7702_RichmondCoLF_February2024GWMR_FID1831109_20240229

NELAP Certification Number: CA00046
DoD-ELAP Certification Number: 4064.01
State Certification Number:
908 N. Temperance Ave., Clovis, CA 93611 - Phone [phone] - www.metirigroup.com
February 27, 2024
Waypoint Analytical
Greenville, NC 27858
114 Oakmont Drive
Ann Baynor
Enclosed are the results of analyses for samples received by our laboratory on 2/15/2024. If you
have any questions concerning this report, please feel free to contact me.
I certify that this data package is in compliance with the terms and conditions of the contract, both
technically and for completeness, for other than the conditions detailed above. These test results
meet all requirements of NELAC and DoD QSM. Release of the hard copy has been authorized by
the Laboratory Manager or designee, as verified by the following signature.
RE: 6026 Richmond County Solid Waste
24B0105
[TOC_1]Cover
Letter[TOC]
Sincerely,
Chue Moua
Project Manager
[e-mail]
559-862-2155
Page 1 of 31
Table of Contents
Table of Contents
Cover Letter 1
Samples in Report 3
Case Narratives Analyses 3
Sample Results 4
Quality Assurance Results 21
Qualifiers and Definitions 26
Login Summary 27
Chain of Custody 29
Other Documents or Sub Lab Data 31
Page 2 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
[TOC_1]Samples in
Report[TOC]Work Order Case Narrative

The COC listed WELL #5 & WELL #7 and the sample containers listed MW 5 and MW 7 with the same
collection date and time. Ok, to use the COC sample IDs.
The COC listed sample WELL #3. We only received sample WELL #2 with the sample collection date and
time. Ok, to proceed with WELL #2.
Analysis Case Narrative

EPA 1633: Manual integrations were performed for this method in accordance with APPLs SOP. Abbreviated flags for technical
justification are provided as data qualifiers.
The extracted internal standard 13C8-PFOSA recovered below the lower control limit in sample 01 UPSTREAM.
[TOC_1]Case Narratives -
Analyses[TOC]
Samples in this Report
Sample Lab ID Matrix Date Sampled Date Received
UPSTREAM Water24B0105-01 02/15/202402/07/2024 12:40
DOWNSTREAM Water24B0105-02 02/15/202402/07/2024 11:05
WELL#2 Water24B0105-03 02/15/202402/07/2024 10:25
WELL#4 Water24B0105-04 02/15/202402/07/2024 11:46
WELL#5 Water24B0105-05 02/15/202402/07/2024 12:14
WELL#7 Water24B0105-06 02/15/202402/07/2024 12:45
WELL#8 Water24B0105-07 02/15/202402/07/2024 10:59
WELL#9 Water24B0105-08 02/15/202402/07/2024 09:48
Page 3 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 3 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Sample Results

Sample:
24B0105-01 (Water)
UPSTREAM
Analyte Result PQL
Date
Analyzed Method/Qual Units DFMDL
Prep
Batch
Per- and Polyfluoroalkyl Substances
PFBA ND 1.4 EPA 163302/23/240.19 BDB03021ng/L
PFPeA ND 0.72 EPA 163302/23/240.058 BDB03021ng/L
PFHxA ND 0.36 EPA 163302/23/240.049 BDB03021ng/L
PFHpA ND 0.36 EPA 163302/23/240.037 BDB03021ng/L
PFOA 0.15 0.36 EPA 163302/23/240.14 BDB0302J1ng/L
PFNA ND 0.36 EPA 163302/23/240.073 BDB03021ng/L
PFDA ND 0.36 EPA 163302/23/240.091 BDB03021ng/L
PFUnA ND 0.36 EPA 163302/23/240.14 BDB03021ng/L
PFDoA ND 0.36 EPA 163302/23/240.10 BDB03021ng/L
PFTrDA ND 0.36 EPA 163302/23/240.18 BDB03021ng/L
PFTeDA ND 0.36 EPA 163302/23/240.18 BDB03021ng/L
PFBS 0.21 0.36 EPA 163302/23/240.033 BDB0302J1ng/L
PFPeS ND 0.36 EPA 163302/23/240.056 BDB03021ng/L
PFHxS 0.22 0.36 EPA 163302/23/240.028 BDB0302J1ng/L
PFHpS ND 0.36 EPA 163302/23/240.046 BDB03021ng/L
PFOS 1.7 0.36 EPA 163302/23/240.057 BDB0302MI41ng/L
PFNS ND 0.36 EPA 163302/23/240.11 BDB03021ng/L
PFDS ND 0.36 EPA 163302/23/240.14 BDB03021ng/L
PFDoS ND 0.36 EPA 163302/23/240.11 BDB03021ng/L
4:2FTS ND 1.4 EPA 163302/23/240.26 BDB03021ng/L
6:2FTS ND 1.4 EPA 163302/23/240.28 BDB03021ng/L
8:2FTS ND 1.4 EPA 163302/23/240.074 BDB03021ng/L
PFOSA ND 0.36 EPA 163302/23/240.093 BDB03021ng/L
NMeFOSA ND 1.4 EPA 163302/23/240.42 BDB03021ng/L
NEtFOSA ND 1.4 EPA 163302/23/240.37 BDB03021ng/L
NMeFOSAA ND 0.36 EPA 163302/23/240.095 BDB03021ng/L
NEtFOSAA ND 0.36 EPA 163302/23/240.10 BDB03021ng/L
NMeFOSE ND 1.4 EPA 163302/23/240.91 BDB03021ng/L
NEtFOSE ND 1.4 EPA 163302/23/240.94 BDB03021ng/L
HFPO-DA ND 0.72 EPA 163302/23/240.16 BDB03021ng/L
ADONA ND 0.72 EPA 163302/23/240.11 BDB03021ng/L
PFEESA ND 0.72 EPA 163302/23/240.098 BDB03021ng/L
PFMPA ND 0.72 EPA 163302/23/240.048 BDB03021ng/L
PFMBA ND 0.72 EPA 163302/23/240.081 BDB03021ng/L
NFDHA ND 0.72 EPA 163302/23/240.27 BDB03021ng/L
9Cl-PF3ONS ND 0.72 EPA 163302/23/240.19 BDB03021ng/L
11Cl-PF3OUDS ND 0.72 EPA 163302/23/240.18 BDB03021ng/L
3:3FTCA ND 1.4 EPA 163302/23/240.52 BDB03021ng/L
5:3FTCA ND 1.4 EPA 163302/23/240.40 BDB03021ng/L
7:3FTCA ND 1.4 EPA 163302/23/240.50 BDB03021ng/L
Surrogate: 13C4-PFBA 94.0%5-130 EPA 163302/23/24 1
Surrogate: 13C5-PFPEA 101%40-130 EPA 163302/23/24 1
Surrogate: 13C5-PFHXA 93.4%40-130 EPA 163302/23/24 1
Surrogate: 13C4-PFHPA 96.4%40-130 EPA 163302/23/24 1
Surrogate: 13C8-PFOA 99.2%40-130 EPA 163302/23/24 1
[TOC_1]Sample Results[TOC]
Page 4 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 4 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Sample Results
(Continued)
Sample:
24B0105-01 (Water)
UPSTREAM (Continued)
Analyte Result PQL
Date
Analyzed Method/Qual Units DFMDL
Prep
Batch
Per- and Polyfluoroalkyl Substances (Continued)
Surrogate: 13C9-PFNA 99.4%40-130 EPA 163302/23/24 1
Surrogate: 13C6-PFDA 96.5%40-130 EPA 163302/23/24 1
Surrogate: 13C7-PFUnA 77.1%30-130 EPA 163302/23/24 1
Surrogate: 13C2-PFDOA 64.8%10-130 EPA 163302/23/24 1
Surrogate: 13C2-PFTEDA 47.0%10-130 EPA 163302/23/24 1
