8106_DukeCliffside_Q42023_SemiAnnual Report_FID1830027_20230213

DENR USE ONLY ❑Paper Report [-]Electronic Data - Email CD (data loaded: Yes / No Doc/Event #:
NC DENR I I Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
• Prepare one form for each individually monitored unit.
• Please type or print legibly.
• Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 213 surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
• Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
• Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
• Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
SynTerra Corporation (Consultant)
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Scott Spinner
E-mail: [e-mail]
Phone: [phone]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Duke Energy Carolinas, LLC 573 Duke Power Road 8106 .0500 October 18, 2023
Roger's Energy Complex Mooresboro, North Carolina
Cliffside Steam Station
CCP Landfill
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring ® Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells ❑
Leachate monitoring data
Surface water monitoring data ❑
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Scott Spinner
Project Manager
Facility R tive Na me (P) Title
2/7/2024
Signature Date
148 River Street, Suite 220, Greenville, SC 29601
Facility Representative Address
C-1478 / North Carolina Geological Corporation Number C-387
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009
[phone]
(Area Code) Telephone Number
Affix NC Licensed/ Professional Geologist Seal
ep�as�a=CCnn���apeag
SM
2243
1 11�j9

REPORT VERIFICATION
PROJECT: SEMIANNUAL WATER QUALITY MONITORING REPORT
OCTOBER 2023 SAMPLING EVENT
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
CCP LANDFILL PHASES I THROUGH IV
f»N1 1Ioil low-301.1
TITLE: OCTOBER 2023 SAMPLING EVENT
This document has been reviewed for accuracy and quality commensurate with the intended
application.
Prepared by: Date: February 7, 2024
Trevor Ludwick
Approved by: 1W Date
Scott Spinner
Project Manager: Scott Spinner, NC LG
February 7, 2024
Licensed Geologist Seal:
SynTerra
148 River Street, Suite 220
Greenville, SC 29601
North Carolina Geological Corporation Number C-387

17
Terra Science &Engineering Consultants
synsynterracorp.com
SEMIANNUAL
WATER QUALITY MONITORING REPORT
OCTOBER 2023 SAMPLING EVENT
CCP LANDFILL PHASES I THROUGH IV
PERMIT No. 8106)
CLEVELAND AND RUTHERFORD COUNTIES
ROGERS ENERGY COMPLEX — CLIFFSIDE STEAM STATION
573 DUKE POWER ROAD
MOORESBORO, NORTH CAROLINA
FEBRUARY 7, 2024
PREPARED FOR
r� DUKE
ENERGY,:
CAROLINAS
DUKE ENERGY CAROLINAS, LLC
to 1-e.'f "-
Kathryn W. Webb
Senior Peer Reviewer
j
Trevor Ludwick
Project Scientist
Scott Spinner, NC LG #2243
Project Manager

Semiannual Water Quality Monitoring Report — October 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
TABLE OF CONTENTS
SECTION PAGE
1.0
INTRODUCTION AND BACKGROUND..........................................................................1-1
1.1
Site and Landfill Information......................................................................................1-1
1.2
Hydrogeologic Setting................................................................................................1-1
1.3
Landfill Semiannual Monitoring Program...................................................................1-2
2.0
METHODS..................................................................................................................
2-1
2.1
Sampling and Analysis Methods.................................................................................2-1
2.2
Regulatory Criteria.....................................................................................................2-2
2.3
Statement of Work.....................................................................................................2-2
3.0
RESULTS.....................................................................................................................3-1
3.1
Site Groundwater Flow...............................................................................................3-1
3.2
Analytical Results.......................................................................................................3-1
3.3
Quality Assurance/Quality Control.............................................................................3-2
4.0
REFERENCES...............................................................................................................4-1
February 2024 Page i
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — October 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
LIST OF FIGURES
Figure 1
Site Location Map
Figure 2
Sample Location Map
Figure 3A
Groundwater Level Map — Surficial Flow Zone — October 2023
Figure 3B
Groundwater Level Map — Bedrock Flow Zone — October 2023
LIST OF TABLES
Table 1 Monitoring Location Summary
Table 2 Well Construction Summary
Table 3 Groundwater, Surface Water, and Leachate Monitoring Parameters
Table 4 Groundwater Seepage Velocities
Table 5 Field Data Parameters
Table 6 Leachate Field Results and Analytical Detections
Table 7 Groundwater Field Results and Analytical Detections
Table 8 Field and Analytical Results Equal to or Greater Than Groundwater Quality
Standards
Table 9 Surface Water Field Results and Analytical Detections
Table 10 Field and Analytical Results Equal to or Greater Than Surface Water Quality
Standards
LIST OF APPENDICES
Appendix A Field Sampling Forms
Appendix B Laboratory Report and Chain -of -Custody Forms
February 2024 Page H
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — October 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
LIST OF ACRONYMS
µg/L
micrograms per liter
02L standards
Title 15A NCAC 02L .0202(g) Groundwater Quality Standards
02B standards
Title 15A NCAC 02B .0200 Surface Water and Wetland standards
CCP
coal combustion products
CCR
coal combustion residuals
Cliffside
Cliffside Steam Station
Duke Energy
Duke Energy Carolinas, LLC
DWM
Division of Waste Management
EDD
electronic data deliverable
HDPE
High -density polyethylene
ISTV
in -stream target value
landfill
CCP Landfill Phases I through IV
mg/L
milligrams per liter
NCAC
North Carolina Administrative Code
NCDEQ
North Carolina Department of Environmental Quality
NRWQC
National Recommended Water Quality Criteria
QA
Quality Assurance
QC
Quality Control
Site
Cliffside Steam Station
SW
Solid Waste
USEPA
U.S. Environmental Protection Agency
WQMP
Water Quality Monitoring Plan
February 2024 Page iii
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — October 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
"KIMI►1f :1�]1�I� [�]►I_1 Ll:�_1�l:t�l:%1�1►L
This semiannual report pertains to the Duke Energy Carolinas, LLC (Duke Energy) Rogers Energy
Complex — Cliffside Steam Station (Cliffside or Site) Coal Combustion Products (CCP) Landfill
(landfill) and documents the results of the October 2023 groundwater, surface water, and
leachate monitoring event.
1.1 Site and Landfill Information
Duke Energy owns and operates Cliffside, located at 573 Duke Power Road in Mooresboro,
North Carolina (Figure 1).
The CCP Landfill has been developed in four Phases (Phases I through IV) and comprises a total
area of approximately 71.7 acres. The CCP Landfill currently accepts coal combustion residual
(CCR) material generated during coal fired power generation and other CCR disposal needs for
the Site, which includes excavated CCR materials from the on -Site ash basins. The landfill
includes a liner system consisting of two geosynthetic barrier components (a 60-mil High -
density polyethylene (HDPE) geomembrane and a geosynthetic clay liner) between waste and
the groundwater beneath the landfill (SynTerra, 2022).
1.2 Hydrogeologic Setting
The Site is located in the Inner Piedmont Belt of the Piedmont Physiographic Province. The
Piedmont Physiographic Province in North Carolina is characterized by gentle to steep, hilly
terrain with small quantities of alluvium. The Inner Piedmont is bounded on the northwest by
the Brevard Fault zone, on the southeast by the Kings Mountain Belt, and by the faults and
shear zones that define the central Piedmont structure.
As typical in the Piedmont region, groundwater is present within the residuum, saprolite,
partially weathered rock, and fractured bedrock beneath the CCP Landfill. In general, surface
drainage from the CCP Landfill flows from the west to the north towards Duke Power Road, and
to the south and east toward Suck Creek. The highest elevations at the landfill are along the
western edge of the landfill.
Two streams are near the CCP Landfill. Suck Creek is located approximately 1,200 feet
southeast of the landfill and flows north to the Broad River. An unnamed tributary to the Broad
River is located approximately 1,100 feet west of the landfill. Surface waters draining to the
Broad River are classified as WS-IV per Title 15A, North Carolina Administrative Code (NCAC)
Subchapter 02B, .0200 Surface Water and Wetland standards (02B standards). Based on
evaluation of local topography, shallow groundwater beneath the landfill liner is expected to
discharge to Suck Creek and the unnamed tributary.
The landfill and surrounding topographic and physiographic features are shown on Figure 2.
February 2024 Page 1-1
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — October 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
1.3 Landfill Semiannual Monitoring Program
The October 2023 sampling event and this Semiannual Water Quality Monitoring Report
comply with Revision 0 of the Water Quality Monitoring Plan, (WQMP; SynTerra, 2022)
submitted to the North Carolina Department of Environmental Quality (NCDEQ) Division of
Waste Management (DWM), Solid Waste (SW) Section on March 31, 2022. The WQMP was
subsequently approved by the DWM on April 4, 2022. The landfill semiannual monitoring
program, described in detail in the WQMP, consists of 17 groundwater, 3 surface water, and 2
leachate monitoring locations listed in Table 1 and shown on Figure 2. A summary of
monitoring well construction information is presented in Table 2 and analytical parameter
coverage for the landfill semiannual monitoring program, updated in March 2023, is
summarized in Table 3.
February 2024 Page 1-2
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — October 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
2.0 METHODS
2.1 Sampling and Analysis Methods
On October 18, 2023, Pace Analytical Services personnel (North Carolina Field Certification
#5342) performed groundwater, surface water, and leachate sampling in accordance with the
North Carolina SW Management Guidelines. Copies of the field sampling forms are included in
Appendix A. Duke Energy Analytical Laboratory (North Carolina Laboratory Certification #248)
analyzed the reported parameters and constituents. The laboratory report and chain -of -
custody forms are included in Appendix B.
Duke Energy developed a list of parameters and constituents using guidance from the NCDEQ
DWM, SW Section. The samples were analyzed using the updated parameter and constituent
list, approved by NCDEQ on March 20, 2023. In addition, surface water samples will be
analyzed for dissolved selenium. The monitoring parameters, U.S. Environmental Protection
Agency (USEPA) SW-846 analytical methods, and applicable groundwater and surface water
standards are presented in Table 3.
In addition to 02B standards for surface water, Duke Energy provides comparisons against in -
stream target values (ISTV) and USEPA National Recommended Water Quality Criteria
(NRWQC). The ISTV comparison is conducted with the qualification that an exceedance of the
published value is not necessarily a violation of the water quality standard for toxicity. As stated
by the USEPA, NRWQC standards do not constitute regulations, nor do they impose a legally
binding requirement. Therefore, comparisons with ISTV and USEPA NRWQC criteria are for
screening purposes only.
Additional information regarding surface water standards and screening criteria are presented
in Table 3 and outlined below:
• Several 02B standards and ISTV require sampling methods specific to acute or chronic
concentrations and are not applicable to the grab sample method; however acute
standards are considered more applicable to grab sampling and are included for
screening purposes only.
• Hardness -dependent standards require sampling methods specific to acute or chronic
concentrations and are not applicable to the grab sample method. Duke Energy will use
a standard hardness of 25 milligrams per liter (mg/L) for screening purposes only;
however, if the in -stream hardness values for a given sampling event are substantially
less than or greater than 25 mg/L, the minimum in -stream hardness value will be used
to calculate the hardness -dependent standard to more accurately screen analytical
results.
February 2024 Page 2-1
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — October 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
• The 02B surface water standards for chromium are based upon speciation for dissolved
trivalent and hexavalent chromium. Duke Energy will sample for total and dissolved
total chromium. Results will be screened to the dissolved trivalent 02B standard; this
standard is also a hardness dependent, acute standard and will be based on 25 mg/L
hardness and used for screening purposes only.
• The 02B surface water standard for mercury represents a total concentration and is not
for acute, chronic, or hardness -dependent concentrations. The mercury 02B standard
for Class B, C, and water supply waters is 0.012 micrograms per liter (µg/L). Duke Energy
will use the analytical method USEPA 245.1/SW 7470A for mercury analysis, which has a
reporting limit of 0.050 µg/L and is greater than the 02B criteria of 0.012 µg/L.
2.2 Regulatory Criteria
Evaluation of the semiannual monitoring analytical results are compared to the following
regulatory criteria:
Groundwater
• 15A NCAC 02L .0202(g) Groundwater Quality standards (02L standards)
Surface Water
• 15A NCAC 02B .0200 Surface Water and Wetland standards (0213 standards)
Leachate
• Not compared to water quality standards
2.3 Statement of Work
The following tasks were completed for semiannual water quality monitoring:
• Groundwater, surface water, and leachate samples were collected by Pace Analytical
Services on October 18, 2023.
• Reviewed the laboratory analytical results pertaining to the parameters listed in Table 3.
• Compared groundwater analytical results to 02L standards and historical concentration
ranges.
• Compared surface water analytical results to 02B standards and historical concentration
ranges.
• Developed generalized groundwater surface contour maps using groundwater elevation
data from the October 2023 monitoring event (October 18, 2023) and a Site -wide water
level sweep conducted on October 16, 2023.
February 2024 Page 2-2
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — October 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
• Calculated groundwater flow velocities based on groundwater elevations at wells
perpendicular to groundwater flow.
• Converted the laboratory provided electronic data deliverable (EDD) to the format
requirements of the NCDEQ DWM EDD template and submitted copies of EDDs to the
NCDEQ DWM with this report.
• Prepared and submitted this Semiannual Water Quality Monitoring Report.
February 2024 Page 2-3
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — October 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
3.1 Site Groundwater Flow
The predominant direction of groundwater flow at the Site is north toward the Broad River,
with a portion of groundwater in the central part of the Site flowing toward Suck Creek and
then north to the Broad River. Groundwater beneath CCP Landfill predominantly flows east or
southeast toward Suck Creek, with a portion of the groundwater flowing north/northeast
toward the Broad River or northwest toward an unnamed tributary of the Broad River.
Generalized groundwater elevation contours and groundwater flow direction arrows in the
vicinity of the CCP Landfill are shown on Figure 3A for the surficial flow zone (shallow and deep
flow zones) and Figure 3B for the bedrock flow zone. These contours were developed by
calculating groundwater elevations in each monitoring well using depth -to -water -level
measurements taken during the October 2023 monitoring event (October 18, 2023) or a Site -
wide water level sweep conducted on October 16, 2023. Depth -to -water -level measurements
taken during the Site -wide water level sweep were used to calculate groundwater elevations
for monitoring wells CCR-CCPBG-1D, CCPMW-2S, and CCPMW-7 only. Depth -to -water
measurements and calculated groundwater elevations are presented in Table 2. Calculated
groundwater seepage velocities are presented in Table 4. Calculated groundwater elevations,
based on depth -to -water measurements gauged during the October 2023 monitoring event and
the Site -wide water level sweep, indicate groundwater at the landfill generally flows to the
east/southeast, consistent with historical Site observations.
3.2 Analytical Results
A summary of the groundwater, surface water, and leachate field data is presented in Table S.
Analytical results and reference comparisons discussed below are summarized in Table 6
through Table 10. Sample locations are depicted on Figure 2.
Leachate
Leachate samples were collected from two discharge points (CCP-Leachate and CCP-Leachate-
34) located at the leachate pond. Analytical results are presented in Table 6. Leachate analytical
results are not compared to groundwater (02L) or surface water (0213) quality standards and are
provided for informational purposes only.
Groundwater Results
Field and analytical results for the collected downgradient and background groundwater
samples are presented in Table 7. Groundwater analytical results are compared with 02L
standards. Constituent concentrations equal to or greater than 02L standards are noted in
Table 7 by bold font and grey highlighted cells. The laboratory analytical reports are included as
Appendix B. A summary of the groundwater field and analytical results that are equal to or
greater than comparison criteria are presented in Table 8. Note that for pH, the 02L standard is
February 2024 Page 3-1
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — October 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
a range of values, so pH results outside of the range would be highlighted and bolded in Table 7
and included in Table 8. Constituent concentrations in Table 7 which are identified as being
equal or greater than their applicable comparative criteria (or outside the comparative criteria
range for pH) are not attributed to a release from the CCP Landfill.
Groundwater samples were not collected from monitoring wells CCPMW-3S, CCPMW-8, or
CCPTW-2 during the October 2023 monitoring event due to insufficient water volume in the
wells. Monitoring well CCPMW-8 has not had sufficient water in the well to collect a sample for
three consecutive semiannual water quality monitoring events. Monitoring wells CCPMW-3S
and CCPTW-2 have not had sufficient water to collect samples during the last four semiannual
water quality monitoring events. An updated WQMP is planned to be prepared in 2024. An
evaluation to determine if those wells are viable to be included in the monitoring network or if
additional monitoring wells are needed is ongoing and the results of that evaluation will be
communicated to the NCDEQ. The agreed upon updated water quality monitoring network
would be included in the updated WQMP.
Surface Water
Field and analytical results for surface water samples are presented in Table 9. The sample
locations are depicted on Figure 2. Analytical results for surface water samples are compared
with applicable 02B Class WS-IV regulatory surface water standards. Constituent concentrations
greater than applicable 02B standards are noted in Table 9 by bold font and grey highlighted
cells. A summary of surface water analytical results equal to or greater than applicable 02B
comparison criteria is presented in Table 10. Note that for pH, the 02B standard is a range of
values, so pH results outside of the range would be highlighted and bolded in Table 9 and
included in Table 10.
Additionally, analytical results for surface water samples are compared with the screening
criteria discussed in Section 2.1. Constituent concentrations equal to or greater than the
screening criteria are noted in Table 9 by cells with only bold font for informational purposes
only.
3.3 Quality Assurance/Quality Control
Field -performed quality assurance and quality control (QA/QC) consisted of the collection and
analysis of field blanks to evaluate if contamination was imparted to the samples by the sample
container, preservative, or other exogenous sources. A field duplicate sample was also collected
to estimate sampling and laboratory precision.
Select samples were diluted, as is normal laboratory practice, to bring samples within the
calibrated range of the analysis. Specifics regarding the samples that were diluted, including the
dilution amount, are reported in the EDD and in the lab report. Additional QA/QC data,
laboratory analyses, and chain -of -custody forms are included in Appendix B.
February 2024 Page 3-2
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — October 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
L111=04=440["i
SynTerra. (Rev 0, 2022). Water Quality Monitoring Plan, Rogers Energy Complex — Cliffside
Steam Station CCP Landfill Phases I Through IV, March 2022.
February 2024 Page 4-1
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — October 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
FIGURES
L7
synTerra
Science & Engineering Consultants

�• 1
41
DUKE ENERGY CAROLINAS . `'♦ •
PROPERTY BOUNDARY ♦• ■
` FORMER UNITS 1-4 ASH BASIN
♦ /WASTE BOUNDARY
/ UNIT 5 `♦//
POWER
PLANT,,,,,,
LANT Broth: l�"
UNIT 5 INACTIVE ASH BASIN
WASTE BOUNDARY UNIT 6 `' ■
POWER ■
PLANT ACTIVE ASH BASIN
■
■ ,_ ■ �. = WASTE BOUNDARY
CCP LANDFILL
WASTE BOUNDARY
■ • I
♦♦fir �..� i
■
0 L
Q
j1
�0 �P(,
NOTES: e f o
1. ALL BOUNDARIES ARE APPROXIMATE. x,
2. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY /
CAROLINAS. j
3. USGS TOPOGRAPHIC MAP OBTAINED FROM ESRI ARCGIS t
ONLINE BASEMAP SERVICE, LAST UPDATED APRIL 2023.
FIGURE 1
DUKE
SITE LOCATION MAP
SEMIANNUAL WATER QUALITY MONITORING REPORT
ENERGY
ENER
WINSTONSALEM
CCP LANDFILL PHASES I THROUGH IV
;`
CAROLINASHEVI'lE
CHARLOTTE
PERMIT NO. 8106-INDUS
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
MOORESBORO, NORTH CAROLINA
RUTHERFORD CLEVELAND
DRAWN By B MCCANN DATE:10/20/2022
GRAPHIC SCALE
COUNTY COUNTY
REVISED BY L FOREMAN DATE: 12/13/2023
CHECKED BY TLUDWICK DATE 12/13/2023
0 500 1,000 2,000 3,000
synTerra
SPINNER
APPROVED BV_S. SPINNER DATE-12/13/2023
www_svnterracorp.com
NFEET)
PROIECTMANAGER 5 SPINNER

' - ^'� • r., �a - _ MW-5
� ■CCPMW-4 —,,� S• 1* .* .a
CCPMW-6S/D
S.
a � - `=.��' �' •",w CCPMW-7
CCPMW-1 S/D • •
■ 1 . „ { •
m g3 .
rho 0
* CCR CCPBG-1 D/BR $90 CCPTW-2 n
. - — « . • CCPMW-8 CCPMW 11 :' •� •Ail <
. _ • .0001.
• ` '' CCPMW-2S/D CCPMW-3S/D '.
■ • .��•.!, CCPMW-10 / 1}
' - +..
� ,� • •• ��,.� ,� ,. t �. _' . LEGEND
A, � SOLID WASTE SECTION MONITORING WELL
Nc. ' / ,. ,y�1 VV A
r SOLID WASTE SECTION BACKGROUND MONITORING WELL
0 / 1 SURFACE WATER SAMPLE LOCATION
+ • � ,� 1 �'' � LEACHATE SAMPLE LOCATION
ti - ,M • . _Ito — LANDFILL COMPLIANCE BOUNDARY
— LANDFILL REVIEW BOUNDARY
4 ■ ' ' 'I�s�r+ •�� _ +� r t LANDFILL LIMIT OF WASTE
e ASH BASIN WASTE BOUNDARY
IL _ % ,
DUKE ENERGY CAROLINAS PROPERTY BOUNDARY
;r, r
•(i! ti > STREAM (AMEC NRTR)
o,' WETLANDS (AMEC NRTR)
TOPOGRAPHY CONTOUR (10' INTERVAL)
•'it • -,i :�, FWjL, • - . L 1� NOTES:
• * T"' 1. THE WATERS OF THE US DELINEATION HAS NOT BEEN APPROVED BY THE
US ARMY CORPS OF ENGINEERS AT THE TIME OF THE MAP CREATION. THIS MAP
IS NOT TO BE USED FOR JURISDICTIONAL DETERMINATION PURPOSES. THE
WETLANDS AND STREAMS BOUNDARIES WERE OBTAINED FROM STREAM AND
WETLAND DELINEATION CONDUCTED BYAMEC FOSTER WHEELER ENVIRONMENTAL AND
ti INFRASTRUCTURE, INC. NATURAL RESOURCE TECHNICAL REPORT (NRTR) FOR CLIFFSIDE
' STEAM STATION, JUNE 2015.
2. ALL BOUNDARIES ARE APPROXIMATE.
3. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY CAROLINAS.
■.,�,.' y
! y 4. AERIAL IMAGERY IS COMBINATION OF DUKE ENERGY PROPELLER PHOTOGRAPHY
COLLECTED ON OCTOBER 23, 2023, GOOGLE EARTH AERIAL PHOTOGRAPHY COLLECTED
�L - _ 1• ON JUNE 8, 2022 AND AERIAL PHOTOGRAPHY PROVIDED BY ESRI, COLLECTED ON APRIL 2,
2020.
5. DRAWING HAS BEEN SET WITHAPROJECTION OF NORTH CAROLINA STATE
y i• — PLANE COORDINATE SYSTEM FIPS 3200 (NAD83).
_ / GRAPHIC SCALE
4' / • . ;�: ' DUKE 340 0 340 680 FIGURE 2
' ENERGY
SAMPLE LOCATION MAP
CAROLINAS
(IN FEET)
SEMIANNUAL WATER QUALITY MONITORING REPORT
•� -
+
DRAWN BYC WYATT
DATE: 10/20/2022
CCP LANDFILL PHASES I THROUGH IV
REVISED BY L FOREMAN
DATE: 12/13/2023
PERMIT NO. 8106-INDUS
>''�•
CHECKED BY. T. LUDWICK
DATE: 12 13 2023
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
APPROVED BY S-SPINNER
PROJECTMANAGER s SPINNER
DATE 12/13/2023
MOORESBORO, NORTH CAROLINA
", 111 �� ••"
synTerm
..
www.s nterracor
.corn
P_\OARCGIS PRO PROJECTS\DUKE_ENERGY\CLIFFSIDE\2023\SEMIANNUAL_ WATER_ QUALITY_ MONITOR I NG_REPORT\SEMIANNUAL_ WATER -QUALITY _MONITORING_REPORTAPRX

9! 4
1 1 % ,
Av
7v
J.n 2 a
It
to t a ,
- r1
♦ ■ ` •, CCPMW-65 ♦ s 1 - Y� } ' t
815.11 • ►� '�1 jr ��' p
■
+ tom, � �!� t ♦ � � �♦ � `_.v.� • -,,, y w �.� �"1", ,� Q+yf �'r�
j
T 1
•
44
812.19
i
DUKE POWER R=__--
1 � � ----- y1� �Rr t,F�, ram. `-.r rr�-•
CCPMW-1S ` , ♦•ram
v '
.838.95
LEGEND
1
+y F'y ✓ , / T " + V ■ SOLID WASTE SECTION MONITORING WELL
k
SOLID WASTE SECTION BACKGROUND MONITORING WELL
INFERRED GROUNDWATER ELEVATION CONTOUR (FEET)
GROUNDWATER FLOW DIRECTION
LANDFILL COMPLIANCE BOUNDARY
_� r�lr / r r ■ ■ - - - LANDFILL REVIEW BOUNDARY
i ��_ _' 6 -j ■ ■ LANDFILL LIMIT OF WASTE
' ` 1 ' / / ■ ■ ASH BASIN WASTE BOUNDARY
r /'` ' / / ''�• j , 1 1 DUKE ENERGY CAROLINAS PROPERTY BOUNDARY
TOPOGRAPHY CONTOUR (10' INTERVAL)
�� ' o ■ --� STREAM (AMEC NRTR)
fit
w;� WETLANDS (AMEC NRTR)
_ _,��� , ' / r / r ■ NOTES
'°°� j / / / _ / ! ■ / ' 1. WATER LEVELS FOR MONITORING WELLS CCR-CCPBG-1D, CCPMW-2S, AND CCPMW-7 WERE GAUGED ON OCTOBER 16, 2023. ALL OTHER WATER LEVELS WERE GAUGED ON �,. ■ OCTOBER 18 2023.
2. BTOP - BELOW TOP OF PUMP
/ / / •" /`/ - /' I _ _ '�"'� 3. ELEVATIONS ARE REFERENCED TO THE NORTH AMERICAN VERTICAL DATUM OF 1888
' - ` + - — - _ J / �, _ .'f • / . . - - (NAVD 88)-
4. WAT / /' - - j -" - THE ER OF THE US DELINEATION HAS NOT BEEN APPROVED BY THE US ARMY
CCR-CCPBG-1 D I
, / +- - CORPS OF ENGNEERS AT THE TIME OF THE MAP CREATION. THIS MAP IS NOT TO BE USED
841.93 , /' +� / FORJURISDICTONALDETERMINATIONPURPOSES- THEWETLANDSANDSTREAMS
BOUNDARIES WERE OBTAINED FROM STREAM AND WETLAND DELINEATION CONDUCTED BY
r-^ir vo 7CCPMW-2 I + _ t;' AMEC FOSTER WHEELER ENVIRONMENTALAND INFRASTRUCTURE, INC. NATURAL
BTOP ♦ / CCPMW-11 RESOURCE TECHNICAL REPORT (NRTR) FOR CLIFFSIDE STEAM STATION, JUNE 2015.
CCPMW-8
■ _ `L ' r - A - _ / - - ♦ 5. ALL BOUNDARIES ARE APPROXIMATE.
�Y DRY777.63 m . i
Q � 6. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY CAROLINAS-
,. ♦ �° �= CCPMW-3S • . F
• + . O - r - — r �, -�:+ - • i ` 7. AERIAL IMAGERY IS A COMBINATION OF DUKE ENERGY PROPELLER PHOTOGRAPHY
�+,� ♦-- r - - DRY I — �' r - — - — _ _ r •- +�.-- "F Jl COLLECTED ON OCTOBER 23, 2023AND GOGGLE EARTH AERIAL PHOTOGRAPHY
M a ^� /3`• ~- CCPMW-10 COLLECTED ON JUNE 8, 2022.
y' �♦ CCPMW-2S _ �• A� 777,03 .� tom.
�y .`
?� •� 54 s "� 801.49 , r a / • C DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE
*• ` - r • ` � w r . � - COORDINATE SYSTEM FIPS 3200 (NAD83).
GRAPHIC SCALE FIGURE 3A
DUKE 150 0 150 soo r' GROUNDWATER LEVEL MAP - OCTOBER 2023
ENERGY® CAROLINAS
(IN FEET) SURFICIAL (SHALLOW AND DEEP) FLOW ZONE
DRAWNBYR_MCGANN DATEJ0/20/2022 SEMIANNUAL WATER QUALITY MONITORING REPORT
REVISED RYLFOREMAN DATE02/05/2024 CCP LANDFILL PHASES I THROUGH IV
. �' CHECKED BY T LUDWICK DATE=02/05/2024 PERMIT NO. 8106-INDUS
' APPROVED BY S SPINNER DATE02/05/2024 ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
synTerl d PROJECT MANAGER 5 SPINNER
MOORESBORO, NORTH CAROLINA
1:.
www.svnterracoro.com

1524
r �0
�l - ` ,♦� CCPMW-6D �0
� ar'
` ♦ ` 850
e5n
♦ I ♦%840
♦♦
♦ , I -
amiggla
01
Q W t I � P, ` fir... SS���, :. ♦•
1 y '
• � � � CCPMW-1 D id ! , ,. ► c
wl
i
' 4 ,A
I
Ar
77
■# CCR-CCPBG-1BR
� I `..� 835.3340
'•.! 6CPMW-2D - - °
—.
179990
O _ / _ (,I�y•A�.r.-.r.i CCPMW-'A ,! ■�: ,_ yw�.. r _
lb 79073
i
_ ✓ .,. � �'� � _ -ii - -r ft830ir. `'O -< �r"i« _ 830
i��,p y `' +� f } s•L i'"N�; ., - oeaMs O � � . — - - � - ez � . � _- ego s�o >'"a
M"f,• M; _ r, i $.yo "`fir, GRAPHIC SCALE
DUKE 150 0 150 300
fun ENERGY® Ilk ! • = CAROLINAS (IN FEE )
DRAWN BY B- MCGANN DATE = 10/26/2022
y
w��� - r �KT • REVISED BY_ L FOREMAN DATE 02/05/2024
CHECKED BY TL UDWICK DATE-02/05/2024
APPROVED BY S-SPINNER DATE_02/05/2024
' PJAGER-S SPINNER
iTe PROJECT MA WWWSVDLP.Pf73COID CORI
• y a ��
LEGEND
SOLID WASTE SECTION MONITORING WELL
® SOLID WASTE SECTION BACKGROUND MONITORING WELL
—► GROUNDWATER FLOW DIRECTION
INFERRED GROUNDWATER ELEVATION CONTOUR (FEET)
- - - LANDFILL COMPLIANCE BOUNDARY
- - LANDFILL REVIEW BOUNDARY
LANDFILL LIMIT OF WASTE
ASH BASIN WASTE BOUNDARY
DUKE ENERGY CAROLINAS PROPERTY BOUNDARY
TOPOGRAPHY CONTOUR (10' INTERVAL)
--i• STREAM (AMEC NRTR)
® WETLANDS (AMEC NRTR)
NOTES:
1. WATER LEVELS WERE GAUGED ON OCTOBER 18 2023.
2. ELEVATIONS ARE REFERENCED TO THE NORTH AMERICAN VERTICAL DATUM OF 1988 (NAVD
88).
3. THE WATERS OF THE US DELINEATION HAS NOT BEEN APPROVED BY THE US ARMY CORPS OF
ENGINEERS AT THE TIME OF THE MAP CREATION. THIS MAP IS NOT TO BE USED FOR
JURISDICTIONAL DETERMINATION PURPOSES. THE WETLANDS AND STREAMS BOUNDARIES
WERE OBTAINED FROM STREAM AND WETLAND DELINEATION CONDUCTED BY AMEC FOSTER
WHEELER ENVIRONMENTAL AND INFRASTRUCTURE, INC. NATURAL RESOURCE TECHNICAL
REPORT (NRTR) FOR CLIFFSIDE STEAM STATION, JUNE 2015.
4 ALLBOUNDARIES ARE APPROXIMATE
5. PROPERTY BOUNDARY PROVIDEO BY DUKE ENERGY CAROLINAS.
6 AERIAL IMAGERY IS A COMBINATION OF DUKE ENERGY PROPELLER PHOTOGRAPHY
COLLECTED ON OCTOBER 23, 2023 AND GOGGLE EARTH AERIAL PHOTOGRAPHY COLLECTED ON
JUNE 8, 2022.
7. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE
COORDINATE SYSTEM RES 3200 (NAD83).
FIGURE 3B
GROUNDWATER LEVEL MAP - OCTOBER 2023
BEDROCK FLOW ZONE
SEMIANNUAL WATER QUALITY MONITORING REPORT
CCP LANDFILL PHASES I THROUGH IV
PERMIT NO. 8106-INDUS
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
MOORESBORO, NORTH CAROLINA

Semiannual Water Quality Monitoring Report — October 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
TABLES
L7
synTerra
Science & Engineering Consultants

