FA-3861_29769_CA_CSA_20231027

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
October 27, 2023

Mr. Mike Haseltine
NCDEQ-UST Section
Wilmington Regional Office
127 Cardinal Drive Extension
Wilmington, NC 28405

Re: Comprehensive Site Assessment Report
March - September 2023
Minute Man #3
501 North East Street
Roseboro, Sampson County
North Carolina
Facility ID Number: 0-00-0000009436
Incident Number: 29769
GRI Project Number: 3148

Dear Mr. Haseltine,

Please find enclosed the referenced report for the abovementioned site.
If you have any questions, please contact Laura Minor at 704-845-4010.

Sincerely,
Geological Resources, Inc.

Leslie Maxtone-Graham
Administrative Assistant

Enclosure

Cc: Ms. Jill Smith; Campbell Oil Company, Inc., file

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•
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Comprehensive Site Assessment Report
March-September 2023
Minute Man #3
501 North East Street
Roseboro, Sampson County
North Carolina
Facility ID Number: 0-00-0000009436
Incident Number: 29769
GRI Project Number: 3148

Prepared for:

Ms. Jill Smith
Campbell Oil Company, Inc.
Post Office Box 637
Elizabethtown, North Carolina 28337

October 24, 2023

Laura Minor
Project Manager
Eric M. Eubanks, P.G.
Report Writer

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: October 24, 2023 Minute Man #3
Project Manager: Laura Minor GRI Project No. 3148
i
EXECUTIVE SUMMARY
The Minute Man #3 site is an active convenience store and gasoline retail facility located at 501 North
East Street in Roseboro, Sampson County, North Carolina. The site is covered by concrete and asphalt.
The surrounding properties are commercial and residential. There are two 6,000-gallon gasoline USTs,
one 4,000-gallon gasoline UST, and one 2,000-gallon kerosene UST and associated pumps and product
piping are currently in use at the site with two associated gasoline dispenser islands. Reportedly, one
3,000-gallon diesel UST was removed in 1992.

On June 8, 2012, a monitoring well was installed down gradient of the site for an adjoining incident
(Incident No. 6601). Free product was measured in this monitoring well and therefore a site check was
completed at the subject site in June 2012. Site Check results confirmed a release at the site and an LSA
was required.

Based on the December 2012 receptor survey, three water supply wells were identified within a 1,500-
foot radius of the site. No potable water supply wells were identified within a 1,000-foot radius of the
site and no non-potable water supply wells were identified within a 250-foot radius of the site. No surface
water bodies were identified within a 500-foot radius of the site. Municipal water is available to the site
and surrounding properties.

An NRP for the site was filed on July 22, 2016. However, during well abandonment activities, free product
was observed in MW-1. Therefore, on July 5, 2017, five additional Type II monitoring wells (MW-2 through
MW-6) were installed at the site. Based on the results of ground water sampling and free product removal
activities, a CSA was required.

On March 8 and 9, 2023, five Type II monitoring wells (MW-7 through MW-11) and one Type III telescoping
well (TW-1) were installed as part of CSA activities. The contaminant concentrations of benzene, toluene,
ethylbenzene, xylenes, naphthalene, n-propylbenzene, 1,2,4-trimethylbenzene, C5-C8 aliphatics, and/or
C9-C22 aromatics reported in the ground water samples collected from MW-3, MW-6, MW-9, and MW-
11 exceeded the MACs. All contaminant concentrations were below the GCLs. Free product thicknesses
of 0.74 feet, 0.31 feet, 1.49 feet, and 0.36 feet were measured in monitoring wells MW-1, MW-2, MW-4,
and MW-5, respectively.

Due to the lack of delineation of contaminant concentrations, two (2) additional Type II monitoring wells
(MW-12 and MW-13) were installed along the NCDOT right-of-way located north and west of MW-5,
respectively, on September 12, 2023. The newly installed wells were sampled on September 21, 2023,
while the existing wells (MW-1 through MW-11 and TW-1) were only gauged. Concentrations of benzene,
xylenes, naphthalene, 1,2,4-trimethylbenzene, C5-C8 aliphtatics, C9-C18 aliphatics and/or C9-C22
aromatics that exceeded the MACs were reported in MW-12 and/or MW-13. Free product thicknesses of
1.35 feet, 0.29 feet, 0.37 feet, 2.87 feet, 0.33 feet and 0.03 feet in MW-1 through MW-6, respectively.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: October 24, 2023 Minute Man #3
Project Manager: Laura Minor GRI Project No. 3148
ii
During the March 2023 monitoring well installation activities, two soil samples (SB-1 (18’)) and SB-2 (20’))
were collected and submitted for laboratory analysis. The concentrations of benzene, toluene,
ethylbenzene, xylenes, naphthalene, n-propylbenzene, n-butylbenzene, sec-butylbenzene,
isopropylbenzene, 4-isopropyltoluene, methylene chloride, styrene, 1,2,4-trimethylbenzene, 1,3,5-
trimethylbenzene, 1-methylnaphthalene, 2-methylnaphthalene, C9-C18 aliphatics, C11-C22 aromatics,
C5-C8 aliphatics, C9-C12 aliphatics, and/or C9-C10 aromatics reported in soil samples SB-1 (18’) and SB-2
(20’) exceeded the MCCs. The concentrations of ethylbenzene, naphthalene, 1,2,4-trimethylbenzene, C5-
C8 aliphatics, and/or C9-C10 aromatics reported in soil samples SB-1 (18’) and SB-2 (20’) exceeded the
Residential SCLs. The concentration of naphthalene reported in soil sample SB-1 (18’) exceeded the
Industrial SCL. Due to the lack of delineation of contaminant concentrations, two (2) additional Type II
monitoring wells (MW-12 and MW-13) were installed along the NCDOT right-of-way located north and
west of MW-5, respectively.

Based on observations made during assessment activities, surficial soils observed at the site consist of
various clays, silts, and sands to 45 feet BGS. Ground water flowed radially away from MW-2. The vertical
hydraulic gradient was downward. Rising head slug tests were conducted on MW-7, MW-8, and TW-1.
The average hydraulic conductivity and seepage velocity for the Type II monitoring wells were 1.343 x 100
feet per minute (1,933 feet per day) and 6.44 x 100 feet per day (2,350 feet per year). The hydraulic
conductivity and seepage velocity in the Type III monitoring well were 2.586 x 10-3 feet per minute (3.724
feet per day) and 2.48 x 10-2 feet per day (9.06 feet per year), respectively.

The site risk classification has been deemed as intermediate risk based on the presence of free product
and/or GCL exceedances. Therefore, free product must be removed from the site and the ground water
contamination must be remediated to concentrations less than the GCLs.

GRI recommends continuing free product recovery at the site in order to lower the risk ranking. A
comprehensive ground water sampling event that includes monitoring wells RBP-42 and RBP-17 (which
are monitoring wells MW-42 and MW-17 associated with Roseboro BP (Incident No. 6601)) should be
conducted at the site. Prior to further free product removal and/or assessment and sampling activities,
GRI also recommends that a site check be completed by the current tank owner to determine if a new
release has occurred.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: October 24, 2023 Minute Man #3
Project Manager: Laura Minor GRI Project No. 3148
iii
SITE INFORMATION
1. Site Identification
 Minute Man #3 (Facility ID 0-00-0000009436)
 Incident Number 29769 – Intermediate Risk (I180D)
 Location of Source Area: 501 North East Street
Roseboro, NC 28382
Sampson County
34.9557861°N, 78.5102027°W (Topographical Map)

2. Information about Contacts Associated with the Leaking UST System

Former Owner/Operator
Campbell Oil & Gas Company
Post Office Box 637
Elizabethtown, NC 28337
[e-mail]
910-862-8423

Current UST/AST Operator
Alhobishi Convenience Stores
411 North Wilkinson Road
St. Pauls, NC 28384
Email Unknown
910-521-9030

Property Occupant
Alhobishi Convenience Stores
411 North Wilkinson Road
St. Pauls, NC 28384
Email Unknown
910-521-9030

Property Owner
Alhobishi Convenience Stores
411 North Wilkinson Road
St. Pauls, NC 28384
Email Unknown
910-521-9030

Consultant/Contractor
Geological Resources, Inc.
3502 Hayes Road
Monroe, NC 28110
[e-mail]
704-845-4010

Analytical Laboratory
Waypoint Analytical, LLC
449 Springbrook Road
Charlotte, NC 28217
State Cert. Nos. 37735 and 402
[phone]
3. Information about Release
 On June 8, 2012, a monitoring well was installed down gradient of the site for an adjoining incident
(Incident No. 6601). Free product was observed in the well, which indicated a possible UST release
at this site.
 Two 6,000-gallon gasoline USTs, one 4,000-gallon gasoline UST, and one 2,000-gallon kerosene
UST and associated pumps and product piping are active at the site. One 3,000-gallon diesel UST
was removed in 1992.

Certification:

I, Samuel L. McKay, III, a Licensed Geologist for Geological Resources, Inc., do certify that the information
contained in this report is correct and accurate to the best of my knowledge.

Geological Resources, Inc. is licensed to practice geology and engineering in North Carolina. The
certification numbers of the company are C-127 and C-2727, respectively.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: October 24, 2023 Minute Man #3
Project Manager: Laura Minor GRI Project No. 3148
iv
ACRONYMS
ACM: Asbestos Containing Materials
AFVR: Aggressive Fluid-Vapor Recovery
ARR: Acknowledgement of Report Receipt
AS: Air Sparging
AST: Aboveground Storage Tank
ASTM: American Society for Testing and
Materials
BGS: Below Ground Surface
CAP: Corrective Action Plan
CFR: Code of Federal Regulations
CSA: Comprehensive Site Assessment
DPE: Dual Phase Extraction
DRO: Total Petroleum Hydrocarbons Diesel
Range Organics
DWM: Division of Waste Management
DWR: Department of Water Resources
EPA: Environmental Protection Agency
EPH: Extractible Petroleum Hydrocarbons
ESA: Environmental Site Assessment
GCL: Gross Contamination Level
GRI: Geological Resources, Inc.
GRO: Total Petroleum Hydrocarbons
Gasoline Range Organics
LSA: Limited Site Assessment
MAC: Maximum Allowable Concentration as
specified in T15A NCAC 2L.0202
MADEP: Massachusetts Department of
Environmental Protection
MCC: Maximum Contaminant Concentrations
MMPE: Mobile Multi-Phase Extraction
NAPL: Non-Aqueous Phase Liquid, “Free
Product”
NCDEQ: North Carolina Department of
Environmental Quality
NCDOT: North Carolina Department of
Transportation
NFA: Notice of No Further Action
NORR: Notice of Regulatory Requirements
NOV: Notice of Violation
NPDES: National Pollutant Discharge
Elimination System
NRP: Notice of Residual Petroleum
O&M: Operation and Maintenance
PAHs: Polynuclear Aromatic Hydrocarbons
PCA: Pre-Construction Assessment
RAL: Regulatory Action Level
SCLs: Soil Cleanup Level
SPCC: Spill Prevention Control and
Countermeasures
SVE: Soil Vapor Extraction
SVOCs: Semi-Volatile Organic Compounds
SWAP: Source Water Assessment and
Protection
SWPPP: Stormwater Pollution Prevention Plan
TCLP: Toxicity Characteristic Leaching
Procedure (EPA Method SW-846 1311)
TOC: Top of Casing
TPH: Total Petroleum Hydrocarbons
USGS: United States Geological Survey
UST: Underground Storage Tank
UVF: Ultraviolet Fluorescence
VOCs: Volatile Organic Compounds
VPH: Volatile Petroleum Hydrocarbons

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: October 24, 2023 Minute Man #3
Project Manager: Laura Minor GRI Project No. 3148

TABLE OF CONTENTS
EXECUTIVE SUMMARY ....................................................................................................................... i
SITE INFORMATION ........................................................................................................................... iii
ACRONYMS ....................................................................................................................................... iv
1.0 SITE HISTORY AND CHARACTERIZATION ...................................................................................1
2.0 RECEPTOR INFORMATION ........................................................................................................3
3.0 LAND USE ................................................................................................................................4
4.0 SOIL ASSESSMENT ...................................................................................................................4
5.0 GROUND WATER ASSESSMENT ................................................................................................5
6.0 FREE PRODUCT INVESTIGATION AND RECOVERY ......................................................................7
7.0 HYDROGEOLOGIC INVESTIGATION ...........................................................................................7
8.0 REGIONAL GEOLOGY AND HYDROGEOLOGY .............................................................................8
9.0 SITE GEOLOGY AND HYDROGEOLOGY ......................................................................................8
10.0 DISCUSSION ............................................................................................................................9
11.0 CONCLUSIONS AND RECOMMENDATIONS ...............................................................................9
12.0 PUBLIC NOTICE ........................................................................................................................9
13.0 LIMITATIONS ......................................................................................................................... 10
14.0 REFERENCES .......................................................................................................................... 10

FIGURES
Figure 1: Site Location Map
Figure 2: Site Map
Figure 3A: Site Vicinity Map
Figure 3B: Zoning Map
Figure 4: Soil Quality Map
Figure 5: Cross-Section A-A’
Figure 6: Cross-Section B-B’
Figure 7: Estimated Contaminant Map
Figure 8: Ground Water Quality Map
Figure 9: Free Product Plume Map
Figure 10: Water Table Surface Map (3/08/23)
Figure 11: Water Table Surface Map (9/21/23)

TABLES
Table 1: UST Owner and Operator Information
Table 2: UST System Information
Table 3: Water Supply Well Information
Table 4: Adjacent Property Owner Information
Table 5: Land Use Information

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: October 24, 2023 Minute Man #3
Project Manager: Laura Minor GRI Project No. 3148

Table 6: Summary of Soil Sample Analytical Results
Table 7: Summary of Ground Water Sample Analytical Results
Table 8: Free Product Recovery Results
Table 9: Free Product Recovery Event Information
Table 10: Free Product Recovery Cost Summary
Table 11: Well Construction and Gauging Information
Table 12: Summary of Slug Test Analyses
APPENDICES
Appendix A: State Correspondence
Appendix B: NCDEQ Incident Reports
Appendix C: Site-Specific Health and Safety Plan & Field Data Sheet
Appendix D: Roseboro Zoning Map
Appendix E: Well Permits, Well Construction Records, and Subsurface Logs
Appendix F: Laboratory Analytical Reports
Appendix G: Historical Gauging and Ground Water Quality Data
Appendix H: Slug Test Data
Appendix I: Public Notification

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: October 24, 2023 Minute Man #3
Project Manager: Laura Minor GRI Project No. 3148
1
1.0 SITE HISTORY AND CHARACTERIZATION
GRI presents the results of the March 2023 CSA activities at the Minute Man #3 site, located at 501 North
East Street in Roseboro, Sampson County, North Carolina. A topographic map showing the general site
location and the surrounding area is included as Figure 1. These activities were conducted in accordance
with GRI Proposal No. 22-642, which was submitted to the NCDEQ on November 16, 2022, and was
approved as Task Authorization No. 29769-10 on November 18, 2022. State correspondence is included
as Appendix A.

The site is currently owned by Alhobishi Convenience Stores & Rentals, Inc. and operated as a petroleum
retail facility convenience store. Currently, two 6,000-gallon gasoline USTs, one 4,000-gallon gasoline UST,
and one 2,000-gallon kerosene UST are active at the site. One 3,000-gallon diesel UST was removed in
1992. UST owner/operator information and UST system information are included as Table 1 and Table 2,
respectively. The Registered Tank Report is shown below:

A previous release (Incident No. 12362) was reported for the site on June 30, 1994, after petroleum-
contaminated ground water was encountered during UST removal activities conducted in December 1993.
A CSA and a CAP were completed for the site by a previous consultant in September 1994 and January
1996, respectively. The incident was closed with an NFA on September 14, 1998. The NCDEQ Incident
Reports for this site are included as Appendix B.

On June 8, 2012, a monitoring well was installed downgradient of the site for an adjoining incident
(Incident No. 6601). Free product was measured in this monitoring well during the Site Check that was
completed at the Minute Man #3 site on June 18, 2012. Site Check results confirmed a release, and an
LSA was required by the NCDEQ.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: October 24, 2023 Minute Man #3
Project Manager: Laura Minor GRI Project No. 3148
2
On December 10, 2012, GRI personnel conducted an LSA at the site. One Type II monitoring well (MW-1)
was installed and two soil samples (MW-1 (5’) and MW-1(10’)) were collected at 5-foot intervals during
the installation of monitoring well MW-1. The concentration of benzene reported in soil sample MW-1(5’)
exceeded the MCC. The concentrations of benzene, toluene, ethylbenzene, xylenes, MTBE, naphthalene,
methylene chloride, n-propylbenzene, 1,2,4-trimethybenzene, 2-methylnaphthalene, EDB, lead, C5-C8
aliphatics, C9-C18 aliphatics and C9-C22 aromatics reported in the ground water sample collected from
MW-1 exceeded the MACs. All contaminant concentrations were below the GCLs. No free product was
observed at the site.

An NRP for the site was filed on July 22, 2016. However, during well abandonment activities, free product
was observed in MW-1. Therefore, on July 5, 2017, five additional Type II monitoring wells (MW-2 through
MW-6) were installed at the site. The concentrations of benzene, toluene, ethylbenzene, xylenes,
naphthalene, isopropylbenzene, n-propylbenzene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, 1-
methylnaphthalene, 2-methylnaphthalene, EDB, and/or lead reported in the ground water samples
collected from MW-3, MW-5, and MW-6 exceeded the MACs. All contaminant concentrations were below
the GCLs. Free product thicknesses of 1.10, 1.31, and 0.67 feet were measured in monitoring wells MW-
1, MW-2, and MW-4, respectively. Free product recovery activities were conducted on MW-2 on July 20,
2017. Approximately 0.50 gallons of free product was hand-bailed from MW-2.

Between February 28, 2019, and April 16, 2021, two AFVR events and one MMPE event have been
conducted at the site. To date, approximately 25,357.78 gallons of petroleum contact water and 1.09
gallons of product have been removed.

On November 17, 2021, a CSA was required by NCDEQ to delineate the horizontal and vertical extent of
petroleum contamination. On March 8 and 9, 2023, five additional Type II monitoring wells (MW-7
through MW-11) and one Type III telescoping monitoring well (TW-1) were installed, gauged, and/or
sampled as part of the CSA activities. The concentrations of benzene, toluene, ethylbenzene, xylenes,
naphthalene, n-propylbenzene, 1,2,4-trimethylbenzene, C5-C8 aliphatics, and/or C9-C22 aromatics
reported in the ground water samples collected from MW-3, MW-6, MW-9, and MW-11 exceeded the
MACs. All contaminant concentrations were below the GCLs. Free product was measured in MW-1, MW-
2, MW-4, and MW-5 with thicknesses of 0.74, 0.31, 1.49 and 0.36 feet, respectively.

Due to the lack of delineation of contaminant concentrations, two (2) additional Type II monitoring wells
(MW-12 and MW-13) were installed along the NCDOT right-of-way located north and west of MW-5, on
September 12, 2023. The newly installed wells were sampled on September 21, 2023, while the existing
wells (MW-1 through MW-11 and TW-1) were only gauged. Concentrations of benzene, xylenes,
naphthalene, 1,2,4-trimethylbenzene, C5-C8 aliphtatics, C9-C18 aliphatics and/or C9-C22 aromatics that
exceeded the MACs were reported in MW-12 and/or MW-13. Free product thicknesses of 1.35 feet, 0.29
feet, 0.37 feet, 2.87 feet, 0.33 feet and 0.03 feet in MW-1 through MW-6, respectively.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: October 24, 2023 Minute Man #3
Project Manager: Laura Minor GRI Project No. 3148
3
During March 2023 monitoring well installation activities, two soil borings were advanced to 20’ BGS
screened every 2’ with a PID. Soil samples SB-1 (18’) and SB-2 (20’) were collected from newly advanced
soil borings. Soil sample SB-2 (20’) was collected during the installation of telescoping well TW-1. Soil
samples SB-1 (18’) and SB-2 (20’) were submitted for laboratory analysis. The concentrations of benzene,
toluene, ethylbenzene, xylenes, naphthalene, n-propylbenzene, n-butylbenzene, sec-butylbenzene,
isopropylbenzene, 4-isopropyltoluene, methylene chloride, styrene, 1,2,4-trimethylbenzene, 1,3,5-
trimethylbenzene, 1-methylnaphthalene, 2-methylnaphthalene, C9-C18 aliphatics, C11-C22 aromatics,
C5-C8 aliphatics, C9-C12 aliphatics, and/or C9-C10 aromatics reported in soil samples SB-1 (18’) and SB-2
(20’) exceeded the MCCs. The concentrations of ethylbenzene, naphthalene, 1,2,4-trimethylbenzene, C5-
C8 aliphatics, and/or C9-C10 aromatics reported in soil samples SB-1 (18’) and SB-2 (20’) exceeded the
Residential SCLs. The concentration of naphthalene reported in soil sample SB-1 (18’) exceeded the
Industrial SCL.

Slug tests were performed for three wells at the site on March 13 and March 27, 2023. A Site Map showing
the locations of the monitoring wells and the structures on-site is included as Figure 2. A copy of the site-
specific Health and Safety Plan is included as Appendix C.

2.0 RECEPTOR INFORMATION
Water Supply Wells:
According to the information determined during receptor survey activities conducted on December 10,
2012, three non-potable water supply wells were identified within 1,500 feet of the site. No water supply
wells were identified within 250 feet of the site. A table summarizing the Water Supply Well owner
information is included as Table 3. A Site Vicinity Map showing the locations of the water supply wells is
included in Figure 3.

Public Water Supplies:
Public water is available to the site and all of the surrounding properties. Water lines run along the public
streets in the area. Public water is supplied by Sampson County Public Works.

Surface Water:
No surface water bodies were identified within 500 feet of the subject site during the December 10, 2012,
receptor survey.

Wellhead Protection Areas:
On December 20, 2012, GRI personnel accessed the NCDEQ SWAP Program’s website to identify wellhead
protection areas in the vicinity of the subject site. The site is not located within a wellhead protection
area.

Deep Aquifers in the Coastal Plain Physiographic Region:
The surficial aquifer (which is approximately 39 feet thick in the vicinity of the site) directly overlies the
Black Creek confining unit and Black Creek aquifer.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: October 24, 2023 Minute Man #3
Project Manager: Laura Minor GRI Project No. 3148
4

Subsurface Structures:
No structures with basements were observed in the vicinity of the source area. However, utilities in the
source area may intersect the seasonal high water table.

3.0 LAND USE
The site is currently occupied by a petroleum retail facility and convenience store. The closest primary
residence is located on an adjacent property approximately 200 feet south of the source area. The Casons
Community Daycare is located approximately 750 feet to the southwest of the source area. The adjoining
properties are commercial. According to the Sampson County Official Zoning Map, the site and
surrounding areas are zoned Extraterritorial Jurisdiction. Adjacent property owner information and land
use information are summarized in Table 4 and Table 5, respectively. Land use and zoning information is
presented in Figure 3B. A copy of the Roseboro zoning map is included as Appendix D.

4.0 SOIL ASSESSMENT
On June 8, 2012, one off-site monitoring well installed downgradient of the site contained free product,
so on June 21, 2012, GRI personnel conducted a site check at the subject site. Ten soil borings were
advanced around the UST basin and dispensers to depths varying from 3 to 11 feet BGS. Soil samples (GP-
1 through GP-10) were collected from each of the borings. The concentration of TPH-GRO in soil sample
GP-6 exceeded the existing RAL.

During the installation of monitoring well MW-1, soil samples were collected at 5-foot intervals above the
seasonally high water table (MW-1 (5’) and MW-1 (10’)) and submitted for laboratory analysis of VOCs by
EPA Method 8260B and EPH and VPH by the MADEP method. The concentration of benzene reported in
soil sample MW-1 (5’) exceeded the MCC.

On March 8, 2023, two soil samples were collected and screened using a PID. Soil sample SB-1 (18’) was
collected during the installation of monitoring well TW-1, while SB-2 (20’) was collected from a newly
installed boring. Both soil samples were submitted for laboratory analysis of VOCs by EPA Method 8260B,
SVOCs by EPA Method 8270, and EPH and VPH by the MADEP Methods. The concentrations of benzene,
toluene, ethylbenzene, xylenes, naphthalene, n-propylbenzene, n-butylbenzene, sec-butylbenzene,
isopropylbenzene, 4-isopropyltoluene, methylene chloride, styrene, 1,2,4-trimethylbenzene, 1,3,5-
trimethylbenzene, 1-methylnaphthalene, 2-methylnaphthalene, C9-C18 aliphatics, C11-C22 aromatics,
C5-C8 aliphatics, C9-C12 aliphatics, and/or C9-C10 aromatics reported in soil samples SB-1 (18’) and SB-2
(20’) exceeded the MCCs. The concentrations of ethylbenzene, naphthalene, 1,2,4-trimethylbenzene, C5-
C8 aliphatics, and/or C9-C10 aromatics reported in soil samples SB-1 (18’) and SB-2 (20’) exceeded the
Residential SCLs. The concentration of naphthalene reported in soil sample SB-1 (18’) exceeded the
Industrial SCL. The soil sampling analytical results are presented in Table 6. A Soil Quality Map with the
results of the soil sampling in 2023 is included as Figure 4. A summary of the soil sampling data from the
March 2023 CSA activities is shown below:

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: October 24, 2023 Minute Man #3
Project Manager: Laura Minor GRI Project No. 3148
5 Sample ID Sample Depth (ft-BGS) Benzene Toluene Ethylbenzene Total Xylenes MTBE Naphthalene Soil to Water MCCs (mg/kg) 0.0072 5.4 8 6 0.085 0.2
Residential SCLs (mg/kg) 12 1,250 60.3 3,120 156 5.5
Industrial SCLs (mg/kg) 59.4 18,600 297 46,700 1,810 27
SB-1 (18’) 18 5.48 230 87.1 448 <0.193 33.9
SB-2 (20’) 20 0.576 J 35.7 25.9 121 <0.193 13.0

Clean, disposable nitrile gloves were used for the collection of the soil samples. The samples were
collected in laboratory supplied containers and shipped to the laboratory in a cooler following proper
chain-of-custody procedures.

5.0 GROUND WATER ASSESSMENT
During LSA activities, one Type II monitoring well (MW-1) was installed to a total depth of 20 feet BGS
with a 10-foot screened interval. The concentrations of benzene, toluene, ethylbenzene, xylenes, MTBE,
naphthalene, methylene chloride, n-propylbenzene, 1,2,4-trimethybenzene, 2-methylnaphthalene, EDB,
lead C5-C8 aliphatics, C9-C18 aliphatics and C9-C22 aromatics reported in the ground water sample
collected from MW-1 exceeded the MACs. All contaminant concentrations were below the GCLs. Based
on the results of the LSA, a CSA was required.

On July 5, 2017, five additional Type II monitoring wells (MW-2 through MW-6) were installed at the site.
All newly installed monitoring wells were completed to 20 feet BGS with a 15-foot screened interval. The
concentrations of benzene, toluene, ethylbenzene, xylenes, naphthalene, isopropylbenzene, n-
propylbenzene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, 1-methylnaphthalene, 2-
methylnaphthalene, EDB, and/or lead reported in the ground water samples collected from MW-3, MW-
5, and MW-6 exceeded the MACs. All contaminant concentrations were below the GCLs. Free product
thicknesses of 1.10, 1.31, and 0.67 feet were measured in monitoring wells MW-1, MW-2, and MW-4,
respectively.

Between April 8, 2019, and June 1, 2021, four comprehensive ground water sampling events were
conducted at the site. The concentrations of benzene, toluene, ethylbenzene, xylenes, naphthalene, TAA,
methyl chloride, n-propylbenzene, and/or 1,2,4-trimethylbenzene reported in the ground water samples
collected from MW-2, MW-3, MW-5, and MW-6 exceeded the MACs. All contaminant concentrations
were below the GCLs. Free product with maximum thicknesses of 1.30, 1.12, and 1.31 feet were measured
in MW-1, MW-2, and MW-4, respectively.

On March 8 and 9, 2023, five additional Type II monitoring wells (MW-7 through MW-11) and one Type III
telescoping well (TW-1) were installed at the site. The newly installed Type II wells were completed to 20
feet BGS with a 15-foot screened interval, and the Type III telescoping well was completed to 45 feet BGS
with a 5-foot screened interval. On March 13, 2023, all wells were gauged, purged, and/or sampled. The

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: October 24, 2023 Minute Man #3
Project Manager: Laura Minor GRI Project No. 3148
6
concentrations of benzene, toluene, ethylbenzene, xylenes, naphthalene, n-propylbenzene, 1,2,4-
trimethylbenzene, C5-C8 aliphatics, and/or C9-C22 aromatics reported in the ground water samples
collected from MW-3, MW-6, MW-9, and MW-11, respectively, exceeded the MACs. All contaminant
concentrations were below the GCLs. Free product thicknesses of 0.74, 0.31, 1.49, and 0.36 feet were
measured in monitoring wells MW-1, MW-2, MW-4, and MW-5, respectively.

Due to the lack of delineation of contaminant concentrations, two (2) additional Type II monitoring wells
(MW-12 and MW-13) were installed along the NCDOT right-of-way located north and west of MW-5,
respectively, on September 12, 2023. The newly installed wells were sampled on September 21, 2023,
while the existing wells (MW-1 through MW-11 and TW-1) were only gauged. Concentrations of benzene,
xylenes, naphthalene, 1,2,4-trimethylbenzene, C5-C8 aliphtatics, C9-C18 aliphatics and/or C9-C22
aromatics that exceeded the MACs were reported in MW-12 and/or MW-13. Free product thicknesses of
1.35 feet, 0.29 feet, 0.37 feet, 2.87 feet, 0.33 feet and 0.03 feet in MW-1 through MW-6, respectively. A
summary of the March 13, 2023 (MW-1 through MW-11 and TW-1) and September 21, 2023 (MW-12 and
MW-13) ground water analytical data is shown below:

Contaminant
of Concern Benzene Toluene Ethylbenzene Xylenes MTBE Naphthalene Well
ID
MACs (μg/l) 1 600 600 500 20 6
GCL (μg/l) 5,000 260,000 80,000 50,000 20,000 6,000
MW-1 FP FP FP FP FP FP
MW-2 FP FP FP FP FP FP
MW-3 1,240 10,400 1,360 6,940 <14.0 311
MW-4 FP FP FP FP FP FP
MW-5 FP FP FP FP FP FP
MW-6 50.8 2,030 190 1,320 <1.40 <4.70
MW-7 0.954 4.12 0.925 5.17 <0.140 <0.470
MW-8 0.626 5.68 2.51 8.59 <0.140 0.618 J
MW-9 9.26 124 103 298 <1.40 52.7
MW-10 <0.180 <0.220 <0.170 <0.21 <0.140 <0.470
MW-11 56.6 2.75 45.7 108 0.241 J 2.16
MW-12 1.92 34.9 110 1,140 <0.140 42.8
MW-13 0.631 8.85 46.0 301 0.231 J 53.1
TW-1 <0.180 0.441 J <0.170 <0.21 <0.140 <0.470

All samples were collected in accordance with the NCDEQ guidelines. Clean, disposable bailers and nitrile
gloves were used for the collection of the ground water samples. The samples were collected in
laboratory supplied containers and shipped to the laboratory in a cooler following proper chain-of-custody
procedures. A laboratory supplied trip blank was included in the sample cooler. No detectable
concentrations of requested method constituents were reported in the trip blank.

The baseline contaminant mass at the site was determined in GRI’s August 26, 2021, MMPE and Ground
Water Monitoring Report using total BTEX, MTBE and naphthalene concentrations from the July 2017
ground water sampling event as well as the maximum historical water column height observed in each

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: October 24, 2023 Minute Man #3
Project Manager: Laura Minor GRI Project No. 3148
7
area. The contaminant plume was divided into three areas (Areas 1 through 3) based on the benzene
concentrations during the July 2017 ground water sampling event. For wells not sampled due to the
presence of free product, GCL values were used. The locations of the monitoring wells are shown in Figure
2. Well permits, well construction records, and boring logs for the monitoring wells installed during CSA
activities are included as Appendix E.

Cross sections A-A’ and B-B’ are included as Figures 5 and 6; the lines of cross section are included on
Figure 2. A map of the contaminant mass areas are included as Figure 7. A Ground Water Quality Map
for the March 2023 and September 2023 ground water sampling event is included as Figure 8. A summary
of laboratory analyses for the ground water samples collected during CSA activities are included as Table
7. Complete copies of the laboratory reports for the soil and ground water samples are included as
Appendix F.

6.0 FREE PRODUCT INVESTIGATION AND RECOVERY
Free product is currently present in MW-1 through MW-6. Between July 20, 2017, and April 16, 2021,
hand bailing, two AFVR events, and one MMPE event have been conducted on MW-1, MW-2, and MW-4
at the site as part of free product recovery activities. A total of 25,357.78 gallons of affected ground water
was recovered during these events. Approximately 0.50 gallons of liquid free product and 0.59 gallons of
vaporized free product has been recovered from these free product removal activities. A free product
plume map is included as Figure 9. Summaries of the free product removal results and costs are included
as Tables 9 through 11. Based on the results of the AFVR event, AFVR does not appear to be the most
cost-effective method of free product removal.

7.0 HYDROGEOLOGIC INVESTIGATION
The depths to ground water in the Type II monitoring wells (MW-1 through MW-11) measured on March
13, 2023, ranged from 13.98 to 15.13 feet below the tops of well casings. Ground water elevations at the
site, based on an assumed datum of 100.00 feet assigned to MW-1, ranged from 86.15 to 86.49 feet
relative to a temporary benchmark. Based on this information, ground water flowed radially away from
MW-2. The horizontal hydraulic gradient across the site was approximately 0.001 feet per foot. The
vertical hydraulic gradient calculated for paired wells MW-1/TW-1 was approximately 0.002 feet per foot
in the downward direction. On September 21, 2023, monitoring wells, MW-1 through MW-13 and TW-1
were gauged, purged and/or sampled. Depths to ground water in the Type II monitoring wells ranged
from 12.80 to 14.98 feet below the tops of well casings. Ground water elevations at the site, based on an
assumed datum of 100.00 feet assigned to MW-1, ranged from 87.35 to 88.18 feet relative to a temporary
benchmark. Ground water flow was in a radial pattern away from MW-2.

A summary of ground water elevation data obtained during assessment activities to date is presented in
Table 12. Water Table Surface Maps based on the March 13, 2023, and September 21, 2023, gauging
data are included as Figure 10 and Figure 11, respectively. Monitoring wells RBP-17 and RBP-42 (which
are monitoring wells MW-17 and MW-42 associated with Roseboro BP (Incident No. 6601)) were surveyed
and located with a GPS on March 13, 2023. Historical gauging and ground water quality data for RBP-17
and RBP-42 are included as Appendix G.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: October 24, 2023 Minute Man #3
Project Manager: Laura Minor GRI Project No. 3148
8

Rising head slug tests were conducted in MW-7, MW-8 and TW-1 on March 13 and March 27, 2023.
Hydraulic conductivities in the Type II monitoring wells, calculated using the Bouwer and Rice method,
ranged from 1.280 x 10-1 feet per minute (184.3 feet per day) to 2.557 x 100 feet per minute (3,682 feet per
day). The average hydraulic conductivity was 1.343 x 100 feet per minute (1,933 feet per day). Seepage
velocities, calculated using the equation V = K(dh/dl)/ne, ranged from 6.14 x 10-1 to 1.23 x 101 feet per day
(224 to 4,480 feet per year). The average seepage velocity was 6.44 x 100 feet per day (2,350 feet per
year). The hydraulic conductivity in the Type III monitoring well calculated using the Bouwer and Rice
method was 2.586 x 10-3 feet per minute (3.724 feet per day). The seepage velocity calculated for the
Type III monitoring well was 2.48 x 10-2 feet per day (9.06 feet per year). A summary of the results of slug
test analyses is included in Table 13. Calculations and raw data from the slug tests have been included as
Appendix H.

8.0 REGIONAL GEOLOGY AND HYDROGEOLOGY
According to the 1985 Geologic Map of North Carolina, the site is located in the Black Creek Formation.
which is described as gray to black lignitic clay, with thin beds of micaceous sand and thick lenses of cross-
bedded sand. Bedrock was not encountered during monitoring well installation activities. The surficial
aquifer directly overlies the Black Creek confining unit and the Black Creek aquifer.
9.0 SITE GEOLOGY AND HYDROGEOLOGY
Based on observations made during assessment activities, surficial soils observed at the site consist of
various clays, silts, and sands to approximately 45 feet BGS. A summary of the current ground water
gauging data from the September 21, 2023, site visit is shown below:

Well ID
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(feet)
Free
Product
Thickness
(ft.)
Ground
Water
Elevation
(ft.)
MW-1 10 - 20 20 100.00 13.62 1.35 87.54
MW-2 5 - 20 20 100.87 13.46 0.29 88.18
MW-3 5 - 20 20 100.75 13.56 0.37 87.51
MW-4 5 - 20 20 100.20 14.98 2.87 87.68
MW-5 5 - 20 20 100.34 13.17 0.33 87.45
MW-6 5 - 20 20 100.29 12.80 0.03 87.51
MW-7 5 - 20 20 100.71 13.25 --- 87.46
MW-8 5 - 20 20 100.76 13.31 --- 87.45
MW-9 5 - 20 20 100.77 13.33 --- 87.44
MW-10 5 - 20 20 101.30 13.93 --- 87.37
MW-11 5 - 20 20 101.04 13.69 --- 87.35
MW-12 5 - 20 20 101.54 14.11 --- 87.43
MW-13 5 - 20 20 100.98 13.49 --- 87.49
TW-1 40 - 45 45 99.86 13.54 --- 86.32

On March 13, 2023, monitoring wells MW-1 through MW-11 and TW-1 were gauged, purged and/or
sampled. Depths to ground water in the Type II monitoring wells ranged from 13.98 to 15.13 feet below
the tops of well casings Ground water elevations at the site, based on an assumed datum of 100.00 feet

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: October 24, 2023 Minute Man #3
Project Manager: Laura Minor GRI Project No. 3148
9
assigned to MW-1, ranged from 86.15 to 86.49 feet relative to a temporary benchmark. Ground water
flow was generally radial away from MW-2. On September 21, 2023, monitoring wells, MW-1 through
MW-13 and TW-1 were gauged, purged and/or sampled. Depths to ground water in the Type II monitoring
wells ranged from 12.80 to 14.98 feet below the tops of well casings. Ground water elevations at the site,
based on an assumed datum of 100.00 feet assigned to MW-1, ranged from 87.35 to 88.18 feet relative
to a temporary benchmark. Ground water flow was in a radial pattern away from MW-2. Please note
that natural attenuation parameters were collected in the field during the September 2023 gauging (and
limited sampling) event. A copy of the field data sheet is included in Appendix C.
10.0 DISCUSSION
On June 8, 2012, a monitoring well was installed downgradient of the site for an adjoining incident
(Incident No. 6601). Free product was measured in this monitoring well during the Site Check that was
completed at the Minute Man #3 site on June 18, 2012. Site Check results confirmed a release, and an
LSA was required by the NCDEQ.

To date, thirteen Type II monitoring wells and one telescoping well have been installed to determine the
horizontal and vertical extent of the release. Free product has been observed in the vicinity of the UST
basin and the former dispenser islands in monitoring wells MW-1 through MW-6. Monitoring well MW-
4 contained the highest ground water contamination levels during the CSA activities. Based on the current
risk ranking of the site, free product removal activities will be required.

The risk ranking for the site has been established as intermediate due to the presence of free product.
GRI recommends continuing free product recovery at the site in order to lower the risk ranking. A
comprehensive ground water sampling event that includes monitoring wells RBP-42 and RBP-17 (which
are monitoring wells MW-42 and MW-17 associated with Roseboro BP (Incident No. 6601)) should be
conducted at the site.
11.0 CONCLUSIONS AND RECOMMENDATIONS
• Ground water flow direction is radial away from MW-2.
• The free product plume remains undefined horizontally to the northwest.
• Based on this site assessment, the site risk classification should remain intermediate.
• Free product removal should continue until free product is no longer present.
• GRI recommends free product recovery and comprehensive ground water sampling activities to
be conducted at the site.
• Prior to further free product removal and/or assessment and sampling activities, GRI also
recommends that a site check be completed by the current tank owner to determine if a new
release has occurred.
12.0 PUBLIC NOTICE
Copies of the applicable portions of this CSA report have been forwarded to the appropriate local officials
by certified mail. Copies of the cover letters are included in Appendix I.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: October 24, 2023 Minute Man #3
Project Manager: Laura Minor GRI Project No. 3148
10
13.0 LIMITATIONS
This report has been prepared for the exclusive use of Campbell Oil Company for specific application to
the referenced site in Sampson County, North Carolina. The assessment was conducted based on the
scope of work and level of effort desired by the NCDEQ and with resources adequate only for that scope
of work. Our findings have been developed in accordance with generally accepted standards of
environmental practices in the State of North Carolina, available information, and our professional
judgment. No other warranty is expressed or implied.

The data that is presented in this report is indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would
be interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from this data.
14.0 REFERENCES
Bouwer, H., 1989, The Bouwer and Rice slug test - an update, Ground Water, vol.27, no. 3, pp.304-309
Bouwer, H. and R.C. Rice, 1976, A slug test method for determining hydraulic conductivity of unconfined
aquifers with completely or partially penetrating wells, Water Resources Research, vol. 12, no.3,
pp. 423-428
Department of Natural Resources and Community Development, 1985, Geologic Map of North Carolina,
1 sheet
Fetter, C. W., 1988, Applied Hydrogeology, Second Edition, Macmillan Publishing Company, 592 p.
North Carolina Department of Environment and Natural Resources, 2000, Ground Water Section
Guidelines for the Investigation and Remediation of Soil and Ground Water, 79 p.
North Carolina Department of Environmental Quality, Division of Waste Management – UST Section
Assessment Guidelines: Petroleum and Hazardous Substances UST Releases; Petroleum Non-UST
Releases, January 19, 2021, Version
Initial Abatement Action Report – Site Check, Minute Man #3, Geological Resources, Inc., July 24, 2012
Phase I Limited Site Assessment Report, Minute Man #3, Geological Resources, Inc., January 22, 2023

FIGURES
SITE LOCATION
Figure 1
Site Location
Minute Man #3
Corner of Highway 24 and Highway 211
Roseboro, North Carolina
Sampson County
Incident No. 29769
GRI Project No. 3148
500 M
2000 FT
Date: 10/13/2023 Location: 34.9557861° N -78.5102027° W
D
a
d
"J
"J
D.
SITE
WSW-3
WSW-2
WSW-1
08012524505
08080584001
08089532001
0800800800108076208
5
0
1
0 8 029596002081147686010 8 0 2 9 3 1 25 0 1
08015669002
08104824301
0 81 0 61 640 01
08115016003
N EAST STBROAD STW N O R T H S T
E C L I N T O N S T
C U L B R E T H S T
NE RAILROAD ST
N WEST STE NORTH STOAK ST
W C LI N T ON ST E R O S E B O R O S T
E DR MARTIN L KING JR BLVD
E P L E A S A N T S T
P
E
A
R
L S
T
MAPLE ST
LEGI
ON STS U M N E R A V E
B
U
LL
A
R
D ST CYPRESS STNATI
ONAL STPARK DRW R O S E B O R O STMCPHERSON STVA
N
C
E ST HOBBS STW DR MARTIN L KING JR BLVD
N CHURCH STS EAST STDILLO N S TB U T L E R S TN BROAD STBOWEN STE H OW A RD STS HALL STN HALL STH E R R IN G S T
NW RAILROAD ST
S WEST STSW RAI
LROAD STE R O S E B O R O STBROAD STNW RAI
LROAD STROSEBORO HWYS CHURCH SS BROADW P L E A S A N T S T
W R O S E B O R O S T
FIGURE 3A: SITE VICINITY MAP
MINUTE MAN #3
501 N. EAST STREET
ROSEBORO, SAMPSON COUNTY
NORTH CAROLINA
INCIDENT NO. 29769
GRI NO. 3148
PREPARED BY:
GEOLOGICAL RESOURCES, INC.
JANUARY 22, 2013
³
0 300150
Feet
1 inch = 300 feet
1,500-FOOT RADIUS
1,000-FOOT RADIUS
250-FOOT RADIUS
1
2
4
3
LEGEND
"J Water Supply Well
D.Water Supply Well (Destroyed)
Centerlines
Adjacent Properties and Well Owners
Parcels (Yellow)
Land Use Code1
500-FOOT RADIUS
CORNER OF HIGHWAY 24 & HIGHWAY 211
"J
"J
D.
SITE
WSW-3
WSW-2
WSW-1
N EAST STBROAD STW N O R T H S T
E C L I N T O N S T
C U L B R E T H S T
NE RAILROAD ST
N WEST STE NORTH STOAK ST
W C LI N T ON ST E R O S E B O R O S T
E DR MARTIN L KING JR BLVD
E P L E A S A N T S T
P
E
A
R
L S
T
MAPLE ST
LEGI
ON STS U M N E R A V E
B
U
LL
A
R
D ST CYPRESS STNATI
ONAL STPARK DRW R O S E B O R O STMCPHERSON STVA
N
C
E ST HOBBS STW DR MARTIN L KING JR BLVD
N CHURCH STS EAST STDILLO N S TB U T L E R S TN BROAD STBOWEN STE H OW A RD STS HALL STN HALL STH E R R IN G S T
NW RAILROAD ST
S WEST STSW RAI
LROAD STE R O S E B O R O STBROAD STNW RAI
LROAD STROSEBORO HWYS CHURCH SS BROADW P L E A S A N T S T
W R O S E B O R O S T
FIGURE 3B: ZONING MAP
MINUTE MAN #3
501 N. EAST STREET
ROSEBORO, SAMPSON COUNTY
NORTH CAROLINA
INCIDENT NO. 29769
GRI NO. 3148
PREPARED BY:
GEOLOGICAL RESOURCES, INC.
JANUARY 22, 2013
³
0 300150
Feet
1 inch = 300 feet
1,500-FOOT RADIUS
1,000-FOOT RADIUS
250-FOOT RADIUS
1
2
4
3
500-FOOT RADIUS
LEGEND
D.Water Supply Well (Destroyed)
"J Water Supply Well
Centerlines
ZONING - ETJ
nc_sampson_parcels_poly
Land Use Code1
CORNER OF HIGHWAY 24 & HIGHWAY 211
Sample ID
Date
Collected
(mm/dd/yy)
Sample
Location
Sample
Depth
(ft-BGS)
50 100 NE NE NE NE NE NE
NE NE 0.0072 5.4 8 6 0.085 0.2
NE NE 12 1,250 60.3 3,120 156 5.5
NE NE 59.4 18,600 297 46,700 1,810 27
SB-1 (18') 03/08/23 TW-1 18 NR NR 5.48 230 87.1 448 <0.193 33.9
SB-2 (20')03/08/23 UST Basin 20 NR NR 0.576 J 35.7 25.9 121 <0.193 13.0
RALs (mg/kg)
Soil-to-Water MCCs (mg/kg)Total XylenesMTBENaphthaleneContaminant of Concern Gasoline-Range TPHDiesel-Range TPHBenzeneTolueneEthylbenzeneResidential SCLs (mg/kg)
Industrial/Commercial Soil Cleanup Levels (mg/kg)
Sample IDDate Sampled1 600 600 500 20 6
5,000 260,000 80,000 50,000 20,000 6,000
03/13/23 FP FP FP FP FP FP
03/13/23 1,240 10,400 1,360 6,940 <14.0 311
03/13/23 FP FP FP FP FP FP
03/13/23 FP FP FP FP FP FP
MW-9 03/13/23 9.26 124 103 298 <1.40 52.7
MW-13 09/21/23 0.631 8.85 46.0 301 0.231 J 53.1
TW-1 03/13/23 <0.180 0.441 J <0.170 <0.21 <0.140 <0.470
Contaminant of Concern
MW-1
MW-3
MW-4 BenzeneTolueneEthylbenzeneXylenesMTBENaphthaleneMW-5
GCL (µg/l)
MAC (µg/l)
7
8
9
10
11

