1203_Burke_JohnsRiver_MSWLF_CDLF_Nov23GW_FID1831382_20240304

�ENR USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #•
"Nc DENR Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each Individually monitored unit.
Please type or print legibly.
• Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
LaBella Associates
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: G. Van Ness Burbach, PhD., PG Phone: [phone]
E-mail: vburbach(a)labellapc.com
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Johns River 2500 Marsh Trail 12-03 .1600 November 6-8, 2023
C&D-over-MSW Landfill Morganton, NC
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring ❑ Detection Monitoring X❑ Assessment Monitoring ❑X Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells
Groundwater monitoring data from private water supply wells
Leachate monitoring data
Surface water monitoring data ❑
Methane gas monitoring data
Corrective action data (specify) MNA & LFG Performance/Sentinel
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
G. Van Ness Burbach, Ph.D., PG Sr. Technical Consultant [phone]
Fac�iRe s%t Name (Print) Title (Area Code) Telephone Number
AVJ/ / �'/ �..�_ // r 'I % n /nt1 i Affix N(`i Te3Af#gjpfessional Geologist Seal
12 D Oak Branch Dr., Ste. 101 Greensboro, NC 27407
Facility Representative Address
C-609
NC PE Firm License Number (if applicable effective May 1, 2009)
o•`�Q•� ROB'••.
JCEN,
SEAL
1349
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9
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Revised 6/2009

LaBeRa
Powered by partnership.
February 28, 2024
Jaclynne Drummond
Compliance Hydrogeologist
NC Department of Environmental Quality
Division of Waste Management - Solid Waste Section
2090 US Highway 70, Swannanoa, NC 28778
Via email: [e-mail]
RE: Burke County, Johns River Landfill
Permit Number 12-03
Closed C&D-over-MSW Landfill
November 2023 Semiannual Water Quality Monitoring Report
Project No. 2233479/03
Dear Ms. Drummond:
On behalf of Burke County, we are submitting the November 2023 Semiannual Water Quality
Monitoring Report in electronic format, as well as a copy of the Environmental Monitoring Form and
the laboratory EDD's for the Closed C&D-over-MSW Landfill at the Johns River Waste Management
Facility, Permit # 12-03. This report completes the second semiannual compliance monitoring event
of 2023 as required by the North Carolina Division of Waste Management, Solid Waste Section. If we
can provide any additional information, please call me at [phone].
Respectfully submitted,
LaBella Associates
Van Burbach, Ph.D., P.G.
Sr. Technical Geologist
Enclosure
cc: Mark Delehant, Burke County
12-D Oak Branch Drive I Greensboro, NC 27407 I p [phone]
www.LabeLLapc.com

Prepared For:
BOARD OF COMMISSIONERS
COUNTY OF BURKE
P.O. BOX 1486
MORGANTON, NORTH CAROLINA 28680
4 �raxE
e
Submitted by:
LaBella Associates
12-D Oak Branch Drive
Greensboro, NC 27407
[phone]
NC License No. C-609
LaBeRa
Powered by partnership.
NOVEMBER 2023 SEMIANNUAL WATER QUALITY
MONITORING REPORT
JOHNS RIVER WASTE MANAGEMENT FACILITY
C&D-OVER-MSW LANDFILL
Permit No. 12-03
FEBRUARY 2024
PROJECT NO. 2233479/03

November 2023 Semiannual Water Quality Monitoring Report
Johns River Waste Management Facility - Permit No. 12-03
C&D-over-MSW Landfill
Burke County, North Carolina
TABLE OF CONTENTS
ACRONYMS
1.0
INTRODUCTION.............................................................................................................................1
1.1
Site Information...................................................................................................................................1
1.2
Site Geology.........................................................................................................................................1
1.3
Regulatory Status.................................................................................................................................2
1.4
Groundwater Monitoring History.........................................................................................................2
2.0
FACILITY MONITORING PROGRAM...............................................................................................3
2.1
Groundwater Monitoring Program......................................................................................................3
2.2
Background -Based Groundwater Protection Standards...................................................................5
2.3
Surface Water Monitoring Program....................................................................................................5
3.0
HYDROGEOLOGICAL CONDITIONS ...............................................................................................6
4.0
NOVEMBER 2023 SEMIANNUAL SAMPLING EVENT...................................................................6
4.1
Field Work.............................................................................................................................................6
4.1.1
Groundwater Sampling...................................................................................................................6
4.1.2 Surface Water Sampling.................................................................................................................7
4.2
Laboratory Analysis and Quality Control.............................................................................................8
5.0
ANALYTICAL RESULTS AND STATISTICAL ANALYSIS....................................................................8
5.1
Inorganic Constituents in Groundwater..............................................................................................8
5.2
Organic Constituents in Groundwater................................................................................................9
5.3
Statistical Analyses..............................................................................................................................9
5.4
Analytical Results for Surface Water..................................................................................................9
6.0
EVALUATION OF MONITORED NATURAL ATTENUATION (MNA)................................................
10
6.1
MNA Parameters and Biodegradation Screening Matrix...............................................................
10
6.2
Biochlor Modeling and Mass -Balance Assessment........................................................................
10
6.3
Trend Analysis and Plume Stability..................................................................................................
11
7.0
CONCLUSIONS...........................................................................................................................12
8.0 REFERENCES.............................................................................................................................12
November 2023 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County, Johns River C&D-over-MSW Landfill, Permit No. 12-03 February 2024
i

TABLE OF CONTENTS (CONTINUED)
Tables:
Table 1
Groundwater Elevations (November 2023)
Table 2
Hydraulic Gradients & Linear Velocities (November 2023)
Table 3
Field Parameters (November 2023)
Table 4
Detected Constituents (November 2023)
Table 5
Exceedances of Standards (November 2023)
Table 6
MNA Parameters (November 2023)
Table 7
Biodegradation Screening Matrix (November 2023)
Charts:
Chart 1
Benzene Concentrations vs. Time
Chart 2
1,4-Dichlorobenzene Concentrations vs. Time
Chart 3
1,1-Dichloroethane Concentrations vs. Time
Chart 4
1,2-Dichloroethane Concentrations vs. Time
Chart 5
Tetrachloroethylene (PCE) Concentrations vs. Time
Chart 6
Trichloroethylene (TCE) Concentrations vs. Time
Chart 7
Vinyl Chloride Concentrations vs. Time
Chart 8
Methylene Chloride Concentrations vs. Time
Chart 9
1,4-Dioxane Concentrations vs. Time
Chart 10
Cobalt Concentrations vs. Time
Chart 11
Thallium Concentrations vs. Time
Chart 12
Mercury Concentrations vs. Time
Chart 13
Iron Concentrations vs. Time
Chart 14
Manganese Concentrations vs. Time
Figure:
Figure 1
Site Location Map
Drawing:
Drawing 1
Groundwater Potentiometric Surface Map (November 2023)
Appendices:
Appendix A
Well Construction Data
Appendix B
Laboratory Analytical Reports and Field Logs
Appendix C Historical Data Tables
Table C-1 Historical Groundwater Elevations
Table C-2 Historical Detected Groundwater Constituents
Table C-3 Historical Detected Constituents in Performance & Sentinel Wells
Table C-4 Historical Detected Surface Water Constituents
Table C-5 Historical MNA Parameters
Appendix D Biochlor Modeling Input & Output
November 2023 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County, Johns River C&D-over-MSW Landfill, Permit No. 12-03 February 2024

ACRONYMS
ACM Assessment of Corrective Measures (Report)
AMSL Above Mean Sea Level
AOC Area of Concern
BGS Below Ground Surface
C&D Construction and Demolition Waste
CAP Corrective Action Plan (Report)
CAER Corrective Action Evaluation Report (Report)
CAMP Corrective Action Monitoring Plan (Report)
CAS Chemical Abstracts Service
CFR Code of Federal Regulations
COC Contaminant of Concern (for corrective action)
COC Chain of Custody (for sampling and lab reports)
DL Detection Limit (for laboratory data)
DO Dissolved Oxygen
EPA United States Environmental Protection Agency (or USEPA)
GEU Gas Extraction Unit
GPS Groundwater Protection Standards per 15A NCAC 13B.1634.(g)
ISTV Instream Target Values
LFG Landfill Gas
MCL Maximum Contaminant Level (USEPA)
MDL Method Detection Limit (same as DL)
MNA Monitored Natural Attenuation
MRL Method Reporting Limit (same as RL or QL)
MSW Municipal Solid Waste
NC2B North Carolina Surface Water Standards found in 15A NCAC 2B
NC21L North Carolina Groundwater Standards found in 15A NCAC 2L
NCAC North Carolina Administrative Code
NCDENR North Carolina Department of Environment and Natural Resources (now the NCDEQ)
NCDEQ North Carolina Department of Environmental Quality (formerly the NCDENR)
NCGS North Carolina Geological Survey
November 2023 Water Quality Monitoring Report LaBella Associates
Burke County, Johns River C&D-over-MSW Landfill, Permit No. 12-03 February 2024
iii

NCSWMR North Carolina Solid Waste Management Regulations (15A NCAC 1313)
ND
Not Detected (for laboratory data) (same as MDL)
NES
Nature and Extent Study (Report)
NRWQC
Nationally Recommended Water Quality Criteria (USEPA)
QL
Quantitation Limit (for laboratory data) (same as RL or MRL)
RL
Reporting Limit (for laboratory data) (same as QL or MRL)
RQD
Rock Quality Designation
SSI
Statistically Significant Increase (above background concentrations)
SWS
Solid Waste Section (of NCDEQ-Division of Waste Management)
TOC
Top of Casing (Well)
USCS
Unified Soil Classification System
USEPA
United States Environmental Protection Agency (or EPA)
USGS
United States Geological Survey
VOC
Volatile Organic Compound
WQAR
Water Quality Assessment Report
WQMP
Water Quality Monitoring Plan
WQMR
Water Quality Monitoring Report
November 2023 Water Quality Monitoring Report LaBella Associates
Burke County, Johns River C&D-over-MSW Landfill, Permit No. 12-03 February 2024
iv

1.0 INTRODUCTION
1.1 Site Information
The Johns River Waste Management Facility (JRWMF) is located in the north -central portion of Burke
County, north of Morganton, North Carolina. The 318-acre landfill property is bordered by Lower Creek
to the north and east, and the Catawba River to the south. The Catawba River forms Lake Rhodhiss
along the southeastern property line (Figure 1). Lake Rhodhiss is a long, narrow lake formed by the
Rhodhiss Hydroelectric Dam located approximately 12 miles downstream of the landfill. The Johns
River flows into the Catawba River near the southwest corner of the landfill property. A site plan
showing all the features of the facility is provided in Drawing 1.
The site has rolling topography with elevations ranging from 975 feet to 1,150 feet above mean sea
level (AMSL). The central portion is generally gently sloping and contains the higher elevations;
relatively steep slopes and significant drainage features are located around the perimeter. The 100-
year flood boundary extends onto the landfill property. The adjacent property to the west of the JRWMF
consists of undeveloped, heavily wooded land. Properties within 2,000 feet of the landfill boundary
are covered by surface water or are heavily wooded.
The unlined waste disposal unit consists of 28 acres in the southwest corner of the landfill property.
The municipal solid waste (MSW) landfill began operation in April 1988 under Permit # 1203-MSWLF-
1987, but was closed to comply with North Carolina Administrative Code Title 15A Chapter 13 Sub -
Chapter .1627 (15A NCAC 13B .1627) (c)(10)(A) rule, a regulation governing MSW landfill units that
were not designed with a base liner and leachate collection system. Burke County operated a
permitted Construction and Demolition (C&D) disposal area on top of the closed MSW landfill between
1998 and 2015 under Permit # 1203-CDLF-1998, and the C&D landfill was closed in 2016.
The County also operates an active C&D landfill under Permit # 1203-CDLF-2014 northeast of the
C&D-over-MSW landfill. Phase 1A of the C&D expansion was constructed in 2014, Phase 2A of the
C&D expansion was constructed and began operation in 2018, and Phase 4 construction has been
completed and a permit to operate was issued in December 2023. Results of groundwater monitoring
for C&D Expansion Landfill will be presented in a separate report.
An MSW transfer facility is located on the eastern half of the property and is operated by the County
under Permit # 1205T-TRANSFER-1998.
1.2 Site Geology
The JRWMF is located in the Inner Piedmont Belt of the Piedmont Physiographic Province, and in close
proximity to the Brevard Shear Zone. It is underlain by highly metamorphosed rocks including gneiss
and schist, as well as calc-silicate rocks, felsic rocks, and metavolcanic rocks. The dominant rock type
at the facility is biotite-muscovite schist, as seen in outcrops, boulders, and rock cores on site. The
structures within limited outcrops indicate that these rocks are complexly folded, with attitudes that
vary from vertical to horizontal. The site regolith is typical of the Inner Piedmont Belt and consists
mostly of silty sand, clayey sand, and sandy silt. The regolith is up to 100 feet thick and varies in
thickness with topography.
An abundance of rounded gravel, cobble, and boulder -sized alluvial deposits are exposed along the
banks of the Catawba River, which borders the site. The greatest accumulation of these deposits is
along the southwestern site boundary. These river deposits are 40 feet or more above the current
river elevation and have been described as ancient river terrace deposits.
November 2023 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County, Johns River C&D-over-MSW Landfill, Permit No. 12-03 February 2024
1

1.3 Regulatory Status
The following report of groundwater monitoring data from the JRWMF C&D-over-MSW landfill has been
prepared in accordance with the North Carolina Solid Waste Management Rules (NCSWMR) 15A NCAC
13B §.1632 (Groundwater Sampling & Analysis Requirements), §.1633 (Detection Monitoring
Program), and §.1634 (Assessment Monitoring Program). The facility has operated under these
programs as regulated by the North Carolina Department of Environmental Quality (NCDEQ), formerly
the North Carolina Department of Environment and Natural Resources (NCDENR).
The C&D over MSW landfill has been in the Assessment Monitoring Program since August 1995. In
January 2000, Burke County submitted a Water Quality Assessment Report (WQAR), for the landfill to
the NCDEQ. The WQAR determined that the constituents -of -concern (COCs) at the landfill were the
volatile organic compounds (VOCs) benzene, 1,4-dichlorobenzene, methylene chloride,
tetrachloroethylene, and trichloroethylene.
The JRWMF entered the Corrective Action Program following correspondence received from the NCDEQ
Solid Waste Section (SWS) dated August 18, 2003. An Assessment of Corrective Measures (ACM) was
submitted to NCDEQ in February 2005. A Corrective Action Plan (CAP) was submitted to NCDEQ in
June 2008 and revised in November 2008. The CAP was approved by NCDEQ in a letter dated January
29, 2009. An addendum to the facility's CAP was submitted to the NCDEQ in August 2013, adding
control of landfill gas as a remedy for groundwater impacts on the northeastern side of the landfill
between the old landfill and the new C&D expansion area. A revised Addendum to the CAP was
submitted in January 2018 to add an active gas extraction unit (GEU) to the remedy, and the revised
Addendum was approved by the NCDEQ on February 7, 2018. The GEU was installed and began
operation in July 2019.
1.4 Groundwater Monitoring History
• April 1988: Facility began operations as a MSW landfill.
• August 1995: Assessment Monitoring began.
• January 1998: Facility closed as a MSW landfill but began operating a C&D landfill on top of
the former MSW landfill.
• January 2000: WQAR, (JOYCE, 2000).
• October 2004: WQAR Update, (JOYCE, 2004).
• February 2005: ACM, (JOYCE, 2005a) and Quantitative Risk Assessment, (JOYCE, 2005b).
• May 2006: Public Meeting for ACM.
• June 2008: CAP submitted to NCDEQ-SWS.
• November 2008: CAP Revised per comments from NCDEQ-SWS & resubmitted.
• January 2009: CAP Approved by NCDEQ-SWS.
• June 2009: First Monitored Natural Attenuation (MNA) baseline sampling event.
• May 2011: First Corrective Action Evaluation Report (CAER).
• April 2012: Alternate Source Demonstration (ASD) for iron and manganese approved by
NCDEQ.
• August 2013: Addendum to the CAP to add control of landfill gas as a remedy.
• April 2016: Second CAER.
• December 2017: Cobalt added as a constituent of concern.
• January 2018: Second Addendum to the CAP to add an active GEU to the remedy.
• December 2018: Thallium and 1,4-dioxane added as COCs.
• July 2019: GEU installed and started.
November 2023 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County, Johns River C&D-over-MSW Landfill, Permit No. 12-03 February 2024
2

June 3, 2020: ASD for metals submitted to NCDEQ and approved on June 9, 2020.
Established background -based standards for cobalt, iron, manganese, and vanadium.
March 2021: Third CAER. Iron and manganese added to COC list, alpha-BHC and beta-BHC
removed from COC list.
• 2022: Mercury added to COC list after November 2021 sampling event.
2.0 FACILITY MONITORING PROGRAM
2.1 Groundwater Monitoring Program
The monitoring program consists of two sub -programs, the compliance monitoring program, which
includes Detection and Assessment Monitoring, and the corrective action monitoring program.
Groundwater monitoring at the C&D-over-MSW landfill under the compliance monitoring program is
performed in accordance with NCSWMR §.1634, the site's transition plan (JOYCE, April 1994), the
site's Water Quality Monitoring Plan (WQMP) (JOYCE, 2017), and corrective action monitoring program
under the site's CAP (JOYCE, 2008, 2013, 2018). Groundwater samples are collected semiannually
and analyzed for constituents in accordance with the appropriate monitoring programs. Construction
data for the facility's monitoring wells are presented in Appendix A.
The current compliance groundwater monitoring network at the facility consists of one upgradient well
(MW-21), and five downgradient wells (MW-10, MW-11, MW-12 MW-13, and MW-16S). These wells
are currently sampled under Assessment Monitoring. Monitoring wells MW-18, MW-19, MW-36, and
MW-38 are sampled under the Corrective Action monitoring program. The following is a summary of
the monitoring wells that are currently sampled as part of the monitoring network for the C&D-over-
MSW landfill:
Total
Lithology of
Well ID
Date
Classification
Monitoring
Depth of
Screened
Constituent
Installed
Program
List
Well (feet)
Interval
MW-10
9-2-94
Compliance
Assessment
23.0
Saprolite
Compliance
Compliance/
Assessment/
Compliance/
MW-11
9-2-94
Corrective
43.0
Saprolite
Performance
MNA
Action
Compliance/
Assessment/
Compliance/
MW-12
9-1-94
Corrective
51.5
Bedrock
Performance
MNA*
Action
MW-13
8-31-94
Compliance
Assessment
58.0
Bedrock
Compliance
Compliance/
Assessment/
Compliance/
MW-16S
3-8-99
Corrective
20.0
Saprolite
Performance
MNA
Action
Assessment/
Compliance/
MW-21
5-18-95
Background
Corrective
45.0
Saprolite
Action
MNA*
Corrective
MW-18
4-7-09
Sentinel**
12.0
Alluvial Soil
COCs, MNA*
Action
MW-19
4-7-09
Sentinel**
Corrective
13.0
Alluvial Soil
COCs, MNA*
Action
Performance
Corrective
MW 36
5 8 11
43.0
Bedrock
COCs, LFG
***
Action
Performance
Corrective
MW 38
5 9-11
71.0
Bedrock
COCs, LFG
***
Action
November 2023 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County, Johns River C&D-over-MSW Landfill, Permit No. 12-03 February 2024
3

Notes: Compliance Parameters: 40 CFR Part 258, Appendix I, incorporated by reference into the
NCSWMR (NC Appendix 1) and/or 40 CFR Part 258, Appendix II (NC Appendix 11) organics and
inorganics plus C&D parameters, as required for routine assessment or detection monitoring.
COCs = Constituents of Concern.
MINA = MINA Parameters: Temperature, pH, specific conductance, oxidation-reduction
potential, dissolved oxygen, nitrate, sulfate, chloride, dissolved hydrogen, sulfide, alkalinity,
total organic carbon (TOC), methane, ethane, ethene, volatile fatty acids, carbon dioxide,
ferrous iron, and turbidity.
LFG = Landfill Gas Indicators: Dissolved methane (CH4) and dissolved carbon dioxide (CO2).
* After the baseline period, the NCDEQ approved alternate frequencies for CO2, sulfide,
volatile fatty acids, ethane, and ethene. These parameters will be monitored during both
semiannual events every third year.
** After the baseline period, sampling frequency for sentinel wells was changed to annual
and is done during the fall sampling event.
*** Performance wells (MW-36 & MW-38) for the control of landfill gas remedy were added
in the August 2013 CAP Addendum. Monitoring well MW-38 is also a compliance well for
Phase 1A.
The wells in Assessment Monitoring, which are part of the compliance program (MW-10, MW-11, MW-
12, MW-13, MW-16S, and MW-21), are analyzed for the North Carolina (NC) Appendix I list of
constituents plus additional detected NC Appendix II constituents and additional required C&D
parameters during the first semiannual event, and for all constituents listed in NC Appendix 11 plus
additional required C&D parameters during the second semiannual monitoring event. The current list
of detected Appendix II constituents includes cyanide, tin, mercury, and dichlorodifluoromethane.
Monitoring wells MW-11, MW-12, MW-16S, and MW-21 are also sampled for MNA parameters during
each sampling event. All monitoring wells are also sampled for 1,4-dioxane per the NCDEQ
memorandum dated May 29, 2018.
In accordance with the CAP for the facility, MINA baseline sampling was initiated with the June 2009
sampling event and continued through the November 2010 sampling event. The baseline data were
evaluated in a CAER dated May 2011, and reevaluated in the CAER dated March 2021. In a letter
dated March 2021, the NCDEQ agreed to a reduced frequency for monitoring carbon dioxide, sulfide,
volatile fatty acids, ethane, and ethene. These parameters are now monitored during two semiannual
sampling events every fifth year. They will be monitored next during the spring and fall 2025
semiannual events.
The Corrective Action Monitoring Plan (CAMP) requires samples from sentinel wells MW-18 and MW-19
to be analyzed for the facility's COCs. Samples from MW-36 and MW-38 are analyzed for the VOCs on
the COC list.
The current COC list includes the following constituents:
• Benzene;
• 1,4-Dichlorobenzene;
• Tetrachloroethene (PCE);
• Trichloroethene (TCE);
November 2023 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County, Johns River C&D-over-MSW Landfill, Permit No. 12-03 February 2024
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• 1,1-Dichloroethane;
• 1,2-Dichloroethane;
• Vinyl chloride;
• Methylene chloride;
• 1,4-dioxane;
• Cobalt;
• Thallium;
• Mercury;
• Iron; and
• Manganese.
After the 2011 CAER, the NCDEQ agreed that sentinel wells MW-18 and MW-19 need only be sampled
annually for the COC list plus required MINA parameters. They are monitored during the second
semiannual event each year.
An addendum to the facility's CAP was submitted to the NCDEQ in August 2013, adding control of
landfill gas as a remedy for groundwater impacts on the northeastern side of the landfill between the
old landfill and the new C&D expansion area. In accordance with the CAP addendum, piezometers PZ-
36 and PZ-38 were converted to permanent performance wells MW-36 and MW-38 under the
Corrective Action Monitoring Program. Please note that MW-38 is also a compliance well for the C&D
Expansion Landfill.
2.2 Background -Based Groundwater Protection Standards
An ASD for metals (La Bella, 2020) was submitted on June 3, 2020, and was approved by the NCDEQ
on June 9, 2020. The ASD established statistical background -based standards for cobalt [11.3
micrograms per liter (pg/L)], iron (14,182 pg/L), manganese (535 pg/L), and vanadium (45.2 pg/L).
The ASD also calculated a statistical background value for thallium; however, it was below the current
North Carolina 15A NCAC 2L .0202 Groundwater Standard (NC2L). As a result, the NC2L standard for
thallium is used for groundwater data comparison. No additional statistical analyses have been
performed for this report.
2.3 Surface Water Monitoring Program
The current surface water monitoring points are SMP-5, SMP-6, and SMP-7. Surface water monitoring
point SMP-5 (located at the southwestern property line) and SMP-6 (located at the southeastern
property line) are both located downstream from the existing sediment basins. Surface water
monitoring point SMP-7 is located downstream from the new Phase 1A expansion. Surface water
samples are analyzed for the NC Appendix I list of constituents, detected NC Appendix II constituents
(cyanide, tin, mercury, and dichlorodifluoromethane), and 1,4-dioxane during both semiannual events.
Surface Point
Classification
Monitoring Program
Location
SMP-5
Compliance
Surface Water
Creek on west side of landfill,
downstream of sediment basin.
Creek on east side of landfill,
SMP-6
Compliance
Surface Water
downstream of sediment basin.
Creek southeast of Phase 1A and
SMP-7
Compliance
Surface Water
east of sediment basin SB-2A.
Downstream of PZ-12.
November 2023 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County, Johns River C&D-over-MSW Landfill, Permit No. 12-03 February 2024
5

3.0 HYDROGEOLOGICAL CONDITIONS
Based on drilling information, the water table appears to occur within regolith across the site. The
regolith consists of residual soils and saprolite. Beneath the regolith lies variably fractured and
weathered metamorphic bedrock. Water in the bedrock is transmitted primarily through fractures;
however, even in the saprolite there is often enough relict structure for former fracture zones to
influence groundwater flow. Along the low-lying areas of the Catawba River and its tributaries, the
water table occurs within surficial alluvial deposits overlyingthe residual soils and weathered bedrock.
Static groundwater depth was measured in the monitoring wells at the site prior to sampling. The
November 2023 groundwater elevations are provided in Table 1 and the historical groundwater
elevations are provided in Appendix 2, Table A2-1. The elevations were calculated relative to the
surveyed measuring point (top of casing) for each monitoring well. A groundwater potentiometric
surface map, developed from the static water level data is presented as Drawing 1. The potentiometric
surface map shows groundwater flow primarily to the south. Groundwater discharges into creeks
located to the east and west of the landfill and to the Catawba River to the south.
Horizontal groundwater gradients along representative flow paths were estimated from the November
2023 groundwater contours as shown on Drawing 1 and are summarized on Table 2. The horizontal
gradient across the site was 0.0520. This is consistent with previous estimates.
Linear groundwater flow velocities for wells screened in saprolite were computed using the modified
Darcy equation:
where:
V = K►/ne,
V = average linear velocity (feet per day),
K = hydraulic conductivity (feet per day),
i = horizontal hydraulic gradient, and
ne = effective porosity.
The average of hydraulic conductivities from slug tests previously conducted at the facility (K = 3.28
feet/day) was used in these calculations, along with an effective porosity of ne = 0.40 (40%) based on
laboratory porosities for soil samples collected from the facility. The estimated linear groundwater flow
velocity under the facility was 156 feet per year (Table 2). The modified Darcy equation makes the
simplified assumptions of a homogeneous, isotropic, porous aquifer. This equation may yield
inaccurate velocities when applied to heterogeneous and/or anisotropic conditions such as may exist
at the site. The regolith and fractured bedrock common in the Piedmont terrane are characteristically
heterogeneous and often exhibit some anisotropy.
4.0 NOVEMBER 2023 SEMIANNUAL SAMPLING EVENT
4.1 Field Work
4.1.1 Groundwater Sampling
On November 6-8, 2023, personnel from LaBella Associates (LaBella) visited the JRWMF to purge and
collect groundwater samples from monitoring wells MW-10, MW-11, MW-12, MW-13, MW-16S,
MW-18, MW-19, MW-21, MW-36, and MW-38.
November 2023 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County, Johns River C&D-over-MSW Landfill, Permit No. 12-03 February 2024
6

Depth -to -water measurements were obtained to the nearest 0.01 foot using an electronic water level
indicator for all monitoring wells in the compliance network prior to purging. The November 2023
groundwater elevations data are summarized in Table 1, and historical groundwater elevation data is
presented in Appendix C, Table C-1.
During the November 2023 sampling event, monitoring wells were purged and sampled with
disposable bailers or a 12-volt submersible pump using the multiple volume purge method, or a Mega
Monsoon pump using low -flow techniques.
For the multiple purge method, a minimum of three well volumes were removed before considering
the well purged unless the well went dry. Measurements of temperature, pH, specific conductivity,
dissolved oxygen, oxidation-reduction potential, and turbidity were recorded in the site logbook as well
as on field data logs prior to purging, after each purge volume, and before sampling. Field sampling
logs for the November 2023 event are provided in Appendix 1. During low flow purging, the well was
pumped without interruption until the field parameters were stable and low turbidity was achieved
(where possible).
Measurements of field parameters were recorded in the site logbook as well as on field data logs prior
to purging, after each purge volume, and before sampling. Pumps, water level meters, and other
equipment were decontaminated between wells by washing with a solution of Alconox and water,
rinsing with distilled water, and air -drying. Field data logs for the November 2023 event are provided
in Appendix B and field parameter data are presented in Table 3.
Laboratory -supplied containers were prepared and labeled (either by the laboratory or in the field, as
indicated) with the following information:
• Monitoring well number (completed by field personnel),
• Date and time of sample collection (completed by field personnel),
• Initials of sampling personnel (completed by field personnel),
• Project name and number (completed by the laboratory),
• Chemical preservative (completed by the laboratory); and
• Requested chemical analysis (completed by the laboratory).
Groundwater samples from each monitoring well were dispensed directly from the disposable bailers
or pump discharge tubing into the provided laboratory containers within 24 hours of the final purge
volume. Immediately after collection, the samples were placed in a laboratory -provided cooler and
chilled with ice.
4.1.2 Surface Water Sampling
Surface monitoring point was SMP-6 sampled during the November 2023 sampling event. Monitoring
points SMP-5 and SMP-7 were dry and were not sampled.
Surface water samples were collected by lowering a clean, unpreserved sample container into the
stream flow and dispensing the water into the laboratory -prepared sample containers. At the time of
sampling, surface water was also measured for temperature, pH, specific conductivity, dissolved
oxygen, oxidation-reduction potential, and turbidity and recorded in the site logbook. Immediately after
sample collection, the samples were placed in a laboratory -provided cooler and chilled on ice. Field
data logs are provided in Appendix B and field parameter data are summarized in Table 3.
November 2023 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County, Johns River C&D-over-MSW Landfill, Permit No. 12-03 February 2024
7

4.2 Laboratory Analysis and Quality Control
The November 2023 groundwater and surface water samples were submitted to Pace Analytical
Services, Inc. (Pace) of Huntersville, North Carolina under chain -of -custody control for analysis. The
groundwater samples from the wells in assessment monitoring were analyzed for NC Appendix I
constituents, NC Appendix 11 constituents, C&D parameters, tetrahydrofuran (THF), and 1,4-dioxane.
Samples from corrective action wells were analyzed for the COC list plus MNA or landfill gas
parameters as described in Section 2.1.
Surface water samples were analyzed for NC Appendix I metals, 1,4-dioxane, and hardness. LaBella
requested Level 11 data reports for the final laboratory reports. The samples were received by the
laboratory in good condition, properly preserved, and within required hold times.
In addition to samples collected for monitoring at the JRWMF, a field blank was collected by LaBella
personnel as part of the November 2023 sampling event. Also, a trip blank prepared by the laboratory
accompanied the volatile sampling containers from and to the laboratory. The field blank was analyzed
for the same parameters as the compliance wells in Assessment Monitoring and the trip blank was
analyzed for Appendix II VOCs, THF, and 1,4-dioxane.
Upon receipt of the laboratory data package, LaBella personnel reviewed the data package for quality
assurance/quality control (QA/QC) purposes. If any QA/QC issues were found, the laboratory would
be contacted to resolve the issue, and a resampling event may be scheduled, if needed. The laboratory
analytical packages can be found in Appendix B of this report. The data package was reviewed for the
following:
• General typographical errors;
• Correct analyses performed and within method -specified hold times;
• Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate, and
Laboratory Control Samples;
• Blank -qualified data (B-flags);
• Detections in groundwater exceeding the NC2L, or approved background -based standards;
• Detections in surface water samples that exceeded North Carolina 15A NCAC 2B Surface
Water Standards (NC2B), NC In -stream Target Values (ISTV), or EPA National Recommended
Water Quality Criteria (NRWQC); and
• Detections that are above historical levels.
5.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSIS
The complete laboratory reports and chains -of -custody for the November 2023 monitoring event for
the C&D over MSWLF are included in Appendix 1. The constituents detected above the Method
Detection Limit (MDL) in the sampled monitoring wells and surface monitoring points are presented in
Table 4. Please note that estimated concentrations below the Method Reporting Limit (MRL) are not
considered exceedances of the standard, even if the estimated value is higher than the standard.
The constituents in exceedance of their respective standards are presented in Table 5. Field
parameters for the November 2023 monitoring event are summarized in Table 3.
5.1 Inorganic Constituents in Groundwater
Four inorganic constituents were detected above their respective standards in the monitoring wells
as summarized in Table 5. These exceedances are as follows:
November 2023 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County, Johns River C&D-over-MSW Landfill, Permit No. 12-03 February 2024
8

• Cobalt (MW-10, MW-11, MW-12, MW-13, MW-16S, MW-19, MW-36, and MW-38)
• Iron (MW-21, MW-10, MW-11, MW-12, MW-13, MW-16S, MW-18, MW-19, MW-36,
and MW-38)
• Manganese (MW-10, MW-11, MW-12, MW-13, MW-16S, MW-18, MW-19, MW-36,
and MW-38)
• Mercury (MW-10)
The inorganic detections and exceedances are generally consistent with historical data. Historical
data for groundwater constituents in compliance wells are summarized in Appendix C, Table C-2, and
historical data for constituents in performance and sentinel wells are summarized in Appendix C, Table
C-3.
5.2 Organic Constituents in Groundwater
Eight organic constituents exceeded their respective NC2L standards as follows (Table 5):
• 1,1-Dichloroethane (MW-12, MW-13, and MW-16S)
• 1,4-Dichlorobenzene (MW-11, MW-13, MW-16S, MW-36, and MW-38)
• 1,4-Dioxane ([MW-11, MW-12, MW-16S, MW-18, and MW-38)
• Benzene (MW-10, MW-11, MW-12, MW-13, MW-16S, MW-36, and MW-38)
• Methylene Chloride (MW-13)
• Tetrachloroethane (MW-13 and MW-36)
• Trichloroethene (MW-13)
• Vinyl Chloride (MW-11 and MW-16S)
In general, the detections and concentrations of organic constituents are consistent with historical
data. Historical data for groundwater constituents in compliance wells are summarized in Appendix
C, Table C-2, and historical data for constituents in performance and sentinel wells are summarized in
Appendix C, Table C-3.
5.3 Statistical Analyses
The 2020 ASD for metals established statistical background -based standards for cobalt (11.3 pg/L),
iron (14,182 pg/L), manganese (535 pg/L), and vanadium (45.2 pg/L). The ASD also calculated a
statistical background value for thallium; however, it was below the current NC2L; therefore, it was not
adopted as the GPS. No additional statistical analyses have been performed for this report.
5.4 Analytical Results for Surface Water
Surface monitoring point SMP-6 was sampled during the November 2023 event. Monitoring points
SMP-5 and SMP-7 were dry and were not sampled during this event. Table 4 presents the constituents
detected during the November 2023 sampling event and Table 5 presents the exceedances of surface
water standards. Iron and manganese were detected at concentrations exceeding their respective
NRWQC surface water standards. Historical surface water data can be found in Appendix C, Table C-
4.
November 2023 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County, Johns River C&D-over-MSW Landfill, Permit No. 12-03 February 2024
9

6.0 EVALUATION OF MONITORED NATURAL ATTENUATION (MNA)
6.1 MNA Parameters and Biodegradation Screening Matrix
In accordance with the CAP for the facility, MNA baseline sampling was initiated with the June 2009
sampling event and continued through the November 2010 sampling event. The baseline data were
evaluated in a CAER dated May 2011. MNA parameter data were obtained for the site background
well (MW-21) and downgradient compliance/performance wells MW-11, MW-12, and MW-16S. MNA
field parameters included temperature, pH, specific conductance, oxidation-reduction potential
dissolved oxygen, turbidity, and ferrous iron. MNA laboratory parameters included dissolved hydrogen,
alkalinity, TOC, dissolved methane, nitrate, sulfate, and chloride. Table 6 summarizes the MNA data
for the November 2023 event, and historical MNA data are presented in Appendix C, Table C-5.
The MNA parameter data were evaluated in general accordance with the United States Environmental
Protection Agency (EPA) Technical Protocol Manual (EPA, 1998) to determine whether the conditions
are conducive to, or whether there is evidence for anaerobic degradation of the chlorinated
hydrocarbons. Specifically, the results were evaluated according to the weighted system presented in
Table 2.3 of the Technical Protocol Manual, referred to hereafter as the Biodegradation Screening
Matrix. According to this manual, a score less than 5 indicates that there is inadequate evidence for
anaerobic natural attenuation, a score of 6 to 14 indicates that there is limited evidence for anaerobic
natural attenuation, a score of 15 to 20 indicates that there is adequate evidence for anaerobic natural
attenuation, and a score greater than 20 indicates that there is strong evidence that anaerobic natural
attenuation is occurring.
MNA evaluation was performed based on the results from the November 2023 sampling event for
downgradient wells within the contaminant plume, compared where appropriate to the background
well (MW-21). The Biodegradation Screening Matrix is presented as Table 7. One difficulty in evaluation
of the Screening Matrix is that the matrix assumes some compounds are daughter products of
biodegradation; however, at a landfill these constituents may have been released directly from the
landfill. If scores for these potential daughter products are included, the total score could be artificially
high; however, if these scores are excluded, the score might be artificially low. Table 7 presents scoring
results both with and without the questionable daughter product scores.
The following table summarizes the scoring results from Table 7 for both options for interpreting the
data. The scores ranged from 15 (adequate evidence of natural attenuation) to 28 (strong evidence
of natural attenuation). The average score is 21.5, indicating strong evidence of natural attenuation.
Including daughter
products
excluding daughter
products
Points Awarded
28
15
6.2 Biochlor Modeling and Mass -Balance Assessment
Anaerobic degradation of organic constituents, specifically chlorinated ethenes and ethanes, was
modeled using the EPA Biochlor System. The Biochlor model was set up to model flow, dispersion,
advection, adsorption, and biotransformation along a generalized flow line running from the waste unit
south toward the river. The concentration in the source area was set equal to the December 2015
sampling results from MW-13. Wells MW-11, MW-12, and MW-16S were included in the modeling
based on their respective distances from the southern edge of waste as summarized below:
November 2023 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County, Johns River C&D-over-MSW Landfill, Permit No. 12-03 February 2024
10

WELL:
MW-13
MW-11
MW-12
MW-16S
MW-18
MW-19
MODELED DISTANCE
0
20
60
135
210
430
FROM THE SOURCE (feet):
Modeling was done for both ethenes and ethanes. The ethene degradation sequence goes from
tetrachloroethene (PCE) to trichloroethene (TCE), to dichloroethenes (DCE), and to vinyl chloride (VC).
The ethane degradation sequence goes from trichloroethene (TCA) to dichloroethenes (DCA) to
chloroethane (CA). Please note that DCE is the sum of detected cis-1,2-dichloroethene, trans-1,2-
dichloroethene, and 1,1-dichloroethene. Similarly, DCA is the sum of 1,1-dichloroethane and 1,2-
dichloroethane.
The plume was assumed to be 1,600 feet wide and 500 feet long, based on the width of the plume at
the southern edge of waste and the average distance from the southern edge of waste to the river.
Simulation time was 22 years, based on the time between the closure of the MSW landfill and the
November 2023 sampling event. A seepage velocity of 114 feet/year was used based on groundwater
flow rate calculations for the November 2023 event as presented in Table 2 of this report. The input
and output of the Biochlor modeling are presented in Appendix D.
The results of the Biochlor modeling indicate moderate to poor agreement between the modeled
plume degradation and the analytical results for both ethenes and ethanes. The Biochlor model is a
two-dimensional model that assumes linear flow through an isotropic, homogeneous, porous medium,
and it assumes that the plume emanates from a point source and all the wells are along a line directly
downgradient from the source. Therefore, it is not surprising that it does not produce a good fit to real -
world data; however, it gives a first -order approximation of the biodegradation of chlorinated
hydrocarbons.
The mass rate calculations from the Biochlor modeling are summarized below. Cells labeled
"indeterminate" in the following tables indicate that the data were insufficient for the software to
calculate the values. The results indicate a large percentage of the contaminants are being removed
by biotransformation.
Ethenes
PCE
TCE
DCE VC
Mass Removed
3.1 Kg
4.1Kg
11.3 K -10.4K
% Biotransformed
83.7%
76.2%
67.6% indeterminate
• Change in Mass Rate
10.6%
10.6%
10.6% indeterminate
Ethanes
TCA
DCA
CA
Mass Removed
0.0 Kg
9.0 Kg
-1.4 Kg
% Biotransformed
indeterminate
82.6%
indeterminate
indeterminate
• Change in Mass Rate
indeterminate
99.7%
The fact that VC and CA, which may be the daughter products of dehalogenation of the higher -order
compounds, are detected at higher concentrations near the downgradient edge of the plume is
evidence that reductive dehalogenation is occurring. This supports the contention that biodegradation
is proceeding at an acceptable rate.
6.3 Trend Analysis and Plume Stability
Charts 1-14 show the concentrations of key constituents versus time for the wells MW-10, MW-11,
MW-12, MW-13, and MW-16S (and others, in most cases) versus time. Charts 1-12 include data from
the earliest recorded detections through November 2023; while Charts 12-14 show May 2011 through
November 2023 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County, Johns River C&D-over-MSW Landfill, Permit No. 12-03 February 2024
11

November 2023. In general, most constituents in most wells show decreasing or stable trends,
especially over the last 3 to 5 years. Benzene (Chart 1) in MW-13 shows a long-term increasing trend;
over the last three years it has been decreasing, but this year has shown an increase in levels.
1,4-dichlorobenzene (Chart 2) shows a long-term upward trend in MW-13, including a significant
increase since November 2022. MW-13 is located farther north (upgradient) than the other
downgradient wells and is representative of the central part of the plume, whereas MW-11, MW-12,
and MW-16S are located near the southern leading edge of the plume and MW-10 is located near the
western edge of the plume (Drawing 1). The fact that the concentrations in the central part of the
plume appear to be stable or increasing while the concentrations near the leading edge seem to be
stable or decreasing supports the contention that natural attenuation is adequately controlling the
plume.
Vinyl chloride (Chart 7) in MW-12 has shown an apparent increase in concentration over the last few
years, but with large fluctuations. It has shown an overall decrease since November 2021. 1,4-dioxane
(Chart 11) shows an apparent increase in MW-11 over the last four years, but with fluctuations. There
are no clear trends for 1,4-dioxane in the other wells.
Cobalt (Chart 10) shows a decreasing trend in wells MW-10 and MW-12 over the last 10 to 12 years;
however, cobalt in the other wells appears stable. Thallium (Chart 11) shows a long-term decreasing
trend in MW-10 while in the other wells it appears stable. Mercury (Chart 12) shows an increasing
trend in MW-13 over the last 2 to 3 years, but mercury in the other wells has been stable, mostly below
the NC2L standard. Iron (Chart 13) shows an increasing trend in MW-11, and slight increasing trends
in MW-12 and MW-16S but is stable in the other wells. Manganese (Chart 14) shows a decreasing
trend in MW-10 and an increasing trend in MW-11 but is stable in the other wells.
7.0 CONCLUSIONS
There were several inorganic and organic constituents detected above the NC2L groundwater
standards or established background values at the Johns River C&D-over-MSW Landfill during the
November 2023 sampling event. These results are generally consistent with previous sampling events
and are being addressed by the Corrective Action Plan for the facility. There were no new constituents
to be added to the facility's constituents of concern. A review of the MNA data and trend charts
indicates that MINA is adequately controlling the plume and the current remedies are sufficient. Iron
and manganese were detected above applicable surface water standards in surface water samples
collected during the November 2023 event.
The groundwater flow regime is consistent with previous events and the groundwater monitoring
network remains adequate to monitor the site. Based on these results, the C&D-over-MSW Landfill at
the Johns River Solid Waste Management Facility will remain in Assessment Monitoring and Corrective
Action. The next semiannual sampling event is tentatively scheduled for May 2024.
8.0 REFERENCES
Allen, M.R., Braithwaite, A., and Hills, C.C. (1997). Trace Organic Compounds in Landfill Gas at
Seven U.K. Waste Disposal Sites. Environmental Science and Technology. v. 31, p. 1054-
1061.
Cowie, S. (2004). Emission of Non -methane Organic Compounds (NMOCs) and hazardous air
Pollutants (HAPs) from Decomposing Refuse and Individual Waste Components and Under
Different Conditions. Master's Thesis, North Carolina State University.
November 2023 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County, Johns River C&D-over-MSW Landfill, Permit No. 12-03 February 2024
12

Deisper, A. and Stegmann, R. (1994). The Origin and Fate of Volatile Trace Components in
Municipal Solid Waste Landfills. Waste Management & Research. v. 12, p. 129-139.
Hinchee, R.E., A. Leeson, L. Semprini, and S.K. Ong. 1994. Bioremediation of Chlorinated and
Polycyclic Aromatic Hydrocarbon Compounds. Lewis Publishers, Boca Raton.
Interstate Technology and Regulatory Cooperation Work Group (ITRC). September 1999. Natural
Attenuation of Chlorinated Solvents in Groundwater. Principles and Practices.
Technical/Regulatory Guidelines.
Interstate Technical Regulatory Council (ITRC). 2003. Technical and Regulatory Guidance
Document for Constructed Treatment Wetlands.
Joyce Engineering, Inc. (JOYCE), 1994. Transition Plan, Johns River Waste Management Facility.
April 1994.
JOYCE, 2000. Water Quality Assessment Report, Johns River Waste Management Facility. January
2000.
JOYCE, 2004. Update on Groundwater Assessment Activities, Johns River Waste Management
Facility. October 2004.
JOYCE, 2005a. Assessment of Corrective Measures Report, Johns River Waste Management
Facility. February 2005.
JOYCE, 2005b. Quantitative Risk Assessment, Johns River Waste Management Facility. February
2005.
JOYCE, 2008. Corrective Action Plan, Johns River Waste Management Facility. June 2008.
JOYCE, 2011a. Corrective Action Evaluation Report, Johns River Waste Management Facility. May
2011.
JOYCE, 2011b. Alternate Source Demonstration for Iron and Manganese in Groundwater - Johns
River Waste Management Facility. November 2011.
JOYCE, 2013. Addendum to the Corrective Action Plan, Johns River Waste Management Facility.
August 2013.
JOYCE, 2017. Water Quality Monitoring Plan, Johns River Waste Management Facility. Revised
January 2017.
JOYCE, 2018. Addendum to the Corrective Action Plan, Johns River Waste Management Facility.
January 2018.
LaBella Associates, 2019. Alternate Source Demonstration for Metals - Johns River Waste
Management Facility. June 2019.
National Research Council (NRC), 2000. Natural Attenuation for Groundwater Remediation.
National Academy Press, Washington, D.C. pp. 108-111.
November 2023 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County, Johns River C&D-over-MSW Landfill, Permit No. 12-03 February 2024
13

North Carolina Department of Environmental Quality (NC-NCDEQ), 1997. North Carolina Solid Waste
Management Rules. 15 NCAC 13B. January 1, 1997; amended April 2011.
NCDEQ, 2007. North Carolina Solid Waste Section Guidelines for Corrective Action at Solid Waste
Management Facilities. March 2007.
Sumsion, C.T., and Laney, R.L., 1967, Geology and Ground -water Resources of the Morganton area
North Carolina. N.C. Department of Water Resources, Ground Water Bulletin No. 12, 119 p.
United States Department of Energy (USDE). May 1999. Decision -Making Framework Guide for the
Evaluation and Selection of Monitored Natural Attenuation Remedies at Department of
Energy Sites.
United States Environmental Protection Agency (USEPA), 1992. Statistical Analysis of Groundwater
Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance. July 1992.
USEPA. October 1988. Interim Final Guidance for Conducting Remedial Investigations and Feasibility
Studies under CERCLA. Office of Solid Waste and Emergency Response (OSWER) Directive
9355.3-01, EPA/540/G-89/004.
USEPA. February 1991. Conducting Remedial Investigations/Feasibility Studies for CERCLA
Municipal Landfill Sites. OSWER Directive 9355.3-11, EPA/540/P-91/001.
USEPA. May 1995. How to Evaluate Alternative Cleanup Technologies for Underground Storage Tank
Sites: A Guide for Corrective Action Plan Reviewers. Chapters 2 (Soil Vapor Extraction) and
10 (In -Situ Groundwater Bioremediation).
USEPA. May 1996. Seminars on Bioremediation of Hazardous Waste Sites: Practical Approaches to
Implementation. ORD,EPA/625/K-96/001. Chapters 15 (Natural Attenuation of
Groundwater) and 17 (Natural Attenuation of Landfills).
USEPA and U.S. Air Force (USAF). July 1993. Remediation Technologies Screening Matrix Reference
Guide, Version I. Joint Project of OSWER and Environics Directorate, PB93-2118212.
USEPA, 2009. Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified
Guidance. March 2009.
November 2023 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County, Johns River C&D-over-MSW Landfill, Permit No. 12-03 February 2024
14

TABLES
Table 1
Table 2
Table 3
Table 4
Table 5
Table 6
Table 7
Groundwater Elevations (November 2023)
Hydraulic Gradients & Linear Velocities (November 2023)
Field Parameters (November 2023)
Detected Constituents (November 2023)
Exceedances of Standards (November 2023)
MNA Parameters (November 2023)
Biodegradation Screening Matrix (November 2023)

TABLE 1: Groundwater Elevations (November 2023)
r
Background
Downgradient/Compliance Wells
Sentinel
Performance Wells
Location
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-18
MW-19
MW-36
MW-38
TOC Elevation
1099.86
1012.23
1028.58
1034.22
1059.40
1007.67
998.49
999.95
1099.52
1087.76
(FT - AMSL)
Well Depth
46.80
24.16
44.20
53.00
59.00
21.45
12.00
15.00
45.58
74.50
(FT - BTOC)
Depth to Water
38.35
13.35
36.78
41.59
49.71
16.61
6.96
8.38
34.03
44.56
(FT - BTOC)
Groundwater
Elevation
1061.51
998.88
991.80
992.63
1009.69
991.06
991.53
991.57
1065.49
1043.20
(FT - AMSL)
Notes:
TOC = Top of Casing
FT - AMSL = Feet above mean sea level
FT - BTOC = Feet below TOC
Water levels measured November 6-8, 2023.
Burke Co. - Johns River C+D-over-MSW Landfill LaBella Associates
Permit No. 12-03

TABLE 2: Hydraulic Gradient and Linear Velocity (November 2023)
November 6-8, 2023
HYDRAULIC
LINEAR
GRADIENT
FLOW LINE
GROUNDWATER
HORIZONTAL
EFFECTIVE
FLOW
CONDUCTIVITY
VELOCITY
CALCULATION
LENGTH
ELEVATION
GRADIENT
POROSITY
DIRECTION
K
V
SEGMENT
(feet)
(feet)
i
n e
(feet/day)
(feet/year)
1,060
I1
1,250
South
0.0520
3.28E+00
0.40
156
995
Notes:
Hydraulic conductivity (K=3.28 ft/day) is based on the average K from individual slug tests in saprolite wells at the facility.
Effective Porosity (n e = 0.40) is assumed to be slightly less than the average laboratory porosity for site soil samples (saprolite) = 44% (0.44).
Gradient segments are based on the November 2023 groundwater potentiometric surface map (see Drawing 1).
V = Kiln e; assumes a homogeneous, isotropic, porous aquifer.
Burke County Johns River C+D-over-MSW Landfill LaBella Associates
Permit # 12-03

TABLE 3: Field Parameters (November 2023)
SAMPLE ID
PARAMETER
RESULT
UNITS
DATE
Background Well
pH
10.96
S.U.
Temperature
18.02
°C
Turbidity
9.45
NTU
Conductivity
11.0
PS/cm
MW-21
Oxidation -Reduction Potential
-21.4
my
11/8/2023
Dissolved Oxygen
6.80
mg/L
Ferrous Iron
0.0
mg/L
Static Water Level
38.35
ft
Well Depth
46.80
ft
Downgradient/Compliance Wells
pH
10.03
S.U.
Temperature
18.45
°c
Turbidity
18.00
NTU
Conductivity
126
PS/cm
MW-10
11/7/2023
Oxidation -Reduction Potential
-199.9
my
Dissolved Oxygen
3.04
mg/L
Static Water Level
13.35
ft
Well Depth
24.16
ft
pH
10.97
S.U.
Temperature
18.27
°C
Turbidity
9.18
NTU
Conductivity
750
PS/cm
MW-11
Oxidation -Reduction Potential
-238.3
my
11/6/2023
Dissolved Oxygen
1.07
mg/L
Ferrous Iron
5.0
mg/L
Static Water Level
36.78
ft
Well Depth
44.20
ft
pH
10.81
S.U.
Temperature
17.83
°C
Turbidity
14.90
NTU
Conductivity
282
PS/cm
MW-12
Oxidation -Reduction Potential
16.6
my
11/6/2023
Dissolved Oxygen
0.53
mg/L
Ferrous Iron
3.5
mg/L
Static Water Level
41.59
ft
Well Depth
53.00
ft
Burke Co. - Johns River C+D-over-MSW Landfill
Permit No. 12-03
1of3
LaBella Associates

TABLE 3: Field Parameters (November 2023)
SAMPLE ID
PARAMETER
RESULT
UNITS
DATE
pH
4.74
S.U.
Temperature
17.80
°C
Turbidity
11.30
NTU
Conductivity
52.5
PS/cm
MW-13
11/7/2023
Oxidation -Reduction Potential
173.0
my
Dissolved Oxygen
7.03
mg/L
Static Water Level
49.71
ft
Well Depth
59.00
ft
pH
10.36
S.U.
Temperature
18.25
°C
Turbidity
8.77
NTU
Conductivity
252
PS/cm
MW-16S
Oxidation -Reduction Potential
-249.0
my
11/7/2023
Dissolved Oxygen
2.15
mg/L
Ferrous Iron
2.0
mg/L
Static Water Level
16.61
ft
Well Depth
21.45
ft
Performance & Sentinel Wells
pH
10.94
S.U.
Temperature
16.91
°C
Turbidity
187
NTU
Conductivity
305
PS/cm
MW-18
11/7/2023
Oxidation -Reduction Potential
-308.0
my
Dissolved Oxygen
3.61
mg/L
Static Water Level
6.96
ft
Well Depth
12.00
ft
pH
10.81
S.U.
Temperature
16.79
°C
Turbidity
8.71
NTU
Conductivity
314
PS/cm
MW-19
Oxidation -Reduction Potential
-275.0
my
11/7/2023
Dissolved Oxygen
1.45
mg/L
Ferrous Iron
2.0
mg/L
Static Water Level
8.38
ft
Well Depth
14.77
ft
Burke Co. - Johns River C+D-over-MSW Landfill
Permit No. 12-03
2 of 3
LaBella Associates

TABLE 3: Field Parameters (November 2023)
SAMPLE ID
PARAMETER
RESULT
UNITS
DATE
pH
10.64
S.U.
Temperature
15.84
°C
Turbidity
7.06
NTU
Conductivity
237
PS/cm
MW-36
11/7/2023
Oxidation -Reduction Potential
-141.8
my
Dissolved Oxygen
9.02
mg/L
Static Water Level
34.03
ft
Well Depth
45.58
ft
pH
10.83
S.U.
Temperature
16.05
°C
Turbidity
8.86
NTU
Conductivity
500
PS/cm
MW-38
11/7/2023
Oxidation -Reduction Potential
-182.0
mg/L
Dissolved Oxygen
10.02
my
Static Water Level
44.56
ft
Well Depth
74.50
ft
Surface Water
pH
DRY
S.U.
Temperature
DRY
°C
Turbidity
DRY
NTU
SMP-5
11/6/2023
Conductivity
DRY
PS/cm
Oxidation -Reduction Potential
DRY
my
Dissolved Oxygen
DRY
mg/L
pH
11.24
S.U.
Temperature
14.07
°C
Turbidity
52.00
NTU
SMP-6
11/6/2023
Conductivity
141
PS/cm
Oxidation -Reduction Potential
-298.5
my
Dissolved Oxygen
0.94
mg/L
pH
DRY
S.U.
Temperature
DRY
°C
Turbidity
DRY
NTU
SMP-7
11/6/2023
Conductivity
DRY
PS/cm
Oxidation -Reduction Potential
DRY
my
Dissolved Oxygen
DRY
mg/L
Notes: °C = degrees Centigrade
S.U. = Standard Units
pS/cm = microSiemens per centimeter
NTU = Nephelometric Turbidity Units
mg/L = milligrams per liter
my = millivolts
ft = feet
Burke Co. - Johns River C+D-over-MSW Landfill
Permit No. 12-03
3 of 3
LaBella Associates

TABLE 4: Detected Constituents (November 2023)
WELL ID
PARAMETER
RESULT
METHOD
MDL
I MRL
STANDARD
COLLECT DATE
Background Well
Barium
26.5
EPA 6010D
0.79
5.0
700
NC 2L
Chromium
0.98 J
EPA 6010D
0.63
5.0
10
NC 2L
Cobalt
0.56 J
EPA 6010D
0.44
5.0
11.3
BKGD
Copper
1.8 J
EPA 6010D
0.62
5.0
1000
NC 2L
MW-21
11/6/2023
Iron
574
EPA 6010D
8.9
50.0
14182
NC 2L
Manganese
45.4
EPA 6010D
0.86
5.0
535
BKGD
Vanadium
3.3 J
EPA 6010D
1.6
5.0
45.2
BKGD
Nitrate
150
EPA 353.2 Rev 2.0 1993
29.0
40.0
NE
NE
Downgradient/Compliance Wells
Antimony
3.8 J
EPA 6010D
3.6
5.0
1
NC 2L
Barium
97.3
EPA 6010D
0.79
5.0
700
NC 2L
Cadmium
0.33 J
EPA 6010D
0.29
1.0
2
NC 2L
Chromium
3.8 J
EPA 6010D
0.63
5.0
10
NC 2L
Cobalt
47.5
EPA 6010D
0.44
5.0
11.3
BKGD
Copper
5.6
EPA 6010D
0.62
5.0
1,000
NC 2L
Iron
22,800
EPA 6010D
8.9
50.0
14,182
BKGD
Lead
5.5
EPA 6010D
1.4
5.0
15
NC 2L
Manganese
3,190
EPA 6010D
0.86
5.0
535
BKGD
Mercury
1.8
EPA 7470A
0.12
0.2
1
NC 2L
Nickel
4.9 J
EPA 6010D
0.88
5.0
100
NC 2L
Thallium
0.49
EPA 6020B
0.05
0.2
2
NC 2L
MW-10
Vanadium
6.1
EPA 6010D
1.6
5.0
45.2
BKGD
11/7/2023
Zinc
25.8
EPA 6010D
3.0
10.0
1,000
NC 2L
1,4-Dichlorobenzene
1.2
EPA 8260D
0.33
1.0
6
NC 2L
1,4-Dioxane
1.0 J
EPA 8260D Mod.
0.86
2.0
3
NC 2L
Benzene
1.5
EPA 8260D
0.34
1.0
1
NC 2L
Chlorobenzene
1.5
EPA 8260D
0.28
1.0
50
NC 2L
cis-1,2-Dichloroethene
2.3
EPA 8260D
0.38
1.0
70
NC 2L
Alkalinity
48,500
SM 2320B-2011
5,000
5,000
NE
NE
Chloride
12,000
EPA 300.0 Rev 2.11993
600
1,000
250,000
NC 2L
Nitrate
46.0
EPA 353.2 Rev 2.0 1993
29.0
40.0
NE
NE
Sulfate
1,300
EPA 300.0 Rev 2.11993
500
1,000
250,000
NC 2L
Sulfide
23.4 J
SM 4500-S2D-2011
22.0
100
NE
NE
Total Dissolved Solids
8,400
SM 2540C-2015
2,500
2,500
500,000
NC 2L
Barium
168
EPA 6010D
0.79
5.0
700
NC 2L
Cadmium
1.0
EPA 6010D
0.29
1.0
2
NC 2L
Chromium
6.1
EPA 6010D
0.63
5.0
10
NC 2L
Cobalt
19.8
EPA 6010D
0.44
5.0
11.3
BKGD
Iron
6,800
EPA 6010D
8.95
50.0
14,182
BKGD
Manganese
1,285
EPA 6010D
0.86
5.0
535
BKGD
Nickel
9.8
EPA 6010D
0.88
5.0
100
NC 2L
Silver
0.56 J
EPA 6010D
0.49
5.0
20
NC 2L
Thallium
0.52
EPA 6020B
0.05
0.2
2
NC 2L
Zinc
13.0
EPA 6010D
3.0
10.0
1,000
NC 2L
1,1-Dichloroethane
2.0
EPA 8260D
0.37
1.0
6
NC 2L
1,2-Dichlorobenzene
0.34 J
EPA 8260D
0.34
1.0
20
NC 2L
MW-11
11/6/2023
1,4-Dichlorobenzene
11.9
EPA 8260D
0.33
1.0
6
NC 2L
1,4-Dioxane
35.5
EPA 8260D Mod.
0.86
2.0
3
NC 2L
Benzene
2.7
EPA 8260D
0.34
1.0
1
NC 2L
Chlorobenzene
0.97 J
EPA 8260D
0.28
1.0
50
NC 2L
Chloroethane
1.0
EPA 8260D
0.65
1.0
3,000
NC 2L
cis-1,2-Dichloroethene
3.1
EPA 8260D
0.38
1.0
70
NC 2L
Toluene
0.29 J
EPA 8260D
0.24
1.0
600
NC 2L
Vinyl chloride
1.4
EPA 8260D
0.39
1.0
0.03
NC 2L
Alkalinity
213,000
SM 2320B-2011
5,000
5,000
NE
NE
Chloride
93,800
EPA 300.0 Rev 2.11993
600
1,000
250,000
NC 2L
Sulfate
6,900
EPA 300.0 Rev 2.11993
500
1,000
250,000
NC 2L
Total Dissolved Solids
47,000
SM 2540C-2015
2,500
2,500
500,000
NC 2L
Burke Co. -John's River C+D-over-MSW LF La Bella Associates
Permit No. 12-03 1 of 4

TABLE 4: Detected Constituents (November 2023)
WELL ID
PARAMETER
RESULT
METHOD
MDL
1 MRL
STANDARD
COLLECT DATE
Barium
66.6
EPA 6010D
0.79
5.0
700
NC 2L
Chromium
3.4 J
EPA 6010D
0.63
5.0
10
NC 2L
Cobalt
33.9
EPA 6010D
0.44
5.0
11.3
BKGD
Iron
47,000
EPA 6010D
8.9
50.0
14,182
BKGD
Manganese
1400
EPA 6010D
0.86
5.0
535
BKGD
Nickel
5.3
EPA 6010D
0.88
5.0
100
NC 2L
1,1-Dichloroethane
18.2
EPA 8260D
0.37
1.0
6
NC 2L
1,2-Dichloroethane
0.97 J
EPA 8260D
0.32
1.0
0.4
NC 2L
1,4-Dichlorobenzene
5.4
EPA 8260D
0.33
1.0
6
NC 2L
1,4-Dioxane
13.1
EPA 8260D Mod.
0.86
2.0
3
NC 2L
2-Methyl naphthalene
16.6
EPA 8270E
1.6
8.3
30
NC 2L
Benzene
3.6
EPA 8260D
0.34
1.0
1
NC 2L
Chlorobenzene
0.85 J
EPA 8260D
0.28
1.0
50
NC 2L
MW-12
11/6/2023
Chloroethane
5.7
EPA 8260D
0.65
1.0
3,000
NC 2L
cis-1,2-Dichloroethene
9.5
EPA 8260D
0.38
1.0
70
NC 2L
Ethylbenzene
0.62 J
EPA 8260D
0.3
1.0
600
NC 2L
Toluene
0.77 J
EPA 8260D
0.24
1.0
600
NC 2L
Trichloroethene
2.1
EPA 8260D
0.38
1.0
3
NC 2L
Vinyl chloride
0.69 J
EPA 8260D
0.39
1.0
0.03
NC 2L
Total Xylenes
2.8
EPA 8260D
0.34
1.0
500
NC 2L
Alkalinity
134,000
SM 2320B-2011
5,000
5,000
NE
NE
Chloride
17,000
EPA 300.0 Rev 2.11993
600
1,000
250,000
NC 2L
Nitrate
52.0
EPA 353.2 Rev 2.0 1993
29.0
40.0
NE
NE
Sulfate
1,200
EPA 300.0 Rev 2.11993
500
1,000
250,000
NC 2L
Sulfide
41.1 J
SM 4500-S2D-2011
22.0
100
NE
NE
Total Dissolved Solids
16,400
SM 2540C-2015
2,500
2,500
500,000
NC 2L
Barium
82.4
EPA 6010D
0.79
5.0
700
NC 2L
Cadmium
0.31 J
EPA 6010D
0.29
1.0
2
NC 2L
Chromium
1.4 J
EPA 6010D
0.63
5.0
10
NC 2L
Cobalt
69.8
EPA 6010D
0.44
5.0
11.3
BKGD
Copper
12.0
EPA 6010D
0.62
5.0
1,000
NC 2L
Iron
3,090
EPA 6010D
8.9
50.0
14,182
BKGD
Lead
2.0 J
EPA 6010D
1.4
5.0
15
NC 2L
Manganese
1,930
EPA 6010D
0.86
5.0
535
BKGD
Mercury
3.1
EPA 7470A
0.12
0.2
1
NC 2L
Nickel
4.4 J
EPA 6010D
0.88
5.0
100
NC 2L
Thallium
0.18 J
EPA 6020B
0.05
0.2
2
NC 2L
Vanadium
2.4 J
EPA 6010D
1.6
5.0
45.2
BKGD
Zinc
18.4
EPA 6010D
3.0
10.0
1,000
NC 2L
1,1-Dichloroethane
10.3
EPA 8260D
0.37
1.0
6
NC 2L
1,2-Dichlorobenzene
0.77 J
EPA 8260D
0.34
1.0
20
NC 2L
MW-13
1,2-Dichloroethane
0.65 J
EPA 8260D
0.32
1.0
0.4
NC 2L
11/7/2023
1,4-Dichlorobenzene
20.9
EPA 8260D
0.33
1.0
6
NC 2L
1,4-Dioxane
1.7 J
EPA 8260D Mod.
0.86
2.0
3
NC 2L
Benzene
11.6
EPA 8260D
0.34
1.0
1
NC 2L
Chlorobenzene
1.7
EPA 8260D
0.28
1.0
50
NC 2L
cis-1,2-Dichloroethene
18.4
EPA 8260D
0.38
1.0
70
NC 2L
Ethylbenzene
1.4
EPA 8260D
0.3
1.0
600
NC 2L
Methylene Chloride
38.5
EPA 8260D
2.0
5.0
5
NC 2L
Naphthalene
3.1
EPA 8260D
0.64
1.0
6
NC 2L
Tetrachloroethene
4.1
EPA 8260D
0.29
1.0
0.7
NC 2L
Toluene
1.6
EPA 8260D
0.24
1.0
600
NC 2L
Trichloroethene
6.2
EPA 8260D
0.38
1.0
3
NC 2L
Total Xylenes
53.5
EPA 8260D
0.34
1.0
500
NC 2L
Chloride
2,000
EPA 300.0 Rev 2.11993
600
1,000
250,000
NC 2L
Sulfate
1,200
EPA 300.0 Rev 2.11993
500
1,000
250,000
NC 2L
Total Dissolved Solids
3,300
SM 2540C-2015
2,500
2,500
500,000
NC 2L
Burke Co. -John's River C+D-over-MSW LF La Bella Associates
Permit No. 12-03 2 of 4

TABLE 4: Detected Constituents (November 2023)
WELL ID
PARAMETER
RESULT
METHODE
MDL
MRL
STANDARD
COLLECT DATE
Barium
60.3
EPA 6010D
0.79
5.0
700
NC 2L
Chromium
3.7 J
EPA 6010D
0.63
5.0
10
NC 2L
Cobalt
28
EPA 6010D
0.44
5.0
11.3
BKGD
Iron
39,200
EPA 6010D
8.9
50.0
14,182
BKGD
Manganese
1,370
EPA 6010D
0.86
5.0
535
BKGD
Nickel
5.1
EPA 6010D
0.88
5.0
100
NC 2L
Zinc
4.0 J
EPA 6010D
3.0
10.0
1,000
NC 2L
1,1-Dichloroethane
11.9
EPA 8260D
0.37
1.0
6
NC 2L
1,2-Dichloroethane
1.0
EPA 8260D
0.32
1.0
0.4
NC 2L
1,4-Dichlorobenzene
7.8
EPA 8260D
0.33
1.0
6
NC 2L
1,4-Dioxane
13.3
EPA 8260D Mod.
0.86
2.0
3
NC 2L
MW-16S
11/7/2023
Benzene
3.0
EPA 8260D
0.34
1.0
1
NC 2L
Chlorobenzene
1.0
EPA 8260D
0.28
1.0
50
NC 2L
Chloroethane
4.5
EPA 8260D
0.65
1.0
3,000
NC 2L
cis-1,2-Dichloroethene
6.8
EPA 8260D
0.38
1.0
70
NC 2L
Trichloroethene
0.43 J
EPA 8260D
0.38
1.0
3
NC 2L
Vinyl chloride
1.0
EPA 8260D
0.39
1.0
0.03
NC 2L
Alkalinity
136,000
SM 2320B-2011
5,000
5,000
NE
NE
Chloride
13,000
EPA 300.0 Rev 2.11993
600
1,000
250,000
NC 2L
Nitrate
76.0
EPA 353.2 Rev 2.0 1993
29.0
40.0
NE
NE
Sulfate
1,100
EPA 300.0 Rev 2.11993
500
1,000
250,000
NC 2L
Total Dissolved Solids
16,500
SM 2540C-2015
2,500
2,500
500,000
NC 2L
Performance & Sentinel Wells
Cobalt
9.4 J
EPA 6010
0.96
10.0
11.3
BKGD
Iron
10,200
EPA 6010
25.0
40.0
14,182
BKGD
Manganese
660
EPA 6010
1.5
5.0
535
BKGD
Thallium
0.25 J
EPA 6020
0.11
1.0
2
NC 2L
1,4-Dioxane
3.8
EPA 8260D Mod.
0.86
2.0
3
NC 2L
MW-18
11/7/2023
Vinyl chloride
0.61 J
EPA 8260D
0.39
1.0
0.03
NC 2L
Alkalinity
114,000
SM 2320B-2011
5,000
5,000
NE
NE
Chloride
11,800
EPA 300.0 Rev 2.11993
600
1,000
250,000
NC 2L
Sulfate
540 J
EPA 300.0 Rev 2.11993
500
1,000
250,000
NC 2L
Total Dissolved Solids
14,200
SM 2540C-2015
2,500
2,500
500,000
NC 2L
Cobalt
25.3
EPA 6010
0.96
10.0
11.3
BKGD
Iron
12,500
EPA 6010
25.0
40.0
14,182
BKGD
Manganese
735
EPA 6010
1.1
5.0
535
BKGD
1,1-Dichloroethane
0.54 J
EPA 8260D
0.37
1.0
6
NC 2L
MW-19
Alkalinity
176,000
SM 2320B-2011
5,000
5,000
NE
NE
11/7/2023
Chloride
1,500
EPA 300.0 Rev 2.11993
600
1,000
250,000
NC 2L
Sulfate
2,400
EPA 300.0 Rev 2.11993
500
1,000
250,000
NC 2L
Sulfide
31.0 J
SM 4500-S2D-2011
22.0
100
NE
NE
Total Dissolved Solids
20,300
SM 2540C-2015
2,500
2,500
500,000
NC 2L
Cobalt
34
EPA 6010
0.96
10.0
11.3
BKGD
Iron
22,500
EPA 6010
25.0
40.0
14,182
BKGD
Manganese
2,250
EPA 6010
5.5
25.0
535
BKGD
1,1-Dichloroethane
1.3
EPA 8260D
0.37
1.0
6
NC 2L
MW-36
1,4-Dichlorobenzene
19
EPA 8260D
0.33
1.0
6
NC 2L
11/8/2023
Benzene
3.4
EPA 8260D
0.34
1.0
1
NC 2L
Tetrachloroethene
1.0
EPA 8260D
0.29
1.0
0.7
NC 2L
Trichloroethene
1.6
EPA 8260D
0.38
1.0
3
NC 2L
Vinyl chloride
0.6 J
EPA 8260D
0.39
1.0
0.03
NC 2L
Burke Co. -John's River C+D-over-MSW LF La Bella Associates
Permit No. 12-03 3 of 4

TABLE 4: Detected Constituents (November 2023)
WELL ID
PARAMETER
RESULT
METHOD
MDL
MRL
STANDARD
COLLECT DATE
Barium
143
EPA 6010
0.84
10.0
700
NC 2L
Chromium
4.0 J
EPA 6010
1.7
5.0
10
NC 2L
Cobalt
58.1
EPA 6010
0.96
10.0
11.3
BKGD
Copper
4.5 J
EPA 6010
2.6
5.0
1,000
NC 2L
Iron
14,500
EPA 6010
25.0
40.0
14,182
BKGD
Lead
2.9 J
EPA 6010
2.1
10.0
15
NC 2L
Manganese
383.5
EPA 6010
1.1
5.0
535
BKGD
Nickel
12.4
EPA 6010
1.0
5.0
100
NC 2L
Selenium
4.4 J
EPA 6010
3.9
15.0
20
NC 2L
Vanadium
5.7 J
EPA 6010
1.0
10.0
45.2
NC 2L
Zinc
11.5 J
EPA 6010
11.0
20.0
1,000
NC 2L
1,1-Dichloroethane
2.2
EPA 8260D
0.37
1.0
6
NC 2L
1,2-Dichlorobenzene
0.37 J
EPA 8260D
0.34
1.0
20
NC 2L
MW-38
1,4-Dichlorobenzene
18.6
EPA 8260D
0.33
1.0
6
NC 2L
11/8/2023
1,4-Dioxane
7.5
EPA 8260D Mod.
0.86
2.0
3
NC 2L
Benzene
3.5
EPA 8260D
0.34
1.0
1
NC 2L
Chlorobenzene
0.81 J
EPA 8260D
0.28
1.0
50
NC 2L
cis-1,2-Dichloroethene
1.5
EPA 8260D
0.38
1.0
70
NC 2L
Ethylbenzene
1.7
EPA 8260D
0.3
1.0
600
NC 2L
Tetrahydrofuran
364
EPA 8260D
3.5
10.0
NE
NE
Toluene
0.6 J
EPA 8260D
0.24
1.0
600
NC 2L
Vinyl chloride
0.62 J
EPA 8260D
0.39
1.0
0.03
NC 2L
Total Xylenes
8.4
EPA 8260D
0.34
1.0
500
NC 2L
Alkalinity
252,000
SM 2320B-2011
5,000
5,000
NE
NE
Chloride
13,000
EPA 300.0 Rev 2.11993
600
1,000
250,000
NC 2L
Sulfate
700 J
EPA 300.0 Rev 2.11993
500
1,000
250,000
NC 2L
Total Dissolved Solids
294,000
SM 2540C-2015
25,000
25,000
500,000
NC 2L
Surface Water
Barium
66.1
EPA 6010D
0.79
5.0
1,000
NC 2B
Cadmium
0.31 J
EPA 6010D
0.29
1.0
0.83
NC 2B*
Total Hardness
25,400
EPA 6010D
36.8
662
100,000
NC 2B
Iron
44,600
EPA 6010D
8.9
50.0
1,000
NRWQC
Manganese
1,110
EPA 6010D
0.86
5.0
50
NRWQC
SMP-6
Zinc
5.2 J
EPA 6010D
3.0
10.0
36.69
NC 2B*
11/6/2023
1,1-Dichloroethane
1.3
EPA 8260D
0.37
1.0
6
ISTV
Acetone
11.1 J
EPA 8260D
5.1
25.0
3,100
ISTV
cis-1,2-Dichloroethene
0.97 J
EPA 8260D
0.38
1.0
60
ISTV
Toluene
0.79 J
EPA 8260D
0.24
1.0
11
NC 213
Trichloroethene
0.44 J
EPA 8260D
0.38
1.0
2.5
NC 213
Blanks
FIELD BLANK Iron 18.8 J EPA 6010D 8.9 50.0 11/8/2023
Notes:
All concentrations in micrograms per liter (µg/L)
MDL: Method Detection Limit
MRL: Method Reporting Limit
J: Estimated concentration above the MDL but below the MRL
B: Blank -qualified detection
(Detected at a similar concentration in a trip, field, or method blank)
NC 2L: NC Groundwater Standard from 15A NCAC 2L.0202
NC 2B: NC Surface Water Standard from 15A NCAC 2B
(NC 2B*: hardness -dependent standard)
ISTV: North Carolina In -Stream Target Values
NRWQC: EPA National Recommended Water Quality Criteria
BKGD: Approved Background Value
NE: Not Established
Burke Co. -John's River C+D-over-MSW LF La Bella Associates
Permit No. 12-03 4 of 4

TABLE 5: Exceedances of Standards (November 2023)
WELL ID
PARAMETER
RESULT
METHOD
MIDI
STANDARD
COLLECT DATE
Downgradient/Compliance Wells
Cobalt
47.5
EPA 6010D
0.44
5.0
11.3
BKGD
Iron
22,800
EPA 6010D
8.9
50.0
14,182
BKGD
MW-10
Manganese
3,190
EPA 6010D
0.86
5.0
535
BKGD
11/7/2023
Mercury
1.8
EPA 7470A
0.12
0.2
1
NC 2L
Benzene
1.5
EPA 8260D
0.34
1.0
1
NC 2L
Cobalt
19.8
EPA 6010D
0.44
5.0
11.3
BKGD
Manganese
1,285
EPA 6010D
0.86
5.0
535
BKGD
1,4-Dichlorobenzene
11.9
EPA 8260D
0.33
1.0
6
NC 2L
MW-11
11/6/2023
1,4-Dioxane
35.5
EPA 8260D Mod.
0.86
2.0
3
NC 2L
Benzene
2.7
EPA 8260D
0.34
1.0
1
NC 2L
Vinyl chloride
1.4
EPA 8260D
0.39
1.0
0.03
NC 2L
Cobalt
33.9
EPA 6010D
0.44
5.0
11.3
BKGD
Iron
47,000
EPA 6010D
8.9
50.0
14,182
BKGD
Manganese
1,400
EPA 6010D
0.86
5.0
535
BKGD
MW-12
11/6/2023
1,1-Dichloroethane
18.2
EPA 8260D
0.37
1.0
6
NC 2L
1,4-Dioxane
13.1
EPA 8260D Mod.
0.86
2.0
3
NC 2L
Benzene
3.6
EPA 8260D
0.34
1.0
1
NC 2L
Cobalt
69.8
EPA 6010D
0.44
5.0
11.3
BKGD
Manganese
1,930
EPA 6010D
0.86
5.0
535
BKGD
Mercury
3.1
EPA 7470A
0.12
0.2
1
NC 2L
1,1-Dichloroethane
10.3
EPA 8260D
0.37
1.0
6
NC 2L
MW-13
1,4-Dichlorobenzene
20.9
EPA 8260D
0.33
1.0
6
NC 2L
11/7/2023
Benzene
11.6
EPA 8260D
0.34
1.0
1
NC 2L
Methylene Chloride
38.5
EPA 8260D
2.0
5.0
5
NC 2L
Tetrachloroethene
4.1
EPA 8260D
0.29
1.0
0.7
NC 2L
Trichloroethene
6.2
EPA 8260D
0.38
1.0
3
NC 2L
Cobalt
28.0
EPA 6010D
0.44
5.0
11.3
BKGD
Iron
39,200
EPA 6010D
8.9
50.0
14,182
BKGD
Manganese
1,370
EPA 6010D
0.86
5.0
535
BKGD
1,1-Dichloroethane
11.9
EPA 8260D
0.37
1.0
6
NC 2L
MW-16S
1,2-Dichloroethane
1.0
EPA 8260D
0.32
1.0
0.4
NC 2L
11/7/2023
1,4-Dichlorobenzene
7.8
EPA 8260D
0.33
1.0
6
NC 2L
1,4-Dioxane
13.3
EPA 8260D Mod.
0.86
2.0
3
NC 2L
Benzene
3.0
EPA 8260D
0.34
1.0
1
NC 2L
Vinyl chloride
1.0
EPA 8260D
0.39
1.0
0.03
NC 2L
Performance & Sentinel Wells
Manganese
660
EPA 6010
1.5
5.0
535
BKGD
MW-18
11/7/2023
1,4-Dioxane
3.8
EPA 8260D Mod.
0.86
2.0
3
NC 2L
Cobalt
25.3
EPA 6010
0.96
10.0
11.3
BKGD
MW-19
11/7/2023
Manganese
735
EPA 6010
1.1
5.0
535
BKGD
Cobalt
34.0
EPA 6010
0.96
10.0
11.3
BKGD
Iron
22,500
EPA 6010
25.0
40.0
14,182
BKGD
Manganese
2,250
EPA 6010
5.5
25.0
535
BKGD
M W-36
11/8/2023
1,4-Dichlorobenzene
19
EPA 8260D
0.33
1.0
6
NC 2L
Benzene
3.4
EPA 8260D
0.34
1.0
1
NC 2L
Tetrachloroethene
1.0
EPA 8260D
0.29
1.0
0.7
NC 2L
Cobalt
58.1
EPA 6010
0.96
10.0
11.3
BKGD
Iron
14,500
EPA 6010
25.0
40.0
14,182
BKGD
1,4-Dichlorobenzene
18.6
EPA 8260D
0.33
1.0
6
NC 2L
M W-38
11/8/2023
1,4-Dioxane
7.5
EPA 8260D Mod.
0.86
2.0
3
NC 2L
Benzene
3.5
EPA 8260D
0.34
1.0
1
NC 2L
Tetrahydrofuran
364
EPA 8260D
3.5
10.0
10
NE
Surface Water
Iron
44,600
EPA 6010D
8.9
50
1,000
NRWQC
SMP-6
11/6/2023
Manganese
1,110
EPA 6010D
0.86
5
50
NRWQC
Notes:
All concentrations in micrograms per liter (µg/L)
MDL: Method Detection Limit
MRL: Method Reporting Limit
NC 2L: NC Groundwater Standard from 15A NCAC 2L.0202
BKGD: Approved Background Value
NRWQC: EPA National Recommended Water Quality Criteria
NE: Not Established
Burke Co. - Johns River C+D-over-MSW LF LaBella Associates
Permit No. 12-03

TABLE 6: MNA Parameters (November 2023)
Ana lyte/Para meter
Date
Units
Background
Downgradient
Sentinel
Performance
MW-21
MW-10
MW-11
MW-12
MW-13 MW-16S
MW-18
MW-19
MW-36
MW-38
pH (FP)
11/8/2023
S.U.
10.96
10.03
10.97
10.81
4.74 10.36
10.94
10.81
10.64
10.83
Temperature (FP)
11/8/2023
11/8/2023
11/8/2023
11/8/2023
°C
18.02
18.45
18.27
17.83
17.80 18.25
16.91
16.79
15.84
16.05
500
Conductivity (FP)
pS/cm
11.0
126
750
282
52.5 252
305
314
237
ORP (FP)
mV
-21.4
-199.9
-238.3
16.6
173.0 -249.0
-308.0
-275.0
-141.8
-182.0
Dissolved Oxygen (FP)
mg/L
6.80
3.04
1.07
0.53
7.03 2.15
3.61
1.45
9.02
10.02
Turbidity (FP)
11/8/2023
11/8/2023
NTU
9.45
18.00
9.18
14.90
11.30 8.77
187
8.71
7.06
8.86
Iron II (ferrous iron) (FP)
mg/L
0.0
NA
5.0
3.5
NA 2.0
NA
2.0
NA
NA
Nitrate
11/8/2023
pg/L
150
46
ND
52
NA 76
ND
ND
NA
NA
Alkalinity
11/8/2023
pg/L
ND
48,500
213,000
134,000
ND 136,000
114,000
176,000
NA
252,000
Chloride
11/8/2023
11/8/2023
pg/L
ND
12,000
93,800
17,000
2,000 13,000
11,800
1,500
NA
13,000
Sulfate
pg/L
ND
1,300
6,900
1,200
1,200 1,100
540 J
2,400
NA
700 J
Sulfide
11/8/2023
11/8/2023
pg/L
ND
23.4 J
ND
41.1 J
ND ND
ND
31 J
NA
NA
Methane
pg/L
7.5 J,B
647
2,820
5,920
NA 3,870
2,690
2,240
3,470
4,860
Dissolved Hydrogen
11/8/2023
11/8/2023
nM
1.4 J
NA
ND
1.4 J
NA 5.3
1.6 J
3.0
NA
NA
Total Organic Carbon
pg/L
ND
730 J
7,800
1,500
NA 1,600
3,000
4,300
NA
NA
Tetrachloroethene
11/8/2023
11/8/2023
pg/L
ND
ND
ND
ND
4.1 ND
ND
ND
1.0
ND
Trichloroethene
pg/L
ND
ND
ND
2.1
6.2 0.43 J
ND
ND
1.6
ND
cis-1,2-Dichloroethene
11/8/2023
11/8/2023
pg/L
ND
2.3
3.1
9.5
18.4 6.8
NA
NA
NA
1.5
Vinyl Chloride
pg/L
ND
ND
1.4
0.69 J
ND 1.0
0.61 J
ND
0.60 J
0.62 J
1,1,1-Trichloroethane
11/8/2023
11/8/2023
pg/L
ND
ND
ND
ND
ND ND
NA
NA
NA
ND
1,1-Dichloroethane
pg/L
ND
ND
2.0
18.2
10.3 11.9
ND
0.54 J
1.3
2.2
Chloroethane
11/8/2023
11/8/2023
pg/L
ND
ND
1.0
5.7
ND 4.5
NA
NA
NA
ND
Chloroform
pg/L
ND
ND
ND
ND
ND ND
NA
NA
NA
ND
Methylene Chloride
11/8/2023
pg/L
ND
ND
ND
ND
38.5 ND
ND
ND
ND
ND
Notes:
S.U. = Standard Units
°C = degrees Celsius
pS/cm = microSiemens per centimeter
my = millivolts
NTU = Nephelometric Turbidity Units
nM = nanomoles
J = Estimated concentration above the adjusted method detection limit and below the adjusted reporting II
B = Detected above the reporting limit in the associated method blank
pg/L = micrograms per liter
mg/L = milligrams per liter
(FP) = Field Parameter
ND = Not Detected
Burke Co. -Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03

TABLE 7: Biodegradation Screening Matrix (November 2023)
Concentration
Possible
Points Awarded
Points Awarded
Parameter
in Plume
Interpretation
Points
with DP points
without DP points
Tolerated, suppresses the reductive pathway at higher
< 0.5 mg/L
concentrations
3
Oxygen
> 5 mg/L
Not tolerated; however, vinyl chloride may be oxidized
3
aerobically
t ig er concentrations may compete with reductive
Nitrate
< 1 mg/L
pathway
2
2
2
Iron II (Ferrous Iron)
> 1 mg/L
Reductive pathway possible; vinyl chloride may be oxidized
3
3
3
under Fe (III) - reducing conditions
t ig er concentrations may compete with reductive
Sulfate
< 20 mg/L
pathway
2
2
2
Sulfide*
> 1 mg/L
Reductive pathway possible
3
0
0
< 0.5 mg/L
Vinyl chloride oxidizes
0
Ultimate reductive daughter product, vinyl chloride
Methane
> 0.5 mg/L
3
3
0
accumulates
Oxidation Reduction Potential
< 50 mV
Reductive pathway possible
1
< -100 mV
Reductive pathway likely
2
2
2
5 < pH < 9
Optimal range for reductive pathway
0
p H
5 > pH > 9
Outside optimal range for reductive pathway
-2
-2
-2
Carbon and energy source; drives dechlorination; can be
Total Organic Carbon (TOC)
> 20 mg/L
2
0
0
natural or anthropogenic
Temperature
>200 C
At T > 200C biochemical process is accelerated
1
0
0
Carbon Dioxide *
> 2x background
Ultimate oxidative daughter product
1
0
0
Alkalinity
> 2x background
Results from interaction between CO2 and aquifer minerals
1
1
1
Chloride
> 2x background
Daughter product of organic chlorine
2
2
2
> 1 nM
Reductive pathway possible
3
3
3
Hydrogen
< 1 nM
Vinyl chloride oxidizes
0
Intermediates resulting from biodegradation of more
Volatile Fatty Acids *
> 0.1 mg/L
2
2
2
complex compounds; carbon and energy source
BTEX
> 0.1 mg/L
Carbon and energy source; drives dechlorination
2
0
0
Tetrachloroethene (PCE)
---
Material released
0
0
0
Material released
0
0
Trichloroethene (TCE)
---
Daughter product of PCE
2
2
Dichloroethenes (DCE)
---
Material released
0
0
Daughter product of TCE
2
0
cis-1,2-Dichloroethene
---
Material released
0
0
---
Daughter product of trichlorethene
2
2
Vinyl Chloride (VC)
---
Material released
0
0
Daughter product of DCE
2
2
1,1,1-Trichloroethene (TCA)
---
Material released
0
0
0
1,1-Dichloroethane (DCA)
---
Material released
0
0
Daughter product of TCA
2
2
Chloroethane
---
Daughter product of dichloroethane or vinyl chloride under
2
2
0
reducing conditions
> 0.01 mg/L
2
0
0
Ethene/Ethane *
Daughter products of vinyl chloride/ethene
> 0.1 mg/L 1
3
0
0
Chloroform
---
Material released
0
0
0
Daughter product of carbon tetrachloride
2
0
0
Methylene Chloride
---
Material released
0
0
0
Daughter product of chloroform
1 2
0
1 0
Based on samples collected in November 2023 Total Points Awarded:
28
15
* These parameters are required on a reduced schedule; however, they were available for this event.
mg/L = miligrams per liter When current results are not available, scores for these parameters may be based on historical results.
mV
= millivolts
nM
= nanomolar
C =
Celsius
NA
= Not Analyzed
NOTE: Chloroethane, Methane, TCE, DCE, cis-1,2-DCE, MC, VC, DCA, and CO2 are all present in the plume; however,
it is uncertain whether these are primary leachate constituents or daughter products (DPs); therefore, there
are two calculation columns. The first column assumes all of these are daughter products, and the
second column assumes none of them are. The true score is probably between the two.
BTEX = Sum of Benzene, Toluene, Ethylbenzene, and Total Xylenes (Score based on MW-13 data).
This screening matrix is prepared in general accordance with the United Stated Environmental Protection Agency's
(EPA's) Table 2.3 Analytical Parameters and Weighted for Preliminary Screening for Anaerobic Biodegradation
Process presented in the EPA's Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents
in Groundwater, September 1988.
SCORE:
Evid. of Nat. Atten.
6-14
limited
15-19
adequate
> 20
strong
Burke Co. - Johns River C+D-over-MSW Landfill
Permit 12-03 LaBella Associates

CHARTS
Chart 1
Benzene Concentrations vs. Time
Chart 2
1,4-Dichlorobenzene Concentrations vs. Time
Chart 3
1,1-Dichloroethane Concentrations vs. Time
Chart 4
1,2-Dichloroethane Concentrations vs. Time
Chart 5
Tetrachloroethylene (PCE) Concentrations vs. Time
Chart 6
Trichloroethylene (TCE) Concentrations vs. Time
Chart 7
Vinyl Chloride Concentrations vs. Time
Chart 8
Methylene Chloride Concentrations vs. Time
Chart 9
1,4-Dioxane Concentrations vs. Time
Chart 10
Cobalt Concentrations vs. Time
Chart 11
Thallium Concentrations vs. Time
Chart 12
Mercury Concentrations vs. Time
Chart 13
Iron Concentrations vs. Time
Chart 14
Manganese Concentrations vs. Time

Chart 1:
Benzene Concentration vs. Time in Downgradient Wells
20
15
t M W-10
t M W-11
3
—dr- M W-12
c
�
—(—MW-13
c 10
d
0—MW-16S
c
M W-18
0
U
t M W-19
—MW-36
— M W-38
—GPS
5
I
0
T > T >
T >
>
>
T0
> T
T0
> T > T > T > T > > > > > > >
T0 T0
m >
>
m >
>
@ O l0 O
2 Z 2 Z
@ O
2 Z
M
2 Z2
@T O> M
o
Z 2 Z 2 Z2
O> @T
Z 2 Z2
M o M o M M M M
Z2 Z2 Z2 Z2 Z2 Z2 Z 2 Z2 Z 2 Z2 Z2 Z2 Z2
@T O>
Z 2 Z2
M Z2
Z2
M Z
M O
2 Z
Johns River Landfill, Burke Co. La Bella Associates
Permit 12-03

c
0
c
m
U
c
25
20
15
5
0
Chart 2: IA-Dichlorobenzene Concentration vs. Time in Downgradient Wells
O O) O) a1 O) O) a1 a1 O) a1 a1 O) O OO Q O Q O Q O Q O Q O Q O Q O Q O Q c-I ci c-I c-I ci ci c-I ci ci c-I c-I ci c-I c-I ci ci c-I ci ci c-I N N N N N N N N
(6 O c0 O c0 O f6 O c0 O f6 O c0 O c0 O f6 O c0 O (6 O c0 O c0 O (6 O c0 O f6 O c0 O c0 O f0 O c0 O f6 O c0 O c0 O f6 O c0 O f6 O c0 O c0 O f6 O c0 O
g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z
tMW-10
tMW-11
—BMW-12
—0(-- M W-13
—0Ur M W-16S
— M W-18
tMW-19
— M W-36
— M W-38
—GPS
Johns River Landfill, Burke Co. La Bella Associates
Permit 12-03

300
250
200
u�
c
O
150
c
aD
U
c
0
U
100
50
0
Chart 3: 1,1-Dichloroethane vs. Time in Downgradient Wells
V 7 Ln In O O r ti W 00 O 01 O O e-I .--I N N M M V a Ln In U O r ti W W O O O O e-I .--I N N M m V a Ln In U O r r W W O O O
O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O e-I e-I e-I e-I e-I e-I e-I e-I e-I e-I e-I e-I e-I e-I e-I e-I e-I e-I e-I e-I N N N N N N N N N
T > T > T > T > T > T > T > T > T > T > T > T > T > T > T > T > T > T > T > T > T > T > T > T > T > T > T > T > T > >. >
c6 O (6 O (6 O l6 O (6 O l6 O f6 O l6 O l6 O f6 O l6 O (6 O l6 O f6 O l6 O l6 O f6 O l6 O (6 O l6 O f6 O f6 O l6 O f6 O l6 O (6 O l6 O f6 O f6 O l6 O
2 z g z g z 2 z g z 2 z g z 2 z 2 z g z 2 z g z 2 z g z 2 z 2 z g z 2 z g z 2 z g z g z 2 z g z 2 z g z 2 z g z g z 2 z
tMW-10
tMW-11
—BMW-12
—K-- M W-13
—I-- M W-16S
— M W-18
BMW-19
— M W-36
— M W-38
—GPS
Johns River Landfill, Burke Co. LaBella Associates
Permit 12-03

Chart 4: 1,2-Dichloroethane vs. Time in Downgradient Wells
14
12
10
0
U 6
4
2
0
> T > T > T > T > T > T > T > T > T > T > T > T > T > T > T > T > T > T >
O (0 O (0 O (0 O (0 O f0 O f0 O f0 O (0 O (0 O (0 O f0 O f6 O f0 O f0 O (0 O (0 O (0 O f0 O
Z 2 Z 2 Z 2 Z 2 Z 2 Z 2 Z 2 Z 2 Z 2 Z 2 Z 2 Z 2 Z 2 Z 2 Z 2 Z 2 Z 2 Z 2 Z
tMW-10
f M W-11
—gir- M W-12
--K-- M W-13
--)K-- M W-16S
— M W-18
t M W-19
— M W-36
— M W-38
—GPS
Johns River Landfill, Burke Co. LaBella Associates
Permit 12-03

nil
12
10
8
4
2
0
Chart 5: Tetrachloroethene vs. Time in Downgradient Wells
O O O O O O O O O O O O O O O O O O O O O O O O O O e-I e-I e-I e-I e-I e-I e-I e-I e-I e-I e-I c-I c-I e-I e-I e-I e-I e-I e-I e-I N N N N N N N N
T > T> T > T> T > T> T> T> T> T> T> T> T> T> T> T> T> T> T> T > T> T > T> T > T> T > T>
(0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O 0 O (0 O (0 O (0 O
g z 2 z g z 2 z g z 2 z g z 2 z g z 2 z g z 2 z g z 2 z g z 2 z g z 2 z 2 z g z 2 z g z 2 z g z 2 z g z 2 z
—H M W-10
f M W-11
� M W-12
—�4— M W-13
—I-- M W-16S
— M W-18
t• M W-19
—MW-36
— M W-38
—GPS
Johns River Landfill, Burke Co. LaBella Associates
Permit 12-03

Chart 6: Trichloroethene vs. Time in Downgradient Wells
20
18
16
14
--- M W-10
12
t M W-11
MW-12
c
o
—X--M W-13
10
—I-- M W-16S
a
c
— M W-18
U
$
M W-19
M W-36
M W-38
6
G PS
4
AA
2
0
V V� In O M r N W 00 O 01 O O e-I rl N N M M V V� In O M r N W 00 O 01 O O e-I ei N N M M V V� In O M r ti W 00 O 01 O O c-I ei N N M M
O m 0 0 0 m O m O m O m O O O O O O O O O O O O O O O O O O O O e-I ei e-I ei e-I rl c-I rl c-I rl c-I a -I e-I a -I e-I a -I e-I a -I e-I a -I N N N N N N N N
> >. > >. > >. > >. > >. > >. > >. > >. > T > >. > >. > >. > >. > >. > >. > >. > >. > >. > >. > >. > >. > >. > >. > >. > >. > >. > >. > >. >
(0 (0 (0 (0 (0 (0 (0 (0 (6 (0 (0 (0 (0 (0 (0 (0 (0 (0 (0 (0 (0 (0 (0 (0 (0 (0 (0 (0
O (6 O O O O O O O O O (6 O O O O O O O O O O O O O O O O O O O O
z g z g z g z g z g z g z 2 z 2 z g z g z 2 z g z g z g z g z g z 2 z 2 z g z 2 z 2 z g z g z g z g z 2 z 2 z 2 z g z
Johns River Landfill, Burke Co. LaBella Associates
Permit 12-03

Chart 7:
Vinyl Chloride vs. Time in Downgradient Wells
5
4.5
4
3.5
3
BMW-10
f M W-11
—BMW-12
o
—F M W-13
2.5
c
CIF MW-16S
c�
c
— M W-18
0
t M W-19
2-A
A—
M W-36
— M W-38
A
GPS
1.5
A
r
1
N
'Sir
0.5
0
N
N
O
(0
O
O
O
l0
O
O
O
(0
O
O
�--I
l0
ci
O
ci ci ci
l0 O (0
ci ci ci ci ci ci ci ci ci ci ci ci ci ci ci
O l0 O (0 O (0 O l0 O (0 O l0 O l0 O
N
(0
N
O
N N
l0
C-
O
N
(0
N
O
N N
(0
N N
O
g
z
g
z
g
z
g
z
g z g
z g z g z g z g z g z g z g z
g
z
g
z
g
z
g
z
Johns River Landfill, Burke Co. LaBella Associates
Permit 12-03

Chart 8: Methylene Chloride vs. Time in Downgradient Wells
900
800
700
600
500
c
0
c
d
400
0
U
300
200
100
0
7 0 In CO M 1` 1` w w O O O O ei rl N N M M V-t In In M M 1` 1` w w O M O O c-I ei N N M M a a In In M M 1` r w w M M O O c-I rl N N M M
01 01 01 O) M M O) O) 01 M M M O O O O O O O O O O O O O O O O O O O O c-I ei ei ei ei ei ei ei ei ei ei ei ei ei ei ei ei ei ei ei N N N N N N N N
>. > >. > >. > >. > >. > >. > >. > >. > >. > >. > >. > >. > >. > >. > >. > >. > >. > >. > >. > T > >. > >. > T > T > >. > >. > >. > >. > >. > >. >
M O M O M O M O MO M O M O M O M O M O M O M O M O M O M O M O M O M O M O M O M O M O M O M O M O M O M O M O M O M O
g z g z 2 z g z g Z 2 Z g Z g Z g Z g Z g Z g Z 2 Z g Z g Z g Z g Z g Z g Z g Z g Z g Z g Z g Z g Z g Z g Z g Z g Z g Z
t M W-10
f M W-11
-ram M W-12
—F M W-13
—I-- M W-16S
— M W-18
t M W-19
— M W-36
— M W-38
—GPS
Johns River Landfill, Burke Co.
Permit 12-03 LaBella Associates

40
M
30
25
u�
z
c
0
" 20
c
IV
CJ
C
U
15
10
A
0
Chart 9: 1,4-Dioxane vs. Time in Downgradient Wells
00 O O rl ci N N
N N N N N N N N
> T > T > CO
Z Z CO Z Z � Z Z
t M W-10
f M W-11
M W-12
--A— M W-13
--)K-- M W-16S
BMW-18
t M W-19
— M W-36
M W-38
G PS
Johns River Landfill, Burke Co. LaBella Associates
Permit 12-03

Chart 10: Cobalt vs. Time in Downgradient Wells
375
350
325
300
275
250
225
s
c
8 200
m
Y
175
0
U
150
125
100
75
50
25
0
� Lc') Lc') CO t0 I� ti W W M m O O .-I .1 N N M M 7 7 In In O O r ti W W m m O O rl ei N N M M 7 7 In In O M N N W 00 O O O O rl ci N N M M
O M M M O M O M O7 M m 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 e-I a -I e-I a -I e-I rl e-I a -I e-I a -I e-I rl e-I a -I e-I a -I e-I rl e-I ei N N N N N N N N
0 T > T 0 >. 0 0 >. 0 0 >. 0 0 >. 0 0 0>. > >. 0 0 >. 0 0 >. 0 >. >
O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O (0 O
z 2 z 2 z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z 2 z
t M W-10
t M W-11
MW-12
--A— M W-13
--I-- M W-16S
— M W-18
t M W-19
— M W-36
— M W-38
—GPS
Johns River Landfill, Burke Co. LaBella Associates
Permit 12-03

Chart 11: Thallium vs. Time in Downgradient Wells
40.0
35.0
30.0
15.0
10.0
5.0
0.0
r W W M M O O � . N N M M 7 V 0 0 O (0 r r W w M O O O N M M V 7 0 0 O 0 r r M w M O O O N M M
m M M M M O O O O O O O O O O O O O O O O O O O O rl ci rl ci rl ci rl .-i rl .-i rl ci rl ci rl .-i .-I .-I rl .-i N N N N N N N N
> > > > > > > > > > > > > > > > > > > > > > > > > > >
O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O O m O m O m O m O m O
z z g z g z g z g z g z g z g z g z g z g z z g z g z z z z z z z z 2 z 2 z g z g z g z
tMW-10
fMW-11
—BMW-12
—KFMW-13
—IFMW-16S
tMW-1S
BMW-19
BMW-36
—MW-3S
tGPS
Johns River Landfill, Burke Co. LaBella Associates
Permit 12-03

14
12
10
4
2
0
CHART 12: Mercury Concentrations vs. Time in Downgradient Wells
Ln un lO w 1, n w w T T O O -1 ci N N M M-ZT V Ln u1 W w I- n w w T T O O .--I r-i N N M M V V V1 V1 w w I- n w w T T O O ri ri N N M M
T T T T T T T T T T 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01�
T> T> T> T> T> T> T> T> T> T> T> T> T> T> T> T> T> T> T> T> T> T> T> T> T> T> T> T> T>
M O M O m O M O M O m O M O M O m O M O co O co O M O M O m O M O M O co O M O M O M O M O M O M O M O M O M O M O co O
g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z g z
tMW-10 tMW-11 MW-12 tMW-13 tMW-16S GPS
Johns River C+D-over-MSW Landfill
Permit #12-03 LaBella Associates

Chart 13:
Iron vs. Time in Downgradient Wells
150,000
140,000
130,000
120,000
110,000
M W-21
f M W-10
100,000
—� M W-11
90,000
�—MW-12
s
—I� M W-13
c
°
80,000
BMW-16S
c
tMW-16D
d
70,000
O
—MW-18
VU
_
—MW-19
60,000
—
0--MW-36
t M W-38
50,000
—�GPS
40,000
30,000
20,000
■
10,000
0
O --�
c-I c-I ci
> T >
N N CI
c-I c-I ci
T > T
M V 4 LO
ci c-I c-I c-I
> T > T
LO (O (O f— 00 00 0) 0)
rl c� ci ci c-I c-I ci ci c-I
> T > T > T > T >
O
N
T
O ci '1 N N M CO
N N N N N N N
> T > T > T >
O 07 O
Z Z
07 O (0
Z
O 07 O c6
Z Z
O 07 O (0 O 07 O (0 O
Z Z Z Z Z
(0
O 07 O (0 O 07 O
Z Z Z Z
Johns River Landfill, Burke Co. LaBella Associates
Permit 12-03

Chart 14: Manganese vs. Time in Downgradient Wells
30000
25000
20000
n�
s
c
0
i+
15000
a�
U
0
0
10000
5000
0
0 ci 11 N N M (0 V V LO LO (O (O n r 00 00 0 0 0 0 ci �i N N of M
-4 -1 -1 .--I .-I .-I .--I .--I .-I .-I .--I .--I .-I .--I .--I .-I .-I .--I .--I N N N N N N N N
O (0 O CO O CO O CO O (0 O CO O CO O (0 O CO O (0 O CO O (0 O (0 O
z g z 2 z g z 2 z g z 2 z 2 z g z 2 z g z 2 z g z z
tMW-21
t M W-10
—Ar- M W-11
—F M W-12
—I-- M W-13
t M W-16S
t M W-16D
— M W-18
— M W-19
t M W-36
f M W-38
—Ar-GPS
Johns River Landfill, Burke Co. LaBella Associates
Permit 12-03

FIGURE
Figure 1 Site Location Map

0
I %
1)210
C,
W
'P
0 00
/000
X
%
,APPROXIMATE LOCATION
OF PROPERTY LINE
APPROXIMATE LOCATION
OF ACTIVE LANDFILL
%
160
APPROXIMATE 0 TIO /ZIP
%
OF CLOSED LANDFILL
GRAPHIC SCALE
O'ro 0 1000 2000 4000
(FEET)
LaBeRa MAP SOURCE: MORGANTON, NC USGS QUADRANGLE GROUNDWATER MONITORING REPORT
Powered by partnership.
FIGURE NAME: DRAWN BY: DATE: PROJECT NO.:
12-D OAK BRANCH DRIVE SITE LOCATION MAP RWH 01/05/24 2233479.0
GREENSBORO NC, 27407
PHONE: [phone] PROJECT NAME: FIGURE NUMBER:
JOHNS RIVER LANDFILL
labellapc.com (02024 LaBella Associates BURKE COUNTY, NORTH CAROLINA
L-\Burke Cmnty\2021 SITE LOCATION MAP SITE LOCATION MAP 24.Ewg

DRAWING
Drawing 1 Groundwater Potentiometric Surface Map (November 2023)

O\
1 \ — pq
r / \\ \
� - \ j \\\\ \\\�� % P TECTED RE'A I �'
�\ �� \ \ \ ✓ (1� EXISTING TRAIL \-
/ / /,�/ /1
CURRENT BAeKGRO ND WELL \ \ \�\\� TRANSFER FACILITY \
_ -_
WETLAND-
7080
_
/ I r \
1 ��A� -z4
r � \� 1053.01
MULCHIN
/ GARI
R U Q W
A
C&D EXPANSION
o LANDFILL
a \— l I '�°\ \�
2 A/W/ 00
o
p o / _ ,o,o, \
6\ \ > ( BAND \ 1 /// / l �\ \� 1 // f / /
Ali I
IN
/ / \
l 1 � /� I�
l �/ 11 l I III I PZ-
/
�PPRO . I TO:
\ o-�
XIS I S E
/BOU D R / I� I �l I I 11 II I l s I \\� \ \� \ /
> o M I \\\�� \\\ \ 11 ��� mffz
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o 00 0 C&D OVER MSWI� �/
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��� � // 1\ \ \ � •/
\\�\
/\—� i •
IN
X\\
\\\ \ \ \
\ 1 R
1 \\
\ \ ,o�=
\\ \X
\ \ \ XISTING
\ SEDIMENT
BASIN
MW-16S
9.06 — /
SMP-5 9 17 ✓% -16D �
\smum
/
� —�
991.53 / �99 MW-19
0�0
Q 991.57
/ CPS
GRAPHIC SCALE
0 100 200 400
(FEET)
— 1050 — -
1080
- MW-13
ELEV.
MW-18
O MW-9
PZ-9D
GP GMP-3
0 SMP-5
1 r— e-% r— s 1 r1
EXISTING 25TOPOGRAPHIC CONTOUR
EXISTING 10' TOPOGRAPHIC CONTOUR
EXISTING 5' TOPOGRAPHIC CONTOUR
EXISTING 2' TOPOGRAPHIC CONTOUR
GROUNDWATER SURFACE CONTOUR [FEET
ABOVE MEAN SEA LEVEL (AMSL)]
PROPERTY LINE
GROUNDWATER FLOW PATHWAY USED TO
CALCULATE HYDRAULIC GRADIENT
EXISTING ROAD
APPROXIMATE LIMITS OF WASTE
CENTERLINE OF STREAM
COMPLIANCE WELL LOCATION AND IDENTIFICATION WITH STATIC
WATER LEVEL ELEVATION (FEET AMSL)
SENTINEL WELL LOCATION AND IDENTIFICATION WITH STATIC
WATER LEVEL ELEVATION (FEET AMSL)
ABANDONED OR UNUSED MONITORING WELL
PIEZOMETER LOCATION AND IDENTIFICATION
GAS PROBE LOCATION AND IDENTIFICATION
SURFACE MONITORING POINT LOCATION AND IDENTIFICATION
T1 TEMPORARY WELL
(NM) NOT MEASURED
-^ o APPROXIMATE LOCATION OF SPRING HEAD
Q JE-0020 CONTROL POINT LOCATION AND IDENTIFICATION
OSEGMENT USED FOR GRADIENT CALCULATION
1
FLOW PATH LENGTH
Z1 1,250 LF
Q1,180 LF
l..�ti W.I
1. TOPOGRAPHIC CONTOUR INTERVAL = 2 AND 10 FEET.
2. GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET.
3. STATIC WATER LEVELS WERE MEASURED ON NOVEMBER 6-8, 2023.
4. GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION BETWEEN AND
EXTRAPOLATION FROM KNOWN DATA, TOPOGRAPHIC CONTOURS, AND KNOWN
FIELD CONDITIONS.
LaBeLLa
Powered by partnership.
12-D OAK BRANCH DRIVE
GREENSBORO, NC 27407
PHONE: [phone]
labellapc.com
F— T —1
© 2024 LaBella Associates
JOHNS RIVER WASTE
MANAGEMENT FACILITY
BURKE COUNTY, NORTH CAROLINA
NU: DATE: DESCRIPTION:
Revisions
PROJECT NUMBER:
2233479.0
DRAWN BY:
RH
REVIEWED BY:
PD
ISSUED FOR:
GROUNDWATER MONITORING REPORT
DATE:
02/29/24
DRAWING NAME
GROUNDWATER
POTENTIOMETRIC
SURFACE MAP
NOVEMBER 6-8, 2023
DRAWING NUMBER:
1

APPENDICES
Appendix A: Well Construction Data
Appendix B: Laboratory Analytical Reports and Field Logs
Appendix C: Historical Data Tables
Appendix D: Biochlor Modeling Input & Output

Appendix A
Well Construction Data

APPENDIX A: Construction Data for Wells and Piezometers
ID (Former ID)
GS
Elevation
TOC
Elevation
Date
Installed
GW
AR (BR)
TD
Top
Screen
Bottom
Screen
Stick-up
Lithology of
Screened Interval
Comments
(Ft-AMSL)
(Ft-AMSL)
(Ft.-TOC)
(Ft.-AMSL)
(Ft.-BGS)
(Ft.-AMSL)
(Ft.-BGS)
(Ft.-AMSL)
(Ft.-BGS)
(Ft.-BGS)
(Ft.-BGS)
MW-1 (W-1)
1052.48
1054.98
Sept 1987
31.48
1023.50
bne
< 1012
40
1012.5
18.5
28.5
2.50
Saprolite
Abandoned Feb. 2018
MW-2 (W-5)
1012.00
1014.50
Sept 1987
15.83
998.67
bne
< 988
24.5
987.5
14.5
24.5
2.50
Saprolite
MW-3 (W-4A)
1025.00
1027.50
Sept 1987
43.95
983.55
bne
< 966
59.5
965.5
49.5
59.5
2.50
Saprolite
MW-4 (W-2)
1016.00
1018.00
Sept 1987
25.20
992.80
bne
< 986
30.5
985.5
18.5
30.5
2.00
Saprolite
MW-5 (W-3)
1032.00
1034.00
Sept 1987
49.55
984.45
bne
< 979
53
979.0
43
53
2.00
Saprolite
MW-6 (W-8)
1000.00
1002.50
Sept 1987
na
na
bne
< 983
17
983.0
7
17
2.50
Saprolite
Abandoned 10/94
MW-7 (W-7)
1050.00
1052.50
Sept 1987
na
na
29.5
1020.5
39.5
1010.5
29.5
39.5
2.50
Bedrock
MW-8
1070.70
1072.55
Sept 1987
31.14
1041.41
bne
< 1031
40
1030.7
27.5
37.5
1.85
Saprolite
MW-9
1144.34
1145.97
Sept 1994
na
na
25
1119.3
73
1071.3
51
66
1.63
Bedrock
Abandoned 07/06
MW-10
1009.80
1012.23
Sept 1994
12.05
1000.18
bne
< 987
23
986.8
8
23
2.43
Saprolite
Old LF Compliance
MW-11
1026.63
1028.58
Sept 1994
33.53
995.05
bne
< 984
43
983.6
28
43
1.95
Saprolite
Old LF Compliance
MW-12
1032.57
1034.22
Sept 1994
38.90
995.32
19
1013.6
51.5
981.1
37
51.5
1.65
Bedrock
Old LF Compliance
MW-13
1057.07
1059.40
Sept 1994
49.35
1010.05
bne
< 999
58
999.1
43
58
2.33
Saprolite
Old LF Compliance
MW-14
1014.76
1017.96
June 1996
8.87
1009.09
bne
< 993
21.5
993.3
5
20
3.20
Saprolite
Old LF Compliance
MW-15S
1066.88
1069.04
June 1996
42.40
1026.64
bne
< 1013
54
1012.9
39
54
2.16
Saprolite
Old LF Compliance
MW-15D
1066.67
1069.06
June 1996
41.87
1027.19
100
966.7
118.5
948.2
109
119
2.39
Bedrock
Old LF Compliance
MW-16S
1005.67
1007.67
June 1996
13.60
994.07
20
985.7
20
985.7
5
20
2.00
Saprolite
Old LF Compliance
MW-16D
1005.67
1007.87
June 1996
12.65
995.22
20
985.7
120
885.7
78
88
2.20
Bedrock
Removed from Network April 2022
MW-17
1119.73
1121.77
June 1996
40.15
1081.62
45
1074.7
52
1067.7
37
52
2.04
Transiton Zone
Former Background Well
MW-18
995.67
998.49
April 2009
5.45
993.04
bne
< 984
12
983.7
7
12
2.82
Alluvium
Old LF Sentinel
MW-19
996.99
999.95
April 2009
7.04
992.91
bne
< 984
13
984.0
8
13
2.96
Alluvium
Old LF Sentinel
MW-20 (PZ-4)
1114.74
1115.04
May 1995
62.20
1052.84
67
1047.7
67
1047.7
52
67
0.30
Saprolite
Former Background / Ph. 1A Compliance
MW-21 (PZ-1)
1097.00
1099.86
May 1995
35.15
1064.71
bne
< 1052
45
1052.0
30
45
2.86
Saprolite
Background Well
MW-22S (PZ-22S)
1058.57
1061.20
June 1996
16.95
1044.25
bne
< 1034
25
1033.6
10
25
2.63
Saprolite
Abandoned Feb. 2018
MW-22D (PZ-22D)
1057.90
1060.13
June 1996
15.98
1044.15
45.5
1012.4
45
1012.9
40
45
2.23
Saprolite/PWR
Abandoned Feb. 2018
MW-23S (PZ-16S)
1037.66
1040.23
June 1996
9.35
1030.88
bne
< 1018
20
1017.7
3
20
2.57
Saprolite
Ph. 2A&4 Compliance
MW-23D (PZ-16D)
1037.77
1040.18
June 1996
3.31
1036.87
53
984.8
68
969.8
63
68
2.41
Bedrock
Ph. 2A&4 Supplemental
MW-24S (PZ-8S)
1066.60
1069.04
May 1995
47.29
1021.75
bne
< 1011
55
1011.6
40
55
2.44
Saprolite
No longer sampled.
MW-24D (PZ-8D)
1-066.1-3
1068.15
June 1996
47.44
1020.71
74
992.1
89.5
976.6
84.5
89.5
2.02
Bedrock
Ph.2A&4 Supplemental
MW-30
1052.46
1054.35
16-Dec-2015
31.65
1022.70
bne
< 1002.5
50
1002.5
35
50
1.89
Saprolite
Ph. 2A&4 Compliance
MW-35 (PZ-35)
1060.64
1063.39
May 2011
20.30
1043.09
57.5
1003.1
57.5
1003.1
15
35
2.75
Saprolite
Ph. 2A&4 Compliance
MW-36 (PZ-36)
1096.52
1099.52
May 2011
30.60
1068.92
25
1071.5
43
1053.5
28
43
3.00
Bedrock
Old LF Performance
MW-38 (PZ-38)
1081.63
1084.76
May 2011
40.28
1044.48
30
1051.6
71
1010.6
40-50
60-70
3.13
Bedrock
Ph. 1A Compliance / Old LF Performance
T-1
1012.31
1014.77
March 1999
3.01
1011.76
bne
< 1009
3
1009.3
1
3
2.46
Alluvium
T-2
1005.47
1007.85
March 1999
4.03
1003.82
bne
< 1002
3
1002.5
1
3
2.38
Alluvium
T-3
999.93
1001.84
March 1999
9.23
992.61
bne
< 980
20
979.9
5
20
1.91
Alluvium/Saprolite
T-4
1002.26
1004.08
March 1999
15.13
988.95
bne
< 977
25
977.3
10
25
1.82
Alluvium/Saprolite
T-5
1001.01
1003.30
March 1999
11.45
991.85
bne
< 981
20
981.0
5
20
2.29
Alluvium
PZ-2S
1152.60
1154.74
May 1995
na
na
80
1072.6
80
1 1072.6
65
80
2.14
Saprolite
NLE
PZ-2D
1152.40
1154.53
May 1995
na
na
77
1075.4
117
1035.4
102
117
2.13
Bedrock
NLE
PZ-3
1040.51
1043.01
May 1995
na
na
bne
< 1027
14
1026.5
4
14
2.50
Saprolite
NLE
PZ-5
1095.10
1097.23
May 1995
58.80
1038.43
bne
< 1030
65
1030.1
50
65
2.13
Saprolite
PZ-6
1019.90
1021.91
May 1995
na
na
bne
< 987
33
986.9
18
33
2.01
Saprolite
Damaged, but still existent.
PZ-7
1014.60
1016.48
May 1995
21.06
995.42
bne
< 987
28
986.6
13
28
1.88
Saprolite
Johns River Landfill, Permit #12-03 Page 1 of 2 La Bella Associates
Burke County, NC

APPENDIX A: Construction Data for Wells and Piezometers
ID (Former ID)
GS
Elevation
TOC
Elevation
Date
Installed
GW
AR (BR)
TD
Top
Screen
Bottom
Screen
Stick-up
Lithology of
Screened Interval
Comments
(Ft-AMSL)
(Ft-AMSL)
(Ft.-TOC)
(Ft.-AMSL)
(Ft.-BGS)
(Ft.-AMSL)
(Ft.-BGS)
(Ft.-AMSL)
(Ft.-BGS)
(Ft.-BGS)
(Ft.-BGS)
PZ-9S
1022.66
1025.16
May 1995
21.30
1003.86
bne
< 995
28
994.7
13
28
2.50
Saprolite
PZ-9D
1023.50
1025.96
May 1995
17.21
1008.75
47
976.5
67
956.5
52
67
2.46
Bedrock
PZ-10
1125.30
na
May 1995
na
na
51
1074.3
51
1074.3
na
na
na
na
Boring only
PZ-11
1162.50
na
May 1995
na
na
43.5
1119.0
43.5
1119.0
na
na
na
na
Boring only
PZ-12
1022.55
1025.64
June 1996
7.81
1017.83
bne
< 1011
12
1010.6
5
12
3.09
Saprolite
PZ-13
1014.49
1018.35
June 1996
8.84
1009.51
bne
< 1008
6.5
1008.0
1.5
6.5
3.86
Saprolite
PZ-14
1018.31
1019.34
June 1996
7.11
1012.23
bne
< 1009
9.5
1008.8
2.5
9.5
1.03
Saprolite
PZ-15
1067.45
1069.62
June 1996
na
na
bne
< 1037
30
1037.5
13
30
2.17
Saprolite
NLE
PZ-17
1049.01
1050.95
June 1996
35.29
1015.66
bne
<1014
35
1014.0
20
35
1.94
Saprolite
PZ-18
1054.11
1056.68
June 1996
na
na
bne
< 999
55
999.1
40
55
2.57
Saprolite
NLE
PZ-19
1046.67
1049.17
June 1996
27.98
1021.19
bne
< 1017
30
1016.7
15
30
2.50
Saprolite
PZ-20
1074.59
1075.88
June 1996
na
na
bne
< 1030
45
1029.6
30
45
1.29
Saprolite
PZ-21
1065.07
1067.65
June 1996
55.65
1012.00
bne
< 1000
65
1000.1
50
65
2.58
Saprolite
PZ-23
1057.52
1059.96
June 1996
25.02
1034.94
bne
< 1013
45
1012.5
30
45
2.44
Saprolite
PZ-24
1165.53
1168.28
June 1996
90.03
1078.25
47.5
1118.0
109
1056.5
54
109
2.75
Bedrock
PZ-25
1127.45
1130.14
June 1996
68.76
1061.38
51
1076.5
79
1048.5
64
79
2.69
Bedrock
PZ-26
1122.00
1124.44
June 1996
74.72
1049.72
64
1058.0
84
1038.0
69
84
2.44
Bedrock
PZ-27
1018.34
1020.84
Dec. 1996
Dry
Dry
na
na
-7.25
-1011
na
-7.25
na
na
No Log or Records
PZ-30S
1085.67
1088.92
May 2011
39.93
1048.99
bne
< 1034
52
1033.7
37
52
3.25
Transition Zone
PZ-30D
1085.73
1088.48
May 2011
40.71
1047.77
47
1038.7
82
1003.7
67
82
2.75
Bedrock
PZ-31
1086.69
1089.81
May 2011
27.44
1062.37
35
1051.7
41
1045.7
25
40
3.13
Transition Zone
PZ-32
1080.12
1083.12
May 2011
35.49
1047.63
49.5
1030.6
65
1015.1
29
49
3.00
Saprolite
Abandonded 3/5/2014
PZ-33
1095.96
1098.96
May 2011
46.48
1052.48
52
1044.0
62
1034.0
40
60
3.00
Transition Zone
Abandonded 3/5/2014
PZ-34
1082.46
1085.46
May 2011
35.29
1050.17
bne
< 1019
63
1019.5
27
47
3.00
Saprolite
PZ-37
1117.93
1120.77
May 2011
57.08
1063.69
25
1092.9
80
1037.9
60
80
2.83
Bedrock
Abandonded 3/6/2014
PZ-40
1074.92
1076.82
18-Dec-2015
Dry
Dry
25
1049.9
62
1012.9
32
62
1.90
Bedrock
Abandoned Feb. 2018
PZ-41
1074.35
1076.43
16-Dec-2015
47.26
1029.17
bne
< 1014.4
60
1014.4
40
60
2.08
Saprolite
Abandoned Feb. 2018
PZ-42
1066.60
1068.04
17-Dec-2015
31.11
1036.93
30
1036.6
54
1012.6
34
54
1.44
Bedrock
Abandoned Feb. 2018
Notes: GS = Ground Surface. GW = Groundwater Level (Red - Measured on 1/11/2016; Blue - Measured 5/16-17/2011) .
TOC = Top of Casing. na = Data not available, or not applicable.
TD = Total drilled depth of boring. AR (BR) = Auger Refusal (Interpreted as Bedrock Surface). Ft.-BGS = Feet below ground surface
bne = bedrock (auger refusal) not encountered above TD. Ft.-AMSL = Feet above mean sea level.
NLE = No Longer Existent. (Not found in recent investigations, presumed destroyed.)
# MW-38 has two screen sections (40-50' & 60-70') with solid riser between, but sandpack covered whole interval (38-70').
Pink shaded well = Curent background well for the whole facility.
Blue shaded wells = Current compliance wells for closed C&D-over-MSW landfill.
Yellow shaded wells = Current compliance wells for C&D Expansion landfill (Phases 1A, 2A, & 4).
Green shaded wells = Corrective Action Performance or Sentinel Wells (MW-38 is also a compliance well for the C&D Expansion landfill)
Johns River Landfill, Permit #12-03 Page 2 of 2 La Bella Associates
Burke County, NC

Appendix B
Field Data Logs and Laboratory Analytical Reports

DATE: � `� 2-3� LaBelLa
Powe e,d by p, ,;p, GROUND WATER SAMPLING LOG
Project Name: I kI " - Ptj 40, Project No. /Task No.:
Well ID: PAW - V Sampler(s): �-
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
2 inches
1-6, 3S— feet
o� ,l feet
10 • lb I feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 = oC gallons
For 4" Well: WCT X 0.653 = gallons
For THREE Well Volumes: WV X 3 gallons
Actual Amount Purged/Bailed: gallons
Purged with: 9ail r Pump Other:
Sampled with: Bai er Pump
j Other:
Depth to Water before ampling: �J' `7 feet
Gallons
Time
Temp
(OC)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
o
131�
10.s-
s11D
P10
IIOS
1 �'S
&
-2-
1,320
10'(0
1 yl
In1-b
19v
13
0101
R<
S,
S
p<Ol
Iq2
Sb
Date of sample:
(( J
Before
Sampling:
�/r�
I�I�1
I�j.Na
�b•
3.V(
�' !T"l� I
Comments (weather conditions, odor, color, silt, etc.):W
Signature:
QA/QC Sign Off: �/3- (Aic G vr— Date: 13l Z3

0. LaBeLla
Project Name:
Location:
Project No.:
John's River Fall GW Event
Morganton, NC
12 D Oak Branch Rd
Greensboro, NC 27407 Sampled By: Donovant, Staton
Telephone: [phone]
Facsimile: [phone] Date: 1 1/6/2023
WELL I.D.: MW-11 Weather:
WELL SAMPLING INFORMATION
Well Diameter: 2"
Depth of Well: 44.20
Measuring Point: TOC
Pump Type: Mega -Monsoon
FIELD PARAMETER MF.ACiTRF.MF.NT
Static Water Level:
Length of Well Screen:
Depth to Top of Pump:
Tubing Type:
36.78
42
Single -poly
Time
Pump Rate
Gallons
Purged
pH
Temp
°C(MS/CM)
Conductivity
Turbidity
TU)
Dissolved 02
((mg/I
Redox
mV
Depth to
Water
(ft)
Alkalinity
Iron (II)
Comments
+/- 0.1
+/- 3%
10
+ 10%
+/- 10 mV
1334
0
11.06
20.02
876
43.2
4.20
-211.2
36.97
1339
10.91
18.49
782
31.1
1.61
-218.1
36.88
1344
0.5
10.91
18.62
783
24.0
1.39
-218.8
36.88
1349
10.96
18.26
767
19.7
1.33
-232.9
37.01
1352
200
1.2
10.97
18.27
750
9.18
1.07
-238.3
37.04
5
Purge Time
Start:
OBSERVATIONS
Notes:
Total 1.2 Gallons Purged
1333 Purge Time End: 1443
Sampled 31 (3 PFAS) @ 1352
Final Static Water Level: 37.04
i'L � 0/ 73

0= LaBella
12 D Oak Branch Rd
Greensboro, NC 27407
Telephone: [phone]
Facsimile: [phone]
WELL I.D.: MW-12
WELL SAMPLING INFORMATION
Well Diameter: 2"
Depth of Well: 53.00
Measuring Point: TOC
Pump Type: Mega -Monsoon
FIELD PARAMETER MF,ARITRF,MF.NT
Project Name:
Location:
Project No.:
Sampled By:
Date:
Weather:
John's River Fall GW Event
Morganton, NC
Donovant, Staton
11/6/2023
Static Water Level:
Length of Well Screen:
Depth to Top of Pump:
Tubing Type:
41.59
51
Single -
Time
Pump Rate
Gallons
Purged
pH
Temp
°C(MS/cm)
Conductivity
Turbidity
TU)
Dissolved 02
(m /L
Redox
mV
Depth to
Water
(ft)
Alkalinity
Iron (II)
Comments
+/- 0.1
+/- 3%
10
+ 10%
+/- 10 mV
1502
0
10.69
19.75
356
28.2
1.42
-193
41.80
1507
10.65
17.57
344
69.2
0.20
-265
41.78
1512
1
10.67
17.18
323
204
0.61
-282.5
41.86
1517
10.73
17.25
300
211
0.59
-291.7
41.86
1522
10.76
17.54
293
101.9
0.64
-297.5
41.77
1527
2
10.79
17.36
288
59.1
0.11
-301.7
41.78
1532
10.81
17.38
283
34.7
0.22
-304.4
41.76
1537
10.80
17.59
281
18.9
0.53
-300.6
41.75
1542
10.79
17.71
282
14.5
0.51
-297.4
41.72
1549
210
3
10.81
17.83
282
14.9
0.53
-302.2
41.72
3.5
Purge Time
Start:
OBSERVATIONS
Notes:
I ULM �5 uauons rurgea
1500 Purge Time End: 1624
Sampled 31
Fe 3. S
Final Static Water Level: 41.72

DATE: J
LaBetLa
p45:'er�ci h GROUND WATER SAMPLING LOG
Project Name: t1yl��]S r)� V{'&&& Project No. /Task No.:
Well ID: Jam! Samplers: TPw,
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well:
For 4" Well:
WCT X 0.163
WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled witt
2 inches
�feet
feet
feet [DTB-DTW]
gallons
gallons
5gallons
.5 gallons
Depth to Water before Sampling: qq,--K feet
Gallons
Time
Temp
(0C)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
13y
1--T b
SJ
5D.1
5.2a
15�
`�
&
,-S-
j �. �1
I ,'�-
S43
S?o,
2-, 0
n 3
5-1-;?_%
5-1 q
09, V%29
18/ 0
)-70.1 o
l
6q o
Date of sample:
11 a
re
Sam �in
pg:
I
q-�
S2,
705
I-T3
Comments (weather conditions, odor, color, silt, etc.):. ��� Saii ny
a
Signature:
QA/QC Sign
Date: III 131 Z3

I? LaE eLLa
DATE: 11/7/2023
GROUND WATER SAMPLING LOG
Project Name: John's River GW Event Project No. /Task No.: 2233479/02
Well ID: MW-15S Sampler(s): Donovant, Staton
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled witt
Depth to Water before Sampling:
2
inches
45.58
feet
58.27
feet
12.64
feet [DTB-DTW]
2.07 gallons
— gallons
6.20 gallons
6.20 gallons
feet
Gallons
Time
Temp
(°C)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
0
1531
17.71
10.34
104
5.15
-242
4.66
PD
2.07
1534
16.93
10.16
70
4.29
-242
8.79
PD
4.14
1537
16.86
10.20
67
3.14
-250
7.35
PD
6.20
1542
17.08
10.08
64
4.44
-232
3.92
PD
Date of sample:
Sampled Immediately
Before
Sampling:
Comments (weather conditions, odor, color, silt, etc.): sampled 9 @ 1542
/ /7 f" _ " ., _ ,
Signature s ,, Date: 11 9 2023
QA/QC Si Off:�&
Date: /e.� a

0. LaBella
Project Name
Location:
Project No
John's River Fall GW Event
Morganton, NC
12 D Oak Branch Rd
Greensboro, NC 27407 Sampled By: Donovant, Staton
Telephone: [phone]
Facsimile: [phone] Date: 1 1/7/2023
WELL I.D.: MW-16S Weather:
WELL SAMPLING INFORMATION
Well Diameter: 2"
Depth of Well: 21.45
Measuring Point: TOC
Pump Type: Mega -Monsoon
FIELDPARAMF.TF.R MF.A.R1WF.XTP1VT
Static Water Level:
Length of Well Screen:
Depth to Top of Pump:
Tubing Type:
16.61
19
Single -poly
Time
Pump Rate
Gallons
Purged
pH
Temp
°C
Conductivity
mS/cm)
Turbidity
(NTU)
Dissolved 02
(m L
Redox
mV
Depth to
Water
(ft)
Alkalinity
Iron (1I)
Comments
+/- 0.1
+/- 3%
10
+ 10%
+/- 10 mV
1318
0
10.03
21.36
278
121
7.08
-162
17.29
1323
10.26
18.65
263
35.6
3.39
-218
17.09
1328
10.28
18.46
256
14.6
2.57
-239
17.16
1333
1.5
10.36
18.25
252
8.77
2.15
-249
17.22
2
Purge Time
Start:
OBSERVATIONS
Notes:
Sampled 31
1315 Purge Time End: 1410
Final Static Water Level: 17.22
o%�.avz� 1Z/13�L3

LaBella
Project Name
Location:
12 D Oak Branch Rd
Greensboro, NC 27407
Project No.:
Sampled By:
Telephone: [phone]
Facsimile: [phone]
Date:
WELL I.D.: MW-18 Weather:
WELL SAMPLING INFORMATION
John's River Fall GW Event
Morganton, NC
Donovant, Staton
11 /7/2023
ZIl
Well Diameter:
2"
Depth of Well:
12.0
Measuring Point:
TOC
Pump Type:
Mega -Monsoon
FIELD PARAMETER MF.ARTTREMIRNT
Static Water Level:
Length of Well Screen:
Depth to Top of Pump:
Tubing Type:
6.96
10
Single -poly
Time
Pump Rate
Gallons
Purged
pH
Temp
°C
Conductivity
mS/cm)
Turbidity
(NTU)
Dissolved 02
(m /L
Redox
mV
Depth to
Water
(ft)
Alkalinity
Iron (II)
Comments
+/- 0.1
+/- 3%
10
+ 10%
+/- 10 mV
0914
0
10.90
14.78
353
896
7.03
-277
7.93
0919
10.99
15.14
391
546
4.80
-297
8.03
0924
11.00
15.61
347
>1000
6.48
-306
8.42
0929
0.75
11.01
15.63
313
>1000
4.43
-308
8.68
0934
1
11.00
15.84
308
>1000
3.74
-309
8.81
0939
10.99
15.94
305
>1000
3.92
-308
8.63
0944
10.99
15.96
296
>1000
4.13
-308
8.65
0949
1.5
10.98
16.05
291
887
4.20
-308
8.62
0954
1
10.98
16.15
293
641
3.94
-309
8.60
0959
1.75
10.98
16.31
295
309
3.88
-309
8.60
1004
10.96
16.47
298
254
3.43
-309
8.55
1009
2
10.96
16.56
300
215
3.02
-308
8.60
1014
100
2.2
10.94
16.91
305
187
3.61
-308
8.63
2.5
. .0 vauv113 ru,rru
Purge Time 0911 Purge Time End: 1046 Final Static Water Level: 8.63
Start:
OBSERVATIONS
Notes:
Sampled 19 @ 1014
�21�12.3

�LaBella
�
Project Name:
Location:
12 D Oak Branch Rd
Greensboro, NC 27407
Project No.:
Sampled By:
Telephone: [phone]
Facsimile: [phone]
Date:
WELL I.D.: MW-19 Weather:
John's River Fall GW Event
Morganton, NC
Staton
11 /7/2023
If &©�s
WELL SAMPLING INFORMATION
Well Diameter: 2"
Depth of Well: 14.77 FV
Measuring Point: TOC
Pump Type: Mega -Monsoon
FIELD PARAMF.TF.R MF.ACiTRF.MF.NT
Static Water Level:
Length of Well Screen:
Depth to Top of Pump:
Tubing Type:
8.3
13
Single -poly
Time
Pump Rate
Gallons
Purged
pH
Temp
°C(MS/CM)
Conductivity
Turbidity
TU)
Dissolved 02
(m /L
Redox
mV
Depth to
Water
(ft)
Alkalinity
Iron (II)
Comments
+/- 0.1
+/- 3%
10
+ 10%
+/- 10 mV
1110
0
10.92
18.32
445
228
4.97
-236
8.42
1115
10.77
17.13
440
233
5.41
-249
8.42
1120
10.71
17.34
413
214
4.75
-241
8.45
1125
10.75
16.89
342
103
2.20
-251
8.43
1130
1.5
10.77
16.85
332
56.5
1.67
-260
8.46
1135
2.5
10.76
16.77
326
28.2
1.56
-258
8.47
1140
3
10.73
17.11
325
20.7
1.90
-257
8.44
1145
10.76
17.01
322
14.1
1.11
-265
8.45
1150
4
10.80
16.97
319
12.2
1.06
-273
8.44
1155
1 395
4.5
10.81
16.79
314
8.71
1.45
-275
8.44
2
Purge Time
Start:
OBSERVATIONS
Notes:
i ULM J %iauuus rurgeu
1108 Purge Time End: 1224
Sampled 19 @ 1155
ky;. 2
Final Static Water Level: 8.44

rl, LaBeLLa
DATE: 11/8/2023
t,;.GROUND WATER SAMPLING LOG
Project Name: John's River GW Event Project No. /Task No.:
2233479/02
Well ID: MW-20 Sampler(s):
Donovant,
Staton
Well Location:
Well Diameter:
2
inches
Initial Depth to Water (DTW):
62.03
feet
Depth to Bottom (DTB):
67.00
feet
Water Column Thickness (WCT):
4.97
feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 =
0.81
gallons
For 4" Well: WCT X 0.653 =
—
gallons
For THREE Well Volumes: WV X 3 =
2.43
gallons
Actual Amount Purged/Bailed:
2
gallons
Purged with: Bailer PUMD Other:
Sampled with: Bailer Pump Other:
Depth to Water before Sampling: 61.90
feet
Gallons
Time
Temp
(°C)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
0
0939
16.54
10.80
23
13.63
-150
50.8
PD
0.81
0941
16.31
10.65
17
10.72
-142
37.7
PD
1.62
0943
16.11
10.57
15
9.53
-135
184
PD
2.43
Dry @ 2 gal
Date of sample:
11/8/2023
Before
Sampling:
1309
18.76
10.70
23
12.24
-99.4
189
PD
Comments (weather conditions, odor, color, silt, etc.): sampled 13 @ 1309
Signature:
QA/QC Sig

LaBella
Project Name:
Location:
12 D Oak Branch Rd
Greensboro, NC 27407
Project No.:
Sampled By:
Telephone: [phone]
Facsimile: [phone]
Date:
WELL I.D.: MW-21 Weather:
WELL SAMPLING INFORMATION
John's River Fall GW Event
Morganton, NC
Donovant, Staton
11 /6/2023
Well Diameter:
2"
Depth of Well:
46.80
Measuring Point:
TOC
Pump Type:
Mega -Monsoon
FIELD PARAMF.TF.R M11?ACiTRF.MFNT
Static Water Level:
Length of Well Screen:
Depth to Top of Pump:
Tubing Type:
38.35
45
Single -poly
Time
Pump Rate
Gallons
Purged
pH
Temp
°C
Conductivity
mS/cm)
Turbidity
(NTU)
Dissolved 02
(m /L
Redox
mV
Depth to
Water
(ft)
Alkalinity
Iron (1I)
Comments
+/- 0.1
+/- 3%
10
+ 10%
+/- 10 mV
1116
0
11.10
16.01
17
122
10.13
-56.1
38.78
1121
10.89
15.85
17
138
9.77
-36.2
38.86
1126
10.96
16.22
13
117
9.63
-45.3
38.96
1131
0.5
10.98
16.54
12
78.2
11.90
-41.7
39.10
1136
1.1
10.98
16.96
12
50.0
9.85
-33.5
39.14
1141
11.00
16.97
12
39.9
9.73
-30.6
39.20
1146
1.7
10.98
17.36
12
23.1
9.13
-26.7
39.19
1151
10.96
17.83
12
19.5
9.04
-24.2
39.14
1156
10.98
17.58
11
12.6
9.83
-22.9
1 39.17
1159
10.96
17.86
11
10.79
7.25
-22.1
39.19
1202
2.25
10.96
18.02
11
9.45
6.80
-21.4
39.14
0
Purge Time
Start:
OBSERVATIONS
Notes:
iULM 1.1i "utions rurgea
1115 Purge Time End: 1253
Sampled 31 (3 PFAS) @ 1202
k En, � A � /A �/-; 2-3
Final Static Water Level: 39.14
�vl�3l�

GROUND WATER SAMPLING LOG
Project Name: John's River GW Event Project No. /Task No.: 2233479/02
Well ID: MW-23S Sampler(s):_ Donovant, Staton
Well Location:
Well Diameter: 2 inches
Initial Depth to Water (DTW): 12.25 feet
Depth to Bottom (DTB): 20.00 feet
Water Column Thickness (WCT): 7.75 feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 =
For 4" Well: WCT X 0.653 =
For THREE Well Volumes: WV X 3 =
Actual Amount Purged/Bailed:
Purged with:
Sampled witt
Depth to Water before Sampling: 12.52 feet
1.26 gallons
- gallons
3.79 gallons
3.79 gallons
Gallons
Time
Temp
(OC)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
0
1139
17.79
10.43
31
4.63
-134.7
710
PD
1.26
1142
17.10
10.36
26
5.41
-130.8
549
PD
2.52
1144
16.73
10.37
24
4.65
-131.2
326
PD
3.79
1146
16.56
10.43
12
5.31
-127.6
959
PD
Date of sample:
11/8/2023
Before
Sampling:
1412
17.77
10.42
21
8.02
-114.1
169
PD
Comments (weather conditions, odor, color, silt, etc.): sampled 13 @ 1412
Signature:
QA/QC Sig

DATE: 11/8/2023
0 LaBeLLa
,� I., j- Vd t GROUNDWATER SAMPLING LOG
Project Name: John's River GW Event Project No. /Task No.: 2233479/02
Well ID: MW-30 Sampler(s): Donovant, Staton
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled wit[
Depth to Water before Sampling: 30.08 feet
2
inches
30.08
feet
50.00
feet
19.92
feet [DTB-DTW]
3.25 gallons
- gallons
9.74 gallons
9.74 gallons
Gallons
Time
Temp
(°C)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
0
1227
16.86
10.40
56
12.40
-122.4
>1000
PD
3.25
1232
15.61
10.67
49
9.79
-121.1
547
PD
6.50
1237
15.71
10.44
40
9.44
-117.9
321
PD
9.74
1241
15.50
10.70
37
8.98
-119.0
548
PD
Date of sample:
11/8/2023
Before
Sampling:
1442
17.88
10.23
46
9.14
-74.3
132
PD
Comments (weather conditions, odor, color, silt, etc.): sampled 13 @ 1442
Signature ' Date:_11/8/2023
QA/QC Sig�ff. Date: ��

DATE: 11/8/2023
0 LaBeLLa
GROUND WATER SAMPLING LOG
Project Name: John's River GW Event Project No. /Task No.: 2233479/02
Well ID: MW-35 Sampler(s): Donovant, Staton
Well Location:
Well Diameter: 2 inches
Initial Depth to Water (DTW): 26.37 feet
Depth to Bottom (DTB): 39.05 feet
Water Column Thickness (WCT): 12.68 feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 =
For 4" Well: WCT X 0.653 =
For THREE Well Volumes: WV X 3 =
Actual Amount Purged/Bailed:
Purged with:
Sampled witt
Depth to Water before Sampling: 26.35 feet
2.07 gallons
- gallons
6.21 gallons
6.21 gallons
Gallons
Time
Temp
(°C)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
0
1115
17.44
10.47
26
5.02
-132.3
63.4
PD
2.07
1119
16.54
10.41
23
5.27
-132.8
>1000
PD
4.14
1123
16.39
10.44
24
6.08
-132.0
>1000
PD
6.21
1127
16.43
10.51
25
5.47
-131.6
794
PD
Date of sample:
11/8/2023
Before
Sampling:
1355
18.10
10.39
27
12.24
-96.4
102.9
PD
Comments (weather conditions, odor, color, silt, etc.): sampled 13 @ 1355
Signature �W�u�ate: 11 8 2023
QA/QC Si Off:
0,:, LaBeLLa DATE: 11/8/2023

P, LaBeLta
DATE: 11/7/2023
GROUND WATER SAMPLING LOG
Project Name: John's River GW Event Project No. /Task No.:
2233479/02
Well ID: MW-36 Sampler(s):
Donovant, Staton
Well Location:
Well Diameter:
2
inches
Initial Depth to Water (DTW):
34.03
feet
Depth to Bottom (DTB):
45.58
feet
Water Column Thickness (WCT):
11.55
feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 =
1.88
gallons
For 4" Well: WCT X 0.653 =
—
gallons
For THREE Well Volumes: WV X 3 =
5.64
gallons
Actual Amount Purged/Bailed:
4.5
gallons
Purged with: _ Bailer Pump Other:
Sampled with: Bailer Pump Other:
Depth to Water before Sampling: 33.92
feet
Gallons
Time
Temp
(°C)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
0
1708
17.02
10.62
243
1.92
-224.4
4.79
PD
1.88
1712
15.93
10.61
243
3.04
-237.7
14.2
PD
3.76
1716
15.65
10.62
249
3.55
-241.5
,14:2'
PD
Dry @4.5gal
Date of sample:
11/8/2023
Before
Sampling:
0912
15.84
10.64
237
9.02
-141.8
7.06
PD
Commen s (weather conditions, odor, color, silt, etc.): sampled 10 @ 0912
� 5 rv//-
Signature- M1�"» "date: 11/9 2023
QA/QC Sign Off: Date: /9L

LaBeLLa DATE: 11/7/2023
GROUND WATER SAMPLING LOG
Project Name: John's River GW Event Project No. /Task No.: 2233479/02
Well ID: MW-38 Sampler(s): Donovant, Staton
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
2
inches
44.56
feet
74.50
feet
30.94
feet [DTB-DTW]
5.04 gallons
For 4" Well: WCT X 0.653 = - gallons
For THREE Well Volumes: WV X 3 = 15.12 gallons
Actual Amount Purged/Bailed: 15.12 gallons
Purged with: Bailer Pum Other:
Sampled with: Bailer Pump Other:
Depth to Water before Sampling: 45.44 feet
Gallons
Time
Temp
(°C)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg,/L)
ORP
(mV)
Turb.
(NTU)
Initials
0
1616
21.54
10.22
538
6.96
-232
3.50
PD
5.04
1621
17.09
10.69
622
2.86
-266
17.3
PD
10.08
1626
16.58
10.66
682
3.05
-278
4.00
PD
15.12
1631
16.44
10.73
702
3.84
-286
48.8
PD
Date of sample:
11/8/2023
Before
Sampling:
0849
16.05
10.83
500
10.02
-182
8.86
PD
Comments (weather conditions, odor, color, silt, etc.): sampled 19 @ 0849
.- - I
Signature
QA/QC Sign Off:

LaBeLta DATE:11/8/2023
GROUND WATER SAMPLING LOG
Project Name: John's River GW Event Project No. /Task No.: 2233479/02
Well ID: PZ-12 Sampler(s): Donovant, Staton
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled witt
Depth to Water before Sampling: 8.16 feet
2
inches
8.16
feet
14.90
feet
6.74
feet [DTB-DTW]
1.10 gallons
— gallons
3.30 gallons
1.4 gallons
Gallons
Time
Temp
(OC)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
0
1207
17.00
10.68
38
8.17
-135.7
40.4
PD
1.10
1209
16.19
10.60
29
7.07
-133.4
146
PD
2.20
Dry @ 1.4 gal
3.30
Date of sample:
11/8/2023
Before
Sampling:
1427
17.30
10.18
27
9.58
-95.5
55.1
PD
Comments (weather conditions, odor, color, silt, etc.):_ sampled 12 @ 1427
Signature
QA/QC S

LaBeRa DATE: 11/8/2023
GROUND WATER SAMPLING LOG
Project Name: John's River GW Event Project No. /Task No.:2233479/02
Well ID: PZ-30S Sampler(s): Donovant, Staton
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled wit
Depth to Water before Sampling: 42.90 feet
2
inches
42.93
feet
55.30
feet
12.37
feet [DTB-DTW]
2.02 gallons
— gallons
= 6.05 gallons
5 gallons
Gallons
Time
Temp
(OC)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
0
1035
20.31
10.41
53
6.15
-137
31.0
PD
2.02
1038
19.49
10.44
45
3.92
-138
16.8
PD
4.03
1042
19.42
10.44
46
3.30
-140
99.1
PD
6.05
Dry @ 5 gal
Date of sample:
11/8/2023
Before
Sampling:
1341
21.26
10.16
45
6.02
-102.3
18.3
PD
Comments (weather conditions, odor, color, silt, etc.): sampled 13 @ 1341
Signatur Date: 11/9/2023
QA/QC Si Off: Date: ����

LaBeLLa DATE: 11/8/2023
_,,:. GROUND WATER SAMPLING LOG
Project Name: John's River GW Event Project No. /Task No.: 2233479 02
Well ID: PZ-31 Sampler(s): Donovant, Staton
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT)
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled witt
Depth to Water before Sampling: 30.18 feet
2
inches
30.20
feet
45.60
feet
15.40
feet [DTB-DTW]
2.51 gallons
_ - gallons
= 7.53 gallons
7.53 gallons
Gallons
Time
Temp
(OC)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
0
1003
17.67
10.46
27
9.17
-120.5
12.8
PD
2.51
1010
16.68
10.36
25
8.44
-119.0
39.8
PD
5.02
1014
16.17
10.41
25
7.56
-118.4
53.3
PD
7.53
1020
16.35
10.68
62
5.22
-138.4
17.2
PD
Date of sample:
11/8/2023
Before
Sampling:
1325
19.15
10.10
29
15.04
-79.6
16.2
PD
Comments (weather conditions, odor, color, silt, etc.): sampled 12 @ 1325
SignaturE
QA/QC Si
Date:0-/

