FA-4010_29930_CA_LTRRPT_20231107

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Engineering Certification: C-2727 • Geology Certification: C-127
November 7, 2023

Mr. Ken Currie
North Carolina Department of
Environmental Quality
Division of Waste Management
UST Section
Fayetteville Regional Office
225 Green Street
Suite 714
Fayetteville, North Carolina 28301

Re: Ground Water Sampling
Nic’s Pic Kwik #9
11761 McColl Road
Laurinburg, North Carolina
Scotland County
Incident #29930
GRI Project #3706

Dear Mr. Currie;

Geological Resources, Inc. (GRI) presents the results of the ground water sampling event at the Nic’s Pic
Kwik #9 site in Laurinburg, Scotland County, North Carolina. The activities were conducted in response
to the October 6, 2023, correspondence from NCDEQ.

On October 25, 2023, two monitoring wells (MW-4R and MW-9) were gauged purged and sampled per
NCDEQ guidelines. Depths to ground water for MW-4R and MW-9 were 13.42 and 13.93 feet below the
tops of well casings, respectively. No free product was observed during the October 2023 ground water
sampling event. Ground water samples were submitted for analyses of VOCs by EPA Method 602 and
semi-VOCs + 10 highest tentatively identifiable compounds using EPA Method 625. A Site Location Map
and Site Map from the previous consultant have been included as Figures 1 and 2.

Please see the attached laboratory report for the results of the October 2023 ground water sampling
event. A concentration 2-methylnaphthalene that exceeded the Maximum Allowable Concentration as
specified in T15A NCAC 2L.0202 was reported in the ground water sample collected from MW-9. None
of the reported contaminant concentrations exceeded the GCLs. A copy of the laboratory report is
attached.

Please contact me at 704-698-1253 or [e-mail] with any questions or
comments.
Nic’s Pic Kwik #9
October 2023 Ground Water Sampling
Page 2 of 3

3502 Hayes Road • Monroe, North Carolina 28110
Phone [phone] • [phone] • Fax [phone]

Sincerely,

William Regenthal, P. G.
Project Manager
B
ECD
DRM
June 2021
11/07/23
Technical Report for
GRI (Geological Resources Inc.)
Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
3706
SGS Job Number: FC10730
Sampling Date: 10/25/23
Report to:
GRI
3502 Hayes Rd
Monroe, NC 28110
[e-mail]; [e-mail];
[e-mail]
ATTN: William Regenthal
Total number of pages in report:
Certifications: FL(E83510), LA(03051), KS(E-10327), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AL, AK, AR, CT, IA, KY, MA, MI. MS, ND, NH, NV, OK, OR, IL, UT, VT, WA, WI, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] •
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable unless noted
in the narrative, comments or footnotes.
Client Service contact: Muna Mohammed 407-425-6700
Norm Farmer
Technical Director
Orlando, FL 11/07/23
e-Hardcopy 2.0
Automated Report
37
SGS is the sole authority for authorizing edits or modifications to this document.
Unauthorized modification of this report is strictly prohibited.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions
The results set forth herein are provided by SGS North America Inc.
Please share your ideas about
how we can serve you better at:
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1 of 37
FC10730
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................5
3.1: FC10730-1: MW-4R .....................................................................................................6
3.2: FC10730-2: MW-9 ........................................................................................................10
3.3: FC10730-3: TRIP BLANK ...........................................................................................14
Section 4: Misc. Forms ............................................................................................................16
4.1: Chain of Custody ...........................................................................................................17
Section 5: MS Volatiles - QC Data Summaries .....................................................................20
5.1: Method Blank Summary ................................................................................................21
5.2: Blank Spike Summary ...................................................................................................24
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................27
Section 6: MS Semi-volatiles - QC Data Summaries ............................................................30
6.1: Method Blank Summary ................................................................................................31
6.2: Blank Spike Summary ...................................................................................................34
6.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................36 1234562 of 37
FC10730
SGS North America Inc.
Sample Summary
GRI (Geological Resources Inc.)
Job No:FC10730
Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
Project No: 3706
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
This report contains results reported as ND = Not detected. The following applies:
Organics ND = Not detected above the MDL
FC10730-1 10/25/23 11:45 WR 10/26/23 AQ Water MW-4R
FC10730-2 10/25/23 12:09 WR 10/26/23 AQ Water MW-9
FC10730-3 10/25/23 12:10 WR 10/26/23 AQ Trip Blank Water TRIP BLANK
3 of 37
FC107301
Summary of Hits Page 1 of 1
Job Number:FC10730
Account:GRI (Geological Resources Inc.)
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
Collected:10/25/23
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FC10730-1 MW-4R
Ethylbenzene 0.65 0.50 0.13 ug/l SM 6200B
Naphthalene 5.6 0.50 0.13 ug/l SM 6200B
Xylene (total)0.37 J 1.5 0.25 ug/l SM 6200B
2-Methylnaphthalene 19.5 4.9 0.59 ug/l EPA 625.1
Naphthalene 6.1 4.9 0.49 ug/l EPA 625.1
Total TIC, Semi-Volatile 182.7 J ug/l
FC10730-2 MW-9
Naphthalene 0.44 J 0.50 0.13 ug/l SM 6200B
Xylene (total)0.54 J 1.5 0.25 ug/l SM 6200B
2,4-Dimethylphenol a 80.9 26 3.8 ug/l EPA 625.1
Acenaphthene 8.4 J 26 3.2 ug/l EPA 625.1
Fluorene a 16.0 J 26 3.6 ug/l EPA 625.1
2-Methylnaphthalene 64.3 26 3.1 ug/l EPA 625.1
Total TIC, Semi-Volatile 6900 J ug/l
FC10730-3 TRIP BLANK
No hits reported in this sample.
(a) Associated BS outside control limits high.
4 of 37
FC107302
SGS North America Inc.
