY GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID I N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
ICI f I f I I_I
SAMPLING DATE(s) 4-Dec-2023 5-Dec-2023
WELL/LOCATION NAME
MW-5R
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
767.38
MIDDLE OF WETTED SCREEN (ft toc) 69.12
WELL DEPTH (ft TOC)
76.35
GS ELEV (ft msl)
764.93
PUMP INTAKE DEPTH (ft TOC) 75.35
SCREEN LENGTH (ft)
17
ELEV REF
NAVD 88
SCREEN INTERVAL (ft TOC) 59.35 TO 76.35
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED 1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE 1 45 (psi) RECHARGE 1 10 (sec) DISCHARGE 10 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
61.88
WATER COLUMN (ft)
14.47
WATER ELEVATION (ft msl)
705.50
WELL VOLUME (gal)
2.36
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg Q
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
12:19
6781
270
17.63
16
5.29
11.2
417
7.82
N/A
12:22
62.81
270
17.60
16
5.28
15.5
422
7.78
N/A
12:25
62.81
270
17.64
16
5.26
20.4
425
7.74
N/A
12:48
62.81
270
17.48
16
5.20
85.0
442
7.80
N/A
1:14
70.10
400
17.06
17
5.44
59.9
430
7.92
N/A
1:27
70.10
400
17.16
17
5.38
27.8
432
7.94
N/A
1:42
70.10
400
17.00
17
5.34
29.9
435
7.93
N/A
1:51
70.10
400
17.10
17
5.33
19.8
437
7.98
N/A
1:54
70.10
400
17.10
17
5.33
13.0
437
7.99
N/A
1:57
70.10
400
17.10
17
5.32
19.9
438
7.99
N/A
DRAW -DOWN
8.22
(ft)
INITIAL PURGE VOLUME
1.25
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/I)
TOTAL PURGE VOLUME
7.90
(gal)
12/4/2023 @ 1400
0
Sample preservation verified to pH
FBy:= �1 EHS 12/6/23 (units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA 01-13 ❑BORON ❑SR 89/90 OGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 []IODINE 131 0SO4,CL ❑ALPHA SPEC
OMETALS OF_ALK ❑CO2 ❑RSK 175 ❑VOC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, 504, F_ALK ❑TDS
❑METALS 7NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition I lWell Imoacted By Silting: I NO
WELL CAPS
WELL CASING
ACCESS TO WELLS
PROTECTIVE CASING
FLUSH MOUNT WELLS
WELL TAG
ACCESS AROUND WELL
WELL SECURITY
WELL LOCK CONDITION
Well cap in good conditon
Good Condition
Access cleared into well
Casing in good condition
Well tag in good condition
Access cleared around well
Well found locked
Lock in Rood condition
SAMPLING NOTES

f� DUKE DUKE ENERGY 4 DUKE
ENER Y GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) l 4-Dec-2023 I 5-Dec-2023
WELL/LOCATION NAME
MW-5A
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
768.42
MIDDLE OF WETTED SCREEN (ft toc) 89.00
WELL DEPTH (ft TOC)
96.00
GS ELEV (ft msl)
766.45
PUMP INTAKE DEPTH (ft TOC) 95.00
SCREEN LENGTH (ft)
14
ELEV REF
NGVD 27
SCREEN INTERVAL (ft TOC) 82.00 TO 96.00
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good]I-
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) DISCHARGE (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING W ec_
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
63.55
WATER COLUMN (ft)
32.45
WATER ELEVATION (ft msl)
704.87
WELL VOLUME (gal)
5.29
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(degQ
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
11:42
6770
270
17.42
49
7.02
7.5
352
7.40
N/A
11:45
66.70
270
17.67
49
6.85
6.1
356
1 7.35
N/A
11:48
66.70
270
17.60
49
6.75
6.1
359
7.35
N/A
11:51
66.70
270
17.56
49
6.68
4.9
361
7.31
N/A
11:54
66.70
270
17.76
49
6.63
4.6
363
7.36
N/A
11:57
66.70
270
17.69
49
6.61
4.0
364
7.36
N/A
DRAW -DOWN
3.15
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
1.00
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
2.10
(gal)
12/4/2023 @0 1200
0
11 Sample preservation verified to pH
QC By: EHS 12/6/23 11
(units) =
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA OH3 ❑BORON ❑SR 89/90 OGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 0504,CL []ALPHA SPEC
OMETALS OF_ALK ❑CO2 ❑RSK 175 ❑VOC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS 7NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES I
WELL PAD
WELL CAPS
WELL CASING
ACCESS TO WELLS
PROTECTIVE CASING
FLUSH MOUNT WELLS
WELL TAG
ACCESS AROUND WELL
WELL SECURITY
WELL LOCK CONDITION
Well cap in good conditon
Good Condition
Access cleared into well
Casing in good condition
Well tag in good condition
Access cleared around well
Well found locked
Lock in Rood condition
Silting: I NO
SAMPLING NOTES

DUKE DUKE ENERGY
ENERGY GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR EQUIPMENT PURGE ONLY SAMPLING
DUDE
.' ENERGY
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
b b �
SAMPLING DATE(s) 4-Dec-2023 5-Dec-2023
WELL/LOCATION NAME
MW-6
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
728.45
MIDDLE OF WETTED SCREEN (ft toc)
34.77
WELL DEPTH (ft TOC)
37.20
GS ELEV (ft msl)
726.79
PUMP INTAKE DEPTH (ft TOC)
36.20
SCREEN LENGTH (ft)
14
ELEV REF
NGVD 27
SCREEN INTERVAL (ft TOC) 23.20 TO 37.20
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT
QED T1200
TUBING DIAMETER (in)
i/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE 1 20 (psi) RECHARGE 1 10 1 (sec) I DISCHARGE 10 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL EA
NUCLEAR LANDFILL
Equip. Only Purge
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
32.33
WATER COLUMN (ft)
4.87
WATER ELEVATION (ft msl)
696.12
11WELL
VOLUME (gal)
0.79
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
INITIAL
WATER LEVEL
(ft)
FLOW
RATE
(ml/min)
FINAL
WATER LEVEL
(ft)
TEMP
(deg C)
SPECIFIC
COND.
(umho/cm)
pH
(SU)
TURBIDITY
(NTU)
ORP
(mV -NEH)
DISSOLVED
OXYGEN
(mg/L)
32.33
210
33.39
17.15
115
5.95
3.2
398
8.13
N/A
If Evacuated And It Is Requiered To Return To Sample, Enter The Date, Time, And
Water Level To The Right Before Sampling to Determine Recharge.
DATE:
TIME:
WATER LEVEL:
Well Vol.:
Evacuated:
N/A
N/A
Sample:
Tubing Volume
786
(ml) INITIAL PURGE VOL. EQUIPMENT PURGE ONLY SAMPLE
CHLORINE (mg/I)
Pump (Bladder) Volume
495
(ml) 0.40 SAMPLE COLLECTED BY
(ml) — 0.34 (gal) EHS
I DATE TIME
Total Purge Volume
1281
1 12/4/2023 @ 1550
0
:QC7By]-. EHS 12/6/23
Sample preservation verified to pH
(units) E771
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA OH3 ❑BORON ❑SR 89/90 FIGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 OSO4,CL ❑ALPHA SPEC
OMETALS OF_ALK ❑CO2 ❑RSK 175 OVOC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION
PAD
Good Condition
CAPS
Well cap in good conditon
CASING
Good Condition
iS TO WELLS
Access cleared into well
ECTIVE CASING
Casing in good condition
I MOUNT WELLS
TAG
Well tag in good condition
iS AROUND WELL
Access cleared around well
SECURITY
Well found locked
LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION NOTES
II Impacted By Silting: I NO

f� DUKE DUKE ENERGY 4 DUKE
ENER Y GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) l 4-Dec-2023 I 5-Dec-2023
WELL/LOCATION NAME
MW-6A
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
728.98
MIDDLE OF WETTED SCREEN (ft toc) 40.90
WELL DEPTH (ft TOC)
47.90
GS ELEV (ft msl)
727.54
PUMP INTAKE DEPTH (ft TOC) 46.90
SCREEN LENGTH (ft)
14
ELEV REF
NGVD 27
SCREEN INTERVAL (ft TOC) 33.90 TO 47.90
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good]I-
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) DISCHARGE (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING W ec_
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
31.50
WATER COLUMN (ft)
16.40
WATER ELEVATION (ft msl)
697.48
WELL VOLUME (gal)
2.67
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
3:20
32.40
330
16.99
54
5.58
9.4
410
7.95
N/A
3:23
32.40
330
16.93
55
5.59
8.7
412
7.95
N/A
3:26
32.40
330
16.88
54
5.58
4.0
410
7.87
N/A
DRAW -DOWN
0.90
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
1.00
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
1.55
(gal)
12/4/2023 @0 1530
1 0
11 Sample preservation verified to pH
QC By: EHS 12/6/23 11
(units) =
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA OH3 ❑BORON ❑SR 89/90 OGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 0504,CL []ALPHA SPEC
OMETALS OF_ALK ❑CO2 ❑RSK 175 ❑VOC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS 7NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES I
WELL PAD
WELL CAPS
WELL CASING
ACCESS TO WELLS
PROTECTIVE CASING
FLUSH MOUNT WELLS
WELL TAG
ACCESS AROUND WELL
WELL SECURITY
WELL LOCK CONDITION
Well cap in good conditon
Good Condition
Access cleared into well
Casing in good condition
Well tag in good condition
Access cleared around well
Well found locked
Lock in Rood condition
Silting: I NO
SAMPLING NOTES

f� DUKE DUKE ENERGY 4 DUKE
ENER Y GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) l 4-Dec-2023 I 5-Dec-2023
WELL/LOCATION NAME
MW-7R
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
726.16
MIDDLE OF WETTED SCREEN (ft toc) 42.06
WELL DEPTH (ft TOC)
48.89
GS ELEV (ft msl)
723.53
PUMP INTAKE DEPTH (ft TOC) 47.89
SCREEN LENGTH (ft)
is
ELEV REF
NAVD 88
SCREEN INTERVAL (ft TOC) 33.89 TO 48.89
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED 1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) DISCHARGE (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING W ec_
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
35.22
WATER COLUMN (ft)
13.67
WATER ELEVATION (ft msl)
690.94
WELL VOLUME (gal)
2.23
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(degQ
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
1:35
35.84
240
17.76
46
5.86
3.0
370
7.67
N/A
1:38
35.84
240
17.85
46
5.85
2.2
372
7.69
N/A
1:41
35.84
240
17.57
46
5.84
1.7
376
7.63
N/A
DRAW -DOWN
0.62
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
1.00
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
1.40
(gal)
12/5/2023 @0 1345
1 0
11 Sample preservation verified to pH
QC By: EHS 12/6/23 11
(units) =
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA OH3 ❑BORON ❑SR 89/90 OGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 0504,CL []ALPHA SPEC
OMETALS OF_ALK ❑CO2 ❑RSK 175 ❑VOC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS 7NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES I
WELL PAD
WELL CAPS
WELL CASING
ACCESS TO WELLS
PROTECTIVE CASING
FLUSH MOUNT WELLS
WELL TAG
ACCESS AROUND WELL
WELL SECURITY
WELL LOCK CONDITION
Well cap in good conditon
Good Condition
Access cleared into well
Casing in good condition
Well tag in good condition
Access cleared around well
Well found locked
Lock in Rood condition
Silting: I NO
SAMPLING NOTES

f� DUKE DUKE ENERGY 4 DUKE
ENER Y GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) l 4-Dec-2023 I 5-Dec-2023
WELL/LOCATION NAME
MW-7A
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
724.66
MIDDLE OF WETTED SCREEN (ft toc)
52.40
WELL DEPTH (ft TOC)
59.40
GS ELEV (ft msl)
722.74
PUMP INTAKE DEPTH (ft TOC)
58.40
SCREEN LENGTH (ft)
14
ELEV REF
I NGVD 27
SCREEN INTERVAL (ft TOC) 45.40 TO 59.40
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) I DISCHARGE (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING W ec_
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
32.97
WATER COLUMN (ft)
26.43
WATER ELEVATION (ft msl)
691.69
WELL VOLUME (gal)
4.31
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(degQ
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
12:55
3753
270
17.28
102
6.54
10.4
333
7.42
N/A
12:58
34.53
270
17.33
101
6.54
7.8
334
7.43
N/A
1:01
34.53
270
17.32
101
6.53
7.7
335
7.40
N/A
DRAW -DOWN
1.56
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
1.00
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
1.25
(gal)
L12/5/2023 @ 1305
0
11 Sample preservation verified to pH
QC By: EHS 12/6/23 11
(units) =
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA OH3 ❑BORON ❑SR 89/90 OGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 0504,CL []ALPHA SPEC
OMETALS OF_ALK ❑CO2 ❑RSK 175 OVOC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS 7NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES I
WELL PAD
WELL CAPS
WELL CASING
ACCESS TO WELLS
PROTECTIVE CASING
FLUSH MOUNT WELLS
WELL TAG
ACCESS AROUND WELL
WELL SECURITY
WELL LOCK CONDITION
Well cap in good conditon
Good Condition
Access cleared into well
Casing in good condition
Well tag in good condition
Access cleared around well
Well found locked
Lock in Rood condition
Silting: I NO
SAMPLING NOTES

DUKE DUKE ENERGY
ENERGY GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR EQUIPMENT PURGE ONLY SAMPLING
DUDE
.' ENERGY
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
b b �
SAMPLING DATE(s) 4-Dec-2023 5-Dec-2023
WELL/LOCATION NAME
MW-8
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
759.60
MIDDLE OF WETTED SCREEN (ft toc)
66.90
WELL DEPTH (ft TOC)
71.50
GS ELEV (ft msl)
757.30
PUMP INTAKE DEPTH (ft TOC)
70.50
SCREEN LENGTH (ft)
14
ELEV REF
NGVD 27
SCREEN INTERVAL (ft TOC) 57.50 TO 71.50
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT
QED T1200
TUBING DIAMETER (in)
i/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE 1 35 (psi) RECHARGE 1 10 1 (sec) DISCHARGE 10 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL EA
NUCLEAR LANDFILL
Equip. Only Purge
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
62.29
WATER COLUMN (ft)
9.21
WATER ELEVATION (ft msl)
697.31
11WELL
VOLUME (gal)
1.50
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
INITIAL
WATER LEVEL
(ft)
FLOW
RATE
(ml/min)
FINAL
WATER LEVEL
(ft)
TEMP
(deg C)
SPECIFIC
COND.
(umho/cm)
pH
(SU)
TURBIDITY
(NTU)
ORP
(mV -NEH)
DISSOLVED
OXYGEN
(mg/L)
62.29
360
64.81
16.56
116
6.88
9.1
118
8.06
N/A
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE:
TIME:
WATER LEVEL:
Well Vol.:
Evacuated:
N/A
N/A
Sampled:
Tubing Volume
1531
(MI) INITIAL PURGE VOL. EQUIPMENT PURGE ONLY SAMPLE
CHLORINE (mg/I)
Pump (Bladder) Volume
495
(MI) 0.75 SAMPLE COLLECTED BY
(ml) — 1 0.54 1 (gal) i EHS
DATE TIME
Total Purge Volume
2026
12/4/2023 @ 0930
0
:QC7By]-. EHS 12/6/23
Sample preservation verified to pH
(units) E771
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA OH3 ❑BORON ❑SR 89/90 FIGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 OSO4,CL ❑ALPHA SPEC
OMETALS OF_ALK ❑CO2 ❑RSK 175 OVOC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION
PAD
Good Condition
CAPS
Well cap in good conditon
CASING
Good Condition
iS TO WELLS
Access cleared into well
ECTIVE CASING
Casing in good condition
I MOUNT WELLS
TAG
Well tag in good condition
iS AROUND WELL
Access cleared around well
SECURITY
Well found locked
LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION NOTES
II Impacted By Silting: I NO

f� DUKE DUKE ENERGY 4 DUKE
ENER Y GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) l 4-Dec-2023 I 5-Dec-2023
WELL/LOCATION NAME
MW-8A
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
759.68
MIDDLE OF WETTED SCREEN (ft toc)
77.40
WELL DEPTH (ft TOC)
84.40
GS ELEV (ft msl)
757.61
PUMP INTAKE DEPTH (ft TOC)
83.40
SCREEN LENGTH (ft)
14
ELEV REF
NGVD 27
SCREEN INTERVAL (ft TOC) 70.40 TO 84.40
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT I QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE (psi) I RECHARGE (sec) DISCHARGE (sec)
FD-20231204-1 taken
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING W ec_:::]INUCLEAR
LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
62.39
WATER COLUMN (ft)
22.01
WATER ELEVATION (ft msl)
697.29
WELL VOLUME (gal)
3.59
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(degQ
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
9:56
64.12
360
16.41
104
6.73
4.2
347
7.64
N/A
9:59
64.12
360
16.40
102
6.72
3.6
351
1 7.66
N/A
10:02
64.12
360
16.41
100
6.71
2.5
351
7.69
N/A
DRAW -DOWN
1.73
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
1.00
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
1.60
(gal)
L12/4/2023 @0 1005
0
11 Sample preservation verified to pH
QC By: EHS 12/6/23 11
(units) =
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA OH3 ❑BORON ❑SR 89/90 OGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 0504,CL []ALPHA SPEC
OMETALS OF_ALK ❑CO2 ❑RSK 175 ❑VOC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS 7NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES I
WELL PAD
WELL CAPS
WELL CASING
ACCESS TO WELLS
PROTECTIVE CASING
FLUSH MOUNT WELLS
WELL TAG
ACCESS AROUND WELL
WELL SECURITY
WELL LOCK CONDITION
Well cap in good conditon
Good Condition
Access cleared into well
Casing in good condition
Well tag in good condition
Access cleared around well
Well found locked
Lock in Rood condition
Silting: I NO
SAMPLING NOTES

DUKE DUKE ENERGY
ENERGY GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR EQUIPMENT PURGE ONLY SAMPLING
DUDE
.' ENERGY
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
b b �
SAMPLING DATE(s) 4-Dec-2023 5-Dec-2023
WELL/LOCATION NAME
MW-9
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
711.87
MIDDLE OF WETTED SCREEN (ft toc)
28.71
WELL DEPTH (ft TOC)
30.80
GS ELEV (ft msl)
710.27
PUMP INTAKE DEPTH (ft TOC)
29.80
SCREEN LENGTH (ft)
14
ELEV REF
NGVD 27
SCREEN INTERVAL (ft TOC) 16.80 TO 30.80
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT
QED T1200
TUBING DIAMETER (in)
i/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE 1 15 (psi) RECHARGE 1 8 1 (sec) DISCHARGE 7 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL EA
NUCLEAR LANDFILL
Equip. Only Purge
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
26.61
WATER COLUMN (ft)
4.19
WATER ELEVATION (ft msl)
685.26
11WELL
VOLUME (gal)
0.68
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
INITIAL
WATER LEVEL
(ft)
FLOW
RATE
(ml/min)
FINAL
WATER LEVEL
(ft)
TEMP
(deg C)
SPECIFIC
COND.
(umho/cm)
pH
(SU)
TURBIDITY
(NTU)
ORP
(mV -NEH)
DISSOLVED
OXYGEN
(mg/L)
26.61
240
27.12
19.86
35
6.22
2.5
352
8.11
N/A
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE:
TIME:
WATER LEVEL:
Well Vol.:
Evacuated:
N/A
N/A
Sample:
Tubing Volume
647
(MI) INITIAL PURGE VOL. EQUIPMENT PURGE ONLY SAMPLE
CHLORINE (mg/I)
Pump (Bladder) Volume
495
(MI) 0.30 SAMPLE COLLECTED BY
(ml) — 1 0.30 1 (gal) i EHS
DATE TIME
Total Purge Volume
1142
1 12/5/2023 @ 1030
0
:QC7By]-. EHS 12/6/23
Sample preservation verified to pH
(units) E771
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA OH3 ❑BORON ❑SR 89/90 FIGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 OSO4,CL ❑ALPHA SPEC
OMETALS OF_ALK ❑CO2 ❑RSK 175 OVOC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION
PAD
Good Condition
CAPS
Well cap in good conditon
CASING
Good Condition
iS TO WELLS
Access cleared into well
ECTIVE CASING
Casing in good condition
I MOUNT WELLS
TAG
Well tag in good condition
iS AROUND WELL
Access cleared around well
SECURITY
Well found locked
LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION NOTES
II Impacted By Silting: I NO

f� DUKE DUKE ENERGY 4 DUKE
ENER Y GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) l 4-Dec-2023 I 5-Dec-2023
WELL/LOCATION NAME
MW-9A
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
712.13
MIDDLE OF WETTED SCREEN (ft toc) 40.80
WELL DEPTH (ft TOC)
47.80
GS ELEV (ft msl)
710.30
PUMP INTAKE DEPTH (ft TOC) 46.80
SCREEN LENGTH (ft)
14
ELEV REF
NGVD 27
SCREEN INTERVAL (ft TOC) 33.80 TO 47.80
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
Tubing Condition
Good:]I-
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) DISCHARGE (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING W ec_
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
27.00
WATER COLUMN (ft)
20.80
WATER ELEVATION (ft msl)
685.13
WELL VOLUME (gal)
3.39 :j
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(degQ
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
9:52
27.19
300
17.73
105
6.21
2.2
361
4.10
N/A
9:55
27.19
300
17.81
105
6.21
2.2
356
4.13
N/A
9:58
27.19
300
17.77
105
6.21
1.9
359
4.11
N/A
DRAW -DOWN
0.19
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
1.00
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
1.50
(gal)
12/5/2023 @ 1000
0
11 Sample preservation verified to pH
QC By: EHS 12/6/23 11
(units) =
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA OH3 ❑BORON ❑SR 89/90 OGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 0504,CL []ALPHA SPEC
OMETALS OF_ALK ❑CO2 ❑RSK 175 OVOC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS 7NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES I
WELL PAD
WELL CAPS
WELL CASING
ACCESS TO WELLS
PROTECTIVE CASING
FLUSH MOUNT WELLS
WELL TAG
ACCESS AROUND WELL
WELL SECURITY
WELL LOCK CONDITION
Well cap in good conditon
Good Condition
Access cleared into well
Casing in good condition
Well tag in good condition
Access cleared around well
Well found locked
Lock in Rood condition
Silting: I NO
SAMPLING NOTES

DUKE DUKE ENERGY
ENERGY GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR EQUIPMENT PURGE ONLY SAMPLING
DUDE
.' ENERGY
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
b b �
SAMPLING DATE(s) 4-Dec-2023 5-Dec-2023
WELL/LOCATION NAME
MW-10A
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
755.78
MIDDLE OF WETTED SCREEN (ft toc)
55.98
WELL DEPTH (ft TOC)
59.23
GS ELEV (ft msl)
753.87
PUMP INTAKE DEPTH (ft TOC)
58.23
SCREEN LENGTH (ft)
15
ELEV REF
NGVD 27
SCREEN INTERVAL (ft TOC) 44.23 TO 59.23
EQUIPMENT INFORMATION
Pump Condition
Good
SAMPLING EQUIPMENT
QED T1200
TUBING DIAMETER (in)
i/2 OD
Tubing Condition
Good
PUMP CONTROLLER SETTINGS
PRESSURE 1 30 (psi) RECHARGE 1 10 1 (sec) DISCHARGE 10 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL EA
NUCLEAR LANDFILL
Equip. Only Purge
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
52.72
WATER COLUMN (ft)
6.51
WATER ELEVATION (ft msl)
703.06
11WELL
VOLUME (gal)
1.06
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
INITIAL
WATER LEVEL
(ft)
FLOW
RATE
(ml/min)
FINAL
WATER LEVEL
(ft)
TEMP
(deg C)
SPECIFIC
COND.
(umho/cm)
pH
(SU)
TURBIDITY
(NTU)
ORP
(mV -NEH)
DISSOLVED
OXYGEN
(mg/L)
52.72
300
BTP
19.82
17
5.52
5.7
410
7.69
N/A
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE:
TIME:
WATER LEVEL:
Well Vol.:
Evacuated:
N/A
N/A
Sample:
Tubing Volume
1265
(MI) INITIAL PURGE VOL. EQUIPMENT PURGE ONLY SAMPLE
CHLORINE (mg/I)
Pump (Bladder) Volume
495
(MI) 0.50 SAMPLE COLLECTED BY
(ml) — 1 0.46 1 (gal) i EHS
DATE TIME
Total Purge Volume
1760
1 12/4/2023 @ 1450
0
:QC7By]-. EHS 12/6/23
Sample preservation verified to pH
(units) E771
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA OH3 ❑BORON ❑SR 89/90 FIGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 OSO4,CL ❑ALPHA SPEC
OMETALS OF_ALK ❑CO2 ❑RSK 175 OVOC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION
PAD
Good Condition
CAPS
Well cap in good conditon
CASING
Good Condition
iS TO WELLS
Access cleared into well
ECTIVE CASING
Casing in good condition
I MOUNT WELLS
TAG
Well tag in good condition
iS AROUND WELL
Access cleared around well
SECURITY
Well found locked
LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION NOTES
II Impacted By Silting: I NO

DUKE DUKE ENERGY
ENERGY SURFACE WATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR SURFACE WATER SAMPLING
DUKE
.' ENERGY
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
b b �
SAMPLING DATE(s) 4-Dec-2023 5-Dec-2023
WELL/LOCATION NAME
SW-1
SURFACE WATER LOCATION
INFORMATION
LOCATION TYPE:
I STREAM
IWAS WATER PRESENT:
I YES
IWAS THERE A NOTICABLE FLOW:
YES
SAMPLING METHOD:
PERISTALTIC PUMP
ILOCATION ENVIRONMENT:
I WOODED
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
USE
PURGE METHOD
]EE]WELL
NUCLEAR LANDFILL
Surface Water Sample
SAMPLING INFORMATION
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
DEPTH OF
INTAKE
(METERS)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
o
TURBIDITY
(NTU)
0
ORP
(mV-NEH)
0
DISSOLVED
OXYGEN
(mg/L)
❑
0.01
19.15
89
6.41
9.3
355
6.55
N/A
FLOW
CONDITIONS:
Flowing, 3.00 gallons purged
SURFACE WATER SAMPLE
CHLORINE (mg/1)
0
SAMPLE COLLECTED BY
DATE TIME
EHS
12/5/2023 @ 1445
QC BY: EHS 12/6/23
Sample preservation verified ME70771
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA OH3 ❑BORON ❑SR 89/90 OGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 I]504,CL ❑ALPHA SPEC
OMETALS OF ALK ❑CO2 ❑RSK 175 OVOC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
PAD Well Im
CAPS
CASING
iS TO WELLS Access cleared into well
ECTIVE CASING
I MOUNT WELLS
TAG
iS AROUND WELL Access cleared around well
SECURITY
LOCK CONDITION
SAMPLING NOTES
NO

DUKE DUKE ENERGY
ENERGY SURFACE WATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR SURFACE WATER SAMPLING
DUKE
` ENERGY
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) 4-Dec-2023 5-Dec-2023
WELL/LOCATION NAME
SW-2
SURFACE WATER LOCATION
INFORMATION
LOCATION TYPE:
I STREAM
IWAS WATER PRESENT:
I YES
IWAS THERE A NOTICABLE FLOW:
YES
SAMPLING METHOD:
PERISTALTIC PUMP
ILOCATION ENVIRONMENT:
I WOODED
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
USE
PURGE METHOD
]EE]WELL
NUCLEAR LANDFILL
Surface Water Sample
SAMPLING INFORMATION
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
DEPTH OF
INTAKE
(METERS)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
o
TURBIDITY
(NTU)
0
ORP
(mV-NEH)
0
DISSOLVED
OXYGEN
(mg/L)
❑
0.01
16.67
99
6.48
16.8
337
6.19
N/A
FLOW
CONDITIONS:
Flowing downstream of beaver pond, beaver has
turned area into wetland, 3.00 gallons purged
SURFACE WATER SAMPLE
CHLORINE (mg/1)
0
SAMPLE COLLECTED BY
DATE TIME
EHS
12/5/2023 @ 1140
QC BY: EHS 12/6/23
Sample preservation verified ME70771
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA OH3 ❑BORON ❑SR 89/90 OGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 I]504,CL ❑ALPHA SPEC
OMETALS OF_ALK ❑CO2 ❑RSK 175 OVOC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
PAD Well Im
CAPS
CASING
iS TO WELLS Access cleared into well
ECTIVE CASING
I MOUNT WELLS
TAG
iS AROUND WELL Access cleared around well
SECURITY
LOCK CONDITION
SAMPLING NOTES
NO

DUKE DUKE ENERGY
- ENERGY SURFACE WATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR SURFACE WATER SAMPLING
DUKE
` ENERGY
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s) 4-Dec-2023 5-Dec-2023
WELL/LOCATION NAME
LEACHATE POND
SURFACE WATER LOCATION
INFORMATION
LOCATION TYPE:
LEACHATE/DRAINAGE
IWAS WATER PRESENT:
I YES
IWAS THERE A NOTICABLE FLOW:
YES
SAMPLING METHOD:
GRAB
ILOCATION ENVIRONMENT:
I PIPE
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
ESurface
Water Sample
SAMPLING INFORMATION
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
DEPTH OF
INTAKE
(METERS)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
o
TURBIDITY
(NTU)
0
ORP
(mV-NEH)
0
DISSOLVED
OXYGEN
(mg/L)
❑
0.01
16.32
745
7.43
5.2
344
7.27
N/A
FLOW
CONDITIONS:
PIPE DISCHARGE FLOW RATE = >1000 ml/min
SURFACE WATER SAMPLE
CHLORINE (mg/1)
0
SAMPLE COLLECTED BY
DATE TIME
EHS
12/4/2023 @ 1110
QC BY: EHS 12/6/23
Sample preservation verified ME70771
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA OH3 ❑BORON ❑SR 89/90 OGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 I]504,CL ❑ALPHA SPEC
OMETALS OF_ALK ❑CO2 ❑RSK 175 OVOC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
PAD Well Im
CAPS
CASING
iS TO WELLS Access cleared into well
ECTIVE CASING
I MOUNT WELLS
TAG
iS AROUND WELL Access cleared around well
SECURITY
LOCK CONDITION
SAMPLING NOTES
NO

