6801_OrangeCoMSWLF_November2023GWMR_FID1831893_20240312

Groundwater Monitoring Program March 2024 Results of Sampling and Analysis Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01
Groundwater
Monitoring Program
Results of Sampling
and Analysis
Sampling Event 59: 11.20.23 +
11.21.23 + 11.22.23
Submitted to:
Compliance Unit, NCDEQ-DWM Solid Waste Section 1646 Mail Service Center Raleigh, NC 27699-1646
Orange County Solid Waste Management (South
Facility) Permit No. 68-01
TRC Project Number: 558030
Prepared For:
Orange County Solid Waste Management Post Office Box 17177
Chapel Hill, North Carolina 27516
Prepared By:
TRC Companies 114 Edinburgh South Drive, Suite 200 Cary, NC 27511
March 2024
Prepared by: Sean Jarvah Environmental Specialist Reviewed and Approved by: Bilgen Yuncu, PhD, PE, PMP Environmental Engineer/Project Manager
WELL ID CAS Number PARAMETER RESULT UNITS QUALIFIER METHOD MDL MRL
REGULATORY
PROTECTION
STANDARD
SOURCE ANALYSIS*
6801-MW105-20231122 7440-38-2 Arsenic 33 µg/L EPA 6010D NR 10 15.66 FBAC Not a landfill impact; > MRL; >2L and >FBAC of 15.66 µg/l, ASD approved September 2011
6801-MW105-20231122 7440-48-4 Cobalt 25.8 µg/L EPA 6010D NR 5 2.15 FBAC Not a landfill impact; >MRL; >2L; and >FBAC of 2.15 µg/L, ASD approved 03-30-10
6801-MW111-20231121 7440-62-2 Vanadium 7.6 µg/L EPA 6010D NR 5 6.968 FBAC Not a landfill impact; >MRL; >2L; and > FBAC of 6.968 µg/L, ASD approved 5/26/2011
Well ID Format - facility permit number - well ID - sample collection date (yyyymmdd)
GWPS/NCGQS/2L std - groundwater protection standard
ASD - Alternate Source Demonstration
MDL - Method Detection Limit
MRL - Method Reporting Limit
FBAC - Facility Background Concentration (Letter requesting FBACs as regulatory protection standard submitted to NCDEQ on December 12, 2019)
Bold red values exceed their respective regulatory protection standard (2L, FBAC or MCL).
MCL - Maximum Contaminant Level
NR - Not Reported
INORGANIC CONSTITUENTS ATTAINING OR EXCEEDING THEIR REGULATORY PROTECTION STANDARDS [metals (total = not filtered)]
CONSTITUENTS EXCEEDING REGULATORY PROTECTION STANDARDS
CLIENT: THE COUNTY OF ORANGE
FACILITY: ORANGE COUNTY REGIONAL LANDFILL - SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
DATE OF SAMPLING: 11.20.23 + 11.21.23 + 11.22.23

Groundwater Monitoring Program March 2024 Results of Sampling and Analysis Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01
ATTACHMENTS
1. Figures
2. Monitoring Well Network
3. Groundwater Elevation Data

4. Groundwater Velocity Calculations
5. Organic Constituents
6. Inorganic Constituents

7. Laboratory Certificate-Of-Analysis

8. Field Data
9. Statistical Analyses
10. Quality Control Assessment

11. Correspondence

Groundwater Monitoring Program March, 2024 Results of Sampling and Analysis Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01

Attachment 1: Figures

NORTH
OLDC&D
SOUTH
ACTIVE
C&D
OFFICE
PROJECT:
TITLE:
Orange Co Landfill.dwgFILE:
PROJ. NO.:
DATE:
DRAWN BY:
APPROVED BY:
CHECKED BY:8.5x11 --- USER: kstark --- ATTACHED XREF'S: --- ATTACHED IMAGES: OC6i0_37_000_10987001_20210208_0223R0; OC6i0_37_000_10987002_20210208_0223R0 - Copy; OC6i0_37_000_10987103_20210208_0223R0; OC6i0_37_000_10987104_20210208_0223R0;DRAWING NAME: P:\2023\558027 - OCSWM North\CAD\Current Drawings\ Orange Co Landfill.dwg --- PLOT DATE: December 05, 2023 - 11:14AM --- LAYOUT: Figure 1AVersion: 2017-10-21
ORANGE COUNTY SOLID WASTE MANAGEMENT
NORTH + SOUTH + ACTIVE C&D LANDFILLSCHAPEL HILL, NORTH CAROLINA
VICINITY TOPOGRAPHIC MAP
K STARK
S JARVAH
D COAKLEY
NOVEMBER 2023
558027
FIGURE 1A
650 Suffolk StreetSuite 200Lowell, MA 01854Phone: [phone]
1000 20000
SCALE IN FEET
REFERENCE: USGS 7.5 MINUTETOPOGRAPHIC MAP
CHAPEL HILL, NC 2019
NORTH
OLD
C&D
SOUTH
ACTIVE
C&D Millhouse RoadPROJECT:
TITLE:
Orange Co Landfill.dwgFILE:
PROJ. NO.:
DATE:
DRAWN BY:
APPROVED BY:
CHECKED BY:8.5x11 --- USER: kstark --- ATTACHED XREF'S: --- ATTACHED IMAGES: OC6i0_37_000_10987001_20210208_0223R0; OC6i0_37_000_10987002_20210208_0223R0; OC6i0_37_000_10987103_20210208_0223R0; OC6i0_37_000_10987104_20210208_0223R0;DRAWING NAME: P:\2023\558027 - OCSWM North\CAD\Current Drawings\ Orange Co Landfill.dwg --- PLOT DATE: December 05, 2023 - 11:05AM --- LAYOUT: Figure 1BVersion: 2017-10-21
ORANGE COUNTY SOLID WASTE MANAGEMENT
NORTH + SOUTH + ACTIVE C&D LANDFILLSCHAPEL HILL, NORTH CAROLINA
VICINITY AERIAL PHOTOGRAPH
K STARK
S JARVAH
D COAKLEY
NOVEMBER 2023
558027
FIGURE 1B
650 Suffolk StreetSuite 200Lowell, MA 01854Phone: [phone]
1000 20000
SCALE IN FEET
AERIAL PROVIDED BY NCONE MAPMrSID, 2021
B
B'A'
A
485
480
475
CLOSED
MSW
LANDFILL
CLOSED
C & D
LANDFILL
ACTIVE C & D
LANDFILL
CLOSED
MSW
LANDFILL
490495
505
510
510
515
500
475
470
465
460
24x36 --- USER: KStark --- ATTACHED XREF'S: TOPO_07; 12109F --- ATTACHED IMAGES:DRAWING NAME: P:\2023\558027 - OCSWM North\CAD\Current Drawings\ R00592-POT MAP NOV 2023.dwg --- PLOT DATE: December 08, 2023 - 12:04PM --- LAYOUT: site mapDATE:
DRAWN BY:
CHECKED BY:
APPROVED BY:
PROJECT:
PROJ. NO.:
FILE NO.:
TITLE:
Version: 2017-10-21
ORANGE COUNTY LANDFILL
GROUNDWATER MONITORING PROGRAM
CHAPEL HILL, NORTH CAROLINA
POTENTIOMETRIC MAP
NOVEMBER 2023
558027
R00592-POT MAP NOV 2023.dwg
K STARK
S JARVAH
D COAKLEY SHEET 1
DECEMBER 2023
114 Edinburgh South Drive, Suite 200Cary, NC 27511Phone: [phone]www.trcsolutions.com

Groundwater Monitoring Program March, 2024 Results of Sampling and Analysis Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01

Attachment 2: Monitoring Well Network

Groundwater Monitoring Program March 2024 Results of Sampling and Analysis Attachment 2 Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01
ATTACHMENT 2 GROUNDWATER MONITORING NETWORK: SOUTH FACILITY The well monitoring network associated with the South sanitary landfill has been revised in accordance with the recently approved Comprehensive Landfill Facility Water Quality Monitoring
Plan (submitted September 2019) and consists of ten wells: Upgradient wells:
• 6801-MW04
• 6801-MW110D
• 6801-MW110S Downgradient (shallow) wells:
• 6801-MW101
• 6801-MW102S
• 6801-MW104
• 6801-MW105
• 6801-MW106
• 6801-MW107
• 6801-MW111 Additional downgradient (shallow) wells:
• 6801-MW103S - sampled if a Groundwater Quality Standard is exceeded in well 6801-MW104
• 6801-MW112 - sampled if a Groundwater Quality Standard is exceeded in well 6801-
MW105
Additional downgradient (deep) wells:
• 6801-MW102DR – sampled if a Groundwater Quality Standard is exceeded in well 6801-102S
• 6801-MW103D – sampled if a Groundwater Quality Standard is exceeded in well 6801-103S Note. Well 6801-MW04 is hydrogeologically downgradient of the active C&D landfill and hydrogeologically upgradient of the North sanitary landfill and South sanitary landfill. Accordingly,
well 6801-MW04 is designated as a downgradient well in the C&D network and is designated as a
background well in the North and South sanitary landfill networks. Note. Wells 6801-MW110S and 6801-MW110D are hydrogeologically downgradient of the active C&D landfill and hydrogeologically upgradient of the North sanitary landfill and South sanitary landfill. Accordingly, wells 6801-MW110S and 6801-MW110D are designated as downgradient wells in the C&D network and are designated as background wells in the North and South sanitary landfill networks.
NORTH SOUTH ACTIVE
Well LANDFILL LANDFILL C&D LANDFILL
6801-MW04 X - UP X - UP X - DOWN
6801-MW06R X - UP
6801-MW07R X
6801-MW14A X
6801-MW14B X
6801-MW15 X
6801-MW16 X
6801-MW17 X
6801-MW20 X
6801-MW21D X
6801-MW21S X
6801-MW22 X
6801-MW23 X
6801-MW24 X
6801-MW101 X
6801-MW102S X
6801-MW104 X
6801-MW105 X
6801-MW106 X
6801-MW107 X
6801-MW111 X
6801-MW110D X - UP X - UP
6801-MW110S X - UP X - UP X - DOWN
6804-MW204S X
6804-MW209 X
6804-MW210D X
6804-MW211R X - UP
6801-SW1 X
6801-SW2 X
leachate X
UP - upgradient well location
DOWN - downgradient well location
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: NORTH - SOUTH - C&D
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
MONITORING WELL NETWORK SUMMARY
total depth depth measured elevation elevation elevation elevation
well type of diameter depth to top to top well ground concrete measuring point top steel
designation well northing easting borehole borehole sand bentonite depth stickup surface pad (top PVC wellpipe)casing
6801-MW101 2MW15 807314.1519 1975988.981 0.5 35 18 16 38.33 1.98 506.98 509.25 
6801-MW102S 2MW15 807433.0189 1976435.981 0.5 25 8 6 27.79 1.95 495.06 497.3 
6801-MW102D 2MW15 807424.6914 1976408.348 0.5 55 38 36 57.44 1.76 495.71 n 497.76 n
6801-MW102DR 2MW15 807417.3978 1976401.856 0.5 55 37 34 57.5 2.5 497.62 496.27 498.03 
6801-MW103S 2MW15 807140.3758 1976636.687 0.5 35 18 16 37.98 2.0 495.28 497.57 
6801-MW103D 2MW15 807150.1994 1976625.012 0.5 65 48 46 68.51 2.25 496 498.54 
6801-MW104 2MW15 807258.9678 1976833.533 0.5 35 18 16 38.14 1.89 492.72 494.91 
6801-MW105 2MW10 806744.4377 1976394.117 0.5 33.2 21 19 37.92 2.55 505.8 508.64 
6801-MW106 2MW15 806420.8434 1976235.515 0.5 41.3 17.5 15.4 37.64 1.95 507.22 509.53 
6801-MW107 2MW15 806171.0616 1975892.314 0.5 35 18 16 37.29 1.81 514.36 516.46 
6801-MW108 2MW15 806095.0991 1975391.204 0.5 35 18 16 37.26 2.09 530.36 532.74 
6801-MW109 2MW15 806489.4212 1974988.226 0.5 30 8 6 27.59 2.06 521.58 523.93 
6801-MW110S 2MW15 807019.1106 1974956.856 0.5 40 18 16 38.31 2.04 537.91 540.24 
6801-MW110D 2MW15 807026.571 1974966.137 0.5 70 52.5 50 70.85 2.01 537.88 540.18 
6801-MW111 2MW15 807183.79 1975489.483 0.5 35 18 16 38.46 1.91 522.1 524.31 
6801-MW112 2MW10 806877.74 1976549.9 0.33 35 21 8 38 3.0 500.72 503.72 
Notes:
stick-up = elevation of measuring point - elevation of concrete pad = well abandoned
 = data not available. 2MW15 means "2-inch well pipe with 15 feet of well screen"
WELL SPECIFICATIONS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: MONITORING WELL CONSTRUCTION

Groundwater Monitoring Program March, 2024 Results of Sampling and Analysis Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01

Attachment 3: Groundwater Elevation Data
Groundwater Monitoring Program February 2024 Results of Sampling and Analysis Attachment 3 Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01
ATTACHMENT 3
GROUNDWATER ELEVATION DATA
Static water elevations obtained during the subject sampling event indicate that wells 6801-
MW110S and 6801-MW110D remain hydrogeologically upgradient from all disposal areas within the landfill facility and upgradient from all other wells.
Regarding wells screened within the uppermost portion of the aquifer underlying the facility, the elevation of the water table was found to vary from a high of 512.74 feet above mean sea level at upgradient monitoring well 6801-MW110S to a low of 477.69 feet above mean sea level at downgradient monitoring well 6801-MW104.
A comparison of static water elevations obtained during the referenced sampling event with those obtained during prior sampling events reveals no hydrogeologically significant changes in
directions of groundwater flow.
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
STATIC WATER LEVELS
Date: 11-20-23 + 11-21-23 + 11-22-23
WELL ELEVmp DTW STICKUP DTWc ELEVgs ELEVgw
6801-MW04 549.99 34.10 2.33 31.77 547.66 515.89
6801-MW101 509.25 24.10 2.27 21.83 506.98 485.15
6801-MW102 DR 498.03 2.50 497.62
6801-MW102 S 497.30 14.86 2.24 12.62 495.06 482.44
6801-MW103 D 498.54 2.54 496.00
6801-MW103 S 497.57 2.29 495.28
6801-MW104 494.91 17.22 2.19 15.03 492.72 477.69
6801-MW105 508.64 23.98 2.84 21.14 505.80 484.66
6801-MW106 509.53 21.35 2.31 19.04 507.22 488.18
6801-MW107 516.46 24.35 2.10 22.25 514.36 492.11
6801-MW108 532.74 2.38 530.36
6801-MW109 523.93 2.35 521.58
6801-MW110 D 540.18 34.95 2.30 32.65 537.88 505.23
6801-MW110 S 540.24 27.50 2.33 25.17 537.91 512.74
6801-MW111 524.31 30.98 2.21 28.77 522.10 493.33
6801-MW112 503.72 3.00 500.72
Notes:
Upgradient wells shaded yellow.
Elevations expressed in feet above mean sea level.
DATE MW-101 MW-102 D MW-102 DR MW-102 S MW-103 D MW-103 S MW-104 MW-105 MW-106 MW-107 MW-108 MW-109 MW-110 D MW-110 S MW-111 MW-112
Elves 506.98 495.71 496.27 495.06 496.00 495.28 492.72 505.80 507.22 514.36 530.36 521.58 537.88 537.91 522.10 500.72
Elemi 509.25 497.76 498.03 497.30 498.54 497.57 494.91 508.64 509.53 516.46 532.74 523.93 540.18 540.24 524.31 503.72
06/18/93 484.44
06/22/93 484.24
06/29/93 483.93
01/25/94 485.61
05/25/94 484.63
03/22/95 481.69 489.11 489.50 484.63 484.77 477.98 479.65 490.87 497.93 511.23 517.45 511.13 512.47 497.58
05/09/95 485.98 484.35 484.38 483.44 482.94 477.75 484.14 488.20 495.24 506.90 509.51 515.55 495.40
05/18/95 485.38 483.76 483.78 483.31 482.80 477.65 483.96 487.73 494.46 522.27 509.55 515.39 495.86
07/20/95 488.90 487.18 487.18 483.87 483.52 477.80 484.79 488.87 496.54 508.37 511.08 516.99 496.59
11/28/95 489.95 487.98 488.05 484.54 483.82 478.21 485.32 489.80 497.77 509.47 515.92 511.56 517.31 496.71
02/28/96 493.28 490.44 490.50 485.17 484.56 478.39 486.11 491.24 498.89 514.79 521.35 513.65 520.92 498.96
08/07/96 484.82 482.24 482.28 482.71 482.08 477.28 483.58 486.98 493.13 503.60 510.90 510.25 516.69 495.77
08/27/96 484.73 481.38 481.49 482.29 481.82 476.98 483.13 486.66 492.19 502.19 509.73 509.34 515.82 493.29
02/27/97 495.29 488.61 490.85 485.02 484.47 477.92 486.19 491.12 499.15 515.60 521.43 509.63 521.55 498.64
09/04/97 484.93 482.00 482.10 482.21 481.70 476.69 483.22 486.86 493.04 502.39 509.92 507.83 515.04 494.06
03/25/98 497.90 491.46 491.55 486.44 485.70 479.77 487.98 494.63 501.29 520.14 521.93 515.28 522.77 501.09
11/02/98 486.10 482.76 481.70 482.12 481.77 477.29 483.46 486.93 491.36 500.84 506.33 506.83 512.93 493.10
04/27/99 488.25 486.31 486.38 484.29 483.75 478.74 485.31 489.83 497.31 508.74 515.41 511.18 517.68 496.11
11/22/99 487.65 485.76 485.84 484.24 483.57 478.66 485.29 489.58 496.78 507.73 513.52 511.26 517.79 495.74
05/24/00 490.73 488.29 488.40 484.79 484.05 479.15 485.82 490.86 497.80 510.54 519.13 512.90 520.63 496.54
11/30/00 484.88 483.00 482.97 483.24 482.57 478.31 484.24 487.68 493.76 502.09 511.36 508.97 515.74 494.59
05/30/01 487.90 485.58 485.66 484.02 483.05 478.72 484.99 489.02 496.31 507.21 511.36 510.93 518.04 496.01
11/14/01 484.26 479.61 479.63 481.81 481.24 479.87 483.00 486.23 491.16 500.55 508.33 506.48 512.84 493.73
06/06/02 484.63 480.80 481.20 482.34 482.02 476.90 483.49 487.22 493.34 500.89 511.11 507.23 513.69 494.18
03/13/03 493.33 490.04 490.09 485.31 484.96 479.83 486.79 492.08 500.36 512.12 520.77 513.23 519.74 498.81
06/19/03 493.49 489.86 489.95 485.19 484.67 479.43 486.39 491.61 500.27 511.12 520.83 514.55 522.04 497.41
12/09/03 490.30 486.13 483.90 483.69 482.95 478.07 484.64 488.64 495.67 501.35 512.54 510.37 517.09 495.91
06/23/04 485.33 485.30 483.00 483.34 482.36 477.66 488.63 488.38 496.46 505.43 514.38 501.48 517.35 495.31
12/01/04 489.62 489.66 487.72 484.37 483.81 479.21 490.39 490.30 497.96 503.49 515.83 510.40 517.64 497.51
06/06/05 488.59 488.18 486.03 484.24 483.33 478.88 485.34 489.63 498.15 507.72 517.08 510.78 518.52 497.01
11/03/05 484.35 482.44 480.00 481.92 480.87 476.53 482.96 486.48 491.66 500.50 508.21 505.66 512.62 494.16
05/24/06 485.29 485.20 482.89 483.23 482.53 477.42 484.42 487.63 495.19 501.07 512.53 507.89 515.04 495.45
11/15/06 489.99 489.48 487.59 483.97 483.44 478.43 484.90 488.95 495.87 500.72 510.95 507.07 512.63 496.38
06/14/07 486.71 486.30 484.04 483.60 482.48 477.60 484.90 489.30 496.45 515.06 514.25 508.56 516.41 495.67
12/11/07 483.97 481.19 478.89 480.33 479.45 475.86 481.05 484.73 490.24 499.94 505.24 503.69 510.13 497.50
06/09/08 486.60 486.25 483.98 483.42 482.49 477.90 484.74 488.66 497.41 503.04 513.02 507.73 514.63 495.80
11/06/08 485.62 485.49 483.55 483.86 480.72 477.10 484.04 487.60 495.00 500.42 510.34 506.27 513.27 498.20
05/20/09 488.71 487.90 485.68 484.19 483.25 477.71 485.73 489.78 498.59 509.70 516.76 496.66
10/20/09 484.34 483.00 480.52 481.60 480.32 476.39 482.60 486.50 492.55 512.43 493.96 482.60
06/23/10 488.21 487.39 485.10 482.93 482.81 477.55 485.42 489.41 497.93 509.58 516.37 496.01
11/17/10 484.99 482.81 482.67 482.60 481.39 477.19 483.72 487.15 493.23 505.93 513.04 494.20
05/25/11 487.12 486.84 484.58 483.60 482.77 477.49 484.96 487.30 496.83 508.66 515.29 496.15 484.77
11/16/11 484.51 483.92 481.54 481.31 480.28 476.73 482.31 486.13 490.73 504.68 511.10 493.77 482.38
06/07/12 488.03 487.20 484.96 483.52 481.70 477.85 484.99 489.55 496.76 509.06 515.52 496.25 484.57
11/14/12 485.22 485.21 482.90 482.59 481.67 477.01 483.78 487.93 494.04 506.66 513.66 494.76 483.58
05/14/13 490.95 490.24 488.33 484.90 484.51 478.30 486.69 492.35 500.33 510.85 517.04 497.11 485.82
11/13/13 486.15 485.99 483.60 483.50 482.61 477.26 484.96 489.29 496.66 509.15 516.72 495.13 484.47
05/14/14 492.10 490.79 488.60 485.46 484.77 478.26 487.62 493.65 502.56 512.58 521.52 498.90 486.49
11/12/14 484.70 484.70 482.16 482.70 481.49 477.59 483.81 487.88 493.40 506.98 514.27 494.47 483.62
05/13/15 490.45 487.51 487.20 485.09 484.37 478.13 487.21 492.38 500.81 511.92 519.42 496.05 486.28
11/10/15 496.33 491.68 492.77 485.44 485.64 479.58 486.78 492.61 500.33 510.27 517.28 497.69 486.28
05/18/16 493.35 489.51 489.47 485.80 485.43 479.53 487.92 493.79 502.81 513.98 521.29 498.36 487.54
11/14/16 487.50 485.09 484.78 483.89 482.97 477.95 485.47 489.73 497.34 509.15 517.10 495.01 484.99
05/31/17 492.04 494.78 488.78 484.92 484.25 478.38 486.99 491.58 500.84 510.94 518.00 496.81 486.02
11/15/17 484.65 482.88 482.50 482.22 480.93 477.51 483.54 487.40 491.71 505.01 512.54 494.29 483.27
05/15/18 490.01 487.41 487.27 484.56 484.05 478.36 486.64 491.91 500.12 509.58 516.32 496.07 490.60
11/13/18 499.23 492.79 493.10 486.36 486.72 480.89 488.18 496.71 506.44 512.33 519.36 498.84 487.17
05/21/19 491.80 488.32 488.20 485.39 484.62 478.41 487.79 493.71 502.39 513.43 521.34 497.11 486.50
11/20/19 486.90 484.83 484.70 483.09 481.87 477.88 484.46 487.88 491.29 506.73 513.58 504.16 484.10
05/20/20 495.88 491.83 479.86 488.07 495.68 503.16 511.74 518.56 496.91
11/17/20 495.75 491.85 478.96 487.29 494.01 500.18 511.38 517.79 498.44
05/18/21 489.95 486.98 478.21 487.32 492.78 499.14 511.93 519.89 496.26
11/23/21 487.08 484.60 478.09 483.71 488.50 493.51 507.38 514.80 494.66
05/23/22 491.50 488.80 479.17 487.18 492.26 498.56 509.73 517.04 495.59
11/08/22 485.90 483.55 477.87 491.59 487.59 491.61 505.36 512.54 493.76
05/03/23 495.33 491.25 479.06 487.82 494.35 503.61 516.18 519.04 498.71
11/23/23 485.15 482.44 477.69 484.66 488.18 492.11 505.23 512.74 493.33
MW-101 MW-102 D MW-102 DR MW-102 S MW-103 D MW-103 S MW-104 MW-105 MW-106 MW-107 MW-108 MW-109 MW-110 D MW-110 S MW-111 MW-112
MIN 481.69 479.61 481.19 478.89 480.33 479.45 475.86 479.65 484.73 490.24 499.94 505.24 501.48 510.13 493.10 482.38
MEAN 488.62 485.74 486.86 485.74 483.75 483.01 478.11 485.36 489.71 496.74 506.80 513.83 509.48 516.44 496.27 485.32
MEDIAN 487.78 485.76 486.30 485.03 483.78 482.95 477.97 484.99 489.30 496.77 506.17 513.02 509.58 516.71 496.06 484.99
MAX 499.23 491.46 494.78 493.10 486.44 486.72 480.89 491.59 496.71 506.44 522.27 521.93 516.18 522.77 504.16 490.60
STD 3.97 3.47 3.05 3.54 1.31 1.53 0.97 2.09 2.64 3.71 6.02 4.61 2.93 2.96 1.97 1.93
RANGE 17.54 11.85 13.59 14.21 6.11 7.27 5.03 11.94 11.98 16.20 22.33 16.69 14.70 12.64 11.06 8.22
Notes:
Upgradient wells shaded yellow Elevations in feet above mean sea level
PROJECT: GROUNDWATER MONITORING PROGRAM
HISTORY OF STATIC WATER ELEVATIONS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
LOCATION: CHAPEL HILL, NORTH CAROLINAFACILITY: SOUTH FACILITY
470
480
490
500
510
520
530
Groundwater Surface Elevation (feet above mean sea level)Date
Orange County Solid Waste Management -South FacilityStatic Water Elevations
MW-04 MW-101 MW-102S MW-104 MW-105 MW-106 MW-107 MW-110D MW-110S MW-111

Groundwater Monitoring Program March, 2024 Results of Sampling and Analysis Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01

Attachment 4: Groundwater Velocity Calculations
[Based On Data Presented in Attachment 3]

Groundwater Monitoring Program March 2024 Results of Sampling and Analysis Attachment 4 Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01
ATTACHMENT 4 GROUNDWATER VELOCITY CALCULATIONS The rate of at which constituents are transported in groundwater may be conservatively estimated by the velocity of groundwater flow. We shall distinguish between the apparent Darcy groundwater flow velocity (Vd) and seepage velocity (Vs), which are given by the equations: Vd = ki
and Vs = kin-1 where:
Vd = Darcy velocity Vs = seepage velocity
k = hydraulic conductivity i = hydraulic gradient n = porosity
Hydraulic parameters for wells associated with the subject facility are summarized in the hydraulic
parameters table provided at the end of this ATTACHMENT. Effective porosity values are estimated to range from about 15% (bedrock) to 35% (saprolite). Using groundwater elevations measured during the subject sampling event, the hydraulic gradient of the uppermost aquifer was calculated along the flow path from well 6801-MW110S to well 6801-
MW104. The average hydraulic gradient was estimated by dividing the difference between the hydraulic heads (elevation heads) in well 6801-MW110S and well 6801-MW104 by the distance between those two wells (about 1,881 feet). The hydraulic conductivity value derived from well 6801-MW104 (1.80 x 10-5 m/sec) was used to
calculate groundwater velocity along the flow path from well 6801-MW110S to well 6801-MW104 (being the higher conductivity observed in that particular pair of wells).
Calculated velocities (along the selected flow path) are presented in the groundwater velocity
calculations table at the end of this ATTACHMENT and illustrated on the accompanying graph.
The velocity observed during the subject sampling event (231.5 feet per year) was 8.3% less
than the median velocity (252.4 feet per year along the selected flow path). A review of groundwater velocity over time, commencing in May 2011 (see graph), indicates that velocity generally increased, between late 2011 and early 2014, after which it has generally oscillated around the median velocity along the selected flow path.

Groundwater Monitoring Program March 2024 Results of Sampling and Analysis Attachment 4 Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01 Page 2
We note that the calculated groundwater velocity along a given flow path represents an average
velocity along one of many potential flow paths in the uppermost aquifer underlying the area of interest. Nonetheless, the velocity estimate is believed to be reasonably representative of that area.
Well Screened
Interval
Hydraulic Conductivity
(cm/s)
Hydraulic Conductivity
(m/s)Porosity
MW-101 bedrock 2.30E-04 2.30E-06 0.15
MW-102D bedrock 3.00E-04 3.00E-06 0.15
MW-102S bedrock 3.00E-04 3.00E-06 0.15
MW-103D bedrock 2.60E-03 2.60E-05 0.15
MW-103S saprolite 1.30E-03 1.30E-05 0.35
MW-104 bedrock 1.80E-03 1.80E-05 0.15
MW-105 saprolite 6.82E-04 6.82E-06 0.35
MW-106 bedrock 5.00E-05 5.00E-07 0.15
MW-107 bedrock 3.10E-03 3.10E-05 0.15
MW-108 saprolite 9.00E-04 9.00E-06 0.35
MW-109 bedrock 3.40E-04 3.40E-06 0.15
MW-110D bedrock 1.90E-04 1.90E-06 0.15
MW-110S bedrock 6.20E-04 6.20E-06 0.15
MW-111 bedrock 1.50E-05 1.50E-07 0.15
HYDRAULIC PARAMETERS
CLIENT: THE COUNTY OF ORANGE
FACILITY: ORANGE COUNTY LANDFILL - SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
from …… toward feet/feet meters/yr feet/yr
date
upgradient
location
upgradient
SWE
downgradient
location
downgradient
SWE gradient GW velocity GW velocity
05/25/11 6801-MW110S 515.29 6801-MW104 477.49 2.01E-02 76.1 249.7
11/16/11 6801-MW110S 511.10 6801-MW104 476.73 1.83E-02 69.2 227.0
06/07/12 6801-MW110S 515.52 6801-MW104 477.85 2.00E-02 75.8 248.8
11/14/12 6801-MW110S 513.66 6801-MW104 477.01 1.95E-02 73.8 242.1
05/14/13 6801-MW110S 517.04 6801-MW104 478.30 2.06E-02 78.0 255.9
11/13/13 6801-MW110S 516.72 6801-MW104 477.26 2.10E-02 79.4 260.6
05/14/14 6801-MW110S 521.52 6801-MW104 478.26 2.30E-02 87.1 285.7
11/12/14 6801-MW110S 514.27 6801-MW104 477.59 1.95E-02 73.8 242.3
05/13/15 6801-MW110S 519.42 6801-MW104 478.13 2.20E-02 83.1 272.7
11/10/15 6801-MW110S 517.28 6801-MW104 479.58 2.00E-02 75.9 249.0
05/18/16 6801-MW110S 521.29 6801-MW104 479.53 2.22E-02 84.1 275.8
11/14/16 6801-MW110S 517.10 6801-MW104 477.95 2.08E-02 78.8 258.6
05/31/17 6801-MW110S 518.00 6801-MW104 478.38 2.11E-02 79.8 261.7
11/14/16 6801-MW110S 512.54 6801-MW104 477.51 1.86E-02 70.5 231.4
05/15/18 6801-MW110S 516.32 6801-MW104 478.36 2.02E-02 76.4 250.7
11/13/18 6801-MW110S 519.36 6801-MW104 480.89 2.05E-02 77.4 254.1
05/21/19 6801-MW110S 521.34 6801-MW104 478.41 2.28E-02 86.4 283.4
11/20/19 6801-MW110S 513.58 6801-MW104 477.88 1.90E-02 71.9 235.8
05/20/20 6801-MW110S 518.56 6801-MW104 479.86 2.06E-02 77.9 255.6
11/17/20 6801-MW110S 517.79 6801-MW104 478.96 2.06E-02 78.2 256.5
05/18/21 6801-MW110S 519.89 6801-MW104 478.21 2.22E-02 83.9 275.3
11/23/21 6801-MW110S 514.80 6801-MW104 478.09 1.95E-02 73.9 242.5
05/23/22 6801-MW110S 517.04 6801-MW104 479.17 2.01E-02 76.2 250.1
11/08/22 6801-MW110S 512.54 6801-MW104 477.87 1.84E-02 69.8 229.0
05/03/23 6801-MW110S 519.04 6801-MW104 479.06 2.13E-02 80.5 264.1
11/20/23 6801-MW110S 512.74 6801-MW104 477.69 1.86E-02 70.6 231.5
Constants:
distance between wells = 1,881 feet median = 76.9 252.4
hydraulic conductivity = 1.80E-05 meters/second deviation from median
estimated porosity = 0.15 unitless
seconds per year =31557600 seconds
-8.3%
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
GROUNDWATER VELOCITY CALCULATIONS

Groundwater Monitoring Program March, 2024 Results of Sampling and Analysis Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01

Attachment 5: Summary of Organic Constituents

Groundwater Monitoring Program March 2024 Results of Sampling and Analysis Attachment 5 Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01
ATTACHMENT 5 ORGANIC CONSTITUENTS
On November 20, through November 22, 2023 (sampling event 59), TRC personnel obtained groundwater samples from groundwater monitoring wells associated with the Orange County Solid
Waste Management South Facility (south side of Eubanks Road). Information presented on the certificates can be summarized as follows:
We have received copies of the certificates-of-analysis (dated December 4-6, 2023). During event
59, The laboratory did not detect any organic constituents in groundwater at the subject facility. Discussion. During all sampling events, through event 25 (except event 12 [May 2000], during which the reported occurrence of toluene in one upgradient well was deemed unreliable), the laboratory did not detect any organic constituents in groundwater at the subject facility. However, beginning with the June 2007 sampling event, the laboratory began to observe several volatile organic compounds in several monitoring wells:
 benzene
 carbon disulfide
 chlorobenzene
 chloroethane
 cis-1,2-dichloroethene
 1,1-dichloroethane
 trichloroethene
 vinyl chloride The laboratory was not able to quantify (<MRL) the concentrations of most occurrences, and a considerable majority of the reported occurrences pertained to a single well (6801-MW105). Maximum concentrations of volatile organic constituents in well 6801-MW105 were observed during 2012, after which concentrations began decreasing. By May 2014, the laboratory no longer detected any volatile organic constituents in well 6801-
MW105.
During the November 2023 event, Semi-volatile organics (SVOCs) (Method 8270E), PCBs (Method 8082A) and pesticides (Method 8081B) were analyzed from the sample obtained from MW-105. No detections of pesticides, SVOCs or PCBs were reported in the November 2023
analytical results. In response to the initial occurrences of volatile organic constituents in well 6801-MW105,
OCSWM constructed well 6801-MW112 at a location that is approximately 190 feet
downgradient of well 6801-MW105.

Groundwater Monitoring Program March 2024 Results of Sampling and Analysis Attachment 5 Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01
The laboratory has reported only trace levels (always less than 1 ppb) of several volatile organic constituents in well 6801-MW112.
By May 2013, the laboratory no longer reliably detected any volatile organic constituents in well
6801-MW112 and there were no detections in November 2023.

Groundwater Monitoring Program March, 2024 Results of Sampling and Analysis Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01