Sample Results
Report of Analysis
Orlando, FL
Section 3
5 of 37
FC107303
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:MW-4R
Lab Sample ID:FC10730-1 Date Sampled:10/25/23
Matrix:AQ - Water Date Received:10/26/23
Method:SM 6200B Percent Solids:n/a
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A3919.D 1 11/01/23 18:39 TD n/a n/a V3A190
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
Purgeable Aromatics, Full List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene 0.65 0.50 0.13 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene 5.6 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)0.37 1.5 0.25 ug/l J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 94%70-130%
17060-07-0 1,2-Dichloroethane-D4 108%70-130%
2037-26-5 Toluene-D8 103%70-130%
460-00-4 4-Bromofluorobenzene 104%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 of 37
FC1073033.1
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:MW-4R
Lab Sample ID:FC10730-1 Date Sampled:10/25/23
Matrix:AQ - Water Date Received:10/26/23
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 9I020481.D 1 11/02/23 10:03 KA 11/01/23 07:43 OP99835 S9I726
Run #2
Initial Volume Final Volume
Run #1 1020 ml 1.0 ml
Run #2
ABN Special List
CAS No.Compound Result RL MDL Units Q
65-85-0 Benzoic Acid ND 49 9.8 ug/l
59-50-7 4-Chloro-3-methyl Phenol ND 4.9 0.58 ug/l
95-57-8 2-Chlorophenol ND 4.9 0.62 ug/l
120-83-2 2,4-Dichlorophenol ND 4.9 0.82 ug/l
105-67-9 2,4-Dimethylphenol a ND 4.9 0.72 ug/l
51-28-5 2,4-Dinitrophenol ND 25 4.9 ug/l
534-52-1 4,6-Dinitro-o-cresol ND 9.8 2.0 ug/l
95-48-7 2-Methylphenol ND 4.9 0.55 ug/l
3&4-Methylphenol ND 4.9 0.96 ug/l
88-75-5 2-Nitrophenol ND 4.9 0.84 ug/l
100-02-7 4-Nitrophenol b ND 25 4.9 ug/l
87-86-5 Pentachlorophenol b ND 25 4.9 ug/l
108-95-2 Phenol ND 4.9 0.49 ug/l
88-06-2 2,4,6-Trichlorophenol ND 4.9 0.74 ug/l
83-32-9 Acenaphthene ND 4.9 0.61 ug/l
208-96-8 Acenaphthylene a ND 4.9 0.63 ug/l
120-12-7 Anthracene ND 4.9 0.78 ug/l
56-55-3 Benzo(a)anthracene ND 4.9 0.75 ug/l
50-32-8 Benzo(a)pyrene ND 4.9 0.77 ug/l
205-99-2 Benzo(b)fluoranthene ND 4.9 0.76 ug/l
191-24-2 Benzo(g,h,i)perylene ND 4.9 0.81 ug/l
207-08-9 Benzo(k)fluoranthene a ND 4.9 0.84 ug/l
101-55-3 4-Bromophenyl Phenyl Ether ND 4.9 0.83 ug/l
85-68-7 Butyl Benzyl Phthalate ND 4.9 0.98 ug/l
106-47-8 4-Chloroaniline ND 4.9 0.62 ug/l
111-91-1 bis(2-Chloroethoxy)methane a ND 4.9 0.79 ug/l
111-44-4 bis(2-Chloroethyl)ether ND 4.9 0.72 ug/l
108-60-1 2,2'-Oxybis(1-chloropropane)ND 4.9 0.74 ug/l
91-58-7 2-Chloronaphthalene a ND 4.9 0.49 ug/l
7005-72-3 4-Chlorophenyl Phenyl Ether a ND 4.9 0.53 ug/l
218-01-9 Chrysene ND 4.9 0.83 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 4.9 0.79 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
7 of 37
FC1073033.1
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:MW-4R
Lab Sample ID:FC10730-1 Date Sampled:10/25/23
Matrix:AQ - Water Date Received:10/26/23
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
ABN Special List
CAS No.Compound Result RL MDL Units Q
132-64-9 Dibenzofuran ND 4.9 0.59 ug/l
91-94-1 3,3'-Dichlorobenzidine ND 4.9 0.63 ug/l
84-66-2 Diethyl Phthalate ND 4.9 0.98 ug/l
131-11-3 Dimethyl Phthalate a ND 4.9 0.98 ug/l
84-74-2 Di-n-butyl Phthalate ND 4.9 0.98 ug/l
117-84-0 Di-n-octyl Phthalate ND 4.9 0.98 ug/l
121-14-2 2,4-Dinitrotoluene a ND 4.9 0.80 ug/l
606-20-2 2,6-Dinitrotoluene ND 4.9 0.70 ug/l
117-81-7 bis(2-Ethylhexyl)phthalate ND 4.9 0.98 ug/l
206-44-0 Fluoranthene a ND 4.9 0.54 ug/l
86-73-7 Fluorene a ND 4.9 0.69 ug/l
118-74-1 Hexachlorobenzene ND 4.9 0.68 ug/l
87-68-3 Hexachlorobutadiene ND 4.9 0.49 ug/l
77-47-4 Hexachlorocyclopentadiene a ND 4.9 1.8 ug/l
67-72-1 Hexachloroethane ND 4.9 1.6 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 4.9 0.70 ug/l
78-59-1 Isophorone a ND 4.9 0.76 ug/l
91-57-6 2-Methylnaphthalene 19.5 4.9 0.59 ug/l
91-20-3 Naphthalene 6.1 4.9 0.49 ug/l
98-95-3 Nitrobenzene ND 4.9 0.91 ug/l
621-64-7 N-Nitrosodi-n-propylamine ND 4.9 0.66 ug/l
86-30-6 N-Nitrosodiphenylamine ND 4.9 0.79 ug/l
85-01-8 Phenanthrene ND 4.9 0.85 ug/l
129-00-0 Pyrene ND 4.9 0.67 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
367-12-4 2-Fluorophenol 34%14-67%
4165-62-2 Phenol-d5 22%10-50%
118-79-6 2,4,6-Tribromophenol 106%33-118%
4165-60-0 Nitrobenzene-d5 99%42-108%
321-60-8 2-Fluorobiphenyl 92%40-106%
1718-51-0 Terphenyl-d14 81%39-121%
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
75-85-4 Amylene Hydrate 2.31 22 ug/l JN
103-65-1 Benzene, propyl-5.49 8.6 ug/l JN
141-93-5 Benzene, 1,3-diethyl-6.33 8.4 ug/l JN
527-84-4 Benzene, 1-methyl-2-(1-methylethyl)-6.95 13 ug/l JN
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
8 of 37
FC1073033.1
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:MW-4R
Lab Sample ID:FC10730-1 Date Sampled:10/25/23
Matrix:AQ - Water Date Received:10/26/23
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
ABN Special List
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
3333-13-9 Benzene, 1-methyl-4-(2-propenyl)-7.12 9.3 ug/l JN
119-64-2 Naphthalene, 1,2,3,4-tetrahydro-7.31 22 ug/l JN
1559-81-5 Naphthalene, 1,2,3,4-tetrahydro-1-methyl 7.78 5.8 ug/l JN
98-51-1 4-tert-Butyltoluene 7.81 8 ug/l JN
2809-64-5 Naphthalene, 1,2,3,4-tetrahydro-5-8.08 9.1 ug/l JN
2809-64-5 Naphthalene, 1,2,3,4-tetrahydro-5-methyl 8.27 13 ug/l JN
26465-81-6 1H-Inden-1-one, 2,3-dihydro-3,3-dimethyl 8.61 7 ug/l JN
1000201-99-67-Methylindan-1-one 8.66 5.7 ug/l JN
1127-76-0 Naphthalene, 1-ethyl-8.98 6.2 ug/l JN
575-43-9 Naphthalene, 1,6-dimethyl-9.06 9.5 ug/l JN
581-42-0 Naphthalene, 2,6-dimethyl-9.14 17 ug/l JN
16526-90-2 cis-Bicyclo[5.1.0]octane 9.32 7.1 ug/l JN
1076-22-8 1H-Purine-2,6-dione, 3,7-dihydro-3-methy 9.95 11 ug/l JN
Total TIC, Semi-Volatile 182.7 ug/l J
(a) Associated BS outside control limits high, sample was ND.