NORTH CAROLINA GROUNDWATER SAMPLING SITE CHECK LIST
SITE: MCGUIRE NUCLEAR STATION SAMPLE DATE December 4-5, 2023
PROJECT: NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM FIELD CREW EHS
SITE CONTACT John G. Ballard
WEATHER 12/4/2023 12/5/2023
PAGE 1 OF 1
MW-5R
MW-5A
MW-6
MW-6A
MW-7R
MW-7A
MW-g
MW-BA
MW-9
MW-9A
MW-10A
SW-1
SW-2
LEACH POND
ACCESS TO WELLS
Access cleared into well
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
Access cleared around well
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
Tall grass or weeds - needs mowing
Road washing out/ muddy/ needs grading
Fallen tree blocking access
WELL DEPTH
Well impacted by silting
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
N/A
N/A
N/A
WELL SECURITY
Well found locked
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
N/A
N/A
Well found unlocked
WELL LOCK CONDITION
Lock in good condition
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
N/A
N/A
Lock rusted, difficult to open / needs replacing
Replaced damaged lock
WELL CASINGS
Casing in good condition
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
N/A
N/A
Damaged casing / still functional
Damaged casing / repair required
CONCRETE PADS
Pad in good condition
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
N/A
N/A
Minor cracks
Major cracks / broken / repair required
Undermined / washing out
Fire ants around concrete pad
WELL PROTECTIVE CASINGS
Casing in good condition
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
N/A
N/A
Damaged casing / still functional
Damaged casing / repair required
Broken hinge on protective lid
Wasp nest inside protective casing
Ants inside protective casing
WELL CAPS
Well cap in good conditon
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
N/A
N/A
Damaged / needs replacement
Replaced damaged well cap
FLUSH MOUNT WELLS
Vault in good condition
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Water inside vault
Vault bolt holes broken or stripped
Bolts stripped
Vault lid cracked or broken
WELL ID TAGS
Well tag in good condition
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
N/A
N/A
Well tag missing
Well tag damaged / illegible
Lacks required information - Driller Reg fJ
Lacks required information - Completion date
Lacks required information -Total well depth
Lacks required information - Depth to screen
Lacks required info - Casing depth / diam.
Lacks required information -Screen interval
Lacks required information - Static WL/date
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Lacks required information - Non potable tag
NOTE:

MCGUIRE NUCLEAR STATION
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING
PROGRAM
GROUNDWATER MONITORING FIELD DATA
PERMIT # 60-04
Purge Methods
LF = Low Flow
C = Connventional
EOP = Equip. Only Purge
LO = Level Only NP = No Purge
LF(M) = Low Flow (Mod.)
* = Applicable to LF & LF(M) Purging Only
WELL
DEPTH TO
WATER
PUMP WELL EVAC
SPECIFIC
DATE
WELL
DEPTH
WATER
ELEV.
APPEARANCE
ODOR
PURGE RATE VOL. VOL.
EVAC
TEMP.
CONDUCTANCE
pH
TURBIDITY
ORP
DO
NO
(ff - TOC)
(ft _ TOC)
(ft)
METHOD (ml/min) (gat) (gal)
(YES/NO)
(deg. C)
(umho/cm)
(snits)
(NTU's)
(mV-NHE)
(mg/L)
12/4/2023
MW-5R
76.35
61.88
705.50
Normal
None
LF 348.00 2.36 7.90
N/A
17.10
17
5.32
19.9
438
7.99
12/4/2023
MW-5A
96.00
63.55
704.87
Normal
None
LF 270.00 5.29 2.10
N/A
17.69
49
6.61
4.0
364
7.36
12/4/2023
MW-6
37.20
32.33
696.12
Normal
None
EOP N/A 0.79 0.40
N/A
17.15
115
5.95
3.2
398
8.13
12/4/2023
MW-6A
47.90
31.50
697.48
Normal
None
LF 330.00 2.67 1.55
N/A
16.88
54
5.58
4.0
410
7.87
12/5/2023
MW-7R
48.89
35.22
690.94
Normal
None
LF 240.00 2.23 1.40
N/A
17.57
46
5.84
1.7
376
7.63
12/5/2023
MW-7A
59.40
32.97
691.69
Normal
None
LF 270.00 4.31 1.25
N/A
17.32
101
6.53
7.7
335
7.40
12/4/2023
MW-8
71.50
62.29
697.31
Normal
None
EOP N/A 1.50 0.75
N/A
16.56
116
6.88
9.1
118
8.06
12/4/2023
MW-8A
84.40
62.39
697.29
Normal
None
LF 360.00 3.59 1.60
N/A
16.41
100
6.71
2.5
351
7.69
12/5/2023
MW-9
30.80
26.61
685.26
Normal
None
EOP N/A 0.68 0.30
N/A
19.86
35
6.22
2.5
352
8.11
12/5/2023
MW-9A
47.80
27.00
685.13
Normal
None
LF 300.00 3.39 1.50
N/A
17.77
105
6.21
1.9
359
4.11
12/4/2023
MW-10A
59.23
52.72
703.06
Normal
None
EOP N/A 1.06 0.50
N/A
19.82
17
5.52
5.7
410
7.69
12/5/2023
SW-1
0.00
Normal
None
SWS N/A N/A
N/A
19.15
89
6.41
9.3
355
6.55
12/5/2023
SW-2
0.00
Normal
None
SWS N/A N/A
N/A
16.67
99
6.48
16.8
337
6.19
12/4/2023
LEACHATE POND
0.00
Normal
None
SWS N/A N/A
N/A
16.32
745
7.43
5.2
344
7.27

Appendix IV - Laboratory Reports and Chain -of -Custody
Forms

•DIE Analytical Laboratory
ENERGY,
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J23110327
Project Name:
MCGUIRE - GW LF2
Task Code:
LF
Customer Name(s):
A Healy, C Murphy, B Moeller, J Stowe, E Smith
Customer Address:
McGuire Nuclear Station
13225 Hagers Ferry Rd
Mail Code: MG01CH
Huntersville, NC 28078-8985
Lab Contact: Peggy Kendall Phone: [phone]
Report Authorized By: �#- Jf� pate: 1/5/2024
(Signature)
Kendall
Program Comments:
QC Note:
Page 1 of 148
Acetone detected in both field blanks and trip blank. Per Pace, the acetone hits do not appear to come from the actual lab
process as the method blanks were non -detect. They said it may be possible to attribute the hits to collection or possibly the
vials themselves.
The internal standard for the 1 A dioxane analysis failed in the initial run of MW-5R and FB-20231205-1400. The samples were
re -run outside of hold time with a passing internal standard. Both samples were non -detect.
Please refer to the vendor lab case narrative for a detailed explanation of 8260D (Low Level) qualifiers applied to some results
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions: Page 2 of 148
Sample ID
Plant/Station
Collection
Date and Time
Collected By
Sample Description
2023028548
MCGUIRE
04-Dec-23
2:00 PM
Ethan Smith
MNS MW-5R
2023028549
MCGUIRE
04-Dec-23
12:00 PM
Ethan Smith
MNS MW-5A
2023028550
MCGUIRE
04-Dec-23
3:50 PM
Ethan Smith
MNS MW-6
2023028551
MCGUIRE
04-Dec-23
3:30 PM
Ethan Smith
MNS MW-6A
2023028552
MCGUIRE
05-Dec-23
1:45 PM
Ethan Smith
MNS MW-7R
2023028553
MCGUIRE
05-Dec-23
1:05 PM
Ethan Smith
MNS MW-7A
2023028554
MCGUIRE
04-Dec-23
9:30 AM
Ethan Smith
MNS MW-8
2023028555
MCGUIRE
04-Dec-23
10:05 AM
Ethan Smith
MNS MW-8A
2023028556
MCGUIRE
05-Dec-23
10:30 AM
Ethan Smith
MNS MW-9
2023028557
MCGUIRE
05-Dec-23
10:00 AM
Ethan Smith
MNS MW-9A
2023028558
MCGUIRE
04-Dec-23
2:50 PM
Ethan Smith
MNS MW-10A
2023028559
MCGUIRE
05-Dec-23
2:45 PM
Ethan Smith
MNS SW-1
2023028560
MCGUIRE
05-Dec-23
11:40 AM
Ethan Smith
MNS SW-2
2023028561
MCGUIRE
04-Dec-23
11:10 AM
Ethan Smith
MNS LEACHATE POND
2023028562
MCGUIRE
04-Dec-23
10:30 AM
Ethan Smith
MNS FB-20231204-1030
2023028563
MCGUIRE
05-Dec-23
2:00 PM
Ethan Smith
MNS FB-20231205-1400
2023028564
MCGUIRE
04-Dec-23
8:00 AM
Ethan Smith
MNS TB-20231204-0800
2023028565
MCGUIRE
04-Dec-23
Ethan Smith
MNS FD-20231204-1
18 Total Samples

Page 3 of 148
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
❑d Job Summary Report
❑� Sample Identification
❑� Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
❑� Analytical Laboratory QC Report
❑d Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑� Chain of Custody
❑� Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 1/5/2024

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23110327
Site: MNS MW-5R
Collection Date: 12/04/2023 02:00 PM Loc code: MNS MW-5R
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q23120119
Total Alkalinity as CaCO3 4.69 J mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q23120075
Chloride
1.1
mg/L
0.1
0.0154
1
Sulfate
0.65
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q23120112
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q23120084
Barium (Ba)
0.021
mg/L
0.005
0.002
1
Calcium (Ca)
0.873
mg/L
0.05
0.012
1
Magnesium (Mg)
0.810
mg/L
0.02
0.008
1
Potassium (K)
0.753
mg/L
0.1
0.031
1
Sodium (Na)
0.868
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q23120101
Arsenic (As)
0.12 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
1.20
ug/L
1
0.185
1
Lead (Pb)
0.546 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed
by Pace Laboratories)
Vendor Parameter
Complete
TOTAL PETROLEUM HYDROCARBONS - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Sample #: 2023028548
Matrix: GW RCRA
Page 4 of 148
Method Analysis Date/Time Analyst
SM 2320134d 12/08/2023 10:55 CELL106
EPA 9056A
12/07/2023 08:09
BGN9034
EPA 9056A
12/07/2023 08:09
BGN9034
EPA 7470A
12/12/2023 10:42
SNEGLIA
SW 601OD
12/12/2023 11:34
CELL106
SW 601OD
12/12/2023 11:34
CELL106
SW 601OD
12/12/2023 11:34
CELL106
SW 601OD
12/12/2023 11:34
CELL106
SW 601OD
12/12/2023 11:34
CELL106
SW 6020B
12/08/2023 19:38
MHALL3
SW 6020B
12/08/2023 19:38
MHALL3
SW 6020E
12/08/2023 19:38
MHALL3
SW 6020B
12/08/2023 19:38
MHALL3
SW 6020E
12/08/2023 19:38
MHALL3
SW 6020B
12/08/2023 19:38
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23110327
Site: MNS MW-5A
Collection Date: 12/04/2023 12:00 PM Loc code: MNS MW-5A
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q23120119
Total Alkalinity as CaCO3 21.6 mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q23120075
Chloride
1.3
mg/L
0.1
0.0154
1
Sulfate
2.3
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q23120112
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q23120084
Barium (Ba)
0.022
mg/L
0.005
0.002
1
Calcium (Ca)
3.03
mg/L
0.05
0.012
1
Magnesium (Mg)
1.31
mg/L
0.02
0.008
1
Potassium (K)
1.01
mg/L
0.1
0.031
1
Sodium (Na)
6.40
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q23120101
Arsenic (As)
0.306 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.586 J
ug/L
1
0.185
1
Lead (Pb)
0.059 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.217 J
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed
by Pace Laboratories)
Vendor Parameter
Complete
TOTAL PETROLEUM HYDROCARBONS - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Sample #: 2023028549
Matrix: GW RCRA
Page 5 of 148
Method Analysis Date/Time Analyst
SM 2320134d 12/08/2023 11:07 CELL106
EPA 9056A
12/07/2023 08:56
BGN9034
EPA 9056A
12/07/2023 08:56
BGN9034
EPA 7470A
12/12/2023 10:44
SNEGLIA
SW 601OD
12/12/2023 11:46
CELL106
SW 601OD
12/12/2023 11:46
CELL106
SW 601OD
12/12/2023 11:46
CELL106
SW 601OD
12/12/2023 11:46
CELL106
SW 601OD
12/12/2023 11:46
CELL106
SW 6020B
12/08/2023 19:10
MHALL3
SW 6020B
12/08/2023 19:10
MHALL3
SW 6020E
12/08/2023 19:10
MHALL3
SW 6020B
12/08/2023 19:10
MHALL3
SW 6020E
12/08/2023 19:10
MHALL3
SW 6020B
12/08/2023 19:10
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23110327
Site: MNS MW-6
Collection Date: 12/04/2023 03:50 PM Loc code: MNS MW-6
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q23120119
Total Alkalinity as CaCO3 57.7 mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q23120075
Chloride
1.3
mg/L
0.1
0.0154
1
Sulfate
2.3
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q23120112
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q23120084
Barium (Ba)
0.047
mg/L
0.005
0.002
1
Calcium (Ca)
18.8
mg/L
0.05
0.012
1
Magnesium (Mg)
5.93
mg/L
0.02
0.008
1
Potassium (K)
1.04
mg/L
0.1
0.031
1
Sodium (Na)
6.75
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q23120101
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
1.96
ug/L
1
0.185
1
Lead (Pb)
0.037 U
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed
by Pace Laboratories)
Vendor Parameter
Complete
TOTAL PETROLEUM HYDROCARBONS - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Sample #: 2023028550
Matrix: GW RCRA
Page 6 of 148
Method Analysis Date/Time Analyst
SM 2320134d 12/08/2023 11:21 CELL106
EPA 9056A
12/07/2023 09:12
BGN9034
EPA 9056A
12/07/2023 09:12
BGN9034
EPA 7470A
12/12/2023 10:47
SNEGLIA
SW 601OD
12/12/2023 11:50
CELL106
SW 601OD
12/12/2023 11:50
CELL106
SW 601OD
12/12/2023 11:50
CELL106
SW 601OD
12/12/2023 11:50
CELL106
SW 601OD
12/12/2023 11:50
CELL106
SW 6020B
12/08/2023 19:47
MHALL3
SW 6020B
12/08/2023 19:47
MHALL3
SW 6020E
12/08/2023 19:47
MHALL3
SW 6020B
12/08/2023 19:47
MHALL3
SW 6020E
12/08/2023 19:47
MHALL3
SW 6020B
12/08/2023 19:47
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23110327
Site: MNS MW-6A
Collection Date: 12/04/2023 03:30 PM Loc code: MNS MW-6A
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q23120119
Total Alkalinity as CaCO3 13.0 mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q23120075
Chloride
5.7
mg/L
0.1
0.0154
1
Sulfate
0.05 J
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q23120112
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q23120084
Barium (Ba)
0.052
mg/L
0.005
0.002
1
Calcium (Ca)
5.19
mg/L
0.05
0.012
1
Magnesium (Mg)
1.58
mg/L
0.02
0.008
1
Potassium (K)
0.275
mg/L
0.1
0.031
1
Sodium (Na)
4.01
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q23120101
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.696 J
ug/L
1
0.185
1
Lead (Pb)
0.037 U
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed
by Pace Laboratories)
Vendor Parameter
Complete
TOTAL PETROLEUM HYDROCARBONS - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Sample #: 2023028551
Matrix: GW RCRA
Page 7 of 148
Method Analysis Date/Time Analyst
SM 2320134d 12/08/2023 11:30 CELL106
EPA 9056A
12/07/2023 09:27
BGN9034
EPA 9056A
12/07/2023 09:27
BGN9034
EPA 7470A
12/12/2023 10:49
SNEGLIA
SW 601OD
12/12/2023 11:53
CELL106
SW 601OD
12/12/2023 11:53
CELL106
SW 601OD
12/12/2023 11:53
CELL106
SW 601OD
12/12/2023 11:53
CELL106
SW 601OD
12/12/2023 11:53
CELL106
SW 6020B
12/08/2023 19:57
MHALL3
SW 6020B
12/08/2023 19:57
MHALL3
SW 6020E
12/08/2023 19:57
MHALL3
SW 6020B
12/08/2023 19:57
MHALL3
SW 6020E
12/08/2023 19:57
MHALL3
SW 6020B
12/08/2023 19:57
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23110327
Site: MNS MW-7R
Collection Date: 12/05/2023 01:45 PM Loc code: MNS MW-7R
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q23120119
Total Alkalinity as CaCO3 18.6 mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q23120075
Chloride
2.5
mg/L
0.1
0.0154
1
Sulfate
0.05 J
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q23120112
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q23120084
Barium (Ba)
0.026
mg/L
0.005
0.002
1
Calcium (Ca)
4.03
mg/L
0.05
0.012
1
Magnesium (Mg)
3.10
mg/L
0.02
0.008
1
Potassium (K)
0.259
mg/L
0.1
0.031
1
Sodium (Na)
1.24
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q23120101
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.516 J
ug/L
1
0.185
1
Lead (Pb)
0.058 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed
by Pace Laboratories)
Vendor Parameter
Complete
TOTAL PETROLEUM HYDROCARBONS - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Sample #: 2023028552
Matrix: GW RCRA
Page 8 of 148
Method Analysis Date/Time Analyst
SM 2320134d 12/08/2023 11:37 CELL106
EPA 9056A
12/07/2023 09:43
BGN9034
EPA 9056A
12/07/2023 09:43
BGN9034
EPA 7470A
12/12/2023 10:52
SNEGLIA
SW 601OD
12/12/2023 11:57
CELL106
SW 601OD
12/12/2023 11:57
CELL106
SW 601OD
12/12/2023 11:57
CELL106
SW 601OD
12/12/2023 11:57
CELL106
SW 601OD
12/12/2023 11:57
CELL106
SW 6020B
12/08/2023 20:06
MHALL3
SW 6020B
12/08/2023 20:06
MHALL3
SW 6020E
12/08/2023 20:06
MHALL3
SW 6020B
12/08/2023 20:06
MHALL3
SW 6020E
12/08/2023 20:06
MHALL3
SW 6020B
12/08/2023 20:06
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23110327
Site: MNS MW-7A
Collection Date: 12/05/2023 01:05 PM Loc code: MNS MW-7A
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q23120173
Total Alkalinity as CaCO3 56 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q23120075
Chloride
1.1
mg/L
0.1
0.0154
1
Sulfate
0.24
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q23120112
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q23120084
Barium (Ba)
0.005 J
mg/L
0.005
0.002
1
Calcium (Ca)
14.5
mg/L
0.05
0.012
1
Magnesium (Mg)
3.69
mg/L
0.02
0.008
1
Potassium (K)
0.450
mg/L
0.1
0.031
1
Sodium (Na)
3.64
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q23120101
Arsenic (As)
0.138 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.539 J
ug/L
1
0.185
1
Lead (Pb)
0.037 U
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.045 J
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed
by Pace Laboratories)
Vendor Parameter
Complete
TOTAL PETROLEUM HYDROCARBONS - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Sample #: 2023028553
Matrix: GW RCRA
Page 9 of 148
Method Analysis Date/Time Analyst
SM 2320B 12/12/2023 11:26 SNEGLIA
EPA 9056A
12/07/2023 09:59
BGN9034
EPA 9056A
12/07/2023 09:59
BGN9034
EPA 7470A
12/12/2023 11:01
SNEGLIA
SW 601OD
12/12/2023 12:17
CELL106
SW 601OD
12/12/2023 12:17
CELL106
SW 601OD
12/12/2023 12:17
CELL106
SW 601OD
12/12/2023 12:17
CELL106
SW 601OD
12/12/2023 12:17
CELL106
SW 6020B
12/08/2023 20:15
MHALL3
SW 6020B
12/08/2023 20:15
MHALL3
SW 6020E
12/08/2023 20:15
MHALL3
SW 6020B
12/08/2023 20:15
MHALL3
SW 6020E
12/08/2023 20:15
MHALL3
SW 6020B
12/08/2023 20:15
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23110327
Site: MNS MW-8
Collection Date: 12/04/2023 09:30 AM Loc code: MNS MW-8
Analyte Result Units Qualifiers RDL MDL DF
ALKALINITY (FIXED END POINT 4.5) - Q23120173
Total Alkalinity as CaCO3 63 mg/L 20 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q23120075
Chloride
1.3
mg/L
0.1
0.0154
1
Sulfate
0.94
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q23120112
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q23120084
Barium (Ba)
0.014
mg/L
0.005
0.002
1
Calcium (Ca)
16.1
mg/L
0.05
0.012
1
Magnesium (Mg)
3.16
mg/L
0.02
0.008
1
Potassium (K)
0.926
mg/L
0.1
0.031
1
Sodium (Na)
6.37
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q23120101
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.675 J
ug/L
1
0.185
1
Lead (Pb)
0.037 U
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed
by Pace Laboratories)
Vendor Parameter
Complete
TOTAL PETROLEUM HYDROCARBONS - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 10 of 148
Sample #: 2023028554
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320B 12/12/2023 11:30 SNEGLIA
EPA 9056A
12/07/2023 10:15
BGN9034
EPA 9056A
12/07/2023 10:15
BGN9034
EPA 7470A
12/12/2023 11:08
SNEGLIA
SW 601OD
12/12/2023 12:20
CELL106
SW 601OD
12/12/2023 12:20
CELL106
SW 601OD
12/12/2023 12:20
CELL106
SW 601OD
12/12/2023 12:20
CELL106
SW 601OD
12/12/2023 12:20
CELL106
SW 6020B
12/08/2023 20:25
MHALL3
SW 6020B
12/08/2023 20:25
MHALL3
SW 6020E
12/08/2023 20:25
MHALL3
SW 6020B
12/08/2023 20:25
MHALL3
SW 6020E
12/08/2023 20:25
MHALL3
SW 6020B
12/08/2023 20:25
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23110327
Site: MNS MW-8A
Collection Date: 12/04/2023 10:05 AM Loc code: MNS MW-8A
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q23120119
Total Alkalinity as CaCO3 49.9 mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q23120075
Chloride
2.0
mg/L
0.1
0.0154
1
Sulfate
1.2
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q23120112
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q23120084
Barium (Ba)
0.032
mg/L
0.005
0.002
1
Calcium (Ca)
12.2
mg/L
0.05
0.012
1
Magnesium (Mg)
3.78
mg/L
0.02
0.008
1
Potassium (K)
1.43
mg/L
0.1
0.031
1
Sodium (Na)
4.95
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q23120101
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.533 J
ug/L
1
0.185
1
Lead (Pb)
0.037 U
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed
by Pace Laboratories)
Vendor Parameter
Complete
TOTAL PETROLEUM HYDROCARBONS - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 11 of 148
Sample #: 2023028555
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320134d 12/08/2023 11:43 CELL106
EPA 9056A
12/07/2023 10:30
BGN9034
EPA 9056A
12/07/2023 10:30
BGN9034
EPA 7470A
12/12/2023 11:11
SNEGLIA
SW 601OD
12/12/2023 12:32
CELL106
SW 601OD
12/12/2023 12:32
CELL106
SW 601OD
12/12/2023 12:32
CELL106
SW 601OD
12/12/2023 12:32
CELL106
SW 601OD
12/12/2023 12:32
CELL106
SW 6020B
12/08/2023 20:34
MHALL3
SW 6020B
12/08/2023 20:34
MHALL3
SW 6020E
12/08/2023 20:34
MHALL3
SW 6020B
12/08/2023 20:34
MHALL3
SW 6020E
12/08/2023 20:34
MHALL3
SW 6020B
12/08/2023 20:34
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23110327
Site: MNS MW-9
Collection Date: 12/05/2023 10:30 AM Loc code: MNS MW-9
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q23120119
Total Alkalinity as CaCO3 39.2 mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q23120075
Chloride
2.3
mg/L
0.1
0.0154
1
Sulfate
0.14
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q23120112
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q23120084
Barium (Ba)
0.020
mg/L
0.005
0.002
1
Calcium (Ca)
8.73
mg/L
0.05
0.012
1
Magnesium (Mg)
3.83
mg/L
0.02
0.008
1
Potassium (K)
0.434
mg/L
0.1
0.031
1
Sodium (Na)
3.47
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q23120101
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
1.29
ug/L
1
0.185
1
Lead (Pb)
0.037 U
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed
by Pace Laboratories)
Vendor Parameter
Complete
TOTAL PETROLEUM HYDROCARBONS - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 12 of 148
Sample #: 2023028556
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320134d 12/08/2023 11:51 CELL106
EPA 9056A
12/07/2023 10:46
BGN9034
EPA 9056A
12/07/2023 10:46
BGN9034
EPA 7470A
12/12/2023 11:13
SNEGLIA
SW 601OD
12/12/2023 12:36
CELL106
SW 601OD
12/12/2023 12:36
CELL106
SW 601OD
12/12/2023 12:36
CELL106
SW 601OD
12/12/2023 12:36
CELL106
SW 601OD
12/12/2023 12:36
CELL106
SW 6020B
12/08/2023 20:43
MHALL3
SW 6020B
12/08/2023 20:43
MHALL3
SW 6020E
12/08/2023 20:43
MHALL3
SW 6020B
12/08/2023 20:43
MHALL3
SW 6020E
12/08/2023 20:43
MHALL3
SW 6020B
12/08/2023 20:43
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23110327
Site: MNS MW-9A
Collection Date: 12/05/2023 10:00 AM Loc code: MNS MW-9A
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q23120119
Total Alkalinity as CaCO3 53.5 mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q23120075
Chloride
1.7
mg/L
0.1
0.0154
1
Sulfate
0.18
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q23120112
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q23120084
Barium (Ba)
0.011
mg/L
0.005
0.002
1
Calcium (Ca)
11.8
mg/L
0.05
0.012
1
Magnesium (Mg)
4.94
mg/L
0.02
0.008
1
Potassium (K)
0.554
mg/L
0.1
0.031
1
Sodium (Na)
5.10
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q23120101
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
1.96
ug/L
1
0.185
1
Lead (Pb)
0.037 U
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed
by Pace Laboratories)
Vendor Parameter
Complete
TOTAL PETROLEUM HYDROCARBONS - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 13 of 148
Sample #: 2023028557
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320134d 12/08/2023 11:59 CELL106
EPA 9056A
12/07/2023 11:02
BGN9034
EPA 9056A
12/07/2023 11:02
BGN9034
EPA 7470A
12/12/2023 11:16
SNEGLIA
SW 601OD
12/12/2023 12:40
CELL106
SW 601OD
12/12/2023 12:40
CELL106
SW 601OD
12/12/2023 12:40
CELL106
SW 601OD
12/12/2023 12:40
CELL106
SW 601OD
12/12/2023 12:40
CELL106
SW 6020B
12/08/2023 21:20
MHALL3
SW 6020B
12/08/2023 21:20
MHALL3
SW 6020E
12/08/2023 21:20
MHALL3
SW 6020B
12/08/2023 21:20
MHALL3
SW 6020E
12/08/2023 21:20
MHALL3
SW 6020B
12/08/2023 21:20
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23110327
Site: MNS MW-10A
Collection Date: 12/04/2023 02:50 PM Loc code: MNS MW-10A
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q23120119
Total Alkalinity as CaCO3 8.05 mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q23120075
Chloride
1.3
mg/L
0.1
0.0154
1
Sulfate
0.43
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q23120112
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q23120084
Barium (Ba)
0.024
mg/L
0.005
0.002
1
Calcium (Ca)
1.63
mg/L
0.05
0.012
1
Magnesium (Mg)
1.44
mg/L
0.02
0.008
1
Potassium (K)
0.801
mg/L
0.1
0.031
1
Sodium (Na)
1.81
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q23120101
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.727 J
ug/L
1
0.185
1
Lead (Pb)
0.224 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed
by Pace Laboratories)
Vendor Parameter
Complete
TOTAL PETROLEUM HYDROCARBONS - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 14 of 148
Sample #: 2023028558
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320134d 12/08/2023 12:07 CELL106
EPA 9056A
12/07/2023 12:04
BGN9034
EPA 9056A
12/07/2023 12:04
BGN9034
EPA 7470A
12/12/2023 11:18
SNEGLIA
SW 601OD
12/12/2023 12:44
CELL106
SW 601OD
12/12/2023 12:44
CELL106
SW 601OD
12/12/2023 12:44
CELL106
SW 601OD
12/12/2023 12:44
CELL106
SW 601OD
12/12/2023 12:44
CELL106
SW 6020B
12/08/2023 21:29
MHALL3
SW 6020B
12/08/2023 21:29
MHALL3
SW 6020E
12/08/2023 21:29
MHALL3
SW 6020B
12/08/2023 21:29
MHALL3
SW 6020E
12/08/2023 21:29
MHALL3
SW 6020B
12/08/2023 21:29
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23110327
Site: MNS SW-1
Collection Date: 12/05/2023 02:45 PM Loc code: MNS SW-1
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q23120119
Total Alkalinity as CaCO3 50.7 mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q23120075
Chloride
2.9
mg/L
0.1
0.0154
1
Sulfate
1.2
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q23120112
Mercury (Hg)
0.01 J
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED) - Q23120082
Barium (Ba)
0.023
mg/L
0.005
0.002
1
TOTAL RECOVERABLE METALS BY ICP - Q23120084
Barium (Ba)
0.024
mg/L
0.005
0.002
1
Calcium (Ca)
11.0
mg/L
0.05
0.012
1
Magnesium (Mg)
4.37
mg/L
0.02
0.008
1
Potassium (K)
1.47
mg/L
0.1
0.031
1
Sodium (Na)
5.75
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) -
023120094
Arsenic (As)
0.118 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.275 J
ug/L
1
0.185
1
Lead (Pb)
0.037 U
ug/L
1
0.037
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q23120101
Arsenic (As)
0.142 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
Lead (Pb)
0.052 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
TOTAL PETROLEUM HYDROCARBONS - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 15 of 148
Sample #: 2023028559
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320134d 12/08/2023 12:14 CELL106
EPA 9056A
12/07/2023 12:20
BGN9034
EPA 9056A
12/07/2023 12:20
BGN9034
EPA 7470A
12/12/2023 11:20
SNEGLIA
SW 601OD
12/08/2023 18:01
CELL106
SW 601OD
12/12/2023 12:48
CELL106
SW 601OD
12/12/2023 12:48
CELL106
SW 601OD
12/12/2023 12:48
CELL106
SW 601OD
12/12/2023 12:48
CELL106
SW 601OD
12/12/2023 12:48
CELL106
SW 6020B
12/11/2023 17:28
MHALL3
SW 6020B
12/11/2023 17:28
MHALL3
SW 6020E
12/11/2023 17:28
MHALL3
SW 6020E
12/11/2023 17:28
MHALL3
SW 6020B
12/11/2023 17:28
MHALL3
SW 6020B
12/08/2023 21:39
MHALL3
SW 6020B
12/08/2023 21:39
MHALL3
SW 6020E
12/08/2023 21:39
MHALL3
SW 6020B
12/08/2023 21:39
MHALL3
SW 6020E
12/08/2023 21:39
MHALL3
SW 6020B
12/08/2023 21:39
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23110327
Site: MNS SW-2
Collection Date: 12/05/2023 11:40 AM Loc code: MNS SW-2
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q23120119
Total Alkalinity as CaCO3 53.3 mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q23120075
Chloride
2.5
mg/L
0.1
0.0154
1
Sulfate
2.1
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q23120112
Mercury (Hg)
0.01 J
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED) - Q23120082
Barium (Ba)
0.031
mg/L
0.005
0.002
1
TOTAL RECOVERABLE METALS BY ICP - Q23120084
Barium (Ba)
0.034
mg/L
0.005
0.002
1
Calcium (Ca)
12.0
mg/L
0.05
0.012
1
Magnesium (Mg)
4.64
mg/L
0.02
0.008
1
Potassium (K)
1.70
mg/L
0.1
0.031
1
Sodium (Na)
5.68
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) -
023120094
Arsenic (As)
0.153 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.21 J
ug/L
1
0.185
1
Lead (Pb)
0.037 U
ug/L
1
0.037
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q23120101
Arsenic (As)
0.224 J
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.322 J
ug/L
1
0.185
1
Lead (Pb)
0.214 J
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
TOTAL PETROLEUM HYDROCARBONS - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 16 of 148
Sample #: 2023028560
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320134d 12/08/2023 12:22 CELL106
EPA 9056A
12/07/2023 12:35
BGN9034
EPA 9056A
12/07/2023 12:35
BGN9034
EPA 7470A
12/12/2023 11:23
SNEGLIA
SW 601OD
12/08/2023 18:17
CELL106
SW 601OD
12/12/2023 12:51
CELL106
SW 601OD
12/12/2023 12:51
CELL106
SW 601OD
12/12/2023 12:51
CELL106
SW 601OD
12/12/2023 12:51
CELL106
SW 601OD
12/12/2023 12:51
CELL106
SW 6020B
12/11/2023 17:02
MHALL3
SW 6020B
12/11/2023 17:02
MHALL3
SW 6020E
12/11/2023 17:02
MHALL3
SW 6020E
12/11/2023 17:02
MHALL3
SW 6020B
12/11/2023 17:02
MHALL3
SW 6020B
12/08/2023 21:48
MHALL3
SW 6020B
12/08/2023 21:48
MHALL3
SW 6020E
12/08/2023 21:48
MHALL3
SW 6020B
12/08/2023 21:48
MHALL3
SW 6020E
12/08/2023 21:48
MHALL3
SW 6020B
12/08/2023 21:48
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23110327
Site: MNS LEACHATE POND
Collection Date: 12/04/2023 11:10 AM
Page 17 of 148
Sample #: 2023028561
Loc code: MNS LEACHATE POND Matrix: GW RCRA
Analyte Result
Units Qualifiers
RDL
MDL
DF
TOTAL ALKALINITY - Q23120156
Alkalinity, Bicarbonate 313
mg/L
5
1.7
1
INORGANIC IONS BY IC - Q23120075
Chloride 52
mg/L
1
0.0154
10
Sulfate 29
mg/L
1
0.0428
10
MERCURY (COLD VAPOR) IN WATER - Q23120112
Mercury (Hg) 0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q23120084
Barium (Ba) 0.105
mg/L
0.005
0.002
1
Calcium (Ca) 99.5
mg/L
0.05
0.012
1
Magnesium (Mg) 17.6
mg/L
0.02
0.008
1
Potassium (K) 12.8
mg/L
0.1
0.031
1
Sodium (Na) 53.5
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q23120101
Arsenic (As) 0.249 J
ug/L
1
0.111
1
Cadmium (Cd) 0.032 U
ug/L
1
0.032
1
Chromium (Cr) 0.185 U
ug/L
1
0.185
1
Lead (Pb) 0.037 U
ug/L
1
0.037
1
Selenium (Se) 0.269 J
ug/L
1
0.193
1
Silver (Ag) 0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by a Vendor Laboratory
- (Analysis Performed
by Pace Laboratories)
Vendor Parameter Complete
TOTAL PETROLEUM HYDROCARBONS - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Method Analysis Date/Time Analyst
SM 2320B-2011 12/11/2023 13:58 CELL106
EPA 9056A
12/07/2023 12:51
BGN9034
EPA 9056A
12/07/2023 12:51
BGN9034
EPA 7470A
12/12/2023 11:25
SNEGLIA
SW 601OD
12/12/2023 12:55
CELL106
SW 601OD
12/12/2023 12:55
CELL106
SW 601OD
12/12/2023 12:55
CELL106
SW 601OD
12/12/2023 12:55
CELL106
SW 601OD
12/12/2023 12:55
CELL106
SW 6020B
12/08/2023 21:57
MHALL3
SW 6020B
12/08/2023 21:57
MHALL3
SW 6020B
12/08/2023 21:57
MHALL3
SW 6020E
12/08/2023 21:57
MHALL3
SW 6020B
12/08/2023 21:57
MHALL3
SW 6020E
12/08/2023 21:57
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23110327
Site: MNS FB-20231204-1030 Field Blank
Collection Date: 12/04/2023 10:30 AM Loc code: MNS QA
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q23120119
Total Alkalinity as CaCO3 1.7 U mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q23120075
Chloride
0.04 J
mg/L
0.1
0.0154
1
Sulfate
0.0428 U
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q23120112
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q23120084
Barium (Ba)
0.002 U
mg/L
0.005
0.002
1
Calcium (Ca)
0.012 U
mg/L
0.05
0.012
1
Magnesium (Mg)
0.008 U
mg/L
0.02
0.008
1
Potassium (K)
0.031 U
mg/L
0.1
0.031
1
Sodium (Na)
0.017 U
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q23120101
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
Lead (Pb)
0.037 U
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed
by Pace Laboratories)
Vendor Parameter
Complete
TOTAL PETROLEUM HYDROCARBONS - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 18 of 148
Sample #: 2023028562
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320134d 12/08/2023 12:34 CELL106
EPA 9056A
12/07/2023 13:06
BGN9034
EPA 9056A
12/07/2023 13:06
BGN9034
EPA 7470A
12/12/2023 11:28
SNEGLIA
SW 601OD
12/12/2023 12:59
CELL106
SW 601OD
12/12/2023 12:59
CELL106
SW 601OD
12/12/2023 12:59
CELL106
SW 601OD
12/12/2023 12:59
CELL106
SW 601OD
12/12/2023 12:59
CELL106
SW 6020B
12/08/2023 22:06
MHALL3
SW 6020B
12/08/2023 22:06
MHALL3
SW 6020E
12/08/2023 22:06
MHALL3
SW 6020B
12/08/2023 22:06
MHALL3
SW 6020E
12/08/2023 22:06
MHALL3
SW 6020B
12/08/2023 22:06
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23110327
Site: MNS FB-20231205-1400 Field Blank
Collection Date: 12/05/2023 02:00 PM Loc code: MNS QA
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q23120119
Total Alkalinity as CaCO3 1.7 U mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q23120075
Chloride
0.04 J
mg/L
0.1
0.0154
1
Sulfate
0.0428 U
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q23120112
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q23120084
Barium (Ba)
0.002 U
mg/L
0.005
0.002
1
Calcium (Ca)
0.012 U
mg/L
0.05
0.012
1
Magnesium (Mg)
0.008 U
mg/L
0.02
0.008
1
Potassium (K)
0.031 U
mg/L
0.1
0.031
1
Sodium (Na)
0.017 U
mg/L
0.05
0.017
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q23120101
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
Lead (Pb)
0.037 U
ug/L
1
0.037
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed
by Pace Laboratories)
Vendor Parameter
Complete
TOTAL PETROLEUM HYDROCARBONS - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Page 19 of 148
Sample #: 2023028563
Matrix: GW RCRA
Method Analysis Date/Time Analyst
SM 2320134d 12/08/2023 12:40 CELL106
EPA 9056A
12/07/2023 13:22
BGN9034
EPA 9056A
12/07/2023 13:22
BGN9034
EPA 7470A
12/12/2023 11:35
SNEGLIA
SW 601OD
12/12/2023 13:03
CELL106
SW 601OD
12/12/2023 13:03
CELL106
SW 601OD
12/12/2023 13:03
CELL106
SW 601OD
12/12/2023 13:03
CELL106
SW 601OD
12/12/2023 13:03
CELL106
SW 6020B
12/08/2023 22:15
MHALL3
SW 6020B
12/08/2023 22:15
MHALL3
SW 6020E
12/08/2023 22:15
MHALL3
SW 6020B
12/08/2023 22:15
MHALL3
SW 6020E
12/08/2023 22:15
MHALL3
SW 6020B
12/08/2023 22:15
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23110327
Site: MNS_TB-20231204-0800 Trip Blank
Collection Date: 12/04/2023 08:00 AM Loc code: MNS TB
Analyte Result Units Qualifiers RDL MDL DF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 20 of 148
Sample #: 2023028564
Matrix: GW RCRA
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis Page 21 of 148
This report shall not be reproduced, except in full.
Order # J23110327
Site: MNS_FD-20231204-1 Duplicate Sample #: 2023028565
Collection Date: 12/04/2023 Loc code: MNS FD Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
LOW LEVEL ALKALINITY (FIXED END POINT) - Q23120119
Total Alkalinity as CaCO3 49.8 mg/L 5 1.7 1 SM 2320134d 12/08/2023 12:45 CELLI06
(CaCO3)
INORGANIC IONS BY IC - Q23120075
Chloride
2.0
mg/L
0.1
0.0154
1
EPA 9056A
12/07/2023 13:38
BGN9034
Sulfate
1.2
mg/L
0.1
0.0428
1
EPA 9056A
12/07/2023 13:38
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q23120112
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
12/12/2023 11:42
SNEGLIA
TOTAL RECOVERABLE METALS BY ICP - Q23120084
Barium (Ba)
0.032
mg/L
0.005
0.002
1
SW 601OD
12/12/2023 13:07
CELLI06
Calcium (Ca)
12.0
mg/L
0.05
0.012
1
SW 601OD
12/12/2023 13:07
CELLI06
Magnesium (Mg)
3.75
mg/L
0.02
0.008
1
SW 601OD
12/12/2023 13:07
CELLI06
Potassium (K)
1.43
mg/L
0.1
0.031
1
SW 601OD
12/12/2023 13:07
CELLI06
Sodium (Na)
4.91
mg/L
0.05
0.017
1
SW 601OD
12/12/2023 13:07
CELLI06
TOTAL RECOVERABLE METALS BY ICP-MS - Q23120101
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
12/08/2023 22:25
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
12/08/2023 22:25
MHALL3
Chromium (Cr)
0.496 J
ug/L
1
0.185
1
SW 6020E
12/08/2023 22:25
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
12/08/2023 22:25
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020E
12/08/2023 22:25
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
12/08/2023 22:25
MHALL3
Miscellaneous Tests by
a Vendor Laboratory
- (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
TOTAL PETROLEUM HYDROCARBONS - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an estimate.