Surrogate: 13C3-PFBS 101%40-135 EPA 163302/23/24 1
Surrogate: 13C3-PFHXS 105%40-130 EPA 163302/23/24 1
Surrogate: 13C8-PFOS 96.9%40-130 EPA 163302/23/24 1
Surrogate: 13C2-4:2FTS 86.9%40-200 EPA 163302/23/24 1
Surrogate: 13C2-6:2FTS 70.2%40-200 EPA 163302/23/24 1
Surrogate: 13C2-8:2FTS 73.4%40-300 EPA 163302/23/24 1
Surrogate: 13C8-PFOSA 39.0%40-130 EPA 163302/23/24S1 1
Surrogate: D3-NMEFOSA 20.3%10-130 EPA 163302/23/24 1
Surrogate: D5-NETFOSA 19.8%10-130 EPA 163302/23/24 1
Surrogate: D3-NMEFOSAA 67.9%40-170 EPA 163302/23/24 1
Surrogate: D5-NETFOSAA 53.1%25-135 EPA 163302/23/24 1
Surrogate: D7-NMEFOSE 30.6%10-130 EPA 163302/23/24 1
Surrogate: D9-NETFOSE 27.3%10-130 EPA 163302/23/24 1
Surrogate: 13C3-HFPO-DA 108%40-130 EPA 163302/23/24 1
Page 5 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 5 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Sample Results
(Continued)
Sample:
24B0105-02 (Water)
DOWNSTREAM
Analyte Result PQL
Date
Analyzed Method/Qual Units DFMDL
Prep
Batch
Per- and Polyfluoroalkyl Substances
PFBA ND 1.5 EPA 163302/23/240.19 BDB03021ng/L
PFPeA ND 0.73 EPA 163302/23/240.059 BDB03021ng/L
PFHxA ND 0.36 EPA 163302/23/240.050 BDB03021ng/L
PFHpA ND 0.36 EPA 163302/23/240.037 BDB03021ng/L
PFOA 0.14 0.36 EPA 163302/23/240.14 BDB0302J1ng/L
PFNA ND 0.36 EPA 163302/23/240.075 BDB03021ng/L
PFDA ND 0.36 EPA 163302/23/240.092 BDB03021ng/L
PFUnA ND 0.36 EPA 163302/23/240.15 BDB03021ng/L
PFDoA ND 0.36 EPA 163302/23/240.10 BDB03021ng/L
PFTrDA ND 0.36 EPA 163302/23/240.19 BDB03021ng/L
PFTeDA ND 0.36 EPA 163302/23/240.18 BDB03021ng/L
PFBS ND 0.36 EPA 163302/23/240.033 BDB03021ng/L
PFPeS ND 0.36 EPA 163302/23/240.057 BDB03021ng/L
PFHxS 0.071 0.36 EPA 163302/23/240.029 BDB0302J1ng/L
PFHpS ND 0.36 EPA 163302/23/240.047 BDB03021ng/L
PFOS 0.50 0.36 EPA 163302/23/240.058 BDB0302MI41ng/L
PFNS ND 0.36 EPA 163302/23/240.11 BDB03021ng/L
PFDS ND 0.36 EPA 163302/23/240.14 BDB03021ng/L
PFDoS ND 0.36 EPA 163302/23/240.11 BDB03021ng/L
4:2FTS ND 1.5 EPA 163302/23/240.26 BDB03021ng/L
6:2FTS ND 1.5 EPA 163302/23/240.29 BDB03021ng/L
8:2FTS ND 1.5 EPA 163302/23/240.075 BDB03021ng/L
PFOSA 0.14 0.36 EPA 163302/23/240.095 BDB0302J1ng/L
NMeFOSA ND 1.5 EPA 163302/23/240.43 BDB03021ng/L
NEtFOSA ND 1.5 EPA 163302/23/240.38 BDB03021ng/L
NMeFOSAA ND 0.36 EPA 163302/23/240.096 BDB03021ng/L
NEtFOSAA ND 0.36 EPA 163302/23/240.10 BDB03021ng/L
NMeFOSE ND 1.5 EPA 163302/23/240.92 BDB03021ng/L
NEtFOSE ND 1.5 EPA 163302/23/240.95 BDB03021ng/L
HFPO-DA ND 0.73 EPA 163302/23/240.16 BDB03021ng/L
ADONA ND 0.73 EPA 163302/23/240.11 BDB03021ng/L
PFEESA ND 0.73 EPA 163302/23/240.099 BDB03021ng/L
PFMPA ND 0.73 EPA 163302/23/240.049 BDB03021ng/L
PFMBA ND 0.73 EPA 163302/23/240.083 BDB03021ng/L
NFDHA ND 0.73 EPA 163302/23/240.27 BDB03021ng/L
9Cl-PF3ONS ND 0.73 EPA 163302/23/240.19 BDB03021ng/L
11Cl-PF3OUDS ND 0.73 EPA 163302/23/240.19 BDB03021ng/L
3:3FTCA ND 1.5 EPA 163302/23/240.52 BDB03021ng/L
5:3FTCA ND 1.5 EPA 163302/23/240.40 BDB03021ng/L
7:3FTCA ND 1.5 EPA 163302/23/240.50 BDB03021ng/L
Surrogate: 13C4-PFBA 87.9%5-130 EPA 163302/23/24 1
Surrogate: 13C5-PFPEA 104%40-130 EPA 163302/23/24 1
Surrogate: 13C5-PFHXA 98.9%40-130 EPA 163302/23/24 1
Surrogate: 13C4-PFHPA 98.2%40-130 EPA 163302/23/24 1
Surrogate: 13C8-PFOA 107%40-130 EPA 163302/23/24 1
Page 6 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 6 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Sample Results
(Continued)
Sample:
24B0105-02 (Water)
DOWNSTREAM (Continued)
Analyte Result PQL
Date
Analyzed Method/Qual Units DFMDL
Prep
Batch
Per- and Polyfluoroalkyl Substances (Continued)
Surrogate: 13C9-PFNA 102%40-130 EPA 163302/23/24 1
Surrogate: 13C6-PFDA 105%40-130 EPA 163302/23/24 1
Surrogate: 13C7-PFUnA 87.6%30-130 EPA 163302/23/24 1
Surrogate: 13C2-PFDOA 78.6%10-130 EPA 163302/23/24 1
Surrogate: 13C2-PFTEDA 50.1%10-130 EPA 163302/23/24 1
Surrogate: 13C3-PFBS 108%40-135 EPA 163302/23/24 1
Surrogate: 13C3-PFHXS 108%40-130 EPA 163302/23/24 1
Surrogate: 13C8-PFOS 101%40-130 EPA 163302/23/24 1
Surrogate: 13C2-4:2FTS 92.0%40-200 EPA 163302/23/24 1
Surrogate: 13C2-6:2FTS 79.1%40-200 EPA 163302/23/24 1
Surrogate: 13C2-8:2FTS 79.7%40-300 EPA 163302/23/24 1
Surrogate: 13C8-PFOSA 53.3%40-130 EPA 163302/23/24 1
Surrogate: D3-NMEFOSA 27.1%10-130 EPA 163302/23/24 1
Surrogate: D5-NETFOSA 24.7%10-130 EPA 163302/23/24 1
Surrogate: D3-NMEFOSAA 75.8%40-170 EPA 163302/23/24 1
Surrogate: D5-NETFOSAA 60.5%25-135 EPA 163302/23/24 1
Surrogate: D7-NMEFOSE 36.9%10-130 EPA 163302/23/24 1
Surrogate: D9-NETFOSE 32.2%10-130 EPA 163302/23/24 1
Surrogate: 13C3-HFPO-DA 111%40-130 EPA 163302/23/24 1
Page 7 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 7 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Sample Results
(Continued)
Sample:
24B0105-03 (Water)
WELL#2
Analyte Result PQL
Date
Analyzed Method/Qual Units DFMDL
Prep
Batch
Per- and Polyfluoroalkyl Substances
PFBA 9.3 1.4 EPA 163302/23/240.18 BDB03021ng/L
PFPeA 0.76 0.71 EPA 163302/23/240.058 BDB03021ng/L
PFHxA 1.2 0.35 EPA 163302/23/240.049 BDB03021ng/L
PFHpA 1.3 0.35 EPA 163302/23/240.036 BDB03021ng/L
PFOA 4.7 0.35 EPA 163302/23/240.14 BDB03021ng/L
PFNA ND 0.35 EPA 163302/23/240.073 BDB03021ng/L
PFDA ND 0.35 EPA 163302/23/240.090 BDB03021ng/L
PFUnA ND 0.35 EPA 163302/23/240.14 BDB03021ng/L
PFDoA ND 0.35 EPA 163302/23/240.099 BDB03021ng/L
PFTrDA ND 0.35 EPA 163302/23/240.18 BDB03021ng/L
PFTeDA ND 0.35 EPA 163302/23/240.18 BDB03021ng/L
PFBS 2.4 0.35 EPA 163302/23/240.033 BDB03021ng/L
PFPeS 0.70 0.35 EPA 163302/23/240.056 BDB03021ng/L
PFHxS 1.7 0.35 EPA 163302/23/240.028 BDB0302MI41ng/L
PFHpS ND 0.35 EPA 163302/23/240.046 BDB03021ng/L
