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HomeMy WebLinkAbout8102_Rutherford_South_MSWLF_Nov2023GW_FID1830486_20240220DEN R USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR I IEnvironmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Bunnell-Lammons Engineering, Inc. (consultant) Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Andrew W. Alexander. P.G. RSM Phone: (864) 288-1265 E-mail: andy.alexander(a_)blecorp.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Rutherford County 102-MSWLF- .0500 November 29-30, 2023 South Landfill 4 Avondale Landfill Rd 1977 Mooresboro, NC 28114 Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑X Detection Monitoring ❑ Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Groundwater monitoring data from private water supply wells ❑ Leachate monitoring data El water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Andrew W. Alexander, P.G. RSM Consultant Hydrogeologist (864) 288-1265 Facility Representative Name (Print) Title (Area Code) Telephone Number �� w a• �E,o•,....=...1`.a•d„®`,•o,o 2/20/2024 Signature Date 6004 Ponders Court, Greenville, SC, 29615 Facility Representative Address C-284 & C-1538 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 Affix NC Licensed/ Professional Geologist Seal SEMI-ANNUAL WATER QUALITY MONITORING REPORT SECOND EVENT OF 2023 RUTHERFORD COUNTY SOUTH LANDFILL RUTHERFORD COUNTY, NORTH CAROLINA Permit No. 8102-MSWLF-1977 Prepared For: Rutherford County Solid Waste Dept. Rutherfordton, North Carolina BLE Project Number J23-20955-01 February 20, 2024 BLE North Carolina Business Licenses C-284 & C-1538 is IM IM BUNNELL LAMMONS ENGINEERING 6004 Ponders Court I Greenville, 5C 29615 864,288.1265 �I 864.288,4330 0 info@blecorp.com BLECORP.COM IJIMIM I RUNNELS LAIN IN ELL ONS ENGINEERING February 20, 2024 Rutherford County Solid Waste Department P.O. Box 1957 Rutherfordton, North Carolina 28139 Attention: Mr. James Kilgo Subject: Semi -Annual Water Quality Monitoring Report Second Event of 2023 Rutherford County South Landfill Rutherford County, North Carolina Facility Permit Number 8102-MSWLF-1977 BLE Project Number J23-20955-01 Dear Mr. Kilgo: Pursuant to authorization of Bunnell-Lammons Engineering, Inc. (BLE) contract number J23-20955-01, dated September 20, 2023, BLE has prepared this water quality report for the 2" d semi-annual sampling event of 2023 at the Rutherford County South Landfill. Consistent with the North Carolina Division of Waste Management (DWM) — Solid Waste Section (SWS) approved monitoring program, sampling and analyses has be conducted twice in 2023. This report contains the information required by the SWS to document the sampling and analysis activities for the second event of 2023 in the State's permanent project record. Sincerely, BUNNELL LAMMONS ENGINEERING INC. R1 Blais, P.G. Andrew W. Alex 4a6del r�,P. G., R S M Project Hydrogeologist Consultant Hydrogeologist Registered, NC #2896 Registered, NC #1475 cc: 1 Ms. Jackie Drummond —NC SWS 6004 Ponders Court, Greenvllle, SC 29615 t064.280.1265 A.864.2138.4430 -Minfo@hlecmrp,Eom BLECORP.COM 1s 1m 1i Water Quality Report - 2nd Semi -Annual Event 2023 February 20, 2024 Rutherford County South Landfill — Rutherford Co., North Carolina BLE Project No. J23-20955-01 TABLE OF CONTENTS 1.0 PROJECT INFORMATION........................................................................................................1 2.0 FIELD ACTIVITIES, SAMPLING, AND ANALYSIS.............................................................1 3.0 GROUNDWATER FLOW...........................................................................................................1 4.0 RESULTS.......................................................................................................................................1 4.1 Groundwater.................................................................................................................................... 1 4.2 Surface Water.................................................................................................................................. 2 5.0 SUMMARY AND RECOMMENDATIONS............................................................................... 2 6.0 QUALIFICATIONS OF REPORT.............................................................................................. 2 7.0 CLOSING.......................................................................................................................................2 Tables Table 1 SWS Approved Monitoring Matrix Table 2 Groundwater Monitoring Well Data Table 3 Groundwater VOCs Table 4 Groundwater Field Parameters and Total Metals Table 5 Surface Water VOCs Table 6 Surface Water Field Parameters and Total Metals Figures Figure 1 Site Location Map Figure 2 Groundwater Elevation Contour Map — November 29, 2023 Appendices Appendix A Field Sampling Logs — Pace Analytical Services, LLC. Appendix B Laboratory Analytical Data — Pace Analytical Services, LLC. iofi 1s 1m 1i Water Quality Report - 2nd Semi -Annual Event 2023 February 20, 2024 Rutherford County South Landfill — Rutherford Co., North Carolina BLE Project No. J23-20955-01 1.0 PROJECT INFORMATION The subject landfill site is located in Rutherford County, North Carolina, southeast of the town of Forest City with a physical address of 4 Avondale Landfill Road (Figure 1). Rutherford County owns the unlined inactive/closed MSWLF (Permit No. 8102-MS)VLF-1977). The existing groundwater monitoring network for the Rutherford County South Landfill consists of ten (10) wells (MW-1, MW-2A, NM-3, MW-4A, MW-5, MW-6, MW-7, MW-8, MW-9S, and MW-9D) [Figure 21. In accordance with rule 15A NCAC 13B .0602, two (2) surface water monitoring locations have been established for the facility to monitor surface water quality near the closed waste footprint. The existing surface water locations are designated SW-1 and SW-2 (Figure 2). 2.0 FIELD ACTIVITIES, SAMPLING, AND ANALYSIS Groundwater and surface water samples were collected for the second semi-annual sampling event by personnel from Pace Analytical Services, LLC. (Pace) between November 29-30, 2023. Groundwater samples were collected from the groundwater monitoring well locations located on the site as specified on Table 1. Groundwater monitoring well MW-3 was dry at the time of sampling, therefore no sample was collected. Both surface water locations were sampled during the event. The groundwater and surface water samples were delivered to and analyzed in Pace's Asheville, North Carolina and Charlotte, North Carolina laboratories for the constituents in the approved matrix (Table 1). The field parameters of pH, specific conductance, turbidity, and temperature were measured in the field by Pace. A copy of the Pace field sampling logs is included in Appendix A. A copy of the laboratory analytical data is included in Appendix B. A duplicate sample was collected from one well (MW-91)) in accordance with the quality control program (Table 1). The duplicate sample was laboratory blind. The laboratory results for the duplicate sample are included in Appendix B. kxi= :11100P]1'/:V1IMRy111111A The water level data collected during the groundwater sampling event on November 29, 2023 are presented in Table 2. A groundwater elevation contour map is presented as Figure 2 which includes generalized groundwater flow directions. 4.0 RESULTS 4.1 Groundwater The results of the groundwater field and laboratory analyses are summarized in Table 3 and Table 4 and the laboratory analytical data are included in Appendix B. Please refer to Table 3 and Table 4 for a summary of which groundwater constituents exceeded North Carolina Groundwater Quality Standards (NC2L) maximum contaminant levels' (MCLs). ' North Carolina Department of Environmental Quality, Classifications of Water Quality Standards, Section 15A NCAC 2L.0202, April 1, 2022. 1 of 2 1s 1m 1i Water Quality Report - 2nd Semi -Annual Event 2023 February 20, 2024 Rutherford County South Landfill — Rutherford Co., North Carolina BLE Project No. J23-20955-01 Field parameters measured in the groundwater included pH, specific conductance, turbidity, and temperature. The field parameter of pH was below its NC2L standard in all nine (9) of the sampled wells. Previous semi- annual reports for the subject site indicate that pH is frequently detected below the NC2L standards in the majority of the wells on site. No other field parameters were outside the NC2L standard limits for groundwater, if established. 4.2 Surface Water The results of the surface water field and laboratory analyses are summarized in Table 5 and Table 6 and the laboratory analytical data are included in Appendix B. Please refer to Table 5 and Table 6 for a summary of which surface water constituents exceeded their established North Carolina Surface Water Quality Standards (NC2B)2 standard limits. Field parameters measured in the surface water included pH, specific conductance, turbidity, and temperature. None of the sampled field parameters were outside their NC2B standard limits for surface water, if established. 5.0 SUMMARY AND RECOMMENDATIONS Semi-annual assessment monitoring was performed during the second semi-annual event of 2023 in general accordance with the approved WQMP and SWS approved monitoring matrix (Table 1). Detected constituents which exceed their respective groundwater and surface water standards are identified on the summary tables. We recommend that semi-annual sampling continue in accordance with the SWS approved monitoring matrix. 6.0 QUALIFICATIONS OF REPORT The activities and evaluative approaches used in this assessment are consistent with those normally employed in hydrogeological and environmental assessments of this type. Our evaluation of site conditions has been based on our understanding of the site and project information and the data provided to BLE. This report has been prepared on behalf of and exclusively for the use of Rutherford County, North Carolina. This report and the findings contained herein shall not, in whole or in part, be used or relied upon by any other party (excluding the SWS) without BLE's prior written consent. 7.0 CLOSING We appreciate the opportunity to be of service to Rutherford County, North Carolina. Please contact us at (864) 288-1265 if you have any questions or comments. 2 North Carolina Department of Environmental Quality, Surface Waters and Wetlands Standards, Section 15A NCAC 02B workbook dated July 26, 2021. 2 of 2 TABLES Table 1 SWS Approved Monitoring Matrix Rutherford County South Landfill Rutherford Co., North Carolina Permit No. 8102-MSWLF-1977 BLE Project Number J23-20955-01 Fall 2023 Only Station ID *Analytical Suite* 1,4-Dioxane MW-1 A-1 Yes MW-2A A-1 Yes MW-3 A-1 Yes MW-4A A-1 Yes U MW-5 A-1 Yes a o MW-6 A-1 Yes U MW-7 A-1 Yes MW-8 A-1 Yes MW-9S A-1 Yes MW-9D A-1 Yes w SW-1 A-1 Yes SW-2 A-1 Yes = Duplicate A-1 VOC Only - U (l Sample) Notes A-1 = Appendix I VOCs & RCRA Metals RCSLF SWS Approved Matrix 20955-01 Prepared by: RLB T 1 Approved Matrix Checked by: TCG Table 2 Groundwater Monitoring Well Data Rutherford County South Landfill Rutherford Co., North Carolina Permit No. 8102-MSWLF-1977 BLE Project Number J23-20995-01 Monitoring Point Latitude (north) Longitude (west) Northing Easting TOCI Ground Surface Elevation Depth to GW (ft) November 29, 2023 Groundwater Elevation (ft) Well Depth (below TOC) Geology Monitored Well Status/Purpose MW-1 DNA DNA DNA DNA 811.88 DNA 31.36 780.52 37.58 DNA Compliance MW-2A DNA DNA DNA DNA 790.40 DNA 36.54 753.86 45.21 DNA Compliance MW-3 DNA DNA DNA DNA 783.42 DNA Dry Dry 19.00 DNA Compliance MW-4A DNA DNA DNA DNA 845.17 DNA 26.05 819.12 30.35 DNA Background MW-5 DNA DNA DNA DNA 765.32 DNA 11.76 753.56 20.13 DNA Compliance MW-6 DNA DNA DNA DNA 801.87 DNA 30.72 771.15 37.00 DNA Compliance MW-7 DNA DNA DNA DNA 770.68 DNA 19.31 751.37 30.30 DNA Compliance MW-8 DNA DNA DNA DNA 813.03 DNA 33.51 779.52 42.30 DNA Compliance MW-9S DNA DNA DNA DNA 763.93 DNA 7.08 756.85 24.85 DNA Compliance MW-9D DNA DNA DNA DNA 764.28 DNA 6.74 757.54 67.70 DNA Compliance Notes• 1 - Data from report titled Results of Water Quality Sampling - June 2023 (FID 1817170) prepared by Scarlett Geophysical Consulting, PC. dated 8/25/23 TOC - Top Of Casing GS - Ground Surface All depth measurments in feet DNA - Data Not Available 20955-01 GW Tables (Completion, water levels, detections) Prepared by: RLB T2 MW Points Checked by: TAO/AWA Table 3 Groundwater VOCs Rutherford County South Landfill Rutherford Co., North Carolina Permit No. 8102-MSWLF-1977 BLE Project Number J23-20995-01 Sampled by Pace Analytical Services, LLC November 29-30, 2023 Compliance Wells TEST UNITS RL MDL MCL MW-1 MW-2A MW-3 MW-4A MW-5 MW-6 MW-7 MW-8 MW-9S MW-91) Acetone µg/1 25.0 5.1 6,000 <5.1 <5.1 Dry <5.1 <5.1 <5.1 <5.1 <5.1 <5.1 <5.1 Acrylonitrile µg/1 10.0 1.8 NE <1.8 <1.8 Dry <1.8 <1.8 <1.8 <1.8 <1.8 <1.8 <1.8 Benzene µg/1 1.0 0.34 1.0 2.2 0.53 J Dry <0.34 0.65 J 1.6 0.57 J <0.34 <0.34 <0.34 Bromochloromethane µg/1 1.0 0.47 NE <0.47 <0.47 Dry <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 Bromodichloromethane µg/1 1.0 0.31 0.6 <0.31 <0.31 Dry <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 Bromoform µg/l 1.0 0.34 4.0 <0.34 <0.34 Dry <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 Carbon Disulfide µg/1 2.0 0.36 700 <0.36 <0.36 Dry <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 Bromomethane (Methylbromide) µg/l 2.0 1.7 10 <1.7 <1.7 Dry <1.7 <1.7 <1.7 <1.7 <1.7 <1.7 <1.7 Carbon tetrachloride µg/1 1.0 0.33 0.3 <0.33 <0.33 Dry <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 Chlorobenzene (mono) µg/1 1.0 0.28 50 3.1 5.8 Dry <0.28 1.8 3.4 1.6 <0.28 <0.28 <0.28 Chloroethane µg/1 1.0 0.65 3,000 12.1 0.73 J Dry <0.65 1.6 0.90 J <0.65 <0.65 <0.65 <0.65 Chloroform µg/I 1.0 0.43 70 <0.43 <0.43 Dry <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 Chloromethane (Methylchloride) µg/1 1.0 0.54 3.0 <0.54 <0.54 Dry <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 Dibromochloromethane µg/I 1.0 0.36 0.4 <0.36 <0.36 Dry <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 1,2-Dibromo-3-chloropropane; DBCP µg/1 2.0 0.34 0.04 <0.34 <0.34 Dry <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 1,2-Dibromoethane; Ethylene dibromide µg/l 1.0 0.27 0.02 <0.27 <0.27 Dry <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 Dibromomethane µg/1 1.0 0.39 70 (i) <0.39 <0.39 Dry <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 <0.39 1,2-Dichlorobenzene µg/l 1.0 0.34 20 <0.34 <0.34 Dry <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 1,4-Dichlorobenzene µg/1 1.0 0.33 6.0 <0.33 1.7 Dry <0.33 1.8 1.8 0.77 J <0.33 <0.33 <0.33 trans-1,4-Dichloro-2-butene µg/l 1.0 0.56 NE <0.56 <0.56 Dry <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 1,1-Dichloroethane µg/1 1.0 0.37 6.0 44.9 <0.37 Dry <0.37 2.4 0.37 J <0.37 1.5 <0.37 <0.37 1,2-Dichloroethane µg/l 1.0 0.32 0.4 0.38 J <0.32 Dry <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 1,1-Dichloroethene (-ethylene) µg/1 1.0 0.35 350 0.75 J <0.35 Dry <0.35 <0.35 <0.35 <0.35 <0.35 <0.35 <0.35 cis-1,2-Dichloroethene (-ethylene) µg/I 1.0 0.38 70 6.0 0.46 J Dry <0.38 5.5 1.0 0.79 J <0.38 <0.38 <0.38 trans-1,2-Dichloroethene (-ylene) µg/1 1.0 0.40 100 <0.40 <0.40 Dry <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 1,2-Dichloropropane µg/I 1.0 0.36 0.6 <0.36 <0.36 Dry <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 cis-1,3-Dichloropropene (-propylene) µg/1 1.0 0.36 0.4 <0.36 <0.36 Dry <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 trans-1,3-Dichloropropene (-propylene) µg/1 1.0 0.36 0.4 <0.36 <0.36 Dry <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 Ethylbenzene µg/1 1.0 0.30 600 <0.30 <0.30 Dry <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 2-Hexanone µg/I 5.0 0.48 40 <0.48 <0.48 Dry <0.48 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48 Iodomethane µg/1 20.0 9.7 NE <9.7 <9.7 Dry <9.7 <9.7 <9.7 <9.7 <9.7 <9.7 <9.7 Dichloromethane (Methylene chloride) µg/1 5.0 2.0 5.0 12.7 <2.0 Dry <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 2-Butanone (Methyl ethyl ketone) µg/I 5.0 4.0 4,000 <4.0 <4.0 Dry <4.0 <4.0 <4.0 <4.0 <4.0 <4.0 <4.0 4-Methyl-2-Pentanone µg/1 5.0 2.7 NE <2.7 <2.7 Dry <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 Styrene µg/I 1.0 0.29 70 <0.29 <0.29 Dry <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 1, 1, 1,2-Tetrachloroethane µg/1 1.0 0.31 1.0 <0.31 <0.31 Dry <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 <0.31 1,1,2,2-Tetrachloroethane µg/l 1.0 0.22 0.2 <0.22 <0.22 Dry <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 Tetrachloroethene (-ethylene) µg/1 1.0 0.29 0.7 <0.29 <0.29 Dry <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.29 Toluene µg/l 1.0 0.24 600 <0.24 <0.24 Dry <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 1, 1, 1 -Trichloroethane µg/1 1.0 0.33 200 <0.33 <0.33 Dry <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 1,1,2-Trichloroethane µg/l 1.0 0.32 0.6 <0.32 <0.32 Dry <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 Trichloroethene (-ethylene) µg/1 1.0 0.38 3.0 <0.38 <0.38 Dry <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 Trichlorofluoromethane µg/l 1.0 0.30 2,000 <0.30 <0.30 Dry <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 1,2,3-Trichloropropane µg/1 1.0 0.26 0.005 <0.26 <0.26 Dry <0.26 <0.26 <0.26 <0.26 <0.26 <0.26 <0.26 Vinyl acetate µg/I 2.0 1.3 88 (i) <1.3 <1.3 Dry <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 Vinyl chloride µg/1 1.0 0.39 0.03 <0.39 <0.39 Dry <0.39 0.79 J <0.39 <0.39 <0.39 <0.39 <0.39 Total Xylenes µg/I 1.0 0.34 500 3.7 <0.34 Dry <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 1,4-Dioxane 2.0 0.86 3.0 <0.86 13.6 Dry <0.86 20.1 38.6 17.4 <0.86 <0.86 <0.86 Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable to Groundwaters of North Carolina, Section 15A NCAC 2L .0202. Amended Eff. April 1, 2022 2. (i) = Interim Maximum Allowable Concentrations (IMACs). Updated April 1, 2022 3. Shaded cells indicate exceedances of DAACs 4. Shaded cells indicated exceedances of MCLs 5. NE = Not Established; North Carolina has not established a MCL 6. RL = Reporting Limit 7. MDL = Method Detection Limit 8. NT = Not Tested 9. NS = Not Sampled 10. "J"-flagged data (i.e., values estimated between the MDL and the RL) are presented on this spreadsheet. 