Loading...
HomeMy WebLinkAbout8103_Rutherford_Central_MSWLF_CDLF_Nov24GW_FID1830491_20240220DEN R USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR I IEnvironmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Bunnell-Lammons Engineering, Inc. (consultant) Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Andrew W. Alexander. P.G. RSM Phone: (864)288-1265 E-mail: andy.alexander(cDblecorp.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) 8103-MSWLF- Rutherford County 656 Laurel Hill Drive 1974 .1600 Central Landfill Rutherfordton, NC November 20-29, 2023 8103-CDLF-2002 .0500 0 Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑X Detection Monitoring ❑X Assessment Monitoring ❑X Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Groundwater monitoring data from private water supply wells ❑ Leachate monitoring data El water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Andrew W. Alexander, P.G. RSM Consultant Hydrogeologist (864) 288-1265 Facility Representative Name (Print) Title (Area Code) Telephone Number �� w a• �E,o•,....=...1`.a•d„®`,•o,o 2/20/2024 Signature Date 6004 Ponders Court, Greenville, SC, 29615 Facility Representative Address C-284 & C-1538 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 Affix NC Licensed/ Professional Geologist Seal SEMI-ANNUAL WATER QUALITY MONITORING REPORT SECOND EVENT 2023 RUTHERFORD COUNTY CENTRAL LANDFILL RUTHERFORDTON, NORTH CAROLINA PERMIT No. 8103-MSWLF-1974 PERMIT No. 8103-CDLF-2002 Prepared For: Rutherford County Solid Waste Dept. Rutherfordton, North Carolina BLE Project Number J23-13675-06 February 20, 2024 BLE North Carolina Business Licenses C-284 & C-1538 is IM IM BUNNELL LAMMONS ENGINEERING 6004 Ponders Court I Greenville, 5C 29615 864,288.1265 �I 864.288,4330 0 info@blecorp.com BLECORP.COM � CANNONS ENGINEERING February 20, 2024 Rutherford County Solid Waste Department P.O. Box 1957 Rutherfordton, North Carolina 28139 Attention: Mr. James Kilgo Subject: Semi -Annual Water Quality Monitoring Report Second Event 2023 Rutherford County Central Landfill Rutherfordton, North Carolina Permit Nos. 8103-MSWLF-1974 & 8103-CDLF-2002 BLE Project No. J23-13675-06 Dear Mr. Kilgo: Pursuant to Rutherford County's authorization of Bunnell-Lammons Engineering, Inc. (BLE) Contract Number J23-13675-06, dated September 20, 2023, BLE has prepared this reportof the groundwater and surface water sampling and laboratory analysis for the second semi-annual sampling event of 2023 at the Rutherford County Central Landfill. Consistent with the North Carolina Division of Waste Management (DWM) — Solid Waste Section (SWS) approved monitoring program, sampling and analysis has been conducted twice in 2023. This report contains the information required by the SWS to document the sampling and analysis activities for the second semi-annual sampling event of 2023 in the State's permanent project record. Sincerely, BUNNELL LAMMONS ENGINEERING INC. Blais, P.G. Project Hydrogeologist Registered, NC #2896 cc: Ms. Jaclynne Drummond — SWS Acl Andrew W. Alex der, P.G., RSM Consultant Hydrogeologist Registered, NC #1475 '6004 Panders Court, Greenvll€e, SC 29615 1,864,288.1265 r,-#864,288.4430 info@hleeorp,com BLECORP.COM 1s 1m 1i Water Quality Report — 2nd Semi -Annual Event 2023 February 20, 2024 Rutherford County Central Landfill — Rutherfordton, North Carolina BLE Project No. J23-13675-06 TABLE OF CONTENTS 1.0 PROJECT INFORMATION........................................................................................................1 2.0 FIELD ACTIVITIES, SAMPLING, AND ANALYSIS............................................................. 2 3.0 GROUNDWATER FLOW........................................................................................................... 2 4.0 GROUNDWATER RESULTS..................................................................................................... 2 5.0 SURFACE WATER RESULTS................................................................................................... 2 6.0 SUMMARY.................................................................................................................................... 3 6.1 General.............................................................................................................................................3 6.2 Results for 1,4-Dioxane Analyses.................................................................................................... 3 6.3 Corrective Action............................................................................................................................. 3 7.0 QUALIFICATIONS OF REPORT.............................................................................................. 4 8.0 CLOSING.......................................................................................................................................4 Tables Table 1 SWS Approved Monitoring Matrix Table 2A Groundwater Monitoring Well Data Table 213 Surface Water Monitoring Point Data Table 3 Range of Groundwater Flow Velocities Table 4 Groundwater VOCs Table 5 Groundwater Field Parameters, Total Metals, and Other Parameters Table 6 Surface Water VOCs Table 7 Surface Water Field Parameters and Total Metals Figures Figure 1 Site Location Map Figure 2 Groundwater Elevation Contour Map — November 28, 2023 Appendices Appendix A Field Sampling Logs — Pace Analytical Services, LLC. Appendix B Laboratory Analytical Data — Pace Analytical Services, LLC. i of i 1s 1m 1i Water Quality Report — 2nd Semi -Annual Event 2023 February 20, 2024 Rutherford County Central Landfill — Rutherfordton, North Carolina BLE Project No. J23-13675-06 1.0 PROJECT INFORMATION The subject landfill site is located in Rutherford County, North Carolina, between the cities of Rutherfordton and Spindale with a physical address of 656 Laurel Hill Dr, Rutherfordton, North Carolina (Figure 1). Rutherford County owns and operates an inactive/closed MSWLF (Permit No. 8103-MSWLF- 1974) and an active CDLF (Permit No. 8103-CDLF-2002) consisting of two waste units designated Phase 1 and Phase 2. A Water Quality Monitoring Plan (WQMP) dated February 19, 2021 was prepared by BLE (Project No J19-13675-02) and submitted to the North Carolina Solid Waste Section (SWS). The WQMP was approved on March 1, 2021 (FID 1542209). Scarlett Geophysical Consulting, P.C. (SGC) submitted a document titled Corrective Action Evaluation Report dated January 5, 2022 (FID 1629801). SGC submitted a letter dated April 8, 2022 (FID 1664554) to the SWS regarding the findings of the corrective action evaluation report (CAER) and requested a change to the groundwater and surface water monitoring matrices. The SWS approved the CAER on February 15, 2022 (FID 1642699) and the SGC letter on April 19, 2022 (FID 1664556). The SWS-approved monitoring matrix for the Fall 2023 monitoring event is included for reference (Table 1). The SWS issued a memorandum dated March 13, 2023 to all solid waste directors and landfill owners/operators. The memo requires that all groundwater, surface water, and leachate samples collected at solid waste sanitary landfills after July 1, 2023 be analyzed for PFAS. The SWS issued a second memorandum dated July 17, 2023 to all solid waste directors and landfill owners/operators. The second memo provides clarification to the PFAS monitoring requirements including an option to propose a subset of assessment/corrective action groundwater monitoring wells and a subset of surface water monitoring points. Odom Engineering, PLLC. on behalf of Rutherford County, issued a notice to the SWS dated September 25, 2023 (FID 1818144) that the facility would initiate the required PFAS monitoring program beginning with the April 2024 water quality sampling event. The SWS approved the monitoring request on September 27, 2023 (FID 1818148). The existing groundwater monitoring network for the Rutherford County Landfill consists of one (1) upgradient (background) well (MW-2) and fifteen (15) downgradient (compliance) wells (MW-3, MW-4, MW-6, MW-7, MW-8, MW-9, MW-lOB, MW-IOC, MW-10D, MW-11A, MW-1113, MW-12, MW-13, MW-14, and MW-15) and three (3) inactive wells (MW-1, MW-5, and MW-10A). Additionally, there is one (1) assessment well, MW-16. The inactive monitoring wells MW-1 and MW-10A are present but are not monitored as part of the compliance network. The status of inactive monitoring well MW-5 is unknown. The monitoring well location and construction data is summarized on Table 2A. In accordance with Rule .0602 and Rule .0544(c), five (5) surface water monitoring locations have been established for the facility to monitor surface water quality surrounding the existing waste footprints. The existing surface water locations consist of one (1) upstream (background) point (SW-4) and four (4) downstream (compliance) points (SW-2, SW-3, SW-5, and SW-6). The surface water monitoring locations are summarized on Table 2B. The facility requires semi-annual groundwater and surface water monitoring and reporting in accordance with the WQMP et seq. Semi-annual sampling is typically conducted each April and October and those events are designated "Spring" and "Fall," respectively. This report represents the second semi-annual (Fall) sampling 1 of 4 1s 1m 1i Water Quality Report — 2nd Semi -Annual Event 2023 February 20, 2024 Rutherford County Central Landfill — Rutherfordton, North Carolina BLE Project No. J23-13675-06 event of 2023. This single report includes the results from the MSWLF and CDLF as has traditionally been submitted in the past. 2.0 FIELD ACTIVITIES, SAMPLING, AND ANALYSIS Groundwater and surface water samples were collected between November 20-29, 2023 by personnel from Pace Analytical Services, LLC. (Pace). Groundwater samples were collected from all sixteen (16) groundwater monitoring well locations and the assessment well (MW-16). Additionally, the five (5) surface water locations were sampled. The groundwater and surface water samples were analyzed by Pace in their Asheville and Charlotte, North Carolina laboratories per the approved monitoring matrix (Table 1). The field parameters of dissolved oxygen, pH, redox potential, specific conductance, turbidity, and temperature were measured in the field by Pace. A copy of the Pace field sampling logs is included in Appendix A. A copy of the laboratory analytical data is included in Appendix B. A duplicate sample was collected from one well (MW-3) in accordance with the quality control program (Table 1). The duplicate sample was laboratory blind. The laboratory results for the duplicate sample are included in Appendix B. 3.0 GROUNDWATER FLOW The water level data collected during the groundwater sampling event on November 28, 2023 is presented in Table 2A. Groundwater flow velocity estimates are presented on Table 3. A groundwater elevation contour map with generalized groundwater flow directions is presented as Figure 2. 4.0 GROUNDWATER RESULTS The results of the groundwater field and laboratory analyses for the CDLF and MSWLF are summarized on Table 4 and Table 5 and the laboratory analytical data is included in Appendix B. Please refer to Table 4 and Table 5 for a summary of which groundwater constituents exceed North Carolina Groundwater Quality Standards (NC2L) maximum contaminant levels' (MCLs). Field parameters measured in the groundwater included dissolved oxygen, pH, redox potential, specific conductance, turbidity, and temperature. Please refer to Table 5 for a summary of measured field parameters. The field parameter, pH, was below its NC2L in twelve (12) of the sixteen (16) compliance wells. 5.0 SURFACE WATER RESULTS The results of the surface water field and laboratory analyses are summarized on Table 6 and Table 7 and the laboratory analytical data is included in Appendix B. ' North Carolina Department of Environmental Quality, Groundwater Classification and Standards, Section 15A NCAC 2L.202, April 1, 2022. 2 of 4 1s 1M 1i Water Quality Report — 2nd Semi -Annual Event 2023 February 20, 2024 Rutherford County Central Landfill — Rutherfordton, North Carolina BLE Project No. J23-13675-06 Field parameters measured in the surface water included dissolved oxygen, pH, redox potential, specific conductance, turbidity, and temperature. Please refer to Table 6 and Table 7 for a summary of which surface water constituents and field parameters exceeded their established North Carolina Surface Water Quality Standards (NC2B)2 standard limits. 6.0 SUMMARY 6.1 General Semi-annual assessment monitoring was performed during the second semi-annual event of 2023 in general accordance with the approved WQMP and SWS-approved matrix. Detected constituents which exceed their respective groundwater and surface water standards (if any) are identified on the summary tables. The November 2023 results are similar to the prior June 2023 monitoring event. We recommend that semi-annual sampling continue in accordance with the approved plans and matrices. 6.2 Results for 1,4-Dioxane Analyses The facility has continued to collect and analyze groundwater and surface water samples for 1,4-doxane (an emerging contaminant) as required by the SWS. Detected concentrations of 1,4-doxane exceed the promulgated groundwater standard in several groundwater monitoring wells. 1,4-Dioxane was not detected in the surface waters at the facility. We understand that the SWS does not currently consider the 1,4-doxane results a compliance issue at the subject facility. However, we understand that the SWS could require an assessment of the extent of 1,4-doxane in the future and that these determinations are made on a case -by -case basis. 6.3 Corrective Action The SWS has approved a corrective action plan (CAP) for the subject facility. The approved remedy in the CAP is monitored natural attenuation (MNA). Prior to 2022, groundwater monitoring for Appendix II and MNA parameters was required for each semi- annual event. We understand that the sampling schedule was adopted in 2007 with the acceptance of the CAP. The Appendix II and MNA monitoring reports were prepared in conjunction with the semi-annual water quality reports in the past. The most recent Appendix II and MNA sampling event for the facility was performed in May 2022. The next Appendix II and MNA sampling event is scheduled for April 2024. The next CAER should be submitted following the April 2026 biennial Appendix II and MNA sampling event. 2 North Carolina Department of Environmental Quality, Surface Waters and Wetlands Standards, Section 15A NCAC 02B.0100, .0200, and .0300, per NC DWR Surface Water Quality Standards, Criteria, & In -Stream Target Values (Workbook Dated 7-26-2021) 3 of 4 1s 1M 1i Water Quality Report — 2nd Semi -Annual Event 2023 February 20, 2024 Rutherford County Central Landfill — Rutherfordton, North Carolina BLE Project No. J23-13675-06 7.0 QUALIFICATIONS OF REPORT The activities and evaluative approaches used in this assessment are consistent with those normally employed in hydrogeological and environmental assessments of this type. Our evaluation of site conditions has been based on our understanding of the site and project information and the data provided to BLE. This report has been prepared on behalf of and exclusively for the use of Rutherford County, North Carolina. This report and the findings contained herein shall not, in whole or in part, be used or relied upon by any other parry (excluding the SWS) without BLE's prior written consent. 8.0 CLOSING We appreciate the opportunity to be of service to Rutherford County, North Carolina. Please contact us at (864) 288-1265 if you have any questions or comments. 4 of 4 Tables Table 1 SWS Approved Monitoring Matrix Rutherford County Central Landfill Rutherfordton, North Carolina Permit No. 8103-MSWLF-1974 Permit No. 8103-CDLF-2002 BLE Project Number J23-13657-06 Fall 2023 Only *Analytical Suite* 1,4-Dioxane Station ID a o V 3 MW-2 A-1 Plus Yes W MW-1 - MW-3 A-1 Plus Yes MW-4 A-1 Yes MW-5 - MW-6 A-1 Yes MW-7 A-1 Yes MW-8 A-1 Yes MW-9 A-1 Yes V F7 ° = MW-10A - a 0 3 MW-10B A-1 Yes U MW-10C A-1 Yes MW-10D A-1 Yes MW-11A A-1 Yes MW-11B A-1 Yes MW-12 A-1 Plus Yes MW-13 A-1 Plus Yes MW-14 A-1 Plus Yes MW-15 A-1 Plus Yes MW-16 A-1 Plus Yes SW-2 A-1 Plus Yes y SW-3 A-1 Plus Yes SW 4 A-1 Plus Yes SW-5 A-1 Plus Yes SW-6 I A-1 Plus I Yes � o Duplicate A-1 VOC Only - O U (1 Sample) Notes: A-1 = Appendix I VOCs & Metals A-1 Plus = Appendix I VOCs plus Tetrahydrofuran, & Metals plus Mercury, Manganese, Iron, Aluminum, Sulfate, Chloride, Alkalinity, & Total Dissolved Solids RCCLF SWS Approved Matrix 13657-06 Prepared by: RLB Tl Approved Matrix Checked by: TCG Table 2A Groundwater Monitoring Well Data Rutherford County Landfill Rutherfordton, North Carolina Permit No. 8103-CDLF-2002 Permit No. 8103-MSWLF-1974 BLE Project Number J23-13657-06 Monitoring Point MSW or C&D Northing (ft) Easting (ft) Latitude (dd) Longitude (dd) TOC Elevation (ft) Ground Surface Elevation (ft) Depth to GW (ft) November 28, 2023 Groundwater Elevation (ft) Well Depth (ft) Screen Depth (below GS) Installation Date Geology Monitored Well Status/Purpose Well Diameter (in) MW-1I Background 596,114.73 1,120,714.40 35.352042 -81.949322 1007.76 1006.05 NM NM 45.5 35.5 - 45.5 DNA Saprolite/PWR Inactive 2.0 MW-2I Background 596,355.31 1,119,904.89 35.352636 -81.952059 994.86 994.47 48.56 946.30 60.0 50.0 - 60.0 DNA Saprolite/PWR Background 2.0 MW-32 C&D 595,209.61 1,118,703.75 1 35.349391 -81.955971 860.28 859.62 35.14 825.14 47.0 37.0 - 47.0 DNA Saprolite/PWR Compliance 2.0 MW-42 MSW 594,627.05 1,118,864.35 35.347805 -81.955375 851.03 849.72 36.44 814.59 50.0 40.0 - 50.0 DNA DNA Compliance 2.0 MW-52 MSW 592,671.03 1,1195287.91 35.342467 -81.953760 824.23 823.23 NM NM DNA DNA DNA DNA Inactive 2.0 MW-62 MSW 593,847.08 1,118,805.37 35.345658 -81.955495 834.90 833.43 31.74 803.16 37.5 22.5 - 37.5 11/16/1994 Saprolite/PWR Compliance 2.0 MW-72 MSW 5935056.27 1,1185974.79 35.343499 -81.954848 892.70 890.51 37.76 854.94 54.0 39.0 - 54.0 11/16/1994 Bedrock Compliance 2.0 MW-82 MSW 593,666.26 1,119,935.70 35.345254 81.951688 860.31 857.86 47.51 812.80 44.5 29.5 - 44.5 3/15/1995 Saprolite Compliance 2.0 MW-92 MSW 594,368.07 1,1205182.39 35.347201 -81.950931 867.25 864.97 34.82 832.43 37.5 22.5 - 37.5 3/18/1995 Saprolite Compliance 2.0 MW-10A MSW DNA DNA DNA DNA 837.23 834.73 NM NM 101.0 91.0 - 101.0 8/5/1998 Bedrock Inactive 2.0 MW-10B MSW DNA DNA DNA DNA 836.15 834.50 9.62 826.53 37.0 32.0 - 37.0 8/5/1998 PWR Compliance 2.0 MW-10C MSW DNA DNA DNA DNA 836.19 834.50 9.38 826.81 16.0 11.0 - 16.0 8/5/1998 Saprolite Compliance 2.0 MW-lOD MSW DNA DNA DNA DNA 837.23 834.73 10.68 826.55 66.0 56.0 - 66.0 8/5/1998 Bedrock Compliance 2.0 MW-11A MSW DNA DNA DNA DNA 817.18 815.39 8.79 808.39 45.0 35.0 - 45.0 8/8/1998 PWR/Bedrock Compliance 2.0 MW-1113 MSW DNA DNA DNA DNA 817.72 816.02 9.95 807.77 20.0 10.0 - 20.0 8/8/1998 Saprolite Compliance 2.0 MW-12 C&D DNA DNA DNA DNA 886.68 884.33 42.25 844.43 45.5 35.5 - 45.5 6/14/2002 Saprolite/PWR Compliance 2.0 MW-13' C&D 594,988.71 1,1205032.88 35.348893 -81.951494 962.47 960.35 81.76 880.71 88.0 73.0 - 88.0 5/24/2000 Bedrock Compliance 2.0 MW-14' C&D 595,446.06 1,118,985.16 35.350064 -81.955052 868.94 866.54 25.96 842.98 32.4 17.4 - 32.4 2/7/2008 Saprolite/PWR Compliance 2.0 MW-15' C&D 595,672.95 1,1185986.20 35.350687 -81.955071 889.13 887.52 38.27 850.86 38.0 28.0 - 38.0 5/25/2000 Bedrock Compliance 2.0 MW-16 C&D DNA DNA DNA DNA DNA DNA 26.31 DNA DNA DNA May 2019 DNA Assessment 2.0 Notes: 1 - Surveying for locations was performed by McGill Associates of Asheville, NC on December 2-3, 2019. 2 - Surveying for locations was performed by Professional Surveying Services of Rutherfordton, NC on May 17, 1993. DNA = Data Not Available. Information was not provided in previous SHR & DHR reports performed by others. TOC - Top of Casing. GS - Ground Surface. NM - Not Measured. All depth measurements in feet. 13657-06 GW Tables (Completion, water levels, detections) Prepared by: RLB T2A MW Points Checked by: ZJD/TAO Table 2B Surface Water Monitoring Point Data Rutherford County Landfill Rutherfordton, North Carolina Permit No. 8103-CDLF-2002 Permit No. 8103-MSWLF-1974 BLE Project Number J23-13657-06 Monitoring Point Status Northing (ft) Easting (ft) Latitude (dd) Longitude (dd) SW-2 Compliance 594,929.41 1,118,459.57 35.348602 -81.956762 SW-3 Compliance 592,568.42 1,119,391.36 35.342194 -81.953403 SW-4 Background 597,319.50 1,119,913.68 35.355285 -81.952126 SW-5 Compliance 592,241.97 15225,767.45 35.349467 -81.596782 SW-6 Compliance 594,587.41 1,118,670.73 J 35.347680 -81.956020 Notes: 1 - Surveying data was collected via handheld GPS by Pace Analytical Services, LLC on November 20, 2023. 13657-06 GW Tables (Completion, water levels, detections) Prepared by: RLB T213 SW Points Checked by: ZJD Table 3 Range of Groundwater Flow Velocities Rutherford County Landfill Rutherfordton, North Carolina Permit No. 8103-CDLF-2002 Permit No. 8103-MSWLF-1974 BLE Project Number J23-13657-06 Hydraulic Conductivity K(ft/min) K(cm/sec) K(ft/day) High Estimate 8.9E-03 4.5E-03 12.813 Low Estimate 2.6E-06 1.3E-06 0.004 Geometric Mean 1.5E-04 7.8E-05 0.221 Geometric Mean Hydraulic Conductivity K(ft/day) Hydraulic Grad. (ft/ft) Effective Porosity Flow Vel. (ft/day) Flow Vel. (ft/year) High Estimate 0.221 0.167 5% 0.74 269 Low Estimate 0.221 0.014 35% 0.01 3 Notes: 1. Hydraulic conductivity and effective porosity values obtainted from the Design Hydrogeologic Report - Phase 2 prepared by BLE dated February 3, 2021. 3. The hydraulic gradients were measured from the November 28, 2023 groundwater elevation contour map (Figure 2). The high hydraulic gradient was measured between the 810-ft & 860-ft groundwater contours near MW-6. The low hydraulic gradient was measured between the 850-ft & 870-ft groundwater contours in the closed MSWLF area. 4. Groundwater velocity derived from V = Ki/ne where: K = geometric mean hydraulic conductivity, i = hydraulic gradient, and ne = effective porosity. 5. The high and low velocity estimates are calculated using the geometric mean K and the high and low range of site hydraulic data obtained from BLE's 2021 DHR. 13657-06 GW Tables (Completion, water levels, detections) Prepared By: RLB T3 GW Flow Vel. Checked By: TAO Table 4 Groundwater VOCs Rutherford County Landfill Rutherfordton, North Carolina Permit No. 8103-CDLF-2002 Permit No. 8103-MSWLF-1974 BLE Project Number J23-13657-06 Sampled by Pace Analytical Services, LLC. November 20, 28, & 29 2023 Background Well Compliance Wells TEST UNITS RL DL MCL MW-2 14W-3 MM ATM MW-7 MW-8 MW-9 14W-10B MW-10C 14W-10D MV011A MN011B MW-12 14W-13 MW-14 MW-15 MW-16 Acetone µg/1 25.0 5.1 6,000 <5.1 <5.1 <5.1 <5.1 <5.1 <5.1 <5.1 <5.1 <5.1 <5.1 <5.1 <5.1 <5.1 <5.1 <5.1 <5.1 <5.1 Acrylonitrile µg/l 10.0 1.8 NE CA <11 <11 <11 ON <11 <11 <11 At <11 <11 <11 CA At CA ON 0.8 Benzene µg/l 1.0 0.34 1.0 <0.34 <0.34 <0.34 0.48 J <0.34 <0.34 <0.34 <0.34 <0.34 0.49 J <0.34 <0.34 <0.34 0.97 J <0.34 <0.34 <0.34 Bromochloromethane µg/l 1.0 0.47 NE <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 Bromodichloromethane µg/l 1.0 0.31 0.6 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 Bromoform µg/l 1.0 0.34 4.0 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 Carbon Disulfide µg/l 2.0 0.36 700 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 Bromomethane (Methylbromide) µg/l 2.0 1.7 10 <1.7 <1.7 <1.7 <1.7 <1.7 <1.7 <1.7 <1.7 <1.7 <1.7 <1.7 <1.7 <1.7 <1.7 <1.7 <1.7 <1.7 Carbon tetrachloride µg/l 1.0 0.33 0.3 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 Chlorobenzene (mono) µg/l 1.0 0.28 50 <0.28 <0.28 0.49 J 39.3 <0.28 <0.28 <0.28 <0.28 <0.28 1.3 2.6 <0.28 <0.28 <0.28 <0.28 <0.28 <0.28 Chloroethane µg/l 1.0 0.65 3,000 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 Chloroform µg/l 1.0 0.43 70 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 Chloromethane (Methylchloride) µg/l 1.0 0.54 3.0 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 Dibromochloromethane µg/l 1.0 0.36 0.4 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 1,2-Dibromo-3-chloropropane; DBCP µg/1 2.0 0.34 0.04 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 1,2-Dibromoethane; Ethylene dibromide µg/1 1.0 0.27 0.02 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 Dibromomethane µg/1 1.0 0.39 70 (i) <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 1,2-Dichlorobenzene µg/l 1.0 0.34 20 <0.34 <0.34 <0.34 0.49 J <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 1,4-Dichlorobenzene µg/l 1.0 0.33 6.0 <0.33 <0.33 0.42 J 4.7 <0.33 <0.33 <0.33 <0.33 <0.33 1.1 1.4 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 trans-1,4-Dichloro-2-butene µg/1 1.0 0.56 NE <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 1,1-Dichloroethane µg/1 1.0 0.37 6.0 <0.37 <0.37 <0.37 <0.37 0.55 J <0.37 <0.37 <0.37 <0.37 0.71 J <0.37 <0.37 <0.37 <0.37 <0.37 <0.37 <0.37 1,2-Dichloroethane µg/1 1.0 0.32 0.4 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 1, 1 -Dichloroethene (-ethylene) µg/l 1.0 0.35 350 <0.35 <0.35 <0.35 <0.35 <0.35 <0.35 <0.35 <0.35 <0.35 <0.35 <0.35 <0.35 <0.35 <0.35 <0.35 <0.35 <0.35 cis-1,2-Dichloroethene (-ethylene) µg/l 1.0 0.38 70 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 0.57 J <0.38 8.9 <0.38 <0.38 <0.38 0.60 J 0.49 J <0.38 <0.38 trans-1,2-Dichloroethene (-ylene) µg/l 1.0 0.40 100 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 1,2-Dichloropropane µg/l 1.0 0.36 0.6 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 42.6 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 cis-1,3-Dichloropropene (-propylene) µg/l 1.0 0.36 0.4 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 trans-1,3-Dichloropropene (-propylene) µg/l 1.0 0.36 0.4 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 Ethylbenzene µg/l 1.0 0.30 600 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 2-Hexanone µg/l 5.0 0.48 40 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48 Iodomethane µg/l 20.0 9.7 NE <9.7 <9.7 <9.7 <9.7 <9.7 <9.7 <9.7 <9.7 <9.7 <9.7 <9.7 <9.7 <9.7 <9.7 <9.7 <9.7 <9.7 Dichloromethane (Methylene chloride) 99/1 5.0 2.0 5.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 2-Butanone (Methyl ethyl ketone) µg/l 5.0 4.0 4,000 <4.0 <4.0 <4.0 <4.0 <4.0 <4.0 <4.0 <4.0 <4.0 <4.0 <4.0 <4.0 <4.0 <4.0 <4.0 <4.0 <4.0 4-Methyl-2-Pentanone 99/1 5.0 2.7 NE <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 Styrene µg/l 1.0 0.29 70 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 1, 1, 1,2-Tetrachloroethane 99/1 1.0 0.31 1.0 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 1,1,2,2-Tetrachloroethane 99/1 1.0 0.22 0.2 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 Tetrachloroethene (-ethylene) µg/l 1.0 0.29 0.7 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 0.57 J <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 Tetrahydrofuran µg/l 110 3.5 2100 (1) 0.5 05 NT NT NT NT NT NT NT NT NT NT <30 0.5 <3.5 <3.5 0.5 Toluene µg/l 1.0 0.24 600 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 1, 1, 1 -Trichloroethane 99/1 1.0 0.33 200 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 1,1,2-Trichloroethane µg/l 1.0 0.32 0.6 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 Trichloroethene (-ethylene) µg/l 1.0 0.38 3.0 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 0.69 J <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 Trichlorofluoromethane 99/1 1.0 0.30 2,000 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 1,2,3-Trichloropropane 99/1 1.0 0.26 0.005 <0.26 <0.26 <0.26 <0.26 <0.26 <0.26 1.6 <0.26 <0.26 <0.26 <0.26 <0.26 <0.26 <0.26 <0.26 <0.26 <0.26 Vinyl acetate 99/1 2.0 1.3 88(i) <1.3 <1.3 03 03 03 03 03 03 03 03 03 03 03 03 03 03 0.3 Vinyl chloride µg/l 1.0 0.39 0.03 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 Total Xylenes µg/l I A 0.34 500 <0.34 <aM <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 0.40 J <0.34 <0.34 <0.34 1,4-Dioxane l 2.0 0.86 3.0 <0.86 18.9 <0.86 119 3.4 31.8 <0.86 <0.86 <0.86 <0.86 15.8 2.0 <0.86 <0.86 2.6 1.5 J <0.86 Notes.• 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable to Groundwaters of North Carolina, Section 15A NCAC 2L .0202. Amended Eff. April 1, 2022 2. (i) = Interim Maximum Allowable Concentrations (IMACs). Updated January 18, 2024 3. Shaded cells indicate exceedances of IMACs 4. Shaded cells indicated exceedances of MCLs 5. NE = Not Established; North Carolina has not established a MCL 6. RL = Reporting Limit 7. DL = method Detection Limit 8. NT = Not Tested 9. NS = Not Sampled 10. "J"-flagged data (i.e., values estimated between the DL and the RL) are presented on this spreadsheet. 13657-06 GW Tables (Completion, water levels, detections) T4 (11-20-23) VOC Prepared by: RLB Checked by: TAO Table 5 Groundwater Field Parameters,Total Metals, and Other Parameters Rutherford County Landfill Rutherfordton, North Carolina Permit No. 8103-CDLF-2002 Permit No. 8103-MSWLF-1974 BLE Project Number J23-13657-06 Sampled by Pace Analytical Services, LLC. November 20, 28, & 29 2023 Background Well Compliance Wells TEST UNITS RL DL MCL MW-2 8.4 MW-3 MW-4 MW-6 MW-7 MW-8 MW-9 MW-10B MW-10C MW-10D MW-11A MW-11B MW-12 MW-13 MW-14 MW-15 MW-16 pH s.u. - <6.5; >8.5 6.4 6.5 6.5 6.4 5.9 5.5 5.7 6.1 6.1 q1 6.6 5.8 6.2 5.5 5.7 5.5 7.4 Specific Conductance µmhos/cm - NE 84.2 760 558.7 1,671 927 842 46.1 116.3 103.1 350.1 928 188.9 433.7 171.8 272.3 173.7 664 Temperature °C - NE 17.6 15.3 15.4 16 15.5 14.6 16.6 15.8 16.2 15.5 15.7 16.8 11.3 18.0 14.9 15.8 12.8 Turbidity NTU - NE 50.1 251.8 24.4 7.2 3.7 9.5 5.3 2.2 9.0 1.1 7.5 2.1 3.7 0.7 4.1 9.3 4.2 Alkalinity mg/l 5.0 5.0 NE 44.2 435 NT NT NT NT NT NT NT NT NT NT 247 81.7 89.5 52.1 390 TDS mg/1 25 25 1000 52 505 NT NT NT NT NT NT NT NT NT NT 265 112 176 116 417 Chloride mg/l 1.0 0.6 250 1.2 30.7 NT NT NT NT NT NT NT NT NT NT 6.6 3.5 8.7 8.0 6.1 Sulfate 1119/1 1.0 0.5 250 <0.5 34.9 NT NT NT NT NT NT NT NT NT NT 5.2 <0.5 46.0 21.4 5.4 Total Aluminum (Al) µg/1 100 10.3 NE 529 2,060 NT NT NT NT NT NT NT NT NT NT 118 <10.3 66.5 J 1,840 35.8 J Total Antimony (Sb) µg/1 5.0 3.6 1.0 <3.6 <3.6 <3.6 <3.6 <3.6 <3.6 <3.6 <3.6 <3.6 <3.6 <3.6 <3.6 <3.6 <3.6 <3.6 <3.6 <3.6 Total Arsenic (As) µg/l 10.0 2.5 10 <2.5 <2.5 <2.5 <2.5 <2.5 3.3 J <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 Total Barium (Ba) µg/1 5.0 0.79 700 19.9 192 115 234 106 283 56.9 57.7 121 182 116 94.5 103 132 136 110 81.3 Total Beryllium (Be) µg/l 1.0 0.16 4 <0.16 0.19 J <0.16 <0.16 <0.16 <0.16 <0.16 <0.16 <0.16 <0.16 <0.16 <0.16 <0.16 <0.16 <0.16 <0.16 <0.16 Total Cadmium (Cd) µg/1 1.0 0.29 2.0 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 Total Chromium (Cr) µg/l 5.0 0.63 10 3.8 J 4.2 J 3.2 J 0.87 J 13.9 2.8 J 0.72 J <0.63 <0.63 1.3 J 3.8 J 1.3 J <0.63 <0.63 16.6 <0.63 Total Cobalt (Co) µg/1 5.0 0.44 1.0 <0.4 <0.44 <0.44 19.4 0.93 J <0.44 <0.44 <0.44 <0.44 12.2 0.49 J <0.44 <0.44 3.0 J <0.44 <0.44 <0.44 Total Copper (Cu) µg/l 5.0 0.62 1,000 1.7 J 4.0 J 6.7 <0.62 1.2 J <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 4.6 J <0.62 0.71 J 3.1 J 0.64 J Iron (Fe) µg/1 50.0 8.9 300 1,610 5,560 NT NT NT NT NT NT NT NT NT NT 226 1,780 78.2 2,330 3,470 Total Lead (Pb) µg/l 5.0 1.4 15 <1.4 <1.4 7.8 <1.4 <1.4 <1.4 <1.4 <1.4 <1.4 <1.4 <1.4 <1.4 <1.4 <1.4 <1.4 <1.4 <1.4 Total Manganese (Mn) µg/1 5.0 0.86 50 21.5 375 NT NT NT NT NT NT NT NT NT NT 82.8 1,180 78.3 143 2,110 Total Mercury (Hg) µg/l 0.2 0.12 1 <0.12 <0.12 NT NT NT NT NT NT NT NT NT NT <0.12 <0.12 <0.12 <0.12 <0.12 Total Nickel (Ni) µg/1 5.0 0.88 100 8.1 4.5 J 5.2 18.00 4.0 J 9.1 1.7 J 1.11 1.3 J 4.7 J 3.3 J 1.6 J 1.6 J 4.7 J <0.88 9.9 <0.88 Total Selenium (Se) µg/l 10.0 4.1 20 <4.1 <4.1 <4.1 <4.1 4.4 J 4.3 J <4.1 <4.1 <4.1 <4.1 <4.1 <4.1 <4.1 <4.1 <4.1 <4.1 <4.1 Total Silver (Ag) µg/1 5.0 0.49 20 <0.5 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 Total Thallium (Tl) µg/l 0.2 0.05 2.0 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 0.064 J <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 Total Vanadium (V) µg/1 5.0 1.6 7.0 2.6 J 13.1 11.5 3.3 J <1.6 3.4 J <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 4.7 J <1.6 Total Zinc (Zn) µ /l 10.0 3.0 1,000 6.5 J 11.2 15.6 <3.0 5.7 J 11.4 4.9 J <3.0 <3.0 <3.0 <3.0 5.0 J 4.2 J 3.1 J <3.0 8.7 J <3.0 Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable to Groundwaters of North Carolina, Section 15A NCAC 2L .0202. Amended Eff. April 1, 2022 2. (i) = Interim Maximum Allowable Concentrations (IMACs). Updated January 18, 2024 3. Shaded cells indicate exceedances of IMACs 4. Shaded cells indicated exceedances of MCLs 5. NE = Not Established; North Carolina has not established a MCL 6. RL = Reporting Limit 7. DL = method Detection Limit 8. NT = Not Tested 9. NS = Not Sampled 10. "J"-flagged data (i.e., values estimated between the DL and the RL) are presented on this spreadsheet. 