TABLES
UST ID Number 1-4 Facility ID Number
Owner or Operator?
Owner/Operator
UST ID Number 1-4 Facility ID Number
Owner or Operator?
Owner/Operator
Address Telephone Number
Post Office Box 637, Elizabethtown, NC 28337 1-910-862-8423
00-0-0000009436
Name of Owner or Operator Dates of Ownership / Operation
Campbell Oil Company, Inc. Unknown-11/02/16
Alhobishi Convenience Stores & Rentals, Inc. 11/02/2016 - Current
Address Telephone Number
Post Office Box 807, Saint Pauls, NC 28384 1-910-521-9030
TABLE 1
UST OWNER/OPERATOR INFORMATION
MINUTE MAN #3 (INCIDENT NO. 29769)
00-0-0000009436
Name of Owner or Operator Dates of Ownership / Operation
Date:10/25/19
Was
Release
Associated
withUST
System?
(Yes/No)
1 Gasoline 6,000 05/10/1968 SingleWallSteel 8'x16'SingleWall
FRP Current Yes
2 Gasoline 6,000 05/10/1968 SingleWallSteel 8'x16'SingleWall
FRP Current No
3 Gasoline 4,000 05/10/1968 SingleWallSteel 64"x24'SingleWall
FRP Current No
4 Gasoline 2,000 05/07/1980 SingleWallSteel 64"x12'SingleWall
FRP Current No
5 Diesel 3,000 05/07/1980 SingleWallSteel 64"x18'SingleWall
Steel
Removed
(02/28/1992)Unknown
Notes:
•FRP:Fiberglassreinforcedplastic.
Description
of
Associated
Product
Piping
and
Pumps
Status
of
UST
TABLE2
USTSYSTEMINFORMATION
MINUTEMAN#3(INCIDENTNO.29769)
UST
ID
No.
Current
orMost
Recent
Contents
Capacity
(gallons)
Date
Installed
Construction
Details
Tank
Dimensions
FacilityID#:00-0-0000009436
Date:03/29/23 FacilityID#:00-0-0000009436
08104824301(Site)AlhobishiConvenienceStores 411NorthWilkinsonRoad
SaintPauls,NC28384
08029312501 JieYang 307EastRoseboroStreet
Roseboro,NC28382
08012524505 Wade-CaryHoldings,LLC 2331ProfessionalDrive
RockyMount,NC27804
08114768601 GPMSoutheast,LLC 8565MagellanParkway
Richmond,VA23227
08010118201 TheTownofRoseboroBoardof
AlcoholicControl
Highway24andHighway242
Roseboro,NC28382
08080584001 JoeS.Edge,Sr.PostOfficeBox858
Roseboro,NC28382
08029596002 JamesTradingCo.ofRoseboroInc.317NorthEastStreet
Roseboro,NC28382
08106164001 JamesTradingCo.ofRoseboroInc.317NorthEastStreet
Roseboro,NC28382
08015669002 JamesTradingCo.ofRoseboroInc.317NorthEastStreet
Roseboro,NC28382
Note:
•PropertiesarekeyedtoFigure3A.
MINUTEMAN#3(INCIDENTNO.29769)
ADJACENTPROPERTYOWNERINFORMATION
TABLE3
ParcelIDNo.PropertyOwnerName MailingAddress
WellID.ParcelIDNo.WellOwner MailingAddress WellAddress WellStatus
(Active/In-Active)
WellUse
(Potable/Non-
Potable
etc.)
Municipal
Water
Connected?
Well
Depth
(ft.BGS)
TypeofWell
(Drilled/
Bored)
Well
Casing
Depth
(ft.BGS)
WellScreen
Interval
(xtoyft.
BGS)
Distancefromsource
areaofrelease
(ft.)
WSW-1 08115016003 TeodoraG.andNicolasTurrubiartez,Jr.309OakStreet
Roseboro,NC28382
309OakStreet
Roseboro,NC28382 Inactive Unknown Yes 17 Unknown 15 15-17 ~800'NE
WSW-2 08008008001 ElimRivera&MelissaTimmer 412OakStreet
Roseboro,NC28382
412OakStreet
Roseboro,NC28382 Inactive Unknown Yes Unknown Unknown Unknown Unknown ~1300'E
WSW-3 08089532001 GaryW.andAudraCulbreth 3606ElizabethtownHighway
Roseboro,NC28382
413OakStreet
Roseboro,NC28382 Inactive Unknown Yes Unknown Unknown Unknown Unknown ~1350'ENE
Notes:
•WatersupplywellsarekeyedtoFigure3A.
•Ft.BGS:Feetbelowgroundsurface
TABLE4
WATERSUPPLYWELLINFORMATION
MINUTEMAN#3(INCIDENTNO.29769)
Date:3/28/23 FacilityID#:00-0-0000009436
Date:03/29/23 FacilityID#:00-0-0000009436
MapIDNo.LandUseFeature Zoning Description Address
Distancefrom
SourceArea
(feet)
1 CasonsCommunityDaycare ETJ DayCare 306NWestSt,
Roseboro,NC28382 ~750WSW
2 RoseboroMethodistChurch ETJ Church 300NBroadSt,
Roseboro,NC28382 ~1,250WSW
3 SampsonCountyBeatitude
House ETJ Church 212WRoseboroSt,
Roseboro,NC28382 ~1,450SW
4 OhanaMidwifery&Wellness,
LLC ETJ Midwifery 303ERoseboroSt,
Roseboro,NC28382 ~1,025SE
n/a ETJ Extraterritorial
Jurisdiction n/a n/a
Note:
•PropertiesarekeyedtoFigure3B.
TABLE5
LANDUSEINFORMATION
MINUTEMAN#3(INCIDENTNO.29769)
Page1of1
Date:04/03/23 FacilityID#:00-0-0000009436
SampleID
Date
Collected
(mm/dd/yy)
Sample
Location
Sample
Depth
(ft-BGS)
50 100 NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NA NA NA
NE NE 0.0072 5.4 8 6 0.085 0.2 1.4 2.4 2.2 1.3 0.12 0.023 0.9 6.6 6.6 0.054 1.5 540 NE 31 68 540 31
NE NE 12 1,250 60.3 3,120 156 5.5 1,560 782 1,560 1,560 1,560 93.8 3,120 156 156 22.8 62.5 1,560 31,200 469 625 1,500 469
NE NE 59.4 18,600 297 46,700 1,810 27 23,300 11,600 23,300 23,300 23,300 1,400 46,700 2,330 2,330 112 934 23,300 467,000 7,000 9,340 23,300 7,000
MW-1(5')12/10/12 5 NR NR 0.0260 0.0025J 0.0416 0.0609 0.0219 0.0299 0.0190 0.0039J *0.0064 ***0.113 0.0354 **<5.9 <5.9 NA <2.0 <2.0 4.56
MW-1(10')12/10/12 10 NR NR 0.0034J 0.0065 0.0224 0.0789 0.0074 0.0035J 0.0155 0.0047J *0.0040J ***0.0861 0.0262 **<6.2 <6.2 NA 2.88J <2.1 5.56J
SB-1(18')03/08/23 TW-1 18 NR NR 5.48 230 87.1 448 <0.193 33.9 31.5 10.4 4.44 8.95 2.57 0.461J 1.17J 214 56.4 6.12 13.4 894 <76.6 359 2,670 554 1,910
SB-2(20')03/08/23 USTBasin 20 NR NR 0.576J 35.7 25.9 121 <0.193 13.0 11.9 4.35 2.03 3.38 1.25J 0.558J <0.442 67.8 21.8 3.88 7.19 1,250 <152 461J 4,110J 1,060 1,910
Notes:
•Resultsreportedinmg/kg(milligramsperkilogram).
•RAL:RegulatoryActionLevel(soil).
•MCC:MaximumContaminantConcentrations(soil).
•NE:NotEstablished.
•NR:Analysis
•*Concentrationspriortotheinitialexceedancehavenotbeenupdated.
•ConcentrationsinboldfacetypeindicatethereportedconcentrationsexceedtheSoil-to-WaterMCCs.
•ConcentrationsinreditalicfacetypeindicatethethereportedconcentrationsexceedtheResidentialSCLs.
•<:Lessthanthemethoddetectionlimitspecifiedinthelaboratoryreport.
•J:Resultisestimated.
ResidentialSCLs(mg/kg)
Industrial/CommercialSoilCleanupLevels(mg/kg)
USTBasin C5-C8AliphaticsC9-C12AliphaticsGasoline-RangeTPHDiesel-RangeTPHBenzeneTolueneEthylbenzenesec-ButylbenzeneC11-C22Aromatics4-IsopropyltolueneMethyleneChlorideStyrene1-MethylnaphthaleneRALs(mg/kg)
Soil-to-WaterMCCs(mg/kg)C9-C18AliphaticsC19-C36Aliphatics1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneTotalXylenesMTBENaphthalenen-Propylbenzenen-ButylbenzeneIsopropylbenzeneContaminantofConcern2-MethylnaphthaleneC9-C10AromaticsTABLE6
SUMMARYOFSOILSAMPLEANALYTICALRESULTS
MINUTEMAN#3(INCIDENTNO.29769)
AnalyticalMethod
UVF/EPAMethods
5030/8015Band
3550/8015B
EPAMethod8260D MADEPEPH MADEPVPHEPAMethod8270
Page1of2
Date:10/11/2023 FacilityID#:00-0-0000009436
EPA
Method
504.1
EPA
Method
6010B
SampleIDDateSampled1 600 600 500 20 6 70 70 70 400 400 1 30 0.02 15 400 700 10,000 200
5,000 260,000 80,000 50,000 20,000 6,000 30,500 70,000 30,000 28,500 24,100 1,000 12,000 50 15,000 NE NE NE NE
12/10/12 779 8,210 1,030 5,350 26.1 184 34.2 6.7J 114 893 203 NR 191 2.2 37.9 8,090 4,970 <98 9,564
07/20/17 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
04/08/19 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
10/22/19 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
09/15/20 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
06/01/21 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
03/13/23 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
07/20/17 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
04/08/19 129J 9,210 3,750 17,100 <31903 NR <31NR NR NR NR NR NR NR NR NR NR NR
10/22/19 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
09/15/20 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
06/01/21 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
03/13/23 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
07/20/17 38.7 618 270 1,390 <3.193.4 23.3 <3.192 595 171 8.3 15.9 0.14 286 NR NR NR NR
04/08/19 40.1 694 554 2,610 <3.1217 NR <3.1NR NR NR NR NR NR NR NR NR NR NR
10/22/19 812 10,300 1,280 6,810 <3.1408 NR <3.1NR NR NR NR NR NR NR NR NR NR NR
09/15/20 24.3 249 81.8 380 <0.63 27.8 NR <0.63 NR NR NR NR NR NR NR NR NR NR NR
06/01/21 65.7 868 259 1,230 <3.180.3 10.5J <3.142.4 353 111 NR NR NR NR NR NR NR NR
03/13/23 1,240 10,400 1,360 6,940 <14.0 311 34.8J <50.0 77.8 822 314 NR NR NR NR NR NR NR NR
07/20/17 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
04/08/19 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
10/22/19 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
09/15/20 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
06/01/21 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
03/13/23 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
MADEPMethodsVPHandEPH
C9-C22AromaticsMAC(µg/l)EDBLead2-MethylnaphthaleneIsopropylbenzene1,2,4-TrimethylbenzeneC19-C36AliphaticsAnalyticalMethod EPAMethod6200B/EPA602
n-Propylbenzene1,3,5-TrimethylbenzeneEPAMethod625
1-MethylnaphthaleneTABLE7
SUMMARYOFGROUNDWATERSAMPLEANALYTICALRESULTS
MINUTEMAN#3(INCIDENTNO.29769)BenzeneTolueneEthylbenzeneXylenesMTBENaphthaleneIPEC5-C8AliphaticsC9-C18AliphaticsGCL(µg/l)
ContaminantofConcern
MW-1
MW-2
MW-3
MW-4
Page1of2
Date:10/11/2023 FacilityID#:00-0-0000009436
EPA
Method
504.1
EPA
Method
6010B
SampleIDDateSampled1 600 600 500 20 6 70 70 70 400 400 1 30 0.02 15 400 700 10,000 200
5,000 260,000 80,000 50,000 20,000 6,000 30,500 70,000 30,000 28,500 24,100 1,000 12,000 50 15,000 NE NE NE NE
MADEPMethodsVPHandEPH
C9-C22AromaticsMAC(µg/l)EDBLead2-MethylnaphthaleneIsopropylbenzene1,2,4-TrimethylbenzeneC19-C36AliphaticsAnalyticalMethod EPAMethod6200B/EPA602
n-Propylbenzene1,3,5-TrimethylbenzeneEPAMethod625
1-MethylnaphthaleneTABLE7
SUMMARYOFGROUNDWATERSAMPLEANALYTICALRESULTS
MINUTEMAN#3(INCIDENTNO.29769)BenzeneTolueneEthylbenzeneXylenesMTBENaphthaleneIPEC5-C8AliphaticsC9-C18AliphaticsGCL(µg/l)
ContaminantofConcern
07/20/17 111 3,930 688 3,380 4.8J 128 21.9 <3.162.3 504 133 14.4 23.7 <0.0098203 NR NR NR NR
04/08/19 126 3,920 1,200 5,210 <13291 NR <13NR NR NR NR NR NR NR NR NR NR NR
10/22/19 195 7,520 2,320 9,510 <13521 NR <13NR NR NR NR NR NR NR NR NR NR NR
09/15/20 202 6,540 1,890 8,220 <25 386 NR <25 NR NR NR NR NR NR NR NR NR NR NR
06/01/21 91 4,080 1,490 5,910 <13278 30.7J <1391 955 268 NR NR NR NR NR NR NR NR
03/13/23 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
07/20/17 77.1 5,680 1,680 9,280 <13466 90.2 <13296 2,200 637 39.6 68.6 <0.009796.1 NR NR NR NR
04/08/19 9.9 482 307 1,040 <1.3134 NR <1.3NR NR NR NR NR NR NR NR NR NR NR
10/22/19 60.5 3,050 416 2,530 <2.5241 NR <2.5NR NR NR NR NR NR NR NR NR NR NR
09/15/20 22.4J 1,660 514 2,860 <6.3 99.6 NR <6.3 NR NR NR NR NR NR NR NR NR NR NR
06/01/21 9.5J 954 263 1,380 <2.5171 9.6J <2.538.5 358 99.8 NR NR NR NR NR NR NR NR
03/13/23 50.8 2,030 190 1,320 <1.40 <4.70 6.81 <5.00 12.1 126 69.0 NR NR NR NR NR NR NR NR
MW-7 03/13/23 0.954 4.12 0.925 5.17 <0.140 <0.470 <0.180 <0.500 <0.190 1.29 0.385J NR NR <0.00342 9 <11.5 28.3J <135 <70.82
MW-8 03/13/23 0.626 5.68 2.51 8.59 <0.140 0.618J 0.752 <0.500 1.77 3.67 1.27 NR NR <0.00342 <2 329 42.2J <135 9.45J
MW-9 03/13/23 9.26 124 103 298 <1.40 52.7 16.9 <5.00 45.5 91.0 62.2 NR NR 0.0167J 2J 1,040 54.9 <124 706.8J
MW-10 03/13/23 <0.180 <0.220 <0.170 <0.21 <0.140 <0.470 <0.180 <0.500 <0.190 <0.190 <0.180 NR NR <0.00342 2J <11.5 <57.5 <139 <72.82
MW-11 03/13/23 56.6 2.75 45.7 108 0.241J 2.16 1.91 <0.500 2.86 2.14 6.71 NR NR <0.00348 9 114 129J <124 32.9J
MW-12 09/21/23 1.92 34.9 110 1,140 <0.140 42.8 16.1 <0.500 34.3 451 135 NR NR <0.00343 6 584 1,090 <124 1,121.9
MW-13 09/21/23 0.631 8.85 46.0 301 0.231J 53.1 6.42 0.500M 16.0 336 109 NR NR <0.00347 2J 353 1,000 <124 773.6J
TW-1 03/13/23 <0.180 0.441J <0.170 <0.21 <0.140 <0.470 <0.180 <0.500 <0.190 <0.190 <0.180 NR NR <0.00345 3J <11.5 <58.2 <143 <74.32
03/13/23 <0.180 <0.220 <0.170 <0.21 <0.140 <0.470 <0.180 <0.500 <0.190 <0.190 <0.180 NR NR NR NR NR NR NR NR
09/21/23 <0.180 <0.220 <0.170 <0.21 <0.140 <0.470 <0.180 <0.500 <0.190 <0.190 <0.180 NR NR NR NR NR NR NR NR
MW-5
MW-6
TripBlank
Page2of2
Date:06/16/2021
MethodofMeasurement:
WellID ProductType
(gas,diesel,etc.)
Dateof
Recovery
(mm/dd/yy)
FreeProduct
Recovery
Method*
Casing
Diameter
(inches)
ProductThickness
beforeRecovery
(feet)
ProductThickness
afterRecovery
(feet)
AmountofLiquid
Recovered
(gallons)
Amountof
Product
Recovered
(gallons)
MW-2 Gasoline,diesel
andkerosene07/20/17 HandBailing 2 1.31 -0.50 0.50
MW-1 2 1.70 -
MW-2 2 1.01 -
MW-4 2 0.26 -
MW-1 2 1.00 -
MW-4 2 0.26 -
MW-1 2 0.78 -
MW-2 2 1.12 0.63
MW-4 2 1.31 -
Notes:
•*:Bailing,Skimming,AggressiveFluidVaporRecovery(AFVR),MobileMultiphaseExtraction(MMPE)
•AmountofLiquidRecovered(gallons)includesTotalliquids(WaterandFreeProduct)asindicatedonDisposalManifest.
•AmountofProductRecovered(ingallons)includesonlythevolumeoffreeproductinthetankerattheendoftheevent(basedonDisposalManifest
and/orFieldNotes).
0.002,784.28AFVR09/17/19Gasoline,diesel
andkerosene
AFVR02/28/19Gasoline,diesel
andkerosene0.062,784.00
TABLE8
FREEPRODUCTRECOVERYRESULTS
MINUTEMAN#3(INCIDENTNO.29769)
FacilityID#:00-0-0000009436
Interfaceprobeattop-of-casing
0.0019,789.00MMPE04/12/2021-
04/16/2021
Gasoline,diesel
andkerosene
Page1of1
Date:06/16/2021
MW-2 07/20/17 HandBailing ------------0.50 0.50 0.50
MW-1,MW-2,
andMW-4 02/28/19 AFVR 673.08 83.28 482.78 0.06 2,784.00 0.00 0.06
MW-1and
MW-4 09/17/19 AFVR 333.00 94.6 3,327.90 0.27 2,784.28 0.00 0.27
MW-1,MW-2,
andMW-4 04/12/2021-
04/16/2021 MMPE 325.39 78.74 1,307.61 0.26 19,789.00 0.00 0.26
0.59 25,357.78 0.50 1.09
Notes:
•*:Bailing,Skimming,AggressiveFluidVaporRecovery(AFVR),MobileMultiphaseExtraction(MMPE)
•AmountofVaporizedProduct(ingallons)isbasedonVaporEmissionsSummarySheet,=lbsemitted/6.25
•AmountofLiquidRecoveredincludesTotalliquids(WaterandFreeProduct)asindicatedonDisposalManifest.
•AmountofProductRecoveredasLiquidincludesonlythevolumeoffreeproductinthetankerattheendoftheevent(basedonDisposal
Manifestand/orFieldNotes).
•TotalAmountofProductRecovered=AmountofVaporizedProduct+AmountofProductRecoveredasLiquid
•TotalFluidsRemoved=AmountofVaporizedProduct+AmountofLiquidRecovered
•Informationregardinghistoricalfreeproductrecoveryactivitiesisnotavailable.
Amountof
Vaporized
Product
(gallons)
Amountof
Liquid
Recovered
(gallons)
Amountof
Product
Recoveredas
Liquid(gallons)
TotalAmount
ofProduct
Recovered
(gallons)
TABLE9
FREEPRODUCTRECOVERYEVENTINFORMATION
MINUTEMAN#3(INCIDENTNO.29769)
FacilityID#:00-0-0000009436
WellID Date
(mm/dd/yy)
Product
Recovery
Method*
Average
Effluent
Velocity
(ft/min)
Average
Effluent
Temperature
(°F)
Average
Effluent
Concentration
(ppm)
Total 25,357.78 1.09
Totals
SUMMARYOFFLUIDREMOVAL
Summary TotalFluidsRemoved(ingallons)TotalProductRemoved(ingallons)
Page1of1
Date:06/16/2021
WellsIncludedin
Event
Product
Recovery
Method*
DateofEvent
(mm/dd/yy)
TotalAmountof
VaporPhaseand
Liquids
Recovered
(gallons)
CostofFree
Product
Recovery
Event
CostPer
Gallon
Recovered
MW-2 HandBailing 07/20/17 0.50 $177.00$354.00
MW-1,MW-2,
andMW-4 AFVR 02/28/19 2,784.06 $2,841.40$1.02
MW-1andMW-4 AFVR 09/17/19 2,785.96 $2,788.00$1.00
MW-1,MW-2,
andMW-4 MMPE 04/12/2021-
04/16/2021 19,789.26 $14,037.95$0.71
25,359.78 $19,844.35 $0.78
Notes:
•*:Bailing,Skimming,AggressiveFluidVaporRecovery(AFVR),MobileMultiphaseExtraction(MMPE)
•N/A:groundwatersampleswerenotcollectedbeforeand/oraftertheeventtoprovidedataforanalysis.
•CostofFreeProductRecoveryEventincludessupervision,travel,mileage,perdiem,subcontractorcosts,reportpreparationand
projectmanagement.
Costpergallonfortheeventisbased
onatotalvolumeoffreeproductand
water.
TOTAL(todate)
TABLE10
FREEPRODUCTRECOVERYCOSTSUMMARY
MINUTEMAN#3(INCIDENTNO.29769)
Comments
Costpergallonfortheeventisbased
onatotalvolumeof2,784.06gallons
offreeproductandwater.
FacilityID#:00-0-0000009436
Costpergallonfortheeventisbased
onatotalvolumeof2,785.96gallons
offreeproductandwater.
Costpergallonfortheeventisbased
onatotalvolumeof19,789.26gallons
offreeproductandwater.
Page1of1
Date:10/11/2023
12/10/12 13.97 ---86.03 ---
07/20/17 12.91 1.10 88.03 ---
02/28/19 10.54 1.70 90.92 PreAFVR
02/28/19 9.62 ---90.38 PostAFVR
04/08/19 8.96 0.02 91.06 ---
09/17/19 12.78 1.00 88.08 PreAFVR
09/17/19 12.02 ---87.98 PostAFVR
10/22/19 12.45 0.05 87.59 ---
09/15/20 10.71 1.30 77.74 ---
04/12/21 9.51 0.78 91.16 PreMMPE
04/16/21 10.17 ---89.83 PostMMPE
06/01/21 11.49 0.17 88.66
03/13/23 14.35 0.74 86.28
09/21/23 13.62 1.35 87.54
07/20/17 13.57 1.31 88.42 ---
02/28/19 11.01 1.01 90.73 PreAFVR
02/28/19 10.27 ---90.60 PostAFVR
04/08/19 9.87 ---91.00 ---
10/22/19 13.12 0.03 87.78 ---
09/15/20 12.01 0.30 76.51 ---
04/12/21 9.27 1.12 92.56 PreMMPE
04/16/21 10.21 0.63 91.20 PostMMPE
06/01/21 12.30 0.21 88.75
03/13/23 14.65 0.31 86.49
09/21/23 13.46 0.29 88.18
07/20/17 12.77 ---87.98 ---
04/08/19 9.57 ---91.18 ---
10/22/19 13.24 ---87.51 ---
09/15/20 11.78 ---88.97 ---
06/01/21 12.05 ---88.70
03/13/23 14.51 ---86.24
09/21/23 13.56 0.37 87.51
07/20/17 12.68 0.67 88.09 ---
02/28/19 9.48 0.26 90.94 PreAFVR
02/28/19 9.44 ---90.76 PostAFVR
04/08/19 9.06 0.07 91.20 ---
09/17/19 12.38 0.26 88.04 PreAFVR
09/17/19 12.20 ---88.00 PostAFVR
10/22/19 12.61 0.23 87.79 ---
09/15/20 11.95 1.08 76.65 ---
04/12/21 9.87 1.31 91.45 PreMMPE
04/16/21 10.56 ---89.64 PostMMPE
06/01/21 12.50 1.27 88.79
03/13/23 15.13 1.49 86.35
09/21/23 14.98 2.87 87.68
07/20/17 12.31 ---88.03 ---
04/08/19 9.11 ---91.23 ---
10/22/19 12.79 ---87.55 ---
09/15/20 11.20 ---89.14 ---
06/01/21 11.50 ---88.84
03/13/23 14.31 0.36 86.34
09/21/23 13.17 0.33 87.45
07/20/17 12.22 ---88.07 ---
04/08/19 9.04 ---91.25 ---
10/22/19 13.01 ---87.28 ---
09/15/20 11.13 ---89.16 ---
06/01/21 11.45 ---88.84
03/13/23 13.98 ---86.31
09/21/23 12.80 0.03 87.51
03/13/23 14.41 ---86.30
09/21/23 13.25 ---87.46
03/13/23 14.45 ---86.31
09/21/23 13.31 ---87.45
03/13/23 14.48 ---86.29
09/21/23 13.33 ---87.44
03/13/23 15.13 ---86.17
09/21/23 13.93 ---87.37
03/13/23 14.89 ---86.15
09/21/23 13.69 ---87.35
MW-12 09/12/23 09/21/23 5 5-20 20 101.54 14.11 ---87.43
MW-13 09/12/23 09/21/23 5 5-20 20 100.98 13.49 ---87.49
03/13/23 13.64 ---86.22
09/21/23 13.54 ---86.32
RBP-17 Unknown 03/13/23 7 7-20 20 100.29 NM NM NM
RBP-42 06/06/12 03/13/23 5.5 5.5-15.5 15.5 100.93 NM NM NM
Notes:
MINUTEMAN#3(INCIDENTNO.29769)
TABLE11
WELLCONSTRUCTIONANDGAUGINGINFORMATION
FacilityID#:00-0-0000009436
•ftBGS:feetbelowgroundsurface.
10 10-20
100.87
MW-6 07/05/17
MW-5 07/05/17
MW-3 07/05/17
5 5-20
•NA:NotAvailable
Bottom
ofWell
(ft.BGS)
Topof
Casing
Elevation
(ft.)
Depthto
Waterfrom
TopofCasing
(feet)
FreeProduct
Thickness
(ft.)
Ground
Water
Elevation(ft.)
CommentsWellID
Date
Installed
(mm/dd/yy)
DateWaterLevel
Measured
(mm/dd/yy)
Well
Casing
Depth
(ft.BGS)
Screened
Interval
(xtoyft.
BGS)
100.75
5 5-20 20
20 100.29
5 5-20 20
TW-1 03/09/23
MW-11 03/08/23
40
5
40-45 45 99.86
101.04205-20
101.30
MW-9 03/08/23 5 5-20 20 100.77
MW-10 03/08/23 5 5-20 20
100.76
MW-7 03/08/23 5 5-20 20 100.71
MW-8 03/08/23 5 5-20 20
20 100.00
100.34
MW-4 07/05/17 5 5-20 20 100.20
MW-2 07/05/17
MW-1 12/10/12
5 5-20 20
Page1of1
FacilityID#:00-0-0000009436
ft/min ft/day ft/day ft/year
MW-7 1.280E-01 1.843E+02 6.14E-01 2.24E+02
MW-8 2.557E+00 3.682E+03 1.23E+01 4.48E+03
Averages 1.343E+00 1.933E+03 6.44E+00 2.35E+03
TW-1 2.586E-03 3.724E+00 2.48E-02 9.06E+00
Note:
Seepagevelocitiescalculatedusingtheequationv=K(dh/dl)/ne,where:
K=hydraulicconductivity
ne=effectiveporosity=0.30forTypeIIwells,0.15forTypeIIIwells
dh/dl=hydraulicgradient=0.001ft/ft
TABLE12
SUMMARYOFSLUGTESTANALYSES
MINUTEMAN#3(INCIDENTNO.29769)
Date:03/28/23
Well HydraulicConductivity(K)SeepageVelocity(v)
Page1of1

APPENDICES

APPENDIX A
State Correspondence

November 17, 2021

Campbell Oil and Gas Company
Jill Smith
P.O. Box 637
Elizabethtown, NC 28337-0637

Re: Notice of Regulatory Requirements
15A NCAC 2L .0407(d)
Risk-based Assessment and Corrective Action for
Petroleum Underground Storage Tanks

Minuteman #3
Hwy 24 and Hwy 211
Roseboro, Sampson County
Incident Number: 29769
Risk Classification: Intermediate
Ranking: I1704

Dear Jim Smith:

A review of information on file with the Underground Storage Tank (UST) Section, Division of
Waste Management, Fayetteville Regional Office indicates that the risk posed by the discharge or release
at the subject site is classified by the Department of Environmental Quality as intermediate, as stipulated
under Title 15A NCAC 2L .0406. The land use at the site is classified as industrial/commercial. Title
15A NCAC 2L .0407(a) requires you to notify the Department of any changes that might affect the risk or
land use classifications that have been assigned.

Title 15A NCAC 2L .0407(d) requires you to comply with assessment and cleanup requirements
of Title 15A NCAC 2N .0706 and Title 15A NCAC 2L .0106(c) and 2L .0106(g). A Comprehensive Site
Assessment (CSA) Report prepared in accordance with these requirements and the most recent version of
the UST Section Assessment Guidelines must be received by this office within 90 days of the date of this
notice. In addition, you must submit a summary of the CSA Report to the local Health Director and the
local Chief Administrative Officer in accordance with 15A NCAC 2L .0114. The summary should be
submitted to these persons no later than five working days after submittal of the CSA Report to this
office. Failure to comply in the manner and time specified, may result in the assessment of civil penalties
and /or the use of other enforcement mechanisms. UST guidance documents can be found on the UST
Section’s website at https://deq.nc.gov/about/divisions/waste-management/ust/guidance-documents.

Effective October 1, 2004, the Department requires that all work following the submittal of the
Limited Site Assessment Report (Title 15A NCAC 2L .0405) be preapproved if State Trust Fund
reimbursement is anticipated. To comply with this requirement, a completed Preapproval/Claim
Authorization Form, encompassing the required remedial activities, must be received in this office within
14 days of the date of this letter. Upon completion of the preapproved activities, you should submit your
claim promptly.

3148 Received NOV 19 2021

North Carolina Department of Environmental Quality | Division of Waste Management
Fayetteville Regional Office | 225 Green Street | Suite 714 | Systel Building | Fayetteville,
NC 28301 | [phone]

Reimbursement funds are budgeted based on completed preapprovals, but lengthy delays in
reimbursement can occur if claims are not submitted immediately following work completion.

Because a release or discharge has been confirmed, a Licensed Geologist or a Professional
Engineer, certified by the State of North Carolina, is required to prepare and certify all reports submitted
to the Department in accordance with Title 15A NCAC 2L .0103(e) and 2L .0111(b).

If you have any questions regarding trust fund eligibility or reimbursement from the Commercial
or Noncommercial Leaking Petroleum Underground Storage Tank Cleanup Funds, please contact the
UST Section Trust Fund Branch at [phone]. If you have any questions regarding the actions that
must be taken or the rules mentioned in this letter, please contact me at the address or telephone number
listed below.

Sincerely,

James W. Brown
Hydrogeologist
Fayetteville Regional Office
UST Section, Division of Waste Management, NCDEQ

cc: Rae Brown – GRI (e-mail)

Site Name City / County /Sampson Incident #29769
Resp Pty Name / Contact /Incident Mgr Region FAY
RP Type (Owner/Operator / Landowner / Attny-in-fact)Change Order?Prev. TA #8
Consultant / Project Mgr /Laura Minor
Telephone / Fax Number /Task Authorization Number:9 ChangeOrd:
Project Mgr Email Site Risk / Rank / Abatement:I180D RRA Date:8/29/2016
Proposal# / Scope Dates /% Commercial (C=100%, NC=0%, Both=1%-99%)
Has STF Eligibility Been Determined? (Y/N)Site Status (Active or NFA Date)
With Claim: [ ] All Main Consultant/Contractor invoices attached?[ ] Proof of payment attached directly to the front of each invoice?
Important: The date of reimbursement is dependent on the Trust Fund balance. There may be a delay in the reimbursement of claims for work under this ePATA.3rd Pty Ded?Task #Lab /
SubCode RO AuthProposed
Rate/Price
(Consultant)CO AuthProposed Task
Subtotal
(Consultant)
Final
Preapproved
Subtotal
(UST Section)
Claimed
Amount3
(Consultant)
1.050 2 /agreement Y $300.00 Y $600.00 $600.00 /
3.080 2 /permit Y $250.00 Y $500.00 $500.00 /
3.101 140 /feet Y $12.50 Y $1,750.00 $1,750.00 /
3.101 45 /feet Y $18.00 Y $810.00 $810.00 /
3.111 40 /feet Y $20.00 Y $800.00 $800.00 /
3.113 100 /feet Y $50.00 Y $5,000.00 $5,000.00 /
3.115 45 /feet Y $75.00 Y $3,375.00 $3,375.00 /
3.118 225 /feet Y $5.00 Y $1,125.00 $1,125.00 /
3.351 6 /wells Y $80.00 Y $480.00 $480.00 /
3.397 2 /Mobes Y $100.00 Y $200.00 $200.00 /
3.398 2 /Mobes Y $350.00 Y $700.00 $700.00 /
3.500 3 /nights Y $151.00 Y $453.00 $453.00 /
4.031 12 /wells Y $110.00 Y $1,320.00 $1,320.00 /
4.080 20 /sample pt.Y $45.00 Y $900.00 $900.00 /
4.090 #240 12 /samples Y $94.00 Y $1,128.00 $1,128.00 /
4.090 #272 1 /sample Y $66.00 Y $66.00 $66.00 /
4.090 #280 6 /samples Y $45.00 Y $270.00 $270.00 /
4.090 #301 6 /samples Y $208.00 Y $1,248.00 $1,248.00 /
4.090 #330 6 /samples Y $14.00 Y $84.00 $84.00 /
4.090 #341 6 /samples Y $56.00 Y $336.00 $336.00 /
4.090 #342 6 /samples Y $100.00 Y $600.00 $600.00 /
4.090 #409 2 /samples Y $84.00 Y $168.00 $168.00 /
4.090 #410 2 /samples Y $187.00 Y $374.00 $374.00 /
4.090 #421 2 /samples Y $58.00 Y $116.00 $116.00 /
4.090 #422 2 /samples Y $100.00 Y $200.00 $200.00 /
4.090 #590 2 /samples Y $38.00 Y $76.00 $76.00 /
4.090 #640 2 /samples Y $129.00 Y $258.00 $258.00 /
4.091 2 /shipment Y $60.00 Y $120.00 $120.00 /
5.010 1 /site Y $1,300.00 Y $1,300.00 $1,300.00 /
6.050 1 /report Y $4,400.00 Y $4,400.00 $4,400.00 /
6.082 1 /report Y $500.00 Y $500.00 $500.00 /
12.030 3 /nights Y $151.00 Y $453.00 $453.00 /
12.050 3 /trip Y $250.00 Y $750.00 $750.00 /
12.055 3 /trip Y $50.00 Y $150.00 $150.00 /
//
//
Requested Preapproved Claimed3
TOTAL:$30,610.00 $30,610.00 TOTAL:
Total Standard Costs (Not Third Party)$30,610.00 $30,610.00 Total Standard Costs
Total applied as Third Party Deductible/Damage Costs $0.00 $0.00 Total Third Pty Costs
Process Tracking (Date)
TA Submittal:11/16/22 by:(PM)(Reserved for RO)
RO Review:11/16/22 by:(IM)Joint UST Preapproval Confirmed By:Date1 11/18/2022
CO Review:11/17/22 by:(STF)RP or Designee Receipt Confirmed By:Date 4
1 - This ePATA expires one year from the Joint UST Preapproval date. This does not extend, alter, or supersede any regulatory deadlines (e.g., NORR's, NOV's, Enforcements, etc.)
2 - THE ONE YEAR STATUTE OF LIMITATIONS APPLIES TO EACH INDIVIDUAL TASK. Costs must be claimed within one year of completion of that task to be reimbursable.
3 - Only Tasks included on this ePATA may be claimed. Do not include other Tasks or claimed costs (i.e., Claim preparation) that were not preapproved or the claim will be returned.
4 - Preapproval is not valid (i.e., claimable) until receipt is signed as 'Confirmed' by the RP or their designee and returned to the Trust Fund within a week of approval. Signature
indicates acknowledgement of the tasks and amounts approved. Any objections/appeals must be submitted via Change Order prior to work proceeding. Scope/cost
negotiations do not supersede other regulatory deadlines as described in #1 above. Also, any ePATA that has been signed as 'Confirmed' by both the UST Section and RP
is not to be modified without written consent by all signatories.
5 - Tasks approved on Directed - CAB Only ePATAs must be performed in accordance with all applicable rules, statutes, and RRD Task Scopes of Work to be reimbursed in full.
DWM/UST ePATA 4/1/2022
LJM
Proposed
Units / Type
(Consultant)
MIKE HASELTINE
activeYES
22-642 11/2022-1/2023
704-845-4012
Dates of Work
(Consultant)
Started1 / Completed2
FINAL REIMBURSEMENT
NO
[e-mail]
Campbell Oil & Gas Company Jill Smith
Geological Resources, Inc.
DIRECTED COSTS
Roseboro
(Must Complete with Claim Submittal)(See Instructions / RRD for Tasks requiring Preapproval / Task Authorization)
Owner/Operator
704-845-4010
(Reserved for Incident Manager)
PREAPPROVAL / TASK AUTHORIZATION
Minute Man #3
Note:This ElectronicPreapproval Task Authorization (ePATA)shall be used to receive preapprovalfrom the UST Section.Aproposal,includingmaps andfigures,must be attached to
elaborate on the costsforthe tasks listed below that describes thescopeof work and the rationalefor theproposed activities.If,followingcompletion of this ePATA,you discover that
unexpectedtasks must be performed,incurring costs for tasksnotoriginallyincluded withthisform,you must complete andsubmit aseparateePATArequestdesignated as a "Change
Order"intheprovidedspaceabove prior to conductingthose tasks.Includea copy of theprior ePATA form forconfirmation.Please attachthis form to the cover of thecorresponding
claim when requesting reimbursement.IMPORTANT:Only one claim may be submitted per ePATA and all work on the ePATA must have been completed within 12 months of the
completion date of the FIRST completed task to remain within the Statute of Limitations.All ePATAs submitted within a claim are closedwith that claim,and may not be re-used ina
separate submittal,even for costs or tasks that were not originally claimed.Final reimbursement of costs associated with the Total Claimed amount below may be affected by the
eligibility status of the site (i.e.,deductibles,apportionment,etc.),and thedocumentary validation of incurred costs as reasonable andnecessaryexpenses per 15ANCAC 2P .0402 and
.0404.
MHH
WER
(Initials)
ELECTRONIC PREAPPROVAL TASK AUTHORIZATION FORM
Dept of Environmental Quality -Division of Waste Management
3148 Received NOV 19 2022
11/19/2022

APPENDIX B
NCDEQ Incident Reports
NCDEQ Incident Report
RP/Company LEE MOORE OIL CO., INC.
RPAddress P.O. DRAWER 9
RPCity SANFORD
Contact LINDA HARRIS
RPState NC
TELEPHONE
IncidentNumber 12362 USTNum FA-686
IncidentName SHORT STOP 9
FacilID
Address HWY 24
CityTown ROSEBORO State NC
ZipCode 28382-
DateOccurred 12/16/1993
DateReported 12/16/1993
ConfRisk L
CloseOut 9/14/1998
COMMENT
file archived 1/20/2004
RptType Rcvd Rvwd Appvd
Incident Mgr JWBLongitude-78.510184 Latitude 34.956065
County SAMPS
CSA 1/1/1991
CAP 1/1/1992
LSA 9/11/1998 9/14/1998 10/21/2002
Thursday, March 23, 2023 Page 1 of 1
NCDEQ Incident Report
RP/Company CAMPBELL OIL AND GAS COMPANY
RPAddress P.O. BOX 637
RPCity ELIZABETHTOWN
Contact JILL SMITH
RPState NC
TELEPHONE
IncidentNumber 29769 USTNum FA-3861
IncidentName MINUTEMAN # 3
FacilID
Address INTERSECTION OF HWY 24 & 211
CityTown ROSEBORO State NC
ZipCode
DateOccurred 6 /8 /2012
DateReported 6 /8 /2012
ConfRisk I
CloseOut
COMMENT
IAA Report confirmed minor soil contamination in the UST pit area. LSA required. NOV issued 10/30/2012 for failure
to submit an LSA. No response to date 12/10/2012. Issue 10 Day Letter. LSA received and confirmed groundwater
contamination down-gradient of the UST basin above 2L. CSA Norr issued 2/8/2013. Possible source for free product
exist up-gradient of Minuteman # 3 at a closed Short Stop # 9 facility, Incident # 12362 with a NFA dated 9/14/1998.
CSA should assist with a determination of free product source.
RptType Rcvd Rvwd Appvd
Incident Mgr JWBLongitude-78.510196 Latitude 34.956090
County SAMPS
IAA 7/25/2012 7/27/2012 7/27/2012
complete a LSA Report
LSA1 1/24/2013 1/29/2013 2/8/2013
Groundwater contamination confirmed in MW-1 located down-gradient of
UST basin.
Friday, March 24, 2023 Page 1 of 5
MRP 8/7/2017 8/10/2017 9/18/2017
Free product thicknesses of 1.10, 1.31 and 0.67 feet were measured in
MW-1, MW-2 and MW-4,
respectively.
3
An estimated 0.50 gallons of free product were recovered from MW-2
through the use of hand
bailing on July 20, 2017.
The average depth to ground water in the monitoring wells during the
July 2017 sampling event
was 12.74 feet. Ground water flow was generally toward the
north/northeast with an average
horizontal hydraulic gradient of less than 0.01 feet per foot.
Concentrations of one or more individual BTEX constituents,
naphthalene, isopropylbenzene, npropylbenzene,
styrene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, EDB, lead, 1-
methylnaphthalene and/or 2-methylnaphthalene that exceeded the MACs
were reported in the
ground water samples collected from MW-3, MW-5 and MW-6. None of
the reported
contaminant concentrations exceeded the GCLs.
Based on this information, the vertical and horizontal extents of the
contaminant and free product
plumes are not defined. GRI recommends a free product evaluation be
conducted along with
free product recovery events.
A possible former dispenser island appears to have been asphalted over
during past site
renovations. Interviews with local personnel indicate the possibility of a
secondary source
located on the property. Therefore, GRI also recommends using Ground
Penetrating Radar onsite
to investigate the possibility of unregistered orphan tanks that could be
contributing to the free
product plume.
Friday, March 24, 2023 Page 2 of 5
FPRS 5/28/2019 6/12/2018
On February 28, 2019, 2,784 gallons of petroleum impacted ground water
were removed during
an AFVR event conducted on MW-1, MW-2, and MW-4. Prior to the start of
the event, free
product was measured in, and was observed in MW-1 (1.70 feet), MW-2
(1.01 feet), and MW-4
(0.26 feet). No measurable free product was observed in MW-1, MW-2, or
MW-4 at the
conclusion of the event.
On April 8, 2019, average depth to ground water in the Type II
monitoring wells in April 2019
was 9.27 feet. Ground water flow during the April 2019 gauging event was
generally toward the
southeast, with an average horizontal hydraulic gradient of less than 0.01
feet per foot.
During the April 2019 sampling event, free product was measured in MW-
1 (0.02 feet) and MW-
4 (0.07 feet).
Concentrations of one or more BTEX constituents and/or naphthalene
that exceeded the MACs
were reported in the ground water samples collected from MW-2, MW-3,
MW-5, and MW-6.
None of the reported concentrations exceeded the GCLs.
Based on this information, GRI recommends that AFVR and semi-annual
ground water sampling
events continue at the site until free product is removed and contaminant
concentrations do not
exceed the GCLs. The next semi-annual ground water sampling event is
tentatively scheduled
for October 2019.
Friday, March 24, 2023 Page 3 of 5
FPRS 1/14/2020 2/3/2020 2/3/2020
•On September 17, 2019, an AFVR event was conducted at the site on
MW-1 and MW-4.
•A total of 2,784.28 gallons of affected ground water was recovered
during the AFVR event. At the conclusion of the event, no free product was
measured in any of the wells associated with the AFVR event. The average
liquid recovery rate was 464.05 gallons per hour. An additional 0.27 gallons
of vapor phase hydrocarbons were removed at an average rate of 0.05
gallons per hour.
•On October 22, 2019, six Type II monitoring were gauged, purged,
and/or sampled. Monitoring wells MW-1, MW-2, and MW-4 contained free
product and were not sampled. Ground water flow was divergent to the
north and south with a horizontal gradient of less than 0.01 feet per foot.
•The MACs were below the concentraons of benzene, toluene,
ethylbenzene, xylenes, and naphthalene reported in the ground water
samples collected from MW-3, MW-5, and MW-6. All of the reported
contaminant concentrations were below the GCLs.
•The contaminant mass has remained stable in Area 1 and has increased
by 144% and 32% in Areas 2 and 3, respectively. The total contaminant
mass has increased by 4% since July 2017.
•Based on this informaon, the risk classificaon for the site should
remain intermediate risk. Free product recovery events should continue at
the site until free product is no longer present and contaminant
concentrations are below the GCLs. Additional assessment of the extent of
free product and the ground water contaminant plume should be
conducted. Semi-annual ground water monitoring should continue at the
site. The next sampling event is tentatively scheduled for April 2020.
Friday, March 24, 2023 Page 4 of 5
MRP 10/21/2020 10/22/2020 10/22/2020
On September 15, 2020, six Type II monitoring were gauged, purged,
and/or sampled. Monitoring
wells MW-1, MW-2, and MW-4 contained free product and were not
sampled. Ground water
flow was convergent towards the UST basin with a horizontal gradient of
approximately 0.25 feet
per foot.
The MACs were below the concentrations of benzene, toluene,
ethylbenzene, MTBE, and xylenes
reported in the ground water samples collected from MW-3, MW-5,
and/or MW-6. All of the
reported contaminant concentrations were below the GCLs.
The estimated contaminant mass has increased 45% and 109% in Areas 1
and 2, respectively, and
decreased by 17% in Area 3. The total estimated contaminant mass has
increased by 43% since
July 2017.
Based on this information, the risk classification for the site should remain
intermediate risk. Free
product recovery events should continue at the site until free product is no
longer present and
contaminant concentrations are below the GCLs. A Mobile Multi Phase
Extraction event and semiannual
ground water monitoring event should be conducted at the site in February
and March
2021, respectively.
SCH 3/24/2021 3/24/2021 3/24/2021
MRP 8/24/2021 9/15/2021 9/15/2021
Friday, March 24, 2023 Page 5 of 5
NCDEQ Incident Report
RP/Company WELLMAN OIL & PROPANE COMPANY, INC.
RPAddress PO BOX 780
RPCity CLINTON
Contact WILLIAM H. OWEN
RPState NC
TELEPHONE [phone]
Monday, April 3, 2023 Page 1 of 7
IncidentNumber 6601 USTNum FA-233
IncidentName ROSEBORO B.P. STATION
FacilID 00-0-0000008172
Address HWY 24 E.
CityTown ROSEBORO State NC
ZipCode 28382-
DateOccurred 5 /21/1991
DateReported 5 /21/1991
ConfRisk H
CloseOut
COMMENT
CSA received after rerank due to MTBE identified in Roseboro city well # 2. UST's were removed and soil was
excavated and land farmed at Oak Hill Farms. CSA received 10/23/2003 and returned 11/14/2003 due to failure to
complete soil assessment and GW plume deliniation according to Clark Env. UST section review found additional
wells possible along fringe of plume and in area of city well. CSA required on or before 1/15/2004. Note: RP notified
in early January of a change in primary consultant due to conflicts with Clark Env. Letter received of change in
consultant. New consultant is Geological Resources, Inc. Pre-approval received 2/9/2004 requesting a Pre-CAP
monitoring report, site survey, and file review. Site survey and file review approved 2/16/2004 after receipt of the
CSA returned with the soil assessment and removal report on 2/16/2004. Soil Assessment report received and CSA
resubmitted after soil removal complete. CSA approved with deliniation of MTBE plume incomplete to expedite
corrective action. Roseboro Well # 2 sample received from Public Water Supply Branch with MTBE @ 2.7 ppb. Sample
collected 1/28/2004 by Keith Puckett. New consultant Geological Resources, Inc. contracted to complete Corrective
Action.>>>Risk Rank Score: H485R Update received 12/13/2004 from GRI stating that the well owners had been
contacted and that Mr. Hoffman had refused again to abandonment. Letter was issued to Art Barnhardt (AP Section)
for assistance with well abandonment on 12/14/2004. Copies of letters received from AP Section requiring well
owners to allow abandonment of irrigation wells on 1/6/2004. A re-evaluation of the data has confirmed that the risk
/rank score is H 665 R due to 4 non potable wells with contaminants above 2L and two threatened in addition to the
municipal well with MTBE and IPE below the 2L standard and within 500 feet of the plume edge. NORR issued October
13, 2005 requiring implementation of Phase 1 of the Corrective Action Plan that was previously Pre-Approved
October 27,2004. Free product (2 feet) identified in MW-2 in Quarterly Monitoring Report an elevated MTBE levels in
MW-36 and MW-41. Well abandonment occurred at the Hoffman and Hudson residences in addition to the DMW's
designated as DMW- 1, DMW-2, & DMW-7 due to improper construction. Memo issued to AP Section (July 24,2006)
requesting assistance with proper abandonment of Hoffman residence wells after site visit confirmed that the casing
were not removed as required since no grout to prevent removal. Drilling contractor to return on August 10, 2006 to
properly abandon those wells. Pre-Approval Task Authorization received for quarterly monitoring as required in the
CAP on July 25,2006. Pre-Approval to be returned to include free product recovery (MMPE) at MW-2, MW-36 & MW-
41. In addition, the number of wells / samples required for quarterly sampling differs from the proposal. Municipal
well sampling report received on July 27, 2006 identified MTBE in the raw sample @ 1.2 ppb. and .83 ppb in the
treated sample. Several consitituents associated with the chlorination process were identified in the treated sample.
Municipal water well samples received for the month of August were raw @ 2.3 ppb MTBE and treated with
bromomethane and bromochloromethane. No bleed thru of MTBE. AFVR events conducted week of August 29 thru
31 on MW's 2R, MW-41, & MW-36. Public Notice letters issued July 25,2006 and letters,receipts received August 28,
2006. No request were received. Re-rank of site on 10/9/2006 has determined that the new site rank is below the
bar and no additional assessment is required at this time. NORR issued stopping work as of 10/9/2006. October 2006
municipal well sample results received from GRI with no MTBE in treated sample and 1.6 ppb MTBE in raw water
sample. Similar to previous results. MW-36 and MW-41 were sampled during this event due to previous month AFVR
to confirm MTBE reduction for possible future events. Reduction observed in MW-41 from 850 ppb to 770 ppb. NORR
issued 11/08/2006 stopping work after rerank due to closure of wells. Issued funding resumed NORR on 5/16/2007
requiring a Remediation Monitoring Report on 8/16/2007. Municipal water sample results received 3/28/2008 with
raw water @ 2.2 mtbe and no confirmation in treated water. Municipal water sample results received 10/12/2008
with raw water @ 2.28 MTBE. Free product check report received and Acknowledgement Letter issued 6/22/2009.
No free product identified in MW-2A. Review sample results and request HRE for WSW-7. Issue HRE results letter to
Buck Ammon, Town of Roseboro Public Works on 5/11/2010 to include sample results. No free product in MW-2R
Incident Mgr NJBLongitude-78.509380 Latitude 34.956120
County SAMPS
Monday, April 3, 2023 Page 2 of 7
and minor reductions in MW's and public water supply well.
2023.01.15 NJB new incident manager.
RptType Rcvd Rvwd Appvd
CSAS 10/23/2003 11/12/2003 2/17/2004
CSA received and reviewed on 11/14/2003. Returned due to failure to
complete the required soil assessment and to require additional gw
evaluation at the consultants request. Boundaries of GW plume were
questionable according to Clark Bros. Soil assessment submitted with the
CSA for approval on 2/16/2004. CSA approved. However, additional gw
assessment necessary per report.
CAP 7/15/2004 7/27/2004 7/27/2004
CAP proposes Natural Attenuation with the abandonment of non-potable
water supply wells & deep monitoring wells up-gradient of the Municipal
well and quarterly monitoring.
RMR 7/20/2006 7/28/2006 7/28/2006
Remediation Monitoring Report identified several mw's with increased
levels of constituents down gradient of the source and free product in mw
2. MTBE was identified in two mw's at high levels and may require
recovery if levels continue in future monitoring.
RMR 10/4/2006 10/4/2006 10/4/2006
Monitoring Report confirmed three MW-s wirh 2L violations. MTBE levels
remain in 12 shallow mw's and 4 deep mw's at levels below the 2L
standard with the exception of two mw's (mw-36 7 mw-41). Continue
quarterly monitoring thru 2006.
FPRI 10/4/2006 10/4/2006 10/4/2006
FPR was received documenting the recovery event from MW-2R, MW-36,
& MW-41. Very little fp was recovered from MW-2R and only contaminant
reduction of dissolved petroleum was anticipated from MW_36 & MW-41.
RMR 12/31/2007 1/9/2008 1/9/2008
free product identified in MW-2R
RMR 12/12/2008 12/18/2008 12/19/2008
Similar MTBE plume as previous reports with .5 ppb identified in Post
sample for Roseboro City well. Continue semi-annual monitoring. Notify
Keith Puckett of well sample results by phone and by memo with copy of
results.
FPRS 6/17/2009 6/17/2009 6/17/2009
No free product in MW-2 at time of AFVR event
Monday, April 3, 2023 Page 3 of 7
RMR 6/26/2009 7/7/2009 7/7/2009
Report identified two areas where the plume is considered incomplete
delineation. Propose additional wells NW of the release and S of the
release site. Possible additional RP Scotchman.
RMR 1/11/2010 1/14/2010 1/14/2010
FP reported in MW-2R @ .03 feet. Minor reductions in MTBE
contamination observed in MW-37, MW-41 near community water supply
well. Continue semi-annual monitoring.
RMR 8/4/2010 8/4/2010 8/4/2010
No Free Product reported in MW-2R. Minor reductions in petroleum
constituents during this sampling period.
FPRS 8/9/2010 8/10/2010 8/10/2010
Minor reduction observed in the monitoring wells sampled in June. No
additional fp and only minimal vapor phase recovery. Discontinue until
further notice or fp returns.
RMR 1/13/2011 1/14/2011 1/14/2011
No significant constituents level changes in this quarter.
RMR 6/30/2011 7/6/2011 7/6/2011
Chlorinated solvents at low levels were reported in several monitoring
wells located in a residential area with no apparent source. MTBE @ 1.5
ppb identified in raw water from city of Roseboro well.
RMR 12/28/2011 1/10/2012 1/10/2012
Increased Benzene level in up-gradient mw 17. MTBE levels lower in
municipal well in raw water sample (<1ppb). Continue quarterly sampling
of municipal well and semi-annual sampling,
RMR 7/10/2012 7/13/2012 7/13/2012
continue semi-annual monitoring
RMR 1/24/2013 1/28/2013 1/28/2013
continue semi-annual groundwater monitoring to include all monitoring
wells and the public water supply well (raw and treated) in the sampling
event.
RMR 7/15/2013 8/6/2013 8/6/2013
No FP encountered and there were not any GCL violations - continue semi
annual monitoring
Monday, April 3, 2023 Page 4 of 7
RMR 12/27/2013 1/8/2014 1/8/2014
OTH 4/14/2014 4/29/2014 4/29/2014
Municipal Well Sampling Results
RMR 7/24/2014 8/14/2014 8/14/2014
FP detected in upgradient well. Continue with groundwater sampling.
OTH 11/7/2014 12/11/2014 12/11/2014
Municiple Well Sampling Results
RMR 1/29/2015 3/9/2015 3/9/2015
Additional groundwater and fp recoverery will need to be conducted.
RMR 6/25/2015 7/20/2015 7/20/2015
No FP mesasured in most recent event. MW-1R and MW-3R will be
replaced and the number of monitoring wells will be reduced. Next
Sampling Event Dec 2015
MRP 1/21/2016 2/11/2016 2/11/2016
RMR 7/5/2016 8/1/2016 8/1/2016
RMR 3/16/2017 6/5/2017 6/5/2017
Continued monitoring GCL's Next event September 2018
Monday, April 3, 2023 Page 5 of 7
MRP 6/19/2018 8/1/2018 8/3/2018
Ground water flow during the May 2018 sampling event was generally
toward the northeast.
Concentrations of one or more individual BTEX constituents, MTBE,
and/or naphthalene that
exceeded the MACs were reported in the ground water samples collected
from MW-2R, MW-11, MW-
12, MW-20, MW-22, MW-28, MW-37, MW-43 and MW-44.
The concentration of benzene reported in the ground water sample
collected from MW-43 exceeded the
GCL.
Free product was not detected during the May 2018 sampling event.
Based on the available information, no definitive evidence exists that the
free product found in MW-
101 and MW-102 at the EPCO 3-Way Food Mart originated from the
release that occurred at
Roseboro BP.
GRI recommends an additional monitoring event at the site in order to
evaluate the GCL violation in
MW-43. If concentrations continue to increase, a recovery event should be
conducted to reduce
contaminant concentrations. The next ground water sampling event is
tentatively scheduled for
November 2018.
MRP 2/5/2019 2/5/2019 2/5/2019
Free product was not detected during the November 2018 sampling event.
Concentrations of one or more individual BTEX constituents, MTBE,
and/or naphthalene that
exceeded the MACs were reported in the ground water samples collected
from MW-2R, MW-11, MW-
12, MW-17, MW-20, MW-25, MW-43, and MW-44. None of the reported
contaminant concentrations
exceeded the GCLs.
Based on the available information, no definitive evidence exists that the
free product found in MW-
101 and MW-102 at the EPCO 3-Way Food Mart originated from the
release that occurred at
Roseboro BP.
Total BTEX constituent concentrations in MW-43 have decreased 58.75%
from 40,978 μg/l in May
2018 to 16,905 μg/l in November 2018.
GRI recommends continuing monitoring annually at the site until the site
risk can be reduced. The next
ground water sampling event is tentatively scheduled for May 2019.
Monday, April 3, 2023 Page 6 of 7
MRP 12/19/2019 12/19/2019 12/19/2019
•On November 7, 2019, thirteen Type II monitoring wells and one
telescoping well (DMW-3) were gauged, purged and/or sampled. Two wells
were not sampled (MW-17 and MW-19). Ground water flow was generally
to the northeast with a horizontal gradient of less than 0.01 feet per foot.
The vertical gradient between paired wells MW-35 and DMW-3 was less
than 0.01 feet per foot in the downward direction.
•The MACs were below the concentraons of benzene, toluene,
ethylbenzene, xylenes, MTBE, and/or naphthalene, reported in the ground
water samples collected from MW-2R, MW-11, MW- 12, MW-20, MW-22,
MW-25, MW-28, MW-37, MW-43, and MW-44. All of the reported
contaminant concentrations were below the GCLs, except for benzene
concentration in MW-43.
•In January 2010, a second plume on the Roseboro BP site was reported.
However, no definitive evidence exists that the free product from the
Roseboro BP release migrated off site; and, ground water contamination
reported in adjacent property wells may be from the EPCO 3-Way Food
Mart release. Therefore, NCDEQ should direct a comprehensive sampling
event for the EPCO 3-Way Food Mart site to compare with ground water
quality at Roseboro BP and confirm the contaminant flow. No remediation
at Former Roseboro BP should be conducted until these data are reviewed.
•An updated receptor survey should be conducted for the Roseboro BP
and annual ground water monitoring should continue; the next sampling
event is tentatively scheduled for November 2020.
MRP 1/6/2021 2/3/2021 2/3/2021
MRP 3/31/2022 3/31/2022 4/8/2022
Response letter for report noted inconsistent risk ranking (listed as "I" in
summary but describes as "high" in text. Site is ranked as "high".)
Selective data interpretation for contmainant mass estimaten, missing
historical contaminant vs. time vs. groundwater graphs, addressed
comments regarding EPCO 3-Way Food Mart (Incident #29932), and
agreed with recommendation for continued annual sampling. Requested
next sampling event to include Town of Roseboro supply well. Next
sampling due 1/2023. Regarding adjacent incident (29932) - early work by
Clark Environmental installed 4 MW's and a vapor sparge system on the
EPCO property prior to its initial development in approximately 1999 as a
consumer electronics retail store. Believe that air sparge system and
collection trenches pulled FP to EPCO property. Believe that when system
went out of use, FP stayed on EPCO property. No FP in gauged wells. GCL
exceedances in EPCO MW-102 (ethylbenzene, xylenes, naphthalene). 2L
exceedances in MW-2, MW-20, MW-22, MW-35, MW-43, MW-44, DMW-3,
EPCO MW-101, and EPCO MW-102.
Monday, April 3, 2023 Page 7 of 7