DATE: I ( 3
LaBetta
I—J LEACHATE MONITORING LOG
Project Name: Gil S IIU Project/Task No.:
Sample Point ID: SH P 5 Sampler(s):
Location: W halw) -to
Field Parameters:
Time of Sampling:
pH:
Temperature:
Conductivity:
Turbidity:
Dissolved Oxygen
Oxidation -Reduction Potential
(0C)
(US/CM)
(ntu)
(mg/L)
(mv)
Comments/Sample Description (weather conditions, odor, color, silt, etc.):
Summary/Sketch of Sa ling Location
Sip-S"
Signature: Date:T�/�`.�?
QA/QC Sign Off Date: m l3( 7i-3

DATE:J 11 k 2
LaBetta
LEACHATE MONITORING LOG
Project Name: 30 i S h i V6iAL b4j&Z Project/Task No.:
Sample Point ID: S LA E—_bSampler(s): P)) hs
Location:- Pig
Field Parameters:
Time of Sampling:
pH:
Temperature:
Conductivity:
Turbidity:
Dissolved Oxygen
Oxidation -Reduction Potential
11, 2_g
Iw-�z (0C)
141 (US/cm)
S� (ntu)
(mv)
Comments/Sample Description (weather conditions, odor, color, silt, etc.):
Y 0 'J !�:
M.
X
Summary/Sketch o/f/Sammpling Location p
Signature: I Date: 12-
QA/QC Sign Off: Date:

L—: LaBetta
DATE: 4 Gs Z
P"ve'e'c, — LEACHATE MONITORING LOG
Project Name: I' . JD Va Project/Task No.:
Sample Point ID:_ g,P Sampler(s):
Location: Wff__hY'Yrw;m �31�!/� P-27-1Z
Field Parameters:
Time of Sampling:
pH:
Temperature:
Conductivity:
Turbidity:
Dissolved Oxygen
Oxidation -Reduction Potential
(°C)
(US/cm)
(ntu)
(mg/L)
(mv)
Comments/Sample Description (weather conditions, odor, color, silt, etc.):
4_:_
Summary/Sketch of Sampling Location
1�
Signature: I Date: �co-
QA/QC Sign Date: t2/ l31 23

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
November 28, 2023
Mr. Van Burbach
LaBella Associates, D.P.C.
12-D Oak Branch Drive
Greensboro, NC 27407
RE: Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory between November 07, 2023 and November
10, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable
TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the
report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace National - Mt. Juliet
• Pace Analytical Services - Asheville
• Pace Analytical Services - Baton Rouge
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Eden
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor M Cannon
[e-mail]
704-977-0943
Project Manager
Enclosures
cc: Van Burbach, LaBella Associates, DPC
Kandice Estes. Labella Associates
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 90

Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Pace Analytical Services National
12065 Lebanon Road, Mt. Juliet, TN 37122
Alabama Certification #: 40660
Alaska Certification 17-026
Arizona Certification #: AZ0612
Arkansas Certification #: 88-0469
California Certification #: 2932
Canada Certification #: 1461.01
Colorado Certification #: TN00003
Connecticut Certification #: PH-0197
DOD Certification: #1461.01
EPA# TN00003
Florida Certification #: E87487
Georgia DW Certification #: 923
Georgia Certification: NELAP
Idaho Certification #: TN00003
Illinois Certification #: 200008
Indiana Certification #: C-TN-01
Iowa Certification #: 364
Kansas Certification #: E-10277
Kentucky UST Certification #: 16
Kentucky Certification #: 90010
Louisiana Certification #: A130792
Louisiana DW Certification #: LA180010
Maine Certification #: TN0002
Maryland Certification #: 324
Massachusetts Certification #: M-TNO03
Michigan Certification #: 9958
Minnesota Certification #: 047-999-395
Mississippi Certification #: TN00003
Missouri Certification #: 340
Montana Certification M CERT0086
Nebraska Certification #: NE-OS-15-05
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
Pace Analytical Services Eden
205 East Meadow Road Suite A, Eden, NC 27288
North Carolina Drinking Water Certification #: 37738
CERTIFICATIONS
Nevada Certification #: TN-03-2002-34
New Hampshire Certification #: 2975
New Jersey Certification #: TNO02
New Mexico DW Certification
New York Certification #: 11742
North Carolina Aquatic Toxicity Certification #: 41
North Carolina Drinking Water Certification #: 21704
North Carolina Environmental Certificate #: 375
North Dakota Certification #: R-140
Ohio VAP Certification #: CL0069
Oklahoma Certification #: 9915
Oregon Certification #: TN200002
Pennsylvania Certification #: 68-02979
Rhode Island Certification #: LA000356
South Carolina Certification #: 84004
South Dakota Certification
Tennessee DW/Chem/Micro Certification #: 2006
Texas Certification #: T 104704245-17-14
Texas Mold Certification #: LAB0152
USDA Soil Permit #: P330-15-00234
Utah Certification #: TN00003
Virginia Certification #: VT2006
Vermont Dept. of Health: ID# VT-2006
Virginia Certification #: 460132
Washington Certification #: C847
West Virginia Certification #: 233
Wisconsin Certification #: 998093910
Wyoming UST Certification #: via A21-A 2926.01
A21-A-ISO 17025 Certification #: 1461.01
A21-A-ISO 17025 Certification #: 1461.02
AIHA-LAP/LLC EMLAP Certification #:100789
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification #: 633
Virginia/VELAP Certification #: 460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Pace Analytical Services Baton Rouge
7979 Innovation Park Drive Ste A, Baton Rouge, LA
70820-7402
Louisiana Dept of Enviromental Quality (NELAC/LELAP):
01979
Florida Dept of Health (NELAC/FELAP): E87854
DoD ELAP (A2LA) #: 6429.01
Alabama DEM #: 41900
Alaska DEC-DW #: LA00024
Alaska DEC CS -LAP #: 21-001
Arkansas DEQ #: 88-0655
California ELAP #: 3063
Georgia DPD M C050
Hawaii DOH State Laboratories Division
Illinois EPA#: 200048
Kansas DoHE #: E-10354
Kentucky DEP UST Branch #: 123054
Louisiana DOH #: LA036
Minnesota DOH #: 2233799
Mississippi State Dept of Health
CERTIFICATIONS
Montana Department of Environmental Quality
Nebraska DHHS #: NE-OS-35.21
Nevada DCNR DEP #: LA00024
New York DOH M 12149
North Carolina DEQ - WW & GW #: 618
North Dakota DEQ #: R195
Ohio EPA#: 87782
Oklahoma Dept of Environmental Quality #: 9403
Oregon ELAP #: 4168
Pennsylvania Dept of Environmental Protection #: 68-
05973
South Carolina DHEC #: 73006001
Texas CEQ #: T104704178-23-15
Utah DOH M LA00024
Virginia DCLS #: 6460215
Washington Dept of Ecology #: C929
Wisconsin DNR #: 399139510
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92697340001
1203-MW21
Water
11/06/23 12:02
11/07/23 17:05
92697340002
Trip Blank
Water
11/06/23 08:00
11/07/23 17:05
92697337005
1203-MW-21
Water
11/06/23 12:02
11/07/23 17:05
92697351001
1203-MW-21
Water
11/06/23 12:02
11/07/23 17:05
92698166001
1203-FIELD BLANK
Water
11/08/23 14:56
11/10/23 09:45
92697345001
1203-SMP6
Water
11/06/2317:22
11/07/23 17:05
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 90

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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
92697340001
1203-MW21
EPA 8151
RDH
5
PAN
EPA 8081 B
SEM
21
PASI-C
EPA 8082A
SEM
8
PASI-C
EPA 6010D
DBB1
17
PASI-A
EPA 6020E
KRL
1
PASI-A
EPA 7470A
BM
1
PASI-A
EPA 8270E
PKS
112
PASI-C
EPA 8260D
LMB
62
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 2540C-2015
JAY
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
2
PASI-A
SM 4500-CN-E-2016
MMA
1
PASI-A
92697340002
Trip Blank
EPA 8260D
LMB
62
PASI-C
92697337005
1203-MW-21
EPA 353.2 Rev 2.0 1993
SRS
1
PASI-E
RSK 175 Modified
TEG
1
PASI-C
SM 5310B-2014
MJP
1
PASI-A
92697351001
1203-MW-21
AM20
LB
1
PASI-BR
92698166001
1203-FIELD BLANK
EPA 8081B
SEM
21
PASI-C
EPA 8082A
SEM
8
PASI-C
EPA 6010D
DBB1, SBW
17
PASI-A
EPA 6020E
CRW
1
PASI-A
EPA 7470A
BM
1
PASI-A
EPA 8270E
PKS
112
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
2
PASI-A
SM 4500-CN-E-2016
EGC
1
PASI-A
92697345001
1203-SMP6
EPA 6010D
DBB1
17
PASI-A
EPA 6020E
KRL
1
PASI-A
EPA 7470A
BM
1
PASI-A
EPA 8260D
JJK
51
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
SM 4500-CN-E-2016
EGC
1
PASI-A
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
PAN = Pace National - Mt. Juliet
PASI-A = Pace Analytical Services - Asheville
PASI-BR = Pace Analytical Services - Baton Rouge
PASI-C = Pace Analytical Services - Charlotte
PASI-E = Pace Analytical Services - Eden
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 6 of 90

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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Lab Sample ID
Method
Client Sample ID
Parameters
92697340001
1203-MW21
EPA 6010D
Barium
EPA 6010D
Chromium
EPA 6010D
Cobalt
EPA 6010D
Copper
EPA 6010D
Iron
EPA 6010D
Manganese
EPA 6010D
Vanadium
92697337005
1203-MW-21
EPA 353.2 Rev 2.0 1993
Nitrogen, Nitrate
RSK 175 Modified
Methane
92697351001
1203-MW-21
AM20
Hydrogen
92698166001
1203-FIELD BLANK
EPA 6010D
Iron
92697345001
1203-SMP6
EPA 6010D
Barium
EPA 6010D
Cadmium
EPA 6010D
Iron
EPA 6010D
Manganese
EPA 6010D
Hardness, Total(SM 2340B)
EPA 6010D
Zinc
EPA 8260D
Acetone
EPA 8260D
1,1-Dichloroethane
EPA 8260D
cis-1,2-Dichloroethene
EPA 8260D
Toluene
EPA 8260D
Trichloroethene
Result
Units
Report Limit
Analyzed
26.5
ug/L
5.0
11/13/2316:58
0.98J
ug/L
5.0
11/13/2316:58
0.56J
ug/L
5.0
11/13/2316:58
1.8J
ug/L
5.0
11/13/2316:58
574
ug/L
50.0
11/13/2316:58
45.4
ug/L
5.0
11/13/2316:58
3.3J
ug/L
5.0
11/13/2316:58
0.15
mg/L
7.5J
18.8J ug/L 50.0 11/15/2312:29
66.1 ug/L 5.0 11/13/2317:06
0.31J ug/L 1.0 11/13/2317:06
44600 ug/L 50.0 11/13/2317:06
1110 ug/L 5.0 11/13/2317:06
25400 ug/L 662 11/13/2317:06
5.2J ug/L 10.0 11/13/2317:06
11.1J ug/L 25.0 11/10/2317:39
1.3 ug/L 1.0 11/10/2317:39
0.97J ug/L 1.0 11/10/2317:39
0.79J ug/L 1.0 11/10/2317:39
0.44J ug/L 1.0 11/10/2317:39
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Qualifiers
Page 7 of 90
0.040 11 /08/23 09:26
10.0 11 /09/23 17:24 B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Qualifiers
Page 7 of 90
0.040 11 /08/23 09:26
10.0 11 /09/23 17:24 B

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Sample: 1203-MW21
Lab ID:
92697340001
Collected:
11/06/23 12:02
Received: 11/07/23 17:05 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
Chlorinated Herb. (GC) 8151
Analytical
Method: EPA8151
Preparation
Method: 8151A
Pace National
- Mt. Juliet
2,4-D
ND
ug/L
2.00
0.547
1
11/13/23 11:59
11/14/23 12:42
94-75-7
2,4,5-T
ND
ug/L
2.00
0.258
1
11/13/23 11:59
11/14/23 12:42
93-76-5
2,4,5-TP (Silvex)
ND
ug/L
2.00
0.335
1
11/13/23 11:59
11/14/23 12:42
93-72-1
Dinoseb
ND
ug/L
2.00
0.250
1
11/13/23 11:59
11/14/23 12:42
88-85-7
Surrogates
2,4-DCAA (S)
66.2
%
14.0-158
1
11/13/23 11:59
11/14/23 12:42
19719-28-9
8081 OC Pesticides RVE
Analytical
Method: EPA 8081
B Preparation Method: EPA 3510C
Pace Analytical
Services
- Charlotte
Aldrin
ND
ug/L
0.042
0.012
1
11/09/23 06:34
11/10/23 16:56
309-00-2
alpha-BHC
ND
ug/L
0.042
0.010
1
11/09/23 06:34
11/10/23 16:56
319-84-6
beta-BHC
ND
ug/L
0.042
0.041
1
11/09/23 06:34
11/10/23 16:56
319-85-7
delta-BHC
ND
ug/L
0.042
0.012
1
11/09/23 06:34
11/10/23 16:56
319-86-8
gamma-BHC (Lindane)
ND
ug/L
0.042
0.010
1
11/09/23 06:34
11/10/23 16:56
58-89-9
Chlordane (Technical)
ND
ug/L
0.42
0.13
1
11/09/23 06:34
11/10/23 16:56
57-74-9
4,4'-DDD
ND
ug/L
0.042
0.014
1
11/09/23 06:34
11/10/23 16:56
72-54-8
4,4'-DDE
ND
ug/L
0.042
0.020
1
11/09/23 06:34
11/10/23 16:56
72-55-9
4,4'-DDT
ND
ug/L
0.042
0.022
1
11/09/23 06:34
11/10/23 16:56
50-29-3
Dieldrin
ND
ug/L
0.042
0.012
1
11/09/23 06:34
11/10/23 16:56
60-57-1
Endosulfan I
ND
ug/L
0.042
0.014
1
11/09/23 06:34
11/10/23 16:56
959-98-8
Endosulfan 11
ND
ug/L
0.042
0.013
1
11/09/23 06:34
11/10/23 16:56
33213-65-9
Endosulfan sulfate
ND
ug/L
0.042
0.012
1
11/09/23 06:34
11/10/23 16:56
1031-07-8
Endrin
ND
ug/L
0.042
0.015
1
11/09/23 06:34
11/10/23 16:56
72-20-8
Endrin aldehyde
ND
ug/L
0.042
0.014
1
11/09/23 06:34
11/10/23 16:56
7421-93-4
Heptachlor
ND
ug/L
0.042
0.016
1
11/09/23 06:34
11/10/23 16:56
76-44-8
Heptachlor epoxide
ND
ug/L
0.042
0.024
1
11/09/23 06:34
11/10/23 16:56
1024-57-3
Methoxychlor
ND
ug/L
0.12
0.035
1
11/09/23 06:34
11/10/23 16:56
72-43-5
Toxaphene
ND
ug/L
0.42
0.18
1
11/09/23 06:34
11/10/23 16:56
8001-35-2
Surrogates
Tetrachloro-m-xylene (S)
100
%
10-137
1
11/09/23 06:34
11/10/23 16:56
877-09-8
Decachlorobiphenyl (S)
68
%
19-200
1
11/09/23 06:34
11/10/23 16:56
2051-24-3
8082 GCS PCB RVE
Analytical
Method: EPA 8082A
Preparation Method:
EPA 3510C
Pace Analytical
Services
- Charlotte
PCB-1016 (Aroclor 1016)
ND
ug/L
0.42
0.18
1
11/13/23 13:26
11/15/23 00:39
12674-11-2
PCB-1221 (Aroclor 1221)
ND
ug/L
0.42
0.19
1
11/13/23 13:26
11/15/23 00:39
11104-28-2
PCB-1232 (Aroclor 1232)
ND
ug/L
0.42
0.19
1
11/13/23 13:26
11/15/23 00:39
11141-16-5
PCB-1242 (Aroclor 1242)
ND
ug/L
0.42
0.21
1
11/13/23 13:26
11/15/23 00:39
53469-21-9
PCB-1248 (Aroclor 1248)
ND
ug/L
0.42
0.24
1
11/13/23 13:26
11/15/23 00:39
12672-29-6
PCB-1254 (Aroclor 1254)
ND
ug/L
0.42
0.18
1
11/13/23 13:26
11/15/23 00:39
11097-69-1
PCB-1260 (Aroclor 1260)
ND
ug/L
0.42
0.13
1
11/13/23 13:26
11/15/23 00:39
11096-82-5
Surrogates
Decachlorobiphenyl (S)
127
%
10-193
1
11/13/23 13:26
11/15/23 00:39
2051-24-3
Date: 11/28/2023 12:33 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 8 of 90

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Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Sample: 1203-MW21 Lab ID: 92697340001 Collected: 11/06/23 12:02 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.6
1
11/10/2312:00
11/13/2316:58
7440-36-0
Arsenic
ND
ug/L
10.0
2.5
1
11/10/2312:00
11/13/2316:58
7440-38-2
Barium
26.5
ug/L
5.0
0.79
1
11/10/2312:00
11/13/2316:58
7440-39-3
Beryllium
ND
ug/L
1.0
0.16
1
11/10/2312:00
11/13/2316:58
7440-41-7
Cadmium
ND
ug/L
1.0
0.29
1
11/10/2312:00
11/13/2316:58
7440-43-9
Chromium
0.981
ug/L
5.0
0.63
1
11/10/2312:00
11/13/2316:58
7440-47-3
Cobalt
0.56J
ug/L
5.0
0.44
1
11/10/2312:00
11/13/2316:58
7440-48-4
Copper
1.81
ug/L
5.0
0.62
1
11/10/2312:00
11/13/2316:58
7440-50-8
Iron
574
ug/L
50.0
8.9
1
11/10/2312:00
11/13/2316:58
7439-89-6
Lead
ND
ug/L
5.0
1.4
1
11/10/2312:00
11/13/2316:58
7439-92-1
Manganese
45.4
ug/L
5.0
0.86
1
11/10/2312:00
11/13/2316:58
7439-96-5
Nickel
ND
ug/L
5.0
0.88
1
11/10/2312:00
11/13/2316:58
7440-02-0
Selenium
ND
ug/L
10.0
4.1
1
11/10/2312:00
11/13/2316:58
7782-49-2
Silver
ND
ug/L
5.0
0.49
1
11/10/2312:00
11/13/2316:58
7440-22-4
Tin
ND
ug/L
5.0
2.0
1
11/10/2312:00
11/13/2316:58
7440-31-5
Vanadium
3.3.11
ug/L
5.0
1.6
1
11/10/2312:00
11/13/2316:58
7440-62-2
Zinc
ND
ug/L
10.0
3.0
1
11/10/2312:00
11/13/2316:58
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.20
0.050
1
11/10/23 12:25
11/12/23 20:01
7440-28-0
7470 Mercury
Analytical Method: EPA 7470A Preparation Method: EPA
7470A
Pace Analytical Services -Asheville
Mercury
ND
ug/L
0.20
0.12
1
11/11/23 22:12
11/12/23 11:58
7439-97-6
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA
3510C
Pace Analytical Services - Charlotte
Acenaphthene
ND
ug/L
8.3
1.7
1
11/09/23 10:09
11/12/23 18:43
83-32-9
Acenaphthylene
ND
ug/L
8.3
1.6
1
11/09/23 10:09
11/12/23 18:43
208-96-8
Acetophenone
ND
ug/L
8.3
1.2
1
11/09/23 10:09
11/12/23 18:43
98-86-2
2-Acetylaminofluorene
ND
ug/L
8.3
3.4
1
11/09/23 10:09
11/12/23 18:43
53-96-3
4-Aminobiphenyl
ND
ug/L
8.3
4.0
1
11/09/23 10:09
11/12/23 18:43
92-67-1
Anthracene
ND
ug/L
8.3
1.9
1
11/09/23 10:09
11/12/23 18:43
120-12-7
Benzo(a)anthracene
ND
ug/L
8.3
2.2
1
11/09/23 10:09
11/12/23 18:43
56-55-3
Benzo(a)pyrene
ND
ug/L
8.3
2.3
1
11/09/23 10:09
11/12/23 18:43
50-32-8
Benzo(b)fluoranthene
ND
ug/L
8.3
2.2
1
11/09/23 10:09
11/12/23 18:43
205-99-2
Benzo(g,h,i)perylene
ND
ug/L
8.3
2.4
1
11/09/23 10:09
11/12/23 18:43
191-24-2
Benzo(k)fluoranthene
ND
ug/L
8.3
2.3
1
11/09/23 10:09
11/12/23 18:43
207-08-9
Benzyl alcohol
ND
ug/L
16.7
2.4
1
11/09/23 10:09
11/12/23 18:43
100-51-6
4-Bromophenylphenyl ether
ND
ug/L
8.3
1.5
1
11/09/23 10:09
11/12/23 18:43
101-55-3
Butylbenzylphthalate
ND
ug/L
8.3
2.6
1
11/09/23 10:09
11/12/23 18:43
85-68-7
4-ChIoro-3-methyl phenol
ND
ug/L
8.3
2.8
1
11/09/23 10:09
11/12/23 18:43
59-50-7
4-Chloroaniline
ND
ug/L
16.7
3.0
1
11/09/23 10:09
11/12/23 18:43
106-47-8
Chlorobenzilate
ND
ug/L
8.3
3.2
1
11/09/23 10:09
11/12/23 18:43
510-15-6
REPORT OF
LABORATORY ANALYSIS
This report shall not be reproduced, except in
full,
Date: 11 /28/2023 12:33 PM
without the written consent of Pace Analytical Services,
LLC.
Page 9 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Sample: 1203-MW21 Lab ID: 92697340001 Collected: 11/06/23 12:02 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
bis(2-Chloroethoxy)methane
ND
ug/L
8.3
1.5
1
11/09/23 10:09
11/12/23 18:43
111-91-1
bis(2-Chloroethyl) ether
ND
ug/L
8.3
1.6
1
11/09/23 10:09
11/12/23 18:43
111-44-4
2-Chloronaphthalene
ND
ug/L
8.3
1.4
1
11/09/23 10:09
11/12/23 18:43
91-58-7
2-Chlorophenol
ND
ug/L
8.3
1.0
1
11/09/23 10:09
11/12/23 18:43
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
8.3
1.7
1
11/09/23 10:09
11/12/23 18:43
7005-72-3
Chrysene
ND
ug/L
8.3
2.3
1
11/09/23 10:09
11/12/23 18:43
218-01-9
Diallate
ND
ug/L
8.3
2.8
1
11/09/23 10:09
11/12/23 18:43
2303-16-4
Dibenz(a,h)anthracene
ND
ug/L
8.3
2.5
1
11/09/23 10:09
11/12/23 18:43
53-70-3
Dibenzofuran
ND
ug/L
8.3
1.8
1
11/09/23 10:09
11/12/23 18:43
132-64-9
3,3'-Dichlorobenzidine
ND
ug/L
16.7
6.8
1
11/09/23 10:09
11/12/23 18:43
91-94-1
2,4-Dichlorophenol
ND
ug/L
8.3
1.2
1
11/09/23 10:09
11/12/23 18:43
120-83-2
2,6-Dichlorophenol
ND
ug/L
8.3
3.5
1
11/09/23 10:09
11/12/23 18:43
87-65-0
Diethylphthalate
ND
ug/L
8.3
1.7
1
11/09/23 10:09
11/12/23 18:43
84-66-2
Dimethoate
ND
ug/L
8.3
3.0
1
11/09/23 10:09
11/12/23 18:43
60-51-5
P-Dimethylaminoazobenzene
ND
ug/L
4.2
2.0
1
11/09/23 10:09
11/12/23 18:43
60-11-7
7,12-Dimethylbenz(a)anthracene
ND
ug/L
8.3
2.5
1
11/09/23 10:09
11/12/23 18:43
57-97-6
3,3'-Dimethylbenzidine
ND
ug/L
41.7
25.9
1
11/09/23 10:09
11/12/23 18:43
119-93-7
2,4-Dimethylphenol
ND
ug/L
8.3
1.4
1
11/09/23 10:09
11/12/23 18:43
105-67-9
Dimethylphthalate
ND
ug/L
8.3
1.8
1
11/09/23 10:09
11/12/23 18:43
131-11-3
Di-n-butylphthalate
ND
ug/L
8.3
1.8
1
11/09/23 10:09
11/12/23 18:43
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
16.7
6.5
1
11/09/23 10:09
11/12/23 18:43
534-52-1
1,3-Dinitrobenzene
ND
ug/L
8.3
3.1
1
11/09/23 10:09
11/12/23 18:43
99-65-0
2,4-Dinitrophenol
ND
ug/L
41.7
21.7
1
11/09/23 10:09
11/12/23 18:43
51-28-5
2,4-Dinitrotoluene
ND
ug/L
8.3
1.4
1
11/09/23 10:09
11/12/23 18:43
121-14-2
2,6-Dinitrotoluene
ND
ug/L
8.3
1.4
1
11/09/23 10:09
11/12/23 18:43
606-20-2
Di-n-octylphthalate
ND
ug/L
8.3
3.3
1
11/09/23 10:09
11/12/23 18:43
117-84-0
Diphenylamine
ND
ug/L
8.3
2.5
1
11/09/23 10:09
11/12/23 18:43
122-39-4
Disulfoton
ND
ug/L
8.3
3.9
1
11/09/23 10:09
11/12/23 18:43
298-04-4
bis(2- Ethyl hexyl)phthalate
ND
ug/L
5.0
3.1
1
11/09/23 10:09
11/12/23 18:43
117-81-7
Ethyl methanesulfonate
ND
ug/L
16.7
2.5
1
11/09/23 10:09
11/12/23 18:43
62-50-0
Famphur
ND
ug/L
8.3
5.1
1
11/09/23 10:09
11/12/23 18:43
52-85-7
Fluoranthene
ND
ug/L
8.3
1.8
1
11/09/23 10:09
11/12/23 18:43
206-44-0
Fluorene
ND
ug/L
8.3
1.7
1
11/09/23 10:09
11/12/23 18:43
86-73-7
Hexachloro-1,3-butadiene
ND
ug/L
8.3
1.5
1
11/09/23 10:09
11/12/23 18:43
87-68-3
Hexachlorobenzene
ND
ug/L
8.3
1.8
1
11/09/23 10:09
11/12/23 18:43
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
8.3
1.3
1
11/09/23 10:09
11/12/23 18:43
77-47-4
Hexachloroethane
ND
ug/L
8.3
1.2
1
11/09/23 10:09
11/12/23 18:43
67-72-1
Hexachloropropene
ND
ug/L
8.3
2.2
1
11/09/23 10:09
11/12/23 18:43
1888-71-7
Indeno(1,2,3-cd)pyrene
ND
ug/L
8.3
2.4
1
11/09/23 10:09
11/12/23 18:43
193-39-5
Isodrin
ND
ug/L
8.3
2.3
1
11/09/23 10:09
11/12/23 18:43
465-73-6
Isophorone
ND
ug/L
8.3
1.4
1
11/09/23 10:09
11/12/23 18:43
78-59-1
Isosafrole
ND
ug/L
8.3
2.1
1
11/09/23 10:09
11/12/23 18:43
120-58-1
Kepone
ND
ug/L
16.7
11.8
1
11/09/23 10:09
11/12/23 18:43
143-50-0
Methapyrilene
ND
ug/L
41.7
14.2
1
11/09/23 10:09
11/12/23 18:43
91-80-5
3-Methylcholanthrene
ND
ug/L
8.3
3.1
1
11/09/23 10:09
11/12/23 18:43
56-49-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Sample: 1203-MW21 Lab ID: 92697340001 Collected: 11/06/23 12:02 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Methyl methanesulfonate
ND
ug/L
4.2
2.6
1
11/09/23 10:09
11/12/23 18:43
66-27-3
2-Methylnaphthalene
ND
ug/L
8.3
1.6
1
11/09/23 10:09
11/12/23 18:43
91-57-6
Methyl parathion
ND
ug/L
8.3
3.1
1
11/09/23 10:09
11/12/23 18:43
298-00-0
2-Methylphenol(o-Cresol)
ND
ug/L
8.3
1.6
1
11/09/23 10:09
11/12/23 18:43
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
8.3
1.0
1
11/09/23 10:09
11/12/23 18:43
15831-10-4
1-Naphthalenamine
ND
ug/L
8.3
5.0
1
11/09/23 10:09
11/12/23 18:43
134-32-7
2-Naphthalenamine
ND
ug/L
8.3
4.5
1
11/09/23 10:09
11/12/23 18:43
91-59-8
1,4-Naphthoquinone
ND
ug/L
4.2
3.7
1
11/09/23 10:09
11/12/23 18:43
130-15-4
2-Nitroaniline
ND
ug/L
16.7
2.5
1
11/09/23 10:09
11/12/23 18:43
88-74-4
3-Nitroaniline
ND
ug/L
16.7
3.1
1
11/09/23 10:09
11/12/23 18:43
99-09-2
4-Nitroaniline
ND
ug/L
16.7
4.2
1
11/09/23 10:09
11/12/23 18:43
100-01-6
Nitrobenzene
ND
ug/L
8.3
1.6
1
11/09/23 10:09
11/12/23 18:43
98-95-3
2-Nitrophenol
ND
ug/L
8.3
1.2
1
11/09/23 10:09
11/12/23 18:43
88-75-5
4-Nitrophenol
ND
ug/L
41.7
5.5
1
11/09/23 10:09
11/12/23 18:43
100-02-7
5-Nitro-o-toluidine
ND
ug/L
8.3
3.2
1
11/09/23 10:09
11/12/23 18:43
99-55-8
N-Nitrosodiethylamine
ND
ug/L
8.3
1.9
1
11/09/23 10:09
11/12/23 18:43
55-18-5
N-Nitrosodimethylamine
ND
ug/L
8.3
1.6
1
11/09/23 10:09
11/12/23 18:43
62-75-9
N-Nitroso-di-n-butylamine
ND
ug/L
8.3
1.6
1
11/09/23 10:09
11/12/23 18:43
924-16-3
N-Nitroso-di-n-propylamine
ND
ug/L
8.3
1.1
1
11/09/23 10:09
11/12/23 18:43
621-64-7
N-Nitrosodiphenylamine
ND
ug/L
8.3
2.5
1
11/09/23 10:09
11/12/23 18:43
86-30-6
N-Nitrosomethylethylamine
ND
ug/L
8.3
6.2
1
11/09/23 10:09
11/12/23 18:43
10595-95-6
N-Nitrosopiperidine
ND
ug/L
8.3
2.1
1
11/09/23 10:09
11/12/23 18:43
100-75-4
N-Nitrosopyrrolidine
ND
ug/L
8.3
2.6
1
11/09/23 10:09
11/12/23 18:43
930-55-2
O,O,O-Triethylphosphorothioate
ND
ug/L
8.3
2.1
1
11/09/23 10:09
11/12/23 18:43
126-68-1
2,2'-Oxybis(1-chloropropane)
ND
ug/L
8.3
0.96
1
11/09/23 10:09
11/12/23 18:43
108-60-1
Parathion (Ethyl parathion)
ND
ug/L
8.3
3.2
1
11/09/23 10:09
11/12/23 18:43
56-38-2
Pentachlorobenzene
ND
ug/L
8.3
2.8
1
11/09/23 10:09
11/12/23 18:43
608-93-5
Pentachloronitrobenzene
ND
ug/L
8.3
2.7
1
11/09/23 10:09
11/12/23 18:43
82-68-8
Pentachlorophenol
ND
ug/L
16.7
3.1
1
11/09/23 10:09
11/12/23 18:43
87-86-5
Phenacetin
ND
ug/L
8.3
3.0
1
11/09/23 10:09
11/12/23 18:43
62-44-2
Phenanthrene
ND
ug/L
8.3
1.7
1
11/09/23 10:09
11/12/23 18:43
85-01-8
Phenol
ND
ug/L
8.3
1.1
1
11/09/23 10:09
11/12/23 18:43
108-95-2
p-Phenylenediamine
ND
ug/L
8.3
8.3
1
11/09/23 10:09
11/12/23 18:43
106-50-3
Phorate
ND
ug/L
8.3
3.0
1
11/09/23 10:09
11/12/23 18:43
298-02-2
Pronamide
ND
ug/L
8.3
2.6
1
11/09/23 10:09
11/12/23 18:43
23950-58-5
Pyrene
ND
ug/L
8.3
1.8
1
11/09/23 10:09
11/12/23 18:43
129-00-0
Safrole
ND
ug/L
8.3
1.9
1
11/09/23 10:09
11/12/23 18:43
94-59-7
1,2,4,5-Tetrachlorobenzene
ND
ug/L
8.3
3.7
1
11/09/23 10:09
11/12/23 18:43
95-94-3
2,3,4,6-Tetrachlorophenol
ND
ug/L
8.3
1.3
1
11/09/23 10:09
11/12/23 18:43
58-90-2
Thionazin
ND
ug/L
8.3
2.4
1
11/09/23 10:09
11/12/23 18:43
297-97-2
O-Toluidine
ND
ug/L
8.3
2.2
1
11/09/23 10:09
11/12/23 18:43
95-53-4
2,4,5-Trichlorophenol
ND
ug/L
8.3
1.2
1
11/09/23 10:09
11/12/23 18:43
95-95-4
2,4,6-Trichlorophenol
ND
ug/L
8.3
1.3
1
11/09/23 10:09
11/12/23 18:43
88-06-2
1,3,5-Trinitrobenzene
ND
ug/L
8.3
4.6
1
11/09/23 10:09
11/12/23 18:43
99-35-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Sample: 1203-MW21 Lab ID: 92697340001 Collected: 11/06/23 12:02 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260D MSV Low Level Landfill
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Allyl chloride
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Chloroprene
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Date: 11/28/2023 12:33 PM
86
%
10-133
1
11/09/2310:09
11/12/2318:43
4165-60-0
79
%
10-130
1
11 /09/23 10:09
11 /12/23 18:43
321-60-8
105
%
10-193
1
11 /09/23 10:09
11 /12/23 18:43
1718-51-0
41
%
10-130
1
11/09/2310:09
11/12/2318:43
13127-88-3
55
%
10-130
1
11/09/2310:09
11/12/2318:43
367-12-4
97
%
10-166
1
11/09/2310:09
11/12/2318:43
118-79-6
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
11/13/2312:10
67-64-1
ND
ug/L
50.0
24.8
1
11/13/2312:10
75-05-8
ND
ug/L
10.0
8.5
1
11/13/2312:10
107-02-8 AC
ND
ug/L
10.0
1.8
1
11/13/2312:10
107-13-1
ND
ug/L
2.0
0.50
1
11/13/2312:10
107-05-1
ND
ug/L
1.0
0.34
1
11/13/2312:10
71-43-2
ND
ug/L
1.0
0.47
1
11/13/2312:10
74-97-5
ND
ug/L
1.0
0.31
1
11/13/2312:10
75-27-4
ND
ug/L
1.0
0.34
1
11/13/2312:10
75-25-2
ND
ug/L
2.0
1.7
1
11/13/2312:10
74-83-9
ND
ug/L
5.0
4.0
1
11/13/2312:10
78-93-3
ND
ug/L
2.0
0.36
1
11/13/2312:10
75-15-0
ND
ug/L
1.0
0.33
1
11/13/2312:10
56-23-5
ND
ug/L
1.0
0.28
1
11/13/2312:10
108-90-7
ND
ug/L
1.0
0.65
1
11/13/2312:10
75-00-3
ND
ug/L
1.0
0.43
1
11/13/2312:10
67-66-3
ND
ug/L
1.0
0.54
1
11/13/2312:10
74-87-3
ND
ug/L
5.0
1.6
1
11/13/2312:10
126-99-8
ND
ug/L
1.0
0.36
1
11/13/2312:10
124-48-1
ND
ug/L
1.0
0.34
1
11/13/2312:10
95-50-1
ND
ug/L
1.0
0.34
1
11/13/2312:10
541-73-1
ND
ug/L
1.0
0.33
1
11/13/2312:10
106-46-7
ND
ug/L
1.0
0.56
1
11/13/2312:10
110-57-6
ND
ug/L
1.0
0.35
1
11/13/2312:10
75-71-8
ND
ug/L
1.0
0.37
1
11/13/2312:10
75-34-3
ND
ug/L
1.0
0.32
1
11/13/2312:10
107-06-2
ND
ug/L
1.0
0.35
1
11/13/2312:10
75-35-4
ND
ug/L
1.0
0.38
1
11/13/2312:10
156-59-2
ND
ug/L
1.0
0.40
1
11/13/2312:10
156-60-5
ND
ug/L
1.0
0.28
1
11/13/2312:10
142-28-9
ND
ug/L
1.0
0.39
1
11/13/2312:10
594-20-7 v1
ND
ug/L
1.0
0.43
1
11/13/2312:10
563-58-6
ND
ug/L
1.0
0.36
1
11 /13/23 12:10
10061-01-5
ND
ug/L
1.0
0.36
1
11/13/2312:10
10061-02-6
ND
ug/L
1.0
0.30
1
11/13/2312:10
100-41-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Sample: 1203-MW21 Lab ID: 92697340001 Collected: 11/06/23 12:02 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Ethyl methacrylate
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Methylene Chloride
Methyl methacrylate
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
2540C Total Dissolved Solids
Total Dissolved Solids
Date: 11/28/2023 12:33 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
20.0
ND
ug/L
100
ND
ug/L
10.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
20.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
96
%
70-130
95
%
70-130
101
%
70-130
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
ND ug/L 2.0
93 % 67-130
91 % 70-130
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
ND mg/L 5.0
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
ND mg/L 2.5
0.28
1
11/13/2312:10
97-63-2
1.5
1
11/13/2312:10
87-68-3
0.48
1
11 /13/23 12:10
591-78-6
9.7
1
11/13/2312:10
74-88-4
52.3
1
11/13/2312:10
78-83-1
4.2
1
11 /13/23 12:10
126-98-7
2.0
1
11/13/2312:10
75-09-2
0.32
1
11/13/2312:10
80-62-6
0.64
1
11 /13/23 12:10
91-20-3
3.6
1
11 /13/23 12:10
107-12-0
0.29
1
11 /13/23 12:10
100-42-5
0.31
1
11/13/2312:10
630-20-6
0.22
1
11/13/2312:10
79-34-5
0.29
1
11 /13/23 12:10
127-18-4
0.24
1
11 /13/23 12:10
108-88-3
0.64
1
11 /13/23 12:10
120-82-1
0.33
1
11 /13/23 12:10
71-55-6
0.32
1
11/13/2312:10
79-00-5
0.38
1
11 /13/23 12:10
79-01-6
0.30
1
11/13/2312:10
75-69-4
0.26
1
11/13/2312:10
96-18-4
1.3
1
11 /13/23 12:10
108-05-4
0.39
1
11 /13/23 12:10
75-01-4
0.34
1
11 /13/23 12:10
1330-20-7
I
111E:I:>il
I
5.0 1
2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
11/13/2312:10 460-00-4
11 /13/23 12:10 17060-07-0
11/13/2312:10 2037-26-5
ffIf10011911&'iC5!tiPX ;SQi
11/10/23 05:44 17060-07-0
11/10/23 05:44 2037-26-5
11 /15/23 19:26
11 /09/23 10:48
Page 13 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Sample: 1203-MW21
Lab ID: 92697340001 Collected: 11/06/23 12:02
Received: 11/07/23 17:05 Matrix: Water
Report
Parameters
Results Units Limit MDL
DF
Prepared Analyzed
CAS No. Qual
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
Sulfide
ND ug/L 100 22.0
1
11/09/23 05:38
18496-25-8
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
Chloride
ND mg/L 1.0 0.60
1
11/10/23 02:12
16887-00-6
Sulfate
ND mg/L 1.0 0.50
1
11/10/23 02:12
14808-79-8
4500CNE Cyanide, Total
Analytical Method: SM 4500-CN-E-2016 Preparation Method:
SM 4500-CN-E-2016
Pace Analytical Services -Asheville
Cyanide
ND ug/L 8.0 6.0
1
11/14/23 17:30 11/14/23 20:32
57-12-5
Date: 11/28/2023 12:33 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 14 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Sample: Trip Blank Lab ID: 92697340002 Collected: 11/06/23 08:00 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Allyl chloride
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Chloroprene
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Ethyl methacrylate
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Methylene Chloride
Methyl methacrylate
Naphthalene
Propionitrile
Date: 11/28/2023 12:33 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
5.1
1
11/13/2311:33
67-64-1
ND
ug/L
50.0
24.8
1
11/13/2311:33
75-05-8
ND
ug/L
10.0
8.5
1
11/13/2311:33
107-02-8
ND
ug/L
10.0
1.8
1
11/13/2311:33
107-13-1
ND
ug/L
2.0
0.50
1
11/13/2311:33
107-05-1
ND
ug/L
1.0
0.34
1
11/13/2311:33
71-43-2
ND
ug/L
1.0
0.47
1
11/13/2311:33
74-97-5
ND
ug/L
1.0
0.31
1
11/13/2311:33
75-27-4
ND
ug/L
1.0
0.34
1
11/13/2311:33
75-25-2
ND
ug/L
2.0
1.7
1
11/13/2311:33
74-83-9
ND
ug/L
5.0
4.0
1
11/13/2311:33
78-93-3
ND
ug/L
2.0
0.36
1
11/13/2311:33
75-15-0
ND
ug/L
1.0
0.33
1
11/13/2311:33
56-23-5
ND
ug/L
1.0
0.28
1
11/13/2311:33
108-90-7
ND
ug/L
1.0
0.65
1
11/13/2311:33
75-00-3
ND
ug/L
1.0
0.43
1
11/13/2311:33
67-66-3
ND
ug/L
1.0
0.54
1
11/13/2311:33
74-87-3
ND
ug/L
5.0
1.6
1
11/13/2311:33
126-99-8
ND
ug/L
1.0
0.36
1
11/13/2311:33
124-48-1
ND
ug/L
1.0
0.34
1
11/13/2311:33
95-50-1
ND
ug/L
1.0
0.34
1
11/13/2311:33
541-73-1
ND
ug/L
1.0
0.33
1
11/13/2311:33
106-46-7
ND
ug/L
1.0
0.56
1
11/13/2311:33
110-57-6
ND
ug/L
1.0
0.35
1
11/13/2311:33
75-71-8
ND
ug/L
1.0
0.37
1
11/13/2311:33
75-34-3
ND
ug/L
1.0
0.32
1
11/13/2311:33
107-06-2
ND
ug/L
1.0
0.35
1
11/13/2311:33
75-35-4
ND
ug/L
1.0
0.38
1
11/13/2311:33
156-59-2
ND
ug/L
1.0
0.40
1
11/13/2311:33
156-60-5
ND
ug/L
1.0
0.28
1
11/13/2311:33
142-28-9
ND
ug/L
1.0
0.39
1
11/13/2311:33
594-20-7
ND
ug/L
1.0
0.43
1
11/13/2311:33
563-58-6
ND
ug/L
1.0
0.36
1
11/13/2311:33
10061-01-5
ND
ug/L
1.0
0.36
1
11/13/2311:33
10061-02-6
ND
ug/L
1.0
0.30
1
11/13/2311:33
100-41-4
ND
ug/L
1.0
0.28
1
11/13/2311:33
97-63-2
ND
ug/L
2.0
1.5
1
11/13/2311:33
87-68-3
ND
ug/L
5.0
0.48
1
11/13/2311:33
591-78-6
ND
ug/L
20.0
9.7
1
11/13/2311:33
74-88-4
ND
ug/L
100
52.3
1
11/13/2311:33
78-83-1
ND
ug/L
10.0
4.2
1
11/13/2311:33
126-98-7
ND
ug/L
5.0
2.0
1
11/13/2311:33
75-09-2
ND
ug/L
2.0
0.32
1
11/13/2311:33
80-62-6
ND
ug/L
1.0
0.64
1
11/13/2311:33
91-20-3
ND
ug/L
20.0
3.6
1
11/13/2311:33
107-12-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
AC
v1
Page 15 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Sample: Trip Blank
Parameters
Lab ID:
Results
92697340002
Units
Collected:
Report
Limit
11/06/23 08:00
MDL DF
Received: 11/07/23 17:05 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
Styrene
ND
ug/L
1.0
0.29
1
11/13/23 11:33
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
11/13/23 11:33
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
11/13/23 11:33
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
11/13/23 11:33
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
11/13/23 11:33
108-88-3
1,2,4-Trichlorobenzene
ND
ug/L
1.0
0.64
1
11/13/23 11:33
120-82-1
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
11/13/23 11:33
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
11/13/23 11:33
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
11/13/23 11:33
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
11/13/23 11:33
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
11/13/23 11:33
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
11/13/23 11:33
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
11/13/23 11:33
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
11/13/23 11:33
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
11/13/23 11:33
460-00-4
1,2-Dichloroethane-d4 (S)
99
%
70-130
1
11/13/23 11:33
17060-07-0
Toluene-d8 (S)
101
%
70-130
1
11/13/23 11:33
2037-26-5
Date: 11/28/2023 12:33 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 16 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Sample: 1203-MW-21
Lab ID: 92697337005 Collected:
11/06/23
12:02
Received: 11/07/23 17:05 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
353.2 NO2/NO3 unpres EDN
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services - Eden
Nitrogen, Nitrate
0.15 mg/L 0.040
0.029
1
11/08/23 09:26
14797-55-8
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
7.5J ug/L 10.0
5.3
1
11/09/2317:24
74-82-8 B
5310B TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
ND mg/L 1.0
0.50
1
11/20/23 12:23
7440-44-0
Date: 11/28/2023 12:33 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 17 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Sample: 1203-MW-21 Lab ID: 92697351001 Collected: 11/06/23 12:02 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
BR Hydrogen by AM20 in Vapor Analytical Method: AM20
Pace Analytical Services - Baton Rouge
Hydrogen 1.4J nMoles 1.9 0.49 1 11/14/23 09:01 1333-74-0
Date: 11/28/2023 12:33 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 18 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Sample: 1203-FIELD BLANK Lab ID: 92698166001 Collected: 11/08/23 14:56 Received: 11/10/23 09:45 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8081 OC Pesticides RVE
Aldrin
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Chlordane (Technical)
4,4'-DDD
4,4'-DDE
4,4'-DDT
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
Surrogates
Tetrachloro-m-xylene (S)
Decachlorobiphenyl (S)
8082 GCS PCB RVE
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
Surrogates
Decachlorobiphenyl (S)
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Date: 11/28/2023 12:33 PM
Analytical Method: EPA 8081 B Preparation Method: EPA 3510C
Pace Analytical Services
- Charlotte
ND
ug/L
0.045
0.013
1
11/12/23 16:02
11/21/2313:47
309-00-2
L1
ND
ug/L
0.045
0.011
1
11/12/23 16:02
11/21/2313:47
319-84-6
L1
ND
ug/L
0.045
0.044
1
11/12/23 16:02
11 /21 /23 13:47
319-85-7
ND
ug/L
0.045
0.013
1
11/12/23 16:02
11 /21 /23 13:47
319-86-8
ND
ug/L
0.045
0.011
1
11/12/23 16:02
11/21/2313:47
58-89-9
L1
ND
ug/L
0.45
0.14
1
11/12/23 16:02
11 /21 /23 13:47
57-74-9
ND
ug/L
0.045
0.015
1
11/12/23 16:02
11/21/2313:47
72-54-8
L1
ND
ug/L
0.045
0.022
1
11/12/23 16:02
11/21/2313:47
72-55-9
L1
ND
ug/L
0.045
0.023
1
11/12/23 16:02
11/21/2313:47
50-29-3
L1
ND
ug/L
0.045
0.014
1
11/12/23 16:02
11/21/2313:47
60-57-1
L1
ND
ug/L
0.045
0.016
1
11/12/23 16:02
11 /21 /23 13:47
959-98-8
ND
ug/L
0.045
0.014
1
11/12/23 16:02
11/21/2313:47
33213-65-9
L1
ND
ug/L
0.045
0.013
1
11/12/23 16:02
11 /21 /23 13:47
1031-07-8
ND
ug/L
0.045
0.016
1
11/12/23 16:02
11/21/2313:47
72-20-8
L1
ND
ug/L
0.045
0.015
1
11/12/23 16:02
11 /21 /23 13:47
7421-93-4
ND
ug/L
0.045
0.018
1
11/12/23 16:02
11/21/2313:47
76-44-8
L1
ND
ug/L
0.045
0.026
1
11/12/23 16:02
11 /21 /23 13:47
1024-57-3
ND
ug/L
0.14
0.038
1
11/12/23 16:02
11 /21 /23 13:47
72-43-5
ND
ug/L
0.45
0.20
1
11/12/23 16:02
11 /21 /23 13:47
8001-35-2
172
%
10-137
1
11/12/23 16:02
11/21/2313:47
877-09-8
S3
136
%
19-200
1
11/12/23 16:02
11 /21 /23 13:47
2051-24-3
Analytical Method: EPA 8082A Preparation Method: EPA
3510C
Pace Analytical Services
- Charlotte
ND
ug/L
0.45
0.19
1
11/12/23 16:02
11/23/23 03:33
12674-11-2
ND
ug/L
0.45
0.21
1
11/12/23 16:02
11/23/23 03:33
11104-28-2
ND
ug/L
0.45
0.21
1
11/12/23 16:02
11/23/23 03:33
11141-16-5
N D
ug/L
0.45
0.23
1
11/12/23 16:02
11/23/23 03:33
53469-21-9
ND
ug/L
0.45
0.26
1
11/12/23 16:02
11/23/23 03:33
12672-29-6
ND
ug/L
0.45
0.19
1
11/12/23 16:02
11/23/23 03:33
11097-69-1
ND
ug/L
0.45
0.14
1
11/12/23 16:02
11/23/23 03:33
11096-82-5
90
%
10-193
1
11/12/23 16:02
11/23/23 03:33
2051-24-3
Analytical Method: EPA 601 OD Preparation Method:
EPA
3010A
Pace Analytical Services
-Asheville
ND
ug/L
5.0
3.6
1
11/14/2311:35
11/16/2311:12
7440-36-0
ND
ug/L
10.0
2.5
1
11/14/2311:35
11/15/2312:29
7440-38-2
ND
ug/L
5.0
0.79
1
11/14/2311:35
11/15/2312:29
7440-39-3
ND
ug/L
1.0
0.16
1
11/14/2311:35
11/15/2312:29
7440-41-7
ND
ug/L
1.0
0.29
1
11/14/2311:35
11/15/2312:29
7440-43-9
ND
ug/L
5.0
0.63
1
11/14/2311:35
11/15/2312:29
7440-47-3
ND
ug/L
5.0
0.44
1
11/14/2311:35
11/15/2312:29
7440-48-4
ND
ug/L
5.0
0.62
1
11/14/2311:35
11/15/2312:29
7440-50-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 19 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Sample: 1203-FIELD BLANK Lab ID: 92698166001 Collected: 11/08/23 14:56 Received: 11/10/23 09:45 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Iron
18.8J
ug/L
50.0
8.9
1
11/14/2311:35
11/15/2312:29
7439-89-6
Lead
ND
ug/L
5.0
1.4
1
11/14/2311:35
11/15/2312:29
7439-92-1
Manganese
ND
ug/L
5.0
0.86
1
11/14/2311:35
11/15/2312:29
7439-96-5
Nickel
ND
ug/L
5.0
0.88
1
11/14/2311:35
11/15/2312:29
7440-02-0
Selenium
ND
ug/L
10.0
4.1
1
11/14/2311:35
11/16/2311:12
7782-49-2
Silver
ND
ug/L
5.0
0.49
1
11/14/2311:35
11/15/2312:29
7440-22-4
Tin
ND
ug/L
5.0
2.0
1
11/14/2311:35
11/15/2312:29
7440-31-5
Vanadium
ND
ug/L
5.0
1.6
1
11/14/2311:35
11/15/2312:29
7440-62-2
Zinc
ND
ug/L
10.0
3.0
1
11/14/2311:35
11/15/2312:29
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020B Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.20
0.050
1
11/14/23 00:34
11/15/23 19:09
7440-28-0
7470 Mercury
Analytical Method: EPA 7470A Preparation Method: EPA
7470A
Pace Analytical Services -Asheville
Mercury
ND
ug/L
0.20
0.12
1
11/15/23 16:59
11/17/23 21:00
7439-97-6
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA
3510C
Pace Analytical Services - Charlotte
Acenaphthene
ND
ug/L
9.1
1.8
1
11/13/23 10:45
11/14/23 20:24
83-32-9
Acenaphthylene
ND
ug/L
9.1
1.8
1
11/13/23 10:45
11/14/23 20:24
208-96-8
Acetophenone
ND
ug/L
9.1
1.4
1
11/13/23 10:45
11/14/23 20:24
98-86-2
2-Acetylaminofluorene
ND
ug/L
9.1
3.7
1
11/13/23 10:45
11/14/23 20:24
53-96-3
4-Aminobiphenyl
ND
ug/L
9.1
4.3
1
11/13/23 10:45
11/14/23 20:24
92-67-1
Anthracene
ND
ug/L
9.1
2.1
1
11/13/23 10:45
11/14/23 20:24
120-12-7
Benzo(a)anthracene
ND
ug/L
9.1
2.4
1
11/13/23 10:45
11/14/23 20:24
56-55-3
Benzo(a)pyrene
ND
ug/L
9.1
2.5
1
11/13/23 10:45
11/14/23 20:24
50-32-8
Benzo(b)fluoranthene
ND
ug/L
9.1
2.4
1
11/13/23 10:45
11/14/23 20:24
205-99-2
Benzo(g,h,i)perylene
ND
ug/L
9.1
2.6
1
11/13/23 10:45
11/14/23 20:24
191-24-2
Benzo(k)fluoranthene
ND
ug/L
9.1
2.5
1
11/13/23 10:45
11/14/23 20:24
207-08-9
Benzyl alcohol
ND
ug/L
18.2
2.6
1
11/13/23 10:45
11/14/23 20:24
100-51-6
4-Bromophenylphenyl ether
ND
ug/L
9.1
1.6
1
11/13/23 10:45
11/14/23 20:24
101-55-3
Butylbenzylphthalate
ND
ug/L
9.1
2.9
1
11/13/23 10:45
11/14/23 20:24
85-68-7
4-ChIoro-3-methyl phenol
ND
ug/L
9.1
3.0
1
11/13/23 10:45
11/14/23 20:24
59-50-7
4-Chloroaniline
ND
ug/L
18.2
3.3
1
11/13/23 10:45
11/14/23 20:24
106-47-8
Chlorobenzilate
ND
ug/L
9.1
3.4
1
11/13/23 10:45
11/14/23 20:24
510-15-6
bis(2-Chloroethoxy)methane
ND
ug/L
9.1
1.7
1
11/13/23 10:45
11/14/23 20:24
111-91-1
bis(2-Chloroethyl) ether
ND
ug/L
9.1
1.7
1
11/13/23 10:45
11/14/23 20:24
111-44-4
2-Chloronaphthalene
ND
ug/L
9.1
1.6
1
11/13/23 10:45
11/14/23 20:24
91-58-7
2-Chlorophenol
ND
ug/L
9.1
1.1
1
11/13/23 10:45
11/14/23 20:24
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
9.1
1.8
1
11/13/23 10:45
11/14/23 20:24
7005-72-3
Chrysene
ND
ug/L
9.1
2.5
1
11/13/23 10:45
11/14/23 20:24
218-01-9
Diallate
ND
ug/L
9.1
3.1
1
11/13/23 10:45
11/14/23 20:24
2303-16-4
Dibenz(a,h)anthracene
ND
ug/L
9.1
2.7
1
11/13/23 10:45
11/14/23 20:24
53-70-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 20 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Sample: 1203-FIELD BLANK Lab ID: 92698166001 Collected: 11/08/23 14:56 Received: 11/10/23 09:45 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Dibenzofuran
ND
ug/L
9.1
1.9
1
11/13/23 10:45
11/14/23 20:24
132-64-9
3,3'-Dichlorobenzidine
ND
ug/L
18.2
7.4
1
11/13/23 10:45
11/14/23 20:24
91-94-1
2,4-Dichlorophenol
ND
ug/L
9.1
1.3
1
11/13/23 10:45
11/14/23 20:24
120-83-2
2,6-Dichlorophenol
ND
ug/L
9.1
3.8
1
11/13/23 10:45
11/14/23 20:24
87-65-0
Diethylphthalate
ND
ug/L
9.1
1.9
1
11/13/23 10:45
11/14/23 20:24
84-66-2
Dimethoate
ND
ug/L
9.1
3.3
1
11/13/23 10:45
11/14/23 20:24
60-51-5
P-Dimethylaminoazobenzene
ND
ug/L
4.5
2.2
1
11/13/23 10:45
11/14/23 20:24
60-11-7
7,12-Dimethylbenz(a)anthracene
ND
ug/L
9.1
2.7
1
11/13/23 10:45
11/14/23 20:24
57-97-6
3,3'-Dimethylbenzidine
ND
ug/L
45.5
28.3
1
11/13/23 10:45
11/14/23 20:24
119-93-7
2,4-Dimethylphenol
ND
ug/L
9.1
1.5
1
11/13/23 10:45
11/14/23 20:24
105-67-9
Dimethylphthalate
ND
ug/L
9.1
1.9
1
11/13/23 10:45
11/14/23 20:24
131-11-3
Di-n-butylphthalate
ND
ug/L
9.1
2.0
1
11/13/23 10:45
11/14/23 20:24
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
18.2
7.1
1
11/13/23 10:45
11/14/23 20:24
534-52-1
1,3-Dinitrobenzene
ND
ug/L
9.1
3.4
1
11/13/23 10:45
11/14/23 20:24
99-65-0
2,4-Dinitrophenol
ND
ug/L
45.5
23.6
1
11/13/23 10:45
11/14/23 20:24
51-28-5
2,4-Dinitrotoluene
ND
ug/L
9.1
1.5
1
11/13/23 10:45
11/14/23 20:24
121-14-2
2,6-Dinitrotoluene
ND
ug/L
9.1
1.6
1
11/13/23 10:45
11/14/23 20:24
606-20-2
Di-n-octylphthalate
ND
ug/L
9.1
3.6
1
11/13/23 10:45
11/14/23 20:24
117-84-0
Diphenylamine
ND
ug/L
9.1
2.7
1
11/13/23 10:45
11/14/23 20:24
122-39-4
Disulfoton
ND
ug/L
9.1
4.2
1
11/13/23 10:45
11/14/23 20:24
298-04-4
bis(2- Ethyl hexyl)phthalate
ND
ug/L
5.5
3.4
1
11/13/23 10:45
11/14/23 20:24
117-81-7
Ethyl methanesulfonate
ND
ug/L
18.2
2.7
1
11/13/23 10:45
11/14/23 20:24
62-50-0
Famphur
ND
ug/L
9.1
5.6
1
11/13/23 10:45
11/14/23 20:24
52-85-7
Fluoranthene
ND
ug/L
9.1
2.0
1
11/13/23 10:45
11/14/23 20:24
206-44-0
Fluorene
ND
ug/L
9.1
1.9
1
11/13/23 10:45
11/14/23 20:24
86-73-7
Hexachloro-1,3-butadiene
ND
ug/L
9.1
1.6
1
11/13/23 10:45
11/14/23 20:24
87-68-3
Hexachlorobenzene
ND
ug/L
9.1
2.0
1
11/13/23 10:45
11/14/23 20:24
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
9.1
1.4
1
11/13/23 10:45
11/14/23 20:24
77-47-4
Hexachloroethane
ND
ug/L
9.1
1.3
1
11/13/23 10:45
11/14/23 20:24
67-72-1
Hexachloropropene
ND
ug/L
9.1
2.5
1
11/13/23 10:45
11/14/23 20:24
1888-71-7
Indeno(1,2,3-cd)pyrene
ND
ug/L
9.1
2.6
1
11/13/23 10:45
11/14/23 20:24
193-39-5
Isodrin
ND
ug/L
9.1
2.5
1
11/13/23 10:45
11/14/23 20:24
465-73-6
Isophorone
ND
ug/L
9.1
1.5
1
11/13/23 10:45
11/14/23 20:24
78-59-1
Isosafrole
ND
ug/L
9.1
2.3
1
11/13/23 10:45
11/14/23 20:24
120-58-1
Kepone
ND
ug/L
18.2
12.8
1
11/13/23 10:45
11/14/23 20:24
143-50-0
Methapyrilene
ND
ug/L
45.5
15.5
1
11/13/23 10:45
11/14/23 20:24
91-80-5
3-Methylcholanthrene
ND
ug/L
9.1
3.4
1
11/13/23 10:45
11/14/23 20:24
56-49-5
Methyl methanesulfonate
ND
ug/L
4.5
2.8
1
11/13/23 10:45
11/14/23 20:24
66-27-3
2-Methylnaphthalene
ND
ug/L
9.1
1.7
1
11/13/23 10:45
11/14/23 20:24
91-57-6
Methyl parathion
ND
ug/L
9.1
3.4
1
11/13/23 10:45
11/14/23 20:24
298-00-0
2-Methylphenol(o-Cresol)
ND
ug/L
9.1
1.7
1
11/13/23 10:45
11/14/23 20:24
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
9.1
1.1
1
11/13/23 10:45
11/14/23 20:24
15831-10-4
1-Naphthalenamine
ND
ug/L
9.1
5.5
1
11/13/23 10:45
11/14/23 20:24
134-32-7
2-Naphthalenamine
ND
ug/L
9.1
5.0
1
11/13/23 10:45
11/14/23 20:24
91-59-8
1,4-Naphthoquinone
ND
ug/L
4.5
4.0
1
11/13/23 10:45
11/14/23 20:24
130-15-4
REPORT OF LABORATORY ANALYSIS
L2,v2
v1
L1
L2,v1
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Sample: 1203-FIELD BLANK Lab ID: 92698166001 Collected: 11/08/23 14:56 Received: 11/10/23 09:45 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
5-Nitro-o-toluidine
N-Nitrosodiethylamine
N-Nitrosodimethylamine
N-Nitroso-di-n-butylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
N-Nitrosomethylethylamine
N-Nitrosopiperidine
N-Nitrosopyrrolidine
O, O,O-Triethyl phosphorothioate
2,2'-Oxybis(1-chloropropane)
Parathion (Ethyl parathion)
Pentachlorobenzene
Pentachloronitrobenzene
Pentachlorophenol
Phenacetin
Phenanthrene
Phenol
p-Phenylenediamine
Phorate
Pronamide
Pyrene
Safrole
1,2,4,5-Tetrachlorobenzene
2,3,4,6-Tetrachlorophenol
Thionazin
O-Toluidine
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
1,3,5-Trinitrobenzene
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Date: 11/28/2023 12:33 PM
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
ND
ug/L
18.2
2.7
1
11/13/23 10:45
11/14/23 20:24
88-74-4
ND
ug/L
18.2
3.4
1
11/13/23 10:45
11/14/23 20:24
99-09-2
ND
ug/L
18.2
4.6
1
11/13/23 10:45
11/14/23 20:24
100-01-6
ND
ug/L
9.1
1.7
1
11/13/23 10:45
11/14/23 20:24
98-95-3
ND
ug/L
9.1
1.3
1
11/13/23 10:45
11/14/23 20:24
88-75-5
ND
ug/L
45.5
6.0
1
11/13/23 10:45
11/14/23 20:24
100-02-7
ND
ug/L
9.1
3.5
1
11/13/23 10:45
11/14/23 20:24
99-55-8
ND
ug/L
9.1
2.1
1
11/13/23 10:45
11/14/23 20:24
55-18-5
ND
ug/L
9.1
1.7
1
11/13/23 10:45
11/14/23 20:24
62-75-9
ND
ug/L
9.1
1.8
1
11/13/23 10:45
11/14/23 20:24
924-16-3
ND
ug/L
9.1
1.2
1
11/13/23 10:45
11/14/23 20:24
621-64-7
ND
ug/L
9.1
2.7
1
11/13/23 10:45
11/14/23 20:24
86-30-6
ND
ug/L
9.1
6.8
1
11/13/23 10:45
11/14/23 20:24
10595-95-6
ND
ug/L
9.1
2.3
1
11/13/23 10:45
11/14/23 20:24
100-75-4
ND
ug/L
9.1
2.8
1
11/13/23 10:45
11/14/23 20:24
930-55-2
ND
ug/L
9.1
2.3
1
11/13/23 10:45
11/14/23 20:24
126-68-1
ND
ug/L
9.1
1.0
1
11/13/23 10:45
11/14/23 20:24
108-60-1
ND
ug/L
9.1
3.5
1
11/13/23 10:45
11/14/23 20:24
56-38-2
ND
ug/L
9.1
3.1
1
11/13/23 10:45
11/14/23 20:24
608-93-5
ND
ug/L
9.1
3.0
1
11/13/23 10:45
11/14/23 20:24
82-68-8
ND
ug/L
18.2
3.4
1
11/13/23 10:45
11/14/23 20:24
87-86-5
ND
ug/L
9.1
3.3
1
11/13/23 10:45
11/14/23 20:24
62-44-2
ND
ug/L
9.1
1.8
1
11/13/23 10:45
11/14/23 20:24
85-01-8
ND
ug/L
9.1
1.2
1
11/13/23 10:45
11/14/23 20:24
108-95-2
ND
ug/L
9.1
9.1
1
11/13/23 10:45
11/14/23 20:24
106-50-3
ND
ug/L
9.1
3.2
1
11/13/23 10:45
11/14/23 20:24
298-02-2
ND
ug/L
9.1
2.8
1
11/13/23 10:45
11/14/23 20:24
23950-58-5
ND
ug/L
9.1
2.0
1
11/13/23 10:45
11/14/23 20:24
129-00-0
ND
ug/L
9.1
2.1
1
11/13/23 10:45
11/14/23 20:24
94-59-7
ND
ug/L
9.1
4.1
1
11/13/23 10:45
11/14/23 20:24
95-94-3
ND
ug/L
9.1
1.4
1
11/13/23 10:45
11/14/23 20:24
58-90-2
ND
ug/L
9.1
2.6
1
11/13/23 10:45
11/14/23 20:24
297-97-2
ND
ug/L
9.1
2.4
1
11/13/23 10:45
11/14/23 20:24
95-53-4
ND
ug/L
9.1
1.3
1
11/13/23 10:45
11/14/23 20:24
95-95-4
ND
ug/L
9.1
1.4
1
11/13/23 10:45
11/14/23 20:24
88-06-2
ND
ug/L
9.1
5.0
1
11/13/23 10:45
11/14/23 20:24
99-35-4
107
%
10-133
1
11/13/23 10:45
11/14/23 20:24
4165-60-0
83
%
10-130
1
11/13/23 10:45
11/14/23 20:24
321-60-8
116
%
10-193
1
11/13/23 10:45
11/14/23 20:24
1718-51-0
64
%
10-130
1
11/13/23 10:45
11/14/23 20:24
13127-88-3
62
%
10-130
1
11/13/23 10:45
11/14/23 20:24
367-12-4
92
%
10-166
1
11/13/23 10:45
11/14/23 20:24
118-79-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
L1
Page 22 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Sample: 1203-FIELD BLANK
Parameters
Lab ID: 92698166001 Collected:
Report
Results Units Limit
11/08/23 14:56
MDL DF
Received: 11/10/23 09:45 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV SIM
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
1,4-Dioxane (p-Dioxane)
ND ug/L 2.0
0.86
1
11/13/23 22:45
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
84 % 67-130
1
11/13/23 22:45
17060-07-0
Toluene-d8 (S)
90 % 70-130
1
11/13/23 22:45
2037-26-5
2320B Alkalinity
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
Alkalinity, Total as CaCO3
ND mg/L 5.0
5.0
1
11/17/23 17:46
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
Sulfide
ND ug/L 100
22.0
1
11/14/23 04:03
18496-25-8
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1
1993
Pace Analytical Services -Asheville
Chloride
ND mg/L 1.0
0.60
1
11/14/23 23:16
16887-00-6
Sulfate
ND mg/L 1.0
0.50
1
11/14/23 23:16
14808-79-8
450OCNE Cyanide, Total
Analytical Method: SM 4500-CN-E-2016
Preparation Method:
SM 4500-CN-E-2016
Pace Analytical Services -Asheville
Cyanide
ND ug/L 8.0
6.0
1
11/18/2314:01 11/18/2316:31
57-12-5
Date: 11/28/2023 12:33 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 23 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Sample: 1203-SMP6 Lab ID: 92697345001 Collected: 11/06/23 17:22 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Iron
Lead
Manganese
Nickel
Selenium
Silver
Hardness, Total(SM 2340B)
Vanadium
Zinc
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
ND
ug/L
5.0
3.6
1
11/10/2312:00
11/13/2317:06
7440-36-0
ND
ug/L
10.0
2.5
1
11/10/2312:00
11/13/2317:06
7440-38-2
66.1
ug/L
5.0
0.79
1
11/10/2312:00
11/13/2317:06
7440-39-3
ND
ug/L
1.0
0.16
1
11/10/2312:00
11/13/2317:06
7440-41-7
0.31J
ug/L
1.0
0.29
1
11/10/2312:00
11/13/2317:06
7440-43-9
ND
ug/L
5.0
0.63
1
11/10/2312:00
11/13/2317:06
7440-47-3
ND
ug/L
5.0
0.44
1
11/10/2312:00
11/13/2317:06
7440-48-4
ND
ug/L
5.0
0.62
1
11/10/2312:00
11/13/2317:06
7440-50-8
44600
ug/L
50.0
8.9
1
11/10/2312:00
11/13/2317:06
7439-89-6
ND
ug/L
5.0
1.4
1
11/10/2312:00
11/13/2317:06
7439-92-1
1110
ug/L
5.0
0.86
1
11/10/2312:00
11/13/2317:06
7439-96-5
ND
ug/L
5.0
0.88
1
11/10/2312:00
11/13/2317:06
7440-02-0
ND
ug/L
10.0
4.1
1
11/10/2312:00
11/13/2317:06
7782-49-2
ND
ug/L
5.0
0.49
1
11/10/2312:00
11/13/2317:06
7440-22-4
25400
ug/L
662
36.8
1
11/10/2312:00
11/13/2317:06
ND
ug/L
5.0
1.6
1
11/10/2312:00
11/13/2317:06
7440-62-2
5.2.11
ug/L
10.0
3.0
1
11/10/2312:00
11/13/2317:06
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Thallium
7470 Mercury
Mercury
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Date: 11/28/2023 12:33 PM
ND ug/L 0.20 0.050 1 11/10/23 12:25 11/12/23 20:06 7440-28-0
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
ND ug/L 0.20 0.12 1 11/11/23 22:12 11/12/23 12:05 7439-97-6
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
11.1J
ug/L
25.0
ND
ug/L
10.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
5.1
1
11/10/2317:39
67-64-1
1.8
1
11 /10/23 17:39
107-13-1
0.34
1
11 /10/23 17:39
71-43-2
0.47
1
11/10/2317:39
74-97-5
0.31
1
11/10/2317:39
75-27-4
0.34
1
11/10/2317:39
75-25-2
1.7
1
11/10/2317:39
74-83-9
4.0
1
11/10/2317:39
78-93-3
0.36
1
11/10/2317:39
75-15-0
0.33
1
11/10/2317:39
56-23-5
0.28
1
11 /10/23 17:39
108-90-7
0.65
1
11/10/2317:39
75-00-3
0.43
1
11/10/2317:39
67-66-3
0.54
1
11/10/2317:39
74-87-3
0.34
1
11/10/2317:39
96-12-8
0.36
1
11 /10/23 17:39
124-48-1
0.27
1
11 /10/23 17:39
106-93-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 24 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Sample: 1203-SMP6 Lab ID: 92697345001 Collected: 11/06/23 17:22 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 11/28/2023 12:33 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.39
1
11/10/2317:39
74-95-3
ND
ug/L
1.0
0.34
1
11/10/2317:39
95-50-1
ND
ug/L
1.0
0.33
1
11/10/2317:39
106-46-7
ND
ug/L
1.0
0.56
1
11/10/2317:39
110-57-6
1.3
ug/L
1.0
0.37
1
11/10/2317:39
75-34-3
ND
ug/L
1.0
0.32
1
11/10/2317:39
107-06-2
ND
ug/L
1.0
0.35
1
11/10/2317:39
75-35-4
0.97J
ug/L
1.0
0.38
1
11/10/2317:39
156-59-2
ND
ug/L
1.0
0.40
1
11/10/2317:39
156-60-5
ND
ug/L
1.0
0.36
1
11/10/2317:39
78-87-5
ND
ug/L
1.0
0.36
1
11/10/23 17:39
10061-01-5
ND
ug/L
1.0
0.36
1
11/10/2317:39
10061-02-6
ND
ug/L
1.0
0.30
1
11/10/2317:39
100-41-4
ND
ug/L
5.0
0.48
1
11/10/2317:39
591-78-6
ND
ug/L
20.0
9.7
1
11/10/2317:39
74-88-4
ND
ug/L
5.0
2.0
1
11/10/2317:39
75-09-2
ND
ug/L
5.0
2.7
1
11/10/2317:39
108-10-1
ND
ug/L
1.0
0.29
1
11/10/2317:39
100-42-5
ND
ug/L
1.0
0.31
1
11/10/2317:39
630-20-6
ND
ug/L
1.0
0.22
1
11/10/2317:39
79-34-5
ND
ug/L
1.0
0.29
1
11/10/2317:39
127-18-4
ND
ug/L
10.0
3.5
1
11/10/2317:39
109-99-9
0.79J
ug/L
1.0
0.24
1
11/10/2317:39
108-88-3
ND
ug/L
1.0
0.33
1
11/10/2317:39
71-55-6
ND
ug/L
1.0
0.32
1
11/10/2317:39
79-00-5
0.44J
ug/L
1.0
0.38
1
11/10/2317:39
79-01-6
ND
ug/L
1.0
0.30
1
11/10/2317:39
75-69-4
ND
ug/L
1.0
0.26
1
11/10/2317:39
96-18-4
ND
ug/L
2.0
1.3
1
11/10/2317:39
108-05-4
ND
ug/L
1.0
0.39
1
11/10/2317:39
75-01-4
ND
ug/L
1.0
0.34
1
11/10/2317:39
1330-20-7
99
%
70-130
1
11/10/2317:39
460-00-4
90
%
70-130
1
11/10/2317:39
17060-07-0
103
%
70-130
1
11/10/2317:39
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
ND
ug/L
2.0
0.86
1
11/10/23 08:14
123-91-1
90
%
67-130
1
11/10/23 08:14
17060-07-0
90
%
70-130
1
11/10/23 08:14
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report
shall not be reproduced,
except in full,
without the written
consent of Pace
Analytical Services, LLC.
Page 25 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Sample: 1203-SMP6 Lab ID: 92697345001 Collected: 11/06/23 17:22 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
450OCNE Cyanide, Total Analytical Method: SM 4500-CN-E-2016 Preparation Method: SM 4500-CN-E-2016
Pace Analytical Services -Asheville
Cyanide ND mg/L 0.0080 0.0060 1 11/10/2319:12 11/11/2310:57 57-12-5
Date: 11/28/2023 12:33 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 26 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 307943 Analysis Method: AM20
QC Batch Method: AM20 Analysis Description: BR Hydrogen by AM20 in Vapor
Laboratory: Pace Analytical Services - Baton Rouge
Associated Lab Samples: 92697351001
METHOD BLANK: 1473991 Matrix: Air
Associated Lab Samples: 92697351001
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Hydrogen nMoles ND 1.9 0.49 11/14/23 08:48
LABORATORY CONTROL SAMPLE & LCSD: 1473993 1473992
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers
Hydrogen nMoles 11.9 12.6 12.2 102 70-130 4 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 811687 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. EDN
Laboratory: Pace Analytical Services - Eden
Associated Lab Samples: 92697337005
METHOD BLANK: 4202489
Associated Lab Samples: 92697337005
Parameter Units
Nitrogen, Nitrate mg/L
LABORATORY CONTROL SAMPLE: 4202490
Parameter Units
Nitrogen, Nitrate mg/L
Matrix: Water
Blank Reporting
Result Limit
ND 0.040
Spike LCS
Conc. Result
1.5 1.5
MDL Analyzed Qualifiers
0.029 11/08/23 09:06
LCS % Rec
% Rec Limits Qualifiers
100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4202789 4202790
MS MSD
92697337005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L 0.15 1.5 1.5 1.6 1.7 99 101 90-110 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4205693 4205694
MS MSD
92697827012 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L 0.087 1.5 1.5 1.6 1.6 102 100 90-110 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 28 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 2169599 Analysis Method: EPA 8151
QC Batch Method: 8151A Analysis Description: Chlorinated Herb. (GC) 8151
Laboratory: Pace National - Mt. Juliet
Associated Lab Samples: 92697340001
METHOD BLANK: R3999739-1
Matrix:
Water
Associated Lab Samples: 92697340001
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
2,4-D
ug/L
ND
2.00
0.547
11/14/23 04:08
2,4,5-T
ug/L
ND
2.00
0.258
11/14/23 04:08
2,4,5-TP (Silvex)
ug/L
ND
2.00
0.335
11/14/23 04:08
Dinoseb
ug/L
ND
2.00
0.250
11/14/23 04:08
2,4-DCAA (S)
%
71.8
14.0-158
11/14/23 04:08
LABORATORY CONTROL SAMPLE:
R3999739-2
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
2,4-D
ug/L
5.00
5.31
106
50.0-120 E
2,4,5-T
ug/L
5.00
5.10
102
54.0-120 E
2,4,5-TP (Silvex)
ug/L
5.00
4.36
87.2
50.0-125
Dinoseb
ug/L
5.00
6.48
130
36.0-134 E
2,4-DCAA (S)
%
78.6
14.0-158
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: R3999739-3
R3999739-4
MS
MSD
L1676413-07
Spike
Spike
MS
MSD
MS
MSD % Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec Limits
RPD
RPD Qual
2,4-D
ug/L
ND
4.76
4.76
4.84
4.93
102
104 50.0-120
1.84
20 E
2,4,5-T
ug/L
ND
4.76
4.76
4.56
4.51
95.8
94.7 54.0-120
1.10
20
2,4,5-TP (Silvex)
ug/L
ND
4.76
4.76
4.38
3.64
92.0
76.5 50.0-125
18.5
20
Dinoseb
ug/L
ND
4.76
4.76
5.14
5.10
108
107 36.0-134
0.781
20 E
2,4-DCAA (S)
%
72.5
75.0 14.0-158
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 29 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 812107 Analysis Method: RSK 175 Modified
QC Batch Method: RSK 175 Modified Analysis Description: RSK 175 HEADSPACE
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92697337005
METHOD BLANK: 4204821
Associated Lab Samples: 92697337005
Parameter
Units
Methane
ug/L
LABORATORY CONTROL SAMPLE:
4204822
Parameter
Units
Methane
ug/L
MATRIX SPIKE SAMPLE:
4204824
Parameter
Units
Methane
ug/L
Matrix: Water
Blank Reporting
Result Limit MDL Analyzed Qualifiers
5.3J 10.0 5.3 11/09/2313:29
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
297 276 93 70-130
92697583002 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
8570 297 5500 -1030 70-130 H1,M1
SAMPLE DUPLICATE: 4204823
92697583001 Dup
Parameter Units Result Result
Methane ug/L 9070 5820
SAMPLE DUPLICATE: 4204825
92697337003 Dup
Parameter Units Result Result
Methane ug/L 5920 3690
Max
RPD RPD Qualifiers
44 20 D6,H1,R2
Max
RPD RPD Qualifiers
46 20 D6.H1.R2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 812700 Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697340001, 92697345001
METHOD BLANK: 4207985 Matrix: Water
Associated Lab Samples: 92697340001, 92697345001
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Mercury ug/L ND 0.20 0.12 11/12/2311:53
LABORATORY CONTROL SAMPLE: 4207986
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 2.5 2.6 103 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4207987 4207988
MS MSD
92697340001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND 2.5 2.5 2.6 2.6 105 104 75-125 2 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 31 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 813394 Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92698166001
METHOD BLANK: 4211231
Matrix:
Water
Associated Lab Samples: 92698166001
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Mercury
ug/L
ND
0.20
0.12 11/17/23 20:04
LABORATORY CONTROL SAMPLE:
4211232
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Mercury
ug/L
2.5
2.6 103
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4211233 4211234
MS MSD
92698127033 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L <0.20 2.5 2.5 2.4 2.4 98 98 75-125 0 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 812399 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697340001, 92697345001
METHOD BLANK: 4206419
Associated Lab Samples: 92697340001, 92697345001
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
Antimony
ug/L
ND
5.0
3.6
11/13/2316:04
Arsenic
ug/L
ND
10.0
2.5
11/13/2316:04
Barium
ug/L
ND
5.0
0.79
11/13/2316:04
Beryllium
ug/L
ND
1.0
0.16
11/13/2316:04
Cadmium
ug/L
ND
1.0
0.29
11/13/2316:04
Chromium
ug/L
ND
5.0
0.63
11/13/2316:04
Cobalt
ug/L
ND
5.0
0.44
11/13/2316:04
Copper
ug/L
ND
5.0
0.62
11/13/2316:04
Hardness, Total(SM 2340B)
ug/L
79.OJ
662
36.8
11/13/23 16:04
Iron
ug/L
ND
50.0
8.9
11/13/2316:04
Lead
ug/L
ND
5.0
1.4
11/13/2316:04
Manganese
ug/L
ND
5.0
0.86
11/13/2316:04
Nickel
ug/L
ND
5.0
0.88
11/13/2316:04
Selenium
ug/L
ND
10.0
4.1
11/13/2316:04
Silver
ug/L
ND
5.0
0.49
11/13/2316:04
Tin
ug/L
ND
5.0
2.0
11/13/2316:04
Vanadium
ug/L
ND
5.0
1.6
11/13/2316:04
Zinc
ug/L
ND
10.0
3.0
11/13/2316:04
LABORATORY CONTROL SAMPLE:
4206420
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Antimony
ug/L
500
485
97
80-120
Arsenic
ug/L
500
502
100
80-120
Barium
ug/L
500
492
98
80-120
Beryllium
ug/L
500
483
97
80-120
Cadmium
ug/L
500
503
101
80-120
Chromium
ug/L
500
483
97
80-120
Cobalt
ug/L
500
489
98
80-120
Copper
ug/L
500
481
96
80-120
Hardness, Total(SM 2340B)
ug/L
33100
32300
98
80-120
Iron
ug/L
5000
4860
97
80-120
Lead
ug/L
500
491
98
80-120
Manganese
ug/L
500
497
99
80-120
Nickel
ug/L
500
495
99
80-120
Selenium
ug/L
500
475
95
80-120
Silver
ug/L
250
236
95
80-120
Tin
ug/L
500
498
100
80-120
Vanadium
ug/L
500
498
100
80-120
Results presented on this page are in the units
indicated by the "Units"
column except
where an alternate unit
is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
LABORATORY CONTROL SAMPLE: 4206420
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Zinc ug/L 500 504 101 80-120
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 4206421
4206422
MS
MSD
92697057001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
500
500
519
519
104
104
75-125
0
20
Arsenic
ug/L
ND
500
500
539
546
108
109
75-125
1
20
Barium
ug/L
85.6
500
500
617
619
106
107
75-125
0
20
Beryllium
ug/L
ND
500
500
521
523
104
105
75-125
0
20
Cadmium
ug/L
ND
500
500
533
535
107
107
75-125
0
20
Chromium
ug/L
3.3J
500
500
511
514
102
102
75-125
0
20
Cobalt
ug/L
48.2
500
500
562
565
103
103
75-125
1
20
Copper
ug/L
14.0
500
500
520
521
101
101
75-125
0
20
Hardness, Total(SM 2340B)
ug/L
24200
33100
33100
59600
59500
107
107
75-125
0
20
Iron
ug/L
4310
5000
5000
10700
10600
127
126
75-125
0
20 M1
Lead
ug/L
ND
500
500
512
514
102
103
75-125
0
20
Manganese
ug/L
1200
500
500
1800
1760
121
113
75-125
2
20
Nickel
ug/L
20.0
500
500
543
545
105
105
75-125
0
20
Selenium
ug/L
ND
500
500
529
530
106
106
75-125
0
20
Silver
ug/L
ND
250
250
249
250
99
100
75-125
1
20
Tin
ug/L
ND
500
500
534
539
107
108
75-125
1
20
Vanadium
ug/L
5.5
500
500
534
537
106
106
75-125
1
20
Zinc
ug/L
108
500
500
649
651
108
109
75-125
0
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 34 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 813065 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92698166001
METHOD BLANK: 4209654
Associated Lab Samples: 92698166001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
Antimony
ug/L
ND
5.0
3.6
11/16/2310:52
Arsenic
ug/L
ND
10.0
2.5
11/15/2312:12
Barium
ug/L
ND
5.0
0.79
11/15/2312:12
Beryllium
ug/L
ND
1.0
0.16
11/15/2312:12
Cadmium
ug/L
ND
1.0
0.29
11/15/2312:12
Chromium
ug/L
ND
5.0
0.63
11/15/2312:12
Cobalt
ug/L
ND
5.0
0.44
11/15/2312:12
Copper
ug/L
ND
5.0
0.62
11/15/2312:12
Iron
ug/L
ND
50.0
8.9
11/15/2312:12
Lead
ug/L
ND
5.0
1.4
11/15/2312:12
Manganese
ug/L
ND
5.0
0.86
11/15/2312:12
Nickel
ug/L
ND
5.0
0.88
11/15/2312:12
Selenium
ug/L
ND
10.0
4.1
11/16/2310:52
Silver
ug/L
ND
5.0
0.49
11/15/2312:12
Tin
ug/L
ND
5.0
2.0
11/15/2312:12
Vanadium
ug/L
ND
5.0
1.6
11/15/2312:12
Zinc
ug/L
ND
10.0
3.0
11/15/2312:12
LABORATORY CONTROL SAMPLE:
4209655
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Antimony
ug/L
500
513
103
80-120
Arsenic
ug/L
500
500
100
80-120
Barium
ug/L
500
552
110
80-120
Beryllium
ug/L
500
498
100
80-120
Cadmium
ug/L
500
500
100
80-120
Chromium
ug/L
500
504
101
80-120
Cobalt
ug/L
500
502
100
80-120
Copper
ug/L
500
504
101
80-120
Iron
ug/L
5000
5460
109
80-120
Lead
ug/L
500
503
101
80-120
Manganese
ug/L
500
549
110
80-120
Nickel
ug/L
500
498
100
80-120
Selenium
ug/L
500
505
101
80-120
Silver
ug/L
250
253
101
80-120
Tin
ug/L
500
500
100
80-120
Vanadium
ug/L
500
501
100
80-120
Zinc
ug/L
500
494
99
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 35 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
Burke Co. Johns R Background
92697340
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4209656
4209657
MS
MSD
92698207024
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
500
500
539
542
107
108
75-125
0
20
Arsenic
ug/L
ND
500
500
527
526
105
104
75-125
0
20
Barium
ug/L
98.7
500
500
634
620
107
104
75-125
2
20
Beryllium
ug/L
ND
500
500
523
521
104
104
75-125
0
20
Cadmium
ug/L
ND
500
500
515
514
103
103
75-125
0
20
Chromium
ug/L
ND
500
500
515
513
103
102
75-125
0
20
Cobalt
ug/L
31.2
500
500
534
535
101
101
75-125
0
20
Copper
ug/L
ND
500
500
518
520
103
103
75-125
0
20
Iron
ug/L
3570
5000
5000
8640
8300
101
95
75-125
4
20
Lead
ug/L
ND
500
500
510
509
102
102
75-125
0
20
Manganese
ug/L
1290
500
500
1840
1700
109
83
75-125
8
20
Nickel
ug/L
8.8
500
500
515
513
101
101
75-125
0
20
Selenium
ug/L
ND
500
500
554
560
111
112
75-125
1
20
Silver
ug/L
ND
250
250
259
258
104
103
75-125
0
20
Tin
ug/L
ND
500
500
515
514
103
102
75-125
0
20
Vanadium
ug/L
ND
500
500
516
514
103
102
75-125
0
20
Zinc
ug/L
43.1
500
500
556
553
103
102
75-125
1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 36 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 812425 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697340001, 92697345001
METHOD BLANK: 4206546 Matrix: Water
Associated Lab Samples: 92697340001, 92697345001
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Thallium ug/L ND 0.20 0.050 11/12/2318:46
LABORATORY CONTROL SAMPLE: 4206547
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Thallium ug/L 25 25.2 101 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4206548 4206549
MS MSD
92697334001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Thallium ug/L 0.49 25 25 26.7 26.4 105 104 75-125 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 37 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 812973 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92698166001
METHOD BLANK: 4209431
Matrix:
Water
Associated Lab Samples: 92698166001
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
Thallium
ug/L
ND
0.20
0.050 11/15/2317:03
LABORATORY CONTROL SAMPLE:
4209432
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Thallium
ug/L
25
27.4
110 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4209433 4209434
MS MSD
92698309003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Thallium ug/L ND 25 25 28.4 28.2 114 113 75-125 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 812467 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92697345001
METHOD BLANK: 4206844
Associated Lab Samples: 92697345001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
11/10/23 16:26
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
11/10/23 16:26
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
11/10/23 16:26
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
11/10/23 16:26
1,1-Dichloroethane
ug/L
ND
1.0
0.37
11/10/23 16:26
1,1-Dichloroethene
ug/L
ND
1.0
0.35
11/10/23 16:26
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
11/10/23 16:26
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
11/10/23 16:26
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
11/10/23 16:26
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
11/10/23 16:26
1,2-Dichloroethane
ug/L
ND
1.0
0.32
11/10/23 16:26
1,2-Dichloropropane
ug/L
ND
1.0
0.36
11/10/23 16:26
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
11/10/23 16:26
2-Butanone (MEK)
ug/L
ND
5.0
4.0
11/10/23 16:26
2-Hexanone
ug/L
ND
5.0
0.48
11/10/23 16:26
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
11/10/23 16:26
Acetone
ug/L
ND
25.0
5.1
11/10/23 16:26
Acrylonitrile
ug/L
ND
10.0
1.8
11/10/23 16:26
Benzene
ug/L
ND
1.0
0.34
11/10/23 16:26
Bromochloromethane
ug/L
ND
1.0
0.47
11/10/23 16:26
Bromodichloromethane
ug/L
ND
1.0
0.31
11/10/23 16:26
Bromoform
ug/L
ND
1.0
0.34
11/10/23 16:26
Bromomethane
ug/L
ND
2.0
1.7
11/10/23 16:26
Carbon disulfide
ug/L
ND
2.0
0.36
11/10/23 16:26
Carbon tetrachloride
ug/L
ND
1.0
0.33
11/10/23 16:26
Chlorobenzene
ug/L
ND
1.0
0.28
11/10/23 16:26
Chloroethane
ug/L
ND
1.0
0.65
11/10/23 16:26
Chloroform
ug/L
ND
1.0
0.43
11/10/23 16:26
Chloromethane
ug/L
ND
1.0
0.54
11/10/23 16:26
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
11/10/23 16:26
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
11/10/23 16:26
Dibromochloromethane
ug/L
ND
1.0
0.36
11/10/23 16:26
Dibromomethane
ug/L
ND
1.0
0.39
11/10/23 16:26
Ethylbenzene
ug/L
ND
1.0
0.30
11/10/23 16:26
lodomethane
ug/L
ND
20.0
9.7
11/10/23 16:26
Methylene Chloride
ug/L
ND
5.0
2.0
11/10/23 16:26
Styrene
ug/L
ND
1.0
0.29
11/10/23 16:26
Tetrachloroethene
ug/L
ND
1.0
0.29
11/10/23 16:26
Tetrahydrofuran
ug/L
ND
10.0
3.5
11/10/23 16:26
Toluene
ug/L
ND
1.0
0.24
11/10/23 16:26
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 39 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
METHOD BLANK: 4206844
Associated Lab Samples: 92697345001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
11/10/23 16:26
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
11/10/23 16:26
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
11/10/23 16:26
Trichloroethene
ug/L
ND
1.0
0.38
11/10/23 16:26
Trichlorofluoromethane
ug/L
ND
1.0
0.30
11/10/23 16:26
Vinyl acetate
ug/L
ND
2.0
1.3
11/10/23 16:26
Vinyl chloride
ug/L
ND
1.0
0.39
11/10/23 16:26
Xylene (Total)
ug/L
ND
1.0
0.34
11/10/23 16:26
1,2-Dichloroethane-d4 (S)
%
88
70-130
11/10/23 16:26
4-Bromofluorobenzene (S)
%
99
70-130
11/10/23 16:26
Toluene-d8 (S)
%
104
70-130
11/10/23 16:26
LABORATORY CONTROL SAMPLE:
4206845
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
20
19.6
98
70-130
1,1,1-Trichloroethane
ug/L
20
19.7
99
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
20.7
103
70-130
1,1,2-Trichloroethane
ug/L
20
21.2
106
70-130
1,1-Dichloroethane
ug/L
20
20.6
103
70-130
1,1-Dichloroethene
ug/L
20
20.3
102
69-131
1,2,3-Trichloropropane
ug/L
20
19.2
96
70-130
1,2-Dibromo-3-chloropropane
ug/L
20
21.0
105
70-130
1,2-Dibromoethane (EDB)
ug/L
20
20.5
102
70-130
1,2-Dichlorobenzene
ug/L
20
20.7
104
70-130
1,2-Dichloroethane
ug/L
20
18.4
92
70-130
1,2-Dichloropropane
ug/L
20
21.8
109
70-130
1,4-Dichlorobenzene
ug/L
20
20.0
100
70-130
2-Butanone (MEK)
ug/L
40
37.2
93
67-133
2-Hexanone
ug/L
40
43.3
108
70-133
4-Methyl-2-pentanone (MIBK)
ug/L
40
42.6
106
70-130
Acetone
ug/L
40
40.1
100
67-130
Acrylonitrile
ug/L
100
111
111
70-130
Benzene
ug/L
20
20.9
104
70-130
Bromochloromethane
ug/L
20
20.9
105
70-130
Bromodichloromethane
ug/L
20
19.4
97
70-130
Bromoform
ug/L
20
19.5
97
70-133
Bromomethane
ug/L
20
16.1
80
41-148
Carbon disulfide
ug/L
20
22.3
111
70-131
Carbon tetrachloride
ug/L
20
19.4
97
70-130
Chlorobenzene
ug/L
20
20.0
100
70-130
Chloroethane
ug/L
20
18.7
94
41-157
Chloroform
ug/L
20
20.1
100
70-130
Chloromethane
ug/L
20
24.0
120
59-141
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 90

Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
aceo Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
LABORATORY CONTROL SAMPLE:
Parameter
4206845
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
cis-1,2-Dichloroethene
ug/L
20
20.5
103
70-130
cis-1,3-Dichloropropene
ug/L
20
20.4
102
70-130
Dibromochloromethane
ug/L
20
20.1
100
70-130
Dibromomethane
ug/L
20
20.0
100
70-130
Ethylbenzene
ug/L
20
19.7
98
70-130
lodomethane
ug/L
40
36.5
91
57-140
Methylene Chloride
ug/L
20
21.2
106
62-130
Styrene
ug/L
20
20.4
102
70-130
Tetrachloroethene
ug/L
20
19.1
95
70-130
Tetrahydrofuran
ug/L
200
219
110
70-131
Toluene
ug/L
20
20.1
101
70-130
trans-1,2-Dichloroethene
ug/L
20
20.8
104
70-130
trans- 1,3-Dichloropropene
ug/L
20
19.7
98
70-130
trans-1,4-Dichloro-2-butene
ug/L
20
19.1
96
57-149
Trichloroethene
ug/L
20
19.6
98
70-130
Trichlorofluoromethane
ug/L
20
19.6
98
57-130
Vinyl acetate
ug/L
40
35.6
89
70-141
Vinyl chloride
ug/L
20
21.6
108
66-140
Xylene (Total)
ug/L
60
59.4
99
70-130
1,2-Dichloroethane-d4 (S)
%
90
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
102
70-130
MATRIX SPIKE SAMPLE:
Parameter
4206846
Units
92697345001
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
24.3
122
70-146
1,1,1-Trichloroethane
ug/L
ND
20
25.2
126
70-150
1,1,2,2-Tetrachloroethane
ug/L
ND
20
24.4
122
66-144
1,1,2-Trichloroethane
ug/L
ND
20
23.8
119
70-142
1,1-Dichloroethane
ug/L
1.3
20
25.8
123
68-150
1,1-Dichloroethene
ug/L
ND
20
25.9
130
64-162
1,2,3-Trichloropropane
ug/L
ND
20
22.7
114
66-144
1,2-Dibromo-3-chloropropane
ug/L
ND
20
23.5
118
62-146
1,2-Dibromoethane (EDB)
ug/L
ND
20
24.8
124
70-143
1,2-Dichlorobenzene
ug/L
ND
20
23.3
116
70-142
1,2-Dichloroethane
ug/L
ND
20
24.0
120
68-145
1,2-Dichloropropane
ug/L
ND
20
24.7
123
70-144
1,4-Dichlorobenzene
ug/L
ND
20
23.7
118
70-140
2-Butanone (MEK)
ug/L
ND
40
45.3
108
57-156
2-Hexanone
ug/L
ND
40
50.3
126
62-153
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
45.9
115
65-144
Acetone
ug/L
11.11
40
55.5
111
49-162
Acrylonitrile
ug/L
ND
100
118
118
59-155
Benzene
ug/L
ND
20
25.1
124
68-144
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
MATRIX SPIKE SAMPLE:
Parameter
4206846
Units
92697345001
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
Bromochloromethane
ug/L
ND
20
24.3
121
70-148
Bromodichloromethane
ug/L
ND
20
23.5
117
70-141
Bromoform
ug/L
ND
20
23.0
115
59-144
Bromomethane
ug/L
ND
20
21.9
109
23-190
Carbon disulfide
ug/L
ND
20
25.7
128
64-160
Carbon tetrachloride
ug/L
ND
20
25.0
125
70-147
Chlorobenzene
ug/L
ND
20
24.3
121
70-143
Chloroethane
ug/L
ND
20
24.1
120
55-190
Chloroform
ug/L
ND
20
24.7
124
67-148
Chloromethane
ug/L
ND
20
22.6
113
38-180
cis-1,2-Dichloroethene
ug/L
0.97J
20
25.3
122
67-151
cis-1,3-Dichloropropene
ug/L
ND
20
23.4
117
70-142
Dibromochloromethane
ug/L
ND
20
24.1
121
68-140
Dibromomethane
ug/L
ND
20
23.6
118
70-142
Ethylbenzene
ug/L
ND
20
24.1
121
70-145
lodomethane
ug/L
ND
40
42.6
107
37-160
Methylene Chloride
ug/L
ND
20
23.8
118
54-149
Styrene
ug/L
ND
20
24.5
122
70-147
Tetrachloroethene
ug/L
ND
20
23.1
115
70-145
Tetrahydrofuran
ug/L
ND
200
232
116
48-160
Toluene
ug/L
0.79J
20
24.7
120
65-146
trans-1,2-Dichloroethene
ug/L
ND
20
25.3
126
69-155
trans- 1,3-Dichloropropene
ug/L
ND
20
23.9
119
70-142
trans-1,4-Dichloro-2-butene
ug/L
ND
20
21.6
108
39-149
Trichloroethene
ug/L
0.44J
20
25.2
124
70-152
Trichlorofluoromethane
ug/L
ND
20
25.6
128
60-158
Vinyl acetate
ug/L
ND
40
41.0
103
56-157
Vinyl chloride
ug/L
ND
20
21.6
108
51-178
Xylene (Total)
ug/L
ND
60
72.6
121
70-146
1,2-Dichloroethane-d4 (S)
%
102
70-130
4-Bromofluorobenzene (S)
%
102
70-130
Toluene-d8 (S)
%
99
70-130
SAMPLE DUPLICATE: 4206847
Parameter
Units
92697346005
Result
Dup
Result RPD
Max
RPD Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,1-Trichloroethane
ug/L
ND
ND
30
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,2-Trichloroethane
ug/L
ND
ND
30
1,1-Dichloroethane
ug/L
0.44J
0.43J
30
1,1-Dichloroethene
ug/L
ND
ND
30
1,2,3-Trichloropropane
ug/L
ND
ND
30
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
30
1,2-Dibromoethane (EDB)
ug/L
ND
ND
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 42 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
SAMPLE DUPLICATE: 4206847
Parameter
Units
92697346005
Result
Dup
Result
1,2-Dichlorobenzene
ug/L
ND
ND
1,2-Dichloroethane
ug/L
ND
ND
1,2-Dichloropropane
ug/L
ND
ND
1,4-Dichlorobenzene
ug/L
ND
ND
2-Butanone (MEK)
ug/L
ND
ND
2-Hexanone
ug/L
ND
ND
4-Methyl-2-pentanone (MIBK)
ug/L
ND
ND
Acetone
ug/L
ND
ND
Acrylonitrile
ug/L
ND
ND
Benzene
ug/L
ND
ND
Bromochloromethane
ug/L
ND
ND
Bromodichloromethane
ug/L
ND
ND
Bromoform
ug/L
ND
ND
Bromomethane
ug/L
ND
ND
Carbon disulfide
ug/L
ND
ND
Carbon tetrachloride
ug/L
ND
ND
Chlorobenzene
ug/L
ND
ND
Chloroethane
ug/L
ND
ND
Chloroform
ug/L
ND
ND
Chloromethane
ug/L
ND
ND
cis-1,2-Dichloroethene
ug/L
2.8
2.8
cis-1,3-Dichloropropene
ug/L
ND
ND
Dibromochloromethane
ug/L
ND
ND
Dibromomethane
ug/L
ND
ND
Ethylbenzene
ug/L
ND
ND
lodomethane
ug/L
ND
ND
Methylene Chloride
ug/L
ND
ND
Styrene
ug/L
ND
ND
Tetrachloroethene
ug/L
0.31J
ND
Tetrahydrofuran
ug/L
ND
ND
Toluene
ug/L
ND
ND
trans-1,2-Dichloroethene
ug/L
ND
ND
trans- 1,3-Dichloropropene
ug/L
ND
ND
trans-1,4-Dichloro-2-butene
ug/L
ND
ND
Trichloroethene
ug/L
ND
ND
Trichlorofluoromethane
ug/L
ND
ND
Vinyl acetate
ug/L
ND
ND
Vinyl chloride
ug/L
ND
ND
Xylene (Total)
ug/L
ND
ND
1,2-Dichloroethane-d4 (S)
%
89
97
4-Bromofluorobenzene (S)
%
98
99
Toluene-d8(S)
%
102
104
Max
RPD RPD
0
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 43 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 812793 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92697340001, 92697340002
METHOD BLANK: 4208244
Associated Lab Samples: 92697340001, 92697340002
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
11/13/23 10:01
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
11/13/23 10:01
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
11/13/23 10:01
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
11/13/23 10:01
1,1-Dichloroethane
ug/L
ND
1.0
0.37
11/13/23 10:01
1,1-Dichloroethene
ug/L
ND
1.0
0.35
11/13/23 10:01
1,1-Dichloropropene
ug/L
ND
1.0
0.43
11/13/23 10:01
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
11/13/23 10:01
1,2,4-Trichlorobenzene
ug/L
ND
1.0
0.64
11/13/23 10:01
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
11/13/23 10:01
1,2-Dichloroethane
ug/L
ND
1.0
0.32
11/13/23 10:01
1,3-Dichlorobenzene
ug/L
ND
1.0
0.34
11/13/23 10:01
1,3-Dichloropropane
ug/L
ND
1.0
0.28
11/13/23 10:01
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
11/13/23 10:01
2,2-Dichloropropane
ug/L
ND
1.0
0.39
11/13/23 10:01
2-Butanone (MEK)
ug/L
ND
5.0
4.0
11/13/23 10:01
2-Hexanone
ug/L
ND
5.0
0.48
11/13/23 10:01
Acetone
ug/L
ND
25.0
5.1
11/13/23 10:01
Acetonitrile
ug/L
ND
50.0
24.8
11/13/23 10:01
Acrolein
ug/L
ND
10.0
8.5
11/13/23 10:01
Acrylonitrile
ug/L
ND
10.0
1.8
11/13/23 10:01
Allyl chloride
ug/L
ND
2.0
0.50
11/13/23 10:01
Benzene
ug/L
ND
1.0
0.34
11/13/23 10:01
Bromochloromethane
ug/L
ND
1.0
0.47
11/13/23 10:01
Bromodichloromethane
ug/L
ND
1.0
0.31
11/13/23 10:01
Bromoform
ug/L
ND
1.0
0.34
11/13/23 10:01
Bromomethane
ug/L
ND
2.0
1.7
11/13/23 10:01
Carbon disulfide
ug/L
ND
2.0
0.36
11/13/23 10:01
Carbon tetrachloride
ug/L
ND
1.0
0.33
11/13/23 10:01
Chlorobenzene
ug/L
ND
1.0
0.28
11/13/23 10:01
Chloroethane
ug/L
ND
1.0
0.65
11/13/23 10:01
Chloroform
ug/L
ND
1.0
0.43
11/13/23 10:01
Chloromethane
ug/L
ND
1.0
0.54
11/13/23 10:01
Chloroprene
ug/L
ND
5.0
1.6
11/13/23 10:01
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
11/13/23 10:01
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
11/13/23 10:01
Dibromochloromethane
ug/L
ND
1.0
0.36
11/13/23 10:01
Dichlorodifluoromethane
ug/L
ND
1.0
0.35
11/13/23 10:01
Ethyl methacrylate
ug/L
ND
1.0
0.28
11/13/23 10:01
Ethylbenzene
ug/L
ND
1.0
0.30
11/13/23 10:01
v1
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 44 of 90

Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
aceo Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
METHOD BLANK: 4208244
Associated Lab Samples: 92697340001, 92697340002
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
Hexachloro-1,3-butadiene
ug/L
ND
2.0
1.5
11/13/23 10:01
lodomethane
ug/L
ND
20.0
9.7
11/13/23 10:01
Isobutanol
ug/L
ND
100
52.3
11/13/23 10:01
Methacrylonitrile
ug/L
ND
10.0
4.2
11/13/23 10:01
Methyl methacrylate
ug/L
ND
2.0
0.32
11/13/23 10:01
Methylene Chloride
ug/L
ND
5.0
2.0
11/13/23 10:01
Naphthalene
ug/L
ND
1.0
0.64
11/13/23 10:01
Propionitrile
ug/L
ND
20.0
3.6
11/13/23 10:01
Styrene
ug/L
ND
1.0
0.29
11/13/23 10:01
Tetrachloroethene
ug/L
ND
1.0
0.29
11/13/23 10:01
Toluene
ug/L
ND
1.0
0.24
11/13/23 10:01
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
11/13/23 10:01
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
11/13/23 10:01
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
11/13/23 10:01
Trichloroethene
ug/L
ND
1.0
0.38
11/13/23 10:01
Trichlorofluoromethane
ug/L
ND
1.0
0.30
11/13/23 10:01
Vinyl acetate
ug/L
ND
2.0
1.3
11/13/23 10:01
Vinyl chloride
ug/L
ND
1.0
0.39
11/13/23 10:01
Xylene (Total)
ug/L
ND
1.0
0.34
11/13/23 10:01
1,2-Dichloroethane-d4 (S)
%
95
70-130
11/13/23 10:01
4-Bromofluorobenzene (S)
%
100
70-130
11/13/23 10:01
Toluene-d8 (S)
%
101
70-130
11/13/23 10:01
LABORATORY CONTROL SAMPLE:
Parameter
4208245
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
20
22.6
113
70-130
1,1,1-Trichloroethane
ug/L
20
23.3
116
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
21.2
106
70-130
1,1,2-Trichloroethane
ug/L
20
22.1
111
70-130
1,1-Dichloroethane
ug/L
20
22.4
112
70-130
1,1-Dichloroethene
ug/L
20
24.4
122
69-131
1,1-Dichloropropene
ug/L
20
25.1
125
70-132
1,2,3-Trichloropropane
ug/L
20
20.2
101
70-130
1,2,4-Trichlorobenzene
ug/L
20
23.7
119
70-130
1,2-Dichlorobenzene
ug/L
20
22.4
112
70-130
1,2-Dichloroethane
ug/L
20
20.3
102
70-130
1,3-Dichlorobenzene
ug/L
20
22.8
114
70-130
1,3-Dichloropropane
ug/L
20
20.9
104
70-130
1,4-Dichlorobenzene
ug/L
20
23.1
116
70-130
2,2-Dichloropropane
ug/L
20
25.6
128
69-130 v1
2-Butanone (MEK)
ug/L
40
39.2
98
67-133
2-Hexanone
ug/L
40
41.2
103
70-133
Acetone
ug/L
40
38.8
97
67-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
LABORATORY CONTROL SAMPLE:
Parameter
4208245
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Acetonitrile
ug/L
200
193
97
70-130
Acrolein
ug/L
100
104
104
53-166
Acrylonitrile
ug/L
100
104
104
70-130
Allyl chloride
ug/L
20
22.8
114
69-130
Benzene
ug/L
20
22.5
113
70-130
Bromochloromethane
ug/L
20
21.6
108
70-130
Bromodichloromethane
ug/L
20
21.3
107
70-130
Bromoform
ug/L
20
22.2
111
70-133
Bromomethane
ug/L
20
20.0
100
41-148
Carbon disulfide
ug/L
20
24.6
123
70-131
Carbon tetrachloride
ug/L
20
23.7
118
70-130
Chlorobenzene
ug/L
20
22.5
113
70-130
Chloroethane
ug/L
20
23.6
118
41-157
Chloroform
ug/L
20
21.2
106
70-130
Chloromethane
ug/L
20
20.9
104
59-141
Chloroprene
ug/L
20
23.3
116
70-130
cis-1,2-Dichloroethene
ug/L
20
22.1
110
70-130
cis-1,3-Dichloropropene
ug/L
20
22.7
113
70-130
Dibromochloromethane
ug/L
20
21.9
110
70-130
Dichlorodifluoromethane
ug/L
20
23.3
116
54-147
Ethyl methacrylate
ug/L
20
21.1
106
70-130
Ethylbenzene
ug/L
20
22.8
114
70-130
Hexachloro-1,3-butadiene
ug/L
20
24.9
125
70-134
lodomethane
ug/L
40
44.6
112
57-140
Isobutanol
ug/L
400
326
82
67-136
Methacrylonitrile
ug/L
200
200
100
70-130
Methyl methacrylate
ug/L
20
19.9
99
70-130
Methylene Chloride
ug/L
20
20.7
103
62-130
Naphthalene
ug/L
20
23.7
119
70-135
Propionitrile
ug/L
200
194
97
70-130
Styrene
ug/L
20
22.9
115
70-130
Tetrachloroethene
ug/L
20
23.9
120
70-130
Toluene
ug/L
20
22.2
111
70-130
trans-1,2-Dichloroethene
ug/L
20
22.7
114
70-130
trans- 1,3-Dichloropropene
ug/L
20
22.5
113
70-130
trans-1,4-Dichloro-2-butene
ug/L
20
20.6
103
57-149
Trichloroethene
ug/L
20
23.7
119
70-130
Trichlorofluoromethane
ug/L
20
24.1
121
57-130
Vinyl acetate
ug/L
40
45.5
114
70-141
Vinyl chloride
ug/L
20
20.7
103
66-140
Xylene (Total)
ug/L
60
68.8
115
70-130
1,2-Dichloroethane-d4 (S)
%
95
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8 (S)
%
100
70-130
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 46 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4208246
4208247
MS
MSD
92697827007
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
24.8
24.8
124
124
70-146
0
30
1,1,1-Trichloroethane
ug/L
ND
20
20
26.9
25.5
135
128
70-150
5
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
23.1
23.0
115
115
66-144
0
30
1,1,2-Trichloroethane
ug/L
ND
20
20
24.1
23.6
120
118
70-142
2
30
1,1-Dichloroethane
ug/L
ND
20
20
25.6
24.5
128
122
68-150
4
30
1,1-Dichloroethene
ug/L
ND
20
20
28.0
27.3
140
136
64-162
3
30
1,1-Dichloropropene
ug/L
ND
20
20
28.8
27.3
144
136
70-160
6
30
1,2,3-Trichloropropane
ug/L
ND
20
20
21.8
21.3
109
106
66-144
2
30
1,2,4-Trichlorobenzene
ug/L
ND
20
20
26.6
25.8
133
129
69-147
3
30
1,2-Dichlorobenzene
ug/L
ND
20
20
25.2
24.1
126
121
70-142
4
30
1,2-Dichloroethane
ug/L
ND
20
20
22.8
21.3
114
106
68-145
7
30
1,3-Dichlorobenzene
ug/L
ND
20
20
25.9
24.6
129
123
70-142
5
30
1,3-Dichloropropane
ug/L
ND
20
20
22.9
22.1
115
111
70-141
4
30
1,4-Dichlorobenzene
ug/L
ND
20
20
25.8
24.5
129
123
70-140
5
30
2,2-Dichloropropane
ug/L
ND
20
20
29.0
27.7
145
138
58-160
5
30
2-Butanone (MEK)
ug/L
ND
40
40
43.2
41.8
108
104
57-156
3
30
2-Hexanone
ug/L
ND
40
40
44.0
44.0
110
110
62-153
0
30
Acetone
ug/L
ND
40
40
39.5
37.9
99
95
49-162
4
30
Acetonitrile
ug/L
ND
200
200
204
205
102
103
69-145
1
30
Acrolein
ug/L
ND
100
100
114
114
114
114
10-200
0
30
Acrylonitrile
ug/L
ND
100
100
118
111
118
111
59-155
7
30
Allyl chloride
ug/L
ND
20
20
25.2
24.0
126
120
70-146
5
30
Benzene
ug/L
ND
20
20
25.1
24.9
125
124
68-144
1
30
Bromochloromethane
ug/L
ND
20
20
24.7
22.6
124
113
70-148
9
30
Bromodichloromethane
ug/L
ND
20
20
23.9
22.8
120
114
70-141
5
30
Bromoform
ug/L
ND
20
20
23.5
23.1
118
116
59-144
2
30
Bromomethane
ug/L
ND
20
20
23.2
22.6
116
113
23-190
3
30
Carbon disulfide
ug/L
ND
20
20
28.4
26.9
142
134
64-160
6
30
Carbon tetrachloride
ug/L
ND
20
20
27.0
26.8
135
134
70-147
1
30
Chlorobenzene
ug/L
ND
20
20
25.2
24.3
126
122
70-143
4
30
Chloroethane
ug/L
ND
20
20
27.9
26.7
140
134
55-190
4
30
Chloroform
ug/L
ND
20
20
25.0
24.2
125
121
67-148
3
30
Chloromethane
ug/L
ND
20
20
25.2
23.4
126
117
38-180
7
30
Chloroprene
ug/L
ND
20
20
26.2
25.3
131
127
70-148
4
30
cis-1,2-Dichloroethene
ug/L
ND
20
20
25.0
23.7
125
118
67-151
6
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
24.3
23.5
122
117
70-142
3
30
Dibromochloromethane
ug/L
ND
20
20
23.6
23.0
118
115
68-140
2
30
Dichlorodifluoromethane
ug/L
ND
20
20
26.0
25.2
130
126
15-200
3
30
Ethyl methacrylate
ug/L
ND
20
20
22.6
21.8
113
109
68-139
4
30
Ethylbenzene
ug/L
ND
20
20
25.4
24.8
127
124
70-145
3
30
Hexachloro-1,3-butadiene
ug/L
ND
20
20
28.6
28.2
143
141
64-164
1
30
lodomethane
ug/L
ND
40
40
49.7
48.0
124
120
37-160
3
30
Isobutanol
ug/L
ND
400
400
373
363
93
91
53-152
3
30 v3
Methacrylonitrile
ug/L
ND
200
200
217
211
109
106
70-137
3
30
Methyl methacrylate
ug/L
ND
20
20
22.2
21.6
111
108
69-134
3
30
Methylene Chloride
ug/L
ND
20
20
23.3
22.4
117
112
54-149
4
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 47 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 4208246
4208247
MS
MSD
92697827007
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Naphthalene
ug/L
ND
20
20
25.1
24.6
126
123
62-154
2
30
Propionitrile
ug/L
ND
200
200
218
208
109
104
70-136
5
30
Styrene
ug/L
ND
20
20
25.3
24.5
127
123
70-147
3
30
Tetrachloroethene
ug/L
ND
20
20
26.5
25.0
133
125
70-145
6
30
Toluene
ug/L
ND
20
20
24.9
24.1
124
121
65-146
3
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
26.8
24.7
134
124
69-155
8
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
24.0
23.3
120
116
70-142
3
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
22.9
22.5
115
112
39-149
2
30
Trichloroethene
ug/L
ND
20
20
26.5
25.9
133
129
70-152
3
30
Trichlorofluoromethane
ug/L
ND
20
20
27.3
26.4
137
132
60-158
4
30
Vinyl acetate
ug/L
ND
40
40
49.2
46.5
123
116
56-157
6
30
Vinyl chloride
ug/L
ND
20
20
24.1
23.2
120
116
51-178
4
30
Xylene (Total)
ug/L
ND
60
60
75.8
74.4
126
124
70-146
2
30
1,2-Dichloroethane-d4 (S)
%
90
87
70-130
4-Bromofluorobenzene (S)
%
98
100
70-130
Toluene-d8 (S)
%
98
99
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 48 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 812181 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92697340001, 92697345001
METHOD BLANK: 4205427
Matrix:
Water
Associated Lab Samples:
92697340001, 92697345001
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
0.86 11/10/23 01:48
1,2-Dichloroethane-d4 (S)
%
91
67-130
11/10/23 01:48
Toluene-d8 (S)
%
92
70-130
11/10/23 01:48
LABORATORY CONTROL SAMPLE: 4205428
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane(p-Dioxane) ug/L 20 19.6 98 70-130
1,2-Dichloroethane-d4 (S) % 90 67-130
Toluene-d8 (S) % 92 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4205429
4205430
MS
MSD
92697334001 Spike
Spike MS MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result Result
% Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane(p-Dioxane)
ug/L 1.01 20
20 19.4 19.8
92
94
55-137
2 30
1,2-Dichloroethane-d4 (S)
%
88
88
67-130
30
Toluene-d8 (S)
%
97
97
70-130
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 49 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 812926 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92698166001
METHOD BLANK: 4209218
Matrix:
Water
Associated Lab Samples: 92698166001
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
0.86 11/13/23 18:55
1,2-Dichloroethane-d4 (S)
%
90
67-130
11/13/23 18:55
Toluene-d8 (S)
%
92
70-130
11/13/23 18:55
LABORATORY CONTROL SAMPLE: 4209219
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 20 24.9 124 70-130
1,2-Dichloroethane-d4 (S) % 92 67-130
Toluene-d8 (S) % 92 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4209220
4209221
MS
MSD
92698167001 Spike
Spike MS MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result Result
% Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane (p-Dioxane)
ug/L ND 20
20 24.3 28.8
121
143
55-137
17 30 M1
1,2-Dichloroethane-d4 (S)
%
95
96
67-130
30
Toluene-d8 (S)
%
96
98
70-130
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 50 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 811670 Analysis Method: EPA 8081 B
QC Batch Method: EPA 3510C Analysis Description: 8081 OC Pesticides Red Vol
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92697340001
METHOD BLANK: 4202442
Associated Lab Samples: 92697340001
Parameter
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
Chlordane (Technical)
delta-BHC
Dieldrin
Endosulfan I
Endosulfan 11
Endosulfan sulfate
Endrin
Endrin aldehyde
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
Decachlorobiphenyl (S)
Tetrachloro-m-xylene (S)
Matrix: Water
Units
Blank
Result
Reporting
Limit
MDL
Analyzed
ug/L
ND
0.050
0.017
11/09/2313:06
ug/L
ND
0.050
0.024
11/09/2313:06
ug/L
ND
0.050
0.026
11/09/2313:06
ug/L
ND
0.050
0.014
11/09/2313:06
ug/L
ND
0.050
0.012
11/09/2313:06
ug/L
ND
0.050
0.049
11/09/2313:06
ug/L
ND
0.50
0.16
11/09/2313:06
ug/L
ND
0.050
0.014
11/09/2313:06
ug/L
ND
0.050
0.015
11/09/2313:06
ug/L
ND
0.050
0.017
11/09/2313:06
ug/L
ND
0.050
0.016
11/09/2313:06
ug/L
ND
0.050
0.015
11/09/2313:06
ug/L
ND
0.050
0.018
11/09/2313:06
ug/L
ND
0.050
0.016
11/09/2313:06
ug/L
ND
0.050
0.012
11/09/2313:06
ug/L
ND
0.050
0.020
11/09/2313:06
ug/L
ND
0.050
0.028
11/09/2313:06
ug/L
ND
0.15
0.042
11/09/2313:06
ug/L
ND
0.50
0.22
11/09/2313:06
%
106
19-200
11 /09/23 13:06
%
89
10-137
11 /09/23 13:06
LABORATORY CONTROL SAMPLE: 4202443
Qualifiers
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
4,4'-DDD
ug/L
0.25
0.39
156
27-195
4,4'-DDE
ug/L
0.25
0.35
142
24-178
4,4'-DDT
ug/L
0.25
0.31
125
25-200
Aldrin
ug/L
0.25
0.28
113
14-135
alpha-BHC
ug/L
0.25
0.29
114
30-146
beta-BHC
ug/L
0.25
0.29
116
38-158
delta-BHC
ug/L
0.25
0.26
104
10-185
Dieldrin
ug/L
0.25
0.35
139
26-180
Endosulfan I
ug/L
0.25
0.28
112
36-154
Endosulfan II
ug/L
0.25
0.29
117
38-155
Endosulfan sulfate
ug/L
0.25
0.26
105
42-170
Endrin
ug/L
0.25
0.36
144
33-190
Endrin aldehyde
ug/L
0.25
0.24
97
33-153
gamma-BHC (Lindane)
ug/L
0.25
0.28
114
32-148
Results presented on
this page are in the units
indicated by the "Units"
column except
where an alternate unit
is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 51 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
LABORATORY CONTROL SAMPLE:
4202443
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Heptachlor
ug/L
0.25
0.35
138
32-149
Heptachlor epoxide
ug/L
0.25
0.29
118
37-149
Methoxychlor
ug/L
0.75
0.78
104
35-171
Decachlorobiphenyl (S)
%
94
19-200
Tetrachloro-m-xylene (S)
%
94
10-137
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
4202444
4202445
MS
MSD
92697329005
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
4,4'-DDD
ug/L
ND
0.5
0.5
0.76
0.71
151
141
10-200
7
30
4,4'-DDE
ug/L
ND
0.5
0.5
0.69
0.66
139
131
10-188
5
30
4,4'-DDT
ug/L
ND
0.5
0.5
0.66
0.61
131
122
10-200
7
30
Aldrin
ug/L
ND
0.5
0.5
0.56
0.51
112
102
10-144
10
30
alpha-BHC
ug/L
ND
0.5
0.5
0.56
0.53
112
106
21-151
5
30
beta-BHC
ug/L
ND
0.5
0.5
0.57
0.53
113
106
21-175
7
30
delta-BHC
ug/L
ND
0.5
0.5
0.50
0.46
100
92
15-163
8
30
Dieldrin
ug/L
ND
0.5
0.5
0.60
0.57
120
115
10-184
4
30
Endosulfan I
ug/L
ND
0.5
0.5
0.52
0.48
105
95
11-180
10
30
Endosulfan II
ug/L
ND
0.5
0.5
0.58
0.54
116
108
13-174
7
30
Endosulfan sulfate
ug/L
ND
0.5
0.5
0.57
0.54
114
108
25-182
6
30
Endrin
ug/L
ND
0.5
0.5
0.70
0.66
141
132
10-200
6
30
Endrin aldehyde
ug/L
ND
0.5
0.5
0.52
0.48
105
97
10-167
8
30
gamma-BHC (Lindane)
ug/L
ND
0.5
0.5
0.55
0.51
110
103
13-163
7
30
Heptachlor
ug/L
ND
0.5
0.5
0.70
0.67
141
134
10-172
5
30
Heptachlor epoxide
ug/L
ND
0.5
0.5
0.52
0.50
105
101
10-168
4
30
Methoxychlor
ug/L
ND
1.5
1.5
1.7
1.6
112
109
13-183
2
30
Decachlorobiphenyl (S)
%
72
84
19-200
Tetrachloro-m-xylene (S)
%
106
96
10-137
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 52 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 812712 Analysis Method: EPA 8081 B
QC Batch Method: EPA 3510C Analysis Description: 8081 OC Pesticides Red Vol
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92698166001
METHOD BLANK: 4208031
Associated Lab Samples: 92698166001
Parameter
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
Chlordane (Technical)
delta-BHC
Dieldrin
Endosulfan I
Endosulfan 11
Endosulfan sulfate
Endrin
Endrin aldehyde
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
Decachlorobiphenyl (S)
Tetrachloro-m-xylene (S)
Matrix: Water
Blank
Reporting
Units
Result
Limit
MDL
Analyzed
ug/L
ND
0.050
0.017
11/16/2316:01
ug/L
ND
0.050
0.024
11/16/2316:01
ug/L
ND
0.050
0.026
11/16/2316:01
ug/L
ND
0.050
0.014
11/16/2316:01
ug/L
ND
0.050
0.012
11/16/2316:01
ug/L
ND
0.050
0.049
11/16/2316:01
ug/L
ND
0.50
0.16
11/16/2316:01
ug/L
ND
0.050
0.014
11/16/2316:01
ug/L
ND
0.050
0.015
11/16/2316:01
ug/L
ND
0.050
0.017
11/16/2316:01
ug/L
ND
0.050
0.016
11/16/2316:01
ug/L
ND
0.050
0.015
11/16/2316:01
ug/L
ND
0.050
0.018
11/16/2316:01
ug/L
ND
0.050
0.016
11/16/2316:01
ug/L
ND
0.050
0.012
11/16/2316:01
ug/L
ND
0.050
0.020
11/16/2316:01
ug/L
ND
0.050
0.028
11/16/2316:01
ug/L
ND
0.15
0.042
11/16/2316:01
ug/L
ND
0.50
0.22
11/16/2316:01
%
184
19-200
11 /16/23 16:01
%
140
10-137
11/16/2316:01 S3
LABORATORY CONTROL SAMPLE: 4208032
Qualifiers
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
4,4'-DDD
ug/L
0.25
0.52
207
27-195 L1
4,4'-DDE
ug/L
0.25
0.50
199
24-178 L1
4,4'-DDT
ug/L
0.25
0.51
205
25-200 L1
Aldrin
ug/L
0.25
0.38
151
14-135 L1
alpha-BHC
ug/L
0.25
0.39
156
30-146 L1
beta-BHC
ug/L
0.25
0.39
157
38-158
delta-BHC
ug/L
0.25
0.36
144
10-185
Dieldrin
ug/L
0.25
0.49
195
26-180 L1
Endosulfan I
ug/L
0.25
0.38
151
36-154
Endosulfan II
ug/L
0.25
0.41
162
38-155 L1
Endosulfan sulfate
ug/L
0.25
0.39
157
42-170
Endrin
ug/L
0.25
0.51
203
33-190 L1
Endrin aldehyde
ug/L
0.25
0.38
152
33-153
gamma-BHC (Lindane)
ug/L
0.25
0.39
156
32-148 L1
Results presented on
this page are in the units
indicated by the "Units"
column except
where an alternate unit
is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 53 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
LABORATORY CONTROL SAMPLE:
4208032
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Heptachlor
ug/L
0.25
0.40
160
32-149 L1
Heptachlor epoxide
ug/L
0.25
0.37
149
37-149
Methoxychlor
ug/L
0.75
1.2
163
35-171
Decachlorobiphenyl (S)
%
155
19-200
Tetrachloro-m-xylene (S)
%
135
10-137
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
4208033
4208034
MS
MSD
92698127033
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
4,4'-DDD
ug/L
<0.050
0.5
0.5
1.1
1.0
215
209
10-200
3
30 MO
4,4'-DDE
ug/L
<0.050
0.5
0.5
1.0
1.0
207
207
10-188
0
30 MO
4,4'-DDT
ug/L
<0.050
0.5
0.5
1.2
1.1
231
226
10-200
2
30 MO
Aldrin
ug/L
<0.050
0.5
0.5
0.64
0.63
128
125
10-144
2
30
alpha-BHC
ug/L
<0.050
0.5
0.5
0.84
0.80
168
160
21-151
5
30 MO
beta-BHC
ug/L
<0.050
0.5
0.5
2.2
2.2
440
437
21-175
1
30 M1
delta-BHC
ug/L
<0.050
0.5
0.5
0.78
0.73
157
147
15-163
6
30
Dieldrin
ug/L
<0.050
0.5
0.5
1.0
0.99
202
199
10-184
2
30 MO
Endosulfan I
ug/L
<0.050
0.5
0.5
0.73
0.75
147
150
11-180
2
30
Endosulfan II
ug/L
<0.050
0.5
0.5
0.88
0.86
176
171
13-174
3
30 MO
Endosulfan sulfate
ug/L
<0.050
0.5
0.5
1.2
1.1
232
221
25-182
5
30 M1
Endrin
ug/L
<0.050
0.5
0.5
1.1
1.0
216
209
10-200
4
30 MO
Endrin aldehyde
ug/L
<0.050
0.5
0.5
2.1
2.0
427
400
10-167
6
30 M1
gamma-BHC (Lindane)
ug/L
<0.050
0.5
0.5
0.88
0.84
175
168
13-163
4
30 MO
Heptachlor
ug/L
<0.050
0.5
0.5
0.76
0.77
152
153
10-172
1
30
Heptachlor epoxide
ug/L
<0.050
0.5
0.5
0.94
0.91
188
182
10-168
3
30 M1
Methoxychlor
ug/L
<0.15
1.5
1.5
2.5
2.5
167
166
13-183
1
30
Decachlorobiphenyl (S)
%
177
170
19-200
Tetrachloro-m-xylene (S)
%
144
130
10-137
SO
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 54 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 812713 Analysis Method: EPA 8082A
QC Batch Method: EPA 3510C Analysis Description: 8082 GCS PCB
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92698166001
METHOD BLANK: 4208035
Matrix:
Water
Associated Lab Samples: 92698166001
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
PCB-1016 (Aroclor 1016)
ug/L
ND
0.50
0.21
11/17/23 01:55
PCB-1221 (Aroclor 1221)
ug/L
ND
0.50
0.23
11/17/23 01:55
PCB-1232 (Aroclor 1232)
ug/L
ND
0.50
0.23
11/17/23 01:55
PCB-1242 (Aroclor 1242)
ug/L
ND
0.50
0.25
11/17/23 01:55
PCB-1248 (Aroclor 1248)
ug/L
ND
0.50
0.29
11/17/23 01:55
PCB-1254 (Aroclor 1254)
ug/L
ND
0.50
0.21
11/17/23 01:55
PCB-1260 (Aroclor 1260)
ug/L
ND
0.50
0.16
11/17/23 01:55
Decachlorobiphenyl (S)
%
171
10-193
11/17/23 01:55
LABORATORY CONTROL SAMPLE: 4208036
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
PCB-1016 (Aroclor 1016) ug/L 5 5.0 100 34-137
PCB-1260 (Aroclor 1260) ug/L 5 2.6 52 39-145
Decachlorobiphenyl (S) % 146 10-193
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4208037
4208038
MS
MSD
92698127033 Spike
Spike MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result Conc.
Conc. Result
Result
% Rec
% Rec
Limits
RPD RPD Qual
PCB-1016 (Aroclor 1016)
ug/L
<0.50 10
10 15.1
17.1
151
171
10-153
12 30 M1
PCB-1260 (Aroclor 1260)
ug/L
<0.50 10
10 4.8
4.8
48
48
10-156
0 30
Decachlorobiphenyl (S)
%
154
161
10-193
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 55 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 812855 Analysis Method: EPA 8082A
QC Batch Method: EPA 3510C Analysis Description: 8082 GCS PCB
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92697340001
METHOD BLANK: 4208686
Matrix:
Water
Associated Lab Samples: 92697340001
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
PCB-1016 (Aroclor 1016)
ug/L
ND
0.50
0.21
11/14/23 12:39
PCB-1221 (Aroclor 1221)
ug/L
ND
0.50
0.23
11/14/23 12:39
PCB-1232 (Aroclor 1232)
ug/L
ND
0.50
0.23
11/14/23 12:39
PCB-1242 (Aroclor 1242)
ug/L
ND
0.50
0.25
11/14/23 12:39
PCB-1248 (Aroclor 1248)
ug/L
ND
0.50
0.29
11/14/23 12:39
PCB-1254 (Aroclor 1254)
ug/L
ND
0.50
0.21
11/14/23 12:39
PCB-1260 (Aroclor 1260)
ug/L
ND
0.50
0.16
11/14/23 12:39
Decachlorobiphenyl (S)
%
138
10-193
11/14/23 12:39
LABORATORY CONTROL SAMPLE: 4208687
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
PCB-1016 (Aroclor 1016) ug/L 4.2 2.8 67 34-137
PCB-1260 (Aroclor 1260) ug/L 4.2 2.7 65 39-145
Decachlorobiphenyl (S) % 104 10-193
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4208688
4208689
MS
MSD
92697649004 Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD RPD Qual
PCB-1016 (Aroclor 1016)
ug/L ND 8.3
8.3
8.4
9.5
100
114
10-153
12 30
PCB-1260 (Aroclor 1260)
ug/L ND 8.3
8.3
8.2
9.4
98
113
10-156
14 30
Decachlorobiphenyl (S)
%
130
160
10-193
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 56 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 811997 Analysis Method: EPA 8270E
QC Batch Method: EPA 3510C Analysis Description: 8270E Water APP9 RV MSSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92697340001
METHOD BLANK: 4204406
Associated Lab Samples: 92697340001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
1,2,4,5-Tetrachlorobenzene
ug/L
ND
10.0
4.5
11/12/23 12:55
1,3,5-Trinitrobenzene
ug/L
ND
10.0
5.5
11/12/23 12:55
1,3-Dinitrobenzene
ug/L
ND
10.0
3.8
11/12/23 12:55
1,4-Naphthoquinone
ug/L
ND
5.0
4.4
11/12/23 12:55
1-Naphthalenamine
ug/L
ND
10.0
6.0
11/12/23 12:55
2,2'-Oxybis(1-chloropropane)
ug/L
ND
10.0
1.2
11/12/23 12:55
2,3,4,6-Tetrachlorophenol
ug/L
ND
10.0
1.5
11/12/23 12:55
2,4,5-Trichlorophenol
ug/L
ND
10.0
1.4
11/12/23 12:55
2,4,6-Trichlorophenol
ug/L
ND
10.0
1.6
11/12/23 12:55
2,4-Dichlorophenol
ug/L
ND
10.0
1.4
11/12/23 12:55
2,4-Dimethylphenol
ug/L
ND
10.0
1.7
11/12/23 12:55
2,4-Dinitrophenol
ug/L
ND
50.0
26.0
11/12/23 12:55
2,4-Dinitrotoluene
ug/L
ND
10.0
1.6
11/12/23 12:55
2,6-Dichlorophenol
ug/L
ND
10.0
4.2
11/12/23 12:55
2,6-Dinitrotoluene
ug/L
ND
10.0
1.7
11/12/23 12:55
2-Acetylaminofluorene
ug/L
ND
10.0
4.1
11/12/23 12:55
2-Chloronaphthalene
ug/L
ND
10.0
1.7
11/12/23 12:55
2-Chlorophenol
ug/L
ND
10.0
1.2
11/12/23 12:55
2-Methylnaphthalene
ug/L
ND
10.0
1.9
11/12/23 12:55
2-Methylphenol(o-Cresol)
ug/L
ND
10.0
1.9
11/12/23 12:55
2-Naphthalenamine
ug/L
ND
10.0
5.4
11/12/23 12:55
2-Nitroaniline
ug/L
ND
20.0
3.0
11/12/23 12:55
2-Nitrophenol
ug/L
ND
10.0
1.4
11/12/23 12:55
3&4-Methyl phenol (m&p Cresol)
ug/L
ND
10.0
1.2
11/12/23 12:55
3,3'-Dichlorobenzidine
ug/L
ND
20.0
8.1
11/12/23 12:55
3,3'-Dimethylbenzidine
ug/L
ND
50.0
31.1
11/12/23 12:55
3-Methylcholanthrene
ug/L
ND
10.0
3.7
11/12/23 12:55
3-Nitroaniline
ug/L
ND
20.0
3.8
11/12/23 12:55
4,6-Dinitro-2-methyl phenol
ug/L
ND
20.0
7.8
11/12/23 12:55
4-Aminobiphenyl
ug/L
ND
10.0
4.7
11/12/23 12:55
4-Bromophenylphenyl ether
ug/L
ND
10.0
1.8
11/12/23 12:55
4-ChIoro-3-methyl phenol
ug/L
ND
10.0
3.3
11/12/23 12:55
4-Chloroaniline
ug/L
ND
20.0
3.6
11/12/23 12:55
4-Chlorophenylphenyl ether
ug/L
ND
10.0
2.0
11/12/23 12:55
4-Nitroaniline
ug/L
ND
20.0
5.1
11/12/23 12:55
4-Nitrophenol
ug/L
ND
50.0
6.6
11/12/23 12:55
5-Nitro-o-toluidine
ug/L
ND
10.0
3.8
11/12/23 12:55
7,12-Dimethylbenz(a)anthracene
ug/L
ND
10.0
3.0
11/12/23 12:55
Acenaphthene
ug/L
ND
10.0
2.0
11/12/23 12:55
Acenaphthylene
ug/L
ND
10.0
2.0
11/12/23 12:55
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 57 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
METHOD BLANK: 4204406
Associated Lab Samples: 92697340001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Acetophenone
ug/L
ND
10.0
1.5
11/12/23 12:55
Anthracene
ug/L
ND
10.0
2.3
11/12/23 12:55
Benzo(a)anthracene
ug/L
ND
10.0
2.7
11/12/23 12:55
Benzo(a)pyrene
ug/L
ND
10.0
2.8
11/12/23 12:55
Benzo(b)fluoranthene
ug/L
ND
10.0
2.6
11/12/23 12:55
Benzo(g,h,i)perylene
ug/L
ND
10.0
2.8
11/12/23 12:55
Benzo(k)fluoranthene
ug/L
ND
10.0
2.7
11/12/23 12:55
Benzyl alcohol
ug/L
ND
20.0
2.9
11/12/23 12:55
bis(2-Chloroethoxy)methane
ug/L
ND
10.0
1.8
11/12/23 12:55
bis(2-Chloroethyl) ether
ug/L
ND
10.0
1.9
11/12/23 12:55
bis(2-Ethylhexyl)phthalate
ug/L
ND
6.0
3.7
11/12/23 12:55
Butylbenzylphthalate
ug/L
ND
10.0
3.1
11/12/23 12:55
Chlorobenzilate
ug/L
ND
10.0
3.8
11/12/23 12:55
Chrysene
ug/L
ND
10.0
2.8
11/12/23 12:55
Di-n-butylphthalate
ug/L
ND
10.0
2.2
11/12/23 12:55
Di-n-octylphthalate
ug/L
ND
10.0
3.9
11/12/23 12:55
Diallate
ug/L
ND
10.0
3.4
11/12/23 12:55
Dibenz(a,h)anthracene
ug/L
ND
10.0
3.0
11/12/23 12:55
Dibenzofuran
ug/L
ND
10.0
2.1
11/12/23 12:55
Diethylphthalate
ug/L
ND
10.0
2.0
11/12/23 12:55
Dimethoate
ug/L
ND
10.0
3.7
11/12/23 12:55
Dimethylphthalate
ug/L
ND
10.0
2.1
11/12/23 12:55
Diphenylamine
ug/L
ND
10.0
3.0
11/12/23 12:55
Disulfoton
ug/L
ND
10.0
4.6
11/12/23 12:55
Ethyl methanesulfonate
ug/L
ND
20.0
3.0
11/12/23 12:55
Famphur
ug/L
ND
10.0
6.1
11/12/23 12:55
Fluoranthene
ug/L
ND
10.0
2.2
11/12/23 12:55
Fluorene
ug/L
ND
10.0
2.1
11/12/23 12:55
Hexachloro-1,3-butadiene
ug/L
ND
10.0
1.8
11/12/23 12:55
Hexachlorobenzene
ug/L
ND
10.0
2.2
11/12/23 12:55
Hexachlorocyclopentadiene
ug/L
ND
10.0
1.6
11/12/23 12:55
Hexachloroethane
ug/L
ND
10.0
1.4
11/12/23 12:55
Hexachloropropene
ug/L
ND
10.0
2.7
11/12/23 12:55
Indeno(1,2,3-cd)pyrene
ug/L
ND
10.0
2.9
11/12/23 12:55
Isodrin
ug/L
ND
10.0
2.8
11/12/23 12:55
Isophorone
ug/L
ND
10.0
1.7
11/12/23 12:55
Isosafrole
ug/L
ND
10.0
2.5
11/12/23 12:55
Kepone
ug/L
ND
20.0
14.1
11/12/23 12:55
Methapyrilene
ug/L
ND
50.0
17.0
11/12/23 12:55
Methyl methanesulfonate
ug/L
ND
5.0
3.1
11/12/23 12:55
Methyl parathion
ug/L
ND
10.0
3.7
11/12/23 12:55
N-Nitroso-di-n-butylamine
ug/L
ND
10.0
2.0
11/12/23 12:55
N-Nitroso-di-n-propylamine
ug/L
ND
10.0
1.3
11/12/23 12:55
N-Nitrosodiethylamine
ug/L
ND
10.0
2.3
11/12/23 12:55
N-Nitrosodimethylamine
ug/L
ND
10.0
1.9
11/12/23 12:55
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 58 of 90

Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
aceo Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
METHOD BLANK: 4204406
Associated Lab Samples: 92697340001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
N-Nitrosodiphenylamine
ug/L
ND
10.0
3.0
11/12/23 12:55
N-Nitrosomethylethylamine
ug/L
ND
10.0
7.5
11/12/23 12:55
N-Nitrosopiperidine
ug/L
ND
10.0
2.5
11/12/23 12:55
N-Nitrosopyrrolidine
ug/L
ND
10.0
3.1
11/12/23 12:55
Nitrobenzene
ug/L
ND
10.0
1.9
11/12/23 12:55
O,O,O-Triethylphosphorothioate
ug/L
ND
10.0
2.6
11/12/23 12:55
O-Toluidine
ug/L
ND
10.0
2.6
11/12/23 12:55
P-Dimethylaminoazobenzene
ug/L
ND
5.0
2.4
11/12/23 12:55
p-Phenylenediamine
ug/L
ND
10.0
10.0
11/12/23 12:55
Parathion (Ethyl parathion)
ug/L
ND
10.0
3.9
11/12/23 12:55
Pentachlorobenzene
ug/L
ND
10.0
3.4
11/12/23 12:55
Pentachloronitrobenzene
ug/L
ND
10.0
3.3
11/12/23 12:55
Pentachlorophenol
ug/L
ND
20.0
3.8
11/12/23 12:55
Phenacetin
ug/L
ND
10.0
3.6
11/12/23 12:55
Phenanthrene
ug/L
ND
10.0
2.0
11/12/23 12:55
Phenol
ug/L
ND
10.0
1.4
11/12/23 12:55
Phorate
ug/L
ND
10.0
3.6
11/12/23 12:55
Pronamide
ug/L
ND
10.0
3.1
11/12/23 12:55
Pyrene
ug/L
ND
10.0
2.2
11/12/23 12:55
Safrole
ug/L
ND
10.0
2.3
11/12/23 12:55
Thionazin
ug/L
ND
10.0
2.9
11/12/23 12:55
2,4,6-Tribromophenol (S)
%
97
10-166
11/12/23 12:55
2-Fluorobiphenyl (S)
%
72
10-130
11/12/23 12:55
2-Fluorophenol (S)
%
64
10-130
11/12/23 12:55
Nitrobenzene-d5 (S)
%
85
10-133
11/12/23 12:55
Phenol-d6 (S)
%
49
10-130
11/12/23 12:55
Terphenyl-d14 (S)
%
115
10-193
11/12/23 12:55
LABORATORY CONTROL SAMPLE:
4204407
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,2,4,5-Tetrachlorobenzene
ug/L
50
35.7
71
18-130
1,3,5-Trinitrobenzene
ug/L
50
43.7
87
59-200
1,3-Dinitrobenzene
ug/L
50
53.4
107
51-170
1,4-Naphthoquinone
ug/L
50
35.8
72
32-132
1-Naphthalenamine
ug/L
50
39.4
79
35-140
2,2'-Oxybis(1-chloropropane)
ug/L
50
34.9
70
23-130
2,3,4,6-Tetrachlorophenol
ug/L
50
48.0
96
38-154
2,4,5-Trichlorophenol
ug/L
50
47.0
94
36-150
2,4,6-Trichlorophenol
ug/L
50
40.9
82
30-151
2,4-Dichlorophenol
ug/L
50
40.0
80
36-140
2,4-Dimethylphenol
ug/L
50
43.1
86
36-155
2,4-Dinitrophenol
ug/L
250
248
99
10-169
2,4-Dinitrotoluene
ug/L
50
51.4
103
46-160
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 59 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
LABORATORY CONTROL SAMPLE:
Parameter
4204407
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
2,6-Dichlorophenol
ug/L
50
42.5
85
34-156
2,6-Dinitrotoluene
ug/L
50
49.9
100
47-161
2-Acetylaminofluorene
ug/L
50
54.5
109
39-184
2-Chloronaphthalene
ug/L
50
34.2
68
29-134
2-Chlorophenol
ug/L
50
37.5
75
29-130
2-Methylnaphthalene
ug/L
50
35.8
72
26-130
2-Methylphenol(o-Cresol)
ug/L
50
35.3
71
32-130
2-Naphthalenamine
ug/L
50
47.3
95
23-145
2-Nitroaniline
ug/L
100
89.9
90
41-150
2-Nitrophenol
ug/L
50
40.7
81
31-145
3&4-Methyl phenol (m&p Cresol)
ug/L
50
34.2
68
29-130
3,3'-Dichlorobenzidine
ug/L
100
121
121
46-153
3,3'-Dimethylbenzidine
ug/L
100
147
147
24-200
3-Methylcholanthrene
ug/L
50
60.7
121
31-195
3-Nitroaniline
ug/L
100
96.4
96
47-156
4,6-Dinitro-2-methyl phenol
ug/L
100
113
113
23-161
4-Aminobiphenyl
ug/L
50
34.6
69
26-151
4-Bromophenylphenyl ether
ug/L
50
49.3
99
45-143
4-ChIoro-3-methyl phenol
ug/L
100
89.9
90
42-143
4-Chloroaniline
ug/L
100
76.7
77
37-135
4-Chlorophenylphenyl ether
ug/L
50
44.7
89
43-140
4-Nitroaniline
ug/L
100
108
108
47-157
4-Nitrophenol
ug/L
250
165
66
10-130
5-Nitro-o-toluidine
ug/L
50
58.8
118
54-170
7,12-Dimethylbenz(a)anthracene
ug/L
50
57.3
115
29-176
Acenaphthene
ug/L
50
39.3
79
38-138
Acenaphthylene
ug/L
50
40.0
80
39-139
Acetophenone
ug/L
50
40.0
80
34-135
Anthracene
ug/L
50
51.2
102
45-136
Benzo(a)anthracene
ug/L
50
58.6
117
52-151
Benzo(a)pyrene
ug/L
50
58.8
118
46-165
Benzo(b)fluoranthene
ug/L
50
63.8
128
44-170
Benzo(g,h,i)perylene
ug/L
50
60.2
120
39-171
Benzo(k)fluoranthene
ug/L
50
58.2
116
43-168
Benzyl alcohol
ug/L
100
76.9
77
33-134
bis(2-Chloroethoxy)methane
ug/L
50
39.9
80
37-140
bis(2-Chloroethyl) ether
ug/L
50
38.2
76
33-136
bis(2-Ethylhexyl)phthalate
ug/L
50
63.1
126
50-169
Butylbenzylphthalate
ug/L
50
62.4
125
50-174
Chlorobenzilate
ug/L
50
63.7
127
46-167
Chrysene
ug/L
50
58.0
116
52-148
Di-n-butylphthalate
ug/L
50
55.5
111
51-154
Di-n-octylphthalate
ug/L
50
62.6
125
44-170
Diallate
ug/L
50
53.1
106
49-147
Dibenz(a,h)anthracene
ug/L
50
59.4
119
41-171
Dibenzofuran
ug/L
50
39.6
79
42-157
Diethylphthalate
ug/L
50
48.9
98
50-149
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 60 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
LABORATORY CONTROL SAMPLE:
Parameter
4204407
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Dimethoate
ug/L
50
62.8
126
52-169
Dimethylphthalate
ug/L
50
46.6
93
47-146
Diphenylamine
ug/L
50
49.7
99
53-142
Disulfoton
ug/L
50
54.4
109
45-135
Ethyl methanesulfonate
ug/L
50
40.1
80
27-146
Famphur
ug/L
100
91.0
91
13-130
Fluoranthene
ug/L
50
54.1
108
51-152
Fluorene
ug/L
50
45.1
90
46-143
Hexachloro-1,3-butadiene
ug/L
50
23.2
46
10-130
Hexachlorobenzene
ug/L
50
48.9
98
40-139
Hexachlorocyclopentadiene
ug/L
50
29.7
59
10-130
Hexachloroethane
ug/L
50
18.1
36
10-130
Hexachloropropene
ug/L
50
20.7
41
10-130
Indeno(1,2,3-cd)pyrene
ug/L
50
58.2
116
40-172
Isodrin
ug/L
50
52.6
105
50-150
Isophorone
ug/L
50
41.3
83
37-143
Isosafrole
ug/L
50
35.7
71
35-130
Kepone
ug/L
100
66.1
66
12-130
Methapyrilene
ug/L
50
ND
30
10-188
Methyl methanesulfonate
ug/L
50
36.4
73
24-135
Methyl parathion
ug/L
50
68.8
138
59-174
N-Nitroso-di-n-butylamine
ug/L
50
40.8
82
33-130
N-Nitroso-di-n-propylamine
ug/L
50
40.8
82
38-145
N-Nitrosodiethylamine
ug/L
50
42.6
85
26-145
N-Nitrosodimethylamine
ug/L
50
31.9
64
30-130
N-Nitrosodiphenylamine
ug/L
50
49.7
99
46-144
N-Nitrosomethylethylamine
ug/L
50
41.0
82
19-138
N-Nitrosopiperidine
ug/L
50
44.7
89
35-147
N-Nitrosopyrrolidine
ug/L
50
41.2
82
31-142
Nitrobenzene
ug/L
50
37.6
75
33-136
O,O,O-Triethylphosphorothioate
ug/L
50
43.3
87
27-136
O-Toluidine
ug/L
50
37.3
75
27-140
P-Dimethylaminoazobenzene
ug/L
50
30.8
62
23-130
p-Phenylenediamine
ug/L
ND
Parathion (Ethyl parathion)
ug/L
50
68.5
137
59-171
Pentachlorobenzene
ug/L
50
41.0
82
42-138
Pentachloronitrobenzene
ug/L
50
66.5
133
64-185
Pentachlorophenol
ug/L
100
112
112
19-156
Phenacetin
ug/L
50
61.3
123
57-174
Phenanthrene
ug/L
50
51.9
104
49-143
Phenol
ug/L
50
25.0
50
18-130
Phorate
ug/L
50
56.2
112
41-200
Pronamide
ug/L
50
60.5
121
59-174
Pyrene
ug/L
50
58.3
117
48-156
Safrole
ug/L
50
40.0
80
31-136
Thionazin
ug/L
50
57.5
115
52-151
2,4,6-Tribromophenol (S)
%
119
10-166
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 61 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
LABORATORY CONTROL SAMPLE:
4204407
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
2-Fluorobiphenyl (S)
%
77
10-130
2-Fluorophenol(S)
%
63
10-130
Nitrobenzene-d5 (S)
%
86
10-133
Phenol-d6 (S)
%
53
10-130
Terphenyl-d14 (S)
%
129
10-193
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
4204408
4204409
MS
MSD
92697057002
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
1,2,4,5-Tetrachlorobenzene
ug/L
ND
83.3
83.3
76.5
73.0
92
88
10-136
5
30
1,3,5-Trinitrobenzene
ug/L
ND
83.3
83.3
71.2
69.0
85
83
32-200
3
30
1,3-Dinitrobenzene
ug/L
ND
83.3
83.3
93.6
94.1
112
113
30-173
1
30
1,4-Naphthoquinone
ug/L
ND
83.3
83.3
84.9
73.0
102
88
10-144
15
30
1-Naphthalenamine
ug/L
ND
83.3
83.3
75.6
88.4
91
106
10-156
16
30
2,2'-Oxybis(1-
ug/L
ND
83.3
83.3
73.1
73.2
88
88
10-132
0
30
chloropropane)
2,3,4,6-Tetrachlorophenol
ug/L
ND
83.3
83.3
82.3
3.5J
99
4
10-185
30 M1
2,4,5-Trichlorophenol
ug/L
ND
83.3
83.3
84.2
16.3J
101
20
10-174
30
2,4,6-Trichlorophenol
ug/L
ND
83.3
83.3
81.6
6.OJ
98
7
10-173
30 M1
2,4-Dichlorophenol
ug/L
ND
83.3
83.3
82.7
27.0
99
32
10-153
102
30 R1
2,4-Dimethylphenol
ug/L
ND
83.3
83.3
89.3
90.6
107
109
12-157
1
30
2,4-Dinitrophenol
ug/L
ND
417
417
436
ND
105
1
10-165
30 M1
2,4-Dinitrotoluene
ug/L
ND
83.3
83.3
87.1
90.2
105
108
29-168
4
30
2,6-Dichlorophenol
ug/L
ND
83.3
83.3
88.2
7.9J
106
9
10-178
30 M1
2,6-Dinitrotoluene
ug/L
ND
83.3
83.3
90.2
97.3
108
117
28-168
8
30
2-Acetylam inofl uorene
ug/L
ND
83.3
83.3
87.5
101
105
122
20-194
15
30
2-Chloronaphthalene
ug/L
ND
83.3
83.3
73.9
77.6
89
93
11-136
5
30
2-Chlorophenol
ug/L
ND
83.3
83.3
76.8
28.1
92
34
10-134
93
30 R1
2-Methyl naphthalene
ug/L
ND
83.3
83.3
82.5
84.3
99
101
10-131
2
30
2-Methyl phenol(o-Cresol)
ug/L
ND
83.3
83.3
73.9
70.8
89
85
10-130
4
30
2-Naphthalenamine
ug/L
ND
83.3
83.3
40.1
71.5
48
86
10-147
56
30 R1
2-Nitroaniline
ug/L
ND
167
167
158
170
95
102
19-156
7
30
2-Nitrophenol
ug/L
ND
83.3
83.3
84.4
26.9
101
32
10-160
103
30 R1
3&4-Methylphenol(m&p
ug/L
ND
83.3
83.3
70.8
65.4
85
78
10-132
8
30
Cresol)
3,3'-Dichlorobenzidine
ug/L
ND
167
167
179
199
107
119
10-173
11
30
3,3'-Dimethylbenzidine
ug/L
ND
167
167
194
394
116
236
10-200
68
30 M1,R1
3-Methylcholanthrene
ug/L
ND
83.3
83.3
100
101
120
121
10-200
1
30
3-Nitroaniline
ug/L
ND
167
167
170
186
102
112
19-169
9
30
4,6-Dinitro-2-methylphenol
ug/L
ND
167
167
192
ND
115
2
10-178
30 M1
4-Aminobiphenyl
ug/L
ND
83.3
83.3
61.4
83.9
74
101
10-170
31
30 R1
4-Bromophenylphenyl ether
ug/L
ND
83.3
83.3
85.8
93.4
103
112
28-149
8
30
4-Chloro-3-methylphenol
ug/L
ND
167
167
173
160
104
96
18-148
8
30
4-Chloroaniline
ug/L
ND
167
167
161
171
96
103
10-141
6
30
4-Chlorophenylphenyl ether
ug/L
ND
83.3
83.3
86.1
91.9
103
110
24-144
7
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 62 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4204408
MS
92697057002 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
4204409
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
4-Nitroaniline
ug/L
ND
167
167
162
180
97
108
18-170
10
30
4-Nitrophenol
ug/L
ND
417
417
277
11.7J
66
3
10-130
30 M1
5-Nitro-o-toluidine
ug/L
ND
83.3
83.3
96.3
97.6
116
117
38-167
1
30
7,12-
ug/L
ND
83.3
83.3
96.8
97.2
116
117
10-182
0
30
Dimethylbenz(a)anthracene
Acenaphthene
ug/L
ND
83.3
83.3
79.1
84.6
95
101
18-142
7
30
Acenaphthylene
ug/L
ND
83.3
83.3
80.8
85.5
97
103
18-143
6
30
Acetophenone
ug/L
ND
83.3
83.3
82.2
84.4
99
101
10-142
3
30
Anthracene
ug/L
ND
83.3
83.3
83.0
89.0
100
107
32-138
7
30
Benzo(a)anth race ne
ug/L
ND
83.3
83.3
90.4
96.9
108
116
41-155
7
30
Benzo(a)pyrene
ug/L
ND
83.3
83.3
92.5
99.5
111
119
10-167
7
30
Benzo(b)fluoranthene
ug/L
ND
83.3
83.3
101
108
122
130
31-172
6
30
Benzo(g,h,i)perylene
ug/L
ND
83.3
83.3
84.9
93.5
102
112
26-177
10
30
Benzo(k)fluoranthene
ug/L
ND
83.3
83.3
92.2
98.2
111
118
31-168
6
30
Benzyl alcohol
ug/L
ND
167
167
158
158
95
95
10-136
0
30
bis(2-
ug/L
ND
83.3
83.3
81.3
84.2
98
101
12-143
3
30
Chloroethoxy)methane
bis(2-Chloroethyl) ether
ug/L
ND
83.3
83.3
77.3
78.3
93
94
10-139
1
30
bis(2- Ethyl hexyl)phthalate
ug/L
ND
83.3
83.3
98.0
104
118
124
41-173
6
30
Butylbenzylphthalate
ug/L
ND
83.3
83.3
99.1
105
119
127
38-182
6
30
Chlorobenzilate
ug/L
ND
83.3
83.3
104
104
124
125
33-175
0
30
Chrysene
ug/L
ND
83.3
83.3
88.7
95.9
106
115
41-152
8
30
Di-n-butylphthalate
ug/L
ND
83.3
83.3
87.8
93.2
105
112
37-162
6
30
Di-n-octylphthalate
ug/L
ND
83.3
83.3
102
107
123
129
36-176
5
30
Diallate
ug/L
ND
83.3
83.3
89.4
89.8
107
108
26-155
0
30
Dibenz(a,h)anthracene
ug/L
ND
83.3
83.3
87.3
95.4
105
114
29-175
9
30
Dibenzofuran
ug/L
ND
83.3
83.3
78.3
83.6
94
100
23-144
7
30
Diethylphthalate
ug/L
ND
83.3
83.3
83.5
90.1
100
108
33-154
8
30
Dimethoate
ug/L
ND
83.3
83.3
99.1
95.2
119
114
41-169
4
30
Dimethylphthalate
ug/L
ND
83.3
83.3
81.8
87.9
98
105
29-150
7
30
Diphenylamine
ug/L
ND
83.3
83.3
82.6
88.8
99
107
34-146
7
30
Disulfoton
ug/L
ND
83.3
83.3
90.5
91.0
109
109
36-133
0
30
Ethyl methanesulfonate
ug/L
ND
83.3
83.3
81.1
78.3
97
94
10-147
4
30
Famphur
ug/L
ND
167
167
99.8
58.6
60
35
10-130
52
30 R1
Fluoranthene
ug/L
ND
83.3
83.3
85.6
92.1
103
111
40-156
7
30
Fluorene
ug/L
ND
83.3
83.3
84.1
89.7
101
108
26-148
7
30
Hexachloro-1,3-butadiene
ug/L
ND
83.3
83.3
69.5
62.7
83
75
10-130
10
30
Hexachlorobenzene
ug/L
ND
83.3
83.3
84.2
90.6
101
109
27-145
7
30
Hexachlorocyclopentadiene
ug/L
ND
83.3
83.3
78.8
76.0
95
91
10-130
4
30
Hexachloroethane
ug/L
ND
83.3
83.3
56.6
46.9
68
56
10-130
19
30
Hexachloropropene
ug/L
ND
83.3
83.3
60.2
48.1
72
58
10-130
22
30
Indeno(1,2,3-cd)pyrene
ug/L
ND
83.3
83.3
85.1
94.0
102
113
28-176
10
30
Isodrin
ug/L
ND
83.3
83.3
86.8
87.1
104
104
33-153
0
30
Isophorone
ug/L
ND
83.3
83.3
83.6
87.9
100
105
14-145
5
30
Isosafrole
ug/L
ND
83.3
83.3
76.0
75.2
91
90
13-136
1
30
Kepone
ug/L
ND
167
167
85.4
56.4
51
34
10-130
41
30 R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 63 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 4204408
4204409
MS
MSD
92697057002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Methapyrilene
ug/L
ND
83.3
83.3
73.9J
109
89
131
10-200
30
Methyl methanesulfonate
ug/L
ND
83.3
83.3
72.3
68.1
87
82
10-138
6
30
Methyl parathion
ug/L
ND
83.3
83.3
110
107
132
128
44-177
3
30
N-Nitroso-di-n-butylamine
ug/L
ND
83.3
83.3
83.7
85.6
100
103
14-133
2
30
N-Nitroso-di-n-propylamine
ug/L
ND
83.3
83.3
86.5
86.3
104
104
12-149
0
30
N-Nitrosodiethylamine
ug/L
ND
83.3
83.3
86.4
82.5
104
99
10-148
5
30
N-Nitrosodimethylamine
ug/L
ND
83.3
83.3
65.7
63.9
79
77
10-130
3
30
N-Nitrosodiphenylamine
ug/L
ND
83.3
83.3
82.6
88.8
99
107
29-149
7
30
N-Nitrosomethylethylamine
ug/L
ND
83.3
83.3
74.4
68.7
89
82
10-139
8
30
N-Nitrosopiperidine
ug/L
ND
83.3
83.3
92.1
89.9
111
108
14-151
2
30
N-Nitrosopyrrolidine
ug/L
ND
83.3
83.3
85.2
82.2
102
99
14-143
4
30
Nitrobenzene
ug/L
ND
83.3
83.3
77.2
78.7
93
94
10-145
2
30
0,0,0-
ug/L
ND
83.3
83.3
93.6
91.9
112
110
10-142
2
30
Triethylphosphorothioate
O-Toluidine
ug/L
ND
83.3
83.3
81.6
81.6
98
98
10-137
0
30
P-
ug/L
ND
83.3
83.3
50.9
51.4
61
62
17-130
1
30
Dimethylaminoazobenzene
p-Phenylenediamine
ug/L
ND
ND
ND
30
Parathion (Ethyl parathion)
ug/L
ND
83.3
83.3
111
112
133
134
45-174
0
30
Pentachlorobenzene
ug/L
ND
83.3
83.3
83.0
82.9
100
100
20-143
0
30
Pentachloronitrobenzene
ug/L
ND
83.3
83.3
110
98.4
132
118
39-186
11
30
Pentachlorophenol
ug/L
ND
167
167
183
ND
110
3
10-178
30 M1
Phenacetin
ug/L
ND
83.3
83.3
96.5
97.5
116
117
36-185
1
30
Phenanthrene
ug/L
ND
83.3
83.3
82.8
89.2
99
107
36-146
7
30
Phenol
ug/L
ND
83.3
83.3
50.0
29.3
60
35
10-130
52
30 R1
Phorate
ug/L
ND
83.3
83.3
96.0
95.9
115
115
26-200
0
30
Pronamide
ug/L
ND
83.3
83.3
98.0
98.2
118
118
40-181
0
30
Pyrene
ug/L
ND
83.3
83.3
91.0
96.9
109
116
42-156
6
30
Safrole
ug/L
ND
83.3
83.3
86.8
85.1
104
102
10-142
2
30
Thionazin
ug/L
ND
83.3
83.3
96.9
98.0
116
118
31-159
1
30
2,4,6-Tribromophenol (S)
%
98
17
10-166
2-Fluorobiphenyl (S)
%
79
81
10-130
2-Fluorophenol (S)
%
65
10
10-130
Nitrobenzene-d5 (S)
%
86
87
10-133
Phenol-d6 (S)
%
54
30
10-130
Terphenyl-d14 (S)
%
95
103
10-193
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 64 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 812753 Analysis Method: EPA 8270E
QC Batch Method: EPA 3510C Analysis Description: 8270E Water APP9 RV MSSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92698166001
METHOD BLANK: 4208121
Associated Lab Samples: 92698166001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
1,2,4,5-Tetrachlorobenzene
ug/L
ND
10.0
4.5
11/14/23 10:51
1,3,5-Trinitrobenzene
ug/L
ND
10.0
5.5
11/14/23 10:51
1,3-Dinitrobenzene
ug/L
ND
10.0
3.8
11/14/23 10:51
1,4-Naphthoquinone
ug/L
ND
5.0
4.4
11/14/23 10:51
1-Naphthalenamine
ug/L
ND
10.0
6.0
11/14/23 10:51
2,2'-Oxybis(1-chloropropane)
ug/L
ND
10.0
1.2
11/14/23 10:51
2,3,4,6-Tetrachlorophenol
ug/L
ND
10.0
1.5
11/14/23 10:51
2,4,5-Trichlorophenol
ug/L
ND
10.0
1.4
11/14/23 10:51
2,4,6-Trichlorophenol
ug/L
ND
10.0
1.6
11/14/23 10:51
2,4-Dichlorophenol
ug/L
ND
10.0
1.4
11/14/23 10:51
2,4-Dimethylphenol
ug/L
ND
10.0
1.7
11/14/23 10:51
2,4-Dinitrophenol
ug/L
ND
50.0
26.0
11/14/23 10:51
2,4-Dinitrotoluene
ug/L
ND
10.0
1.6
11/14/23 10:51
2,6-Dichlorophenol
ug/L
ND
10.0
4.2
11/14/23 10:51
2,6-Dinitrotoluene
ug/L
ND
10.0
1.7
11/14/23 10:51
2-Acetylaminofluorene
ug/L
ND
10.0
4.1
11/14/23 10:51
2-Chloronaphthalene
ug/L
ND
10.0
1.7
11/14/23 10:51
2-Chlorophenol
ug/L
ND
10.0
1.2
11/14/23 10:51
2-Methylnaphthalene
ug/L
ND
10.0
1.9
11/14/23 10:51
2-Methylphenol(o-Cresol)
ug/L
ND
10.0
1.9
11/14/23 10:51
2-Naphthalenamine
ug/L
ND
10.0
5.4
11/14/23 10:51
2-Nitroaniline
ug/L
ND
20.0
3.0
11/14/23 10:51
2-Nitrophenol
ug/L
ND
10.0
1.4
11/14/23 10:51
3&4-Methyl phenol (m&p Cresol)
ug/L
ND
10.0
1.2
11/14/23 10:51
3,3'-Dichlorobenzidine
ug/L
ND
20.0
8.1
11/14/23 10:51
3,3'-Dimethylbenzidine
ug/L
ND
50.0
31.1
11/14/23 10:51
3-Methylcholanthrene
ug/L
ND
10.0
3.7
11/14/23 10:51
3-Nitroaniline
ug/L
ND
20.0
3.8
11/14/23 10:51
4,6-Dinitro-2-methyl phenol
ug/L
ND
20.0
7.8
11/14/23 10:51
4-Aminobiphenyl
ug/L
ND
10.0
4.7
11/14/23 10:51
4-Bromophenylphenyl ether
ug/L
ND
10.0
1.8
11/14/23 10:51
4-ChIoro-3-methyl phenol
ug/L
ND
10.0
3.3
11/14/23 10:51
4-Chloroaniline
ug/L
ND
20.0
3.6
11/14/23 10:51
4-Chlorophenylphenyl ether
ug/L
ND
10.0
2.0
11/14/23 10:51
4-Nitroaniline
ug/L
ND
20.0
5.1
11/14/23 10:51
4-Nitrophenol
ug/L
ND
50.0
6.6
11/14/23 10:51
5-Nitro-o-toluidine
ug/L
ND
10.0
3.8
11/14/23 10:51
7,12-Dimethylbenz(a)anthracene
ug/L
ND
10.0
3.0
11/14/23 10:51
Acenaphthene
ug/L
ND
10.0
2.0
11/14/23 10:51
Acenaphthylene
ug/L
ND
10.0
2.0
11/14/23 10:51
v2
v1
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 65 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
METHOD BLANK: 4208121
Matrix:
Water
Associated Lab Samples: 92698166001
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed
Acetophenone
ug/L
ND
10.0
1.5
11/14/23 10:51
Anthracene
ug/L
ND
10.0
2.3
11/14/23 10:51
Benzo(a)anthracene
ug/L
ND
10.0
2.7
11/14/23 10:51
Benzo(a)pyrene
ug/L
ND
10.0
2.8
11/14/23 10:51
Benzo(b)fluoranthene
ug/L
ND
10.0
2.6
11/14/23 10:51
Benzo(g,h,i)perylene
ug/L
ND
10.0
2.8
11/14/23 10:51
Benzo(k)fluoranthene
ug/L
ND
10.0
2.7
11/14/23 10:51
Benzyl alcohol
ug/L
ND
20.0
2.9
11/14/23 10:51
bis(2-Chloroethoxy)methane
ug/L
ND
10.0
1.8
11/14/23 10:51
bis(2-Chloroethyl) ether
ug/L
ND
10.0
1.9
11/14/23 10:51
bis(2-Ethylhexyl)phthalate
ug/L
ND
6.0
3.7
11/14/23 10:51
Butylbenzylphthalate
ug/L
ND
10.0
3.1
11/14/23 10:51
Chlorobenzilate
ug/L
ND
10.0
3.8
11/14/23 10:51
Chrysene
ug/L
ND
10.0
2.8
11/14/23 10:51
Di-n-butylphthalate
ug/L
ND
10.0
2.2
11/14/23 10:51
Di-n-octylphthalate
ug/L
ND
10.0
3.9
11/14/23 10:51
Diallate
ug/L
ND
10.0
3.4
11/14/23 10:51
Dibenz(a,h)anthracene
ug/L
ND
10.0
3.0
11/14/23 10:51
Dibenzofuran
ug/L
ND
10.0
2.1
11/14/23 10:51
Diethylphthalate
ug/L
ND
10.0
2.0
11/14/23 10:51
Dimethoate
ug/L
ND
10.0
3.7
11/14/23 10:51
Dimethylphthalate
ug/L
ND
10.0
2.1
11/14/23 10:51
Diphenylamine
ug/L
ND
10.0
3.0
11/14/23 10:51
Disulfoton
ug/L
ND
10.0
4.6
11/14/23 10:51
Ethyl methanesulfonate
ug/L
ND
20.0
3.0
11/14/23 10:51
Famphur
ug/L
ND
10.0
6.1
11/14/23 10:51
Fluoranthene
ug/L
ND
10.0
2.2
11/14/23 10:51
Fluorene
ug/L
ND
10.0
2.1
11/14/23 10:51
Hexachloro-1,3-butadiene
ug/L
ND
10.0
1.8
11/14/23 10:51
Hexachlorobenzene
ug/L
ND
10.0
2.2
11/14/23 10:51
Hexachlorocyclopentadiene
ug/L
ND
10.0
1.6
11/14/23 10:51
Hexachloroethane
ug/L
ND
10.0
1.4
11/14/23 10:51
Hexachloropropene
ug/L
ND
10.0
2.7
11/14/23 10:51
Indeno(1,2,3-cd)pyrene
ug/L
ND
10.0
2.9
11/14/23 10:51
Isodrin
ug/L
ND
10.0
2.8
11/14/23 10:51
Isophorone
ug/L
ND
10.0
1.7
11/14/23 10:51
Isosafrole
ug/L
ND
10.0
2.5
11/14/23 10:51
Kepone
ug/L
ND
20.0
14.1
11/14/23 10:51
Methapyrilene
ug/L
ND
50.0
17.0
11/14/23 10:51 v1
Methyl methanesulfonate
ug/L
ND
5.0
3.1
11/14/23 10:51
Methyl parathion
ug/L
ND
10.0
3.7
11/14/23 10:51
N-Nitroso-di-n-butylamine
ug/L
ND
10.0
2.0
11/14/23 10:51
N-Nitroso-di-n-propylamine
ug/L
ND
10.0
1.3
11/14/23 10:51
N-Nitrosodiethylamine
ug/L
ND
10.0
2.3
11/14/23 10:51
N-Nitrosodimethylamine
ug/L
ND
10.0
1.9
11/14/23 10:51
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 66 of 90

Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
aceo Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
METHOD BLANK: 4208121
Associated Lab Samples: 92698166001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
N-Nitrosodiphenylamine
ug/L
ND
10.0
3.0
11/14/23 10:51
N-Nitrosomethylethylamine
ug/L
ND
10.0
7.5
11/14/23 10:51
N-Nitrosopiperidine
ug/L
ND
10.0
2.5
11/14/23 10:51
N-Nitrosopyrrolidine
ug/L
ND
10.0
3.1
11/14/23 10:51
Nitrobenzene
ug/L
ND
10.0
1.9
11/14/23 10:51
O,O,O-Triethylphosphorothioate
ug/L
ND
10.0
2.6
11/14/23 10:51
O-Toluidine
ug/L
ND
10.0
2.6
11/14/23 10:51
P-Dimethylaminoazobenzene
ug/L
ND
5.0
2.4
11/14/23 10:51
p-Phenylenediamine
ug/L
ND
10.0
10.0
11/14/23 10:51
Parathion (Ethyl parathion)
ug/L
ND
10.0
3.9
11/14/23 10:51
Pentachlorobenzene
ug/L
ND
10.0
3.4
11/14/23 10:51
Pentachloronitrobenzene
ug/L
ND
10.0
3.3
11/14/23 10:51
Pentachlorophenol
ug/L
ND
20.0
3.8
11/14/23 10:51
Phenacetin
ug/L
ND
10.0
3.6
11/14/23 10:51
Phenanthrene
ug/L
ND
10.0
2.0
11/14/23 10:51
Phenol
ug/L
ND
10.0
1.4
11/14/23 10:51
Phorate
ug/L
ND
10.0
3.6
11/14/23 10:51
Pronamide
ug/L
ND
10.0
3.1
11/14/23 10:51
Pyrene
ug/L
ND
10.0
2.2
11/14/23 10:51
Safrole
ug/L
ND
10.0
2.3
11/14/23 10:51
Thionazin
ug/L
ND
10.0
2.9
11/14/23 10:51
2,4,6-Tribromophenol (S)
%
110
10-166
11/14/23 10:51
2-Fluorobiphenyl (S)
%
85
10-130
11/14/23 10:51
2-Fluorophenol (S)
%
77
10-130
11/14/23 10:51
Nitrobenzene-d5 (S)
%
101
10-133
11/14/23 10:51
Phenol-d6 (S)
%
58
10-130
11/14/23 10:51
Terphenyl-d14 (S)
%
114
10-193
11/14/23 10:51
LABORATORY CONTROL SAMPLE:
4208122
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,2,4,5-Tetrachlorobenzene
ug/L
50
54.0
108
18-130
1,3,5-Trinitrobenzene
ug/L
50
53.4
107
59-200
1,3-Dinitrobenzene
ug/L
50
68.1
136
51-170
1,4-Naphthoquinone
ug/L
50
48.5
97
32-132
1-Naphthalenamine
ug/L
50
38.9
78
35-140
2,2'-Oxybis(1-chloropropane)
ug/L
50
58.5
117
23-130
2,3,4,6-Tetrachlorophenol
ug/L
50
64.8
130
38-154
2,4,5-Trichlorophenol
ug/L
50
65.4
131
36-150
2,4,6-Trichlorophenol
ug/L
50
64.1
128
30-151
2,4-Dichlorophenol
ug/L
50
66.0
132
36-140
2,4-Dimethylphenol
ug/L
50
70.7
141
36-155
2,4-Dinitrophenol
ug/L
250
364
146
10-169
2,4-Dinitrotoluene
ug/L
50
68.3
137
46-160
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 67 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
LABORATORY CONTROL SAMPLE: 4208122
Parameter
QUALITY CONTROL DATA
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
2,6-Dichlorophenol
ug/L
50
65.8
132
34-156
2,6-Dinitrotoluene
ug/L
50
70.5
141
47-161
2-Acetylaminofluorene
ug/L
50
75.9
152
39-184
2-Chloronaphthalene
ug/L
50
56.5
113
29-134
2-Chlorophenol
ug/L
50
63.8
128
29-130
2-Methylnaphthalene
ug/L
50
61.3
123
26-130
2-Methylphenol(o-Cresol)
ug/L
50
60.9
122
32-130
2-Naphthalenamine
ug/L
50
51.7
103
23-145
2-Nitroaniline
ug/L
100
112
112
41-150
2-Nitrophenol
ug/L
50
69.1
138
31-145
3&4-Methyl phenol (m&p Cresol)
ug/L
50
59.3
119
29-130
3,3'-Dichlorobenzidine
ug/L
100
143
143
46-153
3,3'-Dimethylbenzidine
ug/L
100
ND
21
24-200 L2,v3
3-Methylcholanthrene
ug/L
50
73.6
147
31-195
3-Nitroaniline
ug/L
100
134
134
47-156
4,6-Dinitro-2-methyl phenol
ug/L
100
153
153
23-161 v1
4-Aminobiphenyl
ug/L
50
28.9
58
26-151
4-Bromophenylphenyl ether
ug/L
50
66.2
132
45-143
4-ChIoro-3-methyl phenol
ug/L
100
134
134
42-143
4-Chloroaniline
ug/L
100
118
118
37-135
4-Chlorophenylphenyl ether
ug/L
50
66.6
133
43-140
4-Nitroaniline
ug/L
100
131
131
47-157
4-Nitrophenol
ug/L
250
227
91
10-130
5-Nitro-o-toluidine
ug/L
50
70.0
140
54-170
7,12-Dimethylbenz(a)anthracene
ug/L
50
68.9
138
29-176
Acenaphthene
ug/L
50
60.9
122
38-138
Acenaphthylene
ug/L
50
62.2
124
39-139
Acetophenone
ug/L
50
67.5
135
34-135
Anthracene
ug/L
50
65.1
130
45-136
Benzo(a)anthracene
ug/L
50
71.4
143
52-151
Benzo(a)pyrene
ug/L
50
73.1
146
46-165
Benzo(b)fluoranthene
ug/L
50
79.2
158
44-170
Benzo(g,h,i)perylene
ug/L
50
75.8
152
39-171
Benzo(k)fluoranthene
ug/L
50
73.6
147
43-168
Benzyl alcohol
ug/L
100
129
129
33-134
bis(2-Chloroethoxy)methane
ug/L
50
65.7
131
37-140
bis(2-Chloroethyl) ether
ug/L
50
64.1
128
33-136
bis(2-Ethylhexyl)phthalate
ug/L
50
75.2
150
50-169
Butylbenzylphthalate
ug/L
50
74.7
149
50-174
Chlorobenzilate
ug/L
50
72.8
146
46-167
Chrysene
ug/L
50
70.9
142
52-148
Di-n-butylphthalate
ug/L
50
69.0
138
51-154
Di-n-octylphthalate
ug/L
50
79.5
159
44-170
Diallate
ug/L
50
63.0
126
49-147
Dibenz(a,h)anthracene
ug/L
50
76.0
152
41-171
Dibenzofuran
ug/L
50
60.8
122
42-157
Diethylphthalate
ug/L
50
64.8
130
50-149
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 68 of 90

Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
aceo Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
LABORATORY CONTROL SAMPLE:
Parameter
4208122
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Dimethoate
ug/L
50
75.0
150
52-169
Dimethylphthalate
ug/L
50
63.7
127
47-146
Diphenylamine
ug/L
50
63.0
126
53-142
Disulfoton
ug/L
50
61.2
122
45-135
Ethyl methanesulfonate
ug/L
50
62.0
124
27-146
Famphur
ug/L
100
139
139
13-130 L1
Fluoranthene
ug/L
50
70.0
140
51-152
Fluorene
ug/L
50
65.0
130
46-143
Hexachloro-1,3-butadiene
ug/L
50
45.9
92
10-130
Hexachlorobenzene
ug/L
50
65.1
130
40-139
Hexachlorocyclopentadiene
ug/L
50
55.4
111
10-130
Hexachloroethane
ug/L
50
40.0
80
10-130
Hexachloropropene
ug/L
50
34.4
69
10-130
Indeno(1,2,3-cd)pyrene
ug/L
50
74.0
148
40-172
Isodrin
ug/L
50
62.1
124
50-150
Isophorone
ug/L
50
66.9
134
37-143
Isosafrole
ug/L
50
55.0
110
35-130
Kepone
ug/L
100
108
108
12-130
Methapyrilene
ug/L
50
ND
7
10-188 L2,v1
Methyl methanesulfonate
ug/L
50
55.8
112
24-135
Methyl parathion
ug/L
50
83.0
166
59-174
N-Nitroso-di-n-butylamine
ug/L
50
51.2
102
33-130
N-Nitroso-di-n-propylamine
ug/L
50
68.2
136
38-145
N-Nitrosodiethylamine
ug/L
50
65.0
130
26-145
N-Nitrosodimethylamine
ug/L
50
54.3
109
30-130
N-Nitrosodiphenylamine
ug/L
50
63.0
126
46-144
N-Nitrosomethylethylamine
ug/L
50
60.1
120
19-138
N-Nitrosopiperidine
ug/L
50
67.6
135
35-147
N-Nitrosopyrrolidine
ug/L
50
61.4
123
31-142
Nitrobenzene
ug/L
50
61.6
123
33-136
O,O,O-Triethylphosphorothioate
ug/L
50
69.6
139
27-136 L1
O-Toluidine
ug/L
50
55.0
110
27-140
P-Dimethylaminoazobenzene
ug/L
50
35.7
71
23-130
p-Phenylenediamine
ug/L
ND
Parathion (Ethyl parathion)
ug/L
50
80.9
162
59-171
Pentachlorobenzene
ug/L
50
59.9
120
42-138
Pentachloronitrobenzene
ug/L
50
81.1
162
64-185
Pentachlorophenol
ug/L
100
144
144
19-156
Phenacetin
ug/L
50
72.1
144
57-174
Phenanthrene
ug/L
50
64.7
129
49-143
Phenol
ug/L
50
44.1
88
18-130
Phorate
ug/L
50
66.7
133
41-200
Pronamide
ug/L
50
71.5
143
59-174
Pyrene
ug/L
50
66.9
134
48-156
Safrole
ug/L
50
62.7
125
31-136
Thionazin
ug/L
50
68.9
138
52-151
2,4,6-Tribromophenol (S)
%
128
10-166
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 69 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
LABORATORY CONTROL SAMPLE:
4208122
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
2-Fluorobiphenyl (S)
%
101
10-130
2-Fluorophenol(S)
%
95
10-130
Nitrobenzene-d5 (S)
%
115
10-133
Phenol-d6 (S)
%
78
10-130
Terphenyl-d14 (S)
%
123
10-193
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
4208123
4208124
MS
MSD
92698135002
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
1,2,4,5-Tetrachlorobenzene
ug/L
ND
83.3
83.3
99.2
84.3
119
101
10-136
16
30
1,3,5-Trinitrobenzene
ug/L
ND
83.3
83.3
88.1
89.9
106
108
32-200
2
30
1,3-Dinitrobenzene
ug/L
ND
83.3
83.3
116
114
139
137
30-173
2
30
1,4-Naphthoquinone
ug/L
ND
83.3
83.3
113
91.8
136
110
10-144
21
30
1-Naphthalenamine
ug/L
ND
83.3
83.3
39.1
68.5
47
82
10-156
55
30 R1
2,2'-Oxybis(1-
ug/L
ND
83.3
83.3
91.2
81.1
109
97
10-132
12
30
chloropropane)
2,3,4,6-Tetrachlorophenol
ug/L
ND
83.3
83.3
101
101
121
121
10-185
0
30
2,4,5-Trichlorophenol
ug/L
ND
83.3
83.3
101
99.9
121
120
10-174
1
30
2,4,6-Trichlorophenol
ug/L
ND
83.3
83.3
98.7
94.3
118
113
10-173
5
30
2,4-Dichlorophenol
ug/L
ND
83.3
83.3
104
98.3
125
118
10-153
6
30
2,4-Dimethylphenol
ug/L
ND
83.3
83.3
109
104
131
125
12-157
5
30
2,4-Dinitrophenol
ug/L
ND
417
417
561
555
135
133
10-165
1
30
2,4-Dinitrotoluene
ug/L
ND
83.3
83.3
103
102
123
122
29-168
1
30
2,6-Dichlorophenol
ug/L
ND
83.3
83.3
116
110
140
132
10-178
5
30
2,6-Dinitrotoluene
ug/L
ND
83.3
83.3
107
104
128
125
28-168
3
30
2-Acetylam inofl uorene
ug/L
ND
83.3
83.3
129
136
155
163
20-194
5
30
2-Chloronaphthalene
ug/L
ND
83.3
83.3
89.8
81.2
108
97
11-136
10
30
2-Chlorophenol
ug/L
ND
83.3
83.3
97.3
93.8
117
113
10-134
4
30
2-Methyl naphthalene
ug/L
ND
83.3
83.3
104
91.7
125
110
10-131
12
30
2-Methyl phenol(o-Cresol)
ug/L
ND
83.3
83.3
94.3
88.9
113
107
10-130
6
30
2-Naphthalenamine
ug/L
ND
83.3
83.3
26.1
60.4
31
73
10-147
79
30 R1
2-Nitroaniline
ug/L
ND
167
167
160
159
96
95
19-156
0
30
2-Nitrophenol
ug/L
ND
83.3
83.3
110
103
132
123
10-160
7
30
3&4-Methylphenol(m&p
ug/L
ND
83.3
83.3
90.7
85.1
109
102
10-132
6
30
Cresol)
3,3'-Dichlorobenzidine
ug/L
ND
167
167
85.4
150
51
90
10-173
55
30 R1
3,3'-Dimethylbenzidine
ug/L
ND
167
167
ND
ND
1
4
10-200
30 MO,v2
3-Methylcholanthrene
ug/L
ND
83.3
83.3
118
122
142
146
10-200
3
30
3-Nitroaniline
ug/L
ND
167
167
194
194
116
116
19-169
0
30
4,6-Dinitro-2-methylphenol
ug/L
ND
167
167
231
235
138
141
10-178
2
30 v1
4-Aminobiphenyl
ug/L
ND
83.3
83.3
36.4
53.3
44
64
10-170
38
30 R1
4-Bromophenylphenyl ether
ug/L
ND
83.3
83.3
102
100
123
120
28-149
2
30
4-Chloro-3-methylphenol
ug/L
ND
167
167
214
212
128
127
18-148
1
30
4-Chloroaniline
ug/L
ND
167
167
175
183
105
110
10-141
5
30
4-Chlorophenylphenyl ether
ug/L
ND
83.3
83.3
103
97.1
123
117
24-144
6
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 70 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4208123
MS
92698135002 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
4208124
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
4-Nitroaniline
ug/L
ND
167
167
186
189
111
113
18-170
2
30
4-Nitrophenol
ug/L
ND
417
417
350
338
84
81
10-130
4
30
5-Nitro-o-toluidine
ug/L
ND
83.3
83.3
113
116
136
139
38-167
2
30
7,12-
ug/L
ND
83.3
83.3
115
115
137
139
10-182
1
30
Dimethylbenz(a)anthracene
Acenaphthene
ug/L
ND
83.3
83.3
95.3
87.6
114
105
18-142
8
30
Acenaphthylene
ug/L
ND
83.3
83.3
97.6
90.6
117
109
18-143
7
30
Acetophenone
ug/L
ND
83.3
83.3
103
97.5
124
117
10-142
6
30
Anthracene
ug/L
ND
83.3
83.3
98.4
99.4
118
119
32-138
1
30
Benzo(a)anth race ne
ug/L
ND
83.3
83.3
106
109
127
131
41-155
4
30
Benzo(a)pyrene
ug/L
ND
83.3
83.3
108
110
129
132
10-167
2
30
Benzo(b)fluoranthene
ug/L
ND
83.3
83.3
116
121
140
146
31-172
4
30
Benzo(g,h,i)perylene
ug/L
ND
83.3
83.3
109
113
131
136
26-177
4
30
Benzo(k)fluoranthene
ug/L
ND
83.3
83.3
108
109
129
131
31-168
1
30
Benzyl alcohol
ug/L
ND
167
167
197
189
118
114
10-136
4
30
bis(2-
ug/L
ND
83.3
83.3
105
96.6
126
116
12-143
8
30
Chloroethoxy)methane
bis(2-Chloroethyl) ether
ug/L
ND
83.3
83.3
98.9
93.6
119
112
10-139
6
30
bis(2- Ethyl hexyl)phthalate
ug/L
ND
83.3
83.3
112
114
135
137
41-173
2
30
Butylbenzylphthalate
ug/L
ND
83.3
83.3
111
114
134
137
38-182
3
30
Chlorobenzilate
ug/L
ND
83.3
83.3
125
125
150
150
33-175
0
30
Chrysene
ug/L
ND
83.3
83.3
107
109
128
131
41-152
2
30
Di-n-butylphthalate
ug/L
ND
83.3
83.3
103
106
124
127
37-162
2
30
Di-n-octylphthalate
ug/L
ND
83.3
83.3
119
123
143
148
36-176
4
30
Diallate
ug/L
ND
83.3
83.3
108
106
129
128
26-155
1
30
Dibenz(a,h)anthracene
ug/L
ND
83.3
83.3
110
114
132
136
29-175
3
30
Dibenzofuran
ug/L
ND
83.3
83.3
94.0
88.0
113
106
23-144
7
30
Diethylphthalate
ug/L
ND
83.3
83.3
99.0
97.8
119
117
33-154
1
30
Dimethoate
ug/L
ND
83.3
83.3
114
109
137
131
41-169
4
30
Dimethylphthalate
ug/L
ND
83.3
83.3
97.2
94.3
117
113
29-150
3
30
Diphenylamine
ug/L
ND
83.3
83.3
92.0
96.4
110
116
34-146
5
30
Disulfoton
ug/L
ND
83.3
83.3
109
108
130
130
36-133
0
30
Ethyl methanesulfonate
ug/L
ND
83.3
83.3
104
101
125
121
10-147
3
30
Famphur
ug/L
ND
167
167
93.7
58.9
56
35
10-130
46
30 R1
Fluoranthene
ug/L
ND
83.3
83.3
105
108
127
130
40-156
3
30
Fluorene
ug/L
ND
83.3
83.3
99.9
94.1
120
113
26-148
6
30
Hexachloro-1,3-butadiene
ug/L
ND
83.3
83.3
80.2
64.3
96
77
10-130
22
30
Hexachlorobenzene
ug/L
ND
83.3
83.3
99.4
98.2
119
118
27-145
1
30
Hexachlorocyclopentadiene
ug/L
ND
83.3
83.3
95.2
77.6
114
93
10-130
20
30
Hexachloroethane
ug/L
ND
83.3
83.3
55.7
48.2
67
58
10-130
15
30
Hexachloropropene
ug/L
ND
83.3
83.3
77.4
56.0
93
67
10-130
32
30 R1
Indeno(1,2,3-cd)pyrene
ug/L
ND
83.3
83.3
107
111
128
134
28-176
4
30
Isodrin
ug/L
ND
83.3
83.3
109
109
130
131
33-153
0
30
Isophorone
ug/L
ND
83.3
83.3
105
98.9
126
119
14-145
6
30
Isosafrole
ug/L
ND
83.3
83.3
93.4
86.4
112
104
13-136
8
30
Kepone
ug/L
ND
167
167
106
129
64
77
10-130
19
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 71 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4208123
MS
92698135002 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
4208124
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
Methapyrilene
ug/L
ND
83.3
83.3
ND
64.9J
32
78
10-200
30 v1
Methyl methanesulfonate
ug/L
ND
83.3
83.3
94.6
89.5
114
107
10-138
6
30
Methyl parathion
ug/L
ND
83.3
83.3
135
131
162
158
44-177
2
30
N-Nitroso-di-n-butylamine
ug/L
ND
83.3
83.3
87.2
80.4
105
97
14-133
8
30
N-Nitroso-di-n-propylamine
ug/L
ND
83.3
83.3
105
98.3
126
118
12-149
6
30
N-Nitrosodiethylamine
ug/L
ND
83.3
83.3
109
104
130
125
10-148
4
30
N-Nitrosodimethylamine
ug/L
ND
83.3
83.3
81.2
76.9
97
92
10-130
5
30
N-Nitrosodiphenylamine
ug/L
ND
83.3
83.3
92.0
96.4
110
116
29-149
5
30
N-Nitrosomethylethylamine
ug/L
ND
83.3
83.3
99.3
89.8
119
108
10-139
10
30
N-Nitrosopiperidine
ug/L
ND
83.3
83.3
114
107
137
129
14-151
7
30
N-Nitrosopyrrolidine
ug/L
ND
83.3
83.3
101
95.1
121
114
14-143
6
30
Nitrobenzene
ug/L
ND
83.3
83.3
102
90.7
123
109
10-145
12
30
0,0,0-
ug/L
ND
83.3
83.3
122
113
146
136
10-142
8
30 MO
Triethylphosphorothioate
O-Toluidine
ug/L
ND
83.3
83.3
91.0
97.3
109
117
10-137
7
30
P-
ug/L
ND
83.3
83.3
54.3
55.5
65
67
17-130
2
30
Dimethylaminoazobenzene
p-Phenylenediamine
ug/L
ND
ND
ND
30
Parathion (Ethyl parathion)
ug/L
ND
83.3
83.3
140
139
168
167
45-174
1
30
Pentachlorobenzene
ug/L
ND
83.3
83.3
105
95.6
126
115
20-143
9
30
Pentachloronitrobenzene
ug/L
ND
83.3
83.3
135
137
162
164
39-186
1
30
Pentachlorophenol
ug/L
ND
167
167
224
233
135
140
10-178
4
30
Phenacetin
ug/L
ND
83.3
83.3
119
123
143
147
36-185
3
30
Phenanthrene
ug/L
ND
83.3
83.3
97.8
98.7
117
118
36-146
1
30
Phenol
ug/L
ND
83.3
83.3
68.4
64.7
82
78
10-130
6
30
Phorate
ug/L
ND
83.3
83.3
114
113
137
136
26-200
1
30
Pronamide
ug/L
ND
83.3
83.3
117
122
141
146
40-181
4
30
Pyrene
ug/L
ND
83.3
83.3
101
104
121
125
42-156
3
30
Safrole
ug/L
ND
83.3
83.3
114
102
137
123
10-142
11
30
Thionazin
ug/L
ND
83.3
83.3
122
118
146
142
31-159
3
30
2,4,6-Tribromophenol (S)
%
122
127
10-166
2-Fluorobiphenyl (S)
%
101
95
10-130
2-Fluorophenol (S)
%
90
86
10-130
Nitrobenzene-d5 (S)
%
115
110
10-133
Phenol-d6 (S)
%
76
70
10-130
Terphenyl-d14 (S)
%
112
123
10-193
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 72 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 813358 Analysis Method: SM 2320B-2011
QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697340001
METHOD BLANK: 4211121
Matrix:
Water
Associated Lab Samples: 92697340001
Blank
Reporting
Parameter
Units
Result
Limit
Alkalinity, Total as CaCO3
mg/L
ND
5.0
LABORATORY CONTROL SAMPLE:
4211122
Spike
LCS
Parameter
Units
Conc.
Result
Alkalinity, Total as CaCO3
mg/L
50
51.3
LABORATORY CONTROL SAMPLE:
4211123
Spike
LCS
Parameter
Units
Conc.
Result
Alkalinity, Total as CaCO3
mg/L
50
50.0
MDL Analyzed Qualifiers
5.0 11 /15/23 17:40
LCS % Rec
% Rec Limits Qualifiers
103 80-120
LCS % Rec
% Rec Limits Qualifiers
100 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4211124 4211125
MS MSD
92697337006 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L 114 50 50 139 141 50 55 80-120 2 25 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4211126 4211127
MS MSD
92697337007 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L 176 50 50 200 201 48 50 80-120 1 25 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 73 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 813872 Analysis Method: SM 2320B-2011
QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92698166001
METHOD BLANK: 4213753
Associated Lab Samples: 92698166001
Parameter Units
Alkalinity, Total as CaCO3 mg/L
LABORATORY CONTROL SAMPLE: 4213754
Parameter Units
Alkalinity, Total as CaCO3 mg/L
Matrix: Water
Blank Reporting
Result Limit
ND 5.0
Spike LCS
Conc. Result
50 50.7
MDL Analyzed Qualifiers
5.0 11 /17/23 16:08
LCS % Rec
% Rec Limits Qualifiers
101 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4213756 4213757
MS MSD
92698009002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L 102 50 50 158 156 112 108 80-120 1 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4213758 4213759
MS MSD
92698009003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L 75.4 50 50 127 128 103 104 80-120 1 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 74 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 812030 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697340001
METHOD BLANK: 4204492
Matrix:
Water
Associated Lab Samples: 92697340001
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Total Dissolved Solids
mg/L
ND
2.5
2.5 11/09/23 10:47
LABORATORY CONTROL SAMPLE:
4204493
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Total Dissolved Solids
mg/L
250
244 97
90-110
SAMPLE DUPLICATE: 4204494
92697329001
Dup
Max
Parameter
Units
Result
Result RPD
RPD Qualifiers
Total Dissolved Solids
mg/L
12.3
11.3
8 25
SAMPLE DUPLICATE: 4204495
92697334005 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Dissolved Solids mg/L 16.5 16.8 2 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 75 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 811982 Analysis Method: SM 4500-S2D-2011
QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697340001
METHOD BLANK: 4204370
Matrix:
Water
Associated Lab Samples: 92697340001
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Sulfide
ug/L
ND
100
22.0 11/09/23 05:24
LABORATORY CONTROL SAMPLE:
4204371
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Sulfide
ug/L
500
462 92
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4204372 4204373
MS MSD
92697329001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide ug/L 0.030J 500 500 586 588 111 112 80-120 0 10
mg/L
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4204374 4204375
MS MSD
92697332002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide ug/L 0.036J 500 500 519 514 97 96 80-120 1 10
mg/L
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 76 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 812970 Analysis Method: SM 4500-S2D-2011
QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92698166001
METHOD BLANK: 4209421
Matrix:
Water
Associated Lab Samples: 92698166001
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Sulfide
ug/L
ND
100
22.0 11/14/23 04:02
LABORATORY CONTROL SAMPLE:
4209422
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Sulfide
ug/L
500
512 102
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4209423 4209424
MS MSD
92698166001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide ug/L ND 500 500 504 513 100 102 80-120 2 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4209425 4209426
MS MSD
92698009009 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide ug/L ND 500 500 276 294 51 55 80-120 6 10 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 77 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 812245
Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993
Analysis Description: 300.0 IC Anions
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697340001
METHOD BLANK: 4205872
Matrix: Water
Associated Lab Samples: 92697340001
Blank Reporting
Parameter Units
Result Limit
MDL
Analyzed Qualifiers
Chloride mg/L
ND 1.0
0.60 11/09/23 21:52
Sulfate mg/L
ND 1.0
0.50 11/09/23 21:52
LABORATORY CONTROL SAMPLE: 4205873
Spike LCS
LCS
% Rec
Parameter Units
Conc. Result
% Rec
Limits Qualifiers
Chloride mg/L
50 51.4
103
90-110
Sulfate mg/L
50 52.0
104
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4205874 4205875
MS MSD
92697615001
Spike Spike MS
MSD
MS MSD % Rec
Max
Parameter Units Result
Conc. Conc. Result
Result
% Rec % Rec Limits
RPD RPD Qual
Chloride mg/L 1690
50 50 1730
1720
80 73 90-110
0 10 M1
Sulfate mg/L 38.9
50 50 79.4
79.9
81 82 90-110
1 10 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4205876 4205877
MS MSD
92697337006
Spike Spike MS
MSD
MS MSD % Rec
Max
Parameter Units Result
Conc. Conc. Result
Result
% Rec % Rec Limits
RPD RPD Qual
Chloride mg/L 11.8
50 50 60.7
61.6
98 100 90-110
1 10
Sulfate mg/L 0.54J
50 50 62.4
64.0
124 127 90-110
3 10 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 78 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 813006
Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993
Analysis Description: 300.0 IC Anions
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92698166001
METHOD BLANK: 4209525
Matrix: Water
Associated Lab Samples: 92698166001
Blank Reporting
Parameter Units
Result Limit
MDL
Analyzed Qualifiers
Chloride mg/L
ND 1.0
0.60 11/14/2319:53
Sulfate mg/L
ND 1.0
0.50 11/14/2319:53
LABORATORY CONTROL SAMPLE: 4209526
Spike LCS
LCS
% Rec
Parameter Units
Conc. Result
% Rec
Limits Qualifiers
Chloride mg/L
50 51.3
103
90-110
Sulfate mg/L
50 51.5
103
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4209527 4209528
MS MSD
92697983003
Spike Spike MS
MSD
MS MSD % Rec
Max
Parameter Units Result
Conc. Conc. Result
Result
% Rec % Rec Limits
RPD RPD Qual
Chloride mg/L 14.2
50 50 64.5
65.6
101 103 90-110
2 10
Sulfate mg/L ND
50 50 51.0
52.0
101 103 90-110
2 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4209529 4209530
MS MSD
92698167002
Spike Spike MS
MSD
MS MSD % Rec
Max
Parameter Units Result
Conc. Conc. Result
Result
% Rec % Rec Limits
RPD RPD Qual
Chloride mg/L 1.2
50 50 52.3
52.5
102 103 90-110
0 10
Sulfate mg/L 1.9
50 50 53.2
53.4
103 103 90-110
0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 79 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 812548 Analysis Method: SM 4500-CN-E-2016
QC Batch Method: SM 4500-CN-E-2016 Analysis Description: 450OCNE Cyanide, Total
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697345001
METHOD BLANK: 4207198
Matrix:
Water
Associated Lab Samples: 92697345001
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
Cyanide
mg/L
ND
0.0080
0.0060 11/11/2310:31
LABORATORY CONTROL SAMPLE:
4207199
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Cyanide
mg/L
0.1
0.10
104 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4207200 4207201
MS MSD
92697649003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Cyanide mg/L ND 0.1 0.1 0.084 0.085 84 84 80-120 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4207202 4207203
MS MSD
92697708003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Cyanide mg/L ND 0.1 0.1 0.090 0.089 90 89 80-120 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 80 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 812877 Analysis Method: SM 4500-CN-E-2016
QC Batch Method: SM 4500-CN-E-2016 Analysis Description: 450OCNE Cyanide, Total
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697340001
METHOD BLANK: 4208833
Matrix:
Water
Associated Lab Samples: 92697340001
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Cyanide
ug/L
ND
8.0
6.0 11/14/23 20:16
LABORATORY CONTROL SAMPLE:
4208834
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Cyanide
ug/L
100
84.4 84
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4208835 4208836
MS MSD
92698047003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Cyanide ug/L 0.013 100 100 73.1 76.8 60 64 80-120 5 10 M1
mg/L
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4208837 4208838
MS MSD
92697811001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Cyanide ug/L ND 100 100 ND ND 0 0 80-120 10 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 81 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 814295 Analysis Method: SM 4500-CN-E-2016
QC Batch Method: SM 4500-CN-E-2016 Analysis Description: 450OCNE Cyanide, Total
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92698166001
METHOD BLANK: 4216177
Matrix:
Water
Associated Lab Samples: 92698166001
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Cyanide
ug/L
ND
8.0
6.0 11/18/2316:22
LABORATORY CONTROL SAMPLE:
4216178
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Cyanide
ug/L
100
105 105
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4216179 4216180
MS MSD
92697843005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Cyanide ug/L ND 100 100 98.6 98.5 92 92 80-120 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 82 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
QC Batch: 814397 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697337005
METHOD BLANK: 4216419
Associated Lab Samples: 92697337005
Parameter Units
Total Organic Carbon mg/L
LABORATORY CONTROL SAMPLE: 4216420
Parameter Units
Total Organic Carbon mg/L
Matrix: Water
Blank Reporting
Result Limit
ND 1.0
Spike LCS
Conc. Result
25 24.1
MDL Analyzed Qualifiers
0.50 11 /20/23 10:52
LCS % Rec
% Rec Limits Qualifiers
96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4216421 4216422
MS MSD
92697473004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon mg/L 3.9 25 25 28.5 28.1 98 97 90-110 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4216423 4216424
MS MSD
92697473005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon mg/L 2.9 25 25 26.8 27.0 96 97 90-110 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC.
Page 83 of 90

Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
aceo Huntersville, NC 28078
[phone]
QUALIFIERS
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
AC Analysis of acrolein and/or acrylonitrile was performed from a sample that was field preserved to pH < 2, which is less
than the pH range of 4-5 specified in the test method and required for NPDES compliance per 40CFR Part 136.
B Analyte was detected in the associated method blank.
D6 The precision between the sample and sample duplicate exceeded laboratory control limits.
E Analyte concentration exceeded the calibration range. The reported result is estimated.
H1 Analysis conducted outside the EPA method holding time.
L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.
L2 Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.
MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
R2 RPD value was outside control limits due to matrix interference
SO Surrogate recovery outside laboratory control limits.
S3 Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated sample.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
ANALYTE QUALIFIERS
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 85 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Burke Co. Johns R Background
92697340
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92697351001
1203-MW-21
AM20
307943
92697337005
1203-MW-21
EPA 353.2 Rev 2.0 1993
811687
92697340001
1203-MW21
8151A
2169599
EPA8151
2169599
92697340001
1203-MW21
EPA 3510C
811670
EPA 8081 B
812042
92698166001
1203-FIELD
BLANK
EPA 3510C
812712
EPA 8081 B
813712
92697340001
1203-MW21
EPA 3510C
812855
EPA 8082A
812985
92698166001
1203-FIELD
BLANK
EPA 3510C
812713
EPA 8082A
813713
92697337005
1203-MW-21
RSK 175 Modified
812107
92697340001
1203-MW21
EPA 3010A
812399
EPA 6010D
812526
92697345001
1203-SMP6
EPA 3010A
812399
EPA 6010D
812526
92698166001
1203-FIELD
BLANK
EPA 3010A
813065
EPA6010D
813228
92697340001
1203-MW21
EPA 3010A
812425
EPA 6020B
812510
92697345001
1203-SMP6
EPA 3010A
812425
EPA 6020B
812510
92698166001
1203-FIELD
BLANK
EPA 3010A
812973
EPA 6020B
812975
92697340001
1203-MW21
EPA 7470A
812700
EPA 7470A
812702
92697345001
1203-SMP6
EPA 7470A
812700
EPA 7470A
812702
92698166001
1203-FIELD
BLANK
EPA 7470A
813394
EPA 7470A
813886
92697340001
1203-MW21
EPA 3510C
811997
EPA 8270E
812452
92698166001
1203-FIELD
BLANK
EPA 3510C
812753
EPA 8270E
813040
92697340001
1203-MW21
EPA 8260D
812793
92697340002
Trip Blank
EPA 8260D
812793
92697345001
1203-SMP6
EPA 8260D
812467
92697340001
1203-MW21
EPA 8260D Mod.
812181
92697345001
1203-SMP6
EPA 8260D Mod.
812181
92698166001
1203-FIELD
BLANK
EPA 8260D Mod.
812926
92697340001
1203-MW21
SM 2320B-2011
813358
92698166001
1203-FIELD
BLANK
SM 2320B-2011
813872
92697340001
1203-MW21
SM 2540C-2015
812030
92697340001
1203-MW21
SM 4500-S2D-2011
811982
92698166001
1203-FIELD
BLANK
SM 4500-S2D-2011
812970
92697340001
1203-MW21
EPA 300.0 Rev 2.1 1993
812245
92698166001
1203-FIELD
BLANK
EPA 300.0 Rev 2.1 1993
813006
92697345001
1203-SMP6
SM 4500-CN-E-2016
812548
SM 4500-CN-E-2016
812599
92697340001
1203-MW21
SM 4500-CN-E-2016
812877
SM 4500-CN-E-2016
813245
Date: 11/28/2023 12:33 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 86 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Burke Co. Johns R Background
Pace Project No.: 92697340
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92698166001 1203-FIELD BLANK SM 4500-CN-E-2016 814295 SM 4500-CN-E-2016 814318
92697337005 1203-MW-21 SM 531OB-2014 814397
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 87 of 90

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Pace
DC#_Title: ENV-FRM-HUN1-0084 v01_Tech Spec Sample Condition
Upon Receipt
Effective Date: 05/12/2022
Laboratory receiving samples:
Asheville ❑ Eden ❑ Greenwood ❑ Huntersville ❑ Raleigh[] Mechanicsville[] Atlanta[] Kernersville[f
Courier:
❑ Commercial
Carrier Tracking Number:
Client Name:
tr a H't 11 a
❑Fed Ex []UPS
❑Pace
f f D 4 4t 14 f Project #:
❑LISPS PfCIient
❑Other:
Custody Seal Present? ❑Yes []No Seals Intact? ❑Yes ❑No
Packing Material: []Bubble Wrap []Bubble Bags ❑None ❑ Other
o Z
gµr9e C a -
�d kr f
$atleg r#Kild
Date/Initials Person Examining Contents: rf
Biological Tissue Fr zen?
[]Yes❑No [ N/A
Thermometer: ❑ IR Gun ID: te—f' I U Type of Ice: EfWet ❑ Blue ❑ None
Cooler Temp ('C ): $ ' + Correction Factor: Add / Subtract ('C 1 r Temp should be above freezing to 6"C
Corrected Cooler Temp ('C
❑Samples out of temp criteria. Samples on ice, cooling process
I:has begun
USDA Regulated Soil ( [/1 N/A, water sample}
Did samples originate in a quarant ne zone within the United States CA, NY, or SC (check maps)? Did xamples originate From a foreign source (internationally,
❑Yes ❑No kncluding Hawaii and Puerto Rico)? ❑Yes ❑No
Comments/Discrepancy:
Chain of Custody Present?
es
❑No
N/A
1.
Samples Arrived within Ho d Time?
12ryes
❑No
❑N/A
2
Short Hold Time Analysis (<72 hr.)?
Na
❑N!A
3
Rush Turn Around Time Requested?
—[]Yes
[]Yet
No
❑N; A
4
Sufficient Volume?
❑Yes
E3N.
❑N. A
9.
Correct Containers Used?
Pace Containers Used?
VYes
es
❑No
[]No
[]N/A
[]N/A
6.
Containers Intact?
es
QNo
❑N/A
7.
Dissolved analysis: Samples Field Filtered?
❑Yes
[:]No
dNJA
S.
Sample Labels Match COC?
-Includes Date/Time/ID/Analysis Matrix:
TYes
r
[]No
[:]NIA
9.
Headspace in VOA Vials (>5-6mm)?
[]Yes
[!fNo
❑NJA
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
❑Yes
❑Yes
[:]No
ONo
[]N/A
[]N/A
11.
COMMEN15/5AMPLE D15CREPANCY
Temp Log: Temp must be maintained
at <6 C during login, record temp
every 20 minutes.
Time opened4't�0 Temp: S.
Time: I, qV57 put in cooler
Time: Temp:
Person Contacted:
Project Manager SCURF Review:
Project Manager SRF Review:
Qualtrax Document ID- 70677
Field Data Required? ❑Yes ❑No
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Date/TimP:
Date:
Date:
Page 1 of 2
Page 89 of 90

Document Narre Document Issued November 15, 2021
Bottle Identification Form IBIFI _ Page 1 of 1 _
T'�fGL'Alh��jlCr7j Document No Issuing Authority:
F•CAR-CS-043-Rev.01 Pace Carolina$ Quality Office
*Check mark top half of box if pH and/or dechlorination is Project i#
verified and within the acceptance range for preservation
samples.
Exceptions VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottles
E
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot p
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 90 of 90

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
November 28, 2023
Mr. Van Burbach
LaBella Associates, D.P.C.
12-D Oak Branch Drive
Greensboro, NC 27407
RE: Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory between November 07, 2023 and November
10, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable
TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the
report.
Some analyses were subcontracted outside of the Pace Network. The test report from the external subcontractor is
attached to this report in its entirety.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace National - Mt. Juliet
• Pace Analytical Services - Asheville
• Pace Analytical Services - Baton Rouge
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Eden
• Pace Analytical Services - Ormond Beach
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor M Cannon
[e-mail]
704-977-0943
Project Manager
Enclosures
cc: Van Burbach, LaBella Associates, DPC
Kandice Estes, Labella Associates
�pQ ACcrlFO
C REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
9eO without the written consent of Pace Analytical Services, LLC.
Page 1 of 130

Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Pace Analytical Services Ormond Beach
8 East Tower Circle, Ormond Beach, FL 32174
Alaska DEC- CS/UST/LUST
Alabama Certification #: 41320
Colorado Certification: FL NELAC Reciprocity
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
DoD-ANAB MADE-3199
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maine Certification #: FL01264
Maryland Certification: #346
Massachusetts Certification #: M-FL1264
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Pace Analytical Services National
12065 Lebanon Road, Mt. Juliet, TN 37122
Alabama Certification #: 40660
Alaska Certification 17-026
Arizona Certification #: AZ0612
Arkansas Certification #: 88-0469
California Certification #: 2932
Canada Certification #: 1461.01
Colorado Certification #: TN00003
Connecticut Certification #: PH-0197
DOD Certification: #1461.01
EPA# TN00003
Florida Certification #: E87487
Georgia DW Certification #: 923
Georgia Certification: NELAP
Idaho Certification #: TN00003
Illinois Certification #: 200008
Indiana Certification #: C-TN-01
Iowa Certification #: 364
Kansas Certification M E-10277
Kentucky UST Certification #: 16
Kentucky Certification #: 90010
Louisiana Certification #: A130792
Louisiana DW Certification #: LA180010
Maine Certification #: TN0002
Maryland Certification #: 324
Massachusetts Certification #: M-TNO03
Michigan Certification #: 9958
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
CERTIFICATIONS
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
New Hampshire Certification #: 2958
New Jersey Certification #: FL022
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Ohio DEP 87780
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Minnesota Certification #: 047-999-395
Mississippi Certification #: TN00003
Missouri Certification #: 340
Montana Certification #: CERT0086
Nebraska Certification #: NE-OS-15-05
Nevada Certification #: TN-03-2002-34
New Hampshire Certification #: 2975
New Jersey Certification #: TNO02
New Mexico DW Certification
New York Certification #: 11742
North Carolina Aquatic Toxicity Certification #: 41
North Carolina Drinking Water Certification #: 21704
North Carolina Environmental Certificate #: 375
North Dakota Certification #: R-140
Ohio VAP Certification #: CL0069
Oklahoma Certification #: 9915
Oregon Certification #: TN200002
Pennsylvania Certification #: 68-02979
Rhode Island Certification #: LA000356
South Carolina Certification #: 84004
South Dakota Certification
Tennessee DW/Chem/Micro Certification #: 2006
Texas Mold Certification #: LAB0152
Texas Certification #: T 104704245-17-14
USDA Soil Permit #: P330-15-00234
Utah Certification #: TN00003
Virginia Certification #: VT2006
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Pace Analytical Services National
Vermont Dept. of Health: ID# VT-2006
Virginia Certification #: 460132
Washington Certification #: C847
West Virginia Certification #: 233
Wisconsin Certification #: 998093910
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification M E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
Pace Analytical Services Eden
205 East Meadow Road Suite A, Eden, NC 27288
North Carolina Drinking Water Certification #: 37738
Pace Analytical Services Baton Rouge
7979 Innovation Park Drive Ste A, Baton Rouge, LA
70820-7402
Louisiana Dept of Enviromental Quality (NELAC/LELAP):
01979
Florida Dept of Health (NELAC/FELAP): E87854
DoD ELAP (A2LA) #: 6429.01
Alabama DEM #: 41900
Alaska DEC-DW #: LA00024
Alaska DEC CS -LAP #: 21-001
Arkansas DEQ #: 88-0655
California ELAP #: 3063
Georgia DPD #: C050
Hawaii DOH State Laboratories Division
Illinois EPA#: 200048
Kansas DoHE #: E-10354
Kentucky DEP UST Branch #: 123054
Louisiana DOH #: LA036
Minnesota DOH #: 2233799
Mississippi State Dept of Health
CERTIFICATIONS
Wyoming UST Certification #: via A21-A 2926.01
A21-A-ISO 17025 Certification #: 1461.01
A21-A-ISO 17025 Certification #: 1461.02
AIHA-LAP/LLC EMLAP Certification #:100789
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification #: 633
Virginia/VELAP Certification #: 460025
Montana Department of Environmental Quality
Nebraska DHHS #: NE-OS-35.21
Nevada DCNR DEP #: LA00024
New York DOH #: 12149
North Carolina DEQ - WW & GW #: 618
North Dakota DEQ #: R195
Ohio EPA#: 87782
Oklahoma Dept of Environmental Quality #: 9403
Oregon ELAP #: 4168
Pennsylvania Dept of Environmental Protection #: 68-
05973
South Carolina DHEC #: 73006001
Texas CEQ #: T104704178-23-15
Utah DOH #: LA00024
Virginia DCLS #: 6460215
Washington Dept of Ecology #: C929
Wisconsin DNR #: 399139510
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92697334001
1203-MW-10
Water
11/07/2314:44
11/07/23 17:05
92697334002
1203-MW-11
Water
11/06/23 13:52
11/07/23 17:05
92697334003
1203-MW-12
Water
11/06/2315:49
11/07/23 17:05
92697334004
1203-MW-13
Water
11/07/23 14:55
11/07/23 17:05
92697334005
1203-MW-16S
Water
11/07/2313:33
11/07/23 17:05
92697337001
1203-MW-10
Water
11/07/2314:44
11/07/23 17:05
92697337002
1203-MW-11
Water
11/06/23 13:52
11/07/23 17:05
92697337003
1203-MW-12
Water
11/06/2315:49
11/07/23 17:05
92697337004
1203-MW-16S
Water
11/07/23 13:33
11/07/23 17:05
92697337006
1203-MW-18
Water
11/07/2310:14
11/07/23 17:05
92697337007
1203-MW-19
Water
11/07/2311:55
11/07/23 17:05
92697351002
1203-MW-19
Water
11/07/2311:55
11/07/23 17:05
92697351003
1203-MW-18
Water
11/07/2310:14
11/07/23 17:05
92697351004
1203-MW-11
Water
11/06/23 13:52
11/07/23 17:05
92697351005
1203-MW-12
Water
11/06/2315:49
11/07/23 17:05
92697351006
1203-MW-16S
Water
11/07/2313:33
11/07/23 17:05
92698172001
1203-MW-36
Water
11/08/23 09:12
11/10/23 09:45
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
92697334001
1203-MW-10
EPA 8151
RDH
5
PAN
EPA 8081 B
SEM
21
PASI-C
EPA 8082A
SEM
8
PASI-C
EPA 6010D
DBB1
17
PASI-A
EPA 6020E
KRL
1
PASI-A
EPA 7470A
BM
1
PASI-A
EPA 8270E
PKS
112
PASI-C
EPA 8260D
LMB
62
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 2540C-2015
JAY
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
2
PASI-A
SM 4500-CN-E-2016
MMA
1
PASI-A
92697334002
1203-MW-11
EPA 8151
RDH
5
PAN
EPA 8081 B
SEM
21
PASI-C
EPA 8082A
SEM
8
PASI-C
EPA 6010D
DBB1
17
PASI-A
EPA 6020E
KRL
1
PASI-A
EPA 7470A
BM
1
PASI-A
EPA 8270E
PKS
112
PASI-C
EPA 8260D
LMB
62
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 2540C-2015
JAY
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
2
PASI-A
SM 4500-CN-E-2016
MMA
1
PASI-A
92697334003
1203-MW-12
EPA 8151
RDH
5
PAN
EPA 8081 B
SEM
21
PASI-C
EPA 8082A
SEM
8
PASI-C
EPA 6010D
DBB1
17
PASI-A
EPA 6020E
KRL
1
PASI-A
EPA 7470A
BM
1
PASI-A
EPA 8270E
PKS
112
PASI-C
EPA 8260D
LMB
62
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 5 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Johns R. C&D/MSWLF GW
92697334
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
SM 2320B-2011
SMS
1
PASI-A
SM 2540C-2015
JAY
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
2
PASI-A
SM 4500-CN-E-2016
MMA
1
PASI-A
92697334004
1203-MW-13
EPA 8151
NWH
5
PAN
EPA 8081 B
SEM
21
PASI-C
EPA 8082A
SEM
8
PASI-C
EPA 6010D
DBB1
17
PASI-A
EPA 6020E
KRL
1
PASI-A
EPA 7470A
BM
1
PASI-A
EPA 8270E
PKS
112
PASI-C
EPA 8260D
LMB
62
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 2540C-2015
JAY
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
2
PASI-A
SM 4500-CN-E-2016
MMA
1
PASI-A
92697334005
1203-MW-16S
EPA 8151
RDH
5
PAN
EPA 8081 B
SEM
21
PASI-C
EPA 8082A
SEM
8
PASI-C
EPA 6010D
DBB1
17
PASI-A
EPA 6020E
KRL
1
PASI-A
EPA 7470A
BM
1
PASI-A
EPA 8270E
PKS
112
PASI-C
EPA 8260D
JJK
62
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 2540C-2015
JAY
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
2
PASI-A
SM 4500-CN-E-2016
MMA
1
PASI-A
92697337001
1203-MW-10
EPA 353.2 Rev 2.0 1993
SRS
1
PASI-E
RSK 175 Modified
TEG
1
PASI-C
SM 5310B-2014
KDF1
1
PASI-A
92697337002
1203-MW-11
EPA 353.2 Rev 2.0 1993
SRS
1
PASI-E
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 6 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Johns R. C&D/MSWLF GW
Pace Project No.:
92697334
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
RSK 175 Modified
TEG
1
PASI-C
SM 531OB-2014
KDF1
1
PASI-A
92697337003
1203-MW-12
EPA 353.2 Rev 2.0 1993
SRS
1
PASI-E
RSK 175 Modified
TEG
1
PASI-C
SM 531OB-2014
KDF1
1
PASI-A
92697337004
1203-MW-16S
EPA 353.2 Rev 2.0 1993
SRS
1
PASI-E
RSK 175 Modified
TEG
1
PASI-C
SM 531OB-2014
KDF1
1
PASI-A
92697337006
1203-MW-18
EPA 353.2 Rev 2.0 1993
SRS
1
PASI-E
RSK 175 Modified
TEG
1
PASI-C
EPA 6010
AME, TMA
3
PASI-O
EPA 6020
LEC
1
PASI-O
EPA 7470
JNK
1
PASI-O
EPA 8260D
JJK
11
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 2540C-2015
JAY
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
2
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92697337007
1203-MW-19
EPA 353.2 Rev 2.0 1993
SRS
1
PASI-E
RSK 175 Modified
TEG
1
PASI-C
EPA 6010
AME, TMA
3
PASI-O
EPA 6020
LEC
1
PASI-O
EPA 7470
JNK
1
PASI-O
EPA 8260D
JJK
11
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 2540C-2015
JAY
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
2
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92697351002
1203-MW-19
AM20
LB
1
PASI-BR
92697351003
1203-MW-18
AM20
LB
1
PASI-BR
92697351004
1203-MW-11
AM20
LB
1
PASI-BR
92697351005
1203-MW-12
AM20
LB
1
PASI-BR
92697351006
1203-MW-16S
AM20
LB
1
PASI-BR
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 7 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Johns R. C&D/MSWLF GW
92697334
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92698172001
1203-MW-36
RSK 175 Modified
TEG
1
PASI-C
EPA 6010
AME
3
PASI-O
EPA 6020
EAP
1
PASI-O
EPA 7470
JNK
1
PASI-O
EPA 8260D
LMB
11
PASI-C
PAN = Pace National - Mt. Juliet
PASI-A = Pace Analytical Services - Asheville
PASI-BR = Pace Analytical Services - Baton Rouge
PASI-C = Pace Analytical Services - Charlotte
PASI-E = Pace Analytical Services - Eden
PASI-O = Pace Analytical Services - Ormond Beach
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92697334001
1203-MW-10
EPA 601OD
Antimony
3.8J
ug/L
5.0
11/13/2316:44
EPA 601OD
Barium
97.3
ug/L
5.0
11/13/2316:44
EPA 601OD
Cadmium
0.33J
ug/L
1.0
11/13/2316:44
EPA 601OD
Chromium
3.8J
ug/L
5.0
11/13/2316:44
EPA 601OD
Cobalt
47.5
ug/L
5.0
11/13/2316:44
EPA 601OD
Copper
5.6
ug/L
5.0
11/13/2316:44
EPA 601OD
Iron
22800
ug/L
50.0
11/13/2316:44
EPA 601OD
Lead
5.5
ug/L
5.0
11/13/2316:44
EPA 601OD
Manganese
3190
ug/L
5.0
11/13/2316:44
EPA 601OD
Nickel
4.9J
ug/L
5.0
11/13/2316:44
EPA 601OD
Vanadium
6.1
ug/L
5.0
11/13/2316:44
EPA 601OD
Zinc
25.8
ug/L
10.0
11/13/2316:44
EPA6020B
Thallium
0.49
ug/L
0.20
11/12/2319:01
EPA7470A
Mercury
1.8
ug/L
0.20
11/18/2311:38
EPA 8260D
Benzene
1.5
ug/L
1.0
11/11/2311:37
EPA 8260D
Chlorobenzene
1.5
ug/L
1.0
11/11/2311:37
EPA 8260D
1,4-Dichlorobenzene
1.2
ug/L
1.0
11/11/2311:37
EPA 8260D
cis-1,2-Dichloroethene
2.3
ug/L
1.0
11/11/2311:37
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
1.0J
ug/L
2.0
11/10/23 03:57
SM 2320B-2011
Alkalinity, Total as CaCO3
48.5
mg/L
5.0
11/15/23 19:57
SM 2540C-2015
Total Dissolved Solids
8.4
mg/L
2.5
11/09/23 10:48
SM 4500-S2D-2011
Sulfide
23AJ
ug/L
100
11/09/23 05:41
EPA 300.0 Rev 2.1 1993
Chloride
12.0
mg/L
1.0
11/09/23 23:18
EPA 300.0 Rev 2.1 1993
Sulfate
1.3
mg/L
1.0
11/09/23 23:18
92697334002
1203-MW-11
EPA 601OD
Barium
168
ug/L
5.0
11/13/2316:47
EPA 601OD
Cadmium
1.0
ug/L
1.0
11/13/2316:47
EPA 601OD
Chromium
6.1
ug/L
5.0
11/13/2316:47
EPA 601OD
Cobalt
19.8
ug/L
5.0
11/13/2316:47
EPA 601OD
Iron
136000
ug/L
1000
11/14/2315:13
EPA 601OD
Manganese
25700
ug/L
100
11/14/2315:13
EPA 601OD
Nickel
9.8
ug/L
5.0
11/13/2316:47
EPA 601OD
Silver
0.56J
ug/L
5.0
11/13/2316:47
EPA 601OD
Zinc
13.0
ug/L
10.0
11/13/2316:47
EPA6020B
Thallium
0.52
ug/L
0.20
11/12/2319:26
EPA 8260D
Benzene
2.7
ug/L
1.0
11/11/2311:55
EPA 8260D
Chlorobenzene
0.97J
ug/L
1.0
11/11/2311:55
EPA 8260D
Chloroethane
1.0
ug/L
1.0
11/11/2311:55
EPA 8260D
1,2-Dichlorobenzene
0.34J
ug/L
1.0
11/11/2311:55
EPA 8260D
1,4-Dichlorobenzene
11.9
ug/L
1.0
11/11/2311:55
EPA 8260D
1,1-Dichloroethane
2.0
ug/L
1.0
11/11/2311:55
EPA 8260D
cis-1,2-Dichloroethene
3.1
ug/L
1.0
11/11/2311:55
EPA 8260D
Toluene
0.29J
ug/L
1.0
11/11/2311:55
EPA 8260D
Vinyl chloride
1.4
ug/L
1.0
11/11/23 11:55
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
35.5
ug/L
2.0
11/10/23 04:18
SM 2320B-2011
Alkalinity, Total as CaCO3
213
mg/L
5.0
11/16/23 10:18
SM 2540C-2015
Total Dissolved Solids
47.0
mg/L
2.5
11/09/23 10:48
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 9 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Lab Sample ID Client Sample ID
Method Parameters
92697334002
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
92697334003
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6010D
EPA 8270E
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D Mod.
SM 2320B-2011
SM 2540C-2015
SM 4500-S2D-2011
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
92697334004
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6020B
EPA 7470A
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
1203-MW-11
Chloride
Sulfate
1203-MW-12
Barium
Chromium
Cobalt
Iron
Manganese
Nickel
2-Methylnaphthalene
Benzene
Chlorobenzene
Chloroethane
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
cis-1,2-Dichloroethene
Ethylbenzene
Toluene
Trichloroethene
Vinyl chloride
Xylene (Total)
1,4-Dioxane (p-Dioxane)
Alkalinity, Total as CaCO3
Total Dissolved Solids
Sulfide
Chloride
Sulfate
1203-MW-13
Barium
Cadmium
Chromium
Cobalt
Copper
Iron
Lead
Manganese
Nickel
Vanadium
Zinc
Thallium
Mercury
Benzene
Chlorobenzene
1,2-Dichlorobenzene
1,4-Dichlorobenzene
SUMMARY OF DETECTION
Result
Units
Report Limit
Analyzed Qualifiers
93.8
mg/L
1.0
11/09/23 23:33
6.9
mg/L
1.0
11/09/23 23:33
66.6
ug/L
5.0
11/13/2316:50
3AJ
ug/L
5.0
11/13/2316:50
33.9
ug/L
5.0
11/13/2316:50
47000
ug/L
50.0
11/13/2316:50
14000
ug/L
50.0
11/14/2315:15
5.3
ug/L
5.0
11/13/2316:50
16.6
ug/L
8.3
11/12/2318:17
3.6
ug/L
1.0
11/11/2312:14
0.85J
ug/L
1.0
11/11/2312:14
5.7
ug/L
1.0
11/11/2312:14
5.4
ug/L
1.0
11/11/2312:14
18.2
ug/L
1.0
11/11/2312:14
0.97J
ug/L
1.0
11/11/2312:14
9.5
ug/L
1.0
11/11/2312:14
0.62J
ug/L
1.0
11/11/2312:14
0.77J
ug/L
1.0
11/11/2312:14
2.1
ug/L
1.0
11/11/2312:14
0.69J
ug/L
1.0
11/11/2312:14
2.8
ug/L
1.0
11/11/2312:14
13.1
ug/L
2.0
11/10/23 04:40
134
mg/L
5.0
11/15/2319:14
16.4
mg/L
2.5
11/09/2310:48
41.1 J
ug/L
100
11/09/23 05:37
17.0
mg/L
1.0
11/09/23 23:47
1.2
mg/L
1.0
11/09/23 23:47
82.4
ug/L
5.0
11/13/2316:52
0.31J
ug/L
1.0
11/13/2316:52
1.4J
ug/L
5.0
11/13/2316:52
69.8
ug/L
5.0
11/13/2316:52
12.0
ug/L
5.0
11/13/2316:52
3090
ug/L
50.0
11/13/2316:52
2.OJ
ug/L
5.0
11/13/2316:52
1930
ug/L
5.0
11/13/2316:52
4AJ
ug/L
5.0
11/13/2316:52
2AJ
ug/L
5.0
11/13/2316:52
18.4
ug/L
10.0
11/13/2316:52
0.18J
ug/L
0.20
11/12/2319:51
3.1
ug/L
0.20
11/18/2311:45
11.6
ug/L
1.0
11/11/2312:32
1.7
ug/L
1.0
11/11/2312:32
0.77J
ug/L
1.0
11/11/2312:32
20.9
ug/L
1.0
11/11/2312:32
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 10 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Lab Sample ID Client Sample ID
Method Parameters
92697334004
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D Mod.
SM 2540C-2015
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
92697334005
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6010D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D
EPA 8260D Mod.
SM 2320B-2011
SM 2540C-2015
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
92697337001
EPA 353.2 Rev 2.0 1993
RSK 175 Modified
SM 5310B-2014
92697337002
RSK 175 Modified
SM 5310B-2014
92697337003
EPA 353.2 Rev 2.0 1993
1203-MW-13
1,1-Dichloroethane
1,2-Dichloroethane
cis-1,2-Dichloroethene
Ethylbenzene
Methylene Chloride
Naphthalene
Tetrachloroethene
Toluene
Trichloroethene
Xylene (Total)
1,4-Dioxane (p-Dioxane)
Total Dissolved Solids
Chloride
Sulfate
1203-MW-16S
Barium
Chromium
Cobalt
Iron
Manganese
Nickel
Zinc
Benzene
Chlorobenzene
Chloroethane
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
cis-1,2-Dichloroethene
Trichloroethene
Vinyl chloride
1,4-Dioxane (p-Dioxane)
Alkalinity, Total as CaCO3
Total Dissolved Solids
Chloride
Sulfate
1203-MW-10
Nitrogen, Nitrate
Methane
Total Organic Carbon
1203-MW-11
Methane
Total Organic Carbon
1203-MW-12
Nitrogen, Nitrate
SUMMARY OF DETECTION
Result
Units
Report Limit
Analyzed Qualifiers
10.3
ug/L
1.0
11/11/2312:32
0.65J
ug/L
1.0
11/11/2312:32
18.4
ug/L
1.0
11/11/2312:32
1.4
ug/L
1.0
11/11/2312:32
38.5
ug/L
5.0
11/11/2312:32
3.1
ug/L
1.0
11/11/2312:32
4.1
ug/L
1.0
11/11/2312:32
1.6
ug/L
1.0
11/11/2312:32
6.2
ug/L
1.0
11/11/2312:32
53.5
ug/L
1.0
11/11/2312:32
1.7J
ug/L
2.0
11/10/23 05:01
3.3
mg/L
2.5
11/09/2310:48
2.0
mg/L
1.0
11/10/23 00:02
1.2
mg/L
1.0
11/10/23 00:02
60.3
ug/L
5.0
11/13/2316:55
3.7J
ug/L
5.0
11/13/2316:55
28.0
ug/L
5.0
11/13/2316:55
39200
ug/L
50.0
11/13/2316:55
13700
ug/L
50.0
11 /21 /23 12:16
5.1
ug/L
5.0
11/13/2316:55
4.OJ
ug/L
10.0
11/13/2316:55
3.0
ug/L
1.0
11/10/2319:46
1.0
ug/L
1.0
11/10/2319:46
4.5
ug/L
1.0
11/10/2319:46
7.8
ug/L
1.0
11/10/2319:46
11.9
ug/L
1.0
11/10/2319:46
1.0
ug/L
1.0
11/10/2319:46
6.8
ug/L
1.0
11/10/2319:46
0.43J
ug/L
1.0
11/10/2319:46
1.0
ug/L
1.0
11/10/2319:46
13.3
ug/L
2.0
11/10/23 05:22
136
mg/L
5.0
11/15/23 20:13
16.5
mg/L
2.5
11/09/2310:48
13.0
mg/L
1.0
11/10/23 01:00
1.1
mg/L
1.0
11/10/23 01:00
0.046
mg/L
0.040
11/08/23 09:23
647
ug/L
10.0
11/09/2315:51
0.73J
mg/L
1.0
11/17/23 07:03
2820
ug/L
10.0
11/09/2316:07
7.8
mg/L
1.0
11/17/23 07:23
0.052
mg/L
0.040
11/08/23 09:25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 11 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Lab Sample ID
Method
92697337003
RSK 175 Modified
SM 531OB-2014
92697337004
EPA 353.2 Rev 2.0 1993
RSK 175 Modified
SM 531OB-2014
92697337006
RSK 175 Modified
EPA 6010
EPA 6010
EPA 6010
EPA 6020
EPA 8260D
EPA 8260D Mod.
SM 2320B-2011
SM 254OC-2015
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
SM 531OB-2014
92697337007
RSK 175 Modified
EPA 6010
EPA 6010
EPA 6010
EPA 8260D
SM 2320B-2011
SM 254OC-2015
SM 4500-S2D-2011
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
SM 531OB-2014
92697351002
AM20
92697351003
AM20
92697351005
AM20
92697351006
AM20
92698172001
RSK 175 Modified
EPA 6010
Client Sample ID
Parameters
1203-MW-12
Methane
Total Organic Carbon
1203-MW-16S
Nitrogen, Nitrate
Methane
Total Organic Carbon
1203-MW-18
Methane
Cobalt
Iron
Manganese
Thallium
Vinyl chloride
1,4-Dioxane (p-Dioxane)
Alkalinity, Total as CaCO3
Total Dissolved Solids
Chloride
Sulfate
Total Organic Carbon
1203-MW-19
Methane
Cobalt
Iron
Manganese
1,1-Dichloroethane
Alkalinity, Total as CaCO3
Total Dissolved Solids
Sulfide
Chloride
Sulfate
Total Organic Carbon
1203-MW-19
Hydrogen
1203-MW-18
Hydrogen
1203-MW-12
Hydrogen
1203-MW-16S
Hydrogen
1203-MW-36
Methane
Cobalt
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
5920 ug/L 10.0 11/09/2316:52 D6
1.5 mg/L 1.0 11/17/23 07:44
0.076 mg/L 0.040 11/08/23 09:24
3870 ug/L 10.0 11/09/2317:08
1.6 mg/L 1.0 11/17/23 08:03
2690 ug/L 10.0 11/09/2317:40
9AJ ug/L 10.0 11/16/2315:55
102000 ug/L 400 11/17/23 03:34
6600 ug/L 50.0 11/17/23 03:34
0.25J ug/L 1.0 11/16/2317:24
0.61J ug/L 1.0 11/10/2320:04
3.8 ug/L 2.0 11/10/2312:10
114 mg/L 5.0 11/15/23 20:46 M1
14.2 mg/L 2.5 11/09/2310:48
11.8 mg/L 1.0 11/10/23 01:14
0.54J mg/L 1.0 11/10/23 01:14 M1
3.0 mg/L 1.0 11/20/2312:39
2240 ug/L 10.0 11/09/2317:56
25.3 ug/L 10.0 11/16/2315:59
62500 ug/L 200 11/17/23 03:37
14700 ug/L 100 11/17/23 03:41
0.54J ug/L 1.0 11/11/2313:39
176 mg/L 5.0 11/15/23 21:13 M1
20.3 mg/L 2.5 11/09/2310:48
0.031J mg/L 0.10 11/09/2305:45
1.5 mg/L 1.0 11/10/23 01:58
2.4 mg/L 1.0 11/10/23 01:58
4.3 mg/L 1.0 11/20/2313:02
3.0 nMoles 1.9 11/14/23 09:13
1.6J nMoles 1.9 11/14/23 09:25
1.4J nMoles 1.9 11/14/23 09:56
5.3 nMoles 1.9 11/14/2311:00
3470 ug/L 10.0 11/14/2317:57
34.0 ug/L 10.0 11/21/23 09:42
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
Johns R. C&D/MSWLF GW
92697334
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92698172001
1203-MW-36
EPA6010
Iron
22500
ug/L
40.0
11/21/2309:42
EPA 6010
Manganese
2250
ug/L
25.0
11/22/23 01:53
EPA 8260D
Benzene
3.4
ug/L
1.0
11/16/23 01:21
EPA 8260D
1,4-Dichlorobenzene
19.0
ug/L
1.0
11/16/23 01:21
EPA 8260D
1,1-Dichloroethane
1.3
ug/L
1.0
11/16/23 01:21
EPA 8260D
Tetrachloroethene
1.0
ug/L
1.0
11/16/23 01:21
EPA 8260D
Trichloroethene
1.6
ug/L
1.0
11/16/23 01:21
EPA 8260D
Vinyl chloride
0.60J
ug/L
1.0
11/16/23 01:21
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 13 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-10
Lab ID:
92697334001
Collected:
11/07/23 14:44
Received: 11/07/23 17:05 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
Chlorinated Herb. (GC) 8151
Analytical
Method: EPA8151
Preparation
Method: 8151A
Pace National
- Mt. Juliet
2,4-D
ND
ug/L
2.00
0.547
1
11/13/23 11:59
11/14/23 14:56
94-75-7
2,4,5-T
ND
ug/L
2.00
0.258
1
11/13/23 11:59
11/14/23 14:56
93-76-5
2,4,5-TP (Silvex)
ND
ug/L
2.00
0.335
1
11/13/23 11:59
11/14/23 14:56
93-72-1
Dinoseb
ND
ug/L
2.00
0.250
1
11/13/23 11:59
11/14/23 14:56
88-85-7
Surrogates
2,4-DCAA (S)
69.5
%
14.0-158
1
11/13/23 11:59
11/14/23 14:56
19719-28-9
8081 OC Pesticides RVE
Analytical
Method: EPA 8081
B Preparation Method: EPA 3510C
Pace Analytical
Services
- Charlotte
Aldrin
ND
ug/L
0.042
0.012
1
11/09/23 10:05
11/10/23 14:37
309-00-2
alpha-BHC
ND
ug/L
0.042
0.010
1
11/09/23 10:05
11/10/23 14:37
319-84-6
beta-BHC
ND
ug/L
0.042
0.041
1
11/09/23 10:05
11/10/23 14:37
319-85-7
delta-BHC
ND
ug/L
0.042
0.012
1
11/09/23 10:05
11/10/23 14:37
319-86-8 M1,R1
gamma-BHC (Lindane)
ND
ug/L
0.042
0.010
1
11/09/23 10:05
11/10/23 14:37
58-89-9
Chlordane (Technical)
ND
ug/L
0.42
0.13
1
11/09/23 10:05
11/10/23 14:37
57-74-9
4,4'-DDD
ND
ug/L
0.042
0.014
1
11/09/23 10:05
11/10/23 14:37
72-54-8
4,4'-DDE
ND
ug/L
0.042
0.020
1
11/09/23 10:05
11/10/23 14:37
72-55-9
4,4'-DDT
ND
ug/L
0.042
0.022
1
11/09/23 10:05
11/10/23 14:37
50-29-3
Dieldrin
ND
ug/L
0.042
0.012
1
11/09/23 10:05
11/10/23 14:37
60-57-1
Endosulfan I
ND
ug/L
0.042
0.014
1
11/09/23 10:05
11/10/23 14:37
959-98-8
Endosulfan 11
ND
ug/L
0.042
0.013
1
11/09/23 10:05
11/10/23 14:37
33213-65-9
Endosulfan sulfate
ND
ug/L
0.042
0.012
1
11/09/23 10:05
11/10/23 14:37
1031-07-8
Endrin
ND
ug/L
0.042
0.015
1
11/09/23 10:05
11/10/23 14:37
72-20-8
Endrin aldehyde
ND
ug/L
0.042
0.014
1
11/09/23 10:05
11/10/23 14:37
7421-93-4
Heptachlor
ND
ug/L
0.042
0.016
1
11/09/23 10:05
11/10/23 14:37
76-44-8
Heptachlor epoxide
ND
ug/L
0.042
0.024
1
11/09/23 10:05
11/10/23 14:37
1024-57-3
Methoxychlor
ND
ug/L
0.12
0.035
1
11/09/23 10:05
11/10/23 14:37
72-43-5
Toxaphene
ND
ug/L
0.42
0.18
1
11/09/23 10:05
11/10/23 14:37
8001-35-2
Surrogates
Tetrachloro-m-xylene (S)
116
%
10-137
1
11/09/23 10:05
11/10/23 14:37
877-09-8
Decachlorobiphenyl (S)
73
%
19-200
1
11/09/23 10:05
11/10/23 14:37
2051-24-3
8082 GCS PCB RVE
Analytical
Method: EPA 8082A
Preparation Method:
EPA 3510C
Pace Analytical
Services
- Charlotte
PCB-1016 (Aroclor 1016)
ND
ug/L
0.42
0.18
1
11/22/23 11:11
11/27/23 06:41
12674-11-2
PCB-1221 (Aroclor 1221)
ND
ug/L
0.42
0.19
1
11/22/23 11:11
11/27/23 06:41
11104-28-2
PCB-1232 (Aroclor 1232)
ND
ug/L
0.42
0.19
1
11/22/23 11:11
11/27/23 06:41
11141-16-5
PCB-1242 (Aroclor 1242)
ND
ug/L
0.42
0.21
1
11/22/23 11:11
11/27/23 06:41
53469-21-9
PCB-1248 (Aroclor 1248)
ND
ug/L
0.42
0.24
1
11/22/23 11:11
11/27/23 06:41
12672-29-6
PCB-1254 (Aroclor 1254)
ND
ug/L
0.42
0.18
1
11/22/23 11:11
11/27/23 06:41
11097-69-1
PCB-1260 (Aroclor 1260)
ND
ug/L
0.42
0.13
1
11/22/23 11:11
11/27/23 06:41
11096-82-5
Surrogates
Decachlorobiphenyl (S)
112
%
10-193
1
11/22/23 11:11
11/27/23 06:41
2051-24-3
Date: 11/28/2023 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 14 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-10 Lab ID: 92697334001 Collected: 11/07/23 14:44 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
3.8J
ug/L
5.0
3.6
1
11/10/2312:00
11/13/2316:44
7440-36-0
Arsenic
ND
ug/L
10.0
2.5
1
11/10/2312:00
11/13/2316:44
7440-38-2
Barium
97.3
ug/L
5.0
0.79
1
11/10/2312:00
11/13/2316:44
7440-39-3
Beryllium
ND
ug/L
1.0
0.16
1
11/10/2312:00
11/13/2316:44
7440-41-7
Cadmium
0.33J
ug/L
1.0
0.29
1
11/10/2312:00
11/13/2316:44
7440-43-9
Chromium
3.8.1
ug/L
5.0
0.63
1
11/10/2312:00
11/13/2316:44
7440-47-3
Cobalt
47.5
ug/L
5.0
0.44
1
11/10/2312:00
11/13/2316:44
7440-48-4
Copper
5.6
ug/L
5.0
0.62
1
11/10/2312:00
11/13/2316:44
7440-50-8
Iron
22800
ug/L
50.0
8.9
1
11/10/2312:00
11/13/2316:44
7439-89-6
Lead
5.5
ug/L
5.0
1.4
1
11/10/2312:00
11/13/2316:44
7439-92-1
Manganese
3190
ug/L
5.0
0.86
1
11/10/2312:00
11/13/2316:44
7439-96-5
Nickel
4.9.1
ug/L
5.0
0.88
1
11/10/2312:00
11/13/2316:44
7440-02-0
Selenium
ND
ug/L
10.0
4.1
1
11/10/2312:00
11/13/2316:44
7782-49-2
Silver
ND
ug/L
5.0
0.49
1
11/10/2312:00
11/13/2316:44
7440-22-4
Tin
ND
ug/L
5.0
2.0
1
11/10/2312:00
11/13/2316:44
7440-31-5
Vanadium
6.1
ug/L
5.0
1.6
1
11/10/2312:00
11/13/2316:44
7440-62-2
Zinc
25.8
ug/L
10.0
3.0
1
11/10/2312:00
11/13/2316:44
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
0.49
ug/L
0.20
0.050
1
11/10/2312:25
11/12/2319:01
7440-28-0
7470 Mercury
Analytical Method: EPA 7470A Preparation Method: EPA
7470A
Pace Analytical Services -Asheville
Mercury
1.8
ug/L
0.20
0.12
1
11/15/2316:59
11/18/2311:38
7439-97-6
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA
3510C
Pace Analytical Services - Charlotte
Acenaphthene
ND
ug/L
8.3
1.7
1
11/09/23 15:47
11/14/23 17:00
83-32-9
Acenaphthylene
ND
ug/L
8.3
1.6
1
11/09/23 15:47
11/14/23 17:00
208-96-8
Acetophenone
ND
ug/L
8.3
1.2
1
11/09/23 15:47
11/14/23 17:00
98-86-2
2-Acetylaminofluorene
ND
ug/L
8.3
3.4
1
11/09/23 15:47
11/14/23 17:00
53-96-3
4-Aminobiphenyl
ND
ug/L
8.3
4.0
1
11/09/23 15:47
11/14/23 17:00
92-67-1
Anthracene
ND
ug/L
8.3
1.9
1
11/09/23 15:47
11/14/23 17:00
120-12-7
Benzo(a)anthracene
ND
ug/L
8.3
2.2
1
11/09/23 15:47
11/14/23 17:00
56-55-3
Benzo(a)pyrene
ND
ug/L
8.3
2.3
1
11/09/23 15:47
11/14/23 17:00
50-32-8
Benzo(b)fluoranthene
ND
ug/L
8.3
2.2
1
11/09/23 15:47
11/14/23 17:00
205-99-2
Benzo(g,h,i)perylene
ND
ug/L
8.3
2.4
1
11/09/23 15:47
11/14/23 17:00
191-24-2
Benzo(k)fluoranthene
ND
ug/L
8.3
2.3
1
11/09/23 15:47
11/14/23 17:00
207-08-9
Benzyl alcohol
ND
ug/L
16.7
2.4
1
11/09/23 15:47
11/14/23 17:00
100-51-6
4-Bromophenylphenyl ether
ND
ug/L
8.3
1.5
1
11/09/23 15:47
11/14/23 17:00
101-55-3
Butylbenzylphthalate
ND
ug/L
8.3
2.6
1
11/09/23 15:47
11/14/23 17:00
85-68-7
4-ChIoro-3-methyl phenol
ND
ug/L
8.3
2.8
1
11/09/23 15:47
11/14/23 17:00
59-50-7
4-Chloroaniline
ND
ug/L
16.7
3.0
1
11/09/23 15:47
11/14/23 17:00
106-47-8
Chlorobenzilate
ND
ug/L
8.3
3.2
1
11/09/23 15:47
11/14/23 17:00
510-15-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 15 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-10 Lab ID: 92697334001 Collected: 11/07/23 14:44 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
bis(2-Chloroethoxy)methane
ND
ug/L
8.3
1.5
1
11/09/23 15:47
11/14/23 17:00
111-91-1
bis(2-Chloroethyl) ether
ND
ug/L
8.3
1.6
1
11/09/23 15:47
11/14/23 17:00
111-44-4
2-Chloronaphthalene
ND
ug/L
8.3
1.4
1
11/09/23 15:47
11/14/23 17:00
91-58-7
2-Chlorophenol
ND
ug/L
8.3
1.0
1
11/09/23 15:47
11/14/23 17:00
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
8.3
1.7
1
11/09/23 15:47
11/14/23 17:00
7005-72-3
Chrysene
ND
ug/L
8.3
2.3
1
11/09/23 15:47
11/14/23 17:00
218-01-9
Diallate
ND
ug/L
8.3
2.8
1
11/09/23 15:47
11/14/23 17:00
2303-16-4
Dibenz(a,h)anthracene
ND
ug/L
8.3
2.5
1
11/09/23 15:47
11/14/23 17:00
53-70-3
Dibenzofuran
ND
ug/L
8.3
1.8
1
11/09/23 15:47
11/14/23 17:00
132-64-9
3,3'-Dichlorobenzidine
ND
ug/L
16.7
6.8
1
11/09/23 15:47
11/14/23 17:00
91-94-1
2,4-Dichlorophenol
ND
ug/L
8.3
1.2
1
11/09/23 15:47
11/14/23 17:00
120-83-2
2,6-Dichlorophenol
ND
ug/L
8.3
3.5
1
11/09/23 15:47
11/14/23 17:00
87-65-0
Diethylphthalate
ND
ug/L
8.3
1.7
1
11/09/23 15:47
11/14/23 17:00
84-66-2
Dimethoate
ND
ug/L
8.3
3.0
1
11/09/23 15:47
11/14/23 17:00
60-51-5
P-Dimethylaminoazobenzene
ND
ug/L
4.2
2.0
1
11/09/23 15:47
11/14/23 17:00
60-11-7
7,12-Dimethylbenz(a)anthracene
ND
ug/L
8.3
2.5
1
11/09/23 15:47
11/14/23 17:00
57-97-6
3,3'-Dimethylbenzidine
ND
ug/L
41.7
25.9
1
11/09/23 15:47
11/14/23 17:00
119-93-7
2,4-Dimethylphenol
ND
ug/L
8.3
1.4
1
11/09/23 15:47
11/14/23 17:00
105-67-9
Dimethylphthalate
ND
ug/L
8.3
1.8
1
11/09/23 15:47
11/14/23 17:00
131-11-3
Di-n-butylphthalate
ND
ug/L
8.3
1.8
1
11/09/23 15:47
11/14/23 17:00
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
16.7
6.5
1
11/09/23 15:47
11/14/23 17:00
534-52-1
1,3-Dinitrobenzene
ND
ug/L
8.3
3.1
1
11/09/23 15:47
11/14/23 17:00
99-65-0
2,4-Dinitrophenol
ND
ug/L
41.7
21.7
1
11/09/23 15:47
11/14/23 17:00
51-28-5
2,4-Dinitrotoluene
ND
ug/L
8.3
1.4
1
11/09/23 15:47
11/14/23 17:00
121-14-2
2,6-Dinitrotoluene
ND
ug/L
8.3
1.4
1
11/09/23 15:47
11/14/23 17:00
606-20-2
Di-n-octylphthalate
ND
ug/L
8.3
3.3
1
11/09/23 15:47
11/14/23 17:00
117-84-0
Diphenylamine
ND
ug/L
8.3
2.5
1
11/09/23 15:47
11/14/23 17:00
122-39-4
Disulfoton
ND
ug/L
8.3
3.9
1
11/09/23 15:47
11/14/23 17:00
298-04-4
bis(2- Ethyl hexyl)phthalate
ND
ug/L
5.0
3.1
1
11/09/23 15:47
11/14/23 17:00
117-81-7
Ethyl methanesulfonate
ND
ug/L
16.7
2.5
1
11/09/23 15:47
11/14/23 17:00
62-50-0
Famphur
ND
ug/L
8.3
5.1
1
11/09/23 15:47
11/14/23 17:00
52-85-7
Fluoranthene
ND
ug/L
8.3
1.8
1
11/09/23 15:47
11/14/23 17:00
206-44-0
Fluorene
ND
ug/L
8.3
1.7
1
11/09/23 15:47
11/14/23 17:00
86-73-7
Hexachloro-1,3-butadiene
ND
ug/L
8.3
1.5
1
11/09/23 15:47
11/14/23 17:00
87-68-3
Hexachlorobenzene
ND
ug/L
8.3
1.8
1
11/09/23 15:47
11/14/23 17:00
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
8.3
1.3
1
11/09/23 15:47
11/14/23 17:00
77-47-4
Hexachloroethane
ND
ug/L
8.3
1.2
1
11/09/23 15:47
11/14/23 17:00
67-72-1
Hexachloropropene
ND
ug/L
8.3
2.2
1
11/09/23 15:47
11/14/23 17:00
1888-71-7
Indeno(1,2,3-cd)pyrene
ND
ug/L
8.3
2.4
1
11/09/23 15:47
11/14/23 17:00
193-39-5
Isodrin
ND
ug/L
8.3
2.3
1
11/09/23 15:47
11/14/23 17:00
465-73-6
Isophorone
ND
ug/L
8.3
1.4
1
11/09/23 15:47
11/14/23 17:00
78-59-1
Isosafrole
ND
ug/L
8.3
2.1
1
11/09/23 15:47
11/14/23 17:00
120-58-1
Kepone
ND
ug/L
16.7
11.8
1
11/09/23 15:47
11/14/23 17:00
143-50-0
Methapyrilene
ND
ug/L
41.7
14.2
1
11/09/23 15:47
11/14/23 17:00
91-80-5
3-Methylcholanthrene
ND
ug/L
8.3
3.1
1
11/09/23 15:47
11/14/23 17:00
56-49-5
REPORT OF LABORATORY ANALYSIS
L2,v2
v1
L2,v1
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-10 Lab ID: 92697334001 Collected: 11/07/23 14:44 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Methyl methanesulfonate
ND
ug/L
4.2
2.6
1
11/09/23 15:47
11/14/23 17:00
66-27-3
2-Methylnaphthalene
ND
ug/L
8.3
1.6
1
11/09/23 15:47
11/14/23 17:00
91-57-6
Methyl parathion
ND
ug/L
8.3
3.1
1
11/09/23 15:47
11/14/23 17:00
298-00-0
2-Methylphenol(o-Cresol)
ND
ug/L
8.3
1.6
1
11/09/23 15:47
11/14/23 17:00
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
8.3
1.0
1
11/09/23 15:47
11/14/23 17:00
15831-10-4
1-Naphthalenamine
ND
ug/L
8.3
5.0
1
11/09/23 15:47
11/14/23 17:00
134-32-7
2-Naphthalenamine
ND
ug/L
8.3
4.5
1
11/09/23 15:47
11/14/23 17:00
91-59-8
1,4-Naphthoquinone
ND
ug/L
4.2
3.7
1
11/09/23 15:47
11/14/23 17:00
130-15-4
2-Nitroaniline
ND
ug/L
16.7
2.5
1
11/09/23 15:47
11/14/23 17:00
88-74-4
3-Nitroaniline
ND
ug/L
16.7
3.1
1
11/09/23 15:47
11/14/23 17:00
99-09-2
4-Nitroaniline
ND
ug/L
16.7
4.2
1
11/09/23 15:47
11/14/23 17:00
100-01-6
Nitrobenzene
ND
ug/L
8.3
1.6
1
11/09/23 15:47
11/14/23 17:00
98-95-3
2-Nitrophenol
ND
ug/L
8.3
1.2
1
11/09/23 15:47
11/14/23 17:00
88-75-5
4-Nitrophenol
ND
ug/L
41.7
5.5
1
11/09/23 15:47
11/14/23 17:00
100-02-7
5-Nitro-o-toluidine
ND
ug/L
8.3
3.2
1
11/09/23 15:47
11/14/23 17:00
99-55-8
N-Nitrosodiethylamine
ND
ug/L
8.3
1.9
1
11/09/23 15:47
11/14/23 17:00
55-18-5
N-Nitrosodimethylamine
ND
ug/L
8.3
1.6
1
11/09/23 15:47
11/14/23 17:00
62-75-9
N-Nitroso-di-n-butylamine
ND
ug/L
8.3
1.6
1
11/09/23 15:47
11/14/23 17:00
924-16-3
N-Nitroso-di-n-propylamine
ND
ug/L
8.3
1.1
1
11/09/23 15:47
11/14/23 17:00
621-64-7
N-Nitrosodiphenylamine
ND
ug/L
8.3
2.5
1
11/09/23 15:47
11/14/23 17:00
86-30-6
N-Nitrosomethylethylamine
ND
ug/L
8.3
6.2
1
11/09/23 15:47
11/14/23 17:00
10595-95-6
N-Nitrosopiperidine
ND
ug/L
8.3
2.1
1
11/09/23 15:47
11/14/23 17:00
100-75-4
N-Nitrosopyrrolidine
ND
ug/L
8.3
2.6
1
11/09/23 15:47
11/14/23 17:00
930-55-2
O,O,O-Triethylphosphorothioate
ND
ug/L
8.3
2.1
1
11/09/23 15:47
11/14/23 17:00
126-68-1
2,2'-Oxybis(1-chloropropane)
ND
ug/L
8.3
0.96
1
11/09/23 15:47
11/14/23 17:00
108-60-1
Parathion (Ethyl parathion)
ND
ug/L
8.3
3.2
1
11/09/23 15:47
11/14/23 17:00
56-38-2
Pentachlorobenzene
ND
ug/L
8.3
2.8
1
11/09/23 15:47
11/14/23 17:00
608-93-5
Pentachloronitrobenzene
ND
ug/L
8.3
2.7
1
11/09/23 15:47
11/14/23 17:00
82-68-8
Pentachlorophenol
ND
ug/L
16.7
3.1
1
11/09/23 15:47
11/14/23 17:00
87-86-5
Phenacetin
ND
ug/L
8.3
3.0
1
11/09/23 15:47
11/14/23 17:00
62-44-2
Phenanthrene
ND
ug/L
8.3
1.7
1
11/09/23 15:47
11/14/23 17:00
85-01-8
Phenol
ND
ug/L
8.3
1.1
1
11/09/23 15:47
11/14/23 17:00
108-95-2
p-Phenylenediamine
ND
ug/L
8.3
8.3
1
11/09/23 15:47
11/14/23 17:00
106-50-3
Phorate
ND
ug/L
8.3
3.0
1
11/09/23 15:47
11/14/23 17:00
298-02-2
Pronamide
ND
ug/L
8.3
2.6
1
11/09/23 15:47
11/14/23 17:00
23950-58-5
Pyrene
ND
ug/L
8.3
1.8
1
11/09/23 15:47
11/14/23 17:00
129-00-0
Safrole
ND
ug/L
8.3
1.9
1
11/09/23 15:47
11/14/23 17:00
94-59-7
1,2,4,5-Tetrachlorobenzene
ND
ug/L
8.3
3.7
1
11/09/23 15:47
11/14/23 17:00
95-94-3
2,3,4,6-Tetrachlorophenol
ND
ug/L
8.3
1.3
1
11/09/23 15:47
11/14/23 17:00
58-90-2
Thionazin
ND
ug/L
8.3
2.4
1
11/09/23 15:47
11/14/23 17:00
297-97-2
O-Toluidine
ND
ug/L
8.3
2.2
1
11/09/23 15:47
11/14/23 17:00
95-53-4
2,4,5-Trichlorophenol
ND
ug/L
8.3
1.2
1
11/09/23 15:47
11/14/23 17:00
95-95-4
2,4,6-Trichlorophenol
ND
ug/L
8.3
1.3
1
11/09/23 15:47
11/14/23 17:00
88-06-2
1,3,5-Trinitrobenzene
ND
ug/L
8.3
4.6
1
11/09/23 15:47
11/14/23 17:00
99-35-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-10 Lab ID: 92697334001 Collected: 11/07/23 14:44 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260D MSV Low Level Landfill
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Allyl chloride
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Chloroprene
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Date: 11/28/2023 02:34 PM
84
%
10-133
1
11/09/2315:47
11/14/2317:00
4165-60-0
78
%
10-130
1
11 /09/23 15:47
11 /14/23 17:00
321-60-8
123
%
10-193
1
11 /09/23 15:47
11 /14/23 17:00
1718-51-0
45
%
10-130
1
11/09/2315:47
11/14/2317:00
13127-88-3
62
%
10-130
1
11/09/2315:47
11/14/2317:00
367-12-4
103
%
10-166
1
11/09/2315:47
11/14/2317:00
118-79-6
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
11/11/2311:37
67-64-1
ND
ug/L
50.0
24.8
1
11/11/2311:37
75-05-8
ND
ug/L
10.0
8.5
1
11/11/2311:37
107-02-8 AC
ND
ug/L
10.0
1.8
1
11/11/2311:37
107-13-1
ND
ug/L
2.0
0.50
1
11/11/2311:37
107-05-1
1.5
ug/L
1.0
0.34
1
11/11/23 11:37
71-43-2
ND
ug/L
1.0
0.47
1
11/11/2311:37
74-97-5
ND
ug/L
1.0
0.31
1
11/11/2311:37
75-27-4
ND
ug/L
1.0
0.34
1
11/11/2311:37
75-25-2
ND
ug/L
2.0
1.7
1
11/11/2311:37
74-83-9
ND
ug/L
5.0
4.0
1
11/11/2311:37
78-93-3
ND
ug/L
2.0
0.36
1
11/11/2311:37
75-15-0
ND
ug/L
1.0
0.33
1
11/11/2311:37
56-23-5
1.5
ug/L
1.0
0.28
1
11/11/2311:37
108-90-7
ND
ug/L
1.0
0.65
1
11/11/2311:37
75-00-3
ND
ug/L
1.0
0.43
1
11/11/2311:37
67-66-3
ND
ug/L
1.0
0.54
1
11/11/2311:37
74-87-3
ND
ug/L
5.0
1.6
1
11/11/2311:37
126-99-8
ND
ug/L
1.0
0.36
1
11/11/2311:37
124-48-1
ND
ug/L
1.0
0.34
1
11/11/2311:37
95-50-1
ND
ug/L
1.0
0.34
1
11/11/2311:37
541-73-1
1.2
ug/L
1.0
0.33
1
11/11/2311:37
106-46-7
ND
ug/L
1.0
0.56
1
11/11/2311:37
110-57-6
ND
ug/L
1.0
0.35
1
11/11/2311:37
75-71-8 v1
ND
ug/L
1.0
0.37
1
11/11/2311:37
75-34-3
ND
ug/L
1.0
0.32
1
11/11/2311:37
107-06-2
ND
ug/L
1.0
0.35
1
11/11/2311:37
75-35-4
2.3
ug/L
1.0
0.38
1
11/11/2311:37
156-59-2
ND
ug/L
1.0
0.40
1
11/11/2311:37
156-60-5
ND
ug/L
1.0
0.28
1
11/11/2311:37
142-28-9
ND
ug/L
1.0
0.39
1
11/11/2311:37
594-20-7
ND
ug/L
1.0
0.43
1
11/11/2311:37
563-58-6 v1
ND
ug/L
1.0
0.36
1
11/11/2311:37
10061-01-5
ND
ug/L
1.0
0.36
1
11 /11 /23 11:37
10061-02-6
ND
ug/L
1.0
0.30
1
11 /11 /23 11:37
100-41-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 18 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-10 Lab ID: 92697334001 Collected: 11/07/23 14:44 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Ethyl methacrylate
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Methylene Chloride
Methyl methacrylate
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
2540C Total Dissolved Solids
Total Dissolved Solids
Date: 11/28/2023 02:34 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
20.0
ND
ug/L
100
ND
ug/L
10.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
20.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
97
%
70-130
97
%
70-130
101
%
70-130
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
1.0J ug/L 2.0
92 % 67-130
91 % 70-130
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
48.5 mg/L 5.0
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
8.4 mg/L 2.5
0.28
1
11/11/23 11:37
97-63-2
1.5
1
11/11/23 11:37
87-68-3
0.48
1
11/11/23 11:37
591-78-6
9.7
1
11/11/23 11:37
74-88-4
52.3
1
11/11/23 11:37
78-83-1
4.2
1
11/11/23 11:37
126-98-7
2.0
1
11/11/23 11:37
75-09-2
0.32
1
11/11/23 11:37
80-62-6
0.64
1
11/11/23 11:37
91-20-3
3.6
1
11/11/23 11:37
107-12-0
0.29
1
11/11/23 11:37
100-42-5
0.31
1
11/11/23 11:37
630-20-6
0.22
1
11/11/23 11:37
79-34-5
0.29
1
11/11/23 11:37
127-18-4
0.24
1
11/11/23 11:37
108-88-3
0.64
1
11/11/23 11:37
120-82-1
0.33
1
11/11/23 11:37
71-55-6
0.32
1
11/11/23 11:37
79-00-5
0.38
1
11/11/23 11:37
79-01-6
0.30
1
11/11/23 11:37
75-69-4
0.26
1
11/11/23 11:37
96-18-4
1.3
1
11/11/23 11:37
108-05-4
0.39
1
11/11/23 11:37
75-01-4
0.34
1
11/11/23 11:37
1330-20-7
I
111E:I:>il
I
5.0 1
2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
11 /11 /23 11:37 460-00-4
11/11/23 11:37 17060-07-0
11/11/23 11:37 2037-26-5
11/10/23 03:57 17060-07-0
11/10/23 03:57 2037-26-5
11 /15/23 19:57
11 /09/23 10:48
Page 19 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-10
Lab ID: 92697334001 Collected: 11/07/23 14:44
Received: 11/07/23 17:05 Matrix: Water
Report
Parameters
Results Units Limit MDL
DF
Prepared Analyzed
CAS No. Qual
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
Sulfide
23AJ ug/L 100 22.0
1
11/09/23 05:41
18496-25-8
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
Chloride
12.0 mg/L 1.0 0.60
1
11/09/23 23:18
16887-00-6
Sulfate
1.3 mg/L 1.0 0.50
1
11/09/23 23:18
14808-79-8
4500CNE Cyanide, Total
Analytical Method: SM 4500-CN-E-2016 Preparation Method:
SM 4500-CN-E-2016
Pace Analytical Services -Asheville
Cyanide
ND ug/L 8.0 6.0
1
11/14/23 17:30 11/14/23 20:40
57-12-5
Date: 11/28/2023 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 20 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-11
Lab ID:
92697334002
Collected:
11/06/23 13:52
Received: 11/07/23 17:05 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
Chlorinated Herb. (GC) 8151
Analytical
Method: EPA8151
Preparation
Method: 8151A
Pace National
- Mt. Juliet
2,4-D
ND
ug/L
2.00
0.547
1
11/13/23 11:59
11/14/23 10:14
94-75-7
2,4,5-T
ND
ug/L
2.00
0.258
1
11/13/23 11:59
11/14/23 10:14
93-76-5
2,4,5-TP (Silvex)
ND
ug/L
2.00
0.335
1
11/13/23 11:59
11/14/23 10:14
93-72-1
Dinoseb
ND
ug/L
2.00
0.250
1
11/13/23 11:59
11/14/23 10:14
88-85-7
Surrogates
2,4-DCAA (S)
128
%
14.0-158
1
11/13/23 11:59
11/14/23 10:14
19719-28-9
8081 OC Pesticides RVE
Analytical
Method: EPA 8081
B Preparation Method: EPA 3510C
Pace Analytical
Services
- Charlotte
Aldrin
ND
ug/L
0.042
0.012
1
11/09/23 10:05
11/10/23 14:12
309-00-2
alpha-BHC
ND
ug/L
0.042
0.010
1
11/09/23 10:05
11/10/23 14:12
319-84-6
beta-BHC
ND
ug/L
0.042
0.041
1
11/09/23 10:05
11/10/23 14:12
319-85-7
delta-BHC
ND
ug/L
0.042
0.012
1
11/09/23 10:05
11/10/23 14:12
319-86-8
gamma-BHC (Lindane)
ND
ug/L
0.042
0.010
1
11/09/23 10:05
11/10/23 14:12
58-89-9
Chlordane (Technical)
ND
ug/L
0.42
0.13
1
11/09/23 10:05
11/10/23 14:12
57-74-9
4,4'-DDD
ND
ug/L
0.042
0.014
1
11/09/23 10:05
11/10/23 14:12
72-54-8
4,4'-DDE
ND
ug/L
0.042
0.020
1
11/09/23 10:05
11/10/23 14:12
72-55-9
4,4'-DDT
ND
ug/L
0.042
0.022
1
11/09/23 10:05
11/10/23 14:12
50-29-3
Dieldrin
ND
ug/L
0.042
0.012
1
11/09/23 10:05
11/10/23 14:12
60-57-1
Endosulfan I
ND
ug/L
0.042
0.014
1
11/09/23 10:05
11/10/23 14:12
959-98-8
Endosulfan 11
ND
ug/L
0.042
0.013
1
11/09/23 10:05
11/10/23 14:12
33213-65-9
Endosulfan sulfate
ND
ug/L
0.042
0.012
1
11/09/23 10:05
11/10/23 14:12
1031-07-8
Endrin
ND
ug/L
0.042
0.015
1
11/09/23 10:05
11/10/23 14:12
72-20-8
Endrin aldehyde
ND
ug/L
0.042
0.014
1
11/09/23 10:05
11/10/23 14:12
7421-93-4
Heptachlor
ND
ug/L
0.042
0.016
1
11/09/23 10:05
11/10/23 14:12
76-44-8
Heptachlor epoxide
ND
ug/L
0.042
0.024
1
11/09/23 10:05
11/10/23 14:12
1024-57-3
Methoxychlor
ND
ug/L
0.12
0.035
1
11/09/23 10:05
11/10/23 14:12
72-43-5
Toxaphene
ND
ug/L
0.42
0.18
1
11/09/23 10:05
11/10/23 14:12
8001-35-2
Surrogates
Tetrachloro-m-xylene (S)
222
%
10-137
1
11/09/23 10:05
11/10/23 14:12
877-09-8 S3
Decachlorobiphenyl (S)
46
%
19-200
1
11/09/23 10:05
11/10/23 14:12
2051-24-3
8082 GCS PCB RVE
Analytical
Method: EPA 8082A
Preparation Method:
EPA 3510C
Pace Analytical
Services
- Charlotte
PCB-1016 (Aroclor 1016)
ND
ug/L
0.42
0.18
1
11/22/23 11:11
11/27/23 06:54
12674-11-2
PCB-1221 (Aroclor 1221)
ND
ug/L
0.42
0.19
1
11/22/23 11:11
11/27/23 06:54
11104-28-2
PCB-1232 (Aroclor 1232)
ND
ug/L
0.42
0.19
1
11/22/23 11:11
11/27/23 06:54
11141-16-5
PCB-1242 (Aroclor 1242)
ND
ug/L
0.42
0.21
1
11/22/23 11:11
11/27/23 06:54
53469-21-9
PCB-1248 (Aroclor 1248)
ND
ug/L
0.42
0.24
1
11/22/23 11:11
11/27/23 06:54
12672-29-6
PCB-1254 (Aroclor 1254)
ND
ug/L
0.42
0.18
1
11/22/23 11:11
11/27/23 06:54
11097-69-1
PCB-1260 (Aroclor 1260)
ND
ug/L
0.42
0.13
1
11/22/23 11:11
11/27/23 06:54
11096-82-5
Surrogates
Decachlorobiphenyl (S)
103
%
10-193
1
11/22/23 11:11
11/27/23 06:54
2051-24-3
Date: 11/28/2023 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 21 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-11 Lab ID: 92697334002 Collected: 11/06/23 13:52 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.6
1
11/10/2312:00
11/13/2316:47
7440-36-0
Arsenic
ND
ug/L
10.0
2.5
1
11/10/2312:00
11/13/2316:47
7440-38-2
Barium
168
ug/L
5.0
0.79
1
11/10/2312:00
11/13/2316:47
7440-39-3
Beryllium
ND
ug/L
1.0
0.16
1
11/10/2312:00
11/13/2316:47
7440-41-7
Cadmium
1.0
ug/L
1.0
0.29
1
11/10/2312:00
11/13/2316:47
7440-43-9
Chromium
6.1
ug/L
5.0
0.63
1
11/10/2312:00
11/13/2316:47
7440-47-3
Cobalt
19.8
ug/L
5.0
0.44
1
11/10/2312:00
11/13/2316:47
7440-48-4
Copper
ND
ug/L
5.0
0.62
1
11/10/2312:00
11/13/2316:47
7440-50-8
Iron
136000
ug/L
1000
179
20
11/10/2312:00
11/14/2315:13
7439-89-6
Lead
ND
ug/L
5.0
1.4
1
11/10/2312:00
11/13/2316:47
7439-92-1
Manganese
25700
ug/L
100
17.2
20
11/10/2312:00
11/14/2315:13
7439-96-5
Nickel
9.8
ug/L
5.0
0.88
1
11/10/2312:00
11/13/2316:47
7440-02-0
Selenium
ND
ug/L
200
82.5
20
11/10/2312:00
11/14/2315:13
7782-49-2
Silver
0.56J
ug/L
5.0
0.49
1
11/10/2312:00
11/13/2316:47
7440-22-4
Tin
ND
ug/L
5.0
2.0
1
11/10/2312:00
11/13/2316:47
7440-31-5
Vanadium
ND
ug/L
5.0
1.6
1
11/10/2312:00
11/13/2316:47
7440-62-2
Zinc
13.0
ug/L
10.0
3.0
1
11/10/2312:00
11/13/2316:47
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Pace Analytical Services
-Asheville
Thallium
0.52
ug/L
0.20
0.050
1
11/10/2312:25
11/12/2319:26
7440-28-0
7470 Mercury
Analytical Method: EPA 7470A Preparation Method:
EPA 7470A
Pace Analytical Services -Asheville
Mercury
ND
ug/L
0.20
0.12
1
11/15/2316:59
11/18/2311:40
7439-97-6
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Acenaphthene
ND
ug/L
8.3
1.7
1
11/09/23 10:09
11/12/23 17:52
83-32-9
Acenaphthylene
ND
ug/L
8.3
1.6
1
11/09/23 10:09
11/12/23 17:52
208-96-8
Acetophenone
ND
ug/L
8.3
1.2
1
11/09/23 10:09
11/12/23 17:52
98-86-2
2-Acetylaminofluorene
ND
ug/L
8.3
3.4
1
11/09/23 10:09
11/12/23 17:52
53-96-3
4-Aminobiphenyl
ND
ug/L
8.3
4.0
1
11/09/23 10:09
11/12/23 17:52
92-67-1
Anthracene
ND
ug/L
8.3
1.9
1
11/09/23 10:09
11/12/23 17:52
120-12-7
Benzo(a)anthracene
ND
ug/L
8.3
2.2
1
11/09/23 10:09
11/12/23 17:52
56-55-3
Benzo(a)pyrene
ND
ug/L
8.3
2.3
1
11/09/23 10:09
11/12/23 17:52
50-32-8
Benzo(b)fluoranthene
ND
ug/L
8.3
2.2
1
11/09/23 10:09
11/12/23 17:52
205-99-2
Benzo(g,h,i)perylene
ND
ug/L
8.3
2.4
1
11/09/23 10:09
11/12/23 17:52
191-24-2
Benzo(k)fluoranthene
ND
ug/L
8.3
2.3
1
11/09/23 10:09
11/12/23 17:52
207-08-9
Benzyl alcohol
ND
ug/L
16.7
2.4
1
11/09/23 10:09
11/12/23 17:52
100-51-6
4-Bromophenylphenyl ether
ND
ug/L
8.3
1.5
1
11/09/23 10:09
11/12/23 17:52
101-55-3
Butylbenzylphthalate
ND
ug/L
8.3
2.6
1
11/09/23 10:09
11/12/23 17:52
85-68-7
4-ChIoro-3-methyl phenol
ND
ug/L
8.3
2.8
1
11/09/23 10:09
11/12/23 17:52
59-50-7
4-Chloroaniline
ND
ug/L
16.7
3.0
1
11/09/23 10:09
11/12/23 17:52
106-47-8
Chlorobenzilate
ND
ug/L
8.3
3.2
1
11/09/23 10:09
11/12/23 17:52
510-15-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
D3
Page 22 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-11 Lab ID: 92697334002 Collected: 11/06/23 13:52 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
bis(2-Chloroethoxy)methane
ND
ug/L
8.3
1.5
1
11/09/23 10:09
11/12/23 17:52
111-91-1
bis(2-Chloroethyl) ether
ND
ug/L
8.3
1.6
1
11/09/23 10:09
11/12/23 17:52
111-44-4
2-Chloronaphthalene
ND
ug/L
8.3
1.4
1
11/09/23 10:09
11/12/23 17:52
91-58-7
2-Chlorophenol
ND
ug/L
8.3
1.0
1
11/09/23 10:09
11/12/23 17:52
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
8.3
1.7
1
11/09/23 10:09
11/12/23 17:52
7005-72-3
Chrysene
ND
ug/L
8.3
2.3
1
11/09/23 10:09
11/12/23 17:52
218-01-9
Diallate
ND
ug/L
8.3
2.8
1
11/09/23 10:09
11/12/23 17:52
2303-16-4
Dibenz(a,h)anthracene
ND
ug/L
8.3
2.5
1
11/09/23 10:09
11/12/23 17:52
53-70-3
Dibenzofuran
ND
ug/L
8.3
1.8
1
11/09/23 10:09
11/12/23 17:52
132-64-9
3,3'-Dichlorobenzidine
ND
ug/L
16.7
6.8
1
11/09/23 10:09
11/12/23 17:52
91-94-1
2,4-Dichlorophenol
ND
ug/L
8.3
1.2
1
11/09/23 10:09
11/12/23 17:52
120-83-2
2,6-Dichlorophenol
ND
ug/L
8.3
3.5
1
11/09/23 10:09
11/12/23 17:52
87-65-0
Diethylphthalate
ND
ug/L
8.3
1.7
1
11/09/23 10:09
11/12/23 17:52
84-66-2
Dimethoate
ND
ug/L
8.3
3.0
1
11/09/23 10:09
11/12/23 17:52
60-51-5
P-Dimethylaminoazobenzene
ND
ug/L
4.2
2.0
1
11/09/23 10:09
11/12/23 17:52
60-11-7
7,12-Dimethylbenz(a)anthracene
ND
ug/L
8.3
2.5
1
11/09/23 10:09
11/12/23 17:52
57-97-6
3,3'-Dimethylbenzidine
ND
ug/L
41.7
25.9
1
11/09/23 10:09
11/12/23 17:52
119-93-7
2,4-Dimethylphenol
ND
ug/L
8.3
1.4
1
11/09/23 10:09
11/12/23 17:52
105-67-9
Dimethylphthalate
ND
ug/L
8.3
1.8
1
11/09/23 10:09
11/12/23 17:52
131-11-3
Di-n-butylphthalate
ND
ug/L
8.3
1.8
1
11/09/23 10:09
11/12/23 17:52
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
16.7
6.5
1
11/09/23 10:09
11/12/23 17:52
534-52-1
1,3-Dinitrobenzene
ND
ug/L
8.3
3.1
1
11/09/23 10:09
11/12/23 17:52
99-65-0
2,4-Dinitrophenol
ND
ug/L
41.7
21.7
1
11/09/23 10:09
11/12/23 17:52
51-28-5
2,4-Dinitrotoluene
ND
ug/L
8.3
1.4
1
11/09/23 10:09
11/12/23 17:52
121-14-2
2,6-Dinitrotoluene
ND
ug/L
8.3
1.4
1
11/09/23 10:09
11/12/23 17:52
606-20-2
Di-n-octylphthalate
ND
ug/L
8.3
3.3
1
11/09/23 10:09
11/12/23 17:52
117-84-0
Diphenylamine
ND
ug/L
8.3
2.5
1
11/09/23 10:09
11/12/23 17:52
122-39-4
Disulfoton
ND
ug/L
8.3
3.9
1
11/09/23 10:09
11/12/23 17:52
298-04-4
bis(2- Ethyl hexyl)phthalate
ND
ug/L
5.0
3.1
1
11/09/23 10:09
11/12/23 17:52
117-81-7
Ethyl methanesulfonate
ND
ug/L
16.7
2.5
1
11/09/23 10:09
11/12/23 17:52
62-50-0
Famphur
ND
ug/L
8.3
5.1
1
11/09/23 10:09
11/12/23 17:52
52-85-7
Fluoranthene
ND
ug/L
8.3
1.8
1
11/09/23 10:09
11/12/23 17:52
206-44-0
Fluorene
ND
ug/L
8.3
1.7
1
11/09/23 10:09
11/12/23 17:52
86-73-7
Hexachloro-1,3-butadiene
ND
ug/L
8.3
1.5
1
11/09/23 10:09
11/12/23 17:52
87-68-3
Hexachlorobenzene
ND
ug/L
8.3
1.8
1
11/09/23 10:09
11/12/23 17:52
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
8.3
1.3
1
11/09/23 10:09
11/12/23 17:52
77-47-4
Hexachloroethane
ND
ug/L
8.3
1.2
1
11/09/23 10:09
11/12/23 17:52
67-72-1
Hexachloropropene
ND
ug/L
8.3
2.2
1
11/09/23 10:09
11/12/23 17:52
1888-71-7
Indeno(1,2,3-cd)pyrene
ND
ug/L
8.3
2.4
1
11/09/23 10:09
11/12/23 17:52
193-39-5
Isodrin
ND
ug/L
8.3
2.3
1
11/09/23 10:09
11/12/23 17:52
465-73-6
Isophorone
ND
ug/L
8.3
1.4
1
11/09/23 10:09
11/12/23 17:52
78-59-1
Isosafrole
ND
ug/L
8.3
2.1
1
11/09/23 10:09
11/12/23 17:52
120-58-1
Kepone
ND
ug/L
16.7
11.8
1
11/09/23 10:09
11/12/23 17:52
143-50-0
Methapyrilene
ND
ug/L
41.7
14.2
1
11/09/23 10:09
11/12/23 17:52
91-80-5
3-Methylcholanthrene
ND
ug/L
8.3
3.1
1
11/09/23 10:09
11/12/23 17:52
56-49-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-11 Lab ID: 92697334002 Collected: 11/06/23 13:52 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Methyl methanesulfonate
ND
ug/L
4.2
2.6
1
11/09/23 10:09
11/12/23 17:52
66-27-3
2-Methylnaphthalene
ND
ug/L
8.3
1.6
1
11/09/23 10:09
11/12/23 17:52
91-57-6
Methyl parathion
ND
ug/L
8.3
3.1
1
11/09/23 10:09
11/12/23 17:52
298-00-0
2-Methylphenol(o-Cresol)
ND
ug/L
8.3
1.6
1
11/09/23 10:09
11/12/23 17:52
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
8.3
1.0
1
11/09/23 10:09
11/12/23 17:52
15831-10-4
1-Naphthalenamine
ND
ug/L
8.3
5.0
1
11/09/23 10:09
11/12/23 17:52
134-32-7
2-Naphthalenamine
ND
ug/L
8.3
4.5
1
11/09/23 10:09
11/12/23 17:52
91-59-8
1,4-Naphthoquinone
ND
ug/L
4.2
3.7
1
11/09/23 10:09
11/12/23 17:52
130-15-4
2-Nitroaniline
ND
ug/L
16.7
2.5
1
11/09/23 10:09
11/12/23 17:52
88-74-4
3-Nitroaniline
ND
ug/L
16.7
3.1
1
11/09/23 10:09
11/12/23 17:52
99-09-2
4-Nitroaniline
ND
ug/L
16.7
4.2
1
11/09/23 10:09
11/12/23 17:52
100-01-6
Nitrobenzene
ND
ug/L
8.3
1.6
1
11/09/23 10:09
11/12/23 17:52
98-95-3
2-Nitrophenol
ND
ug/L
8.3
1.2
1
11/09/23 10:09
11/12/23 17:52
88-75-5
4-Nitrophenol
ND
ug/L
41.7
5.5
1
11/09/23 10:09
11/12/23 17:52
100-02-7
5-Nitro-o-toluidine
ND
ug/L
8.3
3.2
1
11/09/23 10:09
11/12/23 17:52
99-55-8
N-Nitrosodiethylamine
ND
ug/L
8.3
1.9
1
11/09/23 10:09
11/12/23 17:52
55-18-5
N-Nitrosodimethylamine
ND
ug/L
8.3
1.6
1
11/09/23 10:09
11/12/23 17:52
62-75-9
N-Nitroso-di-n-butylamine
ND
ug/L
8.3
1.6
1
11/09/23 10:09
11/12/23 17:52
924-16-3
N-Nitroso-di-n-propylamine
ND
ug/L
8.3
1.1
1
11/09/23 10:09
11/12/23 17:52
621-64-7
N-Nitrosodiphenylamine
ND
ug/L
8.3
2.5
1
11/09/23 10:09
11/12/23 17:52
86-30-6
N-Nitrosomethylethylamine
ND
ug/L
8.3
6.2
1
11/09/23 10:09
11/12/23 17:52
10595-95-6
N-Nitrosopiperidine
ND
ug/L
8.3
2.1
1
11/09/23 10:09
11/12/23 17:52
100-75-4
N-Nitrosopyrrolidine
ND
ug/L
8.3
2.6
1
11/09/23 10:09
11/12/23 17:52
930-55-2
O,O,O-Triethylphosphorothioate
ND
ug/L
8.3
2.1
1
11/09/23 10:09
11/12/23 17:52
126-68-1
2,2'-Oxybis(1-chloropropane)
ND
ug/L
8.3
0.96
1
11/09/23 10:09
11/12/23 17:52
108-60-1
Parathion (Ethyl parathion)
ND
ug/L
8.3
3.2
1
11/09/23 10:09
11/12/23 17:52
56-38-2
Pentachlorobenzene
ND
ug/L
8.3
2.8
1
11/09/23 10:09
11/12/23 17:52
608-93-5
Pentachloronitrobenzene
ND
ug/L
8.3
2.7
1
11/09/23 10:09
11/12/23 17:52
82-68-8
Pentachlorophenol
ND
ug/L
16.7
3.1
1
11/09/23 10:09
11/12/23 17:52
87-86-5
Phenacetin
ND
ug/L
8.3
3.0
1
11/09/23 10:09
11/12/23 17:52
62-44-2
Phenanthrene
ND
ug/L
8.3
1.7
1
11/09/23 10:09
11/12/23 17:52
85-01-8
Phenol
ND
ug/L
8.3
1.1
1
11/09/23 10:09
11/12/23 17:52
108-95-2
p-Phenylenediamine
ND
ug/L
8.3
8.3
1
11/09/23 10:09
11/12/23 17:52
106-50-3
Phorate
ND
ug/L
8.3
3.0
1
11/09/23 10:09
11/12/23 17:52
298-02-2
Pronamide
ND
ug/L
8.3
2.6
1
11/09/23 10:09
11/12/23 17:52
23950-58-5
Pyrene
ND
ug/L
8.3
1.8
1
11/09/23 10:09
11/12/23 17:52
129-00-0
Safrole
ND
ug/L
8.3
1.9
1
11/09/23 10:09
11/12/23 17:52
94-59-7
1,2,4,5-Tetrachlorobenzene
ND
ug/L
8.3
3.7
1
11/09/23 10:09
11/12/23 17:52
95-94-3
2,3,4,6-Tetrachlorophenol
ND
ug/L
8.3
1.3
1
11/09/23 10:09
11/12/23 17:52
58-90-2
Thionazin
ND
ug/L
8.3
2.4
1
11/09/23 10:09
11/12/23 17:52
297-97-2
O-Toluidine
ND
ug/L
8.3
2.2
1
11/09/23 10:09
11/12/23 17:52
95-53-4
2,4,5-Trichlorophenol
ND
ug/L
8.3
1.2
1
11/09/23 10:09
11/12/23 17:52
95-95-4
2,4,6-Trichlorophenol
ND
ug/L
8.3
1.3
1
11/09/23 10:09
11/12/23 17:52
88-06-2
1,3,5-Trinitrobenzene
ND
ug/L
8.3
4.6
1
11/09/23 10:09
11/12/23 17:52
99-35-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-11 Lab ID: 92697334002 Collected: 11/06/23 13:52 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260D MSV Low Level Landfill
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Allyl chloride
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Chloroprene
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Date: 11/28/2023 02:34 PM
88
%
10-133
1
11 /09/23 10:09
11 /12/23 17:52
4165-60-0
1 g
77
%
10-130
1
11 /09/23 10:09
11 /12/23 17:52
321-60-8
108
%
10-193
1
11 /09/23 10:09
11 /12/23 17:52
1718-51-0
5
%
10-130
1
11/09/2310:09
11/12/2317:52
13127-88-3
SO
1
%
10-130
1
11/09/2310:09
11/12/2317:52
367-12-4
SO
5
%
10-166
1
11/09/2310:09
11/12/2317:52
118-79-6
SO
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
11/11/23 11:55
67-64-1
ND
ug/L
50.0
24.8
1
11/11/23 11:55
75-05-8
ND
ug/L
10.0
8.5
1
11/11/23 11:55
107-02-8
AC
ND
ug/L
10.0
1.8
1
11/11/23 11:55
107-13-1
ND
ug/L
2.0
0.50
1
11/11/23 11:55
107-05-1
2.7
ug/L
1.0
0.34
1
11/11/23 11:55
71-43-2
ND
ug/L
1.0
0.47
1
11/11/23 11:55
74-97-5
ND
ug/L
1.0
0.31
1
11/11/23 11:55
75-27-4
ND
ug/L
1.0
0.34
1
11/11/23 11:55
75-25-2
ND
ug/L
2.0
1.7
1
11/11/23 11:55
74-83-9
ND
ug/L
5.0
4.0
1
11/11/23 11:55
78-93-3
ND
ug/L
2.0
0.36
1
11/11/23 11:55
75-15-0
ND
ug/L
1.0
0.33
1
11/11/23 11:55
56-23-5
0.97J
ug/L
1.0
0.28
1
11/11/23 11:55
108-90-7
1.0
ug/L
1.0
0.65
1
11/11/23 11:55
75-00-3
ND
ug/L
1.0
0.43
1
11/11/23 11:55
67-66-3
ND
ug/L
1.0
0.54
1
11/11/23 11:55
74-87-3
ND
ug/L
5.0
1.6
1
11/11/23 11:55
126-99-8
ND
ug/L
1.0
0.36
1
11/11/23 11:55
124-48-1
0.34J
ug/L
1.0
0.34
1
11/11/23 11:55
95-50-1
ND
ug/L
1.0
0.34
1
11/11/23 11:55
541-73-1
11.9
ug/L
1.0
0.33
1
11/11/23 11:55
106-46-7
ND
ug/L
1.0
0.56
1
11/11/23 11:55
110-57-6
ND
ug/L
1.0
0.35
1
11/11/23 11:55
75-71-8
v1
2.0
ug/L
1.0
0.37
1
11/11/23 11:55
75-34-3
ND
ug/L
1.0
0.32
1
11/11/23 11:55
107-06-2
ND
ug/L
1.0
0.35
1
11/11/23 11:55
75-35-4
3.1
ug/L
1.0
0.38
1
11/11/23 11:55
156-59-2
ND
ug/L
1.0
0.40
1
11/11/23 11:55
156-60-5
ND
ug/L
1.0
0.28
1
11/11/23 11:55
142-28-9
ND
ug/L
1.0
0.39
1
11/11/23 11:55
594-20-7
ND
ug/L
1.0
0.43
1
11/11/23 11:55
563-58-6
v1
ND
ug/L
1.0
0.36
1
11/11/23 11:55
10061-01-5
ND
ug/L
1.0
0.36
1
11/11/23 11:55
10061-02-6
ND
ug/L
1.0
0.30
1
11/11/23 11:55
100-41-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 25 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-11 Lab ID: 92697334002 Collected: 11/06/23 13:52 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Ethyl methacrylate
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Methylene Chloride
Methyl methacrylate
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
2540C Total Dissolved Solids
Total Dissolved Solids
Date: 11/28/2023 02:34 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
20.0
ND
ug/L
100
ND
ug/L
10.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
20.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
0.29J
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
1.4
ug/L
1.0
ND
ug/L
1.0
97
%
70-130
101
%
70-130
101
%
70-130
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
35.5 ug/L 2.0
89 % 67-130
90 % 70-130
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
213 mg/L 5.0
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
47.0 mg/L 2.5
0.28
1
11/11/23 11:55
97-63-2
1.5
1
11/11/23 11:55
87-68-3
0.48
1
11/11/23 11:55
591-78-6
9.7
1
11/11/23 11:55
74-88-4
52.3
1
11/11/23 11:55
78-83-1
4.2
1
11/11/23 11:55
126-98-7
2.0
1
11/11/23 11:55
75-09-2
0.32
1
11/11/23 11:55
80-62-6
0.64
1
11/11/23 11:55
91-20-3
3.6
1
11/11/23 11:55
107-12-0
0.29
1
11/11/23 11:55
100-42-5
0.31
1
11/11/23 11:55
630-20-6
0.22
1
11/11/23 11:55
79-34-5
0.29
1
11/11/23 11:55
127-18-4
0.24
1
11/11/23 11:55
108-88-3
0.64
1
11/11/23 11:55
120-82-1
0.33
1
11/11/23 11:55
71-55-6
0.32
1
11/11/23 11:55
79-00-5
0.38
1
11/11/23 11:55
79-01-6
0.30
1
11/11/23 11:55
75-69-4
0.26
1
11/11/23 11:55
96-18-4
1.3
1
11/11/23 11:55
108-05-4
0.39
1
11/11/23 11:55
75-01-4
0.34
1
11/11/23 11:55
1330-20-7
I
111E:I:>il
I
5.0 1
2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
11 /11 /23 11:55 460-00-4
11/11/23 11:55 17060-07-0
11/11/23 11:55 2037-26-5
ffIf100�ci1L!fiE:Wif a 5;SQi
11/10/23 04:18 17060-07-0
11/10/23 04:18 2037-26-5
11/16/23 10:18
11 /09/23 10:48
Page 26 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-11
Lab ID: 92697334002 Collected: 11/06/23 13:52
Received: 11/07/23 17:05 Matrix: Water
Report
Parameters
Results Units Limit MDL
DF
Prepared Analyzed
CAS No. Qual
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
Sulfide
ND ug/L 100 22.0
1
11/09/23 05:37
18496-25-8
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
Chloride
93.8 mg/L 1.0 0.60
1
11/09/23 23:33
16887-00-6
Sulfate
6.9 mg/L 1.0 0.50
1
11/09/23 23:33
14808-79-8
4500CNE Cyanide, Total
Analytical Method: SM 4500-CN-E-2016 Preparation Method:
SM 4500-CN-E-2016
Pace Analytical Services -Asheville
Cyanide
ND ug/L 8.0 6.0
1
11/14/23 17:30 11/14/23 20:30
57-12-5
Date: 11/28/2023 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 27 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-12
Lab ID:
92697334003
Collected:
11/06/23 15:49
Received: 11/07/23 17:05 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
Chlorinated Herb. (GC) 8151
Analytical
Method: EPA8151
Preparation
Method: 8151A
Pace National
- Mt. Juliet
2,4-D
ND
ug/L
2.00
0.547
1
11/13/23 11:59
11/14/23 12:20
94-75-7
2,4,5-T
ND
ug/L
2.00
0.258
1
11/13/23 11:59
11/14/23 12:20
93-76-5
2,4,5-TP (Silvex)
ND
ug/L
2.00
0.335
1
11/13/23 11:59
11/14/23 12:20
93-72-1
Dinoseb
ND
ug/L
2.00
0.250
1
11/13/23 11:59
11/14/23 12:20
88-85-7
Surrogates
2,4-DCAA (S)
123
%
14.0-158
1
11/13/23 11:59
11/14/23 12:20
19719-28-9
8081 OC Pesticides RVE
Analytical
Method: EPA 8081
B Preparation Method: EPA 3510C
Pace Analytical
Services
- Charlotte
Aldrin
ND
ug/L
0.042
0.012
1
11/09/23 10:05
11/10/23 14:25
309-00-2
alpha-BHC
ND
ug/L
0.042
0.010
1
11/09/23 10:05
11/10/23 14:25
319-84-6
beta-BHC
ND
ug/L
0.042
0.041
1
11/09/23 10:05
11/10/23 14:25
319-85-7
delta-BHC
ND
ug/L
0.042
0.012
1
11/09/23 10:05
11/10/23 14:25
319-86-8
gamma-BHC (Lindane)
ND
ug/L
0.042
0.010
1
11/09/23 10:05
11/10/23 14:25
58-89-9
Chlordane (Technical)
ND
ug/L
0.42
0.13
1
11/09/23 10:05
11/10/23 14:25
57-74-9
4,4'-DDD
ND
ug/L
0.042
0.014
1
11/09/23 10:05
11/10/23 14:25
72-54-8
4,4'-DDE
ND
ug/L
0.042
0.020
1
11/09/23 10:05
11/10/23 14:25
72-55-9
4,4'-DDT
ND
ug/L
0.042
0.022
1
11/09/23 10:05
11/10/23 14:25
50-29-3
Dieldrin
ND
ug/L
0.042
0.012
1
11/09/23 10:05
11/10/23 14:25
60-57-1
Endosulfan I
ND
ug/L
0.042
0.014
1
11/09/23 10:05
11/10/23 14:25
959-98-8
Endosulfan 11
ND
ug/L
0.042
0.013
1
11/09/23 10:05
11/10/23 14:25
33213-65-9
Endosulfan sulfate
ND
ug/L
0.042
0.012
1
11/09/23 10:05
11/10/23 14:25
1031-07-8
Endrin
ND
ug/L
0.042
0.015
1
11/09/23 10:05
11/10/23 14:25
72-20-8
Endrin aldehyde
ND
ug/L
0.042
0.014
1
11/09/23 10:05
11/10/23 14:25
7421-93-4
Heptachlor
ND
ug/L
0.042
0.016
1
11/09/23 10:05
11/10/23 14:25
76-44-8
Heptachlor epoxide
ND
ug/L
0.042
0.024
1
11/09/23 10:05
11/10/23 14:25
1024-57-3
Methoxychlor
ND
ug/L
0.12
0.035
1
11/09/23 10:05
11/10/23 14:25
72-43-5
Toxaphene
ND
ug/L
0.42
0.18
1
11/09/23 10:05
11/10/23 14:25
8001-35-2
Surrogates
Tetrachloro-m-xylene (S)
87
%
10-137
1
11/09/23 10:05
11/10/23 14:25
877-09-8
Decachlorobiphenyl (S)
39
%
19-200
1
11/09/23 10:05
11/10/23 14:25
2051-24-3
8082 GCS PCB RVE
Analytical
Method: EPA 8082A
Preparation Method:
EPA 3510C
Pace Analytical
Services
- Charlotte
PCB-1016 (Aroclor 1016)
ND
ug/L
0.42
0.18
1
11/22/23 11:11
11/27/23 07:07
12674-11-2
PCB-1221 (Aroclor 1221)
ND
ug/L
0.42
0.19
1
11/22/23 11:11
11/27/23 07:07
11104-28-2
PCB-1232 (Aroclor 1232)
ND
ug/L
0.42
0.19
1
11/22/23 11:11
11/27/23 07:07
11141-16-5
PCB-1242 (Aroclor 1242)
ND
ug/L
0.42
0.21
1
11/22/23 11:11
11/27/23 07:07
53469-21-9
PCB-1248 (Aroclor 1248)
ND
ug/L
0.42
0.24
1
11/22/23 11:11
11/27/23 07:07
12672-29-6
PCB-1254 (Aroclor 1254)
ND
ug/L
0.42
0.18
1
11/22/23 11:11
11/27/23 07:07
11097-69-1
PCB-1260 (Aroclor 1260)
ND
ug/L
0.42
0.13
1
11/22/23 11:11
11/27/23 07:07
11096-82-5
Surrogates
Decachlorobiphenyl (S)
121
%
10-193
1
11/22/23 11:11
11/27/23 07:07
2051-24-3
Date: 11/28/2023 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 28 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-12 Lab ID: 92697334003 Collected: 11/06/23 15:49 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.6
1
11/10/2312:00
11/13/2316:50
7440-36-0
Arsenic
ND
ug/L
10.0
2.5
1
11/10/2312:00
11/13/2316:50
7440-38-2
Barium
66.6
ug/L
5.0
0.79
1
11/10/2312:00
11/13/2316:50
7440-39-3
Beryllium
ND
ug/L
1.0
0.16
1
11/10/2312:00
11/13/2316:50
7440-41-7
Cadmium
ND
ug/L
1.0
0.29
1
11/10/2312:00
11/13/2316:50
7440-43-9
Chromium
3.4.1
ug/L
5.0
0.63
1
11/10/2312:00
11/13/2316:50
7440-47-3
Cobalt
33.9
ug/L
5.0
0.44
1
11/10/2312:00
11/13/2316:50
7440-48-4
Copper
ND
ug/L
5.0
0.62
1
11/10/2312:00
11/13/2316:50
7440-50-8
Iron
47000
ug/L
50.0
8.9
1
11/10/2312:00
11/13/2316:50
7439-89-6
Lead
ND
ug/L
5.0
1.4
1
11/10/2312:00
11/13/2316:50
7439-92-1
Manganese
14000
ug/L
50.0
8.6
10
11/10/2312:00
11/14/2315:15
7439-96-5
Nickel
5.3
ug/L
5.0
0.88
1
11/10/2312:00
11/13/2316:50
7440-02-0
Selenium
ND
ug/L
10.0
4.1
1
11/10/2312:00
11/13/2316:50
7782-49-2
Silver
ND
ug/L
5.0
0.49
1
11/10/2312:00
11/13/2316:50
7440-22-4
Tin
ND
ug/L
5.0
2.0
1
11/10/2312:00
11/13/2316:50
7440-31-5
Vanadium
ND
ug/L
5.0
1.6
1
11/10/2312:00
11/13/2316:50
7440-62-2
Zinc
ND
ug/L
10.0
3.0
1
11/10/2312:00
11/13/2316:50
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.20
0.050
1
11/10/2312:25
11/12/2319:31
7440-28-0
7470 Mercury
Analytical Method: EPA 7470A Preparation Method:
EPA 7470A
Pace Analytical Services -Asheville
Mercury
ND
ug/L
0.20
0.12
1
11/15/2316:59
11/18/2311:42
7439-97-6
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Acenaphthene
ND
ug/L
8.3
1.7
1
11/09/23 10:09
11/12/23 18:17
83-32-9
Acenaphthylene
ND
ug/L
8.3
1.6
1
11/09/23 10:09
11/12/23 18:17
208-96-8
Acetophenone
ND
ug/L
8.3
1.2
1
11/09/23 10:09
11/12/23 18:17
98-86-2
2-Acetylaminofluorene
ND
ug/L
8.3
3.4
1
11/09/23 10:09
11/12/23 18:17
53-96-3
4-Aminobiphenyl
ND
ug/L
8.3
4.0
1
11/09/23 10:09
11/12/23 18:17
92-67-1
Anthracene
ND
ug/L
8.3
1.9
1
11/09/23 10:09
11/12/23 18:17
120-12-7
Benzo(a)anthracene
ND
ug/L
8.3
2.2
1
11/09/23 10:09
11/12/23 18:17
56-55-3
Benzo(a)pyrene
ND
ug/L
8.3
2.3
1
11/09/23 10:09
11/12/23 18:17
50-32-8
Benzo(b)fluoranthene
ND
ug/L
8.3
2.2
1
11/09/23 10:09
11/12/23 18:17
205-99-2
Benzo(g,h,i)perylene
ND
ug/L
8.3
2.4
1
11/09/23 10:09
11/12/23 18:17
191-24-2
Benzo(k)fluoranthene
ND
ug/L
8.3
2.3
1
11/09/23 10:09
11/12/23 18:17
207-08-9
Benzyl alcohol
ND
ug/L
16.7
2.4
1
11/09/23 10:09
11/12/23 18:17
100-51-6
4-Bromophenylphenyl ether
ND
ug/L
8.3
1.5
1
11/09/23 10:09
11/12/23 18:17
101-55-3
Butylbenzylphthalate
ND
ug/L
8.3
2.6
1
11/09/23 10:09
11/12/23 18:17
85-68-7
4-ChIoro-3-methyl phenol
ND
ug/L
8.3
2.8
1
11/09/23 10:09
11/12/23 18:17
59-50-7
4-Chloroaniline
ND
ug/L
16.7
3.0
1
11/09/23 10:09
11/12/23 18:17
106-47-8
Chlorobenzilate
ND
ug/L
8.3
3.2
1
11/09/23 10:09
11/12/23 18:17
510-15-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 29 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-12 Lab ID: 92697334003 Collected: 11/06/23 15:49 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
bis(2-Chloroethoxy)methane
ND
ug/L
8.3
1.5
1
11/09/23 10:09
11/12/23 18:17
111-91-1
bis(2-Chloroethyl) ether
ND
ug/L
8.3
1.6
1
11/09/23 10:09
11/12/23 18:17
111-44-4
2-Chloronaphthalene
ND
ug/L
8.3
1.4
1
11/09/23 10:09
11/12/23 18:17
91-58-7
2-Chlorophenol
ND
ug/L
8.3
1.0
1
11/09/23 10:09
11/12/23 18:17
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
8.3
1.7
1
11/09/23 10:09
11/12/23 18:17
7005-72-3
Chrysene
ND
ug/L
8.3
2.3
1
11/09/23 10:09
11/12/23 18:17
218-01-9
Diallate
ND
ug/L
8.3
2.8
1
11/09/23 10:09
11/12/23 18:17
2303-16-4
Dibenz(a,h)anthracene
ND
ug/L
8.3
2.5
1
11/09/23 10:09
11/12/23 18:17
53-70-3
Dibenzofuran
ND
ug/L
8.3
1.8
1
11/09/23 10:09
11/12/23 18:17
132-64-9
3,3'-Dichlorobenzidine
ND
ug/L
16.7
6.8
1
11/09/23 10:09
11/12/23 18:17
91-94-1
2,4-Dichlorophenol
ND
ug/L
8.3
1.2
1
11/09/23 10:09
11/12/23 18:17
120-83-2
2,6-Dichlorophenol
ND
ug/L
8.3
3.5
1
11/09/23 10:09
11/12/23 18:17
87-65-0
Diethylphthalate
ND
ug/L
8.3
1.7
1
11/09/23 10:09
11/12/23 18:17
84-66-2
Dimethoate
ND
ug/L
8.3
3.0
1
11/09/23 10:09
11/12/23 18:17
60-51-5
P-Dimethylaminoazobenzene
ND
ug/L
4.2
2.0
1
11/09/23 10:09
11/12/23 18:17
60-11-7
7,12-Dimethylbenz(a)anthracene
ND
ug/L
8.3
2.5
1
11/09/23 10:09
11/12/23 18:17
57-97-6
3,3'-Dimethylbenzidine
ND
ug/L
41.7
25.9
1
11/09/23 10:09
11/12/23 18:17
119-93-7
2,4-Dimethylphenol
ND
ug/L
8.3
1.4
1
11/09/23 10:09
11/12/23 18:17
105-67-9
Dimethylphthalate
ND
ug/L
8.3
1.8
1
11/09/23 10:09
11/12/23 18:17
131-11-3
Di-n-butylphthalate
ND
ug/L
8.3
1.8
1
11/09/23 10:09
11/12/23 18:17
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
16.7
6.5
1
11/09/23 10:09
11/12/23 18:17
534-52-1
1,3-Dinitrobenzene
ND
ug/L
8.3
3.1
1
11/09/23 10:09
11/12/23 18:17
99-65-0
2,4-Dinitrophenol
ND
ug/L
41.7
21.7
1
11/09/23 10:09
11/12/23 18:17
51-28-5
2,4-Dinitrotoluene
ND
ug/L
8.3
1.4
1
11/09/23 10:09
11/12/23 18:17
121-14-2
2,6-Dinitrotoluene
ND
ug/L
8.3
1.4
1
11/09/23 10:09
11/12/23 18:17
606-20-2
Di-n-octylphthalate
ND
ug/L
8.3
3.3
1
11/09/23 10:09
11/12/23 18:17
117-84-0
Diphenylamine
ND
ug/L
8.3
2.5
1
11/09/23 10:09
11/12/23 18:17
122-39-4
Disulfoton
ND
ug/L
8.3
3.9
1
11/09/23 10:09
11/12/23 18:17
298-04-4
bis(2- Ethyl hexyl)phthalate
ND
ug/L
5.0
3.1
1
11/09/23 10:09
11/12/23 18:17
117-81-7
Ethyl methanesulfonate
ND
ug/L
16.7
2.5
1
11/09/23 10:09
11/12/23 18:17
62-50-0
Famphur
ND
ug/L
8.3
5.1
1
11/09/23 10:09
11/12/23 18:17
52-85-7
Fluoranthene
ND
ug/L
8.3
1.8
1
11/09/23 10:09
11/12/23 18:17
206-44-0
Fluorene
ND
ug/L
8.3
1.7
1
11/09/23 10:09
11/12/23 18:17
86-73-7
Hexachloro-1,3-butadiene
ND
ug/L
8.3
1.5
1
11/09/23 10:09
11/12/23 18:17
87-68-3
Hexachlorobenzene
ND
ug/L
8.3
1.8
1
11/09/23 10:09
11/12/23 18:17
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
8.3
1.3
1
11/09/23 10:09
11/12/23 18:17
77-47-4
Hexachloroethane
ND
ug/L
8.3
1.2
1
11/09/23 10:09
11/12/23 18:17
67-72-1
Hexachloropropene
ND
ug/L
8.3
2.2
1
11/09/23 10:09
11/12/23 18:17
1888-71-7
Indeno(1,2,3-cd)pyrene
ND
ug/L
8.3
2.4
1
11/09/23 10:09
11/12/23 18:17
193-39-5
Isodrin
ND
ug/L
8.3
2.3
1
11/09/23 10:09
11/12/23 18:17
465-73-6
Isophorone
ND
ug/L
8.3
1.4
1
11/09/23 10:09
11/12/23 18:17
78-59-1
Isosafrole
ND
ug/L
8.3
2.1
1
11/09/23 10:09
11/12/23 18:17
120-58-1
Kepone
ND
ug/L
16.7
11.8
1
11/09/23 10:09
11/12/23 18:17
143-50-0
Methapyrilene
ND
ug/L
41.7
14.2
1
11/09/23 10:09
11/12/23 18:17
91-80-5
3-Methylcholanthrene
ND
ug/L
8.3
3.1
1
11/09/23 10:09
11/12/23 18:17
56-49-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-12 Lab ID: 92697334003 Collected: 11/06/23 15:49 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Methyl methanesulfonate
ND
ug/L
4.2
2.6
1
11/09/23 10:09
11/12/23 18:17
66-27-3
2-Methylnaphthalene
16.6
ug/L
8.3
1.6
1
11/09/23 10:09
11/12/23 18:17
91-57-6
Methyl parathion
ND
ug/L
8.3
3.1
1
11/09/23 10:09
11/12/23 18:17
298-00-0
2-Methylphenol(o-Cresol)
ND
ug/L
8.3
1.6
1
11/09/23 10:09
11/12/23 18:17
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
8.3
1.0
1
11/09/23 10:09
11/12/23 18:17
15831-10-4
1-Naphthalenamine
ND
ug/L
8.3
5.0
1
11/09/23 10:09
11/12/23 18:17
134-32-7
2-Naphthalenamine
ND
ug/L
8.3
4.5
1
11/09/23 10:09
11/12/23 18:17
91-59-8
1,4-Naphthoquinone
ND
ug/L
4.2
3.7
1
11/09/23 10:09
11/12/23 18:17
130-15-4
2-Nitroaniline
ND
ug/L
16.7
2.5
1
11/09/23 10:09
11/12/23 18:17
88-74-4
3-Nitroaniline
ND
ug/L
16.7
3.1
1
11/09/23 10:09
11/12/23 18:17
99-09-2
4-Nitroaniline
ND
ug/L
16.7
4.2
1
11/09/23 10:09
11/12/23 18:17
100-01-6
Nitrobenzene
ND
ug/L
8.3
1.6
1
11/09/23 10:09
11/12/23 18:17
98-95-3
2-Nitrophenol
ND
ug/L
8.3
1.2
1
11/09/23 10:09
11/12/23 18:17
88-75-5
4-Nitrophenol
ND
ug/L
41.7
5.5
1
11/09/23 10:09
11/12/23 18:17
100-02-7
5-Nitro-o-toluidine
ND
ug/L
8.3
3.2
1
11/09/23 10:09
11/12/23 18:17
99-55-8
N-Nitrosodiethylamine
ND
ug/L
8.3
1.9
1
11/09/23 10:09
11/12/23 18:17
55-18-5
N-Nitrosodimethylamine
ND
ug/L
8.3
1.6
1
11/09/23 10:09
11/12/23 18:17
62-75-9
N-Nitroso-di-n-butylamine
ND
ug/L
8.3
1.6
1
11/09/23 10:09
11/12/23 18:17
924-16-3
N-Nitroso-di-n-propylamine
ND
ug/L
8.3
1.1
1
11/09/23 10:09
11/12/23 18:17
621-64-7
N-Nitrosodiphenylamine
ND
ug/L
8.3
2.5
1
11/09/23 10:09
11/12/23 18:17
86-30-6
N-Nitrosomethylethylamine
ND
ug/L
8.3
6.2
1
11/09/23 10:09
11/12/23 18:17
10595-95-6
N-Nitrosopiperidine
ND
ug/L
8.3
2.1
1
11/09/23 10:09
11/12/23 18:17
100-75-4
N-Nitrosopyrrolidine
ND
ug/L
8.3
2.6
1
11/09/23 10:09
11/12/23 18:17
930-55-2
O,O,O-Triethylphosphorothioate
ND
ug/L
8.3
2.1
1
11/09/23 10:09
11/12/23 18:17
126-68-1
2,2'-Oxybis(1-chloropropane)
ND
ug/L
8.3
0.96
1
11/09/23 10:09
11/12/23 18:17
108-60-1
Parathion (Ethyl parathion)
ND
ug/L
8.3
3.2
1
11/09/23 10:09
11/12/23 18:17
56-38-2
Pentachlorobenzene
ND
ug/L
8.3
2.8
1
11/09/23 10:09
11/12/23 18:17
608-93-5
Pentachloronitrobenzene
ND
ug/L
8.3
2.7
1
11/09/23 10:09
11/12/23 18:17
82-68-8
Pentachlorophenol
ND
ug/L
16.7
3.1
1
11/09/23 10:09
11/12/23 18:17
87-86-5
Phenacetin
ND
ug/L
8.3
3.0
1
11/09/23 10:09
11/12/23 18:17
62-44-2
Phenanthrene
ND
ug/L
8.3
1.7
1
11/09/23 10:09
11/12/23 18:17
85-01-8
Phenol
ND
ug/L
8.3
1.1
1
11/09/23 10:09
11/12/23 18:17
108-95-2
p-Phenylenediamine
ND
ug/L
8.3
8.3
1
11/09/23 10:09
11/12/23 18:17
106-50-3
Phorate
ND
ug/L
8.3
3.0
1
11/09/23 10:09
11/12/23 18:17
298-02-2
Pronamide
ND
ug/L
8.3
2.6
1
11/09/23 10:09
11/12/23 18:17
23950-58-5
Pyrene
ND
ug/L
8.3
1.8
1
11/09/23 10:09
11/12/23 18:17
129-00-0
Safrole
ND
ug/L
8.3
1.9
1
11/09/23 10:09
11/12/23 18:17
94-59-7
1,2,4,5-Tetrachlorobenzene
ND
ug/L
8.3
3.7
1
11/09/23 10:09
11/12/23 18:17
95-94-3
2,3,4,6-Tetrachlorophenol
ND
ug/L
8.3
1.3
1
11/09/23 10:09
11/12/23 18:17
58-90-2
Thionazin
ND
ug/L
8.3
2.4
1
11/09/23 10:09
11/12/23 18:17
297-97-2
O-Toluidine
ND
ug/L
8.3
2.2
1
11/09/23 10:09
11/12/23 18:17
95-53-4
2,4,5-Trichlorophenol
ND
ug/L
8.3
1.2
1
11/09/23 10:09
11/12/23 18:17
95-95-4
2,4,6-Trichlorophenol
ND
ug/L
8.3
1.3
1
11/09/23 10:09
11/12/23 18:17
88-06-2
1,3,5-Trinitrobenzene
ND
ug/L
8.3
4.6
1
11/09/23 10:09
11/12/23 18:17
99-35-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-12 Lab ID: 92697334003 Collected: 11/06/23 15:49 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260D MSV Low Level Landfill
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Allyl chloride
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Chloroprene
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Date: 11/28/2023 02:34 PM
92
%
10-133
1
11/09/2310:09
11/12/2318:17
4165-60-0
81
%
10-130
1
11 /09/23 10:09
11 /12/23 18:17
321-60-8
103
%
10-193
1
11 /09/23 10:09
11 /12/23 18:17
1718-51-0
45
%
10-130
1
11/09/2310:09
11/12/2318:17
13127-88-3
56
%
10-130
1
11/09/2310:09
11/12/2318:17
367-12-4
104
%
10-166
1
11/09/2310:09
11/12/2318:17
118-79-6
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
11/11/2312:14
67-64-1
ND
ug/L
50.0
24.8
1
11/11/2312:14
75-05-8
ND
ug/L
10.0
8.5
1
11/11/2312:14
107-02-8 AC
ND
ug/L
10.0
1.8
1
11/11/2312:14
107-13-1
ND
ug/L
2.0
0.50
1
11/11/2312:14
107-05-1
3.6
ug/L
1.0
0.34
1
11/11/2312:14
71-43-2
ND
ug/L
1.0
0.47
1
11/11/2312:14
74-97-5
ND
ug/L
1.0
0.31
1
11/11/2312:14
75-27-4
ND
ug/L
1.0
0.34
1
11/11/2312:14
75-25-2
ND
ug/L
2.0
1.7
1
11/11/2312:14
74-83-9
ND
ug/L
5.0
4.0
1
11/11/2312:14
78-93-3
ND
ug/L
2.0
0.36
1
11/11/2312:14
75-15-0
ND
ug/L
1.0
0.33
1
11/11/2312:14
56-23-5
0.85J
ug/L
1.0
0.28
1
11/11/2312:14
108-90-7
5.7
ug/L
1.0
0.65
1
11/11/2312:14
75-00-3
ND
ug/L
1.0
0.43
1
11/11/2312:14
67-66-3
ND
ug/L
1.0
0.54
1
11/11/2312:14
74-87-3
ND
ug/L
5.0
1.6
1
11/11/2312:14
126-99-8
ND
ug/L
1.0
0.36
1
11/11/2312:14
124-48-1
ND
ug/L
1.0
0.34
1
11/11/2312:14
95-50-1
ND
ug/L
1.0
0.34
1
11/11/2312:14
541-73-1
5.4
ug/L
1.0
0.33
1
11/11/2312:14
106-46-7
ND
ug/L
1.0
0.56
1
11/11/2312:14
110-57-6
ND
ug/L
1.0
0.35
1
11/11/2312:14
75-71-8 v1
18.2
ug/L
1.0
0.37
1
11/11/2312:14
75-34-3
0.97J
ug/L
1.0
0.32
1
11/11/2312:14
107-06-2
ND
ug/L
1.0
0.35
1
11/11/2312:14
75-35-4
9.5
ug/L
1.0
0.38
1
11/11/2312:14
156-59-2
ND
ug/L
1.0
0.40
1
11/11/2312:14
156-60-5
ND
ug/L
1.0
0.28
1
11/11/2312:14
142-28-9
ND
ug/L
1.0
0.39
1
11/11/2312:14
594-20-7
ND
ug/L
1.0
0.43
1
11/11/2312:14
563-58-6 v1
ND
ug/L
1.0
0.36
1
11/11/2312:14
10061-01-5
ND
ug/L
1.0
0.36
1
11 /11 /23 12:14
10061-02-6
0.62J
ug/L
1.0
0.30
1
11/11/2312:14
100-41-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 32 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-12 Lab ID: 92697334003 Collected: 11/06/23 15:49 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Ethyl methacrylate
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Methylene Chloride
Methyl methacrylate
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
2540C Total Dissolved Solids
Total Dissolved Solids
Date: 11/28/2023 02:34 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
20.0
ND
ug/L
100
ND
ug/L
10.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
20.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
0.77J
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
2.1
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
0.69.1
ug/L
1.0
2.8
ug/L
1.0
97
%
70-130
97
%
70-130
99
%
70-130
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
13.1 ug/L 2.0
89 % 67-130
90 % 70-130
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
134 mg/L 5.0
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
16.4 mg/L 2.5
0.28
1
11/11/23 12:14
97-63-2
1.5
1
11/11/23 12:14
87-68-3
0.48
1
11/11/23 12:14
591-78-6
9.7
1
11/11/23 12:14
74-88-4
52.3
1
11/11/23 12:14
78-83-1
4.2
1
11/11/23 12:14
126-98-7
2.0
1
11/11/23 12:14
75-09-2
0.32
1
11/11/23 12:14
80-62-6
0.64
1
11/11/23 12:14
91-20-3
3.6
1
11/11/23 12:14
107-12-0
0.29
1
11/11/23 12:14
100-42-5
0.31
1
11/11/23 12:14
630-20-6
0.22
1
11/11/23 12:14
79-34-5
0.29
1
11/11/23 12:14
127-18-4
0.24
1
11/11/23 12:14
108-88-3
0.64
1
11/11/23 12:14
120-82-1
0.33
1
11/11/23 12:14
71-55-6
0.32
1
11/11/23 12:14
79-00-5
0.38
1
11/11/23 12:14
79-01-6
0.30
1
11/11/23 12:14
75-69-4
0.26
1
11/11/23 12:14
96-18-4
1.3
1
11/11/23 12:14
108-05-4
0.39
1
11/11/23 12:14
75-01-4
0.34
1
11/11/23 12:14
1330-20-7
I
111E:I:>il
I
5.0 1
2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
11 /11 /23 12:14 460-00-4
11/11/23 12:14 17060-07-0
11/11/23 12:14 2037-26-5
IfIf100�ci1LICElm fa 4Qi
11/10/23 04:40 17060-07-0
11/10/23 04:40 2037-26-5
11/15/23 19:14
11 /09/23 10:48
Page 33 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-12
Lab ID: 92697334003 Collected: 11/06/23 15:49
Received: 11/07/23 17:05 Matrix: Water
Report
Parameters
Results Units Limit MDL
DF
Prepared Analyzed
CAS No. Qual
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
Sulfide
41.1J ug/L 100 22.0
1
11/09/23 05:37
18496-25-8
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
Chloride
17.0 mg/L 1.0 0.60
1
11/09/23 23:47
16887-00-6
Sulfate
1.2 mg/L 1.0 0.50
1
11/09/23 23:47
14808-79-8
4500CNE Cyanide, Total
Analytical Method: SM 4500-CN-E-2016 Preparation Method:
SM 4500-CN-E-2016
Pace Analytical Services -Asheville
Cyanide
ND ug/L 8.0 6.0
1
11/14/23 17:30 11/14/23 20:31
57-12-5
Date: 11/28/2023 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 34 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-13
Lab ID:
92697334004
Collected:
11/07/23 14:55
Received: 11/07/23 17:05 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
Chlorinated Herb. (GC) 8151
Analytical
Method: EPA8151
Preparation
Method: 8151A
Pace National
- Mt. Juliet
2,4-D
ND
ug/L
2.00
0.547
1
11/13/23 11:59
11/14/23 15:07
94-75-7
2,4,5-T
ND
ug/L
2.00
0.258
1
11/13/23 11:59
11/14/23 15:07
93-76-5
2,4,5-TP (Silvex)
ND
ug/L
2.00
0.335
1
11/13/23 11:59
11/14/23 15:07
93-72-1
Dinoseb
ND
ug/L
2.00
0.250
1
11/13/23 11:59
11/14/23 15:07
88-85-7
Surrogates
2,4-DCAA (S)
95.6
%
14.0-158
1
11/13/23 11:59
11/14/23 15:07
19719-28-9
8081 OC Pesticides RVE
Analytical
Method: EPA 8081
B Preparation Method: EPA 3510C
Pace Analytical
Services
- Charlotte
Aldrin
ND
ug/L
0.042
0.012
1
11/09/23 10:05
11/10/23 15:15
309-00-2
alpha-BHC
ND
ug/L
0.042
0.010
1
11/09/23 10:05
11/10/23 15:15
319-84-6
beta-BHC
ND
ug/L
0.042
0.041
1
11/09/23 10:05
11/10/23 15:15
319-85-7
delta-BHC
ND
ug/L
0.042
0.012
1
11/09/23 10:05
11/10/23 15:15
319-86-8
gamma-BHC (Lindane)
ND
ug/L
0.042
0.010
1
11/09/23 10:05
11/10/23 15:15
58-89-9
Chlordane (Technical)
ND
ug/L
0.42
0.13
1
11/09/23 10:05
11/10/23 15:15
57-74-9
4,4'-DDD
ND
ug/L
0.042
0.014
1
11/09/23 10:05
11/10/23 15:15
72-54-8
4,4'-DDE
ND
ug/L
0.042
0.020
1
11/09/23 10:05
11/10/23 15:15
72-55-9
4,4'-DDT
ND
ug/L
0.042
0.022
1
11/09/23 10:05
11/10/23 15:15
50-29-3
Dieldrin
ND
ug/L
0.042
0.012
1
11/09/23 10:05
11/10/23 15:15
60-57-1
Endosulfan I
ND
ug/L
0.042
0.014
1
11/09/23 10:05
11/10/23 15:15
959-98-8
Endosulfan 11
ND
ug/L
0.042
0.013
1
11/09/23 10:05
11/10/23 15:15
33213-65-9
Endosulfan sulfate
ND
ug/L
0.042
0.012
1
11/09/23 10:05
11/10/23 15:15
1031-07-8
Endrin
ND
ug/L
0.042
0.015
1
11/09/23 10:05
11/10/23 15:15
72-20-8
Endrin aldehyde
ND
ug/L
0.042
0.014
1
11/09/23 10:05
11/10/23 15:15
7421-93-4
Heptachlor
ND
ug/L
0.042
0.016
1
11/09/23 10:05
11/10/23 15:15
76-44-8
Heptachlor epoxide
ND
ug/L
0.042
0.024
1
11/09/23 10:05
11/10/23 15:15
1024-57-3
Methoxychlor
ND
ug/L
0.12
0.035
1
11/09/23 10:05
11/10/23 15:15
72-43-5
Toxaphene
ND
ug/L
0.42
0.18
1
11/09/23 10:05
11/10/23 15:15
8001-35-2
Surrogates
Tetrachloro-m-xylene (S)
170
%
10-137
1
11/09/23 10:05
11/10/23 15:15
877-09-8 S3
Decachlorobiphenyl (S)
51
%
19-200
1
11/09/23 10:05
11/10/23 15:15
2051-24-3
8082 GCS PCB RVE
Analytical
Method: EPA 8082A
Preparation Method:
EPA 3510C
Pace Analytical
Services
- Charlotte
PCB-1016 (Aroclor 1016)
ND
ug/L
0.42
0.18
1
11/22/23 11:11
11/27/23 07:19
12674-11-2
PCB-1221 (Aroclor 1221)
ND
ug/L
0.42
0.19
1
11/22/23 11:11
11/27/23 07:19
11104-28-2
PCB-1232 (Aroclor 1232)
ND
ug/L
0.42
0.19
1
11/22/23 11:11
11/27/23 07:19
11141-16-5
PCB-1242 (Aroclor 1242)
ND
ug/L
0.42
0.21
1
11/22/23 11:11
11/27/23 07:19
53469-21-9
PCB-1248 (Aroclor 1248)
ND
ug/L
0.42
0.24
1
11/22/23 11:11
11/27/23 07:19
12672-29-6
PCB-1254 (Aroclor 1254)
ND
ug/L
0.42
0.18
1
11/22/23 11:11
11/27/23 07:19
11097-69-1
PCB-1260 (Aroclor 1260)
ND
ug/L
0.42
0.13
1
11/22/23 11:11
11/27/23 07:19
11096-82-5
Surrogates
Decachlorobiphenyl (S)
102
%
10-193
1
11/22/23 11:11
11/27/23 07:19
2051-24-3
Date: 11/28/2023 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 35 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-13 Lab ID: 92697334004 Collected: 11/07/23 14:55 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.6
1
11/10/2312:00
11/13/2316:52
7440-36-0
Arsenic
ND
ug/L
10.0
2.5
1
11/10/2312:00
11/13/2316:52
7440-38-2
Barium
82.4
ug/L
5.0
0.79
1
11/10/2312:00
11/13/2316:52
7440-39-3
Beryllium
ND
ug/L
1.0
0.16
1
11/10/2312:00
11/13/2316:52
7440-41-7
Cadmium
0.31J
ug/L
1.0
0.29
1
11/10/2312:00
11/13/2316:52
7440-43-9
Chromium
11.4.1
ug/L
5.0
0.63
1
11/10/2312:00
11/13/2316:52
7440-47-3
Cobalt
69.8
ug/L
5.0
0.44
1
11/10/2312:00
11/13/2316:52
7440-48-4
Copper
12.0
ug/L
5.0
0.62
1
11/10/2312:00
11/13/2316:52
7440-50-8
Iron
3090
ug/L
50.0
8.9
1
11/10/2312:00
11/13/2316:52
7439-89-6
Lead
2.0.1
ug/L
5.0
1.4
1
11/10/2312:00
11/13/2316:52
7439-92-1
Manganese
1930
ug/L
5.0
0.86
1
11/10/2312:00
11/13/2316:52
7439-96-5
Nickel
4.4.1
ug/L
5.0
0.88
1
11/10/2312:00
11/13/2316:52
7440-02-0
Selenium
ND
ug/L
10.0
4.1
1
11/10/2312:00
11/13/2316:52
7782-49-2
Silver
ND
ug/L
5.0
0.49
1
11/10/2312:00
11/13/2316:52
7440-22-4
Tin
ND
ug/L
5.0
2.0
1
11/10/2312:00
11/13/2316:52
7440-31-5
Vanadium
2.4J
ug/L
5.0
1.6
1
11/10/2312:00
11/13/2316:52
7440-62-2
Zinc
18.4
ug/L
10.0
3.0
1
11/10/2312:00
11/13/2316:52
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
0.181
ug/L
0.20
0.050
1
11/10/2312:25
11/12/2319:51
7440-28-0
7470 Mercury
Analytical Method: EPA 7470A Preparation Method: EPA
7470A
Pace Analytical Services -Asheville
Mercury
3.1
ug/L
0.20
0.12
1
11/15/2316:59
11/18/2311:45
7439-97-6
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA
3510C
Pace Analytical Services - Charlotte
Acenaphthene
ND
ug/L
9.1
1.8
1
11/09/23 15:47
11/14/23 17:25
83-32-9
Acenaphthylene
ND
ug/L
9.1
1.8
1
11/09/23 15:47
11/14/23 17:25
208-96-8
Acetophenone
ND
ug/L
9.1
1.4
1
11/09/23 15:47
11/14/23 17:25
98-86-2
2-Acetylaminofluorene
ND
ug/L
9.1
3.7
1
11/09/23 15:47
11/14/23 17:25
53-96-3
4-Aminobiphenyl
ND
ug/L
9.1
4.3
1
11/09/23 15:47
11/14/23 17:25
92-67-1
Anthracene
ND
ug/L
9.1
2.1
1
11/09/23 15:47
11/14/23 17:25
120-12-7
Benzo(a)anthracene
ND
ug/L
9.1
2.4
1
11/09/23 15:47
11/14/23 17:25
56-55-3
Benzo(a)pyrene
ND
ug/L
9.1
2.5
1
11/09/23 15:47
11/14/23 17:25
50-32-8
Benzo(b)fluoranthene
ND
ug/L
9.1
2.4
1
11/09/23 15:47
11/14/23 17:25
205-99-2
Benzo(g,h,i)perylene
ND
ug/L
9.1
2.6
1
11/09/23 15:47
11/14/23 17:25
191-24-2
Benzo(k)fluoranthene
ND
ug/L
9.1
2.5
1
11/09/23 15:47
11/14/23 17:25
207-08-9
Benzyl alcohol
ND
ug/L
18.2
2.6
1
11/09/23 15:47
11/14/23 17:25
100-51-6
4-Bromophenylphenyl ether
ND
ug/L
9.1
1.6
1
11/09/23 15:47
11/14/23 17:25
101-55-3
Butylbenzylphthalate
ND
ug/L
9.1
2.9
1
11/09/23 15:47
11/14/23 17:25
85-68-7
4-ChIoro-3-methyl phenol
ND
ug/L
9.1
3.0
1
11/09/23 15:47
11/14/23 17:25
59-50-7
4-Chloroaniline
ND
ug/L
18.2
3.3
1
11/09/23 15:47
11/14/23 17:25
106-47-8
Chlorobenzilate
ND
ug/L
9.1
3.4
1
11/09/23 15:47
11/14/23 17:25
510-15-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 36 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-13 Lab ID: 92697334004 Collected: 11/07/23 14:55 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
bis(2-Chloroethoxy)methane
ND
ug/L
9.1
1.7
1
11/09/23 15:47
11/14/23 17:25
111-91-1
bis(2-Chloroethyl) ether
ND
ug/L
9.1
1.7
1
11/09/23 15:47
11/14/23 17:25
111-44-4
2-Chloronaphthalene
ND
ug/L
9.1
1.6
1
11/09/23 15:47
11/14/23 17:25
91-58-7
2-Chlorophenol
ND
ug/L
9.1
1.1
1
11/09/23 15:47
11/14/23 17:25
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
9.1
1.8
1
11/09/23 15:47
11/14/23 17:25
7005-72-3
Chrysene
ND
ug/L
9.1
2.5
1
11/09/23 15:47
11/14/23 17:25
218-01-9
Diallate
ND
ug/L
9.1
3.1
1
11/09/23 15:47
11/14/23 17:25
2303-16-4
Dibenz(a,h)anthracene
ND
ug/L
9.1
2.7
1
11/09/23 15:47
11/14/23 17:25
53-70-3
Dibenzofuran
ND
ug/L
9.1
1.9
1
11/09/23 15:47
11/14/23 17:25
132-64-9
3,3'-Dichlorobenzidine
ND
ug/L
18.2
7.4
1
11/09/23 15:47
11/14/23 17:25
91-94-1
2,4-Dichlorophenol
ND
ug/L
9.1
1.3
1
11/09/23 15:47
11/14/23 17:25
120-83-2
2,6-Dichlorophenol
ND
ug/L
9.1
3.8
1
11/09/23 15:47
11/14/23 17:25
87-65-0
Diethylphthalate
ND
ug/L
9.1
1.9
1
11/09/23 15:47
11/14/23 17:25
84-66-2
Dimethoate
ND
ug/L
9.1
3.3
1
11/09/23 15:47
11/14/23 17:25
60-51-5
P-Dimethylaminoazobenzene
ND
ug/L
4.5
2.2
1
11/09/23 15:47
11/14/23 17:25
60-11-7
7,12-Dimethylbenz(a)anthracene
ND
ug/L
9.1
2.7
1
11/09/23 15:47
11/14/23 17:25
57-97-6
3,3'-Dimethylbenzidine
ND
ug/L
45.5
28.3
1
11/09/23 15:47
11/14/23 17:25
119-93-7
2,4-Dimethylphenol
ND
ug/L
9.1
1.5
1
11/09/23 15:47
11/14/23 17:25
105-67-9
Dimethylphthalate
ND
ug/L
9.1
1.9
1
11/09/23 15:47
11/14/23 17:25
131-11-3
Di-n-butylphthalate
ND
ug/L
9.1
2.0
1
11/09/23 15:47
11/14/23 17:25
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
18.2
7.1
1
11/09/23 15:47
11/14/23 17:25
534-52-1
1,3-Dinitrobenzene
ND
ug/L
9.1
3.4
1
11/09/23 15:47
11/14/23 17:25
99-65-0
2,4-Dinitrophenol
ND
ug/L
45.5
23.6
1
11/09/23 15:47
11/14/23 17:25
51-28-5
2,4-Dinitrotoluene
ND
ug/L
9.1
1.5
1
11/09/23 15:47
11/14/23 17:25
121-14-2
2,6-Dinitrotoluene
ND
ug/L
9.1
1.6
1
11/09/23 15:47
11/14/23 17:25
606-20-2
Di-n-octylphthalate
ND
ug/L
9.1
3.6
1
11/09/23 15:47
11/14/23 17:25
117-84-0
Diphenylamine
ND
ug/L
9.1
2.7
1
11/09/23 15:47
11/14/23 17:25
122-39-4
Disulfoton
ND
ug/L
9.1
4.2
1
11/09/23 15:47
11/14/23 17:25
298-04-4
bis(2- Ethyl hexyl)phthalate
ND
ug/L
5.5
3.4
1
11/09/23 15:47
11/14/23 17:25
117-81-7
Ethyl methanesulfonate
ND
ug/L
18.2
2.7
1
11/09/23 15:47
11/14/23 17:25
62-50-0
Famphur
ND
ug/L
9.1
5.6
1
11/09/23 15:47
11/14/23 17:25
52-85-7
Fluoranthene
ND
ug/L
9.1
2.0
1
11/09/23 15:47
11/14/23 17:25
206-44-0
Fluorene
ND
ug/L
9.1
1.9
1
11/09/23 15:47
11/14/23 17:25
86-73-7
Hexachloro-1,3-butadiene
ND
ug/L
9.1
1.6
1
11/09/23 15:47
11/14/23 17:25
87-68-3
Hexachlorobenzene
ND
ug/L
9.1
2.0
1
11/09/23 15:47
11/14/23 17:25
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
9.1
1.4
1
11/09/23 15:47
11/14/23 17:25
77-47-4
Hexachloroethane
ND
ug/L
9.1
1.3
1
11/09/23 15:47
11/14/23 17:25
67-72-1
Hexachloropropene
ND
ug/L
9.1
2.5
1
11/09/23 15:47
11/14/23 17:25
1888-71-7
Indeno(1,2,3-cd)pyrene
ND
ug/L
9.1
2.6
1
11/09/23 15:47
11/14/23 17:25
193-39-5
Isodrin
ND
ug/L
9.1
2.5
1
11/09/23 15:47
11/14/23 17:25
465-73-6
Isophorone
ND
ug/L
9.1
1.5
1
11/09/23 15:47
11/14/23 17:25
78-59-1
Isosafrole
ND
ug/L
9.1
2.3
1
11/09/23 15:47
11/14/23 17:25
120-58-1
Kepone
ND
ug/L
18.2
12.8
1
11/09/23 15:47
11/14/23 17:25
143-50-0
Methapyrilene
ND
ug/L
45.5
15.5
1
11/09/23 15:47
11/14/23 17:25
91-80-5
3-Methylcholanthrene
ND
ug/L
9.1
3.4
1
11/09/23 15:47
11/14/23 17:25
56-49-5
REPORT OF LABORATORY ANALYSIS
L2,v2
v1
L2,v1
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-13 Lab ID: 92697334004 Collected: 11/07/23 14:55 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Methyl methanesulfonate
ND
ug/L
4.5
2.8
1
11/09/23 15:47
11/14/23 17:25
66-27-3
2-Methylnaphthalene
ND
ug/L
9.1
1.7
1
11/09/23 15:47
11/14/23 17:25
91-57-6
Methyl parathion
ND
ug/L
9.1
3.4
1
11/09/23 15:47
11/14/23 17:25
298-00-0
2-Methylphenol(o-Cresol)
ND
ug/L
9.1
1.7
1
11/09/23 15:47
11/14/23 17:25
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
9.1
1.1
1
11/09/23 15:47
11/14/23 17:25
15831-10-4
1-Naphthalenamine
ND
ug/L
9.1
5.5
1
11/09/23 15:47
11/14/23 17:25
134-32-7
2-Naphthalenamine
ND
ug/L
9.1
5.0
1
11/09/23 15:47
11/14/23 17:25
91-59-8
1,4-Naphthoquinone
ND
ug/L
4.5
4.0
1
11/09/23 15:47
11/14/23 17:25
130-15-4
2-Nitroaniline
ND
ug/L
18.2
2.7
1
11/09/23 15:47
11/14/23 17:25
88-74-4
3-Nitroaniline
ND
ug/L
18.2
3.4
1
11/09/23 15:47
11/14/23 17:25
99-09-2
4-Nitroaniline
ND
ug/L
18.2
4.6
1
11/09/23 15:47
11/14/23 17:25
100-01-6
Nitrobenzene
ND
ug/L
9.1
1.7
1
11/09/23 15:47
11/14/23 17:25
98-95-3
2-Nitrophenol
ND
ug/L
9.1
1.3
1
11/09/23 15:47
11/14/23 17:25
88-75-5
4-Nitrophenol
ND
ug/L
45.5
6.0
1
11/09/23 15:47
11/14/23 17:25
100-02-7
5-Nitro-o-toluidine
ND
ug/L
9.1
3.5
1
11/09/23 15:47
11/14/23 17:25
99-55-8
N-Nitrosodiethylamine
ND
ug/L
9.1
2.1
1
11/09/23 15:47
11/14/23 17:25
55-18-5
N-Nitrosodimethylamine
ND
ug/L
9.1
1.7
1
11/09/23 15:47
11/14/23 17:25
62-75-9
N-Nitroso-di-n-butylamine
ND
ug/L
9.1
1.8
1
11/09/23 15:47
11/14/23 17:25
924-16-3
N-Nitroso-di-n-propylamine
ND
ug/L
9.1
1.2
1
11/09/23 15:47
11/14/23 17:25
621-64-7
N-Nitrosodiphenylamine
ND
ug/L
9.1
2.7
1
11/09/23 15:47
11/14/23 17:25
86-30-6
N-Nitrosomethylethylamine
ND
ug/L
9.1
6.8
1
11/09/23 15:47
11/14/23 17:25
10595-95-6
N-Nitrosopiperidine
ND
ug/L
9.1
2.3
1
11/09/23 15:47
11/14/23 17:25
100-75-4
N-Nitrosopyrrolidine
ND
ug/L
9.1
2.8
1
11/09/23 15:47
11/14/23 17:25
930-55-2
O,O,O-Triethylphosphorothioate
ND
ug/L
9.1
2.3
1
11/09/23 15:47
11/14/23 17:25
126-68-1
2,2'-Oxybis(1-chloropropane)
ND
ug/L
9.1
1.0
1
11/09/23 15:47
11/14/23 17:25
108-60-1
Parathion (Ethyl parathion)
ND
ug/L
9.1
3.5
1
11/09/23 15:47
11/14/23 17:25
56-38-2
Pentachlorobenzene
ND
ug/L
9.1
3.1
1
11/09/23 15:47
11/14/23 17:25
608-93-5
Pentachloronitrobenzene
ND
ug/L
9.1
3.0
1
11/09/23 15:47
11/14/23 17:25
82-68-8
Pentachlorophenol
ND
ug/L
18.2
3.4
1
11/09/23 15:47
11/14/23 17:25
87-86-5
Phenacetin
ND
ug/L
9.1
3.3
1
11/09/23 15:47
11/14/23 17:25
62-44-2
Phenanthrene
ND
ug/L
9.1
1.8
1
11/09/23 15:47
11/14/23 17:25
85-01-8
Phenol
ND
ug/L
9.1
1.2
1
11/09/23 15:47
11/14/23 17:25
108-95-2
p-Phenylenediamine
ND
ug/L
9.1
9.1
1
11/09/23 15:47
11/14/23 17:25
106-50-3
Phorate
ND
ug/L
9.1
3.2
1
11/09/23 15:47
11/14/23 17:25
298-02-2
Pronamide
ND
ug/L
9.1
2.8
1
11/09/23 15:47
11/14/23 17:25
23950-58-5
Pyrene
ND
ug/L
9.1
2.0
1
11/09/23 15:47
11/14/23 17:25
129-00-0
Safrole
ND
ug/L
9.1
2.1
1
11/09/23 15:47
11/14/23 17:25
94-59-7
1,2,4,5-Tetrachlorobenzene
ND
ug/L
9.1
4.1
1
11/09/23 15:47
11/14/23 17:25
95-94-3
2,3,4,6-Tetrachlorophenol
ND
ug/L
9.1
1.4
1
11/09/23 15:47
11/14/23 17:25
58-90-2
Thionazin
ND
ug/L
9.1
2.6
1
11/09/23 15:47
11/14/23 17:25
297-97-2
O-Toluidine
ND
ug/L
9.1
2.4
1
11/09/23 15:47
11/14/23 17:25
95-53-4
2,4,5-Trichlorophenol
ND
ug/L
9.1
1.3
1
11/09/23 15:47
11/14/23 17:25
95-95-4
2,4,6-Trichlorophenol
ND
ug/L
9.1
1.4
1
11/09/23 15:47
11/14/23 17:25
88-06-2
1,3,5-Trinitrobenzene
ND
ug/L
9.1
5.0
1
11/09/23 15:47
11/14/23 17:25
99-35-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-13 Lab ID: 92697334004 Collected: 11/07/23 14:55 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260D MSV Low Level Landfill
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Allyl chloride
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Chloroprene
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Date: 11/28/2023 02:34 PM
89
%
10-133
1
11/09/2315:47
11/14/2317:25
4165-60-0
82
%
10-130
1
11 /09/23 15:47
11 /14/23 17:25
321-60-8
122
%
10-193
1
11 /09/23 15:47
11 /14/23 17:25
1718-51-0
49
%
10-130
1
11/09/2315:47
11/14/2317:25
13127-88-3
66
%
10-130
1
11/09/2315:47
11/14/2317:25
367-12-4
118
%
10-166
1
11/09/2315:47
11/14/2317:25
118-79-6
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
11/11/2312:32
67-64-1
ND
ug/L
50.0
24.8
1
11/11/2312:32
75-05-8
ND
ug/L
10.0
8.5
1
11/11/2312:32
107-02-8 AC
ND
ug/L
10.0
1.8
1
11/11/2312:32
107-13-1
ND
ug/L
2.0
0.50
1
11/11/2312:32
107-05-1
11.6
ug/L
1.0
0.34
1
11/11/23 12:32
71-43-2
ND
ug/L
1.0
0.47
1
11/11/2312:32
74-97-5
ND
ug/L
1.0
0.31
1
11/11/2312:32
75-27-4
ND
ug/L
1.0
0.34
1
11/11/2312:32
75-25-2
ND
ug/L
2.0
1.7
1
11/11/2312:32
74-83-9
ND
ug/L
5.0
4.0
1
11/11/2312:32
78-93-3
ND
ug/L
2.0
0.36
1
11/11/2312:32
75-15-0
ND
ug/L
1.0
0.33
1
11/11/2312:32
56-23-5
1.7
ug/L
1.0
0.28
1
11/11/2312:32
108-90-7
ND
ug/L
1.0
0.65
1
11/11/2312:32
75-00-3
ND
ug/L
1.0
0.43
1
11/11/2312:32
67-66-3
ND
ug/L
1.0
0.54
1
11/11/2312:32
74-87-3
ND
ug/L
5.0
1.6
1
11/11/2312:32
126-99-8
ND
ug/L
1.0
0.36
1
11/11/2312:32
124-48-1
0.77J
ug/L
1.0
0.34
1
11/11/2312:32
95-50-1
ND
ug/L
1.0
0.34
1
11/11/2312:32
541-73-1
20.9
ug/L
1.0
0.33
1
11/11/2312:32
106-46-7
ND
ug/L
1.0
0.56
1
11/11/2312:32
110-57-6
ND
ug/L
1.0
0.35
1
11/11/2312:32
75-71-8 v1
10.3
ug/L
1.0
0.37
1
11/11/2312:32
75-34-3
0.65J
ug/L
1.0
0.32
1
11/11/2312:32
107-06-2
ND
ug/L
1.0
0.35
1
11/11/2312:32
75-35-4
18.4
ug/L
1.0
0.38
1
11/11/2312:32
156-59-2
ND
ug/L
1.0
0.40
1
11/11/2312:32
156-60-5
ND
ug/L
1.0
0.28
1
11/11/2312:32
142-28-9
ND
ug/L
1.0
0.39
1
11/11/2312:32
594-20-7
ND
ug/L
1.0
0.43
1
11/11/2312:32
563-58-6 v1
ND
ug/L
1.0
0.36
1
11/11/2312:32
10061-01-5
ND
ug/L
1.0
0.36
1
11 /11 /23 12:32
10061-02-6
1.4
ug/L
1.0
0.30
1
11/11/2312:32
100-41-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 39 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-13 Lab ID: 92697334004 Collected: 11/07/23 14:55 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Ethyl methacrylate
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Methylene Chloride
Methyl methacrylate
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
2540C Total Dissolved Solids
Total Dissolved Solids
Date: 11/28/2023 02:34 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
20.0
ND
ug/L
100
ND
ug/L
10.0
38.5
ug/L
5.0
ND
ug/L
2.0
3.1
ug/L
1.0
ND
ug/L
20.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
4.1
ug/L
1.0
1.6
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
6.2
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
1.0
53.5
ug/L
1.0
98
%
70-130
94
%
70-130
101
%
70-130
Analytical
Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
1.7J
ug/L
2.0
85
%
67-130
89
%
70-130
Analytical
Method: SM 2320B-2011
Pace Analytical Services
-Asheville
ND
mg/L
5.0
Analytical
Method: SM 2540C-2015
Pace Analytical Services
-Asheville
3.3
mg/L
2.5
0.28
1
11/11/23 12:32
97-63-2
1.5
1
11/11/23 12:32
87-68-3
0.48
1
11/11/23 12:32
591-78-6
9.7
1
11/11/23 12:32
74-88-4
52.3
1
11/11/23 12:32
78-83-1
4.2
1
11/11/23 12:32
126-98-7
2.0
1
11/11/23 12:32
75-09-2
0.32
1
11/11/23 12:32
80-62-6
0.64
1
11/11/23 12:32
91-20-3
3.6
1
11/11/23 12:32
107-12-0
0.29
1
11/11/23 12:32
100-42-5
0.31
1
11/11/23 12:32
630-20-6
0.22
1
11/11/23 12:32
79-34-5
0.29
1
11/11/23 12:32
127-18-4
0.24
1
11/11/23 12:32
108-88-3
0.64
1
11/11/23 12:32
120-82-1
0.33
1
11/11/23 12:32
71-55-6
0.32
1
11/11/23 12:32
79-00-5
0.38
1
11/11/23 12:32
79-01-6
0.30
1
11/11/23 12:32
75-69-4
0.26
1
11/11/23 12:32
96-18-4
1.3
1
11/11/23 12:32
108-05-4
0.39
1
11/11/23 12:32
75-01-4
0.34
1
11/11/23 12:32
1330-20-7
I
111E:I:>il
I
5.0 1
2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
11/11/23 12:32 460-00-4
11/11/23 12:32 17060-07-0
11/11/23 12:32 2037-26-5
ffIf10011911&' 111=iPa ;SQiI
11/10/23 05:01 17060-07-0
11/10/23 05:01 2037-26-5
11/15/23 20:07
11 /09/23 10:48
Page 40 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-13
Lab ID: 92697334004 Collected: 11/07/23 14:55
Received: 11/07/23 17:05 Matrix: Water
Report
Parameters
Results Units Limit MDL
DF
Prepared Analyzed
CAS No. Qual
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
Sulfide
ND ug/L 100 22.0
1
11/09/23 05:42
18496-25-8
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
Chloride
2.0 mg/L 1.0 0.60
1
11/10/23 00:02
16887-00-6
Sulfate
1.2 mg/L 1.0 0.50
1
11/10/23 00:02
14808-79-8
4500CNE Cyanide, Total
Analytical Method: SM 4500-CN-E-2016 Preparation Method:
SM 4500-CN-E-2016
Pace Analytical Services -Asheville
Cyanide
ND ug/L 8.0 6.0
1
11/14/23 17:30 11/14/23 20:41
57-12-5
Date: 11/28/2023 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 41 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-16S
Lab ID:
92697334005
Collected:
11/07/23 13:33
Received: 11/07/23 17:05 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
Chlorinated Herb. (GC) 8151
Analytical
Method: EPA8151
Preparation
Method: 8151A
Pace National
- Mt. Juliet
2,4-D
ND
ug/L
2.00
0.547
1
11/13/23 11:59
11/14/23 12:31
94-75-7
2,4,5-T
ND
ug/L
2.00
0.258
1
11/13/23 11:59
11/14/23 12:31
93-76-5
2,4,5-TP (Silvex)
ND
ug/L
2.00
0.335
1
11/13/23 11:59
11/14/23 12:31
93-72-1
Dinoseb
ND
ug/L
2.00
0.250
1
11/13/23 11:59
11/14/23 12:31
88-85-7
Surrogates
2,4-DCAA (S)
107
%
14.0-158
1
11/13/23 11:59
11/14/23 12:31
19719-28-9
8081 OC Pesticides RVE
Analytical
Method: EPA 8081
B Preparation Method: EPA 3510C
Pace Analytical
Services
- Charlotte
Aldrin
ND
ug/L
0.042
0.012
1
11/09/23 10:05
11/10/23 15:28
309-00-2
alpha-BHC
ND
ug/L
0.042
0.010
1
11/09/23 10:05
11/10/23 15:28
319-84-6
beta-BHC
ND
ug/L
0.042
0.041
1
11/09/23 10:05
11/10/23 15:28
319-85-7
delta-BHC
ND
ug/L
0.042
0.012
1
11/09/23 10:05
11/10/23 15:28
319-86-8
gamma-BHC (Lindane)
ND
ug/L
0.042
0.010
1
11/09/23 10:05
11/10/23 15:28
58-89-9
Chlordane (Technical)
ND
ug/L
0.42
0.13
1
11/09/23 10:05
11/10/23 15:28
57-74-9
4,4'-DDD
ND
ug/L
0.042
0.014
1
11/09/23 10:05
11/10/23 15:28
72-54-8
4,4'-DDE
ND
ug/L
0.042
0.020
1
11/09/23 10:05
11/10/23 15:28
72-55-9
4,4'-DDT
ND
ug/L
0.042
0.022
1
11/09/23 10:05
11/10/23 15:28
50-29-3
Dieldrin
ND
ug/L
0.042
0.012
1
11/09/23 10:05
11/10/23 15:28
60-57-1
Endosulfan I
ND
ug/L
0.042
0.014
1
11/09/23 10:05
11/10/23 15:28
959-98-8
Endosulfan 11
ND
ug/L
0.042
0.013
1
11/09/23 10:05
11/10/23 15:28
33213-65-9
Endosulfan sulfate
ND
ug/L
0.042
0.012
1
11/09/23 10:05
11/10/23 15:28
1031-07-8
Endrin
ND
ug/L
0.042
0.015
1
11/09/23 10:05
11/10/23 15:28
72-20-8
Endrin aldehyde
ND
ug/L
0.042
0.014
1
11/09/23 10:05
11/10/23 15:28
7421-93-4
Heptachlor
ND
ug/L
0.042
0.016
1
11/09/23 10:05
11/10/23 15:28
76-44-8
Heptachlor epoxide
ND
ug/L
0.042
0.024
1
11/09/23 10:05
11/10/23 15:28
1024-57-3
Methoxychlor
ND
ug/L
0.12
0.035
1
11/09/23 10:05
11/10/23 15:28
72-43-5
Toxaphene
ND
ug/L
0.42
0.18
1
11/09/23 10:05
11/10/23 15:28
8001-35-2
Surrogates
Tetrachloro-m-xylene (S)
67
%
10-137
1
11/09/23 10:05
11/10/23 15:28
877-09-8
Decachlorobiphenyl (S)
55
%
19-200
1
11/09/23 10:05
11/10/23 15:28
2051-24-3
8082 GCS PCB RVE
Analytical
Method: EPA 8082A
Preparation Method:
EPA 3510C
Pace Analytical
Services
- Charlotte
PCB-1016 (Aroclor 1016)
ND
ug/L
0.42
0.18
1
11/22/23 11:11
11/27/23 07:32
12674-11-2
PCB-1221 (Aroclor 1221)
ND
ug/L
0.42
0.19
1
11/22/23 11:11
11/27/23 07:32
11104-28-2
PCB-1232 (Aroclor 1232)
ND
ug/L
0.42
0.19
1
11/22/23 11:11
11/27/23 07:32
11141-16-5
PCB-1242 (Aroclor 1242)
ND
ug/L
0.42
0.21
1
11/22/23 11:11
11/27/23 07:32
53469-21-9
PCB-1248 (Aroclor 1248)
ND
ug/L
0.42
0.24
1
11/22/23 11:11
11/27/23 07:32
12672-29-6
PCB-1254 (Aroclor 1254)
ND
ug/L
0.42
0.18
1
11/22/23 11:11
11/27/23 07:32
11097-69-1
PCB-1260 (Aroclor 1260)
ND
ug/L
0.42
0.13
1
11/22/23 11:11
11/27/23 07:32
11096-82-5
Surrogates
Decachlorobiphenyl (S)
133
%
10-193
1
11/22/23 11:11
11/27/23 07:32
2051-24-3
Date: 11/28/2023 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 42 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-16S
Lab ID:
92697334005
Collected:
11/07/23
13:33
Received: 11/07/23 17:05 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
6010 MET ICP
Analytical
Method: EPA 6010D
Preparation Method: EPA 3010A
Pace Analytical Services
-Asheville
Antimony
ND
ug/L
5.0
3.6
1
11/10/2312:00
11/13/2316:55
7440-36-0
Arsenic
ND
ug/L
10.0
2.5
1
11/10/2312:00
11/13/2316:55
7440-38-2
Barium
60.3
ug/L
5.0
0.79
1
11/10/2312:00
11/13/2316:55
7440-39-3
Beryllium
ND
ug/L
1.0
0.16
1
11/10/2312:00
11/13/2316:55
7440-41-7
Cadmium
ND
ug/L
1.0
0.29
1
11/10/2312:00
11/13/2316:55
7440-43-9
Chromium
3.7J
ug/L
5.0
0.63
1
11/10/2312:00
11/13/2316:55
7440-47-3
Cobalt
28.0
ug/L
5.0
0.44
1
11/10/2312:00
11/13/2316:55
7440-48-4
Copper
ND
ug/L
5.0
0.62
1
11/10/2312:00
11/13/2316:55
7440-50-8
Iron
39200
ug/L
50.0
8.9
1
11/10/2312:00
11/13/2316:55
7439-89-6
Lead
ND
ug/L
5.0
1.4
1
11/10/2312:00
11/13/2316:55
7439-92-1
Manganese
13700
ug/L
50.0
8.6
10
11/10/2312:00
11/21/2312:16
7439-96-5
Nickel
5.1
ug/L
5.0
0.88
1
11/10/2312:00
11/13/2316:55
7440-02-0
Selenium
ND
ug/L
10.0
4.1
1
11/10/2312:00
11/13/2316:55
7782-49-2
Silver
ND
ug/L
5.0
0.49
1
11/10/2312:00
11/13/2316:55
7440-22-4
Tin
ND
ug/L
5.0
2.0
1
11/10/2312:00
11/13/2316:55
7440-31-5
Vanadium
ND
ug/L
5.0
1.6
1
11/10/2312:00
11/13/2316:55
7440-62-2
Zinc
4.OJ
ug/L
10.0
3.0
1
11/10/2312:00
11/13/2316:55
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020E
Preparation Method: EPA 3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.20
0.050
1
11/10/2312:25
11/12/2319:56
7440-28-0
7470 Mercury
Analytical
Method: EPA 7470A Preparation Method:
EPA 7470A
Pace Analytical Services
-Asheville
Mercury
ND
ug/L
1.0
0.61
5
11/15/2316:59
11/18/2311:55
7439-97-6 D3
8270E APP9 RV
Analytical
Method: EPA 8270E
Preparation Method: EPA 3510C
Pace Analytical Services
- Charlotte
Acenaphthene
ND
ug/L
8.3
1.7
1
11/09/23 15:47
11/14/23 17:51
83-32-9
Acenaphthylene
ND
ug/L
8.3
1.6
1
11/09/23 15:47
11/14/23 17:51
208-96-8
Acetophenone
ND
ug/L
8.3
1.2
1
11/09/23 15:47
11/14/23 17:51
98-86-2
2-Acetylaminofluorene
ND
ug/L
8.3
3.4
1
11/09/23 15:47
11/14/23 17:51
53-96-3
4-Aminobiphenyl
ND
ug/L
8.3
4.0
1
11/09/23 15:47
11/14/23 17:51
92-67-1
Anthracene
ND
ug/L
8.3
1.9
1
11/09/23 15:47
11/14/23 17:51
120-12-7
Benzo(a)anthracene
ND
ug/L
8.3
2.2
1
11/09/23 15:47
11/14/23 17:51
56-55-3
Benzo(a)pyrene
ND
ug/L
8.3
2.3
1
11/09/23 15:47
11/14/23 17:51
50-32-8
Benzo(b)fluoranthene
ND
ug/L
8.3
2.2
1
11/09/23 15:47
11/14/23 17:51
205-99-2
Benzo(g,h,i)perylene
ND
ug/L
8.3
2.4
1
11/09/23 15:47
11/14/23 17:51
191-24-2
Benzo(k)fluoranthene
ND
ug/L
8.3
2.3
1
11/09/23 15:47
11/14/23 17:51
207-08-9
Benzyl alcohol
ND
ug/L
16.7
2.4
1
11/09/23 15:47
11/14/23 17:51
100-51-6
4-Bromophenylphenyl ether
ND
ug/L
8.3
1.5
1
11/09/23 15:47
11/14/23 17:51
101-55-3
Butylbenzylphthalate
ND
ug/L
8.3
2.6
1
11/09/23 15:47
11/14/23 17:51
85-68-7
4-ChIoro-3-methyl phenol
ND
ug/L
8.3
2.8
1
11/09/23 15:47
11/14/23 17:51
59-50-7
4-Chloroaniline
ND
ug/L
16.7
3.0
1
11/09/23 15:47
11/14/23 17:51
106-47-8
Chlorobenzilate
ND
ug/L
8.3
3.2
1
11/09/23 15:47
11/14/23 17:51
510-15-6
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except in
full,
Date: 11 /28/2023 02:34 PM
without the written consent of Pace Analytical Services, LLC.
Page 43 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-16S Lab ID: 92697334005 Collected: 11/07/23 13:33 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
bis(2-Chloroethoxy)methane
ND
ug/L
8.3
1.5
1
11/09/23 15:47
11/14/23 17:51
111-91-1
bis(2-Chloroethyl) ether
ND
ug/L
8.3
1.6
1
11/09/23 15:47
11/14/23 17:51
111-44-4
2-Chloronaphthalene
ND
ug/L
8.3
1.4
1
11/09/23 15:47
11/14/23 17:51
91-58-7
2-Chlorophenol
ND
ug/L
8.3
1.0
1
11/09/23 15:47
11/14/23 17:51
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
8.3
1.7
1
11/09/23 15:47
11/14/23 17:51
7005-72-3
Chrysene
ND
ug/L
8.3
2.3
1
11/09/23 15:47
11/14/23 17:51
218-01-9
Diallate
ND
ug/L
8.3
2.8
1
11/09/23 15:47
11/14/23 17:51
2303-16-4
Dibenz(a,h)anthracene
ND
ug/L
8.3
2.5
1
11/09/23 15:47
11/14/23 17:51
53-70-3
Dibenzofuran
ND
ug/L
8.3
1.8
1
11/09/23 15:47
11/14/23 17:51
132-64-9
3,3'-Dichlorobenzidine
ND
ug/L
16.7
6.8
1
11/09/23 15:47
11/14/23 17:51
91-94-1
2,4-Dichlorophenol
ND
ug/L
8.3
1.2
1
11/09/23 15:47
11/14/23 17:51
120-83-2
2,6-Dichlorophenol
ND
ug/L
8.3
3.5
1
11/09/23 15:47
11/14/23 17:51
87-65-0
Diethylphthalate
ND
ug/L
8.3
1.7
1
11/09/23 15:47
11/14/23 17:51
84-66-2
Dimethoate
ND
ug/L
8.3
3.0
1
11/09/23 15:47
11/14/23 17:51
60-51-5
P-Dimethylaminoazobenzene
ND
ug/L
4.2
2.0
1
11/09/23 15:47
11/14/23 17:51
60-11-7
7,12-Dimethylbenz(a)anthracene
ND
ug/L
8.3
2.5
1
11/09/23 15:47
11/14/23 17:51
57-97-6
3,3'-Dimethylbenzidine
ND
ug/L
41.7
25.9
1
11/09/23 15:47
11/14/23 17:51
119-93-7
2,4-Dimethylphenol
ND
ug/L
8.3
1.4
1
11/09/23 15:47
11/14/23 17:51
105-67-9
Dimethylphthalate
ND
ug/L
8.3
1.8
1
11/09/23 15:47
11/14/23 17:51
131-11-3
Di-n-butylphthalate
ND
ug/L
8.3
1.8
1
11/09/23 15:47
11/14/23 17:51
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
16.7
6.5
1
11/09/23 15:47
11/14/23 17:51
534-52-1
1,3-Dinitrobenzene
ND
ug/L
8.3
3.1
1
11/09/23 15:47
11/14/23 17:51
99-65-0
2,4-Dinitrophenol
ND
ug/L
41.7
21.7
1
11/09/23 15:47
11/14/23 17:51
51-28-5
2,4-Dinitrotoluene
ND
ug/L
8.3
1.4
1
11/09/23 15:47
11/14/23 17:51
121-14-2
2,6-Dinitrotoluene
ND
ug/L
8.3
1.4
1
11/09/23 15:47
11/14/23 17:51
606-20-2
Di-n-octylphthalate
ND
ug/L
8.3
3.3
1
11/09/23 15:47
11/14/23 17:51
117-84-0
Diphenylamine
ND
ug/L
8.3
2.5
1
11/09/23 15:47
11/14/23 17:51
122-39-4
Disulfoton
ND
ug/L
8.3
3.9
1
11/09/23 15:47
11/14/23 17:51
298-04-4
bis(2- Ethyl hexyl)phthalate
ND
ug/L
5.0
3.1
1
11/09/23 15:47
11/14/23 17:51
117-81-7
Ethyl methanesulfonate
ND
ug/L
16.7
2.5
1
11/09/23 15:47
11/14/23 17:51
62-50-0
Famphur
ND
ug/L
8.3
5.1
1
11/09/23 15:47
11/14/23 17:51
52-85-7
Fluoranthene
ND
ug/L
8.3
1.8
1
11/09/23 15:47
11/14/23 17:51
206-44-0
Fluorene
ND
ug/L
8.3
1.7
1
11/09/23 15:47
11/14/23 17:51
86-73-7
Hexachloro-1,3-butadiene
ND
ug/L
8.3
1.5
1
11/09/23 15:47
11/14/23 17:51
87-68-3
Hexachlorobenzene
ND
ug/L
8.3
1.8
1
11/09/23 15:47
11/14/23 17:51
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
8.3
1.3
1
11/09/23 15:47
11/14/23 17:51
77-47-4
Hexachloroethane
ND
ug/L
8.3
1.2
1
11/09/23 15:47
11/14/23 17:51
67-72-1
Hexachloropropene
ND
ug/L
8.3
2.2
1
11/09/23 15:47
11/14/23 17:51
1888-71-7
Indeno(1,2,3-cd)pyrene
ND
ug/L
8.3
2.4
1
11/09/23 15:47
11/14/23 17:51
193-39-5
Isodrin
ND
ug/L
8.3
2.3
1
11/09/23 15:47
11/14/23 17:51
465-73-6
Isophorone
ND
ug/L
8.3
1.4
1
11/09/23 15:47
11/14/23 17:51
78-59-1
Isosafrole
ND
ug/L
8.3
2.1
1
11/09/23 15:47
11/14/23 17:51
120-58-1
Kepone
ND
ug/L
16.7
11.8
1
11/09/23 15:47
11/14/23 17:51
143-50-0
Methapyrilene
ND
ug/L
41.7
14.2
1
11/09/23 15:47
11/14/23 17:51
91-80-5
3-Methylcholanthrene
ND
ug/L
8.3
3.1
1
11/09/23 15:47
11/14/23 17:51
56-49-5
REPORT OF LABORATORY ANALYSIS
L2,v2
v1
L2,v1
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-16S Lab ID: 92697334005 Collected: 11/07/23 13:33 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Methyl methanesulfonate
ND
ug/L
4.2
2.6
1
11/09/23 15:47
11/14/23 17:51
66-27-3
2-Methylnaphthalene
ND
ug/L
8.3
1.6
1
11/09/23 15:47
11/14/23 17:51
91-57-6
Methyl parathion
ND
ug/L
8.3
3.1
1
11/09/23 15:47
11/14/23 17:51
298-00-0
2-Methylphenol(o-Cresol)
ND
ug/L
8.3
1.6
1
11/09/23 15:47
11/14/23 17:51
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
8.3
1.0
1
11/09/23 15:47
11/14/23 17:51
15831-10-4
1-Naphthalenamine
ND
ug/L
8.3
5.0
1
11/09/23 15:47
11/14/23 17:51
134-32-7
2-Naphthalenamine
ND
ug/L
8.3
4.5
1
11/09/23 15:47
11/14/23 17:51
91-59-8
1,4-Naphthoquinone
ND
ug/L
4.2
3.7
1
11/09/23 15:47
11/14/23 17:51
130-15-4
2-Nitroaniline
ND
ug/L
16.7
2.5
1
11/09/23 15:47
11/14/23 17:51
88-74-4
3-Nitroaniline
ND
ug/L
16.7
3.1
1
11/09/23 15:47
11/14/23 17:51
99-09-2
4-Nitroaniline
ND
ug/L
16.7
4.2
1
11/09/23 15:47
11/14/23 17:51
100-01-6
Nitrobenzene
ND
ug/L
8.3
1.6
1
11/09/23 15:47
11/14/23 17:51
98-95-3
2-Nitrophenol
ND
ug/L
8.3
1.2
1
11/09/23 15:47
11/14/23 17:51
88-75-5
4-Nitrophenol
ND
ug/L
41.7
5.5
1
11/09/23 15:47
11/14/23 17:51
100-02-7
5-Nitro-o-toluidine
ND
ug/L
8.3
3.2
1
11/09/23 15:47
11/14/23 17:51
99-55-8
N-Nitrosodiethylamine
ND
ug/L
8.3
1.9
1
11/09/23 15:47
11/14/23 17:51
55-18-5
N-Nitrosodimethylamine
ND
ug/L
8.3
1.6
1
11/09/23 15:47
11/14/23 17:51
62-75-9
N-Nitroso-di-n-butylamine
ND
ug/L
8.3
1.6
1
11/09/23 15:47
11/14/23 17:51
924-16-3
N-Nitroso-di-n-propylamine
ND
ug/L
8.3
1.1
1
11/09/23 15:47
11/14/23 17:51
621-64-7
N-Nitrosodiphenylamine
ND
ug/L
8.3
2.5
1
11/09/23 15:47
11/14/23 17:51
86-30-6
N-Nitrosomethylethylamine
ND
ug/L
8.3
6.2
1
11/09/23 15:47
11/14/23 17:51
10595-95-6
N-Nitrosopiperidine
ND
ug/L
8.3
2.1
1
11/09/23 15:47
11/14/23 17:51
100-75-4
N-Nitrosopyrrolidine
ND
ug/L
8.3
2.6
1
11/09/23 15:47
11/14/23 17:51
930-55-2
O,O,O-Triethylphosphorothioate
ND
ug/L
8.3
2.1
1
11/09/23 15:47
11/14/23 17:51
126-68-1
2,2'-Oxybis(1-chloropropane)
ND
ug/L
8.3
0.96
1
11/09/23 15:47
11/14/23 17:51
108-60-1
Parathion (Ethyl parathion)
ND
ug/L
8.3
3.2
1
11/09/23 15:47
11/14/23 17:51
56-38-2
Pentachlorobenzene
ND
ug/L
8.3
2.8
1
11/09/23 15:47
11/14/23 17:51
608-93-5
Pentachloronitrobenzene
ND
ug/L
8.3
2.7
1
11/09/23 15:47
11/14/23 17:51
82-68-8
Pentachlorophenol
ND
ug/L
16.7
3.1
1
11/09/23 15:47
11/14/23 17:51
87-86-5
Phenacetin
ND
ug/L
8.3
3.0
1
11/09/23 15:47
11/14/23 17:51
62-44-2
Phenanthrene
ND
ug/L
8.3
1.7
1
11/09/23 15:47
11/14/23 17:51
85-01-8
Phenol
ND
ug/L
8.3
1.1
1
11/09/23 15:47
11/14/23 17:51
108-95-2
p-Phenylenediamine
ND
ug/L
8.3
8.3
1
11/09/23 15:47
11/14/23 17:51
106-50-3
Phorate
ND
ug/L
8.3
3.0
1
11/09/23 15:47
11/14/23 17:51
298-02-2
Pronamide
ND
ug/L
8.3
2.6
1
11/09/23 15:47
11/14/23 17:51
23950-58-5
Pyrene
ND
ug/L
8.3
1.8
1
11/09/23 15:47
11/14/23 17:51
129-00-0
Safrole
ND
ug/L
8.3
1.9
1
11/09/23 15:47
11/14/23 17:51
94-59-7
1,2,4,5-Tetrachlorobenzene
ND
ug/L
8.3
3.7
1
11/09/23 15:47
11/14/23 17:51
95-94-3
2,3,4,6-Tetrachlorophenol
ND
ug/L
8.3
1.3
1
11/09/23 15:47
11/14/23 17:51
58-90-2
Thionazin
ND
ug/L
8.3
2.4
1
11/09/23 15:47
11/14/23 17:51
297-97-2
O-Toluidine
ND
ug/L
8.3
2.2
1
11/09/23 15:47
11/14/23 17:51
95-53-4
2,4,5-Trichlorophenol
ND
ug/L
8.3
1.2
1
11/09/23 15:47
11/14/23 17:51
95-95-4
2,4,6-Trichlorophenol
ND
ug/L
8.3
1.3
1
11/09/23 15:47
11/14/23 17:51
88-06-2
1,3,5-Trinitrobenzene
ND
ug/L
8.3
4.6
1
11/09/23 15:47
11/14/23 17:51
99-35-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-16S Lab ID: 92697334005 Collected: 11/07/23 13:33 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Surrogates
Nitrobenzene-d5 (S)
83
%
10-133
1 11/09/23 15:47
11/14/23 17:51
4165-60-0
2-Fluorobiphenyl (S)
80
%
10-130
1 11/09/23 15:47
11/14/23 17:51
321-60-8
Terphenyl-d14 (S)
119
%
10-193
1 11/09/23 15:47
11/14/23 17:51
1718-51-0
Phenol-d6 (S)
22
%
10-130
1 11/09/23 15:47
11/14/23 17:51
13127-88-3
2-Fluorophenol (S)
6
%
10-130
1 11/09/23 15:47
11/14/23 17:51
367-12-4
SO
2,4,6-Tribromophenol (S)
18
%
10-166
1 11/09/23 15:47
11/14/23 17:51
118-79-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
11/10/23 19:46
67-64-1
Acetonitrile
ND
ug/L
50.0
24.8
1
11/10/23 19:46
75-05-8
Acrolein
ND
ug/L
10.0
8.5
1
11/10/23 19:46
107-02-8
AC,v1
Acrylonitrile
ND
ug/L
10.0
1.8
1
11/10/23 19:46
107-13-1
Allyl chloride
ND
ug/L
2.0
0.50
1
11/10/23 19:46
107-05-1
Benzene
3.0
ug/L
1.0
0.34
1
11/10/23 19:46
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
11/10/23 19:46
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
11/10/23 19:46
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
11/10/23 19:46
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
11/10/23 19:46
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
11/10/23 19:46
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
11/10/23 19:46
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
11/10/23 19:46
56-23-5
Chlorobenzene
1.0
ug/L
1.0
0.28
1
11/10/23 19:46
108-90-7
Chloroethane
4.5
ug/L
1.0
0.65
1
11/10/23 19:46
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
11/10/23 19:46
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
11/10/23 19:46
74-87-3
Chloroprene
ND
ug/L
5.0
1.6
1
11/10/23 19:46
126-99-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
11/10/23 19:46
124-48-1
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
11/10/23 19:46
95-50-1
1,3-Dichlorobenzene
ND
ug/L
1.0
0.34
1
11/10/23 19:46
541-73-1
1,4-Dichlorobenzene
7.8
ug/L
1.0
0.33
1
11/10/23 19:46
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
11/10/23 19:46
110-57-6
Dichlorodifluoromethane
ND
ug/L
1.0
0.35
1
11/10/23 19:46
75-71-8
IH,L1,
v1
1,1-Dichloroethane
11.9
ug/L
1.0
0.37
1
11/10/23 19:46
75-34-3
1,2-Dichloroethane
1.0
ug/L
1.0
0.32
1
11/10/23 19:46
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
11/10/23 19:46
75-35-4
cis-1,2-Dichloroethene
6.8
ug/L
1.0
0.38
1
11/10/23 19:46
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
11/10/23 19:46
156-60-5
1,3-Dichloropropane
ND
ug/L
1.0
0.28
1
11/10/23 19:46
142-28-9
2,2-Dichloropropane
ND
ug/L
1.0
0.39
1
11/10/23 19:46
594-20-7
1,1-Dichloropropene
ND
ug/L
1.0
0.43
1
11/10/23 19:46
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
11/10/23 19:46
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
11/10/23 19:46
10061-02-6
REPORT OF LABORATORY ANALYSIS
This report
shall not be reproduced,
except in full,
Date: 11 /28/2023 02:34 PM
without the written
consent of Pace
Analytical Services, LLC.
Page
46 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-16S Lab ID: 92697334005 Collected: 11/07/23 13:33 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Ethylbenzene
Ethyl methacrylate
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Methylene Chloride
Methyl methacrylate
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
2540C Total Dissolved Solids
Total Dissolved Solids
Date: 11/28/2023 02:34 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND ug/L
1.0
0.30
1
11/10/2319:46
100-41-4
ND ug/L
1.0
0.28
1
11/10/2319:46
97-63-2
ND ug/L
2.0
1.5
1
11/10/2319:46
87-68-3
ND ug/L
5.0
0.48
1
11/10/2319:46
591-78-6
ND ug/L
20.0
9.7
1
11/10/2319:46
74-88-4
ND ug/L
100
52.3
1
11/10/2319:46
78-83-1
ND ug/L
10.0
4.2
1
11/10/2319:46
126-98-7
ND ug/L
5.0
2.0
1
11/10/2319:46
75-09-2
ND ug/L
2.0
0.32
1
11/10/2319:46
80-62-6
ND ug/L
1.0
0.64
1
11/10/2319:46
91-20-3
ND ug/L
20.0
3.6
1
11/10/2319:46
107-12-0
ND ug/L
1.0
0.29
1
11/10/2319:46
100-42-5
ND ug/L
1.0
0.31
1
11/10/2319:46
630-20-6
ND ug/L
1.0
0.22
1
11/10/2319:46
79-34-5
ND ug/L
1.0
0.29
1
11/10/2319:46
127-18-4
ND ug/L
1.0
0.24
1
11/10/2319:46
108-88-3
ND ug/L
1.0
0.64
1
11/10/2319:46
120-82-1
ND ug/L
1.0
0.33
1
11/10/2319:46
71-55-6
ND ug/L
1.0
0.32
1
11/10/2319:46
79-00-5
0.43J ug/L
1.0
0.38
1
11/10/2319:46
79-01-6
ND ug/L
1.0
0.30
1
11/10/2319:46
75-69-4
ND ug/L
1.0
0.26
1
11/10/2319:46
96-18-4
ND ug/L
2.0
1.3
1
11/10/2319:46
108-05-4
1.0 ug/L
1.0
0.39
1
11/10/2319:46
75-01-4
ND ug/L
1.0
0.34
1
11/10/2319:46
1330-20-7
98 %
70-130
1
11/10/2319:46
460-00-4
91 %
70-130
1
11/10/2319:46
17060-07-0
106 %
70-130
1
11/10/2319:46
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
13.3 ug/L
2.0
0.86
1
11/10/23 05:22
123-91-1
90 %
67-130
1
11/10/23 05:22
17060-07-0
91 %
70-130
1
11/10/23 05:22
2037-26-5
Analytical Method: SM 2320B-2011
Pace Analytical Services
-Asheville
136 mg/L
5.0
5.0
1
11/15/23 20:13
Analytical Method: SM 2540C-2015
Pace Analytical Services
-Asheville
16.5 mg/L
2.5
2.5
1
11/09/2310:48
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 47 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-16S
Lab ID: 92697334005 Collected: 11/07/23 13:33
Received: 11/07/23 17:05 Matrix: Water
Report
Parameters
Results Units Limit MDL
DF
Prepared Analyzed
CAS No. Qual
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
Sulfide
ND ug/L 100 22.0
1
11/09/23 05:43
18496-25-8
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
Chloride
13.0 mg/L 1.0 0.60
1
11/10/23 01:00
16887-00-6
Sulfate
1.1 mg/L 1.0 0.50
1
11/10/23 01:00
14808-79-8
4500CNE Cyanide, Total
Analytical Method: SM 4500-CN-E-2016 Preparation Method:
SM 4500-CN-E-2016
Pace Analytical Services -Asheville
Cyanide
ND ug/L 8.0 6.0
1
11/14/23 17:30 11/14/23 20:42
57-12-5
Date: 11/28/2023 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 48 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-10
Parameters
Lab ID: 92697337001 Collected:
Report
Results Units Limit
11/07/23 14:44
MDL DF
Received: 11/07/23 17:05 Matrix: Water
Prepared Analyzed CAS No. Qual
353.2 NO2/NO3 unpres EDN
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services - Eden
Nitrogen, Nitrate
0.046 mg/L 0.040
0.029
1
11/08/23 09:23
14797-55-8
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
647 ug/L 10.0
5.3
1
11/09/2315:51
74-82-8
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
0.73J mg/L 1.0
0.50
1
11/17/23 07:03
7440-44-0
Date: 11/28/2023 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 49 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-11
Parameters
Lab ID: 92697337002 Collected:
Report
Results Units Limit
11/06/23 13:52
MDL DF
Received: 11/07/23 17:05 Matrix: Water
Prepared Analyzed CAS No. Qual
353.2 NO2/NO3 unpres EDN
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services - Eden
Nitrogen, Nitrate
ND mg/L 0.040
0.029
1
11/08/23 09:15
14797-55-8
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
2820 ug/L 10.0
5.3
1
11/09/2316:07
74-82-8
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
7.8 mg/L 1.0
0.50
1
11/17/23 07:23
7440-44-0
Date: 11/28/2023 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 50 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-12
Lab ID: 92697337003 Collected:
11/06/23
15:49
Received: 11/07/23 17:05 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
353.2 NO2/NO3 unpres EDN
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services - Eden
Nitrogen, Nitrate
0.052 mg/L 0.040
0.029
1
11/08/23 09:25
14797-55-8
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
5920 ug/L 10.0
5.3
1
11/09/2316:52
74-82-8 D6
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
1.5 mg/L 1.0
0.50
1
11/17/23 07:44
7440-44-0
Date: 11/28/2023 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 51 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-16S
Parameters
Lab ID: 92697337004 Collected:
Report
Results Units Limit
11/07/23 13:33
MDL DF
Received: 11/07/23 17:05 Matrix: Water
Prepared Analyzed CAS No. Qual
353.2 NO2/NO3 unpres EDN
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services - Eden
Nitrogen, Nitrate
0.076 mg/L 0.040
0.029
1
11/08/23 09:24
14797-55-8
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
3870 ug/L 10.0
5.3
1
11/09/2317:08
74-82-8
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
1.6 mg/L 1.0
0.50
1
11/17/23 08:03
7440-44-0
Date: 11/28/2023 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 52 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-18 Lab ID: 92697337006 Collected: 11/07/23 10:14 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
353.2 NO2/NO3 unpres EDN
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Eden
Nitrogen, Nitrate
ND mg/L 0.040 0.029
1
11/08/23 09:16
14797-55-8
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
2690 ug/L 10.0 5.3
1
11/09/2317:40
74-82-8
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
Cobalt
9.4J ug/L 10.0 0.96
1 11/16/23 03:53
11/16/23 15:55
7440-48-4
Iron
102000 ug/L 400 250
10 11/16/23 03:53
11/17/23 03:34
7439-89-6
Manganese
6600 ug/L 50.0 11.0
10 11/16/23 03:53
11/17/23 03:34
7439-96-5
6020 MET ICPMS
Analytical Method: EPA 6020 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
Thallium
0.25J ug/L 1.0 0.11
1 11/16/23 03:53
11/16/23 17:24
7440-28-0
7470 Mercury
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Pace Analytical Services - Ormond Beach
Mercury
ND ug/L 0.20 0.14
1 11/16/23 09:28
11/16/23 14:33
7439-97-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Benzene
ND ug/L 1.0 0.34
1
11/10/23 20:04
71-43-2
1,4-Dichlorobenzene
ND ug/L 1.0 0.33
1
11/10/23 20:04
106-46-7
1,1-Dichloroethane
ND ug/L 1.0 0.37
1
11/10/23 20:04
75-34-3
1,2-Dichloroethane
ND ug/L 1.0 0.32
1
11/10/23 20:04
107-06-2
Methylene Chloride
ND ug/L 5.0 2.0
1
11/10/23 20:04
75-09-2
Tetrachloroethene
ND ug/L 1.0 0.29
1
11/10/23 20:04
127-18-4
Trichloroethene
ND ug/L 1.0 0.38
1
11/10/23 20:04
79-01-6
Vinyl chloride
0.61J ug/L 1.0 0.39
1
11/10/23 20:04
75-01-4
Surrogates
4-Bromofluorobenzene (S)
98 % 70-130
1
11/10/23 20:04
460-00-4
1,2-Dichloroethane-d4 (S)
90 % 70-130
1
11/10/23 20:04
17060-07-0
Toluene-d8 (S)
105 % 70-130
1
11/10/23 20:04
2037-26-5
8260D MSV SIM
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
1,4-Dioxane (p-Dioxane)
3.8 ug/L 2.0 0.86
1
11/10/23 12:10
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
91 % 67-130
1
11/10/23 12:10
17060-07-0
Toluene-d8 (S)
89 % 70-130
1
11/10/23 12:10
2037-26-5
REPORT OF LABORATORY ANALYSIS
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Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 53 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-18
Lab ID: 92697337006 Collected:
11/07/23 10:14
Received: 11/07/23 17:05 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared Analyzed CAS No. Qual
2320B Alkalinity
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
Alkalinity, Total as CaCO3
114 mg/L 5.0
5.0
1
11/15/23 20:46 M1
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
14.2 mg/L 2.5
2.5
1
11/09/23 10:48
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
Sulfide
ND mg/L 0.10
0.022
1
11/09/23 05:45 18496-25-8
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1
1993
Pace Analytical Services -Asheville
Chloride
Sulfate
5310B TOC
Total Organic Carbon
Date: 11/28/2023 02:34 PM
11.8 mg/L 1.0 0.60 1 11/10/23 01:14 16887-00-6
0.54J mg/L 1.0 0.50 1 11/10/23 01:14 14808-79-8 M1
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
3.0 mg/L 1.0 0.50 1 11/20/2312:39 7440-44-0
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 54 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-19 Lab ID: 92697337007 Collected: 11/07/23 11:55 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
353.2 NO2/NO3 unpres EDN
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Eden
Nitrogen, Nitrate
ND mg/L 0.040 0.029
1
11/08/23 09:22
14797-55-8
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
2240 ug/L 10.0 5.3
1
11/09/2317:56
74-82-8
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
Cobalt
25.3 ug/L 10.0 0.96
1 11/16/23 03:53
11/16/23 15:59
7440-48-4
Iron
62500 ug/L 200 125
5 11/16/23 03:53
11/17/23 03:37
7439-89-6
Manganese
14700 ug/L 100 22.0
20 11/16/23 03:53
11/17/23 03:41
7439-96-5
6020 MET ICPMS
Analytical Method: EPA 6020 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
Thallium
ND ug/L 1.0 0.11
1 11/16/23 03:53
11/16/23 17:27
7440-28-0
7470 Mercury
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Pace Analytical Services - Ormond Beach
Mercury
ND ug/L 0.20 0.14
1 11/16/23 09:28
11/16/23 15:24
7439-97-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Benzene
ND ug/L 1.0 0.34
1
11/11/23 13:39
71-43-2
1,4-Dichlorobenzene
ND ug/L 1.0 0.33
1
11/11/23 13:39
106-46-7
1,1-Dichloroethane
0.54J ug/L 1.0 0.37
1
11/11/23 13:39
75-34-3
1,2-Dichloroethane
ND ug/L 1.0 0.32
1
11/11/23 13:39
107-06-2
Methylene Chloride
ND ug/L 5.0 2.0
1
11/11/23 13:39
75-09-2
Tetrachloroethene
ND ug/L 1.0 0.29
1
11/11/23 13:39
127-18-4
Trichloroethene
ND ug/L 1.0 0.38
1
11/11/23 13:39
79-01-6
Vinyl chloride
ND ug/L 1.0 0.39
1
11/11/23 13:39
75-01-4
Surrogates
4-Bromofluorobenzene (S)
97 % 70-130
1
11/11/23 13:39
460-00-4
1,2-Dichloroethane-d4 (S)
93 % 70-130
1
11/11/23 13:39
17060-07-0
Toluene-d8 (S)
105 % 70-130
1
11/11/23 13:39
2037-26-5
8260D MSV SIM
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
1,4-Dioxane (p-Dioxane)
ND ug/L 2.0 0.86
1
11/10/23 12:32
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
88 % 67-130
1
11/10/23 12:32
17060-07-0
Toluene-d8 (S)
90 % 70-130
1
11/10/23 12:32
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 55 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-19
Lab ID: 92697337007 Collected:
11/07/23 11:55
Received: 11/07/23 17:05 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
2320B Alkalinity
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
Alkalinity, Total as CaCO3
176 mg/L 5.0
5.0
1
11/15/23 21:13
M1
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
20.3 mg/L 2.5
2.5
1
11/09/23 10:48
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
Sulfide
0.031J mg/L 0.10
0.022
1
11/09/23 05:45
18496-25-8
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1
1993
Pace Analytical Services -Asheville
Chloride
1.5 mg/L 1.0
0.60
1
11/10/23 01:58
16887-00-6
Sulfate
2.4 mg/L 1.0
0.50
1
11/10/23 01:58
14808-79-8
5310B TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
4.3 mg/L 1.0
0.50
1
11/20/23 13:02
7440-44-0
Date: 11/28/2023 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 56 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-19 Lab ID: 92697351002 Collected: 11/07/23 11:55 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
BR Hydrogen by AM20 in Vapor Analytical Method: AM20
Pace Analytical Services - Baton Rouge
Hydrogen 3.0 nMoles 1.9 0.49 1 11/14/23 09:13 1333-74-0
Date: 11/28/2023 02:34 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 57 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-18 Lab ID: 92697351003 Collected: 11/07/23 10:14 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
BR Hydrogen by AM20 in Vapor Analytical Method: AM20
Pace Analytical Services - Baton Rouge
Hydrogen 1.6J nMoles 1.9 0.49 1 11/14/23 09:25 1333-74-0
Date: 11/28/2023 02:34 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 58 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-11 Lab ID: 92697351004 Collected: 11/06/23 13:52 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
BR Hydrogen by AM20 in Vapor Analytical Method: AM20
Pace Analytical Services - Baton Rouge
Hydrogen ND nMoles 1.9 0.49 1 11/14/23 09:39 1333-74-0
Date: 11/28/2023 02:34 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 59 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-12 Lab ID: 92697351005 Collected: 11/06/23 15:49 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
BR Hydrogen by AM20 in Vapor Analytical Method: AM20
Pace Analytical Services - Baton Rouge
Hydrogen 1.4J nMoles 1.9 0.49 1 11/14/23 09:56 1333-74-0
Date: 11/28/2023 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 60 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-16S Lab ID: 92697351006 Collected: 11/07/23 13:33 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
BR Hydrogen by AM20 in Vapor Analytical Method: AM20
Pace Analytical Services - Baton Rouge
Hydrogen 5.3 nMoles 1.9 0.49 1 11/14/2311:00 1333-74-0
Date: 11/28/2023 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 61 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
Sample: 1203-MW-36 Lab ID: 92698172001 Collected: 11/08/23 09:12 Received: 11/10/23 09:45 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
6010 MET ICP
Cobalt
Iron
Manganese
6020 MET ICPMS
Thallium
7470 Mercury
Mercury
8260D MSV Low Level Landfill
Benzene
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
Methylene Chloride
Tetrachloroethene
Trichloroethene
Vinyl chloride
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 11/28/2023 02:34 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
3470 ug/L 10.0 5.3
1
11/14/2317:57
74-82-8
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
34.0 ug/L 10.0 0.96
1 11/18/23 00:45
11/21/23 09:42
7440-48-4
22500 ug/L 40.0 25.0
1 11/18/23 00:45
11/21/23 09:42
7439-89-6
2250 ug/L 25.0 5.5
5 11/18/23 00:45
11/22/23 01:53
7439-96-5
Analytical Method: EPA 6020 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
ND ug/L 1.0 0.11
1 11/18/23 00:45
11/20/23 20:45
7440-28-0
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Pace Analytical Services - Ormond Beach
ND ug/L 0.20 0.14
1 11 /27/23 10:19
11 /27/23 15:03
7439-97-6
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
3.4 ug/L 1.0 0.34
1
11/16/23 01:21
71-43-2
19.0 ug/L 1.0 0.33
1
11/16/23 01:21
106-46-7
1.3 ug/L 1.0 0.37
1
11/16/23 01:21
75-34-3
ND ug/L 1.0 0.32
1
11/16/23 01:21
107-06-2
ND ug/L 5.0 2.0
1
11/16/23 01:21
75-09-2
1.0 ug/L 1.0 0.29
1
11/16/23 01:21
127-18-4
1.6 ug/L 1.0 0.38
1
11/16/23 01:21
79-01-6
0.60J ug/L 1.0 0.39
1
11/16/23 01:21
75-01-4
97 % 70-130
1
11/16/23 01:21
460-00-4
93 % 70-130
1
11/16/23 01:21
17060-07-0
101 % 70-130
1
11/16/23 01:21
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 62 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 307943 Analysis Method: AM20
QC Batch Method: AM20 Analysis Description: BR Hydrogen by AM20 in Vapor
Laboratory: Pace Analytical Services - Baton Rouge
Associated Lab Samples: 92697351002, 92697351003, 92697351004, 92697351005, 92697351006
METHOD BLANK: 1473991 Matrix: Air
Associated Lab Samples: 92697351002, 92697351003, 92697351004, 92697351005, 92697351006
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Hydrogen nMoles ND 1.9 0.49 11/14/23 08:48
LABORATORY CONTROL SAMPLE & LCSD: 1473993 1473992
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers
Hydrogen nMoles 11.9 12.6 12.2 102 70-130 4 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 63 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 811687 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. EDN
Laboratory: Pace Analytical Services - Eden
Associated Lab Samples: 92697337001, 92697337002, 92697337003, 92697337004, 92697337006, 92697337007
METHOD BLANK: 4202489 Matrix: Water
Associated Lab Samples: 92697337001, 92697337002, 92697337003, 92697337004, 92697337006, 92697337007
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Nitrogen, Nitrate mg/L ND 0.040 0.029 11/08/23 09:06
LABORATORY CONTROL SAMPLE: 4202490
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L 1.5 1.5 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4202789 4202790
MS MSD
92697337005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L 0.15 1.5 1.5 1.6 1.7 99 101 90-110 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4205693 4205694
MS MSD
92697827012 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L 0.087 1.5 1.5 1.6 1.6 102 100 90-110 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 64 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 2169599 Analysis Method: EPA 8151
QC Batch Method: 8151A Analysis Description: Chlorinated Herb. (GC) 8151
Laboratory: Pace National - Mt. Juliet
Associated Lab Samples: 92697334001, 92697334002, 92697334003, 92697334004, 92697334005
METHOD BLANK: R3999739-1
Matrix:
Water
Associated Lab Samples:
92697334001, 92697334002, 92697334003, 92697334004, 92697334005
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
2,4-D
ug/L
ND
2.00
0.547
11/14/23 04:08
2,4,5-T
ug/L
ND
2.00
0.258
11/14/23 04:08
2,4,5-TP (Silvex)
ug/L
ND
2.00
0.335
11/14/23 04:08
Dinoseb
ug/L
ND
2.00
0.250
11/14/23 04:08
2,4-DCAA (S)
%
71.8
14.0-158
11/14/23 04:08
LABORATORY CONTROL SAMPLE:
R3999739-2
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
2,4-D
ug/L
5.00
5.31
106
50.0-120 E
2,4,5-T
ug/L
5.00
5.10
102
54.0-120 E
2,4,5-TP (Silvex)
ug/L
5.00
4.36
87.2
50.0-125
Dinoseb
ug/L
5.00
6.48
130
36.0-134 E
2,4-DCAA (S)
%
78.6
14.0-158
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: R3999739-3
R3999739-4
MS
MSD
L1676413-07
Spike
Spike
MS
MSD
MS
MSD % Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec Limits
RPD
RPD Qual
2,4-D
ug/L
ND
4.76
4.76
4.84
4.93
102
104 50.0-120
1.84
20 E
2,4,5-T
ug/L
ND
4.76
4.76
4.56
4.51
95.8
94.7 54.0-120
1.10
20
2,4,5-TP (Silvex)
ug/L
ND
4.76
4.76
4.38
3.64
92.0
76.5 50.0-125
18.5
20
Dinoseb
ug/L
ND
4.76
4.76
5.14
5.10
108
107 36.0-134
0.781
20 E
2,4-DCAA (S)
%
72.5
75.0 14.0-158
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 65 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 812107 Analysis Method: RSK 175 Modified
QC Batch Method: RSK 175 Modified Analysis Description: RSK 175 HEADSPACE
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92697337001, 92697337002, 92697337003, 92697337004, 92697337006, 92697337007
METHOD BLANK: 4204821
Matrix:
Water
Associated Lab Samples: 92697337001, 92697337002, 92697337003, 92697337004, 92697337006, 92697337007
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Methane
ug/L
5.3J
10.0
5.3 11/09/2313:29
LABORATORY CONTROL SAMPLE:
4204822
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Methane
ug/L
297
276 93
70-130
MATRIX SPIKE SAMPLE: 4204824
92697583002 Spike MS MS % Rec
Parameter Units Result Conc. Result % Rec Limits Qualifiers
Methane ug/L 8570 297 5500 -1030 70-130 H1,M1
SAMPLE DUPLICATE: 4204823
92697583001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Methane ug/L 9070 5820 44 20 D6,H1,R2
SAMPLE DUPLICATE: 4204825
92697337003 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Methane ug/L 5920 3690 46 20 D6,H1,R2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 66 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 813082 Analysis Method: RSK 175 Modified
QC Batch Method: RSK 175 Modified Analysis Description: RSK 175 HEADSPACE
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92698172001
METHOD BLANK: 4209765
Associated Lab Samples: 92698172001
Parameter
Units
Methane
ug/L
LABORATORY CONTROL SAMPLE:
4209766
Parameter
Units
Methane
ug/L
MATRIX SPIKE SAMPLE:
4209768
Parameter
Units
Methane
ug/L
Matrix: Water
Blank Reporting
Result Limit MDL Analyzed Qualifiers
ND 10.0 5.3 11/14/2313:49
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
297 208 70 70-130
92698163002 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
365 297 571 69 70-130 M1
SAMPLE DUPLICATE: 4209767
92698163001 Dup
Parameter Units Result Result
Methane ug/L 87.4 78.9
SAMPLE DUPLICATE: 4209769
92697869001 Dup
Parameter Units Result Result
Methane ug/L 658 707
Max
RPD RPD Qualifiers
10 20
Max
RPD RPD Qualifiers
7 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 67 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 966882 Analysis Method: EPA 7470
QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 92697337006, 92697337007
METHOD BLANK: 5319171 Matrix: Water
Associated Lab Samples: 92697337006, 92697337007
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Mercury ug/L 0.15J 0.20 0.14 11/16/2314:28
LABORATORY CONTROL SAMPLE: 5319172
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 2 1.9 96 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 5319173 5319174
MS MSD
92697337006 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND 2 2 1.6 1.6 76 76 75-125 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 68 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 968880 Analysis Method: EPA 7470
QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 92698172001
METHOD BLANK: 5329267
Matrix:
Water
Associated Lab Samples: 92698172001
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Mercury
ug/L
ND
0.20
0.14 11/27/2314:27
LABORATORY CONTROL SAMPLE:
5329268
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Mercury
ug/L
2
1.8 90
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 5329269 5329270
MS MSD
35840531002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L 0.14U 2 2 2.0 1.9 100 96 75-125 5 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 69 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 813388 Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697334001, 92697334002, 92697334003, 92697334004, 92697334005
METHOD BLANK: 4211213 Matrix: Water
Associated Lab Samples: 92697334001, 92697334002, 92697334003, 92697334004, 92697334005
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Mercury ug/L ND 0.20 0.12 11/18/2311:33
LABORATORY CONTROL SAMPLE: 4211214
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 2.5 2.6 104 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4211215 4211216
MS MSD
92697367021 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND 2.5 2.5 2.5 2.5 101 101 75-125 1 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 70 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 812399 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697334001, 92697334002, 92697334003, 92697334004, 92697334005
METHOD BLANK: 4206419
Matrix:
Water
Associated Lab Samples: 92697334001, 92697334002, 92697334003,
92697334004, 92697334005
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
Antimony
ug/L
ND
5.0
3.6
11/13/2316:04
Arsenic
ug/L
ND
10.0
2.5
11/13/2316:04
Barium
ug/L
ND
5.0
0.79
11/13/2316:04
Beryllium
ug/L
ND
1.0
0.16
11/13/2316:04
Cadmium
ug/L
ND
1.0
0.29
11/13/2316:04
Chromium
ug/L
ND
5.0
0.63
11/13/2316:04
Cobalt
ug/L
ND
5.0
0.44
11/13/2316:04
Copper
ug/L
ND
5.0
0.62
11/13/2316:04
Iron
ug/L
ND
50.0
8.9
11/13/2316:04
Lead
ug/L
ND
5.0
1.4
11/13/2316:04
Manganese
ug/L
ND
5.0
0.86
11/13/2316:04
Nickel
ug/L
ND
5.0
0.88
11/13/2316:04
Selenium
ug/L
ND
10.0
4.1
11/13/2316:04
Silver
ug/L
ND
5.0
0.49
11/13/2316:04
Tin
ug/L
ND
5.0
2.0
11/13/2316:04
Vanadium
ug/L
ND
5.0
1.6
11/13/2316:04
Zinc
ug/L
ND
10.0
3.0
11/13/2316:04
LABORATORY CONTROL SAMPLE:
4206420
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Antimony
ug/L
500
485
97
80-120
Arsenic
ug/L
500
502
100
80-120
Barium
ug/L
500
492
98
80-120
Beryllium
ug/L
500
483
97
80-120
Cadmium
ug/L
500
503
101
80-120
Chromium
ug/L
500
483
97
80-120
Cobalt
ug/L
500
489
98
80-120
Copper
ug/L
500
481
96
80-120
Iron
ug/L
5000
4860
97
80-120
Lead
ug/L
500
491
98
80-120
Manganese
ug/L
500
497
99
80-120
Nickel
ug/L
500
495
99
80-120
Selenium
ug/L
500
475
95
80-120
Silver
ug/L
250
236
95
80-120
Tin
ug/L
500
498
100
80-120
Vanadium
ug/L
500
498
100
80-120
Zinc
ug/L
500
504
101
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 71 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
MATRIX SPIKE & MATRIX
SPIKE DUPLICATE: 4206421
4206422
MS
MSD
92697057001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
500
500
519
519
104
104
75-125
0
20
Arsenic
ug/L
ND
500
500
539
546
108
109
75-125
1
20
Barium
ug/L
85.6
500
500
617
619
106
107
75-125
0
20
Beryllium
ug/L
ND
500
500
521
523
104
105
75-125
0
20
Cadmium
ug/L
ND
500
500
533
535
107
107
75-125
0
20
Chromium
ug/L
3.3J
500
500
511
514
102
102
75-125
0
20
Cobalt
ug/L
48.2
500
500
562
565
103
103
75-125
1
20
Copper
ug/L
14.0
500
500
520
521
101
101
75-125
0
20
Iron
ug/L
4310
5000
5000
10700
10600
127
126
75-125
0
20 M1
Lead
ug/L
ND
500
500
512
514
102
103
75-125
0
20
Manganese
ug/L
1200
500
500
1800
1760
121
113
75-125
2
20
Nickel
ug/L
20.0
500
500
543
545
105
105
75-125
0
20
Selenium
ug/L
ND
500
500
529
530
106
106
75-125
0
20
Silver
ug/L
ND
250
250
249
250
99
100
75-125
1
20
Tin
ug/L
ND
500
500
534
539
107
108
75-125
1
20
Vanadium
ug/L
5.5
500
500
534
537
106
106
75-125
1
20
Zinc
ug/L
108
500
500
649
651
108
109
75-125
0
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 72 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 966774 Analysis Method: EPA 6010
QC Batch Method: EPA 3010 Analysis Description: 6010 MET
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 92697337006, 92697337007
METHOD BLANK: 5318818
Matrix:
Water
Associated Lab Samples: 92697337006, 92697337007
Blank
Reporting
Parameter Units
Result
Limit
MDL Analyzed Qualifiers
Cobalt ug/L
ND
10.0
0.96 11/16/2315:40
Iron ug/L
ND
40.0
25.0 11/16/2315:40
Manganese ug/L
ND
5.0
1.1 11/16/2315:40
LABORATORY CONTROL SAMPLE:
5318819
Spike
LCS LCS % Rec
Parameter
Units
Conc.
Result % Rec Limits Qualifiers
Cobalt
ug/L
250
250 100 80-120
Iron
ug/L
2500
2470 99 80-120
Manganese
ug/L
250
244 98 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 5318820
5318821
MS
MSD
92697346007
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD RPD Qual
Cobalt ug/L
ND
250
250
252
252
100
100
75-125
0 20
Iron ug/L
366
2500
2500
2900
2870
101
100
75-125
1 20
Manganese ug/L
75.3
250
250
316
313
96
95
75-125
1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 73 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 967448 Analysis Method: EPA 6010
QC Batch Method: EPA 3010 Analysis Description: 6010 MET
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 92698172001
METHOD BLANK: 5322429
Matrix:
Water
Associated Lab Samples: 92698172001
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
Cobalt
ug/L
ND
10.0
0.96 11/21/23 08:00
Iron
ug/L
ND
40.0
25.0 11/21/23 08:00
Manganese
ug/L
ND
5.0
1.1 11/21/23 08:00
LABORATORY CONTROL SAMPLE:
5322430
Spike
LCS LCS % Rec
Parameter
Units
Conc.
Result % Rec Limits Qualifiers
Cobalt
ug/L
250
254 102 80-120
Iron
ug/L
2500
2510 101 80-120
Manganese
ug/L
250
251 101 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 5322431
5322432
MS
MSD
35840556002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD RPD Qual
Cobalt ug/L
0.96U
250
250
254
253
101
101
75-125
0 20
Iron ug/L
10800
2500
2500
13400
13200
102
94
75-125
2 20
Manganese ug/L
32.4
250
250
282
280
100
99
75-125
1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 74 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 812425 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697334001, 92697334002, 92697334003, 92697334004, 92697334005
METHOD BLANK: 4206546 Matrix: Water
Associated Lab Samples: 92697334001, 92697334002, 92697334003, 92697334004, 92697334005
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Thallium ug/L ND 0.20 0.050 11/12/2318:46
LABORATORY CONTROL SAMPLE: 4206547
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Thallium ug/L 25 25.2 101 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4206548 4206549
MS MSD
92697334001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Thallium ug/L 0.49 25 25 26.7 26.4 105 104 75-125 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 75 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 966773 Analysis Method: EPA 6020
QC Batch Method: EPA 3010 Analysis Description: 6020 MET
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 92697337006, 92697337007
METHOD BLANK: 5318814 Matrix: Water
Associated Lab Samples: 92697337006, 92697337007
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Thallium ug/L ND 1.0 0.11 11/16/2316:50
LABORATORY CONTROL SAMPLE: 5318815
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Thallium ug/L 50 52.2 104 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 5318816 5318817
MS MSD
35840730004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Thallium ug/L 0.36J 50 50 52.6 52.5 104 104 75-125 0 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 76 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 967447 Analysis Method: EPA 6020
QC Batch Method: EPA 3010 Analysis Description: 6020 MET
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 92698172001
METHOD BLANK: 5322425
Matrix:
Water
Associated Lab Samples: 92698172001
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Thallium
ug/L
ND
1.0 0.11
11/20/2318:22
LABORATORY CONTROL SAMPLE:
5322426
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Thallium
ug/L
50
49.0 98
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 5322427 5322428
MS MSD
35840475001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Thallium ug/L 0.11 U 50 50 47.5 47.0 95 94 75-125 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 77 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 812462 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92697334001, 92697334002, 92697334003, 92697334004
METHOD BLANK: 4206813 Matrix: Water
Associated Lab Samples: 92697334001, 92697334002, 92697334003, 92697334004
Blank Reporting
Parameter Units Result Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
11/11/23 04:12
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
11/11/23 04:12
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
11/11/23 04:12
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
11/11/23 04:12
1,1-Dichloroethane
ug/L
ND
1.0
0.37
11/11/23 04:12
1,1-Dichloroethene
ug/L
ND
1.0
0.35
11/11/23 04:12
1,1-Dichloropropene
ug/L
ND
1.0
0.43
11/11/23 04:12
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
11/11/23 04:12
1,2,4-Trichlorobenzene
ug/L
ND
1.0
0.64
11/11/23 04:12
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
11/11/23 04:12
1,2-Dichloroethane
ug/L
ND
1.0
0.32
11/11/23 04:12
1,3-Dichlorobenzene
ug/L
ND
1.0
0.34
11/11/23 04:12
1,3-Dichloropropane
ug/L
ND
1.0
0.28
11/11/23 04:12
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
11/11/23 04:12
2,2-Dichloropropane
ug/L
ND
1.0
0.39
11/11/23 04:12
2-Butanone (MEK)
ug/L
ND
5.0
4.0
11/11/23 04:12
2-Hexanone
ug/L
ND
5.0
0.48
11/11/23 04:12
Acetone
ug/L
ND
25.0
5.1
11/11/23 04:12
Acetonitrile
ug/L
ND
50.0
24.8
11/11/23 04:12
Acrolein
ug/L
ND
10.0
8.5
11/11/23 04:12
Acrylonitrile
ug/L
ND
10.0
1.8
11/11/23 04:12
Allyl chloride
ug/L
ND
2.0
0.50
11/11/23 04:12
Benzene
ug/L
ND
1.0
0.34
11/11/23 04:12
Bromochloromethane
ug/L
ND
1.0
0.47
11/11/23 04:12
Bromodichloromethane
ug/L
ND
1.0
0.31
11/11/23 04:12
Bromoform
ug/L
ND
1.0
0.34
11/11/23 04:12
Bromomethane
ug/L
ND
2.0
1.7
11/11/23 04:12
Carbon disulfide
ug/L
ND
2.0
0.36
11/11/23 04:12
Carbon tetrachloride
ug/L
ND
1.0
0.33
11/11/23 04:12
Chlorobenzene
ug/L
ND
1.0
0.28
11/11/23 04:12
Chloroethane
ug/L
ND
1.0
0.65
11/11/23 04:12
Chloroform
ug/L
ND
1.0
0.43
11/11/23 04:12
Chloromethane
ug/L
ND
1.0
0.54
11/11/23 04:12
Chloroprene
ug/L
ND
5.0
1.6
11/11/23 04:12
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
11/11/23 04:12
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
11/11/23 04:12
Dibromochloromethane
ug/L
ND
1.0
0.36
11/11/23 04:12
Dichlorodifluoromethane
ug/L
ND
1.0
0.35
11/11/23 04:12
Ethyl methacrylate
ug/L
ND
1.0
0.28
11/11/23 04:12
Ethylbenzene
ug/L
ND
1.0
0.30
11/11/23 04:12
v1
v1
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 78 of 130

Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
aceo Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
METHOD BLANK: 4206813 Matrix: Water
Associated Lab Samples: 92697334001, 92697334002, 92697334003, 92697334004
Blank Reporting
Parameter Units Result Limit
MDL
Analyzed Qualifiers
Hexachloro-1,3-butadiene
ug/L
ND
2.0
1.5
11/11/23 04:12
lodomethane
ug/L
ND
20.0
9.7
11/11/23 04:12
Isobutanol
ug/L
ND
100
52.3
11/11/23 04:12
Methacrylonitrile
ug/L
ND
10.0
4.2
11/11/23 04:12
Methyl methacrylate
ug/L
ND
2.0
0.32
11/11/23 04:12
Methylene Chloride
ug/L
ND
5.0
2.0
11/11/23 04:12
Naphthalene
ug/L
ND
1.0
0.64
11/11/23 04:12
Propionitrile
ug/L
ND
20.0
3.6
11/11/23 04:12
Styrene
ug/L
ND
1.0
0.29
11/11/23 04:12
Tetrachloroethene
ug/L
ND
1.0
0.29
11/11/23 04:12
Toluene
ug/L
ND
1.0
0.24
11/11/23 04:12
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
11/11/23 04:12
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
11/11/23 04:12
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
11/11/23 04:12
Trichloroethene
ug/L
ND
1.0
0.38
11/11/23 04:12
Trichlorofluoromethane
ug/L
ND
1.0
0.30
11/11/23 04:12
Vinyl acetate
ug/L
ND
2.0
1.3
11/11/23 04:12
Vinyl chloride
ug/L
ND
1.0
0.39
11/11/23 04:12
Xylene (Total)
ug/L
ND
1.0
0.34
11/11/23 04:12
1,2-Dichloroethane-d4 (S)
%
99
70-130
11/11/23 04:12
4-Bromofluorobenzene (S)
%
98
70-130
11/11/23 04:12
Toluene-d8 (S)
%
101
70-130
11/11/23 04:12
LABORATORY CONTROL SAMPLE:
Parameter
4206814
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
20
21.6
108
70-130
1,1,1-Trichloroethane
ug/L
20
22.4
112
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
21.6
108
70-130
1,1,2-Trichloroethane
ug/L
20
21.1
106
70-130
1,1-Dichloroethane
ug/L
20
22.3
111
70-130
1,1-Dichloroethene
ug/L
20
23.8
119
69-131
1,1-Dichloropropene
ug/L
20
24.0
120
70-132 v1
1,2,3-Trichloropropane
ug/L
20
20.7
104
70-130
1,2,4-Trichlorobenzene
ug/L
20
22.1
110
70-130
1,2-Dichlorobenzene
ug/L
20
21.8
109
70-130
1,2-Dichloroethane
ug/L
20
21.0
105
70-130
1,3-Dichlorobenzene
ug/L
20
21.8
109
70-130
1,3-Dichloropropane
ug/L
20
20.8
104
70-130
1,4-Dichlorobenzene
ug/L
20
22.0
110
70-130
2,2-Dichloropropane
ug/L
20
21.8
109
69-130
2-Butanone (MEK)
ug/L
40
41.7
104
67-133
2-Hexanone
ug/L
40
43.8
109
70-133
Acetone
ug/L
40
41.4
103
67-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 79 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
LABORATORY CONTROL SAMPLE:
Parameter
4206814
Units
Spike
Conc.
Acetonitrile
ug/L
200
Acrolein
ug/L
100
Acrylonitrile
ug/L
100
Allyl chloride
ug/L
20
Benzene
ug/L
20
Bromochloromethane
ug/L
20
Bromodichloromethane
ug/L
20
Bromoform
ug/L
20
Bromomethane
ug/L
20
Carbon disulfide
ug/L
20
Carbon tetrachloride
ug/L
20
Chlorobenzene
ug/L
20
Chloroethane
ug/L
20
Chloroform
ug/L
20
Chloromethane
ug/L
20
Chloroprene
ug/L
20
cis-1,2-Dichloroethene
ug/L
20
cis-1,3-Dichloropropene
ug/L
20
Dibromochloromethane
ug/L
20
Dichlorodifluoromethane
ug/L
20
Ethyl methacrylate
ug/L
20
Ethylbenzene
ug/L
20
Hexachloro-1,3-butadiene
ug/L
20
lodomethane
ug/L
40
Isobutanol
ug/L
400
Methacrylonitrile
ug/L
200
Methyl methacrylate
ug/L
20
Methylene Chloride
ug/L
20
Naphthalene
ug/L
20
Propionitrile
ug/L
200
Styrene
ug/L
20
Tetrachloroethene
ug/L
20
Toluene
ug/L
20
trans-1,2-Dichloroethene
ug/L
20
trans- 1,3-Dichloropropene
ug/L
20
trans-1,4-Dichloro-2-butene
ug/L
20
Trichloroethene
ug/L
20
Trichlorofluoromethane
ug/L
20
Vinyl acetate
ug/L
40
Vinyl chloride
ug/L
20
Xylene (Total)
ug/L
60
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
205
103
70-130
109
109
53-166
112
112
70-130
21.0
105
69-130
21.5
108
70-130
20.9
104
70-130
20.7
103
70-130
21.1
105
70-133
17.4
87
41-148
23.7
119
70-131
22.9
115
70-130
21.9
109
70-130
23.2
116
41-157
21.9
110
70-130
20.6
103
59-141
22.1
110
70-130
21.4
107
70-130
21.4
107
70-130
21.1
106
70-130
25.6
128
54-147 v1
21.0
105
70-130
21.6
108
70-130
21.6
108
70-134
40.0
100
57-140
359
90
67-136
210
105
70-130
21.1
106
70-130
20.2
101
62-130
22.2
111
70-135
212
106
70-130
21.9
110
70-130
23.1
115
70-130
21.2
106
70-130
23.1
116
70-130
21.1
105
70-130
20.9
105
57-149
22.3
112
70-130
23.6
118
57-130
44.8
112
70-141
20.4
102
66-140
65.7
110
70-130
99
70-130
99
70-130
100
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 80 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
MATRIX SPIKE SAMPLE:
Parameter
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2,2-Dichloropropane
2-Butanone (MEK)
2-Hexanone
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Allyl chloride
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Chloroprene
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dichlorodifluoromethane
Ethyl methacrylate
Ethylbenzene
Hexachloro-1,3-butadiene
lodomethane
Isobutanol
Methacrylonitrile
Methyl methacrylate
Methylene Chloride
Naphthalene
4206815
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
QUALITY CONTROL DATA
92697583005 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND
20
24.9
124
70-146
ND
20
25.7
128
70-150
ND
20
22.8
114
66-144
ND
20
23.4
117
70-142
ND
20
24.0
120
68-150
ND
20
26.1
131
64-162
ND
20
27.6
138
70-160
ND
20
22.2
111
66-144
ND
20
26.0
130
69-147
ND
20
24.6
123
70-142
ND
20
21.5
108
68-145
ND
20
24.9
124
70-142
ND
20
22.7
113
70-141
ND
20
24.7
123
70-140
ND
20
28.4
142
58-160
ND
40
44.8
112
57-156
ND
40
47.3
118
62-153
ND
40
41.8
104
49-162
ND
200
199
100
69-145
ND
100
124
124
10-200
ND
100
115
115
59-155
ND
20
23.6
118
70-146
ND
20
24.8
124
68-144
ND
20
23.4
117
70-148
ND
20
23.1
116
70-141
ND
20
24.1
120
59-144
ND
20
21.1
105
23-190
ND
20
26.5
132
64-160
ND
20
26.8
134
70-147
ND
20
24.5
123
70-143
ND
20
25.1
125
55-190
ND
20
23.0
115
67-148
ND
20
21.6
108
38-180
ND
20
24.9
125
70-148
ND
20
23.6
118
67-151
ND
20
23.6
118
70-142
ND
20
23.7
118
68-140
ND
20
21.5
107
15-200
ND
20
22.8
114
68-139
ND
20
25.5
125
70-145
ND
20
28.5
142
64-164
ND
40
46.4
116
37-160
ND
400
360
90
53-152
ND
200
215
108
70-137
ND
20
21.6
108
69-134
ND
20
21.8
109
54-149
ND
20
25.4
127
62-154
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 81 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
MATRIX SPIKE SAMPLE:
4206815
92697583005
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Propionitrile
ug/L
ND
200
215
107
70-136
Styrene
ug/L
ND
20
25.0
125
70-147
Tetrachloroethene
ug/L
ND
20
26.0
130
70-145
Toluene
ug/L
ND
20
24.1
120
65-146
trans-1,2-Dichloroethene
ug/L
ND
20
26.0
130
69-155
trans- 1,3-Dichloropropene
ug/L
ND
20
23.7
118
70-142
trans-1,4-Dichloro-2-butene
ug/L
ND
20
24.2
121
39-149
Trichloroethene
ug/L
ND
20
26.1
131
70-152
Trichlorofluoromethane
ug/L
ND
20
25.8
129
60-158
Vinyl acetate
ug/L
ND
40
48.9
122
56-157
Vinyl chloride
ug/L
ND
20
22.0
110
51-178
Xylene (Total)
ug/L
ND
60
75.5
126
70-146
1,2-Dichloroethane-d4 (S)
%
89
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
100
70-130
SAMPLE DUPLICATE: 4206816
92697583004
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,1-Trichloroethane
ug/L
ND
ND
30
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,2-Trichloroethane
ug/L
ND
ND
30
1,1-Dichloroethane
ug/L
ND
ND
30
1,1-Dichloroethene
ug/L
ND
ND
30
1,1-Dichloropropene
ug/L
ND
ND
30
1,2,3-Trichloropropane
ug/L
ND
ND
30
1,2,4-Trichlorobenzene
ug/L
ND
ND
30
1,2-Dichlorobenzene
ug/L
ND
ND
30
1,2-Dichloroethane
ug/L
ND
ND
30
1,3-Dichlorobenzene
ug/L
ND
ND
30
1,3-Dichloropropane
ug/L
ND
ND
30
1,4-Dichlorobenzene
ug/L
ND
ND
30
2,2-Dichloropropane
ug/L
ND
ND
30
2-Butanone (MEK)
ug/L
ND
ND
30
2-Hexanone
ug/L
ND
ND
30
Acetone
ug/L
ND
ND
30
Acetonitrile
ug/L
ND
ND
30
Acrolein
ug/L
ND
ND
30 AC
Acrylonitrile
ug/L
ND
ND
30
Allyl chloride
ug/L
ND
ND
30
Benzene
ug/L
ND
ND
30
Bromochloromethane
ug/L
ND
ND
30
Bromodichloromethane
ug/L
ND
ND
30
Bromoform
ug/L
ND
ND
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 82 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
SAMPLE DUPLICATE: 4206816
Parameter
Units
92697583004
Result
Dup
Result RPD
Max
RPD
Bromomethane
ug/L
ND
ND
30
Carbon disulfide
ug/L
ND
ND
30
Carbon tetrachloride
ug/L
ND
ND
30
Chlorobenzene
ug/L
ND
ND
30
Chloroethane
ug/L
ND
ND
30
Chloroform
ug/L
ND
ND
30
Chloromethane
ug/L
ND
ND
30
Chloroprene
ug/L
ND
ND
30
cis-1,2-Dichloroethene
ug/L
ND
ND
30
cis-1,3-Dichloropropene
ug/L
ND
ND
30
Dibromochloromethane
ug/L
ND
ND
30
Dichlorodifluoromethane
ug/L
ND
ND
30
Ethyl methacrylate
ug/L
ND
ND
30
Ethylbenzene
ug/L
ND
ND
30
Hexachloro-1,3-butadiene
ug/L
ND
ND
30
lodomethane
ug/L
ND
ND
30
Isobutanol
ug/L
ND
ND
30
Methacrylonitrile
ug/L
ND
ND
30
Methyl methacrylate
ug/L
ND
ND
30
Methylene Chloride
ug/L
ND
ND
30
Naphthalene
ug/L
ND
ND
30
Propionitrile
ug/L
ND
ND
30
Styrene
ug/L
ND
ND
30
Tetrachloroethene
ug/L
ND
ND
30
Toluene
ug/L
ND
ND
30
trans-1,2-Dichloroethene
ug/L
ND
ND
30
trans- 1,3-Dichloropropene
ug/L
ND
ND
30
trans-1,4-Dichloro-2-butene
ug/L
ND
ND
30
Trichloroethene
ug/L
ND
ND
30
Trichlorofluoromethane
ug/L
ND
ND
30
Vinyl acetate
ug/L
ND
ND
30
Vinyl chloride
ug/L
ND
ND
30
Xylene (Total)
ug/L
ND
ND
30
1,2-Dichloroethane-d4 (S)
%
98
98
4-Bromofluorobenzene (S)
%
97
97
Toluene-d8 (S)
%
100
101
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 83 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 812467
QC Batch Method: EPA 8260D
Associated Lab Samples: 92697334005, 92697337006
METHOD BLANK: 4206844
Associated Lab Samples: 92697334005, 92697337006
Parameter Units
1,1,1,2-Tetrachloroethane
ug/L
1,1,1-Trichloroethane
ug/L
1,1,2,2-Tetrachloroethane
ug/L
1,1,2-Trichloroethane
ug/L
1,1-Dichloroethane
ug/L
1,1-Dichloroethene
ug/L
1,1-Dichloropropene
ug/L
1,2,3-Trichloropropane
ug/L
1,2,4-Trichlorobenzene
ug/L
1,2-Dichlorobenzene
ug/L
1,2-Dichloroethane
ug/L
1,3-Dichlorobenzene
ug/L
1,3-Dichloropropane
ug/L
1,4-Dichlorobenzene
ug/L
2,2-Dichloropropane
ug/L
2-Butanone (MEK)
ug/L
2-Hexanone
ug/L
Acetone
ug/L
Acetonitrile
ug/L
Acrolein
ug/L
Acrylonitrile
ug/L
Allyl chloride
ug/L
Benzene
ug/L
Bromochloromethane
ug/L
Bromodichloromethane
ug/L
Bromoform
ug/L
Bromomethane
ug/L
Carbon disulfide
ug/L
Carbon tetrachloride
ug/L
Chlorobenzene
ug/L
Chloroethane
ug/L
Chloroform
ug/L
Chloromethane
ug/L
Chloroprene
ug/L
cis-1,2-Dichloroethene
ug/L
cis-1,3-Dichloropropene
ug/L
Dibromochloromethane
ug/L
Dichlorodifluoromethane
ug/L
Ethyl methacrylate
ug/L
Ethylbenzene
ug/L
QUALITY CONTROL DATA
Analysis Method: EPA 8260D
Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Matrix: Water
Blank
Result
Reporting
Limit
MDL
Analyzed Qualifiers
ND
1.0
0.31
11/10/2316:26
ND
1.0
0.33
11/10/2316:26
ND
1.0
0.22
11/10/2316:26
ND
1.0
0.32
11/10/2316:26
ND
1.0
0.37
11/10/2316:26
ND
1.0
0.35
11/10/2316:26
ND
1.0
0.43
11/10/2316:26
ND
1.0
0.26
11/10/2316:26
ND
1.0
0.64
11/10/2316:26
ND
1.0
0.34
11/10/2316:26
ND
1.0
0.32
11/10/2316:26
ND
1.0
0.34
11/10/2316:26
ND
1.0
0.28
11/10/2316:26
ND
1.0
0.33
11/10/2316:26
ND
1.0
0.39
11/10/2316:26
ND
5.0
4.0
11/10/2316:26
ND
5.0
0.48
11/10/2316:26
ND
25.0
5.1
11/10/2316:26
ND
50.0
24.8
11/10/2316:26
ND
10.0
8.5
11/10/2316:26 v1
ND
10.0
1.8
11/10/2316:26
ND
2.0
0.50
11/10/2316:26
ND
1.0
0.34
11/10/2316:26
ND
1.0
0.47
11/10/2316:26
ND
1.0
0.31
11/10/2316:26
ND
1.0
0.34
11/10/2316:26
ND
2.0
1.7
11/10/2316:26
ND
2.0
0.36
11/10/2316:26
ND
1.0
0.33
11/10/2316:26
ND
1.0
0.28
11/10/2316:26
ND
1.0
0.65
11/10/2316:26
ND
1.0
0.43
11/10/2316:26
ND
1.0
0.54
11/10/2316:26
ND
5.0
1.6
11/10/2316:26
ND
1.0
0.38
11/10/2316:26
ND
1.0
0.36
11/10/2316:26
ND
1.0
0.36
11/10/2316:26
ND
1.0
0.35
11/10/2316:26 IH,v1
ND
1.0
0.28
11/10/2316:26
ND
1.0
0.30
11/10/2316:26
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 84 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
METHOD BLANK: 4206844
Associated Lab Samples: 92697334005, 92697337006
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Hexachloro-1,3-butadiene
ug/L
ND
2.0
1.5
11/10/23 16:26
lodomethane
ug/L
ND
20.0
9.7
11/10/23 16:26
Isobutanol
ug/L
ND
100
52.3
11/10/23 16:26
Methacrylonitrile
ug/L
ND
10.0
4.2
11/10/23 16:26
Methyl methacrylate
ug/L
ND
2.0
0.32
11/10/23 16:26
Methylene Chloride
ug/L
ND
5.0
2.0
11/10/23 16:26
Naphthalene
ug/L
ND
1.0
0.64
11/10/23 16:26
Propionitrile
ug/L
ND
20.0
3.6
11/10/23 16:26
Styrene
ug/L
ND
1.0
0.29
11/10/23 16:26
Tetrachloroethene
ug/L
ND
1.0
0.29
11/10/23 16:26
Toluene
ug/L
ND
1.0
0.24
11/10/23 16:26
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
11/10/23 16:26
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
11/10/23 16:26
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
11/10/23 16:26
Trichloroethene
ug/L
ND
1.0
0.38
11/10/23 16:26
Trichlorofluoromethane
ug/L
ND
1.0
0.30
11/10/23 16:26
Vinyl acetate
ug/L
ND
2.0
1.3
11/10/23 16:26
Vinyl chloride
ug/L
ND
1.0
0.39
11/10/23 16:26
Xylene (Total)
ug/L
ND
1.0
0.34
11/10/23 16:26
1,2-Dichloroethane-d4 (S)
%
88
70-130
11/10/23 16:26
4-Bromofluorobenzene (S)
%
99
70-130
11/10/23 16:26
Toluene-d8 (S)
%
104
70-130
11/10/23 16:26
LABORATORY CONTROL SAMPLE:
Parameter
4206845
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1,2-Tetrachloroethane
ug/L
20
19.6
98
70-130
1,1,1-Trichloroethane
ug/L
20
19.7
99
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
20.7
103
70-130
1,1,2-Trichloroethane
ug/L
20
21.2
106
70-130
1,1-Dichloroethane
ug/L
20
20.6
103
70-130
1,1-Dichloroethene
ug/L
20
20.3
102
69-131
1,1-Dichloropropene
ug/L
20
22.6
113
70-132
1,2,3-Trichloropropane
ug/L
20
19.2
96
70-130
1,2,4-Trichlorobenzene
ug/L
20
20.8
104
70-130
1,2-Dichlorobenzene
ug/L
20
20.7
104
70-130
1,2-Dichloroethane
ug/L
20
18.4
92
70-130
1,3-Dichlorobenzene
ug/L
20
20.6
103
70-130
1,3-Dichloropropane
ug/L
20
20.4
102
70-130
1,4-Dichlorobenzene
ug/L
20
20.0
100
70-130
2,2-Dichloropropane
ug/L
20
19.5
97
69-130
2-Butanone (MEK)
ug/L
40
37.2
93
67-133
2-Hexanone
ug/L
40
43.3
108
70-133
Acetone
ug/L
40
40.1
100
67-130
Qualifiers
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 85 of 130

Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
aceo Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
LABORATORY CONTROL SAMPLE:
Parameter
4206845
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Acetonitrile
ug/L
200
228
114
70-130
Acrolein
ug/L
100
138
138
53-166 v1
Acrylonitrile
ug/L
100
111
111
70-130
Allyl chloride
ug/L
20
22.9
115
69-130
Benzene
ug/L
20
20.9
104
70-130
Bromochloromethane
ug/L
20
20.9
105
70-130
Bromodichloromethane
ug/L
20
19.4
97
70-130
Bromoform
ug/L
20
19.5
97
70-133
Bromomethane
ug/L
20
16.1
80
41-148
Carbon disulfide
ug/L
20
22.3
111
70-131
Carbon tetrachloride
ug/L
20
19.4
97
70-130
Chlorobenzene
ug/L
20
20.0
100
70-130
Chloroethane
ug/L
20
18.7
94
41-157
Chloroform
ug/L
20
20.1
100
70-130
Chloromethane
ug/L
20
24.0
120
59-141
Chloroprene
ug/L
20
20.7
104
70-130
cis-1,2-Dichloroethene
ug/L
20
20.5
103
70-130
cis-1,3-Dichloropropene
ug/L
20
20.4
102
70-130
Dibromochloromethane
ug/L
20
20.1
100
70-130
Dichlorodifluoromethane
ug/L
20
30.4
152
54-1471H,L1,v1
Ethyl methacrylate
ug/L
20
21.5
107
70-130
Ethylbenzene
ug/L
20
19.7
98
70-130
Hexachloro-1,3-butadiene
ug/L
20
20.6
103
70-134
lodomethane
ug/L
40
36.5
91
57-140
Isobutanol
ug/L
400
380
95
67-136
Methacrylonitrile
ug/L
200
205
102
70-130
Methyl methacrylate
ug/L
20
20.9
104
70-130
Methylene Chloride
ug/L
20
21.2
106
62-130
Naphthalene
ug/L
20
22.4
112
70-135
Propionitrile
ug/L
200
216
108
70-130
Styrene
ug/L
20
20.4
102
70-130
Tetrachloroethene
ug/L
20
19.1
95
70-130
Toluene
ug/L
20
20.1
101
70-130
trans-1,2-Dichloroethene
ug/L
20
20.8
104
70-130
trans- 1,3-Dichloropropene
ug/L
20
19.7
98
70-130
trans-1,4-Dichloro-2-butene
ug/L
20
19.1
96
57-149
Trichloroethene
ug/L
20
19.6
98
70-130
Trichlorofluoromethane
ug/L
20
19.6
98
57-130
Vinyl acetate
ug/L
40
35.6
89
70-141
Vinyl chloride
ug/L
20
21.6
108
66-140
Xylene (Total)
ug/L
60
59.4
99
70-130
1,2-Dichloroethane-d4 (S)
%
90
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
102
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 86 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
MATRIX SPIKE SAMPLE:
Parameter
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2,2-Dichloropropane
2-Butanone (MEK)
2-Hexanone
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Allyl chloride
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Chloroprene
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dichlorodifluoromethane
Ethyl methacrylate
Ethylbenzene
Hexachloro-1,3-butadiene
lodomethane
Isobutanol
Methacrylonitrile
Methyl methacrylate
Methylene Chloride
Naphthalene
4206846
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
QUALITY CONTROL DATA
92697345001 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND
20
24.3
122
70-146
ND
20
25.2
126
70-150
ND
20
24.4
122
66-144
ND
20
23.8
119
70-142
1.3
20
25.8
123
68-150
ND
20
25.9
130
64-162
ND
20
26.9
134
70-160
ND
20
22.7
114
66-144
ND
20
22.5
112
69-147
ND
20
23.3
116
70-142
ND
20
24.0
120
68-145
ND
20
23.3
116
70-142
ND
20
23.8
119
70-141
ND
20
23.7
118
70-140
ND
20
26.5
133
58-160
ND
40
45.3
108
57-156
ND
40
50.3
126
62-153
11.11
40
55.5
111
49-162
ND
200
228
112
69-145
ND
100
140
140
10-200 AC
ND
100
118
118
59-155
ND
20
25.8
129
70-146
ND
20
25.1
124
68-144
ND
20
24.3
121
70-148
ND
20
23.5
117
70-141
ND
20
23.0
115
59-144
ND
20
21.9
109
23-190
ND
20
25.7
128
64-160
ND
20
25.0
125
70-147
ND
20
24.3
121
70-143
ND
20
24.1
120
55-190
ND
20
24.7
124
67-148
ND
20
22.6
113
38-180
ND
20
25.5
128
70-148
0.97J
20
25.3
122
67-151
ND
20
23.4
117
70-142
ND
20
24.1
121
68-140
ND
20
25.9
130
15-200
ND
20
24.5
123
68-139
ND
20
24.1
121
70-145
ND
20
23.7
118
64-164
ND
40
42.6
107
37-160
ND
400
424
106
53-152
ND
200
232
116
70-137
ND
20
23.7
118
69-134
ND
20
23.8
118
54-149
ND
20
23.6
118
62-154
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 87 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
MATRIX SPIKE SAMPLE:
4206846
92697345001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Propionitrile
ug/L
ND
200
234
117
70-136
Styrene
ug/L
ND
20
24.5
122
70-147
Tetrachloroethene
ug/L
ND
20
23.1
115
70-145
Toluene
ug/L
0.79J
20
24.7
120
65-146
trans-1,2-Dichloroethene
ug/L
ND
20
25.3
126
69-155
trans- 1,3-Dichloropropene
ug/L
ND
20
23.9
119
70-142
trans-1,4-Dichloro-2-butene
ug/L
ND
20
21.6
108
39-149
Trichloroethene
ug/L
0.44J
20
25.2
124
70-152
Trichlorofluoromethane
ug/L
ND
20
25.6
128
60-158
Vinyl acetate
ug/L
ND
40
41.0
103
56-157
Vinyl chloride
ug/L
ND
20
21.6
108
51-178
Xylene (Total)
ug/L
ND
60
72.6
121
70-146
1,2-Dichloroethane-d4 (S)
%
102
70-130
4-Bromofluorobenzene (S)
%
102
70-130
Toluene-d8 (S)
%
99
70-130
SAMPLE DUPLICATE: 4206847
92697346005
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,1-Trichloroethane
ug/L
ND
ND
30
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,2-Trichloroethane
ug/L
ND
ND
30
1,1-Dichloroethane
ug/L
0.44J
0.43J
30
1,1-Dichloroethene
ug/L
ND
ND
30
1,1-Dichloropropene
ug/L
ND
ND
30
1,2,3-Trichloropropane
ug/L
ND
ND
30
1,2,4-Trichlorobenzene
ug/L
ND
ND
30
1,2-Dichlorobenzene
ug/L
ND
ND
30
1,2-Dichloroethane
ug/L
ND
ND
30
1,3-Dichlorobenzene
ug/L
ND
ND
30
1,3-Dichloropropane
ug/L
ND
ND
30
1,4-Dichlorobenzene
ug/L
ND
ND
30
2,2-Dichloropropane
ug/L
ND
ND
30
2-Butanone (MEK)
ug/L
ND
ND
30
2-Hexanone
ug/L
ND
ND
30
Acetone
ug/L
ND
ND
30
Acetonitrile
ug/L
ND
ND
30
Acrolein
ug/L
ND
ND
30 AC
Acrylonitrile
ug/L
ND
ND
30
Allyl chloride
ug/L
ND
ND
30
Benzene
ug/L
ND
ND
30
Bromochloromethane
ug/L
ND
ND
30
Bromodichloromethane
ug/L
ND
ND
30
Bromoform
ug/L
ND
ND
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 88 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
SAMPLE DUPLICATE: 4206847
Parameter
Units
92697346005
Result
Bromomethane
ug/L
ND
Carbon disulfide
ug/L
ND
Carbon tetrachloride
ug/L
ND
Chlorobenzene
ug/L
ND
Chloroethane
ug/L
ND
Chloroform
ug/L
ND
Chloromethane
ug/L
ND
Chloroprene
ug/L
ND
cis-1,2-Dichloroethene
ug/L
2.8
cis-1,3-Dichloropropene
ug/L
ND
Dibromochloromethane
ug/L
ND
Dichlorodifluoromethane
ug/L
ND
Ethyl methacrylate
ug/L
ND
Ethylbenzene
ug/L
ND
Hexachloro-1,3-butadiene
ug/L
ND
lodomethane
ug/L
ND
Isobutanol
ug/L
ND
Methacrylonitrile
ug/L
ND
Methyl methacrylate
ug/L
ND
Methylene Chloride
ug/L
ND
Naphthalene
ug/L
ND
Propionitrile
ug/L
ND
Styrene
ug/L
ND
Tetrachloroethene
ug/L
0.31 J
Toluene
ug/L
ND
trans-1,2-Dichloroethene
ug/L
ND
trans- 1,3-Dichloropropene
ug/L
ND
trans-1,4-Dichloro-2-butene
ug/L
ND
Trichloroethene
ug/L
ND
Trichlorofluoromethane
ug/L
ND
Vinyl acetate
ug/L
ND
Vinyl chloride
ug/L
ND
Xylene (Total)
ug/L
ND
1,2-Dichloroethane-d4 (S)
%
89
4-Bromofluorobenzene (S)
%
98
Toluene-d8 (S)
%
102
Dup
Result RPD
ND
ND
ND
ND
ND
ND
ND
ND
2.8
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
97
99
104
0
Max
RPD
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 89 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 812579 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92697337007
METHOD BLANK: 4207450
Associated Lab Samples: 92697337007
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
1,1-Dichloroethane
ug/L
ND
1.0
0.37
11/11/23 05:09
1,2-Dichloroethane
ug/L
ND
1.0
0.32
11/11/23 05:09
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
11/11/23 05:09
Benzene
ug/L
ND
1.0
0.34
11/11/23 05:09
Methylene Chloride
ug/L
ND
5.0
2.0
11/11/23 05:09
Tetrachloroethene
ug/L
ND
1.0
0.29
11/11/23 05:09
Trichloroethene
ug/L
ND
1.0
0.38
11/11/23 05:09
Vinyl chloride
ug/L
ND
1.0
0.39
11/11/23 05:09
1,2-Dichloroethane-d4 (S)
%
88
70-130
11/11/23 05:09
4-Bromofluorobenzene (S)
%
97
70-130
11/11/23 05:09
Toluene-d8 (S)
%
103
70-130
11/11/23 05:09
LABORATORY CONTROL SAMPLE:
Parameter
4207451
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1-Dichloroethane
ug/L
20
22.1
110
70-130
1,2-Dichloroethane
ug/L
20
19.4
97
70-130
1,4-Dichlorobenzene
ug/L
20
21.2
106
70-130
Benzene
ug/L
20
22.1
110
70-130
Methylene Chloride
ug/L
20
21.9
109
62-130
Tetrachloroethene
ug/L
20
21.4
107
70-130
Trichloroethene
ug/L
20
21.0
105
70-130
Vinyl chloride
ug/L
20
22.8
114
66-140
1,2-Dichloroethane-d4 (S)
%
92
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
100
70-130
MATRIX SPIKE SAMPLE:
Parameter
4207453
Units
92697346003
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
1,1-Dichloroethane
ug/L
ND
20
21.9
108
68-150
1,2-Dichloroethane
ug/L
ND
20
20.7
103
68-145
1,4-Dichlorobenzene
ug/L
11.4
20
31.8
102
70-140
Benzene
ug/L
3.6
20
25.9
111
68-144
Methylene Chloride
ug/L
ND
20
21.6
107
54-149
Tetrachloroethene
ug/L
ND
20
20.9
105
70-145
Trichloroethene
ug/L
ND
20
22.2
111
70-152
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 90 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
MATRIX SPIKE SAMPLE:
4207453
92697346003 Spike MS MS
% Rec
Parameter
Units
Result Conc. Result % Rec
Limits Qualifiers
Vinyl chloride
ug/L
ND 20 19.7 99
51-178
1,2-Dichloroethane-d4 (S)
%
100
70-130
4-Bromofluorobenzene (S)
%
102
70-130
Toluene-d8 (S)
%
100
70-130
SAMPLE DUPLICATE: 4207452
Parameter
Units
92697346001
Result
Dup
Result
1,1-Dichloroethane
ug/L
ND
ND
1,2-Dichloroethane
ug/L
ND
ND
1,4-Dichlorobenzene
ug/L
ND
ND
Benzene
ug/L
ND
ND
Methylene Chloride
ug/L
ND
ND
Tetrachloroethene
ug/L
ND
ND
Trichloroethene
ug/L
ND
ND
Vinyl chloride
ug/L
ND
ND
1,2-Dichloroethane-d4 (S)
%
97
95
4-Bromofluorobenzene (S)
%
101
100
Toluene-d8(S)
%
104
103
Max
RPD RPD Qualifiers
30
30
30
30
30
30
30
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 91 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 812809 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92698172001
METHOD BLANK: 4208323
Associated Lab Samples: 92698172001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
1,1-Dichloroethane
ug/L
ND
1.0
0.37
11/16/23 00:44
1,2-Dichloroethane
ug/L
ND
1.0
0.32
11/16/23 00:44
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
11/16/23 00:44
Benzene
ug/L
ND
1.0
0.34
11/16/23 00:44
Methylene Chloride
ug/L
ND
5.0
2.0
11/16/23 00:44
Tetrachloroethene
ug/L
ND
1.0
0.29
11/16/23 00:44
Trichloroethene
ug/L
ND
1.0
0.38
11/16/23 00:44
Vinyl chloride
ug/L
ND
1.0
0.39
11/16/23 00:44
1,2-Dichloroethane-d4 (S)
%
95
70-130
11/16/23 00:44
4-Bromofluorobenzene (S)
%
96
70-130
11/16/23 00:44
Toluene-d8 (S)
%
101
70-130
11/16/23 00:44
LABORATORY CONTROL SAMPLE:
Parameter
4208324
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1-Dichloroethane
ug/L
20
21.7
109
70-130
1,2-Dichloroethane
ug/L
20
21.4
107
70-130
1,4-Dichlorobenzene
ug/L
20
21.8
109
70-130
Benzene
ug/L
20
22.4
112
70-130
Methylene Chloride
ug/L
20
21.7
108
62-130
Tetrachloroethene
ug/L
20
22.6
113
70-130
Trichloroethene
ug/L
20
23.3
117
70-130
Vinyl chloride
ug/L
20
21.1
105
66-140
1,2-Dichloroethane-d4 (S)
%
97
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8 (S)
%
100
70-130
MATRIX SPIKE SAMPLE:
Parameter
4208326
Units
92698172004
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
1,1-Dichloroethane
ug/L
ND
20
24.8
124
68-150
1,2-Dichloroethane
ug/L
ND
20
21.7
109
68-145
1,4-Dichlorobenzene
ug/L
ND
20
24.7
124
70-140
Benzene
ug/L
ND
20
24.9
125
68-144
Methylene Chloride
ug/L
ND
20
22.8
114
54-149
Tetrachloroethene
ug/L
ND
20
25.8
129
70-145
Trichloroethene
ug/L
ND
20
25.7
129
70-152
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 92 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
MATRIX SPIKE SAMPLE:
4208326
92698172004 Spike MS MS
% Rec
Parameter
Units
Result Conc. Result % Rec
Limits Qualifiers
Vinyl chloride
ug/L
ND 20 24.1 120
51-178
1,2-Dichloroethane-d4 (S)
%
91
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
100
70-130
SAMPLE DUPLICATE: 4208325
Parameter
Units
92698172003
Result
Dup
Result
1,1-Dichloroethane
ug/L
ND
ND
1,2-Dichloroethane
ug/L
ND
ND
1,4-Dichlorobenzene
ug/L
0.68J
0.74J
Benzene
ug/L
0.40J
0.41 J
Methylene Chloride
ug/L
ND
ND
Tetrachloroethene
ug/L
ND
ND
Trichloroethene
ug/L
ND
ND
Vinyl chloride
ug/L
ND
ND
1,2-Dichloroethane-d4 (S)
%
94
92
4-Bromofluorobenzene (S)
%
97
96
Toluene-d8(S)
%
101
101
Max
RPD RPD Qualifiers
30
30
30
30
30
30
30
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 93 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 812181 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92697334001, 92697334002, 92697334003, 92697334004, 92697334005
METHOD BLANK: 4205427
Matrix:
Water
Associated Lab Samples:
92697334001, 92697334002, 92697334003, 92697334004, 92697334005
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0 0.86
11/10/23 01:48
1,2-Dichloroethane-d4 (S)
%
91
67-130
11/10/23 01:48
Toluene-d8 (S)
%
92
70-130
11/10/23 01:48
LABORATORY CONTROL SAMPLE: 4205428
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane(p-Dioxane) ug/L 20 19.6 98 70-130
1,2-Dichloroethane-d4 (S) % 90 67-130
Toluene-d8 (S) % 92 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4205429
4205430
MS
MSD
92697334001 Spike
Spike MS MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result Result
% Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane(p-Dioxane)
ug/L 1.01 20
20 19.4 19.8
92
94
55-137
2 30
1,2-Dichloroethane-d4 (S)
%
88
88
67-130
30
Toluene-d8 (S)
%
97
97
70-130
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 94 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 812182 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92697337006, 92697337007
METHOD BLANK: 4205446
Matrix:
Water
Associated Lab Samples:
92697337006, 92697337007
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
0.86 11/10/23 02:10
1,2-Dichloroethane-d4 (S)
%
90
67-130
11/10/23 02:10
Toluene-d8 (S)
%
92
70-130
11/10/23 02:10
LABORATORY CONTROL SAMPLE: 4205447
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 20 20.0 100 70-130
1,2-Dichloroethane-d4 (S) % 90 67-130
Toluene-d8 (S) % 93 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4205448
4205449
MS
MSD
92697346004 Spike
Spike MS MSD MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result Result % Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane(p-Dioxane)
ug/L 111 20
20 123 128 61
82
55-137
3 30
1,2-Dichloroethane-d4 (S)
%
94
94
67-130
30
Toluene-d8 (S)
%
96
95
70-130
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 95 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 812043 Analysis Method: EPA 8081 B
QC Batch Method: EPA 3510C Analysis Description: 8081 OC Pesticides Red Vol
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92697334001, 92697334002, 92697334003, 92697334004, 92697334005
METHOD BLANK: 4204514 Matrix: Water
Associated Lab Samples: 92697334001, 92697334002, 92697334003, 92697334004, 92697334005
Blank Reporting
Parameter Units Result Limit MDL
Analyzed Qualifiers
4,4'-DDD
ug/L
ND
0.050
0.017
11/10/23 15:53
4,4'-DDE
ug/L
ND
0.050
0.024
11/10/23 15:53
4,4'-DDT
ug/L
ND
0.050
0.026
11/10/23 15:53
Aldrin
ug/L
ND
0.050
0.014
11/10/23 15:53
alpha-BHC
ug/L
ND
0.050
0.012
11/10/23 15:53
beta-BHC
ug/L
ND
0.050
0.049
11/10/23 15:53
Chlordane (Technical)
ug/L
ND
0.50
0.16
11/10/23 15:53
delta-BHC
ug/L
ND
0.050
0.014
11/10/23 15:53
Dieldrin
ug/L
ND
0.050
0.015
11/10/23 15:53
Endosulfan I
ug/L
ND
0.050
0.017
11/10/23 15:53
Endosulfan 11
ug/L
ND
0.050
0.016
11/10/23 15:53
Endosulfan sulfate
ug/L
ND
0.050
0.015
11/10/23 15:53
Endrin
ug/L
ND
0.050
0.018
11/10/23 15:53
Endrin aldehyde
ug/L
ND
0.050
0.016
11/10/23 15:53
gamma-BHC (Lindane)
ug/L
ND
0.050
0.012
11/10/23 15:53
Heptachlor
ug/L
ND
0.050
0.020
11/10/23 15:53
Heptachlor epoxide
ug/L
ND
0.050
0.028
11/10/23 15:53
Methoxychlor
ug/L
ND
0.15
0.042
11/10/23 15:53
Toxaphene
ug/L
ND
0.50
0.22
11/10/23 15:53
Decachlorobiphenyl (S)
%
79
19-200
11/10/23 15:53
Tetrachloro-m-xylene (S)
%
11
10-137
11/10/23 15:53
LABORATORY CONTROL SAMPLE:
4204515
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
4,4'-DDD
ug/L
0.25
0.30
118
27-195
4,4'-DDE
ug/L
0.25
0.28
110
24-178
4,4'-DDT
ug/L
0.25
0.30
122
25-200
Aldrin
ug/L
0.25
0.18
71
14-135
alpha-BHC
ug/L
0.25
0.19
74
30-146
beta-BHC
ug/L
0.25
0.18
73
38-158
delta-BHC
ug/L
0.25
0.20
80
10-185
Dieldrin
ug/L
0.25
0.26
106
26-180
Endosulfan I
ug/L
0.25
0.18
74
36-154
Endosulfan II
ug/L
0.25
0.22
89
38-155
Endosulfan sulfate
ug/L
0.25
0.23
93
42-170
Endrin
ug/L
0.25
0.26
105
33-190
Endrin aldehyde
ug/L
0.25
0.25
100
33-153
gamma-BHC (Lindane)
ug/L
0.25
0.19
77
32-148
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 96 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
LABORATORY CONTROL SAMPLE:
4204515
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Heptachlor
ug/L
0.25
0.20
79
32-149
Heptachlor epoxide
ug/L
0.25
0.21
82
37-149
Methoxychlor
ug/L
0.75
0.76
101
35-171
Decachlorobiphenyl (S)
%
111
19-200
Tetrachloro-m-xylene (S)
%
86
10-137
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
4204516
4204517
MS
MSD
92697334001
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
4,4'-DDD
ug/L
ND
0.42
0.42
0.69
0.69
167
166
10-200
0
30
4,4'-DDE
ug/L
ND
0.42
0.42
0.63
0.69
152
167
10-188
9
30
4,4'-DDT
ug/L
ND
0.42
0.42
0.69
0.74
166
176
10-200
6
30
Aldrin
ug/L
ND
0.42
0.42
0.50
0.56
121
134
10-144
11
30
alpha-BHC
ug/L
ND
0.42
0.42
0.42
0.48
102
116
21-151
13
30
beta-BHC
ug/L
ND
0.42
0.42
0.44
0.49
106
119
21-175
11
30
delta-BHC
ug/L
ND
0.42
0.42
1.1
0.56
258
135
15-163
63
30 M1,R1
Dieldrin
ug/L
ND
0.42
0.42
0.60
0.65
143
155
10-184
8
30
Endosulfan I
ug/L
ND
0.42
0.42
0.41
0.45
97
109
11-180
11
30
Endosulfan II
ug/L
ND
0.42
0.42
0.50
0.53
120
128
13-174
6
30
Endosulfan sulfate
ug/L
ND
0.42
0.42
0.51
0.54
123
131
25-182
6
30
Endrin
ug/L
ND
0.42
0.42
0.59
0.64
142
153
10-200
8
30
Endrin aldehyde
ug/L
ND
0.42
0.42
0.64
0.67
154
161
10-167
4
30
gamma-BHC (Lindane)
ug/L
ND
0.42
0.42
0.44
0.50
107
120
13-163
11
30
Heptachlor
ug/L
ND
0.42
0.42
0.45
0.53
107
126
10-172
16
30
Heptachlor epoxide
ug/L
ND
0.42
0.42
0.53
0.64
128
153
10-168
18
30
Methoxychlor
ug/L
ND
1.2
1.2
1.7
1.8
137
142
13-183
3
30
Decachlorobiphenyl (S)
%
60
91
19-200
Tetrachloro-m-xylene (S)
%
86
105
10-137
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 97 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 815068 Analysis Method: EPA 8082A
QC Batch Method: EPA 3510C Analysis Description: 8082 GCS PCB
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92697334001, 92697334002, 92697334003, 92697334004, 92697334005
METHOD BLANK: 4219440
Matrix:
Water
Associated Lab Samples:
92697334001, 92697334002, 92697334003, 92697334004, 92697334005
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
PCB-1016 (Aroclor 1016)
ug/L
ND
0.50
0.21
11/27/23 08:35
PCB-1221 (Aroclor 1221)
ug/L
ND
0.50
0.23
11/27/23 08:35
PCB-1232 (Aroclor 1232)
ug/L
ND
0.50
0.23
11/27/23 08:35
PCB-1242 (Aroclor 1242)
ug/L
ND
0.50
0.25
11/27/23 08:35
PCB-1248 (Aroclor 1248)
ug/L
ND
0.50
0.29
11/27/23 08:35
PCB-1254 (Aroclor 1254)
ug/L
ND
0.50
0.21
11/27/23 08:35
PCB-1260 (Aroclor 1260)
ug/L
ND
0.50
0.16
11/27/23 08:35
Decachlorobiphenyl (S)
%
71
10-193
11/27/23 08:35
LABORATORY CONTROL SAMPLE: 4219441
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
PCB-1016 (Aroclor 1016) ug/L 5 5.7 115 34-137
PCB-1260 (Aroclor 1260) ug/L 5 5.1 102 39-145
Decachlorobiphenyl (S) % 124 10-193
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4219442
4219443
MS
MSD
92700038001 Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD RPD Qual
PCB-1016 (Aroclor 1016)
ug/L ND 8.3
8.3
9.7
9.1
116
110
10-153
6 30
PCB-1260 (Aroclor 1260)
ug/L ND 8.3
8.3
9.1
8.3
109
100
10-156
9 30
Decachlorobiphenyl (S)
%
124
120
10-193
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 98 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 811997 Analysis Method: EPA 8270E
QC Batch Method: EPA 3510C Analysis Description: 8270E Water APP9 RV MSSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92697334002, 92697334003
METHOD BLANK: 4204406
Associated Lab Samples: 92697334002, 92697334003
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
1,2,4,5-Tetrachlorobenzene
ug/L
ND
10.0
4.5
11/12/23 12:55
1,3,5-Trinitrobenzene
ug/L
ND
10.0
5.5
11/12/23 12:55
1,3-Dinitrobenzene
ug/L
ND
10.0
3.8
11/12/23 12:55
1,4-Naphthoquinone
ug/L
ND
5.0
4.4
11/12/23 12:55
1-Naphthalenamine
ug/L
ND
10.0
6.0
11/12/23 12:55
2,2'-Oxybis(1-chloropropane)
ug/L
ND
10.0
1.2
11/12/23 12:55
2,3,4,6-Tetrachlorophenol
ug/L
ND
10.0
1.5
11/12/23 12:55
2,4,5-Trichlorophenol
ug/L
ND
10.0
1.4
11/12/23 12:55
2,4,6-Trichlorophenol
ug/L
ND
10.0
1.6
11/12/23 12:55
2,4-Dichlorophenol
ug/L
ND
10.0
1.4
11/12/23 12:55
2,4-Dimethylphenol
ug/L
ND
10.0
1.7
11/12/23 12:55
2,4-Dinitrophenol
ug/L
ND
50.0
26.0
11/12/23 12:55
2,4-Dinitrotoluene
ug/L
ND
10.0
1.6
11/12/23 12:55
2,6-Dichlorophenol
ug/L
ND
10.0
4.2
11/12/23 12:55
2,6-Dinitrotoluene
ug/L
ND
10.0
1.7
11/12/23 12:55
2-Acetylaminofluorene
ug/L
ND
10.0
4.1
11/12/23 12:55
2-Chloronaphthalene
ug/L
ND
10.0
1.7
11/12/23 12:55
2-Chlorophenol
ug/L
ND
10.0
1.2
11/12/23 12:55
2-Methylnaphthalene
ug/L
ND
10.0
1.9
11/12/23 12:55
2-Methylphenol(o-Cresol)
ug/L
ND
10.0
1.9
11/12/23 12:55
2-Naphthalenamine
ug/L
ND
10.0
5.4
11/12/23 12:55
2-Nitroaniline
ug/L
ND
20.0
3.0
11/12/23 12:55
2-Nitrophenol
ug/L
ND
10.0
1.4
11/12/23 12:55
3&4-Methyl phenol (m&p Cresol)
ug/L
ND
10.0
1.2
11/12/23 12:55
3,3'-Dichlorobenzidine
ug/L
ND
20.0
8.1
11/12/23 12:55
3,3'-Dimethylbenzidine
ug/L
ND
50.0
31.1
11/12/23 12:55
3-Methylcholanthrene
ug/L
ND
10.0
3.7
11/12/23 12:55
3-Nitroaniline
ug/L
ND
20.0
3.8
11/12/23 12:55
4,6-Dinitro-2-methyl phenol
ug/L
ND
20.0
7.8
11/12/23 12:55
4-Aminobiphenyl
ug/L
ND
10.0
4.7
11/12/23 12:55
4-Bromophenylphenyl ether
ug/L
ND
10.0
1.8
11/12/23 12:55
4-ChIoro-3-methyl phenol
ug/L
ND
10.0
3.3
11/12/23 12:55
4-Chloroaniline
ug/L
ND
20.0
3.6
11/12/23 12:55
4-Chlorophenylphenyl ether
ug/L
ND
10.0
2.0
11/12/23 12:55
4-Nitroaniline
ug/L
ND
20.0
5.1
11/12/23 12:55
4-Nitrophenol
ug/L
ND
50.0
6.6
11/12/23 12:55
5-Nitro-o-toluidine
ug/L
ND
10.0
3.8
11/12/23 12:55
7,12-Dimethylbenz(a)anthracene
ug/L
ND
10.0
3.0
11/12/23 12:55
Acenaphthene
ug/L
ND
10.0
2.0
11/12/23 12:55
Acenaphthylene
ug/L
ND
10.0
2.0
11/12/23 12:55
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 99 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
METHOD BLANK: 4204406
Associated Lab Samples: 92697334002, 92697334003
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Acetophenone
ug/L
ND
10.0
1.5
11/12/23 12:55
Anthracene
ug/L
ND
10.0
2.3
11/12/23 12:55
Benzo(a)anthracene
ug/L
ND
10.0
2.7
11/12/23 12:55
Benzo(a)pyrene
ug/L
ND
10.0
2.8
11/12/23 12:55
Benzo(b)fluoranthene
ug/L
ND
10.0
2.6
11/12/23 12:55
Benzo(g,h,i)perylene
ug/L
ND
10.0
2.8
11/12/23 12:55
Benzo(k)fluoranthene
ug/L
ND
10.0
2.7
11/12/23 12:55
Benzyl alcohol
ug/L
ND
20.0
2.9
11/12/23 12:55
bis(2-Chloroethoxy)methane
ug/L
ND
10.0
1.8
11/12/23 12:55
bis(2-Chloroethyl) ether
ug/L
ND
10.0
1.9
11/12/23 12:55
bis(2-Ethylhexyl)phthalate
ug/L
ND
6.0
3.7
11/12/23 12:55
Butylbenzylphthalate
ug/L
ND
10.0
3.1
11/12/23 12:55
Chlorobenzilate
ug/L
ND
10.0
3.8
11/12/23 12:55
Chrysene
ug/L
ND
10.0
2.8
11/12/23 12:55
Di-n-butylphthalate
ug/L
ND
10.0
2.2
11/12/23 12:55
Di-n-octylphthalate
ug/L
ND
10.0
3.9
11/12/23 12:55
Diallate
ug/L
ND
10.0
3.4
11/12/23 12:55
Dibenz(a,h)anthracene
ug/L
ND
10.0
3.0
11/12/23 12:55
Dibenzofuran
ug/L
ND
10.0
2.1
11/12/23 12:55
Diethylphthalate
ug/L
ND
10.0
2.0
11/12/23 12:55
Dimethoate
ug/L
ND
10.0
3.7
11/12/23 12:55
Dimethylphthalate
ug/L
ND
10.0
2.1
11/12/23 12:55
Diphenylamine
ug/L
ND
10.0
3.0
11/12/23 12:55
Disulfoton
ug/L
ND
10.0
4.6
11/12/23 12:55
Ethyl methanesulfonate
ug/L
ND
20.0
3.0
11/12/23 12:55
Famphur
ug/L
ND
10.0
6.1
11/12/23 12:55
Fluoranthene
ug/L
ND
10.0
2.2
11/12/23 12:55
Fluorene
ug/L
ND
10.0
2.1
11/12/23 12:55
Hexachloro-1,3-butadiene
ug/L
ND
10.0
1.8
11/12/23 12:55
Hexachlorobenzene
ug/L
ND
10.0
2.2
11/12/23 12:55
Hexachlorocyclopentadiene
ug/L
ND
10.0
1.6
11/12/23 12:55
Hexachloroethane
ug/L
ND
10.0
1.4
11/12/23 12:55
Hexachloropropene
ug/L
ND
10.0
2.7
11/12/23 12:55
Indeno(1,2,3-cd)pyrene
ug/L
ND
10.0
2.9
11/12/23 12:55
Isodrin
ug/L
ND
10.0
2.8
11/12/23 12:55
Isophorone
ug/L
ND
10.0
1.7
11/12/23 12:55
Isosafrole
ug/L
ND
10.0
2.5
11/12/23 12:55
Kepone
ug/L
ND
20.0
14.1
11/12/23 12:55
Methapyrilene
ug/L
ND
50.0
17.0
11/12/23 12:55
Methyl methanesulfonate
ug/L
ND
5.0
3.1
11/12/23 12:55
Methyl parathion
ug/L
ND
10.0
3.7
11/12/23 12:55
N-Nitroso-di-n-butylamine
ug/L
ND
10.0
2.0
11/12/23 12:55
N-Nitroso-di-n-propylamine
ug/L
ND
10.0
1.3
11/12/23 12:55
N-Nitrosodiethylamine
ug/L
ND
10.0
2.3
11/12/23 12:55
N-Nitrosodimethylamine
ug/L
ND
10.0
1.9
11/12/23 12:55
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 100 of 130

Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
aceo Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
METHOD BLANK: 4204406
Associated Lab Samples: 92697334002, 92697334003
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
N-Nitrosodiphenylamine
ug/L
ND
10.0
3.0
11/12/23 12:55
N-Nitrosomethylethylamine
ug/L
ND
10.0
7.5
11/12/23 12:55
N-Nitrosopiperidine
ug/L
ND
10.0
2.5
11/12/23 12:55
N-Nitrosopyrrolidine
ug/L
ND
10.0
3.1
11/12/23 12:55
Nitrobenzene
ug/L
ND
10.0
1.9
11/12/23 12:55
O,O,O-Triethylphosphorothioate
ug/L
ND
10.0
2.6
11/12/23 12:55
O-Toluidine
ug/L
ND
10.0
2.6
11/12/23 12:55
P-Dimethylaminoazobenzene
ug/L
ND
5.0
2.4
11/12/23 12:55
p-Phenylenediamine
ug/L
ND
10.0
10.0
11/12/23 12:55
Parathion (Ethyl parathion)
ug/L
ND
10.0
3.9
11/12/23 12:55
Pentachlorobenzene
ug/L
ND
10.0
3.4
11/12/23 12:55
Pentachloronitrobenzene
ug/L
ND
10.0
3.3
11/12/23 12:55
Pentachlorophenol
ug/L
ND
20.0
3.8
11/12/23 12:55
Phenacetin
ug/L
ND
10.0
3.6
11/12/23 12:55
Phenanthrene
ug/L
ND
10.0
2.0
11/12/23 12:55
Phenol
ug/L
ND
10.0
1.4
11/12/23 12:55
Phorate
ug/L
ND
10.0
3.6
11/12/23 12:55
Pronamide
ug/L
ND
10.0
3.1
11/12/23 12:55
Pyrene
ug/L
ND
10.0
2.2
11/12/23 12:55
Safrole
ug/L
ND
10.0
2.3
11/12/23 12:55
Thionazin
ug/L
ND
10.0
2.9
11/12/23 12:55
2,4,6-Tribromophenol (S)
%
97
10-166
11/12/23 12:55
2-Fluorobiphenyl (S)
%
72
10-130
11/12/23 12:55
2-Fluorophenol (S)
%
64
10-130
11/12/23 12:55
Nitrobenzene-d5 (S)
%
85
10-133
11/12/23 12:55
Phenol-d6 (S)
%
49
10-130
11/12/23 12:55
Terphenyl-d14 (S)
%
115
10-193
11/12/23 12:55
LABORATORY CONTROL SAMPLE:
4204407
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,2,4,5-Tetrachlorobenzene
ug/L
50
35.7
71
18-130
1,3,5-Trinitrobenzene
ug/L
50
43.7
87
59-200
1,3-Dinitrobenzene
ug/L
50
53.4
107
51-170
1,4-Naphthoquinone
ug/L
50
35.8
72
32-132
1-Naphthalenamine
ug/L
50
39.4
79
35-140
2,2'-Oxybis(1-chloropropane)
ug/L
50
34.9
70
23-130
2,3,4,6-Tetrachlorophenol
ug/L
50
48.0
96
38-154
2,4,5-Trichlorophenol
ug/L
50
47.0
94
36-150
2,4,6-Trichlorophenol
ug/L
50
40.9
82
30-151
2,4-Dichlorophenol
ug/L
50
40.0
80
36-140
2,4-Dimethylphenol
ug/L
50
43.1
86
36-155
2,4-Dinitrophenol
ug/L
250
248
99
10-169
2,4-Dinitrotoluene
ug/L
50
51.4
103
46-160
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 101 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
LABORATORY CONTROL SAMPLE:
Parameter
4204407
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
2,6-Dichlorophenol
ug/L
50
42.5
85
34-156
2,6-Dinitrotoluene
ug/L
50
49.9
100
47-161
2-Acetylaminofluorene
ug/L
50
54.5
109
39-184
2-Chloronaphthalene
ug/L
50
34.2
68
29-134
2-Chlorophenol
ug/L
50
37.5
75
29-130
2-Methylnaphthalene
ug/L
50
35.8
72
26-130
2-Methylphenol(o-Cresol)
ug/L
50
35.3
71
32-130
2-Naphthalenamine
ug/L
50
47.3
95
23-145
2-Nitroaniline
ug/L
100
89.9
90
41-150
2-Nitrophenol
ug/L
50
40.7
81
31-145
3&4-Methyl phenol (m&p Cresol)
ug/L
50
34.2
68
29-130
3,3'-Dichlorobenzidine
ug/L
100
121
121
46-153
3,3'-Dimethylbenzidine
ug/L
100
147
147
24-200
3-Methylcholanthrene
ug/L
50
60.7
121
31-195
3-Nitroaniline
ug/L
100
96.4
96
47-156
4,6-Dinitro-2-methyl phenol
ug/L
100
113
113
23-161
4-Aminobiphenyl
ug/L
50
34.6
69
26-151
4-Bromophenylphenyl ether
ug/L
50
49.3
99
45-143
4-ChIoro-3-methyl phenol
ug/L
100
89.9
90
42-143
4-Chloroaniline
ug/L
100
76.7
77
37-135
4-Chlorophenylphenyl ether
ug/L
50
44.7
89
43-140
4-Nitroaniline
ug/L
100
108
108
47-157
4-Nitrophenol
ug/L
250
165
66
10-130
5-Nitro-o-toluidine
ug/L
50
58.8
118
54-170
7,12-Dimethylbenz(a)anthracene
ug/L
50
57.3
115
29-176
Acenaphthene
ug/L
50
39.3
79
38-138
Acenaphthylene
ug/L
50
40.0
80
39-139
Acetophenone
ug/L
50
40.0
80
34-135
Anthracene
ug/L
50
51.2
102
45-136
Benzo(a)anthracene
ug/L
50
58.6
117
52-151
Benzo(a)pyrene
ug/L
50
58.8
118
46-165
Benzo(b)fluoranthene
ug/L
50
63.8
128
44-170
Benzo(g,h,i)perylene
ug/L
50
60.2
120
39-171
Benzo(k)fluoranthene
ug/L
50
58.2
116
43-168
Benzyl alcohol
ug/L
100
76.9
77
33-134
bis(2-Chloroethoxy)methane
ug/L
50
39.9
80
37-140
bis(2-Chloroethyl) ether
ug/L
50
38.2
76
33-136
bis(2-Ethylhexyl)phthalate
ug/L
50
63.1
126
50-169
Butylbenzylphthalate
ug/L
50
62.4
125
50-174
Chlorobenzilate
ug/L
50
63.7
127
46-167
Chrysene
ug/L
50
58.0
116
52-148
Di-n-butylphthalate
ug/L
50
55.5
111
51-154
Di-n-octylphthalate
ug/L
50
62.6
125
44-170
Diallate
ug/L
50
53.1
106
49-147
Dibenz(a,h)anthracene
ug/L
50
59.4
119
41-171
Dibenzofuran
ug/L
50
39.6
79
42-157
Diethylphthalate
ug/L
50
48.9
98
50-149
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 102 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
LABORATORY CONTROL SAMPLE:
Parameter
4204407
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Dimethoate
ug/L
50
62.8
126
52-169
Dimethylphthalate
ug/L
50
46.6
93
47-146
Diphenylamine
ug/L
50
49.7
99
53-142
Disulfoton
ug/L
50
54.4
109
45-135
Ethyl methanesulfonate
ug/L
50
40.1
80
27-146
Famphur
ug/L
100
91.0
91
13-130
Fluoranthene
ug/L
50
54.1
108
51-152
Fluorene
ug/L
50
45.1
90
46-143
Hexachloro-1,3-butadiene
ug/L
50
23.2
46
10-130
Hexachlorobenzene
ug/L
50
48.9
98
40-139
Hexachlorocyclopentadiene
ug/L
50
29.7
59
10-130
Hexachloroethane
ug/L
50
18.1
36
10-130
Hexachloropropene
ug/L
50
20.7
41
10-130
Indeno(1,2,3-cd)pyrene
ug/L
50
58.2
116
40-172
Isodrin
ug/L
50
52.6
105
50-150
Isophorone
ug/L
50
41.3
83
37-143
Isosafrole
ug/L
50
35.7
71
35-130
Kepone
ug/L
100
66.1
66
12-130
Methapyrilene
ug/L
50
ND
30
10-188
Methyl methanesulfonate
ug/L
50
36.4
73
24-135
Methyl parathion
ug/L
50
68.8
138
59-174
N-Nitroso-di-n-butylamine
ug/L
50
40.8
82
33-130
N-Nitroso-di-n-propylamine
ug/L
50
40.8
82
38-145
N-Nitrosodiethylamine
ug/L
50
42.6
85
26-145
N-Nitrosodimethylamine
ug/L
50
31.9
64
30-130
N-Nitrosodiphenylamine
ug/L
50
49.7
99
46-144
N-Nitrosomethylethylamine
ug/L
50
41.0
82
19-138
N-Nitrosopiperidine
ug/L
50
44.7
89
35-147
N-Nitrosopyrrolidine
ug/L
50
41.2
82
31-142
Nitrobenzene
ug/L
50
37.6
75
33-136
O,O,O-Triethylphosphorothioate
ug/L
50
43.3
87
27-136
O-Toluidine
ug/L
50
37.3
75
27-140
P-Dimethylaminoazobenzene
ug/L
50
30.8
62
23-130
p-Phenylenediamine
ug/L
ND
Parathion (Ethyl parathion)
ug/L
50
68.5
137
59-171
Pentachlorobenzene
ug/L
50
41.0
82
42-138
Pentachloronitrobenzene
ug/L
50
66.5
133
64-185
Pentachlorophenol
ug/L
100
112
112
19-156
Phenacetin
ug/L
50
61.3
123
57-174
Phenanthrene
ug/L
50
51.9
104
49-143
Phenol
ug/L
50
25.0
50
18-130
Phorate
ug/L
50
56.2
112
41-200
Pronamide
ug/L
50
60.5
121
59-174
Pyrene
ug/L
50
58.3
117
48-156
Safrole
ug/L
50
40.0
80
31-136
Thionazin
ug/L
50
57.5
115
52-151
2,4,6-Tribromophenol (S)
%
119
10-166
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 103 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
LABORATORY CONTROL SAMPLE:
4204407
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
2-Fluorobiphenyl (S)
%
77
10-130
2-Fluorophenol(S)
%
63
10-130
Nitrobenzene-d5 (S)
%
86
10-133
Phenol-d6 (S)
%
53
10-130
Terphenyl-d14 (S)
%
129
10-193
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
4204408
4204409
MS
MSD
92697057002
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result % Rec % Rec
Limits
RPD
RPD Qual
1,2,4,5-Tetrachlorobenzene
ug/L
ND
83.3
83.3
76.5
73.0
92
88
10-136
5
30
1,3,5-Trinitrobenzene
ug/L
ND
83.3
83.3
71.2
69.0
85
83
32-200
3
30
1,3-Dinitrobenzene
ug/L
ND
83.3
83.3
93.6
94.1
112
113
30-173
1
30
1,4-Naphthoquinone
ug/L
ND
83.3
83.3
84.9
73.0
102
88
10-144
15
30
1-Naphthalenamine
ug/L
ND
83.3
83.3
75.6
88.4
91
106
10-156
16
30
2,2'-Oxybis(1-
ug/L
ND
83.3
83.3
73.1
73.2
88
88
10-132
0
30
chloropropane)
2,3,4,6-Tetrachlorophenol
ug/L
ND
83.3
83.3
82.3
3.5J
99
4
10-185
30 M1
2,4,5-Trichlorophenol
ug/L
ND
83.3
83.3
84.2
16.3J
101
20
10-174
30
2,4,6-Trichlorophenol
ug/L
ND
83.3
83.3
81.6
6.OJ
98
7
10-173
30 M1
2,4-Dichlorophenol
ug/L
ND
83.3
83.3
82.7
27.0
99
32
10-153
102
30 R1
2,4-Dimethylphenol
ug/L
ND
83.3
83.3
89.3
90.6
107
109
12-157
1
30
2,4-Dinitrophenol
ug/L
ND
417
417
436
ND
105
1
10-165
30 M1
2,4-Dinitrotoluene
ug/L
ND
83.3
83.3
87.1
90.2
105
108
29-168
4
30
2,6-Dichlorophenol
ug/L
ND
83.3
83.3
88.2
7.9J
106
9
10-178
30 M1
2,6-Dinitrotoluene
ug/L
ND
83.3
83.3
90.2
97.3
108
117
28-168
8
30
2-Acetylam inofl uorene
ug/L
ND
83.3
83.3
87.5
101
105
122
20-194
15
30
2-Chloronaphthalene
ug/L
ND
83.3
83.3
73.9
77.6
89
93
11-136
5
30
2-Chlorophenol
ug/L
ND
83.3
83.3
76.8
28.1
92
34
10-134
93
30 R1
2-Methyl naphthalene
ug/L
ND
83.3
83.3
82.5
84.3
99
101
10-131
2
30
2-Methyl phenol(o-Cresol)
ug/L
ND
83.3
83.3
73.9
70.8
89
85
10-130
4
30
2-Naphthalenamine
ug/L
ND
83.3
83.3
40.1
71.5
48
86
10-147
56
30 R1
2-Nitroaniline
ug/L
ND
167
167
158
170
95
102
19-156
7
30
2-Nitrophenol
ug/L
ND
83.3
83.3
84.4
26.9
101
32
10-160
103
30 R1
3&4-Methylphenol(m&p
ug/L
ND
83.3
83.3
70.8
65.4
85
78
10-132
8
30
Cresol)
3,3'-Dichlorobenzidine
ug/L
ND
167
167
179
199
107
119
10-173
11
30
3,3'-Dimethylbenzidine
ug/L
ND
167
167
194
394
116
236
10-200
68
30 M1,R1
3-Methylcholanthrene
ug/L
ND
83.3
83.3
100
101
120
121
10-200
1
30
3-Nitroaniline
ug/L
ND
167
167
170
186
102
112
19-169
9
30
4,6-Dinitro-2-methylphenol
ug/L
ND
167
167
192
ND
115
2
10-178
30 M1
4-Aminobiphenyl
ug/L
ND
83.3
83.3
61.4
83.9
74
101
10-170
31
30 R1
4-Bromophenylphenyl ether
ug/L
ND
83.3
83.3
85.8
93.4
103
112
28-149
8
30
4-Chloro-3-methylphenol
ug/L
ND
167
167
173
160
104
96
18-148
8
30
4-Chloroaniline
ug/L
ND
167
167
161
171
96
103
10-141
6
30
4-Chlorophenylphenyl ether
ug/L
ND
83.3
83.3
86.1
91.9
103
110
24-144
7
30
Results presented
on this page are in the units
indicated by the
"Units" column except where
an alternate unit is presented to the right of the result.
REPORT
OF LABORATORY ANALYSIS
This report shall not be reproduced,
except
in full,
Date: 11 /28/2023 02:34 PM
without
the written consent of Pace Analytical Services, LLC.
Page 104 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4204408
MS
92697057002 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
4204409
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
4-Nitroaniline
ug/L
ND
167
167
162
180
97
108
18-170
10
30
4-Nitrophenol
ug/L
ND
417
417
277
11.7J
66
3
10-130
30 M1
5-Nitro-o-toluidine
ug/L
ND
83.3
83.3
96.3
97.6
116
117
38-167
1
30
7,12-
ug/L
ND
83.3
83.3
96.8
97.2
116
117
10-182
0
30
Dimethylbenz(a)anthracene
Acenaphthene
ug/L
ND
83.3
83.3
79.1
84.6
95
101
18-142
7
30
Acenaphthylene
ug/L
ND
83.3
83.3
80.8
85.5
97
103
18-143
6
30
Acetophenone
ug/L
ND
83.3
83.3
82.2
84.4
99
101
10-142
3
30
Anthracene
ug/L
ND
83.3
83.3
83.0
89.0
100
107
32-138
7
30
Benzo(a)anth race ne
ug/L
ND
83.3
83.3
90.4
96.9
108
116
41-155
7
30
Benzo(a)pyrene
ug/L
ND
83.3
83.3
92.5
99.5
111
119
10-167
7
30
Benzo(b)fluoranthene
ug/L
ND
83.3
83.3
101
108
122
130
31-172
6
30
Benzo(g,h,i)perylene
ug/L
ND
83.3
83.3
84.9
93.5
102
112
26-177
10
30
Benzo(k)fluoranthene
ug/L
ND
83.3
83.3
92.2
98.2
111
118
31-168
6
30
Benzyl alcohol
ug/L
ND
167
167
158
158
95
95
10-136
0
30
bis(2-
ug/L
ND
83.3
83.3
81.3
84.2
98
101
12-143
3
30
Chloroethoxy)methane
bis(2-Chloroethyl) ether
ug/L
ND
83.3
83.3
77.3
78.3
93
94
10-139
1
30
bis(2- Ethyl hexyl)phthalate
ug/L
ND
83.3
83.3
98.0
104
118
124
41-173
6
30
Butylbenzylphthalate
ug/L
ND
83.3
83.3
99.1
105
119
127
38-182
6
30
Chlorobenzilate
ug/L
ND
83.3
83.3
104
104
124
125
33-175
0
30
Chrysene
ug/L
ND
83.3
83.3
88.7
95.9
106
115
41-152
8
30
Di-n-butylphthalate
ug/L
ND
83.3
83.3
87.8
93.2
105
112
37-162
6
30
Di-n-octylphthalate
ug/L
ND
83.3
83.3
102
107
123
129
36-176
5
30
Diallate
ug/L
ND
83.3
83.3
89.4
89.8
107
108
26-155
0
30
Dibenz(a,h)anthracene
ug/L
ND
83.3
83.3
87.3
95.4
105
114
29-175
9
30
Dibenzofuran
ug/L
ND
83.3
83.3
78.3
83.6
94
100
23-144
7
30
Diethylphthalate
ug/L
ND
83.3
83.3
83.5
90.1
100
108
33-154
8
30
Dimethoate
ug/L
ND
83.3
83.3
99.1
95.2
119
114
41-169
4
30
Dimethylphthalate
ug/L
ND
83.3
83.3
81.8
87.9
98
105
29-150
7
30
Diphenylamine
ug/L
ND
83.3
83.3
82.6
88.8
99
107
34-146
7
30
Disulfoton
ug/L
ND
83.3
83.3
90.5
91.0
109
109
36-133
0
30
Ethyl methanesulfonate
ug/L
ND
83.3
83.3
81.1
78.3
97
94
10-147
4
30
Famphur
ug/L
ND
167
167
99.8
58.6
60
35
10-130
52
30 R1
Fluoranthene
ug/L
ND
83.3
83.3
85.6
92.1
103
111
40-156
7
30
Fluorene
ug/L
ND
83.3
83.3
84.1
89.7
101
108
26-148
7
30
Hexachloro-1,3-butadiene
ug/L
ND
83.3
83.3
69.5
62.7
83
75
10-130
10
30
Hexachlorobenzene
ug/L
ND
83.3
83.3
84.2
90.6
101
109
27-145
7
30
Hexachlorocyclopentadiene
ug/L
ND
83.3
83.3
78.8
76.0
95
91
10-130
4
30
Hexachloroethane
ug/L
ND
83.3
83.3
56.6
46.9
68
56
10-130
19
30
Hexachloropropene
ug/L
ND
83.3
83.3
60.2
48.1
72
58
10-130
22
30
Indeno(1,2,3-cd)pyrene
ug/L
ND
83.3
83.3
85.1
94.0
102
113
28-176
10
30
Isodrin
ug/L
ND
83.3
83.3
86.8
87.1
104
104
33-153
0
30
Isophorone
ug/L
ND
83.3
83.3
83.6
87.9
100
105
14-145
5
30
Isosafrole
ug/L
ND
83.3
83.3
76.0
75.2
91
90
13-136
1
30
Kepone
ug/L
ND
167
167
85.4
56.4
51
34
10-130
41
30 R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 105 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
4204408
4204409
MS
MSD
92697057002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Methapyrilene
ug/L
ND
83.3
83.3
73.9J
109
89
131
10-200
30
Methyl methanesulfonate
ug/L
ND
83.3
83.3
72.3
68.1
87
82
10-138
6
30
Methyl parathion
ug/L
ND
83.3
83.3
110
107
132
128
44-177
3
30
N-Nitroso-di-n-butylamine
ug/L
ND
83.3
83.3
83.7
85.6
100
103
14-133
2
30
N-Nitroso-di-n-propylamine
ug/L
ND
83.3
83.3
86.5
86.3
104
104
12-149
0
30
N-Nitrosodiethylamine
ug/L
ND
83.3
83.3
86.4
82.5
104
99
10-148
5
30
N-Nitrosodimethylamine
ug/L
ND
83.3
83.3
65.7
63.9
79
77
10-130
3
30
N-Nitrosodiphenylamine
ug/L
ND
83.3
83.3
82.6
88.8
99
107
29-149
7
30
N-Nitrosomethylethylamine
ug/L
ND
83.3
83.3
74.4
68.7
89
82
10-139
8
30
N-Nitrosopiperidine
ug/L
ND
83.3
83.3
92.1
89.9
111
108
14-151
2
30
N-Nitrosopyrrolidine
ug/L
ND
83.3
83.3
85.2
82.2
102
99
14-143
4
30
Nitrobenzene
ug/L
ND
83.3
83.3
77.2
78.7
93
94
10-145
2
30
0,0,0-
ug/L
ND
83.3
83.3
93.6
91.9
112
110
10-142
2
30
Triethylphosphorothioate
O-Toluidine
ug/L
ND
83.3
83.3
81.6
81.6
98
98
10-137
0
30
P-
ug/L
ND
83.3
83.3
50.9
51.4
61
62
17-130
1
30
Dimethylaminoazobenzene
p-Phenylenediamine
ug/L
ND
ND
ND
30
Parathion (Ethyl parathion)
ug/L
ND
83.3
83.3
111
112
133
134
45-174
0
30
Pentachlorobenzene
ug/L
ND
83.3
83.3
83.0
82.9
100
100
20-143
0
30
Pentachloronitrobenzene
ug/L
ND
83.3
83.3
110
98.4
132
118
39-186
11
30
Pentachlorophenol
ug/L
ND
167
167
183
ND
110
3
10-178
30 M1
Phenacetin
ug/L
ND
83.3
83.3
96.5
97.5
116
117
36-185
1
30
Phenanthrene
ug/L
ND
83.3
83.3
82.8
89.2
99
107
36-146
7
30
Phenol
ug/L
ND
83.3
83.3
50.0
29.3
60
35
10-130
52
30 R1
Phorate
ug/L
ND
83.3
83.3
96.0
95.9
115
115
26-200
0
30
Pronamide
ug/L
ND
83.3
83.3
98.0
98.2
118
118
40-181
0
30
Pyrene
ug/L
ND
83.3
83.3
91.0
96.9
109
116
42-156
6
30
Safrole
ug/L
ND
83.3
83.3
86.8
85.1
104
102
10-142
2
30
Thionazin
ug/L
ND
83.3
83.3
96.9
98.0
116
118
31-159
1
30
2,4,6-Tribromophenol (S)
%
98
17
10-166
2-Fluorobiphenyl (S)
%
79
81
10-130
2-Fluorophenol (S)
%
65
10
10-130
Nitrobenzene-d5 (S)
%
86
87
10-133
Phenol-d6 (S)
%
54
30
10-130
Terphenyl-d14 (S)
%
95
103
10-193
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 106 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 812141 Analysis Method: EPA 8270E
QC Batch Method: EPA 3510C Analysis Description: 8270E Water APP9 RV MSSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92697334001, 92697334004, 92697334005
METHOD BLANK: 4205196 Matrix:
Associated Lab Samples: 92697334001, 92697334004, 92697334005
Blank
Parameter Units Result
Water
Reporting
Limit
MDL
Analyzed
1,2,4,5-Tetrachlorobenzene
ug/L
ND
10.0
4.5
11/12/23 04:39
1,3,5-Trinitrobenzene
ug/L
ND
10.0
5.5
11/12/23 04:39
1,3-Dinitrobenzene
ug/L
ND
10.0
3.8
11/12/23 04:39
1,4-Naphthoquinone
ug/L
ND
5.0
4.4
11/12/23 04:39
1-Naphthalenamine
ug/L
ND
10.0
6.0
11/12/23 04:39
2,2'-Oxybis(1-chloropropane)
ug/L
ND
10.0
1.2
11/12/23 04:39
2,3,4,6-Tetrachlorophenol
ug/L
ND
10.0
1.5
11/12/23 04:39
2,4,5-Trichlorophenol
ug/L
ND
10.0
1.4
11/12/23 04:39
2,4,6-Trichlorophenol
ug/L
ND
10.0
1.6
11/12/23 04:39
2,4-Dichlorophenol
ug/L
ND
10.0
1.4
11/12/23 04:39
2,4-Dimethylphenol
ug/L
ND
10.0
1.7
11/12/23 04:39
2,4-Dinitrophenol
ug/L
ND
50.0
26.0
11/12/23 04:39
2,4-Dinitrotoluene
ug/L
ND
10.0
1.6
11/12/23 04:39
2,6-Dichlorophenol
ug/L
ND
10.0
4.2
11/12/23 04:39
2,6-Dinitrotoluene
ug/L
ND
10.0
1.7
11/12/23 04:39
2-Acetylaminofluorene
ug/L
ND
10.0
4.1
11/12/23 04:39
2-Chloronaphthalene
ug/L
ND
10.0
1.7
11/12/23 04:39
2-Chlorophenol
ug/L
ND
10.0
1.2
11/12/23 04:39
2-Methylnaphthalene
ug/L
ND
10.0
1.9
11/12/23 04:39
2-Methylphenol(o-Cresol)
ug/L
ND
10.0
1.9
11/12/23 04:39
2-Naphthalenamine
ug/L
ND
10.0
5.4
11/12/23 04:39
2-Nitroaniline
ug/L
ND
20.0
3.0
11/12/23 04:39
2-Nitrophenol
ug/L
ND
10.0
1.4
11/12/23 04:39
3&4-Methyl phenol (m&p Cresol)
ug/L
ND
10.0
1.2
11/12/23 04:39
3,3'-Dichlorobenzidine
ug/L
ND
20.0
8.1
11/12/23 04:39
3,3'-Dimethylbenzidine
ug/L
ND
50.0
31.1
11/12/23 04:39
3-Methylcholanthrene
ug/L
ND
10.0
3.7
11/12/23 04:39
3-Nitroaniline
ug/L
ND
20.0
3.8
11/12/23 04:39
4,6-Dinitro-2-methyl phenol
ug/L
ND
20.0
7.8
11/12/23 04:39
4-Aminobiphenyl
ug/L
ND
10.0
4.7
11/12/23 04:39
4-Bromophenylphenyl ether
ug/L
ND
10.0
1.8
11/12/23 04:39
4-ChIoro-3-methyl phenol
ug/L
ND
10.0
3.3
11/12/23 04:39
4-Chloroaniline
ug/L
ND
20.0
3.6
11/12/23 04:39
4-Chlorophenylphenyl ether
ug/L
ND
10.0
2.0
11/12/23 04:39
4-Nitroaniline
ug/L
ND
20.0
5.1
11/12/23 04:39
4-Nitrophenol
ug/L
ND
50.0
6.6
11/12/23 04:39
5-Nitro-o-toluidine
ug/L
ND
10.0
3.8
11/12/23 04:39
7,12-Dimethylbenz(a)anthracene
ug/L
ND
10.0
3.0
11/12/23 04:39
Acenaphthene
ug/L
ND
10.0
2.0
11/12/23 04:39
Acenaphthylene
ug/L
ND
10.0
2.0
11/12/23 04:39
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 107 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
METHOD BLANK: 4205196 Matrix:
Associated Lab Samples: 92697334001, 92697334004, 92697334005
Blank
Parameter Units Result
Water
Reporting
Limit
MDL
Analyzed
Acetophenone
ug/L
ND
10.0
1.5
11/12/23 04:39
Anthracene
ug/L
ND
10.0
2.3
11/12/23 04:39
Benzo(a)anthracene
ug/L
ND
10.0
2.7
11/12/23 04:39
Benzo(a)pyrene
ug/L
ND
10.0
2.8
11/12/23 04:39
Benzo(b)fluoranthene
ug/L
ND
10.0
2.6
11/12/23 04:39
Benzo(g,h,i)perylene
ug/L
ND
10.0
2.8
11/12/23 04:39
Benzo(k)fluoranthene
ug/L
ND
10.0
2.7
11/12/23 04:39
Benzyl alcohol
ug/L
ND
20.0
2.9
11/12/23 04:39
bis(2-Chloroethoxy)methane
ug/L
ND
10.0
1.8
11/12/23 04:39
bis(2-Chloroethyl) ether
ug/L
ND
10.0
1.9
11/12/23 04:39
bis(2-Ethylhexyl)phthalate
ug/L
ND
6.0
3.7
11/12/23 04:39
Butylbenzylphthalate
ug/L
ND
10.0
3.1
11/12/23 04:39
Chlorobenzilate
ug/L
ND
10.0
3.8
11/12/23 04:39
Chrysene
ug/L
ND
10.0
2.8
11/12/23 04:39
Di-n-butylphthalate
ug/L
ND
10.0
2.2
11/12/23 04:39
Di-n-octylphthalate
ug/L
ND
10.0
3.9
11/12/23 04:39
Diallate
ug/L
ND
10.0
3.4
11/12/23 04:39
Dibenz(a,h)anthracene
ug/L
ND
10.0
3.0
11/12/23 04:39
Dibenzofuran
ug/L
ND
10.0
2.1
11/12/23 04:39
Diethylphthalate
ug/L
ND
10.0
2.0
11/12/23 04:39
Dimethoate
ug/L
ND
10.0
3.7
11/12/23 04:39
Dimethylphthalate
ug/L
ND
10.0
2.1
11/12/23 04:39
Diphenylamine
ug/L
ND
10.0
3.0
11/12/23 04:39
Disulfoton
ug/L
ND
10.0
4.6
11/12/23 04:39
Ethyl methanesulfonate
ug/L
ND
20.0
3.0
11/12/23 04:39
Famphur
ug/L
ND
10.0
6.1
11/12/23 04:39
Fluoranthene
ug/L
ND
10.0
2.2
11/12/23 04:39
Fluorene
ug/L
ND
10.0
2.1
11/12/23 04:39
Hexachloro-1,3-butadiene
ug/L
ND
10.0
1.8
11/12/23 04:39
Hexachlorobenzene
ug/L
ND
10.0
2.2
11/12/23 04:39
Hexachlorocyclopentadiene
ug/L
ND
10.0
1.6
11/12/23 04:39
Hexachloroethane
ug/L
ND
10.0
1.4
11/12/23 04:39
Hexachloropropene
ug/L
ND
10.0
2.7
11/12/23 04:39
Indeno(1,2,3-cd)pyrene
ug/L
ND
10.0
2.9
11/12/23 04:39
Isodrin
ug/L
ND
10.0
2.8
11/12/23 04:39
Isophorone
ug/L
ND
10.0
1.7
11/12/23 04:39
Isosafrole
ug/L
ND
10.0
2.5
11/12/23 04:39
Kepone
ug/L
ND
20.0
14.1
11/12/23 04:39
Methapyrilene
ug/L
ND
50.0
17.0
11/12/23 04:39
Methyl methanesulfonate
ug/L
ND
5.0
3.1
11/12/23 04:39
Methyl parathion
ug/L
ND
10.0
3.7
11/12/23 04:39
N-Nitroso-di-n-butylamine
ug/L
ND
10.0
2.0
11/12/23 04:39
N-Nitroso-di-n-propylamine
ug/L
ND
10.0
1.3
11/12/23 04:39
N-Nitrosodiethylamine
ug/L
ND
10.0
2.3
11/12/23 04:39
N-Nitrosodimethylamine
ug/L
ND
10.0
1.9
11/12/23 04:39
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 108 of 130

Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
aceo Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
METHOD BLANK: 4205196 Matrix:
Associated Lab Samples: 92697334001, 92697334004, 92697334005
Blank
Parameter Units Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
N-Nitrosodiphenylamine
ug/L
ND
10.0
3.0
11/12/23 04:39
N-Nitrosomethylethylamine
ug/L
ND
10.0
7.5
11/12/23 04:39
N-Nitrosopiperidine
ug/L
ND
10.0
2.5
11/12/23 04:39
N-Nitrosopyrrolidine
ug/L
ND
10.0
3.1
11/12/23 04:39
Nitrobenzene
ug/L
ND
10.0
1.9
11/12/23 04:39
O,O,O-Triethylphosphorothioate
ug/L
ND
10.0
2.6
11/12/23 04:39
O-Toluidine
ug/L
ND
10.0
2.6
11/12/23 04:39
P-Dimethylaminoazobenzene
ug/L
ND
5.0
2.4
11/12/23 04:39
p-Phenylenediamine
ug/L
ND
10.0
10.0
11/12/23 04:39
Parathion (Ethyl parathion)
ug/L
ND
10.0
3.9
11/12/23 04:39
Pentachlorobenzene
ug/L
ND
10.0
3.4
11/12/23 04:39
Pentachloronitrobenzene
ug/L
ND
10.0
3.3
11/12/23 04:39
Pentachlorophenol
ug/L
ND
20.0
3.8
11/12/23 04:39
Phenacetin
ug/L
ND
10.0
3.6
11/12/23 04:39
Phenanthrene
ug/L
ND
10.0
2.0
11/12/23 04:39
Phenol
ug/L
ND
10.0
1.4
11/12/23 04:39
Phorate
ug/L
ND
10.0
3.6
11/12/23 04:39
Pronamide
ug/L
ND
10.0
3.1
11/12/23 04:39
Pyrene
ug/L
ND
10.0
2.2
11/12/23 04:39
Safrole
ug/L
ND
10.0
2.3
11/12/23 04:39
Thionazin
ug/L
ND
10.0
2.9
11/12/23 04:39
2,4,6-Tribromophenol (S)
%
82
10-166
11/12/23 04:39
2-Fluorobiphenyl (S)
%
63
10-130
11/12/23 04:39
2-Fluorophenol (S)
%
54
10-130
11/12/23 04:39
Nitrobenzene-d5 (S)
%
74
10-133
11/12/23 04:39
Phenol-d6 (S)
%
41
10-130
11/12/23 04:39
Terphenyl-d14 (S)
%
122
10-193
11/12/23 04:39
LABORATORY CONTROL SAMPLE:
4205197
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,2,4,5-Tetrachlorobenzene
ug/L
50
45.1
90
18-130
1,3,5-Trinitrobenzene
ug/L
50
46.9
94
59-200
1,3-Dinitrobenzene
ug/L
50
59.0
118
51-170
1,4-Naphthoquinone
ug/L
50
48.8
98
32-132
1-Naphthalenamine
ug/L
50
41.0
82
35-140
2,2'-Oxybis(1-chloropropane)
ug/L
50
42.2
84
23-130
2,3,4,6-Tetrachlorophenol
ug/L
50
46.1
92
38-154
2,4,5-Trichlorophenol
ug/L
50
46.0
92
36-150
2,4,6-Trichlorophenol
ug/L
50
45.1
90
30-151
2,4-Dichlorophenol
ug/L
50
46.6
93
36-140
2,4-Dimethylphenol
ug/L
50
48.7
97
36-155
2,4-Dinitrophenol
ug/L
250
259
104
10-169
2,4-Dinitrotoluene
ug/L
50
48.7
97
46-160
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 109 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
LABORATORY CONTROL SAMPLE:
Parameter
4205197
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
2,6-Dichlorophenol
ug/L
50
56.4
113
34-156
2,6-Dinitrotoluene
ug/L
50
49.6
99
47-161
2-Acetylaminofluorene
ug/L
50
66.8
134
39-184
2-Chloronaphthalene
ug/L
50
38.8
78
29-134
2-Chlorophenol
ug/L
50
44.9
90
29-130
2-Methylnaphthalene
ug/L
50
43.6
87
26-130
2-Methylphenol(o-Cresol)
ug/L
50
41.9
84
32-130
2-Naphthalenamine
ug/L
50
42.4
85
23-145
2-Nitroaniline
ug/L
100
91.7
92
41-150
2-Nitrophenol
ug/L
50
48.6
97
31-145
3&4-Methyl phenol (m&p Cresol)
ug/L
50
39.8
80
29-130
3,3'-Dichlorobenzidine
ug/L
100
104
104
46-153
3,3'-Dimethylbenzidine
ug/L
100
ND
22
24-200 L2
3-Methylcholanthrene
ug/L
50
63.0
126
31-195
3-Nitroaniline
ug/L
100
95.5
95
47-156
4,6-Dinitro-2-methyl phenol
ug/L
100
110
110
23-161
4-Aminobiphenyl
ug/L
50
32.5
65
26-151
4-Bromophenylphenyl ether
ug/L
50
47.8
96
45-143
4-ChIoro-3-methyl phenol
ug/L
100
94.9
95
42-143
4-Chloroaniline
ug/L
100
88.3
88
37-135
4-Chlorophenylphenyl ether
ug/L
50
46.1
92
43-140
4-Nitroaniline
ug/L
100
92.8
93
47-157
4-Nitrophenol
ug/L
250
149
60
10-130
5-Nitro-o-toluidine
ug/L
50
61.5
123
54-170
7,12-Dimethylbenz(a)anthracene
ug/L
50
56.6
113
29-176
Acenaphthene
ug/L
50
41.2
82
38-138
Acenaphthylene
ug/L
50
42.4
85
39-139
Acetophenone
ug/L
50
47.7
95
34-135
Anthracene
ug/L
50
46.2
92
45-136
Benzo(a)anthracene
ug/L
50
51.6
103
52-151
Benzo(a)pyrene
ug/L
50
51.4
103
46-165
Benzo(b)fluoranthene
ug/L
50
57.6
115
44-170
Benzo(g,h,i)perylene
ug/L
50
48.9
98
39-171
Benzo(k)fluoranthene
ug/L
50
50.8
102
43-168
Benzyl alcohol
ug/L
100
91.6
92
33-134
bis(2-Chloroethoxy)methane
ug/L
50
47.1
94
37-140
bis(2-Chloroethyl) ether
ug/L
50
45.6
91
33-136
bis(2-Ethylhexyl)phthalate
ug/L
50
56.0
112
50-169
Butylbenzylphthalate
ug/L
50
55.6
111
50-174
Chlorobenzilate
ug/L
50
67.0
134
46-167
Chrysene
ug/L
50
51.0
102
52-148
Di-n-butylphthalate
ug/L
50
49.6
99
51-154
Di-n-octylphthalate
ug/L
50
57.7
115
44-170
Diallate
ug/L
50
56.4
113
49-147
Dibenz(a,h)anthracene
ug/L
50
49.7
99
41-171
Dibenzofuran
ug/L
50
41.3
83
42-157
Diethylphthalate
ug/L
50
46.0
92
50-149
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 110 of 130

Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
aceo Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
LABORATORY CONTROL SAMPLE:
Parameter
4205197
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Dimethoate
ug/L
50
65.1
130
52-169
Dimethylphthalate
ug/L
50
45.3
91
47-146
Diphenylamine
ug/L
50
46.4
93
53-142
Disulfoton
ug/L
50
51.1
102
45-135
Ethyl methanesulfonate
ug/L
50
52.8
106
27-146
Famphur
ug/L
100
102
102
13-130
Fluoranthene
ug/L
50
48.7
97
51-152
Fluorene
ug/L
50
44.5
89
46-143
Hexachloro-1,3-butadiene
ug/L
50
35.9
72
10-130
Hexachlorobenzene
ug/L
50
47.2
94
40-139
Hexachlorocyclopentadiene
ug/L
50
42.6
85
10-130
Hexachloroethane
ug/L
50
27.1
54
10-130
Hexachloropropene
ug/L
50
36.1
72
10-130
Indeno(1,2,3-cd)pyrene
ug/L
50
48.4
97
40-172
Isodrin
ug/L
50
56.2
112
50-150
Isophorone
ug/L
50
47.3
95
37-143
Isosafrole
ug/L
50
45.6
91
35-130
Kepone
ug/L
100
79.6
80
12-130
Methapyrilene
ug/L
50
ND
6
10-188 L2
Methyl methanesulfonate
ug/L
50
46.2
92
24-135
Methyl parathion
ug/L
50
73.0
146
59-174
N-Nitroso-di-n-butylamine
ug/L
50
47.0
94
33-130
N-Nitroso-di-n-propylamine
ug/L
50
49.5
99
38-145
N-Nitrosodiethylamine
ug/L
50
56.3
113
26-145
N-Nitrosodimethylamine
ug/L
50
37.9
76
30-130
N-Nitrosodiphenylamine
ug/L
50
46.4
93
46-144
N-Nitrosomethylethylamine
ug/L
50
48.4
97
19-138
N-Nitrosopiperidine
ug/L
50
58.8
118
35-147
N-Nitrosopyrrolidine
ug/L
50
55.4
111
31-142
Nitrobenzene
ug/L
50
43.8
88
33-136
O,O,O-Triethylphosphorothioate
ug/L
50
59.5
119
27-136
O-Toluidine
ug/L
50
50.0
100
27-140
P-Dimethylaminoazobenzene
ug/L
50
32.6
65
23-130
p-Phenylenediamine
ug/L
ND
Parathion (Ethyl parathion)
ug/L
50
73.1
146
59-171
Pentachlorobenzene
ug/L
50
49.7
99
42-138
Pentachloronitrobenzene
ug/L
50
70.0
140
64-185
Pentachlorophenol
ug/L
100
104
104
19-156
Phenacetin
ug/L
50
64.2
128
57-174
Phenanthrene
ug/L
50
46.0
92
49-143
Phenol
ug/L
50
28.3
57
18-130
Phorate
ug/L
50
58.9
118
41-200
Pronamide
ug/L
50
63.6
127
59-174
Pyrene
ug/L
50
51.1
102
48-156
Safrole
ug/L
50
53.7
107
31-136
Thionazin
ug/L
50
61.5
123
52-151
2,4,6-Tribromophenol (S)
%
102
10-166
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 111 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
LABORATORY CONTROL SAMPLE:
4205197
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
2-Fluorobiphenyl (S)
%
79
10-130
2-Fluorophenol(S)
%
69
10-130
Nitrobenzene-d5 (S)
%
93
10-133
Phenol-d6 (S)
%
55
10-130
Terphenyl-d14 (S)
%
102
10-193
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
4205198
4205199
MS
MSD
92697649001
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result % Rec % Rec
Limits
RPD
RPD Qual
1,2,4,5-Tetrachlorobenzene
ug/L
ND
100
100
83.4
89.1
83
89
10-136
7
30
1,3,5-Trinitrobenzene
ug/L
ND
100
100
92.8
90.1
93
90
32-200
3
30
1,3-Dinitrobenzene
ug/L
ND
100
100
119
115
119
115
30-173
4
30
1,4-Naphthoquinone
ug/L
ND
100
100
90.6
95.9
91
96
10-144
6
30
1-Naphthalenamine
ug/L
ND
100
100
67.4
69.1
67
69
10-156
2
30
2,2'-Oxybis(1-
ug/L
ND
100
100
87.1
83.4
87
83
10-132
4
30
chloropropane)
2,3,4,6-Tetrachlorophenol
ug/L
ND
100
100
103
98.4
103
98
10-185
5
30
2,4,5-Trichlorophenol
ug/L
ND
100
100
106
102
106
102
10-174
5
30
2,4,6-Trichlorophenol
ug/L
ND
100
100
103
97.7
103
98
10-173
5
30
2,4-Dichlorophenol
ug/L
ND
100
100
102
96.6
102
97
10-153
6
30
2,4-Dimethylphenol
ug/L
ND
100
100
102
79.7
102
80
12-157
24
30
2,4-Dinitrophenol
ug/L
ND
500
500
537
521
107
104
10-165
3
30
2,4-Dinitrotoluene
ug/L
ND
100
100
108
103
108
103
29-168
5
30
2,6-Dichlorophenol
ug/L
ND
100
100
111
108
111
108
10-178
3
30
2,6-Dinitrotoluene
ug/L
ND
100
100
113
107
113
107
28-168
5
30
2-Acetylam inofl uorene
ug/L
ND
100
100
138
132
138
132
20-194
5
30
2-Chloronaphthalene
ug/L
ND
100
100
86.1
83.0
86
83
11-136
4
30
2-Chlorophenol
ug/L
ND
100
100
94.1
89.9
94
90
10-134
5
30
2-Methyl naphthalene
ug/L
ND
100
100
90.0
86.8
90
87
10-131
4
30
2-Methyl phenol(o-Cresol)
ug/L
ND
100
100
87.5
82.9
88
83
10-130
5
30
2-Naphthalenamine
ug/L
ND
100
100
67.5
44.0
67
44
10-147
42
30 R1
2-Nitroaniline
ug/L
ND
200
200
186
175
93
88
19-156
6
30
2-Nitrophenol
ug/L
ND
100
100
105
100
105
100
10-160
5
30
3&4-Methylphenol(m&p
ug/L
ND
100
100
83.5
79.7
84
80
10-132
5
30
Cresol)
3,3'-Dichlorobenzidine
ug/L
ND
200
200
210
200
105
100
10-173
5
30
3,3'-Dimethylbenzidine
ug/L
ND
200
200
125
159
62
79
10-200
24
30
3-Methylcholanthrene
ug/L
ND
100
100
128
126
128
126
10-200
2
30
3-Nitroaniline
ug/L
ND
200
200
200
191
100
96
19-169
5
30
4,6-Dinitro-2-methylphenol
ug/L
ND
200
200
245
238
122
119
10-178
3
30
4-Aminobiphenyl
ug/L
ND
100
100
66.2
63.1
66
63
10-170
5
30
4-Bromophenylphenyl ether
ug/L
ND
100
100
113
108
113
108
28-149
5
30
4-Chloro-3-methylphenol
ug/L
ND
200
200
212
201
106
101
18-148
5
30
4-Chloroaniline
ug/L
ND
200
200
177
177
89
88
10-141
0
30
4-Chlorophenylphenyl ether
ug/L
ND
100
100
105
100
105
100
24-144
5
30
Results presented
on this page are in the units
indicated by the
"Units" column except where
an alternate unit is presented to the right of the result.
REPORT
OF LABORATORY ANALYSIS
This report shall not be reproduced,
except
in full,
Date: 11 /28/2023 02:34 PM
without
the written consent of Pace Analytical Services, LLC.
Page 112 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
4205198
4205199
MS
MSD
92697649001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
4-Nitroaniline
ug/L
ND
200
200
193
178
97
89
18-170
8
30
4-Nitrophenol
ug/L
ND
500
500
320
304
64
61
10-130
5
30
5-Nitro-o-toluidine
ug/L
ND
100
100
123
118
123
118
38-167
4
30
7,12-
ug/L
ND
100
100
123
122
123
122
10-182
1
30
Dimethylbenz(a)anthracene
Acenaphthene
ug/L
ND
100
100
94.9
89.8
95
90
18-142
5
30
Acenaphthylene
ug/L
ND
100
100
96.7
91.7
97
92
18-143
5
30
Acetophenone
ug/L
ND
100
100
100
95.7
100
96
10-142
5
30
Anthracene
ug/L
ND
100
100
108
102
108
102
32-138
6
30
Benzo(a)anth race ne
ug/L
ND
100
100
120
112
120
112
41-155
6
30
Benzo(a)pyrene
ug/L
ND
100
100
119
114
119
114
10-167
4
30
Benzo(b)fluoranthene
ug/L
ND
100
100
132
126
132
126
31-172
5
30
Benzo(g,h,i)perylene
ug/L
ND
100
100
111
109
111
109
26-177
2
30
Benzo(k)fluoranthene
ug/L
ND
100
100
122
116
122
116
31-168
6
30
Benzyl alcohol
ug/L
ND
200
200
185
180
93
90
10-136
3
30
bis(2-
ug/L
ND
100
100
104
100
104
100
12-143
4
30
Chloroethoxy)methane
bis(2-Chloroethyl) ether
ug/L
ND
100
100
94.8
90.5
95
91
10-139
5
30
bis(2- Ethyl hexyl)phthalate
ug/L
ND
100
100
133
124
132
122
41-173
7
30
Butylbenzylphthalate
ug/L
ND
100
100
132
124
132
124
38-182
6
30
Chlorobenzilate
ug/L
ND
100
100
147
140
147
140
33-175
5
30
Chrysene
ug/L
ND
100
100
118
111
118
111
41-152
6
30
Di-n-butylphthalate
ug/L
ND
100
100
115
108
115
108
37-162
7
30
Di-n-octylphthalate
ug/L
ND
100
100
130
122
130
122
36-176
6
30
Diallate
ug/L
ND
100
100
121
117
121
117
26-155
4
30
Dibenz(a,h)anthracene
ug/L
ND
100
100
114
111
114
111
29-175
3
30
Dibenzofuran
ug/L
ND
100
100
95.5
90.2
96
90
23-144
6
30
Diethylphthalate
ug/L
ND
100
100
106
98.5
106
99
33-154
8
30
Dimethoate
ug/L
ND
100
100
127
120
127
120
41-169
6
30
Dimethylphthalate
ug/L
ND
100
100
103
98.1
103
98
29-150
5
30
Diphenylamine
ug/L
ND
100
100
108
98.8
108
99
34-146
9
30
Disulfoton
ug/L
ND
100
100
121
116
121
116
36-133
4
30
Ethyl methanesulfonate
ug/L
ND
100
100
100
98.8
100
99
10-147
1
30
Famphur
ug/L
ND
200
200
125
105
63
53
10-130
17
30
Fluoranthene
ug/L
ND
100
100
109
103
109
103
40-156
6
30
Fluorene
ug/L
ND
100
100
103
97.5
103
98
26-148
6
30
Hexachloro-1,3-butadiene
ug/L
ND
100
100
69.2
62.6
69
63
10-130
10
30
Hexachlorobenzene
ug/L
ND
100
100
111
105
111
105
27-145
6
30
Hexachlorocyclopentadiene
ug/L
ND
100
100
77.7
76.2
78
76
10-130
2
30
Hexachloroethane
ug/L
ND
100
100
58.5
50.6
59
51
10-130
14
30
Hexachloropropene
ug/L
ND
100
100
36.8
48.2
37
48
10-130
27
30
Indeno(1,2,3-cd)pyrene
ug/L
ND
100
100
111
107
111
107
28-176
4
30
Isodrin
ug/L
ND
100
100
116
114
116
114
33-153
2
30
Isophorone
ug/L
ND
100
100
103
97.4
103
97
14-145
6
30
Isosafrole
ug/L
ND
100
100
92.2
88.9
92
89
13-136
4
30
Kepone
ug/L
ND
200
200
122
116
61
58
10-130
5
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 113 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
4205198
4205199
MS
MSD
92697649001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Methapyrilene
ug/L
ND
100
100
37.6J
46.8J
38
47
10-200
30
Methyl methanesulfonate
ug/L
ND
100
100
87.0
87.2
87
87
10-138
0
30
Methyl parathion
ug/L
ND
100
100
147
139
147
139
44-177
6
30
N-Nitroso-di-n-butylamine
ug/L
ND
100
100
93.1
88.3
93
88
14-133
5
30
N-Nitroso-di-n-propylamine
ug/L
ND
100
100
104
99.4
104
99
12-149
5
30
N-Nitrosodiethylamine
ug/L
ND
100
100
107
107
107
107
10-148
1
30
N-Nitrosodimethylamine
ug/L
ND
100
100
75.5
74.2
76
74
10-130
2
30
N-Nitrosodiphenylamine
ug/L
ND
100
100
108
98.8
108
99
29-149
9
30
N-Nitrosomethylethylamine
ug/L
ND
100
100
89.5
88.9
89
89
10-139
1
30
N-Nitrosopiperidine
ug/L
ND
100
100
115
110
115
110
14-151
5
30
N-Nitrosopyrrolidine
ug/L
ND
100
100
102
102
102
102
14-143
0
30
Nitrobenzene
ug/L
ND
100
100
97.5
92.4
98
92
10-145
5
30
0,0,0-
ug/L
ND
100
100
113
112
113
112
10-142
1
30
Triethylphosphorothioate
O-Toluidine
ug/L
ND
100
100
89.6
93.8
90
94
10-137
5
30
P-
ug/L
ND
100
100
70.8
67.3
71
67
17-130
5
30
Dimethylaminoazobenzene
p-Phenylenediamine
ug/L
ND
ND
ND
30
Parathion (Ethyl parathion)
ug/L
ND
100
100
146
143
146
143
45-174
2
30
Pentachlorobenzene
ug/L
ND
100
100
106
101
106
101
20-143
4
30
Pentachloronitrobenzene
ug/L
ND
100
100
150
144
150
144
39-186
4
30
Pentachlorophenol
ug/L
ND
200
200
235
221
117
111
10-178
6
30
Phenacetin
ug/L
ND
100
100
129
122
129
122
36-185
5
30
Phenanthrene
ug/L
ND
100
100
108
102
108
102
36-146
6
30
Phenol
ug/L
ND
100
100
58.2
56.2
58
56
10-130
4
30
Phorate
ug/L
ND
100
100
129
124
129
124
26-200
4
30
Pronamide
ug/L
ND
100
100
131
125
131
125
40-181
5
30
Pyrene
ug/L
ND
100
100
125
118
125
118
42-156
6
30
Safrole
ug/L
ND
100
100
102
102
102
102
10-142
0
30
Thionazin
ug/L
ND
100
100
126
120
126
120
31-159
4
30
2,4,6-Tribromophenol (S)
%
132
129
10-166
2-Fluorobiphenyl (S)
%
98
96
10-130
2-Fluorophenol (S)
%
76
76
10-130
Nitrobenzene-d5 (S)
%
108
104
10-133
Phenol-d6 (S)
%
60
60
10-130
Terphenyl-d14 (S)
%
139
134
10-193
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 114 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 813358 Analysis Method: SM 2320B-2011
QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697334001, 92697334002, 92697334003, 92697334004, 92697334005, 92697337006, 92697337007
METHOD BLANK: 4211121 Matrix: Water
Associated Lab Samples: 92697334001, 92697334002, 92697334003, 92697334004, 92697334005, 92697337006, 92697337007
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Alkalinity, Total as CaCO3 mg/L ND 5.0 5.0 11/15/23 17:40
LABORATORY CONTROL SAMPLE: 4211122
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 mg/L 50 51.3 103 80-120
LABORATORY CONTROL SAMPLE: 4211123
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 mg/L 50 50.0 100 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4211124 4211125
MS MSD
92697337006 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L 114 50 50 139 141 50 55 80-120 2 25 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4211126 4211127
MS MSD
92697337007 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L 176 50 50 200 201 48 50 80-120 1 25 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 115 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 812030 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697334001, 92697334002, 92697334003, 92697334004, 92697334005, 92697337006, 92697337007
METHOD BLANK: 4204492
Matrix:
Water
Associated Lab Samples: 92697334001, 92697334002, 92697334003, 92697334004, 92697334005, 92697337006, 92697337007
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Total Dissolved Solids
mg/L
ND
2.5
2.5 11/09/23 10:47
LABORATORY CONTROL SAMPLE:
4204493
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Total Dissolved Solids
mg/L
250
244 97
90-110
SAMPLE DUPLICATE: 4204494
92697329001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Dissolved Solids mg/L 12.3 11.3 8 25
SAMPLE DUPLICATE: 4204495
92697334005 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Dissolved Solids mg/L 16.5 16.8 2 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 116 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 811982 Analysis Method: SM 4500-S2D-2011
QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697334001, 92697334002, 92697334003, 92697334004
METHOD BLANK: 4204370 Matrix: Water
Associated Lab Samples: 92697334001, 92697334002, 92697334003, 92697334004
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Sulfide ug/L ND 100 22.0 11/09/23 05:24
LABORATORY CONTROL SAMPLE: 4204371
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide ug/L 500 462 92 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4204372 4204373
MS MSD
92697329001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide ug/L 0.030J 500 500 586 588 111 112 80-120 0 10
mg/L
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4204374 4204375
MS MSD
92697332002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide ug/L 0.036J 500 500 519 514 97 96 80-120 1 10
mg/L
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 117 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 811983 Analysis Method: SM 4500-S2D-2011
QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697334005, 92697337006, 92697337007
METHOD BLANK: 4204376 Matrix: Water
Associated Lab Samples: 92697334005, 92697337006, 92697337007
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Sulfide ug/L ND 100 22.0 11/09/23 05:43
LABORATORY CONTROL SAMPLE: 4204377
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide ug/L 500 482 96 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4204378 4204379
MS MSD
92697334005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide ug/L ND 500 500 551 559 109 110 80-120 2 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4204380 4204381
MS MSD
92697616004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide ug/L ND 500 500 450 451 90 90 80-120 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 118 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns
R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 812245
Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA
300.0 Rev 2.1 1993
Analysis Description: 300.0 IC Anions
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples:
92697334001, 92697334002,
92697334003, 92697334004, 92697334005, 92697337006, 92697337007
METHOD BLANK: 4205872
Matrix: Water
Associated Lab Samples:
92697334001, 92697334002,
92697334003, 92697334004, 92697334005, 92697337006, 92697337007
Blank Reporting
Parameter
Units
Result Limit MDL Analyzed Qualifiers
Chloride
mg/L
ND 1.0 0.60 11/09/23 21:52
Sulfate
mg/L
ND 1.0 0.50 11/09/23 21:52
LABORATORY CONTROL
SAMPLE: 4205873
Spike LCS LCS % Rec
Parameter
Units
Conc. Result % Rec Limits Qualifiers
Chloride
mg/L
50 51.4 103 90-110
Sulfate
mg/L
50 52.0 104 90-110
MATRIX SPIKE & MATRIX
SPIKE DUPLICATE: 4205874 4205875
MS MSD
92697615001
Spike Spike MS MSD MS MSD % Rec
Max
Parameter
Units Result
Conc. Conc. Result Result % Rec % Rec Limits
RPD RPD Qual
Chloride
mg/L 1690
50 50 1730 1720 80 73 90-110
0 10 M1
Sulfate
mg/L 38.9
50 50 79.4 79.9 81 82 90-110
1 10 M1
MATRIX SPIKE & MATRIX
SPIKE DUPLICATE: 4205876 4205877
MS MSD
92697337006
Spike Spike MS MSD MS MSD % Rec
Max
Parameter
Units Result
Conc. Conc. Result Result % Rec % Rec Limits
RPD RPD Qual
Chloride
mg/L 11.8
50 50 60.7 61.6 98 100 90-110
1 10
Sulfate
mg/L 0.54J
50 50 62.4 64.0 124 127 90-110
3 10 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 119 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 812877 Analysis Method: SM 4500-CN-E-2016
QC Batch Method: SM 4500-CN-E-2016 Analysis Description: 450OCNE Cyanide, Total
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697334001, 92697334002, 92697334003, 92697334004, 92697334005
METHOD BLANK: 4208833 Matrix: Water
Associated Lab Samples: 92697334001, 92697334002, 92697334003, 92697334004, 92697334005
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Cyanide ug/L ND 8.0 6.0 11/14/23 20:16
LABORATORY CONTROL SAMPLE: 4208834
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Cyanide ug/L 100 84.4 84 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4208835 4208836
MS MSD
92698047003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Cyanide ug/L 0.013 100 100 73.1 76.8 60 64 80-120 5 10 M1
mg/L
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4208837 4208838
MS MSD
92697811001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Cyanide ug/L ND 100 100 ND ND 0 0 80-120 10 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 120 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 813703 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697337001, 92697337002, 92697337003, 92697337004
METHOD BLANK: 4212858 Matrix: Water
Associated Lab Samples: 92697337001, 92697337002, 92697337003, 92697337004
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Total Organic Carbon mg/L ND 1.0 0.50 11/16/23 22:49
LABORATORY CONTROL SAMPLE: 4212859
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Organic Carbon mg/L 25 23.9 96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4212860 4212861
MS MSD
92698018019 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon mg/L ND 25 25 24.4 24.4 97 97 90-110 0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4212862 4212863
MS MSD
92698018020 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon mg/L ND 25 25 23.9 23.9 96 96 90-110 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 121 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
QC Batch: 814397 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697337006, 92697337007
METHOD BLANK: 4216419 Matrix: Water
Associated Lab Samples: 92697337006, 92697337007
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Total Organic Carbon mg/L ND 1.0 0.50 11/20/23 10:52
LABORATORY CONTROL SAMPLE: 4216420
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Organic Carbon mg/L 25 24.1 96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4216421 4216422
MS MSD
92697473004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon mg/L 3.9 25 25 28.5 28.1 98 97 90-110 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4216423 4216424
MS MSD
92697473005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon mg/L 2.9 25 25 26.8 27.0 96 97 90-110 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC.
Page 122 of 130

Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
aceo Huntersville, NC 28078
[phone]
QUALIFIERS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
1g Re -extraction conducted in excess of EPA method holding time. Results confirm original analysis performed in hold time.
AC Analysis of acrolein and/or acrylonitrile was performed from a sample that was field preserved to pH < 2, which is less
than the pH range of 4-5 specified in the test method and required for NPDES compliance per 40CFR Part 136.
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
D6 The precision between the sample and sample duplicate exceeded laboratory control limits.
E Analyte concentration exceeded the calibration range. The reported result is estimated.
H1 Analysis conducted outside the EPA method holding time.
IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be
considered an estimated value.
L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.
L2 Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
R2 RPD value was outside control limits due to matrix interference
SO Surrogate recovery outside laboratory control limits.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 123 of 130

QUALIFIERS
Project: Johns R. C&D/MSWLF GW
Pace Project No.: 92697334
ANALYTE QUALIFIERS
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
S3 Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated sample.
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM without the written consent of Pace Analytical Services, LLC. Page 124 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Johns R. C&D/MSWLF GW
92697334
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92697351002
1203-MW-19
AM20
307943
92697351003
1203-MW-18
AM20
307943
92697351004
1203-MW-11
AM20
307943
92697351005
1203-MW-12
AM20
307943
92697351006
1203-MW-16S
AM20
307943
92697337001
1203-MW-10
EPA 353.2 Rev 2.0 1993
811687
92697337002
1203-MW-11
EPA 353.2 Rev 2.0 1993
811687
92697337003
1203-MW-12
EPA 353.2 Rev 2.0 1993
811687
92697337004
1203-MW-16S
EPA 353.2 Rev 2.0 1993
811687
92697337006
1203-MW-18
EPA 353.2 Rev 2.0 1993
811687
92697337007
1203-MW-19
EPA 353.2 Rev 2.0 1993
811687
92697334001
1203-MW-10
8151A
2169599
EPA8151
2169599
92697334002
1203-MW-11
8151A
2169599
EPA8151
2169599
92697334003
1203-MW-12
8151A
2169599
EPA8151
2169599
92697334004
1203-MW-13
8151A
2169599
EPA8151
2169599
92697334005
1203-MW-16S
8151A
2169599
EPA8151
2169599
92697334001
1203-MW-10
EPA 3510C
812043
EPA 8081 B
812475
92697334002
1203-MW-11
EPA 3510C
812043
EPA 8081 B
812475
92697334003
1203-MW-12
EPA 3510C
812043
EPA 8081 B
812475
92697334004
1203-MW-13
EPA 3510C
812043
EPA 8081 B
812475
92697334005
1203-MW-16S
EPA 3510C
812043
EPA 8081 B
812475
92697334001
1203-MW-10
EPA 3510C
815068
EPA 8082A
815393
92697334002
1203-MW-11
EPA 3510C
815068
EPA 8082A
815393
92697334003
1203-MW-12
EPA 3510C
815068
EPA 8082A
815393
92697334004
1203-MW-13
EPA 3510C
815068
EPA 8082A
815393
92697334005
1203-MW-16S
EPA 3510C
815068
EPA 8082A
815393
92697337001
1203-MW-10
RSK 175 Modified
812107
92697337002
1203-MW-11
RSK 175 Modified
812107
92697337003
1203-MW-12
RSK 175 Modified
812107
92697337004
1203-MW-16S
RSK 175 Modified
812107
92697337006
1203-MW-18
RSK 175 Modified
812107
92697337007
1203-MW-19
RSK 175 Modified
812107
92698172001
1203-MW-36
RSK 175 Modified
813082
92697334001
1203-MW-10
EPA 3010A
812399
EPA 6010D
812526
92697334002
1203-MW-11
EPA 3010A
812399
EPA 6010D
812526
92697334003
1203-MW-12
EPA 3010A
812399
EPA 6010D
812526
92697334004
1203-MW-13
EPA 3010A
812399
EPA 6010D
812526
92697334005
1203-MW-16S
EPA 3010A
812399
EPA 6010D
812526
92697337006
1203-MW-18
EPA 3010
966774
EPA 6010
966844
92697337007
1203-MW-19
EPA 3010
966774
EPA 6010
966844
92698172001
1203-MW-36
EPA 3010
967448
EPA 6010
967466
92697334001
1203-MW-10
EPA 3010A
812425
EPA 6020B
812510
92697334002
1203-MW-11
EPA 3010A
812425
EPA 6020B
812510
92697334003
1203-MW-12
EPA 3010A
812425
EPA 6020B
812510
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /28/2023 02:34 PM
without the written consent of Pace Analytical Services, LLC.
Page 125 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Johns R. C&D/MSWLF GW
92697334
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92697334004
1203-MW-13
EPA 3010A
812425
EPA 6020B
812510
92697334005
1203-MW-16S
EPA 3010A
812425
EPA 6020B
812510
92697337006
1203-MW-18
EPA 3010
966773
EPA 6020
966842
92697337007
1203-MW-19
EPA 3010
966773
EPA 6020
966842
92698172001
1203-MW-36
EPA 3010
967447
EPA 6020
967465
92697337006
1203-MW-18
EPA 7470
966882
EPA 7470
966964
92697337007
1203-MW-19
EPA 7470
966882
EPA 7470
966964
92698172001
1203-MW-36
EPA 7470
968880
EPA 7470
968913
92697334001
1203-MW-10
EPA 7470A
813388
EPA 7470A
813895
92697334002
1203-MW-11
EPA 7470A
813388
EPA 7470A
813895
92697334003
1203-MW-12
EPA 7470A
813388
EPA 7470A
813895
92697334004
1203-MW-13
EPA 7470A
813388
EPA 7470A
813895
92697334005
1203-MW-16S
EPA 7470A
813388
EPA 7470A
813895
92697334001
1203-MW-10
EPA 3510C
812141
EPA 8270E
812494
92697334002
1203-MW-11
EPA 3510C
811997
EPA 8270E
812452
92697334003
1203-MW-12
EPA 3510C
811997
EPA 8270E
812452
92697334004
1203-MW-13
EPA 3510C
812141
EPA 8270E
812494
92697334005
1203-MW-16S
EPA 3510C
812141
EPA 8270E
812494
92697334001
1203-MW-10
EPA 8260D
812462
92697334002
1203-MW-11
EPA 8260D
812462
92697334003
1203-MW-12
EPA 8260D
812462
92697334004
1203-MW-13
EPA 8260D
812462
92697334005
1203-MW-16S
EPA 8260D
812467
92697337006
1203-MW-18
EPA 8260D
812467
92697337007
1203-MW-19
EPA 8260D
812579
92698172001
1203-MW-36
EPA 8260D
812809
92697334001
1203-MW-10
EPA 8260D Mod.
812181
92697334002
1203-MW-11
EPA 8260D Mod.
812181
92697334003
1203-MW-12
EPA 8260D Mod.
812181
92697334004
1203-MW-13
EPA 8260D Mod.
812181
92697334005
1203-MW-16S
EPA 8260D Mod.
812181
92697337006
1203-MW-18
EPA 8260D Mod.
812182
92697337007
1203-MW-19
EPA 8260D Mod.
812182
92697334001
1203-MW-10
SM 2320B-2011
813358
92697334002
1203-MW-11
SM 2320B-2011
813358
92697334003
1203-MW-12
SM 2320B-2011
813358
92697334004
1203-MW-13
SM 2320B-2011
813358
92697334005
1203-MW-16S
SM 2320B-2011
813358
92697337006
1203-MW-18
SM 2320B-2011
813358
92697337007
1203-MW-19
SM 2320B-2011
813358
92697334001
1203-MW-10
SM 2540C-2015
812030
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except
in full,
Date: 11 /28/2023 02:34 PM
without the written consent of Pace Analytical Services, LLC.
Page 126 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Johns R. C&D/MSWLF GW
92697334
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method Batch
92697334002
1203-MW-11
SM 2540C-2015
812030
92697334003
1203-MW-12
SM 2540C-2015
812030
92697334004
1203-MW-13
SM 2540C-2015
812030
92697334005
1203-MW-16S
SM 2540C-2015
812030
92697337006
1203-MW-18
SM 2540C-2015
812030
92697337007
1203-MW-19
SM 2540C-2015
812030
92697334001
1203-MW-10
SM 4500-S2D-2011
811982
92697334002
1203-MW-11
SM 4500-S2D-2011
811982
92697334003
1203-MW-12
SM 4500-S2D-2011
811982
92697334004
1203-MW-13
SM 4500-S2D-2011
811982
92697334005
1203-MW-16S
SM 4500-S2D-2011
811983
92697337006
1203-MW-18
SM 4500-S2D-2011
811983
92697337007
1203-MW-19
SM 4500-S2D-2011
811983
92697334001
1203-MW-10
EPA 300.0 Rev 2.1 1993
812245
92697334002
1203-MW-11
EPA 300.0 Rev 2.1 1993
812245
92697334003
1203-MW-12
EPA 300.0 Rev 2.1 1993
812245
92697334004
1203-MW-13
EPA 300.0 Rev 2.1 1993
812245
92697334005
1203-MW-16S
EPA 300.0 Rev 2.1 1993
812245
92697337006
1203-MW-18
EPA 300.0 Rev 2.1 1993
812245
92697337007
1203-MW-19
EPA 300.0 Rev 2.1 1993
812245
92697334001
1203-MW-10
SM 4500-CN-E-2016
812877
SM 4500-CN-E-2016 813245
92697334002
1203-MW-11
SM 4500-CN-E-2016
812877
SM 4500-CN-E-2016 813245
92697334003
1203-MW-12
SM 4500-CN-E-2016
812877
SM 4500-CN-E-2016 813245
92697334004
1203-MW-13
SM 4500-CN-E-2016
812877
SM 4500-CN-E-2016 813245
92697334005
1203-MW-16S
SM 4500-CN-E-2016
812877
SM 4500-CN-E-2016 813245
92697337001
1203-MW-10
SM 5310B-2014
813703
92697337002
1203-MW-11
SM 5310B-2014
813703
92697337003
1203-MW-12
SM 5310B-2014
813703
92697337004
1203-MW-16S
SM 5310B-2014
813703
92697337006
1203-MW-18
SM 5310B-2014
814397
92697337007
1203-MW-19
SM 5310B-2014
814397
Date: 11/28/2023 02:34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 127 of 130

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DC#_Title: ENV-FRM-HUN1-0084 v01_Tech Spec Sample Condition
Upon Receipt
- a7ce
tiYi+1k4 i
Effective Date: 05/12/2022
Laboratory receiving samples:
Asheville ❑ Eden ❑ Greenwood ❑ Huntersville ❑ Raleigh[] Mechanicsville❑ Atlanta❑ Kernersville4Y
ConditionSample Client Name:
Receipt b�
CtX
Courier: [-]Fed Ex ❑UPS ❑USPS
❑ Commercial []Pace ❑Other:
Carrier Tracking Number:
Project #: � N 5
0Cltent
Custody Seal Present?
❑Yes Ml o
Seals Intact? ❑Yes
[-]No
Packing Material:
Dbble Wrap
E19,6bble Bags ❑None
❑ Other
Thermometer: ❑ I Gun ID: -0jV� Type of Ice: ❑ 0 ue
Cooler Temp ('C): k , Correction Factor: Add / Subtract ('C I
Corrected Cooler Temp ('C ):- 1( ' `0
USDA Regulated Soil (�i/A, water sample)
Did samples originate in a quarantine zone within the Untted States: CA, NY, or SC (check maps)?
❑Yes ❑No
Date/Initials Person Examining Contents:
Biological Tissue Frozen?
[]Yes ❑No UN/A
❑ None
Temp should be above freezing to 6'C
❑Samples out of temp criteria. Samples an ice, cooling process
has begun
Did samples originate from a foreign source (internationally,
inrhidino Hawaii nnrd Vuprtn RirnP FlVac nmI
Comments/Discrepancy:
Chain of Custody Present?
Oes
[]NO
[]N/A
1,
Samples Arrived within Hold Time?
es
No
❑NJA
2.
Short Hold Time Analysis (<72 hr.)?
❑Yes
[[No
❑NJA
3,
Rush Turn Around Time Requested?
[]Yes
5<o
❑iv/A
4.
Sufficient Volume?
Oes
QNo
❑N/A
S.
Correct Containers Used?
-Pace Containers Used?
[g'(es
es
[:]No
❑No
❑N/A
[]N/A
6.
Containers Intact?
[R4$
[-]No
[]N/A
7.
Dissolved analysis: Samples Field Filtered? []Yes
[]No
MdJA
8.
Sample Labels Match COC?
-Includes Date/Time/ID/Analysis
Wes
Matrix: w�
❑No
❑N/A
9.
Headspace in VOA Vials (>5-6mm)?
❑Yes
MNo
[]N/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
❑Yes
[]Yes[]No/A
❑No
Q91
11.
COMMENTS/SAMPLE D15CREPANCY
Temp Log: Temp must be maintained
at <6 C during login, record temp
every 20 minut s.
Time opened emp:
Time: 0 put in cooler
Time: Temp:
Person Contacted:
Project Manager SCURF Review:
Project Manager SRF Review:
Qualtrax Document ID: 70677
Field Data Required? [_-]Yes [:]No
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Date/Time:
Date:
Date:
Page 1 of 2
Page 129 of 130

Documert Name:
Bottle Identification Form IBfF)
PaCeAlh ly`(lCc7I ——pocument No :
F-CAR-CS-043-Rev.01
*Check mark top half of box if pH and/or dechlorination is Project #
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 jwater) DOC, Ll-mg
**Bottom half of box is to list number of bottles
Document Issued November 15, 2021
Page IofI
Issuing Authority:
Pace Carolinas Quality Office
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot p
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office {i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 130 of 130

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
November 22, 2023
Mr. Van Burbach
LaBella Associates, D.P.C.
12-D Oak Branch Drive
Greensboro, NC 27407
RE: Project: Burke Co Johs River Diss H2
Pace Project No.: 92697351
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on November 07, 2023. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Baton Rouge
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
c5�
Taylor M Cannon
[e-mail]
704-977-0943
Project Manager
Enclosures
cc: Van Burbach, LaBella Associates, DPC
Kandice Estes, Labella Associates
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 16

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Burke Co Johs River Diss H2
Pace Project No.: 92697351
Pace Analytical Services Baton Rouge
7979 Innovation Park Drive Ste A, Baton Rouge, LA
70820-7402
Louisiana Dept of Enviromental Quality (NELAC/LELAP):
01979
Florida Dept of Health (NELAC/FELAP): E87854
DoD ELAP (A2LA) #: 6429.01
Alabama DEM #: 41900
Alaska DEC-DW #: LA00024
Alaska DEC CS -LAP #: 21-001
Arkansas DEQ #: 88-0655
California ELAP #: 3063
Georgia DPD M C050
Hawaii DOH State Laboratories Division
Illinois EPA#: 200048
Kansas DoHE #: E-10354
Kentucky DEP UST Branch #: 123054
Louisiana DOH #: LA036
Minnesota DOH #: 2233799
Mississippi State Dept of Health
CERTIFICATIONS
Montana Department of Environmental Quality
Nebraska DHHS #: NE-OS-35.21
Nevada DCNR DEP #: LA00024
New York DOH M 12149
North Carolina DEQ - WW & GW #: 618
North Dakota DEQ #: R195
Ohio EPA#: 87782
Oklahoma Dept of Environmental Quality #: 9403
Oregon ELAP #: 4168
Pennsylvania Dept of Environmental Protection #: 68-
05973
South Carolina DHEC #: 73006001
Texas CEQ #: T104704178-23-15
Utah DOH M LA00024
Virginia DCLS #: 6460215
Washington Dept of Ecology #: C929
Wisconsin DNR #: 399139510
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 16

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Pace Analytical Services, LLC
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SAMPLE SUMMARY
Project: Burke Co Johs River Diss H2
Pace Project No.: 92697351
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92697351001
1203-MW-21
Water
11/06/23 12:02
11/07/23 17:05
92697351002
1203-MW-19
Water
11/07/2311:55
11/07/23 17:05
92697351003
1203-MW-18
Water
11/07/2310:14
11/07/23 17:05
92697351004
1203-MW-11
Water
11/06/23 13:52
11/07/23 17:05
92697351005
1203-MW-12
Water
11/06/2315:49
11/07/23 17:05
92697351006
1203-MW-16S
Water
11/07/2313:33
11/07/23 17:05
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 16

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Pace Analytical Services, LLC
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SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Burke Co Johs River Diss H2
92697351
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92697351001
1203-MW-21
AM20
LB
1
PASI-BR
92697351002
1203-MW-19
AM20
LB
1
PASI-BR
92697351003
1203-MW-18
AM20
LB
1
PASI-BR
92697351004
1203-MW-11
AM20
LB
1
PASI-BR
92697351005
1203-MW-12
AM20
LB
1
PASI-BR
92697351006
1203-MW-16S
AM20
LB
1
PASI-BR
PASI-BR = Pace Analytical Services - Baton Rouge
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 4 of 16

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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
Project: Burke Co Johs River Diss H2
Pace Project No.: 92697351
Lab Sample ID
Method
Client Sample ID
Parameters
92697351001
1203-MW-21
AM20
Hydrogen
92697351002
1203-MW-19
AM20
Hydrogen
92697351003
1203-MW-18
AM20
Hydrogen
92697351005
1203-MW-12
AM20
Hydrogen
92697351006
1203-MW-16S
AM20
Hydrogen
SUMMARY OF DETECTION
Result Units
1 AJ nMoles
3.0 nMoles
1.6J nMoles
1 AJ nMoles
5.3 nMoles
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Report Limit Analyzed
1.9 11/14/23 09:01
1.9 11/14/23 09:13
1.9 11/14/23 09:25
1.9 11/14/23 09:56
1.9 11/14/23 11:00
Qualifiers
Page 5 of 16

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Pace Analytical Services, LLC
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[phone]
ANALYTICAL RESULTS
Project: Burke Co Johs River Diss H2
Pace Project No.: 92697351
Sample: 1203-MW-21 Lab ID: 92697351001 Collected: 11/06/23 12:02 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
BR Hydrogen by AM20 in Vapor Analytical Method: AM20
Pace Analytical Services - Baton Rouge
Hydrogen 1.4J nMoles 1.9 0.49 1 11/14/23 09:01 1333-74-0
Date: 11/22/2023 03:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 16

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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co Johs River Diss H2
Pace Project No.: 92697351
Sample: 1203-MW-19 Lab ID: 92697351002 Collected: 11/07/23 11:55 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
BR Hydrogen by AM20 in Vapor Analytical Method: AM20
Pace Analytical Services - Baton Rouge
Hydrogen 3.0 nMoles 1.9 0.49 1 11/14/23 09:13 1333-74-0
Date: 11/22/2023 03:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 16

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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co Johs River Diss H2
Pace Project No.: 92697351
Sample: 1203-MW-18 Lab ID: 92697351003 Collected: 11/07/23 10:14 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
BR Hydrogen by AM20 in Vapor Analytical Method: AM20
Pace Analytical Services - Baton Rouge
Hydrogen 1.6J nMoles 1.9 0.49 1 11/14/23 09:25 1333-74-0
Date: 11/22/2023 03:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 16

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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co Johs River Diss H2
Pace Project No.: 92697351
Sample: 1203-MW-11 Lab ID: 92697351004 Collected: 11/06/23 13:52 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
BR Hydrogen by AM20 in Vapor Analytical Method: AM20
Pace Analytical Services - Baton Rouge
Hydrogen ND nMoles 1.9 0.49 1 11/14/23 09:39 1333-74-0
Date: 11/22/2023 03:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 16

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co Johs River Diss H2
Pace Project No.: 92697351
Sample: 1203-MW-12 Lab ID: 92697351005 Collected: 11/06/23 15:49 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
BR Hydrogen by AM20 in Vapor Analytical Method: AM20
Pace Analytical Services - Baton Rouge
Hydrogen 1.4J nMoles 1.9 0.49 1 11/14/23 09:56 1333-74-0
Date: 11/22/2023 03:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 10 of 16

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co Johs River Diss H2
Pace Project No.: 92697351
Sample: 1203-MW-16S Lab ID: 92697351006 Collected: 11/07/23 13:33 Received: 11/07/23 17:05 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
BR Hydrogen by AM20 in Vapor Analytical Method: AM20
Pace Analytical Services - Baton Rouge
Hydrogen 5.3 nMoles 1.9 0.49 1 11/14/2311:00 1333-74-0
Date: 11/22/2023 03:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 16

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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
QUALITY CONTROL DATA
Project: Burke Co Johs River Diss H2
Pace Project No.: 92697351
QC Batch: 307943 Analysis Method: AM20
QC Batch Method: AM20 Analysis Description: BR Hydrogen by AM20 in Vapor
Laboratory: Pace Analytical Services - Baton Rouge
Associated Lab Samples: 92697351001, 92697351002, 92697351003, 92697351004, 92697351005, 92697351006
METHOD BLANK: 1473991 Matrix: Air
Associated Lab Samples: 92697351001, 92697351002, 92697351003, 92697351004, 92697351005, 92697351006
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Hydrogen nMoles ND 1.9 0.49 11/14/23 08:48
LABORATORY CONTROL SAMPLE & LCSD: 1473993 1473992
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers
Hydrogen nMoles 11.9 12.6 12.2 106 102 70-130 4 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /22/2023 03:30 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 16

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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: Burke Co Johs River Diss H2
Pace Project No.: 92697351
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /22/2023 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 16

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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Burke Co Johs River Diss H2
Pace Project No.: 92697351
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
92697351001
1203-MW-21
AM20
307943
92697351002
1203-MW-19
AM20
307943
92697351003
1203-MW-18
AM20
307943
92697351004
1203-MW-11
AM20
307943
92697351005
1203-MW-12
AM20
307943
92697351006
1203-MW-16S
AM20
307943
Date: 11/22/2023 03:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical
Batch
Page 14 of 16

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Document Na-Me:
_ Bottle Identification Form jBIFj
ceAt?,dyticaI Document No.:
F •CAR• CS-043- Rev.01
*Check mark top half of box if pH and/or dechlorination is Project #
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, I.LHg
**Bottom half of box is to list number of bottles
Document Issued: November 15, 2021
Page 1 of 1
Issuing Authority:
Pace Carolinas Quality Office
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
pate preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
tqt I
Note Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i e
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 16 of 16

Appendix C
Historical Data Tables
Table C-1 Historical Groundwater Elevations
Table C-2 Historical Detected Groundwater Constituents
Table C-3 Historical Detected Constituents in Performance & Sentinel Wells
Table CA Historical Detected Surface Water Constituents
Table C-5 Historical MNA Parameters