13657-06 GW Tables (Completion, water levels, detections) T5 (11-28-23) Metals Prepared by: RLB Checked by: TAO Table 6 Surface Water VOCs Rutherford County Landfill Rutherfordton, North Carolina Permit No. 8103-CDLF-2002 Permit No. 8103-MSWLF-1974 BLE Project Number J23-13657-06 Sampled by Pace Analytical Services, LLC. November 20 & 28, 2023 TEST Acetone UNITS RL DL NC2B SW-2 SW-3 SW-4 SW-5 SW-6 µg/l 25.0 5.1 2,000 <5.1 <5.1 <5.1 <5.1 <5.1 Acrylonitrile µg/l 10.0 1.8 420 <1.8 <1.8 <1.8 <1.8 <1.8 Benzene µg/l 1.0 0.34 51 <0.34 <0.34 <0.34 <0.34 <0.34 Bromochloromethane µg/l 1.0 0.47 NE <0.47 <0.47 <0.47 <0.47 <0.47 Bromodichloromethane µg/l 1.0 0.31 NE <0.31 <0.31 <0.31 <0.31 <0.31 Bromoform µg/l 1.0 0.34 120 <0.34 <0.34 <0.34 <0.34 <0.34 Carbon Disulfide µg/l 2.0 0.36 100 <0.36 <0.36 <0.36 <0.36 <0.36 Bromomethane (Methylbromide) µg/l 2.0 1.7 0.04 <1.7 <1.7 <1.7 <1.7 <1.7 Carbon tetrachloride µg/l 1.0 0.33 1.6 <0.33 <0.33 <0.33 <0.33 <0.33 Chlorobenzene (mono) µg/l 1.0 0.28 800 <0.28 <0.28 <0.28 <0.28 <0.28 Chloroethane µg/l 1.0 0.65 NE <0.65 <0.65 <0.65 <0.65 <0.65 Chloroform µg/l 1.0 0.43 2,000 <0.43 <0.43 <0.43 <0.43 <0.43 Chloromethane (Methylchloride) µg/l 1.0 0.54 96 <0.54 <0.54 <0.54 <0.54 <0.54 Dibromochloromethane µg/l 1.0 0.36 21 <0.36 <0.36 <0.36 <0.36 <0.36 1,2-Dibromo-3-chloropropane; DBCP µg/l 2.0 0.34 0.13 <0.34 <0.34 <0.34 <0.34 <0.34 1,2-Dibromoethane; Ethylene dibromide µg/l 1.0 0.27 0.1 <0.27 <0.27 <0.27 <0.27 <0.27 Dibromomethane µg/l 1.0 0.39 NE <0.39 <0.39 <0.39 <0.39 <0.39 1,2-Dichlorobenzene µg/l 1.0 0.34 3,000 <0.34 <0.34 <0.34 <0.34 <0.34 1,4-Dichlorobenzene µg/l 1.0 0.33 900 <0.33 <0.33 <0.33 <0.33 <0.33 trans-1,4-Dichloro-2-butene µg/l 1.0 0.56 NE <0.56 <0.56 <0.56 <0.56 <0.56 1, 1 -Dichloroethane µg/l 1.0 0.37 100 <0.37 <0.37 <0.37 <0.37 <0.37 1,2-Dichloroethane µg/l 1.0 0.32 650 <0.32 <0.32 <0.32 <0.32 <0.32 1, 1 -Dichloroethene (-ethylene) µg/l 1.0 0.35 20,000 <0.35 <0.35 <0.35 <0.35 <0.35 cis-1,2-Dichloroethene (-ethylene) µg/l 1.0 0.38 720 <0.38 <0.38 <0.38 <0.38 <0.38 trans-1,2-Dichloroethene (-ylene) µg/l 1.0 0.40 4,000 <0.40 <0.40 <0.40 <0.40 <0.40 1,2-Dichloropropane µg/l 1.0 0.36 31 <0.36 <0.36 <0.36 <0.36 <0.36 cis-1,3-Dichloropropene (-propylene) µg/l 1.0 0.36 NE <0.36 <0.36 <0.36 <0.36 <0.36 trans-1,3-Dichloropropene (-propylene) µg/l 1.0 0.36 NE <0.36 <0.36 <0.36 <0.36 <0.36 Ethylbenzene µg/l 1.0 0.30 97 <0.30 <0.30 <0.30 <0.30 <0.30 2-Hexanone µg/l 5.0 0.48 NE <0.48 <0.48 <0.48 <0.48 <0.48 Iodomethane µg/l 20.0 9.7 NE <9.7 <9.7 <9.7 <9.7 <9.7 Dichloromethane (Methylene chloride) µg/l 5.0 2.0 1,000 <2.0 <2.0 <2.0 <2.0 <2.0 2-Butanone (Methyl ethyl ketone) µg/l 5.0 4.0 26,000 <4.0 <4.0 <4.0 <4.0 <4.0 4-Methyl-2-Pentanone µg/l 5.0 2.7 26,000 <2.7 <2.7 <2.7 <2.7 <2.7 Styrene µg/l 1.0 0.29 NE <0.29 <0.29 <0.29 <0.29 <0.29 1, 1, 1,2-Tetrachloroethane µg/l 1.0 0.31 NE <0.31 <0.31 <0.31 <0.31 <0.31 1,1,2,2-Tetrachloroethane µg/l 1.0 0.22 4.0 <0.22 <0.22 <0.22 <0.22 <0.22 Tetrachloroethene (-ethylene) µg/l 1.0 0.29 3.3 <0.29 <0.29 <0.29 <0.29 <0.29 Tetrahydrofuran µg/l 10.0 3.5 110,000 <3.5 <3.5 <3.5 <3.5 <3.5 Toluene µg/l 1.0 0.24 11 <0.24 <0.24 <0.24 <0.24 <0.24 1, 1, 1 -Trichloroethane µg/l 1.0 0.33 200,000 <0.33 <0.33 <0.33 <0.33 <0.33 1,1,2-Trichloroethane µg/l 1.0 0.32 8.9 <0.32 <0.32 <0.32 <0.32 <0.32 Tichloroethene (-ethylene) µg/l 1.0 0.38 30 <0.38 <0.38 <0.38 <0.38 <0.38 Trichlorofluoromethane µg/l 1.0 0.30 67,000 <0.30 <0.30 <0.30 <0.30 <0.30 1,2,3-Trichloropropane µg/l 1.0 0.26 0.001 <0.26 <0.26 <0.26 <0.26 <0.26 Vinyl acetate µg/l 2.0 1.3 NE <1.3 <1.3 <1.3 <1.3 <1.3 Vinyl chloride µg/l 1.0 0.39 2.4 <0.39 <0.39 <0.39 <0.39 <0.39 Total Xylenes µg/l 1.0 0.34 670 <0.34 <0.34 <0.34 <0.34 <0.34 1,4-Dioxane 2.0 1 0.86 1 80 <0.86 <0.86 <0.86 <0.86 <0.86 Notes 1. NC213 = North Carolina Surface Water Standards for Class C freshwater under Title 15A Subchapter 2B. per NC DWR Surface Water Quality Standards, Criteria, & In -Stream Target Values (Workbook Dated 7-26-2021) 2. NE = Not Established; North Carolina has not established a MCL 3. Shaded cells indicated exceedances of MCLs 4. RL = Method Reporting Limit 5. NT = Not Tested 6. NS = Not Sampled 13 65 7-06 SW Tables Prepared by: RLB T6 (11-28-23) VOC Checked by: TAO Table 7 Surface Water Field Parameters and Total Metals Rutherford County Landfill Rutherfordton, North Carolina Permit No. 8103-CDLF-2002 Permit No. 8103-MSWLF-1974 BLE Project Number J23-13657-06 Sampled by Pace Analytical Services, LLC. November 20 & 28, 2023 TEST UNITS RL DL NC2B SW-2 SW-3 SW-4 SW-5 SW-6 pH s.u. <6.0; >9.0 6.7 6.8 6.5 6.5 7.3 Specific Conductance µmhos/cm NE 81.4 36.8 50.2 77.2 104.3 Temperature °C 29.0 11.9 11.8 11.7 11.7 8.8 Turbidity NTU <50 1.3 1.7 1.3 1.5 3.4 Alkalinity mg/1 5.0 5.0 20 29.5 24.3 14.7 30.2 42.0 TDS mg/1 25 25 NE 1030 50.0 35.0 56.0 83.0 Chloride mg/1 1.0 0.6 230 3.7 4.4 4.0 3.6 5.7 Sulfate mg/1 1.0 0.5 NE 5.5 1.3 <0.5 5.2 2.0 Aluminum (Al) µg/1 100 10.3 8000 63.0 J 35.0 J 71.1 J 66.6 J 59.0 J Total Antimony (Sb) µg/1 5.0 3.6 5,300 <3.6 <3.6 <3.6 <3.6 <3.6 Total Arsenic (As) µg/1 10.0 2.5 10 <2.5 <2.5 <2.5 <2.5 <2.5 Total Barium (Ba) µg/1 5.0 0.79 21,000 33.3 24.4 26.6 33.0 31.6 Total Beryllium (Be) µg/1 1.0 0.16 65 <0.16 <0.16 <0.16 <0.16 <0.16 Total Cadmium (Cd) µg/1 1.0 0.29 0.82 <0.29 <0.29 <0.29 <0.29 <0.29 Total Chromium (Cr) µg/1 5.0 0.63 183.07 0.97 J 0.73 J <0.63 0.65 J 1.3 J Total Cobalt (Co) µg/1 5.0 0.44 16 <0.44 <0.44 <0.44 <0.44 <0.44 Total Copper (Cu) µg/1 5.0 0.62 3.64 <0.62 <0.62 <0.62 <0.62 0.73 J Iron (Fe) µg/1 50.0 8.9 1,000 123 155 126 176 253 Total Lead (Pb) µg/1 5.0 1.4 13.88 <1.4 <1.4 <1.4 <1.4 <1.4 Total Manganese (Mn) µg/1 5.0 0.86 100 4.7 J 18.1 4.4 J 30.2 37.4 Total Mercury (Hg) µg/1 0.2 0.12 0.012 <0.12 <0.12 <0.12 <0.12 <0.12 Total Nickel (Ni) µg/1 5.0 0.88 144.92 <0.88 <0.88 <0.88 1.3 J <0.88 Total Selenium (Se) µg/1 10.0 4.1 5.0 <4.1 <4.1 <4.1 <4.1 <4.1 Total Silver (Ag) µg/1 5.0 0.49 0.3 <0.49 <0.49 <0.49 <0.49 <0.49 Total Thallium (Tl) µg/1 0.2 0.05 2 <0.05 <0.05 <0.05 <0.05 <0.05 Total Vanadium (V) µg/1 5.0 1.6 NE <1.6 <1.6 <1.6 <1.6 <1.6 Total Zinc Zn 1 1 10.0 1 3.0 1 36.20 1 <3.0 1 <3.0 1 <3.0 1 <3.0 1 <3.0 Notes: 1. NC213 = North Carolina Surface Water Standards for Class C freshwater under Title 15A Subchapter 2B. per NC DWR Surface Water Quality Standards, Criteria, & In -Stream Target Values (Workbook Dated 7-26-2021) A hardness of 25 mg/L was utilized to calculate an acute standard at each surface water location for metals highlighted in green. - 2. NE = Not Established; North Carolina has not established a standard 3. Shaded cells indicated exceedances of MCLs 4. RL = method Reporting Limit 5. NT = Not Tested 6. NS = Not Sampled 13657-06 SW Tables Prepared by: RLB T7 (11-28-23) Metals Checked by: TAO Figures OR ,off o PLC 4 Fig ^ ; °oo ° 0 Z ..Saint pti�� Francis Episcopal p ChurchlCem q00 p y 2 West Memonal Church,Cem a 0 13 �� l ' wCOURT ST 21 FzNO,f?c g-r EOo�RTST O o \� \ T H igST \ Bus RYON ��Qv �Ruthe fordt0111 74 oXF �RD Alt } % 0 ST K) © GJ Q o y a yF 2 V e�'A' J �plA CDLIF OF% riR 4q ♦�AJFr ,, 1. .i. ' o Alt 2 J1 �yFDR 0 CouyT�` litter-, o� 1 A PROBER BO oar BusF s m s � o 'Y ° a � J�v O 0 221 A 4TFR 0 r p �1 � hoo 0 goo r rV J �0 O �,� Mounta�m G� View`'Baphst 'Ch ru ch.Cem � oo OQLFN.op � RT�'o o a 1p00 0 I� I REFERENCES: -USGS TOPOGRAPHIC MAP, 7.5 2000 l000 0 2000 4000 a7 MINUTE SERIES, RUTHERFORDTON SOUTH. NC. QUADRANGLE 2017 APPROXIMATE SCALE IN FEET Z�. - DRAWN: KLW DATE: 2-15-24 BUNNELL FIGURE IM LAMMONIS M ENGINEERING 6004 Ponders Court, Greenville, SC 29615 Phone: (864) 288-1265 Fax: (864) 288-4430 SITE LOCATION MAP RUTHERFORD COUNTY LANDFILL RUTHERFORDTON, NORTH CAROLINA CHECKED: RLB CAD: RCLF-06SLM APPROVED: AWA 1OB NO: J23-13675-06 MONITORING LOCATION LEGEND M W-7 854.94 SW-3) LFG-4 M W- 5 D 17 NM STONECUT CREEK THUNDER ROAD LFG-3 s, d n LFG-5 TOWN OF RUTHERFORDTON WASTEWATER TREATMENT FACILITY I. CLEGHORN CREEK Sw-6 O � MW-11B MW-11A 808.39 807.7� M W-6 -.dk- 803.16 CLOSED MSWLF X MW-8 812.80 LFG-2 �_:N4 990 M W- 9 832.43 1 � 10 g70 -860' $~'— �84p SW-23 a2 SW-5 W-3' 25.14; EXISTING CDLF - PHASE 1 TRANSFER STATION MW-13 (B-6) % o �Y-m880.71 0 p0o� N � rn - � 880 `b 920MAINTE0 �� ' � �L1�� G-1 AREAS NANCE STORAGE AND � � MW-10C 826.81 MW-10A MW-10D NM 826.55 MW-1OBti� 826.53 , to DRAWN: KLW CHECKED: RLB/ZJD APPROVED: AWA DATE: 1-26-24 CAD FILE: RCLF-06GWM JOB N0: J23-13675-06 i —IOUSE - e 00' MW-15 (B-29) 851.86 1 ■ EXISTING CDLF PHASE 2 APPROXIMATE FACILITY BOUNDARY LFG-11 BMW-2 \G LFG-8A (B-12D), LFG-10 \ FG-8 (B-12S), o O W O I ^000 ANIMAL / �oP SHELTER FACILITY / 1020 ,1010 O 0 - ° NM 00 0 980 970� IM IBUNNELL � LAMMONS ENGINEERING 6004 Ponders Court, Greenville, SC 29615 Phone: (864) 288-1265 Fax: (864) 288-4430 015 kz�' �r INDUSTRIAL PARK ROAD b" LAUREL HILL DRIVE LFG-9 LANDFILL GAS MONITORING WELL, SURVEYED BY MCGILL ASSOCIATES, 12/2/19 - 12/3/19 FG-5 LANDFILL GAS MONITORING WELL, APPROXIMATE LOCATION MW-8 GROUNDWATER MONITORING WELL, APPROXIMATE LOCATION 3 SURFACE WATER SAMPLING LOCATION, APPROXIMATE TOPOGRAPHIC & GEOLOGIC LEGEND EXISTING 2' CONTOUR - LIDAR/ALS/MCGILL EXISTING 10' CONTOUR - LIDAR/ALS/MCGILL STREAM FACILITY BOUNDARY — — WASTE UNIT BOUNDARY 890 GROUNDWATER ELEVATION CONTOUR IN FEET ABOVE MSL (CONTOUR INTERVAL = 10 FEET) 814.59 GROUNDWATER ELEVATION (FEET MSL) DNA DATA NOT AVAILABLE NM NOT MEASURED GENERALIZED GROUNDWATER FLOW PATH REFERENCES: 1. RUTHERFORD COUNTY LANDFILL GROUNDWATER AND SURFACE WATER MONITORING PLAN FIGURE 2 AND 3 PREPARED BY ODOM ENGINEERING DATED NOVEMBER 15, 2018 2. RUTHERFORD COUNTY LANDFILL GAS MONITORING PLAN FIGURE 2 AND 3 PREPARED BY ODOM ENGINEERING DATED NOVEMBER 1, 2018 3. RUTHERFORD COUNTY LANDFILL - SURVEY CONTROL REPORT AND BORE/WELL LOCATIONS REPORT ID CDO0640 PREPARED BY MCGILL DATED JANUARY 7, 2020 NOTES: LOCATION ACCURACY OF THE FEATURES SHOWN IS LIMITED BY THE REFERENCES THEMSELVES. GENERAL MAP REFERENCE 200 100 0 200 400 APPROXIMATE SCALE IN FEET GROUNDWATER ELEVATION CONTOUR MAP - NOVEMBER 28, 2023 RUTHERFORD COUNTY LANDFILL RUTHERFORDTON, NORTH CAROLINA FIGURE NO. 2 APPENDIX A FIELD SAMPLING LOGS PACE ANALYTICAL SERVICES, LLC. Dotwntcnf Name: Field data t3hcnt Date loved: March 8. 2(n9 page-. 1 of Ce/l►k��ylrCul Duc-ument Number: R•CAR-FLD-Wl-ray.Q'i Inuytg.Au0tority: Pam litwtersvilie Quality Olfke 8 L' SP rr r � Field Data, Sheet Name and Afflliation (Sampler(s): S ' biI 1'_I 4 Namwand Affiliation (inspector): �� Well lnforiiation WeajD: $ 10 i►hw`� Well Diameter: Taal Weit Depth: Gi0_i 6 i5 ft Static Water Level: LM, ft Heiglif of Water Column; ft wL roect#: R Q4hPrPG a Lc -Id Data Sheet Review: Date: By: 0t?A' Well Locked: (T(S,$ / NO / Plushmount ) Construction: I' C/Steel/Stainless Steel) Multi Factor':01163 p(Radiu9/12)2 x 3.14 x.7,01 Casing Volume: - - gallons Cal. a Volumes: •gallons Pump intake: C'ti ft EuMe Inf ion �'' ,, -- Date.Purged: 2 0 / 3 Start: Plhlsh: l'urge.Rate: �-aG 1�t4; !ua rah I SP,v [11zo 123 Purging Method: Mon $0_n � Total Volume Purged: (gallons/0/4 2'S GrJO Sampling nfa o . Date ColIected:_U_AL9 2 Time Collected.-.-._-- (am Sampling. Equipment Used: Mo is ib_0 4 instrument iD; V 2 i 1 11, 5- Battle Type 2 6 r, tn. L 2 x zlr� ML G, Sr L( C� l heserva#ion 1 Analysis Required _TCL/ A i *-g U A it y Sample Temp eq: 1-2 1 ^Time: 1G Turbidity (ntu): �a s 1 ^ Time: ZD Diss,Oxy (mg/L)- 1 Time: Fe 2+ mg/L: r� Time: Specific Cond. (uS): — �Z Time: Res. Cl (mg/Lj/,(pS/L):_- "rime:----- -- Sample pH (s.u.): , Time: Odor:_ �� _ __Time: �. ReDox (mV): 2 a�— Time: Appearance: C;/� Cj i Time:A321nL ReDox (PH value):YSI Proplus +20GMV 2 0 Other: -Time: �~ General/Weather Observatiobel, N A-;+ta t, n�� u f�fi r- hl (sunny to y/rainy) Temp.-6j _rF) Wind Sampler Signature: Date: II 12Q.12 Stabilization Test Time Put'ged Temp. (C) Diss Oxy.ReDox Spec. Cond pH (s'u') Turbidity Volume removed (gallons/t Water level Other (mg/L) s)' (mV) (ntu) (ft) L I G12>3 'k CD`i U Lbj V k ' Ilkqig Lu Docuutcnt'Naute Field Data Sheet Document lssacd: Mwch 8, 2M9 Pagc-,of Z Document Nurntrcr: issueing Authority: aceAr�r�lytrcaf F4CAR-PLI)-MLrev.03 Pace Huntersvilld Quality Office �- 9 py d 6 /zol �3 Client: �-`�'►—hra►-fl���9-1'�---�r--�~�fl•�- `�---' Location-, G f h r- it), IMC Project: Q,. LAt At3r+0 r& -.r, WellID- 11 03 m dV — Z -- Reviewed Date and By: (\ I k Stabilization Test i L- a1 `73 MER 'Alell Diameter -Multiplication Factor' 1 0.0408 1.2 0.0918 1.625 0.1080 z 0.1630 3 0.3670 4 0.65.30 6 1.4680 8 2.6100 Tirner •Turbidity .nd. (US) circle Ohe ��KIM Mr � r ' �.r " l?oCuntcnl Now,. Field data Sheet Rafe Issued: March8 2"9 Ply. 1 o(� CeMaJytrCul' bucnmcnt Nund�or: F CAR FID Otll-rev.0! Issuing Authority: Pace Hlniteraville Quality Mot i , 1) , Field Data Sheet Name:and Affiliation (Sampler(s):- P4UQCL° Name -and Affiliation (Inspector):. Well Information Well Ci3:Vo3~ftil 4z 3 Well Locked; Well Diameter: _ _Z �� _. Construction: :Id Data gheetkeview: y1-II-a3 MEIZ Date: I % IA ;� By: f afA- steel) Total Well Depth; (47,4 it Multt Fktbe.,_.(� I'(Ruliva/12)2 x.3:i4 x 7.481 Static Water Level: 3 SA Q 3 ft Casing Volume: �— gallons Height of Water Column; r03 ft Cal. 3 Volumes: Z gallons Pump Intake: ,j- / — ft &r e.Informatlon Date PtArged:Start Finish: .Purge Rate; �C. A'I s I 4h Purging Method; of Total Volume Purged: i rG (gallons/&/L) Samnlins raformatio Dote Collectet(:4 1_%�O/__,I_F, Time Collected:,��C_ . _ (am,iir Sampling, Equipment used: -Instrument 1D: Y 51 I i W ? 1 1- 5-(3( $vale Type Preservation Analysis Required 1112084 L L f Rn. n> C S Field Meaeurements/Observations Sample Temp VC):, kh 13 Time: 1 �Zw_Turbidtty(ntu): Z-51 & Time: M5 DL%0xy (mg/L): Time: Fe 2+ mg/L:_ _' _ _ _ ._Time: Specific Cond. (US): 76Q,..� Time: Ices. Cl^_._Time: � Sample pH (s:u.): ,Time: Odor._ rVb Time: FL 4�0 RePox (mV):101 i �_ 33me: Appearance. CjordAlllkct'� i�ze: ReDox (EH value)AI ProPlus +200mV Z. iT Other: — f Time: r. � GeneraVWeather Observations • 1 • in-e >° S 4 e T IC 04 1�'+ tAl i 11,i-C (y I'±k (s u Y/ au y/rainy) TempLk_CF) Wind (mph) f 19R wre 5h tII / .3 Sampler Signature:.'-&A4 A Date: Z4 Stabiliaatign Test Time Purged Temp. CC) Diss Oxy. (mg/L) Cond. H (sp.u_) ReDox (mV) Turbidity (ntu) r Volume removed (gallons/&/ Water level (ft) Other f 2 j 3 O p 3z 29 G ggt,� 3 5 I 1 ? C" 6 2 2 ,n3 5 P iv I I Iz01z3 11C16Ariatylical Dcxwnent Name, Field DataSlreLt Document Issued: Mardi R, 2019 Page f2, Docrmrent IVumUvr; Issnelng Aullrority: j r-CAR-VLD-001.rev.03 Pate Huntersville Quality Office Cllent: ki 4! Location: 4, L J,Lo 1� � Project: 1� Well ID: Reviewed Date and By:�l Stabilization Test ACC - [Yell Diameter Multiplication Factor" 1 0.0408 1.2 0,0918 1.625 0.1080 2 0.1630 3 0.3670 4 0,6530 6 1 A690 3 2.6100 Timer i •Turbidity (gallon ml /L) Document Name; r1e1�1 drtta Sh�M bot Issued: March Ii,.2019 I'a ge: 1 of a. e/irt,4lyfical Inauing Auttwiily: Pace t-luntersvilte Quality Document Numtxr, F-CAR-A[D-001-rev.03 Offke Client:�9a L Locatlow Name and Affiliation (Sampler(s): RA- Vao Name and Affiliation (inspector): Well Informs 'on Well.ID U UJ Well Diameter: J1 Total Well Depth: 54' 1 ft Static Water Level: $--044 jt 1-ieight of Water Colunui_I LA. V,ft Well Locked: Construction: [old Data Sheet Review: Date:`) I`4 127 11 ful13 / NO / Frlushmount. ) Steel) Multi Factor': O• Sa r(liadiva/12)1x 3J4 x 7,0l Casing Volume: 14 gallons Cal. 3 Volumes: :1•>' . gituot s Pitntp Intake: Zi, ( cm- ft ', Co • �Cen�14-F-�� I t� Purtke.InformaHon k$45 Date Purged:; a_/_)R__/27, Start: jL46 F,inish:42�_. Purge Rate:_&M_�Lm`A jJVA 1LI�Va3 Purging Method:_ 4.bWA_Total Volume Purged: _'7 300_ (gallons�ml�/i ) Sampling lnfonnatlon � Date Copected: 11 /3? Time Coavcted:__ya=�_ _ (an!/ .19 Sampling 8qulpment Used: _ _ W _ �W& instrument ll) 5 Bottle Type gFon Preservation Va pr--- Analysis Required .�I;t 1.10 61' f TIT01120 p r irl•T1i� � - its � 3,.i�t n �. r Field ea Pen: n bs s �a Sample emp ): �4`I1me; 1 �vC_1 turbidity (nYu): �a- ti, �45c� Dist Oxy (mg/1): Q - Time: - .-Fe 2+ mg/L: ��" r_'fin}e: Specific Corid. (uS): Time: --- -Iles. Cl (mg/ L)/(µg/ L):— . Time: Swupie pH (s.u.): _ _22�0NS Time: � Odor: TfPe: _ i$ ReDox (mV); - _- 5.�R9, t Tunas _ tr250 Appearance: 6XOUL Time:_��r ReDox (i?H value):YSI ProPlus +2011m,V_ SyS.1 Other: General/Weather Observationeu��NQL L4)A ► W1;HVAIti Akl? aO -Wke WmAt- C IQAA-- -a, (Sunny ou /rainy) Temp._(°F) Winc3_`5 (mph) Sampler Signature Stabilization Test Time Purged Temp, (aC) Diss Oxy. (mg/L) Spec' Co . pH (s u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/e/ L Water level (A) Other wr 1. 1,!J 14 tD 5U Y I rr J 1 -1^� NW4.5 S 0 1N'q 15A 6-(01.j lD Y 31101 1 ' u . 3� �I %P$ aws, W Documwt.Name: Documentlssued: M Och 8, 2019 Field Data Shtet Nge!anfa— ��.RMAMWYUWI Document Number: IMPeing Authority: P-CAR-FLD-M.rev.03 face Huntersvl[it Qualily Office r Client:.. Location: rJ4011 V Project: u- WellID:__-_"{t_ ` ^� Reviewed Date and By: Stabllirat an est I�f0.Va2 At�•1 VVQU Dismstar Multi lieation Factor' 1 0.0408 1.2 0.0918 1..625 0.1080 2 0.1630 3 0.367.0 4 0.6530 6 1.4680 8 2,.6100 (us) Jntu) cirde one �mulk1�.1�M,M. - f , =� A t7ocadunf Maw. Field dntn 5(teet Bate Issued: March 8; 20]9 ` Page, ] of _ I.. ACBNhrlylFCal lasuing Authorily: pace Hwotersville Quality r5ocunlenk Neimber: F=CAR-FLD.001rrev.W Office 'Field Uata Sheet Name and Affillation 'K- .Prgjkt #: r Id DataSheet Review: Name and Affiliation (Inspectory —' L 1�1 t17i k'z k-z 3 LDatk-:IVI ?e1I Infvrm�ti t/7 11! 1/Z3 ►Also ID:1Y4'3 � w7 Well L&k.ed: NO / Plushmount.) Well Dlameter: 3 g,7Construction:'&Steel/Stainless Steel) TotalWell.Depth: it Multi-Pactof'-Qlia V(Radlus/12)2x3.14x.7A81 Static. Water Level: fti Castng.volume: gallons Height of Water Column; 'TLI t Cal- 9 Volumes: .gallons Pump Intake: 3 6 rt A,rQ BY: R A)e Pu elnforntAlton A Date Purged: )! I p'q /;' � start:_I L4 Fi.nish: DV Purge Rate: ) OP Purging Method.4f $746 PwMn _Total Volume Purge& Mc2 (gallons/ jPL) Bamla ins information Date (;:ollected:/213/-L�— Sampling Equipment Bottle'Type Time Collected -I iln, I?mervaiion f`,4-03�� 11 Analysis Required _kt}BOA • SX•�7 l -`fi i��D /Z .Field Meadumments/Obseryaiiona _ sample Temp eq: R (� o Time: �5-O Turbidity (ntu): � l Z Time: ) � a 7 Dies Oxy (mg/L): 'Time:. Fe 2f mg/U ' 5 Time: --.. Specific Cond. (us): L Time: Res. Cl (mg/LY(µg/L):. Sample pH (s.u.): Time: Odor: '4-0 Time: Repox (mV): _ � 4' q' Time:... _ --__ -- Appearance: L (IM 'rime:- - ... ReDox (EH value):YSI ProPlus *200tnV 2-b 4. 4-,Other. Time: General/Weather Observations; cloudy/rainy) Temp 5-0—(°F) Sampler Signature Stabilization Test Maw Temp. Digs Oxy, SM. • pH (s.u.) ReDox Turbidity Volume removed (gallons/, Water level Other Putged CC) (mg/L) Con (mV) (Btu) (ft) L is� o. 1 1y�5 s. c? 1 5-00 3 .? I 3 i�-ty1 • S 20 •Y �1� Document.Name: Doeumettt 19sued; March 8, 2019 r7GB Awlyrlcal f'ield Data Sheet ppge� fz-, Ikrcu'inent Number. F=CAR FLO-001.rev.03 Issueing.Authority: Pace Huntc+rsvdle Quality Office Client: Location: k! D N Project: 4(d a XAMorJ'� `�,., L- weli io• Reviewed Date and By: t III!'1* billn Tea i21t/ 23 �+►� I-VoU Diameter QuIti licatiort Factor" 1 0.0408 1.2 0.0918 1.625 0.1080 2 0.1630 3 0.3670 4 0.6530 6 1.4680 8 2.6100 Timer Purged Co.nd. Turbidity(gallons/ Other ram■ ��■�■���� on Lj Xumen( NO= Field data $hcet- Date Issue& Marth:8,2014 GBAik7lyliCal page, 1 of j Document Number: FLCAft_n-001-rev.00.3 Issuing (lutltorlty: Pace Huntersvilid Qua iry office Client; � � I aca Name and Affiliation (SamgIer(ss): J '' Name -and Affiliation (Inspectpr� A1,51t- l information )t-+wI-,'&) Well I . Well Diameter. -- Total Well Depth: 52 - & Ift Static Water :Leve1: nJ ? "71 ft Height of Water Column:_LD_1_ft 3on4 tiCJroject#:AM/W/M Y-�!.P ` Pield Data Sheet Review: bate. 12/iizg By. R+v►a i2f u�.3 D�fc.J Well Locked: { NO./ Flushrnount.) Construction: (I' :C teel/Stainless Steel) MultiPaetor*: r4-/C 3 V(Rediu9jM2x3.14x7ABj Casing.Volume: 3 ' 1 `� gallons Cal. 3 Volumes,, ai ' � s gallons Pump Intake, ft L_ 4" Purge lnIF atian r _ f Date !'urged:/, �- $tart :J a �i Finish: Purge Rate:!_ PurgWg Method: Sf SGL%l3 PAP Total Volume Purged: 2 0(gallons L) Sarngling Inform t on �r-- Dafe Collected.- _ —A 3 Time Collected:_ t-/_ 1 _ 51V40v / Sampling Equipment Used: 5S ��� /QiL.�►!/° lnstwnsnt ID: �. �- --- �✓i5 6 `/� Bottle V, a Preservation Analysis Required � �"�"- /ire �. � � � fop �'� I •. � �'9.'t-� Field Measuremente/Qltaexyations Sample Temp: (OC); If' � Time: i �) � Turbidity (ntu): , � ( Time: �Z Diss'Oxy(mg/L): L ' If Time: Fe2+mg/L;^ �� Time: Specific Coi;d. (uS): 7 Time: Res. Q (rg/L)/(itg/L): Time: Sample pH (e,u.): - Time: Odor: y _ITime: ReAox (mV); II`-t't..( Time: Appearance: G�'� rime: ReDox (EH value):YSI ProPlus t2D mV �- - Other: _. _ Time: General/Weather Temp.Y_r_(°F) Sampler Signature Stabilization Test Time Temp. Diss Oxy: Spec' pH (s.0 ) ReDox Turbidity Volume removed Water Other Purged cc) (mg/L) (u� (mV) (ntu) (gallons/& L level (ft) i+, , .p o-L 106.1 -7-6 D g yS la7.v ,— -- C141 31 4 -9t 15-00 3 I �'�99 q% i� - -7: ;, 9 'fo•4 1.1 0XV0,0400ma.Ffeid data sheet Dete,isaucd:.Merich s..2p79 Paige: 1 of'? t CeA7lytrCa! lkxurotnF Number. F•CAIt-fl D-0�l-rev,09 ImWns Aui4aritp: PecefIunteravitle Quality Offkc /1 L Fi@Id pAjj ahe Pi^; sIIIL L O� Clfent: yiJ Rtvl%PffMiU�t/yCFro t #: 14�•fit�D/�/ Cvw A-i y ^Pield _Location: Name and Affiliation (Sampler(s): J ��Data Sheet Review: Name -and Affiliation (Jnspeckor): N Date. I t/i/ 2 3 By, R fi6 Well Intotion d 1�l j i A Well ID: JWIZZ~ D Well Locked: t / NO / Flushmount ) Well Diameter: Corotructio'n:. (1 C #eel/Stainless:Steel) Total Weil Depth:. 4-7 ' 1 ft Multi Factor':- l'(liadiue/12)2 x 3.14 x 7A8I .Static Water Level:�f 3 ti Vft Casing Volume: gallons Heightof Water Column; 9-0) ft Cut.S:volumes: 5 gallons Pump Intake: !� % ft Purge Informattan q Date Pdrged:�,/�_] : 1 Z �} t Y0.4i ^ y.•wn� Start . 1 b D 0 Finish. lfftl Purge Rate: WE Purging Method: S w fi r4-%'S u ,.N1 Total Volume Purged:(gallons/(9—L) f Mo gamvlinglnformatin�t . DIte Collect¢d:j._/,4 J�O� �r►sr�f Time Collected; a pm} / Sainpiing,EquipmentUsed: S5 5 4-16 kt trument1D:Vf Bottle Type Pre ervation Analysis Required. Ilk X/k I"1r ' M _ n^, — i d S�✓1�' :Z- )' -�W 6 "`" (^LA41 _y ILC L EF Field Measurements/0-iservationa _`` )r�� J Sample Temp (C): I!t- F ,Time: 96� Turbidity(ntu):_ �l ' 7 Time: .- Diss,Oxy (mg/L): Q - Time: Fe 2+ mg/L. " ` Time: Specific Cond. (uS): 4X Time: Res. Cl (mg/Ly(ug/L): �. 'rime• Sample pH (sm.); h Time: Odor:_._ . _ Time: ReDox (mV); t Time: Appearance: G L Time ReDox (EH value):YSI ProPlus +72OOmV ^Other: _ _ Time: General/'Weather tdy/rainy) Temp—)—l-C) Wind &— (mph) Sampler Signature Rfalhitizafinn 'T'PwF Time Purged Temp. C) Diss Oxy. Sic' Cond. pH (s,u,) ReDox Turbidity (ntu) o ume removed (gallons/nrl / Water level (ft) Other ( (mg/L) (US)(mV) i. )0,1 �'1, '� C- 0J H , V iTL oza �j fW ;Lf; fq p3i; 124 Document:Nazne: Document lasuedr Marcli 8, 2M9 Field Data Sheet Nge2af-?-. Docaalept Number: Issueing Authority: ('_'*2ceAnaIy1kaI P-CAR-PI.Daj.rev.03 Pace HuntemVlile Quality Office CIlent: L'- Location; k.l-�wAr-AdT IV -1,G Project: Bkn C17�v+✓� Y„ L /{�- L F, moo- W Well ID: Reviewed Date and By: IV I /1:i A-t\j Stabilization Test IL/I / 23 PA IS i4reli Diameter X2ulti licakioxt Factor• 1 0:04,08 1.2 0.0918 1.625 0.1080 2 0.1630 31 0.3670 4 0.6530 6 1-.4680 8 2.6100 semi I (us) r . i circle one Water level �IlL'sII ����� % � � �■i�s� mil» � • e���� � ✓ � �■�� RM Ills r •_ �i� A = Ir ' �+,���� rp; t o P*�� 00unulnt'ldgmr,- Fieid datO $hcet t 6cument Numbw P-CAR-TtD-0 1-mv.0 �,;nr rf'�►14 Field DaJA SheO _.,4_.,.R rPrAiAkxn .4ic Name-and'affiliation'(Samgler(,)i. Ale 15 Name and Mfiliatian (inspector) . -" ----- b e�,l 1nFormat[on Wel11D• `r1a3~ A+.+✓�_- - - Well Lacked: Well Diameter: -- Constructfon: Issued:' MaYcii 8i 2no Pa e: 1 of l rky>' ceflunWmviII6quality Office a� firLGtr-w-lO [,G9%11- !ld Data Sheet -Review: 1 1izi/ Z3 Date:. t l JA 1 Y3 ()M NO./ Flushmowit Q(pSteel/Skainlm Steel) Total We11 Depth: ' 3.0 ft Multi Factor l-C,/( 3('(9ad1pg/12)2x3.14x7A81 Statlowater Level: Wit. CasingVolume: C9- rd gallons Height bf Water colugtin:_L- �fY_ft Cal. S; Voit chest z - c -7 gallon$ By: N g4- Pump Intake• L L!4 -ft u e In f s ''r� t,L Date Fur ea:. / x / :- ,Start : b. qQ -- - FiWsh-_L5_2L Purge Rate,: f 01 Purging Ml thod: 5L IS 10bt1) Total Volume llurg4d: 8arivlire Inforiiiati"off Date ColltlCtetl:_ �f / �3 . Time Collected; 1 SO Jr jam'1� Sampling i.quipment bsed:'27!5146 Pn/tli . tnstrumentM V Bottle Type Pre¢ervation Analysis Required M� GNfk Y ° '�` 3 +il n�R,�s, tv t:a -t!J 717X+ MAIti2 4n x `3 _ 11-G1 - uLF IWI Vd C SampleTemp,eq: Time: �� Q Turbidity (ntu): S Time: Diss-Oxy. (mg/1-,):. Time, Fe 2+ mg/L: NOD Time Specific Cond. (uS): Time: Res. el (mg/LV(µg/L):. Time Sample pH (s.u.): `? 7 Time: Odor.--- T-- ti>7 _ TTime L +C1 Re1�ox (mV). (�� t Tune: . APFMAItce. ,. Tune._ ReDox(BHvalue):YSIProPlus+200rnV i i• (_ Other: ' -_Time:, General/Weather Observations; ain Temp. ff) Wind b T (mph) Sampler Signature Stabilization Teat 'Time Purged Temp. VC) Diss Oxy: (mg/L) Spy' on pH {s.u.) ReDox (mV) Turbidity (ntu) o ume removed (gallons/t L Water level (ft)(us Other q I tp — r 0 0 A 57;_ I Lt . 2 N 0 17i7 r. 3 y I qvo f 15' - �E - 5 3 I fl ? S- 2- A, lk,cun�ertt..Pi6A11eRt Fhbe T�surd: Msgrh 9. 2M9 Page: 1ofL �• OwwTo cmt Nuffib iF;CAR }III-rrrA# inui'$ Aukl,nxktyr Parr I iunkrrawil leOn lily QtTJ4Y Natnc and Affiliation Nowt and AfflioNon lna�ecfiafJr /t ` .--.- willinfonnatLnn "UY IL),_Crr 4 - ! ilr F Total tYW [Depth; _ ={� � .-_-rft stftdE dater z evel: ° ft 11vislit of watee Cpluui.rt; 7 14 Wvrli Ur WL. c0f0tructkAv Field Da id Sheet Rvvkema [I f �r,1 Oak: ��J,j � 'b � f Flulhrrtautlt } 5 kfl�tlbE!I�E.i7 casing Volume, �alions �Ri�y*e_ 214fux=nBti oT1 1>, Lo Datetmrt w. .��PuE liAie � A,r#s Purging Melhpif:-rat l_ ell} ToW VOLu=Poseed- _ �V_ 0 , . .(galkaa*lr l.} ftIMI i n% iriEormalian J%tp C's,llected, h jlw ) Time Cu lerted: � 0,%/49 5smplingSquipment Used: AP4,09 1 104/ f ltutruritCnt M_ (( q?rv%!° - J f 'NoMeTy" rMservalion Analpie Required Pv Field Mea�ure�mrnta�(3baerualior 5aIxlpleTemp(° ):-ry_- ,. .� '��x8:� '` .TLUb1d1tyjrt4u): - .'T`iu,e;_. � OiwOxy (nt L)z 'Liu1C. Fe2+ p►g(l.:_ ' 'IiLme: 5peciflc Car�dF (u5): � • � 7ioae; Res. CI (uxS,�i.•;�{l�g�'4)� _ Titne�. - - Saxnpie Odor, - -.-... � �Tia►e: . 1tePux (Mv): Time: Appeamwe: _-- ... � wire' ReUnK (8H alue),YSF "Iu f lOkl1 L]fj r= TWIM, .......__.. Gemral jetlher C?vetlnn&' ,T 1�14t1��['�ou�]► + �k1 JCI�a.�i°�} ind�q : � .(rnQb} HsniplerSignature:�-- Stabilization't"esl G urne Time Temp,i3 DissQxy. Lnci- nd pH (s,u-� XeDDx Turbfdily r4twYed wRter Other f�seged -� CC) (wg fL) (u5} (MV) (r") Wonss f Iruel (£Y) � L 0 + F� J •7 1000 f) I J ` C? 3 I�mont Nome tttrld data Sheet' grte'Issetedi March.8, 2019 Pm e. I a uBA1,�1yi�G71 DocunienR Number; T+•EAlt=1:S.D•901-rpv,ai Isauing Authoritr Ace Huntersville Quality Off�4 I5 CA . . ,.,.� Name and Affiliation (5arrtp er{s}: NaRne anti Af#tliatiRtt (lrispeetor):'g' Well lnFgmAibn. Well ID..-' ¢1 (71 Well Diameter• _ Tptal Welt :StatiG(+Vater:l.tn+ei:_�' 3�_ �t Ieightaf'WtiterCoWrtmc�3 ft ,Field Data Sheet. `Well Locked: Consiruction: -id lbata Sheet Review: i 1/7,i/z7 DAte: tk1)103 Steel) Mniti Ftictor-: N9- /G r(1iad1ue/12)2x 3.14 % 7.dsl Casing Vofvme: I • f :�— gallons Chi, 3 Vollittiesi t'f, , ) 4 gaitom Bump intake: / S ft a 4 F Ck•,t-i✓1 L 5 lPo 13y: PM, :D4tepkged. ll -J X / z 3 Start: (10 5. - . Finish: / IV' ftge Rate: �J Purging Metb6`d`-101M1pdA,-10, ,.. _ Total Volume Purged: �O�C> - (gallons/ tls .L) Samn • informaHOA Date Collected-, � _ 12, 9j Z Time Colleetgd ptn): Sampling Equipment Used:. p"t .. _ _ _Instrument 1D:_('LPWY' `i�ZTirh,15 u 'Battle Type �L Preservation .metal" ysis Required �L4SI t' �-0 3 (oho/tio� fir'/'• 1 tir_,L /►,aAl'1R /rt►�';,f . �'"t. >< i _ y.tii"ii�f.... �-6 S1M - r.0 ,Al'.oX9�.i,• .4AGL/KJ_ `t� '"� X 3 F� Fx p -i-LL� - P 1 vOC Field Meaeurementa(0baervations [ G� Sample Temp ("q: , 2 Time: r / Turbidity (ntu); ` ' 0 L7 Time: f %5 Dissbxy'(ztilg/l.}: Tim2: Fe 2+ mg/U. 'lime: Specific'Cond: (itS): � Time.. Res. C1(mg/LY(µg/L):- — Time.: Sample'PH (s,u.):. b- --r _Time: actor: _ 4,4 Time: ReDox (mV).. ILL Time: Appearance: C (AZ 2 Time: ReDox-(1'rR vatue):YSI Pr.oP)us.-t2oOmV 1 yY • f _Other: _ Time: General/Weather Observation (sunny/ u /rainy) Tejt�p.-fic7 CF) Wind�(rnph) SamolerSianature: C 1 n ot-4 _ alhj Date: / /` )- 0- •Z 3 -- Stabilization Test Time Temp. Dias 'Oxy. Spec, pH (s.u.) ReDox Turbidity volume removed Water Other Purged ec) (mg/L) { S) (mV) (ntu) (gallons/a level (ft) !1 )"I f, T 17 G•2 17. 9.z•0 fba .-ir s h 5-�• 2-1-0 - •--• �-- I •t7 1TY 1 11.5 2 - irzD .o s"•3 L0 a.t 1 •3 oQo -711 s5' 15- WS - Pl. •p Lfor7 �?•7 Dmoincul Name: Docunu:ntlssued: March k 7A19 c?f AIk�1J/ iwl' Field Data Sheet Page 1 of ; Document Nipnbqr: is�uutog Authority: F-CAR-FLQ4)M.rev.03 Nce HuntOrsville Quality Office Gient: R Lt fIV%&PPkO LBill.vI y — G #8- Ni n & L J- ,fir Location: ALA Project: i A. w 1-y M L Well ID: fl( o � ~ 144 W / D G -- Reviewed Date at)d By: kNML* t" % Stabilization Test (1 / 2,1 S P 71/ 1lteU Diameter MultiphCatioA Factoe 1 0.0408 1.2 0.0918 1.625 0.1080 2 0.163U 3 0.3670 4 0.6530 6 I A680 8 2.6100 Temp. . . - r . Turbift(00 (nto) ,A1t� Vim►, circle one e man Eno M M r, I I 0 C)ncunreitt.[+{amr. Fielil.daia ShC�t Via. )e lasued: Ma�t]r:$; 2p19 �'� e: 7 of-_� . CBArAalyfrCal. 1opi$ Authority: PaceftunlemVilleQuelity Document Numl;et: F-CAR-FFJ.IMI-mv.(l3 Office FleldData Sheet ea CjfAP dZ L,A !j7V3 ^ A.21A#AA...r»w. .r.r ...... rA _ Name-aind Affiliation (Sampler(a):. J7*� l�'xf' pield Data Sheet lteview: Name and Affiliation (Inspector)::_. - Date: 0f EY: �( Weli I;ttforinatian zJ �. WeIl lo.'" _ �l o 3 . 'Nt W l r7 D. Well hocked: ( -NO ./ Fiushrnonnt ) Well. Diamiiev Constructidnt ( teel/Stainless S'teet) Total Well Depthi gf# 1VIu1t3Pactor*: �G3('(Rrtdius/12)3x3.i4x.7.481 Static WaterLevel: : ft Casing.Volume: �galtons Freight of Water C 1U.d.. is 5��. Yet Cal. 3: Volumes; �!! �(• gEyilons PumpInake:, b� fi ft Purge Information ^t t}rg �/^.�,/ . Sfart : p llj5h: 3 purge hate:J 7 ,pate I' ed• � i-•0 �-� ,i 3 �a 3 �' PurgingMetiro& .Y A4kAM j.*V Total Volume Purged: 26� (galloa6/�S G) 3a»�pllug irlibrntatlon -Pate Collected: lY 1�—.110/x Time Collacted': 1 3 (ani/ Sampling Equipm nt Used: Q 44 u�}'fY4o Pz+^l Instrument ID:'! S� Battle Type` Preservation Ana ysis liequired. LF)-5- 2-0 If -0.3 GOI On bix-0 - 0)0/11. ^4 fyi- s Field MeasuMm_c tslobse_ryatiQns Sample Temp OC): 1 1 Time: 14 v Turbidity (ntu).. Time: . Di6s Oxy (mg/L): brie: Fe 2+ mg/L: tid 'rime: Specific Cond. (uS):.. i .1�0 'rune: Res. Cl (fig/L;y(µg/L): .fine: Sample pH (s;u.): Time: Odor:_- — .- _Time: ReDpx (mV). — - «11 Timer Appel;ance:. - GL6 ._Time;_ r� ReDox (LH value):YSI ProPlus +200mV 60' Other: General/Weather Observations• (sunny/claud Y/GiLTemp., `,�_(°F) Wind 0 !j (mph) Sampler Signature Date: i I - zP -,'- "S - Stabilization Test Time Purged Temp. (C) I Diss Oxy. (n1g/L).PH Spec. Cond. (s.u.) ReDox (mV) Turbidity (nm) o ume. removed ($amens/ r�l / L VVate . level (ft} Other ,0 3 - Ihr 1 9-1'r 4 � v 1 1q. 3 15.4 2 eJ6G., 1.1 I `1 0 CBAiuilyllCal Pm-ument Name: MOO data Sheet Date Issued:, March 8, 2019 Pn e; 1 tl . flocumeM Number FCAR-CAR-rev.03 Issuing Aulltority: Pace H ntersville.Quslity Office V Name and Affiliation (Sanxpler(s): Ih Name and Affiliation (inspector): . Well Informa Well ID; w Well Diameter, r}II Total Well Depth: At Static Water Level• �'ft Heightof Water.CpluMfi-.H--Q�-ft Well Locked: Construction: Ad Data Sheet RZevlew: 111110-3 -olo Date: By: I+IZ+Fit i�1 Steel) Mu1tl Fnctor•:. 0• `t-0l'(Racitus/12)2 x 3.I4 x 7.461 Casing Volume: —(kd_ gallons Cal. 3 Volytmes; [i •' gallotls Pump Intake; -4-Aanki- ft -CQA1?Al vf"- )A& age Infarination Va4 ttrgeci:__�J/ _/ _Start : .Finish: Pru�rge» Rate: (�M htr A Purging Method: n4k!k tal Volume Purged: (gallons Sa.mnliug information Date Collected:_/X/ Y� Time Colloeted:-I—)4�-L_ (am Sampling Equipment Used: !W, ?,�A tLW �-instrumentlD:4� aa140-qw Bottle Type �+L Wh1 Yt 1ly`J5 Field MeasuremenhVObservatlons Preservation Analysis -Required ?�l ? uolo uw 5 •� x VUC. ilbA- groop 3l~M - li -�- oYua4 -.— _. !�ft3nla3 Sample Temp (0q- 15-1 rime. U ,,,_ . `furbidlty (ntu): ��� Time. aY7 --- Dtss 0 fl g/r ), O.LQ_ yTime: �� Fe 2+ mg/L., Tittle: SpecificCgn �u�): n)thA=-. Le: _ices.G(iing/L)/ g/L):~ � Time: Sample pH (s.u.): _ 0-%& Time: ti'� Odor: Time:-- ReDox (mV): 2LL i Time: 1. 115_Appearanc • L WIN ime: S ReDox (EH value):YST Proplus +260MV A(P-, --Other: Time. GeneraT/Weathefr /rainy) Sampler Signature RF�h: N� eFinn 'f`nnf Time Purged Temp. Disc Oxy, Spec' pH (&u.) ReDox Turbidity (ntu) remoyed (gallons/ n�l / Water level (ft) Other (oC) (mg/L) Cond. (mV) 1.1 S • -1 10A a St .� '5-7 C-0. (0- 31 ,. b,, Zwj C): 7• 3ona ,Ct lade k,54 0-w `1a.�- LP.ur 4b, -j W-4- 44 = 6--1`T Doniment Nair. Flelddnin Shcet Date Issued: March S, 2019 t Pa .. 1.00 ACBAllnlyNCr!' fhx umenl Nugtber. RCAIt-FI.p 001-rev,03 IssokiS Aulhority: Pace Huntersville Quality Ofte Nameand Affiliation (Sampler(s)• UK" - Name and Affiliation onspeator): Well lnf rmation Weu 1D: 1JC��- L Wep Diameter: 3VL Total Well Depth: )ALko ft Static Water Level:_ _ q 1 t Hetg(t of Water-Column:_yt Well Locked: 614�rfutr�(o.-cenfiruk Field Data -Sheet Review: Date:, i 2-3 llyT �ttoo r,4a PTU. . / NO / Flushinount ) Construction: &/Steel/Sialriless Steel) Multi Ai4ctor": G+tO3 r(Radius/12)2 x:3.14 x 7.461 Casing Volume: I gallons Cal. 3 Volumes: gallons PumpJntake: c1.60.tt- ft rKge Infaratationn t Date Pur& d:__�L/ �S�_/ Start :.. _Finish: Y� aD Purge. Rate: 14 Purging Method: �ECt t�1� [(,� 'total Volume Purged: �� (gallons/&/L) SaMgIMIL-10foringfion: Date Collected: /2/�t�2 _ Tirr�e Collected:_ (am/m Sampling Equipment Uaed:—_ 2 + t instrument ID. Bottle Type Preservation Analysis Require$ Mt U. qlaul? - LLL�r -` MT VOL . tkoM r _ 1jUPr brm - [4 &fd(j Field MeasyremenjgQbjervatiops Sample Temp ('C): �� Timer'[ urtridity (ntu): , _- Time: , \�4-) Dins Oxy (mg/41.O _- Timt':� Fe 2+ mg/L. Time:' Specific Cond. (uS): Tiuie: ,� Res. Cl Sample pH (s.a.): _ '5�_Timc: 13�5 _ Odor:_, 1JQ - Time: _ 1a3 ReDox (mV)c j14j,!? Tfuig:_Appearance: CAeDfwJ'Lk `Z Time: N15 ReDox (EH veiue):YSi ProPlus +204m.V �. 3 Other: '��^' Time: General/Weather Observations• sunny/ ou /rainy) 'femp.,5-1_(°P) Whld k (tnlsh) Time Purged ge Temp: C i°) Dlss.QXy. m L (�l) Spec. Cond, ( pH (s.u.) ReDox mV ) Turbidity ntu ( ) volume removed ailons ( L /i+l Water level ft ( ) Other ILA-1tJn CJ [ 1. Y i -7 a ` � - --- [t. 1, 1-I. b1 1 1 Vko Ot`15 11,10 . 160.La 6, ID 3.1 Mold ]]Rf1. i t,Q v 1 J r` JrVMq tallk� Cst5 •r 1 [dab LU-S 1..i7 1 nt. `t 6�t ltlal9. { a . .? out" -I_-1 zw ate bitted: March 6, 2019 Downient Nam; Field data +hheet Pa 1 of 1 r CBA►471yflGT! Authorily:,lfe: ace Hunterwille Quality ument Number: F-CARM D�001-rev.03 Document Office Name and Affiliation (Sampler(s): Name and Affiliation Well Infornia' do Well ID; W` Well Diameter:' TWO Wen. Depth: -.. _a•3'S ft Static Water Level: ft Height of Water:Column: 10.E it Well Locked: Ca oft"m% "o Field Data Sheet Review: IZ`1 _2'3 d Date. 1I J 1 i 7,3 By: / NO / Flushmount ) Construction: (n/Steel/S(ainless Steel) Multi Factor": 0- (F(Radius/i2)2a3.14 x 7.461 Casing Volume. 1,w gallons CA]. I Volumes: 14 Z ._ gallons Pump Intake: _53. C1n& -- ft Purge InuforLnation &}--) Date PurSd:—ML/-g /—)�t _ Start :—Lg5D— Finish: Purge .Rate:111* ,1 Purging Method: (�SU)n . .Total Volume Purged: IOCD (gnlIonsj�L) Saar 1g_igg Information Date Collected:.._ f/ ' Time Collected:15.nt) 1 (am/ Sampling Equipment Used: d Instrument ID: Bottle Type Neservatlon Analysis Required i, c k,7, ^moo rvC - - 5 uc�c. T05 T � M-4- -- � Q Av. �r� G vittl5 t`L L VOL a- 50Ift W&WC 1AkP WOO I coat, P'1'}76 - A?p k Nzk05 Field s re n Obse atio s Sample Temp (°C): 1'ime. MO rurbidity (ntu): 3,? Time:._ Digs Oxy (mg/L)s T-U► ie: �kOPe 2+ mg/L., Specific Goad. (uS). 14133.i Time: M __ Res. Cl (mg/L)/(µg/L):.. Time: ' Sample pH (s,u.): �� k Time: Vik) Odor: ReDox (mV): )lA3.7-7 Time: i50 Appearance: LrEl1Uf�' 'ime: 15td ReDox (EH value):YSI ProPlus +200mV Other, General/Weather Sampler Signature Stabilization Test =Time- cloudy/rainy) TempA-1—CFj Time Purged Temp. CC) Diss Oxy. (mg/L) Spec' Cond. pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/&/ L Water level (ft) Other Nf�- 11,22 a, a .� taocunieet Nanw: Field data Sheet Date issued: Merrh 8, 2019 Page: i AL ceArhalyfica! Dmument Number: F-CAk-FI.D4)01-rev.M InuGng Autl%ority-.Puce Hunlersviil#Quality offwe Name and Affiliation Name and Affiliation Well Inforniation Well ID: ` 13 Well Diameter.. _ p9�t l� TQtat Well Depth: }v� �-�0€t Static Water Level; __mil �_ (o ft Height of Water Coluuhtt:..!8 LN._ft raeiu uara Knee CC-- [on..tA� er' 0 0A C Project #: to A(i A Cc, Field DataSheet R.J'I : Spy Date: �� (a,1 � } By: Well Locked: � NO / Plushmount ) Construction: (fDStecl/Stalnless Steel) Multi Factor":. JL 1r(9adius/12)2x3.1¢x7.A8j Casing Volume: 13�6 gallons Cal. 3 Volumes, -_I v gallons Pulnp intake: SS-0 —it Ptuge Information �1� I' �L Date -Purged: l l .i�Q_/. X3 .Start : I q .. Pihish: IH50 Purge Rate- Purging Method: /AeQa P 10600A. _______ Total Volume Purged: '1 0� �U (gallons n L) Cer+�ru 11-F Safnllax Information Date Collected:/24 Time Coileeted: H 555 (am/0- y Sampling Equipment Used:�a MOf15 D.8 . instrument ID: r7 0 Bottle Twe Preservation 1903 _ UvtOEM. ra v,Q 5 . Ck Sample Temp (C): Time:1!; Turbidity (ntu): 02^ Time: _I H 55 piss Oxy (mg/L): Cp Time: H 55 - Pe 2+ mg/I : H.10 Time: i 55 Specific Cond. (uS): _ I?ir� —Time:. 1'455 Res. Cl (mg%LY4tg/L):, _- . _ 'rime: Sample pH (sm,): Time: 1 H 55 Qdor: Iq 1 _ Time I 1455 ReDox (mV):. , �, Time:I 55 Appearance:- G Time: Rei)ox (EH value):YSI. ProPlus +200mV_A0, Other: Time: General/Weather Temp,5 Sampler Signature: - Stabilization Teat Q Time r. M . MM ` ; ARM : ►+ Mxfl© . aceAr�7lytrcal Dacument.Name: Re1d DatEt5tteet Documeit Issued: Maych 8, 2019 Peg46f V DkWunWnt Namogr Issueing AutImity: F-CARAM-dmrev,4 Pace HunteroviHe Quality Office Client: vv Loc9tion: AL Project: A Co, — CeAfiI I- F 423 Well 10: } D3 -A W.-13 Reviewed Date and By: k IA i A W & Stabilization Ig f/ Z I P Z-i S P tl Well-tkarnetar MultihCaHon FACtor" 1 0.0408 1.2 0.0918 1.625 0.1.030 2 0,1630 3 0.3670 4 0.5530 6 1.4680 3 2.6100 Time Purged am' Cond. Turbidity ., drde one a Em •® i • . I . r w MMI I�oainrent N°mr: Fic1d. dola Sheet Dgle Fasued:. Moth 8, 2019 Page: 1 of! aceatnryrrca! Issuing Aulhadly,: Pace Hunler6ville'Quallty Ducpment Nuntber F-GAR-Fid>-001-ray.03 Office Name and Affiliation Name and Affiliation (Inspector): Well Inf m Welt ID: _ NAl_._____ Well Diameter: �► Total Well Depth: 3�. DU t Static Water Level, 1)5,W ft Height of Water Column:- UAk _ ft v-LQ Well Locked: Construction: Data Sheet Review: Date: Flushmount ). finless Steel) Multi Factor*. Ad i"(itadfua/12)2 x 3.14 x 7.481 Casing Volume: ,, q gallons Cal. 3 Volumes: galiorui Rump Intake: 3a„CD ":} _ft (Djavt a -20)r,.) J14 By: AIX,� Purge Information Purge Rate: Of7N . LCA Sri Purging Method: TLC b k ih C Total Volume Purged: M _ (gallons/ n)/L) .Saml2liB&h#QMatj§n Date Collected:_ Ak_/, aLl Time Collected Sampling Equipment Used:_.. . �� 3iZ instrument ID: 5 D Bottle Type Preservation Anslyais Required to WV, cptu,r *g wd�> Z" S1M -1,.194juao Field Measurementa/Obseryationa Sample Temp (°C): 14-!j_Time:_L7D6 Turbidity (ntu): _�-- ---Time:. _ 1307 Diss.Oxy (mg/L): .,a -CZ _ Time: 1-305 Pe t+ mg/L: � --Time: Specific Cond. (uS):.._. Timer Res. Cl (mg/L)/(ug/L):Tf _ Tune - Sample pH s.u. Time: ( Odor. W7 Time:. i ReDox (mV): Time: L�V7 Appearance. ReDox (RH vttlue).YSI ProPlus +200mV q.$ Other: Time: General/Weather Observations: /cloudy/rainy) Temp.Aj..._(*9 Sampler Signature Stabilization Test Time Purged Temp. (°C) Diss Oxy. (mg/L) Spec. Cond. (A pH (s.u.) ReDox (mV) Turbidity (ntu) o ume removed (galIans/Q� L Water level (ft) Other �, a • r s, � � � ��e� ai9o� laocament Name -Field data Sheet Data•, Issued: Marth 8, Zn9 i'a Bell 1 of ( eeAm441C !' b.munaent Number: P-C"-FIM-001-mvAs Isauing Aulhorlty: face Hunteraville Quality Office LS P [v t14.Field Client _ T _ :r. r _ O Loeaiion: P �i 11n At Profert #: d Name and Afflliation (S,a►npler(s):. S p u) / C1 Field Data Sheet Review: Name=and Affiliation (Impector): 11-2k-11 MF,�L Date: dial 113 By: paw_ VV�It Information Well ID: _ !R I r� , �0W `.4 t Well Locked: ( / NO / kishmount ) Well Diameter: Constructions (l/Steel/Stainless Steel) Total Well Depth: 3 19 (a it Multi Factor':_ r(Itadlua/12)2x 3.1d x 1A81 Static Water Level: rI 63 ft Casing Volume:-Q. 3 l gallons Height of Watet Cdlurtirt:k wft Cal. 3-Volumes: Q j9Y gallons Pump Intake: t L— ft Purge Information Date Purged: I ". 2[3 I..>� Start :_Q_CLEY,,,.. Fftvsh: 10 10 Purge Rate: l b f/A., Purging Method: N G A �c2p A Total Volume Purged: LI SO (gallons/19/L) Samnlintr information I?ate.Collected:-,/ W/- 13 Time Collected: � O�a /pm) r Sampling Equipment Used: 1� �?�1�'LQ_ji Instrument ID: '�! S 2 l G ti 1 T A(L 13 i Bottle Type Preservation Analysis Required 2 X tnhc Kan 1 _(,Asa d 1+ Y Field. Measurements/Observations Sample.TBmp (C): 1 � t '� Time:0 '[ urbidity° (ntu): f Time: Diss Oxy (mg/L): Time: Fe 2+ mg/L-. 1 Time: Specific Cond. (uS): 7.3dTime: Res. Cl (mg/L)/(pg/L): ^ 'rime: ---� Sample pH (s.u.): . Time: Odor:_ Time: _ 10 1 T ( ): s - p� J C�4 ReDox mV 6 i -Tung: A roue. � rime:, ReDox (EH value):XSI ProPlus +200mV_U4,2._ Other: "~' Time: -^+ / rainy) Sampler Signature Stabilization Test Ph) Time Purged Temp. (C) Diss Oxy. (mg/L) Ste' pH {s'u') RePox (mV) Turbidity (ntu) Volume removed (gallons/ I L Water level (ft) Other LOQQ1 St, t -Z T } CZ10 a 1 Dw Issued: March 8, 2419 Dwiment Nanie: Field dainShwl l'a e: 1 Of s aceN>�lylrcar' Issuing Aulhority:Pace HuntersvilleQuAlit'y Document Number. F-CAR-PI-D-001-rev,03 Office CD. GQ10MI Name and :Affiliation (Sampler(s): tl Flield Data Sheet Review: Name and Affiliation (Inspector).T_-..-- J ..-- Date: 1 2^ 1` 2 S By: y Well Information 12) l(a,_1 1VA Well ID: , 710—MW A Q Well Locked: / NO / 14uslimount.). Well Diameter: _ '211 Construction: (2)�/Steel/Stainless Steel) Total Well Depth: it Multi Factor*. Q, kW [$(Radios/'i2)z'x.3.14 x 7.48] Static Water Level: jt Casing Volume: t o gallons Heightof Water Ct luirk t,t?i ft Cal.9 Volumes:. 