APPENDIX C
Site-Specific Health and Safety Plan &
Field Data Sheet

1
GEOLOGICAL RESOURCES, INC.
Site Specific Health and Safety Plan

1.0 General Information:
a. Project name: Minuteman #3
b. Location: Hwy 24 & Hwy 211, Roseboro NC
c. GRI Job #: 3148

2.0 Project Organization:
a. Site Supervisor/H&S Officer: Jacob Brooks
b. Project Manager: Laura Minor 803-371-0997
c. Subcontractor(s):
d. Site Contact: Same as PM

3.0 Safety Plan Preparation:
a. Prepared by & date: Laura Minor 3/3/23
b. Reviewed/approved by & date: T. Kennedy 3/3/23

4.0 Site History and Description:
a. Type of site (i.e., spill, leaking UST system, etc.): LUST site
b. Site/project description: CSA
Soil borings, ground water monitoring well installs, soil & GW sampling

5.0 Potential Hazards:
Physical Hazards: (check)
X Slips X Overhead X Explosion Sun burn X Electricity
X Trips utilities X Noise Cold Weather X Pressurized line/vessels
X Falls X Underground X Pinch points Hot Weather
X
Fire utilities X Burns X Crush X
Check for Weather
alerts and make sure
your phone has the
alerts set for the area

Chemical Hazards: (check)
X Gasoline Used Oil
X Diesel Solvents
Kerosene Antifreeze
New Oil Acid (sample preservative)

Equipment/Vehicular/Other: (i.e., Geoprobe, drill rig, back hoe, track hoe, traffic, skid steer etc.)
GRI support trucks, drill rig, UVF mobile lab

2
Biological Hazards: (i.e., toxic insects, spiders, poisonous plants, poisonous snakes, aggressive dogs)

6.0 Site Organization and Safety Control: (Evaluate the need for site control to protect
persons from exposure to hazardous conditions; i.e. work permits, cones, barricade tape,
exclusion zones, etc.)
a. Work area(s) identified: __Entire site _________________________________________
b. Work area marked _____ Yes_____ No
c. Work area barricaded _____ Yes _____ No
d. Support area established: ________________________________________________
e. Entry and escape routes identified: ________________________________________
f. Rally point identified: _____ Yes ____ No Location:____________________________
g. Emergency shut-off for water identified _____ Yes _____ No
h. Emergency fuel shut-off identified _____ Yes _____ No
i. Site map attached: _____ Yes _____ No
**Emergency Response Procedures**
Action (i.e. shut off all power equipment) Assemble at rally point
Call 911 for medical or utilities emergency Do NOT enter confined spaces
Discuss what to do if …..cut product line, water line, cable/electric line

7.0 Job Activities in Work Plan:
UST Removal x Soil Sampling Manual FP Recovery
Soil Excavation System O&M Other (specify)
x Powered Drilling MMPE/AFVR __________________
Hand Augering x Water sampling __________________

8.0 Required Education and/or Training:
X OSHA 40 hr X Annual 8 hr Refresher OSHA Site Supervisor

9.0 Air Monitoring:
If, in the opinion of the site supervisor, petroleum hydrocarbon vapor concentrations are
excessive, site activities will cease until petroleum hydrocarbon vapor concentrations diminish to
acceptable levels.

10.0 Equipment:
FID/PID Combustible gas indicator X Interface Probe
O2 meter x Other Water level meter

11.0 Personnel Protection Equipment:
X Hard hat Rubber boots Respirator X Hearing
X Safety glasses X Work gloves Sun screen protection
X Steel toe boots X First aid kit Repellent X Nitrile
Tyvek suit X Fire extinguisher Dust mask gloves

3
12.0 Decontamination Procedures: (evaluate need for decon, describe procedures)
Use Alconox and DI water to decontaminate WLM between gauging each well. Use new, clean
bailers, gloves and string for each temporary monitoring well. Decon augers/rods as needed.

13.0 Emergency Contacts:
a. Local Assistance:
Site Phone Fire Department 911
Police 911 Ambulance 911
Water Department Sanitary Sewer
Natural Gas Power Company

b. National or Regional Sources of Assistance:
1) Geological Resources, Inc. [phone]
2) Chemtrec (24 Hours) [phone]
3) Bureau of Explosives (24 Hours) [phone]
4) National Response Center, NRC [phone]
(Oil/Hazardous Substances)
5) DOT, Off. Of Haz. Operations [phone]

14.0 Signatures:

This plan has been reviewed by all on-site personnel and all provisions are clear (signatures
required).

Project Manager:
3/3/23
Site Supervisor:
Other personnel:

4
15.0 Amendments:

a. Site Specific Health and Safety Plans are based on information available at the time of
plan preparation. Unexpected conditions may arise. It is important that personal
protective measures be thoroughly assessed prior to and during the planned activities.
Unplanned activities and/or changes in the hazard status should initiate a review of this
plan and may result in major changes to it.
b. Changes in the hazard status or unplanned activities are to be submitted on “Amendment
to the Site Specific Health and Safety Plan” which is included bellow.
c. Amendment must be approved by the Project Manager prior to implementation of the
amendment.

AMENDMENT TO THE SITE SPECIFIC HEALTH AND SAFETY PLAN

A. Changes in field activities or hazards:

B. Proposed amendment:

C. Approval:

Proposed by: ___________________________________date ______________________

Approved by: ___________________________________date _____________________

Amendment number: ____________________________

Amendment effective date: _______________________

APPENDIX D
Roseboro Zoning Map
70

APPENDIX E
Well Permits, Well Construction Records and Subsurface Logs
3148

STATE OF NORTH CAROLINA
DEPARTMENT OF TRANSPORTATION
ROY COOPER J. ERIC BOYETTE GOVERNOR SECRETARY

Mailing Address:
NC DEPARTMENT OF TRANSPORTATION
DISTRICT ENGINEER’S OFFICE
220 NORTH BOULEVARD
CLINTON, NC 28328
Telephone: [phone]
Fax: [phone]
Customer Service: 1-877-368-4968

Website: ncdot.gov
Location:
220 NORTH BOULEVARD
CLINTON, NC 28328

June 6, 2023
Division 3, District 2
Sampson County

Geological Resources, Inc
3502 Hayes Road
Monroe, NC 28110

Subject: Request for revision to a NCDOT Encroachment Agreement:
(E032-082-23-00006-R1) Revision to Encroachment agreement located on
SR 1515 in Sampson County.

Dear Applicant,

This letter shall serve as approval for the requested revision to NCDOT Encroachment
agreement E032-082-23-00006. Geological Resources Inc has requested a revision to the
previously approved encroachment agreement to add two additional monitoring wells as
shown on the attached plans.

All conditions of the original permit shall remain in effect.

Please refer to Encroachment agreement E032-082-23-00006 in all future correspondence
with this office concerning this project.

Sincerely,

J. Patrick Wurzel
Assistant District Engineer
For Chad Kimes P.E.
Division Engineer

NCDOT does not
approve anything
outside of R/W
Est. proposed
locations of 2
additional
monitoring
wells
60' r/w
60' r/w
8' from edge of curb
8' from edge of curb
STATE OF NORTH CAROLINA
DEPARTMENTOF TRANSPORTATION
ROY COOPER J. ERIC BOYETTE
GOVERNOR SECRETARY
Mailing Address:
NC DEPARTMENT OF TRANSPORTATION
DISTRICT ENGINEER’S OFFICE
220 NORTH BOULEVARD
CLINTON, NC 28328
Telephone:[phone]
Fax: [phone]
Customer Service: 1-877-368-4968
Website: ncdot.gov
Location:
220 NORTH BOULEVARD
CLINTON, NC 28328
CL
February 08, 2023 Division 3, District 2 Duplin/Sampson County
Geological Resources, Inc 3502 Hayes Road Monroe, NC 28110
Subject: Encroachment agreement on SR 1515 Reference # E032-082-23-00006
Description: Placement of Two Type II monitoring wells measuring 2” in diameter
Authorization is hereby granted for you to proceed with construction of the attached encroachment agreement. Please notify Clinton District at 910-682-5100 prior to beginning work on NCDOT right of way. The encroaching owner or their agent or contractor must have onsite at all times an executed copy of the approved Encroachment Agreement. (E032-082-23-00006)
This approval is subject to the work being done in accordance with the attached plan sheets, Standard Conditions, and following time restrictions. Time Restriction – Peak Hours Restricted: No lane closures shall be allowed from 6:00am to 9:00am and from 4:00pm to 7:00pm and NO weekend lane closures.
The Continuing Indemnity Bond (Geological Resources, Inc) No. B1259996 is hereby obligated to cover work under this encroachment agreement. After the project has been completed for one year the applicant shall notify Clinton District at 910 682- 5100 and request a final inspection. If found satisfactory the bond will be released.
Please refer to Encroachment Agreement # E032-082-23-00006 in all future correspondence with this office concerning this project.
Sincerely,
Dan Cumbo P.E.
District Engineer
For Chad Kimes P.E.
Division Engineer
FORM R/W 16.1A (Revised February 2021)
STATE OF NORTH CAROLINA
ROUTE PROJECT COUNTY OF
DEPARTMENT OF TRANSPORTATION
-AND-
RIGHT OF WAY ENCROACHMENT AGREEMENT
FOR NON-UTILITY ENCROACHMENTS ON
PRIMARY AND SECONDARY HIGHWAYS
THIS AGREEMENT, made and entered into this the day of , 20 , by and between the Department
of Transportation, party of the first part; and
party of the second part,
W I T N E S S E T H
THAT WHEREAS, the party of the second part desires to encroach on the right of way of the public road designated as
Route(s) , located
with the construction and/or erection of:
WHEREAS, it is to the material advantage of the party of the second part to effect this encroachment, and the
party of the first part in the exercise of authority conferred upon it by statute, is willing to permit the encroachment
within the limits of the right of way as indicated, subject to the conditions of this agreement;
NOW, THEREFORE, IT IS AGREED that the party of the first part hereby grants to the party of the second
part the right and privilege to make this encroachment as shown on attached plan sheet(s), specifications and
special provisions which are made a part hereof upon the following conditions, to wit:
That the said party of the second part binds and obligates himself to install and maintain the encroaching facility in such safe
and proper condition that it will not interfere with or endanger travel upon said highway, nor obstruct nor interfere with the proper
maintenance thereof, to reimburse the party of the first part for the cost incurred for any repairs or maintenance to its roadways
and structures necessary due to the installation and existence of the facilities of the party of the second part, and if at any time the
party of the first part shall require the removal of or changes in the location of the said facilities, that the said party of the second part binds himself, his successors and assigns, to promptly remove or alter the said facilities, in order to conform to the said
requirement, without any cost to the party of the first part.
That the party of the second part agrees to provide during construction and any subsequent maintenance proper signs, signal
lights, flagmen and other warning devices for the protection of traffic in conformance with the latest Manual on Uniform Traffic
Control Devices for Streets and Highways and Amendments or Supplements thereto. Information as to the above rules and
regulations may be obtained from the Division Engineer of the party of the first part.
That the party of the second part hereby agrees to indemnify and save harmless the party of the first part from all damages
and claims for damage that may arise by reason of the installation and maintenance of this encroachment.
It is clearly understood by the party of the second part that the party of the first part will assume no responsibility for any
damage that may be caused to such facilities, within the highway rights of way limits, in carrying out its construction and
maintenance operations.
That the party of the second part agrees to restore all areas disturbed during installation and maintenance to the satisfaction of the Division Engineer of the party of the first part. The party of the second part agrees to exercise every reasonable precaution
during construction and maintenance to prevent eroding of soil; silting or pollution of rivers, streams, lakes, reservoirs, other water
impoundments, ground surfaces or other property; or pollution of the air. There shall be compliance with applicable rules and
regulations of the North Carolina Division of Environmental Management, North Carolina Sedimentation Control Commission, and
with ordinances and regulations of various counties, municipalities and other official agencies relating to pollution prevention and
control. When any installation or maintenance operation disturbs the ground surface and existing ground cover, the party of the
second part agrees to remove and replace the sod or otherwise reestablish the grass cover to meet the satisfaction of the Division Engineer of the party of the first part.
That the party of the second part agrees to assume the actual cost of any inspection of the work considered to be necessary
by the Division Engineer of the party of the first part.
That the party of the second part agrees to have available at the encroaching site, at all times during construction, a copy of this agreement showing evidence of approval by the party of the first part. The party of the first part reserves the right to stop all
work unless evidence of approval can be shown.
Provided the work contained in this agreement is being performed on a completed highway open to traffic; the party of the
second part agrees to give written notice to the Division Engineer of the party of the first part when all work contained herein has
been completed. Unless specifically requested by the party of the first part, written notice of completion of work on highway
projects under construction will not be required.
That in the case of noncompliance with the terms of this agreement by the party of the second part, the party of the first partreserves the right to stop all work until the facility has been brought into compliance or removed from the right of way at no cost to
the party of the first part.
That it is agreed by both parties that this agreement shall become void if actual construction of the work contemplated herein
is not begun within one (1) year from the date of authorization by the party of the first part unless written waiver is secured by the
party of the second part from the party of the first part.

Division 3, District 2 Updated 09/16/2021
Encroachment Agreement Standard Conditions
District Office Contact Information:
220 North Blvd
Clinton, NC 28328
[phone]
The Standard Conditions in this document apply to this and all encroachment agreements issued by District 2.

Pre-Construction
SC1 A Pre-Construction Meeting is required prior to beginning work. Contact the District Office to schedule.
SC2 This permit along with all terms and agreements shall be incorporated into any lease or sales agreement.
SC3 Approval may be rescinded upon failure to follow any of the provisions in this permit and may be considered a
violation of the encroachment agreement.
SC4 If the approved permit encroaches within the limits of an active construction project the Encroaching Party will be
required to coordinate with the NCDOT contractor as well as secure a hold harmless agreement prior to
commencing work. If the approved permit encroaches within the limits of a project in preconstruction, the
Encroaching Party will be required to coordinate with the Department s Project Development Unit to ensure no
conflicts are created with the installation.
SC5 The Encroaching party or their contractor shall provide the following notices prior to construction activity within the NCDOT Right of Way: a. Three (3) business days advance phone call at telephone [phone] to Travis Salazar or email [e-mail] at the District Engineer s office b. If the construction falls within the limits of an NCDOT managed construction project, five (5) business days advance phone call to the Assistant Resident Engineer, Nathan Tew at [phone] or email to [e-mail]
Failure to provide these notifications prior to beginning construction is subject to the Division Engi retion
to cease construction activity for this encroachment. NCDOT reserves the right to cease any construction or
maintenance work associated with this installation by the encroaching party until the construction or maintenance
meets the satisfaction of the Division Engineer or their representative.
SC6 Prior to beginning work, it is the requirement of the Encroaching Party to contact the appropriate Utility Companies involved and make arrangements to adjust or relocate any utilities that conflict with the proposed work.
SC7 It shall be the responsibility of the encroaching party to determine the location of utilities within the encroachment area. NCGS § 87-115 through § 87-130 of the Underground Utility Safety and Damage Prevention Act requires underground utilities to be located by calling 811 prior to construction. The encroaching party shall be responsible for notifying other utility owners and providing protection and safeguards to prevent damage or interruption to existing facilities and maintain access to them.
SC8 The encroaching party shall notify the appropriate municipal office prior to beginning any work within the .
SC9 NC 811 services DOES NOT provide locates of traffic signal cables. Excavation within 1000 feet of a signalized
intersection will require notification by the encroaching party to the Division Traffic Engineer s Office at telephone
number [phone] no less than one week prior to beginning work. All traffic signal or detection cables must
be located prior to excavation. Cost to replace or repair NCDOT signs, signals, pavement markings or
associated equipment and facilities shall be the responsibility of the encroaching party.
SC10 If modifications to a traffic signal are required under this encroachment agreement, a separate traffic agreement is
required prior to work. Contact the Division Traffic Engineer or Deputy Division Traffic Engineer at [phone].
SC11 This agreement does not authorize installations within nor encroachment onto railroad rights of way. Permits for
installations within railroad right of way must be obtained from the railroad and are the responsibility of the
encroaching party.
SC12 At the discretion of the District Engineer, a NOTIFICATION FOR UTILITY / NON-UTILITY ENCROACHMENT WITHIN
NCDOT R/W form (See corresponding attachment) with the scheduled pre-construction meeting and associated

Division 3, District 2 Updated 09/16/2021
construction schedule details must be completed and submitted to the District office a minimum of one
week prior to construction.
SC13 At the discretion of the District Engineer, the encroaching party (not the utility contractor) shall make arrangements
to have a qualified inspector, under the supervision of a Professional Engineer registered in North Carolina, on site
at all times during construction. The registered Professional Engineer shall be required to submit a signed and PE
sealed certification that the utility was installed in accordance with the encroachment agreement.

Legal & Right-of-Way Issues
SC14 This approval and associated plans and supporting documents shall not be interpreted to allow any design change
or change in the intent of the design by the Owner, Design Engineer, or any of their representatives. Any revisions
or changes to these approved plans or intent for construction must be obtained in writing from the Division
or their representative prior to construction or during construction, if an issue arises during
construction to warrant changes. No alteration of the approved plan will be allowed without written approval by
NCDOT. All design plan changes proposed by the contractor shall be prepared by the Engineer of Record and
submitted by the Owner/Permittee to NCDOT for review to ensure that the Engineer and Owner participate in all
construction changes. Field changes constructed without prior written approval by NCDOT will not be accepted by
NCDOT during the inspection process.
SC15 NCDOT does not guarantee the right of way on this road, nor will it be responsible for any claim for damages
brought about by any property owner by reason of this installation. It is the responsibility of the encroaching party
to verify the right of way.
SC16 Encroaching party shall be responsible for obtaining all necessary permanent and/or temporary construction,
drainage, utility and/or sight distance easements.
SC17 It shall be the responsibility of the property owner or local municipality to maintain any proposed sidewalk that will
be placed within the NCDOT Right of Way. It is the responsibility of the Encroaching Party to place the sidewalk and
wheelchair ramps per NCDOT standards and the latest edition of the Americans with Disabilities Act. This
maintenance requires an encroachment agreement through the District Office.
SC18 No commercial advertising shall be allowed within NCDOT Right of Way.
SC19 The encroaching party shall obtain proper approval from all affected pole owners prior to attachment to any pole.
SC20 The installation within the Control of Access fence shall not adversely affect the design, construction, maintenance,
stability, traffic safety or operation of the controlled access highway, and the utility must be serviced without access
from the through-traffic roadways or ramps.
SC21 It shall be unlawful to place any highway obstruction, including a driveway headwall, fence, rural mailbox, newspaper
delivery box, or other roadside obstruction, so as to interfere with the traffic or maintenance of the roads and
highways of the state highway system. See North Carolina Administrative Code 19A NCAC 2E.0404.

Bonds
SC22 A Performance and Indemnity Bond posted with the North Carolina Department of Transportation is hereby
obligated to cover work under this encroachment agreement. This bond is only for work within NCDOT Right of
Way.
SC23 An Initial Construction Inspection is required after the completion of the work. An Initial Inspection Report will be
issued upon satisfactory completion of the work and begins the one year warranty period. Contact the District Office
to schedule an inspection.
SC24 A Final inspection is required after one year and prior to release of the bond. Contact the District Office three
months prior to the end of the one year bonding period for final inspection and creation of a list of deficiencies; this
should provide enough time for corrective action prior to the end of one year. A Final Inspection Acceptance will be
issued once the work has been completed and any deficiencies addressed.
SC25 All bonds will be held for a minimum of one year from the time of the Initial Construction Inspection Acceptance. At
the end of that time period, the bond may be released at the request of the applicant pending Final Inspection
Acceptance.

Division 3, District 2 Updated 09/16/2021
Work Zone Traffic
SC26 WORK ZONE TRAFFIC CONTROL QUALIFICATIONS AND TRAINING PROGRAM All personnel performing any activity inside the highway right of way are required to be familiar with the NCDOT Maintenance / Utility Traffic Control Guidelines (MUTCG). No specific training course or test is required for qualification in the Maintenance /Utility Traffic Control Guidelines (MUTCG).
All flagging, spotting, or operating Automated Flagger Assist Devices (AFAD) inside the highway right of way requires qualified and trained Work Zone Flaggers. Training for this certification is provided by NCDOT approved training resources and by private entities that have been pre-approved to train themselves.
All personnel involved with the installation of Work Zone Traffic Control devices inside the highway right of way are required to be qualified and trained Work Zone Installers. Training for this certification is provided by NCDOT approved training resources and by private entities that have been pre-approved to train themselves.
All personnel in charge of overseeing work zone Temporary Traffic Control operations and installations inside the highway right of way are required to be qualified and trained Work Zone Supervisors. Training for this certification is provided by NCDOT approved training resources and by private entities that have been pre-approved to train themselves.
For questions and/or additional information regarding this training program please refer to
https://connect.ncdot.gov/projects/WZTC/Pages/Training.aspx or call the NCDOT Work Zone Traffic Control Section
[phone].
SC27 The party of the second part shall employ traffic control measures that are in accordance with the prevailing
federal, state, local, and NCDOT policies, standards, and procedures. These policies, standards, and procedures
include, but are not limited to the following:
a. Manual on Uniform Traffic Control Devices (MUTCD) North Carolina has adopted the MUTCD to provide
basic principles and guidelines for traffic control device design, application, installation, and maintenance.
North Carolina uses the MUTCD as a minimum requirement where higher supplemental standards specific
to North Carolina are not established. Use fundamental principles and best practices of MUTCD (Part 6,
Temporary Traffic Control).
b. NCDOT Maintenance / Utility Traffic Control Guidelines This document enhances the fundamental
principles and best practices established in MUTCD Part 6, Temporary Traffic Control, incorporating
NCDOT-specific standards and details. It also covers important safety knowledge for a wide range of work
zone job responsibilities.
SC28 There shall be no lane closures, narrowing of lanes, detaining and/or altering the traffic flow on or during holidays,
holiday weekends, special events or any other time when traffic is unusually heavy, including the following
schedules:
a. For unexpected occurrence that creates unusually high traffic volumes, as directed by the Engineer.
b. For New Year s Day, between the hours of 6:00 AM December 31st and 7:00 PM January 2nd. If New
Year s Day is on a Friday, Saturday, Sunday, or Monday, then until 7:00 PM the following Tuesday.
c. For Easter, between the hours of 6:00 AM Thursday and 7:00 PM Monday.
d. For Memorial Day, between the hours of 6:00 AM Friday and 7:00 PM Tuesday.
e. For Independence Day, between the hours of 6:00 AM the day before Independence Day and 7:00 PM
the day after Independence Day.
If Independence Day is on a Friday, Saturday, Sunday, or Monday, then between the hours of 6:00 AM
the Thursday before Independence Day and 7:00 PM the Tuesday after Independence Day.
f. For Labor Day, between the hours of 6:00 AM Friday and 7:00 PM Tuesday.
g. For Thanksgiving, between the hours of 6:00 AM Tuesday and 7:00 PM Monday.
h. For Christmas, between the hours of 6:00 AM the Friday before the week of Christmas Day and 7:00 PM
the following Tuesday after the week of Christmas Day.
These restrictions are in addition to any lane closure restrictions list in the Encroachment Special Provisions.
SC29 If the Traffic Control Supervisor determines that portable concrete barrier (PCB) is required to shield a hazard within the clear zone, then PCB shall be designed and sealed by a licensed North Carolina Professional Engineer. PCB plans and design calculations shall be submitted to the District Engineer for review and approval prior to installation.

Division 3, District 2 Updated 09/16/2021
SC30 Ingress and egress shall be maintained to all businesses and dwellings affected by the project. Special attention shall be paid to police, EMS and fire stations, fire hydrants, secondary schools, and hospitals.
SC31 Two-way traffic shall be maintained at all times unless designated by the District Engineer. Traffic shall not be
rerouted or detoured without the prior written approval from the District Engineer. No utility work will be allowed
on state holidays from 7:00 PM the night before through 9:00 AM the day prior to, following or during local
events without prior approval from the District Engineer. If the construction is within 1000 feet of a school
location or on a designated bus route, the construction shall be coordinated with the school start and end times
to avoid traffic delays.
SC32 Work requiring lane or shoulder closures shall not be performed on both sides of the road simultaneously within the same area.
SC33 Any work requiring equipment or personnel within 5 feet of the edge of any travel lane of an undivided facility and within 10 feet of the edge of any travel lane of a divided facility shall require a lane closure with appropriate tapers per current NCDOT Roadway Standard Drawings or MANUAL ON UNIFORM TRAFFIC CONTROL DEVICES.
SC34 At the discretion of the District Engineer, a traffic control plan shall be developed and submitted under the seal and signature of a Licensed North Carolina Professional Engineer prior to construction. The plan shall be specific to the site and adequately detailed. Issues such as the close proximity to intersections shall be addressed.
SC35 If pavement markings are required under this encroachment agreement, the Encroaching Party shall have the
pavement markings pre-marked, inspected, and approved by NCDOT personnel prior to the placement of final
pavement markings. Contact Traffic Services at [phone] for pre-marking inspections or field changes.
SC36 All temporary and final pavement markings are the responsibility of the encroaching party. Centerline pavement markings shall be installed the same day resurfacing is accomplished. All other pavement markings shall be completed within five days of resurfacing. Final pavement markings and sign plans shall be submitted with the encroachment request to the Division Traffic Engineer prior to construction. Final pavement markings shall be thermoplastic unless otherwise directed by the Division Traffic Engineer or District Engineer.
SC37 Any pavement markings that are damaged or obliterated shall be restored by the encroaching party at no expense to NCDOT.
SC38 All concrete or paved channelization islands shall have a 12 inch diameter round or square smooth wall hole drilled,
cored, formed, or air-hammered to the subgrade and backfilled with soil placed a minimum of 10 feet from the nose
of each end of the island (see Roadway Standard Drawing 904.50), or as directed by the engineer. All sign supports
that are to be erected in existing or proposed concrete or paved channelization islands shall meet the same
requirements. If necessary, contact Traffic Services at [phone] to mark core locations.
SC39 Sidewalk closures shall be installed as necessary. Pedestrian traffic shall be detoured around these closures and
shall be signed appropriately and in accordance with The American with Disabilities Act Accessibility Guidelines.
The encroaching party must adhere to the guidelines for accommodating pedestrians in encroachment work
zones as described in the NCDOT Pedestrian Work Zone Accommodations Training found at
https://www.youtube.com/watch?v=AOuYa5IW3dg&feature=youtu.be
Roadside Environmental
SC40 The encroaching party shall comply with all applicable Federal, State and local environmental regulations and shall
obtain all necessary Federal, State and local environmental permits, including but not limited to, those related to
sediment control, stormwater, wetland, streams, endangered species and historical sites. Additional information
can be obtained by contacting the NCDOT Division Environmental Office regarding the North Carolina Natural
Heritage Program or the United States Fish and Wildlife Services. Contact the Division Environmental Office at
[phone].
SC41 The Verification of Compliance with Environmental Regulations (VCER-1) form is required for all non-utility
encroachment agreements or any utility encroachments. The VCER-1 form must be signed and/or sealed by a NC
registered professional engineer (PE), registered land surveyor (RLS), or authorized personnel who has verified that
all appropriate environmental permits (if applicable) have been obtained and all applicable environmental
regulations have been followed.
SC42 All erosion control devices and measures shall be constructed, installed, maintained, and removed by the Encroacher in accordance with all applicable Federal, State, and Local laws, regulations, ordinances, and policies.
Permanent vegetation shall be established on all disturbed areas in accordance with the recommendations of the Division Roadside Environmental Engineer. All areas disturbed (shoulders, ditches, removed accesses, etc.) shall
be graded and seeded in accordance with the latest NCDOT Standards Specifications for Roads and Structures and within 15 calendar days with an approved NCDOT seed mixture (all lawn type areas shall be maintained and
reseeded as such). Seeding rates per acre shall be applied according to the Division Roadside Environmental

Division 3, District 2 Updated 09/16/2021
Engineer. Any plants, vegetation or trees in the NCDOT planted sites that is destroyed or damaged as a result of this encroachment shall be replaced with plants, vegetation or trees of like kind or similar shape. Contact the Division Roadside Environmental Engineer at 910-259-4919.
SC43 No trees within NCDOT shall be cut without authorization from the Division Roadside Environmental Engineer. An
inventory of trees measuring greater than 4 caliper inches (m above the ground) is required when trees
within C/A right of way will be impacted by the encroachment installation. Mitigation is required and will be
determined by the Division Roadside Environm Office.
SC44 The applicant is responsible for identifying project impacts to waters of the United States (wetlands, intermittent
streams, perennial streams and ponds) located within the NCDOT right-of-way. The discharge of dredged or fill
material into waters of the United States requires authorization from the United States Army Corps of Engineers
(USACE) and certification from the North Carolina Division of Water Quality (NCDWQ). The applicant is required to
obtain pertinent permits or certification from these regulatory agencies if construction of the project impacts
waters of the United States within the NCDOT right-of-way. The applicant is responsible for complying with any
river or stream Riparian Buffer Rule as regulated by the NCDWQ. The Rule regulates activity within a 50-foot
buffer along perennial streams, intermittent streams and ponds. Additional information can be obtained by
contacting the NCDWQ or the USACE.
SC45 The contractor shall not begin the construction until after the traffic control and erosion control devices have been installed to the satisfaction of the Division Engineer or their agent.
SC46 The contractor shall perform all monitoring and record keeping and any required maintenance of erosion and sediment control measures to maintain compliance with stormwater regulations.
STIP (or Division Managed) Projects
SC47 State Transportation Improvement Projects (STIP) If encroachment falls within a STIP that is active or in design when installation takes place coordination with Division Utility Coordinator is required. If project is specifically equired. Any encroachment determined to be in conflict STIP construction shall be removed and/or relocated at the e s expense.
Construction
General
SC48 An executed copy of the encroachment agreement, provisions and approved plans shall be present at the
construction site at all times. NCDOT reserves the right to stop all work unless evidence of approval can be shown.
Additionally, if safety or traffic conditions warrant such an action, NCDOT reserves the right to further limit, restrict
or suspend operations within the right of way.
SC49 The Encroaching Party and/or their Contractor shall comply with all OSHA requirements and provide a competent person on site to supervise excavation at all times. If OSHA visits the work area associated with this encroachment, the District Office shall be notified by the encroaching party immediately if any violations are cited.
SC50 The Encroaching Party shall follow any and all revisions shown in RED on attached plan(s).
SC51 All disturbed areas are to be fully restored to current NCDOT minimum roadway standards or as directed by the
Division Engineer or their representative. Disturbed areas within NCDOT Right-of-Way include, but not limited to,
any excavation areas, pavement removal, drainage or other features.
SC52 All drainage structures disturbed, damaged or blocked shall be restored to its original condition as directed by the
Division Engineer or their representative.
SC53 All pipes placed within the NCDOT Right of Way shall be NCDOT approved materials. All joints shall be sealed with
mortar or other NCDOT approved material. Backfill compaction shall meet NCDOT Standardized Testing Method.
SC54 Throughout the life of the project, the Encroaching Party shall maintain all drop-offs within the work zone such that
they do not exceed the maximum of 2".
SC55 All removed curb, driveways, and shoulder areas shall be backfilled at a 6:1 slope or flatter at the end of the days'
production.
SC56 Abandoned pipes 12" in diameter and larger in fills 20' or less shall be removed and backfilled, filled with grout, or
plugged, as directed by the Manager of Right-of-Way, Division Engineer or State Design Services Engineer. There
may be unusual circumstances where the same requirements will apply on pipes smaller than 12".

Division 3, District 2 Updated 09/16/2021
SC57 For trenching excavations within the typical ditch cross-section, positive drainage shall be restored within the
existing ditch by grading between driveway pipe invert elevations or by re-establishing the original hydraulic grade
line.
SC58 Material shall NOT be unloaded or stockpiled on the roadway at any time without proper lane closure during the
project. Work is not permitted when the shoulder material is wet or during adverse weather conditions.
SC59 The placement of curb and gutter is not allowed within shoulder sections of roadway.
SC60 A minimum of 5 feet (10 feet desirable) clearance is required for utility installations beneath or near drainage pipes, headwalls, and a minimum of two-foot clearance below the flowline of streams. If directional drilling, a minimum ten-foot clearance distance is required from drainage structures and a minimum of 5 feet below flowline of streams.
SC61 At points where the utility is placed under existing storm drainage, the trench will be backfilled with excavatable flowable fill up to the outside diameter of the existing pipe.
SC62 Unless specified otherwise, during non-working hours, equipment shall be located away from the job site or parked as close to the right of way line as possible and be properly barricaded in order not to have any equipment obstruction within the Clear Recovery Area. Also, during non-working hours, no parking or material storage shall be allowed along the shoulders of any state-maintained roadway.
SC63 No access to the job site, parking or material storage shall be allowed along or from the Control of Access Roadway.
SC64 Guardrail removed or damaged during construction shall be replaced or repaired by an NCDOT approved guardrail contractor to its original condition, meeting current NCDOT standards or as directed by the Division Engineer or their representative.
SC65 The resetting of the Control of Access fence shall be in accordance with the applicable NCDOT standard and as directed by the Division Engineer or their representative.
SC66 Right of Way monuments disturbed during construction shall be referenced by a registered Land Surveyor and reset after construction.
SC67 All Traffic signs moved during construction shall be reinstalled as soon as possible to the satisfaction of the Division Engineer or their representative.
SC68 Any utility markers, cabinets, pedestals, meter bases and services for meter reading required shall be as close to the Right of Way line as possible. If it is not feasible to install at or near Right of Way line, then written approval shall be obtained from NCDOT prior to installation.
SC69 Any sewer manholes, telephone vaults or valve vaults that are to be abandoned shall either be removed or broken
down two (2) feet below subgrade, plugged and filled with suitable material.
SC70 Detection tape, where required by NCGS § 87-115 through § 87-130 of the Underground Utility Safety and Damage Prevention Act, shall be buried in the trench approximately 1 foot above the installed facility. Where conduit is installed in the right of way and is not of ferrous material, locating tape or detection wire shall be installed with the conduit.
SC71 All driveways disturbed during construction shall be returned to a state comparable with the condition of the driveways prior to construction.
SC72 Conformance with driveway permit review should be required in conjunction with this encroachment agreement. In the event there is a conflict between the driveway permit and the encroachment agreement, the District Engineer should resolve the conflict and notify the parties involved.
SC73 If the approved method of construction is unsuccessful and other means are required, prior approval must be obtained through the District Engineer before construction may continue.
Engineering
SC74 All traffic control, asphalt mixes, structures, construction, workmanship and construction methods, and materials shall be in compliance with the most-recent versions of the following resources: ASTM Standards, Manual on
Uniform Traffic Control Devices, NCDOT Utilities Accommodations Manual, NCDOT Standard Specifications for Roads and Structures, NCDOT Roadway Standard Drawings, NCDOT Asphalt Quality Management System manual,
and the approved plans.
SC75 Prior approval for any blasting must be obtained from the Division Engineer or their representative.
SC76 Regulator stations, metering stations, cathodic test stations, and anode beds are not permitted within NCDOT right of way. Header wires are permitted.
SC77 Non-Utility Communication and Data Transmission installations (ground mounted type or Small Cell pole-mounted type) must adhere to guidelines in the Utilities Accommodations Manual and, when located within municipal jurisdictions, are subject to review and approval by municipal ordinances and any additional municipal