(b) Associated CCV outside of control limits high, sample was ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
9 of 37
FC1073033.1
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:MW-9
Lab Sample ID:FC10730-2 Date Sampled:10/25/23
Matrix:AQ - Water Date Received:10/26/23
Method:SM 6200B Percent Solids:n/a
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A3920.D 1 11/01/23 19:03 TD n/a n/a V3A190
Run #2 a 3A3884.D 10 11/01/23 04:21 TD n/a n/a V3A189
Purge Volume
Run #1 5.0 ml
Run #2 5.0 ml
Purgeable Aromatics, Full List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene 0.44 0.50 0.13 ug/l J
108-88-3 Toluene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)0.54 1.5 0.25 ug/l J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 95%94%70-130%
17060-07-0 1,2-Dichloroethane-D4 108%107%70-130%
2037-26-5 Toluene-D8 103%104%70-130%
460-00-4 4-Bromofluorobenzene 109%103%70-130%
(a) Confirmation run.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
10 of 37
FC1073033.2
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:MW-9
Lab Sample ID:FC10730-2 Date Sampled:10/25/23
Matrix:AQ - Water Date Received:10/26/23
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 9I020487.D 5 11/02/23 12:35 KA 11/01/23 07:43 OP99835 S9I726
Run #2 a 9I020482.D 1 11/02/23 10:28 KA 11/01/23 07:43 OP99835 S9I726
Initial Volume Final Volume
Run #1 980 ml 1.0 ml
Run #2 980 ml 1.0 ml
ABN Special List
CAS No.Compound Result RL MDL Units Q
65-85-0 Benzoic Acid ND 260 51 ug/l
59-50-7 4-Chloro-3-methyl Phenol ND 26 3.0 ug/l
95-57-8 2-Chlorophenol ND 26 3.2 ug/l
120-83-2 2,4-Dichlorophenol ND 26 4.3 ug/l
105-67-9 2,4-Dimethylphenol b 80.9 26 3.8 ug/l
51-28-5 2,4-Dinitrophenol ND 130 26 ug/l
534-52-1 4,6-Dinitro-o-cresol ND 51 10 ug/l
95-48-7 2-Methylphenol ND 26 2.8 ug/l
3&4-Methylphenol ND 26 5.0 ug/l
88-75-5 2-Nitrophenol ND 26 4.3 ug/l
100-02-7 4-Nitrophenol c ND 130 26 ug/l
87-86-5 Pentachlorophenol c ND 130 26 ug/l
108-95-2 Phenol ND 26 2.6 ug/l
88-06-2 2,4,6-Trichlorophenol ND 26 3.8 ug/l
83-32-9 Acenaphthene 8.4 26 3.2 ug/l J
208-96-8 Acenaphthylene d ND 26 3.3 ug/l
120-12-7 Anthracene ND 26 4.1 ug/l
56-55-3 Benzo(a)anthracene ND 26 3.9 ug/l
50-32-8 Benzo(a)pyrene ND 26 4.0 ug/l
205-99-2 Benzo(b)fluoranthene ND 26 4.0 ug/l
191-24-2 Benzo(g,h,i)perylene ND 26 4.2 ug/l
207-08-9 Benzo(k)fluoranthene d ND 26 4.4 ug/l
101-55-3 4-Bromophenyl Phenyl Ether ND 26 4.3 ug/l
85-68-7 Butyl Benzyl Phthalate ND 26 5.1 ug/l
106-47-8 4-Chloroaniline ND 26 3.2 ug/l
111-91-1 bis(2-Chloroethoxy)methane d ND 26 4.1 ug/l
111-44-4 bis(2-Chloroethyl)ether ND 26 3.7 ug/l
108-60-1 2,2'-Oxybis(1-chloropropane)ND 26 3.9 ug/l
91-58-7 2-Chloronaphthalene d ND 26 2.6 ug/l
7005-72-3 4-Chlorophenyl Phenyl Ether d ND 26 2.7 ug/l
218-01-9 Chrysene ND 26 4.3 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 26 4.1 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
11 of 37
FC1073033.2
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:MW-9
Lab Sample ID:FC10730-2 Date Sampled:10/25/23
Matrix:AQ - Water Date Received:10/26/23
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
ABN Special List
CAS No.Compound Result RL MDL Units Q
132-64-9 Dibenzofuran ND 26 3.1 ug/l
91-94-1 3,3'-Dichlorobenzidine ND 26 3.3 ug/l
84-66-2 Diethyl Phthalate d ND 26 5.1 ug/l
131-11-3 Dimethyl Phthalate ND 26 5.1 ug/l
84-74-2 Di-n-butyl Phthalate ND 26 5.1 ug/l
117-84-0 Di-n-octyl Phthalate ND 26 5.1 ug/l
121-14-2 2,4-Dinitrotoluene d ND 26 4.1 ug/l
606-20-2 2,6-Dinitrotoluene ND 26 3.6 ug/l
117-81-7 bis(2-Ethylhexyl)phthalate ND 26 5.1 ug/l
206-44-0 Fluoranthene d ND 26 2.8 ug/l
86-73-7 Fluorene b 16.0 26 3.6 ug/l J
118-74-1 Hexachlorobenzene ND 26 3.5 ug/l
87-68-3 Hexachlorobutadiene ND 26 2.6 ug/l
77-47-4 Hexachlorocyclopentadiene d ND 26 9.2 ug/l
67-72-1 Hexachloroethane ND 26 8.4 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 26 3.6 ug/l
78-59-1 Isophorone d ND 26 4.0 ug/l
91-57-6 2-Methylnaphthalene 64.3 26 3.1 ug/l
91-20-3 Naphthalene ND 26 2.6 ug/l
98-95-3 Nitrobenzene ND 26 4.8 ug/l
621-64-7 N-Nitrosodi-n-propylamine ND 26 3.4 ug/l
86-30-6 N-Nitrosodiphenylamine ND 26 4.1 ug/l
85-01-8 Phenanthrene ND 26 4.4 ug/l
129-00-0 Pyrene ND 26 3.5 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
367-12-4 2-Fluorophenol 29%19%14-67%
4165-62-2 Phenol-d5 18%19%10-50%
118-79-6 2,4,6-Tribromophenol 130% e 115%33-118%
4165-60-0 Nitrobenzene-d5 323% e 324%42-108%
321-60-8 2-Fluorobiphenyl 141% e 124%40-106%
1718-51-0 Terphenyl-d14 110%92%39-121%
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
2051-30-1 Octane, 2,6-dimethyl-5.28 220 ug/l JN
17301-94-9 Nonane, 4-methyl-5.54 150 ug/l JN
1072-16-8 Octane, 2,7-dimethyl-5.57 240 ug/l JN
4291-79-6 Cyclohexane, 1-methyl-2-propyl-5.80 220 ug/l JN
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
12 of 37
FC1073033.2
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:MW-9
Lab Sample ID:FC10730-2 Date Sampled:10/25/23
Matrix:AQ - Water Date Received:10/26/23
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
ABN Special List
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
124-18-5 Decane 5.91 750 ug/l JN
1678-98-4 Cyclohexane, (2-methylpropyl)-6.24 340 ug/l JN
13151-34-3 Decane, 3-methyl-6.34 170 ug/l JN
13151-35-4 Decane, 5-methyl-6.39 230 ug/l JN
105-05-5 Benzene, 1,4-diethyl-6.43 190 ug/l JN
6975-98-0 Decane, 2-methyl-6.46 250 ug/l JN
1074-17-5 Benzene, 1-methyl-2-propyl-6.51 480 ug/l JN
1120-21-4 Undecane 6.79 1100 ug/l JN
95-93-2 Benzene, 1,2,4,5-tetramethyl-6.97 150 ug/l JN
17312-55-9 Decane, 3,8-dimethyl-7.27 150 ug/l JN
17312-55-9 Decane, 3,8-dimethyl-7.31 160 ug/l JN
629-50-5 Tridecane 8.28 220 ug/l JN
629-59-4 Tetradecane 8.95 260 ug/l JN
629-78-7 Heptadecane 10.70 1200 ug/l JN
593-45-3 Octadecane 11.23 270 ug/l JN
629-92-5 Nonadecane 11.74 150 ug/l JN
Total TIC, Semi-Volatile 6900 ug/l J
(a) Confirmation run.
(b) Associated BS outside control limits high.
(c) Associated CCV outside of control limits high, sample was ND.
(d) Associated BS outside control limits high, sample was ND.
(e) Outside control limits due to matrix interference.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
13 of 37
FC1073033.2
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:TRIP BLANK
Lab Sample ID:FC10730-3 Date Sampled:10/25/23
Matrix:AQ - Trip Blank Water Date Received:10/26/23
Method:SM 6200B Percent Solids:n/a
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A3966.D 1 11/02/23 13:42 TD n/a n/a V3A192
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
14 of 37
FC1073033.3
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:TRIP BLANK
Lab Sample ID:FC10730-3 Date Sampled:10/25/23
Matrix:AQ - Trip Blank Water Date Received:10/26/23
Method:SM 6200B Percent Solids:n/a
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 93%70-130%
17060-07-0 1,2-Dichloroethane-D4 105%70-130%
2037-26-5 Toluene-D8 103%70-130%
460-00-4 4-Bromofluorobenzene 102%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
15 of 37
FC1073033.3
SGS North America Inc.