20955-01 GW Tables (Completion, water levels, detections) Prepared by: RLB T3 (10-26-23) VOC Checked by: TAO/AWA Table 4 Groundwater Field Parameters and Total Metals Rutherford County South Landfill Rutherford Co., North Carolina Permit No. 8102-MSWLF-1977 BLE Project Number J23-20995-01 Sampled by Pace Analytical Services, LLC November 29-30, 2023 Compliance Wells TEST UNITS RL MDL MCL MW-1 MW-2A MW-3 MW-4A MW-5 MW-6 MW-7 MW-8 MW-9S MW-9D PH S.U. <6.5; >8.5 5.1 5.9 Dry 4.8 6.0 6.0 5.3 5.0 5.2 5.4 Specific Conductance µmhos/cm NE 58.0 323.8 Dry 39.9 412.8 1195 272.6 37.8 34.0 38.0 Temperature °C NE 12.6 17.1 Dry 12.4 14.0 16.3 18.5 16.5 13.8 12.5 Turbidity NTU NE 1.9 5.6 Dry 9.7 8.7 6.4 8.6 9.7 4.7 1.0 Total Arsenic (As) µg/1 10 2.5 10 <2.5 16.2 Dry <2.5 8.3 J <2.5 <2.5 <2.5 <2.5 <2.5 Total Barium (Ba) µg/1 5.0 0.79 700 92.3 134 Dry 33.0 174 154 54.2 103 36.3 30.6 Total Cadmium (Cd) µg/1 1.0 0.29 2.0 <0.29 <0.29 Dry <0.29 <0.29 0.31 J <0.29 <0.29 <0.29 <0.29 Total Chromium (Cr) µg/1 5.0 0.63 10 <0.63 1.9 J Dry 0.78 J 5.1 2.6 J <0.63 <0.63 <0.63 <0.63 Total Lead (Pb) µg/l 5.0 1.4 15 <1.4 <1.4 Dry <1.4 <1.4 <1.4 <1.4 <1.4 <1.4 <1.4 Total Mercury (Hg) µg/1 0.20 0.12 1.0 <0.12 <0.12 Dry 0.12 J <0.12 <0.12 <0.12 1.6 <0.12 <0.12 Total Selenium (Se) µg/l 10 4.1 20 <4.1 <4.1 Dry <4.1 <4.1 <4.1 <4.1 <4.1 <4.1 <4.1 Total Silver A 5.0 0.49 20 1 <0.49 <0.49 Dry <0.49 <0.49 <0.49 1 <0.49 1 <0.49 <0.49 <0.49 Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable to Groundwaters of North Carolina, Section 15A NCAC_2L .0202. Amended Eff. April 1, 2022 2. Shaded cells indicated exceedances of MCLs 3. NE = Not Established; North Carolina has not established a MCL 4. RL = Reporting Limit 5. MDL = Method Detection Limit 6. NT = Not Tested 7. NS = Not Sampled 8. "J"-flagged data (i.e., values estimated between the MDL and the RL) are presented on this spreadsheet. 20955-01 GW Tables (Completion, water levels, detections) T4 (10-26-23) Metals Prepared by: RLB Checked by: TAO/AWA Table 5 Surface Water VOCs Rutherford County South Landfill Rutherord Co., North Carolina Permit No. 8102-MSWLF-1977 BLE Project Number J23-20955-01 Sampled by Pace Analytical Services, LLC November 29-30, 2023 TEST Acetone UNITS RL MDL NC211 SW-1 SW-2 µg/1 25.0 5.1 2,000 <5.1 <5.1 Acrylonitrile µg/1 10.0 1.8 0.061 <1.8 <1.8 Benzene µg/1 1.0 0.34 1.19 <0.34 <0.34 Bromochloromethane µg/1 1.0 0.47 NE <0.47 <0.47 Bromodichloromethane µg/1 1.0 0.31 NE <0.31 <0.31 Bromoform µg/1 1.0 0.34 7 <0.34 <0.34 Carbon Disulfide µg/1 2.0 0.36 100 <0.36 <0.36 Bromomethane (Methylbromide) µg/1 2.0 1.7 0.04 <1.7 <1.7 Carbon tetrachloride µg/1 1.0 0.33 0.254 <0.33 <0.33 Chlorobenzene (mono) µg/1 1.0 0.28 488 <0.28 <0.28 Chloroethane µg/1 1.0 0.65 NE <0.65 <0.65 Chloroform µg/1 1.0 0.43 60 <0.43 <0.43 Chloromethane (Methylchloride) µg/1 1.0 0.54 20 <0.54 <0.54 Dibromochloromethane µg/1 1.0 0.36 0.8 <0.36 <0.36 1,2-Dibromo-3-chloropropane; DBCP µg/1 2.0 0.34 0.13 <0.34 <0.34 1,2-Dibromoethane; Ethylene dibromide µg/1 1.0 0.27 0.1 <0.27 <0.27 Dibromomethane µg/1 1.0 0.39 NE <0.39 <0.39 1,2-Dichlorobenzene µg/1 1.0 0.34 448 <0.34 <0.34 1,4-Dichlorobenzene µg/1 1.0 0.33 448 <0.33 <0.33 trans-1,4-Dichloro-2butene 1g/1 1.0 0.56 NE <0.56 <0.56 1, 1 -Dichloroethane µg/1 1.0 0.37 100 <0.37 <0.37 1,2-Dichloroethane µg/1 1.0 0.32 650 <0.32 <0.32 1, 1 -Dichloroethene (-ethylene) µg/1 1.0 0.35 20,000 <0.35 <0.35 cis-1,2-Dichloroethene (-ethylene) µg/1 1.0 0.38 720 <0.38 <0.38 trans-1,2-Dichloroethene (-ylene) µg/1 1.0 0.40 4,000 <0.40 <0.40 1,2-Dichloropropane µg/1 1.0 0.36 31 <0.36 <0.36 cis-1,3-Dichloropropene (-propylene) µg/1 1.0 0.36 NE <0.36 <0.36 trans-1,3-Dichloropropene (-propylene) µg/1 1.0 0.36 NE <0.36 <0.36 Ethylbenzene µg/1 1.0 0.30 97 <0.30 <0.30 2-Hexanone µg/1 5.0 0.48 NE <0.48 <0.48 Iodomethane µg/1 20.0 9.7 NE <9.7 <9.7 Dichloromethane (Methylene chloride) 1g/1 5.0 2.0 1,000 <2.0 <2.0 2-Butanone (Methyl ethyl ketone) µg/1 5.0 4.0 26,000 <4.0 <4.0 4-Methyl-2-Pentanone µg/1 5.0 2.7 26,000 <2.7 <2.7 Styrene µg/1 1.0 0.29 NE <0.29 <0.29 1, 1, 1,2-Tetrachloroethane µg/1 1.0 0.31 NE <0.31 <0.31 1,1,2,2-Tetrachloroethane µg/1 1.0 0.22 0.2 <0.22 <0.22 Tetrachloroethene (-ethylene) µg/1 1.0 0.29 0.7 <0.29 <0.29 Toluene µg/1 1.0 0.24 11 <0.24 <0.24 1, 1, 1 -Trichloroethane µg/1 1.0 0.33 200,000 <0.33 <0.33 1,1,2-Trichloroethane µg/1 1.0 0.32 8.9 <0.32 <0.32 Trichloroethene (-ethylene) µg/1 1.0 0.38 3 <0.38 <0.38 Trichlorofluoromethane µg/1 1.0 0.30 67,000 <0.30 <0.30 1,2,3-Trichloropropane µg/1 1.0 0.26 0.001 <0.26 <0.26 Vinyl acetate µg/1 2.0 1.3 NE <1.3 <1.3 Vinyl chloride µg/1 1.0 0.39 0.025 <0.39 <0.39 Total Xylenes µg/1 1.0 0.34 670 <0.34 <0.34 1,4-Dioxane µg/1 2.0 0.86 80 <0.86 4.1 Notes: 1. NC213 = North Carolina Surface Water Standards for Class WS-IV freshwater under Title 15A Subchapter 2B. per NC DWR Surface Water Quality Standards, Criteria, & In -Stream Target Values (Workbook Dated 7-26-2021) 2. NE = Not Established; North Carolina has not established a MCL 3. Shaded cells indicated exceedances of MCLs 4. RL = Reporting Limit 5. MDL = Method Detection Limit 6. NT = Not Tested 7. NS = Not Sampled 8. "J"-flagged data (i.e., values estimated between the MDL and the RL) are presented on this spreadsheet. 20955-01 SW Tables Prepared by: RLB T5 SW VOC (11-29-23) Checked by: TAO Table 6 Surface Water Field Parameters and Total Metals Rutherford County South Landfill Rutherord Co., North Carolina Permit No. 8102-MSWLF-1977 BLE Project Number J23-20955-01 Sampled by Pace Analytical Services, LLC November 29-30, 2023 TEST UNITS RL MDL NC2B SW-1 SW-2 pH s.u. (on -site) - - <6.0; >9.0 6.6 6.4 Specific Conductance µmhos/cm (on -site) - - NE 43.0 59.5 Temperature °C (on -site) - - 29.0 8.7 6.5 Turbidity NTU (on -site) - - 50.0 7.0 3.1 Hardness mg/1 10 NT 100 NT NT Total Arsenic (As) µg/1 10.0 2.5 10 <2.5 <2.5 Total Barium (Ba) µg/1 5.0 0.79 1,000 19.4 22.4 Total Cadmium (Cd) µg/1 1.0 0.29 0.82 <0.29 <0.29 Total Chromium (Cr) µg/1 5.0 0.63 183.07 <0.63 <0.63 Total Lead (Pb) µg/1 5.0 1.4 13.88 <1.4 <1.4 Total Mercury (Hg) µg/1 0.20 0.12 0.012 <0.12 <0.12 Total Selenium (Se) µg/1 10.0 4.1 5.0 <4.1 <4.1 Total Silver A µ 1 5.0 0.49 0.3 <0.49 <0.49 Notes: 1. NC2B = North Carolina Surface Water Standards for Class WS-IV freshwater under Title 15A Subchapter 2B. per NC DWR Surface Water Quality Standards, Criteria, & In -Stream Target Values (Workbook Dated 7-26-2021) A hardness of 25 mg/L was utilized to calculate an acute standard at each surface water location for metals highlighted in green. 2. NE = Not Established; North Carolina has not established a standard 3. Shaded cells indicated exceedances of MCLs 4. RL = Reporting Limit 5. MDL = Method Detection Limit 6. NT = Not Tested 7. NS = Not Sampled 8. "J"-flagged data (i.e., values estimated between the MDL and the RL) are presented on this spreadsheet. 20955-01 SW Tables Prepared by: RLB T6 SW Metals (11-29-23) Checked by: TAO FIGURES FARM DR C H HAMRICK RD- _ s �A _ 41. o Q �pQO O � 1 Q VIV IAN� — T,win Airpark 0 0v FF a I soD zm M/L [ S 0 BOSS 900 AV f KELLY RD 0 Cary Teen O h ,gyp DOGWOO 0 VAL[EYRD co O..�000PfR1/NERD p ck: W m \ W �� 2 u y o ` + Fyp�F \ moo \ Carol i Avondale 1 a �yF Q o l HenriettaCem MCDOWELL ST AVO -E.LANpF/[ I COO _ Avondale 2S P� 800 f 80.0� Oho CNORCH Providence = `r0 teed Meth'o'dist 4 r,❑c�h Graveyard 4�oQ P�"S A q a cm m _ IL dpO A AG -TOWN RRD Zion Hill:Cem y 800 S,P�2Jl o P /800 - J 1Henriettag �P� �D{tRAY ST \�OC W/SEM �' -- - AN RO _ - HARRIS HENRIETTA RD REFERENCES: USGS TOPOGRAPHIC MAP, 7.5 2000 1000 0 2000 4000 0 MINUTE SERIES, FOREST CITY. NC. 17— QUADRANGLE 2022 APPROXIMATE SCALE IN FEET [AKERD DRAWN: KLW 1-8-24 DATE: IM FIGURE B U N N E L L SITE LOCATION MAP M LAMM13NS RUTHERFORD COUNTY SOUTH LANDFILL CHECKED:RLB CAD: RUTHERFORDSOUTH—01SLM M ENGINEERING RUTHERFORD, NORTH CAROLINA 6004 Ponders Court, Greenville, SC 29615 APPROVEDAWA JOB 10: J23-20955-01 Phone: (864) 288-1265 Fax: (864) 288-4430 :''r A 1166 Ii-i'm A� , . wk- V- bw* r } a MW-an MW-9S 757.54 756.85 IF mw Ar ii 46 / y�wp�Il. L ` I � 1� {i :i 8 0.5 2 L or t M: 'y '!• ti z +7 L ;9113ECOND BROAD RIVER x_ i - �y ' SW-2 f ' - MW-2A ' 8�1 O 753.86 —� 0 _ $O fhill - ii ' iiiim - MW-6 771.15 '- r MW-7 n Z. . �•` r '_ %7O MW-3 r -yf t _AO DRY L 1_ li' -{ ' •,, I " Ire L _M1 i -r r r AVONDALE LANDFILL ROAD LI - f R SbIt" '�it ti st_ i 1 � 5 Ff � • f L. _ � :Y+ �' _ , r . •+ F11`_• .ILL{, �h mead REVISIONS No. DESCRIPTION BY DRAWN: KLW CHECKED: RLB/TAO APPROVED: AWA DATE: 2-14-24 CAD FILE: RUTHERFORDSOUTH-01PROD JOB NO: J23-20955-01 IM JBILININIELL LAMM � AMMONS ENGINEERING 6004 Ponders Court, Greenville, SC 29615 Phone; (864) 288-1265 Fox; (864) 288-4430 Joe b W. ■ !k MONITORING LOCATION LEGEND MW-8 APPROXIMATE GROUNDWATER MONITORING WELL LOCATION SW-1 APPROXIMATE SURFACE WATER SAMPLE LOCATION TOPOGRAPHIC & GEOLOGIC LEGEND � Y L 790 POTENTIOMETRIC SURFACE CONTOUR LINE (CI = 10') GROUNDWATER FLOW DIRECTION ` SURFACE WATER APPROXIMATE PARCEL BOUNDARY t r' IL IL NOTES: SAMPLE LOCATIONS ARE APPROXIMATE AND LIMITED BY THE REFERENCES THEMSELVES GENERAL MAP REFERENCE a 150 75 0 150 300 lk ,a• APPROXIMATE SCALE IN FEET J 1 REFERENCES: 1. PROPERTY LINES SHOWN OBTAINED FROM RUTHERFORD COUNTY GIS. 2. GROUNDWATER MONITORING WELL AND SURFACE WATER LOCATIONS FROM FIGURE 2 — SITE MAP WITH CONTOURS, JUNE 15-2023. PREPARED BY SCARLETT GEOPHYSICAL CONSULTING, PC. LOCATIONS ARE APPROXIMATE. GROUNDWATER ELEVATION CONTOUR MAP - NOVEMBER 29, 2023 RUTHERFORD COUNTY SOUTH LANDFILL RUTHERFORD COUNTY, NORTH CAROLINA FIGURE NO. 2 APPENDIX A FIELD SAMPLING LOGS PACE ANALYTICAL SERVICES, LLC. Document Nante:17M doln Sheet Date issued: Mairdi 8,2019 Pa r: 1 df I ceak�ryrrcar' Issuing Authority: Pace Hunterrville Quality Document Number, P-CAR M.-WI-rev.01 Office Field Data Sheet Client: BL-a _ Location: oCQtA- �yINC. ^Project#;i shsh _xC%Sov„-4L� Name and Affiliation (Sampler(a): f Field Date Sheet Review: Name and Affiliation (Inspector):_ t9 J Date: 13y: R�f� ffjel Informiltion (x 3 Well 1D: _ �� off^ - MW ' 1 _ Well Locked: Q:M / NO flushmount ) Well Diameter: �- n Construction: 'Steel/Stainless Steel) Total WvII Depth: 3?-S2 ft Multi Factor•:4 •(—(d_A ('(Radius/12)z x 3,14 x 7A81 Static Water Level- It - L 1 ft Cashig Volume: (• CC1 ----.gallons Height of Water Column— —, I ft Cal. S. Volumes: gallons Pump Intake.S _ ft EMSe lnformatian Date Purged: (� / 30 / 13 $tart:_if2C' .Finish: 1i3S Plsrgehate: t0 ;n Purging Method:-_NkonSo*n Total Volume Purged:,±tSOQ __(gallonst L) Sampling information Date Collected: it A / _43 Titnne Collected: E IH 0 twpm) Sampling Equipment Used., �kornSoo!N -Instrumentll7:-;(Sio2+<\ llottleType Preservation Analysis Required i>< ? Ion 1�L�s�' ; _ "1J b , -r tr,a 41GL w -w.r.- 1 eigid Measurements/Observations Sample Temp (°C): Time: 11 `l � Turbidity (ntu); .! • � � Time: VK0 Diss Oxy (mg/L): O :� Time: Pe 2+ ipg/L:.. �_ _Time;�___R_�__ �^ Spgcifte Cond. (u$): S4,54 Time: Res: Cl (mg/L)/(pg/L):.. . rune:_ Sailiple pH (sm.); S . l Time: Odor: Time:- ReDox (mV): Ma .O Tinne: Appearance:_ CkQD�.r Time: 1VA0 ReDox (SH value):YSI ProPlus +200mV •4 Other: _ Time: General/Weather Observations; to cloudy/rainy) Temp.S_1 (°F) Wind fl -S (mph) Sampler Signatuve Stabilization Pest - Time Purged Temp. (°C) Diss Choy. (mg/ L) Spec. Coon • pH (s u-) Repox (mV) 'Turbidity (ntu) Volume removed (gallons/ Water level (ft) Other 11'1S to .-j SZv 3l . 411 ."S S IS. t t'7,1 1 y .") 5,00 1l lk.5 0 "S S k. k \11.1 2, o0 t i3 12,5 .3 •2 .2 l(fa � o0 T)papatentNamo::Fialcldais SNee1 Date I"P. March 8. V19 Pn er 1 of dG9AlIS1yfIC.?1 fkicument t�fumNrr= F BAR-FI 1i-00l-iev.il3 Issuing Authority.: J'acefitLnterevtlte Quo lity Officg L& Name and Affiliation 1Varne.and Affiliation (Inspector): A 't 611li9gaLni�lon n Well ID: %101-1% -�. r9� Well Locked: - Well Diameter: �-. Construction: towT� L Imo, Li �-G ra ect il:,�w/Z�ie c�;y rd Data Sheet Review: 1zfi8 Qate: 1-4/ I /2-3 13y: �/lr ti'�� AT%j ( XW/ NG / Flushmount ) (Steel/Stainless Steel) Total Well Depth:Multi'FaCtor*: (Q "(FL 4tus/12)2x3.1dx7.d81 Static Water Level: 3 ' S ft Casing Volume: �� gMtons Height of Water Column i'67 ft Cal. 3 Volµmes: tj2 3 gallons Pump intake: � 3 ft e Info att Date Purged:) l 3 / �' start : )3 ` . Finish: 1 5 Purge Rate:_1 - Purging Method.: SS 5 At. ✓Lt 14 Tatal Volume Purged: (gallons/ i L) Sampling Informat Date Collected:_jL_• :jQ/ Time Collected: l 2.Od (am/ —OR, Sampling Equipment Used; S 55 t i6 % ✓ 7,e instrument [D: 00W S� Bottle . e Preservation Anal sis Required. - - �z0 '14-!h i?c 11�ir-o 6 Vf.� s r� �. kdML__ii-Gi'�SS_ ►ra■-a41�e1dr._ %_ L Sri-lrOiJ -i��r� �rl��. 1roC f �%,lt'/0'� li`L��___�_._: �, ��/`-✓�' ....� .XiLo1� /y7Sv 'S.fM 1•tf i71ir�„6 Field Measurementa/Observations SampleTemp Cq: Time: 12, 00. Turbidity (ntu): hiss Oxy (mg/l,): '. Time: Fe 2+ mg/l::-_ CJ �., Specific Cond. (uS): � �`b Time: Res. a (mg/L)/(ug/l.):. "J - Sample pid (s.u.): A Time: Odor:_ ReDox (mV); I'( �' -1 Time: Appearance: Rel)ox (EH value):YSI ProPlus•+2DOmV �''f �i ' Other: .General/Weather Observations; �f $ampler Signature: 0=1/-L,- r'4A Date:_- Stabilization Test Time: ) I Time. _Time: _ �Time:� Time: /rainy) Temp. l7 0 (*F) Windom 5 (mph) Time Temp. Dlss Oxy. Spec, . pH (s.u.) ReDox Turbidity Volume removed Water Other Purged (°C) (mg/L) (u (mV) (ntu) (gallons/� level (ft) L I40 46.0 04 9--1 K }- LI 10t7 {, O-S -� i ro toL 5, s- 4 1-3 TOO [ 4 ry -7 - 2 r Gr Da% Ifme4r.P&O" ZIn'; P-QAWFIDAn-mv.09 InkcLhg ALLOmdly: I ILLntErRvI IIA'Ooalily QUA LaTA 213M k, L F i±t, N L -e�! Nwia and A ffiffiation (Sampla(Ah; OA rAL field Data t FevIew" Name-ffnd Affillim*n Date: j 2.- 1.1 06 Fjy: M11 Inftimidi I ze, Q-3 a^e Well ID: F Q1 NO "I 7.. 7 i'At.) Well DIarneter, Crmslrucficn: (Pa5tpe},�tIRWOM gfeL-j) 'TOW Weir r�Pth., epfto#?X�,iJw-"] SLatk-watpr Levek -casItig VnIurne gallons .kIP1811t Pf water cdlumn a Vblqmvs;-.-..gallons .FLc;np 4i6aJ(e. Date Nlrgek— --_-fir tar ush,,— Pwge Rl" iw ""P -- - I rm (4m/ pin) some -Type Preammilmn AnatysIs Field a D;vs QNy-�mV-L),m - . W. - - -.-Fe Z+ mg/ L: spuumc cund'+ 001, Tfim Sample pff (s,u)- ..C?dDr: ReDOX (Fa f value) 1,W ProPlus +-200MV — Geapj^,-ath L r Observat I&T, VeU r (r _+Wcloudyj raLry) Temp, 4 WtndLY (m-ph) 9amplecSignatvre;-- t - 30,-23 %tabill-Antion TerA ago 0 if k Dbotnent Name: PIPJJ data §hcO date lusued;-March 8. 2D19 FA e: 1 of +Z CeAag4ftaf Ducumestl iVumtmx F CQR FI i�-0Ot-rev.03 issuing Authterity;-Pace fiuntersviflSQua fly Office Client:A_t-r - _Location: Name and Affiliation (Sampler(s): �J ' 'Oht-4A Name and Affiliation (Inspector): � I`T yVelHnformation a Welt 1Di %A 2' M 'Al' r r Well Locked: Well Diameter: Total Well Depth: 3 5 Ft Static Water Level; " �.... ft Height. of Water Colu#u1. 4 , 21 ft Construction: (f1 Data Sheet Review: Date: 12./1 m3 f1h /1,::L NO / Flushmouni eel/Stainless Steel) Multi Factor`: 0401 0 1 (`(iiad1us/12)2 x 314 x 9A8j F A'ih1S Casing Volumed s� gallons Cal. 3 Volumes:... i ..._ �. gallon.+ Pump lntal m. Z Y ft b0`v/1f r R By,RM B Pu e-infor a ion Date Purged: L / 3 /�?Start: 0 01,9 -- Finish. 10 �O Purge -Rate: ) 00 Purging Method: 74-AP —Total Volume Purged: - 5 (gallons/&L) 5amv� linglnfQrmation Y Dato Collected:—j_j2_O_/ ;L) Time Collected d 5 a pm) Saanpling.Equipment Used: I'M J- A.-t-P Instrument ID:.i Bottle Type Preservation Analysis Required 1 2, � ,`vPt-err d03. _.. /�cs,+ Aa 79 s Gars '7(f741 LDQ i ac,,4 Ii��1 1�DC Field Measuremente/Obne"niation Sample Temp(°C): _Tlme:_JJ3.5__`Turb1dity(ntu): q- -Time: Dias Oxy (mg/L): (9 ' •Time: Fe 2•+ mg/L: Time Specific Cond. (uS): Time: Res. Cl (mg/LY(,ug/L): rime Sample pH.(s:u.): '`� TJme: Odor: / / 'rime ReDox (mV): _ 11- `i Time: Appearatice:- i./z.-Tirane: ReDox (EH value):YSI ProPlus.+200niv L i Other: -� Time-4-General/Weather Observations, unn cloudy/rainy) Temp_q f_- ff) WindS_ LT(mph) Sampler Signature Stabilization Test -10 -;1- Time Tem Dias 0 Spec' Cond. PH (s.u.) ReDox Turbid&' ry o ume remgved Water Other Purged (° (mg/ S� (nti� (n) (gallons) is L level (ft) o •s I 10'q -f -. Tl-k 1 L O A .30 1(7. 0 -$ ). o 1i •7 .7 4_1.2. .---y Oq SID j 4 .1 -2 1000 c•3 ' ma l . p . .p '. 0 T �:5— �- D d 'z 0 o 1 �-- B .2. $ .7 r?CBArk7ij/11C�?j Dmpienl Name: Pied Crate Sheet Docuumat issued; March 8, 7,i M ftgelof -1- OwIment Number: Essuehis Authority: P-CAR PLO-tlDt.rm-03 Pace Huntersville QdalityOffice Client: L " Location: U��lY _ _ tiC Project: Rat 1 �p cow �✓j'Y Sow11f1u well ID: M IV Reviewed Date and By: 11LO/1.3 R MB Stablli:atlonTest j'l..r! I NQ ►ATQ I-Nfe l Diffl�letar I'lulti licatiion Factor* 1 04408 1.2 0,0918 1.620 0.1000. 