PFOS 1.1 0.35 EPA 163302/23/240.056 BDB0302MI41ng/L
PFNS ND 0.35 EPA 163302/23/240.11 BDB03021ng/L
PFDS ND 0.35 EPA 163302/23/240.13 BDB03021ng/L
PFDoS ND 0.35 EPA 163302/23/240.11 BDB03021ng/L
4:2FTS ND 1.4 EPA 163302/23/240.26 BDB03021ng/L
6:2FTS ND 1.4 EPA 163302/23/240.28 BDB03021ng/L
8:2FTS ND 1.4 EPA 163302/23/240.073 BDB03021ng/L
PFOSA 0.11 0.35 EPA 163302/23/240.092 BDB0302J1ng/L
NMeFOSA ND 1.4 EPA 163302/23/240.42 BDB03021ng/L
NEtFOSA ND 1.4 EPA 163302/23/240.37 BDB03021ng/L
NMeFOSAA ND 0.35 EPA 163302/23/240.094 BDB03021ng/L
NEtFOSAA ND 0.35 EPA 163302/23/240.10 BDB03021ng/L
NMeFOSE ND 1.4 EPA 163302/23/240.90 BDB03021ng/L
NEtFOSE ND 1.4 EPA 163302/23/240.93 BDB03021ng/L
HFPO-DA ND 0.71 EPA 163302/23/240.15 BDB03021ng/L
ADONA ND 0.71 EPA 163302/23/240.11 BDB03021ng/L
PFEESA ND 0.71 EPA 163302/23/240.097 BDB03021ng/L
PFMPA ND 0.71 EPA 163302/23/240.048 BDB03021ng/L
PFMBA ND 0.71 EPA 163302/23/240.080 BDB03021ng/L
NFDHA ND 0.71 EPA 163302/23/240.27 BDB03021ng/L
9Cl-PF3ONS ND 0.71 EPA 163302/23/240.19 BDB03021ng/L
11Cl-PF3OUDS ND 0.71 EPA 163302/23/240.18 BDB03021ng/L
3:3FTCA ND 1.4 EPA 163302/23/240.51 BDB03021ng/L
5:3FTCA ND 1.4 EPA 163302/23/240.39 BDB03021ng/L
7:3FTCA ND 1.4 EPA 163302/23/240.49 BDB03021ng/L
Surrogate: 13C4-PFBA 73.3%5-130 EPA 163302/23/24 1
Surrogate: 13C5-PFPEA 103%40-130 EPA 163302/23/24 1
Surrogate: 13C5-PFHXA 97.9%40-130 EPA 163302/23/24 1
Surrogate: 13C4-PFHPA 100%40-130 EPA 163302/23/24 1
Surrogate: 13C8-PFOA 104%40-130 EPA 163302/23/24 1
Page 8 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 8 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Sample Results
(Continued)
Sample:
24B0105-03 (Water)
WELL#2 (Continued)
Analyte Result PQL
Date
Analyzed Method/Qual Units DFMDL
Prep
Batch
Per- and Polyfluoroalkyl Substances (Continued)
Surrogate: 13C9-PFNA 94.4%40-130 EPA 163302/23/24 1
Surrogate: 13C6-PFDA 87.1%40-130 EPA 163302/23/24 1
Surrogate: 13C7-PFUnA 79.0%30-130 EPA 163302/23/24 1
Surrogate: 13C2-PFDOA 71.7%10-130 EPA 163302/23/24 1
Surrogate: 13C2-PFTEDA 67.9%10-130 EPA 163302/23/24 1
Surrogate: 13C3-PFBS 110%40-135 EPA 163302/23/24 1
Surrogate: 13C3-PFHXS 111%40-130 EPA 163302/23/24 1
Surrogate: 13C8-PFOS 91.6%40-130 EPA 163302/23/24 1
Surrogate: 13C2-4:2FTS 102%40-200 EPA 163302/23/24 1
Surrogate: 13C2-6:2FTS 79.0%40-200 EPA 163302/23/24 1
Surrogate: 13C2-8:2FTS 76.5%40-300 EPA 163302/23/24 1
Surrogate: 13C8-PFOSA 59.7%40-130 EPA 163302/23/24 1
Surrogate: D3-NMEFOSA 34.0%10-130 EPA 163302/23/24 1
Surrogate: D5-NETFOSA 35.2%10-130 EPA 163302/23/24 1
Surrogate: D3-NMEFOSAA 77.0%40-170 EPA 163302/23/24 1
Surrogate: D5-NETFOSAA 67.4%25-135 EPA 163302/23/24 1
Surrogate: D7-NMEFOSE 54.7%10-130 EPA 163302/23/24 1
Surrogate: D9-NETFOSE 55.8%10-130 EPA 163302/23/24 1
Surrogate: 13C3-HFPO-DA 110%40-130 EPA 163302/23/24 1
Page 9 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 9 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Sample Results
(Continued)
Sample:
24B0105-04 (Water)
WELL#4
Analyte Result PQL
Date
Analyzed Method/Qual Units DFMDL
Prep
Batch
Per- and Polyfluoroalkyl Substances
PFBA 11 1.5 EPA 163302/23/240.19 BDB03021ng/L
PFPeA ND 0.73 EPA 163302/23/240.059 BDB03021ng/L
PFHxA 0.55 0.36 EPA 163302/23/240.050 BDB03021ng/L
PFHpA 0.52 0.36 EPA 163302/23/240.037 BDB03021ng/L
PFOA 19 0.36 EPA 163302/23/240.14 BDB0302MI41ng/L
PFNA 4.2 0.36 EPA 163302/23/240.075 BDB03021ng/L
PFDA 0.60 0.36 EPA 163302/23/240.092 BDB03021ng/L
PFUnA ND 0.36 EPA 163302/23/240.15 BDB03021ng/L
PFDoA ND 0.36 EPA 163302/23/240.10 BDB03021ng/L
PFTrDA ND 0.36 EPA 163302/23/240.19 BDB03021ng/L
PFTeDA ND 0.36 EPA 163302/23/240.18 BDB03021ng/L
PFBS 19 0.36 EPA 163302/23/240.033 BDB03021ng/L
PFPeS 6.4 0.36 EPA 163302/23/240.057 BDB03021ng/L
PFHxS 28 0.36 EPA 163302/23/240.029 BDB03021ng/L
PFHpS 1.9 0.36 EPA 163302/23/240.047 BDB03021ng/L
PFOS 99 0.36 EPA 163302/23/240.058 BDB03021ng/L
PFNS ND 0.36 EPA 163302/23/240.11 BDB03021ng/L
PFDS ND 0.36 EPA 163302/23/240.14 BDB03021ng/L
PFDoS ND 0.36 EPA 163302/23/240.11 BDB03021ng/L
4:2FTS ND 1.5 EPA 163302/23/240.26 BDB03021ng/L
6:2FTS ND 1.5 EPA 163302/23/240.29 BDB03021ng/L
8:2FTS ND 1.5 EPA 163302/23/240.075 BDB03021ng/L
PFOSA 0.10 0.36 EPA 163302/23/240.095 BDB0302J1ng/L
NMeFOSA ND 1.5 EPA 163302/23/240.43 BDB03021ng/L
NEtFOSA ND 1.5 EPA 163302/23/240.38 BDB03021ng/L
NMeFOSAA ND 0.36 EPA 163302/23/240.096 BDB03021ng/L
NEtFOSAA ND 0.36 EPA 163302/23/240.10 BDB03021ng/L
NMeFOSE ND 1.5 EPA 163302/23/240.92 BDB03021ng/L
NEtFOSE ND 1.5 EPA 163302/23/240.95 BDB03021ng/L
HFPO-DA ND 0.73 EPA 163302/23/240.16 BDB03021ng/L
ADONA ND 0.73 EPA 163302/23/240.11 BDB03021ng/L
PFEESA ND 0.73 EPA 163302/23/240.099 BDB03021ng/L
PFMPA ND 0.73 EPA 163302/23/240.049 BDB03021ng/L
PFMBA ND 0.73 EPA 163302/23/240.083 BDB03021ng/L
NFDHA ND 0.73 EPA 163302/23/240.27 BDB03021ng/L
9Cl-PF3ONS ND 0.73 EPA 163302/23/240.19 BDB03021ng/L
11Cl-PF3OUDS ND 0.73 EPA 163302/23/240.19 BDB03021ng/L
3:3FTCA ND 1.5 EPA 163302/23/240.52 BDB03021ng/L
5:3FTCA ND 1.5 EPA 163302/23/240.40 BDB03021ng/L
7:3FTCA ND 1.5 EPA 163302/23/240.50 BDB03021ng/L
Surrogate: 13C4-PFBA 36.4%5-130 EPA 163302/23/24 1
Surrogate: 13C5-PFPEA 68.6%40-130 EPA 163302/23/24 1
Surrogate: 13C5-PFHXA 91.7%40-130 EPA 163302/23/24 1
Surrogate: 13C4-PFHPA 99.7%40-130 EPA 163302/23/24 1
Surrogate: 13C8-PFOA 105%40-130 EPA 163302/23/24 1
Page 10 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 10 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Sample Results
(Continued)
Sample:
24B0105-04 (Water)
WELL#4 (Continued)
Analyte Result PQL
Date
Analyzed Method/Qual Units DFMDL
Prep
Batch