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Orlando, FL
Section 4
16 of 37
FC107304
FC10730: Chain of Custody
Page 1 of 3
17 of 37
FC1073044.1
Job Number:fc10730 Client:6RI
Date / Time Received:10/26/2023 9:30:00 AM Delivery Method:FED EX
Project:3706
Airbill #'s:684033199536
Cooler Information
1. Custody Seals Present:
Y or N
2. Custody Seals Intact:
4. Cooler temp verification:
3. Temp criteria achieved:
5. Cooler media:
IR Gun
Ice (Bag)
Trip Blank Information Y or N N/A
1. Trip Blank present / cooler:
2. Trip Blank listed on COC:
Sample Information
1. Sample labels present on bottles:
2. Samples presented properly
3. Suffiient volume/containers recv'd for analysis
4. Condition of sample:
5. Sample recv'd within HT
6. Dates/Times/IDs on COC match sample label
7. VOCs have headspace
8. Bottles received for unspecified tests
9. Compositing instructions clear
10. Voa Soil Kits/Jars received past 48hrs?
Intact
Comments
Cooler Temps (Raw Measured) °C:
Cooler Temps (Corrected) °C:
Cooler 1: (2.2);
Cooler 1: (2.6);
SM001Rev. Date 05/04/17
SGS Sample Receipt Summary
Test Strip Lot #s:pH 0-3:226422 pH 10-12:Other: (Specify)pH 1.0 - 12.0 222221
3. Type of TB Received
W or S N/A
Y or N N/A
11. % Solids Jar Received?
12. Residual Chlorine Present?
Misc Information
Number of Encores:25 Gram 5 Gram
Residual Chlorine Test Strip Lot #
Number of Lab Filtered Metals:
Technician:ZANEB Date:10/26/2023 1:49:59 PM Reviewer:Date:
FC10730: Chain of Custody
Page 2 of 3
18 of 37
FC1073044.1
TAT (Days):7
Received Date:10/26/2023
Due Date:10/26/2023
Project Description:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, N
Account Name:GRI (Geological Resources Inc.)
Deliverable:COMMB
Requested Date:10/26/2023
Job Change Order:FC10730
PM:MMOC/O Initiated By:MUNA_MOH
Sample #:FC10730-ALL
Change:Per client the sample collection time is incorrect. Samples were collected on 10/25/23.
Dept:LOGIN
=========================================================================================================================
Client ID:TAT:7
Above Changes Per:
To Client: This Change Order is confirmation of the revisions, previously discussed with the Client Service Representative.
Date/Time:10/26/2023
Page 1 of 1
William Regenthal
FC10730: Chain of Custody
Page 3 of 3
19 of 37
FC1073044.1
SGS North America Inc.
MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 5
20 of 37
FC107305
Method Blank Summary Page 1 of 1
Job Number:FC10730
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A190-MB 3A3904.D 1 11/01/23 TD n/a n/a V3A190
The QC reported here applies to the following samples:Method: SM 6200B
FC10730-1, FC10730-2
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 92%70-130%
17060-07-0 1,2-Dichloroethane-D4 104%70-130%
2037-26-5 Toluene-D8 103%70-130%
460-00-4 4-Bromofluorobenzene 102%70-130%
21 of 37
FC1073055.1.1
Method Blank Summary Page 1 of 2
Job Number:FC10730
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A192-MB 3A3957.D 1 11/02/23 TD n/a n/a V3A192
The QC reported here applies to the following samples:Method: SM 6200B
FC10730-3
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
22 of 37
FC1073055.1.2
Method Blank Summary Page 2 of 2
Job Number:FC10730
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A192-MB 3A3957.D 1 11/02/23 TD n/a n/a V3A192
The QC reported here applies to the following samples:Method: SM 6200B
FC10730-3
CAS No.Compound Result RL MDL Units Q
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride 1.5 2.0 1.0 ug/l J
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 94%70-130%
17060-07-0 1,2-Dichloroethane-D4 104%70-130%
2037-26-5 Toluene-D8 103%70-130%
460-00-4 4-Bromofluorobenzene 103%70-130%
23 of 37
FC1073055.1.2
Blank Spike Summary Page 1 of 1
Job Number:FC10730
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A190-BS 3A3902.D 1 11/01/23 TD n/a n/a V3A190
The QC reported here applies to the following samples:Method: SM 6200B
FC10730-1, FC10730-2
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 9.0 90 70-130
108-90-7 Chlorobenzene 10 9.3 93 70-130
95-50-1 1,2-Dichlorobenzene 10 9.3 93 70-130
541-73-1 1,3-Dichlorobenzene 10 9.2 92 70-130
106-46-7 1,4-Dichlorobenzene 10 9.3 93 70-130
108-20-3 Di-Isopropyl Ether 10 10.5 105 70-130
100-41-4 Ethylbenzene 10 9.5 95 70-130
1634-04-4 Methyl Tert Butyl Ether 10 9.6 96 70-130
91-20-3 Naphthalene 10 9.0 90 70-130
108-88-3 Toluene 10 9.4 94 70-130
1330-20-7 Xylene (total)30 28.6 95 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 96%70-130%
17060-07-0 1,2-Dichloroethane-D4 104%70-130%
2037-26-5 Toluene-D8 105%70-130%
460-00-4 4-Bromofluorobenzene 105%70-130%
* = Outside of Control Limits.
24 of 37
FC1073055.2.1
Blank Spike Summary Page 1 of 2
Job Number:FC10730
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A192-BS 3A3955.D 1 11/02/23 TD n/a n/a V3A192
The QC reported here applies to the following samples:Method: SM 6200B
FC10730-3
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 9.0 90 70-130
108-86-1 Bromobenzene 10 9.6 96 70-130
74-97-5 Bromochloromethane 10 8.7 87 70-130
75-27-4 Bromodichloromethane 10 8.4 84 70-130
75-25-2 Bromoform 10 9.2 92 70-130
104-51-8 n-Butylbenzene 10 9.9 99 70-130
135-98-8 sec-Butylbenzene 10 9.1 91 70-130
98-06-6 tert-Butylbenzene 10 9.2 92 70-130
56-23-5 Carbon Tetrachloride 10 9.4 94 70-130
108-90-7 Chlorobenzene 10 9.2 92 70-130
75-00-3 Chloroethane 10 8.6 86 60-140
67-66-3 Chloroform 10 8.6 86 70-130
95-49-8 o-Chlorotoluene 10 9.7 97 70-130
106-43-4 p-Chlorotoluene 10 9.8 98 70-130
124-48-1 Dibromochloromethane 10 9.6 96 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 9.5 95 70-130
106-93-4 1,2-Dibromoethane 10 8.7 87 70-130
75-71-8 Dichlorodifluoromethane 10 9.6 96 60-140
95-50-1 1,2-Dichlorobenzene 10 9.5 95 70-130
541-73-1 1,3-Dichlorobenzene 10 9.3 93 70-130
106-46-7 1,4-Dichlorobenzene 10 9.2 92 70-130
75-34-3 1,1-Dichloroethane 10 8.6 86 70-130
107-06-2 1,2-Dichloroethane 10 9.0 90 70-130
75-35-4 1,1-Dichloroethylene 10 8.1 81 70-130
156-59-2 cis-1,2-Dichloroethylene 10 8.7 87 70-130
156-60-5 trans-1,2-Dichloroethylene 10 8.8 88 70-130
78-87-5 1,2-Dichloropropane 10 9.9 99 70-130
142-28-9 1,3-Dichloropropane 10 10.5 105 70-130
594-20-7 2,2-Dichloropropane 10 9.4 94 70-130
563-58-6 1,1-Dichloropropene 10 8.9 89 70-130
10061-01-5 cis-1,3-Dichloropropene 10 9.0 90 70-130
10061-02-6 trans-1,3-Dichloropropene 10 8.8 88 70-130
108-20-3 Di-Isopropyl Ether 10 10.9 109 70-130
100-41-4 Ethylbenzene 10 9.4 94 70-130
87-68-3 Hexachlorobutadiene 10 9.0 90 70-130
98-82-8 Isopropylbenzene 10 8.9 89 70-130
* = Outside of Control Limits.