TABLE 1
MONITORING LOCATION SUMMARY
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Media
Monitoring Location ID
Comments
CCR-CCPBG-1BR*
CCR-CCPBG-1BR was installed to monitor background groundwater and is located southwest and upgradient of the landfill.
CCR-CCPBG-1D*
CCR-CCPBG-1D was installed to monitor background groundwater and is located southwest and upgradient of the landfill.
CCPMW-IS*
CCPMW-IS was installed to monitor background groundwater and is located west and upgradient of the landfill.
CCPMW-1D*
CCPMW-1D was installed to monitor background groundwater and is located west and upgradient of the landfill.
CCPMW-2S
CCPMW-2S was installed for assessment, is located south and downgradient of the landfill.
CCPMW-2D
CCPMW-2D was installed for assessment, is located south and downgradient of the landfill.
CCPMW-3S
CCPMW-3S was installed for assessment, is located south and downgradient of the landfill.
CCPMW-3D
CCPMW-3D was installed for assessment, is located south and downgradient of the landfill.
Groundwater
CCPMW-4
CCPMW-4 was installed for assessment, is located northwest and downgradient of the landfill.
CCPMW-5
CCPMW-5 was installed for assessment, is located north and downgradient of the landfill.
CCPMW-6S
CCPMW-6S was installed for assessment, is located north and downgradient of the landfill.
CCPMW-6D
CCPMW-6D was installed for assessment, is located north and downgradient of the landfill.
CCPMW-7
CCPMW-7 was installed for assessment, is located north and downgradient of the landfill.
CCPMW-8
CCPMW-8 was installed for assessment, is located south and downgradient of the landfill.
CCPMW-10
CCPMW-10 was installed for assessment, is located south and downgradient of the landfill.
CCPMW-11
CCPMW-11 was installed for assessment, is located southeast and downgradient of the landfill.
CCPTW-2
CCPTW-2 was installed for assessment, is located south and downgradient of the landfill.
CCPSW-1
CCPSW-1 surface water monitoring location is south and upgradient of the landfill.
Surface Water
CCPSW-2
CCPSW-2 surface water monitoring location is east and downgradient of the landfill.
CCPSW-3
CCPSW-3 surface water monitoring location is west and downgradient of the landfill.
Leachate
CCP-Leachate
Leachate sample, representing leachate from Phases 1 and 2 of the landfill, collected from an in -line sampling point south and
downgradient of the landfill.
CCP-Leachate-34
Leachate sample, representing leachate from Phases 3 and 4 of the landfill, collected from an in -line sampling point south and
clowngradient of the landfill.
Note:
See Table 2 Well Construction Summary for monitoring well construction information.
* - Indicates background groundwater monitoring well.
CCP - Coal combustion products
Prepared by: TWL Checked by: CS
Page 1 of 1

TABLE 2
WELL CONSTRUCTION SUMMARY
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Well ID
Date
Installed
Flow Zone
Material
Diameter
(Inches)
Latitude
(degrees)
Longitude
(degrees)
Well Depth
(ft, BTOC)
Screened
Interval
(ft, BGS)
Measuring
Point TOC
(ft, NAVD 88)
Ground
Surface
(ft, NAVD 88)
Groundwater
Elevation
(ft, NAVD 88)
Depth
to Water
(ft, BTOC)
CCR-CCPBG-1D*
7/17/2020
Deep
PVC
2
35.203856335
-81.775968875
50.74
43.0 - 48.0
889.28
886.26
841.93
47.35
CCR-CCPBG-1BR*
7/23/2020
Bedrock
PVC
2
35.203831869
-81.775968852
98.75
91.0 - 96.0
889.02
886.52
835.33
53.69
CCPMW-1S*
2/23/2010
Deep
PVC
2
35.206702100
-81.774304900
42.45
30.0 - 40.0
875.58
873.24
838.95
36.63
CCPMW-1D*
2/24/2010
Bedrock
PVC
2
35.206713399
-81.774299699
56.95
49.0 - 54.0
875.89
873.33
838.09
37.80
CCPMW-2S
2/24/2010
Shallow
PVC
2
35.203550900
-81.772735000
44.30
32.0 - 42.0
842.24
840.26
801.49
40.75
CCPMW-2D
2/24/2010
Bedrock
PVC
2
35.203552399
-81.772721900
72.80
65.0 - 70.0
842.35
840.20
799.90
42.45
CCPMW-3S
6/27/2007
Shallow
PVC
2
35.203409300
-81.771019100
15.29
9.0 - 14.0
811.56
810.56
796.44 (Eff. Dry)
15.12
CCPMW-3D
7/16/2007
Bedrock
PVC
2
35.203408701
-81.771000500
35.41
26.0 - 31.0
811.74
810.47
790.73
21.01
CCPMW-4
10/26/2015
Bedrock
PVC
2
35.208929900
-81.774815100
68.31
50.0 - 65.0
845.95
843.29
817.07
28.88
CCPMW-5
10/23/2015
Bedrock
PVC
2
35.209926100
-81.772851900
75.42
62.5 - 72.5
858.63
855.87
815.24
43.39
CCPMW-6S
10/21/2015
Deep
PVC
2
35.208665599
-81.771117398
46.79
33.5 - 43.5
854.38
851.48
815.11
39.27
CCPMW-6D
10/26/2015
Bedrock
PVC
2
35.208653899
-81.771102700
63.00
50.0 - 60.0
854.35
851.45
815.15
39.20
CCPMW-7
7/8/2020
Shallow
PVC
2
35.207790757
-81.769444485
51.07
37.0 - 47.0
855.49
852.63
812.19
43.30
CCPMW-8
7/6/2020
Shallow
PVC
2
35.203717021
-81.769460949
49.05
35.0 - 45.0
831.52
828.24
782.69 (Eff. Dry)
48.83
CCPMW-10
7/7/2020
Shallow
PVC
2
35.203376929
-81.768415081
45.38
32.0 - 42.0
812.98
810.45
777.03
35.95
CCPMW-11
7/1/2020
Shallow
PVC
2
35.203812900
-81.766750379
33.75
20.0 - 30.0
803.32
800.24
777.63
25.69
CCPTW-2
2/25/2010
Shallow
PVC
2
35.203862801
1 -81.770429800
1 45.00
35.0 - 45.0
841.72
839.62
BTOP
BTOP
Notes:
Groundwater elevations for CCR-CCPBG-1D, CCPMW-2S, and CCPMW-7 are based on water level data collected on October 16, 2023. All other groundwater elevations are based on water level data collected on October 18, 2023.
* - Indicates background groundwater monitoring well.
BGS - below ground surface
BTOC - below top of casing
BTOP - below top of pump
CCP - coal combustion products
Eff. Dry - Monitoring well effectively dry. Measured water level not representative of groundwater elevation. Groundwater elevation presented as "dry" on figure.
ft - feet
NAVD 88 - Vertical elevations in feet based on North American Vertical Datum of 1988
PVC - Polyvinylchloride
TOP - Value represents depth to top of pump. Water level below top of pump.
Prepared by: TWL Checked by: CS
Page 1 of 1

TABLE 3
GROUNDWATER, SURFACE WATER, AND LEACHATE MONITORING PARAMETERS
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Constituent
Analytical
Methods
Units
15A NCAC 02L
Standards for
Groundwater
15A NCAC 02B
(Class WS-IV)
Standards, ISTV, and
USEPA Criteria for
Surface Water
In Situ Parameters
pH
Multi -Parameter Water Quality Meter
S.U.
6.5-8.5
6.0-9.0
Temperature
Multi -Parameter Water Quality Meter
degrees Celsius
NE
<_ 29
Specific Conductance
Multi -Parameter Water Quality Meter
µmhos/cm
NE
NE
Dissolved Oxygen
Multi -Parameter Water Quality Meter
mg/L
NE
>_ 4
Oxidation Reduction
Potential
Multi -Parameter Water Quality Meter
millivolts
NE
NE
Turbidity
Turbidimeter
NTU
NE
Streams <_ 50
Water Level
Water Level Meter
ft
NE
NE
Laboratory Analyses
Antimony
EPA 200.8 / SW 6020E
µg/L
1
5 300$
Arsenic
EPA 200.8 / SW 6020E
µg/L
10
10
Barium
EPA 200.7 / SW 6010D
µg/L
700
1,000
Beryllium
EPA 200.8 / SW 6020E
µg/L
4
NE
Beryllium (dissolved)
EPA 200.8 / SW 6020E
µg/L
NE
65^
Boron
EPA 200.7 / SW 6010D
µg/L
700
34,000#
Cadmium
EPA 200.8 / SW 6020E
µg/L
2
NE
Cadmium (dissolved)
EPA 200.8 / SW 6020E
µg/L
NE
0.75^'t
Calcium
EPA 200.7 / SW 6010D
mg/L
NE
NE
Chloride
EPA 300.0 / EPA 9056A
mg/L
250
230
Chromium
EPA 200.8 / SW 6020E
µg/L
10
NE
Chromium (dissolved)
EPA 200.8 / SW 6020E
µg/L
NE
180^'"
Cobalt
EPA 200.8 / SW 6020E
µg/L
1
3$
Copper
EPA 200.8 / SW 6020E
µg/L
1,000
NE
Copper (dissolved)
EPA 200.8 / SW 6020E
µg/L
NE
3.6"'t
Fluoride
EPA 300.0 / EPA 9056A
mg/L
2
1.8
Iron
EPA 200.7 / SW 6010D
µg/L
300
1,000*
Lead
EPA 200.8 / SW 6020E
µg/L
15
NE
Lead (dissolved)
EPA 200.8 / SW 6020E
µg/L
NE
14"'t
Lithium
EPA 200.7 / SW 6010D
µg/L
NE
NE
Magnesium
EPA 200.7 / SW 6010D
mg/L
NE
NE
Manganese
EPA 200.7 / SW 6010D
µg/L
50
50.
Mercury
EPA 245.1 / SW 7470A
µg/L
1
0.012
Molybdenum
EPA 200.8 / SW 6020E
µg/L
NE
160$
Nickel
EPA 200.8 / SW 6020E
µg/L
100
25
Nickel (dissolved)
EPA 200.8 / SW 6020E
µg/L
NE
140^'t
Nitrate (as N)
EPA 300.0 / EPA 9056A
mg-N/L
10
10
Selenium
EPA 200.8 / SW 6020E
µg/L
20
NE
Selenium (dissolved)
EPA 200.8 / SW 6020E
µg/L
NE
3.1&
Silver
EPA 200.8 or SW 6020A
µg/L
20
NE
Silver (dissolved)
EPA 200.8 or SW 6020A
µg/L
NE
0.30^'t
Sulfate
EPA 300.0 / EPA 9056A
mg/L
250
250
Thallium
EPA 200.8 / SW 6020E
µg/L
2
2$
Total Dissolved Solids
SM 2540C / EPA 160.1 / ASTM D5907
mg/L
500
500
Page 1 of 2

TABLE 3
GROUNDWATER, SURFACE WATER, AND LEACHATE MONITORING PARAMETERS
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
15A NCAC 02B
15A NCAC 02L
(Class WS-IV)
Analytical
Constituent
Units
Standards for
Standards, ISTV, and
Methods
Groundwater
USEPA Criteria for
Surface Water
Laboratory Analyses (Continued)
Total Hardness
Calculation (2.497 (calcium) + 4.118 (magnesium))
mg/L
NE
100
Vanadium
EPA 200.8 / SW 6020B
µg/L
7
NE
Zinc
EPA 200.7 / SW 6010D
µg/L
1,000
NE
Zinc (dissolved)
EPA 200.7 / SW 6010D
µg/L
NE
36^'t
Prepared by: TWL Checked by: CS
Notes:
15A NCAC 02L Standard refers to Class GA Standards as found in 15A NCAC 02L .0202 Groundwater Quality Standards, last amended on April 1, 2022.
15A NCAC 02B Standards for Class WS-IV surface water. Water quality standards applicable to Class C waters also apply to Class WS-IV waters.
North Carolina surface water and wetland standards (effective September 1, 2022).
Total recoverable metal analysis applicable to samples collected from groundwater and surface water as it pertains to water quality standards defined in 15A NCAC 02L and 15A NCAC 02B.
Dissolved analysis only applicable for samples collected from surface water as it pertains to receiving water body with water quality standards applicable to waters and wetlands of NC as defined in
Title 15A NCAC 026. Total hardness is also only applicable for surface water samples.
ISTV for Surface Water - In -stream target values established per 15A NCAC 02B .0202 and .0208.
USEPA Criteria for Surface Water - U.S. Environmental Protection Agency National Recommended Water Quality Criteria.
For 15A NCAC 02B Standards and ISTVs with acute and chronic criteria, the acute criteria are considered more applicable to grab sampling; therefore, those values are presented.
$ - An exceedance of a published ISTV is not automatically a violation of the water quality standard for toxicity. Comparison value presented is the lesser of the Aquatic Life & Secondary Recreation or
Fish Consumption value, when applicable.
- ISTV is based on acute sampling method described in 15A NCAC 02B (11)(e). Compliance with acute instream standard is not applicable to sampling method. An exceedance of a published ISTV is
not automatically a violation of the water quality standard for toxicity.
USEPA National Recommended Water Quality Criteria are not a regulation, nor do they impose a legally -binding requirement. Therefore, comparisons with these criteria are for situational context.
Comparison criteria based on acute sampling method described in 15A NCAC 02B (11)(e). Compliance with acute instream standard is not applicable to sampling method and provided for screening
purposes only.
- Hardness -dependent standard calculated using 25 mg/L hardness and not actual in -stream hardness value. Provided for screening purposes only.
`- Hardness -dependent standard for chromium III calculated using 25 mg/L hardness and not actual in -stream hardness value. Provided for screening purposes only.
& - Selenium standard for lotic water based on a 30-day average. Not applicable to the sampling method and provided for screening purposes only.
µg/L - micrograms per liter
µmhos/cm - micromhos per centimeter
ft - feet
mg/L - milligrams per liter
mg-N/L - milligrams nitrogen per liter
NE - not established
NTU - nephelometric turbidity units
S.U. - standard units
Page 2 of 2

TABLE 4
GROUNDWATER SEEPAGE VELOCITIES
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Surficial and Transition Flow Zone
Upgradient
Downgradient
Seepage
Groundwater
Groundwater
K
Ah
Distance
Well ID
Elevation
Elevation
(ft/day)'
(ft)
(ft)
Effective PorosityZ
Velocity
(ft/day)
(ft, NAVD 88)
(ft, NAVD 88)
CCPMW-1S to CCPMW-10
1 838.95
1 777.03
1 1.02
1 61.92
1 2135
1 0.20
1 0.148
Bedrock Flow Zone
Upgradient
Downgradient
Seepage
Well ID
Groundwater
Groundwater
K
Ah
Distance
Effective PorosityZ
Velocity
Elevation
Elevation
1
(ft/day)
(ft)
(ft)
(ft/day)3
(ft, NAVD 88)
(ft, NAVD 88)
CCPMW-1D to CCPMW-3D
838.09
790.73
1.30
47.36
1555
0.05
0.792
CCPMW-1D to CCPMW-6D
838.09
815.15
1.30
22.94
1188
0.05
0.502
Prepared by: TWL Checked by: CS
Notes:
1- Values used are a calculated Geomean of hydraulic conductivities (K) in paired wells. K values are derived from slug test data presented in the Groundwater Monitoring Well
Installation Report (SynTerra, April 2021).
Z - Value taken from Updated Groundwater Flow and Transport Modeling Report for Cliffside Steam Station, Mooresboro, NC, December 2019 (SynTerra) .
s - Value represents an estimate of the velocity of groundwater through bedrock fractures.
Ah - difference in head/groundwater elevation
ft - feet
ft/day - feet per day
Groundwater elevations are based on water level data collected on October 18, 2023.
Hydraulic gradients and groundwater velocities are approximate.
NAVD 88 - North American Vertical Datum of 1988
Page 1 of 1

TABLE 5
FIELD DATA PARAMETERS
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Sample ID
Sample Date
Appearance
Odor
Purge Method
Average Pump Rate
mL min
( / )
Temp
De C
(Deg )
Specific
Conductance
(µmhos/cm)
pH
S.U.
( )
ORP
mV
( )
Dissolved
Oxygen
(mg/L)
Turbidity
NTU
( )
Groundwater
Elevation
(ft, NAVD 88)
Depth to Water
ft, BTOC
( )
Groundwater Parameters
CCR-CCPBG-1D*
10/18/2023
Clear
None
Bladder Pump
40
25
77
5.5
91
5.2
3.6
841.93
47.35
CCR-CCPBG-1BR*
10/18/2023
Clear
None
Bladder Pump
300
18
1,217
7.7
85
0.3
0.8
835.33
53.69
CCPMW-1S*
10/18/2023
Clear
None
Bladder Pump
80
16
22
5.1
73
7.3
1.9
838.95
36.63
CCPMW-1D*
10/18/2023
Clear
None
Bladder Pump
200
16
49
5.2
199
5.6
0.1
838.09
37.80
CCPMW-2S
10/18/2023
Clear
None
Bladder Pump
50
18
53
5.2
114
8.5
6.9
801.49
40.75
CCPMW-2D
10/18/2023
Clear
None
Bladder Pump
200
17
120
7.7
76
3.4
1.0
799.90
42.45
CCPMW-3S
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
796.44 (Eff. Dry)
15.12
CCPMW-3D
10/18/2023
Clear
None
Bladder Pump
100
17
103
5.5
112
5.9
1.1
790.73
21.01
CCPMW-4
10/18/2023
Clear
Sulfur
Bladder Pump
80
15
172
8.3
125
3.0
2.7
817.07
28.88
CCPMW-5
10/18/2023
Clear with fines
None
Bladder Pump
200
19
175
10.5
153
6.1
5.4
815.24
43.39
CCPMW-6S
10/18/2023
Clear
None
Bladder Pump
100
20
51
5.2
86
5.1
8.9
815.11
39.27
CCPMW-6D
10/18/2023
Clear
None
Bladder Pump
200
19
49
5.3
126
6.1
0.1
815.15
39.20
CCPMW-7
10/18/2023
Clear
None
Bladder Pump
50
18
78
5.5
194
5.6
8.4
812.19
43.30
CCPMW-8
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
782.69 (Eff. Dry)
48.83
CCPMW-10
10/18/2023
Clear
None
Bladder Pump
90
19
47
5.0
7
5.5
7.7
777.03
35.95
CCPMW-11
10/18/2023
Clear
None
Peristaltic Pump
180
18
54
5.4
-38
3.6
2.9
777.63
25.69
CCPTW-2
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
BTOP
BTOP
Surface Water Parameters
CCPSW-1
10/18/2023
Clear
None
Grab
NA
15
99
6.8
20
5.7
3.2
NA
NA
CCPSW-2
10/18/2023
Slightly Cloudy
Earthy
Grab
NA
12
66
6.3
146
7.8
13.6
NA
NA
CCPSW-3
10/18/2023
Clear
None
Grab
NA
14
55
5.8
125
6.1
2.5
NA
NA
Leachate Collection Parameters
CCP-Leachate
10/18/2023
Clear
None
Grab
NA
19
36,370
4.7
105
4.1
0.6
NA
NA
CCP-Leachate-34
10/18/2023
Clear
None
Grab
NA
19
4,734
4.7
39
2.9
1.0
NA
NA
Notes:
* - Indicates background groundwater monitoring well.
Analytical data presented in this table reflect the Duke Energy Biological Analytical Data Storage System (BASS) as of 12/11/2023.
Monitoring wells CCPMW-3S, CCPMW-8, and CCPTW-2 not sampled due to insufficient volume of water.
Water level data for CCR-CCPBG-1D, CCPMW-2S, and CCPMW-7 collected on October 16, 2023. All other water level data collected on October 18, 2023.
µmhos/cm - micromhos per centimeter
BTOC - below top of casing
BTOP - below top of pump
Deg C - degrees Celsius
Eff. Dry - Monitoring well effectively dry. Measured water level not representative of groundwater elevation. Groundwater elevation presented as "dry" on figure.
ft - feet
mg/L - milligrams per liter
mL/min - milliliters per minute
mV - millivolts
NA - not applicable
NAVD88 - North American Vertical Datum of 1988
NS - not sampled
NTU - nephelometric turbidity units
ORP - oxidation reduction potential
S.U. - standard units
Prepared by: TWL Checked by: CS
Page 1 of 1

TABLE 6
LEACHATE FIELD RESULTS AND ANALYTICAL DETECTIONS
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Parameter
SWS ID
Units
Leachate Sample ID
MDL
CCP-Leachate
CCP-Leachate-34
pH
320
S.U.
4.7
4.7
NA
Temperature
325
Deg C
19
19
NA
Specific Conductance
323
µmhos/cm
36,370
4,734
NA
Dissolved Oxygen
NE
mg/L
4.1
2.9
NA
Oxidation Reduction Potential
336
mV
105
39
NA
Eh
NE
mV
310
244
NA
Turbidity
330
NTU
0.6
1.0
NA
Antimony
13
µg/L
0.255 J
< 2
0.104
Arsenic
14
µg/L
8.17
7.16
0.111
Barium
15
µg/L
417
55
2
Beryllium
23
µg/L
0.927 J
4.15
0.249
Boron
428
µg/L
9,190
5,850
5
Cadmium
34
µg/L
2.09
1.48 J
0.032
Calcium
375
mg/L
7,660
947
0.012
Chloride
301
mg/L
15,000
1,100
0.0154
Chromium
51
µg/L
1.13 J
2.11
0.185
Cobalt
53
µg/L
490
530
0.077
Copper
54
µg/L
32.9
118
0.787
Fluoride
312
mg/L
< 20
0.37 J
0.0479
Iron
340
µg/L
550
5,300
4
Lead
131
µg/L
133
30.2
0.037
Lithium
NE
µg/L
7,550
183
2
Magnesium
376
mg/L
58.3
122
0.008
Manganese
342
µg/L
11,100
23,600
1
Mercury
132
µg/L
< 0.05
< 0.05
0.01
Molybdenum
397
µg/L
334
0.782 J
0.18
Nickel
152
µg/L
103
276
0.256
Nitrate (as N)
303
mg-N/L
4.6 J
1.7
0.002
Selenium
183
µg/L
69.5
5.18
0.193
Silver
184
µg/L
0.147 J
0.119 J
0.035
Sulfate
315
mg/L
860
1,600
0.0428
Thallium
194
µg/L
8.77
2.35
0.041
Total Dissolved Solids
311
mg/L
20,300
3,930
25
Vanadium
209
µg/L
1.11 J
0.126 J
0.114
Zinc
213
µg/L
1 105
1 296
4
Notes:
Samples collected by Pace Analytical personnel on October 18, 2023.
Analytical data presented in this table reflects the Duke Energy Biological Analytical Data Storage System (BASS) as of 12/11/2023.
<- Concentration not detected at or above the adjusted reporting limit.
Deg C - degrees Celsius
µg/L- micrograms per liter
µmhos/cm - micromhos per centimeter
1 - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
MDL- Laboratory Method Detection Limit; VOL values presented are for samples not diluted by the laboratory during analysis.
mg/L- milligrams per liter
mg-N/L- milligrams nitrogen per liter
mV - millivolts
NA - not applicable
NE - not established
NTU - nephelometric turbidity units
S.U. - standard units
SWS ID - Solid Waste Section Identification Number
Prepared by: TWL Checked by: CS
Page 1 of 1

TABLE 7
GROUNDWATER FIELD RESULTS AND ANALYTICAL DETECTIONS
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Parameter
SWS ID
Units
Monitoring Wells
MDL
SW
GWPS
15A NCAC
02L Standard
CCPMW-15
CCPMW-ID
CCPMW-2S
CCPMW-2D
CCPMW-35
CCPMW-3D
CCPMW-4
CCPMW-5
CCPMW-6S
CCPMW-6D
CCPMW-7
CCPMW-8
CCPMW-10
CCPMW-11
CCPTW-2
CCR-CCPBG-1D
CCR-CCPBG-1BR
pH
320
S.U.
5.1
5.2
5.2
7.7
NS
5.5
8.3
10.5
5.2
5.3
5.5
NS
5.0
5.4
NS
5.5
7.7
NA
NE
6.5-8.5
Temperature
325
Deg C
16
16
18
17
NS
17
15
19
20
19
18
NS
19
18
NS
25
18
NA
NE
NE
Specific Conductance
323
µmhos/cm
22
49
53
120
NS
103
172
175
51
49
78
NS
47
54
NS
77
1,217
NA
NE
NE
Dissolved Oxygen
NE
mg/L
7.3
5.6
8.5
3.4
NS
5.9
3.0
6.1
5.1
6.1
5.6
NS
5.5
3.6
NS
5.2
0.3
NA
NE
NE
Oxidation Reduction Potential
336
mV
73
199
114
76
NS
112
125
153
86
126
194
NS
7
-38
NS
91
85
NA
NE
NE
Eh
NE
mV
278
404
319
281
NS
317
330
358
291
331
399
NS
212
167
NS
296
290
NA
NE
NE
Turbidity
330
NTU
1.9
0.1
6.9
1.0
NS
1.1
2.7
5.4
8.9
0.1
8.4
NS
7.7
2.9
NS
3.6
0.8
NA
NE
NE
Antimony
13
µg/L
<1
<1
<1
<1
NS
<1
0.179J
0.491J
<1
<1
0.125J
NS
<1
<1
NS
<1
<1
0.104
NE
1
Arsenic
14
µg/L
< 1
< 1
0.116 J
0.529 J
NS
< 1
0.72 J
3.23
0.257 J
0.116 J
0.228 J
NS
< 1
0.12 J
NS
< 1
0.698 J
0.111
NE
10
Barium
15
µg/L
23
17
33
9
NS
34
36
4J
39
37
44
NS
52
37
NS
33
6
2
NE
700
Beryllium
23
µg/L
<1
<1
<1
<1
NS
<1
<1
<1
<1
<1
0.8J
NS
<1
<1
NS
<1
<1
0.249
NE
4
Boron
428
µg/L
5 J
8 J
13 J
10.1
NS
40 J
7 J
23 J
< 50
< 50
< 50
NS
< 50
< 50
NS
< 50
14 J
5
NE
700
Cadmium
34
µg/L
< 1
0.035 J
< 1
< 1
NS
< 1
< 1
< 1
< 1
< 1
0.033 J
NS
0.033 J
< 1
NS
< 1
< 1
0.032
NE
2
Calcium
375
mg/L
0.167
2.68
2.92
15.5
NS
9.73
23.2
26.3
1.40
1.68
4.96
NS
1.81
2.12
NS
3.61
40.3
0.012
NE
NE
Chloride
301
mg/L
3.9
8.0
2.9
5.6
NS
9.5
1.7
4.8
4.8
5.3
11
NS
5.7
5.2
NS
9.2
120
0.0154
NE
250
Chromium
51
µg/L
0.428 J
< 1
1.67
0.678 J
NS
1.08
0.208 J
4.58
2.15
1.39
2.12
NS
1.40
4.76
NS
0.409 J
< 1
0.185
NE
10
Cobalt
53
µg/L
1.14 J
0.3 J
0.657 J
< 1
NS
0.158 J
< 1
0.117 J
2.20
6.13
0.305 J
NS
1.22 J
0.456 J
NS
0.653 J
0.096 J
0.077
NE
1
Copper
54
µg/L
< 1
< 1
< 1
< 1
NS
< 1
< 1
1.39
1.12
< 1
1.11
NS
< 1
1.32
NS
< 1
< 1
0.787
NE
1,000
Fluoride
312
mg/L
<0.1
<0.1
<0.1
<0.1
NS
<0.1
0.17
0.1J
<0.1
<0.1
<0.1
NS
<0.1
<0.1
NS
<0.1
0.13J
0.0479
NE
2
Iron
340
µg/L
11
6J
272J
27
NS
<10
84
166
732
128
367
NS
167
380
NS
54
5.1
4
NE
300
Lead
131
µg/L
< 1
< 1
0.24 J
< 1
NS
< 1
< 1
0.245 J
0.557 J
0.401 J
0.245 J
NS
0.205 J
0.46 J
NS
0.105 J
< 1
0.037
NE
15
Lithium
NE
µg/L
5 J
5
4 J
6
NS
2 J
8
3 J
3 J
3 J
3 J
NS
2 J
2 J
NS
11
9
2
NE
NE
Magnesium
376
mg/L
0.664
1.43
1.95
1.08
NS
2.58
1.02
0.289
1.85
1.67
2.05
NS
1.77
1.94
NS
2.14
2.71
0.008
NE
NE
Manganese
342
µg/L
16 J
8 J
40
2 J
NS
9 J
23 J
10.1
38
87
29 J
NS
20 J
25 J
NS
28 J
36
1
NE
50
Mercury
132
µg/L
0.01 J
< 0.05
< 0.05
< 0.05
NS
< 0.05
< 0.05
< 0.05
< 0.05
0.01 J
0.01 J
NS
0.03 J
< 0.05
NS
< 0.05
< 0.05
0.01
NE
1
Molybdenum
397
µg/L
< 1
< 1
< 1
0.431 J
NS
< 1
11.3
1.51 J
< 1
< 1
0.223 J
NS
< 1
< 1
NS
< 1
20.8
0.18
NE
NE
Nickel
152
µg/L
0.439 J
0.876 J
0.895 J
< 1
NS
< 1
< 1
0.75 J
1.87
0.693 J
1.38
NS
0.886 J
5.30
NS
1.07
2.83
0.256
NE
100
Nitrate (as N)
303
mg-N/L
0.03 J
0.33
1.5
1.3
NS
1.2
0.01 J
0.91
2.9
2.2
1.9
NS
1.7
1.4
NS
1 3.8
0.47
0.002
NE
10
Selenium
183
µg/L
<1
<1
0.516J
<1
NS
<1
<1
0.198J
<1
<1
<1
NS
<1
<1
NS
<1
<1
0.193
NE
20
Silver
184
µg/L
<1
<1
<1
<1
NS
<1
<1
<1
<1
<1
<1
NS
<1
<1
NS
0.274J
<1
0.035
NE
20
Sulfate
315
mg/L
0.24
1.4
6.7
4.3
NS
16
15
17
1.2
0.34
0.48
NS
0.22
0.32
NS
0.44
170
0.0428
NE
250
Thallium
194
µg/L
< 0.2
< 0.2
< 0.2
< 0.2
NS
< 0.2
< 0.2
< 0.2
0.066 J
0.048 J
< 0.2
NS
0.047 J
0.049 J
NS
0.056 J
< 0.2
0.041
NE
2
Total Dissolved Solids
311
mg/L
< 25
28.0
38.0 J
85.0
NS
72.0
114
132
32.0
52.0
56.0
NS
26.0
29.0
NS
65.0
566
25
NE
500
Vanadium
209
µg/L
< 1
< 1
0.685 J
3.51
NS
0.121 J
0.13 J
11.6
0.993 J
0.217 J
0.812 J
NS
0.316 J
0.632 J
NS
< 1
0.632 J
0.114
NE
7
Zinc
213
µg/L
<5
<5
<5
<5
NS
<5
<5
<5
<5
<5
<5
NS
<5
<5
NS
<5
<5
4
NE
1,000
Notes:
Bold and Grey highlighted concentrations are equal to or greater than the 15A NCAC 02L Standard (for pH, outside the 02L Standard range).
Analytical data presented in this table reflects the Duke Energy Biological Analytical Data Storage System (BASS) as of 12/11/2023.
15A NCAC 02L Standard refers to Class GA Standards as found in 15A NCAC 02L. 0202 Groundwater Quality Standards, last amended on April 1, 2022.
CCPMW-1S/D and CCR-CCPBG-1D/BR are background groundwater monitoring wells.
Samples collected by Pace Analytical personnel on October 18, 2023.
<- Concentration not detected at or above the adjusted reporting limit.
1 - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
MDL - Laboratory Method Detection Limit; MDL values presented are for samples not diluted by the laboratory during analysis.
SW GWPS -Solid Waste Groundwater Protection Standard
SWS ID - Solid Waste Section Identification Number
Deg C - degrees Celsius NA - not applicable
µg/L - micrograms per liter NCAC - North Carolina Administrative Code
µmhos/cm - micromhos per centimeter NE - not established
mg/L - milligrams per liter NS - not sampled
mg-N/L - milligrams nitrogen per liter NTU - nephelometric turbidity units
mV - millivolts S.U. - standard units
Prepared by: TWL Checked by: CS
Page 1 of 1

TABLE 8
FIELD AND ANALYTICAL RESULTS EQUAL TO OR GREATER THAN GROUNDWATER QUALITY STANDARDS
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Parameter
Sample ID
October 2023
Concentration
Units
1SA NCAC
02L Standard
Historical
Concentration Range
Cause and Significance
pH
CCPMW-1S
5.1
S.U.
6.5 - 8.5
4.4 - 6.6
Background well, represents naturally occurring conditions.
CCPMW-1D
5.2
4.4 - 6.2
Background well, represents naturally occurring conditions.
CCPMW-2S
5.2
4.4 - 6.4
pH is consistent with the range of historical readings at CCPMW-2S.
CCPMW-3D
5.5
4.7 - 5.6
pH is consistent than the range of historical readings at CCPMW-3D.
CCPMW-5
10.5
8.1- 11.0
pH is consistent with the range of historical readings at CCPMW-5.
CCPMW-6S
5.2
4.6 - 5.8
pH is consistent than the range of historical readings at CCPMW-6S.
CCPMW-6D
5.3
5.1 - 5.4
pH is consistent with the range of historical readings at CCPMW-6D.
CCPMW-7
5.5
4.7 - 5.8
pH is consistent with the range of historical readings at CCPMW-7.
CCPMW-10
5.0
4.5 - 5.2
pH is consistent with the range of historical readings at CCPMW-10.
CCPMW-11
5.4
5.3 - 5.8
pH is consistent with the range of historical readings at CCPMW-11.
CCR-CCPBG-1D
5.5
5.1 - 5.4
Background well, represents naturally occurring conditions.
Cobalt
CCPMW-1S
1.14 J
µg/L
1
0.6 - 10.7
Background well, represents naturally occurring conditions.
CCPMW-6S
2.20
1.95 - 10.3
Cobalt is consistent with the range of historical concentrations at CCPMW-6S.
CCPMW-6D
6.13
0.527 J - 1.86
Cobalt is greater than the range of historical concentrations at CCPMW-6D.
CCPMW-10
1.22 J
0.84 J - 2.5
Cobalt is consistent with the range of historical concentrations at CCPMW-10.
Iron
CCPMW-6S
732
µg/L
300
105 - 1,390
Iron is consistent with the range of historical concentrations at CCPMW-6S.
CCPMW-7
367
18.2 - 170
Iron is greater than the range of historical concentrations at CCPMW-7.
CCPMW-11
380
58 - 635
Iron is consistent with the range of historical concentrations at CCPMW-11.
Manganese
CCPMW-6D
87
µg/L
50
<5 - 134
Manganese is consistent with the range of historical concentrations at CCPMW-6D.
TDS
CCR-CCPBG-1BR
566
mg/L
500
165 - 1,090
Background well, represents naturally occurring conditions.
Vanadium
CCPMW-5
11.6
µg/L
7
7.54 - 17.1
Vanadium is consistent with the range of historical concentrations at CCPMW-5.
Notes:
Historical ranges are based on all applicable data in Duke Energy Carolinas, LLC (Duke Energy) analytical results database and previous reporting. Historical ranges exclude sample data with turbidity values greater than 10 NTUs.
Analytical data presented in this table reflects the Duke Energy Biological Analytical Data Storage System (BASS) as of 12/11/2023.
15A NCAC 02L Standard refers to Class GA Standards as found in 15A NCAC 02L .0202 Groundwater Quality Standards, last amended on April 1, 2022.
<- Concentration not detected at or above the adjusted reporting limit.
µg/L - micrograms per liter
J - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
mg/L - milligrams per liter
NCAC - North Carolina Administrative Code
NTU - nephelometric turbidity units
S.U. - standard units
TDS - total dissolved solids
Prepared by: TWL Checked by: CS
Page 1 of 1