Per- and Polyfluoroalkyl Substances (Continued)
Surrogate: 13C9-PFNA 93.7%40-130 EPA 163302/23/24 1
Surrogate: 13C6-PFDA 94.5%40-130 EPA 163302/23/24 1
Surrogate: 13C7-PFUnA 85.2%30-130 EPA 163302/23/24 1
Surrogate: 13C2-PFDOA 82.1%10-130 EPA 163302/23/24 1
Surrogate: 13C2-PFTEDA 67.0%10-130 EPA 163302/23/24 1
Surrogate: 13C3-PFBS 103%40-135 EPA 163302/23/24 1
Surrogate: 13C3-PFHXS 103%40-130 EPA 163302/23/24 1
Surrogate: 13C8-PFOS 92.2%40-130 EPA 163302/23/24 1
Surrogate: 13C2-4:2FTS 91.0%40-200 EPA 163302/23/24 1
Surrogate: 13C2-6:2FTS 80.1%40-200 EPA 163302/23/24 1
Surrogate: 13C2-8:2FTS 72.2%40-300 EPA 163302/23/24 1
Surrogate: 13C8-PFOSA 81.4%40-130 EPA 163302/23/24 1
Surrogate: D3-NMEFOSA 42.1%10-130 EPA 163302/23/24 1
Surrogate: D5-NETFOSA 41.2%10-130 EPA 163302/23/24 1
Surrogate: D3-NMEFOSAA 73.6%40-170 EPA 163302/23/24 1
Surrogate: D5-NETFOSAA 69.2%25-135 EPA 163302/23/24 1
Surrogate: D7-NMEFOSE 61.5%10-130 EPA 163302/23/24 1
Surrogate: D9-NETFOSE 58.4%10-130 EPA 163302/23/24 1
Surrogate: 13C3-HFPO-DA 101%40-130 EPA 163302/23/24 1
Page 11 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 11 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Sample Results
(Continued)
Sample:
24B0105-05 (Water)
WELL#5
Analyte Result PQL
Date
Analyzed Method/Qual Units DFMDL
Prep
Batch
Per- and Polyfluoroalkyl Substances
PFBA ND 1.4 EPA 163302/23/240.18 BDB03021ng/L
PFPeA ND 0.70 EPA 163302/23/240.057 BDB03021ng/L
PFHxA ND 0.35 EPA 163302/23/240.048 BDB03021ng/L
PFHpA ND 0.35 EPA 163302/23/240.036 BDB03021ng/L
PFOA ND 0.35 EPA 163302/23/240.13 BDB03021ng/L
PFNA ND 0.35 EPA 163302/23/240.071 BDB03021ng/L
PFDA ND 0.35 EPA 163302/23/240.088 BDB03021ng/L
PFUnA ND 0.35 EPA 163302/23/240.14 BDB03021ng/L
PFDoA ND 0.35 EPA 163302/23/240.097 BDB03021ng/L
PFTrDA ND 0.35 EPA 163302/23/240.18 BDB03021ng/L
PFTeDA ND 0.35 EPA 163302/23/240.17 BDB03021ng/L
PFBS 0.82 0.35 EPA 163302/23/240.032 BDB03021ng/L
PFPeS 0.41 0.35 EPA 163302/23/240.055 BDB03021ng/L
PFHxS 1.6 0.35 EPA 163302/23/240.028 BDB0302MI41ng/L
PFHpS ND 0.35 EPA 163302/23/240.045 BDB03021ng/L
PFOS 0.66 0.35 EPA 163302/23/240.055 BDB0302MI41ng/L
PFNS ND 0.35 EPA 163302/23/240.11 BDB03021ng/L
PFDS ND 0.35 EPA 163302/23/240.13 BDB03021ng/L
PFDoS ND 0.35 EPA 163302/23/240.11 BDB03021ng/L
4:2FTS ND 1.4 EPA 163302/23/240.25 BDB03021ng/L
6:2FTS ND 1.4 EPA 163302/23/240.27 BDB03021ng/L
8:2FTS ND 1.4 EPA 163302/23/240.072 BDB03021ng/L
PFOSA 0.13 0.35 EPA 163302/23/240.091 BDB0302J1ng/L
NMeFOSA ND 1.4 EPA 163302/23/240.41 BDB03021ng/L
NEtFOSA ND 1.4 EPA 163302/23/240.36 BDB03021ng/L
NMeFOSAA ND 0.35 EPA 163302/23/240.092 BDB03021ng/L
NEtFOSAA ND 0.35 EPA 163302/23/240.10 BDB03021ng/L
NMeFOSE ND 1.4 EPA 163302/23/240.88 BDB03021ng/L
NEtFOSE ND 1.4 EPA 163302/23/240.91 BDB03021ng/L
HFPO-DA ND 0.70 EPA 163302/23/240.15 BDB03021ng/L
ADONA ND 0.70 EPA 163302/23/240.11 BDB03021ng/L
PFEESA ND 0.70 EPA 163302/23/240.095 BDB03021ng/L
PFMPA ND 0.70 EPA 163302/23/240.047 BDB03021ng/L
PFMBA ND 0.70 EPA 163302/23/240.079 BDB03021ng/L
NFDHA ND 0.70 EPA 163302/23/240.26 BDB03021ng/L
9Cl-PF3ONS ND 0.70 EPA 163302/23/240.18 BDB03021ng/L
11Cl-PF3OUDS ND 0.70 EPA 163302/23/240.18 BDB03021ng/L
3:3FTCA ND 1.4 EPA 163302/23/240.50 BDB03021ng/L
5:3FTCA ND 1.4 EPA 163302/23/240.39 BDB03021ng/L
7:3FTCA ND 1.4 EPA 163302/23/240.48 BDB03021ng/L
Surrogate: 13C4-PFBA 92.8%5-130 EPA 163302/23/24 1
Surrogate: 13C5-PFPEA 107%40-130 EPA 163302/23/24 1
Surrogate: 13C5-PFHXA 94.5%40-130 EPA 163302/23/24 1
Surrogate: 13C4-PFHPA 95.5%40-130 EPA 163302/23/24 1
Surrogate: 13C8-PFOA 100%40-130 EPA 163302/23/24 1
Page 12 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 12 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Sample Results
(Continued)
Sample:
24B0105-05 (Water)
WELL#5 (Continued)
Analyte Result PQL
Date
Analyzed Method/Qual Units DFMDL
Prep
Batch
Per- and Polyfluoroalkyl Substances (Continued)
Surrogate: 13C9-PFNA 100%40-130 EPA 163302/23/24 1
Surrogate: 13C6-PFDA 100%40-130 EPA 163302/23/24 1
Surrogate: 13C7-PFUnA 91.2%30-130 EPA 163302/23/24 1
Surrogate: 13C2-PFDOA 89.7%10-130 EPA 163302/23/24 1
Surrogate: 13C2-PFTEDA 86.2%10-130 EPA 163302/23/24 1
Surrogate: 13C3-PFBS 109%40-135 EPA 163302/23/24 1
Surrogate: 13C3-PFHXS 106%40-130 EPA 163302/23/24 1
Surrogate: 13C8-PFOS 102%40-130 EPA 163302/23/24 1
Surrogate: 13C2-4:2FTS 97.0%40-200 EPA 163302/23/24 1
Surrogate: 13C2-6:2FTS 75.3%40-200 EPA 163302/23/24 1
Surrogate: 13C2-8:2FTS 76.1%40-300 EPA 163302/23/24 1
Surrogate: 13C8-PFOSA 61.3%40-130 EPA 163302/23/24 1
Surrogate: D3-NMEFOSA 24.4%10-130 EPA 163302/23/24 1
Surrogate: D5-NETFOSA 23.5%10-130 EPA 163302/23/24 1
Surrogate: D3-NMEFOSAA 81.1%40-170 EPA 163302/23/24 1
Surrogate: D5-NETFOSAA 68.7%25-135 EPA 163302/23/24 1
Surrogate: D7-NMEFOSE 58.4%10-130 EPA 163302/23/24 1
Surrogate: D9-NETFOSE 65.0%10-130 EPA 163302/23/24 1
Surrogate: 13C3-HFPO-DA 113%40-130 EPA 163302/23/24 1
Page 13 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 13 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Sample Results
(Continued)
Sample:
24B0105-06 (Water)
WELL#7
Analyte Result PQL
Date
Analyzed Method/Qual Units DFMDL
Prep
Batch
Per- and Polyfluoroalkyl Substances
PFBA 0.36 1.5 EPA 163302/23/240.19 BDB0302MI3, J 1ng/L
PFPeA 0.29 0.74 EPA 163302/23/240.060 BDB0302J1ng/L
PFHxA 0.50 0.37 EPA 163302/23/240.051 BDB03021ng/L
PFHpA 0.78 0.37 EPA 163302/23/240.038 BDB03021ng/L
PFOA 3.5 0.37 EPA 163302/23/240.14 BDB0302MI41ng/L
PFNA ND 0.37 EPA 163302/23/240.076 BDB03021ng/L
PFDA ND 0.37 EPA 163302/23/240.094 BDB03021ng/L
PFUnA ND 0.37 EPA 163302/23/240.15 BDB03021ng/L
PFDoA ND 0.37 EPA 163302/23/240.10 BDB03021ng/L