25 of 37
FC1073055.2.2
Blank Spike Summary Page 2 of 2
Job Number:FC10730
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A192-BS 3A3955.D 1 11/02/23 TD n/a n/a V3A192
The QC reported here applies to the following samples:Method: SM 6200B
FC10730-3
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
99-87-6 p-Isopropyltoluene 10 9.2 92 70-130
74-83-9 Methyl Bromide 10 7.2 72 60-140
74-87-3 Methyl Chloride 10 11.2 112 60-140
74-95-3 Methylene Bromide 10 8.9 89 70-130
75-09-2 Methylene Chloride 10 11.0 110 70-130
1634-04-4 Methyl Tert Butyl Ether 10 9.4 94 70-130
91-20-3 Naphthalene 10 8.9 89 70-130
103-65-1 n-Propylbenzene 10 9.9 99 70-130
100-42-5 Styrene 10 8.7 87 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 8.9 89 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 9.4 94 70-130
127-18-4 Tetrachloroethylene 10 8.8 88 70-130
108-88-3 Toluene 10 9.3 93 70-130
87-61-6 1,2,3-Trichlorobenzene 10 9.3 93 70-130
120-82-1 1,2,4-Trichlorobenzene 10 9.5 95 70-130
71-55-6 1,1,1-Trichloroethane 10 8.7 87 70-130
79-00-5 1,1,2-Trichloroethane 10 9.6 96 70-130
79-01-6 Trichloroethylene 10 8.4 84 70-130
75-69-4 Trichlorofluoromethane 10 8.1 81 60-140
96-18-4 1,2,3-Trichloropropane 10 10.1 101 70-130
95-63-6 1,2,4-Trimethylbenzene 10 9.3 93 70-130
108-67-8 1,3,5-Trimethylbenzene 10 9.2 92 70-130
75-01-4 Vinyl Chloride 10 9.9 99 60-140
m,p-Xylene 20 19.4 97 70-130
95-47-6 o-Xylene 10 8.9 89 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 94%70-130%
17060-07-0 1,2-Dichloroethane-D4 101%70-130%
2037-26-5 Toluene-D8 103%70-130%
460-00-4 4-Bromofluorobenzene 103%70-130%
* = Outside of Control Limits.
26 of 37
FC1073055.2.2
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1
Job Number:FC10730
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC10736-8MS 3A3923.D 5 11/01/23 TD n/a n/a V3A190
FC10736-8MSD 3A3924.D 5 11/01/23 TD n/a n/a V3A190
FC10736-8 3A3915.D 1 11/01/23 TD n/a n/a V3A190
The QC reported here applies to the following samples:Method: SM 6200B
FC10730-1, FC10730-2
FC10736-8 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene ND 50 41.4 83 50 40.9 82 1 70-130/20
108-90-7 Chlorobenzene ND 50 41.3 83 50 40.6 81 2 70-130/20
95-50-1 1,2-Dichlorobenzene ND 50 41.1 82 50 40.2 80 2 70-130/20
541-73-1 1,3-Dichlorobenzene ND 50 40.2 80 50 40.3 81 0 70-130/20
106-46-7 1,4-Dichlorobenzene ND 50 40.2 80 50 40.1 80 0 70-130/20
108-20-3 Di-Isopropyl Ether ND 50 46.3 93 50 45.8 92 1 70-130/20
100-41-4 Ethylbenzene 0.45 J 50 43.6 86 50 42.9 85 2 70-130/20
1634-04-4 Methyl Tert Butyl Ether ND 50 41.4 83 50 41.1 82 1 70-130/20
91-20-3 Naphthalene 0.14 J 50 36.2 72 50 32.0 64*12 70-130/20
108-88-3 Toluene ND 50 43.1 86 50 42.6 85 1 70-130/20
1330-20-7 Xylene (total)2.1 150 132 87 150 129 85 2 70-130/20
CAS No.Surrogate Recoveries MS MSD FC10736-8 Limits
1868-53-7 Dibromofluoromethane 94%96%93%70-130%
17060-07-0 1,2-Dichloroethane-D4 104%105%105%70-130%
2037-26-5 Toluene-D8 103%103%105%70-130%
460-00-4 4-Bromofluorobenzene 105%106%106%70-130%
* = Outside of Control Limits.
27 of 37
FC1073055.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FC10730
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC10726-2MS 3A3978.D 5 11/02/23 TD n/a n/a V3A192
FC10726-2MSD 3A3979.D 5 11/02/23 TD n/a n/a V3A192
FC10726-2 3A3967.D 1 11/02/23 TD n/a n/a V3A192
The QC reported here applies to the following samples:Method: SM 6200B
FC10730-3
FC10726-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene ND 50 39.3 79 50 41.3 83 5 70-130/20
108-86-1 Bromobenzene ND 50 39.9 80 50 42.1 84 5 70-130/20
74-97-5 Bromochloromethane ND 50 35.6 71 50 38.1 76 7 70-130/20
75-27-4 Bromodichloromethane ND 50 32.7 65*50 35.6 71 8 70-130/20
75-25-2 Bromoform ND 50 33.0 66*50 37.2 74 12 70-130/20
104-51-8 n-Butylbenzene ND 50 41.4 83 50 43.6 87 5 70-130/20
135-98-8 sec-Butylbenzene ND 50 39.6 79 50 40.9 82 3 70-130/20
98-06-6 tert-Butylbenzene ND 50 39.8 80 50 41.4 83 4 70-130/20
56-23-5 Carbon Tetrachloride ND 50 40.6 81 50 43.9 88 8 70-130/20
108-90-7 Chlorobenzene ND 50 38.8 78 50 41.6 83 7 70-130/20
75-00-3 Chloroethane ND 50 38.4 77 50 36.3 73 6 60-140/20
67-66-3 Chloroform ND 50 37.0 74 50 39.7 79 7 70-130/20
95-49-8 o-Chlorotoluene ND 50 41.7 83 50 43.6 87 4 70-130/20
106-43-4 p-Chlorotoluene ND 50 40.8 82 50 43.3 87 6 70-130/20
124-48-1 Dibromochloromethane ND 50 34.9 70 50 38.7 77 10 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 50 35.1 70 50 38.2 76 8 70-130/20
106-93-4 1,2-Dibromoethane ND 50 33.8 68*50 36.7 73 8 70-130/20
75-71-8 Dichlorodifluoromethane ND 50 46.7 93 50 43.3 87 8 60-140/20
95-50-1 1,2-Dichlorobenzene ND 50 38.8 78 50 40.8 82 5 70-130/20
541-73-1 1,3-Dichlorobenzene ND 50 38.4 77 50 40.5 81 5 70-130/20
106-46-7 1,4-Dichlorobenzene ND 50 38.2 76 50 40.6 81 6 70-130/20
75-34-3 1,1-Dichloroethane ND 50 37.3 75 50 39.6 79 6 70-130/20
107-06-2 1,2-Dichloroethane ND 50 37.2 74 50 39.6 79 6 70-130/20
75-35-4 1,1-Dichloroethylene ND 50 37.1 74 50 38.8 78 4 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 50 36.6 73 50 38.8 78 6 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 50 38.6 77 50 41.1 82 6 70-130/20
78-87-5 1,2-Dichloropropane ND 50 41.5 83 50 43.9 88 6 70-130/20
142-28-9 1,3-Dichloropropane ND 50 41.3 83 50 44.8 90 8 70-130/20
594-20-7 2,2-Dichloropropane ND 50 40.2 80 50 43.6 87 8 70-130/20
563-58-6 1,1-Dichloropropene ND 50 40.2 80 50 42.4 85 5 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 50 34.3 69*50 36.8 74 7 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 50 33.1 66*50 36.2 72 9 70-130/20
108-20-3 Di-Isopropyl Ether ND 50 45.5 91 50 48.4 97 6 70-130/20
100-41-4 Ethylbenzene ND 50 40.6 81 50 42.4 85 4 70-130/20
87-68-3 Hexachlorobutadiene ND 50 37.6 75 50 37.2 74 1 70-130/20
98-82-8 Isopropylbenzene ND 50 38.3 77 50 40.8 82 6 70-130/20
* = Outside of Control Limits.