Division 3, District 2 Updated 09/16/2021
approval for proximity to historic districts and landmarks. All wiring and related telecommunications work shall conform to the latest regulations by the Federal Communications Commission.
SC78 All wiring and related electrical work shall conform to the latest edition of the National Electrical Safety Code.
Location within R/W
SC79 All utility access points, such as manholes, vaults, handholes, splice boxes and junction boxes shall be located as close to the right of way line as possible and shall not be placed in the ditch line, side slopes of the ditches or in the pavement. All manholes, handholes, splice boxes, junction boxes and vaults and covers shall be flush with the ground when located within the vehicle clear zone. Slack loops for telecommunications in industry standard housing units shall be buried a minimum of 18 inches when buried or meet minimum NCDOT vertical and horizontal clearances when installed aerially.
SC80 Proposed manholes, handholes, valves or other appurtenances shall be installed flush to match the elevation of the existing ground and shall not be located in the existing ditch line, front slope of a ditch, or in a manner that would restrict the maintenance or flow of the existing ditch line.
SC81 Fire Hydrants shall be of the breakaway type. Fire Hydrant(s) shall be placed a maximum of 1 foot from the right-of-
way line. (STD. 1515.02 in the NCDOT Roadway Standard Drawings).
SC82 Luminaire and/or utility poles and guy wires shall be set as close to the Right of Way line as practical and outside the Clear Zone in accordance with the latest version of the AASHTO Roadside Design Guide (See corresponding attachment) or made breakaway in accordance with the requirements of NCHRP Report 350. Any relocation of the utility poles from the original design due to Clear Zone requirements shall require a re-submittal for the utility design.
SC83 Luminaire and/or utility poles shall be set a minimum of 5 -face of any guardrail or otherwise sufficiently protected. However, standard placement may be reduced t -behind face of guardrail when posts are spaced -mit is less than 55 MPH.
SC84 Hot box (aka ASSE 1060) or Safe-T-Cover type enclosures covering utility main pipe joints, backflow preventers, valves, vent pipes, cross connections, pumps, grinders, irrigation assemblies, transformers, generators, and other similar large appurtenances shall be located outside sight distance triangles and off of the NCDOT Right-of-Way.
SC85 Sprinkler heads shall be located a minimum of 10 feet from the edge of pavement, edge of shoulder, or back of curb whichever is greater and shall be directed so that water does not spray or drain on the roadway surface, sidewalk, or passing vehicles at any time. Upon completion of the installation and prior to activation of the system, the Encroacher shall contact the District Engineer to schedule a test of the system to verify the spray pattern. Sprinkler systems shall not be operated during periods of high wind or freezing weather, or to the extent that the subgrade adjacent to the pavement structure becomes saturated. NCDOT reserves the right to require immediate termination and removal of any sprinkler system which in its judgement and opinion adversely affects safety, maintenance, or operation of the roadway.
Excavation
SC86 Excavation material shall not be placed on pavement.
SC87 It is the responsibility of the encroaching party or their contractor to prevent any mud/dirt from tracking onto the roadway. Any dirt which may collect on the roadway pavement from equipment and/or truck traffic on site shall be immediately removed to avoid any unsafe traffic conditions.
SC88 The utility shall be installed within 5 feet of the right of way line and outside the 5-foot minimum from travel lane plus theoretical 2:1 slope from the edge of pavement to the bottom of the nearest excavation wall for temporary shoring. If the 2:1 slope plus 5 feet requirement above is met for traffic, then temporary shoring is typically only necessary to protect roadways from damage when a theoretical 1:1 slope from the edge of pavement intersects the nearest excavation wall. This rule of thumb should be used with caution and does not apply to all subsurface conditions, surcharge loadings and excavation geometries. Situations where this 1:1 slope is not recommended include groundwater depth is above bottom of excavation or excavation is deeper than 10 feet or in Type B or C soils as defined by OSHA Technical Manual. Temporary shoring may be avoided by locating trenches, bore pits, and other excavations far enough away from the open travel lane, edge of pavement and any existing structure, support, utility, property, etc. to be protected. Temporary shoring is required when a theoretical 2:1 slope from the bottom of excavation will intersect the existing ground line less than 5 feet from the outside edge of an open travel lane as shown in the figure below or when a theoretical 2:1 slope from the bottom of excavation will intersect any existing structure, support, utility, property, etc. to be protected.
Division 3, District 2 Updated 09/16/2021
Temporary shoring shall be designed and constructed in accordance with current NCDOT Standard Temporary
Shoring provisions (refer to https://connect.ncdot.gov/resources/Specifications/Pages/2018-Specifications-and-
Special-Provisions.aspx and see SP11 R002).
a. Temporary excavation shoring, such as sheet piling, shall be installed. The design of the shoring shall include
the effects of traffic loads. The shoring system shall be designed and sealed by a licensed North Carolina
Professional Engineer. Shoring plans and design calculations shall be submitted to the Division Engineer for
review and approval prior to construction. (See NCDOT Utilities Accommodations Manual for more
information on requirements for shoring plans and design calculations.) Trench boxes shall not be accepted
as temporary shoring and will not be approved for use in instances where shoring is required to
protect the highway, drainage structure, and/or supporting pavement or structure foundation.
b. All trench excavation inside the limits of the theoretical one-to-one slope, as defined by the policy, shall be
completely backfilled and compacted at the end of each construction day. No portion of the trench shall be
left open overnight. Any excavation that is not backfilled by the end of the workday must address any safety
and traveling public concerns including accommodations for bicycles, pedestrians and persons with
disabilities.
c. The trench backfill material shall meet the Statewide Borrow Criteria. The trench shall be backfilled in
accordance with Section 300-7 of the latest NCDOT Standard Specifications for Roads and Structures, which
basically requires the backfill material to be placed in layers not to exceed 6 inches loose and compacted to at
least 95% of the density obtained by compacting a sample in accordance with AASHTO T99 as modified by
DOT.
Division 3, District 2 Updated 09/16/2021
d. At the discretion of the Division Engineer, a qualified NCDOT inspector shall be on the site at all times during
construction. The encroaching party shall reimburse NCDOT for the cost of providing the inspector. If NCDOT
cannot supply an inspector, the encroaching party (not the utility contractor) should make arrangements to
have a qualified inspector, under the supervision of a licensed North Carolina Professional Engineer, on the
site at all times. The Professional Registered Engineer shall certify that the utility was installed in accordance
with the encroachment agreement and that the backfill material meets the Statewide Borrow Criteria.
e. The length of parallel excavation shall be limited to the length necessary to install and backfill one joint of
pipe at a time, not to exceed twenty-five (25) feet.
SC89 All material to a depth of 8 inches below the finished surface of the subgrade shall be compacted to a density equal
to at least 100% of that obtained by compacting a sample of the material in accordance with AASHTO T99 as
modified by the Department. The subgrade shall be compacted at a moisture content which is approximately that
required to produce the maximum density indicated by the above test method. The contractor shall dry or add
moisture to the subgrade when required to provide a uniformly compacted and acceptable subgrade. The option to
backfill any trenches with dirt or either #57 stone or #78 stone with consolidation with a plate tamp and without a
conventional density test may be pursued with the written consent of the District Engineer. If this option is exercised,
then roadway ABC stone and asphalt repair as required will also be specified by the District Engineer.
Directional bore
SC90 Boring equipment will be provided of a type and size to facilitate boring in the local geologic conditions and shall
be able to facilitate the encroachment work.
SC91 When Horizontal Directional Drilling (HDD) is used, the following stipulations apply:
a. Use drilling fluids as appropriate for the type soils but use of water alone is prohibited. Pump drilling fluidsonly while drilling or reaming. Directional boring using jetting with a Bentonite (or equivalent material) slurryis recommended. Monitor flow rates to match the amount leaving the bore hole and do not increase pressureor flow to free stuck drill heads, reamers or piping. Open cutting to retrieve stuck drill heads is not allowedwithout prior permission from the District Engineer.b. The minimum depth shall adhere to the table below for transverse (under non-controlled access, partialcontrolled access, or limited controlled access roadway) installations and refers to maximum diameter of holedrilled and not the dimension of the carrier or encasement pipe.
Diameter of Drilled Hole Minimum Depth of Cover (Backream) 2" to 10 10 feet
>10 to 1 12 times hole diameter (e.g. 11-inch hole means 11 feet minimum depth)
15 feet or greater
c. Under fully controlled access roadway installations, the minimum depth for transverse crossings shall be 15feet under any pavement (ramps or thru lanes)d. An overbore (backream diameter) shall not be more than 1.5 times the outside diameter of the pipe orencasement under any highway for pipes 12 inches in diameter or less. For pipes with outer diameter largerthan 12 inches, the overbore may be no larger than outer diameter of pipe plus 6 inches. An overboreexceeding 1.5 times greater than the outside diameter of the pipe or encasement may be considered if theencroachment agreement includes a statement signed and sealed by a licensed North Carolina ProfessionalEngineer indicating that an overbore in excess of 1.5 times the outside diameter of the pipe or encasementwill appropriately arch and no damage will be done to the pavement or sub-grade.e. Directional boring is allowed beneath embankment material in naturally occurring soil.f. Any parallel installation utilizing the directional boring method shall be made at a minimum depth of five (5feet (cover) below the ground surface and outside the theoretical 1:1 slope from the existing edge ofpavement except where the parallel installation crosses a paved roadway.g. All directional bores shall maintain ten (10) feet minimum (clear) distance from the nearest part of anystructure, including but not limited to bridges, footings, pipe culverts or box culverts. Directional bores arenot allowed beneath bridge footings, culvert wingwall footings, slope protection or retaining walls.h. The tip of the drill string shall have a cutter head.i. Detection wire shall be installed with non-ferrous material.j. HDPE pipe installed by directional boring shall not be connected to existing pipe or fittings for one (1) weekfrom the time of installation to allow tensional stresses to relax.
Division 3, District 2 Updated 09/16/2021
Aerial clearances
SC92 Vertical clearance of overhead power and communication lines shall meet the National Electrical Safety Code
requirements except the minimum vertical clearance shall be 1 Fully
Controlled Access roadways ions.
SC93 In relation to the bridge, the utility line shall be located with minimum clearances as indicated on the attachment for
NCDOT Required Clearances for Aerial Installations by Encroachment Near Bridge Structures.
Pavement Detail and Repair
SC94 The paving of roadways shall be in accordance with the latest version of NCDOT Standard Specifications, Sections
610, 1012 and 1020. The Contractor shall follow all procedures of the Quality Management System (QMS) for
asphalt pavement - Maintenance Version (see
https://connect.ncdot.gov/resources/Materials/MaterialsResources/2018%20QMS%20Asphalt%20Manual.pdf).
The Contractor must adhere to all testing requirements and quality control requirements specified. The Contractor
shall contact the NCDOT Division QA Supervisor prior to producing plant mix and make the Supervisor aware that
the mix is being produced for a future NCDOT road. Only NCDOT approved mix designs will be acceptable. A
Quality Control Plan shall be submitted (as Directed by the District Engineer) to the District Engineer's Office prior
to asphalt production utilizing form QMS-MV1. Failing mixes and/or densities are subject to penalties including
monetary payments or removal and replacement. To minimize traffic queuing in construction areas, the possibility
of traffic detours may be considered when working on high traffic routes even if traffic control is used. The District
Engineer may require traffic detours.
SC95 When paving beyond utility installation is involved, a Roadway certification report sealed by a Professional Engineer
he following:
Pavement thickness by type
Pavement density, core and/or test locations
Base thickness
Base density
Subgrade density
Test frequency and method shall be in conformance with the NCDOT Materials and Tests Manual. Test must be
performed by a Certified Technician including name and Certification number on report.
SC96 diameter keyhole pavement
core. Pavement core locations shall not be placed in the wheel path whenever possible. Vacuum excavation shall
be utilized to expose underground utilities. Pavement cores shall be repaired within the same working day. The
pavement core shall be retained and reused to fill the core hole.
The excavation shall be backfilled and compacted with select material to the bottom of the existing pavement
structure or as indicated by the District Engineer. The retained core shall be placed in the hole and secured with a
waterproof, mechanical joint. If the pavement core is damaged and cannot be re-used, the core may be replaced
with the surface mix, S9.5B. The asphalt patch shall match the thickness of the existing asphalt or four inches,
whichever is greater. All materials must be listed on the NCDOT Approved Products List (APL) found at:
https://apps.ncdot.gov/vendor/approvedproducts/.
SC97 The minimum pavement design for pavement repair shall be according to NCDOT Standard Drawing 654.01
(https://connect.ncdot.gov/resources/Specifications/2018StandardRdwyDrawings/Division%2006%20Asphalt%20B
ases%20and%20Pavements.pdf) and shall include a mechanical overlay extent to be a minimum of 25 feet each
side of the pavement repair area OR as directed by the District Engineer. Any open cutting of pavement shall be
repaired using the following method:
Pavements shall be cut full depth and removed.
After trench work is complete, the edges of the existing pavement along the trench shall be recut a
. If the pavement is undermined, the edges of the existing
pavement along the trench shall be recut ond the undermined portion and the pavement removed.
The design section stated below is to be placed in those areas.
The pavement repair shall be performed using the following method and pavement design section:
o B25.0C Asphalt Concrete Base Course (accomplished in 2 lifts minimum) according to NCDOT
Standard 654.01.
Division 3, District 2 Updated 09/16/2021
o Mill the entire area a depth starting from in front of the edge of the final pavement cut.
o Overlay entire area length mechanical overlay) S9.5B Asphalt Concrete
Surface Course for a total asphalt depth of . Butt joints are required with no feathering of joints.
All open cuts shall be backfilled, paved and traversable prior to removing lane closure.
SC98 Pavement cuts shall be repaired the same day the cuts are made.
SC99 Any pavement damaged because of settlement of the pavement or damaged by equipment used to perform
encroachment work, shall be re-surfaced to the satisfaction of the District Engineer. This may include the removal of
pavement overlay. All pavement work and pavement markings (temporary and final) are the
responsibility of the Encroaching Party. Centerline pavement markings shall be installed the same day resurfacing is
accomplished. All other pavement markings shall be completed within five days of resurfacing.
SC100 For projects with open cuts and roadway improvements, a PE certification may be required. When applicable, upon
completion of construction, a certification memo that has been signed and sealed as appropriate under General
Statute 89C-16 by a North Carolina Professional Engineer or Registered Land Surveyor shall be submitted to the
District Engineer prior to opening the access connection for public use. Supporting documentation shall be attached
certifying that improvements for the driveway access(s) meet the approved plan and NCDOT standards. All
documentation shall be dated and initialed by the contractor. Verification will include inspection reports, testing
reports, or any supporting documentation and calculations. Verification will cover, but is not limited to, subgrade,
pavement structure, drainage, and traffic control items.
Post Construction
Close out/ Inspection
SC101 The Encroaching party shall not siness days after construction is complete.
The District Engineer may perform a construction inspection. Any deficiencies may be noted and reported to the
encroaching party to make immediate repairs or resolve any issues to restore the right-of-way to a similar condition
prior to construction, including pavement, signage, traffic signals, pavement markings, drainage, structures/pipes, or
other highway design features.
SC102 At the discretion of the District Engineer, a final inspection report may be provided to the encroaching party upon
satisfactory completion of the work.
SC103 A written acknowledgement of the completed work by the Dist begins the one-year warranty
period associated with the performance bond.
SC104 If the actual construction differs from the approved plans associated with this encroachment, a cop as-built
plans shall be submitted to the District En
weeks of construction.
SC105 The encroaching party shall provide the North Carolina Turnpike Authority (NCTA) with an electronic copy of
coordinate correct as-built plans within two weeks of installation completion. Failure to provide the as-built plans
may jeopardize future approvals within NCTA right of way.
SC106 A copy (in PDF format) of the completed ground water analysis shall be given to the District Engineer, including
detailed drawings as-

Division 3, District 2 Updated 09/16/2021

Division 3, District 2 Updated 09/16/2021
Division 3, District 2 Updated 09/16/2021
VERIFICATION OF COMPLIANCE WITH
ENVIRONMENTAL REGULATIONS
(Check Appropriate Box)
Permits from the N.C. Department of Environmental Quality and the
U.S. Army Corp of Engineers are not required for this project. However,
all applicable federal and state regulations have been followed.
The required permits from the N.C. Department of Environmental
Quality and the U.S. Army Corp of Engineers have been obtained for this
project. Copies of the permits are attached.
All applicable NPDES Stormwater Permit requirements have been or will
be met for this project.
The project is in compliance with all applicable sedimentation and
erosion control laws and regulations.
Project Name:
___________________
Township:___________________County:____________
Project Engineer:___________________Phone Number ____________
Project Contact:
___________________
Applicant’s Name:___________________________P.E. Seal
Date Submitted:
___________________________
Form VCER-1
June 2016
2/9/2023
Laura Minor on behalf of Campbell Oil & Gas Co, Inc.
704-845-4010
Laura Minor
SampsonRoseboro
Minuteman #3
If the actual construction differs from the approved plans associated with this
encroachment, a copy of “as-built” plans shall be submitted to the District
Engineer’s office in a PDF format and in a current ESRI GIS format within 4
weeks of construction.
Excerpts from “Work Zone Safety: Guidelines for Construction, Maintenance, and Utility Operations” published April 2002 by
Institute for Transportation Research and Education, Raleigh, NC.
Excerpts from “Work Zone Safety: Guidelines for Construction, Maintenance, and Utility Operations” published April 2002 by
Institute for Transportation Research and Education, Raleigh, NC.

Excerpts from “Work Zone Safety: Guidelines for Construction, Maintenance, and Utility Operations” published April 2002 by
Institute for Transportation Research and Education, Raleigh, NC.
Excerpts from “Work Zone Safety: Guidelines for Construction, Maintenance, and Utility Operations” published April 2002 by
Institute for Transportation Research and Education, Raleigh, NC.

North Carolina Department of Environmental Quality | Division of Water Resources
Fayetteville Regional Office | 225 Green St., Suite 714 | Fayetteville, North Carolina 28301-5043
910.433.3300

12 September 2023

Ms. Laura Minor c/o
Geological Resources, Inc.
3502 Hayes Rd.
Monroe, NC 28110

SUBJECT: Well Construction Permit No. WM0601273
2 Monitoring Wells
Roseboro, Sampson Co., N.C.

Ms. Minor:
In accordance with the application prepared by you on 31 August 2023 and received in the
Fayetteville Regional Office on 31 August 2023; we are forwarding herewith Well Construction
Permit No. WM0601273 dated 12 September 2023 issued to Geological Resources, Inc. at 3502 Hayes
Rd., Monroe, NC 28110 for the construction of two (2) monitoring wells located at NCDOT Right-Of-
Way near E. Dr. Martin L. King, Jr. Blvd. in Roseboro, NC (NCDOT Encroachment Agreement E032-
082-23-00006-R1).

This Permit will be effective from the date of its issuance for one year and shall be subject to the
conditions and limitations as specified therein.

Please note that according to North Carolina Administrative Code, Title 15A, Subchapter 2C,
Section .0105 (g), "it is the responsibility of the well owner or his agent to see that a permit is secured
prior to the commencement of construction of any well for which a permit is required."

Issuance of this permit does not constitute approval of the subject wells for reimbursement from Trust
Funds.

If any parts, requirements, or limitations contained in this Permit are unacceptable to you, you have
the right to an adjudicatory hearing before a hearing officer upon written demand to the Director
within 30 days following receipt of this Permit, identifying the specific issues to be contended. Unless
such demand is made, this Permit shall be final and binding.

Sincerely,

Trent Allen, Regional Supervisor
Division of Water Resources – Water Quality Programs

Enclosure
cc: FRO Files

North Carolina Department of Environmental Quality | Division of Water Resources
Fayetteville Regional Office | 225 Green Street, Suite 714 | Fayetteville, North Carolina 28301-5043
910-433-3300

NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY DIVISION OF WATER RESOURCES – WATER QUALITY PROGRAMS PERMIT FOR THE CONSTRUCTION OF A MONITORING WELL
In accordance with the provisions of Article 7, Chapter 87, North Carolina General Statutes, and other
applicable Laws, Rules and Regulations.
PERMISSION IS HEREBY GRANTED TO

Geologic Resources, Inc.

FOR THE CONSTRUCTION OF A MONITORING WELL SYSTEM owned by Geological Resources, Inc. at
3502 Hayes Rd., Monroe, NC 28110 for the construction of two (2) monitoring wells located at
NCDOT Right-Of-Way near E. Dr. Martin L. King, Jr. Blvd. in Roseboro, NC (NCDOT Encroachment
Agreement E032-082-23-00006-R1). This Permit is issued in accordance with the application
received on 31 August 2023, in conformity with specifications and supporting data, all of which are
filed with the Department of Environmental Quality and are considered integral parts of this Permit.
This Permit is for well construction only and does not waive any provision or requirement of any
other applicable law or regulation. Construction of any well under this Permit shall be in strict
compliance with the North Carolina Well Construction Regulations and Standards (15A NCAC
02C .0100), and other State and Local Laws and regulations pertaining to well construction.

If any requirements or limitations specified in this Permit are unacceptable, you have a right to an
adjudicatory hearing upon written request within 30 days of receipt of this Permit. The request must
be in the form of a written petition conforming to Chapter 150B of the North Carolina General
Statutes and filed with the Office of Administrative Hearings, 6714 Mail Service Center, Raleigh, North
Carolina 27699-6714. Unless such a demand is made, this Permit is final and binding. This Permit will be effective for one year from the date of its issuance and shall be subject to other
specified conditions, limitations, or exceptions as follows:

North Carolina Department of Environmental Quality | Division of Water Resources
Fayetteville Regional Office | 225 Green Street, Suite 714 | Fayetteville, North Carolina 28301-5043
910-433-3300

1. Issuance of this Permit does not obligate reimbursement from State trust
funds, if these wells are being installed as part of an investigation for
contamination from an underground storage tank or dry cleaner incident.
2. Issuance of this Permit does not supersede any other agreement, permit, or
requirement issued by another agency.
3. The well(s) shall be located and constructed as shown on the attachments
submitted as part of the Permit application.
4. Each well shall have a Well Contractor Identification Plate in
accordance with 15A NCAC 02C .0108(o).
5. Well construction records (GW-1) for each well shall be submitted to
the Division of Water Resources Information Processing Unit within 30 days
of the well completion.
6. When the well is discontinued or abandoned, it shall be abandoned in
accordance with 15A NCAC 02C .0113 and a well abandonment record (GW-
30) shall be submitted to the Division of Water Resources Information
Processing Unit within 30 days of the well abandonment.

Permit issued the 12th. day of September 2023
FOR THE NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION

_______________________________________________
Trent Allen, Regional Supervisor
Division of Water Resources – Water Quality Programs
By Authority of the Environmental Management Commission
Permit No. # WM0601273

Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Depth:
Diameter:Completion Details:
PID Lab
From To (ppm)Sample Description Color Moisture Odor
Depth (ft)Lithology
SITE INFORMATION
DRILLING INFORMATION
BORING INFORMATION
Minute Man #3
3148
03/08/23
Stephanie Gainey
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548-A
MW-7
6"
20
Well installed at completion
0 2 Brown silt Dry
2 15 Tan silty clay Moist
15 20 Tan fine sand Wet

Photo 1: Preclearing Photo 2: Completion
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Top of Casing:
Diameter:Depth to Water:
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
Sand
Bentonite
Grout
Screen
Casing
SITE INFORMATION
DRILLING INFORMATION
WELL CONSTRUCTION INFORMATION
DIAGRAM - MONITORING WELL
Sand
Bentonite
Grout Screen
Inner Casing
Outer Casing
Minute Man #3
3148
03/08/23
Stephanie Gainey
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548-A
MW-7
6"
100.71
14.41
3 20
1 3
0 1
0
0 5 2
5 20 2
1
3
20
5
20

WELLCONSTRUCTIONRECORD
Thisformcanbeusedforsingleormultiplewells
FormGW-1 NorthCarolinaDepartmentofEnvironmentandNaturalResources–DivisionofWaterResources RevisedAugust2013
1.WellContractorInformation:

WellContractorName

NCWellContractorCertificationNumber

CompanyName

2.WellConstructionPermit#:
List all applicable well permits (i.e. County, State, Variance, Injection, etc.)

3.WellUse(checkwelluse):
WaterSupplyWell:
□Agricultural□Municipal/Public
□Geothermal(Heating/CoolingSupply)□ResidentialWaterSupply(single)
□Industrial/Commercial□ResidentialWaterSupply(shared)
□Irrigation
Non-WaterSupplyWell:
□Monitoring□Recovery
InjectionWell:
□AquiferRecharge□GroundwaterRemediation
□AquiferStorageandRecovery□SalinityBarrier
□AquiferTest□StormwaterDrainage
□ExperimentalTechnology□SubsidenceControl
□Geothermal(ClosedLoop)□Tracer
□Geothermal(Heating/CoolingReturn)□Other(explainunder#21Remarks)

4.DateWell(s)Completed:____________WellID#______________________

5a.WellLocation:

Facility/OwnerNameFacilityID#(ifapplicable)

PhysicalAddress,City,andZip

CountyParcelIdentificationNo.(PIN)

5b.LatitudeandLongitudeindegrees/minutes/secondsordecimaldegrees:
(ifwellfield,onelat/longissufficient)

N W

6.Is(are)thewell(s):□Permanentor□Temporary

7.Isthisarepairtoanexistingwell:□Yesor□No
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8.Numberofwellsconstructed:
For multiple injection or non-water supply wells ONLY with the same construction, you can
submit one form.

9.Totalwelldepthbelowlandsurface: (ft.)
For multiple wells list all depths if different (example- 3@200’ and 2@100′)

10.Staticwaterlevelbelowtopofcasing:(ft.)
If water level is above casing, use “+”

11.Boreholediameter:(in.)

12.Wellconstructionmethod:
(i.e.auger,rotary,cable,directpush,etc.)

FORWATERSUPPLYWELLSONLY:
13a.Yield(gpm) Methodoftest:

13b.Disinfectiontype:Amount:

14.WATERZONES
FROMTODESCRIPTION
ft.ft.
ft.ft.
15.OUTERCASING(formulti-casedwells)ORLINER(ifapplicable)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
16.INNERCASINGORTUBING(geothermalclosed-loop)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
17.SCREEN
FROMTODIAMETERSLOTSIZETHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
18.GROUT
FROMTOMATERIALEMPLACEMENTMETHOD&AMOUNT
ft.ft.
ft.ft.
ft.ft.
19.SAND/GRAVELPACK(ifapplicable)
FROMTOMATERIALEMPLACEMENTMETHOD
ft.ft.
ft.ft.
20.DRILLINGLOG(attachadditionalsheetsifnecessary)
FROMTODESCRIPTION(color,hardness,soil/rocktype,grainsize,etc.)
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
21.REMARKS

22.Certification:

SignatureofCertifiedWellContractorDateBy signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23.Sitediagramoradditionalwelldetails:Youmayusethebackofthispagetoprovideadditionalwellsitedetailsorwell
constructiondetails.Youmayalsoattachadditionalpagesifnecessary.

SUBMITTALINSTUCTIONS

24a.ForAllWells:Submit this formwithin30daysof completionof well
constructiontothefollowing:
DivisionofWaterResources,InformationProcessingUnit,
1617MailServiceCenter,Raleigh,NC27699-1617
24b.ForInjectionWellsONLY:Inadditiontosendingtheformtotheaddressin
24aabove,alsosubmitacopyofthisformwithin30 daysofcompletionof well
constructiontothefollowing:

DivisionofWaterResources,UndergroundInjectionControlProgram,
1636MailServiceCenter,Raleigh,NC27699-1636
24c.ForWaterSupply&InjectionWells:
Also submitone copyof this form within30days ofcompletionof
wellconstructiontothecountyhealthdepartment ofthecountywhere
constructed.
ForInternalUseONLY:
Matt Steele
4548-A
Geological Resources, Inc.
WM0601249
03/08/23 MW-7
Minute Man #3 00-0-0000009436
200 E Dr. Martin Luther King Jr. Blvd., Roseboro
Sampson 08104824301
34.956065 78.510184
1
20
14.41
6"
Solid Stem Auger
0
0 5 2 Sch 40 PVC
5 20 2 0.010 Sch 40 PVC
0 1 grout pour
1 3 bentonite pour
3 20 #2 Sand Pour
0 2 Brown silt
2 15 Tan silty clay
15 20 Tan fine sand
03/08/23
_______________
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Depth:
Diameter:Completion Details:
PID Lab
From To (ppm)Sample Description Color Moisture Odor
Depth (ft)Lithology
SITE INFORMATION
DRILLING INFORMATION
BORING INFORMATION
Minute Man #3
3148
03/08/23
Stephanie Gainey
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548-A
MW-8
6"
20
Well installed at completion
0 0.4 Asphalt
0.4 2 Brown silt Dry
2 14 Brown silty clay Moist
14 20 Tan fine sand Wet

Photo 1: Preclearing Photo 2: Completion
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Top of Casing:
Diameter:Depth to Water:
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
Sand
Bentonite
Grout
Screen
Casing
SITE INFORMATION
DRILLING INFORMATION
WELL CONSTRUCTION INFORMATION
DIAGRAM - MONITORING WELL
Sand
Bentonite
Grout Screen
Inner Casing
Outer Casing
Minute Man #3
3148
03/08/23
Stephanie Gainey
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548-A
MW-8
6"
100.76
14.45
3 20
1 3
0 1
0
0 5 2
5 20 2
1
3
20
5
20

WELLCONSTRUCTIONRECORD
Thisformcanbeusedforsingleormultiplewells
FormGW-1 NorthCarolinaDepartmentofEnvironmentandNaturalResources–DivisionofWaterResources RevisedAugust2013
1.WellContractorInformation:

WellContractorName

NCWellContractorCertificationNumber

CompanyName

2.WellConstructionPermit#:
List all applicable well permits (i.e. County, State, Variance, Injection, etc.)

3.WellUse(checkwelluse):
WaterSupplyWell:
□Agricultural□Municipal/Public
□Geothermal(Heating/CoolingSupply)□ResidentialWaterSupply(single)
□Industrial/Commercial□ResidentialWaterSupply(shared)
□Irrigation
Non-WaterSupplyWell:
□Monitoring□Recovery
InjectionWell:
□AquiferRecharge□GroundwaterRemediation
□AquiferStorageandRecovery□SalinityBarrier
□AquiferTest□StormwaterDrainage
□ExperimentalTechnology□SubsidenceControl
□Geothermal(ClosedLoop)□Tracer
□Geothermal(Heating/CoolingReturn)□Other(explainunder#21Remarks)

4.DateWell(s)Completed:____________WellID#______________________

5a.WellLocation:

Facility/OwnerNameFacilityID#(ifapplicable)

PhysicalAddress,City,andZip

CountyParcelIdentificationNo.(PIN)

5b.LatitudeandLongitudeindegrees/minutes/secondsordecimaldegrees:
(ifwellfield,onelat/longissufficient)

N W

6.Is(are)thewell(s):□Permanentor□Temporary

7.Isthisarepairtoanexistingwell:□Yesor□No
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8.Numberofwellsconstructed:
For multiple injection or non-water supply wells ONLY with the same construction, you can
submit one form.

9.Totalwelldepthbelowlandsurface: (ft.)
For multiple wells list all depths if different (example- 3@200’ and 2@100′)

10.Staticwaterlevelbelowtopofcasing:(ft.)
If water level is above casing, use “+”

11.Boreholediameter:(in.)

12.Wellconstructionmethod:
(i.e.auger,rotary,cable,directpush,etc.)

FORWATERSUPPLYWELLSONLY:
13a.Yield(gpm) Methodoftest:

13b.Disinfectiontype:Amount:

14.WATERZONES
FROMTODESCRIPTION
ft.ft.
ft.ft.
15.OUTERCASING(formulti-casedwells)ORLINER(ifapplicable)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
16.INNERCASINGORTUBING(geothermalclosed-loop)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
17.SCREEN
FROMTODIAMETERSLOTSIZETHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
18.GROUT
FROMTOMATERIALEMPLACEMENTMETHOD&AMOUNT
ft.ft.
ft.ft.
ft.ft.
19.SAND/GRAVELPACK(ifapplicable)
FROMTOMATERIALEMPLACEMENTMETHOD
ft.ft.
ft.ft.
20.DRILLINGLOG(attachadditionalsheetsifnecessary)
FROMTODESCRIPTION(color,hardness,soil/rocktype,grainsize,etc.)
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
21.REMARKS

22.Certification:

SignatureofCertifiedWellContractorDateBy signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23.Sitediagramoradditionalwelldetails:Youmayusethebackofthispagetoprovideadditionalwellsitedetailsorwell
constructiondetails.Youmayalsoattachadditionalpagesifnecessary.

SUBMITTALINSTUCTIONS

24a.ForAllWells:Submit this formwithin30daysof completionof well
constructiontothefollowing:
DivisionofWaterResources,InformationProcessingUnit,
1617MailServiceCenter,Raleigh,NC27699-1617
24b.ForInjectionWellsONLY:Inadditiontosendingtheformtotheaddressin
24aabove,alsosubmitacopyofthisformwithin30 daysofcompletionof well
constructiontothefollowing:

DivisionofWaterResources,UndergroundInjectionControlProgram,
1636MailServiceCenter,Raleigh,NC27699-1636
24c.ForWaterSupply&InjectionWells:
Also submitone copyof this form within30days ofcompletionof
wellconstructiontothecountyhealthdepartment ofthecountywhere
constructed.
ForInternalUseONLY:
Matt Steele
4548-A
Geological Resources, Inc.
WM0601248
03/08/23 MW-8
Minute Man #3 00-0-0000009436
200 E Dr. Martin Luther King Jr. Blvd., Roseboro
Sampson 08104824301
34.956065 78.510184
1
20
14.45
6"
Solid Stem Auger
0
0 5 2 Sch 40 PVC
5 20 2 0.010 Sch 40 PVC
0 1 grout pour
1 3 bentonite pour
3 20 #2 Sand Pour
0 0.4 Asphalt
0.4 2 Brown silt
2 14 Brown silty clay
14 20 Tan fine sand
03/08/23
_______________
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Depth:
Diameter:Completion Details:
PID Lab
From To (ppm)Sample Description Color Moisture Odor
Depth (ft)Lithology
SITE INFORMATION
DRILLING INFORMATION
BORING INFORMATION
Minute Man #3
3148
03/08/23
Stephanie Gainey
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548-A
MW-9
6"
20
Well installed at completion
0 0.4 Asphalt
0.4 2 Brown silt Dry
2 9 Brown silty clay Moist
9 15 Red silty clay Moist
15 20 Tan fine sand Wet

Photo 1: Preclearing Photo 2: Completion
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Top of Casing:
Diameter:Depth to Water:
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
Sand
Bentonite
Grout
Screen
Casing
SITE INFORMATION
DRILLING INFORMATION
WELL CONSTRUCTION INFORMATION
DIAGRAM - MONITORING WELL
Sand
Bentonite
Grout Screen
Inner Casing
Outer Casing
Minute Man #3
3148
03/08/23
Stephanie Gainey
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548-A
MW-9
6"
100.77
14.48
3 20
1 3
0 1
0
0 5 2
5 20 2
1
3
20
5
20

WELLCONSTRUCTIONRECORD
Thisformcanbeusedforsingleormultiplewells
FormGW-1 NorthCarolinaDepartmentofEnvironmentandNaturalResources–DivisionofWaterResources RevisedAugust2013
1.WellContractorInformation:

WellContractorName

NCWellContractorCertificationNumber

CompanyName

2.WellConstructionPermit#:
List all applicable well permits (i.e. County, State, Variance, Injection, etc.)

3.WellUse(checkwelluse):
WaterSupplyWell:
□Agricultural□Municipal/Public
□Geothermal(Heating/CoolingSupply)□ResidentialWaterSupply(single)
□Industrial/Commercial□ResidentialWaterSupply(shared)
□Irrigation
Non-WaterSupplyWell:
□Monitoring□Recovery
InjectionWell:
□AquiferRecharge□GroundwaterRemediation
□AquiferStorageandRecovery□SalinityBarrier
□AquiferTest□StormwaterDrainage
□ExperimentalTechnology□SubsidenceControl
□Geothermal(ClosedLoop)□Tracer
□Geothermal(Heating/CoolingReturn)□Other(explainunder#21Remarks)

4.DateWell(s)Completed:____________WellID#______________________

5a.WellLocation:

Facility/OwnerNameFacilityID#(ifapplicable)

PhysicalAddress,City,andZip

CountyParcelIdentificationNo.(PIN)

5b.LatitudeandLongitudeindegrees/minutes/secondsordecimaldegrees:
(ifwellfield,onelat/longissufficient)

N W

6.Is(are)thewell(s):□Permanentor□Temporary

7.Isthisarepairtoanexistingwell:□Yesor□No
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8.Numberofwellsconstructed:
For multiple injection or non-water supply wells ONLY with the same construction, you can
submit one form.

9.Totalwelldepthbelowlandsurface: (ft.)
For multiple wells list all depths if different (example- 3@200’ and 2@100′)

10.Staticwaterlevelbelowtopofcasing:(ft.)
If water level is above casing, use “+”

11.Boreholediameter:(in.)

12.Wellconstructionmethod:
(i.e.auger,rotary,cable,directpush,etc.)

FORWATERSUPPLYWELLSONLY:
13a.Yield(gpm) Methodoftest:

13b.Disinfectiontype:Amount:

14.WATERZONES
FROMTODESCRIPTION
ft.ft.
ft.ft.
15.OUTERCASING(formulti-casedwells)ORLINER(ifapplicable)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
16.INNERCASINGORTUBING(geothermalclosed-loop)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
17.SCREEN
FROMTODIAMETERSLOTSIZETHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
18.GROUT
FROMTOMATERIALEMPLACEMENTMETHOD&AMOUNT
ft.ft.
ft.ft.
ft.ft.
19.SAND/GRAVELPACK(ifapplicable)
FROMTOMATERIALEMPLACEMENTMETHOD
ft.ft.
ft.ft.
20.DRILLINGLOG(attachadditionalsheetsifnecessary)
FROMTODESCRIPTION(color,hardness,soil/rocktype,grainsize,etc.)
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
21.REMARKS

22.Certification:

SignatureofCertifiedWellContractorDateBy signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23.Sitediagramoradditionalwelldetails:Youmayusethebackofthispagetoprovideadditionalwellsitedetailsorwell
constructiondetails.Youmayalsoattachadditionalpagesifnecessary.

SUBMITTALINSTUCTIONS

24a.ForAllWells:Submit this formwithin30daysof completionof well
constructiontothefollowing:
DivisionofWaterResources,InformationProcessingUnit,
1617MailServiceCenter,Raleigh,NC27699-1617
24b.ForInjectionWellsONLY:Inadditiontosendingtheformtotheaddressin
24aabove,alsosubmitacopyofthisformwithin30 daysofcompletionof well
constructiontothefollowing:

DivisionofWaterResources,UndergroundInjectionControlProgram,
1636MailServiceCenter,Raleigh,NC27699-1636
24c.ForWaterSupply&InjectionWells:
Also submitone copyof this form within30days ofcompletionof
wellconstructiontothecountyhealthdepartment ofthecountywhere
constructed.
ForInternalUseONLY:
Matt Steele
4548-A
Geological Resources, Inc.
WM0601248
03/08/23 MW-9
Minute Man #3 00-0-0000009436
200 E Dr. Martin Luther King Jr. Blvd., Roseboro
Sampson 08104824301
34.956065 78.510184
1
20
14.48
6"
Solid Stem Auger
0
0 5 2 Sch 40 PVC
5 20 2 0.010 Sch 40 PVC
0 1 grout pour
1 3 bentonite pour
3 20 #2 Sand Pour
0 0.4 Asphalt
0.4 2 Brown silt
2 9 Brown silty clay
9 15 Red silty clay
15 20 Tan fine sand
03/08/23
_______________
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Depth:
Diameter:Completion Details:
PID Lab
From To (ppm)Sample Description Color Moisture Odor
Depth (ft)Lithology
SITE INFORMATION
DRILLING INFORMATION
BORING INFORMATION
Minute Man #3
3148
03/08/23
Stephanie Gainey
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548-A
MW-10
6"
20
Well installed at completion
0 1 Brown silt Dry
1 4 Tan course sand Dry
4 14 Brown silty clay Moist
14 20 Tan fine sand Wet

Photo 1: Preclearing Photo 2: Completion
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Top of Casing:
Diameter:Depth to Water:
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
Sand
Bentonite
Grout
Screen
Casing
SITE INFORMATION
DRILLING INFORMATION
WELL CONSTRUCTION INFORMATION
DIAGRAM - MONITORING WELL
Sand
Bentonite
Grout Screen
Inner Casing
Outer Casing
Minute Man #3
3148
03/08/23
Stephanie Gainey
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548-A
MW-10
6"
101.30
15.13
3 20
1 3
0 1
0
0 5 2
5 20 2
1
3
20
5
20

WELLCONSTRUCTIONRECORD
Thisformcanbeusedforsingleormultiplewells
FormGW-1 NorthCarolinaDepartmentofEnvironmentandNaturalResources–DivisionofWaterResources RevisedAugust2013
1.WellContractorInformation:

WellContractorName

NCWellContractorCertificationNumber

CompanyName

2.WellConstructionPermit#:
List all applicable well permits (i.e. County, State, Variance, Injection, etc.)

3.WellUse(checkwelluse):
WaterSupplyWell:
□Agricultural□Municipal/Public
□Geothermal(Heating/CoolingSupply)□ResidentialWaterSupply(single)
□Industrial/Commercial□ResidentialWaterSupply(shared)
□Irrigation
Non-WaterSupplyWell:
□Monitoring□Recovery
InjectionWell:
□AquiferRecharge□GroundwaterRemediation
□AquiferStorageandRecovery□SalinityBarrier
□AquiferTest□StormwaterDrainage
□ExperimentalTechnology□SubsidenceControl
□Geothermal(ClosedLoop)□Tracer
□Geothermal(Heating/CoolingReturn)□Other(explainunder#21Remarks)

4.DateWell(s)Completed:____________WellID#______________________

5a.WellLocation:

Facility/OwnerNameFacilityID#(ifapplicable)

PhysicalAddress,City,andZip

CountyParcelIdentificationNo.(PIN)

5b.LatitudeandLongitudeindegrees/minutes/secondsordecimaldegrees:
(ifwellfield,onelat/longissufficient)

N W

6.Is(are)thewell(s):□Permanentor□Temporary

7.Isthisarepairtoanexistingwell:□Yesor□No
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8.Numberofwellsconstructed:
For multiple injection or non-water supply wells ONLY with the same construction, you can
submit one form.

9.Totalwelldepthbelowlandsurface: (ft.)
For multiple wells list all depths if different (example- 3@200’ and 2@100′)

10.Staticwaterlevelbelowtopofcasing:(ft.)
If water level is above casing, use “+”

11.Boreholediameter:(in.)

12.Wellconstructionmethod:
(i.e.auger,rotary,cable,directpush,etc.)

FORWATERSUPPLYWELLSONLY:
13a.Yield(gpm) Methodoftest:

13b.Disinfectiontype:Amount:

14.WATERZONES
FROMTODESCRIPTION
ft.ft.
ft.ft.
15.OUTERCASING(formulti-casedwells)ORLINER(ifapplicable)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
16.INNERCASINGORTUBING(geothermalclosed-loop)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
17.SCREEN
FROMTODIAMETERSLOTSIZETHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
18.GROUT
FROMTOMATERIALEMPLACEMENTMETHOD&AMOUNT
ft.ft.
ft.ft.
ft.ft.
19.SAND/GRAVELPACK(ifapplicable)
FROMTOMATERIALEMPLACEMENTMETHOD
ft.ft.
ft.ft.
20.DRILLINGLOG(attachadditionalsheetsifnecessary)
FROMTODESCRIPTION(color,hardness,soil/rocktype,grainsize,etc.)
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
21.REMARKS

22.Certification:

SignatureofCertifiedWellContractorDateBy signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23.Sitediagramoradditionalwelldetails:Youmayusethebackofthispagetoprovideadditionalwellsitedetailsorwell
constructiondetails.Youmayalsoattachadditionalpagesifnecessary.

SUBMITTALINSTUCTIONS

24a.ForAllWells:Submit this formwithin30daysof completionof well
constructiontothefollowing:
DivisionofWaterResources,InformationProcessingUnit,
1617MailServiceCenter,Raleigh,NC27699-1617
24b.ForInjectionWellsONLY:Inadditiontosendingtheformtotheaddressin
24aabove,alsosubmitacopyofthisformwithin30 daysofcompletionof well
constructiontothefollowing:

DivisionofWaterResources,UndergroundInjectionControlProgram,
1636MailServiceCenter,Raleigh,NC27699-1636
24c.ForWaterSupply&InjectionWells:
Also submitone copyof this form within30days ofcompletionof
wellconstructiontothecountyhealthdepartment ofthecountywhere
constructed.
ForInternalUseONLY:
Matt Steele
4548-A
Geological Resources, Inc.
E032-082-23-00006
03/08/23 MW-10
Minute Man #3 00-0-0000009436
200 E Dr. Martin Luther King Jr. Blvd., Roseboro
Sampson 08104824301
34.956065 78.510184
1
20
15.13
6"
Solid Stem Auger
0
0 5 2 Sch 40 PVC
5 20 2 0.010 Sch 40 PVC
0 1 grout pour
1 3 bentonite pour
3 20 #2 Sand Pour
0 1 Brown silt
1 4 Tan course sand
4 14 Brown silty clay
14 20 Tan fine sand
03/08/23
_______________
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Depth:
Diameter:Completion Details:
PID Lab
From To (ppm)Sample Description Color Moisture Odor
Depth (ft)Lithology
SITE INFORMATION
DRILLING INFORMATION
BORING INFORMATION
Minute Man #3
3148
03/08/23
Stephanie Gainey
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548-A
MW-11
6"
20
Well installed at completion
0 1 Brown silt Dry
1 4 Tan course sand Dry
4 14 Brown silty clay Moist
14 20 Tan fine sand Wet

Photo 1: Preclearing Photo 2: Completion
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Top of Casing:
Diameter:Depth to Water:
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
Sand
Bentonite
Grout
Screen
Casing
SITE INFORMATION
DRILLING INFORMATION
WELL CONSTRUCTION INFORMATION
DIAGRAM - MONITORING WELL
Sand
Bentonite
Grout Screen
Inner Casing
Outer Casing
Minute Man #3
3148
03/08/23
Stephanie Gainey
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548-A
MW-11
6"
101.04
14.89
3 20
1 3
0 1
0
0 5 2
5 20 2
1
3
20
5
20

WELLCONSTRUCTIONRECORD
Thisformcanbeusedforsingleormultiplewells
FormGW-1 NorthCarolinaDepartmentofEnvironmentandNaturalResources–DivisionofWaterResources RevisedAugust2013
1.WellContractorInformation:

WellContractorName

NCWellContractorCertificationNumber

CompanyName

2.WellConstructionPermit#:
List all applicable well permits (i.e. County, State, Variance, Injection, etc.)

3.WellUse(checkwelluse):
WaterSupplyWell:
□Agricultural□Municipal/Public
□Geothermal(Heating/CoolingSupply)□ResidentialWaterSupply(single)
□Industrial/Commercial□ResidentialWaterSupply(shared)
□Irrigation
Non-WaterSupplyWell:
□Monitoring□Recovery
InjectionWell:
□AquiferRecharge□GroundwaterRemediation
□AquiferStorageandRecovery□SalinityBarrier
□AquiferTest□StormwaterDrainage
□ExperimentalTechnology□SubsidenceControl
□Geothermal(ClosedLoop)□Tracer
□Geothermal(Heating/CoolingReturn)□Other(explainunder#21Remarks)

4.DateWell(s)Completed:____________WellID#______________________

5a.WellLocation:

Facility/OwnerNameFacilityID#(ifapplicable)

PhysicalAddress,City,andZip

CountyParcelIdentificationNo.(PIN)

5b.LatitudeandLongitudeindegrees/minutes/secondsordecimaldegrees:
(ifwellfield,onelat/longissufficient)

N W

6.Is(are)thewell(s):□Permanentor□Temporary

7.Isthisarepairtoanexistingwell:□Yesor□No
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8.Numberofwellsconstructed:
For multiple injection or non-water supply wells ONLY with the same construction, you can
submit one form.

9.Totalwelldepthbelowlandsurface: (ft.)
For multiple wells list all depths if different (example- 3@200’ and 2@100′)

10.Staticwaterlevelbelowtopofcasing:(ft.)
If water level is above casing, use “+”

11.Boreholediameter:(in.)

12.Wellconstructionmethod:
(i.e.auger,rotary,cable,directpush,etc.)

FORWATERSUPPLYWELLSONLY:
13a.Yield(gpm) Methodoftest:

13b.Disinfectiontype:Amount:

14.WATERZONES
FROMTODESCRIPTION
ft.ft.
ft.ft.
15.OUTERCASING(formulti-casedwells)ORLINER(ifapplicable)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
16.INNERCASINGORTUBING(geothermalclosed-loop)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
17.SCREEN
FROMTODIAMETERSLOTSIZETHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
18.GROUT
FROMTOMATERIALEMPLACEMENTMETHOD&AMOUNT
ft.ft.
ft.ft.
ft.ft.
19.SAND/GRAVELPACK(ifapplicable)
FROMTOMATERIALEMPLACEMENTMETHOD
ft.ft.
ft.ft.
20.DRILLINGLOG(attachadditionalsheetsifnecessary)
FROMTODESCRIPTION(color,hardness,soil/rocktype,grainsize,etc.)
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
21.REMARKS

22.Certification:

SignatureofCertifiedWellContractorDateBy signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23.Sitediagramoradditionalwelldetails:Youmayusethebackofthispagetoprovideadditionalwellsitedetailsorwell
constructiondetails.Youmayalsoattachadditionalpagesifnecessary.

SUBMITTALINSTUCTIONS

24a.ForAllWells:Submit this formwithin30daysof completionof well
constructiontothefollowing:
DivisionofWaterResources,InformationProcessingUnit,
1617MailServiceCenter,Raleigh,NC27699-1617
24b.ForInjectionWellsONLY:Inadditiontosendingtheformtotheaddressin
24aabove,alsosubmitacopyofthisformwithin30 daysofcompletionof well
constructiontothefollowing:

DivisionofWaterResources,UndergroundInjectionControlProgram,
1636MailServiceCenter,Raleigh,NC27699-1636
24c.ForWaterSupply&InjectionWells:
Also submitone copyof this form within30days ofcompletionof
wellconstructiontothecountyhealthdepartment ofthecountywhere
constructed.
ForInternalUseONLY:
Matt Steele
4548-A
Geological Resources, Inc.
E032-082-23-00006
03/08/23 MW-11
Minute Man #3 00-0-0000009436
200 E Dr. Martin Luther King Jr. Blvd., Roseboro
Sampson 08104824301
34.956065 78.510184
1
20
14.89
6"
Solid Stem Auger
0
0 5 2 Sch 40 PVC
5 20 2 0.010 Sch 40 PVC
0 1 grout pour
1 3 bentonite pour
3 20 #2 Sand Pour
0 1 Brown silt
1 4 Tan course sand
4 14 Brown silty clay
14 20 Tan fine sand
03/08/23
_______________
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Depth:
Diameter:Completion Details:
PID Lab
From To (ppm)Sample Description Color Moisture Odor
Depth (ft)Lithology
SITE INFORMATION
DRILLING INFORMATION
BORING INFORMATION
Minute Man #3
3148
03/08/23
Stephanie Gainey
Geological Resources, Inc.
Matt Steele
Mud Rotary
4548-A
TW-1
4
45
Well installed at completion
0 0.4 Asphalt
0.4 1 Brown sandy silt Dry
1 7 Brown silty clay Dry
7 15 Red silty clay Moist
15 22 Tan fine sand Moist
22 26 Tan fine sand Wet
26 30 Gray stiff clay Moist
30 37 Gray clay Wet
37 45 Gray clay with course sand Wet

Photo 1: Preclearing Photo 2: Completion
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Top of Casing:
Diameter:Depth to Water:
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
SITE INFORMATION
DRILLING INFORMATION
WELL CONSTRUCTION INFORMATION
Sand Outer Casing
Bentonite
Grout
Inner Casing
Screen
Screen
Bentonite
Sand
DIAGRAM - TELESCOPING WELL
Grout
Outer
Casing
Inner Casing
Minute Man #3
3148
03/08/23
Stephanie Gainey
Geological Resources, Inc.
Matt Steele
Mud Rotary
4548-A
TW-1
4
99.86
13.64
38 45
36 38
0 36
0 30 5
30 40 2
40 45 2
36
38
45
30
40
45

WELLCONSTRUCTIONRECORD
Thisformcanbeusedforsingleormultiplewells
FormGW-1 NorthCarolinaDepartmentofEnvironmentandNaturalResources–DivisionofWaterResources RevisedAugust2013
1.WellContractorInformation:

WellContractorName

NCWellContractorCertificationNumber

CompanyName

2.WellConstructionPermit#:
List all applicable well permits (i.e. County, State, Variance, Injection, etc.)

3.WellUse(checkwelluse):
WaterSupplyWell:
□Agricultural□Municipal/Public
□Geothermal(Heating/CoolingSupply)□ResidentialWaterSupply(single)
□Industrial/Commercial□ResidentialWaterSupply(shared)
□Irrigation
Non-WaterSupplyWell:
□Monitoring□Recovery
InjectionWell:
□AquiferRecharge□GroundwaterRemediation
□AquiferStorageandRecovery□SalinityBarrier
□AquiferTest□StormwaterDrainage
□ExperimentalTechnology□SubsidenceControl
□Geothermal(ClosedLoop)□Tracer
□Geothermal(Heating/CoolingReturn)□Other(explainunder#21Remarks)

4.DateWell(s)Completed:____________WellID#______________________

5a.WellLocation:

Facility/OwnerNameFacilityID#(ifapplicable)

PhysicalAddress,City,andZip

CountyParcelIdentificationNo.(PIN)

5b.LatitudeandLongitudeindegrees/minutes/secondsordecimaldegrees:
(ifwellfield,onelat/longissufficient)

N W

6.Is(are)thewell(s):□Permanentor□Temporary

7.Isthisarepairtoanexistingwell:□Yesor□No
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8.Numberofwellsconstructed:
For multiple injection or non-water supply wells ONLY with the same construction, you can
submit one form.

9.Totalwelldepthbelowlandsurface: (ft.)
For multiple wells list all depths if different (example- 3@200’ and 2@100′)

10.Staticwaterlevelbelowtopofcasing:(ft.)
If water level is above casing, use “+”

11.Boreholediameter:(in.)

12.Wellconstructionmethod:
(i.e.auger,rotary,cable,directpush,etc.)

FORWATERSUPPLYWELLSONLY:
13a.Yield(gpm) Methodoftest:

13b.Disinfectiontype:Amount:

14.WATERZONES
FROMTODESCRIPTION
ft.ft.
ft.ft.
15.OUTERCASING(formulti-casedwells)ORLINER(ifapplicable)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
16.INNERCASINGORTUBING(geothermalclosed-loop)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
17.SCREEN
FROMTODIAMETERSLOTSIZETHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
18.GROUT
FROMTOMATERIALEMPLACEMENTMETHOD&AMOUNT
ft.ft.
ft.ft.
ft.ft.
19.SAND/GRAVELPACK(ifapplicable)
FROMTOMATERIALEMPLACEMENTMETHOD
ft.ft.
ft.ft.
20.DRILLINGLOG(attachadditionalsheetsifnecessary)
FROMTODESCRIPTION(color,hardness,soil/rocktype,grainsize,etc.)
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
21.REMARKS

22.Certification:

SignatureofCertifiedWellContractorDateBy signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23.Sitediagramoradditionalwelldetails:Youmayusethebackofthispagetoprovideadditionalwellsitedetailsorwell
constructiondetails.Youmayalsoattachadditionalpagesifnecessary.