PFTrDA ND 0.37 EPA 163302/23/240.19 BDB03021ng/L
PFTeDA ND 0.37 EPA 163302/23/240.18 BDB03021ng/L
PFBS 0.23 0.37 EPA 163302/23/240.034 BDB0302MI6, J 1ng/L
PFPeS 0.21 0.37 EPA 163302/23/240.058 BDB0302J1ng/L
PFHxS 0.58 0.37 EPA 163302/23/240.029 BDB0302MI41ng/L
PFHpS ND 0.37 EPA 163302/23/240.048 BDB03021ng/L
PFOS 1.4 0.37 EPA 163302/23/240.059 BDB03021ng/L
PFNS ND 0.37 EPA 163302/23/240.11 BDB03021ng/L
PFDS ND 0.37 EPA 163302/23/240.14 BDB03021ng/L
PFDoS ND 0.37 EPA 163302/23/240.11 BDB03021ng/L
4:2FTS ND 1.5 EPA 163302/23/240.27 BDB03021ng/L
6:2FTS ND 1.5 EPA 163302/23/240.29 BDB03021ng/L
8:2FTS ND 1.5 EPA 163302/23/240.076 BDB03021ng/L
PFOSA 0.20 0.37 EPA 163302/23/240.097 BDB0302MI4, J 1ng/L
NMeFOSA ND 1.5 EPA 163302/23/240.44 BDB03021ng/L
NEtFOSA ND 1.5 EPA 163302/23/240.38 BDB03021ng/L
NMeFOSAA ND 0.37 EPA 163302/23/240.098 BDB03021ng/L
NEtFOSAA ND 0.37 EPA 163302/23/240.11 BDB03021ng/L
NMeFOSE ND 1.5 EPA 163302/23/240.94 BDB03021ng/L
NEtFOSE ND 1.5 EPA 163302/23/240.97 BDB03021ng/L
HFPO-DA ND 0.74 EPA 163302/23/240.16 BDB03021ng/L
ADONA ND 0.74 EPA 163302/23/240.11 BDB03021ng/L
PFEESA ND 0.74 EPA 163302/23/240.10 BDB03021ng/L
PFMPA ND 0.74 EPA 163302/23/240.050 BDB03021ng/L
PFMBA ND 0.74 EPA 163302/23/240.084 BDB03021ng/L
NFDHA ND 0.74 EPA 163302/23/240.28 BDB03021ng/L
9Cl-PF3ONS ND 0.74 EPA 163302/23/240.19 BDB03021ng/L
11Cl-PF3OUDS ND 0.74 EPA 163302/23/240.19 BDB03021ng/L
3:3FTCA ND 1.5 EPA 163302/23/240.53 BDB03021ng/L
5:3FTCA ND 1.5 EPA 163302/23/240.41 BDB03021ng/L
7:3FTCA ND 1.5 EPA 163302/23/240.51 BDB03021ng/L
Surrogate: 13C4-PFBA 89.7%5-130 EPA 163302/23/24 1
Surrogate: 13C5-PFPEA 105%40-130 EPA 163302/23/24 1
Surrogate: 13C5-PFHXA 94.8%40-130 EPA 163302/23/24 1
Surrogate: 13C4-PFHPA 98.9%40-130 EPA 163302/23/24 1
Surrogate: 13C8-PFOA 109%40-130 EPA 163302/23/24 1
Page 14 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 14 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Sample Results
(Continued)
Sample:
24B0105-06 (Water)
WELL#7 (Continued)
Analyte Result PQL
Date
Analyzed Method/Qual Units DFMDL
Prep
Batch
Per- and Polyfluoroalkyl Substances (Continued)
Surrogate: 13C9-PFNA 97.8%40-130 EPA 163302/23/24 1
Surrogate: 13C6-PFDA 95.0%40-130 EPA 163302/23/24 1
Surrogate: 13C7-PFUnA 74.9%30-130 EPA 163302/23/24 1
Surrogate: 13C2-PFDOA 68.4%10-130 EPA 163302/23/24 1
Surrogate: 13C2-PFTEDA 58.3%10-130 EPA 163302/23/24 1
Surrogate: 13C3-PFBS 107%40-135 EPA 163302/23/24 1
Surrogate: 13C3-PFHXS 110%40-130 EPA 163302/23/24 1
Surrogate: 13C8-PFOS 93.4%40-130 EPA 163302/23/24 1
Surrogate: 13C2-4:2FTS 118%40-200 EPA 163302/23/24 1
Surrogate: 13C2-6:2FTS 76.2%40-200 EPA 163302/23/24 1
Surrogate: 13C2-8:2FTS 70.1%40-300 EPA 163302/23/24 1
Surrogate: 13C8-PFOSA 55.5%40-130 EPA 163302/23/24 1
Surrogate: D3-NMEFOSA 23.8%10-130 EPA 163302/23/24 1
Surrogate: D5-NETFOSA 24.3%10-130 EPA 163302/23/24 1
Surrogate: D3-NMEFOSAA 73.4%40-170 EPA 163302/23/24 1
Surrogate: D5-NETFOSAA 56.1%25-135 EPA 163302/23/24 1
Surrogate: D7-NMEFOSE 39.6%10-130 EPA 163302/23/24 1
Surrogate: D9-NETFOSE 40.1%10-130 EPA 163302/23/24 1
Surrogate: 13C3-HFPO-DA 114%40-130 EPA 163302/23/24 1
Page 15 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 15 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Sample Results
(Continued)
Sample:
24B0105-07 (Water)
WELL#8
Analyte Result PQL
Date
Analyzed Method/Qual Units DFMDL
Prep
Batch
Per- and Polyfluoroalkyl Substances
PFBA 9.7 1.4 EPA 163302/23/240.18 BDB0302MI61ng/L
PFPeA 8.8 0.70 EPA 163302/23/240.057 BDB03021ng/L
PFHxA 9.8 0.35 EPA 163302/23/240.048 BDB03021ng/L
PFHpA 4.7 0.35 EPA 163302/23/240.036 BDB03021ng/L
PFOA 17 0.35 EPA 163302/23/240.13 BDB0302MI41ng/L
PFNA 1.2 0.35 EPA 163302/23/240.071 BDB03021ng/L
PFDA 0.44 0.35 EPA 163302/23/240.088 BDB03021ng/L
PFUnA ND 0.35 EPA 163302/23/240.14 BDB0302IR2, 1ng/L
PFDoA ND 0.35 EPA 163302/23/240.098 BDB03021ng/L
PFTrDA ND 0.35 EPA 163302/23/240.18 BDB03021ng/L
PFTeDA ND 0.35 EPA 163302/23/240.17 BDB03021ng/L
PFBS 3.7 0.35 EPA 163302/23/240.032 BDB03021ng/L
PFPeS 0.50 0.35 EPA 163302/23/240.055 BDB03021ng/L
PFHxS 1.0 0.35 EPA 163302/23/240.028 BDB0302MI41ng/L
PFHpS 0.17 0.35 EPA 163302/23/240.045 BDB0302J1ng/L
PFOS 12 0.35 EPA 163302/23/240.055 BDB03021ng/L
PFNS ND 0.35 EPA 163302/23/240.11 BDB03021ng/L
PFDS ND 0.35 EPA 163302/23/240.13 BDB03021ng/L
PFDoS ND 0.35 EPA 163302/23/240.11 BDB03021ng/L
4:2FTS ND 1.4 EPA 163302/23/240.25 BDB03021ng/L
6:2FTS ND 1.4 EPA 163302/23/240.27 BDB03021ng/L
8:2FTS ND 1.4 EPA 163302/23/240.072 BDB03021ng/L
PFOSA 0.18 0.35 EPA 163302/23/240.091 BDB0302MI4, J 1ng/L
NMeFOSA ND 1.4 EPA 163302/23/240.41 BDB03021ng/L
NEtFOSA ND 1.4 EPA 163302/23/240.36 BDB03021ng/L
NMeFOSAA ND 0.35 EPA 163302/23/240.092 BDB03021ng/L
NEtFOSAA ND 0.35 EPA 163302/23/240.10 BDB03021ng/L
NMeFOSE ND 1.4 EPA 163302/23/240.88 BDB03021ng/L
NEtFOSE ND 1.4 EPA 163302/23/240.91 BDB03021ng/L
HFPO-DA ND 0.70 EPA 163302/23/240.15 BDB0302IR1, 1ng/L
ADONA ND 0.70 EPA 163302/23/240.11 BDB03021ng/L
PFEESA ND 0.70 EPA 163302/23/240.095 BDB03021ng/L
PFMPA ND 0.70 EPA 163302/23/240.047 BDB03021ng/L
PFMBA ND 0.70 EPA 163302/23/240.079 BDB03021ng/L
NFDHA ND 0.70 EPA 163302/23/240.26 BDB03021ng/L
9Cl-PF3ONS ND 0.70 EPA 163302/23/240.18 BDB03021ng/L
11Cl-PF3OUDS ND 0.70 EPA 163302/23/240.18 BDB03021ng/L
3:3FTCA ND 1.4 EPA 163302/23/240.50 BDB03021ng/L
5:3FTCA ND 1.4 EPA 163302/23/240.39 BDB03021ng/L
7:3FTCA ND 1.4 EPA 163302/23/240.48 BDB03021ng/L
Surrogate: 13C4-PFBA 40.9%5-130 EPA 163302/23/24 1
Surrogate: 13C5-PFPEA 58.7%40-130 EPA 163302/23/24 1
Surrogate: 13C5-PFHXA 77.0%40-130 EPA 163302/23/24 1