2 0.1630 3 03670 4 0.6330 6 1A680 $ 2.6.1 Time•Spec. PurgeO ,A, t-,�K ,A, t-,�K 13ALl.k kwed, M=h 1� Z)11� Fjoc%ifiloeLt NO= pida Otal shept Pmst; I WE -A 1��28bhlwcgl, Lmuirijr AishcMty! Pepe � i�LnNrayfU* iaj.Ll iky TNKUntoot Nunlbot. FC"-FIO-M-Mv OMCF Cliant- 13 L T� Narne and AfflliaOon (SomplevOlk M E9 7—� Nami7 and Affiliatlon (1MpQcWr)--Lj—k.. - Well 1ptLqMAqq—n well 11), .eid Datit Sheet REVfMW j X, Date: 1 2/f/ z� / NO/ - vlohtaiint) Wa 151631aff. . —d- ConSM&ORML, -FotAl wea.r;tPth., 0� k4. it Multi Factor&-Lw Poftda,1�3)-A �L-m 'L ?41 stat(c Water Level:_ Casing Volume; kreishrof Water CoILLWM CIO.. 5-vulam"I gallons -Ftij<qlnlake: -7 11 ... —JR c, LF .Pate a I L). 1pus.hL D 5, 5 .,vu;r RELtv; V6ALL 01 Pu�" row. Volume Nrsed: , Unginfomixtion D11[:KQ.Llx-dad;-A1—/3-CY '�3 Tiale 'Sampling 13qt1ipFnentUcf!d,._�e (,PLO P IwMmON 1D.. POW 15 ButrlIe Type Preltervifflon Am aim Reqtdred r� �CJZA 15 Field DES* DAY Fe 2+ rplg/ L__ S*Iflc C:nrd. (aS), ALI--Ll Titne;.-LD-P C---R", Cl (�jg/ Ly(c&/ L);. hew = Sample pH �Lu.), Time: 10 D.D. ..Odcr� ..-nme I DZOVGX.(Mv): Ttme. -LC->PR- Appeamoce: C i str-11mv I �-Vpo [?uDox (HH-value),ySi NoPiws +20GrnV-.-j IQ - 3 GenerWWeatb oe ()bwrvaqw 3 Time tpmp, DID Oxy- Cond pH (S.U.) ReDox 1'rtubiait3C reAwved watpr Oer th Purged ec) (Fnw L) , (Inv) (r.to) (89110ray L) lft6 (ft) 0�35 [12.3 q-115 5. ci 31.1 )p -- 17-- F -421.s 5, 1 3j. 1 D 0 13. Er .2.0 1f,5 1 2-P /I- �5- KLLAI i. I 43, -LA- -- r I -7 3 (0) ()1513.1 0 , r-j 413,u 5d `j 1u- 1 61 1 dL � v () I i. 6-> �A�TJyli�ai t pOMFLI 5k Kama; V'40t$ data Sheet t7. w Ir,Gucd_ Mm3th 6, 2019 1a 'rkrunimtNLFnbgt;@- CAH-Stn4JQi-tev.Q ` IrsuingAu�lwttkyr.f'eref I DffM Mid r h jo C;Jt n _-.° acal3an, N C- I'r err k -&—t Natne-andPiedi)ata5hvetRewiew: ilarin� �n Aif>liakio (Jneerlpr}:.-.-. N 11- t.' s ) I}abc; OUInfoLnIdi n. t r�Jt Weil LU U - Mw-- _ Wei! Locke t NO f Mughmolint ) Cmrutruc Hunt OAtecl f stawes® st ij TOM Weil ij ptN 1- IL) ft Mul4,Faclxir: '� � �{i�Jj../V2x-3,14x`!A9] Static watur LeveL. casmg vblurm-_ 1, � " go HQfght of WIt@er DjL uw �ft i. 3 V sl al[bzx, Pumlrtt19F: - ft By: -re++Jlle Qu nlijy rk +one kme iitfermAtion Mitte l'urged..--LL1 1. 3 51att : D_ Snisk . L i urg& F. te:� t1 Lf-.. Purgirkg imetho& Volume Purge '; r -- fgeill°nsl� f L] .9 mpi lug nu niter coilecbCd:! i Tit)rw. CgLeete&, - .6 I/P ) S=pLing F-pipmentUso& l'"+�m 0.0 kaj x--.- natrur;tent ID; � . 0 LI + (� ctt#f i Frerervatk n Analy -Requ"d AK field MeaeurenigrLO Ubseryations 5a,livio'Tetrtp {°c _- _ .. k, 7 IDlt��. M i 5 Turhtdlty (rktti): Mai-- 115�7 r Re& Cl (m :LMS/I ;- 8a rnp�e pH {�.�� Tlm� °� t 1 is . _ od,aEti.._.. ..- ---- Tt�iN�►:. ' i t � � RODOx (ati :.. Taw, I I i Appenrulca~; .._ Tira�ax {8� i< value�:YS[ Y�vFlus �2010m� � .. [Jiher: , 7ixn�. �� . Gener�IVoaF1�Obe�rsHolktl• _ W�(mpb) ?a.hiliiutinri TFKt Time 1�lYge+d. --- Temp. �) cc). DiM Oxy. (mg/L) Slr�r. Cnnd. {•."'J H P (su ) Rel x {rstVj Tuitbdd Y {i;stu) . 4u . reinDv6d fgpiCo53s f J a� w level (ft) Other l l,a • D 12013 I - C) LI . LD -3 -- � 1 3 U-D 5Dp Sao' DAtelssueds March 8, 2019 Uocgntent Name: tfeld data Sheet Page: 100- caceArk7lyflC�71 tseuirig Aulhorily face Huntersviile (2uality fkcunieni Number: F•CAR+B D-001-wvAi Office Name and Affiliation (Sampler(e): w W. Meld Data Sheet Review: Name -and Affiliation (inspector): Well 1nf r to Well ID&kw Well Locked: / NO / F14811 xtount ). WeJI Diameter: du Construction: O f Steel/Stainless Steel) Total Well Depth:_�� fit Multi Factor": 40AL03 (}(Radius/12) x 3.14 x 7.g8J Static Water Level: ` %; I Casing Volume: T gallons ��ft Height of Water Coiww. �+' .,ft Cal.3 Volumes; .gdJJoiw Pump Intake.. ft .Sovm V W6 SA By: RA6 Purge Informafion `.,� Date.Purged:��/ � /� _ Stark -IM Finish:�� Purge Rdte:.11t� O A Purging; Method: ��i t71a►i•+ L Total Volume Purged: (gallons4g)L) S mUling Information Date Calicctec(: _/_3_Qj Tine (74lected: Wo G/pm) Sampling Equipment Used: �iSa�tlkJC Instrument Bottle Type Preservation Analysis Recjuired. N - Ao —tests Vuc. ?r LAO µ1. V 'M 430 ht Ca§D w O A-1,H V Oka Field Measurementn/Obaeryation_p, Sample TempVq: %1@5 '['ime:0_'1'urbldity(ntu): Time: 100 Dlss Oxy (mg/. L): Time, �� Pe 2+ mg/ L:� Specific Cond. (uS): _•Time: 1130_ Res. Cl Sample pH (s.u.): 5.?z^Time: _ddor: Nfl Timer L ReDox (mV): 11. 3 Time: 1110 ._ Appearance: LA_wx 4;Time: ReDox (RH vaiue):YSI ProPlus +20dntV jot_$ _.Other Time: General/WeatherObservafl=6: _ -_- . - -, _( nn /cloudy/rainy) Temp., (°l) Wind,-.� (mph) Stahilizatinn Teat Time Temp. Diss Oxy. Spec. ` PH (&%) ReDox Turbidity o ttme removed {gallons/1 Water level Other Purged (1C) (mgll,) �� (mV) (ntu) ti / (ft) r .J 5 lip -is, 606 ll Vi �y ■ ww 1. V! 9. pocuaegt Pjamm Document Issued: Marrlt s, 2m9 ceArtalytic��!' Meld Data Sheet �aga10l� Docmhent Number: F-AR-FLD-M.rev.03 issueing Authority: Puce Hunteraville Quality Office l Client, RL Location: Project, Co WBII JD:. Reviewed Date and -By:_IZZ(/2j_ A -AP) Stabilixatlonjest lV& Dlame%r 'Alulti licatibrt Factor, 1 0.0408 1.2 0.0918 1.623 0.1080 2 0.1630 3 0.3670 4 0.6330 6 1.4680 81 2.6100 Time • • d, • I)Atc Issued: March 8,.2019 Dotument Name: Meld dataSheet PaLe t of 1 f �rceA►k7lylfcnl Issuing Authodly: race Ftuntersviite'Quality Document Number; r CAR-T'LD OOt mv.03 Offke Field Data sheet Location:� FQ Name and Affiliation (Sampler(s): AT - S&a_ Nance and Affiliation (Inspector): Well Informs Well TD: IK t o - W ' Well Diameter: a Total Well. Depth: '41-1a ft Static water Level:2,1,S ft Height of Water Cotunut:t .—II A Purse Information Date.Purged:-Ik-,._./ '30J.. ]XI Data Sheet Review: Date, Well locked: QEY NO / Rashmount ) Construction: M Steel/Stainless Steel) Multi Factor•• •1 �3 ..._ C(rtadi-/j2)2x 3.14 x 7.401 Casing Volume: i • 3 gallons Cal. 3 Volumes: L4 • 1° _ gallons Pump Intake: 4 G ft Se wH� 1»4wa�`rt\\ J r' By' eme Start :13' 5 , Finish:_) o3ti--- purge Rate:�o 1 ;, Purging Method: Won5eo A - _.Total Volume Purged: Samgligs Information Date CoUecteds +/�/T].,3 Time Collected: tOSS I/pnt) Sampling Equipment Used: I�XL3esiagnlnstrumeftt ID: �1S a2h, 'T�1 6il'1. Bottle Type i,�25o �.l 17iasa-:� 3x4a .-J Field MeasuremeAWD-- iseMa—bons Preservation Analysis Required RC W %4 • 6ntkIIA10 Sample Temp (PC): tf, .� 1-im 1o3S Turbidity(ntu); Diss Oxy (rng/L)-. 'Time: Fe 2+ Specific CbrSd..(uS): 3i . Tinter Res. CI (xr►g/Ly(µg/i:):Time: Sample pH (s.u.): 5 - Sa _ Time: Odor:_ ltr\� Time: Repox (mV): ^ II A Time: Appearance-Al'-'gmT dv TTime; t OAS ReDox (EH value):YSI ProPlus +206m.V 2 - Other. Time: ` General/Weather Observatigns- s ny cloudy/rainy) Temp.-Lok'S -rF) WindO-S (mph) Sampler Signature Stabilizationtest Diss Oxy. Ste' Cond: pH (s.u.) ReDox Turbidity Volume removed Water Other Purged (Ing/L) (us) (mV) (ntu) (gallons/a'�/ level (ft) L fiql�.s %.4 43.5 S 6 l 2S. t�LSo 'SI.5 �t3S 5. [ b6.1 .2-5. M5qS.1 s So is. 16.2 b2T 2 • 3-7. $. $2, 1y. g7sa Document Nanlo: PkId.dotii Shed ante issued: With d, 2019 PaLe: 1 of j acealn1y11cM rimument-Numtmr, F-CAR-PIJ341-rev.03 Issuing AltIhwJty:,Nce HunteLwille'QO;Iity Offke. Field Data Sheet Name and Affiliation (Sanipler(s):_ Name.and Affiliation (inspector): Well Information Well ID:..�'8to' N1U� 'gS Well Diameter: Total Well Depth: 41A45 ft Static Water Level:�0$ ft Height.of Water .Column:_n.I-7 ft Well Locked: co, S0U+'n'LdA -; Field Data SheetReWew: 12-I- L3 Date: l 2�1 /2.j By.,'M IC3 NO / Flushmount ) Construction-. �/Steel/Stainless Steel) Multi Factor•: CAJ31 lt(Radiug/12)2x8.14 x 7.481 Casing Volume: ? . R — gallons Cal.3 Volumes., B. gallops Pump Intake: 00A'CI)w ft rVjM Information Date Start: _�Q Finish: tWS Pi;ge Rate: kOOM A Purging Method: ¢rt5i�+e Total Volume Purged: .15W (gallons/@/L) Sarnoline Information UTteCollected:—A--/_&i/_A�L, TIW6Colltscted:. _lA3o . OM/6 Sampling UquipmentUsed: e�l7 iZ instrumantlD; � ���0 Bottle Type Preservation Analysis Requixed i- I5F)VAL V\ uot) Tmwl.kkw� (Miol-7,+-to _3- �R+u Nil, avriixr a--w D �36o fl S t M 169 Field Measurentents/Observatlon Sample Temp CC): !,>49 l'irXte:�t�! + Turbidity (ft u): q-7 Time: Diss.Oxy (mg/L): (Q-� - $ -- - Tione, 1t3a Fe 21- mgtL: �Tlme:- --WAWN135 Specific Cond. (uS): 3*i ,Q Time: 140 Res, Cl (mg/L)/(µg/L): ! Tiute— Sample pH (s.u.): _ Time: ' ��,�A, Odor:.. � -- - Time: LI__._ ReDox (mV); 3�1�. ��Time: _Ap earancesS(YW1i r'1rfi+culuk $me: ReDox (RH vnlue):YSI ProPlus +20ainV 9a13.1-. _Other: Time: General/Weather Observations, �_ un /cloudy/rainy) Temp.__,(°F� Wind .(milli) Stabilization Test Time Temp. Disc C)xy. Spec. Cond. pH (s.u.) ReDox Turbidity Volume remove Water Other Purged e(C) (mg/ L) (MS) (mV) (ntu) (gallons/ level (ft) L 13.g 34.E �.. 'T % 'V �� n �Y Vr"„ '1 k1 1919 f M r'a2r Ov 'T t% Document Nuini: Field datn Sheet D,110 Issued: March 8, 2019 Page; t of _ r7C8A n71YIWr' fssusog Authoiily: Pam HuntersvitteQualitY Ti xumcnl Number, P-CAR-PL11301-rev.01 Office Name and Affiliation (Sampler(a):�i( Name and Affiliation (Inspector): Well Information Wel11D:-M\AJ- °iD_ Well Diameter; n U Total Well Depth:. (61-7p ft Static Water Level: (4,74 ft Height of Water Column:-Sga,%Eft Well Locked: Construction: Data Sheet Review: 1x-i-z3 Date: Steel) MuttlFactor*: 6A93 (1(9a4ius/12)2x3.14x7.481 Casing Volume: gallons Cal. 3 Volumes, �_ I gallolls Pump -Intake: (M W-�i-_ft 5(wvk 14-2d'13 Irk By: RAO i!Am Information Date Pul cj:_1]_/ /- �� Start: 132D Finish: Q' 6I'tirgeRate:� rn�1 Purging Method: Qt'i ,�"tC total Volume Purged: (gallons/�O/L) -SAmgHgg lnf rrnation Date Colletted: _ 1l_ -I�LII .�3 fine Collected:_ (ani%�) Sampling Equipment. Used; Instrument ID: Bottle Type preservation Analysis Required y dam. clNOW— Field M asurementaf0bservations Sample Temp Cq. _ i'ime:,_fo Turbidity (ntu): -- -�— Time: Diss.Oxy.(mg/L):_SQ.��Time, _Fe2+mg/L:._ Time:. Specific CQnd. (uS): _,�. d Time: _.. 6 Res. Ci (li,g/L�(ug/ L}:^� _Tune :`�+ Sample PH (s.u.).. 67. RTlme: \L60 Odor:,_„_ ReDox (mV): (0�9,,q Time: �Appearatwe: P&Zr W ; iY'�fime: 13517 ReDox (PH value):YSI ProPlus +200mV Other: , , .. ._� Time: General/Weather Observations• W �l unn /cloudy/rainy) Ternp.�_(911 Wind t-,S (r Sampler Signature Stabilization Test Time Purged Temp. CC) DissO . (mg/) Spec' (US) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/le/ L Water Level (ft) Othee 3$ �: kenoMI 1 ► �-o,5i.V .� - Lp. 3rS3�o '� a�8 .'i -M5 1a-1 kp.cY n o 16,i} ?(P-6-`t t-t jbw tP• t`'� Dotumeat Now: Field dote Sheet fate leaned: March 6, 2t314 Page, 1of� .:P,?CeArt,�lylk��l' Imubig Authority; Mice Hunteraville Quality tk+cumcntNumber, FCAR-F1.11 p¢1 rvv.g3 Office Field Qata Sheet Name and Affiliation (Sampler(s): 1' S40 Name And Affiliation (Inspector):"—" Weil Information Well ID': g1O)r --R W -1 ttia'q as - Well Diameter: c1`i Total Well Depth: ft Static Wate vel�ft Heig f Water Colunin:—-,ft Purge Information Date:Pt4ro, Well Locked: Construction; (P Sou4Yll.ana�• II-� Field Data Sheet Review: IL- tf4- Date: %Z/f/1) By' (1tn/3 Multi Factor*: I-(Radius/i1)2 0.14 x 7A$l Casing Volu gallons CAI, 3 V 4tmes: gailpns P p Intake: —it Start: Finish: Puggs. Rate: —^-� Purging Method: Total Volume Purged: --- (gallons/mis/ L) SamoliAL, Irif Date Collected:. L1 /�9/ a2 Tints Cal3ecte& W( Pm) Sampling Equipment Used: C� t- _Instrument IU: "�� w'�J Bottle Type. Preservation Analysis: Required _3--14aaw+a[ G1Cx4c,uk.3 W-D14 Field MeasuremenWgbservations Sample Temp CC): $• --- - 'i'zme; _ � A _ Turbidity (ntu)! MD 'Time: Dis$ Oxy (mg/i,): 1p Time. W Fe 2+ mg/ Time: Specific Corid. (u9): Time: 1' --Res. La tithe/L)/('t8/L): TjMe. Sample pH (s.u.): Time: I 45Odor: tjTime:' ReDox (mV)-. Ti.'.. P1`A1p'p1earance: Gnu Time: ` ReDox (EH vatue):YS1 ProPlus +200mV 'b .0 Other: ime: General/Weather Observatians• rul/cloudy/rainy) Tetnp.:Hg (°F) Wl�id,1�(mph) Stabilization Teat Time Purged Temp. CC) Diss Oxy. (tng/L) Spy' Cond(u5) ` pl{ (s.U.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/mis/ L Water level (ft) Other •7. Inaft AIAIkNYs f'MnH LUkWXVtIIe'QUA 7,t offive 'kilttiewW Affiliatian C5mpIe*)-__ Ek UP- FiEdd DiataShVet kevieW: i2a well M. - —,— Totial Weil up-ptil, statfc-watmpr Levek Casing Volume, gallons tT�i$ht of WEUCT ColuArl-7,ift Cal. 3 voluzim; FurgInamo6od - L. ... Pump lntvkc z UWVolurfte Purged: IVI R20: BY: Date. CoRected, /'-D Sampling-f-iquipmML mtruwaf ID'_ pffnYvailion Ainalyzim Required HAVj t I'Js Field Gas uremenWQbpervatlo Sample-Tompfq: LCL. _TtyWity.(*)I.._ 3, 1 Time, ._J 01C.) TIfne;- UD_2.Q C3 _j SDI 0 OdwL,,. __ nue, I D I D Appearance- L Rej)ox (XIJ vd4o).Y!o NOPIUS _Other: Tin= General/Weather obsftva"OOL6ef _,_ 35f IiiII.-OV " &)j �j 0 Lf S.%mPler Sipatu 100 Temp, Didv�- 9PK. Cnnd- (u5) pH (a.u.) ReDox ' (MVO Turbidity imovpd wtiter kvel eft), Other I L Rutherford Co. South landfill Nov. 2023 Well ID Static Time Date M W-1 31.36 1258 11/29/2023 MW-2A 36.54 1003 MW-3 DRY 1017 MW-4A 26.051 1013 M W-5 11.76 1043 MW-6 30.72 1024 MW-7 19.31 1237 MW-8 33.51 1253 MW-95 7.081 1302 MW-913 1 6.741 1302 APPENDIX B LABORATORY ANALYTICAL DATA - PACE ANALYTICAL SERVICES, LLC. ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 December 12, 2023 James Kilgo Rutherford County Solid Waste PO Box 1957 Rutherfordton, NC 28139 RE: Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Dear James Kilgo: Enclosed are the analytical results for sample(s) received by the laboratory on November 30, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Mr. Andy Alexander, Bunnell-Lammons Engineering Riley Blais, BILE Corp Accounts Payable, Rutherford County Landfill Director REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 69 Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Rutherford Co South LF Nov23 92700988 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92700988001 8102-MW-9S EPA 6010D D13131 7 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D LMB 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C 92700988002 8102-MW-9D EPA 6010D D13131 7 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D LMB 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C 92700988003 8102-SW-1 EPA 6010D DBB1 7 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D LMB 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C 92700988004 8102-Duplicate EPA 8260D LMB 52 PASI-C 92700988005 8102-MW-1 EPA 6010D DBB1 7 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D SAS 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C 92700988006 8102-MW-2A EPA 6010D DBB1 7 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D SAS 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C 92700988007 8102-MW-4A EPA 6010D DBB1 7 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D SAS 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C 92700988008 8102-MW-5 EPA 6010D DBB1 7 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D SAS 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C 92700988009 8102-MW-6 EPA 6010D DBB1 7 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D SAS 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C 92700988010 8102-MW-7 EPA 6010D DBB1 7 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D SAS 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92700988011 8102-MW-8 EPA 6010D DBB1 7 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D SAS 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C 92700988012 8102-SW-2 EPA 6010D D661 7 PASI-A EPA 7470A BM 1 PASI-A EPA 8260D SAS 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Sample: 8102-MW-9S Lab ID: 92700988001 Collected: 11/29/23 14:30 Received: 11/30/23 08:00 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic <2.5 ug/L 2.5 1 12/03/2312:45 12/11/2318:55 7440-38-2 Barium 36.3 ug/L 0.79 1 12/03/2312:45 12/11/2318:55 7440-39-3 Cadmium <0.29 ug/L 0.29 1 12/03/2312:45 12/11/2318:55 7440-43-9 Chromium <0.63 ug/L 0.63 1 12/03/2312:45 12/11/2318:55 7440-47-3 Lead <1.4 ug/L 1.4 1 12/03/2312:45 12/11/2318:55 7439-92-1 Selenium <4.1 ug/L 4.1 1 12/03/2312:45 12/11/2318:55 7782-49-2 Silver <0.49 ug/L 0.49 1 12/03/2312:45 12/11/2318:55 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury <0.12 ug/L 0.12 1 12/08/2313:03 12/09/2312:05 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone <5.1 ug/L 5.1 1 12/05/23 09:00 67-64-1 v2 Acrylonitrile <1.8 ug/L 1.8 1 12/05/23 09:00 107-13-1 Benzene <0.34 ug/L 0.34 1 12/05/23 09:00 71-43-2 Bromochloromethane <0.47 ug/L 0.47 1 12/05/23 09:00 74-97-5 Bromodichloromethane <0.31 ug/L 0.31 1 12/05/23 09:00 75-27-4 Bromoform <0.34 ug/L 0.34 1 12/05/23 09:00 75-25-2 Bromomethane <1.7 ug/L 1.7 1 12/05/23 09:00 74-83-9 IH 2-Butanone (MEK) <4.0 ug/L 4.0 1 12/05/23 09:00 78-93-3 Carbon disulfide <0.36 ug/L 0.36 1 12/05/23 09:00 75-15-0 Carbon tetrachloride <0.33 ug/L 0.33 1 12/05/23 09:00 56-23-5 Chlorobenzene <0.28 ug/L 0.28 1 12/05/23 09:00 108-90-7 Chloroethane <0.65 ug/L 0.65 1 12/05/23 09:00 75-00-3 Chloroform <0.43 ug/L 0.43 1 12/05/23 09:00 67-66-3 Chloromethane <0.54 ug/L 0.54 1 12/05/23 09:00 74-87-3 1,2-Dibromo-3-chloropropane <0.34 ug/L 0.34 1 12/05/23 09:00 96-12-8 Dibromochloromethane <0.36 ug/L 0.36 1 12/05/23 09:00 124-48-1 1,2-Dibromoethane (EDB) <0.27 ug/L 0.27 1 12/05/23 09:00 106-93-4 Dibromomethane <0.39 ug/L 0.39 1 12/05/23 09:00 74-95-3 1,2-Dichlorobenzene <0.34 ug/L 0.34 1 12/05/23 09:00 95-50-1 1,4-Dichlorobenzene <0.33 ug/L 0.33 1 12/05/23 09:00 106-46-7 trans-1,4-Dichloro-2-butene <0.56 ug/L 0.56 1 12/05/23 09:00 110-57-6 1,1-Dichloroethane <0.37 ug/L 0.37 1 12/05/23 09:00 75-34-3 1,2-Dichloroethane <0.32 ug/L 0.32 1 12/05/23 09:00 107-06-2 1,1-Dichloroethene <0.35 ug/L 0.35 1 12/05/23 09:00 75-35-4 