Table A2-1: Historical Groundwater Elevations
Location
Background
Downgradient/Compliance Wells
Sentinel
Performance
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-18
MW-19
MW-36
MW-38
TOC Elevation
1099.86
1012.23
1028.58
1034.22
1059.40
1007.67
998.49
999.95
1099.52
1087.76
Well Depth
41.00
24.16
44.20
53.00
59.00
21.45
12.00
15.00
45.00
73.13
18-Apr-96
NM
998.78
993.30
993.84
1010.40
NI
NI
NI
NI
NI
18-Jun-96
NM
998.41
992.80
994.50
1010.03
NI
NI
NI
NI
NI
6-May-14
NM
999.71
990.63
994.22
1010.84
992.73
993.31
993.17
1069.17
1042.18
21-Oct-14
1063.48
999.49
993.93
994.27
1009.98
992.97
NM
NM
1066.52
1045.18
21-May-15
1062.18
999.22
993.03
993.62
1010.18
992.11
992.54
992.60
1066.03
1044.68
8-Dec-15
1061.71
999.49
992.25
993.42
1009.64
994.47
NM
NM
1066.72
1046.24
4-May-16
1065.36
998.98
993.73
993.22
1009.66
992.97
992.74
993.45
1071.22
1044.91
13-Dec-16
1061.11
998.88
992.90
993.47
1007.90
992.08
NM
NM
1065.99
1042.81
28-Jun-17
1061.51
999.55
992.87
993.13
1009.84
992.82
NM
NM
1065.77
1044.86
15-Dec-17
1060.87
999.61
993.89
994.21
1010.18
992.84
993.66
993.35
1066.07
1044.92
15-May-18
1064.15
999.76
994.14
994.72
1010.78
993.22
NM
NM
1066.68
1045.76
4-Dec-18
1064.45
1000.03
995.46
995.53
1010.70
994.33
995.09
994.23
1067.96
1045.84
7-May-19
1071.05
1000.05
994.76
995.17
1011.69
993.78
NM
NM
1070.69
1047.19
6-Nov-19
1065.97
999.62
994.34
994.67
1010.35
993.39
994.24
993.96
1066.57
1044.85
20-Nov-19
NM
NM
NM
994.21
NM
NM
NM
NM
NM
NM
7-May-20
1069.16
999.88
994.28
994.86
1011.35
993.31
NM
NM
1068.31
1046.26
11-Nov-20
1071.28
1000.17
995.03
995.42
1011.11
994.06
994.25
NM
1067.92
1047.14
1-Dec-20
1072.33
NM
994.61
995.07
NM
993.57
992.65
993.44
NM
NM
4-May-21
1072.75
NM
993.96
994.52
1011.87
993.11
NM
NM
1068.07
1046.96
19-May-22
1062.64
999.35
993.42
994.07
1010.10
992.57
NM
NM
1064.24
1047.77
17-Nov-22
1061.13
999.83
995.17
994.89
1010.33
993.65
994.38
993.87
1064.90
1044.93
8-Nov-23
1061.51
998.88
991.80
992.63
1009.69
991.06
991.53
991.57
1065.49
1043.20
Notes:
NM: Groundwater Level not measured
NI: Monitoring Well not yet installed
*All Groundwater Elevations are measured in feet above mean sea level (FT - AMSL)
Burke Co. - John's River C+D-over-MSW Landfill LaBella Associates
Permit No. 12-03 1 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Sample
EPA
Analy[e
Collection Date
Method
DL
RL
MW-9 MW-17
MW-20
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-16D
Blanks
Inorganic Compounds
Antimony
30-May-07
-
6
-- ND
---
---
ND
ND
1.09
1 ND
ND
ND
ND
GWPS= 1.4 pg/L(10/23/07)
29-Nov-07
-
6
- ND
---
--
ND
ND
1.94
J ND
ND
ND
ND
29-May-08
2.6
6.0
- ND
---
---
ND
ND
ND
ND
ND
ND
ND
6-Nov-08
2.6
6.0
- ND
---
---
ND
ND
2.7
1 ND
5.9
J ND
ND
3-Jun-09
2.6
6.0
- ND
-
---
ND
ND
ND
ND
ND
3.2 1
ND
18-Nov-09
2.6
6.0
- ND
-
---
ND
ND
ND
ND
ND
ND
ND
16-Jun-10
2.6
6.0
- ND
-
---
ND
ND
2.8
1 ND
ND
ND
ND
GWPS=1pg/L(8/1/10)
1-Dec-10
2.6
6.0
- ND
ND
--
ND
3.5
J 2.9
J ND
ND
ND
ND
1-Jun-11
2.6
6.0
- ND
ND
---
ND
ND
ND
ND
ND
2.9 1
ND
20-Dec-11
5.0
6.0
- -
ND
---
ND
ND
ND
ND
ND
ND
ND
30-May-12
5.0
6.0
- -
ND
--
ND
ND
ND
ND
ND
ND
ND
5-Dec-12
5.0
6.0
- -
ND
--
ND
ND
ND
ND
ND
ND
ND
12-Jun-13
5.0
6.0
- -
ND
--
ND
ND
ND
ND
ND
ND
ND
28-Oct-13
5.0
6.0
- -
ND
--
ND
ND
ND
ND
ND
ND
ND
6-May-14
EPA 6010
5.0
6.0
- -
ND
--
ND
ND
ND
ND
ND
ND
ND
23-Oct-14
EPA 6010
5.0
6.0
- -
*
ND
ND
ND
ND
ND
ND
ND
ND
20-May-15
EPA 6010
3.8
6.0
- -
-
ND
ND
ND
ND
ND
ND
ND
ND
8-Dec-15
EPA 6010
3.8
6.0
- -
-
ND
ND
ND
6.3
ND
ND
ND
ND
Lab Re -run Analyses>
8-Dec-15
EPA 6010
3.8
6.0
- -
-
-
-
-
6.2
-
-
-
-
Resample>
4-Feb-i6
EPA 6010
3.8
6.0
- -
-
-
-
-
ND
-
-
-
ND
3-May-16
EPA 6010
3.8
6.0
- -
-
ND
ND
ND
ND
ND
ND
ND
ND
13-Dec-16
EPA 6010
3.8
6.0
- -
-
ND
ND
ND
ND
ND
ND
ND
ND
27-Jun-17
EPA 6010
3.9
6.0
- -
-
ND
ND
ND
ND
ND
ND
ND
-
13-Dec-17
EPA 6010
3.9
6.0
- -
-
ND
ND
ND
ND
ND
ND
ND
ND
IMAC=1pg/L
16-May-18
EPA 6010
3.9
6.0
- -
-
ND
ND
ND
ND
ND
ND
ND
ND
6-Dec-18
EPA 6010
3.9
5.0
- -
-
ND
ND
ND
ND
ND
ND
ND
ND
8-May-19
EPA 6010D
3.9
5.0
- -
ND
ND
ND
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA 6010D
3.0
5.0
- -
ND
ND
ND
ND
ND
ND
ND
ND
ND
8-May-20
EPA 6010D
3.0
5.0
- -
-
ND
ND
ND
ND
ND
ND
ND
ND
11-Nov-20
EPA 6010D
3.0
5.0
- -
-
ND
ND
ND
ND
ND
ND
-
ND
Resample>
28-Jan-21
EPA 6010D
3.0
5.0
- -
-
-
-
ND
-
-
-
-
-
5-May-21
EPA 6010D
3.0
5.0
- -
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
EPA 6010D
3.0
5.0
- -
-
ND
ND
6.8
ND
ND
ND
-
ND
Resample>
17-Feb-22
EPA 6010D
3.0
5.0
- -
-
-
-
ND
-
-
-
-
ND
NC2L=1
19-May-22
EPA 6020B
0.8
3.0
- -
-
ND
ND
1.1
J ND
ND
ND
-
-
17-Nov-22
EPA 6020B
0.8
3.0
- -
ND
ND
ND
ND
ND
ND
ND
-
-
6-Nov-23
EPA 6010D
3.6
5.0
- -
-
ND
3.8 J
ND
ND
ND
ND
-
--
Arsenic
30-May-07
-
10
- ND
-
--
2.2
B ND
3.6 B
ND
2.1 B
2.6 1
NC 2L = 50 pg/L (10/23/07)
29-Nov-07
-
10
- 2.5 J
-
-
ND
ND
ND
2.1
J ND
ND
29-May-08
2.7
10.0
- ND
-
-
ND
ND
ND
ND
ND
ND
6-Nov-08
2.7
10.0
- ND
-
--
3.1
B ND
3.2 B
3
B ND
4.1 1
3-Jun-09
2.7
10.0
- ND
-
---
ND
ND
ND
ND
ND
3.2 J
ND
16-Nov-09
2.7
10.0
- ND
-
---
3.0 J
ND
ND
ND
ND
ND
ND
NC 2L = 10 pg/L (01/01/10)
16-Jun-10
2.7
10.0
- ND
-
--
ND
4.6
J ND
ND
3.0
J ND
ND
1-Dec-10
2.7
10.0
- ND
ND
---
ND
ND
ND
ND
ND
ND
ND
1-Jun-11
2.7
10.0
- ND
ND
---
ND
ND
ND
ND
ND
ND
ND
20-Dec-11
5.0
10.0
- -
ND
---
ND
ND
ND
ND
ND
ND
ND
30-May-12
5.0
10.0
- -
ND
--
ND
ND
ND
ND
ND
ND
ND
5-Dec-12
5.0
10.0
- -
ND
-
ND
ND
ND
ND
ND
ND
ND
12-Jun-13
5.0
10.0
- -
ND
--
ND
ND
ND
ND
ND
ND
ND
28-Oct-13
5.0
10.0
- -
ND
---
ND
ND
ND
ND
ND
ND
ND
6-May-14
EPA 6010
5.0
10.0
- -
ND
-
ND
ND
ND
ND
ND
ND
ND
23-Oct-14
EPA 6010
5.0
10.0
- -
*
ND
ND
ND
ND
ND
ND
ND
ND
20-May-15
EPA 6010
2.5
10.0
- -
-
ND
ND
ND
ND
ND
ND
ND
ND
8-Dec-15
EPA 6010
2.5
10.0
- -
-
ND
ND
ND
ND
ND
ND
ND
ND
3-May-16
EPA 6010
2.5
10.0
- -
-
ND
ND
3.7
1 ND
ND
ND
ND
ND
13-Dec-16
EPA 6010
2.5
10.0
- -
-
ND
3.2 J
ND
ND
ND
ND
3.5 J
ND
27-Jun-17
EPA 6010
5.0
10.0
- -
-
ND
ND
ND
ND
ND
ND
ND
-
13-Dec-17
EPA 6010
5.0
10.0
- -
-
ND
ND
ND
ND
ND
ND
ND
ND
16-May-18
EPA 6010
5.0
10.0
- -
-
ND
ND
ND
ND
ND
ND
ND
ND
6-Dec-18
EPA 6010
5.0
10.0
- -
-
ND
ND
ND
ND
ND
ND
ND
ND
8-May-19
EPA 6010D
5.0
10.0
- -
ND
ND
ND
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA 6010D
4.7
10.0
- -
ND
ND
ND
ND
ND
ND
ND
ND
ND
8-May-20
EPA 6010D
4.7
10.0
- -
-
ND
5.6 1
8.5
1 9.7
J ND
7.9
J ND
ND
11-Nov-20
EPA 6010D
4.7
10.0
- -
-
ND
ND
14.3
ND
ND
ND
-
ND
Resample>
28-Jan-21
EPA 6010D
4.7
10.0
- -
-
-
-
7.5
1 -
-
-
-
-
5-May-21
EPA 6010D
4.7
10.0
- -
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
EPA 6010D
4.7
10.0
- -
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
EPA 6020B
2.2
5.0
- -
-
ND
ND
ND
ND
ND
ND
-
--
17-Nov-22
EPA 6020B
0.1
1.0
- -
0.28 J
ND
ND
2.4
0.3
J ND
0.8
J -
---
6-Nov-23
EPA 6010D
2.5
10.0
-- -
-
ND
ND
ND
ND
ND
ND
-
---
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 1 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-16D
Blanks
Barium
15-Sep-94
---
100
1320
NI
NI
NI
194
5580
ND
584
NI
NI
ND
1Oct-94
---
100
-
NI
NI
NI
-
1030
-
--
NI
NI
ND
18-Jan-95
---
100
981
NI
NI
NI
122
1490
ND
355
NI
NI
ND
6-Feb-95
---
100
435
NI
NI
Ni
124
350
ND
311
NI
NI
ND
1-Mar-95
---
100
556
NI
NI
NI
260
732
196
528
NI
NI
ND
1-Aug-95
---
100
199
NI
-
---
250
688
ND
408
NI
NI
ND
1-Jan-96
--
100
455
NI
-
--
228
734
196
ND
NI
NI
ND
1-Feb-96
-
100
306
NI
-
-
211
321
288
ND
NI
NI
ND
1-May-96
-
100
170
NI
-
--
ND
453
319
ND
NI
NI
ND
1Oct-96
-
100
302
NI
-
---
234
447
102
ND
NI
NI
ND
1-May-97
-
100
330
NI
-
---
170
360
400
ND
NI
NI
ND
1-Nov-97
-
100
800
NI
-
---
200
600
800
100
NI
NI
ND
1-May-98
-
100
400
NI
-
---
200
400
1200
200
NI
NI
ND
1-Nov-98
-
100
140
NI
-
---
270
310
880
ND
NI
NI
ND
11-May-99
-
5
240
200
-
--
70
130
200
60
220
16
ND
18-Oct-99
-
500
1900
ND
-
---
ND
ND
1400
ND
ND
ND
ND
3-May-00
-
500
ND
ND
-
---
ND
ND
ND
ND
730
ND
ND
7-Nov-00
-
500
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
31-May-01
-
500
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
7-Nov-01
-
500
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
22-May-02
-
500
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
14-Nov-02
-
500
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
14-May-03
-
500
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
20-Nov-03
-
500
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
6-May-04
-
500
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
10-Nov-04
-
500
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
5-May-05
-
500
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
3-Nov-05
-
500
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
25-May-06
-
500
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
2-Nov-06
-
500
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
30-May-07
-
100
-
52.0
J -
---
48.1
J 132
88.4
J 66.9
J 50.9
J 8.0 J
0.20 J
NC 21 2,000 Ng/L (10/23/07)
29-Nov-07
-
100
-
214
-
-
54.8
J 232
97.0
J 75.3
1 57.9
1 8.6 1
0.50 1
29-May-08
0.20
100
-
67.9
J -
--
41.5
J 148
71.0
J 77.0
J 43.7
1 7.9 1
ND
6-Nov-08
0.20
100
-
82.3
J -
--
45.5
B 118
81.2
J 90.6
J 66.7
1 7.1 B
9.6 1
3-Jun-09
0.20
100
-
34.2
B -
--
26.9
B 119
67.6
B 66.9
B 49.5
B 9.8 B
15.9 1
18-Nov-09
0.20
100
-
78.9
B -
--
36.3
B 116
88.6
B 81.0
B 46.6
B 7.8 B
20.1 1
NC 21 700 Ng/L (01/01/10)
16-1un-10
0.20
100
-
58.1
J -
-
50.5
1 296
103
73.4
1 47.0
1 8.6 1
0.77 J
1-Dec-10
0.20
100
-
60.1
1 376
--
59.6
J 134
94.1
J 78.7
J 37.5
1 16.3 1
ND
1-Jun-11
0.20
100
-
55.6
J 164
-
43.3
J 154
74.3
J 74.4
J 44.7
1 12.3 1
ND
20-Dec-11
5.0
100
-
-
119
-
50.9
J 138
76.6
J 78.3
J 46.7
J 10.5 1
ND
30-May-12
5.0
100
-
-
96.7
J -
40.6
J 137
77.7
J 74.5
J 67.8
J 9.1 1
ND
5-Dec-12
5.0
100
-
-
63.0
1 ---
53.3
1 148
89.8
J 81.4
J 43.6
J 10.5 J
ND
12-Jun-13
5.0
100
-
-
59.6
B -
28.3
B 167
82.3
J 83.6
J 48.1
B 13.2 B
13.6 1
28-Oct-13
5.0
100
-
-
47.9
1 -
47.4
1 194
93.8
J 70.7
J 49.4
J 9.6 J
ND
6-May-14
EPA 6010
5.0
100
-
-
73.6
1 -
37.3
J 129
89.9
J 73.9
J 45.5
J 8.2 J
ND
23-Oct-14
EPA 6010
5.0
100
-
-
*
20.3 J
53.4
J 127
74.6
J 76.0
J 46.3
J 13.3 J
ND
20-May-15
EPA 6010
2.5
100
-
-
-
17.9
47.5
J 145
75.5
J 76.9
J 44.6
J 8.4 J
ND
8-Dec-15
EPA 6010
2.5
100
-
-
-
17.6 1
45.6
J 140
132
82.6
J 50.6
J 8.0 J
ND
3-May-16
EPA 6010
2.5
100
-
-
-
26.6 1
43.6
J 156
82.4
J 87.3
J 51.2
J 9.5 J
ND
13-Dec-16
EPA 6010
2.5
100
-
-
-
13.4 1
66.0
J 128
83.2
J 80.9
J 48.1
J 10.0 J
ND
27-Jun-17
EPA 6010
2.5
100
-
-
-
18.8 1
47.4
J 127
81.1
J 76.2
J 50.7
J 9.9 J
-
13-Dec-17
EPA 6010
2.5
100
-
-
-
17.6 1
60.0
J 126
68.0
J 80.1
J 45.1
J 7.7 J
-
16-May-18
EPA 6010
2.5
100
-
-
-
16.1 J
57.1
J 156
65.0
J 79.4
J 50.2
J 16.0 J
ND
6-Dec-18
EPA 6010
2.5
5
-
-
-
16.1
53.7
129
70.0
80.9
47.8
8.6
ND
8-May-19
EPA 6010D
2.5
5
-
-
51.9
22.4
53.0
106
66.4
72.5
50.9
8.6
ND
8-Nov-19
EPA 6010D
1.0
5
---
-
88.3
25.6
68.5
139
90.5
82.0
52.6
8.9
ND
8-May-20
EPA 6010D
3.5
5
---
-
-
21.7
60.7
145
77.2
69.8
56.9
21.2
ND
II-Nov-20
EPA 6010D
3.5
5
---
-
-
47.4
68.8
604
90.2
75.8
59.2
-
ND
Resample>
28-Jan-21
EPA 6010D
3.5
5
---
-
-
-
-
148.0
-
-
-
-
-
5-May-21
EPA 6010D
3.5
5
---
-
-
18.2
71.0
209
70.3
87.7
52.4
-
ND
3-Nov-21
EPA 6010D
3.5
5
-
-
-
22.3
99.5
161
78.4
92.2
72.0
-
ND
19-May-22
EPA 6020B
0.7
5
-
-
-
25.8
83.6
164
66.5
76.4
60.5
-
--
17-Nov-22
EPA 6020B
0.7
5
-
-
82.2
38
52.8
168
73.2
106.0
54.7
-
---
6-Nov-23
EPA 6010D
0.8
5
-
-
-
26.5
97.3
168
66.6
82.4
60.3
-
---
Beryllium
1-May-97
-
1
ND
NI
--
--
ND
ND
1.0
ND
NI
NI
ND
1-Nov-97
-
1
1.0
NI
--
---
ND
3.0
ND
ND
NI
NI
ND
1-May-98
-
1
ND
NI
-
---
ND
ND
3.0
ND
NI
NI
ND
1-Nov-98
-
1
ND
NI
-
---
ND
ND
1
ND
NI
NI
ND
11-May-99
-
2
ND
ND
-
---
ND
ND
ND
ND
4.3
ND
ND
18-Oct-99
-
2
8.0
3.0
1 -
---
2.0
1 2.0 J
13.0
ND
ND
ND
ND
3-May-00
-
2
ND
ND
-
---
ND
ND
ND
ND
8.0
ND
ND
7-Nov-00
-
2
ND
2.0
-
---
ND
ND
ND
ND
ND
ND
ND
31-May-01
-
2
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
7-Nov-01
-
2
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
22-May-02
-
2
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
14-Nov-02
-
2
ND
ND
-
---
ND
ND
ND
ND
ND
ND
2.1
14-May-03
-
2
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
20-Nov-03
-
2
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
6-May-04
--
2
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
10-Nov-04
---
2
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
5-May-05
---
2
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
3-Nov-05
---
2
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
25-May-06
---
2
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
2-Nov-06
---
2
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
30-May-07
---
1
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
GWPS = 4 Ng/L (10/23/07)
29-Nov-07
-
1
-
ND
-
--
ND
ND
ND
ND
ND
ND
ND
29-May-08
0.10
1.0
-
ND
-
---
0.18
J ND
ND
ND
ND
ND
ND
6-Nov-08
0.10
1.0
-
0.49
B -
--
0.65
B 0.32 B
0.42
B 0.61
B 0.53
B 0.27 B
0.29 1
3-Jun-09
0.10
1.0
-
ND
-
---
ND
ND
ND
0.25
J 0.23
J 2.2
ND
18-Nov-09
0.10
1.0
-
ND
-
---
ND
ND
ND
0.25
J ND
ND
ND
16-Jun-10
0.10
1.0
-
ND
-
---
0.24
J 0.94 J
ND
0.11
J ND
ND
ND
1-Dec-10
0.10
1.0
-
ND
1.7
---
0.14
J ND
ND
ND
ND
ND
ND
1-Jun-11
0.10
1.0
-
ND
0.44
J --- J
ND
ND
ND
ND
ND
ND
ND
20-Dec-11
1.0
1.0
-
-
ND
---
ND
ND
ND
ND
ND
ND
ND
30-May-12
1.0
1.0
-
-
ND
---
ND
ND
ND
ND
ND
ND
ND
5-Dec-12
1.0
1.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
ND
12-Jun-13
1.0
1.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
ND
28-Oct-13
1.0
1.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
ND
6-May-14
EPA 6010
1.0
1.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
ND
23-Oct-14
EPA 6010
1.0
1.0
-
-
*
ND
ND
ND
ND
ND
ND
ND
ND
20-May-15
EPA 6010
0.5
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
8-Dec-15
EPA 6010
0.5
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
3-May-16
EPA 6010
0.5
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
13-Dec-16
EPA 6010
0.5
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
27-Jun-17
EPA 6010
0.5
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
-
13-Dec-17
EPA 6010
0.5
1.0
-
-
-
ND
0.73
1 1.0
0.63
J ND
0.64
J ND
ND
IMAC=4 ug/L
16-May-18
EPA 6010
0.5
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
6-Dec-18
EPA 6010
0.5
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
8-May-19
EPA 6010D
0.5
1.0
-
-
ND
ND
ND
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA 6010D
0.2
1.0
-
-
0.36
1 ND
0.39
J ND
ND
0.25
J ND
ND
ND
8-May-20
EPA 6010D
0.7
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
11-Nov-20
EPA 6010D
0.7
1.0
-
-
-
ND
ND
1.8
ND
ND
ND
-
ND
Resample>
28-Jan-21
EPA 6010D
0.7
1.0
-
-
-
-
-
ND
-
-
-
-
-
5-May-21
EPA 6010D
0.7
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
EPA 6010D
0.7
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
EPA 6020B
0.1
0.5
-
-
-
0.054 J
0.42
J ND
ND
0.17
J 0.06
J -
---
NC2L=4
17-Nov-22
EPA 6020B
0.1
0.5
-
-
0.27
J ND
ND
0.1 J
ND
ND
ND
-
---
6-Nov-23
EPA 6010D
0.2
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
---
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 2 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Analy[e
Sample
Collection Date
EPA
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW10
MW-11
MW-12
MW-13
MW-16S
MW-161D
Blanks
Cadmium
1-May-97
---
1
ND
NI
ND
ND
1.0
ND
NI
NI
ND
1-Nov-97
---
1
ND
NI
ND
ND
ND
ND
NI
NI
ND
1-May-98
---
1
ND
NI
---
---
ND
ND
1.0
ND
NI
NI
ND
1-Nov-98
---
1
ND
NI
-
---
ND
ND
2.0
ND
NI
NI
ND
II-May-99
--
1
ND
ND
--
---
ND
ND
ND
ND
ND
ND
ND
18-Oct-99
-
1
24.0
6.0
---
---
6.0
3.0
1 30.0
2.0
J 2.0
J ND
ND
3-May-00
-
1
ND
ND
---
---
ND
1.0
1 1.0
1 ND
5.0
ND
ND
7-Nov-00
-
1
2.0
5.0
-
---
ND
ND
1.0
ND
1.0
ND
ND
31-May-01
-
1
ND
ND
-
---
ND
ND
1.0
1 ND
1.0
1 ND
ND
7-Nov-01
-
1
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
22-May-02
-
1
ND
ND
-
---
ND
ND
ND
2.0
B ND
ND
1.3
14-Nov-02
-
1
ND
ND
-
---
ND
ND
1.2
ND
3.7
ND
ND
14-May-03
-
1
ND
ND
-
---
1.1
ND
ND
ND
2.5
ND
ND
20-Nov-03
-
1
2.0
1.3
-
---
ND
ND
1.2
ND
ND
ND
ND
6-May-04
-
1
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
10-Nov-04
-
1
ND
ND
-
---
1.5
ND
ND
ND
2.2
ND
ND
5-May-05
-
1
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
3-Nov-05
-
1
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
25-May-06
-
1
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
2-Nov-06
-
1
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
30-May-07
---
1
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
NC 2L = 1.75 pg/L (10/23/07)
29-Nov-07
-
1
-
ND
-
--
ND
ND
0.60
J ND
ND
ND
ND
29-May-08
0.50
1.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
6-Nov-08
0.50
1.0
-
ND
-
---
ND
ND
ND
ND
0.94
J ND
ND
3-Jun-09
0.50
1.0
-
ND
-
---
ND
ND
ND
ND
ND
1.9
ND
16-Nov-09
0.50
1.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
NC 2L = 2 pg/L (01/01/10)
16-Jun-10
0.50
1.0
-
ND
-
--
ND
6.0
ND
ND
ND
ND
ND
Resample>
5-Aug-10
0.50
1.0
-
-
-
---
-
1.2
-
-
-
-
ND
1-Dec-10
0.50
1.0
-
ND
ND
---
ND
ND
ND
ND
ND
ND
ND
1-Jun-11
0.50
1.0
-
ND
ND
---
ND
ND
ND
ND
ND
ND
ND
20-Dec-11
1.0
1.0
-
-
ND
---
ND
ND
ND
ND
ND
ND
ND
30-May-12
1.0
1.0
-
-
ND
---
ND
ND
ND
ND
ND
ND
ND
5-Dec-12
1.0
1.0
-
-
ND
---
ND
ND
ND
ND
ND
ND
ND
12-Jun-13
1.0
1.0
-
-
ND
---
ND
ND
ND
ND
ND
ND
ND
28-Oct-13
1.0
1.0
-
-
ND
---
ND
ND
ND
ND
ND
ND
ND
6-May-14
EPA 6010
1.0
1.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
ND
23-Oct-14
EPA 6010
1.0
1.0
-
-
*
ND
ND
ND
ND
ND
ND
ND
ND
20-May-15
EPA 6010
0.5
1.0
-
-
-
ND
ND
0.85
J ND
ND
ND
ND
ND
8-Dec-15
EPA 6010
0.5
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
3-May-16
EPA 6010
0.5
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
13-Dec-16
EPA 6010
0.5
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
27-Jun-17
EPA 6010
0.5
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
-
13-Dec-17
EPA 6010
0.5
1.0
-
-
-
ND
0.64
J 1.6
2.9
0.88
J 0.80
J ND
ND
Resample>
19-Mar-18
EPA 6010
0.5
1.0
-
-
-
-
-
-
ND
-
-
-
16-May-18
EPA 6010
0.5
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
6-Dec-18
EPA 6010
0.5
1.0
-
-
-
ND
0.56
1 1.0
ND
ND
0.51
J ND
ND
8-May-19
EPA 6010D
0.5
1.0
-
-
ND
ND
ND
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA 6010D
0.4
1.0
-
-
ND
ND
ND
ND
ND
ND
ND
ND
ND
8-May-20
EPA 6010D
0.4
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
11-Nov-20
EPA 6010D
0.4
1.0
-
-
-
ND
ND
0.74
J ND
ND
ND
-
ND
Resample>
28-Jan-21
EPA 6010D
0.4
1.0
-
-
-
-
-
ND
-
-
-
-
-
5-May-21
EPA 6010D
0.4
1.0
-
-
-
ND
ND
ND
ND
0.51
J ND
-
ND
3-Nov-21
EPA 6010D
0.4
1.0
-
-
-
ND
0.44
1 ND
ND
0.79
J ND
-
ND
19-May-22
EPA 6020B
0.1
0.5
-
-
-
ND
ND
ND
ND
0.22
1 ND
-
-
17-Nov-22
EPA 6020B
0.1
0.5
-
-
ND
ND
ND
ND
ND
1.00
ND
-
--
6-Nov-23
EPA 6010D
0.3
1.0
-
-
-
ND
0.33
1 1.0
ND
0.31
J ND
-
-
Chromium
1-Mar-95
--
5
ND
NI
NI
NI
ND
ND
11.0
ND
NI
NI
ND
1-Aug-95
-
5
ND
NI
-
-
ND
ND
ND
ND
NI
NI
ND
1-Jan-96
-
5
ND
NI
-
--
ND
ND
7.0
ND
NI
NI
ND
1-Feb-96
-
5
ND
NI
-
---
ND
ND
6.0
ND
NI
NI
ND
1-May-96
-
5
ND
NI
-
---
ND
ND
16.0
ND
NI
NI
ND
1Oct-96
-
5
ND
NI
-
---
ND
ND
6.0
ND
NI
NI
ND
1-May-97
--
1
4.0
NI
-
---
2.0
3.0
18.0
3.0
NI
NI
ND
1-Nov-97
---
1
6.0
NI
-
---
1.0
1.0
108
2.0
NI
NI
ND
1-May-98
---
1
8.0
NI
-
---
4.0
6.0
66.0
6.0
NI
NI
ND
1-Nov-98
--
1
3.0
NI
-
---
1.0
3.0
180
3.0
NI
NI
ND
11-May-99
-
5
26.0
24.0
-
---
8.4
6.5
44.0
11.0
46.0
ND
ND
18-Oct-99
-
10
290
58.0
-
---
44.0
36.0
410
21.0
ND
ND
ND
3-May-00
-
10
ND
ND
-
---
ND
ND
12.0
ND
92.0
ND
ND
7-Nov-00
-
10
11.0
30.0
-
---
ND
ND
ND
ND
ND
ND
ND
31-May-01
-
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
7-Nov-01
-
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
22-May-02
-
10
ND
ND
-
---
ND
ND
ND
ND
10.0
ND
ND
14-Nov-02
-
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
14-May-03
-
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
20-Nov-03
-
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
6-May-04
-
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
10-Nov-04
-
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
5-May-05
-
10
12.0
ND
-
---
ND
ND
ND
ND
ND
ND
ND
3-Nov-05
-
10
--
ND
-
---
ND
ND
ND
ND
ND
ND
ND
25-May-06
-
10
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
2-Nov-06
-
10
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
30-May-07
-
10
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
NC 2L = 50 pg/L (10/23/07)
29-Nov-07
-
10
-
ND
-
--
ND
ND
ND
ND
ND
ND
ND
29-May-08
0.40
10.0
-
ND
-
---
ND
1.9
B 1
B 1.4
B ND
ND
0.85 J
6-Nov-08
0.40
10.0
-
0.59 J
-
---
1
J 0.83
J 2.8
J 3.4
J 2.5
J ND
ND
3-Jun-09
0.40
10.0
-
ND
-
---
ND
2.1
J ND
1.1
J 0.66
J 2.1 1
ND
16-Nov-09
0.40
10.0
-
ND
-
---
ND
ND
2.2
J 2.2
J ND
ND
ND
NC 2L = 10 pg/L (01/01/10)
16-Jun-10
0.40
10.0
-
0.43 B
-
-
1.0
B 13.9
4.7
J 1.0
B ND
ND
0.74 J
Resample>
5-Aug-10
0.40
10.0
-
-
-
---
--
0.88
B -
-
-
-
0.51 J
1-Dec-10
0.40
10.0
-
0.60 B
39.6
---
1.8
B 1.3
B 5.5
J 1.2
B ND
ND
0.51 J
Resample>
13-Jan-11
0.40
10.0
-
-
ND
---
--
-
-
-
-
-
ND
1-Jun-11
0.40
10.0
-
ND
11.2
---
ND
1.2
B 0.72
B ND
ND
ND
0.73 J
Resample>
7-Jul-11
0.40
10.0
-
-
7.8
1 ---
-
-
-
-
-
-
ND
20-Dec-11
5.0
10.0
-
-
8.2
1 ---
ND
ND
ND
ND
ND
ND
ND
30-May-12
5.0
10.0
-
-
5.3
J --
ND
ND
ND
ND
5.4
J ND
ND
5-Dec-12
5.0
10.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
ND
12-Jun-13
5.0
10.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
ND
28-Oct-13
5.0
10.0
-
-
ND
---
ND
ND
ND
ND
ND
ND
ND
6-May-14
EPA 6010
5.0
10.0
-
-
6.1
1 ---
ND
ND
ND
ND
ND
ND
ND
23-Oct-14
EPA 6010
5.0
10.0
-
-
*
ND
ND
ND
ND
ND
ND
ND
ND
20-May-15
EPA 6010
2.5
10.0
-
-
-
ND
ND
3.9
J ND
ND
ND
4.7 J
ND
8-Dec-15
EPA 6010
2.5
10.0
-
-
-
ND
ND
ND
13.8
ND
ND
ND
ND
Lab Re -run Analyses>
8-Dec-15
EPA 6010
2.5
10.0
-
-
-
-
-
-
14.7
-
-
-
-
Resample>
4-Feb-16
EPA 6010
2.5
10.0
-
-
-
-
-
-
ND
-
-
-
ND
3-May-16
EPA 6010
2.5
10.0
-
-
-
4.2 J
ND
3.1
J 4.1
J 4.5
J ND
ND
ND
13-Dec-16
EPA 6010
2.5
10.0
-
-
-
ND
ND
3.7
J 4.4
J ND
ND
ND
ND
27-Jun-17
EPA 6010
2.5
10.0
-
-
-
ND
ND
3.9
J 5.8
1 ND
ND
ND
-
13-Dec-17
EPA 6010
2.5
10.0
-
-
-
ND
ND
0.4
J 2.6
J ND
ND
5.5 J
ND
16-May-18
EPA 6010
2.5
10.0
-
-
-
ND
ND
4.6
J ND
ND
ND
ND
ND
6-Dec-18
EPA 6010
2.5
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
Resample>
7-Feb-19
EPA 6010
2.5
5.0
-
-
4.6
1 -
-
-
-
-
-
-
ND
8-May-19
EPA 6010D
2.5
5.0
-
-
4.5
1 ND
ND
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA 6010D
1.0
5.0
-
-
6.0
2.4 J
ND
ND
ND
ND
ND
ND
ND
8-May-20
EPA 6010D
3.7
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
11-Nov-20
EPA 6010D
3.7
5.0
-
-
-
7.0
ND
26.0
ND
ND
ND
-
ND
Resample>
28-Jan-21
EPA 6010D
3.7
5.0
-
-
-
-
-
5.5
-
-
-
-
-
5-May-21
EPA 6010D
3.7
5.0
-
-
-
ND
ND
52.9
ND
ND
ND
-
ND
3-Nov-21
EPA 6010D
3.7
5.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
EPA 6020B
1.1
5.0
-
-
-
2.5 1
ND
ND
2.6
J ND
ND
-
---
17-Nov-22
EPA 6020B
1.1
5.0
-
-
3.6
1, ND
ND
3.4
23.3
6.1
1.9
-
---
6-Nov-23
EPA 6010D
0.6
5.0
-
-
-
0.98 1
3.8
1 6.1
3.4
J 1.4
J 3.7
J -
---
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 3 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-16D
Blanks
Cobalt
1&Jan-95
---
10
35.0
NI
NI
NI
35.0
14.0
52.0
14.0
NI
NI
ND
6-Feb-95
-
10
16.0
NI
NI
NI
43.0
ND
66.0
ND
NI
NI
ND
Mar-95
-
10
28.0
NI
NI
NI
57.0
ND
78.0
20.0
NI
NI
ND
Aug-95
-
10
ND
NI
-
---
58.0
ND
30.0
32.0
NI
NI
ND
Jan-96
-
10
17.0
NI
-
---
37.0
ND
23.0
ND
NI
NI
ND
Feb-96
-
10
37.0
NI
-
---
41.0
ND
24.0
ND
NI
NI
ND
May-96
-
10
11.0
NI
-
---
26.0
ND
24.0
ND
NI
NI
ND
Oct-96
-
10
16.0
NI
-
---
52.0
ND
16.0
ND
NI
NI
ND
May-97
-
6
33.0
NI
-
---
120
5.0
1 32.0
6.0
NI
NI
ND
Nov-97
-
5
29.0
NI
-
---
99.0
11.0
48.0
14.0
NI
NI
ND
May-98
--
1
28.0
NI
-
---
120
8.0
76.0
32.0
NI
NI
ND
Nov-98
--
1
10.0
NI
-
---
140
6.0
47.0
1.0
NI
NI
ND
11-May-99
-
5
20.0
26.0
-
--
48.0
13.0
34.0
17.0
59.0
ND
ND
18-Oct-99
-
10
120
37.0
-
--
85.0
20.0
220
16.0
40.0
ND
ND
3-May-00
-
10
ND
ND
-
---
54.0
ND
31.0
13.0
89.0
ND
ND
7-Nov-00
-
10
ND
20.0
-
---
40.0
ND
18.0
ND
32.0
ND
ND
31-May-01
-
10
ND
ND
-
---
53.0
ND
30.0
11.0
32.0
ND
ND
7-Nov-01
-
10
ND
ND
-
---
29.0
ND
23.0
ND
26.0
ND
ND
22-May-02
-
10
14.0 B
14.0
B -
--
68.0
16.0
B 51.0
B 17.0
B 39.0
B 12.0 B
11.0
14-Nov-02
-
10
ND
ND
-
---
90.0
ND
41.0
11.0
34.0
ND
ND
14-May-03
-
10
19.0
ND
-
---
280
ND
46.0
53.0
24.0
ND
ND
20-Nov-03
-
10
26.0
10.0
1 -
--
340
18.0
56.0
58.0
30.0
ND
ND
6-May-04
-
10
ND
ND
-
---
140
ND
46.0
47.0
29.0
ND
ND
10-Nov-04
-
10
10.0
ND
-
---
170
21.0
50.0
46.0
29.0
ND
ND
5-May-05
-
10
12.0
ND
-
---
130
16.0
46.0
60.0
26.0
ND
ND
3-Nov-05
--
10
-
ND
-
---
66.0
15.0
42.0
45.0
25.0
ND
ND
25-May-06
--
10
-
ND
-
---
80.3
21.7
42.7
43.2
24.9
ND
ND
2-Nov-06
-
10
-
ND
-
---
131
30.8
37.0
28.3
26.6
ND
ND
30-May-07
-
10
-
4.1
1 -
---
87.2
20.7
44.0
36.9
26.6
ND
ND
GWPS = 70 pg/L (10/23/07)
29-Nov-07
-
10
-
7.3
J -
--
67.2
55.5
47.9
J 23.4
30.7
ND
ND
29-May-08
0.60
10.0
-
5.4
J -
--
71.9
54.6
34.8
35.3
ND
ND
ND
6-Nov-08
0.60
10.0
-
9.2
1 -
---
71.9
60.0
47.9
44.1
24.3
2.2 B
1.6 1
3-Jun-09
0.60
10.0
-
22.8
B -
--
139
78.6
53.5
49.3
54.7
7.6 B
7.6 1
Resample>
27-Aug-09
0.60
10.0
-
-
-
---
60.0
-
-
-
-
-
-
1&Nov-09
0.60
10.0
-
14.9
-
--
126
84.5
50.3
44.1
31.8
ND
ND
16-Jun-10
0.60
10.0
-
19.1
-
--
96.1
103
70.9
38.0
48.6
ND
ND
Resample>
5-Aug-10
0.60
10.0
-
-
-
---
-
85.5
-
-
-
-
ND
GWPS = 1 pg/L (10/1/10)
1-Dec-10
0.60
10.0
-
9.8
J 22.1
---
72.7
151
111
43.1
33.3
ND
ND
Resample>
13-Jan-11
0.60
10.0
-
-
ND
---
-
84.2
-
-
-
-
ND
1-Jun-11
0.60
10.0
-
7.8
1 2.6
1 --- J
76.4
99.3
72.9
41.7
38.6
ND
ND
20-Dec-11
5.0
10.0
-
-
ND
---
92.8
75.6
62.7
36.5
25.5
ND
ND
30-May-12
5.0
10.0
-
-
ND
---
90.2
108
78.8
42.3
46.2
ND
ND
5-Dec-12
5.0
10.0
-
-
ND
--
46.6
27.9
101
45.8
51.4
ND
ND
12-Jun-13
5.0
10.0
-
-
ND
-
243
150
118
92.2
66.0
ND
ND
28-Oct-13
5.0
10.0
-
-
ND
--
200
128
124
117
75.7
ND
ND
Resample>
10-Dec-13
5.0
10.0
-
-
-
--
-
---
-
40.4
-
-
ND
6-May-14
EPA 6010
5.0
10.0
-
-
ND
-
138
33.4
68.9
65.9
26.6
ND
ND
22-Oct-14
EPA 6010
5.0
10.0
-
-
*
ND
126
37.1
82.0
74.9
32.1
ND
ND
20-May-15
EPA 6010
2.5
10.0
-
-
-
ND
116
34.8
77.8
90.0
34.0
ND
ND
8-Dec-15
EPA 6010
2.5
10.0
-
-
-
ND
175
61.0
84.8
49.7
32.8
ND
ND
3-May-16
EPA 6010
2.5
10.0
-
-
-
4.0 1
132
52.6
69.7
85.0
27.6
ND
ND
13-Dec-16
EPA 6010
2.5
10.0
-
-
-
ND
93.2
52.4
70.6
58.8
28.1
ND
ND
27-1un-17
EPA 6010
2.5
10.0
-
-
-
ND
121
60.5
74.0
75.5
35.4
ND
-
13-Dec-17
EPA 6010
2.5
10.0
-
-
-
ND
73.9
54.4
66.5
93.6
31.1
ND
ND
IMAC=1pg/L
16-May-18
EPA 6010
2.5
10.0
-
-
-
ND
64.8
55.1
61.0
83.0
33.0
ND
ND
6-Dec-18
EPA 6010
2.5
5.0
-
-
-
ND
74.3
58.0
67.9
102
38.1
ND
ND
Resample>
7-Feb-19
EPA 6010
2.5
5.0
-
-
ND
-
-
---
-
-
-
-
ND
BKGD=11.3 pg/L
8-May-19
EPA 6010D
2.5
5.0
-
-
ND
ND
64.0
48.6
57.5
92.7
36.8
ND
ND
8-Nov-19
EPA 6010D
1.1
5.0
-
-
2.2
1 2.8 1
53.8
52.0
70.1
66.0
32.8
ND
ND
8-May-20
EPA 6010D
3.6
5.0
-
-
-
ND
60.4
51.1
68.6
140
35.8
ND
ND
11-Nov-20
EPA 6010D
3.6
5.0
-
-
-
8.7
68.8
68.5
66.3
109
37.1
-
ND
Resample>
28-Jan-21
EPA 6010D
3.6
5.0
-
-
-
ND
-
65.3
-
-
-
-
-
5-May-21
EPA 6010D
3.6
5.0
-
-
-
ND
56.9
62.1
61.8
124
33.1
-
ND
3-Nov-21
EPA 6010D
3.6
5.0
-
-
-
ND
65.9
66.0
68.5
85.0
33.3
-
ND
19-May-22
EPA 6020B
0.4
5.0
-
-
-
1.6 1
57.7
73.0
59.1
88.5
40.1
-
-
17-Nov-22
EPA 6020B
0.4
5.0
-
-
1.5
J 3.7 J
30.5
55.8
61.2
121.0
37.7
-
--
6-Nov-23
EPA 6010D
0.4
5.0
-
-
-
0.56 1
47.5
19.8
33.9
69.8
28.0
-
-
Copper
1&Jan-95
-
10
16.0
NI
NI
NI
ND
ND
ND
14.0
NI
NI
ND
6-Feb-95
-
10
ND
NI
NI
NI
ND
ND
ND
ND
NI
NI
ND
1-Mar-95
-
10
ND
NI
NI
NI
ND
ND
ND
20.0
NI
NI
ND
1-Aug-95
-
10
ND
NI
-
---
ND
ND
ND
18.0
NI
NI
ND
1-Jan-96
--
10
ND
NI
-
---
ND
ND
ND
ND
NI
NI
ND
1-Feb-96
---
10
21.0
NI
-
---
ND
ND
ND
ND
NI
NI
ND
1-May-96
---
10
14.0
NI
-
---
13.0
11.0
ND
11.0
NI
NI
ND
1Oct-96
---
10
ND
NI
-
---
ND
ND
ND
ND
NI
NI
ND
1-May-97
---
10
ND
NI
-
---
30.0
ND
ND
ND
NI
NI
ND
1-Nov-97
--
10
ND
NI
-
---
ND
ND
ND
ND
NI
NI
ND
1-May-98
-
10
20.0
NI
-
---
ND
10.0
70.0
20.0
NI
NI
ND
1-Nov-98
-
10
ND
NI
-
---
13.0
ND
28.0
ND
NI
NI
ND
11-May-99
-
5
28.0
49.0
-
---
14.0
ND
9.3
28.0
37.0
ND
ND
18-Oct-99
-
200
380
ND
-
---
ND
ND
240
ND
ND
ND
ND
3-May-00
-
200
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
7-Nov-00
-
200
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
31-May-01
-
200
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
7-Nov-01
-
200
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
22-May-02
-
200
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
14-Nov-02
-
200
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
14-May-03
-
200
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
20-Nov-03
-
200
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
6-May-04
-
200
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
10-Nov-04
-
200
ND
ND
-
---
ND
NO,
ND
ND
ND
ND
ND
5-May-05
-
200
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
3-Nov-05
-
200
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
25-May-06
-
200
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
2-Nov-06
-
200
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
30-May-07
-
10
-
0.7
B -
---
ND
ND
ND
3.2
B ND
ND
1.3 J
NC 21 1,000 pg/L (10/23/07)
29-Nov-07
-
10
-
8.30
J -
--
ND
ND
ND
6.10
1 ND
ND
ND
29-May-08
0.30
10.0
-
0.42
B -
--
0.99
B 1.5
B 1.0
B 14.9
0.89
B ND
0.37 1
6-Nov-08
0.30
10.0
-
2.0
B -
--
1.8
B 0.7
B 2.4
B 16.6
4.2
1 0.46 B
0.65 1
3-Jun-09
0.30
10.0
-
0.83
J -
---
ND
1
J ND
6.7
1 0.61
1 3.5 J
ND
18-Nov-09
0.30
10.0
-
0.34
J -
--
ND
ND
1.2
J 10.7
0.38
J ND
ND
16-Jun-10
0.30
10.0
-
0.37
B -
--
2.6
B 9.0
J 3.2
B 3.4
B ND
ND
0.77 1
1-Dec-10
0.30
10.0
-
1.3
J 36.1
--
3.8
J 1.2
J 1.8
J 3.9
J 2.1
J ND
ND
1-Jun-11
0.30
10.0
-
0.54
J 12.9
--
0.94
J 2.3
J 0.79
J 4.8
J 0.66
J ND
ND
20-Dec-11
5.0
10.0
-
-
9.0
1 ---
ND
ND
ND
ND
ND
ND
ND
30-May-12
5.0
10.0
-
-
7.0
1 --
ND
ND
ND
ND
5.6
J ND
ND
5-Dec-12
5.0
10.0
-
-
ND
--
ND
ND
ND
5.6
1 ND
ND
ND
12-Jun-13
5.0
10.0
-
-
34.0
B --
ND
ND
ND
11.1
B ND
ND
9.8 J
28-Oct-13
5.0
10.0
-
-
ND
--
ND
6.1
1 ND
ND
ND
ND
ND
6-May-14
EPA 6010
5.0
10.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
ND
23-Oct-14
EPA 6010
5.0
10.0
-
-
*
ND
ND
ND
ND
ND
ND
ND
ND
20-May-15
EPA 6010
2.5
10.0
-
-
-
ND
ND
ND
ND
4.6
J ND
ND
ND
8-Dec-15
EPA 6010
2.5
10.0
-
-
-
ND
8.1
1 6.4
J 9.7
1 ND
5.9
J ND
ND
3-May-16
EPA 6010
2.5
10.0
-
-
-
8.7 1
ND
ND
ND
9.6
J ND
8.6 J
ND
13-Dec-16
EPA 6010
2.5
10.0
-
-
-
4.1 1
ND
ND
ND
ND
ND
ND
ND
27-Jun-17
EPA 6010
2.5
10.0
-
-
-
3.9 1
ND
ND
ND
ND
ND
ND
-
13-Dec-17
EPA 6010
2.5
10.0
-
-
-
ND
ND
7.3
1 ND
10.2
ND
ND
ND
16-May-18
EPA 6010
2.5
10.0
-
-
-
ND
ND
ND
ND
3.6
J ND
ND
ND
6-Dec-18
EPA 6010
2.5
5.0
-
-
-
ND
ND
ND
ND
9.1
ND
ND
ND
8-May-19
EPA 6010D
2.5
5.0
-
-
2.8
1 3.3 1
ND
ND
ND
6.5
ND
ND
ND
8-Nov-19
EPA 6010D
2.1
5.0
-
-
6.7
6.0
ND
2.4
J 2.8
J 5.6
2.7
J ND
ND
8-May-20
EPA 6010D
4.3
5.0
-
-
-
4.5 1
ND
4.8
1 ND
ND
ND
ND
ND
11-Nov-20
EPA 6010D
4.3
5.0
-
-
-
19.7
ND
25.0
ND
5.0
ND
-
ND
Resample>
28-Jan-21
EPA 6010D
4.3
5.0
-
-
-
-
-
ND
-
-
-
-
-
5-May-21
EPA 6010D
4.3
5.0
-
-
-
ND
ND
ND
ND
12.8
ND
-
ND
3-Nov-21
EPA 6010D
4.3
5.0
-
-
-
6.2
ND
ND
ND
36.8
ND
-
ND
19-May-22
EPA 6020B
1.0
5.0
-
-
-
2.7 1
1.3
J ND
ND
14.9
ND
-
-
17-Nov-22
EPA 6020B
1.1
2.0
-
-
5.3
5.6
ND
ND
1.2
J 62.5
ND
-
-
6-Nov-23
EPA 6010D
0.6
5.0
-
-
-
1.8 1
5.6
ND
ND
12.0
ND
-
-
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 4 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
MW-9
MW47
MW-20
MW-21
MW40
MW41
MW42
MW43
MW46S
MW46D
Blanks
Cyanide
1-Nov-98
-
2
6.0
NI
-
-
2.0
ND
7.0
ND
NI
NI
ND
11-May-99
-
2
ND
ND
-
-
ND
ND
ND
ND
ND
ND
ND
18-Oct-99
--
50
ND
ND
-
-
-
ND
ND
ND
ND
ND
ND
7-Nov-00
--
50
ND
-
-
-
ND
ND
ND
ND
ND
-
ND
31-May-01
--
50
ND
-
-
-
ND
ND
ND
ND
ND
-
ND
7-Nov-01
--
50
ND
-
-
-
ND
ND
ND
ND
ND
-
ND
14-Nov-02
--
50
ND
-
-
-
ND
ND
ND
ND
ND
-
ND
20-Nov-03
--
50
ND
-
-
-
ND
ND
ND
ND
ND
-
ND
10-Nov-04
--
10
ND
-
-
-
ND
ND
ND
ND
ND
-
ND
3-Nov-05
--
-
-
ND
-
-
ND
ND
ND
ND
ND
-
ND
2-Nov-06
--
50
-
ND
-
-
ND
ND
ND
ND
ND
-
ND
NC 2L = 70 pg/L (10/23/07)
29-Nov-07
-
10
-
ND
-
-
ND
ND
ND
ND
ND
-
ND
6-Nov-08
5.0
10.0
-
ND
-
-
ND
ND
ND
ND
ND
-
ND
18-Nov-09
5.0
10.0
-
ND
-
-
ND
ND
ND
ND
ND
-
ND
1-Dec-10
5.0
10.0
-
ND
5.9 J
-
ND
ND
5.2
J 5.8
J 6.5
J -
ND
Resample>
13-Jan-11
5.0
10.0
-
-
ND
-
-
-
5.0
J ND
5.8
J -
ND
5-Dec-12
5.0
10.0
-
-
ND
-
ND
ND
ND
ND
7.0
1 -
ND
28-Oct-13
5.0
10.0
-
-
ND
-
12.4
5.6 J
10.0
ND
6.5
J ND
ND
Resample>
10-Dec-13
5.0
10.0
-
-
-
-
10.8
-
9.0
J -
-
-
ND
6-May-14
SM 4500-CN-E
0.0
0.0
-
-
ND
-
ND
ND
ND
ND
ND
-
ND
23-Oct-14
SM 4500-CN-E
2.5
10.0
-
-
*
ND
3.6
J 4.7 J
4.2
J ND
5.2
J -
ND
20-May-15
SM 4500-CN-E
0.0
10.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
8-Dec-15
SM 4500-CN-E
4.0
10.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-May-16
SM 4500-CN-E
4.0
10.0
-
-
-
ND
ND
ND
5.3
1 ND
ND
-
ND
13-Dec-16
SM 4500-CN-E
4.0
10.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
27-Jun-17
SM 4500-CN-E
4.0
10.0
-
-
-
ND
ND
ND
ND
ND
4.3
1 -
-
13-Dec-17
SM 4500-CN-E
4.0
10.0
-
-
-
-
5.5
J 7.6 J
7.6
J ND
8.7
J -
-
16-May-18
SM 4500-CN-E
4.0
10.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
6-Dec-18
SM 4500-CN-E
4.0
8.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
8-May-19
µ �-�-
6.0
8.0
-
-
-
-
ND
ND
ND
ND
ND
-
ND
8-Nov-19
6.0
8.0
-
-
-
ND
ND
ND
7.7
J ND
6.8
J -
-
8-May-20
µ �-�-
6.0
8.0
-
-
-
ND
ND
ND
ND
ND
6.5
1 -
--
11-Nov-20
6.0
8.0
-
-
-
ND
ND
ND
ND
ND
7.5
J -
-
5-May-21
�-`-
6.0
8.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
6.0
8.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
�-`-
6.0
8.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
17-Nov-22
6.0
8.0
-
-
-
ND
ND
ND
ND
ND
ND
-
-
6-Nov-23
��-�-
6.0
8.0
-
-
-
ND
ND
ND
ND
ND
ND
-
--
Iron
1-Jun-11
14.0
300
-
308
11,000
-
20,500
29,200
16,300
886
22,200
413
ND
Resample>
7-Jul-11
50.0
300
-
-
7,150
-
-
-
-
-
-
-
ND
NC 2L = 300 pg/L (01/01/10)
20-Dec-11
50.0
300
-
-
8,010
-
26,300
36,700
22,900
1,160
22,200
93.5 1
ND
30-May-12
50.0
300
-
--
5,940
-
24,500
45,700
21,700
1,300
24,500
ND
ND
5-Dec-12
50.0
300
-
-
2,970
-
7,010
8,730
28,200
393
21,700
159 J
ND
12-Jun-13
50.0
300
-
-
2,460
-
55,300
55,300
34,800
4,650
26,700
522
81.2 J
28-Oct-13
50.0
300
-
-
883
-
28,700
49,700
29,800
1,730
24,300
ND
ND
6-May-14
EPA 6010
50.0
300
-
-
4,240
-
47,300
46,800
29,700
1,200
24,600
ND
ND
23-Oct-14
EPA 6010
50.0
300
-
-
*
2,340
33,600
29,200
31,200
528
27,700
171 1
ND
20-May-15
EPA 6010
25.0
300
-
-
-
350
22,400
22,600
33,800
672
25,800
63.5 1
ND
8-Dec-15
EPA 6010
25.0
300
-
-
-
1,380
102,000
74,200
50,200
1,460
27,400
43.7 1
ND
3-May-16
EPA 6010
25.0
300
-
-
-
7,630
39,300
67,900
42,400
3,870
24,000
168 1
27.3 1
13-Dec-16
EPA 6010
25.0
300
-
-
-
2,020
17,600
67,800
45,300
969
24,000
217 1
ND
27-Jun-17
EPA 6010
25.0
300
-
-
-
2,340
58,100
67,400
51,800
1,230
29,100
213 1
-
13-Dec-17
EPA 6010
25.0
300
-
-
-
1,030
21,400
68,800
40,900
2,600
26,300
62.6 1
ND
16-May-18
EPA 6010
25.0
300
-
-
-
295 J
18,900
62,200
43,600
1,030
31,800
402
ND
6-Dec-18
EPA 6010
25.0
50
-
-
-
141
43,300
72,100
43,000
1,740
35,300
84.2
ND
Resample>
7-Feb-19
EPA 6010
25.0
50
-
-
3,290
-
-
-
-
-
-
-
ND
BKGD = 14,182 pg/L
8-May-19
EPA 6010D
25.0
50
-
-
2,900
2,550
26,400
61,600
37,200
2,320
29,400
47.8 1
ND
8-Nov-19
EPA 6010D
19.5
50
-
-
5,530
4,320 C
20,100
72,800
44,400
1,830
28,400
20.2 1
ND
8-May-20
EPA 6010D
41.5
50
-
-
-
2,580
30,200
70,100
47,600
2,280
32,600
1,100
ND
11-Nov-20
EPA 6010D
41.5
50
-
-
-
15,400
37,600
147,000
52,200
1,890
36,600
-
ND
Resample>
28-Jan-21
EPA 6010D
41.5
50
-
-
-
799
-
98,000
-
-
---
-
-
5-May-21
EPA 6010D
41.5
50
-
-
-
202
28,100
108,000
43,800
3,760
36,600
-
ND
3-Nov-21
EPA 6010D
41.5
50
-
-
-
812
19,100
104,000
47,600
1,570
42,300
-
ND
19-May-22
EPA 6020B
1480.0
2000
-
-
-
905
24,600
125,000
47,100
860
47,600
-
-
17-Nov-22
EPA 6020B
105.0
250
-
-
4550 M1
373
36,100
115,000
59,200
4,640
43,700
---
--
6-Nov-23
EPA 6010D
8.9
50
-
-
-
574
22,800
136,000
47,000
3,090
39,200
---
--
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 5 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Anal a
Sample
Collection Date
EPA
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-16D
Blanks
Lead
15-Sep-94
---
5
41.0
NI
NI
NI
12.0
49.0
7.0
43.0
NI
NI
ND
1-Oct-94
--
5
-
NI
NI
NI
-
9.0
-
-
NI
NI
ND
18-Jan-95
-
5
35.0
NI
NI
NI
9.0
17.0
10.0
30.0
NI
NI
ND
6-Feb-95
-
5
15.0
NI
NI
NI
7.0
ND
ND
26.0
NI
NI
ND
1-Mar-95
-
5
26.0
NI
NI
NI
16.0
12.0
9.0
43.0
NI
NI
ND
1-Aug-95
-
5
11.0
NI
-
---
25.0
16.0
6.0
48.0
NI
NI
ND
1-Jan-96
-
5
22.0
NI
-
---
18.0
12.0
10.0
7.0
NI
NI
ND
1-Feb-96
-
5
16.0
NI
-
---
15.0
6.0
9.0
10.0
NI
NI
ND
1-May-96
-
5
7.0
NI
-
---
8.0
9.0
15.0
ND
NI
NI
ND
1Oct-96
-
5
15.0
NI
-
---
24.0
10.0
7.0
6.0
NI
NI
ND
1-May-97
-
5
16.0
NI
-
---
23.0
10.0
22.0
16.0
NI
NI
ND
1-Nov-97
-
5
40.0
NI
-
---
27.0
14.0
30.0
24.0
NI
NI
ND
1-May-98
--
5
18.0
NI
-
---
9.0
ND
10.0
6.0
NI
NI
ND
1-Nov-98
---
5
7.0
NI
-
---
39.0
9.0
47.0
14.0
NI
NI
ND
11-May-99
---
10
14.0
18.0
-
--
ND
ND
ND
ND
ND
ND
ND
18-Oct-99
---
10
160
54.0
-
--
56.0
27.0
140
23.0
ND
ND
ND
3-May-00
---
10
ND
ND
-
---
ND
ND
ND
ND
11.0 1
ND
ND
7-Nov-00
---
10
ND
20.0
-
---
ND
ND
ND
ND
ND
ND
ND
31-May-01
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
7-Nov-01
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
22-May-02
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
14-Nov-02
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
14-May-03
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
20-Nov-03
---
10
ND
19.0
-
---
ND
ND
ND
20.0
ND
ND
ND
6-May-04
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
10-Nov-04
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
5-May-05
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
3-Nov-05
---
10
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
25-May-06
---
10
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
2-Nov-06
---
10
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
30-May-07
---
10
-
2.5 J
-
---
ND
ND
ND
2.3 1
ND
ND
ND
NC 21 15 pg/L (10/23/07)
29-Nov-07
---
10
-
7.5 J
-
--
ND
6.1
J ND
5.1 1
ND
ND
ND
29-May-08
4.0
10.0
-
ND
-
---
ND
ND
ND
6.8
ND
ND
ND
6-Nov-08
4.0
10.0
-
ND
-
---
ND
ND
ND
8.8 1
ND
ND
ND
3-Jun-09
4.0
10.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
18-Nov-09
4.0
10.0
-
ND
-
---
ND
ND
ND
5.5 1
ND
ND
ND
16-Jun-10
4.0
10.0
-
ND
-
---
4.4
J 13.9
ND
ND
ND
ND
ND
1-Dec-10
4.0
10.0
-
ND
16.8
---
ND
ND
ND
ND
ND
ND
ND
Resample>
13-Jan-11
4.0
10.0
-
ND
ND
---
--
-
-
-
-
-
ND
1-Jun-11
4.0
10.0
-
ND
5.9 1
---
ND
ND
ND
ND
ND
ND
ND
20-Dec-11
5.0
10.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
ND
30-May-12
5.0
10.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
ND
5-Dec-12
5.0
10.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
ND
12-Jun-13
5.0
10.0
-
-
ND
--
ND
5.5
1 ND
5.6 1
ND
ND
ND
28-Oct-13
5.0
10.0
-
-
ND
--
ND
5.2
1 ND
ND
ND
ND
ND
6-May-14
EPA 6010
5.0
10.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
ND
23-Oct-14
EPA 6010
5.0
10.0
-
-
*
ND
ND
ND
ND
ND
ND
ND
ND
20-May-15
EPA 6010
2.5
10.0
-
-
-
ND
4.9
1 4.3
J ND
ND
2.7 J
ND
ND
8-Dec-15
EPA 6010
2.5
10.0
-
-
-
ND
7.8
1 6.3
J 9.8
1 ND
ND
ND
ND
3-May-16
EPA 6010
2.5
10.0
-
-
-
ND
ND
6.8
J 5.3
J 3.3 J
3.8 J
ND
ND
13-Dec-16
EPA 6010
2.5
10.0
-
-
-
ND
ND
3.5
J 2.6
1 ND
ND
ND
ND
27-Jun-17
EPA 6010
2.5
10.0
-
-
-
ND
3.0
J 3.9
J 5.0
1 ND
ND
ND
-
13-Dec-17
EPA 6010
2.5
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
16-May-18
EPA 6010
2.5
10.0
-
-
-
ND
ND
6.6
J 2.9
J ND
ND
ND
ND
6-Dec-18
EPA 6010
2.5
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
8-May-19
EPA 6010D
2.5
5.0
-
-
ND
ND
ND
ND
ND
ND
ND
ND
ND
S-Nov-19
EPA 6010D
1.6
5.0
-
-
2.5 1
ND
3.4
1 3.0
J 4.1
J 2.2 J
ND
ND
ND
8-May-20
EPA 6010D
4.5
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
11-Nov-20
EPA 6010D
4.5
5.0
-
-
-
ND
ND
31.9
ND
ND
ND
-
ND
Resample>
28-Jan-21
EPA 6010D
4.5
5.0
-
-
-
-
-
ND
-
-
-
-
-
5-May-21
EPA 6010D
4.5
5.0
-
-
-
ND
ND
8.0
ND
6.7
ND
-
ND
3-Nov-21
EPA 6010D
4.5
5.0
-
-
-
ND
ND
ND
ND
8.4
ND
-
ND
19-May-22
EPA 6020B
0.9
1.0
-
-
-
ND
1.3
ND
ND
1.8
ND
-
---
17-Nov-22
EPA 6020B
0.1
1.0
-
-
2.5
1
ND
1.0
0.3
J 14.2
ND
-
---
6-Nov-23
EPA 6010D
1.4
5.0
-
-
-
ND
5.5
ND
ND
2.0 J
ND
-
---
Manganese
1-Jun-11
0.30
50.0
-
385
209
-
5,770
14,500
9,330
1,160
8,460
123
0.36J
Resample>
7-Jul-11
5.0
50.0
-
-
143
-
-
--
-
-
-
-
ND
NC 21 50 pg/L (01/01/10)
20-Dec-11
5.0
50.0
-
-
136
-
6,670
15,500
D 9,480
1,030
8,540
119
ND
30-May-12
5.0
50.0
-
-
104
-
6,700
14,300
9,370
1,170
8,790
119
ND
5-Dec-12
5.0
50.0
-
-
54.5
-
2,650
8,930
9,150
1,230
9,180
122
ND
12-Jun-13
5.0
50.0
-
-
49.3 1
-
16,800
15,400
11,700
2,060
8,150
130
ND
28-Oct-13
5.0
50.0
-
-
80.0
-
8,420
15,000
91910
2,500
9,680
124
ND
6-May-14
EPA 6010
50.0
50.0
-
-
83.5
-
12,300
18,300
9,950
1,600
9,720
119
ND
23-Oct-14
EPA 6010
50.0
50.0
-
-
*
73.6
9,400
23,200
11,000
1,740
11,500
115
ND
20-May-15
EPA 6010
2.5
50.0
-
-
-
27.4
9,070
29,800
10,800
2,010
12,400
121
ND
8-Dec-15
EPA 6010
12.5
50.0
-
-
-
50.0 1
15,000
18,100
10,800
1,500
8,440
124
ND
3-May-16
EPA 6010
2.5
50.0
-
-
-
142
7,850
17,500
9,140
1,810
6,600
119
ND
13-Dec-16
EPA 6010
2.5
50.0
-
-
-
48.1 1
5,100
17,900
8,850
1,560
10,900
122
ND
27-Jun-17
EPA 6010
2.5
50.0
-
-
-
60.3
8,910
19,900
10,200
1,750
11,000
131
--
13-Dec-17
EPA 6010
2.5
50.0
-
-
-
40.8 1
5,200
18,600
9,960
2,260
9,940
105
-
16-May-18
EPA 6010
2.5
50.0
-
-
-
25.8 J
4,780
19,400
9,940
2,090
91090
123
ND
6-Dec-18
EPA 6010
2.5
5.0
-
-
-
23.6
5,310
17,700
9,750
2,440
9,730
123
ND
Resample>
7-Feb-19
EPA 6010
2.5
5.0
-
-
61.6
-
-
-
-
-
-
-
ND
BKGD = 535 pg/L
8-May-19
EPA 6010D
2.5
5.0
-
-
68.6
73.7
4,070
17,200
9,210
2,170
11,900
112
ND
S-Nov-19
EPA 6010D
0.9
5.0
-
-
106
126
3,540
15,200
10,900
1,770
9,540
124
ND
8-May-20
EPA 6010D
3.4
5.0
-
-
-
84.2
3,520
16,400
10,500
2,710
9,680
134
ND
11-Nov-20
EPA 6010D
3.4
5.0
-
-
-
348
3,880
20,500
9,290
2,380
91690
-
ND
Resample>
28-Jan-21
EPA 6010D
3.4
5.0
-
-
-
34.1
-
21,000
-
-
-
-
-
5-May-21
EPA 6010D
3.4
5.0
-
-
-
26.2
3,020
20,700
D 12,200
D 2,700
9,130
-
ND
3-Nov-21
EPA 6010D
3.4
5.0
-
-
-
49
2,560
20,600
12,400
2,070
9,090
-
ND
19-May-22
EPA 6020B
57.4
500.0
-
-
-
70.4
2,950
22,800
11,300
2,110
12,800
-
-
17-Nov-22
EPA 6020B
1.1
10.0
-
-
78.8
102
2,710
21,600
12,200
2,650
13,200
-
--
6-Nov-23
EPA 6010D
0.9
5.0
-
-
-
45.4
3,190
25,700
14,000
1,930
13,700
-
--
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 6 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW-10
MW-11
MW-12
MW-13
MW46S
MW-16D
Blanks
Mercury
16- Aug -95
--
0.20
0.30 B
NI
-
-
0.30
B
0.30 B
0.20 B
0.30
B NI
NI
0.2
25-Jan-96
-
0.20
1.6
NI
-
-
0.40
0.70
ND
1.3
NI
NI
ND
28-Feb-96
-
0.20
ND
NI
-
-
2.4
ND
ND
0.20
NI
NI
ND
1-May-96
-
0.20
1.4
NI
-
-
1.7
1.5
2.1
2.3
NI
NI
ND
1-Oct-96
-
0.50
ND
NI
-
-
ND
ND
ND
ND
NI
NI
ND
1-May-97
-
-
-
NI
-
-
NS
NS
NS
NS
NI
NI
NS
1-Nov-97
-
0.20
ND
NI
-
-
0.80
ND
ND
ND
NI
NI
ND
1-May-98
-
0.20
ND
NI
-
-
0.80
ND
ND
0.40
NI
NI
ND
1-Nov-98
-
0.20
ND
NI
-
-
1.3
ND
ND
0.49
NI
NI
ND
11-May-99
-
0.20
-
ND
-
-
-
-
-
-
ND
ND
-
18-Oct-99
-
0.50
ND
ND
-
-
-
ND
ND
0.55
ND
ND
ND
3-May-00
-
0.50
-
-
-
-
-
-
-
-
-
-
-
7-Nov-00
-
0.50
ND
-
-
-
ND
ND
ND
ND
ND
-
ND
31-May-01
-
0.50
ND
-
-
-
0.70
ND
ND
0.90
ND
-
ND
7-Nov-01
-
0.50
ND
-
-
-
ND
ND
ND
1.0
ND
-
ND
22-May-02
-
0.50
ND
-
-
-
0.62
ND
ND
ND
ND
-
ND
14-Nov-02
-
0.50
ND
-
-
-
ND
ND
ND
ND
ND
-
ND
14-May-03
-
0.50
ND
-
-
-
ND
ND
ND
ND
ND
-
ND
20-Nov-03
-
0.50
ND
-
-
-
0.80
ND
ND
0.73
ND
-
ND
6-May-04
-
0.50
ND
-
-
-
0.71
ND
ND
0.52
ND
-
ND
10-Nov-04
-
0.50
ND
-
-
-
ND
ND
ND
0.74
ND
-
ND
5-May-05
-
0.50
ND
-
-
-
ND
ND
ND
ND
ND
-
ND
3-Nov-05
-
0.50
-
ND
-
-
1.0
ND
ND
ND
ND
-
ND
25-May-06
-
2.0
-
-
-
-
ND
ND
ND
ND
ND
-
ND
2-Nov-06
-
0.50
-
ND
-
-
ND
ND
ND
ND
ND
ND
ND
30-May-07
-
0.20
-
-
-
-
0.12
J
ND
ND
0.13
J ND
-
-
NC 2L = 1.05 pg/L (10/23/07)
29-Nov-07
-
0.20
-
ND
-
-
0.88
ND
ND
0.50
ND
ND
ND
29-May-08
0.090
0.20
-
-
-
-
0.12
B
ND
0.13 B
0.66
0.12 B
-
0.1 J
6-Nov-08
0.090
0.20
-
ND
-
-
ND
ND
ND
0.41
ND
ND
ND
3-Jun-09
0.070
0.20
-
ND
-
-
ND
ND
ND
0.14
J ND
-
ND
18-Nov-09
0.070
0.20
-
ND
-
-
ND
ND
ND
0.43
ND
ND
ND
NC 21- = 1 pg/L (01/01/10)
16-Jun-10
0.070
0.20
-
ND
-
-
0.17
J
ND
ND
0.077
J -
-
ND
1-Dec-10
0.070
0.20
-
0.089 J
ND
-
0.62
ND
ND
0.21
ND
ND
ND
1-Jun-11
0.10
0.20
-
ND
ND
-
0.19
J
ND
ND
0.19
J ND
-
ND
20-Dec-11
0.10
0.20
-
-
ND
-
0.14
J
ND
ND
0.15
J ND
ND
ND
30-May-12
0.10
0.10
-
-
ND
-
0.13
J
ND
ND
0.10
J ND
ND
ND
5-Dec-12
0.10
0.20
-
-
ND
-
0.11
J
ND
ND
0.27
ND
-
ND
12-Jun-13
0.10
0.20
-
-
ND
-
ND
ND
ND
0.56
ND
ND
ND
28-Oct-13
0.10
0.20
-
-
ND
-
0.15
1
ND
ND
0.11
J ND
ND
ND
6-May-14
EPA 7470
0.10
0.20
-
-
ND
-
0.15
J
ND
ND
ND
ND
ND
ND
23-Oct-14
EPA 7470
0.10
0.20
-
-
*
ND
ND
ND
ND
0.38
ND
ND
ND
20-May-15
EPA 7470
0.10
0.20
-
-
-
ND
0.13
J
ND
ND
0.45
ND
ND
ND
8-Dec-15
EPA 7470
0.10
0.20
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
3-May-16
EPA 7470
0.10
0.20
-
-
-
ND
0.33
ND
ND
0.40
ND
ND
ND
13-Dec-16
EPA 7470
0.10
0.20
-
-
-
ND
0.25
ND
ND
0.15
J ND
ND
ND
27-Jun-17
EPA 7470
0.10
0.20
-
-
-
ND
0.17
1
ND
ND
ND
ND
ND
-
13-Dec-17
EPA 7470
0.10
0.20
-
-
-
ND
ND
ND
ND
0.89
ND
ND
ND
16-May-18
EPA 7470
0.10
0.20
-
-
-
ND
ND
ND
ND
0.32
ND
ND
ND
6-Dec-18
EPA 7470
0.10
0.20
-
-
-
ND
0.15
1
ND
ND
0.63
ND
ND
ND
8-May-19
EPA 7470A
0.10
0.20
-
-
-
ND
0.18
JB
ND
0.10 JB
0.54
B ND
0.13 JB
0.11 J
8-Nov-19
EPA 7470A
0.10
0.20
-
-
0.13 1
ND
-
ND
ND
-
ND
0.15 J
ND
8-May-20
EPA 7470A
0.12
0.20
-
-
-
ND
1.7
ND
ND
0.23
ND
ND
ND
II-Nov-20
EPA 7470A
0.12
0.20
-
-
-
ND
ND
ND
ND
0.21
ND
-
ND
5-May-21
EPA 7470A
0.12
0.20
-
-
-
ND
0.19
J
ND
ND
1.4
ND
-
ND
3-Nov-21
EPA 7470A
0.12
0.20
-
-
-
ND
0.43
ND
0.42
3.3
ND
-
ND
19-May-22
EPA 7470A
0.13
0.20
-
-
-
ND
0.38
ND
ND
1.6
ND
-
-
17-Nov-22
EPA 7470A
0.12
0.20
-
-
ND
ND
0.23
ND
ND
13.1
ND
-
---
6-Nov-23
EPA 7470A
0.12
0.20
-
-
-
ND
1.8
ND
ND
3.1
ND
-
-
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 7 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-16D
Blanks
Nickel
15-Sep-94
-
50
ND
NI
NI
NI
ND
ND
100
ND
NI
NI
ND
1-Oct-94
-
50
-
NI
NI
NI
-
ND
-
-
NI
NI
ND
18-Jan-95
-
50
ND
NI
NI
NI
ND
ND
ND
ND
NI
NI
ND
6-Feb-95
-
50
ND
NI
NI
NI
ND
ND
71.0
ND
NI
NI
ND
1-Mar-95
-
50
ND
NI
NI
NI
ND
ND
ND
ND
NI
NI
ND
1-Aug-95
-
50
ND
NI
-
-
ND
ND
ND
ND
NI
NI
ND
1-Jan-96
-
50
ND
NI
-
-
ND
ND
ND
ND
NI
NI
ND
1-Feb-96
-
50
ND
NI
-
-
ND
ND
ND
ND
NI
NI
ND
1-May-96
-
50
ND
NI
-
--
ND
ND
ND
ND
NI
NI
ND
1Oct-96
-
50
ND
NI
-
--
ND
ND
ND
ND
NI
NI
ND
1-May-97
-
50
ND
NI
-
---
ND
ND
ND
ND
NI
NI
ND
1-Nov-97
-
50
ND
NI
-
---
ND
ND
80.0
ND
NI
NI
ND
1-May-98
-
50
ND
NI
-
---
ND
ND
90.0
ND
NI
NI
ND
1-Nov-98
-
50
ND
NI
-
---
ND
ND
74.0
ND
NI
NI
ND
11-May-99
-
5
21.0
33.0
-
--
16.0
11.0
63.0
14.0
53.0
ND
ND
18-Oct-99
-
50
180
67.0
-
--
55.0
ND
570
ND
ND
ND
ND
3-May-00
-
50
ND
ND
-
---
ND
ND
ND
ND
71.0
ND
ND
7-Nov-00
-
50
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
31-May-01
-
50
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
7-Nov-01
-
50
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
22-May-02
-
50
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
14-Nov-02
-
50
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
14-May-03
-
50
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
20-Nov-03
-
50
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
6-May-04
-
50
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
10-Nov-04
--
50
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
5-May-05
--
50
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
3-Nov-05
--
50
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
25-May-06
-
50
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
2-Nov-06
--
50
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
30-May-07
--
50
-
2.2
1 -
---
2.1
1 2.2
1 3.7
1 4.1
1 ND
ND
ND
NC 2L = 100 Ng/L (10/23/07)
29-Nov-07
---
50
-
3.9
1 -
--
ND
7.3
1 8.0
1 2.2
1 ND
ND
ND
29-May-08
1.7
50.0
-
3.6
1 -
---
3.1
1 5.6
1 3.0
1 4.3
1 2.5
J ND
ND
6-Nov-08
1.7
50.0
-
2.2
1 -
---
2.9
1 5.6
1 6.8
1 5.1
1 5.6
J ND
ND
3-Jun-09
1.7
50.0
-
3.1
B --
---
2.6
B 8.5
B ND
4.1
B 2.8
B 2.2 B
1.7 1
18-Nov-09
1.7
50.0
-
2.4
1 -
---
3.2
1 5.9
1 4.9
1 4.9
1 1.8
J ND
ND
16-Jun-10
1.7
50.0
-
1.7
1 -
---
4.5
J 13.1
J 8.2
1 3.4
1 1.7
J ND
ND
1-Dec-10
1.7
50.0
-
ND
19.0
1 ---
3.1
1 4.1
1 7.8
1 3.7
J ND
ND
ND
1-Jun-11
1.7
50.0
-
ND
4.7
B ---
2.2
B 3.5
B 2.2
B 3.0
B ND
ND
2.3 1
20-Dec-11
5.0
50.0
-
-
ND
---
ND
ND
ND
ND
ND
ND
ND
30-May-12
5.0
50.0
-
-
ND
---
ND
ND
ND
ND
5.2
J ND
ND
5-Dec-12
5.0
50.0
-
-
ND
---
ND
ND
6.7
1 ND
ND
ND
ND
12-Jun-13
5.0
50.0
-
-
ND
--
ND
ND
5.2
1 5.4
1 ND
ND
ND
28-Oct-13
5.0
50.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
ND
6-May-14
EPA 6010
5.0
50.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
ND
23-Oct-14
EPA 6010
5.0
50.0
-
-
*
ND
6.0
J ND
ND
ND
ND
ND
ND
20-May-15
EPA 6010
2.5
50.0
-
-
-
ND
5.3
J 4.6
J 3.1
J 4.4
J ND
ND
ND
8-Dec-15
EPA 6010
2.5
50.0
-
-
-
ND
5.5
1 3.4
J 17.7
J 4.2
J ND
ND
ND
3-May-16
EPA 6010
2.5
50.0
-
-
-
ND
4.5
1 5.0
J 21.6
J 5.6
J ND
ND
ND
13-Dec-16
EPA 6010
2.5
50.0
-
-
-
ND
3.9
1 3.8
J 29.7
J 3.8
J ND
ND
ND
27-Jun-17
EPA 6010
2.5
50.0
-
-
-
ND
4.7
1 4.1
1 29.0
J 4.5
J ND
ND
-
13-Dec-17
EPA 6010
2.5
50.0
-
-
-
ND
5.1
1 10.1
J 51.7
17.1
J 9.1
J 2.6 J
ND
16-May-18
EPA 6010
2.5
50.0
-
-
-
ND
4.2
J 4.8
J 6.0
J 4.6
J ND
ND
ND
6-Dec-18
EPA 6010
2.5
5.0
-
-
-
ND
4.4
1 5.1
5.6
4.7
J 3.8
J ND
ND
8-May-19
EPA 6010D
2.5
5.0
-
-
ND
ND
3.6
1 2.9
1 3.5
J 5.0
ND
ND
ND
8-Nov-19
EPA 6010D
0.9
5.0
-
-
3.0
1 1.1 1
2.5
1 3.9
J 5.2
3.9
J 2.3
J ND
ND
8-May-20
EPA 6010D
3.5
5.0
-
-
-
ND
ND
4.3
1 14.5
5.2
ND
ND
ND
II-Nov-20
EPA 6010D
3.5
5.0
-
-
-
ND
ND
19.7
25.2
4.5
J ND
-
ND
Resample>
28-Jan-21
EPA 6010D
3.5
5.0
-
-
-
-
-
5.8
-
-
-
-
-
5-May-21
EPA 6010D
3.5
5.0
-
-
-
ND
ND
30
ND
6.9
ND
-
ND
3-Nov-21
EPA 6010D
3.5
5.0
-
-
-
ND
ND
4.7
1 ND
5.3
ND
-
ND
19-May-22
EPA 6020B
0.7
5.0
-
-
-
1.7 1
3.1
J 3
J 3.3
J 4.3
J 1.9
1 -
-
17-Nov-22
EPA 6020B
0.7
5.0
-
-
2.2
1, 0.95 J
ND
3.9
14.0
7.3
2.4
-
--
6-Nov-23
EPA 6010D
0.9
5.0
-
-
-
ND
4.9
1 9.8
5.3
4.4
J 5.1
-
---
Selenium
29-May-08
3.8
10.0
-
ND
-
--
ND
6.1
J ND
ND
5.8
J ND
ND
6-Nov-08
3.8
10.0
-
ND
-
---
13.2
6.4
1 6.7
J ND
5.8
J ND
ND
3-Jun-09
3.8
10.0
-
ND
-
---
ND
5.4
J ND
ND
ND
ND
ND
18-Nov-09
3.8
10.0
-
ND
-
---
ND
4.3
1 4.7
1 4.4
1 5.0
J ND
ND
NC 2L = 20 pg/L (01/01/10)
16-1un-10
3.8
10.0
-
ND
-
--
3.8
J ND
6.9
J ND
ND
ND
ND
1-Dec-10
3.8
10.0
-
ND
ND
--
ND
ND
ND
ND
ND
ND
ND
1-Jun-11
3.8
10.0
-
ND
ND
-
ND
ND
ND
ND
ND
ND
ND
20-Dec-11
10.0
10.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
ND
30-May-12
10.0
10.0
-
-
ND
--
11.7
11.3
ND
ND
ND
ND
ND
5-Dec-12
10.0
10.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
ND
12-Jun-13
10.0
10.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
ND
28-Oct-13
10.0
10.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
ND
6-May-14
EPA 6010
10.0
10.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
ND
23-Oct-14
EPA 6010
10.0
10.0
-
-
*
ND
ND
ND
ND
ND
ND
ND
ND
20-May-15
EPA 6010
5.0
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
8-Dec-15
EPA 6010
5.0
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
3-May-16
EPA 6010
5.0
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
13-Dec-16
EPA 6010
5.0
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
27-Jun-17
EPA 6010
5.0
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
-
13-Dec-17
EPA 6010
5.0
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
16-May-18
EPA 6010
5.0
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
6-Dec-18
EPA 6010
5.0
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
8-May-19
EPA 6010D
5.0
10.0
-
-
ND
ND
ND
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA 6010D
4.7
10.0
-
-
ND
ND
ND
6.8
1 ND
ND
ND
ND
ND
8-May-20
EPA 6010D
4.7
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
11-Nov-20
EPA 6010D
4.7
10.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
Resample>
28-Jan-21
EPA 6010D
4.7
10.0
-
-
-
-
-
ND
-
-
-
-
-
5-May-21
EPA 6010D
4.7
10.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
5-May-21
EPA 6010D
4.7
10.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
EPA 6020B
1.4
5.0
-
-
-
ND
ND
ND
ND
ND
ND
-
-
17-Nov-22
EPA 6020B
0.1
2.0
-
-
0.085
J ND
ND
0.1
J ND
ND
ND
-
-
6-Nov-23
EPA 6010D
4.1
10.0
-
-
-
ND
ND
ND
ND
ND
ND
-
-
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 8 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Analy[e
Sample
Collection Date
EPA
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-16D
Blanks
Silver
6-Feb-95
---
10
ND
NI
NI
NI
11.0
ND
11.0
ND
NI
NI
ND
1-Mar-95
--
10
ND
NI
NI
NI
ND
ND
ND
ND
NI
NI
ND
1-Aug-95
-
1
ND
NI
-
---
ND
ND
ND
ND
NI
NI
ND
1-Jan-96
-
1
ND
NI
-
---
ND
ND
ND
ND
NI
NI
ND
1-Feb-96
-
1
ND
NI
-
---
ND
ND
ND
ND
NI
NI
ND
1-May-96
-
1
ND
NI
--
---
ND
ND
ND
ND
NI
NI
ND
1-0ct-96
-
1
ND
NI
---
ND
ND
ND
ND
NI
NI
ND
1-May-97
-
5
ND
NI
---
---
6.0
ND
ND
ND
NI
NI
ND
1-Nov-97
-
1
ND
NI
-
---
ND
ND
ND
ND
NI
NI
ND
1-May-98
-
1
ND
NI
-
---
ND
ND
ND
ND
NI
NI
ND
1-Nov-98
-
1
ND
NI
-
---
ND
ND
ND
ND
NI
NI
ND
11-May-99
--
2
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
18-Oct-99
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
3-May-00
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
7-Nov-00
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
31-May-01
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
7-Nov-01
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
22-May-02
---
10
15.0 B
15.0
B -
--
14.0
B
15.0
B 14.0
B 12.0
B 16.0
B 16.0 B
15.0
14-Nov-02
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
14-May-03
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
20-Nov-03
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
6-May-04
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
10-Nov-04
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
5-May-05
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
3-Nov-05
---
10
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
25-May-06
---
10
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
2-Nov-06
---
10
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
30-May-07
---
10
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
INC 21 17.5 pg/L (10/23/07)
29-Nov-07
-
10
-
ND
-
--
ND
ND
ND
ND
ND
ND
ND
29-May-08
0.10
10.0
-
0.14
J -
--
0.59
1
1.1
1 0.45
J ND
0.57
J ND
ND
6-Nov-08
0.10
10.0
-
0.25
B -
--
1.1
B
2.1
1 1.3
J 0.26
B 1.1
B 0.22 B
0.23 1
3-Jun-09
0.10
10.0
-
0.68
B -
--
1.0
B
1.4
B 0.73
B 0.13
B 0.76
B 1.0 B
0.31 1
18-Nov-09
0.10
10.0
-
0.28
B -
--
0.72
B
1.0
B 0.61
B 0.19
B 0.57
B 0.19 B
0.23 1
INC 21 20 pg/L (01/01/10)
16-Jun-10
0.10
10.0
-
ND
-
--
ND
ND
ND
ND
ND
ND
ND
1-Dec-10
0.10
10.0
-
ND
ND
---
ND
0.24
J ND
ND
ND
ND
ND
1-Jun-11
0.10
10.0
-
0.39
B 0.16 B
-
0.22
B
0.60
B 0.32
B 0.29
B 0.22
B 0.23 B
0.17 J
20-Dec-11
5.0
10.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
ND
30-May-12
5.0
10.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
ND
5-Dec-12
5.0
10.0
-
-
ND
---
ND
ND
ND
ND
ND
ND
ND
12-Jun-13
5.0
10.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
ND
28-Oct-13
5.0
10.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
ND
6-May-14
EPA 6010
5.0
10.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
ND
23-Oct-14
EPA 6010
5.0
10.0
-
-
*
ND
ND
ND
ND
ND
ND
ND
ND
20-May-15
EPA 6010
2.5
10.0
-
-
-
ND
ND
3.6
J ND
ND
ND
ND
ND
8-Dec-15
EPA 6010
2.5
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
3-May-16
EPA 6010
2.5
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
13-Dec-16
EPA 6010
2.5
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
27-Jun-17
EPA 6010
2.5
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
-
13-Dec-17
EPA 6010
2.5
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
16-May-18
EPA 6010
2.5
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
6-Dec-18
EPA 6010
2.5
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
8-May-19
EPA 6010D
2.5
5.0
-
-
ND
ND
ND
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA 6010D
2.5
5.0
-
-
ND
ND
ND
ND
ND
ND
ND
ND
ND
8-May-20
EPA 6010D
2.5
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
II-Nov-20
EPA 6010D
2.5
5.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
Resample>
28-Jan-21
EPA 6010D
2.5
5.0
-
-
-
-
-
ND
-
-
-
-
-
5-May-21
EPA 6010D
2.5
5.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
EPA 6010D
2.5
5.0
-
-
-
ND
ND
10.1
4.5
J ND
3.1
J -
ND
19-May-22
EPA 6020B
0.4
5.0
-
-
-
ND
ND
ND
ND
ND
ND
-
---
17-Nov-22
EPA 6020B
0.4
5.0
-
-
ND
ND
ND
ND
ND
ND
ND
-
---
6-Nov-23
EPA 6010D
0.5
5.0
-
-
-
ND
ND
0.6
1 ND
ND
ND
-
--
Sulfide
1-Aug-95
--
100
900
NI
-
--
ND
600
ND
100
NI
NI
ND
1-Jan-96
---
100
ND
NI
-
---
ND
300
ND
ND
NI
NI
ND
1-Feb-96
---
100
ND
NI
-
---
ND
100
ND
ND
NI
NI
ND
1-May-96
--
100
200
NI
-
---
ND
900
700
300
NI
NI
ND
1-0ct-96
-
100
2,800
NI
-
---
ND
200
3,000
7,500
NI
NI
ND
1-May-97
-
50
ND
NI
-
---
ND
ND
ND
ND
NI
NI
ND
1-Nov-97
-
50
ND
NI
-
---
ND
ND
ND
ND
NI
NI
ND
1-May-98
-
50
50
NI
-
---
ND
ND
ND
ND
NI
NI
ND
1-Nov-98
-
50
ND
NI
-
---
130
ND
80.0
110
NI
NI
ND
11-May-99
-
50
ND
ND
-
---
ND
ND
ND
ND
-
ND
ND
18-Oct-99
-
1,000
ND
ND
-
---
-
ND
ND
ND
ND
ND
ND
7-Nov-00
-
1,000
ND
-
-
---
ND
ND
ND
ND
ND
-
ND
31-May-01
-
1,000
ND
-
-
---
ND
ND
ND
ND
ND
-
ND
7-Nov-01
-
1,000
ND
-
-
---
ND
ND
ND
ND
ND
-
ND
14-Nov-02
-
1,000
ND
-
-
---
ND
ND
ND
ND
ND
-
ND
20-Nov-03
-
1,000
ND
-
-
---
ND
ND
ND
ND
ND
-
ND
10-Nov-04
--
1,000
ND
-
-
---
ND
ND
ND
ND
ND
-
6
3-Nov-05
--
-
-
ND
-
---
ND
ND
1,800
ND
ND
--
ND
2-Nov-06
--
1,000
-
ND
-
---
ND
ND
ND
ND
ND
--
ND
INC 21 NE (10/23/07)
29-Nov-07
-
1,000
-
ND
-
--
ND
ND
ND
ND
ND
---
ND
6-Nov-08
100
1,000
-
ND
-
---
ND
ND
ND
ND
ND
-
ND
3-Jun-09
100
1,000
-
ND
-
---
-
ND
ND
-
ND
--
ND
16-Nov-09
100
1,000
-
ND
-
-
ND
ND
ND
ND
ND
--
ND
16-Jun-10
100
1,000
-
ND
-
-
-
ND
ND
-
ND
-
ND
1-Dec-10
100
1,000
-
ND
ND
--
ND
ND
ND
ND
ND
-
ND
5-Dec-12
100
1,000
-
-
ND
---
ND
ND
ND
ND
ND
-
ND
12-Jun-13
100
1,000
-
-
ND
--
ND
ND
ND
ND
ND
-
ND
28-Oct-13
100
1,000
-
-
ND
-
ND
ND
ND
ND
ND
ND
ND
23-Oct-14
SM 4500-S2D
100
1,000
-
-
*
ND
-
-
-
-
-
-
ND
8-Dec-15
SM 4500-S21)
100
1,000
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-May-16
SM 4500-S21)
100
1,000
-
-
-
ND
-
-
-
-
-
-
ND
13-Dec-16
SM 4500-S2D
100
1,000
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
27-Jun-17
SM 4500-S2D
100
1,000
-
-
-
ND
-
-
-
-
-
-
-
13-Dec-17
SM 4500-S2D
100
1,000
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
16-May-18
SM 4500-S2D
100
1,000
-
-
-
ND
-
-
-
-
-
-
ND
6-Dec-18
SM 4500-S21)
50
100
-
-
-
ND
ND
ND
ND
91.2
J 89.3
J ND
ND
8-May-19
SM 4500-S2D-2011
50
100
-
-
-
ND
-
ND
ND
-
85.0
1 -
--
S-Nov-19
SM 4500-S2D-2011
50
100
-
-
-
ND
ND
ND
ND
ND
69.6
1 -
--
11-Nov-20
SM 4500-S2D-2011
50
100
-
-
-
ND
ND
ND
88.5
1 ND
78.3
1 -
-
5-May-21
SM 4500-S2D-2012
-
-
-
-
-
-
-
-
-
-
-
-
ND
3-Nov-21
SIM 4500S2D-201
50
100
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
16-May-22
SIM 4500S2D-201
50
100
-
-
-
ND
-
ND
ND
-
ND
-
-
17-Nov-22
SIM 4500S2D-201
22
100
-
-
-
ND
28.2
I,H'
ND
ND
ND
ND
-
--
6-Nov-23
SIM 4500-S2D-201
22
100
-
-
-
ND
23.4
1
ND
41.1
1 ND
ND
-
-
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 9 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Analy[e
Sample
Collection Date
EPA
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-16D
Blanks
Thallium
1-Nov-97
--
1
2.0 B
NI
---
---
2.0
B 2.0
B 3.0
B 1.0
B NI
NI
2.0
1-May-98
-
1
ND
NI
---
---
ND
ND
ND
1.0
NI
NI
ND
1-Nov-98
-
1
ND
NI
---
---
ND
ND
ND
1.0
NI
NI
ND
11-May-99
-
2
2.0
3.0
---
---
4.0
3.0
4.0
ND
3
2.0
ND
18-Oct-99
--
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
3-May-00
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
7-Nov-00
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
31-May-01
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
7-Nov-01
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
22-May-02
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
14-Nov-02
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
14-May-03
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
20-Nov-03
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
6-May-04
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
10-Nov-04
---
10
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
5-May-05
---
10
16.0
ND
-
---
41.0
23.0
25.0
14.0
26.0
ND
ND
3-Nov-05
---
10
-
ND
-
---
19.0
17.0
15.0
ND
13.0
ND
ND
25-May-06
---
10
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
2-Nov-06
---
10
-
ND
-
--
ND
ND
ND
ND
ND
ND
ND
30-May-07
--
5.5
-
ND
-
-
0.169
J 0.29
J 0.221
J 0.131
J 0.078
J ND
ND
GWPS = 0.28 pg/L (10/23/07)
29-Nov-07
--
5.5
-
0.042 J
-
-
0.118
1 0.321
1 0.199
1 0.150
1 0.065
J ND
ND
29-May-08
3.0
5.5
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
6-Nov-08
3.0
5.5
-
ND
-
---
8.9
ND
ND
ND
ND
ND
ND
3-Jun-09
3.0
5.5
-
ND
-
---
ND
ND
ND
ND
ND
14.8
ND
16-Nov-09
3.0
5.5
-
ND
-
---
ND
ND
ND
ND
ND
ND
4.2 1
16-Jun-10
3.0
5.5
-
ND
-
---
5.3
1 7.7
4.1
1 ND
4.0
1 ND
ND
Resample>
5-Aug-10
3.0
5.5
-
-
-
---
-
20.4
-
-
-
-
3.2 1
1-Dec-10
3.0
5.5
-
3.3 B
ND
--
3.3
B 9.1
B 5.1
B ND
7.8
B ND
3.1 1
1-Jun-11
3.0
5.5
-
ND
ND
--
ND
ND
ND
ND
ND
ND
ND
20-Dec-11
5.4
5.5
-
-
ND
--
ND
ND
ND
ND
ND
ND
ND
30-May-12
5.4
5.5
-
-
ND
--
ND
ND
ND
ND
ND
ND
ND
5-Dec-12
5.4
5.5
-
-
ND
--
ND
ND
ND
ND
ND
ND
6.8
12-Jun-13
5.4
5.5
-
-
ND
--
ND
ND
ND
ND
ND
ND
ND
28-Oct-13
5.4
5.5
-
-
ND
--
ND
ND
ND
ND
ND
ND
ND
6-May-14
EPA 6010
5.4
5.5
-
-
ND
-
ND
ND
ND
ND
ND
ND
ND
23-Oct-14
EPA 6010
5.4
5.5
-
-
*
ND
ND
ND
ND
ND
ND
ND
ND
20-May-15
EPA 6010
5.0
5.5
-
-
-
ND
ND
6.4
ND
ND
ND
ND
ND
S-Dec-15
EPA 6010
5.0
5.5
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
3-May-16
EPA 6010
5.0
5.5
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
13-Dec-16
EPA 6010
5.0
5.5
-
-
-
ND
5.3
1 5.1
1 ND
ND
ND
ND
ND
27-Jun-17
EPA 6020B
0.020
5.5
-
-
-
ND
0.24
J 0.36
J 0.094
J 0.097
J ND
ND
-
13-Dec-17
EPA 6020B
0.028
5.5
-
-
-
ND
0.73
J 0.60
J 0.03
J 0.18
J ND
ND
ND
IMAC=0.2 pg/L
16-May-18
EPA 6020
0.500
5.5
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
6-Dec-18
EPA 6020
0.060
0.1
-
-
-
ND
0.53
0.47
ND
0.15
ND
ND
ND
Resample>
7-Feb-19
EPA 6020
0.060
0.1
-
-
-
-
0.11
0.40
-
-
-
-
ND
8-May-19
EPA 6020E
0.060
0.1
-
-
0.12
ND
0.70
0.48
ND
0.14
ND
ND
ND
S-Nov-19
EPA 6020B
0.060
0.1
-
-
0.15
ND
UO
0.49
0.069
1 0.14
ND
ND
ND
8-May-20
EPA 6020E
0.050
0.1
-
-
-
ND
0.68
0.79
ND
0.12
ND
ND
ND
11-Nov-20
EPA 6020E
0.050
0.1
-
-
-
ND
0.32
2.80
0.087
1 0.14
ND
-
ND
Resample>
28-Jan-21
EPA 6010D
0.050
0.1
-
-
-
-
-
0.83
-
-
-
-
-
5-May-21
EPA 6020B
0.05
1
-
-
-
ND
0.53
1 0.9
J ND
0.21
J ND
-
ND
3-Nov-21
EPA 6020B
0.05
0.47
-
-
-
ND
0.52
0.66
ND
0.25
J ND
-
ND
Resample>
17-Feb-22
EPA 6020B
0.05
0.47
-
-
-
-
-
ND
-
-
-
-
-
NC2L=2
19-May-22
EPA 6020B
0.18
1
-
-
-
ND
0.45
J 0.7
J ND
0.19
J ND
-
---
17-Nov-22
EPA 6020B
0.05
0.47
-
-
0.16 J
0.19 J
0.7
0.50
ND
0.4
J ND
-
---
6-Nov-23
EPA 6020B
0.05
0.2
-
-
-
ND
0.5
0.52
ND
0.2
J ND
-
---
Tin
6-Nov-08
1.8
100
-
ND
-
--
2.3
1 3.8
1 2.1
1 ND
2.9
1 -
ND
GWPS = 0.28 pg/L (10/23/07)
3-Jun-09
--
-
-
-
-
---
-
-
-
-
-
-
-
16-Nov-09
1.8
100
-
ND
-
--
ND
ND
ND
ND
ND
ND
ND
GWPS =2,100 pg/L (01/01/10)
16-1un-10
1.8
100
-
ND
-
---
ND
ND
ND
ND
-
-
ND
GWPS =2,000 pg/L (10/1/10)
1-Dec-10
1.8
100
-
ND
ND
---
ND
ND
ND
ND
ND
-
ND
1-Jun-11
1.8
100
-
ND
ND
---
ND
ND
ND
ND
ND
ND
ND
20-Dec-11
5.0
100
--
-
ND
--
ND
ND
ND
ND
ND
ND
ND
30-May-12
5.0
100
--
-
ND
--
ND
ND
ND
ND
ND
ND
ND
5-Dec-12
5.0
100
-
-
ND
---
ND
ND
ND
ND
ND
-
ND
12-Jun-13
5.0
100
-
-
ND
---
ND
ND
ND
ND
ND
ND
ND
28-Oct-13
5.0
100
-
-
ND
---
ND
5.1
1 ND
ND
ND
-
ND
6-May-14
EPA 6010
5.0
100
-
-
ND
-
ND
ND
ND
ND
ND
-
ND
23-Oct-14
EPA 6010
5.0
100
-
-
*
ND
ND
ND
ND
ND
ND
-
ND
20-May-15
EPA 6010
2.5
100
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
S-Dec-15
EPA 6010
2.5
100
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-May-16
EPA 6010
2.5
100
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
13-Dec-16
EPA 6010
2.5
100
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
27-Jun-17
EPA 6010
2.5
5
-
-
-
ND
ND
ND
ND
ND
ND
-
-
13-Dec-17
EPA 6010
2.5
5
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
IMAC=2,000 pg/L
16-May-18
EPA 6010
2.5
100
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
6-Dec-18
EPA 6010
2.5
5
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
8-May-19
EPA 6010D
2.5
5
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
S-Nov-19
EPA 6010D
1.6
5
--
-
ND
ND
ND
ND
ND
ND
ND
-
-
8-May-20
EPA 6010D
4.7
5
---
-
-
ND
ND
ND
ND
ND
ND
-
-
11-Nov-20
EPA 6010D
4.7
5
---
-
-
ND
ND
ND
ND
ND
ND
-
-
5-May-21
EPA 6010D
4.7
5
---
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
EPA 6010D
4.7
5
---
-
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
EPA 6020E
1.5
20
--
-
-
ND
ND
ND
ND
ND
2.8
J -
-
17-Nov-22
EPA 6020E
1.5
20
--
-
2.2 1
ND
ND
ND
ND
ND
ND
-
-
6-Nov-23
EPA 6010D
2.0
5
---
-
-
ND
ND
ND
ND
ND
ND
-
-
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 10 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Analy[e
Sample
Collection Date
EPA
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-16D
Blanks
Vanadium
1-May-97
---
5
12.0
NI
---
---
5.0
ND
66.0
9.0
NI
NI
ND
1-Nov-97
--
40
ND
NI
---
---
ND
ND
180
ND
NI
NI
ND
1-May-98
-
5
14.0
NI
---
---
6.0
7.0
159
22.0
NI
NI
ND
1-Nov-98
--
5
15.0
NI
--
---
12.0
8.0
110
14.0
NI
NI
ND
II-May-99
---
5
55.0
58.0
-
--
25.0
16.0
72.0
31.0
71.0
100
ND
18-Oct-99
---
40
630
150
-
--
150
79.0
690
62.0
ND
ND
ND
3-May-00
---
40
ND
ND
-
---
ND
ND
ND
ND
140
ND
ND
7-Nov-00
---
40
ND
66.0
-
---
ND
ND
ND
ND
ND
ND
ND
31-May-01
---
40
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
7-Nov-01
---
40
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
22-May-02
---
40
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
14-Nov-02
---
40
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
14-May-03
---
40
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
20-Nov-03
---
40
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
6-May-04
---
40
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
10-Nov-04
---
40
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
5-May-05
---
40
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
3-Nov-05
---
40
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
25-May-06
---
40
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
2-Nov-06
---
40
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
30-May-07
--
25
-
ND
-
---
ND
ND
ND
ND
ND
ND
1.3 1
GWPS = 3.5 pg/L (10/23/07)
29-Nov-07
-
25
-
7.3
1 -
--
ND
ND
ND
ND
ND
ND
ND
29-May-08
0.2
25.0
-
0.43
J -
--
ND
2.4
1 1.3
1 3.7
1 ND
ND
ND
6-Nov-08
0.2
25.0
-
3.0
B -
--
2.2
B 0.53
B 5.5
B 11.1
1 6.2
B 1.4 B
2.1 1
3-Jun-09
0.2
25.0
-
0.94
B -
---
0.47
B 0.91
B 0.66
B 5.2
1 1.8
B 2.7 B
1.0 1
18-Nov-09
0.20
25.0
-
0.82
B -
--
0.43
B 0.66
B 4.1
1 5.4
1 1.3
B 0.29 B
0.56 1
16-Jun-10
0.20
25.0
-
1.1
B -
--
4.5
B 28.5
8.3
1 2.0
B 1.3
B 0.66 B
0.98 1
Resample>
5-Aug-10
0.20
25.0
-
-
-
---
--
1.5
B -
-
-
-
0.62 J
GWPS = 0.3 pg/L (10/1/10)
1-Dec-10
0.20
25.0
-
0.48
J 55.2
---
3.2
J 0.63
J 5.7
J 0.33
J 2.9
1 2.4 1
ND
Resample>
13-Jan-11
0.20
25.0
-
-
0.55
B -
-
-
-
-
-
-
0.33 J
1-Jun-11
0.20
25.0
-
0.69
J 17.2
J -
0.34
1 1.5
1 0.32
J 0.37
J ND
5.5 1
ND
20-Dec-11
5.0
25.0
-
-
10.7
J --
ND
ND
ND
ND
ND
ND
ND
30-May-12
5.0
25.0
-
-
9.2
1 ---
ND
ND
ND
ND
7.9
1 ND
ND
5-Dec-12
5.0
25.0
-
-
ND
--
ND
ND
6.1
1 ND
ND
ND
ND
12-Jun-13
5.0
25.0
-
-
ND
-
ND
ND
ND
5.6
1 ND
ND
ND
28-Oct-13
5.0
25.0
-
-
ND
-
ND
8.3
1 ND
ND
ND
ND
ND
6-May-14
EPA 6010
5.0
25.0
-
-
6.7
1 -
ND
ND
ND
ND
ND
ND
ND
22-Oct-14
EPA 6010
5.0
25.0
-
-
*
9.6 J
ND
ND
ND
ND
ND
ND
ND
20-May-15
EPA 6010
2.5
25.0
-
-
-
ND
9.1
1 20.1
J 10.7
J 2.6
J 11.3
J ND
ND
8-Dec-15
EPA 6010
2.5
25.0
-
-
-
6.6 1
20.4
1 23.5
J 36.9
3.0
1 11.5
1 ND
ND
Lab Re -run analyses>
8-Dec-15
EPA 6010
2.5
25.0
-
-
-
-
-
-
19.8
1 -
-
-
-
3-May-16
EPA 6010
2.5
25.0
-
-
-
29.7
ND
ND
ND
5.7
1 ND
ND
ND
13-Dec-16
EPA 6010
2.5
25.0
-
-
-
6.8 1
ND
ND
ND
ND
ND
ND
ND
27-Jun-17
EPA 6010
2.5
25.0
-
-
-
9.4 1
10.6
1 20.6
J 15.8
J ND
12.5
J ND
-
13-Dec-17
EPA 6010
2.5
25.0
-
-
-
4.2 1
ND
4.5
J 3.5
J 3.4
J ND
ND
ND
IMAC=0.3 pg/L
16-May-18
EPA 6010
2.5
25.0
-
-
-
ND
ND
5.5
J ND
ND
ND
ND
ND
6-Dec-18
EPA 6010
2.5
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
Resample>
7-Feb-19
EPA 6010
2.5
5.0
-
-
5.1
-
-
-
-
-
-
-
ND
BKGD=45.2 pg/L
8-May-19
EPA 6010D
2.5
5.0
-
-
4.2
J 10.4
ND
ND
ND
3.1
J ND
ND
ND
8-Nov-19
EPA 6010D
1.3
5.0
-
-
8.9
17.5
ND
2.9
J 6.8
ND
3.3
J ND
-
8-May-20
EPA 6010D
3.9
5.0
-
-
-
10.3
ND
ND
ND
ND
ND
ND
ND
II-Nov-20
EPA 6010D
3.9
5.0
-
-
-
63.0
9.6
101
28.0
6.8
21.6
-
ND
Resample>
28-Jan-21
EPA 6010D
3.9
5.0
-
-
-
ND
-
ND
-
-
-
-
-
5-May-21
EPA 6010D
3.9
5.0
-
-
-
ND
ND
17.2
6
9.6
5.9
-
ND
3-Nov-21
EPA 6010D
3.9
5.0
-
-
-
ND
15.1
125
64.7
ND
52.9
-
ND
Resample>
17-Feb-22
EPA 6010D
3.9
5.0
-
-
-
-
-
ND
-
-
-
-
-
19-May-22
EPA 6020B
1.9
10.0
-
-
-
3.3 J
ND
ND
ND
ND
ND
-
--
17-Nov-22
EPA 6020B
1.9
10.0
-
-
4.9
J 2.6 J
ND
2.80
1.5
12.0
0.6
J -
---
6-Nov-23
EPA 6010D
1.6
5.0
-
-
-
3.3 1
6.1
ND
ND
2.4
J ND
-
---
Zinc
15Sep-94
---
10
36.0
NI
NI
NI
ND
27.0
ND
ND
NI
NI
ND
1Oct-94
---
10
-
NI
NI
NI
-
52.0
-
-
NI
NI
ND
18-Jan-95
---
10
21.0
NI
NI
NI
ND
27.0
21.0
ND
NI
NI
ND
6-Feb-95
---
10
21.0
NI
NI
NI
ND
18.0
37.0
14.0
NI
NI
ND
1-Mar-95
---
10
27.0
NI
NI
NI
14.0
24.0
29.0
29.0
NI
NI
ND
1-Aug-95
---
10
ND
NI
-
-
ND
29.0
23.0
27.0
NI
NI
ND
1-Jan-96
-
10
28.0
NI
-
---
22.0
37.0
49.0
21.0
NI
NI
ND
1-Feb-96
-
10
48.0
NI
-
--
27.0
24.0
31.0
26.0
NI
NI
ND
1-May-96
-
10
46.0
NI
-
-
46.0
48.0
56.0
55.0
NI
NI
ND
1-0ct-96
---
10
23.0
NI
-
--
16.0
30.0
20.0
16.0
NI
NI
ND
1-May-97
---
10
50.0
NI
-
---
50.0
50.0
80.0
50.0
NI
NI
ND
1-Nov-97
---
10
60.0
NI
-
---
20.0
30.0
80.0
ND
NI
NI
ND
1-May-98
---
10
40.0
NI
-
---
30.0
40.0
110
30.0
NI
NI
ND
1-Nov-98
---
10
29.0
NI
-
---
24.0
23.0
150
ND
NI
NI
ND
11-May-99
---
20
64.0
43.0
-
--
150
28.0
68.0
61.0
69.0
210
ND
18-Oct-99
---
50
570
89.0
-
---
160
140
700
75.0
J ND
99.0
ND
3-May-00
---
50
ND
ND
-
---
ND
ND
ND
62.0
1 160
63.0 J
ND
7-Nov-00
---
50
130
150
-
--
ND
110
60.0
70.0
ND
ND
ND
31-May-01
---
50
ND
ND
-
---
ND
ND
79.0
ND
ND
ND
ND
7-Nov-01
---
50
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
22-May-02
---
50
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
14-Nov-02
---
50
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
14-May-03
---
50
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
20-Nov-03
---
50
ND
100
-
---
50.0
ND
ND
ND
ND
ND
ND
6-May-04
---
50
ND
ND
-
---
78.0
ND
ND
ND
ND
ND
ND
10-Nov-04
---
50
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
5-May-05
---
50
ND
ND
-
---
ND
ND
ND
ND
ND
ND
ND
3-Nov-05
---
50
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
25-May-06
---
50
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
2-Nov-06
---
50
-
ND
-
---
ND
ND
ND
ND
ND
ND
ND
30-May-07
---
10
-
5.9
B -
---
7.6
B 11.4
19.3
14.0
46.5
1.3
1.6 1
NC 2L = 1,050 pg/L (10/23/07)
29-Nov-07
--
10
-
20.4
-
--
10.9
B 62.0
30.2
16.4
44.5
35.6
3.1 1
29-May-08
0.40
10.0
-
2.9
B -
--
20.4
44.3
27.9
25.7
35.2
25.0
3.0 1
6-Nov-08
0.40
10.0
-
12.1
B -
--
10.2
B 16.6
18.6
27.1
76.7
30.9
2.7 1
3-Jun-09
0.40
10.0
-
3.9
B -
---
4.6
B 40.5
B 7.0
B 20.0
B 19.2
B 6.6 B
82.0
16-Nov-09
0.40
10.0
-
4.2
B -
-
7.2
B 21.4
18.6
22.1
13.6
B 2.5 B
3.1 1
NC 2L = 1,000 pg/L (01/01/10)
16-1un-10
0.40
10.0
-
ND
-
-
6.0
1 56.2
20.5
10.1
24.0
ND
ND
1-Dec-10
0.40
10.0
-
6.5
J 76.5
-
14.1
33.4
25.6
16.2
119
5.4 1
0.62 J
1-Jun-11
0.40
10.0
-
8.3
B 31.6
B --
14.3
B 40.8
B 27.2
B 20.1
B 24.9
B 44.7 B
13.7
20-Dec-11
10.0
10.0
-
-
19.6
-
13.3
40.8
20.2
17.6
30.5
15.8
ND
30-May-12
10.0
10.0
-
-
11.5
-
ND
39.2
16.6
13.3
48.8
ND
ND
5-Dec-12
10.0
10.0
-
-
ND
--
12.1
17.8
24.4
17.8
ND
11.2
ND
12-Jun-13
10.0
10.0
-
-
31.4
--
ND
38.9
B ND
23.7
B ND
32.2 B
76.5
28-Oct-13
10.0
10.0
-
-
15.9
-
ND
68.9
14.3
22.0
18.2
ND
ND
6-May-14
EPA 6010
10.0
10.0
-
-
13.7
-
ND
23.4
12.2
17.2
11.7
ND
ND
23-Oct-14
EPA 6010
10.0
10.0
-
-
*
ND
ND
17.8
11.2
18.5
32.2
13.9
ND
20-May-15
EPA 6010
5.0
10.0
-
-
-
26.4
9.6
J 24.2
15.6
19.8
20.4
ND
ND
8-Dec-15
EPA 6010
5.0
10.0
-
-
-
ND
9.0
1 20.0
65.1
19.0
47.3
8.2 J
ND
3-May-16
EPA 6010
5.0
10.0
-
-
-
10.5 B
7.5
B 35.3
B 8.4
B 23.2
B 20.7
B 9.3 B
7.4 1
13-Dec-16
EPA 6010
5.0
10.0
-
-
-
ND
12.8
17.6
9.7
J 15.7
51
6.8 J
ND
27-Jun-17
EPA 6010
5.0
10.0
-
-
-
8.2 1
10.0
1 19.6
11.7
21.9
35.8
9.8 J
-
13-Dec-17
EPA 6010
5.0
10.0
-
-
-
ND
5.7
1 13.9
ND
15.8
8.6
J ND
ND
16-May-18
EPA 6010
5.0
10.0
-
-
-
5.2 1
9.6
J 31.8
ND
14.2
16.7
22.8
ND
6-Dec-18
EPA 6010
5.0
10.0
-
-
-
ND
11.6
21.7
5.6
J 20.4
6.4
J 6.1 J
ND
8-May-19
EPA 6010D
5.0
10.0
-
-
10.3
18.1
6.9
J ND
ND
16.7
ND
ND
ND
8-Nov-19
EPA 6010D
3.9
10.0
-
-
14.6
6.7 J
8.8
J 11.8
9.8
J 17.7
14.6
ND
ND
8-May-20
EPA 6010D
9.5
10.0
-
-
-
ND
ND
14.4
ND
16.1
ND
27.2
ND
11-Nov-20
EPA 6010D
9.5
10.0
-
-
-
17.2
ND
375
11.3
16.1
32.1
-
ND
Resample>
28-Jan-21
EPA 6010D
9.5
10.0
-
-
-
-
-
ND
-
-
-
-
-
5-May-21
EPA 6010D
9.5
10.0
-
-
-
ND
ND
63.4
ND
24.2
ND
-
ND
3-Nov-21
EPA 6010D
9.5
10.0
-
-
-
12.4
17.1
16.9
ND
19.4
17.5
-
ND
19-May-22
EPA 6020B
7.0
10.0
-
-
-
ND
14.0
ND
ND
16.0
13.2
-
-
17-Nov-22
EPA 6020B
2.7
10.0
-
-
12.6
ND
ND
28.4
4.3
J 34.6
5.6
J -
-
6-Nov-23
EPA 6010D
3.0
10.0
-
--
-
ND
25.8
13.0
ND
18.4
4.0
J -
-
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 11 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Sample
EPA
Analyte
Collection Date
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-16D
Blanks
Organic Compounds
Alkalinity, Total as CaCO3
1-Jun-11
5,000
5,000
--
45,100
-
-
-
177,000
70,700
-
109,000
--
NO
NC 21 NE (01/01/10)
20-Dec-11
5,000
5,000
---
---
8,580
--
53,600
189,000
70,800
NO
77,200
47,200
NO
30-May-12
1,000
1,000
-
---
8,140
-
64,700
200,000
76,700
8,360
104,000
44,400
NO
5-Dec-12
1,000
5,000
-
---
7,690
-
22,600
178,000
76,600
ND
106,000
46,500
ND
12-Jun-13
1,000
5,000
-
---
7,950
-
138,000
202,000
111,000
7,020
99,700
51,700
ND
28-Oct-13
1,000
5,000
-
---
8,140
-
69,900
197,000
91,300
9,520
116,000
45,000
ND
6-May-14
SM 2320B
1,000
5,000
-
-
8,060
-
85,900
208,000
90,600
5,520
119,000
45,700
ND
23-Oct-14
SM 2320B
1,000
5,000
-
-
*
1,360 J
88,100
215,000
96,100
7,500
122,000
52,000
--
20-May-15
SM 2320B
1,000
5,000
-
-
-
NO
67,300
153,000
67,500
8,780
92,100
41,600
---
8-Dec-15
SM 2320B
1,000
NE
-
-
-
1,030 J
98,400
202,000
88,800
9,130
95,900
46,200
---
3-May-16
SM 2320B
1,000
NE
-
-
-
1,250 J
57,400
146,000
56,800
9,300
79,200
49,600
ND
13-Dec-16
SM 2320B
1,000
5,000
-
-
-
1,190 J
35,700
97,700
54,100
9,380
72,100
49,400
---
27-Jun-17
SM 2320B
1,000
5,000
-
-
-
NO
102,000
165,000
98,700
11,300
99,100
51,200
--
13-Dec-17
SM 2320B
1,000
5,000
-
-
-
-
42,900
117,000
69,000
10,200
92,100
49,600
---
16-May-18
SM 2320B
1,000
NE
-
-
-
2,340 J
72,300
151,000
94,400
7,350
99,300
50,800
ND
6-Dec-18
SM 2320B
1,000
5,000
-
-
-
-
68,500
196,000
122,000
ND
128,000
52,400
ND
8-May-19
SM 2320B-2011
1,000
5,000
-
-
3,950
J -
79,600
179,000
82,600
3,800
J 121,000
49,600
ND
8-Nov-19
SM 2320B-2011
5,000
5,000
-
-
ND
ND
40,400
141,000
105,000
ND
65,000
47,500
---
8-May-20
SM 2320B-2011
5,000
5,000
-
-
-
NO
61,700
141,000
67,300
11,000
114,000
49,400
--
11-Nov-20
SM 2320B-2011
5,000
5,000
-
-
-
ND
61,500
156,000
103,000
7,720
135,000
-
--
5-May-21
SM 2320B-2011
5,000
5,000
-
-
-
NO
58,000
210,000
88,000
9,230
124,000
-
ND
3-Nov-21
SM 2320B-2011
5,000
5,000
-
-
-
ND
33,200
123,000
97,000
10,000
117,000
-
ND
19-May-22
SM 2320B-2011
5,000
5,000
-
-
-
NO
58,000
210,000
88,000
9,230
124,000
-
ND
17-Nov-22
SM 2320B-2011
5,000
5,000
-
-
5,690
ND
63,000
165,000
115,000
6,250
151,000
-
ND
6-Nov-23
SM 2320B-2011
5,000
5,000
-
-
-
NO
48,500
213,000
134,000
ND
136,000
-
-
Chloride
1-Jun-11
5,000
5,000
-
ND
-
-
-
17,000
6,330
-
7,870
-
ND
NC 2L = 250,000 Ng/L (01/01/10)
20-Dec-11
5,000
5,000
-
-
NO
-
6,320
20,200
6,400
NO
6,530
NO
NO
30-May-12
1,000
1,000
-
-
1,480
-
6,190
20,000
ND
2,100
5,840
NO
NO
5-Dec-12
1,000
1,000
-
-
2,130
-
5,970
19,500
7,290
2,060
7,430
1,130
ND
12-Jun-13
1,000
1,000
-
-
1,380
-
13,300
19,500
7,500
2,260
5,100
NO
NO
28-Oct-13
1,000
1,000
-
-
1,120
-
11,400
18,100
7,750
2,210
8,490
NO
NO
6-May-14
SM 4500-CI-E
1,000
1,000
-
-
NO
-
17,300
18,200
8,140
1,890
8,920
ND
ND
23-Oct-14
SM 4500-CI-E
500
1,000
-
-
*
NO
19,200
20,800
9,050
1,570
8,120
642 J
ND
20-May-15
SM 4500-CI-E
500
1,000
-
-
-
-
14,000
25,300
9,680
1,720
10,400
572 J
-
8-Dec-15
SM 4500-CI-E
500
NE
-
-
-
859 J
26,500
30,800
9,400
1,910
4,190
945 J
-
3-May-16
SM 4500-CI-E
500
NE
-
-
-
558 J
13,500
33,200
11,300
3,170
7,810
1,120
-
13-Dec-16
SM 4500-CI-E
500
1,000
-
-
-
1,470
9,040
35,000
7,650
1,810
9,280
965 J
-
27-Jun-17
SM 4500-CI-E
500
1,000
-
-
-
NO
11,500
29,700
10,400
1,550
7,000
NO
-
13-Dec-17
SM 4500-CI-E
500
1,000
-
-
-
681 J
9,490
39,000
10,900
1,900
8,430
739 J
ND
16-May-18
SM 4500-CI-E
500
NE
-
-
-
1,100
8,410
34,200
9,550
2,010
5,730
1,310
ND
6-Dec-18
SM 4500-CI-E
1,000
2,000
-
-
-
1,020
8,470
52,900
11,700
2,020
9,740
1,110
ND
8-May-19
SM 4500-CI-E-2011
500
1,000
-
-
1,330
-
9,180
44,800
12,700
1,940
11,000
730 J
NO
S-Nov-19
SM 4500-Cl-E-2011
500
1,000
-
-
1,610
1,020
8,560
50,900
13,300
1,850
5,030
892 J
-
8-May-20
SM 4500-CI-E-2011
500
1,000
-
-
-
1,270
9,160
44,500
13,400
2,680
10,400
2,970
-
11-Nov-20
SM4500-CI-E-2011
500
1,000
-
-
-
720 1
9,790
62,600
14,100
1,860
7,210
-
-
5-May-21
SM 4500-CI-E-2011
500
1,000
-
-
-
601 J
10,200
76,100 D
14,900
1,880
9,730
-
ND
3-Nov-21
SM4500-Cl-E-2011
500
1,000
-
-
-
588 1
11,600
77,000
14,300
2,040
6,940
-
ND
19-May-22
SM 4500-CI-E-2011
500
1,000
-
-
-
825 J
-
82,600
14,800
-
12,600
-
-
17-Nov-22
SM 4500-Cl-E-2011
500
1,000
-
-
1,850
2,510
11,000
72,600
15,200
2,990
10,700
-
--
6-Nov-23
EPA 300.0 Rev 2.1
looa
600
1,000
-
-
-
NO
12,000
93,800
17,000
2,000
13,000
-
-
Sulfate
1-Jun-11
5,000
5,000
-
ND
-
-
-
ND
ND
-
ND
-
ND
NC 21 250,000 Ng/L (01/01/10)
20-Dec-11
5,000
5,000
-
-
ND
-
5,150
NO
NO
NO
NO
8,630
NO
30-May-12
2,000
250,000
-
-
ND
-
5,380
J ND
ND
ND
ND
8,860 1
ND
5-Dec-12
2,000
250,000
-
-
ND
-
2,880
J 2,920 J
4,400
J
ND
2,320 J
8,910 J
ND
12-Jun-13
2,000
250,000
-
-
ND
-
11,200
J 3,080 J
2,910
J
6,940
J ND
9,310 J
ND
28-Oct-13
2,000
250,000
-
-
ND
-
4,420
J ND
2,940
J
ND
ND
8,150 J
ND
6-May-14
EPA 300.0
2,000
250,000
-
-
NO
-
10,500
J 2,300 J
3,720
J
ND
2,070 J
8,780 J
ND
23-Oct-14
EPA 300.0
1,000
250,000
-
-
*
NO
7,270
J 2,280 J
3,740
J
1,240
J 1,940 J
9,710 J
ND
20-May-15
EPA 300.0
1,000
250,000
-
-
-
NO
5,620
J 2,310 J
3,440
J
ND
2,150 J
8,780 J
-
8-Dec-15
EPA 300.0
1,000
250,000
-
-
-
NO
10,200
J 1,530 J
2,020
J
ND
ND
9,260 J
--
3-May-16
EPA 300.0
2,000
250,000
-
-
-
NO
5,300
J 5,490 J
3,440
J
ND
ND
8,720 J
--
13-Dec-16
EPA 300.0
1,000
250,000
-
-
-
1,340 J
3,220
J 3,500 J
4,050
J
1,340
J 1,930 J
9,850 J
--
27-Jun-17
EPA 300.0
500
250,000
-
-
-
NO
5,290
J 2,120 J
3,200
J
ND
NO
9,920 J
--
13-Dec-17
EPA 300.0
500
250,000
-
-
-
-
2,000
J 2,230 J
2,080
J
ND
NO
9,590 J
-
16-May-18
EPA 300.0
500
250,000
-
-
-
NO
1,690
J 1,780 J
1,580
J
ND
ND
7,530 J
ND
6-Dec-18
EPA 300.0
500
1,000
-
-
-
NO
1,560
1,720
1,450
526
J 621 J
8,670
ND
8-May-19
EPA 300.0 R. 2.11993
500
1,000
-
-
ND
-
3,080
2,830
1,960
720
J 1,790
8,940
ND
8-Nov-19
EPA 300.0 Rev 2.11993
500
1,000
-
-
ND
ND
1,070
2,560
1,490
838
J ND
8,200
-
8-May-20
EPA 300.0Rev2.11993
500
1,000
-
-
-
ND
1,430
3,640
2,520
ND
ND
8,520
-
11-Nov-20
EPA 300.0 Rev 2.11993
500
1,000
-
-
-
ND
1,100
3,680
1,200
ND
590 J
-
-
5-May-21
EPA 300.0Rev2.11993
500
1,000
-
-
-
ND
782
1 4,560
1,100
ND
510 J
-
ND
3-Nov-21
EPA 300.0 Rev 2.11993
500
1,000
-
-
-
ND
567
J 4,400
960
J
ND
ND
-
ND
19-May-22
EPA 300.0Rev2.11993
500
1,000
-
-
-
ND
1,100
4,330
827
J
557
J ND
-
-
17-Nov-22
EPA 300.0 Rev 2.11993
500
1,000
-
-
532
J ND
1,020
3,330
862
J
576
J 602 J
-
-
6-Nov-23
EPA 300.0Rev2.11993
500
1,000
-
-
-
ND
1,300
6,900
1,200
1,200
1,100
-
-
Total Dissolved Solids
1-Jun-11
25,000
25,000
-
62,000
-
-
-
200,000
93,000
-
127,000
-
ND
NC 21- = 500,000 Ng/L (01/01/10)
20-Dec-11
25,000
25,000
-
-
NO
-
59,000
196,000
82,000
NO
103,000
78,000
NO
30-May-12
25,000
25,000
-
-
37,000
-
85,000
12,500 J
109,000
NO
136,000
90,000
NO
5-Dec-12
25,000
25,000
-
-
35,000
-
50,000
219,000
109,000
28,000
134,000
97,000
ND
12-Jun-13
25,000
25,000
-
-
34,000
-
177,000
225,000
136,000
NO
111,000
107,000
ND
28-Oct-13
25,000
25,000
-
-
49,000
-
109,000
227,000
134,000
NO
138,000
112,000
ND
6-May-14
SM 2540C
25,000
25,000
-
-
34,000
-
136,000
234,000
115,000
32,000
126,000
102,000
ND
23-Oct-14
SM 2540C
25,000
25,000
-
-
*
NO
126,000
238,000
119,000
NO
129,000
98,000
ND
20-May-15
SM 2540C
25,000
25,000
-
-
-
NO
112,000
252,000
122,000
30,000
135,000
88,000
-
8-Dec-15
SM 2540C
25,000
NE
-
-
-
NO
182,000
280,000
117,000
NO
106,000
93,000
-
3-May-16
SM 2540C
25,000
NE
-
-
-
NO
110,000
245,000
129,000
NO
89,000
89,000
-
13-Dec-16
SM 2540C
25,000
25,000
-
-
-
NO
73,000
241,000
133,000
NO
131,000
90,000
-
27-Jun-17
SM 2540C
25,000
25,000
-
-
-
NO
151,000
237,000
153,000
NO
105,000
-
-
13-Dec-17
SM 2540C
25,000
25,000
-
-
-
NO
76,000
239,000
118,000
NO
137,000
72,000
ND
16-May-18
SM 2540C
25,000
NE
-
-
-
NO
74,000
245,000
141,000
27,000
119,000
-
ND
6-Dec-18
SM 2540C
25,000
25,000
-
-
-
NO
99,000
284,000
159,000
32,000
155,000
100,000
ND
8-May-19
SM 2540C-2011
25,000
25,000
-
-
27,000
-
87,000
270,000
149,000
32,000
160,000
101,000
ND
8-May-20
SM 2540C-2011
25,000
25,000
-
-
-
ND
103,000
279,000
165,000
34,000
130,000
98,000
---
11-Nov-20
SM 254OC-2011
25,000
25,000
-
-
-
ND
116,000
329,000
1,680,000
43,000
172,000
-
--
5-May-21
SM 254OC-2011
25,000
25,000
-
-
-
NO
69,000
169,000
148,000
ND
164,000
-
ND
3-Nov-21
SM 2540c-2015
25,000
25,000
-
-
-
NO
71,000
403,000
161,000
30,000
ND
-
ND
18-May-22
SM 2540c-2016
25,000
25,000
-
-
-
NO
69,000
169,000
148,000
ND
16,400
-
ND
17-Nov-22
SM 2540c-2016
25000
25000
-
-
-
ND
71000
403000
161000
30000
NO
-
NO
Methane
8-May-20
RSK 175 Mod.
3
10
-
-
-
NO
-
3,000
14,500
-
11,700
-
-
11-Nov-20
RSK 175 Modified
3
10
-
-
-
NO
-
2,290
17,600
-
17,500
-
-
5-May-21
-
-
-
-
-
-
-
-
-
-
-
-
-
-
3-Nov-21
RSK-175
2.91
10
-
-
-
-
-
-
9230
-
9270
-
-
18-May-22
RSK 175 Modified
3.4
10
-
-
-
NO
-
5430
27000
-
12400
-
-
17-Nov-22
RSK-175
2.91
10
-
-
NO
NO
-
5170
-
-
-
-
-
11-May-23
RSK 175 Modified
5.3
10
-
-
-
NO
-
1370
4500
M1
-
5610
-
-
6-Nov-23
RSK 175 Modified
5.3
10
-
-
-
7.5 J,
647
2820
5920
D6
-
3870
-
-
Total Organic Carbon
8-May-20
SM 5310E-2011
500
1,000
-
-
-
555 J
-
5,410
1,840
-
3,710
-
--
11-Nov-20
SM 5310E-2011
500
1,000
-
-
-
ND
-
6,000
2,450
-
3,890
-
--
5-May-21
-
-
-
-
--
--
---
---
3-Nov-21
SM 5310E-2014
500
1000
-
-
-
-
--
-
1390
-
3010
-
--
18-May-22
SM 5310E-2014
500
1000
-
-
-
ND
-
7170
1280
-
2350
-
--
17-Nov-22
SM 2540C-2011
500
1000
-
--
-
ND
-
7070
1330
-
2110
-
--
11-May-23
SM 5310E-2014
500
1000
-
---
-
ND
-
8700
1800
-
2300
-
--
6-Nov-23
SM 5310E-2014
500
1000
-
---
--
ND
730
J 7800
1500
-
1600
-
--
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 12 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Sample
EPA
Analyte
Collection Date
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-16D
Blanks
Nitrogen, Nitrate
8-May-20
EPA 353.2 Rev 2.0 1992
10
40
178
---
---
---
---
II-Nov-20
EPA 353.2 R. 2.01993
10
40
163
ND
ND
ND
1-Dec-20
EPA 353.2 Rev 2.01993
10
40
152
ND
39
1
37
1
II-Nov-20
EPA 353.2 R. 2.01993
10
40
163
ND
ND
ND
5-May-21
-
---
---
---
---
---
---
3-Nov-21
EPA 353.2 R. 2.01993
500
2000
--
ND
ND
18-May-22
EPA 353.2 R. 2.01993
10
40
170
ND
ND
20.8
1
17-Nov-22
EPA 353.2 R. 2.01993
100
400
171
ND
ND
ND
11-May-23
EPA 353.2 R. 2.01993
10
40
150
--
ND
ND
ND
6-Nov-23
EPA 353.2 R. 2.01993
29
40
150
46
ND
52
76
Acetone
30-May-07
-
100.0
-
2.7
B
--
ND
ND
ND
ND
ND
ND
NC 21- = 700 pg/L (10/23/07)
29-Nov-07
-
100.0
-
8.1
B
3
B ND
2.8
B 8.1 B
13
B 2.6 B
29-May-08
20.0
100.0
-
ND
ND
ND
ND
ND
ND
ND
6-Nov-08
20.0
100.0
-
26.8
J
ND
ND
ND
ND
ND
ND
3-Jun-09
2.2
100.0
-
48.3
J
6.5
1 ND
ND
ND
18.5
1 ND
18-Nov-09
2.2
100.0
-
ND
ND
ND
ND
ND
ND
ND
ND
NC 21- 6,000 pg/L (01/01/10)
16-Jun-10
2.2
100.0
-
5.3
B -
-
ND
3.1
B ND
ND
ND
ND
1-Dec-10
2.2
100.0
-
ND
ND
8.4
B ND
ND
ND
56.6
1 ND
1-Jun-11
2.2
100.0
-
3.5
B ND
3.4
B 8.1
B 7.7
B ND
80
1 ND
20-Dec-11
2.2
100.0
-
-
ND
ND
ND
ND
ND
ND
ND
30-May-12
2.2
100.0
-
-
ND
ND
ND
ND
ND
ND
ND
5-Dec-12
10.0
100.0
-
-
ND
ND
ND
ND
ND
ND
ND
12-Jun-13
10.0
100.0
-
-
ND
33
1 ND
ND
ND
20.5
1 ND
28-Oct-13
10.0
100.0
-
-
ND
ND
ND
ND
ND
ND
ND
6-May-14
EPA 8260
10.0
100.0
-
-
ND
ND
ND
ND
ND
ND
ND
22-Oct-14
EPA 8260
10.0
100.0
-
-
ND
ND
ND
10.4
1 ND
ND
ND
21-May-15
EPA 8260
10.0
100.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Dec-15
EPA 8260
10.0
100.0
-
-
-
ND
ND
ND
ND
ND
16.5
1 ND
3-May-16
EPA 8260
10.0
100.0
-
-
-
ND
ND
ND
ND
41.5 J
ND
ND
ND
13-Dec-16
EPA 8260
10.0
100.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
27-Jun-17
EPA 8260
10.0
100.0
-
-
-
35.8 J
10.4
J 32.4
J 22.8
1 15.9 1
33
1 13.4 1
-
13-Dec-18
EPA 8260
10.0
100.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
4-Jun-18
EPA 8260
10.0
100.0
-
-
ND
ND
ND
ND
ND
14.7
1 ND
6-Dec-18
EPA 8260
10.0
25.0
-
-
ND
12.3
1 ND
ND
ND
ND
ND
8-May-19
EPA 8260
8.2
25.0
-
-
ND
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA 6010D
19.5
50.0
-
-
ND
ND
ND
ND
ND
ND
ND
ND
8-May-20
EPA 8260D
6.2
25.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
11-Nov-20
EPA 8260D
6.2
25.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
5-May-21
EPA 8260D
5.1
25.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
EPA 8260D
5.1
25.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
EPA 8260D
5.1
25.0
-
-
-
ND
ND
ND
ND
ND
ND
-
17-Nov-22
EPA 8260D
5.1
25.0
-
-
ND
ND
ND
15.4
J ND
ND
ND
-
6-Nov-23
EPA8260D
5.1
25.0
-
-
-
ND
ND
ND
ND
ND
ND
-
Acrolein
8-Dec-15
EPA 8260
1.6
53.0
-
-
1.6 B
ND
ND
ND
ND
ND
-
# NC 2L 6,000 pg/L (01/01/10)
13-Dec-16
EPA8260
1.6
53.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
6-Dec-18
EPA 8260
1.6
10.0
-
-
-
ND
ND
ND
ND
ND
ND
-
8-Nov-19
EPA8260D
2.7
10.0
ND
ND
ND
ND
ND
ND
ND
11-Nov-20
EPA8260D
2.7
10.0
ND
ND
ND
ND
ND
ND
ND
3-Nov-21
EPA8260D
8.5
10
ND
ND
ND
ND
ND
ND
ND
5-May-21
-
-
17-Nov-22
EPA8260D
8.5
10
ND
ND
ND
ND
ND
ND
6-Nov-23
EPA8260D
8.5
10
ND
ND
ND
ND
ND
ND
Benzene
1-Oct-96
-
5.0
NI
-
ND
6
ND
ND
NI
NI
1-May-97
5.0
ND
NI
-
ND
6.8
2.7
1 ND
NI
NI
1-Nov-97
1.0
ND
NI
-
ND
9
ND
ND
NI
NI
1-May-98
5.0
ND
NI
-
ND
10
9.4
ND
NI
NI
24-Nov-98
2.0
ND
NI
-
ND
11.6
ND
ND
NI
NI
10-May-99
5.0
ND
ND
-
ND
13
ND
ND
5.3
ND
18-Oct-99
5.0
ND
ND
-
ND
12
ND
ND
5.4
ND
3-May-00
5.0
ND
ND
-
ND
10
ND
ND
6.3
ND
7-Nov-00
5.0
ND
ND
-
ND
9.2
ND
ND
ND
ND
31-May-01
5.0
ND
ND
-
ND
7.7
ND
ND
5.8
ND
7-Nov-01
5.0
ND
ND
-
ND
8.1
5.2
ND
6.7
ND
22-May-02
5.0
ND
ND
-
ND
8.2
8.1
ND
8.0
ND
14-Nov-02
5.0
ND
ND
-
ND
5.1
7.7
ND
9.4
ND
14-May-03
5.0
ND
ND
-
ND
8
5.4
7
13
ND
20-Nov-03
5.0
ND
ND
-
ND
7.3
5.7
7.5
9.2
ND
6-May-04
5.0
ND
ND
-
ND
7.3
7.2
9.3
9.6
ND
10-Nov-04
5.0
ND
ND
-
ND
7.5
6
8.5
10
ND
27-May-05
5.0
ND
ND
-
ND
8
9
11
9
ND
3-Nov-05
5.0
ND
-
ND
ND
5
8
6
ND
25-May-06
-
5.0
ND
-
ND
ND
6.1
8.5
5.3
ND
2-Nov-06
-
5.0
ND
-
ND
5.3
5.3
11
7.6
ND
30-May-07
1.0
0.22
J -
0.87
1 7.3
7.4
13
6.6
ND
NC 21- = 1 pg/L (10/23/07)
29-Nov-07
-
1.0
0.6
1 -
0.79
1 3.6
2.8
U
3.3
ND
29-May-08
0.25
1.0
0.49
J -
0.88
1 4.6
4.6
13.5
4.1
ND
6-Nov-08
0.25
1.0
0.53
J -
0.81
1 4.3
4.4
12
3.1
ND
3-Jun-09
0.25
1.0
0.67
J -
1.2
4.5
5.4
15.3
4.1
ND
18-Nov-09
0.25
1.0
1.3
-
0.81
1 4
5.6
14.9
3.3
ND
16-Jun-10
0.25
1.0
0.59
J -
0.81
1 5.9
5
14.3
2.4
ND
1-Dec-10
0.25
1.0
ND
ND
0.96
1 5
3
11.5
4
ND
1-Jun-11
0.25
1.0
0.99
1 ND
1.0
5.4
3.9
16.1
1.2
ND
20-Dec-11
0.25
1.0
-
ND
1.0
1 4.2
3.1
12.9 D
2
ND
30-May-12
0.25
1.0
-
ND
ND
4.4
2.8
14.7
2
ND
5-Dec-12
0.25
1.0
-
ND
0.83
1 4.1
2.8
14.9
1.6
ND
12-Jun-13
0.25
1.0
-
ND
1.5
3.5
4.2
15.9
2.9
ND
28-Oct-13
0.25
1.0
-
ND
1.0
4.1
4.1
15.6
2
ND
6-May-14
EPA 8260
0.25
1.0
-
ND
1.6
3.9
3.8
17.2
2.1
ND
22-Oct-14
EPA 8260
0.25
1.0
ND
1.8
2.8
3.0
14.9
1.8
ND
21-May-15
EPA 8260
0.25
1.0
ND
ND
1.3
2.8
2.8
12.3
1.2
ND
8-Dec-15
EPA 8260
0.25
1.0
-
-
ND
1.6
2.2
2.3
13.8
1.7
ND
3-May-16
EPA 8260
0.25
1.0
-
-
-
ND
1.8
2.8
2.9
14.1
1.5
ND
ND
13-Dec-16
EPA 8260
0.25
1.0
-
-
-
ND
1.7
2.3
2.8
14.5
1.4
ND
ND
27-Jun-17
EPA 8260
0.25
1.0
-
-
-
ND
1.6
2.1
2.6
14.8
1.2
ND
13-Dec-18
EPA 8260
0.25
1.0
-
-
-
ND
1.6
2.6
2.5
14.5
1.2
ND
4-Jun-18
EPA 8260
0.25
1.0
-
-
ND
1.2
1.7
2.2
12.6
1.4
ND
6-Dec-18
EPA 8260
0.25
1.0
-
-
ND
ND
2.4
3.1
13.9
2.1
ND
8-May-19
EPA 8260
0.2
1.0
-
-
ND
2.3
3.2
5.4
18.6
2.7
ND
8-Nov-19
EPA8260D
0.2
1.0
-
-
ND
ND
1.4
1.8
2.8
12.3
1.2
ND
8-May-20
EPA8260D
0.2
1.0
-
-
-
ND
1.2
2.1
3.1
13.1
1.5
ND
ND
11-Nov-20
EPA8260D
0.9
10.0
-
-
-
ND
1.6
2.7
3.5
12.9
2.1
ND
5-May-21
EPA8260D
0.34
1.0
-
-
-
ND
1.6
2.7
3.1
11.8
1.8
ND
3-Nov-21
EPA8260D
0.34
1.0
-
-
-
ND
1.9
2.3
2.5
10.9
1.5
ND
19-May-22
EPA8260D
0.34
1.0
-
-
-
ND
1.5
2.4
2.8
10.3
1.4
17-Nov-22
EPA8260D
1.80
10.0
-
-
ND
ND
1.5
1.8
3.4
9.3
2.1
6-Nov-23
EPA8260D
1.80
10.0
-
-
ND
1.5
2.7
3.6
11.6
3.0
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 13 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Sample
EPA
Analyte
Collection Date
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-16D
Blanks
Bromodichloromethane
30-May-07
--
1.0
---
ND
---
---
0.54 J
ND
0.63 1
ND
ND
ND
NC 2L= 0.56 pg/L (10/23/07)
29-Nov-07
-
1.0
--
ND
--
---
ND
ND
ND
ND
ND
ND
29-May-08
0.18
1.0
--
ND
-
---
ND
ND
ND
ND
ND
ND
6-Nov-08
0.18
1.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
3-Jun-09
0.18
1.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
18-Nov-09
0.18
1.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
NC 2L = 0.6 pg/L (01/01/10)
16-Jun-10
0.18
1.0
-
ND
-
--
ND
ND
ND
ND
ND
ND
1-Dec-10
0.18
1.0
-
ND
ND
---
ND
ND
ND
ND
ND
ND
1-Jun-11
0.18
1.0
-
ND
ND
---
ND
ND
ND
ND
ND
ND
20-Dec-11
0.18
1.0
-
-
ND
---
ND
ND
ND
ND
ND
ND
30-May-12
0.18
1.0
-
-
ND
---
ND
ND
ND
ND
ND
ND
5-Dec-12
0.18
1.0
-
-
ND
---
ND
ND
ND
ND
ND
ND
12-Jun-13
0.18
1.0
--
-
ND
--
ND
ND
ND
ND
ND
ND
28-Oct-13
0.18
1.0
--
-
ND
-
ND
ND
ND
ND
ND
ND
6-May-14
EPA 8260
0.18
1.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
22-Oct-14
EPA 8260
0.18
1.0
-
-
*
ND
ND
ND
ND
ND
ND
ND
21-May-15
EPA 8260
0.18
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Dec-15
EPA 8260
0.18
1.0
--
-
-
ND
ND
ND
ND
ND
ND
ND
3-May-16
EPA 8260
0.18
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
13-Dec-16
EPA 8260
0.18
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
27-Jun-17
EPA 8260
0.18
1.0
--
--
-
ND
ND
ND
ND
ND
ND
ND
---
13-Dec-18
EPA 8260
0.18
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
4-Jun-18
EPA 8260
0.18
1.0
--
--
-
ND
ND
ND
ND
ND
ND
ND
6-Dec-18
EPA 8260
0.18
1.0
--
--
-
ND
ND
ND
ND
ND
ND
ND
8-May-19
EPA 8260
0.36
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA 8260D
0.26
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-20
EPA8260D
0.34
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
II-Nov-20
EPA8260D
0.34
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
5-May-21
EPA8260D
0.31
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
EPA 8260D
0.31
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
EPA8260D
0.47
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
---
17-Nov-22
EPA8260D
0.47
1.0
-
-
ND
ND
ND
ND
ND
ND
ND
-
---
6-Nov-23
EPA8260D
0.47
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
---
Bromomethane
12-Jun-13
0.29
10.0
-
-
ND
---
1.4 J
ND
ND
ND
ND
ND
NC 2L = NE (10/23/07)
28-Oct-13
0.29
10.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
6-May-14
EPA 8260
0.29
10.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
22-Oct-14
EPA 8260
0.29
10.0
-
-
*
ND
ND
ND
ND
ND
ND
ND
21-May-15
EPA 8260
0.29
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Dec-15
EPA 8260
0.29
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
3-May-16
EPA 8260
0.29
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
13-Dec-16
EPA 8260
0.29
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
27-Jun-17
EPA 8260
0.29
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
---
13-Dec-18
EPA 8260
0.29
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
6-Dec-18
EPA 8260
0.29
2.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-19
EPA 8260
0.95
2.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA8260D
0.62
2.0
8-May-20
EPA8260D
0.62
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
II-Nov-20
EPA8260D
0.62
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
5-May-21
EPA8260D
1.7
2.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
EPA8260D
1.7
2.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
EPA 8260D
0.3
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
---
17-Nov-22
EPA 8260D
0.3
1.0
-
-
ND
ND
ND
ND
ND
ND
ND
-
---
6-Nov-23
EPA 8260D
0.3
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
---
2-Butanone (MEK)
20-Dec-11
0.96
100.0
-
-
ND
-
ND
ND
ND
5.6
ND
ND
NC 2L = 4000 pg/L (10/23/07)
30-May-12
0.96
100.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
5-Dec-12
0.96
100.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
12-Jun-13
0.96
100.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
28-Oct-13
0.96
100.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
6-May-14
EPA 8260
0.96
100.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
22-Oct-14
EPA 8260
0.96
100.0
-
-
*
ND
ND
ND
ND
ND
ND
ND
21-May-15
EPA 8260
0.96
100.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Dec-15
EPA 8260
0.96
100.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
3-May-16
EPA 8260
0.96
100.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
13-Dec-16
EPA 8260
0.96
100.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
27-Jun-17
EPA 8260
0.96
100.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
--
13-Dec-18
EPA 8260
0.96
100.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
4-Jun-18
EPA 8260
0.96
100.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
6-Dec-18
EPA 8260
0.96
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-19
EPA 8260
3.2
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA8260D
3.3
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-20
EPA8260D
3.3
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
11-Nov-20
EPA8260D
3.3
5.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
5-May-21
EPA8260D
4.0
5.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
EPA8260D
4.0
5.0
-
-
-
ND
ND
4.9 1
ND
ND
ND
-
ND
19-May-22
EPA8260D
4.0
5.0
-
-
-
ND
ND
ND
ND
ND
ND
-
-
17-Nov-22
EPA8260D
4.0
5.0
-
-
ND
ND
ND
ND
ND
ND
ND
-
--
6-Nov-23
EPA8260D
4.0
5.0
-
-
-
ND
ND
ND
ND
ND
ND
-
-
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 14 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Sample
EPA
Analy[e
Collection Date
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW-10
MW-11
MW-1-2
MW-13
MW-16S
MW-161D
Blanks
Carbon Disulfide
1-Nov-97
-
1.0
S
NI
ND
ND
ND
ND
NI
NI
1-May-98
-
5.0
ND
NI
ND
ND
ND
ND
NI
NI
24-Nov-98
-
2.0
6.2
NI
---
---
ND
ND
8.9
ND
NI
NI
10-May-99
-
5.0
ND
ND
-
---
ND
ND
6.7
9
ND
100
18-Oct-99
-
100.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
3-May-00
-
100.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
7-Nov-00
-
100.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
31-May-01
-
100.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
7-Nov-01
-
100.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
22-May-02
-
100.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
14-Nov-02
-
100.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
14-May-03
-
100.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
20-Nov-03
-
100.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
6-May-04
-
100.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
10-Nov-04
-
100.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
27-May-05
-
100.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
3-Nov-05
-
100.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
25-May-06
-
100.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
2-Nov-06
-
100.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
30-May-07
-
100.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
NC 2L = 700 pg/L (10/23/07)
29-Nov-07
-
100.0
-
ND
-
--
ND
ND
ND
ND
ND
ND
29-May-08
1.2
100.0
-
ND
-
--
ND
ND
ND
ND
ND
ND
6-Nov-08
1.2
100.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
3-Jun-09
1.2
100.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
18-Nov-09
1.2
100.0
-
ND
-
--
ND
ND
ND
ND
ND
ND
16-Jun-10
1.2
100.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
1-Dec-10
1.2
100.0
-
ND
ND
--
ND
ND
ND
ND
ND
ND
1-Jun-11
1.2
100.0
-
ND
ND
--
ND
ND
ND
ND
ND
ND
20-Dec-11
1.2
100.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
30-May-12
1.2
100.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
5-Dec-12
1.2
100.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
12-Jun-13
1.2
100.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
28-Oct-13
1.2
100.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
6-May-14
EPA 8260
1.2
100.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
22-Oct-14
EPA 8260
1.2
100.0
-
-
*
ND
ND
ND
ND
ND
ND
ND
21-May-15
EPA 8260
1.2
100.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Dec-15
EPA 8260
1.2
100.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
3-May-16
EPA 8260
1.2
100.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
13-Dec-16
EPA 8260
1.2
100.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
27-Jun-17
EPA 8260
1.2
100.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
---
13-Dec-18
EPA 8260
1.2
100.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
4-Jun-18
EPA 8260
1.2
100.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
6-Dec-18
EPA 8260
1.2
2.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-19
EPA 8260D
0.79
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA 8260D
0.40
2.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-20
EPA 8260D
0.40
2.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
II-Nov-20
EPA 8260D
0.40
2.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
5-May-21
EPA 8260D
0.73
2.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
EPA 8260D
0.73
2.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
EPA 8260D
0.36
2.0
-
-
-
ND
ND
ND
ND
ND
ND
-
---
17-Nov-22
EPA 8260D
0.36
2.0
-
-
ND
ND
ND
ND
ND
ND
ND
-
---
6-Nov-23
EPA 8260D
0.36
2.0
-
-
-
ND
ND
ND
ND
ND
ND
-
---
Carbon Tetrachloride
8-May-19
EPA 8260D
0.42
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
NC 2L= 0.3 pg/L(04/2013)
8-Nov-19
EPA8260D
0.22
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-20
EPA 8260D
0.22
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
II-Nov-20
EPA 8260D
0.22
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
5-May-21
EPA 8260D
0.33
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
EPA 8260D
0.33
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
EPA 8260D
0.33
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
---
17-Nov-22
EPA 8260D
0.33
1.0
-
-
ND
ND
ND
ND
ND
ND
ND
-
---
6-Nov-23
EPA 8260D
0.33
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
---
Chlorobenzene
30-May-07
-
3.0
-
ND
--
--
ND
0.63
1 1.1
1 0.3
1 0.61
1 ND
NC 2L= 50 pg/L(10/23/07)
29-Nov-07
-
3.0
-
ND
-
-
ND
ND
ND
ND
ND
ND
29-May-08
0.23
3.0
-
ND
-
-
ND
0.48
1 0.7
J 0.32
J 0.59
J ND
6-Nov-08
0.23
3.0
-
ND
-
--
ND
0.53
1 0.8
1 0.3
J 0.59
J ND
3-Jun-09
0.23
3.0
-
ND
-
---
0.26
1 0.47
1 0.73
1 0.39
J 0.76
J ND
18-Nov-09
0.23
3.0
-
ND
-
---
ND
0.51
1 1.0
J 0.39
J 0.71
J ND
16-1un-10
0.23
3.0
-
ND
-
---
ND
0.9
1 1.2
1 0.41
1 0.79
J ND
1-Dec-10
0.23
3.0
-
ND
ND
---
ND
0.74
1 0.63
1 ND
0.72
J ND
1-Jun-11
0.23
3.0
-
ND
ND
---
ND
0.8
1 1.0
1 0.5
1 0.4
1 ND
20-Dec-11
0.23
3.0
-
-
ND
---
ND
0.7
1 0.7
1 ND
0.7
1 ND
30-May-12
0.23
3.0
-
-
ND
---
0.24
J 0.73
J 0.7
J 0.47
J 0.7
J ND
5-Dec-12
0.23
3.0
-
-
ND
---
ND
0.7
1 0.6
1 0.54
1 0.7
J ND
12-1un-13
0.23
3.0
-
-
ND
---
0.88
1 0.57
1 0.86
J 0.57
J 0.65
1 ND
28-Oct-13
0.23
3.0
-
-
ND
---
0.35
1 0.93
1 0.94
J 0.6
J 0.91
J ND
6-May-14
EPA 8260
0.23
3.0
-
-
ND
-
0.7
1 0.93
J 0.9
J 0.79
J 0.91
J ND
22-Oct-14
EPA 8260
0.23
3.0
-
-
*
ND
0.84
J 0.77
J 0.79
J 0.80
J 0.78
J ND
21-May-15
EPA 8260
0.23
3.0
-
-
-
ND
0.67
J 0.84
J 0.74
J 0.72
J 0.58
J ND
8-Dec-15
EPA 8260
0.23
3.0
-
-
-
ND
1.5
J 0.61
J 0.73
J 0.86
J 0.82
J ND
3-May-16
EPA 8260
0.23
3.0
-
-
-
ND
1.0
J 0.58
J 0.94
J 0.81
J 0.63
J ND
ND
13-Dec-16
EPA 8260
0.23
3.0
-
-
-
ND
0.85
J 0.48
J 0.63
J 0.96
J 0.69
J ND
ND
27-1un-17
EPA 8260
0.23
3.0
-
-
-
ND
1.3
J 0.53
J 0.73
J 1.1
J 0.57
J ND
--
13-Dec-18
EPA 8260
0.23
3.0
-
-
-
ND
1.2
J 0.70
J 0.63
J 1.1
J 0.76
J ND
4-Jun-18
EPA 8260
0.23
3.0
-
-
-
ND
1.3
J 0.76
1 0.8
J 1.2
J 0.81
J ND
6-Dec-18
EPA 8260
0.23
1.0
-
-
-
ND
1.5
0.81
J 0.87
J 1.3
1.1
ND
8-May-19
EPA 8260D
0.53
1.0
-
-
-
ND
1.8
0.89
J 1.4
1.7
1.1
ND
8-Nov-19
EPA 8260D
0.23
1.0
ND
1.2
0.49
J 0.75
J 1.2
5.8
J ND
ND
8-May-20
EPA 8260D
0.23
1.0
-
-
-
ND
1.1
0.80
J 0.84
J 1.3
0.82
1 ND
ND
II-Nov-20
EPA 8260D
0.23
1.0
-
-
-
ND
1.8
1.0
1.1
1.6
1.2
-
ND
5-May-21
EPA 8260D
0.28
1.0
-
-
-
ND
1.5
1.0
1.1
1.3
0.96
J -
ND
3-Nov-21
EPA 8260D
0.28
1.0
-
-
-
ND
ND
ND
ND
1.4
1.1
-
ND
19-May-22
EPA8260D
0.28
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
-
17-Nov-22
EPA8260D
0.28
1.0
-
-
ND
ND
1.5
0.9
J 0.82
J 1.2
0.95
J -
-
6-Nov-23
EPA8260D
0.28
1.0
-
-
-
ND
1.5
1.0
J 0.85
J 1.7
1
-
-
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 15 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Sample
EPA
Analyte
Collection Date
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-16D
Blanks
Chloroethane
1-Sep-94
---
10.0
ND
NI
NI
NI
ND
29
ND
ND
NI
NI
1-Jan-95
-
10.0
--
NI
NI
NI
ND
16
ND
ND
NI
NI
1-Feb-95
-
10.0
--
NI
NI
NI
ND
32
ND
ND
NI
NI
1-Mar-95
-
10.0
ND
NI
NI
NI
ND
34
11
ND
NI
NI
1-Aug-95
-
10.0
ND
NI
-
--
ND
47
ND
ND
NI
NI
1-Jan-96
-
10.0
-
NI
-
--
ND
ND
ND
ND
NI
NI
1-Feb-96
-
10.0
-
NI
-
-
ND
28
ND
ND
NI
NI
1-May-96
-
10.0
-
NI
-
--
ND
34
11
ND
NI
NI
1-Oct-96
---
10.0
-
NI
-
---
ND
23
11.00
ND
NI
NI
1-May-97
---
5.0
3.8 J
NI
-
---
15
33
11
ND
NI
NI
1-Nov-97
--
1.0
3
NI
-
---
10
ND
7
ND
NI
NI
1-May-98
--
10.0
ND
NI
-
---
ND
30
28
10
NI
NI
24-Nov-98
--
2.0
ND
NI
-
---
ND
ND
ND
ND
NI
NI
10-May-99
--
10.0
ND
ND
-
---
ND
10.0
ND
ND
17
ND
18-Oct-99
--
10.0
ND
ND
-
---
ND
12
ND
ND
21
ND
3-May-00
--
10.0
ND
ND
-
---
ND
ND
6.1
6.7
19
ND
7-Nov-00
--
10.0
ND
ND
-
---
ND
ND
ND
ND
13
ND
31-May-01
--
10.0
ND
ND
-
---
ND
ND
ND
ND
12
ND
7-Nov-01
--
10.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
22-May-02
--
10.0
12
ND
-
---
ND
ND
ND
ND
12
ND
14-Nov-02
--
10.0
10
ND
-
---
ND
ND
ND
ND
ND
ND
14-May-03
--
10.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
20-Nov-03
--
10.0
ND
ND
-
---
ND
ND
10
ND
ND
ND
6-May-04
---
10.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
10-Nov-04
--
10.0
ND
ND
-
---
ND
ND
10
ND
ND
ND
27-May-05
-
10.0
ND
ND
-
---
ND
ND
10.0
ND
ND
ND
3-Nov-05
-
10.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
25-May-06
-
10.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
2-Nov-06
-
10.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
30-May-07
-
10.0
-
ND
-
---
ND
ND
9.8
1 8.9
J ND
ND
NC 2L = 2,800 pg/L (10/23/07)
29-Nov-07
-
10.0
-
1.4
J -
--
ND
ND
4.3
J 5.7
JD 4.3
J ND
29-May-08
0.54
10.0
-
1.2
J --
--
1.1
1 ND
1.5
J 6.0
J 2.6
J ND
6-Nov-08
0.54
10.0
-
2
J ---
---
ND
0.9
1 3.5
1 5.6
J 4.3
J ND
3-Jun-09
0.54
10.0
-
1.1
J ---
---
ND
ND
ND
4.0
J 4.4
1 ND
18-Nov-09
0.54
10.0
-
3.1
J --
--
0.8
1 0.6
J 5.5
J 5.1
J 3.5
J ND
NC 2L = 3,000 pg/L (01/01/10)
16-Jun-10
0.54
10.0
-
1.7
J -
-
0.72
J 0.88
J 3.1
J 4.5
J 2.2
J ND
1-Dec-10
0.54
10.0
-
ND
ND
-
ND
ND
ND
ND
ND
ND
1-Jun-11
0.54
10.0
-
1.5
J ND
-
0.71
1 ND
2.7
1 3.8
J ND
ND
20-Dec-11
0.54
10.0
-
-
ND
-
0.64
1 ND
2.1
1 ND
2.9
J ND
30-May-12
0.54
10.0
-
-
ND
--
ND
ND
1.5
1 2.4
J ND
ND
5-Dec-12
0.54
10.0
-
-
ND
---
ND
ND
1.8
1 2.7
1 1.9
1 ND
12-1un-13
0.54
10.0
-
-
ND
--
ND
ND
0.63
1 0.84
J 1.5
J ND
28-Oct-13
0.54
10.0
-
-
ND
-
ND
ND
1.9
1 2.3
1 ND
ND
6-May-14
EPA 8260
0.54
10.0
-
-
ND
-
ND
ND
1.6
J 1.7
J 1.3
J ND
22-Oct-14
EPA 8260
0.54
10.0
-
-
*
ND
0.75
J ND
ND
2.1
J 1.6
J ND
21-May-15
EPA 8260
0.54
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Dec-15
EPA 8260
0.54
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
3-May-16
EPA 8260
0.54
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
13-Dec-16
EPA 8260
0.54
10.0
-
-
-
ND
ND
ND
3.0
J 1.2
J 1.7
J ND
ND
27-1un-17
EPA 8260
0.54
10.0
-
-
-
ND
0.58
1 ND
2.6
J 0.78
J 1.6
J ND
-
13-Dec-18
EPA 8260
0.54
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
4-Jun-18
EPA 8260
0.54
10.0
-
-
-
ND
ND
ND
1.8
1 ND
ND
ND
6-Dec-18
EPA 8260
0.54
1.0
-
-
-
ND
ND
ND
2.3
ND
2.9
ND
8-May-19
EPA 8260D
0.52
1.0
-
-
-
ND
ND
ND
1.3
ND
1.8
ND
8-Nov-19
EPA8260D
0.49
1.0
-
-
-
ND
ND
ND
1.9
ND
5.8
ND
ND
8-May-20
EPA8260D
0.49
1.0
-
-
-
ND
ND
ND
2.0
0.56
J 3.0
ND
ND
11-Nov-20
EPA8260D
0.49
1.0
-
-
-
ND
ND
ND
4.0
ND
2.9
-
ND
5-May-21
EPA8260D
0.65
1.0
-
-
-
ND
ND
ND
6.7
ND
34.6
-
ND
3-Nov-21
EPA 8260D
0.65
1.0
-
-
-
ND
ND
ND
ND
ND
3.2
-
ND
19-May-22
EPA 8260D
0.65
1.0
-
-
-
ND
ND
ND
2.8
ND
4.2
-
---
17-Nov-22
EPA 8260D
0.65
1.0
-
-
ND
ND
ND
ND
4.9
ND
4.3
-
---
6-Nov-23
EPA 8260D
0.65
1.0
-
-
-
ND
ND
1
5.7
ND
4.5
-
---
Chloromethane
18-Nov-09
0.11
1.0
-
ND
-
--
ND
ND
ND
0.45
1 ND
ND
NC 2L = 3 pg/L (01/01/10)
16-Jun-10
0.11
1.0
-
ND
-
---
0.14
J ND
ND
0.48
J ND
ND
1-Dec-10
0.11
1.0
-
ND
ND
--
ND
ND
ND
ND
ND
ND
1-Jun-11
0.11
1.0
-
ND
ND
---
ND
ND
ND
ND
ND
ND
20-Dec-11
0.11
1.0
-
-
ND
---
ND
ND
ND
ND
ND
ND
30-May-12
0.11
1.0
-
-
ND
---
ND
ND
ND
ND
ND
ND
5-Dec-12
0.11
1.0
-
-
ND
---
ND
ND
ND
ND
ND
ND
12-Jun-13
0.11
1.0
--
-
ND
---
ND
ND
ND
ND
ND
ND
28-Oct-13
0.11
1.0
--
-
ND
---
ND
ND
ND
ND
ND
ND
6-May-14
EPA 8260
0.11
1.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
22-Oct-14
EPA 8260
0.11
1.0
-
-
*
ND
ND
ND
ND
ND
ND
ND
21-May-15
EPA 8260
0.11
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Dec-15
EPA 8260
0.11
1.0
--
-
-
ND
ND
ND
ND
ND
ND
ND
3-May-16
EPA 8260
0.11
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
13-Dec-16
EPA 8260
0.11
1.0
-
-
-
ND
ND
ND
ND
ND
0.16
B ND
0.17 J
27-Jun-17
EPA 8260
0.11
1.0
--
-
-
ND
0.31
J 0.20
J 0.27
J 0.36
J 0.28
J 0.30 J
ND
13-Dec-18
EPA 8260
0.11
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
4-Jun-18
EPA 8260
0.11
1.0
--
-
-
ND
ND
ND
ND
ND
ND
ND
6-Dec-18
EPA 8260
0.11
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-19
EPA 8260D
0.38
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA8260D
0.39
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
8-May-20
EPA 8260D
0.39
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
11-Nov-20
EPA 8260D
0.39
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
5-May-21
EPA 8260D
0.54
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
EPA 8260D
0.54
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
EPA 8260D
0.54
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
---
17-Nov-22
EPA 8260D
0.54
1.0
-
-
ND
ND
ND
ND
ND
ND
ND
-
---
6-Nov-23
EPA 8260D
0.54
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
---
Chloroform
30-May-07
-
5.0
-
ND
-
-
0.92
B 1.2
B 0.99
B 1.4
B 1
B ND
NC 2L = 70 pg/L (10/23/07)
29-Nov-07
---
5.0
-
ND
-
-
ND
ND
ND
ND
ND
ND
29-May-08
0.14
5.0
-
ND
-
--
ND
ND
ND
ND
ND
ND
6-Nov-08
0.14
5.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
3-Jun-09
0.14
5.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
18-Nov-09
0.14
5.0
-
ND
-
--
ND
ND
ND
ND
ND
ND
16-Jun-10
0.14
5.0
-
ND
-
--
ND
ND
ND
0.2
B ND
ND
1-Dec-10
0.14
5.0
-
ND
ND
-
ND
ND
ND
ND
ND
ND
1-Jun-11
0.14
5.0
-
ND
ND
--
ND
ND
ND
0.36
B ND
ND
20-Dec-11
0.14
5.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
30-May-12
0.14
5.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
5-Dec-12
0.14
5.0
-
-
ND
--
ND
ND
ND
0.14
1 ND
ND
12-Jun-13
0.14
5.0
-
-
ND
---
ND
ND
ND
ND
ND
ND
28-Oct-13
0.14
5.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
6-May-14
EPA 8260
0.14
5.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
22-Oct-14
EPA 8260
0.14
5.0
-
-
*
ND
ND
ND
ND
ND
ND
ND
21-May-15
EPA 8260
0.14
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Dec-15
EPA 8260
0.14
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
3-May-16
EPA 8260
0.14
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
13-Dec-16
EPA 8260
0.14
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
27-1un-17
EPA 8260
0.14
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
-
13-Dec-18
EPA 8260
0.14
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
4-Jun-18
EPA 8260
0.14
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
6-Dec-18
EPA 8260
0.14
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-19
EPA 8260D
0.58
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA8260D
2.30
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
8-May-20
EPA8260D
2.30
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
11-Nov-20
EPA8260D
2.30
5.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
5-May-21
EPA8260D
1.60
5.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
EPA 8260D
0.43
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
EPA 8260D
0.43
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
-
17-Nov-22
EPA 8260D
0.43
1.0
-
-
ND
ND
ND
ND
ND
ND
ND
-
-
6-Nov-23
EPA8260D
0.43
1.0
-
--
-
ND
ND
ND
ND
ND
ND
-
-
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 16 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Sample
EPA
Analy[e
Collection Date
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-16D
Blanks
Dibromochloromethane
30-May-07
-
1.0
-
ND
---
---
1.7
ND
ND
ND
1.7
ND
Nov-07
-
3.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
May -OS
0.21
3.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
Nov -OS
0.21
3.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
Jun-09
0.21
3.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
Nov-09
0.21
3.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
NC 21 0.4 pg/L(01/01/10)
Jun-10
0.21
3.0
-
ND
-
--
ND
ND
ND
ND
ND
ND
Dec-10
0.21
3.0
-
ND
ND
---
ND
ND
ND
ND
ND
ND
Jun-11
0.21
3.0
-
ND
ND
---
ND
ND
ND
ND
ND
ND
Dec-11
0.21
3.0
-
-
ND
---
ND
ND
ND
ND
ND
ND
May-12
0.21
3.0
-
-
ND
---
ND
ND
ND
ND
ND
ND
5-Dec-12
0.21
3.0
-
-
ND
---
ND
ND
ND
ND
ND
ND
12-1un-13
0.21
3.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
28-Oct-13
0.21
3.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
6-May-14
EPA 8260
0.21
3.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
22-Oct-14
EPA 8260
0.21
3.0
-
-
*
ND
ND
ND
ND
ND
ND
ND
21-May-15
EPA 8260
0.21
3.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Dec-15
EPA 8260
0.21
3.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
3-May-16
EPA 8260
0.21
3.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
13-Dec-16
EPA 8260
0.21
3.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
27-1un-17
EPA 8260
0.21
3.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
-
13-Dec-18
EPA 8260
0.21
3.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
4-Jun-18
EPA 8260
0.21
3.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
6-Dec-18
EPA 8260
0.21
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-19
EPA 8260D
0.31
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA 8260D
0.41
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-20
EPA 8260D
0.41
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
II-Nov-20
EPA 8260D
0.41
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
5-May-21
EPA 8260D
0.36
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
EPA 8260D
0.36
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
EPA 8260D
0.36
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
-
17-Nov-22
EPA 8260D
0.36
1.0
-
-
ND
ND
ND
ND
ND
ND
ND
-
-
6-Nov-23
EPA 8260D
0.36
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
-
1,2-Dichlorobenzene
3-Jun-09
0.3
5.0
-
ND
-
--
ND
ND
ND
0.4
1 ND
ND
NC 21 = 24 pg/L(10/23/07)
18-Nov-09
0.3
5.0
-
ND
-
-
ND
ND
ND
0.4
J ND
ND
NC 21 = 20 Ng/L(01/01/10)
16-Jun-10
0.3
5.0
-
ND
-
-
ND
0.39
J ND
0.4
J ND
ND
1-Dec-10
0.3
5.0
-
ND
ND
--
ND
0.49
J ND
0.5
1 ND
ND
1-Jun-11
0.3
5.0
-
ND
ND
--
ND
0.5
J ND
0.5
1 ND
ND
20-Dec-11
0.3
5.0
-
-
ND
--
ND
0.4
1 ND
ND
ND
ND
30-May-12
0.3
5.0
-
-
ND
-
ND
0.4
J ND
0.6
J ND
ND
5-Dec-12
0.3
5.0
--
-
ND
-
ND
0.4
J ND
0.6
J ND
ND
12-Jun-13
0.3
5.0
-
-
ND
--
ND
0.4
J ND
0.6
J ND
ND
28-Oct-13
0.3
5.0
-
-
ND
---
ND
0.39
1 ND
0.54
J ND
ND
6-May-14
EPA 8260
0.3
5.0
-
-
ND
-
ND
0.46
J ND
0.55
J ND
ND
22-Oct-14
EPA 8260
0.3
5.0
--
-
*
ND
ND
0.45
J ND
ND
ND
ND
21-May-15
EPA 8260
0.3
5.0
-
-
-
ND
ND
0.45
J ND
0.58
J ND
ND
8-Dec-15
EPA 8260
0.3
5.0
-
-
-
ND
ND
0.39
J ND
0.45
J ND
ND
3-May-16
EPA 8260
0.3
5.0
-
-
-
ND
ND
0.42
J ND
0.54
J ND
ND
ND
13-Dec-16
EPA 8260
0.3
5.0
-
-
-
ND
ND
0.32
J ND
0.67
J ND
ND
ND
27-Jun-17
EPA 8260
0.3
5.0
-
-
-
ND
ND
0.31
J ND
0.80
J ND
ND
---
13-Dec-18
EPA 8260
0.3
5.0
-
-
-
ND
ND
0.40
J ND
0.79
J ND
ND
4-Jun-18
EPA 8260
0.3
5.0
-
-
-
ND
ND
0.35
J ND
0.66
J ND
ND
6-Dec-18
EPA 8260
0.3
1.0
-
-
-
ND
ND
0.37
J ND
0.84
J ND
ND
8-May-19
EPA 8260D
0.49
1.0
-
-
-
ND
ND
ND
ND
0.96
J ND
ND
8-Nov-19
EPA8260D
0.29
1.0
-
-
-
ND
ND
ND
ND
0.65
J ND
ND
8-May-20
EPA8260D
0.29
1.0
-
-
-
ND
ND
0.37
J ND
0.82
J ND
ND
ND
II-Nov-20
EPA 8260D
0.29
1.0
-
-
-
ND
ND
0.34
J ND
0.76
J 0.33 J
-
ND
5-May-21
EPA 8260D
0.34
1.0
-
-
-
ND
ND
0.34
J ND
0.66
J ND
-
ND
3-Nov-21
EPA 8260D
0.34
1.0
-
-
-
ND
ND
ND
ND
0.66
J ND
-
ND
19-May-22
EPA 8260D
0.34
1.0
-
-
-
ND
ND
ND
ND
0.69
J ND
-
---
17-Nov-22
EPA 8260D
0.34
1.0
-
-
ND
ND
ND
ND
ND
0.63
J ND
-
---
6-Nov-23
EPA 8260D
0.34
1.0
-
-
-
ND
ND
0.34
J ND
0.77
J ND
-
---
1,4-Dichlorobenzene
1-Sep-94
-
5.0
ND
NI
NI
NI
ND
6.5
ND
ND
NI
NI
1-Oct-94
-
5.0
-
NI
NI
NI
--
8
-
-
NI
NI
1-Jan-95
-
5.0
-
NI
NI
NI
ND
ND
ND
ND
NI
NI
1-Feb-95
-
5.0
-
NI
NI
NI
ND
9.8
ND
ND
NI
NI
1-Mar-95
-
5.0
ND
NI
NI
NI
ND
12.0
ND
ND
NI
NI
1-Aug-95
-
5.0
ND
NI
-
-
ND
14.0
ND
ND
NI
NI
1-Jan-96
-
5.0
-
NI
-
-
ND
20
ND
ND
NI
NI
1-Feb-96
-
5.0
-
NI
-
-
ND
19.0
ND
ND
NI
NI
1-May-96
--
5.0
-
NI
-
--
ND
18
ND
ND
NI
NI
1-Oct-96
-
5.0
-
NI
-
---
ND
16.0
ND
ND
NI
NI
1-May-97
--
5.0
ND
NI
-
---
ND
14.0
ND
ND
NI
NI
1-Nov-97
--
1.0
ND
NI
-
---
ND
ND
ND
ND
NI
NI
1-May-98
--
5.0
ND
NI
-
---
ND
ND
ND
ND
NI
NI
24-Nov-98
--
2.0
ND
NI
-
---
ND
4
ND
ND
NI
NI
10-May-99
--
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
18-Oct-99
--
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
3-May-00
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
7-Nov-00
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
31-May-01
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
7-Nov-01
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
22-May-02
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
14-Nov-02
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
14-May-03
---
5.0
ND
ND
-
---
ND
7.2
ND
ND
6.5
ND
20-Nov-03
---
5.0
ND
ND
-
---
ND
12
ND
ND
5.7
ND
6-May-04
---
5.0
ND
ND
-
---
ND
14
ND
ND
5.2
ND
10-Nov-04
---
5.0
ND
ND
-
---
ND
17
ND
ND
6.7
ND
27-May-05
---
5.0
ND
ND
-
---
ND
20.0
ND
ND
6.0
ND
3-Nov-05
---
5.0
-
ND
-
---
ND
21
ND
ND
6.0
ND
25-May-06
---
5.0
-
ND
-
---
ND
16.5
ND
ND
5.4
ND
2-Nov-06
---
5.0
-
ND
-
---
ND
16
ND
ND
7.2
ND
30-May-07
---
1.0
-
ND
-
---
ND
23.0
5.2
4.4
7.2
ND
NC 21 1.4 pg/L (10/23/07)
29-Nov-07
-
1.0
-
ND
-
--
ND
11
2.3
4.5
5.2
ND
29-May-08
0.33
1.0
-
ND
-
---
ND
13.5
3.1
5.2
6.0
ND
6-Nov-08
0.33
1.0
-
ND
-
---
ND
9.7
Q 3.7
4.3
5.5
ND
3-Jun-09
0.33
1.0
-
ND
-
---
ND
14.3
4.2
7.3
8.0
ND
18-Nov-09
0.33
1.0
-
ND
-
---
ND
12.2
4.5
6.4
6.8
ND
NC 21 6 pg/L (01/01/10)
16-Jun-10
0.33
1.0
-
ND
-
--
ND
19.8
4.7
6.8
5.7
ND
1-Dec-10
0.33
1.0
-
ND
ND
---
0.43
J 18.5
3.5
7.5
7.5
ND
1-Jun-11
0.33
1.0
-
ND
ND
--
ND
19.2
4.5
8.4
3.4
ND
20-Dec-11
0.33
1.0
-
-
ND
--
0.37
J 13.9
4
7.8
D 6.5
ND
30-May-12
0.33
1.0
-
-
ND
--
ND
16.4
4.2
9.9
7.0
ND
5-Dec-12
0.33
1.0
-
-
ND
---
ND
15
4.4
9.7
6.0
ND
12-1un-13
0.33
1.0
-
-
ND
---
0.48
J 12.4
4.9
9.7
7.5
ND
28-Oct-13
0.33
1.0
--
--
0.63 1
---
0.45
J 16.7
5
10.1
8.3
ND
6-May-14
EPA 8260
0.33
1.0
-
-
ND
-
0.63
1 18
5.2
12.3
8.9
ND
22-Oct-14
EPA 8260
0.33
1.0
--
--
*
ND
0.73
J 16.1
4.8
11.9
7.5
ND
21-May-15
EPA 8260
0.33
1.0
-
-
-
ND
0.70
J 17.1
5.0
12.0
7.1
ND
S-Dec-15
EPA 8260
0.33
1.0
--
--
-
ND
0.98
J 12.6
4.8
13.2
9.1
ND
3-May-16
EPA 8260
0.33
1.0
-
-
-
ND
0.93
J 14.2
6.0
15.0
6.6
ND
ND
13-Dec-16
EPA 8260
0.33
1.0
--
--
-
ND
0.89
1 10.5
4.7
13.9
7.2
ND
ND
27-Jun-17
EPA 8260
0.33
1.0
--
--
-
ND
ND
10.6
ND
16.0
ND
ND
---
13-Dec-18
EPA 8260
0.33
1.0
--
--
-
ND
0.81
J 13.1
4.1
14.9
7.0
ND
4-Jun-18
EPA 8260
0.33
1.0
-
-
-
ND
0.63
1 11.5
5.6
15.7
7.9
ND
6-Dec-18
EPA 8260
0.33
1.0
-
-
-
ND
0.74
J 12.1
ND
17.3
8.7
ND
8-May-19
EPA 8260D
0.58
1.0
-
-
-
ND
1.1
15.4
7.8
22.0
10.1
ND
8-Nov-19
EPA8260D
0.26
1.0
ND
0.99
1 4.8
5.0
16.0
7.3
ND
8-May-20
EPA8260D
0.26
1.0
-
-
-
ND
0.84
J 12.3
5.0
15.9
7.3
ND
ND
11-Nov-20
EPA 8260D
0.26
1.0
-
-
-
ND
1.1
15.5
6.8
18.8
10.4
-
ND
5-May-21
EPA8260D
0.33
1.0
-
-
-
ND
ND
11.3
4.9
15.1
7.1
-
ND
3-Nov-21
EPA 8260D
0.33
1.0
-
-
-
ND
ND
ND
ND
16.6
8.6
-
ND
19-May-22
EPA 8260D
0.33
1.0
-
-
-
ND
ND
ND
ND
17.3
ND
-
---
17-Nov-22
EPA8260D
0.33
1.0
-
-
ND
ND
1.3
10.9
5.5
15.6
7.6
-
---
6-Nov-23
EPA8260D
0.33
1.0
-
-
-
ND
1.2
11.9
5.4
20.9
7.8
--
---
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 17 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-16D
Blanks
Dichlorodifluoromethane
1-Aug-95
---
5.0
ND
NI
---
---
ND
26
ND
22
NI
NI
#
1-Jan-96
---
5.0
---
NI
---
---
ND
ND
ND
ND
NI
NI
1-Feb-96
---
10.0
---
NI
---
---
ND
ND
ND
ND
NI
NI
1-May-96
---
10.0
---
NI
--
---
ND
35
25
ND
NI
NI
1-Oct-96
---
5.0
-
NI
-
---
ND
ND
ND
ND
NI
NI
1-May-97
---
5.0
6.4
NI
-
---
ND
16
20.0
42.0
NI
NI
1-Nov-97
---
5.0
14
NI
-
---
ND
ND
31.0
90.0
NI
NI
24-Nov-98
--
2.0
ND
NI
-
---
ND
ND
ND
ND
NI
NI
10-May-99
--
10.0
ND
ND
-
---
ND
ND
19.0
27.0
ND
ND
18-Oct-99
--
5.0
ND
ND
-
---
-
14.0
50.0
130.0
25
ND
3-May-00
--
5.0
-
-
-
---
--
ND
16.00
36.0
8.9
---
7-Nov-00
--
5.0
ND
-
-
---
ND
ND
9.40
30.0
7.9
---
31-May-01
--
5.0
ND
-
-
---
ND
ND
13
25
6.2
---
7-Nov-01
--
5.0
ND
-
--
---
ND
5.5
ND
34
12
-
22-May-02
--
5.0
ND
-
---
---
ND
5
15
24
11
-
14-Nov-02
--
5.0
ND
-
---
---
ND
ND
ND
20
ND
--
14-May-03
--
5.0
ND
-
---
---
ND
ND
8.7
12
ND
-
20-Nov-03
--
5.0
ND
ND
---
---
ND
ND
6.3
10
ND
ND
6-May-04
-
5.0
ND
-
-
---
ND
ND
ND
9.2
ND
-
10-Nov-04
-
5.0
ND
-
-
---
ND
ND
7.6
10
ND
ND
27-May-05
-
5.0
ND
-
-
---
ND
ND
14
22
ND
-
3-Nov-05
-
5.0
-
ND
-
---
ND
ND
9
12
ND
ND
25-May-06
-
5.0
-
-
-
---
ND
ND
ND
5.4
ND
-
2-Nov-06
-
5.0
-
ND
-
---
ND
ND
8.2
6.6
ND
ND
30-May-07
-
5.0
-
-
-
---
ND
ND
7.1
7.6
ND
NC 2L 1,400 pg/L(10/23/07)
29-Nov-07
-
5.0
-
ND
-
--
ND
ND
1.1
J 1.8
JD ND
ND
29-May-08
0.21
1.0
-
-
-
---
ND
0.35
J 2.9
3.6
ND
-
6-Nov-08
0.21
5.0
-
0.62
J -
---
ND
0.33
J 1.9
1 2.2
1 0.69
J ND
3-Jun-09
0.21
5.0
-
0.45
J -
---
0.96
1 ND
2.5
1 1.9
1 0.72
1 ND
18-Nov-09
0.21
5.0
-
ND
-
---
ND
ND
1.2
1 1.9
1 0.47
1 ND
NC 2L = 1,000 pg/L (01/01/10)
16-1un-10
0.21
5.0
-
ND
-
--
ND
ND
0.81
1 1.4
1 ND
ND
1-Dec-10
0.21
5.0
-
0.26
J ND
---
ND
ND
0.69
J 1.1
1 0.55
J ND
1-Jun-11
0.21
5.0
-
0.42
J ND
---
ND
ND
ND
1.2
1 ND
ND
20-Dec-11
0.21
5.0
-
-
ND
-
ND
ND
ND
0.76
J ND
ND
30-May-12
0.21
5.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
5-Dec-12
0.21
5.0
-
-
ND
-
ND
ND
ND
ND
ND
-
12-Jun-13
0.21
5.0
-
-
ND
-
0.34
1 ND
ND
ND
ND
ND
28-Oct-13
0.21
5.0
-
-
ND
-
ND
ND
ND
1.1
1 ND
ND
6-May-14
EPA 8260
0.21
5.0
-
-
ND
-
ND
ND
ND
ND
ND
-
22-Oct-14
EPA 8260
0.21
5.0
-
-
*
ND
ND
ND
ND
ND
ND
-
21-May-15
EPA 8260
0.21
5.0
-
-
-
ND
ND
ND
ND
ND
ND
-
8-Dec-15
EPA 8260
0.21
5.0
-
-
-
ND
ND
ND
ND
ND
ND
-
3-May-16
EPA 8260
0.21
5.0
-
-
-
ND
ND
ND
ND
0.54
J 0.26
1 -
ND
13-Dec-16
EPA 8260
0.21
5.0
-
-
-
ND
ND
ND
ND
0.57
J ND
-
ND
27-Jun-17
EPA 8260
0.21
5.0
-
-
-
ND
ND
ND
ND
0.64
J ND
-
-
13-Dec-18
EPA 8260
0.21
5.0
-
-
-
ND
ND
ND
ND
0.30
J ND
-
4-Jun-18
EPA 8260
0.21
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
6-Dec-18
EPA 8260
0.21
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-19
EPA8260D
0.48
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
8-Nov-19
EPA8260D
0.23
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
8-May-20
EPA8260D
0.23
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
11-Nov-20
EPA8260D
0.23
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
5-May-21
EPA8260D
0.35
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
EPA8260D
0.35
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
EPA8260D
0.35
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
-
17-Nov-22
EPA8260D
0.56
1.0
-
-
ND
ND
ND
ND
ND
ND
ND
-
-
6-Nov-23
EPA8260D
0.35
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
--
1,1-Dichloroethane
1Sep-94
-
5.0
ND
NI
NI
NI
ND
50
7.5
ND
NI
NI
1-Jan-95
-
5.0
-
NI
NI
NI
ND
35
33
ND
NI
NI
1-Feb-95
-
5.0
-
NI
NI
NI
ND
66
34
ND
NI
NI
1-Mar-95
-
5.0
ND
NI
NI
NI
ND
72
34
ND
NI
NI
1-Aug-95
-
5.0
ND
NI
-
-
ND
96
ND
ND
NI
NI
1-Jan-96
-
5.0
-
NI
-
-
13
120
54
ND
NI
NI
1-Feb-96
-
5.0
-
NI
-
-
11
ND
ND
ND
NI
NI
1-May-96
-
5.0
-
NI
-
-
12
110
68
ND
NI
NI
1-Oct-96
-
5.0
-
NI
-
-
17
140
86
ND
NI
NI
1-May-97
-
5.0
ND
NI
-
-
39
170
100
4
1 NI
NI
1-Nov-97
-
1.0
2
NI
-
-
22
200
69.0
8
NI
NI
1-May-98
-
5.0
5.5
NI
-
-
22.0
250
250
45.0
NI
NI
24-Nov-98
-
2.0
3.8
NI
-
-
14
150
57
19.9
NI
NI
10-May-99
-
5.0
7.7
ND
-
-
9.7
180
64.0
30.0
120
ND
18-Oct-99
-
5.0
11.0 1
ND
-
-
9.3
J 200
59
30.0
120
ND
3-May-00
-
5.0
9.3 1
ND
-
-
6.2
J 120
61.0
38.0
120
ND
7-Nov-00
-
5.0
9.5
ND
-
-
5.0
110
60.0
44.0
92
ND
31-May-01
-
5.0
7.9
6
-
-
ND
80.0
75.0
45.0
79
ND
7-Nov-01
-
5.0
14.0
5.3
-
-
ND
84.0
100
42.0
95
ND
22-May-02
-
5.0
19.0
ND
-
-
ND
75.0
110
57
100
ND
14-Nov-02
-
5.0
21.0
ND
-
-
ND
41.0
90.0
50.0
82
ND
14-May-03
-
5.0
27.0
ND
-
-
ND
48.0
60.0
69.0
82
ND
20-Nov-03
-
5.0
25.0
ND
-
-
ND
34.0
48.0
62.0
59
ND
6-May-04
-
5.0
33.0
ND
-
-
ND
33
58.0
72.0
58
ND
10-Nov-04
-
5.0
38.0
ND
-
-
ND
22.0
37.0
50.0
42
ND
27-May-05
-
5.0
68.0
ND
-
-
ND
25
48
66
44.0
ND
3-Nov-05
-
5.0
-
ND
-
-
ND
18.0
34
54.0
38
ND
25-May-06
-
5.0
-
ND
-
-
ND
10.9
27
37.6
25.3
ND
2-Nov-06
-
5.0
-
ND
-
-
ND
12
34
47
33
ND
30-May-07
-
5.0
-
5.3
-
-
3.3
J 16
48
59
41
ND
NC 2L = 70 pg/L (10/23/07)
29-Nov-07
-
5.0
-
6.1
-
-
2.2
J 7.7
39
44
34
ND
29-May-08
0.32
5.0
-
1.7
1 -
-
1.7
J 8.7
38.8
ND
29.7
ND
6-Nov-08
0.32
5.0
-
5.7
-
-
1.9
J 8.1
34.6
52.3
26.2
ND
3-Jun-09
0.32
5.0
-
6.3
-
-
1.3
J 8.2
47.8
53.1
32
ND
18-Nov-09
0.32
5.0
-
10.8
-
-
1.2
J 6.7
41.9
52.0
29.4
ND
NC 2L = 6 pg/L (01/01/10)
16-Jun-10
0.32
5.0
-
3.9
J -
-
1.2
J 5.7
35.7
43.1
32.1
ND
1-Dec-10
0.32
5.0
-
6.8
ND
-
1.7
1 5.4
41.3
37.9
16.9
ND
1-Jun-11
0.32
5.0
-
9.3
ND
-
2
1 6.8
45.5
53.3
19.1
ND
20-Dec-11
0.32
5.0
-
-
ND
-
1.9
1 5.1
39.7
39.7
26.2
ND
30-May-12
0.32
5.0
-
-
ND
-
1.5
1 5.9
38.2
45.8
24.1
ND
5-Dec-12
0.32
5.0
-
-
ND
-
1.7
1 4.6
1 39.3
39.3
26.5
ND
12-Jun-13
0.32
5.0
-
-
ND
-
0.73
1 5.3
37.1
41.6
21.4
ND
28-Oct-13
0.32
5.0
-
-
ND
-
1
1 4.9
1 43.2
41.8
26.2
ND
6-May-14
EPA 8260
0.32
5.0
-
-
ND
-
1
1 4
1 43.4
39.5
21.5
ND
22-Oct-14
EPA 8260
0.32
5.0
-
-
*
ND
1.3
1 3.6
1 34.4
33.2
25.3
ND
21-May-15
EPA 8260
0.32
5.0
-
-
-
ND
0.75
1 2.8
1 26.7
23.1
17.3
ND
8-Dec-15
EPA 8260
0.32
5.0
-
-
-
ND
0.95
1 3.2
1 31.7
33.7
10.3
ND
3-May-16
EPA 8260
0.32
5.0
-
-
-
ND
1.3
1 3.4
1 23.4
28.4
14.8
ND
ND
13-Dec-16
EPA 8260
0.32
5.0
-
-
-
ND
1.4
1 3.0
1 27.4
26.4
22.1
ND
ND
27-Jun-17
EPA 8260
0.32
5.0
-
-
-
ND
0.78
1 3.3
1 26.8
24.2
17.8
ND
-
13-Dec-18
EPA 8260
0.32
5.0
-
-
-
ND
0.74
1 2.6
1 24.7
19.5
14.1
ND
4-Jun-18
EPA 8260
0.32
5.0
-
-
-
ND
0.44
1 2.2
1 19.9
16.6
12.4
ND
6-Dec-18
EPA 8260
0.32
1.0
-
-
-
ND
ND
2.4
25.3
19.8
14.4
ND
8-May-19
EPA8260D
0.41
1.0
-
-
-
ND
0.65
1 2.7
27.3
19.3
16.9
ND
8-Nov-19
EPA8260D
0.27
1.0
ND
0.72
1 2.0
24.0
15.1
7.4
ND
8-May-20
EPA8260D
0.27
1.0
-
-
-
ND
0.58
1 1.7
18.3
14.3
7.8
ND
ND
11-Nov-20
EPA8260D
0.27
1.0
-
-
-
ND
0.66
1 1.9
18.8
14.6
6.4
-
ND
5-May-21
EPA8260D
0.37
1.0
-
-
-
ND
0.53
1 2.0
18.9
13.4
8.6
-
ND
3-Nov-21
EPA8260D
0.37
1.0
-
-
-
ND
0.84
1 1.7
18.0
12.6
6.1
-
ND
19-May-22
EPA 8260D
0.37
1.0
-
-
-
ND
0.6
1 1.5
16
11.7
4.4
-
-
17-Nov-22
EPA 8260D
0.37
1.0
-
-
ND
ND
0.41
1 1.7
17.1
9.6
9
-
-
6-Nov-23
EPA 8260D
0.37
1.0
-
-
-
ND
ND
2.0
18.2
10.3
11.9
-
-
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 18 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Analy[e
Sample
Collection Date
EPA
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-16D
Blanks
1,2-Dichloroethane
3-Nov-05
--
5.0
ND
ND
13
ND
ND
ND
ND
25-May-06
--
5.0
---
ND
---
---
ND
ND
ND
ND
ND
ND
2-Nov-06
--
5.0
---
ND
-
---
ND
ND
ND
ND
ND
ND
30-May-07
--
1.0
---
ND
-
---
ND
2.4
ND
1.6
ND
ND
INC 2L = 0.38 pg/L (10/23/07)
29-Nov-07
--
1.0
-
ND
-
--
ND
ND
ND
ND
ND
ND
29-May-08
0.12
1.0
-
ND
-
---
ND
1.2
0.64
1 1.5
1.1
ND
6-Nov-08
0.12
1.0
-
ND
-
---
ND
0.65
B 0.27
B 1.8
B 0.46
B ND
3-Jun-09
0.12
1.0
-
ND
-
---
ND
0.78
J 0.8
1 1.9
0.98
J ND
1&Nov-09
0.12
1.0
-
ND
-
---
ND
0.98
1 1.0
1.8
0.97
1 ND
INC 2L = 0.4 pg/L (01/01/10)
16-1un-10
0.12
1.0
-
ND
-
--
ND
1.2
1.1
1.8
1.0
ND
1-Dec-10
0.12
1.0
-
ND
ND
---
ND
0.94
1 0.58
1 1.5
0.18
1 ND
1-Jun-11
0.12
1.0
-
ND
ND
---
ND
ND
1.1
2.1
1.0
ND
20-Dec-11
0.12
1.0
-
-
ND
---
ND
0.8
1 0.92
1 1.8
1 1.0
ND
30-May-12
0.12
1.0
-
-
ND
--
ND
0.75
J 0.97
1 2
1
ND
5-Dec-12
0.12
1.0
-
-
ND
-
ND
0.7
1 0.8
1 1.7
1.3
ND
12-Jun-13
0.12
1.0
-
-
ND
--
ND
0.6
1 1.3
1.7
1.0
ND
28-Oct-13
0.12
1.0
-
-
ND
--
ND
0.9
1 1.4
1.7
1.4
ND
6-May-14
EPA 8260
0.12
1.0
-
-
ND
-
ND
0.8
1 1.2
1.6
1.2
ND
22-Oct-14
EPA 8260
0.12
1.0
--
--
*
ND
ND
0.51
J 0.85
J 1.5
1.2
ND
21-May-15
EPA 8260
0.12
1.0
-
-
-
ND
ND
ND
0.71
J ND
ND
ND
8-Dec-15
EPA 8260
0.24
1.0
--
--
-
ND
ND
0.65
J ND
1.3
1.3
ND
3-May-16
EPA 8260
0.24
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
13-Dec-16
EPA 8260
0.24
1.0
--
-
-
ND
ND
0.48
J 1.1
1.3
1.2
ND
ND
27-Jun-17
EPA 8260
0.24
1.0
--
-
-
ND
ND
0.26
J 0.88
J 1.3
1.0
J ND
---
13-Dec-18
EPA 8260
0.24
1.0
--
-
-
ND
ND
ND
0.25
J 0.62
J 0.46
1 ND
4-Jun-18
EPA 8260
0.24
1.0
-
-
-
ND
ND
0.43
J 1.3
1.0
1.0
ND
6-Dec-18
EPA 8260
0.24
1.0
-
-
-
ND
ND
0.42
J 1.1
1.2
1.4
ND
8-May-19
EPA 8260D
0.67
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA 8260D
0.34
1.0
-
-
-
ND
ND
0.42
J 1.2
1.1
0.81
J ND
8-May-20
EPA 8260D
0.34
1.0
-
-
-
ND
ND
0.39
J 1.0
1.1
0.93
J ND
ND
11-Nov-20
EPA 8260D
0.34
1.0
-
-
-
ND
ND
0.50
J 1.3
1.2
1.1
-
ND
Resample>
27-Jan-21
EPA 8260D
0.34
1.0
-
-
-
-
-
-
1.0
-
-
-
-
5-May-21
EPA 8260D
0.32
1.0
-
-
-
ND
ND
ND
1.3
0.84
1 0.93
1 -
ND
3-Nov-21
EPA 8260D
0.32
1.0
-
-
-
ND
ND
ND
0.89
J 0.90
0.67
J -
ND
19-May-22
EPA 8260D
0.32
1.0
-
-
-
ND
ND
ND
0.9
J 0.89
J 0.89
J -
-
17-Nov-22
EPA 8260D
0.32
1.0
-
-
ND
ND
ND
ND
0.96
J 0.69
J L10
-
--
6-Nov-23
EPA 8260D
0.32
1.0
-
-
-
ND
ND
ND
0.97
J 0.65
J LOO
--
---
1,1-Dichloroethene
1-May-97
-
5.0
ND
NI
-
-
ND
3
1 ND
4
1 NI
NI
1-Nov-97
---
1.0
ND
NI
-
--
ND
ND
ND
ND
NI
NI
1-May-98
---
5.0
ND
NI
---
---
ND
ND
ND
ND
NI
NI
24-Nov-98
---
2.0
ND
NI
---
---
ND
ND
ND
ND
NI
NI
10-May-99
---
5.0
ND
ND
---
---
ND
ND
ND
ND
ND
ND
18-Oct-99
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
3-May-00
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
7-Nov-00
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
31-May-01
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
7-Nov-01
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
22-May-02
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
14-Nov-02
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
14-May-03
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
20-Nov-03
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
6-May-04
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
10-Nov-04
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
27-May-05
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
3-Nov-05
---
5.0
--
ND
-
---
ND
ND
ND
ND
ND
ND
25-May-06
---
5.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
2-Nov-06
---
5.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
30-May-07
--
5.0
-
ND
-
---
ND
ND
0.93
1 1.8
1 0.42
1 ND
INC 2L= 7 pg/L(10/23/07)
29-Nov-07
-
5.0
-
ND
-
--
ND
ND
0.80
J 1.2
JD 0.59
J ND
29-May-08
0.6
1.0
-
ND
-
---
ND
ND
0.75
1 1.3
ND
ND
6-Nov-08
0.6
5.0
-
ND
-
---
ND
ND
0.64
1 1.1
1 ND
ND
3-Jun-09
0.6
5.0
-
ND
-
---
ND
ND
0.95
1 1.1
1 ND
ND
16-Nov-09
0.6
5.0
-
ND
-
---
ND
ND
0.78
1 1.1
1 ND
ND
16-Jun-10
0.6
5.0
-
ND
-
---
0.98 J
ND
0.68
J 1.2
1 ND
ND
1-Dec-10
0.6
5.0
-
ND
ND
--
ND
ND
ND
ND
ND
ND
1-Jun-11
0.6
5.0
-
ND
ND
--
ND
ND
0.68
1 0.82
1 ND
ND
20-Dec-11
0.6
5.0
-
-
ND
--
ND
ND
0.59
J ND
ND
ND
30-May-12
0.6
5.0
-
-
ND
--
ND
ND
0.62
J 0.58
J ND
ND
5-Dec-12
0.6
5.0
-
-
ND
--
ND
ND
0.66
J 0.58
J ND
ND
INC 2L = 350 pg/L (04/01/2013)
12-1un-13
0.6
5.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
28-Oct-13
0.6
5.0
-
-
ND
-
ND
ND
0.60
J ND
ND
ND
6-May-14
EPA 8260
0.6
5.0
-
-
ND
-
ND
ND
0.59
J ND
ND
ND
22-Oct-14
EPA 8260
0.6
5.0
-
-
*
ND
ND
ND
ND
ND
ND
ND
21-May-15
EPA 8260
0.6
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Dec-15
EPA 8260
0.6
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
3-May-16
EPA 8260
0.6
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
13-Dec-16
EPA 8260
0.6
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
27-Jun-17
EPA 8260
0.6
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
---
13-Dec-18
EPA 8260
0.6
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
4-Jun-18
EPA 8260
0.6
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
6-Dec-18
EPA 8260
0.6
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-19
EPA 8260D
0.72
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA 8260D
0.24
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-20
EPA 8260D
0.24
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
11-Nov-20
EPA 8260D
0.24
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
5-May-21
EPA 8260D
0.35
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
EPA 8260D
0.35
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
EPA 8260D
0.35
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
---
17-Nov-22
EPA 8260D
0.35
1.0
-
-
ND
ND
ND
ND
ND
ND
ND
-
---
6-Nov-23
EPA 8260D
0.35
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
---
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 19 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Sample
EPA
Analyte
Collection Date
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW10
MW-11
MW-12
MW-13
MW-16S
MW-16D
Blanks
cis-1,2-Dichloroethene
1-Feb-96
---
5.0
---
NI
---
---
11
89
35
ND
NI
NI
1-May-96
---
5.0
---
NI
---
---
ND
ND
ND
ND
NI
NI
1-Oct-96
---
5.0
-
NI
---
---
ND
ND
ND
ND
NI
NI
1-May-97
---
5.0
ND
NI
---
---
ND
2.1
J ND
ND
NI
NI
1-Nov-97
---
1.0
ND
NI
-
---
ND
ND
ND
ND
NI
NI
1-May-98
---
5.0
ND
NI
-
---
ND
ND
ND
ND
NI
NI
24-Nov-98
---
2.0
ND
NI
-
---
ND
2.8
ND
ND
NI
NI
10-May-99
---
5.0
ND
ND
-
---
ND
ND
ND
ND
7
ND
18-Oct-99
---
5.0
ND
ND
-
---
ND
6.3
ND
ND
14
ND
3-May-00
---
5.0
ND
ND
-
---
ND
ND
ND
ND
13
ND
7-Nov-00
---
5.0
ND
ND
-
---
ND
ND
ND
ND
13
ND
31-May-01
---
5.0
ND
ND
-
---
ND
ND
ND
ND
14
ND
7-Nov-01
---
5.0
ND
ND
-
---
ND
5.9
6.5
ND
18
ND
22-May-02
---
5.0
ND
ND
-
---
ND
8
11
ND
24
ND
14-Nov-02
---
5.0
ND
ND
-
---
5
7
13.0
ND
28
ND
14-May-03
---
5.0
ND
ND
-
---
7
11
8
5
36
ND
20-Nov-03
---
5.0
ND
ND
-
---
5
14
13
6
27
ND
6-May-04
---
5.0
ND
ND
-
---
ND
16
17
7.2
32
ND
10-Nov-04
---
5.0
ND
ND
-
---
ND
14
13
5.8
29
ND
27-May-05
---
5.0
ND
ND
-
---
ND
16
23
8
23
ND
3-Nov-05
---
5.0
-
ND
-
---
ND
5
6
ND
9
ND
25-May-06
---
5.0
-
ND
-
---
ND
8.2
9.3
5.2
7.7
ND
2-Nov-06
--
5.0
-
ND
-
---
ND
16
12.0
12
17
ND
30-May-07
-
5.0
-
ND
-
---
4.9
1 20
21.0
17
15
ND
NC 21 70 pg/L (10/23/07)
29-Nov-07
-
5.0
-
ND
-
--
2.9
J 8.6
7.2
13
9.1
ND
29-May-08
0.19
5.0
-
ND
-
---
2.8
1 13.4
10.9
18.4
10.4
ND
6-Nov-08
0.19
5.0
-
0.5
1 -
---
2.8
1 12.7
10
20.4
7.6
ND
3-Jun-09
0.19
5.0
-
0.71
1 -
---
2.5
1 13.1
11.9
25.3
10.4
ND
18-Nov-09
0.19
5.0
-
2.8
B -
--
2.5
B 12.2
B 20
25.9
10.8
B ND
16-1un-10
0.19
5.0
-
1.7
1 -
---
2.3
1 14.8
15.6
22.2
9.7
ND
1-Dec-10
0.19
5.0
-
0.66
1 ND
---
3.1
1 11.3
9.2
19.7
7.1
ND
1-Jun-11
0.19
5.0
-
0.89
1 ND
--
3.7
1 14.5
13.8
28.8
5.7
ND
20-Dec-11
0.19
5.0
-
-
ND
--
3.7
1 9.5
9.7
21.4
D 6.5
ND
30-May-12
0.19
5.0
-
-
ND
--
3.1
1 11.8
11.2
26.5
6.8
ND
5-Dec-12
0.19
5.0
-
-
ND
---
3.3
1 9.1
9.4
25.4
6.6
ND
12-1un-13
0.19
5.0
-
-
ND
--
2.5
1 9
12.8
26.2
6.2
ND
28-Oct-13
0.19
5.0
--
-
ND
-
3
J 11.2
14
29.1
7.7
ND
6-May-14
EPA 8260
0.19
5.0
-
-
ND
-
3.4
J 9.5
13
27.1
7.7
ND
22-Oct-14
EPA 8260
0.19
5.0
--
-
*
ND
4.3
J 8.0
10.1
25
7.1
ND
21-May-15
EPA 8260
0.19
5.0
-
-
-
ND
2.8
J 6.7
7.6
17.0
4.2
J ND
8-Dec-15
EPA 8260
0.19
5.0
--
-
-
ND
3.9
J 6.9
9.9
25.8
4.4
J ND
3-May-16
EPA 8260
0.19
5.0
-
-
-
ND
4.3
J 5.9
9.6
23.9
4.6
J ND
ND
13-Dec-16
EPA 8260
0.19
5.0
--
--
-
ND
5.1
5.7
9.8
25.7
6.1
ND
ND
27-Jun-17
EPA 8260
0.19
5.0
--
--
-
ND
3.5
J 5.8
9.0
23.3
5.4
ND
---
13-Dec-18
EPA 8260
0.19
5.0
--
-
-
ND
3.4
J 4.9
J 9.0
22.1
4.7
J ND
4-Jun-18
EPA 8260
0.19
5.0
--
-
-
ND
2
J 3.8
J 7.9
19.9
4.6
J ND
6-Dec-18
EPA 8260
0.19
1.0
--
-
-
ND
ND
4.2
9.5
24.1
6.3
ND
8-May-19
EPA 8260D
0.66
1.0
-
-
-
ND
3.4
5.9
14.1
30.3
8.5
ND
8-Nov-19
EPA 8260D
0.29
1.0
ND
3.3
3.6
9.9
20.3
3.9
ND
8-May-20
EPA 8260D
0.29
1.0
-
-
-
ND
2.5
3.5
8.4
19.6
4.8
ND
ND
11-Nov-20
EPA8260D
0.29
1.0
-
-
-
ND
2.7
4.0
8.8
19.9
5.1
-
ND
5-May-21
EPA 8260D
0.38
1.0
-
-
-
ND
2.8
4.2
9.3
19.7
5.1
-
ND
3-Nov-21
EPA 8260D
0.38
1.0
-
-
-
ND
4.3
3.1
8.6
18.6
3.5
-
ND
19-May-22
EPA 8260D
0.38
1.0
-
-
-
ND
3
3.3
8.1
17.1
3
-
---
17-Nov-22
EPA 8260D
0.38
1.0
-
-
ND
ND
2.7
3.0
9.0
15.9
5.1
-
---
6-Nov-23
EPA 8260D
0.38
1.0
-
-
-
ND
2.3
3.1
9.5
18.4
6.8
-
---
trans-1,2-Dichloroethene
5-Dec-13
0.49
5.0
-
-
ND
--
ND
ND
0.67
1 0.59
1 ND
ND
NC 21 100 pg/L (10/23/07)
12-Jun-13
0.49
5.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
28-Oct-13
0.49
5.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
6-May-14
EPA 8260
0.49
5.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
22-Oct-14
EPA 8260
0.49
5.0
-
-
*
ND
ND
ND
ND
ND
ND
ND
21-May-15
EPA 8260
0.49
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Dec-15
EPA 8260
0.49
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
3-May-16
EPA 8260
0.49
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
13-Dec-16
EPA 8260
0.49
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
27-Jun-17
EPA 8260
0.49
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
---
13-Dec-18
EPA 8260
0.49
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
4-Jun-18
EPA 8260
0.49
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
6-Dec-18
EPA 8260
0.49
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-19
EPA 8260D
0.46
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA 8260D
0.25
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-20
EPA 8260D
0.25
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
11-Nov-20
EPA 8260D
0.25
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
5-May-21
EPA 8260D
0.40
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
3-Nov-21
EPA 8260D
0.40
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
EPA 8260D
0.40
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
-
17-Nov-22
EPA 8260D
0.40
1.0
-
-
ND
ND
ND
ND
ND
ND
ND
-
---
6-Nov-23
EPA 8260D
0.40
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
---
1,2-Dichloropropane
30-May-07
-
1.0
-
ND
-
--
ND
ND
ND
2.2
2.5
ND
NC 21 0.51 pg/L (10/23/07)
29-Nov-07
-
1.0
-
ND
-
-
ND
ND
ND
ND
0.7
J ND
29-May-08
0.27
1.0
-
ND
-
--
ND
ND
0.4
J 0.72
J 0.85
J ND
6-Nov-08
0.27
1.0
-
ND
-
---
ND
0.32
J 0.5
J 0.68
J 0.67
J ND
3-Jun-09
0.27
1.0
-
ND
-
---
ND
ND
ND
0.88
J 0.9
J ND
18-Nov-09
0.27
1.0
-
ND
-
---
ND
ND
0.5
J 0.7
J 0.84
J ND
NC 21 0.6 pg/L (01/01/10)
16-Jun-10
0.27
1.0
-
ND
-
--
ND
ND
0.5
J 0.7
J 0.67
J ND
1-Dec-10
0.27
1.0
-
ND
ND
---
ND
0.33
J 0.29
J 0.55
J 0.72
J ND
1-Jun-11
0.27
1.0
-
ND
ND
---
ND
ND
ND
0.88
1 ND
ND
20-Dec-11
0.27
1.0
-
-
ND
--
ND
ND
0.35
J 0.57
11) 0.48
1 ND
30-May-12
0.27
1.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
5-Dec-12
0.27
1.0
-
-
ND
--
ND
ND
0.37
1 0.65
1 0.59
J ND
12-Jun-13
0.27
1.0
-
-
ND
--
ND
ND
0.35
1 0.6
1 0.59
1 ND
28-Oct-13
0.27
1.0
-
-
ND
--
ND
ND
ND
ND
0.47
1 ND
6-May-14
EPA 8260
0.27
1.0
-
-
ND
-
ND
ND
0.33
J 0.54
J 0.58
J ND
22-Oct-14
EPA 8260
0.27
1.0
--
-
*
ND
ND
ND
ND
ND
0.49
J ND
21-May-15
EPA 8260
0.27
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Dec-15
EPA 8260
0.27
1.0
--
-
-
ND
ND
ND
ND
ND
ND
ND
3-May-16
EPA 8260
0.27
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
13-Dec-16
EPA 8260
0.27
1.0
--
-
-
ND
ND
ND
ND
ND
ND
ND
ND
27-Jun-17
EPA 8260
0.27
1.0
--
-
-
ND
ND
ND
ND
0.28
J ND
ND
---
13-Dec-18
EPA 8260
0.27
1.0
--
-
-
ND
ND
ND
0.29
J 0.46
J 0.39
J ND
4-Jun-18
EPA 8260
0.27
1.0
--
-
-
ND
ND
ND
ND
ND
ND
ND
6-Dec-18
EPA 8260
0.27
1.0
-
-
-
ND
ND
ND
ND
ND
0.37
J ND
8-May-19
EPA 8260D
0.6
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA 8260D
0.2
1.0
-
-
-
ND
ND
ND
ND
0.28
J 0.29
J ND
8-May-20
EPA 8260D
0.2
1.0
-
-
-
ND
ND
ND
ND
0.35
J 0.32
J ND
ND
11-Nov-20
EPA 8260D
0.2
1.0
-
-
-
ND
ND
ND
ND
0.32
J 0.37
J -
ND
5-May-21
EPA 8260D
0.36
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
EPA 8260D
0.36
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
EPA 8260D
0.36
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
---
17-Nov-22
EPA 8260D
0.36
1.0
-
-
ND
ND
ND
ND
ND
ND
ND
-
---
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 20 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Sample
EPA
Analy[e
Collection Date
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-16D
Blanks
Ethylbenzene
1-May-98
---
5.0
ND
NI
ND
ND
6.4
ND
NI
NI
24-Nov-98
---
2.0
ND
NI
---
---
ND
ND
ND
ND
NI
NI
10-May-99
---
5.0
ND
ND
--
---
ND
ND
ND
ND
ND
ND
18-Oct-99
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
3-May-00
--
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
7-Nov-00
--
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
31-May-01
---
5.0
ND
ND
-
---
ND
ND
6.4
ND
ND
ND
7-Nov-01
---
5.0
ND
ND
-
---
ND
ND
5
ND
ND
ND
22-May-02
---
5.0
ND
ND
-
---
ND
ND
14
ND
ND
ND
14-Nov-02
---
5.0
ND
ND
-
---
ND
ND
14
ND
ND
ND
14-May-03
--
5.0
ND
ND
-
---
ND
ND
11
8.8
ND
ND
20-Nov-03
---
5.0
ND
ND
-
---
ND
ND
15
8.3
ND
ND
6-May-04
---
5.0
ND
ND
-
---
ND
ND
21
7.6
ND
ND
10-Nov-04
---
5.0
ND
ND
-
---
ND
ND
11.0
ND
ND
ND
27-May-05
---
5.0
ND
ND
-
---
ND
ND
23
8
ND
ND
3-Nov-05
-
5.0
-
ND
-
---
ND
ND
14
9
ND
ND
25-May-06
-
5.0
-
ND
-
---
ND
ND
17
5.8
ND
ND
2-Nov-06
-
5.0
-
ND
-
---
ND
ND
8.4
ND
ND
ND
30-May-07
-
1.0
-
ND
-
---
ND
ND
18
4.1
ND
ND
INC 2L= 550 pg/L(10/23/07)
29-Nov-07
-
1.0
-
ND
-
--
ND
ND
0.54
J 2
ND
ND
29-May-08
0.3
1.0
-
ND
-
---
ND
ND
2.6
2.6
ND
ND
6-Nov-08
0.3
1.0
-
ND
-
---
ND
ND
2
3.5
ND
ND
3-Jun-09
0.3
1.0
-
ND
-
---
ND
ND
6
8
ND
ND
18-Nov-09
0.3
1.0
-
ND
-
---
ND
ND
3.3
4.1
ND
ND
INC 2L= 600 pg/L(01/01/10)
16-Jun-10
0.3
1.0
-
ND
-
--
ND
ND
6.5
5
ND
ND
1-Dec-10
0.3
1.0
-
ND
ND
---
ND
ND
2.9
3
ND
ND
1-Jun-11
0.3
1.0
-
ND
ND
---
ND
ND
1.3
3
ND
ND
20-Dec-11
0.3
1.0
-
-
ND
---
ND
ND
0.59
1 1.2 1D
ND
ND
30-May-12
0.3
1.0
-
-
ND
---
ND
0.38
1 0.77
1 7
ND
ND
5-Dec-12
0.3
1.0
-
-
ND
---
ND
0.32
J 1.1
2.1
ND
ND
12-1un-13
0.3
1.0
-
-
ND
--
ND
0.4
J 2.3
5.1
ND
ND
28-Oct-13
0.3
1.0
-
-
ND
-
ND
0.35
J 1
5.9
ND
ND
6-May-14
EPA 8260
0.3
1.0
-
-
ND
-
ND
ND
ND
1.6
ND
ND
22-Oct-14
EPA 8260
0.3
1.0
-
-
*
ND
ND
ND
0.32
J 1.5
ND
ND
21-May-15
EPA 8260
0.3
1.0
-
-
-
ND
ND
ND
0.86
J 1.3
ND
ND
8-Dec-15
EPA 8260
0.3
1.0
-
-
-
ND
ND
ND
1.2
2.7
ND
ND
3-May-16
EPA 8260
0.3
1.0
-
-
-
ND
ND
ND
1.4
4.6
ND
ND
ND
13-Dec-16
EPA 8260
0.3
1.0
-
-
-
ND
ND
ND
ND
3.0
ND
ND
ND
27-1un-17
EPA 8260
0.3
1.0
-
-
-
ND
ND
ND
ND
1.5
ND
ND
-
13-Dec-18
EPA 8260
0.3
1.0
-
-
-
ND
ND
ND
ND
3.1
ND
ND
4-Jun-18
EPA 8260
0.3
1.0
-
-
-
ND
ND
ND
1.9
2.4
ND
ND
6-Dec-18
EPA 8260
0.3
1.0
-
-
-
ND
ND
ND
ND
3.4
ND
ND
8-May-19
EPA 8260D
0.45
1.0
-
-
-
ND
ND
ND
0.95
J 10.7
ND
ND
8-Nov-19
EPA 8260D
0.26
1.0
-
-
-
ND
ND
ND
0.34
J 2.0
ND
ND
8-May-20
EPA 8260D
0.30
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
11-Nov-20
EPA 8260D
0.26
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
5-May-21
EPA 8260D
0.30
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
EPA 8260D
0.30
1.0
-
-
-
ND
ND
ND
ND
3.5
ND
-
ND
19-May-22
EPA 8260D
0.30
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
--
17-Nov-22
EPA 8260D
0.30
1.0
-
-
ND
ND
ND
ND
ND
ND
ND
-
---
6-Nov-23
EPA 8260D
0.30
1.0
-
-
-
ND
ND
ND
0.62
J ND
ND
-
---
4-Methyl-2-pentanone(MIBK)
8-May-19
EPA 8260D
0.86
5.0
-
-
-
ND
ND
ND
ND
5.0
ND
ND
IMAC= 100 pg/L(04/2013)
S-Nov-19
EPA8260D
4.50
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-20
EPA 8260D
4.50
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
11-Nov-20
EPA 8260D
4.50
5.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
5-May-21
EPA 8260D
2.70
5.0
-
-
-
ND
ND
ND
ND
2.9 J
ND
-
ND
3-Nov-21
EPA 8260D
2.70
5.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
EPA 8260D
2.70
5.0
-
-
-
ND
ND
ND
ND
ND
ND
-
---
17-Nov-22
EPA 8260D
2.70
5.0
-
-
ND
ND
ND
ND
ND
ND
ND
-
---
6-Nov-23
EPA 8260D
2.70
5.0
-
-
ND
ND
ND
ND
ND
ND
ND
-
---
Methylene Chloride
1-Sep-94
--
5.0
ND
NI
NI
NI
ND
360
ND
ND
NI
NI
1-Oct-94
-
5.0
-
NI
NI
NI
--
430
-
-
NI
NI
1-Jan-95
-
5.0
-
NI
NI
NI
ND
290
ND
ND
NI
NI
1-Feb-95
-
5.0
-
NI
NI
NI
ND
560
ND
ND
NI
NI
1-Mar-95
-
5.0
ND
NI
NI
NI
ND
610
ND
ND
NI
NI
1-Aug-95
-
5.0
ND
NI
-
-
ND
810
ND
ND
NI
NI
1-Jan-96
-
5.0
-
NI
-
--
ND
380
ND
ND
NI
NI
1-Feb-96
-
5.0
--
NI
-
--
ND
ND
ND
ND
NI
NI
1-May-96
--
5.0
---
NI
-
-
ND
330
5.3
ND
NI
NI
1-Oct-96
-
5.0
---
NI
-
--
--
68
19
ND
NI
NI
1-May-97
--
5.0
ND
NI
-
---
2.4 J
280
11
ND
NI
NI
1-Nov-97
--
5.0
ND
NI
-
---
ND
ND
ND
ND
NI
NI
1-May-98
--
5.0
ND
NI
-
---
ND
420
450
61
NI
NI
24-Nov-98
--
10.0
ND
NI
-
---
ND
92.5
B ND
ND
NI
NI
10-May-99
--
5.0
ND
ND
-
---
ND
120
ND
37
ND
ND
18-Oct-99
--
10.0
ND
ND
-
---
ND
78.00
B ND
34 B
ND
ND
3-May-00
--
10.0
ND
ND
-
---
ND
98
ND
68
ND
ND
7-Nov-00
--
10.0
ND
ND
-
---
ND
ND
ND
56
ND
ND
31-May-01
--
10.0
ND
ND
-
---
ND
18
ND
96
ND
ND
7-Nov-01
--
10.0
ND
ND
-
---
ND
ND
ND
88
ND
ND
22-May-02
--
10.0
ND
ND
-
---
ND
ND
11
130
ND
ND
14-Nov-02
--
10.0
ND
ND
-
---
ND
ND
20
130
ND
ND
14-May-03
--
10.0
ND
ND
-
---
ND
18
ND
320
ND
ND
20-Nov-03
-
10.0
ND
ND
-
---
ND
ND
ND
570
ND
ND
6-May-04
-
10.0
12
ND
-
---
ND
ND
10
420
ND
ND
10-Nov-04
-
10.0
12
ND
-
---
ND
ND
ND
360
ND
ND
27-May-05
-
10.0
40
ND
-
---
ND
ND
ND
480
ND
ND
3-Nov-05
-
10.0
--
ND
-
---
ND
ND
ND
510
ND
ND
25-May-06
-
10.0
-
ND
-
---
ND
ND
ND
375
ND
ND
2-Nov-06
-
10.0
-
ND
-
---
ND
ND
ND
210
ND
ND
30-May-07
-
1.0
-
2.3 B
-
---
ND
ND
ND
310
ND
ND
INC 2L= 4.6 pg/L(10/23/07)
29-Nov-07
-
1.0
-
4.8
-
---
0.89 1
ND
ND
220
ND
ND
29-May-08
0.97
2.0
-
2.2 B
-
--
ND
ND
ND
285
ND
ND
6-Nov-08
0.97
2.0
-
2.6 B
-
--
1.1 B
ND
ND
831
ND
ND
3-Jun-09
0.97
2.0
-
ND
-
---
ND
ND
ND
278
ND
ND
1&Nov-09
0.97
2.0
-
11.1
-
---
ND
ND
ND
241
ND
ND
INC 2L= 5 pg/L(01/01/10)
16-Jun-10
0.97
2.0
-
ND
-
--
ND
ND
ND
234
ND
ND
1-Dec-10
0.97
1.0
-
2.2
ND
---
ND
ND
ND
174
ND
ND
1-Jun-11
0.97
1.0
-
2.3
ND
---
ND
ND
ND
232
ND
ND
20-Dec-11
0.97
1.0
-
-
ND
--
ND
ND
ND
196 D
ND
ND
30-May-12
0.97
1.0
-
-
ND
--
ND
ND
ND
185
ND
ND
5-Dec-12
0.97
1.0
-
-
ND
--
ND
ND
ND
174
ND
ND
12-Jun-13
0.97
1.0
-
-
ND
---
ND
ND
ND
77.9
ND
ND
28-Oct-13
0.97
1.0
-
-
ND
-
ND
ND
ND
128
ND
ND
6-May-14
EPA 8260
0.97
1.0
-
-
ND
-
ND
ND
ND
154
ND
ND
22-Oct-14
EPA 8260
0.97
1.0
-
-
*
ND
ND
ND
ND
130
ND
ND
21-May-15
EPA 8260
0.97
1.0
-
-
-
ND
ND
ND
ND
82.8
ND
ND
8-Dec-15
EPA 8260
0.97
1.0
-
-
-
ND
ND
ND
ND
113
ND
ND
3-May-16
EPA 8260
0.97
1.0
-
-
-
ND
ND
ND
ND
30.5
ND
ND
ND
13-Dec-16
EPA 8260
0.97
1.0
-
-
-
ND
ND
ND
ND
41.8
ND
ND
ND
27-Jun-17
EPA 8260
0.97
1.0
-
-
-
ND
ND
ND
ND
17.3
ND
ND
--
13-Dec-18
EPA 8260
0.97
1.0
-
-
-
ND
ND
ND
ND
73.9
ND
ND
4-Jun-18
EPA 8260
0.97
1.0
-
-
-
ND
ND
ND
ND
66.9
ND
ND
6-Dec-18
EPA 8260
0.97
1.0
-
-
-
ND
ND
ND
ND
79.4
ND
ND
8-May-19
EPA 8260D
0.5
1.0
-
-
-
ND
ND
ND
ND
76.0
ND
ND
8-Nov-19
EPA 8260D
3.7
5.0
-
-
-
ND
ND
ND
ND
55.7
ND
ND
8-May-20
EPA 8260D
3.7
5.0
-
-
-
ND
ND
ND
ND
45.4
ND
ND
ND
11-Nov-20
EPA 8260D
3.7
5.0
-
-
-
ND
ND
ND
ND
52.6
ND
-
ND
5-May-21
EPA 8260D
2.0
5.0
-
-
-
ND
ND
ND
ND
55.1
ND
-
ND
3-Nov-21
EPA 8260D
2.0
5.0
-
-
-
ND
ND
ND
ND
45.5
ND
-
ND
19-May-22
EPA 8260D
2.0
5.0
-
--
-
ND
ND
ND
ND
48.7
ND
-
---
17-Nov-22
EPA 8260D
2.0
5.0
-
---
ND
ND
ND
ND
ND
39.9
ND
--
---
6-Nov-23
EPA 8260D
2.0
5.0
-
---
-
ND
ND
ND
ND
38.5
ND
--
---
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 21 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Sample
EPA
Analy[e
Collection Date
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-16D
Blanks
lodomethane
29-May-08
0
10.0
---
0.35 J
---
---
ND
ND
ND
ND
ND
ND
NC 2L = NE (10/23/07)
6-Nov-08
0
10.0
---
ND
---
---
ND
ND
ND
ND
ND
ND
3-Jun-09
0
10.0
---
ND
-
---
ND
ND
ND
ND
ND
ND
18-Nov-09
0
10.0
--
ND
-
--
ND
ND
ND
ND
ND
ND
16-Jun-10
0
10.0
-
ND
-
-
ND
ND
ND
ND
ND
ND
1-Dec-10
0
10.0
-
ND
ND
-
5 1
ND
ND
ND
ND
ND
1-Jun-11
0.32
10.0
-
ND
ND
-
ND
ND
ND
ND
ND
ND
20-Dec-11
0.32
10.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
30-May-12
0.32
10.0
-
-
ND
---
ND
ND
ND
ND
ND
ND
5-Dec-12
0.32
10.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
12-1un-13
0.32
10.0
-
-
ND
-
8.6 1
ND
ND
ND
ND
ND
28-Oct-13
0.32
10.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
6-May-14
EPA 8260
0.32
10.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
22-Oct-14
EPA 8260
0.32
10.0
-
-
*
ND
ND
ND
ND
ND
ND
ND
21-May-15
EPA 8260
0.32
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Dec-15
EPA 8260
0.32
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
3-May-16
EPA 8260
0.32
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
13-Dec-16
EPA 8260
0.32
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
27-1un-17
EPA 8260
0.32
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
-
13-Dec-18
EPA 8260
0.32
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
4-Jun-18
EPA 8260
0.32
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
6-Dec-18
EPA 8260
0.32
5.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-19
EPA 8260D
3.1
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA 8260D
12.5
20.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-20
EPA 8260D
12.5
20.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
11-Nov-20
EPA 8260D
12.5
20.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
5-May-21
EPA 8260D
9.7
20.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
EPA 8260D
9.7
20.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
EPA 8260D
9.7
20.0
-
-
-
ND
ND
ND
ND
ND
ND
-
---
17-Nov-22
EPA 8260D
9.7
20.0
-
-
ND
ND
ND
ND
ND
ND
ND
-
---
6-Nov-23
EPA 8260D
9.7
20.0
-
-
-
ND
ND
ND
ND
ND
ND
-
---
Styrene
3-Jun-09
0.26
1.0
-
ND
-
--
ND
2
ND
ND
ND
ND
NC 2L= 100 pg/L(10/23/07)
18-Nov-09
0.26
1.0
-
ND
-
-
ND
ND
ND
ND
ND
ND
NC 2L= 70 pg/L(01/01/10)
16-Jun-10
0.26
1.0
-
ND
-
-
ND
ND
ND
ND
ND
ND
1-Dec-10
0.26
1.0
-
ND
ND
--
ND
ND
ND
ND
ND
ND
1-Jun-11
0.26
1.0
-
ND
ND
---
ND
ND
ND
ND
ND
ND
20-Dec-11
0.26
1.0
-
-
ND
---
ND
ND
ND
ND
ND
ND
30-May-12
0.26
1.0
-
-
ND
---
ND
ND
ND
ND
ND
ND
5-Dec-12
0.26
1.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
12-Jun-13
0.26
1.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
28-Oct-13
0.26
1.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
6-May-14
EPA 8260
0.26
1.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
22-Oct-14
EPA 8260
0.26
1.0
-
-
*
ND
ND
ND
ND
ND
ND
ND
21-May-15
EPA 8260
0.26
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Dec-15
EPA 8260
0.26
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
3-May-16
EPA 8260
0.26
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
13-Dec-16
EPA 8260
0.26
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
27-Jun-17
EPA 8260
0.26
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
-
13-Dec-18
EPA 8260
0.26
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
4-Jun-18
EPA 8260
0.26
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
6-Dec-18
EPA 8260
0.26
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-19
EPA 8260D
0.5
1.0
-
-
-
ND
ND
ND
ND
1.3
ND
ND
8-Nov-19
EPA 8260D
0.3
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-20
EPA 8260D
0.3
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
II-Nov-20
EPA 8260D
0.3
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
5-May-21
EPA 8260D
0.29
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
EPA 8260D
0.29
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
EPA 8260D
0.29
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
---
17-Nov-22
EPA 8260D
0.29
1.0
-
-
ND
ND
ND
ND
ND
ND
ND
-
---
6-Nov-23
EPA 8260D
0.29
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
---
Tetrachloroethene
1-May-97
-
5.0
5.6
NI
--
--
ND
6.3
3.6
J ND
NI
NI
1-Nov-97
--
1.0
2.0
NI
--
--
ND
ND
ND
ND
NI
NI
1-May-98
---
5.0
ND
NI
-
-
ND
ND
ND
ND
NI
NI
24-Nov-98
---
2.0
6.7
NI
-
--
ND
7.8
3.2
ND
NI
NI
10-May-99
---
5.0
8.5
ND
---
---
ND
9.3
ND
ND
ND
ND
18-Oct-99
---
5.0
5.3
ND
--
---
ND
7.3
ND
ND
ND
ND
3-May-00
---
5.0
7.0
ND
-
---
ND
6.4
ND
ND
ND
ND
7-Nov-00
---
5.0
6.6
ND
-
---
ND
5.3
ND
ND
ND
ND
31-May-01
---
5.0
9.6
ND
-
---
ND
7.1
ND
ND
ND
ND
7-Nov-01
---
5.0
9.5
ND
-
---
ND
5.6
5.0
ND
ND
ND
22-May-02
---
5.0
10.0
ND
-
---
ND
5.7
5.5
ND
ND
ND
14-Nov-02
---
5.0
8.0
ND
-
---
ND
ND
ND
ND
ND
ND
14-May-03
---
5.0
10.0
ND
-
---
ND
5.5
ND
ND
ND
ND
20-Nov-03
---
5.0
8.8
ND
-
---
ND
6.6
ND
ND
ND
ND
6-May-04
---
5.0
8.9
ND
-
---
ND
ND
ND
ND
ND
ND
10-Nov-04
---
5.0
12.0
ND
-
---
ND
ND
ND
5.1
ND
ND
27-May-05
---
5.0
10
ND
-
---
ND
ND
ND
ND
ND
ND
3-Nov-05
--
5.0
---
ND
-
---
ND
ND
ND
12.0
ND
ND
25-May-06
--
5.0
---
ND
-
---
ND
ND
ND
ND
ND
ND
2-Nov-06
--
5.0
---
ND
-
---
ND
ND
ND
5.8
ND
ND
30-May-07
--
1.0
---
1.6
-
---
ND
0.44 J
1.6
5.9
ND
ND
NC 2L = 0.7 pg/L (10/23/07)
29-Nov-07
---
1.0
-
1.7
-
---
ND
ND
1.1
4.9
ND
ND
29-May-08
0.46
1.0
-
2.2
-
---
ND
ND
1.1
6.6
ND
ND
6-Nov-08
0.46
1.0
-
2.7
-
---
ND
ND
1.3
6.2
ND
ND
3-Jun-09
0.46
1.0
-
2.1
-
---
ND
ND
0.70
J 7.5
ND
ND
18-Nov-09
0.46
1.0
--
2.6
-
---
ND
ND
0.49
1 6.3
ND
ND
16-Jun-10
0.46
1.0
-
1.2
-
---
ND
ND
0.46
J 6.7
ND
ND
1-Dec-10
0.46
1.0
-
3.0
ND
--
ND
ND
ND
5.8
ND
ND
1-Jun-11
0.46
1.0
-
3.6
ND
--
ND
ND
ND
7.7
ND
ND
20-Dec-11
0.46
1.0
-
-
ND
--
ND
0.59 B
0.70
B 5.7 D
ND
ND
30-May-12
0.46
1.0
-
-
ND
--
ND
ND
ND
7.7
ND
ND
5-Dec-12
0.46
1.0
-
-
ND
--
ND
ND
ND
7.3
ND
ND
12-1un-13
0.46
1.0
-
-
ND
-
ND
ND
ND
6.4
ND
ND
28-Oct-13
0.46
1.0
-
-
ND
-
ND
ND
ND
5.7
ND
ND
6-May-14
EPA 8260
0.46
1.0
-
-
ND
-
ND
ND
ND
7.3
ND
ND
22-Oct-14
EPA 8260
0.46
1.0
-
-
*
ND
ND
ND
ND
7.0
ND
ND
21-May-15
EPA 8260
0.46
1.0
-
-
-
ND
ND
ND
ND
6.4
ND
ND
8-Dec-15
EPA 8260
0.46
1.0
-
-
-
ND
ND
ND
ND
5.6
ND
ND
3-May-16
EPA 8260
0.46
1.0
-
-
-
ND
ND
ND
ND
7.6
ND
ND
ND
13-Dec-16
EPA 8260
0.46
1.0
-
-
-
ND
ND
ND
ND
5.9
ND
ND
ND
27-1un-17
EPA 8260
0.46
1.0
-
-
-
ND
ND
ND
ND
6.5
ND
ND
---
13-Dec-18
EPA 8260
0.46
1.0
-
-
-
ND
ND
ND
ND
6.6
ND
ND
4-Jun-18
EPA 8260
0.46
1.0
-
-
-
ND
ND
ND
ND
5.8
ND
ND
6-Dec-18
EPA 8260
0.46
1.0
-
-
-
ND
ND
ND
ND
6.1
ND
ND
8-May-19
EPA 8260D
0.78
1.0
-
-
-
ND
ND
ND
ND
7.3
ND
ND
8-Nov-19
EPA 8260D
0.16
1.0
-
-
-
ND
ND
ND
ND
5.5
ND
ND
8-May-20
EPA 8260D
0.34
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
11-Nov-20
EPA 8260D
0.34
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
5-May-21
EPA 8260D
0.29
1.0
-
-
-
ND
ND
ND
ND
3.9
ND
-
ND
3-Nov-21
EPA 8260D
0.29
1.0
-
-
-
ND
ND
ND
ND
4.5
ND
-
ND
19-May-22
EPA 8260D
0.31
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
-
17-Nov-22
EPA 8260D
0.31
1.0
-
-
ND
ND
ND
ND
ND
ND
ND
-
-
6-Nov-23
EPA 8260D
0.31
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
-
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 22 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Analy[e
Sample
Collection Date
EPA
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-161D
Blanks
Tetrahydrofuran
1-Dec-10
3.1
10.0
---
ND
ND
ND
ND
ND
10.1
ND
ND
NC 2L=NE (01/01/10)
1-Jun-11
3.1
10.0
---
ND
ND
ND
ND
ND
ND
ND
ND
20-Dec-11
3.1
10.0
---
-
ND
---
ND
ND
ND
9.3
JD ND
ND
30-May-12
3.1
10.0
--
-
ND
---
ND
ND
ND
8.9
1 ND
ND
5-Dec-12
3.1
10.0
-
-
ND
--
ND
ND
ND
6.9
1 ND
ND
12-1un-13
3.1
10.0
-
-
ND
--
ND
ND
ND
6.3
1 ND
ND
28-Oct-13
3.1
10.0
-
-
ND
--
ND
ND
ND
8.6
1 ND
ND
6-May-14
EPA 8260
3.1
10.0
-
-
ND
--
ND
ND
ND
10.2
ND
ND
22-Oct-14
EPA 8260
3.1
10.0
-
-
*
ND
ND
ND
ND
7.4
J ND
ND
21-May-15
EPA 8260
3.1
NE
-
-
-
ND
ND
ND
ND
6.3
1 ND
ND
8-Dec-15
EPA 8260
3.1
NE
-
-
-
ND
ND
ND
ND
9.7
1 ND
ND
3-May-16
EPA 8260
3.1
NE
-
-
-
ND
ND
ND
ND
7.9
1 ND
ND
ND
13-Dec-16
EPA 8260
3.1
NE
-
-
-
ND
ND
ND
ND
9.2
1 ND
ND
--
27-Jun-17
EPA 8260
3.1
10.0
-
-
-
ND
ND
ND
ND
7.5
1 ND
ND
--
13-Dec-18
EPA 8260
3.1
10.0
-
-
-
ND
ND
ND
ND
8.3
J ND
ND
4-Jun-18
EPA 8260
3.1
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
6-Dec-18
EPA 8260
3.1
10.0
-
-
-
ND
ND
ND
ND
7.1
1 ND
ND
8-May-19
EPA 8260D
1.3
10.0
-
-
-
ND
ND
ND
ND
6.2
J ND
ND
8-Nov-19
EPA 8260D
1.9
10.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-20
EPA 8260D
1.9
10.0
-
-
-
ND
ND
ND
ND
7.8
J ND
ND
ND
11-Nov-20
EPA 8260D
1.9
10.0
-
-
-
-
ND
ND
ND
8.2
J ND
-
ND
5-May-21
EPA 8260D
3.5
10.0
-
-
-
ND
ND
ND
ND
9.6
J ND
-
ND
3-Nov-21
EPA 8260D
3.5
10.0
-
-
-
ND
ND
ND
ND
ND
ND
-
-
19-May-22
EPA 8260D
3.5
10.0
-
-
-
ND
ND
ND
ND
ND
ND
-
-
17-Nov-22
EPA 8260D
3.5
10.0
-
-
ND
ND
ND
ND
ND
13.8
ND
-
--
6-Nov-23
EPA 8260D
3.5
10.0
-
-
ND
ND
ND
ND
ND
14.8
ND
-
--
Toluene
1-Jan-95
---
5.0
-
NI
NI
NI
ND
ND
19
ND
NI
NI
1-Feb-95
---
5.0
-
NI
NI
NI
ND
ND
ND
ND
NI
NI
1-Mar-95
---
5.0
ND
NI
NI
NI
ND
ND
ND
ND
NI
NI
1-Aug-95
---
5.0
ND
NI
-
--
ND
ND
ND
ND
NI
NI
1-Jan-96
---
5.0
-
NI
-
---
ND
ND
ND
ND
NI
NI
1-Feb-96
---
5.0
-
NI
-
---
ND
ND
ND
ND
NI
NI
1-May-96
---
5.0
-
NI
-
---
ND
ND
ND
ND
NI
NI
1-Oct-96
---
5.0
-
NI
-
---
ND
ND
5
ND
NI
NI
1-May-97
---
5.0
ND
NI
-
---
ND
ND
2
J 3.4
J NI
NI
1-Nov-97
---
1.0
ND
NI
-
---
ND
ND
ND
ND
NI
NI
1-May-98
---
5.0
ND
NI
-
---
ND
ND
ND
ND
NI
NI
24-Nov-98
---
2.0
ND
NI
-
---
ND
ND
ND
ND
NI
NI
10-May-99
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
18-Oct-99
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
3-May-00
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
7-Nov-00
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
31-May-01
---
5.0
ND
ND
-
---
ND
ND
22
15.0
ND
ND
7-Nov-01
---
5.0
ND
ND
-
---
ND
ND
11
7.2
ND
ND
22-May-02
---
5.0
ND
ND
-
---
ND
ND
11
17.0
ND
ND
14-Nov-02
---
5.0
ND
ND
-
---
ND
ND
21
ND
ND
ND
14-May-03
---
5.0
ND
ND
-
---
ND
ND
8.4
86.0
ND
ND
20-Nov-03
---
5.0
ND
ND
-
---
ND
ND
14
77.0
ND
ND
6-May-04
---
5.0
ND
ND
-
---
ND
ND
22
54.0
ND
ND
10-Nov-04
---
5.0
ND
ND
-
---
ND
ND
ND
35.0
ND
ND
27-May-05
---
5.0
ND
ND
-
---
ND
ND
ND
100
ND
ND
3-Nov-05
---
5.0
-
ND
-
---
ND
ND
20
80.0
ND
ND
25-May-06
-
5.0
-
ND
-
---
ND
ND
30.4
35.6
ND
ND
2-Nov-06
-
5.0
-
ND
-
---
ND
ND
ND
22.0
ND
ND
30-May-07
-
1.0
-
ND
-
---
0.22 B
0.3 B
27.0
30.0
0.58
B ND
NC 2L= 1,000 pg/L(10/23/07)
29-Nov-07
-
1.0
-
ND
-
--
ND
ND
1.5
12.0
ND
ND
29-May-08
0.26
1.0
-
ND
-
---
ND
ND
3.1
12.8
5.9
ND
6-Nov-08
0.26
1.0
-
ND
-
---
ND
ND
0.7
1 23.5
0.76
J ND
3-Jun-09
0.26
1.0
-
ND
-
---
ND
ND
0.4
1 52.6
0.85
J ND
18-Nov-09
0.26
1.0
-
ND
-
---
ND
ND
ND
27.2
0.55
J ND
NC 2L= 600 pg/L(01/01/10)
16-Jun-10
0.26
1.0
-
ND
-
--
ND
ND
2.5
34.8
0.38
J ND
1-Dec-10
0.26
1.0
-
ND
ND
---
ND
ND
4.1
17.5
ND
ND
1-Jun-11
0.26
1.0
-
ND
ND
---
ND
ND
ND
24.7
1.1
ND
20-Dec-11
0.26
1.0
-
-
ND
--
ND
ND
ND
4.9
D 0.53
J ND
30-May-12
0.26
1.0
-
-
ND
-
ND
ND
ND
46.8
0.67
J ND
5-Dec-12
0.26
1.0
-
-
ND
-
ND
ND
0.33
1 10.7
0.45
J ND
12-1un-13
0.26
1.0
-
-
ND
-
ND
ND
ND
27.6
0.7
1 ND
28-Oct-13
0.26
1.0
-
-
ND
--
ND
ND
ND
14.6
0.5
J ND
6-May-14
EPA 8260
0.26
1.0
-
-
ND
--
ND
ND
ND
3.9
0.48
J ND
22-Oct-14
EPA 8260
0.26
1.0
-
-
*
ND
ND
ND
ND
4.3
0.28
J ND
21-May-15
EPA 8260
0.26
1.0
-
-
-
ND
ND
ND
ND
4.1
ND
ND
8-Dec-15
EPA 8260
0.26
1.0
-
-
-
ND
ND
ND
ND
6.0
0.31
J ND
3-May-16
EPA 8260
0.26
1.0
-
-
-
ND
ND
ND
ND
38.2
0.53
J ND
ND
13-Dec-16
EPA 8260
0.26
1.0
-
-
-
ND
ND
ND
ND
6.8
0.28
J ND
ND
27-1un-17
EPA 8260
0.26
1.0
-
-
-
ND
ND
ND
ND
2.1
0.47
J ND
-
13-Dec-18
EPA 8260
0.26
1.0
-
-
-
ND
ND
ND
ND
12.3
0.26
J ND
4-Jun-18
EPA 8260
0.26
1.0
-
-
-
ND
ND
ND
ND
5.9
ND
ND
6-Dec-18
EPA 8260
0.26
1.0
-
-
-
ND
ND
ND
ND
14.9
2.4
ND
8-May-19
EPA 8260D
0.31
1.0
-
-
-
ND
ND
ND
ND
54.6
ND
ND
8-Nov-19
EPA 8260D
0.24
1.0
-
-
-
ND
ND
ND
ND
3.7
0.30
J ND
8-May-20
EPA 8260D
0.24
1.0
-
-
-
ND
ND
ND
ND
27.7
0.28
J ND
ND
11-Nov-20
EPA 8260D
0.24
1.0
-
-
-
ND
ND
ND
ND
32.6
1.2
-
ND
5-May-21
EPA 8260D
0.48
1.0
-
-
-
ND
ND
ND
ND
26.4
ND
-
ND
3-Nov-21
EPA 8260D
0.48
1.0
-
-
-
ND
ND
ND
ND
8.0
ND
-
ND
19-May-22
EPA 8260D
0.48
1.0
-
-
-
ND
ND
ND
ND
6.1
ND
-
---
17-Nov-22
EPA 8260D
0.24
1.0
-
-
ND
ND
ND
ND
0.4
J 7.1
ND
-
---
6-Nov-23
EPA 8260D
0.24
1.0
-
-
-
ND
ND
0.29 J
0.77
J 1.6
ND
-
---
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 23 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Analy[e
Sample
Collection Date
EPA
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-16D
Blanks
1,1,1-Trichloroethane
1-Sep-94
---
5.0
ND
NI
NI
NI
ND
26
ND
ND
NI
NI
1-Oct-94
---
5.0
-
NI
NI
NI
--
ND
-
-
NI
NI
1-Jan-95
---
5.0
-
NI
NI
NI
ND
23
ND
ND
NI
NI
1-Feb-95
---
5.0
-
NI
NI
NI
ND
27
ND
ND
NI
NI
1-Mar-95
---
5.0
ND
NI
NI
NI
ND
28
6.5
ND
NI
NI
1-Aug-95
---
5.0
ND
NI
-
-
ND
42
ND
5
NI
NI
1-Jan-96
---
5.0
-
NI
-
-
ND
44
6
9
NI
NI
1-Feb-96
---
5.0
-
NI
-
-
ND
31
6.7
ND
NI
NI
1-May-96
---
5.0
-
NI
-
--
ND
30
6.7
9.2
NI
NI
1-Oct-96
---
5.0
-
NI
-
---
ND
22
5
9
NI
NI
1-May-97
---
5.0
16
NI
-
---
2.4 1
19
5.3
17
NI
NI
1-Nov-97
---
1.0
14
NI
-
---
ND
ND
ND
14
NI
NI
1-May-98
---
5.0
15
NI
-
---
ND
9.3
9.3
22.0
NI
NI
24-Nov-98
---
2.0
10.1
NI
-
---
ND
4.9
3
9.3
NI
NI
10-May-99
---
5.0
15
ND
-
---
ND
ND
ND
8.7
ND
ND
18-Oct-99
---
5.0
11
ND
-
---
ND
ND
ND
9.2
ND
ND
3-May-00
---
5.0
12
ND
-
---
ND
ND
ND
8.5
ND
ND
7-Nov-00
---
5.0
10
ND
-
---
ND
ND
ND
7.3
ND
ND
31-May-01
---
5.0
9.8
ND
-
---
ND
ND
ND
6.0
ND
ND
7-Nov-01
---
5.0
14
ND
-
---
ND
ND
ND
7.9
ND
ND
22-May-02
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
14-Nov-02
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
14-May-03
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
20-Nov-03
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
6-May-04
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
10-Nov-04
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
27-May-05
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
3-Nov-05
---
5.0
-
ND
-
---
ND
ND
ND
5.0
ND
ND
25-May-06
---
5.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
2-Nov-06
---
5.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
30-May-07
--
1.0
-
ND
-
---
ND
ND
ND
3.4
ND
ND
NC 21 200 pg/L (10/23/07)
29-Nov-07
---
1.0
-
ND
-
--
ND
ND
ND
ND
ND
ND
29-May-08
0.48
1.0
-
ND
-
---
ND
ND
ND
0.75 J
ND
ND
6-Nov-08
0.48
1.0
-
ND
-
---
ND
ND
ND
0.69 J
ND
ND
3-Jun-09
0.48
1.0
-
ND
-
---
ND
ND
ND
0.54 1
ND
ND
18-Nov-09
0.48
1.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
16-Jun-10
0.48
1.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
1-Dec-10
0.48
1.0
-
ND
ND
---
ND
ND
ND
ND
ND
ND
1-Jun-11
0.48
1.0
-
ND
ND
---
ND
ND
ND
ND
ND
ND
20-Dec-11
0.48
1.0
--
-
ND
---
ND
ND
ND
ND
ND
ND
30-May-12
0.48
1.0
--
-
ND
---
ND
ND
ND
ND
ND
ND
5-Dec-12
0.48
1.0
-
-
ND
---
ND
ND
ND
ND
ND
ND
12-Jun-13
0.48
1.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
28-Oct-13
0.48
1.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
6-May-14
EPA 8260
0.48
1.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
22-Oct-14
EPA 8260
0.48
1.0
-
-
*
ND
ND
ND
ND
ND
ND
ND
21-May-15
EPA 8260
0.48
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Dec-15
EPA 8260
0.48
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
3-May-16
EPA 8260
0.48
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
13-Dec-16
EPA 8260
0.48
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
27-Jun-17
EPA 8260
0.48
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
---
13-Dec-18
EPA 8260
0.48
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
4-Jun-18
EPA 8260
0.48
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
6-Dec-18
EPA 8260
0.48
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-19
EPA 8260D
0.38
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA 8260D
0.18
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-20
EPA 8260D
0.18
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
11-Nov-20
EPA 8260D
0.18
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
5-May-21
EPA 8260D
0.33
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
EPA 8260D
0.33
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
EPA 8260D
0.33
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
---
17-Nov-22
EPA 8260D
0.33
1.0
-
-
ND
ND
ND
ND
ND
ND
ND
-
---
6-Nov-23
EPA 8260D
0.33
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
---
Trichloroethene
1-Sep-94
-
5.0
ND
NI
NI
NI
ND
9
ND
ND
NI
NI
1-Oct-94
-
5.0
-
NI
NI
NI
--
11
-
-
NI
NI
1-Jan-95
-
5.0
-
NI
NI
NI
ND
6
ND
ND
NI
NI
1-Feb-95
-
5.0
-
NI
NI
NI
ND
10
ND
ND
NI
NI
1-Mar-95
-
5.0
ND
NI
NI
NI
ND
12
ND
ND
NI
NI
1-Aug-95
-
5.0
ND
NI
-
-
ND
13
ND
ND
NI
NI
1-Jan-96
-
5.0
-
NI
-
-
ND
13
ND
ND
NI
NI
1-Feb-96
-
5.0
-
NI
-
-
ND
14
ND
ND
NI
NI
1-May-96
--
5.0
-
NI
-
--
ND
14
ND
ND
NI
NI
1-Oct-96
-
5.0
-
NI
-
---
ND
14
ND
ND
NI
NI
1-May-97
--
5.0
2 J
NI
-
---
ND
13
5 J
ND
NI
NI
1-Nov-97
--
1.0
2
NI
-
---
ND
16
J ND
ND
NI
NI
1-May-98
--
5.0
ND
NI
-
---
ND
14
13
ND
NI
NI
24Nov-98
--
2.0
4
NI
-
---
ND
16
4
ND
NI
NI
10-May-99
--
5.0
6
ND
-
---
ND
19
5
ND
ND
ND
18-Oct-99
--
5.0
ND
ND
-
---
ND
15
ND
ND
5
ND
3-May-00
---
5.0
5.4
ND
-
---
ND
14
6
ND
6
ND
7-Nov-00
---
5.0
ND
ND
-
---
ND
12
ND
ND
ND
ND
31-May-01
---
5.0
ND
ND
-
---
ND
12
7
6
5
ND
7-Nov-01
---
5.0
ND
ND
-
---
ND
12
8
7
5
ND
22-May-02
---
5.0
ND
ND
-
---
ND
10
9
8
ND
ND
14-Nov-02
---
5.0
ND
ND
-
---
ND
5.5
7.6
6.5
ND
ND
14May-03
---
5.0
ND
ND
-
---
ND
11
7
12
6.8
ND
20-Nov-03
---
5.0
ND
ND
-
---
ND
9.5
6.6
12
ND
ND
6-May-04
---
5.0
ND
ND
-
---
ND
9.1
5.8
12
ND
ND
10-Nov-04
---
5.0
ND
ND
-
---
ND
8.6
ND
11
ND
ND
27-May-05
---
5.0
5
ND
-
---
ND
11
ND
12
ND
ND
3-Nov-05
---
5.0
-
ND
-
---
ND
9
ND
14
ND
ND
25-May-06
---
5.0
-
ND
-
---
ND
8.6
ND
10
ND
ND
2-Nov-06
---
5.0
-
ND
-
---
ND
7
ND
12
ND
ND
30-May-07
---
1.0
-
2
-
---
1.9
8.5
4.6
12
2.8
ND
NC 21 2.8 pg/L (10/23/07)
29-Nov-07
-
1.0
-
1
-
--
0.45 J
3.5
2.5
9.7
1.6
ND
29-May-08
0.47
1.0
-
ND
-
---
ND
3.5
2.9
11.9
1.4
ND
6-Nov-08
0.47
1.0
-
1.3
-
---
0.53 1
3.7
3.3
11.6
1.3
ND
3-Jun-09
0.47
1.0
-
1.8
-
---
ND
3.6
4.3
12.1
1.4
ND
18-Nov-09
0.47
1.0
-
1.9
-
--
0.58 J
3.3
3.3
11.2
1.2
ND
NC 21 3 pg/L (01/01/10)
16-Jun-10
0.47
1.0
-
0.6 J
-
--
ND
5.1
3.3
11.2
1.4
ND
1-Dec-10
0.47
1.0
-
1.9
ND
---
0.76 J
3.7
3.3
9.3
ND
ND
1-Jun-11
0.47
1.0
-
2
ND
--
0.51 1
2.8
3.2
11.4
ND
ND
20-Dec-11
0.47
1.0
-
-
ND
--
0.6 1
2.5
3.5
10.0 D
1.1
ND
30-May-12
0.47
1.0
-
-
ND
--
ND
2.5
2.6
11.1
0.55
1 ND
5-Dec-12
0.47
1.0
-
-
ND
---
0.53 1
2.3
3.3
11.2
0.67
1 ND
12-1un-13
0.47
1.0
-
-
ND
---
0.66 1
2.1
1.8
11.5
0.76
1 ND
28-Oct-13
0.47
1.0
-
-
ND
---
ND
3.1
2.5
10.7
0.76
1 ND
6-May-14
EPA 8260
0.47
1.0
-
-
ND
-
ND
2.0
2.6
11.9
0.60
1 ND
22-Oct-14
EPA 8260
0.47
1.0
-
-
*
ND
0.61 J
1.3
2.2
11.4
0.86
1 ND
21-May-15
EPA 8260
0.47
1.0
-
-
-
ND
ND
0.90
J 2.3
10.1
ND
ND
8-Dec-15
EPA 8260
0.47
1.0
-
-
-
ND
ND
0.71
1 1.4
9.7
ND
ND
3-May-16
EPA 8260
0.47
1.0
-
-
-
ND
0.53 J
0.63
J 1.8
10.1
ND
ND
ND
13-Dec-16
EPA 8260
0.47
1.0
-
-
-
ND
0.52 J
0.56
J 2.1
9.9
0.64
1 ND
ND
27-1un-17
EPA 8260
0.47
1.0
-
-
-
ND
ND
ND
1.4
10.0
0.56
1 ND
---
13-Dec-18
EPA 8260
0.47
1.0
-
-
-
ND
ND
0.63
1 2.2
9.9
0.51
1 ND
4-Jun-18
EPA 8260
0.47
1.0
-
-
-
ND
ND
ND
1.0
7.9
0.55
1 ND
6-Dec-18
EPA 8260
0.47
1.0
-
-
-
ND
ND
0.75
J 1.7
9.1
0.80
1 ND
8-May-19
EPA8260D
0.34
1.0
-
-
-
ND
0.47 J
0.99
J 2.0
11.5
1.2
ND
8-Nov-19
EPA 8260D
0.22
1.0
-
-
-
ND
ND
ND
1.6
7.7
ND
ND
8-May-20
EPA 8260D
0.24
1.0
-
-
-
ND
ND
0.53
J 1.6
7.3
ND
ND
ND
11-Nov-20
EPA8260D
0.22
1.0
-
-
-
ND
ND
0.55
J 1.8
8.6
ND
-
ND
5-May-21
EPA 8260D
0.38
1.0
-
-
-
ND
ND
ND
1.6
6.5
ND
-
ND
3-Nov-21
EPA 8260D
0.38
1.0
-
-
-
ND
ND
ND
ND
6.2
ND
-
ND
19-May-22
EPA8260D
0.32
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
-
17-Nov-22
EPA 8260D
0.32
1.0
-
-
ND
ND
ND
ND
ND
ND
ND
-
-
6-Nov-23
EPA 8260D
0.38
1.0
-
-
-
ND
ND
ND
ND
ND
0.43
J -
-
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 24 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-16D
Blanks
Trichlorofluoromethane
1-Oct-94
---
5.0
---
Ni
NI
NI
--
60
-
-
NI
NI
1-Jan-95
---
5.0
-
NI
NI
NI
ND
37
ND
ND
NI
NI
1-Feb-95
---
5.0
-
NI
NI
NI
ND
40
ND
ND
NI
NI
1-Mar-95
---
5.0
ND
NI
NI
NI
ND
48
ND
ND
NI
NI
1-Aug-95
---
5.0
ND
NI
-
---
ND
51
ND
9
NI
NI
1-Jan-96
---
5.0
-
NI
-
---
ND
20
5
11
NI
NI
1-Feb-96
---
5.0
-
NI
-
---
ND
11
6.2
7.9
NI
NI
1-May-96
---
5.0
-
NI
-
---
ND
8.8
ND
9.1
NI
NI
1-0ct-96
---
5.0
-
NI
-
---
ND
ND
ND
9
NI
NI
1-May-97
---
5.0
4.2 1
NI
-
---
ND
2.1
1 3.4
1 11
NI
NI
1-Nov-97
---
1.0
4
NI
-
---
ND
ND
ND
11
NI
NI
1-May-98
--
5.0
ND
NI
-
---
ND
ND
ND
5
NI
NI
24-Nov-98
-
2.0
ND
NI
-
---
ND
ND
ND
7.6
NI
NI
10-May-99
-
10.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
18-Oct-99
-
5.0
ND
ND
-
---
ND
ND
ND
12
ND
ND
3-May-00
-
5.0
ND
ND
-
---
ND
ND
ND
9.4
ND
ND
7-Nov-00
-
5.0
ND
ND
-
---
ND
ND
ND
10
ND
ND
31-May-01
-
5.0
ND
ND
-
---
ND
ND
ND
6.5
ND
ND
7-Nov-01
-
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
22-May-02
-
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
14-Nov-02
-
5.0
ND
ND
-
---
ND
ND
ND
6.5
ND
ND
14-May-03
--
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
20-Nov-03
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
6-May-04
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
10-Nov-04
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
27-May-05
---
5.0
ND
ND
-
---
ND
ND
ND
ND
ND
ND
3-Nov-05
--
5.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
25-May-06
-
5.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
2-Nov-06
-
5.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
30-May-07
-
1.0
-
ND
-
---
ND
ND
ND
4.2
ND
ND
NC 21 2,100 Ng/L(10/23/07)
29-Nov-07
-
1.0
-
0.74
J -
--
ND
ND
ND
ND
ND
ND
29-May-08
0.2
1.0
-
0.42
1 -
---
ND
ND
ND
ND
ND
ND
6-Nov-08
0.2
1.0
-
0.71
1 -
---
ND
ND
0.24
1 1.1
ND
ND
3-Jun-09
0.2
1.0
-
0.38
1 -
---
ND
ND
ND
ND
ND
ND
18-Nov-09
0.2
1.0
-
1.9
-
---
ND
ND
1.6
2.1
ND
ND
NC 21 2,000 Ng/L(01/01/10)
16-Jun-1O
0.2
1.0
-
ND
-
--
ND
ND
ND
ND
ND
ND
1-Dec-10
0.2
1.0
-
0.34
1 ND
---
ND
ND
ND
0.58 J
ND
ND
1-Jun-11
0.2
1.0
-
0.5
1 ND
---
ND
ND
ND
0.79 1
ND
ND
20-Dec-11
0.2
1.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
30-May-12
0.2
1.0
-
-
ND
-
ND
ND
ND
ND
ND
ND
5-Dec-12
0.2
1.0
-
-
ND
--
ND
ND
ND
0.65 1
ND
ND
12-1un-13
0.2
1.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
28-Oct-13
0.2
1.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
6-May-14
EPA 8260
0.2
1.0
-
-
ND
-
ND
ND
ND
0.3 J
ND
ND
22-Oct-14
EPA 8260
0.2
1.0
-
-
*
ND
ND
ND
ND
ND
ND
ND
21-May-15
EPA 8260
0.2
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Dec-15
EPA 8260
0.2
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
3-May-16
EPA 8260
0.2
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
13-Dec-16
EPA 8260
0.2
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
27-1un-17
EPA 8260
0.2
1.0
-
-
-
ND
ND
ND
ND
0.26 J
ND
ND
-
13-Dec-18
EPA 8260
0.2
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
4-Jun-18
EPA 8260
0.2
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
6-Dec-18
EPA 8260
0.2
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-May-19
EPA 8260D
0.51
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
8-Nov-19
EPA 8260D
0.31
1.0
ND
ND
ND
ND
ND
ND
ND
8-May-20
EPA 8260D
0.31
1.0
-
-
-
ND
ND
ND
ND
ND
ND
ND
ND
11-Nov-20
EPA 8260D
0.31
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
5-May-21
EPA 8260D
0.30
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
EPA 8260D
0.30
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
EPA 8260D
0.30
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
-
17-Nov-22
EPA 8260D
0.30
1.0
-
-
ND
ND
ND
ND
ND
ND
ND
-
--
6-Nov-23
EPA 8260D
0.30
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
--
Vinyl Chloride
30-May-07
0.62
1.0
-
ND
--
--
ND
0.46
1 1.6
ND
3.1
ND
NC 21 0.015 Ng/L (10/23/07)
29-Nov-07
0.62
1.0
-
0.42
J -
-
ND
ND
1.4
ND
1.9
ND
29-May-08
0.62
1.0
-
ND
-
-
ND
ND
1.2
ND
2.2
ND
6-Nov-08
0.62
1.0
-
0.63
1 -
--
ND
0.68
1 1.1
ND
1.8
ND
3-Jun-09
0.62
1.0
-
ND
-
---
ND
ND
0.95
1 ND
2.0
ND
18-Nov-09
0.62
1.0
-
0.69
1 -
--
ND
0.66
1 1.6
ND
2.5
ND
NC 21 0.03 Ng/L(01/01/10)
16-Jun-10
0.62
1.0
-
ND
-
--
ND
ND
1.1
ND
2.1
ND
1-Dec-10
0.62
1.0
-
ND
ND
---
ND
0.65
1 0.93
1 ND
3.5
ND
1-Jun-11
0.62
1.0
-
ND
ND
---
ND
0.87
1 1.1
ND
1.8
ND
20-Dec-11
0.62
1.0
-
-
ND
---
ND
0.63
1 ND
ND
1.4
ND
30-May-12
0.62
1.0
-
-
ND
--
ND
ND
ND
ND
1.6
ND
5-Dec-12
0.62
1.0
-
-
ND
--
ND
ND
ND
ND
ND
ND
12-1un-13
0.62
1.0
-
-
ND
--
ND
ND
0.96
1 ND
2.1
ND
28-Oct-13
0.62
1.0
-
-
ND
--
ND
ND
0.74
1 ND
1.3
ND
6-May-14
EPA 8260
0.62
1.0
-
-
ND
-
ND
ND
0.77
J ND
1.8
ND
22-Oct-14
EPA 8260
0.62
1.0
-
-
*
ND
ND
ND
ND
ND
1.3
ND
21-May-15
EPA 8260
0.62
1.0
-
-
-
ND
ND
ND
ND
ND
1.1
ND
8-Dec-15
EPA 8260
0.62
1.0
-
-
-
ND
ND
0.72
J ND
ND
1.4
ND
3-May-16
EPA 8260
0.62
1.0
-
-
-
ND
ND
ND
0.74
J ND
1.2
ND
ND
13-Dec-16
EPA 8260
0.62
1.0
-
-
-
ND
ND
ND
ND
ND
0.90 J
ND
ND
27-1un-17
EPA 8260
0.62
1.0
-
-
-
ND
ND
0.63
1 0.80
J ND
0.95 J
ND
-
13-Dec-18
EPA 8260
0.62
1.0
-
-
-
ND
ND
0.98
J ND
ND
0.83 J
ND
4-Jun-18
EPA 8260
0.62
1.0
-
-
-
ND
ND
ND
ND
ND
1.1
ND
6-Dec-18
EPA 8260
0.62
1.0
-
-
-
ND
ND
0.91
J 0.71
J ND
1.4
ND
8-May-19
EPA 8260D
0.6
0.0
-
-
-
ND
ND
1.1
0.85
1 ND
1.3
ND
8-Nov-19
EPA 8260D
0.2
1.0
-
-
-
ND
ND
ND
0.72
1 ND
ND
ND
8-May-20
EPA 8260D
0.4
1.0
-
-
-
ND
ND
0.87
J ND
ND
1.1
ND
ND
11-Nov-20
EPA 8260D
0.2
1.0
-
-
-
ND
ND
1.1
0.88
1 ND
1.3
-
ND
5-May-21
EPA 8260D
0.39
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
EPA 8260D
0.39
1.0
-
-
-
ND
ND
ND
0.84
J ND
ND
-
ND
19-May-22
EPA 8260D
0.39
1.0
-
-
-
ND
ND
0.91
J 0.67
J ND
0.9 J
-
-
17-Nov-22
EPA 8260D
0.39
1.0
-
-
ND
ND
ND
ND
0.75
J ND
0.9 J
-
-
6-Nov-23
EPA 8260D
0.39
1.0
-
-
-
ND
ND
ND
0.69
J ND
ND
-
-
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 25 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Sample
EPA
Analy[e
Collection Date
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-16D
Blanks
Xylene (Total)
1-Sep-94
--
5.0
ND
NI
NI
NI
ND
12
ND
ND
NI
NI
1Oct-94
-
5.0
--
NI
NI
NI
-
22
-
-
NI
NI
1-Jan-95
-
5.0
-
NI
NI
NI
ND
7.6
ND
ND
NI
NI
1-Feb-95
-
5.0
-
NI
NI
NI
ND
20
ND
ND
NI
NI
1-Mar-95
-
5.0
ND
NI
NI
NI
ND
24
ND
ND
NI
NI
1-Aug-95
-
5.0
ND
NI
NI
NI
ND
5
ND
ND
NI
NI
1-Jan-96
-
5.0
-
NI
-
-
ND
ND
ND
ND
NI
NI
1-Feb-96
-
5.0
-
NI
-
-
ND
ND
ND
ND
NI
NI
1-May-96
-
5.0
-
NI
-
-
ND
ND
ND
ND
NI
NI
1Oct-96
-
5.0
-
NI
-
--
ND
6
ND
ND
NI
NI
1-May-97
-
5.0
ND
NI
-
---
ND
9.2
4.3
1 ND
NI
NI
1-Nov-97
--
2.0
ND
NI
-
---
ND
ND
ND
ND
NI
NI
1-May-98
---
5.0
ND
NI
-
---
ND
5.6
ND
ND
NI
NI
24-Nov-98
---
2.0
ND
NI
-
---
ND
14.8
ND
ND
NI
NI
10-May-99
---
5.0
ND
ND
-
---
ND
13
ND
ND
ND
ND
18-Oct-99
---
5.0
ND
ND
-
---
ND
14
ND
ND
ND
ND
3-May-00
---
5.0
ND
ND
-
---
ND
17.5
ND
ND
ND
ND
7-Nov-00
---
5.0
ND
ND
-
---
ND
11
ND
ND
ND
ND
31-May-01
---
5.0
ND
ND
-
---
ND
10
9
10
ND
ND
7-Nov-01
--
5.0
ND
ND
-
---
ND
7.9
5.3
7.6
ND
ND
22-May-02
---
5.0
ND
ND
-
---
ND
5.3
8.5
14
ND
ND
14-Nov-02
---
5.0
ND
ND
-
---
ND
ND
21.3
12
ND
ND
14-May-03
---
5.0
ND
ND
-
---
ND
5.4
6.6
48
ND
ND
20-Nov-03
---
5.0
ND
ND
-
---
ND
ND
7.4
50
ND
ND
6-May-04
---
5.0
ND
ND
-
---
ND
ND
18.9
58
ND
ND
10-Nov-04
---
5.0
ND
ND
-
---
ND
ND
ND
54
ND
ND
27-May-05
---
5.0
11
ND
-
---
ND
ND
7
58
ND
ND
3-Nov-05
---
5.0
-
ND
-
---
ND
ND
26
119
ND
ND
25-May-06
---
5.0
-
ND
-
---
ND
ND
17.4
38.7
ND
ND
2-Nov-06
--
10.0
-
ND
-
---
ND
ND
ND
31
ND
ND
30-May-07
-
4.0
-
1.1 1
-
---
ND
2
1 24
34
1.2 1
ND
NC 2L = 530 pg/L (10/23/07)
29-Nov-07
-
5.0
-
2.7 J
-
--
ND
ND
3.9
J 24
ND
ND
29-May-08
0.89
10.0
-
1.7 1
-
--
ND
0.92
J 6.2
J 29.6
ND
ND
6-Nov-08
0.66
2.0
-
2.3
-
---
ND
0.78
J 2.8
28.7
ND
ND
3-Jun-09
0.66
2.0
-
1.6 1
-
---
ND
ND
4.7
46.5
ND
ND
18-Nov-09
0.66
2.0
-
5.7
-
--
ND
ND
3.1
40.3
ND
ND
NC 2L = 500 pg/L (01/01/10)
16-Jun-10
0.66
2.0
-
1.8 J
-
--
ND
1
J 5.2
40.3
ND
ND
1-Dec-10
0.66
2.0
-
2.3
ND
--
ND
ND
5.6
42.9
ND
ND
1-Jun-11
0.66
2.0
-
3.6
ND
-
ND
ND
0.88
1 44.1
ND
ND
20-Dec-11
0.66
2.0
-
-
ND
--
ND
ND
0.94
1 26.8
D ND
ND
30-May-12
0.66
2.0
-
-
ND
---
ND
ND
0.70
J 53.5
ND
ND
5-Dec-12
0.66
5.0
-
-
ND
--
ND
ND
2.4
1 43.6
ND
ND
12-1un-13
0.66
5.0
-
-
ND
-
ND
ND
ND
48.3
ND
ND
28-Oct-13
0.66
5.0
-
-
ND
--
ND
ND
ND
49.3
ND
ND
6-May-14
EPA 8260
0.66
5.0
-
-
ND
--
ND
ND
ND
40.7
ND
ND
22-Oct-14
EPA 8260
0.66
5.0
-
-
*
ND
ND
ND
ND
46.6
ND
ND
21-May-15
EPA 8260
0.66
5.0
-
-
-
ND
ND
ND
ND
43.6
ND
ND
8-Dec-15
EPA 8260
0.66
5.0
-
-
-
ND
ND
ND
ND
45.4
ND
ND
3-May-16
EPA 8260
0.66
5.0
-
-
-
ND
ND
ND
ND
72.4
ND
ND
ND
13-Dec-16
EPA 8260
0.66
5.0
-
-
-
ND
ND
ND
ND
63.8
ND
ND
ND
27-1un-17
EPA 8260
0.66
5.0
-
-
-
ND
ND
ND
ND
63.8
ND
ND
-
13-Dec-18
EPA 8260
0.66
5.0
-
-
-
ND
ND
ND
ND
65.9
ND
ND
4-Jun-18
EPA 8260
0.66
5.0
-
-
-
ND
ND
ND
ND
45.5
ND
ND
6-Dec-18
EPA 8260
0.66
1.0
-
-
-
ND
ND
ND
ND
73.6
ND
ND
8-May-19
EPA 8260D
1.5
2.0
-
-
-
ND
ND
ND
ND
122
ND
ND
8-Nov-19
EPA 8260D
0.6
1.0
-
-
-
ND
ND
ND
ND
99.6
ND
ND
8-May-20
EPA 8260D
0.6
1.0
-
-
-
ND
ND
ND
ND
90.9
ND
ND
ND
11-Nov-20
EPA 8260D
0.6
1.0
-
-
-
ND
ND
ND
ND
99.6
ND
-
ND
5-May-21
EPA 8260D
0.34
1.0
-
-
-
ND
ND
ND
ND
82.3
ND
-
ND
3-Nov-21
EPA 8260D
0.34
1.0
-
-
-
ND
ND
ND
ND
79.1
ND
-
ND
19-May-22
EPA8260D
0.34
1.0
-
-
-
ND
ND
ND
ND
80.7
ND
-
-
17-Nov-22
EPA8260D
0.34
1.0
-
-
ND
ND
ND
ND
ND
68.5
ND
-
--
6-Nov-23
EPA8260D
0.34
1.0
-
-
-
ND
ND
ND
2.8
53.5
ND
-
--
Diethyl phthalate
29-Nov-07
-
10.0
-
ND
-
--
1.7 1
2.3
1 2
1 ND
1.3 1
---
#
6-Nov-08
2.5
10.0
-
ND
-
---
ND
ND
ND
ND
ND
ND
NC 2L= 5,000 pg/L(10/23/07)
18-Nov-09
4
10.0
-
ND
-
-
ND
ND
ND
ND
ND
--
1-Dec-10
2.7
10.0
-
ND
ND
--
ND
ND
ND
ND
ND
--
20-Dec-11
0.58
10.0
-
-
ND
-
ND
ND
ND
ND
ND
-
5-Dec-12
0.58
6000
-
-
ND
-
ND
ND
ND
ND
ND
-
28-Oct-13
0.58
6000
-
-
ND
-
ND
ND
ND
ND
ND
--
22-Oct-14
0.91
6000
-
-
*
ND
ND
ND
ND
ND
ND
-
8-Dec-15
1.3
6000
-
-
-
ND
ND
ND
ND
ND
ND
-
6-Dec-18
EPA 8270
1.6
10
-
-
-
ND
ND
ND
ND
ND
ND
-
11-Nov-20
-
-
-
ND
ND
ND
ND
ND
ND
-
5-May-21
--
---
---
---
-
3-Nov-21
-
---
---
---
-
-
ND
ND
ND
ND
3.5
ND
-
ND
19-May-22
EPA 8270E
---
---
--
-
-
ND
ND
ND
ND
ND
ND
--
---
17-Nov-22
EPA 8270E
---
---
-
-
-
ND
ND
ND
ND
ND
ND
---
---
Naphthalene
29-Nov-07
-
10.0
-
ND
-
--
ND
ND
ND
1.3
1 ND
--
#
6-Nov-08
0.24
10.0
-
ND
-
--
ND
ND
ND
ND
ND
-
NC2L= 21 pg/L(10/23/07)
18-Nov-09
0.24
10.0
-
ND
-
-
ND
ND
ND
0.77
J ND
-
NC2L= 6 pg/L(01/01/10)
1-Dec-10
4
10.0
-
ND
ND
--
ND
ND
ND
0.96
J ND
-
20-Dec-11
0.34
10.0
-
-
ND
--
ND
ND
ND
0.84
1 ND
-
5-Dec-12
0.34
10.0
-
-
ND
-
ND
ND
ND
1.5
B ND
-
28-Oct-13
0.24
10.0
-
-
ND
-
ND
ND
ND
1.6
1 ND
-
22-Oct-14
EPA 8260
0.24
10.0
-
-
*
ND
ND
ND
ND
1.9
J ND
--
8-Dec-15
EPA 8260
0.24
10.0
-
-
-
ND
ND
ND
ND
2.2
1 ND
-
13-Dec-16
EPA 8260
0.24
10.0
-
-
-
ND
ND
ND
ND
2.6
J ND
-
0.26 J
6-Dec-18
EPA 8260
0.24
1.0
-
-
-
ND
ND
ND
ND
3.6
ND
-
8-Nov-19
EPA 8260D
0.35
1.0
-
-
-
ND
ND
ND
ND
3.3
ND
-
ND
11-Nov-20
EPA 8260D
0.35
1.0
-
-
-
ND
ND
ND
ND
4.8
ND
-
ND
5-May-21
--
-
-
-
-
-
-
-
-
-
-
-
-
-
3-Nov-21
EPA 8260D
0.64
1.0
-
-
-
ND
ND
ND
ND
3.5
ND
-
ND
19-May-22
EPA 8260D
0.64
1.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
17-Nov-22
EPA 8260D
0.64
1.0
-
-
-
ND
ND
ND
ND
3.9
ND
-
-
6-Nov-23
EPA 8260D
0.64
1.0
-
-
-
ND
ND
ND
ND
3.1
ND
-
-
Pentachlorophenol
29-Nov-07
--
25.0
-
ND
-
--
ND
ND
ND
0.420
1 ND
--
#
6-Nov-08
1.7
25.0
-
ND
-
-
ND
ND
ND
ND
ND
NC 2L 0.29 pg/L(10/23/07)
18-Nov-09
5
50.0
-
ND
-
-
ND
ND
ND
ND
ND
-
1-Dec-10
18
25.0
-
ND
ND
---
ND
ND
ND
ND
ND
---
20-Dec-11
4.6
25.0
-
-
ND
--
ND
ND
ND
ND
ND
--
5-Dec-12
4.6
25.0
-
-
ND
-
ND
ND
ND
ND
ND
-
28-Oct-13
4.6
25.0
-
-
ND
-
ND
ND
ND
ND
ND
-
22-Oct-14
EPA 8270
1.2
25.0
-
-
*
ND
ND
ND
ND
ND
ND
--
8-Dec-15
EPA 8270
2.3
25.0
-
-
-
ND
ND
ND
ND
ND
ND
-
13-Dec-16
EPA 8270
2.3
25.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
6-Dec-18
EPA 8270
3.5
25.0
-
-
-
ND
ND
ND
ND
ND
ND
-
8-Nov-19
EPA 8270E
2.2
25.0
-
-
-
ND
ND
ND
ND
ND
ND
-
11-Nov-20
EPA 8270E
3.8
20.0
-
-
-
ND
ND
ND
ND
ND
ND
-
-
5-May-21
EPA 8270E
3.8
20.0
-
-
-
-
-
-
-
-
-
-
-
3-Nov-21
EPA 8270E
3.8
20.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
EPA 8270E
3.8
20.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
17-Nov-22
EPA 8270E
3.8
20.0
-
-
-
ND
ND
ND
ND
ND
ND
-
-
6-Nov-23
EPA 8270E
3.1
16.7
-
-
-
ND
ND
ND
ND
ND
ND
-
-
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 26 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Sample
EPA
Analyte
Collection Date
Method
DL
RL
MW-9
MW47
MW-20
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-16D
Blanks
alpha-BHC
1-Oct-96
-
0.050
-
NI
-
-
ND
0.070
ND
ND
NI
NI
#
1-May-97
-
0.050
ND
NI
-
-
ND
ND
ND
ND
NI
NI
1-Nov-97
-
0.100
ND
NI
-
-
ND
ND
ND
ND
NI
NI
1-May-98
-
0.050
ND
NI
-
-
ND
ND
ND
ND
NI
NI
24-Nov-98
-
0.050
ND
NI
-
-
ND
ND
ND
ND
NI
NI
10-May-99
-
0.050
ND
ND
-
-
0.061
ND
ND
ND
ND
ND
18-Oct-99
-
0.050
ND
ND
-
-
-
ND
ND
ND
ND
ND
3-May-00
-
0.050
ND
-
-
-
ND
ND
-
-
-
-
7-Nov-00
-
0.050
ND
-
-
-
ND
ND
ND
ND
ND
-
7-Nov-01
-
0.050
ND
-
-
-
ND
ND
ND
ND
ND
-
14-Nov-02
-
0.050
ND
-
-
-
ND
ND
ND
ND
ND
-
20-Nov-03
-
0.050
ND
-
-
-
ND
ND
ND
ND
ND
-
10-Nov-04
-
0.050
ND
-
-
-
ND
ND
ND
ND
ND
-
3-Nov-05
-
0.050
-
ND
-
-
ND
ND
ND
ND
ND
-
2-Nov-06
-
0.050
-
ND
-
-
ND
ND
ND
ND
ND
-
GWPS = 0.006 pg/L (10/23/07)
29-Nov-07
-
0.050
-
ND
-
-
ND
ND
ND
ND
ND
-
6-Nov-08
0.05
0.050
-
ND
-
-
ND
ND
ND
ND
ND
-
18-Nov-09
0.00031
0.010
-
ND
-
-
ND
ND
ND
ND
ND
-
1-Dec-10
0.0003
0.050
-
ND
ND
-
ND
ND
ND
ND
ND
-
20-Dec-11
0.05
0.050
-
-
ND
-
ND
ND
ND
ND
ND
-
5-Dec-12
0.05
0.050
-
-
ND
-
ND
ND
ND
ND
ND
-
28-Oct-13
0.05
0.050
-
-
ND
-
ND
ND
ND
0.190
ND
-
Resample >
10-Dec-13
0.05
0.050
-
-
-
-
-
-
-
0.085
-
-
6-May-14
EPA 8081
0.05
0.050
-
-
ND
-
ND
ND
ND
0.070
ND
-
22-Oct-14
EPA 8081
0.05
0.050
-
-
*
ND
ND
ND
ND
ND
ND
-
21-May-15
EPA 8081
0.05
0.050
-
-
-
ND
ND
ND
ND
0.120
ND
-
8-Dec-15
EPA 8081
0.05
0.050
-
-
-
ND
ND
ND
ND
ND
ND
-
3-May-16
EPA 8081
0.05
0.050
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
13-Dec-16
EPA 8081
0.05
0.050
-
-
-
ND
ND
ND
ND
0.063
ND
-
ND
27-Jun-17
EPA 8081
0.05
0.050
-
-
-
ND
ND
ND
ND
0.110
ND
-
-
13-Dec-18
EPA 8081
0.05
0.050
-
-
-
ND
ND
ND
ND
0.093
ND
-
16-May-18
EPA 8081
0.05
0.050
-
-
-
ND
ND
ND
ND
0.072
ND
-
6-Dec-18
EPA 8081
0.05
0.050
-
-
-
ND
ND
ND
ND
ND
ND
-
8-May-19
EPA 8081B
0.019
0.05
-
-
-
-
ND
ND
ND
ND
ND
-
8-Nov-19
EPA 8081B
0.019
0.05
-
-
-
-
ND
ND
ND
ND
ND
-
8-May-20
EPA 8081B
0.019
0.05
-
-
-
ND
ND
ND
ND
ND
ND
-
-
11-Nov-20
EPA 8081B
0.019
0.05
-
-
-
ND
ND
ND
ND
ND
ND
-
-
5-May-21
EPA 8081B
0.026
0.05
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
3-Nov-21
EPA 8081B
0.0172
0.05
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
19-May-22
EPA 8081B
0.0172
0.05
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
17-Nov-22
EPA 8081B
0.0110
0.05
-
-
-
ND
ND
ND
ND
ND
ND
-
-
6-Nov-23
EPA 8081B
0.0100
0.04
-
-
-
ND
ND
ND
ND
ND
ND
-
-
beta-BHC
1-Dec-10
0.0005
0.050
-
ND
ND
-
ND
ND
0.019 J
ND
ND
-
# Resample>
13-Jan-11
0.0005
0.050
-
-
-
-
-
-
ND
-
-
-
GWPS= 0.019 pg/L(10/23/07)
20-Dec-11
0.05
0.050
-
-
ND
-
ND
ND
ND
ND
ND
-
5-Dec-12
0.05
0.050
-
-
ND
-
ND
ND
ND
ND
ND
-
28-Oct-13
0.05
0.050
-
-
ND
-
ND
ND
ND
ND
ND
-
22-Oct-14
EPA 8081
0.05
0.050
-
-
*
ND
ND
ND
ND
ND
ND
-
8-Dec-15
EPA 8081
0.05
0.050
-
-
-
ND
ND
0.16
ND
ND
ND
-
Resample >
4-Feb-16
EPA 8081
0.05
0.050
-
-
-
-
-
0.33
-
-
-
-
3-May-16
EPA 8081
0.05
0.050
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
13-Dec-16
EPA 8081
0.05
0.050
-
-
-
ND
ND
0.12
ND
ND
ND
-
ND
27-Jun-17
EPA 8081
0.05
0.050
-
-
-
ND
ND
ND
ND
ND
ND
-
-
13-Dec-18
EPA 8081
0.05
0.050
-
-
-
ND
ND
0.093
ND
ND
ND
-
16-May-18
EPA 8081
0.05
0.050
-
-
-
ND
ND
ND
ND
ND
ND
-
6-Dec-18
EPA 8081
0.05
0.050
-
-
-
ND
ND
ND
ND
ND
ND
-
8-May-19
EPA 8081B
0.014
0.05
-
-
-
-
ND
ND
ND
ND
ND
-
8-Nov-19
EPA 8081B
0.014
0.05
-
-
-
ND
ND
ND
ND
ND
ND
8-May-20
EPA 8081B
0.014
0.05
-
-
-
ND
ND
ND
ND
ND
ND
-
-
11-Nov-20
EPA 8081B
0.014
0.05
-
-
-
ND
ND
ND
ND
ND
ND
-
-
5-May-21
EPA 8081B
0.022
0.05
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
17-Nov-22
EPA 8081B
0.0440
0.05
-
-
-
ND
ND
ND
ND
ND
ND
-
-
6-Nov-23
EPA 8081B
0.0410
0.04
-
-
-
ND
ND
ND
ND
ND
ND
-
-
Delta-BHC
18-Oct-99
-
0.050
ND
ND
-
-
-
0.06 J
ND
ND
ND
ND
#
3-May-00
-
0.050
ND
-
-
-
ND
ND
-
-
-
-
7-Nov-00
-
0.050
ND
-
-
-
ND
ND
ND
ND
ND
-
7-Nov-01
-
0.050
ND
-
-
-
ND
ND
ND
ND
ND
-
14-Nov-02
-
0.050
ND
-
-
-
ND
ND
ND
ND
ND
-
20-Nov-03
-
0.050
ND
-
-
-
ND
ND
ND
ND
ND
-
10-Nov-04
-
0.050
ND
-
-
-
ND
ND
ND
ND
ND
-
3-Nov-05
-
0.050
-
ND
-
-
ND
ND
ND
ND
ND
-
2-Nov-06
-
0.050
-
ND
-
-
ND
ND
ND
ND
ND
-
GWPS= 0.019 pg/L(10/23/07)
29-Nov-07
-
0.050
-
ND
-
-
ND
ND
ND
ND
ND
-
6-Nov-08
0.05
0.050
-
ND
-
-
ND
ND
ND
ND
ND
-
18-Nov-09
0.00041
0.010
-
ND
-
-
ND
ND
ND
ND
ND
-
1-Dec-10
0.0004
0.050
-
ND
ND
-
ND
ND
ND
ND
ND
-
20-Dec-11
0.05
0.050
-
-
ND
-
ND
ND
ND
ND
ND
-
5-Dec-12
0.05
0.050
-
-
ND
-
ND
ND
ND
ND
ND
-
28-Oct-13
0.05
0.050
-
-
ND
-
ND
ND
ND
ND
ND
-
22-Oct-14
EPA 8081
0.05
0.050
-
-
*
ND
ND
ND
ND
ND
ND
-
8-Dec-15
EPA 8081
0.05
0.050
-
-
-
ND
ND
ND
ND
ND
ND
-
13-Dec-16
EPA 8081
0.05
0.050
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
6-Dec-18
EPA 8081
0.05
0.050
-
-
-
ND
ND
ND
ND
ND
ND
-
8-Nov-19
EPA 8081B
0.02
0.050
-
-
-
ND
ND
ND
ND
ND
ND
11-Nov-20
EPA 8081B
0.02
0.050
-
-
-
ND
ND
ND
ND
ND
ND
-
5-May-21
-
-
-
-
-
-
-
-
-
-
-
-
-
-
17-Nov-22
EPA 8081B
0.013
0.045
-
-
-
ND
ND
ND
ND
ND
ND
-
-
6-Nov-23
EPA 8081B
0.012
0.042
-
-
-
ND
ND
ND
ND
ND
ND
-
-
Gamma-BHC
18-Oct-99
-
0.050
ND
ND
-
-
-
0.08 J
ND
ND
ND
ND
(Lindane)
3-May-00
-
0.050
ND
-
-
-
ND
ND
-
-
-
-
#
7-Nov-00
-
0.050
ND
-
-
-
ND
ND
ND
ND
ND
-
7-Nov-01
-
0.050
ND
-
-
-
ND
ND
ND
ND
ND
-
14-Nov-02
-
0.050
ND
-
-
-
ND
ND
ND
ND
ND
-
20-Nov-03
-
0.050
ND
-
-
-
ND
ND
ND
ND
ND
-
10-Nov-04
-
0.050
ND
-
-
-
ND
ND
ND
ND
ND
-
3-Nov-05
-
0.050
-
ND
-
-
ND
ND
ND
ND
ND
-
2-Nov-06
-
0.050
-
ND
-
-
ND
ND
ND
ND
ND
-
NC2L= 0.2 pg/L(10/23/07)
29-Nov-07
-
0.050
-
ND
-
-
ND
ND
ND
ND
ND
-
6-Nov-08
0.05
0.050
-
ND
-
-
ND
ND
ND
ND
ND
-
18-Nov-09
0.00021
0.010
-
0.032
-
-
ND
ND
ND
ND
ND
-
Resample>
19-Jan-10
0.00021
0.010
-
ND
-
-
-
-
-
-
-
-
1-Dec-10
0.0002
0.050
-
ND
ND
-
ND
ND
0.034 J
ND
ND
-
Resample >
13-Jan-11
0.0002
0.050
-
-
-
-
-
-
0.048 J
-
-
-
20-Dec-11
0.05
0.050
-
-
ND
-
ND
ND
ND
ND
ND
-
5-Dec-12
0.05
0.050
-
-
ND
-
ND
ND
ND
ND
ND
-
28-Oct-13
0.05
0.050
-
-
ND
-
ND
ND
ND
ND
ND
-
22-Oct-14
0.05
0.050
-
-
*
ND
ND
ND
ND
ND
ND
-
8-Dec-15
0.05
0.050
-
-
-
ND
ND
ND
ND
ND
ND
-
6-Dec-18
EPA 8081
0.05
0.050
-
-
-
ND
ND
ND
ND
ND
ND
-
5-May-21
-
-
-
-
-
-
-
-
-
-
-
-
-
-
3-Nov-21
EPA 8081B
0.0209
0.05
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 27 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Sample
EPA
Analyte
Collection Date
Method
DL
RL
MW-9
MW-17
MW-20
MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-16D
Blanks
Heptachlor
18-Oct-99
--
0.050
ND
ND
---
---
-
0.11
J ND
ND
ND
ND
#
3-May-00
-
0.050
ND
---
---
---
ND
ND
-
---
---
---
7-Nov-01
-
0.050
ND
-
---
---
ND
ND
ND
ND
ND
---
14-Nov-02
-
0.050
ND
-
--
---
ND
ND
ND
ND
ND
--
20-Nov-03
-
0.050
ND
-
-
---
ND
ND
ND
ND
ND
--
10-Nov-04
-
0.050
ND
-
-
---
ND
ND
ND
ND
ND
--
3-Nov-05
-
0.050
-
ND
-
---
ND
ND
ND
ND
ND
---
2-Nov-06
-
0.050
-
ND
-
---
ND
ND
ND
ND
ND
---
NC2L= 0.007E pg/L(10/23/07)
29-Nov-07
-
0.050
-
ND
-
-
ND
ND
ND
ND
ND
--
6-Nov-08
0.05
0.050
-
ND
-
--
ND
ND
ND
ND
ND
--
18-Nov-09
0.0015
0.010
-
ND
-
--
ND
ND
ND
ND
ND
--
1-Dec-10
0.0015
0.050
-
ND
ND
--
ND
ND
ND
ND
ND
--
20-Dec-11
0.05
0.050
-
-
ND
--
ND
ND
ND
ND
ND
--
5-Dec-12
0.05
0.050
-
-
ND
-
ND
ND
ND
ND
ND
--
28-Oct-13
0.05
0.050
-
-
ND
-
ND
ND
ND
ND
ND
-
22-Oct-14
EPA 8081
0.05
0.050
-
-
*
ND
ND
ND
ND
ND
ND
-
8-Dec-15
EPA 8081
0.05
0.050
-
-
-
ND
ND
ND
ND
ND
ND
-
13-Dec-16
EPA 8081
0.05
0.050
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
6-Dec-18
EPA 8081
0.05
0.050
-
-
-
ND
ND
ND
ND
ND
ND
-
8-Nov-19
EPA 8081B
0.016
0.050
-
-
-
ND
ND
ND
ND
ND
ND
II-Nov-20
EPA 8081B
0.016
0.050
-
-
-
ND
ND
ND
ND
ND
ND
-
--
5-May-21
--
-
-
-
-
-
-
-
-
-
-
-
-
--
3-Nov-21
EPA 8270E
-
-
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
17-Nov-22
EPA 8270E
2
10
-
-
-
ND
ND
ND
ND
ND
ND
-
-
6-Nov-23
EPA 8081B
0.016
0.042
-
-
-
ND
ND
ND
ND
ND
ND
-
-
N-Nitroso-di-n-butylamine
22-Oct-14
EPA 8270
1.3
10.0
-
-
-
-
4.0 1
ND
ND
11.2
ND
-
# Resample>
22-Dec-14
1.3
10.0
-
-
-
-
-
-
-
ND
-
-
NC2L=NE (01/01/10)
S-Dec-15
EPA 8270
2.2
10.0
-
-
-
ND
ND
ND
ND
ND
ND
-
13-Dec-16
EPA 8270
2.2
10.0
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
6-Dec-18
EPA 8270
1.6
10.0
-
-
-
ND
ND
ND
ND
ND
ND
-
8-Nov-19
EPA 8270E
3.2
10.0
-
-
-
ND
ND
ND
ND
ND
ND
II-Nov-20
EPA 8270E
6.2
10.0
-
-
-
ND
ND
ND
ND
ND
ND
-
--
5-May-21
-
-
-
-
-
-
-
-
-
-
-
-
-
---
3-Nov-21
EPA 8270E
-
-
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
17-Nov-22
EPA 8270E
2
10
-
-
-
ND
ND
ND
ND
ND
ND
-
--
6-Nov-23
EPA 8270E
1.6
8.3
-
-
-
ND
ND
ND
ND
ND
ND
-
--
2,4-1)
1-Aug-95
-
0.3
ND
NI
---
---
ND
0.478
ND
ND
NI
NI
#
1-Jan-96
--
2.0
-
NI
-
---
ND
ND
ND
ND
NI
NI
1-Feb-96
--
2.0
-
NI
-
---
ND
ND
ND
ND
NI
NI
1-May-96
-
2.0
-
NI
--
---
ND
ND
ND
ND
NI
NI
1-Oct-96
-
0.5
-
NI
--
---
ND
ND
ND
ND
NI
NI
1-Nov-97
-
0.4
ND
NI
-
---
ND
ND
ND
ND
NI
NI
24-Nov-98
-
2.0
ND
NI
-
---
ND
ND
ND
ND
NI
NI
18-Oct-99
-
2.0
ND
ND
-
---
-
ND
ND
ND
ND
ND
7-Nov-01
-
2.0
ND
-
-
---
ND
ND
ND
ND
ND
-
14-Nov-02
-
2.0
ND
-
-
---
ND
ND
ND
ND
ND
---
20-Nov-03
-
2.0
ND
-
-
---
ND
ND
ND
ND
ND
--
10-Nov-04
-
2.0
ND
-
-
---
ND
ND
ND
ND
ND
-
3-Nov-05
-
2.0
-
ND
-
---
ND
ND
ND
ND
ND
-
2-Nov-06
-
2.0
-
ND
-
---
ND
ND
ND
ND
ND
-
NC2L= 70 pg/L(10/23/07)
29-Nov-07
-
2.0
-
ND
-
--
ND
1.4
J ND
ND
ND
-
6-Nov-OS
1
2.0
-
ND
-
---
ND
ND
ND
ND
ND
---
18-Nov-09
0.22
2.0
-
ND
-
---
ND
ND
ND
ND
ND
-
Resample>
19-Jan-10
0.23
1.0
-
ND
-
---
-
-
-
ND
-
-
1-Dec-10
0.22
2.0
-
ND
ND
---
ND
ND
ND
ND
ND
-
20-Dec-11
0.22
2.0
-
-
ND
---
ND
ND
ND
ND
ND
-
5-Dec-12
0.22
2.0
-
-
ND
---
ND
ND
ND
ND
ND
--
28-Oct-13
0.22
2.0
-
-
ND
--
ND
ND
ND
ND
ND
--
22-Oct-14
EPA 8151
0.23
0.96
-
-
*
ND
ND
ND
ND
ND
ND
--
8-Dec-15
EPA 8151
0.22
2.00
-
-
-
ND
ND
ND
ND
ND
ND
--
13-Dec-16
EPA 8151
0.22
2.00
-
-
-
ND
ND
ND
ND
ND
ND
---
ND
6-Dec-18
EPA 8151
0.31
0.95
-
-
-
ND
ND
ND
ND
ND
ND
--
8-Nov-19
EPA 815J.A
1.6
5.00
-
-
-
ND
ND
ND
ND
ND
ND
-
11-Nov-20
EPA 8151
0.547
2.00
-
-
-
ND
ND
ND
ND
ND
ND
-
-
5-May-21
-
-
-
-
-
-
-
-
-
-
-
-
-
--
3-Nov-21
EPA 8151
0.547
2
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
17-Nov-22
EPA 8321
1
2
-
-
-
ND
ND
ND
ND
ND
3.88
-
-
6-Nov-23
EPA 8151
0.547
2
-
-
-
ND
ND
ND
ND
ND
ND
-
-
2,4,5-TP(Silvex)
13-Dec-16
EPA 8151
0.049
2.00
-
-
-
ND
ND
0.14
J ND
ND
ND
-
ND
NC 21 = 50 pg/L (01/01/10)
6-Dec-18
EPA 8151
0.028
0.18
-
-
-
ND
ND
ND
ND
ND
ND
-
5-May-21
--
-
-
-
-
-
-
-
-
-
-
-
-
-
3-Nov-21
EPA 8151
0.335
2
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
17-Nov-22
EPA 8151
0.335
2
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
4,4'-DDD
1-Dec-10
0.0019
0.10
-
ND
ND
-
ND
0.019
J ND
ND
ND
-
# Resample>
13-Jan-11
0.0019
0.10
-
-
-
--
-
ND
-
-
-
-
NC2L= 0.1 pg/L (01/01/10)
20-Dec-11
0.05
0.05
-
-
ND
--
ND
ND
ND
ND
ND
-
5-Dec-12
0.05
0.10
-
-
ND
-
ND
ND
ND
ND
ND
-
2S-Oct-13
0.05
0.10
-
-
ND
-
ND
ND
ND
ND
ND
-
22-Oct-14
EPA 8081
0.05
0.10
-
-
*
ND
ND
ND
ND
ND
ND
-
8-Dec-15
EPA 8081
0.05
0.10
-
-
-
ND
ND
ND
ND
ND
ND
-
13-Dec-16
EPA 8081
0.05
0.10
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
6-Dec-18
EPA 8081
0.05
0.05
-
-
-
ND
ND
ND
ND
ND
ND
-
8-Nov-19
EPA 8081B
0.0069
0.05
-
-
-
ND
ND
ND
ND
ND
ND
-
11-Nov-20
EPA 8081B
0.0069
0.05
-
-
-
ND
ND
ND
ND
ND
ND
-
-
5-May-21
--
-
-
-
-
-
-
-
-
-
-
-
-
-
3-Nov-21
EPA 8081B
0.0154
0.05
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
17-Nov-22
EPA 8081B
0.022
0.045
-
-
-
ND
ND
ND
ND
ND
ND
-
-
6-Nov-23
EPA 8081B
0.014
0.042
-
-
-
ND
ND
ND
ND
ND
ND
-
-
4,4'-DDE
1-Dec-10
0.0009
0.10
-
ND
ND
-
ND
ND
ND
0.019 J
ND
-
# Resample >
13-Jan-11
0.0009
0.10
-
-
-
-
-
-
-
0.027 J
-
-
NC2L=NE (01/01/10)
20-Dec-11
0.05
0.05
-
-
ND
-
ND
ND
ND
ND
ND
-
5-Dec-12
0.05
0.10
-
-
ND
---
ND
ND
ND
ND
ND
---
28-Oct-13
0.05
0.10
-
-
ND
--
ND
ND
ND
ND
ND
-
22-Oct-14
EPA 8081
0.05
0.10
-
-
*
ND
ND
ND
ND
ND
ND
-
8-Dec-15
EPA 8081
0.05
0.10
-
-
-
ND
ND
ND
ND
ND
ND
-
13-Dec-16
EPA 8081
0.05
0.10
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
6-Dec-18
EPA 8081
0.05
0.05
-
-
-
ND
ND
ND
ND
ND
ND
-
8-Nov-19
EPA 8081B
0.0064
0.05
-
-
-
ND
ND
ND
ND
ND
ND
-
11-Nov-20
EPA 8081B
0.0064
0.05
-
-
-
ND
ND
ND
ND
ND
ND
-
-
5-May-21
--
-
-
-
-
-
-
-
-
-
-
-
-
--
3-Nov-21
EPA 8081B
0.0154
0.05
-
-
-
ND
ND
ND
ND
ND
ND
-
ND
17-Nov-22
EPA 8081B
0.022
0.045
-
-
-
ND
ND
ND
ND
ND
ND
-
-
6-Nov-23
EPA 8081B
0.02
0.042
-
-
-
ND
ND
ND
ND
ND
ND
-
-
1,2,4-Trichlorobenzene
6-Dec-18
EPA 8260
0.35
1
-
-
-
ND
ND
ND
ND
ND
0.35 1
-
NC2L=70 pg/L
S-Nov-19
EPA 8260D
0.22
1
-
-
-
ND
ND
ND
ND
ND
ND
-
11-Nov-20
EPA 8260D
0.22
1
-
-
-
ND
ND
ND
ND
ND
ND
-
--
5-May-21
-
-
-
-
-
-
-
-
-
-
-
-
--
---
3-Nov-21
EPA 8260D
0.64
1
-
-
-
ND
ND
ND
ND
ND
ND
---
ND
17-Nov-22
EPA 8260D
0.64
1
-
-
-
ND
ND
ND
ND
ND
ND
--
--
6-Nov-23
EPA 8260D
0.64
1
-
-
-
ND
ND
ND
ND
ND
ND
-
--
Dinoseb
6-Dec-18
EPA 8151
0.026
0.18
-
-
-
ND
ND
ND
ND
ND
0.058 J
-
IMAC=7 pg/L
8-Nov-19
EPA 815J.A
1.2
5
-
-
-
ND
ND
ND
ND
ND
ND
-
11-Nov-20
EPA 8151
0.25
2
-
-
-
ND
ND
ND
ND
ND
ND
-
--
5-May-21
-
-
-
-
-
-
-
-
-
-
-
-
---
---
3-Nov-21
EPA 8151
0.25
2
-
-
-
ND
ND
ND
ND
ND
ND
--
ND
17-Nov-22
EPA 8321
0.639
2
-
-
-
ND
ND
ND
ND
ND
ND
-
--
6-Nov-23
EPA 8151
0.25
2
-
---
--
ND
ND
ND
ND
ND
ND
-
--
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 28 of 29 March 2024