Attachment 5: Organic Constituents Tables
acetone 05/18/95
MCL = 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 6000 (2L Std)02/28/96
2L Std = 700 (pre- Jan. 2010)08/27/96
2L Std = 6000 (Jan. 2010)02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/06/05
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 2.9 JB 1.2 100 f
06/09/08 <1.2 <1.2 <1.2 <1.2 <1.2 5.5 JB <1.2 1.2 100
11/06/08 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100 f
05/20/09 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
10/20/09 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
06/23/10 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
11/17/10 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
05/25/11 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100
11/16/11 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100
06/07/12 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100
11/14/12 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100
05/14/13 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100
11/13/13 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100
05/14/14 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100
11/12/14 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100
05/13/15 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100
11/10/15 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 5.0 100
05/18/16 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100
11/14/16 <10 <10 <10 <10 <10 <10 <10 10 100
05/31/17 <10 <10 <10 <10 <10 <10 <10 10 100
11/15/17 <10 <10 <10 <10 <10 <10 <10 10 100
05/16/18 <10 <10 <10 <10 <10 <10 <10 10 100
11/13/18 <10 <10 <10 <10 <10 <10 <10 10 20
05/21/19 <10 15 J <10 <10 <10 <10 <10 10 20 lcs
11/20/19 <10 <10 <10 <10 <10 <10 <10 10 20
05/20/20 <10 <10 <10 <10 10 20
11/18/20 <10 <10 <10 <10 10 20
05/18/21 <10 <10 <10 <10 10 20
11/23/21 <10 <10 <10 <10 10 20
05/23/22 <10 <10 <10 <10 10 20
11/08/22 <10 <10 <10 <10 10 20
05/02/23 <10 <10 <10 <10 10 20
11/20/23 <25.0 <25.0 <25.0 <25.0 25
PROJECT: GROUNDWATER MONITORING PROGRAM
HISTORY OF CHEMICAL ANALYSIS
ORGANIC CONSTITUENTS
MW-105 MDL MRL QA/QC
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
Constituent Sample Date MW-101 MW-102S MW-102D MW-102 DR MW-103D MW-104MW-103S
acetone 05/18/95
MCL = 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 6000 (2L Std)02/28/96
2L Std = 700 (pre- Jan. 2010)08/27/96
2L Std = 6000 (Jan. 2010)02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/01/05
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100 f
06/09/08 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100
11/06/08 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100 f
05/20/09 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
10/20/09 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
06/23/10 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
11/17/10 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
05/25/11 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100
11/16/11 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100
06/07/12 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100
11/14/12 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100
05/14/13 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100
11/13/13 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100
05/14/14 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100
11/12/14 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100
05/13/15 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100
11/10/15 <5.0 <5.0 <5.0 <5.0 <5.0 5.0 100
05/18/16 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100
11/14/16 <10 <10 <10 <10 <10 10 100
05/31/17 <10 <10 <10 <10 <10 10 100
11/15/17 <10 <10 <10 <10 <10 10 100
05/16/18 <10 <10 <10 <10 <10 10 100
11/13/18 <10 <10 <10 <10 <10 10 20
05/21/19 <10 <10 <10 <10 <10 10 20 lcs
11/20/19 <10 <10 <10 <10 <10 10 20
05/20/20 <10 <10 <10 <10 10 20
11/18/20 <10 <10 <10 <10 10 20
05/18/21 <10 <10 <10 <10 10 20
11/29/21 <10 <10 <10 <10 10 20
05/23/22 <10 <10 <10 <10 10 20
11/08/22 <10 <10 <10 <10 10 20
05/02/23 <10 <10 <10 <10 10 20
11/20/23 <25.0 <25.0 <25.0 <25.0 25
MW110S
PROJECT: GROUNDWATER MONITORING PROGRAM
HISTORY OF CHEMICAL ANALYSIS
ORGANIC CONSTITUENTS
MW-110D MW-111ConstituentSample Date
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
MDL MRL QA/QCMW-112MW-106 MW-107 MW-108
benzene 05/18/95
MCL = 5 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 1 (2L Std)02/28/96
08/27/96
02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/06/05
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07
06/09/08
11/06/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.2 J 0.1 1.0
05/20/09 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 1.0
10/20/09 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 1.0
06/23/10 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 0.05 1.0
11/17/10 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 1.0
05/25/11 <0.68 <0.68 <0.68 <0.68 <0.68 <0.68 0.7 J 0.68 1.0
11/16/11 <0.68 <0.68 <0.68 <0.68 <0.68 <0.68 <0.68 0.68 1.0
06/07/12 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 1.1 0.15 1.0
verification event 07/19/12 0.83 J 0.15 1.0
11/14/12 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.62 J 0.15 1.0
05/14/13 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/13/13 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/14/14 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/12/14 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/13/15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/10/15 <0.71 <0.71 <0.71 <0.71 <0.71 <0.71 <0.71 0.71 1.0
05/18/16 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/14/16 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/31/17 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/15/17 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/16/18 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/13/18 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/21/19 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/20/19 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/20/20 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/18/20 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/18/21 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/23/21 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/23/22 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/08/22 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/02/23 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
HISTORY OF CHEMICAL ANALYSIS
ORGANIC CONSTITUENTS
Constituent Sample Date MW-101 MW-102S MW-102D MW-102 DR MW-103D MW-104 MW-105 MDL MRL
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
QA/QCMW-103S
benzene 05/18/95
MCL = 5 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 1 (2L Std)02/28/96
08/27/96
02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/01/05
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07 <0.5 <0.5 <0.5 <0.5 <0.5 0.5 100
06/09/08 <0.5 <0.5 <0.5 <0.5 <0.5 0.5 100
11/06/08 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0
05/20/09 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 1.0
10/20/09 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 1.0
06/23/10 <0.05 <0.05 <0.05 <0.05 <0.05 0.05 1.0
11/17/10 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 1.0
05/25/11 <0.68 <0.68 <0.68 <0.68 <0.68 <0.68 0.68 1.0
11/16/11 <0.68 <0.68 <0.68 <0.68 <0.68 <0.68 0.68 1.0
06/07/12 <0.15 <0.15 <0.15 <0.15 <0.15 0.41 J 0.15 1.0
verification event 07/19/12 0.15 1.0
11/14/12 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/14/13 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/13/13 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/14/14 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/12/14 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/13/15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/10/15 <0.71 <0.71 <0.71 <0.71 <0.71 0.71 1.0
05/18/16 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/14/16 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/31/17 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/15/17 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/16/18 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/13/18 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/21/19 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/20/19 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/20/20 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/18/20 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/18/21 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/29/21 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/23/22 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/08/22 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/02/23 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
MW110S
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
HISTORY OF CHEMICAL ANALYSIS
ORGANIC CONSTITUENTS
QA/QCMW-112MW-111 MDL MRLConstituentSample Date MW-106 MW-107 MW-108 MW-110D
carbon disulfide 05/18/95
MCL = 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 700 (2L Std)02/28/96
08/27/96
02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/06/05
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 3.2 J 0.5 100
06/09/08 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 0.5 100
11/06/08 <0.5 1.6 J 1.1 J <0.5 <0.5 <0.5 0.8 J 0.5 100
05/20/09 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 0.54 100
10/20/09 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 0.54 100
06/23/10 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 0.54 100
11/17/10 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 0.54 100
05/25/11 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
11/16/11 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
06/07/12 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
11/14/12 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
05/14/13 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
11/13/13 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
05/14/14 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
11/12/14 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
05/13/15 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
11/10/15 <2.6 <2.6 <2.6 <2.6 <2.6 <2.6 <2.6 2.6 100
05/18/16 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
11/14/16 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
05/31/17 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
11/15/17 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
05/16/18 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
11/13/18 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 5.0
05/21/19 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 5.0
11/20/19 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 5.0
05/20/20 <1.5 <1.5 <1.5 <1.5 1.5 5.0
11/18/20 <1.5 <1.5 <1.5 <1.5 1.5 5.0
05/18/21 <1.5 <1.5 <1.5 <1.5 1.5 5.0
11/23/21 <1.5 <1.5 <1.5 <1.5 1.5 5.0
05/23/22 <1.5 <1.5 <1.5 <1.5 1.5 5.0
11/08/22 <1.5 <1.5 <1.5 <1.5 1.5 5.0
05/02/23 <1.5 <1.5 <1.5 <1.5 1.5 5.0
11/20/23 <2.0 <2.0 <2.0 <2.0 2.0
Constituent Sample Date MW-101 MW-102S MW-102D MW-102 DR
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
HISTORY OF CHEMICAL ANALYSIS
ORGANIC CONSTITUENTS
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
MW-103S QA/QCMW-103D MW-104 MW-105 MDL MRL
carbon disulfide 05/18/95
MCL = 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 700 (2L Std)02/28/96
08/27/96
02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/01/05
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07 <0.5 <0.5 <0.5 <0.5 <0.5 0.5 100
06/09/08 <0.5 <0.5 <0.5 <0.5 <0.5 0.5 100
11/06/08 <0.5 <0.5 <0.5 <0.5 <0.5 0.5 100
05/20/09 <0.54 <0.54 <0.54 <0.54 <0.54 0.54 100
10/20/09 <0.54 <0.54 <0.54 <0.54 <0.54 0.54 100
06/23/10 <0.54 <0.54 <0.54 <0.54 <0.54 0.54 100
11/17/10 <0.54 <0.54 <0.54 <0.54 <0.54 0.54 100
05/25/11 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
11/16/11 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
06/07/12 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
11/14/12 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
05/14/13 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
11/13/13 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
05/14/14 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
11/12/14 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
05/13/15 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
11/10/15 <2.6 <2.6 <2.6 <2.6 <2.6 2.6 100
05/18/16 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
11/14/16 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
05/31/17 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
11/15/17 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
05/16/18 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100
11/13/18 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 5.0
05/21/19 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 5.0
11/20/19 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 5.0
05/20/20 <1.5 <1.5 <1.5 <1.5 1.5 5.0
11/18/20 <1.5 <1.5 <1.5 <1.5 1.5 5.0
05/18/21 <1.5 <1.5 <1.5 <1.5 1.5 5.0
11/29/21 <1.5 <1.5 <1.5 <1.5 1.5 5.0
05/23/22 <1.5 <1.5 <1.5 <1.5 1.5 5.0
11/08/22 <1.5 <1.5 <1.5 <1.5 1.5 5.0
05/02/23 <1.5 <1.5 <1.5 <1.5 1.5 5.0
11/20/23 <2.0 <2.0 <2.0 <2.0 2.0
MW110S
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
HISTORY OF CHEMICAL ANALYSIS
ORGANIC CONSTITUENTS
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
Constituent Sample Date MW-106 MW-107 MW-108 MW-112MW-110D MW-111 MDL MRL QA/QC
chlorobenzene 05/18/95
MCL = 100 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 50 (2L Std)02/28/96
08/27/96
02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/06/05
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07 0.27 J <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 3.0
06/09/08 3 J <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 3.0 ic, cc
11/06/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 3.0
05/20/09 3.6 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 3.0
10/20/09 1.1 J <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 3.0
06/23/10 <0.069 <0.069 <0.069 <0.069 <0.069 <0.069 <0.069 0.069 3.0
11/17/10 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 3.0
05/25/11 <0.74 <0.74 <0.74 <0.74 <0.74 <0.74 <0.74 0.74 3.0
11/16/11 <0.74 <0.74 <0.74 <0.74 <0.74 <0.74 <0.74 0.74 3.0
06/07/12 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3.0
11/14/12 1.3 J <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3.0
05/14/13 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3.0
11/13/13 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3.0
05/14/14 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3.0
11/14/14 1.4 J <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3.0
05/13/15 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3.0
11/10/15 <0.72 <0.72 <0.72 <0.72 <0.72 <0.72 <0.72 0.72 3.0
05/18/16 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3.0
11/14/16 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3.0
05/31/17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3.0
11/15/17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3.0
05/16/18 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3.0
11/13/18 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 1.0
05/21/19 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 1.0
11/20/19 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 1.0
05/20/20 <0.17 <0.17 <0.17 <0.17 0.17 1.0
11/18/20 <0.17 <0.17 <0.17 <0.17 0.17 1.0
05/18/21 <0.17 <0.17 <0.17 <0.17 0.17 1.0
11/23/21 <0.17 <0.17 <0.17 <0.17 0.17 1.0
05/23/22 <0.17 <0.17 <0.17 <0.17 0.17 1.0
11/08/22 <0.17 <0.17 <0.17 <0.17 0.17 1.0
05/02/23 <0.17 <0.17 <0.17 <0.17 0.17 1.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
PROJECT: GROUNDWATER MONITORING PROGRAM
HISTORY OF CHEMICAL ANALYSISORGANIC CONSTITUENTS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
Constituent Sample Date MW-101 MW-102S MW-102D MW-102 DR MW-103D MW-104 MW-105 MDL MRL QA/QCMW-103S
chlorobenzene 05/18/95
MCL = 100 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 50 (2L Std)02/28/96
08/27/96
02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/01/05
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 3.0
06/09/08 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 3.0 ic, cc
11/06/08 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 3.0
05/20/09 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 3.0
10/20/09 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 3.0
06/23/10 <0.069 <0.069 <0.069 <0.069 <0.069 0.069 3.0
11/17/10 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 3.0
05/25/11 <0.74 <0.74 <0.74 <0.74 <0.74 <0.74 0.74 3.0
11/16/11 <0.74 <0.74 <0.74 <0.74 <0.74 <0.74 0.74 3.0
06/07/12 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3.0
11/14/12 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3.0
05/14/13 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3.0
11/13/13 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3.0
05/14/14 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3.0
11/14/14 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3.0
05/13/15 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3.0
11/10/15 <0.72 <0.72 <0.72 <0.72 <0.72 0.72 3.0
05/18/16 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3.0
11/14/16 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3.0
05/31/17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3.0
11/15/17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3.0
05/16/18 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3.0
11/13/18 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 1.0
05/21/19 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 1.0
11/20/19 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 1.0
05/20/20 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 1.0
11/18/20 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 1.0
05/18/21 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 1.0
11/29/21 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 1.0
05/23/22 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 1.0
11/08/22 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 1.0
05/02/23 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 1.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
MW110S MRL QA/QC
PROJECT: GROUNDWATER MONITORING PROGRAM
HISTORY OF CHEMICAL ANALYSISORGANIC CONSTITUENTS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
MDLMW-112MW-106 MW-107 MW-108 MW-110D MW-111ConstituentSample Date
chloroethane 05/18/95
MCL = 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 3000 (2L Std)02/28/96
2L Std = NE (pre- Jan. 2010)08/27/96
2L Std = 3000 (Jan. 2010)02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/06/05
11/03/05
05/24/06
11/15/06
06/14/07 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 2.6 J 0.1 10 ic, cc
12/11/07 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.4 J 0.1 10
06/09/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.8 J 0.1 10 ic, cc
11/06/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.7 J 0.1 10
11/12/08 0.87 J 0.3 10
05/20/09 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 0.3 10
10/20/09 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 0.56 J 0.3 10
06/23/10 <0.18 <0.18 <0.18 <0.18 <0.18 <0.18 <0.18 0.18 10
11/17/10 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 0.62 J 0.3 10
05/25/11 <0.75 <0.75 <0.75 <0.75 <0.75 <0.75 0.76 J 0.75 10
11/16/11 <0.75 <0.75 <0.75 <0.75 <0.75 <0.75 <0.75 0.75 10
06/07/12 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10
11/14/12 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10
05/14/13 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10
11/13/13 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10
05/14/14 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10
11/12/14 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10
05/13/15 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10
11/10/15 <0.98 <0.98 <0.98 <0.98 <0.98 <0.98 <0.98 0.98 10
05/18/16 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10
11/14/16 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10
05/31/17 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10
11/15/17 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10
05/16/18 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10
11/13/18 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1.0
05/21/19 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1.0
11/20/19 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1.0
05/20/20 <0.23 <0.23 <0.23 <0.23 0.23 1.0
11/18/20 <0.23 <0.23 <0.23 <0.23 0.23 1.0
05/18/21 <0.23 <0.23 <0.23 <0.23 0.23 1.0
11/23/21 <0.23 <0.23 <0.23 <0.23 0.23 1.0
05/23/22 <0.23 <0.23 <0.23 <0.23 0.23 1.0
11/08/22 <0.23 <0.23 <0.23 <0.23 0.23 1.0
05/02/23 <0.23 <0.23 <0.23 <0.23 0.23 1.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
Sample Date MW-101 MW-102S MW-102D MW-102 DR
HISTORY OF CHEMICAL ANALYSIS
ORGANIC CONSTITUENTS
MW-103S QA/QCMW-103D MW-104 MW-105 MDL MRLConstituent
chloroethane 05/18/95
MCL = 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 3000 (2L Std)02/28/96
2L Std = NE (pre- Jan. 2010)08/27/96
2L Std = 3000 (Jan. 2010)02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/01/05
11/03/05
05/24/06
11/15/06
06/14/07 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 10 ic, cc
12/11/07 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 10
06/09/08 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 10 ic, cc
11/06/08 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 10
11/12/08 0.3 10
05/20/09 <0.3 <0.3 <0.3 <0.3 <0.3 0.3 10
10/20/09 <0.3 <0.3 <0.3 <0.3 <0.3 0.3 10
06/23/10 <0.18 <0.18 <0.18 <0.18 <0.18 0.18 10
11/17/10 <0.3 <0.3 <0.3 <0.3 <0.3 0.3 10
05/25/11 <0.75 <0.75 <0.75 <0.75 <0.75 <0.75 0.75 10
11/16/11 <0.75 <0.75 <0.75 <0.75 <0.75 <0.75 0.75 10
06/07/12 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10
11/14/12 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10
05/14/13 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10
11/13/13 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10
05/14/14 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10
11/12/14 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10
05/13/15 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10
11/10/15 <0.98 <0.98 <0.98 <0.98 <0.98 0.98 10
05/18/16 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10
11/14/16 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10
05/31/17 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10
11/15/17 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10
05/16/18 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10
11/13/18 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1.0
05/21/19 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1.0
11/20/19 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1.0
05/20/20 <0.23 <0.23 <0.23 <0.23 0.23 1.0
11/18/20 <0.23 <0.23 <0.23 <0.23 0.23 1.0
05/18/21 <0.23 <0.23 <0.23 <0.23 0.23 1.0
11/29/21 <0.23 <0.23 <0.23 <0.23 0.23 1.0
05/23/22 <0.23 <0.23 <0.23 <0.23 0.23 1.0
11/08/22 <0.23 <0.23 <0.23 <0.23 0.23 1.0
05/02/23 <0.23 <0.23 <0.23 <0.23 0.23 1.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
MW110S
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
HISTORY OF CHEMICAL ANALYSIS
ORGANIC CONSTITUENTS
MW-110D MW-111 MDL MRL QA/QCConstituentSample Date MW-106 MW-107 MW-108 MW-112
chloromethane 05/18/95
MCL = 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 3 (2L Std)02/28/96
2L Std = 2.6 (pre- Jan. 2010)08/27/96
2L Std = 3 (Jan. 2010)02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/06/05
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07
06/09/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.4 J 0.1 1.0 ic, cc
11/06/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0 f
05/20/09 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 0.34 1.0
10/20/09 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 0.34 1.0
06/23/10 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 0.05 1.0
11/17/10 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 0.34 1.0
05/25/11 <0.55 <0.55 <0.55 <0.55 <0.55 <0.55 <0.55 0.55 1.0
11/16/11 <0.55 <0.55 <0.55 <0.55 <0.55 <0.55 <0.55 0.55 1.0
06/07/12 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/14/12 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/14/13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/13/13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/14/14 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/12/14 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/13/15 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/10/15 <0.82 <0.82 <0.82 <0.82 <0.82 <0.82 <0.82 0.82 1.0
05/18/16 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/14/16 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/31/17 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/15/17 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/16/18 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/13/18 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/21/19 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/20/19 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/20/20 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/18/20 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/18/21 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/23/21 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/23/22 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/08/22 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/02/23 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
HISTORY OF CHEMICAL ANALYSIS
ORGANIC CONSTITUENTS
Constituent Sample Date MW-101 MW-102S MW-102D MW-102 DR MW-103D MW-104MW-103S MW-105 MDL MRL QA/QC
chloromethane 05/18/95
MCL = 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 3 (2L Std)02/28/96
2L Std = 2.6 (pre- Jan. 2010)08/27/96
2L Std = 3 (Jan. 2010)02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/01/05
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07
06/09/08 0.5 J <0.1 <0.1 <0.1 <0.1 0.1 1.0 ic, cc
11/06/08 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0 f
05/20/09 <0.34 <0.34 <0.34 <0.34 <0.34 0.34 1.0
10/20/09 <0.34 <0.34 <0.34 <0.34 <0.34 0.34 1.0
06/23/10 <0.05 <0.05 <0.05 <0.05 <0.05 0.05 1.0
11/17/10 <0.05 <0.05 <0.05 <0.05 <0.05 0.05 1.0
05/25/11 <0.55 <0.55 <0.55 <0.55 <0.55 <0.55 0.55 1.0
11/16/11 <0.55 <0.55 <0.55 <0.55 <0.55 <0.55 0.55 1.0
06/07/12 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/14/12 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/14/13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/13/13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/14/14 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/12/14 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/13/15 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/10/15 <0.82 <0.82 <0.82 <0.82 <0.82 0.82 1.0
05/18/16 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/14/16 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/31/17 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/15/17 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/16/18 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/13/18 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/21/19 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/20/19 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/20/20 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/18/20 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/18/21 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/29/21 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/23/22 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/08/22 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/02/23 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
MW110S MW-111
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
HISTORY OF CHEMICAL ANALYSIS
ORGANIC CONSTITUENTS
Constituent Sample Date MDL MRL QA/QCMW-112MW-106 MW-107 MW-108 MW-110D
1,1-dichloroethane 05/18/95
MCL = 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 6 (2L Std)02/28/96
2L Std = 70 (pre- Jan. 2010)08/27/96
2L Std = 6 (Jan. 2010)02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/06/05
11/03/05
05/24/06
11/15/06
06/14/07 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.5 J 0.2 5.0 ic, cc
12/11/07 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.3 J 0.2 5.0
06/09/08 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.6 J 0.2 5.0 ic, cc
11/06/08 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.6 J 0.2 5.0
11/12/08 0.75 J 0.33 5.0
05/20/09 0.60 J <0.33 <0.33 <0.33 <0.33 <0.33 0.76 J 0.33 5.0
10/20/09 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 0.63 J 0.33 5.0
06/23/10 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 0.43 J 0.05 5.0
11/17/10 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 0.53 J 0.33 5.0
05/25/11 <0.08 <0.08 <0.08 <0.08 <0.08 <0.08 0.97 J 0.08 5.0
11/16/11 <0.08 <0.08 <0.08 <0.08 <0.08 <0.08 0.45 J 0.08 5.0
06/07/12 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.95 J 0.13 5.0
11/14/12 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.65 J 0.13 5.0
05/14/13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 5.0
11/13/13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.41 J 0.13 5.0
05/14/14 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 5.0
11/12/14 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 5.0
05/13/15 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 5.0
11/10/15 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 0.62 5.0
05/18/16 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 5.0
11/14/16 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 5.0
05/31/17 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 5.0
11/15/17 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 5.0
05/16/18 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 5.0
11/13/18 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/21/19 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/20/19 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/20/20 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/18/20 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/18/21 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/23/21 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/23/22 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/08/22 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/02/23 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
ORGANIC CONSTITUENTS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
PROJECT: GROUNDWATER MONITORING PROGRAM
HISTORY OF CHEMICAL ANALYSIS
MW-103SSample Date MW-101 MW-102S MW-102D MW-102 DR MW-103D MW-104 MW-105 MDL MRL QA/QC
LOCATION: CHAPEL HILL, NORTH CAROLINA
Constituent
1,1-dichloroethane 05/18/95
MCL = 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 6 (2L Std)02/28/96
2L Std = 70 (pre- Jan. 2010)08/27/96
2L Std = 6 (Jan. 2010)02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/01/05
11/03/05
05/24/06
11/15/06
06/14/07 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 5.0 ic, cc
12/11/07 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 5.0
06/09/08 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 5.0 ic, cc
11/06/08 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 5.0
11/12/08 0.33 5.0
05/20/09 <0.33 <0.33 <0.33 <0.33 <0.33 0.33 5.0
10/20/09 <0.33 <0.33 <0.33 <0.33 0.41 J 0.33 5.0
06/23/10 <0.05 <0.05 <0.05 <0.05 <0.05 0.05 5.0
11/17/10 <0.33 <0.33 <0.33 <0.33 <0.33 0.33 5.0
05/25/11 <0.08 <0.08 <0.08 <0.08 <0.08 0.49 J 0.08 5.0
11/16/11 <0.08 <0.08 <0.08 <0.08 <0.08 <0.08 0.08 5.0
06/07/12 <0.13 <0.13 <0.13 <0.13 <0.13 0.48 J 0.13 5.0
11/14/12 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 5.0
05/14/13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 5.0
11/13/13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 5.0
05/14/14 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 5.0
11/12/14 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 5.0
05/13/15 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 5.0
11/10/15 <0.62 <0.62 <0.62 <0.62 <0.62 0.62 5.0
05/18/16 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 5.0
11/14/16 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 5.0
05/31/17 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 5.0
11/15/17 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 5.0
05/16/18 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 5.0
11/13/18 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/21/19 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/20/19 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/20/20 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/18/20 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/18/21 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/29/21 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/23/22 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/08/22 <0.13 <0.13 <0.13 <0.13 0.13 1.0
05/02/23 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
MW-112
ORGANIC CONSTITUENTS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
PROJECT: GROUNDWATER MONITORING PROGRAM
HISTORY OF CHEMICAL ANALYSIS
QA/QCMW110S MDL MRLMW-106 MW-107 MW-108 MW-110D MW-111ConstituentSample Date
LOCATION: CHAPEL HILL, NORTH CAROLINA
cis-1,2-dichloroethene 05/18/95
MCL = 70 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 70 (2L Std)02/28/96
08/27/96
02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/06/05
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.4 J 0.1 5.0
06/09/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.8 J 0.1 5.0 ic, cc
11/06/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.8 J 0.1 5.0
11/12/08 0.72 J 0.36 5.0
05/20/09 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 1.0 J 0.36 5.0
10/20/09 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 0.51 J 0.36 5.0
06/23/10 <0.075 <0.075 <0.075 <0.075 <0.075 <0.075 0.85 J 0.075 5.0
11/17/10 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 0.41 J 0.36 5.0
05/25/11 <0.72 <0.72 <0.72 <0.72 <0.72 <0.72 1.7 J 0.72 5.0
11/16/11 <0.72 <0.72 <0.72 <0.72 <0.72 <0.72 <0.72 0.72 5.0
06/07/12 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 2.4 J 0.15 5.0
11/14/12 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 1 J 0.15 5.0
verification event 01/08/13 0.15 5.0
05/14/13 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 1 J 0.15 5.0
11/13/13 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.52 J 0.15 5.0
05/14/14 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 5.0
11/12/14 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 5.0
05/13/15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 5.0
11/10/15 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 0.53 5.0
05/18/16 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 5.0
11/14/16 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 5.0
05/31/17 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 5.0
11/15/17 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 5.0
05/16/18 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 5.0
11/13/18 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/21/19 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/20/19 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/20/20 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/18/20 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/18/21 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/23/21 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/23/22 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/08/22 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/02/23 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
Constituent Sample Date MW-101 MW-102S MW-102D MW-102 DR QA/QC
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
MRL
HISTORY OF CHEMICAL ANALYSIS
ORGANIC CONSTITUENTS
MW-104 MW-105 MDL
FACILITY: SOUTH FACILITY
MW-103D MW-103S
cis-1,2-dichloroethene 05/18/95
MCL = 70 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 70 (2L Std)02/28/96
08/27/96
02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/01/05
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 5.0
06/09/08 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 5.0 ic, cc
11/06/08 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 5.0
11/12/08 0.36 5.0
05/20/09 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 5.0
10/20/09 <0.36 <0.36 <0.36 <0.36 0.77 J 0.36 5.0
06/23/10 <0.075 <0.075 <0.075 <0.075 <0.075 0.075 5.0
11/17/10 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 5.0
05/25/11 <0.72 <0.72 <0.72 <0.72 <0.72 0.81 J 0.72 5.0
11/16/11 <0.72 <0.72 <0.72 <0.72 <0.72 <0.72 0.72 5.0
06/07/12 <0.15 <0.15 <0.15 <0.15 <0.15 0.92 J 0.15 5.0
11/14/12 <0.15 0.79 J <0.15 <0.15 <0.15 0.15 5.0
verification event 01/08/13 <0.15 0.15 5.0
05/14/13 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 5.0
11/13/13 <0.15 0.42 J <0.15 <0.15 <0.15 0.15 5.0
05/14/14 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 5.0
11/12/14 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 5.0
05/13/15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 5.0
11/10/15 <0.53 <0.53 <0.53 <0.53 <0.53 0.53 5.0
05/18/16 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 5.0
11/14/16 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 5.0
05/31/17 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 5.0
11/15/17 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 5.0
05/16/18 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 5.0
11/13/18 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/21/19 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/20/19 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/20/20 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/18/20 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/18/21 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/29/21 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/23/22 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/08/22 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/02/23 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
MW110S MDL MRLMW-111 QA/QCConstituentSample Date MW-106 MW-107 MW-108 MW-112
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
MW-110D
FACILITY: SOUTH FACILITY
HISTORY OF CHEMICAL ANALYSIS
ORGANIC CONSTITUENTS
1,2-dichlorobenzene 05/18/95
MCL = 600 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 20 (2L Std)02/28/96
2L Std = 24 (pre- Jan. 2010)08/27/96
2L Std = 20 (Jan. 2010)02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/06/05
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07
06/09/08
11/06/08
11/12/08
05/20/09 0.41 J <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 5.0
10/20/09 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 5.0
06/23/10 <0.052 <0.052 <0.052 <0.052 <0.052 <0.052 <0.052 0.052 5.0
11/17/10 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 5.0
05/25/11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.0
11/16/11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.0
06/07/12 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5.0
11/14/12 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5.0
05/14/13 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5.0
11/13/13 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5.0
05/14/14 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5.0
11/12/14 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5.0
05/13/15 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5.0
11/10/15 <0.73 <0.73 <0.73 <0.73 <0.73 <0.73 <0.73 0.73 5.0
05/18/16 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5.0
11/14/16 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5.0
05/31/17 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5.0
11/15/17 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5.0
05/16/18 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5.0
11/13/18 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/21/19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/20/19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/20/20 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/18/20 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/18/21 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/23/21 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/23/22 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/08/22 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/02/23 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
MW-103S
PROJECT: GROUNDWATER MONITORING PROGRAM
HISTORY OF CHEMICAL ANALYSIS
ORGANIC CONSTITUENTS
LOCATION: CHAPEL HILL, NORTH CAROLINA
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENTFACILITY: SOUTH FACILITY
MW-105 MDL MRL QA/QCConstituentSample Date MW-101 MW-102S MW-102D MW-102 DR MW-103D MW-104
1,2-dichlorobenzene 05/18/95
MCL = 600 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 20 (2L Std)02/28/96
2L Std = 24 (pre- Jan. 2010)08/27/96
2L Std = 20 (Jan. 2010)02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/01/05
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07
06/09/08
11/06/08
11/12/08
05/20/09 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 5.0
10/20/09 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 5.0
06/23/10 <0.052 <0.052 <0.052 <0.052 <0.052 0.052 5.0
11/17/10 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 5.0
05/25/11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.0
11/16/11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.0
06/07/12 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5.0
11/14/12 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5.0
05/14/13 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5.0
11/13/13 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5.0
05/14/14 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5.0
11/12/14 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5.0
05/13/15 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5.0
11/10/15 <0.73 <0.73 <0.73 <0.73 <0.73 0.73 5.0
05/18/16 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5.0
11/14/16 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5.0
05/31/17 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5.0
11/15/17 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5.0
05/16/18 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5.0
11/13/18 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/21/19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/20/19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/20/20 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/18/20 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/18/21 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/29/21 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/23/22 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/08/22 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/02/23 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
MW110S
PROJECT: GROUNDWATER MONITORING PROGRAM
HISTORY OF CHEMICAL ANALYSIS
ORGANIC CONSTITUENTS
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
MW-110D MW-111
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
MDL MRL QA/QCMW-112ConstituentSample Date MW-106 MW-107 MW-108
1,4-dichlorobenzene 05/18/95
MCL = 75 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 6 (2L Std)02/28/96
2L Std = 1.4 (pre- Jan. 2010)08/27/96
2L Std = 6 (Jan. 2010)02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/06/05
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07
06/09/08
11/06/08
11/12/08
05/20/09 0.51 J <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 0.38 1.0
10/20/09 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 0.38 1.0
06/23/10 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0
11/17/10 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 0.38 1.0
05/25/11 <0.79 <0.79 <0.79 <0.79 <0.79 <0.79 <0.79 0.79 1.0
11/16/11 <0.79 <0.79 <0.79 <0.79 <0.79 <0.79 <0.79 0.79 1.0
06/07/12 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/14/12 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/14/13 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/13/13 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/14/14 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/12/14 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/13/15 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/10/15 <0.76 <0.76 <0.76 <0.76 <0.76 <0.76 <0.76 0.76 1.0
05/18/16 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/14/16 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/31/17 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/15/17 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/16/18 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/13/18 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/21/19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/20/19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/20/20 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/18/10 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/18/21 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/23/21 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/23/22 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/08/22 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/02/23 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
MW-103S
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
HISTORY OF CHEMICAL ANALYSIS
ORGANIC CONSTITUENTS
Constituent Sample Date MW-101 MW-102S MW-102D MW-102 DR MW-103D MW-104 MW-105 MDL MRL QA/QC
1,4-dichlorobenzene 05/18/95
MCL = 75 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 6 (2L Std)02/28/96
2L Std = 1.4 (pre- Jan. 2010)08/27/96
2L Std = 6 (Jan. 2010)02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/01/05
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07
06/09/08
11/06/08
11/12/08
05/20/09 <0.38 <0.38 <0.38 <0.38 <0.38 0.38 1.0
10/20/09 <0.38 <0.38 <0.38 <0.38 <0.38 0.38 1.0
06/23/10 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0
11/17/10 <0.38 <0.38 <0.38 <0.38 <0.38 0.38 1.0
05/25/11 <0.79 <0.79 <0.79 <0.79 <0.79 <0.79 0.79 1.0
11/16/11 <0.79 <0.79 <0.79 <0.79 <0.79 <0.79 0.79 1.0
06/07/12 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/14/12 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/14/13 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/13/13 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/14/14 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/12/14 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/13/15 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/10/15 <0.76 <0.76 <0.76 <0.76 <0.76 0.76 1.0
05/18/16 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/14/16 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/31/17 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/15/17 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/16/18 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/13/18 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/21/19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/20/19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/20/20 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/18/20 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/18/21 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/29/21 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/23/22 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/08/22 <0.19 <0.19 <0.19 <0.19 0.19 1.0
05/02/23 <0.19 <0.19 <0.19 <0.19 0.19 1.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
MW110S MW-112
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
MW-110D MW-111
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
HISTORY OF CHEMICAL ANALYSIS
MDL MRL QA/QC
ORGANIC CONSTITUENTS
MW-106 MW-107 MW-108ConstituentSample Date
methylene chloride 05/18/95
MCL = 5 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 5 (2L Std)02/28/96
08/27/96
02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/06/05
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07
06/09/08
11/06/08
11/12/08
05/20/09
10/20/09
06/23/10
11/17/10
05/25/11
11/16/11
06/07/12
11/14/12
05/14/13
11/13/13
05/14/14
11/12/14
05/13/15
11/10/15
05/18/16
11/14/16
05/31/17
11/15/17
05/16/18
11/13/18 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1.0
05/21/19 <0.23 0.42 J <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1.0
11/20/19 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1.0
05/20/20 <0.23 <0.23 <0.23 <0.23 0.23 1.0
11/18/20 <0.23 <0.23 <0.23 <0.23 0.23 1.0
05/18/21 <0.23 <0.23 <0.23 <0.23 0.23 1.0
11/23/21 <0.23 <0.23 <0.23 <0.23 0.23 1.0
05/23/22 <0.23 <0.23 <0.23 <0.23 0.23 1.0
11/08/22 <0.23 <0.23 <0.23 <0.23 0.23 1.0
05/02/23 <0.23 <0.23 <0.23 <0.23 0.23 1.0
11/20/23 <5.0 <5.0 <5.0 <5.0 5.0
HISTORY OF CHEMICAL ANALYSIS
ORGANIC CONSTITUENTS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
MW-105 MDL MRL QA/QCConstituentSample Date MW-101 MW-102S MW-102D MW-102 DR MW-103S MW-103D MW-104
methylene chloride 05/18/95
MCL = 5 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 5 (2L Std)02/28/96
08/27/96
02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/01/05
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07
06/09/08
11/06/08
11/12/08
05/20/09
10/20/09
06/23/10
11/17/10
05/25/11
11/16/11
06/07/12
11/14/12
05/14/13
11/13/13
05/14/14
11/12/14
05/13/15
11/10/15
05/18/16
11/14/16
05/31/17
11/15/17
05/16/18
11/13/18 <0.23 0.54 J <0.23 <0.23 0.63 J 0.23 1.0
05/21/19 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1.0
11/20/19 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1.0 t= 0.99 J
05/20/20 <0.23 <0.23 <0.23 <0.23 0.23 1.0
11/18/20 <0.23 <0.23 <0.23 <0.23 0.23 1.0
05/18/21 <0.23 <0.23 <0.23 <0.23 0.23 1.0
11/29/21 <0.23 <0.23 <0.23 <0.23 0.23 1.0
05/23/22 <0.23 <0.23 <0.23 <0.23 0.23 1.0
11/08/22 <0.23 <0.23 <0.23 <0.23 0.23 1.0
05/02/23 <0.23 <0.23 <0.23 <0.23 0.23 1.0
11/20/23 <5.0 <5.0 <5.0 <5.0 5.0
HISTORY OF CHEMICAL ANALYSIS
ORGANIC CONSTITUENTS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
MW110S MW-110D MW-111 MW-112 MDL MRL QA/QCConstituentSample Date MW-106 MW-107 MW-108
toluene 05/18/95 <5 <5 <5 <5 <5 <5 <5
MCL = 1000 07/20/95 <5 <5 <5 <5 <5 <5 <5
FBAC = MDL (LOD)11/28/95 <5 <5 <5 <5 <5 <5 <5
NCGQS = 600 (2L Std)02/28/96 <5 <5 <5 <5 <5 <5 <5
2L Std = 1000 (pre- Jan. 2010)08/27/96 <5 <5 <5 <5 <5 <5 <5
2L Std = 600 (Jan. 2010)02/27/97 <5 <5 <5 <5 <5 <5 <5
09/04/97 <5 <5 <5 <5 <5 <5 <5
03/25/98 <5 <5 <5 <5 <5 <5 <5
11/02/98 <5 <5 <5 <5 <5 <5 <5
04/27/99 <5 <5 <5 <5 <5 <5 <5
11/22/99 <5 <5 <5 <5 <5 <5 <5
05/24/00 <5 <5 <5 <5 <5 <5 <5
11/30/00 <5 <5 <5 <5 <5 <5 <5
05/30/01 <5 <5 <5 <5 <5 <5 <5
11/14/01 <5 <5 <5 <5 <5 <5 <5
06/06/02 <5 <5 <5 <5 <5 <5 <5
03/13/03 <5 <5 <5 <5 <5 <5 <5
06/19/03 <5 <5 <5 <5 <5 <5 <5
12/09/03 <5 <5 <5 <5 <5 <5 <5
06/23/04 <5 <5 <5 <5 <5 <5 <5
12/01/04 <5 <5 <5 <5 <5 <5 <5
06/06/05 <5 <5 <5 <5 <5 <5 <5
11/03/05 <5 <5 <5 <5 <5 <5 <5
05/24/06 <5 <5 <5 <5 <5 <5 <5
11/15/06 <5 <5 <5 <5 <5 <5 <5
06/14/07 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 0.3 1.0 ic, cc
12/11/07 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 0.3 1.0
06/09/08 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 0.3 1.0
11/06/08 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 0.3 1.0
05/20/09 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 1.0
10/20/09 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 1.0
06/23/10 <0.053 <0.053 <0.053 <0.053 <0.053 <0.053 <0.053 0.053 1.0
11/17/10 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 1.0
05/25/11 <0.85 <0.85 <0.85 <0.85 <0.85 <0.85 <0.85 0.85 1.0
11/16/11 <0.85 <0.85 <0.85 <0.85 <0.85 <0.85 <0.85 0.85 1.0
06/07/12 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
11/14/12 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
05/14/13 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
11/13/13 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
05/14/14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
11/12/14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
05/13/15 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
11/10/15 <0.72 <0.72 <0.72 <0.72 <0.72 <0.72 <0.72 0.72 1.0
05/18/16 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
11/14/16 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
05/31/17 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
11/15/17 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
05/16/18 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
11/13/18 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
05/21/19 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
11/20/19 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
05/20/20 <0.14 <0.14 <0.14 <0.14 0.14 1.0
11/18/20 <0.14 <0.14 <0.14 <0.14 0.14 1.0
05/18/21 <0.14 <0.14 <0.14 <0.14 0.14 1.0
11/23/21 <0.14 <0.14 <0.14 <0.14 0.14 1.0
05/23/22 <0.14 <0.14 <0.14 <0.14 0.14 1.0
11/08/22 <0.14 <0.14 <0.14 <0.14 0.14 1.0
05/02/23 <0.14 <0.14 <0.14 <0.14 0.14 1.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
HISTORY OF CHEMICAL ANALYSIS
ORGANIC CONSTITUENTS
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
MW-103D MW-104 MW-105 MDL MRLConstituentSample Date MW-101 MW-102S MW-102D MW-102 DR MW-103S QA/QC
toluene 05/18/95 <5 <5 <5 <5 <5 <5
MCL = 1000 07/20/95 <5 <5 <5 <5 <5 <5
FBAC = MDL (LOD)11/28/95 <5 <5 <5 <5 n <5
NCGQS = 600 (2L Std)02/28/96 <5 <5 <5 <5 <5 <5
2L Std = 1000 (pre- Jan. 2010)08/27/96 <5 <5 <5 <5 <5 <5
2L Std = 600 (Jan. 2010)02/27/97 <5 <5 <5 <5 <5 <5
09/04/97 <5 <5 <5 <5 <5 <5
03/25/98 <5 <5 <5 <5 <5 <5
11/02/98 <5 <5 <5 <5 <5 n
04/27/99 <5 <5 <5 <5 <5 <5
11/22/99 <5 <5 <5 <5 <5 <5
05/24/00 <5 <5 7 R <5 <5 <5
11/30/00 <5 <5 <5 <5 <5 <5
05/30/01 <5 <5 <5 <5 <5 <5
11/14/01 <5 <5 <5 <5 <5 <5
06/06/02 <5 <5 <5 <5 <5 <5
03/13/03 <5 <5 <5 <5 <5 <5
06/19/03 <5 <5 <5 <5 <5 <5
12/09/03 <5 <5 <5 <5
06/23/04 <5 <5 <5 <5
12/01/04 <5 <5 <5 <5
06/01/05 <5 <5 <5 <5 <5
11/03/05 <5 <5 <5 <5 <5
05/24/06 <5 <5 <5 <5 <5
11/15/06 <5 <5 <5 <5 <5
06/14/07 <0.3 <0.3 <0.3 <0.3 <0.3 0.3 1.0 ic, cc
12/11/07 <0.3 <0.3 <0.3 <0.3 <0.3 0.3 1.0
06/09/08 <0.3 <0.3 <0.3 <0.3 <0.3 0.3 1.0
11/06/08 <0.3 <0.3 <0.3 <0.3 <0.3 0.3 1.0
05/20/09 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 1.0
10/20/09 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 1.0
06/23/10 <0.053 <0.053 <0.053 <0.053 <0.053 0.053 1.0
11/17/10 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 1.0
05/25/11 <0.85 <0.85 <0.85 <0.85 <0.85 <0.85 0.85 1.0
11/16/11 <0.85 <0.85 <0.85 <0.85 <0.85 <0.85 0.85 1.0
06/07/12 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
11/14/12 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
05/14/13 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
11/13/13 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
05/14/14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
11/12/14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
05/13/15 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
11/10/15 <0.72 <0.72 <0.72 <0.72 <0.72 0.72 1.0
05/18/16 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
11/14/16 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
05/31/17 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
11/15/17 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
05/16/18 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
11/13/18 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
05/21/19 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
11/20/19 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1.0
05/20/20 <0.14 <0.14 <0.14 <0.14 0.14 1.0
11/18/20 <0.14 <0.14 <0.14 <0.14 0.14 1.0
05/18/21 <0.14 <0.14 <0.14 <0.14 0.14 1.0
11/29/21 <0.14 <0.14 <0.14 <0.14 0.14 1.0
05/23/22 <0.14 <0.14 <0.14 <0.14 0.14 1.0
11/08/22 <0.14 <0.14 <0.14 <0.14 0.14 1.0
05/02/23 <0.14 <0.14 <0.14 <0.14 0.14 1.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
MW-112
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
HISTORY OF CHEMICAL ANALYSIS
ORGANIC CONSTITUENTS
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
MW-110D MW-111 MDL MRL QA/QCConstituentSample Date MW-106 MW-107 MW-108 MW110S
trichloroethene 05/18/95
MCL = 5 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 3 (2L Std)02/28/96
2L Std = 2.8 (pre- Jan. 2010)08/27/96
2L Std = 3 (Jan. 2010)02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/06/05
11/03/05
05/24/06
11/15/06
06/14/07 <0.1 <0.1 <0.1 <0.1 <0.1 0.5 J 1.2 J 0.1 1.0 ic, cc
12/11/07 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.6 J 0.1 1.0
06/09/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 1.5 J 0.1 1.0 ic, cc
11/06/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.8 J 0.1 1.0
11/12/08 0.78 J 0.38 1.0
05/20/09 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 1.3 0.38 1.0
10/20/09 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 0.38 1.0
06/23/10 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.80 J 0.13 1.0
11/17/10 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 0.38 1.0
05/25/11 <0.72 <0.72 <0.72 <0.72 <0.72 <0.72 1.5 0.72 1.0
11/16/11 <0.72 <0.72 <0.72 <0.72 <0.72 <0.72 <0.72 0.72 1.0
06/07/12 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 1.2 0.15 1.0
11/14/12 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
verification event 01/08/13 0.15 1.0
05/14/13 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/13/13 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/14/14 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/12/14 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/13/15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/10/15 <0.89 <0.89 <0.89 <0.89 <0.89 <0.89 <0.89 0.89 1.0
05/18/16 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/14/16 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/31/17 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/15/17 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.005/16/18 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/13/18 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.005/21/19 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.011/20/19 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.005/20/20 <0.15 <0.15 <0.15 <0.15 0.15 1.011/18/20 <0.15 <0.15 <0.15 <0.15 0.15 1.005/18/21 <0.15 <0.15 <0.15 <0.15 0.15 1.011/23/21 <0.15 <0.15 <0.15 <0.15 0.15 1.005/23/22 <0.15 <0.15 <0.15 <0.15 0.15 1.011/08/22 <0.15 <0.15 <0.15 <0.15 0.15 1.005/02/23 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
PROJECT: GROUNDWATER MONITORING PROGRAM
HISTORY OF CHEMICAL ANALYSIS
ORGANIC CONSTITUENTS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
Constituent Sample Date MW-101 MW-102S MW-102D MW-102 DR MW-103D MW-104MW-103S MW-105 MDL MRL QA/QC
trichloroethene 05/18/95
MCL = 5 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 3 (2L Std)02/28/96
2L Std = 2.8 (pre- Jan. 2010)08/27/96
2L Std = 3 (Jan. 2010)02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/01/05
11/03/05
05/24/06
11/15/06
06/14/07 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0 ic, cc
12/11/07 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0
06/09/08 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0 ic, cc
11/06/08 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0
11/12/08 0.38 1.0
05/20/09 <0.38 <0.38 <0.38 <0.38 <0.38 0.38 1.0
10/20/09 <0.38 <0.38 <0.38 <0.38 0.68 J 0.38 1.0
06/23/10 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1.0
11/17/10 <0.38 <0.38 <0.38 <0.38 <0.38 0.38 1.0
05/25/11 <0.72 <0.72 <0.72 <0.72 <0.72 0.79 J 0.72 1.0
11/16/11 <0.72 <0.72 <0.72 <0.72 <0.72 <0.72 0.72 1.0
06/07/12 <0.15 <0.15 <0.15 <0.15 <0.15 0.55 J 0.15 1.0
11/14/12 <0.15 0.66 J <0.15 <0.15 <0.15 0.15 1.0
verification event 01/08/13 <0.15 0.15 1.0
05/14/13 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/13/13 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/14/14 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/12/14 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/13/15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/10/15 <0.89 <0.89 <0.89 <0.89 <0.89 0.89 1.0
05/18/16 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/14/16 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
05/31/17 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/15/17 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.005/16/18 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/13/18 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.005/21/19 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.011/20/19 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1.005/20/20 <0.15 <0.15 <0.15 <0.15 0.15 1.011/18/20 <0.15 <0.15 <0.15 <0.15 0.15 1.005/18/21 <0.15 <0.15 <0.15 <0.15 0.15 1.011/29/21 <0.15 <0.15 <0.15 <0.15 0.15 1.005/23/22 <0.15 <0.15 <0.15 <0.15 0.15 1.011/08/22 <0.15 <0.15 <0.15 <0.15 0.15 1.005/02/23 <0.15 <0.15 <0.15 <0.15 0.15 1.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
MW-112
PROJECT: GROUNDWATER MONITORING PROGRAM
HISTORY OF CHEMICAL ANALYSIS
ORGANIC CONSTITUENTS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
MDL MRL QA/QCMW110S MW-106 MW-107 MW-108 MW-110D MW-111ConstituentSample Date
vinyl chloride 05/18/95
MCL = 2 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 0.03 (2L Std)02/28/96
2L Std = 0.015 (pre- Jan. 2010)08/27/96
2L Std = 0.03 (Jan. 2010)02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/06/05
11/03/05
05/24/06
11/15/06
06/14/07 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 1 J 0.1 1.0 ic, cc
12/11/07 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.5 J 0.1 1.0
06/09/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 1.1 J 0.1 1.0 ic, cc
11/06/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.9 J 0.1 1.0
11/12/08 0.66 J 0.3 1.0
05/20/09 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 0.86 J 0.3 1.0
10/20/09 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 0.86 J 0.3 1.0
06/23/10 <0.083 <0.083 <0.083 <0.083 <0.083 <0.083 0.61 J 0.083 1.0
11/17/10 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 0.3 1.0
05/25/11 <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 1.1 0.6 1.0
verification event 07/06/11 1 0.6 1.0
11/16/11 <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 0.6 1.0
06/07/12 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 1.3 0.32 1.0
verification event 07/19/12 1.1 0.32 1.0
11/14/12 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 0.6 J 0.32 1.0
verification event 01/08/13 0.32 1.0
05/14/13 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 0.32 1.0
11/13/13 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 0.32 1.0
05/14/14 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 0.32 1.0
11/12/14 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 0.32 1.0
05/13/15 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 0.32 1.0
11/10/15 <0.71 <0.71 <0.71 <0.71 <0.71 <0.71 <0.71 0.71 1.0
05/18/16 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 0.32 1.0
11/14/16 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 0.32 1.0
05/31/17 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 0.32 1.0
11/15/17 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 0.32 1.0
05/16/18 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 0.32 1.0
11/13/18 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 0.32 1.0
05/21/19 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 0.32 1.0
11/20/19 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 0.32 1.0
05/20/20 <0.32 <0.32 <0.32 <0.32 0.32 1.0
11/18/20 <0.32 <0.32 <0.32 <0.32 0.32 1.0
05/18/21 <0.32 <0.32 <0.32 <0.32 0.32 1.0
11/23/21 <0.32 <0.32 <0.32 <0.32 0.32 1.0
05/23/22 <0.32 <0.32 <0.32 <0.32 0.32 1.0
11/08/23 <0.32 <0.32 <0.32 <0.32 0.32 1.0
05/02/23 <0.32 <0.32 <0.32 <0.32 0.32 1.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
HISTORY OF CHEMICAL ANALYSIS
ORGANIC CONSTITUENTS
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
QA/QCMW-103D MW-104 MW-105 MDL MRLConstituentSample Date MW-101 MW-102S MW-102D MW-102 DR MW-103S
vinyl chloride 05/18/95
MCL = 2 07/20/95
FBAC = MDL (LOD)11/28/95
NCGQS = 0.03 (2L Std)02/28/96
2L Std = 0.015 (pre- Jan. 2010)08/27/96
2L Std = 0.03 (Jan. 2010)02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/01/05
11/03/05
05/24/06
11/15/06
06/14/07 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0 ic, cc
12/11/07 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0
06/09/08 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0 ic, cc
11/06/08 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0
11/12/08 0.3 1.0
05/20/09 <0.3 <0.3 <0.3 <0.3 <0.3 0.3 1.0
10/20/09 <0.3 <0.3 <0.3 <0.3 <0.3 0.3 1.0
06/23/10 <0.083 <0.083 <0.083 <0.083 <0.083 0.083 1.0
11/17/10 <0.3 <0.3 <0.3 <0.3 <0.3 0.3 1.0
05/25/11 <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 0.6 1.0
verification event 07/06/11 0.6 1.0
11/16/11 <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 0.6 1.0
06/07/12 <0.32 <0.32 <0.32 <0.32 <0.32 0.59 J 0.32 1.0
verification event 07/19/12 0.32 1.0
11/14/12 <0.32 0.88 J <0.32 <0.32 <0.32 0.32 1.0
verification event 01/08/13 <0.32 0.32 1.0
05/14/13 <0.32 <0.32 <0.32 <0.32 <0.32 0.32 1.0
11/13/13 <0.33 0.54 J <0.32 <0.32 <0.32 0.32 1.0
05/14/14 <0.33 <0.32 <0.32 <0.32 <0.32 0.32 1.0
11/12/14 <0.33 <0.32 <0.32 <0.32 <0.32 0.32 1.0
05/13/15 <0.33 <0.32 <0.32 <0.32 <0.32 0.32 1.0
11/10/15 <0.71 <0.71 <0.71 <0.71 <0.71 0.71 1.0
05/18/16 <0.33 <0.32 <0.32 <0.32 <0.32 0.32 1.0
11/14/16 <0.32 <0.32 <0.32 <0.32 <0.32 0.32 1.0
05/31/17 <0.32 <0.32 <0.32 <0.32 <0.32 0.32 1.0
11/15/17 <0.32 <0.32 <0.32 <0.32 <0.32 0.32 1.0
05/16/18 <0.32 <0.32 <0.32 <0.32 <0.32 0.32 1.0
11/13/18 <0.32 <0.32 <0.32 <0.32 <0.32 0.32 1.0
05/21/19 <0.32 <0.32 <0.32 <0.32 <0.32 0.32 1.0
11/20/19 <0.32 <0.32 <0.32 <0.32 <0.32 0.32 1.0
05/20/20 <0.32 <0.32 <0.32 <0.32 0.32 1.0
11/18/20 <0.32 <0.32 <0.32 <0.32 0.32 1.0
05/18/21 <0.32 <0.32 <0.32 <0.32 0.32 1.0
11/29/21 <0.32 <0.32 <0.32 <0.32 0.32 1.0
05/23/22 <0.32 <0.32 <0.32 <0.32 0.32 1.0
11/08/23 <0.32 <0.32 <0.32 <0.32 0.32 1.0
05/02/23 <0.32 <0.32 <0.32 <0.32 0.32 1.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
MW-112
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
HISTORY OF CHEMICAL ANALYSIS
ORGANIC CONSTITUENTS
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
MDL MRL QA/QCConstituentSample Date MW-106 MW-107 MW-108 MW110S MW-110D MW-111
All results in µg/L.
Upgradient wells not shaded.
Empty cells indicate no data available.
Blue bolded cells indicate concentrations that exceeded the FBAC.
Red bolded cells indicate concentrations that exceeded the NCGQS.
Green bolded cells indicate concentrations that were >MDL but <MRL.

R - analyte concentration unreliable S - analyte concentration suspect
i - found in instrument blank t - found in trip blank
f - found in field blank ic - initial calibration beyond limits
cc - continuing calibration beyond limits md - matrix spike duplicates beyond limits
ss - surrogate spikes beyond limits is - internal standard beyond limits
** - no constituents detected for this date lcs - laboratory control sample beyond limits
FBAC - facility background NCGQS - Groundwater Standard, as established by NCDEQ
SWSL -Solid Waste Section Limit, as established by NCDEQ SPL - statistical prediction limit
GWPS - groundwater protection standard SWSL eliminated in 2019 and replaced with Method Reporting Limit
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
HISTORY OF CHEMICAL ANALYSIS
ORGANIC CONSTITUENTS

Groundwater Monitoring Program March, 2024 Results of Sampling and Analysis Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01

Attachment 6: Summary of Inorganic Constituents

Groundwater Monitoring Program February 2024 Results of Sampling and Analysis Attachment 6 Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01
ATTACHMENT 6 INORGANIC CONSTITUENTS
On November 20, through November 22, 2023 (sampling event 59), TRC personnel obtained groundwater samples from groundwater monitoring wells associated with the Orange County Solid Waste Management South Facility (south side of Eubanks Road). Groundwater samples to be analyzed for metals were not filtered in the field, such that all metals were analyzed as total metals. We have received copies of the certificates-of-analysis (dated December 4-6, 2023). Information presented on the certificates are summarized as follows:
 During event 59, the laboratory detected eight inorganic constituents (metals), at
concentrations greater than their respective method detection limits (>MDLs): arsenic, barium, cobalt, copper, iron (C&D parameter), nickel, vanadium and zinc.
 Of the eight inorganic constituents detected (>MDL), the laboratory was able to quantify (>MRL) the concentrations of all eight inorganic constituents: arsenic, barium, cobalt, copper, iron, nickel, vanadium and zinc which are included in this summary.

 Of the eight inorganic constituents that the laboratory were able to quantify (>MRL), the concentrations of five constituents exceeded their respective Regulatory Protection
Standard (2L or FBAC).
 The reported concentration of arsenic in wells 6804-MW105 (33.0 µg/L) exceeded its Facility Background Concentration (15.66 ug/L) and its Groundwater Quality Standard (10 µg/L). The reported concentration of arsenic in well 6804-MW110D (14.0 µg/L) exceeded its Groundwater Quality Standard (10 µg/L). As discussed below, an Alternate Source Demonstration (ASD) was approved for arsenic during September 2011.
 The reported concentration of cobalt in well MW105 (25.8 µg/L) exceeded its Facility Background Concentration (2.15 µg/L) and its Groundwater Quality Standard (1.0 µg/L). As discussed below, an Alternate Source Demonstration (ASD) was approved for cobalt
during March 2011.
 The reported estimated concentration of nickel in wells 6804-MW101(5.5 µg/L) 6804-
MW105 (8.6 µg/L) and 6804-MW111 (6.5 µg/L) exceeded its Facility Background Concentration (2.688 µg/L) but not their Groundwater Quality Standard (100 µg/L).
 The reported concentration of vanadium in well 6804-MW111 (7.6 µg/L), exceeded its Groundwater Quality Standard (0.3 µg/L), and the Facility Background Concentration (6.968 µg/L) As discussed below, an Alternate Source Demonstration (ASD) was approved for vanadium during March 2011.

Groundwater Monitoring Program February 2024 Results of Sampling and Analysis Attachment 6 Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01 Page 2
 The reported concentration of zinc in well 6804-MW101 (24.9 µg/L), exceeded its Facility
Background Concentration (22.83 µg/L) but not its Groundwater Quality Standard (1,000 µg/L). Alternate Source Demonstrations. As summarized below, OCSWM has prepared Alternate Source Demonstrations to address apparent exceedances of several metals at one or more of the three solid waste management units (North, South, C&D). The following Alternate Source Demonstrations pertained to the South landfill:
 Cobalt. OCSWM submitted an Alternate Source Demonstration showing that total cobalt observed in groundwater at the site could have been derived from onsite soils. In a letter from NCDEQ to OCSWM (dated March 30, 2011), NCDEQ approved the Alternate Source Demonstration. In accordance with the approved Alternate Source Demonstration, the reported exceedances of total cobalt may be attributed to the naturally occurring
presence of cobalt in onsite soils.
 Vanadium. OCSWM submitted an Alternate Source Demonstration showing that total
vanadium observed in groundwater at the site could have been derived from onsite soils. In a letter from NCDEQ to OCSWM (dated May 26, 2010), NCDEQ approved the Alternate Source Demonstration. In accordance with the approved Alternate Source
Demonstration, the reported exceedances of total vanadium may be attributed to the naturally occurring presence of vanadium in onsite soil and rock. The following Alternate Source Demonstrations pertained to the North landfill:
 Arsenic. OCSWM submitted an Alternate Source Demonstration (dated September 2,
2011), showing that total arsenic observed in groundwater at the facility could have been derived from onsite soils. In a letter from NCDEQ to OCSWM (dated September 26, 2011), NCDEQ approved the Alternate Source Demonstration. In accordance with the approved Alternate Source Demonstration, the reported exceedances of total arsenic may be attributed to the naturally occurring presence of arsenic in onsite soils.

 Cobalt. OCSWM submitted an Alternate Source Demonstration (dated September 2, 2011), showing that total cobalt observed in groundwater at the facility could have been
derived from onsite soils. In a letter from NCDEQ to OCSWM (dated September 26, 2011), NCDEQ approved the Alternate Source Demonstration. In accordance with the approved Alternate Source Demonstration, the reported exceedances of total cobalt may be
attributed to the naturally occurring presence of cobalt in onsite soils.
 Lead. OCSWM submitted an Alternate Source Demonstration (dated September 2, 2011), showing that total lead observed in groundwater at the facility could have been derived from onsite soils. In a letter from NCDEQ to OCSWM (dated September 26, 2011), NCDEQ approved the Alternate Source Demonstration. In accordance with the approved. Alternate Source Demonstration, the reported exceedances of total lead may be attributed to the naturally occurring presence of lead in onsite soils.

Groundwater Monitoring Program February 2024 Results of Sampling and Analysis Attachment 6 Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01 Page 3
 Selenium. OCSWM submitted an Alternate Source Demonstration (dated September
2, 2011), showing that total selenium observed in groundwater at the facility could have been derived from onsite soils. In a letter from NCDEQ to OCSWM (dated September 26, 2011), NCDEQ approved the Alternate Source Demonstration. In accordance with
the approved Alternate Source Demonstration, the reported exceedances of total
selenium may be attributed to the naturally occurring presence of selenium in onsite soils. Whereas these Alternate Source Demonstrations were submitted to address particular exceedances at either North or South landfill, we suggest that all Alternate Source Demonstrations noted above are applicable to all waste management units at the facility. Such general applicability is demonstrated by the Alternate Source Demonstrations submitted separately for cobalt at both North and South waste management units. Future Actions. Based upon the results of the subject sampling event, the facility may
continue monitoring groundwater in accordance with the current program.

Groundwater Monitoring Program March, 2024 Results of Sampling and Analysis Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01

Attachment 6: Inorganic Constituents - Graphs
0
50
100
150
200
250
300
350
400
450
500
Total Arsenic Concentration (µg/L)Date
Orange County Solid Waste Management -South Unit
Historic and Current Detections of Total Arsenic
MW-104 MW-105 MW-110D FBAC
Notes: Estimated (J)values are included. Non-detect results were plotted at 0.5 x MDL.
0
50
100
150
200
250
300
350
400
450
500
Total Arsenic Concentration (µg/L)Date
Orange County Solid Waste Management -South Unit
Historic and Current Detections of Total Arsenic
MW-104 MW-105 MW-110D FBAC
Notes: Estimated (J)values are included. Non-detect results were plotted at 0.5 x MDL.

Groundwater Monitoring Program March, 2024 Results of Sampling and Analysis Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01