SUBMITTALINSTUCTIONS

24a.ForAllWells:Submit this formwithin30daysof completionof well
constructiontothefollowing:
DivisionofWaterResources,InformationProcessingUnit,
1617MailServiceCenter,Raleigh,NC27699-1617
24b.ForInjectionWellsONLY:Inadditiontosendingtheformtotheaddressin
24aabove,alsosubmitacopyofthisformwithin30 daysofcompletionof well
constructiontothefollowing:

DivisionofWaterResources,UndergroundInjectionControlProgram,
1636MailServiceCenter,Raleigh,NC27699-1636
24c.ForWaterSupply&InjectionWells:
Also submitone copyof this form within30days ofcompletionof
wellconstructiontothecountyhealthdepartment ofthecountywhere
constructed.
ForInternalUseONLY:
Matt Steele
4548-A
Geological Resources, Inc.
WM0601249
03/08/23 TW-1
Minute Man #3 00-0-0000009436
200 E Dr. Martin Luther King Jr. Blvd., Roseboro
Sampson 08104824301
34.956065 78.510184
1
45
13.64
4
Mud Rotary
0 30 5
30 40 2 Sch 40 PVC
40 45 2 0.010 Sch 40 PVC
0 36 grout pour
36 38 bentonite pour
38 45 #2 Sand Pour
0 0.4 Asphalt
0.4 1 Brown sandy silt
1 7 Brown silty clay
7 15 Red silty clay
15 22 Tan fine sand
22 26 Tan fine sand
26 30 Gray stiff clay
30'-37' Gray clay; 37'-45' Gray clay with course sand
03/08/23
_______________
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Depth:
Diameter:Completion Details:
PID Lab
From To (ppm)Sample Description Color Moisture Odor
Depth (ft)Lithology
SITE INFORMATION
DRILLING INFORMATION
BORING INFORMATION
Photo 1: Preclearing Photo 2: Completion
Minute Man #3
3148
09/12/23
L. Weathersby
Geological Resources, Inc.
Matt Steele
Direct Push
4548-A
MW-12
3.25"
20
Well installed at completion
0 1 Silt brown Dry
1 4 Sandy silt tan Dry
4 20 DPT; no recovery

Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Top of Casing:
Diameter:Depth to Water:
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
Sand
Bentonite
Grout
Screen
Casing
SITE INFORMATION
DRILLING INFORMATION
WELL CONSTRUCTION INFORMATION
DIAGRAM - MONITORING WELL
Sand
Bentonite
Grout Screen
Inner Casing
Outer Casing
Minute Man #3
3148
09/12/23
L. Weathersby
Geological Resources, Inc.
Matt Steele
Direct Push
4548-A
MW-12
3.25"
100.71
unknown
3 20
1 3
0 1
0 5 2
5 20 2
1
3
20
5
20
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Top of Casing:
Diameter:Depth to Water:
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
SITE INFORMATION
DRILLING INFORMATION
WELL CONSTRUCTION INFORMATION
Sand Outer Casing
Bentonite
Grout
Inner Casing
Screen
Screen
Bentonite
Sand
DIAGRAM - TELESCOPING WELL
Grout
Outer
Casing
Inner Casing
Minute Man #3
3148
09/12/23
L. Weathersby
Geological Resources, Inc.
Matt Steele
Direct Push
4548-A
MW-12
3.25"
100.71
unknown
3 20
1 3
0 1
0 5 2
5 20 2
1
3
20
5
20

WELLCONSTRUCTIONRECORD
Thisformcanbeusedforsingleormultiplewells
FormGW-1 NorthCarolinaDepartmentofEnvironmentandNaturalResources–DivisionofWaterResources RevisedAugust2013
1.WellContractorInformation:

WellContractorName

NCWellContractorCertificationNumber

CompanyName

2.WellConstructionPermit#:
List all applicable well permits (i.e. County, State, Variance, Injection, etc.)

3.WellUse(checkwelluse):
WaterSupplyWell:
□Agricultural□Municipal/Public
□Geothermal(Heating/CoolingSupply)□ResidentialWaterSupply(single)
□Industrial/Commercial□ResidentialWaterSupply(shared)
□Irrigation
Non-WaterSupplyWell:
□Monitoring□Recovery
InjectionWell:
□AquiferRecharge□GroundwaterRemediation
□AquiferStorageandRecovery□SalinityBarrier
□AquiferTest□StormwaterDrainage
□ExperimentalTechnology□SubsidenceControl
□Geothermal(ClosedLoop)□Tracer
□Geothermal(Heating/CoolingReturn)□Other(explainunder#21Remarks)

4.DateWell(s)Completed:____________WellID#______________________

5a.WellLocation:

Facility/OwnerNameFacilityID#(ifapplicable)

PhysicalAddress,City,andZip

CountyParcelIdentificationNo.(PIN)

5b.LatitudeandLongitudeindegrees/minutes/secondsordecimaldegrees:
(ifwellfield,onelat/longissufficient)

N W

6.Is(are)thewell(s):□Permanentor□Temporary

7.Isthisarepairtoanexistingwell:□Yesor□No
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8.Numberofwellsconstructed:
For multiple injection or non-water supply wells ONLY with the same construction, you can
submit one form.

9.Totalwelldepthbelowlandsurface: (ft.)
For multiple wells list all depths if different (example- 3@200’ and 2@100′)

10.Staticwaterlevelbelowtopofcasing:(ft.)
If water level is above casing, use “+”

11.Boreholediameter:(in.)

12.Wellconstructionmethod:
(i.e.auger,rotary,cable,directpush,etc.)

FORWATERSUPPLYWELLSONLY:
13a.Yield(gpm) Methodoftest:

13b.Disinfectiontype:Amount:

14.WATERZONES
FROMTODESCRIPTION
ft.ft.
ft.ft.
15.OUTERCASING(formulti-casedwells)ORLINER(ifapplicable)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
16.INNERCASINGORTUBING(geothermalclosed-loop)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
17.SCREEN
FROMTODIAMETERSLOTSIZETHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
18.GROUT
FROMTOMATERIALEMPLACEMENTMETHOD&AMOUNT
ft.ft.
ft.ft.
ft.ft.
19.SAND/GRAVELPACK(ifapplicable)
FROMTOMATERIALEMPLACEMENTMETHOD
ft.ft.
ft.ft.
20.DRILLINGLOG(attachadditionalsheetsifnecessary)
FROMTODESCRIPTION(color,hardness,soil/rocktype,grainsize,etc.)
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
21.REMARKS

22.Certification:

SignatureofCertifiedWellContractorDateBy signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23.Sitediagramoradditionalwelldetails:Youmayusethebackofthispagetoprovideadditionalwellsitedetailsorwell
constructiondetails.Youmayalsoattachadditionalpagesifnecessary.

SUBMITTALINSTUCTIONS

24a.ForAllWells:Submit this formwithin30daysof completionof well
constructiontothefollowing:
DivisionofWaterResources,InformationProcessingUnit,
1617MailServiceCenter,Raleigh,NC27699-1617
24b.ForInjectionWellsONLY:Inadditiontosendingtheformtotheaddressin
24aabove,alsosubmitacopyofthisformwithin30 daysofcompletionof well
constructiontothefollowing:

DivisionofWaterResources,UndergroundInjectionControlProgram,
1636MailServiceCenter,Raleigh,NC27699-1636
24c.ForWaterSupply&InjectionWells:
Also submitone copyof this form within30days ofcompletionof
wellconstructiontothecountyhealthdepartment ofthecountywhere
constructed.
ForInternalUseONLY:
_______________
Matt Steele
4548-A
Geological Resources, Inc.
09/12/23 MW-12
Minute Man #3 00-0-0000009436
200 E Dr. Martin Luther King Jr. Blvd, Roseboro, NC
Sampson 08104824301
34.9557861 78.5102027
1
20
unknown
3.25"
Direct Push
0 5 2 Sch 40 PVC
5 20 2 0.010 Sch 40 PVC
0 1 grout pour
1 3 bentonite pour
3 20 #2 Sand Pour
0 1 Silt
1 4 Sandy silt
4 20 DPT; no recovery
09/12/23
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Depth:
Diameter:Completion Details:
PID Lab
From To (ppm)Sample Description Color Moisture Odor
Depth (ft)Lithology
SITE INFORMATION
DRILLING INFORMATION
BORING INFORMATION
Photo 1: Preclearing Photo 2: Completion
Minute Man #3
3148
09/12/23
L. Weathersby
Geological Resources, Inc.
Matt Steele
Direct Push
4548-A
MW-13
3.25"
20
Well installed at completion
0 1 Silt brown Dry
1 4 Sandy silt tan Dry
4 20 DPT; no recovery

Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Top of Casing:
Diameter:Depth to Water:
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
Sand
Bentonite
Grout
Screen
Casing
SITE INFORMATION
DRILLING INFORMATION
WELL CONSTRUCTION INFORMATION
DIAGRAM - MONITORING WELL
Sand
Bentonite
Grout Screen
Inner Casing
Outer Casing
Minute Man #3
3148
09/12/23
L. Weathersby
Geological Resources, Inc.
Matt Steele
Direct Push
4548-A
MW-13
3.25"
100.71
unknown
3 20
1 3
0 1
0 5 2
5 20 2
1
3
20
5
20
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Top of Casing:
Diameter:Depth to Water:
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
SITE INFORMATION
DRILLING INFORMATION
WELL CONSTRUCTION INFORMATION
Sand Outer Casing
Bentonite
Grout
Inner Casing
Screen
Screen
Bentonite
Sand
DIAGRAM - TELESCOPING WELL
Grout
Outer
Casing
Inner Casing
Minute Man #3
3148
09/12/23
L. Weathersby
Geological Resources, Inc.
Matt Steele
Direct Push
4548-A
MW-13
3.25"
100.71
unknown
3 20
1 3
0 1
0 5 2
5 20 2
1
3
20
5
20

WELLCONSTRUCTIONRECORD
Thisformcanbeusedforsingleormultiplewells
FormGW-1 NorthCarolinaDepartmentofEnvironmentandNaturalResources–DivisionofWaterResources RevisedAugust2013
1.WellContractorInformation:

WellContractorName

NCWellContractorCertificationNumber

CompanyName

2.WellConstructionPermit#:
List all applicable well permits (i.e. County, State, Variance, Injection, etc.)

3.WellUse(checkwelluse):
WaterSupplyWell:
□Agricultural□Municipal/Public
□Geothermal(Heating/CoolingSupply)□ResidentialWaterSupply(single)
□Industrial/Commercial□ResidentialWaterSupply(shared)
□Irrigation
Non-WaterSupplyWell:
□Monitoring□Recovery
InjectionWell:
□AquiferRecharge□GroundwaterRemediation
□AquiferStorageandRecovery□SalinityBarrier
□AquiferTest□StormwaterDrainage
□ExperimentalTechnology□SubsidenceControl
□Geothermal(ClosedLoop)□Tracer
□Geothermal(Heating/CoolingReturn)□Other(explainunder#21Remarks)

4.DateWell(s)Completed:____________WellID#______________________

5a.WellLocation:

Facility/OwnerNameFacilityID#(ifapplicable)

PhysicalAddress,City,andZip

CountyParcelIdentificationNo.(PIN)

5b.LatitudeandLongitudeindegrees/minutes/secondsordecimaldegrees:
(ifwellfield,onelat/longissufficient)

N W

6.Is(are)thewell(s):□Permanentor□Temporary

7.Isthisarepairtoanexistingwell:□Yesor□No
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8.Numberofwellsconstructed:
For multiple injection or non-water supply wells ONLY with the same construction, you can
submit one form.

9.Totalwelldepthbelowlandsurface: (ft.)
For multiple wells list all depths if different (example- 3@200’ and 2@100′)

10.Staticwaterlevelbelowtopofcasing:(ft.)
If water level is above casing, use “+”

11.Boreholediameter:(in.)

12.Wellconstructionmethod:
(i.e.auger,rotary,cable,directpush,etc.)

FORWATERSUPPLYWELLSONLY:
13a.Yield(gpm) Methodoftest:

13b.Disinfectiontype:Amount:

14.WATERZONES
FROMTODESCRIPTION
ft.ft.
ft.ft.
15.OUTERCASING(formulti-casedwells)ORLINER(ifapplicable)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
16.INNERCASINGORTUBING(geothermalclosed-loop)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
17.SCREEN
FROMTODIAMETERSLOTSIZETHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
18.GROUT
FROMTOMATERIALEMPLACEMENTMETHOD&AMOUNT
ft.ft.
ft.ft.
ft.ft.
19.SAND/GRAVELPACK(ifapplicable)
FROMTOMATERIALEMPLACEMENTMETHOD
ft.ft.
ft.ft.
20.DRILLINGLOG(attachadditionalsheetsifnecessary)
FROMTODESCRIPTION(color,hardness,soil/rocktype,grainsize,etc.)
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
21.REMARKS

22.Certification:

SignatureofCertifiedWellContractorDateBy signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23.Sitediagramoradditionalwelldetails:Youmayusethebackofthispagetoprovideadditionalwellsitedetailsorwell
constructiondetails.Youmayalsoattachadditionalpagesifnecessary.

SUBMITTALINSTUCTIONS

24a.ForAllWells:Submit this formwithin30daysof completionof well
constructiontothefollowing:
DivisionofWaterResources,InformationProcessingUnit,
1617MailServiceCenter,Raleigh,NC27699-1617
24b.ForInjectionWellsONLY:Inadditiontosendingtheformtotheaddressin
24aabove,alsosubmitacopyofthisformwithin30 daysofcompletionof well
constructiontothefollowing:

DivisionofWaterResources,UndergroundInjectionControlProgram,
1636MailServiceCenter,Raleigh,NC27699-1636
24c.ForWaterSupply&InjectionWells:
Also submitone copyof this form within30days ofcompletionof
wellconstructiontothecountyhealthdepartment ofthecountywhere
constructed.
ForInternalUseONLY:
_______________
Matt Steele
4548-A
Geological Resources, Inc.
09/12/23 MW-13
Minute Man #3 00-0-0000009436
200 E Dr. Martin Luther King Jr. Blvd, Roseboro, NC
Sampson 08104824301
34.9557861 78.5102027
1
20
unknown
3.25"
Direct Push
0 5 2 Sch 40 PVC
5 20 2 0.010 Sch 40 PVC
0 1 grout pour
1 3 bentonite pour
3 20 #2 Sand Pour
0 1 Silt
1 4 Sandy silt
4 20 DPT; no recovery
09/12/23

APPENDIX F
Laboratory Analytical Reports

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

3/30/2023

GeologicalResources,Inc.
3502HayesRoad
Monroe,NC,28110

Ref: AnalyticalTesting
LabReportNumber:23-073-0013
ClientProjectDescription:MinuteMan#3
GRI#3148

WaypointAnalytical,LLC(Charlotte)receivedsample(s)on3/14/2023fortheanalysespresentedinthe
followingreport.

Theabovereferencedprojecthasbeenanalyzedperyourinstructions.Theanalyseswereperformedin
accordancewiththeapplicableanalyticalmethod.

Theanalyticaldatahasbeenvalidatedusingstandardqualitycontrolmeasuresperformedasrequiredbythe
analyticalmethod.QualityAssurance,methodvalidations,instrumentationmaintenanceandcalibrationforall
parameterswereperformedinaccordancewithguidelinesestablishedbytheUSEPA(including40CFR136
MethodUpdateRuleMay2021)unlessotherwiseindicated.

Certainparameters(chlorine,pH,dissolvedoxygen,sulfite...)arerequiredtobeanalyzedwithin15minutesof
sampling.Usually,butnotalways,anyfieldparameteranalyzedatthelaboratoryisoutsideofthisholdingtime.
Refertosampleanalysistimeforconfirmationofholdingtimecompliance.

TheresultsareshownontheattachedReportofAnalysis(s).Resultsforsolidmatricesarereportedonanas-
receivedbasisunlessotherwiseindicated.Thisreportshallnotbereproducedexceptinfullandrelatesonlyto
thesamplesincludedinthisreport.

Pleasedonothesitatetocontactmeorclientservicesifyouhaveanyquestionsorneedadditionalinformation.

Sincerely,
DanyaleLove
ProjectManager
Page 1 of 163
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2023402State ProgramNorth Carolina
07/31/202399012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State Program Lab ID Expiration Date
02/29/202440750State ProgramAlabama
02/07/202488-0650State ProgramArkansas
06/30/20232904State ProgramCalifornia
06/30/2023E871157State Program - NELAPFlorida
11/14/2025C044State ProgramGeorgia
06/30/202304015State ProgramGeorgia
10/10/2023200078State Program - NELAPIllinois
06/30/202380215State ProgramKentucky
12/31/2023KY90047State ProgramKentucky
12/31/2023LA037State Program - NELAPLouisiana
06/30/202304015State Program - NELAPLouisiana
02/11/2023MSState ProgramMississippi
07/31/202347701State ProgramNorth Carolina
12/31/2023415State ProgramNorth Carolina
05/31/202368-03195State Program - NELAPPennsylvania
06/30/202384002State ProgramSouth Carolina
11/14/202502027State ProgramTennessee
09/30/2023T104704180State Program - NELAPTexas
06/30/202300106State ProgramVirginia
09/14/2023460181State Program - NELAPVirginia
Page 1 of 1 00016/23-073-0013
Page 2 of 163
Report Number:
Sample Summary Table
Client Project Description:
23-073-0013
Minute Man #3
GRI #3148
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
03/08/2023 14:24Solids 91094 MW-8 (16')03/14/2023 11:00 SIEVE TEST WP MTN -
03/08/2023 14:24Solids 91094 MW-8 (16')03/14/2023 11:00 SIEVE WP MTN -
03/08/2023 14:24Solids 91094 MW-8 (16')03/14/2023 11:00 Texture WP MTN -
03/08/2023 14:24Solids 91094 MW-8 (16')03/14/2023 11:00 WALK-BLACK WP MTN -
03/08/2023 15:09Solids 91095 MW-7 (16')03/14/2023 11:00 SIEVE TEST WP MTN -
03/08/2023 15:09Solids 91095 MW-7 (16')03/14/2023 11:00 Texture WP MTN -
03/08/2023 15:09Solids 91095 MW-7 (16')03/14/2023 11:00 SIEVE WP MTN -
03/08/2023 15:09Solids 91095 MW-7 (16')03/14/2023 11:00 WALK-BLACK WP MTN -
03/09/2023 12:17Solids 91096 TW-1 (42')03/14/2023 11:00 WALK-BLACK WP MTN -
03/09/2023 12:17Solids 91096 TW-1 (42')03/14/2023 11:00 Texture WP MTN -
03/09/2023 12:17Solids 91096 TW-1 (42')03/14/2023 11:00 SIEVE TEST WP MTN -
03/09/2023 12:17Solids 91096 TW-1 (42')03/14/2023 11:00 SIEVE WP MTN -
03/08/2023 09:47Solids 91097 SB-1 (18')03/14/2023 11:00
03/08/2023 13:31Solids 91098 SB-2 (20')03/14/2023 11:00
03/13/2023 11:52Aqueous 91099 TW-1 03/14/2023 11:00
03/13/2023 12:17Aqueous 91100 MW-11 03/14/2023 11:00
03/13/2023 12:41Aqueous 91101 MW-10 03/14/2023 11:00
03/13/2023 08:08Aqueous 91102 Trip Blank 03/14/2023 11:00
03/13/2023 13:04Aqueous 91103 MW-9 03/14/2023 11:00
03/13/2023 13:27Aqueous 91104 MW-8 03/14/2023 11:00
03/13/2023 13:50Aqueous 91105 MW-7 03/14/2023 11:00
03/13/2023 14:06Aqueous 91106 MW-6 03/14/2023 11:00
03/13/2023 14:19Aqueous 91107 MW-3 03/14/2023 11:00
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 3 of 163
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-073-0013
Report Limit
Project:Minute Man #3
V 91094MW-8 (16')
99.9 03/23/2023 11:00SIEVE% Passing 10 Mesh %0.1
95.9 03/23/2023 11:00SIEVE% Passing 40 Mesh %0.1
56.0 03/23/2023 11:00SIEVE% Passing 60 Mesh %0.1
21.3 03/23/2023 11:00SIEVE TEST % Passing 100 Mesh %0.1
99.4 03/23/2023 11:00SIEVE TEST % Passing 20 Mesh %0.1
17.3 03/23/2023 11:00SIEVE TEST % Passing 200 Mesh %0.1
100.0 03/23/2023 11:00SIEVE TEST % Passing 4 Mesh %0.1
9.0 03/20/2023 08:12Texture%Clay %0.1
90.0 03/20/2023 08:12Texture%Sand %0.1
1.0 03/20/2023 08:12Texture%Silt %0.1
Sand 03/20/2023 08:12TextureSoil Classification
0.11 03/22/2023 10:25WALK-BLACK Total Organic Carbon %0.05
V 91095MW-7 (16')
100.0 03/23/2023 11:00SIEVE% Passing 10 Mesh %0.1
98.5 03/23/2023 11:00SIEVE% Passing 40 Mesh %0.1
64.0 03/23/2023 11:00SIEVE% Passing 60 Mesh %0.1
26.3 03/23/2023 11:00SIEVE TEST % Passing 100 Mesh %0.1
100.0 03/23/2023 11:00SIEVE TEST % Passing 20 Mesh %0.1
22.5 03/23/2023 11:00SIEVE TEST % Passing 200 Mesh %0.1
100.0 03/23/2023 11:00SIEVE TEST % Passing 4 Mesh %0.1
9.0 03/20/2023 08:12Texture%Clay %0.1
90.0 03/20/2023 08:12Texture%Sand %0.1
1.0 03/20/2023 08:12Texture%Silt %0.1
Sand 03/20/2023 08:12TextureSoil Classification
0.11 03/22/2023 10:25WALK-BLACK Total Organic Carbon %0.05
V 91096TW-1 (42')
91.7 03/23/2023 11:00SIEVE% Passing 10 Mesh %0.1
49.3 03/23/2023 11:00SIEVE% Passing 40 Mesh %0.1
36.3 03/23/2023 11:00SIEVE% Passing 60 Mesh %0.1
30.1 03/23/2023 11:00SIEVE TEST % Passing 100 Mesh %0.1
68.9 03/23/2023 11:00SIEVE TEST % Passing 20 Mesh %0.1
26.6 03/23/2023 11:00SIEVE TEST % Passing 200 Mesh %0.1
99.4 03/23/2023 11:00SIEVE TEST % Passing 4 Mesh %0.1
19.0 03/20/2023 08:12Texture%Clay %0.1
70.0 03/20/2023 08:12Texture%Sand %0.1
11.0 03/20/2023 08:12Texture%Silt %0.1
Page 4 of 163
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-073-0013
Report Limit
Project:Minute Man #3
V 91096TW-1 (42')
Sandy Loam 03/20/2023 08:12TextureSoil Classification
3.01 03/22/2023 10:25WALK-BLACK Total Organic Carbon %0.05
V 91097SB-1 (18')
5.48 03/15/2023 15:538260DBenzenemg/Kg - dry 0.181
10.4 03/15/2023 15:538260Dn-Butylbenzene mg/Kg - dry 0.153
4.44 03/15/2023 15:538260Dsec-Butyl benzene mg/Kg - dry 0.175
87.1 03/15/2023 15:538260DEthylbenzenemg/Kg - dry 0.181
32.7 03/15/2023 15:538260Dn-Hexane mg/Kg - dry 0.206
8.95 03/15/2023 15:538260DIsopropylbenzenemg/Kg - dry 0.143
2.57 03/15/2023 15:538260D4-Isopropyl toluene mg/Kg - dry 0.406
J0.461 03/15/2023 15:538260DMethylene Chloride mg/Kg - dry 0.460
33.9 03/15/2023 15:538260DNaphthalenemg/Kg - dry 0.310
31.5 03/15/2023 15:538260Dn-Propylbenzene mg/Kg - dry 0.168
J1.17 03/15/2023 15:538260DStyrenemg/Kg - dry 0.444
230 03/15/2023 16:208260DToluenemg/Kg - dry 2.07
214 03/15/2023 16:208260D1,2,4-Trimethylbenzene mg/Kg - dry 1.54
56.4 03/15/2023 15:538260D1,3,5-Trimethylbenzene mg/Kg - dry 0.168
110 03/15/2023 15:538260Do-Xylene mg/Kg - dry 0.156
338 03/15/2023 16:208260Dm,p-Xylene mg/Kg - dry 3.94
448 03/15/2023 15:538260DXylene (Total)mg/Kg - dry 0.156
6.12 03/17/2023 18:588270E1-Methylnaphthalene mg/Kg - dry 0.132
13.4 03/21/2023 20:138270E2-Methylnaphthalene mg/Kg - dry 0.500
13.1 03/21/2023 20:138270ENaphthalenemg/Kg - dry 0.720
2670 03/15/2023 15:53CALCULATIONAliphatic C5-C8 (Adjusted)mg/Kg - dry 7.61
554 03/15/2023 15:53CALCULATIONAliphatics C9-C12 (Adjusted)mg/Kg - dry 28.5
1910 03/15/2023 18:48CALCULATIONAromatic C9-C10 (Adjusted)mg/Kg - dry 3.90
347 03/17/2023 18:58CALCULATIONAromatic C11-C22 (Adjusted)mg/Kg - dry 89.2
894 03/21/2023 18:57MADEP-EPH Aliphatic C9-C18 mg/Kg - dry 57.8
359 03/21/2023 18:57MADEP-EPH Aromatic C11-C22 mg/Kg - dry 89.2
2900 03/15/2023 18:48MADEP-VPH Aliphatic C5-C8 mg/Kg - dry 7.61
3000 03/15/2023 18:48MADEP-VPH Aliphatic C9-C12 mg/Kg - dry 28.5
1910 03/15/2023 18:48MADEP-VPH Aromatic C9-C10 mg/Kg - dry 3.90
20.1 03/20/2023 18:38SW-DRYWT Moisture %
V 91098SB-2 (20')
J0.576 03/15/2023 14:598260DBenzenemg/Kg - dry 0.180
4.35 03/15/2023 14:598260Dn-Butylbenzene mg/Kg - dry 0.153
Page 5 of 163
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-073-0013
Report Limit
Project:Minute Man #3
V 91098SB-2 (20')
2.03 03/15/2023 14:598260Dsec-Butyl benzene mg/Kg - dry 0.174
25.9 03/15/2023 14:598260DEthylbenzenemg/Kg - dry 0.180
19.3 03/15/2023 14:598260Dn-Hexane mg/Kg - dry 0.205
3.38 03/15/2023 14:598260DIsopropylbenzenemg/Kg - dry 0.143
J1.25 03/15/2023 14:598260D4-Isopropyl toluene mg/Kg - dry 0.405
J0.558 03/15/2023 14:598260DMethylene Chloride mg/Kg - dry 0.458
13.0 03/15/2023 14:598260DNaphthalenemg/Kg - dry 0.309
11.9 03/15/2023 14:598260Dn-Propylbenzene mg/Kg - dry 0.168
35.7 03/15/2023 14:598260DToluenemg/Kg - dry 0.205
67.8 03/15/2023 14:598260D1,2,4-Trimethylbenzene mg/Kg - dry 0.153
21.8 03/15/2023 14:598260D1,3,5-Trimethylbenzene mg/Kg - dry 0.168
32.8 03/15/2023 14:598260Do-Xylene mg/Kg - dry 0.155
88.4 03/15/2023 14:598260Dm,p-Xylene mg/Kg - dry 0.392
121 03/15/2023 14:598260DXylene (Total)mg/Kg - dry 0.155
3.88 03/17/2023 19:208270E1-Methylnaphthalene mg/Kg - dry 0.132
7.19 03/17/2023 19:208270E2-Methylnaphthalene mg/Kg - dry 0.124
6.56 03/17/2023 19:208270ENaphthalenemg/Kg - dry 0.179
J411003/15/2023 14:59CALCULATIONAliphatic C5-C8 (Adjusted)mg/Kg - dry 7.58
1060 03/15/2023 14:59CALCULATIONAliphatics C9-C12 (Adjusted)mg/Kg - dry 28.4
1910 03/15/2023 18:25CALCULATIONAromatic C9-C10 (Adjusted)mg/Kg - dry 3.89
J45503/17/2023 19:20CALCULATIONAromatic C11-C22 (Adjusted)mg/Kg - dry 177
1250 03/21/2023 19:33MADEP-EPH Aliphatic C9-C18 mg/Kg - dry 115
J46103/21/2023 19:33MADEP-EPH Aromatic C11-C22 mg/Kg - dry 177
4150 03/15/2023 18:25MADEP-VPH Aliphatic C5-C8 mg/Kg - dry 7.58
3120 03/15/2023 18:25MADEP-VPH Aliphatic C9-C12 mg/Kg - dry 28.4
1910 03/15/2023 18:25MADEP-VPH Aromatic C9-C10 mg/Kg - dry 3.89
19.8 03/20/2023 18:38SW-DRYWT Moisture %
V 91099TW-1
J0.003 03/27/2023 17:296010DLeadmg/L 0.002
J4.84 03/17/2023 19:406200BAcetoneµg/L 1.80
J0.441 03/17/2023 19:406200BTolueneµg/L 0.220
8.56 03/16/2023 22:50625.1 Di-n-butyl phthalate µg/L 2.08
V 91100MW-11
0.009 03/27/2023 17:346010DLeadmg/L 0.002
56.6 03/20/2023 16:006200BBenzeneµg/L 0.180
J0.245 03/20/2023 16:006200Bsec-Butyl benzene µg/L 0.200
Page 6 of 163
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-073-0013
Report Limit
Project:Minute Man #3
V 91100MW-11
45.7 03/20/2023 16:006200BEthylbenzeneµg/L 0.170
1.91 03/20/2023 16:006200BIsopropylbenzeneµg/L 0.180
J0.383 03/20/2023 16:006200B4-Isopropyl toluene µg/L 0.089
J0.241 03/20/2023 16:006200BMethyl tert-butyl ether (MTBE)µg/L 0.140
2.16 03/20/2023 16:006200BNaphthaleneµg/L 0.470
2.86 03/20/2023 16:006200Bn-Propylbenzene µg/L 0.190
J0.237 03/20/2023 16:006200BStyreneµg/L 0.220
J2.50 03/20/2023 16:006200Btert-Butyl Alcohol (TBA)µg/L 1.60
82.7 03/20/2023 16:006200Btert-Amyl Alcohol (TAA)µg/L 1.90
J0.449 03/20/2023 16:006200Btert-Amyl Methyl Ether (TAME)µg/L 0.280
2.75 03/20/2023 16:006200BTolueneµg/L 0.220
2.14 03/20/2023 16:006200B1,2,4-Trimethylbenzene µg/L 0.190
6.71 03/20/2023 16:006200B1,3,5-Trimethylbenzene µg/L 0.180
79.8 03/20/2023 16:006200Bo-Xylene µg/L 0.210
28.4 03/20/2023 16:006200Bm,p-Xylene µg/L 0.420
108 03/20/2023 16:006200BXylene (Total)µg/L 0.210
3.20 03/16/2023 23:13625.1 Naphthalene µg/L 0.735
114 03/15/2023 14:26CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 11.5
J12903/15/2023 14:26CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 25.8
J32.9 03/15/2023 14:26CALCULATIONAromatic C9-C10 (Adjusted)µg/L 4.02
173 03/15/2023 14:26MADEP-VPH Aliphatic C5-C8 µg/L 11.5
316 03/15/2023 14:26MADEP-VPH Aliphatic C9-C12 µg/L 25.8
J32.9 03/15/2023 14:26MADEP-VPH Aromatic C9-C10 µg/L 4.02
V 91101MW-10
J0.002 03/27/2023 18:056010DLeadmg/L 0.002
J0.320 03/17/2023 21:016200BChloroformµg/L 0.220
V 91103MW-9
J0.002 03/27/2023 18:096010DLeadmg/L 0.002
9.26 03/17/2023 22:506200BBenzeneµg/L 1.80
J4.29 03/17/2023 22:506200Bn-Butylbenzene µg/L 1.80
J3.60 03/17/2023 22:506200Bsec-Butyl benzene µg/L 2.00
103 03/17/2023 22:506200BEthylbenzeneµg/L 1.70
16.9 03/17/2023 22:506200BIsopropylbenzeneµg/L 1.80
52.7 03/17/2023 22:506200BNaphthaleneµg/L 4.70
45.5 03/17/2023 22:506200Bn-Propylbenzene µg/L 1.90
124 03/17/2023 22:506200BTolueneµg/L 2.20
Page 7 of 163
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-073-0013
Report Limit
Project:Minute Man #3
V 91103MW-9
91.0 03/17/2023 22:506200B1,2,4-Trimethylbenzene µg/L 1.90
62.2 03/17/2023 22:506200B1,3,5-Trimethylbenzene µg/L 1.80
77.1 03/17/2023 22:506200Bo-Xylene µg/L 2.10
221 03/17/2023 22:506200Bm,p-Xylene µg/L 4.20
298 03/17/2023 22:506200BXylene (Total)µg/L 2.10
28.6 03/16/2023 23:58625.1 Naphthalene µg/L 0.731
J1.30 03/16/2023 23:58625.1 Phenanthrene µg/L 0.430
1040 03/15/2023 13:15CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 11.5
54.9 03/15/2023 13:15CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 25.8
644 03/15/2023 13:15CALCULATIONAromatic C9-C10 (Adjusted)µg/L 4.02
J62.8 03/16/2023 23:58CALCULATIONAromatic C11-C22 (Adjusted)µg/L 61.2
J0.0167 03/20/2023 17:58EPA-504.1 1,2-Dibromoethane µg/L 0.00343
J92.7 03/24/2023 19:27MADEP-EPH Aromatic C11-C22 µg/L 61.2
1170 03/15/2023 13:15MADEP-VPH Aliphatic C5-C8 µg/L 11.5
1100 03/15/2023 13:15MADEP-VPH Aliphatic C9-C12 µg/L 25.8
644 03/15/2023 13:15MADEP-VPH Aromatic C9-C10 µg/L 4.02
V 91104MW-8
0.626 03/17/2023 20:076200BBenzeneµg/L 0.180
J0.242 03/17/2023 20:076200Bn-Butylbenzene µg/L 0.180
J0.345 03/17/2023 20:076200Bsec-Butyl benzene µg/L 0.200
2.51 03/17/2023 20:076200BEthylbenzeneµg/L 0.170
0.752 03/17/2023 20:076200BIsopropylbenzeneµg/L 0.180
J0.618 03/17/2023 20:076200BNaphthaleneµg/L 0.470
1.77 03/17/2023 20:076200Bn-Propylbenzene µg/L 0.190
5.68 03/17/2023 20:076200BTolueneµg/L 0.220
3.67 03/17/2023 20:076200B1,2,4-Trimethylbenzene µg/L 0.190
1.27 03/17/2023 20:076200B1,3,5-Trimethylbenzene µg/L 0.180
2.44 03/17/2023 20:076200Bo-Xylene µg/L 0.210
6.15 03/17/2023 20:076200Bm,p-Xylene µg/L 0.420
8.59 03/17/2023 20:076200BXylene (Total)µg/L 0.210
329 03/15/2023 13:39CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 11.5
J42.2 03/15/2023 13:39CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 25.8
J9.45 03/15/2023 13:39CALCULATIONAromatic C9-C10 (Adjusted)µg/L 4.02
335 03/15/2023 13:39MADEP-VPH Aliphatic C5-C8 µg/L 11.5
62.7 03/15/2023 13:39MADEP-VPH Aliphatic C9-C12 µg/L 25.8
J9.45 03/15/2023 13:39MADEP-VPH Aromatic C9-C10 µg/L 4.02
Page 8 of 163
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-073-0013
Report Limit
Project:Minute Man #3
V 91105MW-7
0.009 03/29/2023 18:006010DLeadmg/L 0.002
0.954 03/17/2023 20:346200BBenzeneµg/L 0.180
0.925 03/17/2023 20:346200BEthylbenzeneµg/L 0.170
4.12 03/17/2023 20:346200BTolueneµg/L 0.220
1.29 03/17/2023 20:346200B1,2,4-Trimethylbenzene µg/L 0.190
J0.385 03/17/2023 20:346200B1,3,5-Trimethylbenzene µg/L 0.180
1.51 03/17/2023 20:346200Bo-Xylene µg/L 0.210
3.66 03/17/2023 20:346200Bm,p-Xylene µg/L 0.420
5.17 03/17/2023 20:346200BXylene (Total)µg/L 0.210
J28.3 03/15/2023 14:02CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 25.8
J34.4 03/15/2023 14:02MADEP-VPH Aliphatic C9-C12 µg/L 25.8
V 91106MW-6
50.8 03/17/2023 18:346200BBenzeneµg/L 1.80
190 03/17/2023 18:346200BEthylbenzeneµg/L 1.70
6.81 03/17/2023 18:346200BIsopropylbenzeneµg/L 1.80
12.1 03/17/2023 18:346200Bn-Propylbenzene µg/L 1.90
8.18 03/17/2023 18:346200BStyreneµg/L 2.20
2030 03/20/2023 19:596200BTolueneµg/L 22.0
126 03/17/2023 18:346200B1,2,4-Trimethylbenzene µg/L 1.90
69.0 03/17/2023 18:346200B1,3,5-Trimethylbenzene µg/L 1.80
418 03/17/2023 18:346200Bo-Xylene µg/L 2.10
897 03/17/2023 18:346200Bm,p-Xylene µg/L 4.20
1320 03/17/2023 18:346200BXylene (Total)µg/L 2.10
V 91107MW-3
1240 03/17/2023 19:216200BBenzeneµg/L 18.0
115 03/17/2023 19:216200BBromodichloromethaneµg/L 16.0
76.6 03/17/2023 19:216200BChlorodibromomethaneµg/L 19.0
284 03/17/2023 19:216200BChloroformµg/L 22.0
1360 03/17/2023 19:216200BEthylbenzeneµg/L 17.0
J34.8 03/17/2023 19:216200BIsopropylbenzeneµg/L 18.0
311 03/17/2023 19:216200BNaphthaleneµg/L 47.0
77.8 03/17/2023 19:216200Bn-Propylbenzene µg/L 19.0
2180 03/17/2023 19:216200Btert-Amyl Alcohol (TAA)µg/L 190
10400 03/21/2023 23:386200BTolueneµg/L 220
822 03/17/2023 19:216200B1,2,4-Trimethylbenzene µg/L 19.0
314 03/17/2023 19:216200B1,3,5-Trimethylbenzene µg/L 18.0
Page 9 of 163
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-073-0013
Report Limit
Project:Minute Man #3
V 91107MW-3
2280 03/17/2023 19:216200Bo-Xylene µg/L 21.0
4660 03/17/2023 19:216200Bm,p-Xylene µg/L 42.0
6940 03/17/2023 19:216200BXylene (Total)µg/L 21.0
Page 10 of 163

Client:GeologicalResources,Inc. CASENARRATIVE
Project:MinuteMan#3
LabReportNumber:23-073-0013
Date:3/30/2023

625.1-Base/NeutralsandAcidsbyGC/MSMethod625.1
Sample91100(MW-11)
Analyte:2,4,6-Tribromophenol
QCBatchNo:V30970/V30880
Surrogatewasdoubledduringsampleprep.Therecoveryis73.5%

Sample91101(MW-10)
Analyte:2,4,6-Tribromophenol
QCBatchNo:V30970/V30880
Surrogatewasdoubledduringsampleprep.Therecoveryis65%

Sample91100(MW-11)
Analyte:2-Fluorobiphenyl
QCBatchNo:V30970/V30880
Surrogatewasdoubledduringsampleprep.Therecoveryis126%.

Sample91101(MW-10)
Analyte:2-Fluorobiphenyl
QCBatchNo:V30970/V30880
Surrogatewasdoubledduringsampleprep.Therecoveryis61%

Sample91100(MW-11)
Analyte:2-Fluorophenol
QCBatchNo:V30970/V30880
Surrogatewasdoubledduringsampleprep.Therecoveryis32%

Sample91101(MW-10)
Analyte:2-Fluorophenol
QCBatchNo:V30970/V30880
Surrogatewasdoubledduringsampleprep.Therecoveryis31%

Sample91100(MW-11)
Analyte:4-Terphenyl-d14
QCBatchNo:V30970/V30880
Surrogatewasdoubledduringsampleprep.Therecoveryis83%

Sample91101(MW-10)
Analyte:4-Terphenyl-d14
QCBatchNo:V30970/V30880
Surrogatewasdoubledduringsampleprep.Therecoveryis74%

Analyte:Benzidine
QCBatchNo:V30970/V30880
RelativePercentDifference(RPD)fortheduplicateanalysiswasoutsideoftheallowableQClimits.

Page 11 of 163

Sample91100(MW-11)
Analyte:Nitrobenzene-d5
QCBatchNo:V30970/V30880
Surrogatewasdoubledduringsampleprep.Therecoveryis57%

Sample91101(MW-10)
Analyte:Nitrobenzene-d5
QCBatchNo:V30970/V30880
Surrogatewasdoubledduringsampleprep.Therecoveryis54.5%

Sample91100(MW-11)
Analyte:Phenol-d5
QCBatchNo:V30970/V30880
Surrogatewasdoubledduringsampleprep.Therecoveryis22%

Sample91101(MW-10)
Analyte:Phenol-d5
QCBatchNo:V30970/V30880
Surrogatewasdoubledduringsampleprep.Therecoveryis21%

MassachusettsEPHMethodMADEP-EPH
Sample91097(SB-1(18'))
QCBatchNo:V31003
Samplerequiresdilutionduetohighlevelsoftargetand/ornon-targetanalytes.

Sample91098(SB-2(20'))
QCBatchNo:V31003
Samplerequiresdilutionduetohighlevelsoftargetand/ornon-targetanalytes.

Sample91098(SB-2(20'))
Analyte:2-Bromonaphthalene
QCBatchNo:V31003/V30933
Surrogatehighduetomatrixinterference.

Analyte:2-Bromonaphthalene
QCBatchNo:V31230/V30933
Fractionationsurrogate2-Bromonaphthalenerunninghighforentirebatch.Theotherfractionationsurrogate,2-
fluorobiphenyl,passesfortheenitrebatch.

Analyte:AromaticC11-C22
QCBatchNo:V30950/V30933
AromaticrangeishighinLCSD.LCSpassesandRPDiswithinacceptedrange.Allassociatedsamplesarenon-
detect.

Analyte:AromaticC11-C22
QCBatchNo:V31003/V30933
AromaticrangeinLCSDishigh.LCSpassesandRPDiswithinacceptablerange.

Analyte:Chlorooctadecane
QCBatchNo:V30950/V30933
Chlorooctadecane(surrogate)failedlowinLRB,LCS,andLCSD,passesinallassociatedsamples.

Page 12 of 163

VolatileOrganicCompounds-GC/MSMethod6200B
Analyte:3,3-Dimethyl-1-butanol
QCBatchNo:V31039/V30983
RecoveryfortheLCSexceededtheupperacceptancelimit.However,allsampleresultsassociatedwiththe
batcharebelowtheMQL,sothishighbiashadnoimpactupontheclientdata.Theresultsareconsideredtobe
acceptable.

Analyte:Ethanol
QCBatchNo:V31039/V30983
RecoveryfortheLCSexceededtheupperacceptancelimit.However,allsampleresultsassociatedwiththe
batcharebelowtheMQL,sothishighbiashadnoimpactupontheclientdata.Theresultsareconsideredtobe
acceptable.

Analyte:tert-Amylalcohol
QCBatchNo:V30982/V30983
RecoveryfortheLCSexceededtheupperacceptancelimit.However,allsampleresultsassociatedwiththe
batcharebelowtheMQL,sothishighbiashadnoimpactupontheclientdata.Theresultsareconsideredtobe
acceptable.

Analyte:tert-Amylalcohol
QCBatchNo:V31039/V30983
RecoveryfortheLCSexceededtheupperacceptancelimit.However,allsampleresultsassociatedwiththe
batcharebelowtheMQL,sothishighbiashadnoimpactupontheclientdata.Theresultsareconsideredtobe
acceptable.

Analyte:tert-Amylalcohol
QCBatchNo:V31068/V30983
RelativePercentDifference(RPD)fortheduplicateanalysiswasoutsideoftheallowableQClimits.

Analyte:tert-Butylformate
QCBatchNo:V30982/V30983
RecoveryfortheLCSexceededtheupperacceptancelimit.However,allsampleresultsassociatedwiththe
batcharebelowtheMQL,sothishighbiashadnoimpactupontheclientdata.Theresultsareconsideredtobe
acceptable.

Analyte:tert-Butylformate
QCBatchNo:V31039/V30983
RecoveryfortheLCSexceededtheupperacceptancelimit.However,allsampleresultsassociatedwiththe
batcharebelowtheMQL,sothishighbiashadnoimpactupontheclientdata.Theresultsareconsideredtobe
acceptable.

Analyte:Vinylacetate
QCBatchNo:V30982/V30983
RecoveryfortheLCSexceededtheupperacceptancelimit.However,allsampleresultsassociatedwiththe
batcharebelowtheMQL,sothishighbiashadnoimpactupontheclientdata.Theresultsareconsideredtobe
acceptable.

Analyte:Vinylacetate
QCBatchNo:V31039/V30983
RecoveryfortheLCSexceededtheupperacceptancelimit.However,allsampleresultsassociatedwiththe
batcharebelowtheMQL,sothishighbiashadnoimpactupontheclientdata.Theresultsareconsideredtobe
acceptable.

Page 13 of 163

SemivolatileOrganicCompounds-GC/MSMethod8270E
Analyte:4-Nitrophenol
QCBatchNo:V30974/V30932
RecoveryfortheLCSexceededtheupperacceptancelimit.However,allsampleresultsassociatedwiththe
batcharebelowtheMQL,sothishighbiashadnoimpactupontheclientdata.Theresultsareconsideredtobe
acceptable.

Analyte:Aniline
QCBatchNo:V30974/V30932
RecoveryfortheLCSexceededtheupperacceptancelimit.However,allsampleresultsassociatedwiththe
batcharebelowtheMQL,sothishighbiashadnoimpactupontheclientdata.Theresultsareconsideredtobe
acceptable.

Analyte:BenzoicAcid
QCBatchNo:V30974/V30932
ThistargetanalytewasflaggedforrecoveriesoutsideQClimitsintheassociatedLCS/LCSD.Dataforthis
analyteisflagged"M"toindicatethatresultsshouldbeconsideredminimumconcentrationduetothepotentialfor
alowbias.

Analyte:Bis(2-chloroethyl)ether
QCBatchNo:V30974/V30932
RelativePercentDifference(RPD)fortheduplicateanalysiswasoutsideoftheallowableQClimits.