28 of 37
FC1073055.3.2
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FC10730
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC10726-2MS 3A3978.D 5 11/02/23 TD n/a n/a V3A192
FC10726-2MSD 3A3979.D 5 11/02/23 TD n/a n/a V3A192
FC10726-2 3A3967.D 1 11/02/23 TD n/a n/a V3A192
The QC reported here applies to the following samples:Method: SM 6200B
FC10730-3
FC10726-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
99-87-6 p-Isopropyltoluene ND 50 39.1 78 50 40.5 81 4 70-130/20
74-83-9 Methyl Bromide ND 50 27.8 56*50 30.4 61 9 60-140/20
74-87-3 Methyl Chloride ND 50 50.7 101 50 48.5 97 4 60-140/20
74-95-3 Methylene Bromide ND 50 36.4 73 50 39.2 78 7 70-130/20
75-09-2 Methylene Chloride ND 50 51.6 103 50 58.0 116 12 70-130/20
1634-04-4 Methyl Tert Butyl Ether 1.5 50 39.8 77 50 42.4 82 6 70-130/20
91-20-3 Naphthalene ND 50 34.6 69*50 36.1 72 4 70-130/20
103-65-1 n-Propylbenzene ND 50 42.6 85 50 44.8 90 5 70-130/20
100-42-5 Styrene ND 50 34.8 70 50 37.5 75 7 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 50 35.0 70 50 38.1 76 8 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 50 37.8 76 50 40.6 81 7 70-130/20
127-18-4 Tetrachloroethylene ND 50 39.7 79 50 41.1 82 3 70-130/20
108-88-3 Toluene ND 50 40.9 82 50 42.7 85 4 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 50 36.9 74 50 39.4 79 7 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 50 37.8 76 50 39.5 79 4 70-130/20
71-55-6 1,1,1-Trichloroethane ND 50 38.6 77 50 40.7 81 5 70-130/20
79-00-5 1,1,2-Trichloroethane ND 50 39.0 78 50 41.2 82 5 70-130/20
79-01-6 Trichloroethylene ND 50 36.8 74 50 38.5 77 5 70-130/20
75-69-4 Trichlorofluoromethane ND 50 37.9 76 50 35.8 72 6 60-140/20
96-18-4 1,2,3-Trichloropropane ND 50 40.2 80 50 43.7 87 8 70-130/20
95-63-6 1,2,4-Trimethylbenzene ND 50 39.8 80 50 41.6 83 4 70-130/20
108-67-8 1,3,5-Trimethylbenzene ND 50 39.9 80 50 41.4 83 4 70-130/20
75-01-4 Vinyl Chloride ND 50 46.2 92 50 44.3 89 4 60-140/20
m,p-Xylene ND 100 83.2 83 100 88.0 88 6 70-130/20
95-47-6 o-Xylene ND 50 37.4 75 50 39.4 79 5 70-130/20
CAS No.Surrogate Recoveries MS MSD FC10726-2 Limits
1868-53-7 Dibromofluoromethane 95%96%94%70-130%
17060-07-0 1,2-Dichloroethane-D4 105%103%104%70-130%
2037-26-5 Toluene-D8 102%102%102%70-130%
460-00-4 4-Bromofluorobenzene 104%102%103%70-130%
* = Outside of Control Limits.
29 of 37
FC1073055.3.2
SGS North America Inc.
MS Semi-volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 6
30 of 37
FC107306
Method Blank Summary Page 1 of 3
Job Number:FC10730
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP99835-MB 9I020480.D 1 11/02/23 KA 11/01/23 OP99835 S9I726
The QC reported here applies to the following samples:Method: EPA 625.1
FC10730-1, FC10730-2
CAS No.Compound Result RL MDL Units Q
65-85-0 Benzoic Acid ND 50 10 ug/l
59-50-7 4-Chloro-3-methyl Phenol ND 5.0 0.59 ug/l
95-57-8 2-Chlorophenol ND 5.0 0.63 ug/l
120-83-2 2,4-Dichlorophenol ND 5.0 0.84 ug/l
105-67-9 2,4-Dimethylphenol ND 5.0 0.74 ug/l
51-28-5 2,4-Dinitrophenol ND 25 5.0 ug/l
534-52-1 4,6-Dinitro-o-cresol ND 10 2.0 ug/l
95-48-7 2-Methylphenol ND 5.0 0.56 ug/l
3&4-Methylphenol ND 5.0 0.98 ug/l
88-75-5 2-Nitrophenol ND 5.0 0.85 ug/l
100-02-7 4-Nitrophenol ND 25 5.0 ug/l
87-86-5 Pentachlorophenol ND 25 5.0 ug/l
108-95-2 Phenol ND 5.0 0.50 ug/l
88-06-2 2,4,6-Trichlorophenol ND 5.0 0.75 ug/l
83-32-9 Acenaphthene ND 5.0 0.63 ug/l
208-96-8 Acenaphthylene ND 5.0 0.64 ug/l
120-12-7 Anthracene ND 5.0 0.80 ug/l
56-55-3 Benzo(a)anthracene ND 5.0 0.76 ug/l
50-32-8 Benzo(a)pyrene ND 5.0 0.78 ug/l
205-99-2 Benzo(b)fluoranthene ND 5.0 0.78 ug/l
191-24-2 Benzo(g,h,i)perylene ND 5.0 0.82 ug/l
207-08-9 Benzo(k)fluoranthene ND 5.0 0.86 ug/l
101-55-3 4-Bromophenyl Phenyl Ether ND 5.0 0.85 ug/l
85-68-7 Butyl Benzyl Phthalate ND 5.0 1.0 ug/l
106-47-8 4-Chloroaniline ND 5.0 0.63 ug/l
111-91-1 bis(2-Chloroethoxy)methane ND 5.0 0.81 ug/l
111-44-4 bis(2-Chloroethyl)ether ND 5.0 0.73 ug/l
108-60-1 2,2'-Oxybis(1-chloropropane)ND 5.0 0.76 ug/l
91-58-7 2-Chloronaphthalene ND 5.0 0.50 ug/l
7005-72-3 4-Chlorophenyl Phenyl Ether ND 5.0 0.54 ug/l
218-01-9 Chrysene ND 5.0 0.85 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 5.0 0.80 ug/l
132-64-9 Dibenzofuran ND 5.0 0.60 ug/l
91-94-1 3,3'-Dichlorobenzidine ND 5.0 0.64 ug/l
84-66-2 Diethyl Phthalate ND 5.0 1.0 ug/l
131-11-3 Dimethyl Phthalate ND 5.0 1.0 ug/l
31 of 37
FC1073066.1.1
Method Blank Summary Page 2 of 3
Job Number:FC10730
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP99835-MB 9I020480.D 1 11/02/23 KA 11/01/23 OP99835 S9I726
The QC reported here applies to the following samples:Method: EPA 625.1
FC10730-1, FC10730-2
CAS No.Compound Result RL MDL Units Q
84-74-2 Di-n-butyl Phthalate ND 5.0 1.0 ug/l
117-84-0 Di-n-octyl Phthalate ND 5.0 1.0 ug/l
121-14-2 2,4-Dinitrotoluene ND 5.0 0.81 ug/l
606-20-2 2,6-Dinitrotoluene ND 5.0 0.71 ug/l
117-81-7 bis(2-Ethylhexyl)phthalate ND 5.0 1.0 ug/l