Surrogate: 13C4-PFHPA 86.4%40-130 EPA 163302/23/24 1
Surrogate: 13C8-PFOA 84.4%40-130 EPA 163302/23/24 1
Page 16 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 16 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Sample Results
(Continued)
Sample:
24B0105-07 (Water)
WELL#8 (Continued)
Analyte Result PQL
Date
Analyzed Method/Qual Units DFMDL
Prep
Batch
Per- and Polyfluoroalkyl Substances (Continued)
Surrogate: 13C9-PFNA 77.5%40-130 EPA 163302/23/24 1
Surrogate: 13C6-PFDA 68.4%40-130 EPA 163302/23/24 1
Surrogate: 13C7-PFUnA 61.5%30-130 EPA 163302/23/24 1
Surrogate: 13C2-PFDOA 52.6%10-130 EPA 163302/23/24 1
Surrogate: 13C2-PFTEDA 26.8%10-130 EPA 163302/23/24 1
Surrogate: 13C3-PFBS 91.6%40-135 EPA 163302/23/24 1
Surrogate: 13C3-PFHXS 89.6%40-130 EPA 163302/23/24 1
Surrogate: 13C8-PFOS 76.2%40-130 EPA 163302/23/24 1
Surrogate: 13C2-4:2FTS 79.3%40-200 EPA 163302/23/24 1
Surrogate: 13C2-6:2FTS 86.2%40-200 EPA 163302/23/24 1
Surrogate: 13C2-8:2FTS 65.7%40-300 EPA 163302/23/24 1
Surrogate: 13C8-PFOSA 50.8%40-130 EPA 163302/23/24 1
Surrogate: D3-NMEFOSA 24.3%10-130 EPA 163302/23/24 1
Surrogate: D5-NETFOSA 21.8%10-130 EPA 163302/23/24 1
Surrogate: D3-NMEFOSAA 51.3%40-170 EPA 163302/23/24 1
Surrogate: D5-NETFOSAA 51.2%25-135 EPA 163302/23/24 1
Surrogate: D7-NMEFOSE 43.8%10-130 EPA 163302/23/24 1
Surrogate: D9-NETFOSE 38.8%10-130 EPA 163302/23/24 1
Surrogate: 13C3-HFPO-DA 84.4%40-130 EPA 163302/23/24 1
Page 17 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 17 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Sample Results
(Continued)
Sample:
24B0105-08 (Water)
WELL#9
Analyte Result PQL
Date
Analyzed Method/Qual Units DFMDL
Prep
Batch
Per- and Polyfluoroalkyl Substances
PFBA 6.5 1.5 EPA 163302/23/240.19 BDB03021ng/L
PFPeA 11 0.74 EPA 163302/23/240.060 BDB03021ng/L
PFHxA 14 0.37 EPA 163302/23/240.051 BDB03021ng/L
PFHpA 3.3 0.37 EPA 163302/23/240.038 BDB03021ng/L
PFOA 14 0.37 EPA 163302/23/240.14 BDB03021ng/L
PFNA 0.49 0.37 EPA 163302/23/240.076 BDB03021ng/L
PFDA 0.22 0.37 EPA 163302/23/240.094 BDB0302J1ng/L
PFUnA ND 0.37 EPA 163302/23/240.15 BDB03021ng/L
PFDoA ND 0.37 EPA 163302/23/240.10 BDB03021ng/L
PFTrDA ND 0.37 EPA 163302/23/240.19 BDB03021ng/L
PFTeDA ND 0.37 EPA 163302/23/240.18 BDB03021ng/L
PFBS 1.4 0.37 EPA 163302/23/240.034 BDB03021ng/L
PFPeS 0.82 0.37 EPA 163302/23/240.058 BDB03021ng/L
PFHxS 3.9 0.37 EPA 163302/23/240.029 BDB03021ng/L
PFHpS 0.25 0.37 EPA 163302/23/240.048 BDB0302J1ng/L
PFOS 9.8 0.37 EPA 163302/23/240.059 BDB03021ng/L
PFNS ND 0.37 EPA 163302/23/240.11 BDB03021ng/L
PFDS ND 0.37 EPA 163302/23/240.14 BDB03021ng/L
PFDoS ND 0.37 EPA 163302/23/240.11 BDB03021ng/L
4:2FTS ND 1.5 EPA 163302/23/240.27 BDB03021ng/L
6:2FTS 0.34 1.5 EPA 163302/23/240.29 BDB0302J1ng/L
8:2FTS 0.46 1.5 EPA 163302/23/240.076 BDB0302J1ng/L
PFOSA 0.13 0.37 EPA 163302/23/240.097 BDB0302MI4, J 1ng/L
NMeFOSA ND 1.5 EPA 163302/23/240.44 BDB03021ng/L
NEtFOSA ND 1.5 EPA 163302/23/240.38 BDB03021ng/L
NMeFOSAA 0.41 0.37 EPA 163302/23/240.098 BDB0302MI41ng/L
NEtFOSAA 0.25 0.37 EPA 163302/23/240.11 BDB0302J1ng/L
NMeFOSE ND 1.5 EPA 163302/23/240.94 BDB03021ng/L
NEtFOSE ND 1.5 EPA 163302/23/240.97 BDB03021ng/L
HFPO-DA 0.52 0.74 EPA 163302/23/240.16 BDB0302J1ng/L
ADONA ND 0.74 EPA 163302/23/240.11 BDB03021ng/L
PFEESA ND 0.74 EPA 163302/23/240.10 BDB03021ng/L
PFMPA ND 0.74 EPA 163302/23/240.050 BDB03021ng/L
PFMBA ND 0.74 EPA 163302/23/240.084 BDB03021ng/L
NFDHA ND 0.74 EPA 163302/23/240.28 BDB03021ng/L
9Cl-PF3ONS ND 0.74 EPA 163302/23/240.19 BDB03021ng/L
11Cl-PF3OUDS ND 0.74 EPA 163302/23/240.19 BDB03021ng/L
3:3FTCA ND 1.5 EPA 163302/23/240.53 BDB03021ng/L
5:3FTCA ND 1.5 EPA 163302/23/240.41 BDB03021ng/L
7:3FTCA ND 1.5 EPA 163302/23/240.51 BDB03021ng/L
Surrogate: 13C4-PFBA 82.4%5-130 EPA 163302/23/24 1
Surrogate: 13C5-PFPEA 88.8%40-130 EPA 163302/23/24 1
Surrogate: 13C5-PFHXA 85.1%40-130 EPA 163302/23/24 1
Surrogate: 13C4-PFHPA 93.3%40-130 EPA 163302/23/24 1
Surrogate: 13C8-PFOA 99.3%40-130 EPA 163302/23/24 1
Page 18 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 18 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Sample Results
(Continued)
Sample:
24B0105-08 (Water)
WELL#9 (Continued)
Analyte Result PQL
Date
Analyzed Method/Qual Units DFMDL
Prep
Batch
Per- and Polyfluoroalkyl Substances (Continued)
Surrogate: 13C9-PFNA 88.2%40-130 EPA 163302/23/24 1
Surrogate: 13C6-PFDA 75.5%40-130 EPA 163302/23/24 1
Surrogate: 13C7-PFUnA 62.1%30-130 EPA 163302/23/24 1
Surrogate: 13C2-PFDOA 58.4%10-130 EPA 163302/23/24 1
Surrogate: 13C2-PFTEDA 55.6%10-130 EPA 163302/23/24 1
Surrogate: 13C3-PFBS 104%40-135 EPA 163302/23/24 1
Surrogate: 13C3-PFHXS 104%40-130 EPA 163302/23/24 1
Surrogate: 13C8-PFOS 76.8%40-130 EPA 163302/23/24 1
Surrogate: 13C2-4:2FTS 97.1%40-200 EPA 163302/23/24 1
Surrogate: 13C2-6:2FTS 77.1%40-200 EPA 163302/23/24 1
Surrogate: 13C2-8:2FTS 62.2%40-300 EPA 163302/23/24 1
Surrogate: 13C8-PFOSA 42.8%40-130 EPA 163302/23/24 1
Surrogate: D3-NMEFOSA 31.2%10-130 EPA 163302/23/24 1
Surrogate: D5-NETFOSA 33.5%10-130 EPA 163302/23/24 1
Surrogate: D3-NMEFOSAA 55.7%40-170 EPA 163302/23/24 1
Surrogate: D5-NETFOSAA 50.7%25-135 EPA 163302/23/24 1
Surrogate: D7-NMEFOSE 46.7%10-130 EPA 163302/23/24 1
Surrogate: D9-NETFOSE 47.1%10-130 EPA 163302/23/24 1
Surrogate: 13C3-HFPO-DA 107%40-130 EPA 163302/23/24 1
Page 19 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 19 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
EPA 1633
PREPARATION BATCH SUMMARY
Laboratory:
Client:
Batch Matrix:Batch:Preparation:
APPL, LLC
Waypoint Analytical
BDB0302 Water EPA 1633
SAMPLE NAME LAB SAMPLE ID DATE PREPARED INITIAL VOL./WEIGHT
mL
FINAL VOL.