Page 14 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-8 (16')
91094 Matrix:
3/8/2023 14:24
Solids
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
9.0 %0.1%Clay 1 03/20/23 08:12 TextureEB
90.0 %0.1%Sand 1 03/20/23 08:12 TextureEB
1.0 %0.1%Silt 1 03/20/23 08:12 TextureEB
SandSoil Classification 1 03/20/23 08:12 TextureEB
0.11 %0.05Total Organic Carbon 1 03/22/23 10:25 WALK-BLACKAAB
100.0 %0.1% Passing 4 Mesh 1 03/23/23 11:00 SIEVE TESTVVP
99.9 %0.1% Passing 10 Mesh 1 03/23/23 11:00 SIEVEVVP
99.4 %0.1% Passing 20 Mesh 1 03/23/23 11:00 SIEVE TESTVVP
95.9 %0.1% Passing 40 Mesh 1 03/23/23 11:00 SIEVEVVP
56.0 %0.1% Passing 60 Mesh 1 03/23/23 11:00 SIEVEVVP
21.3 %0.1% Passing 100 Mesh 1 03/23/23 11:00 SIEVE TESTVVP
17.3 %0.1% Passing 200 Mesh 1 03/23/23 11:00 SIEVE TESTVVP
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 15 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-7 (16')
91095 Matrix:
3/8/2023 15:09
Solids
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
9.0 %0.1%Clay 1 03/20/23 08:12 TextureEB
90.0 %0.1%Sand 1 03/20/23 08:12 TextureEB
1.0 %0.1%Silt 1 03/20/23 08:12 TextureEB
SandSoil Classification 1 03/20/23 08:12 TextureEB
0.11 %0.05Total Organic Carbon 1 03/22/23 10:25 WALK-BLACKAAB
100.0 %0.1% Passing 4 Mesh 1 03/23/23 11:00 SIEVE TESTVVP
100.0 %0.1% Passing 10 Mesh 1 03/23/23 11:00 SIEVEVVP
100.0 %0.1% Passing 20 Mesh 1 03/23/23 11:00 SIEVE TESTVVP
98.5 %0.1% Passing 40 Mesh 1 03/23/23 11:00 SIEVEVVP
64.0 %0.1% Passing 60 Mesh 1 03/23/23 11:00 SIEVEVVP
26.3 %0.1% Passing 100 Mesh 1 03/23/23 11:00 SIEVE TESTVVP
22.5 %0.1% Passing 200 Mesh 1 03/23/23 11:00 SIEVE TESTVVP
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 16 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:TW-1 (42')
91096 Matrix:
3/9/2023 12:17
Solids
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
19.0 %0.1%Clay 1 03/20/23 08:12 TextureEB
70.0 %0.1%Sand 1 03/20/23 08:12 TextureEB
11.0 %0.1%Silt 1 03/20/23 08:12 TextureEB
Sandy LoamSoil Classification 1 03/20/23 08:12 TextureEB
3.01 %0.05Total Organic Carbon 1 03/22/23 10:25 WALK-BLACKAAB
99.4 %0.1% Passing 4 Mesh 1 03/23/23 11:00 SIEVE TESTVVP
91.7 %0.1% Passing 10 Mesh 1 03/23/23 11:00 SIEVEVVP
68.9 %0.1% Passing 20 Mesh 1 03/23/23 11:00 SIEVE TESTVVP
49.3 %0.1% Passing 40 Mesh 1 03/23/23 11:00 SIEVEVVP
36.3 %0.1% Passing 60 Mesh 1 03/23/23 11:00 SIEVEVVP
30.1 %0.1% Passing 100 Mesh 1 03/23/23 11:00 SIEVE TESTVVP
26.6 %0.1% Passing 200 Mesh 1 03/23/23 11:00 SIEVE TESTVVP
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 17 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:SB-1 (18')
91097 Matrix:
3/8/2023 9:47
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
20.1 %Moisture 1 03/20/23 18:38 SW-DRYWTAMB
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 18 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:SB-1 (18')
91097 Matrix:
3/8/2023 9:47
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V30878 03/15/23 08:00
<0.750 mg/Kg - dry 0.750 6.26Acetone 500 03/15/23 15:53 V30879TBL
<0.379 mg/Kg - dry 0.379 6.26Acrolein 500 03/15/23 15:53 V30879TBL
<0.235 mg/Kg - dry 0.235 6.26Acrylonitrile 500 03/15/23 15:53 V30879TBL
5.48 mg/Kg - dry 0.181 1.56Benzene 500 03/15/23 15:53 V30879TBL
<0.156 mg/Kg - dry 0.156 1.56Bromobenzene 500 03/15/23 15:53 V30879TBL
<0.250 mg/Kg - dry 0.250 1.56Bromochloromethane 500 03/15/23 15:53 V30879TBL
<0.372 mg/Kg - dry 0.372 1.56Bromodichloromethane 500 03/15/23 15:53 V30879TBL
<0.316 mg/Kg - dry 0.316 1.56Bromoform 500 03/15/23 15:53 V30879TBL
<0.569 mg/Kg - dry 0.569 3.13Bromomethane 500 03/15/23 15:53 V30879TBL
10.4 mg/Kg - dry 0.153 1.56n-Butylbenzene 500 03/15/23 15:53 V30879TBL
4.44 mg/Kg - dry 0.175 1.56sec-Butyl benzene 500 03/15/23 15:53 V30879TBL
<0.156 mg/Kg - dry 0.156 1.56tert-Butyl benzene 500 03/15/23 15:53 V30879TBL
<0.200 mg/Kg - dry 0.200 1.56Carbon Disulfide 500 03/15/23 15:53 V30879TBL
<0.494 mg/Kg - dry 0.494 1.56Carbon Tetrachloride 500 03/15/23 15:53 V30879TBL
<0.210 mg/Kg - dry 0.210 1.56Chlorobenzene 500 03/15/23 15:53 V30879TBL
<0.279 mg/Kg - dry 0.279 1.56Chlorodibromomethane 500 03/15/23 15:53 V30879TBL
<0.279 mg/Kg - dry 0.279 3.13Chloroethane 500 03/15/23 15:53 V30879TBL
<0.329 mg/Kg - dry 0.329 1.56Chloroform 500 03/15/23 15:53 V30879TBL
<0.197 mg/Kg - dry 0.197 3.13Chloromethane 500 03/15/23 15:53 V30879TBL
<0.160 mg/Kg - dry 0.160 1.562-Chlorotoluene 500 03/15/23 15:53 V30879TBL
<0.122 mg/Kg - dry 0.122 1.564-Chlorotoluene 500 03/15/23 15:53 V30879TBL
<0.229 mg/Kg - dry 0.229 1.56Di-Isopropyl Ether (DIPE)500 03/15/23 15:53 V30879TBL
<0.137 mg/Kg - dry 0.137 3.131,2-Dibromo-3-Chloropropane 500 03/15/23 15:53 V30879TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 19 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:SB-1 (18')
91097 Matrix:
3/8/2023 9:47
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V30878 03/15/23 08:00
<0.185 mg/Kg - dry 0.185 1.561,2-Dibromoethane 500 03/15/23 15:53 V30879TBL
<0.310 mg/Kg - dry 0.310 1.56Dibromomethane 500 03/15/23 15:53 V30879TBL
<0.096 mg/Kg - dry 0.096 1.561,2-Dichlorobenzene 500 03/15/23 15:53 V30879TBL
<0.118 mg/Kg - dry 0.118 1.561,3-Dichlorobenzene 500 03/15/23 15:53 V30879TBL
<0.187 mg/Kg - dry 0.187 1.561,4-Dichlorobenzene 500 03/15/23 15:53 V30879TBL
<0.413 mg/Kg - dry 0.413 3.13Dichlorodifluoromethane 500 03/15/23 15:53 V30879TBL
<0.256 mg/Kg - dry 0.256 1.561,1-Dichloroethane 500 03/15/23 15:53 V30879TBL
<0.431 mg/Kg - dry 0.431 1.561,2-Dichloroethane 500 03/15/23 15:53 V30879TBL
<0.229 mg/Kg - dry 0.229 1.561,1-Dichloroethene 500 03/15/23 15:53 V30879TBL
<0.247 mg/Kg - dry 0.247 1.56cis-1,2-Dichloroethene 500 03/15/23 15:53 V30879TBL
<0.329 mg/Kg - dry 0.329 1.56trans-1,2-Dichloroethene 500 03/15/23 15:53 V30879TBL
<0.137 mg/Kg - dry 0.137 1.561,2-Dichloropropane 500 03/15/23 15:53 V30879TBL
<0.172 mg/Kg - dry 0.172 1.561,3-Dichloropropane 500 03/15/23 15:53 V30879TBL
<0.397 mg/Kg - dry 0.397 1.562,2-Dichloropropane 500 03/15/23 15:53 V30879TBL
<0.237 mg/Kg - dry 0.237 1.561,1-Dichloropropene 500 03/15/23 15:53 V30879TBL
<0.168 mg/Kg - dry 0.168 1.56cis-1,3-Dichloropropene 500 03/15/23 15:53 V30879TBL
<0.250 mg/Kg - dry 0.250 1.56trans-1,3-Dichloropropene 500 03/15/23 15:53 V30879TBL
87.1 mg/Kg - dry 0.181 1.56Ethylbenzene 500 03/15/23 15:53 V30879TBL
<0.260 mg/Kg - dry 0.260 31.3Ethyl Tertiary Butyl Ether (ETBE)500 03/15/23 15:53 V30879TBL
<0.247 mg/Kg - dry 0.247 3.13Hexachlorobutadiene 500 03/15/23 15:53 V30879TBL
32.7 mg/Kg - dry 0.206 3.13n-Hexane 500 03/15/23 15:53 V30879TBL
<0.193 mg/Kg - dry 0.193 6.262-Hexanone 500 03/15/23 15:53 V30879TBL
8.95 mg/Kg - dry 0.143 1.56Isopropylbenzene 500 03/15/23 15:53 V30879TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 20 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:SB-1 (18')
91097 Matrix:
3/8/2023 9:47
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V30878 03/15/23 08:00
2.57 mg/Kg - dry 0.406 1.564-Isopropyl toluene 500 03/15/23 15:53 V30879TBL
<0.204 mg/Kg - dry 0.204 6.26Methyl Ethyl Ketone (MEK)500 03/15/23 15:53 V30879TBL
<0.193 mg/Kg - dry 0.193 1.56Methyl tert-butyl ether (MTBE)500 03/15/23 15:53 V30879TBL
<4.69 mg/Kg - dry 4.69 6.264-Methyl-2-Pentanone 500 03/15/23 15:53 V30879TBL
0.461 J mg/Kg - dry 0.460 1.56Methylene Chloride 500 03/15/23 15:53 V30879TBL
33.9 mg/Kg - dry 0.310 3.13Naphthalene 500 03/15/23 15:53 V30879TBL
31.5 mg/Kg - dry 0.168 1.56n-Propylbenzene 500 03/15/23 15:53 V30879TBL
1.17 J mg/Kg - dry 0.444 1.56Styrene 500 03/15/23 15:53 V30879TBL
<0.329 mg/Kg - dry 0.329 1.561,1,1,2-Tetrachloroethane 500 03/15/23 15:53 V30879TBL
<0.100 mg/Kg - dry 0.100 1.561,1,2,2-Tetrachloroethane 500 03/15/23 15:53 V30879TBL
<0.281 mg/Kg - dry 0.281 1.56Tetrachloroethene 500 03/15/23 15:53 V30879TBL
230 mg/Kg - dry 2.07 15.6Toluene 5000 03/15/23 16:20 V30879TBL
<0.168 mg/Kg - dry 0.168 3.131,2,3-Trichlorobenzene 500 03/15/23 15:53 V30879TBL
<0.200 mg/Kg - dry 0.200 3.131,2,4-Trichlorobenzene 500 03/15/23 15:53 V30879TBL
<0.450 mg/Kg - dry 0.450 1.561,1,1-Trichloroethane 500 03/15/23 15:53 V30879TBL
<0.147 mg/Kg - dry 0.147 1.561,1,2-Trichloroethane 500 03/15/23 15:53 V30879TBL
<0.287 mg/Kg - dry 0.287 1.56Trichloroethene 500 03/15/23 15:53 V30879TBL
<0.654 mg/Kg - dry 0.654 3.13Trichlorofluoromethane 500 03/15/23 15:53 V30879TBL
<0.225 mg/Kg - dry 0.225 1.561,2,3-Trichloropropane 500 03/15/23 15:53 V30879TBL
214 mg/Kg - dry 1.54 15.61,2,4-Trimethylbenzene 5000 03/15/23 16:20 V30879TBL
56.4 mg/Kg - dry 0.168 1.561,3,5-Trimethylbenzene 500 03/15/23 15:53 V30879TBL
<0.143 mg/Kg - dry 0.143 3.13Vinyl Acetate 500 03/15/23 15:53 V30879TBL
<0.150 mg/Kg - dry 0.150 3.13Vinyl Chloride 500 03/15/23 15:53 V30879TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 21 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:SB-1 (18')
91097 Matrix:
3/8/2023 9:47
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V30878 03/15/23 08:00
110 mg/Kg - dry 0.156 1.56o-Xylene 500 03/15/23 15:53 V30879TBL
338 mg/Kg - dry 3.94 31.3m,p-Xylene 5000 03/15/23 16:20 V30879TBL
448 mg/Kg - dry 0.156 1.56Xylene (Total)500 03/15/23 15:53 V30879
Surrogate: 4-Bromofluorobenzene 96.2 Limits: 70-130%03/15/23 15:53500 TBL V30879
Surrogate: Dibromofluoromethane 96.7 Limits: 70-130%03/15/23 15:53500 TBL V30879
Surrogate: Toluene-d8 95.1 Limits: 76-129%03/15/23 15:53500 TBL V30879
Surrogate: 4-Bromofluorobenzene 98.2 Limits: 70-130%03/15/23 16:205000 TBL V30879
Surrogate: Dibromofluoromethane 101 Limits: 70-130%03/15/23 16:205000 TBL V30879
Surrogate: Toluene-d8 96.2 Limits: 76-129%03/15/23 16:205000 TBL V30879
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V30932 03/17/23 09:00
<0.145 mg/Kg - dry 0.145 0.827Acenaphthene 1 03/17/23 18:58 V30974JMV
<0.131 mg/Kg - dry 0.131 0.827Acenaphthylene 1 03/17/23 18:58 V30974JMV
<0.190 mg/Kg - dry 0.190 0.827Aniline 1 03/17/23 18:58 V30974JMV
<0.178 mg/Kg - dry 0.178 0.827Anthracene 1 03/17/23 18:58 V30974JMV
<0.173 mg/Kg - dry 0.173 0.827Benzo(a)anthracene 1 03/17/23 18:58 V30974JMV
<0.183 mg/Kg - dry 0.183 0.827Benzo(a)pyrene 1 03/17/23 18:58 V30974JMV
<0.182 mg/Kg - dry 0.182 0.827Benzo(b)fluoranthene 1 03/17/23 18:58 V30974JMV
<0.170 mg/Kg - dry 0.170 0.827Benzo(g,h,i)perylene 1 03/17/23 18:58 V30974JMV
<0.171 mg/Kg - dry 0.171 0.827Benzo(k)fluoranthene 1 03/17/23 18:58 V30974JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 22 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:SB-1 (18')
91097 Matrix:
3/8/2023 9:47
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V30932 03/17/23 09:00
<0.725 M mg/Kg - dry 0.725 2.50Benzoic Acid 1 03/17/23 18:58 V30974JMV
<0.131 mg/Kg - dry 0.131 0.827Benzyl alcohol 1 03/17/23 18:58 V30974JMV
<0.147 mg/Kg - dry 0.147 0.827Bis(2-Chloroethoxy)methane 1 03/17/23 18:58 V30974JMV
<0.133 mg/Kg - dry 0.133 0.827Bis(2-Chloroethyl)ether 1 03/17/23 18:58 V30974JMV
<0.170 mg/Kg - dry 0.170 0.413Bis(2-Chloroisopropyl)ether 1 03/17/23 18:58 V30974JMV
<0.150 mg/Kg - dry 0.150 0.827Bis(2-ethylhexyl)phthalate 1 03/17/23 18:58 V30974JMV
<0.136 mg/Kg - dry 0.136 0.8274-Bromophenyl phenyl ether 1 03/17/23 18:58 V30974JMV
<0.141 mg/Kg - dry 0.141 0.413Butyl benzyl phthalate 1 03/17/23 18:58 V30974JMV
<0.115 mg/Kg - dry 0.115 0.8274-Chloro-3-methylphenol 1 03/17/23 18:58 V30974JMV
<0.140 mg/Kg - dry 0.140 0.4134-Chloroaniline 1 03/17/23 18:58 V30974JMV
<0.145 mg/Kg - dry 0.145 0.8272-Chloronaphthalene 1 03/17/23 18:58 V30974JMV
<0.123 mg/Kg - dry 0.123 0.8272-Chlorophenol 1 03/17/23 18:58 V30974JMV
<0.157 mg/Kg - dry 0.157 1.254-Chlorophenyl phenyl ether 1 03/17/23 18:58 V30974JMV
<0.177 mg/Kg - dry 0.177 0.827Chrysene 1 03/17/23 18:58 V30974JMV
<0.287 mg/Kg - dry 0.287 0.827Dibenz(a,h)anthracene 1 03/17/23 18:58 V30974JMV
<0.148 mg/Kg - dry 0.148 0.827Dibenzofuran 1 03/17/23 18:58 V30974JMV
<0.118 mg/Kg - dry 0.118 0.8271,2-Dichlorobenzene 1 03/17/23 18:58 V30974JMV
<0.121 mg/Kg - dry 0.121 0.8271,3-Dichlorobenzene 1 03/17/23 18:58 V30974JMV
<0.122 mg/Kg - dry 0.122 0.4131,4-Dichlorobenzene 1 03/17/23 18:58 V30974JMV
<0.183 mg/Kg - dry 0.183 0.8273,3'-Dichlorobenzidine 1 03/17/23 18:58 V30974JMV
<0.120 mg/Kg - dry 0.120 0.8272,4-Dichlorophenol 1 03/17/23 18:58 V30974JMV
<0.225 mg/Kg - dry 0.225 0.827Diethyl phthalate 1 03/17/23 18:58 V30974JMV
<0.217 mg/Kg - dry 0.217 0.827Dimethyl phthalate 1 03/17/23 18:58 V30974JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 23 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:SB-1 (18')
91097 Matrix:
3/8/2023 9:47
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V30932 03/17/23 09:00
<0.135 mg/Kg - dry 0.135 0.4132,4-Dimethylphenol 1 03/17/23 18:58 V30974JMV
<0.133 mg/Kg - dry 0.133 0.827Di-n-butyl phthalate 1 03/17/23 18:58 V30974JMV
<0.300 mg/Kg - dry 0.300 1.884,6-Dinitro-2-methylphenol 1 03/17/23 18:58 V30974JMV
<0.650 mg/Kg - dry 0.650 1.882,4-Dinitrophenol 1 03/17/23 18:58 V30974JMV
<0.121 mg/Kg - dry 0.121 0.8272,4-Dinitrotoluene 1 03/17/23 18:58 V30974JMV
<0.135 mg/Kg - dry 0.135 0.8272,6-Dinitrotoluene 1 03/17/23 18:58 V30974JMV
<0.178 mg/Kg - dry 0.178 0.413Di-n-Octyl Phthalate 1 03/17/23 18:58 V30974JMV
<0.153 mg/Kg - dry 0.153 0.827Fluoranthene 1 03/17/23 18:58 V30974JMV
<0.160 mg/Kg - dry 0.160 0.827Fluorene 1 03/17/23 18:58 V30974JMV
<0.132 mg/Kg - dry 0.132 0.827Hexachlorobenzene 1 03/17/23 18:58 V30974JMV
<0.122 mg/Kg - dry 0.122 0.827Hexachlorobutadiene 1 03/17/23 18:58 V30974JMV
<0.196 mg/Kg - dry 0.196 0.827Hexachlorocyclopentadiene 1 03/17/23 18:58 V30974JMV
<0.099 mg/Kg - dry 0.099 0.827Hexachloroethane 1 03/17/23 18:58 V30974JMV
<0.224 mg/Kg - dry 0.224 0.827Indeno(1,2,3-cd)pyrene 1 03/17/23 18:58 V30974JMV
<0.239 mg/Kg - dry 0.239 0.827Isophorone 1 03/17/23 18:58 V30974JMV
6.12 mg/Kg - dry 0.132 0.8271-Methylnaphthalene 1 03/17/23 18:58 V30974JMV
13.4 mg/Kg - dry 0.500 3.302-Methylnaphthalene 4 03/21/23 20:13 V30974JMV
<0.121 mg/Kg - dry 0.121 0.8272-Methylphenol 1 03/17/23 18:58 V30974JMV
<0.106 mg/Kg - dry 0.106 0.8273&4 Methylphenol 1 03/17/23 18:58 V30974JMV
13.1 mg/Kg - dry 0.720 3.30Naphthalene 4 03/21/23 20:13 V30974JMV
<0.121 mg/Kg - dry 0.121 0.8272-Nitroaniline 1 03/17/23 18:58 V30974JMV
<0.150 mg/Kg - dry 0.150 0.8273-Nitroaniline 1 03/17/23 18:58 V30974JMV
<0.116 mg/Kg - dry 0.116 0.4134-Nitroaniline 1 03/17/23 18:58 V30974JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 24 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:SB-1 (18')
91097 Matrix:
3/8/2023 9:47
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V30932 03/17/23 09:00
<0.145 mg/Kg - dry 0.145 0.413Nitrobenzene 1 03/17/23 18:58 V30974JMV
<0.111 mg/Kg - dry 0.111 0.8272-Nitrophenol 1 03/17/23 18:58 V30974JMV
<0.146 mg/Kg - dry 0.146 0.8274-Nitrophenol 1 03/17/23 18:58 V30974JMV
<0.329 mg/Kg - dry 0.329 0.827N-Nitrosodimethylamine 1 03/17/23 18:58 V30974JMV
<0.226 mg/Kg - dry 0.226 0.827N-Nitrosodiphenylamine 1 03/17/23 18:58 V30974JMV
<0.147 mg/Kg - dry 0.147 0.827N-Nitroso-di-n-propylamine 1 03/17/23 18:58 V30974JMV
<0.434 mg/Kg - dry 0.434 1.25Pentachlorophenol 1 03/17/23 18:58 V30974JMV
<0.260 mg/Kg - dry 0.260 0.827Phenanthrene 1 03/17/23 18:58 V30974JMV
<0.140 mg/Kg - dry 0.140 0.827Phenol 1 03/17/23 18:58 V30974JMV
<0.167 mg/Kg - dry 0.167 0.827Pyrene 1 03/17/23 18:58 V30974JMV
<0.099 mg/Kg - dry 0.099 0.413Pyridine 1 03/17/23 18:58 V30974JMV
<0.133 mg/Kg - dry 0.133 0.8271,2,4-Trichlorobenzene 1 03/17/23 18:58 V30974JMV
<0.120 mg/Kg - dry 0.120 0.8272,4,5-Trichlorophenol 1 03/17/23 18:58 V30974JMV
<0.121 mg/Kg - dry 0.121 0.8272,4,6-Trichlorophenol 1 03/17/23 18:58 V30974JMV
8270ESurrogate: Phenol-d5 82.6 Limits: 34-121%03/17/23 18:581 JMV
Surrogate: 2-Fluorobiphenyl 102 Limits: 44-115%03/17/23 18:581 JMV V30974
Surrogate: 2-Fluorophenol 84.7 Limits: 35-115%03/17/23 18:581 JMV V30974
Surrogate: Nitrobenzene-d5 92.8 Limits: 37-122%03/17/23 18:581 JMV V30974
Surrogate: 4-Terphenyl-d14 108 Limits: 54-127%03/17/23 18:581 JMV V30974
Surrogate: 2,4,6-Tribromophenol 98.8 Limits: 39-132%03/17/23 18:581 JMV V30974
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 25 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:SB-1 (18')
91097 Matrix:
3/8/2023 9:47
Solids
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
2670 mg/Kg - dry 7.61 50.1Aliphatic C5-C8 (Adjusted)500 03/15/23 15:53
554 mg/Kg - dry 28.5 50.1Aliphatics C9-C12 (Adjusted)500 03/15/23 15:53
1910 mg/Kg - dry 3.90 50.1Aromatic C9-C10 (Adjusted)500 03/15/23 18:48
347 mg/Kg - dry 89.2 314Aromatic C11-C22 (Adjusted)1 03/17/23 18:58
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V30933 03/17/23 16:00
894 mg/Kg - dry 57.8 314Aliphatic C9-C18 5 03/21/23 18:57 V31003AMP
<76.6 mg/Kg - dry 76.6 314Aliphatic C19-C36 5 03/21/23 18:57 V31003AMP
359 mg/Kg - dry 89.2 314
Aromatic C11-C22 5 03/21/23 18:57 V31003AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene 137 Limits: 40-140%03/21/23 18:575 AMP
MADEP-EPHSurrogate: Chlorooctadecane 87.5 Limits: 40-140%03/21/23 18:575 AMP
MADEP-EPHSurrogate: OTP Surrogate 107 Limits: 40-140%03/21/23 18:575 AMP
Surrogate: 2-Fluorobiphenyl 126 Limits: 40-140%03/21/23 18:575 AMP V31003
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V30855 03/15/23 08:00
2900 mg/Kg - dry 7.61 50.1Aliphatic C5-C8 500 03/15/23 18:48 V30856TBL
3000 mg/Kg - dry 28.5 50.1Aliphatic C9-C12 500 03/15/23 18:48 V30856TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 26 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:SB-1 (18')
91097 Matrix:
3/8/2023 9:47
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V30855 03/15/23 08:00
1910 mg/Kg - dry 3.90 50.1Aromatic C9-C10 500 03/15/23 18:48 V30856TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)96.2 Limits: 70-130%03/15/23 18:48500 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)98.1 Limits: 70-130%03/15/23 18:48500 TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 27 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:SB-2 (20')
91098 Matrix:
3/8/2023 13:31
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
19.8 %Moisture 1 03/20/23 18:38 SW-DRYWTAMB
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 28 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:SB-2 (20')
91098 Matrix:
3/8/2023 13:31
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V30878 03/15/23 08:00
<0.748 mg/Kg - dry 0.748 6.23Acetone 500 03/15/23 14:59 V30879TBL
<0.377 mg/Kg - dry 0.377 6.23Acrolein 500 03/15/23 14:59 V30879TBL
<0.234 mg/Kg - dry 0.234 6.23Acrylonitrile 500 03/15/23 14:59 V30879TBL
0.576 J mg/Kg - dry 0.180 1.56Benzene 500 03/15/23 14:59 V30879TBL
<0.155 mg/Kg - dry 0.155 1.56Bromobenzene 500 03/15/23 14:59 V30879TBL
<0.249 mg/Kg - dry 0.249 1.56Bromochloromethane 500 03/15/23 14:59 V30879TBL
<0.371 mg/Kg - dry 0.371 1.56Bromodichloromethane 500 03/15/23 14:59 V30879TBL
<0.315 mg/Kg - dry 0.315 1.56Bromoform 500 03/15/23 14:59 V30879TBL
<0.567 mg/Kg - dry 0.567 3.12Bromomethane 500 03/15/23 14:59 V30879TBL
4.35 mg/Kg - dry 0.153 1.56n-Butylbenzene 500 03/15/23 14:59 V30879TBL
2.03 mg/Kg - dry 0.174 1.56sec-Butyl benzene 500 03/15/23 14:59 V30879TBL
<0.155 mg/Kg - dry 0.155 1.56tert-Butyl benzene 500 03/15/23 14:59 V30879TBL
<0.199 mg/Kg - dry 0.199 1.56Carbon Disulfide 500 03/15/23 14:59 V30879TBL
<0.492 mg/Kg - dry 0.492 1.56Carbon Tetrachloride 500 03/15/23 14:59 V30879TBL
<0.209 mg/Kg - dry 0.209 1.56Chlorobenzene 500 03/15/23 14:59 V30879TBL
<0.278 mg/Kg - dry 0.278 1.56Chlorodibromomethane 500 03/15/23 14:59 V30879TBL
<0.278 mg/Kg - dry 0.278 3.12Chloroethane 500 03/15/23 14:59 V30879TBL
<0.327 mg/Kg - dry 0.327 1.56Chloroform 500 03/15/23 14:59 V30879TBL
<0.197 mg/Kg - dry 0.197 3.12Chloromethane 500 03/15/23 14:59 V30879TBL
<0.159 mg/Kg - dry 0.159 1.562-Chlorotoluene 500 03/15/23 14:59 V30879TBL
<0.121 mg/Kg - dry 0.121 1.564-Chlorotoluene 500 03/15/23 14:59 V30879TBL
<0.228 mg/Kg - dry 0.228 1.56Di-Isopropyl Ether (DIPE)500 03/15/23 14:59 V30879TBL
<0.137 mg/Kg - dry 0.137 3.121,2-Dibromo-3-Chloropropane 500 03/15/23 14:59 V30879TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 29 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:SB-2 (20')
91098 Matrix:
3/8/2023 13:31
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V30878 03/15/23 08:00
<0.184 mg/Kg - dry 0.184 1.561,2-Dibromoethane 500 03/15/23 14:59 V30879TBL
<0.309 mg/Kg - dry 0.309 1.56Dibromomethane 500 03/15/23 14:59 V30879TBL
<0.096 mg/Kg - dry 0.096 1.561,2-Dichlorobenzene 500 03/15/23 14:59 V30879TBL
<0.118 mg/Kg - dry 0.118 1.561,3-Dichlorobenzene 500 03/15/23 14:59 V30879TBL
<0.187 mg/Kg - dry 0.187 1.561,4-Dichlorobenzene 500 03/15/23 14:59 V30879TBL
<0.411 mg/Kg - dry 0.411 3.12Dichlorodifluoromethane 500 03/15/23 14:59 V30879TBL
<0.255 mg/Kg - dry 0.255 1.561,1-Dichloroethane 500 03/15/23 14:59 V30879TBL
<0.430 mg/Kg - dry 0.430 1.561,2-Dichloroethane 500 03/15/23 14:59 V30879TBL
<0.228 mg/Kg - dry 0.228 1.561,1-Dichloroethene 500 03/15/23 14:59 V30879TBL
<0.246 mg/Kg - dry 0.246 1.56cis-1,2-Dichloroethene 500 03/15/23 14:59 V30879TBL
<0.327 mg/Kg - dry 0.327 1.56trans-1,2-Dichloroethene 500 03/15/23 14:59 V30879TBL
<0.137 mg/Kg - dry 0.137 1.561,2-Dichloropropane 500 03/15/23 14:59 V30879TBL
<0.172 mg/Kg - dry 0.172 1.561,3-Dichloropropane 500 03/15/23 14:59 V30879TBL
<0.396 mg/Kg - dry 0.396 1.562,2-Dichloropropane 500 03/15/23 14:59 V30879TBL
<0.236 mg/Kg - dry 0.236 1.561,1-Dichloropropene 500 03/15/23 14:59 V30879TBL
<0.168 mg/Kg - dry 0.168 1.56cis-1,3-Dichloropropene 500 03/15/23 14:59 V30879TBL
<0.249 mg/Kg - dry 0.249 1.56trans-1,3-Dichloropropene 500 03/15/23 14:59 V30879TBL
25.9 mg/Kg - dry 0.180 1.56Ethylbenzene 500 03/15/23 14:59 V30879TBL
<0.259 mg/Kg - dry 0.259 31.2Ethyl Tertiary Butyl Ether (ETBE)500 03/15/23 14:59 V30879TBL
<0.246 mg/Kg - dry 0.246 3.12Hexachlorobutadiene 500 03/15/23 14:59 V30879TBL
19.3 mg/Kg - dry 0.205 3.12n-Hexane 500 03/15/23 14:59 V30879TBL
<0.193 mg/Kg - dry 0.193 6.232-Hexanone 500 03/15/23 14:59 V30879TBL
3.38 mg/Kg - dry 0.143 1.56Isopropylbenzene 500 03/15/23 14:59 V30879TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 30 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:SB-2 (20')
91098 Matrix:
3/8/2023 13:31
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V30878 03/15/23 08:00
1.25 J mg/Kg - dry 0.405 1.564-Isopropyl toluene 500 03/15/23 14:59 V30879TBL
<0.203 mg/Kg - dry 0.203 6.23Methyl Ethyl Ketone (MEK)500 03/15/23 14:59 V30879TBL
<0.193 mg/Kg - dry 0.193 1.56Methyl tert-butyl ether (MTBE)500 03/15/23 14:59 V30879TBL
<4.68 mg/Kg - dry 4.68 6.234-Methyl-2-Pentanone 500 03/15/23 14:59 V30879TBL
0.558 J mg/Kg - dry 0.458 1.56Methylene Chloride 500 03/15/23 14:59 V30879TBL
13.0 mg/Kg - dry 0.309 3.12Naphthalene 500 03/15/23 14:59 V30879TBL
11.9 mg/Kg - dry 0.168 1.56n-Propylbenzene 500 03/15/23 14:59 V30879TBL
<0.442 mg/Kg - dry 0.442 1.56Styrene 500 03/15/23 14:59 V30879TBL
<0.327 mg/Kg - dry 0.327 1.561,1,1,2-Tetrachloroethane 500 03/15/23 14:59 V30879TBL
<0.099 mg/Kg - dry 0.099 1.561,1,2,2-Tetrachloroethane 500 03/15/23 14:59 V30879TBL
<0.280 mg/Kg - dry 0.280 1.56Tetrachloroethene 500 03/15/23 14:59 V30879TBL
35.7 mg/Kg - dry 0.205 1.56Toluene 500 03/15/23 14:59 V30879TBL
<0.168 mg/Kg - dry 0.168 3.121,2,3-Trichlorobenzene 500 03/15/23 14:59 V30879TBL
<0.199 mg/Kg - dry 0.199 3.121,2,4-Trichlorobenzene 500 03/15/23 14:59 V30879TBL
<0.448 mg/Kg - dry 0.448 1.561,1,1-Trichloroethane 500 03/15/23 14:59 V30879TBL
<0.147 mg/Kg - dry 0.147 1.561,1,2-Trichloroethane 500 03/15/23 14:59 V30879TBL
<0.286 mg/Kg - dry 0.286 1.56Trichloroethene 500 03/15/23 14:59 V30879TBL
<0.652 mg/Kg - dry 0.652 3.12Trichlorofluoromethane 500 03/15/23 14:59 V30879TBL
<0.224 mg/Kg - dry 0.224 1.561,2,3-Trichloropropane 500 03/15/23 14:59 V30879TBL
67.8 mg/Kg - dry 0.153 1.561,2,4-Trimethylbenzene 500 03/15/23 14:59 V30879TBL
21.8 mg/Kg - dry 0.168 1.561,3,5-Trimethylbenzene 500 03/15/23 14:59 V30879TBL
<0.143 mg/Kg - dry 0.143 3.12Vinyl Acetate 500 03/15/23 14:59 V30879TBL
<0.149 mg/Kg - dry 0.149 3.12Vinyl Chloride 500 03/15/23 14:59 V30879TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 31 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:SB-2 (20')
91098 Matrix:
3/8/2023 13:31
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V30878 03/15/23 08:00
32.8 mg/Kg - dry 0.155 1.56o-Xylene 500 03/15/23 14:59 V30879TBL
88.4 mg/Kg - dry 0.392 3.12m,p-Xylene 500 03/15/23 14:59 V30879TBL
121 mg/Kg - dry 0.155 1.56Xylene (Total)500 03/15/23 14:59 V30879
Surrogate: 4-Bromofluorobenzene 97.7 Limits: 70-130%03/15/23 14:59500 TBL V30879
Surrogate: Dibromofluoromethane 96.8 Limits: 70-130%03/15/23 14:59500 TBL V30879
Surrogate: Toluene-d8 95.9 Limits: 76-129%03/15/23 14:59500 TBL V30879
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V30932 03/17/23 09:00
<0.144 mg/Kg - dry 0.144 0.824
Acenaphthene 1 03/17/23 19:20 V30974JMV
<0.130 mg/Kg - dry 0.130 0.824Acenaphthylene 1 03/17/23 19:20 V30974JMV
<0.189 mg/Kg - dry 0.189 0.824Aniline 1 03/17/23 19:20 V30974JMV
<0.178 mg/Kg - dry 0.178 0.824Anthracene 1 03/17/23 19:20 V30974JMV
<0.173 mg/Kg - dry 0.173 0.824Benzo(a)anthracene 1 03/17/23 19:20 V30974JMV
<0.183 mg/Kg - dry 0.183 0.824
Benzo(a)pyrene 1 03/17/23 19:20 V30974JMV
<0.182 mg/Kg - dry 0.182 0.824Benzo(b)fluoranthene 1 03/17/23 19:20 V30974JMV
<0.169 mg/Kg - dry 0.169 0.824Benzo(g,h,i)perylene 1 03/17/23 19:20 V30974JMV
<0.170 mg/Kg - dry 0.170 0.824Benzo(k)fluoranthene 1 03/17/23 19:20 V30974JMV
<0.723 M mg/Kg - dry 0.723 2.49Benzoic Acid 1 03/17/23 19:20 V30974JMV
<0.130 mg/Kg - dry 0.130 0.824
Benzyl alcohol 1 03/17/23 19:20 V30974JMV
<0.147 mg/Kg - dry 0.147 0.824Bis(2-Chloroethoxy)methane 1 03/17/23 19:20 V30974JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 32 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:SB-2 (20')
91098 Matrix:
3/8/2023 13:31
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V30932 03/17/23 09:00
<0.133 mg/Kg - dry 0.133 0.824Bis(2-Chloroethyl)ether 1 03/17/23 19:20 V30974JMV
<0.169 mg/Kg - dry 0.169 0.411Bis(2-Chloroisopropyl)ether 1 03/17/23 19:20 V30974JMV
<0.149 mg/Kg - dry 0.149 0.824Bis(2-ethylhexyl)phthalate 1 03/17/23 19:20 V30974JMV
<0.135 mg/Kg - dry 0.135 0.8244-Bromophenyl phenyl ether 1 03/17/23 19:20 V30974JMV
<0.140 mg/Kg - dry 0.140 0.411Butyl benzyl phthalate 1 03/17/23 19:20 V30974JMV
<0.115 mg/Kg - dry 0.115 0.8244-Chloro-3-methylphenol 1 03/17/23 19:20 V30974JMV
<0.139 mg/Kg - dry 0.139 0.4114-Chloroaniline 1 03/17/23 19:20 V30974JMV
<0.144 mg/Kg - dry 0.144 0.8242-Chloronaphthalene 1 03/17/23 19:20 V30974JMV
<0.122 mg/Kg - dry 0.122 0.8242-Chlorophenol 1 03/17/23 19:20 V30974JMV
<0.157 mg/Kg - dry 0.157 1.254-Chlorophenyl phenyl ether 1 03/17/23 19:20 V30974JMV
<0.177 mg/Kg - dry 0.177 0.824Chrysene 1 03/17/23 19:20 V30974JMV
<0.286 mg/Kg - dry 0.286 0.824Dibenz(a,h)anthracene 1 03/17/23 19:20 V30974JMV
<0.148 mg/Kg - dry 0.148 0.824Dibenzofuran 1 03/17/23 19:20 V30974JMV
<0.117 mg/Kg - dry 0.117 0.8241,2-Dichlorobenzene 1 03/17/23 19:20 V30974JMV
<0.121 mg/Kg - dry 0.121 0.8241,3-Dichlorobenzene 1 03/17/23 19:20 V30974JMV
<0.121 mg/Kg - dry 0.121 0.4111,4-Dichlorobenzene 1 03/17/23 19:20 V30974JMV
<0.183 mg/Kg - dry 0.183 0.8243,3'-Dichlorobenzidine 1 03/17/23 19:20 V30974JMV
<0.119 mg/Kg - dry 0.119 0.8242,4-Dichlorophenol 1 03/17/23 19:20 V30974JMV
<0.224 mg/Kg - dry 0.224 0.824Diethyl phthalate 1 03/17/23 19:20 V30974JMV
<0.216 mg/Kg - dry 0.216 0.824Dimethyl phthalate 1 03/17/23 19:20 V30974JMV
<0.134 mg/Kg - dry 0.134 0.4112,4-Dimethylphenol 1 03/17/23 19:20 V30974JMV
<0.133 mg/Kg - dry 0.133 0.824Di-n-butyl phthalate 1 03/17/23 19:20 V30974JMV
<0.299 mg/Kg - dry 0.299 1.874,6-Dinitro-2-methylphenol 1 03/17/23 19:20 V30974JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 33 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:SB-2 (20')
91098 Matrix:
3/8/2023 13:31
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V30932 03/17/23 09:00
<0.648 mg/Kg - dry 0.648 1.872,4-Dinitrophenol 1 03/17/23 19:20 V30974JMV
<0.120 mg/Kg - dry 0.120 0.8242,4-Dinitrotoluene 1 03/17/23 19:20 V30974JMV
<0.134 mg/Kg - dry 0.134 0.8242,6-Dinitrotoluene 1 03/17/23 19:20 V30974JMV
<0.178 mg/Kg - dry 0.178 0.411Di-n-Octyl Phthalate 1 03/17/23 19:20 V30974JMV
<0.153 mg/Kg - dry 0.153 0.824Fluoranthene 1 03/17/23 19:20 V30974JMV
<0.159 mg/Kg - dry 0.159 0.824Fluorene 1 03/17/23 19:20 V30974JMV
<0.132 mg/Kg - dry 0.132 0.824Hexachlorobenzene 1 03/17/23 19:20 V30974JMV
<0.121 mg/Kg - dry 0.121 0.824Hexachlorobutadiene 1 03/17/23 19:20 V30974JMV
<0.195 mg/Kg - dry 0.195 0.824Hexachlorocyclopentadiene 1 03/17/23 19:20 V30974JMV
<0.098 mg/Kg - dry 0.098 0.824Hexachloroethane 1 03/17/23 19:20 V30974JMV
<0.223 mg/Kg - dry 0.223 0.824Indeno(1,2,3-cd)pyrene 1 03/17/23 19:20 V30974JMV
<0.238 mg/Kg - dry 0.238 0.824Isophorone 1 03/17/23 19:20 V30974JMV
3.88 mg/Kg - dry 0.132 0.8241-Methylnaphthalene 1 03/17/23 19:20 V30974JMV
7.19 mg/Kg - dry 0.124 0.8242-Methylnaphthalene 1 03/17/23 19:20 V30974JMV
<0.121 mg/Kg - dry 0.121 0.8242-Methylphenol 1 03/17/23 19:20 V30974JMV
<0.105 mg/Kg - dry 0.105 0.8243&4 Methylphenol 1 03/17/23 19:20 V30974JMV
6.56 mg/Kg - dry 0.179 0.824Naphthalene 1 03/17/23 19:20 V30974JMV
<0.120 mg/Kg - dry 0.120 0.8242-Nitroaniline 1 03/17/23 19:20 V30974JMV
<0.149 mg/Kg - dry 0.149 0.8243-Nitroaniline 1 03/17/23 19:20 V30974JMV
<0.116 mg/Kg - dry 0.116 0.4114-Nitroaniline 1 03/17/23 19:20 V30974JMV
<0.144 mg/Kg - dry 0.144 0.411Nitrobenzene 1 03/17/23 19:20 V30974JMV
<0.110 mg/Kg - dry 0.110 0.8242-Nitrophenol 1 03/17/23 19:20 V30974JMV
<0.145 mg/Kg - dry 0.145 0.8244-Nitrophenol 1 03/17/23 19:20 V30974JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 34 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:SB-2 (20')
91098 Matrix:
3/8/2023 13:31
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V30932 03/17/23 09:00
<0.327 mg/Kg - dry 0.327 0.824N-Nitrosodimethylamine 1 03/17/23 19:20 V30974JMV
<0.225 mg/Kg - dry 0.225 0.824N-Nitrosodiphenylamine 1 03/17/23 19:20 V30974JMV
<0.147 mg/Kg - dry 0.147 0.824N-Nitroso-di-n-propylamine 1 03/17/23 19:20 V30974JMV
<0.432 mg/Kg - dry 0.432 1.25Pentachlorophenol 1 03/17/23 19:20 V30974JMV
<0.259 mg/Kg - dry 0.259 0.824Phenanthrene 1 03/17/23 19:20 V30974JMV
<0.139 mg/Kg - dry 0.139 0.824Phenol 1 03/17/23 19:20 V30974JMV
<0.167 mg/Kg - dry 0.167 0.824Pyrene 1 03/17/23 19:20 V30974JMV
<0.098 mg/Kg - dry 0.098 0.411Pyridine 1 03/17/23 19:20 V30974JMV
<0.133 mg/Kg - dry 0.133 0.8241,2,4-Trichlorobenzene 1 03/17/23 19:20 V30974JMV
<0.120 mg/Kg - dry 0.120 0.8242,4,5-Trichlorophenol 1 03/17/23 19:20 V30974JMV
<0.120 mg/Kg - dry 0.120 0.8242,4,6-Trichlorophenol 1 03/17/23 19:20 V30974JMV
8270ESurrogate: Phenol-d5 77.8 Limits: 34-121%03/17/23 19:201 JMV
Surrogate: 2-Fluorobiphenyl 95.8 Limits: 44-115%03/17/23 19:201 JMV V30974
Surrogate: 2-Fluorophenol 84.4 Limits: 35-115%03/17/23 19:201 JMV V30974
Surrogate: Nitrobenzene-d5 85.6 Limits: 37-122%03/17/23 19:201 JMV V30974
Surrogate: 4-Terphenyl-d14 104 Limits: 54-127%03/17/23 19:201 JMV V30974
Surrogate: 2,4,6-Tribromophenol 97.3 Limits: 39-132%03/17/23 19:201 JMV V30974
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 35 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:SB-2 (20')
91098 Matrix:
3/8/2023 13:31
Solids
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
4110 J mg/Kg - dry 7.58 49.9Aliphatic C5-C8 (Adjusted)500 03/15/23 14:59
1060 mg/Kg - dry 28.4 49.9Aliphatics C9-C12 (Adjusted)500 03/15/23 14:59
1910 mg/Kg - dry 3.89 49.9Aromatic C9-C10 (Adjusted)500 03/15/23 18:25
455 J mg/Kg - dry 177 623Aromatic C11-C22 (Adjusted)1 03/17/23 19:20
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V30933 03/17/23 16:00
1250 mg/Kg - dry 115 623Aliphatic C9-C18 10 03/21/23 19:33 V31003AMP
<152 mg/Kg - dry 152 623Aliphatic C19-C36 10 03/21/23 19:33 V31003AMP
461 J
mg/Kg - dry 177 623
Aromatic C11-C22 10 03/21/23 19:33 V31003AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene 147 *Limits: 40-140%03/21/23 19:3310 AMP
MADEP-EPHSurrogate: Chlorooctadecane 84.7 Limits: 40-140%03/21/23 19:3310 AMP
MADEP-EPHSurrogate: OTP Surrogate 114 Limits: 40-140%03/21/23 19:3310 AMP
Surrogate: 2-Fluorobiphenyl 131 Limits: 40-140%03/21/23 19:3310 AMP V31003
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V30855 03/15/23 08:00
4150 mg/Kg - dry 7.58 49.9Aliphatic C5-C8 500 03/15/23 18:25 V30856TBL
3120 mg/Kg - dry 28.4 49.9Aliphatic C9-C12 500 03/15/23 18:25 V30856TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 36 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:SB-2 (20')
91098 Matrix:
3/8/2023 13:31
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V30855 03/15/23 08:00
1910 mg/Kg - dry 3.89 49.9Aromatic C9-C10 500 03/15/23 18:25 V30856TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)93.5 Limits: 70-130%03/15/23 18:25500 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)103 Limits: 70-130%03/15/23 18:25500 TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 37 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:TW-1
91099 Matrix:
3/13/2023 11:52
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 03/17/23 19:40 6200BMSA
0.003 J mg/L 0.002 0.006Lead 1 03/27/23 17:29 6010DMMR
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 38 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:TW-1
91099 Matrix:
3/13/2023 11:52
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30983 03/17/23 09:00
4.84 J µg/L 1.80 10.0Acetone 1 03/17/23 19:40 V30984MSA
<0.180 µg/L 0.180 0.500Benzene 1 03/17/23 19:40 V30984MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 03/17/23 19:40 V30984MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 03/17/23 19:40 V30984MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 03/17/23 19:40 V30984MSA
<1.50 µg/L 1.50 5.00Bromoform 1 03/17/23 19:40 V30984MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 03/17/23 19:40 V30984MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 03/17/23 19:40 V30984MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 03/17/23 19:40 V30984MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 03/17/23 19:40 V30984MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 03/17/23 19:40 V30984MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 03/17/23 19:40 V30984MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 03/17/23 19:40 V30984MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 03/17/23 19:40 V30984MSA
<0.220 µg/L 0.220 0.500Chloroform 1 03/17/23 19:40 V30984MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 03/17/23 19:40 V30984MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 03/17/23 19:40 V30984MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 03/17/23 19:40 V30984MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 03/17/23 19:40 V30984MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 03/17/23 19:40 V30984MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 03/17/23 19:40 V30984MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 03/17/23 19:40 V30984MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 03/17/23 19:40 V30984MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 39 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:TW-1
91099 Matrix:
3/13/2023 11:52
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30983 03/17/23 09:00
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 03/17/23 19:40 V30984MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 03/17/23 19:40 V30984MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 03/17/23 19:40 V30984MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 03/17/23 19:40 V30984MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 03/17/23 19:40 V30984MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 03/17/23 19:40 V30984MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 03/17/23 19:40 V30984MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 03/17/23 19:40 V30984MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 03/17/23 19:40 V30984MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 03/17/23 19:40 V30984MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 03/17/23 19:40 V30984MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 03/17/23 19:40 V30984MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 03/17/23 19:40 V30984MSA
<42.0 µg/L 42.0 200Ethanol 1 03/17/23 19:40 V30984MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 03/17/23 19:40 V30984MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 03/17/23 19:40 V30984MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 03/17/23 19:40 V30984MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 03/17/23 19:40 V30984MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 03/17/23 19:40 V30984MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 03/17/23 19:40 V30984MSA
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 03/17/23 19:40 V30984MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 03/17/23 19:40 V30984MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 03/17/23 19:40 V30984MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 40 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:TW-1
91099 Matrix:
3/13/2023 11:52
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30983 03/17/23 09:00
<0.470 µg/L 0.470 1.00Naphthalene 1 03/17/23 19:40 V30984MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 03/17/23 19:40 V30984MSA
<0.220 µg/L 0.220 0.500Styrene 1 03/17/23 19:40 V30984MSA
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 03/17/23 19:40 V30984MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 03/17/23 19:40 V30984MSA
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 03/17/23 19:40 V30984MSA
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 03/17/23 19:40 V30984MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 03/17/23 19:40 V30984MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 03/17/23 19:40 V30984MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 03/17/23 19:40 V30984MSA
0.441 J µg/L 0.220 0.500Toluene 1 03/17/23 19:40 V30984MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 03/17/23 19:40 V30984MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 03/17/23 19:40 V30984MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 03/17/23 19:40 V30984MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 03/17/23 19:40 V30984MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 03/17/23 19:40 V30984MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 03/17/23 19:40 V30984MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 03/17/23 19:40 V30984MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 03/17/23 19:40 V30984MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 03/17/23 19:40 V30984MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 03/17/23 19:40 V30984MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 03/17/23 19:40 V30984MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 03/17/23 19:40 V30984MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 41 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:TW-1
91099 Matrix:
3/13/2023 11:52
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30983 03/17/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 03/17/23 19:40 V30984MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 03/17/23 19:40 V30984KCC
Surrogate: 4-Bromofluorobenzene 97.2 Limits: 70-130%03/17/23 19:401 MSA V30984
Surrogate: Dibromofluoromethane 88.8 Limits: 70-130%03/17/23 19:401 MSA V30984
Surrogate: 1,2-Dichloroethane - d4 91.2 Limits: 70-130%03/17/23 19:401 MSA V30984
Surrogate: Toluene-d8 97.0 Limits: 70-130%03/17/23 19:401 MSA V30984
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V30880 03/16/23 09:02
<0.305 µg/L 0.305 2.02Acenaphthene 1 03/16/23 22:50 V30970JMV
<0.299 µg/L 0.299 2.02Acenaphthylene 1 03/16/23 22:50 V30970JMV
<0.844 µg/L 0.844 2.02Anthracene 1 03/16/23 22:50 V30970JMV
<1.33 µg/L 1.33 10.1Benzidine 1 03/16/23 22:50 V30970JMV
<0.643 µg/L 0.643 2.02Benzo(a)anthracene 1 03/16/23 22:50 V30970JMV
<1.03 µg/L 1.03 2.02Benzo(a)pyrene 1 03/16/23 22:50 V30970JMV
<2.51 µg/L 2.51 5.05Benzo(b)fluoranthene 1 03/16/23 22:50 V30970JMV
<1.02 µg/L 1.02 5.05Benzo(g,h,i)perylene 1 03/16/23 22:50 V30970JMV
<2.01 µg/L 2.01 5.05Benzo(k)fluoranthene 1 03/16/23 22:50 V30970JMV
<1.11 µg/L 1.11 10.1Benzoic Acid 1 03/16/23 22:50 V30970JMV
<0.690 µg/L 0.690 5.05Benzyl alcohol 1 03/16/23 22:50 V30970JMV
<0.472 µg/L 0.472 5.05Bis(2-Chloroethoxy)methane 1 03/16/23 22:50 V30970JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 42 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:TW-1
91099 Matrix:
3/13/2023 11:52
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V30880 03/16/23 09:02
<1.05 µg/L 1.05 5.05Bis(2-Chloroethyl)ether 1 03/16/23 22:50 V30970JMV
<1.09 µg/L 1.09 5.05Bis(2-Chloroisopropyl)ether 1 03/16/23 22:50 V30970JMV
<3.49 µg/L 3.49 10.1Bis(2-ethylhexyl)phthalate 1 03/16/23 22:50 V30970JMV
<1.12 µg/L 1.12 5.054-Bromophenyl phenyl ether 1 03/16/23 22:50 V30970JMV
<1.85 µg/L 1.85 5.05Butyl benzyl phthalate 1 03/16/23 22:50 V30970JMV
<1.19 µg/L 1.19 5.054-Chloro-3-methylphenol 1 03/16/23 22:50 V30970JMV
<7.45 µg/L 7.45 20.22-Chloronaphthalene 1 03/16/23 22:50 V30970JMV
<0.947 µg/L 0.947 10.12-Chlorophenol 1 03/16/23 22:50 V30970JMV
<1.73 µg/L 1.73 5.054-Chlorophenyl phenyl ether 1 03/16/23 22:50 V30970JMV
<0.409 µg/L 0.409 2.02Chrysene 1 03/16/23 22:50 V30970JMV
<0.438 µg/L 0.438 2.02Dibenz(a,h)anthracene 1 03/16/23 22:50 V30970JMV
<0.864 µg/L 0.864 5.05Dibenzofuran 1 03/16/23 22:50 V30970JMV
<2.02 µg/L 2.02 5.051,2-Dichlorobenzene 1 03/16/23 22:50 V30970JMV
<2.02 µg/L 2.02 5.051,3-Dichlorobenzene 1 03/16/23 22:50 V30970JMV
<2.07 µg/L 2.07 5.051,4-Dichlorobenzene 1 03/16/23 22:50 V30970JMV
<1.91 µg/L 1.91 5.053,3'-Dichlorobenzidine 1 03/16/23 22:50 V30970JMV
<1.47 µg/L 1.47 10.12,4-Dichlorophenol 1 03/16/23 22:50 V30970JMV
<0.752 µg/L 0.752 5.05Diethyl phthalate 1 03/16/23 22:50 V30970JMV
<0.948 µg/L 0.948 5.05Dimethyl phthalate 1 03/16/23 22:50 V30970JMV
<1.59 µg/L 1.59 20.22,4-Dimethylphenol 1 03/16/23 22:50 V30970JMV
8.56 µg/L 2.08 5.05Di-n-butyl phthalate 1 03/16/23 22:50 V30970JMV
<2.09 µg/L 2.09 10.14,6-Dinitro-2-methylphenol 1 03/16/23 22:50 V30970JMV
<1.94 µg/L 1.94 10.12,4-Dinitrophenol 1 03/16/23 22:50 V30970JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 43 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:TW-1
91099 Matrix:
3/13/2023 11:52
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V30880 03/16/23 09:02
<1.12 µg/L 1.12 5.052,4-Dinitrotoluene 1 03/16/23 22:50 V30970JMV
<0.817 µg/L 0.817 5.052,6-Dinitrotoluene 1 03/16/23 22:50 V30970JMV
<1.67 µg/L 1.67 5.05Di-n-Octyl Phthalate 1 03/16/23 22:50 V30970JMV
<0.252 µg/L 0.252 2.02Fluoranthene 1 03/16/23 22:50 V30970JMV
<0.815 µg/L 0.815 2.02Fluorene 1 03/16/23 22:50 V30970JMV
<0.988 µg/L 0.988 5.05Hexachlorobenzene 1 03/16/23 22:50 V30970JMV
<2.76 µg/L 2.76 5.05Hexachlorobutadiene 1 03/16/23 22:50 V30970JMV
<2.07 µg/L 2.07 5.05Hexachlorocyclopentadiene 1 03/16/23 22:50 V30970JMV
<1.78 µg/L 1.78 5.05Hexachloroethane 1 03/16/23 22:50 V30970JMV
<0.481 µg/L 0.481 2.02Indeno(1,2,3-cd)pyrene 1 03/16/23 22:50 V30970JMV
<0.448 µg/L 0.448 5.05Isophorone 1 03/16/23 22:50 V30970JMV
<0.735 µg/L 0.735 2.02Naphthalene 1 03/16/23 22:50 V30970JMV
<0.914 µg/L 0.914 5.05Nitrobenzene 1 03/16/23 22:50 V30970JMV