5-• _ 011orw Pump Intake: S cr7 . o'- ft PHEse laiRmflon DAtePt0ged._JA_--/ a$ /_A_t_start:Ainish:109 PurgeRate:__7;t_>PjbjMtj Purging Method: Total Volume Purged: kQti '(gallons/L) Sanrulirtg Irtfpimation Date Collected: (� TimeCollected:D 7 a m) Sampling Equipment Used: instrument iD: Bottle Type Preservation Analysis Required ua — i AL - -w�^t� vaa►� Ae q,4wo SkA -tf,-I OtA AA,t��,(�►(ffc13o1ZNrto Qr�o j Field Measurements/Obseryations Sample Temp. CC): Vl:&. Time:A )5 Turbidity (ntu): Time: Diss Oxy (ulg/L): 0,: Titre: _ 1145 Fe 2+ mg/L: Specific Corid. (uS): ^ [ olg!A Time: 11' S Iles. Gi (tag/L}/(µg/L):_^ � Time: r" Sample pH (s.u.):. __ :I. 1A. __ Time: W45 Odor: J6 it Time: , %Q5 ReDox (mV); - L t - Time: �5 Appearance: C Vow k d..- ime: 11 a ReDox (RH value):XSi Proplus +200mV__LLLA_^ Othen "" Time: GeneraJ/WeatUer Observations; ( nn /cloudy/rainy) Temp. (m Wlnd.1:5_(mph) Sampler Signature: Date: 1Aa� Stabilizatinn Teat Time Purged Temp: (°C) Dins Oxy. (mg/L). Spy- on ' pH (s.u.) ReDox (mV). Turbidity (ntu) Volume removed (gallons/i i@/ L Water level (ft) Other „ t071 tit-5.` 10 9?.1 (01 �� -113,� tf�• `� t 1 0. -t 5) 41,%1 ll Zy,,A 0 Dmumapt Namc Field Bala RK-Rt Date Issued: Marah.8, 2619 1'a e: I a CBArk�lyfiCal leauLig Auiitorify: Pare 1 IunlersviE{¢ Quality rkxument Number. F-CAWFLD-00i-tev.Q3 Off-�e Name and Affiliation (Sampler(s):_.j Nwe and Affiliadnit (Inspector)A Well Infivination Well ID: 3I Da _52W —2, Well C? meter. Total Well Depth: _ ft -Static Water Level: A Helpt of Water Coluthn: ft Pleld bat gg Sheet Review: Well Locked: Construction: MultiFoctork: NRadius/92)2x3.107.481 Casing'Volume: gallons Cal. 3 Volumes: = gallons Pump Intake:_ _fit CA C4) — Cen{'aI LP a0 93 By: Nei - forge Information Datel'yiged: _ 5taTt : ___ C�iniah: Purpte Rater Purging Method: Total Volume Purged: (gallons/mis/L) Sam lain$ Infbrmatiom DateCollectdd__11 93 Time Collected-(atri m Ind I Sampling Equipment used: CT I`0 nstrument ID: io69LTP `� r 5�, 6�ui P Bottle Tvve Preservation Analysis Required. q NO3 _Ag I Ni +'a IS UyI pre5. 5. — G loride U �plLS. s r+ G( pP .r V005, Sample Temp (C): �TTinte:_L9KS TurbIdity (ntu): _ -3 Time: L 9 Diss Oxy (mg/t): KID Time: 1 a'6! Fe 2+ mg/l /V Q Time: ) a o Specific Cond. (uS): I. .._ _ Time: I P-o5 Res. Cl (mg/L)/(µg/L):_ Time:--_---. Sample pH (s,u.): �a_ _ _,. Time: PLO odor: ND Time: - j2 ()5 lieDox (mV): Time: 905 Appearance: L g C 4r' Ck hme: 1205 5 Reboz (L+H vaiue):YSI ProPlus +20omV 277 � other: Time: General/Weather Observ#ione 1 PS COO(AML0.k e f 35,3qS Z23) Sampler Signature: 1W yl ILL&k Date: �3 stabilization -Test ^•_ Time Purged Temp. eC) Diss Oxy. (mg/L) Spec. ( pH (s.a.) Belson (mv) Turbidity (ntu) Volume removed (gallons/mis/ L Water level (ft) Other DN � � GJ g � � , �D Vtorument Nam- 14etd data S*t Date Issued: Manth 8, 2b14 a i>ucument Numter: E-t;AR-1:LD-001-mv:03 I'aui^g Autliortty; Pace H.iiu ntenville Quality 1PrZC8M.71yliCRl, 011ice Nameand Affiliation (Sampler(s): -TC Ce. Name and Affiliation ([nspector): AIA Wi11 Inforinatkm WellID:_ Sib3--5J-3 Well, Diameter: Total Welt Depth:.. R Static Water Level:. It Height of Water Colualn: ft Well Locked: Construction: co, !Id Data Sheet l/ ?_1/Z I Review: SPw Date: Ik1A 1)3 By: myh- MultiFactorl —_ . [6(Radius/12)2x3.14x7.481 Casing Volume: _- ---gallons Cal. 3 volumes:_—, _-_ _ _-.. . gallons Pump intake. _ft Pure Information Date Purged, Start : FlWwh: ,Purge Rate` '~^ Purging Method:.-- - ...�"—"" Total Volume Purged:_ T_— (gallons/ ads/ L) — CeE1+i-a I t-F —" 1 a0a3 34mpl1tkz 1nformatlan Date Collecttrd:_(��/�/ 23 Time Collected• a55 _ (aat1ED Sampling Equipment Used: %!`Ab lnstrumentlD: YST#(13 hFW #1565 Bottle Type Preservation Analysis Required o� -2570 NFL-PlAtc Uaa A PP T - --5 L- rn, 0 VAL �1A ie Ckloh 3� 65 a 3- mL a� r- C Its M G� pp � VOL Field Measurerpents/Ober_vations Sample Tomp (Q: 11 S Time: o_ i 5� Turbidity (ntu): 1_ •- � Time: _ d� Diss Ox} (mg/L):� 'Time: �� Fe 2+ mg/Li N D Time: 1 26 Specific Cohd. (uS): Time: �_ Res. Cl (zng/L}j(Ng/L): 'rime: Sample pH (s,u.): �rs Time: �_ Odor: _ N ) Time: C __, ReDox (mV); $a.a Time- .I a55 Appearance: C lear 'rime: I a2,6, ReDox (RH value):YS[ ProPlus +200mV_— .Other.: "-�— Time: ~- General/Weathielr abseroatinnso C:,� CoorUA,, 0< 35z3 W , J 1 9 303 5arnple�i 1tA5� �a�i>nh� 11 ' Ova„Mw�S year' brig, sunny !ou rainy) Temp; 15T °F) Windy"' Sampler Signature: Date: � &-Q Z23 Stabilization Test AR_ No pi++k Time Purged Temp. (eC) Dins Oxy. (mg/L) Sic' bus). pH {s.u.} ReDox (mV) Turbidity (ntu) Volume removed (gallons/mis/ l Water level (ft) Other u111 10.5E, `6 Oo2,0 I Dncununf Nemr:-Plaid daG�;3hcel Date IsSUO March $Wig. gage: 1 of eMalyliCal � Document Num1mr. R-rAR-F1D401-rev.03 issuing Aullwflty: Pate untRmvilldQuglity Name and Affiliation (Saatpler(s): SG M — Name and Affiliation (Inspector}: _ Well Infgrnration We.I11D• � 103 "5W— i Well QlaYneten Total Well Depth: Et Static Water Level:�ft Ffelghtof Water Columt[ ft l?urme wo rmation. CO. !id Data Sheet Review: 5,� I/ zi /.Z3 Date: It DAIa3 By: Nor Weil Locked: Construction[ ) Multi FActor":-.. rotadbAs/1.2)2.;(3.1kx 7A8l Casing Volume: — gallons Gail. 3 Volumes] gallons Pump Intake: ft Mart :inisli `�= .- Purge hate: Purging Method: Total Volume Purged.,__ -' -. (gallons/mis/ L) &Jpt i L_F 121 0a3 $ag�piin¢1:nformaElpt,I Date Cotiected:_L/O-13 _ Time Collected: j o I � am pm) Sampling.EquipmentUsed: Gca I� Instrument ID: .5� 1565 Battle Type Preservation Analysis Required. L c it A r5. � UA Qre5. A a ;A , Ghlorld2 W l b assV��15 s. I �i ahi\e' 3_,iO r - Avn_ r�aSS 10416 G ors Sample Temp. ( q. - 7Time.- a_1 _ Turbidity (ntu); I Time: r Diss Oxy (mg/L); 10.1 Time. S 010. ____ Fe 2+ mg/U.. - .-T�--.-- �W nim(,: Ci Specfftc Cond. (uS). 501 Time. 1010 Res CI (mg/,L)r/Lµg/L):- . Time - Sample pH (s,u.): � .. Time: , I QCL Odor.. - .. f V I) d 1 G . yt� } y Gl_� Time:..._ � � i l� ReDox (rn'V). _. Time: 10.10 Appearance; of +� � Time: 1010 Rebox (RH value):YSI ProPlus +200mV. AIA Veil %cee6I no ya vay M-"r , SntD WO Sampler Signature Stabilization Teat Other: Time: pS ; 35,3552 SS3—�54.g5�1�6�t o sl�na �ar5w, ny oud rainy) Temp._4 (°F) Wind. _(mph) DIA+ • K,0 ft We le — Time Purged Temp. (°C) Disc Qxy. (mg/L) Spec. Cond. S, • pH(s.u.) Repox (mV) Turbidity (ntu) Volume removed (gallons/mis/ L Water level (ft) Other nomwert Nano: Pield data Sheet Date IsLued: Marti6Is, 2019. Ea e 1 of CBAth7VIC81 7 muikwnt Number: F-CAR FI D• 191-Mv.0$ Issuing Aulhorfiy; ace Hunlem.111L Quality Office -6-1.4 n,.c.. CU-6 Ci#ent g Location:+ i+21� A. G Pro Nameand Affillation (Sampler{a) Cf� 1". PaleField Data eet`�ev�ew: Mame<and Afliliatian.(I spector): Liate: We11 Information Well lD: � 46103 -.5w Weil Locked: Well Diameter Construction: ) Total Well Deptb:, ft Multi Pactot': - I+({iadius/ 12)2 x 3.14 x 7.481 Static Water Level.^ Casing Volume: ""� gallons Height of Water Colui»;itt: - f1 Cal. 3 vold7 ies, —�'� gallons l?utnp Intake: ft &Fge Information Date Purged: / Start : Finlsh: Purge Rate: Purging Metho . Total Volume Purged: (gallons/slits/L) 5arnul#ng lttfdrnlatlnn '' �t Date Capected:1L--/ i/__)—,_3 Time Collected: Sampling Equipment"Used: #1565 RntFle T'vne PYeservation 0 U APTS. HCI P Sample Temp { C): 1� : I I Timer 1 �:�S -Turbidity (ntu):. 1. 5. - Time: 1195 Disc; Oxy (mg/L): 1 Time: a5 ire 2+ mgfL:. 0 —'Ilme: Specific Cotnd.(US). 02 Time: Res. CI m L L Time - Sample pH (s.u.): �t . Time: Odor. Time' ReDox(rnv): %7% Time: 119-5 -_Appearance:;Ciw W.1 por lme:^1 I�5 Ret7ax (EH value):YSI ProPlus +20dmV eZ%%. General/Weather nt,ee..,,�s....o.l-,P� rnAr.1).an4ZA 353LAH6 % ~g(.596%817) r�� aMk Fiaa Sampler Signature Stabilization Test rainy) Temp. .{o� Wind 3 (mph) a3 Time Purged Temp. Cq Diss Oxy. (mg/1.) Spec. on . pH (s.u.) ReDox (nN) Turbidity (ntu) volume removed (gallons/mis/ L Water ; level (ft) Other In -7 a 6, Wfe Issued: Marcht 2019 Document Naute: Field (lain Sheet Page. 1 of C8f11tr7lyllG7l Irsu ft Authodly: Pace Hunteraville'Quality- Document Idugiber; I CAR PE.t1I-rev.03 Office Client: C3Lb -. _Locatian:�� Name and Affiliation (Sampler(s):����" Name and Affiliatton (Inspector):. INeII Information Well ID:&_c5) -Q Wall Dlameter: Total Well Dept ft Static W Level:ft H t of Water Column:.___ __-f( �L Project # - . - - o _ -°. G2/I "I j- �Co !Id Data Sheet Review: Date: l 1-1-1 1 B. J 12/1123 y RAS Weil Locked: Construction: ( ) Multi Factor`: I"(A&dlus/14)2x-&14 x 7.401 Casing Volu e: gallons Cal. 3 V limes: __ __ _ gallons P p Intake: ft Em a Irtfo:rmation Date.PurFed- Start:- Khfsh: Purge Rate:_, Purging Method: Total Volume Purged: �.(gallons/mils/ L) .SL MllIg g Infarm'atidn. Date Collected: t4 &I 3 Time Collected: U (am/ m Sampling Equipment Used:. Qztit13 _ Ins►rument ID: W . Mottle Type Preservation Analysis -Required �EtA CAL +,rc LI t}A -CPS]RLKu1w*A.54fblke.GINiA;T"JI "3 � ►Mi f�A mla) .. -Air__ U60D Lk-L-F yvw, rawjw c , gVlay _fb1tiQ -- -� Field.MeauremeaWObservations SampleTemp.ec). Time: _Turbidity(ntu): �J. y Time: k3'5D Dls9 OxY (mg/Q., �jf a Time: Pe 2+ mg/L: - �� Tirtte: "r Specific Coact, (us): l.b�-1.'�, _ Time: X551 Res. Cl (mg/L)/(pg/ L)' 'may Time - Sample PH (5.10: Time:.- Odon h----Time: 050 ReDox (mV): (D. Tune: 26� Appearance lfc:C+ ► t. ime; �O ReDox (EH value):YSI PrOPIU5 +200mV 65W A Other: _ Time: General/Weather ObservationaL3 Sampler Signature a#,.hIIIvA inn'fact .W Time Purged Temp. CC) DissQxy. (mg/L) Spec. (MS) ` PH (s.u.) ReDox (m� Turbidity (null) Volume removed (gallons/mis/ L Water Level (ft) Other Rutherford Co. Central Landfill Nov. 2023 Well ID Static Date Time M W-2 48.56 11/28/2023 840 M W-3 35.14 849 M W-4 36.44 908 M W-6 31.74 921 MW-7 37.76 926 MW-8 47.51 938 M W-9 34.82 945 MW-104 9.62 952 MW-100 9.38 952 MW-100 10.68 953 MW-IV 8.791 911 MW-11E 9.95 912 MW-12 42.25 903 MW-13 81.76 1002 MW-14 25.96 857 M W-15 38.27 847 MW-16 26.31 853 APPENDIX B LABORATORY ANALYTICAL DATA - PACE ANALYTICAL SERVICES, LLC. ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 January 17, 2024 James Kilgo Rutherford County Solid Waste PO Box 1957 Rutherfordton, NC 28139 RE: Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Dear James Kilgo: Enclosed are the analytical results for sample(s) received by the laboratory between November 21, 2023 and November 30, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Mr. Andy Alexander, Bunnell-Lammons Engineering Riley Blais, BLE Corp Accounts Payable, Rutherford County Landfill Director REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 130 Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE SUMMARY Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Lab ID Sample ID Matrix Date Collected Date Received 92699658001 8103-MW-2 Water 11/20/23 13:20 11/21/23 08:00 92699658002 8103-MW-3 Water 11/20/23 15:50 11/21/23 08:00 92699658003 8103-MW-13 Water 11/20/23 14:55 11/21/23 08:00 92699658004 8103-MW-15 Water 11/20/23 10:15 11/21/23 08:00 92699658005 8103-SW-2 Water 11/20/23 12:05 11/21/23 08:00 92699658006 8103-SW-3 Water 11/20/23 12:55 11/21/23 08:00 92699658007 8103-SW-4 Water 11/20/23 10:10 11/21/23 08:00 92699658008 8103-SW-5 Water 11/20/2311:25 11/21/23 08:00 92699658009 8103-MW-4 Water 11/20/23 15:50 11/21/23 08:00 92699658010 8103-MW-9 Water 11/20/23 15:05 11/21/23 08:00 92699658011 8103-MW-10B Water 11/20/23 12:45 11/21/23 08:00 92699658012 8103-MW-10C Water 11/20/23 11:50 11/21/23 08:00 92699658013 8103-MW-10D Water 11/20/23 13:40 11/21/23 08:00 92699658014 8103-MW-11A Water 11/20/23 12:25 11/21/23 08:00 92699658015 8103-MW-11B Water 11/20/23 13:25 11/21/23 08:00 92699658016 8103-Duplicate Water 11/20/23 15:50 11/21/23 08:00 92699658017 8103-MW-12 Water 11/28/23 15:10 11/29/23 08:00 92699658018 8103-MW-14 Water 11/28/23 13:05 11/29/23 08:00 92699658019 8103-MW-16 Water 11/28/2311:25 11/29/23 08:00 92699658020 8103-SW-6 Water 11/28/23 13:50 11/29/23 08:00 92699658021 8103-MW-6 Water 11/29/23 15:05 11/30/23 08:00 92699658022 8103-MW-7 Water 11/29/23 13:15 11/30/23 08:00 92699658023 8103-MW-8 Water 11/29/23 12:05 11/30/23 08:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Rutherford Co Central LF Nov23 92699658 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92699658001 8103-MW-2 EPA 6010D Mil 17 PASI-A EPA 6020E KRL 1 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D LMB 53 PASI-C EPA 8260D Mod. TEG 3 PASI-C SM 2320B-2011 SMS 1 PASI-A SM 2540C-2015 JAY 1 PASI-A EPA 300.0 Rev 2.1 1993 JCM 2 PASI-A 92699658002 8103-MW-3 EPA 6010D Mil 17 PASI-A EPA 6020E KRL 1 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D LMB 53 PASI-C EPA 8260D Mod. TEG 3 PASI-C SM 2320B-2011 SMS 1 PASI-A SM 2540C-2015 JAY 1 PASI-A EPA 300.0 Rev 2.1 1993 JCM 2 PASI-A 92699658003 8103-MW-13 EPA 6010D Mil 17 PASI-A EPA 6020E KRL 1 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D LMB 53 PASI-C EPA 8260D Mod. TEG 3 PASI-C SM 2320B-2011 SMS 1 PASI-A SM 2540C-2015 JAY 1 PASI-A EPA 300.0 Rev 2.1 1993 JCM 2 PASI-A 92699658004 8103-MW-15 EPA 6010D Mil 17 PASI-A EPA 6020E KRL 1 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D LMB 53 PASI-C EPA 8260D Mod. TEG 3 PASI-C SM 2320B-2011 SMS 1 PASI-A SM 2540C-2015 JAY 1 PASI-A EPA 300.0 Rev 2.1 1993 JCM 2 PASI-A 92699658005 8103-SW-2 EPA 6010D Mil 17 PASI-A EPA 6020E KRL 1 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D LMB 53 PASI-C EPA 8260D Mod. TEG 3 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Rutherford Co Central LF Nov23 92699658 Analytes Lab ID Sample ID Method Analysts Reported Laboratory SM 2320B-2011 SMS 1 PASI-A SM 2540C-2015 JAY 1 PASI-A EPA 300.0 Rev 2.1 1993 JCM 2 PASI-A 92699658006 8103-SW-3 EPA 6010D Mil 17 PASI-A EPA 6020E KRL 1 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D LMB 53 PASI-C EPA 8260D Mod. TEG 3 PASI-C SM 2320B-2011 SMS 1 PASI-A SM 2540C-2015 JAY 1 PASI-A EPA 300.0 Rev 2.1 1993 JCM 2 PASI-A 92699658007 8103-SW-4 EPA 6010D Mil 17 PASI-A EPA 6020E KRL 1 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D LMB 53 PASI-C EPA 8260D Mod. TEG 3 PASI-C SM 2320B-2011 SMS 1 PASI-A SM 2540C-2015 JAY 1 PASI-A EPA 300.0 Rev 2.1 1993 JCM 2 PASI-A 92699658008 8103-SW-5 EPA 6010D Mil 17 PASI-A EPA 6020E KRL 1 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D LMB 53 PASI-C EPA 8260D Mod. TEG 3 PASI-C SM 2320B-2011 SMS 1 PASI-A SM 2540C-2015 JAY 1 PASI-A EPA 300.0 Rev 2.1 1993 JCM 2 PASI-A 92699658009 8103-MW-4 EPA 6010D Mil 14 PASI-A EPA 6020E KRL 1 PASI-A EPA 8260D LMB 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C 92699658010 8103-MW-9 EPA 6010D Mil 14 PASI-A EPA 6020E KRL 1 PASI-A EPA 8260D LMB 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C 92699658011 8103-MW-10B EPA 6010D Mil 14 PASI-A EPA 6020E KRL 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Rutherford Co Central LF Nov23 92699658 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 8260D LMB 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C 92699658012 8103-MW-10C EPA 6010D Mil 14 PASI-A EPA 6020E KRL 1 PASI-A EPA 8260D LMB 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C 92699658013 8103-MW-10D EPA 6010D Mil 14 PASI-A EPA 6020E KRL 1 PASI-A EPA 8260D LMB 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C 92699658014 8103-MW-11A EPA 6010D Mil 14 PASI-A EPA 6020E KRL 1 PASI-A EPA 8260D LMB 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C 92699658015 8103-MW-11B EPA 6010D Mil 14 PASI-A EPA 6020E KRL 1 PASI-A EPA 8260D LMB 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C 92699658016 8103-Duplicate EPA 8260D LMB 52 PASI-C 92699658017 8103-MW-12 EPA 6010D DBB1, SBW 17 PASI-A EPA 6020E KRL 1 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D SAS 53 PASI-C EPA 8260D Mod. TEG 3 PASI-C SM 2320B-2011 SMS 1 PASI-A SM 2540C-2015 RVS 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 2 PASI-A 92699658018 8103-MW-14 EPA 6010D DBB1, SBW 17 PASI-A EPA 6020E KRL 1 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D SAS 53 PASI-C EPA 8260D Mod. TEG 3 PASI-C SM 2320B-2011 SMS 1 PASI-A SM 2540C-2015 RVS 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 2 PASI-A 92699658019 8103-MW-16 EPA 6010D DBB1, SBW 17 PASI-A EPA 6020E KRL 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Lab ID Sample ID Method Analysts Analytes Reported Laboratory EPA 7470A BM 1 PASI-A EPA 8260D JJK 53 PASI-C EPA 8260D Mod. TEG 3 PASI-C SM 2320B-2011 SMS 1 PASI-A SM 2540C-2015 RVS 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 2 PASI-A 92699658020 8103-SW-6 EPA 6010D DBB1, SBW 17 PASI-A EPA 6020E KRL 1 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D JJK 53 PASI-C EPA 8260D Mod. TEG 3 PASI-C SM 2320B-2011 SMS 1 PASI-A SM 2540C-2015 RVS 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 2 PASI-A 92699658021 8103-MW-6 EPA 6010D SBW 14 PASI-A EPA 6020E KRL 1 PASI-A EPA 8260D LMB 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C 92699658022 8103-MW-7 EPA 6010D SBW 14 PASI-A EPA 6020E KRL 1 PASI-A EPA 8260D LMB 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C 92699658023 8103-MW-8 EPA 6010D SBW 14 PASI-A EPA 6020E KRL 1 PASI-A EPA 8260D LMB 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-2 Lab ID: 92699658001 Collected: 11/20/23 13:20 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Aluminum 529 ug/L 100 10.3 1 11/22/2311:55 12/08/2318:35 7429-90-5 Antimony ND ug/L 5.0 3.6 1 11/22/2311:55 12/08/2318:35 7440-36-0 Arsenic ND ug/L 10.0 2.5 1 11/22/2311:55 12/08/2318:35 7440-38-2 Barium 19.9 ug/L 5.0 0.79 1 11/22/2311:55 12/08/2318:35 7440-39-3 Beryllium ND ug/L 1.0 0.16 1 11/22/2311:55 12/08/2318:35 7440-41-7 Cadmium ND ug/L 1.0 0.29 1 11/22/2311:55 12/08/2318:35 7440-43-9 Chromium 15.3 ug/L 5.0 0.63 1 11/22/2311:55 12/08/2318:35 7440-47-3 Cobalt ND ug/L 5.0 0.44 1 11/22/2311:55 12/08/2318:35 7440-48-4 Copper 1.7J ug/L 5.0 0.62 1 11/22/2311:55 12/08/2318:35 7440-50-8 Iron 1610 ug/L 50.0 8.9 1 11/22/2311:55 12/08/2318:35 7439-89-6 Lead ND ug/L 5.0 1.4 1 11/22/2311:55 12/08/2318:35 7439-92-1 Manganese 21.5 ug/L 5.0 0.86 1 11/22/2311:55 12/08/2318:35 7439-96-5 Nickel 8.1 ug/L 5.0 0.88 1 11/22/2311:55 12/08/2318:35 7440-02-0 Selenium ND ug/L 10.0 4.1 1 11/22/2311:55 12/08/2318:35 7782-49-2 Silver ND ug/L 5.0 0.49 1 11/22/2311:55 12/08/2318:35 7440-22-4 Vanadium 2.6J ug/L 5.0 1.6 1 11/22/2311:55 12/08/2318:35 7440-62-2 Zinc 6.5J ug/L 10.0 3.0 1 11/22/2311:55 12/08/2318:35 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.20 0.050 1 11/22/23 11:50 11/26/23 23:05 7440-28-0 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Date: 01/17/2024 04:40 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 11/26/2312:56 11/28/2311:07 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 5.1 1 11/30/2317:19 67-64-1 1.8 1 11 /30/23 17:19 107-13-1 0.34 1 11 /30/23 17:19 71-43-2 0.47 1 11 /30/23 17:19 74-97-5 0.31 1 11 /30/23 17:19 75-27-4 0.34 1 11 /30/23 17:19 75-25-2 1.7 1 11 /30/23 17:19 74-83-9 4.0 1 11 /30/23 17:19 78-93-3 0.36 1 11/30/2317:19 75-15-0 0.33 1 11 /30/23 17:19 56-23-5 0.28 1 11 /30/23 17:19 108-90-7 0.65 1 11 /30/23 17:19 75-00-3 0.43 1 11 /30/23 17:19 67-66-3 0.54 1 11 /30/23 17:19 74-87-3 0.34 1 11/30/2317:19 96-12-8 0.36 1 11 /30/23 17:19 124-48-1 0.27 1 11 /30/23 17:19 106-93-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 8 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-2 Lab ID: 92699658001 Collected: 11/20/23 13:20 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) E:Y*-:11]H�46yTAyI�4 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/17/2024 04:40 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.39 1 11/30/2317:19 74-95-3 ND ug/L 1.0 0.34 1 11/30/2317:19 95-50-1 ND ug/L 1.0 0.33 1 11/30/2317:19 106-46-7 ND ug/L 1.0 0.56 1 11/30/2317:19 110-57-6 ND ug/L 1.0 0.37 1 11/30/2317:19 75-34-3 ND ug/L 1.0 0.32 1 11/30/2317:19 107-06-2 ND ug/L 1.0 0.35 1 11/30/2317:19 75-35-4 ND ug/L 1.0 0.38 1 11/30/2317:19 156-59-2 ND ug/L 1.0 0.40 1 11/30/2317:19 156-60-5 ND ug/L 1.0 0.36 1 11/30/2317:19 78-87-5 ND ug/L 1.0 0.36 1 11 /30/23 17:19 10061-01-5 ND ug/L 1.0 0.36 1 11 /30/23 17:19 10061-02-6 ND ug/L 1.0 0.30 1 11 /30/23 17:19 100-41-4 ND ug/L 5.0 0.48 1 11 /30/23 17:19 591-78-6 ND ug/L 20.0 9.7 1 11/30/2317:19 74-88-4 v2 ND ug/L 5.0 2.0 1 11/30/2317:19 75-09-2 ND ug/L 5.0 2.7 1 11/30/2317:19 108-10-1 ND ug/L 1.0 0.29 1 11/30/2317:19 100-42-5 ND ug/L 1.0 0.31 1 11/30/2317:19 630-20-6 ND ug/L 1.0 0.22 1 11/30/2317:19 79-34-5 ND ug/L 1.0 0.29 1 11/30/2317:19 127-18-4 ND ug/L 10.0 3.5 1 11/30/2317:19 109-99-9 ND ug/L 1.0 0.24 1 11/30/2317:19 108-88-3 ND ug/L 1.0 0.33 1 11 /30/23 17:19 71-55-6 ND ug/L 1.0 0.32 1 11/30/2317:19 79-00-5 ND ug/L 1.0 0.38 1 11 /30/23 17:19 79-01-6 ND ug/L 1.0 0.30 1 11/30/2317:19 75-69-4 ND ug/L 1.0 0.26 1 11/30/2317:19 96-18-4 ND ug/L 2.0 1.3 1 11/30/2317:19 108-05-4 ND ug/L 1.0 0.39 1 11 /30/23 17:19 75-01-4 ND ug/L 1.0 0.34 1 11/30/2317:19 1330-20-7 ND ug/L 2.0 0.71 1 11/30/2317:19 179601-23-1 ND ug/L 1.0 0.34 1 11/30/2317:19 95-47-6 103 % 70-130 1 11/30/2317:19 460-00-4 92 % 70-130 1 11/30/2317:19 17060-07-0 97 % 70-130 1 11/30/2317:19 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 11/22/2311:02 123-91-1 90 % 67-130 1 11/22/2311:02 17060-07-0 92 % 70-130 1 11/22/2311:02 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-2 Lab ID: 92699658001 Collected: 11/20/23 13:20 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2320B Alkalinity Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville Alkalinity, Total as CaCO3 44.2 mg/L 5.0 5.0 1 11/29/23 16:13 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 52.0 mg/L 25.0 25.0 1 11/27/23 10:24 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Chloride 1.2 mg/L 1.0 0.60 1 11/22/2311:00 16887-00-6 Sulfate ND mg/L 1.0 0.50 1 11/22/2311:00 14808-79-8 Date: 01/17/2024 04:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-3 Lab ID: 92699658002 Collected: 11/20/23 15:50 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Aluminum 2060 ug/L 100 10.3 1 11/22/2311:55 12/08/2318:47 7429-90-5 Antimony ND ug/L 5.0 3.6 1 11/22/2311:55 12/08/2318:47 7440-36-0 Arsenic ND ug/L 10.0 2.5 1 11/22/2311:55 12/08/2318:47 7440-38-2 Barium 192 ug/L 5.0 0.79 1 11/22/2311:55 12/08/2318:47 7440-39-3 Beryllium 0.191 ug/L 1.0 0.16 1 11/22/2311:55 12/08/2318:47 7440-41-7 Cadmium ND ug/L 1.0 0.29 1 11/22/2311:55 12/08/2318:47 7440-43-9 Chromium 3.8J ug/L 5.0 0.63 1 11/22/2311:55 12/08/2318:47 7440-47-3 Cobalt ND ug/L 5.0 0.44 1 11/22/2311:55 12/08/2318:47 7440-48-4 Copper 4.OJ ug/L 5.0 0.62 1 11/22/2311:55 12/08/2318:47 7440-50-8 Iron 5560 ug/L 50.0 8.9 1 11/22/2311:55 12/08/2318:47 7439-89-6 Lead ND ug/L 5.0 1.4 1 11/22/2311:55 12/08/2318:47 7439-92-1 Manganese 375 ug/L 5.0 0.86 1 11/22/2311:55 12/08/2318:47 7439-96-5 Nickel 4.5J ug/L 5.0 0.88 1 11/22/2311:55 12/08/2318:47 7440-02-0 Selenium ND ug/L 10.0 4.1 1 11/22/2311:55 12/08/2318:47 7782-49-2 Silver ND ug/L 5.0 0.49 1 11/22/2311:55 12/08/2318:47 7440-22-4 Vanadium 13.1 ug/L 5.0 1.6 1 11/22/2311:55 12/08/2318:47 7440-62-2 Zinc 11.2 ug/L 10.0 3.0 1 11/22/2311:55 12/08/2318:47 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.20 0.050 1 11/22/23 11:50 11/26/23 23:10 7440-28-0 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Date: 01/17/2024 04:40 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 11/26/2312:56 11/28/2311:09 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 5.1 1 11/30/2317:37 67-64-1 1.8 1 11 /30/23 17:37 107-13-1 0.34 1 11 /30/23 17:37 71-43-2 0.47 1 11 /30/23 17:37 74-97-5 0.31 1 11 /30/23 17:37 75-27-4 0.34 1 11 /30/23 17:37 75-25-2 1.7 1 11 /30/23 17:37 74-83-9 4.0 1 11 /30/23 17:37 78-93-3 0.36 1 11/30/2317:37 75-15-0 0.33 1 11 /30/23 17:37 56-23-5 0.28 1 11 /30/23 17:37 108-90-7 0.65 1 11 /30/23 17:37 75-00-3 0.43 1 11 /30/23 17:37 67-66-3 0.54 1 11 /30/23 17:37 74-87-3 0.34 1 11/30/2317:37 96-12-8 0.36 1 11 /30/23 17:37 124-48-1 0.27 1 11 /30/23 17:37 106-93-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 11 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-3 Lab ID: 92699658002 Collected: 11/20/23 15:50 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) E:Y*-:11]H�46yTAyI�4 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/17/2024 04:40 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.39 1 11/30/2317:37 74-95-3 ND ug/L 1.0 0.34 1 11/30/2317:37 95-50-1 ND ug/L 1.0 0.33 1 11/30/2317:37 106-46-7 ND ug/L 1.0 0.56 1 11/30/2317:37 110-57-6 ND ug/L 1.0 0.37 1 11/30/2317:37 75-34-3 ND ug/L 1.0 0.32 1 11/30/2317:37 107-06-2 ND ug/L 1.0 0.35 1 11/30/2317:37 75-35-4 ND ug/L 1.0 0.38 1 11/30/2317:37 156-59-2 ND ug/L 1.0 0.40 1 11/30/2317:37 156-60-5 ND ug/L 1.0 0.36 1 11/30/2317:37 78-87-5 ND ug/L 1.0 0.36 1 11 /30/23 17:37 10061-01-5 ND ug/L 1.0 0.36 1 11 /30/23 17:37 10061-02-6 ND ug/L 1.0 0.30 1 11 /30/23 17:37 100-41-4 ND ug/L 5.0 0.48 1 11 /30/23 17:37 591-78-6 ND ug/L 20.0 9.7 1 11/30/2317:37 74-88-4 v2 ND ug/L 5.0 2.0 1 11/30/2317:37 75-09-2 ND ug/L 5.0 2.7 1 11/30/2317:37 108-10-1 ND ug/L 1.0 0.29 1 11/30/2317:37 100-42-5 ND ug/L 1.0 0.31 1 11/30/2317:37 630-20-6 ND ug/L 1.0 0.22 1 11/30/2317:37 79-34-5 ND ug/L 1.0 0.29 1 11/30/2317:37 127-18-4 ND ug/L 10.0 3.5 1 11/30/2317:37 109-99-9 ND ug/L 1.0 0.24 1 11/30/2317:37 108-88-3 ND ug/L 1.0 0.33 1 11 /30/23 17:37 71-55-6 ND ug/L 1.0 0.32 1 11/30/2317:37 79-00-5 ND ug/L 1.0 0.38 1 11 /30/23 17:37 79-01-6 ND ug/L 1.0 0.30 1 11/30/2317:37 75-69-4 ND ug/L 1.0 0.26 1 11/30/2317:37 96-18-4 ND ug/L 2.0 1.3 1 11/30/2317:37 108-05-4 ND ug/L 1.0 0.39 1 11 /30/23 17:37 75-01-4 ND ug/L 1.0 0.34 1 11/30/2317:37 1330-20-7 ND ug/L 2.0 0.71 1 11/30/2317:37 179601-23-1 ND ug/L 1.0 0.34 1 11/30/2317:37 95-47-6 102 % 70-130 1 11/30/2317:37 460-00-4 95 % 70-130 1 11/30/2317:37 17060-07-0 98 % 70-130 1 11/30/2317:37 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 18.9 ug/L 2.0 0.86 1 11/21/23 22:53 123-91-1 91 % 67-130 1 11/21/23 22:53 17060-07-0 95 % 70-130 1 11/21/23 22:53 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-3 Lab ID: 92699658002 Collected: 11/20/23 15:50 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2320B Alkalinity Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville Alkalinity, Total as CaCO3 435 mg/L 5.0 5.0 1 11/29/23 17:16 2540C Total Dissolved Solids Analytical Method: SM 254OC-2015 Pace Analytical Services -Asheville Total Dissolved Solids 505 mg/L 25.0 25.0 1 11/27/23 10:24 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Chloride 30.7 mg/L 1.0 0.60 1 11/22/2311:44 16887-00-6 Sulfate 34.9 mg/L 1.0 0.50 1 11/22/2311:44 14808-79-8 Date: 01/17/2024 04:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-13 Lab ID: 92699658003 Collected: 11/20/23 14:55 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Aluminum ND ug/L 100 10.3 1 11/22/2311:55 12/08/2318:49 7429-90-5 Antimony ND ug/L 5.0 3.6 1 11/22/2311:55 12/08/2318:49 7440-36-0 Arsenic ND ug/L 10.0 2.5 1 11/22/2311:55 12/08/2318:49 7440-38-2 Barium 132 ug/L 5.0 0.79 1 11/22/2311:55 12/08/2318:49 7440-39-3 Beryllium ND ug/L 1.0 0.16 1 11/22/2311:55 12/08/2318:49 7440-41-7 Cadmium ND ug/L 1.0 0.29 1 11/22/2311:55 12/08/2318:49 7440-43-9 Chromium ND ug/L 5.0 0.63 1 11/22/2311:55 12/08/2318:49 7440-47-3 Cobalt 3.OJ ug/L 5.0 0.44 1 11/22/2311:55 12/08/2318:49 7440-48-4 Copper ND ug/L 5.0 0.62 1 11/22/2311:55 12/08/2318:49 7440-50-8 Iron 1780 ug/L 50.0 8.9 1 11/22/2311:55 12/08/2318:49 7439-89-6 Lead ND ug/L 5.0 1.4 1 11/22/2311:55 12/08/2318:49 7439-92-1 Manganese 1180 ug/L 5.0 0.86 1 11/22/2311:55 12/08/2318:49 7439-96-5 Nickel 4.7J ug/L 5.0 0.88 1 11/22/2311:55 12/08/2318:49 7440-02-0 Selenium ND ug/L 10.0 4.1 1 11/22/2311:55 12/08/2318:49 7782-49-2 Silver ND ug/L 5.0 0.49 1 11/22/2311:55 12/08/2318:49 7440-22-4 Vanadium ND ug/L 5.0 1.6 1 11/22/2311:55 12/08/2318:49 7440-62-2 Zinc 3.1J ug/L 10.0 3.0 1 11/22/2311:55 12/08/2318:49 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.20 0.050 1 11/22/23 11:50 11/26/23 23:14 7440-28-0 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Date: 01/17/2024 04:40 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 11 /26/23 12:56 11 /28/23 11:16 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 0.97J ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 5.1 1 11/30/2317:54 67-64-1 1.8 1 11 /30/23 17:54 107-13-1 0.34 1 11 /30/23 17:54 71-43-2 0.47 1 11 /30/23 17:54 74-97-5 0.31 1 11 /30/23 17:54 75-27-4 0.34 1 11 /30/23 17:54 75-25-2 1.7 1 11 /30/23 17:54 74-83-9 4.0 1 11 /30/23 17:54 78-93-3 0.36 1 11/30/2317:54 75-15-0 0.33 1 11 /30/23 17:54 56-23-5 0.28 1 11 /30/23 17:54 108-90-7 0.65 1 11 /30/23 17:54 75-00-3 0.43 1 11 /30/23 17:54 67-66-3 0.54 1 11 /30/23 17:54 74-87-3 0.34 1 11/30/2317:54 96-12-8 0.36 1 11 /30/23 17:54 124-48-1 0.27 1 11 /30/23 17:54 106-93-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 14 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-13 Lab ID: 92699658003 Collected: 11/20/23 14:55 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) E:Y*-:11]H�46yTAyI�4 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/17/2024 04:40 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.39 1 11/30/2317:54 74-95-3 ND ug/L 1.0 0.34 1 11/30/2317:54 95-50-1 ND ug/L 1.0 0.33 1 11/30/2317:54 106-46-7 ND ug/L 1.0 0.56 1 11/30/2317:54 110-57-6 ND ug/L 1.0 0.37 1 11/30/2317:54 75-34-3 ND ug/L 1.0 0.32 1 11/30/2317:54 107-06-2 ND ug/L 1.0 0.35 1 11/30/2317:54 75-35-4 O.60J ug/L 1.0 0.38 1 11/30/2317:54 156-59-2 ND ug/L 1.0 0.40 1 11/30/2317:54 156-60-5 ND ug/L 1.0 0.36 1 11/30/2317:54 78-87-5 ND ug/L 1.0 0.36 1 11 /30/23 17:54 10061-01-5 ND ug/L 1.0 0.36 1 11 /30/23 17:54 10061-02-6 ND ug/L 1.0 0.30 1 11 /30/23 17:54 100-41-4 ND ug/L 5.0 0.48 1 11 /30/23 17:54 591-78-6 ND ug/L 20.0 9.7 1 11/30/2317:54 74-88-4 v2 ND ug/L 5.0 2.0 1 11/30/2317:54 75-09-2 ND ug/L 5.0 2.7 1 11/30/2317:54 108-10-1 ND ug/L 1.0 0.29 1 11/30/2317:54 100-42-5 ND ug/L 1.0 0.31 1 11/30/2317:54 630-20-6 ND ug/L 1.0 0.22 1 11/30/2317:54 79-34-5 ND ug/L 1.0 0.29 1 11/30/2317:54 127-18-4 ND ug/L 10.0 3.5 1 11/30/2317:54 109-99-9 ND ug/L 1.0 0.24 1 11/30/2317:54 108-88-3 ND ug/L 1.0 0.33 1 11 /30/23 17:54 71-55-6 ND ug/L 1.0 0.32 1 11/30/2317:54 79-00-5 ND ug/L 1.0 0.38 1 11 /30/23 17:54 79-01-6 ND ug/L 1.0 0.30 1 11/30/2317:54 75-69-4 ND ug/L 1.0 0.26 1 11/30/2317:54 96-18-4 ND ug/L 2.0 1.3 1 11/30/2317:54 108-05-4 ND ug/L 1.0 0.39 1 11 /30/23 17:54 75-01-4 0.40J ug/L 1.0 0.34 1 11/30/2317:54 1330-20-7 ND ug/L 2.0 0.71 1 11/30/2317:54 179601-23-1 0.40J ug/L 1.0 0.34 1 11/30/2317:54 95-47-6 99 % 70-130 1 11/30/2317:54 460-00-4 94 % 70-130 1 11/30/2317:54 17060-07-0 96 % 70-130 1 11/30/2317:54 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 11/21/23 23:14 123-91-1 92 % 67-130 1 11/21/23 23:14 17060-07-0 95 % 70-130 1 11/21/23 23:14 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-13 Lab ID: 92699658003 Collected: 11/20/23 14:55 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2320B Alkalinity Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville Alkalinity, Total as CaCO3 81.7 mg/L 5.0 5.0 1 11/29/23 16:37 2540C Total Dissolved Solids Analytical Method: SM 254OC-2015 Pace Analytical Services -Asheville Total Dissolved Solids 112 mg/L 25.0 25.0 1 11/27/23 10:24 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Chloride 3.5 mg/L 1.0 0.60 1 11/22/2311:58 16887-00-6 Sulfate ND mg/L 1.0 0.50 1 11/22/2311:58 14808-79-8 Date: 01/17/2024 04:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-15 Lab ID: 92699658004 Collected: 11/20/23 10:15 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Aluminum 1840 ug/L 100 10.3 1 11/22/2311:55 12/08/2318:58 7429-90-5 Antimony ND ug/L 5.0 3.6 1 11/22/2311:55 12/08/2318:58 7440-36-0 Arsenic ND ug/L 10.0 2.5 1 11/22/2311:55 12/08/2318:58 7440-38-2 Barium 110 ug/L 5.0 0.79 1 11/22/2311:55 12/08/2318:58 7440-39-3 Beryllium ND ug/L 1.0 0.16 1 11/22/2311:55 12/08/2318:58 7440-41-7 Cadmium ND ug/L 1.0 0.29 1 11/22/2311:55 12/08/2318:58 7440-43-9 Chromium 16.6 ug/L 5.0 0.63 1 11/22/2311:55 12/08/2318:58 7440-47-3 Cobalt ND ug/L 5.0 0.44 1 11/22/2311:55 12/08/2318:58 7440-48-4 Copper 3.1J ug/L 5.0 0.62 1 11/22/2311:55 12/08/2318:58 7440-50-8 Iron 2330 ug/L 50.0 8.9 1 11/22/2311:55 12/08/2318:58 7439-89-6 Lead ND ug/L 5.0 1.4 1 11/22/2311:55 12/08/2318:58 7439-92-1 Manganese 143 ug/L 5.0 0.86 1 11/22/2311:55 12/08/2318:58 7439-96-5 Nickel 9.9 ug/L 5.0 0.88 1 11/22/2311:55 12/08/2318:58 7440-02-0 Selenium ND ug/L 10.0 4.1 1 11/22/2311:55 12/08/2318:58 7782-49-2 Silver ND ug/L 5.0 0.49 1 11/22/2311:55 12/08/2318:58 7440-22-4 Vanadium 4.7J ug/L 5.0 1.6 1 11/22/2311:55 12/08/2318:58 7440-62-2 Zinc 8.7J ug/L 10.0 3.0 1 11/22/2311:55 12/08/2318:58 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.20 0.050 1 11/22/23 11:50 11/26/23 23:19 7440-28-0 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Date: 01/17/2024 04:40 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 11 /26/23 12:56 11 /28/23 11:18 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 5.1 1 11/30/2318:12 67-64-1 1.8 1 11 /30/23 18:12 107-13-1 0.34 1 11 /30/23 18:12 71-43-2 0.47 1 11 /30/23 18:12 74-97-5 0.31 1 11 /30/23 18:12 75-27-4 0.34 1 11 /30/23 18:12 75-25-2 1.7 1 11 /30/23 18:12 74-83-9 4.0 1 11 /30/23 18:12 78-93-3 0.36 1 11/30/2318:12 75-15-0 0.33 1 11 /30/23 18:12 56-23-5 0.28 1 11 /30/23 18:12 108-90-7 0.65 1 11 /30/23 18:12 75-00-3 0.43 1 11 /30/23 18:12 67-66-3 0.54 1 11 /30/23 18:12 74-87-3 0.34 1 11/30/2318:12 96-12-8 0.36 1 11 /30/23 18:12 124-48-1 0.27 1 11 /30/23 18:12 106-93-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 17 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-15 Lab ID: 92699658004 Collected: 11/20/23 10:15 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) E:Y*-:11]H�46yTAyI�4 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/17/2024 04:40 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.39 1 11/30/2318:12 74-95-3 ND ug/L 1.0 0.34 1 11/30/2318:12 95-50-1 ND ug/L 1.0 0.33 1 11/30/2318:12 106-46-7 ND ug/L 1.0 0.56 1 11/30/2318:12 110-57-6 ND ug/L 1.0 0.37 1 11/30/2318:12 75-34-3 ND ug/L 1.0 0.32 1 11/30/2318:12 107-06-2 ND ug/L 1.0 0.35 1 11/30/2318:12 75-35-4 ND ug/L 1.0 0.38 1 11/30/2318:12 156-59-2 ND ug/L 1.0 0.40 1 11/30/2318:12 156-60-5 ND ug/L 1.0 0.36 1 11/30/2318:12 78-87-5 ND ug/L 1.0 0.36 1 11 /30/23 18:12 10061-01-5 ND ug/L 1.0 0.36 1 11 /30/23 18:12 10061-02-6 ND ug/L 1.0 0.30 1 11 /30/23 18:12 100-41-4 ND ug/L 5.0 0.48 1 11 /30/23 18:12 591-78-6 ND ug/L 20.0 9.7 1 11/30/2318:12 74-88-4 v2 ND ug/L 5.0 2.0 1 11/30/2318:12 75-09-2 ND ug/L 5.0 2.7 1 11/30/2318:12 108-10-1 ND ug/L 1.0 0.29 1 11/30/2318:12 100-42-5 ND ug/L 1.0 0.31 1 11/30/2318:12 630-20-6 ND ug/L 1.0 0.22 1 11/30/2318:12 79-34-5 ND ug/L 1.0 0.29 1 11/30/2318:12 127-18-4 ND ug/L 10.0 3.5 1 11/30/2318:12 109-99-9 ND ug/L 1.0 0.24 1 11/30/2318:12 108-88-3 ND ug/L 1.0 0.33 1 11 /30/23 18:12 71-55-6 ND ug/L 1.0 0.32 1 11/30/2318:12 79-00-5 ND ug/L 1.0 0.38 1 11 /30/23 18:12 79-01-6 ND ug/L 1.0 0.30 1 11/30/2318:12 75-69-4 ND ug/L 1.0 0.26 1 11/30/2318:12 96-18-4 ND ug/L 2.0 1.3 1 11/30/2318:12 108-05-4 ND ug/L 1.0 0.39 1 11 /30/23 18:12 75-01-4 ND ug/L 1.0 0.34 1 11/30/2318:12 1330-20-7 ND ug/L 2.0 0.71 1 11/30/2318:12 179601-23-1 ND ug/L 1.0 0.34 1 11/30/2318:12 95-47-6 102 % 70-130 1 11/30/2318:12 460-00-4 93 % 70-130 1 11/30/2318:12 17060-07-0 97 % 70-130 1 11/30/2318:12 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1.51 ug/L 2.0 0.86 1 11/21/23 23:36 123-91-1 90 % 67-130 1 11/21/23 23:36 17060-07-0 94 % 70-130 1 11/21/23 23:36 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-15 Lab ID: 92699658004 Collected: 11/20/23 10:15 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2320B Alkalinity Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville Alkalinity, Total as CaCO3 52.1 mg/L 5.0 5.0 1 11/29/23 16:48 2540C Total Dissolved Solids Analytical Method: SM 254OC-2015 Pace Analytical Services -Asheville Total Dissolved Solids 116 mg/L 25.0 25.0 1 11/27/23 10:24 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Chloride 8.0 mg/L 1.0 0.60 1 11/22/2312:13 16887-00-6 Sulfate 21.4 mg/L 1.0 0.50 1 11/22/2312:13 14808-79-8 Date: 01/17/2024 04:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-SW-2 Lab ID: 92699658005 Collected: 11/20/23 12:05 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Aluminum 63.OJ ug/L 100 10.3 1 11/22/2311:55 12/08/2319:01 7429-90-5 Antimony ND ug/L 5.0 3.6 1 11/22/2311:55 12/08/2319:01 7440-36-0 Arsenic ND ug/L 10.0 2.5 1 11/22/2311:55 12/08/2319:01 7440-38-2 Barium 33.3 ug/L 5.0 0.79 1 11/22/2311:55 12/08/2319:01 7440-39-3 Beryllium ND ug/L 1.0 0.16 1 11/22/2311:55 12/08/2319:01 7440-41-7 Cadmium ND ug/L 1.0 0.29 1 11/22/2311:55 12/08/2319:01 7440-43-9 Chromium 0.97J ug/L 5.0 0.63 1 11/22/2311:55 12/08/2319:01 7440-47-3 Cobalt ND ug/L 5.0 0.44 1 11/22/2311:55 12/08/2319:01 7440-48-4 Copper ND ug/L 5.0 0.62 1 11/22/2311:55 12/08/2319:01 7440-50-8 Iron 123 ug/L 50.0 8.9 1 11/22/2311:55 12/08/2319:01 7439-89-6 Lead ND ug/L 5.0 1.4 1 11/22/2311:55 12/08/2319:01 7439-92-1 Manganese 4.7J ug/L 5.0 0.86 1 11/22/2311:55 12/08/2319:01 7439-96-5 Nickel ND ug/L 5.0 0.88 1 11/22/2311:55 12/08/2319:01 7440-02-0 Selenium ND ug/L 10.0 4.1 1 11/22/2311:55 12/08/2319:01 7782-49-2 Silver ND ug/L 5.0 0.49 1 11/22/2311:55 12/08/2319:01 7440-22-4 Vanadium ND ug/L 5.0 1.6 1 11/22/2311:55 12/08/2319:01 7440-62-2 Zinc ND ug/L 10.0 3.0 1 11/22/2311:55 12/08/2319:01 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.20 0.050 1 11/22/23 11:50 11/26/23 23:25 7440-28-0 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Date: 01/17/2024 04:40 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 11 /26/23 12:56 11 /28/23 11:20 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 5.1 1 11/30/2318:30 67-64-1 1.8 1 11 /30/23 18:30 