mL
UPSTREAM 24B0105-01 02/19/24 13:30 557.54 2.00
DOWNSTREAM 24B0105-02 02/19/24 13:30 549.14 2.00
WELL#2 24B0105-03 02/19/24 13:30 563.74 2.00
WELL#4 24B0105-04 02/19/24 13:30 548.95 2.00
WELL#5 24B0105-05 02/19/24 13:30 573.56 2.00
WELL#7 24B0105-06 02/19/24 13:30 538.08 2.00
WELL#8 24B0105-07 02/19/24 13:30 572.65 2.00
WELL#9 24B0105-08 02/19/24 13:30 537.75 2.00
Blank BDB0302-BLK1 02/19/24 13:30 500.00 2.00
LCS BDB0302-BS1 02/19/24 13:30 500.00 2.00
MRL Check BDB0302-MRL1 02/19/24 13:30 500.00 2.00
Page 20 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 20 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Result/PQL Units
Spike
Level
Source
Result %REC
%REC
Limits RPD
RPD
LimitQual Analyte
Quality Control
Per- and Polyfluoroalkyl Substances
MDL
Batch: BDB0302 - EPA 1633
Method: EPA 1633
Prepared: 02/19/24 13:30 Analyzed: 02/23/24 05:06Blank (BDB0302-BLK1)
PFBA ND 1.6 ng/L0.21
PFPeA ND 0.80 ng/L0.065
PFHxA ND 0.40 ng/L0.055
PFHpA ND 0.40 ng/L0.041
PFOA ND 0.40 ng/L0.15
PFNA ND 0.40 ng/L0.082
PFDA ND 0.40 ng/L0.10
PFUnA ND 0.40 ng/L0.16
PFDoA ND 0.40 ng/L0.11
PFTrDA ND 0.40 ng/L0.20
PFTeDA ND 0.40 ng/L0.20
PFBS ND 0.40 ng/L0.037
PFPeS ND 0.40 ng/L0.063
PFHxS ND 0.40 ng/L0.032
PFHpS ND 0.40 ng/L0.051
PFOS 0.0979 0.40 ng/L0.064IR2, MI4, J
PFNS ND 0.40 ng/L0.12
PFDS ND 0.40 ng/L0.15
PFDoS ND 0.40 ng/L0.12
4:2FTS ND 1.6 ng/L0.29
6:2FTS ND 1.6 ng/L0.31
8:2FTS ND 1.6 ng/L0.082
PFOSA ND 0.40 ng/L0.10
NMeFOSA ND 1.6 ng/L0.47
NEtFOSA ND 1.6 ng/L0.41
NMeFOSAA ND 0.40 ng/L0.11
NEtFOSAA ND 0.40 ng/L0.11
NMeFOSE ND 1.6 ng/L1.0
NEtFOSE ND 1.6 ng/L1.0
HFPO-DA ND 0.80 ng/L0.17
ADONA ND 0.80 ng/L0.12
PFEESA ND 0.80 ng/L0.11
PFMPA ND 0.80 ng/L0.054
PFMBA ND 0.80 ng/L0.091
NFDHA ND 0.80 ng/L0.30
9Cl-PF3ONS ND 0.80 ng/L0.21
11Cl-PF3OUDS ND 0.80 ng/L0.21
3:3FTCA ND 1.6 ng/L0.57
5:3FTCA ND 1.6 ng/L0.44
7:3FTCA ND 1.6 ng/L0.55
32.0 5-130Surrogate: 13C4-PFBA 10132.4 ng/L
16.0 40-130Surrogate: 13C5-PFPEA 10216.3 ng/L
8.00 40-130Surrogate: 13C5-PFHXA 91.47.31 ng/L
8.00 40-130Surrogate: 13C4-PFHPA 92.47.40 ng/L
8.00 40-130Surrogate: 13C8-PFOA 1018.08 ng/L
4.00 40-130Surrogate: 13C9-PFNA 1014.03 ng/L
4.00 40-130Surrogate: 13C6-PFDA 1034.10 ng/L
[TOC_1]Quality Assurance
Results[TOC]
Page 21 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 21 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Result/PQL Units
Spike
Level
Source
Result %REC
%REC
Limits RPD
RPD
LimitQual Analyte
Quality Control
(Continued)
Per- and Polyfluoroalkyl Substances (Continued)
MDL
Prepared: 02/19/24 13:30 Analyzed: 02/23/24 05:06Blank (BDB0302-BLK1)
4.00 30-130Surrogate: 13C7-PFUnA 97.93.92 ng/L
4.00 10-130Surrogate: 13C2-PFDOA 95.03.80 ng/L
4.00 10-130Surrogate: 13C2-PFTEDA 92.03.68 ng/L
8.00 40-135Surrogate: 13C3-PFBS 1028.19 ng/L
8.00 40-130Surrogate: 13C3-PFHXS 1048.31 ng/L
8.00 40-130Surrogate: 13C8-PFOS 1018.06 ng/L
16.0 40-200Surrogate: 13C2-4:2FTS 10917.5 ng/L
16.0 40-200Surrogate: 13C2-6:2FTS 79.012.6 ng/L
16.0 40-300Surrogate: 13C2-8:2FTS 77.312.4 ng/L
8.00 40-130Surrogate: 13C8-PFOSA 52.94.23 ng/L
8.00 10-130Surrogate: D3-NMEFOSA 15.01.20 ng/L
8.00 10-130Surrogate: D5-NETFOSA 15.41.23 ng/L
16.0 40-170Surrogate: D3-NMEFOSAA 86.613.9 ng/L
16.0 25-135Surrogate: D5-NETFOSAA 71.111.4 ng/L
80.0 10-130Surrogate: D7-NMEFOSE 52.942.3 ng/L
80.0 10-130Surrogate: D9-NETFOSE 60.048.0 ng/L
32.0 40-130Surrogate: 13C3-HFPO-DA 10734.1 ng/L
Prepared: 02/19/24 13:30 Analyzed: 02/23/24 05:28LCS (BDB0302-BS1)
PFBA 16.2 16.0 70-140101ng/L
PFPeA 8.18 8.00 65-135102ng/L
PFHxA 4.00 4.00 70-14599.9ng/L
PFHpA 4.04 4.00 70-150101ng/L
PFOA 4.06 4.00 70-150102ng/L
PFNA 4.04 4.00 70-150101ng/L
PFDA 4.12 4.00 70-140103ng/L
PFUnA 4.19 4.00 70-145105ng/L
PFDoA 4.16 4.00 70-140104ng/L
PFTrDA 4.04 4.00 65-140101ng/L
PFTeDA 4.32 4.00 60-140108ng/L
PFBS 3.49 3.54 60-14598.6ng/L
PFPeS 3.92 3.76 65-140104ng/L
PFHxS 3.93 3.66 65-145107ng/L
PFHpS 3.80 3.82 70-15099.4ng/L
PFOS 3.84 3.72 55-150103ng/L
PFNS 3.95 3.84 65-145103ng/L
PFDS 3.65 3.86 60-14594.6ng/L
PFDoS 3.60 3.88 50-14592.9ng/L
4:2FTS 15.9 15.0 70-145106ng/L
6:2FTS 16.4 15.2 65-155108ng/L
8:2FTS 15.6 15.4 60-150101ng/L
PFOSA 4.08 4.00 70-145102ng/L
NMeFOSA 15.0 16.0 60-15093.9ng/L
NEtFOSA 13.7 16.0 65-14585.6ng/L
NMeFOSAA 4.17 4.00 50-140104ng/L
NEtFOSAA 3.83 4.00 70-14595.9ng/L
NMeFOSE 14.5 16.0 70-14590.8ng/L
NEtFOSE 14.5 16.0 70-13590.7ng/L
HFPO-DA 4.06 4.00 70-140102ng/L
ADONA 3.03 3.78 65-14580.1ng/L
Page 22 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 22 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Result/PQL Units
Spike
Level
Source
Result %REC
%REC
Limits RPD
RPD
LimitQual Analyte
Quality Control
(Continued)
Per- and Polyfluoroalkyl Substances (Continued)
MDL
Prepared: 02/19/24 13:30 Analyzed: 02/23/24 05:28LCS (BDB0302-BS1)
PFEESA 6.90 7.12 70-14096.9ng/L
PFMPA 7.93 8.00 55-14099.1ng/L
PFMBA 7.76 8.00 60-15097.0ng/L
NFDHA 9.72 8.00 50-150121ng/L
9Cl-PF3ONS 3.02 3.74 70-15580.7ng/L
11Cl-PF3OUDS 2.84 3.78 55-16075.1ng/L
3:3FTCA 13.4 16.0 65-13083.5ng/L
5:3FTCA 14.1 16.0 70-13588.4ng/L
7:3FTCA 11.6 16.0 50-14572.6ng/L
32.0 5-130Surrogate: 13C4-PFBA 99.331.8 ng/L
16.0 40-130Surrogate: 13C5-PFPEA 10016.0 ng/L
8.00 40-130Surrogate: 13C5-PFHXA 95.47.63 ng/L
8.00 40-130Surrogate: 13C4-PFHPA 94.57.56 ng/L
8.00 40-130Surrogate: 13C8-PFOA 98.57.88 ng/L
4.00 40-130Surrogate: 13C9-PFNA 1004.01 ng/L
4.00 40-130Surrogate: 13C6-PFDA 1014.04 ng/L
4.00 30-130Surrogate: 13C7-PFUnA 93.53.74 ng/L
4.00 10-130Surrogate: 13C2-PFDOA 94.43.77 ng/L
4.00 10-130Surrogate: 13C2-PFTEDA 87.13.48 ng/L
8.00 40-135Surrogate: 13C3-PFBS 1068.46 ng/L
8.00 40-130Surrogate: 13C3-PFHXS 98.77.90 ng/L
8.00 40-130Surrogate: 13C8-PFOS 1038.24 ng/L
16.0 40-200Surrogate: 13C2-4:2FTS 10216.4 ng/L
16.0 40-200Surrogate: 13C2-6:2FTS 72.011.5 ng/L
16.0 40-300Surrogate: 13C2-8:2FTS 77.112.3 ng/L
8.00 40-130Surrogate: 13C8-PFOSA 49.33.94 ng/L
8.00 10-130Surrogate: D3-NMEFOSA 13.61.09 ng/L
8.00 10-130Surrogate: D5-NETFOSA 12.71.02 ng/L
16.0 40-170Surrogate: D3-NMEFOSAA 84.613.5 ng/L
16.0 25-135Surrogate: D5-NETFOSAA 71.011.4 ng/L
80.0 10-130Surrogate: D7-NMEFOSE 44.435.5 ng/L
80.0 10-130Surrogate: D9-NETFOSE 49.239.3 ng/L
32.0 40-130Surrogate: 13C3-HFPO-DA 10834.7 ng/L
Page 23 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 23 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Result/PQL Units
Spike
Level
Source
Result %REC
%REC
Limits RPD
RPD
LimitQual Analyte
Quality Control
(Continued)
Per- and Polyfluoroalkyl Substances (Continued)
MDL