206-44-0 Fluoranthene ND 5.0 0.55 ug/l
86-73-7 Fluorene ND 5.0 0.70 ug/l
118-74-1 Hexachlorobenzene ND 5.0 0.69 ug/l
87-68-3 Hexachlorobutadiene ND 5.0 0.50 ug/l
77-47-4 Hexachlorocyclopentadiene ND 5.0 1.8 ug/l
67-72-1 Hexachloroethane ND 5.0 1.6 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 5.0 0.71 ug/l
78-59-1 Isophorone ND 5.0 0.78 ug/l
91-57-6 2-Methylnaphthalene ND 5.0 0.60 ug/l
91-20-3 Naphthalene ND 5.0 0.50 ug/l
98-95-3 Nitrobenzene ND 5.0 0.93 ug/l
621-64-7 N-Nitrosodi-n-propylamine ND 5.0 0.67 ug/l
86-30-6 N-Nitrosodiphenylamine ND 5.0 0.81 ug/l
85-01-8 Phenanthrene ND 5.0 0.86 ug/l
129-00-0 Pyrene ND 5.0 0.68 ug/l
CAS No.Surrogate Recoveries Limits
367-12-4 2-Fluorophenol 53%14-67%
4165-62-2 Phenol-d5 39%10-50%
118-79-6 2,4,6-Tribromophenol 110%33-118%
4165-60-0 Nitrobenzene-d5 95%42-108%
321-60-8 2-Fluorobiphenyl 92%40-106%
1718-51-0 Terphenyl-d14 113%39-121%
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
75-85-4 Amylene Hydrate 2.31 43 ug/l JN
107-86-8 2-Butenal, 3-methyl-5.12 4.5 ug/l JN
32 of 37
FC1073066.1.1
Method Blank Summary Page 3 of 3
Job Number:FC10730
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP99835-MB 9I020480.D 1 11/02/23 KA 11/01/23 OP99835 S9I726
The QC reported here applies to the following samples:Method:
FC10730-1, FC10730-2
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
Total TIC, Semi-Volatile 47.5 ug/l J
33 of 37
FC1073066.1.1
Blank Spike Summary Page 1 of 2
Job Number:FC10730
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP99835-BS 9I020486.D 1 11/02/23 KA 11/01/23 OP99835 S9I726
The QC reported here applies to the following samples:Method: EPA 625.1
FC10730-1, FC10730-2
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
65-85-0 Benzoic Acid 100 39.8 40 10-69
59-50-7 4-Chloro-3-methyl Phenol 50 48.3 97 54-103
95-57-8 2-Chlorophenol 50 44.4 89 52-98
120-83-2 2,4-Dichlorophenol 50 51.0 102 53-103
105-67-9 2,4-Dimethylphenol 50 45.5 91*43-90
51-28-5 2,4-Dinitrophenol 100 95.4 95 44-112
534-52-1 4,6-Dinitro-o-cresol 100 102 102 66-121
95-48-7 2-Methylphenol 50 36.6 73 43-90
3&4-Methylphenol 100 73.6 74 36-88
88-75-5 2-Nitrophenol 50 49.4 99 53-102
100-02-7 4-Nitrophenol 100 54.4 54 18-62
87-86-5 Pentachlorophenol 100 111 111 61-115
108-95-2 Phenol 50 22.6 45 19-56
88-06-2 2,4,6-Trichlorophenol 50 52.1 104 59-107
83-32-9 Acenaphthene 50 52.5 105 61-107
208-96-8 Acenaphthylene 50 52.5 105*60-104
120-12-7 Anthracene 50 49.1 98 65-108
56-55-3 Benzo(a)anthracene 50 51.7 103 66-111
50-32-8 Benzo(a)pyrene 50 50.9 102 62-107
205-99-2 Benzo(b)fluoranthene 50 54.3 109 65-114
191-24-2 Benzo(g,h,i)perylene 50 51.8 104 66-116
207-08-9 Benzo(k)fluoranthene 50 58.8 118*65-114
101-55-3 4-Bromophenyl Phenyl Ether 50 54.5 109 65-109
85-68-7 Butyl Benzyl Phthalate 50 50.3 101 65-112
106-47-8 4-Chloroaniline 50 46.0 92 49-105
111-91-1 bis(2-Chloroethoxy)methane 50 52.5 105*51-102
111-44-4 bis(2-Chloroethyl)ether 50 48.0 96 53-100
108-60-1 2,2'-Oxybis(1-chloropropane)50 46.6 93 45-106
91-58-7 2-Chloronaphthalene 50 51.8 104*57-103
7005-72-3 4-Chlorophenyl Phenyl Ether 50 53.7 107*62-105
218-01-9 Chrysene 50 54.4 109 66-111
53-70-3 Dibenzo(a,h)anthracene 50 51.9 104 66-119
132-64-9 Dibenzofuran 50 53.0 106 61-106
91-94-1 3,3'-Dichlorobenzidine 50 42.8 86 46-117
84-66-2 Diethyl Phthalate 50 53.6 107 64-108
131-11-3 Dimethyl Phthalate 50 53.4 107*63-106
* = Outside of Control Limits.
34 of 37
FC1073066.2.1
Blank Spike Summary Page 2 of 2
Job Number:FC10730
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP99835-BS 9I020486.D 1 11/02/23 KA 11/01/23 OP99835 S9I726
The QC reported here applies to the following samples:Method: EPA 625.1
FC10730-1, FC10730-2
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
84-74-2 Di-n-butyl Phthalate 50 52.9 106 65-107
117-84-0 Di-n-octyl Phthalate 50 50.7 101 62-118
121-14-2 2,4-Dinitrotoluene 50 56.6 113*61-110
606-20-2 2,6-Dinitrotoluene 50 52.6 105 63-108
117-81-7 bis(2-Ethylhexyl)phthalate 50 49.1 98 61-117
206-44-0 Fluoranthene 50 54.1 108*63-106
86-73-7 Fluorene 50 55.9 112*62-108
118-74-1 Hexachlorobenzene 50 53.7 107 63-108
87-68-3 Hexachlorobutadiene 50 51.2 102 42-102
77-47-4 Hexachlorocyclopentadiene 50 63.3 127*39-102
67-72-1 Hexachloroethane 50 44.4 89 42-100
193-39-5 Indeno(1,2,3-cd)pyrene 50 44.3 89 64-119
78-59-1 Isophorone 50 50.5 101*43-87
91-57-6 2-Methylnaphthalene 50 50.5 101 51-102
91-20-3 Naphthalene 50 49.3 99 47-100
98-95-3 Nitrobenzene 50 50.1 100 50-104
621-64-7 N-Nitrosodi-n-propylamine 50 49.6 99 52-104
86-30-6 N-Nitrosodiphenylamine 50 49.9 100 64-108
85-01-8 Phenanthrene 50 53.3 107 66-110
129-00-0 Pyrene 50 53.7 107 64-113
CAS No.Surrogate Recoveries BSP Limits
367-12-4 2-Fluorophenol 57%14-67%
4165-62-2 Phenol-d5 41%10-50%
118-79-6 2,4,6-Tribromophenol 114%33-118%
4165-60-0 Nitrobenzene-d5 101%42-108%
321-60-8 2-Fluorobiphenyl 103%40-106%
1718-51-0 Terphenyl-d14 103%39-121%
* = Outside of Control Limits.