107-13-1 0.34 1 11 /30/23 18:30 71-43-2 0.47 1 11 /30/23 18:30 74-97-5 0.31 1 11 /30/23 18:30 75-27-4 0.34 1 11 /30/23 18:30 75-25-2 1.7 1 11 /30/23 18:30 74-83-9 4.0 1 11 /30/23 18:30 78-93-3 0.36 1 11/30/2318:30 75-15-0 0.33 1 11 /30/23 18:30 56-23-5 0.28 1 11 /30/23 18:30 108-90-7 0.65 1 11 /30/23 18:30 75-00-3 0.43 1 11 /30/23 18:30 67-66-3 0.54 1 11 /30/23 18:30 74-87-3 0.34 1 11/30/2318:30 96-12-8 0.36 1 11 /30/23 18:30 124-48-1 0.27 1 11 /30/23 18:30 106-93-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 20 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-SW-2 Lab ID: 92699658005 Collected: 11/20/23 12:05 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) E:Y*-:11]H�46yTAyI�4 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/17/2024 04:40 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.39 1 11/30/2318:30 74-95-3 ND ug/L 1.0 0.34 1 11/30/2318:30 95-50-1 ND ug/L 1.0 0.33 1 11/30/2318:30 106-46-7 ND ug/L 1.0 0.56 1 11/30/2318:30 110-57-6 ND ug/L 1.0 0.37 1 11/30/2318:30 75-34-3 ND ug/L 1.0 0.32 1 11/30/2318:30 107-06-2 ND ug/L 1.0 0.35 1 11/30/2318:30 75-35-4 ND ug/L 1.0 0.38 1 11/30/2318:30 156-59-2 ND ug/L 1.0 0.40 1 11/30/2318:30 156-60-5 ND ug/L 1.0 0.36 1 11/30/2318:30 78-87-5 ND ug/L 1.0 0.36 1 11 /30/23 18:30 10061-01-5 ND ug/L 1.0 0.36 1 11 /30/23 18:30 10061-02-6 ND ug/L 1.0 0.30 1 11 /30/23 18:30 100-41-4 ND ug/L 5.0 0.48 1 11 /30/23 18:30 591-78-6 ND ug/L 20.0 9.7 1 11/30/2318:30 74-88-4 v2 ND ug/L 5.0 2.0 1 11/30/2318:30 75-09-2 ND ug/L 5.0 2.7 1 11/30/2318:30 108-10-1 ND ug/L 1.0 0.29 1 11/30/2318:30 100-42-5 ND ug/L 1.0 0.31 1 11/30/2318:30 630-20-6 ND ug/L 1.0 0.22 1 11/30/2318:30 79-34-5 ND ug/L 1.0 0.29 1 11/30/2318:30 127-18-4 ND ug/L 10.0 3.5 1 11/30/2318:30 109-99-9 ND ug/L 1.0 0.24 1 11/30/2318:30 108-88-3 ND ug/L 1.0 0.33 1 11 /30/23 18:30 71-55-6 ND ug/L 1.0 0.32 1 11/30/2318:30 79-00-5 ND ug/L 1.0 0.38 1 11 /30/23 18:30 79-01-6 ND ug/L 1.0 0.30 1 11/30/2318:30 75-69-4 ND ug/L 1.0 0.26 1 11/30/2318:30 96-18-4 ND ug/L 2.0 1.3 1 11/30/2318:30 108-05-4 ND ug/L 1.0 0.39 1 11 /30/23 18:30 75-01-4 ND ug/L 1.0 0.34 1 11/30/2318:30 1330-20-7 ND ug/L 2.0 0.71 1 11/30/2318:30 179601-23-1 ND ug/L 1.0 0.34 1 11/30/2318:30 95-47-6 100 % 70-130 1 11/30/2318:30 460-00-4 92 % 70-130 1 11/30/2318:30 17060-07-0 100 % 70-130 1 11/30/2318:30 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 11/21/23 23:57 123-91-1 90 % 67-130 1 11/21/23 23:57 17060-07-0 94 % 70-130 1 11/21/23 23:57 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-SW-2 Lab ID: 92699658005 Collected: 11/20/23 12:05 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2320B Alkalinity Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville Alkalinity, Total as CaCO3 29.5 mg/L 5.0 5.0 1 11/29/23 16:55 2540C Total Dissolved Solids Analytical Method: SM 254OC-2015 Pace Analytical Services -Asheville Total Dissolved Solids 1030 mg/L 50.0 50.0 1 11/27/23 10:24 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Chloride 3.7 mg/L 1.0 0.60 1 11/22/2312:27 16887-00-6 Sulfate 5.5 mg/L 1.0 0.50 1 11/22/2312:27 14808-79-8 Date: 01/17/2024 04:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-SW-3 Lab ID: 92699658006 Collected: 11/20/23 12:55 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Aluminum 35.OJ ug/L 100 10.3 1 11/22/2311:55 12/08/2319:04 7429-90-5 Antimony ND ug/L 5.0 3.6 1 11/22/2311:55 12/08/2319:04 7440-36-0 Arsenic ND ug/L 10.0 2.5 1 11/22/2311:55 12/08/2319:04 7440-38-2 Barium 24.4 ug/L 5.0 0.79 1 11/22/2311:55 12/08/2319:04 7440-39-3 Beryllium ND ug/L 1.0 0.16 1 11/22/2311:55 12/08/2319:04 7440-41-7 Cadmium ND ug/L 1.0 0.29 1 11/22/2311:55 12/08/2319:04 7440-43-9 Chromium 0.73J ug/L 5.0 0.63 1 11/22/2311:55 12/08/2319:04 7440-47-3 Cobalt ND ug/L 5.0 0.44 1 11/22/2311:55 12/08/2319:04 7440-48-4 Copper ND ug/L 5.0 0.62 1 11/22/2311:55 12/08/2319:04 7440-50-8 Iron 155 ug/L 50.0 8.9 1 11/22/2311:55 12/08/2319:04 7439-89-6 Lead ND ug/L 5.0 1.4 1 11/22/2311:55 12/08/2319:04 7439-92-1 Manganese 18.1 ug/L 5.0 0.86 1 11/22/2311:55 12/08/2319:04 7439-96-5 Nickel ND ug/L 5.0 0.88 1 11/22/2311:55 12/08/2319:04 7440-02-0 Selenium ND ug/L 10.0 4.1 1 11/22/2311:55 12/08/2319:04 7782-49-2 Silver ND ug/L 5.0 0.49 1 11/22/2311:55 12/08/2319:04 7440-22-4 Vanadium ND ug/L 5.0 1.6 1 11/22/2311:55 12/08/2319:04 7440-62-2 Zinc ND ug/L 10.0 3.0 1 11/22/2311:55 12/08/2319:04 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.20 0.050 1 11/22/23 11:50 11/26/23 23:39 7440-28-0 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Date: 01/17/2024 04:40 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 11 /26/23 12:56 11 /28/23 11:22 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 5.1 1 11/30/2318:47 67-64-1 1.8 1 11 /30/23 18:47 107-13-1 0.34 1 11 /30/23 18:47 71-43-2 0.47 1 11 /30/23 18:47 74-97-5 0.31 1 11 /30/23 18:47 75-27-4 0.34 1 11 /30/23 18:47 75-25-2 1.7 1 11 /30/23 18:47 74-83-9 4.0 1 11 /30/23 18:47 78-93-3 0.36 1 11/30/2318:47 75-15-0 0.33 1 11 /30/23 18:47 56-23-5 0.28 1 11 /30/23 18:47 108-90-7 0.65 1 11 /30/23 18:47 75-00-3 0.43 1 11 /30/23 18:47 67-66-3 0.54 1 11 /30/23 18:47 74-87-3 0.34 1 11/30/2318:47 96-12-8 0.36 1 11 /30/23 18:47 124-48-1 0.27 1 11 /30/23 18:47 106-93-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 23 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-SW-3 Lab ID: 92699658006 Collected: 11/20/23 12:55 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) E:Y*-:11]H�46yTAyI�4 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/17/2024 04:40 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.39 1 11/30/2318:47 74-95-3 ND ug/L 1.0 0.34 1 11/30/2318:47 95-50-1 ND ug/L 1.0 0.33 1 11/30/2318:47 106-46-7 ND ug/L 1.0 0.56 1 11/30/2318:47 110-57-6 ND ug/L 1.0 0.37 1 11/30/2318:47 75-34-3 ND ug/L 1.0 0.32 1 11/30/2318:47 107-06-2 ND ug/L 1.0 0.35 1 11/30/2318:47 75-35-4 ND ug/L 1.0 0.38 1 11/30/2318:47 156-59-2 ND ug/L 1.0 0.40 1 11/30/2318:47 156-60-5 ND ug/L 1.0 0.36 1 11/30/2318:47 78-87-5 ND ug/L 1.0 0.36 1 11 /30/23 18:47 10061-01-5 ND ug/L 1.0 0.36 1 11 /30/23 18:47 10061-02-6 ND ug/L 1.0 0.30 1 11 /30/23 18:47 100-41-4 ND ug/L 5.0 0.48 1 11 /30/23 18:47 591-78-6 ND ug/L 20.0 9.7 1 11/30/2318:47 74-88-4 v2 ND ug/L 5.0 2.0 1 11/30/2318:47 75-09-2 ND ug/L 5.0 2.7 1 11/30/2318:47 108-10-1 ND ug/L 1.0 0.29 1 11/30/2318:47 100-42-5 ND ug/L 1.0 0.31 1 11/30/2318:47 630-20-6 ND ug/L 1.0 0.22 1 11/30/2318:47 79-34-5 ND ug/L 1.0 0.29 1 11/30/2318:47 127-18-4 ND ug/L 10.0 3.5 1 11/30/2318:47 109-99-9 ND ug/L 1.0 0.24 1 11/30/2318:47 108-88-3 ND ug/L 1.0 0.33 1 11 /30/23 18:47 71-55-6 ND ug/L 1.0 0.32 1 11/30/2318:47 79-00-5 ND ug/L 1.0 0.38 1 11 /30/23 18:47 79-01-6 ND ug/L 1.0 0.30 1 11/30/2318:47 75-69-4 ND ug/L 1.0 0.26 1 11/30/2318:47 96-18-4 ND ug/L 2.0 1.3 1 11/30/2318:47 108-05-4 ND ug/L 1.0 0.39 1 11 /30/23 18:47 75-01-4 ND ug/L 1.0 0.34 1 11/30/2318:47 1330-20-7 ND ug/L 2.0 0.71 1 11/30/2318:47 179601-23-1 ND ug/L 1.0 0.34 1 11/30/2318:47 95-47-6 100 % 70-130 1 11/30/2318:47 460-00-4 93 % 70-130 1 11/30/2318:47 17060-07-0 97 % 70-130 1 11/30/2318:47 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 11/22/23 00:19 123-91-1 91 % 67-130 1 11/22/23 00:19 17060-07-0 94 % 70-130 1 11/22/23 00:19 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-SW-3 Lab ID: 92699658006 Collected: 11/20/23 12:55 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2320B Alkalinity Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville Alkalinity, Total as CaCO3 24.3 mg/L 5.0 5.0 1 11/29/23 17:01 2540C Total Dissolved Solids Analytical Method: SM 254OC-2015 Pace Analytical Services -Asheville Total Dissolved Solids 50.0 mg/L 25.0 25.0 1 11/27/23 10:25 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Chloride 4.4 mg/L 1.0 0.60 1 11/22/2312:42 16887-00-6 Sulfate 1.3 mg/L 1.0 0.50 1 11/22/2312:42 14808-79-8 Date: 01/17/2024 04:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 25 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-SW-4 Lab ID: 92699658007 Collected: 11/20/23 10:10 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Aluminum 71.1J ug/L 100 10.3 1 11/22/2311:55 12/08/2319:06 7429-90-5 Antimony ND ug/L 5.0 3.6 1 11/22/2311:55 12/08/2319:06 7440-36-0 Arsenic ND ug/L 10.0 2.5 1 11/22/2311:55 12/08/2319:06 7440-38-2 Barium 26.6 ug/L 5.0 0.79 1 11/22/2311:55 12/08/2319:06 7440-39-3 Beryllium ND ug/L 1.0 0.16 1 11/22/2311:55 12/08/2319:06 7440-41-7 Cadmium ND ug/L 1.0 0.29 1 11/22/2311:55 12/08/2319:06 7440-43-9 Chromium ND ug/L 5.0 0.63 1 11/22/2311:55 12/08/2319:06 7440-47-3 Cobalt ND ug/L 5.0 0.44 1 11/22/2311:55 12/08/2319:06 7440-48-4 Copper ND ug/L 5.0 0.62 1 11/22/2311:55 12/08/2319:06 7440-50-8 Iron 126 ug/L 50.0 8.9 1 11/22/2311:55 12/08/2319:06 7439-89-6 Lead ND ug/L 5.0 1.4 1 11/22/2311:55 12/08/2319:06 7439-92-1 Manganese 4.4J ug/L 5.0 0.86 1 11/22/2311:55 12/08/2319:06 7439-96-5 Nickel ND ug/L 5.0 0.88 1 11/22/2311:55 12/08/2319:06 7440-02-0 Selenium ND ug/L 10.0 4.1 1 11/22/2311:55 12/08/2319:06 7782-49-2 Silver ND ug/L 5.0 0.49 1 11/22/2311:55 12/08/2319:06 7440-22-4 Vanadium ND ug/L 5.0 1.6 1 11/22/2311:55 12/08/2319:06 7440-62-2 Zinc ND ug/L 10.0 3.0 1 11/22/2311:55 12/08/2319:06 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.20 0.050 1 11/22/23 11:50 11/26/23 23:44 7440-28-0 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Date: 01/17/2024 04:40 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 11 /26/23 12:56 11 /28/23 11:24 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 5.1 1 11/30/2319:05 67-64-1 1.8 1 11 /30/23 19:05 107-13-1 0.34 1 11 /30/23 19:05 71-43-2 0.47 1 11 /30/23 19:05 74-97-5 0.31 1 11 /30/23 19:05 75-27-4 0.34 1 11 /30/23 19:05 75-25-2 1.7 1 11 /30/23 19:05 74-83-9 4.0 1 11 /30/23 19:05 78-93-3 0.36 1 11/30/2319:05 75-15-0 0.33 1 11 /30/23 19:05 56-23-5 0.28 1 11 /30/23 19:05 108-90-7 0.65 1 11 /30/23 19:05 75-00-3 0.43 1 11 /30/23 19:05 67-66-3 0.54 1 11 /30/23 19:05 74-87-3 0.34 1 11/30/2319:05 96-12-8 0.36 1 11 /30/23 19:05 124-48-1 0.27 1 11 /30/23 19:05 106-93-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 26 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-SW-4 Lab ID: 92699658007 Collected: 11/20/23 10:10 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) E:Y*-:11]H�46yTAyI�4 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/17/2024 04:40 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.39 1 11/30/2319:05 74-95-3 ND ug/L 1.0 0.34 1 11/30/2319:05 95-50-1 ND ug/L 1.0 0.33 1 11/30/2319:05 106-46-7 ND ug/L 1.0 0.56 1 11/30/2319:05 110-57-6 ND ug/L 1.0 0.37 1 11/30/2319:05 75-34-3 ND ug/L 1.0 0.32 1 11/30/2319:05 107-06-2 ND ug/L 1.0 0.35 1 11/30/2319:05 75-35-4 ND ug/L 1.0 0.38 1 11/30/2319:05 156-59-2 ND ug/L 1.0 0.40 1 11/30/2319:05 156-60-5 ND ug/L 1.0 0.36 1 11/30/2319:05 78-87-5 ND ug/L 1.0 0.36 1 11 /30/23 19:05 10061-01-5 ND ug/L 1.0 0.36 1 11 /30/23 19:05 10061-02-6 ND ug/L 1.0 0.30 1 11 /30/23 19:05 100-41-4 ND ug/L 5.0 0.48 1 11 /30/23 19:05 591-78-6 ND ug/L 20.0 9.7 1 11/30/2319:05 74-88-4 v2 ND ug/L 5.0 2.0 1 11/30/2319:05 75-09-2 ND ug/L 5.0 2.7 1 11/30/2319:05 108-10-1 ND ug/L 1.0 0.29 1 11/30/2319:05 100-42-5 ND ug/L 1.0 0.31 1 11/30/2319:05 630-20-6 ND ug/L 1.0 0.22 1 11/30/2319:05 79-34-5 ND ug/L 1.0 0.29 1 11/30/2319:05 127-18-4 ND ug/L 10.0 3.5 1 11/30/2319:05 109-99-9 ND ug/L 1.0 0.24 1 11/30/2319:05 108-88-3 ND ug/L 1.0 0.33 1 11 /30/23 19:05 71-55-6 ND ug/L 1.0 0.32 1 11/30/2319:05 79-00-5 ND ug/L 1.0 0.38 1 11 /30/23 19:05 79-01-6 ND ug/L 1.0 0.30 1 11/30/2319:05 75-69-4 ND ug/L 1.0 0.26 1 11/30/2319:05 96-18-4 ND ug/L 2.0 1.3 1 11/30/2319:05 108-05-4 ND ug/L 1.0 0.39 1 11 /30/23 19:05 75-01-4 ND ug/L 1.0 0.34 1 11/30/2319:05 1330-20-7 ND ug/L 2.0 0.71 1 11/30/2319:05 179601-23-1 ND ug/L 1.0 0.34 1 11/30/2319:05 95-47-6 103 % 70-130 1 11/30/2319:05 460-00-4 93 % 70-130 1 11/30/2319:05 17060-07-0 98 % 70-130 1 11/30/2319:05 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 11/22/23 00:40 123-91-1 90 % 67-130 1 11/22/23 00:40 17060-07-0 94 % 70-130 1 11/22/23 00:40 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-SW-4 Lab ID: 92699658007 Collected: 11/20/23 10:10 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2320B Alkalinity Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville Alkalinity, Total as CaCO3 14.7 mg/L 5.0 5.0 1 11/30/23 16:10 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 35.0 mg/L 25.0 25.0 1 11/27/23 10:25 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Chloride 4.0 mg/L 1.0 0.60 1 11/22/2313:25 16887-00-6 Sulfate ND mg/L 1.0 0.50 1 11/22/2313:25 14808-79-8 Date: 01/17/2024 04:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 28 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-SW-5 Lab ID: 92699658008 Collected: 11/20/23 11:25 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Aluminum 66.6J ug/L 100 10.3 1 11/22/2311:55 12/08/2319:09 7429-90-5 Antimony ND ug/L 5.0 3.6 1 11/22/2311:55 12/08/2319:09 7440-36-0 Arsenic ND ug/L 10.0 2.5 1 11/22/2311:55 12/08/2319:09 7440-38-2 Barium 33.0 ug/L 5.0 0.79 1 11/22/2311:55 12/08/2319:09 7440-39-3 Beryllium ND ug/L 1.0 0.16 1 11/22/2311:55 12/08/2319:09 7440-41-7 Cadmium ND ug/L 1.0 0.29 1 11/22/2311:55 12/08/2319:09 7440-43-9 Chromium 0.65J ug/L 5.0 0.63 1 11/22/2311:55 12/08/2319:09 7440-47-3 Cobalt ND ug/L 5.0 0.44 1 11/22/2311:55 12/08/2319:09 7440-48-4 Copper ND ug/L 5.0 0.62 1 11/22/2311:55 12/08/2319:09 7440-50-8 Iron 176 ug/L 50.0 8.9 1 11/22/2311:55 12/08/2319:09 7439-89-6 Lead ND ug/L 5.0 1.4 1 11/22/2311:55 12/08/2319:09 7439-92-1 Manganese 30.2 ug/L 5.0 0.86 1 11/22/2311:55 12/08/2319:09 7439-96-5 Nickel 1.3J ug/L 5.0 0.88 1 11/22/2311:55 12/08/2319:09 7440-02-0 Selenium ND ug/L 10.0 4.1 1 11/22/2311:55 12/08/2319:09 7782-49-2 Silver ND ug/L 5.0 0.49 1 11/22/2311:55 12/08/2319:09 7440-22-4 Vanadium ND ug/L 5.0 1.6 1 11/22/2311:55 12/08/2319:09 7440-62-2 Zinc ND ug/L 10.0 3.0 1 11/22/2311:55 12/08/2319:09 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.20 0.050 1 11/22/23 11:50 11/26/23 23:49 7440-28-0 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Date: 01/17/2024 04:40 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 11 /26/23 12:56 11 /28/23 11:26 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 5.1 1 11/30/2319:23 67-64-1 1.8 1 11 /30/23 19:23 107-13-1 0.34 1 11 /30/23 19:23 71-43-2 0.47 1 11 /30/23 19:23 74-97-5 0.31 1 11 /30/23 19:23 75-27-4 0.34 1 11 /30/23 19:23 75-25-2 1.7 1 11 /30/23 19:23 74-83-9 4.0 1 11 /30/23 19:23 78-93-3 0.36 1 11/30/2319:23 75-15-0 0.33 1 11 /30/23 19:23 56-23-5 0.28 1 11 /30/23 19:23 108-90-7 0.65 1 11 /30/23 19:23 75-00-3 0.43 1 11 /30/23 19:23 67-66-3 0.54 1 11 /30/23 19:23 74-87-3 0.34 1 11/30/2319:23 96-12-8 0.36 1 11 /30/23 19:23 124-48-1 0.27 1 11 /30/23 19:23 106-93-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 29 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-SW-5 Lab ID: 92699658008 Collected: 11/20/23 11:25 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) E:Y*-:11]H�46yTAyI�4 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/17/2024 04:40 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.39 1 11/30/2319:23 74-95-3 ND ug/L 1.0 0.34 1 11/30/2319:23 95-50-1 ND ug/L 1.0 0.33 1 11/30/2319:23 106-46-7 ND ug/L 1.0 0.56 1 11/30/2319:23 110-57-6 ND ug/L 1.0 0.37 1 11/30/2319:23 75-34-3 ND ug/L 1.0 0.32 1 11/30/2319:23 107-06-2 ND ug/L 1.0 0.35 1 11/30/2319:23 75-35-4 ND ug/L 1.0 0.38 1 11/30/2319:23 156-59-2 ND ug/L 1.0 0.40 1 11/30/2319:23 156-60-5 ND ug/L 1.0 0.36 1 11/30/2319:23 78-87-5 ND ug/L 1.0 0.36 1 11 /30/23 19:23 10061-01-5 ND ug/L 1.0 0.36 1 11 /30/23 19:23 10061-02-6 ND ug/L 1.0 0.30 1 11 /30/23 19:23 100-41-4 ND ug/L 5.0 0.48 1 11 /30/23 19:23 591-78-6 ND ug/L 20.0 9.7 1 11/30/2319:23 74-88-4 v2 ND ug/L 5.0 2.0 1 11/30/2319:23 75-09-2 ND ug/L 5.0 2.7 1 11/30/2319:23 108-10-1 ND ug/L 1.0 0.29 1 11/30/2319:23 100-42-5 ND ug/L 1.0 0.31 1 11/30/2319:23 630-20-6 ND ug/L 1.0 0.22 1 11/30/2319:23 79-34-5 ND ug/L 1.0 0.29 1 11/30/2319:23 127-18-4 ND ug/L 10.0 3.5 1 11/30/2319:23 109-99-9 ND ug/L 1.0 0.24 1 11/30/2319:23 108-88-3 ND ug/L 1.0 0.33 1 11 /30/23 19:23 71-55-6 ND ug/L 1.0 0.32 1 11/30/2319:23 79-00-5 ND ug/L 1.0 0.38 1 11 /30/23 19:23 79-01-6 ND ug/L 1.0 0.30 1 11/30/2319:23 75-69-4 ND ug/L 1.0 0.26 1 11/30/2319:23 96-18-4 ND ug/L 2.0 1.3 1 11/30/2319:23 108-05-4 ND ug/L 1.0 0.39 1 11 /30/23 19:23 75-01-4 ND ug/L 1.0 0.34 1 11/30/2319:23 1330-20-7 ND ug/L 2.0 0.71 1 11/30/2319:23 179601-23-1 ND ug/L 1.0 0.34 1 11/30/2319:23 95-47-6 101 % 70-130 1 11/30/2319:23 460-00-4 94 % 70-130 1 11/30/2319:23 17060-07-0 99 % 70-130 1 11/30/2319:23 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 11/22/23 01:01 123-91-1 91 % 67-130 1 11/22/23 01:01 17060-07-0 94 % 70-130 1 11/22/23 01:01 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 30 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-SW-5 Lab ID: 92699658008 Collected: 11/20/23 11:25 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2320B Alkalinity Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville Alkalinity, Total as CaCO3 30.2 mg/L 5.0 5.0 1 11/30/23 16:16 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 56.0 mg/L 25.0 25.0 1 11/27/23 10:25 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Chloride 3.6 mg/L 1.0 0.60 1 11/22/2313:40 16887-00-6 Sulfate 5.2 mg/L 1.0 0.50 1 11/22/2313:40 14808-79-8 Date: 01/17/2024 04:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 31 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-4 Lab ID: 92699658009 Collected: 11/20/23 15:50 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.6 1 11/22/2311:55 12/08/2319:12 7440-36-0 Arsenic ND ug/L 10.0 2.5 1 11/22/2311:55 12/08/2319:12 7440-38-2 Barium 115 ug/L 5.0 0.79 1 11/22/2311:55 12/08/2319:12 7440-39-3 Beryllium ND ug/L 1.0 0.16 1 11/22/2311:55 12/08/2319:12 7440-41-7 Cadmium ND ug/L 1.0 0.29 1 11/22/2311:55 12/08/2319:12 7440-43-9 Chromium 4.2J ug/L 5.0 0.63 1 11/22/2311:55 12/08/2319:12 7440-47-3 Cobalt ND ug/L 5.0 0.44 1 11/22/2311:55 12/08/2319:12 7440-48-4 Copper 6.7 ug/L 5.0 0.62 1 11/22/2311:55 12/08/2319:12 7440-50-8 Lead 7.8 ug/L 5.0 1.4 1 11/22/2311:55 12/08/2319:12 7439-92-1 Nickel 5.2 ug/L 5.0 0.88 1 11/22/2311:55 12/08/2319:12 7440-02-0 Selenium ND ug/L 10.0 4.1 1 11/22/2311:55 12/08/2319:12 7782-49-2 Silver ND ug/L 5.0 0.49 1 11/22/2311:55 12/08/2319:12 7440-22-4 Vanadium 11.5 ug/L 5.0 1.6 1 11/22/2311:55 12/08/2319:12 7440-62-2 Zinc 15.6 ug/L 10.0 3.0 1 11/22/2311:55 12/08/2319:12 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.20 0.050 1 11/22/23 11:50 11/26/23 23:54 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/30/23 19:41 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/30/23 19:41 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/30/23 19:41 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/30/23 19:41 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/30/23 19:41 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/30/23 19:41 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/30/23 19:41 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/30/23 19:41 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 11/30/23 19:41 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/30/23 19:41 56-23-5 Chlorobenzene 0.49J ug/L 1.0 0.28 1 11/30/23 19:41 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/30/23 19:41 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/30/23 19:41 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/30/23 19:41 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/30/23 19:41 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/30/23 19:41 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/30/23 19:41 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/30/23 19:41 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/30/23 19:41 95-50-1 1,4-Dichlorobenzene 0.42J ug/L 1.0 0.33 1 11/30/23 19:41 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/30/23 19:41 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/30/23 19:41 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/30/23 19:41 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/30/23 19:41 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. v2 Page 32 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-4 Lab ID: 92699658009 Collected: 11/20/23 15:50 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/17/2024 04:40 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 11/30/2319:41 156-59-2 ND ug/L 1.0 0.40 1 11/30/2319:41 156-60-5 ND ug/L 1.0 0.36 1 11/30/2319:41 78-87-5 ND ug/L 1.0 0.36 1 11 /30/23 19:41 10061-01-5 ND ug/L 1.0 0.36 1 11 /30/23 19:41 10061-02-6 ND ug/L 1.0 0.30 1 11 /30/23 19:41 100-41-4 ND ug/L 5.0 0.48 1 11 /30/23 19:41 591-78-6 ND ug/L 20.0 9.7 1 11/30/2319:41 74-88-4 v2 ND ug/L 5.0 2.0 1 11/30/2319:41 75-09-2 ND ug/L 5.0 2.7 1 11/30/2319:41 108-10-1 ND ug/L 1.0 0.29 1 11/30/2319:41 100-42-5 ND ug/L 1.0 0.31 1 11/30/2319:41 630-20-6 ND ug/L 1.0 0.22 1 11/30/2319:41 79-34-5 ND ug/L 1.0 0.29 1 11/30/2319:41 127-18-4 ND ug/L 1.0 0.24 1 11/30/2319:41 108-88-3 ND ug/L 1.0 0.33 1 11 /30/23 19:41 71-55-6 ND ug/L 1.0 0.32 1 11/30/2319:41 79-00-5 ND ug/L 1.0 0.38 1 11 /30/23 19:41 79-01-6 ND ug/L 1.0 0.30 1 11/30/2319:41 75-69-4 ND ug/L 1.0 0.26 1 11/30/2319:41 96-18-4 ND ug/L 2.0 1.3 1 11/30/2319:41 108-05-4 ND ug/L 1.0 0.39 1 11 /30/23 19:41 75-01-4 ND ug/L 1.0 0.34 1 11/30/2319:41 1330-20-7 ND ug/L 2.0 0.71 1 11/30/2319:41 179601-23-1 ND ug/L 1.0 0.34 1 11/30/2319:41 95-47-6 101 % 70-130 1 11/30/2319:41 460-00-4 93 % 70-130 1 11/30/2319:41 17060-07-0 99 % 70-130 1 11/30/2319:41 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 11/22/23 01:23 123-91-1 90 % 67-130 1 11/22/23 01:23 17060-07-0 93 % 70-130 1 11/22/23 01:23 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 33 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-9 Lab ID: 92699658010 Collected: 11/20/23 15:05 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.6 1 11/22/2311:55 12/08/2319:15 7440-36-0 Arsenic ND ug/L 10.0 2.5 1 11/22/2311:55 12/08/2319:15 7440-38-2 Barium 56.9 ug/L 5.0 0.79 1 11/22/2311:55 12/08/2319:15 7440-39-3 Beryllium ND ug/L 1.0 0.16 1 11/22/2311:55 12/08/2319:15 7440-41-7 Cadmium ND ug/L 1.0 0.29 1 11/22/2311:55 12/08/2319:15 7440-43-9 Chromium 2.8J ug/L 5.0 0.63 1 11/22/2311:55 12/08/2319:15 7440-47-3 Cobalt ND ug/L 5.0 0.44 1 11/22/2311:55 12/08/2319:15 7440-48-4 Copper ND ug/L 5.0 0.62 1 11/22/2311:55 12/08/2319:15 7440-50-8 Lead ND ug/L 5.0 1.4 1 11/22/2311:55 12/08/2319:15 7439-92-1 Nickel 1.7J ug/L 5.0 0.88 1 11/22/2311:55 12/08/2319:15 7440-02-0 Selenium ND ug/L 10.0 4.1 1 11/22/2311:55 12/08/2319:15 7782-49-2 Silver ND ug/L 5.0 0.49 1 11/22/2311:55 12/08/2319:15 7440-22-4 Vanadium ND ug/L 5.0 1.6 1 11/22/2311:55 12/08/2319:15 7440-62-2 Zinc 4.9J ug/L 10.0 3.0 1 11/22/2311:55 12/08/2319:15 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.064J ug/L 0.20 0.050 1 11/22/23 11:50 11/26/23 23:59 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/30/23 19:59 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/30/23 19:59 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/30/23 19:59 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/30/23 19:59 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/30/23 19:59 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/30/23 19:59 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/30/23 19:59 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/30/23 19:59 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 11/30/23 19:59 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/30/23 19:59 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 11/30/23 19:59 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/30/23 19:59 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/30/23 19:59 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/30/23 19:59 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/30/23 19:59 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/30/23 19:59 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/30/23 19:59 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/30/23 19:59 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/30/23 19:59 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 11/30/23 19:59 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/30/23 19:59 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/30/23 19:59 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/30/23 19:59 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/30/23 19:59 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. v2 Page 34 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-9 Lab ID: 92699658010 Collected: 11/20/23 15:05 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/17/2024 04:40 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 11/30/2319:59 156-59-2 ND ug/L 1.0 0.40 1 11/30/2319:59 156-60-5 42.6 ug/L 1.0 0.36 1 11/30/2319:59 78-87-5 ND ug/L 1.0 0.36 1 11 /30/23 19:59 10061-01-5 ND ug/L 1.0 0.36 1 11 /30/23 19:59 10061-02-6 ND ug/L 1.0 0.30 1 11 /30/23 19:59 100-41-4 ND ug/L 5.0 0.48 1 11 /30/23 19:59 591-78-6 ND ug/L 20.0 9.7 1 11/30/2319:59 74-88-4 v2 ND ug/L 5.0 2.0 1 11/30/2319:59 75-09-2 ND ug/L 5.0 2.7 1 11/30/2319:59 108-10-1 ND ug/L 1.0 0.29 1 11/30/2319:59 100-42-5 ND ug/L 1.0 0.31 1 11/30/2319:59 630-20-6 ND ug/L 1.0 0.22 1 11/30/2319:59 79-34-5 ND ug/L 1.0 0.29 1 11/30/2319:59 127-18-4 ND ug/L 1.0 0.24 1 11/30/2319:59 108-88-3 ND ug/L 1.0 0.33 1 11 /30/23 19:59 71-55-6 ND ug/L 1.0 0.32 1 11/30/2319:59 79-00-5 ND ug/L 1.0 0.38 1 11 /30/23 19:59 79-01-6 ND ug/L 1.0 0.30 1 11/30/2319:59 75-69-4 1.6 ug/L 1.0 0.26 1 11/30/2319:59 96-18-4 ND ug/L 2.0 1.3 1 11/30/2319:59 108-05-4 ND ug/L 1.0 0.39 1 11 /30/23 19:59 75-01-4 ND ug/L 1.0 0.34 1 11/30/2319:59 1330-20-7 ND ug/L 2.0 0.71 1 11/30/2319:59 179601-23-1 ND ug/L 1.0 0.34 1 11/30/2319:59 95-47-6 100 % 70-130 1 11/30/2319:59 460-00-4 94 % 70-130 1 11/30/2319:59 17060-07-0 97 % 70-130 1 11/30/2319:59 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 11/22/23 01:44 123-91-1 92 % 67-130 1 11/22/23 01:44 17060-07-0 94 % 70-130 1 11/22/23 01:44 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 35 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-10B Lab ID: 92699658011 Collected: 11/20/23 12:45 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.6 1 11/22/2311:55 12/08/2319:18 7440-36-0 Arsenic ND ug/L 10.0 2.5 1 11/22/2311:55 12/08/2319:18 7440-38-2 Barium 57.7 ug/L 5.0 0.79 1 11/22/2311:55 12/08/2319:18 7440-39-3 Beryllium ND ug/L 1.0 0.16 1 11/22/2311:55 12/08/2319:18 7440-41-7 Cadmium ND ug/L 1.0 0.29 1 11/22/2311:55 12/08/2319:18 7440-43-9 Chromium 0.72J ug/L 5.0 0.63 1 11/22/2311:55 12/08/2319:18 7440-47-3 Cobalt ND ug/L 5.0 0.44 1 11/22/2311:55 12/08/2319:18 7440-48-4 Copper ND ug/L 5.0 0.62 1 11/22/2311:55 12/08/2319:18 7440-50-8 Lead ND ug/L 5.0 1.4 1 11/22/2311:55 12/08/2319:18 7439-92-1 Nickel 1.1J ug/L 5.0 0.88 1 11/22/2311:55 12/08/2319:18 7440-02-0 Selenium ND ug/L 10.0 4.1 1 11/22/2311:55 12/08/2319:18 7782-49-2 Silver ND ug/L 5.0 0.49 1 11/22/2311:55 12/08/2319:18 7440-22-4 Vanadium ND ug/L 5.0 1.6 1 11/22/2311:55 12/08/2319:18 7440-62-2 Zinc ND ug/L 10.0 3.0 1 11/22/2311:55 12/08/2319:18 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.20 0.050 1 11/22/23 11:50 11/27/23 00:04 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/30/23 20:17 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/30/23 20:17 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/30/23 20:17 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/30/23 20:17 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/30/23 20:17 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/30/23 20:17 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/30/23 20:17 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/30/23 20:17 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 11/30/23 20:17 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/30/23 20:17 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 11/30/23 20:17 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/30/23 20:17 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/30/23 20:17 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/30/23 20:17 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/30/23 20:17 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/30/23 20:17 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/30/23 20:17 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/30/23 20:17 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/30/23 20:17 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 11/30/23 20:17 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/30/23 20:17 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/30/23 20:17 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/30/23 20:17 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/30/23 20:17 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. v2 Page 36 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-10B Lab ID: 92699658011 Collected: 11/20/23 12:45 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/17/2024 04:40 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 0.57J ug/L 1.0 0.38 1 11/30/23 20:17 156-59-2 ND ug/L 1.0 0.40 1 11/30/23 20:17 156-60-5 ND ug/L 1.0 0.36 1 11/30/23 20:17 78-87-5 ND ug/L 1.0 0.36 1 11/30/23 20:17 10061-01-5 ND ug/L 1.0 0.36 1 11/30/23 20:17 10061-02-6 ND ug/L 1.0 0.30 1 11/30/23 20:17 100-41-4 ND ug/L 5.0 0.48 1 11/30/23 20:17 591-78-6 ND ug/L 20.0 9.7 1 11/30/23 20:17 74-88-4 v2 ND ug/L 5.0 2.0 1 11/30/23 20:17 75-09-2 ND ug/L 5.0 2.7 1 11/30/23 20:17 108-10-1 ND ug/L 1.0 0.29 1 11/30/23 20:17 100-42-5 ND ug/L 1.0 0.31 1 11/30/23 20:17 630-20-6 ND ug/L 1.0 0.22 1 11/30/23 20:17 79-34-5 ND ug/L 1.0 0.29 1 11/30/23 20:17 127-18-4 ND ug/L 1.0 0.24 1 11/30/23 20:17 108-88-3 ND ug/L 1.0 0.33 1 11/30/23 20:17 71-55-6 ND ug/L 1.0 0.32 1 11/30/23 20:17 79-00-5 ND ug/L 1.0 0.38 1 11/30/23 20:17 79-01-6 ND ug/L 1.0 0.30 1 11/30/23 20:17 75-69-4 ND ug/L 1.0 0.26 1 11/30/23 20:17 96-18-4 ND ug/L 2.0 1.3 1 11/30/23 20:17 108-05-4 ND ug/L 1.0 0.39 1 11/30/23 20:17 75-01-4 ND ug/L 1.0 0.34 1 11/30/23 20:17 1330-20-7 ND ug/L 2.0 0.71 1 11/30/23 20:17 179601-23-1 ND ug/L 1.0 0.34 1 11/30/23 20:17 95-47-6 99 % 70-130 1 11/30/23 20:17 460-00-4 92 % 70-130 1 11/30/23 20:17 17060-07-0 97 % 70-130 1 11/30/23 20:17 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 11/22/23 02:06 123-91-1 90 % 67-130 1 11/22/23 02:06 17060-07-0 93 % 70-130 1 11/22/23 02:06 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 37 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-10C Lab ID: 92699658012 Collected: 11/20/23 11:50 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.6 1 11/22/2311:55 12/08/2319:20 7440-36-0 Arsenic ND ug/L 10.0 2.5 1 11/22/2311:55 12/08/2319:20 7440-38-2 Barium 121 ug/L 5.0 0.79 1 11/22/2311:55 12/08/2319:20 7440-39-3 Beryllium ND ug/L 1.0 0.16 1 11/22/2311:55 12/08/2319:20 7440-41-7 Cadmium ND ug/L 1.0 0.29 1 11/22/2311:55 12/08/2319:20 7440-43-9 Chromium ND ug/L 5.0 0.63 1 11/22/2311:55 12/08/2319:20 7440-47-3 Cobalt ND ug/L 5.0 0.44 1 11/22/2311:55 12/08/2319:20 7440-48-4 Copper ND ug/L 5.0 0.62 1 11/22/2311:55 12/08/2319:20 7440-50-8 Lead ND ug/L 5.0 1.4 1 11/22/2311:55 12/08/2319:20 7439-92-1 Nickel 1.3J ug/L 5.0 0.88 1 11/22/2311:55 12/08/2319:20 7440-02-0 Selenium ND ug/L 10.0 4.1 1 11/22/2311:55 12/08/2319:20 7782-49-2 Silver ND ug/L 5.0 0.49 1 11/22/2311:55 12/08/2319:20 7440-22-4 Vanadium ND ug/L 5.0 1.6 1 11/22/2311:55 12/08/2319:20 7440-62-2 Zinc ND ug/L 10.0 3.0 1 11/22/2311:55 12/08/2319:20 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.20 0.050 1 11/22/23 11:50 11/27/23 00:09 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/30/23 20:34 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/30/23 20:34 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/30/23 20:34 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/30/23 20:34 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/30/23 20:34 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/30/23 20:34 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/30/23 20:34 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/30/23 20:34 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 11/30/23 20:34 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/30/23 20:34 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 11/30/23 20:34 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/30/23 20:34 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/30/23 20:34 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/30/23 20:34 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/30/23 20:34 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/30/23 20:34 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/30/23 20:34 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/30/23 20:34 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/30/23 20:34 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 11/30/23 20:34 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/30/23 20:34 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/30/23 20:34 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/30/23 20:34 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/30/23 20:34 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. v2 Page 38 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-10C Lab ID: 92699658012 Collected: 11/20/23 11:50 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/17/2024 04:40 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 11/30/23 20:34 156-59-2 ND ug/L 1.0 0.40 1 11/30/23 20:34 156-60-5 ND ug/L 1.0 0.36 1 11/30/23 20:34 78-87-5 ND ug/L 1.0 0.36 1 11/30/23 20:34 10061-01-5 ND ug/L 1.0 0.36 1 11/30/23 20:34 10061-02-6 ND ug/L 1.0 0.30 1 11/30/23 20:34 100-41-4 ND ug/L 5.0 0.48 1 11/30/23 20:34 591-78-6 ND ug/L 20.0 9.7 1 11/30/23 20:34 74-88-4 v2 ND ug/L 5.0 2.0 1 11/30/23 20:34 75-09-2 ND ug/L 5.0 2.7 1 11/30/23 20:34 108-10-1 ND ug/L 1.0 0.29 1 11/30/23 20:34 100-42-5 ND ug/L 1.0 0.31 1 11/30/23 20:34 630-20-6 ND ug/L 1.0 0.22 1 11/30/23 20:34 79-34-5 ND ug/L 1.0 0.29 1 11/30/23 20:34 127-18-4 ND ug/L 1.0 0.24 1 11/30/23 20:34 108-88-3 ND ug/L 1.0 0.33 1 11/30/23 20:34 71-55-6 ND ug/L 1.0 0.32 1 11/30/23 20:34 79-00-5 ND ug/L 1.0 0.38 1 11/30/23 20:34 79-01-6 ND ug/L 1.0 0.30 1 11/30/23 20:34 75-69-4 ND ug/L 1.0 0.26 1 11/30/23 20:34 96-18-4 ND ug/L 2.0 1.3 1 11/30/23 20:34 108-05-4 ND ug/L 1.0 0.39 1 11/30/23 20:34 75-01-4 ND ug/L 1.0 0.34 1 11/30/23 20:34 1330-20-7 ND ug/L 2.0 0.71 1 11/30/23 20:34 179601-23-1 ND ug/L 1.0 0.34 1 11/30/23 20:34 95-47-6 101 % 70-130 1 11/30/23 20:34 460-00-4 95 % 70-130 1 11/30/23 20:34 17060-07-0 97 % 70-130 1 11/30/23 20:34 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 11/22/23 02:27 123-91-1 89 % 67-130 1 11/22/23 02:27 17060-07-0 93 % 70-130 1 11/22/23 02:27 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 39 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-10D Lab ID: 92699658013 Collected: 11/20/23 13:40 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.6 1 11/22/2311:55 12/08/2319:23 7440-36-0 Arsenic ND ug/L 10.0 2.5 1 11/22/2311:55 12/08/2319:23 7440-38-2 Barium 182 ug/L 5.0 0.79 1 11/22/2311:55 12/08/2319:23 7440-39-3 Beryllium ND ug/L 1.0 0.16 1 11/22/2311:55 12/08/2319:23 7440-41-7 Cadmium ND ug/L 1.0 0.29 1 11/22/2311:55 12/08/2319:23 7440-43-9 Chromium ND ug/L 5.0 0.63 1 11/22/2311:55 12/08/2319:23 7440-47-3 Cobalt 12.2 ug/L 5.0 0.44 1 11/22/2311:55 12/08/2319:23 7440-48-4 Copper ND ug/L 5.0 0.62 1 11/22/2311:55 12/08/2319:23 7440-50-8 Lead ND ug/L 5.0 1.4 1 11/22/2311:55 12/08/2319:23 7439-92-1 Nickel 4.7J ug/L 5.0 0.88 1 11/22/2311:55 12/08/2319:23 7440-02-0 Selenium ND ug/L 10.0 4.1 1 11/22/2311:55 12/08/2319:23 7782-49-2 Silver ND ug/L 5.0 0.49 1 11/22/2311:55 12/08/2319:23 7440-22-4 Vanadium ND ug/L 5.0 1.6 1 11/22/2311:55 12/08/2319:23 7440-62-2 Zinc ND ug/L 10.0 3.0 1 11/22/2311:55 12/08/2319:23 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.20 0.050 1 11/22/23 11:50 11/27/23 00:14 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/30/23 20:52 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/30/23 20:52 107-13-1 Benzene 0.49J ug/L 1.0 0.34 1 11/30/23 20:52 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/30/23 20:52 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/30/23 20:52 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/30/23 20:52 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/30/23 20:52 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/30/23 20:52 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 11/30/23 20:52 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/30/23 20:52 56-23-5 Chlorobenzene 1.3 ug/L 1.0 0.28 1 11/30/23 20:52 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/30/23 20:52 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/30/23 20:52 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/30/23 20:52 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/30/23 20:52 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/30/23 20:52 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/30/23 20:52 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/30/23 20:52 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/30/23 20:52 95-50-1 1,4-Dichlorobenzene 1.1 ug/L 1.0 0.33 1 11/30/23 20:52 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/30/23 20:52 110-57-6 1,1-Dichloroethane 0.71J ug/L 1.0 0.37 1 11/30/23 20:52 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/30/23 20:52 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/30/23 20:52 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. v2 Page 40 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-10D Lab