TABLE 9
SURFACE WATER FIELD RESULTS AND ANALYTICAL DETECTIONS
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Parameter
SWS ID
Units
Surface Water
Sample ID
MDI.
15A NCAC 02B
1
(Class WS-IV) Standards', ISTV,
and USEPA Criteria
CCPSW-1
CCPSW-2
CCPSW-3
pH
320
S.U.
6.8
6.3
5.8
NA
6.0-9.0
Temperature
325
Deg C
15
12
14
NA
<_ 29
Specific Conductance
323
µmhos/cm
99
66
55
NA
NE
Dissolved Oxygen
NE
mg/L
5.7
7.8
6.1
NA
>_ 4
Oxidation Reduction Potential
336
mV
20
146
125
NA
NE
Eh
NE
mV
225
351
330
NA
NE
Turbidity
330
NTU
3.2
13.6
2.5
NA
Streams <_ 50
Antimony
13
µg/L
< 1
< 1
< 1
0.104
5,300$
Arsenic
14
µg/L
0.207 J
0.211 J
0.176 J
0.111
10
Barium
15
µg/L
20
21
18
2
1,000
Beryllium
23
µg/L
< 1
< 1
< 1
0.249
NE
Beryllium (dissolved)
23
µg/L
< 1
< 1
< 1
0.249
65^
Boron
428
µg/L
6 J
< 50
< 50
5
34,000#
Cadmium
34
µg/L
< 1
< 1
< 1
0.032
NE
Cadmium (dissolved)
34
µg/L
< 1
< 1
< 1
0.032
0.75"t
Calcium
375
mg/L
2.72
2.82
2.54
0.012
NE
Chloride
301
mg/L
4.1
4.2
5.3
0.0154
230
Chromium
51
µg/L
0.545 J
0.432 J
0.385 J
0.185
NE
Chromium (dissolved)
51
µg/L
0.286 J
0.253 J
0.198 J
0.185
180^'x
Cobalt
53
µg/L
0.245 J
0.158 J
0.497 J
0.077
3$
Copper
54
µg/L
< 1
< 1
< 1
0.787
NE
Copper (dissolved)
54
µg/L
< 1
< 1
< 1
0.787
3.6^'t
Fluoride
312
mg/L
< 0.1
< 0.1
< 0.1
0.0479
1.8
Iron
340
µg/L
1,030
958
511
4
1,000*
Lead
131
µg/L
0.112 J
0.161 J
0.096 J
0.037
NE
Lead (dissolved)
131
µg/L
0.064 J
0.059 J
< 1
0.037
14^'t
Lithium
NE
µg/L
13
7
5
2
NE
Magnesium
376
mg/L
1.37
1.45
1.58
0.008
NE
Manganese
342
µg/L
26 J
22 J
18 J
1
50*
Mercury
132
µg/L
< 0.05
< 0.05
< 0.05
0.01
0.012
Molybdenum
397
µg/L
< 1
< 1
< 1
0.18
160$
Nickel
152
µg/L
< 1
< 1
0.387 J
0.256
25
Nickel (dissolved)
152
µg/L
0.435 J
0.372 J
0.392 J
0.256
140"t
Nitrate (as N)
303
mg-N/L
0.50
0.47
0.19
0.002
10
Selenium
183
µg/L
< 1
< 1
< 1
0.193
NE
Silver
184
µg/L
< 1
< 1
< 1
0.035
NE
Silver (dissolved)
184
µg/L
< 1
< 1
< 1
0.035
0.30^'t
Sulfate
315
mg/L
0.93
1.6
1.5
0.0428
250
Thallium
194
µg/L
< 0.2
< 0.2
< 0.2
0.041
2$
Total Dissolved Solids
311
mg/L
29.0
34.0
35.0
25
500
Total Hardness
NE
mg/L
12.4
13.0
12.8
NA
100
Page 1 of 2

TABLE 9
SURFACE WATER FIELD RESULTS AND ANALYTICAL DETECTIONS
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Surface Water
15A NCAC 02B
Parameter
SWS ID
Units
Sample ID
MDL
(Class WS-IV) Standards', ISTV,
CCPSW-1
CCPSW-2
CCPSW-3
and USEPA Criteria
Vanadium
209
µg/L
0.256 J
0.41 J
0.243 J
0.114
NE
Zinc
213
µg/L
< 5
< 5
< 5
4
NE
Zinc (dissolved)
213
µg/L
< 5
< 5
< 5
4
36"t
Prepared byTWL Checked by: CS
Notes:
Bold and grey concentrations are equal to or greater than the applicable 15A NCAC 02B Standard (or outside the 02B Standard range for pH). Concentrations greater than other comparison criteria, used
solely for screening purposes, are only bold.
Samples collected by Pace Analytical personnel on October 18, 2023.
Analytical data presented in this table reflect the Duke Energy Biological Analytical Data Storage System (BASS) as of 12/11/2023.
CCPSW-1 surface water sample location is upgradient of the CCP landfill.
ISTV - In -stream target values established per 15A NCAC 02B .0202 and .0208.
USEPA Criteria - U.S. Environmental Protection Agency National Recommended Water Quality Criteria
For constituents with acute and chronic criteria, the acute criteria are considered more applicable to grab sampling; therefore, those values are presented.
1- 15A NCAC 02B Standards for Class WS-IV surface water. Water quality standards applicable to Class C waters also apply to Class WS-IV waters. North Carolina surface water and
wetland standards (effective September 1, 2022).
$ - An exceedance of a published ISTV is not automatically a violation of the water quality standard for toxicity. Comparison value presented is the lesser of the Aquatic Life & Secondary
Recreation or Fish Consumption value, when applicable.
- ISTV is based on acute sampling method described in 15A NCAC 02B (11)(e). Compliance with acute instream standard is not applicable to sampling method. An exceedance of a
published ISTV is not automatically a violation of the water quality standard for toxicity.
USEPA National Recommended Water Quality Criteria are not a regulation, nor do they impose a legally -binding requirement. Therefore, comparisons with these criteria are for situational context.
Comparison criteria based on acute sampling method described in 15A NCAC 02B (11)(e). Compliance with acute instream standard is not applicable to sampling method and provided for
screening purposes only.
- Hardness -dependent standard calculated using 25 mg/L hardness and not actual in -stream hardness value. Provided for screening purposes only.
`- Hardness -dependent standard for chromium III calculated using 25 mg/L hardness and not actual in -stream hardness value. Provided for screening purposes only.
<- Concentration not detected at or above the adjusted reporting limit.
µg/L - micrograms per liter
µmhos/cm - micromhos per centimeter
Deg C - degrees Celsius
CCP - coal combustion products
J - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
MDL - Laboratory Method Detection Limit; MDL values presented are for samples not diluted by the laboratory during analysis.
mg/L - milligrams per liter
mg-N/L - milligrams nitrogen per liter
mV - millivolts
NA - not applicable
NE - not established
NCAC - North Carolina Administrative Code
NTU - nephelometric turbidity units
S.U. - standard units
SW GWPS - Solid Waste Groundwater Protection Standard
SWS ID - Solid Waste Section Identification Number
Page 2 of 2

TABLE 10
FIELD AND ANALYTICAL RESULTS EQUAL TO OR GREATER THAN SURFACE WATER QUALITY STANDARDS
CCP LANDFILL PHASES I THROUGH IV (PERMIT NO. 8106-INDUS)
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
15A NCAC 02B
Historical
October 2023
Parameter
Sample ID
Units
Standard
Concentration
Cause and Significance
Concentration
(Class WS-IV)1
Range
pH
CCPSW-3
5.8
S.U.
6.0 - 9.0
4.8 - 6.2
pH is consistent with the range of historical readings at CCPSW-3.
Prepared by: TWL Checked by: CS
Notes:
Historical ranges are based on all applicable data in Duke Energy Carolinas, LLC (Duke Energy) analytical results database and previous reporting. Historical ranges exclude sample data with turbidity
values greater than 50 NTUs.
1 15A NCAC 02B Standards for Class WS-IV surface waters. Water quality standards applicable to Class C waters also apply to Class WS-IV waters. North Carolina surface water and wetland
standards (effective September 1, 2022).
Analytical data presented in this table reflects the Duke Energy Biological Analytical Data Storage System (BASS) as of 12/11/2023.
CCP - coal combustion products
NCAC - North Carolina Administrative Code
NTU - nephelometric turbidity units
S.U. -standard units
Page 1 of 1

Semiannual Water Quality Monitoring Report — October 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
APPENDIX A
FIELD SAMPLING FORMS
L7
synTerra
Science & Engineering Consultants

42
Location nearllDate JONIS/23
Project/Client YSTo of /TA„loa8y (y,l "AMi'an�/
B�l�t: io.zl:e kefa,. .a
L' 7 ✓
!'lt Ca
2
(Op
Baoee/
_
TLp 0.
TP,n P
4.00S
-
a — 4 • h
4.oce�.
13.3 Of
.n
in.00i
-
0,145 k),I ti� P
1i.5 �(
h.
oob 4.0oS
7-e
r L
�
>.o
to
r_S Rq.Sr r
13.7-°l
DAPS
tao
S loc.*—
�;1s4
0VL
—
_
) r
r o.
Je r
e —te
_0
b/18/t3
OW
t
oraV o V2
i-tw,t..
r Q
0 VAT (_
.4
—
'•0z ht-
p. r
Location '"0 O.'J 6a.e NC Date 10// 1Z 343
Project / Client _ YO L 0 6 '4 / ""01 y 'WO-6
Q•4. vv'�,1.,:io .15� � rg/A6�Isl0.?' 29 I >'nh9to 1 G2f v:w Bu • o � .w
o:
A
A

1j0 7
Location t G!;/17 Y'E"�i/ C'i ( Date
Project/Client �",�.,5 (� t (y'"y i 'l ''fit
%i.� S,L �(7 f�Cilfi I�rtl ZfA�S�`.�G
all
t`1
TI--
-��
2.ei,3,F
n---U-1u-6=�,C_ Date
L

Location ld.�u IW
JL ^lDate _�
Project/Client _`(�'iq<l —Gdt 7
H CT- z7,11
. !U11 S%L.i 129
Location 1"�@ �.� �c�-u, xJ"�,- Date
Project /Client
EMM
■■■■■■■■
■■iOM
■■�■�■
■■
a
•'
■EIM■
M=■■■
■■■■■■■■■■■■■■
■■■■■■■■■■■■�■■■
MEN
■t!1Z■■■■A
■■■■P�A■■■■■■■■
■■■►i■■■■■■■■■■
■■/�■■■■■■■■■
■r■■■■■■■■■■■■■

Location/ ,PZ<e LAo
A/C
Date .�
.. L✓r jre` ma y '
- '.. '.
Project / Client �f/%/%�J/�r/�ljr f7s
,Y Location
'�f
/1,ekT/eT All
- 59
Date ,(? 'z
_d0,26
�ogUS
Project/Clienty
lo,Oq,,, �-0.,12
r.. - lu,'It
� l Sy �� a ;
�
•`'
—_
c1. R y:cxi ° Itoo11
2' Q4
I
r®-MM
M
e
OEMi
:
{—
i
a
_
f
�

!' 34
Location I"loorp�bp,-" (V(,J r:Le Date ID•i�y_}_
Location Mp �> (�G.^6rNC I GLS Date _I UISiof �, 35
Project / Client _`ISt o2oH J"rpwI$u�
3.P,c Project/client YSI 0204 ITPW IS(p
3�.Ilr 1i I'.Fk}va= 'L5.3Ln Ng jjP L- 3od
h LJ= ra nGi '
cc,
MqQT�e/
--
— Q. o---
= •oo
e 1Lb I
5 Lon=
@II 31f$
---
ID ig_}3—
II
f
-_
0.0
f00as JM9
S (I/.
O.D,as
(dOUus
l V. 3=� ---
Re
IA ( C
d$2-0
_ S�t.a
CW
V
✓ a
�• . ___
g00%
t7, ti
^sly _ �G.�3Mf��
• ---
G
H
a-
C�
f
E '�'•
�
L
P
�
�
o s„
_
�
03
%_
�
.o��_
f�•
_
I

88
Location l`.�ti��77�;,, °�.C�, a' )14- ,}- Date Protect / Client caL.� f(f—i`n
1
1 i<G
a
kOL-
tQ b to
to
rt
` j
i�.
�b ic, C
D
LJ 1` S�
I
_
Ctv
wb. ukko 01
VAL
�^�
l
i
LP-� 1
1
e
i
1 v wG���j,'t' �.�iS U �B �') 89 ,
Location Date ,.h. n n
Project / Client �cS 9���'��.a�. ti��}Cvi— ��" ��, z
Yee-3`-H nct fit a�P =r i 4�bia3+� �i7� re
■■■�■■■■■■■■
■
eft;.
.L,�■■■■

77Doeunignk D
PAW'. led
Dmument Nunibm, F-CA�REUl-Wl-my. 1 0
Usuffig.
04ke,
Name and A,ffMotion (Sampler(,),Ice� �11- -Z�I, AM Data sheet Renew:
Name and Afffttion
Wifll IfiformatiOn Date! 11403 By.
wof la Well Locked,
W,ell D lameter- Construction: . OQSteelfgtafrdess steel)
multi Factor -a- �IK-�,-
Static, Water Level..- 3-C, C —3ft CasingVolume: gallons ns.
Height of Water Coluftn,SP7-it Cal. ;ganon.$
Pump intake. ----
Purge Wormation
Date Purged: Start
Purging Method_YotalVolUroeFUrged:
Sam Wfingftlonna� �'Gn
Dat I eC I a I U I ecte N) [IS-,/Z3
-Lb — Time Collected-.-
Sampling Equipment Used: &� IR-r
Bottle Type Preservation Analysis Required
Field Measurements/Observations
Sample Temp (oq:
•Time;
oiss oxy
Time
Fe 2+ mg/L-.
Specific Coo& (uS):
Time:
I %) 3 J
Res. Cl (jng/L)/(gg(L) -
S=Vle pH (s.u.),i
Time..
IJ3b
Odor:...zte
—Time:
) 1z;! c3
ReDox (mV);
Time:
i `43 O
Appearance: <12elvl-
lime: —L'43U
ReDox(EH value):YSIPr,oPlus.+200mv Other
Wind. 0 (mph}
Sampler Signature
Stabilization Test
Time
Purged
Temp.Diss.
CC)
Oxy.
(Ing/1-1
Spec.
Cond.
(US)
PH (&u.)
ReDox
(MV)
Turbidity
(ntu)
Volume
removed
(gallonsom
L)
-
Water
level (ft)
Other
loll
15'. 3
3
-13 -
11
st t
-+-el2.
Li
IjU
\,-, 3
'4_13
-CS, 1
5, -L
�%
-z,
15, 3
5,z
-j-C, ?L
-Z '3
'34.z_s
ES1,5
=l-
I
=71 Q
15, 1
1-4-310
.

General/Weather Observations:
---( by/cloudy/rainy) Temp 53 (°R) GsFind o _5 (mph)
Sampler Signature:Date: )c,/!' /2.j
Stabilization Testy
Time
Purged
TTemp,Dins/L)
(C)
S ec
Cond.
pH(s.u.)'
ReDox ''Turbidity'
o ume
removed
Water
Other
(mg(L)
(PST
(mV
(rite)
(gallons%tir
level(ft)
�01,1
D.

'
or 0
Docmaient Name Field data Sheet
bate issuedt Marcia,&, 2019'
Page: I of 1 .
� 8/itk91Y!/Cd!'
tlooument Number. F-CAR-F[.17-001-rev.63
Issuing Autborityp Pace Humersville Quawy
Office
Field
Data Shee t
� n Client: ra � t- A n�i Location: 1 A G n n� . w S'IP. ra rrs KIG Project C
i/
Name and Affiliation (Sampler(s):�_.[G
Field Data Sheet Review:
Name and Affiliation (Inspector):
Date:(p/ 2 4 ( 23 13 Td3j
y,
4Ve11 Information
1 w (2� � j,jJ, 1
WellID: C, C'P IrA
Well Locked: (1�91/
NO / Flushmount)
Well Diameter: ��
Construction: (P /Steel/Stainless Steel)
Total Well Depth: q L4 t '3 fE
Multi Factor*: 3_ r(R1diu1/12)2 x 114 x 7 agl
Static Water Level: G P go.CJ t
Casing Volume: �� gallons
Height of Water Column: :7� ft
CaL 3 Volumes: --' gallons
Pump Intake: h '2- d — ft
Purge Information
Date Purged: Lt /IG /_Zt3__ Start
7
: O'LFuush: �, i t 0 Pur1ge Rater
Purging Method: B L 4 ati AfP
Total Volume Purged: _j2-,5_a (gallons/ tls/L)
Sampling Information
° p
Date Collected: l,C� /�D/Z3
Time Collected; c r s.a (n&pm)
Sampling Equipment Used: Ct
Instrument ID: if i lW 5 I y
Bottle Type
Preservation Analysis 11equired
Field Measurements/Observations
Sample Temp (°C}:
Time:
� � Turbidity' (ntu). __f2_L_j,__ Time:
DissOxy'(mg/L): �` i $ Time: `
Fe2+mB/L: At `Time:__
Specific Cond. (us): Time:
Res. Cl (mg/L)&g/L): ` Time:
Sample pH (s.u.): - ,-Z— Time:
ReDox (mV): �_� u q Timer.
, Appearance: Qj! C C Time: _
ReDox (EH value):YSI ProPlus +200mV - 1 l�_':� Other: Time:
General/Weather Observations_TCj—.2,
�L� ff e� (T_ Vx P i':C
( trit y/cloudytt/rainy) Temp.t_!4_(QF) Wind 3 _(mph)
Sampler Signature: �
Date: t�� ��� 2?
Stabilization
Test
Spec.
Volume
Time
Temp.
Digs Oxy,
Cond.
pH (s.u.)
ReDox
Turbidity
removed
Water
Omer
Purged
(C)
(mg/L)
(US)
(Inv),
(ntu)
(gallons/�/
-
level (ft)
5 iv.
)U
o
''
)
i
Z l ..
bJ
7
14
12.i6
0la l7t`l Der h2,5 kIZ Oil 6,� I2I, &� roP

dir IFPage:
Oueuntent Name: Meld Aafa Sheet
Datelsaued: March &,.2mx
1 et 2
:.
Document Numt+er: P-CAR-xi.17-tlQl-cev.Q9
Issuing Autlnonty Pace Htmtecaviite Quality
.Office
�2CeAttalytiCt+!`
I
Client: 611Se Lora
Flame and Affiliation (Sampler(s):
rreu ur. cv - Well Lucked, ((izzyi iuu/ rtusnmuum)
Well Diameter: ) ' Construction: (t&/Steel/Stauiless Steel)
Total Well Depth: 'i) SQ ft Multi Factor*:0.163 r*(Radius/12)2x3,14x748j
Static Water Level: (OO —6 it Casing volume: `l. 9 s gallons
Height -of Water Column:.�5S ft C41.3. Vglumes: gallons
Pump Intake: 10 ft
Purge lnformat
D P 10 1$ 2 0 (c�2( .{2�y
at. urge.d . /uf tart. Fixtu At l urge Rate:
1nl
Purging Method: l"
Total Volume Purged: O(3v (gallons Ii /L)
Sampling Information
DateCpllected: /u /A&/ )1
Time Collected: 'I�2S (am/ .
Sampling'; Equipment Used: 61"Ltl—
Instrument ID: Y5Zk1/C76 -�L 1 Pw4'609'1-
BottleType
Preservation Analysis Required
Field Measurements/Observations
Sample Temp CC): f Time: ; l? Turbidity (ntu); I .:r) Time: 1),) S
Diss Oxy(mg/L): 3 `( Time: Pe 2+mg/L: / A Time: ) 22 $
Specific Cond. (uS): ; )IR.S Time:
Res. Cl (izgJL)/(ltg/L): — 'rime:
Sample PH (s.u.): _� ,i Tirne: "
Odor:-- A, 2� -�_ Time: , 2i a F
ReDox (mV): ��. Time:
Appearance: CG(0. — Time: P15
ReDox (EH value):XSI ProPlus +200mV a C Other: — `rime:
General/Weather Observations:
u y/cloudy/rainy) Temp.-iU (°F) Wind_(mph)
Sampler Signature:
Date: /ca�7ff �u
Stabilization Test
Spec.
Volume
Time
Temp.
Diss Oxy.
Cond.
pH (s.u.)
ReDox
Turbidity'
removed
Water
Other
Purged
(C)
(mg/L)
(US)
(mV)
(ntu)
(gallons/&/
level (ft)
L;
a )0
K-8
q. I
I I .
f (3c) G'
L4 : p
t1, 1
I11. ,
_
Li—
I�Io
)s.
HM
5.6
q9j
I t1'
1 3000
1LJ ISz
u3: q
y. 5
/- L)
�'3
jcjci,,,

��� _
c GBF1/TTc3�yilCr3%
,t
Document Name:
Field Data Sheet
Document Issued: Much 8, 2019
Page:0
Dvcuntent Number:
Issueing Authority:
t
F-CAR-FLD-001.rev.03
Pice Huntersvitle Quality Office
Nell Diameter Multiplication Factor* I
Client: L)tnl4�(a� l
%� Location: otxz-,�-� A hu, C-
Project: i_t-S (q L1= Pan J Ste.
MUD: CLP M ➢ -2 1�
Reviewed Date and By: 101 au(I *3 1
Stabilization Test I (I Q s� 23 -i"�
1
0,0403
1.2
0:0913
1.625
01030
2
0.1630
3 _
0.3670
4
0.6330
6
1,4680
8
2,
6100
Time
Purged
Temp.
a
Qiss Oxy.
(mg(L)
Spec.
Cord.
(u5)
pH (s,u.)
ReDox (mV)
Turbidity
(ntu)
Volume Removed
(gallons/di s/LJ
circle:one
Waterlevel
(ft)
Other
11&
J.y
al
0C)0
r)-.17_
Illu
I
M--7
'36.3
t,v
11000
-y. 55-
it)-0
I6:2-
3.(,
125.6
1 1.0
(i(-I
IS000
S.gS
_
113o
ib.)
i,s
t 27 i
I.5
1 5 c oo
C. i'
-
ILO(
I(o,x-
�4-
12L6
8 0
W-4
0.8
al000
121U
I�.S
3.
11cl.
v
I61
`SS-i
111,N

(� 8J11Fl1ylICt11
IBoCumentName: Field elate sheet
Date Issued: March 8, 2019- .
Pa e: i of
CJocument Number: F-CARFIS3-0Ol-rev.03
Issuing Authority: Pace HmrtersvilleQuality
Office
I
1
I
c
I
m
]ata Sheet
Project #_cis c� p f P
�C_ Field Data Sheet Review:
icy O9l:-�
Date: -5�2� Eyj
)0/2
-�-� YYcu ING/,.r1VDHIUVLHILi
peter: tI Construction: (&V /Steel/Stainless Steel)
It Depth: 3 b •c-I 1 €t Multi Factor*: Q...�_ [ (Radiusll2)2 014 x 7,481
ter Level X, - ( I1 ft Casing Volume: gallons
'Miter ColujrVu- 14tu ft CaL 3, Volumes; 0�4 gallons
Pump lntake: !"' 33 ft
ormation
;ed: I. O !/8 f a3 Start:05Sc; Finish: 01'�S Purge Rate /0-01L,-'
dethod: PL. n-IIJ Total Volume Purged: 2.000 (gallons/&/L)
Information
ected:10_/ 15'c/ z3 TimimeCollected: ' IOC: ((@k/pm)
Equipment Used: NoLo r hoi p Instrument ID: ` 514 K -7 I) Pc, 4 CUy}
ittleType Preservation An4alys'iisltequired
Field Measurements/Observations
Sample Temp CC); I 1 Time: f�(� _ Turbidity'(ntu): P.1 Time:
Diss Oxy,(mg/L): 5 Time: Fe 2+ mg/L: Time: 1�0
Specific Cond. (uS): I O} Time: Res. CI (mg/Ly(itg/L): --'rime:
Sample pH (s.u.): -i - Time: ; Odor:_.'_ np^-< 'Time: _.j 00__ _
ReDox (mV): 1 \ 1 • Time: Appearance: da -/ 'Time: 100 O
ReDox (EH value):XSI ProPlus +200mV 3) IA Other: Time:
GeneraVWeather Observations:
( y/cloudy/rainy) Temp.1 O (°F) Wind 3 (mph)
Sampler Signature 646 ' Date: 1 J/l$ I-� 3
Stabilization Test 61
Time
Purged
Temp.
(C}
Diss Oxy.
(mg/I,)
Spec.
Coed
(US)
pH (s u }4ReDoxTurbidity
(ntu)
Volume
removed
(gallons/ i s
L
Water
level (€t)
tither
OC)Lis,
G.-
r.s
tjou
-
LictS� :
G o
1J3.g
S
t,> -7 -5
1 1.6
Isvi
&t5 'i
I
IIO.C1
I D•Y
'10-
V-

act3s3Nu1yGcal.
Document Name: Field data Sheet
Date Issued: March 8. 2fn9 '.
I Page: 40fa'
Docummt Number. F CAR-Ft.D-001-mv.Q3
wing Authority; Pace FAmtersvitle-Quality
Office
Field Data Sheet,
�/�
Client D(.ye
,n
Location:_�At=AMO' VC Project #: _—_ �f b11{ .�rytQluh�
Name and Affiliation (Sampler(s): gA 'SQ '_
Field Data Sheet Review:
Name and Affiliation (Inspector):
rJ�
Date: 1LY2`l) 23 By:
WeII Information
l o/ 9t" /yy j 11
p
Well ID:: ` (KUJ-
Well Locked: ( E
/ NO / Flushmount )
Well Diameter: ran
Construction: (p/Sfeei/Stalnless Steel)
Total Well Depth: It
MultiFactor*: 0& _r(Radius/12)2x914z7.481
Static Water Level: oZ9•g�$' ft
Casing Volume: (.QA ,_ gallons
Height of Water Column: 3�{.43 fE
Cal. 3 Volumes: %A•X gatIons -
Pump Intake: LOU, Obkr - ft
Purge Information
DatePurged;_YZ/X`a_f
�� Finish: Purge Rate dWt hl(�
1r'7� --S
Purging Method: �
``tart;
1 Total Volume Purged: ' f3>0 (gallons/&/L)
Sampling Information
Date Collected.. to ��7
Time Collected: 1040 &/�Pru))
Sampling; Equipment Used: DO.
�y
&OA Instrument ID: qc� i�'t31`�r�
Bottle Type
Preservation Analysis Required
Field Measurements/Observations
Sample Temp (°C):----L'A,-5—Timei O—�'l'-�"". Turbidity;(ntu): a.7 Times �Ai o
Diss Oxy (mg/L): 3ro Time. _ _'j0 Fe 2+mg/L: JD Time: 1040
Specific Cond. (uS): '1�. Time:. " Res. Cl (mg/ty(µg/l): *rime:
Sample pH (s.u.): Time: 1040 Odor:_,;._
ReDox (mV): : g Time Ifigo Appearance: y / rime: WAO
ReDox (EH value):XSI ProPlus +200mV Other: Time:
General/Weather Observations:
( nn-D/cloudy/rainy) Temp_S3 (°F) Word -VS (mph)
Sampler Signature: Date:. to 181a3
Stabilization Test
Spec`
Volume
Time
Temp.
e
Diss Oxy.
Cond.
pH (au:)
Turbidity
removed
Water
Other
Purged
(C)
(mg/L)
(US)
(ntu)
(gallons/�l
Ieve1 (ft)7.53'
jReDox
'I
- 00.v1Ghb
w'
;tea csftpAjal
, .
1 5
W 0ILA.%
1 2p, bi
103,'h
1 10
13ai
I bc3
wit

- , c7GBAtT�7/yrllQtii
Document Name:
Field Data Sheet
Document Issued: March 8, 2019
Pag4of j-
Document Number:
Issuemg Authority:
F-CAR-Blip 001,rev:03
Face Huntersville Quality Office
1Vef1 Diameter Multiplicationation Factor*
Client: wC
xo
Location; Mw(d-)
Project: C� _ l�l' K —KJ(i4 at 01oukA
Well ID: �GP(�►uj-4
Reviewed Date and By:_.
Stabilization Test
ll
• 0 •Turbidity
• EMIM �������
®®®®®®®®®®
®®®®®®®®®®
®®®®®®®®®®
®®®®®®®®®®

Uocumen}'tJume: FieYtl data Sheri Pate Issued: March g,2o19
CelitkllytlCal' 1'a
J � Dmument Number: F-CAR-FI D-001-rev.03 tasumg Authority: Pace Himter4vill0 Quality
Office
j��� Field Dat Sheet p
Client:-A�'��`C � Location: (0 Project#:GLS_�eQlf le('���c1MPL(
Name and Affiliation (Sampler(s)• -Q(d c R Field Data Sheet Review:
Name and Affiliation (Inspector): it)/ 2`1123 1"�i
Date: By: �.
Well Information ) O l Zrl 9-3 IOHM
Well ID: iiPMW .:5 Well Locked: / NO /, Flushmount)
Well Diameter: au Construction: (CV/Steel/Stainless Steel)
Total Well Depth: %J.- ar ft MuIN Factor*: O, U r(Radius/12)2 x 3.14 x 7 4s1
Static Water Level:A3 ft Casing Volume: S a gallons -
Height of Water Column: � -a3 Ft Cal.3 Volumes: �$•� gallons
Pump intake: %7u. CD�1L It
Purge Information
Date Purged. to /� f�3 Start :_ 9 5 _ Finish: 145D Purge Rate:uWt
Purging Method:__ L-AAIIt"W Total Volume Purged: 00 (gallons/(9/L)
Sampling Information �q
Date Collected:_to_/ ($/ �? _ 1 ' Time Collected:—
Sampling^aI �J1
, Equipment Used: ► Mh Instrument ID: q-x5)!4 f1 tl��ttr_S &o
Bottle Type Preservation Analysis Required
Field MeasurementgQbservations
Sample Temp (1q:.___i--5—Time:, 'A Turbidity(ntu): S:q Time:
DissOxy(mg/L): Y/.1 Time., M51Fe2+mg/L: JP Time: 1455
Specific Cond. (uS):. V15.3 Time: '- 114255 Res. Cl (1ng/L)/(µg/L)zt Time:
Sample pH (s.tt.): _ Time: lyrj Odor:
ReDox (mV): ��l�.� Time: 1455 Appearaneen4P404' h-0 Time: O
ReDox (EH value):YST ProPlus +200mV 35 Other: Time:
General/Weather Observations;
(s nny cloudy/rainy) Temp. %-S (°F) Wind_j:-: _.(mph)
Sampler Signature-.
Stabilization Test 61�ret z
Time
Purged
Temp.
(°C)
Diss Oxy.
(Yng/L)
Spec.
Cored.:
pH (s.u.)
ReDox
(MV)
Turbidity
(ntu)
�•Vo utne
removed
(gallons/ 11s
Water
level (ft)
Other
(US)
Q.3
U:'
l7.
°I.
.3
�i.�
tN'
µ
A .
Its
--t
1.
%0-
44-0
�.
,PU-7
h.
1
d•
1w
.63

Dac=ent Name: Docuncent Issued: March 8, 2019
Field Data Sheet pagedefa
_ ... c7CPAikT/�ICAt
t Document Number:. issueing..Authority:
F-CAR-FLLD Utri.rev.03 pare Huntersville Quality Office
Factor"
1
0,0408
1.2
0:0918
1.623
0.1080
2
0.1630
3
0.3670
4
0.6530
6
1.4680
3
16100
Client: �p LO ,��Y'f7l u
Location: IY�t�OU(rwc(9p,�
Project: QUS- C� Lf —Pef r44- r. 01 t/Ld
Well ID: Cf�M W
Reviewed Date and By:
Stabilization Test I Q N-V 2-3 f r1f
Well Diameter Multiplication
Kiln
Own
Me
®®®®®®®®®®
®®®®®®®®®®

lhxumcnY Name: Field data Sheet
Date Issued: March &, 2019'
Page: 1 of J
Eelllr7/y7lCtil
Document Number. F-CAR-FI.e-0Ol-rev.03
Issuing Authority: Pace Hsmtersvftle Quality
ff
Office
Field Data Sheet
Name and Affiliation (Sampler(s): /A L 149qce Field Data Sheet Review:
Name and Affiliation (Inspector): Date: 10/ a i I J3 By: FMO
Well Information
to / �D 2-3 ip{ A
Well ID; _r .P M 6 — J
Well Locked: / NO / Flushmount )
Well Diameter: �, r t
Construction: (l V�/Steel f Stainless Steel)
Total Well Depth: 7�j_ft
Multi Factor*:[•(Radius/12)2x3:i4x7481
Static Water Level: 0-7_fk
Casing Volume:
I , 2 3 gallons
Height of Water Column r � � ft
Cal. 3 Volumes: _il,_69 gallons
Pump Intake- L/ ! ff ft
Purge Information- � �1
Date Purged: i G f 4 /_� Start : OG Finish: �) (_ .Purge Rate: e �1 G s /A f k
Purging Method: (fZ i r � 0 Total Volume Purged:... (gallons/tt�+ L)-
SarnplingInformation'�j
llate Collected:_16 /�/ 71 Time Collected: I 2O.__ (am/ t�'n
Sampling Equipment Used: 8 t q l r t- Instrument ID: mV 5X 2®
Bottle Type Preservation Analysis Required
Field Measurements/Observations
Sample Temp (°C); O-; Time; ` 2 _Turbidity (ntu):_ Time:
Diss Ozy (mg/L): � Time. Fe 2+ mg/ AZ 2 Time:
3 2c,
Specific Cond. (uS): tj p , Time: Res. CI,(mg/L)&g/L): Time:
Sra7lple pH s,u.):-1f Time: Odor: , ivfl ---_,—Time: t C7
ReDox mV 9 Tim& \ Appearance: CIeV(P Fime: 13 2
ReDox (EH value);YSI ProPlus+200m.VS�Other: Time:
General/Weather Observations:
(Dfcloudyfrainy) Temp.40A_(°F) Wind (mph)
Sampler Signature; Date: bG l
Stabilization Test
Time
Purged
Temp.
(C)
Diss Oxy.
(mg/L)
Spec.kReDoxTurbidity
Conti.
(tiS)
pH (s.u.j
o tune
removed
(gallons/>�s
Water
level (ft)L1,0
Other
5 Z
ccp
lk
S,)
SIC
•2
f,21
iu,
fi,
I ('U
2-