Attachment 6: Inorganic Constituents - Tables
Constituent Well / Date MW-101 MW-102S MW-102D MW-102DR MW-103D MW-103S MW-104 MW-105 MDL MRL QA/QC
antimony 05/18/95
MCL = 6 07/20/95
FBAC = 1.85 11/28/95
NCGQS = 1 (GWPS)02/28/96
GWPS = 1.4 (pre-Oct. 2010)08/27/96
GWPS = 1 (Oct. 2010)02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
Fbac revised 04-06-04 12/09/03
06/23/04
12/01/04
06/06/05
11/03/05
05/24/06
11/15/06
06/14/07 4.6 JB <1.2 1.5 JB 1.2 JB <1.2 <1.2 <1.2 1.2 6 i
12/11/07 <1.2 <1.2 <1.2 <1.2 <1.2 1.8 JB 1.3 JB 1.2 6 i
06/09/08 2.6 JB <1.2 <1.2 2.8 JB <1.2 <1.2 1.9 JB 1.2 6 i
11/06/08 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 6
05/20/09 <0.68 <0.68 <0.68 <0.68 <0.68 <0.68 <0.68 0.68 6 i
10/20/09 <0.073 <0.073 <0.073 <0.073 <0.073 <0.073 <0.073 0.073 6
06/23/10 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 0.22 6
11/17/10 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 0.22 6
05/25/11 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 0.22 6
11/16/11 0.826 JB <0.22 <0.22 <0.22 0.589 JB <0.22 <0.22 0.22 6 i
06/07/12 0.37 JB 0.239 JB 0.555 JB <0.22 0.312 JB <0.22 <0.22 0.22 6 i
11/14/12 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 0.22 6 i
05/14/13 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 0.22 6 i
11/13/13 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 0.220 6
05/14/14 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 0.220 6
11/12/14 0.329 J <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 0.220 6
05/13/15 <0.220 0.376 J <0.220 <0.220 <0.220 0.280 J <0.220 0.220 6
06/16/15 verification
11/10/15 0.992 J 0.366 J 0.560 J <0.220 <0.220 <0.220 <0.220 0.220 6
05/18/16 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 0.220 6
11/14/16 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 0.220 6
05/31/17 <0.370 <0.370 <0.370 <0.370 <0.370 <0.370 <0.370 0.370 6
11/15/17 <0.370 <0.370 <0.370 <0.370 <0.370 <0.370 <0.370 0.370 6
05/16/18 <1.85 <1.85 <1.85 <1.85 <1.85 <1.85 <1.85 1.850 6
11/13/18 <1.85 <1.85 <1.85 <1.85 <1.85 <1.85 <1.85 1.85 5
05/21/19 <0.740 <0.740 <0.740 <0.740 <0.740 <0.740 <0.740 0.740 2.00
Fbac revised 12-12-19 11/20/19 <0.740 <0.740 <0.740 <0.740 <0.740 <0.740 <0.740 0.740 2.00
05/20/20 <0.740 <0.740 <0.740 <0.740 0.740 2.00
11/18/20 <0.740 <0.740 <0.740 <0.740 0.740 2.00
05/18/21 <0.740 <0.740 <0.740 <0.740 0.740 2.00
11/23/21 <0.740 <0.740 <0.740 <0.740 0.740 2.00
05/23/22 <0.740 <0.740 <0.740 <0.740 0.740 2.00
11/08/22 <0.52 <0.52 <0.52 <0.52 0.52 5.0
05/07/23 <9.0 <9.0 <9.0 <9.0 9.0 20
11/20/23 <5.0 <5.0 <5.0 <5.0 5.0
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
Constituent Well / Date MW-106 MW-107 MW-108 MW-110D MW110S MW-111 MW-112 MDL MRL QA/QC
antimony 05/18/95
MCL = 6 07/20/95
FBAC = 1.85 11/28/95
NCGQS = 1 (GWPS)02/28/96
GWPS = 1.4 (pre-Oct. 2010)08/27/96
GWPS = 1 (Oct. 2010)02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
Fbac revised 04-06-04 12/09/03
06/23/04
12/01/04
06/06/05
11/03/05
05/24/06
11/15/06
06/14/07 <1.2 <1.2 1.8 JB <1.2 <1.2 1.2 6 i
12/11/07 1.8 JB 1.3 JB 1.8 JB <1.2 <1.2 1.2 6 i
06/09/08 2.3 JB 2.5 JB 2.2 JB 1.6 JB <1.2 1.2 6 i
11/06/08 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 6
05/20/09 <0.68 <0.68 <0.68 <0.68 <0.68 0.68 6 i
10/20/09 0.233 J <0.073 <0.073 <0.073 <0.073 0.073 6
06/23/10 <0.22 <0.22 <0.22 <0.22 <0.22 0.22 6
11/17/10 <0.22 <0.22 <0.22 <0.22 <0.22 0.22 6
05/25/11 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 0.22 6
11/16/11 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 0.22 6 i
06/07/12 <0.22 <0.22 0.797 JB 1.18 JB <0.22 <0.22 0.22 6 i
11/14/12 <0.22 <0.22 0.34 J <0.22 <0.22 0.22 6 i
05/14/13 <0.22 <0.22 0.277 J <0.22 <0.22 0.22 6 i
11/13/13 <0.220 <0.220 <0.220 <0.220 <0.220 0.220 6
05/14/14 <0.220 <0.220 <0.220 <0.220 <0.220 0.220 6
11/12/14 <0.220 <0.220 0.609 J <0.220 <0.220 0.220 6
05/13/15 <0.220 <0.220 0.765 J <0.220 <0.220 0.220 6
06/16/15
11/10/15 <0.220 <0.220 <0.220 <0.220 <0.220 0.220 6
05/18/16 <0.220 <0.220 <0.220 <0.220 <0.220 0.220 6
11/14/16 <0.220 <0.220 0.967 J <0.220 <0.220 0.220 6
05/31/17 <0.370 <0.370 <0.370 <0.370 <0.370 0.370 6
11/15/17 <0.370 <0.370 <0.370 <0.370 <0.370 0.370 6
05/16/18 <1.85 <1.85 <1.85 <1.85 <1.85 1.850 6
11/13/18 <1.85 <1.85 <1.85 <1.85 <1.85 1.850 5
05/21/19 <0.740 <0.740 <0.740 <0.740 <0.740 0.740 2.00
Fbac revised 12-12-19 11/20/19 <0.740 <0.740 <0.740 <0.740 <0.740 0.740 2.00
05/20/20 <0.740 <0.740 <0.740 <0.740 0.740 2.00
11/18/20 <0.740 <0.740 <0.740 <0.740 0.740 2.00
05/18/21 <0.740 <0.740 <0.740 <0.740 0.740 2.00
11/29/21 <0.740 <0.740 <0.740 <0.740 0.740 2.00
05/23/22 <0.740 <0.740 <0.740 <0.740 0.740 2.00
11/08/22 0.80 J <0.52 <0.52 <0.52 0.52 5.0
05/07/23 <9.0 <9.0 <9.0 <9.0 9.0 20
11/20/23 <5.0 <5.0 <5.0 <5.0 5.0
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
Constituent Well / Date MW-101 MW-102S MW-102D MW-102DR MW-103D MW-103S MW-104 MW-105 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
arsenic 05/18/95 <10 <10 <10 <10 <10 <10 <10 ms
MCL = 10 07/20/95 <10 <10 <10 <10 <10 <10 <10 i,ms
FBAC = 15.66 (SPL)11/28/95 <10 <10 <10 <10 35 <10 <10
NCGQS = 10 (2L Std)02/28/96 <10 <10 <10 <10 <10 18 <10
2L Std = 50 (pre- Jan. 2010)08/27/96 <10 <10 <10 <10 <10 <10 <10
2L Std = 10 (Jan. 2010)02/27/97 <10 <10 <10 <10 <10 11 <10
09/04/97 <10 <10 <10 <10 <10 19 B <10 i,t
03/25/98 <10 <10 <10 <10 <10 <10 <10
11/02/98 <10 <10 <10 <10 <10 20.4 J <10 i,d
04/27/99 <10 <10 <10 <10 <10 26 J <10 ms
11/22/99 <10 <10 <10 <10 <10 <10 <10
05/24/00 <10 <10 <10 <10 <10 23 J <10 q
11/30/00 <10 <10 <10 <10 <10 <10 <10
05/30/01 <10 <10 <10 <10 <10 188 <10 i, f, t
11/14/01 <10 <10 <10 <10 <10 168 J <10 d
06/06/02 <10 <10 <10 <10 <10 181 J <10 msd
03/13/03 <10 <10 <10 <10 <10 270 <10
06/19/03 <10 <10 <10 <10 <10 42 <10
Fbac revised 04-06-04 12/09/03 <10 <10 <10 <10 <10 169 J <10 d
06/23/04 <10 <10 <10 <10 <10 12 <10
12/01/04 <10 <10 <10 <10 <10 26 <10
06/06/05 <10 <10 <10 <10 <10 86 <10
11/03/05 <10 <10 <10 <10 <10 64 <10
05/24/06 <10 <10 <10 <10 <10 49 <10
Fbac revised 02-28-07 11/15/06 <10 <10 <10 <10 <10 10 <10
06/14/07 <5.5 <5.5 <5.5 <5.5 <5.5 225 8.5 J 5.5 10
12/11/07 <5.5 <5.5 <5.5 <5.5 <5.5 186 8.3 J 5.5 10
06/09/08 <5.5 <5.5 <5.5 <5.5 <5.5 8.8 JB 18.7 B 5.5 10 t, i
11/06/08 <5.5 <5.5 <5.5 <5.5 <5.5 8.4 JB 16.3 B 5.5 10 f
05/20/09 <2.8 <2.8 <2.8 <2.8 4.6 J 5.5 J 53.4 2.8 10
10/20/09 <2.8 <2.8 <2.8 <2.8 5.13 J 5.66 J 39.1 2.8 10
06/23/10 <2.8 <2.8 <2.8 <2.8 6.51 J 8.85 J 54.1 2.8 10
11/17/10 <2.8 <2.8 <2.8 <2.8 <2.8 5.69 J 47.5 2.8 10
05/25/11 <2.8 <2.8 <2.8 <2.8 <2.8 <2.8 107 2.8 10
11/16/11 <2.8 4.37 JB <2.8 <2.8 2.81 JB 5.86 JB 72.2 2.8 10 i
06/07/12 <2.8 <2.8 <2.8 <2.8 <2.8 <2.8 111 2.8 10
11/14/12 3.28 J <2.8 <2.8 <2.8 <2.8 8.67 J 97.6 2.8 10 i
05/14/13 <5.4 <5.4 <5.4 <5.4 <5.4 <5.4 118 5.4 10 i
11/13/13 <5.40 <5.40 <5.40 <5.40 <5.40 <5.40 115 5.40 10
05/14/14 <5.40 <5.40 <5.40 <5.40 <5.40 5.69 J 85.1 5.40 10
11/12/14 <5.40 <5.40 <5.40 <5.40 <5.40 <5.40 92.7 5.40 10
05/13/15 <6.80 <6.80 <6.80 <13.6 <6.80 7.42 J 86.9 6.80/13.6 10
06/16/15 verification
11/10/15 <6.80 <6.80 <6.80 <6.80 <6.80 <6.80 81.7 6.80 10
05/18/16 <6.80 <6.80 <6.80 <6.80 <6.80 8.38 J 81.3 6.80 10
11/14/16 <6.80 <6.80 <6.80 <6.80 <6.80 9.66 J 67.8 6.80 10
05/31/17 <6.80 <6.80 <6.80 <6.80 <6.80 7.33 J 62.6 6.80 10
11/15/17 <6.80 <6.80 <6.80 <6.80 <6.80 <6.80 63.0 6.80 10
05/16/18 <6.80 <6.80 <6.80 <6.80 <6.80 <6.80 44.2 6.80 10
11/13/18 <7.60 <7.60 <7.60 <7.60 <7.60 <7.60 43.1 7.60 10
05/21/19 <7.60 <7.60 <7.60 <7.60 <7.60 28.5 42.0 7.60 10
FBAC Revised 12-12-2019 11/20/19 <7.60 <7.60 <7.60 <7.60 <7.60 <7.60 46.5 7.60 10
05/20/20 <7.60 <7.60 14.9 34.6 7.60 10
11/18/20 <7.60 <7.60 <7.60 <7.60 7.60 10
05/18/21 <7.60 <7.60 9.90 J 24.9 7.60 10
11/23/21 <7.60 <7.60 <7.60 28.5 7.60 10
05/23/22 <7.60 <7.60 <7.60 30.5 7.60 10
11/08/22 <6.4 <6.4 11 J 31.0 6.40 20
05/07/23 <6.4 <6.4 20 26 6.40 20
11/20/23 <10.0 <10.0 <10.0 33.0 10.0
Constituent Well / Date MW-106 MW-107 MW-108 MW-110D MW110S MW-111 MW-112 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
arsenic 05/18/95 13 J <10 <10 25 J <10 <10 ms
MCL = 10 07/20/95 <10/11 B <10 <10 27 J <10 <10 i,ms
FBAC = 15.66 (SPL)11/28/95 45 <10 14 176 <10 <10
NCGQS = 10 (2L Std)02/28/96 <10 <10 <10 14 <10 <10
2L Std = 50 (pre- Jan. 2010)08/27/96 14 <10 <10 20 <10 <10
2L Std = 10 (Jan. 2010)02/27/97 <10 <10 <10 <10 <10 <10
09/04/97 22 B <10 <10 12 B <10 <10 i,t
03/25/98 18 <10 <10 11 <10 <10
11/02/98 30 J <10 <10 <10 <10 i,d
04/27/99 <10 <10 <10 <10 <10 <10 ms
11/22/99 <10 <10 <10 <10 <10 <10
05/24/00 <10 <10 <10 10 J <10 <10 q
11/30/00 <10 <10 <10 <10 <10 <10
05/30/01 <10 <10 <10 324 <10 <10 i, f, t
11/14/01 <10 <10 <10 447 J <10 <10 d
06/06/02 <10 <10 <10 342 J <10 <10 msd
03/13/03 <10 <10 <10 <10
06/19/03 <10 12 312 <10 <10
Fbac revised 04-06-04 12/09/03 <10 <10 149 J <10 <10 d
06/23/04 <10 11 <10 <10 <10
12/01/04 <10 <10 <10 <10 <10
06/06/05 <10 <10 157 <10 <10
11/03/05 <10 <10 <10 <10 <10
05/24/06 <10 12 120 <10 <10
Fbac revised 02-28-07 11/15/06 <10 <10 137 <10 <10
06/14/07 <5.5 <5.5 260 <5.5 <5.5 5.5 10
12/11/07 <5.5 <5.5 48.7 <5.5 <5.5 5.5 10
06/09/08 <5.5 <5.5 42 B <5.5 <5.5 5.5 10 t, i
11/06/08 <5.5 <5.5 87.9 B <5.5 <5.5 5.5 10 f
05/20/09 2.8 J <2.8 11.9 <2.8 <2.8 2.8 10
10/20/09 4.06 J 4.12 J 3.18 J 3.69 J 16.5 2.8 10
06/23/10 6.13 J 4.39 J 13.1 <2.8 <2.8 2.8 10
11/17/10 <2.8 4.08 J 15.9 <2.8 <2.8 2.8 10
05/25/11 <2.8 3.39 J 31.6 <2.8 <2.8 10.5 2.8 10
11/16/11 3.29 JB 6.01 JB <2.8 13.4B <2.8 10.7B 2.8 10 i
06/07/12 <2.8 3.05 J 15.2 <2.8 3.93 J 14.9 2.8 10
11/14/12 5.07 J 5.43 J 16 B 3.42 JB 3.29 J 15.8 2.8 10 i
05/14/13 <5.4 <5.4 8.92 J <5.4 <5.4 14.6 5.4 10 i
11/13/13 <5.40 <5.40 13.6 <5.40 <5.40 <5.40 5.40 10
05/14/14 <5.40 <5.40 12.6 <5.40 <5.40 <5.40 5.40 10
11/12/14 <5.40 <5.40 <5.40 <5.40 <5.40 <5.40 5.40 10
05/13/15 <6.80 195 11.5 <6.80 <6.80 <6.80 6.80/13.6 10
06/16/15
11/10/15 <6.80 <6.80 7.92 J <6.80 <6.80 <6.80 6.80 10
05/18/16 <6.80 <6.80 10.2 <6.80 <6.80 <6.80 6.80 10
11/14/16 <6.80 <6.80 <6.80 <6.80 <6.80 16.1 6.80 10
05/31/17 <6.80 <6.80 8.84 J <6.80 <6.80 <6.80 6.80 10
11/15/17 <6.80 <6.80 9.02 J <6.80 <6.80 <6.80 6.80 10
05/16/18 <6.80 <6.80 10.1 <6.80 <6.80 <6.80 6.80 10
11/13/18 <7.60 <7.60 <7.60 <7.60 <7.60 <7.60 7.60 10
05/21/19 <7.60 <7.60 <7.60 <7.60 <7.60 <7.60 7.60 10
FBAC Revised 12-12-2019 11/20/19 <7.60 <7.60 <7.60 <7.60 <7.60 <7.60 7.60 10
05/20/20 <7.60 <7.60 8.42 J <7.60 <7.60 7.60 10
11/18/20 <7.60 <7.60 <7.60 <7.60 <7.60 7.60 10.0
05/18/21 <7.60 <7.60 <7.60 <7.60 <7.60 7.60 10.0
11/29/21 <7.60 <7.60 9.87 J <7.60 <7.60 7.60 10.0
05/23/22 <7.60 <7.60 <7.60 <7.60 <7.60 7.60 10.0
11/08/22 <6.4 <6.4 <6.4 <6.4 <6.4 6.4 20
05/07/23 <6.4 <6.4 8.8 J <6.4 <6.4 6.4 20
11/20/23 <10.0 <10.0 14.0 <10.0 <10.0 10.0
Constituent Well / Date MW-101 MW-102S MW-102D MW-102DR MW-103D MW-103S MW-104 MW-105 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
barium 05/18/95 <500 <500 <500 <500 <500 <500 <500
MCL = 2000 07/20/95 <500 <500 <500 <500 <500 <500 <500
FBAC = 81.94 (SPL)11/28/95 <500 <500 <500 <500 <500 <500 <500
NCGQS = 700 (2L Std)02/28/96 <500 <500 <500 <500 <500 <500 <500 i,t,f
2L Std = 2000 (pre- Jan. 2010)08/27/96 <500 <500 <500 <500 <500 <500 <500
2L Std = 700 (Jan. 2010)02/27/97 <500 <500 <500 <500 <500 <500 <500 i,t
09/04/97 <500 <500 <500 <500 <500 <500 <500 i,f
03/25/98 <500 <500 <500 <500 <500 <500 <500
11/02/98 <500 <500 <500 <500 <500 <500 <500 ics
04/27/99 <500 <500 <500 <500 <500 <500 <500
11/22/99 <500 <500 <500 <500 <500 <500 <500
05/24/00 <500 <500 <500 <500 <500 <500 <500
11/30/00 <500 <500 <500 <500 <500 <500 <500
05/30/01 <500 <500 <500 <500 <500 <500 <500 i, f, t
11/14/01 <500 <500 <500 <500 <500 <500 <500
06/06/02 <500 <500 <500 <500 <500 <500 <500
03/13/03 <500 <500 <500 <500 <500 <500 <500
06/19/03 <500 <500 <500 <500 <500 <500 <500
12/09/03 <500 <500 <500 <500 <500 <500 <500
06/23/04 <500 <500 <500 <500 <500 <500 <500
12/01/04 <500 <500 <500 <500 <500 <500 <500
06/06/05 <500 <500 <500 <500 <500 <500 <500
11/03/05 <500 <500 <500 <500 <500 <500 <500
05/24/06 <500 <500 <500 <500 <500 <500 <500
11/15/06 <500 <500 <500 <500 <500 <500 <500 f
06/14/07 16.1 JB 67.7 J 11.9 JB 22 JB 19.6 JB 19.6 JB 10.7 JB 1.1 100 t, f
12/11/07 9.2 J 29.4 J 3.2 JB 5.1 JB 2.9 JB 19.5 J 4.8 JB 1.1 100 i
06/09/08 16.1 JB 30.0 JB 5.5 JB 4.1 JB 3.6 JB 2.9 JB 7.0 JB 1.1 100 t, f
11/06/08 18.7 JB 30.9 JB 4.1 JB 2.8 JB 3.3 JB 2.9 JB 5.7 JB 1.1 100 t, f, i
05/20/09 43.9 J 37.8 J 5.48 J <4.2 6.81 J <4.2 6.83 J 4.2 100
10/20/09 49.9 J 33.4 J 3.6 J 2.53 J 3.37 J <1 6.99 J 1 100
06/23/10 15.6 J 31.3 J 2.22 J 3.07 J 7.35 J <1 5.14 J 1 100
11/17/10 11.8 J 29.0 J 1.57 J 3.27 J 3.04 J 1.27 J 6.51 J 1 100
05/25/11 20.4 J 33.1 J 1.88 J 3.19 J 2.79 J <1 8.69 J 1 100
11/16/11 16.7 J 30.3 J 1.85 J 3.03 J 1.81 J <1 7.7 J 1 100
06/07/12 17.9 J 35.4 J <1 2.56 J 1.29 J <1 9.31 J 1 100
11/14/12 44.3 J 32.6 J 1.58 J 3.19 J 1.71 J <1 9.61 J 1 100
05/14/13 14.9 J 33.4 J <1 2.87 J 6.8 J <1 7.46 J 1 100 i
11/13/13 15.8 J 38.3 J 1.98 J 3.73 J 1.77 J <1.00 7.99 J 1.00 100
05/14/14 17.5 J 36.5 J 2.08 J 4.04 J 2.59 J 1.22 J 7.16 J 1.00 100
11/12/14 45.6 J 38.7 J 2.01 J 3.54 J 3.10 J 1.11 J 8.59 J 1.00 100
05/13/15 17.1 J 33.3 J 1.08 J 6.06 J 1.56 J 1.07 J 6.81 J 1.00 100
06/16/15 verification
11/10/15 14.5 J 29.5 J 1.07 J 3.14 J 1.42 J <1.00 6.53 J 1.00 100
05/18/16 17.2 J 37.4 J <1.00 2.71 J 1.50 J 1.09 J 6.19 J 1.00 100
11/14/16 19.0 J 34.4 J 1.28 J 3.03 J 1.47 J 1.29 J 6.43 J 1.00 100
05/31/17 17.2 J 34.4 J <1.00 3.08 J 1.41 J 1.06 J 5.11 J 1.00 100
11/15/17 24.4 J 33.3 J 1.44 J 2.53 J 1.37 J 1.00 J 6.26 J 1.00 100
05/16/18 13.9 J 46.5 J 1.32 J 3.14 J 1.67 J 1.40 J 5.17 J 1.00 100
11/13/18 16.5 38.9 1.77 J 3.48 J 2.18 J 1.46 J 4.74 J 1.10 10
05/21/19 18.0 30.6 1.73 J 3.14 J 2.03 J 2.36 J 5.18 J 1.10 10
11/20/19 16.1 27.1 1.14 J 2.72 J 1.46 J 1.62 J 4.56 J 1.10 10
05/20/20 13.7 22.4 1.21 J 3.40 J 1.10 10
11/18/20 15.8 25.2 <1.10 <1.10 1.10 10
05/18/21 17.6 22.7 1.85 J 4.24 J 1.10 10
11/23/21 48.3 20.5 1.80 J 4.43 J 1.10 10
05/23/22 16.5 21.9 1.31 J 4.50 J 1.10 10
11/08/22 37.0 21.0 <4.40 4.90 J 4.40 10
05/07/23 18 22 <4.40 5.5 J 4.40 10
11/20/23 15.5 23.5 <5.0 5.8 5.0
Constituent Well / Date MW-106 MW-107 MW-108 MW-110D MW110S MW-111 MW-112 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
barium 05/18/95 <500 <500 <500 <500 <500 <500
MCL = 2000 07/20/95 <500 <500 <500 <500 <500 <500
FBAC = 81.94 (SPL)11/28/95 <500 <500 <500 512 <500 <500
NCGQS = 700 (2L Std)02/28/96 <500 <500 <500 <500 <500 <500 i,t,f
2L Std = 2000 (pre- Jan. 2010)08/27/96 <500 <500 <500 <500 <500 <500
2L Std = 700 (Jan. 2010)02/27/97 <500 <500 <500 <500 <500 <500 i,t
09/04/97 <500 <500 <500 <500 <500 <500 i,f
03/25/98 <500 <500 <500 <500 <500 <500
11/02/98 <500 <500 <500 <500 <500 ics
04/27/99 <500 <500 <500 <500 <500 <500
11/22/99 <500 <500 <500 <500 <500 <500
05/24/00 <500 <500 <500 <500 <500 <500
11/30/00 <500 <500 <500 <500 <500 <500
05/30/01 <500 <500 <500 <500 <500 <500 i, f, t
11/14/01 <500 <500 <500 <500 <500 <500
06/06/02 <500 <500 <500 <500 <500 <500
03/13/03 <500 <500 <500 <500
06/19/03 <500 <500 <500 <500
12/09/03 <500 <500 <500 <500
06/24/04 <500 <500 <500 <500
12/01/04 <500 <500 <500 <500
06/06/05 <500 <500 <500 <500 <500
11/03/05 <500 <500 <500 <500 <500
05/24/06 <500 <500 <500 <500 <500
11/15/06 <500 <500 <500 <500 <500 f
06/14/07 21.5 JB 6.1 JB 53.8 J 6.1 JB 4.9 JB 1.1 100 t, f
12/11/07 13.4 J 6.3 JB 14.5 J 25.1 J 2.4 JB 1.1 100 i
06/09/08 16.6 JB 23.5 JB 11.4 JB 4.8 JB 8.5 JB 1.1 100 t, f
11/06/08 11 JB 6.5 JB 22.3 JB 5.5 JB 3.0 JB 1.1 100 t, f, i
05/20/09 19.1 J 12.1 J 5.19 J <4.2 <4.2 4.2 100
10/20/09 17.6 J 8.33 J 6.96 J 2.74 J 16.2 J 1.0 100
06/23/10 14.5 J 11.5 J 4.01 J 5.93 J 2.27 J 1.0 100
11/17/10 13.4 J 7.76 J 4.79 J 3.99 J 1.85 J 1.0 100
05/25/11 13.8 J 9.46 J 9.97 J 3.88 J 3.45 J 16.4 J 1.0 100
11/16/11 14.3 J 8.13 J 3.91 J 4.59 J 5.35 J 16.1 J 1.0 100
06/07/12 13.1 J 9.05 J 4.51 J 3.29 J 2.65 J 17.4 J 1.0 100
11/14/12 11.4 J 7.18 J 3.96 J 2.27 J 16.1 J 1.0 100
05/14/13 11.8 J 6.91 J 4.16 J 2.35 J 19.1 J 1.0 100 i
11/13/13 9.26 J 6.35 J 4.45 J 2.12 J 16.4 J 1.00 100
05/14/14 9.51 J 7.17 J 4.30 J 8.62 J 16.0 J 1.00 100
11/12/14 11.5 J 6.40 J 4.58 J 3.41 J 16.0 J 1.00 100
05/13/15 3.85 J 216 4.95 J 4.54 J 13.7 J 1.00 100
06/16/15
11/10/15 10.2 J 6.39 J 3.55 J 3.39J 12.0 J 1.00 100
05/18/16 8.74 J 5.37 J 4.33 J 4.93 J 11.7 J 1.00 100
11/14/16 19.6 J 11.6 J 4.83 J 61.1 J 12.5 J 1.00 100
05/31/17 9.52 J 5.54 J 4.20 J 6.76 J 11.6 J 1.00 100
11/15/17 11.1 J 5.50 J 5.55 J 2.92 J 10.5 J 1.00 100
05/16/18 10.7 J 6.94 J 4.17 J 3.30 J 10.1 J 1.00 100
11/13/18 15.0 6.81 J 4.10 J 6.66 J 9.37 J 1.10 10
05/21/19 10.6 7.15 J 6.34 J 6.08 J 9.11 J 1.10 10
11/20/19 11.5 10.7 4.40 J 2.85 J 9.65 J 1.10 10
05/20/20 11.7 7.97 J 3.72 J 2.12 J 1.10 10
11/18/20 14.1 9.82 J 4.23 J 2.88 J 1.10 10
05/18/21 10.1 6.48 J 5.08 J 3.25 J 1.10 10
11/29/21 11.3 6.03 J 5.15 J 2.62 J 1.10 10
05/23/22 11.0 8.0 J 4.42 J 3.43 J 1.10 10
11/08/22 11.0 6.5 J <4.40 <4.40 4.40 10
05/07/23 10 7.2 J <4.40 <4.40 4.40 10
11/20/23 13.8 7.0 <5.0 <5.0 5.0
Constituent Well / Date MW-101 MW-102S MW-102D MW-102DR MW-103D MW-103S MW-104 MW-105 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
beryllium 05/18/95 12 <2 <2 <2 <2 <2 <2
MCL = 4 07/20/95 <2 <2 <2 <2 <2 <2 <2
FBAC = 0.571 (SPL)11/28/95 3 <2 <2 <2 29 <2 <2
NCGQS = 4 (GWPS)02/28/96 <2 <2 <2 <2 32 J <2 <2 sd
08/27/96 <2 <2 <2 <2 2 <2 2
02/27/97 <2 <2 <2 <2 <2 <2 <2
09/04/97 <2 <2 <2 <2 <2 <2 <2
03/25/98 <2 <2 <2 <2 6 B <2 <2 i
11/02/98 <2 <2 <2 <2 <2 <2 <2 i
04/27/99 <2 <2 <2 <2 <2 <2 <2 i,f
11/22/99 <2 <2 <2 <2 <2 <2 <2
05/24/00 <2 <2 <2 <2 <2 <2 <2
11/30/00 <2 <2 <2 <2 <2 <2 <2
05/30/01 <2 <2 <2 <2 <2 <2 <2 i, f, t
11/14/01 <2 <2 <2 <2 <2 <2 <2
06/06/02 <2 <2 <2 <2 <2 <2 <2
03/13/03 <2 <2 <2 <2 <2 <2 <2
06/19/03 <2 <2 <2 <2 <2 <2 <2
12/09/03 <2 <2 <2 <2 <2 <2 <2
06/23/04 <2 <2 <2 <2 <2 <2 <2
12/01/04 <2 <2 <2 <2 <2 <2 <2
06/06/05 <2 <2 <2 <2 <2 <2 <2
11/03/05 <2 <2 <2 <2 <2 <2 <2
05/24/06 <2 <2 <2 <2 <2 <2 <2
11/15/06 <2 <2 <2 <2 <2 <2 <2
06/14/07 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 1.0
12/11/07 <0.2 <0.2 <0.2 <0.2 <0.2 0.3 JB <0.2 0.2 1.0 i
06/09/08 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 1.0
11/06/08 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 1.0
05/20/09 0.15 J <0.08 <0.08 <0.08 0.13 J <0.08 <0.08 0.08 1.0
10/20/09 0.13 J <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0
06/23/10 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0
11/17/10 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0
05/25/11 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0
11/16/11 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0
06/07/12 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0
11/14/12 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0
05/14/13 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0
11/13/13 <0.100 <0.100 <0.100 <0.100 <0.100 <0.100 <0.100 0.100 1.0
05/14/14 <0.100 <0.100 <0.100 <0.100 <0.100 <0.100 <0.100 0.100 1.0
11/12/14 <0.100 <0.100 <0.100 <0.100 <0.100 <0.100 <0.100 0.100 1.0
05/13/15 <0.100 <0.100 <0.100 <0.200 <0.100 <0.100 <0.100 0.100/0.200 1.0
06/16/15 verification
11/10/15 <0.100 <0.100 <0.100 <0.100 <0.100 <0.100 <0.100 0.100 1.0
05/18/16 <0.100 <0.100 <0.100 <0.100 <0.100 <0.100 <0.100 0.100 1.0
11/14/16 <0.100 <0.100 <0.100 <0.100 <0.100 <0.100 <0.100 0.100 1.0
05/31/17 <0.130 <0.130 <0.130 <0.130 <0.130 <0.130 <0.130 0.130 1.0
11/15/17 <0.130 <0.130 <0.130 <0.130 <0.130 <0.130 <0.130 0.130 1.0
05/16/18 <0.130 <0.130 <0.130 <0.130 <0.130 <0.130 <0.130 0.130 1.0
11/13/18 <0.160 <0.160 0.167 J 0.205 J <0.160 0.285 J <0.160 0.160 1.0
05/21/19 <0.160 <0.160 <0.160 <0.160 <0.160 <0.160 <0.160 0.160 1.0
11/20/19 <0.160 <0.160 <0.160 <0.160 <0.160 <0.160 <0.160 0.160 1.0
05/20/20 <0.160 <0.160 <0.160 <0.160 0.16 1.0
11/18/20 <0.160 <0.160 <0.160 <0.160 0.16 1.0
05/18/21 <0.160 <0.160 <0.160 <0.160 0.16 1.0
11/23/21 <0.160 <0.160 <0.160 <0.160 0.16 1.0
05/23/22 <0.160 <0.160 <0.160 <0.160 0.16 1.0
11/08/22 <0.30 <0.30 <0.30 <0.30 0.30 4.0
05/07/23 <0.30 <0.30 <0.30 <0.30 0.30 4.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
Constituent Well / Date MW-106 MW-107 MW-108 MW-110D MW110S MW-111 MW-112 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
beryllium 05/18/95 2 <2 2 2 2 6
MCL = 4 07/20/95 <2/<2 <2 <2 3 <2 <2
FBAC = 0.571 (SPL)11/28/95 5 <2 5 37 <2 <2
NCGQS = 4 (GWPS)02/28/96 3.3 <2 <2 2.6 <2 <2 sd
08/27/96 5 2 <2 2 <2 <2
02/27/97 <2 <2 <2 <2 <2 <2
09/04/97 <2 <2 <2 <2 <2 <2
03/25/98 <2 <2 <2 <2 <2 <2 i
11/02/98 <2 <2 <2 <2 <2 i
04/27/99 <2 <2 <2 <2 <2 <2 i,f
11/22/99 <2 <2 <2 <2 <2 <2
05/24/00 <2 <2 <2 <2 <2 <2
11/30/00 <2 <2 <2 <2 <2 <2
05/30/01 <2 <2 <2 <2 <2 <2
11/14/01 <2 <2 <2 <2 <2 <2
06/06/02 <2 <2 <2 <2 <2 <2
03/13/03 <2 <2 <2 <2
06/19/03 <2 <2 <2 <2
12/09/03 <2 <2 <2 <2
06/23/04 <2 <2 <2 <2
12/01/04 <2 <2 <2 <2
06/06/05 <2 <2 <2 <2 <2
11/03/05 <2 <2 <2 <2 <2
05/24/06 <2 <2 <2 <2 <2
11/15/06 <2 <2 <2 <2 <2
06/14/07 <0.2 <0.2 0.4 J <0.2 <0.2 0.2 1.0
12/11/07 <0.2 <0.2 <0.2 <0.2 0.2 JB 0.2 1.0 i
06/09/08 0.2 J 0.3 J 0.6 J <0.2 <0.2 0.2 1.0
11/06/08 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 1.0
05/20/09 0.11 J <0.08 0.12 J <0.08 <0.08 0.08 1.0
10/20/09 <0.1 <0.1 0.58 J <0.1 0.485 J 0.1 1.0
06/23/10 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0
11/17/10 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0
05/25/11 <0.1 <0.1 0.106 J <0.1 <0.1 <0.1 0.1 1.0
11/16/11 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0
06/07/12 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0
11/14/12 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0
05/14/13 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1.0
11/13/13 <0.100 <0.100 <0.100 <0.100 <0.100 0.100 1.0
05/14/14 <0.100 <0.100 <0.100 <0.100 <0.100 0.100 1.0
11/12/14 <0.100 <0.100 <0.100 <0.100 <0.100 0.100 1.0
05/13/15 <0.100 20.5 R <0.100 <0.100 <0.100 0.100/0.200 1.0
06/16/15 <0.100 0.100 1.0 verification
11/10/15 <0.100 <0.100 <0.100 <0.100 <0.100 0.100 1.0
05/18/16 <0.100 <0.100 <0.100 <0.100 <0.100 0.100 1.0
11/14/16 <0.100 <0.100 <0.100 <0.100 <0.100 0.100 1.0
05/31/17 <0.130 <0.130 <0.130 <0.130 <0.130 0.130 1.0
11/15/17 <0.130 <0.130 <0.130 <0.130 <0.130 0.130 1.0
05/16/18 <0.130 <0.130 <0.130 <0.130 <0.130 0.130 1.0
11/13/18 0.391 J 0.182 J <0.160 <0.160 0.231 J 0.160 1.0
05/21/19 <0.160 <0.160 <0.160 <0.160 <0.160 0.160 1.0
11/20/19 <0.160 <0.160 <0.160 <0.160 <0.160 0.160 1.0
05/20/20 0.177 J 0.186 J <0.160 <0.160 0.160 1.0
11/18/20 <0.160 <0.160 <0.160 <0.160 0.160 1.0
05/18/21 <0.160 <0.160 <0.160 <0.160 0.160 1.0
11/29/21 <0.160 <0.160 <0.160 <0.160 0.160 1.0
05/23/22 <0.160 <0.160 <0.160 <0.160 0.160 1.0
11/08/22 <0.30 <0.30 <0.30 <0.30 0.30 4.0
05/07/23 <0.30 <0.30 <0.30 <0.30 0.30 4.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
Constituent Well / Date MW-101 MW-102S MW-102D MW-102DR MW-103D MW-103S MW-104 MW-105 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
cadmium 05/18/95 <1 <1 <1 <1 <1 <1 <1 i,t,d,ms
MCL = 5 07/20/95 <1 1.2 B <1 <1 <1 1.2 B <1 i
FBAC = 0.458 11/28/95 <1 1.1 B <1 <1 1.5 B <1 <1 i,ms
NCGQS = 2 (2L Std)02/28/96 <1 <1 <1 <1 <1 <1 <1
2L Std = 1.75 (pre- Jan. 2010)08/27/96 <1 1.1 B <1 <1 <1 <1 <1 f,ms
2L Std = 2 (Jan. 2010)02/27/97 <1 1.6 B <1 <1 1.5 B <1 <1 t
09/04/97 <1 1.3 <1 <1 <1 <1 <1 i
03/25/98 <1 <1 <1 <1 <1 <1 <1 i
11/02/98 <1 <1 <1 1.3 B <1 <1 <1 d,t,f
04/27/99 <1 1.6 J <1 <1 <1 <1 <1 cc,i
11/22/99 <1 <1 <1 <1 <1 <1 <1
05/24/00 <1 <1 <1 2 B <1 <1 1 B cc,t,f,q
11/30/00 <1 <1 <1 <1 <1 <1 <1 i, f, t
05/30/01 <1 <1 <1 <1 <1 4 3 i, f, t
11/14/01 <1 <1 <1 <1 <1 <1 <1 f
06/06/02 <1 <1 <1 <1 <1 <1 <1 f
03/13/03 <1 <1 <1 <1 <1 <1 <1
06/19/03 <1 2 <1 <1 1 <1 <1
12/09/03 2 B <1 <1 <1 <1 <1 <1 t
06/23/04 <1 <1 <1 <1 <1 <1 <1
12/01/04 <1 <1 <1 <1 <1 <1 <1
06/06/05 <1 <1 <1 <1 <1 <1 <1
11/03/05 <1 <1 <1 <1 <1 <1 <1
05/24/06 <1 <1 <1 <1 <1 <1 <1
11/15/06 <1 <1 <1 <1 <1 <1 <1
06/14/07 <0.2 <0.2 <0.2 <0.2 <0.2 4 0.2 J 0.2 1
12/11/07 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 1 i
06/09/08 0.3 JB 0.3 JB 0.4 JB 0.3 JB 0.3 JB <0.2 0.2 JB 0.2 1 f
11/06/08 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 JB 0.2 JB 0.2 1 f, i
05/20/09 0.29 J 0.18 J 0.16 J 0.11 J <0.09 0.20 J 0.13 J 0.09 1
10/20/09 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1
06/23/10 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1
11/17/10 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1
05/25/11 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1
11/16/11 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1
06/07/12 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1
11/14/12 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1
05/14/13 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1
11/13/13 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1
05/14/14 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1
11/12/14 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1
05/13/15 <0.360 <0.360 <0.360 <0.720 <0.360 <0.360 <0.360 0.360/0.720 1
06/16/15 verification
11/10/15 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0
05/18/16 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0
11/14/16 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0
05/31/17 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0
11/15/17 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0
05/16/18 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0
11/13/18 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0
05/21/19 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0
11/20/19 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0 i
05/20/20 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0
11/18/20 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0
05/18/21 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0
11/23/21 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0
05/23/22 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0
11/08/22 <0.44 <0.44 <0.44 <0.44 <0.44 <0.44 <0.44 0.44 5.0
05/07/23 <0.44 <0.44 <0.44 <0.44 <0.44 <0.44 <0.44 0.44 5.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
Constituent Well / Date MW-106 MW-107 MW-108 MW-110D MW110S MW-111 MW-112 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
cadmium 05/18/95 <1 3 B <1 1.7 B <1 3 B i,t,d,ms
MCL = 5 07/20/95 <1/<1 <1 <1 <1 <1 <1 i
FBAC = 0.458 11/28/95 <1 <1 <1 6.1 J <1 <1 i,ms
NCGQS = 2 (2L Std)02/28/96 <1 <1 <1 <1 <1 <1
2L Std = 1.75 (pre- Jan. 2010)08/27/96 4.5 J <1 1.3 B <1 <1 2.2 B f,ms
2L Std = 2 (Jan. 2010)02/27/97 <1 <1 <1 <1 <1 <1 t
09/04/97 <1 <1 <1 <1 <1 1.7 i
03/25/98 <1 <1 <1 <1 <1 <1 i
11/02/98 <1 <1 <1 <1 <1 d,t,f
04/27/99 <1 <1 <1 <1 <1 <1 cc,i
11/22/99 <1 <1 <1 <1 <1 <1
05/24/00 <1 <1 <1 <1 4 J <1 cc,t,f,q
11/30/00 <1 <1 <1 1.2 B <1 <1 i, f, t
05/30/01 <1 3 <1 2 <1 <1 i, f, t
11/14/01 <1 <1 <1 <1 <1 <1 f
06/06/02 <1 <1 <1 <1 <1 <1 f
03/13/03 <1 <1 <1 <1
06/19/03 <1 <1 <1 <1
12/09/03 <1 <1 <1 <1 t
06/23/04 <1 <1 <1 <1
12/01/04 <1 <1 <1 <1
06/06/05 <1 <1 <1 <1 <1
11/03/05 <1 <1 <1 <1 <1
05/24/06 <1 <1 <1 <1 <1
11/15/06 <1 <1 <1 <1 <1
06/14/07 <0.2 <0.2 3.1 <0.2 <0.2 0.2 1.0
12/11/07 <0.2 <0.2 <0.2 <0.2 0.3 JB 0.2 1.0 i
06/09/08 0.6 JB 0.5 JB 0.4 JB 0.4 JB 0.3 JB 0.2 1.0 f
11/06/08 <0.2 <0.2 <0.2 0.2 JB 0.4 JB 0.2 1.0 f, i
05/20/09 0.11 J 0.33 J 0.15 J 0.23 J 0.11 J 0.09 1.0
10/20/09 <0.36 <0.36 0.675 J <0.36 <0.36 0.36 1.0
06/23/10 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1.0
11/17/10 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1.0
05/25/11 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1.0
11/16/11 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1.0
06/07/12 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1.0
11/14/12 <0.36 <0.36 0.43 J <0.36 <0.36 0.36 1.0
05/14/13 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1.0
11/13/13 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0
05/14/14 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0
11/12/14 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0
05/13/15 <0.360 21.0 R <0.360 <0.360 <0.360 0.360/0.720 1.0
06/16/15 <0.360 0.360 1.0 verification
11/10/15 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0
05/18/16 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0
11/14/16 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0
05/31/17 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0
11/15/17 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0
05/16/18 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0
11/13/18 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0
05/21/19 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1.0
11/20/19 <0.360 0.380 JB <0.360 <0.360 <0.360 0.360 1.0 i
05/20/20 <0.360 <0.360 <0.360 <0.360 0.360 1.0
11/18/20 <0.360 <0.360 <0.360 <0.360 0.360 1.0
05/18/21 <0.360 <0.360 <0.360 <0.360 0.360 1.0
11/29/21 <0.360 <0.360 <0.360 <0.360 0.360 1.0
05/23/22 <0.360 <0.360 <0.360 <0.360 0.360 1.0
11/08/22 <0.44 <0.44 <0.44 <0.44 0.44 5.0
05/07/23 <0.44 <0.44 <0.44 <0.44 0.44 5.0
11/20/23 <1.0 <1.0 <1.0 <1.0 1.0
Constituent Well / Date MW-101 MW-102S MW-102D MW-102DR MW-103D MW-103S MW-104 MW-105 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
chromium 02/27/97 31 <10 <10 <10 22 B <10 <10 i,t,f
FBAC = 3.228 08/27/96 33 <10 <10 <10 12 B <10 25 f
MCL = 100 05/18/95 356 J 28 J 11 B <10 <10 <10 <10 i,t,d,ms
NCGQS = 10 (2L Std)11/28/95 64 <10 <10 <10 167 <10 <10
2L Std = 10 (Jan. 2010)07/20/95 64 J <10 <10 <10 <10 <10 <10 f,ms
2L Std = 50 (pre- Jan. 2010)02/28/96 24 J <10 <10 <10 81 J <10 <10 t,f,ms
09/04/97 16 <10 <10 <10 15 <10 <10 f
03/25/98 24 <10 <10 <10 48 <10 <10 i
11/02/98 <10 <10 <10 <10 <10 <10 <10
04/27/99 <10 <10 <10 <10 40 J <10 <10 cc
11/22/99 <10 <10 <10 <10 <10 <10 <10
05/24/00 <10 <10 <10 <10 <10 <10 <10
11/30/00 <10 <10 <10 <10 <10 <10 <10
05/30/01 <10 <10 <10 <10 <10 <10 <10 i, f, t
11/14/01 <10 <10 <10 <10 <10 <10 <10 i
06/06/02 <10 <10 <10 <10 <10 <10 <10 i
03/13/03 <10 <10 <10 <10 <10 <10 <10
06/19/03 <10 <10 <10 <10 <10 <10 <10
12/09/03 <10 <10 <10 <10 <10 <10 <10
06/23/04 <10 <10 <10 <10 <10 <10 <10
12/01/04 <10 <10 <10 <10 <10 <10 <10
06/06/05 <10 <10 <10 <10 <10 <10 <10
11/03/05 <10 <10 <10 <10 <10 <10 <10
05/24/06 <10 <10 <10 <10 <10 <10 <10
11/15/06 <10 <10 <10 <10 <10 <10 <10
06/14/07 9.6 JB 2.1 JB 2.6 JB <0.7 <0.7 <0.7 3 JB 0.7 10 t, f, cc
12/11/07 1.4 JB 1 JB 1.1 JB <0.7 3.4 JB <0.7 1.5 JB 0.7 10 i
06/09/08 4.8 J 0.9 JB 1.8 JB 0.8 JB 1.4 JB <0.7 1.9 JB 0.7 10 f
11/06/08 12.4 B <0.7 6.8 JB <0.7 <0.7 <0.7 1.5 JB 0.7 10 t, f, i
05/20/09 9.3 J <0.7 2.3 J <0.7 5.6 J <0.7 2.5 J 0.7 10
10/20/09 46.9 <1 <1 <1 1.58 J <1 2.32 J 1 10
06/23/10 1.02 J <1 <1 <1 3.22 J <1 <1 1 10
11/17/10 2.25 J <1 <1 <1 <1 <1 <1 1 10
05/25/11 4.7 J <1 <1 <1 1.43 J <1 4.05 J 1 10
11/16/11 3.69 J <1 <1 <1 <1 <1 2.16 J 1 10
06/07/12 7.45 J <1 <1 <1 <1 <1 4.46 J 1 10
11/14/12 8.23 J <1 <1 <1 <1 <1 1.97 J 1 10
05/14/13 <1.4 <1.4 <1.4 <1.4 5.67 J <1.4 <1.4 1.4 10 i
11/13/13 1.55 J <1.40 <1.40 <1.40 <1.40 <1.40 2.64 J 1.40 10
05/14/14 1.82 J <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 10
11/12/14 12.5 <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 10
05/13/15 7.63 JB 3.41 J 2.29 JB 6.38 J 3.47 J 3.16 J 2.99 J 1.40 10
06/16/15 verification
11/10/15 <1.40 1.91 J <1.40 <1.40 <1.40 <1.40 <1.40 1.40 10
05/18/16 <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 10
11/14/16 <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 10
05/31/17 2.28 J <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 10
11/15/17 <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 10
05/16/18 2.13 J <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 10
11/13/18 <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 10
05/21/19 <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 10
11/20/19 2.81 J <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 10
05/20/20 <1.40 <1.40 <1.40 <1.40 1.40 10
11/18/20 2.18 J <1.40 <1.40 <1.40 1.40 10
05/18/21 2.41 J 5.97 J <1.40 2.12 J 1.40 10
11/23/21 10.4 <1.40 <1.40 1.66 J 1.40 10
05/23/22 2.86 J <1.40 <1.40 1.59 J 1.40 10
11/08/22 5.2 J <1.1 <1.1 <1.1 1.1 10
05/07/23 1.3 J <0.0039 <0.0039 <0.0039 <0.0039 <0.030
11/20/23 <5.0 <5.0 <5.0 <5.0 5.0
Constituent Well / Date MW-106 MW-107 MW-108 MW-110D MW110S MW-111 MW-112 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
chromium 02/27/97 <10 <10 37 B <10 <10 30 i,t,f
FBAC = 3.228 08/27/96 42 17 20 11 B <10 86 f
MCL = 100 05/18/95 28 J <10 50 J 10 B 16.5 B 187 J i,t,d,ms
NCGQS = 10 (2L Std)11/28/95 41 <10 88 69 <10 24
2L Std = 10 (Jan. 2010)07/20/95 27 J/26 J <10 <10 22 J 12 B 16 B f,ms
2L Std = 50 (pre- Jan. 2010)02/28/96 20 J <10 22 J <10 <10 22 J t,f,ms
09/04/97 <10 <10 <10 <10 <10 <10 f
03/25/98 <10 <10 17 <10 <10 16 i
11/02/98 <10 <10 <10 <10 <10
04/27/99 <10 <10 <10 <10 <10 <10 cc
11/22/99 <10 <10 45 <10 <10 <10
05/24/00 <10 <10 <10 <10 <10 <10
11/30/00 <10 <10 <10 <10 <10 <10
05/30/01 <10 <10 <10 <10 <10 12 B i, f, t
11/14/01 <10 <10 <10 <10 <10 <10 i
06/06/02 <10 <10 15 <10 <10 <10 i
03/13/03 <10 <10 <10 <10
06/19/03 <10 <10 <10 <10
12/09/03 <10 <10 <10 <10
06/23/04 <10 <10 <10 <10
12/01/04 <10 <10 <10 <10
06/06/05 <10 <10 <10 <10 <10
11/03/05 <10 <10 <10 <10 <10
05/24/06 <10 <10 <10 <10 <10
11/15/06 <10 <10 <10 <10 <10
06/14/07 <0.7 <0.7 <0.7 1.3 JB 5.8 JB 0.7 10 t, f, cc
12/11/07 0.76 JB 0.81 JB <0.7 <0.7 1.1 JB 0.7 10 i
06/09/08 1.3 JB 1.6 JB 2.1 JB 0.9 JB 8.4 J 0.7 10 f
11/06/08 <0.7 <0.7 <0.7 1.9 JB 6.7 JB 0.7 10 t, f, i
05/20/09 3.2 J <0.7 <0.7 <0.7 2.4 J 0.7 10
10/20/09 2.36 J <1 1.69 J 3.5 J 2.78 J 1 10
06/23/10 1.63 J <1 <1 <1 1.46 J 1 10
11/17/10 1.13 J <1 <1 <1 1.65 J 1 10
05/25/11 <1 <1 1.14 J <1 3.69 J 1.61 J 1 10
11/16/11 1.84 J <1 <1 <1 10.1 <1 1 10
06/07/12 <1 <1 <1 <1 4.1 J 1.89 J 1 10
11/14/12 <1 <1 <1 1.46 J 5.05 J 1 10
05/14/13 1.66 J <1.4 <1.4 <1.4 <1.4 1.4 10 i
11/13/13 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 10
05/14/14 <1.40 <1.40 <1.40 10.4 1.46 J 1.40 10
11/12/14 <1.40 <1.40 <1.40 2.35 J <1.40 1.40 10
05/13/15 2.96 J 209 R 4.21 J 5.99 JB 4.29 J 1.40 10
06/16/15 <1.40 1.40 10 verification
11/10/15 <1.40 <1.40 <1.40 2.30 J <1.40 1.40 10
05/18/16 <1.40 <1.40 <1.40 2.31 J <1.40 1.40 10
11/14/16 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 10
05/31/17 <1.40 <1.40 <1.40 9.53 J <1.40 1.40 10
11/15/17 <1.40 <1.40 <1.40 3.14 J <1.40 1.40 10
05/16/18 1.65 J <1.40 <1.40 2.45 J <1.40 1.40 10
11/13/18 <1.40 <1.40 <1.40 7.40 J <1.40 1.40 10
05/21/19 <1.40 <1.40 <1.40 5.77 J <1.40 1.40 10
11/20/19 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 10
05/20/20 <1.40 <1.40 <1.40 <1.40 1.40 10
11/18/20 <1.40 <1.40 <1.40 <1.40 1.40 10
05/18/21 <1.40 <1.40 <1.40 <1.40 1.40 10
11/29/21 <1.40 <1.40 <1.40 <1.40 1.40 10
05/23/22 <1.40 2.06 J <1.40 1.59 J 1.40 10
11/08/22 <1.1 <1.1 <1.1 <1.1 1.1 10
05/07/23 <0.0039 <0.0039 <0.0039 2.3 J <0.0039 <0.030
11/20/23 <5.0 <5.0 <5.0 <5.0 5.0
Constituent Well / Date MW-101 MW-102S MW-102D MW-102DR MW-103D MW-103S MW-104 MW-105 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
cobalt 05/18/95 107 B <10 <10 <10 <10 <10 <10 i,t,ms
FBAC = 2.15 07/20/95 18 <10 <10 <10 <10 <10 <10
NCGQS = 1 (GWPS)11/28/95 20 <10 <10 <10 18 <10 <10
GWPS = 70 (pre-Oct. 2010)02/28/96 <10 <10 <10 <10 82 <10 <10
GWPS = 1 (Oct. 2010)08/27/96 18 <10 <10 <10 30 <10 10 i
02/27/97 <10 14 <10 <10 29 <10 <10 i,f
09/04/97 <10 <10 <10 <10 82 <10 <10 i
03/25/98 13 <10 <10 <10 56 <10 <10
11/02/98 <10 <10 <10 <10 <10 <10 <10 i
04/27/99 19 J <10 <10 <10 <10 <10 <10 cc
11/22/99 <10 <10 <10 <10 <10 <10 <10 cc,d,lcs,q
05/24/00 <10 <10 <10 <10 <10 <10 <10 t,f
11/30/00 <10 <10 <10 <10 13 <10 <10 i,f
05/30/01 <10 <10 <10 <10 <10 <10 <10 i, f, t
11/14/01 <10 <10 <10 <10 <10 <10 <10
06/06/02 <10 <10 <10 <10 <10 <10 <10
03/13/03 <10 <10 <10 <10 <10 <10 <10
06/19/03 <10 <10 <10 <10 <10 <10 <10
12/09/03 <10 <10 <10 <10 <10 <10 <10
06/23/04 17 <10 <10 <10 <10 <10 <10
12/01/04 <10 <10 <10 <10 <10 <10 14
06/06/05 14 <10 <10 <10 <10 <10 17
11/03/05 <10 <10 <10 <10 <10 <10 24
05/24/06 <10 <10 <10 <10 <10 <10 19
11/15/06 <10 <10 <10 <10 <10 <10 24 i
06/14/07 26.6 J 3.2 J <0.7 <0.7 2.5 J 1.2 J 47.2 J 0.7 10 cc
12/11/07 6.3 J 2.3 J 0.7 J <0.7 4.1 J 1.5 J 39 0.7 10
06/09/08 25.8 2.0 J 1.6 J 1.2 J 0.8 J <0.7 50.8 0.7 10
11/06/08 16.6 2.7 J 1.5 J 1.4 J 0.9 J <0.7 56.4 0.7 10
05/20/09 4.3 J 2.1 J 0.7 J <0.6 5.1 J <0.6 80.4 0.6 10
10/20/09 11 2.93 J <1.1 <1.1 <1.1 <1.1 58.1 1.1 10
06/23/10 7.86 J 1.82 J <1.1 <1.1 2.68 J <1.1 47.8 1.1 10
11/17/10 3.13 J 2.26 J <1.1 1.43 J <1.1 <1.1 47.6 1.1 10
05/25/11 11.8 1.93 J <1.1 <1.1 <1.1 <1.1 73.7 1.1 10
11/16/11 8.17 J 1.94 J <1.1 <1.1 <1.1 <1.1 48.2 1.1 10
06/07/12 <1.1 2.08 J <1.1 <1.1 <1.1 1.14 J 65.8 1.1 10
11/14/12 9.18 J 2.81 J <1.1 <1.1 <1.1 <1.1 48.5 1.1 10
05/14/13 <1.1 1.5 JB <1.1 <1.1 4.32 JB 1.35 JB 49.3 1.1 10 i
11/13/13 3.06 J 4.43 J <1.10 1.40 J 1.13 J 1.22 J 48.9 1.10 10
05/14/14 6.83 J 2.70 J <1.10 1.57 J 1.44 J <1.10 44.5 1.10 10
11/12/14 9.57 J 4.73 J <1.10 1.10 J <1.10 <1.10 46.6 1.10 10
05/13/15 4.42 J 1.83 J <1.10 <2.20 <1.10 <1.10 43.1 1.10/2.20 10
06/16/15 verification
11/10/15 <1.10 3.27 J <1.10 <1.10 <1.10 <1.10 39.5 1.10 10
05/18/16 3.60 J 2.34 J <1.10 <1.10 <1.10 <1.10 39.1 1.10 10
11/14/16 <1.10 3.64 J <1.10 <1.10 <1.10 <1.10 35.6 1.10 10
05/31/17 2.45 J 2.76 J <1.10 <1.10 <1.10 <1.10 33.1 1.10 10
11/15/17 2.78 J 3.98 J <1.10 <1.10 <1.10 <1.10 37.7 1.10 10
05/16/18 3.25 JB 2.61 JB 1.15 JB <1.10 1.10 JB <1.10 29.6 1.10 10 i
11/13/18 1.67 J 5.98 J 1.86 J 2.04 J 1.46 J 2.04 J 31.6 1.40 10
05/21/19 3.62 J 4.92 J <1.40 <1.40 <1.40 <1.40 30 1.40 10
11/20/19 2.56 J 2.29 J <1.40 <1.40 <1.40 <1.40 30.8 1.40 10
05/20/20 2.89 J 1.91 J <1.40 25.4 1.40 10
11/18/20 2.96 J 1.43 J <1.40 25.3 1.40 10
05/18/21 8.07 J 1.86 J <1.40 29.8 1.40 10
11/23/21 6.63 J 2.12 J <1.40 28.1 1.40 10
05/23/22 4.15 J 4.15 J <1.40 28.8 1.40 10
11/08/22 3.5 J 3.2 J <1.40 27.0 1.40 10
05/07/23 3.2 J <1.40 <1.40 33 1.40 10
11/20/23 <5.0 <5.0 <5.0 25.8 5.0
Constituent Well / Date MW-106 MW-107 MW-108 MW-110D MW110S MW-111 MW-112 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
cobalt 05/18/95 19 J <10 23 J 16 J 43 J 71 B i,t,ms
FBAC = 2.15 07/20/95 14/14 <10 <10 14 23 <10
NCGQS = 1 (GWPS)11/28/95 50 <10 50 810 15 19
GWPS = 70 (pre-Oct. 2010)02/28/96 18 <10 <10 14 17 14
GWPS = 1 (Oct. 2010)08/27/96 32 13 <10 29 10 <10 i
02/27/97 <10 <10 15 <10 <10 11 i,f
09/04/97 21 <10 <10 <10 <10 <10 i
03/25/98 30 <10 11 <10 <10 24
11/02/98 34 <10 <10 <10 <10 i
04/27/99 22 J <10 <10 <10 <10 <10 cc
11/22/99 19 J <10 <10 <10 <10 12 J cc,d,lcs,q
05/24/00 26 <10 <10 <10 <10 15 B t,f
11/30/00 <10 <10 <10 <10 <10 <10 i,f
05/30/01 <10 <10 <10 <10 <10 <10 i, f, t
11/14/01 22 <10 <10 <10 <10 <10
06/06/02 <10 <10 <10 <10 <10 <10
03/13/03 <10 <10 <10 <10
06/19/03 <10 <10 <10 <10
12/09/03 18 <10 <10 <10
06/23/04 <10 <10 <10 <10
12/01/04 23 11 <10 <10
06/06/06 <10 <10 <10 <10
11/03/05 12 <10 <10 <10
05/24/06 <10 <10 <10 <10
11/15/06 <10 <10 <10 <10 i
06/14/07 3.4 J 9.1 J 1.7 J <0.7 0.8 J 0.7 10 cc
12/11/07 13.9 16.4 <0.7 0.7 J 0.97 J 0.7 10
06/09/08 5.6 J 17.6 1.7 J <0.7 4.2 J 0.7 10
11/06/08 1.9 J 13.7 1.6 J 2.3 J 2.3 J 0.7 10
05/20/09 3.6 J 21 1.1 J <0.6 2.1 J 0.6 10
10/20/09 4.82 J 19 4.26 J 2.73 J 49.9 1.1 10
06/23/10 1.89 J 14.6 <1.1 <1.1 1.34 J 1.1 10
11/17/10 1.19 J 16.8 <1.1 <1.1 1.66 J 1.1 10
05/25/11 1.36 J 13 <1.1 <1.1 3.91 J 48.8 1.1 10
11/16/11 2.61 J 12.4 1.15 J <1.1 5.72 J 19.7 1.1 10
06/07/12 4.26 J 11.3 <1.1 <1.1 4.37 J 50.3 1.1 10
11/14/12 1.63 J 14 <1.1 2.08 J 44.1 1.1 10
05/14/13 1.74 JB 10.6 <1.1 <1.1 36.5 1.1 10 i
11/13/13 2.93 J 11.2 1.48 J 1.57 J 37.3 1.10 10
05/14/14 2.00 J 7.34 J 1.25 J 12.4 27.6 1.10 10
11/12/14 3.01 J 15.8 1.38 J 3.11 J 31.7 1.10 10
05/13/15 <1.10 208 R 2.15 J 3.05 J 13.6 1.10/2.20 10
06/16/15 6.81 J 1.10 10 verification
11/10/15 <1.10 5.95 J <1.10 3.58 J 13.7 1.10 10
05/18/16 <1.10 1.68 J <1.10 1.34 J 8.27 J 1.10 10
11/14/16 1.31 J 3.79 J <1.10 <1.10 14.30 1.10 10
05/31/17 1.10 J 2.00 J <1.10 8.40 J 6.98 J 1.10 10
11/15/17 <1.10 3.41 J <1.10 2.30 J 11.8 1.10 10
05/16/18 1.91 JB 1.77 JB <1.10 3.36 JB 5.21 JB 1.10 10 i
11/13/18 2.11 J 2.37 J <1.40 9.09 J 8.02 J 1.40 10
05/21/19 <1.40 <1.40 <1.40 7.58 J 4.68 J 1.40 10
11/20/19 <1.40 <1.40 <1.40 2.23 J 9.57 J 1.40 10
05/20/20 5.98 J <1.40 <1.40 2.98 J 1.40 10
11/18/20 2.67 J <1.40 <1.40 1.59 J 1.40 10
05/18/21 1.61 J <1.40 <1.40 1.71 J 1.40 10
11/29/21 4.46 J <1.40 <1.40 1.96 J 1.40 10
05/23/22 2.66 J <1.40 <1.40 2.98 J 1.40 10
11/08/22 3.4 J <1.40 <1.40 1.4 J 1.40 10
05/07/23 <1.40 <1.40 <1.40 1.8 J 1.40 10
11/20/23 <5.0 <5.0 <5.0 <5.0 5.0
Constituent Well / Date MW-101 MW-102S MW-102D MW-102DR MW-103D MW-103S MW-104 MW-105 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
copper 05/18/95 <200 <200 <200 <200 <200 <200 <200
MCL = 1300 07/20/95 <200 <200 <200 <200 <200 <200 <200
FBAC = 7807 11/28/95 <200 <200 <200 <200 285 <200 <200
NCGQS = 1000 (2L Std)02/28/96 <200 <200 <200 <200 <200 <200 <200 f,sd
08/27/96 <200 <200 <200 <200 <200 <200 <200 i,t,f
02/27/97 <200 <200 <200 <200 <200 <200 <200
09/04/97 <200 <200 <200 <200 <200 <200 <200 t
03/25/98 <200 <200 <200 <200 <200 <200 <200 i
11/02/98 <200 <200 <200 <200 <200 <200 <200
04/27/99 <200 <200 <200 <200 <200 <200 <200
11/22/99 <200 <200 <200 <200 <200 <200 <200
05/24/00 <200 <200 <200 <200 <200 <200 <200
11/30/00 <200 <200 <200 <200 <200 <200 <200
05/30/01 <200 <200 <200 <200 <200 <200 <200 i, f, t
11/14/01 <200 <200 <200 <200 <200 <200 <200
06/06/02 <200 <200 <200 <200 <200 <200 <200
03/13/03 <200 <200 <200 <200 <200 <200 <200
06/19/03 <200 <200 <200 <200 <200 <200 <200
12/09/03 <200 <200 <200 <200 <200 <200 <200
06/23/04 <200 <200 <200 <200 <200 <200 <200
12/01/04 <200 <200 <200 <200 <200 <200 <200
06/06/05 200 <200 <200 <200 <200 <200 <200
11/03/05 <200 <200 <200 <200 <200 <200 <200
05/24/06 <200 <200 <200 <200 <200 <200 <200
11/15/06 <200 <200 <200 <200 <200 <200 <200
06/14/07 3.3 J 3.1 J 2.9 J 3.5 J 3.9 J 2.1 J 2.7 J 2 10
12/11/07 3.8 JB <2 <2 <2 1.3 JB <2 1.8 JB 2 10 f
06/09/08 3.5 J <2 <2 <2 <2 <2 <2 2 10
11/06/08 8.5 JB <2 <2 <2 <2 <2 <2 2 10 i
05/20/09 3.62 J <0.81 4.63 J <0.81 5.69 J <0.81 <0.81 0.81 10
10/20/09 14.2 <1.6 2.19 J <1.6 <1.6 <1.6 <1.6 1.6 10
06/23/10 4.79 J <1.6 3.07 J <1.6 5.01 J <1.6 <1.6 1.6 10
11/17/10 6.42 J <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 1.6 10 i
05/25/11 4.51 J <1.6 1.78 J <1.6 <1.6 <1.6 <1.6 1.6 10
11/16/11 3.47 J <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 1.6 10
06/07/12 3.07 J <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 1.6 10
11/14/12 8.16 J <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 1.6 10
05/14/13 <1.6 <1.6 <1.6 <1.6 6.46 J <1.6 <1.6 1.6 10
11/13/13 <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 1.60 10
05/14/14 2.03 J <1.60 2.08 J <1.60 <1.60 <1.60 <1.60 1.60 10
11/12/14 8.62 J <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 1.60 10
05/13/15 <1.60 <1.60 <1.60 <3.20 <1.60 <1.60 <1.60 1.60/3.20 10
06/16/15 verification
11/10/15 <1.60 <1.60 <1.60 1.60 <1.60 <1.60 <1.60 1.60 10
05/18/16 <1.60 <1.60 <1.60 1.60 <1.60 <1.60 <1.60 1.60 10
11/14/16 4.57 J 4.47 J 3.89 J 4.37 J 4.05 J 3.95 J <1.60 1.60 10
05/31/17 <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 1.60 10
08/22/17 verification
11/15/17 2.04 J <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 1.60 10
05/16/18 <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 1.60 10
11/13/18 <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 1.60 10
05/21/19 1.86 J <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 1.60 10
11/20/19 <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 1.60 10
05/20/20 <1.60 <1.60 <1.60 <1.60 1.60 10
11/18/20 <1.60 <1.60 <1.60 <1.60 1.60 10
05/18/21 <1.60 <1.60 <1.60 <1.60 1.60 10
11/23/21 <1.60 <1.60 <1.60 <1.60 1.60 10
05/23/22 <1.60 <1.60 <1.60 <1.60 1.60 10
11/08/22 7.8 J <3.2 <3.2 <3.2 3.2 20
05/07/23 <3.2 <3.2 <3.2 <3.2 3.2 20
11/20/23 15.6 <5.0 <5.0 <5.0 5.0
Constituent Well / Date MW-106 MW-107 MW-108 MW-110D MW110S MW-111 MW-112 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
copper 05/18/95 <200 <200 <200 <200 <200 <200
MCL = 1300 07/20/95 <200 <200 <200 <200 <200 <200
FBAC = 7807 11/28/95 <200 <200 <200 483 <200 <200
NCGQS = 1000 (2L Std)02/28/96 <200 <200 <200 <200 <200 <200 f,sd
08/27/96 <200 <200 <200 <200 <200 <200 i,t,f
02/27/97 <200 <200 <200 <200 <200 <200
09/04/97 <200 <200 <200 <200 <200 <200 t
03/25/98 <200 <200 <200 <200 <200 <200 i
11/02/98 <200 <200 <200 <200 <200
04/27/99 <200 <200 <200 <200 <200 <200
11/22/99 <200 <200 <200 <200 <200 <200
05/24/00 <200 <200 <200 <200 <200 <200
11/30/00 <200 <200 <200 <200 <200 <200
05/30/01 <200 <200 <200 <200 <200 <200 i, f, t
11/14/01 <200 <200 <200 <200 <200 <200
06/06/02 <200 <200 <200 <200 <200 <200
03/13/03 <200 <200 <200 <200
06/19/03 <200 <200 <200 <200
12/09/03 <200 <200 <200 <200
06/23/04 <200 <200 <200 <200
12/01/04 <200 <200 <200 <200
06/06/05 <200 <200 <200 <200 <200
11/03/05 <200 <200 <200 <200 <200
05/24/06 <200 <200 <200 <200 <200
11/15/06 <200 <200 <200 <200 <200
06/14/07 2.8 J 3.3 J 2.2 J <2 2.8 J 2 10
12/11/07 3.1 JB <2 <2 2.7 JB 2.9 JB 2 10 f
06/09/08 <2 <2 <2 2.2 J 4.3 J 2 10
11/06/08 <2 <2 <2 <2 5.3 JB 2 10 i
05/20/09 4.39 J <0.81 1.01 J <0.81 1.80 J 0.81 10
10/20/09 <1.6 <1.6 1.99 J 3.83 J <1.6 1.6 10
06/23/10 2.84 J 3.74 J <1.6 <1.6 2.25 J 1.6 10
11/17/10 2.22 J 7.35 J 3.01 J <1.6 3.02 J 1.6 10 i
05/25/11 1.78 J 1.71 J 3.17 J 3.17 J 5.24 J <1.6 1.6 10
11/16/11 <1.6 2.79 J <1.6 <1.6 8.05 J <1.6 1.6 10
06/07/12 2.11 J 2.97 J 1.65 J 1.78 J 5.49 J <1.6 1.6 10
11/14/12 <1.6 <1.6 <1.6 <1.6 <1.6 1.6 10
05/14/13 2.34 J <1.6 <1.6 <1.6 <1.6 1.6 10
11/13/13 <1.60 <1.60 <1.60 2.69 J <1.60 1.60 10
05/14/14 1.90 J <1.60 <1.60 11.6 R 2.18 J 1.60 10
11/12/14 1.89 J <1.60 4.98 J 3.28 J <1.60 1.60 10
05/13/15 <1.60 198 R <1.60 3.62 J <1.60 1.60/3.20 10
06/16/15 <1.60 1.60 10 verification
11/10/15 <1.60 <1.60 <1.60 2.16 J <1.60 1.60 10
05/18/16 <1.60 <1.60 <1.60 <1.60 <1.60 1.60 10
11/14/16 <1.60 <1.60 4.25 J <1.60 <1.60 1.60 10
05/31/17 2.29 J 1.80 J <1.60 2.29 J 1.60 10
08/22/17 <1.60 1.60 10 verification
11/15/17 <1.60 <1.60 <1.60 2.82 J <1.60 1.60 10
05/16/18 1.78 J <1.60 <1.60 <1.60 <1.60 1.60 10
11/13/18 <1.60 <1.60 <1.60 4.46 J <1.60 1.60 10
05/21/19 3.63 J <1.60 <1.60 6.92 J 1.64 J 1.60 10
11/20/19 <1.60 <1.60 <1.60 <1.60 <1.60 1.60 10
05/20/20 1.83 J <1.60 <1.60 <1.60 1.60 10
11/18/20 2.13 J <1.60 <1.60 <1.60 1.60 10
05/18/21 <1.60 <1.60 <1.60 <1.60 1.60 10
11/29/21 2.13 J <1.60 <1.60 <1.60 1.60 10
05/23/22 2.02 J 2.21 J <1.60 2.22 J 1.60 10
11/08/22 <3.2 <3.2 <3.2 34 3.20 20