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23110327
Level II QC Summary
Q23120156 ALK CarbBicarb TOTAL ALKALINITY
Page 22 of 148
Duplicate # 1 Parent Sample: J23120189 -- 2023030462
Parameter Measured Final Units Dil MDL RPD Qualifier
Alkalinity, Bicarbonate 38.2 mg/L 1 1.7 1.15

Certificate of Laboratory Analysis Page 23 of 148
This report shall not be reproduced, except in full.
Order # J23110327
Level II QC Summary
Q23120173 ALK FIX4.5 ALKALINITY (FIXED END POINT 4.5)
Duplicate # I
Parameter Measured Final
Total Alkalinity as CaCO3 54.1
LCS # I
Parameter Measured Final
Total Alkalinity as CaCO3 29.5
Parent Sample: J23110327 -- 2023028553
Units Dil MDL RPD
mg/L 1 1.7 2.46
(CaCO3)
Units Dil MDL Spike % Recovery LCL UCL
mg/L 1 1.7 29 102 85 115
(CaCO3)
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 24 of 148
This report shall not be reproduced, except in full.
Order # J23110327
Level II QC Summary
Q23120119 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Duplicate # 1
Parent Sample:
J23110327 -- 2023028548
Parameter Measured
Final
Units
Dil
MDL
RPD
Total Alkalinity as CaCO3
4.49
mg/L
1
1.7
4.36
Duplicate # 2
Parent Sample:
J23110327 -- 2023028549
Parameter Measured
Final
Units
Dil
MDL
RPD
Total Alkalinity as CaCO3
21.7
mg/L
1
1.7
0.601
LCS # 1
Parameter Measured
Final
Units
Dil
MDL
S ike % Recovery
LCL UCL
Total Alkalinity as CaCO3
26.6
mg/L
1
1.7
29 91.8
85 115
(CaCO3)
LCS # 2
Parameter Measured Final Units Dil MDL Spike % Recovery LCL UCL
Total Alkalinity as CaCO3 26.5 mg/L 1 1.7 29 91.4 85 115
(CaCO3)
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 25 of 148
This report shall not be reproduced, except in full.
Order # J23110327
Level II QC Summary
Q23120075 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Sulfate
0.002
0.002
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Chloride
5.09
5.09
mg/L
1
0.0154
5
102
80
120
Sulfate
5.15
5.15
mg/L
1
0.0428
5
103
80
120
MS # 1
Parent Sample:
J23110327 -- 2023028548
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Chloride
6.11
6.11
mg/L
1
0.0154
5
99.2
80
120
Sulfate
5.65
5.65
mg/L
1
0.0428
5
100
80
120
MSD # 1
Parent Sample:
J23110327 -- 2023028548
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Chloride
6.08
6.08
mg/L
1
0.0154
5
98.7
80
120 0.445
Sulfate
5.64
5.64
mg/L
1
0.0428
5
99.8
80
120 0.12
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 26 of 148
This report shall not be reproduced, except in full.
Order # J23110327
Level II QC Summary
Q23120112 HG 7470 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.01
-0.01
ug/L
1
0.01
0.05
< MDL
Blank # 2
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.001
0.001
ug/L
1
0.01
0.05
< MDL
Blank # 3
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.001
0.001
ug/L
1
0.01
0.05
< MDL
Blank # 4
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.008
-0.008
ug/L
1
0.01
0.05
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery LCL UCL
Qualifier
Mercury (Hg)
1.84
1.84
ug/L
1
0.01
2
91.9 85 115
LCS # 2
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.86
1.86
ug/L
1
0.01
2
92.8
85 115
MS # 1
Parent Sample:
J23120159 -- 2023030356
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.02
1.02
ug/L
1
0.01
1
102
75 125
MSD # 1
Parent Sample:
J23120159 -- 2023030356
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL UCL RPD
Qualifier
Mercury (Hg)
1.02
1.02
ug/L
1
0.01
1
102
75 125 0.0978
MS # 2
Parent Sample:
J23120164 -- 2023030366
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1
1
ug/L
1
0.01
1
100
75 125
MSD # 2
Parent Sample:
J23120164 -- 2023030366
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.991
0.991
ug/L
1
0.01
1
99.1
75 125 0.904
MS # 3
Parent Sample:
J23110327 -- 2023028553
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL UCL
Qualifier
Mercury (Hg)
1.05
1.05
ug/L
1
0.01
1
105
75 125

Certificate of Laboratory Analysis Page 27 of 148
This report shall not be reproduced, except in full.
Order # J23110327
Level II QC Summary
Q23120112 HG 7470 MERCURY (COLD VAPOR) IN WATER
MSD # 3
Parent Sample:
J23110327
-- 2023028553
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD Qualifier
Mercury (Hg)
1.04
1.04
ug/L
1
0.01
1
104
75
125 1.05
MS # 4
Parent Sample:
J23110327
-- 2023028563
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL Qualifier
Mercury (Hg)
1.03
1.03
ug/L
1
0.01
1
103
75
125
MSD # 4
Parent Sample:
J23110327
-- 2023028563
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD Qualifier
Mercury (Hg)
1.06
1.06
ug/L
1
0.01
1
106
75
125 3.64

Certificate of Laboratory Analysis Page 28 of 148
This report shall not be reproduced, except in full.
Order # J23110327
Level II QC Summary
Q23120082 ICP_DIS_TRM TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
-0.000359
-0.000359
mg/L
1
0.002
0.005
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
4.96
4.96
mg/L
1
0.002
5
99.2
80
120
MS # 1
Parent Sample:
J23110327 -- 2023028559
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
5.04
5.04
mg/L
1
0.002
5
100
70
130
MSD # 1
Parent Sample:
J23110327 -- 2023028559
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Barium (Ba)
5.04
5.04
mg/L
1
0.002
5
100
70
130 0.0198
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 29 of 148
This report shall not be reproduced, except in full.
Order # J23110327
Level II QC Summary
Q23120084 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
-0.000032
-0.000032
mg/L
1
0.002
0.005
< MDL
Calcium (Ca)
0.00238
0.00238
mg/L
1
0.012
0.05
< MDL
Magnesium (Mg)
-0.00132
-0.00132
mg/L
1
0.008
0.02
< MDL
Potassium (K)
-0.00599
-0.00599
mg/L
1
0.031
0.1
< MDL
Sodium (Na)
-0.0143
-0.0143
mg/L
1
0.017
0.05
< MDL
LCS # 1
MS # 1
Parameter
Measured
Final
Units
Barium (Ba)
5.11
5.11
mg/L
Calcium (Ca)
5.17
5.17
mg/L
Magnesium (Mg)
5.14
5.14
mg/L
Potassium (K)
5.18
5.18
mg/L
Sodium (Na)
5.09
5.09
mg/L
Parameter
Measured
Final
Units
Barium (Ba)
5.19
5.19
mg/L
Calcium (Ca)
6.14
6.14
mg/L
Magnesium (Mg)
6.06
6.06
mg/L
Potassium (K)
6.02
6.02
mg/L
Sodium (Na)
6.07
6.07
mg/L
MSD # 1
Parameter
Measured
Final
Units
Barium (Ba)
5.08
5.08
mg/L
Calcium (Ca)
6.01
6.01
mg/L
Magnesium (Mg)
5.93
5.93
mg/L
Potassium (K)
5.9
5.9
mg/L
Sodium (Na)
5.95
5.95
mg/L
Dil
MDL
Spike
% Recovery
LCL
UCL
1
0.002
5
102
80
120
1
0.012
5
103
80
120
1
0.008
5
103
80
120
1
0.031
5
104
80
120
1
0.017
5
102
80
120
Parent Sample:
J23110327
-- 2023028548
Dil
MDL
Spike
% Recover v
LCL
UCL
1
0.002
5
103
75
125
1
0.012
5
105
75
125
1
0.008
5
105
75
125
1
0.031
5
105
75
125
1
0.017
5
104
75
125
Parent Sample:
J23110327
-- 2023028548
Dil
MDL
Spike
% Recover v
LCL
UCL
RPD
1
0.002
5
101
75
125
2.14
1
0.012
5
103
75
125
2.14
1
0.008
5
102
75
125
2.17
1
0.031
5
103
75
125
2.01
1
0.017
5
102
75
125
2
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 30 of 148
This report shall not be reproduced, except in full.
Order # J23110327
Level II QC Summary
Q23120094 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Blank # 1
LCS # 1
MS # 1
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Arsenic (As)
-0.014
-0.014
ug/L
1
0.111
1
< MDL
Cadmium (Cd)
-0.002
-0.002
ug/L
1
0.032
1
< MDL
Chromium (Cr)
0.085
0.085
ug/L
1
0.185
1
< MDL
Lead (Pb)
-0.003
-0.003
ug/L
1
0.037
1
< MDL
Silver (Ag)
0.002
0.002
ug/L
1
0.035
1
< MDL
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Arsenic (As)
49.5
49.5
ug/L
1
0.111
50
99
80
120
Cadmium (Cd)
49.9
49.9
ug/L
1
0.032
50
99.9
80
120
Chromium (Cr)
51.4
51.4
ug/L
1
0.185
50
103
80
120
Lead (Pb)
51.6
51.6
ug/L
1
0.037
50
103
80
120
Silver (Ag)
50.4
50.4
ug/L
1
0.035
50
101
80
120
Parent Sample:
J23110327 -- 2023028560
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
Arsenic (As)
48.9
48.9
ug/L
1
0.111
50
97.4
75
125
Cadmium (Cd)
50.1
50.1
ug/L
1
0.032
50
100
75
125
Chromium (Cr)
51.4
51.4
ug/L
1
0.185
50
102
75
125
Lead (Pb)
51.4
51.4
ug/L
1
0.037
50
103
75
125
Silver (Ag)
49.8
49.8
ug/L
1
0.035
50
99.6
75
125
Parent Sample:
J23110327 -- 2023028560
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
RPD
Arsenic (As)
48.7
48.7
ug/L
1
0.111
50
97.1
75
125
0.364
Cadmium (Cd)
49.7
49.7
ug/L
1
0.032
50
99.4
75
125
0.732
Chromium (Cr)
51.1
51.1
ug/L
1
0.185
50
102
75
125
0.646
Lead (Pb)
51
51
ug/L
1
0.037
50
102
75
125
0.934
Silver (Ag)
49.2
49.2
ug/L
1
0.035
50
98.4
75
125
1.19
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 31 of 148
This report shall not be reproduced, except in full.
Order # J23110327
Level II QC Summary
Q23120101 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
LCS # 1
MS # 1
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Arsenic (As)
0.003
0.003
ug/L
1
0.111
1
< MDL
Cadmium (Cd)
0.09
0.09
ug/L
1
0.032
1
> MDL
Chromium (Cr)
0.005
0.005
ug/L
1
0.185
1
< MDL
Lead (Pb)
0.058
0.058
ug/L
1
0.037
1
> MDL
Selenium (Se)
-0.001
-0.001
ug/L
1
0.193
1
< MDL
Silver (Ag)
0.002
0.002
ug/L
1
0.035
1
< MDL
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Arsenic (As)
47.7
47.7
ug/L
1
0.111
50
95.3
80
120
Cadmium (Cd)
48.6
48.6
ug/L
1
0.032
50
97.2
80
120
Chromium (Cr)
49.8
49.8
ug/L
1
0.185
50
99.6
80
120
Lead (Pb)
49.9
49.9
ug/L
1
0.037
50
99.8
80
120
Selenium (Se)
46.5
46.5
ug/L
1
0.193
50
93
80
120
Silver (Ag)
49.1
49.1
ug/L
1
0.035
50
98.2
80
120
Parent Sample:
J23110327 -- 2023028549
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Arsenic (As)
47.6
47.6
ug/L
1
0.111
50
94.6
75
125
Cadmium (Cd)
49.2
49.2
ug/L
1
0.032
50
98.3
75
125
Chromium (Cr)
51
51
ug/L
1
0.185
50
101
75
125
Lead (Pb)
50
50
ug/L
1
0.037
50
99.8
75
125
Selenium (Se)
45.9
45.9
ug/L
1
0.193
50
91.7
75
125
Silver (Ag)
49.1
49.1
ug/L
1
0.035
50
97.8
75
125
Parent Sample:
J23110327 -- 2023028549
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Arsenic (As)
48.2
48.2
ug/L
1
0.111
50
95.8
75
125
1.34
Cadmium (Cd)
49.2
49.2
ug/L
1
0.032
50
98.5
75
125
0.15
Chromium (Cr)
51.1
51.1
ug/L
1
0.185
50
101
75
125
0.0396
Lead (Pb)
50.1
50.1
ug/L
1
0.037
50
100
75
125
0.252
Selenium (Se)
46.4
46.4
ug/L
1
0.193
50
92.7
75
125
1.04
Silver (Ag)
49.1
49.1
ug/L
1
0.035
50
97.8
75
125
0.0205
Qualifier
Qualifier
Qualifier
Qualifier

ace
Pace Analytical Services, LLC
P989OgrWY449e. Suite 100
Huntersville, NC 28078
[phone]
December 28, 2023
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on December 06, 2023. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
Revised Report. The report has been revised to include J flags and MDLs. The time of collection for MW-8 (92702270-
007) has also been corrected.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lord Patton
[e-mail]
828-417-6055
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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Pace Analytical Services, LLC
P989OgrWY449e. Suite 100
Huntersville, NC 28078
[phone]
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
VirginiaNELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 2 of 60

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Pace Analytical Services, LLC
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[phone]
SAMPLE SUMMARY
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92702270001
MW-5R
Water
12/04/23 14:00
12/06/23 14:00
92702270002
MW-5A
Water
12/04/2312:00
12/06/23 14:00
92702270003
MW-6
Water
12/04/2315:50
12/06/23 14:00
92702270004
MW-6A
Water
12/04/2315:30
12/06/23 14:00
92702270005
MW-7R
Water
12/05/2313:45
12/06/23 14:00
92702270006
MW-7A
Water
12/05/2313:05
12/06/23 14:00
92702270007
MW-8
Water
12/04/23 09:30
12/06/23 14:00
92702270008
MW-8A
Water
12/04/2310:05
12/06/23 14:00
92702270009
MW-9
Water
12/05/2310:30
12/06/23 14:00
92702270010
MW-9A
Water
12/05/2310:00
12/06/23 14:00
92702270011
MW-10A
Water
12/04/2314:50
12/06/23 14:00
92702270012
SW-1
Water
12/05/2314:45
12/06/23 14:00
92702270013
SW-2
Water
12/05/2311:40
12/06/23 14:00
92702270014
LEACHATE POND
Water
12/04/23 11:10
12/06/23 14:00
92702270015
MNS FB-20231204-1030
Water
12/04/2310:30
12/06/23 14:00
92702270016
MNS FB-20231205-1400
Water
12/05/2314:00
12/06/23 14:00
92702270017
MNS TB-20241204-0800
Water
12/04/23 08:00
12/06/23 14:00
92702270018
MNS FD-20231204-1
Water
12/04/23 00:00
12/06/23 14:00
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 3 of 60

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Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J23110327 MNS Landfill
92702270
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92702270001
MW-5R
EPA8260D
JJK
50
PASI-C
92702270002
MW-5A
EPA8260D
JJK
50
PASI-C
92702270003
MW-6
EPA8260D
JJK
50
PASI-C
92702270004
MW-6A
EPA8260D
JJK
50
PASI-C
92702270005
MW-7R
EPA8260D
JJK
50
PASI-C
92702270006
MW-7A
EPA8260D
JJK
50
PASI-C
92702270007
MW-8
EPA8260D
JJK
50
PASI-C
92702270008
MW-8A
EPA8260D
JJK
50
PASI-C
92702270009
MW-9
EPA8260D
JJK
50
PASI-C
92702270010
MW-9A
EPA8260D
JJK
50
PASI-C
92702270011
MW-10A
EPA8260D
JJK
50
PASI-C
92702270012
SW-1
EPA8260D
JJK
50
PASI-C
92702270013
SW-2
EPA8260D
JJK
50
PASI-C
92702270014
LEACHATE POND
EPA8260D
JJK
50
PASI-C
92702270015
MNS FB-20231204-1030
EPA8260D
JJK
50
PASI-C
92702270016
MNS FB-20231205-1400
EPA8260D
JJK
50
PASI-C
92702270017
MNS TB-20241204-0800
EPA8260D
JJK
50
PASI-C
92702270018
MNS FD-20231204-1
EPA8260D
JJK
50
PASI-C
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 4 of 60

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Pace Analytical Services, LLC
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SUMMARY OF DETECTION
Project:
Pace Project No.:
J23110327 MNS Landfill
92702270
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92702270015
MNS FB-20231204-1030
EPA 8260D
Acetone
28.5
ug/L
25.0
12/08/23 14:08
EPA 8260D
2-Butanone (MEK)
4.9J
ug/L
5.0
12/08/23 14:08
EPA 8260D
2-Hexanone
0.76J
ug/L
5.0
12/08/23 14:08
92702270016
MNS FB-20231205-1400
EPA 8260D
Acetone
28.9
ug/L
25.0
12/08/23 14:26
EPA 8260D
2-Butanone (MEK)
4.8J
ug/L
5.0
12/08/23 14:26
EPA 8260D
2-Hexanone
0.78J
ug/L
5.0
12/08/23 14:26
92702270017
MNS TB-20241204-0800
EPA 8260D
Acetone
28.8
ug/L
25.0
12/08/23 14:44
EPA 8260D
2-Butanone (MEK)
5.1
ug/L
5.0
12/08/23 14:44
EPA 8260D
2-Hexanone
0.71 J
ug/L
5.0
12/08/23 14:44
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 5 of 60

ace
Pace Analytical Services, LLC
POWWOWe. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Method: EPA 8260D
Description: 8260D MSV Low Level
Client: Duke Energy
Date: December 28, 2023
General Information:
18 samples were analyzed for EPA 8260D by Pace Analytical Services Charlotte. All samples were received in acceptable condition
with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end
of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
QC Batch: 818019
v2: The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated
samples and the sensitivity of the instrument was verified with a reporting limit check standard.
• BLANK (Lab ID: 4234350)
• Bromomethane
• Vinyl acetate
• MW-5A (Lab ID: 92702270002)
• Bromomethane
• Vinyl acetate
• MW-5R (Lab ID: 92702270001)
• Bromomethane
• Vinyl acetate
• MW-6 (Lab ID: 92702270003)
• Bromomethane
• Vinyl acetate
• MW-6A (Lab ID: 92702270004)
• Bromomethane
• Vinyl acetate
• MW-7A (Lab ID: 92702270006)
• Bromomethane
• Vinyl acetate
• MW-7R (Lab ID: 92702270005)
• Bromomethane
• Vinyl acetate
• MW-8 (Lab ID: 92702270007)
• Bromomethane
• Vinyl acetate
• MW-8A (Lab ID: 92702270008)
• Bromomethane
Vinyl acetate
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 6 of 60

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Pace Analytical Services, LLC
POWWOWe. Suite 100
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[phone]
PROJECT NARRATIVE
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Method: EPA 8260D
Description: 8260D MSV Low Level
Client: Duke Energy
Date: December 28, 2023
QC Batch: 818019
v3: The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated
samples may have low bias.
• LCS (Lab ID: 4234351)
• Bromomethane
• Vinyl acetate
QC Batch: 818022
v2: The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated
samples and the sensitivity of the instrument was verified with a reporting limit check standard.
• BLANK (Lab ID: 4234436)
• Bromomethane
• lodomethane
• LEACHATE POND (Lab ID: 92702270014)
• Bromomethane
• lodomethane
• MNS_FB-20231204-1030 (Lab ID: 92702270015)
• Bromomethane
• lodomethane
• MNS_FB-20231205-1400 (Lab ID: 92702270016)
• Bromomethane
• lodomethane
• MNS_FD-20231204-1 (Lab ID: 92702270018)
• Bromomethane
• lodomethane
• MNS_TB-20241204-0800 (Lab ID: 92702270017)
• Bromomethane
• lodomethane
• MW-10A (Lab ID: 92702270011)
• Bromomethane
• lodomethane
• MW-9 (Lab ID: 92702270009)
• Bromomethane
• lodomethane
• MW-9A (Lab ID: 92702270010)
• Bromomethane
• lodomethane
• SW-1 (Lab ID: 92702270012)
• Bromomethane
• lodomethane
• SW-2 (Lab ID: 92702270013)
• Bromomethane
• lodomethane
v3: The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated
samples may have low bias.
• LCS (Lab ID: 4234437)
• Bromomethane
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 7 of 60

ace
Pace Analytical Services, LLC
P989'q irfUfe. Suite 100
�J Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Method: EPA 8260D
Description: 8260D MSV Low Level
Client: Duke Energy
Date: December 28, 2023
QC Batch: 818022
v3: The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated
samples may have low bias.
• lodomethane
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: 818022
CO: Result confirmed by second analysis.
• MNS_FB-20231204-1030 (Lab ID: 92702270015)
• 4-Bromofluorobenzene (S)
• MNS_FB-20231205-1400 (Lab ID: 92702270016)
• 4-Bromofluorobenzene (S)
• MNS_TB-20241204-0800 (Lab ID: 92702270017)
• 4-Bromofluorobenzene (S)
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 8 of 60