cis-1,2-Dichloroethene <0.38 ug/L 0.38 1 12/05/23 09:00 156-59-2 trans-1,2-Dichloroethene <0.40 ug/L 0.40 1 12/05/23 09:00 156-60-5 1,2-Dichloropropane <0.36 ug/L 0.36 1 12/05/23 09:00 78-87-5 cis-1,3-Dichloropropene <0.36 ug/L 0.36 1 12/05/23 09:00 10061-01-5 trans- 1,3-Dichloropropene <0.36 ug/L 0.36 1 12/05/23 09:00 10061-02-6 Ethylbenzene <0.30 ug/L 0.30 1 12/05/23 09:00 100-41-4 2-Hexanone <0.48 ug/L 0.48 1 12/05/23 09:00 591-78-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Sample: 8102-MW-9S Lab ID: 92700988001 Collected: 11/29/23 14:30 Received: 11/30/23 08:00 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte lodomethane <9.7 ug/L 9.7 1 12/05/23 09:00 74-88-4 Methylene Chloride <2.0 ug/L 2.0 1 12/05/23 09:00 75-09-2 4-Methyl-2-pentanone (MIBK) <2.7 ug/L 2.7 1 12/05/23 09:00 108-10-1 Styrene <0.29 ug/L 0.29 1 12/05/23 09:00 100-42-5 1,1,1,2-Tetrachloroethane <0.31 ug/L 0.31 1 12/05/23 09:00 630-20-6 1,1,2,2-Tetrachloroethane <0.22 ug/L 0.22 1 12/05/23 09:00 79-34-5 Tetrachloroethene <0.29 ug/L 0.29 1 12/05/23 09:00 127-18-4 Toluene <0.24 ug/L 0.24 1 12/05/23 09:00 108-88-3 1,1,1-Trichloroethane <0.33 ug/L 0.33 1 12/05/23 09:00 71-55-6 1,1,2-Trichloroethane <0.32 ug/L 0.32 1 12/05/23 09:00 79-00-5 Trichloroethene <0.38 ug/L 0.38 1 12/05/23 09:00 79-01-6 Trichlorofluoromethane <0.30 ug/L 0.30 1 12/05/23 09:00 75-69-4 1,2,3-Trichloropropane <0.26 ug/L 0.26 1 12/05/23 09:00 96-18-4 Vinyl acetate <1.3 ug/L 1.3 1 12/05/23 09:00 108-05-4 Vinyl chloride <0.39 ug/L 0.39 1 12/05/23 09:00 75-01-4 Xylene (Total) <0.34 ug/L 0.34 1 12/05/23 09:00 1330-20-7 m&p-Xylene <0.71 ug/L 0.71 1 12/05/23 09:00 179601-23-1 o-Xylene <0.34 ug/L 0.34 1 12/05/23 09:00 95-47-6 Surrogates 4-Bromofluorobenzene (S) 90 % 70-130 1 12/05/23 09:00 460-00-4 1,2-Dichloroethane-d4 (S) 90 % 70-130 1 12/05/23 09:00 17060-07-0 Toluene-d8(S) 97 % 70-130 1 12/05/23 09:00 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) <0.86 ug/L 0.86 1 12/01/23 20:27 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 96 % 67-130 1 12/01/23 20:27 17060-07-0 Toluene-d8(S) 100 % 70-130 1 12/01/23 20:27 2037-26-5 Date: 12/12/2023 05:36 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Sample: 8102-MW-9D Lab ID: 92700988002 Collected: 11/29/23 13:50 Received: 11/30/23 08:00 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic <2.5 ug/L 2.5 1 12/03/2312:45 12/11/2319:06 7440-38-2 Barium 30.6 ug/L 0.79 1 12/03/2312:45 12/11/2319:06 7440-39-3 Cadmium <0.29 ug/L 0.29 1 12/03/2312:45 12/11/2319:06 7440-43-9 Chromium <0.63 ug/L 0.63 1 12/03/2312:45 12/11/2319:06 7440-47-3 Lead <1.4 ug/L 1.4 1 12/03/2312:45 12/11/2319:06 7439-92-1 Selenium <4.1 ug/L 4.1 1 12/03/2312:45 12/11/2319:06 7782-49-2 Silver <0.49 ug/L 0.49 1 12/03/2312:45 12/11/2319:06 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury <0.12 ug/L 0.12 1 12/08/2313:03 12/09/2312:08 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone <5.1 ug/L 5.1 1 12/05/23 09:19 67-64-1 v2 Acrylonitrile <1.8 ug/L 1.8 1 12/05/23 09:19 107-13-1 Benzene <0.34 ug/L 0.34 1 12/05/23 09:19 71-43-2 Bromochloromethane <0.47 ug/L 0.47 1 12/05/23 09:19 74-97-5 Bromodichloromethane <0.31 ug/L 0.31 1 12/05/23 09:19 75-27-4 Bromoform <0.34 ug/L 0.34 1 12/05/23 09:19 75-25-2 Bromomethane <1.7 ug/L 1.7 1 12/05/23 09:19 74-83-9 IH 2-Butanone (MEK) <4.0 ug/L 4.0 1 12/05/23 09:19 78-93-3 Carbon disulfide <0.36 ug/L 0.36 1 12/05/23 09:19 75-15-0 Carbon tetrachloride <0.33 ug/L 0.33 1 12/05/23 09:19 56-23-5 Chlorobenzene <0.28 ug/L 0.28 1 12/05/23 09:19 108-90-7 Chloroethane <0.65 ug/L 0.65 1 12/05/23 09:19 75-00-3 Chloroform <0.43 ug/L 0.43 1 12/05/23 09:19 67-66-3 Chloromethane <0.54 ug/L 0.54 1 12/05/23 09:19 74-87-3 1,2-Dibromo-3-chloropropane <0.34 ug/L 0.34 1 12/05/23 09:19 96-12-8 Dibromochloromethane <0.36 ug/L 0.36 1 12/05/23 09:19 124-48-1 1,2-Dibromoethane (EDB) <0.27 ug/L 0.27 1 12/05/23 09:19 106-93-4 Dibromomethane <0.39 ug/L 0.39 1 12/05/23 09:19 74-95-3 1,2-Dichlorobenzene <0.34 ug/L 0.34 1 12/05/23 09:19 95-50-1 1,4-Dichlorobenzene <0.33 ug/L 0.33 1 12/05/23 09:19 106-46-7 trans-1,4-Dichloro-2-butene <0.56 ug/L 0.56 1 12/05/23 09:19 110-57-6 1,1-Dichloroethane <0.37 ug/L 0.37 1 12/05/23 09:19 75-34-3 1,2-Dichloroethane <0.32 ug/L 0.32 1 12/05/23 09:19 107-06-2 1,1-Dichloroethene <0.35 ug/L 0.35 1 12/05/23 09:19 75-35-4 cis-1,2-Dichloroethene <0.38 ug/L 0.38 1 12/05/23 09:19 156-59-2 trans-1,2-Dichloroethene <0.40 ug/L 0.40 1 12/05/23 09:19 156-60-5 1,2-Dichloropropane <0.36 ug/L 0.36 1 12/05/23 09:19 78-87-5 cis-1,3-Dichloropropene <0.36 ug/L 0.36 1 12/05/23 09:19 10061-01-5 trans- 1,3-Dichloropropene <0.36 ug/L 0.36 1 12/05/23 09:19 10061-02-6 Ethylbenzene <0.30 ug/L 0.30 1 12/05/23 09:19 100-41-4 2-Hexanone <0.48 ug/L 0.48 1 12/05/23 09:19 591-78-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Sample: 8102-MW-9D Lab ID: 92700988002 Collected: 11/29/23 13:50 Received: 11/30/23 08:00 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte lodomethane <9.7 ug/L 9.7 1 12/05/23 09:19 74-88-4 Methylene Chloride <2.0 ug/L 2.0 1 12/05/23 09:19 75-09-2 4-Methyl-2-pentanone (MIBK) <2.7 ug/L 2.7 1 12/05/23 09:19 108-10-1 Styrene <0.29 ug/L 0.29 1 12/05/23 09:19 100-42-5 1,1,1,2-Tetrachloroethane <0.31 ug/L 0.31 1 12/05/23 09:19 630-20-6 1,1,2,2-Tetrachloroethane <0.22 ug/L 0.22 1 12/05/23 09:19 79-34-5 Tetrachloroethene <0.29 ug/L 0.29 1 12/05/23 09:19 127-18-4 Toluene <0.24 ug/L 0.24 1 12/05/23 09:19 108-88-3 1,1,1-Trichloroethane <0.33 ug/L 0.33 1 12/05/23 09:19 71-55-6 1,1,2-Trichloroethane <0.32 ug/L 0.32 1 12/05/23 09:19 79-00-5 Trichloroethene <0.38 ug/L 0.38 1 12/05/23 09:19 79-01-6 Trichlorofluoromethane <0.30 ug/L 0.30 1 12/05/23 09:19 75-69-4 1,2,3-Trichloropropane <0.26 ug/L 0.26 1 12/05/23 09:19 96-18-4 Vinyl acetate <1.3 ug/L 1.3 1 12/05/23 09:19 108-05-4 Vinyl chloride <0.39 ug/L 0.39 1 12/05/23 09:19 75-01-4 Xylene (Total) <0.34 ug/L 0.34 1 12/05/23 09:19 1330-20-7 m&p-Xylene <0.71 ug/L 0.71 1 12/05/23 09:19 179601-23-1 o-Xylene <0.34 ug/L 0.34 1 12/05/23 09:19 95-47-6 Surrogates 4-Bromofluorobenzene (S) 93 % 70-130 1 12/05/23 09:19 460-00-4 1,2-Dichloroethane-d4 (S) 88 % 70-130 1 12/05/23 09:19 17060-07-0 Toluene-d8(S) 99 % 70-130 1 12/05/23 09:19 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) <0.86 ug/L 0.86 1 12/01/23 20:48 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 96 % 67-130 1 12/01/23 20:48 17060-07-0 Toluene-d8(S) 100 % 70-130 1 12/01/23 20:48 2037-26-5 Date: 12/12/2023 05:36 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Sample: 8102-SW-1 Lab ID: 92700988003 Collected: 11/29/23 14:50 Received: 11/30/23 08:00 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic <2.5 ug/L 2.5 1 12/03/2312:45 12/11/2319:09 7440-38-2 Barium 19.4 ug/L 0.79 1 12/03/2312:45 12/11/2319:09 7440-39-3 Cadmium <0.29 ug/L 0.29 1 12/03/2312:45 12/11/2319:09 7440-43-9 Chromium <0.63 ug/L 0.63 1 12/03/2312:45 12/11/2319:09 7440-47-3 Lead <1.4 ug/L 1.4 1 12/03/2312:45 12/11/2319:09 7439-92-1 Selenium <4.1 ug/L 4.1 1 12/03/2312:45 12/11/2319:09 7782-49-2 Silver <0.49 ug/L 0.49 1 12/03/2312:45 12/11/2319:09 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury <0.12 ug/L 0.12 1 12/08/2313:03 12/09/2312:14 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone <5.1 ug/L 5.1 1 12/05/23 09:38 67-64-1 v2 Acrylonitrile <1.8 ug/L 1.8 1 12/05/23 09:38 107-13-1 Benzene <0.34 ug/L 0.34 1 12/05/23 09:38 71-43-2 Bromochloromethane <0.47 ug/L 0.47 1 12/05/23 09:38 74-97-5 Bromodichloromethane <0.31 ug/L 0.31 1 12/05/23 09:38 75-27-4 Bromoform <0.34 ug/L 0.34 1 12/05/23 09:38 75-25-2 Bromomethane <1.7 ug/L 1.7 1 12/05/23 09:38 74-83-9 IH 2-Butanone (MEK) <4.0 ug/L 4.0 1 12/05/23 09:38 78-93-3 Carbon disulfide <0.36 ug/L 0.36 1 12/05/23 09:38 75-15-0 Carbon tetrachloride <0.33 ug/L 0.33 1 12/05/23 09:38 56-23-5 Chlorobenzene <0.28 ug/L 0.28 1 12/05/23 09:38 108-90-7 Chloroethane <0.65 ug/L 0.65 1 12/05/23 09:38 75-00-3 Chloroform <0.43 ug/L 0.43 1 12/05/23 09:38 67-66-3 Chloromethane <0.54 ug/L 0.54 1 12/05/23 09:38 74-87-3 1,2-Dibromo-3-chloropropane <0.34 ug/L 0.34 1 12/05/23 09:38 96-12-8 Dibromochloromethane <0.36 ug/L 0.36 1 12/05/23 09:38 124-48-1 1,2-Dibromoethane (EDB) <0.27 ug/L 0.27 1 12/05/23 09:38 106-93-4 Dibromomethane <0.39 ug/L 0.39 1 12/05/23 09:38 74-95-3 1,2-Dichlorobenzene <0.34 ug/L 0.34 1 12/05/23 09:38 95-50-1 1,4-Dichlorobenzene <0.33 ug/L 0.33 1 12/05/23 09:38 106-46-7 trans-1,4-Dichloro-2-butene <0.56 ug/L 0.56 1 12/05/23 09:38 110-57-6 1,1-Dichloroethane <0.37 ug/L 0.37 1 12/05/23 09:38 75-34-3 1,2-Dichloroethane <0.32 ug/L 0.32 1 12/05/23 09:38 107-06-2 1,1-Dichloroethene <0.35 ug/L 0.35 1 12/05/23 09:38 75-35-4 cis-1,2-Dichloroethene <0.38 ug/L 0.38 1 12/05/23 09:38 156-59-2 trans-1,2-Dichloroethene <0.40 ug/L 0.40 1 12/05/23 09:38 156-60-5 1,2-Dichloropropane <0.36 ug/L 0.36 1 12/05/23 09:38 78-87-5 cis-1,3-Dichloropropene <0.36 ug/L 0.36 1 12/05/23 09:38 10061-01-5 trans- 1,3-Dichloropropene <0.36 ug/L 0.36 1 12/05/23 09:38 10061-02-6 Ethylbenzene <0.30 ug/L 0.30 1 12/05/23 09:38 100-41-4 2-Hexanone <0.48 ug/L 0.48 1 12/05/23 09:38 591-78-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Sample: 8102-SW-1 Lab ID: 92700988003 Collected: 11/29/23 14:50 Received: 11/30/23 08:00 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/12/2023 05:36 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte <9.7 ug/L <2.0 ug/L <2.7 ug/L <0.29 ug/L <0.31 ug/L <0.22 ug/L <0.29 ug/L <0.24 ug/L <0.33 ug/L <0.32 ug/L <0.38 ug/L <0.30 ug/L <0.26 ug/L <1.3 ug/L <0.39 ug/L <0.34 ug/L <0.71 ug/L <0.34 ug/L 92 % 89 % 99 % Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte <0.86 ug/L 96 % 100 % 9.7 1 12/05/23 09:38 74-88-4 2.0 1 12/05/23 09:38 75-09-2 2.7 1 12/05/23 09:38 108-10-1 0.29 1 12/05/23 09:38 100-42-5 0.31 1 12/05/23 09:38 630-20-6 0.22 1 12/05/23 09:38 79-34-5 0.29 1 12/05/23 09:38 127-18-4 0.24 1 12/05/23 09:38 108-88-3 0.33 1 12/05/23 09:38 71-55-6 0.32 1 12/05/23 09:38 79-00-5 0.38 1 12/05/23 09:38 79-01-6 0.30 1 12/05/23 09:38 75-69-4 0.26 1 12/05/23 09:38 96-18-4 1.3 1 12/05/23 09:38 108-05-4 0.39 1 12/05/23 09:38 75-01-4 0.34 1 12/05/23 09:38 1330-20-7 0.71 1 12/05/23 09:38 179601-23-1 0.34 1 12/05/23 09:38 95-47-6 70-130 1 70-130 1 70-130 1 67-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/05/23 09:38 460-00-4 12/05/23 09:38 17060-07-0 12/05/23 09:38 2037-26-5 12/01 /23 21:09 17060-07-0 12/01 /23 21:09 2037-26-5 Page 10 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Sample: 8102-Duplicate Parameters 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride ANALYTICAL RESULTS Lab ID: 92700988004 Collected: 11/29/23 13:50 Received: 11/30/23 08:00 Matrix: Water Results Units Analytical Method: EPA 8260D Pace Analytical Services - Charlotte <5.1 ug/L <1.8 ug/L <0.34 ug/L <0.47 ug/L <0.31 ug/L <0.34 ug/L <1.7 ug/L <4.0 ug/L <0.36 ug/L <0.33 ug/L <0.28 ug/L <0.65 ug/L <0.43 ug/L <0.54 ug/L <0.34 ug/L <0.36 ug/L <0.27 ug/L <0.39 ug/L <0.34 ug/L <0.33 ug/L <0.56 ug/L <0.37 ug/L <0.32 ug/L <0.35 ug/L <0.38 ug/L <0.40 ug/L <0.36 ug/L <0.36 ug/L <0.36 ug/L <0.30 ug/L <0.48 ug/L <9.7 ug/L <2.0 ug/L <2.7 ug/L <0.29 ug/L <0.31 ug/L <0.22 ug/L <0.29 ug/L <0.24 ug/L <0.33 ug/L <0.32 ug/L <0.38 ug/L <0.30 ug/L <0.26 ug/L <1.3 ug/L <0.39 ug/L PQL DF Prepared Analyzed CAS No. Qual 5.1 1 12/05/23 09:56 67-64-1 1.8 1 12/05/23 09:56 107-13-1 0.34 1 12/05/23 09:56 71-43-2 0.47 1 12/05/23 09:56 74-97-5 0.31 1 12/05/23 09:56 75-27-4 0.34 1 12/05/23 09:56 75-25-2 1.7 1 12/05/23 09:56 74-83-9 4.0 1 12/05/23 09:56 78-93-3 0.36 1 12/05/23 09:56 75-15-0 0.33 1 12/05/23 09:56 56-23-5 0.28 1 12/05/23 09:56 108-90-7 0.65 1 12/05/23 09:56 75-00-3 0.43 1 12/05/23 09:56 67-66-3 0.54 1 12/05/23 09:56 74-87-3 0.34 1 12/05/23 09:56 96-12-8 0.36 1 12/05/23 09:56 124-48-1 0.27 1 12/05/23 09:56 106-93-4 0.39 1 12/05/23 09:56 74-95-3 0.34 1 12/05/23 09:56 95-50-1 0.33 1 12/05/23 09:56 106-46-7 0.56 1 12/05/23 09:56 110-57-6 0.37 1 12/05/23 09:56 75-34-3 0.32 1 12/05/23 09:56 107-06-2 0.35 1 12/05/23 09:56 75-35-4 0.38 1 12/05/23 09:56 156-59-2 0.40 1 12/05/23 09:56 156-60-5 0.36 1 12/05/23 09:56 78-87-5 0.36 1 12/05/23 09:56 10061-01-5 0.36 1 12/05/23 09:56 10061-02-6 0.30 1 12/05/23 09:56 100-41-4 0.48 1 12/05/23 09:56 591-78-6 9.7 1 12/05/23 09:56 74-88-4 2.0 1 12/05/23 09:56 75-09-2 2.7 1 12/05/23 09:56 108-10-1 0.29 1 12/05/23 09:56 100-42-5 0.31 1 12/05/23 09:56 630-20-6 0.22 1 12/05/23 09:56 79-34-5 0.29 1 12/05/23 09:56 127-18-4 0.24 1 12/05/23 09:56 108-88-3 0.33 1 12/05/23 09:56 71-55-6 0.32 1 12/05/23 09:56 79-00-5 0.38 1 12/05/23 09:56 79-01-6 0.30 1 12/05/23 09:56 75-69-4 0.26 1 12/05/23 09:56 96-18-4 1.3 1 12/05/23 09:56 108-05-4 0.39 1 12/05/23 09:56 75-01-4 REPORT OF LABORATORY ANALYSIS v2 IH This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Sample: 8102-Duplicate Parameters Lab ID: 92700988004 Collected: 11/29/23 13:50 Results Units PQL DF Received: 11/30/23 08:00 Matrix: Water Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Xylene (Total) <0.34 ug/L 0.34 1 12/05/23 09:56 1330-20-7 m&p-Xylene <0.71 ug/L 0.71 1 12/05/23 09:56 179601-23-1 o-Xylene <0.34 ug/L 0.34 1 12/05/23 09:56 95-47-6 Surrogates 4-Bromofluorobenzene (S) 93 % 70-130 1 12/05/23 09:56 460-00-4 1,2-Dichloroethane-d4 (S) 86 % 70-130 1 12/05/23 09:56 17060-07-0 Toluene-d8(S) 99 % 70-130 1 12/05/23 09:56 2037-26-5 Date: 12/12/2023 05:36 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Sample: 8102-MW-1 Lab ID: 92700988005 Collected: 11/30/23 11:40 Received: 11/30/23 14:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic <2.5 ug/L 2.5 1 12/03/2312:45 12/11/2319:34 7440-38-2 Barium 92.3 ug/L 0.79 1 12/03/2312:45 12/11/2319:34 7440-39-3 Cadmium <0.29 ug/L 0.29 1 12/03/2312:45 12/11/2319:34 7440-43-9 Chromium <0.63 ug/L 0.63 1 12/03/2312:45 12/11/2319:34 7440-47-3 Lead <1.4 ug/L 1.4 1 12/03/2312:45 12/11/2319:34 7439-92-1 Selenium <4.1 ug/L 4.1 1 12/03/2312:45 12/11/2319:34 7782-49-2 Silver <0.49 ug/L 0.49 1 12/03/2312:45 12/11/2319:34 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury <0.12 ug/L 0.12 1 12/11/23 10:23 12/12/23 09:40 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone <5.1 ug/L 5.1 1 12/07/23 07:28 67-64-1 Acrylonitrile <1.8 ug/L 1.8 1 12/07/23 07:28 107-13-1 Benzene 2.2 ug/L 0.34 1 12/07/23 07:28 71-43-2 Bromochloromethane <0.47 ug/L 0.47 1 12/07/23 07:28 74-97-5 Bromodichloromethane <0.31 ug/L 0.31 1 12/07/23 07:28 75-27-4 Bromoform <0.34 ug/L 0.34 1 12/07/23 07:28 75-25-2 v2 Bromomethane <1.7 ug/L 1.7 1 12/07/23 07:28 74-83-9 v2 2-Butanone (MEK) <4.0 ug/L 4.0 1 12/07/23 07:28 78-93-3 Carbon disulfide <0.36 ug/L 0.36 1 12/07/23 07:28 75-15-0 Carbon tetrachloride <0.33 ug/L 0.33 1 12/07/23 07:28 56-23-5 Chlorobenzene 3.1 ug/L 0.28 1 12/07/23 07:28 108-90-7 Chloroethane 12.1 ug/L 0.65 1 12/07/23 07:28 75-00-3 Chloroform <0.43 ug/L 0.43 1 12/07/23 07:28 67-66-3 Chloromethane <0.54 ug/L 0.54 1 12/07/23 07:28 74-87-3 1,2-Dibromo-3-chloropropane <0.34 ug/L 0.34 1 12/07/23 07:28 96-12-8 Dibromochloromethane <0.36 ug/L 0.36 1 12/07/23 07:28 124-48-1 1,2-Dibromoethane (EDB) <0.27 ug/L 0.27 1 12/07/23 07:28 106-93-4 Dibromomethane <0.39 ug/L 0.39 1 12/07/23 07:28 74-95-3 1,2-Dichlorobenzene <0.34 ug/L 0.34 1 12/07/23 07:28 95-50-1 1,4-Dichlorobenzene <0.33 ug/L 0.33 1 12/07/23 07:28 106-46-7 trans-1,4-Dichloro-2-butene <0.56 ug/L 0.56 1 12/07/23 07:28 110-57-6 1,1-Dichloroethane 44.9 ug/L 0.37 1 12/07/23 07:28 75-34-3 1,2-Dichloroethane 0.32 ug/L 0.32 1 12/07/23 07:28 107-06-2 1,1-Dichloroethene 0.35 ug/L 0.35 1 12/07/23 07:28 75-35-4 cis-1,2-Dichloroethene 6.0 ug/L 0.38 1 12/07/23 07:28 156-59-2 trans-1,2-Dichloroethene <0.40 ug/L 0.40 1 12/07/23 07:28 156-60-5 1,2-Dichloropropane <0.36 ug/L 0.36 1 12/07/23 07:28 78-87-5 cis-1,3-Dichloropropene <0.36 ug/L 0.36 1 12/07/23 07:28 10061-01-5 trans- 1,3-Dichloropropene <0.36 ug/L 0.36 1 12/07/23 07:28 10061-02-6 Ethylbenzene <0.30 ug/L 0.30 1 12/07/23 07:28 100-41-4 2-Hexanone <0.48 ug/L 0.48 1 12/07/23 07:28 591-78-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Sample: 8102-MW-1 Lab ID: 92700988005 Collected: 11/30/23 11:40 Received: 11/30/23 14:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/12/2023 05:36 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte <9.7 ug/L 12.7 ug/L <2.7 ug/L <0.29 ug/L <0.31 ug/L <0.22 ug/L <0.29 ug/L <0.24 ug/L <0.33 ug/L <0.32 ug/L <0.38 ug/L <0.30 ug/L <0.26 ug/L <1.3 ug/L <0.39 ug/L 3.7 ug/L <0.71 ug/L 3.7 ug/L 97 % 118 % 95 % Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte <0.86 ug/L 94 % 97 % 9.7 1 12/07/23 07:28 74-88-4 2.0 1 12/07/23 07:28 75-09-2 2.7 1 12/07/23 07:28 108-10-1 0.29 1 12/07/23 07:28 100-42-5 0.31 1 12/07/23 07:28 630-20-6 0.22 1 12/07/23 07:28 79-34-5 0.29 1 12/07/23 07:28 127-18-4 0.24 1 12/07/23 07:28 108-88-3 0.33 1 12/07/23 07:28 71-55-6 0.32 1 12/07/23 07:28 79-00-5 0.38 1 12/07/23 07:28 79-01-6 0.30 1 12/07/23 07:28 75-69-4 0.26 1 12/07/23 07:28 96-18-4 1.3 1 12/07/23 07:28 108-05-4 0.39 1 12/07/23 07:28 75-01-4 0.34 1 12/07/23 07:28 1330-20-7 0.71 1 12/07/23 07:28 179601-23-1 0.34 1 12/07/23 07:28 95-47-6 70-130 1 70-130 1 70-130 1 67-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/07/23 07:28 460-00-4 12/07/23 07:28 17060-07-0 12/07/23 07:28 2037-26-5 I L��LIYa%��LilIC3 �I [CAI ��C�;S QI 12/02/23 03:13 17060-07-0 12/02/23 03:13 2037-26-5 Page 14 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Sample: 8102-MW-2A Lab ID: 92700988006 Collected: 11/30/23 12:00 Received: 11/30/23 14:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic 16.2 ug/L 2.5 1 12/03/2312:45 12/11/2319:37 7440-38-2 Barium 134 ug/L 0.79 1 12/03/2312:45 12/11/2319:37 7440-39-3 