05/07/23 <3.2 <3.2 <3.2 <3.2 3.20 20
11/20/23 <5.0 <5.0 <5.0 5.8 5.0
Constituent Well / Date MW-101 MW-102S MW-102D MW-102DR MW-103D MW-103S MW-104 MW-105 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
iron 05/18/95
MCL = ♦07/20/95
FBAC = 9778 11/28/95
NCGQS = 300 (2L Std)02/28/96
08/27/96
02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/06/05
11/03/05
05/24/06
11/15/06
06/13/07
12/12/07
06/11/08
11/06/08
05/20/09
11/19/09
06/23/10
11/17/10
05/24/11
11/17/11
06/05/12
11/14/12
05/13/13
11/12/13
05/14/14
11/11/14
05/13/15
11/10/15
05/18/16
11/15/16
05/30/17
11/14/17
05/14/18
11/14/18
05/21/19
11/20/19
05/20/20
11/18/20
05/18/21
11/23/21
05/23/22
11/09/22
05/07/23
11/20/23
Constituent Well / Date MW-106 MW-107 MW-108 MW-110D MW110S MW-111 MW-112 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
iron 05/18/95
MCL = ♦07/20/95
FBAC = 9778 11/28/95
NCGQS = 300 (2L Std)02/28/96
08/27/96
02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/06/05
11/03/05
05/24/06
11/15/06
06/13/07 59 JB 95.7 JB 21.5 300
12/12/07 12500 74 JB 21.5 300
06/11/08 9510 <21.5 21.5 300
11/06/08 2440 115 JB 21.5 300
05/20/09 2180 216 J 31 300
11/19/09 2440 218 J 22 300
06/23/10 1780 550 22 300
11/17/10 3330 256 J 22 300
05/24/11 8710 171 J 22 300
11/17/11 369 2110 22 300
06/05/12 2610 103 J 22 300
11/14/12 163 J 22 300
05/13/13 152 J 22 300
11/12/13 89.5 J 22.0 300
05/14/14 175 J 22.0 300
11/11/14 258 J 22.0 300
05/13/15 118 J 22.0 300
11/10/15 356 22.0 300
05/18/16 90.7 22.0 300
11/15/16 225 J 22.0 300
05/30/17 80.7 J 22.0 300
11/14/17 141 J 22.0 300
05/14/18 64.4 J 22.0 300
11/14/18 114 22.0 50
05/21/19 123 22.0 50
11/20/19 169 22.0 50
05/20/20 55 22.0 50
11/18/20 119 22.0 50
05/18/21 82.3 22.0 50
11/29/21 103 22.0 50
05/23/22 < 22.0 22.0 50
11/09/22 73 J 20.0 100
05/07/23 69 J 20.0 100
11/20/23 139 50
Constituent Well / Date MW-101 MW-102S MW-102D MW-102DR MW-103D MW-103S MW-104 MW-105 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
lead 05/18/95 58 B 11 B <10 <10 <10 <10 <10 i,t
MCL = 15 07/20/95 <10 <10 <10 <10 <10 <10 <10 f
FBAC = 10 11/28/95 <10 <10 <10 <10 63 J <10 <10 i,ms
NCGQS = 15 (2L Std)02/28/96 <10 <10 <10 <10 41 <10 <10 i,t,f
08/27/96 <10 <10 <10 <10 <10 <10 <10 f
02/27/97 <10 <10 <10 <10 11 B <10 <10 t,f,ms
09/04/97 <10 12 B <10 <10 25 B 18 B <10 i,t,f
03/25/98 <10 <10 <10 12 B 30 <10 <10 i,t
11/02/98 <10 <10 <10 13.7 J <10 <10 <10 d
04/27/99 <10 <10 <10 <10 <10 <10 <10 cc
11/22/99 <10 <10 <10 <10 <10 <10 <10
05/24/00 <10 <10 <10 <10 <10 <10 <10
11/30/00 <10 <10 <10 <10 <10 <10 <10
05/30/01 <10 <10 <10 <10 <10 <10 <10 i, f, t
11/14/01 <10 <10 <10 <10 <10 <10 <10
06/06/02 <10 <10 <10 <10 <10 <10 <10 i
03/13/03 <10 <10 <10 <10 <10 <10 <10
06/19/03 <10 <10 <10 <10 <10 <10 <10
12/09/03 <10 <10 <10 <10 <10 <10 <10
06/23/04 <10 <10 <10 16 <10 <10 <10
12/01/04 <10 <10 <10 <10 <10 <10 <10
06/06/05 <10 <10 <10 <10 <10 <10 <10
11/03/05 <10 <10 <10 <10 <10 <10 <10
05/24/06 <10 <10 <10 <10 <10 <10 <10
11/15/06 <10 <10 <10 <10 <10 <10 <10 i, f
06/14/07 <2 <2 <2 <2 <2 <2 <2 2 10
12/11/07 2 J <2 <2 <2 <2 2.9 J <2 2 10
06/09/08 <2 <2 <2 <2 <2 <2 2.1 JB 2 10 i
11/06/08 <2 2.2 JB <2 <2 <2 <2 <2 2 10 i
05/20/09 <1.6 <1.6 <1.6 <1.6 2.4 J <1.6 <1.6 1.6 10
10/20/09 8.74 J <1.9 <1.9 <1.9 2.03 J <1.9 <1.9 1.9 10
06/23/10 <1.9 <1.9 <1.9 <1.9 2.16 J <1.9 <1.9 1.9 10
11/17/10 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10
05/25/11 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10
11/16/11 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10
06/07/12 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 2.28 J 1.9 10
11/14/12 2.77 J <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10
05/14/13 <2.1 <2.1 <2.1 <2.1 <2.1 <2.1 <2.1 2.1 10
11/13/13 <2.10 <2.10 <2.10 <2.10 <2.10 <2.10 <2.10 2.10 10
05/14/14 <2.10 <2.10 <2.10 2.22 J <2.10 <2.10 <2.10 2.10 10
11/12/14 <2.10 <2.10 <2.10 <2.10 <2.10 <2.10 <2.10 2.10 10
05/13/15 <3.10 <3.10 <3.10 <6.20 <3.10 <3.10 <3.10 3.10/6.20 10
06/16/15 verification
11/10/15 <3.10 <3.10 <3.10 <3.10 <3.10 3.29 J <3.10 3.10 10
05/18/16 <3.10 <3.10 <3.10 <3.10 <3.10 <3.10 <3.10 3.10 10
11/14/16 <3.10 <3.10 <3.10 <3.10 <3.10 <3.10 <3.10 3.10 10
05/31/17 <3.10 <3.10 <3.10 <3.10 <3.10 <3.10 <3.10 3.10 10
11/15/17 <3.10 <3.10 <3.10 <3.10 <3.10 <3.10 <3.10 3.10 10
05/16/18 <3.10 <3.10 <3.10 <3.10 <3.10 <3.10 <3.10 3.10 10
11/13/18 <3.10 <3.10 <3.10 <3.10 <3.10 <3.10 <3.10 3.10 10
05/21/19 <3.10 <3.10 <3.10 <3.10 <3.10 <3.10 <3.10 3.10 10
11/20/19 <3.10 <3.10 <3.10 <3.10 <3.10 <3.10 <3.10 3.10 10
05/20/20 <3.10 <3.10 <3.10 <3.10 3.10 10
11/18/20 <3.10 <3.10 <3.10 <3.10 3.10 10
05/18/21 <3.10 <3.10 <3.10 <3.10 3.10 10
11/23/21 <3.10 <3.10 <3.10 <3.10 3.10 10
05/23/22 <3.10 <3.10 <3.10 <3.10 3.10 10
11/08/22 <6.6 <6.6 <6.6 <6.6 6.6 10
05/07/23 <6.6 <6.6 <6.6 <6.6 6.6 10
11/20/23 <5.0 <5.0 <5.0 <5.0 5.0
Constituent Well / Date MW-106 MW-107 MW-108 MW-110D MW110S MW-111 MW-112 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
lead 05/18/95 17 B <10 <10 31.1 B 17.3 B 16 B i,t
MCL = 15 07/20/95 <10/<10 <10 <10 37 <10 <10 f
FBAC = 10 11/28/95 15 B <10 18 J 163 J <10 <10 i,ms
NCGQS = 15 (2L Std)02/28/96 <10 <10 <10 18 B 21 B <10 i,t,f
08/27/96 10 12 <10 13 <10 <10 f
02/27/97 <10 <10 <10 <10 <10 <10 t,f,ms
09/04/97 11 B 16 B 18 B 14 B <10 <10 i,t,f
03/25/98 <10 <10 <10 <10 <10 <10 i,t
11/02/98 <10 <10 <10 <10 <10 d
04/27/99 <10 <10 <10 <10 <10 <10 cc
11/22/99 <10 <10 <10 <10 <10 <10
05/24/00 <10 <10 <10 <10 <10 <10
11/30/00 <10 <10 <10 <10 <10 <10
05/30/01 <10 <10 <10 40 <10 <10 i, f, t
11/14/01 <10 <10 <10 31 <10 <10
06/06/02 <10 <10 <10 27 <10 <10 i
03/13/03 <10 <10 <10 <10
06/19/03 <10 <10 <10 <10
12/09/03 <10 <10 <10 <10
06/23/04 <10 <10 <10 <10
12/01/04 <10 <10 <10 <10
06/06/05 <10 <10 16 <10 <10
11/03/05 <10 <10 <10 <10 <10
05/24/06 <10 10 <10 <10 <10
11/15/06 <10 10 B <10 <10 <10 i, f
06/14/07 <2 <2 22.1 <2 <2 2 10
12/11/07 <2 <2 4.4 J <2 <2 2 10
06/09/08 <2 <2 5.5 JB <2 <2 2 10 i
11/06/08 <2 <2 10 JB <2 3.2 JB 2 10 i
05/20/09 <1.6 <1.6 1.6 J <1.6 <1.6 1.6 10
10/20/09 <1.9 <1.9 2.76 J <1.9 2.24 J 1.9 10
06/23/10 2.25 J <1.9 <1.9 <1.9 <1.9 1.9 10
11/17/10 <1.9 <1.9 3.07 J <1.9 <1.9 1.9 10
05/25/11 <1.9 <1.9 5.61 J <1.9 <1.9 2.05 J 1.9 10
11/16/11 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10
06/07/12 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10
11/14/12 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10
05/14/13 <2.1 <2.1 <2.1 <2.1 <2.1 2.1 10
11/13/13 <2.10 <2.10 <2.10 <2.10 <2.10 2.10 10
05/14/14 <2.10 <2.10 <2.10 <2.10 <2.10 2.10 10
11/12/14 <2.10 <2.10 <2.10 <2.10 <2.10 2.10 10
05/13/15 <3.10 208 R <3.10 <3.10 <3.10 3.10/6.20 10
06/16/15 <3.10 3.10 10 verification
11/10/15 <3.10 3.82 J 4.07 J <3.10 <3.10 3.10 10
05/18/16 <3.10 <3.10 <3.10 <3.10 <3.10 3.10 10
11/14/16 <3.10 <3.10 <3.10 <3.10 <3.10 3.10 10
05/31/17 <3.10 <3.10 <3.10 <3.10 <3.10 3.10 10
11/15/17 <3.10 <3.10 <3.10 <3.10 <3.10 3.10 10
05/16/18 <3.10 <3.10 <3.10 <3.10 <3.10 3.10 10
11/13/18 <3.10 <3.10 <3.10 <3.10 <3.10 3.10 10
05/21/19 <3.10 <3.10 <3.10 <3.10 <3.10 3.10 10
11/20/19 <3.10 <3.10 <3.10 <3.10 <3.10 3.10 10
05/20/20 <3.10 <3.10 <3.10 <3.10 3.10 10
11/18/20 <3.10 <3.10 <3.10 <3.10 3.10 10
05/18/21 <3.10 <3.10 <3.10 <3.10 3.10 10
11/29/21 <3.10 <3.10 <3.10 <3.10 3.10 10
05/23/22 <3.10 <3.10 <3.10 <3.10 3.10 10
11/08/22 <6.6 <6.6 <6.6 <6.6 6.60 10
05/07/23 <6.6 <6.6 <6.6 <6.6 6.60 10
11/20/23 <5.0 <5.0 <5.0 <5.0 5.0
Constituent Well / Date MW-101 MW-102S MW-102D MW-102DR MW-103D MW-103S MW-104 MW-105 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
manganese 06/14/07
FBAC = 3635 12/11/07
NCGQS = 50 (2L Std)06/09/08
11/06/08
05/20/09
10/20/09
06/23/10
11/17/10
05/25/11
11/16/11
06/07/12
11/14/12
05/14/13
11/13/13
05/14/14
11/12/14
05/13/15
11/10/15
05/18/16
11/14/16
05/31/17
11/15/17
05/16/18
11/13/18
05/21/19
11/20/19
05/20/20
11/18/20
05/18/21
11/29/21
11/09/22
05/07/23
11/20/23
Constituent Well / Date MW-106 MW-107 MW-108 MW-110D MW110S MW-111 MW-112 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
manganese 06/14/07 63 6 J
FBAC = 3635 12/11/07 32 J 17.6 J
NCGQS = 50 (2L Std)06/09/08 44 8.4 JB
11/06/08 33.8 JB 39.4 J
05/20/09 70.3 6 J
10/20/09 55.4 7.91 J
06/23/10 62.8 13 J
11/17/10 48.3 J 6.99 J
05/25/11 65.7 9.4 J
11/16/11 14.1 J 57.3
06/07/12 54.7 5.24 J
11/14/12 12.7 J
05/14/13 4.75 JB
11/13/13 10.8 J
05/14/14 9.97 J
11/12/14 16.8 J
05/13/15 9.24 J
11/10/15 7.71 J
05/18/16 8.70 J
11/14/16 9.93 J
05/31/17 8.79 J
11/15/17 13.7 J
05/16/18 8.77 J 1.5 50
11/13/18 4.49 J 1.5 10
05/21/19 7.31 J 1.50 10
11/20/19 20.5 1.50 10
05/20/20 8.80 J 1.50 10
11/18/20 3.08 J 1.50 10
05/18/21 2.31 J 1.50 10
11/29/21 8.69 J 1.50 10
11/09/22 2.9 J 1.3 10
05/07/23 6.6 J 1.3 10
11/20/23 <5.0 5.0
Constituent Well / Date MW-101 MW-102S MW-102D MW-102DR MW-103D MW-103S MW-104 MW-105 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
mercury 05/18/95
MCL = 2 07/20/95
FBAC = MRL 11/28/95
NCGQS = 1 (2L Std)02/28/96
2L Std = 1.05 (pre- Jan. 2010)08/27/96
2L Std = 1 (Jan. 2010)02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/06/05
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07
06/09/08
11/06/08 0.01 0.2 i
05/20/09
10/20/09 0.121 J <0.054 <0.054 <0.054 <0.054 <0.054 <0.054 0.054 0.2
06/23/10
11/17/10 <0.17 0.17 0.2
05/25/11 0.17 0.2
11/16/11 <0.17 0.17 0.2
06/07/12 0.17 0.2
11/14/12 <0.17 0.17 0.2
05/14/13 0.17 0.2
11/13/13 <0.170 0.170 0.2
05/14/14 0.17 0.2
11/12/14 <0.170 0.170 0.2
05/13/15 0.170 0.2
06/16/15 verification
11/10/15 <0.170 0.170 0.2
05/18/16 0.170 0.2
11/14/16 <0.170 0.170 0.2
05/31/17 0.170 0.2
11/15/17 <0.170 0.170 0.2
05/16/18 0.150 0.2
11/13/18 <0.150 0.150 0.2
05/21/19 <0.150 0.150 0.2
11/20/19 <0.150 0.150 0.2
05/20/20 <0.150 0.150 0.2
11/18/20 <0.150 0.150 0.2
05/18/21 <0.150 0.150 0.2
11/23/21 <0.150 0.150 0.2
05/23/22 <0.150 0.150 0.2
11/09/22 <0.080 0.080 0.20
05/07/23 <0.080 0.080 0.20
11/20/23 <0.20 0.20
Constituent Well / Date MW-106 MW-107 MW-108 MW-110D MW110S MW-111 MW-112 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
mercury 05/18/95
MCL = 2 07/20/95
FBAC = MRL 11/28/95
NCGQS = 1 (2L Std)02/28/96
2L Std = 1.05 (pre- Jan. 2010)08/27/96
2L Std = 1 (Jan. 2010)02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/06/05
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07
06/09/08
11/06/08 0.13 JB 0.16 JB 0.01 0.2 i
05/20/09
10/20/09 <0.054 <0.054 <0.054 <0.054 0.054 0.2
06/23/10
11/17/10 0.17 0.2
05/25/11 <0.17 <0.17 0.17 0.2
11/16/11 <0.17 <0.17 0.17 0.2
06/07/12 <0.17 <0.17 0.17 0.2
11/14/12 <0.17 0.17 0.2
05/14/13 <0.17 0.17 0.2
11/13/13 <0.170 0.170 0.2
05/14/14 <0.170 0.170 0.2
11/12/14 <0.170 0.170 0.2
05/13/15 <0.170 0.170 0.2
06/16/15
11/10/15 <0.170 0.170 0.2
05/18/16 <0.170 0.170 0.2
11/14/16 <0.170 0.170 0.2
05/31/17 <0.170 0.170 0.2
11/15/17 <0.170 0.170 0.2
05/16/18 <0.150 0.150 0.2
11/13/18 <0.150 0.150 0.2
05/21/19 <0.150 0.150 0.2
11/20/19 <0.150 0.150 0.2
05/20/20 <0.150 0.150 0.2
11/18/20 <0.150 0.150 0.2
05/18/21 <0.150 0.150 0.2
11/29/21 <0.150 0.150 0.2
05/23/22 2.57 J 0.150 0.2
11/09/22 <0.080 0.080 0.20
05/07/23 <0.080 0.080 0.20
11/20/23 <0.20 0.20
Constituent Well / Date MW-101 MW-102S MW-102D MW-102DR MW-103D MW-103S MW-104 MW-105 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
nickel 05/18/95 259 <50 <50 <50 <50 <50 <50 i,t
FBAC = 2.688 07/20/95 <50 <50 <50 <50 <50 <50 <50
NCGQS = 100 (2L Std)11/28/95 <50 <50 <50 <50 301 <50 <50
02/28/96 <50 <50 <50 <50 105 <50 <50
08/27/96 <50 <50 <50 <50 <50 <50 <50 i,t,f
02/27/97 <50 <50 <50 <50 <50 <50 <50 i,t,f,sd
09/04/97 <50 <50 <50 <50 72 <50 <50 t,f
03/25/98 <50 <50 <50 <50 63 <50 <50 t
11/02/98 <50 <50 <50 <50 <50 <50 <50
04/27/99 <50 <50 <50 <50 <50 <50 <50
11/22/99 <50 <50 <50 <50 <50 <50 <50
05/24/00 <50 <50 <50 <50 <50 <50 <50
11/30/00 <50 <50 <50 <50 <50 <50 <50
05/30/01 <50 <50 <50 <50 <50 <50 <50 i, f, t
11/14/01 <50 <50 <50 <50 <50 <50 <50
06/06/02 <50 <50 <50 <50 <50 <50 <50
03/13/03 <50 <50 <50 <50 <50 <50 <50
06/19/03 <50 <50 <50 <50 <50 <50 <50
12/09/03 <50 <50 <50 <50 <50 <50 <50
06/23/04 <50 <50 <50 <50 <50 <50 <50
12/01/04 <50 <50 <50 <50 <50 <50 <50
06/06/05 <50 <50 <50 <50 <50 <50 <50
11/03/05 <50 <50 <50 <50 <50 <50 <50
05/24/06 <50 <50 <50 <50 <50 <50 <50
11/15/06 <50 <50 <50 <50 <50 <50 <50
06/14/07 3.7 JB 4.1 JB 1.8 JB 2.6 JB 7.1 JB 1.2 JB 12 J 0.6 50 t, f
12/11/07 1.4 JB 2.8 JB <0.6 1.6 JB 2.6 JB 4.1 JB 10.4 J 0.6 50 t, i
06/09/08 1.3 J 1.3 J <0.6 0.8 J <0.6 <0.6 11.0 J 0.6 50
11/06/08 7.3 JB 3.1 JB 3.1 JB 0.7 JB 2.8 JB <0.6 25.6 JB 0.6 50 t, f
05/20/09 5.9 J 4.1 J 1.5 J 2.6 J 8.8 J <0.6 14.0 J 0.6 50
10/20/09 26.3 J 5.17 J <1.8 <1.8 2.69 J <1.8 10.4 J 1.8 50
06/23/10 <1.8 3.40 J <1.8 <1.8 4.75 J <1.8 7.73 J 1.8 50
11/17/10 <1.8 3.48 J <1.8 <1.8 2.16 J <1.8 8.94 J 1.8 50
05/25/11 3.06 J 3.6 J <1.8 2.46 J 3 J <1.8 14.6 J 1.8 50
11/16/11 <1.8 3.89 J <1.8 2.19 J <1.8 <1.8 8.53 J 1.8 50
06/07/12 4.25 J 4.92 J <1.8 1.97 J 1.9 J <1.8 12.4 J 1.8 50
11/14/12 5.03 J 5.03 J <1.8 <1.8 <1.8 <1.8 7.55 J 1.8 50
05/14/13 <1.8 2.82 JB <1.8 2.36 JB 10.1 JB <1.8 8.98 JB 1.8 50 i
11/13/13 <1.80 9.88 J <1.80 <1.80 1.87 J <1.80 9.85 J 1.80 50
05/14/14 <1.80 3.96 J <1.80 <1.80 2.43 J <1.80 8.27 J 1.80 50
11/12/14 8.38 J 5.11 J <1.80 2.04 J <1.80 <1.80 9.65 J 1.80 50
05/13/15 3.51 J 5.52 J <1.80 6.67 J 3.92 J <1.80 11.0 J 1.80/3.60 50
06/16/15 verification
11/10/15 <1.80 4.50 J <1.80 2.26 J 1.81 J <1.80 8.64 J 1.80 50
05/18/16 <2.20 5.32 J <2.20 <2.20 2.66 J <2.20 8.74 J 2.20 50
11/14/16 <2.20 6.72 J <2.20 3.20 J 3.97 J <2.20 9.04 J 2.20 50
05/31/17 <2.20 4.61 J <2.20 2.45 J <2.20 <2.20 8.55 J 2.20 50
11/15/17 <2.20 5.05 J <2.20 <2.20 2.23 J <2.20 7.72 J 2.20 50
05/16/18 <2.20 2.94 J <2.20 <2.20 <2.20 <2.20 6.81 J 2.20 50
11/13/18 <2.20 5.91 J <2.20 3.49 J 3.47 J <2.20 8.34 J 2.20 10
05/21/19 2.72 J 6.86 J <2.20 3.57 J 3.04 J <2.20 9.30 J 2.20 10
11/20/19 3.22 J 5.56 J <2.20 4.48 J 3.01 J <2.20 9.19 J 2.20 10
05/20/20 <2.20 <2.20 <2.20 5.30 J 2.20 10
11/18/20 <2.20 3.55 J <2.20 8.16 J 2.20 10
05/18/21 <2.20 3.90 J <2.20 9.24 J 2.20 10
11/23/21 4.17 J 4.50 J <2.20 7.80 J 2.20 10
05/23/22 <2.20 3.02 J <2.20 6.99 J 2.20 10
11/08/22 4.3 J 4.2 J <3.3 7.2 J 3.30 40
05/07/23 <3.3 <3.3 <3.3 9.2 J 3.30 40
11/20/23 5.5 <5.0 <5.0 8.6 5.0
Constituent Well / Date MW-106 MW-107 MW-108 MW-110D MW110S MW-111 MW-112 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
nickel 05/18/95 <50 <50 <50 <50 <50 125 i,t
FBAC = 2.688 07/20/95 <50/<50 <50 <50 <50 <50 <50
NCGQS = 100 (2L Std)11/28/95 <50 <50 84 402 <50 <50
02/28/96 <50 <50 <50 <50 <50 <50
08/27/96 <50 <50 <50 <50 <50 <50 i,t,f
02/27/97 <50 <50 <50 <50 <50 <50 i,t,f,sd
09/04/97 <50 <50 <50 <50 <50 <50 t,f
03/25/98 <50 <50 <50 <50 <50 <50 t
11/02/98 <50 <50 <50 <50 <50
04/27/99 <50 <50 <50 <50 <50 <50
11/22/99 <50 <50 <50 <50 <50 <50
05/24/00 <50 <50 <50 <50 <50 <50
11/30/00 <50 <50 <50 <50 <50 <50
05/30/01 <50 <50 <50 <50 <50 <50 i, f, t
11/14/01 <50 <50 <50 <50 <50 <50
06/06/02 <50 <50 <50 <50 <50 <50
03/13/03 <50 <50 <50 <50
06/19/03 <50 <50 <50 <50
12/09/03 <50 <50 <50 <50
06/23/04 <50 <50 <50 <50
12/01/04 <50 <50 <50 <50
06/06/05 <50 <50 <50 <50 <50
11/03/05 <50 <50 <50 <50 <50
05/24/06 <50 <50 <50 <50 <50
11/15/06 <50 <50 <50 <50 <50
06/14/07 1.6 JB 4.8 JB 4.7 JB 1 JB 3.6 JB 0.6 50 t, f
12/11/07 7 J 6.1 JB 2.4 JB 2.6 JB <0.6 0.6 50 t, i
06/09/08 3.9 J 2.8 J 1.8 J <0.6 1.9 J 0.6 50
11/06/08 4.3 JB 5.6 JB 10.9 JB 1.8 JB 3.8 JB 0.6 50 t, f
05/20/09 4.9 J 4.3 J 2.5 J 1.1 J 2.5 J 0.6 50
10/20/09 3.32 J 4.77 J 2.23 J 3.05 J 8.32 J 1.8 50
06/23/10 4.46 J 3.69 J <1.8 <1.8 <1.8 1.8 50
11/17/10 3.88 J 4.77 J 2.20 J <1.8 2.39 J 1.8 50
05/25/11 4.8 J 5.42 J 2.97 J <1.8 4.56 J 8.11 J 1.8 50
11/16/11 5.75 J 6.04 J <1.8 2.1 J 8.01 J 6.57 J 1.8 50
06/07/12 19.3 J 5.38 J 1.89 J <1.8 4.49 J 9.37 J 1.8 50
11/14/12 5.06 J 6.48 J <1.8 2.27 J 11.2 J 1.8 50
05/14/13 5.16 JB 5.42 JB 1.91 JB 1.96 JB 11.7 JB 1.8 50 i
11/13/13 3.03 J 4.56 J <1.80 <1.80 8.02 J 1.80 50
05/14/14 4.19 J 2.98 J <1.80 9.73 J 6.91 J 1.80 50
11/12/14 5.25 J 4.50 J <1.80 2.72 J 6.97 J 1.80 50
05/13/15 2.01 J 211 R 3.39 J 3.98 J 8.68 J 1.80/3.60 50
06/16/15 3.18 J 1.80 50 verification
11/10/15 3.99 J 4.35 J <1.80 3.62 J 5.88 J 1.80 50
05/18/16 <2.20 2.61 J <2.20 2.66 J 5.70 J 2.20 50
11/14/16 9.63 J 4.49 J <2.20 2.33 J 5.62 J 2.20 50
05/31/17 3.80 J 3.03 J <2.20 9.34 J 5.00 J 2.20 50
11/15/17 3.36 J 2.85 J <2.20 2.64 J 2.68 J 2.20 50
05/16/18 <2.20 <2.20 <2.20 2.39 J <2.20 2.20 50
11/13/18 3.36 J 2.55 J <2.20 8.61 J 4.52 J 2.20 10
05/21/19 5.86 J 4.34 J <2.20 7.55 J 4.74 J 2.20 10
11/20/19 4.23 J 4.92 J <2.20 3.26 J 5.09 J 2.20 10
05/20/20 2.65 J <2.20 <2.20 <2.20 2.20 10
11/18/20 5.36 J 2.54 J <2.20 2.31 J 2.20 10
05/18/21 4.86 J <2.20 <2.20 2.41 J 2.20 10
11/29/21 7.14 J 2.47 J <2.20 2.60 J 2.20 10
05/23/22 3.53 J <2.20 <2.20 2.98 J 2.20 10
11/08/22 3.9 J <3.3 <3.3 <3.3 3.30 40
05/07/23 <3.3 <3.3 <3.3 3.7 J 3.30 40
11/20/23 <5.0 <5.0 <5.0 6.5 5.0
Constituent Well / Date MW-101 MW-102S MW-102D MW-102DR MW-103D MW-103S MW-104 MW-105 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
selenium 05/18/95
MCL = 50 07/20/95
FBAC = 5.9 11/28/95
NCGQS = 20 (2L Std)02/28/96
2L Std = 50 (pre- Jan. 2010)08/27/96
2L Std = 20 (Jan. 2010)02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07
06/09/08
11/06/08
05/20/09 <3.4 3.4 J <3.4 6.5 J <3.4 <3.4 <3.4 3.4 10
10/20/09 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 2.7 10
06/23/10 <0.83 <0.83 <0.83 <0.83 <0.83 <0.83 <0.83 0.83 10
11/17/10 <0.83 <0.83 <0.83 <0.83 <0.83 <0.83 <0.83 0.83 10 i
05/25/11 <0.83 <0.83 <0.83 <0.83 <0.83 <0.83 <0.83 0.83 10
11/16/11 1.96 J <0.83 0.993 J <0.83 1.01 J <0.83 <0.83 0.83 10
06/07/12 <0.83 <0.83 <0.83 <0.83 <0.83 <0.83 <0.83 0.83 10
11/14/12 <0.83 0.927 J <0.83 <0.83 <0.83 <0.83 <0.83 0.83 10
05/14/13 <0.91 <0.91 <0.91 <0.91 <0.91 <0.91 <0.91 0.91 10
11/13/13 <0.910 <0.910 <0.910 <0.910 <0.910 <0.910 <0.910 0.910 10
05/14/14 <0.910 <0.910 <0.910 <0.910 <0.910 <0.910 <0.910 0.910 10
11/12/14 <0.910 <0.910 <0.910 <0.910 <0.910 <0.910 <0.910 0.910 10
05/13/15 <0.910 <0.910 <0.910 <0.910 <0.910 <0.910 <0.910 0.910 10
06/16/15 verification
11/10/15 <0.910 <0.910 <0.910 <0.910 <0.910 <0.910 <0.910 0.910 10
05/18/16 <0.910 <0.910 <0.910 1.08 J <0.910 <0.910 <0.910 0.910 10
11/14/16 <0.910 <0.910 <0.910 <0.910 <0.910 <0.910 <0.910 0.910 10
05/31/17 1.14 J <0.910 <0.910 <0.910 <0.910 <0.910 <0.910 0.910 10
11/15/17 <0.910 <0.910 <0.910 <0.910 <0.910 <0.910 <0.910 0.910 10
05/16/18 <4.55 <4.55 <4.55 <4.55 <4.55 <4.55 <4.55 4.550 10
11/13/18 <4.55 <4.55 <4.55 <4.55 <4.55 <4.55 <4.55 4.550 10
05/21/19 <1.82 <1.82 <1.82 <1.82 <1.82 <1.82 <1.82 1.82 2.0
11/20/19 <1.82 <1.82 <1.82 <1.82 <1.82 <1.82 <1.82 1.82 2.0
05/20/20 <1.82 <1.82 <1.82 <1.82 1.82 2.0
11/18/20 2.33 <1.82 <1.82 <1.82 1.82 2.0
05/18/21 <1.82 <1.82 <1.82 <1.82 1.82 2.0
11/23/21 <1.82 <1.82 <1.82 <1.82 1.82 2.0
05/23/22 <1.82 <1.82 <1.82 <1.82 1.82 2.0
11/08/22 <1.2 <1.2 <1.2 <1.2 1.2 2.5
05/07/23 <1.2 <1.2 <1.2 <1.2 1.2 2.5
11/20/23 <10.0 <10.0 <10.0 <10.0 10.0
Constituent Well / Date MW-106 MW-107 MW-108 MW-110D MW110S MW-111 MW-112 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
selenium 05/18/95
MCL = 50 07/20/95
FBAC = 5.9 11/28/95
NCGQS = 20 (2L Std)02/28/96
2L Std = 50 (pre- Jan. 2010)08/27/96
2L Std = 20 (Jan. 2010)02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07
06/09/08
11/06/08
05/20/09 <3.4 <3.4 5.9 J 5.0 J <3.4 3.4 10
10/20/09 <2.7 <2.7 <2.7 <2.7 <2.7 2.7 10
06/23/10 <0.83 <0.83 <0.83 <0.83 <0.83 0.83 10
11/17/10 <0.83 <0.83 <0.83 <0.83 <0.83 0.83 10 i
05/25/11 <0.83 <0.83 <0.83 <0.83 <0.83 <0.83 0.83 10
11/16/11 <0.83 <0.83 <0.83 <0.83 <0.83 <0.83 0.83 10
06/07/12 <0.83 <0.83 <0.83 <0.83 <0.83 <0.83 0.83 10
11/14/12 <0.83 <0.83 <0.83 <0.83 <0.83 0.83 10
05/14/13 <0.91 <0.91 <0.91 <0.91 <0.91 0.91 10
11/13/13 <0.910 <0.910 <0.910 <0.910 <0.910 0.910 10
05/14/14 <0.910 <0.910 <0.910 <0.910 <0.910 0.910 10
11/12/14 <0.910 <0.910 <0.910 <0.910 <0.910 0.910 10
05/13/15 <0.910 <0.910 <0.910 <0.910 <0.910 0.910 10
06/16/15
11/10/15 <0.910 <0.910 <0.910 <0.910 <0.910 0.910 10
05/18/16 <0.910 <0.910 <0.910 <0.910 <0.910 0.910 10
11/14/16 <0.910 <0.910 <0.910 <0.910 <0.910 0.910 10
05/31/17 <0.910 <0.910 <0.910 <0.910 <0.910 0.910 10
11/15/17 <0.910 <0.910 <0.910 <0.910 <0.910 0.910 10
05/16/18 <4.55 <4.55 <4.55 <4.55 <4.55 4.550 10
11/13/18 <4.55 <4.55 <4.55 <4.55 <4.55 4.550 10
05/21/19 <1.82 <1.82 <1.82 <1.82 <1.82 1.82 2.0
11/20/19 <1.82 <1.82 <1.82 <1.82 <1.82 1.82 2.0
05/20/20 <1.82 <1.82 <1.82 <1.82 1.82 2.0
11/18/20 <1.82 <1.82 <1.82 <1.82 1.82 2.0
05/18/21 <1.82 <1.82 <1.82 <1.82 1.82 2.0
11/29/21 <1.82 <1.82 <1.82 <1.82 1.82 2.0
05/23/22 <1.82 <1.82 <1.82 <1.82 1.82 2.0
11/08/22 <1.2 <1.2 <1.2 <1.2 1.20 2.5
05/07/23 <1.2 <1.2 <1.2 <1.2 1.20 2.5
11/20/23 <10.0 <10.0 <10.0 <10.0 10.0
Constituent Well / Date MW-101 MW-102S MW-102D MW-102DR MW-103D MW-103S MW-104 MW-105 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
silver 05/18/95 <10 <10 <10 <10 <10 <10 <10
FBAC = 2.13 07/20/95 <10 <10 <10 <10 <10 <10 <10
NCGQS = 20 (2L Std)11/28/95 <10 <10 <10 <10 <10 <10 <10
2L Std = 17.5 (pre- Jan. 2010)02/28/96 <10 <10 <10 <10 <10 <10 <10
2L Std = 20 (Jan. 2010)08/27/96 <10 <10 <10 <10 <10 <10 <10
02/27/97 <10 <10 <10 <10 <10 <10 <10
09/04/97 <10 <10 <10 <10 <10 <10 <10
03/25/98 <10 <10 <10 <10 <10 <10 <10 i,lc
11/02/98 <10 <10 <10 <10 <10 <10 <10 ics
04/27/99 <10 <10 <10 <10 <10 <10 <10 i
11/22/99 <10 <10 <10 <10 <10 <10 <10
05/24/00 <10 <10 <10 <10 <10 <10 <10 i,cc
11/30/00 <10 <10 <10 <10 <10 <10 <10
05/30/01 <10 <10 <10 <10 <10 <10 <10 i, f, t
11/14/01 <10 <10 <10 <10 <10 <10 <10
06/06/02 <10 <10 <10 <10 <10 <10 <10
03/13/03 <10 <10 <10 <10 <10 <10 <10
06/19/03 <10 <10 <10 <10 <10 <10 <10
12/09/03 <10 <10 <10 <10 <10 <10 <10
06/23/04 <10 <10 <10 <10 <10 <10 <10
12/01/04 <10 <10 <10 <10 <10 <10 <10
11/03/05 <10 <10 <10 <10 <10 <10 <10
05/24/06 <10 <10 <10 <10 <10 <10 <10
11/15/06 <10 <10 <10 <10 <10 <10 <10
06/14/07 <1.1 <1.1 <1.1 <1.1 <1.1 <1.1 <1.1 1.1 10 cc
12/11/07 <1.1 <1.1 <1.1 <1.1 <1.1 <1.1 <1.1 1.1 10
06/09/08 1.9 J <1.1 <1.1 <1.1 <1.1 <1.1 <1.1 1.1 10
11/06/08 <1.1 <1.1 <1.1 <1.1 <1.1 <1.1 2.5 JB 1.1 10 i
05/20/09 1.1 J <1 <1 1.0 J <1 <1 1.5 J 1 10
10/20/09 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10
06/23/10 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10
11/17/10 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10
05/25/11 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 2.23 J 1.9 10
11/16/11 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10
06/07/12 <1.9 <1.9 <1.9 2.09 J <1.9 <1.9 3.58 J 1.9 10
11/14/12 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10
05/14/13 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 2.82 JB 1.9 10 i
11/13/13 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 1.90 10
05/14/14 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 1.90 10
11/12/14 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 2.14 J 1.90 10
05/13/15 <1.90 <1.90 <1.90 <3.80 <1.90 <1.90 <1.90 1.90/3.80 10
06/16/15 verification
11/10/15 2.38 J <1.90 <1.90 2.77 J <1.90 <1.90 2.65 J 1.90 10
05/18/16 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 1.90 10
11/14/16 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 2.09 J 1.90 10
05/31/17 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 1.90 10
11/15/17 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 1.90 10
05/16/18 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 1.90 10
11/13/18 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 1.90 10
05/21/19 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 1.90 10
11/20/19 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 1.90 10
05/20/20 <1.90 <1.90 <1.90 <1.90 1.90 10
11/18/20 <1.90 <1.90 <1.90 <1.90 1.90 10
05/18/21 <1.90 <1.90 <1.90 <1.90 1.90 10
11/23/21 <1.90 <1.90 <1.90 <1.90 1.90 10
05/23/22 <1.90 <1.90 <1.90 <1.90 1.90 10
11/08/22 <1.5 <1.5 <1.5 <1.5 1.50 10
05/07/23 <1.5 <1.5 <1.5 <1.5 1.50 10
11/20/23 <5.0 <5.0 <5.0 <5.0 5.0
Constituent Well / Date MW-106 MW-107 MW-108 MW-110D MW110S MW-111 MW-112 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
silver 05/18/95 <10 <10 <10 <10 <10 <10
FBAC = 2.13 07/20/95 <10 <10 <10 <10 <10 <10
NCGQS = 20 (2L Std)11/28/95 <10 <10 <10 <10 <10 <10
2L Std = 17.5 (pre- Jan. 2010)02/28/96 <10 <10 <10 <10 <10 <10
2L Std = 20 (Jan. 2010)08/27/96 <10 <10 <10 <10 <10 <10
02/27/97 <10 <10 <10 <10 <10 <10
09/04/97 <10 <10 <10 <10 <10 <10
03/25/98 <10 <10 <10 14 B 10 B <10 i,lc
11/02/98 <10 <10 <10 <10 <10 ics
04/27/99 <10 <10 <10 <10 <10 <10 i
11/22/99 <10 <10 <10 <10 <10 <10
05/24/00 <10 <10 16 B <10 <10 <10 i,cc
11/30/00 <10 <10 <10 <10 <10 <10
05/30/01 <10 <10 <10 <10 <10 <10 i, f, t
11/14/01 <10 <10 <10 <10 <10 <10
06/06/02 <10 <10 <10 <10 <10 <10
03/13/03 <10 <10 <10 <10
06/19/03 <10 <10 <10 <10
12/09/03 <10 <10 <10 <10
06/23/04 <10 <10 <10 <10
12/01/04 <10 <10 <10 <10
11/03/05 <10 <10 <10 <10
05/24/06 <10 <10 <10 <10
11/15/06 <10 <10 <10 <10
06/14/07 <1.1 <1.1 <1.1 <1.1 <1.1 1.1 10 cc
12/11/07 <1.1 <1.1 <1.1 <1.1 <1.1 1.1 10
06/09/08 <1.1 <1.1 <1.1 <1.1 <1.1 1.1 10
11/06/08 <1.1 <1.1 <1.1 <1.1 <1.1 1.1 10 i
05/20/09 <1 1.0 J <1 <1 <1.0 1 10
10/20/09 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10
06/23/10 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10
11/17/10 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10
05/25/11 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10
11/16/11 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10
06/07/12 <1.9 <1.9 <1.9 <1.9 <1.9 2.4 J 1.9 10
11/14/12 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10
05/14/13 <1.9 <1.9 2.13 J <1.9 2.14 JB 1.9 10 i
11/13/13 <1.90 <1.90 <1.90 <1.90 <1.90 1.90 10
05/14/14 <1.90 <1.90 <1.90 <1.90 <1.90 1.90 10
11/12/14 <1.90 <1.90 <1.90 <1.90 <1.90 1.90 10
05/13/15 <1.90 180 R <1.90 <1.90 <1.90 1.90/3.80 10
06/16/15 <1.90 1.90 10 verification
11/10/15 <1.90 <1.90 <1.90 <1.90 2.53 J 1.90 10
05/18/16 <1.90 <1.90 <1.90 <1.90 <1.90 1.90 10
11/14/16 <1.90 <1.90 <1.90 <1.90 <1.90 1.90 10
05/31/17 <1.90 <1.90 <1.90 <1.90 <1.90 1.90 10
11/15/17 <1.90 <1.90 <1.90 <1.90 <1.90 1.90 10
05/16/18 <1.90 <1.90 <1.90 <1.90 <1.90 1.90 10
11/13/18 <1.90 <1.90 <1.90 <1.90 <1.90 1.90 10
05/21/19 <1.90 <1.90 <1.90 <1.90 <1.90 1.90 10
11/20/19 <1.90 <1.90 <1.90 <1.90 <1.90 1.90 10
05/20/20 <1.90 <1.90 <1.90 <1.90 1.90 10
11/18/20 <1.90 <1.90 <1.90 <1.90 1.90 10
05/18/21 <1.90 <1.90 <1.90 <1.90 1.90 10
11/29/21 <1.90 <1.90 <1.90 <1.90 1.90 10
05/23/22 <1.90 <1.90 <1.90 <1.90 1.90 10
11/08/22 <1.5 <1.5 <1.5 <1.5 1.50 10
05/07/23 <1.5 <1.5 <1.5 <1.5 1.50 10
11/20/23 <5.0 <5.0 <5.0 <5.0 5.0
Constituent Well / Date MW-101 MW-102S MW-102D MW-102DR MW-103D MW-103S MW-104 MW-105 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
thallium 05/18/95
MCL = 2 07/20/95
FBAC = 2.70 11/28/95
02/28/96
08/27/96
02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01 i, f, t
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/06/05
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07 <2.7 <2.7 3.4 JB <2.7 <2.7 <2.7 <2.7 2.7 5.5 f
06/09/08 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 2.7 5.5
11/06/08 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 2.7 5.5 i
05/20/09 <0.036 <0.036 <0.036 <0.036 <0.036 <0.036 <0.036 0.036 5.5 i
10/20/09 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5
06/23/10 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5
11/17/10 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5
05/25/11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5
11/16/11 0.726 JB <0.11 <0.11 <0.11 0.538 JB <0.11 <0.11 0.11 5.5 i
06/07/12 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5
11/14/12 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5
05/14/13 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5
11/13/13 <0.110 <0.110 <0.110 <0.110 <0.110 <0.110 <0.110 0.110 5.5
05/14/14 <0.110 <0.110 <0.110 <0.110 <0.110 <0.110 <0.110 0.110 5.5
11/12/14 <0.110 <0.110 <0.110 <0.110 <0.110 <0.110 <0.110 0.110 5.5
05/13/15 <0.110 <0.110 <0.110 <0.110 <0.110 <0.110 <0.110 0.110 5.5
06/16/15 verification
11/10/15 <0.110 <0.110 <0.110 <0.110 <0.110 <0.110 <0.110 0.110 5.5
05/18/16 <0.110 <0.110 <0.110 <0.110 <0.110 <0.110 <0.110 0.110 5.5
11/14/16 <0.110 0.128 J 0.110 <0.110 0.131 J <0.110 <0.110 0.110 5.5
05/31/17 0.266 J 0.306 J 0.290 J 0.223 J 0.472 J 0.210 J 0.174 J 0.110 5.5
11/15/17 0.459 J 0.415 J 0.408 J 0.177 J 0.410 J 0.172 J 0.257 J 0.110 5.5
05/16/18 <0.550 <0.550 <0.550 <0.550 <0.550 <0.550 <0.550 0.550 5.5
11/13/18 <0.550 <0.550 <0.550 <0.550 <0.550 <0.550 <0.550 0.550 5.5
05/21/19 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 0.220 2.0
11/20/19 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 0.220 2.0
05/20/20 <0.220 <0.220 <0.220 <0.220 0.220 2.0
11/18/20 <0.220 <0.220 <0.220 <0.220 0.220 2.0
05/18/21 <0.220 <0.220 <0.220 <0.220 0.220 2.0
11/23/21 <0.220 <0.220 <0.220 <0.220 0.220 2.0
05/23/22 <0.220 <0.220 <0.220 <0.220 0.220 2.0
11/08/22 <0.26 <0.26 <0.26 <0.26 0.26 1.0
05/07/23 <0.26 <0.26 <0.26 <0.26 0.26 1.0
11/20/23 <10.0 <10.0 <10.0 <10.0 10.0
Constituent Well / Date MW-106 MW-107 MW-108 MW-110D MW110S MW-111 MW-112 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
thallium 05/18/95
MCL = 2 07/20/95
FBAC = 2.70 11/28/95
02/28/96
08/27/96
02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/06/05
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07 <2.7 <2.7 <2.7 <2.7 5.2 JB 2.7 5.5 f
06/09/08 <2.7 <2.7 <2.7 <2.7 <2.7 2.7 5.5
11/06/08 <2.7 <2.7 4.7 JB <2.7 4.4 JB 2.7 5.5 i
05/20/09 <0.036 <0.036 <0.036 <0.036 <0.036 0.036 5.5 i
10/20/09 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5
06/23/10 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5
11/17/10 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5
05/25/11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5
11/16/11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5 i
06/07/12 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5
11/14/12 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5
05/14/13 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5
11/13/13 <0.110 <0.110 <0.110 <0.110 <0.110 0.110 5.5
05/14/14 <0.110 <0.110 <0.110 <0.110 <0.110 0.110 5.5
11/12/14 <0.110 <0.110 <0.110 <0.110 <0.110 0.110 5.5
05/13/15 <0.110 <0.110 <0.110 <0.110 <0.110 0.110 5.5
06/16/15
11/10/15 <0.110 <0.110 <0.110 <0.110 <0.110 0.110 5.5
05/18/16 <0.110 <0.110 <0.110 <0.110 <0.110 0.110 5.5
11/14/16 0.130 J <0.110 <0.110 <0.110 <0.110 0.110 5.5
05/31/17 0.209 J 0.122 J 0.117 J 0.190 J 0.133 J 0.110 5.5
11/15/17 0.264 J 0.175 J 0.135 J 0.238 J 0.216 J 0.110 5.5
05/16/18 <0.550 <0.550 <0.550 <0.550 <0.550 0.550 5.5
11/13/18 <0.550 <0.550 <0.550 <0.550 <0.550 0.550 5.0
05/21/19 <0.220 <0.220 <0.220 <0.220 <0.220 0.220 2.0
11/20/19 <0.220 <0.220 <0.220 <0.220 <0.220 0.220 2.0
05/20/20 <0.220 <0.220 <0.220 <0.220 0.220 2.0
11/18/20 <0.220 <0.220 <0.220 <0.220 0.220 2.0
05/18/21 <0.220 <0.220 <0.220 <0.220 0.220 2.0
11/29/21 <0.220 <0.220 <0.220 <0.220 0.220 2.0
05/23/22 <0.220 <0.220 <0.220 <0.220 0.220 2.0
11/08/22 0.66 J <0.26 <0.26 <0.26 0.26 1.0
05/07/23 <0.26 <0.220 <0.220 <0.26 0.26 1.0
11/20/23 <10.0 <10.0 <10.0 <10.0 10.0
Constituent Well / Date MW-101 MW-102S MW-102D MW-102DR MW-103D MW-103S MW-104 MW-105 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
tin 05/18/95
FBAC = 5.32 07/20/95
GWPS = 2100 (pre-Oct. 2010)11/28/95
GWPS = 2000 (Oct. 2010)02/28/96
08/27/96
02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/06/05
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07
06/09/08
11/06/08
05/20/09
10/20/09 5.95 J 3.52 J 6.37 J 7.68 J 4.06 J 4.37 J 2.86 J 2.1 100
06/23/10
11/17/10 2.70 J 2.1 100 i
05/25/11
11/16/11 2.62 J 2.1 100
06/07/12
11/14/12 3.47 J 2.1 100
05/14/13
11/13/13 <2.1 2.1 100
05/14/14
11/12/14 <2.10 2.10 100
05/13/15
06/16/15 verification
11/10/15 <2.40 2.40 100
05/18/16
11/14/16 <2.40 2.40 100
05/31/17
11/15/17 <2.40 2.40 100
05/16/18
11/13/18 <2.90 2.90 10
05/21/19
11/20/19 <2.90 2.90 10
05/20/20
11/18/20 <2.90 2.90 10
05/18/21
11/23/21 <2.90 2.90 10
05/23/22
11/09/22 <11 11 50
05/07/23
11/20/23
Constituent Well / Date MW-106 MW-107 MW-108 MW-110D MW110S MW-111 MW-112 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
tin 05/18/95
FBAC =5.32 07/20/95
GWPS = 2100 (pre-Oct. 2010)11/28/95
GWPS = 2000 (Oct. 2010)02/28/96
08/27/96
02/27/97
09/04/97
03/25/98
11/02/98
04/27/99
11/22/99
05/24/00
11/30/00
05/30/01
11/14/01
06/06/02
03/13/03
06/19/03
12/09/03
06/23/04
12/01/04
06/06/05
11/03/05
05/24/06
11/15/06
06/14/07
12/11/07
06/09/08
11/06/08
05/20/09
10/20/09 4.64 J <2.1 3.34 J <2.1 2.1 100
06/23/10
11/17/10 2.1 100 i
05/25/11
11/16/11 2.1 100
06/07/12
11/14/12 2.1 100
05/14/13
11/13/13 2.1 100
05/14/14
11/12/14 2.10 100
05/13/15
06/16/15
11/10/15 2.40 100
05/18/16
11/14/16 2.40 100
05/31/17
11/15/17 2.40 100
05/16/18
11/13/18 2.90 10
05/21/19
11/20/19 2.90 10
05/20/20
11/20/19 2.90 10
05/18/21
11/29/21 2.90 10
05/23/22
11/09/22 11 50
05/07/23 11 50
11/20/23
Constituent Well / Date MW-101 MW-102S MW-102D MW-102DR MW-103D MW-103S MW-104 MW-105 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
vanadium 05/18/95 285 <40 <40 <40 <40 <40 <40
FBAC = 6.968 07/20/95 <40 <40 <40 <40 <40 <40 <40
NCGQS = 0.3 (GWPS)11/28/95 55 <40 <40 <40 344 <40 <40
GWPS = 3.5 (pre-Oct. 2010)02/28/96 <40 <40 <40 <40 88 <40 <40 i,t,f,sd
GWPS = 0.3 (Oct. 2010)08/27/96 <40 <40 <40 <40 <40 <40 <40 i,t,f
02/27/97 <40 <40 <40 <40 <40 <40 <40
09/04/97 <40 <40 <40 <40 <40 <40 <40
03/25/98 <40 <40 <40 <40 54 <40 <40
11/02/98 <40 <40 <40 <40 <40 <40 <40 ics
04/27/99 <40 <40 <40 <40 <40 <40 <40
11/22/99 <40 <40 <40 <40 <40 <40 <40
05/24/00 <40 <40 <40 <40 <40 <40 <40
11/30/00 <40 <40 <40 <40 <40 <40 <40
05/30/01 <40 <40 <40 <40 <40 <40 <40 i, f, t
11/14/01 <40 <40 <40 <40 <40 <40 <40
06/06/02 <40 <40 <40 <40 <40 <40 <40
03/13/03 <40 <40 <40 <40 <40 <40 <40
06/19/03 <40 <40 <40 <40 <40 <40 <40
12/09/03 <40 <40 <40 <40 <40 <40 <40
06/23/04 <40 <40 <40 <40 <40 <40 <40
12/01/04 <40 <40 <40 <40 <40 <40 <40
06/06/05 <40 <40 <40 <40 <40 <40 <40
11/03/05 <40 <40 <40 <40 <40 <40 <40
05/24/06 <40 <40 <40 <40 <40 <40 <40
11/15/06 <40 <40 <40 <40 <40 <40 <40
06/14/07 1.1 J 0.4 J 0.7 J <0.4 <0.4 <0.4 <0.4 0.4 25
12/11/07 0.98 J 0.8 J <0.4 <0.4 <0.4 3.8 J <0.4 0.4 25
06/09/08 3 JB 2.3 JB 2.3 JB 0.9 JB 1 JB 1.3 JB 1 JB 0.4 25 t, f
11/06/08 4.1 JB 0.7 JB 1.5 JB <0.4 <0.4 <0.4 25 J 0.4 25 f
05/20/09 8.2 J <0.7 4.9 J <0.7 10.1 J <0.7 <0.7 0.7 25
10/20/09 41.4 <1.4 3.9 J <1.4 3.98 J <1.4 <1.4 1.4 25
verification event 11/20/09 30.4 1.4 25
verification event 12/17/09 77.7 1.4 25
06/23/10 2.14 J <1.4 2.65 J <1.4 5.83 J <1.4 <1.4 1.4 25
11/17/10 2.68 J <1.4 1.45 J <1.4 <1.4 <1.4 <1.4 1.4 25
05/25/11 4.05 J <1.4 1.74 J <1.4 1.71 J <1.4 <1.4 1.4 25
11/16/11 2.68 J <1.4 1.62 J <1.4 <1.4 <1.4 <1.4 1.4 25
06/07/12 6.11 J <1.4 <1.4 <1.4 <1.4 <1.4 <1.4 1.4 25
11/14/12 7.22 J <1.4 <1.4 <1.4 <1.4 <1.4 <1.4 1.4 25
05/14/13 <1.4 <1.4 <1.4 <1.4 10.6 J <1.4 <1.4 1.4 25
11/13/13 1.70 J <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 25
05/14/14 <1.40 <1.40 1.66 J <1.40 <1.40 <1.40 <1.40 1.40 25
11/12/14 10.1 J <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 25
05/13/15 4.40 J <1.40 <1.40 <2.80 <1.40 <1.40 <1.40 1.40/2.80 25
06/16/15 verification
11/10/15 <1.40 3.98 J <1.40 <1.40 <1.40 <1.40 <1.40 1.40 25
05/18/16 <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 25
11/14/16 <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 25
05/31/17 2.48 J <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 25
11/15/17 1.44 J <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 25
05/16/18 2.41 J <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 25
11/13/18 <1.40 2.39 J <1.40 <1.40 <1.40 <1.40 <1.40 1.40 10
12/17/18 0.24 1.0 verification
05/21/19 <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 10.0
07/10/19 1.40 10.0
11/20/19 3.50 J <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 10.0 verification
05/20/20 <1.40 <1.40 <1.40 <1.40 1.40 10.0
11/18/20 <1.40 <1.40 <1.40 <1.40 1.40 10.0
05/18/21 <1.40 <1.40 <1.40 <1.40 1.40 10.0
11/23/21 <1.40 <1.40 <1.40 <1.40 1.40 10.0
05/23/22 <1.40 <1.40 <1.40 <1.40 1.40 10.0
11/08/22 12 <1.0 <1.0 <1.0 1.0 10
05/07/23 1.1 J <1.0 <1.0 <1.0 1.0 10
11/20/23 <5.0 <5.0 <5.0 <5.0 5.0
Constituent Well / Date MW-106 MW-107 MW-108 MW-110D MW110S MW-111 MW-112 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
vanadium 05/18/95 <40 <40 <40 <40 <40 147
FBAC = 6.968 07/20/95 <40/<40 <40 <40 <40 <40 <40
NCGQS = 0.3 (GWPS)11/28/95 67 <40 81 261 <40 <40
GWPS = 3.5 (pre-Oct. 2010)02/28/96 <40 <40 <40 <40 <40 <40 i,t,f,sd
GWPS = 0.3 (Oct. 2010)08/27/96 <40 <40 <40 <40 <40 <40 i,t,f
02/27/97 <40 <40 <40 <40 <40 <40
09/04/97 <40 <40 <40 <40 <40 <40
03/25/98 <40 <40 <40 <40 <40 <40
11/02/98 <40 <40 <40 <40 <40 ics
04/27/99 <40 <40 <40 <40 <40 <40
11/22/99 <40 <40 <40 <40 <40 <40
05/24/00 <40 <40 <40 <40 <40 <40
11/30/00 <40 <40 <40 <40 <40 <40
05/30/01 <40 <40 <40 <40 <40 <40 i, f, t
11/14/01 <40 <40 <40 <40 <40 <40
06/06/02 <40 <40 <40 <40 <40 <40
03/13/03 <40 <40 <40 <40
06/19/03 <40 <40 <40 <40
12/09/03 <40 <40 <40 <40
06/23/04 <40 <40 <40 <40
12/01/04 <40 <40 <40 <40
06/06/05 <40 <40 <40 <40 <40
11/03/05 <40 <40 <40 <40 <40
05/24/06 <40 <40 <40 <40 <40
11/15/06 <40 <40 <40 <40 <40
06/14/07 <0.4 0.8 J <0.4 <0.4 <0.4 0.4 25
12/11/07 <0.4 <0.4 <0.4 <0.4 0.7 J 0.4 25
06/09/08 2 JB 5 J 1.9 JB <0.4 3.8 JB 0.4 25 t, f
11/06/08 0.6 JB 1 JB 1.4 JB <0.4 2.1 JB 0.4 25 f
05/20/09 3.7 J <0.7 1.0 J <0.7 3.2 J 0.7 25
10/20/09 6.28 J <1.4 2.19 J 5.2 J <1.4 1.4 25
verification event 11/20/09 1.4 25
verification event 12/17/09 1.4 25
06/23/10 2.79 J 1.71 J <1.4 <1.4 2.67 J 1.4 25
11/17/10 <1.4 1.72 J <1.4 <1.4 2.45 J 1.4 25
05/25/11 1.55 J 1.66 J 1.6 J <1.4 6.07 J <1.4 1.4 25
11/16/11 2 J 2.02 J <1.4 <1.4 12.2 J <1.4 1.4 25
06/07/12 <1.4 <1.4 <1.4 <1.4 5.08 J <1.4 1.4 25
11/14/12 <1.4 <1.4 <1.4 3.31 J <1.4 1.4 25
05/14/13 2.85 J <1.4 <1.4 <1.4 2.97 J 1.4 25
11/13/13 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 25
05/14/14 1.83 J <1.40 <1.40 20.1 J 1.52 J 1.40 25
11/12/14 1.69 J <1.40 <1.40 5.49 J <1.40 1.40 25
05/13/15 <1.40 197 R <1.40 5.72 J <1.40 1.40/2.80 25
06/16/15 <1.40 1.40 25 verification
11/10/15 2.55 J 5.21 J 1.51 J 6.31 J <1.40 1.40 25
05/18/16 <1.40 <1.40 <1.40 1.99 J <1.40 1.40 25
11/14/16 <1.40 1.52 J <1.40 1.44 J <1.40 1.40 25
05/31/17 2.16 J 1.54 J <1.40 15.9 J 2.00 J 1.40 25
11/15/17 <1.40 <1.40 <1.40 4.07 J <1.40 1.40 25
05/16/18 3.40 J 2.83 J <1.40 4.09 J <1.40 1.40 25
11/13/18 2.56 J 2.30 J <1.40 13.7 R <1.40 1.40 10 R - unreliable
12/17/18 1.8 0.24 1.0 verification
05/21/19 1.90 J 1.66 J <1.40 10.1 R <1.40 1.40 10.0 R - unreliable
07/10/19 2.27 J <1.40 1.40 10.0 verification
11/20/19 <1.40 <1.40 <1.40 2.51 J <1.40 1.40 10.0 verification
05/20/20 <1.40 <1.40 <1.40 1.42 J 1.40 10.0
11/18/20 <1.40 <1.40 <1.40 1.76 J 1.40 10.0
05/18/21 <1.40 <1.40 <1.40 2.38 J 1.40 10.0
11/29/21 <1.40 <1.40 <1.40 1.68 J 1.40 10.0
05/23/22 1.42 J 3.72 J <1.40 2.01 J 1.40 10.0
11/08/22 <1.0 <1.0 <1.0 1.9 J 1.0 10
05/07/23 <1.0 1.2 J <1.0 3.4 J 1.0 10
11/20/23 <5.0 <5.0 <5.0 7.6 5.0
Constituent Well / Date MW-101 MW-102S MW-102D MW-102DR MW-103D MW-103S MW-104 MW-105 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
zinc 05/18/95 282 J <50 <50 <50 <50 <50 <50 i,f,t,ms,sd
FBAC = 22.83 07/20/95 79 B <50 <50 <50 <50 <50 <50 i,f,t
NCGQS = 1000 (2L Std)11/28/95 71 B 208 B 73 B 88 B 520 B <50 <50 i,f,t
2L Std = 1050 (pre- Jan. 2010)02/28/96 <50 68 <50 <50 165 J <50 <50 i,t,sd
2L Std = 1000 (Jan. 2010)08/27/96 <50 <50 <50 <50 53 B <50 <50 i,t,f,ms
02/27/97 89 B <50 126 B 79 B 78 B 103 B 65 B i,t,f,sd
09/04/97 <50 80 B <50 <50 <50 225 B <50 t,f,sd
03/25/98 <50 <50 <50 <50 115 B <50 <50 i,t,f
11/02/98 <50 <50 <50 <50 <50 <50 <50 i,t,lcs
04/27/99 <50 <50 <50 <50 <50 <50 <50 i,t,f
11/22/99 <50 <50 81 B <50 <50 <50 50 B i,t,f,q
05/24/00 <50 <50 <50 <50 <50 <50 86 B cc,i,t,f
11/30/00 <50 <50 <50 <50 <50 <50 <50
05/30/01 <50 80 B <50 <50 <50 <50 <50 i,t,f
11/14/01 <50 <50 <50 <50 <50 <50 <50 i,t,f
06/06/02 <50 <50 <50 <50 <50 <50 <50 t,f
03/13/03 <50 <50 <50 <50 <50 <50 <50
06/19/03 <50 <50 <50 <50 <50 <50 <50
12/09/03 <50 <50 <50 <50 <50 <50 <50
06/23/04 <50 <50 <50 <50 <50 <50 <50
12/01/04 <50 <50 <50 <50 <50 <50 <50
06/06/05 <50 <50 <50 <50 <50 81 <50
11/03/05 <50 <50 <50 <50 <50 <50 <50
05/24/06 <50 <50 <50 <50 <50 <50 <50
11/15/06 <50 <50 <50 <50 <50 <50 <50
06/14/07 6.1 JB 5.4 JB 3.4 JB 3.1 JB 18.7 18.8 8.5 JB 2.7 10 t, f
12/11/07 10.3 B 46 7.6 JB 65 56.8 30.9 B 13.5 B 2.7 10 t, i
06/09/08 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 2.7 10
11/06/08 14.6 B <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 2.7 10 i
05/20/09 18.1 <3.4 <3.4 <3.4 16.4 <3.4 <3.4 3.4 10
10/20/09 24.6 <3.8 <3.8 <3.8 <3.8 <3.8 <3.8 3.8 10
06/23/10 19.6 4.85 J 4.58 J 4.84 J 12 <3.8 <3.8 3.8 10
11/17/10 21.7 5.58 J <3.8 <3.8 <3.8 <3.8 <3.8 3.8 10
05/25/11 13.4 4.78 J <3.8 <3.8 <3.8 <3.8 <3.8 3.8 10
11/16/11 6.2 J <3.8 <3.8 <3.8 <3.8 <3.8 3.87 J 3.8 10
06/07/12 5.78 J <3.8 <3.8 <3.8 5.15 J <3.8 <3.8 3.8 10
11/14/12 11.2 <3.8 <3.8 <3.8 <3.8 <3.8 4.13 J 3.8 10
05/14/13 5.88 J <3.8 <3.8 <3.8 7.33 J <3.8 <3.8 3.8 10
11/13/13 3.87 J 4.15 J <3.80 <3.80 <3.80 <3.80 4.09 J 3.80 10
05/14/14 <3.80 <3.80 <3.80 <3.80 <3.80 <3.80 <3.80 3.80 10
11/12/14 9.29 J 4.03 J <3.80 4.39 J <3.80 4.03 J 4.12 J 3.80 10
05/13/15 4.21 J <3.80 <3.80 <7.60 <3.80 <3.80 <3.80 3.80/7.60 10
06/16/15 verification
11/10/15 <3.80 <3.80 <3.80 <3.80 <3.80 <3.80 <3.80 3.80 10
05/18/16 <4.40 <4.40 <4.40 <4.40 <4.40 <4.40 <4.40 4.40 10
11/14/16 <4.40 <4.40 <4.40 <4.40 <4.40 <4.40 <4.40 4.40 10
05/31/17 <4.40 <4.40 <4.40 <4.40 <4.40 <4.40 <4.40 4.40 10
11/15/17 <4.40 <4.40 <4.40 <4.40 <4.40 <4.40 <4.40 4.40 10
05/16/18 <4.40 <4.40 <4.40 <4.40 <4.40 <4.40 <4.40 4.40 10
11/13/18 <4.40 <4.40 <4.40 <4.40 <4.40 <4.40 <4.40 4.40 10
05/21/19 <4.40 <4.40 <4.40 <4.40 <4.40 <4.40 <4.40 4.40 10
11/20/19 5.45 J <4.40 <4.40 5.05 J <4.40 <4.40 4.95 J 4.40 10
05/20/20 <4.40 <4.40 <4.40 <4.40 4.40 10
11/18/20 <4.40 <4.40 <4.40 <4.40 4.40 10
05/18/21 <4.40 <4.40 <4.40 <4.40 4.40 10
11/23/21 5.74 J <4.40 <4.40 <4.40 4.40 10
05/23/22 8.07 J <4.40 <4.40 <4.40 4.40 10
11/08/22 <8.7 <8.7 <8.7 <8.7 8.70 20
05/07/23 <8.7 <8.7 <8.7 <8.7 8.70 20
11/20/23 24.9 <10.0 <10.0 <10.0 10.0
Constituent Well / Date MW-106 MW-107 MW-108 MW-110D MW110S MW-111 MW-112 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
zinc 05/18/95 <50 <50 243 J <50 72 B 86 B i,f,t,ms,sd
FBAC = 22.83 07/20/95 64 B/<50 <50 <50 69 B 64 B <50 i,f,t
NCGQS = 1000 (2L Std)11/28/95 126 B 79 B 176 B 628 B 117 B 50 B i,f,t
2L Std = 1050 (pre- Jan. 2010)02/28/96 61 <50 <50 66 120 J 70 i,t,sd
2L Std = 1000 (Jan. 2010)08/27/96 56 B <50 <50 <50 <50 <50 i,t,f,ms
02/27/97 80 B <50 59 B 80 B 90 B 94 B i,t,f,sd
09/04/97 <50 <50 54 B 65 B 105 B <50 t,f,sd
03/25/98 54 B 55 B 51 B <50 316 B 52 B i,t,f
11/02/98 <50 <50 55 B <50 <50 i,t,lcs
04/27/99 <50 <50 <50 <50 <50 <50 i,t,f
11/22/99 <50 58 B 137 B 52 B 75 B 50 B i,t,f,q
05/24/00 <50 63 B <50 53 B <50 <50 cc,i,t,f
11/30/00 <50 <50 <50 <50 <50 <50
05/30/01 <50 <50 <50 55 B 158 B 52 B i,t,f
11/14/01 <50 <50 <50 <50 <50 <50 i,t,f
06/06/02 <50 <50 <50 <50 <50 <50 t,f
03/13/03 <50 <50 <50 <50
06/19/03 <50 <50 <50 <50
12/09/03 <50 <50 <50 <50
06/23/04 <50 <50 <50 <50
12/01/04 <50 <50 <50 <50
06/06/05 <50 <50 <50 <50 <50
11/03/05 <50 <50 <50 <50 <50
05/24/06 <50 <50 <50 <50 <50
11/15/06 <50 <50 <50 <50 <50
06/14/07 5.5 JB 35.6 20.7 14.8 B <2.7 2.7 10 t, f
12/11/07 28.2 B 17 B 12.4 B 17.2 B 13.2 B 2.7 10 t, i
06/09/08 <2.7 13.4 <2.7 <2.7 <2.7 2.7 10
11/06/08 <2.7 <2.7 13.2 B <2.7 <2.7 2.7 10 i
05/20/09 22.8 <3.4 4.8 J <3.4 <3.4 3.4 10
10/20/09 5.29 J 4.07 J 5.69 J 4.9 J 5.83 J 3.8 10
06/23/10 16 10.9 4.9 J 6.9 J 14.1 3.8 10
11/17/10 6.13 J 14 4.47 J 3.83 J 4 J 3.8 10
05/25/11 8.94 J 3.94 J 4.88 J 4.01 J 8.68 J <3.8 3.8 10
11/16/11 <3.8 12.4 <3.8 4.42 J 5.08 J <3.8 3.8 10
06/07/12 10.6 <3.8 <3.8 <3.8 <3.8 <3.8 3.8 10
11/14/12 5.41 J 8.68 J <3.8 <3.8 4.91 J 3.8 10
05/14/13 5.5 J <3.8 <3.8 <3.8 <3.8 3.8 10
11/13/13 <3.80 9.08 J 4.06 J 7.82 J <3.80 3.80 10
05/14/14 <3.80 <3.80 <3.80 6.17 J <3.80 3.80 10
11/12/14 5.82 J 4.60 J 10.8 27.8 4.30 J 3.80 10
05/13/15 <3.80 218 R 4.16 J 3.84 J <3.80 3.80/7.60 10
06/16/15 <3.80 3.80 10 verification
11/10/15 <3.80 <3.80 <3.80 <3.80 <3.80 3.80 10
05/18/16 <4.40 <4.40 <4.40 <4.40 <4.40 4.40 10
11/14/16 <4.40 <4.40 <4.40 <4.40 <4.40 4.40 10
05/31/17 <4.40 <4.40 <4.40 4.46 J 17.1 4.40 10
11/15/17 <4.40 <4.40 <4.40 <4.40 <4.40 4.40 10
05/16/18 4.68 J <4.40 <4.40 <4.40 <4.40 4.40 10
11/13/18 5.16 J <4.40 <4.40 4.54 J <4.40 4.40 10
05/21/19 <4.40 <4.40 <4.40 <4.40 <4.40 4.40 10
11/20/19 <4.40 5.01 J 4.78 J <4.40 <4.40 4.40 10
05/20/20 <4.40 <4.40 <4.40 <4.40 4.40 10
11/18/20 <4.40 <4.40 <4.40 <4.40 4.40 10
05/18/21 <4.40 <4.40 <4.40 <4.40 4.40 10
11/29/21 <4.40 <4.40 <4.40 <4.40 4.40 10
05/23/22 7.17 J <4.40 4.79 J <4.40 4.40 10
11/08/22 <8.7 <8.7 <8.7 18 J 8.7 20
05/07/23 <8.7 <8.7 <8.7 <8.7 8.7 20
11/20/23 <10.0 <10.0 <10.0 <10.0 10.0
Constituent Well / Date MW-101 MW-102S MW-102D MW-102DR MW-103D MW-103S MW-104 MW-105 MDL MRL QA/QC
HISTORY OF CHEMICAL ANALYSIS
INORGANIC CONSTITUENTS: TOTAL METALS
CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT
FACILITY: SOUTH FACILITY
LOCATION: CHAPEL HILL, NORTH CAROLINA
PROJECT: GROUNDWATER MONITORING PROGRAM
All results in µg/L.
Empty cells indicate data not available.
Upgradient wells not shaded.
Blue bolded values indicate concentrations that exceeded the FBAC.
Red bolded values indicate concentrations that exceeded the NCGQS.
Green bolded cells indicate concentrations that were >LOD but <SWSL.
B - detect associated with blank contamination J - concentration is estimated
i - found in instrument blank t - found in trip blank
f - found in field blank ic - initial calibration beyond limits
cc - continuing calibration beyond limits d - duplicates beyond limits
ss - surrogate spikes beyond limits is - internal standard beyond limits
sd - serial dilution beyond limits ms - matrix spike beyond limits
ics - interference check sample beyond limits lcs – laboratory control sample beyond limits
q – reporting limit standard beyond limits msd - matrix spike duplicate beyond limits
FBAC – facility background NCGQS - Groundwater Standard, as established by the NCDEQ
SWSL - solid waste section limit, as established by NCDEQ SPL – statistical prediction limit
GWPS - ground water protection standard SWSL eliminated in 2019 and replaced with Method Reporting Limit