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P98904br6f0We. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MW-5R Lab ID: 92702270001 Collected: 12/04/23 14:00 Received: 12/06/23 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
5.1
1
12/08/23 03:38
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
12/08/23 03:38
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
12/08/23 03:38
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
12/08/23 03:38
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
12/08/23 03:38
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
12/08/23 03:38
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
12/08/23 03:38
74-83-9 v2
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
12/08/23 03:38
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
12/08/23 03:38
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
12/08/23 03:38
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
12/08/23 03:38
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
12/08/23 03:38
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
12/08/23 03:38
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
12/08/23 03:38
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
12/08/23 03:38
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
12/08/23 03:38
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
12/08/23 03:38
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
12/08/23 03:38
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
12/08/23 03:38
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
12/08/23 03:38
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
12/08/23 03:38
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
12/08/23 03:38
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
12/08/23 03:38
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
12/08/23 03:38
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
12/08/23 03:38
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
12/08/23 03:38
156-60-5
1,2-Dichloropropene
ND
ug/L
1.0
0.36
1
12/08/23 03:38
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
12/08/23 03:38
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
12/08/23 03:38
10061-02-6
Ethylbenzene
ND
ug/L
1.0
0.30
1
12/08/23 03:38
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
12/08/23 03:38
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
12/08/23 03:38
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
12/08/23 03:38
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
12/08/23 03:38
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
12/08/23 03:38
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
12/08/23 03:38
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
12/08/23 03:38
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
12/08/23 03:38
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
12/08/23 03:38
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
12/08/23 03:38
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
12/08/23 03:38
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
12/08/23 03:38
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
12/08/23 03:38
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
12/08/23 03:38
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
12/08/23 03:38
108-05-4 v2
REPORT OF LABORATORY ANALYSIS
This report
shall not be reproduced,
except in full,
Date: 12/28/2023 02:27 PM
without the written consent of Pace
Analytical Services, LLC.
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Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MW-5R
Lab ID: 92702270001 Collected:
12/04/23 14:00
Received: 12/06/23 14:00 Matrix: Water
Parameters
Results Units PQL
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Vinyl chloride
ND ug/L 1.0
0.39 1
12/08/23 03:38
75-01-4
Xylene (Total)
ND ug/L 1.0
0.34 1
12/08/23 03:38
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99 % 70-130
1
12/08/23 03:38
460-00-4
1,2-Dichloroethane-d4 (S)
94 % 70-130
1
12/08/23 03:38
17060-07-0
Toluene-d8 (S)
103 % 70-130
1
12/08/23 03:38
2037-26-5
Date: 12/28/2023 02:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 10 of 60

ace
Pace Analytical Services, LLC
P989041f�1 eUWe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MW-5A Lab ID: 92702270002 Collected: 12/04/23 12:00 Received: 12/06/23 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
5.1
1
12/08/23 03:56
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
12/08/23 03:56
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
12/08/23 03:56
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
12/08/23 03:56
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
12/08/23 03:56
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
12/08/23 03:56
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
12/08/23 03:56
74-83-9 v2
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
12/08/23 03:56
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
12/08/23 03:56
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
12/08/23 03:56
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
12/08/23 03:56
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
12/08/23 03:56
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
12/08/23 03:56
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
12/08/23 03:56
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
12/08/23 03:56
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
12/08/23 03:56
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
12/08/23 03:56
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
12/08/23 03:56
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
12/08/23 03:56
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
12/08/23 03:56
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
12/08/23 03:56
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
12/08/23 03:56
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
12/08/23 03:56
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
12/08/23 03:56
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
12/08/23 03:56
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
12/08/23 03:56
156-60-5
1,2-Dichloropropene
ND
ug/L
1.0
0.36
1
12/08/23 03:56
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
12/08/23 03:56
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
12/08/23 03:56
10061-02-6
Ethylbenzene
ND
ug/L
1.0
0.30
1
12/08/23 03:56
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
12/08/23 03:56
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
12/08/23 03:56
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
12/08/23 03:56
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
12/08/23 03:56
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
12/08/23 03:56
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
12/08/23 03:56
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
12/08/23 03:56
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
12/08/23 03:56
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
12/08/23 03:56
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
12/08/23 03:56
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
12/08/23 03:56
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
12/08/23 03:56
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
12/08/23 03:56
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
12/08/23 03:56
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
12/08/23 03:56
108-05-4 v2
REPORT OF LABORATORY ANALYSIS
This report
shall not be reproduced,
except in full,
Date: 12/28/2023 02:27 PM
without the written consent of Pace
Analytical Services, LLC.
Page 11 of 60

ace
Pace Analytical Services, LLC
P989041 WeOWie. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MW-5A
Lab ID: 92702270002 Collected:
12/04/23 12:00
Received: 12/06/23 14:00 Matrix: Water
Parameters
Results Units PQL
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Vinyl chloride
ND ug/L 1.0
0.39 1
12/08/23 03:56
75-01-4
Xylene (Total)
ND ug/L 1.0
0.34 1
12/08/23 03:56
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
97 % 70-130
1
12/08/23 03:56
460-00-4
1,2-Dichloroethane-d4 (S)
91 % 70-130
1
12/08/23 03:56
17060-07-0
Toluene-d8 (S)
100 % 70-130
1
12/08/23 03:56
2037-26-5
Date: 12/28/2023 02:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 60

ace
Pace Analytical Services, LLC
P98904 'irWOWe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MW-6 Lab ID: 92702270003 Collected: 12/04/23 15:50 Received: 12/06/23 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
5.1
1
12/08/23 04:15
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
12/08/23 04:15
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
12/08/23 04:15
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
12/08/23 04:15
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
12/08/23 04:15
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
12/08/23 04:15
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
12/08/23 04:15
74-83-9 v2
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
12/08/23 04:15
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
12/08/23 04:15
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
12/08/23 04:15
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
12/08/23 04:15
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
12/08/23 04:15
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
12/08/23 04:15
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
12/08/23 04:15
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
12/08/23 04:15
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
12/08/23 04:15
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
12/08/23 04:15
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
12/08/23 04:15
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
12/08/23 04:15
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
12/08/23 04:15
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
12/08/23 04:15
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
12/08/23 04:15
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
12/08/23 04:15
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
12/08/23 04:15
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
12/08/23 04:15
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
12/08/23 04:15
156-60-5
1,2-Dichloropropene
ND
ug/L
1.0
0.36
1
12/08/23 04:15
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
12/08/23 04:15
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
12/08/23 04:15
10061-02-6
Ethylbenzene
ND
ug/L
1.0
0.30
1
12/08/23 04:15
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
12/08/23 04:15
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
12/08/23 04:15
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
12/08/23 04:15
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
12/08/23 04:15
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
12/08/23 04:15
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
12/08/23 04:15
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
12/08/23 04:15
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
12/08/23 04:15
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
12/08/23 04:15
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
12/08/23 04:15
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
12/08/23 04:15
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
12/08/23 04:15
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
12/08/23 04:15
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
12/08/23 04:15
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
12/08/23 04:15
108-05-4 v2
REPORT OF LABORATORY ANALYSIS
This report
shall not be reproduced,
except in full,
Date: 12/28/2023 02:27 PM
without the written consent of Pace
Analytical Services, LLC.
Page 13 of 60

ace
Pace Analytical Services, LLC
P98904"UWe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MW-6
Lab ID: 92702270003 Collected:
12/04/23 15:50
Received: 12/06/23 14:00 Matrix: Water
Parameters
Results Units PQL
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Vinyl chloride
ND ug/L 1.0
0.39 1
12/08/23 04:15
75-01-4
Xylene (Total)
ND ug/L 1.0
0.34 1
12/08/23 04:15
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99 % 70-130
1
12/08/23 04:15
460-00-4
1,2-Dichloroethane-d4 (S)
90 % 70-130
1
12/08/23 04:15
17060-07-0
Toluene-d8 (S)
103 % 70-130
1
12/08/23 04:15
2037-26-5
Date: 12/28/2023 02:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 14 of 60

ace
Pace Analytical Services, LLC
PdaR041 y,iVe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MW-6A Lab ID: 92702270004 Collected: 12/04/23 15:30 Received: 12/06/23 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
5.1
1
12/08/23 04:33
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
12/08/23 04:33
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
12/08/23 04:33
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
12/08/23 04:33
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
12/08/23 04:33
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
12/08/23 04:33
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
12/08/23 04:33
74-83-9 v2
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
12/08/23 04:33
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
12/08/23 04:33
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
12/08/23 04:33
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
12/08/23 04:33
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
12/08/23 04:33
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
12/08/23 04:33
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
12/08/23 04:33
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
12/08/23 04:33
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
12/08/23 04:33
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
12/08/23 04:33
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
12/08/23 04:33
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
12/08/23 04:33
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
12/08/23 04:33
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
12/08/23 04:33
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
12/08/23 04:33
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
12/08/23 04:33
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
12/08/23 04:33
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
12/08/23 04:33
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
12/08/23 04:33
156-60-5
1,2-Dichloropropene
ND
ug/L
1.0
0.36
1
12/08/23 04:33
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
12/08/23 04:33
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
12/08/23 04:33
10061-02-6
Ethylbenzene
ND
ug/L
1.0
0.30
1
12/08/23 04:33
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
12/08/23 04:33
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
12/08/23 04:33
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
12/08/23 04:33
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
12/08/23 04:33
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
12/08/23 04:33
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
12/08/23 04:33
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
12/08/23 04:33
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
12/08/23 04:33
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
12/08/23 04:33
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
12/08/23 04:33
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
12/08/23 04:33
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
12/08/23 04:33
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
12/08/23 04:33
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
12/08/23 04:33
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
12/08/23 04:33
108-05-4 v2
REPORT OF LABORATORY ANALYSIS
This report
shall not be reproduced,
except in full,
Date: 12/28/2023 02:27 PM
without the written consent of Pace
Analytical Services, LLC.
Page 15 of 60

ace
Pace Analytical Services, LLC
P989041 We0Wie. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MW-6A
Lab ID: 92702270004 Collected:
12/04/23 15:30
Received: 12/06/23 14:00 Matrix: Water
Parameters
Results Units PQL
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Vinyl chloride
ND ug/L 1.0
0.39 1
12/08/23 04:33
75-01-4
Xylene (Total)
ND ug/L 1.0
0.34 1
12/08/23 04:33
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
98 % 70-130
1
12/08/23 04:33
460-00-4
1,2-Dichloroethane-d4 (S)
91 % 70-130
1
12/08/23 04:33
17060-07-0
Toluene-d8 (S)
102 % 70-130
1
12/08/23 04:33
2037-26-5
Date: 12/28/2023 02:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 16 of 60

ace
Pace Analytical Services, LLC
P989041 We0Wie. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MW-7R Lab ID: 92702270005 Collected: 12/05/23 13:45 Received: 12/06/23 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
5.1
1
12/08/23 04:51
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
12/08/23 04:51
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
12/08/23 04:51
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
12/08/23 04:51
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
12/08/23 04:51
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
12/08/23 04:51
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
12/08/23 04:51
74-83-9 v2
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
12/08/23 04:51
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
12/08/23 04:51
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
12/08/23 04:51
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
12/08/23 04:51
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
12/08/23 04:51
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
12/08/23 04:51
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
12/08/23 04:51
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
12/08/23 04:51
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
12/08/23 04:51
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
12/08/23 04:51
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
12/08/23 04:51
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
12/08/23 04:51
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
12/08/23 04:51
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
12/08/23 04:51
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
12/08/23 04:51
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
12/08/23 04:51
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
12/08/23 04:51
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
12/08/23 04:51
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
12/08/23 04:51
156-60-5
1,2-Dichloropropene
ND
ug/L
1.0
0.36
1
12/08/23 04:51
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
12/08/23 04:51
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
12/08/23 04:51
10061-02-6
Ethylbenzene
ND
ug/L
1.0
0.30
1
12/08/23 04:51
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
12/08/23 04:51
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
12/08/23 04:51
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
12/08/23 04:51
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
12/08/23 04:51
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
12/08/23 04:51
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
12/08/23 04:51
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
12/08/23 04:51
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
12/08/23 04:51
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
12/08/23 04:51
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
12/08/23 04:51
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
12/08/23 04:51
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
12/08/23 04:51
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
12/08/23 04:51
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
12/08/23 04:51
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
12/08/23 04:51
108-05-4 v2
REPORT OF LABORATORY ANALYSIS
This report
shall not be reproduced,
except in full,
Date: 12/28/2023 02:27 PM
without the written consent of Pace
Analytical Services, LLC.
Page 17 of 60

ace
Pace Analytical Services, LLC
P989041 We0Wie. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MW-7R
Lab ID: 92702270005 Collected:
12/05/23 13:45
Received: 12/06/23 14:00 Matrix: Water
Parameters
Results Units PQL
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Vinyl chloride
ND ug/L 1.0
0.39 1
12/08/23 04:51
75-01-4
Xylene (Total)
ND ug/L 1.0
0.34 1
12/08/23 04:51
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99 % 70-130
1
12/08/23 04:51
460-00-4
1,2-Dichloroethane-d4 (S)
92 % 70-130
1
12/08/23 04:51
17060-07-0
Toluene-d8 (S)
101 % 70-130
1
12/08/23 04:51
2037-26-5
Date: 12/28/2023 02:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 18 of 60

ace
Pace Analytical Services, LLC
PARWWOwie. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MW-7A Lab ID: 92702270006 Collected: 12/05/23 13:05 Received: 12/06/23 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
5.1
1
12/08/23 05:09
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
12/08/23 05:09
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
12/08/23 05:09
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
12/08/23 05:09
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
12/08/23 05:09
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
12/08/23 05:09
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
12/08/23 05:09
74-83-9 v2
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
12/08/23 05:09
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
12/08/23 05:09
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
12/08/23 05:09
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
12/08/23 05:09
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
12/08/23 05:09
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
12/08/23 05:09
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
12/08/23 05:09
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
12/08/23 05:09
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
12/08/23 05:09
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
12/08/23 05:09
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
12/08/23 05:09
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
12/08/23 05:09
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
12/08/23 05:09
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
12/08/23 05:09
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
12/08/23 05:09
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
12/08/23 05:09
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
12/08/23 05:09
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
12/08/23 05:09
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
12/08/23 05:09
156-60-5
1,2-Dichloropropene
ND
ug/L
1.0
0.36
1
12/08/23 05:09
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
12/08/23 05:09
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
12/08/23 05:09
10061-02-6
Ethylbenzene
ND
ug/L
1.0
0.30
1
12/08/23 05:09
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
12/08/23 05:09
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
12/08/23 05:09
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
12/08/23 05:09
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
12/08/23 05:09
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
12/08/23 05:09
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
12/08/23 05:09
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
12/08/23 05:09
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
12/08/23 05:09
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
12/08/23 05:09
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
12/08/23 05:09
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
12/08/23 05:09
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
12/08/23 05:09
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
12/08/23 05:09
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
12/08/23 05:09
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
12/08/23 05:09
108-05-4 v2
REPORT OF LABORATORY ANALYSIS
This report
shall not be reproduced,
except in full,
Date: 12/28/2023 02:27 PM
without the written consent of Pace
Analytical Services, LLC.
Page 19 of 60

ace
Pace Analytical Services, LLC
Pdago, rpy�e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MW-7A
Lab ID: 92702270006 Collected:
12/05/23 13:05
Received: 12/06/23 14:00 Matrix: Water
Parameters
Results Units PQL
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Vinyl chloride
ND ug/L 1.0
0.39 1
12/08/23 05:09
75-01-4
Xylene (Total)
ND ug/L 1.0
0.34 1
12/08/23 05:09
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
97 % 70-130
1
12/08/23 05:09
460-00-4
1,2-Dichloroethane-d4 (S)
93 % 70-130
1
12/08/23 05:09
17060-07-0
Toluene-d8 (S)
102 % 70-130
1
12/08/23 05:09
2037-26-5
Date: 12/28/2023 02:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 20 of 60

ace
Pace Analytical Services, LLC
PAR&WOwe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MW-8 Lab ID: 92702270007 Collected: 12/04/23 09:30 Received: 12/06/23 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
5.1
1
12/08/23 05:27
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
12/08/23 05:27
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
12/08/23 05:27
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
12/08/23 05:27
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
12/08/23 05:27
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
12/08/23 05:27
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
12/08/23 05:27
74-83-9 v2
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
12/08/23 05:27
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
12/08/23 05:27
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
12/08/23 05:27
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
12/08/23 05:27
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
12/08/23 05:27
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
12/08/23 05:27
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
12/08/23 05:27
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
12/08/23 05:27
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
12/08/23 05:27
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
12/08/23 05:27
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
12/08/23 05:27
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
12/08/23 05:27
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
12/08/23 05:27
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
12/08/23 05:27
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
12/08/23 05:27
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
12/08/23 05:27
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
12/08/23 05:27
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
12/08/23 05:27
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
12/08/23 05:27
156-60-5
1,2-Dichloropropene
ND
ug/L
1.0
0.36
1
12/08/23 05:27
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
12/08/23 05:27
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
12/08/23 05:27
10061-02-6
Ethylbenzene
ND
ug/L
1.0
0.30
1
12/08/23 05:27
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
12/08/23 05:27
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
12/08/23 05:27
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
12/08/23 05:27
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
12/08/23 05:27
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
12/08/23 05:27
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
12/08/23 05:27
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
12/08/23 05:27
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
12/08/23 05:27
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
12/08/23 05:27
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
12/08/23 05:27
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
12/08/23 05:27
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
12/08/23 05:27
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
12/08/23 05:27
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
12/08/23 05:27
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
12/08/23 05:27
108-05-4 v2
REPORT OF LABORATORY ANALYSIS
This report
shall not be reproduced,
except in full,
Date: 12/28/2023 02:27 PM
without the written consent of Pace
Analytical Services, LLC.
Page 21 of 60

ace
Pace Analytical Services, LLC
POWWOW e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MW-8
Lab ID: 92702270007 Collected:
12/04/23 09:30
Received: 12/06/23 14:00 Matrix: Water
Parameters
Results Units PQL
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Vinyl chloride
ND ug/L 1.0
0.39 1
12/08/23 05:27
75-01-4
Xylene (Total)
ND ug/L 1.0
0.34 1
12/08/23 05:27
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99 % 70-130
1
12/08/23 05:27
460-00-4
1,2-Dichloroethane-d4 (S)
94 % 70-130
1
12/08/23 05:27
17060-07-0
Toluene-d8 (S)
102 % 70-130
1
12/08/23 05:27
2037-26-5
Date: 12/28/2023 02:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 22 of 60

ace
Pace Analytical Services, LLC
Pdag0Aiirpy,jWe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MW-8A Lab ID: 92702270008 Collected: 12/04/23 10:05 Received: 12/06/23 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
5.1
1
12/08/23 05:46
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
12/08/23 05:46
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
12/08/23 05:46
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
12/08/23 05:46
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
12/08/23 05:46
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
12/08/23 05:46
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
12/08/23 05:46
74-83-9 v2
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
12/08/23 05:46
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
12/08/23 05:46
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
12/08/23 05:46
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
12/08/23 05:46
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
12/08/23 05:46
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
12/08/23 05:46
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
12/08/23 05:46
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
12/08/23 05:46
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
12/08/23 05:46
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
12/08/23 05:46
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
12/08/23 05:46
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
12/08/23 05:46
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
12/08/23 05:46
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
12/08/23 05:46
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
12/08/23 05:46
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
12/08/23 05:46
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
12/08/23 05:46
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
12/08/23 05:46
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
12/08/23 05:46
156-60-5
1,2-Dichloropropene
ND
ug/L
1.0
0.36
1
12/08/23 05:46
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
12/08/23 05:46
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
12/08/23 05:46
10061-02-6
Ethylbenzene
ND
ug/L
1.0
0.30
1
12/08/23 05:46
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
12/08/23 05:46
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
12/08/23 05:46
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
12/08/23 05:46
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
12/08/23 05:46
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
12/08/23 05:46
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
12/08/23 05:46
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
12/08/23 05:46
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
12/08/23 05:46
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
12/08/23 05:46
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
12/08/23 05:46
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
12/08/23 05:46
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
12/08/23 05:46
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
12/08/23 05:46
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
12/08/23 05:46
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
12/08/23 05:46
108-05-4 v2
REPORT OF LABORATORY ANALYSIS
This report
shall not be reproduced,
except in full,
Date: 12/28/2023 02:27 PM
without the written consent of Pace
Analytical Services, LLC.
Page 23 of 60

ace
Pace Analytical Services, LLC
POWWOWe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MW-8A
Lab ID: 92702270008 Collected:
12/04/23 10:05
Received: 12/06/23 14:00 Matrix: Water
Parameters
Results Units PQL
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Vinyl chloride
ND ug/L 1.0
0.39 1
12/08/23 05:46
75-01-4
Xylene (Total)
ND ug/L 1.0
0.34 1
12/08/23 05:46
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
98 % 70-130
1
12/08/23 05:46
460-00-4
1,2-Dichloroethane-d4 (S)
94 % 70-130
1
12/08/23 05:46
17060-07-0
Toluene-d8 (S)
102 % 70-130
1
12/08/23 05:46
2037-26-5
Date: 12/28/2023 02:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 24 of 60

ace
Pace Analytical Services, LLC
p36RVir6fy�e. Suite 100
��JJ Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MW-9 Lab ID: 92702270009 Collected: 12/05/23 10:30 Received: 12/06/23 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Date: 12/28/2023 02:27 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
5.1
1
12/08/2315:57
67-64-1
ND
ug/L
10.0
1.8
1
12/08/2315:57
107-13-1
ND
ug/L
1.0
0.34
1
12/08/2315:57
71-43-2
ND
ug/L
1.0
0.47
1
12/08/2315:57
74-97-5
ND
ug/L
1.0
0.31
1
12/08/2315:57
75-27-4
ND
ug/L
1.0
0.34
1
12/08/2315:57
75-25-2
ND
ug/L
2.0
1.7
1
12/08/2315:57
74-83-9
ND
ug/L
5.0
4.0
1
12/08/2315:57
78-93-3
ND
ug/L
2.0
0.36
1
12/08/2315:57
75-15-0
ND
ug/L
1.0
0.33
1
12/08/2315:57
56-23-5
ND
ug/L
1.0
0.28
1
12/08/2315:57
108-90-7
ND
ug/L
1.0
0.65
1
12/08/2315:57
75-00-3
ND
ug/L
1.0
0.43
1
12/08/2315:57
67-66-3
ND
ug/L
1.0
0.54
1
12/08/2315:57
74-87-3
ND
ug/L
2.0
0.34
1
12/08/2315:57
96-12-8
ND
ug/L
1.0
0.36
1
12/08/2315:57
124-48-1
ND
ug/L
1.0
0.27
1
12/08/2315:57
106-93-4
ND
ug/L
1.0
0.39
1
12/08/2315:57
74-95-3
ND
ug/L
1.0
0.34
1
12/08/2315:57
95-50-1
ND
ug/L
1.0
0.33
1
12/08/2315:57
106-46-7
ND
ug/L
1.0
0.56
1
12/08/2315:57
110-57-6
ND
ug/L
1.0
0.37
1
12/08/2315:57
75-34-3
ND
ug/L
1.0
0.32
1
12/08/2315:57
107-06-2
ND
ug/L
1.0
0.35
1
12/08/2315:57
75-35-4
ND
ug/L
1.0
0.38
1
12/08/2315:57
156-59-2
ND
ug/L
1.0
0.40
1
12/08/2315:57
156-60-5
ND
ug/L
1.0
0.36
1
12/08/2315:57
78-87-5
ND
ug/L
1.0
0.36
1
12/08/23 15:57
10061-01-5
ND
ug/L
1.0
0.36
1
12/08/2315:57
10061-02-6
ND
ug/L
1.0
0.30
1
12/08/2315:57
100-41-4
ND
ug/L
5.0
0.48
1
12/08/2315:57
591-78-6
ND
ug/L
20.0
9.7
1
12/08/2315:57
74-88-4
ND
ug/L
5.0
2.0
1
12/08/2315:57
75-09-2
ND
ug/L
5.0
2.7
1
12/08/2315:57
108-10-1
ND
ug/L
1.0
0.29
1
12/08/2315:57
100-42-5
ND
ug/L
1.0
0.31
1
12/08/2315:57
630-20-6
ND
ug/L
1.0
0.22
1
12/08/2315:57
79-34-5
ND
ug/L
1.0
0.29
1
12/08/2315:57
127-18-4
ND
ug/L
1.0
0.24
1
12/08/2315:57
108-88-3
ND
ug/L
1.0
0.33
1
12/08/2315:57
71-55-6
ND
ug/L
1.0
0.32
1
12/08/2315:57
79-00-5
ND
ug/L
1.0
0.38
1
12/08/2315:57
79-01-6
ND
ug/L
1.0
0.30
1
12/08/2315:57
75-69-4
ND
ug/L
1.0
0.26
1
12/08/2315:57
96-18-4
ND
ug/L
2.0
1.3
1
12/08/2315:57
108-05-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
Page 25 of 60

ace
Pace Analytical Services, LLC
POWWOWe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MW-9
Lab ID: 92702270009 Collected:
12/05/23 10:30
Received: 12/06/23 14:00 Matrix: Water
Parameters
Results Units PQL
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Vinyl chloride
ND ug/L 1.0
0.39 1
12/08/23 15:57
75-01-4
Xylene (Total)
ND ug/L 1.0
0.34 1
12/08/23 15:57
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
100 % 70-130
1
12/08/23 15:57
460-00-4
1,2-Dichloroethane-d4 (S)
100 % 70-130
1
12/08/23 15:57
17060-07-0
Toluene-d8 (S)
100 % 70-130
1
12/08/23 15:57
2037-26-5
Date: 12/28/2023 02:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 26 of 60

ace
Pace Analytical Services, LLC
POWWOW e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MW-9A Lab ID: 92702270010 Collected: 12/05/23 10:00 Received: 12/06/23 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Date: 12/28/2023 02:27 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
5.1
1
12/08/2316:15
67-64-1
ND
ug/L
10.0
1.8
1
12/08/2316:15
107-13-1
ND
ug/L
1.0
0.34
1
12/08/2316:15
71-43-2
ND
ug/L
1.0
0.47
1
12/08/2316:15
74-97-5
ND
ug/L
1.0
0.31
1
12/08/2316:15
75-27-4
ND
ug/L
1.0
0.34
1
12/08/2316:15
75-25-2
ND
ug/L
2.0
1.7
1
12/08/2316:15
74-83-9
ND
ug/L
5.0
4.0
1
12/08/2316:15
78-93-3
ND
ug/L
2.0
0.36
1
12/08/2316:15
75-15-0
ND
ug/L
1.0
0.33
1
12/08/2316:15
56-23-5
ND
ug/L
1.0
0.28
1
12/08/2316:15
108-90-7
ND
ug/L
1.0
0.65
1
12/08/2316:15
75-00-3
ND
ug/L
1.0
0.43
1
12/08/2316:15
67-66-3
ND
ug/L
1.0
0.54
1
12/08/2316:15
74-87-3
ND
ug/L
2.0
0.34
1
12/08/2316:15
96-12-8
ND
ug/L
1.0
0.36
1
12/08/2316:15
124-48-1
ND
ug/L
1.0
0.27
1
12/08/2316:15
106-93-4
ND
ug/L
1.0
0.39
1
12/08/2316:15
74-95-3
ND
ug/L
1.0
0.34
1
12/08/2316:15
95-50-1
ND
ug/L
1.0
0.33
1
12/08/2316:15
106-46-7
ND
ug/L
1.0
0.56
1
12/08/2316:15
110-57-6
ND
ug/L
1.0
0.37
1
12/08/2316:15
75-34-3
ND
ug/L
1.0
0.32
1
12/08/2316:15
107-06-2
ND
ug/L
1.0
0.35
1
12/08/2316:15
75-35-4
ND
ug/L
1.0
0.38
1
12/08/2316:15
156-59-2
ND
ug/L
1.0
0.40
1
12/08/2316:15
156-60-5
ND
ug/L
1.0
0.36
1
12/08/2316:15
78-87-5
ND
ug/L
1.0
0.36
1
12/08/23 16:15
10061-01-5
ND
ug/L
1.0
0.36
1
12/08/2316:15
10061-02-6
ND
ug/L
1.0
0.30
1
12/08/2316:15
100-41-4
ND
ug/L
5.0
0.48
1
12/08/2316:15
591-78-6
ND
ug/L
20.0
9.7
1
12/08/2316:15
74-88-4
ND
ug/L
5.0
2.0
1
12/08/2316:15
75-09-2
ND
ug/L
5.0
2.7
1
12/08/2316:15
108-10-1
ND
ug/L
1.0
0.29
1
12/08/2316:15
100-42-5
ND
ug/L
1.0
0.31
1
12/08/2316:15
630-20-6
ND
ug/L
1.0
0.22
1
12/08/2316:15
79-34-5
ND
ug/L
1.0
0.29
1
12/08/2316:15
127-18-4
ND
ug/L
1.0
0.24
1
12/08/2316:15
108-88-3
ND
ug/L
1.0
0.33
1
12/08/2316:15
71-55-6
ND
ug/L
1.0
0.32
1
12/08/2316:15
79-00-5
ND
ug/L
1.0
0.38
1
12/08/2316:15
79-01-6
ND
ug/L
1.0
0.30
1
12/08/2316:15
75-69-4
ND
ug/L
1.0
0.26
1
12/08/2316:15
96-18-4
ND
ug/L
2.0
1.3
1
12/08/2316:15
108-05-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
Page 27 of 60

ace
Pace Analytical Services, LLC
POWWOWe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MW-9A
Lab ID: 92702270010 Collected:
12/05/23 10:00
Received: 12/06/23 14:00 Matrix: Water
Parameters
Results Units PQL
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Vinyl chloride
ND ug/L 1.0
0.39 1
12/08/23 16:15
75-01-4
Xylene (Total)
ND ug/L 1.0
0.34 1
12/08/23 16:15
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99 % 70-130
1
12/08/23 16:15
460-00-4
1,2-Dichloroethane-d4 (S)
102 % 70-130
1
12/08/23 16:15
17060-07-0
Toluene-d8 (S)
99 % 70-130
1
12/08/23 16:15
2037-26-5
Date: 12/28/2023 02:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 28 of 60