Cadmium <0.29 ug/L 0.29 1 12/03/2312:45 12/11/2319:37 7440-43-9 Chromium 0.63 ug/L 0.63 1 12/03/2312:45 12/11/2319:37 7440-47-3 Lead <1.4 ug/L 1.4 1 12/03/2312:45 12/11/2319:37 7439-92-1 Selenium <4.1 ug/L 4.1 1 12/03/2312:45 12/11/2319:37 7782-49-2 Silver <0.49 ug/L 0.49 1 12/03/2312:45 12/11/2319:37 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury <0.12 ug/L 0.12 1 12/11/23 10:23 12/12/23 09:47 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone <5.1 ug/L 5.1 1 12/07/23 07:46 67-64-1 Acrylonitrile <1.8 ug/L 1.8 1 12/07/23 07:46 107-13-1 Benzene 0.34 ug/L 0.34 1 12/07/23 07:46 71-43-2 Bromochloromethane <0.47 ug/L 0.47 1 12/07/23 07:46 74-97-5 Bromodichloromethane <0.31 ug/L 0.31 1 12/07/23 07:46 75-27-4 Bromoform <0.34 ug/L 0.34 1 12/07/23 07:46 75-25-2 v2 Bromomethane <1.7 ug/L 1.7 1 12/07/23 07:46 74-83-9 v2 2-Butanone (MEK) <4.0 ug/L 4.0 1 12/07/23 07:46 78-93-3 Carbon disulfide <0.36 ug/L 0.36 1 12/07/23 07:46 75-15-0 Carbon tetrachloride <0.33 ug/L 0.33 1 12/07/23 07:46 56-23-5 Chlorobenzene 5.8 ug/L 0.28 1 12/07/23 07:46 108-90-7 Chloroethane 0.65 ug/L 0.65 1 12/07/23 07:46 75-00-3 Chloroform <0.43 ug/L 0.43 1 12/07/23 07:46 67-66-3 Chloromethane <0.54 ug/L 0.54 1 12/07/23 07:46 74-87-3 1,2-Dibromo-3-chloropropane <0.34 ug/L 0.34 1 12/07/23 07:46 96-12-8 Dibromochloromethane <0.36 ug/L 0.36 1 12/07/23 07:46 124-48-1 1,2-Dibromoethane (EDB) <0.27 ug/L 0.27 1 12/07/23 07:46 106-93-4 Dibromomethane <0.39 ug/L 0.39 1 12/07/23 07:46 74-95-3 1,2-Dichlorobenzene <0.34 ug/L 0.34 1 12/07/23 07:46 95-50-1 1,4-Dichlorobenzene 1.7 ug/L 0.33 1 12/07/23 07:46 106-46-7 trans-1,4-Dichloro-2-butene <0.56 ug/L 0.56 1 12/07/23 07:46 110-57-6 1,1-Dichloroethane <0.37 ug/L 0.37 1 12/07/23 07:46 75-34-3 1,2-Dichloroethane <0.32 ug/L 0.32 1 12/07/23 07:46 107-06-2 1,1-Dichloroethene <0.35 ug/L 0.35 1 12/07/23 07:46 75-35-4 cis-1,2-Dichloroethene 0.38 ug/L 0.38 1 12/07/23 07:46 156-59-2 trans-1,2-Dichloroethene <0.40 ug/L 0.40 1 12/07/23 07:46 156-60-5 1,2-Dichloropropane <0.36 ug/L 0.36 1 12/07/23 07:46 78-87-5 cis-1,3-Dichloropropene <0.36 ug/L 0.36 1 12/07/23 07:46 10061-01-5 trans- 1,3-Dichloropropene <0.36 ug/L 0.36 1 12/07/23 07:46 10061-02-6 Ethylbenzene <0.30 ug/L 0.30 1 12/07/23 07:46 100-41-4 2-Hexanone <0.48 ug/L 0.48 1 12/07/23 07:46 591-78-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Sample: 8102-MW-2A Lab ID: 92700988006 Collected: 11/30/23 12:00 Received: 11/30/23 14:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/12/2023 05:36 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte <9.7 ug/L <2.0 ug/L <2.7 ug/L <0.29 ug/L <0.31 ug/L <0.22 ug/L <0.29 ug/L <0.24 ug/L <0.33 ug/L <0.32 ug/L <0.38 ug/L <0.30 ug/L <0.26 ug/L <1.3 ug/L <0.39 ug/L <0.34 ug/L <0.71 ug/L <0.34 ug/L 98 % 116 % 97 % Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 13.6 ug/L 95 % 99 % 9.7 1 12/07/23 07:46 74-88-4 2.0 1 12/07/23 07:46 75-09-2 2.7 1 12/07/23 07:46 108-10-1 0.29 1 12/07/23 07:46 100-42-5 0.31 1 12/07/23 07:46 630-20-6 0.22 1 12/07/23 07:46 79-34-5 0.29 1 12/07/23 07:46 127-18-4 0.24 1 12/07/23 07:46 108-88-3 0.33 1 12/07/23 07:46 71-55-6 0.32 1 12/07/23 07:46 79-00-5 0.38 1 12/07/23 07:46 79-01-6 0.30 1 12/07/23 07:46 75-69-4 0.26 1 12/07/23 07:46 96-18-4 1.3 1 12/07/23 07:46 108-05-4 0.39 1 12/07/23 07:46 75-01-4 0.34 1 12/07/23 07:46 1330-20-7 0.71 1 12/07/23 07:46 179601-23-1 0.34 1 12/07/23 07:46 95-47-6 70-130 1 70-130 1 70-130 1 67-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/07/23 07:46 460-00-4 12/07/23 07:46 17060-07-0 12/07/23 07:46 2037-26-5 I L��LIYa%��LilIC3 [GI.' 1 <I ��C�;S QI 12/02/23 03:35 17060-07-0 12/02/23 03:35 2037-26-5 Page 16 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Sample: 8102-MW-4A Lab ID: 92700988007 Collected: 11/30/23 10:35 Received: 11/30/23 14:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic <2.5 ug/L 2.5 1 12/03/2312:45 12/11/2319:40 7440-38-2 Barium 33.0 ug/L 0.79 1 12/03/2312:45 12/11/2319:40 7440-39-3 Cadmium <0.29 ug/L 0.29 1 12/03/2312:45 12/11/2319:40 7440-43-9 Chromium 0.63 ug/L 0.63 1 12/03/2312:45 12/11/2319:40 7440-47-3 Lead <1.4 ug/L 1.4 1 12/03/2312:45 12/11/2319:40 7439-92-1 Selenium <4.1 ug/L 4.1 1 12/03/2312:45 12/11/2319:40 7782-49-2 Silver <0.49 ug/L 0.49 1 12/03/2312:45 12/11/2319:40 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury 0.12 ug/L 0.12 1 12/11/23 10:23 12/12/23 09:49 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone <5.1 ug/L 5.1 1 12/07/23 08:04 67-64-1 Acrylonitrile <1.8 ug/L 1.8 1 12/07/23 08:04 107-13-1 Benzene <0.34 ug/L 0.34 1 12/07/23 08:04 71-43-2 Bromochloromethane <0.47 ug/L 0.47 1 12/07/23 08:04 74-97-5 Bromodichloromethane <0.31 ug/L 0.31 1 12/07/23 08:04 75-27-4 Bromoform <0.34 ug/L 0.34 1 12/07/23 08:04 75-25-2 v2 Bromomethane <1.7 ug/L 1.7 1 12/07/23 08:04 74-83-9 v2 2-Butanone (MEK) <4.0 ug/L 4.0 1 12/07/23 08:04 78-93-3 Carbon disulfide <0.36 ug/L 0.36 1 12/07/23 08:04 75-15-0 Carbon tetrachloride <0.33 ug/L 0.33 1 12/07/23 08:04 56-23-5 Chlorobenzene <0.28 ug/L 0.28 1 12/07/23 08:04 108-90-7 Chloroethane <0.65 ug/L 0.65 1 12/07/23 08:04 75-00-3 Chloroform <0.43 ug/L 0.43 1 12/07/23 08:04 67-66-3 Chloromethane <0.54 ug/L 0.54 1 12/07/23 08:04 74-87-3 1,2-Dibromo-3-chloropropane <0.34 ug/L 0.34 1 12/07/23 08:04 96-12-8 Dibromochloromethane <0.36 ug/L 0.36 1 12/07/23 08:04 124-48-1 1,2-Dibromoethane (EDB) <0.27 ug/L 0.27 1 12/07/23 08:04 106-93-4 Dibromomethane <0.39 ug/L 0.39 1 12/07/23 08:04 74-95-3 1,2-Dichlorobenzene <0.34 ug/L 0.34 1 12/07/23 08:04 95-50-1 1,4-Dichlorobenzene <0.33 ug/L 0.33 1 12/07/23 08:04 106-46-7 trans-1,4-Dichloro-2-butene <0.56 ug/L 0.56 1 12/07/23 08:04 110-57-6 1,1-Dichloroethane <0.37 ug/L 0.37 1 12/07/23 08:04 75-34-3 1,2-Dichloroethane <0.32 ug/L 0.32 1 12/07/23 08:04 107-06-2 1,1-Dichloroethene <0.35 ug/L 0.35 1 12/07/23 08:04 75-35-4 cis-1,2-Dichloroethene <0.38 ug/L 0.38 1 12/07/23 08:04 156-59-2 trans-1,2-Dichloroethene <0.40 ug/L 0.40 1 12/07/23 08:04 156-60-5 1,2-Dichloropropane <0.36 ug/L 0.36 1 12/07/23 08:04 78-87-5 cis-1,3-Dichloropropene <0.36 ug/L 0.36 1 12/07/23 08:04 10061-01-5 trans- 1,3-Dichloropropene <0.36 ug/L 0.36 1 12/07/23 08:04 10061-02-6 Ethylbenzene <0.30 ug/L 0.30 1 12/07/23 08:04 100-41-4 2-Hexanone <0.48 ug/L 0.48 1 12/07/23 08:04 591-78-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Sample: 8102-MW-4A Lab ID: 92700988007 Collected: 11/30/23 10:35 Received: 11/30/23 14:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/12/2023 05:36 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte <9.7 ug/L <2.0 ug/L <2.7 ug/L <0.29 ug/L <0.31 ug/L <0.22 ug/L <0.29 ug/L <0.24 ug/L <0.33 ug/L <0.32 ug/L <0.38 ug/L <0.30 ug/L <0.26 ug/L <1.3 ug/L <0.39 ug/L <0.34 ug/L <0.71 ug/L <0.34 ug/L 98 % 118 % 93 % Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte <0.86 ug/L 95 % 100 % 9.7 1 12/07/23 08:04 74-88-4 2.0 1 12/07/23 08:04 75-09-2 2.7 1 12/07/23 08:04 108-10-1 0.29 1 12/07/23 08:04 100-42-5 0.31 1 12/07/23 08:04 630-20-6 0.22 1 12/07/23 08:04 79-34-5 0.29 1 12/07/23 08:04 127-18-4 0.24 1 12/07/23 08:04 108-88-3 0.33 1 12/07/23 08:04 71-55-6 0.32 1 12/07/23 08:04 79-00-5 0.38 1 12/07/23 08:04 79-01-6 0.30 1 12/07/23 08:04 75-69-4 0.26 1 12/07/23 08:04 96-18-4 1.3 1 12/07/23 08:04 108-05-4 0.39 1 12/07/23 08:04 75-01-4 0.34 1 12/07/23 08:04 1330-20-7 0.71 1 12/07/23 08:04 179601-23-1 0.34 1 12/07/23 08:04 95-47-6 70-130 1 70-130 1 70-130 1 67-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/07/23 08:04 460-00-4 12/07/23 08:04 17060-07-0 12/07/23 08:04 2037-26-5 i 108011aN9i11191 U.'1111111lipas4m 12/02/23 03:56 17060-07-0 12/02/23 03:56 2037-26-5 Page 18 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Sample: 8102-MW-5 Lab ID: 92700988008 Collected: 11/30/23 10:00 Received: 11/30/23 14:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic 2.5 ug/L 2.5 1 12/03/2312:45 12/11/2319:43 7440-38-2 Barium 174 ug/L 0.79 1 12/03/2312:45 12/11/2319:43 7440-39-3 Cadmium <0.29 ug/L 0.29 1 12/03/2312:45 12/11/2319:43 7440-43-9 Chromium 5.1 ug/L 0.63 1 12/03/2312:45 12/11/2319:43 7440-47-3 Lead <1.4 ug/L 1.4 1 12/03/2312:45 12/11/2319:43 7439-92-1 Selenium <4.1 ug/L 4.1 1 12/03/2312:45 12/11/2319:43 7782-49-2 Silver <0.49 ug/L 0.49 1 12/03/2312:45 12/11/2319:43 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury <0.12 ug/L 0.12 1 12/11/23 10:23 12/12/23 09:52 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone <5.1 ug/L 5.1 1 12/07/23 08:22 67-64-1 Acrylonitrile <1.8 ug/L 1.8 1 12/07/23 08:22 107-13-1 Benzene 0.34 ug/L 0.34 1 12/07/23 08:22 71-43-2 Bromochloromethane <0.47 ug/L 0.47 1 12/07/23 08:22 74-97-5 Bromodichloromethane <0.31 ug/L 0.31 1 12/07/23 08:22 75-27-4 Bromoform <0.34 ug/L 0.34 1 12/07/23 08:22 75-25-2 v2 Bromomethane <1.7 ug/L 1.7 1 12/07/23 08:22 74-83-9 v2 2-Butanone (MEK) <4.0 ug/L 4.0 1 12/07/23 08:22 78-93-3 Carbon disulfide <0.36 ug/L 0.36 1 12/07/23 08:22 75-15-0 Carbon tetrachloride <0.33 ug/L 0.33 1 12/07/23 08:22 56-23-5 Chlorobenzene 1.8 ug/L 0.28 1 12/07/23 08:22 108-90-7 Chloroethane 1.6 ug/L 0.65 1 12/07/23 08:22 75-00-3 Chloroform <0.43 ug/L 0.43 1 12/07/23 08:22 67-66-3 Chloromethane <0.54 ug/L 0.54 1 12/07/23 08:22 74-87-3 1,2-Dibromo-3-chloropropane <0.34 ug/L 0.34 1 12/07/23 08:22 96-12-8 Dibromochloromethane <0.36 ug/L 0.36 1 12/07/23 08:22 124-48-1 1,2-Dibromoethane (EDB) <0.27 ug/L 0.27 1 12/07/23 08:22 106-93-4 Dibromomethane <0.39 ug/L 0.39 1 12/07/23 08:22 74-95-3 1,2-Dichlorobenzene <0.34 ug/L 0.34 1 12/07/23 08:22 95-50-1 1,4-Dichlorobenzene 1.8 ug/L 0.33 1 12/07/23 08:22 106-46-7 trans-1,4-Dichloro-2-butene <0.56 ug/L 0.56 1 12/07/23 08:22 110-57-6 1,1-Dichloroethane 2.4 ug/L 0.37 1 12/07/23 08:22 75-34-3 1,2-Dichloroethane <0.32 ug/L 0.32 1 12/07/23 08:22 107-06-2 1,1-Dichloroethene <0.35 ug/L 0.35 1 12/07/23 08:22 75-35-4 cis-1,2-Dichloroethene 5.5 ug/L 0.38 1 12/07/23 08:22 156-59-2 trans-1,2-Dichloroethene <0.40 ug/L 0.40 1 12/07/23 08:22 156-60-5 1,2-Dichloropropane <0.36 ug/L 0.36 1 12/07/23 08:22 78-87-5 cis-1,3-Dichloropropene <0.36 ug/L 0.36 1 12/07/23 08:22 10061-01-5 trans- 1,3-Dichloropropene <0.36 ug/L 0.36 1 12/07/23 08:22 10061-02-6 Ethylbenzene <0.30 ug/L 0.30 1 12/07/23 08:22 100-41-4 2-Hexanone <0.48 ug/L 0.48 1 12/07/23 08:22 591-78-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Sample: 8102-MW-5 Lab ID: 92700988008 Collected: 11/30/23 10:00 Received: 11/30/23 14:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/12/2023 05:36 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte <9.7 ug/L <2.0 ug/L <2.7 ug/L <0.29 ug/L <0.31 ug/L <0.22 ug/L <0.29 ug/L <0.24 ug/L <0.33 ug/L <0.32 ug/L <0.38 ug/L <0.30 ug/L <0.26 ug/L <1.3 ug/L 0.39 ug/L <0.34 ug/L <0.71 ug/L <0.34 ug/L 97 % 119 % 96 % Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 20.1 ug/L 94 % 98 % 9.7 1 12/07/23 08:22 74-88-4 2.0 1 12/07/23 08:22 75-09-2 2.7 1 12/07/23 08:22 108-10-1 0.29 1 12/07/23 08:22 100-42-5 0.31 1 12/07/23 08:22 630-20-6 0.22 1 12/07/23 08:22 79-34-5 0.29 1 12/07/23 08:22 127-18-4 0.24 1 12/07/23 08:22 108-88-3 0.33 1 12/07/23 08:22 71-55-6 0.32 1 12/07/23 08:22 79-00-5 0.38 1 12/07/23 08:22 79-01-6 0.30 1 12/07/23 08:22 75-69-4 0.26 1 12/07/23 08:22 96-18-4 1.3 1 12/07/23 08:22 108-05-4 0.39 1 12/07/23 08:22 75-01-4 0.34 1 12/07/23 08:22 1330-20-7 0.71 1 12/07/23 08:22 179601-23-1 0.34 1 12/07/23 08:22 95-47-6 70-130 1 70-130 1 70-130 1 67-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/07/23 08:22 460-00-4 12/07/23 08:22 17060-07-0 12/07/23 08:22 2037-26-5 if080111P9I11LSfirtif as4Qi 12/02/23 04:17 17060-07-0 12/02/23 04:17 2037-26-5 Page 20 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Sample: 8102-MW-6 Lab ID: 92700988009 Collected: 11/30/23 11:50 Received: 11/30/23 14:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic <2.5 ug/L 2.5 1 12/03/2312:45 12/11/2319:46 7440-38-2 Barium 154 ug/L 0.79 1 12/03/2312:45 12/11/2319:46 7440-39-3 Cadmium 0.29 ug/L 0.29 1 12/03/2312:45 12/11/2319:46 7440-43-9 Chromium 0.63 ug/L 0.63 1 12/03/2312:45 12/11/2319:46 7440-47-3 Lead <1.4 ug/L 1.4 1 12/03/2312:45 12/11/2319:46 7439-92-1 Selenium <4.1 ug/L 4.1 1 12/03/2312:45 12/11/2319:46 7782-49-2 Silver <0.49 ug/L 0.49 1 12/03/2312:45 12/11/2319:46 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury <0.12 ug/L 0.12 1 12/11/23 10:23 12/12/23 09:54 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone <5.1 ug/L 5.1 1 12/07/23 08:40 67-64-1 Acrylonitrile <1.8 ug/L 1.8 1 12/07/23 08:40 107-13-1 Benzene 1.6 ug/L 0.34 1 12/07/23 08:40 71-43-2 Bromochloromethane <0.47 ug/L 0.47 1 12/07/23 08:40 74-97-5 Bromodichloromethane <0.31 ug/L 0.31 1 12/07/23 08:40 75-27-4 Bromoform <0.34 ug/L 0.34 1 12/07/23 08:40 75-25-2 v2 Bromomethane <1.7 ug/L 1.7 1 12/07/23 08:40 74-83-9 v2 2-Butanone (MEK) <4.0 ug/L 4.0 1 12/07/23 08:40 78-93-3 Carbon disulfide <0.36 ug/L 0.36 1 12/07/23 08:40 75-15-0 Carbon tetrachloride <0.33 ug/L 0.33 1 12/07/23 08:40 56-23-5 Chlorobenzene 3.4 ug/L 0.28 1 12/07/23 08:40 108-90-7 Chloroethane 0.65 ug/L 0.65 1 12/07/23 08:40 75-00-3 Chloroform <0.43 ug/L 0.43 1 12/07/23 08:40 67-66-3 Chloromethane <0.54 ug/L 0.54 1 12/07/23 08:40 74-87-3 1,2-Dibromo-3-chloropropane <0.34 ug/L 0.34 1 12/07/23 08:40 96-12-8 Dibromochloromethane <0.36 ug/L 0.36 1 12/07/23 08:40 124-48-1 1,2-Dibromoethane (EDB) <0.27 ug/L 0.27 1 12/07/23 08:40 106-93-4 Dibromomethane <0.39 ug/L 0.39 1 12/07/23 08:40 74-95-3 1,2-Dichlorobenzene <0.34 ug/L 0.34 1 12/07/23 08:40 95-50-1 1,4-Dichlorobenzene 1.8 ug/L 0.33 1 12/07/23 08:40 106-46-7 trans-1,4-Dichloro-2-butene <0.56 ug/L 0.56 1 12/07/23 08:40 110-57-6 1,1-Dichloroethane 0.37 ug/L 0.37 1 12/07/23 08:40 75-34-3 1,2-Dichloroethane <0.32 ug/L 0.32 1 12/07/23 08:40 107-06-2 1,1-Dichloroethene <0.35 ug/L 0.35 1 12/07/23 08:40 75-35-4 cis-1,2-Dichloroethene 1.0 ug/L 0.38 1 12/07/23 08:40 156-59-2 trans-1,2-Dichloroethene <0.40 ug/L 0.40 1 12/07/23 08:40 156-60-5 1,2-Dichloropropane <0.36 ug/L 0.36 1 12/07/23 08:40 78-87-5 cis-1,3-Dichloropropene <0.36 ug/L 0.36 1 12/07/23 08:40 10061-01-5 trans- 1,3-Dichloropropene <0.36 ug/L 0.36 1 12/07/23 08:40 10061-02-6 Ethylbenzene <0.30 ug/L 0.30 1 12/07/23 08:40 100-41-4 2-Hexanone <0.48 ug/L 0.48 1 12/07/23 08:40 591-78-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Sample: 8102-MW-6 Lab ID: 92700988009 Collected: 11/30/23 11:50 Received: 11/30/23 14:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/12/2023 05:36 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte <9.7 ug/L <2.0 ug/L <2.7 ug/L <0.29 ug/L <0.31 ug/L <0.22 ug/L <0.29 ug/L <0.24 ug/L <0.33 ug/L <0.32 ug/L <0.38 ug/L <0.30 ug/L <0.26 ug/L <1.3 ug/L <0.39 ug/L <0.34 ug/L <0.71 ug/L <0.34 ug/L 97 % 113 % 97 % Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 38.6 ug/L 94 % 98 % 9.7 1 12/07/23 08:40 74-88-4 2.0 1 12/07/23 08:40 75-09-2 2.7 1 12/07/23 08:40 108-10-1 0.29 1 12/07/23 08:40 100-42-5 0.31 1 12/07/23 08:40 630-20-6 0.22 1 12/07/23 08:40 79-34-5 0.29 1 12/07/23 08:40 127-18-4 0.24 1 12/07/23 08:40 108-88-3 0.33 1 12/07/23 08:40 71-55-6 0.32 1 12/07/23 08:40 79-00-5 0.38 1 12/07/23 08:40 79-01-6 0.30 1 12/07/23 08:40 75-69-4 0.26 1 12/07/23 08:40 96-18-4 1.3 1 12/07/23 08:40 108-05-4 0.39 1 12/07/23 08:40 75-01-4 0.34 1 12/07/23 08:40 1330-20-7 0.71 1 12/07/23 08:40 179601-23-1 0.34 1 12/07/23 08:40 95-47-6 70-130 1 70-130 1 70-130 1 67-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/07/23 08:40 460-00-4 12/07/23 08:40 17060-07-0 12/07/23 08:40 2037-26-5 12/02/23 04:39 17060-07-0 12/02/23 04:39 2037-26-5 Page 22 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Sample: 8102-MW-7 Lab ID: 92700988010 Collected: 11/30/23 11:30 Received: 11/30/23 14:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic <2.5 ug/L 2.5 1 12/03/2312:45 12/11/2319:49 7440-38-2 Barium 54.2 ug/L 0.79 1 12/03/2312:45 12/11/2319:49 7440-39-3 Cadmium <0.29 ug/L 0.29 1 12/03/2312:45 12/11/2319:49 7440-43-9 Chromium <0.63 ug/L 0.63 1 12/03/2312:45 12/11/2319:49 7440-47-3 Lead <1.4 ug/L 1.4 1 12/03/2312:45 12/11/2319:49 7439-92-1 Selenium <4.1 ug/L 4.1 1 12/03/2312:45 12/11/2319:49 7782-49-2 Silver <0.49 ug/L 0.49 1 12/03/2312:45 12/11/2319:49 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury <0.12 ug/L 0.12 1 12/11/23 10:23 12/12/23 09:56 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone <5.1 ug/L 5.1 1 12/07/23 08:58 67-64-1 Acrylonitrile <1.8 ug/L 1.8 1 12/07/23 08:58 107-13-1 Benzene 0.34 ug/L 0.34 1 12/07/23 08:58 71-43-2 Bromochloromethane <0.47 ug/L 0.47 1 12/07/23 08:58 74-97-5 Bromodichloromethane <0.31 ug/L 0.31 1 12/07/23 08:58 75-27-4 Bromoform <0.34 ug/L 0.34 1 12/07/23 08:58 75-25-2 v2 Bromomethane <1.7 ug/L 1.7 1 12/07/23 08:58 74-83-9 v2 2-Butanone (MEK) <4.0 ug/L 4.0 1 12/07/23 08:58 78-93-3 Carbon disulfide <0.36 ug/L 0.36 1 12/07/23 08:58 75-15-0 Carbon tetrachloride <0.33 ug/L 0.33 1 12/07/23 08:58 56-23-5 Chlorobenzene 1.6 ug/L 0.28 1 12/07/23 08:58 108-90-7 Chloroethane <0.65 ug/L 0.65 1 12/07/23 08:58 75-00-3 Chloroform <0.43 ug/L 0.43 1 12/07/23 08:58 67-66-3 Chloromethane <0.54 ug/L 0.54 1 12/07/23 08:58 74-87-3 1,2-Dibromo-3-chloropropane <0.34 ug/L 0.34 1 12/07/23 08:58 96-12-8 Dibromochloromethane <0.36 ug/L 0.36 1 12/07/23 08:58 124-48-1 1,2-Dibromoethane (EDB) <0.27 ug/L 0.27 1 12/07/23 08:58 106-93-4 Dibromomethane <0.39 ug/L 0.39 1 12/07/23 08:58 74-95-3 1,2-Dichlorobenzene <0.34 ug/L 0.34 1 12/07/23 08:58 95-50-1 1,4-Dichlorobenzene 0.33 ug/L 0.33 1 12/07/23 08:58 106-46-7 trans-1,4-Dichloro-2-butene <0.56 ug/L 0.56 1 12/07/23 08:58 110-57-6 1,1-Dichloroethane <0.37 ug/L 0.37 1 12/07/23 08:58 75-34-3 1,2-Dichloroethane <0.32 ug/L 0.32 1 12/07/23 08:58 107-06-2 