Groundwater Monitoring Program March, 2024 Results of Sampling and Analysis Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01

Attachment 7: Laboratory Certificates of Analysis, Chains of Custody Quality Control Information

Groundwater Monitoring Program March, 2024 Results of Sampling and Analysis Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01

Attachment 7: South Monitoring Wells
#=CL#
December 06, 2023
LIMS USE: FR - DEBORAH COAKLEY
LIMS OBJECT ID: 92700176
92700176
Project:
Pace Project No.:
RE:
Deborah Ann Coakley
TRC Companies
1030 Wilmer Ave.
Suite 100
Richmond, VA 23227
OCSWM FALL-SOUTH
Dear Deborah Coakley:
Enclosed are the analytical results for sample(s) received by the laboratory on November 22, 2023. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Matthew Brainard
[e-mail]
Project Manager
704-977-0942
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 32
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 32
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92700176001 6801-MW101 EPA 6010D 15 PASI-ADBB1
EPA 8260D 50 PASI-CLMB
EPA 8260D Mod.3 PASI-CTEG
92700176002 6801-MW102S EPA 6010D 15 PASI-ADBB1
EPA 8260D 50 PASI-CLMB
EPA 8260D Mod.3 PASI-CTEG
92700176003 6801-MW104 EPA 6010D 15 PASI-ADBB1
EPA 8260D 50 PASI-CLMB
EPA 8260D Mod.3 PASI-CTEG
92700176004 6801-MW111 EPA 6010D 15 PASI-ADBB1
EPA 8260D 50 PASI-CLMB
EPA 8260D Mod.3 PASI-CTEG
92700176005 TRIP BLANK 1 EPA 8260D 50 PASI-CLMB
92700176006 TRIP BLANK 2 EPA 8260D 50 PASI-CLMB
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Sample: 6801-MW101 Lab ID: 92700176001 Collected: 11/21/23 12:55 Received: 11/22/23 12:18 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services - Asheville
6010 MET ICP
Antimony ND ug/L 12/04/23 21:33 7440-36-011/28/23 12:305.0 1
Arsenic ND ug/L 12/04/23 21:33 7440-38-211/28/23 12:3010.0 1
Barium 15.5 ug/L 12/04/23 21:33 7440-39-311/28/23 12:305.0 1
Beryllium ND ug/L 12/04/23 21:33 7440-41-711/28/23 12:301.0 1
Cadmium ND ug/L 12/04/23 21:33 7440-43-911/28/23 12:301.0 1
Chromium ND ug/L 12/04/23 21:33 7440-47-311/28/23 12:305.0 1
Cobalt ND ug/L 12/04/23 21:33 7440-48-411/28/23 12:305.0 1
Copper 15.6 ug/L 12/04/23 21:33 7440-50-811/28/23 12:305.0 1
Lead ND ug/L 12/04/23 21:33 7439-92-111/28/23 12:305.0 1
Nickel 5.5 ug/L 12/04/23 21:33 7440-02-011/28/23 12:305.0 1
Selenium ND ug/L 12/04/23 21:33 7782-49-211/28/23 12:3010.0 1
Silver ND ug/L 12/04/23 21:33 7440-22-411/28/23 12:305.0 1
Thallium ND ug/L 12/04/23 21:33 7440-28-011/28/23 12:3010.0 1
Vanadium ND ug/L 12/04/23 21:33 7440-62-211/28/23 12:305.0 1
Zinc 24.9 ug/L 12/04/23 21:33 7440-66-611/28/23 12:3010.0 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 11/30/23 16:25 67-64-125.0 1
Acrylonitrile ND ug/L 11/30/23 16:25 107-13-110.0 1
Benzene ND ug/L 11/30/23 16:25 71-43-21.0 1
Bromochloromethane ND ug/L 11/30/23 16:25 74-97-51.0 1
Bromodichloromethane ND ug/L 11/30/23 16:25 75-27-41.0 1
Bromoform ND ug/L 11/30/23 16:25 75-25-21.0 1
Bromomethane ND ug/L 11/30/23 16:25 74-83-9 v22.0 1
2-Butanone (MEK)ND ug/L 11/30/23 16:25 78-93-35.0 1
Carbon disulfide ND ug/L 11/30/23 16:25 75-15-02.0 1
Carbon tetrachloride ND ug/L 11/30/23 16:25 56-23-51.0 1
Chlorobenzene ND ug/L 11/30/23 16:25 108-90-71.0 1
Chloroethane ND ug/L 11/30/23 16:25 75-00-31.0 1
Chloroform ND ug/L 11/30/23 16:25 67-66-31.0 1
Chloromethane ND ug/L 11/30/23 16:25 74-87-31.0 1
Dibromochloromethane ND ug/L 11/30/23 16:25 124-48-11.0 1
Dibromomethane ND ug/L 11/30/23 16:25 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 11/30/23 16:25 95-50-11.0 1
1,4-Dichlorobenzene ND ug/L 11/30/23 16:25 106-46-71.0 1
trans-1,4-Dichloro-2-butene ND ug/L 11/30/23 16:25 110-57-61.0 1
1,1-Dichloroethane ND ug/L 11/30/23 16:25 75-34-31.0 1
1,2-Dichloroethane ND ug/L 11/30/23 16:25 107-06-21.0 1
1,1-Dichloroethene ND ug/L 11/30/23 16:25 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 11/30/23 16:25 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 11/30/23 16:25 156-60-51.0 1
1,2-Dichloropropane ND ug/L 11/30/23 16:25 78-87-51.0 1
cis-1,3-Dichloropropene ND ug/L 11/30/23 16:25 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 11/30/23 16:25 10061-02-61.0 1
Ethylbenzene ND ug/L 11/30/23 16:25 100-41-41.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Sample: 6801-MW101 Lab ID: 92700176001 Collected: 11/21/23 12:55 Received: 11/22/23 12:18 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
2-Hexanone ND ug/L 11/30/23 16:25 591-78-65.0 1
Iodomethane ND ug/L 11/30/23 16:25 74-88-4 v220.0 1
Methylene Chloride ND ug/L 11/30/23 16:25 75-09-25.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/30/23 16:25 108-10-15.0 1
Styrene ND ug/L 11/30/23 16:25 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 11/30/23 16:25 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 11/30/23 16:25 79-34-51.0 1
Tetrachloroethene ND ug/L 11/30/23 16:25 127-18-41.0 1
Toluene ND ug/L 11/30/23 16:25 108-88-31.0 1
1,1,1-Trichloroethane ND ug/L 11/30/23 16:25 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 11/30/23 16:25 79-00-51.0 1
Trichloroethene ND ug/L 11/30/23 16:25 79-01-61.0 1
Trichlorofluoromethane ND ug/L 11/30/23 16:25 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 11/30/23 16:25 96-18-41.0 1
Vinyl acetate ND ug/L 11/30/23 16:25 108-05-42.0 1
Vinyl chloride ND ug/L 11/30/23 16:25 75-01-41.0 1
Xylene (Total)ND ug/L 11/30/23 16:25 1330-20-71.0 1
m&p-Xylene ND ug/L 11/30/23 16:25 179601-23-12.0 1
o-Xylene ND ug/L 11/30/23 16:25 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)99 %11/30/23 16:25 460-00-470-130 1
1,2-Dichloroethane-d4 (S)93 %11/30/23 16:25 17060-07-070-130 1
Toluene-d8 (S)96 %11/30/23 16:25 2037-26-570-130 1
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
8260D MSV SIM
1,4-Dioxane (p-Dioxane)ND ug/L 11/23/23 02:32 123-91-12.0 1
Surrogates
1,2-Dichloroethane-d4 (S)88 %11/23/23 02:32 17060-07-067-130 1
Toluene-d8 (S)91 %11/23/23 02:32 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Sample: 6801-MW102S Lab ID: 92700176002 Collected: 11/21/23 13:25 Received: 11/22/23 12:18 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services - Asheville
6010 MET ICP
Antimony ND ug/L 12/04/23 21:36 7440-36-011/28/23 12:305.0 1
Arsenic ND ug/L 12/04/23 21:36 7440-38-211/28/23 12:3010.0 1
Barium 23.5 ug/L 12/04/23 21:36 7440-39-311/28/23 12:305.0 1
Beryllium ND ug/L 12/04/23 21:36 7440-41-711/28/23 12:301.0 1
Cadmium ND ug/L 12/04/23 21:36 7440-43-911/28/23 12:301.0 1
Chromium ND ug/L 12/04/23 21:36 7440-47-311/28/23 12:305.0 1
Cobalt ND ug/L 12/04/23 21:36 7440-48-411/28/23 12:305.0 1
Copper ND ug/L 12/04/23 21:36 7440-50-811/28/23 12:305.0 1
Lead ND ug/L 12/04/23 21:36 7439-92-111/28/23 12:305.0 1
Nickel ND ug/L 12/04/23 21:36 7440-02-011/28/23 12:305.0 1
Selenium ND ug/L 12/04/23 21:36 7782-49-211/28/23 12:3010.0 1
Silver ND ug/L 12/04/23 21:36 7440-22-411/28/23 12:305.0 1
Thallium ND ug/L 12/04/23 21:36 7440-28-011/28/23 12:3010.0 1
Vanadium ND ug/L 12/04/23 21:36 7440-62-211/28/23 12:305.0 1
Zinc ND ug/L 12/04/23 21:36 7440-66-611/28/23 12:3010.0 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 11/30/23 16:43 67-64-125.0 1
Acrylonitrile ND ug/L 11/30/23 16:43 107-13-110.0 1
Benzene ND ug/L 11/30/23 16:43 71-43-21.0 1
Bromochloromethane ND ug/L 11/30/23 16:43 74-97-51.0 1
Bromodichloromethane ND ug/L 11/30/23 16:43 75-27-41.0 1
Bromoform ND ug/L 11/30/23 16:43 75-25-21.0 1
Bromomethane ND ug/L 11/30/23 16:43 74-83-9 v22.0 1
2-Butanone (MEK)ND ug/L 11/30/23 16:43 78-93-35.0 1
Carbon disulfide ND ug/L 11/30/23 16:43 75-15-02.0 1
Carbon tetrachloride ND ug/L 11/30/23 16:43 56-23-51.0 1
Chlorobenzene ND ug/L 11/30/23 16:43 108-90-71.0 1
Chloroethane ND ug/L 11/30/23 16:43 75-00-31.0 1
Chloroform ND ug/L 11/30/23 16:43 67-66-31.0 1
Chloromethane ND ug/L 11/30/23 16:43 74-87-31.0 1
Dibromochloromethane ND ug/L 11/30/23 16:43 124-48-11.0 1
Dibromomethane ND ug/L 11/30/23 16:43 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 11/30/23 16:43 95-50-11.0 1
1,4-Dichlorobenzene ND ug/L 11/30/23 16:43 106-46-71.0 1
trans-1,4-Dichloro-2-butene ND ug/L 11/30/23 16:43 110-57-61.0 1
1,1-Dichloroethane ND ug/L 11/30/23 16:43 75-34-31.0 1
1,2-Dichloroethane ND ug/L 11/30/23 16:43 107-06-21.0 1
1,1-Dichloroethene ND ug/L 11/30/23 16:43 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 11/30/23 16:43 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 11/30/23 16:43 156-60-51.0 1
1,2-Dichloropropane ND ug/L 11/30/23 16:43 78-87-51.0 1
cis-1,3-Dichloropropene ND ug/L 11/30/23 16:43 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 11/30/23 16:43 10061-02-61.0 1
Ethylbenzene ND ug/L 11/30/23 16:43 100-41-41.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Sample: 6801-MW102S Lab ID: 92700176002 Collected: 11/21/23 13:25 Received: 11/22/23 12:18 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
2-Hexanone ND ug/L 11/30/23 16:43 591-78-65.0 1
Iodomethane ND ug/L 11/30/23 16:43 74-88-4 v220.0 1
Methylene Chloride ND ug/L 11/30/23 16:43 75-09-25.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/30/23 16:43 108-10-15.0 1
Styrene ND ug/L 11/30/23 16:43 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 11/30/23 16:43 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 11/30/23 16:43 79-34-51.0 1
Tetrachloroethene ND ug/L 11/30/23 16:43 127-18-41.0 1
Toluene ND ug/L 11/30/23 16:43 108-88-31.0 1
1,1,1-Trichloroethane ND ug/L 11/30/23 16:43 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 11/30/23 16:43 79-00-51.0 1
Trichloroethene ND ug/L 11/30/23 16:43 79-01-61.0 1
Trichlorofluoromethane ND ug/L 11/30/23 16:43 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 11/30/23 16:43 96-18-41.0 1
Vinyl acetate ND ug/L 11/30/23 16:43 108-05-42.0 1
Vinyl chloride ND ug/L 11/30/23 16:43 75-01-41.0 1
Xylene (Total)ND ug/L 11/30/23 16:43 1330-20-71.0 1
m&p-Xylene ND ug/L 11/30/23 16:43 179601-23-12.0 1
o-Xylene ND ug/L 11/30/23 16:43 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)102 %11/30/23 16:43 460-00-470-130 1
1,2-Dichloroethane-d4 (S)93 %11/30/23 16:43 17060-07-070-130 1
Toluene-d8 (S)98 %11/30/23 16:43 2037-26-570-130 1
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
8260D MSV SIM
1,4-Dioxane (p-Dioxane)ND ug/L 11/23/23 02:53 123-91-12.0 1
Surrogates
1,2-Dichloroethane-d4 (S)87 %11/23/23 02:53 17060-07-067-130 1
Toluene-d8 (S)91 %11/23/23 02:53 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Sample: 6801-MW104 Lab ID: 92700176003 Collected: 11/21/23 14:00 Received: 11/22/23 12:18 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services - Asheville
6010 MET ICP
Antimony ND ug/L 12/04/23 21:39 7440-36-011/28/23 12:305.0 1
Arsenic ND ug/L 12/04/23 21:39 7440-38-211/28/23 12:3010.0 1
Barium ND ug/L 12/04/23 21:39 7440-39-311/28/23 12:305.0 1
Beryllium ND ug/L 12/04/23 21:39 7440-41-711/28/23 12:301.0 1
Cadmium ND ug/L 12/04/23 21:39 7440-43-911/28/23 12:301.0 1
Chromium ND ug/L 12/04/23 21:39 7440-47-311/28/23 12:305.0 1
Cobalt ND ug/L 12/04/23 21:39 7440-48-411/28/23 12:305.0 1
Copper ND ug/L 12/04/23 21:39 7440-50-811/28/23 12:305.0 1
Lead ND ug/L 12/04/23 21:39 7439-92-111/28/23 12:305.0 1
Nickel ND ug/L 12/04/23 21:39 7440-02-011/28/23 12:305.0 1
Selenium ND ug/L 12/04/23 21:39 7782-49-211/28/23 12:3010.0 1
Silver ND ug/L 12/04/23 21:39 7440-22-411/28/23 12:305.0 1
Thallium ND ug/L 12/04/23 21:39 7440-28-011/28/23 12:3010.0 1
Vanadium ND ug/L 12/04/23 21:39 7440-62-211/28/23 12:305.0 1
Zinc ND ug/L 12/04/23 21:39 7440-66-611/28/23 12:3010.0 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 11/30/23 17:01 67-64-125.0 1
Acrylonitrile ND ug/L 11/30/23 17:01 107-13-110.0 1
Benzene ND ug/L 11/30/23 17:01 71-43-21.0 1
Bromochloromethane ND ug/L 11/30/23 17:01 74-97-51.0 1
Bromodichloromethane ND ug/L 11/30/23 17:01 75-27-41.0 1
Bromoform ND ug/L 11/30/23 17:01 75-25-21.0 1
Bromomethane ND ug/L 11/30/23 17:01 74-83-9 v22.0 1
2-Butanone (MEK)ND ug/L 11/30/23 17:01 78-93-35.0 1
Carbon disulfide ND ug/L 11/30/23 17:01 75-15-02.0 1
Carbon tetrachloride ND ug/L 11/30/23 17:01 56-23-51.0 1
Chlorobenzene ND ug/L 11/30/23 17:01 108-90-71.0 1
Chloroethane ND ug/L 11/30/23 17:01 75-00-31.0 1
Chloroform ND ug/L 11/30/23 17:01 67-66-31.0 1
Chloromethane ND ug/L 11/30/23 17:01 74-87-31.0 1
Dibromochloromethane ND ug/L 11/30/23 17:01 124-48-11.0 1
Dibromomethane ND ug/L 11/30/23 17:01 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 11/30/23 17:01 95-50-11.0 1
1,4-Dichlorobenzene ND ug/L 11/30/23 17:01 106-46-71.0 1
trans-1,4-Dichloro-2-butene ND ug/L 11/30/23 17:01 110-57-61.0 1
1,1-Dichloroethane ND ug/L 11/30/23 17:01 75-34-31.0 1
1,2-Dichloroethane ND ug/L 11/30/23 17:01 107-06-21.0 1
1,1-Dichloroethene ND ug/L 11/30/23 17:01 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 11/30/23 17:01 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 11/30/23 17:01 156-60-51.0 1
1,2-Dichloropropane ND ug/L 11/30/23 17:01 78-87-51.0 1
cis-1,3-Dichloropropene ND ug/L 11/30/23 17:01 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 11/30/23 17:01 10061-02-61.0 1
Ethylbenzene ND ug/L 11/30/23 17:01 100-41-41.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Sample: 6801-MW104 Lab ID: 92700176003 Collected: 11/21/23 14:00 Received: 11/22/23 12:18 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
2-Hexanone ND ug/L 11/30/23 17:01 591-78-65.0 1
Iodomethane ND ug/L 11/30/23 17:01 74-88-4 v220.0 1
Methylene Chloride ND ug/L 11/30/23 17:01 75-09-25.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/30/23 17:01 108-10-15.0 1
Styrene ND ug/L 11/30/23 17:01 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 11/30/23 17:01 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 11/30/23 17:01 79-34-51.0 1
Tetrachloroethene ND ug/L 11/30/23 17:01 127-18-41.0 1
Toluene ND ug/L 11/30/23 17:01 108-88-31.0 1
1,1,1-Trichloroethane ND ug/L 11/30/23 17:01 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 11/30/23 17:01 79-00-51.0 1
Trichloroethene ND ug/L 11/30/23 17:01 79-01-61.0 1
Trichlorofluoromethane ND ug/L 11/30/23 17:01 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 11/30/23 17:01 96-18-41.0 1
Vinyl acetate ND ug/L 11/30/23 17:01 108-05-42.0 1
Vinyl chloride ND ug/L 11/30/23 17:01 75-01-41.0 1
Xylene (Total)ND ug/L 11/30/23 17:01 1330-20-71.0 1
m&p-Xylene ND ug/L 11/30/23 17:01 179601-23-12.0 1
o-Xylene ND ug/L 11/30/23 17:01 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)102 %11/30/23 17:01 460-00-470-130 1
1,2-Dichloroethane-d4 (S)91 %11/30/23 17:01 17060-07-070-130 1
Toluene-d8 (S)99 %11/30/23 17:01 2037-26-570-130 1
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
8260D MSV SIM
1,4-Dioxane (p-Dioxane)ND ug/L 11/23/23 03:15 123-91-12.0 1
Surrogates
1,2-Dichloroethane-d4 (S)88 %11/23/23 03:15 17060-07-067-130 1
Toluene-d8 (S)91 %11/23/23 03:15 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Sample: 6801-MW111 Lab ID: 92700176004 Collected: 11/21/23 12:20 Received: 11/22/23 12:18 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services - Asheville
6010 MET ICP
Antimony ND ug/L 12/04/23 21:42 7440-36-011/28/23 12:305.0 1
Arsenic ND ug/L 12/04/23 21:42 7440-38-211/28/23 12:3010.0 1
Barium ND ug/L 12/04/23 21:42 7440-39-311/28/23 12:305.0 1
Beryllium ND ug/L 12/04/23 21:42 7440-41-711/28/23 12:301.0 1
Cadmium ND ug/L 12/04/23 21:42 7440-43-911/28/23 12:301.0 1
Chromium ND ug/L 12/04/23 21:42 7440-47-311/28/23 12:305.0 1
Cobalt ND ug/L 12/04/23 21:42 7440-48-411/28/23 12:305.0 1
Copper 5.8 ug/L 12/04/23 21:42 7440-50-811/28/23 12:305.0 1
Lead ND ug/L 12/04/23 21:42 7439-92-111/28/23 12:305.0 1
Nickel 6.5 ug/L 12/04/23 21:42 7440-02-011/28/23 12:305.0 1
Selenium ND ug/L 12/04/23 21:42 7782-49-211/28/23 12:3010.0 1
Silver ND ug/L 12/04/23 21:42 7440-22-411/28/23 12:305.0 1
Thallium ND ug/L 12/04/23 21:42 7440-28-011/28/23 12:3010.0 1
Vanadium 7.6 ug/L 12/04/23 21:42 7440-62-211/28/23 12:305.0 1
Zinc ND ug/L 12/04/23 21:42 7440-66-611/28/23 12:3010.0 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 12/01/23 11:25 67-64-125.0 1
Acrylonitrile ND ug/L 12/01/23 11:25 107-13-110.0 1
Benzene ND ug/L 12/01/23 11:25 71-43-21.0 1
Bromochloromethane ND ug/L 12/01/23 11:25 74-97-51.0 1
Bromodichloromethane ND ug/L 12/01/23 11:25 75-27-41.0 1
Bromoform ND ug/L 12/01/23 11:25 75-25-21.0 1
Bromomethane ND ug/L 12/01/23 11:25 74-83-9 IH2.0 1
2-Butanone (MEK)ND ug/L 12/01/23 11:25 78-93-35.0 1
Carbon disulfide ND ug/L 12/01/23 11:25 75-15-02.0 1
Carbon tetrachloride ND ug/L 12/01/23 11:25 56-23-51.0 1
Chlorobenzene ND ug/L 12/01/23 11:25 108-90-71.0 1
Chloroethane ND ug/L 12/01/23 11:25 75-00-31.0 1
Chloroform ND ug/L 12/01/23 11:25 67-66-31.0 1
Chloromethane ND ug/L 12/01/23 11:25 74-87-31.0 1
Dibromochloromethane ND ug/L 12/01/23 11:25 124-48-11.0 1
Dibromomethane ND ug/L 12/01/23 11:25 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 12/01/23 11:25 95-50-11.0 1
1,4-Dichlorobenzene ND ug/L 12/01/23 11:25 106-46-71.0 1
trans-1,4-Dichloro-2-butene ND ug/L 12/01/23 11:25 110-57-61.0 1
1,1-Dichloroethane ND ug/L 12/01/23 11:25 75-34-31.0 1
1,2-Dichloroethane ND ug/L 12/01/23 11:25 107-06-21.0 1
1,1-Dichloroethene ND ug/L 12/01/23 11:25 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 12/01/23 11:25 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 12/01/23 11:25 156-60-51.0 1
1,2-Dichloropropane ND ug/L 12/01/23 11:25 78-87-51.0 1
cis-1,3-Dichloropropene ND ug/L 12/01/23 11:25 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 12/01/23 11:25 10061-02-61.0 1
Ethylbenzene ND ug/L 12/01/23 11:25 100-41-41.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Sample: 6801-MW111 Lab ID: 92700176004 Collected: 11/21/23 12:20 Received: 11/22/23 12:18 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
2-Hexanone ND ug/L 12/01/23 11:25 591-78-65.0 1
Iodomethane ND ug/L 12/01/23 11:25 74-88-420.0 1
Methylene Chloride ND ug/L 12/01/23 11:25 75-09-25.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/01/23 11:25 108-10-15.0 1
Styrene ND ug/L 12/01/23 11:25 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 12/01/23 11:25 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 12/01/23 11:25 79-34-51.0 1
Tetrachloroethene ND ug/L 12/01/23 11:25 127-18-41.0 1
Toluene ND ug/L 12/01/23 11:25 108-88-31.0 1
1,1,1-Trichloroethane ND ug/L 12/01/23 11:25 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 12/01/23 11:25 79-00-51.0 1
Trichloroethene ND ug/L 12/01/23 11:25 79-01-61.0 1
Trichlorofluoromethane ND ug/L 12/01/23 11:25 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 12/01/23 11:25 96-18-41.0 1
Vinyl acetate ND ug/L 12/01/23 11:25 108-05-42.0 1
Vinyl chloride ND ug/L 12/01/23 11:25 75-01-41.0 1
Xylene (Total)ND ug/L 12/01/23 11:25 1330-20-71.0 1
m&p-Xylene ND ug/L 12/01/23 11:25 179601-23-12.0 1
o-Xylene ND ug/L 12/01/23 11:25 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)94 %12/01/23 11:25 460-00-470-130 1
1,2-Dichloroethane-d4 (S)92 %12/01/23 11:25 17060-07-070-130 1
Toluene-d8 (S)99 %12/01/23 11:25 2037-26-570-130 1
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
8260D MSV SIM
1,4-Dioxane (p-Dioxane)ND ug/L 11/23/23 03:36 123-91-12.0 1
Surrogates
1,2-Dichloroethane-d4 (S)89 %11/23/23 03:36 17060-07-067-130 1
Toluene-d8 (S)91 %11/23/23 03:36 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Sample: TRIP BLANK 1 Lab ID: 92700176005 Collected: 11/21/23 00:00 Received: 11/22/23 12:18 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 11/30/23 14:21 67-64-125.0 1
Acrylonitrile ND ug/L 11/30/23 14:21 107-13-110.0 1
Benzene ND ug/L 11/30/23 14:21 71-43-21.0 1
Bromochloromethane ND ug/L 11/30/23 14:21 74-97-51.0 1
Bromodichloromethane ND ug/L 11/30/23 14:21 75-27-41.0 1
Bromoform ND ug/L 11/30/23 14:21 75-25-21.0 1
Bromomethane ND ug/L 11/30/23 14:21 74-83-9 v22.0 1
2-Butanone (MEK)ND ug/L 11/30/23 14:21 78-93-35.0 1
Carbon disulfide ND ug/L 11/30/23 14:21 75-15-02.0 1
Carbon tetrachloride ND ug/L 11/30/23 14:21 56-23-51.0 1
Chlorobenzene ND ug/L 11/30/23 14:21 108-90-71.0 1
Chloroethane ND ug/L 11/30/23 14:21 75-00-31.0 1
Chloroform ND ug/L 11/30/23 14:21 67-66-31.0 1
Chloromethane ND ug/L 11/30/23 14:21 74-87-31.0 1
Dibromochloromethane ND ug/L 11/30/23 14:21 124-48-11.0 1
Dibromomethane ND ug/L 11/30/23 14:21 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 11/30/23 14:21 95-50-11.0 1
1,4-Dichlorobenzene ND ug/L 11/30/23 14:21 106-46-71.0 1
trans-1,4-Dichloro-2-butene ND ug/L 11/30/23 14:21 110-57-61.0 1
1,1-Dichloroethane ND ug/L 11/30/23 14:21 75-34-31.0 1
1,2-Dichloroethane ND ug/L 11/30/23 14:21 107-06-21.0 1
1,1-Dichloroethene ND ug/L 11/30/23 14:21 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 11/30/23 14:21 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 11/30/23 14:21 156-60-51.0 1
1,2-Dichloropropane ND ug/L 11/30/23 14:21 78-87-51.0 1
cis-1,3-Dichloropropene ND ug/L 11/30/23 14:21 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 11/30/23 14:21 10061-02-61.0 1
Ethylbenzene ND ug/L 11/30/23 14:21 100-41-41.0 1
2-Hexanone ND ug/L 11/30/23 14:21 591-78-65.0 1
Iodomethane ND ug/L 11/30/23 14:21 74-88-4 v220.0 1
Methylene Chloride ND ug/L 11/30/23 14:21 75-09-25.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/30/23 14:21 108-10-15.0 1
Styrene ND ug/L 11/30/23 14:21 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 11/30/23 14:21 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 11/30/23 14:21 79-34-51.0 1
Tetrachloroethene ND ug/L 11/30/23 14:21 127-18-41.0 1
Toluene ND ug/L 11/30/23 14:21 108-88-31.0 1
1,1,1-Trichloroethane ND ug/L 11/30/23 14:21 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 11/30/23 14:21 79-00-51.0 1
Trichloroethene ND ug/L 11/30/23 14:21 79-01-61.0 1
Trichlorofluoromethane ND ug/L 11/30/23 14:21 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 11/30/23 14:21 96-18-41.0 1
Vinyl acetate ND ug/L 11/30/23 14:21 108-05-42.0 1
Vinyl chloride ND ug/L 11/30/23 14:21 75-01-41.0 1
Xylene (Total)ND ug/L 11/30/23 14:21 1330-20-71.0 1
m&p-Xylene ND ug/L 11/30/23 14:21 179601-23-12.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Sample: TRIP BLANK 1 Lab ID: 92700176005 Collected: 11/21/23 00:00 Received: 11/22/23 12:18 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
o-Xylene ND ug/L 11/30/23 14:21 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)102 %11/30/23 14:21 460-00-470-130 1
1,2-Dichloroethane-d4 (S)92 %11/30/23 14:21 17060-07-070-130 1
Toluene-d8 (S)98 %11/30/23 14:21 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Sample: TRIP BLANK 2 Lab ID: 92700176006 Collected: 11/21/23 00:00 Received: 11/22/23 12:18 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 11/30/23 14:39 67-64-125.0 1
Acrylonitrile ND ug/L 11/30/23 14:39 107-13-110.0 1
Benzene ND ug/L 11/30/23 14:39 71-43-21.0 1
Bromochloromethane ND ug/L 11/30/23 14:39 74-97-51.0 1
Bromodichloromethane ND ug/L 11/30/23 14:39 75-27-41.0 1
Bromoform ND ug/L 11/30/23 14:39 75-25-21.0 1
Bromomethane ND ug/L 11/30/23 14:39 74-83-9 v22.0 1
2-Butanone (MEK)ND ug/L 11/30/23 14:39 78-93-35.0 1
Carbon disulfide ND ug/L 11/30/23 14:39 75-15-02.0 1
Carbon tetrachloride ND ug/L 11/30/23 14:39 56-23-51.0 1
Chlorobenzene ND ug/L 11/30/23 14:39 108-90-71.0 1
Chloroethane ND ug/L 11/30/23 14:39 75-00-31.0 1
Chloroform ND ug/L 11/30/23 14:39 67-66-31.0 1
Chloromethane ND ug/L 11/30/23 14:39 74-87-31.0 1
Dibromochloromethane ND ug/L 11/30/23 14:39 124-48-11.0 1
Dibromomethane ND ug/L 11/30/23 14:39 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 11/30/23 14:39 95-50-11.0 1
1,4-Dichlorobenzene ND ug/L 11/30/23 14:39 106-46-71.0 1
trans-1,4-Dichloro-2-butene ND ug/L 11/30/23 14:39 110-57-61.0 1
1,1-Dichloroethane ND ug/L 11/30/23 14:39 75-34-31.0 1
1,2-Dichloroethane ND ug/L 11/30/23 14:39 107-06-21.0 1
1,1-Dichloroethene ND ug/L 11/30/23 14:39 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 11/30/23 14:39 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 11/30/23 14:39 156-60-51.0 1
1,2-Dichloropropane ND ug/L 11/30/23 14:39 78-87-51.0 1
cis-1,3-Dichloropropene ND ug/L 11/30/23 14:39 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 11/30/23 14:39 10061-02-61.0 1
Ethylbenzene ND ug/L 11/30/23 14:39 100-41-41.0 1
2-Hexanone ND ug/L 11/30/23 14:39 591-78-65.0 1
Iodomethane ND ug/L 11/30/23 14:39 74-88-4 v220.0 1
Methylene Chloride ND ug/L 11/30/23 14:39 75-09-25.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/30/23 14:39 108-10-15.0 1
Styrene ND ug/L 11/30/23 14:39 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 11/30/23 14:39 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 11/30/23 14:39 79-34-51.0 1
Tetrachloroethene ND ug/L 11/30/23 14:39 127-18-41.0 1
Toluene ND ug/L 11/30/23 14:39 108-88-31.0 1
1,1,1-Trichloroethane ND ug/L 11/30/23 14:39 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 11/30/23 14:39 79-00-51.0 1
Trichloroethene ND ug/L 11/30/23 14:39 79-01-61.0 1
Trichlorofluoromethane ND ug/L 11/30/23 14:39 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 11/30/23 14:39 96-18-41.0 1
Vinyl acetate ND ug/L 11/30/23 14:39 108-05-42.0 1
Vinyl chloride ND ug/L 11/30/23 14:39 75-01-41.0 1
Xylene (Total)ND ug/L 11/30/23 14:39 1330-20-71.0 1
m&p-Xylene ND ug/L 11/30/23 14:39 179601-23-12.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Sample: TRIP BLANK 2 Lab ID: 92700176006 Collected: 11/21/23 00:00 Received: 11/22/23 12:18 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
o-Xylene ND ug/L 11/30/23 14:39 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)101 %11/30/23 14:39 460-00-470-130 1
1,2-Dichloroethane-d4 (S)91 %11/30/23 14:39 17060-07-070-130 1
Toluene-d8 (S)97 %11/30/23 14:39 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815698
EPA 3010A
EPA 6010D
6010 MET
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples: 92700176001, 92700176002, 92700176003, 92700176004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4222044
Associated Lab Samples:92700176001, 92700176002, 92700176003, 92700176004
Matrix: Water
Analyzed
Antimony ug/L ND 5.0 12/04/23 21:22
Arsenic ug/L ND 10.0 12/04/23 21:22
Barium ug/L ND 5.0 12/05/23 20:09
Beryllium ug/L ND 1.0 12/04/23 21:22
Cadmium ug/L ND 1.0 12/04/23 21:22
Chromium ug/L ND 5.0 12/04/23 21:22
Cobalt ug/L ND 5.0 12/04/23 21:22
Copper ug/L ND 5.0 12/04/23 21:22
Lead ug/L ND 5.0 12/04/23 21:22
Nickel ug/L ND 5.0 12/04/23 21:22
Selenium ug/L ND 10.0 12/04/23 21:22
Silver ug/L ND 5.0 12/04/23 21:22
Thallium ug/L ND 10.0 12/04/23 21:22
Vanadium ug/L ND 5.0 12/04/23 21:22
Zinc ug/L ND 10.0 12/04/23 21:22
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4222045LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 520500 104 80-120
Arsenic ug/L 525500 105 80-120
Barium ug/L 508500 102 80-120
Beryllium ug/L 515500 103 80-120
Cadmium ug/L 524500 105 80-120
Chromium ug/L 519500 104 80-120
Cobalt ug/L 516500 103 80-120
Copper ug/L 518500 104 80-120
Lead ug/L 518500 104 80-120
Nickel ug/L 516500 103 80-120
Selenium ug/L 510500 102 80-120
Silver ug/L 260250 104 80-120
Thallium ug/L 525500 105 80-120
Vanadium ug/L 515500 103 80-120
Zinc ug/L 512500 102 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4222046MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92700200001
4222047
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Antimony ug/L 500 106 75-125107 2500ND528 536
Arsenic ug/L 500 108 75-125109 1500ND540 546
Barium ug/L 500 96 75-12599 350019.1 498 514
Beryllium ug/L 500 105 75-125106 1500ND526 532
Cadmium ug/L 500 105 75-125106 0500ND528 529
Chromium ug/L 500 103 75-125104 1500ND515 520
Cobalt ug/L 500 102 75-125103 1500ND512 517
Copper ug/L 500 102 75-125105 2500ND516 527
Lead ug/L 500 103 75-125103 0500ND514 516
Nickel ug/L 500 102 75-125103 1500ND512 516
Selenium ug/L 500 106 75-125108 2500ND533 543
Silver ug/L 250 103 75-125105 2250ND258 263
Thallium ug/L 500 102 75-125103 1500ND509 516
Vanadium ug/L 500 103 75-125104 1500ND517 522
Zinc ug/L 500 105 75-125104 050050.2 573 572
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
816401
EPA 8260D
EPA 8260D
8260D MSV Low Level Landfill
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples: 92700176001, 92700176002, 92700176003, 92700176005, 92700176006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4225709
Associated Lab Samples:92700176001, 92700176002, 92700176003, 92700176005, 92700176006
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 1.0 11/30/23 14:03
1,1,1-Trichloroethane ug/L ND 1.0 11/30/23 14:03
1,1,2,2-Tetrachloroethane ug/L ND 1.0 11/30/23 14:03
1,1,2-Trichloroethane ug/L ND 1.0 11/30/23 14:03
1,1-Dichloroethane ug/L ND 1.0 11/30/23 14:03
1,1-Dichloroethene ug/L ND 1.0 11/30/23 14:03
1,2,3-Trichloropropane ug/L ND 1.0 11/30/23 14:03
1,2-Dichlorobenzene ug/L ND 1.0 11/30/23 14:03
1,2-Dichloroethane ug/L ND 1.0 11/30/23 14:03
1,2-Dichloropropane ug/L ND 1.0 11/30/23 14:03
1,4-Dichlorobenzene ug/L ND 1.0 11/30/23 14:03
2-Butanone (MEK)ug/L ND 5.0 11/30/23 14:03
2-Hexanone ug/L ND 5.0 11/30/23 14:03
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 11/30/23 14:03
Acetone ug/L ND 25.0 11/30/23 14:03
Acrylonitrile ug/L ND 10.0 11/30/23 14:03
Benzene ug/L ND 1.0 11/30/23 14:03
Bromochloromethane ug/L ND 1.0 11/30/23 14:03
Bromodichloromethane ug/L ND 1.0 11/30/23 14:03
Bromoform ug/L ND 1.0 11/30/23 14:03
Bromomethane ug/L ND 2.0 v211/30/23 14:03
Carbon disulfide ug/L ND 2.0 11/30/23 14:03
Carbon tetrachloride ug/L ND 1.0 11/30/23 14:03
Chlorobenzene ug/L ND 1.0 11/30/23 14:03
Chloroethane ug/L ND 1.0 11/30/23 14:03
Chloroform ug/L ND 1.0 11/30/23 14:03
Chloromethane ug/L ND 1.0 11/30/23 14:03
cis-1,2-Dichloroethene ug/L ND 1.0 11/30/23 14:03
cis-1,3-Dichloropropene ug/L ND 1.0 11/30/23 14:03
Dibromochloromethane ug/L ND 1.0 11/30/23 14:03
Dibromomethane ug/L ND 1.0 11/30/23 14:03
Ethylbenzene ug/L ND 1.0 11/30/23 14:03
Iodomethane ug/L ND 20.0 v211/30/23 14:03
m&p-Xylene ug/L ND 2.0 11/30/23 14:03
Methylene Chloride ug/L ND 5.0 11/30/23 14:03
o-Xylene ug/L ND 1.0 11/30/23 14:03
Styrene ug/L ND 1.0 11/30/23 14:03
Tetrachloroethene ug/L ND 1.0 11/30/23 14:03
Toluene ug/L ND 1.0 11/30/23 14:03
trans-1,2-Dichloroethene ug/L ND 1.0 11/30/23 14:03
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4225709
Associated Lab Samples:92700176001, 92700176002, 92700176003, 92700176005, 92700176006
Matrix: Water
Analyzed
trans-1,3-Dichloropropene ug/L ND 1.0 11/30/23 14:03
trans-1,4-Dichloro-2-butene ug/L ND 1.0 11/30/23 14:03
Trichloroethene ug/L ND 1.0 11/30/23 14:03
Trichlorofluoromethane ug/L ND 1.0 11/30/23 14:03
Vinyl acetate ug/L ND 2.0 11/30/23 14:03
Vinyl chloride ug/L ND 1.0 11/30/23 14:03
Xylene (Total)ug/L ND 1.0 11/30/23 14:03
1,2-Dichloroethane-d4 (S)%93 70-130 11/30/23 14:03
4-Bromofluorobenzene (S)%101 70-130 11/30/23 14:03
Toluene-d8 (S)%97 70-130 11/30/23 14:03
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4225710LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 19.920 100 70-130
1,1,1-Trichloroethane ug/L 19.520 98 70-130
1,1,2,2-Tetrachloroethane ug/L 19.920 99 70-130
1,1,2-Trichloroethane ug/L 19.720 98 70-130
1,1-Dichloroethane ug/L 18.020 90 70-130
1,1-Dichloroethene ug/L 18.520 92 69-131
1,2,3-Trichloropropane ug/L 19.420 97 70-130
1,2-Dichlorobenzene ug/L 20.220 101 70-130
1,2-Dichloroethane ug/L 18.920 95 70-130
1,2-Dichloropropane ug/L 19.420 97 70-130
1,4-Dichlorobenzene ug/L 19.520 97 70-130
2-Butanone (MEK)ug/L 37.640 94 67-133
2-Hexanone ug/L 40.440 101 70-133
4-Methyl-2-pentanone (MIBK)ug/L 38.240 96 70-130
Acetone ug/L 37.440 93 67-130
Acrylonitrile ug/L 88.4100 88 70-130
Benzene ug/L 19.020 95 70-130
Bromochloromethane ug/L 19.720 98 70-130
Bromodichloromethane ug/L 18.420 92 70-130
Bromoform ug/L 16.420 82 70-133
Bromomethane ug/L 16.0 v32080 41-148
Carbon disulfide ug/L 19.120 96 70-131
Carbon tetrachloride ug/L 19.820 99 70-130
Chlorobenzene ug/L 19.420 97 70-130
Chloroethane ug/L 16.220 81 41-157
Chloroform ug/L 18.520 93 70-130
Chloromethane ug/L 17.320 87 59-141
cis-1,2-Dichloroethene ug/L 18.020 90 70-130
cis-1,3-Dichloropropene ug/L 18.920 95 70-130
Dibromochloromethane ug/L 19.220 96 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4225710LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromomethane ug/L 19.620 98 70-130
Ethylbenzene ug/L 19.420 97 70-130
Iodomethane ug/L 33.9 v34085 57-140
m&p-Xylene ug/L 39.240 98 70-130
Methylene Chloride ug/L 17.420 87 62-130
o-Xylene ug/L 19.720 98 70-130
Styrene ug/L 19.720 99 70-130
Tetrachloroethene ug/L 20.720 104 70-130
Toluene ug/L 18.620 93 70-130
trans-1,2-Dichloroethene ug/L 18.720 94 70-130
trans-1,3-Dichloropropene ug/L 18.920 94 70-130
trans-1,4-Dichloro-2-butene ug/L 20.920 104 57-149
Trichloroethene ug/L 20.220 101 70-130
Trichlorofluoromethane ug/L 17.320 87 57-130
Vinyl acetate ug/L 36.240 90 70-141
Vinyl chloride ug/L 17.020 85 66-140
Xylene (Total)ug/L 58.860 98 70-130
1,2-Dichloroethane-d4 (S)%93 70-130
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%97 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
4225711MATRIX SPIKE SAMPLE:
MSSpike
Result
92699883003
1,1,1,2-Tetrachloroethane ug/L 20.620 103 70-146ND
1,1,1-Trichloroethane ug/L 23.020 115 70-150ND
1,1,2,2-Tetrachloroethane ug/L 19.220 96 66-144ND
1,1,2-Trichloroethane ug/L 20.320 102 70-142ND
1,1-Dichloroethane ug/L 19.420 97 68-150ND
1,1-Dichloroethene ug/L 21.820 109 64-162ND
1,2,3-Trichloropropane ug/L 19.420 97 66-144ND
1,2-Dichlorobenzene ug/L 20.720 104 70-142ND
1,2-Dichloroethane ug/L 19.420 97 68-145ND
1,2-Dichloropropane ug/L 19.020 95 70-144ND
1,4-Dichlorobenzene ug/L 20.420 102 70-140ND
2-Butanone (MEK)ug/L 32.740 82 57-156ND
2-Hexanone ug/L 34.340 86 62-153ND
4-Methyl-2-pentanone (MIBK)ug/L 34.040 85 65-144ND
Acetone ug/L 33.940 85 49-162ND
Acrylonitrile ug/L 85.7 v310086 59-155ND
Benzene ug/L 20.220 101 68-144ND
Bromochloromethane ug/L 20.920 104 70-148ND
Bromodichloromethane ug/L 20.520 102 70-141ND
Bromoform ug/L 17.320 87 59-144ND
Bromomethane ug/L 20.6 v320103 23-190ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
4225711MATRIX SPIKE SAMPLE:
MSSpike
Result
92699883003
Carbon disulfide ug/L 22.820 114 64-160ND
Carbon tetrachloride ug/L 25.120 126 70-147ND
Chlorobenzene ug/L 19.220 96 70-143ND
Chloroethane ug/L 19.320 96 55-190ND
Chloroform ug/L 20.620 103 67-148ND
Chloromethane ug/L 18.6 v32093 38-180ND
cis-1,2-Dichloroethene ug/L 18.820 94 67-151ND
cis-1,3-Dichloropropene ug/L 19.220 96 70-142ND
Dibromochloromethane ug/L 19.920 100 68-140ND
Dibromomethane ug/L 21.320 106 70-142ND
Ethylbenzene ug/L 19.620 98 70-145ND
Iodomethane ug/L 42.540 106 37-160ND
m&p-Xylene ug/L 40.240 100 70-148ND
Methylene Chloride ug/L 17.920 89 54-149ND
o-Xylene ug/L 20.020 100 70-145ND
Styrene ug/L 19.820 99 70-147ND
Tetrachloroethene ug/L 22.320 111 70-145ND
Toluene ug/L 19.620 98 65-146ND
trans-1,2-Dichloroethene ug/L 21.020 105 69-155ND
trans-1,3-Dichloropropene ug/L 20.120 100 70-142ND
trans-1,4-Dichloro-2-butene ug/L 18.120 91 39-149ND
Trichloroethene ug/L 22.820 114 70-152ND
Trichlorofluoromethane ug/L 21.620 108 60-158ND
Vinyl acetate ug/L 32.7 v34082 56-157ND
Vinyl chloride ug/L 18.4 v32092 51-178ND
Xylene (Total)ug/L 60.260 100 70-146ND
1,2-Dichloroethane-d4 (S)%97 70-130
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%94 70-130
Parameter Units
Dup
Result QualifiersRPDResult
92699883004
4225712SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L NDND
1,1,1-Trichloroethane ug/L NDND
1,1,2,2-Tetrachloroethane ug/L NDND
1,1,2-Trichloroethane ug/L NDND
1,1-Dichloroethane ug/L NDND
1,1-Dichloroethene ug/L NDND
1,2,3-Trichloropropane ug/L NDND
1,2-Dichlorobenzene ug/L NDND
1,2-Dichloroethane ug/L NDND
1,2-Dichloropropane ug/L NDND
1,4-Dichlorobenzene ug/L NDND
2-Butanone (MEK)ug/L NDND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result QualifiersRPDResult
92699883004
4225712SAMPLE DUPLICATE:
2-Hexanone ug/L NDND
4-Methyl-2-pentanone (MIBK)ug/L NDND
Acetone ug/L NDND
Acrylonitrile ug/L ND v2ND
Benzene ug/L NDND
Bromochloromethane ug/L NDND
Bromodichloromethane ug/L NDND
Bromoform ug/L NDND
Bromomethane ug/L ND v2ND
Carbon disulfide ug/L NDND
Carbon tetrachloride ug/L NDND
Chlorobenzene ug/L NDND
Chloroethane ug/L NDND
Chloroform ug/L NDND
Chloromethane ug/L ND v2ND
cis-1,2-Dichloroethene ug/L NDND
cis-1,3-Dichloropropene ug/L NDND
Dibromochloromethane ug/L NDND
Dibromomethane ug/L NDND
Ethylbenzene ug/L NDND
Iodomethane ug/L NDND
m&p-Xylene ug/L NDND
Methylene Chloride ug/L NDND
o-Xylene ug/L NDND
Styrene ug/L NDND
Tetrachloroethene ug/L NDND
Toluene ug/L NDND
trans-1,2-Dichloroethene ug/L NDND
trans-1,3-Dichloropropene ug/L NDND
trans-1,4-Dichloro-2-butene ug/L NDND
Trichloroethene ug/L NDND
Trichlorofluoromethane ug/L NDND
Vinyl acetate ug/L ND v2ND
Vinyl chloride ug/L ND v2ND
Xylene (Total)ug/L NDND
1,2-Dichloroethane-d4 (S)%9192
4-Bromofluorobenzene (S)%105103
Toluene-d8 (S)%9697
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
816405
EPA 8260D
EPA 8260D
8260D MSV Low Level Landfill
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples: 92700176004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4225726
Associated Lab Samples:92700176004
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 1.0 12/01/23 01:51
1,1,1-Trichloroethane ug/L ND 1.0 12/01/23 01:51
1,1,2,2-Tetrachloroethane ug/L ND 1.0 12/01/23 01:51
1,1,2-Trichloroethane ug/L ND 1.0 12/01/23 01:51
1,1-Dichloroethane ug/L ND 1.0 12/01/23 01:51
1,1-Dichloroethene ug/L ND 1.0 12/01/23 01:51
1,2,3-Trichloropropane ug/L ND 1.0 12/01/23 01:51
1,2-Dichlorobenzene ug/L ND 1.0 12/01/23 01:51
1,2-Dichloroethane ug/L ND 1.0 12/01/23 01:51
1,2-Dichloropropane ug/L ND 1.0 12/01/23 01:51
1,4-Dichlorobenzene ug/L ND 1.0 12/01/23 01:51
2-Butanone (MEK)ug/L ND 5.0 12/01/23 01:51
2-Hexanone ug/L ND 5.0 12/01/23 01:51
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 12/01/23 01:51
Acetone ug/L ND 25.0 12/01/23 01:51
Acrylonitrile ug/L ND 10.0 12/01/23 01:51
Benzene ug/L ND 1.0 12/01/23 01:51
Bromochloromethane ug/L ND 1.0 12/01/23 01:51
Bromodichloromethane ug/L ND 1.0 12/01/23 01:51
Bromoform ug/L ND 1.0 12/01/23 01:51
Bromomethane ug/L ND 2.0 IH12/01/23 01:51
Carbon disulfide ug/L ND 2.0 12/01/23 01:51
Carbon tetrachloride ug/L ND 1.0 12/01/23 01:51
Chlorobenzene ug/L ND 1.0 12/01/23 01:51
Chloroethane ug/L ND 1.0 12/01/23 01:51
Chloroform ug/L ND 1.0 12/01/23 01:51
Chloromethane ug/L ND 1.0 12/01/23 01:51
cis-1,2-Dichloroethene ug/L ND 1.0 12/01/23 01:51
cis-1,3-Dichloropropene ug/L ND 1.0 12/01/23 01:51
Dibromochloromethane ug/L ND 1.0 12/01/23 01:51
Dibromomethane ug/L ND 1.0 12/01/23 01:51
Ethylbenzene ug/L ND 1.0 12/01/23 01:51
Iodomethane ug/L ND 20.0 12/01/23 01:51
m&p-Xylene ug/L ND 2.0 12/01/23 01:51
Methylene Chloride ug/L ND 5.0 12/01/23 01:51
o-Xylene ug/L ND 1.0 12/01/23 01:51
Styrene ug/L ND 1.0 12/01/23 01:51
Tetrachloroethene ug/L ND 1.0 12/01/23 01:51
Toluene ug/L ND 1.0 12/01/23 01:51
trans-1,2-Dichloroethene ug/L ND 1.0 12/01/23 01:51
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4225726
Associated Lab Samples:92700176004
Matrix: Water
Analyzed
trans-1,3-Dichloropropene ug/L ND 1.0 12/01/23 01:51
trans-1,4-Dichloro-2-butene ug/L ND 1.0 12/01/23 01:51
Trichloroethene ug/L ND 1.0 12/01/23 01:51
Trichlorofluoromethane ug/L ND 1.0 12/01/23 01:51
Vinyl acetate ug/L ND 2.0 12/01/23 01:51
Vinyl chloride ug/L ND 1.0 12/01/23 01:51
Xylene (Total)ug/L ND 1.0 12/01/23 01:51
1,2-Dichloroethane-d4 (S)%91 70-130 12/01/23 01:51
4-Bromofluorobenzene (S)%95 70-130 12/01/23 01:51
Toluene-d8 (S)%98 70-130 12/01/23 01:51
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4225727LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 19.720 99 70-130
1,1,1-Trichloroethane ug/L 20.020 100 70-130
1,1,2,2-Tetrachloroethane ug/L 18.720 94 70-130
1,1,2-Trichloroethane ug/L 18.620 93 70-130
1,1-Dichloroethane ug/L 18.420 92 70-130
1,1-Dichloroethene ug/L 20.620 103 69-131
1,2,3-Trichloropropane ug/L 17.420 87 70-130
1,2-Dichlorobenzene ug/L 19.920 99 70-130
1,2-Dichloroethane ug/L 17.120 85 70-130
1,2-Dichloropropane ug/L 18.920 95 70-130
1,4-Dichlorobenzene ug/L 19.920 99 70-130
2-Butanone (MEK)ug/L 33.340 83 67-133
2-Hexanone ug/L 33.340 83 70-133
4-Methyl-2-pentanone (MIBK)ug/L 34.440 86 70-130
Acetone ug/L 31.340 78 67-130
Acrylonitrile ug/L 86.1100 86 70-130
Benzene ug/L 19.720 98 70-130
Bromochloromethane ug/L 18.120 90 70-130
Bromodichloromethane ug/L 18.520 92 70-130
Bromoform ug/L 18.920 94 70-133
Bromomethane ug/L 21.3 IH20107 41-148
Carbon disulfide ug/L 21.220 106 70-131
Carbon tetrachloride ug/L 21.620 108 70-130
Chlorobenzene ug/L 19.820 99 70-130
Chloroethane ug/L 21.520 108 41-157
Chloroform ug/L 17.120 86 70-130
Chloromethane ug/L 22.920 114 59-141
cis-1,2-Dichloroethene ug/L 18.520 92 70-130
cis-1,3-Dichloropropene ug/L 18.120 90 70-130
Dibromochloromethane ug/L 19.220 96 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4225727LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromomethane ug/L 18.920 94 70-130
Ethylbenzene ug/L 19.720 98 70-130
Iodomethane ug/L 38.540 96 57-140
m&p-Xylene ug/L 39.440 99 70-130
Methylene Chloride ug/L 18.520 92 62-130