Document Name, Field data Sheet
Datetssued: March.s, 2019
Pate
dE8JiI1F1%f%Cat
i. A
Document NumberF-CAR-PT.Ip-pp1-rev.p3
lssuing AuthoritysPaceHtmtersville Quality
Office
3
Name and Affiliation (Inspector): Ia) 2`tl J `JY3
Well Information Date: jJ By. r^ H /
We11 ID: C� M w to Well Locked: ((U/ NO /:Flushmount )
Well Diameter -21' Construction: (1 C/Steel/Stainiesssteel)
Total Well Depth;—"—,(—)(—) ---it Multi Factm-,0.141 r(J9adius/12)2x3.14c7.481
Static Water Level: 3J_,4 ft Casingvalume: 3-88 gallons
Height of Water Column: �Z3.$Q ff Cal. 3 VoIutnes: ll: c i .gallons
Pumpintalce: ft
Purge In€ormatian
Date Purged: )0 1 iS /. ..... . 5fart:1-1 7S_0s7 Finish: j 2 Purge Rate;
Samv1.
Date C
Sampli
thod: NcAAa(-✓ rQ'-Y Total Volume Purged: Laoo (gallons' tl /L)
tformation 1330 At— ro i %)> 7
ed: 0 /A/Time Cotlected (am/Cm',
luipmentUsed: strument ID: gS1tf/C7�7 jlows�c�°7
e Type Preservation Analysis Required
I- C� 4- __
ield Measurement
ample Tamp CC)::
tiss Oxy (mg/L):
pecific Cond. (u8):
ample pH (s.u.):
eDox (mV):
eDox (EH value):Y
;eneral/Weather o
/Observations
A Time: As�
Turbidity;(ntu): (J A
Time:
1 :Z�3o
Time:
Fe 2+ mg/ L: I
Time:
1 � 30
�1 • Time:
Res. Cl (mg/1-Agg/I ):
--rime!
.� -Time:
Odor:_ _ ✓13 - t�
Time:
_ 1330
-5,�_ Time.y
Appearance: 641
Time:
1330
it Proplus
other:
Time:
J
nervations:
su /cloud /rain ) Tem
I (° Wind 3 h
11
y y y P• (mp )
Date: f6 a/12-"
Spec Volume
Ox : ReDox ; Turbidity ' removed to
Time '
Temp.
Diss y
Cond.
PH {s.u.)
y
Water
Other
Purged
(C)
(mg/L)
(us)
(mV)
(ntu)
(gallo� /@y/
level (fit)
13to
20
(3
`(I.-4&I[
0,�
X7
3 .25
?c
3
(o. 4
Co. -10
MIS
`i • $
C U
$G1C).
1
31a
—U
1
3
t�
L19-�IO�
y �

s?EBAt7Fllyf/Ettf%
Document Nome: Field data Sheet
-
Date Issued; March B• 2019
1'u e: 1afj,
Dmument Number. F-CAR-Lf.D-001-rev.M
wing Authority: Pacel3mrteria, lIe Quality
Office
FieldData Sheet
Ct4onf, 1).fmo- ri n0 /L� Tncatinn• Mt�n.Oc 1.n n. !J! T3rn.nnt N•/r L /fin t`.Con
- -r .*=�-s-�--•tea--.�•_-�• ... '..
Name and Affiliation (Sampler(s): R jA A f f e-;Field Data Sheet Review:
Name and Affiliation(Inspector): MIA Z3'Well Information ate• /�3By. 1=Welt Iix al! Mp/- 7 Weell Locked:NO / Flushmount)
Weil Diameter: 2.; !� Construction: el/Stauiless Steel)
Total Well Depth: S1.07 ft Multi Factor*, •16 r(Radlus/12)2x314g7.481
Static Water Level: 42.Sa T.44_ ft Casing Volume: gallons
Height of Watei Column: N /4 it Cal. 3 Volumes: �! gallons
Pump Intake: "''19 ft
Purge Information
Date Porged:_10 / 'U i 7.3 Start: OQ45 Finish:_0-5 PurgeRatei 59"^151A, 1
Purging Method: 010.1 trope 1. M Q
: Total Volume Purged: 1 S 04 (gallons/oil)
Sampling Information
Date Collected:_JOJA_?r
Time Collected:'' 1040 am m)
Sampling -Equipment Used: 8la.Adtr
PtdMp InstrumentlD: YSIoSba jT%1vu6noq..._
Bottle Type
Preservation Analysis Required
Field Mt'asurements/Observadons
SampleTemp(C): ►(b.Z Time:_LR_avTurbidlty;(ntu):
I. Lj Time: 1040
Diss Oxy (mg/l): 5.b Time:
Fe 2+ mg/ L: N D Time:
Specific Cond. (us): 7 !b• 4 Timer
Res. Cl
Sample s.u. ; y• Time:
PH
P ( ) �_:. _
Odor:—. _
-1�J 9 n Q Tune:.. l o U�—
ReDox(mV): 1517 Time:
Appearance: LjPo! Time: 1
ReDox ($H value):YSI ProPlus +200mV i 3. 7 .Okher: �- Time:
General/Weather Observations:
sunn oudy/rainy) Temp. 55 ff) Wind-0-5 (mph)
Sampler Signature: Ry 0.A. %y e.
Date:. to 118 /Z
Stabilization
Test
Spec.
Volume
Time
Purged
Temp.
(C)
Diss Oxyr
(mg/L)
Cond.-
pH (s.u.)
ReDox
(Inv)
Turbidity
(ntu)
removed
(gallons mis
Water
level(ft)
ether
(u5)
L
0QSo
, .q'
5.7-
1
6.a
7.1.
459
?%M
0tk
15
f3
'xi .7
5o
Belo Z
S
i i.
t3.
181.0
S1,4
5,010
1005>.
16.5
1 re.0
I Im. h
I G 5
1142.0 ',1,77.9
1 loos,
10 15
117.3S.b
I aj.ip
1 9.5
1 Al.
go-tA
1 ISO

a
�e�natyficaf
Document Name:
Field Data Sheet
Document Issued: March 8, 2DT9
Page I of �.
Document Number:
F-CAR-F4D-00l.rev.03.
Issuemg Aathonty:
Pace Huntersvitle Quality Office
C$Tell Diameter
Client: b44Cei E w2ly y 1
Location: /AD VS born., Ai G 1.2
Nfulti licatiori Factor"
Q-0408
0:09118
1.625'
Project: U,FFS-'Ze- I C e L F- f�,+pt:0.aL-SoTP:'n� 2
WelllDt G.(,PAv/ - 7
4
Reviewed Date and By: T,)1D 101141 as 6
o/ f�3 7�
Stabilization Test - 1 8
4.1080
0.1630
0.3670
06530
1.4680
. _.. _
2,6100
Time
Purged
Temp.Diss
a
O
O xY
(malt)
Spec.'
Cohd.
(US),
pH (s.u,)
ReDox (mV)
Turbidity
(ntu)
Volume Rem ved
(gallons mJsJ
circle one
Water level
(1})
Other
162
S .
19 q 2
-1
I .
200 o
getov

pnegmeotNUmF: Pieta dalaotteet
Dat+ tasuei6�klarch-B, 3{i44 , .
page: at_�
eft, Al
Clocument Nuningr. F-CAPS-F(.1�4Q3-rev,Q3 -
uing'kuthoziiy unketsvil :Qualiky
Of*
Field Data Sheet -
ks/ciouuy/ramyl iemp., jkri xvinn tmpn1
npler Signature.— I-- ` Date: to - i 8 - 3
ibilizationTest
Time
Temp;
Dim Oxy;
Spec
Cond.
I I s n
F {
ReDox
Turbidity
Volume
removed
Water
Other
Purged
(�Cj'
(tngJI)
(to)
')
(,,IV)
(ntu)
{gattonsJro
level (£t)
L_
0925
J
5.v
5.1
-IgIV
.2.
ti s-o
3•_•vo
v
16,o
Y7,1
5.o
51
-74.Y
3.7'
30
t5.0
U-9
SIA
5.1
U4.1
0-A
f o
to;oo
0`l
IS--1t-le
5-b.
5.0
51p.
.z.Z,
i 3sa
l�.a
4D
(U-0
tp. •
I L19,5
L S,b
1 50,'3
1 33.9
1 t F00
13FA5
P-emoved- bladtt-e.r evj> r afTer vRYo re4d,'ng. DrcPPpd

eeAfr��lytrn(%
Document Name:
Field Data Sheet
Document Issued: Mush 8, W19
page �+ f _�
Document Nwnber;
Issuehzg AuBibrity;
F-CAR-FLD-I101.mv.03
Pace HuntersviRe Quality Office
Client: Vvl-c Et.-4- 4
Moo res6o: o1N/C.
Location: Ica, t Sti %I -- MYC to•tLa-A
project: GL5 cc P CF Pe v, .Su �li�c,
Well ID: C crmw - ID
Reviewed Date and By: 101 I'l 2-,3
Stabilization Test 10'25-%23' I�Nm
XVell Diameter 'Multiplication Factor
1 0.0408
1.2 0,09i8
1.625 0.1080
2 0.16,30
3
0.36�0
4
0.6530
6
1.4680
8 2.6100
Time
Purged
Temp,
(°)
Diss Oxy,
(mgJU
Spec.
Cond. J
(us)
pH (s.u.)
ReDox (mV)
Turbidity
(ntu)
Volume Removed
(gallons/I ?JL)
circle one
Water level
()
Other
15115
fA+e
` goMLIMI.,
tK
Ate: Ll�
+ v-,
o .
55
lo®o
(8•5
5.S
48`j
5. a.
19.0
31a•7
2y00
3 `15
005
18.`1
S.1
4$`0
5,,)
1a.3
43U,3
"3oc)a
35.95
1610
!&W
5t.U1
41.g
5.1
W,I
319.5
3U00
35.15
,r O-t
ckg9 c
td To
3c)o,
//
/M,'. '9
IUiS
181
5.7
q-l.4
5,D
10,9
187..3
S100
35A5 `
jro:w
18`Ia
5.(P.
47.3
S,D
11.3
1,;t
COU00
1 35.15
1n25
I81;9
5.5
1 47.4-
S.LL)
1 1D.7
DUJ
9100
35.95
Wo
I V,$
5.5
47.0
5.0
TU
19. 1
9la0O
35.9S
I03S
i9-$
S.S
47.o
57.0
-7 `I
10,1-0
Mao
35.95
0417
13,7
3,5
'{la` 1
5.1)
(e •`I
V7
I ZUOo
35.95

Document Name: Field data Shevt Date Issued: March 8.20t9�
..-., .viceArkAlyfiCal' !'age; 1 Of,
Issuing Aufhouty: ]'are Huntersville Qualit Ducuntvnt Number. F-CAR Pl.tl•Otll-rev.0.'l y
Office
`` ,, Field' Data Sheet
Client: WL�' Fl�ZLocation: N_�rajec"" CLS � e.� Lf
Name and Affiliation (Sampler(s)��7 p CR Field Data Sheet Review:
Name and Affiliation Inspector): T-)b
Well Information Dam' Zt 23 By. j )iAA
Well ID: CGPM W - 1 Well Lacked: 4775 / NO / Flushmount )
Well Diameter: )C/Steel/Stainless Steel)
Construction:,
Total Weil Depth; S�ft Multi Factor*: 4 1'-'1 r(Radius/l2)2x3.14 x 7.48]
Static Water Level; `� • %� ft Casing Volume: i` 3 ` gallons
Height of Water Column: �Z, Q 6 ft Cal. 3 Volumes: gallons
Pump Intake: ?J 1 • ft
Purge Information
Date Purged; t 0 _/ t'3 /_. _ start:: I Qss Finish: 11 I C) P rge Rate: 1' 0 rn L I rn in
Purging Method: c C,111C� Total Volume Purged: ��- OO allon s L
(g / }
Sampling Information
Date Collected:.f -�_./J 3 /_12_ Time Collected:
Sampling Equipment Used: t?('sk11" QwO InstrumentID:
Bottle Type Preservation Analysis Required
' Ae Kt
Field MeasurententalObservagM
Sample Tamp (aC): _Ti'ime: 1 1 } Turbidity (nm): a `I Time: 1 I 1
Diss Oxy (mg/L): Z Time: I \ 1 Ee 2+ to L:
g1:—.IyLTme:..l. \ \ S�
Specific Cond (us): SL1�3 Time: I I — Res. Cl (mg/Ly(µgfL): — Tune:
_—
Sample pH'(s.u.),as_Time: 1 11 Odor: Trme; I 1 f
:ReDox (mv): Time: ,111 Appearance: CAI ?-ul Time:
ReDox (EH value):YSI ProPlus +200mV / 1 � & other: Time:
General/Weather Observations::
_( unn cloudy/rainy) Temp.,S3(OF) Wind (mph)
Sampler Signature:_ - Date: lea 1�
Stabilization Test
spec. volume
Time
Purged
Temp.
(aC)
Diss Oxy.
(leg/L)
Cond•
(US)
FH (s.u.)
ReDox
(Inv)
Turbidity
(ntu)
removed
(gallons/ i/Llevel(ft)
Water
Oflter
b.
S.
- R,
a.
5 0te.
ca
---
IB .
3
5�•
5. ,
-
\1
L-Dqno
Asa

gocuulent Name: Mehldate Sheet
Plata Issued: March %2b19
Pa re: 1 of -�
aCeAnalyfiCilt
rFkicumant
Number, F-CflR-Rl.nrtl01-rew.Q3
Issuing Authority: Pace ;fiuntorsville Quality
Office
Field Data Sheet
Client; � t�rPj Locatial:_.C�. a e rc� Lk Project #: CL S GO LF Okra"
Name and Affiliation (Sampler(s): - �CccR Field DataSheet Review:
Name and Affiliation (Inspector): 10/ a i I a a T) O
Well Information Pate: 'O/� 12-3 By,
Weil ID: GQ LZOtiGI tLyie
Well Diameter: Cons ruc ion: Steel Stainless Steel)
Total Well Depth: ft Multi Factor*: [*(Radius/12)2034x7.48)
Static Water Level: ft Casing Volume: gallons
Height of Water Column: v ft Cal. 3 Volumes: gallons
Pump Intake: ft
Purge Information 3 j al t8 tb7
DatePurged:_�: 33��- Start � Finish: Purge Rate:
ho0ox',
Purging Method: t Total Volume Purged: (gallons/mis/L)
Sampling Information
Date Colleeted:,_J_p_.J 13/ ),3 Time Collected: A - 2O (a /pm)'
Sampling Equipment Used: (2 rLA 1 Instrument ID: yS>
Bottle Type Preservation Analysis\ Required
Field Measurements/Observations
Sample Temp (0q: Cck • _'Time: 1 O-�' C' Turbidity[(ntu): Q rime: to
Diss Oxy (mg/t): L �Time: \ O 'Z�-Q Fe 2+ mg/L: n rime:
Specific Cond. (us):3L Time: o2�"C "Res. Cl
Sample pH (s,u.): 14,q Time: � . Odor: fu-)) Time: O O
ReDox (mV): \ �A b Time: i O HO Appearance: � � Pr' i Time: l ��
ReDox (EH value):YS1 ProPlus +200mU 2J0'-t • � Others Time:
General/Weather Observations:
sunn /cloudy./rainy) Temp.3`t (aF) Wind (mph)
Sampler Signature: Date: I I I_
Stabilization Test
Spec... Volume
Time
Purged
Temp-
{ C)
Diss Oxy:
(mg/L)
Cond.
(US)
pH (s.u.)
ReDox
(mlh
Turbidity
(ntu)
removed
(gallons/mis/
L
Water
level {ft)
Other
tA�q
1 Kf
0

Document Hume. Field data;Sheek
Date Issued. Mardb s, 2019
1
1'a e. 1 of
e4C6Nt11/j/(lCw4/
Issuing Authority: Pace Hun tersvilleQuo Uty
Document Number, F-CAR-PI.R-001-rev.43
Oiee
Field Data Sheet
Client:2nd
lti� �QQC� Location;NCName Affiliation n {Sat p (4): —� 1�a 2 Field Data Sheet Review:
Name and Affiliation (inspector): N
trll ahl 23 V 7S1>
Date: By:
Well Information
Well ID: CGQ- LreiALA-c,34
p d tnvr�n a r s" lessSteel)
Well Diameter: — Con,;. ---
Total Well Depth: ft Multi Factor*: ("(Radius/12)2x 3.14 x 7.48)
Static Water Level: ft Casing Volume: gallons
Height of Water Colunm: ` �ft Cal. 3 Volumes.: gallons
Pump hitake: ft
Puree Information _
Date Purged. / — / _ —Start:. _ .Finish: Purge Rote,
Purging Method: Total Volume purged: _ (gallons/mis/L)
Sampling Information
Date Collected:_( 1e /31/ )'3Time Collected: (o aain0, m)
Sampling Equipment Used: & rah Instrument ID: �5I ropGin� pYlt (sorr't bt 3a
Bottle Type Preservation Analysis Required
Field MeasurementalObservations
Sample Temp (°C): —I!- & Time: Turbidity (ntu): (° Q Time: 'V)
'-) I . r . .,_ ,,, __ ,, . b O
ReDox
Genen
Sampl
3 (s,u.): ' 1
t Time: 7'0 Res. Cl (mg/L
W�ine: Q mOdor:
Time: i Appearance,-
leather Observations;. _
mia Nrra
( unn clou
Tune.
CI-eCr Time: l n3O
Time:
Temp.(°F) Wind�_(mph)
o une
idity removed Water Other
Time
Purged
Temp.
(aC)
Dias Oxy:
(mg/L)
Spec.
Cond.pH
(s u)
ReDox
(mV)
''Turb
(ntu)
(gallons/mis/
L
level (£t)
1 � ,
y 3 `1
�l .
0k .
SION
o
� 123

1>octmtn�u NAnr�., Ptcld Oil Sheet
mte issued. lvtamb 8, 2014
1iC@Alk'tlyllCr�l
Page. 1 of I
])ctcument Number. I'-CAR-}sl.l�'.007-rev 03
Issuing Authority: Pace Huntersville Quality
W
.,Office. .
1," Field Data Sheet
CGP�
F i��rtvc} r>�/T�
Client;yl ltet �' _Location:-C)naQ rS r
uC Project#: f3tE
Name and Affiliation (Sampler{ : '?6 E-R
Field Data Sheet Review.
Name and Affiliation (Inspector): N
i012H123
Well Information CGP sci �
Date: `0/250-
By. L>)-1M
Well ID: -
�ttr 11911'v�Y
hmoun()
Well Diameter: _ C
ss Steel)
Total Well Depth: ft Multi Factor .
["(Radius/12)2x 3.X4 x 7.40]
Static Wafer Level: ` ft Casing Volume:
gallons
Height of Water Column:--" ft Cal. 3 Volumes:
gallons
Pump lritake:
ft
Purge Information
Date Purged- / /= Start: .Finish:
_
PurgeRatet
Purging Method: Totu1 Volume Purged: (gallons/mis/L)
Sampling Information
Date Collected: mil(/j Time Collected:
l��l �✓ Q' an /ptn)
Sampling Equipment Used: Instrument ID: Y S1?
Bottle Type'
Preservation Analysis Required
Field Measurements/Observations
Sample ° ( �•(a
p p(C):
Time; c� 30 !'urlaidit ntu 3 Time: Eti130
y( ): ,a
Diss Oxy (mg/L): $'
Time '0-5 "�0 Fe 2+mg/L:
Specific Cond. (uS): 991,a
Time: 0 5 3 0 Res. Cl (mg/L)&g/L): 27 Time
Sample pH (s.u.):
Time: o cx i 0. Odor: &l� Time: io
ReDox (mV): 3
Tim: � Appearance: C (-Po.r- Time t !J 3 O
�ai
ReDox (EH value):YSI ProPlus +200tnV P✓-V - 3 Other: `� Time
General/Weather Observation '
,0 S [00r-J9 % 3 S" l I . &ST /J - 7
L1L3 � . 16b t LJ
((ulu /cloudy/rainy) Temp.(°P) Wind (Mph)
Sampler Signature:_(
Date:
Stabilization
Test
Time
Temp.
Diss Oxy:
Spec.
nme

1]acunaen} Name: staid data Sheet
Date issued: March &, 2019
:. Page: 3oEJ
QEBAih'ilyf/Eal'
Document Number. F-CAR41.I3401--rev.03
lssuitng Authority: Pam HuntersvilteQuality
Office
Field Data Sheet
Clientt�uutd EALrev
Location: nm9RnVNL Frojert#:SLS
It? LFf1cro:*IwAPM^
01,1P.L0
Name and Affiliation (Samplee(s):
R ^`Q PA I P
Field Data Sheet Review:
Name and Affiliation (Inspector):
PI /A
id) 9-41 a3 fJ1`j
Weil Information
Date: By:
y �V111
l o 17r5
Well ID: LLS _ 61-r6v"- 2
Well Locked: ( YES N 4Wi + I=mmt )
Well Diameter:
Construction: (PUVCLSteelStalrdess Steel)
Total Well Depth:
it Multi Factor*; (*(Radius/i2)2 x3.14 z 7 8]
Static Water Level:
f: Casing Volume: gallons
Height of; Water Column._""`
ft Cal. 3 Volumes: gallons
Pump Intake: e_.— ft
Purge Information
Date Purged: -.7L_ -
Start: FInfsh"=Purge Rate:
Purging Method:
Total Volume Purged: ®' (gallons/irds/L)
f
SampltngIn ormatron
Date Collected: �f to / 23
Time Collected: a 41 ^ am m)
Sampling, Equipment Used:
nstrumentlD:5ZD56EQ/7Pwbagy
Bottle Type
Preservation Analysis Required
�At2loaol',aj K_
Field Measurements/Observations
Sample Temp CC): %- I Time:
91I ;Turbidity (ntu): 3. Time: 0915
piss Oxy'(mg/L): �• Time:
Fe 2+ mg/L: ' (, Time: J_
Specific Cond. (uS): b Time:
-
Res. Cl (mg/LV(µg/I.): — 'Time:
SamplepFl(s.u,): b• � _Time:
Odar: C.r+a�._.' Tlme:. oats
RePox(mV)c 146A�_Tiilae:
Appearance: 41.Llouly Time: �-
ReDox (EH value):YSI ProPlus +2OOmV
Other: — Time:
General/Weather Observations: P S
+. 35.2 o 5 u 3 —,; 7 614 7417
sun- cloudy/rainy) Temzp. 50 Cr) Wind 0-5 (mph)
apler Signature: Rr t e _Y 94 Date: l0 / 18171 l
hilinatinn Tact
Time
Purged
Temp.
(C)
CC)
Diss Oxy.
(rng/I.)
Spec'
Cond.
(US)
pH (s.u.)
ReDox
(mV),
Turbidity
(nut)
Volume
removed
(gallons/m1s/
L
Water
level (ff)
Other
t

//, aCes}nrfyfical"
tier P-GAR-$]A-oo1-rev.in Issuing Aµthonl
d Data Sheet
Parch,&, 20*
� of
kuntersvilte Quality
Name and Affiliation (Samplerw-zy-- �c-/i�
Field Data Sheet Review.
Name axed Affiliation (Inspector); xi///�
t d aw l .:i3 1 7 b
We1I Information
Date:
1p / 7 5/23 r H�
Well SD:
Well Locked: -
Well Diameten
Construction:
Total Well Depth:.- tt
Multi Factor':
Static Water Level: ft
Casingvolume: --- pilons
Height of Water Column: ft
Cal, 3 VoIumes:
Pump Intake:
Purge Information
Date Purged: Start:
lbtisIu;
Purge Rate:
Purging Method:
Total Volume
Purged: (g ons/utls/
Sampling Information
Date Collected, 10 [41 Z 3
Time Collected::
a931 p1
Sampling Equipment Used;yr / u
Instrument ID:
Bottle Type
Preservation
Analysis Required
Field Measurements/Observation
Sample Temp (°C): Turbidity (ntu), Z S Time; 0 9 3 0
Diss Oxy (mg/L.): 6,1 Timer 0930 Fe 2+ mg/L: 2.O Time; 0Y 3, 0
Specific Cond. (uS)t S-j , 5 Time: 0930 Res. CI (ing/L)f(ug/) Pune:
Sample pl t (au ): �.�i Time: 0230 Odor: /t%u v e O
mV : I ZS o Time:
ReDox
( } i"uxte: 0 Q 30 Appearance: �l �, 'I"une: c'i 232
ReDox (FH value):ySI ProPlus +200mV 3 zs- O Other: mtie:
General/Weather Observations: --2s,IrM*11 �
su cloudy/rainy) Temp.ppv (`F) 4VnciG (mph)
Sampler Signatur - / Date: to i� /?3
Time
Purged'
Temp.
(°C)
Diss Oxy:
(mg/L)
Spec.
(US)
PH {s.u.)
ReDox
(mV)
Turty
{ntu)
o unae
removed
(gallons/mis/
L
Water
level (ft)
Other

pocutueat Nam: Field data Sheet
Date Issuedc March 8, 2G]9
<1Cf3A+kry/yllCRi-
Page: 1 of
Document Numlrera P-OAR-P).1S-GGt-r@v.Q.9
Imuhap Authority: Pace;Huntersville Quality
Office
1 ' - Field Data Sheet Liz
Client: �i ke 1 n n Location: e C V4LProject#: LLS CCP ��tMs{ ScrnQly�
i
Name and Affiliation (Sampler(s); ? a
Field Data Sheet Review:
Name and Affiliation (Inspector): N
Dale. fcy zy / 23 BY: 1- 2
Y
Well Information
�0l2S12 @2 PA
Well ID: LL S _ R) --
W it r ked A4-k / +' h e;.aant )
Well Diameter:
Con a�tiorn jPVt /G«a..> t�tainiess Steel)
Total Well Depth: fk
Multi Factor* '— [•(Radius/12)2x-3.l4x 7.48]
Static Water Level; � ft
Casing Volume: _ gallons
Height of Water Column- ft
Cal. 3 Volumes: `— gallons
Pump intake: ` ft
Puree Information
_
Date Purged: — / J_ Start:
_::�_ Finish: Purge Rate:
Purging Method:
Total Volume Purged: (gallons/mis/L)
Sampling information
Date Collected: ! O
Time Collected:. Ll am plu)
Sampling Equipment Used: (9 czA j
Instrument ID; NYST �i v S 3L1 M 1romPU 9 3 q
Bottle Type
Preservation Analysis Required
Field Measurement' Observations
Sample Tem -i — Time: '
Turbldity,(mu); 'lime:
Diss Oxy;(mg/L): ` Time:
L:
Specific Cond. (uS):, Time:
(vg/ Time:
Sample pH (s.u.): ^ mie:
Odor:_ Time:
ReDox (m Time:
Appearance: Time:
Re x (EH value):YSI ProPlus +200mV
Other: — Time:
General/WeatherObservations: (
L,_CQ CA
( nn cloudy/rainy) Temp. S l (OF) wind(mph)
Sampler Signature:
Date:_
Stabilization
Test
MINES
®®®®

Document ty*aitty: Field data Sheet
Date is�sued�March 8, 2R79
aceAnalyfical"
Page: I off,
Document Number: P CA12-FL.t5-801-rev.0.3
Issuing Authonty; PaceHuntersville Quality
t
Office
Field Data Sheet
♦. hd to D- t+A.*.e _i Tn ntinm Ma.i ff hnre.Ne PrniarP$- /t L Ns LG A¢ra. `die nPl: n90C%2023
Name and Affiliation (Sampler(s): R IAB POLL Q Pleld Data Sheet Review:
Name and Affiliation (Inspector): K /A Date: 1 c/2Y 1'2i3
By:
Well Information o / `ZJ�'' 1 ?3
Well ID: G LS _ F 6 Well Locked: (Y'Ecl nrn f'M Wmjqunt )
Well Diameter: Construction: (PVC'f11ee176taixlessSteel)
Total Well Depth; ft Multi Factor*: _---__�(Ra0w5j( 2)2x3.ta z 2,481
Static Water Level ft Casing Volume: gallons
Height of Water Column: = ft
CaL 3 Volumes: gallons
Pump intake: It
Purge Information
Date Purged;— Start,
' Finish, Purge Rate: t
Purging Method
Total Volume Purged: r--- (gallons/mis/L)
Sampling Information
Date Collected: 19 / l� f
Time Collected: 1100 _ Opm)
Sampling, Equipment Used: !. /,Ato
lnstrumenfID: 1111
Bottle Type
PreservationAnalysis Required
p.gce Lompl'aAte K,'r
Field Measurements/Observations
Sample Temp (°C}: Time: '—_
'Turbidity (ntu): \ Time: `—
Diss Oxy (mg/L): ^ Time:
�— Fe 2-r mg/L: Time: ^
Specific Cond. (uS): Time:
Res. CI (mg/L)/(ltg/T )� 'lime:
Sample pH (s.u.): Timet
" Odor: Time:=
ReDox (mV): Time:
.._ Appearance: Time:
ReDox (PH value)XS1 ProPlus +200utV
Other: -- Time: �—
tT..«..o..�nel.... N..... nr ...........u..a... �- •1 A
._ ._ M_•n.rr 1 Iinu... ft •_._.L'A^
(sunny/cloudy/rainy) Temp. 59 (
mpler Signature: 1 Ryan 6 Date: L9 1(912. }J
abilization Test
Time
Purged;
Temp.
Diss Oxy.
(lug/I
Spec.
Cond.',.
(US)
pH (s.u.)
ReDox
(mv)
Turbidity
(ntu) ?
Volume
removed
(gallons/mis/
Water
le'

AIAWical-
1?�wn
t 7 75 T-
7 awi;wdl
office
T t4�— —Z-'-� 1611 r r
Mame and Affiliation (Sarnjleq
Add Data SheetXeview:
well hiforination
y"
Date -D D
well,
Well Ldck�e&
Well DIameten
Construction., zgAtoo/Stalrdess Steel)
Mufli.Factor*!�- - �13' V(I4diu55/1-2)2,x344-x-7A8l
Static Water Level: R�,,w Pjho it
Casing Volume gallons
Height of Water Cojwrm-,-=:�:-f t
CA. 5Volumm galfon$
Pump lntaye---� � —'-ft
Puree YEfomrafion
Date, Ptirged.—I Q—/ 19 /!A— start J3 Fintikj3R) FingeRate.L,10h�411
Purging Method--RkA�
Total volumepurged: (gauons/gipL)
Sam T�SingInfotnaaCion
Date Collected:-LdL/15�/ I-
Time Collected 13 3 -5-
ing Equipment Used: ---JnstrumentID-.
Bottle Type Preservation Analysis RequireA.
D'I'YNe' C"NAM h'4
FWdMe,asurements/Observations
Sample T,ernp(°C)-- ILLt,i -__Tjme, )335 Turbidity hidity (Iltu')�' Time,, 133
Diss Oxy (mg/L.), -5-7- Thne: 133 5' Fe 2+ m
9/L:
Specific rood. (us): Time, 133s-
Res. CI (mg/LY(gg/L)-
Sample pH (siu.): S. S' Time-,. 133 S- Time: 13jr
ReVox (mV); 'i I'l Time: 133S Appearance: Oe-, rlme:-ALS?-�
ReDox(EH value);YSIPr,oPlus.+2OOmV TI,1 Other,
Temp.0-��- (M� Wind 1� (Mph)
Time
Temp.
Diss OXY.
Spec.
Cond.
pH (s. u.)
ReDox
Turbidity
voluiFe—
removed
Water
Other
PuTged
�C)
(mg/L).
(US)
(mV)
(ntu)
allots F-
Z?
lev el (ft)
Q
zz'H
S� 3
'43.t
S.0
4,'�
?-qz0
-Z�-3�
-STT—
--V�
5-1 -S—.
,q�
�5. 3
zli, -�-
5.3
-FI, S'
'2-0
5S C)Z)

-
e�ttafyficat `
'�7bg4mpikN'en�e pield *MVO ..
.. • , D�Ce'ISSpge6`K aYtlt.Bc2ik3 - r `
pa e: 14,
Dpcumept Nutti4¢r F-CAit EIS3l(4�-rdw,QS '.
IsSjdiiig-Aitthortiy Paee�Iimteek3iit�4u`A�ity=
o" .
15 1A ,�Fh�6
flok
,airipler Signature:`
italrilixatinn Tent
(s6ay/c1oudy/rainy) Temp. 6 N (-F) Wind_a_:S (mph).
_Date. I o/I $ %23
spec. o ume
Time
Temp:
�C
Diss Qxy.
p
Cond.;
pH (s.u,}
ReDox
Turbidity'
removed
FVater
Other
Purged
g
{ �
(mg/L�
{�
(mU)
(ntit)
(gatto�S/�/
ievc?7 {fi}
oiM-7
i7.
. `
0vc?
53,b
0
O.1
moo
\.75j 1i.0 C/,- I.J_T t.. i. / is S,`I. Q.'Z 750c
.6q