1,1-Dichloroethene <0.35 ug/L 0.35 1 12/07/23 08:58 75-35-4 cis-1,2-Dichloroethene 0.38 ug/L 0.38 1 12/07/23 08:58 156-59-2 trans-1,2-Dichloroethene <0.40 ug/L 0.40 1 12/07/23 08:58 156-60-5 1,2-Dichloropropane <0.36 ug/L 0.36 1 12/07/23 08:58 78-87-5 cis-1,3-Dichloropropene <0.36 ug/L 0.36 1 12/07/23 08:58 10061-01-5 trans- 1,3-Dichloropropene <0.36 ug/L 0.36 1 12/07/23 08:58 10061-02-6 Ethylbenzene <0.30 ug/L 0.30 1 12/07/23 08:58 100-41-4 2-Hexanone <0.48 ug/L 0.48 1 12/07/23 08:58 591-78-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Sample: 8102-MW-7 Lab ID: 92700988010 Collected: 11/30/23 11:30 Received: 11/30/23 14:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/12/2023 05:36 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte <9.7 ug/L <2.0 ug/L <2.7 ug/L <0.29 ug/L <0.31 ug/L <0.22 ug/L <0.29 ug/L <0.24 ug/L <0.33 ug/L <0.32 ug/L <0.38 ug/L <0.30 ug/L <0.26 ug/L <1.3 ug/L <0.39 ug/L <0.34 ug/L <0.71 ug/L <0.34 ug/L 96 % 109 % 93 % Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 17.4 ug/L 95 % 99 % 9.7 1 12/07/23 08:58 74-88-4 2.0 1 12/07/23 08:58 75-09-2 2.7 1 12/07/23 08:58 108-10-1 0.29 1 12/07/23 08:58 100-42-5 0.31 1 12/07/23 08:58 630-20-6 0.22 1 12/07/23 08:58 79-34-5 0.29 1 12/07/23 08:58 127-18-4 0.24 1 12/07/23 08:58 108-88-3 0.33 1 12/07/23 08:58 71-55-6 0.32 1 12/07/23 08:58 79-00-5 0.38 1 12/07/23 08:58 79-01-6 0.30 1 12/07/23 08:58 75-69-4 0.26 1 12/07/23 08:58 96-18-4 1.3 1 12/07/23 08:58 108-05-4 0.39 1 12/07/23 08:58 75-01-4 0.34 1 12/07/23 08:58 1330-20-7 0.71 1 12/07/23 08:58 179601-23-1 0.34 1 12/07/23 08:58 95-47-6 70-130 1 70-130 1 70-130 1 67-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/07/23 08:58 460-00-4 12/07/23 08:58 17060-07-0 12/07/23 08:58 2037-26-5 I L��LIYa%��Lili.' � [IZIfI ��C�;S QI 12/02/23 05:00 17060-07-0 12/02/23 05:00 2037-26-5 Page 24 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Sample: 8102-MW-8 Lab ID: 92700988011 Collected: 11/30/23 10:35 Received: 11/30/23 14:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic <2.5 ug/L 2.5 1 12/03/2312:45 12/11/2319:57 7440-38-2 Barium 103 ug/L 0.79 1 12/03/2312:45 12/11/2319:57 7440-39-3 Cadmium <0.29 ug/L 0.29 1 12/03/2312:45 12/11/2319:57 7440-43-9 Chromium <0.63 ug/L 0.63 1 12/03/2312:45 12/11/2319:57 7440-47-3 Lead <1.4 ug/L 1.4 1 12/03/2312:45 12/11/2319:57 7439-92-1 Selenium <4.1 ug/L 4.1 1 12/03/2312:45 12/11/2319:57 7782-49-2 Silver <0.49 ug/L 0.49 1 12/03/2312:45 12/11/2319:57 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury 1.6 ug/L 0.12 1 12/11/2310:23 12/12/2310:03 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone <5.1 ug/L 5.1 1 12/07/23 09:16 67-64-1 Acrylonitrile <1.8 ug/L 1.8 1 12/07/23 09:16 107-13-1 Benzene <0.34 ug/L 0.34 1 12/07/23 09:16 71-43-2 Bromochloromethane <0.47 ug/L 0.47 1 12/07/23 09:16 74-97-5 Bromodichloromethane <0.31 ug/L 0.31 1 12/07/23 09:16 75-27-4 Bromoform <0.34 ug/L 0.34 1 12/07/23 09:16 75-25-2 v2 Bromomethane <1.7 ug/L 1.7 1 12/07/23 09:16 74-83-9 v2 2-Butanone (MEK) <4.0 ug/L 4.0 1 12/07/23 09:16 78-93-3 Carbon disulfide <0.36 ug/L 0.36 1 12/07/23 09:16 75-15-0 Carbon tetrachloride <0.33 ug/L 0.33 1 12/07/23 09:16 56-23-5 Chlorobenzene <0.28 ug/L 0.28 1 12/07/23 09:16 108-90-7 Chloroethane <0.65 ug/L 0.65 1 12/07/23 09:16 75-00-3 Chloroform <0.43 ug/L 0.43 1 12/07/23 09:16 67-66-3 Chloromethane <0.54 ug/L 0.54 1 12/07/23 09:16 74-87-3 1,2-Dibromo-3-chloropropane <0.34 ug/L 0.34 1 12/07/23 09:16 96-12-8 Dibromochloromethane <0.36 ug/L 0.36 1 12/07/23 09:16 124-48-1 1,2-Dibromoethane (EDB) <0.27 ug/L 0.27 1 12/07/23 09:16 106-93-4 Dibromomethane <0.39 ug/L 0.39 1 12/07/23 09:16 74-95-3 1,2-Dichlorobenzene <0.34 ug/L 0.34 1 12/07/23 09:16 95-50-1 1,4-Dichlorobenzene <0.33 ug/L 0.33 1 12/07/23 09:16 106-46-7 trans-1,4-Dichloro-2-butene <0.56 ug/L 0.56 1 12/07/23 09:16 110-57-6 1,1-Dichloroethane 1.5 ug/L 0.37 1 12/07/23 09:16 75-34-3 1,2-Dichloroethane <0.32 ug/L 0.32 1 12/07/23 09:16 107-06-2 1,1-Dichloroethene <0.35 ug/L 0.35 1 12/07/23 09:16 75-35-4 cis-1,2-Dichloroethene <0.38 ug/L 0.38 1 12/07/23 09:16 156-59-2 trans-1,2-Dichloroethene <0.40 ug/L 0.40 1 12/07/23 09:16 156-60-5 1,2-Dichloropropane <0.36 ug/L 0.36 1 12/07/23 09:16 78-87-5 cis-1,3-Dichloropropene <0.36 ug/L 0.36 1 12/07/23 09:16 10061-01-5 trans- 1,3-Dichloropropene <0.36 ug/L 0.36 1 12/07/23 09:16 10061-02-6 Ethylbenzene <0.30 ug/L 0.30 1 12/07/23 09:16 100-41-4 2-Hexanone <0.48 ug/L 0.48 1 12/07/23 09:16 591-78-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Sample: 8102-MW-8 Lab ID: 92700988011 Collected: 11/30/23 10:35 Received: 11/30/23 14:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/12/2023 05:36 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte <9.7 ug/L <2.0 ug/L <2.7 ug/L <0.29 ug/L <0.31 ug/L <0.22 ug/L <0.29 ug/L <0.24 ug/L <0.33 ug/L <0.32 ug/L <0.38 ug/L <0.30 ug/L <0.26 ug/L <1.3 ug/L <0.39 ug/L <0.34 ug/L <0.71 ug/L <0.34 ug/L 98 % 121 % 96 % Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte <0.86 ug/L 93 % 99 % 9.7 1 12/07/23 09:16 74-88-4 2.0 1 12/07/23 09:16 75-09-2 2.7 1 12/07/23 09:16 108-10-1 0.29 1 12/07/23 09:16 100-42-5 0.31 1 12/07/23 09:16 630-20-6 0.22 1 12/07/23 09:16 79-34-5 0.29 1 12/07/23 09:16 127-18-4 0.24 1 12/07/23 09:16 108-88-3 0.33 1 12/07/23 09:16 71-55-6 0.32 1 12/07/23 09:16 79-00-5 0.38 1 12/07/23 09:16 79-01-6 0.30 1 12/07/23 09:16 75-69-4 0.26 1 12/07/23 09:16 96-18-4 1.3 1 12/07/23 09:16 108-05-4 0.39 1 12/07/23 09:16 75-01-4 0.34 1 12/07/23 09:16 1330-20-7 0.71 1 12/07/23 09:16 179601-23-1 0.34 1 12/07/23 09:16 95-47-6 70-130 1 70-130 1 70-130 1 67-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/07/23 09:16 460-00-4 12/07/23 09:16 17060-07-0 12/07/23 09:16 2037-26-5 12/02/23 05:22 17060-07-0 12/02/23 05:22 2037-26-5 Page 26 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Sample: 8102-SW-2 Lab ID: 92700988012 Collected: 11/30/23 10:20 Received: 11/30/23 14:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic <2.5 ug/L 2.5 1 12/03/23 12:45 12/11/23 20:00 7440-38-2 Barium 22.4 ug/L 0.79 1 12/03/23 12:45 12/11/23 20:00 7440-39-3 Cadmium <0.29 ug/L 0.29 1 12/03/23 12:45 12/11/23 20:00 7440-43-9 Chromium <0.63 ug/L 0.63 1 12/03/23 12:45 12/11/23 20:00 7440-47-3 Lead <1.4 ug/L 1.4 1 12/03/23 12:45 12/11/23 20:00 7439-92-1 Selenium <4.1 ug/L 4.1 1 12/03/23 12:45 12/11/23 20:00 7782-49-2 Silver <0.49 ug/L 0.49 1 12/03/23 12:45 12/11/23 20:00 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury <0.12 ug/L 0.12 1 12/11/2310:23 12/12/2310:05 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone <5.1 ug/L 5.1 1 12/07/23 09:34 67-64-1 Acrylonitrile <1.8 ug/L 1.8 1 12/07/23 09:34 107-13-1 Benzene <0.34 ug/L 0.34 1 12/07/23 09:34 71-43-2 Bromochloromethane <0.47 ug/L 0.47 1 12/07/23 09:34 74-97-5 Bromodichloromethane <0.31 ug/L 0.31 1 12/07/23 09:34 75-27-4 Bromoform <0.34 ug/L 0.34 1 12/07/23 09:34 75-25-2 v2 Bromomethane <1.7 ug/L 1.7 1 12/07/23 09:34 74-83-9 v2 2-Butanone (MEK) <4.0 ug/L 4.0 1 12/07/23 09:34 78-93-3 Carbon disulfide <0.36 ug/L 0.36 1 12/07/23 09:34 75-15-0 Carbon tetrachloride <0.33 ug/L 0.33 1 12/07/23 09:34 56-23-5 Chlorobenzene <0.28 ug/L 0.28 1 12/07/23 09:34 108-90-7 Chloroethane <0.65 ug/L 0.65 1 12/07/23 09:34 75-00-3 Chloroform <0.43 ug/L 0.43 1 12/07/23 09:34 67-66-3 Chloromethane <0.54 ug/L 0.54 1 12/07/23 09:34 74-87-3 1,2-Dibromo-3-chloropropane <0.34 ug/L 0.34 1 12/07/23 09:34 96-12-8 Dibromochloromethane <0.36 ug/L 0.36 1 12/07/23 09:34 124-48-1 1,2-Dibromoethane (EDB) <0.27 ug/L 0.27 1 12/07/23 09:34 106-93-4 Dibromomethane <0.39 ug/L 0.39 1 12/07/23 09:34 74-95-3 1,2-Dichlorobenzene <0.34 ug/L 0.34 1 12/07/23 09:34 95-50-1 1,4-Dichlorobenzene <0.33 ug/L 0.33 1 12/07/23 09:34 106-46-7 trans-1,4-Dichloro-2-butene <0.56 ug/L 0.56 1 12/07/23 09:34 110-57-6 1,1-Dichloroethane <0.37 ug/L 0.37 1 12/07/23 09:34 75-34-3 1,2-Dichloroethane <0.32 ug/L 0.32 1 12/07/23 09:34 107-06-2 1,1-Dichloroethene <0.35 ug/L 0.35 1 12/07/23 09:34 75-35-4 cis-1,2-Dichloroethene <0.38 ug/L 0.38 1 12/07/23 09:34 156-59-2 trans-1,2-Dichloroethene <0.40 ug/L 0.40 1 12/07/23 09:34 156-60-5 1,2-Dichloropropane <0.36 ug/L 0.36 1 12/07/23 09:34 78-87-5 cis-1,3-Dichloropropene <0.36 ug/L 0.36 1 12/07/23 09:34 10061-01-5 trans- 1,3-Dichloropropene <0.36 ug/L 0.36 1 12/07/23 09:34 10061-02-6 Ethylbenzene <0.30 ug/L 0.30 1 12/07/23 09:34 100-41-4 2-Hexanone <0.48 ug/L 0.48 1 12/07/23 09:34 591-78-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 Sample: 8102-SW-2 Lab ID: 92700988012 Collected: 11/30/23 10:20 Received: 11/30/23 14:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/12/2023 05:36 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte <9.7 ug/L <2.0 ug/L <2.7 ug/L <0.29 ug/L <0.31 ug/L <0.22 ug/L <0.29 ug/L <0.24 ug/L <0.33 ug/L <0.32 ug/L <0.38 ug/L <0.30 ug/L <0.26 ug/L <1.3 ug/L <0.39 ug/L <0.34 ug/L <0.71 ug/L <0.34 ug/L 96 % 113 % 94 % Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 4.1 ug/L 95 % 100 % 9.7 1 12/07/23 09:34 74-88-4 2.0 1 12/07/23 09:34 75-09-2 2.7 1 12/07/23 09:34 108-10-1 0.29 1 12/07/23 09:34 100-42-5 0.31 1 12/07/23 09:34 630-20-6 0.22 1 12/07/23 09:34 79-34-5 0.29 1 12/07/23 09:34 127-18-4 0.24 1 12/07/23 09:34 108-88-3 0.33 1 12/07/23 09:34 71-55-6 0.32 1 12/07/23 09:34 79-00-5 0.38 1 12/07/23 09:34 79-01-6 0.30 1 12/07/23 09:34 75-69-4 0.26 1 12/07/23 09:34 96-18-4 1.3 1 12/07/23 09:34 108-05-4 0.39 1 12/07/23 09:34 75-01-4 0.34 1 12/07/23 09:34 1330-20-7 0.71 1 12/07/23 09:34 179601-23-1 0.34 1 12/07/23 09:34 95-47-6 70-130 1 70-130 1 70-130 1 67-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/07/23 09:34 460-00-4 12/07/23 09:34 17060-07-0 12/07/23 09:34 2037-26-5 12/02/23 05:43 17060-07-0 12/02/23 05:43 2037-26-5 Page 28 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 QC Batch: 818212 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92700988001, 92700988002, 92700988003 METHOD BLANK: 4235301 Matrix: Water Associated Lab Samples: 92700988001, 92700988002, 92700988003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L <0.12 0.12 12/09/2311:49 LABORATORY CONTROL SAMPLE: 4235302 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.4 97 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4235303 4235304 MS MSD 92700857009 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Mercury ug/L ND 2.5 2.5 2.5 2.4 99 97 75-125 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 QC Batch: 818551 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92700988005, 92700988006, 92700988007, 92700988008, 92700988009, 92700988010, 92700988011, 92700988012 METHOD BLANK: 4237121 Matrix: Water Associated Lab Samples: 92700988005, 92700988006, 92700988007, 92700988008, 92700988009, 92700988010, 92700988011, 92700988012 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L <0.12 0.12 12/12/23 09:36 LABORATORY CONTROL SAMPLE: 4237122 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.6 106 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4237123 4237124 MS MSD 92700988005 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Mercury ug/L <0.12 2.5 2.5 2.2 2.6 87 105 75-125 19 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 QC Batch: 816930 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92700988001, 92700988002, 92700988003, 92700988005, 92700988006, 92700988007, 92700988008, 92700988009,92700988010,92700988011,92700988012 METHOD BLANK: 4228334 Matrix: Water Associated Lab Samples: 92700988001, 92700988002, 92700988003, 92700988005, 92700988006, 92700988007, 92700988008, 92700988009,92700988010,92700988011,92700988012 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Arsenic ug/L <2.5 2.5 12/11/2318:49 Barium ug/L <0.79 0.79 12/11/2318:49 Cadmium ug/L <0.29 0.29 12/11/2318:49 Chromium ug/L <0.63 0.63 12/11/2318:49 Lead ug/L <1.4 1.4 12/11 /23 18:49 Selenium ug/L <4.1 4.1 12/11/23 18:49 Silver ug/L <0.49 0.49 12/11/2318:49 LABORATORY CONTROL SAMPLE: Parameter 4228335 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Arsenic ug/L 500 485 97 80-120 Barium ug/L 500 497 99 80-120 Cadmium ug/L 500 489 98 80-120 Chromium ug/L 500 492 98 80-120 Lead ug/L 500 491 98 80-120 Selenium ug/L 500 477 95 80-120 Silver ug/L 250 244 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4228336 4228337 MS MSD 92700988001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Arsenic ug/L <2.5 500 500 522 508 104 102 75-125 3 Barium ug/L 36.3 500 500 551 494 103 92 75-125 11 Cadmium ug/L <0.29 500 500 524 509 105 102 75-125 3 Chromium ug/L <0.63 500 500 519 504 104 101 75-125 3 Lead ug/L <1.4 500 500 520 504 104 101 75-125 3 Selenium ug/L <4.1 500 500 531 510 106 102 75-125 4 Silver ug/L <0.49 250 250 257 249 103 100 75-125 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 QC Batch: 817172 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92700988001, 92700988002, 92700988003, 92700988004 METHOD BLANK: 4229391 Matrix: Water Associated Lab Samples: 92700988001, 92700988002, 92700988003, 92700988004 Blank Reporting Parameter Units Result Limit Analyzed 1,1,1,2-Tetrachloroethane ug/L <0.31 0.31 12/05/23 00:40 1,1,1-Trichloroethane ug/L <0.33 0.33 12/05/23 00:40 1,1,2,2-Tetrachloroethane ug/L <0.22 0.22 12/05/23 00:40 1,1,2-Trichloroethane ug/L <0.32 0.32 12/05/23 00:40 1,1-Dichloroethane ug/L <0.37 0.37 12/05/23 00:40 1,1-Dichloroethene ug/L <0.35 0.35 12/05/23 00:40 1,2,3-Trichloropropane ug/L <0.26 0.26 12/05/23 00:40 1,2-Dibromo-3-chloropropane ug/L <0.34 0.34 12/05/23 00:40 1,2-Dibromoethane (EDB) ug/L <0.27 0.27 12/05/23 00:40 1,2-Dichlorobenzene ug/L <0.34 0.34 12/05/23 00:40 1,2-Dichloroethane ug/L <0.32 0.32 12/05/23 00:40 1,2-Dichloropropane ug/L <0.36 0.36 12/05/23 00:40 1,4-Dichlorobenzene ug/L <0.33 0.33 12/05/23 00:40 2-Butanone (MEK) ug/L <4.0 4.0 12/05/23 00:40 2-Hexanone ug/L <0.48 0.48 12/05/23 00:40 4-Methyl-2-pentanone (MIBK) ug/L <2.7 2.7 12/05/23 00:40 Acetone ug/L <5.1 5.1 12/05/23 00:40 Acrylonitrile ug/L <1.8 1.8 12/05/23 00:40 Benzene ug/L <0.34 0.34 12/05/23 00:40 Bromochloromethane ug/L <0.47 0.47 12/05/23 00:40 Bromodichloromethane ug/L <0.31 0.31 12/05/23 00:40 Bromoform ug/L <0.34 0.34 12/05/23 00:40 Bromomethane ug/L <1.7 1.7 12/05/23 00:40 Carbon disulfide ug/L <0.36 0.36 12/05/23 00:40 Carbon tetrachloride ug/L <0.33 0.33 12/05/23 00:40 Chlorobenzene ug/L <0.28 0.28 12/05/23 00:40 Chloroethane ug/L <0.65 0.65 12/05/23 00:40 Chloroform ug/L <0.43 0.43 12/05/23 00:40 Chloromethane ug/L <0.54 0.54 12/05/23 00:40 cis-1,2-Dichloroethene ug/L <0.38 0.38 12/05/23 00:40 cis-1,3-Dichloropropene ug/L <0.36 0.36 12/05/23 00:40 Dibromochloromethane ug/L <0.36 0.36 12/05/23 00:40 Dibromomethane ug/L <0.39 0.39 12/05/23 00:40 Ethylbenzene ug/L <0.30 0.30 12/05/23 00:40 lodomethane ug/L <9.7 9.7 12/05/23 00:40 m&p-Xylene ug/L <0.71 0.71 12/05/23 00:40 Methylene Chloride ug/L <2.0 2.0 12/05/23 00:40 o-Xylene ug/L <0.34 0.34 12/05/23 00:40 Styrene ug/L <0.29 0.29 12/05/23 00:40 Tetrachloroethene ug/L <0.29 0.29 12/05/23 00:40 v2 IH Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 METHOD BLANK: 4229391 Matrix: Water Associated Lab Samples: 92700988001, 92700988002, 92700988003, 92700988004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Toluene ug/L <0.24 0.24 12/05/23 00:40 trans-1,2-Dichloroethene ug/L <0.40 0.40 12/05/23 00:40 trans- 1,3-Dichloropropene ug/L <0.36 0.36 12/05/23 00:40 trans-1,4-Dichloro-2-butene ug/L <0.56 0.56 12/05/23 00:40 Trichloroethene ug/L <0.38 0.38 12/05/23 00:40 Trichlorofluoromethane ug/L <0.30 0.30 12/05/23 00:40 Vinyl acetate ug/L <1.3 1.3 12/05/23 00:40 Vinyl chloride ug/L <0.39 0.39 12/05/23 00:40 Xylene (Total) ug/L <0.34 0.34 12/05/23 00:40 1,2-Dichloroethane-d4 (S) % 89 70-130 12/05/23 00:40 4-Bromofluorobenzene (S) % 93 70-130 12/05/23 00:40 Toluene-d8 (S) % 99 70-130 12/05/23 00:40 LABORATORY CONTROL SAMPLE: Parameter 4229392 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 20 19.9 100 70-130 1,1,1-Trichloroethane ug/L 20 18.1 91 70-130 1,1,2,2-Tetrachloroethane ug/L 20 18.0 90 70-130 1,1,2-Trichloroethane ug/L 20 18.4 92 70-130 1,1-Dichloroethane ug/L 20 17.2 86 70-130 1,1-Dichloroethene ug/L 20 18.3 91 69-131 1,2,3-Trichloropropane ug/L 20 16.9 84 70-130 1,2-Dibromo-3-chloropropane ug/L 20 19.0 95 70-130 1,2-Dibromoethane (EDB) ug/L 20 18.7 93 70-130 1,2-Dichlorobenzene ug/L 20 19.1 95 70-130 1,2-Dichloroethane ug/L 20 16.2 81 70-130 1,2-Dichloropropane ug/L 20 18.6 93 70-130 1,4-Dichlorobenzene ug/L 20 18.9 95 70-130 2-Butanone (MEK) ug/L 40 32.8 82 67-133 2-Hexanone ug/L 40 32.2 81 70-133 4-Methyl-2-pentanone (MIBK) ug/L 40 33.6 84 70-130 Acetone ug/L 40 30.6 77 67-130 v3 Acrylonitrile ug/L 100 84.2 84 70-130 Benzene ug/L 20 18.8 94 70-130 Bromochloromethane ug/L 20 18.1 91 70-130 Bromodichloromethane ug/L 20 18.0 90 70-130 Bromoform ug/L 20 18.8 94 70-133 Bromomethane ug/L 20 22.1 110 41-148lH Carbon disulfide ug/L 20 18.9 95 70-131 Carbon tetrachloride ug/L 20 21.5 107 70-130 Chlorobenzene ug/L 20 19.5 97 70-130 Chloroethane ug/L 20 19.2 96 41-157 Chloroform ug/L 20 18.3 91 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 69 Pace Analytical Services, LLC 1377 South Park Drive aceo Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 LABORATORY CONTROL SAMPLE: Parameter 4229392 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Chloromethane ug/L 20 19.7 98 59-141 cis-1,2-Dichloroethene ug/L 20 17.2 86 70-130 cis-1,3-Dichloropropene ug/L 20 17.9 89 70-130 Dibromochloromethane ug/L 20 18.6 93 70-130 Dibromomethane ug/L 20 20.1 100 70-130 Ethylbenzene ug/L 20 18.7 93 70-130 lodomethane ug/L 40 36.0 90 57-140 m&p-Xylene ug/L 40 37.4 93 70-130 Methylene