ace
Pace Analytical Services, LLC
POWWOWe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MW-10A Lab ID: 92702270011 Collected: 12/04/23 14:50 Received: 12/06/23 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Date: 12/28/2023 02:27 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
5.1
1
12/08/2316:33
67-64-1
ND
ug/L
10.0
1.8
1
12/08/2316:33
107-13-1
ND
ug/L
1.0
0.34
1
12/08/2316:33
71-43-2
ND
ug/L
1.0
0.47
1
12/08/2316:33
74-97-5
ND
ug/L
1.0
0.31
1
12/08/2316:33
75-27-4
ND
ug/L
1.0
0.34
1
12/08/2316:33
75-25-2
ND
ug/L
2.0
1.7
1
12/08/2316:33
74-83-9
ND
ug/L
5.0
4.0
1
12/08/2316:33
78-93-3
ND
ug/L
2.0
0.36
1
12/08/2316:33
75-15-0
ND
ug/L
1.0
0.33
1
12/08/2316:33
56-23-5
ND
ug/L
1.0
0.28
1
12/08/2316:33
108-90-7
ND
ug/L
1.0
0.65
1
12/08/2316:33
75-00-3
ND
ug/L
1.0
0.43
1
12/08/2316:33
67-66-3
ND
ug/L
1.0
0.54
1
12/08/2316:33
74-87-3
ND
ug/L
2.0
0.34
1
12/08/2316:33
96-12-8
ND
ug/L
1.0
0.36
1
12/08/2316:33
124-48-1
ND
ug/L
1.0
0.27
1
12/08/2316:33
106-93-4
ND
ug/L
1.0
0.39
1
12/08/2316:33
74-95-3
ND
ug/L
1.0
0.34
1
12/08/2316:33
95-50-1
ND
ug/L
1.0
0.33
1
12/08/2316:33
106-46-7
ND
ug/L
1.0
0.56
1
12/08/2316:33
110-57-6
ND
ug/L
1.0
0.37
1
12/08/2316:33
75-34-3
ND
ug/L
1.0
0.32
1
12/08/2316:33
107-06-2
ND
ug/L
1.0
0.35
1
12/08/2316:33
75-35-4
ND
ug/L
1.0
0.38
1
12/08/2316:33
156-59-2
ND
ug/L
1.0
0.40
1
12/08/2316:33
156-60-5
ND
ug/L
1.0
0.36
1
12/08/2316:33
78-87-5
ND
ug/L
1.0
0.36
1
12/08/23 16:33
10061-01-5
ND
ug/L
1.0
0.36
1
12/08/2316:33
10061-02-6
ND
ug/L
1.0
0.30
1
12/08/2316:33
100-41-4
ND
ug/L
5.0
0.48
1
12/08/2316:33
591-78-6
ND
ug/L
20.0
9.7
1
12/08/2316:33
74-88-4
ND
ug/L
5.0
2.0
1
12/08/2316:33
75-09-2
ND
ug/L
5.0
2.7
1
12/08/2316:33
108-10-1
ND
ug/L
1.0
0.29
1
12/08/2316:33
100-42-5
ND
ug/L
1.0
0.31
1
12/08/2316:33
630-20-6
ND
ug/L
1.0
0.22
1
12/08/2316:33
79-34-5
ND
ug/L
1.0
0.29
1
12/08/2316:33
127-18-4
ND
ug/L
1.0
0.24
1
12/08/2316:33
108-88-3
ND
ug/L
1.0
0.33
1
12/08/2316:33
71-55-6
ND
ug/L
1.0
0.32
1
12/08/2316:33
79-00-5
ND
ug/L
1.0
0.38
1
12/08/2316:33
79-01-6
ND
ug/L
1.0
0.30
1
12/08/2316:33
75-69-4
ND
ug/L
1.0
0.26
1
12/08/2316:33
96-18-4
ND
ug/L
2.0
1.3
1
12/08/2316:33
108-05-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
Page 29 of 60

ace
Pace Analytical Services, LLC
PdagmirpYje. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MW-10A
Lab ID: 92702270011 Collected:
12/04/23 14:50
Received: 12/06/23 14:00 Matrix: Water
Parameters
Results Units PQL
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Vinyl chloride
ND ug/L 1.0
0.39 1
12/08/23 16:33
75-01-4
Xylene (Total)
ND ug/L 1.0
0.34 1
12/08/23 16:33
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99 % 70-130
1
12/08/23 16:33
460-00-4
1,2-Dichloroethane-d4 (S)
100 % 70-130
1
12/08/23 16:33
17060-07-0
Toluene-d8 (S)
99 % 70-130
1
12/08/23 16:33
2037-26-5
Date: 12/28/2023 02:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 30 of 60

ace
Pace Analytical Services, LLC
P989%19r6fy4e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: SW-1 Lab ID: 92702270012 Collected: 12/05/23 14:45 Received: 12/06/23 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Date: 12/28/2023 02:27 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
5.1
1
12/08/2315:02
67-64-1
ND
ug/L
10.0
1.8
1
12/08/2315:02
107-13-1
ND
ug/L
1.0
0.34
1
12/08/2315:02
71-43-2
ND
ug/L
1.0
0.47
1
12/08/2315:02
74-97-5
ND
ug/L
1.0
0.31
1
12/08/2315:02
75-27-4
ND
ug/L
1.0
0.34
1
12/08/2315:02
75-25-2
ND
ug/L
2.0
1.7
1
12/08/2315:02
74-83-9
ND
ug/L
5.0
4.0
1
12/08/2315:02
78-93-3
ND
ug/L
2.0
0.36
1
12/08/2315:02
75-15-0
ND
ug/L
1.0
0.33
1
12/08/2315:02
56-23-5
ND
ug/L
1.0
0.28
1
12/08/2315:02
108-90-7
ND
ug/L
1.0
0.65
1
12/08/2315:02
75-00-3
ND
ug/L
1.0
0.43
1
12/08/2315:02
67-66-3
ND
ug/L
1.0
0.54
1
12/08/2315:02
74-87-3
ND
ug/L
2.0
0.34
1
12/08/2315:02
96-12-8
ND
ug/L
1.0
0.36
1
12/08/2315:02
124-48-1
ND
ug/L
1.0
0.27
1
12/08/2315:02
106-93-4
ND
ug/L
1.0
0.39
1
12/08/2315:02
74-95-3
ND
ug/L
1.0
0.34
1
12/08/2315:02
95-50-1
ND
ug/L
1.0
0.33
1
12/08/2315:02
106-46-7
ND
ug/L
1.0
0.56
1
12/08/2315:02
110-57-6
ND
ug/L
1.0
0.37
1
12/08/2315:02
75-34-3
ND
ug/L
1.0
0.32
1
12/08/2315:02
107-06-2
ND
ug/L
1.0
0.35
1
12/08/2315:02
75-35-4
ND
ug/L
1.0
0.38
1
12/08/2315:02
156-59-2
ND
ug/L
1.0
0.40
1
12/08/2315:02
156-60-5
ND
ug/L
1.0
0.36
1
12/08/2315:02
78-87-5
ND
ug/L
1.0
0.36
1
12/08/23 15:02
10061-01-5
ND
ug/L
1.0
0.36
1
12/08/2315:02
10061-02-6
ND
ug/L
1.0
0.30
1
12/08/2315:02
100-41-4
ND
ug/L
5.0
0.48
1
12/08/2315:02
591-78-6
ND
ug/L
20.0
9.7
1
12/08/2315:02
74-88-4
ND
ug/L
5.0
2.0
1
12/08/2315:02
75-09-2
ND
ug/L
5.0
2.7
1
12/08/2315:02
108-10-1
ND
ug/L
1.0
0.29
1
12/08/2315:02
100-42-5
ND
ug/L
1.0
0.31
1
12/08/2315:02
630-20-6
ND
ug/L
1.0
0.22
1
12/08/2315:02
79-34-5
ND
ug/L
1.0
0.29
1
12/08/2315:02
127-18-4
ND
ug/L
1.0
0.24
1
12/08/2315:02
108-88-3
ND
ug/L
1.0
0.33
1
12/08/2315:02
71-55-6
ND
ug/L
1.0
0.32
1
12/08/2315:02
79-00-5
ND
ug/L
1.0
0.38
1
12/08/2315:02
79-01-6
ND
ug/L
1.0
0.30
1
12/08/2315:02
75-69-4
ND
ug/L
1.0
0.26
1
12/08/2315:02
96-18-4
ND
ug/L
2.0
1.3
1
12/08/2315:02
108-05-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
Page 31 of 60

ace
Pace Analytical Services, LLC
P98HISr6f0we. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: SW-1
Lab ID: 92702270012 Collected:
12/05/23 14:45
Received: 12/06/23 14:00 Matrix: Water
Parameters
Results Units PQL
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Vinyl chloride
ND ug/L 1.0
0.39 1
12/08/23 15:02
75-01-4
Xylene (Total)
ND ug/L 1.0
0.34 1
12/08/23 15:02
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
100 % 70-130
1
12/08/23 15:02
460-00-4
1,2-Dichloroethane-d4 (S)
101 % 70-130
1
12/08/23 15:02
17060-07-0
Toluene-d8 (S)
100 % 70-130
1
12/08/23 15:02
2037-26-5
Date: 12/28/2023 02:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 32 of 60

ace
Pace Analytical Services, LLC
P36g�ir6fy,JWe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: SW-2 Lab ID: 92702270013 Collected: 12/05/23 11:40 Received: 12/06/23 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Date: 12/28/2023 02:27 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
5.1
1
12/08/2315:20
67-64-1
ND
ug/L
10.0
1.8
1
12/08/2315:20
107-13-1
ND
ug/L
1.0
0.34
1
12/08/2315:20
71-43-2
ND
ug/L
1.0
0.47
1
12/08/2315:20
74-97-5
ND
ug/L
1.0
0.31
1
12/08/2315:20
75-27-4
ND
ug/L
1.0
0.34
1
12/08/2315:20
75-25-2
ND
ug/L
2.0
1.7
1
12/08/2315:20
74-83-9
ND
ug/L
5.0
4.0
1
12/08/2315:20
78-93-3
ND
ug/L
2.0
0.36
1
12/08/2315:20
75-15-0
ND
ug/L
1.0
0.33
1
12/08/2315:20
56-23-5
ND
ug/L
1.0
0.28
1
12/08/2315:20
108-90-7
ND
ug/L
1.0
0.65
1
12/08/2315:20
75-00-3
ND
ug/L
1.0
0.43
1
12/08/2315:20
67-66-3
ND
ug/L
1.0
0.54
1
12/08/2315:20
74-87-3
ND
ug/L
2.0
0.34
1
12/08/2315:20
96-12-8
ND
ug/L
1.0
0.36
1
12/08/2315:20
124-48-1
ND
ug/L
1.0
0.27
1
12/08/2315:20
106-93-4
ND
ug/L
1.0
0.39
1
12/08/2315:20
74-95-3
ND
ug/L
1.0
0.34
1
12/08/2315:20
95-50-1
ND
ug/L
1.0
0.33
1
12/08/2315:20
106-46-7
ND
ug/L
1.0
0.56
1
12/08/2315:20
110-57-6
ND
ug/L
1.0
0.37
1
12/08/2315:20
75-34-3
ND
ug/L
1.0
0.32
1
12/08/2315:20
107-06-2
ND
ug/L
1.0
0.35
1
12/08/2315:20
75-35-4
ND
ug/L
1.0
0.38
1
12/08/2315:20
156-59-2
ND
ug/L
1.0
0.40
1
12/08/2315:20
156-60-5
ND
ug/L
1.0
0.36
1
12/08/2315:20
78-87-5
ND
ug/L
1.0
0.36
1
12/08/23 15:20
10061-01-5
ND
ug/L
1.0
0.36
1
12/08/2315:20
10061-02-6
ND
ug/L
1.0
0.30
1
12/08/2315:20
100-41-4
ND
ug/L
5.0
0.48
1
12/08/2315:20
591-78-6
ND
ug/L
20.0
9.7
1
12/08/2315:20
74-88-4
ND
ug/L
5.0
2.0
1
12/08/2315:20
75-09-2
ND
ug/L
5.0
2.7
1
12/08/2315:20
108-10-1
ND
ug/L
1.0
0.29
1
12/08/2315:20
100-42-5
ND
ug/L
1.0
0.31
1
12/08/2315:20
630-20-6
ND
ug/L
1.0
0.22
1
12/08/2315:20
79-34-5
ND
ug/L
1.0
0.29
1
12/08/2315:20
127-18-4
ND
ug/L
1.0
0.24
1
12/08/2315:20
108-88-3
ND
ug/L
1.0
0.33
1
12/08/2315:20
71-55-6
ND
ug/L
1.0
0.32
1
12/08/2315:20
79-00-5
ND
ug/L
1.0
0.38
1
12/08/2315:20
79-01-6
ND
ug/L
1.0
0.30
1
12/08/2315:20
75-69-4
ND
ug/L
1.0
0.26
1
12/08/2315:20
96-18-4
ND
ug/L
2.0
1.3
1
12/08/2315:20
108-05-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
Page 33 of 60

ace
Pace Analytical Services, LLC
P989%18r6fy4e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: SW-2
Lab ID: 92702270013 Collected:
12/05/23 11:40
Received: 12/06/23 14:00 Matrix: Water
Parameters
Results Units PQL
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Vinyl chloride
ND ug/L 1.0
0.39 1
12/08/23 15:20
75-01-4
Xylene (Total)
ND ug/L 1.0
0.34 1
12/08/23 15:20
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
98 % 70-130
1
12/08/23 15:20
460-00-4
1,2-Dichloroethane-d4 (S)
100 % 70-130
1
12/08/23 15:20
17060-07-0
Toluene-d8 (S)
100 % 70-130
1
12/08/23 15:20
2037-26-5
Date: 12/28/2023 02:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 34 of 60

ace
Pace Analytical Services, LLC
P3ag%larpy,iVe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: LEACHATE POND Lab ID: 92702270014 Collected: 12/04/23 11:10 Received: 12/06/23 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Date: 12/28/2023 02:27 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
5.1
1
12/08/2315:38
67-64-1
ND
ug/L
10.0
1.8
1
12/08/2315:38
107-13-1
ND
ug/L
1.0
0.34
1
12/08/2315:38
71-43-2
ND
ug/L
1.0
0.47
1
12/08/2315:38
74-97-5
ND
ug/L
1.0
0.31
1
12/08/2315:38
75-27-4
ND
ug/L
1.0
0.34
1
12/08/2315:38
75-25-2
ND
ug/L
2.0
1.7
1
12/08/2315:38
74-83-9
ND
ug/L
5.0
4.0
1
12/08/2315:38
78-93-3
ND
ug/L
2.0
0.36
1
12/08/2315:38
75-15-0
ND
ug/L
1.0
0.33
1
12/08/2315:38
56-23-5
ND
ug/L
1.0
0.28
1
12/08/2315:38
108-90-7
ND
ug/L
1.0
0.65
1
12/08/2315:38
75-00-3
ND
ug/L
1.0
0.43
1
12/08/2315:38
67-66-3
ND
ug/L
1.0
0.54
1
12/08/2315:38
74-87-3
ND
ug/L
2.0
0.34
1
12/08/2315:38
96-12-8
ND
ug/L
1.0
0.36
1
12/08/2315:38
124-48-1
ND
ug/L
1.0
0.27
1
12/08/2315:38
106-93-4
ND
ug/L
1.0
0.39
1
12/08/2315:38
74-95-3
ND
ug/L
1.0
0.34
1
12/08/2315:38
95-50-1
ND
ug/L
1.0
0.33
1
12/08/2315:38
106-46-7
ND
ug/L
1.0
0.56
1
12/08/2315:38
110-57-6
ND
ug/L
1.0
0.37
1
12/08/2315:38
75-34-3
ND
ug/L
1.0
0.32
1
12/08/2315:38
107-06-2
ND
ug/L
1.0
0.35
1
12/08/2315:38
75-35-4
ND
ug/L
1.0
0.38
1
12/08/2315:38
156-59-2
ND
ug/L
1.0
0.40
1
12/08/2315:38
156-60-5
ND
ug/L
1.0
0.36
1
12/08/2315:38
78-87-5
ND
ug/L
1.0
0.36
1
12/08/23 15:38
10061-01-5
ND
ug/L
1.0
0.36
1
12/08/2315:38
10061-02-6
ND
ug/L
1.0
0.30
1
12/08/2315:38
100-41-4
ND
ug/L
5.0
0.48
1
12/08/2315:38
591-78-6
ND
ug/L
20.0
9.7
1
12/08/2315:38
74-88-4
ND
ug/L
5.0
2.0
1
12/08/2315:38
75-09-2
ND
ug/L
5.0
2.7
1
12/08/2315:38
108-10-1
ND
ug/L
1.0
0.29
1
12/08/2315:38
100-42-5
ND
ug/L
1.0
0.31
1
12/08/2315:38
630-20-6
ND
ug/L
1.0
0.22
1
12/08/2315:38
79-34-5
ND
ug/L
1.0
0.29
1
12/08/2315:38
127-18-4
ND
ug/L
1.0
0.24
1
12/08/2315:38
108-88-3
ND
ug/L
1.0
0.33
1
12/08/2315:38
71-55-6
ND
ug/L
1.0
0.32
1
12/08/2315:38
79-00-5
ND
ug/L
1.0
0.38
1
12/08/2315:38
79-01-6
ND
ug/L
1.0
0.30
1
12/08/2315:38
75-69-4
ND
ug/L
1.0
0.26
1
12/08/2315:38
96-18-4
ND
ug/L
2.0
1.3
1
12/08/2315:38
108-05-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
Page 35 of 60

ace
Pace Analytical Services, LLC
P���WWOWe. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: LEACHATE POND
Lab ID:
92702270014 Collected:
12/04/23 11:10
Received: 12/06/23 14:00 Matrix: Water
Parameters
Results
Units PQL
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
Vinyl chloride
ND
ug/L 1.0
0.39 1
12/08/23 15:38
75-01-4
Xylene (Total)
ND
ug/L 1.0
0.34 1
12/08/23 15:38
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
98
% 70-130
1
12/08/23 15:38
460-00-4
1,2-Dichloroethane-d4 (S)
100
% 70-130
1
12/08/23 15:38
17060-07-0
Toluene-d8 (S)
100
% 70-130
1
12/08/23 15:38
2037-26-5
Date: 12/28/2023 02:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 36 of 60

ace
Pace Analytical Services, LLC
P98 91618r6f0we. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MNS_FB-20231204-1030 Lab ID: 92702270015 Collected: 12/04/23 10:30 Received: 12/06/23 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Date: 12/28/2023 02:27 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
28.5
ug/L
25.0
5.1
1
12/08/2314:08
67-64-1
ND
ug/L
10.0
1.8
1
12/08/2314:08
107-13-1
ND
ug/L
1.0
0.34
1
12/08/2314:08
71-43-2
ND
ug/L
1.0
0.47
1
12/08/2314:08
74-97-5
ND
ug/L
1.0
0.31
1
12/08/2314:08
75-27-4
ND
ug/L
1.0
0.34
1
12/08/2314:08
75-25-2
ND
ug/L
2.0
1.7
1
12/08/2314:08
74-83-9
4.9J
ug/L
5.0
4.0
1
12/08/2314:08
78-93-3
ND
ug/L
2.0
0.36
1
12/08/2314:08
75-15-0
ND
ug/L
1.0
0.33
1
12/08/2314:08
56-23-5
ND
ug/L
1.0
0.28
1
12/08/2314:08
108-90-7
ND
ug/L
1.0
0.65
1
12/08/2314:08
75-00-3
ND
ug/L
1.0
0.43
1
12/08/2314:08
67-66-3
ND
ug/L
1.0
0.54
1
12/08/2314:08
74-87-3
ND
ug/L
2.0
0.34
1
12/08/2314:08
96-12-8
ND
ug/L
1.0
0.36
1
12/08/2314:08
124-48-1
ND
ug/L
1.0
0.27
1
12/08/2314:08
106-93-4
ND
ug/L
1.0
0.39
1
12/08/2314:08
74-95-3
ND
ug/L
1.0
0.34
1
12/08/2314:08
95-50-1
ND
ug/L
1.0
0.33
1
12/08/2314:08
106-46-7
ND
ug/L
1.0
0.56
1
12/08/2314:08
110-57-6
ND
ug/L
1.0
0.37
1
12/08/2314:08
75-34-3
ND
ug/L
1.0
0.32
1
12/08/2314:08
107-06-2
ND
ug/L
1.0
0.35
1
12/08/2314:08
75-35-4
ND
ug/L
1.0
0.38
1
12/08/2314:08
156-59-2
ND
ug/L
1.0
0.40
1
12/08/2314:08
156-60-5
ND
ug/L
1.0
0.36
1
12/08/2314:08
78-87-5
ND
ug/L
1.0
0.36
1
12/08/23 14:08
10061-01-5
ND
ug/L
1.0
0.36
1
12/08/2314:08
10061-02-6
ND
ug/L
1.0
0.30
1
12/08/2314:08
100-41-4
0.76J
ug/L
5.0
0.48
1
12/08/2314:08
591-78-6
ND
ug/L
20.0
9.7
1
12/08/2314:08
74-88-4
ND
ug/L
5.0
2.0
1
12/08/2314:08
75-09-2
ND
ug/L
5.0
2.7
1
12/08/2314:08
108-10-1
ND
ug/L
1.0
0.29
1
12/08/2314:08
100-42-5
ND
ug/L
1.0
0.31
1
12/08/2314:08
630-20-6
ND
ug/L
1.0
0.22
1
12/08/2314:08
79-34-5
ND
ug/L
1.0
0.29
1
12/08/2314:08
127-18-4
ND
ug/L
1.0
0.24
1
12/08/2314:08
108-88-3
ND
ug/L
1.0
0.33
1
12/08/2314:08
71-55-6
ND
ug/L
1.0
0.32
1
12/08/2314:08
79-00-5
ND
ug/L
1.0
0.38
1
12/08/2314:08
79-01-6
ND
ug/L
1.0
0.30
1
12/08/2314:08
75-69-4
ND
ug/L
1.0
0.26
1
12/08/2314:08
96-18-4
ND
ug/L
2.0
1.3
1
12/08/2314:08
108-05-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
Page 37 of 60

ace
Pace Analytical Services, LLC
P989%16r6fy4e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MNS_FB-20231204-1030
Lab ID:
92702270015 Collected:
12/04/23 10:30
Received: 12/06/23 14:00 Matrix: Water
Parameters
Results
Units PQL
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
Vinyl chloride
ND
ug/L 1.0
0.39 1
12/08/23 14:08
75-01-4
Xylene (Total)
ND
ug/L 1.0
0.34 1
12/08/23 14:08
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99
% 70-130
1
12/08/23 14:08
460-00-4 CO
1,2-Dichloroethane-d4 (S)
100
% 70-130
1
12/08/23 14:08
17060-07-0
Toluene-d8 (S)
100
% 70-130
1
12/08/23 14:08
2037-26-5
Date: 12/28/2023 02:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 38 of 60

ace
Pace Analytical Services, LLC
P9890 bir6f0we. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MNS_FB-20231205-1400 Lab ID: 92702270016 Collected: 12/05/23 14:00 Received: 12/06/23 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Date: 12/28/2023 02:27 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
28.9
ug/L
25.0
5.1
1
12/08/2314:26
67-64-1
ND
ug/L
10.0
1.8
1
12/08/2314:26
107-13-1
ND
ug/L
1.0
0.34
1
12/08/2314:26
71-43-2
ND
ug/L
1.0
0.47
1
12/08/2314:26
74-97-5
ND
ug/L
1.0
0.31
1
12/08/2314:26
75-27-4
ND
ug/L
1.0
0.34
1
12/08/2314:26
75-25-2
ND
ug/L
2.0
1.7
1
12/08/2314:26
74-83-9
4.8.1
ug/L
5.0
4.0
1
12/08/2314:26
78-93-3
ND
ug/L
2.0
0.36
1
12/08/2314:26
75-15-0
ND
ug/L
1.0
0.33
1
12/08/2314:26
56-23-5
ND
ug/L
1.0
0.28
1
12/08/2314:26
108-90-7
ND
ug/L
1.0
0.65
1
12/08/2314:26
75-00-3
ND
ug/L
1.0
0.43
1
12/08/2314:26
67-66-3
ND
ug/L
1.0
0.54
1
12/08/2314:26
74-87-3
ND
ug/L
2.0
0.34
1
12/08/2314:26
96-12-8
ND
ug/L
1.0
0.36
1
12/08/2314:26
124-48-1
ND
ug/L
1.0
0.27
1
12/08/2314:26
106-93-4
ND
ug/L
1.0
0.39
1
12/08/2314:26
74-95-3
ND
ug/L
1.0
0.34
1
12/08/2314:26
95-50-1
ND
ug/L
1.0
0.33
1
12/08/2314:26
106-46-7
ND
ug/L
1.0
0.56
1
12/08/2314:26
110-57-6
ND
ug/L
1.0
0.37
1
12/08/2314:26
75-34-3
ND
ug/L
1.0
0.32
1
12/08/2314:26
107-06-2
ND
ug/L
1.0
0.35
1
12/08/2314:26
75-35-4
ND
ug/L
1.0
0.38
1
12/08/2314:26
156-59-2
ND
ug/L
1.0
0.40
1
12/08/2314:26
156-60-5
ND
ug/L
1.0
0.36
1
12/08/2314:26
78-87-5
ND
ug/L
1.0
0.36
1
12/08/23 14:26
10061-01-5
ND
ug/L
1.0
0.36
1
12/08/2314:26
10061-02-6
ND
ug/L
1.0
0.30
1
12/08/2314:26
100-41-4
0.78J
ug/L
5.0
0.48
1
12/08/2314:26
591-78-6
ND
ug/L
20.0
9.7
1
12/08/2314:26
74-88-4
ND
ug/L
5.0
2.0
1
12/08/2314:26
75-09-2
ND
ug/L
5.0
2.7
1
12/08/2314:26
108-10-1
ND
ug/L
1.0
0.29
1
12/08/2314:26
100-42-5
ND
ug/L
1.0
0.31
1
12/08/2314:26
630-20-6
ND
ug/L
1.0
0.22
1
12/08/2314:26
79-34-5
ND
ug/L
1.0
0.29
1
12/08/2314:26
127-18-4
ND
ug/L
1.0
0.24
1
12/08/2314:26
108-88-3
ND
ug/L
1.0
0.33
1
12/08/2314:26
71-55-6
ND
ug/L
1.0
0.32
1
12/08/2314:26
79-00-5
ND
ug/L
1.0
0.38
1
12/08/2314:26
79-01-6
ND
ug/L
1.0
0.30
1
12/08/2314:26
75-69-4
ND
ug/L
1.0
0.26
1
12/08/2314:26
96-18-4
ND
ug/L
2.0
1.3
1
12/08/2314:26
108-05-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
Page 39 of 60

ace
Pace Analytical Services, LLC
PdapAirpy�e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MNS_FB-20231205-1400
Lab ID:
92702270016 Collected:
12/05/23 14:00
Received: 12/06/23 14:00 Matrix: Water
Parameters
Results
Units PQL
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
Vinyl chloride
ND
ug/L 1.0
0.39 1
12/08/23 14:26
75-01-4
Xylene (Total)
ND
ug/L 1.0
0.34 1
12/08/23 14:26
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
100
% 70-130
1
12/08/23 14:26
460-00-4 CO
1,2-Dichloroethane-d4 (S)
100
% 70-130
1
12/08/23 14:26
17060-07-0
Toluene-d8 (S)
100
% 70-130
1
12/08/23 14:26
2037-26-5
Date: 12/28/2023 02:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 40 of 60

ace
Pace Analytical Services, LLC
POWWOWe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MNS_TB-20241204-0800 Lab ID: 92702270017 Collected: 12/04/23 08:00 Received: 12/06/23 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Date: 12/28/2023 02:27 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
28.8
ug/L
25.0
5.1
1
12/08/2314:44
67-64-1
ND
ug/L
10.0
1.8
1
12/08/2314:44
107-13-1
ND
ug/L
1.0
0.34
1
12/08/2314:44
71-43-2
ND
ug/L
1.0
0.47
1
12/08/2314:44
74-97-5
ND
ug/L
1.0
0.31
1
12/08/2314:44
75-27-4
ND
ug/L
1.0
0.34
1
12/08/2314:44
75-25-2
ND
ug/L
2.0
1.7
1
12/08/2314:44
74-83-9
5.1
ug/L
5.0
4.0
1
12/08/2314:44
78-93-3
ND
ug/L
2.0
0.36
1
12/08/2314:44
75-15-0
ND
ug/L
1.0
0.33
1
12/08/2314:44
56-23-5
ND
ug/L
1.0
0.28
1
12/08/2314:44
108-90-7
ND
ug/L
1.0
0.65
1
12/08/2314:44
75-00-3
ND
ug/L
1.0
0.43
1
12/08/2314:44
67-66-3
ND
ug/L
1.0
0.54
1
12/08/2314:44
74-87-3
ND
ug/L
2.0
0.34
1
12/08/2314:44
96-12-8
ND
ug/L
1.0
0.36
1
12/08/2314:44
124-48-1
ND
ug/L
1.0
0.27
1
12/08/2314:44
106-93-4
ND
ug/L
1.0
0.39
1
12/08/2314:44
74-95-3
ND
ug/L
1.0
0.34
1
12/08/2314:44
95-50-1
ND
ug/L
1.0
0.33
1
12/08/2314:44
106-46-7
ND
ug/L
1.0
0.56
1
12/08/2314:44
110-57-6
ND
ug/L
1.0
0.37
1
12/08/2314:44
75-34-3
ND
ug/L
1.0
0.32
1
12/08/2314:44
107-06-2
ND
ug/L
1.0
0.35
1
12/08/2314:44
75-35-4
ND
ug/L
1.0
0.38
1
12/08/2314:44
156-59-2
ND
ug/L
1.0
0.40
1
12/08/2314:44
156-60-5
ND
ug/L
1.0
0.36
1
12/08/2314:44
78-87-5
ND
ug/L
1.0
0.36
1
12/08/23 14:44
10061-01-5
ND
ug/L
1.0
0.36
1
12/08/2314:44
10061-02-6
ND
ug/L
1.0
0.30
1
12/08/2314:44
100-41-4
0.71J
ug/L
5.0
0.48
1
12/08/2314:44
591-78-6
ND
ug/L
20.0
9.7
1
12/08/2314:44
74-88-4
ND
ug/L
5.0
2.0
1
12/08/2314:44
75-09-2
ND
ug/L
5.0
2.7
1
12/08/2314:44
108-10-1
ND
ug/L
1.0
0.29
1
12/08/2314:44
100-42-5
ND
ug/L
1.0
0.31
1
12/08/2314:44
630-20-6
ND
ug/L
1.0
0.22
1
12/08/2314:44
79-34-5
ND
ug/L
1.0
0.29
1
12/08/2314:44
127-18-4
ND
ug/L
1.0
0.24
1
12/08/2314:44
108-88-3
ND
ug/L
1.0
0.33
1
12/08/2314:44
71-55-6
ND
ug/L
1.0
0.32
1
12/08/2314:44
79-00-5
ND
ug/L
1.0
0.38
1
12/08/2314:44
79-01-6
ND
ug/L
1.0
0.30
1
12/08/2314:44
75-69-4
ND
ug/L
1.0
0.26
1
12/08/2314:44
96-18-4
ND
ug/L
2.0
1.3
1
12/08/2314:44
108-05-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
Page 41 of 60

ace
Pace Analytical Services, LLC
Pdago �irwOwe. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MNS_TB-20241204-0800
Lab ID:
92702270017 Collected:
12/04/23 08:00
Received: 12/06/23 14:00 Matrix: Water
Parameters
Results
Units PQL
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
Vinyl chloride
ND
ug/L 1.0
0.39 1
12/08/23 14:44
75-01-4
Xylene (Total)
ND
ug/L 1.0
0.34 1
12/08/23 14:44
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
101
% 70-130
1
12/08/23 14:44
460-00-4 CO
1,2-Dichloroethane-d4 (S)
101
% 70-130
1
12/08/23 14:44
17060-07-0
Toluene-d8 (S)
100
% 70-130
1
12/08/23 14:44
2037-26-5
Date: 12/28/2023 02:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 42 of 60