o-Xylene ug/L 19.420 97 70-130
Styrene ug/L 19.820 99 70-130
Tetrachloroethene ug/L 20.820 104 70-130
Toluene ug/L 19.620 98 70-130
trans-1,2-Dichloroethene ug/L 19.020 95 70-130
trans-1,3-Dichloropropene ug/L 18.620 93 70-130
trans-1,4-Dichloro-2-butene ug/L 17.120 85 57-149
Trichloroethene ug/L 20.620 103 70-130
Trichlorofluoromethane ug/L 23.620 118 57-130
Vinyl acetate ug/L 34.240 85 70-141
Vinyl chloride ug/L 22.020 110 66-140
Xylene (Total)ug/L 58.860 98 70-130
1,2-Dichloroethane-d4 (S)%88 70-130
4-Bromofluorobenzene (S)%96 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4225728MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92700200001
4225729
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 116 70-146125 820ND23.1 25.0
1,1,1-Trichloroethane ug/L 20 112 70-150121 820ND22.4 24.2
1,1,2,2-Tetrachloroethane ug/L 20 102 66-144114 1120ND20.5 22.7
1,1,2-Trichloroethane ug/L 20 107 70-142115 820ND21.3 23.0
1,1-Dichloroethane ug/L 20 101 68-150113 1120ND20.3 22.5
1,1-Dichloroethene ug/L 20 112 64-162125 1120ND22.4 25.0
1,2,3-Trichloropropane ug/L 20 93 66-144108 1520ND18.6 21.5
1,2-Dichlorobenzene ug/L 20 110 70-142121 1020ND22.0 24.2
1,2-Dichloroethane ug/L 20 92 68-145102 1020ND18.3 20.3
1,2-Dichloropropane ug/L 20 106 70-144118 1120ND21.2 23.6
1,4-Dichlorobenzene ug/L 20 108 70-140120 1020ND21.7 24.1
2-Butanone (MEK)ug/L 40 90 57-156105 1640ND35.9 42.1
2-Hexanone ug/L 40 94 62-153105 1140ND37.7 42.1
4-Methyl-2-pentanone (MIBK) ug/L 40 97 65-144108 1140ND38.7 43.1
Acetone ug/L 40 79 49-16292 1540ND31.5 36.8
Acrylonitrile ug/L 100 96 59-155107 11100ND95.8 107
Benzene ug/L 20 110 68-144121 1020ND21.9 24.2
Bromochloromethane ug/L 20 104 70-148112 820ND20.8 22.5
Bromodichloromethane ug/L 20 103 70-141112 820ND20.6 22.4
Bromoform ug/L 20 109 59-144119 920ND21.8 23.7
REPORT OF LABORATORY ANALYSIS
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Page 25 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4225728MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92700200001
4225729
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Bromomethane ug/L IH2013823-190138 120ND27.5 27.7
Carbon disulfide ug/L 20 116 64-160126 820ND23.2 25.3
Carbon tetrachloride ug/L 20 127 70-147138 820ND25.5 27.6
Chlorobenzene ug/L 20 112 70-143122 820ND22.4 24.4
Chloroethane ug/L 20 116 55-190129 1020ND23.3 25.9
Chloroform ug/L 20 103 67-148114 1020ND20.5 22.7
Chloromethane ug/L 20 128 38-180139 820ND25.6 27.8
cis-1,2-Dichloroethene ug/L 20 100 67-151112 1120ND20.0 22.3
cis-1,3-Dichloropropene ug/L 20 101 70-142111 1020ND20.3 22.3
Dibromochloromethane ug/L 20 106 68-140116 1020ND21.2 23.3
Dibromomethane ug/L 20 115 70-142125 820ND23.1 24.9
Ethylbenzene ug/L 20 111 70-145121 820ND22.2 24.1
Iodomethane ug/L 40 103 37-160115 1140ND41.2 46.0
m&p-Xylene ug/L 40 111 70-148121 840ND44.6 48.3
Methylene Chloride ug/L 20 95 54-149105 1020ND19.0 20.9
o-Xylene ug/L 20 112 70-145122 920ND22.4 24.4
Styrene ug/L 20 111 70-147120 820ND22.3 24.0
Tetrachloroethene ug/L 20 124 70-145134 820ND24.9 26.9
Toluene ug/L 20 108 65-146119 920ND21.7 23.8
trans-1,2-Dichloroethene ug/L 20 103 69-155114 1020ND20.5 22.8
trans-1,3-Dichloropropene ug/L 20 105 70-142114 820ND20.9 22.7
trans-1,4-Dichloro-2-butene ug/L 20 89 39-149102 1420ND17.8 20.5
Trichloroethene ug/L 20 119 70-152130 920ND23.7 26.1
Trichlorofluoromethane ug/L 20 133 60-158146 1020ND26.6 29.3
Vinyl acetate ug/L 40 94 56-157104 1140ND37.5 41.7
Vinyl chloride ug/L 20 125 51-178136 920ND25.0 27.3
Xylene (Total)ug/L 60 112 70-146121 860ND66.9 72.7
1,2-Dichloroethane-d4 (S)%82 70-13082
4-Bromofluorobenzene (S)%97 70-13096
Toluene-d8 (S)%97 70-13097
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
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Page 26 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815205
EPA 8260D Mod.
EPA 8260D Mod.
8260D MSV SIM
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples: 92700176001, 92700176002, 92700176003, 92700176004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4220270
Associated Lab Samples:92700176001, 92700176002, 92700176003, 92700176004
Matrix: Water
Analyzed
1,4-Dioxane (p-Dioxane)ug/L ND 2.0 11/22/23 17:58
1,2-Dichloroethane-d4 (S)%88 67-130 11/22/23 17:58
Toluene-d8 (S)%90 70-130 11/22/23 17:58
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4220271LABORATORY CONTROL SAMPLE:
LCSSpike
1,4-Dioxane (p-Dioxane)ug/L 17.120 86 70-130
1,2-Dichloroethane-d4 (S)%87 67-130
Toluene-d8 (S)%92 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4220272MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699898001
4220273
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,4-Dioxane (p-Dioxane)ug/L 20 85 55-13790 620ND16.9 17.9
1,2-Dichloroethane-d4 (S)%89 67-13090
Toluene-d8 (S)%92 70-13092
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4220274MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699907002
4220275
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,4-Dioxane (p-Dioxane)ug/L 20 96 55-13795 020ND19.1 19.1
1,2-Dichloroethane-d4 (S)%88 67-13089
Toluene-d8 (S)%91 70-13092
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
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Page 27 of 32
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be
considered an estimated value.IH
The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.v2
The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.v3
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 32
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92700176
OCSWM FALL-SOUTH
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92700176001 815698 8158316801-MW101 EPA 3010A EPA 6010D
92700176002 815698 8158316801-MW102S EPA 3010A EPA 6010D
92700176003 815698 8158316801-MW104 EPA 3010A EPA 6010D
92700176004 815698 8158316801-MW111 EPA 3010A EPA 6010D
92700176001 8164016801-MW101 EPA 8260D
92700176002 8164016801-MW102S EPA 8260D
92700176003 8164016801-MW104 EPA 8260D
92700176004 8164056801-MW111 EPA 8260D
92700176005 816401TRIP BLANK 1 EPA 8260D
92700176006 816401TRIP BLANK 2 EPA 8260D
92700176001 8152056801-MW101 EPA 8260D Mod.
92700176002 8152056801-MW102S EPA 8260D Mod.
92700176003 8152056801-MW104 EPA 8260D Mod.
92700176004 8152056801-MW111 EPA 8260D Mod.
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:11 PM
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9800 Kincey Ave. Suite 100
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[phone]
Page 29 of 32
Page 30 of 32
Page 31 of 32
Page 32 of 32
#=CL#
December 06, 2023
LIMS USE: FR - DEBORAH COAKLEY
LIMS OBJECT ID: 92700341
92700341
Project:
Pace Project No.:
RE:
Deborah Ann Coakley
TRC Companies
1030 Wilmer Ave.
Suite 100
Richmond, VA 23227
OCSWM FALL-SOUTH
Dear Deborah Coakley:
Enclosed are the analytical results for sample(s) received by the laboratory on November 27, 2023. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
Some analyses were subcontracted outside of the Pace Network. The test report from the external subcontractor is
attached to this report in its entirety.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Matthew Brainard
[e-mail]
Project Manager
704-977-0942
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 49
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Huntersville, NC 28078
[phone]
Page 2 of 49
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92700341001 6801-MW105 EPA 8081B 21 PASI-CSEM
EPA 8082A 7 PASI-CSEM
EPA 6010D 16 PASI-ADBB1
EPA 7470A 1 PASI-ABM
EPA 8270E 111 PASI-CPKS
EPA 8260D 67 PASI-CLMB
EPA 8260D Mod.3 PASI-CTEG
SM 4500-CN-E-2016 1 PASI-AMMA
92700341002 6801-MW106 EPA 6010D 15 PASI-ADBB1
EPA 8260D 50 PASI-CLMB
EPA 8260D Mod.3 PASI-CTEG
92700341003 6801-MW107 EPA 6010D 15 PASI-ADBB1
EPA 8260D 50 PASI-CLMB
EPA 8260D Mod.3 PASI-CTEG
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 3 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Sample: 6801-MW105 Lab ID: 92700341001 Collected: 11/22/23 09:30 Received: 11/27/23 13:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8081B Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
8081 OC Pesticides RVE
Aldrin ND ug/L 11/29/23 10:36 309-00-211/28/23 09:330.042 1
alpha-BHC ND ug/L 11/29/23 10:36 319-84-611/28/23 09:330.042 1
beta-BHC ND ug/L 11/29/23 10:36 319-85-711/28/23 09:330.042 1
delta-BHC ND ug/L 11/29/23 10:36 319-86-811/28/23 09:330.042 1
gamma-BHC (Lindane)ND ug/L 11/29/23 10:36 58-89-911/28/23 09:330.042 1
Chlordane (Technical)ND ug/L 11/29/23 10:36 57-74-911/28/23 09:330.42 1
4,4'-DDD ND ug/L 11/29/23 10:36 72-54-8 L111/28/23 09:330.042 1
4,4'-DDE ND ug/L 11/29/23 10:36 72-55-9 L111/28/23 09:330.042 1
4,4'-DDT ND ug/L 11/29/23 10:36 50-29-311/28/23 09:330.042 1
Dieldrin ND ug/L 11/29/23 10:36 60-57-1 L111/28/23 09:330.042 1
Endosulfan I ND ug/L 11/29/23 10:36 959-98-811/28/23 09:330.042 1
Endosulfan II ND ug/L 11/29/23 10:36 33213-65-9 L111/28/23 09:330.042 1
Endosulfan sulfate ND ug/L 11/29/23 10:36 1031-07-811/28/23 09:330.042 1
Endrin ND ug/L 11/29/23 10:36 72-20-811/28/23 09:330.042 1
Endrin aldehyde ND ug/L 11/29/23 10:36 7421-93-411/28/23 09:330.042 1
Heptachlor ND ug/L 11/29/23 10:36 76-44-811/28/23 09:330.042 1
Heptachlor epoxide ND ug/L 11/29/23 10:36 1024-57-311/28/23 09:330.042 1
Methoxychlor ND ug/L 11/29/23 10:36 72-43-511/28/23 09:330.12 1
Toxaphene ND ug/L 11/29/23 10:36 8001-35-211/28/23 09:330.42 1
Surrogates
Tetrachloro-m-xylene (S)90 %11/29/23 10:36 877-09-811/28/23 09:3310-137 1
Decachlorobiphenyl (S)145 %11/29/23 10:36 2051-24-311/28/23 09:3319-200 1
Analytical Method: EPA 8082A Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
8082 GCS PCB RVE
PCB-1016 (Aroclor 1016)ND ug/L 11/29/23 15:27 12674-11-211/28/23 09:330.42 1
PCB-1221 (Aroclor 1221)ND ug/L 11/29/23 15:27 11104-28-211/28/23 09:330.42 1
PCB-1232 (Aroclor 1232)ND ug/L 11/29/23 15:27 11141-16-511/28/23 09:330.42 1
PCB-1242 (Aroclor 1242)ND ug/L 11/29/23 15:27 53469-21-911/28/23 09:330.42 1
PCB-1248 (Aroclor 1248)ND ug/L 11/29/23 15:27 12672-29-611/28/23 09:330.42 1
PCB-1254 (Aroclor 1254)ND ug/L 11/29/23 15:27 11097-69-111/28/23 09:330.42 1
Surrogates
Decachlorobiphenyl (S)137 %11/29/23 15:27 2051-24-311/28/23 09:3310-193 1
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services - Asheville
6010 MET ICP
Antimony ND ug/L 12/04/23 22:38 7440-36-011/28/23 12:305.0 1
Arsenic 33.0 ug/L 12/04/23 22:38 7440-38-211/28/23 12:3010.0 1
Barium 5.8 ug/L 12/04/23 22:38 7440-39-311/28/23 12:305.0 1
Beryllium ND ug/L 12/04/23 22:38 7440-41-711/28/23 12:301.0 1
Cadmium ND ug/L 12/04/23 22:38 7440-43-911/28/23 12:301.0 1
Chromium ND ug/L 12/04/23 22:38 7440-47-311/28/23 12:305.0 1
Cobalt 25.8 ug/L 12/04/23 22:38 7440-48-411/28/23 12:305.0 1
Copper ND ug/L 12/04/23 22:38 7440-50-811/28/23 12:305.0 1
Lead ND ug/L 12/04/23 22:38 7439-92-111/28/23 12:305.0 1
Nickel 8.6 ug/L 12/04/23 22:38 7440-02-011/28/23 12:305.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
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Page 4 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Sample: 6801-MW105 Lab ID: 92700341001 Collected: 11/22/23 09:30 Received: 11/27/23 13:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services - Asheville
6010 MET ICP
Selenium ND ug/L 12/04/23 22:38 7782-49-211/28/23 12:3010.0 1
Silver ND ug/L 12/04/23 22:38 7440-22-411/28/23 12:305.0 1
Thallium ND ug/L 12/04/23 22:38 7440-28-011/28/23 12:3010.0 1
Tin ND ug/L 12/04/23 22:38 7440-31-511/28/23 12:305.0 1
Vanadium ND ug/L 12/04/23 22:38 7440-62-211/28/23 12:305.0 1
Zinc ND ug/L 12/04/23 22:38 7440-66-611/28/23 12:3010.0 1
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services - Asheville
7470 Mercury
Mercury ND ug/L 11/30/23 09:37 7439-97-611/29/23 11:350.20 1
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
8270E APP9 RV
Acenaphthene ND ug/L 11/29/23 14:06 83-32-911/28/23 07:5910.0 1
Acenaphthylene ND ug/L 11/29/23 14:06 208-96-811/28/23 07:5910.0 1
Acetophenone ND ug/L 11/29/23 14:06 98-86-211/28/23 07:5910.0 1
2-Acetylaminofluorene ND ug/L 11/29/23 14:06 53-96-311/28/23 07:5910.0 1
4-Aminobiphenyl ND ug/L 11/29/23 14:06 92-67-1 R111/28/23 07:5910.0 1
Anthracene ND ug/L 11/29/23 14:06 120-12-711/28/23 07:5910.0 1
Benzo(a)anthracene ND ug/L 11/29/23 14:06 56-55-311/28/23 07:5910.0 1
Benzo(a)pyrene ND ug/L 11/29/23 14:06 50-32-811/28/23 07:5910.0 1
Benzo(b)fluoranthene ND ug/L 11/29/23 14:06 205-99-211/28/23 07:5910.0 1
Benzo(g,h,i)perylene ND ug/L 11/29/23 14:06 191-24-211/28/23 07:5910.0 1
Benzo(k)fluoranthene ND ug/L 11/29/23 14:06 207-08-911/28/23 07:5910.0 1
Benzyl alcohol ND ug/L 11/29/23 14:06 100-51-611/28/23 07:5920.0 1
4-Bromophenylphenyl ether ND ug/L 11/29/23 14:06 101-55-311/28/23 07:5910.0 1
Butylbenzylphthalate ND ug/L 11/29/23 14:06 85-68-711/28/23 07:5910.0 1
4-Chloro-3-methylphenol ND ug/L 11/29/23 14:06 59-50-711/28/23 07:5910.0 1
4-Chloroaniline ND ug/L 11/29/23 14:06 106-47-8 R111/28/23 07:5920.0 1
Chlorobenzilate ND ug/L 11/29/23 14:06 510-15-611/28/23 07:5910.0 1
bis(2-Chloroethoxy)methane ND ug/L 11/29/23 14:06 111-91-111/28/23 07:5910.0 1
bis(2-Chloroethyl) ether ND ug/L 11/29/23 14:06 111-44-411/28/23 07:5910.0 1
2-Chloronaphthalene ND ug/L 11/29/23 14:06 91-58-711/28/23 07:5910.0 1
2-Chlorophenol ND ug/L 11/29/23 14:06 95-57-811/28/23 07:5910.0 1
4-Chlorophenylphenyl ether ND ug/L 11/29/23 14:06 7005-72-311/28/23 07:5910.0 1
Chrysene ND ug/L 11/29/23 14:06 218-01-911/28/23 07:5910.0 1
Diallate ND ug/L 11/29/23 14:06 2303-16-411/28/23 07:5910.0 1
Dibenz(a,h)anthracene ND ug/L 11/29/23 14:06 53-70-311/28/23 07:5910.0 1
Dibenzofuran ND ug/L 11/29/23 14:06 132-64-911/28/23 07:5910.0 1
3,3'-Dichlorobenzidine ND ug/L 11/29/23 14:06 91-94-111/28/23 07:5920.0 1
2,4-Dichlorophenol ND ug/L 11/29/23 14:06 120-83-211/28/23 07:5910.0 1
2,6-Dichlorophenol ND ug/L 11/29/23 14:06 87-65-011/28/23 07:5910.0 1
Diethylphthalate ND ug/L 11/29/23 14:06 84-66-211/28/23 07:5910.0 1
Dimethoate ND ug/L 11/29/23 14:06 60-51-511/28/23 07:5910.0 1
P-Dimethylaminoazobenzene ND ug/L 11/29/23 14:06 60-11-711/28/23 07:595.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Sample: 6801-MW105 Lab ID: 92700341001 Collected: 11/22/23 09:30 Received: 11/27/23 13:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
8270E APP9 RV
7,12-Dimethylbenz(a)anthracene ND ug/L 11/29/23 14:06 57-97-611/28/23 07:5910.0 1
3,3'-Dimethylbenzidine ND ug/L 11/29/23 14:06 119-93-7 M111/28/23 07:5950.0 1
2,4-Dimethylphenol ND ug/L 11/29/23 14:06 105-67-911/28/23 07:5910.0 1
Dimethylphthalate ND ug/L 11/29/23 14:06 131-11-311/28/23 07:5910.0 1
Di-n-butylphthalate ND ug/L 11/29/23 14:06 84-74-211/28/23 07:5910.0 1
4,6-Dinitro-2-methylphenol ND ug/L 11/29/23 14:06 534-52-111/28/23 07:5920.0 1
1,3-Dinitrobenzene ND ug/L 11/29/23 14:06 99-65-011/28/23 07:5910.0 1
2,4-Dinitrophenol ND ug/L 11/29/23 14:06 51-28-511/28/23 07:5950.0 1
2,4-Dinitrotoluene ND ug/L 11/29/23 14:06 121-14-211/28/23 07:5910.0 1
2,6-Dinitrotoluene ND ug/L 11/29/23 14:06 606-20-211/28/23 07:5910.0 1
Di-n-octylphthalate ND ug/L 11/29/23 14:06 117-84-011/28/23 07:5910.0 1
Diphenylamine ND ug/L 11/29/23 14:06 122-39-411/28/23 07:5910.0 1
Disulfoton ND ug/L 11/29/23 14:06 298-04-411/28/23 07:5910.0 1
bis(2-Ethylhexyl)phthalate ND ug/L 11/29/23 14:06 117-81-711/28/23 07:596.0 1
Ethyl methanesulfonate ND ug/L 11/29/23 14:06 62-50-011/28/23 07:5920.0 1
Famphur ND ug/L 11/29/23 14:06 52-85-711/28/23 07:5910.0 1
Fluoranthene ND ug/L 11/29/23 14:06 206-44-011/28/23 07:5910.0 1
Fluorene ND ug/L 11/29/23 14:06 86-73-711/28/23 07:5910.0 1
Hexachlorobenzene ND ug/L 11/29/23 14:06 118-74-111/28/23 07:5910.0 1
Hexachlorocyclopentadiene ND ug/L 11/29/23 14:06 77-47-411/28/23 07:5910.0 1
Hexachloroethane ND ug/L 11/29/23 14:06 67-72-111/28/23 07:5910.0 1
Hexachloropropene ND ug/L 11/29/23 14:06 1888-71-711/28/23 07:5910.0 1
Indeno(1,2,3-cd)pyrene ND ug/L 11/29/23 14:06 193-39-511/28/23 07:5910.0 1
Isodrin ND ug/L 11/29/23 14:06 465-73-611/28/23 07:5910.0 1
Isophorone ND ug/L 11/29/23 14:06 78-59-111/28/23 07:5910.0 1
Isosafrole ND ug/L 11/29/23 14:06 120-58-111/28/23 07:5910.0 1
Kepone ND ug/L 11/29/23 14:06 143-50-011/28/23 07:5920.0 1
Methapyrilene ND ug/L 11/29/23 14:06 91-80-5 M1,v111/28/23 07:5950.0 1
3-Methylcholanthrene ND ug/L 11/29/23 14:06 56-49-511/28/23 07:5910.0 1
Methyl methanesulfonate ND ug/L 11/29/23 14:06 66-27-311/28/23 07:595.0 1
2-Methylnaphthalene ND ug/L 11/29/23 14:06 91-57-611/28/23 07:5910.0 1
Methyl parathion ND ug/L 11/29/23 14:06 298-00-011/28/23 07:5910.0 1
2-Methylphenol(o-Cresol)ND ug/L 11/29/23 14:06 95-48-711/28/23 07:5910.0 1
3&4-Methylphenol(m&p Cresol)ND ug/L 11/29/23 14:06 15831-10-411/28/23 07:5910.0 1
1-Naphthalenamine ND ug/L 11/29/23 14:06 134-32-711/28/23 07:5910.0 1
2-Naphthalenamine ND ug/L 11/29/23 14:06 91-59-8 M111/28/23 07:5910.0 1
1,4-Naphthoquinone ND ug/L 11/29/23 14:06 130-15-411/28/23 07:595.0 1
2-Nitroaniline ND ug/L 11/29/23 14:06 88-74-411/28/23 07:5920.0 1
3-Nitroaniline ND ug/L 11/29/23 14:06 99-09-211/28/23 07:5920.0 1
4-Nitroaniline ND ug/L 11/29/23 14:06 100-01-611/28/23 07:5920.0 1
Nitrobenzene ND ug/L 11/29/23 14:06 98-95-311/28/23 07:5910.0 1
2-Nitrophenol ND ug/L 11/29/23 14:06 88-75-511/28/23 07:5910.0 1
4-Nitrophenol ND ug/L 11/29/23 14:06 100-02-7 R111/28/23 07:5950.0 1
5-Nitro-o-toluidine ND ug/L 11/29/23 14:06 99-55-811/28/23 07:5910.0 1
N-Nitrosodiethylamine ND ug/L 11/29/23 14:06 55-18-511/28/23 07:5910.0 1
N-Nitrosodimethylamine ND ug/L 11/29/23 14:06 62-75-911/28/23 07:5910.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Sample: 6801-MW105 Lab ID: 92700341001 Collected: 11/22/23 09:30 Received: 11/27/23 13:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
8270E APP9 RV
N-Nitroso-di-n-butylamine ND ug/L 11/29/23 14:06 924-16-311/28/23 07:5910.0 1
N-Nitroso-di-n-propylamine ND ug/L 11/29/23 14:06 621-64-711/28/23 07:5910.0 1
N-Nitrosodiphenylamine ND ug/L 11/29/23 14:06 86-30-611/28/23 07:5910.0 1
N-Nitrosomethylethylamine ND ug/L 11/29/23 14:06 10595-95-611/28/23 07:5910.0 1
N-Nitrosopiperidine ND ug/L 11/29/23 14:06 100-75-411/28/23 07:5910.0 1
N-Nitrosopyrrolidine ND ug/L 11/29/23 14:06 930-55-211/28/23 07:5910.0 1
O,O,O-Triethylphosphorothioate ND ug/L 11/29/23 14:06 126-68-111/28/23 07:5910.0 1
2,2'-Oxybis(1-chloropropane)ND ug/L 11/29/23 14:06 108-60-111/28/23 07:5910.0 1
Parathion (Ethyl parathion)ND ug/L 11/29/23 14:06 56-38-211/28/23 07:5910.0 1
Pentachlorobenzene ND ug/L 11/29/23 14:06 608-93-511/28/23 07:5910.0 1
Pentachloronitrobenzene ND ug/L 11/29/23 14:06 82-68-811/28/23 07:5910.0 1
Pentachlorophenol ND ug/L 11/29/23 14:06 87-86-511/28/23 07:5920.0 1
Phenacetin ND ug/L 11/29/23 14:06 62-44-211/28/23 07:5910.0 1
Phenanthrene ND ug/L 11/29/23 14:06 85-01-811/28/23 07:5910.0 1
Phenol ND ug/L 11/29/23 14:06 108-95-211/28/23 07:5910.0 1
p-Phenylenediamine ND ug/L 11/29/23 14:06 106-50-311/28/23 07:5910.0 1
Phorate ND ug/L 11/29/23 14:06 298-02-211/28/23 07:5910.0 1
Pronamide ND ug/L 11/29/23 14:06 23950-58-511/28/23 07:5910.0 1
Pyrene ND ug/L 11/29/23 14:06 129-00-011/28/23 07:5910.0 1
Safrole ND ug/L 11/29/23 14:06 94-59-711/28/23 07:5910.0 1
1,2,4,5-Tetrachlorobenzene ND ug/L 11/29/23 14:06 95-94-311/28/23 07:5910.0 1
2,3,4,6-Tetrachlorophenol ND ug/L 11/29/23 14:06 58-90-211/28/23 07:5910.0 1
Thionazin ND ug/L 11/29/23 14:06 297-97-211/28/23 07:5910.0 1
O-Toluidine ND ug/L 11/29/23 14:06 95-53-411/28/23 07:5910.0 1
2,4,5-Trichlorophenol ND ug/L 11/29/23 14:06 95-95-411/28/23 07:5910.0 1
2,4,6-Trichlorophenol ND ug/L 11/29/23 14:06 88-06-211/28/23 07:5910.0 1
1,3,5-Trinitrobenzene ND ug/L 11/29/23 14:06 99-35-411/28/23 07:5910.0 1
Surrogates
Nitrobenzene-d5 (S)85 %11/29/23 14:06 4165-60-011/28/23 07:5910-133 1
2-Fluorobiphenyl (S)84 %11/29/23 14:06 321-60-811/28/23 07:5910-130 1
Terphenyl-d14 (S)100 %11/29/23 14:06 1718-51-011/28/23 07:5910-193 1
Phenol-d6 (S)34 %11/29/23 14:06 13127-88-311/28/23 07:5910-130 1
2-Fluorophenol (S)54 %11/29/23 14:06 367-12-411/28/23 07:5910-130 1
2,4,6-Tribromophenol (S)92 %11/29/23 14:06 118-79-611/28/23 07:5910-166 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 11/28/23 15:13 67-64-125.0 1
Acetonitrile ND ug/L 11/28/23 15:13 75-05-850.0 1
Acrolein ND ug/L 11/28/23 15:13 107-02-810.0 1
Acrylonitrile ND ug/L 11/28/23 15:13 107-13-110.0 1
Allyl chloride ND ug/L 11/28/23 15:13 107-05-12.0 1
Benzene ND ug/L 11/28/23 15:13 71-43-21.0 1
Bromochloromethane ND ug/L 11/28/23 15:13 74-97-51.0 1
Bromodichloromethane ND ug/L 11/28/23 15:13 75-27-41.0 1
Bromoform ND ug/L 11/28/23 15:13 75-25-21.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Sample: 6801-MW105 Lab ID: 92700341001 Collected: 11/22/23 09:30 Received: 11/27/23 13:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Bromomethane ND ug/L 11/28/23 15:13 74-83-9 IH,v12.0 1
2-Butanone (MEK)ND ug/L 11/28/23 15:13 78-93-35.0 1
Carbon disulfide ND ug/L 11/28/23 15:13 75-15-02.0 1
Carbon tetrachloride ND ug/L 11/28/23 15:13 56-23-51.0 1
Chlorobenzene ND ug/L 11/28/23 15:13 108-90-71.0 1
Chloroethane ND ug/L 11/28/23 15:13 75-00-31.0 1
Chloroform ND ug/L 11/28/23 15:13 67-66-31.0 1
Chloromethane ND ug/L 11/28/23 15:13 74-87-31.0 1
Chloroprene ND ug/L 11/28/23 15:13 126-99-85.0 1
Dibromochloromethane ND ug/L 11/28/23 15:13 124-48-11.0 1
Dibromomethane ND ug/L 11/28/23 15:13 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 11/28/23 15:13 95-50-11.0 1
1,3-Dichlorobenzene ND ug/L 11/28/23 15:13 541-73-11.0 1
1,4-Dichlorobenzene ND ug/L 11/28/23 15:13 106-46-71.0 1
trans-1,4-Dichloro-2-butene ND ug/L 11/28/23 15:13 110-57-61.0 1
Dichlorodifluoromethane ND ug/L 11/28/23 15:13 75-71-81.0 1
1,1-Dichloroethane ND ug/L 11/28/23 15:13 75-34-31.0 1
1,2-Dichloroethane ND ug/L 11/28/23 15:13 107-06-21.0 1
1,1-Dichloroethene ND ug/L 11/28/23 15:13 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 11/28/23 15:13 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 11/28/23 15:13 156-60-51.0 1
1,2-Dichloropropane ND ug/L 11/28/23 15:13 78-87-51.0 1
1,3-Dichloropropane ND ug/L 11/28/23 15:13 142-28-91.0 1
2,2-Dichloropropane ND ug/L 11/28/23 15:13 594-20-71.0 1
1,1-Dichloropropene ND ug/L 11/28/23 15:13 563-58-61.0 1
cis-1,3-Dichloropropene ND ug/L 11/28/23 15:13 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 11/28/23 15:13 10061-02-61.0 1
Ethylbenzene ND ug/L 11/28/23 15:13 100-41-41.0 1
Ethyl methacrylate ND ug/L 11/28/23 15:13 97-63-21.0 1
Hexachloro-1,3-butadiene ND ug/L 11/28/23 15:13 87-68-32.0 1
2-Hexanone ND ug/L 11/28/23 15:13 591-78-65.0 1
Iodomethane ND ug/L 11/28/23 15:13 74-88-420.0 1
Isobutanol ND ug/L 11/28/23 15:13 78-83-1 v2100 1
Methacrylonitrile ND ug/L 11/28/23 15:13 126-98-710.0 1
Methylene Chloride ND ug/L 11/28/23 15:13 75-09-25.0 1
Methyl methacrylate ND ug/L 11/28/23 15:13 80-62-62.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/28/23 15:13 108-10-15.0 1
Naphthalene ND ug/L 11/28/23 15:13 91-20-31.0 1
Propionitrile ND ug/L 11/28/23 15:13 107-12-020.0 1
Styrene ND ug/L 11/28/23 15:13 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 11/28/23 15:13 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 11/28/23 15:13 79-34-51.0 1
Tetrachloroethene ND ug/L 11/28/23 15:13 127-18-41.0 1
Toluene ND ug/L 11/28/23 15:13 108-88-31.0 1
1,2,4-Trichlorobenzene ND ug/L 11/28/23 15:13 120-82-11.0 1
1,1,1-Trichloroethane ND ug/L 11/28/23 15:13 71-55-61.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Sample: 6801-MW105 Lab ID: 92700341001 Collected: 11/22/23 09:30 Received: 11/27/23 13:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
1,1,2-Trichloroethane ND ug/L 11/28/23 15:13 79-00-51.0 1
Trichloroethene ND ug/L 11/28/23 15:13 79-01-61.0 1
Trichlorofluoromethane ND ug/L 11/28/23 15:13 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 11/28/23 15:13 96-18-41.0 1
Vinyl acetate ND ug/L 11/28/23 15:13 108-05-42.0 1
Vinyl chloride ND ug/L 11/28/23 15:13 75-01-41.0 1
Xylene (Total)ND ug/L 11/28/23 15:13 1330-20-71.0 1
m&p-Xylene ND ug/L 11/28/23 15:13 179601-23-12.0 1
o-Xylene ND ug/L 11/28/23 15:13 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)94 %11/28/23 15:13 460-00-470-130 1
1,2-Dichloroethane-d4 (S)93 %11/28/23 15:13 17060-07-070-130 1
Toluene-d8 (S)99 %11/28/23 15:13 2037-26-570-130 1
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
8260D MSV SIM
1,4-Dioxane (p-Dioxane)ND ug/L 11/28/23 19:47 123-91-12.0 1
Surrogates
1,2-Dichloroethane-d4 (S)99 %11/28/23 19:47 17060-07-067-130 1
Toluene-d8 (S)103 %11/28/23 19:47 2037-26-570-130 1
Analytical Method: SM 4500-CN-E-2016 Preparation Method: SM 4500-CN-E-2016
Pace Analytical Services - Asheville
4500CNE Cyanide, Total
Cyanide ND mg/L 12/01/23 16:36 57-12-511/30/23 18:300.0080 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Sample: 6801-MW106 Lab ID: 92700341002 Collected: 11/22/23 08:55 Received: 11/27/23 13:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services - Asheville
6010 MET ICP
Antimony ND ug/L 12/04/23 22:47 7440-36-011/28/23 12:305.0 1
Arsenic ND ug/L 12/04/23 22:47 7440-38-211/28/23 12:3010.0 1
Barium 13.8 ug/L 12/04/23 22:47 7440-39-311/28/23 12:305.0 1
Beryllium ND ug/L 12/04/23 22:47 7440-41-711/28/23 12:301.0 1
Cadmium ND ug/L 12/04/23 22:47 7440-43-911/28/23 12:301.0 1
Chromium ND ug/L 12/04/23 22:47 7440-47-311/28/23 12:305.0 1
Cobalt ND ug/L 12/04/23 22:47 7440-48-411/28/23 12:305.0 1
Copper ND ug/L 12/04/23 22:47 7440-50-811/28/23 12:305.0 1
Lead ND ug/L 12/04/23 22:47 7439-92-111/28/23 12:305.0 1
Nickel ND ug/L 12/04/23 22:47 7440-02-011/28/23 12:305.0 1
Selenium ND ug/L 12/04/23 22:47 7782-49-211/28/23 12:3010.0 1
Silver ND ug/L 12/04/23 22:47 7440-22-411/28/23 12:305.0 1
Thallium ND ug/L 12/04/23 22:47 7440-28-011/28/23 12:3010.0 1
Vanadium ND ug/L 12/04/23 22:47 7440-62-211/28/23 12:305.0 1
Zinc ND ug/L 12/04/23 22:47 7440-66-611/28/23 12:3010.0 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 11/28/23 15:31 67-64-125.0 1
Acrylonitrile ND ug/L 11/28/23 15:31 107-13-110.0 1
Benzene ND ug/L 11/28/23 15:31 71-43-21.0 1
Bromochloromethane ND ug/L 11/28/23 15:31 74-97-51.0 1
Bromodichloromethane ND ug/L 11/28/23 15:31 75-27-41.0 1
Bromoform ND ug/L 11/28/23 15:31 75-25-21.0 1
Bromomethane ND ug/L 11/28/23 15:31 74-83-9 IH,v12.0 1
2-Butanone (MEK)ND ug/L 11/28/23 15:31 78-93-35.0 1
Carbon disulfide ND ug/L 11/28/23 15:31 75-15-02.0 1
Carbon tetrachloride ND ug/L 11/28/23 15:31 56-23-51.0 1
Chlorobenzene ND ug/L 11/28/23 15:31 108-90-71.0 1
Chloroethane ND ug/L 11/28/23 15:31 75-00-31.0 1
Chloroform ND ug/L 11/28/23 15:31 67-66-31.0 1
Chloromethane ND ug/L 11/28/23 15:31 74-87-31.0 1
Dibromochloromethane ND ug/L 11/28/23 15:31 124-48-11.0 1
Dibromomethane ND ug/L 11/28/23 15:31 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 11/28/23 15:31 95-50-11.0 1
1,4-Dichlorobenzene ND ug/L 11/28/23 15:31 106-46-71.0 1
trans-1,4-Dichloro-2-butene ND ug/L 11/28/23 15:31 110-57-61.0 1
1,1-Dichloroethane ND ug/L 11/28/23 15:31 75-34-31.0 1
1,2-Dichloroethane ND ug/L 11/28/23 15:31 107-06-21.0 1
1,1-Dichloroethene ND ug/L 11/28/23 15:31 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 11/28/23 15:31 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 11/28/23 15:31 156-60-51.0 1
1,2-Dichloropropane ND ug/L 11/28/23 15:31 78-87-51.0 1
cis-1,3-Dichloropropene ND ug/L 11/28/23 15:31 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 11/28/23 15:31 10061-02-61.0 1
Ethylbenzene ND ug/L 11/28/23 15:31 100-41-41.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Sample: 6801-MW106 Lab ID: 92700341002 Collected: 11/22/23 08:55 Received: 11/27/23 13:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
2-Hexanone ND ug/L 11/28/23 15:31 591-78-65.0 1
Iodomethane ND ug/L 11/28/23 15:31 74-88-420.0 1
Methylene Chloride ND ug/L 11/28/23 15:31 75-09-25.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/28/23 15:31 108-10-15.0 1
Styrene ND ug/L 11/28/23 15:31 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 11/28/23 15:31 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 11/28/23 15:31 79-34-51.0 1
Tetrachloroethene ND ug/L 11/28/23 15:31 127-18-41.0 1
Toluene ND ug/L 11/28/23 15:31 108-88-31.0 1
1,1,1-Trichloroethane ND ug/L 11/28/23 15:31 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 11/28/23 15:31 79-00-51.0 1
Trichloroethene ND ug/L 11/28/23 15:31 79-01-61.0 1
Trichlorofluoromethane ND ug/L 11/28/23 15:31 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 11/28/23 15:31 96-18-41.0 1
Vinyl acetate ND ug/L 11/28/23 15:31 108-05-42.0 1
Vinyl chloride ND ug/L 11/28/23 15:31 75-01-41.0 1
Xylene (Total)ND ug/L 11/28/23 15:31 1330-20-71.0 1
m&p-Xylene ND ug/L 11/28/23 15:31 179601-23-12.0 1
o-Xylene ND ug/L 11/28/23 15:31 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)96 %11/28/23 15:31 460-00-470-130 1
1,2-Dichloroethane-d4 (S)91 %11/28/23 15:31 17060-07-070-130 1
Toluene-d8 (S)101 %11/28/23 15:31 2037-26-570-130 1
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
8260D MSV SIM
1,4-Dioxane (p-Dioxane)ND ug/L 11/28/23 20:06 123-91-12.0 1
Surrogates
1,2-Dichloroethane-d4 (S)101 %11/28/23 20:06 17060-07-067-130 1
Toluene-d8 (S)104 %11/28/23 20:06 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Sample: 6801-MW107 Lab ID: 92700341003 Collected: 11/22/23 08:15 Received: 11/27/23 13:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services - Asheville
6010 MET ICP
Antimony ND ug/L 12/04/23 22:50 7440-36-011/28/23 12:305.0 1
Arsenic ND ug/L 12/04/23 22:50 7440-38-211/28/23 12:3010.0 1
Barium 7.0 ug/L 12/04/23 22:50 7440-39-311/28/23 12:305.0 1
Beryllium ND ug/L 12/04/23 22:50 7440-41-711/28/23 12:301.0 1
Cadmium ND ug/L 12/04/23 22:50 7440-43-911/28/23 12:301.0 1
Chromium ND ug/L 12/04/23 22:50 7440-47-311/28/23 12:305.0 1
Cobalt ND ug/L 12/04/23 22:50 7440-48-411/28/23 12:305.0 1
Copper ND ug/L 12/04/23 22:50 7440-50-811/28/23 12:305.0 1
Lead ND ug/L 12/04/23 22:50 7439-92-111/28/23 12:305.0 1
Nickel ND ug/L 12/04/23 22:50 7440-02-011/28/23 12:305.0 1
Selenium ND ug/L 12/04/23 22:50 7782-49-211/28/23 12:3010.0 1
Silver ND ug/L 12/04/23 22:50 7440-22-411/28/23 12:305.0 1
Thallium ND ug/L 12/04/23 22:50 7440-28-011/28/23 12:3010.0 1
Vanadium ND ug/L 12/04/23 22:50 7440-62-211/28/23 12:305.0 1
Zinc ND ug/L 12/04/23 22:50 7440-66-611/28/23 12:3010.0 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 11/28/23 15:50 67-64-125.0 1
Acrylonitrile ND ug/L 11/28/23 15:50 107-13-110.0 1
Benzene ND ug/L 11/28/23 15:50 71-43-21.0 1
Bromochloromethane ND ug/L 11/28/23 15:50 74-97-51.0 1
Bromodichloromethane ND ug/L 11/28/23 15:50 75-27-41.0 1
Bromoform ND ug/L 11/28/23 15:50 75-25-21.0 1
Bromomethane ND ug/L 11/28/23 15:50 74-83-9 IH,v12.0 1
2-Butanone (MEK)ND ug/L 11/28/23 15:50 78-93-35.0 1
Carbon disulfide ND ug/L 11/28/23 15:50 75-15-02.0 1
Carbon tetrachloride ND ug/L 11/28/23 15:50 56-23-51.0 1
Chlorobenzene ND ug/L 11/28/23 15:50 108-90-71.0 1
Chloroethane ND ug/L 11/28/23 15:50 75-00-31.0 1
Chloroform ND ug/L 11/28/23 15:50 67-66-31.0 1
Chloromethane ND ug/L 11/28/23 15:50 74-87-31.0 1
Dibromochloromethane ND ug/L 11/28/23 15:50 124-48-11.0 1
Dibromomethane ND ug/L 11/28/23 15:50 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 11/28/23 15:50 95-50-11.0 1
1,4-Dichlorobenzene ND ug/L 11/28/23 15:50 106-46-71.0 1
trans-1,4-Dichloro-2-butene ND ug/L 11/28/23 15:50 110-57-61.0 1
1,1-Dichloroethane ND ug/L 11/28/23 15:50 75-34-31.0 1
1,2-Dichloroethane ND ug/L 11/28/23 15:50 107-06-21.0 1
1,1-Dichloroethene ND ug/L 11/28/23 15:50 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 11/28/23 15:50 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 11/28/23 15:50 156-60-51.0 1
1,2-Dichloropropane ND ug/L 11/28/23 15:50 78-87-51.0 1
cis-1,3-Dichloropropene ND ug/L 11/28/23 15:50 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 11/28/23 15:50 10061-02-61.0 1
Ethylbenzene ND ug/L 11/28/23 15:50 100-41-41.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Sample: 6801-MW107 Lab ID: 92700341003 Collected: 11/22/23 08:15 Received: 11/27/23 13:45 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
2-Hexanone ND ug/L 11/28/23 15:50 591-78-65.0 1
Iodomethane ND ug/L 11/28/23 15:50 74-88-420.0 1
Methylene Chloride ND ug/L 11/28/23 15:50 75-09-25.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/28/23 15:50 108-10-15.0 1
Styrene ND ug/L 11/28/23 15:50 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 11/28/23 15:50 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 11/28/23 15:50 79-34-51.0 1
Tetrachloroethene ND ug/L 11/28/23 15:50 127-18-41.0 1
Toluene ND ug/L 11/28/23 15:50 108-88-31.0 1
1,1,1-Trichloroethane ND ug/L 11/28/23 15:50 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 11/28/23 15:50 79-00-51.0 1
Trichloroethene ND ug/L 11/28/23 15:50 79-01-61.0 1
Trichlorofluoromethane ND ug/L 11/28/23 15:50 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 11/28/23 15:50 96-18-41.0 1
Vinyl acetate ND ug/L 11/28/23 15:50 108-05-42.0 1
Vinyl chloride ND ug/L 11/28/23 15:50 75-01-41.0 1
Xylene (Total)ND ug/L 11/28/23 15:50 1330-20-71.0 1
m&p-Xylene ND ug/L 11/28/23 15:50 179601-23-12.0 1
o-Xylene ND ug/L 11/28/23 15:50 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)96 %11/28/23 15:50 460-00-470-130 1
1,2-Dichloroethane-d4 (S)95 %11/28/23 15:50 17060-07-070-130 1
Toluene-d8 (S)101 %11/28/23 15:50 2037-26-570-130 1
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
8260D MSV SIM
1,4-Dioxane (p-Dioxane)ND ug/L 11/28/23 20:25 123-91-12.0 1
Surrogates
1,2-Dichloroethane-d4 (S)98 %11/28/23 20:25 17060-07-067-130 1
Toluene-d8 (S)102 %11/28/23 20:25 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
816038
EPA 7470A
EPA 7470A
7470 Mercury
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples: 92700341001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4223715
Associated Lab Samples:92700341001
Matrix: Water
Analyzed
Mercury ug/L ND 0.20 11/30/23 09:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4223716LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.62.5 103 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4223717MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92700370002
4223718
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Mercury ug/L 2.5 99 75-125100 22.5ND 2.5 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815698
EPA 3010A
EPA 6010D
6010 MET
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples: 92700341001, 92700341002, 92700341003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4222044
Associated Lab Samples:92700341001, 92700341002, 92700341003
Matrix: Water
Analyzed
Antimony ug/L ND 5.0 12/04/23 21:22
Arsenic ug/L ND 10.0 12/04/23 21:22
Barium ug/L ND 5.0 12/05/23 20:09
Beryllium ug/L ND 1.0 12/04/23 21:22
Cadmium ug/L ND 1.0 12/04/23 21:22
Chromium ug/L ND 5.0 12/04/23 21:22
Cobalt ug/L ND 5.0 12/04/23 21:22
Copper ug/L ND 5.0 12/04/23 21:22
Lead ug/L ND 5.0 12/04/23 21:22
Nickel ug/L ND 5.0 12/04/23 21:22
Selenium ug/L ND 10.0 12/04/23 21:22
Silver ug/L ND 5.0 12/04/23 21:22
Thallium ug/L ND 10.0 12/04/23 21:22
Tin ug/L ND 5.0 12/04/23 21:22
Vanadium ug/L ND 5.0 12/04/23 21:22
Zinc ug/L ND 10.0 12/04/23 21:22
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4222045LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 520500 104 80-120
Arsenic ug/L 525500 105 80-120
Barium ug/L 508500 102 80-120
Beryllium ug/L 515500 103 80-120
Cadmium ug/L 524500 105 80-120
Chromium ug/L 519500 104 80-120
Cobalt ug/L 516500 103 80-120
Copper ug/L 518500 104 80-120
Lead ug/L 518500 104 80-120
Nickel ug/L 516500 103 80-120
Selenium ug/L 510500 102 80-120
Silver ug/L 260250 104 80-120
Thallium ug/L 525500 105 80-120
Tin ug/L 515500 103 80-120
Vanadium ug/L 515500 103 80-120
Zinc ug/L 512500 102 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4222046MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92700200001
4222047
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Antimony ug/L 500 106 75-125107 2500ND528 536
Arsenic ug/L 500 108 75-125109 1500ND540 546
Barium ug/L 500 96 75-12599 350019.1 498 514
Beryllium ug/L 500 105 75-125106 1500ND526 532
Cadmium ug/L 500 105 75-125106 0500ND528 529
Chromium ug/L 500 103 75-125104 1500ND515 520
Cobalt ug/L 500 102 75-125103 1500ND512 517
Copper ug/L 500 102 75-125105 2500ND516 527
Lead ug/L 500 103 75-125103 0500ND514 516
Nickel ug/L 500 102 75-125103 1500ND512 516
Selenium ug/L 500 106 75-125108 2500ND533 543
Silver ug/L 250 103 75-125105 2250ND258 263
Thallium ug/L 500 102 75-125103 1500ND509 516
Tin ug/L 500 104 75-125105 1500ND521 528
Vanadium ug/L 500 103 75-125104 1500ND517 522
Zinc ug/L 500 105 75-125104 050050.2 573 572
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815704
EPA 8260D
EPA 8260D
8260D MSV Low Level Landfill
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples: 92700341001, 92700341002, 92700341003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4222072
Associated Lab Samples:92700341001, 92700341002, 92700341003
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 1.0 11/28/23 11:50
1,1,1-Trichloroethane ug/L ND 1.0 11/28/23 11:50
1,1,2,2-Tetrachloroethane ug/L ND 1.0 11/28/23 11:50
1,1,2-Trichloroethane ug/L ND 1.0 11/28/23 11:50
1,1-Dichloroethane ug/L ND 1.0 11/28/23 11:50
1,1-Dichloroethene ug/L ND 1.0 11/28/23 11:50
1,1-Dichloropropene ug/L ND 1.0 11/28/23 11:50
1,2,3-Trichloropropane ug/L ND 1.0 11/28/23 11:50
1,2,4-Trichlorobenzene ug/L ND 1.0 11/28/23 11:50
1,2-Dichlorobenzene ug/L ND 1.0 11/28/23 11:50
1,2-Dichloroethane ug/L ND 1.0 11/28/23 11:50
1,2-Dichloropropane ug/L ND 1.0 11/28/23 11:50
1,3-Dichlorobenzene ug/L ND 1.0 11/28/23 11:50
1,3-Dichloropropane ug/L ND 1.0 11/28/23 11:50
1,4-Dichlorobenzene ug/L ND 1.0 11/28/23 11:50
2,2-Dichloropropane ug/L ND 1.0 11/28/23 11:50
2-Butanone (MEK)ug/L ND 5.0 11/28/23 11:50
2-Hexanone ug/L ND 5.0 11/28/23 11:50
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 11/28/23 11:50
Acetone ug/L ND 25.0 11/28/23 11:50
Acetonitrile ug/L ND 50.0 11/28/23 11:50
Acrolein ug/L ND 10.0 11/28/23 11:50
Acrylonitrile ug/L ND 10.0 11/28/23 11:50
Allyl chloride ug/L ND 2.0 11/28/23 11:50
Benzene ug/L ND 1.0 11/28/23 11:50
Bromochloromethane ug/L ND 1.0 11/28/23 11:50
Bromodichloromethane ug/L ND 1.0 11/28/23 11:50
Bromoform ug/L ND 1.0 11/28/23 11:50
Bromomethane ug/L ND 2.0 IH,v111/28/23 11:50
Carbon disulfide ug/L ND 2.0 11/28/23 11:50
Carbon tetrachloride ug/L ND 1.0 11/28/23 11:50
Chlorobenzene ug/L ND 1.0 11/28/23 11:50
Chloroethane ug/L ND 1.0 11/28/23 11:50
Chloroform ug/L ND 1.0 11/28/23 11:50
Chloromethane ug/L ND 1.0 11/28/23 11:50
Chloroprene ug/L ND 5.0 11/28/23 11:50
cis-1,2-Dichloroethene ug/L ND 1.0 11/28/23 11:50
cis-1,3-Dichloropropene ug/L ND 1.0 11/28/23 11:50
Dibromochloromethane ug/L ND 1.0 11/28/23 11:50
Dibromomethane ug/L ND 1.0 11/28/23 11:50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4222072
Associated Lab Samples:92700341001, 92700341002, 92700341003
Matrix: Water
Analyzed
Dichlorodifluoromethane ug/L ND 1.0 11/28/23 11:50
Ethyl methacrylate ug/L ND 1.0 11/28/23 11:50
Ethylbenzene ug/L ND 1.0 11/28/23 11:50
Hexachloro-1,3-butadiene ug/L ND 2.0 11/28/23 11:50
Iodomethane ug/L ND 20.0 11/28/23 11:50
Isobutanol ug/L ND 100 v211/28/23 11:50
m&p-Xylene ug/L ND 2.0 11/28/23 11:50
Methacrylonitrile ug/L ND 10.0 11/28/23 11:50
Methyl methacrylate ug/L ND 2.0 11/28/23 11:50
Methylene Chloride ug/L ND 5.0 11/28/23 11:50
Naphthalene ug/L ND 1.0 11/28/23 11:50
o-Xylene ug/L ND 1.0 11/28/23 11:50
Propionitrile ug/L ND 20.0 11/28/23 11:50
Styrene ug/L ND 1.0 11/28/23 11:50
Tetrachloroethene ug/L ND 1.0 11/28/23 11:50
Toluene ug/L ND 1.0 11/28/23 11:50
trans-1,2-Dichloroethene ug/L ND 1.0 11/28/23 11:50
trans-1,3-Dichloropropene ug/L ND 1.0 11/28/23 11:50
trans-1,4-Dichloro-2-butene ug/L ND 1.0 11/28/23 11:50
Trichloroethene ug/L ND 1.0 11/28/23 11:50
Trichlorofluoromethane ug/L ND 1.0 11/28/23 11:50
Vinyl acetate ug/L ND 2.0 11/28/23 11:50
Vinyl chloride ug/L ND 1.0 11/28/23 11:50
Xylene (Total)ug/L ND 1.0 11/28/23 11:50
1,2-Dichloroethane-d4 (S)%95 70-130 11/28/23 11:50
4-Bromofluorobenzene (S)%96 70-130 11/28/23 11:50
Toluene-d8 (S)%102 70-130 11/28/23 11:50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4222073LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 22.520 112 70-130
1,1,1-Trichloroethane ug/L 21.520 107 70-130
1,1,2,2-Tetrachloroethane ug/L 21.620 108 70-130
1,1,2-Trichloroethane ug/L 20.920 104 70-130
1,1-Dichloroethane ug/L 19.920 99 70-130
1,1-Dichloroethene ug/L 22.420 112 69-131
1,1-Dichloropropene ug/L 23.220 116 70-132
1,2,3-Trichloropropane ug/L 20.320 102 70-130
1,2,4-Trichlorobenzene ug/L 22.220 111 70-130
1,2-Dichlorobenzene ug/L 22.020 110 70-130
1,2-Dichloroethane ug/L 19.720 99 70-130
1,2-Dichloropropane ug/L 21.320 107 70-130
1,3-Dichlorobenzene ug/L 22.220 111 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4222073LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichloropropane ug/L 20.520 102 70-130
1,4-Dichlorobenzene ug/L 21.620 108 70-130
2,2-Dichloropropane ug/L 21.620 108 69-130
2-Butanone (MEK)ug/L 40.240 101 67-133
2-Hexanone ug/L 39.040 98 70-133