Document [Jame: Fuld data Sheet
' Date lssued:'Marc�1, 2t}14
BAtk4/yf7Ca1
Page: ok_
Document Number: F-CAI;-P[.D-001-rev.03
wing Authority: Pace Huntersville Quality
Office
Field Data Sheek.
Client: �) L(� E E— A E �U Location:
d
PWC,
ct #: C L ; ._ P if r` M a } 4.1: S(t
Name and Affiliation (Sampler(s); �l_ L AYE / P h ct
Field Data Sheet Review:
Name and Affiliation (Inspector):
1()1)-N t 23
W01 Information 'i W l C3/ 69/z3
Date: By,
Well IDe 17
We Locked: ( YES
/ NO / Flushmount) ,
Diameter:
W
Canstr tion: (PVC/Steel/Stainless Steel)
tal Well th:, —it
Multi Facto • [ (Aadius/12)2x3,Idx 7.481
Static Water Level: it
Casing Volume gallons
Height of Water Column: ft
Cal, 3 Volumes: alIons
Pump Intake: t
Purge Information'
Date urg ,— /�f' _ Start:
—
Finish: Purge Rate:
Purging Method:_
: Fo me Purged: (gallons/mis/L)
Sampling Information
Date Collected:_JQ/ Cf/ Z 3
I
Time Collected;
Sampling Equipment Used: i lG
9 Instrument
Bottle Type
Preservation Analysis Required
Fie FMeasurements Observations
Sample;Fe xt# —iuc): — — Time>_____Turbidity(ntu):
Time;
Diss Oxy (mg/L): Tune: _
Fe 2+ mg/Li Time:
Specific Cond. (uS): Time:
- ResL :—Time:—
Sample pH (s.u.): Time:
fin —.
Repox (mV): Time:
- Appearance: T.
Repox (EH value):YSI ProPlus +2ptlmV
Other: Time: _
General/Weather Observations: P—I,'§°u
to-- �� r
'\ r rl
i . __._ / C -
Sampler
Time
Purged
u 1p.
(C)-
Diss Oxy.
jL)
Spec.
Cond;
(un)
pH (s.u.)
ReDox
(mV)
Turbidity
(ntu)
Volunie
removed
(gallons/cols/
L
Water
level (ff}
Othe
r

Document Name: NUild data Sheet
Date issued: Mamh 8, 2U19
Bfilk94fta(•
Page. 1of
Dmument Number: F-CAg-FI.0-001-rev.03
lssuft Authority: untersOl(e Quality
t
Office
Field Data Shoot
Client:
JF A e£f [-V
Location: A&2znr L (: PY rm e c cz-A
Name and Affiliation (Sampler(s){ S p I(e) AL (M/p e
Field Data Sheet Review:
Name and Affiliation (Inspector):
i ()I aiA I- 3
Date:13y:���
Well' Information
Well 113: C C P M Lf l l
Well Locked: k196
/ NO /'Flushmount )
Well Diameter: 7',
Construction: (,0/Steel/Stainless Steel)
Total Well Depth;., ft
Multi Factor*: 03 l*(1;adius/12)2x 114a 7,481
Static Water Level:;( t._G2—£t
Casing Volume: �1x�i'i gallons
Height of Water Column:_oj d —ft
CaL 3 Volumes; gallons
Pump Intake. � �� ft
Purge Information
��.'
.Date Purged:_{ U;/_n / 21
Start : % ti Finish: Purge Rate:
Purging Method:_ p 1-1 e t +
� (f (. Total Volume Purged: (gallons/mis/L)
Sampling Information
ate Collected
Time eted:' (am/pm)
Sampling Equipment Used: Instrument ID:
Bottle Type Preservation Analysis Required
Field Measurements/Observations
Sample ° Time,_ ____,_Turbidity (ntu): Time:
DissOxy'(mg/L): Time:' ' _Fe—T+—Rrgp,Tme:
Specific Cond. (uS)a Time: S. CL (mg/L)/ 1 L}: Ti1ne:
Sample pi-i (s.u.); Time: Odor: Time:
ReDox (mV): Time. Appearance: "T`
ReDox (EH value):YSI ProPlus +200mV Other: Time:
General/Weather Observations: Ci_s (1 Wry K U` V �41 EZ
LUG_ }fir 1� ff /U',F q psj {I(E 1 ((&y/cloudy/rainy) Temp (°F} Windom (mph)
Sampler Signature: 49y/'` &,da / Date: (Cj l t
Stabilization Test
Spec.. Volume
e
Purge
Temp.
Diss Oxy.
(mg/L)
Cond.
(uS)
pH (s.u:}
ReDox
(mV)
Turbidity
(ntu)
removed
(gallons/mis/
L
Water
level (ft)
Other

- Date Issued: march d. 2019
Document Nanm. Field data Sheet I'a e: 1 of 1
7 tTCPAtktilyJlCdl� Issuing Authority,: I'ace;Huntersville Qual)ty
Document Number; f:-i;AR-17l.H+001-rey.41 Office
'� Field Data Sheet
Client; If..C'LR �(x.er'S, Locstion:,�1t7C1rzs�JoC9:"- Project#: CLS CCP GFP-etv�-y�- Gr"�
Name and Affiliation (Sampler(s); Field Data Sheet Review:
Name and Affiliation (inspectar): /Of 1Ct `-IM 10-N �t
Date: By:
Well Information 19 N- /!3
Well ID: C GPT w - a Well Locked:'LpS / NO / Flushmount )
Well Diameter, Construction: ('t:JSteel/Stainless Steel)
Total Well Depth: H S ' Q0 - ft Multl Factor*;,. g dG 3 KHadius/12)2x3.14x 2.nsj
Static Wafer Level: �C(t2v- P�ft�K5casing
Volume:
gallons
Height of Water Column:
ft Cal. 3 Volumes:
gallons
Pump Intake:
£t
Purge Information
Date Purged: '--' / J�
_ Start:_ Finish:
Purge Rate:
Purging Method-
Total Volume Purged:
(gallons/mis/L)
Sampling-Informafion
_
Date
Time Collected:
(am/pm)
Sampling Equipment Used±
Instrument ID:
Type
Preservation
Analysis Required
`Bottle
Field Measureuxents/Observations
Sam le Temp (°C): '
Thne: Turbidlty (ntu):
Time:
Diss Oxy'(mg
Time: Fe 2+mg/L:
Time:
Specific Cond. (uS):
Time:
Sample pH (s,u.);
Odor:
ReDox (rhV):
Time: Appearance:
Time:
value):YSI ProPlus +200m-Va Other:
Time:
GeneraVWeathey Observation st
tnjd:f - -
('\ie
ce1( 4tn } _24V Illy
sunn /cloudy/rainy77)
Temp.., � j°I� Wind �t'_(mph)
Sampler Signature:
- Date: 1 C1) iz f
a 3
'Stabilization
Test
watu
E
Time '
Purged
°
(C}
Diss Oxy:
(mg_
Spec
Cond.
{u5
gH {s.u.),
ReDox
'Turbidity
mu
a ume
reproved
(gallons/mils/
L -;
level (ft)
er

,Dooment Nam% Field data 9beet
fate Tssu�dzMarch-Br21114 '.
/
ems*iCal�
[7ocuwenk Numbw: P-CAB-Ia.D-QQi-rev:0.3
Issuing A4thorAtp;�'ace Hunkersvtl%4uaiity,,..
office
Field:Data Sheet p
Gent: I✓V� Evo—yeg Locationp/�OOffsbo�o,(VC Protect#:, CLS CGPLF 12/w ) Sa�kPjinS
Narne and affiliation (Sampler(s): I r-R - i o ce Field Data Sheet Review:
Name and Affiliation (inspector): 1VA Date: too Z"il 0- -- 7-j-nr
l O /2-5/23 BY:
Well Information
Well IDi' GC-F LAW -)i WellLocked: Qgj NO / Flushmount )
Well Diameter: Construction: (I/Steel/stainless Steel)
TotekiWell Depth: Multi Factor*:63_r,(RadWs/'t2)zxa:iax7.aal
Static Water Level: `1$.k3 ft Casing Volume: 0-0�1 gallons
Height of Water Colurnd:-Q-- -X�ft Cal. 3 Volumes: �% a gallons
Pump lntake: It
_ _
Date Purged; Start ^ Pitlisl� ,Purge Rate,_
Purging Method: Total Volume Purged:",gaTlmtsaulsfL
8am�1tngInfoxmation--�_�_____
Date Collected: Tfm~Cbiieeted (am/pm)
Sampling Equipment Used: Instrument ID --
Bottle Type Preservation Analysis Required
Field Measurements/Observationa
Sample Te °C): _Time; — Turbidity (ntu): Time:
Diss Oxy (mg/L): --' — te: ` � Fe 2+ mg/L: Time:
SpecificCond. (uS): Time; Res. CI (mg/L)/(µg/L): Ti ne:
Sample pH (s.u.); Time: Odor: Time:
ReDox (_ V): Time: Appearange: 7" e:
ReDox (EH value):YSI ProPlus +2QOmv_,,-,- Other: Time:
Date: f o 18 _ )A
Time
Purged
e
(C)>
CC)
' Ox .
(rng/L)
Spec.
Cond.
(
pH (s.u.)
ReDox
(mV)
_
Turbidity
(ntu)
Volume
removed
(gallons/nUs/
L
Water
level (€t)
Other

Semiannual Water Quality Monitoring Report — October 2023 Sampling Event
Rogers Energy Complex— Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
APPENDIX B
LABORATORY REPORT AND
CHAIN -OF -CUSTODY FORMS
L7
synTerra
Science & Engineering Consultants

Facility/Site
Analytical Data Review Checklist - Aqueous
State Location/Sample IDs'-
;;I,ff;,de;Stearn
Station
NC
CCP-LEACHATE, CCP-LEACHATE-34, CCPMW-1D, CCPMW-IS, CCPMW-2D, CCPMW-2S,
CCPMW-3D, CCPMW-4, CCPMW-5, CCPMW-6D, CCPMW-6S, CCPMW-7, CCPMW-10,
CUM-11, CCPSW-1, CCPSW-2, CCPSW-3, CCR-CCPBG-11311, CCR-CCPBG-1D
References:
- ELN/A
❑v 1 ❑
Duke Central Lab
Lab Report ID Sample Date Sample Receipt Date Analysis Complete Date ❑ Groundwater
J23090016 10/18/2023 10/19/2023 11/7/2023 ❑ Surface Water
❑ Other
National Functional Guidelines for Inorganic Superfund Methods Data Review (USEPA 2020)
Guidance on Environmental Data Verification and Data Validation (USEPA 2002)
Radiochemical Data Verification and Validation (MARLAP 2004)
� Sample Receipt and Chain of Custody
I� 1) Do the sample IDs and laboratory analyses recorded on the Chain of Custody match the sample IDs and analyses listed in the laboratory package?
0
[Il
❑
la) Do the dates and times of sampling listed on the Chain of Custody match the laboratory report?
0
❑
❑
❑
❑
0
2) Is the sample temperature upon receipt at the laboratory recorded on the Chain of Custody form less than 6 degrees Celsius? If NO, then:
2a) Was the presence of wet ice noted in the cooler? OR
❑
❑
0
2b) Were the samples collected less than two hours prior to receipt at the lab?
❑�
❑
❑
3) Was the proper sample preservation checked and documented on the Chain of Custody or sample receipt form?
❑�
1 ❑
❑
4) Are there any special notes, exceptions, and/or anomalies listed either on the Chain of Custody or sample receipt form?
❑
0
❑
5) Was the transfer of custody of the samples properly documented and traceable through signature, date, and time by all persons who relinquished and/or received
custody of the samples?
❑
❑ ❑�
®®Batch
6) Do the values for the field parameters listed on the Chain of Custody match the values entered in the lab report?
eAssurance/Quality
7) Was the holding time for preparation and/or analysis met for each parameter?
❑
❑
❑�
7a) Total Alkalinity, Bicarbonate Alkalinity, Carbonate Alkalinity: Analyzed within 14 days of collection
❑�
❑
❑
7b) Bromide, Chloride, Fluoride, and Sulfate (Anions): Analyzed within 28 days of collection
❑
❑
0
7c) Sulfide: Analyzed within 7 days of collection
0
❑
❑
7d) TOC and/or Nitrate -Nitrite: Analyzed within 28 days of collection
❑
❑
0
7e) Total Phosphorus (TP) and Dissolved TP: Analyzed within 28 days of collection
❑
❑
0
7f) Hexavalent Chromium: Analyzed within 24 hours (unpreserved) / 28 days (preserved) of collection
0
❑
❑
7g) Mercury and Dissolved Mercury: Analyzed within 28 days of collection (preserved)
0
❑
❑
7h) Total and Dissolved Metals: Analyzed within 180 days of collection
0
❑
71) TSS and TDS: Analyzed within 7 days of collection
❑
❑
0
7J) Radionuclides: Analyzed within 180 days of collection
❑
❑
❑
❑
O
0
7k) Methane: Analyzed within 14 days (preserved) / 7 days (unpreserved) of collection
71) Oil and Grease: Analyzed within 28 days of collection
❑�
❑
❑
8) Are there any qualifiers assigned by the laboratory and if so, are the qualifier definitions provided?
❑
❑
0
❑
9) Method Blank- Were any parameters detected in the method blank(s)?
9a) If YES, were any target analyses detected in the samples at concentrations less than ten times the method blank concentration?
❑
❑
❑�
❑
10) Laboratory Control Sample - Were any parameters flagged by the lab as being outside the limits of control in the associated laboratory control sample (LCS)?
10a) If YES, was the parameter recovery less than 50 percent or greater than 150 percent?
❑
❑
❑v
10b) Were the some parameters detected in the samples?
❑�
❑
❑
11) Matrix Spike Sample - Did the laboratory provide matrix spike results (MS/MSD)? If so, then:
❑�
❑
❑
11 a) Was the original sample spiked a project sample? If so, then:
❑�
❑
❑
11 b) Were any parameters flagged by the lab as being outside the limits of control in the associated matrix spike sample?

Batch
70!Assurance/Quality
0 ❑ ❑ 12) Laboratory Duplicate Sample - Did the laboratory provide lab duplicate sample results? If so, then:
❑ ❑ 12a) Was the sample analyzed as a laboratory duplicate a project sample? If so, then:
0 ❑ ❑ 12b) Were any parameters flagged by the lab as being outside the limits of control in the laboratory duplicate sample?
0 I ❑ ❑ 13) Field Duplicate Sample - Is the relative percent difference between the parent and field duplicate sample results greater than 35 percent?
0 ❑ ❑ 14) Field/Equipment/Trip Blanks - Were any parameters detected in the associated field, equipment, and/or trip blanks?
0 ❑ ❑ 14a) If yes, were any target analytes detected in the samples at a concentration less than ten times the Field/Equipment/Trip Blank concentration?
❑v
❑ ❑ 15) Were initial and continuing calibration blank information within acceptable criteria per the lab report?
❑�
❑ ❑ 16) Were any reporting limits for diluted, non -detect results greater than the screening criteria?
❑ ❑ 17) Radionuclides: Are quality control sample results provided?
❑ ❑ ❑� 17a) Are any results flagged or qualified?
❑ ❑ ❑° 17b) Are Uncertainty, MDC, Tracer/ and/or Carrier/ provided for each sample?
The questions on this checklist refer to basic review of laboratory analytical reports for completeness and accuracy of data. Any responses requiring follow up action with the analytical lab or field personnel must be
noted in the summary section at the end of this form before the data can be approved for use by technical leads.
Lab Qualifiers:
J-Analyte detected above the MDL, but below the RL; analyte concentration should be considered an estimate.
7
M - MS and/or MSD recovery was outside of the control limits; the associated LCS recovery was acceptable.
R2 - % RPD indeterminate due to low concentration in the parent sample.
U-Analyte was analyzed for, but not detected above the MDL.
Validation Qualifiers:
R- Result is unusable. The sample result is rejected due to serious deficiencies in meeting quality control criteria; the analyte may or may not be present in the sample.
J - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
U-Analyte was analyzed form but not detected above the minimum detectable concentration (MDC) or method detection limit (MDL).
B -Target analyte detected in the method blank an in the sample at a concentration less than 10x the blank concentration.
• CCPMW-3S, CCPMW-8, and CCPTW-2 not sampled due to insufficient volume.
• Mercury MSD % recovery high (MS ok) for CCPMW-10 (M).
• The RPD between CCPMW-IS and the lab duplicate is greater than lab control limits for TDS (112); the sample result is non -detect.
• The RPD between CCPMW-2S and the field duplicate is greater than 35% for Iron (0.272/0.081 mg/L) and TDS (38/55 mg/L).
• Chloride (0.02 mg/L), Nitrate (0.03 mg/L), Nitrate as N (0.01 mg-N/L), Manganese (0.003 mg/L), Cobalt (0.136 ug/L), and Molybdenum (0.202 ug/L) were detected in the Field Blank; Nitrate,
Nitrate as N, Manganese, Cobalt, and Molybdenum were also detected in the samples at concentrations less than 10x the blank concentrations.
• Due to a dilution factor of 200, the Fluoride reporting limit (20 mg/L) is greater than the EPA Primary MCL (4 mg/L) and CCP-Leachate was reported as non -detect.
• Due to a dilution factor of 50, the Fluoride reporting limit (5 mg/L) is greater than the EPA Primary MCL (4 mg/L) and FD-20231018-1 (parent sample: CCP-Leachate) was reported as non -
detect.
Review Determination: ❑ Usable 0 Usable with Required Actions ❑ Unusable
Signatures: Date:
Data Quality Reviewer REB 11/22/2023
Technical Lead SAS 2/6/2024

DUKE
Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number:
J23090016
Project Name:
CLIFFSIDE - GW CCP LANDFILL
Task Code:
LF
Customer Name(s):
Bill Wylie,Bryan Moeller,Dee O Brien,Josh Stowe
Customer Address:
Cliffside Steam Station
573 Duke Power Rd
Mail Code: Clliffside Steam Station
Mooresboro, NC 28024
Lab Contact:
Peggy Kendall Phone: [phone]
Report Authorized By:
ate: 11/7/2023
Pee(Signature)
�� 11
PVndall
Program Comments:
Page 1 of 46
QC Note: CCPMW-10 Hg MSD recovery exceeded the QC limits. The blank, LCS and MS were within the control limits. The
actual % recovery for the Hg MSD was 125.4; due to a significant figure limitation in LIMS, the result reports as 125.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions: Page 2 of 46
Sample ID
Plant/Station
Collection
Date and Time
Collected By
Sample Description
2023021783
CLIFFSIDE
18-Oct-23
10:30AM
BMSEHM
CLS CCPMW-1S
2023021784
CLIFFSIDE
18-Oct-23
10:30AM
BMSEHM
CLS CCPMW-1D
2023021785
CLIFFSIDE
18-Oct-23
11:15 AM
SPW ALM
CLS CCPMW-2S
2023021786
CLIFFSIDE
18-Oct-23
12:25 PM
SPW ALM
CLS CCPMW-2D
2023021788
CLIFFSIDE
18-Oct-23
10:00 AM
SPW ALM
CLS CCPMW-3D
2023021789
CLIFFSIDE
18-Oct-23
10:40 AM
NRA
CLS CCPMW-4
2023021790
CLIFFSIDE
18-Oct-23
2:55 PM
NRA
CLS CCPMW-5
2023021791
CLIFFSIDE
18-Oct-23
1:20 PM
SPW ALM
CLS CCPMW-6S
2023021792
CLIFFSIDE
18-Oct-23
1:30 PM
SPW ALM
CLS CCPMW-6D
2023021793
CLIFFSIDE
18-Oct-23
10:40 AM
RMB
CLS CCPMW-7
2023021795
CLIFFSIDE
18-Oct-23
10:45 AM
MER
CLS CCPMW-10
2023021796
CLIFFSIDE
18-Oct-23
11:15 AM
JJZ
CLS CCPMW-11
2023021798
CLIFFSIDE
18-Oct-23
10:20 AM
JJZ
CLS CCP-Leachate
2023021799
CLIFFSIDE
18-Oct-23
10:30 AM
JJZ
CLS CCP-LEACHATE-34
2023021800
CLIFFSIDE
18-Oct-23
9:30 AM
JJZ
CLS CCPSW-1
2023021801
CLIFFSIDE
18-Oct-23
9:15 AM
RMB
CLS CCPSW-2
2023021802
CLIFFSIDE
18-Oct-23
9:30 AM
BMSEHM
CLS CCPSW-3
2023021803
CLIFFSIDE
18-Oct-23
JJZ
CLS FD-20231018-1
2023021804
CLIFFSIDE
18-Oct-23
11:00 AM
RMB
CLS FB-20231018-1100
2023021805
CLIFFSIDE
18-Oct-23
1:35 PM
BMSEHM
CLS CCR-CCPBG-1D
2023021806
CLIFFSIDE
18-Oct-23
1:40 PM
BMSEHM
CLS CCR-CCPBG-1BR
2023021807
CLIFFSIDE
18-Oct-23
SPW ALM
CLS FD-20231018-2
22 Total Samples

Page 3 of 46
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals❑ Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
❑d Job Summary Report
❑d Sample Identification
❑� Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
❑� Analytical Laboratory QC Report
❑ Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑� Chain of Custody
❑� Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 11/7/2023

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS CCPMW-1S
Collection Date: 10/18/2023 10:30 AM Loc code: CLS CCPMW-lS
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23100317
Chloride
3.9
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
0.12
mg/L
Nitrate as N
0.03
mg-N/L
Sulfate
0.24
mg/L
MERCURY (COLD VAPOR) IN WATER - Q23100389
Mercury (Hg)
0.01 J
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23100325
Barium (Ba)
0.023
mg/L
Boron (B)
0.005 J
mg/L
Calcium (Ca)
0.167
mg/L
Iron (Fe)
0.011
mg/L
Lithium (Li)
0.005 J
mg/L
Magnesium (Mg)
0.664
mg/L
Manganese (Mn)
0.016
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23100331
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.428 J
ug/L
Cobalt (Co)
1.14
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.439 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V)
0.114 U
ug/L
TOTAL DISSOLVED SOLIDS -
023100376
TDS 25 U mg/L
Sample #: 2023021783
Matrix: GW RCRA
Page 4 of 46
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
10/19/2023 07:36
BGN9034
0.1
0.0479
1
EPA 9056A
10/19/2023 07:36
BGN9034
0.1
0.0209
1
EPA 9056A
10/19/2023 07:36
BGN9034
0.023
0.002
1
EPA 9056A
10/19/2023 07:36
BGN9034
0.1
0.0428
1
EPA 9056A
10/19/2023 07:36
BGN9034
0.05
0.01
1
EPA 7470A
10/24/2023 10:49
SNEGLIA
0.005
0.002
1
SW 601OD
10/20/2023 12:18
CELL106
0.05
0.005
1
SW 601OD
10/20/2023 12:18
CELL106
0.05
0.012
1
SW 601OD
10/20/2023 12:18
CELL106
0.01
0.004
1
SW 601OD
10/20/2023 12:18
CELL106
0.005
0.002
1
SW 601OD
10/20/2023 12:18
CELL106
0.02
0.008
1
SW 601OD
10/20/2023 12:18
CELL106
0.005
0.001
1
SW 601OD
10/20/2023 12:18
CELL106
0.005
0.004
1
SW 601OD
10/20/2023 12:18
CELL106
1
0.104
1
SW 6020B
10/20/2023 14:27
MHALL3
1
0.111
1
SW 6020B
10/20/2023 14:27
MHALL3
1
0.249
1
SW 6020E
10/20/2023 14:27
MHALL3
1
0.032
1
SW 6020E
10/20/2023 14:27
MHALL3
1
0.185
1
SW 6020B
10/20/2023 14:27
MHALL3
1
0.077
1
SW 6020E
10/20/2023 14:27
MHALL3
1
0.787
1
SW 6020B
10/20/2023 14:27
MHALL3
1
0.037
1
SW 6020E
10/20/2023 14:27
MHALL3
1
0.18
1
SW 6020E
10/20/2023 14:27
MHALL3
1
0.256
1
SW 6020B
10/20/2023 14:27
MHALL3
1
0.193
1
SW 6020B
10/20/2023 14:27
MHALL3
1
0.035
1
SW 6020E
10/20/2023 14:27
MHALL3
0.2
0.041
1
SW 6020B
10/20/2023 14:27
MHALL3
1
0.114
1
SW 6020E
10/20/2023 14:27
MHALL3
25
25
1
SM2540C
10/23/2023 09:15
SNEGLIA

Certificate of Laboratory Analysis Page 5 of 46
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS CCPMW-1 D Sample #: 2023021784
Collection Date: 10/18/2023 10:30 AM Loc code: CLS CCPMW-1 D Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23100317
Chloride
8.0
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
1.5
mg/L
Nitrate as N
0.33
mg-N/L
Sulfate
1.4
mg/L
MERCURY (COLD VAPOR) IN WATER - Q23100389
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23100325
Barium (Ba)
0.017
mg/L
Boron (B)
0.008 J
mg/L
Calcium (Ca)
2.68
mg/L
Iron (Fe)
0.006 J
mg/L
Lithium (Li)
0.005
mg/L
Magnesium (Mg)
1.43
mg/L
Manganese (Mn)
0.008
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23100331
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.035 J
ug/L
Chromium (Cr)
0.185 U
ug/L
Cobalt (Co)
0.3 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.876 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V)
0.114 U
ug/L
TOTAL DISSOLVED SOLIDS -
023100376
TDS 28.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
10/19/2023 08:35
BGN9034
0.1
0.0479
1
EPA 9056A
10/19/2023 08:35
BGN9034
0.1
0.0209
1
EPA 9056A
10/19/2023 08:35
BGN9034
0.023
0.002
1
EPA 9056A
10/19/2023 08:35
BGN9034
0.1
0.0428
1
EPA 9056A
10/19/2023 08:35
BGN9034
0.05
0.01
1
EPA 7470A
10/24/2023 10:56
SNEGLIA
0.005
0.002
1
SW 601OD
10/20/2023 12:32
CELL106
0.05
0.005
1
SW 601OD
10/20/2023 12:32
CELL106
0.05
0.012
1
SW 601OD
10/20/2023 12:32
CELL106
0.01
0.004
1
SW 601OD
10/20/2023 12:32
CELL106
0.005
0.002
1
SW 601OD
10/20/2023 12:32
CELL106
0.02
0.008
1
SW 601OD
10/20/2023 12:32
CELL106
0.005
0.001
1
SW 601OD
10/20/2023 12:32
CELL106
0.005
0.004
1
SW 601OD
10/20/2023 12:32
CELL106
1
0.104
1
SW 6020B
10/20/2023 13:44
MHALL3
1
0.111
1
SW 6020B
10/20/2023 13:44
MHALL3
1
0.249
1
SW 6020E
10/20/2023 13:44
MHALL3
1
0.032
1
SW 6020E
10/20/2023 13:44
MHALL3
1
0.185
1
SW 6020B
10/20/2023 13:44
MHALL3
1
0.077
1
SW 6020E
10/20/2023 13:44
MHALL3
1
0.787
1
SW 6020B
10/20/2023 13:44
MHALL3
1
0.037
1
SW 6020E
10/20/2023 13:44
MHALL3
1
0.18
1
SW 6020E
10/20/2023 13:44
MHALL3
1
0.256
1
SW 6020B
10/20/2023 13:44
MHALL3
1
0.193
1
SW 6020B
10/20/2023 13:44
MHALL3
1
0.035
1
SW 6020E
10/20/2023 13:44
MHALL3
0.2
0.041
1
SW 6020B
10/20/2023 13:44
MHALL3
1
0.114
1
SW 6020E
10/20/2023 13:44
MHALL3
25
25
1
SM2540C
10/23/2023 09:15
SNEGLIA

Certificate of Laboratory Analysis Page 6 of 46
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS CCPMW-2S Sample #: 2023021785
Collection Date: 10/18/2023 11:15 AM Loc code: CLS CCPMW-2S Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23100317
Chloride
2.9
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
6.4
mg/L
Nitrate as N
1.5
mg-N/L
Sulfate
6.7
mg/L
MERCURY (COLD VAPOR) IN WATER - Q23100389
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23100325
Barium (Ba)
0.033
mg/L
Boron (B)
0.013 J
mg/L
Calcium (Ca)
2.92
mg/L
Iron (Fe)
0.272
mg/L
Lithium (Li)
0.004 J
mg/L
Magnesium (Mg)
1.95
mg/L
Manganese (Mn)
0.040
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23100331
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.116 J
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
1.67
ug/L
Cobalt (Co)
0.657 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.24 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.895 J
ug/L
Selenium (Se)
0.516 J
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V)
0.685 J
ug/L
TOTAL DISSOLVED SOLIDS -
023100376
TDS 38.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
10/19/2023 08:54
BGN9034
0.1
0.0479
1
EPA 9056A
10/19/2023 08:54
BGN9034
0.1
0.0209
1
EPA 9056A
10/19/2023 08:54
BGN9034
0.023
0.002
1
EPA 9056A
10/19/2023 08:54
BGN9034
0.1
0.0428
1
EPA 9056A
10/19/2023 08:54
BGN9034
0.05
0.01
1
EPA 7470A
10/24/2023 10:58
SNEGLIA
0.005
0.002
1
SW 601OD
10/20/2023 12:37
CELL106
0.05
0.005
1
SW 601OD
10/20/2023 12:37
CELL106
0.05
0.012
1
SW 601OD
10/20/2023 12:37
CELL106
0.01
0.004
1
SW 601OD
10/20/2023 12:37
CELL106
0.005
0.002
1
SW 601OD
10/20/2023 12:37
CELL106
0.02
0.008
1
SW 601OD
10/20/2023 12:37
CELL106
0.005
0.001
1
SW 601OD
10/20/2023 12:37
CELL106
0.005
0.004
1
SW 601OD
10/20/2023 12:37
CELL106
1
0.104
1
SW 6020B
10/20/2023 14:36
MHALL3
1
0.111
1
SW 6020B
10/20/2023 14:36
MHALL3
1
0.249
1
SW 6020E
10/20/2023 14:36
MHALL3
1
0.032
1
SW 6020E
10/20/2023 14:36
MHALL3
1
0.185
1
SW 6020B
10/20/2023 14:36
MHALL3
1
0.077
1
SW 6020E
10/20/2023 14:36
MHALL3
1
0.787
1
SW 6020B
10/20/2023 14:36
MHALL3
1
0.037
1
SW 6020E
10/20/2023 14:36
MHALL3
1
0.18
1
SW 6020E
10/20/2023 14:36
MHALL3
1
0.256
1
SW 6020B
10/20/2023 14:36
MHALL3
1
0.193
1
SW 6020B
10/20/2023 14:36
MHALL3
1
0.035
1
SW 6020E
10/20/2023 14:36
MHALL3
0.2
0.041
1
SW 6020B
10/20/2023 14:36
MHALL3
1
0.114
1
SW 6020E
10/20/2023 14:36
MHALL3
25
25
1
SM2540C
10/23/2023 09:16
SNEGLIA