ace
Pace Analytical Services, LLC
PdaRO�irpy4 re. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MNS_FD-20231204-1 Lab ID: 92702270018 Collected: 12/04/23 00:00 Received: 12/06/23 14:00 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Date: 12/28/2023 02:27 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
5.1
1
12/08/2316:51
67-64-1
ND
ug/L
10.0
1.8
1
12/08/2316:51
107-13-1
ND
ug/L
1.0
0.34
1
12/08/2316:51
71-43-2
ND
ug/L
1.0
0.47
1
12/08/2316:51
74-97-5
ND
ug/L
1.0
0.31
1
12/08/2316:51
75-27-4
ND
ug/L
1.0
0.34
1
12/08/2316:51
75-25-2
ND
ug/L
2.0
1.7
1
12/08/2316:51
74-83-9
ND
ug/L
5.0
4.0
1
12/08/2316:51
78-93-3
ND
ug/L
2.0
0.36
1
12/08/2316:51
75-15-0
ND
ug/L
1.0
0.33
1
12/08/2316:51
56-23-5
ND
ug/L
1.0
0.28
1
12/08/2316:51
108-90-7
ND
ug/L
1.0
0.65
1
12/08/2316:51
75-00-3
ND
ug/L
1.0
0.43
1
12/08/2316:51
67-66-3
ND
ug/L
1.0
0.54
1
12/08/2316:51
74-87-3
ND
ug/L
2.0
0.34
1
12/08/2316:51
96-12-8
ND
ug/L
1.0
0.36
1
12/08/2316:51
124-48-1
ND
ug/L
1.0
0.27
1
12/08/2316:51
106-93-4
ND
ug/L
1.0
0.39
1
12/08/2316:51
74-95-3
ND
ug/L
1.0
0.34
1
12/08/2316:51
95-50-1
ND
ug/L
1.0
0.33
1
12/08/2316:51
106-46-7
ND
ug/L
1.0
0.56
1
12/08/2316:51
110-57-6
ND
ug/L
1.0
0.37
1
12/08/2316:51
75-34-3
ND
ug/L
1.0
0.32
1
12/08/2316:51
107-06-2
ND
ug/L
1.0
0.35
1
12/08/2316:51
75-35-4
ND
ug/L
1.0
0.38
1
12/08/2316:51
156-59-2
ND
ug/L
1.0
0.40
1
12/08/2316:51
156-60-5
ND
ug/L
1.0
0.36
1
12/08/2316:51
78-87-5
ND
ug/L
1.0
0.36
1
12/08/23 16:51
10061-01-5
ND
ug/L
1.0
0.36
1
12/08/2316:51
10061-02-6
ND
ug/L
1.0
0.30
1
12/08/2316:51
100-41-4
ND
ug/L
5.0
0.48
1
12/08/2316:51
591-78-6
ND
ug/L
20.0
9.7
1
12/08/2316:51
74-88-4
ND
ug/L
5.0
2.0
1
12/08/2316:51
75-09-2
ND
ug/L
5.0
2.7
1
12/08/2316:51
108-10-1
ND
ug/L
1.0
0.29
1
12/08/2316:51
100-42-5
ND
ug/L
1.0
0.31
1
12/08/2316:51
630-20-6
ND
ug/L
1.0
0.22
1
12/08/2316:51
79-34-5
ND
ug/L
1.0
0.29
1
12/08/2316:51
127-18-4
ND
ug/L
1.0
0.24
1
12/08/2316:51
108-88-3
ND
ug/L
1.0
0.33
1
12/08/2316:51
71-55-6
ND
ug/L
1.0
0.32
1
12/08/2316:51
79-00-5
ND
ug/L
1.0
0.38
1
12/08/2316:51
79-01-6
ND
ug/L
1.0
0.30
1
12/08/2316:51
75-69-4
ND
ug/L
1.0
0.26
1
12/08/2316:51
96-18-4
ND
ug/L
2.0
1.3
1
12/08/2316:51
108-05-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
Page 43 of 60

ace
Pace Analytical Services, LLC
POWWOWe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Sample: MNS_FD-20231204-1
Lab ID:
92702270018 Collected:
12/04/23 00:00
Received: 12/06/23 14:00 Matrix: Water
Parameters
Results
Units PQL
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
Vinyl chloride
ND
ug/L 1.0
0.39 1
12/08/23 16:51
75-01-4
Xylene (Total)
ND
ug/L 1.0
0.34 1
12/08/23 16:51
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
100
% 70-130
1
12/08/23 16:51
460-00-4
1,2-Dichloroethane-d4 (S)
100
% 70-130
1
12/08/23 16:51
17060-07-0
Toluene-d8 (S)
100
% 70-130
1
12/08/23 16:51
2037-26-5
Date: 12/28/2023 02:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 44 of 60

ace
Pace Analytical Services, LLC
p36R0 t�ir6fy�e. Suite 100
��JJ Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
QC Batch: 818019 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92702270001, 92702270002, 92702270003, 92702270004, 92702270005, 92702270006, 92702270007,
92702270008
METHOD BLANK: 4234350
Matrix: Water
Associated Lab Samples: 92702270001, 92702270002, 92702270003, 92702270004, 92702270005, 92702270006, 92702270007,
92702270008
Parameter
Units
Blank
Result
Reporting
Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
12/08/23 03:02
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
12/08/23 03:02
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
12/08/23 03:02
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
12/08/23 03:02
1,1-Dichloroethane
ug/L
ND
1.0
0.37
12/08/23 03:02
1,1-Dichloroethene
ug/L
ND
1.0
0.35
12/08/23 03:02
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
12/08/23 03:02
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
12/08/23 03:02
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
12/08/23 03:02
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
12/08/23 03:02
1,2-Dichloroethane
ug/L
ND
1.0
0.32
12/08/23 03:02
1,2-Dichloropropane
ug/L
ND
1.0
0.36
12/08/23 03:02
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
12/08/23 03:02
2-Butanone (MEK)
ug/L
ND
5.0
4.0
12/08/23 03:02
2-Hexanone
ug/L
ND
5.0
0.48
12/08/23 03:02
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
12/08/23 03:02
Acetone
ug/L
ND
25.0
5.1
12/08/23 03:02
Acrylonitrile
ug/L
ND
10.0
1.8
12/08/23 03:02
Benzene
ug/L
ND
1.0
0.34
12/08/23 03:02
Bromochloromethane
ug/L
ND
1.0
0.47
12/08/23 03:02
Bromodichloromethane
ug/L
ND
1.0
0.31
12/08/23 03:02
Bromoform
ug/L
ND
1.0
0.34
12/08/23 03:02
Bromomethane
ug/L
ND
2.0
1.7
12/08/23 03:02
Carbon disulfide
ug/L
ND
2.0
0.36
12/08/23 03:02
Carbon tetrachloride
ug/L
ND
1.0
0.33
12/08/23 03:02
Chlorobenzene
ug/L
ND
1.0
0.28
12/08/23 03:02
Chloroethane
ug/L
ND
1.0
0.65
12/08/23 03:02
Chloroform
ug/L
ND
1.0
0.43
12/08/23 03:02
Chloromethane
ug/L
ND
1.0
0.54
12/08/23 03:02
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
12/08/23 03:02
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
12/08/23 03:02
Dibromochloromethane
ug/L
ND
1.0
0.36
12/08/23 03:02
Dibromomethane
ug/L
ND
1.0
0.39
12/08/23 03:02
Ethylbenzene
ug/L
ND
1.0
0.30
12/08/23 03:02
lodomethane
ug/L
ND
20.0
9.7
12/08/23 03:02
Methylene Chloride
ug/L
ND
5.0
2.0
12/08/23 03:02
Styrene
ug/L
ND
1.0
0.29
12/08/23 03:02
Tetrachloroethene
ug/L
ND
1.0
0.29
12/08/23 03:02
Toluene
ug/L
ND
1.0
0.24
12/08/23 03:02
v2
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/28/2023 02:27 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 60

ace
Pace Analytical Services, LLC
POWWOWe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
METHOD BLANK: 4234350 Matrix: Water
Associated Lab Samples: 92702270001, 92702270002, 92702270003, 92702270004, 92702270005, 92702270006, 92702270007,
92702270008
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
12/08/23 03:02
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
12/08/23 03:02
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
12/08/23 03:02
Trichloroethene
ug/L
ND
1.0
0.38
12/08/23 03:02
Trichlorofluoromethane
ug/L
ND
1.0
0.30
12/08/23 03:02
Vinyl acetate
ug/L
ND
2.0
1.3
12/08/23 03:02 v2
Vinyl chloride
ug/L
ND
1.0
0.39
12/08/23 03:02
Xylene (Total)
ug/L
ND
1.0
0.34
12/08/23 03:02
1,2-Dichloroethane-d4 (S)
%
91
70-130
12/08/23 03:02
4-Bromofluorobenzene (S)
%
98
70-130
12/08/23 03:02
Toluene-d8 (S)
%
103
70-130
12/08/23 03:02
LABORATORY CONTROL SAMPLE:
Parameter
4234351
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
20
21.7
109
70-130
1,1,1-Trichloroethane
ug/L
20
19.9
99
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
20.6
103
70-130
1,1,2-Trichloroethane
ug/L
20
20.6
103
70-130
1,1-Dichloroethane
ug/L
20
18.6
93
70-130
1,1-Dichloroethene
ug/L
20
19.4
97
69-131
1,2,3-Trichloropropane
ug/L
20
19.8
99
70-130
1,2-Dibromo-3-chloropropane
ug/L
20
21.9
109
70-130
1,2-Dibromoethane (EDB)
ug/L
20
21.3
106
70-130
1,2-Dichlorobenzene
ug/L
20
21.1
106
70-130
1,2-Dichloroethane
ug/L
20
19.3
96
70-130
1,2-Dichloropropane
ug/L
20
19.1
95
70-130
1,4-Dichlorobenzene
ug/L
20
21.3
106
70-130
2-Butanone (MEK)
ug/L
40
38.3
96
67-133
2-Hexanone
ug/L
40
43.4
109
70-133
4-Methyl-2-pentanone (MIBK)
ug/L
40
40.5
101
70-130
Acetone
ug/L
40
37.7
94
67-130
Acrylonitrile
ug/L
100
93.1
93
70-130
Benzene
ug/L
20
19.9
99
70-130
Bromochloromethane
ug/L
20
19.6
98
70-130
Bromodichloromethane
ug/L
20
19.3
96
70-130
Bromoform
ug/L
20
22.1
111
70-133
Bromomethane
ug/L
20
21.0
105
41-148 v3
Carbon disulfide
ug/L
20
19.7
98
70-131
Carbon tetrachloride
ug/L
20
20.4
102
70-130
Chlorobenzene
ug/L
20
20.7
104
70-130
Chloroethane
ug/L
20
20.3
101
41-157
Chloroform
ug/L
20
20.0
100
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/28/2023 02:27 PM without the written consent of Pace Analytical Services, LLC. Page 46 of 60

ace
Pace Analytical Services, LLC
POWWOWe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
LABORATORY CONTROL SAMPLE:
Parameter
4234351
Units
Spike LCS
Conc. Result
Chloromethane
ug/L
20
cis-1,2-Dichloroethene
ug/L
20
cis-1,3-Dichloropropene
ug/L
20
Dibromochloromethane
ug/L
20
Dibromomethane
ug/L
20
Ethylbenzene
ug/L
20
lodomethane
ug/L
40
Methylene Chloride
ug/L
20
Styrene
ug/L
20
Tetrachloroethene
ug/L
20
Toluene
ug/L
20
trans-1,2-Dichloroethene
ug/L
20
trans- 1,3-Dichloropropene
ug/L
20
trans-1,4-Dichloro-2-butene
ug/L
20
Trichloroethene
ug/L
20
Trichlorofluoromethane
ug/L
20
Vinyl acetate
ug/L
40
Vinyl chloride
ug/L
20
Xylene (Total)
ug/L
60
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
LCS
% Rec
% Rec
Limits Qualifiers
17.3
87
59-141
18.6
93
70-130
20.0
100
70-130
21.7
108
70-130
21.1
106
70-130
20.1
101
70-130
40.3
101
57-140
17.1
85
62-130
21.1
106
70-130
20.1
100
70-130
19.7
98
70-130
18.6
93
70-130
20.3
102
70-130
22.0
110
57-149
21.6
108
70-130
20.7
104
57-130
34.1
85
70-141 v3
16.6
83
66-140
62.0
103
70-130
94
70-130
99
70-130
96
70-130
MATRIX SPIKE SAMPLE:
Parameter
4234352
Units
92702270001
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
23.2
116
70-146
1,1,1-Trichloroethane
ug/L
ND
20
23.9
120
70-150
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20.2
101
66-144
1,1,2-Trichloroethane
ug/L
ND
20
21.9
109
70-142
1,1-Dichloroethane
ug/L
ND
20
20.8
104
68-150
1,1-Dichloroethene
ug/L
ND
20
23.1
116
64-162
1,2,3-Trichloropropane
ug/L
ND
20
19.7
99
66-144
1,2-Dibromo-3-chloropropane
ug/L
ND
20
19.9
99
62-146
1,2-Dibromoethane (EDB)
ug/L
ND
20
21.0
105
70-143
1,2-Dichlorobenzene
ug/L
ND
20
22.2
111
70-142
1,2-Dichloroethane
ug/L
ND
20
21.6
108
68-145
1,2-Dichloropropane
ug/L
ND
20
20.7
104
70-144
1,4-Dichlorobenzene
ug/L
ND
20
21.7
109
70-140
2-Butanone (MEK)
ug/L
ND
40
39.0
97
57-156
2-Hexanone
ug/L
ND
40
39.2
98
62-153
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
39.4
99
65-144
Acetone
ug/L
ND
40
38.7
95
49-162
Acrylonitrile
ug/L
ND
100
95.4
95
59-155
Benzene
ug/L
ND
20
22.1
110
68-144
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/28/2023 02:27 PM without the written consent of Pace Analytical Services, LLC. Page 47 of 60

ace
Pace Analytical Services, LLC
PdagohrwOWe. Suite 100
�J Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
MATRIX SPIKE SAMPLE:
4234352
92702270001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Bromochloromethane
ug/L
ND
20
21.7
108
70-148
Bromodichloromethane
ug/L
ND
20
22.0
110
70-141
Bromoform
ug/L
ND
20
22.7
114
59-144
Bromomethane
ug/L
ND
20
22.5
113
23-190
Carbon disulfide
ug/L
ND
20
22.9
115
64-160
Carbon tetrachloride
ug/L
ND
20
25.6
128
70-147
Chlorobenzene
ug/L
ND
20
22.1
110
70-143
Chloroethane
ug/L
ND
20
23.5
117
55-190
Chloroform
ug/L
ND
20
22.3
112
67-148
Chloromethane
ug/L
ND
20
20.1
101
38-180
cis-1,2-Dichloroethene
ug/L
ND
20
20.7
104
67-151
cis-1,3-Dichloropropene
ug/L
ND
20
21.4
107
70-142
Dibromochloromethane
ug/L
ND
20
22.5
112
68-140
Dibromomethane
ug/L
ND
20
22.8
114
70-142
Ethylbenzene
ug/L
ND
20
21.8
109
70-145
lodomethane
ug/L
ND
40
47.6
119
37-160
Methylene Chloride
ug/L
ND
20
18.5
92
54-149
Styrene
ug/L
ND
20
22.3
111
70-147
Tetrachloroethene
ug/L
ND
20
22.4
112
70-145
Toluene
ug/L
ND
20
22.1
110
65-146
trans-1,2-Dichloroethene
ug/L
ND
20
21.7
109
69-155
trans- 1,3-Dichloropropene
ug/L
ND
20
22.7
113
70-142
trans-1,4-Dichloro-2-butene
ug/L
ND
20
19.5
98
39-149
Trichloroethene
ug/L
ND
20
23.8
119
70-152
Trichlorofluoromethane
ug/L
ND
20
27.3
136
60-158
Vinyl acetate
ug/L
ND
40
34.8
87
56-157
Vinyl chloride
ug/L
ND
20
19.6
98
51-178
Xylene (Total)
ug/L
ND
60
66.3
111
70-146
1,2-Dichloroethane-d4 (S)
%
100
70-130
4-Bromofluorobenzene (S)
%
97
70-130
Toluene-d8 (S)
%
97
70-130
SAMPLE DUPLICATE: 4234353
Parameter
Units
92702270002
Result
Dup
Result RPD
Max
RPD Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,1-Trichloroethane
ug/L
ND
ND
30
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,2-Trichloroethane
ug/L
ND
ND
30
1,1-Dichloroethane
ug/L
ND
ND
30
1,1-Dichloroethene
ug/L
ND
ND
30
1,2,3-Trichloropropane
ug/L
ND
ND
30
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
30
1,2-Dibromoethane (EDB)
ug/L
ND
ND
30
1,2-Dichlorobenzene
ug/L
ND
ND
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/28/2023 02:27 PM without the written consent of Pace Analytical Services, LLC. Page 48 of 60

ace
Pace Analytical Services, LLC
POWWOWe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
SAMPLE DUPLICATE: 4234353
Parameter
Units
92702270002
Result
Dup
Result RPD
Max
RPD
1,2-Dichloroethane
ug/L
ND
ND
30
1,2-Dichloropropane
ug/L
ND
ND
30
1,4-Dichlorobenzene
ug/L
ND
ND
30
2-Butanone (MEK)
ug/L
ND
ND
30
2-Hexanone
ug/L
ND
ND
30
4-Methyl-2-pentanone (MIBK)
ug/L
ND
ND
30
Acetone
ug/L
ND
ND
30
Acrylonitrile
ug/L
ND
ND
30
Benzene
ug/L
ND
ND
30
Bromochloromethane
ug/L
ND
ND
30
Bromodichloromethane
ug/L
ND
ND
30
Bromoform
ug/L
ND
ND
30
Bromomethane
ug/L
ND
ND
30
Carbon disulfide
ug/L
ND
ND
30
Carbon tetrachloride
ug/L
ND
ND
30
Chlorobenzene
ug/L
ND
ND
30
Chloroethane
ug/L
ND
ND
30
Chloroform
ug/L
ND
ND
30
Chloromethane
ug/L
ND
ND
30
cis-1,2-Dichloroethene
ug/L
ND
ND
30
cis-1,3-Dichloropropene
ug/L
ND
ND
30
Dibromochloromethane
ug/L
ND
ND
30
Dibromomethane
ug/L
ND
ND
30
Ethylbenzene
ug/L
ND
ND
30
lodomethane
ug/L
ND
ND
30
Methylene Chloride
ug/L
ND
ND
30
Styrene
ug/L
ND
ND
30
Tetrachloroethene
ug/L
ND
ND
30
Toluene
ug/L
ND
ND
30
trans-1,2-Dichloroethene
ug/L
ND
ND
30
trans- 1,3-Dichloropropene
ug/L
ND
ND
30
trans-1,4-Dichloro-2-butene
ug/L
ND
ND
30
Trichloroethene
ug/L
ND
ND
30
Trichlorofluoromethane
ug/L
ND
ND
30
Vinyl acetate
ug/L
ND
ND
30
Vinyl chloride
ug/L
ND
ND
30
Xylene (Total)
ug/L
ND
ND
30
1,2-Dichloroethane-d4 (S)
%
91
98
4-Bromofluorobenzene (S)
%
97
99
Toluene-d8 (S)
%
100
103
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/28/2023 02:27 PM without the written consent of Pace Analytical Services, LLC.
Page 49 of 60

ace
Pace Analytical Services, LLC
Pd8R0gfir6fggre. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
QC Batch: 818022 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92702270009,92702270010,92702270011,92702270012,92702270013,92702270014,92702270015,
92702270016,92702270017,92702270018
METHOD BLANK: 4234436 Matrix: Water
Associated Lab Samples: 92702270009,92702270010,92702270011,92702270012,92702270013,92702270014,92702270015,
92702270016,92702270017,92702270018
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
12/08/23 13:13
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
12/08/23 13:13
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
12/08/23 13:13
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
12/08/23 13:13
1,1-Dichloroethane
ug/L
ND
1.0
0.37
12/08/23 13:13
1,1-Dichloroethene
ug/L
ND
1.0
0.35
12/08/23 13:13
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
12/08/23 13:13
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
12/08/23 13:13
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
12/08/23 13:13
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
12/08/23 13:13
1,2-Dichloroethane
ug/L
ND
1.0
0.32
12/08/23 13:13
1,2-Dichloropropane
ug/L
ND
1.0
0.36
12/08/23 13:13
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
12/08/23 13:13
2-Butanone (MEK)
ug/L
ND
5.0
4.0
12/08/23 13:13
2-Hexanone
ug/L
ND
5.0
0.48
12/08/23 13:13
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
12/08/23 13:13
Acetone
ug/L
ND
25.0
5.1
12/08/23 13:13
Acrylonitrile
ug/L
ND
10.0
1.8
12/08/23 13:13
Benzene
ug/L
ND
1.0
0.34
12/08/23 13:13
Bromochloromethane
ug/L
ND
1.0
0.47
12/08/23 13:13
Bromodichloromethane
ug/L
ND
1.0
0.31
12/08/23 13:13
Bromoform
ug/L
ND
1.0
0.34
12/08/23 13:13
Bromomethane
ug/L
ND
2.0
1.7
12/08/23 13:13
Carbon disulfide
ug/L
ND
2.0
0.36
12/08/23 13:13
Carbon tetrachloride
ug/L
ND
1.0
0.33
12/08/23 13:13
Chlorobenzene
ug/L
ND
1.0
0.28
12/08/23 13:13
Chloroethane
ug/L
ND
1.0
0.65
12/08/23 13:13
Chloroform
ug/L
ND
1.0
0.43
12/08/23 13:13
Chloromethane
ug/L
ND
1.0
0.54
12/08/23 13:13
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
12/08/23 13:13
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
12/08/23 13:13
Dibromochloromethane
ug/L
ND
1.0
0.36
12/08/23 13:13
Dibromomethane
ug/L
ND
1.0
0.39
12/08/23 13:13
Ethylbenzene
ug/L
ND
1.0
0.30
12/08/23 13:13
lodomethane
ug/L
ND
20.0
9.7
12/08/23 13:13
Methylene Chloride
ug/L
ND
5.0
2.0
12/08/23 13:13
Styrene
ug/L
ND
1.0
0.29
12/08/23 13:13
Tetrachloroethene
ug/L
ND
1.0
0.29
12/08/23 13:13
Toluene
ug/L
ND
1.0
0.24
12/08/23 13:13
v2
v2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/28/2023 02:27 PM without the written consent of Pace Analytical Services, LLC. Page 50 of 60

ace
Pace Analytical Services, LLC
POWWOWe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
METHOD BLANK: 4234436 Matrix: Water
Associated Lab Samples: 92702270009,92702270010,92702270011,92702270012,92702270013,92702270014,92702270015,
92702270016,92702270017,92702270018
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
12/08/23 13:13
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
12/08/23 13:13
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
12/08/23 13:13
Trichloroethene
ug/L
ND
1.0
0.38
12/08/23 13:13
Trichlorofluoromethane
ug/L
ND
1.0
0.30
12/08/23 13:13
Vinyl acetate
ug/L
ND
2.0
1.3
12/08/23 13:13
Vinyl chloride
ug/L
ND
1.0
0.39
12/08/23 13:13
Xylene (Total)
ug/L
ND
1.0
0.34
12/08/23 13:13
1,2-Dichloroethane-d4 (S)
%
98
70-130
12/08/23 13:13
4-Bromofluorobenzene (S)
%
98
70-130
12/08/23 13:13
Toluene-d8 (S)
%
99
70-130
12/08/23 13:13
LABORATORY CONTROL SAMPLE:
Parameter
4234437
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
20
19.7
99
70-130
1,1,1-Trichloroethane
ug/L
20
19.5
98
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
20.0
100
70-130
1,1,2-Trichloroethane
ug/L
20
19.7
99
70-130
1,1-Dichloroethane
ug/L
20
19.4
97
70-130
1,1-Dichloroethene
ug/L
20
20.5
103
69-131
1,2,3-Trichloropropane
ug/L
20
20.2
101
70-130
1,2-Dibromo-3-chloropropane
ug/L
20
19.0
95
70-130
1,2-Dibromoethane (EDB)
ug/L
20
19.3
97
70-130
1,2-Dichlorobenzene
ug/L
20
20.1
101
70-130
1,2-Dichloroethane
ug/L
20
19.1
96
70-130
1,2-Dichloropropane
ug/L
20
20.1
100
70-130
1,4-Dichlorobenzene
ug/L
20
20.0
100
70-130
2-Butanone (MEK)
ug/L
40
38.2
95
67-133
2-Hexanone
ug/L
40
39.6
99
70-133
4-Methyl-2-pentanone (MIBK)
ug/L
40
39.8
100
70-130
Acetone
ug/L
40
39.1
98
67-130
Acrylonitrile
ug/L
100
101
101
70-130
Benzene
ug/L
20
19.7
99
70-130
Bromochloromethane
ug/L
20
19.4
97
70-130
Bromodichloromethane
ug/L
20
19.0
95
70-130
Bromoform
ug/L
20
18.5
93
70-133
Bromomethane
ug/L
20
15.9
79
41-148 v3
Carbon disulfide
ug/L
20
20.5
103
70-131
Carbon tetrachloride
ug/L
20
19.7
99
70-130
Chlorobenzene
ug/L
20
19.7
99
70-130
Chloroethane
ug/L
20
21.4
107
41-157
Chloroform
ug/L
20
19.3
97
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/28/2023 02:27 PM without the written consent of Pace Analytical Services, LLC. Page 51 of 60

ace
Pace Analytical Services, LLC
POWWOWe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
LABORATORY CONTROL SAMPLE:
Parameter
4234437
Units
Spike LCS
Conc. Result
Chloromethane
ug/L
20
cis-1,2-Dichloroethene
ug/L
20
cis-1,3-Dichloropropene
ug/L
20
Dibromochloromethane
ug/L
20
Dibromomethane
ug/L
20
Ethylbenzene
ug/L
20
lodomethane
ug/L
40
Methylene Chloride
ug/L
20
Styrene
ug/L
20
Tetrachloroethene
ug/L
20
Toluene
ug/L
20
trans-1,2-Dichloroethene
ug/L
20
trans- 1,3-Dichloropropene
ug/L
20
trans-1,4-Dichloro-2-butene
ug/L
20
Trichloroethene
ug/L
20
Trichlorofluoromethane
ug/L
20
Vinyl acetate
ug/L
40
Vinyl chloride
ug/L
20
Xylene (Total)
ug/L
60
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
LCS
% Rec
% Rec
Limits Qualifiers
17.6
88
59-141
19.9
99
70-130
19.2
96
70-130
18.4
92
70-130
19.1
95
70-130
19.5
97
70-130
29.7
74
57-140 v3
17.1
86
62-130
19.7
99
70-130
18.7
93
70-130
19.7
98
70-130
20.0
100
70-130
18.8
94
70-130
21.1
105
57-149
20.0
100
70-130
21.1
105
57-130
39.5
99
70-141
19.4
97
66-140
58.8
98
70-130
100
70-130
99
70-130
101
70-130
MATRIX SPIKE SAMPLE:
Parameter
4234438
Units
92702270012
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
28.0
140
70-146
1,1,1-Trichloroethane
ug/L
ND
20
27.8
139
70-150
1,1,2,2-Tetrachloroethane
ug/L
ND
20
25.4
127
66-144
1,1,2-Trichloroethane
ug/L
ND
20
25.8
129
70-142
1,1-Dichloroethane
ug/L
ND
20
24.3
122
68-150
1,1-Dichloroethene
ug/L
ND
20
27.0
135
64-162
1,2,3-Trichloropropane
ug/L
ND
20
25.0
125
66-144
1,2-Dibromo-3-chloropropane
ug/L
ND
20
27.0
135
62-146
1,2-Dibromoethane (EDB)
ug/L
ND
20
26.0
130
70-143
1,2-Dichlorobenzene
ug/L
ND
20
25.9
130
70-142
1,2-Dichloroethane
ug/L
ND
20
25.3
126
68-145
1,2-Dichloropropane
ug/L
ND
20
24.5
122
70-144
1,4-Dichlorobenzene
ug/L
ND
20
26.3
132
70-140
2-Butanone (MEK)
ug/L
ND
40
50.0
125
57-156
2-Hexanone
ug/L
ND
40
51.3
128
62-153
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
49.2
123
65-144
Acetone
ug/L
ND
40
47.7
114
49-162
Acrylonitrile
ug/L
ND
100
115
115
59-155
Benzene
ug/L
ND
20
26.2
131
68-144
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/28/2023 02:27 PM without the written consent of Pace Analytical Services, LLC. Page 52 of 60

ace
Pace Analytical Services, LLC
P98 M,r6fY4re. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
MATRIX SPIKE SAMPLE:
4234438
92702270012
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Bromochloromethane
ug/L
ND
20
25.9
130
70-148
Bromodichloromethane
ug/L
ND
20
26.0
130
70-141
Bromoform
ug/L
ND
20
27.3
136
59-144
Bromomethane
ug/L
ND
20
24.0
120
23-190
Carbon disulfide
ug/L
ND
20
25.9
130
64-160
Carbon tetrachloride
ug/L
ND
20
29.4
147
70-147
Chlorobenzene
ug/L
ND
20
27.0
135
70-143
Chloroethane
ug/L
ND
20
26.7
133
55-190
Chloroform
ug/L
ND
20
24.7
124
67-148
Chloromethane
ug/L
ND
20
22.9
115
38-180
cis-1,2-Dichloroethene
ug/L
ND
20
24.3
121
67-151
cis-1,3-Dichloropropene
ug/L
ND
20
25.7
128
70-142
Dibromochloromethane
ug/L
ND
20
27.3
137
68-140
Dibromomethane
ug/L
ND
20
27.0
135
70-142
Ethylbenzene
ug/L
ND
20
26.4
132
70-145
lodomethane
ug/L
ND
40
54.9
137
37-160
Methylene Chloride
ug/L
ND
20
21.5
107
54-149
Styrene
ug/L
ND
20
26.7
134
70-147
Tetrachloroethene
ug/L
ND
20
27.2
136
70-145
Toluene
ug/L
ND
20
25.7
128
65-146
trans-1,2-Dichloroethene
ug/L
ND
20
25.3
127
69-155
trans- 1,3-Dichloropropene
ug/L
ND
20
26.6
133
70-142
trans-1,4-Dichloro-2-butene
ug/L
ND
20
16.9
84
39-149
Trichloroethene
ug/L
ND
20
29.2
146
70-152
Trichlorofluoromethane
ug/L
ND
20
31.5
158
60-158
Vinyl acetate
ug/L
ND
40
41.7
104
56-157
Vinyl chloride
ug/L
ND
20
22.7
113
51-178
Xylene (Total)
ug/L
ND
60
79.8
133
70-146
1,2-Dichloroethane-d4 (S)
%
101
70-130
4-Bromofluorobenzene (S)
%
98
70-130
Toluene-d8 (S)
%
95
70-130
SAMPLE DUPLICATE: 4234439
Parameter
Units
92702270013
Result
Dup
Result RPD
Max
RPD Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,1-Trichloroethane
ug/L
ND
ND
30
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,2-Trichloroethane
ug/L
ND
ND
30
1,1-Dichloroethane
ug/L
ND
ND
30
1,1-Dichloroethene
ug/L
ND
ND
30
1,2,3-Trichloropropane
ug/L
ND
ND
30
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
30
1,2-Dibromoethane (EDB)
ug/L
ND
ND
30
1,2-Dichlorobenzene
ug/L
ND
ND
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/28/2023 02:27 PM without the written consent of Pace Analytical Services, LLC. Page 53 of 60