ID: 92699658013 Collected: 11/20/23 13:40 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/17/2024 04:40 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8.9 ug/L 1.0 0.38 1 11/30/23 20:52 156-59-2 ND ug/L 1.0 0.40 1 11/30/23 20:52 156-60-5 ND ug/L 1.0 0.36 1 11/30/23 20:52 78-87-5 ND ug/L 1.0 0.36 1 11/30/23 20:52 10061-01-5 ND ug/L 1.0 0.36 1 11/30/23 20:52 10061-02-6 ND ug/L 1.0 0.30 1 11/30/23 20:52 100-41-4 ND ug/L 5.0 0.48 1 11/30/23 20:52 591-78-6 ND ug/L 20.0 9.7 1 11/30/23 20:52 74-88-4 ND ug/L 5.0 2.0 1 11/30/23 20:52 75-09-2 ND ug/L 5.0 2.7 1 11/30/23 20:52 108-10-1 ND ug/L 1.0 0.29 1 11/30/23 20:52 100-42-5 ND ug/L 1.0 0.31 1 11/30/23 20:52 630-20-6 ND ug/L 1.0 0.22 1 11/30/23 20:52 79-34-5 0.57J ug/L 1.0 0.29 1 11/30/23 20:52 127-18-4 ND ug/L 1.0 0.24 1 11/30/23 20:52 108-88-3 ND ug/L 1.0 0.33 1 11/30/23 20:52 71-55-6 ND ug/L 1.0 0.32 1 11/30/23 20:52 79-00-5 0.69J ug/L 1.0 0.38 1 11/30/23 20:52 79-01-6 ND ug/L 1.0 0.30 1 11/30/23 20:52 75-69-4 ND ug/L 1.0 0.26 1 11/30/23 20:52 96-18-4 ND ug/L 2.0 1.3 1 11/30/23 20:52 108-05-4 ND ug/L 1.0 0.39 1 11/30/23 20:52 75-01-4 ND ug/L 1.0 0.34 1 11/30/23 20:52 1330-20-7 ND ug/L 2.0 0.71 1 11/30/23 20:52 179601-23-1 ND ug/L 1.0 0.34 1 11/30/23 20:52 95-47-6 101 % 70-130 1 11/30/23 20:52 460-00-4 93 % 70-130 1 11/30/23 20:52 17060-07-0 98 % 70-130 1 11/30/23 20:52 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 11/22/23 02:49 123-91-1 89 % 67-130 1 11/22/23 02:49 17060-07-0 92 % 70-130 1 11/22/23 02:49 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 41 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-11A Lab ID: 92699658014 Collected: 11/20/23 12:25 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.6 1 11/22/2311:55 12/08/2319:37 7440-36-0 Arsenic ND ug/L 10.0 2.5 1 11/22/2311:55 12/08/2319:37 7440-38-2 Barium 116 ug/L 5.0 0.79 1 11/22/2311:55 12/08/2319:37 7440-39-3 Beryllium ND ug/L 1.0 0.16 1 11/22/2311:55 12/08/2319:37 7440-41-7 Cadmium ND ug/L 1.0 0.29 1 11/22/2311:55 12/08/2319:37 7440-43-9 Chromium 1.3J ug/L 5.0 0.63 1 11/22/2311:55 12/08/2319:37 7440-47-3 Cobalt 0.49J ug/L 5.0 0.44 1 11/22/2311:55 12/08/2319:37 7440-48-4 Copper ND ug/L 5.0 0.62 1 11/22/2311:55 12/08/2319:37 7440-50-8 Lead ND ug/L 5.0 1.4 1 11/22/2311:55 12/08/2319:37 7439-92-1 Nickel 3.3J ug/L 5.0 0.88 1 11/22/2311:55 12/08/2319:37 7440-02-0 Selenium ND ug/L 10.0 4.1 1 11/22/2311:55 12/08/2319:37 7782-49-2 Silver ND ug/L 5.0 0.49 1 11/22/2311:55 12/08/2319:37 7440-22-4 Vanadium ND ug/L 5.0 1.6 1 11/22/2311:55 12/08/2319:37 7440-62-2 Zinc ND ug/L 10.0 3.0 1 11/22/2311:55 12/08/2319:37 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.20 0.050 1 11/22/23 11:50 11/27/23 00:19 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/30/23 21:10 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/30/23 21:10 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/30/23 21:10 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/30/23 21:10 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/30/23 21:10 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/30/23 21:10 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/30/23 21:10 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/30/23 21:10 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 11/30/23 21:10 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/30/23 21:10 56-23-5 Chlorobenzene 2.6 ug/L 1.0 0.28 1 11/30/23 21:10 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/30/23 21:10 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/30/23 21:10 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/30/23 21:10 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/30/23 21:10 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/30/23 21:10 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/30/23 21:10 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/30/23 21:10 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/30/23 21:10 95-50-1 1,4-Dichlorobenzene 1.4 ug/L 1.0 0.33 1 11/30/23 21:10 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/30/23 21:10 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/30/23 21:10 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/30/23 21:10 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/30/23 21:10 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. v2 Page 42 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-11A Lab ID: 92699658014 Collected: 11/20/23 12:25 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/17/2024 04:40 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 11/30/23 21:10 156-59-2 ND ug/L 1.0 0.40 1 11/30/23 21:10 156-60-5 ND ug/L 1.0 0.36 1 11/30/23 21:10 78-87-5 ND ug/L 1.0 0.36 1 11/30/23 21:10 10061-01-5 ND ug/L 1.0 0.36 1 11/30/23 21:10 10061-02-6 ND ug/L 1.0 0.30 1 11/30/23 21:10 100-41-4 ND ug/L 5.0 0.48 1 11/30/23 21:10 591-78-6 ND ug/L 20.0 9.7 1 11/30/23 21:10 74-88-4 ND ug/L 5.0 2.0 1 11/30/23 21:10 75-09-2 ND ug/L 5.0 2.7 1 11/30/23 21:10 108-10-1 ND ug/L 1.0 0.29 1 11/30/23 21:10 100-42-5 ND ug/L 1.0 0.31 1 11/30/23 21:10 630-20-6 ND ug/L 1.0 0.22 1 11/30/23 21:10 79-34-5 ND ug/L 1.0 0.29 1 11/30/23 21:10 127-18-4 ND ug/L 1.0 0.24 1 11/30/23 21:10 108-88-3 ND ug/L 1.0 0.33 1 11/30/23 21:10 71-55-6 ND ug/L 1.0 0.32 1 11/30/23 21:10 79-00-5 ND ug/L 1.0 0.38 1 11/30/23 21:10 79-01-6 ND ug/L 1.0 0.30 1 11/30/23 21:10 75-69-4 ND ug/L 1.0 0.26 1 11/30/23 21:10 96-18-4 ND ug/L 2.0 1.3 1 11/30/23 21:10 108-05-4 ND ug/L 1.0 0.39 1 11/30/23 21:10 75-01-4 ND ug/L 1.0 0.34 1 11/30/23 21:10 1330-20-7 ND ug/L 2.0 0.71 1 11/30/23 21:10 179601-23-1 ND ug/L 1.0 0.34 1 11/30/23 21:10 95-47-6 101 % 70-130 1 11/30/23 21:10 460-00-4 92 % 70-130 1 11/30/23 21:10 17060-07-0 96 % 70-130 1 11/30/23 21:10 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 15.8 ug/L 2.0 0.86 1 11/22/23 03:10 123-91-1 89 % 67-130 1 11/22/23 03:10 17060-07-0 92 % 70-130 1 11/22/23 03:10 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 43 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-11B Lab ID: 92699658015 Collected: 11/20/23 13:25 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.6 1 11/22/2311:55 12/08/2319:40 7440-36-0 Arsenic ND ug/L 10.0 2.5 1 11/22/2311:55 12/08/2319:40 7440-38-2 Barium 94.5 ug/L 5.0 0.79 1 11/22/2311:55 12/08/2319:40 7440-39-3 Beryllium ND ug/L 1.0 0.16 1 11/22/2311:55 12/08/2319:40 7440-41-7 Cadmium ND ug/L 1.0 0.29 1 11/22/2311:55 12/08/2319:40 7440-43-9 Chromium 3.8J ug/L 5.0 0.63 1 11/22/2311:55 12/08/2319:40 7440-47-3 Cobalt ND ug/L 5.0 0.44 1 11/22/2311:55 12/08/2319:40 7440-48-4 Copper ND ug/L 5.0 0.62 1 11/22/2311:55 12/08/2319:40 7440-50-8 Lead ND ug/L 5.0 1.4 1 11/22/2311:55 12/08/2319:40 7439-92-1 Nickel 1.6J ug/L 5.0 0.88 1 11/22/2311:55 12/08/2319:40 7440-02-0 Selenium ND ug/L 10.0 4.1 1 11/22/2311:55 12/08/2319:40 7782-49-2 Silver ND ug/L 5.0 0.49 1 11/22/2311:55 12/08/2319:40 7440-22-4 Vanadium ND ug/L 5.0 1.6 1 11/22/2311:55 12/08/2319:40 7440-62-2 Zinc 5.OJ ug/L 10.0 3.0 1 11/22/2311:55 12/08/2319:40 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.20 0.050 1 11/22/23 11:50 11/27/23 00:24 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/30/23 21:28 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/30/23 21:28 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/30/23 21:28 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/30/23 21:28 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/30/23 21:28 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/30/23 21:28 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/30/23 21:28 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/30/23 21:28 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 11/30/23 21:28 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/30/23 21:28 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 11/30/23 21:28 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/30/23 21:28 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/30/23 21:28 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/30/23 21:28 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/30/23 21:28 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/30/23 21:28 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/30/23 21:28 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/30/23 21:28 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/30/23 21:28 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 11/30/23 21:28 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/30/23 21:28 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/30/23 21:28 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/30/23 21:28 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/30/23 21:28 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. v2 Page 44 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-11B Lab ID: 92699658015 Collected: 11/20/23 13:25 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/17/2024 04:40 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 11/30/23 21:28 156-59-2 ND ug/L 1.0 0.40 1 11/30/23 21:28 156-60-5 ND ug/L 1.0 0.36 1 11/30/23 21:28 78-87-5 ND ug/L 1.0 0.36 1 11/30/23 21:28 10061-01-5 ND ug/L 1.0 0.36 1 11/30/23 21:28 10061-02-6 ND ug/L 1.0 0.30 1 11/30/23 21:28 100-41-4 ND ug/L 5.0 0.48 1 11/30/23 21:28 591-78-6 ND ug/L 20.0 9.7 1 11/30/23 21:28 74-88-4 ND ug/L 5.0 2.0 1 11/30/23 21:28 75-09-2 ND ug/L 5.0 2.7 1 11/30/23 21:28 108-10-1 ND ug/L 1.0 0.29 1 11/30/23 21:28 100-42-5 ND ug/L 1.0 0.31 1 11/30/23 21:28 630-20-6 ND ug/L 1.0 0.22 1 11/30/23 21:28 79-34-5 ND ug/L 1.0 0.29 1 11/30/23 21:28 127-18-4 ND ug/L 1.0 0.24 1 11/30/23 21:28 108-88-3 ND ug/L 1.0 0.33 1 11/30/23 21:28 71-55-6 ND ug/L 1.0 0.32 1 11/30/23 21:28 79-00-5 ND ug/L 1.0 0.38 1 11/30/23 21:28 79-01-6 ND ug/L 1.0 0.30 1 11/30/23 21:28 75-69-4 ND ug/L 1.0 0.26 1 11/30/23 21:28 96-18-4 ND ug/L 2.0 1.3 1 11/30/23 21:28 108-05-4 ND ug/L 1.0 0.39 1 11/30/23 21:28 75-01-4 ND ug/L 1.0 0.34 1 11/30/23 21:28 1330-20-7 ND ug/L 2.0 0.71 1 11/30/23 21:28 179601-23-1 ND ug/L 1.0 0.34 1 11/30/23 21:28 95-47-6 99 % 70-130 1 11/30/23 21:28 460-00-4 91 % 70-130 1 11/30/23 21:28 17060-07-0 98 % 70-130 1 11/30/23 21:28 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 2.0 ug/L 2.0 0.86 1 11/22/23 03:31 123-91-1 89 % 67-130 1 11/22/23 03:31 17060-07-0 92 % 70-130 1 11/22/23 03:31 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 45 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-Duplicate Lab ID: 92699658016 Collected: 11/20/23 15:50 Received: 11/21/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Date: 01/17/2024 04:40 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 5.1 1 11/30/23 21:45 67-64-1 ND ug/L 10.0 1.8 1 11/30/23 21:45 107-13-1 ND ug/L 1.0 0.34 1 11/30/23 21:45 71-43-2 ND ug/L 1.0 0.47 1 11/30/23 21:45 74-97-5 ND ug/L 1.0 0.31 1 11/30/23 21:45 75-27-4 ND ug/L 1.0 0.34 1 11/30/23 21:45 75-25-2 ND ug/L 2.0 1.7 1 11/30/23 21:45 74-83-9 v2 ND ug/L 5.0 4.0 1 11/30/23 21:45 78-93-3 ND ug/L 2.0 0.36 1 11/30/23 21:45 75-15-0 ND ug/L 1.0 0.33 1 11/30/23 21:45 56-23-5 ND ug/L 1.0 0.28 1 11/30/23 21:45 108-90-7 ND ug/L 1.0 0.65 1 11/30/23 21:45 75-00-3 ND ug/L 1.0 0.43 1 11/30/23 21:45 67-66-3 ND ug/L 1.0 0.54 1 11/30/23 21:45 74-87-3 ND ug/L 2.0 0.34 1 11/30/23 21:45 96-12-8 ND ug/L 1.0 0.36 1 11/30/23 21:45 124-48-1 ND ug/L 1.0 0.27 1 11/30/23 21:45 106-93-4 ND ug/L 1.0 0.39 1 11/30/23 21:45 74-95-3 ND ug/L 1.0 0.34 1 11/30/23 21:45 95-50-1 ND ug/L 1.0 0.33 1 11/30/23 21:45 106-46-7 ND ug/L 1.0 0.56 1 11/30/23 21:45 110-57-6 ND ug/L 1.0 0.37 1 11/30/23 21:45 75-34-3 ND ug/L 1.0 0.32 1 11/30/23 21:45 107-06-2 ND ug/L 1.0 0.35 1 11/30/23 21:45 75-35-4 ND ug/L 1.0 0.38 1 11/30/23 21:45 156-59-2 ND ug/L 1.0 0.40 1 11/30/23 21:45 156-60-5 ND ug/L 1.0 0.36 1 11/30/23 21:45 78-87-5 ND ug/L 1.0 0.36 1 11/30/23 21:45 10061-01-5 ND ug/L 1.0 0.36 1 11/30/23 21:45 10061-02-6 ND ug/L 1.0 0.30 1 11/30/23 21:45 100-41-4 ND ug/L 5.0 0.48 1 11/30/23 21:45 591-78-6 ND ug/L 20.0 9.7 1 11/30/23 21:45 74-88-4 ND ug/L 5.0 2.0 1 11/30/23 21:45 75-09-2 ND ug/L 5.0 2.7 1 11/30/23 21:45 108-10-1 ND ug/L 1.0 0.29 1 11/30/23 21:45 100-42-5 ND ug/L 1.0 0.31 1 11/30/23 21:45 630-20-6 ND ug/L 1.0 0.22 1 11/30/23 21:45 79-34-5 ND ug/L 1.0 0.29 1 11/30/23 21:45 127-18-4 ND ug/L 1.0 0.24 1 11/30/23 21:45 108-88-3 ND ug/L 1.0 0.33 1 11/30/23 21:45 71-55-6 ND ug/L 1.0 0.32 1 11/30/23 21:45 79-00-5 ND ug/L 1.0 0.38 1 11/30/23 21:45 79-01-6 ND ug/L 1.0 0.30 1 11/30/23 21:45 75-69-4 ND ug/L 1.0 0.26 1 11/30/23 21:45 96-18-4 ND ug/L 2.0 1.3 1 11/30/23 21:45 108-05-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 46 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-Duplicate Parameters Lab ID: Results 92699658016 Units Collected: Report Limit 11/20/23 15:50 MDL DF Received: 11/21/23 08:00 Matrix: Water Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Vinyl chloride ND ug/L 1.0 0.39 1 11/30/23 21:45 75-01-4 Xylene (Total) ND ug/L 1.0 0.34 1 11/30/23 21:45 1330-20-7 m&p-Xylene ND ug/L 2.0 0.71 1 11/30/23 21:45 179601-23-1 o-Xylene ND ug/L 1.0 0.34 1 11/30/23 21:45 95-47-6 Surrogates 4-Bromofluorobenzene (S) 101 % 70-130 1 11/30/23 21:45 460-00-4 1,2-Dichloroethane-d4 (S) 95 % 70-130 1 11/30/23 21:45 17060-07-0 Toluene-d8 (S) 98 % 70-130 1 11/30/23 21:45 2037-26-5 Date: 01/17/2024 04:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 47 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-12 Lab ID: 92699658017 Collected: 11/28/23 15:10 Received: 11/29/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Aluminum 118 ug/L 100 10.3 1 11/30/2312:45 12/19/2316:23 7429-90-5 Antimony ND ug/L 5.0 3.6 1 11/30/2312:45 12/19/2316:23 7440-36-0 Arsenic ND ug/L 10.0 2.5 1 11/30/2312:45 12/19/2316:23 7440-38-2 Barium 103 ug/L 5.0 0.79 1 11/30/2312:45 12/18/2317:09 7440-39-3 Beryllium ND ug/L 1.0 0.16 1 11/30/2312:45 12/18/2317:09 7440-41-7 Cadmium ND ug/L 1.0 0.29 1 11/30/2312:45 12/19/2316:23 7440-43-9 Chromium 1.3J ug/L 5.0 0.63 1 11/30/2312:45 12/18/2317:09 7440-47-3 Cobalt ND ug/L 5.0 0.44 1 11/30/2312:45 12/18/2317:09 7440-48-4 Copper 4.6J ug/L 5.0 0.62 1 11/30/2312:45 12/19/2316:23 7440-50-8 Iron 226 ug/L 50.0 8.9 1 11/30/2312:45 12/18/2317:09 7439-89-6 Lead ND ug/L 5.0 1.4 1 11/30/2312:45 12/19/2316:23 7439-92-1 Manganese 82.8 ug/L 5.0 0.86 1 11/30/2312:45 12/18/2317:09 7439-96-5 Nickel 1.6J ug/L 5.0 0.88 1 11/30/2312:45 12/18/2317:09 7440-02-0 Selenium ND ug/L 10.0 4.1 1 11/30/2312:45 12/19/2316:23 7782-49-2 Silver ND ug/L 5.0 0.49 1 11/30/2312:45 12/18/2317:09 7440-22-4 Vanadium ND ug/L 5.0 1.6 1 11/30/2312:45 12/18/2317:09 7440-62-2 Zinc 4.2J ug/L 10.0 3.0 1 11/30/2312:45 12/18/2317:09 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.20 0.050 1 11/30/23 12:50 11/30/23 22:02 7440-28-0 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Date: 01/17/2024 04:40 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 12/05/23 09:48 12/06/23 12:22 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 5.1 1 12/05/23 07:46 67-64-1 1.8 1 12/05/23 07:46 107-13-1 0.34 1 12/05/23 07:46 71-43-2 0.47 1 12/05/23 07:46 74-97-5 0.31 1 12/05/23 07:46 75-27-4 0.34 1 12/05/23 07:46 75-25-2 1.7 1 12/05/23 07:46 74-83-9 4.0 1 12/05/23 07:46 78-93-3 0.36 1 12/05/23 07:46 75-15-0 0.33 1 12/05/23 07:46 56-23-5 0.28 1 12/05/23 07:46 108-90-7 0.65 1 12/05/23 07:46 75-00-3 0.43 1 12/05/23 07:46 67-66-3 0.54 1 12/05/23 07:46 74-87-3 0.34 1 12/05/23 07:46 96-12-8 0.36 1 12/05/23 07:46 124-48-1 0.27 1 12/05/23 07:46 106-93-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 48 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-12 Lab ID: 92699658017 Collected: 11/28/23 15:10 Received: 11/29/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) E:Y*-:11]H�46yTAyI�4 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/17/2024 04:40 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.39 1 12/05/23 07:46 74-95-3 ND ug/L 1.0 0.34 1 12/05/23 07:46 95-50-1 ND ug/L 1.0 0.33 1 12/05/23 07:46 106-46-7 ND ug/L 1.0 0.56 1 12/05/23 07:46 110-57-6 ND ug/L 1.0 0.37 1 12/05/23 07:46 75-34-3 ND ug/L 1.0 0.32 1 12/05/23 07:46 107-06-2 ND ug/L 1.0 0.35 1 12/05/23 07:46 75-35-4 ND ug/L 1.0 0.38 1 12/05/23 07:46 156-59-2 ND ug/L 1.0 0.40 1 12/05/23 07:46 156-60-5 ND ug/L 1.0 0.36 1 12/05/23 07:46 78-87-5 ND ug/L 1.0 0.36 1 12/05/23 07:46 10061-01-5 ND ug/L 1.0 0.36 1 12/05/23 07:46 10061-02-6 ND ug/L 1.0 0.30 1 12/05/23 07:46 100-41-4 ND ug/L 5.0 0.48 1 12/05/23 07:46 591-78-6 ND ug/L 20.0 9.7 1 12/05/23 07:46 74-88-4 ND ug/L 5.0 2.0 1 12/05/23 07:46 75-09-2 ND ug/L 5.0 2.7 1 12/05/23 07:46 108-10-1 ND ug/L 1.0 0.29 1 12/05/23 07:46 100-42-5 ND ug/L 1.0 0.31 1 12/05/23 07:46 630-20-6 ND ug/L 1.0 0.22 1 12/05/23 07:46 79-34-5 ND ug/L 1.0 0.29 1 12/05/23 07:46 127-18-4 ND ug/L 10.0 3.5 1 12/05/23 07:46 109-99-9 ND ug/L 1.0 0.24 1 12/05/23 07:46 108-88-3 ND ug/L 1.0 0.33 1 12/05/23 07:46 71-55-6 ND ug/L 1.0 0.32 1 12/05/23 07:46 79-00-5 ND ug/L 1.0 0.38 1 12/05/23 07:46 79-01-6 ND ug/L 1.0 0.30 1 12/05/23 07:46 75-69-4 ND ug/L 1.0 0.26 1 12/05/23 07:46 96-18-4 ND ug/L 2.0 1.3 1 12/05/23 07:46 108-05-4 ND ug/L 1.0 0.39 1 12/05/23 07:46 75-01-4 ND ug/L 1.0 0.34 1 12/05/23 07:46 1330-20-7 ND ug/L 2.0 0.71 1 12/05/23 07:46 179601-23-1 ND ug/L 1.0 0.34 1 12/05/23 07:46 95-47-6 102 % 70-130 1 12/05/23 07:46 460-00-4 120 % 70-130 1 12/05/23 07:46 17060-07-0 98 % 70-130 1 12/05/23 07:46 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 11/30/23 22:44 123-91-1 105 % 67-130 1 11/30/23 22:44 17060-07-0 102 % 70-130 1 11/30/23 22:44 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 49 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-12 Lab ID: 92699658017 Collected: 11/28/23 15:10 Received: 11/29/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2320B Alkalinity Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville Alkalinity, Total as CaCO3 247 mg/L 5.0 5.0 1 12/06/23 08:16 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 265 mg/L 25.0 25.0 1 11/30/23 17:41 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Chloride 6.6 mg/L 1.0 0.60 1 12/01/23 00:45 16887-00-6 Sulfate 5.2 mg/L 1.0 0.50 1 12/01/23 00:45 14808-79-8 Date: 01/17/2024 04:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 50 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-14 Lab ID: 92699658018 Collected: 11/28/23 13:05 Received: 11/29/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Aluminum 66.5J ug/L 100 10.3 1 11/30/2312:45 12/19/2316:35 7429-90-5 Antimony ND ug/L 5.0 3.6 1 11/30/2312:45 12/19/2316:35 7440-36-0 Arsenic ND ug/L 10.0 2.5 1 11/30/2312:45 12/19/2316:35 7440-38-2 Barium 136 ug/L 5.0 0.79 1 11/30/2312:45 12/18/2317:32 7440-39-3 Beryllium ND ug/L 1.0 0.16 1 11/30/2312:45 12/18/2317:32 7440-41-7 Cadmium ND ug/L 1.0 0.29 1 11/30/2312:45 12/19/2316:35 7440-43-9 Chromium ND ug/L 5.0 0.63 1 11/30/2312:45 12/18/2317:32 7440-47-3 Cobalt ND ug/L 5.0 0.44 1 11/30/2312:45 12/18/2317:32 7440-48-4 Copper 0.71J ug/L 5.0 0.62 1 11/30/2312:45 12/19/2316:35 7440-50-8 Iron 78.2 ug/L 50.0 8.9 1 11/30/2312:45 12/18/2317:32 7439-89-6 Lead ND ug/L 5.0 1.4 1 11/30/2312:45 12/19/2316:35 7439-92-1 Manganese 78.3 ug/L 5.0 0.86 1 11/30/2312:45 12/18/2317:32 7439-96-5 Nickel ND ug/L 5.0 0.88 1 11/30/2312:45 12/18/2317:32 7440-02-0 Selenium ND ug/L 10.0 4.1 1 11/30/2312:45 12/19/2316:35 7782-49-2 Silver ND ug/L 5.0 0.49 1 11/30/2312:45 12/18/2317:32 7440-22-4 Vanadium ND ug/L 5.0 1.6 1 11/30/2312:45 12/18/2317:32 7440-62-2 Zinc ND ug/L 10.0 3.0 1 11/30/2312:45 12/18/2317:32 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.20 0.050 1 11/30/23 12:50 11/30/23 22:07 7440-28-0 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Date: 01/17/2024 04:40 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 12/05/23 09:48 12/06/23 12:24 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 5.1 1 12/05/23 08:04 67-64-1 1.8 1 12/05/23 08:04 107-13-1 0.34 1 12/05/23 08:04 71-43-2 0.47 1 12/05/23 08:04 74-97-5 0.31 1 12/05/23 08:04 75-27-4 0.34 1 12/05/23 08:04 75-25-2 1.7 1 12/05/23 08:04 74-83-9 4.0 1 12/05/23 08:04 78-93-3 0.36 1 12/05/23 08:04 75-15-0 0.33 1 12/05/23 08:04 56-23-5 0.28 1 12/05/23 08:04 108-90-7 0.65 1 12/05/23 08:04 75-00-3 0.43 1 12/05/23 08:04 67-66-3 0.54 1 12/05/23 08:04 74-87-3 0.34 1 12/05/23 08:04 96-12-8 0.36 1 12/05/23 08:04 124-48-1 0.27 1 12/05/23 08:04 106-93-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 51 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-14 Lab ID: 92699658018 Collected: 11/28/23 13:05 Received: 11/29/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) E:Y*-:11]H�46yTAyI�4 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/17/2024 04:40 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.39 1 12/05/23 08:04 74-95-3 ND ug/L 1.0 0.34 1 12/05/23 08:04 95-50-1 ND ug/L 1.0 0.33 1 12/05/23 08:04 106-46-7 ND ug/L 1.0 0.56 1 12/05/23 08:04 110-57-6 ND ug/L 1.0 0.37 1 12/05/23 08:04 75-34-3 ND ug/L 1.0 0.32 1 12/05/23 08:04 107-06-2 ND ug/L 1.0 0.35 1 12/05/23 08:04 75-35-4 0.49J ug/L 1.0 0.38 1 12/05/23 08:04 156-59-2 ND ug/L 1.0 0.40 1 12/05/23 08:04 156-60-5 ND ug/L 1.0 0.36 1 12/05/23 08:04 78-87-5 ND ug/L 1.0 0.36 1 12/05/23 08:04 10061-01-5 ND ug/L 1.0 0.36 1 12/05/23 08:04 10061-02-6 ND ug/L 1.0 0.30 1 12/05/23 08:04 100-41-4 ND ug/L 5.0 0.48 1 12/05/23 08:04 591-78-6 ND ug/L 20.0 9.7 1 12/05/23 08:04 74-88-4 ND ug/L 5.0 2.0 1 12/05/23 08:04 75-09-2 ND ug/L 5.0 2.7 1 12/05/23 08:04 108-10-1 ND ug/L 1.0 0.29 1 12/05/23 08:04 100-42-5 ND ug/L 1.0 0.31 1 12/05/23 08:04 630-20-6 ND ug/L 1.0 0.22 1 12/05/23 08:04 79-34-5 ND ug/L 1.0 0.29 1 12/05/23 08:04 127-18-4 ND ug/L 10.0 3.5 1 12/05/23 08:04 109-99-9 ND ug/L 1.0 0.24 1 12/05/23 08:04 108-88-3 ND ug/L 1.0 0.33 1 12/05/23 08:04 71-55-6 ND ug/L 1.0 0.32 1 12/05/23 08:04 79-00-5 ND ug/L 1.0 0.38 1 12/05/23 08:04 79-01-6 ND ug/L 1.0 0.30 1 12/05/23 08:04 75-69-4 ND ug/L 1.0 0.26 1 12/05/23 08:04 96-18-4 ND ug/L 2.0 1.3 1 12/05/23 08:04 108-05-4 ND ug/L 1.0 0.39 1 12/05/23 08:04 75-01-4 ND ug/L 1.0 0.34 1 12/05/23 08:04 1330-20-7 ND ug/L 2.0 0.71 1 12/05/23 08:04 179601-23-1 ND ug/L 1.0 0.34 1 12/05/23 08:04 95-47-6 99 % 70-130 1 12/05/23 08:04 460-00-4 125 % 70-130 1 12/05/23 08:04 17060-07-0 97 % 70-130 1 12/05/23 08:04 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 2.6 ug/L 2.0 0.86 1 11/30/23 23:05 123-91-1 101 % 67-130 1 11/30/23 23:05 17060-07-0 101 % 70-130 1 11/30/23 23:05 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 52 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-14 Lab ID: 92699658018 Collected: 11/28/23 13:05 Received: 11/29/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2320B Alkalinity Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville Alkalinity, Total as CaCO3 89.5 mg/L 5.0 5.0 1 12/05/23 21:28 2540C Total Dissolved Solids Analytical Method: SM 254OC-2015 Pace Analytical Services -Asheville Total Dissolved Solids 176 mg/L 25.0 25.0 1 11/30/23 17:41 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Chloride 8.7 mg/L 1.0 0.60 1 12/01/23 00:59 16887-00-6 Sulfate 46.0 mg/L 1.0 0.50 1 12/01/23 00:59 14808-79-8 Date: 01/17/2024 04:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 53 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-16 Lab ID: 92699658019 Collected: 11/28/23 11:25 Received: 11/29/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Aluminum 35.8J ug/L 100 10.3 1 11/30/2312:45 12/19/2316:37 7429-90-5 Antimony ND ug/L 5.0 3.6 1 11/30/2312:45 12/19/2316:37 7440-36-0 Arsenic ND ug/L 10.0 2.5 1 11/30/2312:45 12/19/2316:37 7440-38-2 Barium 81.3 ug/L 5.0 0.79 1 11/30/2312:45 12/18/2317:34 7440-39-3 Beryllium ND ug/L 1.0 0.16 1 11/30/2312:45 12/18/2317:34 7440-41-7 Cadmium ND ug/L 1.0 0.29 1 11/30/2312:45 12/19/2316:37 7440-43-9 Chromium ND ug/L 5.0 0.63 1 11/30/2312:45 12/18/2317:34 7440-47-3 Cobalt ND ug/L 5.0 0.44 1 11/30/2312:45 12/18/2317:34 7440-48-4 Copper 0.64J ug/L 5.0 0.62 1 11/30/2312:45 12/19/2316:37 7440-50-8 Iron 3470 ug/L 50.0 8.9 1 11/30/2312:45 12/18/2317:34 7439-89-6 Lead ND ug/L 5.0 1.4 1 11/30/2312:45 12/19/2316:37 7439-92-1 Manganese 2110 ug/L 5.0 0.86 1 11/30/2312:45 12/18/2317:34 7439-96-5 Nickel ND ug/L 5.0 0.88 1 11/30/2312:45 12/18/2317:34 7440-02-0 Selenium ND ug/L 10.0 4.1 1 11/30/2312:45 12/19/2316:37 7782-49-2 Silver ND ug/L 5.0 0.49 1 11/30/2312:45 12/18/2317:34 7440-22-4 Vanadium ND ug/L 5.0 1.6 1 11/30/2312:45 12/18/2317:34 7440-62-2 Zinc ND ug/L 10.0 3.0 1 11/30/2312:45 12/18/2317:34 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.20 0.050 1 11/30/23 12:50 11/30/23 22:12 7440-28-0 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Date: 01/17/2024 04:40 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 12/05/23 09:48 12/06/23 12:31 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 5.1 1 12/05/23 09:30 67-64-1 1.8 1 12/05/23 09:30 107-13-1 0.34 1 12/05/23 09:30 71-43-2 0.47 1 12/05/23 09:30 74-97-5 0.31 1 12/05/23 09:30 75-27-4 0.34 1 12/05/23 09:30 75-25-2 1.7 1 12/05/23 09:30 74-83-9 4.0 1 12/05/23 09:30 78-93-3 0.36 1 12/05/23 09:30 75-15-0 0.33 1 12/05/23 09:30 56-23-5 0.28 1 12/05/23 09:30 108-90-7 0.65 1 12/05/23 09:30 75-00-3 0.43 1 12/05/23 09:30 67-66-3 0.54 1 12/05/23 09:30 74-87-3 0.34 1 12/05/23 09:30 96-12-8 0.36 1 12/05/23 09:30 124-48-1 0.27 1 12/05/23 09:30 106-93-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 54 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-16 Lab ID: 92699658019 Collected: 11/28/23 11:25 Received: 11/29/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) E:Y*-:11]H�46yTAyI�4 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/17/2024 04:40 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.39 1 12/05/23 09:30 74-95-3 ND ug/L 1.0 0.34 1 12/05/23 09:30 95-50-1 ND ug/L 1.0 0.33 1 12/05/23 09:30 106-46-7 ND ug/L 1.0 0.56 1 12/05/23 09:30 110-57-6 ND ug/L 1.0 0.37 1 12/05/23 09:30 75-34-3 ND ug/L 1.0 0.32 1 12/05/23 09:30 107-06-2 ND ug/L 1.0 0.35 1 12/05/23 09:30 75-35-4 ND ug/L 1.0 0.38 1 12/05/23 09:30 156-59-2 ND ug/L 1.0 0.40 1 12/05/23 09:30 156-60-5 ND ug/L 1.0 0.36 1 12/05/23 09:30 78-87-5 ND ug/L 1.0 0.36 1 12/05/23 09:30 10061-01-5 ND ug/L 1.0 0.36 1 12/05/23 09:30 10061-02-6 ND ug/L 1.0 0.30 1 12/05/23 09:30 100-41-4 ND ug/L 5.0 0.48 1 12/05/23 09:30 591-78-6 ND ug/L 20.0 9.7 1 12/05/23 09:30 74-88-4 ND ug/L 5.0 2.0 1 12/05/23 09:30 75-09-2 ND ug/L 5.0 2.7 1 12/05/23 09:30 108-10-1 ND ug/L 1.0 0.29 1 12/05/23 09:30 100-42-5 ND ug/L 1.0 0.31 1 12/05/23 09:30 630-20-6 ND ug/L 1.0 0.22 1 12/05/23 09:30 79-34-5 ND ug/L 1.0 0.29 1 12/05/23 09:30 127-18-4 ND ug/L 10.0 3.5 1 12/05/23 09:30 109-99-9 ND ug/L 1.0 0.24 1 12/05/23 09:30 108-88-3 ND ug/L 1.0 0.33 1 12/05/23 09:30 71-55-6 ND ug/L 1.0 0.32 1 12/05/23 09:30 79-00-5 ND ug/L 1.0 0.38 1 12/05/23 09:30 79-01-6 ND ug/L 1.0 0.30 1 12/05/23 09:30 75-69-4 ND ug/L 1.0 0.26 1 12/05/23 09:30 96-18-4 ND ug/L 2.0 1.3 1 12/05/23 09:30 108-05-4 ND ug/L 1.0 0.39 1 12/05/23 09:30 75-01-4 ND ug/L 1.0 0.34 1 12/05/23 09:30 1330-20-7 ND ug/L 2.0 0.71 1 12/05/23 09:30 179601-23-1 ND ug/L 1.0 0.34 1 12/05/23 09:30 95-47-6 99 % 70-130 1 12/05/23 09:30 460-00-4 99 % 70-130 1 12/05/23 09:30 17060-07-0 103 % 70-130 1 12/05/23 09:30 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 11/30/23 23:26 123-91-1 104 % 67-130 1 11/30/23 23:26 17060-07-0 101 % 70-130 1 11/30/23 23:26 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 55 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-16 Lab ID: 92699658019 Collected: 11/28/23 11:25 Received: 11/29/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2320B Alkalinity Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville Alkalinity, Total as CaCO3 390 mg/L 5.0 5.0 1 12/06/23 08:25 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 417 mg/L 25.0 25.0 1 11/30/23 17:41 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Chloride 6.1 mg/L 1.0 0.60 1 12/01/2315:26 16887-00-6 Sulfate 5.4 mg/L 1.0 0.50 1 12/01/2315:26 14808-79-8 Date: 01/17/2024 04:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 56 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-SW-6 Lab ID: 92699658020 Collected: 11/28/23 13:50 Received: 11/29/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Aluminum 59.OJ ug/L 100 10.3 1 11/30/2312:45 12/19/2316:40 7429-90-5 Antimony ND ug/L 5.0 3.6 1 11/30/2312:45 12/19/2316:40 7440-36-0 Arsenic ND ug/L 10.0 2.5 1 11/30/2312:45 12/19/2316:40 7440-38-2 Barium 31.6 ug/L 5.0 0.79 1 11/30/2312:45 12/18/2317:37 7440-39-3 Beryllium ND ug/L 1.0 0.16 1 11/30/2312:45 12/18/2317:37 7440-41-7 Cadmium ND ug/L 1.0 0.29 1 11/30/2312:45 12/19/2316:40 7440-43-9 Chromium 1.3J ug/L 5.0 0.63 1 11/30/2312:45 12/18/2317:37 7440-47-3 Cobalt ND ug/L 5.0 0.44 1 11/30/2312:45 12/18/2317:37 7440-48-4 Copper 0.73J ug/L 5.0 0.62 1 11/30/2312:45 12/19/2316:40 7440-50-8 Iron 253 ug/L 50.0 8.9 1 11/30/2312:45 12/18/2317:37 7439-89-6 Lead ND ug/L 5.0 1.4 1 11/30/2312:45 12/19/2316:40 7439-92-1 Manganese 37.4 ug/L 5.0 0.86 1 11/30/2312:45 12/18/2317:37 7439-96-5 Nickel ND ug/L 5.0 0.88 1 11/30/2312:45 12/18/2317:37 7440-02-0 Selenium ND ug/L 10.0 4.1 1 11/30/2312:45 12/19/2316:40 7782-49-2 Silver ND ug/L 5.0 0.49 1 11/30/2312:45 12/18/2317:37 7440-22-4 Vanadium ND ug/L 5.0 1.6 1 11/30/2312:45 12/18/2317:37 7440-62-2 Zinc ND ug/L 10.0 3.0 1 11/30/2312:45 12/18/2317:37 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.20 0.050 1 11/30/23 12:50 11/30/23 22:17 7440-28-0 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Date: 01/17/2024 04:40 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 12/05/23 09:48 12/06/23 12:33 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 5.1 1 12/05/23 09:48 67-64-1 1.8 1 12/05/23 09:48 107-13-1 0.34 1 12/05/23 09:48 71-43-2 0.47 1 12/05/23 09:48 74-97-5 0.31 1 12/05/23 09:48 75-27-4 0.34 1 12/05/23 09:48 75-25-2 1.7 1 12/05/23 09:48 74-83-9 4.0 1 12/05/23 09:48 78-93-3 0.36 1 12/05/23 09:48 75-15-0 0.33 1 12/05/23 09:48 56-23-5 0.28 1 12/05/23 09:48 108-90-7 0.65 1 12/05/23 09:48 75-00-3 0.43 1 12/05/23 09:48 67-66-3 0.54 1 12/05/23 09:48 74-87-3 0.34 1 12/05/23 09:48 96-12-8 0.36 1 12/05/23 09:48 124-48-1 0.27 1 12/05/23 09:48 106-93-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 57 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-SW-6 Lab ID: 92699658020 Collected: 11/28/23 13:50 Received: 11/29/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) E:Y*-:11]H�46yTAyI�4 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/17/2024 04:40 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.39 1 12/05/23 09:48 74-95-3 ND ug/L 1.0 0.34 1 12/05/23 09:48 95-50-1 ND ug/L 1.0 0.33 1 12/05/23 09:48 106-46-7 ND ug/L 1.0 0.56 1 12/05/23 09:48 110-57-6 ND ug/L 1.0 0.37 1 12/05/23 09:48 75-34-3 ND ug/L 1.0 0.32 1 12/05/23 09:48 107-06-2 ND ug/L 1.0 0.35 1 12/05/23 09:48 75-35-4 ND ug/L 1.0 0.38 1 12/05/23 09:48 156-59-2 ND ug/L 1.0 0.40 1 12/05/23 09:48 156-60-5 ND ug/L 1.0 0.36 1 12/05/23 09:48 78-87-5 ND ug/L 1.0 0.36 1 12/05/23 09:48 10061-01-5 ND ug/L 1.0 0.36 1 12/05/23 09:48 10061-02-6 ND ug/L 1.0 0.30 1 12/05/23 09:48 100-41-4 ND ug/L 5.0 0.48 1 12/05/23 09:48 591-78-6 ND ug/L 20.0 9.7 1 12/05/23 09:48 74-88-4 ND ug/L 5.0 2.0 1 12/05/23 09:48 75-09-2 ND ug/L 5.0 2.7 1 12/05/23 09:48 108-10-1 ND ug/L 1.0 0.29 1 12/05/23 09:48 100-42-5 ND ug/L 1.0 0.31 1 12/05/23 09:48 630-20-6 ND ug/L 1.0 0.22 1 12/05/23 09:48 79-34-5 ND ug/L 1.0 0.29 1 12/05/23 09:48 127-18-4 ND ug/L 10.0 3.5 1 12/05/23 09:48 109-99-9 ND ug/L 1.0 0.24 1 12/05/23 09:48 108-88-3 ND ug/L 1.0 0.33 1 12/05/23 09:48 71-55-6 ND ug/L 1.0 0.32 1 12/05/23 09:48 79-00-5 ND ug/L 1.0 0.38 1 12/05/23 09:48 79-01-6 ND ug/L 1.0 0.30 1 12/05/23 09:48 75-69-4 ND ug/L 1.0 0.26 1 12/05/23 09:48 96-18-4 ND ug/L 2.0 1.3 1 12/05/23 09:48 108-05-4 ND ug/L 1.0 0.39 1 12/05/23 09:48 75-01-4 ND ug/L 1.0 0.34 1 12/05/23 09:48 1330-20-7 ND ug/L 2.0 0.71 1 12/05/23 09:48 179601-23-1 ND ug/L 1.0 0.34 1 12/05/23 09:48 95-47-6 97 % 70-130 1 12/05/23 09:48 460-00-4 102 % 70-130 1 12/05/23 09:48 17060-07-0 104 % 70-130 1 12/05/23 09:48 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 11/30/23 23:48 123-91-1 101 % 67-130 1 11/30/23 23:48 17060-07-0 100 % 70-130 1 11/30/23 23:48 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 58 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-SW-6 Lab ID: 92699658020 Collected: 11/28/23 13:50 Received: 11/29/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2320B Alkalinity Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville Alkalinity, Total as CaCO3 42.0 mg/L 5.0 5.0 1 12/05/23 22:26 2540C Total Dissolved Solids Analytical Method: SM 254OC-2015 Pace Analytical Services -Asheville Total Dissolved Solids 83.0 mg/L 25.0 25.0 1 11/30/23 17:46 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Chloride 5.7 mg/L 1.0 0.60 1 12/01/2316:13 16887-00-6 Sulfate 2.0 mg/L 1.0 0.50 1 12/01/2316:13 14808-79-8 Date: 01/17/2024 04:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 59 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-6 Lab ID: 92699658021 Collected: 11/29/23 15:05 Received: 11/30/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.6 1 12/03/2312:45 12/12/2313:39 7440-36-0 Arsenic ND ug/L 10.0 2.5 1 12/03/2312:45 12/12/2313:39 7440-38-2 Barium 234 ug/L 5.0 0.79 1 12/03/2312:45 12/12/2313:39 7440-39-3 Beryllium ND ug/L 1.0 0.16 1 12/03/2312:45 12/12/2313:39 7440-41-7 Cadmium ND ug/L 1.0 0.29 1 12/03/2312:45 12/12/2313:39 7440-43-9 Chromium 3.2J ug/L 5.0 0.63 1 12/03/2312:45 12/12/2313:39 7440-47-3 Cobalt 19.4 ug/L 5.0 0.44 1 12/03/2312:45 12/12/2313:39 7440-48-4 Copper ND ug/L 5.0 0.62 1 12/03/2312:45 12/12/2313:39 7440-50-8 Lead ND ug/L 5.0 1.4 1 12/03/2312:45 12/12/2313:39 7439-92-1 Nickel 18.0 ug/L 5.0 0.88 1 12/03/2312:45 12/12/2313:39 7440-02-0 Selenium ND ug/L 10.0 4.1 1 12/03/2312:45 12/12/2313:39 7782-49-2 Silver ND ug/L 5.0 0.49 1 12/03/2312:45 12/12/2313:39 7440-22-4 Vanadium 3.3J ug/L 5.0 1.6 1 12/03/2312:45 12/12/2313:39 7440-62-2 Zinc ND ug/L 10.0 3.0 1 12/03/2312:45 12/12/2313:39 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.20 0.050 1 12/01/2313:45 12/02/2310:52 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 12/05/23 08:38 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 12/05/23 08:38 107-13-1 Benzene 0.48J ug/L 1.0 0.34 1 12/05/23 08:38 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 12/05/23 08:38 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 12/05/23 08:38 75-27-4 Bromoform ND ug/L 1.0 0.34 1 12/05/23 08:38 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 12/05/23 08:38 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 12/05/23 08:38 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 12/05/23 08:38 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 12/05/23 08:38 56-23-5 Chlorobenzene 39.3 ug/L 1.0 0.28 1 12/05/23 08:38 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 12/05/23 08:38 75-00-3 Chloroform ND ug/L 1.0 0.43 1 12/05/23 08:38 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 12/05/23 08:38 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 12/05/23 08:38 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 12/05/23 08:38 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 12/05/23 08:38 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 12/05/23 08:38 74-95-3 1,2-Dichlorobenzene 0.49J ug/L 1.0 0.34 1 12/05/23 08:38 95-50-1 1,4-Dichlorobenzene 4.7 ug/L 1.0 0.33 1 12/05/23 08:38 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 12/05/23 08:38 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 12/05/23 08:38 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 12/05/23 08:38 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 12/05/23 08:38 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. v2 Page 60 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-6 Lab ID: 92699658021 Collected: 11/29/23 15:05 Received: 11/30/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/17/2024 04:40 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 12/05/23 08:38 156-59-2 ND ug/L 1.0 0.40 1 12/05/23 08:38 156-60-5 ND ug/L 1.0 0.36 1 12/05/23 08:38 78-87-5 ND ug/L 1.0 0.36 1 12/05/23 08:38 10061-01-5 ND ug/L 1.0 0.36 1 12/05/23 08:38 10061-02-6 ND ug/L 1.0 0.30 1 12/05/23 08:38 100-41-4 ND ug/L 5.0 0.48 1 12/05/23 08:38 591-78-6 ND ug/L 20.0 9.7 1 12/05/23 08:38 74-88-4 ND ug/L 5.0 2.0 1 12/05/23 08:38 75-09-2 ND ug/L 5.0 2.7 1 12/05/23 08:38 108-10-1 ND ug/L 1.0 0.29 1 12/05/23 08:38 100-42-5 ND ug/L 1.0 0.31 1 12/05/23 08:38 630-20-6 ND ug/L 1.0 0.22 1 12/05/23 08:38 79-34-5 ND ug/L 1.0 0.29 1 12/05/23 08:38 127-18-4 ND ug/L 1.0 0.24 1 12/05/23 08:38 108-88-3 ND ug/L 1.0 0.33 1 12/05/23 08:38 71-55-6 ND ug/L 1.0 0.32 1 12/05/23 08:38 79-00-5 ND ug/L 1.0 0.38 1 12/05/23 08:38 79-01-6 ND ug/L 1.0 0.30 1 12/05/23 08:38 75-69-4 ND ug/L 1.0 0.26 1 12/05/23 08:38 96-18-4 ND ug/L 2.0 1.3 1 12/05/23 08:38 108-05-4 ND ug/L 1.0 0.39 1 12/05/23 08:38 75-01-4 ND ug/L 1.0 0.34 1 12/05/23 08:38 1330-20-7 ND ug/L 2.0 0.71 1 12/05/23 08:38 179601-23-1 ND ug/L 1.0 0.34 1 12/05/23 08:38 95-47-6 104 % 70-130 1 12/05/23 08:38 460-00-4 93 % 70-130 1 12/05/23 08:38 17060-07-0 98 % 70-130 1 12/05/23 08:38 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 119 ug/L 4.0 1.7 2 12/03/23 23:32 123-91-1 97 % 67-130 2 12/03/23 23:32 17060-07-0 96 % 70-130 2 12/03/23 23:32 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 61 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-7 Lab ID: 92699658022 Collected: 11/29/23 13:15 Received: 11/30/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.6 1 12/03/2312:45 12/12/2313:42 7440-36-0 Arsenic ND ug/L 10.0 2.5 1 12/03/2312:45 12/12/2313:42 7440-38-2 Barium 106 ug/L 5.0 0.79 1 12/03/2312:45 12/12/2313:42 7440-39-3 Beryllium ND ug/L 1.0 0.16 1 12/03/2312:45 12/12/2313:42 7440-41-7 Cadmium ND ug/L 1.0 0.29 1 12/03/2312:45 12/12/2313:42 7440-43-9 Chromium 0.87J ug/L 5.0 0.63 1 12/03/2312:45 12/12/2313:42 