4-Methyl-2-pentanone (MIBK)ug/L 40.940 102 70-130
Acetone ug/L 35.440 89 67-130
Acetonitrile ug/L 195200 98 70-130
Acrolein ug/L 99.7100 100 53-166
Acrylonitrile ug/L 103100 103 70-130
Allyl chloride ug/L 20.720 103 69-130
Benzene ug/L 21.620 108 70-130
Bromochloromethane ug/L 20.520 102 70-130
Bromodichloromethane ug/L 20.220 101 70-130
Bromoform ug/L 21.020 105 70-133
Bromomethane ug/L 27.7 IH,v120138 41-148
Carbon disulfide ug/L 22.720 114 70-131
Carbon tetrachloride ug/L 23.220 116 70-130
Chlorobenzene ug/L 21.620 108 70-130
Chloroethane ug/L 23.720 119 41-157
Chloroform ug/L 21.020 105 70-130
Chloromethane ug/L 25.420 127 59-141
Chloroprene ug/L 19.820 99 70-130
cis-1,2-Dichloroethene ug/L 20.620 103 70-130
cis-1,3-Dichloropropene ug/L 21.020 105 70-130
Dibromochloromethane ug/L 20.820 104 70-130
Dibromomethane ug/L 22.020 110 70-130
Dichlorodifluoromethane ug/L 25.920 130 54-147
Ethyl methacrylate ug/L 19.920 100 70-130
Ethylbenzene ug/L 21.320 107 70-130
Hexachloro-1,3-butadiene ug/L 23.720 119 70-134
Iodomethane ug/L 39.840 99 57-140
Isobutanol ug/L 363 v340091 67-136
m&p-Xylene ug/L 42.540 106 70-130
Methacrylonitrile ug/L 191200 95 70-130
Methyl methacrylate ug/L 19.820 99 70-130
Methylene Chloride ug/L 19.820 99 62-130
Naphthalene ug/L 20.620 103 70-135
o-Xylene ug/L 20.920 105 70-130
Propionitrile ug/L 203200 101 70-130
Styrene ug/L 21.620 108 70-130
Tetrachloroethene ug/L 21.920 110 70-130
Toluene ug/L 21.020 105 70-130
trans-1,2-Dichloroethene ug/L 21.020 105 70-130
trans-1,3-Dichloropropene ug/L 21.220 106 70-130
trans-1,4-Dichloro-2-butene ug/L 21.520 108 57-149
Trichloroethene ug/L 22.120 111 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4222073LABORATORY CONTROL SAMPLE:
LCSSpike
Trichlorofluoromethane ug/L 24.920 125 57-130
Vinyl acetate ug/L 39.340 98 70-141
Vinyl chloride ug/L 23.920 119 66-140
Xylene (Total)ug/L 63.460 106 70-130
1,2-Dichloroethane-d4 (S)%92 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
4222075MATRIX SPIKE SAMPLE:
MSSpike
Result
92700341003
1,1,1,2-Tetrachloroethane ug/L 23.920 119 70-146ND
1,1,1-Trichloroethane ug/L 24.920 125 70-150ND
1,1,2,2-Tetrachloroethane ug/L 23.020 115 66-144ND
1,1,2-Trichloroethane ug/L 22.820 114 70-142ND
1,1-Dichloroethane ug/L 23.120 115 68-150ND
1,1-Dichloroethene ug/L 25.720 128 64-162ND
1,1-Dichloropropene ug/L 26.620 133 70-160ND
1,2,3-Trichloropropane ug/L 21.620 108 66-144ND
1,2,4-Trichlorobenzene ug/L 24.020 120 69-147ND
1,2-Dichlorobenzene ug/L 23.720 119 70-142ND
1,2-Dichloroethane ug/L 20.920 105 68-145ND
1,2-Dichloropropane ug/L 23.820 119 70-144ND
1,3-Dichlorobenzene ug/L 24.020 120 70-142ND
1,3-Dichloropropane ug/L 21.820 109 70-141ND
1,4-Dichlorobenzene ug/L 23.320 117 70-140ND
2,2-Dichloropropane ug/L 24.820 124 58-160ND
2-Butanone (MEK)ug/L 41.040 103 57-156ND
2-Hexanone ug/L 40.440 101 62-153ND
4-Methyl-2-pentanone (MIBK)ug/L 42.240 105 65-144ND
Acetone ug/L 32.840 82 49-162ND
Acetonitrile ug/L 203200 101 69-145ND
Acrolein ug/L 94.6100 95 10-200ND
Acrylonitrile ug/L 104100 104 59-155ND
Allyl chloride ug/L 23.720 119 70-146ND
Benzene ug/L 24.220 121 68-144ND
Bromochloromethane ug/L 22.720 114 70-148ND
Bromodichloromethane ug/L 22.620 113 70-141ND
Bromoform ug/L 23.020 115 59-144ND
Bromomethane ug/L 26.1 IH20130 23-190ND
Carbon disulfide ug/L 26.220 131 64-160ND
Carbon tetrachloride ug/L 27.120 135 70-147ND
Chlorobenzene ug/L 23.820 119 70-143ND
Chloroethane ug/L 27.820 139 55-190ND
Chloroform ug/L 21.720 108 67-148ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
4222075MATRIX SPIKE SAMPLE:
MSSpike
Result
92700341003
Chloromethane ug/L 28.020 140 38-180ND
Chloroprene ug/L 22.620 113 70-148ND
cis-1,2-Dichloroethene ug/L 23.120 116 67-151ND
cis-1,3-Dichloropropene ug/L 22.620 113 70-142ND
Dibromochloromethane ug/L 22.720 114 68-140ND
Dibromomethane ug/L 23.420 117 70-142ND
Dichlorodifluoromethane ug/L 29.320 147 15-200ND
Ethyl methacrylate ug/L 21.420 107 68-139ND
Ethylbenzene ug/L 23.520 118 70-145ND
Hexachloro-1,3-butadiene ug/L 26.620 133 64-164ND
Iodomethane ug/L 45.940 115 37-160ND
Isobutanol ug/L 366400 92 53-152ND
m&p-Xylene ug/L 47.240 118 70-148ND
Methacrylonitrile ug/L 197200 98 70-137ND
Methyl methacrylate ug/L 21.220 106 69-134ND
Methylene Chloride ug/L 21.620 108 54-149ND
Naphthalene ug/L 20.520 102 62-154ND
o-Xylene ug/L 23.520 118 70-145ND
Propionitrile ug/L 207200 104 70-136ND
Styrene ug/L 23.520 118 70-147ND
Tetrachloroethene ug/L 25.520 127 70-145ND
Toluene ug/L 23.420 117 65-146ND
trans-1,2-Dichloroethene ug/L 23.620 118 69-155ND
trans-1,3-Dichloropropene ug/L 22.920 115 70-142ND
trans-1,4-Dichloro-2-butene ug/L 19.520 98 39-149ND
Trichloroethene ug/L 25.420 127 70-152ND
Trichlorofluoromethane ug/L 29.520 147 60-158ND
Vinyl acetate ug/L 44.240 111 56-157ND
Vinyl chloride ug/L 27.920 140 51-178ND
Xylene (Total)ug/L 70.760 118 70-146ND
1,2-Dichloroethane-d4 (S)%87 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
Dup
Result QualifiersRPDResult
92700341002
4222074SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L NDND
1,1,1-Trichloroethane ug/L NDND
1,1,2,2-Tetrachloroethane ug/L NDND
1,1,2-Trichloroethane ug/L NDND
1,1-Dichloroethane ug/L NDND
1,1-Dichloroethene ug/L NDND
1,1-Dichloropropene ug/L NDND
1,2,3-Trichloropropane ug/L NDND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result QualifiersRPDResult
92700341002
4222074SAMPLE DUPLICATE:
1,2,4-Trichlorobenzene ug/L NDND
1,2-Dichlorobenzene ug/L NDND
1,2-Dichloroethane ug/L NDND
1,2-Dichloropropane ug/L NDND
1,3-Dichlorobenzene ug/L NDND
1,3-Dichloropropane ug/L NDND
1,4-Dichlorobenzene ug/L NDND
2,2-Dichloropropane ug/L NDND
2-Butanone (MEK)ug/L NDND
2-Hexanone ug/L NDND
4-Methyl-2-pentanone (MIBK)ug/L NDND
Acetone ug/L NDND
Acetonitrile ug/L NDND
Acrolein ug/L NDND
Acrylonitrile ug/L NDND
Allyl chloride ug/L NDND
Benzene ug/L NDND
Bromochloromethane ug/L NDND
Bromodichloromethane ug/L NDND
Bromoform ug/L NDND
Bromomethane ug/L ND IHND
Carbon disulfide ug/L NDND
Carbon tetrachloride ug/L NDND
Chlorobenzene ug/L NDND
Chloroethane ug/L NDND
Chloroform ug/L NDND
Chloromethane ug/L NDND
Chloroprene ug/L NDND
cis-1,2-Dichloroethene ug/L NDND
cis-1,3-Dichloropropene ug/L NDND
Dibromochloromethane ug/L NDND
Dibromomethane ug/L NDND
Dichlorodifluoromethane ug/L NDND
Ethyl methacrylate ug/L NDND
Ethylbenzene ug/L NDND
Hexachloro-1,3-butadiene ug/L NDND
Iodomethane ug/L NDND
Isobutanol ug/L NDND
m&p-Xylene ug/L NDND
Methacrylonitrile ug/L NDND
Methyl methacrylate ug/L NDND
Methylene Chloride ug/L NDND
Naphthalene ug/L NDND
o-Xylene ug/L NDND
Propionitrile ug/L NDND
Styrene ug/L NDND
Tetrachloroethene ug/L NDND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result QualifiersRPDResult
92700341002
4222074SAMPLE DUPLICATE:
Toluene ug/L NDND
trans-1,2-Dichloroethene ug/L NDND
trans-1,3-Dichloropropene ug/L NDND
trans-1,4-Dichloro-2-butene ug/L NDND
Trichloroethene ug/L NDND
Trichlorofluoromethane ug/L NDND
Vinyl acetate ug/L NDND
Vinyl chloride ug/L NDND
Xylene (Total)ug/L NDND
1,2-Dichloroethane-d4 (S)%8991
4-Bromofluorobenzene (S)%9596
Toluene-d8 (S)%101101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815360
EPA 8260D Mod.
EPA 8260D Mod.
8260D MSV SIM
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples: 92700341001, 92700341002, 92700341003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4220870
Associated Lab Samples:92700341001, 92700341002, 92700341003
Matrix: Water
Analyzed
1,4-Dioxane (p-Dioxane)ug/L ND 2.0 11/28/23 14:20
1,2-Dichloroethane-d4 (S)%97 67-130 11/28/23 14:20
Toluene-d8 (S)%101 70-130 11/28/23 14:20
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4220871LABORATORY CONTROL SAMPLE:
LCSSpike
1,4-Dioxane (p-Dioxane)ug/L 23.020 115 70-130
1,2-Dichloroethane-d4 (S)%98 67-130
Toluene-d8 (S)%101 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4220872MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92700242002
4220873
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,4-Dioxane (p-Dioxane)ug/L 20 92 55-13790 320ND18.7 18.2
1,2-Dichloroethane-d4 (S)%100 67-130100
Toluene-d8 (S)%104 70-130103
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815639
EPA 3510C
EPA 8081B
8081 OC Pesticides Red Vol
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples: 92700341001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4221866
Associated Lab Samples:92700341001
Matrix: Water
Analyzed
4,4'-DDD ug/L ND 0.050 11/29/23 11:27
4,4'-DDE ug/L ND 0.050 11/29/23 11:27
4,4'-DDT ug/L ND 0.050 11/29/23 11:27
Aldrin ug/L ND 0.050 11/29/23 11:27
alpha-BHC ug/L ND 0.050 11/29/23 11:27
beta-BHC ug/L ND 0.050 11/29/23 11:27
Chlordane (Technical)ug/L ND 0.50 11/29/23 11:27
delta-BHC ug/L ND 0.050 11/29/23 11:27
Dieldrin ug/L ND 0.050 11/29/23 11:27
Endosulfan I ug/L ND 0.050 11/29/23 11:27
Endosulfan II ug/L ND 0.050 11/29/23 11:27
Endosulfan sulfate ug/L ND 0.050 11/29/23 11:27
Endrin ug/L ND 0.050 11/29/23 11:27
Endrin aldehyde ug/L ND 0.050 11/29/23 11:27
gamma-BHC (Lindane)ug/L ND 0.050 11/29/23 11:27
Heptachlor ug/L ND 0.050 11/29/23 11:27
Heptachlor epoxide ug/L ND 0.050 11/29/23 11:27
Methoxychlor ug/L ND 0.15 11/29/23 11:27
Toxaphene ug/L ND 0.50 11/29/23 11:27
Decachlorobiphenyl (S)%86 19-200 11/29/23 11:27
Tetrachloro-m-xylene (S)%113 10-137 11/29/23 11:27
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4221867LABORATORY CONTROL SAMPLE:
LCSSpike
4,4'-DDD ug/L 0.56 L10.25 224 27-195
4,4'-DDE ug/L 0.46 L10.25 185 24-178
4,4'-DDT ug/L 0.440.25 175 25-200
Aldrin ug/L 0.220.25 90 14-135
alpha-BHC ug/L 0.350.25 141 30-146
beta-BHC ug/L 0.370.25 146 38-158
delta-BHC ug/L 0.310.25 123 10-185
Dieldrin ug/L 0.46 L10.25 183 26-180
Endosulfan I ug/L 0.350.25 140 36-154
Endosulfan II ug/L 0.40 L10.25 162 38-155
Endosulfan sulfate ug/L 0.370.25 147 42-170
Endrin ug/L 0.470.25 187 33-190
Endrin aldehyde ug/L 0.360.25 143 33-153
gamma-BHC (Lindane)ug/L 0.360.25 143 32-148
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4221867LABORATORY CONTROL SAMPLE:
LCSSpike
Heptachlor ug/L 0.300.25 122 32-149
Heptachlor epoxide ug/L 0.360.25 143 37-149
Methoxychlor ug/L 1.10.75 143 35-171
Decachlorobiphenyl (S)%147 19-200
Tetrachloro-m-xylene (S)%121 10-137
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4221868MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92700341001
4221869
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
4,4'-DDD ug/L 0.42 135 10-200160 170.42ND 0.56 0.67
4,4'-DDE ug/L 0.42 125 10-188146 150.42ND 0.52 0.61
4,4'-DDT ug/L 0.42 113 10-200135 170.42ND 0.47 0.56
Aldrin ug/L 0.42 69 10-14485 210.42ND 0.29 0.36
alpha-BHC ug/L 0.42 96 21-151110 130.42ND 0.40 0.46
beta-BHC ug/L 0.42 100 21-175117 160.42ND 0.42 0.49
delta-BHC ug/L 0.42 96 15-163110 140.42ND 0.40 0.46
Dieldrin ug/L 0.42 129 10-184146 120.42ND 0.54 0.61
Endosulfan I ug/L 0.42 96 11-180109 120.42ND 0.40 0.45
Endosulfan II ug/L 0.42 103 13-174122 170.42ND 0.43 0.51
Endosulfan sulfate ug/L 0.42 101 25-182119 170.42ND 0.42 0.50
Endrin ug/L 0.42 125 10-200144 150.42ND 0.52 0.60
Endrin aldehyde ug/L 0.42 89 10-167114 240.42ND 0.37 0.47
gamma-BHC (Lindane)ug/L 0.42 97 13-163111 130.42ND 0.40 0.46
Heptachlor ug/L 0.42 101 10-172109 80.42ND 0.42 0.46
Heptachlor epoxide ug/L 0.42 101 10-168114 120.42ND 0.42 0.47
Methoxychlor ug/L 1.2 98 13-183115 161.2ND 1.2 1.4
Decachlorobiphenyl (S)%105 19-200125
Tetrachloro-m-xylene (S)%78 10-13787
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815640
EPA 3510C
EPA 8082A
8082 GCS PCB
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples: 92700341001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4221870
Associated Lab Samples:92700341001
Matrix: Water
Analyzed
PCB-1016 (Aroclor 1016)ug/L ND 0.50 11/29/23 15:52
PCB-1221 (Aroclor 1221)ug/L ND 0.50 11/29/23 15:52
PCB-1232 (Aroclor 1232)ug/L ND 0.50 11/29/23 15:52
PCB-1242 (Aroclor 1242)ug/L ND 0.50 11/29/23 15:52
PCB-1248 (Aroclor 1248)ug/L ND 0.50 11/29/23 15:52
PCB-1254 (Aroclor 1254)ug/L ND 0.50 11/29/23 15:52
Decachlorobiphenyl (S)%141 10-193 11/29/23 15:52
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4221871LABORATORY CONTROL SAMPLE:
LCSSpike
PCB-1016 (Aroclor 1016)ug/L 4.55 89 34-137
Decachlorobiphenyl (S)%140 10-193
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4221872MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92700395002
4221873
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
PCB-1016 (Aroclor 1016)ug/L R1109010-15351 5610ND9.0 5.1
Decachlorobiphenyl (S)%145 10-19376
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815641
EPA 3510C
EPA 8270E
8270E Water APP9 RV MSSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples: 92700341001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4221874
Associated Lab Samples:92700341001
Matrix: Water
Analyzed
1,2,4,5-Tetrachlorobenzene ug/L ND 8.3 11/29/23 12:25
1,3,5-Trinitrobenzene ug/L ND 8.3 11/29/23 12:25
1,3-Dinitrobenzene ug/L ND 8.3 11/29/23 12:25
1,4-Naphthoquinone ug/L ND 4.2 11/29/23 12:25
1-Naphthalenamine ug/L ND 8.3 11/29/23 12:25
2,2'-Oxybis(1-chloropropane)ug/L ND 8.3 11/29/23 12:25
2,3,4,6-Tetrachlorophenol ug/L ND 8.3 11/29/23 12:25
2,4,5-Trichlorophenol ug/L ND 8.3 11/29/23 12:25
2,4,6-Trichlorophenol ug/L ND 8.3 11/29/23 12:25
2,4-Dichlorophenol ug/L ND 8.3 11/29/23 12:25
2,4-Dimethylphenol ug/L ND 8.3 11/29/23 12:25
2,4-Dinitrophenol ug/L ND 41.7 11/29/23 12:25
2,4-Dinitrotoluene ug/L ND 8.3 11/29/23 12:25
2,6-Dichlorophenol ug/L ND 8.3 11/29/23 12:25
2,6-Dinitrotoluene ug/L ND 8.3 11/29/23 12:25
2-Acetylaminofluorene ug/L ND 8.3 11/29/23 12:25
2-Chloronaphthalene ug/L ND 8.3 11/29/23 12:25
2-Chlorophenol ug/L ND 8.3 11/29/23 12:25
2-Methylnaphthalene ug/L ND 8.3 11/29/23 12:25
2-Methylphenol(o-Cresol)ug/L ND 8.3 11/29/23 12:25
2-Naphthalenamine ug/L ND 8.3 11/29/23 12:25
2-Nitroaniline ug/L ND 16.7 11/29/23 12:25
2-Nitrophenol ug/L ND 8.3 11/29/23 12:25
3&4-Methylphenol(m&p Cresol)ug/L ND 8.3 11/29/23 12:25
3,3'-Dichlorobenzidine ug/L ND 16.7 11/29/23 12:25
3,3'-Dimethylbenzidine ug/L ND 41.7 11/29/23 12:25
3-Methylcholanthrene ug/L ND 8.3 11/29/23 12:25
3-Nitroaniline ug/L ND 16.7 11/29/23 12:25
4,6-Dinitro-2-methylphenol ug/L ND 16.7 11/29/23 12:25
4-Aminobiphenyl ug/L ND 8.3 11/29/23 12:25
4-Bromophenylphenyl ether ug/L ND 8.3 11/29/23 12:25
4-Chloro-3-methylphenol ug/L ND 8.3 11/29/23 12:25
4-Chloroaniline ug/L ND 16.7 11/29/23 12:25
4-Chlorophenylphenyl ether ug/L ND 8.3 11/29/23 12:25
4-Nitroaniline ug/L ND 16.7 11/29/23 12:25
4-Nitrophenol ug/L ND 41.7 11/29/23 12:25
5-Nitro-o-toluidine ug/L ND 8.3 11/29/23 12:25
7,12-Dimethylbenz(a)anthracene ug/L ND 8.3 11/29/23 12:25
Acenaphthene ug/L ND 8.3 11/29/23 12:25
Acenaphthylene ug/L ND 8.3 11/29/23 12:25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4221874
Associated Lab Samples:92700341001
Matrix: Water
Analyzed
Acetophenone ug/L ND 8.3 11/29/23 12:25
Anthracene ug/L ND 8.3 11/29/23 12:25
Benzo(a)anthracene ug/L ND 8.3 11/29/23 12:25
Benzo(a)pyrene ug/L ND 8.3 11/29/23 12:25
Benzo(b)fluoranthene ug/L ND 8.3 11/29/23 12:25
Benzo(g,h,i)perylene ug/L ND 8.3 11/29/23 12:25
Benzo(k)fluoranthene ug/L ND 8.3 11/29/23 12:25
Benzyl alcohol ug/L ND 16.7 11/29/23 12:25
bis(2-Chloroethoxy)methane ug/L ND 8.3 11/29/23 12:25
bis(2-Chloroethyl) ether ug/L ND 8.3 11/29/23 12:25
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 11/29/23 12:25
Butylbenzylphthalate ug/L ND 8.3 11/29/23 12:25
Chlorobenzilate ug/L ND 8.3 11/29/23 12:25
Chrysene ug/L ND 8.3 11/29/23 12:25
Di-n-butylphthalate ug/L ND 8.3 11/29/23 12:25
Di-n-octylphthalate ug/L ND 8.3 11/29/23 12:25
Diallate ug/L ND 8.3 11/29/23 12:25
Dibenz(a,h)anthracene ug/L ND 8.3 11/29/23 12:25
Dibenzofuran ug/L ND 8.3 11/29/23 12:25
Diethylphthalate ug/L ND 8.3 11/29/23 12:25
Dimethoate ug/L ND 8.3 11/29/23 12:25
Dimethylphthalate ug/L ND 8.3 11/29/23 12:25
Diphenylamine ug/L ND 8.3 11/29/23 12:25
Disulfoton ug/L ND 8.3 11/29/23 12:25
Ethyl methanesulfonate ug/L ND 16.7 11/29/23 12:25
Famphur ug/L ND 8.3 11/29/23 12:25
Fluoranthene ug/L ND 8.3 11/29/23 12:25
Fluorene ug/L ND 8.3 11/29/23 12:25
Hexachlorobenzene ug/L ND 8.3 11/29/23 12:25
Hexachlorocyclopentadiene ug/L ND 8.3 11/29/23 12:25
Hexachloroethane ug/L ND 8.3 11/29/23 12:25
Hexachloropropene ug/L ND 8.3 11/29/23 12:25
Indeno(1,2,3-cd)pyrene ug/L ND 8.3 11/29/23 12:25
Isodrin ug/L ND 8.3 11/29/23 12:25
Isophorone ug/L ND 8.3 11/29/23 12:25
Isosafrole ug/L ND 8.3 11/29/23 12:25
Kepone ug/L ND 16.7 11/29/23 12:25
Methapyrilene ug/L ND 41.7 v111/29/23 12:25
Methyl methanesulfonate ug/L ND 4.2 11/29/23 12:25
Methyl parathion ug/L ND 8.3 11/29/23 12:25
N-Nitroso-di-n-butylamine ug/L ND 8.3 11/29/23 12:25
N-Nitroso-di-n-propylamine ug/L ND 8.3 11/29/23 12:25
N-Nitrosodiethylamine ug/L ND 8.3 11/29/23 12:25
N-Nitrosodimethylamine ug/L ND 8.3 11/29/23 12:25
N-Nitrosodiphenylamine ug/L ND 8.3 11/29/23 12:25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4221874
Associated Lab Samples:92700341001
Matrix: Water
Analyzed
N-Nitrosomethylethylamine ug/L ND 8.3 11/29/23 12:25
N-Nitrosopiperidine ug/L ND 8.3 11/29/23 12:25
N-Nitrosopyrrolidine ug/L ND 8.3 11/29/23 12:25
Nitrobenzene ug/L ND 8.3 11/29/23 12:25
O,O,O-Triethylphosphorothioate ug/L ND 8.3 11/29/23 12:25
O-Toluidine ug/L ND 8.3 11/29/23 12:25
P-Dimethylaminoazobenzene ug/L ND 4.2 11/29/23 12:25
p-Phenylenediamine ug/L ND 8.3 11/29/23 12:25
Parathion (Ethyl parathion)ug/L ND 8.3 11/29/23 12:25
Pentachlorobenzene ug/L ND 8.3 11/29/23 12:25
Pentachloronitrobenzene ug/L ND 8.3 11/29/23 12:25
Pentachlorophenol ug/L ND 16.7 11/29/23 12:25
Phenacetin ug/L ND 8.3 11/29/23 12:25
Phenanthrene ug/L ND 8.3 11/29/23 12:25
Phenol ug/L ND 8.3 11/29/23 12:25
Phorate ug/L ND 8.3 11/29/23 12:25
Pronamide ug/L ND 8.3 11/29/23 12:25
Pyrene ug/L ND 8.3 11/29/23 12:25
Safrole ug/L ND 8.3 11/29/23 12:25
Thionazin ug/L ND 8.3 11/29/23 12:25
2,4,6-Tribromophenol (S)%102 10-166 11/29/23 12:25
2-Fluorobiphenyl (S)%77 10-130 11/29/23 12:25
2-Fluorophenol (S)%67 10-130 11/29/23 12:25
Nitrobenzene-d5 (S)%84 10-133 11/29/23 12:25
Phenol-d6 (S)%50 10-130 11/29/23 12:25
Terphenyl-d14 (S)%110 10-193 11/29/23 12:25
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4221875LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4,5-Tetrachlorobenzene ug/L 51.550 103 18-130
1,3,5-Trinitrobenzene ug/L 43.250 86 59-200
1,3-Dinitrobenzene ug/L 58.750 117 51-170
1,4-Naphthoquinone ug/L 37.650 75 32-132
1-Naphthalenamine ug/L 30.250 60 35-140
2,2'-Oxybis(1-chloropropane)ug/L 45.750 91 23-130
2,3,4,6-Tetrachlorophenol ug/L 49.450 99 38-154
2,4,5-Trichlorophenol ug/L 52.750 105 36-150
2,4,6-Trichlorophenol ug/L 48.550 97 30-151
2,4-Dichlorophenol ug/L 51.550 103 36-140
2,4-Dimethylphenol ug/L 55.250 110 36-155
2,4-Dinitrophenol ug/L 135250 54 10-169
2,4-Dinitrotoluene ug/L 54.650 109 46-160
2,6-Dichlorophenol ug/L 58.250 116 34-156
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4221875LABORATORY CONTROL SAMPLE:
LCSSpike
2,6-Dinitrotoluene ug/L 56.150 112 47-161
2-Acetylaminofluorene ug/L 56.850 114 39-184
2-Chloronaphthalene ug/L 48.750 97 29-134
2-Chlorophenol ug/L 49.250 98 29-130
2-Methylnaphthalene ug/L 52.350 105 26-130
2-Methylphenol(o-Cresol)ug/L 45.550 91 32-130
2-Naphthalenamine ug/L 41.150 82 23-145
2-Nitroaniline ug/L 86.6100 87 41-150
2-Nitrophenol ug/L 54.250 108 31-145
3&4-Methylphenol(m&p Cresol)ug/L 46.150 92 29-130
3,3'-Dichlorobenzidine ug/L 120100 120 46-153
3,3'-Dimethylbenzidine ug/L 112100 112 24-200
3-Methylcholanthrene ug/L 65.650 131 31-195
3-Nitroaniline ug/L 106100 106 47-156
4,6-Dinitro-2-methylphenol ug/L 91.9100 92 23-161
4-Aminobiphenyl ug/L 33.550 67 26-151
4-Bromophenylphenyl ether ug/L 57.050 114 45-143
4-Chloro-3-methylphenol ug/L 101100 101 42-143
4-Chloroaniline ug/L 94.1100 94 37-135
4-Chlorophenylphenyl ether ug/L 54.350 109 43-140
4-Nitroaniline ug/L 109100 109 47-157
4-Nitrophenol ug/L 125250 50 10-130
5-Nitro-o-toluidine ug/L 59.750 119 54-170
7,12-Dimethylbenz(a)anthracene ug/L 54.950 110 29-176
Acenaphthene ug/L 51.450 103 38-138
Acenaphthylene ug/L 50.950 102 39-139
Acetophenone ug/L 49.550 99 34-135
Anthracene ug/L 54.850 110 45-136
Benzo(a)anthracene ug/L 59.350 119 52-151
Benzo(a)pyrene ug/L 61.150 122 46-165
Benzo(b)fluoranthene ug/L 66.850 134 44-170
Benzo(g,h,i)perylene ug/L 67.750 135 39-171
Benzo(k)fluoranthene ug/L 60.350 121 43-168
Benzyl alcohol ug/L 92.2100 92 33-134
bis(2-Chloroethoxy)methane ug/L 52.450 105 37-140
bis(2-Chloroethyl) ether ug/L 50.050 100 33-136
bis(2-Ethylhexyl)phthalate ug/L 57.950 116 50-169
Butylbenzylphthalate ug/L 59.550 119 50-174
Chlorobenzilate ug/L 62.650 125 46-167
Chrysene ug/L 59.150 118 52-148
Di-n-butylphthalate ug/L 54.350 109 51-154
Di-n-octylphthalate ug/L 56.550 113 44-170
Diallate ug/L 53.750 107 49-147
Dibenz(a,h)anthracene ug/L 65.850 132 41-171
Dibenzofuran ug/L 49.850 100 42-157
Diethylphthalate ug/L 51.450 103 50-149
Dimethoate ug/L 57.750 115 52-169
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4221875LABORATORY CONTROL SAMPLE:
LCSSpike
Dimethylphthalate ug/L 50.950 102 47-146
Diphenylamine ug/L 54.250 108 53-142
Disulfoton ug/L 50.650 101 45-135
Ethyl methanesulfonate ug/L 50.050 100 27-146
Famphur ug/L 89.9100 90 13-130
Fluoranthene ug/L 57.850 116 51-152
Fluorene ug/L 52.950 106 46-143
Hexachlorobenzene ug/L 56.450 113 40-139
Hexachlorocyclopentadiene ug/L 47.950 96 10-130
Hexachloroethane ug/L 33.750 67 10-130
Hexachloropropene ug/L 33.250 66 10-130
Indeno(1,2,3-cd)pyrene ug/L 65.650 131 40-172
Isodrin ug/L 55.150 110 50-150
Isophorone ug/L 50.450 101 37-143
Isosafrole ug/L 48.550 97 35-130
Kepone ug/L 54.6100 55 12-130
Methapyrilene ug/L 30.8J v15062 10-188
Methyl methanesulfonate ug/L 45.850 92 24-135
Methyl parathion ug/L 66.150 132 59-174
N-Nitroso-di-n-butylamine ug/L 47.150 94 33-130
N-Nitroso-di-n-propylamine ug/L 49.550 99 38-145
N-Nitrosodiethylamine ug/L 53.550 107 26-145
N-Nitrosodimethylamine ug/L 39.150 78 30-130
N-Nitrosodiphenylamine ug/L 54.250 108 46-144
N-Nitrosomethylethylamine ug/L 46.750 93 19-138
N-Nitrosopiperidine ug/L 57.450 115 35-147
N-Nitrosopyrrolidine ug/L 48.850 98 31-142
Nitrobenzene ug/L 49.150 98 33-136
O,O,O-Triethylphosphorothioate ug/L 61.350 123 27-136
O-Toluidine ug/L 47.250 94 27-140
P-Dimethylaminoazobenzene ug/L 29.250 58 23-130
p-Phenylenediamine ug/L ND
Parathion (Ethyl parathion)ug/L 63.150 126 59-171
Pentachlorobenzene ug/L 54.950 110 42-138
Pentachloronitrobenzene ug/L 70.950 142 64-185
Pentachlorophenol ug/L 102100 102 19-156
Phenacetin ug/L 58.450 117 57-174
Phenanthrene ug/L 55.350 111 49-143
Phenol ug/L 33.250 66 18-130
Phorate ug/L 56.250 112 41-200
Pronamide ug/L 62.450 125 59-174
Pyrene ug/L 56.650 113 48-156
Safrole ug/L 55.650 111 31-136
Thionazin ug/L 56.550 113 52-151
2,4,6-Tribromophenol (S)%116 10-166
2-Fluorobiphenyl (S)%92 10-130
2-Fluorophenol (S)%72 10-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4221875LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrobenzene-d5 (S)%99 10-133
Phenol-d6 (S)%57 10-130
Terphenyl-d14 (S)%110 10-193
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4221876MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92700341001
4221877
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,2,4,5-Tetrachlorobenzene ug/L 83.3 93 10-136108 1583.3ND 77.5 90.2
1,3,5-Trinitrobenzene ug/L 83.3 80 32-20094 1683.3ND 66.9 78.4
1,3-Dinitrobenzene ug/L 83.3 113 30-173121 783.3ND 94.0 101
1,4-Naphthoquinone ug/L 83.3 96 10-144105 883.3ND 80.4 87.4
1-Naphthalenamine ug/L 83.3 30 10-1561483.3ND 25.4 11.5J
2,2'-Oxybis(1-chloropropane) ug/L 83.3 89 10-13290 283.3ND 73.8 75.2
2,3,4,6-Tetrachlorophenol ug/L 83.3 96 10-185103 783.3ND 80.0 86.0
2,4,5-Trichlorophenol ug/L 83.3 102 10-174109 783.3ND 84.9 91.0
2,4,6-Trichlorophenol ug/L 83.3 98 10-173102 483.3ND 81.8 85.2
2,4-Dichlorophenol ug/L 83.3 101 10-153106 683.3ND 83.8 88.7
2,4-Dimethylphenol ug/L 83.3 106 12-157111 583.3ND 88.2 92.4
2,4-Dinitrophenol ug/L 417 92 10-165108 16417ND383 448
2,4-Dinitrotoluene ug/L 83.3 97 29-168106 983.3ND 80.5 88.4
2,6-Dichlorophenol ug/L 83.3 114 10-178121 583.3ND 95.3 100
2,6-Dinitrotoluene ug/L 83.3 105 28-168110 483.3ND 87.6 91.5
2-Acetylaminofluorene ug/L 83.3 89 20-19494 583.3ND 74.5 78.0
2-Chloronaphthalene ug/L 83.3 92 11-13697 683.3ND 76.3 81.2
2-Chlorophenol ug/L 83.3 98 10-134104 683.3ND 81.7 87.1
2-Methylnaphthalene ug/L 83.3 99 10-131105 683.3ND 82.3 87.4
2-Methylphenol(o-Cresol)ug/L 83.3 91 10-13097 783.3ND 75.8 81.2
2-Naphthalenamine ug/L M183.3 29 10-147583.3ND 23.9 ND
2-Nitroaniline ug/L 167 82 19-15687 6167ND137 144
2-Nitrophenol ug/L 83.3 102 10-160110 783.3ND 85.0 91.6
3&4-Methylphenol(m&pCresol)ug/L 83.3 89 10-13293 483.3ND 74.2 77.3
3,3'-Dichlorobenzidine ug/L 167 105 10-17398 6167ND174 164
3,3'-Dimethylbenzidine ug/L M11673810-2000167ND63.1J ND
3-Methylcholanthrene ug/L 83.3 120 10-200128 783.3ND 99.6 106
3-Nitroaniline ug/L 167 100 19-169105 5167ND166 175
4,6-Dinitro-2-methylphenol ug/L 167 103 10-178117 12167ND172 195
4-Aminobiphenyl ug/L R183.3 53 10-17039 3283.3ND 44.4 32.2
4-Bromophenylphenyl ether ug/L 83.3 106 28-149110 483.3ND 87.9 91.8
4-Chloro-3-methylphenol ug/L 167 95 18-148103 9167ND158 172
4-Chloroaniline ug/L R11678510-14149 54167ND141 81.3
4-Chlorophenylphenyl ether ug/L 83.3 100 24-144105 583.3ND 83.1 87.2
4-Nitroaniline ug/L 167 91 18-17096 5167ND151 160
4-Nitrophenol ug/L R14176210-13090 37417ND258 374
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4221876MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92700341001
4221877
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
5-Nitro-o-toluidine ug/L 83.3 113 38-167119 583.3ND 93.9 98.8
7,12-
Dimethylbenz(a)anthracene ug/L 83.3 110 10-182120 983.3ND 91.7 100
Acenaphthene ug/L 83.3 95 18-142101 783.3ND 79.0 84.3
Acenaphthylene ug/L 83.3 97 18-143102 683.3ND 80.6 85.3
Acetophenone ug/L 83.3 98 10-14299 183.3ND 81.4 82.5
Anthracene ug/L 83.3 98 32-138106 783.3ND 82.0 88.1
Benzo(a)anthracene ug/L 83.3 106 41-155114 783.3ND 88.5 94.7
Benzo(a)pyrene ug/L 83.3 110 10-167116 683.3ND 91.3 97.0
Benzo(b)fluoranthene ug/L 83.3 119 31-172129 883.3ND 99.3 107
Benzo(g,h,i)perylene ug/L 83.3 121 26-177129 683.3ND 101 108
Benzo(k)fluoranthene ug/L 83.3 109 31-168115 583.3ND 90.9 95.9
Benzyl alcohol ug/L 167 91 10-13693 3167ND152 156
bis(2-Chloroethoxy)methane ug/L 83.3 98 12-143102 383.3ND 82.0 84.6
bis(2-Chloroethyl) ether ug/L 83.3 96 10-13997 183.3ND 80.0 80.9
bis(2-Ethylhexyl)phthalate ug/L 83.3 106 41-173112 683.3ND 88.0 93.7
Butylbenzylphthalate ug/L 83.3 106 38-182114 883.3ND 88.0 95.4
Chlorobenzilate ug/L 83.3 116 33-175124 783.3ND 97.0 104
Chrysene ug/L 83.3 109 41-152114 583.3ND 90.5 94.8
Di-n-butylphthalate ug/L 83.3 98 37-162106 883.3ND 82.0 88.4
Di-n-octylphthalate ug/L 83.3 106 36-176114 783.3ND 88.2 94.6
Diallate ug/L 83.3 99 26-155108 983.3ND 82.5 90.2
Dibenz(a,h)anthracene ug/L 83.3 117 29-175126 783.3ND 97.3 105
Dibenzofuran ug/L 83.3 93 23-14499 783.3ND 77.4 82.7
Diethylphthalate ug/L 83.3 97 33-154100 483.3ND 80.5 83.7
Dimethoate ug/L 83.3 110 41-169122 1083.3ND 92.0 101
Dimethylphthalate ug/L 83.3 97 29-150100 383.3ND 80.9 83.3
Diphenylamine ug/L 83.3 100 34-146103 383.3ND 83.3 85.4
Disulfoton ug/L 83.3 96 36-133105 883.3ND 80.4 87.3
Ethyl methanesulfonate ug/L 83.3 99 10-147103 483.3ND 82.2 85.7
Famphur ug/L 167 107 10-130125 16167ND178 208
Fluoranthene ug/L 83.3 103 40-156110 783.3ND 85.6 91.7
Fluorene ug/L 83.3 99 26-148104 583.3ND 82.1 86.5
Hexachlorobenzene ug/L 83.3 103 27-145109 683.3ND 85.5 90.8
Hexachlorocyclopentadiene ug/L 83.3 93 10-130102 1083.3ND 77.4 85.2
Hexachloroethane ug/L 83.3 61 10-13071 1683.3ND 50.5 59.3
Hexachloropropene ug/L 83.3 66 10-13082 2283.3ND 54.9 68.5
Indeno(1,2,3-cd)pyrene ug/L 83.3 117 28-176125 683.3ND 97.5 104
Isodrin ug/L 83.3 102 33-153110 883.3ND 85.0 91.9
Isophorone ug/L 83.3 95 14-14599 583.3ND 79.0 82.8
Isosafrole ug/L 83.3 90 13-136100 1083.3ND 75.2 83.1
Kepone ug/L 167 76 10-13090 17167ND127 150
Methapyrilene ug/L M1,v183.3 9 10-200283.3ND ND ND
Methyl methanesulfonate ug/L 83.3 94 10-13898 483.3ND 78.5 81.9
Methyl parathion ug/L 83.3 123 44-177135 983.3ND 103 113
N-Nitroso-di-n-butylamine ug/L 83.3 94 14-13393 183.3ND 78.3 77.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4221876MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92700341001
4221877
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
N-Nitroso-di-n-propylamine ug/L 83.3 97 12-14998 183.3ND 80.9 82.1
N-Nitrosodiethylamine ug/L 83.3 107 10-148111 483.3ND 89.1 92.5
N-Nitrosodimethylamine ug/L 83.3 77 10-13080 483.3ND 64.3 66.8
N-Nitrosodiphenylamine ug/L 83.3 100 29-149103 383.3ND 83.3 85.4
N-Nitrosomethylethylamine ug/L 83.3 98 10-13990 983.3ND 82.1 74.9
N-Nitrosopiperidine ug/L 83.3 112 14-151118 683.3ND 93.1 98.6
N-Nitrosopyrrolidine ug/L 83.3 99 14-143104 483.3ND 82.6 86.3
Nitrobenzene ug/L 83.3 93 10-14596 483.3ND 77.3 80.2
O,O,O-
Triethylphosphorothioate ug/L 83.3 114 10-142122 783.3ND 95.4 102
O-Toluidine ug/L 83.3 84 10-1371883.3ND 70.3 14.8J
P-Dimethylaminoazobenzene ug/L 83.3 52 17-13058 983.3ND 43.7 48.0
p-Phenylenediamine ug/L ND ND ND
Parathion (Ethyl parathion)ug/L 83.3 121 45-174135 1183.3ND 101 112
Pentachlorobenzene ug/L 83.3 102 20-143114 1183.3ND 84.9 94.7
Pentachloronitrobenzene ug/L 83.3 129 39-186141 983.3ND 108 117
Pentachlorophenol ug/L 167 103 10-178113 9167ND172 189
Phenacetin ug/L 83.3 112 36-185120 783.3ND 93.4 100
Phenanthrene ug/L 83.3 100 36-146106 683.3ND 83.4 88.5
Phenol ug/L 83.3 63 10-13079 2383.3ND 52.1 65.4
Phorate ug/L 83.3 105 26-200113 883.3ND 87.3 94.2
Pronamide ug/L 83.3 115 40-181125 983.3ND 95.5 104
Pyrene ug/L 83.3 102 42-156106 383.3ND 85.4 88.4
Safrole ug/L 83.3 104 10-142113 883.3ND 87.1 94.2
Thionazin ug/L 83.3 104 31-159114 983.3ND 87.0 95.4
2,4,6-Tribromophenol (S)%107 10-166117
2-Fluorobiphenyl (S)%85 10-13096
2-Fluorophenol (S)%70 10-13092
Nitrobenzene-d5 (S)%92 10-133100
Phenol-d6 (S)%55 10-13078
Terphenyl-d14 (S)%93 10-193108
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
816433
SM 4500-CN-E-2016
SM 4500-CN-E-2016
4500CNE Cyanide, Total
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples: 92700341001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4225847
Associated Lab Samples:92700341001
Matrix: Water
Analyzed
Cyanide mg/L ND 0.0080 12/01/23 16:29
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4225848LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide mg/L 0.0860.1 86 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4225851MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92700529004
4225852
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Cyanide mg/L M10.1 -1 80-120270.1ND ND 0.028
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4225894MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92700906001
4225895
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Cyanide mg/L 0.1 87 80-12090 30.1ND 0.092 0.095
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 49
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be
considered an estimated value.IH
Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.L1
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.v1
The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.v2
The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.v3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 49
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92700341
OCSWM FALL-SOUTH
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92700341001 815639 8160046801-MW105 EPA 3510C EPA 8081B
92700341001 815640 8160056801-MW105 EPA 3510C EPA 8082A
92700341001 815698 8158316801-MW105 EPA 3010A EPA 6010D
92700341002 815698 8158316801-MW106 EPA 3010A EPA 6010D
92700341003 815698 8158316801-MW107 EPA 3010A EPA 6010D
92700341001 816038 8161306801-MW105 EPA 7470A EPA 7470A
92700341001 815641 8158966801-MW105 EPA 3510C EPA 8270E
92700341001 8157046801-MW105 EPA 8260D
92700341002 8157046801-MW106 EPA 8260D
92700341003 8157046801-MW107 EPA 8260D
92700341001 8153606801-MW105 EPA 8260D Mod.
92700341002 8153606801-MW106 EPA 8260D Mod.
92700341003 8153606801-MW107 EPA 8260D Mod.
92700341001 816433 8165436801-MW105 SM 4500-CN-E-2016 SM 4500-CN-E-2016
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/06/2023 03:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 49
Page 39 of 49
Page 40 of 49
Page 41 of 49
November 30, 2023
Dear Order No:
RE:
Analytical Environmental Services, Inc. received samples on
for the analyses presented in following report.
1
“No problems were encountered during the analyses except as noted in the Case Narrative or by qualifiers in
the report or QC Summary. Additionally, all results for the associated Quality Control samples were within
EPA and/or AES established limits.
AES’ certifications are as follows:
-NELAP/Florida State Laboratory ID E87582 for analysis of Non-Potable Water, Solid & Chemical Materials,
Air & Emissions for Organics, and Drinking Water Microbiology & Metals, effective 07/01/23-06/30/24.
-North Carolina Certification number 562 for analysis of Surface Water, Groundwater, Effluent, effective until
12/31/23.
-South Carolina Environmental Laboratory Certification number 98016003 effective until 6/30/24.
These results relate only to the items tested as received. This report may only be reproduced in full and with
written permission from the laboratory.
If you have any questions regarding these test results, please feel free to call.
Sincerely,
Project Manager
2311R51
Matthew Brainard
Pace Analytical Services, Inc.
9800 Kincey Ave Suite 100
Huntersville NC 28078-8400
92700341
Shawn Boyd
November 28, 2023 7:51 am
Matthew Brainard:
Page 1 of 8 Page 42 of 49
Page 2 of 8 Page 43 of 49
2311R51-001
30-Nov-23Date:Analytical Environmental Services, Inc
Analyses Date Analyzed
Dilution
FactorBatchIDUnitsQualReporting
LimitResult
Client:
Aqueous
11/22/2023 9:30:00 AM
6801-MW105
Matrix:
Collection Date:
Client Sample ID:
92700341
Pace Analytical Services, Inc.
Lab ID:
Project Name:
Analyst
(SW3510C)CHLORINATED HERBICIDES, APPENDIX II LIST SW8151A
2,4,5-T BRL 2.0 ug/L 367291 1 11/28/2023 20:33 TB
2,4,5-TP (Silvex)BRL 2.0 ug/L 367291 1 11/28/2023 20:33 TB
2,4-D BRL 2.0 ug/L 367291 1 11/28/2023 20:33 TB
Dinoseb BRL 5.0 ug/L 367291 1 11/28/2023 20:33 TB
Surr: DCAA 69.5 48-124 %REC 367291 1 11/28/2023 20:33 TB
Qualifiers: * Value exceeds maximum contaminant level
BRL Below reporting limit
H Holding times for preparation or analysis exceeded
N Analyte not NELAC certified
B Analyte detected in the associated method blank
E Estimated (value above quantitation range)
S Spike Recovery outside limits due to matrix
Narr See case narrative
F Analyzed in the lab which is a deviation from the method
< Less than Result value
> Greater than Result value J Estimated value detected below Reporting Limit Page 3 of 8 Page 44 of 49
1. Client Name:AES Work Order Number: 2. Carrier: FedEx UPS USPS Client Courier OtherYes No N/A3.4.5.6.7.8.9.10.11.If no TAT indicated, proceeded with standard TAT per Terms & Conditions. 12.13.Comments: I certify that I have completed sections 1-13 (dated initials). Yes No N/A14.15.16.17.19.21.22.23.24.25.26.Comments: I certify that I have completed sections 14-26 (dated initials). Yes No N/A27.28.29.*Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms, VOCs and Oil & Grease/TPH. This also excludes metals by EPA 200.7, 200.8 and 245.1 which will be verified between 16 and 24 hours after preservation.I certify that I have completed sections 27-29(dated initials). SAMPLE/COOLER RECEIPT CHECKLISTDetailsCommentsShipping container/cooler received in good condition?damaged leaking other Cooler temperature(s) within limits of 0-6⁰C? [See item 12 for temperature recordings.] Custody seals present on shipping container?Custody seals intact on shipping container?Chain of Custody (COC) present?Chain of Custody signed, dated, and timed when relinquished and received?Sampler name and/or signature on COC?Were all samples received within holding time?TAT marked on the COC?Cooler 1 Temperature ⁰C Cooler 2 Temperature ⁰C Cooler 3 Temperature ⁰C Cooler 4 Temperature ⁰CCooler 5 Temperature ⁰C Cooler 6 Temperature ⁰C Cooler 7 Temperature ⁰C Cooler 8 Temperature ⁰CDetailsCommentsWere sample containers intact upon receipt?Temperature blanks present?Custody seals present on sample containers?Custody seals intact on sample containers?18.Do sample container labels match the COC?incomplete info illegible no label other Are analyses requested indicated on the COC?20.Were all of the samples listed on the COC received?samples received but not listed on COCsamples listed on COC not receivedWas the sample collection date/time noted?Did we receive sufficient sample volume for indicated analyses?Were samples received in appropriate containers?Were VOA samples received without headspace (< 1/4" bubble)? Were trip blanks submitted?listed on COC not listed on COCThis section only applies to samples where pH can be checked at Sample Receipt. DetailsCommentsHave containers needing chemical preservation been checked?*Containers meet preservation guidelines?Was pH adjusted at Sample Receipt?Checklist 7.24.23 Rev 4Pace Analytical Services, Inc.2311R51✔1.5CP2 11/28/23FM 11/28/23FM 11/28/23ClearSave asLockedPage 4 of 8 Page 45 of 49
30-Nov-23Date:Analytical Environmental Services, Inc
Client:
Dates ReportLab Order:
Project Name:
Lab Sample ID Client Sample ID Test NameCollection Date Matrix TCLP Date Prep Date Analysis Date
2311R51
92700341
Pace Analytical Services, Inc.
2311R51-001A 6801-MW105 11/22/2023 9:30:00AM Aqueous CHLORINATED HERBICIDES, APPENDIX II LIST 11/28/2023 10:32:18AM 11/28/2023
Page 5 of 8 Page 46 of 49
30-Nov-23Date:Analytical Environmental Services, Inc
Client:
BatchID:Workorder:
Project Name:ANALYTICAL QC SUMMARY REPORT92700341
2311R51
Pace Analytical Services, Inc.
367291
RPT Limit QualAnalyte Result SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit
SampleType: BatchID: Analysis Date:Seq No:TestCode:367291MBLK 11/28/2023CHLORINATED HERBICIDES, APPENDIX II LIST SW8151A
Units:Prep Date:Sample ID:Client ID:Run No:ug/L 11/27/2023 532307MB-367291
12644570
2,4,5-T 2.0BRL
2,4,5-TP (Silvex)2.0BRL
2,4-D 2.0BRL
Dinoseb 5.0BRL
Surr: DCAA 03.303 5.000 66.1 48 124
RPT Limit QualAnalyteResultSPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit
SampleType:BatchID:Analysis Date:Seq No:TestCode:367291LCS 11/28/2023CHLORINATED HERBICIDES, APPENDIX II LIST SW8151A
Units:Prep Date:Sample ID:Client ID:Run No:ug/L 11/27/2023 532307LCS-367291
12644571
2,4,5-T 2.03.540 5.000 70.8 51.1 120
2,4,5-TP (Silvex)2.03.563 5.000 71.3 51.2 120
2,4-D 2.03.548 5.000 71.0 52.1 120
Surr: DCAA 03.937 5.000 78.7 48 124
RPT Limit QualAnalyteResultSPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit
SampleType:BatchID:Analysis Date:Seq No:TestCode:367291MS 11/28/2023CHLORINATED HERBICIDES, APPENDIX II LIST SW8151A
Units:Prep Date:Sample ID:Client ID:Run No:ug/L 11/27/2023 5323072311P76-001AMS
12644573
2,4,5-T 2.04.232 5.000 84.6 46.8 120
2,4,5-TP (Silvex)2.04.323 5.000 86.5 46.5 120
2,4-D 2.04.867 5.000 97.3 40.2 127
Surr: DCAA 04.617 5.000 92.3 48 124
RPT Limit QualAnalyteResultSPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit
SampleType:BatchID:Analysis Date:Seq No:TestCode:367291MSD 11/28/2023CHLORINATED HERBICIDES, APPENDIX II LIST SW8151A
Units:Prep Date:Sample ID:Client ID:Run No:ug/L 11/27/2023 5323072311P76-001AMSD
12644574
Qualifiers:
J Estimated value detected below Reporting Limit
BRL Below reporting limit H Holding times for preparation or analysis exceeded
N Analyte not NELAC certified
B Analyte detected in the associated method blank
E Estimated (value above quantitation range)
S Spike Recovery outside limits due to matrix
< Less than Result value> Greater than Result value
R RPD outside limits due to matrix
Rpt Lim Reporting Limit Page 6 of 8 Page 47 of 49
30-Nov-23Date:Analytical Environmental Services, Inc
Client:
BatchID:Workorder:
Project Name:ANALYTICAL QC SUMMARY REPORT92700341
2311R51
Pace Analytical Services, Inc.
367291
RPT Limit QualAnalyte Result SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit
SampleType: BatchID: Analysis Date:Seq No:TestCode:367291MSD 11/28/2023CHLORINATED HERBICIDES, APPENDIX II LIST SW8151A
Units:Prep Date:Sample ID:Client ID:Run No:ug/L 11/27/2023 5323072311P76-001AMSD
12644574
2,4,5-T 2.03.862 29.15.000 77.2 46.8 120 4.232 9.16
2,4,5-TP (Silvex)2.03.963 31.45.000 79.3 46.5 120 4.323 8.68
2,4-D 2.04.438 39.95.000 88.8 40.2 127 4.867 9.24
Surr: DCAA 04.216 05.000 84.3 48 124 4.617 0
Qualifiers:
J Estimated value detected below Reporting Limit
BRL Below reporting limit H Holding times for preparation or analysis exceeded
N Analyte not NELAC certified
B Analyte detected in the associated method blank
E Estimated (value above quantitation range)
S Spike Recovery outside limits due to matrix
< Less than Result value> Greater than Result value
R RPD outside limits due to matrix
Rpt Lim Reporting Limit Page 7 of 8 Page 48 of 49