ace
Pace Analytical Services, LLC
POWWOWe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
SAMPLE DUPLICATE: 4234439
Parameter
Units
92702270013
Result
Dup
Result RPD
Max
RPD
1,2-Dichloroethane
ug/L
ND
ND
30
1,2-Dichloropropane
ug/L
ND
ND
30
1,4-Dichlorobenzene
ug/L
ND
ND
30
2-Butanone (MEK)
ug/L
ND
ND
30
2-Hexanone
ug/L
ND
ND
30
4-Methyl-2-pentanone (MIBK)
ug/L
ND
ND
30
Acetone
ug/L
ND
ND
30
Acrylonitrile
ug/L
ND
ND
30
Benzene
ug/L
ND
ND
30
Bromochloromethane
ug/L
ND
ND
30
Bromodichloromethane
ug/L
ND
ND
30
Bromoform
ug/L
ND
ND
30
Bromomethane
ug/L
ND
ND
30
Carbon disulfide
ug/L
ND
ND
30
Carbon tetrachloride
ug/L
ND
ND
30
Chlorobenzene
ug/L
ND
ND
30
Chloroethane
ug/L
ND
ND
30
Chloroform
ug/L
ND
ND
30
Chloromethane
ug/L
ND
ND
30
cis-1,2-Dichloroethene
ug/L
ND
ND
30
cis-1,3-Dichloropropene
ug/L
ND
ND
30
Dibromochloromethane
ug/L
ND
ND
30
Dibromomethane
ug/L
ND
ND
30
Ethylbenzene
ug/L
ND
ND
30
lodomethane
ug/L
ND
ND
30
Methylene Chloride
ug/L
ND
ND
30
Styrene
ug/L
ND
ND
30
Tetrachloroethene
ug/L
ND
ND
30
Toluene
ug/L
ND
ND
30
trans-1,2-Dichloroethene
ug/L
ND
ND
30
trans- 1,3-Dichloropropene
ug/L
ND
ND
30
trans-1,4-Dichloro-2-butene
ug/L
ND
ND
30
Trichloroethene
ug/L
ND
ND
30
Trichlorofluoromethane
ug/L
ND
ND
30
Vinyl acetate
ug/L
ND
ND
30
Vinyl chloride
ug/L
ND
ND
30
Xylene (Total)
ug/L
ND
ND
30
1,2-Dichloroethane-d4 (S)
%
100
97
4-Bromofluorobenzene (S)
%
98
98
Toluene-d8 (S)
%
100
105
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/28/2023 02:27 PM without the written consent of Pace Analytical Services, LLC.
Page 54 of 60

ace
Pace Analytical Services, LLC
p36RVir6fy�e. Suite 100
��JJ Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
CO Result confirmed by second analysis.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/28/2023 02:27 PM without the written consent of Pace Analytical Services, LLC. Page 55 of 60

ace
Pace Analytical Services, LLC
POWWOWe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J23110327 MNS Landfill
Pace Project No.: 92702270
Lab ID Sample ID QC Batch Method QC Batch
92702270001
MW-5R
EPA 8260D
818019
92702270002
MW-5A
EPA 8260D
818019
92702270003
MW-6
EPA 8260D
818019
92702270004
MW-6A
EPA 8260D
818019
92702270005
MW-7R
EPA 8260D
818019
92702270006
MW-7A
EPA 8260D
818019
92702270007
MW-8
EPA 8260D
818019
92702270008
MW-8A
EPA 8260D
818019
92702270009
MW-9
EPA 8260D
818022
92702270010
MW-9A
EPA 8260D
818022
92702270011
MW-10A
EPA 8260D
818022
92702270012
SW-1
EPA 8260D
818022
92702270013
SW-2
EPA 8260D
818022
92702270014
LEACHATE POND
EPA 8260D
818022
92702270015
MNS_FB-20231204-1030
EPA 8260D
818022
92702270016
MNS_FB-20231205-1400
EPA 8260D
818022
92702270017
MNS_TB-20241204-0800
EPA 8260D
818022
92702270018
MNS FD-20231204-1
EPA 8260D
818022
Date: 12/28/2023 02:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical Method
Analytical
Batch
Page 56 of 60

,lace DC#_Title: ENV-FRM-HUN1-0083 v03_Sample Condition Upon Receipt
Page 88 of 148
Effective Date: 11/29/2023 4:16:30 PM
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville K Raleigh[] Mechanicsville❑ Atlanta❑ Kernersville❑
Client Name:
Upon WO# : 92702270
Sample �ltl�L � ryip (` t Project ii: Courier:❑x EJ
UP Client
Commercial Pace Other: 1111111111111111111111
92702270
Custody Sea] Present? ��es ❑ No Seats Intact? es [IN. ❑ N/A nj /J
Date{Initials Person Examining content (/ `s�C—
Packing Material: ❑ Bubble Wrap E5Bubble Bags ❑ None ❑ Other Biological Tissuefrozen?
Thermom er: (� /�] []Yes ❑ No KI N/A
IR Gun ID: " �Y/ Type of Ice: LJ Wet ❑ Blue ❑ None
Correction Factor: �O
Cooler Temp: 7 I Add/Su�btract (°C) f
Cooler Temp Corrected (�j! I, -I jI,
USDA Regulated Soil ( e N/A, water sample}
Did samples originate in a quarantine zone within the United States: CA, NY, or SC
lrho 1, -I? IT1Ywc 11 Nn
Temp should be above freezing to VC
❑ Samples out of temp criteria. Samples on ice, cooling process
has begun
Did samples originate from a foreign source (internationally,
including Hawaii and Puerto Rico)? ❑ Yes ❑ No
Comments/Discrepancy:
Chain of Custody Present?
Y s
❑ No
] N/A
1.
Samples Arrived within Hold Time?
Yes
❑ No
❑ N/A
2.
Short Hold Time Analysis (c72 hr.)?
❑Yes
1No
[IN/A
3.
Rush Turn Around Time Requested?
ElYes
OK
❑ N/A
4.
Sufficient Volume?
hies
❑No
[I N/A
5,
Correct Containers Used?
-Pace Containers Used?
Yes
9Yes
❑No
❑ No
❑N/A
❑N/A
6.
Containers Intact?
Yes
❑ No
❑ N/A
7.
Dissolved analysis: Samples Field Filtered?
❑Yes
❑No
N/A
B.
Sample Labels Match COC7
-Includes Date/Time/ID/Analysis Matrix:
es
L
❑No
❑N/A
9.
Headspace in VOA Vials (>5-6mm)?
❑Yes
❑ No
A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
❑Yes
❑ Yes
❑Na
❑ No
//A
❑ NIA
11.
COMMENTS/SAMPLE DISCREPANCY
Lot ID of split containers
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Project Manager SRF Review:
Date/Time:
Date:
Date:
Field Data Required? LIYes LJ No
Qualtrax V: 69614 Pape 1 of 2 Page 57 of 60

A uUU
,,:. r<
Effective Date: 11/14/2022
`Check mark top half of box if pH and/or dechlorination is verified and
within the acceptance range for preservation samples.
Exceptions: VOA, Cotiform, TOC, Oil and Grease, DR0/8025 Itivaterf DOC. LLHg
"Bottom half of box is to list number of bottles
••`Check all unpreserved Nitrates for chlorine i
Lge 89 of 148
Project M W0# : 92702270
PM: UP Due Date: 12/13/23
CLIENT: 92-Duke Ener
a
v
a
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pH Adjustment Log for Preserved Samples
5ample ID
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adjusted added
tot It
Note Whenever there Is a discrepancyatlecting North Cafolrna contoliance sanpa.es. a eopy of this lorm will br Sent to the Norttr Carohna DENRCeMROLIOrt Office (r e
Out al hold, Incorrect preservative, out of temp, rncorrecl canlamers.
Qualtrax ID. 691314
Page 2 of 2
Page 58 of 60

Vace
DC#_Title: ENV-FRM-HUN1-0083 v02_Sample Condition Upon Receipt
Effective Date: 11/14/2022
... age 90 of 148
*Check mark top half of box if pH and/or dechlorination is verified and
within the acceptance range for preservation samples.
Exceptions: VOA, Coifform, TOC, Oil and Grease, PRO/8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine 0
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pH Adjustment Log for Preserved Samples
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pH upon receipt
Date preservation adjusted
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added
Lot 4
i
Note: whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DENR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Qualtrax ID: 69614 Page 2 of 2 Page 59 of 60

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM Page 91 of 148
puke Energy Analytical Laboratory i i Ana! Ical LeSorato Use Onl ! Page _1_ of oI
Matrix
DUKE t SafMme740e1 ' Matrix WATER DI57RIBUrI�
-Ift.,Mancae.Mnm
! J23110327 9•mv•.carioru•vFr•m SC
ORIGINALCLIENT (i1pPY to
ENERGY, 13]arNna•nFmryRd j — 10 LAB, nwur.,�uf•, n. c. aeore
Ivoq srsatas ! ?Lceg•d Sy �G aam q, it SAMPLE PROGRAM ;
! r /7J 23 Qq
r._._._._._._._._._._._._._.,._.»._.._---- FPrSi9'R nsao�r._._._._-___i Grcund Water _X� NPDES_
PM1.n.N.: IV•^'r^'•o�..�r..a.....�1.. q Drinking Water UST_
i 3 • "RA
cooler Tsm c RCRA Waste _'
Protect Name MNS LANDFILL #2 PERMIT# 60- i PACE _.._.._.._ ._.._.._.-_.._.._..Ei�._.._......-..-..-..-.._.._.._-._.._.._.._-._.._.._.._.._.. _.._.._.._.._.....-_.._.._
Client Ethan Smith I Bryan Moeller I j p
C.11.yMurph IAshle Healyi �a ���ZaS�Q ' Filtration(0.45um) 0 Unfiltered b Filtered
Operating Unit: Process: BLOFLGN AccounU 6 T es Preservative ICE ICE ICE
i i
Project: Activity to: Facility to: Container Volume {mL) • r r 540 ml 500 mi 1000 ml
coo
Program 1 EC1uiS Task Code: Sub•ProgramlTask Code: Container Type
O u s
I� N N Il
J N V p p Q4 N� a ay4u
Customer to complete all appropriero non -shaded Drees, a m x R4. L b W A a u a h m 4 ar m ui
LLI $ Y a x " " : �
Sample Description or ID b �_ x D 6
H Yl J a A q a
WQ4 LySjX CU JIU LLIU H 2 is �' O G8 ig
i SAMPLE ID i Collection Information c v yi ,G � 0.2 g — y P o B '
4 R t
i NUMBER i Data Time Printed Name Signature u u Y a3—f U m '� L m c4i 4 U u Ci w ti c�i E S
r�
2023028548
MiVS_MW-5H
Z y z s
/
JffOd
X
3
1
1
1
3
2023028549
MNS-MW-SA
?j
[7-06
x
3
1
1
1
3
2023028551)
MNS-MW-6
IV410
1550
giA� 3—" CA-
X
3
1
1
1
3
2023028551 !
MNS_MW-45A
I
l536
S'm"trot
X
3
1
1
1
3
2023028552 !
MNS-MW-7R
1 1 L3
3q5
Sr> t
x
3
1
1
1
3
2023028553 i
MNS-MW-7A
12/`503
y 3@
{,
x
3
1
1
1
3
2023028554
MNS_MW-0
1
O
X
3
1
1
1
3
F 2023028555
MNS-MW-aA
I 73
0
x
3
1
1
1
3
2023028556 k
MNS_MW-9
IZ s Z3
1030
X
3
1
1
1
3
2023028557
MNS_MW-9A
12 5 Z3
UOD
X
3
1
1
1
3
PY
2023028558 !
MNS_MW-1DA
� Z3
1450
� rdice-
X.
3
1
1
1
3
'
i 2023028559 i
MNs_sw-1
�3
�+��{5
6in.w+. 51V�1 1
x
3
1
t
i
3
0
1
1
i 2023r 028560 i
MINIS SW-2
12 s Z3
lly�
�-;tl[DyL rjtt
x
3
1
1
1
3
1
1
2023028561
MNS_LEACHATEPOND
ly 23
1110l
x
3
1
1
1
3
2023028562
MNS_F13-7-02.3I20q- f 03A
IYM3
1036am
ri9i4L
X
3
1
1
1
3
2023028563 r
MNS_FB-Z,013JZ05 - It{d0
(
4f60
81(,t6iij ,-A
X
3
1
1
t
3
Iy
2023028564 !
MNS_Te Z6ZE7�t{�O�dD
i 3
0900
99M Jmr-k-
x
3
3
IVA
j 2023028565 i
MNS_FD-Zdz312o4-1
'�
Sryt>S/i
x
3
1
1
1
3
i
TOTAL 0 CONTAINERS
i54
17
15
2
17
54
0
0
0
2
0 1,
Relin ulshed By
DatolTme
J
Acce
DalalTirpe
j c
u�Y2,q15
T
Requested Turnaroundrr„
Relinquish Hy
Oalel Im
Accepted ey:
OatelTlme
c
21 Days
d �
Relinquished By
Date/Time
Accepted By:
yy t/ef7imo/�,
u
o.
14 Days
2 �. �iGl/
Seal/Locked By
DatelTime
SealadlLock Opened E1YV
Daterrime
r`
ca
"—
"7 Days
E
•— m
Comments
`m
a
'Other
3
U
' Add, Cost Will Apply
otalr

Page 92 of 148
O
( ---- aceAnalytical
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Peggy Kendall
Project Name: MNS Landfill #2 Permit #60-04
Project Number: J23110327
Lot Number:YL08039
Date Completed:01/04/2024
01/04/2024 5:48 PM
Approved and released by:
Project Manager II: Cathy S. Dover
14
ANBi IRHNaA'AnYCdfIRE4w B6wC
A CC BED IT E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 56

Page 93 of 148
PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Duke Energy
Lot Number: YL08039
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information associated
with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where sampling is
conducted by the client, results relate to the accuracy of the information provided, and as the samples are
received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current
approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality
Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the
Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope
of accreditation: E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black,
Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon,
Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006
& SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal Coliform Colilert-18.
1,4-Dioxane SIM 8260D
Reanalysis of the following samples was performed outside of the analytical holding time due to internal
standard failure during the initial analysis: YL08039-001 and YL08039-016.
YL08039-001 (2023028548) (Run 2) (Analysis Batch 92687) only the reanalysis, Run 2 has been reported
since the internals affected the results in the Run 1. The sample met acceptance criteria for the Run 2, except
it was analyzed a day outside of the holding time.
YL08039-016 (2023028563) (Run 2) (Analysis Batch 92687) Both runs have been reported for this sample
Insufficient sample volume was provided to perform matrix spike/matrix spike duplicate (MS/MSD) for analytical
batch 92687. An LCS/LCSD was run in lieu of an MS/MSD.
The laboratory control sample duplicate (LCSD) was out of tune time by 3 minutes in batch 92687 due to
analyst error. The samples affected: YLO8039-001 and YL08039-016. The CCV and LCS associated with batch
92687 passed acceptance criteria, therefore the data has been reported.
YLO8039-001 (2023028548) (Run 2) (Analysis Batch 92687)
YL08039-016 (2023028563) (Run 2) (Analysis Batch 92687)
DRO 8015C
The following samples were collected unpreserved containers and the pH was greater than ph of 2 when
verified by the laboratory: YL08039-001, YL08039-002, YL08039-003, YL08039-004, YL08039-005, YL08039-
006, YL08039-007, YL08039-008, YL08039-009, YL08039-010, YL08039-011, YL08039-012, YL08039-013,
YL08039-014, YL08039-015, YL08039-016, and YL08039-018. Before the extraction, the extraction tech
added HCl to each sample to reach a pH of < 2.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 2 of 56

Page 94 of 148
PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
YL08039-001 (2023028548) (Run 1) (Analysis Batch 92070) (Prep Batch 91934) TPH-DRO (RVE)
YL08039-002 (2023028549) (Run 1) (Analysis Batch 92070) (Prep Batch 91934) TPH-DRO (RVE)
YL08039-003 (2023028550) (Run 1) (Analysis Batch 92070) (Prep Batch 91934) TPH-DRO (RVE)
YL08039-004 (2023028551) (Run 1) (Analysis Batch 92070) (Prep Batch 91934) TPH-DRO (RVE)
YL08039-005 (2023028552) (Run 1) (Analysis Batch 92070) (Prep Batch 91934) TPH-DRO (RVE)
YL08039-006 (2023028553) (Run 1) (Analysis Batch 92070) (Prep Batch 91934) TPH-DRO (RVE)
YL08039-007 (2023028554) (Run 1) (Analysis Batch 92070) (Prep Batch 91934) TPH-DRO (RVE)
YL08039-008 (2023028555) (Run 1) (Analysis Batch 92070) (Prep Batch 91934) TPH-DRO (RVE)
YL08039-009 (2023028556) (Run 1) (Analysis Batch 92070) (Prep Batch 91934) TPH-DRO (RVE)
YL08039-010 (2023028557) (Run 1) (Analysis Batch 92070) (Prep Batch 91934) TPH-DRO (RVE)
YL08039-011 (2023028558) (Run 1) (Analysis Batch 92070) (Prep Batch 91934) TPH-DRO (RVE)
YL08039-012 (2023028559) (Run 1) (Analysis Batch 92070) (Prep Batch 91934) TPH-DRO (RVE)
YL08039-013 (2023028560) (Run 1) (Analysis Batch 92070) (Prep Batch 91934) TPH-DRO (RVE)
YL08039-014 (2023028561) (Run 1) (Analysis Batch 92070) (Prep Batch 91934) TPH-DRO (RVE)
YL08039-015 (2023028562) (Run 1) (Analysis Batch 92070) (Prep Batch 91934) TPH-DRO (RVE)
YL08039-016 (2023028563) (Run 1) (Analysis Batch 92070) (Prep Batch 91934) TPH-DRO (RVE)
YL08039-018 (2023028565) (Run 1) (Analysis Batch 92070) (Prep Batch 91934) TPH-DRO (RVE)
If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover
page.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 56

PACE ANALYTICAL SERVICES, LLC Page 95of148
Sample Summary
Duke Energy
Lot Number: YL08039
Project Name: MNS Landfill #2 Permit #60-04
Project Number: J23110327
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
2023028548
Aqueous
12/04/20231400
12/08/2023
002
2023028549
Aqueous
12/04/20231200
12/08/2023
003
2023028550
Aqueous
12/04/20231550
12/08/2023
004
2023028551
Aqueous
12/04/20231530
12/08/2023
005
2023028552
Aqueous
12/05/20231345
12/08/2023
006
2023028553
Aqueous
12/05/20231305
12/08/2023
007
2023028554
Aqueous
12/04/2023 0930
12/08/2023
008
2023028555
Aqueous
12/04/20231005
12/08/2023
009
2023028556
Aqueous
12/05/20231030
12/08/2023
010
2023028557
Aqueous
12/05/20231000
12/08/2023
011
2023028558
Aqueous
12/04/20231450
12/08/2023
012
2023028559
Aqueous
12/05/20231445
12/08/2023
013
2023028560
Aqueous
12/05/20231140
12/08/2023
014
2023028561
Aqueous
12/04/20231110
12/08/2023
015
2023028562
Aqueous
12/04/20231030
12/08/2023
016
2023028563
Aqueous
12/05/20231400
12/08/2023
017
2023028564
Aqueous
12/04/2023 0800
12/08/2023
018
2023028565
Aqueous
12/04/2023
12/08/2023
(18 samples)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 56

PACE ANALYTICAL SERVICES,
LLC
Page 96of148
Detection Summary
Duke Energy
Lot Number: YL08039
Project Name: MNS Landfill #2 Permit #60-04
Project Number: J23110327
Sample Sample ID
Matrix Parameter Method
Result
Q Units Page
014 2023028561
Aqueous TPH-DRO 8015C
4900
ug/L 33
016 2023028563
Aqueous TPH-DRO 8015C
130
J ug/L 38
(2 detections)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 56

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:YL0Pg3g-@9bf 148
Description: 2023028548 Matrix: Aqueous
Date Sampled:12/04/2023 1400 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 5030B 8260D (SIM) 1 12/19/2023 1739 RAD 92687
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND H 3.0 1.0 ug/L 2
Run 2 Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
H 98 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 56

TPH-DRO
Client: Duke Energy Laboratory ID:YL0Pg3g-@gbf 148
Description: 2023028548 Matrix: Aqueous
Date Sampled:12/04/2023 1400 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 12/12/2023 1533 MEZ 12/11/2023 1000 91934
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C ND 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
83 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 56

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:YL0Pg3g-@g20f 148
Description: 2023028549 Matrix: Aqueous
Date Sampled:12/04/2023 1200 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 12/12/2023 1336 DSH 92072
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
92 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 56

TPH-DRO
Client: Duke Energy Laboratory ID:YLH9;4@20f 148
Description: 2023028549 Matrix: Aqueous
Date Sampled:12/04/2023 1200 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 12/12/2023 1601 MEZ 12/11/2023 1000 91934
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C ND 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
85 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 56

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:YLH9;4930f 148
Description: 2023028550 Matrix: Aqueous
Date Sampled:12/04/2023 1550 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 12/12/2023 1400 DSH 92072
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
92 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 56

TPH-DRO
Client: Duke Energy Laboratory ID:YLH9;4 30f 148
Description: 2023028550 Matrix: Aqueous
Date Sampled:12/04/2023 1550 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 12/12/2023 1611 MEZ 12/11/2023 1000 91934
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C ND 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
84 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 11 of 56

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:YLH9;9r®9`bf 148
Description: 2023028551 Matrix: Aqueous
Date Sampled:12/04/2023 1530 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 12/12/2023 1424 DSH 92072
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
86 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 12 of 56

TPH-DRO
Client: Duke Energy Laboratory ID:YLH9;9r®R`bf 148
Description: 2023028551 Matrix: Aqueous
Date Sampled:12/04/2023 1530 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 12/12/2023 1620 MEZ 12/11/2023 1000 91934
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C ND 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
86 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 13 of 56

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:YLH9;49;f 148
Description: 2023028552 Matrix: Aqueous
Date Sampled:12/05/2023 1345 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 12/12/2023 1448 DSH 92072
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
86 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 14 of 56

TPH-DRO
Client: Duke Energy Laboratory ID:YLM9;9r®e;f 148
Description: 2023028552 Matrix: Aqueous
Date Sampled:12/05/2023 1345 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 12/12/2023 1629 MEZ 12/11/2023 1000 91934
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C ND 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
88 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 15 of 56

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:YLH9;9r®966f 148
Description: 2023028553 Matrix: Aqueous
Date Sampled:12/05/2023 1305 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 12/12/2023 1512 DSH 92072
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
84 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 16 of 56

TPH-DRO
Client: Duke Energy Laboratory ID:YLH9;4@60f 148
Description: 2023028553 Matrix: Aqueous
Date Sampled:12/05/2023 1305 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 12/12/2023 1639 MEZ 12/11/2023 1000 91934
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C ND 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
84 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 17 of 56

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:YLH9;4gbf 148
Description: 2023028554 Matrix: Aqueous
Date Sampled:12/04/2023 0930 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 12/12/2023 1536 DSH 92072
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
81 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 18 of 56

TPH-DRO
Client: Duke Energy Laboratory ID:YLM9;9rQ@bf 148
Description: 2023028554 Matrix: Aqueous
Date Sampled:12/04/2023 0930 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 12/12/2023 1648 MEZ 12/11/2023 1000 91934
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C ND 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
86 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 19 of 56

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:YLH9;9r9%f 148
Description: 2023028555 Matrix: Aqueous
Date Sampled:12/04/2023 1005 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 12/12/2023 1600 DSH 92072
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
78 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 20 of 56

TPH-DRO
Client: Duke Energy Laboratory ID:YLH9;9r99l�f 148
Description: 2023028555 Matrix: Aqueous
Date Sampled:12/04/2023 1005 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 12/12/2023 1716 MEZ 12/11/2023 1000 91934
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C ND 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
84 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 21 of 56

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:YLH9;9r99%f 148
Description: 2023028556 Matrix: Aqueous
Date Sampled:12/05/2023 1030 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 12/12/2023 1624 DSH 92072
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
77 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 22 of 56

TPH-DRO
Client: Duke Energy Laboratory ID:YLMB;9r"%f 148
Description: 2023028556 Matrix: Aqueous
Date Sampled:12/05/2023 1030 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 12/12/2023 1726 MEZ 12/11/2023 1000 91934
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C ND 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
85 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 23 of 56

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:YLH9;9r96(61f 148
Description: 2023028557 Matrix: Aqueous
Date Sampled:12/05/2023 1000 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 12/12/2023 1648 DSH 92072
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
76 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 24 of 56

TPH-DRO
Client: Duke Energy Laboratory ID:YLH9;9r9AQ)f 148
Description: 2023028557 Matrix: Aqueous
Date Sampled:12/05/2023 1000 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 12/12/2023 1735 MEZ 12/11/2023 1000 91934
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C ND 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
87 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 25 of 56

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:YLH9;9r9Jtf 148
Description: 2023028558 Matrix: Aqueous
Date Sampled:12/04/2023 1450 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 12/12/2023 1712 DSH 92072
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
76 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 26 of 56

TPH-DRO
Client: Duke Energy Laboratory ID:YLH9;9r9Atf 148
Description: 2023028558 Matrix: Aqueous
Date Sampled:12/04/2023 1450 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 12/12/2023 1745 MEZ 12/11/2023 1000 91934
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C ND 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
85 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 27 of 56

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:YLH9;9r9520f 148
Description: 2023028559 Matrix: Aqueous
Date Sampled:12/05/2023 1445 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 12/12/2023 1736 DSH 92072
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
77 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 28 of 56

TPH-DRO
Client: Duke Energy Laboratory ID:Y11-Mg;9t�820f 148
Description: 2023028559 Matrix: Aqueous
Date Sampled:12/05/2023 1445 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 12/12/2023 1754 MEZ 12/11/2023 1000 91934
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C ND 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
86 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 29 of 56

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:YLH9;9tfl30f 148
Description: 2023028560 Matrix: Aqueous
Date Sampled:12/05/2023 1140 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 12/12/2023 1800 DSH 92072
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
72 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 30 of 56

TPH-DRO
Client: Duke Energy Laboratory ID:Y11-Mg;9t�130f 148
Description: 2023028560 Matrix: Aqueous
Date Sampled:12/05/2023 1140 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 12/12/2023 1803 MEZ 12/11/2023 1000 91934
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C ND 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
88 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 31 of 56

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:YLH9;9t�JJ0f 148
Description: 2023028561 Matrix: Aqueous
Date Sampled:12/04/2023 1110 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 12/12/2023 1825 DSH 92072
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
77 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 32 of 56

TPH-DRO
Client: Duke Energy Laboratory ID:Y11-Mg;9t�4JOf 148
Description: 2023028561 Matrix: Aqueous
Date Sampled:12/04/2023 1110 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 12/12/2023 1813 MEZ 12/11/2023 1000 91934
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C 4900 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
85 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 33 of 56

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:YLH9;9t�6;f 148
Description: 2023028562 Matrix: Aqueous
Date Sampled:12/04/2023 1030 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 12/12/2023 1849 DSH 92072
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
86 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 34 of 56

TPH-DRO
Client: Duke Energy Laboratory ID:YLM9;9rpd;f 148
Description: 2023028562 Matrix: Aqueous
Date Sampled:12/04/2023 1030 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 12/12/2023 1822 MEZ 12/11/2023 1000 91934
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C ND 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
85 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 35 of 56

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:YLH9;9r9J66f 148
Description: 2023028563 Matrix: Aqueous
Date Sampled:12/05/2023 1400 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run
Prep Method
Analytical Method Dilution
Analysis Date Analyst Prep Date
Batch
1
5030B
8260D (SIM) 1
12/13/2023 1309 DSH
92177
2
5030B
8260D (SIM) 1
12/19/2023 1831 RAD
92687
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND Q 3.0 1.0 ug/L 1
Run 1 Acceptance Run 2 Acceptance
Surrogate Q % Recovery Limits Q % Recovery Limits
1,2-Dichloroethane-d4
N 2.4 40-170 96 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 36 of 56

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:Y11-Mg;9t�666f 148
Description: 2023028563 Matrix: Aqueous
Date Sampled:12/05/2023 1400 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run
Prep Method
Analytical Method Dilution
Analysis Date Analyst Prep Date
Batch
1
5030B
8260D (SIM) 1
12/13/2023 1309 DSH
92177
2
5030B
8260D (SIM) 1
12/19/2023 1831 RAD
92687
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 2
Run 1 Acceptance Run 2 Acceptance
Surrogate Q % Recovery Limits Q % Recovery Limits
1,2-Dichloroethane-d4
N 2.4 40-170 96 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 37 of 56

TPH-DRO
Client: Duke Energy Laboratory ID:Y11-Mg;9t�8566f 148
Description: 2023028563 Matrix: Aqueous
Date Sampled:12/05/2023 1400 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 12/12/2023 1832 MEZ 12/11/2023 1000 91934
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C 130 J 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
87 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 38 of 56

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:YLH9;"6bf 148
Description: 2023028564 Matrix: Aqueous
Date Sampled:12/04/2023 0800 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 12/13/2023 1334 DSH 92177
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
59 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 39 of 56

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:YLH9;"%f 148
Description: 2023028565 Matrix: Aqueous
Date Sampled:12/04/2023 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 12/13/2023 1357 DSH 92177
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
65 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 40 of 56

TPH-DRO
Client: Duke Energy Laboratory ID:YLH9;"Jl�f 148
Description: 2023028565 Matrix: Aqueous
Date Sampled:12/04/2023 Project Name: MNS Landfill #2 Permit #60-04
Date Received:12/08/2023 Project Number: J23110327
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 12/12/2023 1841 MEZ 12/11/2023 1000 91934
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C ND 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
87 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 41 of 56

Page 133 of 148
QC Summary
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YL08039
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 42 of 56

Volatile Organic Compounds by GC/MS (SIM) - MB
Paae 134 of 148
Sample ID: YQ92072-001 Matrix: Aqueous
Batch: 92072 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Parameter Result Q Dil LOQ DL Units Analysis Date
1,4-Dioxane ND 1 3.0 1.0 ug/L 12/12/20231048
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
78 40-170
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 43 of 56
QC Data for Lot Number: YL08039