TABLE C-2: Historically Detected Groundwater Constituents
Analyte
Sample
Collection Date
EPA
Method
OIL
RL
MW-9
MW-17 MW-20 MW-21
MW-10
MW-11
MW-12
MW-13
MW-16S
MW-16D
Blanks
EndosulfanI
6-Dec-18
EPA 8081
0.05
0.05
ND
NO
ND
NO
0.064
ND
INC 2L=40 pg/L
8-Nov-19
EPA 8081B
0.0094
0.05
---
--- NO
NO
NO
NO
NO
NO
---
11-Nov-20
EPA 8081B
0.0094
0.05
--
- NO
NO
NO
NO
NO
NO
--
--
5-May-21
--
-
-
--
--- - -
-
-
-
-
-
--
--
3-Nov-21
EPA 8081B
0.016
0.05
-
- - NO
NO
NO
NO
NO
NO
-
NO
17-Nov-22
EPA 8081B
0.016
0.045
-
- - NO
NO
NO
NO
NO
NO
-
-
6-Nov-23
EPA 8081B
0.014
0.042
-
- - NO
NO
NO
NO
NO
NO
-
-
1,4-Dioxane(p-Dioxane)
6-Dec-18
EPA 8260
1.9
2
-
- - NO
NO
16.8
6.7
NO
5.5
NO
INC 2L = 3 pg/L
8-May-19
EPA 8260D Mod.
1.2
2.0
-
- - NO
NO
17.3
7.7
2.1
8.7
NO
8-Nov-19
EPA 8260D Mod.
1.2
2.0
-
- - NO
1.2 1
16.8
8.6
1.9
1 3.4
NO
8-May-20
EPA 8260D Mod.
1.2
2.0
-
- - NO
NO
18.5
8.6
1.5
1 5.1
NO
NO
11-Nov-20
EPA 8260D Mod.
1.2
2.0
-
- - NO
1.5 1
28.5
9.6
2.0
4.5
-
NO
5-May-21
EPA 8260DMod.
0.86
2.0
-
- - NO
0.9 1
29.6
9.6
1.6
1 7.9
-
NO
3-Nov-21
EPA 8260D Mod.
0.86
2.0
-
- - NO
1.1 1
26
9.7
1.5
5.3
-
NO
19-May-22
EPA 8260D Mod.
0.86
2.0
-
- - NO
1.1 1
30.4
9.2
1.3
1 11.7
-
---
17-Nov-22
EPA 8260D Mod.
0.86
2.0
-
- NO NO
1.7 1
28.8
10.2
1.1
1 10.8
-
---
6-Nov-23
EPA 8260D Mod.
0.86
2.0
--
- - NO
1 1
35.5
13.1
1.7
1 13.3
-
---
Notes:
All concentrations in micrograms per liter (pg/L) = parts per billion.
- = Not sampled for this parameter or not reported.
OIL = Laboratory Detection Limit.
RL = Reporting Limit (Lab. Reporting Limit for September 1994 -May 1999; NC PQL for October 1999 -December 2006; and SWSL for December 2006 -present).
J = Estimated value - concentration is less than the RL but greater than the DL.
B = Blank -Qualified (Similar concentrations detected in equipment, field, trip, or method blanks).
NO = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006).
INC 2L = Groundwater Standard from 15A NCAC 2L.0202.
GWPS = Groundwater Protection Standard set by NC-DENRSWS for constituents with no listed NC 2L standard - No longer used.
IMAC = INC Interim Maximum Allowable Concentration -for constituents with no listed NC 2L standard
NE = No INC 2L, GWPS, or IMAC established.
NI = Not Installed; monitoring was not yet installed.
AB = Monitoring well abandoned.
Values above the NC2L Standard, GWPS, or IMAC are bold.
D = Dilution factor >1
Notes (Event Narratives):
Volatile organics (8260) for MW-9 for November 10, 2004 sampling event were unable to be analyzed and were resampled on December 1, 2004.
There was a resamplinging event on August 2, 2007 for MW-16D because the prevoius samples from the May 2007 were analyzed out of hold time. There were no detects in the resample.
* MW-21 replaced MW-20 as the background well starting with the Fall 2014 sampling event; however MW-20 continues to be sampled as a compliance well for the C&D Expansion (Phase 1A).
See the Water Quality Monitrong Report for the C&D Expansion Area for current results for MW-20.
The dates on the table above reflect the last samples were collected during the semiannual monitoring event. Individual collection dates are preserved in the Lab Reports (Appendix B).
Burke County - Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 29 of 29 March 2024

TABLE C-3: Historically Detected Constituents in Performance and Sentinel Wells
Sample
EPA
Sentinel
Performance
Analyte
Collection Date
Method
MDL
MRL
Blanks
MW-18
MW-19
MW-36
MW-38
Organic Compounds
Acetone
3-Jun-09
2.2
100.0
7 J
ND
-
-
ND
18-Nov-09
2.2
100.0
--
-
-
-
ND
16-Jun-10
2.2
100.0
4.6 B
ND
-
-
7.20 J
1-Dec-10
2.2
100.0
--
-
-
-
3.70 J
1-Jun-11
2.2
100.0
8.7 B
ND
-
-
3.90 J
20-Dec-11
2.2
100.0
--
-
-
-
ND
30-May-12
2.2
100.0
-
-
-
-
ND
5-Dec-12
10.0
100.0
---
---
-
---
ND
18-Feb-13
10.0
100.0
---
-
19.8 J
ND
ND
12-Jun-13
10.0
100.0
---
-
-
---
ND
18-Jul-13
10.0
100.0
---
-
-
---
15.80 J
28-Oct-13
10.0
100.0
---
-
-
---
ND
NC 2L = 6,000 pg/I (01/01/10)
6-May-14
10.0
100.0
---
-
-
ND
ND
22-Oct-14
EPA 8261
10.0
100.0
---
---
-
ND
ND
21-May-15
EPA 8260
10.0
100.0
---
-
-
ND
ND
16-May-18
EPA 8260
10.0
100.0
---
-
-
ND
-
6-Dec-18
EPA 8260
10.0
25.0
-
-
-
ND
--
8-May-19
EPA 826OD
8.2
25.0
-
-
ND
ND
8-Nov-19
EPA 826OD
6.2
25.0
-
-
-
ND
--
8-May-20
EPA 826OD
6.2
25.0
-
-
-
ND
ND
11-Nov-20
EPA 826OD
6.2
25.0
-
-
ND
ND
ND
5-May-21
EPA 826OD
5.1
25.0
-
-
---
ND
3-Nov-21
EPA 826OD
5.1
25.0
-
-
--
ND
ND
19-May-22
EPA 826OD
5.1
25.0
-
-
10.80 J
ND
22-Nov-22
EPA 826OD
5.1
25.0
-
-
11.70 J
10.3 J
---
6-Nov-23
EPA 826OD
5.1
25.0
-
-
--
ND
-
Benzene
18-Feb-13
0.25
1.0
-
-
8.0
3.8
ND
NC 2L = 1 pg/I (01/01/10)
18-Jul-13
0.25
1.0
-
-
--
--
ND
28-Oct-13
0.25
1.0
ND
ND
--
--
ND
6-May-14
0.25
1.0
ND
ND
8.7
6.5
ND
22-Oct-14
EPA 8260
0.25
1.0
ND
ND
8.3
5.9
ND
21-May-15
EPA 8260
0.25
1.0
ND
ND
5.8
4.9
ND
8-Dec-15
EPA 8260
0.25
1.0
-
-
5.8
4.4
-
3-May-16
EPA 8260
0.25
1.0
ND
ND
6.7
5.4
-
13-Dec-16
EPA 8260
0.25
1.0
---
-
5.5
--
-
28-Jun-17
EPA 8260
0.25
1.0
-
-
20.1
--
-
12-Dec-17
EPA 8260
0.25
1.0
ND
ND
5.3
5.0
-
16-May-18
EPA 8260
0.25
1.0
-
-
-
4.6
-
6-Dec-18
EPA 8260
0.25
1.0
ND
ND
5.0
5.6
ND
8-May-19
EPA 826OD
0.2
1.0
-
-
6.8
7.3
ND
8-Nov-19
EPA 826OD
0.15
1.0
ND
ND
4.0
2.5
-
8-May-20
EPA 826OD
0.15
1.0
-
-
4.0
4.0
ND
11-Nov-20
EPA 826OD
6.2
25.0
ND
ND
4.0
4.7
ND
5-May-21
EPA 826OD
0.34
1.0
-
-
3.8
5.6
ND
3-Nov-21
EPA 826OD
0.34
1.0
ND
ND
4.1
3.7
ND
19-May-22
EPA 826OD
0.34
1.0
-
-
2.7
4.0
22-Nov-22
EPA 826OD
0.34
1.0
ND
ND
ND
4.2
-
6-Nov-23
EPA 826OD
0.34
1.0
ND
ND
3.4
3.5
-
Chlorobenzene
18-Feb-13
EPA 8257
0.23
3.0
-
-
0.76 J
0.38 J
ND
18-Jul-13
EPA 8258
0.23
3.0
-
-
--
--
ND
NC 2L = 50 pg/I (10/23/07)
6-May-14
EPA 8259
0.23
3.0
-
-
0.60 J
ND
22-Oct-14
EPA 8260
0.23
3.0
-
-
0.61 J
ND
21-May-15
EPA 8260
0.23
3.0
-
-
0.51 J
ND
16-May-18
EPA 8260
0.23
3.0
-
-
0.70 J
---
6-Dec-18
EPA 8260
0.23
1.0
-
-
0.83 J
---
8-May-19
EPA 826OD
0.53
1.0
---
---
-
0.99 J
ND
8-Nov-19
EPA 826OD
0.23
1.0
---
---
-
0.40 J
---
8-May-20
EPA 826OD
0.23
1.0
---
---
--
0.60 J
ND
11-Nov-20
EPA 826OD
0.23
1.0
---
---
0.80 J
0.67 J
ND
5-May-21
EPA 826OD
0.28
1.0
---
---
---
--
ND
3-Nov-21
EPA 826OD
0.28
1.0
---
---
---
0.59 J
ND
19-May-22
EPA 826OD
0.28
1.0
---
---
ND
ND
22-Nov-22
EPA 826OD
0.28
1.0
---
---
ND
ND
--
6-Nov-23
EPA 826OD
0.28
1.0
---
---
---
0.81 J
---
Chloroethane
3-Jun-09
0.5
10.0
4.3 J
ND
-
-
ND
18-Nov-09
0.5
10.0
2.9 J
0.90 J
-
-
ND
NC 2L = 3,000 pg/I (01/01/10)
16-Jun-10
0.5
10.0
2.6 J
0.80 J
---
-
ND
1-Dec-10
0.5
10.0
--
--
-
ND
1-Jun-II
0.5
10.0
3.6 J
0.85 J
---
-
ND
20-Dec-11
0.5
10.0
--
---
---
-
ND
30-May-12
0.5
10.0
-
---
---
-
ND
5-Dec-12
0.5
10.0
-
-
-
ND
18-Feb-13
EPA 8257
0.54
10.0
-
-
1.1 J
ND
ND
12-Jun-13
0.5
10.0
-
-
---
---
ND
18-Jul-13
EPA 8258
0.54
10.0
-
-
-
ND
29-Oct-13
0.5
10.0
-
-
-
ND
6-May-14
EPA 8259
0.54
10.0
-
---
---
ND
ND
22-Oct-14
EPA 8260
0.54
10.0
-
-
---
ND
ND
21-May-15
EPA 8260
0.54
10.0
-
-
---
ND
ND
16-May-18
EPA 8260
0.54
10.0
-
-
---
ND
--
6-Dec-18
EPA 8260
0.54
1.0
-
---
---
ND
-
8-May-19
EPA 826OD
0.52
1.0
-
-
---
ND
ND
8-Nov-19
EPA 826OD
0.49
1.0
-
-
---
ND
-
8-May-20
EPA 826OD
0.49
1.0
-
-
---
ND
ND
11-Nov-20
EPA 826OD
0.49
1.0
-
-
ND
ND
ND
5-May-21
EPA 826OD
0.65
1.0
-
-
-
-
ND
3-Nov-21
EPA 826OD
0.65
1.0
-
-
-
ND
ND
19-May-22
EPA 826OD
0.65
1.0
-
-
ND
ND
22-Nov-22
EPA 826OD
0.65
1.0
-
-
ND
ND
-
6-Nov-23
EPA 826OD
0.65
1.0
-
-
ND
--
Burke Co. - Johns River C+D-over-MSWLF LaBella Associates
Permit No. 12-03 Page 1 of 7 March 2024

TABLE C-3: Historically Detected Constituents in Performance and Sentinel Wells
Sample
EPA
Sentinel
Performance
Analyte
collection Date
Method
MDL
MRL
Blanks
MW-18
MW-19
MW-36
MW-38
1,2-Dichlorobenzene
18-Feb-13
0.30
5.0
-
-
0.44 J
ND
ND
18-Jul-13
0.30
5.0
-
-
--
--
ND
NC 2L = 20 pg/I (01/01/10)
6-May-14
EPA 8260
0.30
5.0
-
-
-
0.36 J
ND
22-Oct-14
EPA 8261
0.30
5.0
-
-
-
0.31 J
ND
21-May-15
EPA 8260
0.30
5.0
-
-
-
ND
ND
16-May-18
EPA 8260
0.30
5.0
-
-
-
0.34 J
---
6-Dec-18
EPA 8260
0.30
1.0
ND
ND
--
ND
-
8-May-19
EPA 8260D
0.49
1.0
-
-
-
ND
ND
8-Nov-19
EPA 8260D
0.29
1.0
-
-
-
ND
-
8-May-20
EPA 8260D
0.29
1.0
-
-
--
ND
ND
11-Nov-20
EPA 8260D
0.29
1.0
-
-
0.50 J
0.38 J
ND
5-May-21
EPA 8260D
0.34
1.0
-
-
--
--
ND
3-Nov-21
EPA 8260D
0.34
1.0
-
-
--
ND
ND
19-May-22
EPA 8260D
0.34
1.0
-
-
0.51 J
0.40 J
22-Nov-22
EPA 8260D
0.34
1.0
-
-
0.44 J
ND
---
6-Nov-23
EPA 8260D
0.34
1.0
-
-
--
0.37 J
---
1,4-Dichlorobenzene
18-Feb-13
0.33
1.0
-
-
18.0
7.8
ND
18-Jul-13
0.33
1.0
-
-
--
--
ND
28-Oct-13
0.33
1.0
ND
ND
--
---
ND
6-May-14
0.33
1.0
ND
ND
10.0
13.5
ND
22-Oct-14
EPA 8260
0.33
1.0
ND
ND
15.2
12.9
ND
NC 2L = 6 pg/I (02/1/15)
21-May-15
EPA 8260
0.33
1.0
ND
ND
18.7
12.3
ND
8-Dec-15
0.33
1.0
-
-
5.8
4.4
ND
3-May-16
0.33
1.0
ND
ND
6.7
5.4
ND
14-Dec-16
0.33
1.0
-
-
5.5
3.0
ND
27-Jun-17
EPA 8260
0.33
1.0
-
-
20.1
12.2 J
ND
15-Dec-17
EPA 8260
0.33
1.0
ND
ND
5.3
ND
ND
16-May-18
EPA 8260
0.33
1.0
-
-
19.1
15.1
-
6-Dec-18
EPA 8260
0.33
1.0
ND
ND
17.2
16.9
ND
8-May-19
EPA 8260D
0.58
1.0
-
---
19.2
22.1
ND
8-Nov-19
EPA 8260D
0.26
1.0
ND
ND
15.4
7.4
-
8-May-20
EPA 8260D
0.26
1.0
-
-
15.4
10.9
ND
11-Nov-20
EPA 8260D
0.29
1.0
ND
ND
15.2
14.0
ND
5-May-21
EPA 8260D
0.33
1.0
-
---
13.8
16.5
ND
3-Nov-21
EPA 8260D
0.33
1.0
ND
ND
ND
12.4
ND
19-May-22
EPA 8260D
0.33
1.0
-
-
17.0
17.0
22-Nov-22
EPA 8260D
0.33
1.0
ND
ND
ND
16.8
-
6-Nov-23
EPA 8260D
0.33
1.0
ND
ND
19.0
18.6
-
1,1-Dichloroethane
3-Jun-09
0.3
5.0
3.9 J
2.8 J
---
-
ND
18-Nov-09
0.3
5.0
6.7
3.7 J
---
-
ND
16-Jun-10
0.3
5.0
4.4 J
2.3 J
---
-
ND
1-Dec-10
0.3
5.0
--
--
-
ND
1-Jun-II
0.3
5.0
2.8 J
2.6 J
---
-
ND
20-Dec-11
0.3
5.0
--
--
-
ND
30-May-12
0.3
5.0
1.6 J
2.7 J
---
-
ND
5-Dec-12
0.3
5.0
--
---
---
-
ND
18-Feb-13
0.32
5.0
-
---
7.9
9.1
ND
12-Jun-13
0.3
5.0
-
---
---
-
ND
18-Jul-13
0.32
5.0
--
---
---
-
ND
28-Oct-13
0.3
5.0
0.93 J
3.0 J
---
--
ND
NC 2L = 6 pg/I (01/01/10)
6-May-14
0.32
5.0
1.2 J
2.9 J
11.6
8.1
ND
22-Oct-14
EPA 8260
0.32
5.0
--
---
9.0
6.9
ND
21-May-15
EPA 8260
0.32
5.0
ND
1.7 J
4.8 J
5.5
ND
8-Dec-15
0.32
5.0
--
---
5.9
7.2
ND
3-May-16
0.32
5.0
0.4 J
2.5 J
5.9
6.5
ND
14-Dec-16
0.32
5.0
--
--
4.4 J
6.0
ND
27-Jun-17
EPA 8260
0.32
5.0
---
--
4.3 J
6.2
ND
15-Dec-17
0.32
5.0
0.5 J
2.5 J
3.1 J
ND
ND
16-May-18
EPA 8260
0.32
5.0
NM
NM
3.8 J
4.1 J
--
6-Dec-18
EPA 8260
0.32
1.0
ND
1.9
3.6
5.2
ND
8-May-19
EPA 8260D
0.41
1.0
-
--
4.6
6.7
ND
8-Nov-19
EPA 8260D
0.27
1.0
ND
2.4
3.1
4.3
-
8-May-20
EPA 8260D
0.27
1.0
--
--
2.7
3.7
ND
11-Nov-20
EPA 8260D
0.27
1.0
0.37 J
1.1
2.5
4.1
ND
5-May-21
EPA 8260D
0.37
1.0
--
--
2.2
4.2
ND
3-Nov-21
EPA 8260D
0.37
1.0
ND
0.98 J
1.3
3.0
ND
19-May-22
EPA 8260D
0.37
1.0
-
--
1.2
3.0
22-Nov-22
EPA 8260D
0.37
1.0
ND
0.63 J
ND
3.1
---
6-Nov-23
EPA 8260D
0.37
1.0
ND
0.54 J
1.3
2.2
---
Burke Co. - Johns River C+D-over-MSWLF LaBella Associates
Permit No. 12-03 Page 2 of 7 March 2024

TABLE C-3: Historically Detected Constituents in Performance and Sentinel Wells
Sample
EPA
Sentinel
Performance
Analyte
Collection Date
Method
MDL
MRL
Blanks
MW-18
MW-19
MW-36
MW-38
1,2-Dichloroethane
3-Jun-09
0.1
1.0
0.33 J
ND
-
-
ND
18-Nov-09
0.1
1.0
0.56 J
ND
-
-
ND
16-Jun-10
0.1
1.0
0.37 J
ND
-
-
ND
1-Dec-10
0.1
1.0
--
-
-
-
ND
1-Jun-11
0.1
1.0
0.34 J
ND
-
-
ND
20-Dec-11
0.1
1.0
--
-
-
-
ND
30-May-12
0.1
1.0
ND
ND
-
-
ND
5-Dec-12
0.1
1.0
-
-
-
-
ND
18-Feb-13
0.12
1.0
-
-
1.0
0.59 J
ND
12-Jun-13
0.1
1.0
-
-
-
-
ND
18-Jul-13
0.12
1.0
-
-
-
ND
28-Oct-13
0.1
1.0
ND
ND
--
-
ND
NC 2L = 0.4 pg/I (01/01/10)
6-May-14
0.12
1.0
ND
ND
0.78 J
ND
ND
22-Oct-14
EPA 8260
0.12
1.0
-
-
0.92 J
0.63 J
ND
21-May-15
EPA 8260
0.12
1.0
ND
ND
ND
ND
ND
8-Dec-15
0.12
1.0
-
-
0.66 J
0.70 J
ND
3-May-16
0.12
1.0
ND
ND
0.92 J
0.74 J
ND
14-Dec-16
0.12
1.0
-
-
ND
ND
ND
27-Jun-17
EPA 8260
0.24
1.0
-
-
0.75 J
0.67 J
ND
15-Dec-17
0.24
1.0
ND
ND
ND
ND
ND
16-May-18
EPA 8260
0.24
1.0
-
---
0.73 J
0.64 J
---
6-Dec-18
EPA 8260
0.24
1.0
ND
ND
ND
ND
ND
8-May-19
EPA 8260D
0.67
1.0
-
-
ND
0.82 J
ND
8-Nov-19
EPA 8260D
0.34
1.0
ND
ND
0.65 J
0.63 J
---
8-May-20
EPA 8260D
0.34
1.0
-
---
0.58 J
0.49 J
ND
11-Nov-20
EPA 8260D
0.34
1.0
ND
ND
0.63 J
0.52 J
ND
5-May-21
EPA 8260D
0.32
1.0
-
-
ND
ND
ND
3-Nov-21
EPA 8260D
0.32
1.0
ND
ND
ND
ND
ND
19-May-22
EPA 8260D
0.32
1.0
-
-
0.37 J
ND
22-Nov-22
EPA 8260D
0.32
1.0
ND
ND
ND
ND
--
6-Nov-23
EPA 8260D
0.32
1.0
ND
ND
ND
ND
-
1,4-Dioxane (p-Dioxane)
6-Dec-18
EPA 8260
1.9
2.0
-
---
ND
2.40
ND
NC 2L = 3 pg/I (06/01/2018)
8-May-19
EPA 8260D Mod.
1.2
2.0
--
---
ND
2.50
ND
8-Nov-19
EPA 8260D Mod.
1.2
2.0
3.0
ND
ND
2.20
--
8-May-20
EPA 8260D Mod.
1.2
2.0
--
-
ND
2.70
-
11-Nov-20
EPA 8260D Mod.
1.2
2.0
2.6
ND
--
2.70
ND
5-May-21
EPA 8260D Mod.
0.86
2.0
--
-
ND
3.5
ND
3-Nov-21
EPA 8260D Mod.
0.86
2.0
4.0
ND
ND
3.5
ND
Resample ->
17-Feb-22
EPA 8260D Mod.
0.86
2.0
4.7
-
-
--
-
19-May-22
EPA 8260D Mod.
0.86
2.0
--
-
ND
5.7
22-Nov-22
EPA 8260D Mod.
0.86
2.0
3.2
ND
ND
7.1
-
6-Nov-23
EPA 8260D Mod.
0.86
2.0
3.8
ND
--
7.5
ND
cis-1,2-Dichloroethene
3-Jun-09
0.2
5.0
3.9 J
ND
-
-
ND
(cis-1,2-Dichloroethylene)
18-Nov-09
0.2
5.0
5.7 B
ND
-
-
2.60 J
16-Jun-10
0.2
5.0
4.5 J
ND
-
-
ND
1-Dec-10
0.2
5.0
--
-
-
-
ND
1-Jun-11
0.2
5.0
4.6 J
ND
-
-
ND
20-Dec-11
0.2
5.0
--
-
-
-
ND
30-May-12
0.2
5.0
-
-
-
-
ND
5-Dec-12
0.2
5.0
-
-
-
-
ND
18-Feb-13
0.19
5.0
-
-
21.0
15.6
ND
12-Jun-13
0.2
5.0
-
-
-
ND
18-Jul-13
0.19
5.0
-
-
--
ND
NC 2L = 70 pg/I (10/23/07)
6-May-14
0.19
5.0
-
-
17.1
ND
22-Oct-14
0.19
5.0
-
-
16.3
ND
21-May-15
EPA 8260
0.19
5.0
-
-
12.1
ND
27-Jun-17
EPA 8260
0.2
5.0
-
-
10.9
ND
16-May-18
EPA 8260
0.2
5.0
-
-
7.1
--
6-Dec-18
EPA 8260
0.2
2.0
-
---
ND
6.9
ND
8-May-19
EPA 8260D
0.7
1.0
-
-
7.8
ND
8-Nov-19
EPA 8260D
0.3
1.0
-
-
7.1
-
8-May-20
EPA 8260D
0.3
1.0
-
--
7.9
ND
11-Nov-20
EPA 8260D
0.3
1.0
-
---
12.7
8.1
ND
5-May-21
EPA 8260D
0.38
1.0
-
--
--
ND
3-Nov-21
EPA 8260D
0.38
1.0
-
--
5.2
ND
19-May-22
EPA 8260D
0.38
1.0
-
---
7.7
1.2
22-Nov-22
EPA 8260D
0.38
1.0
-
---
8.6
1.5
-
6-Nov-23
EPA 8260D
0.38
1.0
-
--
1.5
-
Ethylbenzene
18-Feb-13
0.30
1.0
-
---
23.2
1.4
ND
18-Jul-13
0.30
1.0
-
--
--
ND
NC 2L = 600 pg/I (01/01/10)
6-May-14
0.30
1.0
-
-
1.3
ND
22-Oct-14
0.30
1.0
-
-
1.3
ND
21-May-15
EPA 8260
0.30
1.0
-
-
1.1
ND
16-May-18
EPA 8260
0.30
1.0
-
-
0.70 J
---
6-Dec-18
EPA 8260
0.30
1.0
-
-
0.86 J
ND
8-May-19
EPA 8260D
0.45
1.0
-
-
1.60
ND
8-Nov-19
EPA 8260D
0.26
1.0
-
-
-
ND
--
8-May-20
EPA 8260D
0.26
1.0
-
-
--
0.79 J
ND
11-Nov-20
EPA 8260D
0.26
1.0
-
-
0.69 J
1.4
---
5-May-21
EPA 8260D
0.30
1.0
-
-
--
--
ND
3-Nov-21
EPA 8260D
0.30
1.0
-
-
--
1.1
ND
19-May-22
EPA 8260D
0.30
1.0
-
-
13.0
3.5
22-Nov-22
EPA 8260D
0.30
1.0
-
-
1.8
2.5
-
6-Nov-23
EPA 8260D
0.30
1.0
-
-
--
1.7
-
Burke Co. - Johns River C+D-over-MSWLF LaBella Associates
Permit No. 12-03 Page 3 of 7 March 2024

TABLE C-3: Historically Detected Constituents in Performance and Sentinel Wells
Sample
EPA
Sentinel
Performance
Analyte
collection Date
Method
MDL
MRL
Blanks
MW-18
MW-19
MW-36
MW-38
Methylene Chloride
18-Feb-13
0.97
1.0
-
-
17.9
ND
ND
18-Jul-13
0.97
1.0
-
-
--
-
ND
28-Oct-13
0.97
1.0
ND
ND
--
--
ND
NC 2L = 5 pg/I (01/01/10)
6-May-14
0.97
1.0
-
-
24.1
1.7
2.20
22-Oct-14
EPA 8260
0.97
1.0
-
---
15.7
ND
ND
21-May-15
EPA 8260
0.97
1.0
ND
ND
9.5 B
ND
1.7
8-Dec-15
0.97
1.0
-
-
11.2 B
ND
2.0
3-May-16
0.97
1.0
ND
ND
3.1
ND
ND
14-Dec-16
0.97
1.0
-
---
ND
ND
ND
27-Jun-17
EPA 8260
0.97
1.0
-
-
ND
ND
ND
15-Dec-17
0.97
1.0
ND
ND
ND
ND
ND
16-May-18
EPA 8260
0.97
1.0
-
-
ND
ND
--
6-Dec-18
EPA 8260
0.97
1.0
ND
ND
ND
ND
-
8-May-19
EPA 8260D
0.5
1.0
-
-
2.1
ND
ND
8-Nov-19
EPA 8260D
3.7
5.0
ND
ND
ND
ND
-
8-May-20
EPA 8260D
3.7
5.0
-
-
ND
ND
ND
11-Nov-20
EPA 8260D
3.7
5.0
ND
ND
ND
ND
ND
5-May-21
EPA 8260D
2
5.0
-
-
ND
ND
ND
3-Nov-21
EPA 8260D
2
5.0
ND
ND
ND
ND
ND
19-May-22
EPA 8260D
2
5.0
-
-
ND
ND
22-Nov-22
EPA 8260D
2
5.0
ND
ND
ND
ND
-
6-Nov-23
EPA 8260D
2
5.0
ND
ND
ND
ND
--
Naphthalene
11-Nov-20
EPA 8260D
0.35
1.0
--
--
--
3.70
ND
3-Nov-21
EPA 8260D
0.64
1.0
-
-
-
ND
ND
NC 2L = 6 pg/I (01/01/10)
5-May-21
--
--
---
--
--
--
--
--
Tetrachloroethene
18-Feb-13
0.46
1.0
-
-
5.5
ND
ND
18-Jul-13
0.46
1.0
-
-
--
-
ND
28-Oct-13
0.46
1.0
ND
ND
--
--
ND
NC 2L = 0.7 pg/I (10/23/07)
6-May-14
0.46
1.0
-
-
7.9
ND
ND
22-Oct-14
EPA 8260
0.46
1.0
-
-
7.3
ND
ND
21-May-15
EPA 8260
0.46
1.0
ND
ND
6.0
ND
ND
8-Dec-15
0.46
1.0
-
-
5.0
ND
ND
3-May-16
0.46
1.0
ND
ND
4.5
ND
ND
14-Dec-16
0.46
1.0
-
-
ND
ND
ND
27-Jun-17
EPA 8260
0.46
1.0
-
-
ND
ND
ND
15-Dec-17
0.46
1.0
ND
ND
ND
ND
ND
16-May-18
EPA 8260
0.46
1.0
---
---
3.6
ND
-
6-Dec-18
EPA 8260
0.46
1.0
ND
ND
2.9
ND
--
8-May-19
EPA 8260D
0.78
1.0
-
-
4.4
ND
ND
8-Nov-19
EPA 8260D
0.16
1.0
ND
ND
2.0
ND
--
8-May-20
EPA 8260D
0.16
1.0
-
-
2.4
ND
ND
11-Nov-20
EPA 8260D
0.16
1.0
ND
ND
2.3
ND
ND
5-May-21
EPA 8260D
0.29
1.0
-
---
2.0
ND
ND
3-Nov-21
EPA 8260D
0.29
1.0
ND
ND
1.6
ND
ND
19-May-22
EPA 8260D
0.29
1.0
-
-
1.5
ND
22-Nov-22
EPA 8260D
0.29
1.0
ND
ND
ND
ND
--
6-Nov-23
EPA 8260D
0.29
1.0
ND
ND
1.0
ND
-
Toluene
3-Jun-09
0.3
1.0
ND
ND
-
-
ND
18-Nov-09
0.3
1.0
2.3
ND
-
-
ND
16-Jun-10
0.3
1.0
0.29 J
ND
---
-
ND
1-Dec-10
0.3
1.0
--
-
-
-
ND
1-Jun-11
0.3
1.0
ND
ND
-
-
ND
20-Dec-11
0.3
1.0
-
-
-
-
ND
30-May-12
0.3
1.0
-
-
-
ND
5-Dec-12
0.3
1.0
-
-
---
-
ND
18-Feb-13
0.26
1.0
-
-
44.10
0.77 J
ND
12-Jun-13
0.3
1.0
-
-
--
--
ND
18-Jul-13
0.26
1.0
-
-
-
-
ND
28-Oct-13
0.30
1.0
-
-
-
--
ND
NC 2L = 600 pg/I (01/01/10)
6-May-14
0.26
1.0
-
-
-
0.68 J
ND
22-Oct-14
0.26
1.0
-
-
-
0.66 J
ND
21-May-15
EPA 8260
0.26
1.0
-
-
-
0.48 J
ND
16-May-18
EPA 8260
0.26
1.0
-
-
-
0.54 J
---
6-Dec-18
EPA 8260
0.26
1.0
-
-
-
ND
-
8-May-19
EPA 8260D
0.31
1.0
-
-
-
1.9
ND
8-Nov-19
EPA 8260D
0.24
1.0
-
-
-
ND
-
8-May-20
EPA 8260D
0.24
1.0
-
-
-
0.45 J
ND
11-Nov-20
EPA 8260D
0.24
1.0
-
-
ND
0.64 J
ND
5-May-21
EPA 8260D
0.48
1.0
-
-
-
--
ND
3-Nov-21
EPA 8260D
0.48
1.0
-
-
--
ND
ND
19-May-22
EPA 8260D
0.48
1.0
-
-
1.40
1.40
22-Nov-22
EPA 8260D
0.24
1.0
-
-
0.42 J
1.00
---
6-Nov-23
EPA 8260D
0.24
1.0
-
-
--
0.60 J
---
Tetrahydrofuran
27-Jun-17
EPA 8260
3.1
10.0
-
-
-
3.1 J
---
NC 2L = NE
16-May-18
EPA 8260
3.1
NE
-
-
-
314
-
6-Dec-18
EPA 8260
3.1
10.0
-
-
-
447
--
8-May-19
EPA 8260D
1.3
10.0
-
-
-
470
ND
8-Nov-19
EPA 8260D
1.9
10.0
-
-
-
ND
--
8-May-20
EPA 8260D
1.9
10.0
-
-
-
95.3
ND
5-May-21
EPA 8260D
3.5
10.0
-
-
-
--
ND
3-Nov-21
EPA 8260D
3.5
10.0
-
-
-
ND
-
19-May-22
EPA 8260D
3.5
10.0
-
-
250.0
645.0
22-Nov-22
EPA 8260D
3.5
10.0
-
-
161.0
702.0
-
6-Nov-23
EPA 8260D
3.5
10.0
-
-
ND
--
Burke Co. - Johns River C+D-over-MSWLF LaBella Associates
Permit No. 12-03 Page 4 of 7 March 2024

TABLE C-3: Historically Detected Constituents in Performance and Sentinel Wells
Sample
EPA
Sentinel
Performance
Analyte
collection Date
Method
MDL
MRL
Blanks
MW-18
MW-19
MW-36
MW-38
Trichloroethene
18-Feb-13
0.47
1.0
-
-
3.6
2.7
ND
18-Jul-13
0.47
1.0
-
-
--
--
ND
28-Oct-13
0.47
1.0
ND
ND
--
--
ND
NC 2L = 3 pg/I (01/01/10)
6-May-14
0.47
1.0
-
-
6.0
2.1
ND
22-Oct-14
EPA 8260
0.47
1.0
-
-
5.1
1.8
ND
21-May-15
EPA 8260
0.47
1.0
ND
ND
3.5
0.92 J
ND
8-Dec-15
0.47
1.0
-
-
2.9
2.1
ND
3-May-16
0.47
1.0
ND
ND
3.1
1.7
ND
14-Dec-16
0.47
1.0
-
-
ND
1.8
ND
27-Jun-17
EPA 8260
0.47
1.0
-
-
ND
0.30 J
ND
15-Dec-17
0.47
1.0
ND
ND
2.8
ND
ND
16-May-18
EPA 8260
0.47
1.0
-
-
3.1
1.2
--
6-Dec-18
EPA 8260
0.47
1.0
ND
ND
2.2
ND
-
8-May-19
EPA 8260D
0.34
1.0
-
-
4.1
ND
ND
8-Nov-19
EPA 8260D
0.22
1.0
ND
ND
1.6
0.73 J
--
8-May-20
EPA 8260D
0.22
1.0
-
-
1.9
0.63 J
ND
11-Nov-20
EPA 8260D
0.22
1.0
ND
ND
1.7
ND
ND
5-May-21
EPA 8260D
0.38
1.0
-
-
2.0
ND
ND
3-Nov-21
EPA 8260D
0.38
1.0
ND
ND
0.86 J
ND
ND
19-May-22
EPA 8260D
0.38
1.0
-
-
1.2
ND
22-Nov-22
EPA 8260D
0.38
1.0
ND
ND
ND
ND
-
6-Nov-23
EPA 8260D
0.38
1.0
ND
ND
1.6
ND
--
Trichlorofluoromethane
18-Feb-13
0.20
1.0
-
-
0.65 J
ND
ND
18-Jul-13
0.20
1.0
-
-
--
-
ND
NC 2L = 2,000 pg/I (01/01/10)
6-May-14
0.20
1.0
-
-
-
ND
ND
22-Oct-14
0.20
1.0
-
-
-
ND
ND
21-May-15
EPA 8260
0.20
1.0
-
-
-
ND
ND
16-May-18
EPA 8260
0.20
1.0
-
-
-
ND
-
6-Dec-18
EPA 8260
0.20
1.0
ND
ND
--
ND
--
8-May-19
EPA 8260D
0.51
1.0
-
-
-
ND
ND
8-Nov-19
EPA 8260D
0.31
1.0
-
-
-
ND
--
8-May-20
EPA 8260D
0.31
1.0
-
-
-
ND
ND
11-Nov-20
EPA 8260D
0.31
1.0
-
-
ND
ND
ND
5-May-21
EPA 8260D
0.30
1.0
-
-
-
-
ND
3-Nov-21
EPA 8260D
0.30
1.0
-
-
-
ND
ND
19-May-22
EPA 8260D
0.30
1.0
-
-
ND
ND
22-Nov-22
EPA 8260D
0.30
1.0
-
-
ND
ND
--
6-Nov-23
EPA 8260D
0.30
1.0
-
-
--
ND
-
Vinyl chloride
18-Feb-13
0.62
1.0
-
-
1.2
ND
ND
18-Jul-13
0.62
1.0
-
-
---
-
ND
28-Oct-13
0.62
1.0
ND
ND
--
-
ND
NC 2L = 0.03 pg/I (01/01/10)
6-May-14
0.62
1.0
-
-
1.1
ND
ND
22-Oct-14
EPA 8260
0.62
1.0
-
-
0.87 J
ND
ND
21-May-15
EPA 8260
0.62
1.0
ND
ND
ND
ND
ND
8-Dec-15
0.62
1.0
-
-
0.80 J
ND
ND
3-May-16
0.62
1.0
ND
ND
0.80 J
1.8
ND
Resample >
9-Jun-16
0.62
1.0
-
-
--
ND
ND
14-Dec-16
0.62
1.0
-
-
--
ND
ND
27-Jun-17
EPA 8260
0.62
1.0
-
-
0.64 J
1.9
ND
Resample >
8-Aug-17
EPA 8260
0.62
1.0
-
-
--
0.87 J
---
15-Dec-17
0.62
1.0
ND
ND
ND
ND
ND
16-May-18
EPA 8260
0.62
1.0
-
-
0.66 J
3.1
-
6-Dec-18
EPA 8260
0.62
1.0
ND
ND
ND
4.3
-
8-May-19
EPA 8260D
0.60
1.0
-
-
ND
4.8
ND
8-Nov-19
EPA 8260D
0.24
1.0
ND
ND
ND
1.4
-
8-May-20
EPA 8260D
0.24
1.0
-
-
0.56 J
0.85 J
ND
11-Nov-20
EPA 8260D
0.24
1.0
ND
ND
ND
1.10
ND
5-May-21
EPA 8260D
0.39
1.0
-
-
ND
4.2
ND
3-Nov-21
EPA 8260D
0.39
1.0
ND
ND
0.59 J
ND
ND
19-May-22
EPA 8260D
0.39
1.0
-
-
0.50 J
1.4
22-Nov-22
EPA 8260D
0.39
1.0
ND
ND
ND
1.0 J
---
6-Nov-23
EPA 8260D
0.39
1.0
0.61 J
ND
0.60 J
0.6 J
---
Xylene (Total)
18-Feb-13
0.66
2.0
-
-
295
1.7 J
ND
18-Jul-13
0.66
2.0
-
-
--
--
ND
NC 2L = 500 pg/I (01/01/10)
6-May-14
0.66
2.0
-
-
-
19.3
ND
22-Oct-14
0.66
2.0
-
-
-
18.7
ND
21-May-15
EPA 8260
0.66
5.0
-
-
-
17.1
ND
16-May-18
EPA 8260
0.66
5.0
-
-
-
9.8
-
6-Dec-18
EPA 8260
0.66
1.0
-
-
-
14.7
--
8-May-19
EPA 8260D
1.50
2.0
-
-
-
22.8
ND
8-Nov-19
EPA 8260D
0.63
1.0
-
-
---
ND
--
8-May-20
EPA 8260D
0.63
1.0
-
-
--
ND
ND
11-Nov-20
EPA 8260D
0.63
1.0
-
-
10.80
ND
ND
5-May-21
EPA 8260D
0.34
1.0
-
-
--
-
ND
3-Nov-21
EPA 8260D
0.34
1.0
-
-
--
ND
ND
19-May-22
EPA 8260D
0.34
1.0
-
-
36.00
13.4
22-Nov-22
EPA 8260D
0.34
1.0
-
-
18.40
9.2
--
6-Nov-23
EPA 8260D
0.34
1.0
-
-
--
8.4
--
Burke Co. - Johns River C+D-over-MSWLF LaBella Associates
Permit No. 12-03 Page 5 of 7 March 2024

TABLE C-3: Historically Detected Constituents in Performance and Sentinel Wells
ne
ved Methane)
Alpha-BHC
IMAC= 0.006 (02/01/15)
JIMAC= 0.019 (02/01/15)
nic
L = 10 pg/L
I naiiium
IMAC = 0.2 pg/L
(Cadmium
=10pg/L
D=11.3pg/L
Barium
NC21- = 700 pg/L
Iron
BKGD = 14,182 pg/L
Sample
EPA
Collection Date
Method
MDL
I MRL
18-Feb-13
0.66
2.0
18-Jul-13
0.66
2.0
6-May-14
0.66
2.0
22-Oct-14
RSK 175
3.30
6.6
21-May-15
RSK 175
0.63
10.0
16-May-18
RSK 175
0.63
10.0
6-Dec-18
RSK 175
20.00
20.0
8-May-19
RSK 175 Modified
3.40
10.0
8-Nov-19
RSK 175 Modified
3.40
10.0
8-May-20
RSK 175 Modified
3.40
10.0
11-Nov-20
RSK 175 Modified
3.40
10.0
5-May-21
--
--
--
18-May-22
RSK 175 Modified
3
10
3-Nov-21
RSK-175
2.91
10
19-May-22
RSK 175 Modified
3
10
22-Nov-22
RSK-175
3
10
6-Nov-23
RSK 175 Modified
5
10
21-May-15
8-Dec-15
6-Dec-18
EPA 8081
0.05
0.05
8-May-19
EPA 8081B
0.02
0.05
8-Nov-19
EPA 8081B
0.02
0.05
8-May-20
EPA 8081B
0.02
0.05
11-Nov-20
EPA 8081B
0.02
0.05
5-May-21
EPA 8081B
0.026
0.05
3-Nov-21
EPA 8081B
0.0172
0.05
6-Nov-23
EPA 8081B
0.0110
0.045
21-May-15
8-Dec-15
6-Dec-18
EPA 8081
0.05
0.05
8-May-19
EPA 8081B
0.02
0.05
8-Nov-19
EPA 8081B
0.02
0.05
8-May-20
EPA 8081B
0.02
0.05
11-Nov-20
EPA 8081B
0.02
0.05
5-May-21
EPA 8081B
0.022
0.05
3-Nov-21
EPA 8081B
0.0208
0.05
6-Nov-23
EPA 8081B
0.0440
0.05
11-Nov-20
EPA 6010D
0.47
10.0
5-May-21
EPA 6010D
4.7
10.0
3-Nov-21
EPA 6010D
4.7
10.0
19-May-22
EPA 6020B
2.2
5.0
22-Nov-22
EPA 6020B
2.2
5.0
6-Nov-23
EPA 6010D
2.5
10.0
8-May-20
EPA 6020B
0.05
0.1
11-Nov-20
EPA 6020B
0.05
0.1
5-May-21
EPA 6020B
0.05
1.0
3-Nov-21
EPA 6020B
0.05
0.47
19-May-22
EPA 6020B
0.18
1.0
22-Nov-22
EPA 6020B
0.05
0.5
6-Nov-23
EPA 6020
0.11
1.0
11-Nov-20
EPA 6010D
0.47
10.0
5-May-21
EPA 6010D
0.4
1.0
3-Nov-21
EPA 6010D
0.4
1.0
19-May-22
EPA 6020B
0.1
0.5
22-Nov-22
EPA 6020B
0.1
0.5
6-Nov-23
EPA 6010D
0.3
1.0
Sentinel
MW-18
MW 19
136
3,060
1,100
1,330
1,080
1,020
281
2,910
1,170
780
3,190
779
2,690
2,240
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.064
J
ND
0.26
J
0.077 J
0.16
J
ND
0.25
J
ND
0.4
1
Performance
MW-36
MW-38
348
4,150
8,450
6,820
173
4,900
29,100
11,500
27,800
12,300
--
14,300
8,820
1,730
13,800
8,570
14,200
12,000
4,810
3,500
7,950
22,900
3,550
2,640
3,470
4,860
QIo'�\IW
ND
ND
ND
ND
ND
ND
--
4.8 J
-
10.1
ND
ND
3 J
ND
--
ND
0.073 J
ND
0.052 J
ND
ND
ND
ND
0.20 J
0.250 J
ND
0.120 J
ND
ND
ND
---
0.43 J
---
ND
ND
ND
0.18 J
ND
--
ND
8-May-20
11-Nov-20
5-May-21
3-Nov-21
19-May-22
22-Nov-22
6-Nov-23
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6020B
EPA 6020B
EPA 6010
3.60
3.60
3.60
3.60
0.39
0.39
0.96
5.0
5.0
5.0
5.0
5.0
5.0
10.0
--
6.1
--
9.3
--
11.8
9.4 J
--
29.3
--
25.8
--
29.4
25.3
51.5
45.7
41.3
37.8
37.2
35.6
34.0
8.0
7.5
18.6
7.5
27.2
34.8
58.1
8-May-20
EPA 6010D
3.50
5.0
-
-
---
91.8
11-Nov-20
EPA 6010D
3.50
5.0
-
-
100
95.4
5-May-21
EPA 6010D
3.50
5.0
-
-
---
--
3-Nov-21
EPA 6010D
3.50
5.0
-
-
---
174
19-May-22
EPA 6020B
0.67
5.0
-
-
78
115.0
22-Nov-22
EPA 6020B
0.67
5.0
-
-
68
118.0
6-Nov-23
EPA 6010D
0.79
5.0
-
-
---
143.0
8-May-20
EPA 6010D
41.50
50.0
-
-
-
35,100
11-Nov-20
EPA 6010D
41.50
50.0
-
-
-
19,600
5-May-21
EPA 6010D
41.50
50.0
---
---
---
---
3-Nov-21
EPA 6010D
41.50
50.0
---
---
---
48,200
3-Nov-21
EPA 6010D
3.40
5.0
-
-
---
6,460
19-May-22
EPA 6020B
1,480
2,000
-
-
12,500
15,000
22-Nov-22
EPA 6020B
296
400
--
--
15,000
16,400
6-Nov-23
EPA 6010D
9
50
102000
62500
22,500
14,500
Blanks
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
18.80 J
Burke Co. - Johns River C+D-over-MSWLF LaBella Associates
Permit No. 12-03 Page 6 of 7 March 2024