<0.497 µg/L 0.497 5.052-Nitrophenol 1 03/16/23 22:50 V30970JMV
<1.24 µg/L 1.24 10.14-Nitrophenol 1 03/16/23 22:50 V30970JMV
<1.11 µg/L 1.11 5.05N-Nitrosodiphenylamine 1 03/16/23 22:50 V30970JMV
<0.647 µg/L 0.647 5.05N-Nitroso-di-n-propylamine 1 03/16/23 22:50 V30970JMV
<1.44 µg/L 1.44 5.05Pentachlorophenol 1 03/16/23 22:50 V30970JMV
<0.432 µg/L 0.432 2.02Phenanthrene 1 03/16/23 22:50 V30970JMV
<0.657 µg/L 0.657 5.05Phenol 1 03/16/23 22:50 V30970JMV
<0.438 µg/L 0.438 2.02Pyrene 1 03/16/23 22:50 V30970JMV
<2.23 µg/L 2.23 5.051,2,4-Trichlorobenzene 1 03/16/23 22:50 V30970JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 44 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:TW-1
91099 Matrix:
3/13/2023 11:52
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V30880 03/16/23 09:02
<1.33 µg/L 1.33 5.052,4,6-Trichlorophenol 1 03/16/23 22:50 V30970JMV
625.1Surrogate: Phenol-d5 32.9 Limits: 10-63%03/16/23 22:501 JMV
Surrogate: 2-Fluorobiphenyl 82.2 Limits: 49-118%03/16/23 22:501 JMV V30970
Surrogate: 2-Fluorophenol 45.0 Limits: 22-84%03/16/23 22:501 JMV V30970
Surrogate: Nitrobenzene-d5 69.9 Limits: 43-123%03/16/23 22:501 JMV V30970
Surrogate: 4-Terphenyl-d14 92.9 Limits: 49-151%03/16/23 22:501 JMV V30970
Surrogate: 2,4,6-Tribromophenol 88.0 Limits: 31-144%03/16/23 22:501 JMV V30970
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V30967 03/20/23 13:44
<0.00345 µg/L 0.00345 0.02091,2-Dibromoethane 1 03/20/23 16:28 V31002AMP
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 45 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:TW-1
91099 Matrix:
3/13/2023 11:52
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 03/15/23 12:27
<25.8 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 03/15/23 12:27
<4.02 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 03/15/23 12:27
<70.3 µg/L 70.3 287Aromatic C11-C22 (Adjusted)1 03/16/23 22:50
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V30918 03/17/23 10:35
<32.4 µg/L 32.4 402Aliphatic C9-C18 1 03/20/23 11:35 V30950AMP
<143 µg/L 143 575Aliphatic C19-C36 1 03/20/23 11:35 V30950AMP
<70.3 µg/L 70.3 287
Aromatic C11-C22 1 03/20/23 11:35 V30950AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene 107 Limits: 40-140%03/20/23 11:351 AMP
MADEP-EPHSurrogate: Chlorooctadecane 72.5 Limits: 40-140%03/20/23 11:351 AMP
MADEP-EPHSurrogate: OTP Surrogate 82.0 Limits: 40-140%03/20/23 11:351 AMP
Surrogate: 2-Fluorobiphenyl 108 Limits: 40-140%03/20/23 11:351 AMP V30950
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V30853 03/15/23 08:00
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 03/15/23 12:27 V30854TBL
<25.8 µg/L 25.8 50.0Aliphatic C9-C12 1 03/15/23 12:27 V30854TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 46 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:TW-1
91099 Matrix:
3/13/2023 11:52
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V30853 03/15/23 08:00
<4.02 µg/L 4.02 50.0Aromatic C9-C10 1 03/15/23 12:27 V30854TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)90.2 Limits: 70-130%03/15/23 12:271 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)85.3 Limits: 70-130%03/15/23 12:271 TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 47 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-11
91100 Matrix:
3/13/2023 12:17
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 03/20/23 16:00 6200BMSA
0.009 mg/L 0.002 0.006Lead 1 03/27/23 17:34 6010DMMR
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 48 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-11
91100 Matrix:
3/13/2023 12:17
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31045 03/20/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 03/20/23 16:00 V31046MSA
56.6 µg/L 0.180 0.500Benzene 1 03/20/23 16:00 V31046MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 03/20/23 16:00 V31046MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 03/20/23 16:00 V31046MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 03/20/23 16:00 V31046MSA
<1.50 µg/L 1.50 5.00Bromoform 1 03/20/23 16:00 V31046MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 03/20/23 16:00 V31046MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 03/20/23 16:00 V31046MSA
0.245 J µg/L 0.200 0.500sec-Butyl benzene 1 03/20/23 16:00 V31046MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 03/20/23 16:00 V31046MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 03/20/23 16:00 V31046MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 03/20/23 16:00 V31046MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 03/20/23 16:00 V31046MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 03/20/23 16:00 V31046MSA
<0.220 µg/L 0.220 0.500Chloroform 1 03/20/23 16:00 V31046MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 03/20/23 16:00 V31046MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 03/20/23 16:00 V31046MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 03/20/23 16:00 V31046MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 03/20/23 16:00 V31046MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 03/20/23 16:00 V31046MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 03/20/23 16:00 V31046MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 03/20/23 16:00 V31046MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 03/20/23 16:00 V31046MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 49 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-11
91100 Matrix:
3/13/2023 12:17
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31045 03/20/23 09:00
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 03/20/23 16:00 V31046MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 03/20/23 16:00 V31046MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 03/20/23 16:00 V31046MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 03/20/23 16:00 V31046MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 03/20/23 16:00 V31046MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 03/20/23 16:00 V31046MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 03/20/23 16:00 V31046MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 03/20/23 16:00 V31046MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 03/20/23 16:00 V31046MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 03/20/23 16:00 V31046MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 03/20/23 16:00 V31046MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 03/20/23 16:00 V31046MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 03/20/23 16:00 V31046MSA
<42.0 µg/L 42.0 200Ethanol 1 03/20/23 16:00 V31046MSA
45.7 µg/L 0.170 0.500Ethylbenzene 1 03/20/23 16:00 V31046MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 03/20/23 16:00 V31046MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 03/20/23 16:00 V31046MSA
1.91 µg/L 0.180 0.500Isopropylbenzene 1 03/20/23 16:00 V31046MSA
0.383 J µg/L 0.089 0.5004-Isopropyl toluene 1 03/20/23 16:00 V31046MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 03/20/23 16:00 V31046MSA
0.241 J µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 03/20/23 16:00 V31046MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 03/20/23 16:00 V31046MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 03/20/23 16:00 V31046MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 50 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-11
91100 Matrix:
3/13/2023 12:17
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31045 03/20/23 09:00
2.16 µg/L 0.470 1.00Naphthalene 1 03/20/23 16:00 V31046MSA
2.86 µg/L 0.190 0.500n-Propylbenzene 1 03/20/23 16:00 V31046MSA
0.237 J µg/L 0.220 0.500Styrene 1 03/20/23 16:00 V31046MSA
2.50 J µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 03/20/23 16:00 V31046MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 03/20/23 16:00 V31046MSA
82.7 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 03/20/23 16:00 V31046MSA
0.449 J µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 03/20/23 16:00 V31046MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 03/20/23 16:00 V31046MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 03/20/23 16:00 V31046MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 03/20/23 16:00 V31046MSA
2.75 µg/L 0.220 0.500Toluene 1 03/20/23 16:00 V31046MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 03/20/23 16:00 V31046MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 03/20/23 16:00 V31046MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 03/20/23 16:00 V31046MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 03/20/23 16:00 V31046MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 03/20/23 16:00 V31046MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 03/20/23 16:00 V31046MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 03/20/23 16:00 V31046MSA
2.14 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 03/20/23 16:00 V31046MSA
6.71 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 03/20/23 16:00 V31046MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 03/20/23 16:00 V31046MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 03/20/23 16:00 V31046MSA
79.8 µg/L 0.210 0.500o-Xylene 1 03/20/23 16:00 V31046MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 51 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-11
91100 Matrix:
3/13/2023 12:17
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31045 03/20/23 09:00
28.4 µg/L 0.420 1.00m,p-Xylene 1 03/20/23 16:00 V31046MSA
108 µg/L 0.210 0.500Xylene (Total)1 03/20/23 16:00 V31046KCC
Surrogate: 4-Bromofluorobenzene 96.0 Limits: 70-130%03/20/23 16:001 MSA V31046
Surrogate: Dibromofluoromethane 86.6 Limits: 70-130%03/20/23 16:001 MSA V31046
Surrogate: 1,2-Dichloroethane - d4 88.4 Limits: 70-130%03/20/23 16:001 MSA V31046
Surrogate: Toluene-d8 98.4 Limits: 70-130%03/20/23 16:001 MSA V31046
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V30880 03/16/23 09:02
<0.305 µg/L 0.305 2.02Acenaphthene 1 03/16/23 23:13 V30970JMV
<0.299 µg/L 0.299 2.02Acenaphthylene 1 03/16/23 23:13 V30970JMV
<0.844 µg/L 0.844 2.02Anthracene 1 03/16/23 23:13 V30970JMV
<1.33 µg/L 1.33 10.1Benzidine 1 03/16/23 23:13 V30970JMV
<0.643 µg/L 0.643 2.02Benzo(a)anthracene 1 03/16/23 23:13 V30970JMV
<1.03 µg/L 1.03 2.02Benzo(a)pyrene 1 03/16/23 23:13 V30970JMV
<2.51 µg/L 2.51 5.05Benzo(b)fluoranthene 1 03/16/23 23:13 V30970JMV
<1.02 µg/L 1.02 5.05Benzo(g,h,i)perylene 1 03/16/23 23:13 V30970JMV
<2.01 µg/L 2.01 5.05Benzo(k)fluoranthene 1 03/16/23 23:13 V30970JMV
<1.11 µg/L 1.11 10.1Benzoic Acid 1 03/16/23 23:13 V30970JMV
<0.690 µg/L 0.690 5.05Benzyl alcohol 1 03/16/23 23:13 V30970JMV
<0.472 µg/L 0.472 5.05Bis(2-Chloroethoxy)methane 1 03/16/23 23:13 V30970JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 52 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-11
91100 Matrix:
3/13/2023 12:17
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V30880 03/16/23 09:02
<1.05 µg/L 1.05 5.05Bis(2-Chloroethyl)ether 1 03/16/23 23:13 V30970JMV
<1.09 µg/L 1.09 5.05Bis(2-Chloroisopropyl)ether 1 03/16/23 23:13 V30970JMV
<3.49 µg/L 3.49 10.1Bis(2-ethylhexyl)phthalate 1 03/16/23 23:13 V30970JMV
<1.12 µg/L 1.12 5.054-Bromophenyl phenyl ether 1 03/16/23 23:13 V30970JMV
<1.85 µg/L 1.85 5.05Butyl benzyl phthalate 1 03/16/23 23:13 V30970JMV
<1.19 µg/L 1.19 5.054-Chloro-3-methylphenol 1 03/16/23 23:13 V30970JMV
<7.45 µg/L 7.45 20.22-Chloronaphthalene 1 03/16/23 23:13 V30970JMV
<0.947 µg/L 0.947 10.12-Chlorophenol 1 03/16/23 23:13 V30970JMV
<1.73 µg/L 1.73 5.054-Chlorophenyl phenyl ether 1 03/16/23 23:13 V30970JMV
<0.409 µg/L 0.409 2.02Chrysene 1 03/16/23 23:13 V30970JMV
<0.438 µg/L 0.438 2.02Dibenz(a,h)anthracene 1 03/16/23 23:13 V30970JMV
<0.864 µg/L 0.864 5.05Dibenzofuran 1 03/16/23 23:13 V30970JMV
<2.02 µg/L 2.02 5.051,2-Dichlorobenzene 1 03/16/23 23:13 V30970JMV
<2.02 µg/L 2.02 5.051,3-Dichlorobenzene 1 03/16/23 23:13 V30970JMV
<2.07 µg/L 2.07 5.051,4-Dichlorobenzene 1 03/16/23 23:13 V30970JMV
<1.91 µg/L 1.91 5.053,3'-Dichlorobenzidine 1 03/16/23 23:13 V30970JMV
<1.47 µg/L 1.47 10.12,4-Dichlorophenol 1 03/16/23 23:13 V30970JMV
<0.752 µg/L 0.752 5.05Diethyl phthalate 1 03/16/23 23:13 V30970JMV
<0.948 µg/L 0.948 5.05Dimethyl phthalate 1 03/16/23 23:13 V30970JMV
<1.59 µg/L 1.59 20.22,4-Dimethylphenol 1 03/16/23 23:13 V30970JMV
<2.08 µg/L 2.08 5.05Di-n-butyl phthalate 1 03/16/23 23:13 V30970JMV
<2.09 µg/L 2.09 10.14,6-Dinitro-2-methylphenol 1 03/16/23 23:13 V30970JMV
<1.94 µg/L 1.94 10.12,4-Dinitrophenol 1 03/16/23 23:13 V30970JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 53 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-11
91100 Matrix:
3/13/2023 12:17
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V30880 03/16/23 09:02
<1.12 µg/L 1.12 5.052,4-Dinitrotoluene 1 03/16/23 23:13 V30970JMV
<0.817 µg/L 0.817 5.052,6-Dinitrotoluene 1 03/16/23 23:13 V30970JMV
<1.67 µg/L 1.67 5.05Di-n-Octyl Phthalate 1 03/16/23 23:13 V30970JMV
<0.252 µg/L 0.252 2.02Fluoranthene 1 03/16/23 23:13 V30970JMV
<0.815 µg/L 0.815 2.02Fluorene 1 03/16/23 23:13 V30970JMV
<0.988 µg/L 0.988 5.05Hexachlorobenzene 1 03/16/23 23:13 V30970JMV
<2.76 µg/L 2.76 5.05Hexachlorobutadiene 1 03/16/23 23:13 V30970JMV
<2.07 µg/L 2.07 5.05Hexachlorocyclopentadiene 1 03/16/23 23:13 V30970JMV
<1.78 µg/L 1.78 5.05Hexachloroethane 1 03/16/23 23:13 V30970JMV
<0.481 µg/L 0.481 2.02Indeno(1,2,3-cd)pyrene 1 03/16/23 23:13 V30970JMV
<0.448 µg/L 0.448 5.05Isophorone 1 03/16/23 23:13 V30970JMV
3.20 µg/L 0.735 2.02Naphthalene 1 03/16/23 23:13 V30970JMV
<0.914 µg/L 0.914 5.05Nitrobenzene 1 03/16/23 23:13 V30970JMV
<0.497 µg/L 0.497 5.052-Nitrophenol 1 03/16/23 23:13 V30970JMV
<1.24 µg/L 1.24 10.14-Nitrophenol 1 03/16/23 23:13 V30970JMV
<1.11 µg/L 1.11 5.05N-Nitrosodiphenylamine 1 03/16/23 23:13 V30970JMV
<0.647 µg/L 0.647 5.05N-Nitroso-di-n-propylamine 1 03/16/23 23:13 V30970JMV
<1.44 µg/L 1.44 5.05Pentachlorophenol 1 03/16/23 23:13 V30970JMV
<0.432 µg/L 0.432 2.02Phenanthrene 1 03/16/23 23:13 V30970JMV
<0.657 µg/L 0.657 5.05Phenol 1 03/16/23 23:13 V30970JMV
<0.438 µg/L 0.438 2.02Pyrene 1 03/16/23 23:13 V30970JMV
<2.23 µg/L 2.23 5.051,2,4-Trichlorobenzene 1 03/16/23 23:13 V30970JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 54 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-11
91100 Matrix:
3/13/2023 12:17
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V30880 03/16/23 09:02
<1.33 µg/L 1.33 5.052,4,6-Trichlorophenol 1 03/16/23 23:13 V30970JMV
625.1Surrogate: Phenol-d5 43.8 Limits: 10-63%03/16/23 23:131 JMV
Surrogate: 2-Fluorobiphenyl 127 *Limits: 49-118%03/16/23 23:131 JMV V30970
Surrogate: 2-Fluorophenol 64.0 Limits: 22-84%03/16/23 23:131 JMV V30970
Surrogate: Nitrobenzene-d5 114 Limits: 43-123%03/16/23 23:131 JMV V30970
Surrogate: 4-Terphenyl-d14 166 *Limits: 49-151%03/16/23 23:131 JMV V30970
Surrogate: 2,4,6-Tribromophenol 148 *Limits: 31-144%03/16/23 23:131 JMV V30970
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V30967 03/20/23 13:44
<0.00348 µg/L 0.00348 0.02111,2-Dibromoethane 1 03/20/23 17:03 V31002AMP
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 55 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-11
91100 Matrix:
3/13/2023 12:17
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
114 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 03/15/23 14:26
129 J µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 03/15/23 14:26
32.9 J µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 03/15/23 14:26
<61.2 µg/L 61.2 250Aromatic C11-C22 (Adjusted)1 03/24/23 18:51
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V31110 03/23/23 10:25
<28.2 µg/L 28.2 350Aliphatic C9-C18 1 03/24/23 18:51 V31230AMP
<124 µg/L 124 500Aliphatic C19-C36 1 03/24/23 18:51 V31230AMP
<61.2 µg/L 61.2 250
Aromatic C11-C22 1 03/24/23 18:51 V31230AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene I *Limits: 40-140%03/24/23 18:511 AMP
MADEP-EPHSurrogate: Chlorooctadecane 66.3 Limits: 40-140%03/24/23 18:511 AMP
MADEP-EPHSurrogate: OTP Surrogate 76.1 Limits: 40-140%03/24/23 18:511 AMP
Surrogate: 2-Fluorobiphenyl 98.8 Limits: 40-140%03/24/23 18:511 AMP V31230
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V30853 03/15/23 08:00
173 µg/L 11.5 50.0Aliphatic C5-C8 1 03/15/23 14:26 V30854TBL
316 µg/L 25.8 50.0Aliphatic C9-C12 1 03/15/23 14:26 V30854TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 56 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-11
91100 Matrix:
3/13/2023 12:17
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V30853 03/15/23 08:00
32.9 J µg/L 4.02 50.0Aromatic C9-C10 1 03/15/23 14:26 V30854TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)96.0 Limits: 70-130%03/15/23 14:261 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)90.2 Limits: 70-130%03/15/23 14:261 TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 57 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-10
91101 Matrix:
3/13/2023 12:41
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 03/17/23 21:01 6200BMSA
0.002 J mg/L 0.002 0.006Lead 1 03/27/23 18:05 6010DMMR
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 58 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-10
91101 Matrix:
3/13/2023 12:41
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30983 03/17/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 03/17/23 21:01 V30984MSA
<0.180 µg/L 0.180 0.500Benzene 1 03/17/23 21:01 V30984MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 03/17/23 21:01 V30984MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 03/17/23 21:01 V30984MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 03/17/23 21:01 V30984MSA
<1.50 µg/L 1.50 5.00Bromoform 1 03/17/23 21:01 V30984MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 03/17/23 21:01 V30984MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 03/17/23 21:01 V30984MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 03/17/23 21:01 V30984MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 03/17/23 21:01 V30984MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 03/17/23 21:01 V30984MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 03/17/23 21:01 V30984MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 03/17/23 21:01 V30984MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 03/17/23 21:01 V30984MSA
0.320 J µg/L 0.220 0.500Chloroform 1 03/17/23 21:01 V30984MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 03/17/23 21:01 V30984MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 03/17/23 21:01 V30984MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 03/17/23 21:01 V30984MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 03/17/23 21:01 V30984MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 03/17/23 21:01 V30984MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 03/17/23 21:01 V30984MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 03/17/23 21:01 V30984MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 03/17/23 21:01 V30984MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 59 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-10
91101 Matrix:
3/13/2023 12:41
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30983 03/17/23 09:00
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 03/17/23 21:01 V30984MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 03/17/23 21:01 V30984MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 03/17/23 21:01 V30984MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 03/17/23 21:01 V30984MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 03/17/23 21:01 V30984MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 03/17/23 21:01 V30984MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 03/17/23 21:01 V30984MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 03/17/23 21:01 V30984MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 03/17/23 21:01 V30984MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 03/17/23 21:01 V30984MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 03/17/23 21:01 V30984MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 03/17/23 21:01 V30984MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 03/17/23 21:01 V30984MSA
<42.0 µg/L 42.0 200Ethanol 1 03/17/23 21:01 V30984MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 03/17/23 21:01 V30984MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 03/17/23 21:01 V30984MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 03/17/23 21:01 V30984MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 03/17/23 21:01 V30984MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 03/17/23 21:01 V30984MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 03/17/23 21:01 V30984MSA
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 03/17/23 21:01 V30984MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 03/17/23 21:01 V30984MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 03/17/23 21:01 V30984MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 60 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-10
91101 Matrix:
3/13/2023 12:41
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30983 03/17/23 09:00
<0.470 µg/L 0.470 1.00Naphthalene 1 03/17/23 21:01 V30984MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 03/17/23 21:01 V30984MSA
<0.220 µg/L 0.220 0.500Styrene 1 03/17/23 21:01 V30984MSA
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 03/17/23 21:01 V30984MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 03/17/23 21:01 V30984MSA
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 03/17/23 21:01 V30984MSA
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 03/17/23 21:01 V30984MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 03/17/23 21:01 V30984MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 03/17/23 21:01 V30984MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 03/17/23 21:01 V30984MSA
<0.220 µg/L 0.220 0.500Toluene 1 03/17/23 21:01 V30984MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 03/17/23 21:01 V30984MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 03/17/23 21:01 V30984MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 03/17/23 21:01 V30984MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 03/17/23 21:01 V30984MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 03/17/23 21:01 V30984MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 03/17/23 21:01 V30984MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 03/17/23 21:01 V30984MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 03/17/23 21:01 V30984MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 03/17/23 21:01 V30984MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 03/17/23 21:01 V30984MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 03/17/23 21:01 V30984MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 03/17/23 21:01 V30984MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 61 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-10
91101 Matrix:
3/13/2023 12:41
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30983 03/17/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 03/17/23 21:01 V30984MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 03/17/23 21:01 V30984
Surrogate: 4-Bromofluorobenzene 96.6 Limits: 70-130%03/17/23 21:011 MSA V30984
Surrogate: Dibromofluoromethane 88.8 Limits: 70-130%03/17/23 21:011 MSA V30984
Surrogate: 1,2-Dichloroethane - d4 88.6 Limits: 70-130%03/17/23 21:011 MSA V30984
Surrogate: Toluene-d8 99.2 Limits: 70-130%03/17/23 21:011 MSA V30984
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V30880 03/16/23 09:02
<0.303 µg/L 0.303 2.01Acenaphthene 1 03/16/23 23:35 V30970JMV
<0.298 µg/L 0.298 2.01Acenaphthylene 1 03/16/23 23:35 V30970JMV
<0.840 µg/L 0.840 2.01Anthracene 1 03/16/23 23:35 V30970JMV
<1.33 µg/L 1.33 10.1Benzidine 1 03/16/23 23:35 V30970JMV
<0.640 µg/L 0.640 2.01Benzo(a)anthracene 1 03/16/23 23:35 V30970JMV
<1.03 µg/L 1.03 2.01Benzo(a)pyrene 1 03/16/23 23:35 V30970JMV
<2.50 µg/L 2.50 5.03Benzo(b)fluoranthene 1 03/16/23 23:35 V30970JMV
<1.02 µg/L 1.02 5.03Benzo(g,h,i)perylene 1 03/16/23 23:35 V30970JMV
<2.00 µg/L 2.00 5.03Benzo(k)fluoranthene 1 03/16/23 23:35 V30970JMV
<1.11 µg/L 1.11 10.1Benzoic Acid 1 03/16/23 23:35 V30970JMV
<0.688 µg/L 0.688 5.03Benzyl alcohol 1 03/16/23 23:35 V30970JMV
<0.470 µg/L 0.470 5.03Bis(2-Chloroethoxy)methane 1 03/16/23 23:35 V30970JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 62 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-10
91101 Matrix:
3/13/2023 12:41
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V30880 03/16/23 09:02
<1.05 µg/L 1.05 5.03Bis(2-Chloroethyl)ether 1 03/16/23 23:35 V30970JMV
<1.09 µg/L 1.09 5.03Bis(2-Chloroisopropyl)ether 1 03/16/23 23:35 V30970JMV
<3.49 µg/L 3.49 10.1Bis(2-ethylhexyl)phthalate 1 03/16/23 23:35 V30970JMV
<1.12 µg/L 1.12 5.034-Bromophenyl phenyl ether 1 03/16/23 23:35 V30970JMV
<1.84 µg/L 1.84 5.03Butyl benzyl phthalate 1 03/16/23 23:35 V30970JMV
<1.19 µg/L 1.19 5.034-Chloro-3-methylphenol 1 03/16/23 23:35 V30970JMV
<7.42 µg/L 7.42 20.12-Chloronaphthalene 1 03/16/23 23:35 V30970JMV
<0.947 µg/L 0.947 10.12-Chlorophenol 1 03/16/23 23:35 V30970JMV
<1.72 µg/L 1.72 5.034-Chlorophenyl phenyl ether 1 03/16/23 23:35 V30970JMV
<0.407 µg/L 0.407 2.01Chrysene 1 03/16/23 23:35 V30970JMV
<0.436 µg/L 0.436 2.01Dibenz(a,h)anthracene 1 03/16/23 23:35 V30970JMV
<0.861 µg/L 0.861 5.03Dibenzofuran 1 03/16/23 23:35 V30970JMV
<2.01 µg/L 2.01 5.031,2-Dichlorobenzene 1 03/16/23 23:35 V30970JMV
<2.01 µg/L 2.01 5.031,3-Dichlorobenzene 1 03/16/23 23:35 V30970JMV
<2.06 µg/L 2.06 5.031,4-Dichlorobenzene 1 03/16/23 23:35 V30970JMV
<1.90 µg/L 1.90 5.033,3'-Dichlorobenzidine 1 03/16/23 23:35 V30970JMV
<1.47 µg/L 1.47 10.12,4-Dichlorophenol 1 03/16/23 23:35 V30970JMV
<0.749 µg/L 0.749 5.03Diethyl phthalate 1 03/16/23 23:35 V30970JMV
<0.944 µg/L 0.944 5.03Dimethyl phthalate 1 03/16/23 23:35 V30970JMV
<1.58 µg/L 1.58 20.12,4-Dimethylphenol 1 03/16/23 23:35 V30970JMV
<2.07 µg/L 2.07 5.03Di-n-butyl phthalate 1 03/16/23 23:35 V30970JMV
<2.09 µg/L 2.09 10.14,6-Dinitro-2-methylphenol 1 03/16/23 23:35 V30970JMV
<1.94 µg/L 1.94 10.12,4-Dinitrophenol 1 03/16/23 23:35 V30970JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 63 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-10
91101 Matrix:
3/13/2023 12:41
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V30880 03/16/23 09:02
<1.12 µg/L 1.12 5.032,4-Dinitrotoluene 1 03/16/23 23:35 V30970JMV
<0.813 µg/L 0.813 5.032,6-Dinitrotoluene 1 03/16/23 23:35 V30970JMV
<1.66 µg/L 1.66 5.03Di-n-Octyl Phthalate 1 03/16/23 23:35 V30970JMV
<0.251 µg/L 0.251 2.01Fluoranthene 1 03/16/23 23:35 V30970JMV
<0.811 µg/L 0.811 2.01Fluorene 1 03/16/23 23:35 V30970JMV
<0.984 µg/L 0.984 5.03Hexachlorobenzene 1 03/16/23 23:35 V30970JMV
<2.75 µg/L 2.75 5.03Hexachlorobutadiene 1 03/16/23 23:35 V30970JMV
<2.06 µg/L 2.06 5.03Hexachlorocyclopentadiene 1 03/16/23 23:35 V30970JMV
<1.77 µg/L 1.77 5.03Hexachloroethane 1 03/16/23 23:35 V30970JMV
<0.479 µg/L 0.479 2.01Indeno(1,2,3-cd)pyrene 1 03/16/23 23:35 V30970JMV
<0.446 µg/L 0.446 5.03Isophorone 1 03/16/23 23:35 V30970JMV
<0.731 µg/L 0.731 2.01Naphthalene 1 03/16/23 23:35 V30970JMV
<0.910 µg/L 0.910 5.03Nitrobenzene 1 03/16/23 23:35 V30970JMV
<0.495 µg/L 0.495 5.032-Nitrophenol 1 03/16/23 23:35 V30970JMV
<1.24 µg/L 1.24 10.14-Nitrophenol 1 03/16/23 23:35 V30970JMV
<1.11 µg/L 1.11 5.03N-Nitrosodiphenylamine 1 03/16/23 23:35 V30970JMV
<0.644 µg/L 0.644 5.03N-Nitroso-di-n-propylamine 1 03/16/23 23:35 V30970JMV
<1.44 µg/L 1.44 5.03Pentachlorophenol 1 03/16/23 23:35 V30970JMV
<0.430 µg/L 0.430 2.01Phenanthrene 1 03/16/23 23:35 V30970JMV
<0.654 µg/L 0.654 5.03Phenol 1 03/16/23 23:35 V30970JMV
<0.436 µg/L 0.436 2.01Pyrene 1 03/16/23 23:35 V30970JMV
<2.22 µg/L 2.22 5.031,2,4-Trichlorobenzene 1 03/16/23 23:35 V30970JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 64 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-10
91101 Matrix:
3/13/2023 12:41
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V30880 03/16/23 09:02
<1.33 µg/L 1.33 5.032,4,6-Trichlorophenol 1 03/16/23 23:35 V30970JMV
625.1Surrogate: Phenol-d5 41.8 Limits: 10-63%03/16/23 23:351 JMV
Surrogate: 2-Fluorobiphenyl 121 *Limits: 49-118%03/16/23 23:351 JMV V30970
Surrogate: 2-Fluorophenol 61.5 Limits: 22-84%03/16/23 23:351 JMV V30970
Surrogate: Nitrobenzene-d5 109 Limits: 43-123%03/16/23 23:351 JMV V30970
Surrogate: 4-Terphenyl-d14 148 Limits: 49-151%03/16/23 23:351 JMV V30970
Surrogate: 2,4,6-Tribromophenol 130 Limits: 31-144%03/16/23 23:351 JMV V30970
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V30967 03/20/23 13:44
<0.00342 µg/L 0.00342 0.02071,2-Dibromoethane 1 03/20/23 17:40 V31002AMP
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 65 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-10
91101 Matrix:
3/13/2023 12:41
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 03/15/23 12:51
<25.8 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 03/15/23 12:51
<4.02 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 03/15/23 12:51
<68.8 µg/L 68.8 281Aromatic C11-C22 (Adjusted)1 03/16/23 23:35
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V30918 03/17/23 10:35
<31.7 µg/L 31.7 393Aliphatic C9-C18 1 03/20/23 12:48 V30950AMP
<139 µg/L 139 562Aliphatic C19-C36 1 03/20/23 12:48 V30950AMP
<68.8 µg/L 68.8 281
Aromatic C11-C22 1 03/20/23 12:48 V30950AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene 121 Limits: 40-140%03/20/23 12:481 AMP
MADEP-EPHSurrogate: Chlorooctadecane 71.3 Limits: 40-140%03/20/23 12:481 AMP
MADEP-EPHSurrogate: OTP Surrogate 93.4 Limits: 40-140%03/20/23 12:481 AMP
Surrogate: 2-Fluorobiphenyl 124 Limits: 40-140%03/20/23 12:481 AMP V30950
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V30853 03/15/23 08:00
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 03/15/23 12:51 V30854TBL
<25.8 µg/L 25.8 50.0Aliphatic C9-C12 1 03/15/23 12:51 V30854TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 66 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-10
91101 Matrix:
3/13/2023 12:41
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V30853 03/15/23 08:00
<4.02 µg/L 4.02 50.0Aromatic C9-C10 1 03/15/23 12:51 V30854TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)96.5 Limits: 70-130%03/15/23 12:511 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)91.0 Limits: 70-130%03/15/23 12:511 TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 67 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:Trip Blank
91102 Matrix:
3/13/2023 8:08
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30983 03/17/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 03/17/23 16:02 V30984MSA
<0.180 µg/L 0.180 0.500Benzene 1 03/17/23 16:02 V30984MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 03/17/23 16:02 V30984MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 03/17/23 16:02 V30984MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 03/17/23 16:02 V30984MSA
<1.50 µg/L 1.50 5.00Bromoform 1 03/17/23 16:02 V30984MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 03/17/23 16:02 V30984MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 03/17/23 16:02 V30984MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 03/17/23 16:02 V30984MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 03/17/23 16:02 V30984MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 03/17/23 16:02 V30984MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 03/17/23 16:02 V30984MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 03/17/23 16:02 V30984MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 03/17/23 16:02 V30984MSA
<0.220 µg/L 0.220 0.500Chloroform 1 03/17/23 16:02 V30984MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 03/17/23 16:02 V30984MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 03/17/23 16:02 V30984MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 03/17/23 16:02 V30984MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 03/17/23 16:02 V30984MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 03/17/23 16:02 V30984MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 03/17/23 16:02 V30984MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 03/17/23 16:02 V30984MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 03/17/23 16:02 V30984MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 68 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:Trip Blank
91102 Matrix:
3/13/2023 8:08
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30983 03/17/23 09:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 03/17/23 16:02 V30984MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 03/17/23 16:02 V30984MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 03/17/23 16:02 V30984MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 03/17/23 16:02 V30984MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 03/17/23 16:02 V30984MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 03/17/23 16:02 V30984MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 03/17/23 16:02 V30984MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 03/17/23 16:02 V30984MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 03/17/23 16:02 V30984MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 03/17/23 16:02 V30984MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 03/17/23 16:02 V30984MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 03/17/23 16:02 V30984MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 03/17/23 16:02 V30984MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 03/17/23 16:02 V30984MSA
<42.0 µg/L 42.0 200Ethanol 1 03/17/23 16:02 V30984MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 03/17/23 16:02 V30984MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 03/17/23 16:02 V30984MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 03/17/23 16:02 V30984MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 03/17/23 16:02 V30984MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 03/17/23 16:02 V30984MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 03/17/23 16:02 V30984MSA
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 03/17/23 16:02 V30984MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 03/17/23 16:02 V30984MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 69 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:Trip Blank
91102 Matrix:
3/13/2023 8:08
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30983 03/17/23 09:00
<0.330 µg/L 0.330 2.00Methylene Chloride 1 03/17/23 16:02 V30984MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 03/17/23 16:02 V30984MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 03/17/23 16:02 V30984MSA
<0.220 µg/L 0.220 0.500Styrene 1 03/17/23 16:02 V30984MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 03/17/23 16:02 V30984MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 03/17/23 16:02 V30984MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 03/17/23 16:02 V30984MSA
<0.220 µg/L 0.220 0.500Toluene 1 03/17/23 16:02 V30984MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 03/17/23 16:02 V30984MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 03/17/23 16:02 V30984MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 03/17/23 16:02 V30984MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 03/17/23 16:02 V30984MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 03/17/23 16:02 V30984MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 03/17/23 16:02 V30984MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 03/17/23 16:02 V30984MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 03/17/23 16:02 V30984MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 03/17/23 16:02 V30984MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 03/17/23 16:02 V30984MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 03/17/23 16:02 V30984MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 03/17/23 16:02 V30984MSA
<0.420 µg/L 0.420 1.00m,p-Xylene 1 03/17/23 16:02 V30984MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 70 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:Trip Blank
91102 Matrix:
3/13/2023 8:08
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30983 03/17/23 09:00
<0.21 µg/L 0.210 0.500Xylene (Total)1 03/17/23 16:02 V30984
Surrogate: 4-Bromofluorobenzene 97.0 Limits: 70-130%03/17/23 16:021 MSA V30984
Surrogate: Dibromofluoromethane 88.0 Limits: 70-130%03/17/23 16:021 MSA V30984
Surrogate: 1,2-Dichloroethane - d4 89.6 Limits: 70-130%03/17/23 16:021 MSA V30984
Surrogate: Toluene-d8 98.6 Limits: 70-130%03/17/23 16:021 MSA V30984
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 71 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-9
91103 Matrix:
3/13/2023 13:04
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0 1003,3-Dimethyl-1-butanol 10 03/17/23 22:50 6200BMSA
0.002 J mg/L 0.002 0.006Lead 1 03/27/23 18:09 6010DMMR
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 72 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-9
91103 Matrix:
3/13/2023 13:04
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30983 03/17/23 09:00
<18.0 µg/L 18.0 100Acetone 10 03/17/23 22:50 V30984MSA
9.26 µg/L 1.80 5.00Benzene 10 03/17/23 22:50 V30984MSA
<2.10 µg/L 2.10 5.00Bromobenzene 10 03/17/23 22:50 V30984MSA
<4.20 µg/L 4.20 10.0Bromochloromethane 10 03/17/23 22:50 V30984MSA
<1.60 µg/L 1.60 5.00Bromodichloromethane 10 03/17/23 22:50 V30984MSA
<15.0 µg/L 15.0 50.0Bromoform 10 03/17/23 22:50 V30984MSA
<2.80 µg/L 2.80 10.0Bromomethane 10 03/17/23 22:50 V30984MSA
4.29 J µg/L 1.80 5.00n-Butylbenzene 10 03/17/23 22:50 V30984MSA
3.60 J µg/L 2.00 5.00sec-Butyl benzene 10 03/17/23 22:50 V30984MSA
<9.20 µg/L 9.20 20.0tert-Butyl benzene 10 03/17/23 22:50 V30984MSA
<1.80 µg/L 1.80 5.00Carbon Tetrachloride 10 03/17/23 22:50 V30984MSA
<1.90 µg/L 1.90 5.00Chlorobenzene 10 03/17/23 22:50 V30984MSA
<1.90 µg/L 1.90 5.00Chlorodibromomethane 10 03/17/23 22:50 V30984MSA
<4.30 µg/L 4.30 10.0Chloroethane 10 03/17/23 22:50 V30984MSA
<2.20 µg/L 2.20 5.00Chloroform 10 03/17/23 22:50 V30984MSA
<2.20 µg/L 2.20 5.00Chloromethane 10 03/17/23 22:50 V30984MSA
<2.00 µg/L 2.00 5.002-Chlorotoluene 10 03/17/23 22:50 V30984MSA
<2.00 µg/L 2.00 5.004-Chlorotoluene 10 03/17/23 22:50 V30984MSA
<5.00 µg/L 5.00 5.00Di-Isopropyl Ether (DIPE)10 03/17/23 22:50 V30984MSA
<11.0 µg/L 11.0 20.01,2-Dibromo-3-Chloropropane 10 03/17/23 22:50 V30984MSA
<2.30 µg/L 2.30 5.00Dibromomethane 10 03/17/23 22:50 V30984MSA
<2.20 µg/L 2.20 5.001,2-Dichlorobenzene 10 03/17/23 22:50 V30984MSA
<1.90 µg/L 1.90 5.001,3-Dichlorobenzene 10 03/17/23 22:50 V30984MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 73 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-9
91103 Matrix:
3/13/2023 13:04
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30983 03/17/23 09:00
<2.10 µg/L 2.10 5.001,4-Dichlorobenzene 10 03/17/23 22:50 V30984MSA
<12.0 µg/L 12.0 50.0Dichlorodifluoromethane 10 03/17/23 22:50 V30984MSA
<2.40 µg/L 2.40 5.001,1-Dichloroethane 10 03/17/23 22:50 V30984MSA
<1.50 µg/L 1.50 5.001,2-Dichloroethane 10 03/17/23 22:50 V30984MSA
<1.50 µg/L 1.50 5.001,1-Dichloroethene 10 03/17/23 22:50 V30984MSA
<2.00 µg/L 2.00 5.00cis-1,2-Dichloroethene 10 03/17/23 22:50 V30984MSA
<1.80 µg/L 1.80 5.00trans-1,2-Dichloroethene 10 03/17/23 22:50 V30984MSA
<1.90 µg/L 1.90 5.001,2-Dichloropropane 10 03/17/23 22:50 V30984MSA
<1.30 µg/L 1.30 5.001,3-Dichloropropane 10 03/17/23 22:50 V30984MSA
<2.10 µg/L 2.10 20.02,2-Dichloropropane 10 03/17/23 22:50 V30984MSA
<2.00 µg/L 2.00 5.001,1-Dichloropropene 10 03/17/23 22:50 V30984MSA
<2.10 µg/L 2.10 5.00cis-1,3-Dichloropropene 10 03/17/23 22:50 V30984MSA
<1.50 µg/L 1.50 5.00trans-1,3-Dichloropropene 10 03/17/23 22:50 V30984MSA
<420 µg/L 420 2000Ethanol 10 03/17/23 22:50 V30984MSA
103 µg/L 1.70 5.00Ethylbenzene 10 03/17/23 22:50 V30984MSA
<3.50 µg/L 3.50 30.0Hexachlorobutadiene 10 03/17/23 22:50 V30984MSA
<3.80 µg/L 3.80 10.02-Hexanone 10 03/17/23 22:50 V30984MSA
16.9 µg/L 1.80 5.00Isopropylbenzene 10 03/17/23 22:50 V30984MSA
<0.890 µg/L 0.890 5.004-Isopropyl toluene 10 03/17/23 22:50 V30984MSA
<7.10 µg/L 7.10 50.0Methyl Ethyl Ketone (MEK)10 03/17/23 22:50 V30984MSA
<1.40 µg/L 1.40 10.0Methyl tert-butyl ether (MTBE)10 03/17/23 22:50 V30984MSA
<0.780 µg/L 0.780 10.04-Methyl-2-Pentanone 10 03/17/23 22:50 V30984MSA
<3.30 µg/L 3.30 20.0Methylene Chloride 10 03/17/23 22:50 V30984MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 74 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-9
91103 Matrix:
3/13/2023 13:04
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30983 03/17/23 09:00
52.7 µg/L 4.70 10.0Naphthalene 10 03/17/23 22:50 V30984MSA
45.5 µg/L 1.90 5.00n-Propylbenzene 10 03/17/23 22:50 V30984MSA
<2.20 µg/L 2.20 5.00Styrene 10 03/17/23 22:50 V30984MSA
<16.0 µg/L 16.0 100tert-Butyl Alcohol (TBA)10 03/17/23 22:50 V30984MSA
<3.50 µg/L 3.50 100tert-Butyl formate (TBF)10 03/17/23 22:50 V30984MSA
<19.0 µg/L 19.0 100tert-Amyl Alcohol (TAA)10 03/17/23 22:50 V30984MSA
<2.80 µg/L 2.80 100tert-Amyl Methyl Ether (TAME)10 03/17/23 22:50 V30984MSA
<1.60 µg/L 1.60 5.001,1,1,2-Tetrachloroethane 10 03/17/23 22:50 V30984MSA
<1.60 µg/L 1.60 5.001,1,2,2-Tetrachloroethane 10 03/17/23 22:50 V30984MSA
<2.20 µg/L 2.20 5.00Tetrachloroethene 10 03/17/23 22:50 V30984MSA
124 µg/L 2.20 5.00Toluene 10 03/17/23 22:50 V30984MSA
<3.80 µg/L 3.80 5.001,2,3-Trichlorobenzene 10 03/17/23 22:50 V30984MSA
<3.10 µg/L 3.10 5.001,2,4-Trichlorobenzene 10 03/17/23 22:50 V30984MSA
<1.60 µg/L 1.60 5.001,1,1-Trichloroethane 10 03/17/23 22:50 V30984MSA
<0.960 µg/L 0.960 5.001,1,2-Trichloroethane 10 03/17/23 22:50 V30984MSA
<1.80 µg/L 1.80 5.00Trichloroethene 10 03/17/23 22:50 V30984MSA
<1.80 µg/L 1.80 5.00Trichlorofluoromethane 10 03/17/23 22:50 V30984MSA
<2.70 µg/L 2.70 5.001,2,3-Trichloropropane 10 03/17/23 22:50 V30984MSA
91.0 µg/L 1.90 5.001,2,4-Trimethylbenzene 10 03/17/23 22:50 V30984MSA
62.2 µg/L 1.80 5.001,3,5-Trimethylbenzene 10 03/17/23 22:50 V30984MSA
<10.0 µg/L 10.0 50.0Vinyl Acetate 10 03/17/23 22:50 V30984MSA
<1.70 µg/L 1.70 5.00Vinyl Chloride 10 03/17/23 22:50 V30984MSA
77.1 µg/L 2.10 5.00o-Xylene 10 03/17/23 22:50 V30984MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 75 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-9
91103 Matrix:
3/13/2023 13:04
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30983 03/17/23 09:00
221 µg/L 4.20 10.0m,p-Xylene 10 03/17/23 22:50 V30984MSA
298 µg/L 2.10 5.00Xylene (Total)10 03/17/23 22:50 V30984
Surrogate: 4-Bromofluorobenzene 95.8 Limits: 70-130%03/17/23 22:5010 MSA V30984
Surrogate: Dibromofluoromethane 85.8 Limits: 70-130%03/17/23 22:5010 MSA V30984
Surrogate: 1,2-Dichloroethane - d4 89.2 Limits: 70-130%03/17/23 22:5010 MSA V30984
Surrogate: Toluene-d8 99.0 Limits: 70-130%03/17/23 22:5010 MSA V30984
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V30880 03/16/23 09:02
<0.303 µg/L 0.303 2.01Acenaphthene 1 03/16/23 23:58 V30970JMV
<0.298 µg/L 0.298 2.01Acenaphthylene 1 03/16/23 23:58 V30970JMV
<0.840 µg/L 0.840 2.01Anthracene 1 03/16/23 23:58 V30970JMV
<1.33 µg/L 1.33 10.1Benzidine 1 03/16/23 23:58 V30970JMV
<0.640 µg/L 0.640 2.01Benzo(a)anthracene 1 03/16/23 23:58 V30970JMV
<1.03 µg/L 1.03 2.01Benzo(a)pyrene 1 03/16/23 23:58 V30970JMV