Certificate of Laboratory Analysis Page 7 of 46
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS CCPMW-2D Sample #: 2023021786
Collection Date: 10/18/2023 12:25 PM Loc code: CLS CCPMW-2D Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23100317
Chloride
5.6
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
5.6
mg/L
Nitrate as N
1.3
mg-N/L
Sulfate
4.3
mg/L
MERCURY (COLD VAPOR) IN WATER - Q23100389
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23100325
Barium (Ba)
0.009
mg/L
Boron (B)
0.01 J
mg/L
Calcium (Ca)
15.5
mg/L
Iron (Fe)
0.027
mg/L
Lithium (Li)
0.006
mg/L
Magnesium (Mg)
1.08
mg/L
Manganese (Mn)
0.002 J
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23100331
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.529 J
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.678 J
ug/L
Cobalt (Co)
0.077 U
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.431 J
ug/L
Nickel (Ni)
0.256 U
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V)
3.51
ug/L
TOTAL DISSOLVED SOLIDS -
023100376
TDS 85.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
10/19/2023 09:14
BGN9034
0.1
0.0479
1
EPA 9056A
10/19/2023 09:14
BGN9034
0.1
0.0209
1
EPA 9056A
10/19/2023 09:14
BGN9034
0.023
0.002
1
EPA 9056A
10/19/2023 09:14
BGN9034
0.1
0.0428
1
EPA 9056A
10/19/2023 09:14
BGN9034
0.05
0.01
1
EPA 7470A
10/24/2023 11:00
SNEGLIA
0.005
0.002
1
SW 601OD
10/20/2023 12:42
CELL106
0.05
0.005
1
SW 601OD
10/20/2023 12:42
CELL106
0.05
0.012
1
SW 601OD
10/20/2023 12:42
CELL106
0.01
0.004
1
SW 601OD
10/20/2023 12:42
CELL106
0.005
0.002
1
SW 601OD
10/20/2023 12:42
CELL106
0.02
0.008
1
SW 601OD
10/20/2023 12:42
CELL106
0.005
0.001
1
SW 601OD
10/20/2023 12:42
CELL106
0.005
0.004
1
SW 601OD
10/20/2023 12:42
CELL106
1
0.104
1
SW 6020B
10/20/2023 14:44
MHALL3
1
0.111
1
SW 6020B
10/20/2023 14:44
MHALL3
1
0.249
1
SW 6020E
10/20/2023 14:44
MHALL3
1
0.032
1
SW 6020E
10/20/2023 14:44
MHALL3
1
0.185
1
SW 6020B
10/20/2023 14:44
MHALL3
1
0.077
1
SW 6020E
10/20/2023 14:44
MHALL3
1
0.787
1
SW 6020B
10/20/2023 14:44
MHALL3
1
0.037
1
SW 6020E
10/20/2023 14:44
MHALL3
1
0.18
1
SW 6020E
10/20/2023 14:44
MHALL3
1
0.256
1
SW 6020B
10/20/2023 14:44
MHALL3
1
0.193
1
SW 6020B
10/20/2023 14:44
MHALL3
1
0.035
1
SW 6020E
10/20/2023 14:44
MHALL3
0.2
0.041
1
SW 6020B
10/20/2023 14:44
MHALL3
1
0.114
1
SW 6020E
10/20/2023 14:44
MHALL3
25
25
1
SM2540C
10/23/2023 09:16
SNEGLIA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS CCPMW-3D
Collection Date: 10/18/2023 10:00 AM Loc code: CLS CCPMW-3D
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23100317
Chloride
9.5
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
5.4
mg/L
Nitrate as N
1.2
mg-N/L
Sulfate
16
mg/L
MERCURY (COLD VAPOR) IN WATER - Q23100389
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23100325
Barium (Ba)
0.034
mg/L
Boron (B)
0.04 J
mg/L
Calcium (Ca)
9.73
mg/L
Iron (Fe)
0.004 U
mg/L
Lithium (Li)
0.002 J
mg/L
Magnesium (Mg)
2.58
mg/L
Manganese (Mn)
0.009
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23100331
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
1.08
ug/L
Cobalt (Co)
0.158 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.256 U
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V)
0.121 J
ug/L
TOTAL DISSOLVED SOLIDS -
023100376
TDS 72.0 mg/L
Sample #: 2023021788
Matrix: GW RCRA
Page 8 of 46
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
10/19/2023 10:13
BGN9034
0.1
0.0479
1
EPA 9056A
10/19/2023 10:13
BGN9034
0.1
0.0209
1
EPA 9056A
10/19/2023 10:13
BGN9034
0.023
0.002
1
EPA 9056A
10/19/2023 10:13
BGN9034
0.5
0.0428
5
EPA 9056A
10/19/2023 10:13
BGN9034
0.05
0.01
1
EPA 7470A
10/24/2023 11:02
SNEGLIA
0.005
0.002
1
SW 601OD
10/20/2023 12:47
CELL106
0.05
0.005
1
SW 601OD
10/20/2023 12:47
CELL106
0.05
0.012
1
SW 601OD
10/20/2023 12:47
CELL106
0.01
0.004
1
SW 601OD
10/20/2023 12:47
CELL106
0.005
0.002
1
SW 601OD
10/20/2023 12:47
CELL106
0.02
0.008
1
SW 601OD
10/20/2023 12:47
CELL106
0.005
0.001
1
SW 601OD
10/20/2023 12:47
CELL106
0.005
0.004
1
SW 601OD
10/20/2023 12:47
CELL106
1
0.104
1
SW 6020B
10/20/2023 14:52
MHALL3
1
0.111
1
SW 6020B
10/20/2023 14:52
MHALL3
1
0.249
1
SW 6020E
10/20/2023 14:52
MHALL3
1
0.032
1
SW 6020E
10/20/2023 14:52
MHALL3
1
0.185
1
SW 6020B
10/20/2023 14:52
MHALL3
1
0.077
1
SW 6020E
10/20/2023 14:52
MHALL3
1
0.787
1
SW 6020B
10/20/2023 14:52
MHALL3
1
0.037
1
SW 6020E
10/20/2023 14:52
MHALL3
1
0.18
1
SW 6020E
10/20/2023 14:52
MHALL3
1
0.256
1
SW 6020B
10/20/2023 14:52
MHALL3
1
0.193
1
SW 6020B
10/20/2023 14:52
MHALL3
1
0.035
1
SW 6020E
10/20/2023 14:52
MHALL3
0.2
0.041
1
SW 6020B
10/20/2023 14:52
MHALL3
1
0.114
1
SW 6020E
10/20/2023 14:52
MHALL3
25
25
1
SM2540C
10/23/2023 09:16
SNEGLIA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS CCPMW-4
Collection Date: 10/18/2023 10:40 AM Loc code: CLS CCPMW-4
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23100317
Chloride
1.7
mg/L
Fluoride
0.17
mg/L
Nitrate
0.05 J
mg/L
Nitrate as N
0.01 J
mg-N/L
Sulfate
15
mg/L
MERCURY (COLD VAPOR) IN WATER - Q23100389
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23100325
Barium (Ba)
0.036
mg/L
Boron (B)
0.007 J
mg/L
Calcium (Ca)
23.2
mg/L
Iron (Fe)
0.084
mg/L
Lithium (Li)
0.008
mg/L
Magnesium (Mg)
1.02
mg/L
Manganese (Mn)
0.023
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23100331
Antimony (Sb)
0.179 J
ug/L
Arsenic (As)
0.72 J
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.208 J
ug/L
Cobalt (Co)
0.077 U
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
11.3
ug/L
Nickel (Ni)
0.256 U
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V)
0.13 J
ug/L
TOTAL DISSOLVED SOLIDS -
023100376
TDS 114 mg/L
Sample #: 2023021789
Matrix: GW RCRA
Page 9 of 46
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
10/19/2023 10:32
BGN9034
0.1
0.0479
1
EPA 9056A
10/19/2023 10:32
BGN9034
0.1
0.0209
1
EPA 9056A
10/19/2023 10:32
BGN9034
0.023
0.002
1
EPA 9056A
10/19/2023 10:32
BGN9034
0.5
0.0428
5
EPA 9056A
10/19/2023 10:32
BGN9034
0.05
0.01
1
EPA 7470A
10/24/2023 11:05
SNEGLIA
0.005
0.002
1
SW 601OD
10/20/2023 12:51
CELL106
0.05
0.005
1
SW 601OD
10/20/2023 12:51
CELL106
0.05
0.012
1
SW 601OD
10/20/2023 12:51
CELL106
0.01
0.004
1
SW 601OD
10/20/2023 12:51
CELL106
0.005
0.002
1
SW 601OD
10/20/2023 12:51
CELL106
0.02
0.008
1
SW 601OD
10/20/2023 12:51
CELL106
0.005
0.001
1
SW 601OD
10/20/2023 12:51
CELL106
0.005
0.004
1
SW 601OD
10/20/2023 12:51
CELL106
1
0.104
1
SW 6020B
10/20/2023 15:01
MHALL3
1
0.111
1
SW 6020B
10/20/2023 15:01
MHALL3
1
0.249
1
SW 6020E
10/20/2023 15:01
MHALL3
1
0.032
1
SW 6020E
10/20/2023 15:01
MHALL3
1
0.185
1
SW 6020B
10/20/2023 15:01
MHALL3
1
0.077
1
SW 6020E
10/20/2023 15:01
MHALL3
1
0.787
1
SW 6020B
10/20/2023 15:01
MHALL3
1
0.037
1
SW 6020E
10/20/2023 15:01
MHALL3
1
0.18
1
SW 6020E
10/20/2023 15:01
MHALL3
1
0.256
1
SW 6020B
10/20/2023 15:01
MHALL3
1
0.193
1
SW 6020B
10/20/2023 15:01
MHALL3
1
0.035
1
SW 6020E
10/20/2023 15:01
MHALL3
0.2
0.041
1
SW 6020B
10/20/2023 15:01
MHALL3
1
0.114
1
SW 6020E
10/20/2023 15:01
MHALL3
25
25
1
SM2540C
10/23/2023 09:16
SNEGLIA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS CCPMW-5
Collection Date: 10/18/2023 02:55 PM Loc code: CLS CCPMW-5
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23100317
Chloride
4.8
mg/L
Fluoride
0.1 J
mg/L
Nitrate
4.0
mg/L
Nitrate as N
0.91
mg-N/L
Sulfate
17
mg/L
MERCURY (COLD VAPOR) IN WATER - Q23100389
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23100325
Barium (Ba)
0.004 J
mg/L
Boron (B)
0.023 J
mg/L
Calcium (Ca)
26.3
mg/L
Iron (Fe)
0.166
mg/L
Lithium (Li)
0.003 J
mg/L
Magnesium (Mg)
0.289
mg/L
Manganese (Mn)
0.010
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23100331
Antimony (Sb)
0.491 J
ug/L
Arsenic (As)
3.23
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
4.58
ug/L
Cobalt (Co)
0.117 J
ug/L
Copper (Cu)
1.39
ug/L
Lead (Pb)
0.245 J
ug/L
Molybdenum (Mo)
1.51
ug/L
Nickel (Ni)
0.75 J
ug/L
Selenium (Se)
0.198 J
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V)
11.6
ug/L
TOTAL DISSOLVED SOLIDS -
023100376
TDS 132 mg/L
Sample #: 2023021790
Matrix: GW RCRA
Page 10 of 46
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
10/19/2023 10:52
BGN9034
0.1
0.0479
1
EPA 9056A
10/19/2023 10:52
BGN9034
0.1
0.0209
1
EPA 9056A
10/19/2023 10:52
BGN9034
0.023
0.002
1
EPA 9056A
10/19/2023 10:52
BGN9034
0.5
0.0428
5
EPA 9056A
10/19/2023 10:52
BGN9034
0.05
0.01
1
EPA 7470A
10/24/2023 11:07
SNEGLIA
0.005
0.002
1
SW 601OD
10/20/2023 12:56
CELL106
0.05
0.005
1
SW 601OD
10/20/2023 12:56
CELL106
0.05
0.012
1
SW 601OD
10/20/2023 12:56
CELL106
0.01
0.004
1
SW 601OD
10/20/2023 12:56
CELL106
0.005
0.002
1
SW 601OD
10/20/2023 12:56
CELL106
0.02
0.008
1
SW 601OD
10/20/2023 12:56
CELL106
0.005
0.001
1
SW 601OD
10/20/2023 12:56
CELL106
0.005
0.004
1
SW 601OD
10/20/2023 12:56
CELL106
1
0.104
1
SW 6020B
10/20/2023 15:09
MHALL3
1
0.111
1
SW 6020B
10/20/2023 15:09
MHALL3
1
0.249
1
SW 6020E
10/20/2023 15:09
MHALL3
1
0.032
1
SW 6020E
10/20/2023 15:09
MHALL3
1
0.185
1
SW 6020B
10/20/2023 15:09
MHALL3
1
0.077
1
SW 6020E
10/20/2023 15:09
MHALL3
1
0.787
1
SW 6020B
10/20/2023 15:09
MHALL3
1
0.037
1
SW 6020E
10/20/2023 15:09
MHALL3
1
0.18
1
SW 6020E
10/20/2023 15:09
MHALL3
1
0.256
1
SW 6020B
10/20/2023 15:09
MHALL3
1
0.193
1
SW 6020B
10/20/2023 15:09
MHALL3
1
0.035
1
SW 6020E
10/20/2023 15:09
MHALL3
0.2
0.041
1
SW 6020B
10/20/2023 15:09
MHALL3
1
0.114
1
SW 6020E
10/20/2023 15:09
MHALL3
25
25
1
SM2540C
10/23/2023 09:16
SNEGLIA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS CCPMW-6S
Collection Date: 10/18/2023 01:20 PM Loc code: CLS CCPMW-6S
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23100317
Chloride
4.8
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
13
mg/L
Nitrate as N
2.9
mg-N/L
Sulfate
1.2
mg/L
MERCURY (COLD VAPOR) IN WATER - Q23100389
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23100325
Barium (Ba)
0.039
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
1.40
mg/L
Iron (Fe)
0.732
mg/L
Lithium (Li)
0.003 J
mg/L
Magnesium (Mg)
1.85
mg/L
Manganese (Mn)
0.038
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23100331
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.257 J
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
2.15
ug/L
Cobalt (Co)
2.20
ug/L
Copper (Cu)
1.12
ug/L
Lead (Pb)
0.557 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
1.87
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.066 J
ug/L
Vanadium (V)
0.993 J
ug/L
TOTAL DISSOLVED SOLIDS -
023100376
TDS 32.0 mg/L
Sample #: 2023021791
Matrix: GW RCRA
Page 11 of 46
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
10/19/2023 09:34
BGN9034
0.1
0.0479
1
EPA 9056A
10/19/2023 09:34
BGN9034
0.5
0.0209
5
EPA 9056A
10/19/2023 09:34
BGN9034
0.115
0.002
5
EPA 9056A
10/19/2023 09:34
BGN9034
0.1
0.0428
1
EPA 9056A
10/19/2023 09:34
BGN9034
0.05
0.01
1
EPA 7470A
10/24/2023 11:09
SNEGLIA
0.005
0.002
1
SW 601OD
10/20/2023 13:01
CELL106
0.05
0.005
1
SW 601OD
10/20/2023 13:01
CELL106
0.05
0.012
1
SW 601OD
10/20/2023 13:01
CELL106
0.01
0.004
1
SW 601OD
10/20/2023 13:01
CELL106
0.005
0.002
1
SW 601OD
10/20/2023 13:01
CELL106
0.02
0.008
1
SW 601OD
10/20/2023 13:01
CELL106
0.005
0.001
1
SW 601OD
10/20/2023 13:01
CELL106
0.005
0.004
1
SW 601OD
10/20/2023 13:01
CELL106
1
0.104
1
SW 6020B
10/20/2023 15:18
MHALL3
1
0.111
1
SW 6020B
10/20/2023 15:18
MHALL3
1
0.249
1
SW 6020E
10/20/2023 15:18
MHALL3
1
0.032
1
SW 6020E
10/20/2023 15:18
MHALL3
1
0.185
1
SW 6020B
10/20/2023 15:18
MHALL3
1
0.077
1
SW 6020E
10/20/2023 15:18
MHALL3
1
0.787
1
SW 6020B
10/20/2023 15:18
MHALL3
1
0.037
1
SW 6020E
10/20/2023 15:18
MHALL3
1
0.18
1
SW 6020E
10/20/2023 15:18
MHALL3
1
0.256
1
SW 6020B
10/20/2023 15:18
MHALL3
1
0.193
1
SW 6020B
10/20/2023 15:18
MHALL3
1
0.035
1
SW 6020E
10/20/2023 15:18
MHALL3
0.2
0.041
1
SW 6020B
10/20/2023 15:18
MHALL3
1
0.114
1
SW 6020E
10/20/2023 15:18
MHALL3
25
25
1
SM2540C
10/23/2023 09:16
SNEGLIA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS CCPMW-6D
Collection Date: 10/18/2023 01:30 PM Loc code: CLS CCPMW-6D
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23100317
Chloride
5.3
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
9.8
mg/L
Nitrate as N
2.2
mg-N/L
Sulfate
0.34
mg/L
MERCURY (COLD VAPOR) IN WATER - Q23100389
Mercury (Hg)
0.01 J
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23100325
Barium (Ba)
0.037
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
1.68
mg/L
Iron (Fe)
0.128
mg/L
Lithium (Li)
0.003 J
mg/L
Magnesium (Mg)
1.67
mg/L
Manganese (Mn)
0.087
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23100331
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.116 J
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
1.39
ug/L
Cobalt (Co)
6.13
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.401 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.693 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.048 J
ug/L
Vanadium (V)
0.217 J
ug/L
TOTAL DISSOLVED SOLIDS -
023100376
TDS 52.0 mg/L
Sample #: 2023021792
Matrix: GW RCRA
Page 12 of 46
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
10/19/2023 09:53
BGN9034
0.1
0.0479
1
EPA 9056A
10/19/2023 09:53
BGN9034
0.5
0.0209
5
EPA 9056A
10/19/2023 09:53
BGN9034
0.115
0.002
5
EPA 9056A
10/19/2023 09:53
BGN9034
0.1
0.0428
1
EPA 9056A
10/19/2023 09:53
BGN9034
0.05
0.01
1
EPA 7470A
10/24/2023 11:11
SNEGLIA
0.005
0.002
1
SW 601OD
10/20/2023 13:05
CELL106
0.05
0.005
1
SW 601OD
10/20/2023 13:05
CELL106
0.05
0.012
1
SW 601OD
10/20/2023 13:05
CELL106
0.01
0.004
1
SW 601OD
10/20/2023 13:05
CELL106
0.005
0.002
1
SW 601OD
10/20/2023 13:05
CELL106
0.02
0.008
1
SW 601OD
10/20/2023 13:05
CELL106
0.005
0.001
1
SW 601OD
10/20/2023 13:05
CELL106
0.005
0.004
1
SW 601OD
10/20/2023 13:05
CELL106
1
0.104
1
SW 6020B
10/20/2023 15:26
MHALL3
1
0.111
1
SW 6020B
10/20/2023 15:26
MHALL3
1
0.249
1
SW 6020E
10/20/2023 15:26
MHALL3
1
0.032
1
SW 6020E
10/20/2023 15:26
MHALL3
1
0.185
1
SW 6020B
10/20/2023 15:26
MHALL3
1
0.077
1
SW 6020E
10/20/2023 15:26
MHALL3
1
0.787
1
SW 6020B
10/20/2023 15:26
MHALL3
1
0.037
1
SW 6020E
10/20/2023 15:26
MHALL3
1
0.18
1
SW 6020E
10/20/2023 15:26
MHALL3
1
0.256
1
SW 6020B
10/20/2023 15:26
MHALL3
1
0.193
1
SW 6020B
10/20/2023 15:26
MHALL3
1
0.035
1
SW 6020E
10/20/2023 15:26
MHALL3
0.2
0.041
1
SW 6020B
10/20/2023 15:26
MHALL3
1
0.114
1
SW 6020E
10/20/2023 15:26
MHALL3
25
25
1
SM2540C
10/23/2023 09:16
SNEGLIA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS CCPMW-7
Collection Date: 10/18/2023 10:40 AM Loc code: CLS CCPMW-7
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23100318
Chloride
11
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
8.6
mg/L
Nitrate as N
1.9
mg-N/L
Sulfate
0.48
mg/L
MERCURY (COLD VAPOR) IN WATER - Q23100389
Mercury (Hg)
0.01 J
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23100325
Barium (Ba)
0.044
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
4.96
mg/L
Iron (Fe)
0.367
mg/L
Lithium (Li)
0.003 J
mg/L
Magnesium (Mg)
2.05
mg/L
Manganese (Mn)
0.029
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23100331
Antimony (Sb)
0.125 J
ug/L
Arsenic (As)
0.228 J
ug/L
Beryllium (Be)
0.8 J
ug/L
Cadmium (Cd)
0.033 J
ug/L
Chromium (Cr)
2.12
ug/L
Cobalt (Co)
0.305 J
ug/L
Copper (Cu)
1.11
ug/L
Lead (Pb)
0.245 J
ug/L
Molybdenum (Mo)
0.223 J
ug/L
Nickel (Ni)
1.38
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V)
0.812 J
ug/L
TOTAL DISSOLVED SOLIDS -
023100376
TDS 56.0 mg/L
Sample #: 2023021793
Matrix: GW RCRA
Page 13 of 46
Method Analysis Date/Time Analyst
0.5
0.0154
5
EPA 9056A
10/19/2023 08:34
BGN9034
0.1
0.0479
1
EPA 9056A
10/19/2023 08:34
BGN9034
0.5
0.0209
5
EPA 9056A
10/19/2023 08:34
BGN9034
0.115
0.002
5
EPA 9056A
10/19/2023 08:34
BGN9034
0.1
0.0428
1
EPA 9056A
10/19/2023 08:34
BGN9034
0.05
0.01
1
EPA 7470A
10/24/2023 11:14
SNEGLIA
0.005
0.002
1
SW 601OD
10/20/2023 13:10
CELL106
0.05
0.005
1
SW 601OD
10/20/2023 13:10
CELL106
0.05
0.012
1
SW 601OD
10/20/2023 13:10
CELL106
0.01
0.004
1
SW 601OD
10/20/2023 13:10
CELL106
0.005
0.002
1
SW 601OD
10/20/2023 13:10
CELL106
0.02
0.008
1
SW 601OD
10/20/2023 13:10
CELL106
0.005
0.001
1
SW 601OD
10/20/2023 13:10
CELL106
0.005
0.004
1
SW 601OD
10/20/2023 13:10
CELL106
1
0.104
1
SW 6020B
10/20/2023 15:34
MHALL3
1
0.111
1
SW 6020B
10/20/2023 15:34
MHALL3
1
0.249
1
SW 6020E
10/20/2023 15:34
MHALL3
1
0.032
1
SW 6020E
10/20/2023 15:34
MHALL3
1
0.185
1
SW 6020B
10/20/2023 15:34
MHALL3
1
0.077
1
SW 6020E
10/20/2023 15:34
MHALL3
1
0.787
1
SW 6020B
10/20/2023 15:34
MHALL3
1
0.037
1
SW 6020E
10/20/2023 15:34
MHALL3
1
0.18
1
SW 6020E
10/20/2023 15:34
MHALL3
1
0.256
1
SW 6020B
10/20/2023 15:34
MHALL3
1
0.193
1
SW 6020B
10/20/2023 15:34
MHALL3
1
0.035
1
SW 6020E
10/20/2023 15:34
MHALL3
0.2
0.041
1
SW 6020B
10/20/2023 15:34
MHALL3
1
0.114
1
SW 6020E
10/20/2023 15:34
MHALL3
25
25
1
SM2540C
10/23/2023 09:17
SNEGLIA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS CCPMW-10
Collection Date: 10/18/2023 10:45 AM Loc code: CLS CCPMW-10
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23100318
Chloride 5.7 mg/L
Fluoride 0.0479 U mg/L
Nitrate 7.6 mg/L
Nitrate as N 1.7 mg-N/L
Sulfate 0.22 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23100389
Mercury (Hg)
0.03 J
ug/L M
TOTAL RECOVERABLE METALS BY ICP - Q23100325
Barium (Ba)
0.052
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
1.81
mg/L
Iron (Fe)
0.167
mg/L
Lithium (Li)
0.002 J
mg/L
Magnesium (Mg)
1.77
mg/L
Manganese (Mn)
0.020
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23100331
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.033 J
ug/L
Chromium (Cr)
1.40
ug/L
Cobalt (Co)
1.22
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.205 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.886 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.047 J
ug/L
Vanadium (V)
0.316 J
ug/L
TOTAL DISSOLVED SOLIDS -
023100376
TDS 26.0 mg/L
Sample #: 2023021795
Matrix: GW RCRA
Page 14 of 46
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
10/19/2023 09:36
BGN9034
0.1
0.0479
1
EPA 9056A
10/19/2023 09:36
BGN9034
0.1
0.0209
1
EPA 9056A
10/19/2023 09:36
BGN9034
0.023
0.002
1
EPA 9056A
10/19/2023 09:36
BGN9034
0.1
0.0428
1
EPA 9056A
10/19/2023 09:36
BGN9034
0.05
0.01
1
EPA 7470A
10/24/2023 11:20
SNEGLIA
0.005
0.002
1
SW 601OD
10/20/2023 13:22
CELL106
0.05
0.005
1
SW 601OD
10/20/2023 13:22
CELL106
0.05
0.012
1
SW 601OD
10/20/2023 13:22
CELL106
0.01
0.004
1
SW 601OD
10/20/2023 13:22
CELL106
0.005
0.002
1
SW 601OD
10/20/2023 13:22
CELL106
0.02
0.008
1
SW 601OD
10/20/2023 13:22
CELL106
0.005
0.001
1
SW 601OD
10/20/2023 13:22
CELL106
0.005
0.004
1
SW 601OD
10/20/2023 13:22
CELL106
1
0.104
1
SW 6020B
10/23/2023 11:03
MHALL3
1
0.111
1
SW 6020B
10/23/2023 11:03
MHALL3
1
0.249
1
SW 6020E
10/23/2023 11:03
MHALL3
1
0.032
1
SW 6020E
10/23/2023 11:03
MHALL3
1
0.185
1
SW 6020B
10/23/2023 11:03
MHALL3
1
0.077
1
SW 6020E
10/23/2023 11:03
MHALL3
1
0.787
1
SW 6020B
10/23/2023 11:03
MHALL3
1
0.037
1
SW 6020E
10/23/2023 11:03
MHALL3
1
0.18
1
SW 6020E
10/23/2023 11:03
MHALL3
1
0.256
1
SW 6020B
10/23/2023 11:03
MHALL3
1
0.193
1
SW 6020B
10/23/2023 11:03
MHALL3
1
0.035
1
SW 6020E
10/23/2023 11:03
MHALL3
0.2
0.041
1
SW 6020B
10/23/2023 11:03
MHALL3
1
0.114
1
SW 6020E
10/23/2023 11:03
MHALL3
25
25
1
SM2540C
10/23/2023 09:17
SNEGLIA

Certificate of Laboratory Analysis Page 15of46
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS CCPMW-11 Sample #: 2023021796
Collection Date: 10/18/2023 11:15 AM Loc code: CLS CCPMW-11 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23100318
Chloride
5.2
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
6.3
mg/L
Nitrate as N
1.4
mg-N/L
Sulfate
0.32
mg/L
MERCURY (COLD VAPOR) IN WATER - Q23100389
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23100325
Barium (Ba)
0.037
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
2.12
mg/L
Iron (Fe)
0.380
mg/L
Lithium (Li)
0.002 J
mg/L
Magnesium (Mg)
1.94
mg/L
Manganese (Mn)
0.025
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23100331
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.12 J
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
4.76
ug/L
Cobalt (Co)
0.456 J
ug/L
Copper (Cu)
1.32
ug/L
Lead (Pb)
0.46 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
5.30
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.049 J
ug/L
Vanadium (V)
0.632 J
ug/L
TOTAL DISSOLVED SOLIDS -
023100376
TDS 29.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
10/19/2023 09:52
BGN9034
0.1
0.0479
1
EPA 9056A
10/19/2023 09:52
BGN9034
0.1
0.0209
1
EPA 9056A
10/19/2023 09:52
BGN9034
0.023
0.002
1
EPA 9056A
10/19/2023 09:52
BGN9034
0.1
0.0428
1
EPA 9056A
10/19/2023 09:52
BGN9034
0.05
0.01
1
EPA 7470A
10/24/2023 11:27
SNEGLIA
0.005
0.002
1
SW 601OD
10/20/2023 13:27
CELL106
0.05
0.005
1
SW 601OD
10/20/2023 13:27
CELL106
0.05
0.012
1
SW 601OD
10/20/2023 13:27
CELL106
0.01
0.004
1
SW 601OD
10/20/2023 13:27
CELL106
0.005
0.002
1
SW 601OD
10/20/2023 13:27
CELL106
0.02
0.008
1
SW 601OD
10/20/2023 13:27
CELL106
0.005
0.001
1
SW 601OD
10/20/2023 13:27
CELL106
0.005
0.004
1
SW 601OD
10/20/2023 13:27
CELL106
1
0.104
1
SW 6020B
10/23/2023 11:11
MHALL3
1
0.111
1
SW 6020B
10/23/2023 11:11
MHALL3
1
0.249
1
SW 6020E
10/23/2023 11:11
MHALL3
1
0.032
1
SW 6020E
10/23/2023 11:11
MHALL3
1
0.185
1
SW 6020B
10/23/2023 11:11
MHALL3
1
0.077
1
SW 6020E
10/23/2023 11:11
MHALL3
1
0.787
1
SW 6020B
10/23/2023 11:11
MHALL3
1
0.037
1
SW 6020E
10/23/2023 11:11
MHALL3
1
0.18
1
SW 6020E
10/23/2023 11:11
MHALL3
1
0.256
1
SW 6020B
10/23/2023 11:11
MHALL3
1
0.193
1
SW 6020B
10/23/2023 11:11
MHALL3
1
0.035
1
SW 6020E
10/23/2023 11:11
MHALL3
0.2
0.041
1
SW 6020B
10/23/2023 11:11
MHALL3
1
0.114
1
SW 6020E
10/23/2023 11:11
MHALL3
25
25
1
SM2540C
10/23/2023 09:17
SNEGLIA

Certificate of Laboratory Analysis Page 16of46
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS CCP-Leachate Sample #: 2023021798
Collection Date: 10/18/2023 10:20 AM Loc code: CLS CCP-Leachate Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23100318
Chloride
15000
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
20
mg/L
Nitrate as N
4.6 J
mg-N/L
Sulfate
860
mg/L
MERCURY (COLD VAPOR) IN WATER - Q23100389
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23100325
Barium (Ba)
0.417
mg/L
Boron (B)
9.19
mg/L
Calcium (Ca)
7660
mg/L
Iron (Fe)
0.550
mg/L
Lithium (Li)
7.55
mg/L
Magnesium (Mg)
58.3
mg/L
Manganese (Mn)
11.1
mg/L
Zinc (Zn)
0.105
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23100331
Antimony (Sb)
0.255 J
ug/L
Arsenic (As)
8.17
ug/L
Beryllium (Be)
0.927 J
ug/L
Cadmium (Cd)
2.09
ug/L
Chromium (Cr)
1.13 J
ug/L
Cobalt (Co)
490
ug/L
Copper (Cu)
32.9
ug/L
Lead (Pb)
133
ug/L
Molybdenum (Mo)
334
ug/L
Nickel (Ni)
103
ug/L
Selenium (Se)
69.5
ug/L
Silver (Ag)
0.147 J
ug/L
Thallium (TI) Low Level
8.77
ug/L
Vanadium (V)
1.11 J
ug/L
TOTAL DISSOLVED SOLIDS -
023100376
TDS 20300 mg/L
Method Analysis Date/Time Analyst
200
0.0154
2000
EPA 9056A
10/19/2023 12:12
BGN9034
20
0.0479
200
EPA 9056A
10/19/2023 12:12
BGN9034
20
0.0209
200
EPA 9056A
10/19/2023 12:12
BGN9034
4.6
0.002
200
EPA 9056A
10/19/2023 12:12
BGN9034
20
0.0428
200
EPA 9056A
10/19/2023 12:12
BGN9034
0.05
0.01
1
EPA 7470A
10/24/2023 11:29
SNEGLIA
0.005
0.002
1
SW 601OD
10/20/2023 13:31
CELL106
0.05
0.005
1
SW 601OD
10/20/2023 13:31
CELL106
5
0.012
100
SW 601OD
10/20/2023 13:31
CELL106
0.01
0.004
1
SW 601OD
10/20/2023 13:31
CELL106
0.005
0.002
1
SW 601OD
10/20/2023 13:31
CELL106
0.02
0.008
1
SW 601OD
10/20/2023 13:31
CELL106
0.005
0.001
1
SW 601OD
10/20/2023 13:31
CELL106
0.005
0.004
1
SW 601OD
10/20/2023 13:31
CELL106
2
0.104
2
SW 6020B
10/24/2023 12:49
MHALL3
2
0.111
2
SW 6020B
10/24/2023 12:49
MHALL3
2
0.249
2
SW 6020E
10/24/2023 12:49
MHALL3
2
0.032
2
SW 6020E
10/24/2023 12:49
MHALL3
2
0.185
2
SW 6020B
10/24/2023 12:49
MHALL3
2
0.077
2
SW 6020E
10/24/2023 12:49
MHALL3
2
0.787
2
SW 6020B
10/24/2023 12:49
MHALL3
2
0.037
2
SW 6020E
10/24/2023 12:49
MHALL3
2
0.18
2
SW 6020E
10/24/2023 12:49
MHALL3
2
0.256
2
SW 6020B
10/24/2023 12:49
MHALL3
2
0.193
2
SW 6020B
10/24/2023 12:49
MHALL3
2
0.035
2
SW 6020E
10/24/2023 12:49
MHALL3
0.4
0.041
2
SW 6020B
10/24/2023 12:49
MHALL3
2
0.114
2
SW 6020E
10/24/2023 12:49
MHALL3
500
25
1
SM2540C
10/23/2023 09:17
SNEGLIA