TABLE C-3: Historically Detected Constituents in Performance and Sentinel Wells
Analyte
Sample
Collection Date
EPA
Method
MDL
MRL
Sentinel
Performance
Blanks
MW-18
MW-19
MW-36
MW-38
Manganese
8-May-20
EPA 6010D
3.40
5.0
—
—
---
5,340
—
BKGD = 535 pg/L
11-Nov-20
EPA 6010D
3.40
5.0
—
—
---
7,780
ND
5-May-21
EPA 6010D
3.40
5.0
—
—
---
--
ND
19-May-22
EPA 300.0 Rev 2.11993
500
1,000
--
--
2,640
6,510
22-Nov-22
EPA 300.0 Rev 2.11993
500
1,000
530 J
1340
2,700
6,570
—
J,
6-Nov-23
EPA 300.0 Rev 2.11993
500
1,000
540 M
14700
2,250
700 J
ND
1
Notes:
All concentrations in micrograms per liter (pg/1) = parts per billion.
MDL = Method Detection Limit.
MRL = Method Reporting Limit.
ND = Not detected above the MDL.
NC 2L = Groundwater Standard from 15A NCAC 2L.0202.
IMAC = Interim Maximum Allowable Concentration for constituents with no listed NC 2L.
--- = Not reported or not sampled.
Burke Co. - Johns River C+D-over-MSWLF LaBella Associates
Permit No. 12-03 Page 7 of 7 March 2024

TABLE C-4: Historically Detected Surface Water Constituents
Sample
EPA
Analyte
Collection Date
Method
DL
RL
SMP-5 SMP-6 SMP-7
Blanks
Inorganics
Antimony
6-Nov-08
2.6
6.0
ND 8.4 -
ND
3-Jun-09
2.6
6.0
ND ND -
ND
18-Nov-09
2.6
6.0
ND ND -
ND
NC 213 = NE (05/01/07)
15-Jun-10
2.6
6.0
ND ND -
ND
1-Dec-10
2.6
6.0
ND ND -
ND
1-Jun-11
2.6
6.0
ND ND -
ND
20-Dec-11
5.0
6.0
ND ND -
ND
30-May-12
5.0
6.0
ND ND -
ND
5-Dec-12
5.0
6.0
ND ND -
ND
12-Jun-13
5.0
6.0
ND ND -
ND
28-Oct-13
5.0
6.0
ND ND -
ND
6-May-14
EPA 6010
5.0
6.0
ND ND -
ND
22-Oct-14
EPA 6010
5.0
6.0
-- ND ND
ND
21-May-15
EPA 6010
3.8
6.0
ND ND ND
ND
9-Dec-15
EPA 6010
3.8
6.0
ND ND ND
ND
NC 213 = 5.6 pg/1 (03/01/16)
4-May-16
EPA 6010
3.8
6.0
ND ND ND
ND
14-Dec-16
EPA 6010
3.8
6.0
ND ND ND
ND
28-Jun-17
EPA 6010
3.9
6.0
ND ND ND
-
13-Dec-17
3.9
6.0
ND ND ND
ND
16-May-18
EPA 6010
3.9
6.0
ND ND ND
-
6-Dec-18
3.9
5.0
ND ND ND
ND
8-May-19
EPA 6O1OD
3.9
5.0
ND ND ND
-
8-Nov-19
EPA 6O1OD
3.0
5.0
ND ND ND
-
8-May-20
EPA 6O1OD
3.0
5.0
ND ND ND
ND
11-Nov-20
EPA 6O1OD
3.0
5.0
ND ND ND
-
5-May-21
EPA 6O1OD
3.0
5.0
ND ND ND
ND
4-Nov-21
EPA 6O1OD
3.0
5.0
- ND -
-
19-May-22
EPA 6O2OB
0.8
3.0
- ND ND
-
17-Nov-22
EPA 6O2OB
0.8
3.0
ND ND ND
ND
6-Nov-23
EPA 6O1OD
3.6
5.0
-- ND -
ND
Arsenic
6-Nov-08
2.7
10.0
2.9 B 4.5 B -
4.1 J
3-Jun-09
2.7
10.0
ND 4.5 J -
ND
18-Nov-09
2.7
10.0
ND ND -
ND
NC 213 = 10 pg/I (05/01/07)
15-Jun-10
2.7
10.0
ND ND -
ND
1-Dec-10
2.7
10.0
ND ND -
ND
1-Jun-11
2.7
10.0
ND ND -
ND
20-Dec-11
5.0
10.0
ND ND -
ND
30-May-12
5.0
10.0
ND ND -
ND
5-Dec-12
5.0
10.0
ND ND -
ND
12-Jun-13
5.0
10.0
ND ND -
ND
28-Oct-13
5.0
10.0
ND ND -
ND
6-May-14
EPA 6010
5.0
10.0
ND ND -
ND
22-Oct-14
EPA 6010
5.0
10.0
-- ND ND
ND
21-May-15
EPA 6010
2.5
10.0
ND ND ND
ND
9-Dec-15
EPA 6010
2.5
10.0
ND ND ND
ND
NC 213 = 10 pg/I (03/01/16)
4-May-16
EPA 6010
2.5
10.0
3.0 J ND 3.3 J
ND
14-Dec-16
EPA 6010
2.5
10.0
ND ND ND
ND
28-Jun-17
EPA 6010
5.0
10.0
ND 5.5 J ND
-
13-Dec-17
5.0
10.0
ND ND ND
ND
16-May-18
EPA 6010
5.0
10.0
ND ND ND
-
6-Dec-18
5.0
10.0
ND ND ND
ND
8-May-19
EPA 6O1OD
5.0
10.0
ND ND ND
-
8-Nov-19
EPA 6O1OD
4.7
10.0
ND ND ND
-
8-May-20
EPA 6O1OD
4.7
10.0
ND ND ND
ND
11-Nov-20
EPA 6O1OD
4.7
10.0
ND ND ND
-
5-May-21
EPA 6O1OD
4.7
10.0
ND ND ND
ND
4-Nov-21
EPA 6O1OD
4.7
10.0
-- ND -
-
5-May-21
EPA 6O1OD
4.7
10.0
ND ND ND
ND
17-Nov-22
EPA 6O2OB
2.2
5.0
ND ND ND
ND
6-Nov-23
EPA 6O1OD
2.5
10.0
- ND -
ND
Burke County Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 1 of 17 March 2024

TABLE C-4: Historically Detected Surface Water Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
SMP-5
SMP-6
SMP-7
Blanks
Barium
30-May-07
--
100
81.3
J 23.8
J ---
0.2 J
29-Nov-07
--
100
116
27.5
J
0.50 J
29-May-08
0.2
100
71.9
J 19.6
J -
ND
6-Nov-08
0.20
100
82.5
J 40.2
B -
9.6 J
3-Jun-09
0.20
100
104
36.2
B -
15.9 J
18-Nov-09
0.20
100
49.9
B 15.7
B -
20.1 J
NC 2B = 1,000 pg/I (05/01/07)
15-Jun-10
0.20
100
47.6
J 20.7
J -
0.77 J
1-Dec-10
0.20
100
39.8
J 46.8
J -
ND
1-Jun-11
0.20
100
51.6
J 19.9
J -
ND
20-Dec-11
5.0
100
63.7
J 13.9
J -
ND
30-May-12
5.0
100
16.9
J 22.0
J -
ND
5-Dec-12
5.0
100
69.9
J 24.8
J -
ND
12-Jun-13
5.0
100
54.9
B 40.0
B -
13.6 J
28-Oct-13
5.0
100
35.4
J 20.8
J -
ND
6-May-14
EPA 6010
5.0
100
37.0
J 17.8
J -
ND
22-Oct-14
EPA 6010
5.0
100
--
25.5
J 19.8 J
ND
21-May-15
EPA 6010
2.5
100
53.0
J 14.6
J 21.6 J
ND
9-Dec-15
EPA 6010
2.5
100
26.1
J 23.4
J 27.8 J
ND
NC 2B = 1,000 pg/I (03/01/16)
4-May-16
EPA 6010
2.5
100
41.4
J 37.3
J 51.0 J
ND
14-Dec-16
EPA 6010
2.5
100
44.7
J 21.2
J 17.5 J
ND
28-Jun-17
EPA 6010
2.5
100
46.3
J 41.4
J 31.5 J
--
13-Dec-17
2.5
100
38.7
J 26.3
J 20.7 J
ND
16-May-18
EPA 6010
2.5
100
34.5
J 42.5
J 46.3 J
--
6-Dec-18
2.5
5
32.6
31.1
30.3
9.9
8-May-19
EPA 6010D
2.5
5
31.7
30.0
25.0
--
8-Nov-19
EPA 6010D
1.0
5
25.6
27.1
27.0
-
8-May-20
EPA 6010D
3.5
5
22.8
28.3
27.6
ND
11-Nov-20
EPA 6010D
3.5
5
20.3
38.5
52.5
-
5-May-21
EPA 6010D
3.5
5
10.5
27.9
28.5
ND
4-Nov-21
EPA 6010D
3.5
5
--
43.7
--
-
19-May-22
EPA 6020B
0.7
5
--
31.9
19.1
-
17-Nov-22
EPA 6020B
0.2
1
18.2
33.0
48.9
ND
6-Nov-23
EPA 6010D
0.8
5
--
66.1
--
ND
Burke County Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 2 of 17 March 2024

TABLE C-4: Historically Detected Surface Water Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
SMP-5 SMP-6 SMP-7
Blanks
Beryllium
14-Nov-02
--
2
2.0 B 2.2 B ---
2.1
14-May-03
--
2
ND ND
ND
20-Nov-03
--
2
ND ND -
ND
6-May-04
--
2
ND ND -
ND
10-Nov-04
--
2
ND ND -
ND
5-May-05
--
2
ND ND -
ND
3-Nov-05
--
2
ND ND -
ND
25-May-06
--
2
ND ND -
ND
2-Nov-06
--
2
ND ND -
ND
30-May-07
--
1
ND ND -
ND
29-Nov-07
--
1
ND ND -
ND
29-May-08
0.10
1.0
ND ND -
ND
6-Nov-08
0.10
1.0
0.24 B 0.37 B -
0.29 J
3-Jun-09
0.10
1.0
0.64 J 0.21 J -
ND
18-Nov-09
0.10
1.0
ND ND -
ND
NC 2B = 6.5 pg/I (05/01/07)
15-Jun-10
0.10
1.0
ND ND -
ND
1-Dec-10
0.10
1.0
ND ND -
ND
1-Jun-11
0.10
1.0
ND ND -
ND
20-Dec-11
1.0
1.0
ND ND -
ND
30-May-12
1.0
1.0
ND ND -
ND
5-Dec-12
1.0
1.0
ND ND -
ND
12-Jun-13
1.0
1.0
ND ND -
ND
28-Oct-13
1.0
1.0
ND ND -
ND
6-May-14
EPA 6010
1.0
1.0
ND ND -
ND
22-Oct-14
EPA 6010
1.0
1.0
-- ND ND
ND
21-May-15
EPA 6010
0.5
1.0
ND ND ND
ND
9-Dec-15
EPA 6010
0.5
1.0
ND ND ND
ND
NC 2B = 6.5 pg/I Chronic (03/01/16)*
4-May-16
EPA 6010
0.5
1.0
ND ND ND
ND
14-Dec-16
EPA 6010
0.5
1.0
ND ND ND
ND
28-Jun-17
EPA 6010
0.5
1.0
ND ND ND
-
13-Dec-17
0.5
1.0
ND ND ND
ND
16-May-18
EPA 6010
0.5
1.0
ND ND ND
-
6-Dec-18
0.5
1.0
ND ND ND
ND
8-May-19
EPA 6O1OD
0.5
1.0
ND ND ND
-
8-Nov-19
EPA 6O1OD
0.2
1.0
ND ND 0.22 J
-
8-May-20
EPA 6O1OD
0.7
1.0
ND ND ND
ND
11-Nov-20
EPA 6O1OD
0.7
1.0
ND ND ND
-
5-May-21
EPA 6O1OD
0.7
1.0
ND ND ND
ND
4-Nov-21
EPA 6O1OD
0.7
1.0
- ND -
-
19-May-22
EPA 6O2OB
0.1
0.5
- ND ND
-
17-Nov-22
EPA 6O2OB
0.1
0.5
ND ND ND
ND
6-Nov-23
EPA 6O1OD
0.2
1.0
- ND -
ND
Burke County Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 3 of 17 March 2024

TABLE C-4: Historically Detected Surface Water Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
SMP-5 SMP-6 SMP-7
Blanks
Cadmium
7-Nov-01
--
1
ND 1.0
ND
22-May-02
--
1
ND 1.7 B -
1.3
14-Nov-02
--
1
ND ND -
ND
14-May-03
--
1
ND ND -
ND
20-Nov-03
--
1
ND ND -
ND
6-May-04
--
1
ND ND -
ND
10-Nov-04
--
1
ND ND -
ND
5-May-05
--
1
ND ND -
ND
3-Nov-05
--
1
ND ND -
ND
25-May-06
--
1
ND ND -
ND
2-Nov-06
--
1
ND ND -
ND
30-May-07
--
1
ND ND -
ND
29-Nov-07
--
1
ND ND -
ND
29-May-08
0.5
1.0
ND ND -
ND
6-Nov-08
0.50
1.0
ND ND -
ND
3-Jun-09
0.50
1.0
ND ND -
ND
18-Nov-09
0.50
1.0
ND ND -
ND
NC 213 = 2 pg/I (05/01/07)
15-Jun-10
0.50
1.0
ND ND -
ND
1-Dec-10
0.50
1.0
ND ND -
ND
1-Jun-11
0.50
1.0
ND ND -
ND
20-Dec-11
1.0
1.0
ND ND -
ND
30-May-12
1.0
1.0
ND ND -
ND
5-Dec-12
1.0
1.0
ND ND -
ND
12-Jun-13
1.0
1.0
ND ND -
ND
28-Oct-13
1.0
1.0
ND ND -
ND
6-May-14
EPA 6010
1.0
1.0
ND ND -
ND
22-Oct-14
EPA 6010
1.0
1.0
-- ND ND
ND
21-May-15
EPA 6010
0.5
1.0
ND ND ND
ND
9-Dec-15
EPA 6010
0.5
1.0
ND ND ND
ND
NC 2B = 0.15 pg/I Chronic (03/01/16)*
4-May-16
EPA 6010
0.5
1.0
ND ND ND
ND
14-Dec-16
EPA 6010
0.5
1.0
ND ND ND
ND
28-Jun-17
EPA 6010
0.5
1.0
ND ND ND
-
13-Dec-17
0.5
1.0
ND ND ND
ND
16-May-18
EPA 6010
0.5
1.0
ND ND ND
-
6-Dec-18
0.5
1.0
ND ND ND
ND
8-May-19
EPA 6O1OD
0.5
1.0
ND ND ND
-
8-Nov-19
EPA 6O1OD
0.4
1.0
ND ND ND
-
8-May-20
EPA 6O1OD
0.4
1.0
ND ND ND
ND
11-Nov-20
EPA 6O1OD
0.4
1.0
ND ND ND
-
5-May-21
EPA 6O1OD
0.4
1.0
0.44 J ND ND
ND
4-Nov-21
EPA 6O1OD
0.4
1.0
-- ND -
-
19-May-22
EPA 6O2OB
0.1
0.5
-- ND ND
-
17-Nov-22
EPA 6O2OB
0.1
0.5
0.16 J ND ND
ND
6-Nov-23
EPA 6O1OD
0.3
1.0
-- 0.31 J -
ND
Burke County Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 4 of 17 March 2024

TABLE C-4: Historically Detected Surface Water Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
SMP-5
SMP-6
SMP-7
Blanks
Chromium
6-Nov-08
0.40
10.0
ND
0.47
J --
ND
3-Jun-09
0.40
10.0
7.5
J 3.2
J
ND
18-Nov-09
0.40
10.0
ND
ND
-
ND
NC 2B = 50 pg/I (05/01/07)
15-Jun-10
0.40
10.0
1.2
B 0.48
B -
0.74 J
1-Dec-10
0.40
10.0
0.68
B 5.1
J -
0.51 J
1-Jun-11
0.40
10.0
0.59
B 0.59
B -
0.73 J
20-Dec-11
5.0
10.0
ND
ND
-
ND
30-May-12
5.0
10.0
ND
ND
-
ND
5-Dec-12
5.0
10.0
ND
ND
-
ND
12-Jun-13
5.0
10.0
ND
ND
-
ND
28-Oct-13
5.0
10.0
ND
ND
-
ND
6-May-14
EPA 6010
5.0
10.0
ND
ND
-
ND
22-Oct-14
EPA 6010
5.0
10.0
--
ND
9.7 J
ND
21-May-15
EPA 6010
2.5
10.0
ND
ND
ND
ND
9-Dec-15
EPA 6010
2.5
10.0
ND
ND
ND
ND
NC 2B = 11 pg/I Chronic (03/01/16)*
4-May-16
EPA 6010
2.5
10.0
4.7
J 4.6
J 8.8 J
ND
14-Oct-16
2.5
10.0
ND
ND
ND
ND
28-Jun-17
2.5
10.0
ND
ND
ND
ND
NC 2B = 23.81 pg/I Chronic (09/22/17)*
13-Dec-17
2.5
10.0
ND
ND
ND
ND
16-May-18
EPA 6010
2.5
10.0
4.8
J ND
ND
-
6-Dec-18
2.5
5.0
ND
ND
ND
ND
8-May-19
EPA 6O1OD
2.5
5.0
2.7
J ND
ND
-
8-Nov-19
EPA 6O1OD
1.0
5.0
1.7
J ND
ND
-
8-May-20
EPA 6O1OD
3.7
5.0
ND
ND
ND
ND
11-Nov-20
EPA 6O1OD
3.7
5.0
ND
4.7
J 8.0
-
5-May-21
EPA 6O1OD
3.7
5.0
ND
ND
ND
ND
4-Nov-21
EPA 6O1OD
3.7
5.0
-
ND
-
-
19-May-22
EPA 6O2OB
1.1
5.0
-
ND
ND
-
17-Nov-22
EPA 6O2OB
1.1
5.0
ND
ND
1.4 J,
ND
6-Nov-23
EPA 6O1OD
0.6
5.0
-
ND
--
ND
Burke County Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 5 of 17 March 2024

TABLE C-4: Historically Detected Surface Water Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
SMP-5
SMP-6
SMP-7
Blanks
Cobalt
22-May-02
--
10
14.0
17.0
--
11.0
14-Nov-02
--
10
ND
ND
--
ND
14-May-03
--
10
ND
10.0
-
ND
20-Nov-03
--
10
14.0
ND
-
ND
6-May-04
--
10
ND
ND
-
ND
10-Nov-04
--
10
10.0
ND
-
ND
5-May-05
--
10
10.0
ND
-
ND
3-Nov-05
--
10
16.0
ND
-
ND
25-May-06
--
10
12
ND
-
ND
2-Nov-06
--
10
13.6
ND
-
ND
30-May-07
--
10
12.3
8.8
J -
ND
29-Nov-07
--
10
19.0
2.1
J -
ND
29-May-08
0.60
10.0
13.7
ND
-
ND
6-Nov-08
0.60
10.0
12.6
ND
-
0.65 J
3-Jun-09
0.60
10.0
11.9
B 6.6
B -
7.6 J
18-Nov-09
0.60
10.0
3.6
J 4.6
J -
ND
NC 213 = NE (05/01/07)
15-Jun-10
0.60
10.0
6.4
J 22.3
-
ND
1-Dec-10
0.60
10.0
0.76
J 4.1
J -
ND
1-Jun-11
0.60
10.0
2.0
J 1.7
J -
ND
20-Dec-11
5.0
10.0
ND
ND
-
ND
30-May-12
5.0
10.0
ND
ND
-
ND
5-Dec-12
5.0
10.0
29.0
7.7
J -
ND
12-Jun-13
5.0
10.0
ND
9.1
J -
ND
28-Oct-13
5.0
10.0
11.5
12.4
-
ND
6-May-14
EPA 6010
5.0
10.0
ND
ND
-
ND
22-Oct-14
EPA 6010
5.0
10.0
--
ND
ND
ND
21-May-15
EPA 6010
2.5
10.0
6.3
J ND
ND
ND
9-Dec-15
EPA 6010
2.5
10.0
ND
ND
ND
ND
NC 2B = 3 pg/I (03/01/16)
4-May-16
EPA 6010
2.5
10.0
4.0
J 5.6
J 3.3 J
ND
14-Dec-16
EPA 6010
2.5
10.0
5.9
J ND
ND
ND
28-Jun-17
EPA 6010
2.5
10.0
6.4
J 3.6
J ND
-
NC 2B = NE (09/22/17)
13-Dec-17
2.5
10.0
6.9
J 4.7
J ND
ND
16-May-18
EPA 6010
2.5
10.0
3.8
J ND
ND
-
6-Dec-18
2.5
5.0
ND
3.4
J ND
ND
8-May-19
EPA 6010D
2.5
5.0
ND
2.9
J ND
-
8-Nov-19
EPA 6010D
1.1
5.0
ND
2.7
J 5.6
-
8-May-20
EPA 6010D
3.6
5.0
ND
ND
ND
ND
11-Nov-20
EPA 6010D
3.6
5.0
ND
4.1
J 5.3
-
5-May-21
EPA 6010D
3.6
5.0
ND
4.9
J 3.9 J
ND
4-Nov-21
EPA 6010D
3.6
5.0
-
ND
-
-
19-May-22
EPA 6020B
0.4
5.0
-
2.2
J 0.91 J
-
17-Nov-22
EPA 6020B
0.4
5.0
ND
3.1
J 1.7 J
ND
6-Nov-23
EPA 6010D
0.4
5.0
-
ND
-
ND
Burke County Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 6 of 17 March 2024

TABLE C-4: Historically Detected Surface Water Constituents
Sample
EPA
Analyte
Collection Date
Method
DL
RL
SMP-5
SMP-6
SMP-7
Blanks
Copper
29-May-08
0.30
10.0
ND
1.3
B --
0.37 J
6-Nov-08
4.0
10.0
0.45
B 3.4
J
0.65 J
3-Jun-09
0.30
10.0
6.6
J 2.1
J -
ND
18-Nov-09
0.30
10.0
ND
ND
-
ND
NC 213 = 7 pg/I (05/01/07)
15-Jun-10
0.30
10.0
0.56
B ND
-
0.77 J
1-Dec-10
0.30
10.0
3.6
J 5.9
J -
ND
1-Jun-11
0.30
10.0
1.8
J 0.35
J -
ND
20-Dec-11
5.0
10.0
ND
ND
-
ND
30-May-12
5.0
10.0
ND
ND
-
ND
5-Dec-12
5.0
10.0
ND
ND
-
ND
12-Jun-13
5.0
10.0
5.2
B ND
-
9.8 J
28-Oct-13
5.0
10.0
ND
ND
-
ND
6-May-14
EPA 6010
5.0
10.0
ND
ND
-
ND
22-Oct-14
EPA 6010
5.0
10.0
--
ND
ND
ND
21-May-15
EPA 6010
2.5
10.0
ND
ND
ND
ND
9-Dec-15
EPA 6010
2.5
10.0
ND
ND
ND
ND
NC 2B = 2.74 pg/1 Chronic (3/1/16)*
4-May-16
EPA 6010
2.5
10.0
4.6
J 5.5
J 11
ND
Resample >
17-May-16
EPA 6010
2.5
10.0
--
--
ND
ND
14-Dec-16
EPA 6010
2.5
10.0
ND
ND
ND
ND
28-Jun-17
EPA 6010
2.5
10.0
ND
ND
ND
-
13-Dec-17
2.5
10.0
ND
3.9
J ND
ND
16-May-18
EPA 6010
2.5
10.0
5.4
J ND
ND
--
6-Dec-18
2.5
5.0
ND
ND
ND
5.8
NC 2B = 3.81 pg/1 chronic (SMP-5 5/8/19)
8-May-19
EPA 6O1OD
2.5
5.0
5.4
ND
ND
--
8-Nov-19
EPA 6O1OD
2.1
5.0
4.1
J ND
ND
-
8-May-20
EPA 6O1OD
4.3
5.0
ND
ND
ND
ND
11-Nov-20
EPA 6O1OD
4.3
5.0
ND
5.7
10.6
-
5-May-21
EPA 6O1OD
4.3
5.0
ND
ND
ND
ND
4-Nov-21
EPA 6O1OD
4.3
5.0
-
ND
-
-
19-May-22
EPA 6O2OB
1.0
5.0
-
ND
ND
--
17-Nov-22
EPA 6O2OB
1.0
5.0
2.4
J ND
5.6
1.2 J
6-Nov-23
EPA 6O1OD
0.6
5.0
--
ND
--
ND
Cyanide
13-Dec-17
4.0
10.0
7.3
B 6.2
B ND
4.2 J
INC 2B = 5 pg/I (09/22/17)
16-May-18
SM 4500-CN-E
4.0
10.0
ND
ND
ND
--
6-Dec-18
4.0
8.0
ND
ND
ND
ND
8-May-19
SM 4500-CN-E-2011
6.0
8.0
ND
ND
ND
ND
8-Nov-19
SM 4500-CN-E-2011
6.0
8.0
ND
ND
ND
-
8-May-20
SM 4500-CN-E-2011
6.0
8.0
ND
ND
ND
ND
11-Nov-20
SM 4500-CN-E-2011
6.0
8.0
ND
ND
ND
-
5-May-21
SM 4500-CN-E-2011
6.0
8.0
ND
ND
ND
ND
4-Nov-21
SM 4500-CN-E-2016
6.0
8.0
--
ND
-
-
5-May-21
SM 4500-CN-E-2011
6.0
8.0
ND
ND
ND
ND
17-Nov-22
SM 4500-CN-E-2016
6.0
8.0
6.3
J ND
ND
ND
6-Nov-23
SM 4500-CN-E-2016
6.0
8.0
--
ND
--
ND
Iron
13-Dec-17
25.0
300.0
9520
7860
454
ND
INC 2B = NE (09/22/17)
16-May-18
EPA 6010
25.0
300.0
5350
3240
2190
--
6-Dec-18
25.0
50.0
1980
3240
511
167
8-May-19
EPA 6O1OD
25.0
50.0
3810
3260
315
--
8-Nov-19
EPA 6O1OD
19.5
50.0
3400
8840
2920
-
8-May-20
EPA 6O1OD
41.5
50.0
--
--
--
ND
11-Nov-20
EPA 6O1OD
41.5
50.0
4550
7270
9650
-
5-May-21
EPA 6O1OD
41.5
50.0
2480
7580
511
ND
4-Nov-21
EPA 6O1OD
41.5
50.0
--
24700
--
-
19-May-22
EPA 6O2OB
296.0
400.0
--
13900
701
-
17-Nov-22
EPA 6O2OB
20.9
50.0
607
6090
723
ND
6-Nov-23
EPA 6O1OD
8.9
50.0
--
44600
--
18.8 J
Burke County Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 7 of 17 March 2024

TABLE C-4: Historically Detected Surface Water Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
SMP-5 SMP-6 SMP-7
Blanks
Lead
3-Jun-09
4.0
10.0
7.3 J ND --
ND
18-Nov-09
4.0
10.0
ND ND
ND
NC 2B = 25 pg/I (05/01/07)
15-Jun-10
4.0
10.0
ND ND -
ND
1-Dec-10
4.0
10.0
ND 4.6 J -
ND
1-Jun-11
4.0
10.0
ND ND -
ND
20-Dec-11
5.0
10.0
ND ND -
ND
30-May-12
5.0
10.0
ND ND -
ND
5-Dec-12
5.0
10.0
ND ND -
ND
12-Jun-13
5.0
10.0
ND ND -
ND
28-Oct-13
5.0
10.0
ND ND -
ND
6-May-14
EPA 6010
5.0
10.0
ND ND -
ND
22-Oct-14
EPA 6010
5.0
10.0
-- ND ND
ND
21-May-15
EPA 6010
2.5
10.0
ND ND ND
ND
9-Dec-15
EPA 6010
2.5
10.0
ND ND ND
ND
NC 2B = 14 pg/I Acute, 0.54 pg/I Chronic *
4-May-16
EPA 6010
2.5
10.0
ND 4.9 J 7.2 J
ND
14-Dec-16
EPA 6010
2.5
10.0
ND ND ND
ND
28-Jun-17
EPA 6010
2.5
10.0
ND ND ND
-
NC 213 = 0.54 pg/I (09/22/17)*
13-Dec-17
2.5
10.0
ND ND ND
ND
16-May-18
EPA 6010
2.5
10.0
3.8 J 2.5 J 2.8 J
--
6-Dec-18
2.5
5.0
ND ND ND
ND
8-May-19
EPA 6O1OD
2.5
5.0
3.5 J ND ND
-
8-Nov-19
EPA 6O1OD
1.6
5.0
3.4 J ND 2.2 J
-
8-May-20
EPA 6O1OD
4.5
5.0
ND ND ND
ND
11-Nov-20
EPA 6O1OD
4.5
5.0
ND 5.4 9.9
-
5-May-21
EPA 6O1OD
4.5
5.0
ND ND ND
ND
4-Nov-21
EPA 6O1OD
4.5
5.0
- ND -
-
19-May-22
EPA 6O2OB
0.9
1.0
- ND ND
-
17-Nov-22
EPA 6O2OB
0.9
1.0
ND ND 3.5
ND
6-Nov-23
EPA 6O1OD
1.4
5.0
-- ND -
ND
Manganese
16-May-18
EPA 6010
2.5
50
294 145 89.8
--
NC 2B = NE (09/22/17)
6-Dec-18
2.50
5.0
17.8 206 199
10
8-May-19
EPA 6O1OD
2.50
5.0
98.2 194 271
--
8-Nov-19
EPA 6O1OD
0.90
5.0
31.9 687 928
-
8-May-20
EPA 6O1OD
3.40
5.0
-- -- --
ND
11-Nov-20
EPA 6O1OD
3.40
5.0
72.2 231 154
-
5-May-21
EPA 6O1OD
3.40
5.0
232 876 566
ND
4-Nov-21
EPA 6O1OD
3.40
5.0
-- 948 --
-
5-May-21
EPA 6O1OD
3.40
5.0
232 876 566
ND
17-Nov-22
EPA 6O2OB
1.10
10.0
8.3 J 485 54.1
ND
6-Nov-23
EPA 6O1OD
0.86
5.0
-- 1110 --
ND
Burke County Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 8 of 17 March 2024

TABLE C-4: Historically Detected Surface Water Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
SMP-5
SMP-6
SMP-7
Blanks
Nickel
3-Jun-09
1.7
50.0
5.5
B ND
-
1.7 J
18-Nov-09
1.7
50.0
ND
ND
-
ND
NC 2B = 25 pg/I (05/01/07)
15-Jun-10
1.7
50.0
ND
ND
-
ND
1-Dec-10
1.7
50.0
2.8
J 2.8 J
-
ND
1-Jun-11
1.7
50.0
ND
ND
-
2.3 J
20-Dec-11
5.0
50.0
ND
ND
-
ND
30-May-12
5.0
50.0
ND
ND
-
ND
5-Dec-12
5.0
50.0
ND
ND
-
ND
12-Jun-13
5.0
50.0
ND
ND
-
ND
28-Oct-13
5.0
50.0
ND
ND
-
ND
6-May-14
EPA 6010
5.0
50.0
ND
ND
-
ND
22-Oct-14
EPA 6010
5.0
50.0
--
ND
ND
ND
21-May-15
EPA 6010
2.5
50.0
ND
ND
ND
ND
9-Dec-15
EPA 6010
2.5
50.0
ND
ND
ND
ND
NC 2B = 16.1 pg/I Chronic (03/01/16)*
4-May-16
EPA 6010
2.5
50.0
3.8
J 3.9 J
6.7 J
ND
14-Dec-16
EPA 6010
2.5
50.0
ND
ND
ND
ND
28-Jun-17
EPA 6010
2.5
50.0
ND
ND
8.0 J
--
13-Dec-17
2.5
50.0
ND
ND
ND
ND
16-May-18
EPA 6010
2.5
50.0
3.9
J ND
ND
-
6-Dec-18
2.5
5.0
ND
ND
ND
ND
8-May-19
EPA 6010D
2.5
5.0
2.7
J ND
ND
-
8-Nov-19
EPA 6010D
0.9
5.0
ND
ND
ND
-
8-May-20
EPA 6010D
3.5
5.0
ND
ND
ND
ND
11-Nov-20
EPA 6010D
3.5
5.0
ND
ND
4.2 J
--
5-May-21
EPA 6010D
3.5
5.0
ND
ND
ND
ND
4-Nov-21
EPA 6010D
3.5
5.0
-
ND
-
-
19-May-22
EPA 6020B
0.7
5.0
-
ND
ND
-
17-Nov-22
EPA 6020B
0.7
5.0
0.79
J, ND
1.5 J,
ND
6-Nov-23
EPA 6010D
0.9
5.0
--
ND
--
ND
Selenium
6-Nov-08
3.8
10
ND
10.9
-
ND
3-Jun-09
3.8
10.0
ND
ND
-
ND
18-Nov-09
3.8
10.0
ND
ND
-
ND
NC 2B = 5 pg/I (05/01/07)
15-Jun-10
3.8
10.0
ND
ND
-
ND
1-Dec-10
3.8
10.0
ND
ND
-
ND
1-Jun-11
3.8
10.0
ND
ND
-
ND
20-Dec-11
10.0
10.0
ND
ND
-
ND
30-May-12
10.0
10.0
ND
ND
-
ND
5-Dec-12
10.0
10.0
ND
ND
-
ND
12-Jun-13
10.0
10.0
ND
ND
-
ND
28-Oct-13
10.0
10.0
ND
ND
-
ND
6-May-14
EPA 6010
10.0
10.0
ND
ND
-
ND
22-Oct-14
EPA 6010
10.0
10.0
--
ND
ND
ND
21-May-15
EPA 6010
5.0
10.0
ND
ND
ND
ND
9-Dec-15
EPA 6010
5.0
10.0
ND
ND
ND
ND
NC 2B = 5 pg/I (03/01/16)
4-May-16
EPA 6010
5.0
10.0
ND
ND
ND
ND
14-Dec-16
EPA 6010
5.0
10.0
ND
ND
ND
ND
28-Jun-17
EPA 6010
5.0
10.0
ND
ND
ND
-
13-Dec-17
5.0
10.0
ND
ND
ND
ND
16-May-18
EPA 6010
5.0
10.0
ND
ND
ND
-
6-Dec-18
5.0
10.0
ND
ND
ND
ND
8-May-19
EPA 6010D
5.0
10.0
ND
ND
ND
-
8-Nov-19
EPA 6010D
4.7
10.0
ND
ND
ND
-
8-May-20
EPA 6010D
4.7
10.0
ND
ND
ND
ND
11-Nov-20
EPA 6010D
4.7
10.0
ND
ND
ND
-
5-May-21
EPA 6010D
4.7
10.0
ND
ND
ND
ND
4-Nov-21
EPA 6010D
4.7
10.0
-
ND
-
-
19-May-22
EPA 6020B
1.4
5.0
-
ND
ND
-
17-Nov-22
EPA 6020B
1.4
5.0
ND
ND
ND
ND
6-Nov-23
EPA 6010D
4.1
10.0
-
ND
-
ND
Burke County Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 9 of 17 March 2024

TABLE C-4: Historically Detected Surface Water Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
SMP-5
SMP-6
SMP-7
Blanks
Silver
22-May-02
--
10
16.0
B 15.0
B --
15.0
14-Nov-02
--
10
ND
ND
--
ND
14-May-03
--
10
ND
ND
-
ND
20-Nov-03
--
10
ND
ND
-
ND
6-May-04
--
10
ND
ND
-
ND
10-Nov-04
--
10
ND
ND
-
ND
5-May-05
--
10
ND
ND
-
ND
3-Nov-05
--
10
ND
ND
-
ND
25-May-06
--
10
ND
ND
-
ND
2-Nov-06
--
10
ND
ND
-
ND
30-May-07
--
10
ND
ND
-
ND
29-Nov-07
--
10
ND
ND
-
ND
29-May-08
0.10
10.0
0.29
J 0.13
J -
ND
6-Nov-08
0.10
10.0
0.72
B 0.38
B -
0.23 J
3-Jun-09
0.10
10.0
0.18
B ND
-
0.31 J
18-Nov-09
0.10
10.0
0.27
B 0.23
B -
0.23 J
NC 213 = 0.06 pg/I (05/01/07)
15-Jun-10
0.10
10.0
ND
ND
-
ND
1-Dec-10
0.10
10.0
ND
ND
-
ND
1-Jun-11
0.10
10.0
ND
0.22
J -
ND
20-Dec-11
5.0
10.0
ND
ND
-
ND
30-May-12
5.0
10.0
ND
ND
-
ND
5-Dec-12
5.0
10.0
ND
ND
-
ND
12-Jun-13
5.0
10.0
ND
ND
-
ND
28-Oct-13
5.0
10.0
ND
ND
-
ND
6-May-14
EPA 6010
5.0
10.0
ND
ND
-
ND
22-Oct-14
EPA 6010
5.0
10.0
--
ND
ND
ND
21-May-15
EPA 6010
2.5
10.0
ND
ND
ND
ND
9-Dec-15
EPA 6010
2.5
10.0
ND
ND
ND
ND
NC 2B = 0.06 pg/I Chronic (03/01/16)*
4-May-16
EPA 6010
2.5
10.0
ND
ND
ND
ND
14-Dec-16
EPA 6010
2.5
10.0
ND
ND
ND
ND
28-Jun-17
EPA 6010
2.5
10.0
ND
ND
ND
-
NC 2B = 0.30 pg/I (09/22/17)*
13-Dec-17
2.5
10.0
ND
ND
ND
ND
16-May-18
EPA 6010
2.5
10.0
ND
ND
ND
-
6-Dec-18
2.5
5.0
ND
ND
ND
ND
8-May-19
EPA 6O1OD
2.5
5.0
ND
ND
ND
-
8-Nov-19
EPA 6O1OD
2.5
5.0
ND
ND
ND
-
8-May-20
EPA 6O1OD
2.5
5.0
ND
ND
ND
ND
11-Nov-20
EPA 6O1OD
2.5
5.0
ND
ND
ND
-
5-May-21
EPA 6O1OD
2.5
5.0
ND
ND
ND
ND
4-Nov-21
EPA 6O1OD
2.5
5.0
-
ND
-
-
19-May-22
EPA 6O2OB
0.4
5.0
-
ND
ND
-
17-Nov-22
EPA 6O2OB
0.4
5.0
ND
ND
ND
ND
6-Nov-23
EPA 6O1OD
0.5
5.0
-
ND
-
ND
Burke County Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 10 of 17 March 2024

TABLE C-4: Historically Detected Surface Water Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
SMP-5 SMP-6 SMP-7
Blanks
Thallium
5-May-05
--
10
22.0 11.0 ---
ND
3-Nov-05
--
10
20.0 ND -
ND
25-May-06
--
10
ND ND -
ND
2-Nov-06
--
10
ND ND -
ND
30-May-07
--
5.5
0.053 J ND -
ND
29-Nov-07
--
5.5
0.055 J ND -
ND
29-May-08
3.0
5.5
ND ND -
ND
6-Nov-08
3.0
5.5
ND ND -
ND
3-Jun-09
3.0
5.5
ND ND -
ND
18-Nov-09
3.0
5.5
ND ND -
4.2 J
NC 213 = NE (05/01/07)
15-Jun-10
3.0
5.5
3.2 J ND -
ND
1-Dec-10
3.0
5.5
ND ND -
4.0 J
1-Jun-11
3.0
5.5
ND ND -
ND
20-Dec-11
5.4
5.5
ND ND -
ND
30-May-12
5.4
5.5
ND ND -
ND
5-Dec-12
5.4
5.5
ND ND -
ND
12-Jun-13
5.4
5.5
ND ND -
ND
28-Oct-13
5.4
5.5
ND ND -
ND
6-May-14
EPA 6010
5.4
5.5
ND ND -
ND
22-Oct-14
EPA 6010
5.4
5.5
-- ND ND
ND
21-May-15
EPA 6010
5.0
5.5
ND ND ND
ND
9-Dec-15
EPA 6010
5.0
5.5
ND ND ND
ND
NC 213 = 0.24 (03/01/16)
4-May-16
EPA 6010
5.0
5.5
ND ND ND
ND
14-Dec-16
EPA 6010
5.0
5.5
ND ND ND
ND
28-Jun-17
EPA 6O2OB
0.020
5.5
ND ND 0.044 J
--
NC 213 = NE (09/22/17)*
13-Dec-17
0.028
5.5
ND ND ND
ND
16-May-18
EPA 6020
2.500
5.5
ND ND ND
-
6-Dec-18
0.060
0.1
ND ND ND
ND
8-May-19
EPA 6O2OB
0.060
0.1
ND ND ND
-
8-Nov-19
EPA 6O2OB
0.060
0.1
ND ND 0.095 J
-
8-May-20
EPA 6O2OB
0.050
0.1
ND ND ND
ND
11-Nov-20
EPA 6O2OB
0.050
0.1
ND 0.076 J 0.12
-
5-May-21
EPA 6O2OB
0.050
1
ND ND 0.059 J
ND
4-Nov-21
EPA 6O2OB
0.050
0.47
- ND --
-
19-May-22
EPA 6O2OB
0.180
1
- ND ND
-
17-Nov-22
EPA 6O2OB
0.180
1
ND ND ND
ND
6-Nov-23
EPA 6O2OB
0.050
0.2
- ND -
ND
Burke County Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 11 of 17 March 2024

TABLE C-4: Historically Detected Surface Water Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
SMP-5
SMP-6
SMP-7
Blanks
Vanadium
6-Nov-08
0.20
25.0
0.90
B 8.9
B --
2.1 J
3-Jun-09
0.20
25.0
17.4
J 7.5
J
1.0 J
18-Nov-09
0.20
25.0
0.26
B 0.30
B -
0.56 J
NC 2B = NE (05/01/07)
15-Jun-10
0.20
25.0
1.5
B 1.0
B -
0.98 J
1-Dec-10
0.20
25.0
1.1
J 13.7
J -
ND
1-Jun-11
0.20
25.0
1.1
J 0.74
J -
ND
20-Dec-11
5.0
25.0
ND
ND
-
ND
30-May-12
5.0
25.0
ND
ND
-
ND
5-Dec-12
5.0
25.0
ND
ND
-
ND
12-Jun-13
5.0
25.0
7.6
J ND
-
ND
28-Oct-13
5.0
25.0
ND
ND
-
ND
6-May-14
EPA 6010
5.0
25.0
ND
ND
-
ND
22-Oct-14
EPA 6010
5.0
25.0
--
ND
ND
ND
21-May-15
EPA 6010
2.5
25.0
7.5
J ND
4.1 J
ND
9-Dec-15
EPA 6010
2.5
25.0
ND
ND
3.9 J
ND
4-May-16
EPA 6010
2.5
25.0
10.9
J 11.4
J 23.9 J
ND
14-Dec-16
EPA 6010
2.5
25.0
ND
ND
ND
ND
28-Jun-17
EPA 6010
2.5
25.0
ND
ND
3.1 J
-
NC 2B = NE (09/22/17)*
13-Dec-17
2.5
25.0
ND
ND
ND
-
16-May-18
EPA 6010
2.5
25.0
14
J 3
J 3.7 J
-
6-Dec-18
2.5
5.0
5.4
ND
ND
ND
8-May-19
EPA 6O1OD
2.5
5.0
8.9
ND
ND
-
8-Nov-19
EPA 6O1OD
1.3
5.0
8.5
ND
2.4 J
-
8-May-20
EPA 6O1OD
3.9
5.0
6.2
ND
ND
ND
11-Nov-20
EPA 6O1OD
3.9
5.0
12.0
14.6
22.5
-
5-May-21
EPA 6O1OD
3.9
5.0
6.6
ND
ND
ND
4-Nov-21
EPA 6O1OD
3.9
5.0
--
7.1
-
-
19-May-22
EPA 6O2OB
1.9
10.0
--
ND
ND
-
17-Nov-22
EPA 6O2OB
1.9
10.0
3.2
J ND
4.7 J
ND
6-Nov-23
EPA 6O1OD
1.6
5.0
--
ND
--
ND
Burke County Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 12 of 17 March 2024

TABLE C-4: Historically Detected Surface Water Constituents
Sample
EPA
Analyte
Collection Date
Method
DL
RL
SMP-5
SMP-6
SMP-7
Blanks
Zinc
30-May-07
--
10
1.8
B
ND
-
1.6 J
29-Nov-07
--
10
9.6
B
ND
-
3.1 J
29-May-08
0.40
10.0
6.0
B
ND
-
3.0 J
6-Nov-08
0.40
10.0
0.82
B
1.4
B
-
2.7 J
3-Jun-09
0.40
10.0
33.7
B
9.6
B
-
82.0
18-Nov-09
0.40
10.0
2.2
B
2.5
B
-
3.1 J
NC 2B = 50 pg/I (05/01/07)
15-Jun-10
0.40
10.0
ND
ND
-
ND
1-Dec-10
0.40
10.0
8.8
J
6.6
J
-
0.62 J
1-Jun-11
0.40
10.0
15.1
B
21.5
B
-
13.7
20-Dec-11
10.0
10.0
ND
ND
-
ND
30-May-12
10.0
10.0
ND
ND
-
ND
5-Dec-12
10.0
10.0
ND
ND
-
ND
12-Jun-13
10.0
10.0
ND
ND
-
76.5
28-Oct-13
10.0
10.0
ND
ND
-
ND
6-May-14
EPA 6010
10.0
10.0
ND
ND
-
ND
22-Oct-14
EPA 6010
10.0
10.0
--
ND
ND
ND
21-May-15
EPA 6010
5.0
10.0
ND
5.8
J
ND
ND
9-Dec-15
EPA 6010
5.0
10.0
ND
ND
ND
ND
NC 2B = 36.2 pg/I (03/01/16)*
4-May-16
EPA 6010
5.0
10.0
8.7
J
7.7
J
15.2
ND
14-Dec-16
EPA 6010
5.0
10.0
ND
ND
6.9 J
ND
28-Jun-17
EPA 6010
5.0
10.0
5.8
J
17.4
39.4
-
13-Dec-17
5.0
10.0
ND
ND
ND
ND
16-May-18
EPA 6010
5.0
10.0
10.7
ND
ND
--
6-Dec-18
5.0
10.0
5
J
5.3
J
ND
51.4
8-May-19
EPA 6O1OD
5.0
10.0
5.4
J
ND
ND
--
8-Nov-19
EPA 6O1OD
3.9
10.0
ND
ND
ND
-
8-May-20
EPA 6O1OD
9.5
10.0
ND
ND
ND
ND
11-Nov-20
EPA 6O1OD
9.5
10.0
ND
ND
18.4
-
5-May-21
EPA 6O1OD
9.5
10.0
ND
ND
ND
ND
4-Nov-21
EPA 6O1OD
9.5
10.0
-
ND
-
-
19-May-22
EPA 6O2OB
7.0
10.0
-
ND
ND
-
17-Nov-22
EPA 6O2OB
7.0
10.0
ND
ND
16.4
ND
6-Nov-23
EPA 6O1OD
3.0
10.0
--
5.2
J
--
ND
Hardness, Total (SM 234OB)
28-Jun-17
EPA 6010
662.00
662.0
32,900
20,900
10,800
-
13-Dec-17
662.00
662.0
28,900
12,900
7,410
ND
16-May-18
EPA 6010
662.00
NE
26,100
14,900
18,500
-
6-Dec-18
662.00
662.0
33900
11100
10200
ND
8-May-19
662.00
662.0
36800
13000
9330
ND
8-Nov-19
EPA 6O1OD
131.00
662.0
20500
15800
9710
-
8-May-20
EPA 6O1OD
131.00
662.0
24800
9880
9500
-
11-Nov-20
EPA 6O1OD
131.00
662.0
16900
14600
20800
-
5-May-21
EPA 6O1OD
131.00
662.0
32300
14600
10800
-
5-May-21
EPA 6O1OD
131.00
662.0
32300
14600
10800
-
17-Nov-22
EPA 6O2OB
456.00
456.0
19700
16400
50100
-
Mercury
8-Nov-19
EPA 747OA
0.10
0.2
0.16
J„C
0.15
J„C
0.15 J„
--
8-May-20
EPA 747OA
0.12
0.2
ND
ND
ND
0.58
5-May-21
EPA 747OA
0.12
0.2
ND
ND
ND
ND
19-May-22
EPA 747OA
0.13
0.2
--
ND
ND
-
17-Nov-22
EPA 747OA
0.13
0.2
ND
ND
ND
ND
6-Nov-23
EPA 747OA
0.12
0.2
--
ND
--
ND
Magnesium
8-Nov-19
EPA 6O1OD
17.10
100.0
2020
1570
1320
-
11-Nov-20
EPA 6O1OD
67.80
100.0
1820
1320
2040
-
19-May-22
EPA 6O1OD
67.80
100.0
--
ND
ND
-
17-Nov-22
EPA 6O1OD
67.80
100.0
ND
ND
ND
ND
Burke County Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 13 of 17 March 2024

TABLE C-4: Historically Detected Surface Water Constituents
Sample
EPA
Analyte
Collection Date
Method
DL
RL
SMP-5
SMP-6
SMP-7
Blanks
Organics
Acetone
29-Nov-07
--
100
3.6
B ND
5.1 J
29-May-08
20
100
ND
ND
-
ND
6-Nov-08
20
100
ND
ND
-
ND
3-Jun-09
2.2
100
5.7
J ND
-
ND
18-Nov-09
2.2
100
ND
ND
-
ND
NC 2B = NE (05/01/07)
15-Jun-10
2.2
100
2.2
B 2.3
B -
7.2 J
1-Dec-10
2.2
100
ND
ND
-
3.7 J
1-Jun-11
2.2
100
5.4
B 2.9
B -
3.9 J
20-Dec-11
2.2
100
ND
ND
-
ND
30-May-12
2.2
100
ND
ND
-
ND
5-Dec-12
10.0
100
ND
ND
-
ND
12-Jun-13
10.0
100
ND
ND
-
ND
28-Oct-13
10.0
100
ND
ND
-
ND
6-May-14
EPA 8260
10.0
100
ND
ND
-
ND
22-Oct-14
EPA 8260
10.0
100
--
ND
ND
ND
21-May-15
EPA 8260
10.0
100
ND
ND
ND
ND
9-Dec-15
EPA 8260
10.0
100
ND
ND
ND
ND
NC 2B = 1,100 mg/I (03/01/16)
4-May-16
EPA 8260
10.0
100
ND
ND
ND
ND
14-Dec-16
EPA 8260
10.0
100
ND
ND
ND
ND
28-Jun-17
EPA 8260
10.0
100
14.7
J 29.4
J 18 J
35.3 J
NC 2B = NE (09/22/17)
13-Dec-17
10.0
100
ND
ND
ND
ND
16-May-18
EPA 8260
10.0
100
ND
ND
ND
-
6-Dec-18
10.0
25
ND
ND
ND
ND
8-May-19
EPA 826OD
8.2
25
ND
ND
ND
ND
8-Nov-19
EPA 826OD
6.2
25
ND
ND
ND
-
8-May-20
EPA 826OD
6.2
25
ND
ND
ND
ND
11-Nov-20
EPA 826OD
6.2
25
ND
ND
ND
-
5-May-21
EPA 826OD
5.1
25
ND
ND
ND
ND
4-Nov-21
EPA 826OD
5.1
25
ND
ND
ND
ND
19-May-22
EPA 826OD
5.1
25
--
ND
ND
-
Resample>
19-Jul-22
EPA 826OD
5.1
25
ND
ND
ND
ND
17-Nov-22
EPA 826OD
5.1
25
ND
ND
ND
ND
6-Nov-23
EPA 826OD
5.1
25
-
11.1
J -
-
Benzene
28-Jun-17
EPA 8260
0.25
1.0
ND
0.59
J ND
-
NC 2B = 1.19 mg/I (03/01/16)
13-Dec-17
0.25
1.0
ND
ND
ND
ND
16-May-18
EPA 8260
0.25
1.0
ND
ND
ND
-
6-Dec-18
0.25
1.0
ND
ND
ND
ND
8-May-19
EPA 826OD
0.20
1.0
ND
ND
ND
ND
8-Nov-19
EPA 826OD
0.15
1.0
ND
ND
ND
-
8-May-20
EPA 826OD
0.15
1.0
ND
ND
ND
ND
11-Nov-20
EPA 826OD
0.15
1.0
ND
ND
ND
-
5-May-21
EPA 826OD
0.34
1.0
ND
ND
ND
ND
4-Nov-21
EPA 826OD
0.34
1.0
--
ND
-
-
19-May-22
EPA 826OD
0.34
1.0
ND
ND
ND
ND
Resample>
19-Jul-22
EPA 826OD
0.34
1.0
ND
ND
ND
ND
17-Nov-22
EPA 826OD
0.34
1.0
ND
ND
ND
ND
6-Nov-23
EPA 826OD
0.34
1.0
-
ND
-
-
Burke County Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 14 of 17 March 2024

TABLE C-4: Historically Detected Surface Water Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
SMP-5 SMP-6 SMP-7
Blanks
Chloromethane
15-Jun-10
0.11
1.0
ND 0.11 J
ND
NC 213 = NE (05/01/07)
1-Dec-10
0.11
1.0
ND ND -
ND
1-Jun-11
0.11
1.0
ND ND -
ND
20-Dec-11
0.11
1.0
ND ND -
ND
30-May-12
0.11
1.0
ND ND -
ND
5-Dec-12
0.11
1.0
ND ND -
ND
12-Jun-13
0.11
1.0
ND ND -
ND
28-Oct-13
0.11
1.0
ND ND -
ND
6-May-14
EPA 8260
0.11
1.0
ND ND -
ND
22-Oct-14
EPA 8260
0.11
1.0
-- ND ND
ND
21-May-15
EPA 8260
0.11
1.0
ND ND ND
ND
9-Dec-15
EPA 8260
0.11
1.0
ND ND ND
ND
NC 213 = NE (03/01/16)
4-May-16
EPA 8260
0.11
1.0
ND ND ND
ND
14-Dec-16
EPA 8260
0.11
1.0
ND ND ND
0.17 J
28-Jun-17
EPA 8260
0.11
1.0
0.46 J 0.65 J 0.5 J
--
NC 213 = NE (09/22/17)
13-Dec-17
0.11
1.0
ND ND ND
ND
16-May-18
EPA 8260
0.11
1.0
ND ND ND
-
6-Dec-18
0.11
1.0
ND ND ND
ND
8-May-19
EPA 826OD
0.38
1.0
ND ND ND
ND
8-Nov-19
EPA 826OD
0.39
1.0
ND ND ND
-
8-May-20
EPA 826OD
0.39
1.0
ND ND ND
ND
11-Nov-20
EPA 826OD
0.39
1.0
ND ND ND
-
5-May-21
EPA 826OD
0.54
1.0
ND ND ND
ND
4-Nov-21
EPA 826OD
0.54
1.0
-- ND -
-
19-May-22
EPA 826OD
0.34
1.0
ND ND ND
ND
Resample>
19-Jul-22
EPA 826OD
0.34
1.0
ND ND ND
ND
17-Nov-22
EPA 826OD
0.54
1.0
ND ND ND
ND
6-Nov-23
EPA 826OD
0.54
1.0
-- ND -
-
Trichloroethene
14-Dec-16
EPA 8260
0.47
1.0
ND 0.52 J ND
ND
NC 213 = 30 pg/I (03/01/16)
28-Jun-17
EPA 8260
0.47
1.0
ND 1.1 ND
-
13-Dec-17
0.47
1.0
ND 0.47 J ND
ND
16-May-18
EPA 8260
0.47
1.0
ND ND ND
-
6-Dec-18
0.47
1.0
ND ND ND
ND
8-May-19
EPA 826OD
0.34
1.0
ND ND ND
ND
8-Nov-19
EPA 826OD
0.22
1.0
ND ND ND
-
8-May-20
EPA 826OD
0.22
1.0
ND ND ND
ND
11-Nov-20
EPA 826OD
0.22
1.0
ND ND ND
-
5-May-21
EPA 826OD
0.38
1.0
ND ND ND
ND
4-Nov-21
EPA 826OD
0.38
1.0
-- ND -
-
19-May-22
EPA 826OD
0.38
1.0
ND ND ND
ND
Resample>
19-Jul-22
EPA 826OD
0.38
1.0
ND ND ND
ND
17-Nov-22
EPA 826OD
0.38
1.0
ND ND ND
ND
6-Nov-23
EPA 826OD
0.38
1.0
- 0.44 J -
-
Burke County Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 15 of 17 March 2024

TABLE C-4: Historically Detected Surface Water Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
SMP-5 SMP-6 SMP-7
Blanks
1,1-Dichloroethane
1-Jun-11
0.32
5.0
ND 0.41 J --
ND
NC 2B = NE (05/01/07)
20-Dec-11
0.32
5.0
ND ND
ND
30-May-12
0.32
5.0
ND ND -
ND
5-Dec-12
0.32
5.0
ND 1.6 J -
ND
12-Jun-13
0.32
5.0
ND ND -
ND
28-Oct-13
0.32
5.0
ND 0.96 J -
ND
6-May-14
EPA826O
0.32
5.0
ND ND -
ND
22-Oct-14
EPA826O
0.32
5.0
-- 1.5 J ND
ND
21-May-15
EPA826O
0.32
5.0
ND ND ND
ND
9-Dec-15
EPA826O
0.32
5.0
ND ND ND
ND
NC 2B = 0.38 pg/I (03/01/16)
4-May-16
EPA 8260
0.32
5.0
ND ND ND
ND
14-Dec-16
EPA826O
0.32
5.0
ND 2.6 J ND
ND
28-Jun-17
EPA826O
0.32
5.0
ND 4.2 J ND
-
NC 2B = NE (09/22/17)
13-Dec-17
0.32
5.0
ND 1.5 J ND
ND
16-May-18
EPA826O
0.32
5.0
ND ND ND
-
6-Dec-18
0.32
1.0
ND ND ND
ND
8-May-19
EPA 826OD
0.41
1.0
ND ND ND
ND
8-Nov-19
EPA 826OD
0.27
1.0
ND ND ND
-
8-May-20
EPA 826OD
0.27
1.0
ND ND ND
ND
11-Nov-20
EPA 826OD
0.27
1.0
ND ND ND
-
5-May-21
EPA 826OD
0.37
1.0
ND 0.45 J ND
ND
4-Nov-21
EPA 826OD
0.37
1.0
-- 0.97 J -
-
19-May-22
EPA 826OD
0.37
1.0
ND ND ND
ND
Resample>
19-Jul-22
EPA 826OD
0.37
1.0
ND ND ND
ND
17-Nov-22
EPA 826OD
0.37
1.0
ND 0.71 J ND
ND
6-Nov-23
EPA 826OD
0.37
1.0
-- 1.3 -
-
1,4-Dichlorobenzene
16-May-18
EPA826O
0.33
1.0
0.33 J ND ND
-
NC 2B = 488 pg/I
6-Dec-18
0.33
1.0
ND ND ND
ND
(total chlorinated benzenes)
8-May-19
EPA 826OD
0.58
1.0
ND ND ND
ND
8-Nov-19
EPA 826OD
0.26
1.0
ND ND ND
-
8-May-20
EPA 826OD
0.26
1.0
ND ND ND
ND
11-Nov-20
EPA 826OD
0.26
1.0
ND ND ND
-
5-May-21
EPA 826OD
0.33
1.0
ND ND ND
ND
4-Nov-21
EPA 826OD
0.33
1.0
-- ND -
-
19-May-22
EPA 826OD
0.33
1.0
ND ND ND
ND
Resample>
19-Jul-22
EPA 826OD
0.33
1.0
ND ND ND
ND
17-Nov-22
EPA 826OD
0.33
1.0
ND ND ND
ND
6-Nov-23
EPA 826OD
0.33
1.0
- ND -
-
Burke County Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 16 of 17 March 2024

TABLE C-4: Historically Detected Surface Water Constituents
Analyte
Sample
Collection Date
EPA
Method
DL
RL
SMP-5 SMP-6 SMP-7
Blanks
cis-1,2-Dichloroethene
22-Oct-14
EPA 8260
0.19
5.0
-- 0.20 J ND
ND
INC 2B = NE (05/15/13)
21-May-15
EPA 8260
0.19
5.0
ND ND ND
ND
9-Dec-15
EPA 8260
0.19
5.0
ND ND ND
ND
INC 2B = 60 pg/1 (03/01/16)
4-May-16
EPA 8260
0.19
5.0
ND ND ND
ND
14-Dec-16
EPA 8260
0.19
5.0
ND 0.43 J ND
ND
28-Jun-17
EPA 8260
0.19
5.0
ND 1.10 J ND
-
NC 2B = NE (09/22/17)
13-Dec-17
0.19
5.0
ND 0.37 J ND
ND
16-May-18
EPA 8260
0.19
5.0
ND ND ND
-
6-Dec-18
0.2
1.0
ND ND ND
ND
8-May-19
EPA 826OD
0.7
1.0
ND ND ND
ND
8-Nov-19
EPA 826OD
0.3
1.0
ND ND ND
-
8-May-20
EPA 826OD
0.3
1.0
ND ND ND
ND
11-Nov-20
EPA 826OD
0.3
1.0
ND ND ND
-
5-May-21
EPA 826OD
0.4
1.0
ND ND ND
ND
4-Nov-21
EPA 826OD
0.4
1.0
-- 0.47 J -
-
19-May-22
EPA 826OD
0.3
1.0
ND ND ND
ND
Resample>
19-Jul-22
EPA 826OD
0.3
1.0
ND ND ND
ND
17-Nov-22
EPA 826OD
0.4
1.0
ND 0.6 J ND
ND
6-Nov-23
EPA 826OD
0.4
1.0
- 0.97 J -
-
Notes:
All concentrations in micrograms per liter (pg/1) = parts per billion. NI = Monitoringwell not yet installed.
RL = Method Reporting Limit AB = Monitoring well abandoned.
DL = Laboratory Method Detection Limit. - = Not sampled for this parameter or Not reported
ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006).
J = Estimated value - concentration is less than the RL but greater than the DL.
B = Blank -Qualified (Based on similar concentrations detected in field, trip, or method blanks).
INC 2B = Groundwater Standard from 15A NCAC 2B. NE = No INC 2B established.
Values above the NC 2B Standard are bold.
Surface waters classified as WS-W (water supply IV, highly developed), B (primary recreation, fresh water), and CA (critical area).
*NC 2B Groundwater Standards and Protective Values include acute and chronic exposure levels for designated metals
based on dissolved metal and in -stream water hardness results. Site specific values may be calculated based on water hardness at time of sampling.
Burke County Johns River C+D-over-MSW Landfill La Bella Associates
Permit 12-03 Page 17 of 17 March 2024

TABLE C-5: HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Background
Compliance
Sentinel
Analyte/Pa ra meter
Date
Units
MW-17
MW-20
MW-21
MW-11
MW-12
MW-16S
MW-18
MW-19
Temperature (FP)
11/3/2006
°c
14.90
NS
NS
15.25
16.97
16.52
NI
NI
6/3/2009
°C
15.90
NS
NS
19.10
19.40
14.50
16.20
16.30
11/17/2009
°C
12.00
NS
NS
13.90
15.90
13.70
13.80
12.00
6/16/2010
°C
16.06
NS
NS
17.65
17.80
17.69
18.83
16.30
12/1/2010
°C
13.43
NU
NS
11.17
12.27
14.10
14.40
14.60
6/1/2011
°C
17.21
NU
NS
18.39
17.59
21.68
15.04
16.57
12/20/2011
°C
NS
14.30
NS
14.52
14.30
14.69
NS
NS
5/30/2012
°C
NS
18.18
NS
21.70
20.80
16.90
16.99
17.26
12/5/2012
°C
NS
15.40
NS
15.00
15.50
16.90
NS
NS
6/12/2013
°C
NS
18.10
NS
18.70
18.20
16.30
NS
NS
10/28/2013
°C
NS
17.70
NS
18.40
18.20
17.50
1 17.40
17.10
5/6/2014
°C
NS
16.90
NS
22.40
21.00
18.00
14.90
14.50
10/23/2014
°C
NS
*
17.20
13.00
11.50
9.80
NS
NS
5/21/2015
°C
NS
*
19.80
18.70
22.20
18.60
18.10
25.50
12/8/2015
°C
NS
*
15.20
15.40
16.10
16.90
NS
NS
5/3/2016
°C
NS
*
17.90
17.00
18.40
17.20
13.70
15.80
12/13/2016
°C
NS
*
14.40
14.90
14.90
14.80
NS
NS
5/23/2017
°C
NS
*
15.00
1 16.80
17.00
16.80
NS
NS
12/12/2017
°C
NS
*
14.10
16.30
13.90
16.30
12.60
14.60
Resample >
3/19/2018
°C
-
-
-
-
16.00
-
-
-
5/16/2018
°C
NS
NS
18.20
19.00
17.70
16.90
NS
NS
12/6/2018
°C
NS
NS
9.30
14.90
13.10
14.70
1 11.50
12.20
Resample >
2/7/2019
°C
NS
20.90
NS
18.60
NS
NS
NS
NS
5/7/2020
°C
NS
NS
17.20
15.80
1 16.80
15.70
NS
NS
11/11/2020
°C
NS
NS
15.90
17.50
16.70
18.30
17.50
16.60
5/5/2021
°C
NS
NS
17.60
18.00
17.10
17.30
NS
NS
11/3/2021
°C
NS
15.50
16.30
18.10
16.80
17.50
16.40
16.20
Resample >
2/17/2022
°C
NS
17.80
NS
17.20
NS
NS
11.80
NS
11/17/2022
°C
NS
16.50
14.70
17.00
16.30
16.80
15.90
16.10
11/8/2023
°C
NS 18.76
18.02
1 18.27
17.83
18.25
16.91
16.79
pH (FP)
11/3/2006
S.U.
5.34
NS
NS
5.32
5.40
5.68
NI
NI
6/3/2009
S.U.
5.79
NS
NS
5.74
5.62
5.96
6.20
6.28
11/17/2009
S.U.
6.03
NS
NS
5.92
5.49
6.08
5.84
6.24
6/16/2010
S.U.
6.23
NS
NS
6.37
6.28
5.64
1 6.28
6.05
12/1/2010
S.U.
5.40
NU
NS
6.10
6.10
6.05
6.52
6.36
6/1/2011
S.U.
5.83
NU
NS
1 6.01
5.96
5.87
6.25
6.24
12/20/2011
S.U.
NS
6.12
NS
5.98
5.90
6.01
NS
NS
5/30/2012
S.U.
NS
6.61
NS
5.74
5.57
5.61
5.84
5.76
12/5/2012
S.U.
NS
5.41
NS
6.12
5.93
5.75
NS
NS
6/12/2013
S.U.
NS
5.92
NS
6.00
5.32
5.57
NS
NS
10/28/2013
S.U.
NS
6.89
NS
5.85
5.88
5.76
6.12
6.22
5/6/2014
S.U.
NS
5.37
NS
5.46
5.69
5.74
5.41
5.74
10/23/2014
S.U.
NS
*
5.52
1 5.80
5.64
5.41
NS
NS
5/21/2015
S.U.
NS
*
5.29
6.03
6.25
5.88
6.09
6.19
12/8/2015
S.U.
NS
*
5.13
6.06
5.81
5.66
NS
NS
5/3/2016
S.U.
NS
*
4.83
5.54
5.34
5.06
5.30
5.29
12/13/2016
S.U.
NS
*
5.17
6.05
6.22
5.77
1 NS
NS
6/27/2017
S.U.
NS
*
6.45
6.06
5.99
5.95
NS
NS
12/12/2017
S.U.
NS
*
7.26
5.94
6.26
6.14
6.05
6.24
Resample >
3/19/2018
S.U.
NS
NS
NS
NS
5.83
NS
NS
NS
5/16/2018
S.U.
NS
NS
6.60
5.62
5.70
5.65
NS
NS
12/6/2018
S.U.
NS
NS
5.41
6.17
6.13
5.85
6.03
6.02
Resample >
2/7/2019
S.U.
NS
5.77
NS
6.24
NS
NS
NS
NS
5/7/2020
S.U.
NS
NS
4.95
6.12
5.73
5.65
NS
NS
11/11/2020
S.U.
NS
NS
6.05
6.19
5.72
5.65
5.87
5.93
5/5/2021
S.U.
NS
NS
4.80
5.99
5.61
5.70
NS
NS
11/3/2021
S.U.
NS
5.82
4.63
6.08
5.70
5.61
5.92
5.81
Resample >
2/17/2022
S.U.
NS
6.45
NS
7.02
NS
NS
6.96
NS
11/17/2022
S.U.
NS
5.37
4.00
5.86
5.47
5.03
5.82
5.54
11/8/2023
S.U.
NS
10.76
10.96
10.97
10.81
10.36
10.94
10.81
Burke Co.- Johns River C+D-over-MSWLF La Bella Associates
Permit No. 12-03 Page 1 of 10 March 2024

TABLE C-5: HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Background
Compliance
Sentinel
Analyte/Parameter
Date
Units
MW-17
MW-20
MW-21
MW-11
MW-12
MW-16S
MW-18
MW-19
Conductivity (FP)
11/3/2006
PS/CM
59.0
NS
NS
133.0
95.0
207.0
NI
NI
6/3/2009
NS/cm
139.5
NS
NS
258.0
146.2
286.0
220.0
329.0
11/17/2009
NS/Cm
182.7
NS
NS
279.0
146.9
245.0
218.0
330.0
6/16/2010
pS/cm
124.0
NS
NS
310.0
214.0
213.0
216.0
309.0
12/1/2010
NS/Cm
143.0
NU
NS
235.0
133.0
160.0
292.0
310.0
6/1/2011
NS/Cm
69.0
NU
NS
384.0
175.0
293.0
241.0
392.0
12/20/2011
NS/Cm
NS
26.0
NS
1 314.0
152.0
229.0
NS
NS
5/30/2012
NS/Cm
NS
26.0
NS
392.0
177.0
229.0
227.0
256.0
12/5/2012
NS/Cm
NS
19.5
NS
370.1
148.8
197.4
NS
NS
6/12/2013
NS/Cm
NS
29.8
NS
345.2
201.7
201.7
NS
NS
10/28/2013
NS/Cm
NS
24.5
NS
430.0
189.5
229.9
215.6
295.2
5/6/2014
NS/Cm
NS
30.1
NS
460.7
208.5
230.4
179.0
276.9
10/23/2014
NS/Cm
NS
*
68.1
311.0
170.2
103.8
NS
NS
5/21/2015
NS/Cm
NS
*
27.2
1 435.4
221.5
231.2
262.0
412.2
12/8/2015
NS/Cm
NS
*
15.5
400.6
203.4
208.5
NS
NS
5/3/2016
NS/Cm
NS
*
16.0
473.5
247.0
221.0
292.0
256.9
12/13/2016
NS/Cm
NS
*
180.4
458.0
198.0
215.0
NS
NS
6/27/2017
NS/Cm
NS
*
28.9
450.1
234.6
226.1
NS
NS
12/12/2017
NS/Cm
NS
*
14.1
347.9
185.8
215.7
123.6
226.3
Resample >
3/19/2018
NS/Cm
NS
NS
NS
NS
209.4
NS
NS
NS
5/16/2018
NS/Cm
NS
NS
13.5
1 375.2
207.4
243.2
NS
NS
12/6/2018
NS/Cm
NS
NS
31.3
363.1
193.5
232.4
141.5
211.5
Resample >
2/7/2019
NS/Cm
NS
19.5
NS
465.1
NS
NS
NS
NS
5/7/2020
NS/Cm
NS
NS
14.4
554.5
265.3
280.2
NS
NS
11/11/2020
NS/Cm
NS
NS
17.3
521.7
246.0
254.4
137.9
231.6
5/5/2021
NS/Cm
NS
NS
12.0
465.9
194.1
222.6
NS
NS
11/3/2021
NS/Cm
NS
19.5
16.0
842.0
326.2
340.8
308.2
377.4
Resample >
2/17/2022
NS/Cm
NS
18.1
NS
766.0
NS
NS
304.0
NS
11/17/2022
NS/Cm
NS
18.8
13.1
676.0
267.8
39.0
307.0
316.0
11/8/2023
NS/Cm
NS
23.0
11.0
750.0
282.0
252.0
305.0
314.0
ORP (FP)
11/3/2006
mV
93.8
NS
NS
143.9
90.5
43.2
NI
NI
6/3/2009
mV
195.0
NS
NS
150.0
130.0
138.0
132.0
113.0
11/17/2009
mV
167.0
NS
NS
133.0
162.0
132.0
158.0
128.0
6/16/2010
mV
13.8
NS
NS
-12.5
-58.6
-73.4
-36.8
-63.5
12/1/2010
mV
31.6
NU
NS
-49.1
-74.7
-105.9
NS
NS
6/1/2011
mV
73.2
NU
NS
28.6
-7.2
40.1
10.3
-2.6
12/20/2011
mV
NS
56.8
NS
18.7
30.3
3.9
1 NS
NS
5/30/2012
mV
NS
7.1
NS
-14.8
38.9
21.7
26.7
20.1
12/5/2012
mV
NS
227.2
NS
-6.9
46.0
23.4
NS
NS
6/12/2013
mV
NS
104.7
NS
-38.0
29.6
86.4
NS
NS
10/28/2013
mV
NS
21.7
NS
-10.5
53.2
47.3
-7.2
5.4
5/6/2014
mV
NS
116.5
NS
21.0
29.7
228.0
94.2
33.9
10/23/2014
mV
NS
*
104.6
-2.3
-3.8
36.6
NS
NS
5/21/2015
mV
NS
*
136.8
21.9
66.0
46.9
66.0
12.5
12/8/2015
mV
NS
*
269.9
-21.4
-6.2
25.7
NS
NS
5/3/2016
mV
NS
*
80.4
14.1
29.3
57.3
29.9
45.7
12/13/2016
mV
NS
*
180.4
29.0
18.1
70.9
NS
NS
6/27/2017
mV
NS
*
184.2
1 5.3
10.7
20.5
NS
NS
12/12/2017
mV
NS
*
121.2
111.0
42.0
27.0
90.7
11.0
Resample >
3/19/2018
mV
NS
NS
NS
NS
-11.5
NS
NS
NS
5/16/2018
mV
NS
NS
154.0
-30.4
-16.8
-26.8
NS
NS
12/6/2018
mV
NS
NS
205.5
11.8
38.9
14.2
31.2
19.9
Resample >
2/7/2019
mV
NS
219.9
NS
NS
NS
NS
NS
NS
5/7/2020
mV
NS
NS
219.5
290.1
181.4
201.6
NS
NS
11/11/2020
mV
NS
NS
246.1
1 13.8
122.9
87.5
85.8
27.2
5/5/2021
mV
NS
NS
247.6
-4.3
52.1
56.6
NS
NS
11/3/2021
mV
NS
108.9
316.8
-45.1
18.2
1 28.4
13.7
12.9
Resample >
2/17/2022
mV
NS
188.5
NS
7.3
NS
NS
82.9
NS
11/17/2022
mV
NS
215.4
317.1
-38.1
16.6
185.6
0.3
24.7
11/8/2023
mV
NS
-99.4
-21.4
-238.3
16.6
-249.0
1 -308.0
1 -275.0
Burke Co.- Johns River C+D-over-MSWLF La Bella Associates
Permit No. 12-03 Page 2 of 10 March 2024

TABLE C-5: HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Background
Compliance
Sentinel
Analyte/Parameter
Date
Units
MW-17
MW-20
MW-21
MW-11
MW-12
MW-16S
MW-18
MW-19
Turbidity (FP)
11/3/2006
NTU
10.4
NS
NS
7.97
64.0
16.3
NI
NI
6/3/2009
NTU
154
NS
NS
20.6
7.54
39.1
390
125
11/17/2009
NTU
318
NS
NS
19.65
7.89
23.0
<100
22.2
6/16/2010
NTU
44.8
NS
NS
165
95.9
43.2
14.9
9.29
12/1/2010
NTU
20.2
NU
NS
31
46.4
43.1
>1000
463
6/1/2011
NTU
7.58
NU
NS
19.06
13.14
5.74
33.4
59.6
12/20/2011
NTU
NS
80.4
NS
1 46.30
36.70
24.80
NS
NS
5/30/2012
NTU
NS
14.0
NS
19.80
33.50
15.90
20.60
27.30
12/5/2012
NTU
NS
631
NS
19.50
23.5
7.14
NS
NS
6/12/2013
NTU
NS
21.3
NS
10.82
15.8
8.11
NS
NS
10/28/2013
NTU
NS
7.39
NS
8.30
6.41
4.31
4.62
14.3
5/6/2014
NTU
NS
37.1
NS
12.95
6.05
4.29
37.0
9.20
10/23/2014
NTU
NS
*
8.15
21.7
10.04
7.55
NS
NS
5/21/2015
NTU
NS
*
8.15
1 12.6
17.5
7.72
9.10
11.13
12/8/2015
NTU
NS
*
25.5
16.7
35.4
30.5
NS
NS
5/3/2016
NTU
NS
*
17.55
19.75
16.88
18.3
21.3
28.1
12/13/2016
NTU
NS
*
12.63
9.48
10.2
9.70
NS
NS
6/27/2017
NTU
NS
*
12.2
7.29
9.78
11.60
NS
NS
12/12/2017
NTU
NS
*
15.01
37.81
25.6
12.22
90.7
57.76
Resample >
3/19/2018
NTU
NS
NS
NS
NS
7.36
NS
NS
NS
5/16/2018
NTU
NS
NS
5.89
1 7.96
9.91
15.12
NS
NS
12/6/2018
NTU
NS
NS
5.40
10.5
21.1
17.8
7.47
223
Resample >
2/7/2019
NTU
NS
71.1
NS
10.7
NS
NS
NS
NS
5/7/2020
NTU
NS
NS
642
36.37
506.3
57.7
NS
NS
11/11/2020
NTU
NS
NS
318
>1000
101
47.0
120
16.4
5/5/2021
NTU
NS
NS
18.5
10.5
12.0
8.12
1 NS
NS
11/3/2021
NTU
NS
587
26.6
11.3
16.4
9.65
268
3.05
Resample >
2/17/2022
NTU
NS
32.5
NS
6.8
NS
NS
546
NS
11/17/2022
NTU
NS
544
13.9
6.20
8.70
439
258
6.97
11/8/2023
NTU
NS
189
9.45
9.18
14.9
8.77
187
8.71
Dissolved Oxygen (FP)
11/3/2006
mg/L
4.01
NS
NS
0.95
1.21
1.10
NI
NI
6/3/2009
mg/L
1.21
NS
NS
0.84
0.57
0.99
1 1.38
0.60
11/17/2009
mg/L
NS
NS
NS
2.35
4.12
3.50
2.23
3.20
6/16/2010
mg/L
4.61
NS
NS
2.49
2.86
2.10
3.59
4.16
12/1/2010
mg/L
7.94
NU
NS
1.29
1.29
5.15
NS
NS
6/1/2011
mg/L
4.76
NU
NS
2.46
1.77
1.64
3.80
3.27
12/20/2011
mg/L
NS
8.18
NS
1.87
2.17
2.17
NS
NS
5/30/2012
mg/L
NS
6.24
NS
3.67
6.33
1.98
8.47
8.11
12/5/2012
mg/L
NS
7.29
NS
1 2.09
3.57
0.99
NS
NS
6/12/2013
mg/L
NS
8.68
NS
1.53
1.25
1.75
NS
NS
10/28/2013
mg/L
NS
7.14
NS
3.42
2.47
2.82
3.62
3.21
5/6/2014
mg/L
NS
7.83
NS
1.89
1.47
1.33
2.25
1.86
10/23/2014
mg/L
NS
NS
5.74
2.78
1.36
2.75
NS
NS
5/21/2015
mg/L
NS
NS
5.66
1.01
1.79
0.01
1.01
0.10
12/8/2015
mg/L
NS
NS
7.59
4.62
2.47
1.49
NS
NS
5/3/2016
mg/L
NS
NS
7.26
1.60
2.23
3.35
4.19
2.20
12/13/2016
mg/L
NS
NS
5.41
5.11
3.23
2.07
NS
NS
6/27/2017
mg/L
NS
NS
7.06
2.40
4.75
2.16
NS
NS
12/12/2017
mg/L
NS
NS
9.05
3.38
4.41
4.40
3.85
2.52
Resample >
3/19/2018
mg/L
NS
NS
NS
NS
1.10
NS
NS
NS
5/16/2018
mg/L
NS
NS
6.54
1.79
2.01
1.21
NS
NS
12/6/2018
mg/L
NS
NS
10.60
4.16
8.24
1.89
2.46
2.29
Resample >
2/7/2019
mg/L
NS
4.38
NS
NS
NS
NS
NS
NS
5/7/2020
mg/L
NS
NS
1.60
5.82
5.42
4.78
NS
NS
11/11/2020
mg/L
NS
NS
8.67
2.07
2.37
2.19
1.83
1.37
5/5/2021
mg/L
NS
NS
10.00
1.27
1.59
1.54
NS
NS
11/3/2021
mg/L
NS
6.75
5.79
0.35
0.29
0.47
0.83
0.30
Resample >
2/17/2022
mg/L
NS
7.57
NS
0.71
NS
NS
2.22
NS
11/17/2022
mg/L
NS
7.81
6.30
0.40
0.11
2.76
0.34
1 0.06
11/8/2023
mg/L
NS
12.24
6.80
1.07
0.53
2.15
3.61
1 1.45
Burke Co.- Johns River C+D-over-MSWLF La Bella Associates
Permit No. 12-03 Page 3 of 10 March 2024

TABLE C-5: HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Background
Compliance
Sentinel
Analyte/Parameter
Date
Units
MW-17
MW-20
MW-21
MW-11
MW-12
MW-16S
MW-18
MW-19
Carbon Dioxide (FP)
11/3/2006
mg/L
NS
NS
NS
NS
NS
NS
NI
NI
6/3/2009
mg/L
170
NS
NS
295
255
325
185
315.60
11/17/2009
mg/L
220
NS
NS
355
335
385
NS
280
6/16/2010
mg/L
220
NS
NS
510
395
430
185
280
12/1/2010
mg/L
25
NU
NS
440
285
230
NS
NS
6/1/2011
mg/L
NS
NU
NS
NS
NS
NS
NS
NS
12/20/2011
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
5/30/2012
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
12/5/2012
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
6/12/2013
mg/L
NS
25.0
NS
80
95
90
NS
NS
10/28/2013
mg/L
NS
25.0
NS
335
240
130
160
130
5/6/2014
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
10/23/2014
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
5/21/2015
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
12/8/2015
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
5/3/2016
mg/L
NS
NS
30
95
85
155
220
150
12/13/2016
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
6/27/2017
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
12/12/2017
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
5/16/2018
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
12/6/2018
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
5/7/2020
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
11/11/2020
mg/L
NS
NS
27.1
164
167
191
97.4
189
Resample >
1/27/2021
mg/L
NS
NS
31.1
193
178
208
96.8
192
5/5/2021
mg/L
NS
NS
36.1 D
247 D
173 D
219 D
NS
NS
11/3/2021
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
11/17/2022
mg/L
NS
NS
ND
ND
ND
ND
118000
46100
11/8/2023
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
Iron II (ferrous iron) (FP)
11/3/2006
mg/L
NS
NS
NS
0.5
6.4
7.5
NI
NI
6/3/2009
mg/L
0.0
NS
NS
5.9
9.5
9.4
7.2
9.4
11/17/2009
mg/L
0.0
NS
NS
5.0
6.8
4.0
4.0
6.0
6/16/2010
mg/L
6.5
NS
NS
8.0
6.5
4.0
5.0
8.8
12/1/2010
mg/L
0.0
NU
NS
6.2
4.6
10.0
NS
NS
6/1/2011
mg/L
NS
NU
I NS
NS
NS
NS
NS
NS
12/20/2011
mg/L
NS
0.0
NS
6.1
4.5
5.6
NS
NS
5/30/2012
mg/L
NS
0.0
NS
5.6
3.8
5.2
3.2
3.3
12/5/2012
mg/L
NS
0.0
NS
5.2
4.0
6.3
NS
NS
6/12/2013
mg/L
NS
0.0
NS
6.0
4.2
3.0
NS
NS
10/28/2013
mg/L
NS
0.0
NS
5.5
9.0
4.8
6.5
6.0
5/6/2014
mg/L
NS
0.0
NS
7.3
4.3
5.8
5.0
5.8
10/23/2014
mg/L
NS
NS
0.0
4.5
7.0
3.8
NS
NS
5/21/2015
mg/L
NS
NS
0.0
5.8
7.0
7.0
4.7
5.8
12/8/2015
mg/L
NS
NS
0.0
3.5
2.0
3.2
NS
NS
5/3/2016
mg/L
NS
NS
0.8
4.5
5.0
3.5
3.4
4.0
12/13/2016
mg/L
NS
NS
0.5
5.2
3.0
2.2
NS
NS
6/27/2017
mg/L
NS
NS
1.0
4.0
0.5
1.5
NS
NS
12/12/2017
mg/L
NS
NS
0.0
5.2
4.6
5.0
2.4
4.1
5/16/2018
mg/L
NS
NS
0.0
2.2
4.0
2.0
NS
NS
12/6/2018
mg/L
NS
NS
0.0
2.3
2.0
2.1
3.0
3.5
5/7/2020
mg/L
NS
NS
0.0
2.0
1.5
1.0
NS
NS
11/11/2020
mg/L
NS
NS
NS
NS
1.8
0.75
NS
2.0
Resample >
1/27/2021
mg/L
NS
NS
0.0
1.5
NS
NS
0.5
NS
5/5/2021
mg/L
NS
NS
0.0
1.8
1.5
1 3.5
NS
NS
11/3/2021
mg/L
NS
NS
1 0.0
2.5
1.5
1.5
1 1.5
1.5
11/17/2022
mg/L
NS
NS
0.0
1.0
0.5
1.4
1.0
1.0
11/8/2023
mg/L
NS
NS
0.0
5.0
3.5
2.0
NS
2.0
Burke Co.- Johns River C+D-over-MSWLF La Bella Associates
Permit No. 12-03 Page 4 of 10 March 2024

TABLE C-5: HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Background
Compliance
Sentinel
Analyte/Parameter
Date
Units
MW-17
MW-20
MW-21
MW-11
MW-12
MW-16S
MW-18
MW-19
Nitrate
11/3/2006
mg/L
NS
NS
NS
<0.5
<0.5
<0.5
NI
NI
6/3/2009
mg/L
<0.1
NS
NS
<0.1
<0.1
<0.1
<0.1
0.26
11/17/2009
mg/L
<0.1
NS
NS
<0.1
<0.1
<0.1
<0.1
<0.1
6/16/2010
mg/L
<0.1
NS
NS
<0.1
<0.1
<0.1
<0.1
<0.1
12/1/2010
mg/L
<0.1
NU
NS
<0.1
<0.1
<0.1
NS
NS
6/1/2011
mg/L
<0.1
NU
NS
<0.1
<0.1
<0.1
<0.1
<0.1
12/20/2011
mg/L
NS
<0.1
NS
<0.1
<0.1
<0.1
NS
NS
5/30/2012
mg/L
NS
.207 J
NS
<0.1
<0.1
<0.1
<0.1
<0.1
12/5/2012
mg/L
NS
.294 J
NS
<0.1
<0.1
<0.1
NS
NS
6/12/2013
mg/L
NS
.384 J
NS
<0.1
<0.1
<0.1
NS
NS
10/28/2013
mg/L
NS
.333 J
NS
<0.1
<0.1
<0.1
<0.1
<0.1
5/6/2014
mg/L
NS
.282 J
NS
<0.1
<0.1
<0.1
<0.1
<0.1
10/23/2014
mg/L
NS
NS
<0.1
<0.1
<0.1
<0.1
NS
NS
5/21/2015
mg/L
NS
NS
I <0.1
<0.1
<0.1
<0.1
<0.1
<0.1
12/8/2016
mg/L
NS
NS
.256 J
<0.1
<0.1
<0.1
NS
NS
5/3/2016
mg/L
NS
NS
0.120J
ND
ND
ND
<0.1
<0.1
12/13/2016
mg/L
NS
NS
0.210J
ND
ND
ND
NS
NS
6/27/2017
mg/L
NS
NS
.201J
ND
ND
ND
NS
NS
12/12/2017
mg/L
NS
NS
0.183J
ND
ND
ND
0.386J
ND
5/16/2018
mg/L
NS
NS
.1911
ND
ND
ND
NS
NS
12/6/2018
ug/L
NS
NS
222
ND
ND
ND
ND
ND
5/7/2020
ug/L
NS
NS
178
ND
ND
ND
NS
NS
11/11/2020
ug/L
NS
NS
163
ND
ND
ND
ND
NS
Resample >
12/2/2020
ug/L
NS
NS
152
NS
39.1 J
37.2 J
ND
52.50
5/5/2021
ug/L
NS
NS
155
ND
ND
ND
NS
NS
11/3/2021
ug/L
NS
ND
ND
ND
ND
ND
ND
ND
11/17/2022
ug/L
NS
ND
171
ND
ND
ND
ND
ND
11/8/2023
ug/L
NS
NS
150
ND
52.00
76.00
ND
ND
Alkalinity
11/3/2006
mg/L
NS
NS
NS
47
36
106
NI
NI
6/3/2009
mg/L
163
NS
NS
112
62.5
76.6
80.8
128
11/17/2009
mg/L
70.8
NS
NS
121
50.0
83.3
81.2
115
6/16/2010
mg/L
61.2
NS
NS
154
59.1
111
74.7
185
12/1/2010
mg/L
35.2
NU
NS
1 156
86.9
64.4
NS
NS
6/1/2011
mg/L
45.1
NU
NS
177
70.7
109
84.6
132
12/20/2011
mg/L
NS
8.58
NS
189
70.8
77.2
NS
NS
5/30/2012
mg/L
NS
8.14
NS
200
76.7
104
107.0
150.0
12/5/2012
mg/L
NS
7.69
NS
178
76.6
106
NS
NS
6/12/2013
mg/L
NS
7.95
NS
202
111
99.7
NS
NS
10/28/2013
mg/L
NS
8.14
NS
197
91.3
116
NS
NS
5/6/2014
mg/L
NS
8.06
NS
1 208
90.6
119
68.90
113.0
10/23/2014
mg/L
NS
*
1.36 J
215
96.1
122
NS
NS
5/21/2015
mg/L
NS
*
ND
153.0
67.5
92.1
51.300
154.000
12/8/2015
mg/L
NS
*
1.030 J
202.0
88.8
95.9
NS
NS
5/3/2016
mg/L
NS
*
1.370 J
122.0
49.0
76.8
62.500
100.000
12/13/2016
mg/L
NS
*
1.190 J
106.0
45.6
77.6
NS
NS
6/27/2017
mg/L
NS
*
ND
165.0
98.7
99.1
NS
NS
12/12/2017
mg/L
NS
*
ND
1 117.0
69.0
92.1
59.30
119.000
5/16/2018
mg/L
NS
*
2.34
151.0
94.4
99.3
NS
NS
12/6/2018
ug/L
NS
*
NS
196,000
122,000
128,000
81,700
133,000
5/7/2020
ug/L
NS
NS
ND
141,000
67,300
114,000
NS
NS
11/11/2020
ug/L
NS
NS
NS
156,000
103,000
135,000
56,900
NS
Resample>
12/2/2020
ug/L
NS
NS
ND
NS
NS
NS
NS
110,000
5/5/2021
ug/L
NS
NS
ND
210,000
88,000
124,000
1 NS
NS
11/3/2021
ug/L
NS
5820.00
ND
123,000
97,000
117,000
58,900
142,000
11/17/2022
ug/L
NS
ND
ND
165,000
115,000
151,000
92,400
14,500
11/8/2023
ug/L
NS
ND
ND
213,000
134,000
136,000
114,000
176,000
Burke Co.- Johns River C+D-over-MSWLF La Bella Associates
Permit No. 12-03 Page 5 of 10 March 2024

TABLE C-5: HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Background
Compliance
Sentinel
Analyte/Parameter
Date
Units
MW-17
MW-20
MW-21
MW-11
MW42
MW-16S
MW-18
MW-19
Chloride
11/3/2006
mg/L
NS
INS
INS
9.30
1.69
2.49
NI
NI
6/3/2009
mg/L
<5.0
INS
INS
16.1
<5.0
6.7
5.9
<5.0
11/17/2009
mg/L
<5.0
INS
INS
16.8
<5.0
<5.0
6.8
<5.0
6/16/2010
mg/L
<5.0
INS
INS
5.45
6.29
8.55
8.23
<5.0
12/1/2010
mg/L
<5.0
NU
INS
15.1
6.84
<5.0
INS
INS
6/1/2011
mg/L
<5.0
NU
INS
17.0
6.33
7.87
9.45
<5.0
12/20/2011
mg/L
INS
<5.0
INS
20.2
6.40
6.53
INS
INS
5/30/2012
mg/L
INS
1.48
INS
20.0
6.32
5.84
133.0
2.79
12/5/2012
mg/L
INS
2.13
INS
19.5
7.29
7.43
INS
INS
6/12/2013
mg/L
INS
1.38
INS
19.5
7.50
5.1
INS
INS
10/28/2013
mg/L
INS
1.12
INS
18.1
7.75
8.49
INS
INS
5/6/2014
mg/L
INS
ND
INS
18.2
8.14
8.92
13.50
2.41
10/23/2014
mg/L
INS
INS
ND
20.8
9.05
8.12
INS
INS
5/21/2015
mg/L
INS
*
ND
1 25.300
9.680
10.400
12.400
2.500
12/8/2015
mg/L
INS
*
0.859 J
30.800
9.400
4.190
INS
INS
5/3/2016
mg/L
INS
*
6.07
33.700
14.000
7.980
13.600
7.150
12/13/2016
mg/L
INS
*
1.330
30.300
10.700
8.240
INS
INS
6/27/2017
mg/L
INS
*
ND
11.500
29.700
10.400
INS
INS
12/12/2017
mg/L
INS
*
ND
39.000
10.900
8.430
10.700
2.980
5/16/2018
mg/L
INS
*
1.10
34.20
9.55
5.73
INS
INS
12/6/2018
ug/L
INS
*
1020
1 52900
11700
9740
7340
3010
5/7/2020
ug/L
INS
INS
1270
44500
13400
10400
INS
INS
11/11/2020
ug/L
INS
INS
720J
62600
14100
7210
8870
INS
Resample >
12/2/2020
ug/L
INS
INS
INS
INS
INS
INS
INS
2720
5/5/2021
ug/L
INS
INS
601J
76100 D
14900
9730
INS
INS
11/3/2021
ug/L
INS
9400
588J
77000
14300
6940
12400
2580
11/17/2022
ug/L
INS
ND
2510
72600
15200
10700
13500
2500
11/8/2023
ug/L
INS
1100
ND
1 93800
17000
13000
11800
1500
Sulfate
11/3/2006
mg/L
INS
INS
INS
3.72
<2
<2
NI
NI
6/3/2009
mg/L
<5.1
INS
INS
<5.0
<5.0
<5.0
5.8
ND
11/17/2009
mg/L
<5.0
INS
INS
<5.0
<5.0
<5.0
1 <5.0
<5.0
6/16/2010
mg/L
<5.0
INS
INS
<5.0
<5.0
<5.0
<5.0
<5.0
12/1/2010
mg/L
<2.5
NU
INS
<12.5
<12.5
<12.5
NS
NS
6/1/2011
mg/L
<5.0
NU
I NS
<5.0
1 <5.0
<5.0
<5.0
<5.0
12/20/2011
mg/L
NS
<5.0
NS
<5.0
<5.0
<5.0
NS
NS
5/30/2012
mg/L
NS
<5.0
NS
<5.0
<5.0
<5.0
<5.0
<5.0
12/5/2012
mg/L
NS
ND
NS
ND
4.4J
ND
INS
INS
6/12/2013
mg/L
INS
ND
INS
3.08J
2.91J
ND
INS
INS
10/28/2013
mg/L
INS
ND
INS
ND
2.94J
ND
INS
INS
5/6/2014
mg/L
INS
ND
INS
2.30 J
3.72 J
2.07 J
ND
2.49 J
10/23/2014
mg/L
INS
*
ND
2.28 J
3.74 J
1.94 J
INS
INS
5/21/2015
mg/L
INS
*
ND
2.310 J
3.440 J
2.750 J
1.700 J
1.980 J
12/8/2015
mg/L
INS
*
ND
1.530 J
2.020 J
9.260 J
INS
INS
5/3/2016
mg/L
INS
*
1.090 J
5.490 J
3.440 J
8.720 J
2.900 J
3.020 J
12/13/2016
mg/L
INS
*
ND
ND
4.020J
10.700J
INS
INS
6/27/2017
mg/L
INS
*
ND
2.20J
3.20J
ND
INS
INS
12/12/2017
mg/L
INS
*
ND
2.23J
2.08J
ND
ND
1.25J
5/16/2018
mg/L
INS
*
ND
1.78J
1.58J
ND
INS
INS
12/6/2018
ug/L
INS
*
ND
1,720
1,450
621J
ND
1270
5/7/2020
ug/L
INS
INS
ND
3,640
2,520
ND
INS
INS
11/11/2020
ug/L
INS
INS
ND
3,680
1,200
590.00
ND
INS
Resample >
12/2/2020
ug/L
INS
INS
INS
INS
INS
INS
INS
1,590
5/5/2021
ug/L
INS
INS
ND
4,560
1,100
5101
INS
INS
11/3/2021
ug/L
INS
ND
I ND
4,400
960J
ND
ND
1,220
11/17/2022
ug/L
INS
ND
ND
3,330
862J
602J
530
1,340
11/8/2023
ug/L
INS
ND
ND
6,900
1,200
1,100
540J
2,400
Burke Co.- Johns River C+D-over-MSWLF La Bella Associates
Permit No. 12-03 Page 6 of 10 March 2024

TABLE C-5: HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Background
Compliance
Sentinel
Analyte/Parameter
Date
Units
MW-17
MW-20
MW-21
MW-11
MW-12
MW-16S
MW-18
MW-19
Sulfide
11/3/2006
mg/L
INS
INS
INS
3.72
<2
<2
NI
NI
6/3/2009
mg/L
<0.10
INS
INS
<0.10
<0.10
<0.10
<0.10
ND
11/17/2009
mg/L
<0.10
INS
INS
<0.10
<0.10
<0.10
INS
INS
6/16/2010
mg/L
<0.10
INS
INS
<0.10
<0.10
<0.10
<0.10
<0.10
12/1/2010
mg/L
<0.10
NU
INS
<0.10
<0.10
<0.10
INS
INS
6/1/2011
mg/L
INS
NU
INS
INS
INS
INS
INS
INS
12/20/2011
mg/L
INS
INS
INS
INS
INS
INS
INS
INS
5/30/2012
mg/L
INS
INS
INS
INS
INS
INS
INS
INS
12/5/2012
mg/L
INS
ND
INS
ND
ND
ND
INS
INS
6/12/2013
mg/L
INS
ND
INS
ND
ND
ND
INS
INS
10/28/2013
mg/L
INS
ND
INS
ND
ND
ND
ND
ND
5/6/2014
mg/L
INS
INS
INS
INS
INS
INS
INS
INS
10/23/2014
mg/L
INS
*
ND
ND
ND
ND
INS
INS
5/21/2015
mg/L
INS
*
INS
INS
INS
INS
INS
INS
12/8/2015
mg/L
INS
*
ND
ND
ND
ND
INS
INS
5/3/2016
mg/L
INS
*
ND
ND
ND
ND
ND
ND
12/13/2016
mg/L
INS
*
ND
ND
ND
ND
INS
INS
6/27/2017
mg/L
INS
*
ND
ND
ND
ND
INS
INS
12/12/2017
mg/L
INS
*
ND
ND
ND
ND
INS
INS
5/16/2018
mg/L
INS
*
ND
ND
ND
ND
INS
INS
12/6/2018
ug/L
INS
*
ND
ND
ND
89.3J
INS
INS
5/7/2020
ug/L
INS
INS
ND
ND
ND
ND
INS
INS
11/11/2020
ug/L
INS
INS
120.00
ND
ND
ND
90.01
INS
Resample>
12/2/2020
ug/L
INS
INS
INS
INS
INS
INS
INS
ND
5/5/2021
ug/L
INS
INS
INS
INS
INS
INS
INS
INS
11/3/2021
ug/L
INS
ND
ND
ND
ND
ND
ND
ND
11/17/2022
ug/L
INS
ND
ND
ND
ND
ND
ND
ND
11/8/2023
ug/L
INS
INS
ND
ND
41.1J
ND
ND
31.1
Methane
11/3/2006
mg/L
INS
INS
INS
2.23
2.50
2.92
NI
NI
6/3/2009
mg/L
0.340
INS
INS
0.111
8.61
8.26
0.494
0.814
11/17/2009
mg/L
2.580
INS
INS
4.310
0.147
10.300
1 1.200
0.271
Resample >
1/19/2010
mg/L
INS
INS
INS
INS
2.120
INS
INS
INS
6/16/2010
mg/L
0.750
INS
INS
4.600
6.000
6.200
1.000
1.100
12/1/2010
mg/L
1.35
NU
INS
3.04
6.0
6.65
INS
INS
6/1/2011
mg/L
2.1
NU
INS
0.157
0.0128
<0.010
0.899
2.64
12/20/2011
mg/L
INS
<0.005
INS
1.460
6.300
5.650
INS
INS
5/30/2012
mg/L
INS
0.0061
INS
0.883
6.130
3.760
0.46
0.718
12/5/2012
mg/L
INS
ND
INS
2.070
2.050
4.910
INS
INS
6/12/2013
mg/L
INS
0.0063
INS
0.964
8.900
11.400
INS
INS
10/28/2013
mg/L
INS
ND
INS
.0033J
2.610
0.173
0.0581
0.0085
5/6/2014
mg/L
INS
ND
INS
2.040
6.190
4.360
0.3850
1.5900
10/23/2014
mg/L
INS
INS
5.93
2.21
ND
5.61
INS
INS
5/21/2015
mg/L
INS
INS
0.0012 J
2.27
6.70
4.94
0.136
3.060
12/8/2015
mg/L
INS
INS
0.0020 J
0.96
0.80
7.51
INS
INS
5/3/2016
mg/L
INS
INS
0.0014 J
1.88
5.35
5.16
0.457
0.514
12/13/2016
mg/L
INS
INS
INS
3.05
8.94
17.30
INS
INS
6/27/2017
mg/L
INS
INS
.00194 D6
3.15
16.60
12.50
INS
INS
12/12/2017
mg/L
INS
INS
ND
3.04
14.80
14.40
0.369
2.260
5/16/2018
ug/L
INS
INS
ND
2.90
17.20
16.40
INS
INS
12/6/2018
ug/L
INS
INS
ND
1,940
15,400
15,000
1,100
1,330
5/7/2020
ug/L
INS
INS
ND
3,000
14,500
11,700
INS
INS
11/11/2020
ug/L
INS
INS
ND
2,290
17,600
17,500
281
INS
Resample >
12/2/2020
ug/L
INS
INS
INS
INS
INS
INS
INS
2,910
5/5/2021
ug/L
INS
INS
I ND
4,800
17,900
16,900
INS
INS
11/3/2021
ug/L
INS
ND
ND
ND
9,230
9,270
1,170
780
11/17/2022
ug/L
INS
ND
ND
6,330
ND
ND
3,190
779
11/8/2023
ug/L
INS
INS
7.5 J
2,820
5,920
3,870
2,690
2,240
Burke Co.- Johns River C+D-over-MSWLF La Bella Associates
Permit No. 12-03 Page 7 of 10 March 2024

TABLE C-5: HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Background
Compliance
Sentinel
Ana lyte/Pa ra meter
Date
Units
MW-17
MW-20
MW-21
MW-11
I MW-12
MW-16S
MW-18
MW-19
Ethane
11/3/2006
mg/L
NS
NS
NS
<0.002
<0.002
<0.002
NI
NI
6/3/2009
mg/L
<0.005
NS
NS
<0.005
<0.005
<0.005
<0.005
<0.005
11/17/2009
mg/L
<0.005
NS
NS
<0.005
<0.005
<0.005
<0.005
<0.005
Resample >
1/19/2010
mg/L
NS
NS
NS
NS
<0.005
NS
NS
NS
6/16/2010
mg/L
<0.013
NS
NS
<0.013
<0.011
<0.011
<0.013
<0.013
12/1/2010
mg/L
<0.0022
NU
NS
<0.0022
<0.0022
<0.0022
NS
NS
6/1/2011
mg/L
NS
NU
NS
NS
NS
NS
NS
NS
12/20/2011
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
5/30/2012
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
12/5/2012
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
6/12/2013
mg/L
NS
ND
NS
ND
ND
ND
NS
NS
10/28/2013
mg/L
NS
ND
NS
.0016J
ND
ND
ND
ND
5/6/2014
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
10/23/2014
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
5/21/2015
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
12/8/2016
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
5/3/2016
mg/L
NS
NS
ND
ND
ND
ND
ND
ND
12/13/2016
mg/L
NS
NS
ND
ND
ND
ND
NS
NS
6/27/2017
mg/L
NS
NS
ND
ND
ND
ND
NS
NS
12/12/2017
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
5/16/2018
ug/L
NS
NS
ND
ND
ND
ND
NS
NS
12/6/2018
ug/L
NS
NS
ND
ND
ND
ND
NS
NS
5/7/2020
ug/L
NS
NS
ND
ND
ND
ND
NS
NS
11/11/2020
ug/L
NS
NS
1.3J
ND
ND
ND
ND
NS
Resample>
12/2/2020
ug/L
NS
NS
NS
NS
NS
NS
NS
ND
5/5/2021
ug/L
NS
NS
ND
21
75.4
72.1
NS
NS
11/3/2021
ug/L
NS
ND
ND
ND
ND
ND
ND
ND
11/17/2022
ug/L
NS
ND
ND
ND
ND
ND
ND
ND
11/8/2023
ug/L
NS
NS
NS
NS
NS
NS
NS
NS
Ethylene (Ethene)
11/3/2006
mg/L
NS
NS
NS
<0.002
1 <0.002
<0.002
NI
NI
6/3/2009
mg/L
<0.005
NS
NS
<0.005
<0.005
<0.005
<0.005
<0.005
11/17/2009
mg/L
<0.005
NS
NS
<0.005
<0.005
<0.005
<0.005
<0.005
Resample >
1/19/2010
mg/L
NS
NS
NS
NS
<0.005
NS
NS
NS
6/16/2010
mg/L
<0.013
NS
NS
<0.013
<0.011
<0.011
1 <0.013
<0.013
12/1/2010
mg/L
<0.0018
NU
NS
<0.0018
<0.0018
<0.0018
NS
NS
6/1/2011
mg/L
NS
NU
NS
NS
NS
NS
NS
NS
12/20/2011
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
5/30/2012
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
12/5/2012
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
6/12/2013
mg/L
NS
ND
NS
ND
ND
ND
NS
NS
10/28/2013
mg/L
NS
ND
NS
.0017 J
ND
ND
ND
ND
5/6/2014
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
10/23/2014
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
5/21/2015
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
12/8/2015
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
5/3/2016
mg/L
NS
NS
ND
ND
ND
ND
ND
ND
12/13/2016
mg/L
NS
NS
ND
ND
ND
ND
NS
NS
6/27/2017
mg/L
NS
NS
ND
ND
ND
ND
NS
NS
12/12/2017
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
5/16/2018
ug/L
NS
NS
ND
ND
ND
0.0113
NS
NS
12/6/2018
ug/L
NS
NS
ND
ND
ND
ND
NS
NS
5/7/2020
ug/L
NS
NS
ND
ND
ND
ND
NS
NS
11/11/2020
ug/L
NS
NS
ND
1.3J
10.5
8.7J
ND
NS
Resample>
12/2/2020
ug/L
NS
NS
NS
NS
NS
NS
NS
ND
5/5/2021
ug/L
NS
NS
ND
3.1 J
7.4 J
9.6 J
NS
NS
11/3/2021
ug/L
NS
ND
ND
ND
ND
ND
ND
ND
11/17/2022
ug/L
NS
ND
ND
ND
ND
ND
ND
ND
11/8/2023
ug/L
NS
NS
NS
NS
NS
NS
NS
NS
Burke Co.- Johns River C+D-over-MSWLF La Bella Associates
Permit No. 12-03 Page 8 of 10 March 2024

TABLE C-5: HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Background
Compliance
Sentinel
Analyte/Parameter
Date
Units
MW-17
MW-20
MW-21
MW-11
MW-12
MW-16S
MW-18
MW-19
Dissolved Hydrogen
11/3/2006
nM
NS
NS
NS
NS
NS
NS
NI
NI
6/3/2009
nM
0.480 J
NS
NS
0.720
<0.600
0.350 J
0.580 J
0.790
11/17/2009
nM
0.780
NS
NS
0.850
0.690
1.000
1.200
0.630
6/16/2010
nM
4.800
NS
NS
3.400
2.800
2.200
2.800
3.300
12/1/2010
nM
1.500
NU
NS
0.850
0.740
0.950
NS
NS
6/1/2011
nM
2.300
NU
NS
2.400
1.900
2.200
2.100
2.000
12/20/2011
nM
NS
21
NS
19
6.3
7.0
NS
NS
5/30/2012
nM
NS
0.74
NS
2.0
1.1
0.84
0.79
0.76
12/5/2012
nM
NS
1.7
NS
0.5 J
0.35 J
0.57 J
NS
NS
6/12/2013
nM
NS
1.1
NS
1.1
0.83
1.60
NS
NS
10/28/2013
nM
NS
0.61
NS
0.61
0.55 J
0.52 J
0.56 J
0.68
5/6/2014
nM
NS
0.61
NS
0.82
1.1 J
1.1 J
0.61
3.50
10/23/2014
nM
NS
NS
0.75
0.86
0.85
1.2
NS
NS
5/21/2015
nM
NS
NS
1.7
1 1.3
1.1
1.6
1.6
1.2
12/8/2016
nM
NS
NS
2.0
1.6
2.3
1.9
NS
NS
5/3/2016
nM
NS
NS
0.97
0.86
0.82
0.77
0.80
0.80
12/13/2016
nM
NS
NS
1.9
2.0
1.5
1.3
NS
NS
6/27/2017
nM
NS
NS
2.0
1.7
2.0
2.0
1 NS
NS
12/12/2017
nM
NS
NS
12
NS
NS
13
12
8.5
5/16/2018
nM
NS
NS
2.2
2.4
2.0
2.7
NS
NS
12/6/2018
nM
NS
NS
NS
NS
NS
5.2
3.8
3.2
Missed Samples >
2/7/2019
nM
NS
NS
16
27
8.8
NS
NS
NS
5/7/2020
nM
NS
NS
NS
NS
NS
NS
NS
NS
12/2/2020
nM
NS
NS
7.7
4.0
77.0
3.3
5.0
5.4
5/5/2021
nM
NS
NS
280 D
4.7
9
6.3
1 NS
NS
11/3/2021
nM
NS
ND
ND
1.4
5
1.5J
0.94J
0.62J
11/17/2022
nM
NS
ND
ND
15.0
2
1.81
ND
2.0
11/8/2023
nM
NS
NS
1.4J
ND
1.4J
5.3
1.6J
3.0
Volatile Fatty Acids
11/3/2006
mg/L
NS
NS
NS
NS
NS
NS
NI
NI
6/3/2009
mg/L
10.9
NS
NS
0.5J
ND
ND
ND
ND
11/17/2009
mg/L
0.9J
NS
NS
ND
0.6J
ND
0.91
ND
6/16/2010
mg/L
ND
NS
NS
32.0
ND
1.3
0.8J
5.2
12/1/2010
mg/L
ND
NU
NS
ND
ND
6.4J
NS
NS
6/1/2011
mg/L
NS
NU
NS
NS
NS
NS
NS
NS
12/20/2011
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
5/30/2012
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
12/5/2012
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
6/12/2013
mg/L
NS
ND
NS
ND
ND
ND
NS
NS
10/28/2013
mg/L
NS
ND
NS
ND
ND
ND
ND
ND
5/6/2014
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
10/23/2014
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
5/21/2015
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
12/8/2015
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
5/3/2016
mg/L
NS
NS
ND
ND
ND
ND
ND
ND
12/13/2016
mg/L
NS
NS
ND
ND
ND
ND
NS
NS
6/27/2017
mg/L
NS
NS
ND
ND
ND
ND
NS
NS
12/12/2017
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
5/16/2018
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
12/6/2018
ug/L
NS
NS
NS
NS
NS
NS
NS
NS
5/7/2020
ug/L
NS
NS
NS
NS
NS
NS
NS
NS
11/11/2020
ug/L
NS
NS
39,700
42,000
43,000
43,000
43,000
36,300
Resample>
12/2/2020
ug/L
NS
NS
NS
NS
NS
NS
NS
ND
5/5/2021
ug/L
NS
NS
5,670
54,500
ND
56,300
NS
NS
11/3/2021
ug/L
NS
ND
ND
ND
ND
ND
ND
ND
11/17/2022
ug/L
NS
ND
13805J
ND
ND
7,860
54,620
55,820
11/8/2023
ug/L
NS
NS
NS
NS
NS
NS
NS
NS
Burke Co.- Johns River C+D-over-MSWLF La Bella Associates
Permit No. 12-03 Page 9 of 10 March 2024

TABLE C-5: HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Background
Compliance
Sentinel
Ana lyte/Pa ra meter
Date
Units
MW-17
MW-20
MW-21
MW-11
MW-12
MW-16S
MW-18
MW-19
TOC
11/3/2006
mg/L
INS
INS
INS
INS
INS
INS
NI
NI
6/3/2009
mg/L
9.4
INS
INS
11.1
10.1
17.8
8.6
14.2
11/17/2009
mg/L
2.1
INS
INS
13.1
12.6
14.6
3.9
11.4
6/16/2010
mg/L
24.9
INS
INS
12.9
8.66
11.1
6.4
16.8
12/1/2010
mg/L
17.6
NU
INS
29.3
23.4
43.8
INS
INS
6/1/2011
mg/L
INS
NU
INS
INS
INS
INS
INS
INS
12/20/2011
mg/L
INS
6.53
INS
13.6
12.2
16.1
INS
INS
5/30/2012
mg/L
INS
6.49
INS
12.5
12.1
14.5
6.55
10.90
12/5/2012
mg/L
INS
ND
INS
13.1
13.1
16.0
INS
INS
6/12/2013
mg/L
INS
ND
INS
13.3
12.9
18.3
INS
INS
10/28/2013
mg/L
INS
ND
INS
15.3
12.9
15.2
7.5
14.7
5/6/2014
mg/L
INS
ND
INS
17.6
12.0
19.9
9.54
11.3
10/23/2014
mg/L
INS
NS
27.0
35.7
66.4
33.2
INS
INS
5/21/2015
mg/L
INS
INS
ND
4.410
4.580
3.880
2.530
8.580
12/8/2016
mg/L
INS
INS
ND
5.320
--
6.070
INS
INS
5/3/2016
mg/L
INS
INS
0.528 J
4.330
2.380
6.080
2.010
3.520
12/13/2016
mg/L
INS
INS
0.70 J
4.0
3.7
3.6
INS
INS
6/27/2017
mg/L
INS
INS
ND
2.98
IV
2.74
INS
INS
12/12/2017
mg/L
INS
INS
INS
3.99
2.89
3.56
1 1.470
3.360
5/16/2018
mg/L
INS
INS
ND
4.28
16.40
7.14
INS
INS
12/6/2018
ug/L
INS
INS
ND
5080
3410
4010
3310
3260
5/7/2020
ug/L
INS
INS
555J
5410
1840
3710
INS
INS
11/11/2020
ug/L
INS
INS
ND
6,000
2,450
3,890
2,100
INS
Resample >
12/2/2020
ug/L
INS
INS
INS
INS
INS
INS
INS
2,710
5/5/2021
ug/L
INS
INS
ND
7,440
1,460
2,570
INS
INS
11/3/2021
ug/L
INS
ND
ND
ND
1 1,390
1 3,010
1 3,910
3,640
11/17/2022
ug/L
INS
ND
ND
7,070
1,330
21110
3,540
3,250
11/8/2023
ug/L
INS
INS
ND
7,800
1,500
1,600
3,000
4,300
Notes:
(FP) = Field Parameter
ND = Not Detected
INS = Not Sampled
my = millivolts
S.U. = standard units
°C = degrees Celcius
mS/cm = microsiemens per centimeter
mg/I = milligrams per liter (parts per million)
pg/I = micrograms per liter (parts per billion)
NU = Not Used as background data until approved
* MW-21 replaced MW-20 as the background well starting with the Fall 2014 sampling event; however MW-20 continues to be sampled as a compliance well
for the C&D Expansion (Phase 1A), and later data from this well can be found the the Water Quality Monitoirng Report for the C&D Expansion.
** MW-20 Replaced MW-17 as the facility background well in 2011.
Burke Co.- Johns River C+D-over-MSWLF La Bella Associates
Permit No. 12-03 Page 10 of 10 March 2024

Appendix D
Biochlor Modeling Input & Output

Biochlor Modeling for Ethenes
BIOCHLOR Natural Attenuation Decision Support System Burke Co.
Version 2.2 Johns River
Excel 2000 Run Name
TYPE OF CHLORINATED SOLVENT: Ethenes
Ethanes
1. ADVECT10N
Seepage Velocity*
or
Hydraulic Conductivity
Hydraulic Gradient
Effective Porosity
.........................................................................................................................
2. DISPERSION
Alpha x*
(Alpha y)1(Alpha x)*
(Alpha z) 1 (Alpha x)*
..........................................................................................................................
3. ADSORPTION
Retardation Factor*
or
Soil Bulk Density, rho
FractionOrganicCarbon, foc
Partition Coefficient
PCE
TCE
DCE
VC
ETH
Common R 0
4. BIOTRANSFORMAT10N
Zone 1
PCE TCE
TCE DCE
DCE VC
VC ETH
Zone 2
PCE TCE
TCE DCE
DCE VC
VC ETH
Vs 114.0
K 1.2E-03
i 0.052
n 0.4
50 (ft) caIc.
0.33 (-) Alpha x
1.E-99 (-)
5. GENERAL
Simulation Time*
C (.Modeled Area Width*
(fUyr) J Modeled Area Length*
Zone 1 Length*
(cm/sec) :Zone 2 Length*
(ftJft}
ro
C
zz
(yr)
- L
1600
(ft)
W Ow
50D
(ft)
1
500
{ft)
0
(ft)
Zone 2-
L - Zone 1
6. SOURCE DATA TYPE: Continuous
Source Options Single Planar
Source Thickness in Sat. Zone* 40 (ft)
Y1
Width* (ft) 1600
R J k*
5
Conc. (mg/L)* C1 (11yr)
1.6 {kglL} PCE 0.0035 0
1.8E-3 (-) TCE 0.0051 0
Koc DCE 0.0159 0
426 (Llkg) 7.13 (-) VC 0.0000 0
130 (Llkg) 2.87 (-) ETH 0.0000 0
125 (L lkg) 2.80 {-)
30 (Ukg) (-) 7. FIELD DATA FOR COMPARISON
302 (Ukg) {-) PCE Cone. (mg/L)
ed in model)* = 11 2.87 TCE Cone. (mg/L)
-1st Order Decay Coefficiene DCE Cone. (mg/L)
k (11yr) half-life (yrs) Yield VC Conc. (mg/L)
2.300 F 0.79 ETH Conc. (mg/L)
2.100 F 0.74 Distance from Source (ft)
Data Input Instructions:
115 -1. Enter value directly.... or
T or x 2. Calculate by filling in gray
r 0.02 cells. Press Enter, then C
(To restore formulas, hit 'Restore Formulas" button }
Variable*- Data used directly in model.
Test if
Biotransformation Natural Attenuation
is Occunrinp -> Screening Protocol
Plane Source: Determine Source Well
,Vertical
Location and Input Solvent Concentrations
View of Plume Looking Down
Observed Centerline Cone. at Monitoring Wells
0.0041
0.0000
0.0000
0.0000
0.0000
0.0000
0.0062
0.0000
0.0021
0.0004
0.0000
0.0000
0.0104
0.0031
0.0095
0.0060
0.0000
0.0000
0.000
U.UU14 U.001 U.0010
0.0006
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0
20
60
135
210
430
1200 O.ti4 Date Data Collected 2023-11
0.000 F 0.45 8. CHOOSE TYPE OF OUTPUT TO SEE:
X (11yr) half-life (yrs)
2.300 F PP]FRU
2.100 F RUN ARRAY
1.200 ERLINE
0.000 F
Restore RESET
Help Formulas
SEE Paste Unprotecl
OUTPUT Example
Burke Co. - Johns River Landfill - Permit # 12-03 La Bella Associates
Page 1 of 18

DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mg1L) at Z=0
PCE
No Degradation
...................................................................................................................
Biotransformation
Field Data from Site
Distance from Source (ft)
0
50
100
150
200
250
300
350
400
450
500
0.003
0.003
0.003
0.003
0.003
0.003
0.003
0.003
0.003
0.003
0.003
0.0035
0.002
0.001
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
—No Degradation/Production
1.0000
0.1000
E
r 0.0100
O
0.0010
c
U 0.0001
c
O
am, iiii
Prepare Animation
Monitoring Well Locations (ft)
—Sequential 1st Order Decay 0 Field Data from Site
Distance From Source (ft.)
Time:
22,0 Years
Log � Linear
See PCE
See TCE
See DCE
See VC
See ETH
Unprotect Return to To All To Array
Sheet Input
Burke Co. - Johns River Landfill - Permit # 12-03 La Bella Associates
Page 2 of 18

Transverse
Distance {
640
320
0
-320
-640
MASS
RATE
(mg/day)
DISSOLVED SOLVENT CONCENTRATIONS IN PLUME
1) Distance from Source (ft)
0
50
100
150
200
250
300
350
400
450
0.0035
0.0035
0.0035
0.0035
0.0034
0.0033
0.0033
0.0032
0.0031
0.0030
0.0035
0.0035
0.0035
0.0035
0.0035
0.0035
0.0035
0.0034
0.0034
0.0033
0.0035
0.0035
0.0035
0.0035
0.0035
0.0035
0.0035
0.0034
0.0034
0.0033
0.0035
0.0035
0.0035
0.0039
0.0035
0.0035
0.0039
0.0034
0.0034
0.0033
0.0035
0.0035
0.0035
0.0035
0.0034
0.0033
0.0033
0.0032
0.0031
0.0030
........
7.9E+2
7.9E+2
7.9E+2
7.9E+2
7.8E+2
........ ........
7.7E+2
7.7E+2
7.6E+2
7.4E+2
7.3E+2
Start Here P PCE
TCE
0 DCE
0 VC
500 0 ETH
0.0029
0.0033 Show No
0.0033 Degradation
0.0033
o.00z9 Show
Biotransformation
7.1 E+2
Displayed Compound
Time: 22 yr Target Level: 0.005 mg/L Displayed Model: No Degradation PCE
0.0035
J .0034
abO.0033
E 0.0032
c
o 0.0031
0.0030
a 0.0020
c0.0028
V 0.0027
0.002(
tl)N 6 0
o
Ln
Distance from Source (ft.)
Chart Area
Plot All Data Plot Data a Target
riume Wass turaer-ot-magnnuae AccuracY)
See Plume Mass If No Degradation 3.7 (Kg)
Gallons
- Plume Mass If Biotransformation/Production 0.6 (Kg)
Mass Removed 3.1 (Kg)
If "Can't Calc.",
make model % Biotransformed =
area longer v
�° Change in Mass Rate = 10.6 /0 5ourcetoed
see Current Volume of Ground Water in Plume 0.00 MGal
acre-R
Flow Rate of Water Through Source Area 0.060 MGD
i
Cam are to Pump and Treat Pumping Rate (gpm)
# Pore Volumes Removed Per Yr. #DIVIO!
# Pore Volumes to Clean -Up
Clean -Up Time (yr)
Mass HELP To Centerline Retum to Input
Burke Co. - Johns River Landfill - Permit # 12-03 La Bella Associates
Page 3 of 18

DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mg]L) at Z=0
TCE
No Degradation
Biotransformation
Distance from Source (ft)
0
50
100
150
200
250
300
350
400
450
500
0.005
0.005
0.005
0.005
0.005
0.005
0.005
0.005
0.005
0.005
0.005
0.0051
0.004
0.002
0.002
0.001
0.001
0.000
0.000
0.000
0.000
0.000
0
Field Data from Site 0.006
20 60
0.000 0.002
�No Degradation/Production
1.0000
0.1000
E
r 0.0100
Q
M" 0.0010
c
U 0.0001
C
Q
V 0.0000
Prepare Animation
Monitoring Well Locations (ft)
135 210 430
0.000 0.000 0.000
—Sequential 1st Order Decay 0 Field Data from Site
Chart Area
Distance From Source (ft.)
Time:
22.0 Years
Log <�=* Linear
)0
See PCE
See TCE
See DCE J
See VC]
See ETH
Unprotect Return to To All To Array
Sheet Input
Burke Co. - Johns River Landfill - Permit # 12-03 La Bella Associates
Page 4 of 18

Transverse
Distance (ft)
0
50
640
0.0051
0.0051
320
0.0051
0.0051
0
0.0051
0.0091
-320
aoo5i
0.0051
-640
0.0051
0.0051
MASS
RA TE
(mg, day)
1.2E+3
1.2E+3
Time: 22 yr
0.0052
Z 0.0050
tM
E 0.0048
p 0.0046
r
0.0044
cu 0.0042
p 0.004C
U
0.003E
DISSOLVED SOLVENT CONCENTRATIONS IN PLUME
Distance from Source (ft)
100
150
200
250
300
0.0051
0.0050
0.0050
0.0049
0.0048
0.0051
0.0051
0.0051
0.0051
0.005o
0.0091
0.0051
0.0051
0.0091
0.0090
0.0051
0.0051
0.0051
0.0051
0.0050
0.0051
0.005o
0.005o
0.0049
0.0048
1.2E+3 1.1E+3 1.1 E+3 1.1 E+3 1.1E+3
Target Level: 0.005 mg/L
0
Q o
Distance from Source (ft.)
Plot All Data Plot Data a Target
E
Start Here o o
PCE
TCE
❑CE
VC
350
400
450
500
ETH
Show No
Degradation
Shaw
Biotransformation
0.0047
0.0045
0.0044
0.0043
0.0050
0.0049
0.0049
0.0048
0.0090
0.0049
0.0049
0.0048
0.0050
0.0049
0.0049
0.0048
0.0047
0.0045
0.0044
0.0043
1.1E+3
1.1 E+3
1.1 E+3
1.0E+3
Displayed Compound
Displayed Model: N❑ Degradation
TCE
rlume Mass turaer-or-magnauae Accuracy)
See Plume Mass If No Degradation 5.4 (Kg)
Gallons
- Plume Mass If Biotransformation/Production 1.3 (Kg)
Mass Removed 4.1 (Kg)
If "Can't Calc_",
make model % Biotransformed =
area longer /° ° 1iIo o source [o ed
Change in Mass Rate = 10.�
see Current Volume of Ground Water in Plume 1 61.28 IMGal
acre-R
Flow Rate of Water Through Source Area 0.060 MGD
I
Compare to Pump and Treat Pumping Rate (gpm)
# Pore Volumes Removed Per Yr. 0.00
# Pore Volumes to Clean -Up
Clean -Up Time (yr)
Mass HELP To Centerline Return to Input
Burke Co. - Johns River Landfill - Permit # 12-03 La Bella Associates
Page 5 of 18

DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mg/L) at Z=0
DCE
No Degradation
Biotransformation
Field Data from Site
Distance from Source (ft)
0
50
100
150
200
250
300
350
400
450
500
0.016
0.016
0.016
0.016
0.016
0.016
0.016
0.016
0.015
0.015
0.015
0.0159
0.012
0.009
0.007
0.005
0.004
0.003
0.002
0.001
0.001
0.001
�No Degradation/Production
1.0000
0.1000
E
r 0.0100
0
T 0.0010
c
U 0.0001
C
Q
Monitoring Well Locations (ft)
-Sequential 1st Order Decay IN Field Data from Site
Distance From Source (ft.)
)a
See PCE
See TCE
See DCE
See VC
See ETH
Time:
22.0 Years Unprotect Return to
Prepare Animation Sheet Input To All To Array
Log `�* Linear
Burke Co. - Johns River Landfill - Permit # 12-03 La Bella Associates
Page 6 of 18

Start Here o PCE
DISSOLVED SOLVENT CONCENTRATIONS IN PLUME TCE
Transverse
Distance (ft) Distance from Source (ft)
L
0
50
100
150
200
250
300
640
0.0159
0.0159
0.0168
0.0157
0.0155
0.0152
0.0149
320
0.0159
0.0159
0.0159
0.0199
0.0198
0.0158
0.0157
0
0.0159
0.0159
0.0199
0.0199
0.0158
0.0158
0.0197
-320
0.0159
0.0159
0.0159
0.0159
0.0158
0.0158
0.0157
-640
OA159
0.0159
0.0188
0.0197
0.0199
0.0152
0.0149
MASS
3.6E+3
3.6E+3
3.6E+3
3.6E+3
3.5E+3
3.5E+3
3.5E+3
(mg/day)] Time: 22 yr Target Level: 0.070 mg1L
0.0160
Zi .0155
C'r0.0150
E 0.0145
r_
o 0.0140
0.0135
C 0.0130
0.0125
V 0.012C
0.011 F
Plot All Data
Cl)o 0
o
Distance from Source (ft.)
Plot Data a Target
lil
+ DCE
0 VC
350
400
450
500
0 ETH
0.0145
0.0142
0.0137
0.0133
Show No
0.0196
0.0154
0.0152
0.0148
Degradation
0.0196
0.0154
0.0152
0.0149
0.0156
0.0154
0.0152
0.0148
0.0145
0.0142
0.0137
0.0133
Show
Biotransformation
3.4E+3
3.4E+3
3.3E+3
3.2E+3
Displayed Compound
Displayed Model:
No Degradation
DCE
Flume Mass (uraer-or-Magnituae Accuracy)
See Plume Mass If No Degradation 16.7 (Kg)
Gallons
- Plume Mass If Biotransformation/Production 5.4 (Kg)
Mass Removed 11.3 (Kg)
If "Can't Calc.",
make model % Biatransformed =
area longer /° ° v source �o edc
Change in Mass Rate = 10.6 /o �
see Current Volume of Ground Water in Plume Can't Calc. MGal
acr�R
Flow Rate of Water Through Source Area 1 0.060 IMGD
Cornare tc Pump and Treat Pumping Rate )
# Pore Volumes Removed Per Yr.
# Pore Volumes to Clean -Up
Clean -Up Time (yr)
Mass HELP To Centerline
Return to Input
Burke Co. - Johns River Landfill - Permit # 12-03 La Bella Associates
Page 7 of 18

DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mg/L) at Z=0
VC
No Degradation
................................................................................................................
Biotransformation
Distance from Source (ft)
0
50
100
150
200
250
300
350
400
450
500
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.0000
0.004
0.007
0.009
0.010
0.011
0.012
0.012
0.013
0.013
0.013
0
Field Data from Site 0.000
20 60
0.001 0.001
�No Degradation/Production
1.000a
0.1000
E
r 0.0100
O
LM 0.0010
U 0.0001
r_
Q
U 0.0000
Prepare Animation
Monitoring Well Locations (ft)
135 210 430
0.001 0.001 0.000
-Sequential 1st Order Decay IN Field Data from Site
Distance From Source (ft.)
Time:
22.0 Years
Log <�=* Linear
See PCE
See TCE
See DCE
See VC
See ETH
Chart Area
Unprotect Return to To All To Array
Sheet Input
Burke Co. - Johns River Landfill - Permit # 12-03 La Bella Associates
Page 8 of 18

Start Here o o PCE
DISSOLVED SOLVENT CONCENTRATIONS IN PLUME 0 TCE
Transverse
Distance (ft) Distance from Source (ft)
0
50
100
150
200
250
300
640
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
320
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
O
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
-320
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
-640
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
MASS
0.0E+0
0.0E+0
0.0E+0
0.0E+0
O.OE+O
0.0E+0
0.0E+0
47•via
(mg/day)] Time: 22 yr Target Level: 0.002 mg/L
1.0000
J .9DDD
W.8000
E o.T000
r- 06000
0.5000
0.4000
y 0.3000
C 02000
V 0.1000
0.000(
Plot All Data
Distance from Source (ft.)
Plot Data > Target
-
n o
un
11
0 ❑CE
VC
350
400
450
500
C) E'TH
0.0000
0.0000
0.0000
0.0000
Show No
0.0000
0.0000
0.0000
0.0000
Degradation
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Show
0.0000
0.0000
0.0000
0.0000
Biotransformation
O.OE+O
O.OE+O
O.OE+0
O.OE+O
Displayed Compound
Displayed Model:
No Degradation
VC
mume mass (uroer-ot-magmtuoe Accuracy)
See Plume Mass If No Degradation 0.0 (Kg)
Gallons
- Plume Mass If Biotransformation/Production 10.4 (Kg)
Mass Removed -10.4 (Kg)
If "Can't Calc.",
make model % Biotransformed =0
area longer n
�o Change In Mass Rate = source toeu e
see Current Volume of Ground Water in Plume 0.00 MGal
acr�R
Flow Rate of Water Through Source Areal 0.060 MGD
Corn are to Pump and Treat Pumping Rate (g
# Pore Volumes Removed Per Yr. #DIV10!
# Pore Volumes to Clean -Up
Clean -Up Time (yr)
Mass HELP To Centerline
Return to Input
Burke Co. - Johns River Landfill - Permit # 12-03 La Bella Associates
Page 9 of 18

DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mg/L) at I=0
ETH
No Degradation
Biotransformation
Distance from Source (ft)
0 Eff
120 60
Field Data from Site 0.000 0.000 0.000
�No Degradation/Production
1.0000 T
0.1000
E
r 0.0100
O
7-
T 0.0010
+r
0.0001
0
Prepare Animation
Monitoring Well Locations (ft)
135 210 430
0.000 0.000 0.000
-5equential 1st Order Decay 0 Field Data from Site
100 200 300 400 500
500
Distance From Source (ft.)
Time:
22.0 Years
Log � Linear
.11
See PCE
See TCE
See DCE
See VC
See ETH
Unprotect Return to To All To Array
Sheet Input
Burke Co. - Johns River Landfill - Permit # 12-03 La Bella Associates
Page 10 of 18

Transverse
Distance (ft)
0
50
640
a0000
0.0000
320
a0000
0.0000
0
0.0000
0.0000
-320
a0000
0.0000
-64011
0.0000
0.0000
MASS
RATE
(mglday) j
0.0E+0
0.0E+0
Time: yr
1.0000
-0 9000
W.0000
E 0.7000
C 0.6000
0.5000
0.4000
y 0.3000
C 02000
V 0.1000
0.000c
DISSOLVED SOLVENT CONCENTRATIONS IN PLUME
Distance from Source (ft)
100
150
200
250
300
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0E+0 0.0E+0 0.0E+0 0.0E+0 0.0E+0
Target Level: Omg/L
0 0
o
Ln
Distance from Source (ft.)
Plot All Data Plot Data a Target
-640
00001
ft.
Start Here P
PCE
TCE
❑CE
0
VC
350
400
450
500i
ETH
0.0000
0.0000
0.0000
0.0000
Show No�
0.0000
0.0000
0.0000
0.0000
Degradation
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Show
0.0000
0.0000
0.0000
0.0000
Biotransformation
0.0E+0
0.0E+0
0.0E+0
0.0E+0
Displayed Compound
Displayed Model:
jNo Degradation
ETH
mume nnass turaer-or-lviagnnuae Accuracy)
See Plume Mass If No Degradation 0.0 (Kg)
Gallons
- Plume Mass If Biotransformation/Production 0.0 (Kg)
Mass Removed 0.0 (Kg)
If "Can't Calc.",
make model % Biotransformed =
area longer % Change in Mass Rate =
see Current Volume of Ground Water in Plume 0.00 MGa!
acre-R
Flow Rate of Water Through Source Area 0.060 1 MGD
Compare to Pump and Treat Pumping Rate (gpm)
# Pore Volumes Removed Per Yr. #DIV10!
# Pore Volumes to Clean -Up
Clean -Up Time (yr)
Mass HELP To Centerline Return to Input
Burke Co. - Johns River Landfill - Permit # 12-03 La Bella Associates
Page 11 of 18

Biochlor Modeling for Ethanes
610CHLCR Natural Attenuation Decision Support System Burke co.
version 2.2 Johns River
Excel 2000 Run Name
TYPE OF CHLORINATED SOLVENT:
1_ ADVECTION
Seepage Velocity*
or
Hydraulic Conductivity
Hydraulic Gradient
Effective Porosity
...........................................................
2. DISPERSION
Alpha x*
(Alpha y) / (Alpha x)*
(Alpha z) / (Alpha x)*
......................................................................................................
3. ADSORPTION
Retardation Factor*
or
Soil Bulk Density, rho
FractionOrganicCarbon, foc
Partition Coefficient
TCA
DCA
CA
Vs
K
i
n
Ethenes
Ethanes
114.0
t
12E-03-03
01 052
0.4
50 (ft} CslC.
Alpha x
0.33 (-)
1.E 999 (-}
R
1.6 (kg/L)
1.BE-3 (-)
Koc -A
;- 5. GENERAL
Simulation Time*
Modeled Area Width*
{tttyr} Modeled Area Length*
Zone 1 Length*
(cmisec) ;Zone 2 Length*
(f lft)
M
(Llkg) 7.13 (-)
(Ukg) 2.87 (-}{Llkg} 2.80 0
Common R (used in model)* =1 " 2.87
4. BIOTRANSFORMATION
-1st Order Decay Coefficient'
Zone 1
�
I (1/yr)
half-life (yrs) Yield
XA
TGA DGA
DCA CA
2.300
2.100
<-
F
0.14
065
CA Ethane
1200.
0.47
0.00
C
(yr)
L
(ft)
W
F
(ft)(fl)
0
(ft)
Zane 2=
...................................................�...
_Zane 1
_ ...........................
Data Input Instructions:
115 - 1. Enter value directly ---- or
T of 2. Calculate by filling in gray
0.02 cells. Press Enter, then C
(To restcre formulas, hit "Restore Formulas" button)
Variable*- Data used directly in model
Test if
Biotransformation Natural Attenuation
is Occurring Screening Protocol
6. SOURCE DATA TYPE: Continuous
Vertical Plane Source Determine Source Well
Source Options Single Planar
Location and Input Solvent Concentrations
Source Thickness in Sat. Zone* 40
(ft}
Y1
C Width* (ft) F 1600
k$*
Con . (mg/L)* G1
(1/yr)
TCA 0.0000
0
DGA 0.0103
0
View of Plume Looking Down
GA 0.0000
0
0
Observed Gentedine Cone. at Monitoring Wells
0
.....................................................................................................
7. FIELD DATA FOR COMPARISON
TGA Conc. (mg/L)
DCA Con _ (mg/L)
C jCA Conc. (mg/L)
Zone 2
TCA
DGA
1 (1/yr)
2.300
half-life (yrs)
DGA
CA
2.100
<-
HELP
a
CA 3
Ethane
1200.
F
0.0000 0.0000 10.0000 1 0.0000 I 0.0000 I 0.0000
0.0110 0.0020 0.0192 0.0129 0.0000 0.0005
0.0000 0.0010 0.0057 0.0045 0.0000 0.0000
Distance from Source (ft) 1 Q 1 20 60 135 210 430
Date Data Collected 2023-11
............................................................................................
8. CHOOSE TYPE OF OUTPUT TO SEE:
Her Restore RESET
CENTERLINE RUN ARRAY p
SEE Paste Unprotect
DUTPUT
Burke Co. - Johns River Landfill - Permit # 12-03 La Bella Associates
Page 12 of 18

DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mglL) at Z=0
TCA
No Degradation
Biotransformation
Distance from Source (ft)
« 1 ««
«III
1 111
« 1 I I
«III
1 111
1 1 I I
« 11 I
« 111
1 1 «1
« 1 ««
1 111
1 111
1 111
1 111
I I11
1 111
1 111
i 111
1 111
1 lil
i 111
0 20 60
Field Data from Site 1 0.000 0.000 0.000
—No Degradation/Production
1.0000 1
0.1000
E
= 0.0100
O
L 0.0010
.r
c
u 0.0001
_
0
100
Monitoring Well Locations (ft)
135 210 430
0.000 0.000 0.000
—Sequential 1 st Order Decay o Field Data from Site
200 300 400 500
Distance From Source (ft.)
.«I
See TCA
See DCA
See CA J
Time:
Years
Prepare Animation 22.0 U protect Return to To All To Array
Log � Linear Input
Burke Co. - Johns River Landfill - Permit # 12-03 La Bella Associates
Page 13 of 18

Transverse
Distance (ft)
0
50
640
o.0000
0.0000
320
o.0000
0.0000
0
0.0000
0.0000
-320
o.0000
0.0000
-640
o.0000
0.0000
MASS
RAT
{mglday)
0.0E+0
0.0E+0
Time: 22 yr
1.00
0.90
J
6, Ono
E 0.70
e D.6D
w
0.50
0.40
y 0.30
0.20
V 0.10
0.oc
Start Here P TCA
DISSOLVED SOLVENT CONCENTRATIONS IN PLUME DCA
0 CA
Distance from Source (ft)
100
150
200
250
300
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0E+0 0.0E+0 0.0E+0 0.0E+0 0.0E+0
Target Level: 0.200 mg/L
o
Distance from Source (ft.)
Plot All Data Plot Data a Target
-640
00001
ft.
350
400
450
500
0.0000
0.0000
0.0000
0.0000
Show No
0.0000
0.0000
0.0000
0.0000
Degradation
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Show
0.0000
0.0000
0.0000
0.0000
Biotransformation
0.0E+0
0.0E+0
0.0E+0
0.0E+0
Displayed Compound
Displayed Model:
Biotransformation
TCA
mume mass turaer-ot-magnituae Accuracy)
See Plume Mass If No Degradation 0.0 (Kg)
Gallons
- Plume Mass If Biotransformation/Production 0.0 (Kg)
Mass Removed 0.0 (Kg)
If "Can't Calc.",
make model % Biotransformed =�
area longer n
/o Change in Mass Rate = source �o
see Current Volume of Ground Water in Plume o.00 MGal
acre-R
Flow Rate of Water Through Source Areal 0.060 MGD
Compare tc Pump and Treat Pumping Rate {
# Pore Volumes Removed Per Yr. #DIV/O!
# Pore Volumes to Clean -Up
Clean -Up Time (yr)
i
Mass HELP To Centerline Return to Input
J
Burke Co. - Johns River Landfill - Permit # 12-03 La Bella Associates
Page 14 of 18

DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mg/L) at Z=0
Distance from Source (ft)
DCA
No Degradation
..................
Biotransformation
Field Data from Site
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
MITI I
1 44.
111
1 11
1 Ii
III
1 111
"we 1
1 Ili
4 111
"we 1
—No Degradation/Production
1.0000 T
0.1000
CD
E o
c 0.0100
0
0.0010
100
v 0.0001
c
0
Prepare Animation
Monitoring Well Locations (ft)
—Sequential 1st Order Decay o Field Data from Site
200
400 °
Distance From Source (ft.)
Time:
22.0 Years
Log <�=* Linear
Unprotect
Sheet
See TCA
See DCA
See CA
500 600
Return to To All To Array
Input
Burke Co. - Johns River Landfill - Permit # 12-03 La Bella Associates
Page 15 of 18

Transverse
Distance (ft)
0
50
640
0.0103
0.0097
320
0.0103
0.0097
0
0.0103
0.0097
-320
0.0103
0.0097
-640
0.0103
0.0057
MASS
RATE
(mg/day)
2.3E+3
1.3E+3
Time: 22 y
0.01
J 001
0.01
0.01
0.00
U
= 0.00
O
U
0.0c
DISSOLVED SOLVENT CONCENTRATIONS IN PLUME
Distance from Source (ft)
100
150
200
250
300
0.0032
0.0018
0.0010
0.0009
0.0003
0.0032
0.0018
0.0010
0.0006
0.0003
0.0032
0.0018
0.0010
0.0006
0.0003
0.0032
0.0018
0.0010
0.0006
0.0003
0.0032
0.0018
0.0010
0.0009
0.0003
7.3E+2 4.0E+2 2.2E+2 1.2E+2 6.9E+1
r Target Level: mg/L
--
r� a
Ln
Distance from Source (ft.)
Plot All Data Plot Data a Target
-640
00001
ft.
Start Here
TCA
❑CA
CA
350
400
450
500
Show No
Degradation
0.0002
0.0001
0.0000
0.0000
0.0002
0.0001
0.0001
0.0000
0.0002
0.0001
0.0001
0.0000
0.0002
0.0001
0.0001
0.0000
Show
Biotransformation
i
0.0002
0.0001
0.0000
0.0000
3.8E+1 .....
............
2.1E+1
1.2E+1
6.6E+0
Displayed Compound
Displayed Model: Biotransformation
DCA
mume mass (uraer-ot-magnitude Accuracy)
See Plume Mass If No Degradation 10.8 (Kg)
Gallons
- Plume Mass If Biotransformation/Production 1.9 (Kg)
Mass Removed 9.0 (Kg)
If "Can't Calc.",
make model % Biotransformed =
area longer o
�'° Change in Mass Rate = 99.7 Io [sourcet°edge]
see Current Volume of Ground Water in Plume 19.15 MGaf
acre-R
Flow Rate of Water Through Source Area 0.060 MGD
Compare to Pump and Treat Pumping Rate (gp
# Pore Volumes Removed Per Yr. 0.00
# Pore Volumes to Clean -Up
Clean -Up Time (yr)
Mass HELP To Centerline Return to Input
Burke Co. - Johns River Landfill - Permit # 12-03 La Bella Associates
Page 16 of 18

DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mg/L) at Z=0
CA
No Degradation
.........
Biotransformation
Distance from Source (ft)
MITI are M
, ,,
, ,,
, we more
,,
, „
, „
, r r
r „
, ,,,
, ,,,
0 20 60
Field Data from Site 0.000 0.001 0.006
—No Degradation/Production
1.0000 T
0.1000
E
a 0.010o
O
0.0010
c
v 0.0001
c
O
r+ , ,,,,,
Prepare Animation
Monitoring Well Locations (ft)
135 210 430
0.005 0.000 0.000
—Sequential 1st order Decay o Field Data from Site
0
100
200
300
Distance From Source (ft.)
Time:
22.0 Years
Log <�=* Linear
See TCA
See DCA
See CA
M
Unprotect Return to To All To Array
Sheet Input
Burke Co. - Johns River Landfill - Permit # 12-03 La Bella Associates
Page 17 of 18

Start Here i TCA
DISSOLVED SOLVENT CONCENTRATIONS IN PLUME DCA
Transverse CA
0
50
640
0.0000
0.0019
320
o.0000
0.0019
0
0.0000
0.0019
-320
o.0000
0.0019
-640
o.0000
0.0019
ISS
.............................
1.4E-4
.....................................
4.4E+2
TE
Iday}
Time: 22 yr
0.00
J
0.00
E
Jnit►_lll■F.ir
Distance from Source (ft)
100
150
200
250
300
0.0024
0.0022
0.0018
0.0014
0.0011
0.0024
0.0023
0.0019
0.0016
0.0011
0.0024
0.0023
0.0019
0.0015
0.0011
0.0024
0.0023
0.0019
0.0015
0.0011
0.0024
0.0022
0.0018
0.0014
0.0011
5.5E+2 5.1 E+2 4.2E+2 3.3E+2 2.5E+2
Target Level: Omg/L
0
t7 V 7 CD
n
Distance from Source (ft.)
Plot Data a Target
-640
0000i
ft.
350
400
450
500
Shoal NO
Degradation
0.0008
0.0005
0.0004
0.0003
0.0008
0.0006
0.0004
0.0003
0.0008
0.0006
0.0004
0.0003
0.0008
0.0006
0.0004
0.0003
Show
Biotransformation,
0.0008
0.0005
0.0004
0.0003
1.8E+2
1.3E+2
9.2E+1
6.5E+1
Displayed Compound
Displayed Model: Biotransformation
CA
Flume Mass {urcier-of-Magn tucie Accuracy)
$ee Plume Mass If No Degradation 0.0 (Kg)
Gallons
- Plume Mass If Biotransformation/Production 1.4 (Kg)
Mass Removed -1.4 (Kg)
If "Can't Calc_",
make model % Biotransformed =
area longer % Change in Mass Rate =
see Current Volume of Ground Water in Plume 0.00 MGal
acre-R
Flow Rate of Water Through Source Areal 0.060 MGD
Compare to Pump and Treat]Pumping Rate (gpm)
# Pore Volumes Removed Per Yr. #DIV/O!
# Pore Volumes to Clean -Up
Clean -Up Time (yr)
Mass HELP To Centerline
Return to Input
Burke Co. - Johns River Landfill - Permit # 12-03 La Bella Associates
Page 18 of 18