End of Report
Page 8 of 8 Page 49 of 49

Groundwater Monitoring Program March, 2024 Results of Sampling and Analysis Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01

Attachment 7: Shared Monitoring Wells (MW-04, MW-110S, MW-110D)
#=CL#
December 04, 2023
LIMS USE: FR - DEBORAH COAKLEY
LIMS OBJECT ID: 92699898
92699898
Project:
Pace Project No.:
RE:
Deborah Ann Coakley
TRC Companies
1030 Wilmer Ave.
Suite 100
Richmond, VA 23227
OCSWM FALL-NORTH (MW-04)
Dear Deborah Coakley:
Enclosed are the analytical results for sample(s) received by the laboratory on November 20, 2023. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Matthew Brainard
[e-mail]
Project Manager
704-977-0942
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 27
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92699898
OCSWM FALL-NORTH (MW-04)
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 27
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92699898
OCSWM FALL-NORTH (MW-04)
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92699898001 6801-MW04 EPA 6010D 17 PASI-ASBW
EPA 7470A 1 PASI-ABM
EPA 8260D 51 PASI-CSAS
EPA 8260D Mod.3 PASI-CTEG
SM 2320B-2011 1 PASI-ASMS
SM 2540C-2015 1 PASI-AJAY
SM 4500-S2D-2011 1 PASI-AJP1
EPA 300.0 Rev 2.1 1993 2 PASI-ACDC
SM 3500-Cr B-2011 1 PASI-AJMH1
92699898002 TRIP BLANK EPA 8260D 51 PASI-CSAS
EPA 8260D Mod.3 PASI-CTEG
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92699898
OCSWM FALL-NORTH (MW-04)
Sample: 6801-MW04 Lab ID: 92699898001 Collected: 11/20/23 07:35 Received: 11/20/23 14:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services - Asheville
6010 MET ICP
Antimony ND ug/L 12/03/23 12:29 7440-36-011/22/23 11:555.0 1
Arsenic ND ug/L 12/03/23 12:29 7440-38-211/22/23 11:5510.0 1
Barium 80.1 ug/L 12/03/23 12:29 7440-39-311/22/23 11:555.0 1
Beryllium ND ug/L 12/03/23 12:29 7440-41-711/22/23 11:551.0 1
Cadmium ND ug/L 12/03/23 12:29 7440-43-911/22/23 11:551.0 1
Chromium ND ug/L 12/03/23 12:29 7440-47-311/22/23 11:555.0 1
Cobalt ND ug/L 12/03/23 12:29 7440-48-411/22/23 11:555.0 1
Copper ND ug/L 12/03/23 12:29 7440-50-811/22/23 11:555.0 1
Iron 106 ug/L 12/03/23 12:29 7439-89-611/22/23 11:5550.0 1
Lead ND ug/L 12/03/23 12:29 7439-92-111/22/23 11:555.0 1
Manganese ND ug/L 12/03/23 12:29 7439-96-511/22/23 11:555.0 1
Nickel ND ug/L 12/03/23 12:29 7440-02-011/22/23 11:555.0 1
Selenium ND ug/L 12/03/23 12:29 7782-49-211/22/23 11:5510.0 1
Silver ND ug/L 12/03/23 12:29 7440-22-411/22/23 11:555.0 1
Thallium ND ug/L 12/03/23 12:29 7440-28-011/22/23 11:5510.0 1
Vanadium ND ug/L 12/03/23 12:29 7440-62-211/22/23 11:555.0 1
Zinc ND ug/L 12/03/23 12:29 7440-66-611/22/23 11:5510.0 1
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services - Asheville
7470 Mercury
Mercury ND ug/L 11/25/23 10:24 7439-97-611/23/23 16:180.20 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 11/23/23 00:24 67-64-125.0 1
Acrylonitrile ND ug/L 11/23/23 00:24 107-13-110.0 1
Benzene ND ug/L 11/23/23 00:24 71-43-21.0 1
Bromochloromethane ND ug/L 11/23/23 00:24 74-97-51.0 1
Bromodichloromethane ND ug/L 11/23/23 00:24 75-27-41.0 1
Bromoform ND ug/L 11/23/23 00:24 75-25-21.0 1
Bromomethane ND ug/L 11/23/23 00:24 74-83-92.0 1
2-Butanone (MEK)ND ug/L 11/23/23 00:24 78-93-35.0 1
Carbon disulfide ND ug/L 11/23/23 00:24 75-15-02.0 1
Carbon tetrachloride ND ug/L 11/23/23 00:24 56-23-51.0 1
Chlorobenzene ND ug/L 11/23/23 00:24 108-90-71.0 1
Chloroethane ND ug/L 11/23/23 00:24 75-00-3 IK1.0 1
Chloroform ND ug/L 11/23/23 00:24 67-66-31.0 1
Chloromethane ND ug/L 11/23/23 00:24 74-87-31.0 1
Dibromochloromethane ND ug/L 11/23/23 00:24 124-48-11.0 1
Dibromomethane ND ug/L 11/23/23 00:24 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 11/23/23 00:24 95-50-11.0 1
1,4-Dichlorobenzene ND ug/L 11/23/23 00:24 106-46-71.0 1
trans-1,4-Dichloro-2-butene ND ug/L 11/23/23 00:24 110-57-61.0 1
1,1-Dichloroethane ND ug/L 11/23/23 00:24 75-34-31.0 1
1,2-Dichloroethane ND ug/L 11/23/23 00:24 107-06-21.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 07:54 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92699898
OCSWM FALL-NORTH (MW-04)
Sample: 6801-MW04 Lab ID: 92699898001 Collected: 11/20/23 07:35 Received: 11/20/23 14:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
1,1-Dichloroethene ND ug/L 11/23/23 00:24 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 11/23/23 00:24 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 11/23/23 00:24 156-60-51.0 1
1,2-Dichloropropane ND ug/L 11/23/23 00:24 78-87-51.0 1
cis-1,3-Dichloropropene ND ug/L 11/23/23 00:24 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 11/23/23 00:24 10061-02-61.0 1
Ethylbenzene ND ug/L 11/23/23 00:24 100-41-41.0 1
2-Hexanone ND ug/L 11/23/23 00:24 591-78-65.0 1
Iodomethane ND ug/L 11/23/23 00:24 74-88-420.0 1
Methylene Chloride ND ug/L 11/23/23 00:24 75-09-25.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/23/23 00:24 108-10-15.0 1
Naphthalene ND ug/L 11/23/23 00:24 91-20-31.0 1
Styrene ND ug/L 11/23/23 00:24 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 11/23/23 00:24 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 11/23/23 00:24 79-34-51.0 1
Tetrachloroethene ND ug/L 11/23/23 00:24 127-18-41.0 1
Toluene ND ug/L 11/23/23 00:24 108-88-31.0 1
1,1,1-Trichloroethane ND ug/L 11/23/23 00:24 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 11/23/23 00:24 79-00-51.0 1
Trichloroethene ND ug/L 11/23/23 00:24 79-01-61.0 1
Trichlorofluoromethane ND ug/L 11/23/23 00:24 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 11/23/23 00:24 96-18-41.0 1
Vinyl acetate ND ug/L 11/23/23 00:24 108-05-42.0 1
Vinyl chloride ND ug/L 11/23/23 00:24 75-01-41.0 1
Xylene (Total)ND ug/L 11/23/23 00:24 1330-20-71.0 1
m&p-Xylene ND ug/L 11/23/23 00:24 179601-23-12.0 1
o-Xylene ND ug/L 11/23/23 00:24 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)93 %11/23/23 00:24 460-00-470-130 1
1,2-Dichloroethane-d4 (S)84 %11/23/23 00:24 17060-07-070-130 1
Toluene-d8 (S)96 %11/23/23 00:24 2037-26-570-130 1
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
8260D MSV SIM
1,4-Dioxane (p-Dioxane)ND ug/L 11/22/23 22:58 123-91-12.0 1
Surrogates
1,2-Dichloroethane-d4 (S)99 %11/22/23 22:58 17060-07-067-130 1
Toluene-d8 (S)93 %11/22/23 22:58 2037-26-570-130 1
Analytical Method: SM 2320B-2011
Pace Analytical Services - Asheville
2320B Alkalinity
Alkalinity, Total as CaCO3 30.3 mg/L 11/29/23 13:315.0 1
Analytical Method: SM 2540C-2015
Pace Analytical Services - Asheville
2540C Total Dissolved Solids
Total Dissolved Solids 68.0 mg/L 11/27/23 10:25 H125.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 07:54 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92699898
OCSWM FALL-NORTH (MW-04)
Sample: 6801-MW04 Lab ID: 92699898001 Collected: 11/20/23 07:35 Received: 11/20/23 14:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services - Asheville
4500S2D Sulfide Water
Sulfide ND mg/L 11/23/23 04:22 18496-25-80.10 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Chloride 8.0 mg/L 11/22/23 02:50 16887-00-61.0 1
Sulfate ND mg/L 11/22/23 02:50 14808-79-81.0 1
Analytical Method: SM 3500-Cr B-2011
Pace Analytical Services - Asheville
Chromium, Hexavalent, 28 Day
Chromium, Hexavalent 0.010 mg/L 11/25/23 15:12 18540-29-9 M10.010 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 07:54 PM
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Page 6 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92699898
OCSWM FALL-NORTH (MW-04)
Sample: TRIP BLANK Lab ID: 92699898002 Collected:Received: 11/20/23 14:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 11/22/23 15:37 67-64-1 v225.0 1
Acrylonitrile ND ug/L 11/22/23 15:37 107-13-110.0 1
Benzene ND ug/L 11/22/23 15:37 71-43-21.0 1
Bromochloromethane ND ug/L 11/22/23 15:37 74-97-51.0 1
Bromodichloromethane ND ug/L 11/22/23 15:37 75-27-41.0 1
Bromoform ND ug/L 11/22/23 15:37 75-25-21.0 1
Bromomethane ND ug/L 11/22/23 15:37 74-83-92.0 1
2-Butanone (MEK)ND ug/L 11/22/23 15:37 78-93-35.0 1
Carbon disulfide ND ug/L 11/22/23 15:37 75-15-02.0 1
Carbon tetrachloride ND ug/L 11/22/23 15:37 56-23-51.0 1
Chlorobenzene ND ug/L 11/22/23 15:37 108-90-71.0 1
Chloroethane ND ug/L 11/22/23 15:37 75-00-3 IK1.0 1
Chloroform ND ug/L 11/22/23 15:37 67-66-31.0 1
Chloromethane ND ug/L 11/22/23 15:37 74-87-31.0 1
Dibromochloromethane ND ug/L 11/22/23 15:37 124-48-11.0 1
Dibromomethane ND ug/L 11/22/23 15:37 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 11/22/23 15:37 95-50-11.0 1
1,4-Dichlorobenzene ND ug/L 11/22/23 15:37 106-46-71.0 1
trans-1,4-Dichloro-2-butene ND ug/L 11/22/23 15:37 110-57-61.0 1
1,1-Dichloroethane ND ug/L 11/22/23 15:37 75-34-31.0 1
1,2-Dichloroethane ND ug/L 11/22/23 15:37 107-06-21.0 1
1,1-Dichloroethene ND ug/L 11/22/23 15:37 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 11/22/23 15:37 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 11/22/23 15:37 156-60-51.0 1
1,2-Dichloropropane ND ug/L 11/22/23 15:37 78-87-51.0 1
cis-1,3-Dichloropropene ND ug/L 11/22/23 15:37 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 11/22/23 15:37 10061-02-61.0 1
Ethylbenzene ND ug/L 11/22/23 15:37 100-41-41.0 1
2-Hexanone ND ug/L 11/22/23 15:37 591-78-65.0 1
Iodomethane ND ug/L 11/22/23 15:37 74-88-420.0 1
Methylene Chloride ND ug/L 11/22/23 15:37 75-09-25.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/22/23 15:37 108-10-15.0 1
Naphthalene ND ug/L 11/22/23 15:37 91-20-31.0 1
Styrene ND ug/L 11/22/23 15:37 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 11/22/23 15:37 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 11/22/23 15:37 79-34-51.0 1
Tetrachloroethene ND ug/L 11/22/23 15:37 127-18-41.0 1
Toluene ND ug/L 11/22/23 15:37 108-88-31.0 1
1,1,1-Trichloroethane ND ug/L 11/22/23 15:37 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 11/22/23 15:37 79-00-51.0 1
Trichloroethene ND ug/L 11/22/23 15:37 79-01-61.0 1
Trichlorofluoromethane ND ug/L 11/22/23 15:37 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 11/22/23 15:37 96-18-41.0 1
Vinyl acetate ND ug/L 11/22/23 15:37 108-05-42.0 1
Vinyl chloride ND ug/L 11/22/23 15:37 75-01-41.0 1
Xylene (Total)ND ug/L 11/22/23 15:37 1330-20-71.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 07:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92699898
OCSWM FALL-NORTH (MW-04)
Sample: TRIP BLANK Lab ID: 92699898002 Collected:Received: 11/20/23 14:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
m&p-Xylene ND ug/L 11/22/23 15:37 179601-23-12.0 1
o-Xylene ND ug/L 11/22/23 15:37 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)94 %11/22/23 15:37 460-00-470-130 1
1,2-Dichloroethane-d4 (S)89 %11/22/23 15:37 17060-07-070-130 1
Toluene-d8 (S)96 %11/22/23 15:37 2037-26-570-130 1
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
8260D MSV SIM
1,4-Dioxane (p-Dioxane)ND ug/L 11/22/23 22:37 123-91-12.0 1
Surrogates
1,2-Dichloroethane-d4 (S)90 %11/22/23 22:37 17060-07-067-130 1
Toluene-d8 (S)92 %11/22/23 22:37 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 07:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699898
OCSWM FALL-NORTH (MW-04)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815270
EPA 7470A
EPA 7470A
7470 Mercury
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples: 92699898001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4220654
Associated Lab Samples:92699898001
Matrix: Water
Analyzed
Mercury ug/L ND 0.20 11/25/23 10:05
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4220655LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4220656MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699898001
4220657
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Mercury ug/L 2.5 101 75-125100 02.5ND 2.5 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 07:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699898
OCSWM FALL-NORTH (MW-04)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815073
EPA 3010A
EPA 6010D
6010 MET
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples: 92699898001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4219471
Associated Lab Samples:92699898001
Matrix: Water
Analyzed
Antimony ug/L ND 5.0 12/03/23 11:26
Arsenic ug/L ND 10.0 12/03/23 11:26
Barium ug/L ND 5.0 12/03/23 11:26
Beryllium ug/L ND 1.0 12/03/23 11:26
Cadmium ug/L ND 1.0 12/03/23 11:26
Chromium ug/L ND 5.0 12/03/23 11:26
Cobalt ug/L ND 5.0 12/03/23 11:26
Copper ug/L ND 5.0 12/03/23 11:26
Iron ug/L ND 50.0 12/03/23 11:26
Lead ug/L ND 5.0 12/03/23 11:26
Manganese ug/L ND 5.0 12/03/23 11:26
Nickel ug/L ND 5.0 12/03/23 11:26
Selenium ug/L ND 10.0 12/03/23 11:26
Silver ug/L ND 5.0 12/03/23 11:26
Thallium ug/L ND 10.0 12/03/23 11:26
Vanadium ug/L ND 5.0 12/03/23 11:26
Zinc ug/L ND 10.0 12/03/23 11:26
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4219472LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 509500 102 80-120
Arsenic ug/L 505500 101 80-120
Barium ug/L 521500 104 80-120
Beryllium ug/L 506500 101 80-120
Cadmium ug/L 510500 102 80-120
Chromium ug/L 510500 102 80-120
Cobalt ug/L 510500 102 80-120
Copper ug/L 512500 102 80-120
Iron ug/L 51905000 104 80-120
Lead ug/L 509500 102 80-120
Manganese ug/L 517500 103 80-120
Nickel ug/L 507500 101 80-120
Selenium ug/L 494500 99 80-120
Silver ug/L 255250 102 80-120
Thallium ug/L 515500 103 80-120
Vanadium ug/L 509500 102 80-120
Zinc ug/L 506500 101 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 07:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699898
OCSWM FALL-NORTH (MW-04)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4219473MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699898001
4219474
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Antimony ug/L 500 102 75-125103 1500ND512 515
Arsenic ug/L 500 103 75-125103 0500ND515 516
Barium ug/L 500 102 75-125105 350080.1 589 606
Beryllium ug/L 500 103 75-125104 1500ND516 520
Cadmium ug/L 500 102 75-125102 1500ND508 512
Chromium ug/L 500 103 75-125103 1500ND513 517
Cobalt ug/L 500 102 75-125103 1500ND508 513
Copper ug/L 500 102 75-125103 1500ND510 514
Iron ug/L 5000 102 75-125105 350001065230 5370
Lead ug/L 500 101 75-125102 1500ND503 509
Manganese ug/L 500 102 75-125105 3500ND514 529
Nickel ug/L 500 101 75-125102 1500ND505 510
Selenium ug/L 500 104 75-125104 1500ND518 522
Silver ug/L 250 103 75-125103 0250ND257 258
Thallium ug/L 500 101 75-125103 1500ND509 515
Vanadium ug/L 500 101 75-125102 1500ND508 512
Zinc ug/L 500 101 75-125102 1500ND515 521
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4219475MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699907002
4219476
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Antimony ug/L 500 105 75-125104 1500ND525 522
Arsenic ug/L 500 105 75-125105 0500ND526 525
Barium ug/L 500 107 75-125107 0500ND539 541
Beryllium ug/L 500 106 75-125105 0500ND529 527
Cadmium ug/L 500 104 75-125104 0500ND519 518
Chromium ug/L 500 105 75-125105 0500ND528 526
Cobalt ug/L 500 104 75-125104 0500ND520 519
Copper ug/L 500 105 75-125105 0500ND524 524
Iron ug/L 5000 108 75-125111 350001395530 5670
Lead ug/L 500 103 75-125103 0500ND515 513
Manganese ug/L 500 107 75-125108 1500ND540 543
Nickel ug/L 500 103 75-125103 0500ND514 514
Selenium ug/L 500 107 75-125106 1500ND533 529
Silver ug/L 250 106 75-125105 1250ND264 262
Thallium ug/L 500 105 75-125104 1500ND526 521
Vanadium ug/L 500 104 75-125104 0500ND520 519
Zinc ug/L 500 103 75-125103 0500ND520 520
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 07:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699898
OCSWM FALL-NORTH (MW-04)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815175
EPA 8260D
EPA 8260D
8260D MSV Low Level Landfill
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples: 92699898001, 92699898002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4220008
Associated Lab Samples:92699898001, 92699898002
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 1.0 11/22/23 15:01
1,1,1-Trichloroethane ug/L ND 1.0 11/22/23 15:01
1,1,2,2-Tetrachloroethane ug/L ND 1.0 11/22/23 15:01
1,1,2-Trichloroethane ug/L ND 1.0 11/22/23 15:01
1,1-Dichloroethane ug/L ND 1.0 11/22/23 15:01
1,1-Dichloroethene ug/L ND 1.0 11/22/23 15:01
1,2,3-Trichloropropane ug/L ND 1.0 11/22/23 15:01
1,2-Dichlorobenzene ug/L ND 1.0 11/22/23 15:01
1,2-Dichloroethane ug/L ND 1.0 11/22/23 15:01
1,2-Dichloropropane ug/L ND 1.0 11/22/23 15:01
1,4-Dichlorobenzene ug/L ND 1.0 11/22/23 15:01
2-Butanone (MEK)ug/L ND 5.0 11/22/23 15:01
2-Hexanone ug/L ND 5.0 11/22/23 15:01
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 11/22/23 15:01
Acetone ug/L ND 25.0 v211/22/23 15:01
Acrylonitrile ug/L ND 10.0 11/22/23 15:01
Benzene ug/L ND 1.0 11/22/23 15:01
Bromochloromethane ug/L ND 1.0 11/22/23 15:01
Bromodichloromethane ug/L ND 1.0 11/22/23 15:01
Bromoform ug/L ND 1.0 11/22/23 15:01
Bromomethane ug/L ND 2.0 11/22/23 15:01
Carbon disulfide ug/L ND 2.0 11/22/23 15:01
Carbon tetrachloride ug/L ND 1.0 11/22/23 15:01
Chlorobenzene ug/L ND 1.0 11/22/23 15:01
Chloroethane ug/L ND 1.0 IK11/22/23 15:01
Chloroform ug/L ND 1.0 11/22/23 15:01
Chloromethane ug/L ND 1.0 11/22/23 15:01
cis-1,2-Dichloroethene ug/L ND 1.0 11/22/23 15:01
cis-1,3-Dichloropropene ug/L ND 1.0 11/22/23 15:01
Dibromochloromethane ug/L ND 1.0 11/22/23 15:01
Dibromomethane ug/L ND 1.0 11/22/23 15:01
Ethylbenzene ug/L ND 1.0 11/22/23 15:01
Iodomethane ug/L ND 20.0 11/22/23 15:01
m&p-Xylene ug/L ND 2.0 11/22/23 15:01
Methylene Chloride ug/L ND 5.0 11/22/23 15:01
Naphthalene ug/L ND 1.0 11/22/23 15:01
o-Xylene ug/L ND 1.0 11/22/23 15:01
Styrene ug/L ND 1.0 11/22/23 15:01
Tetrachloroethene ug/L ND 1.0 11/22/23 15:01
Toluene ug/L ND 1.0 11/22/23 15:01
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 07:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699898
OCSWM FALL-NORTH (MW-04)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4220008
Associated Lab Samples:92699898001, 92699898002
Matrix: Water
Analyzed
trans-1,2-Dichloroethene ug/L ND 1.0 11/22/23 15:01
trans-1,3-Dichloropropene ug/L ND 1.0 11/22/23 15:01
trans-1,4-Dichloro-2-butene ug/L ND 1.0 11/22/23 15:01
Trichloroethene ug/L ND 1.0 11/22/23 15:01
Trichlorofluoromethane ug/L ND 1.0 11/22/23 15:01
Vinyl acetate ug/L ND 2.0 11/22/23 15:01
Vinyl chloride ug/L ND 1.0 11/22/23 15:01
Xylene (Total)ug/L ND 1.0 11/22/23 15:01
1,2-Dichloroethane-d4 (S)%88 70-130 11/22/23 15:01
4-Bromofluorobenzene (S)%96 70-130 11/22/23 15:01
Toluene-d8 (S)%96 70-130 11/22/23 15:01
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4220009LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 18.120 90 70-130
1,1,1-Trichloroethane ug/L 18.220 91 70-130
1,1,2,2-Tetrachloroethane ug/L 19.120 96 70-130
1,1,2-Trichloroethane ug/L 19.320 96 70-130
1,1-Dichloroethane ug/L 17.020 85 70-130
1,1-Dichloroethene ug/L 19.620 98 69-131
1,2,3-Trichloropropane ug/L 18.220 91 70-130
1,2-Dichlorobenzene ug/L 18.920 94 70-130
1,2-Dichloroethane ug/L 17.820 89 70-130
1,2-Dichloropropane ug/L 17.520 88 70-130
1,4-Dichlorobenzene ug/L 18.820 94 70-130
2-Butanone (MEK)ug/L 30.340 76 67-133
2-Hexanone ug/L 34.440 86 70-133
4-Methyl-2-pentanone (MIBK)ug/L 34.640 86 70-130
Acetone ug/L 30.5 v34076 67-130
Acrylonitrile ug/L 83.9100 84 70-130
Benzene ug/L 17.720 89 70-130
Bromochloromethane ug/L 18.420 92 70-130
Bromodichloromethane ug/L 17.820 89 70-130
Bromoform ug/L 17.920 89 70-133
Bromomethane ug/L 19.420 97 41-148
Carbon disulfide ug/L 18.520 92 70-131
Carbon tetrachloride ug/L 18.020 90 70-130
Chlorobenzene ug/L 18.920 94 70-130
Chloroethane ug/L 19.8 IK2099 41-157
Chloroform ug/L 18.120 90 70-130
Chloromethane ug/L 16.520 83 59-141
cis-1,2-Dichloroethene ug/L 16.920 85 70-130
cis-1,3-Dichloropropene ug/L 17.620 88 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 07:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699898
OCSWM FALL-NORTH (MW-04)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4220009LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromochloromethane ug/L 17.120 86 70-130
Dibromomethane ug/L 19.020 95 70-130
Ethylbenzene ug/L 18.220 91 70-130
Iodomethane ug/L 33.340 83 57-140
m&p-Xylene ug/L 37.040 92 70-130
Methylene Chloride ug/L 17.520 88 62-130
Naphthalene ug/L 17.220 86 70-135
o-Xylene ug/L 18.120 91 70-130
Styrene ug/L 18.420 92 70-130
Tetrachloroethene ug/L 17.920 90 70-130
Toluene ug/L 18.020 90 70-130
trans-1,2-Dichloroethene ug/L 17.120 86 70-130
trans-1,3-Dichloropropene ug/L 17.520 88 70-130
trans-1,4-Dichloro-2-butene ug/L 18.020 90 57-149
Trichloroethene ug/L 18.920 94 70-130
Trichlorofluoromethane ug/L 22.320 111 57-130
Vinyl acetate ug/L 37.140 93 70-141
Vinyl chloride ug/L 16.920 85 66-140
Xylene (Total)ug/L 55.160 92 70-130
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%97 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4220010MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699898001
4220011
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 118 70-146117 020ND23.5 23.4
1,1,1-Trichloroethane ug/L 20 126 70-150127 120ND25.2 25.5
1,1,2,2-Tetrachloroethane ug/L 20 116 66-144114 220ND23.2 22.7
1,1,2-Trichloroethane ug/L 20 124 70-142121 220ND24.8 24.2
1,1-Dichloroethane ug/L 20 114 68-150115 120ND22.9 23.0
1,1-Dichloroethene ug/L 20 134 64-162136 120ND26.9 27.2
1,2,3-Trichloropropane ug/L 20 111 66-144109 220ND22.2 21.7
1,2-Dichlorobenzene ug/L 20 114 70-142117 220ND22.8 23.4
1,2-Dichloroethane ug/L 20 115 68-145116 120ND23.0 23.2
1,2-Dichloropropane ug/L 20 113 70-144112 020ND22.5 22.4
1,4-Dichlorobenzene ug/L 20 116 70-140118 220ND23.1 23.7
2-Butanone (MEK)ug/L 40 96 57-15692 540ND38.6 36.8
2-Hexanone ug/L 40 101 62-15396 540ND40.4 38.4
4-Methyl-2-pentanone (MIBK) ug/L 40 105 65-144100 540ND42.1 40.1
Acetone ug/L 40 96 49-16292 540ND38.5 36.8
Acrylonitrile ug/L 100 104 59-155101 3100ND104 101
Benzene ug/L 20 118 68-144117 120ND23.7 23.4
Bromochloromethane ug/L 20 122 70-148123 120ND24.5 24.7
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 07:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699898
OCSWM FALL-NORTH (MW-04)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4220010MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699898001
4220011
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Bromodichloromethane ug/L 20 118 70-141115 220ND23.5 23.0
Bromoform ug/L 20 115 59-144114 120ND23.0 22.7
Bromomethane ug/L 20 126 23-190136 820ND25.2 27.3
Carbon disulfide ug/L v32012864-160131 220ND25.6 26.2
Carbon tetrachloride ug/L 20 126 70-147126 020ND25.2 25.3
Chlorobenzene ug/L 20 119 70-143120 020ND23.9 24.0
Chloroethane ug/L IK2013355-190136 220ND26.7 27.1
Chloroform ug/L 20 118 67-148124 520ND23.5 24.8
Chloromethane ug/L 20 106 38-180109 320ND21.1 21.8
cis-1,2-Dichloroethene ug/L 20 113 67-151114 120ND22.6 22.7
cis-1,3-Dichloropropene ug/L 20 114 70-142112 220ND22.8 22.3
Dibromochloromethane ug/L 20 110 68-140109 120ND22.0 21.8
Dibromomethane ug/L 20 124 70-142122 220ND24.9 24.5
Ethylbenzene ug/L 20 117 70-145117 020ND23.4 23.4
Iodomethane ug/L v34011237-160116 340ND44.9 46.4
m&p-Xylene ug/L 40 118 70-148118 040ND47.1 47.1
Methylene Chloride ug/L 20 110 54-149111 120ND22.0 22.1
Naphthalene ug/L 20 104 62-154104 020ND20.8 20.7
o-Xylene ug/L 20 116 70-145116 020ND23.2 23.2
Styrene ug/L 20 115 70-147115 020ND22.9 23.0
Tetrachloroethene ug/L 20 121 70-145120 120ND24.1 24.0
Toluene ug/L 20 121 65-146120 120ND24.3 24.0
trans-1,2-Dichloroethene ug/L 20 118 69-155119 120ND23.6 23.8
trans-1,3-Dichloropropene ug/L 20 114 70-142112 220ND22.9 22.4
trans-1,4-Dichloro-2-butene ug/L 20 111 39-149105 520ND22.2 21.1
Trichloroethene ug/L 20 128 70-152128 020ND25.6 25.6
Trichlorofluoromethane ug/L 20 157 60-158158 120ND31.3 31.6
Vinyl acetate ug/L 40 117 56-157114 240ND46.8 45.7
Vinyl chloride ug/L 20 116 51-178118 220ND23.1 23.5
Xylene (Total)ug/L 60 117 70-146117 060ND70.3 70.3
1,2-Dichloroethane-d4 (S)%96 70-13095
4-Bromofluorobenzene (S)%100 70-13097
Toluene-d8 (S)%98 70-13097
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 07:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699898
OCSWM FALL-NORTH (MW-04)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815205
EPA 8260D Mod.
EPA 8260D Mod.
8260D MSV SIM
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples: 92699898001, 92699898002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4220270
Associated Lab Samples:92699898001, 92699898002
Matrix: Water
Analyzed
1,4-Dioxane (p-Dioxane)ug/L ND 2.0 11/22/23 17:58
1,2-Dichloroethane-d4 (S)%88 67-130 11/22/23 17:58
Toluene-d8 (S)%90 70-130 11/22/23 17:58
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4220271LABORATORY CONTROL SAMPLE:
LCSSpike
1,4-Dioxane (p-Dioxane)ug/L 17.120 86 70-130
1,2-Dichloroethane-d4 (S)%87 67-130
Toluene-d8 (S)%92 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4220272MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699898001
4220273
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,4-Dioxane (p-Dioxane)ug/L 20 85 55-13790 620ND16.9 17.9
1,2-Dichloroethane-d4 (S)%89 67-13090
Toluene-d8 (S)%92 70-13092
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4220274MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699907002
4220275
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,4-Dioxane (p-Dioxane)ug/L 20 96 55-13795 020ND19.1 19.1
1,2-Dichloroethane-d4 (S)%88 67-13089
Toluene-d8 (S)%91 70-13092
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 07:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699898
OCSWM FALL-NORTH (MW-04)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
816023
SM 2320B-2011
SM 2320B-2011
2320B Alkalinity
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples: 92699898001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4223590
Associated Lab Samples:92699898001
Matrix: Water
Analyzed
Alkalinity, Total as CaCO3 mg/L ND 5.0 11/29/23 12:59
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4223591LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 50.950 102 80-120
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4223592LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 50.550 101 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4223593MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699898001
4223594
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 101 80-120106 35030.3 80.8 83.2
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4223595MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699907002
4223596
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 101 80-120102 05044.0 94.7 94.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 07:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699898
OCSWM FALL-NORTH (MW-04)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815397
SM 2540C-2015
SM 2540C-2015
2540C Total Dissolved Solids
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples: 92699898001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4220963
Associated Lab Samples:92699898001
Matrix: Water
Analyzed
Total Dissolved Solids mg/L ND 25.0 11/27/23 10:23
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4220964LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids mg/L 256250 102 90-110
Parameter Units
Dup
Result QualifiersRPDResult
92699633003
4220965SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 1310 51380
Parameter Units
Dup
Result QualifiersRPDResult
92699658007
4220966SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 32.0 935.0
Parameter Units
Dup
Result QualifiersRPDResult
92699898001
4226112SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 73.0 H1768.0
Parameter Units
Dup
Result QualifiersRPDResult
92699907002
4226113SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 86.0 H11078.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 07:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699898
OCSWM FALL-NORTH (MW-04)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815250
SM 4500-S2D-2011
SM 4500-S2D-2011
4500S2D Sulfide Water
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples: 92699898001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4220621
Associated Lab Samples:92699898001
Matrix: Water
Analyzed
Sulfide mg/L ND 0.10 11/23/23 04:03
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4220622LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.520.5 105 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4220623MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699313003
4220624
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Sulfide mg/L 0.5 103 80-120106 40.5ND 0.51 0.53
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4220637MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699898001
4220638
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Sulfide mg/L 0.5 102 80-120106 30.5ND 0.51 0.53
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 07:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699898
OCSWM FALL-NORTH (MW-04)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
814961
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
300.0 IC Anions
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples: 92699898001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4219102
Associated Lab Samples:92699898001
Matrix: Water
Analyzed
Chloride mg/L ND 1.0 11/22/23 01:40
Sulfate mg/L ND 1.0 11/22/23 01:40
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4219103LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride mg/L 53.050 106 90-110
Sulfate mg/L 52.550 105 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4219104MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699898001
4219105
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Chloride mg/L 50 99 90-110102 3508.0 57.7 59.2
Sulfate mg/L 50 98 90-110101 350ND49.0 50.6
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4219106MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699907002
4219107
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Chloride mg/L 50 99 90-110102 3502.3 51.9 53.4
Sulfate mg/L 50 98 90-110101 3502.2 51.2 52.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 07:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699898
OCSWM FALL-NORTH (MW-04)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815297
SM 3500-Cr B-2011
SM 3500-Cr B-2011
Chromium, Hexavalent by SM3500-Cr B-2011
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples: 92699898001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4220712
Associated Lab Samples:92699898001
Matrix: Water
Analyzed
Chromium, Hexavalent mg/L ND 0.010 11/25/23 15:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4220713LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent mg/L 0.260.25 104 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4220714MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699898001
4220715
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Chromium, Hexavalent mg/L M10.25 75 90-11079 50.250.010 0.20 0.21
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4220716MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699907002
4220717
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Chromium, Hexavalent mg/L 0.25 99 90-11096 30.250.011 0.26 0.25
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 07:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 27
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92699898
OCSWM FALL-NORTH (MW-04)
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Analysis conducted outside the EPA method holding time.H1
The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.IK
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.v2
The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.v3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 07:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 27
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92699898
OCSWM FALL-NORTH (MW-04)
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92699898001 815073 8151836801-MW04 EPA 3010A EPA 6010D
92699898001 815270 8152936801-MW04 EPA 7470A EPA 7470A
92699898001 8151756801-MW04 EPA 8260D
92699898002 815175TRIP BLANK EPA 8260D
92699898001 8152056801-MW04 EPA 8260D Mod.
92699898002 815205TRIP BLANK EPA 8260D Mod.
92699898001 8160236801-MW04 SM 2320B-2011
92699898001 8153976801-MW04 SM 2540C-2015
92699898001 8152506801-MW04 SM 4500-S2D-2011
92699898001 8149616801-MW04 EPA 300.0 Rev 2.1 1993
92699898001 8152976801-MW04 SM 3500-Cr B-2011
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 07:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 27
Page 24 of 27
Page 25 of 27
Page 26 of 27
Page 27 of 27
#=CL#
December 04, 2023
LIMS USE: FR - DEBORAH COAKLEY
LIMS OBJECT ID: 92699907
92699907
Project:
Pace Project No.:
RE:
Deborah Ann Coakley
TRC Companies
1030 Wilmer Ave.
Suite 100
Richmond, VA 23227
OCSWM FALL-SOUTH MW110D/MW110S
Dear Deborah Coakley:
Enclosed are the analytical results for sample(s) received by the laboratory on November 20, 2023. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Matthew Brainard
[e-mail]
Project Manager
704-977-0942
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 32
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 32
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92699907001 6801-MW110D EPA 6010D 1 PASI-ASBW
SM 3500-Cr B-2011 1 PASI-AJMH1
92699907002 6801-MW110S EPA 6010D 17 PASI-ASBW
EPA 7470A 1 PASI-ABM
EPA 8260D 51 PASI-CJJK
EPA 8260D Mod.3 PASI-CTEG
SM 2320B-2011 1 PASI-ASMS
SM 2540C-2015 1 PASI-AJAY
EPA 300.0 Rev 2.1 1993 2 PASI-ACDC
SM 3500-Cr B-2011 1 PASI-AJMH1
92699907003 TRIP BLANK EPA 8260D 51 PASI-CSAS
EPA 8260D Mod.3 PASI-CTEG
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Sample: 6801-MW110D Lab ID: 92699907001 Collected: 11/20/23 12:20 Received: 11/20/23 14:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services - Asheville
6010 MET ICP
Arsenic 14.0 ug/L 12/03/23 12:58 7440-38-211/22/23 11:5510.0 1
Analytical Method: SM 3500-Cr B-2011
Pace Analytical Services - Asheville
Chromium, Hexavalent, 28 Day
Chromium, Hexavalent ND mg/L 11/25/23 15:15 18540-29-90.010 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 04:24 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
Page 4 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Sample: 6801-MW110S Lab ID: 92699907002 Collected: 11/20/23 11:35 Received: 11/20/23 14:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services - Asheville
6010 MET ICP
Antimony ND ug/L 12/03/23 13:03 7440-36-011/22/23 11:555.0 1
Arsenic ND ug/L 12/03/23 13:03 7440-38-211/22/23 11:5510.0 1
Barium ND ug/L 12/03/23 13:03 7440-39-311/22/23 11:555.0 1
Beryllium ND ug/L 12/03/23 13:03 7440-41-711/22/23 11:551.0 1
Cadmium ND ug/L 12/03/23 13:03 7440-43-911/22/23 11:551.0 1
Chromium ND ug/L 12/03/23 13:03 7440-47-311/22/23 11:555.0 1
Cobalt ND ug/L 12/03/23 13:03 7440-48-411/22/23 11:555.0 1
Copper ND ug/L 12/03/23 13:03 7440-50-811/22/23 11:555.0 1
Iron 139 ug/L 12/03/23 13:03 7439-89-611/22/23 11:5550.0 1
Lead ND ug/L 12/03/23 13:03 7439-92-111/22/23 11:555.0 1
Manganese ND ug/L 12/03/23 13:03 7439-96-511/22/23 11:555.0 1
Nickel ND ug/L 12/03/23 13:03 7440-02-011/22/23 11:555.0 1
Selenium ND ug/L 12/03/23 13:03 7782-49-211/22/23 11:5510.0 1
Silver ND ug/L 12/03/23 13:03 7440-22-411/22/23 11:555.0 1
Thallium ND ug/L 12/03/23 13:03 7440-28-011/22/23 11:5510.0 1
Vanadium ND ug/L 12/03/23 13:03 7440-62-211/22/23 11:555.0 1
Zinc ND ug/L 12/03/23 13:03 7440-66-611/22/23 11:5510.0 1
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services - Asheville
7470 Mercury
Mercury ND ug/L 11/26/23 16:34 7439-97-611/26/23 12:560.20 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 11/30/23 18:34 67-64-125.0 1
Acrylonitrile ND ug/L 11/30/23 18:34 107-13-110.0 1
Benzene ND ug/L 11/30/23 18:34 71-43-21.0 1
Bromochloromethane ND ug/L 11/30/23 18:34 74-97-51.0 1
Bromodichloromethane ND ug/L 11/30/23 18:34 75-27-41.0 1
Bromoform ND ug/L 11/30/23 18:34 75-25-21.0 1
Bromomethane ND ug/L 11/30/23 18:34 74-83-9 v22.0 1
2-Butanone (MEK)ND ug/L 11/30/23 18:34 78-93-35.0 1
Carbon disulfide ND ug/L 11/30/23 18:34 75-15-02.0 1
Carbon tetrachloride ND ug/L 11/30/23 18:34 56-23-51.0 1
Chlorobenzene ND ug/L 11/30/23 18:34 108-90-71.0 1
Chloroethane ND ug/L 11/30/23 18:34 75-00-31.0 1
Chloroform ND ug/L 11/30/23 18:34 67-66-31.0 1
Chloromethane ND ug/L 11/30/23 18:34 74-87-3 M11.0 1
Dibromochloromethane ND ug/L 11/30/23 18:34 124-48-11.0 1
Dibromomethane ND ug/L 11/30/23 18:34 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 11/30/23 18:34 95-50-11.0 1
1,4-Dichlorobenzene ND ug/L 11/30/23 18:34 106-46-71.0 1
trans-1,4-Dichloro-2-butene ND ug/L 11/30/23 18:34 110-57-61.0 1
1,1-Dichloroethane ND ug/L 11/30/23 18:34 75-34-31.0 1
1,2-Dichloroethane ND ug/L 11/30/23 18:34 107-06-21.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 04:24 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Sample: 6801-MW110S Lab ID: 92699907002 Collected: 11/20/23 11:35 Received: 11/20/23 14:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
1,1-Dichloroethene ND ug/L 11/30/23 18:34 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 11/30/23 18:34 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 11/30/23 18:34 156-60-51.0 1
1,2-Dichloropropane ND ug/L 11/30/23 18:34 78-87-51.0 1
cis-1,3-Dichloropropene ND ug/L 11/30/23 18:34 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 11/30/23 18:34 10061-02-61.0 1
Ethylbenzene ND ug/L 11/30/23 18:34 100-41-41.0 1
2-Hexanone ND ug/L 11/30/23 18:34 591-78-65.0 1
Iodomethane ND ug/L 11/30/23 18:34 74-88-4 v220.0 1
Methylene Chloride ND ug/L 11/30/23 18:34 75-09-25.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/30/23 18:34 108-10-15.0 1
Styrene ND ug/L 11/30/23 18:34 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 11/30/23 18:34 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 11/30/23 18:34 79-34-51.0 1
Tetrachloroethene ND ug/L 11/30/23 18:34 127-18-41.0 1
Tetrahydrofuran ND ug/L 11/30/23 18:34 109-99-910.0 1
Toluene ND ug/L 11/30/23 18:34 108-88-31.0 1
1,1,1-Trichloroethane ND ug/L 11/30/23 18:34 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 11/30/23 18:34 79-00-51.0 1
Trichloroethene ND ug/L 11/30/23 18:34 79-01-61.0 1
Trichlorofluoromethane ND ug/L 11/30/23 18:34 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 11/30/23 18:34 96-18-41.0 1
Vinyl acetate ND ug/L 11/30/23 18:34 108-05-42.0 1
Vinyl chloride ND ug/L 11/30/23 18:34 75-01-4 M11.0 1
Xylene (Total)ND ug/L 11/30/23 18:34 1330-20-71.0 1
m&p-Xylene ND ug/L 11/30/23 18:34 179601-23-12.0 1
o-Xylene ND ug/L 11/30/23 18:34 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)100 %11/30/23 18:34 460-00-470-130 1
1,2-Dichloroethane-d4 (S)96 %11/30/23 18:34 17060-07-070-130 1
Toluene-d8 (S)105 %11/30/23 18:34 2037-26-570-130 1
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
8260D MSV SIM
1,4-Dioxane (p-Dioxane)ND ug/L 11/22/23 23:19 123-91-12.0 1
Surrogates
1,2-Dichloroethane-d4 (S)89 %11/22/23 23:19 17060-07-067-130 1
Toluene-d8 (S)92 %11/22/23 23:19 2037-26-570-130 1
Analytical Method: SM 2320B-2011
Pace Analytical Services - Asheville
2320B Alkalinity
Alkalinity, Total as CaCO3 44.0 mg/L 11/29/23 13:505.0 1
Analytical Method: SM 2540C-2015
Pace Analytical Services - Asheville
2540C Total Dissolved Solids
Total Dissolved Solids 78.0 mg/L 11/27/23 10:25 H125.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 04:24 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Sample: 6801-MW110S Lab ID: 92699907002 Collected: 11/20/23 11:35 Received: 11/20/23 14:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Chloride 2.3 mg/L 11/22/23 03:32 16887-00-61.0 1
Sulfate 2.2 mg/L 11/22/23 03:32 14808-79-81.0 1
Analytical Method: SM 3500-Cr B-2011
Pace Analytical Services - Asheville
Chromium, Hexavalent, 28 Day
Chromium, Hexavalent 0.011 mg/L 11/25/23 15:15 18540-29-90.010 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 04:24 PM
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Huntersville, NC 28078
[phone]
Page 7 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Sample: TRIP BLANK Lab ID: 92699907003 Collected: 11/20/23 00:00 Received: 11/20/23 14:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 11/22/23 15:55 67-64-1 v225.0 1
Acrylonitrile ND ug/L 11/22/23 15:55 107-13-110.0 1
Benzene ND ug/L 11/22/23 15:55 71-43-21.0 1
Bromochloromethane ND ug/L 11/22/23 15:55 74-97-51.0 1
Bromodichloromethane ND ug/L 11/22/23 15:55 75-27-41.0 1
Bromoform ND ug/L 11/22/23 15:55 75-25-21.0 1
Bromomethane ND ug/L 11/22/23 15:55 74-83-92.0 1
2-Butanone (MEK)ND ug/L 11/22/23 15:55 78-93-35.0 1
Carbon disulfide ND ug/L 11/22/23 15:55 75-15-02.0 1
Carbon tetrachloride ND ug/L 11/22/23 15:55 56-23-51.0 1
Chlorobenzene ND ug/L 11/22/23 15:55 108-90-71.0 1
Chloroethane ND ug/L 11/22/23 15:55 75-00-3 IK1.0 1
Chloroform ND ug/L 11/22/23 15:55 67-66-31.0 1
Chloromethane ND ug/L 11/22/23 15:55 74-87-31.0 1
Dibromochloromethane ND ug/L 11/22/23 15:55 124-48-11.0 1
Dibromomethane ND ug/L 11/22/23 15:55 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 11/22/23 15:55 95-50-11.0 1
1,4-Dichlorobenzene ND ug/L 11/22/23 15:55 106-46-71.0 1
trans-1,4-Dichloro-2-butene ND ug/L 11/22/23 15:55 110-57-61.0 1
1,1-Dichloroethane ND ug/L 11/22/23 15:55 75-34-31.0 1
1,2-Dichloroethane ND ug/L 11/22/23 15:55 107-06-21.0 1
1,1-Dichloroethene ND ug/L 11/22/23 15:55 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 11/22/23 15:55 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 11/22/23 15:55 156-60-51.0 1
1,2-Dichloropropane ND ug/L 11/22/23 15:55 78-87-51.0 1
cis-1,3-Dichloropropene ND ug/L 11/22/23 15:55 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 11/22/23 15:55 10061-02-61.0 1
Ethylbenzene ND ug/L 11/22/23 15:55 100-41-41.0 1
2-Hexanone ND ug/L 11/22/23 15:55 591-78-65.0 1
Iodomethane ND ug/L 11/22/23 15:55 74-88-420.0 1
Methylene Chloride ND ug/L 11/22/23 15:55 75-09-25.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/22/23 15:55 108-10-15.0 1
Styrene ND ug/L 11/22/23 15:55 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 11/22/23 15:55 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 11/22/23 15:55 79-34-51.0 1
Tetrachloroethene ND ug/L 11/22/23 15:55 127-18-41.0 1
Tetrahydrofuran ND ug/L 11/22/23 15:55 109-99-910.0 1
Toluene ND ug/L 11/22/23 15:55 108-88-31.0 1
1,1,1-Trichloroethane ND ug/L 11/22/23 15:55 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 11/22/23 15:55 79-00-51.0 1
Trichloroethene ND ug/L 11/22/23 15:55 79-01-61.0 1
Trichlorofluoromethane ND ug/L 11/22/23 15:55 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 11/22/23 15:55 96-18-41.0 1
Vinyl acetate ND ug/L 11/22/23 15:55 108-05-42.0 1
Vinyl chloride ND ug/L 11/22/23 15:55 75-01-41.0 1
Xylene (Total)ND ug/L 11/22/23 15:55 1330-20-71.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 04:24 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Sample: TRIP BLANK Lab ID: 92699907003 Collected: 11/20/23 00:00 Received: 11/20/23 14:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
m&p-Xylene ND ug/L 11/22/23 15:55 179601-23-12.0 1
o-Xylene ND ug/L 11/22/23 15:55 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)96 %11/22/23 15:55 460-00-470-130 1
1,2-Dichloroethane-d4 (S)89 %11/22/23 15:55 17060-07-070-130 1
Toluene-d8 (S)97 %11/22/23 15:55 2037-26-570-130 1
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
8260D MSV SIM
1,4-Dioxane (p-Dioxane)ND ug/L 11/22/23 22:15 123-91-12.0 1
Surrogates
1,2-Dichloroethane-d4 (S)91 %11/22/23 22:15 17060-07-067-130 1
Toluene-d8 (S)92 %11/22/23 22:15 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 04:24 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815335
EPA 7470A
EPA 7470A
7470 Mercury
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples: 92699907002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4220816
Associated Lab Samples:92699907002
Matrix: Water
Analyzed
Mercury ug/L ND 0.20 11/26/23 16:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4220817LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.32.5 93 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4220818MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699907002
4220819
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Mercury ug/L 2.5 96 75-12593 32.5ND 2.4 2.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 04:24 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815073
EPA 3010A
EPA 6010D
6010 MET
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples: 92699907001, 92699907002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4219471
Associated Lab Samples:92699907001, 92699907002
Matrix: Water
Analyzed
Antimony ug/L ND 5.0 12/03/23 11:26
Arsenic ug/L ND 10.0 12/03/23 11:26
Barium ug/L ND 5.0 12/03/23 11:26
Beryllium ug/L ND 1.0 12/03/23 11:26
Cadmium ug/L ND 1.0 12/03/23 11:26
Chromium ug/L ND 5.0 12/03/23 11:26
Cobalt ug/L ND 5.0 12/03/23 11:26
Copper ug/L ND 5.0 12/03/23 11:26
Iron ug/L ND 50.0 12/03/23 11:26
Lead ug/L ND 5.0 12/03/23 11:26
Manganese ug/L ND 5.0 12/03/23 11:26
Nickel ug/L ND 5.0 12/03/23 11:26
Selenium ug/L ND 10.0 12/03/23 11:26
Silver ug/L ND 5.0 12/03/23 11:26
Thallium ug/L ND 10.0 12/03/23 11:26
Vanadium ug/L ND 5.0 12/03/23 11:26
Zinc ug/L ND 10.0 12/03/23 11:26
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4219472LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 509500 102 80-120
Arsenic ug/L 505500 101 80-120
Barium ug/L 521500 104 80-120
Beryllium ug/L 506500 101 80-120
Cadmium ug/L 510500 102 80-120
Chromium ug/L 510500 102 80-120
Cobalt ug/L 510500 102 80-120
Copper ug/L 512500 102 80-120
Iron ug/L 51905000 104 80-120
Lead ug/L 509500 102 80-120
Manganese ug/L 517500 103 80-120
Nickel ug/L 507500 101 80-120
Selenium ug/L 494500 99 80-120
Silver ug/L 255250 102 80-120
Thallium ug/L 515500 103 80-120
Vanadium ug/L 509500 102 80-120
Zinc ug/L 506500 101 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 04:24 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4219473MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699898001
4219474
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Antimony ug/L 500 102 75-125103 1500ND512 515
Arsenic ug/L 500 103 75-125103 0500ND515 516
Barium ug/L 500 102 75-125105 350080.1 589 606
Beryllium ug/L 500 103 75-125104 1500ND516 520
Cadmium ug/L 500 102 75-125102 1500ND508 512
Chromium ug/L 500 103 75-125103 1500ND513 517
Cobalt ug/L 500 102 75-125103 1500ND508 513
Copper ug/L 500 102 75-125103 1500ND510 514
Iron ug/L 5000 102 75-125105 350001065230 5370
Lead ug/L 500 101 75-125102 1500ND503 509
Manganese ug/L 500 102 75-125105 3500ND514 529
Nickel ug/L 500 101 75-125102 1500ND505 510
Selenium ug/L 500 104 75-125104 1500ND518 522
Silver ug/L 250 103 75-125103 0250ND257 258
Thallium ug/L 500 101 75-125103 1500ND509 515
Vanadium ug/L 500 101 75-125102 1500ND508 512
Zinc ug/L 500 101 75-125102 1500ND515 521
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4219475MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699907002
4219476
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Antimony ug/L 500 105 75-125104 1500ND525 522
Arsenic ug/L 500 105 75-125105 0500ND526 525
Barium ug/L 500 107 75-125107 0500ND539 541
Beryllium ug/L 500 106 75-125105 0500ND529 527
Cadmium ug/L 500 104 75-125104 0500ND519 518
Chromium ug/L 500 105 75-125105 0500ND528 526
Cobalt ug/L 500 104 75-125104 0500ND520 519
Copper ug/L 500 105 75-125105 0500ND524 524
Iron ug/L 5000 108 75-125111 350001395530 5670
Lead ug/L 500 103 75-125103 0500ND515 513
Manganese ug/L 500 107 75-125108 1500ND540 543
Nickel ug/L 500 103 75-125103 0500ND514 514
Selenium ug/L 500 107 75-125106 1500ND533 529
Silver ug/L 250 106 75-125105 1250ND264 262
Thallium ug/L 500 105 75-125104 1500ND526 521
Vanadium ug/L 500 104 75-125104 0500ND520 519
Zinc ug/L 500 103 75-125103 0500ND520 520
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 04:24 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815175
EPA 8260D
EPA 8260D
8260D MSV Low Level Landfill
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples: 92699907003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4220008
Associated Lab Samples:92699907003
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 1.0 11/22/23 15:01
1,1,1-Trichloroethane ug/L ND 1.0 11/22/23 15:01
1,1,2,2-Tetrachloroethane ug/L ND 1.0 11/22/23 15:01
1,1,2-Trichloroethane ug/L ND 1.0 11/22/23 15:01
1,1-Dichloroethane ug/L ND 1.0 11/22/23 15:01
1,1-Dichloroethene ug/L ND 1.0 11/22/23 15:01
1,2,3-Trichloropropane ug/L ND 1.0 11/22/23 15:01
1,2-Dichlorobenzene ug/L ND 1.0 11/22/23 15:01
1,2-Dichloroethane ug/L ND 1.0 11/22/23 15:01
1,2-Dichloropropane ug/L ND 1.0 11/22/23 15:01
1,4-Dichlorobenzene ug/L ND 1.0 11/22/23 15:01
2-Butanone (MEK)ug/L ND 5.0 11/22/23 15:01
2-Hexanone ug/L ND 5.0 11/22/23 15:01
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 11/22/23 15:01
Acetone ug/L ND 25.0 v211/22/23 15:01
Acrylonitrile ug/L ND 10.0 11/22/23 15:01
Benzene ug/L ND 1.0 11/22/23 15:01
Bromochloromethane ug/L ND 1.0 11/22/23 15:01
Bromodichloromethane ug/L ND 1.0 11/22/23 15:01
Bromoform ug/L ND 1.0 11/22/23 15:01
Bromomethane ug/L ND 2.0 11/22/23 15:01
Carbon disulfide ug/L ND 2.0 11/22/23 15:01
Carbon tetrachloride ug/L ND 1.0 11/22/23 15:01
Chlorobenzene ug/L ND 1.0 11/22/23 15:01
Chloroethane ug/L ND 1.0 IK11/22/23 15:01
Chloroform ug/L ND 1.0 11/22/23 15:01
Chloromethane ug/L ND 1.0 11/22/23 15:01
cis-1,2-Dichloroethene ug/L ND 1.0 11/22/23 15:01
cis-1,3-Dichloropropene ug/L ND 1.0 11/22/23 15:01
Dibromochloromethane ug/L ND 1.0 11/22/23 15:01
Dibromomethane ug/L ND 1.0 11/22/23 15:01
Ethylbenzene ug/L ND 1.0 11/22/23 15:01
Iodomethane ug/L ND 20.0 11/22/23 15:01
m&p-Xylene ug/L ND 2.0 11/22/23 15:01
Methylene Chloride ug/L ND 5.0 11/22/23 15:01
o-Xylene ug/L ND 1.0 11/22/23 15:01
Styrene ug/L ND 1.0 11/22/23 15:01
Tetrachloroethene ug/L ND 1.0 11/22/23 15:01
Tetrahydrofuran ug/L ND 10.0 11/22/23 15:01
Toluene ug/L ND 1.0 11/22/23 15:01
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 04:24 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4220008
Associated Lab Samples:92699907003
Matrix: Water
Analyzed
trans-1,2-Dichloroethene ug/L ND 1.0 11/22/23 15:01
trans-1,3-Dichloropropene ug/L ND 1.0 11/22/23 15:01
trans-1,4-Dichloro-2-butene ug/L ND 1.0 11/22/23 15:01
Trichloroethene ug/L ND 1.0 11/22/23 15:01
Trichlorofluoromethane ug/L ND 1.0 11/22/23 15:01
Vinyl acetate ug/L ND 2.0 11/22/23 15:01
Vinyl chloride ug/L ND 1.0 11/22/23 15:01
Xylene (Total)ug/L ND 1.0 11/22/23 15:01
1,2-Dichloroethane-d4 (S)%88 70-130 11/22/23 15:01
4-Bromofluorobenzene (S)%96 70-130 11/22/23 15:01
Toluene-d8 (S)%96 70-130 11/22/23 15:01
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4220009LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 18.120 90 70-130
1,1,1-Trichloroethane ug/L 18.220 91 70-130
1,1,2,2-Tetrachloroethane ug/L 19.120 96 70-130
1,1,2-Trichloroethane ug/L 19.320 96 70-130
1,1-Dichloroethane ug/L 17.020 85 70-130
1,1-Dichloroethene ug/L 19.620 98 69-131
1,2,3-Trichloropropane ug/L 18.220 91 70-130
1,2-Dichlorobenzene ug/L 18.920 94 70-130
1,2-Dichloroethane ug/L 17.820 89 70-130
1,2-Dichloropropane ug/L 17.520 88 70-130
1,4-Dichlorobenzene ug/L 18.820 94 70-130
2-Butanone (MEK)ug/L 30.340 76 67-133
2-Hexanone ug/L 34.440 86 70-133
4-Methyl-2-pentanone (MIBK)ug/L 34.640 86 70-130
Acetone ug/L 30.5 v34076 67-130
Acrylonitrile ug/L 83.9100 84 70-130
Benzene ug/L 17.720 89 70-130
Bromochloromethane ug/L 18.420 92 70-130
Bromodichloromethane ug/L 17.820 89 70-130
Bromoform ug/L 17.920 89 70-133
Bromomethane ug/L 19.420 97 41-148
Carbon disulfide ug/L 18.520 92 70-131
Carbon tetrachloride ug/L 18.020 90 70-130
Chlorobenzene ug/L 18.920 94 70-130
Chloroethane ug/L 19.8 IK2099 41-157
Chloroform ug/L 18.120 90 70-130
Chloromethane ug/L 16.520 83 59-141
cis-1,2-Dichloroethene ug/L 16.920 85 70-130
cis-1,3-Dichloropropene ug/L 17.620 88 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 04:24 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4220009LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromochloromethane ug/L 17.120 86 70-130
Dibromomethane ug/L 19.020 95 70-130
Ethylbenzene ug/L 18.220 91 70-130
Iodomethane ug/L 33.340 83 57-140
m&p-Xylene ug/L 37.040 92 70-130
Methylene Chloride ug/L 17.520 88 62-130
o-Xylene ug/L 18.120 91 70-130
Styrene ug/L 18.420 92 70-130
Tetrachloroethene ug/L 17.920 90 70-130
Tetrahydrofuran ug/L 164200 82 70-131
Toluene ug/L 18.020 90 70-130
trans-1,2-Dichloroethene ug/L 17.120 86 70-130
trans-1,3-Dichloropropene ug/L 17.520 88 70-130
trans-1,4-Dichloro-2-butene ug/L 18.020 90 57-149
Trichloroethene ug/L 18.920 94 70-130
Trichlorofluoromethane ug/L 22.320 111 57-130
Vinyl acetate ug/L 37.140 93 70-141
Vinyl chloride ug/L 16.920 85 66-140
Xylene (Total)ug/L 55.160 92 70-130
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%97 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4220010MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699898001
4220011
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 118 70-146117 020ND23.5 23.4
1,1,1-Trichloroethane ug/L 20 126 70-150127 120ND25.2 25.5
1,1,2,2-Tetrachloroethane ug/L 20 116 66-144114 220ND23.2 22.7
1,1,2-Trichloroethane ug/L 20 124 70-142121 220ND24.8 24.2
1,1-Dichloroethane ug/L 20 114 68-150115 120ND22.9 23.0
1,1-Dichloroethene ug/L 20 134 64-162136 120ND26.9 27.2
1,2,3-Trichloropropane ug/L 20 111 66-144109 220ND22.2 21.7
1,2-Dichlorobenzene ug/L 20 114 70-142117 220ND22.8 23.4
1,2-Dichloroethane ug/L 20 115 68-145116 120ND23.0 23.2
1,2-Dichloropropane ug/L 20 113 70-144112 020ND22.5 22.4
1,4-Dichlorobenzene ug/L 20 116 70-140118 220ND23.1 23.7
2-Butanone (MEK)ug/L 40 96 57-15692 540ND38.6 36.8
2-Hexanone ug/L 40 101 62-15396 540ND40.4 38.4
4-Methyl-2-pentanone (MIBK) ug/L 40 105 65-144100 540ND42.1 40.1
Acetone ug/L 40 96 49-16292 540ND38.5 36.8
Acrylonitrile ug/L 100 104 59-155101 3100ND104 101
Benzene ug/L 20 118 68-144117 120ND23.7 23.4
Bromochloromethane ug/L 20 122 70-148123 120ND24.5 24.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 04:24 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4220010MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699898001
4220011
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Bromodichloromethane ug/L 20 118 70-141115 220ND23.5 23.0
Bromoform ug/L 20 115 59-144114 120ND23.0 22.7
Bromomethane ug/L 20 126 23-190136 820ND25.2 27.3
Carbon disulfide ug/L v32012864-160131 220ND25.6 26.2
Carbon tetrachloride ug/L 20 126 70-147126 020ND25.2 25.3
Chlorobenzene ug/L 20 119 70-143120 020ND23.9 24.0
Chloroethane ug/L IK2013355-190136 220ND26.7 27.1
Chloroform ug/L 20 118 67-148124 520ND23.5 24.8
Chloromethane ug/L 20 106 38-180109 320ND21.1 21.8
cis-1,2-Dichloroethene ug/L 20 113 67-151114 120ND22.6 22.7
cis-1,3-Dichloropropene ug/L 20 114 70-142112 220ND22.8 22.3
Dibromochloromethane ug/L 20 110 68-140109 120ND22.0 21.8
Dibromomethane ug/L 20 124 70-142122 220ND24.9 24.5
Ethylbenzene ug/L 20 117 70-145117 020ND23.4 23.4
Iodomethane ug/L v34011237-160116 340ND44.9 46.4
m&p-Xylene ug/L 40 118 70-148118 040ND47.1 47.1
Methylene Chloride ug/L 20 110 54-149111 120ND22.0 22.1
o-Xylene ug/L 20 116 70-145116 020ND23.2 23.2
Styrene ug/L 20 115 70-147115 020ND22.9 23.0
Tetrachloroethene ug/L 20 121 70-145120 120ND24.1 24.0
Tetrahydrofuran ug/L 200 100 48-16097 3200ND201 194
Toluene ug/L 20 121 65-146120 120ND24.3 24.0
trans-1,2-Dichloroethene ug/L 20 118 69-155119 120ND23.6 23.8
trans-1,3-Dichloropropene ug/L 20 114 70-142112 220ND22.9 22.4
trans-1,4-Dichloro-2-butene ug/L 20 111 39-149105 520ND22.2 21.1
Trichloroethene ug/L 20 128 70-152128 020ND25.6 25.6
Trichlorofluoromethane ug/L 20 157 60-158158 120ND31.3 31.6
Vinyl acetate ug/L 40 117 56-157114 240ND46.8 45.7
Vinyl chloride ug/L 20 116 51-178118 220ND23.1 23.5
Xylene (Total)ug/L 60 117 70-146117 060ND70.3 70.3
1,2-Dichloroethane-d4 (S)%96 70-13095
4-Bromofluorobenzene (S)%100 70-13097
Toluene-d8 (S)%98 70-13097
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 04:24 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
816395
EPA 8260D
EPA 8260D
8260D MSV Low Level Landfill
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples: 92699907002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4225648
Associated Lab Samples:92699907002
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 1.0 11/30/23 12:05
1,1,1-Trichloroethane ug/L ND 1.0 11/30/23 12:05
1,1,2,2-Tetrachloroethane ug/L ND 1.0 11/30/23 12:05
1,1,2-Trichloroethane ug/L ND 1.0 11/30/23 12:05
1,1-Dichloroethane ug/L ND 1.0 11/30/23 12:05
1,1-Dichloroethene ug/L ND 1.0 11/30/23 12:05
1,2,3-Trichloropropane ug/L ND 1.0 11/30/23 12:05
1,2-Dichlorobenzene ug/L ND 1.0 11/30/23 12:05
1,2-Dichloroethane ug/L ND 1.0 11/30/23 12:05
1,2-Dichloropropane ug/L ND 1.0 11/30/23 12:05
1,4-Dichlorobenzene ug/L ND 1.0 11/30/23 12:05
2-Butanone (MEK)ug/L ND 5.0 11/30/23 12:05
2-Hexanone ug/L ND 5.0 11/30/23 12:05
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 11/30/23 12:05
Acetone ug/L ND 25.0 11/30/23 12:05
Acrylonitrile ug/L ND 10.0 11/30/23 12:05
Benzene ug/L ND 1.0 11/30/23 12:05
Bromochloromethane ug/L ND 1.0 11/30/23 12:05
Bromodichloromethane ug/L ND 1.0 11/30/23 12:05
Bromoform ug/L ND 1.0 11/30/23 12:05
Bromomethane ug/L ND 2.0 v211/30/23 12:05
Carbon disulfide ug/L ND 2.0 11/30/23 12:05
Carbon tetrachloride ug/L ND 1.0 11/30/23 12:05
Chlorobenzene ug/L ND 1.0 11/30/23 12:05
Chloroethane ug/L ND 1.0 11/30/23 12:05
Chloroform ug/L ND 1.0 11/30/23 12:05
Chloromethane ug/L ND 1.0 11/30/23 12:05
cis-1,2-Dichloroethene ug/L ND 1.0 11/30/23 12:05
cis-1,3-Dichloropropene ug/L ND 1.0 11/30/23 12:05
Dibromochloromethane ug/L ND 1.0 11/30/23 12:05
Dibromomethane ug/L ND 1.0 11/30/23 12:05
Ethylbenzene ug/L ND 1.0 11/30/23 12:05
Iodomethane ug/L ND 20.0 v211/30/23 12:05
m&p-Xylene ug/L ND 2.0 11/30/23 12:05
Methylene Chloride ug/L ND 5.0 11/30/23 12:05
o-Xylene ug/L ND 1.0 11/30/23 12:05
Styrene ug/L ND 1.0 11/30/23 12:05
Tetrachloroethene ug/L ND 1.0 11/30/23 12:05
Tetrahydrofuran ug/L ND 10.0 11/30/23 12:05
Toluene ug/L ND 1.0 11/30/23 12:05
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 04:24 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4225648
Associated Lab Samples:92699907002
Matrix: Water
Analyzed
trans-1,2-Dichloroethene ug/L ND 1.0 11/30/23 12:05
trans-1,3-Dichloropropene ug/L ND 1.0 11/30/23 12:05
trans-1,4-Dichloro-2-butene ug/L ND 1.0 11/30/23 12:05
Trichloroethene ug/L ND 1.0 11/30/23 12:05
Trichlorofluoromethane ug/L ND 1.0 11/30/23 12:05
Vinyl acetate ug/L ND 2.0 11/30/23 12:05
Vinyl chloride ug/L ND 1.0 11/30/23 12:05
Xylene (Total)ug/L ND 1.0 11/30/23 12:05
1,2-Dichloroethane-d4 (S)%93 70-130 11/30/23 12:05
4-Bromofluorobenzene (S)%102 70-130 11/30/23 12:05
Toluene-d8 (S)%105 70-130 11/30/23 12:05
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4225649LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 20.420 102 70-130
1,1,1-Trichloroethane ug/L 20.420 102 70-130
1,1,2,2-Tetrachloroethane ug/L 19.820 99 70-130
1,1,2-Trichloroethane ug/L 19.820 99 70-130
1,1-Dichloroethane ug/L 18.620 93 70-130
1,1-Dichloroethene ug/L 19.620 98 69-131
1,2,3-Trichloropropane ug/L 19.420 97 70-130
1,2-Dichlorobenzene ug/L 20.720 103 70-130
1,2-Dichloroethane ug/L 19.020 95 70-130
1,2-Dichloropropane ug/L 19.520 97 70-130
1,4-Dichlorobenzene ug/L 20.320 102 70-130
2-Butanone (MEK)ug/L 39.540 99 67-133
2-Hexanone ug/L 44.240 110 70-133
4-Methyl-2-pentanone (MIBK)ug/L 42.340 106 70-130
Acetone ug/L 39.440 99 67-130
Acrylonitrile ug/L 93.7100 94 70-130
Benzene ug/L 20.020 100 70-130
Bromochloromethane ug/L 19.620 98 70-130
Bromodichloromethane ug/L 19.320 96 70-130
Bromoform ug/L 19.820 99 70-133
Bromomethane ug/L 16.5 v32082 41-148
Carbon disulfide ug/L 19.420 97 70-131
Carbon tetrachloride ug/L 20.620 103 70-130
Chlorobenzene ug/L 20.320 102 70-130
Chloroethane ug/L 19.720 98 41-157
Chloroform ug/L 19.020 95 70-130
Chloromethane ug/L 18.920 94 59-141
cis-1,2-Dichloroethene ug/L 18.720 93 70-130
cis-1,3-Dichloropropene ug/L 20.220 101 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 04:24 PM
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Page 18 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4225649LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromochloromethane ug/L 19.820 99 70-130
Dibromomethane ug/L 20.020 100 70-130
Ethylbenzene ug/L 20.120 100 70-130
Iodomethane ug/L 34.9 v34087 57-140
m&p-Xylene ug/L 41.040 102 70-130
Methylene Chloride ug/L 17.320 87 62-130
o-Xylene ug/L 20.120 100 70-130
Styrene ug/L 20.720 103 70-130
Tetrachloroethene ug/L 19.620 98 70-130
Tetrahydrofuran ug/L 196200 98 70-131
Toluene ug/L 19.420 97 70-130
trans-1,2-Dichloroethene ug/L 19.520 97 70-130
trans-1,3-Dichloropropene ug/L 20.220 101 70-130
trans-1,4-Dichloro-2-butene ug/L 20.320 102 57-149
Trichloroethene ug/L 20.920 104 70-130
Trichlorofluoromethane ug/L 21.820 109 57-130
Vinyl acetate ug/L 35.240 88 70-141
Vinyl chloride ug/L 17.320 87 66-140
Xylene (Total)ug/L 61.160 102 70-130
1,2-Dichloroethane-d4 (S)%96 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%97 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4225650MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699907002
4225651
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 128 70-146127 020ND25.6 25.5
1,1,1-Trichloroethane ug/L 20 113 70-150114 120ND22.6 22.8
1,1,2,2-Tetrachloroethane ug/L 20 117 66-144115 220ND23.3 23.0
1,1,2-Trichloroethane ug/L 20 118 70-142121 320ND23.5 24.1
1,1-Dichloroethane ug/L 20 101 68-150100 120ND20.2 20.1
1,1-Dichloroethene ug/L 20 81 64-16284 320ND16.3 16.8
1,2,3-Trichloropropane ug/L 20 114 66-144108 520ND22.7 21.6
1,2-Dichlorobenzene ug/L 20 120 70-142122 120ND24.0 24.4
1,2-Dichloroethane ug/L 20 108 68-145106 220ND21.7 21.2
1,2-Dichloropropane ug/L 20 112 70-144112 020ND22.5 22.4
1,4-Dichlorobenzene ug/L 20 118 70-140119 120ND23.5 23.9
2-Butanone (MEK)ug/L 40 105 57-156104 140ND41.8 41.5
2-Hexanone ug/L 40 123 62-153118 440ND49.3 47.2
4-Methyl-2-pentanone (MIBK) ug/L 40 117 65-144115 240ND46.6 45.8
Acetone ug/L 40 90 49-16290 040ND36.2 36.1
Acrylonitrile ug/L 100 97 59-15594 3100ND96.7 94.1
Benzene ug/L 20 107 68-144109 220ND21.4 21.7
Bromochloromethane ug/L 20 109 70-148108 120ND21.8 21.5
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 04:24 PM
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Page 19 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4225650MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699907002
4225651
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Bromodichloromethane ug/L 20 117 70-141121 320ND23.4 24.2
Bromoform ug/L 20 124 59-144121 220ND24.8 24.3
Bromomethane ug/L v3204723-19046 220ND9.5 9.3
Carbon disulfide ug/L 20 64 64-16065 220ND12.8 13.1
Carbon tetrachloride ug/L 20 117 70-147119 220ND23.4 23.7
Chlorobenzene ug/L 20 122 70-143122 020ND24.4 24.4
Chloroethane ug/L 20 58 55-19057 120ND11.5 11.4
Chloroform ug/L 20 110 67-148109 120ND22.0 21.8
Chloromethane ug/L M1201138-18011 220ND2.2 2.3
cis-1,2-Dichloroethene ug/L 20 104 67-151105 120ND20.9 21.0
cis-1,3-Dichloropropene ug/L 20 116 70-142120 320ND23.3 24.0
Dibromochloromethane ug/L 20 120 68-140121 120ND24.0 24.1
Dibromomethane ug/L 20 119 70-142120 120ND23.7 24.0
Ethylbenzene ug/L 20 121 70-145120 120ND24.2 24.0
Iodomethane ug/L 40 69 37-16072 440ND27.8 28.8
m&p-Xylene ug/L 40 122 70-148122 040ND48.8 49.0
Methylene Chloride ug/L 20 86 54-14989 320ND17.6 18.0
o-Xylene ug/L 20 122 70-145119 320ND24.5 23.7
Styrene ug/L 20 124 70-147124 020ND24.8 24.8
Tetrachloroethene ug/L 20 115 70-145115 020ND23.0 22.9
Tetrahydrofuran ug/L 200 95 48-16095 1200ND191 190
Toluene ug/L 20 115 65-146118 320ND23.0 23.7
trans-1,2-Dichloroethene ug/L 20 97 69-15599 220ND19.4 19.8
trans-1,3-Dichloropropene ug/L 20 122 70-142121 120ND24.5 24.1
trans-1,4-Dichloro-2-butene ug/L 20 111 39-149104 720ND22.3 20.8
Trichloroethene ug/L 20 121 70-152123 220ND24.1 24.5
Trichlorofluoromethane ug/L 20 76 60-15876 020ND15.2 15.3
Vinyl acetate ug/L 40 85 56-15783 340ND33.9 33.0
Vinyl chloride ug/L M1202251-17822 120ND4.3 4.4
Xylene (Total)ug/L 60 122 70-146121 160ND73.3 72.7
1,2-Dichloroethane-d4 (S)%99 70-13097
4-Bromofluorobenzene (S)%101 70-13099
Toluene-d8 (S)%98 70-13099
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 04:24 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815205
EPA 8260D Mod.
EPA 8260D Mod.
8260D MSV SIM
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples: 92699907002, 92699907003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4220270
Associated Lab Samples:92699907002, 92699907003
Matrix: Water
Analyzed
1,4-Dioxane (p-Dioxane)ug/L ND 2.0 11/22/23 17:58
1,2-Dichloroethane-d4 (S)%88 67-130 11/22/23 17:58
Toluene-d8 (S)%90 70-130 11/22/23 17:58
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4220271LABORATORY CONTROL SAMPLE:
LCSSpike
1,4-Dioxane (p-Dioxane)ug/L 17.120 86 70-130
1,2-Dichloroethane-d4 (S)%87 67-130
Toluene-d8 (S)%92 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4220272MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699898001
4220273
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,4-Dioxane (p-Dioxane)ug/L 20 85 55-13790 620ND16.9 17.9
1,2-Dichloroethane-d4 (S)%89 67-13090
Toluene-d8 (S)%92 70-13092
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4220274MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699907002
4220275
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,4-Dioxane (p-Dioxane)ug/L 20 96 55-13795 020ND19.1 19.1
1,2-Dichloroethane-d4 (S)%88 67-13089
Toluene-d8 (S)%91 70-13092
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 04:24 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
816023
SM 2320B-2011
SM 2320B-2011
2320B Alkalinity
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples: 92699907002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4223590
Associated Lab Samples:92699907002
Matrix: Water
Analyzed
Alkalinity, Total as CaCO3 mg/L ND 5.0 11/29/23 12:59
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4223591LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 50.950 102 80-120
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4223592LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 50.550 101 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4223593MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699898001
4223594
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 101 80-120106 35030.3 80.8 83.2
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4223595MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699907002
4223596
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 101 80-120102 05044.0 94.7 94.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 04:24 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815397
SM 2540C-2015
SM 2540C-2015
2540C Total Dissolved Solids
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples: 92699907002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4220963
Associated Lab Samples:92699907002
Matrix: Water
Analyzed
Total Dissolved Solids mg/L ND 25.0 11/27/23 10:23
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4220964LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids mg/L 256250 102 90-110
Parameter Units
Dup
Result QualifiersRPDResult
92699633003
4220965SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 1310 51380
Parameter Units
Dup
Result QualifiersRPDResult
92699658007
4220966SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 32.0 935.0
Parameter Units
Dup
Result QualifiersRPDResult
92699898001
4226112SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 73.0 H1768.0
Parameter Units
Dup
Result QualifiersRPDResult
92699907002
4226113SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 86.0 H11078.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 04:24 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
814961
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
300.0 IC Anions
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples: 92699907002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4219102
Associated Lab Samples:92699907002
Matrix: Water
Analyzed
Chloride mg/L ND 1.0 11/22/23 01:40
Sulfate mg/L ND 1.0 11/22/23 01:40
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4219103LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride mg/L 53.050 106 90-110
Sulfate mg/L 52.550 105 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4219104MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699898001
4219105
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Chloride mg/L 50 99 90-110102 3508.0 57.7 59.2
Sulfate mg/L 50 98 90-110101 350ND49.0 50.6
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4219106MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699907002
4219107
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Chloride mg/L 50 99 90-110102 3502.3 51.9 53.4
Sulfate mg/L 50 98 90-110101 3502.2 51.2 52.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 04:24 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
815297
SM 3500-Cr B-2011
SM 3500-Cr B-2011
Chromium, Hexavalent by SM3500-Cr B-2011
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples: 92699907001, 92699907002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4220712
Associated Lab Samples:92699907001, 92699907002
Matrix: Water
Analyzed
Chromium, Hexavalent mg/L ND 0.010 11/25/23 15:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4220713LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent mg/L 0.260.25 104 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4220714MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699898001
4220715
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Chromium, Hexavalent mg/L M10.25 75 90-11079 50.250.010 0.20 0.21
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4220716MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92699907002
4220717
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Chromium, Hexavalent mg/L 0.25 99 90-11096 30.250.011 0.26 0.25
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 04:24 PM
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9800 Kincey Ave. Suite 100
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[phone]
Page 25 of 32
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Analysis conducted outside the EPA method holding time.H1
The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.IK
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.v2
The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.v3
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 04:24 PM
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[phone]
Page 26 of 32
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92699907
OCSWM FALL-SOUTH MW110D/MW110S
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92699907001 815073 8151836801-MW110D EPA 3010A EPA 6010D
92699907002 815073 8151836801-MW110S EPA 3010A EPA 6010D
92699907002 815335 8153536801-MW110S EPA 7470A EPA 7470A
92699907002 8163956801-MW110S EPA 8260D
92699907003 815175TRIP BLANK EPA 8260D
92699907002 8152056801-MW110S EPA 8260D Mod.
92699907003 815205TRIP BLANK EPA 8260D Mod.
92699907002 8160236801-MW110S SM 2320B-2011
92699907002 8153976801-MW110S SM 2540C-2015
92699907002 8149616801-MW110S EPA 300.0 Rev 2.1 1993
92699907001 8152976801-MW110D SM 3500-Cr B-2011
92699907002 8152976801-MW110S SM 3500-Cr B-2011
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/04/2023 04:24 PM
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Page 27 of 32
Page 28 of 32
Page 29 of 32
Page 30 of 32
Page 31 of 32
Page 32 of 32

Groundwater Monitoring Program March, 2024 Results of Sampling and Analysis Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01
VERIFICATION (DO
NOT INCLUDED THIS
EVENT)

Groundwater Monitoring Program March, 2024 Results of Sampling and Analysis Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01

Attachment 8: Field Data

Groundwater Monitoring Program March 2024 Results of Sampling and Analysis Attachment 8 Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01
ATTACHMENT 8 FIELD DATA: SOUTH FACILITY
Groundwater samples were obtained in accordance with the groundwater monitoring requirements of the 15A North Carolina Administrative Code (NCAC) 13B and the Permit. Detailed sampling procedures are documented on a series of groundwater sampling forms (presented at the end of this ATTACHMENT). 1.1 Chronology On November 20, through November 22, 2023 (sampling event 59), TRC personnel obtained groundwater samples from groundwater monitoring wells associated with the Orange County Solid Waste Management South Facility (south side of Eubanks Road). During the subject sampling event, samples were obtained for the following chemical analyses:
• Samples were obtained from upgradient monitoring well 6801-MW04 for analysis of [1] the constituents listed in 40 CFR Part 258 Appendix I (15A NCAC 13B .1600; plus 1,4-
dioxane), [2] those constituents listed in Appendix II that have been previously and reliably detected at North landfill (mercury, naphthalene, sulfide) and [3] for those constituents required by regulations for monitoring of C&D landfills (manganese, iron, chloride, sulfate,
total dissolved solids, alkalinity).
Note. Well 6801-MW04 is associated with the monitoring programs for the closed North sanitary landfill, the closed South sanitary landfill, and the active C&D landfill.
• Additional samples were obtained from upgradient monitoring well 6801-MW110S for quality control parameters.
• Samples were obtained from upgradient monitoring well 6801-MW110S for analysis of [1] the constituents listed in Appendix I (plus 1,4-dioxane) and [2] the constituents required by regulations for monitoring of C&D landfills (manganese, iron, mercury,
chloride, sulfate, tetrahydrofuran, total dissolved solids, alkalinity).
Note. Well 6801-MW110S is associated with the monitoring programs for the closed
North sanitary landfill, the South sanitary landfill, and active C&D landfill.
• Additional samples were obtained from upgradient well 6801-MW110S for quality control
parameters.
• Samples were obtained from upgradient monitoring well 6801-MW110D for analysis of total arsenic..
• Samples obtained from six compliance wells (6801-MW101, 6801-MW102S, 6801-MW104, 6801-MW106, 6801-MW107, 6801-MW111) were analyzed for the constituents listed in Appendix I (plus 1,4-dioxane).
• Samples obtained from one compliance well (6801-MW105) were analyzed for the constituents listed in Appendix I (plus 1,4-dioxane), semi-volatile organics, PCBs and
pesticides.

Groundwater Monitoring Program March 2024 Results of Sampling and Analysis Attachment 8 Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01 Page 2
• Samples were not obtained from the leachate collection system at the South Facility due to lack of leachate. Historically, leachate is collected for analysis of the constituents listed in Appendix I, plus BOD, COD, manganese, mercury, nitrate, sulfate, and
phosphorus.
• Four trip blanks were to be analyzed for quality control purposes. TRC personnel did not sample wells 6801-MW102DR, 6801-MW103D, 6801-MW103S, or 6801-
MW112, because NCDEQ no longer requires these wells to be sampled on a regular schedule. However, if Groundwater Quality Standards are exceeded in particular wells, then the following wells will be sampled:

• 6801-MW102DR – sampled only if a Groundwater Quality Standard is exceeded in well
6801-102S
• 6801-MW103D – sampled only if a Groundwater Quality Standard is exceeded in well
6801-103S
• 6801-MW103S – sampled only if a Groundwater Quality Standard is exceeded in well
6801-MW104
• 6801-MW112 – sampled only if a Groundwater Quality Standard is exceeded in well 6801-MW105. MW-105 exceeded its Groundwater Quality Standards for Arsenic and
Cobalt in November 2023. As a result, 6801-MW112 will be sampled in May 2024. 1.2 Well Inspection Prior to sampling groundwater, TRC personnel assessed the overall condition of each groundwater
monitoring well (including the surface completion). According to documentation provided by TRC personnel, all wells were observed to be in generally good condition. 1.3 Static Water Levels Using a graduated electronic water level indicator, field personnel measured static water levels in each well prior to purging. All measurements were recorded to the nearest 0.01 foot (relative to the top of the PVC well pipe).
A history of static water elevations is presented in ATTACHMENT 3. 1.4 Purging All permitted wells were purged by TRC personnel using dedicated, submersible bladder pumps with an electric compressor that was driven by a battery and associated control unit. Wells were purged using a performance-based (“low-flow”) criteria presented in the document Guidelines for Groundwater, Soil, and Surface Water Sampling (NCDEQ - SWS; April 2008). Field purge
and sample logs provided by TRC are presented at the end of this ATTACHMENT.

Groundwater Monitoring Program March 2024 Results of Sampling and Analysis Attachment 8 Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01 Page 3
1.5 Groundwater Stability The performance-based purging method essentially involves purging groundwater from a
monitoring well at a sufficient rate so as not to significantly disturb the water column. During the purging process, several water quality parameters (pH, specific conductance, water temperature, dissolved oxygen, turbidity, ORP) are periodically measured until successive
readings are generally consistent (within 10%). Additional purging criteria are presented in the
Guidelines document discussed above. During the subject sampling event, the monitoring wells were purged until several consistent field parameter readings were recorded. These parameters were measured to help ensure that representative groundwater samples were obtained. Groundwater samples were obtained immediately after the physical parameters had stabilized.
Stability is defined in the Groundwater Monitoring Plan as a deviation of less than 10% for three consecutive readings. Readings recorded for each well are presented at the end of this ATTACHMENT.
Note. When water levels are low in a well, or when the screened portion of the aquifer is characterized by low hydraulic conductivity, the well may be purged to dryness. In such cases,
field personnel will allow time for groundwater levels to equilibrate and restart the sampling process from the point at which it was interrupted. If the well again purges to dryness, the technician will obtain samples as the well recharges. In such cases, the groundwater samples are deemed “representative” even if the usual stable readings cannot be obtained. 1.6 Well Sampling Groundwater samples were obtained using the dedicated pumps immediately after pH, specific conductance, and temperature had stabilized. Additional samples for laboratory QA/QC analyses were obtained from well 6801-MW110S, including a Matrix Spike and Matrix Spike Duplicate. .
1.7 Well Sampling Order
On November 20, through November 22, 2023 (sampling event 59), TRC personnel sampled upgradient well(s) before sampling downgradient wells. Downgradient wells were sampled in the order indicated by the times shown on the associated field records.
1.8 Preservation
At the laboratory, all sample containers were prepared with preservative by Pace if required by the method in SW-846.
All samples were placed beneath ice in coolers immediately after the samples were obtained.

Groundwater Monitoring Program March 2024 Results of Sampling and Analysis Attachment 8 Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01 Page 4
1.9 Sample Transport Immediately after the samples were obtained, they were placed beneath ice in insulated containers
for transportation to the laboratory. Samples obtained on November 20 through November 22, 2023, were hand-delivered to Pace on
the day they were collected. Upon arrival at the laboratory, all temperatures inside of the insulated containers were measured and found to lie within acceptable limits (< 4°C). All samples were placed in a refrigerator upon arrival and held at approximately 4°C until the time at which they were analyzed. Additional information concerning each monitoring well is presented at the end of this ATTACHMENT.

Groundwater Monitoring Program March, 2024 Results of Sampling and Analysis Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01

Attachment 9: Statistical Analyses

Groundwater Monitoring Program March 2024 Results of Sampling and Analysis Attachment 9 Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01
ATTACHMENT 9 STATISTICAL ANALYSES
The regulations and the Groundwater Monitoring Plan indicate that (after background sampling and analysis has been completed) each report shall also include:
• the arithmetic mean and variance of background data for each constituent
• the results of statistical analyses
The required statistical analyses are documented in a report previously submitted to the NCDEQ - Solid Waste Section (dated September 1996). Subsequent groundwater data (including data obtained during this sampling event) were compared to the facility background values contained in the September 1996, report. While preparing the report for event 25, the facility background concentration (FBAC) of total arsenic was revised using data derived from upgradient well 6801-MW110D (sampling event 1
through event 25). Facility background values (denoted as “FBAC”) are shown on a series of tables summarizing the
history of groundwater chemistry at the facility (ATTACHMENT 5 and ATTACHMENT 6). Comment. During 2007, NCDEQ promulgated Solid Waste Section Limits (SWSLs) for listed
organic and inorganic constituents, and for most general chemistry parameters. The SWSL values were established in lieu of laboratory Practical Quantitation Limits (PQLs) and were intended to function as the laboratory reporting limits.
Comment. During 2018, NCDEQ discontinued the use of SWSLs, and facilities were advised to choose EPA approved analytical methods sufficiently sensitive to quantify the presence of a pollutant at or below applicable standards.

Groundwater Monitoring Program March, 2024 Results of Sampling and Analysis Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01

Attachment 10: Quality Control

Groundwater Monitoring Program March 2024 Results of Sampling and Analysis Attachment 10 Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01
ATTACHMENT 10 QUALITY CONTROL ASSESSMENT 1.0 FIELD QUALITY ASSURANCE / QUALITY CONTROL Rigorous sampling protocols were employed during groundwater sampling to help ensure that each sample is representative of groundwater in the aquifer. Any non-dedicated equipment used to purge and sample monitoring wells was decontaminated before and after sampling each
well. In addition, trip blanks were analyzed to help validate the observed concentrations of specific
constituents. The concentration of each constituent observed in groundwater was compared to the concentration observed in each blank in accordance with the following rules:
• Regarding common organic laboratory contaminants (acetone, 2-butanone, methylene chloride) and common phthalate contaminants, if the concentration in groundwater is less than ten times (10x) the concentration in the blank, then we conclude that the constituent in
the groundwater sample may be attributed to cross-contamination.
• Regarding organic contaminants that are not commonly used in the laboratory and
inorganic contaminants in general, if the concentration in groundwater is less than five times (5x) the concentration in the blank, then we conclude that the constituent in the groundwater sample may be attributed to cross-contamination. 1.1 Deviations from the Plan All sampling techniques met the specifications set forth in the Groundwater Monitoring Plan. 1.2 Trip Blanks Trip blanks were prepared by the laboratory and transported by field personnel to each monitoring well location. Trip blanks remained in the insulated container, and the lids of the containers were never removed from the time the vehicle left the laboratory until the time field personnel delivered the samples to the laboratory.
Trip blanks were analyzed for all constituents listed in 40 CFR Part 258 Appendix II (15A NCAC 13B .1600) that are typically analyzed using EPA Method 8260D.
The laboratory did not detect any VOCs in the four trip blanks submitted. 2.0 LABORATORY QUALITY ASSURANCE / QUALITY CONTROL A limited QA/QC review was performed on the data provided by Pace Laboratories. In general, the Environmental Protection Agency's (EPA) Contract Laboratory Program (CLP) guidelines for data validation in Region III were followed; however, SW-846 control limits (latest promulgated edition) were used for QA/QC requirements.

Groundwater Monitoring Program March 2024 Results of Sampling and Analysis Attachment 10 Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01
Specifically, laboratory blanks were analyzed to help validate the observed concentrations of specific constituents. The concentration of each constituent observed in groundwater was compared to the concentration observed in each blank in accordance with the following rules:
• Regarding common organic laboratory contaminants (acetone, 2-butanone, methylene chloride) and common phthalate contaminants, if the concentration in groundwater is less than ten times (10x) the concentration in the blank, then we conclude that the constituent in the groundwater sample may be attributed to cross-contamination.
• Regarding organic contaminants that are not commonly used in the laboratory and inorganic contaminants in general, if the concentration in groundwater is less than five times (5x) the concentration in the blank, then we conclude that the constituent in the groundwater sample may be attributed to cross-contamination. 2.1 EPA Method 8260D (volatile constituents)
As part of the QA/QC review, the following were examined:
• technical holding times and preservation requirements
• blank analysis
• transcription/confirmation errors After reviewing the quality control data provided by Pace Laboratories, the reviewer determined
that the dataset met all requirements of the criteria listed above, as specified by SW-846 for the referenced method. 2.2 EPA Method 6010D (ICP - metals) As part of the QA/QC review, the following were examined:

• technical holding times and preservation requirements
• blank analysis
• transcription/confirmation errors
After reviewing the quality control data provided by Pace Laboratories, the reviewer determined that the dataset met all requirements of the criteria listed above, as specified by SW-846 for the referenced method. 2.3 EPA Method 6020B (ICP - metals) As part of the QA/QC review, the following were examined:
• technical holding times and preservation requirements
• blank analysis
• transcription/confirmation errors

Groundwater Monitoring Program March 2024 Results of Sampling and Analysis Attachment 10 Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01
After reviewing the quality control data provided by Pace Laboratories, the reviewer determined that the dataset met all requirements of the criteria listed above, as specified by SW-846 for the referenced method.

Groundwater Monitoring Program March 2024 Results of Sampling and Analysis Attachment 10 Sampling Event 59: 11.20.23 to 11.22.23 OCSWM South Facility, Permit No. 68-01
[QUALITY CONTROL DOCUMENTATION, AS PROVIDED BY THE LABORATORY, IS PRESENTED IN ATTACHMENT 7, ALONG WITH THE ASSOCIATED CERTIFICATE-OF-
ANALYSIS]

OCSWM South Facility, Permit No. 68-01

Attachment 11: Correspondence
Groundwater Monitoring Program March, 2024 Results of Sampling and Analysis Sampling Event 59: 11.20.23 to 11.22.23

OCSWM South Facility, Permit No. 68-01

[RESERVED]

Groundwater Monitoring Program March, 2024
Results of Sampling and Analysis
Sampling Event 59: 11.20.23 to 11.22.23