35 of 37
FC1073066.2.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FC10730
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP99835-MS 9I020483.D 1 11/02/23 KA 11/01/23 OP99835 S9I726
OP99835-MSD 9I020484.D 1 11/02/23 KA 11/01/23 OP99835 S9I726
FC10730-1 9I020481.D 1 11/02/23 KA 11/01/23 OP99835 S9I726
The QC reported here applies to the following samples:Method: EPA 625.1
FC10730-1, FC10730-2
FC10730-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
65-85-0 Benzoic Acid ND 192 105 55 192 108 56 3 10-69/39
59-50-7 4-Chloro-3-methyl Phenol ND 96.2 83.9 87 96.2 86.2 90 3 54-103/23
95-57-8 2-Chlorophenol ND 96.2 76.2 79 96.2 83.3 87 9 52-98/25
120-83-2 2,4-Dichlorophenol ND 96.2 88.2 92 96.2 93.2 97 6 53-103/26
105-67-9 2,4-Dimethylphenol ND 96.2 84.4 88 96.2 86.1 90 2 43-90/27
51-28-5 2,4-Dinitrophenol ND 192 176 92 192 180 94 2 44-112/25
534-52-1 4,6-Dinitro-o-cresol ND 192 189 98 192 194 101 3 66-121/23
95-48-7 2-Methylphenol ND 96.2 67.2 70 96.2 69.4 72 3 43-90/28
3&4-Methylphenol ND 192 133 69 192 142 74 7 36-88/28
88-75-5 2-Nitrophenol ND 96.2 83.3 87 96.2 88.0 92 5 53-102/29
100-02-7 4-Nitrophenol ND 192 109 57 192 111 58 2 18-62/33
87-86-5 Pentachlorophenol ND 192 215 112 192 218 113 1 61-115/26
108-95-2 Phenol ND 96.2 42.8 45 96.2 47.4 49 10 19-56/35
88-06-2 2,4,6-Trichlorophenol ND 96.2 90.4 94 96.2 94.9 99 5 59-107/23
83-32-9 Acenaphthene ND 96.2 88.9 92 96.2 93.9 98 5 61-107/22
208-96-8 Acenaphthylene ND 96.2 89.0 93 96.2 94.9 99 6 60-104/22
120-12-7 Anthracene ND 96.2 87.0 90 96.2 91.0 95 4 65-108/20
56-55-3 Benzo(a)anthracene ND 96.2 88.6 92 96.2 94.4 98 6 66-111/22
50-32-8 Benzo(a)pyrene ND 96.2 87.4 91 96.2 91.9 96 5 62-107/23
205-99-2 Benzo(b)fluoranthene ND 96.2 92.6 96 96.2 101 105 9 65-114/23
191-24-2 Benzo(g,h,i)perylene ND 96.2 91.5 95 96.2 95.6 99 4 66-116/23
207-08-9 Benzo(k)fluoranthene ND 96.2 99.0 103 96.2 103 107 4 65-114/24
101-55-3 4-Bromophenyl Phenyl Ether ND 96.2 98.1 102 96.2 101 105 3 65-109/23
85-68-7 Butyl Benzyl Phthalate ND 96.2 89.7 93 96.2 95.7 100 6 65-112/24
106-47-8 4-Chloroaniline ND 96.2 69.9 73 96.2 74.3 77 6 49-105/27
111-91-1 bis(2-Chloroethoxy)methane ND 96.2 86.7 90 96.2 93.5 97 8 51-102/28
111-44-4 bis(2-Chloroethyl)ether ND 96.2 79.3 82 96.2 87.9 91 10 53-100/27
108-60-1 2,2'-Oxybis(1-chloropropane)ND 96.2 74.7 78 96.2 84.7 88 13 45-106/26
91-58-7 2-Chloronaphthalene ND 96.2 85.9 89 96.2 92.6 96 8 57-103/23
7005-72-3 4-Chlorophenyl Phenyl Ether ND 96.2 90.9 95 96.2 96.0 100 5 62-105/20
218-01-9 Chrysene ND 96.2 96.0 100 96.2 102 106 6 66-111/22
53-70-3 Dibenzo(a,h)anthracene ND 96.2 91.8 95 96.2 96.5 100 5 66-119/24
132-64-9 Dibenzofuran ND 96.2 88.6 92 96.2 93.7 97 6 61-106/21
91-94-1 3,3'-Dichlorobenzidine ND 96.2 30.8 32*96.2 32.7 34*6 46-117/29
84-66-2 Diethyl Phthalate ND 96.2 92.1 96 96.2 94.1 98 2 64-108/21
131-11-3 Dimethyl Phthalate ND 96.2 92.0 96 96.2 94.3 98 2 63-106/22
* = Outside of Control Limits.
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FC1073066.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FC10730
Account:GRINCC GRI (Geological Resources Inc.)
Project:Nic's Pic Kwik 9; 11761 McColl Rd, Laurinburg, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP99835-MS 9I020483.D 1 11/02/23 KA 11/01/23 OP99835 S9I726
OP99835-MSD 9I020484.D 1 11/02/23 KA 11/01/23 OP99835 S9I726
FC10730-1 9I020481.D 1 11/02/23 KA 11/01/23 OP99835 S9I726
The QC reported here applies to the following samples:Method: EPA 625.1
FC10730-1, FC10730-2
FC10730-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
84-74-2 Di-n-butyl Phthalate ND 96.2 92.8 97 96.2 96.4 100 4 65-107/21
117-84-0 Di-n-octyl Phthalate ND 96.2 87.7 91 96.2 94.3 98 7 62-118/24
121-14-2 2,4-Dinitrotoluene ND 96.2 95.4 99 96.2 99.1 103 4 61-110/21
606-20-2 2,6-Dinitrotoluene ND 96.2 92.3 96 96.2 96.0 100 4 63-108/21
117-81-7 bis(2-Ethylhexyl)phthalate ND 96.2 88.8 92 96.2 94.0 98 6 61-117/23
206-44-0 Fluoranthene ND 96.2 95.4 99 96.2 97.5 101 2 63-106/21
86-73-7 Fluorene ND 96.2 94.0 98 96.2 98.3 102 4 62-108/20
118-74-1 Hexachlorobenzene ND 96.2 96.0 100 96.2 98.7 103 3 63-108/22
87-68-3 Hexachlorobutadiene ND 96.2 88.4 92 96.2 93.5 97 6 42-102/28
77-47-4 Hexachlorocyclopentadiene ND 96.2 107 111*96.2 116 121*8 39-102/29
67-72-1 Hexachloroethane ND 96.2 79.0 82 96.2 83.5 87 6 42-100/29
193-39-5 Indeno(1,2,3-cd)pyrene ND 96.2 79.2 82 96.2 85.0 88 7 64-119/24
78-59-1 Isophorone ND 96.2 83.3 87 96.2 90.2 94*8 43-87/25
91-57-6 2-Methylnaphthalene 19.5 96.2 95.2 79 96.2 102 86 7 51-102/26
91-20-3 Naphthalene 6.1 96.2 85.5 83 96.2 92.8 90 8 47-100/29
98-95-3 Nitrobenzene ND 96.2 80.9 84 96.2 88.5 92 9 50-104/28
621-64-7 N-Nitrosodi-n-propylamine ND 96.2 81.2 84 96.2 88.9 92 9 52-104/25
86-30-6 N-Nitrosodiphenylamine ND 96.2 93.9 98 96.2 96.5 100 3 64-108/23
85-01-8 Phenanthrene ND 96.2 96.2 100 96.2 99.3 103 3 66-110/21
129-00-0 Pyrene ND 96.2 93.8 98 96.2 99.9 104 6 64-113/23
CAS No.Surrogate Recoveries MS MSD FC10730-1 Limits
367-12-4 2-Fluorophenol 54%58%34%14-67%
4165-62-2 Phenol-d5 41%45%22%10-50%
118-79-6 2,4,6-Tribromophenol 106%106%106%33-118%
4165-60-0 Nitrobenzene-d5 83%90%99%42-108%
321-60-8 2-Fluorobiphenyl 87%93%92%40-106%
1718-51-0 Terphenyl-d14 89%97%81%39-121%
* = Outside of Control Limits.
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FC1073066.3.1