Chloride ug/L 20 16.8 84 62-130 o-Xylene ug/L 20 18.4 92 70-130 Styrene ug/L 20 19.1 95 70-130 Tetrachloroethene ug/L 20 20.5 102 70-130 Toluene ug/L 20 18.6 93 70-130 trans-1,2-Dichloroethene ug/L 20 17.0 85 70-130 trans- 1,3-Dichloropropene ug/L 20 17.4 87 70-130 trans-1,4-Dichloro-2-butene ug/L 20 15.5 78 57-149 Trichloroethene ug/L 20 20.1 100 70-130 Trichlorofluoromethane ug/L 20 21.4 107 57-130 Vinyl acetate ug/L 40 31.4 79 70-141 Vinyl chloride ug/L 20 19.8 99 66-140 Xylene (Total) ug/L 60 55.7 93 70-130 1,2-Dichloroethane-d4 (S) % 83 70-130 4-Bromofluorobenzene (S) % 95 70-130 Toluene-d8 (S) % 98 70-130 MATRIX SPIKE SAMPLE: Parameter 4229394 Units 92700977004 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 21.9 109 70-146 1,1,1-Trichloroethane ug/L ND 20 22.2 111 70-150 1,1,2,2-Tetrachloroethane ug/L ND 20 21.0 105 66-144 1,1,2-Trichloroethane ug/L ND 20 20.9 104 70-142 1,1-Dichloroethane ug/L ND 20 22.0 110 68-150 1,1-Dichloroethene ug/L ND 20 23.0 115 64-162 1,2,3-Trichloropropane ug/L ND 20 21.4 107 66-144 1,2-Dibromo-3-chloropropane ug/L ND 20 20.5 103 62-146 1,2-Dibromoethane (EDB) ug/L ND 20 21.6 108 70-143 1,2-Dichlorobenzene ug/L ND 20 21.7 108 70-142 1,2-Dichloroethane ug/L ND 20 21.1 106 68-145 1,2-Dichloropropane ug/L ND 20 21.1 105 70-144 1,4-Dichlorobenzene ug/L ND 20 21.6 108 70-140 2-Butanone (MEK) ug/L ND 40 42.7 107 57-156 2-Hexanone ug/L ND 40 41.0 102 62-153 4-Methyl-2-pentanone (MIBK) ug/L ND 40 42.0 105 65-144 Acetone ug/L ND 40 39.9 100 49-162 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 MATRIX SPIKE SAMPLE: Parameter 4229394 Units 92700977004 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers Acrylonitrile ug/L ND 100 107 107 59-155 Benzene ug/L ND 20 21.3 107 68-144 Bromochloromethane ug/L ND 20 21.6 108 70-148 Bromodichloromethane ug/L ND 20 20.8 104 70-141 Bromoform ug/L ND 20 20.0 100 59-144 Bromomethane ug/L ND 20 23.5 118 23-190 Carbon disulfide ug/L ND 20 23.2 116 64-160 Carbon tetrachloride ug/L ND 20 22.5 113 70-147 Chlorobenzene ug/L ND 20 21.2 106 70-143 Chloroethane ug/L ND 20 22.9 114 55-190 Chloroform ug/L ND 20 21.2 106 67-148 Chloromethane ug/L ND 20 22.7 113 38-180 cis-1,2-Dichloroethene ug/L ND 20 22.0 110 67-151 cis-1,3-Dichloropropene ug/L ND 20 20.6 103 70-142 Dibromochloromethane ug/L ND 20 21.3 106 68-140 Dibromomethane ug/L ND 20 21.5 107 70-142 Ethylbenzene ug/L ND 20 21.6 108 70-145 lodomethane ug/L ND 40 42.9 107 37-160 m&p-Xylene ug/L ND 40 43.2 108 70-148 Methylene Chloride ug/L ND 20 21.5 107 54-149 o-Xylene ug/L ND 20 21.5 108 70-145 Styrene ug/L ND 20 21.5 108 70-147 Tetrachloroethene ug/L ND 20 20.7 103 70-145 Toluene ug/L ND 20 21.1 105 65-146 trans-1,2-Dichloroethene ug/L ND 20 21.6 108 69-155 trans- 1,3-Dichloropropene ug/L ND 20 20.7 104 70-142 trans-1,4-Dichloro-2-butene ug/L ND 20 19.1 96 39-149 Trichloroethene ug/L ND 20 21.5 107 70-152 Trichlorofluoromethane ug/L ND 20 22.5 113 60-158 Vinyl acetate ug/L ND 40 39.0 98 56-157 Vinyl chloride ug/L ND 20 21.7 109 51-178 Xylene (Total) ug/L ND 60 64.7 108 70-146 1,2-Dichloroethane-d4 (S) % 97 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 99 70-130 SAMPLE DUPLICATE: 4229393 Parameter Units 92700977002 Result Dup Result 1,1,1,2-Tetrachloroethane ug/L ND <0.31 1,1,1-Trichloroethane ug/L ND <0.33 1,1,2,2-Tetrachloroethane ug/L ND <0.22 1,1,2-Trichloroethane ug/L ND <0.32 1,1-Dichloroethane ug/L ND <0.37 1,1-Dichloroethene ug/L ND <0.35 RPD Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 SAMPLE DUPLICATE: 4229393 Parameter Units 92700977002 Result Dup Result 1,2,3-Trichloropropane ug/L ND <0.26 1,2-Dibromo-3-chloropropane ug/L ND <0.34 1,2-Dibromoethane (EDB) ug/L ND <0.27 1,2-Dichlorobenzene ug/L ND <0.34 1,2-Dichloroethane ug/L ND <0.32 1,2-Dichloropropane ug/L ND <0.36 1,4-Dichlorobenzene ug/L ND <0.33 2-Butanone (MEK) ug/L ND <4.0 2-Hexanone ug/L ND <0.48 4-Methyl-2-pentanone (MIBK) ug/L ND <2.7 Acetone ug/L ND <5.1 Acrylonitrile ug/L ND <1.8 Benzene ug/L ND <0.34 Bromochloromethane ug/L ND <0.47 Bromodichloromethane ug/L ND <0.31 Bromoform ug/L ND <0.34 Bromomethane ug/L ND <1.7 Carbon disulfide ug/L ND <0.36 Carbon tetrachloride ug/L ND <0.33 Chlorobenzene ug/L ND <0.28 Chloroethane ug/L ND <0.65 Chloroform ug/L ND <0.43 Chloromethane ug/L ND <0.54 cis-1,2-Dichloroethene ug/L ND <0.38 cis-1,3-Dichloropropene ug/L ND <0.36 Dibromochloromethane ug/L ND <0.36 Dibromomethane ug/L ND <0.39 Ethylbenzene ug/L ND <0.30 lodomethane ug/L ND <9.7 m&p-Xylene ug/L ND <0.71 Methylene Chloride ug/L ND <2.0 o-Xylene ug/L ND <0.34 Styrene ug/L ND <0.29 Tetrachloroethene ug/L ND <0.29 Toluene ug/L ND <0.24 trans-1,2-Dichloroethene ug/L ND <0.40 trans- 1,3-Dichloropropene ug/L ND <0.36 trans-1,4-Dichloro-2-butene ug/L ND <0.56 Trichloroethene ug/L ND <0.38 Trichlorofluoromethane ug/L ND <0.30 Vinyl acetate ug/L ND <1.3 Vinyl chloride ug/L ND <0.39 Xylene (Total) ug/L ND <0.34 1,2-Dichloroethane-d4 (S) % 91 100 4-Bromofluorobenzene (S) % 95 98 Toluene-d8 (S) % 98 102 RPD Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 QC Batch: 817410 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92700988005, 92700988006, 92700988007, 92700988008, 92700988009, 92700988010, 92700988011, 92700988012 METHOD BLANK: 4230807 Matrix: Water Associated Lab Samples: 92700988005, 92700988006, 92700988007, 92700988008, 92700988009, 92700988010, 92700988011, 92700988012 Parameter Units Blank Result Reporting Limit Analyzed 1,1,1,2-Tetrachloroethane ug/L <0.31 0.31 12/06/23 23:25 1,1,1-Trichloroethane ug/L <0.33 0.33 12/06/23 23:25 1,1,2,2-Tetrachloroethane ug/L <0.22 0.22 12/06/23 23:25 1,1,2-Trichloroethane ug/L <0.32 0.32 12/06/23 23:25 1,1-Dichloroethane ug/L <0.37 0.37 12/06/23 23:25 1,1-Dichloroethene ug/L <0.35 0.35 12/06/23 23:25 1,2,3-Trichloropropane ug/L <0.26 0.26 12/06/23 23:25 1,2-Dibromo-3-chloropropane ug/L <0.34 0.34 12/06/23 23:25 1,2-Dibromoethane (EDB) ug/L <0.27 0.27 12/06/23 23:25 1,2-Dichlorobenzene ug/L <0.34 0.34 12/06/23 23:25 1,2-Dichloroethane ug/L <0.32 0.32 12/06/23 23:25 1,2-Dichloropropane ug/L <0.36 0.36 12/06/23 23:25 1,4-Dichlorobenzene ug/L <0.33 0.33 12/06/23 23:25 2-Butanone (MEK) ug/L <4.0 4.0 12/06/23 23:25 2-Hexanone ug/L <0.48 0.48 12/06/23 23:25 4-Methyl-2-pentanone (MIBK) ug/L <2.7 2.7 12/06/23 23:25 Acetone ug/L <5.1 5.1 12/06/23 23:25 Acrylonitrile ug/L <1.8 1.8 12/06/23 23:25 Benzene ug/L <0.34 0.34 12/06/23 23:25 Bromochloromethane ug/L <0.47 0.47 12/06/23 23:25 Bromodichloromethane ug/L <0.31 0.31 12/06/23 23:25 Bromoform ug/L <0.34 0.34 12/06/23 23:25 Bromomethane ug/L <1.7 1.7 12/06/23 23:25 Carbon disulfide ug/L <0.36 0.36 12/06/23 23:25 Carbon tetrachloride ug/L <0.33 0.33 12/06/23 23:25 Chlorobenzene ug/L <0.28 0.28 12/06/23 23:25 Chloroethane ug/L <0.65 0.65 12/06/23 23:25 Chloroform ug/L <0.43 0.43 12/06/23 23:25 Chloromethane ug/L <0.54 0.54 12/06/23 23:25 cis-1,2-Dichloroethene ug/L <0.38 0.38 12/06/23 23:25 cis-1,3-Dichloropropene ug/L <0.36 0.36 12/06/23 23:25 Dibromochloromethane ug/L <0.36 0.36 12/06/23 23:25 Dibromomethane ug/L <0.39 0.39 12/06/23 23:25 Ethylbenzene ug/L <0.30 0.30 12/06/23 23:25 lodomethane ug/L <9.7 9.7 12/06/23 23:25 m&p-Xylene ug/L <0.71 0.71 12/06/23 23:25 Methylene Chloride ug/L <2.0 2.0 12/06/23 23:25 o-Xylene ug/L <0.34 0.34 12/06/23 23:25 Styrene ug/L <0.29 0.29 12/06/23 23:25 v2 v2 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 METHOD BLANK: 4230807 Matrix: Water Associated Lab Samples: 92700988005, 92700988006, 92700988007, 92700988008, 92700988009, 92700988010, 92700988011, 92700988012 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Tetrachloroethene ug/L <0.29 0.29 12/06/23 23:25 Toluene ug/L <0.24 0.24 12/06/23 23:25 trans-1,2-Dichloroethene ug/L <0.40 0.40 12/06/23 23:25 trans- 1,3-Dichloropropene ug/L <0.36 0.36 12/06/23 23:25 trans-1,4-Dichloro-2-butene ug/L <0.56 0.56 12/06/23 23:25 Trichloroethene ug/L <0.38 0.38 12/06/23 23:25 Trichlorofluoromethane ug/L <0.30 0.30 12/06/23 23:25 Vinyl acetate ug/L <1.3 1.3 12/06/23 23:25 Vinyl chloride ug/L <0.39 0.39 12/06/23 23:25 Xylene (Total) ug/L <0.34 0.34 12/06/23 23:25 1,2-Dichloroethane-d4 (S) % 116 70-130 12/06/23 23:25 4-Bromofluorobenzene (S) % 97 70-130 12/06/23 23:25 Toluene-d8 (S) % 96 70-130 12/06/23 23:25 LABORATORY CONTROL SAMPLE: Parameter 4230808 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 20 22.4 112 70-130 1,1,1-Trichloroethane ug/L 20 21.7 109 70-130 1,1,2,2-Tetrachloroethane ug/L 20 22.6 113 70-130 1,1,2-Trichloroethane ug/L 20 21.6 108 70-130 1,1-Dichloroethane ug/L 20 20.1 101 70-130 1,1-Dichloroethene ug/L 20 22.7 114 69-131 1,2,3-Trichloropropane ug/L 20 23.6 118 70-130 1,2-Dibromo-3-chloropropane ug/L 20 19.0 95 70-130 1,2-Dibromoethane (EDB) ug/L 20 23.7 118 70-130 1,2-Dichlorobenzene ug/L 20 24.5 123 70-130 1,2-Dichloroethane ug/L 20 22.3 112 70-130 1,2-Dichloropropane ug/L 20 21.0 105 70-130 1,4-Dichlorobenzene ug/L 20 24.3 121 70-130 2-Butanone (MEK) ug/L 40 42.4 106 67-133 2-Hexanone ug/L 40 43.8 110 70-133 4-Methyl-2-pentanone (MIBK) ug/L 40 41.5 104 70-130 Acetone ug/L 40 44.8 112 67-130 Acrylonitrile ug/L 100 99.7 100 70-130 Benzene ug/L 20 21.9 110 70-130 Bromochloromethane ug/L 20 20.0 100 70-130 Bromodichloromethane ug/L 20 18.8 94 70-130 Bromoform ug/L 20 16.3 82 70-133 v3 Bromomethane ug/L 20 15.8 79 41-148 v3 Carbon disulfide ug/L 20 17.9 89 70-131 Carbon tetrachloride ug/L 20 20.7 104 70-130 Chlorobenzene ug/L 20 23.7 118 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 69 Pace Analytical Services, LLC 1377 South Park Drive aceo Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 LABORATORY CONTROL SAMPLE: Parameter 4230808 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Chloroethane ug/L 20 23.4 117 41-157 Chloroform ug/L 20 19.9 99 70-130 Chloromethane ug/L 20 20.1 100 59-141 cis-1,2-Dichloroethene ug/L 20 20.8 104 70-130 cis-1,3-Dichloropropene ug/L 20 18.9 94 70-130 Dibromochloromethane ug/L 20 19.5 97 70-130 Dibromomethane ug/L 20 21.2 106 70-130 Ethylbenzene ug/L 20 23.8 119 70-130 lodomethane ug/L 40 37.9 95 57-140 m&p-Xylene ug/L 40 49.5 124 70-130 Methylene Chloride ug/L 20 21.4 107 62-130 o-Xylene ug/L 20 23.5 118 70-130 Styrene ug/L 20 23.0 115 70-130 Tetrachloroethene ug/L 20 23.4 117 70-130 Toluene ug/L 20 20.7 103 70-130 trans-1,2-Dichloroethene ug/L 20 21.5 107 70-130 trans- 1,3-Dichloropropene ug/L 20 18.2 91 70-130 trans-1,4-Dichloro-2-butene ug/L 20 18.5 93 57-149 Trichloroethene ug/L 20 21.4 107 70-130 Trichlorofluoromethane ug/L 20 23.1 116 57-130 Vinyl acetate ug/L 40 49.3 123 70-141 Vinyl chloride ug/L 20 18.3 91 66-140 Xylene (Total) ug/L 60 73.0 122 70-130 1,2-Dichloroethane-d4 (S) % 113 70-130 4-Bromofluorobenzene (S) % 101 70-130 Toluene-d8 (S) % 96 70-130 MATRIX SPIKE SAMPLE: Parameter 4230809 Units 92701243008 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 23.3 116 70-146 1,1,1-Trichloroethane ug/L ND 20 25.0 125 70-150 1,1,2,2-Tetrachloroethane ug/L ND 20 24.0 120 66-144 1,1,2-Trichloroethane ug/L ND 20 21.1 106 70-142 1,1-Dichloroethane ug/L ND 20 22.9 114 68-150 1,1-Dichloroethene ug/L ND 20 26.3 131 64-162 1,2,3-Trichloropropane ug/L ND 20 22.6 113 66-144 1,2-Dibromo-3-chloropropane ug/L ND 20 18.8 94 62-146 1,2-Dibromoethane (EDB) ug/L ND 20 23.7 118 70-143 1,2-Dichlorobenzene ug/L ND 20 24.9 124 70-142 1,2-Dichloroethane ug/L ND 20 23.1 116 68-145 1,2-Dichloropropane ug/L ND 20 22.8 114 70-144 1,4-Dichlorobenzene ug/L ND 20 25.3 126 70-140 2-Butanone (MEK) ug/L ND 40 50.3 126 57-156 2-Hexanone ug/L ND 40 46.7 117 62-153 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 39 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 MATRIX SPIKE SAMPLE: Parameter 4230809 Units 92701243008 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 4-Methyl-2-pentanone (MIBK) ug/L ND 40 42.9 107 65-144 Acetone ug/L ND 40 47.1 118 49-162 Acrylonitrile ug/L ND 100 108 108 59-155 Benzene ug/L ND 20 23.5 117 68-144 Bromochloromethane ug/L ND 20 22.1 110 70-148 Bromodichloromethane ug/L ND 20 19.2 96 70-141 Bromoform ug/L ND 20 17.3 86 59-144 v3 Bromomethane ug/L ND 20 20.6 103 23-190 v3 Carbon disulfide ug/L ND 20 23.3 116 64-160 Carbon tetrachloride ug/L ND 20 22.0 110 70-147 Chlorobenzene ug/L ND 20 23.9 120 70-143 Chloroethane ug/L ND 20 25.0 125 55-190 Chloroform ug/L ND 20 24.7 124 67-148 Chloromethane ug/L ND 20 23.0 115 38-180 cis-1,2-Dichloroethene ug/L ND 20 24.9 123 67-151 cis-1,3-Dichloropropene ug/L ND 20 19.5 97 70-142 Dibromochloromethane ug/L ND 20 20.3 101 68-140 Dibromomethane ug/L ND 20 22.2 111 70-142 Ethylbenzene ug/L ND 20 24.6 123 70-145 lodomethane ug/L ND 40 43.1 108 37-160 v3 m&p-Xylene ug/L ND 40 49.9 125 70-148 Methylene Chloride ug/L ND 20 23.7 119 54-149 o-Xylene ug/L ND 20 24.5 123 70-145 Styrene ug/L ND 20 23.7 118 70-147 Tetrachloroethene ug/L ND 20 23.6 118 70-145 Toluene ug/L ND 20 21.2 106 65-146 trans-1,2-Dichloroethene ug/L ND 20 24.2 121 69-155 trans- 1,3-Dichloropropene ug/L ND 20 19.0 95 70-142 trans-1,4-Dichloro-2-butene ug/L ND 20 17.8 89 39-149 Trichloroethene ug/L ND 20 22.2 111 70-152 Trichlorofluoromethane ug/L ND 20 24.6 123 60-158 Vinyl acetate ug/L ND 40 43.5 109 56-157 Vinyl chloride ug/L ND 20 21.0 105 51-178 Xylene (Total) ug/L ND 60 74.4 124 70-146 1,2-Dichloroethane-d4 (S) % 116 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 95 70-130 SAMPLE DUPLICATE: 4230810 92701243009 Dup Parameter Units Result Result RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND <0.31 1,1,1-Trichloroethane ug/L ND <0.33 1,1,2,2-Tetrachloroethane ug/L ND <0.22 1,1,2-Trichloroethane ug/L ND <0.32 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 SAMPLE DUPLICATE: 4230810 Parameter Units 92701243009 Result Dup Result 1,1-Dichloroethane ug/L ND <0.37 1,1-Dichloroethene ug/L ND <0.35 1,2,3-Trichloropropane ug/L ND <0.26 1,2-Dibromo-3-chloropropane ug/L ND <0.34 1,2-Dibromoethane (EDB) ug/L ND <0.27 1,2-Dichlorobenzene ug/L ND <0.34 1,2-Dichloroethane ug/L ND <0.32 1,2-Dichloropropane ug/L ND <0.36 1,4-Dichlorobenzene ug/L ND <0.33 2-Butanone (MEK) ug/L ND <4.0 2-Hexanone ug/L ND <0.48 4-Methyl-2-pentanone (MIBK) ug/L ND <2.7 Acetone ug/L ND <5.1 Acrylonitrile ug/L ND <1.8 Benzene ug/L ND <0.34 Bromochloromethane ug/L ND <0.47 Bromodichloromethane ug/L ND <0.31 Bromoform ug/L ND <0.34 Bromomethane ug/L ND <1.7 Carbon disulfide ug/L ND <0.36 Carbon tetrachloride ug/L ND <0.33 Chlorobenzene ug/L ND <0.28 Chloroethane ug/L ND <0.65 Chloroform ug/L ND <0.43 Chloromethane ug/L ND <0.54 cis-1,2-Dichloroethene ug/L ND <0.38 cis-1,3-Dichloropropene ug/L ND <0.36 Dibromochloromethane ug/L ND <0.36 Dibromomethane ug/L ND <0.39 Ethylbenzene ug/L ND <0.30 lodomethane ug/L ND <9.7 m&p-Xylene ug/L ND <0.71 Methylene Chloride ug/L ND <2.0 o-Xylene ug/L ND <0.34 Styrene ug/L ND <0.29 Tetrachloroethene ug/L ND <0.29 Toluene ug/L ND <0.24 trans-1,2-Dichloroethene ug/L ND <0.40 trans- 1,3-Dichloropropene ug/L ND <0.36 trans-1,4-Dichloro-2-butene ug/L ND <0.56 Trichloroethene ug/L ND <0.38 Trichlorofluoromethane ug/L ND <0.30 Vinyl acetate ug/L ND <1.3 Vinyl chloride ug/L ND <0.39 Xylene (Total) ug/L ND <0.34 1,2-Dichloroethane-d4 (S) % 113 119 4-Bromofluorobenzene (S) % 99 94 RPD Qualifiers v2 v2 v2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 SAMPLE DUPLICATE: 4230810 92701243009 Dup Parameter Units Result Result RPD Qualifiers Toluene-d8 (S) % 93 95 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 42 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 QC Batch: 816700 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92700988001, 92700988002, 92700988003 METHOD BLANK: 4227004 Matrix: Water Associated Lab Samples: 92700988001, 92700988002, 92700988003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L <0.86 0.86 12/01/23 14:44 1,2-Dichloroethane-d4 (S) % 95 67-130 12/01/23 14:44 Toluene-d8 (S) % 99 70-130 12/01/23 14:44 LABORATORY CONTROL SAMPLE: 4227005 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 20.7 103 70-130 1,2-Dichloroethane-d4 (S) % 96 67-130 Toluene-d8 (S) % 100 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4227006 4227007 MS MSD 92700857011 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 21.6 21.2 108 106 55-137 2 1,2-Dichloroethane-d4 (S) % 95 94 67-130 Toluene-d8(S) % 99 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 43 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 QC Batch: 816704 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92700988005, 92700988006, 92700988007, 92700988008, 92700988009, 92700988010, 92700988011, 92700988012 METHOD BLANK: 4227021 Matrix: Water Associated Lab Samples: 92700988005, 92700988006, 92700988007, 92700988008, 92700988009, 92700988010, 92700988011, 92700988012 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L <0.86 0.86 12/02/23 02:52 1,2-Dichloroethane-d4 (S) % 95 67-130 12/02/23 02:52 Toluene-d8 (S) % 100 70-130 12/02/23 02:52 LABORATORY CONTROL SAMPLE: 4227022 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 22.4 112 70-130 1,2-Dichloroethane-d4 (S) % 94 67-130 Toluene-d8 (S) % 99 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4227023 4227024 MS MSD 92700988005 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual 1,4-Dioxane(p-Dioxane) ug/L <0.86 20 20 19.4 19.8 97 99 55-137 2 1,2-Dichloroethane-d4 (S) % 93 95 67-130 Toluene-d8(S) % 98 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 69 ceo Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALIFIERS Project: Rutherford Co South LF Nov23 Pace Project No.: 92700988 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be considered an estimated value. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 69 Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Rutherford Co South LF Nov23 92700988 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92700988001 8102-MW-9S EPA 3010A 816930 EPA 6010D 816951 92700988002 8102-MW-9D EPA 3010A 816930 EPA 6010D 816951 92700988003 8102-SW-1 EPA 3010A 816930 EPA 6010D 816951 92700988005 8102-MW-1 EPA 3010A 816930 EPA 6010D 816951 92700988006 8102-MW-2A EPA 3010A 816930 EPA 6010D 816951 92700988007 8102-MW-4A EPA 3010A 816930 EPA 6010D 816951 92700988008 8102-MW-5 EPA 3010A 816930 EPA 6010D 816951 92700988009 8102-MW-6 EPA 3010A 816930 EPA 6010D 816951 92700988010 8102-MW-7 EPA 3010A 816930 EPA 6010D 816951 92700988011 8102-MW-8 EPA 3010A 816930 EPA 6010D 816951 92700988012 8102-SW-2 EPA 3010A 816930 EPA 6010D 816951 92700988001 8102-MW-9S EPA 7470A 818212 EPA 7470A 818323 92700988002 8102-MW-9D EPA 7470A 818212 EPA 7470A 818323 92700988003 8102-SW-1 EPA 7470A 818212 EPA 7470A 818323 92700988005 8102-MW-1 EPA 7470A 818551 EPA 7470A 818696 92700988006 8102-MW-2A EPA 7470A 818551 EPA 7470A 818696 92700988007 8102-MW-4A EPA 7470A 818551 EPA 7470A 818696 92700988008 8102-MW-5 EPA 7470A 818551 EPA 7470A 818696 92700988009 8102-MW-6 EPA 7470A 818551 EPA 7470A 818696 92700988010 8102-MW-7 EPA 7470A 818551 EPA 7470A 818696 92700988011 8102-MW-8 EPA 7470A 818551 EPA 7470A 818696 92700988012 8102-SW-2 EPA 7470A 818551 EPA 7470A 818696 92700988001 8102-MW-9S EPA 8260D 817172 92700988002 8102-MW-9D EPA 8260D 817172 92700988003 8102-SW-1 EPA 8260D 817172 92700988004 8102-Duplicate EPA 8260D 817172 92700988005 8102-MW-1 EPA 8260D 817410 92700988006 8102-MW-2A EPA 8260D 817410 92700988007 8102-MW-4A EPA 8260D 817410 92700988008 8102-MW-5 EPA 8260D 817410 92700988009 8102-MW-6 EPA 8260D 817410 92700988010 8102-MW-7 EPA 8260D 817410 92700988011 8102-MW-8 EPA 8260D 817410 92700988012 8102-SW-2 EPA 8260D 817410 92700988001 8102-MW-9S EPA 8260D Mod. 816700 92700988002 8102-MW-9D EPA 8260D Mod. 816700 92700988003 8102-SW-1 EPA 8260D Mod. 816700 92700988005 8102-MW-1 EPA 8260D Mod. 816704 92700988006 8102-MW-2A EPA 8260D Mod. 816704 92700988007 8102-MW-4A EPA 8260D Mod. 816704 92700988008 8102-MW-5 EPA 8260D Mod. 816704 92700988009 8102-MW-6 EPA 8260D Mod. 816704 92700988010 8102-MW-7 EPA 8260D Mod. 816704 92700988011 8102-MW-8 EPA 8260D Mod. 816704 92700988012 8102-SW-2 EPA 8260D Mod. 816704 Date: 12/12/2023 05:36 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 46 of 69 P+tt' Laa:wn neares,en {va Yrat.tsa. (�Q ace Pare •na:ytical Kernersr,Ile, NC NC 27234 i •� 1377 Soac+^ark 9r. I(e mville, :omwny Name: Rutherford Counly Landfill ;1•rn Add,tss. PO Sax.957, Rulhedordton, NC 20139 er Protect .- Nsmr Rutherford CO- -SOJ-h tan4l'" KI On ln(e/talpl,tr ID 1as+bbrk Able) CHAIN -OF -CUSTODY Analytical Request Document Chain ef.C,stodY's a tEGAL DOCUMENT - Cemp'etenll r.W Mflclds Cornact/110*e1 ?b: Ames Mile Phone P: 828.287.6002 E-MaC lames kilgd@rutherfordcd7ntync.gov Cc L Mail! Inro{eu, AeeDuals Payable rrtro ce E•Maa james,kilgo@rutherfordwuntync.gav P,rrctvsc4rtler a 1.1 aPP-Made} Oictt9 m13d6951 meretne Collectra: I 1 ►K I PT j MT I C7 I ] ET '• r r•.- - n _. __,.-_ _._. 1:a Dr.veydles. Regulatory Preat— tow, RCNi. etc I as avaGubte: I : L... I ! I Lerrl It. 1 1 Lerel Iv Rush (Premappraval requlredl: 1 EQUS I l2D+Y I '3daY I ISdaY I IOMer Date Results t -ome• Requested: Morn.Codes ilne,r nM+lar box bebwt:Or:nk:ng Wile, tDW).G,Wnd Water(GWI.Wasu Water(wW1, Product IN. So,Utela trier l0'l, Surface water ISWI.Sed-ment CUM S4Wge Mi. Caulk «tea C.torner;ample to Ma1H. • Corral for Cbmvpslte St+rt)•— SM. MW I WT 8102-MW-2A WT 8302-MW-3 WT 8102-MW4A WT 8102 MW-5 WT 8102-MW-6 WT 8102-MW-7 WT 8102-MW-8 WT 8102-MW-95 WT 8102-MW-9D WT k\ I }LLl Z user nema,. i avevr.. ,..,..,.,,.�..., . M No. 8102-MSWLF-1977 Project No. J23-20955-01 e 17056. Lino 6 %S,50 WO#T: 92700988 92700988 BSCeCifV Conla—r the " •-4un,awn 7ur I1}:40,nL -,k 47 1712501n1.Ia1 175mL 151 ]Oom:lel aOmL mar ill Cn[p•e. ISi rnrato<e, l91 Canr, ICeraify Conlaner PrMfNal-Ye lyor'•• •••D.euvralwr Typo ISI Aenr, 171 HhOS. t31 +,"04 IN t0. W 4aCH, 13} 2r. ar.tate, Ili traHsea. III Sad. /nwsreau, l9} A—INI kw. 1101 Anilyt ReQ,*c J&d Mr4H, 111$0,h.r P•dj- Mgr: c w ti v PwttD P or W W Pe•dyl • ai avPf oe e' x w � � b 7 Feld 3atered pl aoPloblel. I I Yes I I No n m alytii. N O, {OL1, W1Re (w ft 8095rav 181. vabor lvi. ay.aber A Tye..0 a ♦j CrunPoflte End Res• Cenralnen to N ` CL2 _. L? AA ImtrvGipp3 from 3 ftwornhrd brrc.m .f. Ow . —I ale/r+ne. RyCer.N brltpr,ea>'r Isl .—I -- T Submitting a samOkvra%hit Chain 01 custody [OnStillnes&ckrlowledgment and atteptance of -,he Pace' Terms and Conditions frond at fttrps'IhYY�,w•oicelabs.com/resource-library!resource/Wce•rerms-ard•candi[ions/ N CC fD A J 0 ID: 14 o ��70 Prelda/ a"'. old. ID: E2 30u736 Sample Comment ar,.clwn racta. C[I• Oss lernp. 1'q [o.r« w Temp. .red bY' ( I Irn Pe•san ( 1 Courier I I redEX I: UPS I I Other Page: 1 of 2 V•FRM-CORO.0019 v01_082123C T N CC O 00 O_ Suhm.ttmgiSamF�e vu im>�rw����.. ....•,....-_...... _.____. _ race U xrrf_11%ru. %-I'mr-i 1wi, VVYJ •V�-_V MII II,.- ..v..v.1... Effective Date: 11/14/2022 Laboratory receiving samples: Asheville ❑ Eden[] Greenwood ❑ Huntersville E Raleigh❑ Mechanicsville❑ Atlanta[] Kernersville❑ Sample Condition I Client Name: Upon ReceiptfP�oject a: Courier: ❑fed x ❑UPS ❑LISPS ❑Cllent ❑ Commercial ace ❑Other-- Custody Seal Present? ❑Yes o Seals intact? ❑Yes ON. L � Date/Initials Person Examining Contents. S Packing Material: ❑Bubble Wrap 0ubble Bags ❑None ❑ Other Biological Tissue zen? Thermomet ❑yes ❑No N/A Ef IR Gun to! lft2�rv7J Type of Ice: Wet ❑[Slue ❑,lone Correction Factor: Cooler Temp: Add/Subtract i'Ci l Temp should be above freezing to a C Q5amples out of temp tcleria Samples an ice, tooting process Cooler Temp Corrected (' % has begun USDA Regulated Sall ( C3 N/A, water sample) Did sampies originate in a quarantine zone within the United States: CA, NY, or SC Old samples o+iglnate from a .1oreign source (internationatly, (check maps)? ❑Yes ❑NO _ +nckdmg11awiti and Puerto Ricoh ❑Yes ❑No a Chain of Custody Present? Yes []No ❑N/A 1. Samples Arrived within Hold Time? Yes No ©M/A 2 Short bold Time Analysis (02 hr.)? Yes . Na N/A 3 Rush Turn Around Time Requested? Dyes Io ❑N/A 4- Sufficient Volume? es I]No (]N/A 55. Correct Containers Used? -Pace Containers Used? I�� S L/jYes o ©NILNo ❑N/A ❑ N/A ` 6. Containers Intact? , Yes QNo [IIN/A ?. Dissolved analysis: Samples Field Filtered? []Yes [jNo -�N/A Sample labels Match CDC? Ycs QNo ❑FrfA 1 9 I -includes Oate/Time/ID/Analysis Matrix I -- Headspace in VOA Vials (>5.6mm)? Trip Blank Present? Trip Blank Custody Seals Present? COMMENTS/SAMPLE DISCREPANCY CLIENT NOT Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Oualtrax ID 69614 QN/A 10. ON/A Field Data Required? ID of spit containerg Gate/Time; i7ate: Date: Page 1 of 2 Page 49 of 69 --- ... --. ...... ..-... _ - -- ._--- ----r..- - -.,—- _r -- .--- ,-Puce - EHectivo Date: 11/14/2022 *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, CoMorm, TOC, Oil and Grease, DRO/8015 (water) DOC, LLtrg "Bottom half of box is to list number of bottles *"Check all unpreserved Nitrates for Chlorine Project ft L_ ,n. c ? n g l ro a `= 2 v a N U M a a Z Z K y ? ^ A y v q ? q = n z y z z ✓; 7 7 C a .:. .: :. J`. a a a+ = Z rZy p G V a.r u ••:, W d Zan a a y j E t a q O S z Q, q a y n y S s E a D a q ¢ Z Q O E E E 6 S 7 a b [1 I .• a > E a 'ar ? cr ._ a = d .� t E e 'E I n ¢ E E f E a E § V o H r L a a a a m Co m m rn i N m a m a a 0 q a a a t7 l7 EO m m m �; Q a �v', m `* s o or m l7 L7 l7 l,7 t7 0 Q Q a 13 O } m t7 i y m n jj l7 a a X l7 9 n rn o m u tL a L7 vl t7 ul h m 4 } O ! \ \ \ 3 \- 3 I _ I— 10 1! Y2 —� \ — —j pH Adjustment Log for Preserved Samples I sample to I Type of Preservative I pH upon receipt pate preservation adjusted Time preservation Amount of Preservative Lot 4 1 1 adjusted Amount Note Whenn ver there is a discrepancy alfecung North Carolina compliance samples. a copy of this inrm wLR be sent to )lie north Carolina DE NR Certificauort 011ce it e Out of hold. mcorr,•Cl. presrrvalive, out of temp, intofw(t contaweFS. Quallrax ID 69614 Page 2 of 2 Page 50 of 69 Pale- La[dron RaaYesteo1L1tYFata1l: /'�race Anaiyt.Cal Ke, xQIWOle, NC Q Lr a [3II South Pa•4 Dr.. Kc•xrs+nr, NC 27284 :om»nr Name: Ruther!ord Counry Landf,11 deer: add-ess. PO Sox 1957. Rutherfordton, NC 29114 .tom' PralK1 tr. 'alKt Name Rutheeord Co. • South ta'sdfll to Coxert!a^ In fy/Facd.ty 10 las aadl.CMlel- CHAIN-OF-CUSTODY Analytical Request Document Chan-a!Custody s a LEGAL DOCUMENT- Cenmlete all relevant t,rids ConeaeURenan la: James Kilgo Phone a: 828.282.6002 C-MaR: lamesAilgpprulhe!fordcountynC gov Cc E rvaa Imote Ta: Accounts Payable 1,.a f Mal: 14meS Migo(pruiherlordoountynC.gov PU,.ha O-der a (J , .a r.ae r r.... wamoroermaom t.aoe1 ratre WO#:92700988 PM: SK Due Date! 12/14/23 CLIENT: KR-RuthLandf Inra,nv We -- r Prnar.at^+r 1 } Rpvesled 10�. a. 00146951 m o ti r1! Zane Col:ened I ]At I 1 PI [ 1 Mr I ICI 1 ! [T Cowly / $sate."tA or s. moral. North Carolina ,ta ve-'raber• RC•gyl310 V Prcag a fDW. RCAA. etc.) as aaYCable: 1 !Lhe1n I ILe01m I ILe..11V smi o n 0 � a 0.ush{Pre-approvalrcqulredl= OW PW$lp a or WW PCIMAa 2s 300pb4: [ :tQJIs I 12DaY I 11eay I ISday t 10thcr q -. 7 m Feld Fatered [J apohubfel 1 I Yes I I No Date Results M — 1 IGInC' RCVUKtedt Analyt.s: to b > 4 � m E Q Mate,. Codes (,^+err m Milt— boa bepw). Dun4i^g Water (DWI. Ground Water tGW). Waste Water IW WI. Product IPI. Soil/Solis ISSI. 0.1 {DL). Wier WPL Tissue MI.6-oasur M, Vaoar (ri. lwr 101t. Surface Water;S W),Sed'ment M01, Sludge ISLI. Caulk N.mb aTyaaN 26 a:colten Customer Sample ID Maw. - for Con,s11e Stan)[bmpd4le End net. Cnntalnen CLZ m m q D.I. Time I Was,; Grab Dne 1 Tlme Planlr F 8102-MW-1 WT '(� w X X X 8102-MW-2A WT'i• I�'7 W X X X 11 X X X 8102-MW-3 WT II11 n 8102-MW-4A NTT 11f 2 j� e7? + X X X 8102-MW-5 WT '�X . %7 , X X X 8102-MW-6 WT U7 l (Q X X X 8102 MW-7 WT Ml 7 �ry l 1 X X X 8102-MW-8 WT �+ �j;. �.� ,��f l (p X X X X X X 8102-MW-95 WT X X X 8102-MW-90 WT ustomer Remarks / Special Conodtons / Possible Halardll Pnnld Collected ey: Name: ar � �� Additional Inllydelidns from Pau•: mtar .Caen: rnmI eurerlla emh No. 6102-MSWLF-1977 LE Project No. J23-2095"I S'petwe: orde 17056, Lme 6 novn,eC a.lCp^yana Ly.atwet parr!:..., a nY IAM..... ' new+ore btKomwny: ;Sl{n+twrl Date/•rme IRmAW byJCerrPaM R,gnalwrl pax ne.h'+r elrcamwn nPrwN DauRirrrr aernwe b"C."."- S.C.M.n) fmx7Tm+ r. (1re I 4bre.n+re b.KanParn 1Agmwnl pax(imw ...... lac<e.re brlCaryany Is.tmlwrl •' T Subrrlrllmg a sample v a this chain of cuslodY COMIltutes aclnow:edgment and aCeeptanceor the Pacer Terms and Conditions found at hops://www.paCetahs cornlresourcedihrarylresourCa/p2ce-termsand-rondiiions/ v 1a CD U1 '-Cpnu,rr. S,re SSI IL IS1 SpdmL:sl :Som,-161 121mLISI JoemL.i61 AO A wd, (71 InCmr, tat rer.arar.ISl Dinh •••e•.,e..ax.r Srpe. Is Nw,e. 111 n�r01.1) H2SDa, la: xCE Is) NaGL 1612n Areutr ;PI NwaSOd-1a1 Soa ixmwNatr. (9) A,stnbm Acd. Ito) M 0O 1,131 M"r Prot Mgr Stephanie Knott g - AWNuM I Che910 4 O 'ablea e e Rod,/-emgaee 17056 log.. aside Ord -D- Ez 3oxz '36 F s Sample Comment ` oln- Troy. reed by: [ 1 In- person I I Courier t I Fed[a 1 1 LIPS 1 101her Page: I of 2 V•FRM-CORO.0019 u01 082123 W KI T N Ca CD UT N LAB USE ONLY. AM. WorkordMfLd91n Label Mere P.C.. Lo[ahos Repueshrd Icevlsu[rJ. NC CHAIN -OF -CUSTODY Analytical Request Document Pare Js q?VtiUI Rer",s,die. 1377 South Pa•k 01• [anerw+le. NC 272E4 Cna-e-CusioPv's a LEGAL DOCUMENT Comb•eea l releva+[ !efas Co,a ny N+—r Rutherford County Landfill ConSet'tiscPpn TO James K'lyo St•rat Aclo—s pO M. 1+57, Ruthrrlordian, NC 28119 Phone P: 828-287-6W2 Scan OR CadC for i65[000Ii005 E-Mad: fames kilgGorutherfordcdontync.gav CC E Mai;: Custo•ne• P.eKrt •: lnvo4r70+ Accounts Payable "Cerrtarr•.Sur 1311t.- .17175Pm:.ha} P•Ctrct Name: Rull+erfard [p.-SWutn Laadtdl I—C. E.Mad altte56:11 0 ru 1 g thNtOrdCOYn[ynC.gOV SpeW:y Cpnianrr S:e .. aarr..Iyl, 1)i ErCP, e. Ia} 175.n.. i5l 011.I IV onk,Is; ldtnlilyCOntainer P,oil—S-vo I,-'— "'Prrt—t-1vprr it)—, l7ir+NOT.;If emmi I•r'olFaciMr ID Ias,app6ubiel. Pu•rnasl OwerRI,1 M25oa- MI MCI.151 noon, 1412n A:eut.-17) 330cablel: Nar$aa, 181 Sod ;h _.— Of Amvbrr Mid. (101 AMfyyii drov.Srrd WWI.-11)priv" Quilt! a. 001A896d Prq_ Mgr T,me 2pne Cd�Ieclttd_ I l a� I I I I I MT [ounry(Svee e•:d'n er samo4lsb North Carolina tephanie Knott E Data Dll,ve•aC K: R.Sulatorr Prot -am (DW, RC9k etc I M 400irab.0: o Atctlrum/ Client JD: m a [ J Lerll rl I I Lrvwl lei I I Levy IV Rush {Pre -approval required): OW PWSID F M NnN Palm P is dppR[aplC: o C 0 T3Ye a: c [;touts I I 1 Oav I l i day I t s day I 10tntr _ n PrWW. l TrmP'ate: e sires /I�eretl 4raod:cao�el: I }rs I INo Dace Results i c m 17056 € I Jather Requested ANlys:r H , � vrrlog J Dpnle Oro. tD: ' NNIm CWde+([nsen m Matra boat PllOhr] Ona4At Wt., IDWI. Ground wmer{GWI, 1Vaue Water (WAII. P'0dVC' IN, SoalSd.d ISSI, Oil DOLL W-Pe (WP2• Tissue{Ts), fs,-L av 187, Vapor lVl. y � ¢ �Ua, EZ 3D22736 .9 Other 10T1. i-fact Wale1 iSWI.Sedimrm luDl, SWdge iStl. Cau:Y i Collected NumWri TrPfH O O Z ComPJ [drtlPaaite End R0� aasuia • for Coespeche Slant Crrdairhen Z6 n =° Sarnp a Comment Custdme, Sample JD Grab Data lime aa7e Time ►gsek Glass w m r° wab x X X X 8102-SW1 avT WT •�2j 4(�,�il ' x x x 8102-5W-2 X 8102•0uplicate w C(Alectetl By. Additional Inuructinns from Paceac Customer Remarks / Special Conditions f Possible Ha2ards: P-i cl Name. N lC KAublaw n Permit No. 8102-MSWLF-1977 reewers: tD: Careserah racto•I'[b Tema. i'[I Carwned temp{'q 8 EProject No J23.20955-0t Signature 1 J � • l a profile 17056. Lint: a a 0a[�� -6 ¢i7�JJ SR. "T—lun, ,L 7Itn+'1 Oax Delirerld bV: I J In• Person 1 J Courier Catr(Taw rrnrvrd brlco y l5pnaeh,rcl OahrRrmn I J FedCK 1 1 UPS 1 I Other rrlmr.rshn brttomP+nr tS,in+[v.r: Onr/tur,e etecr�•mt b![ongar,r' 15iar,+rr+.1 Drtr/I— page: 2 of 2 R.aryuMw brttomrxr t5,e�+[we; of CA* Pace•-erms and Conditions found athtips!lwrrawR><et+Gs.wnJresaurce•Itararv/resourtr!Pace-terms•and•condirlons, Ef4V•FFIM CORQ-0079_v01_D621230 subml::ing a sample via this chain of custody conswules acknowledgment and acceptance ..r vrr ,r►.... .�.�• , ,.,r. ,.r., .. ter. �.� ..�....,r,.. lWace Effective Date: 11/14/2022 Laboratory receiving samples: Asheville LJ Eden❑ Greenwood ❑ Huntersville Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersville❑ Sample Cordition Client Name. - w�` Project #: r mow' , Courier: Eyed Ex ❑UPS USPS ❑Client ❑ Commertial mpace ❑Other: Custody Seal Present? ❑Yes •i,�wo Seals Intact? es ❑No • Date/lnrCals Person Examining Contents. Packing Material: ❑Bubble Wrap Bubble Bags ❑None ❑ Other Biological Tissue nxon? ! Thermome r: Dyes ❑No N/n 11ty"'AGun ID: p Type of Ice: VW et (:]Blue❑Hone Correction Factor, // Cooler Temp: Add/Subtract 1•C) _� Temp should be above freezing to 6'C ❑samples auto( temp u,ter,a. Samples on ice, tooling process Cooler Temp Correcte�l'C): hasbegun USDA Regulated Soil (pyrV/A, water sample) Did samples origins�fn a quarantine zone within the United States: CA, NY, or SC Did samptes originate tram a Foreign source Internationally, [check maps)? UYes LINo rncllraine IWwan ano Puerto local I Lire Urya Comments/Discrepancy: Chain of Custody Present? ves ❑rt/n 1. Samples Arrived within Bold Time? yes _❑_No ❑No ❑N/n 2 Short Hold Time Analysis 102 hr.)? Dyes a ❑N/A 3. Rush Turn Around Time Requested? ❑yes to []N/A 4. S. 6. Sufficient Volume? es ❑Iva ❑N/A Correct Containers Used? ONO ❑N/A -Pace Containers Used? s ELNo ❑N/n Containers Intact? Nes ❑No ❑N/A 1 7. Dissolved analysis: Samples Field Filtered? Pus o N/A 8. Sample labels Match COC? -includes Date/Time/ID/Analysis Matrix: j yes W ❑No ❑N/A 9 10 Headspace in VOA Vials I?5.6mm)? ❑Yes i a ❑N/A Trig Blank Present? Trip Blank Custody Seals Present? []yes ❑yes a ND i ! 1 COMMENTS/SAMPLE DISCREPANCY riem uata mequ,rear Ures tJr're Lot ID of spill Cdat_au+ers: CLIENT NOT Person contarted: _ Dalellime: Ptbject Manager SCURF Review: eroject Manager SRF Review: Quaitrax 1D 69614 Date: Date: Page 1 of 2 Page 53 of 69 ,'-pace - Effective Date: 11/14/2022 `Check mark top half of box if pH and/or dechlorination is verified and project N within the acceptance range for preservation samples. Exceptions- VOA, Colilorm, TOC, Oil and Grease, ORO/Bois Iwaterl DOC. Wig "Bottom hall of box is to list number of bottles 'Check all unpreserved Nitrates for chlorine _ I v ro m u v 2 V v `r p u x A v xo w X ? a P O y d z w v u a E.' IX = Q a q n n > a m m u A a a J E E WI C3 E a .� _ m m 6 ' M = N 2 ` r0 N R ro ' n E a ro v a g a ° E E 4 J d Q E m E E E a d `v p _ _ ry rNv 3 7 ,n Z rir m 4 7 X ry a a a •• rn a. a 0. V V V m m m m m m I Q d ,y a Z N U S z Z U A 4 E L E A r� d Q C E .r E O p O Q J Q 7 7 E v E E E E e O O O 8 O v a yr K a s r m i m e m m m V t'J V V V V V Q d d O O } > y q r] i E O a ] m 17 O t1 z A d _ O 7 n Y n m ac V ? y y iy C C v, ri n ¢ N E E c of E ry N O o r- r at ta n ry m o `� t9 N N m Q S E Q E 0 rn O 3 — N IL s � i 7 F 10 it 12 E 'LL pH Adjustment Log for Preserved Samples sample to I Type or Preservative pit upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot tf II adjust-d I added Note- Whenever there is adisrrepancyalfectingfJorthCarohaacompliance simples,acopy ofthis form wda lbeserllotheNorthCaralu,DENRCcrtAcalronolhcor lr. Out of hold, incorrect preservallvc, opt of temp, incorrect containers. Ouallrax ID: 69614 Page 2 of 2 Page 54 of 69