Certificate of Laboratory Analysis Page 17of46
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS CCP-LEACHATE-34 Sample #: 2023021799
Collection Date: 10/18/2023 10:30 AM Loc code: CLS CCP-LEACHATE-34 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23100318
Chloride
1100
mg/L
Fluoride
0.37 J
mg/L
Nitrate
7.6
mg/L
Nitrate as N
1.7
mg-N/L
Sulfate
1600
mg/L
MERCURY (COLD VAPOR) IN WATER - Q23100389
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23100325
Barium (Ba)
0.055
mg/L
Boron (B)
5.85
mg/L
Calcium (Ca)
947
mg/L
Iron (Fe)
5.30
mg/L
Lithium (Li)
0.183
mg/L
Magnesium (Mg)
122
mg/L
Manganese (Mn)
23.6
mg/L
Zinc (Zn)
0.296
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23100331
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
7.16
ug/L
Beryllium (Be)
4.15
ug/L
Cadmium (Cd)
1.48 J
ug/L
Chromium (Cr)
2.11
ug/L
Cobalt (Co)
530
ug/L
Copper (Cu)
118
ug/L
Lead (Pb)
30.2
ug/L
Molybdenum (Mo)
0.782 J
ug/L
Nickel (Ni)
276
ug/L
Selenium (Se)
5.18
ug/L
Silver (Ag)
0.119 J
ug/L
Thallium (TI) Low Level
2.35
ug/L
Vanadium (V)
0.126 J
ug/L
TOTAL DISSOLVED SOLIDS -
023100376
TDS 3930 mg/L
Method Analysis Date/Time Analyst
20
0.0154
200
EPA 9056A
10/19/2023 11:56
BGN9034
2
0.0479
20
EPA 9056A
10/19/2023 11:56
BGN9034
2
0.0209
20
EPA 9056A
10/19/2023 11:56
BGN9034
0.46
0.002
20
EPA 9056A
10/19/2023 11:56
BGN9034
20
0.0428
200
EPA 9056A
10/19/2023 11:56
BGN9034
0.05
0.01
1
EPA 7470A
10/24/2023 11:32
SNEGLIA
0.005
0.002
1
SW 601OD
10/20/2023 13:36
CELL106
0.05
0.005
1
SW 601OD
10/20/2023 13:36
CELL106
0.5
0.012
10
SW 601OD
10/20/2023 13:36
CELL106
0.01
0.004
1
SW 601OD
10/20/2023 13:36
CELL106
0.005
0.002
1
SW 601OD
10/20/2023 13:36
CELL106
0.2
0.008
10
SW 601OD
10/20/2023 13:36
CELL106
0.05
0.001
10
SW 601OD
10/20/2023 13:36
CELL106
0.005
0.004
1
SW 601OD
10/20/2023 13:36
CELL106
2
0.104
2
SW 6020B
10/24/2023 13:05
MHALL3
2
0.111
2
SW 6020B
10/24/2023 13:05
MHALL3
2
0.249
2
SW 6020E
10/24/2023 13:05
MHALL3
2
0.032
2
SW 6020E
10/24/2023 13:05
MHALL3
2
0.185
2
SW 6020B
10/24/2023 13:05
MHALL3
2
0.077
2
SW 6020E
10/24/2023 13:05
MHALL3
2
0.787
2
SW 6020B
10/24/2023 13:05
MHALL3
2
0.037
2
SW 6020E
10/24/2023 13:05
MHALL3
2
0.18
2
SW 6020E
10/24/2023 13:05
MHALL3
2
0.256
2
SW 6020B
10/24/2023 13:05
MHALL3
2
0.193
2
SW 6020B
10/24/2023 13:05
MHALL3
2
0.035
2
SW 6020E
10/24/2023 13:05
MHALL3
0.4
0.041
2
SW 6020B
10/24/2023 13:05
MHALL3
2
0.114
2
SW 6020E
10/24/2023 13:05
MHALL3
100
25
1
SM2540C
10/24/2023 08:44
SNEGLIA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS CCPSW-1
Collection Date: 10/18/2023 09:30 AM Loc code: CLS CCPSW-1
Analyte
Result
Units
Qualifiers RDL
MDL
INORGANIC IONS BY IC - Q23100318
Chloride
4.1
mg/L
0.1
0.0154
Fluoride
0.0479 U
mg/L
0.1
0.0479
Nitrate
2.2
mg/L
0.1
0.0209
Nitrate as N
0.50
mg-N/L
0.023
0.002
Sulfate
0.93
mg/L
0.1
0.0428
MERCURY (COLD VAPOR) IN WATER - Q23100389
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q23100355
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q23100325
Barium (Ba)
0.020
mg/L
0.005
0.002
Boron (B)
0.006 J
mg/L
0.05
0.005
Calcium (Ca)
2.72
mg/L
0.05
0.012
Iron (Fe)
1.03
mg/L
0.01
0.004
Lithium (Li)
0.013
mg/L
0.005
0.002
Magnesium (Mg)
1.37
mg/L
0.02
0.008
Manganese (Mn)
0.026
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
12.4
mg/L
0.19
(CaCO3)
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q23100360
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.032 U
ug/L
1
0.032
Chromium (Cr)
0.286 J
ug/L
1
0.185
Copper (Cu)
0.787 U
ug/L
1
0.787
Lead (Pb)
0.064 J
ug/L
1
0.037
Nickel (Ni)
0.435 J
ug/L
1
0.256
Silver (Ag)
0.035 U
ug/L
1
0.035
Sample #: 2023021800
Matrix: GW RCRA
Page 18 of 46
DF
Method
Analysis Date/Time
Analyst
1
EPA 9056A
10/19/2023 10:07
BGN9034
1
EPA 9056A
10/19/2023 10:07
BGN9034
1
EPA 9056A
10/19/2023 10:07
BGN9034
1
EPA 9056A
10/19/2023 10:07
BGN9034
1
EPA 9056A
10/19/2023 10:07
BGN9034
1
EPA 7470A
10/24/2023 11:34
SNEGLIA
1
SW 601OD
10/23/2023 11:04
EBATIAN
1
SW 601OD
10/20/2023 13:41
CELL106
1
SW 601OD
10/20/2023 13:41
CELL106
1
SW 601OD
10/20/2023 13:41
CELL106
1
SW 601OD
10/20/2023 13:41
CELL106
1
SW 601OD
10/20/2023 13:41
CELL106
1
SW 601OD
10/20/2023 13:41
CELL106
1
SW 601OD
10/20/2023 13:41
CELL106
1
SW 6010D
10/20/2023 13:41
CELL106
1
SW 601OD
10/20/2023 13:41
CELL106
1
SW 6020B
10/23/2023 21:36
MHALL3
1
SW 6020B
10/23/2023 21:36
MHALL3
1
SW 6020E
10/23/2023 21:36
MHALL3
1
SW 6020B
10/23/2023 21:36
MHALL3
1
SW 6020B
10/23/2023 21:36
MHALL3
1
SW 6020E
10/23/2023 21:36
MHALL3
1
SW 6020B
10/23/2023 21:36
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS CCPSW-1
Collection Date: 10/18/2023 09:30 AM Loc code: CLS CCPSW-1
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS - Q23100331
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
Arsenic (As)
0.207 J
ug/L
1
0.111
1
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.545 J
ug/L
1
0.185
1
Cobalt (Co)
0.245 J
ug/L
1
0.077
1
Copper (Cu)
0.787 U
ug/L
1
0.787
1
Lead (Pb)
0.112 J
ug/L
1
0.037
1
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
Vanadium (V)
0.256 J
ug/L
1
0.114
1
TOTAL DISSOLVED SOLIDS - Q23100376
TDS
29.0
mg/L
25
25
1
Sample #: 2023021800
Matrix: GW RCRA
Page 19 of 46
Method
Analysis Date/Time
Analyst
SW 6020B
10/23/2023 11:36
MHALL3
SW 6020B
10/23/2023 11:36
MHALL3
SW 6020E
10/23/2023 11:36
MHALL3
SW 6020B
10/23/2023 11:36
MHALL3
SW 6020B
10/23/2023 11:36
MHALL3
SW 6020E
10/23/2023 11:36
MHALL3
SW 6020B
10/23/2023 11:36
MHALL3
SW 6020E
10/23/2023 11:36
MHALL3
SW 6020B
10/23/2023 11:36
MHALL3
SW 6020E
10/23/2023 11:36
MHALL3
SW 6020B
10/23/2023 11:36
MHALL3
SW 6020E
10/23/2023 11:36
MHALL3
SW 6020B
10/23/2023 11:36
MHALL3
SW 6020E
10/23/2023 11:36
MHALL3
SM2540C
10/23/2023 09:18
SNEGLIA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS CCPSW-2
Collection Date: 10/18/2023 09:15 AM Loc code: CLS CCPSW-2
Analyte
Result
Units
Qualifiers RDL
MDL
INORGANIC IONS BY IC - Q23100318
Chloride
4.2
mg/L
0.1
0.0154
Fluoride
0.0479 U
mg/L
0.1
0.0479
Nitrate
2.1
mg/L
0.1
0.0209
Nitrate as N
0.47
mg-N/L
0.023
0.002
Sulfate
1.6
mg/L
0.1
0.0428
MERCURY (COLD VAPOR) IN WATER - Q23100389
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q23100355
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q23100325
Barium (Ba)
0.021
mg/L
0.005
0.002
Boron (B)
0.005 U
mg/L
0.05
0.005
Calcium (Ca)
2.82
mg/L
0.05
0.012
Iron (Fe)
0.958
mg/L
0.01
0.004
Lithium (Li)
0.007
mg/L
0.005
0.002
Magnesium (Mg)
1.45
mg/L
0.02
0.008
Manganese (Mn)
0.022
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
13.0
mg/L
0.19
(CaCO3)
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q23100360
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.032 U
ug/L
1
0.032
Chromium (Cr)
0.253 J
ug/L
1
0.185
Copper (Cu)
0.787 U
ug/L
1
0.787
Lead (Pb)
0.059 J
ug/L
1
0.037
Nickel (Ni)
0.372 J
ug/L
1
0.256
Silver (Ag)
0.035 U
ug/L
1
0.035
Sample #: 2023021801
Matrix: GW RCRA
Page 20 of 46
DF
Method
Analysis Date/Time
Analyst
1
EPA 9056A
10/19/2023 10:23
BGN9034
1
EPA 9056A
10/19/2023 10:23
BGN9034
1
EPA 9056A
10/19/2023 10:23
BGN9034
1
EPA 9056A
10/19/2023 10:23
BGN9034
1
EPA 9056A
10/19/2023 10:23
BGN9034
1
EPA 7470A
10/24/2023 11:36
SNEGLIA
1
SW 601OD
10/23/2023 11:19
EBATIAN
1
SW 601OD
10/20/2023 13:46
CELL106
1
SW 601OD
10/20/2023 13:46
CELL106
1
SW 601OD
10/20/2023 13:46
CELL106
1
SW 601OD
10/20/2023 13:46
CELL106
1
SW 601OD
10/20/2023 13:46
CELL106
1
SW 601OD
10/20/2023 13:46
CELL106
1
SW 601OD
10/20/2023 13:46
CELL106
1
SW 6010D
10/20/2023 13:46
CELL106
1
SW 601OD
10/20/2023 13:46
CELL106
1
SW 6020B
10/23/2023 21:09
MHALL3
1
SW 6020B
10/23/2023 21:09
MHALL3
1
SW 6020E
10/23/2023 21:09
MHALL3
1
SW 6020B
10/23/2023 21:09
MHALL3
1
SW 6020B
10/23/2023 21:09
MHALL3
1
SW 6020E
10/23/2023 21:09
MHALL3
1
SW 6020B
10/23/2023 21:09
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS CCPSW-2
Collection Date: 10/18/2023 09:15 AM Loc code: CLS CCPSW-2
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS - Q23100331
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
Arsenic (As)
0.211 J
ug/L
1
0.111
1
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.432 J
ug/L
1
0.185
1
Cobalt (Co)
0.158 J
ug/L
1
0.077
1
Copper (Cu)
0.787 U
ug/L
1
0.787
1
Lead (Pb)
0.161 J
ug/L
1
0.037
1
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
Vanadium (V)
0.41 J
ug/L
1
0.114
1
TOTAL DISSOLVED SOLIDS - Q23100376
TDS
34.0
mg/L
25
25
1
Sample #: 2023021801
Matrix: GW RCRA
Page 21 of 46
Method
Analysis Date/Time
Analyst
SW 6020B
10/23/2023 11:45
MHALL3
SW 6020B
10/23/2023 11:45
MHALL3
SW 6020E
10/23/2023 11:45
MHALL3
SW 6020B
10/23/2023 11:45
MHALL3
SW 6020B
10/23/2023 11:45
MHALL3
SW 6020E
10/23/2023 11:45
MHALL3
SW 6020B
10/23/2023 11:45
MHALL3
SW 6020E
10/23/2023 11:45
MHALL3
SW 6020B
10/23/2023 11:45
MHALL3
SW 6020E
10/23/2023 11:45
MHALL3
SW 6020B
10/23/2023 11:45
MHALL3
SW 6020E
10/23/2023 11:45
MHALL3
SW 6020B
10/23/2023 11:45
MHALL3
SW 6020E
10/23/2023 11:45
MHALL3
SM2540C
10/23/2023 09:18
SNEGLIA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS CCPSW-3
Collection Date: 10/18/2023 09:30 AM Loc code: CLS CCPSW-3
Analyte
Result
Units
Qualifiers RDL
MDL
INORGANIC IONS BY IC - Q23100318
Chloride
5.3
mg/L
0.1
0.0154
Fluoride
0.0479 U
mg/L
0.1
0.0479
Nitrate
0.86
mg/L
0.1
0.0209
Nitrate as N
0.19
mg-N/L
0.023
0.002
Sulfate
1.5
mg/L
0.1
0.0428
MERCURY (COLD VAPOR) IN WATER - Q23100389
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q23100355
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q23100325
Barium (Ba)
0.018
mg/L
0.005
0.002
Boron (B)
0.005 U
mg/L
0.05
0.005
Calcium (Ca)
2.54
mg/L
0.05
0.012
Iron (Fe)
0.511
mg/L
0.01
0.004
Lithium (Li)
0.005
mg/L
0.005
0.002
Magnesium (Mg)
1.58
mg/L
0.02
0.008
Manganese (Mn)
0.018
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
12.9
mg/L
0.19
(CaCO3)
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q23100360
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.032 U
ug/L
1
0.032
Chromium (Cr)
0.198 J
ug/L
1
0.185
Copper (Cu)
0.787 U
ug/L
1
0.787
Lead (Pb)
0.037 U
ug/L
1
0.037
Nickel (Ni)
0.392 J
ug/L
1
0.256
Silver (Ag)
0.035 U
ug/L
1
0.035
Sample #: 2023021802
Matrix: GW RCRA
Page 22 of 46
DF
Method
Analysis Date/Time
Analyst
1
EPA 9056A
10/19/2023 10:39
BGN9034
1
EPA 9056A
10/19/2023 10:39
BGN9034
1
EPA 9056A
10/19/2023 10:39
BGN9034
1
EPA 9056A
10/19/2023 10:39
BGN9034
1
EPA 9056A
10/19/2023 10:39
BGN9034
1
EPA 7470A
10/24/2023 11:38
SNEGLIA
1
SW 601OD
10/23/2023 11:23
EBATIAN
1
SW 601OD
10/20/2023 13:50
CELL106
1
SW 601OD
10/20/2023 13:50
CELL106
1
SW 601OD
10/20/2023 13:50
CELL106
1
SW 601OD
10/20/2023 13:50
CELL106
1
SW 601OD
10/20/2023 13:50
CELL106
1
SW 601OD
10/20/2023 13:50
CELL106
1
SW 601OD
10/20/2023 13:50
CELL106
1
SW 6010D
10/20/2023 13:50
CELL106
1
SW 601OD
10/20/2023 13:50
CELL106
1
SW 6020B
10/23/2023 21:44
MHALL3
1
SW 6020B
10/23/2023 21:44
MHALL3
1
SW 6020E
10/23/2023 21:44
MHALL3
1
SW 6020B
10/23/2023 21:44
MHALL3
1
SW 6020B
10/23/2023 21:44
MHALL3
1
SW 6020E
10/23/2023 21:44
MHALL3
1
SW 6020B
10/23/2023 21:44
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS CCPSW-3
Collection Date: 10/18/2023 09:30 AM Loc code: CLS CCPSW-3
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS - Q23100331
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
Arsenic (As)
0.176 J
ug/L
1
0.111
1
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.385 J
ug/L
1
0.185
1
Cobalt (Co)
0.497 J
ug/L
1
0.077
1
Copper (Cu)
0.787 U
ug/L
1
0.787
1
Lead (Pb)
0.096 J
ug/L
1
0.037
1
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
Nickel (Ni)
0.387 J
ug/L
1
0.256
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
Vanadium (V)
0.243 J
ug/L
1
0.114
1
TOTAL DISSOLVED SOLIDS - Q23100376
TDS
35.0
mg/L
25
25
1
Sample #: 2023021802
Matrix: GW RCRA
Page 23 of 46
Method
Analysis Date/Time
Analyst
SW 6020B
10/23/2023 11:53
MHALL3
SW 6020B
10/23/2023 11:53
MHALL3
SW 6020E
10/23/2023 11:53
MHALL3
SW 6020B
10/23/2023 11:53
MHALL3
SW 6020B
10/23/2023 11:53
MHALL3
SW 6020E
10/23/2023 11:53
MHALL3
SW 6020B
10/23/2023 11:53
MHALL3
SW 6020E
10/23/2023 11:53
MHALL3
SW 6020B
10/23/2023 11:53
MHALL3
SW 6020E
10/23/2023 11:53
MHALL3
SW 6020B
10/23/2023 11:53
MHALL3
SW 6020E
10/23/2023 11:53
MHALL3
SW 6020B
10/23/2023 11:53
MHALL3
SW 6020E
10/23/2023 11:53
MHALL3
SM2540C
10/23/2023 09:18
SNEGLIA

Certificate of Laboratory Analysis Page 24 of 46
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS_FD-20231018-1 Duplicate Sample #: 2023021803
Collection Date: 10/18/2023 Loc code: CLS FD Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23100318
Chloride
15000
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
18
mg/L
Nitrate as N
4.1
mg-N/L
Sulfate
780
mg/L
MERCURY (COLD VAPOR) IN WATER - Q23100389
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23100325
Barium (Ba)
0.415
mg/L
Boron (B)
10.2
mg/L
Calcium (Ca)
7730
mg/L
Iron (Fe)
0.518
mg/L
Lithium (Li)
7.27
mg/L
Magnesium (Mg)
59.7
mg/L
Manganese (Mn)
12.0
mg/L
Zinc (Zn)
0.111
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23100331
Antimony (Sb)
0.148 J
ug/L
Arsenic (As)
8.72
ug/L
Beryllium (Be)
0.975 J
ug/L
Cadmium (Cd)
2.27
ug/L
Chromium (Cr)
1.14 J
ug/L
Cobalt (Co)
535
ug/L
Copper (Cu)
35.1
ug/L
Lead (Pb)
132
ug/L
Molybdenum (Mo)
381
ug/L
Nickel (Ni)
109
ug/L
Selenium (Se)
70.2
ug/L
Silver (Ag)
0.189 J
ug/L
Thallium (TI) Low Level
9.17
ug/L
Vanadium (V)
1.33 J
ug/L
TOTAL DISSOLVED SOLIDS -
023100376
TDS 24300 mg/L
Method Analysis Date/Time Analyst
200
0.0154
2000
EPA 9056A
10/19/2023 07:48
BGN9034
5
0.0479
50
EPA 9056A
10/19/2023 07:48
BGN9034
5
0.0209
50
EPA 9056A
10/19/2023 07:48
BGN9034
1.15
0.002
50
EPA 9056A
10/19/2023 07:48
BGN9034
200
0.0428
2000
EPA 9056A
10/19/2023 07:48
BGN9034
0.05
0.01
1
EPA 7470A
10/24/2023 11:41
SNEGLIA
0.005
0.002
1
SW 601OD
10/20/2023 13:55
CELL106
0.05
0.005
1
SW 601OD
10/20/2023 13:55
CELL106
5
0.012
100
SW 601OD
10/20/2023 13:55
CELL106
0.01
0.004
1
SW 601OD
10/20/2023 13:55
CELL106
0.005
0.002
1
SW 601OD
10/20/2023 13:55
CELL106
0.02
0.008
1
SW 601OD
10/20/2023 13:55
CELL106
0.005
0.001
1
SW 601OD
10/20/2023 13:55
CELL106
0.005
0.004
1
SW 601OD
10/20/2023 13:55
CELL106
2
0.104
2
SW 6020B
10/24/2023 13:22
MHALL3
2
0.111
2
SW 6020B
10/24/2023 13:22
MHALL3
2
0.249
2
SW 6020E
10/24/2023 13:22
MHALL3
2
0.032
2
SW 6020E
10/24/2023 13:22
MHALL3
2
0.185
2
SW 6020B
10/24/2023 13:22
MHALL3
2
0.077
2
SW 6020E
10/24/2023 13:22
MHALL3
2
0.787
2
SW 6020B
10/24/2023 13:22
MHALL3
2
0.037
2
SW 6020E
10/24/2023 13:22
MHALL3
2
0.18
2
SW 6020E
10/24/2023 13:22
MHALL3
2
0.256
2
SW 6020B
10/24/2023 13:22
MHALL3
2
0.193
2
SW 6020B
10/24/2023 13:22
MHALL3
2
0.035
2
SW 6020E
10/24/2023 13:22
MHALL3
0.4
0.041
2
SW 6020B
10/24/2023 13:22
MHALL3
2
0.114
2
SW 6020E
10/24/2023 13:22
MHALL3
500
25
1
SM2540C
10/23/202310:50
SNEGLIA

Certificate of Laboratory Analysis Page 25 of 46
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS FB-20231018-1100 Field Blank Sample #: 2023021804
Collection Date: 10/18/2023 11:00 AM Loc code: CLS QA Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23100318
Chloride
0.02 J
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
0.03 J
mg/L
Nitrate as N
0.01 J
mg-N/L
Sulfate
0.0428 U
mg/L
MERCURY (COLD VAPOR) IN
WATER - Q23100389
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23100325
Barium (Ba)
0.002 U
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
0.012 U
mg/L
Iron (Fe)
0.004 U
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
0.008 U
mg/L
Manganese (Mn)
0.003 J
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23100331
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.185 U
ug/L
Cobalt (Co)
0.136 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.202 J
ug/L
Nickel (Ni)
0.256 U
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V)
0.114 U
ug/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
10/19/2023 07:17
BGN9034
0.1
0.0479
1
EPA 9056A
10/19/2023 07:17
BGN9034
0.1
0.0209
1
EPA 9056A
10/19/2023 07:17
BGN9034
0.023
0.002
1
EPA 9056A
10/19/2023 07:17
BGN9034
0.1
0.0428
1
EPA 9056A
10/19/2023 07:17
BGN9034
0.05
0.01
1
EPA 7470A
10/24/2023 11:43
SNEGLIA
0.005
0.002
1
SW 601OD
10/20/2023 14:00
CELL106
0.05
0.005
1
SW 601OD
10/20/2023 14:00
CELL106
0.05
0.012
1
SW 601OD
10/20/2023 14:00
CELL106
0.01
0.004
1
SW 601OD
10/20/2023 14:00
CELL106
0.005
0.002
1
SW 601OD
10/20/2023 14:00
CELL106
0.02
0.008
1
SW 601OD
10/20/2023 14:00
CELL106
0.005
0.001
1
SW 601OD
10/20/2023 14:00
CELL106
0.005
0.004
1
SW 601OD
10/20/2023 14:00
CELL106
1
0.104
1
SW 6020B
10/23/2023 12:10
MHALL3
1
0.111
1
SW 6020B
10/23/2023 12:10
MHALL3
1
0.249
1
SW 6020E
10/23/2023 12:10
MHALL3
1
0.032
1
SW 6020E
10/23/2023 12:10
MHALL3
1
0.185
1
SW 6020B
10/23/2023 12:10
MHALL3
1
0.077
1
SW 6020E
10/23/2023 12:10
MHALL3
1
0.787
1
SW 6020B
10/23/2023 12:10
MHALL3
1
0.037
1
SW 6020E
10/23/2023 12:10
MHALL3
1
0.18
1
SW 6020E
10/23/2023 12:10
MHALL3
1
0.256
1
SW 6020B
10/23/2023 12:10
MHALL3
1
0.193
1
SW 6020B
10/23/2023 12:10
MHALL3
1
0.035
1
SW 6020E
10/23/2023 12:10
MHALL3
0.2
0.041
1
SW 6020B
10/23/2023 12:10
MHALL3
1
0.114
1
SW 6020E
10/23/2023 12:10
MHALL3

Certificate of Laboratory Analysis Page 26 of 46
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS CCR-CCPBG-1 D Sample #: 2023021805
Collection Date: 10/18/2023 01:35 PM Loc code: CLS CCR-CCPBG-1 D Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23100318
Chloride
9.2
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
17
mg/L
Nitrate as N
3.8
mg-N/L
Sulfate
0.44
mg/L
MERCURY (COLD VAPOR) IN WATER - Q23100389
Mercury (Hg)
0.01 U
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23100325
Barium (Ba)
0.033
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
3.61
mg/L
Iron (Fe)
0.054
mg/L
Lithium (Li)
0.011
mg/L
Magnesium (Mg)
2.14
mg/L
Manganese (Mn)
0.028
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23100331
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.409 J
ug/L
Cobalt (Co)
0.653 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.105 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
1.07
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.274 J
ug/L
Thallium (TI) Low Level
0.056 J
ug/L
Vanadium (V)
0.114 U
ug/L
TOTAL DISSOLVED SOLIDS -
023100376
TDS 65.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
10/19/2023 10:55
BGN9034
0.1
0.0479
1
EPA 9056A
10/19/2023 10:55
BGN9034
0.5
0.0209
5
EPA 9056A
10/19/2023 10:55
BGN9034
0.115
0.002
5
EPA 9056A
10/19/2023 10:55
BGN9034
0.1
0.0428
1
EPA 9056A
10/19/2023 10:55
BGN9034
0.05
0.01
1
EPA 7470A
10/24/2023 11:45
SNEGLIA
0.005
0.002
1
SW 601OD
10/20/2023 14:05
CELL106
0.05
0.005
1
SW 601OD
10/20/2023 14:05
CELL106
0.05
0.012
1
SW 601OD
10/20/2023 14:05
CELL106
0.01
0.004
1
SW 601OD
10/20/2023 14:05
CELL106
0.005
0.002
1
SW 601OD
10/20/2023 14:05
CELL106
0.02
0.008
1
SW 601OD
10/20/2023 14:05
CELL106
0.005
0.001
1
SW 601OD
10/20/2023 14:05
CELL106
0.005
0.004
1
SW 601OD
10/20/2023 14:05
CELL106
1
0.104
1
SW 6020B
10/23/2023 12:18
MHALL3
1
0.111
1
SW 6020B
10/23/2023 12:18
MHALL3
1
0.249
1
SW 6020E
10/23/2023 12:18
MHALL3
1
0.032
1
SW 6020E
10/23/2023 12:18
MHALL3
1
0.185
1
SW 6020B
10/23/2023 12:18
MHALL3
1
0.077
1
SW 6020E
10/23/2023 12:18
MHALL3
1
0.787
1
SW 6020B
10/23/2023 12:18
MHALL3
1
0.037
1
SW 6020E
10/23/2023 12:18
MHALL3
1
0.18
1
SW 6020E
10/23/2023 12:18
MHALL3
1
0.256
1
SW 6020B
10/23/2023 12:18
MHALL3
1
0.193
1
SW 6020B
10/23/2023 12:18
MHALL3
1
0.035
1
SW 6020E
10/23/2023 12:18
MHALL3
0.2
0.041
1
SW 6020B
10/23/2023 12:18
MHALL3
1
0.114
1
SW 6020E
10/23/2023 12:18
MHALL3
25
25
1
SM2540C
10/23/2023 09:19
SNEGLIA

Certificate of Laboratory Analysis Page 27 of 46
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS CCR-CCPBG-1 BR Sample #: 2023021806
Collection Date: 10/18/2023 01:40 PM Loc code: CLS CCR-CCPBG-1 BR Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23100318
Chloride 120 mg/L
Fluoride 0.13 J mg/L
Nitrate 2.1 mg/L
Nitrate as N 0.47 mg-N/L
Sulfate 170 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23100413
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23100326
Barium (Ba)
0.006
mg/L
Boron (B)
0.014 J
mg/L
Calcium (Ca)
40.3
mg/L
Iron (Fe)
0.005 J
mg/L
Lithium (Li)
0.009
mg/L
Magnesium (Mg)
2.71
mg/L
Manganese (Mn)
0.036
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23100332
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.698 J
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.185 U
ug/L
Cobalt (Co)
0.096 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
20.8
ug/L
Nickel (Ni)
2.83
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V)
0.632 J
ug/L
TOTAL DISSOLVED SOLIDS -
023100376
TDS 566 mg/L
Method Analysis Date/Time Analyst
5
0.0154
50
EPA 9056A
10/19/2023 11:41
BGN9034
0.5
0.0479
5
EPA 9056A
10/19/2023 11:41
BGN9034
0.5
0.0209
5
EPA 9056A
10/19/2023 11:41
BGN9034
0.115
0.002
5
EPA 9056A
10/19/2023 11:41
BGN9034
5
0.0428
50
EPA 9056A
10/19/2023 11:41
BGN9034
0.05
0.01
1
EPA 7470A
10/25/2023 10:11
SNEGLIA
0.005
0.002
1
SW 601OD
10/23/2023 12:01
CELL106
0.05
0.005
1
SW 601OD
10/23/2023 12:01
CELL106
0.05
0.012
1
SW 601OD
10/23/2023 12:01
CELL106
0.01
0.004
1
SW 601OD
10/23/2023 12:01
CELL106
0.005
0.002
1
SW 601OD
10/23/2023 12:01
CELL106
0.02
0.008
1
SW 601OD
10/23/2023 12:01
CELL106
0.005
0.001
1
SW 601OD
10/23/2023 12:01
CELL106
0.005
0.004
1
SW 601OD
10/23/2023 12:01
CELL106
1
0.104
1
SW 6020B
10/23/2023 14:24
MHALL3
1
0.111
1
SW 6020B
10/23/2023 14:24
MHALL3
1
0.249
1
SW 6020E
10/23/2023 14:24
MHALL3
1
0.032
1
SW 6020E
10/23/2023 14:24
MHALL3
1
0.185
1
SW 6020B
10/23/2023 14:24
MHALL3
1
0.077
1
SW 6020E
10/23/2023 14:24
MHALL3
1
0.787
1
SW 6020B
10/23/2023 14:24
MHALL3
1
0.037
1
SW 6020E
10/23/2023 14:24
MHALL3
1
0.18
1
SW 6020E
10/23/2023 14:24
MHALL3
1
0.256
1
SW 6020B
10/23/2023 14:24
MHALL3
1
0.193
1
SW 6020B
10/23/2023 14:24
MHALL3
1
0.035
1
SW 6020E
10/23/2023 14:24
MHALL3
0.2
0.041
1
SW 6020B
10/23/2023 14:24
MHALL3
1
0.114
1
SW 6020E
10/23/2023 14:24
MHALL3
25
25
1
SM2540C
10/23/2023 09:19
SNEGLIA

Certificate of Laboratory Analysis Page 28 of 46
This report shall not be reproduced, except in full.
Order # J23090016
Site: CLS_FD-20231018-2 Duplicate Sample #: 2023021807
Collection Date: 10/18/2023 Loc code: CLS FD Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23100318
Chloride
2.9
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
6.4
mg/L
Nitrate as N
1.4
mg-N/L
Sulfate
6.5
mg/L
MERCURY (COLD VAPOR) IN WATER - Q23100413
Mercury (Hg)
0.01 J
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23100326
Barium (Ba)
0.028
mg/L
Boron (B)
0.012 J
mg/L
Calcium (Ca)
2.94
mg/L
Iron (Fe)
0.081
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
1.91
mg/L
Manganese (Mn)
0.032
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23100332
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
1.28
ug/L
Cobalt (Co)
0.395 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.076 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.6 J
ug/L
Selenium (Se)
0.498 J
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.042 J
ug/L
Vanadium (V)
0.304 J
ug/L
TOTAL DISSOLVED SOLIDS -
023100376
TDS 55 J mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
10/19/2023 09:20
BGN9034
0.1
0.0479
1
EPA 9056A
10/19/2023 09:20
BGN9034
0.1
0.0209
1
EPA 9056A
10/19/2023 09:20
BGN9034
0.023
0.002
1
EPA 9056A
10/19/2023 09:20
BGN9034
0.1
0.0428
1
EPA 9056A
10/19/2023 09:20
BGN9034
0.05
0.01
1
EPA 7470A
10/25/2023 10:29
SNEGLIA
0.005
0.002
1
SW 601OD
10/23/2023 12:16
CELL106
0.05
0.005
1
SW 601OD
10/23/2023 12:16
CELL106
0.05
0.012
1
SW 601OD
10/23/2023 12:16
CELL106
0.01
0.004
1
SW 601OD
10/23/2023 12:16
CELL106
0.005
0.002
1
SW 601OD
10/23/2023 12:16
CELL106
0.02
0.008
1
SW 601OD
10/23/2023 12:16
CELL106
0.005
0.001
1
SW 601OD
10/23/2023 12:16
CELL106
0.005
0.004
1
SW 601OD
10/23/2023 12:16
CELL106
1
0.104
1
SW 6020B
10/23/2023 14:33
MHALL3
1
0.111
1
SW 6020B
10/23/2023 14:33
MHALL3
1
0.249
1
SW 6020E
10/23/2023 14:33
MHALL3
1
0.032
1
SW 6020E
10/23/2023 14:33
MHALL3
1
0.185
1
SW 6020B
10/23/2023 14:33
MHALL3
1
0.077
1
SW 6020E
10/23/2023 14:33
MHALL3
1
0.787
1
SW 6020B
10/23/2023 14:33
MHALL3
1
0.037
1
SW 6020E
10/23/2023 14:33
MHALL3
1
0.18
1
SW 6020E
10/23/2023 14:33
MHALL3
1
0.256
1
SW 6020B
10/23/2023 14:33
MHALL3
1
0.193
1
SW 6020B
10/23/2023 14:33
MHALL3
1
0.035
1
SW 6020E
10/23/2023 14:33
MHALL3
0.2
0.041
1
SW 6020B
10/23/2023 14:33
MHALL3
1
0.114
1
SW 6020E
10/23/2023 14:33
MHALL3
125
25
1
SM2540C
10/24/2023 08:44
SNEGLIA

Certificate of Laboratory Analysis Page 29 of 46
This report shall not be reproduced, except in full.
Order # J23090016
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an estimate.
M Matrix Spike and/or Matrix Spike Duplicate recovery was outside of the control limits. The associated Laboratory Control
Spike (LCS) recovery was acceptable.

Certificate of Laboratory Analysis Page 30 of 46
This report shall not be reproduced, except in full.
Order # J23090016
Level II QC Summary
Q23100317 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Fluoride
0
0
mg/L
1
0.0479
0.1
< MDL
Nitrate
0
0
mg/L
1
0.0209
0.1
< MDL
Sulfate
0.001
0.001
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
5.18
5.18
mg/L
1
0.0154
5
104
80
120
Fluoride
4.91
4.91
mg/L
1
0.0479
5
98.2
80
120
Nitrate
5.28
5.28
mg/L
1
0.0209
5
106
80
120
Sulfate
5.22
5.22
mg/L
1
0.0428
5
104
80
120
MS # 1
Parent Sample:
J23090016 -- 2023021783
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
8.86
8.86
mg/L
1
0.0154
5
98.5
80
120
Fluoride
4.81
4.81
mg/L
1
0.0479
5
96.3
80
120
Nitrate
5.18
5.18
mg/L
1
0.0209
5
101
80
120
Sulfate
5.33
5.33
mg/L
1
0.0428
5
102
80
120
MSD # 1
Parent Sample:
J23090016 -- 2023021783
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Qualifier
Chloride
8.87
8.87
mg/L
1
0.0154
5
98.6
80
120
0.122
Fluoride
4.83
4.83
mg/L
1
0.0479
5
96.6
80
120
0.332
Nitrate
5.17
5.17
mg/L
1
0.0209
5
101
80
120
0.0395
Sulfate
5.35
5.35
mg/L
1
0.0428
5
102
80
120
0.45

Certificate of Laboratory Analysis Page 31 of46
This report shall not be reproduced, except in full.
Order # J23090016
Level II QC Summary
Q23100318 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Fluoride
0
0
mg/L
1
0.0479
0.1
< MDL
Nitrate
0
0
mg/L
1
0.0209
0.1
< MDL
Sulfate
0.002
0.002
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
5.14
5.14
mg/L
1
0.0154
5
103
80
120
Fluoride
4.88
4.88
mg/L
1
0.0479
5
97.5
80
120
Nitrate
5.22
5.22
mg/L
1
0.0209
5
104
80
120
Sulfate
5.18
5.18
mg/L
1
0.0428
5
104
80
120
MS # 1
Parent Sample:
J23090016 -- 2023021793
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
3.1
15.5
mg/L
5
0.0154
5
99
80
120
Fluoride
4.79
4.79
mg/L
1
0.0479
5
95.5
80
120
Nitrate
2.74
13.7
mg/L
5
0.0209
5
101
80
120
Sulfate
5.52
5.52
mg/L
1
0.0428
5
101
80
120
MSD # 1
Parent Sample:
J23090016 -- 2023021793
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Qualifier
Chloride
3.09
15.5
mg/L
5
0.0154
5
97.8
80
120
1.22
Fluoride
4.77
4.77
mg/L
1
0.0479
5
95.2
80
120
0.315
Nitrate
2.73
13.6
mg/L
5
0.0209
5
99.9
80
120
1.1
Sulfate
5.52
5.52
mg/L
1
0.0428
5
101
80
120
0.0397

Certificate of Laboratory Analysis Page 32 of46
This report shall not be reproduced, except in full.
Order # J23090016
Level II QC Summary
Q23100389 HG 7470 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration Qualifier
Mercury (Hg)
0.007
0.007
ug/L
1
0.01
0.05
< MDL
Blank # 2
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration Qualifier
Mercury (Hg)
-0.001
-0.001
ug/L
1
0.01
0.05
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
2.25
2.25
ug/L
1
0.01
2
112
85 115
MS # 1
Parent Sample:
J23090016 -- 2023021783
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.08
1.08
ug/L
1
0.01
1
107
75 125
MSD # 1
Parent Sample:
J23090016 -- 2023021783
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.15
1.15
ug/L
1
0.01
1
114
75 125 6.14
MS # 2
Parent Sample:
J23090016 -- 2023021795
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.2
1.2
ug/L
1
0.01
1
117
75 125
MSD # 2
Parent Sample:
J23090016 -- 2023021795
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.28
1.28
ug/L
1
0.01
1
125
75 125 7.02
M
Qualifiers:
M Matrix Spike and/or Matrix Spike Duplicate recovery was outside of the control limits. The associated
Laboratory Control Spike (LCS) recovery was acceptable.