7440-47-3 Cobalt 0.93J ug/L 5.0 0.44 1 12/03/2312:45 12/12/2313:42 7440-48-4 Copper 1.2J ug/L 5.0 0.62 1 12/03/2312:45 12/12/2313:42 7440-50-8 Lead ND ug/L 5.0 1.4 1 12/03/2312:45 12/12/2313:42 7439-92-1 Nickel 4.OJ ug/L 5.0 0.88 1 12/03/2312:45 12/12/2313:42 7440-02-0 Selenium 4.4J ug/L 10.0 4.1 1 12/03/2312:45 12/12/2313:42 7782-49-2 Silver ND ug/L 5.0 0.49 1 12/03/2312:45 12/12/2313:42 7440-22-4 Vanadium ND ug/L 5.0 1.6 1 12/03/2312:45 12/12/2313:42 7440-62-2 Zinc 5.7J ug/L 10.0 3.0 1 12/03/2312:45 12/12/2313:42 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.20 0.050 1 12/01/2313:45 12/02/2311:16 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 12/05/23 08:56 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 12/05/23 08:56 107-13-1 Benzene ND ug/L 1.0 0.34 1 12/05/23 08:56 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 12/05/23 08:56 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 12/05/23 08:56 75-27-4 Bromoform ND ug/L 1.0 0.34 1 12/05/23 08:56 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 12/05/23 08:56 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 12/05/23 08:56 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 12/05/23 08:56 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 12/05/23 08:56 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 12/05/23 08:56 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 12/05/23 08:56 75-00-3 Chloroform ND ug/L 1.0 0.43 1 12/05/23 08:56 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 12/05/23 08:56 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 12/05/23 08:56 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 12/05/23 08:56 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 12/05/23 08:56 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 12/05/23 08:56 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 12/05/23 08:56 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 12/05/23 08:56 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 12/05/23 08:56 110-57-6 1,1-Dichloroethane 0.551 ug/L 1.0 0.37 1 12/05/23 08:56 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 12/05/23 08:56 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 12/05/23 08:56 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. v2 Page 62 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-7 Lab ID: 92699658022 Collected: 11/29/23 13:15 Received: 11/30/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/17/2024 04:40 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 12/05/23 08:56 156-59-2 ND ug/L 1.0 0.40 1 12/05/23 08:56 156-60-5 ND ug/L 1.0 0.36 1 12/05/23 08:56 78-87-5 ND ug/L 1.0 0.36 1 12/05/23 08:56 10061-01-5 ND ug/L 1.0 0.36 1 12/05/23 08:56 10061-02-6 ND ug/L 1.0 0.30 1 12/05/23 08:56 100-41-4 ND ug/L 5.0 0.48 1 12/05/23 08:56 591-78-6 ND ug/L 20.0 9.7 1 12/05/23 08:56 74-88-4 ND ug/L 5.0 2.0 1 12/05/23 08:56 75-09-2 ND ug/L 5.0 2.7 1 12/05/23 08:56 108-10-1 ND ug/L 1.0 0.29 1 12/05/23 08:56 100-42-5 ND ug/L 1.0 0.31 1 12/05/23 08:56 630-20-6 ND ug/L 1.0 0.22 1 12/05/23 08:56 79-34-5 ND ug/L 1.0 0.29 1 12/05/23 08:56 127-18-4 ND ug/L 1.0 0.24 1 12/05/23 08:56 108-88-3 ND ug/L 1.0 0.33 1 12/05/23 08:56 71-55-6 ND ug/L 1.0 0.32 1 12/05/23 08:56 79-00-5 ND ug/L 1.0 0.38 1 12/05/23 08:56 79-01-6 ND ug/L 1.0 0.30 1 12/05/23 08:56 75-69-4 ND ug/L 1.0 0.26 1 12/05/23 08:56 96-18-4 ND ug/L 2.0 1.3 1 12/05/23 08:56 108-05-4 ND ug/L 1.0 0.39 1 12/05/23 08:56 75-01-4 ND ug/L 1.0 0.34 1 12/05/23 08:56 1330-20-7 ND ug/L 2.0 0.71 1 12/05/23 08:56 179601-23-1 ND ug/L 1.0 0.34 1 12/05/23 08:56 95-47-6 102 % 70-130 1 12/05/23 08:56 460-00-4 93 % 70-130 1 12/05/23 08:56 17060-07-0 98 % 70-130 1 12/05/23 08:56 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 3.4 ug/L 2.0 0.86 1 12/03/23 23:13 123-91-1 95 % 67-130 1 12/03/23 23:13 17060-07-0 95 % 70-130 1 12/03/23 23:13 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 63 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-8 Lab ID: 92699658023 Collected: 11/29/23 12:05 Received: 11/30/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.6 1 12/03/2312:45 12/12/2313:56 7440-36-0 Arsenic 3.3J ug/L 10.0 2.5 1 12/03/2312:45 12/12/2313:56 7440-38-2 B Barium 283 ug/L 5.0 0.79 1 12/03/2312:45 12/12/2313:56 7440-39-3 Beryllium ND ug/L 1.0 0.16 1 12/03/2312:45 12/12/2313:56 7440-41-7 Cadmium ND ug/L 1.0 0.29 1 12/03/2312:45 12/12/2313:56 7440-43-9 Chromium 13.9 ug/L 5.0 0.63 1 12/03/2312:45 12/12/2313:56 7440-47-3 Cobalt ND ug/L 5.0 0.44 1 12/03/2312:45 12/12/2313:56 7440-48-4 Copper ND ug/L 5.0 0.62 1 12/03/2312:45 12/12/2313:56 7440-50-8 Lead ND ug/L 5.0 1.4 1 12/03/2312:45 12/12/2313:56 7439-92-1 Nickel 9.1 ug/L 5.0 0.88 1 12/03/2312:45 12/12/2313:56 7440-02-0 Selenium 4.3J ug/L 10.0 4.1 1 12/03/2312:45 12/12/2313:56 7782-49-2 Silver ND ug/L 5.0 0.49 1 12/03/2312:45 12/12/2313:56 7440-22-4 Vanadium 3.4J ug/L 5.0 1.6 1 12/03/2312:45 12/12/2313:56 7440-62-2 Zinc 11.4 ug/L 10.0 3.0 1 12/03/2312:45 12/12/2313:56 7440-66-6 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene Date: 01/17/2024 04:40 PM Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville ND ug/L 0.20 0.050 1 12/01/2313:45 12/02/2311:20 7440-28-0 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 5.1 1 12/05/23 09:14 67-64-1 ND ug/L 10.0 1.8 1 12/05/23 09:14 107-13-1 ND ug/L 1.0 0.34 1 12/05/23 09:14 71-43-2 ND ug/L 1.0 0.47 1 12/05/23 09:14 74-97-5 ND ug/L 1.0 0.31 1 12/05/23 09:14 75-27-4 ND ug/L 1.0 0.34 1 12/05/23 09:14 75-25-2 ND ug/L 2.0 1.7 1 12/05/23 09:14 74-83-9 ND ug/L 5.0 4.0 1 12/05/23 09:14 78-93-3 ND ug/L 2.0 0.36 1 12/05/23 09:14 75-15-0 ND ug/L 1.0 0.33 1 12/05/23 09:14 56-23-5 ND ug/L 1.0 0.28 1 12/05/23 09:14 108-90-7 ND ug/L 1.0 0.65 1 12/05/23 09:14 75-00-3 ND ug/L 1.0 0.43 1 12/05/23 09:14 67-66-3 ND ug/L 1.0 0.54 1 12/05/23 09:14 74-87-3 ND ug/L 2.0 0.34 1 12/05/23 09:14 96-12-8 ND ug/L 1.0 0.36 1 12/05/23 09:14 124-48-1 ND ug/L 1.0 0.27 1 12/05/23 09:14 106-93-4 ND ug/L 1.0 0.39 1 12/05/23 09:14 74-95-3 ND ug/L 1.0 0.34 1 12/05/23 09:14 95-50-1 ND ug/L 1.0 0.33 1 12/05/23 09:14 106-46-7 ND ug/L 1.0 0.56 1 12/05/23 09:14 110-57-6 ND ug/L 1.0 0.37 1 12/05/23 09:14 75-34-3 ND ug/L 1.0 0.32 1 12/05/23 09:14 107-06-2 ND ug/L 1.0 0.35 1 12/05/23 09:14 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 64 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Sample: 8103-MW-8 Lab ID: 92699658023 Collected: 11/29/23 12:05 Received: 11/30/23 08:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/17/2024 04:40 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 12/05/23 09:14 156-59-2 ND ug/L 1.0 0.40 1 12/05/23 09:14 156-60-5 ND ug/L 1.0 0.36 1 12/05/23 09:14 78-87-5 ND ug/L 1.0 0.36 1 12/05/23 09:14 10061-01-5 ND ug/L 1.0 0.36 1 12/05/23 09:14 10061-02-6 ND ug/L 1.0 0.30 1 12/05/23 09:14 100-41-4 ND ug/L 5.0 0.48 1 12/05/23 09:14 591-78-6 ND ug/L 20.0 9.7 1 12/05/23 09:14 74-88-4 ND ug/L 5.0 2.0 1 12/05/23 09:14 75-09-2 ND ug/L 5.0 2.7 1 12/05/23 09:14 108-10-1 ND ug/L 1.0 0.29 1 12/05/23 09:14 100-42-5 ND ug/L 1.0 0.31 1 12/05/23 09:14 630-20-6 ND ug/L 1.0 0.22 1 12/05/23 09:14 79-34-5 ND ug/L 1.0 0.29 1 12/05/23 09:14 127-18-4 ND ug/L 1.0 0.24 1 12/05/23 09:14 108-88-3 ND ug/L 1.0 0.33 1 12/05/23 09:14 71-55-6 ND ug/L 1.0 0.32 1 12/05/23 09:14 79-00-5 ND ug/L 1.0 0.38 1 12/05/23 09:14 79-01-6 ND ug/L 1.0 0.30 1 12/05/23 09:14 75-69-4 ND ug/L 1.0 0.26 1 12/05/23 09:14 96-18-4 ND ug/L 2.0 1.3 1 12/05/23 09:14 108-05-4 ND ug/L 1.0 0.39 1 12/05/23 09:14 75-01-4 ND ug/L 1.0 0.34 1 12/05/23 09:14 1330-20-7 ND ug/L 2.0 0.71 1 12/05/23 09:14 179601-23-1 ND ug/L 1.0 0.34 1 12/05/23 09:14 95-47-6 101 % 70-130 1 12/05/23 09:14 460-00-4 95 % 70-130 1 12/05/23 09:14 17060-07-0 95 % 70-130 1 12/05/23 09:14 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 31.8 ug/L 2.0 0.86 1 12/01/23 20:05 123-91-1 101 % 67-130 1 12/01 /23 20:05 17060-07-0 100 % 70-130 1 12/01 /23 20:05 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 65 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 815336 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92699658001, 92699658002, 92699658003, 92699658004, 92699658005, 92699658006, 92699658007, 92699658008 METHOD BLANK: 4220820 Matrix: Water Associated Lab Samples: 92699658001, 92699658002, 92699658003, 92699658004, 92699658005, 92699658006, 92699658007, 92699658008 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.20 0.12 11/28/2310:51 LABORATORY CONTROL SAMPLE: 4220821 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.5 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4220822 4220823 MS MSD 92700200001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.5 2.6 100 102 75-125 2 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 66 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 817230 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92699658017, 92699658018, 92699658019, 92699658020 METHOD BLANK: 4229530 Matrix: Water Associated Lab Samples: 92699658017, 92699658018, 92699658019, 92699658020 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.20 0.12 12/06/2311:36 LABORATORY CONTROL SAMPLE: 4229531 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.5 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4229532 4229533 MS MSD 92701243004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.5 2.5 102 101 75-125 1 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 67 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 815074 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92699658001, 92699658002, 92699658003, 92699658004, 92699658005, 92699658006, 92699658007, 92699658008,92699658009,92699658010,92699658011,92699658012,92699658013,92699658014, 92699658015 METHOD BLANK: 4219479 Matrix: Water Associated Lab Samples: 92699658001, 92699658002, 92699658003, 92699658004, 92699658005, 92699658006, 92699658007, 92699658008,92699658009,92699658010,92699658011,92699658012,92699658013,92699658014, 92699658015 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Aluminum ug/L ND 100 10.3 12/08/2318:30 Antimony ug/L ND 5.0 3.6 12/08/2318:30 Arsenic ug/L ND 10.0 2.5 12/08/2318:30 Barium ug/L ND 5.0 0.79 12/08/2318:30 Beryllium ug/L ND 1.0 0.16 12/08/2318:30 Cadmium ug/L ND 1.0 0.29 12/08/2318:30 Chromium ug/L ND 5.0 0.63 12/08/2318:30 Cobalt ug/L ND 5.0 0.44 12/08/2318:30 Copper ug/L ND 5.0 0.62 12/08/2318:30 Iron ug/L ND 50.0 8.9 12/08/2318:30 Lead ug/L ND 5.0 1.4 12/08/2318:30 Manganese ug/L ND 5.0 0.86 12/08/2318:30 Nickel ug/L ND 5.0 0.88 12/08/2318:30 Selenium ug/L ND 10.0 4.1 12/08/2318:30 Silver ug/L ND 5.0 0.49 12/08/2318:30 Vanadium ug/L ND 5.0 1.6 12/08/2318:30 Zinc ug/L ND 10.0 3.0 12/08/2318:30 LABORATORY CONTROL SAMPLE: 4219480 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Aluminum ug/L 5000 4950 99 80-120 Antimony ug/L 500 513 103 80-120 Arsenic ug/L 500 491 98 80-120 Barium ug/L 500 467 93 80-120 Beryllium ug/L 500 487 97 80-120 Cadmium ug/L 500 491 98 80-120 Chromium ug/L 500 485 97 80-120 Cobalt ug/L 500 491 98 80-120 Copper ug/L 500 497 99 80-120 Iron ug/L 5000 4700 94 80-120 Lead ug/L 500 491 98 80-120 Manganese ug/L 500 466 93 80-120 Nickel ug/L 500 492 98 80-120 Selenium ug/L 500 472 94 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 68 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 LABORATORY CONTROL SAMPLE: 4219480 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Silver ug/L 250 243 97 80-120 Vanadium ug/L 500 494 99 80-120 Zinc ug/L 500 487 97 80-120 MATRIX SPIKE & MATRIX Parameter SPIKE DUPLICATE: 4219481 MS 92699658001 Spike Units Result Conc. MSD Spike Conc. 4219482 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Aluminum ug/L 529 5000 5000 6040 5990 110 109 75-125 1 20 Antimony ug/L ND 500 500 523 520 105 104 75-125 1 20 Arsenic ug/L ND 500 500 500 493 100 99 75-125 1 20 Barium ug/L 19.9 500 500 511 493 98 95 75-125 3 20 Beryllium ug/L ND 500 500 500 494 100 99 75-125 1 20 Cadmium ug/L ND 500 500 498 492 100 98 75-125 1 20 Chromium ug/L 15.3 500 500 503 498 98 97 75-125 1 20 Cobalt ug/L ND 500 500 488 482 98 96 75-125 1 20 Copper ug/L 1.7J 500 500 501 492 100 98 75-125 2 20 Iron ug/L 1610 5000 5000 6460 6240 97 93 75-125 3 20 Lead ug/L ND 500 500 493 486 99 97 75-125 1 20 Manganese ug/L 21.5 500 500 510 494 98 94 75-125 3 20 Nickel ug/L 8.1 500 500 499 496 98 98 75-125 1 20 Selenium ug/L ND 500 500 501 492 100 98 75-125 2 20 Silver ug/L ND 250 250 246 243 98 97 75-125 1 20 Vanadium ug/L 2.6J 500 500 502 496 100 99 75-125 1 20 Zinc ug/L 6.5J 500 500 500 495 99 98 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 69 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 816347 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92699658017, 92699658018, 92699658019, 92699658020 METHOD BLANK: 4225380 Matrix: Water Associated Lab Samples: 92699658017, 92699658018, 92699658019, 92699658020 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Aluminum ug/L ND 100 10.3 12/19/2316:12 Antimony ug/L ND 5.0 3.6 12/19/2316:12 Arsenic ug/L ND 10.0 2.5 12/19/2316:12 Barium ug/L ND 5.0 0.79 12/18/2317:03 Beryllium ug/L ND 1.0 0.16 12/18/2317:03 Cadmium ug/L ND 1.0 0.29 12/19/2316:12 Chromium ug/L ND 5.0 0.63 12/18/2317:03 Cobalt ug/L ND 5.0 0.44 12/18/2317:03 Copper ug/L ND 5.0 0.62 12/19/2316:12 Iron ug/L ND 50.0 8.9 12/18/2317:03 Lead ug/L ND 5.0 1.4 12/19/2316:12 Manganese ug/L ND 5.0 0.86 12/18/2317:03 Nickel ug/L ND 5.0 0.88 12/18/2317:03 Selenium ug/L ND 10.0 4.1 12/19/2316:12 Silver ug/L ND 5.0 0.49 12/18/2317:03 Vanadium ug/L ND 5.0 1.6 12/18/2317:03 Zinc ug/L ND 10.0 3.0 12/18/2317:03 LABORATORY CONTROL SAMPLE: Parameter 4225381 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 5000 4870 97 80-120 Antimony ug/L 500 480 96 80-120 Arsenic ug/L 500 477 95 80-120 Barium ug/L 500 450 90 80-120 Beryllium ug/L 500 444 89 80-120 Cadmium ug/L 500 486 97 80-120 Chromium ug/L 500 450 90 80-120 Cobalt ug/L 500 446 89 80-120 Copper ug/L 500 499 100 80-120 Iron ug/L 5000 4600 92 80-120 Lead ug/L 500 490 98 80-120 Manganese ug/L 500 456 91 80-120 Nickel ug/L 500 446 89 80-120 Selenium ug/L 500 476 95 80-120 Silver ug/L 250 222 89 80-120 Vanadium ug/L 500 444 89 80-120 Zinc ug/L 500 444 89 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 70 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Pace Project No.: Rutherford Co Central LF Nov23 92699658 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4225382 4225383 MS MSD 92699658017 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 118 5000 5000 5160 5140 101 100 75-125 0 20 Antimony ug/L ND 500 500 495 495 99 99 75-125 0 20 Arsenic ug/L ND 500 500 493 493 99 99 75-125 0 20 Barium ug/L 103 500 500 571 608 94 101 75-125 6 20 Beryllium ug/L ND 500 500 467 474 93 95 75-125 1 20 Cadmium ug/L ND 500 500 483 484 97 97 75-125 0 20 Chromium ug/L 1.3J 500 500 460 467 92 93 75-125 1 20 Cobalt ug/L ND 500 500 448 454 90 91 75-125 1 20 Copper ug/L 4.6J 500 500 517 516 102 102 75-125 0 20 Iron ug/L 226 5000 5000 4990 5310 95 102 75-125 6 20 Lead ug/L ND 500 500 490 490 98 98 75-125 0 20 Manganese ug/L 82.8 500 500 549 585 93 100 75-125 6 20 Nickel ug/L 1.6J 500 500 444 451 89 90 75-125 2 20 Selenium ug/L ND 500 500 502 501 100 100 75-125 0 20 Silver ug/L ND 250 250 233 236 93 94 75-125 1 20 Vanadium ug/L ND 500 500 457 465 91 93 75-125 2 20 Zinc ug/L 4.2J 500 500 449 455 89 90 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 71 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 816931 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92699658021, 92699658022, 92699658023 METHOD BLANK: 4228338 Matrix: Associated Lab Samples: 92699658021, 92699658022, 92699658023 Blank Parameter Units Result Water Reporting Limit Antimony ug/L ND 5.0 Arsenic ug/L 2.7J 10.0 Barium ug/L ND 5.0 Beryllium ug/L ND 1.0 Cadmium ug/L ND 1.0 Chromium ug/L ND 5.0 Cobalt ug/L ND 5.0 Copper ug/L ND 5.0 Lead ug/L ND 5.0 Nickel ug/L ND 5.0 Selenium ug/L ND 10.0 Silver ug/L ND 5.0 Vanadium ug/L ND 5.0 Zinc ug/L ND 10.0 MDL Analyzed 3.6 12/13/23 21:59 2.5 12/12/23 12:56 0.79 12/12/23 12:56 0.16 12/12/23 12:56 0.29 12/12/23 12:56 0.63 12/12/23 12:56 0.44 12/12/23 12:56 0.62 12/12/23 12:56 1.4 12/12/23 12:56 0.88 12/12/23 12:56 4.1 12/12/23 12:56 0.49 12/12/23 12:56 1.6 12/12/23 12:56 3.0 12/12/23 12:56 LABORATORY CONTROL SAMPLE: Parameter 4228339 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 486 97 80-120 Arsenic ug/L 500 498 100 80-120 Barium ug/L 500 484 97 80-120 Beryllium ug/L 500 491 98 80-120 Cadmium ug/L 500 498 100 80-120 Chromium ug/L 500 493 99 80-120 Cobalt ug/L 500 499 100 80-120 Copper ug/L 500 503 101 80-120 Lead ug/L 500 495 99 80-120 Nickel ug/L 500 496 99 80-120 Selenium ug/L 500 484 97 80-120 Silver ug/L 250 246 98 80-120 Vanadium ug/L 500 493 99 80-120 Zinc ug/L 500 492 98 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 72 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Pace Project No.: Rutherford Co Central LF Nov23 92699658 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4228340 4228341 MS MSD 92701230002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 523 532 104 106 75-125 2 20 Arsenic ug/L ND 500 500 510 515 102 103 75-125 1 20 Barium ug/L 39.8 500 500 529 553 98 103 75-125 4 20 Beryllium ug/L ND 500 500 504 506 101 101 75-125 0 20 Cadmium ug/L ND 500 500 501 503 100 101 75-125 0 20 Chromium ug/L ND 500 500 496 498 99 99 75-125 0 20 Cobalt ug/L ND 500 500 496 497 99 99 75-125 0 20 Copper ug/L 21.6 500 500 530 528 102 101 75-125 0 20 Lead ug/L ND 500 500 495 494 98 98 75-125 0 20 Nickel ug/L 7.2 500 500 505 507 99 100 75-125 0 20 Selenium ug/L ND 500 500 501 512 100 102 75-125 2 20 Silver ug/L ND 250 250 247 246 99 99 75-125 0 20 Vanadium ug/L ND 500 500 502 503 100 100 75-125 0 20 Zinc ug/L 63.3 500 500 559 561 99 100 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 73 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 815071 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92699658001, 92699658002, 92699658003, 92699658004, 92699658005, 92699658006, 92699658007, 92699658008,92699658009,92699658010,92699658011,92699658012,92699658013,92699658014, 92699658015 METHOD BLANK: 4219463 Matrix: Water Associated Lab Samples: 92699658001, 92699658002, 92699658003, 92699658004, 92699658005, 92699658006, 92699658007, 92699658008,92699658009,92699658010,92699658011,92699658012,92699658013,92699658014, 92699658015 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.20 0.050 11/26/23 21:49 LABORATORY CONTROL SAMPLE: 4219464 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 25 24.6 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4219465 4219466 MS MSD 92699980001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 25 25 25.7 25.6 103 102 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 74 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 816344 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92699658017, 92699658018, 92699658019, 92699658020 METHOD BLANK: 4225375 Matrix: Water Associated Lab Samples: 92699658017, 92699658018, 92699658019, 92699658020 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.20 0.050 11/30/23 20:42 LABORATORY CONTROL SAMPLE: 4225376 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 25 25.9 103 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4225377 4225378 MS MSD 92700859001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 25 25 25.7 25.5 103 102 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 75 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 816711 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92699658021, 92699658022, 92699658023 METHOD BLANK: 4227044 Matrix: Water Associated Lab Samples: 92699658021, 92699658022, 92699658023 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.20 0.050 12/02/2310:43 LABORATORY CONTROL SAMPLE: 4227045 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 25 26.2 105 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4227046 4227047 MS MSD 92699658021 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 25 25 26.5 27.4 106 109 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 76 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 816400 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92699658001, 92699658002, 92699658003, 92699658004, 92699658005, 92699658006, 92699658007, 92699658008,92699658009,92699658010,92699658011,92699658012,92699658013,92699658014, 92699658015,92699658016 METHOD BLANK: 4225698 Matrix: Water Associated Lab Samples: 92699658001, 92699658002, 92699658003, 92699658004, 92699658005, 92699658006, 92699658007, 92699658008,92699658009,92699658010,92699658011,92699658012,92699658013,92699658014, 92699658015,92699658016 Parameter Units Blank Result Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 11/30/23 13:45 1,1,1-Trichloroethane ug/L ND 1.0 0.33 11/30/23 13:45 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 11/30/23 13:45 1,1,2-Trichloroethane ug/L ND 1.0 0.32 11/30/23 13:45 1,1-Dichloroethane ug/L ND 1.0 0.37 11/30/23 13:45 1,1-Dichloroethene ug/L ND 1.0 0.35 11/30/23 13:45 1,2,3-Trichloropropane ug/L ND 1.0 0.26 11/30/23 13:45 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 11/30/23 13:45 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 11/30/23 13:45 1,2-Dichlorobenzene ug/L ND 1.0 0.34 11/30/23 13:45 1,2-Dichloroethane ug/L ND 1.0 0.32 11/30/23 13:45 1,2-Dichloropropane ug/L ND 1.0 0.36 11/30/23 13:45 1,4-Dichlorobenzene ug/L ND 1.0 0.33 11/30/23 13:45 2-Butanone (MEK) ug/L ND 5.0 4.0 11/30/23 13:45 2-Hexanone ug/L ND 5.0 0.48 11/30/23 13:45 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 11/30/23 13:45 Acetone ug/L ND 25.0 5.1 11/30/23 13:45 Acrylonitrile ug/L ND 10.0 1.8 11/30/23 13:45 Benzene ug/L ND 1.0 0.34 11/30/23 13:45 Bromochloromethane ug/L ND 1.0 0.47 11/30/23 13:45 Bromodichloromethane ug/L ND 1.0 0.31 11/30/23 13:45 Bromoform ug/L ND 1.0 0.34 11/30/23 13:45 Bromomethane ug/L ND 2.0 1.7 11/30/23 13:45 Carbon disulfide ug/L ND 2.0 0.36 11/30/23 13:45 Carbon tetrachloride ug/L ND 1.0 0.33 11/30/23 13:45 Chlorobenzene ug/L ND 1.0 0.28 11/30/23 13:45 Chloroethane ug/L ND 1.0 0.65 11/30/23 13:45 Chloroform ug/L ND 1.0 0.43 11/30/23 13:45 Chloromethane ug/L ND 1.0 0.54 11/30/23 13:45 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 11/30/23 13:45 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 11/30/23 13:45 Dibromochloromethane ug/L ND 1.0 0.36 11/30/23 13:45 Dibromomethane ug/L ND 1.0 0.39 11/30/23 13:45 Ethylbenzene ug/L ND 1.0 0.30 11/30/23 13:45 lodomethane ug/L ND 20.0 9.7 11/30/23 13:45 m&p-Xylene ug/L ND 2.0 0.71 11/30/23 13:45 Methylene Chloride ug/L ND 5.0 2.0 11/30/23 13:45 v2 v2 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 77 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 METHOD BLANK: 4225698 Matrix: Water Associated Lab Samples: 92699658001, 92699658002, 92699658003, 92699658004, 92699658005, 92699658006, 92699658007, 92699658008,92699658009,92699658010,92699658011,92699658012,92699658013,92699658014, 92699658015,92699658016 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers o-Xylene ug/L ND 1.0 0.34 11/30/23 13:45 Styrene ug/L ND 1.0 0.29 11/30/23 13:45 Tetrachloroethene ug/L ND 1.0 0.29 11/30/23 13:45 Tetrahydrofuran ug/L ND 10.0 3.5 11/30/23 13:45 Toluene ug/L ND 1.0 0.24 11/30/23 13:45 trans-1,2-Dichloroethene ug/L ND 1.0 0.40 11/30/23 13:45 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 11/30/23 13:45 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 11/30/23 13:45 Trichloroethene ug/L ND 1.0 0.38 11/30/23 13:45 Trichlorofluoromethane ug/L ND 1.0 0.30 11/30/23 13:45 Vinyl acetate ug/L ND 2.0 1.3 11/30/23 13:45 Vinyl chloride ug/L ND 1.0 0.39 11/30/23 13:45 Xylene (Total) ug/L ND 1.0 0.34 11/30/23 13:45 1,2-Dichloroethane-d4 (S) % 92 70-130 11/30/23 13:45 4-Bromofluorobenzene (S) % 102 70-130 11/30/23 13:45 Toluene-d8 (S) % 97 70-130 11/30/23 13:45 LABORATORY CONTROL SAMPLE: Parameter 4225699 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 20 19.5 97 70-130 1,1,1-Trichloroethane ug/L 20 19.9 100 70-130 1,1,2,2-Tetrachloroethane ug/L 20 19.4 97 70-130 1,1,2-Trichloroethane ug/L 20 19.2 96 70-130 1,1-Dichloroethane ug/L 20 18.2 91 70-130 1,1-Dichloroethene ug/L 20 18.9 94 69-131 1,2,3-Trichloropropane ug/L 20 18.9 94 70-130 1,2-Dibromo-3-chloropropane ug/L 20 17.3 86 70-130 1,2-Dibromoethane (EDB) ug/L 20 20.1 101 70-130 1,2-Dichlorobenzene ug/L 20 20.0 100 70-130 1,2-Dichloroethane ug/L 20 18.2 91 70-130 1,2-Dichloropropane ug/L 20 19.2 96 70-130 1,4-Dichlorobenzene ug/L 20 19.7 99 70-130 2-Butanone (MEK) ug/L 40 33.5 84 67-133 2-Hexanone ug/L 40 37.2 93 70-133 4-Methyl-2-pentanone (MIBK) ug/L 40 35.7 89 70-130 Acetone ug/L 40 33.4 84 67-130 Acrylonitrile ug/L 100 86.1 86 70-130 Benzene ug/L 20 18.6 93 70-130 Bromochloromethane ug/L 20 19.2 96 70-130 Bromodichloromethane ug/L 20 18.2 91 70-130 Bromoform ug/L 20 16.3 81 70-133 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 78 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 LABORATORY CONTROL SAMPLE: 4225699 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Bromomethane ug/L 20 15.2 76 41-148 v3 Carbon disulfide ug/L 20 19.9 100 70-131 Carbon tetrachloride ug/L 20 19.8 99 70-130 Chlorobenzene ug/L 20 19.4 97 70-130 Chloroethane ug/L 20 16.5 83 41-157 Chloroform ug/L 20 18.3 92 70-130 Chloromethane ug/L 20 17.7 89 59-141 cis-1,2-Dichloroethene ug/L 20 17.9 89 70-130 cis-1,3-Dichloropropene ug/L 20 18.6 93 70-130 Dibromochloromethane ug/L 20 18.6 93 70-130 Dibromomethane ug/L 20 19.6 98 70-130 Ethylbenzene ug/L 20 19.6 98 70-130 lodomethane ug/L 40 34.4 86 57-140 v3 m&p-Xylene ug/L 40 39.8 100 70-130 Methylene Chloride ug/L 20 17.6 88 62-130 o-Xylene ug/L 20 20.3 102 70-130 Styrene ug/L 20 19.5 98 70-130 Tetrachloroethene ug/L 20 21.0 105 70-130 Tetrahydrofuran ug/L 200 169 84 70-131 Toluene ug/L 20 18.6 93 70-130 trans-1,2-Dichloroethene ug/L 20 18.8 94 70-130 trans- 1,3-Dichloropropene ug/L 20 18.4 92 70-130 trans-1,4-Dichloro-2-butene ug/L 20 19.9 100 57-149 Trichloroethene ug/L 20 19.4 97 70-130 Trichlorofluoromethane ug/L 20 17.6 88 57-130 Vinyl acetate ug/L 40 34.4 86 70-141 Vinyl chloride ug/L 20 17.4 87 66-140 Xylene (Total) ug/L 60 60.2 100 70-130 1,2-Dichloroethane-d4 (S) % 92 70-130 4-Bromofluorobenzene (S) % 103 70-130 Toluene-d8 (S) % 96 70-130 MATRIX SPIKE SAMPLE: 4225700 92699658001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits 1,1,1,2-Tetrachloroethane ug/L ND 20 22.0 110 70-146 1,1,1-Trichloroethane ug/L ND 20 24.1 120 70-150 1,1,2,2-Tetrachloroethane ug/L ND 20 20.2 101 66-144 1,1,2-Trichloroethane ug/L ND 20 21.8 109 70-142 1,1-Dichloroethane ug/L ND 20 20.2 101 68-150 1,1-Dichloroethene ug/L ND 20 22.0 110 64-162 1,2,3-Trichloropropane ug/L ND 20 20.2 101 66-144 1,2-Dibromo-3-chloropropane ug/L ND 20 19.3 97 62-146 1,2-Dibromoethane (EDB) ug/L ND 20 21.6 108 70-143 1,2-Dichlorobenzene ug/L ND 20 21.5 108 70-142 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Qualifiers Page 79 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 MATRIX SPIKE SAMPLE: 4225700 92699658001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,2-Dichloroethane ug/L ND 20 20.7 103 68-145 1,2-Dichloropropane ug/L ND 20 20.6 103 70-144 1,4-Dichlorobenzene ug/L ND 20 20.7 103 70-140 2-Butanone (MEK) ug/L ND 40 38.1 95 57-156 2-Hexanone ug/L ND 40 38.4 96 62-153 4-Methyl-2-pentanone (MIBK) ug/L ND 40 36.8 92 65-144 Acetone ug/L ND 40 36.2 91 49-162 Acrylonitrile ug/L ND 100 90.5 90 59-155 Benzene ug/L ND 20 21.0 105 68-144 Bromochloromethane ug/L ND 20 21.5 108 70-148 Bromodichloromethane ug/L ND 20 21.3 107 70-141 Bromoform ug/L ND 20 18.9 95 59-144 Bromomethane ug/L ND 20 21.2 106 23-190 v3 Carbon disulfide ug/L ND 20 23.1 116 64-160 Carbon tetrachloride ug/L ND 20 25.9 130 70-147 Chlorobenzene ug/L ND 20 20.9 105 70-143 Chloroethane ug/L ND 20 19.2 96 55-190 Chloroform ug/L ND 20 21.6 108 67-148 Chloromethane ug/L ND 20 18.5 93 38-180 v3 cis-1,2-Dichloroethene ug/L ND 20 19.6 98 67-151 cis-1,3-Dichloropropene ug/L ND 20 20.9 105 70-142 Dibromochloromethane ug/L ND 20 21.7 108 68-140 Dibromomethane ug/L ND 20 24.0 120 70-142 Ethylbenzene ug/L ND 20 20.9 105 70-145 lodomethane ug/L ND 40 41.3 103 37-160 m&p-Xylene ug/L ND 40 42.3 106 70-148 Methylene Chloride ug/L ND 20 18.1 90 54-149 o-Xylene ug/L ND 20 21.4 107 70-145 Styrene ug/L ND 20 21.0 105 70-147 Tetrachloroethene ug/L ND 20 23.6 118 70-145 Tetrahydrofuran ug/L ND 200 176 88 48-160 v3 Toluene ug/L ND 20 20.9 104 65-146 trans-1,2-Dichloroethene ug/L ND 20 21.6 108 69-155 trans- 1,3-Dichloropropene ug/L ND 20 21.7 108 70-142 trans-1,4-Dichloro-2-butene ug/L ND 20 19.0 95 39-149 Trichloroethene ug/L ND 20 23.6 118 70-152 Trichlorofluoromethane ug/L ND 20 21.5 108 60-158 Vinyl acetate ug/L ND 40 35.4 89 56-157 v3 Vinyl chloride ug/L ND 20 18.3 91 51-178 v3 Xylene (Total) ug/L ND 60 63.7 106 70-146 1,2-Dichloroethane-d4 (S) % 97 70-130 4-Bromofluorobenzene (S) % 103 70-130 Toluene-d8 (S) % 97 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 80 of 130 Pace Analytical Services, LLC 1377 South Park Drive aceo Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 SAMPLE DUPLICATE: 4225701 Parameter Units 92699658002 Result Dup Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Acrylonitrile ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 30 v2 Carbon disulfide ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 30 Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 v2 cis-1,2-Dichloroethene ug/L ND ND 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 lodomethane ug/L ND ND 30 m&p-Xylene ug/L ND ND 30 Methylene Chloride ug/L ND ND 30 o-Xylene ug/L ND ND 30 Styrene ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 Tetrahydrofuran ug/L ND ND 30 v2 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans- 1,3-Dichloropropene ug/L ND ND 30 trans-1,4-Dichloro-2-butene ug/L ND ND 30 Trichloroethene ug/L ND ND 30 Trichlorofluoromethane ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 81 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 SAMPLE DUPLICATE: 4225701 Parameter Vinyl acetate Vinyl chloride Xylene (Total) 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) QUALITY CONTROL DATA Units 92699658002 Result Dup Result ug/L ND ND ug/L ND ND ug/L ND ND % 95 93 102 103 % 98 99 Max RPD RPD Qualifiers 30 v2 30 v2 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 82 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 817059 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92699658017, 92699658018 METHOD BLANK: 4228876 Associated Lab Samples: 92699658017, 92699658018 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 12/05/23 02:06 1,1,1-Trichloroethane ug/L ND 1.0 0.33 12/05/23 02:06 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 12/05/23 02:06 1,1,2-Trichloroethane ug/L ND 1.0 0.32 12/05/23 02:06 1,1-Dichloroethane ug/L ND 1.0 0.37 12/05/23 02:06 1,1-Dichloroethene ug/L ND 1.0 0.35 12/05/23 02:06 1,2,3-Trichloropropane ug/L ND 1.0 0.26 12/05/23 02:06 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 12/05/23 02:06 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 12/05/23 02:06 1,2-Dichlorobenzene ug/L ND 1.0 0.34 12/05/23 02:06 1,2-Dichloroethane ug/L ND 1.0 0.32 12/05/23 02:06 1,2-Dichloropropane ug/L ND 1.0 0.36 12/05/23 02:06 1,4-Dichlorobenzene ug/L ND 1.0 0.33 12/05/23 02:06 2-Butanone (MEK) ug/L ND 5.0 4.0 12/05/23 02:06 2-Hexanone ug/L ND 5.0 0.48 12/05/23 02:06 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 12/05/23 02:06 Acetone ug/L ND 25.0 5.1 12/05/23 02:06 Acrylonitrile ug/L ND 10.0 1.8 12/05/23 02:06 Benzene ug/L ND 1.0 0.34 12/05/23 02:06 Bromochloromethane ug/L ND 1.0 0.47 12/05/23 02:06 Bromodichloromethane ug/L ND 1.0 0.31 12/05/23 02:06 Bromoform ug/L ND 1.0 0.34 12/05/23 02:06 v2 Bromomethane ug/L ND 2.0 1.7 12/05/23 02:06 Carbon disulfide ug/L ND 2.0 0.36 12/05/23 02:06 Carbon tetrachloride ug/L ND 1.0 0.33 12/05/23 02:06 Chlorobenzene ug/L ND 1.0 0.28 12/05/23 02:06 Chloroethane ug/L ND 1.0 0.65 12/05/23 02:06 Chloroform ug/L ND 1.0 0.43 12/05/23 02:06 Chloromethane ug/L ND 1.0 0.54 12/05/23 02:06 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 12/05/23 02:06 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 12/05/23 02:06 Dibromochloromethane ug/L ND 1.0 0.36 12/05/23 02:06 Dibromomethane ug/L ND 1.0 0.39 12/05/23 02:06 Ethylbenzene ug/L ND 1.0 0.30 12/05/23 02:06 lodomethane ug/L ND 20.0 9.7 12/05/23 02:06 m&p-Xylene ug/L ND 2.0 0.71 12/05/23 02:06 Methylene Chloride ug/L ND 5.0 2.0 12/05/23 02:06 o-Xylene ug/L ND 1.0 0.34 12/05/23 02:06 Styrene ug/L ND 1.0 0.29 12/05/23 02:06 Tetrachloroethene ug/L ND 1.0 0.29 12/05/23 02:06 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 83 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 METHOD BLANK: 4228876 Associated Lab Samples: 92699658017, 92699658018 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers Tetrahydrofuran ug/L ND 10.0 3.5 12/05/23 02:06 Toluene ug/L ND 1.0 0.24 12/05/23 02:06 trans-1,2-Dichloroethene ug/L ND 1.0 0.40 12/05/23 02:06 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 12/05/23 02:06 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 12/05/23 02:06 Trichloroethene ug/L ND 1.0 0.38 12/05/23 02:06 Trichlorofluoromethane ug/L ND 1.0 0.30 12/05/23 02:06 Vinyl acetate ug/L ND 2.0 1.3 12/05/23 02:06 Vinyl chloride ug/L ND 1.0 0.39 12/05/23 02:06 Xylene (Total) ug/L ND 1.0 0.34 12/05/23 02:06 1,2-Dichloroethane-d4 (S) % 117 70-130 12/05/23 02:06 4-Bromofluorobenzene (S) % 100 70-130 12/05/23 02:06 Toluene-d8 (S) % 97 70-130 12/05/23 02:06 LABORATORY CONTROL SAMPLE: Parameter 4228877 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 20 18.8 94 70-130 1,1,1-Trichloroethane ug/L 20 21.3 107 70-130 1,1,2,2-Tetrachloroethane ug/L 20 19.9 99 70-130 1,1,2-Trichloroethane ug/L 20 20.2 101 70-130 1,1-Dichloroethane ug/L 20 19.5 98 70-130 1,1-Dichloroethene ug/L 20 22.4 112 69-131 1,2,3-Trichloropropane ug/L 20 19.2 96 70-130 1,2-Dibromo-3-chloropropane ug/L 20 16.8 84 70-130 1,2-Dibromoethane (EDB) ug/L 20 19.9 99 70-130 1,2-Dichlorobenzene ug/L 20 20.2 101 70-130 1,2-Dichloroethane ug/L 20 22.4 112 70-130 1,2-Dichloropropane ug/L 20 19.8 99 70-130 1,4-Dichlorobenzene ug/L 20 20.3 102 70-130 2-Butanone (MEK) ug/L 40 42.5 106 67-133 2-Hexanone ug/L 40 40.2 100 70-133 4-Methyl-2-pentanone (MIBK) ug/L 40 40.4 101 70-130 Acetone ug/L 40 44.3 111 67-130 Acrylonitrile ug/L 100 97.0 97 70-130 Benzene ug/L 20 19.4 97 70-130 Bromochloromethane ug/L 20 19.1 96 70-130 Bromodichloromethane ug/L 20 18.6 93 70-130 Bromoform ug/L 20 15.6 78 70-133 v3 Bromomethane ug/L 20 17.1 86 41-148 Carbon disulfide ug/L 20 19.7 99 70-131 Carbon tetrachloride ug/L 20 20.2 101 70-130 Chlorobenzene ug/L 20 19.4 97 70-130 Chloroethane ug/L 20 20.7 103 41-157 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 84 of 130 Pace Analytical Services, LLC 1377 South Park Drive aceo Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 LABORATORY CONTROL SAMPLE: Parameter 4228877 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Chloroform ug/L 20 19.0 95 70-130 Chloromethane ug/L 20 19.6 98 59-141 cis-1,2-Dichloroethene ug/L 20 20.6 103 70-130 cis-1,3-Dichloropropene ug/L 20 18.0 90 70-130 Dibromochloromethane ug/L 20 17.0 85 70-130 Dibromomethane ug/L 20 20.7 104 70-130 Ethylbenzene ug/L 20 20.5 102 70-130 lodomethane ug/L 40 33.2 83 57-140 m&p-Xylene ug/L 40 41.5 104 70-130 Methylene Chloride ug/L 20 21.4 107 62-130 o-Xylene ug/L 20 19.5 98 70-130 Styrene ug/L 20 20.0 100 70-130 Tetrachloroethene ug/L 20 19.5 97 70-130 Tetrahydrofuran ug/L 200 215 108 70-131 Toluene ug/L 20 19.5 97 70-130 trans-1,2-Dichloroethene ug/L 20 20.7 103 70-130 trans- 1,3-Dichloropropene ug/L 20 17.5 87 70-130 trans-1,4-Dichloro-2-butene ug/L 20 15.0 75 57-149 Trichloroethene ug/L 20 20.5 103 70-130 Trichlorofluoromethane ug/L 20 21.7 108 57-130 Vinyl acetate ug/L 40 44.1 110 70-141 Vinyl chloride ug/L 20 17.9 90 66-140 Xylene (Total) ug/L 60 61.0 102 70-130 1,2-Dichloroethane-d4 (S) % 106 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 98 70-130 MATRIX SPIKE SAMPLE: Parameter 4228878 Units 92700665007 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 24.9 124 70-146 1,1,1-Trichloroethane ug/L ND 20 26.6 133 70-150 1,1,2,2-Tetrachloroethane ug/L ND 20 24.9 125 66-144 1,1,2-Trichloroethane ug/L ND 20 25.5 128 70-142 1,1-Dichloroethane ug/L ND 20 25.9 130 68-150 1,1-Dichloroethene ug/L ND 20 28.2 141 64-162 1,2,3-Trichloropropane ug/L ND 20 23.8 119 66-144 1,2-Dibromo-3-chloropropane ug/L ND 20 22.8 114 62-146 1,2-Dibromoethane (EDB) ug/L ND 20 25.3 126 70-143 1,2-Dichlorobenzene ug/L ND 20 24.6 123 70-142 1,2-Dichloroethane ug/L ND 20 25.5 128 68-145 1,2-Dichloropropane ug/L ND 20 25.7 128 70-144 1,4-Dichlorobenzene ug/L ND 20 24.8 124 70-140 2-Butanone (MEK) ug/L ND 40 49.1 123 57-156 2-Hexanone ug/L ND 40 50.2 126 62-153 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 85 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 MATRIX SPIKE SAMPLE: Parameter 4228878 Units 92700665007 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 4-Methyl-2-pentanone (MIBK) ug/L ND 40 48.3 121 65-144 Acetone ug/L ND 40 50.9 127 49-162 Acrylonitrile ug/L ND 100 123 123 59-155 Benzene ug/L ND 20 26.1 130 68-144 Bromochloromethane ug/L ND 20 26.5 133 70-148 Bromodichloromethane ug/L ND 20 24.6 123 70-141 Bromoform ug/L ND 20 21.8 109 59-144 Bromomethane ug/L ND 20 19.3 96 23-190 Carbon disulfide ug/L ND 20 27.7 139 64-160 Carbon tetrachloride ug/L ND 20 25.8 129 70-147 Chlorobenzene ug/L ND 20 25.5 127 70-143 Chloroethane ug/L ND 20 29.5 147 55-1901K Chloroform ug/L ND 20 26.6 133 67-148 Chloromethane ug/L ND 20 23.9 119 38-180 cis-1,2-Dichloroethene ug/L ND 20 25.8 129 67-151 cis-1,3-Dichloropropene ug/L ND 20 24.0 120 