Prepared: 02/19/24 13:30 Analyzed: 02/23/24 05:49MRL Check (BDB0302-MRL1)
PFBA 3.24 3.20 70-140101ng/LMI3
PFPeA 1.60 1.60 65-13599.8ng/L
PFHxA 0.835 0.800 70-145104ng/L
PFHpA 0.775 0.800 70-15096.8ng/L
PFOA 0.856 0.800 70-150107ng/L
PFNA 0.720 0.800 70-15090.0ng/L
PFDA 0.752 0.800 70-14094.0ng/L
PFUnA 0.702 0.800 70-14587.7ng/L
PFDoA 0.785 0.800 70-14098.2ng/L
PFTrDA 0.793 0.800 65-14099.2ng/L
PFTeDA 0.820 0.800 60-140102ng/L
PFBS 0.698 0.708 60-14598.6ng/L
PFPeS 0.723 0.752 65-14096.1ng/L
PFHxS 0.775 0.732 65-145106ng/L
PFHpS 0.772 0.764 70-150101ng/L
PFOS 0.820 0.744 55-150110ng/L
PFNS 0.719 0.768 65-14593.7ng/L
PFDS 0.663 0.772 60-14585.9ng/L
PFDoS 0.662 0.776 50-14585.3ng/L
4:2FTS 2.58 3.00 70-14586.0ng/L
6:2FTS 3.04 3.04 65-155100ng/L
8:2FTS 3.06 3.07 60-15099.6ng/L
PFOSA 0.774 0.800 70-14596.8ng/L
NMeFOSA 2.58 3.20 60-15080.5ng/L
NEtFOSA 2.15 3.20 65-14567.1ng/L
NMeFOSAA 0.846 0.800 50-140106ng/L
NEtFOSAA 0.754 0.800 70-14594.2ng/LMI4
NMeFOSE 2.81 3.20 70-14587.7ng/L
NEtFOSE 2.63 3.20 70-13582.0ng/LMI4
HFPO-DA 0.868 0.800 70-140108ng/L
ADONA 0.580 0.756 65-14576.8ng/LJ
PFEESA 1.32 1.42 70-14092.8ng/L
PFMPA 1.49 1.60 55-14093.2ng/L
PFMBA 1.50 1.60 60-15093.7ng/L
NFDHA 1.64 1.60 50-150102ng/L
9Cl-PF3ONS 0.584 0.748 70-15578.1ng/LJ
11Cl-PF3OUDS 0.534 0.756 55-16070.6ng/LJ
3:3FTCA 2.43 3.20 65-13076.0ng/L
5:3FTCA 2.86 3.20 70-13589.4ng/L
7:3FTCA 2.36 3.20 50-14573.9ng/L
32.0 5-130Surrogate: 13C4-PFBA 10533.4 ng/L
16.0 40-130Surrogate: 13C5-PFPEA 10116.2 ng/L
8.00 40-130Surrogate: 13C5-PFHXA 93.47.47 ng/L
8.00 40-130Surrogate: 13C4-PFHPA 97.97.83 ng/L
8.00 40-130Surrogate: 13C8-PFOA 1068.46 ng/L
4.00 40-130Surrogate: 13C9-PFNA 1094.38 ng/L
4.00 40-130Surrogate: 13C6-PFDA 1064.25 ng/L
4.00 30-130Surrogate: 13C7-PFUnA 98.43.94 ng/L
4.00 10-130Surrogate: 13C2-PFDOA 98.63.95 ng/L
4.00 10-130Surrogate: 13C2-PFTEDA 92.63.70 ng/L
Page 24 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 24 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Result/PQL Units
Spike
Level
Source
Result %REC
%REC
Limits RPD
RPD
LimitQual Analyte
Quality Control
(Continued)
Per- and Polyfluoroalkyl Substances (Continued)
MDL
Prepared: 02/19/24 13:30 Analyzed: 02/23/24 05:49MRL Check (BDB0302-MRL1)
8.00 40-135Surrogate: 13C3-PFBS 1118.89 ng/L
8.00 40-130Surrogate: 13C3-PFHXS 1118.85 ng/L
8.00 40-130Surrogate: 13C8-PFOS 1078.58 ng/L
16.0 40-200Surrogate: 13C2-4:2FTS 11518.4 ng/L
16.0 40-200Surrogate: 13C2-6:2FTS 80.512.9 ng/L
16.0 40-300Surrogate: 13C2-8:2FTS 79.312.7 ng/L
8.00 40-130Surrogate: 13C8-PFOSA 50.84.06 ng/L
8.00 10-130Surrogate: D3-NMEFOSA 12.71.01 ng/L
8.00 10-130Surrogate: D5-NETFOSA 13.21.06 ng/L
16.0 40-170Surrogate: D3-NMEFOSAA 92.514.8 ng/L
16.0 25-135Surrogate: D5-NETFOSAA 75.112.0 ng/L
80.0 10-130Surrogate: D7-NMEFOSE 52.742.2 ng/L
80.0 10-130Surrogate: D9-NETFOSE 58.546.8 ng/L
32.0 40-130Surrogate: 13C3-HFPO-DA 11336.1 ng/L
Page 25 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 25 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
Notes and Definitions
Item Definition
Ion ratio below the lower control limitIR1
Ion ratio above the upper control limitIR2
Estimated valueJ
Manual integration, peaks splitMI3
Manual integration, peak unsplitMI4
Manual integration, wrong peak integratedMI6
Surrogate recovered below the lower control limitS1
Not detectedU
Dry Sample results reported on a dry weight basis.
MDL Method Detection Limit (only displays if reported to the MDL)
ND Analyte NOT DETECTED at or above the reporting limit.
DF Dilution Factor
DL Detection Limit
RPD Relative Percent Difference
%REC Percent Recovery
Source Sample that was matrix spiked or duplicated.
PQL, Practical Quantitation Limit = Method Reporting Limit (MRL).
[TOC_1]Qualifiers and
Definitions[TOC]
Page 26 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 26 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
RL6026021424PO Number:
Chue MouaProject Manager:
6026 Richmond CountyProject Number:
Project: 6026 Richmond County Solid Waste
Printed: 02/27/2024 1:45 pm
24B0105
WORK ORDER
Waypoint Analytical
Jerri Dawson
2790 Whitten Road
Memphis, TN 38133
Phone: [phone]
Fax: [phone]
Waypoint Analytical
Ann Baynor
114 Oakmont Drive
Greenville, NC 27858
Phone: [phone]
Fax: [phone]
Report To: Invoice To:
Logged In By:Sophia Herrera
Date Due:02/29/2024 (10.00 day TAT)Received By:
Date Received:
Terry Moren
02/15/2024 09:45 AM
Analysis Comments
24B0105-01 UPSTREAM [Water] Sampled 2/7/2024 12:40:00PM
1633 1633
24B0105-02 DOWNSTREAM [Water] Sampled 2/7/2024 11:05:00AM
1633 1633
24B0105-03 WELL#2 [Water] Sampled 2/7/2024 10:25:00AM
1633 1633
24B0105-04 WELL#4 [Water] Sampled 2/7/2024 11:46:00AM
1633 1633
24B0105-05 WELL#5 [Water] Sampled 2/7/2024 12:14:00PM
1633 1633
24B0105-06 WELL#7 [Water] Sampled 2/7/2024 12:45:00PM
1633 1633
24B0105-07 WELL#8 [Water] Sampled 2/7/2024 10:59:00AM
1633 1633
24B0105-08 WELL#9 [Water] Sampled 2/7/2024 9:48:00AM
1633 1633
[TOC_1]Login Summary[TOC]
Page 27 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 27 of 31
Table of Contents
Project:
Project Number:
Project Manager:
Waypoint Analytical
114 Oakmont Drive
Greenville, NC 27858
6026 Richmond County Solid Waste
6026 Richmond County
Ann Baynor Reported: 02/27/2024 13:45
APPL, LLC - 908 N. Temperance Ave., Clovis, CA 93611
24B0105 Sample Receipt Log
2.3CSamples Received at:
Default Cooler
Containers Intact
Yes
Yes
Yes
No
Preservation Confirmed
COC/Labels Agree
Custody Seals
Was a chain of custody received?
Yes
Yes
Yes
Sample labels complete? Sample ID, date/time, etc.
COCs complete/signed in the appropriate places?
YesReceived On Ice
Did all containers arrive in good condition?
Correct containers/preserv. for tests indicated?
Were all containers sealed in separate bags?
Yes
Did all container labels agree with COCs?
Yes
Yes
Yes
Sufficient volume sent for tests requested?
Were bubbles absent in volatile samples?
Yes
Yes
Sufficient remaining holding time for analyses?
pH of non-VOA preserved containers documented?
Unpreserved vials received for VOA analysis?
If "yes", are unpreserved VOA vials noted on Work
Yes
No
No
No
Page 28 of 30
The contents of this report apply to the sample(s) analyzed in accordance with the chain of custody document.
No duplication of this report is allowed, except in its entirety.Page 28 of 31
Table of Contents
Page 29 of 31Table of Contents
Page 30 of 31Table of Contents
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Page 31 of 31
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