Certificate of Laboratory Analysis Page 33 of 46
This report shall not be reproduced, except in full.
Order # J23090016
Level II QC Summary
Q23100413 HG 7470 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Mercury (Hg)
0.005
0.005
Blank # 2
Parameter
Measured
Final
Mercury (Hg)
0.005
0.005
LCS # 1
MS # 1
MSD # 1
MS # 2
MSD # 2
Parameter Measured Final
Mercury (Hg) 2.3 2.3
Parameter Measured Final
Mercury (Hg) 0.773 0.773
Parameter Measured Final
Mercury (Hg) 0.756 0.756
Parameter Measured Final
Mercury (Hg) 1.1 1.1
Parameter Measured Final
Mercury (Hg) 1.06 1.06
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
ug/L
1
0.01
0.05
< MDL
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
ug/L
1
0.01
0.05
< MDL
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
ug/L
1
0.01
2
115
85 115
Parent Sample:
J23100361 -- 2023026178
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
ug/L
1
0.01
1
76.6
75 125
Parent Sample:
J23100361 -- 2023026178
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
ug/L
1
0.01
1
74.9
75 125 2.24
M
Parent Sample:
J23090016 -- 2023021806
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
ug/L
1
0.01
1
109
75 125
Parent Sample:
J23090016 -- 2023021806
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
ug/L
1
0.01
1
105
75 125 3.72
Qualifiers:
M Matrix Spike and/or Matrix Spike Duplicate recovery was outside of the control limits. The associated
Laboratory Control Spike (LCS) recovery was acceptable.

Certificate of Laboratory Analysis Page 34 of 46
This report shall not be reproduced, except in full.
Order # J23090016
Level II QC Summary
Q23100355 ICP_DIS_TRM TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Zinc (Zn)
0.0002
0.0002
mg/L
1
0.004
0.005
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Zinc (Zn)
5.05
5.05
mg/L
1
0.004
5
101
80
120
MS # 1
Parent Sample:
J23090016 -- 2023021800
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Zinc (Zn)
5.05
5.05
mg/L
1
0.004
5
101
70
130
MSD # 1
Parent Sample:
J23090016 -- 2023021800
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Zinc (Zn)
5.09
5.09
mg/L
1
0.004
5
102
70
130 0.714
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 35 of 46
This report shall not be reproduced, except in full.
Order # J23090016
Level II QC Summary
Q23100325 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
0.000008
0.000008
mg/L
1
0.002
0.005
< MDL
Boron (B)
-0.00109
-0.00109
mg/L
1
0.005
0.05
< MDL
Calcium (Ca)
0.000254
0.000254
mg/L
1
0.012
0.05
< MDL
Iron (Fe)
0.00281
0.00281
mg/L
1
0.004
0.01
< MDL
Lithium (Li)
0.000994
0.000994
mg/L
1
0.002
0.005
< MDL
Magnesium (Mg)
0.0043
0.0043
mg/L
1
0.008
0.02
< MDL
Manganese (Mn)
0.000115
0.000115
mg/L
1
0.001
0.005
< MDL
Zinc (Zn)
-0.000043
-0.000043
mg/L
1
0.004
0.005
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
5.18
5.18
mg/L
1
0.002
5
104
80
120
Boron (B)
4.91
4.91
mg/L
1
0.005
5
98.1
80
120
Calcium (Ca)
4.89
4.89
mg/L
1
0.012
5
97.9
80
120
Iron (Fe)
5.03
5.03
mg/L
1
0.004
5
101
80
120
Lithium (Li)
4.87
4.87
mg/L
1
0.002
5
97.4
80
120
Magnesium (Mg)
5.05
5.05
mg/L
1
0.008
5
101
80
120
Manganese (Mn)
4.91
4.91
mg/L
1
0.001
5
98.3
80
120
Zinc (Zn)
5.14
5.14
mg/L
1
0.004
5
103
80
120
MS # 1
Parent Sample:
J23090016
-- 2023021783
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
Barium (Ba)
5.21
5.21
mg/L
1
0.002
5
104
75
125
Boron (B)
4.93
4.93
mg/L
1
0.005
5
98.4
75
125
Calcium (Ca)
5.1
5.1
mg/L
1
0.012
5
98.7
75
125
Iron (Fe)
5.07
5.07
mg/L
1
0.004
5
101
75
125
Lithium (Li)
4.94
4.94
mg/L
1
0.002
5
98.7
75
125
Magnesium (Mg)
5.74
5.74
mg/L
1
0.008
5
101
75
125
Manganese (Mn)
4.95
4.95
mg/L
1
0.001
5
98.6
75
125
Zinc (Zn)
5.17
5.17
mg/L
1
0.004
5
103
75
125
MSD # 1
Parent Sample:
J23090016
-- 2023021783
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Barium (Ba)
5.26
5.26
mg/L
1
0.002
5
105
75
125
0.859
Boron (B)
4.93
4.93
mg/L
1
0.005
5
98.5
75
125
0.101
Calcium (Ca)
5.09
5.09
mg/L
1
0.012
5
98.4
75
125
0.236
Iron (Fe)
5.06
5.06
mg/L
1
0.004
5
101
75
125
0.119
Lithium (Li)
4.93
4.93
mg/L
1
0.002
5
98.4
75
125
0.264
Magnesium (Mg)
5.69
5.69
mg/L
1
0.008
5
101
75
125
0.805
Manganese (Mn)
4.97
4.97
mg/L
1
0.001
5
99.1
75
125
0.504
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 36 of 46
This report shall not be reproduced, except in full.
Order # J23090016
Level II QC Summary
Q23100325 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
MSD # 1 Parent Sample: J23090016 -- 2023021783
Parameter Measured Final Units Dil MDL Spike % Recovery LCL UCL RPD Qualifier
Zinc (Zn) 5.17 5.17 mg/L 1 0.004 5 103 75 125 0.116

Certificate of Laboratory Analysis Page 37 of 46
This report shall not be reproduced, except in full.
Order # J23090016
Level II QC Summary
Q23100326 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
-0.0003
-0.0003
mg/L
1
0.002
0.005
< MDL
Boron (B)
0.000586
0.000586
mg/L
1
0.005
0.05
< MDL
Calcium (Ca)
0.00643
0.00643
mg/L
1
0.012
0.05
< MDL
Iron (Fe)
0.0034
0.0034
mg/L
1
0.004
0.01
< MDL
Lithium (Li)
0.000372
0.000372
mg/L
1
0.002
0.005
< MDL
Magnesium (Mg)
-0.0001
-0.0001
mg/L
1
0.008
0.02
< MDL
Manganese (Mn)
-0.000023
-0.000023
mg/L
1
0.001
0.005
< MDL
Zinc (Zn)
-0.000156
-0.000156
mg/L
1
0.004
0.005
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
4.89
4.89
mg/L
1
0.002
5
97.8
80
120
Boron (B)
4.92
4.92
mg/L
1
0.005
5
98.4
80
120
Calcium (Ca)
5
5
mg/L
1
0.012
5
100
80
120
Iron (Fe)
4.99
4.99
mg/L
1
0.004
5
99.8
80
120
Lithium (Li)
4.97
4.97
mg/L
1
0.002
5
99.5
80
120
Magnesium (Mg)
4.99
4.99
mg/L
1
0.008
5
99.7
80
120
Manganese (Mn)
4.98
4.98
mg/L
1
0.001
5
99.6
80
120
Zinc (Zn)
4.97
4.97
mg/L
1
0.004
5
99.4
80
120
MS # 1
Parent Sample:
J23090016
-- 2023021806
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
Barium (Ba)
4.82
4.82
mg/L
1
0.002
5
96.2
75
125
Boron (B)
4.88
4.88
mg/L
1
0.005
5
97.4
75
125
Calcium (Ca)
45.5
45.5
mg/L
1
0.012
5
105
75
125
Iron (Fe)
4.92
4.92
mg/L
1
0.004
5
98.3
75
125
Lithium (Li)
4.88
4.88
mg/L
1
0.002
5
97.5
75
125
Magnesium (Mg)
7.5
7.5
mg/L
1
0.008
5
95.8
75
125
Manganese (Mn)
4.94
4.94
mg/L
1
0.001
5
98.1
75
125
Zinc (Zn)
4.84
4.84
mg/L
1
0.004
5
96.8
75
125
MSD # 1
Parent Sample:
J23090016
-- 2023021806
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Barium (Ba)
4.82
4.82
mg/L
1
0.002
5
96.2
75
125
0.0415
Boron (B)
4.88
4.88
mg/L
1
0.005
5
97.2
75
125
0.143
Calcium (Ca)
45.5
45.5
mg/L
1
0.012
5
105
75
125
0.00879
Iron (Fe)
4.91
4.91
mg/L
1
0.004
5
98.1
75
125
0.183
Lithium (Li)
4.88
4.88
mg/L
1
0.002
5
97.4
75
125
0.082
Magnesium (Mg)
7.48
7.48
mg/L
1
0.008
5
95.4
75
125
0.273
Manganese (Mn)
4.93
4.93
mg/L
1
0.001
5
97.9
75
125
0.122
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 38 of 46
This report shall not be reproduced, except in full.
Order # J23090016
Level II QC Summary
Q23100326 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
MSD # 1 Parent Sample: J23090016 -- 2023021806
Parameter Measured Final Units Dil MDL Spike % Recovery LCL UCL RPD Qualifier
Zinc (Zn) 4.84 4.84 mg/L 1 0.004 5 96.9 75 125 0.0826

Certificate of Laboratory Analysis Page 39 of 46
This report shall not be reproduced, except in full.
Order # J23090016
Level II QC Summary
Q23100360 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Blank # 1
LCS # 1
MS # 1
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Beryllium (Be)
0.032
0.032
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0.006
0.006
ug/L
1
0.032
1
< MDL
Chromium (Cr)
-0.005
-0.005
ug/L
1
0.185
1
< MDL
Copper (Cu)
0.013
0.013
ug/L
1
0.787
1
< MDL
Lead (Pb)
0.002
0.002
ug/L
1
0.037
1
< MDL
Nickel (Ni)
-0.002
-0.002
ug/L
1
0.256
1
< MDL
Silver (Ag)
0.002
0.002
ug/L
1
0.035
1
< MDL
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Beryllium (Be)
49.2
49.2
ug/L
1
0.249
50
98.5
80
120
Cadmium (Cd)
49.3
49.3
ug/L
1
0.032
50
98.6
80
120
Chromium (Cr)
51.5
51.5
ug/L
1
0.185
50
103
80
120
Copper (Cu)
49.1
49.1
ug/L
1
0.787
50
98.3
80
120
Lead (Pb)
51.3
51.3
ug/L
1
0.037
50
103
80
120
Nickel (Ni)
48
48
ug/L
1
0.256
50
96
80
120
Silver (Ag)
49.4
49.4
ug/L
1
0.035
50
98.9
80
120
Parent Sample:
J23090016 -- 2023021801
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
Beryllium (Be)
50.4
50.4
ug/L
1
0.249
50
101
75
125
Cadmium (Cd)
49.9
49.9
ug/L
1
0.032
50
99.8
75
125
Chromium (Cr)
52.6
52.6
ug/L
1
0.185
50
105
75
125
Copper (Cu)
49
49
ug/L
1
0.787
50
97
75
125
Lead (Pb)
51.5
51.5
ug/L
1
0.037
50
103
75
125
Nickel (Ni)
48.3
48.3
ug/L
1
0.256
50
95.8
75
125
Silver (Ag)
49.4
49.4
ug/L
1
0.035
50
98.8
75
125
Parent Sample:
J23090016 -- 2023021801
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
RPD
Beryllium (Be)
51.8
51.8
ug/L
1
0.249
50
104
75
125
2.75
Cadmium (Cd)
49.8
49.8
ug/L
1
0.032
50
99.6
75
125
0.211
Chromium (Cr)
52.8
52.8
ug/L
1
0.185
50
105
75
125
0.341
Copper (Cu)
49.1
49.1
ug/L
1
0.787
50
97.2
75
125
0.227
Lead (Pb)
51.7
51.7
ug/L
1
0.037
50
103
75
125
0.516
Nickel (Ni)
48.3
48.3
ug/L
1
0.256
50
95.8
75
125
0.0814
Silver (Ag)
49.4
49.4
ug/L
1
0.035
50
98.8
75
125
0.0283
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090016
Level II QC Summary
Q23100331 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
0.06
0.06
ug/L
1
0.104
1
< MDL
Arsenic (As)
0.017
0.017
ug/L
1
0.111
1
< MDL
Beryllium (Be)
0.043
0.043
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0.02
0.02
ug/L
1
0.032
1
< MDL
Chromium (Cr)
0.035
0.035
ug/L
1
0.185
1
< MDL
Cobalt (Co)
0.006
0.006
ug/L
1
0.077
1
< MDL
Copper (Cu)
0.025
0.025
ug/L
1
0.787
1
< MDL
Lead (Pb)
0.005
0.005
ug/L
1
0.037
1
< MDL
Molybdenum (Mo)
0.023
0.023
ug/L
1
0.18
1
< MDL
Nickel (Ni)
0.004
0.004
ug/L
1
0.256
1
< MDL
Selenium (Se)
0
0
ug/L
1
0.193
1
< MDL
Silver (Ag)
0.008
0.008
ug/L
1
0.035
1
< MDL
Thallium (TI) Low Level
-0.01
-0.01
ug/L
1
0.041
0.2
< MDL
Vanadium (V)
-0.006
-0.006
ug/L
1
0.114
1
< MDL
LCS # 1
Page 40 of 46
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
Antimony (Sb)
48.9
48.9
ug/L
1
0.104
50
97.7
80
120
Arsenic (As)
48.3
48.3
ug/L
1
0.111
50
96.6
80
120
Beryllium (Be)
47.6
47.6
ug/L
1
0.249
50
95.2
80
120
Cadmium (Cd)
48.6
48.6
ug/L
1
0.032
50
97.3
80
120
Chromium (Cr)
49.5
49.5
ug/L
1
0.185
50
99.1
80
120
Cobalt (Co)
49.5
49.5
ug/L
1
0.077
50
98.9
80
120
Copper (Cu)
49.1
49.1
ug/L
1
0.787
50
98.1
80
120
Lead (Pb)
49.3
49.3
ug/L
1
0.037
50
98.6
80
120
Molybdenum (Mo)
49.6
49.6
ug/L
1
0.18
50
99.2
80
120
Nickel (Ni)
48.2
48.2
ug/L
1
0.256
50
96.3
80
120
Selenium (Se)
46.5
46.5
ug/L
1
0.193
50
93
80
120
Silver (Ag)
49.1
49.1
ug/L
1
0.035
50
98.2
80
120
Thallium (TI) Low Level
47.8
47.8
ug/L
1
0.041
50
95.7
80
120
Vanadium (V)
48.6
48.6
ug/L
1
0.114
50
97.3
80
120
MS # 1
Parent Sample:
J23090016
-- 2023021784
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
49.2
49.2
ug/L
1
0.104
50
98.4
75
125
Arsenic (As)
48.3
48.3
ug/L
1
0.111
50
96.4
75
125
Beryllium (Be)
47.8
47.8
ug/L
1
0.249
50
95.5
75
125
Cadmium (Cd)
48.9
48.9
ug/L
1
0.032
50
97.7
75
125
Chromium (Cr)
49.8
49.8
ug/L
1
0.185
50
99.3
75
125
Cobalt (Co)
50
50
ug/L
1
0.077
50
99.3
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090016
Level II QC Summary
Q23100331 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
Copper (Cu)
49.2
49.2
ug/L
1
0.787
50
Lead (Pb)
49.4
49.4
ug/L
1
0.037
50
Molybdenum (Mo)
50.8
50.8
ug/L
1
0.18
50
Nickel (Ni)
49.2
49.2
ug/L
1
0.256
50
Selenium (Se)
45.9
45.9
ug/L
1
0.193
50
Silver (Ag)
48.9
48.9
ug/L
1
0.035
50
Thallium (TI) Low Level
47.2
47.2
ug/L
1
0.041
50
Vanadium (V)
48.3
48.3
ug/L
1
0.114
50
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
Antimony (Sb)
48.8
48.8
ug/L
1
0.104
50
Arsenic (As)
47.7
47.7
ug/L
1
0.111
50
Beryllium (Be)
47.5
47.5
ug/L
1
0.249
50
Cadmium (Cd)
48.3
48.3
ug/L
1
0.032
50
Chromium (Cr)
50.2
50.2
ug/L
1
0.185
50
Cobalt (Co)
49.5
49.5
ug/L
1
0.077
50
Copper (Cu)
49.2
49.2
ug/L
1
0.787
50
Lead (Pb)
49.2
49.2
ug/L
1
0.037
50
Molybdenum (Mo)
50.3
50.3
ug/L
1
0.18
50
Nickel (Ni)
48.9
48.9
ug/L
1
0.256
50
Selenium (Se)
45.6
45.6
ug/L
1
0.193
50
Silver (Ag)
48.7
48.7
ug/L
1
0.035
50
Thallium (TI) Low Level
47.2
47.2
ug/L
1
0.041
50
Vanadium (V)
48.9
48.9
ug/L
1
0.114
50
Page 41 of 46
Parent Sample: J23090016 -- 2023021784
% Recovery
LCL
UCL
97.9
75
125
98.8
75
125
101
75
125
96.6
75
125
91.7
75
125
97.8
75
125
94.3
75
125
96.6
75
125
Parent Sample: J23090016 -- 2023021784
% Recovery
LCL
UCL
RPD
97.4
75
125
0.987
95.2
75
125
1.27
94.8
75
125
0.803
96.6
75
125
1.1
100
75
125
0.795
98.3
75
125
1.01
98
75
125
0.096
98.3
75
125
0.501
100
75
125
0.975
96.1
75
125
0.546
91.1
75
125
0.676
97.3
75
125
0.467
94.4
75
125
0.17
97.8
75
125
1.29
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090016
Level II QC Summary
Q23100332 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
-0.05
-0.05
ug/L
1
0.104
1
< MDL
Arsenic (As)
0.042
0.042
ug/L
1
0.111
1
< MDL
Beryllium (Be)
0.107
0.107
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0.236
0.236
ug/L
1
0.032
1
> MDL
Chromium (Cr)
0.082
0.082
ug/L
1
0.185
1
< MDL
Cobalt (Co)
0.078
0.078
ug/L
1
0.077
1
> MDL
Copper (Cu)
0.013
0.013
ug/L
1
0.787
1
< MDL
Lead (Pb)
0.068
0.068
ug/L
1
0.037
1
> MDL
Molybdenum (Mo)
0.017
0.017
ug/L
1
0.18
1
< MDL
Nickel (Ni)
0.195
0.195
ug/L
1
0.256
1
< MDL
Selenium (Se)
-0.032
-0.032
ug/L
1
0.193
1
< MDL
Silver (Ag)
0.005
0.005
ug/L
1
0.035
1
< MDL
Thallium (TI) Low Level
0.007
0.007
ug/L
1
0.041
0.2
< MDL
Vanadium (V)
-0.013
-0.013
ug/L
1
0.114
1
< MDL
LCS # 1
Page 42 of 46
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
Antimony (Sb)
48.7
48.7
ug/L
1
0.104
50
97.5
80
120
Arsenic (As)
48.8
48.8
ug/L
1
0.111
50
97.6
80
120
Beryllium (Be)
50.3
50.3
ug/L
1
0.249
50
101
80
120
Cadmium (Cd)
48
48
ug/L
1
0.032
50
96
80
120
Chromium (Cr)
49.3
49.3
ug/L
1
0.185
50
98.7
80
120
Cobalt (Co)
50.4
50.4
ug/L
1
0.077
50
101
80
120
Copper (Cu)
49.7
49.7
ug/L
1
0.787
50
99.5
80
120
Lead (Pb)
50.2
50.2
ug/L
1
0.037
50
100
80
120
Molybdenum (Mo)
49.5
49.5
ug/L
1
0.18
50
98.9
80
120
Nickel (Ni)
49.2
49.2
ug/L
1
0.256
50
98.5
80
120
Selenium (Se)
47
47
ug/L
1
0.193
50
93.9
80
120
Silver (Ag)
47.5
47.5
ug/L
1
0.035
50
95
80
120
Thallium (TI) Low Level
48.7
48.7
ug/L
1
0.041
50
97.4
80
120
Vanadium (V)
48.5
48.5
ug/L
1
0.114
50
97
80
120
MS # 1
Parent Sample:
J23100346
-- 2023026044
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
25.9
51.8
ug/L
2
0.104
50
103
75
125
Arsenic (As)
28.5
56.9
ug/L
2
0.111
50
102
75
125
Beryllium (Be)
21.7
43.4
ug/L
2
0.249
50
85.3
75
125
Cadmium (Cd)
24.1
48.2
ug/L
2
0.032
50
93.8
75
125
Chromium (Cr)
24.2
48.4
ug/L
2
0.185
50
95.8
75
125
Cobalt (Co)
251
502
ug/L
2
0.077
50
118
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090016
Level II QC Summary
Q23100332 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
Copper (Cu)
45
90
ug/L
2
0.787
50
Lead (Pb)
41.5
83.1
ug/L
2
0.037
50
Molybdenum (Mo)
125
249
ug/L
2
0.18
50
Nickel (Ni)
94.1
188
ug/L
2
0.256
50
Selenium (Se)
38.3
76.5
ug/L
2
0.193
50
Silver (Ag)
23.2
46.4
ug/L
2
0.035
50
Thallium (TI) Low Level
27.6
55.3
ug/L
2
0.041
50
Vanadium (V)
24.5
48.9
ug/L
2
0.114
50
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
Antimony (Sb)
25.3
50.7
ug/L
2
0.104
50
Arsenic (As)
27.5
55
ug/L
2
0.111
50
Beryllium (Be)
21.8
43.7
ug/L
2
0.249
50
Cadmium (Cd)
24.3
48.7
ug/L
2
0.032
50
Chromium (Cr)
24.4
48.7
ug/L
2
0.185
50
Cobalt (Co)
248
495
ug/L
2
0.077
50
Copper (Cu)
44.5
89
ug/L
2
0.787
50
Lead (Pb)
41.5
83
ug/L
2
0.037
50
Molybdenum (Mo)
124
249
ug/L
2
0.18
50
Nickel (Ni)
94
188
ug/L
2
0.256
50
Selenium (Se)
38.4
76.7
ug/L
2
0.193
50
Silver (Ag)
23.1
46.3
ug/L
2
0.035
50
Thallium (TI) Low Level
27.7
55.4
ug/L
2
0.041
50
Vanadium (V)
24.5
49
ug/L
2
0.114
50
Page 43 of 46
Parent Sample: J23100346 -- 2023026044
% Recovery
LCL
UCL
96.6
75
125
104
75
125
113
75
125
101
75
125
98.6
75
125
92.6
75
125
100
75
125
97.2
75
125
Parent Sample: J23100346 -- 2023026044
% Recovery
LCL
UCL
RPD
101
75
125
2.33
98.5
75
125
3.79
85.8
75
125
0.587
94.7
75
125
0.951
96.4
75
125
0.618
105
75
125
11.7
94.5
75
125
2.17
104
75
125
0.224
112
75
125
0.427
101
75
125
0.19
99
75
125
0.389
92.3
75
125
0.323
101
75
125
0.327
97.3
75
125
0.0905
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 44of46
This report shall not be reproduced, except in full.
Order # J23090016
Level II QC Summary
Q23100376 TDS TOTAL DISSOLVED SOLIDS
Blank # 1
Parameter Measured Final
TDS -0.3
Blank # 2
Parameter Measured Final
TDS -0.7
Duplicate # 1
Parameter Measured Final
TDS 9
Duplicate # 2
Parameter Measured Final
TDS 374
LCS # 1
LCS # 2
Parameter Measured Final
TDS 502
Parameter Measured Final
TDS 492
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
25
25
< MDL
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
25
25
< MDL
Parent Sample:
J23090016 -- 2023021783
Units
Dil
MDL
RPD
Qualifier
mg/L
1
25
28.6
R2
Parent Sample:
J23090064 -- 2023022013
Units
Dil
MDL
RPD
Qualifier
mg/L
1
25
1.62
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
25
500
100
90
110
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
25
500
98.4
90
110
Qualifiers:
R2 % RPD indeterminate due to low concentration in the parent sample.

Page 45 of 46
CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
Duke Energy Analytical Laboratory I I
� DUKE MrlCoaerwwA2 (ar°"grros) ; ;Order#J23090016
taataHesesFe yaa
�'
Anal icai uooraeo use vra
Nc_x_
Matrix WATER s.mae,eaaawr,on sc_
;
i
Page _1_ of _2_
DISTRIBUTION
ORIGINAL to LAB, COPY to CLIENT
ENERGY. HureersNae, N.C. 2907a I
(70t) $yss2u iLogged
By
Time `mil
T,
SAMPLE PROGRAM
'
'
Ean-VM_a A5sW i i
J
Ground Water X—
—
NPDES_
_•_,
:................. ._._._._._._._._.._._._._._._. _._._._.
Pianallo: iVendor
Project Name ROGERS CLIFFSIDE CCP I
/Jt 7
Drinking Water_
RCRA Waste
UST_
LANDFILL PERMIT# 81-06 �
eopki mP..LEI.._...._.._.._.._.._.._.._.._.._.._.._.._.._.._—
.._.._.._.._.._.._.._.._..
Client BILL WYLIE,RYAN CZOP, iPo
•
;
i Filtration (0.46 um)
8 Unfiltered
b Filtered
BRYAN MOELLER, DEE O'BRIEN, JOSH STOWE i
Operating Unit: CS56 Process:NGRDWTR Account: I
- Preservative
ICE
ICE
a
a_.._.._.._.._.._.._.._.._.._.._.._.._.._.._.._.._.._.._.._.._.._.._.._.._..
Project: ACS560062 Activity ID: Facility ID: CLS
Container Volume (ml-)
Soo
300
500
Program / EQuiS Task Code: CLS Sub-Program/Task Coda:
Container Type
HDPE
PET
PET
CCPILF
(Metals Prep - TRM) I
Cl, F,
C'
Be,
NO3-N
1.
Customer to
complete all appropriate non -shaded
com P PP
areas. a w
B, C ,Se, LI, MD)
(48-Hr
TDS
`o
- ---------------- Sample Description or ID
i i
Collection Information
2n (8)1 Hg (SW 7470A)
I (IMS - SW 6020B) Sb,
Hold
Time),
i SAMPLE ID i
T---oav
As, Be, Cd, Cr, Co, Cu,
SO4
_
~1°
i NUMBER i
Pb, Mo, NI, Se, Ag,
°Date
Time
Name
Si nature
TI LL V 14
2023021783
CLS_CCPM
10�1� L3
1030
nPrinted
BAW-1S LS E qA
�
x
1
1
1
3
2023021784 !
CLS_CCPMW-1D
101is j, I
IL739
ViS £HA
x
1
1
1
3
2023021785 !
CLS_CCPMW-2S
to li L3
(��S
SPl✓ .4LA
x
1
1
1
3
i
i 2023021786 !
CLS_CCPMW-2D
14 L3
i ZLS-
,
SPty •40A
X
1
1
1
3
2023021 8
� e� rw•S �
—
—
—tA-5
x
1
1
1
3
2023021788 ;
CLS_CCPMW-3D
1d I�' yQ
Io0o
CP1e-x
4
1
1
1
3
2023021789
CLS_CCPMW4
lt7�1 LJ
101(0
A'14x
1
1
1
3
2023021790
CLS_CCPMW-6
loll-$ L3
11{s-
/i/Rhx
1
1
1
3
2023021791 !
CLS _CCPMW 6S
1011$ L3
3L0
SQ1^' //}(ILlx
1
1
1
3
i 2023021792 !
CLS CCPMW 6D
I0 I� Lj
1;i0
S MAI �Lhx
1
1
1
3
i 2023021793 '!
CLS _CCPMW-7
10 I� y3
1p40
Mg
x
1
1
1
3
2023�0217994
9� s S.K 1w 1.
—
—
x
1
1
1
3
2023021795
CLS _CCPMW-10
1d r4 tl
ld4s
MEKx
1
1
1
3
2023021796
CLS_CCPMW-11
1011643
ills
S S R'
2023021797'
1./VS WL
—
—x
1
1
1
3
2023021798 ?
CLS_CCP-LEACHATE
1011 L;
1,7Lo
0r-Tx3
2023021799i
CLS CCP-LEACHATE-34
1 1x
1
1
1
3
1 �
i
Customer to sign & date be ow
Relinquished By D telfime
��` — Pam- ru' p�L3 � J�
a 0
Accepted By:
& j
/VL'
�� e
/Date/Time
5`4 � ,
u
o
Requested Turnaround
Relinquished By DatefTime
Accepted By:
L -
DatelTime
N o
c
d �
a
21 Days
14 Days X
Relinquished By DatelTime
Accepted By: Date/Time
E
o a
c
7 Days
SeaOLocked By DatelTime
Sealed/Lock Opened By Date/Time
�a
v
E
0
Other
Comments
Regulatory Agency: NCDENR/DWm - SW Section
EQUIS REQUIRED I PERMIT # 81-06
U
• Add. Cost Will Apply

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
Page 46 of 46
Duke Energy Analytical Laboratory i Analytical Laboratory Use Only
4n HuDUKE Mail Cod. MG03A2(BuddlN7406) ? !Order#J23090016 Matrix WATER ,,,,,. phie�F m NCx_
ENERGY. 13339Hager.FemrRd ! ! SC_
e mvlae, N. C. 72078 ! Logg d By ee r
(704)976du6 ! i J �� / �"� J SAMPLE PROGRAM
............................... _ _ cax:,[37w11M. 8 a _ __ _ _ ! i v Ground Water _X_ NPDES
•Project Name ROGERS CLIFFSIDE CCP — No: ;Vendor 6' Drinking Water UST_
LANDFILL PERMIT# 81-06 Cooler Te �J C
Waste
Client BILL WYLIE,RYAN CZOP, iPo °
BRYAN MOELLER, DEE O'BRIEN, JOSH STOWE i i Filtration (0.45 um) b Unfiltered
Operating Unit: C356 Process:NGRDWfR Account: ! ! Preservative ICE
Project: ACS560062 Activity ID: Facility ID: CLS Container Volume (mL) 500 300
Program 1 CLSSu EQuiS Task Code: b-ProgramrTask Code: Container Type HDPE PET
CCP I LF
(Metals Prep -TRM) I Cl, F,
Customer tocom lete all appropriate non•shaded areas. PCP -SW 6010D) Be, B, NO3-N
Pv, a Ca, Fe, Li, Mg, Mn, Zn (48-Hr
- - --- - - -: Sample Description or ID (8)1 Hg (SW 7470A)1 Hold
Collection IMonnation (IMS -SW 6020B) Sb, Time),
As, Be, Cd, Cr, Co, Cu,
i SAMPLE ID i Tn.
NUMBER i Pb, MaNi, Se, Ag, SO4Date Time Printed Name Si nature TILLV 14
( Page _2—of 2
I DISTRIBUTION-
i ORIGINAL to LAB, COPY to CLIENT
11 Filtered
ICE
S00 S00
PET HOPE
SW6010D Zn I
SW 6020E Be,9
TDS Cd, Cr, Cu, Pb,
Ni, A9
C
01
i
u
i 2023021800 i
CLS_CCPSW-1
x
t
1
1
1
4
i 2023021801 i
CLS_CCPSW-2
10 Ig�,3
OuT
��}r�.n �7a�5
x
1
1
1
1
4
2023i 0
CLS CCPSW-3
)G l� i;
oso
pa.tR/1't6
$/^S I-HAet
X
1
1
1
1
4
2023021803
CLS_FD -20L.3101$-1
(v f7 Z)
-
S3
2
x
1
1
1
3
2023021804 ':
CLS FB L4fL31n1J- 1100
:( 00
K �tS
nA A
x
1
1
2
2023021806 ;
CLS_CCR-CCPBG-1D
(0 (�
IbS-
DD
pis 014h
X
1
1
1
3
i 2023021806 I
CLS_CCR-CCPBG-1BR
1 V(
��
1140
MkS 4 to
X
1
1
1
3
i 2023021807
CLS FD - ja►L3lo (a- L
10 1
l3—
L/k
X
1
1
1
3
i
i !
r r
i !
i
�—i
Relinquished By
-�- atelTime
Accepted By:
/ "'T"
y
L3
�4j /'jECF
/
Cl(/! vV
U
9
Requested Turnaround
Relinquished By DatelTime
Accepted By: ` DatelTme
h v
21 Days
mc
�
3. 0
Relinquished By Date/Time
Accepted By: DatelTm ,
.. E
�
14 Days X
oo. L
•7 Days
SeaVLocked By DatelTime
Sealed/Lock Opened By DateTme
E 'in
._ e
:c
m
Comments
Regulatory Agency: NCDENRIDWm - SW Section
EQUIS REQUIRED I PERMIT # 81-06 Include Total Hardness
for CCPSW-1,CCPSW-2, CCPSW-3
2
1
•Other
• Add- Cost Will Apply
L)