70-142 Dibromochloromethane ug/L ND 20 23.5 118 68-140 Dibromomethane ug/L ND 20 24.4 122 70-142 Ethylbenzene ug/L ND 20 24.9 124 70-145 lodomethane ug/L ND 40 54.4 136 37-160 m&p-Xylene ug/L ND 40 50.0 125 70-148 Methylene Chloride ug/L ND 20 23.6 118 54-149 o-Xylene ug/L ND 20 24.6 123 70-145 Styrene ug/L ND 20 24.8 124 70-147 Tetrachloroethene ug/L ND 20 24.4 122 70-145 Tetrahydrofuran ug/L ND 200 243 122 48-160 Toluene ug/L ND 20 25.1 126 65-146 trans-1,2-Dichloroethene ug/L ND 20 27.3 137 69-155 trans- 1,3-Dichloropropene ug/L ND 20 23.7 118 70-142 trans-1,4-Dichloro-2-butene ug/L ND 20 22.9 115 39-149 Trichloroethene ug/L ND 20 26.1 131 70-152 Trichlorofluoromethane ug/L ND 20 28.0 140 60-158 Vinyl acetate ug/L ND 40 47.3 118 56-157 Vinyl chloride ug/L ND 20 23.7 118 51-178 Xylene (Total) ug/L ND 60 74.6 124 70-146 1,2-Dichloroethane-d4 (S) % 101 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8 (S) % 99 70-130 SAMPLE DUPLICATE: 4228879 92700665008 Dup Max Parameter Units Result Result RPD RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 86 of 130 Pace Analytical Services, LLC 1377 South Park Drive aceo Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 SAMPLE DUPLICATE: 4228879 Parameter Units 92700665008 Result Dup Result RPD Max RPD Qualifiers 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND 0.43J 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Acrylonitrile ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 30 Carbon disulfide ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND 0.58J 30 Chloroethane ug/L ND ND 301K Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 cis-1,2-Dichloroethene ug/L 0.51J 0.47J 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 lodomethane ug/L ND ND 30 m&p-Xylene ug/L ND ND 30 Methylene Chloride ug/L ND ND 30 o-Xylene ug/L ND ND 30 Styrene ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 Tetrahydrofuran ug/L 3.7J ND 30 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans- 1,3-Dichloropropene ug/L ND ND 30 trans-1,4-Dichloro-2-butene ug/L ND ND 30 Trichloroethene ug/L ND ND 30 Trichlorofluoromethane ug/L ND ND 30 Vinyl acetate ug/L ND ND 30 Vinyl chloride ug/L ND ND 30 Xylene (Total) ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 87 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 SAMPLE DUPLICATE: 4228879 92700665008 Dup Max Parameter Units Result Result RPD RPD 1,2-Dichloroethane-d4 (S) % 122 96 4-Bromofluorobenzene (S) % 100 94 Toluene-d8 (S) % 98 98 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 88 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 817062 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92699658019, 92699658020 METHOD BLANK: 4228887 Associated Lab Samples: 92699658019, 92699658020 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 12/05/23 01:18 1,1,1-Trichloroethane ug/L ND 1.0 0.33 12/05/23 01:18 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 12/05/23 01:18 1,1,2-Trichloroethane ug/L ND 1.0 0.32 12/05/23 01:18 1,1-Dichloroethane ug/L ND 1.0 0.37 12/05/23 01:18 1,1-Dichloroethene ug/L ND 1.0 0.35 12/05/23 01:18 1,2,3-Trichloropropane ug/L ND 1.0 0.26 12/05/23 01:18 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 12/05/23 01:18 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 12/05/23 01:18 1,2-Dichlorobenzene ug/L ND 1.0 0.34 12/05/23 01:18 1,2-Dichloroethane ug/L ND 1.0 0.32 12/05/23 01:18 1,2-Dichloropropane ug/L ND 1.0 0.36 12/05/23 01:18 1,4-Dichlorobenzene ug/L ND 1.0 0.33 12/05/23 01:18 2-Butanone (MEK) ug/L ND 5.0 4.0 12/05/23 01:18 2-Hexanone ug/L ND 5.0 0.48 12/05/23 01:18 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 12/05/23 01:18 Acetone ug/L ND 25.0 5.1 12/05/23 01:18 Acrylonitrile ug/L ND 10.0 1.8 12/05/23 01:18 Benzene ug/L ND 1.0 0.34 12/05/23 01:18 Bromochloromethane ug/L ND 1.0 0.47 12/05/23 01:18 Bromodichloromethane ug/L ND 1.0 0.31 12/05/23 01:18 Bromoform ug/L ND 1.0 0.34 12/05/23 01:18 Bromomethane ug/L ND 2.0 1.7 12/05/23 01:18 v2 Carbon disulfide ug/L ND 2.0 0.36 12/05/23 01:18 Carbon tetrachloride ug/L ND 1.0 0.33 12/05/23 01:18 Chlorobenzene ug/L ND 1.0 0.28 12/05/23 01:18 Chloroethane ug/L ND 1.0 0.65 12/05/23 01:18 Chloroform ug/L ND 1.0 0.43 12/05/23 01:18 Chloromethane ug/L ND 1.0 0.54 12/05/23 01:18 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 12/05/23 01:18 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 12/05/23 01:18 Dibromochloromethane ug/L ND 1.0 0.36 12/05/23 01:18 Dibromomethane ug/L ND 1.0 0.39 12/05/23 01:18 Ethylbenzene ug/L ND 1.0 0.30 12/05/23 01:18 lodomethane ug/L ND 20.0 9.7 12/05/23 01:18 m&p-Xylene ug/L ND 2.0 0.71 12/05/23 01:18 Methylene Chloride ug/L ND 5.0 2.0 12/05/23 01:18 o-Xylene ug/L ND 1.0 0.34 12/05/23 01:18 Styrene ug/L ND 1.0 0.29 12/05/23 01:18 Tetrachloroethene ug/L ND 1.0 0.29 12/05/23 01:18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 89 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 METHOD BLANK: 4228887 Associated Lab Samples: 92699658019, 92699658020 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers Tetrahydrofuran ug/L ND 10.0 3.5 12/05/23 01:18 Toluene ug/L ND 1.0 0.24 12/05/23 01:18 trans-1,2-Dichloroethene ug/L ND 1.0 0.40 12/05/23 01:18 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 12/05/23 01:18 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 12/05/23 01:18 Trichloroethene ug/L ND 1.0 0.38 12/05/23 01:18 Trichlorofluoromethane ug/L ND 1.0 0.30 12/05/23 01:18 Vinyl acetate ug/L ND 2.0 1.3 12/05/23 01:18 Vinyl chloride ug/L ND 1.0 0.39 12/05/23 01:18 Xylene (Total) ug/L ND 1.0 0.34 12/05/23 01:18 1,2-Dichloroethane-d4 (S) % 88 70-130 12/05/23 01:18 4-Bromofluorobenzene (S) % 99 70-130 12/05/23 01:18 Toluene-d8 (S) % 105 70-130 12/05/23 01:18 LABORATORY CONTROL SAMPLE: Parameter 4228888 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 20 21.1 106 70-130 1,1,1-Trichloroethane ug/L 20 19.9 100 70-130 1,1,2,2-Tetrachloroethane ug/L 20 19.5 98 70-130 1,1,2-Trichloroethane ug/L 20 20.1 101 70-130 1,1-Dichloroethane ug/L 20 18.3 91 70-130 1,1-Dichloroethene ug/L 20 17.9 89 69-131 1,2,3-Trichloropropane ug/L 20 19.3 97 70-130 1,2-Dibromo-3-chloropropane ug/L 20 20.4 102 70-130 1,2-Dibromoethane (EDB) ug/L 20 20.3 102 70-130 1,2-Dichlorobenzene ug/L 20 20.9 104 70-130 1,2-Dichloroethane ug/L 20 18.7 94 70-130 1,2-Dichloropropane ug/L 20 19.2 96 70-130 1,4-Dichlorobenzene ug/L 20 20.4 102 70-130 2-Butanone (MEK) ug/L 40 35.4 89 67-133 2-Hexanone ug/L 40 40.1 100 70-133 4-Methyl-2-pentanone (MIBK) ug/L 40 38.3 96 70-130 Acetone ug/L 40 36.4 91 67-130 Acrylonitrile ug/L 100 89.8 90 70-130 Benzene ug/L 20 20.0 100 70-130 Bromochloromethane ug/L 20 19.8 99 70-130 Bromodichloromethane ug/L 20 19.5 97 70-130 Bromoform ug/L 20 20.8 104 70-133 Bromomethane ug/L 20 17.7 89 41-148 v3 Carbon disulfide ug/L 20 19.4 97 70-131 Carbon tetrachloride ug/L 20 19.9 100 70-130 Chlorobenzene ug/L 20 20.6 103 70-130 Chloroethane ug/L 20 20.7 104 41-157 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 90 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 LABORATORY CONTROL SAMPLE: Parameter 4228888 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Chloroform ug/L 20 18.9 95 70-130 Chloromethane ug/L 20 17.2 86 59-141 cis-1,2-Dichloroethene ug/L 20 18.5 93 70-130 cis-1,3-Dichloropropene ug/L 20 20.0 100 70-130 Dibromochloromethane ug/L 20 20.3 102 70-130 Dibromomethane ug/L 20 20.9 105 70-130 Ethylbenzene ug/L 20 19.9 100 70-130 lodomethane ug/L 40 37.5 94 57-140 m&p-Xylene ug/L 40 41.1 103 70-130 Methylene Chloride ug/L 20 17.5 88 62-130 o-Xylene ug/L 20 20.7 104 70-130 Styrene ug/L 20 21.0 105 70-130 Tetrachloroethene ug/L 20 20.3 102 70-130 Tetrahydrofuran ug/L 200 178 89 70-131 Toluene ug/L 20 19.8 99 70-130 trans-1,2-Dichloroethene ug/L 20 18.3 91 70-130 trans- 1,3-Dichloropropene ug/L 20 20.3 101 70-130 trans-1,4-Dichloro-2-butene ug/L 20 23.0 115 57-149 Trichloroethene ug/L 20 21.6 108 70-130 Trichlorofluoromethane ug/L 20 19.4 97 57-130 Vinyl acetate ug/L 40 32.9 82 70-141 Vinyl chloride ug/L 20 16.3 81 66-140 Xylene (Total) ug/L 60 61.8 103 70-130 1,2-Dichloroethane-d4 (S) % 94 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8 (S) % 98 70-130 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4228889 MS 92701119005 Spike Parameter Units Result Conc. MSD Spike Conc. 4228890 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 23.9 24.4 119 122 70-146 2 30 1,1,1-Trichloroethane ug/L ND 20 20 24.9 25.4 125 127 70-150 2 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 21.6 22.5 108 113 66-144 4 30 1,1,2-Trichloroethane ug/L ND 20 20 22.1 22.7 111 114 70-142 3 30 1,1-Dichloroethane ug/L ND 20 20 22.8 22.9 114 114 68-150 1 30 1,1-Dichloroethene ug/L ND 20 20 23.0 24.2 115 121 64-162 5 30 1,2,3-Trichloropropane ug/L ND 20 20 21.0 22.1 105 110 66-144 5 30 1,2-Dibromo-3- ug/L ND 20 20 21.7 22.7 109 114 62-146 4 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 22.1 23.5 111 117 70-143 6 30 1,2-Dichlorobenzene ug/L ND 20 20 23.0 23.5 115 117 70-142 2 30 1,2-Dichloroethane ug/L ND 20 20 23.0 23.6 115 118 68-145 3 30 1,2-Dichloropropane ug/L ND 20 20 22.2 22.8 111 114 70-144 3 30 1,4-Dichlorobenzene ug/L ND 20 20 22.9 23.3 114 117 70-140 2 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 91 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4228889 4228890 MS MSD 92701119005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 2-Butanone (MEK) ug/L ND 40 40 40.9 44.5 102 111 57-156 9 30 2-Hexanone ug/L ND 40 40 42.4 45.9 106 115 62-153 8 30 4-Methyl-2-pentanone ug/L ND 40 40 41.2 43.3 103 108 65-144 5 30 (MIBK) Acetone ug/L ND 40 40 38.2 41.5 94 102 49-162 8 30 Acrylonitrile ug/L ND 100 100 99.3 106 99 106 59-155 6 30 Benzene ug/L ND 20 20 22.8 23.6 114 118 68-144 3 30 Bromochloromethane ug/L ND 20 20 22.5 23.1 112 116 70-148 3 30 Bromodichloromethane ug/L ND 20 20 22.9 23.2 115 116 70-141 1 30 Bromoform ug/L ND 20 20 23.0 24.2 115 121 59-144 5 30 Bromomethane ug/L ND 20 20 24.4 25.8 122 129 23-190 6 30 Carbon disulfide ug/L ND 20 20 22.6 23.2 113 116 64-160 2 30 Carbon tetrachloride ug/L ND 20 20 25.8 25.7 129 128 70-147 1 30 Chlorobenzene ug/L ND 20 20 23.1 23.9 115 120 70-143 4 30 Chloroethane ug/L ND 20 20 23.1 24.5 116 123 55-190 6 30 Chloroform ug/L ND 20 20 23.2 24.1 116 120 67-148 4 30 Chloromethane ug/L ND 20 20 21.3 21.3 107 106 38-180 0 30 cis-1,2-Dichloroethene ug/L ND 20 20 21.9 23.0 110 115 67-151 5 30 cis-1,3-Dichloropropene ug/L ND 20 20 22.7 23.2 114 116 70-142 2 30 Dibromochloromethane ug/L ND 20 20 23.0 22.9 115 115 68-140 0 30 Dibromomethane ug/L ND 20 20 22.6 23.2 113 116 70-142 3 30 Ethylbenzene ug/L ND 20 20 22.8 23.4 114 117 70-145 2 30 lodomethane ug/L ND 40 40 43.3 43.8 108 110 37-160 1 30 m&p-Xylene ug/L ND 40 40 46.7 48.6 117 122 70-148 4 30 Methylene Chloride ug/L ND 20 20 19.8 20.6 98 102 54-149 4 30 o-Xylene ug/L ND 20 20 23.0 23.7 115 118 70-145 3 30 Styrene ug/L ND 20 20 23.5 24.0 117 120 70-147 2 30 Tetrachloroethene ug/L ND 20 20 22.8 24.0 114 120 70-145 5 30 Tetrahydrofuran ug/L ND 200 200 197 211 98 106 48-160 7 30 Toluene ug/L ND 20 20 22.2 23.2 111 116 65-146 4 30 trans-1,2-Dichloroethene ug/L ND 20 20 22.9 23.6 115 118 69-155 3 30 trans-1,3-Dichloropropene ug/L ND 20 20 23.1 23.2 115 116 70-142 0 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 17.2 17.5 86 88 39-149 2 30 Trichloroethene ug/L ND 20 20 24.1 24.9 120 124 70-152 3 30 Trichlorofluoromethane ug/L ND 20 20 26.0 27.3 130 136 60-158 5 30 Vinyl acetate ug/L ND 40 40 36.9 38.9 92 97 56-157 5 30 Vinyl chloride ug/L ND 20 20 20.0 19.9 100 100 51-178 0 30 Xylene (Total) ug/L ND 60 60 69.7 72.3 116 121 70-146 4 30 1,2-Dichloroethane-d4 (S) % 105 106 70-130 4-Bromofluorobenzene (S) % 100 101 70-130 Toluene-d8 (S) % 98 97 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 92 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 817176 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92699658021, 92699658022, 92699658023 METHOD BLANK: 4229411 Matrix: Associated Lab Samples: 92699658021, 92699658022, 92699658023 Blank Parameter Units Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 12/05/23 00:18 1,1,1-Trichloroethane ug/L ND 1.0 0.33 12/05/23 00:18 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 12/05/23 00:18 1,1,2-Trichloroethane ug/L ND 1.0 0.32 12/05/23 00:18 1,1-Dichloroethane ug/L ND 1.0 0.37 12/05/23 00:18 1,1-Dichloroethene ug/L ND 1.0 0.35 12/05/23 00:18 1,2,3-Trichloropropane ug/L ND 1.0 0.26 12/05/23 00:18 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 12/05/23 00:18 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 12/05/23 00:18 1,2-Dichlorobenzene ug/L ND 1.0 0.34 12/05/23 00:18 1,2-Dichloroethane ug/L ND 1.0 0.32 12/05/23 00:18 1,2-Dichloropropane ug/L ND 1.0 0.36 12/05/23 00:18 1,4-Dichlorobenzene ug/L ND 1.0 0.33 12/05/23 00:18 2-Butanone (MEK) ug/L ND 5.0 4.0 12/05/23 00:18 2-Hexanone ug/L ND 5.0 0.48 12/05/23 00:18 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 12/05/23 00:18 Acetone ug/L ND 25.0 5.1 12/05/23 00:18 Acrylonitrile ug/L ND 10.0 1.8 12/05/23 00:18 Benzene ug/L ND 1.0 0.34 12/05/23 00:18 Bromochloromethane ug/L ND 1.0 0.47 12/05/23 00:18 Bromodichloromethane ug/L ND 1.0 0.31 12/05/23 00:18 Bromoform ug/L ND 1.0 0.34 12/05/23 00:18 Bromomethane ug/L ND 2.0 1.7 12/05/23 00:18 Carbon disulfide ug/L ND 2.0 0.36 12/05/23 00:18 Carbon tetrachloride ug/L ND 1.0 0.33 12/05/23 00:18 Chlorobenzene ug/L ND 1.0 0.28 12/05/23 00:18 Chloroethane ug/L ND 1.0 0.65 12/05/23 00:18 Chloroform ug/L ND 1.0 0.43 12/05/23 00:18 Chloromethane ug/L ND 1.0 0.54 12/05/23 00:18 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 12/05/23 00:18 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 12/05/23 00:18 Dibromochloromethane ug/L ND 1.0 0.36 12/05/23 00:18 Dibromomethane ug/L ND 1.0 0.39 12/05/23 00:18 Ethylbenzene ug/L ND 1.0 0.30 12/05/23 00:18 lodomethane ug/L ND 20.0 9.7 12/05/23 00:18 m&p-Xylene ug/L ND 2.0 0.71 12/05/23 00:18 Methylene Chloride ug/L ND 5.0 2.0 12/05/23 00:18 o-Xylene ug/L ND 1.0 0.34 12/05/23 00:18 Styrene ug/L ND 1.0 0.29 12/05/23 00:18 Tetrachloroethene ug/L ND 1.0 0.29 12/05/23 00:18 v2 v2 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 93 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 METHOD BLANK: 4229411 Matrix: Associated Lab Samples: 92699658021, 92699658022, 92699658023 Blank Parameter Units Result Water Reporting Limit MDL Analyzed Qualifiers Toluene ug/L ND 1.0 0.24 12/05/23 00:18 trans-1,2-Dichloroethene ug/L ND 1.0 0.40 12/05/23 00:18 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 12/05/23 00:18 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 12/05/23 00:18 Trichloroethene ug/L ND 1.0 0.38 12/05/23 00:18 Trichlorofluoromethane ug/L ND 1.0 0.30 12/05/23 00:18 Vinyl acetate ug/L ND 2.0 1.3 12/05/23 00:18 v2 Vinyl chloride ug/L ND 1.0 0.39 12/05/23 00:18 Xylene (Total) ug/L ND 1.0 0.34 12/05/23 00:18 1,2-Dichloroethane-d4 (S) % 91 70-130 12/05/23 00:18 4-Bromofluorobenzene (S) % 102 70-130 12/05/23 00:18 Toluene-d8 (S) % 97 70-130 12/05/23 00:18 LABORATORY CONTROL SAMPLE: Parameter 4229412 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 20 18.5 92 70-130 1,1,1-Trichloroethane ug/L 20 19.6 98 70-130 1,1,2,2-Tetrachloroethane ug/L 20 17.6 88 70-130 1,1,2-Trichloroethane ug/L 20 18.4 92 70-130 1,1-Dichloroethane ug/L 20 16.7 83 70-130 1,1-Dichloroethene ug/L 20 17.2 86 69-131 1,2,3-Trichloropropane ug/L 20 18.1 90 70-130 1,2-Dibromo-3-chloropropane ug/L 20 16.3 82 70-130 1,2-Dibromoethane (EDB) ug/L 20 18.0 90 70-130 1,2-Dichlorobenzene ug/L 20 17.7 88 70-130 1,2-Dichloroethane ug/L 20 17.3 87 70-130 1,2-Dichloropropane ug/L 20 17.1 85 70-130 1,4-Dichlorobenzene ug/L 20 17.0 85 70-130 2-Butanone (MEK) ug/L 40 31.5 79 67-133 2-Hexanone ug/L 40 32.2 81 70-133 4-Methyl-2-pentanone (MIBK) ug/L 40 31.7 79 70-130 v2 Acetone ug/L 40 32.5 81 67-130 Acrylonitrile ug/L 100 77.9 78 70-130 Benzene ug/L 20 17.5 88 70-130 Bromochloromethane ug/L 20 19.1 96 70-130 Bromodichloromethane ug/L 20 18.1 90 70-130 Bromoform ug/L 20 16.5 82 70-133 Bromomethane ug/L 20 16.3 81 41-148 v3 Carbon disulfide ug/L 20 17.5 87 70-131 Carbon tetrachloride ug/L 20 21.3 107 70-130 Chlorobenzene ug/L 20 17.7 89 70-130 Chloroethane ug/L 20 15.7 78 41-157 Chloroform ug/L 20 18.1 91 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 94 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 LABORATORY CONTROL SAMPLE: Parameter 4229412 Units Spike LCS Conc. Result Chloromethane ug/L 20 cis-1,2-Dichloroethene ug/L 20 cis-1,3-Dichloropropene ug/L 20 Dibromochloromethane ug/L 20 Dibromomethane ug/L 20 Ethylbenzene ug/L 20 lodomethane ug/L 40 m&p-Xylene ug/L 40 Methylene Chloride ug/L 20 o-Xylene ug/L 20 Styrene ug/L 20 Tetrachloroethene ug/L 20 Toluene ug/L 20 trans-1,2-Dichloroethene ug/L 20 trans- 1,3-Dichloropropene ug/L 20 trans-1,4-Dichloro-2-butene ug/L 20 Trichloroethene ug/L 20 Trichlorofluoromethane ug/L 20 Vinyl acetate ug/L 40 Vinyl chloride ug/L 20 Xylene (Total) ug/L 60 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % LCS % Rec % Rec Limits Qualifiers 14.5 72 59-141 16.0 80 70-130 17.3 86 70-130 18.2 91 70-130 20.5 102 70-130 17.4 87 70-130 34.1 85 57-140 36.3 91 70-130 15.6 78 62-130 18.3 92 70-130 18.1 90 70-130 19.5 97 70-130 17.6 88 70-130 17.2 86 70-130 17.9 90 70-130 23.9 119 57-149 19.6 98 70-130 17.1 86 57-130 28.9 72 70-141 v3 14.0 70 66-140 54.7 91 70-130 97 70-130 103 70-130 98 70-130 MATRIX SPIKE SAMPLE: Parameter 4229414 Units 92701221013 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 25.1 125 70-146 1,1,1-Trichloroethane ug/L ND 20 24.8 124 70-150 1,1,2,2-Tetrachloroethane ug/L ND 20 24.5 122 66-144 1,1,2-Trichloroethane ug/L ND 20 24.4 122 70-142 1,1-Dichloroethane ug/L ND 20 24.8 124 68-150 1,1-Dichloroethene ug/L ND 20 25.7 128 64-162 1,2,3-Trichloropropane ug/L ND 20 24.4 122 66-144 1,2-Dibromo-3-chloropropane ug/L ND 20 25.4 127 62-146 1,2-Dibromoethane (EDB) ug/L ND 20 25.1 126 70-143 1,2-Dichlorobenzene ug/L ND 20 24.8 124 70-142 1,2-Dichloroethane ug/L ND 20 24.1 121 68-145 1,2-Dichloropropane ug/L ND 20 24.2 121 70-144 1,4-Dichlorobenzene ug/L ND 20 24.6 123 70-140 2-Butanone (MEK) ug/L ND 40 52.8 132 57-156 2-Hexanone ug/L ND 40 52.0 130 62-153 4-Methyl-2-pentanone (MIBK) ug/L ND 40 51.5 129 65-144 Acetone ug/L ND 40 48.4 121 49-162 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 95 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 MATRIX SPIKE SAMPLE: 4229414 Parameter Units Acrylonitrile ug/L Benzene ug/L Bromochloromethane ug/L Bromodichloromethane ug/L Bromoform ug/L Bromomethane ug/L Carbon disulfide ug/L Carbon tetrachloride ug/L Chlorobenzene ug/L Chloroethane ug/L Chloroform ug/L Chloromethane ug/L cis-1,2-Dichloroethene ug/L cis-1,3-Dichloropropene ug/L Dibromochloromethane ug/L Dibromomethane ug/L Ethylbenzene ug/L lodomethane ug/L m&p-Xylene ug/L Methylene Chloride ug/L o-Xylene ug/L Styrene ug/L Tetrachloroethene ug/L Toluene ug/L trans-1,2-Dichloroethene ug/L trans- 1,3-Dichloropropene ug/L trans-1,4-Dichloro-2-butene ug/L Trichloroethene ug/L Trichlorofluoromethane ug/L Vinyl acetate ug/L Vinyl chloride ug/L Xylene (Total) ug/L 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % lyltLTil»:8Big] »1111111ydAI�1WIZI-115R] Parameter Units 1,1,1,2-Tetrachloroethane ug/L 1,1,1-Trichloroethane ug/L 1,1,2,2-Tetrachloroethane ug/L 1,1,2-Trichloroethane ug/L 1,1-Dichloroethane ug/L 1,1-Dichloroethene ug/L QUALITY CONTROL DATA 92701221013 Result ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Spike Conc. 100 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 40 40 20 20 20 20 20 20 20 20 20 20 40 20 60 MS MS Result % Rec 122 24.4 24.2 23.9 24.7 25.1 25.8 24.8 24.1 26.1 24.4 25.7 24.3 23.9 24.1 24.4 24.1 47.7 48.2 24.2 24.2 24.7 23.8 24.3 24.8 24.2 23.2 24.4 25.6 48.0 24.2 72.4 92701221010 Dup Result Result RPD 122 122 121 120 123 126 129 124 120 130 122 128 122 120 120 122 121 119 121 121 121 123 119 122 124 121 116 122 128 120 121 121 95 98 99 Max RPD ND ND 30 ND ND 30 ND ND 30 ND ND 30 ND ND 30 ND ND 30 % Rec Limits 59-155 68-144 70-148 70-141 59-144 23-190 64-160 70-147 70-143 55-190 67-148 38-180 67-151 70-142 68-140 70-142 70-145 37-160 70-148 54-149 70-145 70-147 70-145 65-146 69-155 70-142 39-149 70-152 60-158 56-157 51-178 70-146 70-130 70-130 70-130 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Qualifiers Page 96 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 SAMPLE DUPLICATE: 4229413 Parameter Units 92701221010 Result Dup Result RPD Max RPD 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Acrylonitrile ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 30 Carbon disulfide ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 30 Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 cis-1,2-Dichloroethene ug/L ND ND 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 lodomethane ug/L ND ND 30 m&p-Xylene ug/L ND ND 30 Methylene Chloride ug/L ND ND 30 o-Xylene ug/L ND ND 30 Styrene ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans- 1,3-Dichloropropene ug/L ND ND 30 trans-1,4-Dichloro-2-butene ug/L ND ND 30 Trichloroethene ug/L ND ND 30 Trichlorofluoromethane ug/L ND ND 30 Vinyl acetate ug/L ND ND 30 Vinyl chloride ug/L ND ND 30 Xylene (Total) ug/L ND ND 30 1,2-Dichloroethane-d4 (S) % 95 100 4-Bromofluorobenzene (S) % 100 97 Toluene-d8 (S) % 97 103 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 97 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 814843 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92699658001 METHOD BLANK: 4218479 Matrix: Water Associated Lab Samples: 92699658001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 11/22/23 04:57 1,2-Dichloroethane-d4 (S) % 90 67-130 11/22/23 04:57 Toluene-d8 (S) % 92 70-130 11/22/23 04:57 LABORATORY CONTROL SAMPLE: 4218480 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 16.6 83 70-130 1,2-Dichloroethane-d4 (S) % 88 67-130 Toluene-d8 (S) % 92 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4218481 4218482 MS MSD 92699611004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L 19.1 20 20 38.8 39.5 99 102 55-137 2 30 1,2-Dichloroethane-d4 (S) % 90 90 67-130 30 Toluene-d8 (S) % 92 91 70-130 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 98 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 814848 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92699658002, 92699658003, 92699658004, 92699658005, 92699658006, 92699658007, 92699658008, 92699658009,92699658010,92699658011,92699658012,92699658013,92699658014,92699658015 METHOD BLANK: 4218498 Matrix: Water Associated Lab Samples: 92699658002, 92699658003, 92699658004, 92699658005, 92699658006, 92699658007, 92699658008, 92699658009,92699658010,92699658011,92699658012,92699658013,92699658014,92699658015 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 11/21/23 18:15 1,2-Dichloroethane-d4 (S) % 93 67-130 11/21/23 18:15 Toluene-d8 (S) % 94 70-130 11/21/23 18:15 LABORATORY CONTROL SAMPLE: 4218499 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 21.1 105 70-130 1,2-Dichloroethane-d4 (S) % 92 67-130 Toluene-d8(S) % 94 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4218500 4218501 Parameter 1,4-Dioxane (p-Dioxane) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) MS 92699658002 Spike Units Result Conc. ug/L 18.9 20 MSD Spike MS MSD MS MSD % Rec Max Conc. Result Result % Rec % Rec Limits RPD RPD Qual 20 36.8 36.4 89 88 55-137 1 30 90 88 67-130 30 92 91 70-130 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 99 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 816527 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92699658017, 92699658018, 92699658019, 92699658020 METHOD BLANK: 4226412 Matrix: Water Associated Lab Samples: 92699658017, 92699658018, 92699658019, 92699658020 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 11/30/23 17:23 1,2-Dichloroethane-d4 (S) % 100 67-130 11/30/23 17:23 Toluene-d8 (S) % 101 70-130 11/30/23 17:23 LABORATORY CONTROL SAMPLE: 4226413 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane(p-Dioxane) ug/L 20 24.3 121 70-130 1,2-Dichloroethane-d4 (S) % 101 67-130 Toluene-d8(S) % 101 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4226414 4226415 MS MSD 92700665007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane(p-Dioxane) ug/L 6.1 20 20 31.6 31.5 128 127 55-137 1 30 P4 1,2-Dichloroethane-d4 (S) % 101 100 67-130 30 CO Toluene-d8 (S) % 98 99 70-130 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 100 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 816700 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92699658023 METHOD BLANK: 4227004 Matrix: Water Associated Lab Samples: 92699658023 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 12/01/23 14:44 1,2-Dichloroethane-d4 (S) % 95 67-130 12/01/23 14:44 Toluene-d8 (S) % 99 70-130 12/01/23 14:44 LABORATORY CONTROL SAMPLE: 4227005 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 20.7 103 70-130 1,2-Dichloroethane-d4 (S) % 96 67-130 Toluene-d8 (S) % 100 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4227006 4227007 MS MSD 92700857011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 21.6 21.2 108 106 55-137 2 30 1,2-Dichloroethane-d4 (S) % 95 94 67-130 30 Toluene-d8 (S) % 99 100 70-130 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 101 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 816961 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92699658021, 92699658022 METHOD BLANK: 4228435 Matrix: Water Associated Lab Samples: 92699658021, 92699658022 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 12/03/23 18:44 1,2-Dichloroethane-d4 (S) % 91 67-130 12/03/23 18:44 Toluene-d8 (S) % 91 70-130 12/03/23 18:44 LABORATORY CONTROL SAMPLE: 4228436 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 23.0 115 70-130 1,2-Dichloroethane-d4 (S) % 92 67-130 Toluene-d8 (S) % 92 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4228437 4228438 MS MSD 92700888006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 22.0 23.9 110 119 55-137 8 30 1,2-Dichloroethane-d4 (S) % 95 97 67-130 30 Toluene-d8 (S) % 95 96 70-130 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 102 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 816023 Analysis Method: SM 2320B-2011 QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92699658001, 92699658002, 92699658003, 92699658004, 92699658005, 92699658006 METHOD BLANK: 4223590 Matrix: Water Associated Lab Samples: 92699658001, 92699658002, 92699658003, 92699658004, 92699658005, 92699658006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Alkalinity, Total as CaCO3 mg/L ND 5.0 5.0 11/29/23 12:59 LABORATORY CONTROL SAMPLE: 4223591 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 mg/L 50 50.9 102 80-120 LABORATORY CONTROL SAMPLE: 4223592 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 mg/L 50 50.5 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4223593 4223594 MS MSD 92699898001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L 30.3 50 50 80.8 83.2 101 106 80-120 3 25 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4223595 4223596 MS MSD 92699907002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L 44.0 50 50 94.7 94.9 101 102 80-120 0 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 103 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 816336 Analysis Method: SM 2320B-2011 QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92699658007, 92699658008 METHOD BLANK: 4225336 Matrix: Water Associated Lab Samples: 92699658007, 92699658008 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Alkalinity, Total as CaCO3 mg/L ND 5.0 5.0 11/30/23 15:34 LABORATORY CONTROL SAMPLE: 4225337 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 mg/L 50 51.8 104 80-120 LABORATORY CONTROL SAMPLE: 4225338 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 mg/L 50 50.0 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4225339 4225340 MS MSD 92700191001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L 138 50 50 193 194 110 112 80-120 1 25 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4226089 4226090 MS MSD 92700200001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L 82.8 50 50 133 135 101 104 80-120 1 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 104 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 817300 Analysis Method: SM 2320B-2011 QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92699658017, 92699658018 METHOD BLANK: 4229915 Matrix: Water Associated Lab Samples: 92699658017, 92699658018 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Alkalinity, Total as CaCO3 mg/L ND 5.0 5.0 12/05/23 14:43 LABORATORY CONTROL SAMPLE: 4229916 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 mg/L 50 51.5 103 80-120 LABORATORY CONTROL SAMPLE: 4229917 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 mg/L 50 52.5 105 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4229918 4229919 MS MSD 92699658017 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L 247 50 50 287 294 80 94 80-120 2 25 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4229920 4229921 MS MSD 92699658018 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L 89.5 50 50 142 148 105 117 80-120 4 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 105 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 817301 Analysis Method: SM 2320B-2011 QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92699658019, 92699658020 METHOD BLANK: 4229927 Matrix: Water Associated Lab Samples: 92699658019, 92699658020 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Alkalinity, Total as CaCO3 mg/L ND 5.0 5.0 12/05/23 22:01 LABORATORY CONTROL SAMPLE: 4229928 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 mg/L 50 51.0 102 80-120 LABORATORY CONTROL SAMPLE: 4229929 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 mg/L 50 51.6 103 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4229930 4229931 MS MSD 92701334001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L 10.3 50 50 62.2 62.8 104 105 80-120 1 25 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4229932 4229933 MS MSD 92701334002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L 81.4 50 50 133 133 102 103 80-120 0 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 106 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 815397 Analysis Method: SM 2540C-2015 QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92699658001, 92699658002, 92699658003, 92699658004, 92699658005, 92699658006, 92699658007, 92699658008 METHOD BLANK: 4220963 Matrix: Water Associated Lab Samples: 92699658001, 92699658002, 92699658003, 92699658004, 92699658005, 92699658006, 92699658007, 92699658008 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Dissolved Solids mg/L ND 25.0 25.0 11/27/23 10:23 LABORATORY CONTROL SAMPLE: 4220964 Parameter Units Total Dissolved Solids mg/L SAMPLE DUPLICATE: 4220965 Parameter Units Total Dissolved Solids mg/L SAMPLE DUPLICATE: 4220966 Parameter Units Total Dissolved Solids mg/L Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 250 256 102 90-110 92699633003 Dup Max Result Result RPD RPD Qualifiers 1380 1310 5 25 92699658007 Dup Max Result Result RPD RPD Qualifiers 35.0 32.0 9 25 SAMPLE DUPLICATE: 4226112 92699898001 Dup Parameter Units Result Result Total Dissolved Solids mg/L 68.0 73.0 SAMPLE DUPLICATE: 4226113 92699907002 Dup Parameter Units Result Result Total Dissolved Solids mg/L 78.0 86.0 Max RPD RPD Qualifiers 7 25 H1 Max RPD RPD Qualifiers 10 25 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 107 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 816507 Analysis Method: SM 2540C-2015 QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92699658017, 92699658018, 92699658019, 92699658020 METHOD BLANK: 4226218 Matrix: Water Associated Lab Samples: 92699658017, 92699658018, 92699658019, 92699658020 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Dissolved Solids mg/L ND 25.0 25.0 11/30/23 17:41 LABORATORY CONTROL SAMPLE: 4226219 Spike LCS Parameter Units Conc. Result Total Dissolved Solids mg/L 250 248 SAMPLE DUPLICATE: 4226220 92699658017 Dup Parameter Units Result Result Total Dissolved Solids mg/L 265 273 LCS % Rec % Rec Limits Qualifiers 99 90-110 Max RPD RPD Qualifiers 3 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 108 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 815018 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92699658001, 92699658002, 92699658003, 92699658004, 92699658005, 92699658006, 92699658007, 92699658008 METHOD BLANK: 4219256 Matrix: Water Associated Lab Samples: 92699658001, 92699658002, 92699658003, 92699658004, 92699658005, 92699658006, 92699658007, 92699658008 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chloride mg/L ND 1.0 0.60 11/22/2310:31 Sulfate mg/L ND 1.0 0.50 11/22/2310:31 LABORATORY CONTROL SAMPLE: 4219257 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 50 53.0 106 90-110 Sulfate mg/L 50 53.3 107 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4219258 4219259 MS MSD 92699658001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L 1.2 50 50 51.0 52.5 100 103 90-110 3 10 Sulfate mg/L ND 50 50 50.0 51.4 99 102 90-110 3 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 109 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 816472 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92699658017, 92699658018 METHOD BLANK: 4226039 Matrix: Water Associated Lab Samples: 92699658017, 92699658018 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chloride mg/L ND 1.0 0.60 11/30/2319:11 Sulfate mg/L ND 1.0 0.50 11/30/2319:11 LABORATORY CONTROL SAMPLE: 4226040 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 50 51.1 102 90-110 Sulfate mg/L 50 51.4 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4226041 4226042 MS MSD 92700897001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L 16.1 50 50 67.1 68.6 102 105 90-110 2 10 Sulfate mg/L <1.0 50 50 51.8 53.3 103 106 90-110 3 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4226043 4226044 MS MSD 92700897014 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L 1.3 50 50 53.1 53.9 104 105 90-110 2 10 Sulfate mg/L 1.8 50 50 53.8 54.6 104 106 90-110 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 110 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 QC Batch: 816621 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92699658019, 92699658020 METHOD BLANK: 4226672 Matrix: Water Associated Lab Samples: 92699658019, 92699658020 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chloride mg/L ND 1.0 0.60 12/01/2313:06 Sulfate mg/L ND 1.0 0.50 12/01/2313:06 LABORATORY CONTROL SAMPLE: 4226673 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 50 51.8 104 90-110 Sulfate mg/L 50 52.1 104 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4226674 4226675 MS MSD 92701048001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L 3.5 50 50 53.3 54.4 99 102 90-110 2 10 Sulfate mg/L 2.5 50 50 52.5 53.6 100 102 90-110 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 111 of 130 Pace Analytical Services, LLC 1377 South Park Drive aceo Kernersville, NC 27284 (704)977-0981 QUALIFIERS Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. CO Result confirmed by second analysis. H1 Analysis conducted outside the EPA method holding time. IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. P4 Sample field preservation does not meet EPA or method recommendations for this analysis. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 112 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Rutherford Co Central LF 92699658 Nov23 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92699658001 8103-MW-2 EPA 3010A 815074 EPA 6010D 815182 92699658002 8103-MW-3 EPA 3010A 815074 EPA 6010D 815182 92699658003 8103-MW-13 EPA 3010A 815074 EPA 6010D 815182 92699658004 8103-MW-15 EPA 3010A 815074 EPA 6010D 815182 92699658005 8103-SW-2 EPA 3010A 815074 EPA 6010D 815182 92699658006 8103-SW-3 EPA 3010A 815074 EPA 6010D 815182 92699658007 8103-SW-4 EPA 3010A 815074 EPA 6010D 815182 92699658008 8103-SW-5 EPA 3010A 815074 EPA 6010D 815182 92699658009 8103-MW-4 EPA 3010A 815074 EPA 6010D 815182 92699658010 8103-MW-9 EPA 3010A 815074 EPA 6010D 815182 92699658011 8103-MW-10B EPA 3010A 815074 EPA 6010D 815182 92699658012 8103-MW-10C EPA 3010A 815074 EPA 6010D 815182 92699658013 8103-MW-10D EPA 3010A 815074 EPA 6010D 815182 92699658014 8103-MW-11A EPA 3010A 815074 EPA 6010D 815182 92699658015 8103-MW-11 B EPA 3010A 815074 EPA 6010D 815182 92699658017 8103-MW-12 EPA 3010A 816347 EPA 6010D 816488 92699658018 8103-MW-14 EPA 3010A 816347 EPA 6010D 816488 92699658019 8103-MW-16 EPA 3010A 816347 EPA 6010D 816488 92699658020 8103-SW-6 EPA 3010A 816347 EPA 6010D 816488 92699658021 8103-MW-6 EPA 3010A 816931 EPA 6010D 816954 92699658022 8103-MW-7 EPA 3010A 816931 EPA 6010D 816954 92699658023 8103-MW-8 EPA 3010A 816931 EPA 6010D 816954 92699658001 8103-MW-2 EPA 3010A 815071 EPA 6020B 815181 92699658002 8103-MW-3 EPA 3010A 815071 EPA 6020B 815181 92699658003 8103-MW-13 EPA 3010A 815071 EPA 6020B 815181 92699658004 8103-MW-15 EPA 3010A 815071 EPA 6020B 815181 92699658005 8103-SW-2 EPA 3010A 815071 EPA 6020B 815181 92699658006 8103-SW-3 EPA 3010A 815071 EPA 6020B 815181 92699658007 8103-SW-4 EPA 3010A 815071 EPA 6020B 815181 92699658008 8103-SW-5 EPA 3010A 815071 EPA 6020B 815181 92699658009 8103-MW-4 EPA 3010A 815071 EPA 6020B 815181 92699658010 8103-MW-9 EPA 3010A 815071 EPA 6020B 815181 92699658011 8103-MW-10B EPA 3010A 815071 EPA 6020B 815181 92699658012 8103-MW-10C EPA 3010A 815071 EPA 6020B 815181 92699658013 8103-MW-10D EPA 3010A 815071 EPA 6020B 815181 92699658014 8103-MW-11A EPA 3010A 815071 EPA 6020B 815181 92699658015 8103-MW-11 B EPA 3010A 815071 EPA 6020B 815181 92699658017 8103-MW-12 EPA 3010A 816344 EPA 6020B 816489 92699658018 8103-MW-14 EPA 3010A 816344 EPA 6020B 816489 92699658019 8103-MW-16 EPA 3010A 816344 EPA 6020B 816489 92699658020 8103-SW-6 EPA 3010A 816344 EPA 6020B 816489 92699658021 8103-MW-6 EPA 3010A 816711 EPA 6020B 816782 92699658022 8103-MW-7 EPA 3010A 816711 EPA 6020B 816782 92699658023 8103-MW-8 EPA 3010A 816711 EPA 6020B 816782 92699658001 8103-MW-2 EPA 7470A 815336 EPA 7470A 815355 92699658002 8103-MW-3 EPA 7470A 815336 EPA 7470A 815355 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 113 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Rutherford Co Central LF Nov23 92699658 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92699658003 8103-MW-13 EPA 7470A 815336 EPA 7470A 815355 92699658004 8103-MW-15 EPA 7470A 815336 EPA 7470A 815355 92699658005 8103-SW-2 EPA 7470A 815336 EPA 7470A 815355 92699658006 8103-SW-3 EPA 7470A 815336 EPA 7470A 815355 92699658007 8103-SW-4 EPA 7470A 815336 EPA 7470A 815355 92699658008 8103-SW-5 EPA 7470A 815336 EPA 7470A 815355 92699658017 8103-MW-12 EPA 7470A 817230 EPA 7470A 817355 92699658018 8103-MW-14 EPA 7470A 817230 EPA 7470A 817355 92699658019 8103-MW-16 EPA 7470A 817230 EPA 7470A 817355 92699658020 8103-SW-6 EPA 7470A 817230 EPA 7470A 817355 92699658001 8103-MW-2 EPA 8260D 816400 92699658002 8103-MW-3 EPA 8260D 816400 92699658003 8103-MW-13 EPA 8260D 816400 92699658004 8103-MW-15 EPA 8260D 816400 92699658005 8103-SW-2 EPA 8260D 816400 92699658006 8103-SW-3 EPA 8260D 816400 92699658007 8103-SW-4 EPA 8260D 816400 92699658008 8103-SW-5 EPA 8260D 816400 92699658009 8103-MW-4 EPA 8260D 816400 92699658010 8103-MW-9 EPA 8260D 816400 92699658011 8103-MW-10B EPA 8260D 816400 92699658012 8103-MW-10C EPA 8260D 816400 92699658013 8103-MW-10D EPA 8260D 816400 92699658014 8103-MW-11A EPA 8260D 816400 92699658015 8103-MW-11 B EPA 8260D 816400 92699658016 8103-Duplicate EPA 8260D 816400 92699658017 8103-MW-12 EPA 8260D 817059 92699658018 8103-MW-14 EPA 8260D 817059 92699658019 8103-MW-16 EPA 8260D 817062 92699658020 8103-SW-6 EPA 8260D 817062 92699658021 8103-MW-6 EPA 8260D 817176 92699658022 8103-MW-7 EPA 8260D 817176 92699658023 8103-MW-8 EPA 8260D 817176 92699658001 8103-MW-2 EPA 8260D Mod. 814843 92699658002 8103-MW-3 EPA 8260D Mod. 814848 92699658003 8103-MW-13 EPA 8260D Mod. 814848 92699658004 8103-MW-15 EPA 8260D Mod. 814848 92699658005 8103-SW-2 EPA 8260D Mod. 814848 92699658006 8103-SW-3 EPA 8260D Mod. 814848 92699658007 8103-SW-4 EPA 8260D Mod. 814848 92699658008 8103-SW-5 EPA 8260D Mod. 814848 92699658009 8103-MW-4 EPA 8260D Mod. 814848 92699658010 8103-MW-9 EPA 8260D Mod. 814848 92699658011 8103-MW-10B EPA 8260D Mod. 814848 92699658012 8103-MW-10C EPA 8260D Mod. 814848 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Page 114 of 130 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Lab ID Sample ID QC Batch Method QC Batch 92699658013 8103-MW-10D EPA 8260D Mod. 814848 92699658014 8103-MW-11A EPA 8260D Mod. 814848 92699658015 8103-MW-11B EPA 8260D Mod. 814848 92699658017 8103-MW-12 EPA 8260D Mod. 816527 92699658018 8103-MW-14 EPA 8260D Mod. 816527 92699658019 8103-MW-16 EPA 8260D Mod. 816527 92699658020 8103-SW-6 EPA 8260D Mod. 816527 92699658021 8103-MW-6 EPA 8260D Mod. 816961 92699658022 8103-MW-7 EPA 8260D Mod. 816961 92699658023 8103-MW-8 EPA 8260D Mod. 816700 92699658001 8103-MW-2 SM 2320B-2011 816023 92699658002 8103-MW-3 SM 2320B-2011 816023 92699658003 8103-MW-13 SM 2320B-2011 816023 92699658004 8103-MW-15 SM 2320B-2011 816023 92699658005 8103-SW-2 SM 2320B-2011 816023 92699658006 8103-SW-3 SM 2320B-2011 816023 92699658007 8103-SW-4 SM 2320B-2011 816336 92699658008 8103-SW-5 SM 2320B-2011 816336 92699658017 8103-MW-12 SM 2320B-2011 817300 92699658018 8103-MW-14 SM 2320B-2011 817300 92699658019 8103-MW-16 SM 2320B-2011 817301 92699658020 8103-SW-6 SM 2320B-2011 817301 92699658001 8103-MW-2 SM 2540C-2015 815397 92699658002 8103-MW-3 SM 2540C-2015 815397 92699658003 8103-MW-13 SM 2540C-2015 815397 92699658004 8103-MW-15 SM 2540C-2015 815397 92699658005 8103-SW-2 SM 2540C-2015 815397 92699658006 8103-SW-3 SM 2540C-2015 815397 92699658007 8103-SW-4 SM 2540C-2015 815397 92699658008 8103-SW-5 SM 2540C-2015 815397 92699658017 8103-MW-12 SM 2540C-2015 816507 92699658018 8103-MW-14 SM 2540C-2015 816507 92699658019 8103-MW-16 SM 2540C-2015 816507 92699658020 8103-SW-6 SM 2540C-2015 816507 92699658001 8103-MW-2 EPA 300.0 Rev 2.1 1993 815018 92699658002 8103-MW-3 EPA 300.0 Rev 2.1 1993 815018 92699658003 8103-MW-13 EPA 300.0 Rev 2.1 1993 815018 92699658004 8103-MW-15 EPA 300.0 Rev 2.1 1993 815018 92699658005 8103-SW-2 EPA 300.0 Rev 2.1 1993 815018 92699658006 8103-SW-3 EPA 300.0 Rev 2.1 1993 815018 92699658007 8103-SW-4 EPA 300.0 Rev 2.1 1993 815018 92699658008 8103-SW-5 EPA 300.0 Rev 2.1 1993 815018 92699658017 8103-MW-12 EPA 300.0 Rev 2.1 1993 816472 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /17/2024 04:40 PM without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Analytical Analytical Method Batch Page 115 of 130 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Rutherford Co Central LF Nov23 Pace Project No.: 92699658 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92699658018 8103-MW-14 EPA 300.0 Rev 2.1 1993 816472 92699658019 8103-MW-16 EPA 300.0 Rev 2.1 1993 816621 92699658020 8103-SW-6 EPA 300.0 Rev 2.1 1993 816621 Date: 01/17/2024 04:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Batch Page 116 of 130 iffVace ut:;F_ l Itte: tNV-l-KM-NUN1-0U83 v02_5ample Condition Upon Receipt Effective Date: 11/14/2022 Laboratory receiving samples: Asheville ❑ Eden[] Greenwood ❑ Huntersville Q €ialeigh❑ Mechanicsville❑ Atlanta)—!Sample tlanta)—! u�.�A-��• "-r' . . Client Name: Upon �r WOE :92699658 .. .. .. �' � Project q: ❑ Commercial ❑Pace x ❑UPS her: _ _�Clhnt III III 1111111111111111 92699658 J Custody Seal Present? Dyes 0<011 Seals Intact? ❑Yes No Packing Material: ❑Bubble Wrap Bubble Bags ❑None ❑ Other Thermomet I R G� un ID: �( Type of Ice: Wet ❑8 ue t C Correction Factor:? r Cooler Temp; I Add/Subtract-(•C) Cooler Temp Corre�e+7(' -� 6� o C/I ii'b USDA Regulated Soil ( N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC lcheck mansl? MYes rlNo Date/Initials Person Examining Contents: 4 Biological Tissue F zen? V7- ` Oyes [:]NO N/A [-]None Temp should be above freezing to 6"C ❑Samples out of temp criteria. Samples on ice, tooting process has begun Did samples originate from a foreign source (internationally, Comments/Discrepancy: _ Chain of Custody Present? Efyes ❑No ❑N/A 1. Samples Arrived within Hold Time? EKs ❑No ❑N/A 2 Short Hold Time Analysis (02 hr.)? Oyes No ❑N/A 3 Rush Turn Around Time Requested? Dyes 2< ❑N/A 4. Sufficient Volume? es ❑No ❑N/A S. Correct Containers Used? -Pace Containers Used? OYe3l❑No []No ❑N/A ❑N/A 6. Containers Intact? Z Yes ©No ❑N/ 7. Dissolved analysis: Samples Field Filtered? ❑Ye ❑No N/A & Sample Labels Match COC? Includes Date/Time/ID/Analysis Matrix: Yes ©No ❑N/A 9. Headspace in VOA Vials (>5-6mmj? ❑Y No ❑N/A 10 Trip Blank Present? Trip Blank Custody Seals Present? 2fYes ❑Yes �`N. ❑N/A ❑N/A 11. COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person contacted. Project Manager SCURF Review: Project Manager SRF Review: Qualtrax ID: 69614 Lot ID of split containers: Date/Time: Field Data Required? []Yes ❑No Date: Date: Page 1 of 2 Page 117 of 130 r%oM_t Me. elvv-rmivl-riurq t-uulss vuz bampie Lonamon upon Keceipt - -ace L%,..:u.�,, . Effective Date: 11/14/2022 4 *Check mark top half of box if pH and/or dechlorination is verified and Project A WO# : 92699658 within the acceptance range for preservation samples. PM: SK Due Date: 12/14/23 Exceptions: VOA, Coliform, ToC, oil and Grease, DRO/8015 (water) DOC. LCHg CLIENT: KR—RuthLandf "Bottom half of box is to list number of bottles ***Check all unpreserved Nitrates for chlorine CP E Z a a a C Ln v m Z v t' a 7 a E o w+ m z 9ar 2 a a E g 7 N m o ar a G _m a a .� m N y = = a J E $, y m N v Y a T a J C h z en m 2 d ¢ N a J E wr Is x = o N Q J E .~-� m v m W "' N �_ 3 ti 3 d d! E V a. •• C7 a v = N E Q x •+ W a i± N E a E ov eee m t9 a = V0{ N L E a �y t9 a Y O .O 4 J E tO Jr ra t7 a z y L E J dX E O a er t7 o u Q O 7 F p i m i9 Q z 4A m Q p J it v r w t9 y> „ C Q O J E o 7 a l7 = m T Q O ' E O > o+ t9 a a a N �o � E n 0. x} M A Y m 1O Z. tX7 2 W E w a On Z G v E N r d N ON a 0. E N m A. m d 2C] E E l9 a ? O Y C E v� n CN 9i ,D t t, o 1 Z 3 Z 3 4 `4L 5it it 17ji 6 ^ L � 3 7 � 3 1D 2 z z1 1z pH Adjustment Log for Preserved Samples Sample 10 Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot it Out •-•• ' --_• .1 •�Na �r a �« ... 151.V;u, �a1 V11„np d Uu,,odnce s21TTpres, a copy or cnis rorm wnt oe sent to the North Carolina DENR Certification Office tI e. Out of hold, incorrect preservative, out of temp, incorrect conta.ners- Qualtrax ID: 69614 Page 2 of 2 Page 118 of 130 Aace DC#_TItle: ENV FRM-HUN1.0083 v02 Sample Condition Upon Receipt Effective Date: 11/14/2022 'Check mark top half of box if pH and/or dechicrination is verified and within the acceptance range for preservation samples. Exceptions: VOA, COHI'Mm, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottles ***Check all unpreserved Nitrates for chlorine Project # L 2 di ma Z G! Z a Z v u N V n V g o Z dS ro n A c ar z ill 0.a` 6 z 2 �, Y z d n�i N I V n v z °y' '9 o V 2 z N N N d 7 a�i N Z W C r O ,� O o V a Z T i 0 q Z _� u d1 c — u T a y Q O = Ln T L Z x Z z Tr' b m 7 \ m L r1 7 b Z .o Z +_�v 0 N = ? w C o a1 c a E '^ a E a r C g !y a ° Is a J .n a ^� E o a J vEi b n J w 'o f d! E a «' n E a °: E a J E O .n E a � :: E a o E a „� E Z a a 7 J E q 0 J E Q O > J E ¢ O > E ,n a J E m CL m :: E ° ti E "' a E 4 ., o c v Ln E E a E m m cart m a aN ZA N m m M o m .in N-1 e m rl l7 a .-1 a N V' a ,.., t7 a N in L'i a Q Y 1.2 l7 o V Gsi t7 o m t? Q m V Y l'1 0 a N r a. 0. V i7 N IA in 0. a %M N IN N 0. tn r+ M M 6 aN c l7 4 tD N V 0 a Y a v, Ln m a > o 1 � 3 z 3 4 7 8 \ I \ \1_1 \�\ 3 9 ` N 31 10 j E 11 1Z pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservatlort adjusted Time preservation adjusted Amount of Preservative added Lot N ...­ s o u "cya.,,,Y 0„CLL1416 rvuMI -_arunnd cvn,pndnre sdmpFes, a copy or tn+s Form will oe sent to the North Carolina DENR Certification Office Ii e Out of hold, incorrect preservative, out of temp, incorrect containers. Qualtrax ID: 69614 Page 2 of 2 Page 119 of 130 AM DC# Title: ENV FRM-HUN1-0083 02 Sample Condition Upon Receipt Effective Date: 11/14/2022 *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC. LLHg **Bottom half of box is to list number of bottles ***Check all unpreserved Nitrates for chlorine Project 4 Z d z d m _ 2 a i v z N d z `7 z Q r i oV' 0 W a�i r- ca a 7 u at j u �, C = M x u m u N r y .Ni, „ a di a c 7 V n `v x N m 7 >v a v 'r�l = a O z z = z 4 z u z S O d u 4 M ^ ry u a a CIL N y 7 J ,n a J J g a ' J Q J 0 _u ...! ri a J o n a Q 41 a E a :: E .J o E Q a`r a J o E Q E 0 J E p 7 E O J E 0 E a E N +° J E E J E 41 E J o ca Ln E: E Q E ZL £ a; rt 3 a a �[o�rr1 rV 7 rn a lfl ", N a rr .r 0. ,E N.r yr v a n z M a vEi ,N.r N o 0. ,n Nr m a a 0 .a 7 N t7 .-I 2 .� l9 H M W to N Jf M l7 q a m V' v x a W Q r= a 0 O 2 A O Y } e, Pi an n a .M.. CY7 rNi N a N n a LA N Cr a ON 0 o N 0 l9 d at t3 m m m m m m m m 3 a Q a a a o a > > a x a ,n :n m a > a 1 3 3 z 3 3 3 4 5 6 7 g 9 10 11 1217 T pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot p Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy or th.s form will be sent to the North Carolina DENR Unification Office (i e Out of hold, incorrect preservative, out of temp, incorrect containers. Qualtrax ID: 69614 Page 2 of 2 Page 120 of 130 Pace' Location Requested (City/State): /�❑ pace Analytical Kernersville, NC ' CHAIN -OF -CUSTODY Analytical Request Document LAS USE ONLY. Affix Workorder/Logln Label Here �J G 3377 South Park Dr., Kernersville, NC 27294 Chain -al -Custody is a LEGAL DOCUMENT - Complete all relevant fields © Company Name: Rutherford County Landfill Contact/Report To: lames Kilgo Street Address: PO Box 1957, Rutherfordton, NC 28I39 Phone p: 929-297-6002 j�• E-Mail: james-kilgo@rutherfordcountync.gov 0 Scan OR Code for inglntct]ons Cc E•Maih f] 1 Q g/ q Customer Project s: a/+IlSae{ Invoice To: Accounts Payable Specify Container Size '• —Container Sim: (1)1L121500mL43)25OmL,(4) 125mL (s) (DOML (6) 40-L vial, (7) Encore, (2) Project Name: RutherfordCo,- CentralLandfill invoiceE•Mail: james.kllgo@rutherfordeountync.goy TemaCere, (9) Other Site Collection Info/Facility ID (as applicable): Purchase Order s (if Identify Container Preservative Type' • • •'• Preservative Types: (1) None, (2) NN03, (3) applicable):N2SO4• 14) NCI, IS) NaON, (6) 2n Acetate, 171 Nan504, (9) Sod. Thimulfate, M Ascorbic AUtl. (101 Analysis Requested Quote s: D0146952 McOH, (11) Other N m {e Proj-Mgr Stephanie Knott � - PT MT CT Time Zone Collected: [ ] AK t 1 ( I [ ] [ I ET County/ State origin of sample(s): North Carolina Data Deliverables: Regulatory Program (OW, RCIkk etc.) as applicable: ACCtNum /Client [D: ( ] Level II [ 1 Level Iry [ ] Level IV 7 m of v Rush (Pre-apprpvalrequiredj: DW PWSID s orWW permits as applicable: O Tables: ( ] EQU15 [ ] 2 Day ( ] 3 day ( ] S day ( )Other y eu - c0.� � 7 0 0 � E d Field Filtered (if applicable): ( ] Yes [ ] No 3 Profile /Template: Date Results ¢ O n U 0 a ( ] Other Requested: Analysis: G -6o 4 � c y 17056 rg v • Matrix Codes {Insert in Matrix box below]: Drinking Water (DWI, Ground Water (GW), Waste Water (WW), Product (P), Soil/Solid (SS), Oil (OL), Wipe (WP), Tissue, JTSI, &oassay (B]. Vapor (V), Drelog/Bottle Ord. ID: Other 107), Sufface Water (SW),Sediment(SEOI, Sludge(SLI• Caulk H U o v p m 0 0` o y C3 o Imp in 0 N 2:' C x EZ 3022750 a d Customer Sample ID Matrix' G74/ Collected for Ccmpo lle Start Composite End Res. Numbers Typeef [eMalnen Sample Comment G2 ca o to m m 3 Date Time Date Time Plastic Glass 8103-MW-1 WT 111,)0w, 13�, Li tv x x x x x 8103-MW-3 WT W)03 155D u X X X X X 8103-MW-12 WT X X X X X 8103-MW-13 Wl }��:) `1.�4rjrj X X X X X 8103-MW-14 WT X X X X X 8103-MW-15 WT it ��a3 loL� N U X X X X X 8103-MW-16 WT X X X X X 8103-SW-2 WT t�ld� X X X X WT I/ r X X X X X 8103-SW-3 1�55 8103-SW-4 WT ` �j w,(] ►A X X X X X Customer Remarks / Special Conditions 1 Possible Hazards: Collected By: Additional Instructions from Pace"'. Permit No. 8103-MSWLF-197418103-GOLF-2002 Printed Name: BLE Project No. J23-13657-06 Signature: g Coden: /� ;Fort Ce reetlan Factor I•Q: Obs. Temp. ('C) Corrected Temp. ('Q Profile 17056 Line 8(C&D) & Line 9(No C&D) Relinquished by! ompanY: (Signature) Qctu2 DateRme Receive by/ an ature]�.s,sr - _ Da !f'i Tracking Number j K �. Rrlin hed by/CampanY, (Signarum) oate/Time Iteeehed by/Company iSignaturel Duertme Delivered by ( ] fn• Person ( )[tuner N i5inaturel oatejrlme ( j FedEX [ i UPS [ )Other Relshed by/Copny' (Signature) eeeeietlby/Companyan Rebnthed bWrompany (Signatufel Datemme Received by/Company: (Svgnaturel Dale/rkne: Paige: 1 of 3 0 Subqttang a sample via this chain of custody constitutes acknowledgment and acceptance of the Pace* Terms and Conditions found at https.,//www.pacelabs.corn/resource-library/resourcefpace-terms-and-conditionsr ENV FRM-CORO-0019 v01_0621230 0 Pace* Location Requested (City/State): LAB USE ONLY. Affix Workorder/Login Label Here Pace Analytical Kernersville, NC CHAIN -OF -CUSTODY Analytical Request Document 1377 South Park Dr., Kernersvilte, NC 27294 Chainof-Custody is a LEGAL DOCVMENT - Complete all relevant fields Company Name: Rutherford County landfill Contact/Rellort To: lames Kitgo Street Address: PC Box 1957, Rutherfordton, NC 28139 Phone a: 828-297-6DO2 E-Mail; fames-kilgo@rutherfordcountyne.gov Scan OR Code for instructions Cc E-Mail: Customer Project a: lm,6C.e TO: Accounts Payable Specify Container Size •• "CortainerSi­ Ill it, (2)SoomL131250mt-(4) 125mt, IS) 200ml- IQ 40-L vial, (7) EnCefer (8) Project Name: Rutherford Co, - Central Landfill inv6ceE-Mail: james.kilgo@rutherfordcountync,gov Terra[are,(9) Other Site Col {w ion!nfo/Facility 10 tas applicable]: Purchase Order a(if Identify Container Preservative Type••• "' Preservative Types: 11) None. [2) HNO3, f31 applicable]: H2SO4, (a] NCI, IS) NaOH, (6) Zn Aterate, I7) NaH504, (8) $ad. Thiosulfate, l9f Ascorbic Acid.I1o) Analysis Requested Quote a: 00146952 McOH, (11) Other a Pro] Mgr. Stephanie Knott 4 1Z Time Zone Collected: I ] AK I I PT 1 :T I . !t County / State origin of sample(s). North Carolina Data Deliverables: Regulatory Program (OW, RCRA, etc.) as applicable: AoctNum/ Client ID: [ I Levu II [ ] Level III [ 1 Level IV in o m w q d 2 m v0 C7 m a O °i t' Rush [Pre -approval required]: OW PWSID a or W W Permit a as applicable: Table a: I I EQUIS 1: 2 Day [ 3 day I] 5 day [ I Other m a CL m x O 9 0 °' Field Filtered (if applicable); I ]Yes I ]NO Profile / Template: Date Results CL O a 4-a V 3 e E I I ocher Requested: Analysis. o O N � N w l - J J 3 y 17056 `€ Q ' Matrix Codes I nsert in Matrix box below): Drinking Water (DW), Ground Water (GW), Waste Water (WW], Product (P), Soil/Solid (SS), Gil 10L], Wipe (WP), Timm ITS), Bioassay (8), Vapor 1VI, Prelog / Bottle Ord. to: Other (OT), Surface Water (SW),Sediment (SEDL Sludge (SQ, Caulk H U o p O o o o m O m =_ � �x EZ 30227SO " a: Customer Sample ID Matrix • Como,/ CO eet or [omposke Stag Composite End Res, Number a Type of Conralnen Sample Comment Grab C12 N m m to Date Time Date Time Plastic Goss 8103-SW 5 WT t1l�ota3 I�c35 x X X X X 8103-SW-6 WT X X X X X 8103-MW-4 WT i�l ��?a y 15 X X X 8103-MW-6 WT X X X 8103-MW-7 WT X X X 8103-MW-8 WT X X X 8103-MW 9 WT {�C1. Y3 i h5 X X X 8103•MW-10B "a k a3 '%.�45 i X X X 8103-MW-IOC WT l` + 2, I i (a) j X X X 8103-MW 100 WT L�` / X X X Customer Remarks? Special Conditions Possible Hazards Collected By: Additional Instructions from Pace": Permit No 8103-MSWLF-1974 f 8103-CDLF-2002 Printed Name- 13LE Project No, J23.13657.06 Signature: _01a Coolers. Thernwmeter Correct" Factor ('C Obs. Temp- ('Cl Corrected Temp. (*C) Profile 17056 Line 8(C&D) & Line 9(No C&D) i Relinqunhed by/Company: (Signature) n lc, fad Datefime: Rereiued Il tI-)1ig()G bd un e ' ISignamr r Da1e/T a 1 5ft Tracking Number Reenuk1 e qd by/Company: (Signature) Date/T.— Rewired by/Cempamy: (Signature) Date)lnmr Delivered by, ( ] In• Person [ ] Courier N bylCompamy- (Signatwel Datepme I FedEx [ ]UPS [ 'Other Retingyf}hed by/Company: (Signature) Date/nmr Received Relingb&ed by/Company: (Signature) DatelYme. Received by/Company: (Signature! Date/Time: Page: 2 of 3 0 Subrij5ing a sample via this chain of custody constitutes acknowledgment and acceptance of the Pace" Terms and Conditions found at https://www pacelabs.com/resource- brary/resource/pace-terms-and-conditions) ENV-FRM-00RQ-0019, v01_082123 0 Pace* Location Requested (City/State) LAB USE ONLY- Affix WorkordedLogin Label Hero Pace AnalytiCa Kernersmde, NC CHAIN -OF -CUSTODY Analytical Request Document 1377 South Park Or., Kernersvdle, NC 27284 Chan-of-Custodyis a LEGAL DOCUMENT Cbmoleteal relevantfelds Company Name: Rutherford County LandP• Contact/Report To: lames K go Street Addresr. PO Box 1957, Rutherfordton, NC 28139 Phone N- 828-287-M2 E-Mad. james k Igo@rutherfordcountync.gov Scan OR Code for instructions Cc E-Mai Customer Project N. nvoice To Accounts Payabie Specify Container Size '• ••C4 L. iS)15ite: {1j 1L, [21500m71EnCwe, 181 125mL, {S)100mL, 16140mL vial, (7) EnCae.Iel Project Name: Rutherford Co. - Central Landfill Invoice E-Mail: james.kilgo@rutherfordcountync.gov TlrraCore. III Other Site Collection Info/FaCdity ID (as applicable): Purchase Order N (if Idernify Container Preservative Type— ••• Preset nrve Types: (1) None, (2) 1­11103, (31 applicable): N25O4, (4) MCI, IS) NaOM, (6) Zn Atetite, (7) NaM504, (8) Sod. Thwsulla[e, (4) Ascorbic Acid, (10} Analysis Requested quote N' 00146952 McOM, (12) Other m Prop. Mgr: Stephanie Knott Time Zone Caaetted: ( ; AK ( : PT [ . MT ( !Cr ET County.: State origin of sample(:). North Carolina Data Deliverables. Regu atory Program :DW, RCRA, etc ) as applicable: AoctNum / Client ID: I I Level N I ' Level lli [ : Leve. IV 421a o to rn m m CJ 41 e Rush (Pre -approval required): Ow PW51D N ar caw Permit N as appbpble: a c Table a: 1I EQUIS 2 Day 1: 3 day (' 5 day [' Other $, m — c 0 0 L E m o a Field Fltered (if applicablel: I 'Yes [ ]NO 9 Profile / Template: Date Results 6wo — d CL L) Sc( IOther Requested: Analysis: to O O ¢ W ran 17056 0 • Matrix Codes I nsert n Matrx box belawl- Drinking Water DWI, Ground Water (GW), Waste water (caw), Product (PI, Sod/Solid (SS), Oil(OL), Wipe (WP), Tissue (TS), Bioassay (B), Vapor [vl, Prolog /Bottle Ord. 10: Other (O1), Surface Water ISW),Sediment (SED), Sludge t5L], Caulk 0 o se o o 0 m a o fin 0 o Cj 0 0 N 5 Y IZ 3422750 y Sample ID Matrix' Coin / Collected m Composite Start a Composite End Res- NumWraTypeN Centalrters Sample Comment Customer Grab Ll2 N to to tm+t to to 8 Date Time Date Time Plastic I Glass 8103-MW-IIA WT'n X X X 8103-MW-118 WT n2, % X X X 8103-Duplicate WT yrr-) X alai Customer Remarks / Special Conditions / Possible Hazards: Collected Permit No. 8103-MSWLF-1974 f 8103-CDLF-2002 Printed By: }r Additional Instructions from Pace": Name: 1.ij BLE Project No. J23-13657-DB Signature: a coolers: or ('q: obs. Temp. CTemp- CI Corrected I-c1 ;� Profile 17056 Line 8(C&D) & Line 9(ND C&D) 6o: -%/ i S -r1 1 Relinquishedby/Comm pang (Signature)75�rn Dat ff•me:ReWed tt /Compan kgrivtur a t� 4a7 me: Tracking Number: ihe V �Jt Relinquished by/Company (5i9,u ture) Daieffime Received m by/Copany' (Sigma Wrle))j Dlartf' me. Delivered by: [ I In. Person I 1 Courier N ( j FedEX I ) UPS ( ) Other flelingpphetl by/Company, ISignuurd batefrimr Recened by/Company aignmore) Oate/time: RNing0tilhed by/Company, (Signature; Datefrime, Reuived by/Cempanyt (Signature) Date/rime. Page: 3 Of 3 0 Subrtting a sample via this chain of custody constitutes acknowledgment and acceptance of the Pace" Terms and Conditions found at https://www.pacelabs.com/resource-library/resource/pace-terms-and-conditionsj ENV-FRM-CORD-0019_VD1 082123 m CD : ace 17C# Title: ENV-FRM-HUN1-0083 v02 Sample Condition Upon Receipt Effective Date: 11/14/2022 Laboratory receiving samples: Asheville 0 Eden[] Greenwood ❑ Huntersvipe Client Name; Raleigh❑ Mec' _ • �O� . 92fi99fi5H� n Receiptr �ar�pd' �. �. CL-t yl ; t( PM: SK Du* Date: 12/ 14 /23 Courier: OlFed Ex ❑UPS ❑LISPS ❑Client CLIENT: KR—RuthLandf ❑ Commercial Pace ❑Other. Custody Seal Present? ❑Yes []r6 Seals Intact? []Yes [?N✓o L �� Packing Material: �bble Wrap ❑Bubble Bags ❑None ❑ Other Thermometer: �un ID. 0 Type of ice: 'ELVM ❑Blue Correction Factor: Cooler Temp: 1= - Add/Subtract ('C)rr-- r G' Cooler Temp Corrected ('Cj: 11 USDA Regulated Soil (Wf/A, water samplel Did samples originate in a quarantine zone %vithi)i the United States: CA, NY, or SC Oate/Initials Person Examining Content$:_t llpi y Biological Tissue F oxen? ❑Yes ❑No ! N/A ❑YOne Temp should be above freezing to VC ❑Samples out of temp criteria Samples on ice, tooting pfocess has begun Did ampres originate from a loreign source tinter nationally, ,check maps)? (_jYeS WNo including Raw311 and Puerto Ricotr Uyes L4T40 Comments/Discrepancy: Chain of Custody Present? -4ETrs ❑No ❑N/A 1 1. 2. Samples Arrived within Hold Time? Yes . ra ❑N/A Short Hold Time Analysts (02 hr.)? []Yes DN. ❑N/A _ 3, Rush Turn Around Time Requested? []Yes QWQ ❑N/A 4. Sufficient volume? s ❑No ❑NIA S. Correct Containers Used? -PaCe Containers Used? Qrees CIVers ❑No ❑No ❑NJA ❑N/A G. Containers Intact? Yes Duo ❑NIA 7, Dissolved analysis: Samples Field Filtered? ❑Yes ❑No • 3WIC Sample Labels Match CDC? Yes ❑No ❑N/A -includes Oat e/fime/ID/Analysis Matrix: R. 9. - I Headspace in VOA Vials (a5•Gmmj? ❑Yes JQAroO' ❑N/A - )O_ Srip Stank Present? Trip Blank Custody Seals Present? Dyes oyes LjNa ❑No ©N/A.— 6H/A 11. — COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Qualtrax ID- 6961ti Lot ID of split containers: Date/Time. Oat e : Field Data Requirew vYes LINO Page 1 of 2 Page 124 of 130 ��'ace pC#_Title: ENV-FRM-HUN1.0083 v02 Sample Condition Upon Receipt a Effective Date: 11/14/2022 'Check mark top half of box if pH and/or dechlorination is verified and project 0 within the acceptance range for preservation samples. Exceptions: VOA, Coliform. TOC, Oil and Grease, DRO/8015 (water) DOC. LUIC "Bottom half of box is to list number of bottles -� "•Check all unpreserved Nitrates for chlorine z d d = Y n ry• > y w d n X a 't w Z ?• iu Z - UA' A t v ? a q 7 c y a O 6 A 4 S N 2 n n U O %1 mId C R R C E G E a a z 4 E D Q 7 y 0 I U 0 A a a JG d a V b w .. Al - a 1 C L E ,,, E § 7 7 7 7 V1 9UG1 d a d d y .. m ca m; m m o E E v o — a m ,N.1 N tl •., Z N m u 7 rX+ a o a- t7 t7 cm7 lti m m m d d 4 Q\ c ry V N O W 40 Q C] V 0 I f 0 u O 7 5 V ] i s' � o- O 1c Y � 7 F a ,n E F cc 3 a a o � � ,n I m Q S E �7 o ` 3 I _ ti 10 �SU Note Whengeer there rs a discrepancy affecting North Carolina coml Out of hold, incorrect preservatroc, out of temp,,ncorreCt Containers. Quallrax ID 69614 Amount of Preservative added this farm will basenito we North Carolina DENR-_celdicaua-'. 011ce ;rc Page 2 of 2 Page 125 of 130 rT Pale' LMai44 Aeolesled lclylstatel. Pi:tAna •yUcil%!*nlrivdigNC t' 1377 Soulry Park Dr., Ke,,Wsr Ic, NC 27284 CHAIN -OF -CUSTODY Analytical Request Document C13-01-Custody Is a I EGAL DOCUMENT- CemDlete alt relevant 1�clos V LAB USE DNLY Alba WD/kefdar(Laelrl VBet Here Scan QR Code for nSVWion$ co -Da" Name. Ru&erford County Landfill Suet Address: PO So. 1957, Ruthrrfcrdton, INC 29139 cv.mnr:, wnMn d Pro en ma' . Otwherfurd CG -Centra; WnCfill s:e[dlen-or ln'e; F—.t, 11);a, apAliaerF. CwtarJAreon To: tames Kpgo Pnax4c 828-281-NO2 E-N.aatjanws.kilgogDrutherfordcountynC.Cay Cc E-Mail: Inv94e To' Accounts Payable InyoceE Ma,I jamen. kllgaprutiseffordcoictync.gov Prn[nasr Orde•r(.1 aAPbclbleV: Quole A: Dtl14F9S2 Soeciv Coma.", We -•Corr-15Me III 1.,12 Sooml,Is MIr-LI41 175•n:, 1S1100m bl 40mi M> 71 LMae 31 It ) otbr, luentdr Conta4er Preserve ve TYae"• ">•n.,wu„r'rp•s ltl Nor>.121-C1,151 a7So4, (al •4L Is1 NatlN. ;tl :r rr•uer :7) W rSpa- [a) soe. 1v9wBase . tDl Meor 'Lt. dear, A+ia'ys-s Rrquewed t.mr lone mcecera: I ] AK I ] PI I ] Ms j ] [T I j E r Counrr l State or pn 91 sample(sl: North [.uohna p �j d o n U a N w A m dp �' CCC c m w A i n a c W m sx v- S o b a 7j y ¢ ua c Q U Z Pra(. MJI Stephanie Knott 6 9 !t E Data Del,vr•. bees: I ;Le•e:D I jlevel lit ] jLr—I IV I iEDL,IS I I Dtner A"Mlat9•Y P,9,•am low, RCAA, etc.f as acali(ame: ACCINumlClent sD' � Ruth [Pre -approval required): I 170av 1 13 day 15 day I jOther Date RLsYlts RequeFted: DW PWS4b46rWWPNmi1Pas aDp4cib'e: o hale A: Field F,tte•ed (1 applicable): ( I Yes I I ND Analytl: Prolile 7 Temalale: 1TD56 ' Mains C9des llrsrR ,n Ma;,.r bur brbwl. D,-nkw, Wafer (OWL Ground Walk, IG%vL Waste Wal9, 1W W L P•pducl IPl, So VSGhd (SSL Oa (OLl. vym (wPj. T-ssw ['Sl. P—my (B). Vapor IV), oinrr ,Orl, 5u•!ar water Iswlsedimlr,r ISEDh 5kw,e tsll, caulk Preloa / BAetle Ord.ltl' EZ 3022750 Customer Sample ID Malri4>aCl 91tY1 Br Com P41r Sterol Canpdsire End Res. CL2 Mumb ,A CeAlain[•n Ppstk Type M Gran Samp(e Comment Date T1me tl,,te Time 8103•MW-2 WT X X X X X 8103-MW-3 wT X x x X X 8103-MW-12 WT �l yg L••� (� X is X X X 8103 MW 13 WT x x X X x 8103-N1W-14 W7 i t� �j)3 i3� 5 �{ x x x x x 8103-MW-15 WT x x x x x 8103-MW-16 WT VA 2, �` l�� {� x X X X X 8103-$W-2 WT x x X X x 8103-SW-3 WT x x X X X 8303-5W4 INT x x x x x Cusiomef RHnar%sl Special Conditions I Possible HataMs' PermnNo' at03MSWLF•197418103-CDLF-2002 BLE ProjeCI No. J23-13667-06 ProStD 17056 Une BjCAO) S Line 6(No CBDJ Corleaed Prins9dNamer Sq;nieme By: f r M1':� •�Ll yp,.��n � Additional Instructions rrom Pace• re9aers. 'nermo,eeta lo. Ca.rn:a•Fanxt•el Obti temp.I•) cm, Nitema. t'ct 4rknpuMra brlComwny IS•E�Mew j KU- Date/t,mr les d wKomwnr Isienalurrl DneR�me: 1 1od Iran-, Number e,-aunreetk,/C-0 ny Isp,.lc'el pah/rvne ket4VeP eWIc9mParr isWufurn Da./t e. De:mred By [ : In• Person 1�1 Cour�r+ I I FetlE% )UPS I I Other eelm9s,shed blicamwnr IS,it—w Cahn e. ketow•dbvX—N1y n'F-11 el Melt-r: eel-esnkeeOrFComwnrlsrpatu,el �h/tour. Aeremr/Brlco,nwryls;ratu,lf Jate/t,me Page: 1 of 3 Sibniting a sample via this chain of custody constitutes acknowrPdgment and aC[eAWnce9l the Pic&^ Terms ano Lonations soulto al ntApse)ryvww-pxelaps.conrrewurcc-nvr4ry7,9wu,ccrv..c-w�•��>-a •�-.....��•.r-•-••••••--••-----_--• Rare' I.W210n Rear —tea (t1y/51atej; Pau M+IyT..I Krr,rn>n!1e, NC LA9 VSE ONLY -Alva W*rk-der&*gln Label Here CHAIN-OF-CU5TOdY 1377 SolAn Park Dr., K+rnery.,f:l, NC 27294 Analytical Request Document Chan-0-CunodY 4 a LEGAL DOCUMENT. Complete au ro!Qaanl !.t:,s Company Na'ne, Rutherford Cuunly Landfill Zoltan/Rein To' - lames KAgD Svc t Add,MS PO Boe 1957. Rutherlordlon, NC 28139 °^one • 828Q87.6002 james.Eilgo�rutherfwdcoomiynt,go, SCM OR Code fOf inSVUclipn$ Ct E Nsaa: C1:51on ' 9r0' r A lnry .te To: Accounts PayaSte vp1ltl Name. Rutherford Co. - Centrat Landfill 1nro.c. UM. -I: j]mes. kdgokiSrotherfordcourarrac gun Sxerty Ce+lamer sa! •• SIQCol.rct on Inro(rannty ID fas appkablel: Pva•chast- Order a pf 11 .DoFitablej Irlenl�fyCM1 Pret@ryitiyf: Cuote a; 00146952 Ati ya:s Regaested Time24ne CCt![Led. I ;AK I IPT I 'MT [ )CT i IET Cpun1Y/State or:g�n ofumphlsl; North Carolina Data pl Vt+ablM P•CC'+m tDW, RCRA. elt I ofI Le-e III [ Iier! IVRush[Pre-approval jRd0LJJIffnr required;: Dw Pwlip a or WW Perml P as tpp65abe.oFOV.S tPar 1 13d+r ( I;d]r I .Other n ; Results fiea i u.e f fd ""itNo�IOlher • ested: Malnw b o C Matns [odor (rnsrn in UIJNk bba beidwj pnnking Water IDw), Ground Waite (GW). Waste Walx [W W;. P•oduct IPp, Sp 1/5d6d I;51. 0•' IDLi. wipe 15YP;, TnsW Ril. S wtwr [BL +Pa {VI. z Omrr[OTI, a sur'att Wrer (Swl,Sedimenf f5F01, slvoge ISU, lurk c dv J N Cultpmel sam Ie ID P camp/ 01 a Ma[riA• or Corn ite Stan Mumbara Type of U Composite end Res. o C 41 t .� Gras Date Time co. O]te Time CL2 PLenit Glow err r� rg m io a 8103 5W-5 WT X X X X X 8703•SW-6 WT 8103•MW-4 WT X X X 8103•MW-6 WT X X X 8303-MW-7 WT 8103•MW-8 11 X X X 8103-MW 9 WT X X X 8103-MW108 WT X X 8103-MWlOC WT X X X 9103•MW-10D WT X X X :ostomer Rer. ks / SPedal Cand1trons / Possible Hetards: Oy' 'rfrnit ND. 8T03AASWLF19741 Bf03-COLF•2002 �M1IMed TQp Namf: }� t1 / r LL- Addtionsl instructions fromPacea: ELF No. 1 a 170l a 8(C&E57.08 'rofie 17056 Line 8(C8D)6 Line 9(Na C6D) . Cna.a+ TarnnomHer 1b; rlti,4wtra ba.2onpanr [Sgnarr�el pale7r�mr-7 a.[a�.ee MKa+o.nr tsdn]ru,el ?au/r ibmrning a sample via this chain CD N N 4 O D+rlr,me. Reteraeo brKwnamr IsiRat..el D+tr mr WIWI . 4r+"fQ PrlCamp+^r ;s�an+rurcl pap77mr: Dale/T.me Retr._ br/Cempany, ISKnaTerrl on Rimf: acknowledgment and acceptance of The➢ate' Terms and Conditions found at httAs'J/www pacetaos.cal-Vresoumelibrary/msource/pwe-terms-and-condrtbnsr 125m4 (5) ID01-', 161 adnL na1,111 E^car, Iel rit'WoNi. 191 Omer Pr.e t—tetra f11 No-. nNo]. 131 — .t5D4, I4I HCL (51 Naow,'61 rr Krt+te.'71 rar5o+, 1815oa. rkoavR+rr. 191 Axa6t Atd. q?} feDH.1111 CIMr Oral. regr. Stephanie Knott e 9 Profile /Templa:e. 17056 PvOs / Boole Ord ID: EZ 3022750 Sample commend P[a Din Tin.. I'C] Conrned *" N mbar w,tiltr! [ I1�-Pe son (�jtdp.rcr ( 1 Fedfll I I LIPS I I Other Page: 2 of 3 W CD lVace IJS.* I ILI C. Gltl v-rr\It1'1 It1Io r-uvcrs vvs._. urr it— vv —1uv.+ +w�u.l... Effective Date: 11/14/2022 Laboratory receiving samples: Asheville ❑ Eden[] Greenwood ❑ Huntersville Raleigh❑ Me Sample Cordition Client Name: Courier: ❑Fe Ex ❑UPS ❑USPS ❑Client WO# : 92699658 ❑ Commercial ace ❑Other:— -- Custody Seal Present? ❑Yes No Seats Intact? ❑Yes No t 7 Date/Initials Person Examining Contents: / Packing Material: ❑Bubble Wrap Bubble Bags ❑None ❑ Other Biological Tissue ten? ThermometIRG ❑Yes ❑No N/A unID: T71Y' Type ,�wet 6tue [lone Correction Factor: Cooler Temp: Add/Subtract IT) Temp should be above freezing to 6'C ❑Samples out of temp Criteria. Samplei on.ce. Cooling process Cooler Temp Corrected ('Cy has begun USDA Regulated Sail ( N/A, water sample) Did samples originate in a quarantine lane within the United States: CA, NY, or SC Did samptes originate Isom a foreign source. (internationally, ;Check maps)? LJYes LJNo muuuing nawan anu rurr.o —1-y.o t_J— _11 Comments/Discrepancy: I Chain of Custody Present? Yc ❑No ❑N!A i. Samples Arrived within hold Time? Yes ONO ❑NfA _2 , Short Hold Time Analysis (02 hr.)? Yes ONo ©N/A Rush Tum Around Time Requested? ©Yes Nn DN?A _3 4. Sufficient Volume? a ON. ❑N/A S. Correct Containers Used? y Ono ❑N/A 6. -Pace Containers Used? kJy ❑No ❑N)A Containers Intact? EfYips ONO ❑NIA 7 Dissolved analysis. Samples Field Filtered? QYes QNo ErNIA R. Sample Labels Match COC7 iCi [:]No ❑1,11A 9 -Inckldes Date rime/lD/Anatysis Malrw i HHeacispace in VOA Vials 1>5-6mml? []Yes Err ON/A 10. _ Trip Blank Present? Dyes ffNo QN/A 11. Trip Blank Custody Seals Present? QYes 0No -[JNIA COMM ENTS/SAMPtE DISCREPANCY rieovarynegwreur u.c� vi.� CLIENT NOTIFICATION/RESDLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Qualtrax Id 69614 Lot lD of Split Containers' Date/Tirne. Date: Date: Page 1 of 2 Page 128 of 130 aee - :.„ Effective Date: 11/14/2022 "Check mark top half of box if pH and/or 4echlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Colifotm. TOC, Oil and Grease, DRO/8015 lwaterl DOC. tU+g "Bottom half of box is to list number of bottles * "Check all unpreserved Nitrates for chlorine Project A F-- _ 0 d v O U V < �. v z Z p ? a 0. V .'3 a rs C j iO a V N Q 4 Q e i Z z 'a 7 S N W y w is A q i n ,y a E c C ry Q z u 7 A x x I w S Z d a n E -o E E a E q E .Z_-- -N ry U ,p 2 a q O O > } ? G n L C - d Y W G O O r. G Q A E E s 7 ... m m E 7 m ; E E E E v N ,it Z N to �7r Q6 a m m a m m _m m E v E E x. r9i tie a t7 V l7 V' U' U 4 4 a -E q E E x l7 > 7 c E E m E E E 7 -. 7 a V V a a a r a >' G Y VI �+ m 4 E E a 13 \+ \ 3 - I \ 3 3 4 I i \ �\ `_ j� _ \\�1\ Ni\\ _��\ —� I\ I\--- 3 12 pH Adjustment Log for Preserved Samples I Sample ID Type of Preservative pli upon receipt Date preservation adjusted Time preservation Amount of Preservative 1al p adjusted added Note Whenever therers a disclepancyalfecung Pforth Carolina compliance samples, a copy of this form will besenito lhC Plorth Ca Winn DE Pig Cerlrficaton Office (r C. out of hold, incauec(pre servative, out of temp. incorrect contameri. Qualtrax IQ 69614 Page 2 of 2 Page 129 of 130 exe• tecat;dn Reoursled EOWSTOO: CLIENT: KR-RuthLandf Ne CHAIN -OF -CUSTODY Analytical Request Document Pace A"Ylral pern!'tv;IL, 1377 Sane ►ar: Dr - Kernersv Ile, NC 27M Chain of-Cusledy is a LEGALOOCUMENT - [IJmpkte all relewnc heals c,pany Na,u Rutherford County Landlilk [Pmac1lRepen ie: 1ame3 Kilgo ,."I Add•ecr PO ad■ 1957. Rutherferdlon, NC 28139 P`ene a' g2S-287.6D01 E.Mail james.kilgoLlbrvtfiertordcoun:y.ic-gov WO# : 926996 58 Cc i-Mai ustome, PrPJrda mr—::': AWovnls Payable SPrc'ly Cenurkr Sue'• "Cpnwmw&re Ill It. l7: 5D]m..13 25Uvl ial t75r"t I31SWrr.L, 11'It 11111 Fr'Cere."1 Co- Central Landfu $n is EMa: jame5.kilgo@ruthedordeeuntync,gou infect N.— Rutherfosd rdentey[e"ta'x• Pll—at've type••• -•'arrwr•+,rvr -YPn 11) NOM 12: 4N9313 ;re Colt. Woj$ad 9y to I of aPOUIVel pu'cnase Drde-a[ -rsoe,(.;x IS•nap��.le1:r aer+uc. a' app'aaoley. wirlSod tZIS , rrw,�u+re. I%..mb., w. N:) Ana'105 Requested wcC , [111 Cher Qum*P Op1a6952 Prol.Kg•: _ 'me 2esc Ca eaed' I 1 AR I : PT ; Mt 1 I [T I ' ET CPwuy! Slate orlg;n Pt v.npklsl• North Carolina Stephanie Knott e Y AeJ:[Nvn,7 Chem III; )ale p4nC'ablea' Regu'alerY hogramjpW, RCIiA, etl as ae)I,caOle: y -2 Y F Rush Ipm-approval relluiredjt DW pwslo a e, Wlv Permit a as aPplirave. 5 Tsb a a: I I�evrq I-ery IN I ILeve ly 0 N n _ m UO e I lour; i I2ar t Jdaa I j3 day I IolY- ? ¢ b Field F'arc'ed 1i1 aPPI'rablel: I yet I IN. 'S ►raSdel Temp'me, 17056 pate Results — G m I IOther Revvestrtl: C [C� 3 m J .9 Pre10g J Battle Old. .'.. Tn3uf(t51.BroasvrIBI.L'aee•IVI. FlilriaCpol3:M13e•1'nMa[rirbpsbelo.vl Oinking Water;Dlyl.GrourdWale•I4V'ri,l'JaaleWa1CjWWLProd„fl{Pl,5pa75Witlt331.O'I{OU.w'pfIWPI. Water ;Swl,Sedmrm lstD. Sludge [ril. Cads F- n o 0 j C J_ EZ3022750 t Sample Gomment ]ine,1£r,5ur+acr 0 Mee NvmMr L trw N Comp J camp —le End Res. [eatai„ew C.3 o a — r�o m � a- Cestomer Sample lP Matna• Grab ertbmpesiee pau Start Tim. pate Time Q3 phastk Glass m i� m m a X X X x X 8103 SW 5 wr x x x x x 8103-SW-6 WT I x x x B103-MW 4 WT 8103-MW-6 WT iti �l �� i"?��'.j 47 x X x 8103•MW-7 WT 11,3Lti�� ►7+� jl 5 x X X 8103-MW 8 WT x X X 8103•MW-9 WT x X X 8103-MW-2OB WT x X X 8103-MW-I0C WT x X X 8103-MW-lOD WT Colkded By: P.inud tame: 4` t X, A"�, Additional Instrunlons from Pace' Cd3tpmcr Remarks / Scecial Condaions/ Possipse Ifaartls: Permd No. 8103-MSWLF-1974 J 6103-GOLF-2002 1V Signuu•e: aeeelet: Jrrw Ip: C.w ; `Ipr l'q' BILE Project No. Ji3.13657.OB �n Pro111e 17056 Lisle S(Ml 8. Line 9(No M) �r fJY:s' (IIYtIj� °'r n�we rl '� 4eceivcd bylCan,PtnY' SLsn+, Dale a ?-�• Teatkn�g Nua'ber V r7 -a C y v` eesnewttw lrr/CPmaanr I54n.Wre1 ,� it 0.�.� -, 4 lr< 1'1� i 1 -7i7 i���'.1 } L G r . oau• .me. Ilesei.a brlcaa.p-nr;s.anawcl om/ une Llelivered bF I la- Person I I [e„ner tetne'a+bed brKPmw"y ;3'ar'awrrl eelnarn,hed brrte* pa�v 13•gnarvr.l oareliwe: aecw+ee brie —suns'. {ser'+Wrel Oa,cR'mn I ' FedEX I I UPS I Otne' pa,rlT,rne Rece'+edbyJCPrnwm isttisvr.l Merl— Page: 2 of 3 acr,.a.nrea acrtamPaw lscn•fm•I Wit this chain dt eustddyconstitules ACMm;edgment and aapplance of the Pace' Terms and Cendicidns found at httPsr!/+vw'w Pxdabs com/reswrce•sbeery/resarrdelPal:rtermsantl•wnduionsJ ENV-FRM-CORO.0019 u01_0821230 Su'xniuing a sample CD W O O W O