Volatile Organic Compounds by GC/MS (SIM) - LCS
Paae 135 of 148
Sample ID: YQ92072-002 Matrix: Aqueous
Batch: 92072 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
1,4-Dioxane 50 50 1 101 70-130 12/12/2023 0932
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
81 40-170
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 44 of 56
QC Data for Lot Number: YL08039

Volatile Organic Compounds by GC/MS (SIM) - MB
Paae 136 of 148
Sample ID: YQ92177-001 Matrix: Aqueous
Batch: 92177 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Parameter Result Q Dil LOQ DL Units Analysis Date
1,4-Dioxane ND 1 3.0 1.0 ug/L 12/13/20231116
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
79 40-170
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 45 of 56
QC Data for Lot Number: YL08039

Volatile Organic Compounds by GC/MS (SIM) - LCS
Sample ID: YQ92177-002 Matrix: Aqueous
Batch: 92177 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
1,4-Dioxane 50 48 1 96 70-130 12/13/20231001
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
92 40-170
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 46 of 56
QC Data for Lot Number: YL08039

Volatile Organic Compounds by GC/MS (SIM) - MB
Paae 138 of 148
Sample ID: YQ92687-001 Matrix: Aqueous
Batch: 92687 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Parameter Result Q Dil LOQ DL Units Analysis Date
1,4-Dioxane ND 1 3.0 1.0 ug/L 12/19/20231122
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
128 40-170
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 47 of 56
QC Data for Lot Number: YL08039

Volatile Organic Compounds by GC/MS (SIM) - LCS
Sample ID: YQ92687-002 Matrix: Aqueous
Batch: 92687 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
1,4-Dioxane 50 45 1 91 70-130 12/19/2023 0958
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
117 40-170
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 48 of 56
QC Data for Lot Number: YL08039

Volatile Organic Compounds by GC/MS (SIM) - LCSD
Paae 140 of 148
Sample ID: YQ92687-003 Matrix: Aqueous
Batch: 92687 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Spike
Amount Result %Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
1,4-Dioxane 50 49 1 97 6.7 70-130 20 12/19/2023 2119
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
105 40-170
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 49 of 56
QC Data for Lot Number: YL08039

TPH-DRO - MB
Paae 141 of 148
Sample ID: YQ91934-001 Matrix: Aqueous
Batch: 91934 Prep Method: 3520C
Analytical Method: 8015C Prep Date: 12/11/2023 1000
Parameter Result Q Dil LOQ DL Units Analysis Date
TPH-DRO ND 1 200 130 ug/L 12/12/20231505
Surrogate
o - Terphenyl
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
85 53-118
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 50 of 56
QC Data for Lot Number: YL08039

TPH-DRO - LCS
Paae 142 of 148
Sample ID: YQ91934-002
Matrix:
Aqueous
Batch: 91934
Prep Method:
3520C
Analytical Method: 8015C
Prep Date:
12/11/2023 1000
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil
% Rec Limit Analysis Date
TPH-DRO
2000
1800
1
92 70-130 12/12/20231514
Surrogate
Q % Rec
Acceptance
Limit
o - Terphenyl
LOQ = Limit of Quantitation
DL = Detection Limit
94 53-118
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 51 of 56
QC Data for Lot Number: YL08039

TPH-DRO - MS
Sample ID: YL08039-001 MS
Matrix: Aqueous
Batch: 91934
Prep Method: 3520C
Analytical Method: 8015C
Prep Date: 12/11/2023 1000
Sample
Spike
Amount
Amount
Result %Rec
Parameter
(ug/L)
(ug/L)
(ug/L) Q Dil % Rec Limit Analysis Date
TPH-DRO
ND
2000
1900 1 94 70-130 12/12/20231542
Surrogate
o - Terphenyl
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
95 53-118
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 52 of 56
QC Data for Lot Number: YL08039

TPH-DRO - MSD
Sample ID: YL08039-001 MD
Matrix: Aqueous
Batch: 91934
Prep Method: 3520C
Analytical Method: 8015C
Prep Date: 12/11/2023 1000
Sample
Spike
Amount
Amount Result
%Rec % RPD
Parameter
(ug/L)
(ug/L) (ug/L)
Q Dil % Rec % RPD Limit Limit Analysis Date
TPH-DRO
ND
2000 1800
1 91 2.5 70-130 20 12/12/20231552
Surrogate
o - Terphenyl
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
92 53-118
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 53 of 56
QC Data for Lot Number: YL08039

Page 145 of 148
Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 54 of 56

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Qualm Ilk 5060 Pace AonlyticaI Services 1�C
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 56 of 56

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1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 601519
Location: MNS_MW-5R [ MNS Landfill 2 / MW-5R (LANDFILL)]
Collection
Start: 12/4/2023
14:00:00
Job: MNSGW202345
Collection
End: 12/4/2023
14:00:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.40E-01
0.00E+00
4.40E-01
<3
LLD OK
Beta
<3.18E+00
0.00E+00
3.18E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.43E+00
0.00E+00
6.43E+00
<15
<1000
LLD OK
Co-58
<6.98E+00
0.00E+00
6.98E+00
<15
<1000
LLD OK
Fe-59
<1.06E+01
0.00E+00
1.06E+01
<30
<400
LLD OK
Co-60
<4.99E+00
0.00E+00
4.99E+00
<15
<300
LLD OK
Zn-65
<1.29E+01
0.00E+00
1.29E+01
<30
<300
LLD OK
Zr-95
<1.19E+01
0.00E+00
1.19E+01
<15
<400
LLD OK
Nb-95
<6.78E+00
0.00E+00
6.78E+00
<15
<400
LLD OK
1-131
<1.05E+01
0.00E+00
1.05E+01
<15
LLD OK
Cs-134
<7.36E+00
0.00E+00
7.36E+00
<15
<30
LLD OK
Cs-137
<5.34E+00
0.00E+00
5.34E+00
<18
<50
LLD OK
Bala-140
<1.19E+01
0.00E+00
1.19E+01
<15
<200
LLD OK
Be-7
<4.85E+01
0.00E+00
4.85E+01
K-40
1.68E+02
6.60E+01
7.25E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<2.84E+01
0.00E+00
1.76E+02
<250
<20000
LLD OK
Report Generated @ 1/24/2024 13:36:20 EnRad Laboratory Page 1 of 14
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 1 of 15 - 01/24/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 601520
Location: MNS_MW-5A [ MNS Landfill 2 / MW-5A (LANDFILL)]
Collection
Start: 12/4/2023
12:00:00
Job: MNSGW202345
Collection
End: 12/4/2023
12:00:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.39E-01
0.00E+00
4.39E-01
<3
LLD OK
Beta
<3.18E+00
0.00E+00
3.18E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.77E+00
0.00E+00
5.77E+00
<15
<1000
LLD OK
Co-58
<6.50E+00
0.00E+00
6.50E+00
<15
<1000
LLD OK
Fe-59
<1.15E+01
0.00E+00
1.15E+01
<30
<400
LLD OK
Co-60
<5.29E+00
0.00E+00
5.29E+00
<15
<300
LLD OK
Zn-65
<1.25E+01
0.00E+00
1.25E+01
<30
<300
LLD OK
Zr-95
<1.16E+01
0.00E+00
1.16E+01
<15
<400
LLD OK
Nb-95
<6.46E+00
0.00E+00
6.46E+00
<15
<400
LLD OK
1-131
<7.87E+00
0.00E+00
7.87E+00
<15
LLD OK
Cs-134
<5.81 E+00
0.00E+00
5.81 E+00
<15
<30
LLD OK
Cs-137
<5.74E+00
0.00E+00
5.74E+00
<18
<50
LLD OK
Bala-140
<9.10E+00
0.00E+00
9.10E+00
<15
<200
LLD OK
Be-7
<3.99E+01
0.00E+00
3.99E+01
K-40
<1.12E+02
0.00E+00
1.12E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-1.7E+01
0.00E+00
1.76E+02
<250
<20000
LLD OK
Report Generated @ 1/24/2024 13:36:20 EnRad Laboratory Page 2 of 14
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 2 of 15 - 01/24/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 601521
Location: MNS_MW-6 [ MNS Landfill 2 / MW-6 (LANDFILL)]
Collection
Start: 12/4/2023
15:50:00
Job: MNSGW202345
Collection
End: 12/4/2023
15:50:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.38E-01
0.00E+00
4.38E-01
<3
LLD OK
Beta
<3.18E+00
0.00E+00
3.18E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.37E+00
0.00E+00
6.37E+00
<15
<1000
LLD OK
Co-58
<5.60E+00
0.00E+00
5.60E+00
<15
<1000
LLD OK
Fe-59
<1.19E+01
0.00E+00
1.19E+01
<30
<400
LLD OK
Co-60
<5.53E+00
0.00E+00
5.53E+00
<15
<300
LLD OK
Zn-65
<1.25E+01
0.00E+00
1.25E+01
<30
<300
LLD OK
Zr-95
<1.24E+01
0.00E+00
1.24E+01
<15
<400
LLD OK
Nb-95
<6.89E+00
0.00E+00
6.89E+00
<15
<400
LLD OK
1-131
<8.84E+00
0.00E+00
8.84E+00
<15
LLD OK
Cs-134
<7.49E+00
0.00E+00
7.49E+00
<15
<30
LLD OK
Cs-137
<7.09E+00
0.00E+00
7.09E+00
<18
<50
LLD OK
Bala-140
<1.02E+01
0.00E+00
1.02E+01
<15
<200
LLD OK
Be-7
<3.64E+01
0.00E+00
3.64E+01
K-40
1.28E+02
6.88E+01
9.33E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<8.28E+01
0.00E+00
1.76E+02
<250
<20000
LLD OK
Report Generated @ 1/24/2024 13:36:20 EnRad Laboratory Page 3 of 14
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 3 of 15 - 01/24/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 601522
Location: MNS_MW-6A [ MNS Landfill 2 / MW-6A (LANDFILL)]
Collection
Start: 12/4/2023
15:30:00
Job: MNSGW202345
Collection
End: 12/4/2023
15:30:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.39E-01
0.00E+00
4.39E-01
<3
LLD OK
Beta
<3.18E+00
0.00E+00
3.18E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.64E+00
0.00E+00
5.64E+00
<15
<1000
LLD OK
Co-58
<3.92E+00
0.00E+00
3.92E+00
<15
<1000
LLD OK
Fe-59
<1.16E+01
0.00E+00
1.16E+01
<30
<400
LLD OK
Co-60
<5.79E+00
0.00E+00
5.79E+00
<15
<300
LLD OK
Zn-65
<1.09E+01
0.00E+00
1.09E+01
<30
<300
LLD OK
Zr-95
<8.29E+00
0.00E+00
8.29E+00
<15
<400
LLD OK
Nb-95
<4.58E+00
0.00E+00
4.58E+00
<15
<400
LLD OK
1-131
<1.09E+01
0.00E+00
1.09E+01
<15
LLD OK
Cs-134
<6.30E+00
0.00E+00
6.30E+00
<15
<30
LLD OK
Cs-137
<5.98E+00
0.00E+00
5.98E+00
<18
<50
LLD OK
Bala-140
<9.21 E+00
0.00E+00
9.21 E+00
<15
<200
LLD OK
Be-7
<4.72E+01
0.00E+00
4.72E+01
K-40
1.37E+02
6.22E+01
7.48E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<6.86E+01
0.00E+00
1.76E+02
<250
<20000
LLD OK
Report Generated @ 1/24/2024 13:36:20 EnRad Laboratory Page 4 of 14
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 4 of 15 - 01/24/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 601523
Location: MNS_MW-7R [ MNS Landfill 2 / MW-7R (LANDFILL)]
Collection
Start: 12/5/2023
13:45:00
Job: MNSGW202345
Collection
End: 12/5/2023
13:45:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.39E-01
0.00E+00
4.39E-01
<3
LLD OK
Beta
<3.18E+00
0.00E+00
3.18E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.06E+00
0.00E+00
5.06E+00
<15
<1000
LLD OK
Co-58
<5.87E+00
0.00E+00
5.87E+00
<15
<1000
LLD OK
Fe-59
<1.08E+01
0.00E+00
1.08E+01
<30
<400
LLD OK
Co-60
<6.83E+00
0.00E+00
6.83E+00
<15
<300
LLD OK
Zn-65
<1.07E+01
0.00E+00
1.07E+01
<30
<300
LLD OK
Zr-95
<9.87E+00
0.00E+00
9.87E+00
<15
<400
LLD OK
Nb-95
<5.25E+00
0.00E+00
5.25E+00
<15
<400
LLD OK
1-131
<8.37E+00
0.00E+00
8.37E+00
<15
LLD OK
Cs-134
<7.25E+00
0.00E+00
7.25E+00
<15
<30
LLD OK
Cs-137
<5.55E+00
0.00E+00
5.55E+00
<18
<50
LLD OK
Bala-140
<5.16E+00
0.00E+00
5.16E+00
<15
<200
LLD OK
Be-7
<4.88E+01
0.00E+00
4.88E+01
K-40
1.70E+02
7.95E+01
1.05E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<2.61 E+01
0.00E+00
1.77E+02
<250
<20000
LLD OK
Report Generated @ 1/24/2024 13:36:20 EnRad Laboratory Page 5 of 14
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 5 of 15 - 01/24/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 601524
Location: MNS_MW-7A [ MNS Landfill 2 / MW-7A (LANDFILL)]
Collection
Start: 12/5/2023 13:05:00
Job: MNSGW202345
Collection
End: 12/5/2023 13:05:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.39E-01
0.00E+00
4.39E-01
<3
LLD OK
Beta
<3.18E+00
0.00E+00
3.18E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.53E+00
0.00E+00
5.53E+00
<15
<1000
LLD OK
Co-58
<5.88E+00
0.00E+00
5.88E+00
<15
<1000
LLD OK
Fe-59
<1.10E+01
0.00E+00
1.10E+01
<30
<400
LLD OK
Co-60
<6.87E+00
0.00E+00
6.87E+00
<15
<300
LLD OK
Zn-65
<1.16E+01
0.00E+00
1.16E+01
<30
<300
LLD OK
Zr-95
<8.35E+00
0.00E+00
8.35E+00
<15
<400
LLD OK
Nb-95
<5.74E+00
0.00E+00
5.74E+00
<15
<400
LLD OK
1-131
<9.06E+00
0.00E+00
9.06E+00
<15
LLD OK
Cs-134
<6.40E+00
0.00E+00
6.40E+00
<15
<30
LLD OK
Cs-137
<5.37E+00
0.00E+00
5.37E+00
<18
<50
LLD OK
Bala-140
<8.80E+00
0.00E+00
8.80E+00
<15
<200
LLD OK
Be-7
<4.81 E+01
0.00E+00
4.81 E+01
K-40
<1.57E+02
0.00E+00
1.57E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<1.23E+02
0.00E+00
1.75E+02
<250
<20000
LLD OK
Report Generated @ 1/24/2024 13:36:20 EnRad Laboratory Page 6 of 14
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 6 of 15 - 01/24/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 601525
Location: MNS_MW-8 [ MNS Landfill 2 / MW-8 (LANDFILL)]
Collection
Start: 12/4/2023 09:30:00
Job: MNSGW202345
Collection
End: 12/4/2023 09:30:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.39E-01
0.00E+00
4.39E-01
<3
LLD OK
Beta
<3.18E+00
0.00E+00
3.18E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<4.76E+00
0.00E+00
4.76E+00
<15
<1000
LLD OK
Co-58
<6.19E+00
0.00E+00
6.19E+00
<15
<1000
LLD OK
Fe-59
<9.93E+00
0.00E+00
9.93E+00
<30
<400
LLD OK
Co-60
<6.24E+00
0.00E+00
6.24E+00
<15
<300
LLD OK
Zn-65
<1.38E+01
0.00E+00
1.38E+01
<30
<300
LLD OK
Zr-95
<1.12E+01
0.00E+00
1.12E+01
<15
<400
LLD OK
Nb-95
<6.96E+00
0.00E+00
6.96E+00
<15
<400
LLD OK
1-131
<9.36E+00
0.00E+00
9.36E+00
<15
LLD OK
Cs-134
<7.76E+00
0.00E+00
7.76E+00
<15
<30
LLD OK
Cs-137
<6.17E+00
0.00E+00
6.17E+00
<18
<50
LLD OK
Bala-140
<1.15E+01
0.00E+00
1.15E+01
<15
<200
LLD OK
Be-7
<4.75E+01
0.00E+00
4.75E+01
K-40
1.53E+02
6.36E+01
6.91 E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<1.89E+01
0.00E+00
1.76E+02
<250
<20000
LLD OK
Report Generated @ 1/24/2024 13:36:20 EnRad Laboratory Page 7 of 14
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 7 of 15 - 01/24/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 601526
Location: MNS_MW-8A [ MNS Landfill 2 / MW-8A (LANDFILL)]
Collection
Start: 12/4/2023
10:05:00
Job: MNSGW202345
Collection
End: 12/4/2023
10:05:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.39E-01
0.00E+00
4.39E-01
<3
LLD OK
Beta
<3.18E+00
0.00E+00
3.18E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.72E+00
0.00E+00
6.72E+00
<15
<1000
LLD OK
Co-58
<5.63E+00
0.00E+00
5.63E+00
<15
<1000
LLD OK
Fe-59
<1.19E+01
0.00E+00
1.19E+01
<30
<400
LLD OK
Co-60
<8.45E+00
0.00E+00
8.45E+00
<15
<300
LLD OK
Zn-65
<1.30E+01
0.00E+00
1.30E+01
<30
<300
LLD OK
Zr-95
<9.84E+00
0.00E+00
9.84E+00
<15
<400
LLD OK
Nb-95
<7.12E+00
0.00E+00
7.12E+00
<15
<400
LLD OK
1-131
<1.15E+01
0.00E+00
1.15E+01
<15
LLD OK
Cs-134
<7.51 E+00
0.00E+00
7.51 E+00
<15
<30
LLD OK
Cs-137
<4.84E+00
0.00E+00
4.84E+00
<18
<50
LLD OK
Bala-140
<6.76E+00
0.00E+00
6.76E+00
<15
<200
LLD OK
Be-7
<5.64E+01
0.00E+00
5.64E+01
K-40
1.79E+02
8.05E+01
1.06E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<2.61 E+01
0.00E+00
1.77E+02
<250
<20000
LLD OK
Report Generated @ 1/24/2024 13:36:20 EnRad Laboratory Page 8 of 14
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 8 of 15 - 01/24/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 601527
Location: MNS_MW-9 [ MNS Landfill 2 / MW-9 (LANDFILL)]
Collection
Start: 12/5/2023
10:30:00
Job: MNSGW202345
Collection
End: 12/5/2023
10:30:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.39E-01
0.00E+00
4.39E-01
<3
LLD OK
Beta
<3.18E+00
0.00E+00
3.18E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground
Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<7.05E+00
0.00E+00
7.05E+00
<15
<1000
LLD OK
Co-58
<6.60E+00
0.00E+00
6.60E+00
<15
<1000
LLD OK
Fe-59
<1.10E+01
0.00E+00
1.10E+01
<30
<400
LLD OK
Co-60
<8.86E+00
0.00E+00
8.86E+00
<15
<300
LLD OK
Zn-65
<1.65E+01
0.00E+00
1.65E+01
<30
<300
LLD OK
Zr-95
<1.24E+01
0.00E+00
1.24E+01
<15
<400
LLD OK
Nb-95
<7.17E+00
0.00E+00
7.17E+00
<15
<400
LLD OK
1-131
<1.13E+01
0.00E+00
1.13E+01
<15
LLD OK
Cs-134
<8.20E+00
0.00E+00
8.20E+00
<15
<30
LLD OK
Cs-137
<5.71 E+00
0.00E+00
5.71 E+00
<18
<50
LLD OK
Bala-140
<1.09E+01
0.00E+00
1.09E+01
<15
<200
LLD OK
Be-7
<5.26E+01
0.00E+00
5.26E+01
K-40
1.88E+02
8.76E+01
1.20E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<5.89E+01
0.00E+00
1.75E+02
<250
<20000
LLD OK
Report Generated @ 1/24/2024 13:36:20 EnRad Laboratory Page 9 of 14
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 9 of 15 - 01/24/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 601528
Location: MNS_MW-9A [ MNS Landfill 2 / MW-9A (LANDFILL)]
Collection
Start: 12/5/2023 10:00:00
Job: MNSGW202345
Collection
End: 12/5/2023 10:00:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.67E-01
0.00E+00 4.67E-01
<3
LLD OK
Beta
3.41 E+00
4.38E+00 3.29E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.58E+00
0.00E+00 5.58E+00
<15
<1000 LLD OK
Co-58
<7.51 E+00
0.00E+00 7.51 E+00
<15
<1000 LLD OK
Fe-59
<1.18E+01
0.00E+00 1.18E+01
<30
<400 LLD OK
Co-60
<6.06E+00
0.00E+00 6.06E+00
<15
<300 LLD OK
Zn-65
<1.40E+01
0.00E+00 1.40E+01
<30
<300 LLD OK
Zr-95
<1.06E+01
0.00E+00 1.06E+01
<15
<400 LLD OK
Nb-95
<7.60E+00
0.00E+00 7.60E+00
<15
<400 LLD OK
1-131
<9.16E+00
0.00E+00 9.16E+00
<15
LLD OK
Cs-134
<7.36E+00
0.00E+00 7.36E+00
<15
<30 LLD OK
Cs-137
<5.91 E+00
0.00E+00 5.91 E+00
<18
<50 LLD OK
Bala-140
<1.05E+01
0.00E+00 1.05E+01
<15
<200 LLD OK
Be-7
<4.76E+01
0.00E+00 4.76E+01
K-40
1.20E+02
6.74E+01 9.37E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<6.63E+01
0.00E+00 1.76E+02
<250
<20000 LLD OK
Report Generated @ 1/24/2024 13:36:20
EnRad Laboratory
Page 10 of 14
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 10 of 15 - 01/24/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 601529
Location: MNS_MW-10A [ MNS Landfill 2 / MW-10A (LANDFILL)]
Collection
Start: 12/4/2023 14:50:00
Job: MNSGW202345
Collection
End: 12/4/2023 14:50:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
5.43E-01
6.67E-01 4.67E-01
<3
LLD OK
Beta
<3.29E+00
0.00E+00 3.29E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.22E+00
0.00E+00 6.22E+00
<15
<1000 LLD OK
Co-58
<7.18E+00
0.00E+00 7.18E+00
<15
<1000 LLD OK
Fe-59
<1.16E+01
0.00E+00 1.16E+01
<30
<400 LLD OK
Co-60
<5.53E+00
0.00E+00 5.53E+00
<15
<300 LLD OK
Zn-65
<1.31 E+01
0.00E+00 1.31 E+01
<30
<300 LLD OK
Zr-95
<1.35E+01
0.00E+00 1.35E+01
<15
<400 LLD OK
Nb-95
<8.13E+00
0.00E+00 8.13E+00
<15
<400 LLD OK
1-131
<1.01 E+01
0.00E+00 1.01E+01
<15
LLD OK
Cs-134
<6.95E+00
0.00E+00 6.95E+00
<15
<30 LLD OK
Cs-137
<7.33E+00
0.00E+00 7.33E+00
<18
<50 LLD OK
Bala-140
<9.51 E+00
0.00E+00 9.51 E+00
<15
<200 LLD OK
Be-7
<4.19E+01
0.00E+00 4.19E+01
K-40
1.92E+02
7.58E+01 9.30E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<6.18E+01
0.00E+00 1.77E+02
<250
<20000 LLD OK
Report Generated @ 1/24/2024 13:36:20
EnRad Laboratory
Page 11 of 14
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 11 of 15 - 01/24/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 601530
Location: MNS_SW-1 [ MNS Landfill
2/SW-1 (LANDFILL)]
Collection
Start: 12/5/2023 14:45:00
Job: MNSGW202345
Collection
End: 12/5/2023 14:45:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.67E-01
0.00E+00 4.67E-01
<3
LLD OK
Beta
<3.29E+00
0.00E+00 3.29E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.81 E+00
0.00E+00 5.81 E+00
<15
<1000 LLD OK
Co-58
<6.49E+00
0.00E+00 6.49E+00
<15
<1000 LLD OK
Fe-59
<1.28E+01
0.00E+00 1.28E+01
<30
<400 LLD OK
Co-60
<1.11 E+00
0.00E+00 1.11E+00
<15
<300 LLD OK
Zn-65
<1.37E+01
0.00E+00 1.37E+01
<30
<300 LLD OK
Zr-95
<1.04E+01
0.00E+00 1.04E+01
<15
<400 LLD OK
Nb-95
<4.50E+00
0.00E+00 4.50E+00
<15
<400 LLD OK
1-131
<9.33E+00
0.00E+00 9.33E+00
<15
LLD OK
Cs-134
<6.08E+00
0.00E+00 6.08E+00
<15
<30 LLD OK
Cs-137
<5.81 E+00
0.00E+00 5.81 E+00
<18
<50 LLD OK
Bala-140
<8.77E+00
0.00E+00 8.77E+00
<15
<200 LLD OK
Be-7
<5.04E+01
0.00E+00 5.04E+01
K-40
1.22E+02
7.36E+01 1.06E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<2.86E+01
0.00E+00 1.78E+02
<250
<20000 LLD OK
Report Generated @ 1/24/2024 13:36:20
EnRad Laboratory
Page 12 of 14
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 12 of 15 - 01/24/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 601531
Location: MNS_SW-2 [ MNS Landfill
2/SW-2 (LANDFILL)]
Collection
Start: 12/5/2023 11:40:00
Job: MNSGW202345
Collection
End: 12/5/2023 11:40:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.67E-01
0.00E+00 4.67E-01
<3
LLD OK
Beta
3.36E+00
4.38E+00 3.29E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.72E+00
0.00E+00 5.72E+00
<15
<1000 LLD OK
Co-58
<6.09E+00
0.00E+00 6.09E+00
<15
<1000 LLD OK
Fe-59
<1.14E+01
0.00E+00 1.14E+01
<30
<400 LLD OK
Co-60
<5.17E+00
0.00E+00 5.17E+00
<15
<300 LLD OK
Zn-65
<1.44E+01
0.00E+00 1.44E+01
<30
<300 LLD OK
Zr-95
<1.13E+01
0.00E+00 1.13E+01
<15
<400 LLD OK
Nb-95
<7.27E+00
0.00E+00 7.27E+00
<15
<400 LLD OK
1-131
<8.48E+00
0.00E+00 8.48E+00
<15
LLD OK
Cs-134
<6.84E+00
0.00E+00 6.84E+00
<15
<30 LLD OK
Cs-137
<5.93E+00
0.00E+00 5.93E+00
<18
<50 LLD OK
Bala-140
<5.21 E+00
0.00E+00 5.21 E+00
<15
<200 LLD OK
Be-7
<4.79E+01
0.00E+00 4.79E+01
K-40
8.49E+01
6.01 E+01 8.73E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<2.85E+01
0.00E+00 1.77E+02
<250
<20000 LLD OK
Report Generated @ 1/24/2024 13:36:20
EnRad Laboratory
Page 13 of 14
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 13 of 15 - 01/24/2024

1
n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 601532
Location: MNS_LEACHP [ MNS Landfill 2 / Leachate Pond( LANDFILL) ] Collection
Start: 12/4/2023 11:10:00
Job: MNSGW202345
Collection
End: 12/4/2023 11:10:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
6.42E-01
6.84E-01 4.69E-01
<3
LLD OK
Beta
1.09E+01
4.55E+00 3.29E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.34E+00
0.00E+00 5.34E+00
<15
<1000 LLD OK
Co-58
<6.68E+00
0.00E+00 6.68E+00
<15
<1000 LLD OK
Fe-59
<1.12E+01
0.00E+00 1.12E+01
<30
<400 LLD OK
Co-60
<5.81 E+00
0.00E+00 5.81 E+00
<15
<300 LLD OK
Zn-65
<1.22E+01
0.00E+00 1.22E+01
<30
<300 LLD OK
Zr-95
<9.67E+00
0.00E+00 9.67E+00
<15
<400 LLD OK
Nb-95
<6.28E+00
0.00E+00 6.28E+00
<15
<400 LLD OK
1-131
<1.04E+01
0.00E+00 1.04E+01
<15
LLD OK
Cs-134
<5.48E+00
0.00E+00 5.48E+00
<15
<30 LLD OK
Cs-137
<4.53E+00
0.00E+00 4.53E+00
<18
<50 LLD OK
Bala-140
<8.59E+00
0.00E+00 8.59E+00
<15
<200 LLD OK
Be-7
<5.35E+01
0.00E+00 5.35E+01
K-40
1.24E+02
5.81 E+01 6.91 E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
5.73E+02
1.21 E+02 1.75E+02
<250
<20000 LLD OK
Report Generated @ 1/24/2024 13:36:20
EnRad Laboratory
Page 14 of 14
job_report_grouped_by_media
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories - Page 14 of 15 - 01/24/2024

!� r71 IIC� CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
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EnRad Laboratories - Page 15 of 15 - 01/24/2024

Appendix V - Rainfall Data and Leachate Generation Rates
(July 2023 through December 2023)

Leachate Collection System (LCS) and Leak Detection System (LDS) Tracking: July 2023 through December 2023
Landfill No. 2 (Synthetically Lined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
Landfill No. 2 (Cells 1 through 4)
Landfill No. 2
Leachate Collection System (LCS)
Leachate Pond Leak Detection System (LDS)
Monthly
Comments
Month
Duration
(days)
Y
Rainfall*
(notes or anything unusuaUdi Brent in operations or Site conditions; e.g.
Total
Monthly
Leachate
Total
Monthly
Exceeds
Exceeds
(inches)
Gallons
Gallons
Average
Area
Generation
Gallons
Gallons
Area
Leakage
IRLR:300
ALR:421
system downtimes, significant weather/storms, etc.]
Flow
Rate
Pumped
Pumped
(acres)
Rate
Pumped
Pumped
(acres)
gpad
gpad
(gpm)
(gpad)
(gap
(gal)
(gpad)
(gal)
(gal)
(Yes or No)
(Yes or No)
Jul -23
21
2.06
3,410,426
38,251
1.3
5.0
364
777
0
0.2
0.0
No
No
n/a
Au ust-23
41
4.09
3,531,204
120,778
2.0
5.0
589
1,041
264
0.2
32.2
No
No
n/a
Pumps were temporarily out of service for repairs to piping in September
September-23
24
1.93
3,531,207
3
0.0
5.0
0
1,046
5
0.2
1.0
No
No
2023. Measured flow is an artifact of the maintained period. Subsequent
flow meter readings indicated no issues with the flow meter.
October-23
32
1.37
3,675,440
144,233
3.1
5.0
901
1,117
71
0.2
11.1
No
No
n/a
November-23
30
1.76
3,725,563
50,123
1.2
5.0
334
1,133
16
0.2
2.7
No
No
n/a
December-23
27
7.36
1 4,171,437
445,874
11.5
5.0
3,303
1,158
25
0.2
4.6
No
No
n/a
Notes•
*Monthly rainfall data from Duke Meteorological Rain Gage on the McGuire Island
gal - gallons
gpm - gallons per minute
gpad - gallons per acre per day
n/a - not applicable