<2.50 µg/L 2.50 5.03Benzo(b)fluoranthene 1 03/16/23 23:58 V30970JMV
<1.02 µg/L 1.02 5.03Benzo(g,h,i)perylene 1 03/16/23 23:58 V30970JMV
<2.00 µg/L 2.00 5.03Benzo(k)fluoranthene 1 03/16/23 23:58 V30970JMV
<1.11 µg/L 1.11 10.1Benzoic Acid 1 03/16/23 23:58 V30970JMV
<0.688 µg/L 0.688 5.03Benzyl alcohol 1 03/16/23 23:58 V30970JMV
<0.470 µg/L 0.470 5.03Bis(2-Chloroethoxy)methane 1 03/16/23 23:58 V30970JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 76 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-9
91103 Matrix:
3/13/2023 13:04
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V30880 03/16/23 09:02
<1.05 µg/L 1.05 5.03Bis(2-Chloroethyl)ether 1 03/16/23 23:58 V30970JMV
<1.09 µg/L 1.09 5.03Bis(2-Chloroisopropyl)ether 1 03/16/23 23:58 V30970JMV
<3.49 µg/L 3.49 10.1Bis(2-ethylhexyl)phthalate 1 03/16/23 23:58 V30970JMV
<1.12 µg/L 1.12 5.034-Bromophenyl phenyl ether 1 03/16/23 23:58 V30970JMV
<1.84 µg/L 1.84 5.03Butyl benzyl phthalate 1 03/16/23 23:58 V30970JMV
<1.19 µg/L 1.19 5.034-Chloro-3-methylphenol 1 03/16/23 23:58 V30970JMV
<7.42 µg/L 7.42 20.12-Chloronaphthalene 1 03/16/23 23:58 V30970JMV
<0.947 µg/L 0.947 10.12-Chlorophenol 1 03/16/23 23:58 V30970JMV
<1.72 µg/L 1.72 5.034-Chlorophenyl phenyl ether 1 03/16/23 23:58 V30970JMV
<0.407 µg/L 0.407 2.01Chrysene 1 03/16/23 23:58 V30970JMV
<0.436 µg/L 0.436 2.01Dibenz(a,h)anthracene 1 03/16/23 23:58 V30970JMV
<0.861 µg/L 0.861 5.03Dibenzofuran 1 03/16/23 23:58 V30970JMV
<2.01 µg/L 2.01 5.031,2-Dichlorobenzene 1 03/16/23 23:58 V30970JMV
<2.01 µg/L 2.01 5.031,3-Dichlorobenzene 1 03/16/23 23:58 V30970JMV
<2.06 µg/L 2.06 5.031,4-Dichlorobenzene 1 03/16/23 23:58 V30970JMV
<1.90 µg/L 1.90 5.033,3'-Dichlorobenzidine 1 03/16/23 23:58 V30970JMV
<1.47 µg/L 1.47 10.12,4-Dichlorophenol 1 03/16/23 23:58 V30970JMV
<0.749 µg/L 0.749 5.03Diethyl phthalate 1 03/16/23 23:58 V30970JMV
<0.944 µg/L 0.944 5.03Dimethyl phthalate 1 03/16/23 23:58 V30970JMV
<1.58 µg/L 1.58 20.12,4-Dimethylphenol 1 03/16/23 23:58 V30970JMV
<2.07 µg/L 2.07 5.03Di-n-butyl phthalate 1 03/16/23 23:58 V30970JMV
<2.09 µg/L 2.09 10.14,6-Dinitro-2-methylphenol 1 03/16/23 23:58 V30970JMV
<1.94 µg/L 1.94 10.12,4-Dinitrophenol 1 03/16/23 23:58 V30970JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 77 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-9
91103 Matrix:
3/13/2023 13:04
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V30880 03/16/23 09:02
<1.12 µg/L 1.12 5.032,4-Dinitrotoluene 1 03/16/23 23:58 V30970JMV
<0.813 µg/L 0.813 5.032,6-Dinitrotoluene 1 03/16/23 23:58 V30970JMV
<1.66 µg/L 1.66 5.03Di-n-Octyl Phthalate 1 03/16/23 23:58 V30970JMV
<0.251 µg/L 0.251 2.01Fluoranthene 1 03/16/23 23:58 V30970JMV
<0.811 µg/L 0.811 2.01Fluorene 1 03/16/23 23:58 V30970JMV
<0.984 µg/L 0.984 5.03Hexachlorobenzene 1 03/16/23 23:58 V30970JMV
<2.75 µg/L 2.75 5.03Hexachlorobutadiene 1 03/16/23 23:58 V30970JMV
<2.06 µg/L 2.06 5.03Hexachlorocyclopentadiene 1 03/16/23 23:58 V30970JMV
<1.77 µg/L 1.77 5.03Hexachloroethane 1 03/16/23 23:58 V30970JMV
<0.479 µg/L 0.479 2.01Indeno(1,2,3-cd)pyrene 1 03/16/23 23:58 V30970JMV
<0.446 µg/L 0.446 5.03Isophorone 1 03/16/23 23:58 V30970JMV
28.6 µg/L 0.731 2.01Naphthalene 1 03/16/23 23:58 V30970JMV
<0.910 µg/L 0.910 5.03Nitrobenzene 1 03/16/23 23:58 V30970JMV
<0.495 µg/L 0.495 5.032-Nitrophenol 1 03/16/23 23:58 V30970JMV
<1.24 µg/L 1.24 10.14-Nitrophenol 1 03/16/23 23:58 V30970JMV
<1.11 µg/L 1.11 5.03N-Nitrosodiphenylamine 1 03/16/23 23:58 V30970JMV
<0.644 µg/L 0.644 5.03N-Nitroso-di-n-propylamine 1 03/16/23 23:58 V30970JMV
<1.44 µg/L 1.44 5.03Pentachlorophenol 1 03/16/23 23:58 V30970JMV
1.30 J µg/L 0.430 2.01Phenanthrene 1 03/16/23 23:58 V30970JMV
<0.654 µg/L 0.654 5.03Phenol 1 03/16/23 23:58 V30970JMV
<0.436 µg/L 0.436 2.01Pyrene 1 03/16/23 23:58 V30970JMV
<2.22 µg/L 2.22 5.031,2,4-Trichlorobenzene 1 03/16/23 23:58 V30970JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 78 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-9
91103 Matrix:
3/13/2023 13:04
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V30880 03/16/23 09:02
<1.33 µg/L 1.33 5.032,4,6-Trichlorophenol 1 03/16/23 23:58 V30970JMV
625.1Surrogate: Phenol-d5 25.0 Limits: 10-63%03/16/23 23:581 JMV
Surrogate: 2-Fluorobiphenyl 67.8 Limits: 49-118%03/16/23 23:581 JMV V30970
Surrogate: 2-Fluorophenol 36.3 Limits: 22-84%03/16/23 23:581 JMV V30970
Surrogate: Nitrobenzene-d5 58.3 Limits: 43-123%03/16/23 23:581 JMV V30970
Surrogate: 4-Terphenyl-d14 79.5 Limits: 49-151%03/16/23 23:581 JMV V30970
Surrogate: 2,4,6-Tribromophenol 72.3 Limits: 31-144%03/16/23 23:581 JMV V30970
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V30967 03/20/23 13:44
0.0167 J µg/L 0.00343 0.02081,2-Dibromoethane 1 03/20/23 17:58 V31002AMP
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 79 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-9
91103 Matrix:
3/13/2023 13:04
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
1040 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 03/15/23 13:15
54.9 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 03/15/23 13:15
644 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 03/15/23 13:15
62.8 J µg/L 61.2 250Aromatic C11-C22 (Adjusted)1 03/16/23 23:58
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V31110 03/23/23 10:25
<28.2 µg/L 28.2 350Aliphatic C9-C18 1 03/24/23 19:27 V31230AMP
<124 µg/L 124 500Aliphatic C19-C36 1 03/24/23 19:27 V31230AMP
92.7 J
µg/L 61.2 250
Aromatic C11-C22 1 03/24/23 19:27 V31230AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene I *Limits: 40-140%03/24/23 19:271 AMP
MADEP-EPHSurrogate: Chlorooctadecane 58.1 Limits: 40-140%03/24/23 19:271 AMP
MADEP-EPHSurrogate: OTP Surrogate 67.1 Limits: 40-140%03/24/23 19:271 AMP
Surrogate: 2-Fluorobiphenyl 97.3 Limits: 40-140%03/24/23 19:271 AMP V31230
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V30853 03/15/23 08:00
1170 µg/L 11.5 50.0Aliphatic C5-C8 1 03/15/23 13:15 V30854TBL
1100 µg/L 25.8 50.0Aliphatic C9-C12 1 03/15/23 13:15 V30854TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 80 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-9
91103 Matrix:
3/13/2023 13:04
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V30853 03/15/23 08:00
644 µg/L 4.02 50.0Aromatic C9-C10 1 03/15/23 13:15 V30854TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)95.7 Limits: 70-130%03/15/23 13:151 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)89.6 Limits: 70-130%03/15/23 13:151 TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 81 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-8
91104 Matrix:
3/13/2023 13:27
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 03/17/23 20:07 6200BMSA
<0.002 mg/L 0.002 0.006Lead 1 03/27/23 18:14 6010DMMR
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 82 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-8
91104 Matrix:
3/13/2023 13:27
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30983 03/17/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 03/17/23 20:07 V30984MSA
0.626 µg/L 0.180 0.500Benzene 1 03/17/23 20:07 V30984MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 03/17/23 20:07 V30984MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 03/17/23 20:07 V30984MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 03/17/23 20:07 V30984MSA
<1.50 µg/L 1.50 5.00Bromoform 1 03/17/23 20:07 V30984MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 03/17/23 20:07 V30984MSA
0.242 J µg/L 0.180 0.500n-Butylbenzene 1 03/17/23 20:07 V30984MSA
0.345 J µg/L 0.200 0.500sec-Butyl benzene 1 03/17/23 20:07 V30984MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 03/17/23 20:07 V30984MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 03/17/23 20:07 V30984MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 03/17/23 20:07 V30984MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 03/17/23 20:07 V30984MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 03/17/23 20:07 V30984MSA
<0.220 µg/L 0.220 0.500Chloroform 1 03/17/23 20:07 V30984MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 03/17/23 20:07 V30984MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 03/17/23 20:07 V30984MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 03/17/23 20:07 V30984MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 03/17/23 20:07 V30984MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 03/17/23 20:07 V30984MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 03/17/23 20:07 V30984MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 03/17/23 20:07 V30984MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 03/17/23 20:07 V30984MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 83 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-8
91104 Matrix:
3/13/2023 13:27
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30983 03/17/23 09:00
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 03/17/23 20:07 V30984MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 03/17/23 20:07 V30984MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 03/17/23 20:07 V30984MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 03/17/23 20:07 V30984MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 03/17/23 20:07 V30984MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 03/17/23 20:07 V30984MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 03/17/23 20:07 V30984MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 03/17/23 20:07 V30984MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 03/17/23 20:07 V30984MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 03/17/23 20:07 V30984MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 03/17/23 20:07 V30984MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 03/17/23 20:07 V30984MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 03/17/23 20:07 V30984MSA
<42.0 µg/L 42.0 200Ethanol 1 03/17/23 20:07 V30984MSA
2.51 µg/L 0.170 0.500Ethylbenzene 1 03/17/23 20:07 V30984MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 03/17/23 20:07 V30984MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 03/17/23 20:07 V30984MSA
0.752 µg/L 0.180 0.500Isopropylbenzene 1 03/17/23 20:07 V30984MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 03/17/23 20:07 V30984MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 03/17/23 20:07 V30984MSA
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 03/17/23 20:07 V30984MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 03/17/23 20:07 V30984MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 03/17/23 20:07 V30984MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 84 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-8
91104 Matrix:
3/13/2023 13:27
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30983 03/17/23 09:00
0.618 J µg/L 0.470 1.00Naphthalene 1 03/17/23 20:07 V30984MSA
1.77 µg/L 0.190 0.500n-Propylbenzene 1 03/17/23 20:07 V30984MSA
<0.220 µg/L 0.220 0.500Styrene 1 03/17/23 20:07 V30984MSA
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 03/17/23 20:07 V30984MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 03/17/23 20:07 V30984MSA
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 03/17/23 20:07 V30984MSA
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 03/17/23 20:07 V30984MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 03/17/23 20:07 V30984MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 03/17/23 20:07 V30984MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 03/17/23 20:07 V30984MSA
5.68 µg/L 0.220 0.500Toluene 1 03/17/23 20:07 V30984MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 03/17/23 20:07 V30984MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 03/17/23 20:07 V30984MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 03/17/23 20:07 V30984MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 03/17/23 20:07 V30984MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 03/17/23 20:07 V30984MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 03/17/23 20:07 V30984MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 03/17/23 20:07 V30984MSA
3.67 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 03/17/23 20:07 V30984MSA
1.27 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 03/17/23 20:07 V30984MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 03/17/23 20:07 V30984MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 03/17/23 20:07 V30984MSA
2.44 µg/L 0.210 0.500o-Xylene 1 03/17/23 20:07 V30984MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 85 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-8
91104 Matrix:
3/13/2023 13:27
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30983 03/17/23 09:00
6.15 µg/L 0.420 1.00m,p-Xylene 1 03/17/23 20:07 V30984MSA
8.59 µg/L 0.210 0.500Xylene (Total)1 03/17/23 20:07 V30984
Surrogate: 4-Bromofluorobenzene 97.6 Limits: 70-130%03/17/23 20:071 MSA V30984
Surrogate: Dibromofluoromethane 87.0 Limits: 70-130%03/17/23 20:071 MSA V30984
Surrogate: 1,2-Dichloroethane - d4 89.4 Limits: 70-130%03/17/23 20:071 MSA V30984
Surrogate: Toluene-d8 98.6 Limits: 70-130%03/17/23 20:071 MSA V30984
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V30880 03/16/23 09:02
<0.333 µg/L 0.333 2.21Acenaphthene 1 03/17/23 00:20 V30970JMV
<0.328 µg/L 0.328 2.21Acenaphthylene 1 03/17/23 00:20 V30970JMV
<0.923 µg/L 0.923 2.21Anthracene 1 03/17/23 00:20 V30970JMV
<1.45 µg/L 1.45 11.0Benzidine 1 03/17/23 00:20 V30970JMV
<0.703 µg/L 0.703 2.21Benzo(a)anthracene 1 03/17/23 00:20 V30970JMV
<1.13 µg/L 1.13 2.21Benzo(a)pyrene 1 03/17/23 00:20 V30970JMV
<2.75 µg/L 2.75 5.52Benzo(b)fluoranthene 1 03/17/23 00:20 V30970JMV
<1.12 µg/L 1.12 5.52Benzo(g,h,i)perylene 1 03/17/23 00:20 V30970JMV
<2.20 µg/L 2.20 5.52Benzo(k)fluoranthene 1 03/17/23 00:20 V30970JMV
<1.21 µg/L 1.21 11.0Benzoic Acid 1 03/17/23 00:20 V30970JMV
<0.755 µg/L 0.755 5.52Benzyl alcohol 1 03/17/23 00:20 V30970JMV
<0.516 µg/L 0.516 5.52Bis(2-Chloroethoxy)methane 1 03/17/23 00:20 V30970JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 86 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-8
91104 Matrix:
3/13/2023 13:27
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V30880 03/16/23 09:02
<1.15 µg/L 1.15 5.52Bis(2-Chloroethyl)ether 1 03/17/23 00:20 V30970JMV
<1.19 µg/L 1.19 5.52Bis(2-Chloroisopropyl)ether 1 03/17/23 00:20 V30970JMV
<3.81 µg/L 3.81 11.0Bis(2-ethylhexyl)phthalate 1 03/17/23 00:20 V30970JMV
<1.23 µg/L 1.23 5.524-Bromophenyl phenyl ether 1 03/17/23 00:20 V30970JMV
<2.02 µg/L 2.02 5.52Butyl benzyl phthalate 1 03/17/23 00:20 V30970JMV
<1.30 µg/L 1.30 5.524-Chloro-3-methylphenol 1 03/17/23 00:20 V30970JMV
<8.15 µg/L 8.15 22.12-Chloronaphthalene 1 03/17/23 00:20 V30970JMV
<1.03 µg/L 1.03 11.02-Chlorophenol 1 03/17/23 00:20 V30970JMV
<1.89 µg/L 1.89 5.524-Chlorophenyl phenyl ether 1 03/17/23 00:20 V30970JMV
<0.447 µg/L 0.447 2.21Chrysene 1 03/17/23 00:20 V30970JMV
<0.479 µg/L 0.479 2.21Dibenz(a,h)anthracene 1 03/17/23 00:20 V30970JMV
<0.945 µg/L 0.945 5.52Dibenzofuran 1 03/17/23 00:20 V30970JMV
<2.21 µg/L 2.21 5.521,2-Dichlorobenzene 1 03/17/23 00:20 V30970JMV
<2.21 µg/L 2.21 5.521,3-Dichlorobenzene 1 03/17/23 00:20 V30970JMV
<2.26 µg/L 2.26 5.521,4-Dichlorobenzene 1 03/17/23 00:20 V30970JMV
<2.09 µg/L 2.09 5.523,3'-Dichlorobenzidine 1 03/17/23 00:20 V30970JMV
<1.61 µg/L 1.61 11.02,4-Dichlorophenol 1 03/17/23 00:20 V30970JMV
<0.822 µg/L 0.822 5.52Diethyl phthalate 1 03/17/23 00:20 V30970JMV
<1.04 µg/L 1.04 5.52Dimethyl phthalate 1 03/17/23 00:20 V30970JMV
<1.73 µg/L 1.73 22.12,4-Dimethylphenol 1 03/17/23 00:20 V30970JMV
<2.27 µg/L 2.27 5.52Di-n-butyl phthalate 1 03/17/23 00:20 V30970JMV
<2.28 µg/L 2.28 11.04,6-Dinitro-2-methylphenol 1 03/17/23 00:20 V30970JMV
<2.11 µg/L 2.11 11.02,4-Dinitrophenol 1 03/17/23 00:20 V30970JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 87 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-8
91104 Matrix:
3/13/2023 13:27
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V30880 03/16/23 09:02
<1.23 µg/L 1.23 5.522,4-Dinitrotoluene 1 03/17/23 00:20 V30970JMV
<0.893 µg/L 0.893 5.522,6-Dinitrotoluene 1 03/17/23 00:20 V30970JMV
<1.82 µg/L 1.82 5.52Di-n-Octyl Phthalate 1 03/17/23 00:20 V30970JMV
<0.276 µg/L 0.276 2.21Fluoranthene 1 03/17/23 00:20 V30970JMV
<0.891 µg/L 0.891 2.21Fluorene 1 03/17/23 00:20 V30970JMV
<1.08 µg/L 1.08 5.52Hexachlorobenzene 1 03/17/23 00:20 V30970JMV
<3.01 µg/L 3.01 5.52Hexachlorobutadiene 1 03/17/23 00:20 V30970JMV
<2.26 µg/L 2.26 5.52Hexachlorocyclopentadiene 1 03/17/23 00:20 V30970JMV
<1.94 µg/L 1.94 5.52Hexachloroethane 1 03/17/23 00:20 V30970JMV
<0.527 µg/L 0.527 2.21Indeno(1,2,3-cd)pyrene 1 03/17/23 00:20 V30970JMV
<0.490 µg/L 0.490 5.52Isophorone 1 03/17/23 00:20 V30970JMV
<0.804 µg/L 0.804 2.21Naphthalene 1 03/17/23 00:20 V30970JMV
<0.999 µg/L 0.999 5.52Nitrobenzene 1 03/17/23 00:20 V30970JMV
<0.544 µg/L 0.544 5.522-Nitrophenol 1 03/17/23 00:20 V30970JMV
<1.35 µg/L 1.35 11.04-Nitrophenol 1 03/17/23 00:20 V30970JMV
<1.21 µg/L 1.21 5.52N-Nitrosodiphenylamine 1 03/17/23 00:20 V30970JMV
<0.707 µg/L 0.707 5.52N-Nitroso-di-n-propylamine 1 03/17/23 00:20 V30970JMV
<1.58 µg/L 1.58 5.52Pentachlorophenol 1 03/17/23 00:20 V30970JMV
<0.472 µg/L 0.472 2.21Phenanthrene 1 03/17/23 00:20 V30970JMV
<0.718 µg/L 0.718 5.52Phenol 1 03/17/23 00:20 V30970JMV
<0.479 µg/L 0.479 2.21Pyrene 1 03/17/23 00:20 V30970JMV
<2.44 µg/L 2.44 5.521,2,4-Trichlorobenzene 1 03/17/23 00:20 V30970JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 88 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-8
91104 Matrix:
3/13/2023 13:27
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V30880 03/16/23 09:02
<1.46 µg/L 1.46 5.522,4,6-Trichlorophenol 1 03/17/23 00:20 V30970JMV
625.1Surrogate: Phenol-d5 26.4 Limits: 10-63%03/17/23 00:201 JMV
Surrogate: 2-Fluorobiphenyl 71.4 Limits: 49-118%03/17/23 00:201 JMV V30970
Surrogate: 2-Fluorophenol 39.5 Limits: 22-84%03/17/23 00:201 JMV V30970
Surrogate: Nitrobenzene-d5 64.5 Limits: 43-123%03/17/23 00:201 JMV V30970
Surrogate: 4-Terphenyl-d14 81.0 Limits: 49-151%03/17/23 00:201 JMV V30970
Surrogate: 2,4,6-Tribromophenol 71.6 Limits: 31-144%03/17/23 00:201 JMV V30970
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V30967 03/20/23 13:44
<0.00342 µg/L 0.00342 0.02071,2-Dibromoethane 1 03/20/23 18:15 V31002AMP
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 89 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-8
91104 Matrix:
3/13/2023 13:27
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
329 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 03/15/23 13:39
42.2 J µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 03/15/23 13:39
9.45 J µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 03/15/23 13:39
<66.6 µg/L 66.6 272Aromatic C11-C22 (Adjusted)1 03/17/23 00:20
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V30918 03/17/23 10:35
<30.6 µg/L 30.6 380Aliphatic C9-C18 1 03/20/23 14:42 V30950AMP
<135 µg/L 135 543Aliphatic C19-C36 1 03/20/23 14:42 V30950AMP
<66.6 µg/L 66.6 272
Aromatic C11-C22 1 03/20/23 14:42 V30950AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene 122 Limits: 40-140%03/20/23 14:421 AMP
MADEP-EPHSurrogate: Chlorooctadecane 61.1 Limits: 40-140%03/20/23 14:421 AMP
MADEP-EPHSurrogate: OTP Surrogate 87.4 Limits: 40-140%03/20/23 14:421 AMP
Surrogate: 2-Fluorobiphenyl 122 Limits: 40-140%03/20/23 14:421 AMP V30950
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V30853 03/15/23 08:00
335 µg/L 11.5 50.0Aliphatic C5-C8 1 03/15/23 13:39 V30854TBL
62.7 µg/L 25.8 50.0Aliphatic C9-C12 1 03/15/23 13:39 V30854TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 90 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-8
91104 Matrix:
3/13/2023 13:27
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V30853 03/15/23 08:00
9.45 J µg/L 4.02 50.0Aromatic C9-C10 1 03/15/23 13:39 V30854TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)85.2 Limits: 70-130%03/15/23 13:391 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)79.2 Limits: 70-130%03/15/23 13:391 TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 91 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-7
91105 Matrix:
3/13/2023 13:50
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 03/17/23 20:34 6200BMSA
0.009 mg/L 0.002 0.006Lead 1 03/29/23 18:00 6010DMMR
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 92 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-7
91105 Matrix:
3/13/2023 13:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30983 03/17/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 03/17/23 20:34 V30984MSA
0.954 µg/L 0.180 0.500Benzene 1 03/17/23 20:34 V30984MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 03/17/23 20:34 V30984MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 03/17/23 20:34 V30984MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 03/17/23 20:34 V30984MSA
<1.50 µg/L 1.50 5.00Bromoform 1 03/17/23 20:34 V30984MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 03/17/23 20:34 V30984MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 03/17/23 20:34 V30984MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 03/17/23 20:34 V30984MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 03/17/23 20:34 V30984MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 03/17/23 20:34 V30984MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 03/17/23 20:34 V30984MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 03/17/23 20:34 V30984MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 03/17/23 20:34 V30984MSA
<0.220 µg/L 0.220 0.500Chloroform 1 03/17/23 20:34 V30984MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 03/17/23 20:34 V30984MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 03/17/23 20:34 V30984MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 03/17/23 20:34 V30984MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 03/17/23 20:34 V30984MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 03/17/23 20:34 V30984MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 03/17/23 20:34 V30984MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 03/17/23 20:34 V30984MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 03/17/23 20:34 V30984MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 93 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-7
91105 Matrix:
3/13/2023 13:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30983 03/17/23 09:00
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 03/17/23 20:34 V30984MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 03/17/23 20:34 V30984MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 03/17/23 20:34 V30984MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 03/17/23 20:34 V30984MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 03/17/23 20:34 V30984MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 03/17/23 20:34 V30984MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 03/17/23 20:34 V30984MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 03/17/23 20:34 V30984MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 03/17/23 20:34 V30984MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 03/17/23 20:34 V30984MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 03/17/23 20:34 V30984MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 03/17/23 20:34 V30984MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 03/17/23 20:34 V30984MSA
<42.0 µg/L 42.0 200Ethanol 1 03/17/23 20:34 V30984MSA
0.925 µg/L 0.170 0.500Ethylbenzene 1 03/17/23 20:34 V30984MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 03/17/23 20:34 V30984MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 03/17/23 20:34 V30984MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 03/17/23 20:34 V30984MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 03/17/23 20:34 V30984MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 03/17/23 20:34 V30984MSA
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 03/17/23 20:34 V30984MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 03/17/23 20:34 V30984MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 03/17/23 20:34 V30984MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 94 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-7
91105 Matrix:
3/13/2023 13:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30983 03/17/23 09:00
<0.470 µg/L 0.470 1.00Naphthalene 1 03/17/23 20:34 V30984MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 03/17/23 20:34 V30984MSA
<0.220 µg/L 0.220 0.500Styrene 1 03/17/23 20:34 V30984MSA
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 03/17/23 20:34 V30984MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 03/17/23 20:34 V30984MSA
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 03/17/23 20:34 V30984MSA
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 03/17/23 20:34 V30984MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 03/17/23 20:34 V30984MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 03/17/23 20:34 V30984MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 03/17/23 20:34 V30984MSA
4.12 µg/L 0.220 0.500Toluene 1 03/17/23 20:34 V30984MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 03/17/23 20:34 V30984MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 03/17/23 20:34 V30984MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 03/17/23 20:34 V30984MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 03/17/23 20:34 V30984MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 03/17/23 20:34 V30984MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 03/17/23 20:34 V30984MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 03/17/23 20:34 V30984MSA
1.29 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 03/17/23 20:34 V30984MSA
0.385 J µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 03/17/23 20:34 V30984MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 03/17/23 20:34 V30984MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 03/17/23 20:34 V30984MSA
1.51 µg/L 0.210 0.500o-Xylene 1 03/17/23 20:34 V30984MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 95 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-7
91105 Matrix:
3/13/2023 13:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30983 03/17/23 09:00
3.66 µg/L 0.420 1.00m,p-Xylene 1 03/17/23 20:34 V30984MSA
5.17 µg/L 0.210 0.500Xylene (Total)1 03/17/23 20:34 V30984KCC
Surrogate: 4-Bromofluorobenzene 97.4 Limits: 70-130%03/17/23 20:341 MSA V30984
Surrogate: Dibromofluoromethane 88.2 Limits: 70-130%03/17/23 20:341 MSA V30984
Surrogate: 1,2-Dichloroethane - d4 89.4 Limits: 70-130%03/17/23 20:341 MSA V30984
Surrogate: Toluene-d8 97.6 Limits: 70-130%03/17/23 20:341 MSA V30984
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V30880 03/16/23 09:02
<0.305 µg/L 0.305 2.02Acenaphthene 1 03/17/23 00:43 V30970JMV
<0.299 µg/L 0.299 2.02Acenaphthylene 1 03/17/23 00:43 V30970JMV
<0.844 µg/L 0.844 2.02Anthracene 1 03/17/23 00:43 V30970JMV
<1.33 µg/L 1.33 10.1Benzidine 1 03/17/23 00:43 V30970JMV
<0.643 µg/L 0.643 2.02Benzo(a)anthracene 1 03/17/23 00:43 V30970JMV
<1.03 µg/L 1.03 2.02Benzo(a)pyrene 1 03/17/23 00:43 V30970JMV
<2.51 µg/L 2.51 5.05Benzo(b)fluoranthene 1 03/17/23 00:43 V30970JMV
<1.02 µg/L 1.02 5.05Benzo(g,h,i)perylene 1 03/17/23 00:43 V30970JMV
<2.01 µg/L 2.01 5.05Benzo(k)fluoranthene 1 03/17/23 00:43 V30970JMV
<1.11 µg/L 1.11 10.1Benzoic Acid 1 03/17/23 00:43 V30970JMV
<0.690 µg/L 0.690 5.05Benzyl alcohol 1 03/17/23 00:43 V30970JMV
<0.472 µg/L 0.472 5.05Bis(2-Chloroethoxy)methane 1 03/17/23 00:43 V30970JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 96 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-7
91105 Matrix:
3/13/2023 13:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V30880 03/16/23 09:02
<1.05 µg/L 1.05 5.05Bis(2-Chloroethyl)ether 1 03/17/23 00:43 V30970JMV
<1.09 µg/L 1.09 5.05Bis(2-Chloroisopropyl)ether 1 03/17/23 00:43 V30970JMV
<3.49 µg/L 3.49 10.1Bis(2-ethylhexyl)phthalate 1 03/17/23 00:43 V30970JMV
<1.12 µg/L 1.12 5.054-Bromophenyl phenyl ether 1 03/17/23 00:43 V30970JMV
<1.85 µg/L 1.85 5.05Butyl benzyl phthalate 1 03/17/23 00:43 V30970JMV
<1.19 µg/L 1.19 5.054-Chloro-3-methylphenol 1 03/17/23 00:43 V30970JMV
<7.45 µg/L 7.45 20.22-Chloronaphthalene 1 03/17/23 00:43 V30970JMV
<0.947 µg/L 0.947 10.12-Chlorophenol 1 03/17/23 00:43 V30970JMV
<1.73 µg/L 1.73 5.054-Chlorophenyl phenyl ether 1 03/17/23 00:43 V30970JMV
<0.409 µg/L 0.409 2.02Chrysene 1 03/17/23 00:43 V30970JMV
<0.438 µg/L 0.438 2.02Dibenz(a,h)anthracene 1 03/17/23 00:43 V30970JMV
<0.864 µg/L 0.864 5.05Dibenzofuran 1 03/17/23 00:43 V30970JMV
<2.02 µg/L 2.02 5.051,2-Dichlorobenzene 1 03/17/23 00:43 V30970JMV
<2.02 µg/L 2.02 5.051,3-Dichlorobenzene 1 03/17/23 00:43 V30970JMV
<2.07 µg/L 2.07 5.051,4-Dichlorobenzene 1 03/17/23 00:43 V30970JMV
<1.91 µg/L 1.91 5.053,3'-Dichlorobenzidine 1 03/17/23 00:43 V30970JMV
<1.47 µg/L 1.47 10.12,4-Dichlorophenol 1 03/17/23 00:43 V30970JMV
<0.752 µg/L 0.752 5.05Diethyl phthalate 1 03/17/23 00:43 V30970JMV
<0.948 µg/L 0.948 5.05Dimethyl phthalate 1 03/17/23 00:43 V30970JMV
<1.59 µg/L 1.59 20.22,4-Dimethylphenol 1 03/17/23 00:43 V30970JMV
<2.08 µg/L 2.08 5.05Di-n-butyl phthalate 1 03/17/23 00:43 V30970JMV
<2.09 µg/L 2.09 10.14,6-Dinitro-2-methylphenol 1 03/17/23 00:43 V30970JMV
<1.94 µg/L 1.94 10.12,4-Dinitrophenol 1 03/17/23 00:43 V30970JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 97 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-7
91105 Matrix:
3/13/2023 13:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V30880 03/16/23 09:02
<1.12 µg/L 1.12 5.052,4-Dinitrotoluene 1 03/17/23 00:43 V30970JMV
<0.817 µg/L 0.817 5.052,6-Dinitrotoluene 1 03/17/23 00:43 V30970JMV
<1.67 µg/L 1.67 5.05Di-n-Octyl Phthalate 1 03/17/23 00:43 V30970JMV
<0.252 µg/L 0.252 2.02Fluoranthene 1 03/17/23 00:43 V30970JMV
<0.815 µg/L 0.815 2.02Fluorene 1 03/17/23 00:43 V30970JMV
<0.988 µg/L 0.988 5.05Hexachlorobenzene 1 03/17/23 00:43 V30970JMV
<2.76 µg/L 2.76 5.05Hexachlorobutadiene 1 03/17/23 00:43 V30970JMV
<2.07 µg/L 2.07 5.05Hexachlorocyclopentadiene 1 03/17/23 00:43 V30970JMV
<1.78 µg/L 1.78 5.05Hexachloroethane 1 03/17/23 00:43 V30970JMV
<0.481 µg/L 0.481 2.02Indeno(1,2,3-cd)pyrene 1 03/17/23 00:43 V30970JMV
<0.448 µg/L 0.448 5.05Isophorone 1 03/17/23 00:43 V30970JMV
<0.735 µg/L 0.735 2.02Naphthalene 1 03/17/23 00:43 V30970JMV
<0.914 µg/L 0.914 5.05Nitrobenzene 1 03/17/23 00:43 V30970JMV
<0.497 µg/L 0.497 5.052-Nitrophenol 1 03/17/23 00:43 V30970JMV
<1.24 µg/L 1.24 10.14-Nitrophenol 1 03/17/23 00:43 V30970JMV
<1.11 µg/L 1.11 5.05N-Nitrosodiphenylamine 1 03/17/23 00:43 V30970JMV
<0.647 µg/L 0.647 5.05N-Nitroso-di-n-propylamine 1 03/17/23 00:43 V30970JMV
<1.44 µg/L 1.44 5.05Pentachlorophenol 1 03/17/23 00:43 V30970JMV
<0.432 µg/L 0.432 2.02Phenanthrene 1 03/17/23 00:43 V30970JMV
<0.657 µg/L 0.657 5.05Phenol 1 03/17/23 00:43 V30970JMV
<0.438 µg/L 0.438 2.02Pyrene 1 03/17/23 00:43 V30970JMV
<2.23 µg/L 2.23 5.051,2,4-Trichlorobenzene 1 03/17/23 00:43 V30970JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 98 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-7
91105 Matrix:
3/13/2023 13:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V30880 03/16/23 09:02
<1.33 µg/L 1.33 5.052,4,6-Trichlorophenol 1 03/17/23 00:43 V30970JMV
625.1Surrogate: Phenol-d5 28.2 Limits: 10-63%03/17/23 00:431 JMV
Surrogate: 2-Fluorobiphenyl 78.0 Limits: 49-118%03/17/23 00:431 JMV V30970
Surrogate: 2-Fluorophenol 43.5 Limits: 22-84%03/17/23 00:431 JMV V30970
Surrogate: Nitrobenzene-d5 70.9 Limits: 43-123%03/17/23 00:431 JMV V30970
Surrogate: 4-Terphenyl-d14 88.5 Limits: 49-151%03/17/23 00:431 JMV V30970
Surrogate: 2,4,6-Tribromophenol 77.8 Limits: 31-144%03/17/23 00:431 JMV V30970
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V30967 03/20/23 13:44
<0.00342 µg/L 0.00342 0.02071,2-Dibromoethane 1 03/20/23 18:33 V31002AMP
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 99 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-7
91105 Matrix:
3/13/2023 13:50
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 03/15/23 14:02
28.3 J µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 03/15/23 14:02
<4.02 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 03/15/23 14:02
<66.8 µg/L 66.8 273Aromatic C11-C22 (Adjusted)1 03/17/23 00:43
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V30918 03/17/23 10:35
<30.9 µg/L 30.9 383Aliphatic C9-C18 1 03/20/23 15:18 V30950AMP
<135 µg/L 135 546Aliphatic C19-C36 1 03/20/23 15:18 V30950AMP
<66.8 µg/L 66.8 273
Aromatic C11-C22 1 03/20/23 15:18 V30950AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene 114 Limits: 40-140%03/20/23 15:181 AMP
MADEP-EPHSurrogate: Chlorooctadecane 53.0 Limits: 40-140%03/20/23 15:181 AMP
MADEP-EPHSurrogate: OTP Surrogate 69.9 Limits: 40-140%03/20/23 15:181 AMP
Surrogate: 2-Fluorobiphenyl 115 Limits: 40-140%03/20/23 15:181 AMP V30950
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V30853 03/15/23 08:00
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 03/15/23 14:02 V30854TBL
34.4 J µg/L 25.8 50.0Aliphatic C9-C12 1 03/15/23 14:02 V30854TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 100 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-7
91105 Matrix:
3/13/2023 13:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V30853 03/15/23 08:00
<4.02 µg/L 4.02 50.0Aromatic C9-C10 1 03/15/23 14:02 V30854TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)92.0 Limits: 70-130%03/15/23 14:021 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)86.6 Limits: 70-130%03/15/23 14:021 TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 101 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-6
91106 Matrix:
3/13/2023 14:06
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0 1003,3-Dimethyl-1-butanol 10 03/17/23 18:34 6200BMSA
Surrogate: 4-Bromofluorobenzene 91.0 Limits: 70-130%03/17/23 18:3410 MSA V30982
Surrogate: Dibromofluoromethane 91.8 Limits: 70-130%03/17/23 18:3410 MSA V30982
Surrogate: 1,2-Dichloroethane - d4 81.8 Limits: 70-130%03/17/23 18:3410 MSA V30982
Surrogate: Toluene-d8 88.8 Limits: 70-130%03/17/23 18:3410 MSA V30982
Surrogate: 4-Bromofluorobenzene 96.2 Limits: 70-130%03/20/23 19:59100 MSA V31039
Surrogate: Dibromofluoromethane 95.4 Limits: 70-130%03/20/23 19:59100 MSA V31039
Surrogate: 1,2-Dichloroethane - d4 91.8 Limits: 70-130%03/20/23 19:59100 MSA V31039
Surrogate: Toluene-d8 88.2 Limits: 70-130%03/20/23 19:59100 MSA V31039
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 102 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-6
91106 Matrix:
3/13/2023 14:06
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30981 03/17/23 09:00 V31038 03/20/23 09:00
<18.0 µg/L 18.0 100Acetone 10 03/17/23 18:34 V30982MSA
50.8 µg/L 1.80 5.00Benzene 10 03/17/23 18:34 V30982MSA
<2.10 µg/L 2.10 5.00Bromobenzene 10 03/17/23 18:34 V30982MSA
<4.20 µg/L 4.20 10.0Bromochloromethane 10 03/17/23 18:34 V30982MSA
<1.60 µg/L 1.60 5.00Bromodichloromethane 10 03/17/23 18:34 V30982MSA
<15.0 µg/L 15.0 50.0Bromoform 10 03/17/23 18:34 V30982MSA
<2.80 µg/L 2.80 10.0Bromomethane 10 03/17/23 18:34 V30982MSA
<1.80 µg/L 1.80 5.00n-Butylbenzene 10 03/17/23 18:34 V30982MSA
<2.00 µg/L 2.00 5.00sec-Butyl benzene 10 03/17/23 18:34 V30982MSA
<9.20 µg/L 9.20 20.0tert-Butyl benzene 10 03/17/23 18:34 V30982MSA
<1.80 µg/L 1.80 5.00Carbon Tetrachloride 10 03/17/23 18:34 V30982MSA
<1.90 µg/L 1.90 5.00Chlorobenzene 10 03/17/23 18:34 V30982MSA
<1.90 µg/L 1.90 5.00Chlorodibromomethane 10 03/17/23 18:34 V30982MSA
<4.30 µg/L 4.30 10.0Chloroethane 10 03/17/23 18:34 V30982MSA
<2.20 µg/L 2.20 5.00Chloroform 10 03/17/23 18:34 V30982MSA
<2.20 µg/L 2.20 5.00Chloromethane 10 03/17/23 18:34 V30982MSA
<2.00 µg/L 2.00 5.002-Chlorotoluene 10 03/17/23 18:34 V30982MSA
<2.00 µg/L 2.00 5.004-Chlorotoluene 10 03/17/23 18:34 V30982MSA
<5.00 µg/L 5.00 5.00Di-Isopropyl Ether (DIPE)10 03/17/23 18:34 V30982MSA
<11.0 µg/L 11.0 20.01,2-Dibromo-3-Chloropropane 10 03/17/23 18:34 V30982MSA
<2.00 µg/L 2.00 5.001,2-Dibromoethane 10 03/17/23 18:34 V30982MSA
<2.30 µg/L 2.30 5.00Dibromomethane 10 03/17/23 18:34 V30982MSA
<2.20 µg/L 2.20 5.001,2-Dichlorobenzene 10 03/17/23 18:34 V30982MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 103 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-6
91106 Matrix:
3/13/2023 14:06
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30981 03/17/23 09:00 V31038 03/20/23 09:00
<1.90 µg/L 1.90 5.001,3-Dichlorobenzene 10 03/17/23 18:34 V30982MSA
<2.10 µg/L 2.10 5.001,4-Dichlorobenzene 10 03/17/23 18:34 V30982MSA
<12.0 µg/L 12.0 50.0Dichlorodifluoromethane 10 03/17/23 18:34 V30982MSA
<2.40 µg/L 2.40 5.001,1-Dichloroethane 10 03/17/23 18:34 V30982MSA
<1.50 µg/L 1.50 5.001,2-Dichloroethane 10 03/17/23 18:34 V30982MSA
<1.50 µg/L 1.50 5.001,1-Dichloroethene 10 03/17/23 18:34 V30982MSA
<2.00 µg/L 2.00 5.00cis-1,2-Dichloroethene 10 03/17/23 18:34 V30982MSA
<1.80 µg/L 1.80 5.00trans-1,2-Dichloroethene 10 03/17/23 18:34 V30982MSA
<1.90 µg/L 1.90 5.001,2-Dichloropropane 10 03/17/23 18:34 V30982MSA
<1.30 µg/L 1.30 5.001,3-Dichloropropane 10 03/17/23 18:34 V30982MSA
<2.10 µg/L 2.10 20.02,2-Dichloropropane 10 03/17/23 18:34 V30982MSA
<2.00 µg/L 2.00 5.001,1-Dichloropropene 10 03/17/23 18:34 V30982MSA
<2.10 µg/L 2.10 5.00cis-1,3-Dichloropropene 10 03/17/23 18:34 V30982MSA
<1.50 µg/L 1.50 5.00trans-1,3-Dichloropropene 10 03/17/23 18:34 V30982MSA
<420 µg/L 420 2000Ethanol 10 03/17/23 18:34 V30982MSA
190 µg/L 1.70 5.00Ethylbenzene 10 03/17/23 18:34 V30982MSA
<3.50 µg/L 3.50 30.0Hexachlorobutadiene 10 03/17/23 18:34 V30982MSA
<3.80 µg/L 3.80 10.02-Hexanone 10 03/17/23 18:34 V30982MSA
6.81 µg/L 1.80 5.00Isopropylbenzene 10 03/17/23 18:34 V30982MSA
<0.890 µg/L 0.890 5.004-Isopropyl toluene 10 03/17/23 18:34 V30982MSA
<7.10 µg/L 7.10 50.0Methyl Ethyl Ketone (MEK)10 03/17/23 18:34 V30982MSA
<1.40 µg/L 1.40 10.0Methyl tert-butyl ether (MTBE)10 03/17/23 18:34 V30982MSA
<0.780 µg/L 0.780 10.04-Methyl-2-Pentanone 10 03/17/23 18:34 V30982MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 104 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-6
91106 Matrix:
3/13/2023 14:06
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30981 03/17/23 09:00 V31038 03/20/23 09:00
<3.30 µg/L 3.30 20.0Methylene Chloride 10 03/17/23 18:34 V30982MSA
<4.70 µg/L 4.70 10.0Naphthalene 10 03/17/23 18:34 V30982MSA
12.1 µg/L 1.90 5.00n-Propylbenzene 10 03/17/23 18:34 V30982MSA
8.18 µg/L 2.20 5.00Styrene 10 03/17/23 18:34 V30982MSA
<16.0 µg/L 16.0 100tert-Butyl Alcohol (TBA)10 03/17/23 18:34 V30982MSA
<3.50 µg/L 3.50 100tert-Butyl formate (TBF)10 03/17/23 18:34 V30982MSA
<19.0 µg/L 19.0 100tert-Amyl Alcohol (TAA)10 03/17/23 18:34 V30982MSA
<2.80 µg/L 2.80 100tert-Amyl Methyl Ether (TAME)10 03/17/23 18:34 V30982MSA
<1.60 µg/L 1.60 5.001,1,1,2-Tetrachloroethane 10 03/17/23 18:34 V30982MSA
<1.60 µg/L 1.60 5.001,1,2,2-Tetrachloroethane 10 03/17/23 18:34 V30982MSA
<2.20 µg/L 2.20 5.00Tetrachloroethene 10 03/17/23 18:34 V30982MSA
2030 µg/L 22.0 50.0Toluene 100 03/20/23 19:59 V31039MSA
<3.80 µg/L 3.80 5.001,2,3-Trichlorobenzene 10 03/17/23 18:34 V30982MSA
<3.10 µg/L 3.10 5.001,2,4-Trichlorobenzene 10 03/17/23 18:34 V30982MSA
<1.60 µg/L 1.60 5.001,1,1-Trichloroethane 10 03/17/23 18:34 V30982MSA
<0.960 µg/L 0.960 5.001,1,2-Trichloroethane 10 03/17/23 18:34 V30982MSA
<1.80 µg/L 1.80 5.00Trichloroethene 10 03/17/23 18:34 V30982MSA
<1.80 µg/L 1.80 5.00Trichlorofluoromethane 10 03/17/23 18:34 V30982MSA
<2.70 µg/L 2.70 5.001,2,3-Trichloropropane 10 03/17/23 18:34 V30982MSA
126 µg/L 1.90 5.001,2,4-Trimethylbenzene 10 03/17/23 18:34 V30982MSA
69.0 µg/L 1.80 5.001,3,5-Trimethylbenzene 10 03/17/23 18:34 V30982MSA
<10.0 µg/L 10.0 50.0Vinyl Acetate 10 03/17/23 18:34 V30982MSA
<1.70 µg/L 1.70 5.00Vinyl Chloride 10 03/17/23 18:34 V30982MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 105 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-6
91106 Matrix:
3/13/2023 14:06
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30981 03/17/23 09:00 V31038 03/20/23 09:00
418 µg/L 2.10 5.00o-Xylene 10 03/17/23 18:34 V30982MSA
897 µg/L 4.20 10.0m,p-Xylene 10 03/17/23 18:34 V30982MSA
1320 µg/L 2.10 5.00Xylene (Total)10 03/17/23 18:34 V30982
Surrogate: 4-Bromofluorobenzene 91.0 Limits: 70-130%03/17/23 18:3410 MSA V30982
Surrogate: Dibromofluoromethane 91.8 Limits: 70-130%03/17/23 18:3410 MSA V30982
Surrogate: 1,2-Dichloroethane - d4 81.8 Limits: 70-130%03/17/23 18:3410 MSA V30982
Surrogate: Toluene-d8 88.8 Limits: 70-130%03/17/23 18:3410 MSA V30982
Surrogate: 4-Bromofluorobenzene 96.2 Limits: 70-130%03/20/23 19:59100 MSA V31039
Surrogate: Dibromofluoromethane 95.4 Limits: 70-130%03/20/23 19:59100 MSA V31039
Surrogate: 1,2-Dichloroethane - d4 91.8 Limits: 70-130%03/20/23 19:59100 MSA V31039
Surrogate: Toluene-d8 88.2 Limits: 70-130%03/20/23 19:59100 MSA V31039
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 106 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-3
91107 Matrix:
3/13/2023 14:19
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<100 µg/L 100 10003,3-Dimethyl-1-butanol 100 03/17/23 19:21 6200BMSA
Surrogate: 4-Bromofluorobenzene 93.6 Limits: 70-130%03/17/23 19:21100 MSA V30982
Surrogate: Dibromofluoromethane 91.6 Limits: 70-130%03/17/23 19:21100 MSA V30982
Surrogate: 1,2-Dichloroethane - d4 81.2 Limits: 70-130%03/17/23 19:21100 MSA V30982
Surrogate: Toluene-d8 87.6 Limits: 70-130%03/17/23 19:21100 MSA V30982
Surrogate: 4-Bromofluorobenzene 95.0 Limits: 70-130%03/21/23 23:381000 TBL V31068
Surrogate: Dibromofluoromethane 87.6 Limits: 70-130%03/21/23 23:381000 TBL V31068
Surrogate: 1,2-Dichloroethane - d4 88.0 Limits: 70-130%03/21/23 23:381000 TBL V31068
Surrogate: Toluene-d8 96.2 Limits: 70-130%03/21/23 23:381000 TBL V31068
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 107 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-3
91107 Matrix:
3/13/2023 14:19
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30981 03/17/23 09:00 V31066 03/21/23 08:00
<180 µg/L 180 1000Acetone 100 03/17/23 19:21 V30982MSA
1240 µg/L 18.0 50.0Benzene 100 03/17/23 19:21 V30982MSA
<21.0 µg/L 21.0 50.0Bromobenzene 100 03/17/23 19:21 V30982MSA
<42.0 µg/L 42.0 100Bromochloromethane 100 03/17/23 19:21 V30982MSA
115 µg/L 16.0 50.0Bromodichloromethane 100 03/17/23 19:21 V30982MSA
<150 µg/L 150 500Bromoform 100 03/17/23 19:21 V30982MSA
<28.0 µg/L 28.0 100Bromomethane 100 03/17/23 19:21 V30982MSA
<18.0 µg/L 18.0 50.0n-Butylbenzene 100 03/17/23 19:21 V30982MSA
<20.0 µg/L 20.0 50.0sec-Butyl benzene 100 03/17/23 19:21 V30982MSA
<92.0 µg/L 92.0 200tert-Butyl benzene 100 03/17/23 19:21 V30982MSA
<18.0 µg/L 18.0 50.0Carbon Tetrachloride 100 03/17/23 19:21 V30982MSA
<19.0 µg/L 19.0 50.0Chlorobenzene 100 03/17/23 19:21 V30982MSA
76.6 µg/L 19.0 50.0Chlorodibromomethane 100 03/17/23 19:21 V30982MSA
<43.0 µg/L 43.0 100Chloroethane 100 03/17/23 19:21 V30982MSA
284 µg/L 22.0 50.0Chloroform 100 03/17/23 19:21 V30982MSA
<22.0 µg/L 22.0 50.0Chloromethane 100 03/17/23 19:21 V30982MSA
<20.0 µg/L 20.0 50.02-Chlorotoluene 100 03/17/23 19:21 V30982MSA
<20.0 µg/L 20.0 50.04-Chlorotoluene 100 03/17/23 19:21 V30982MSA
<50.0 µg/L 50.0 50.0Di-Isopropyl Ether (DIPE)100 03/17/23 19:21 V30982MSA
<110 µg/L 110 2001,2-Dibromo-3-Chloropropane 100 03/17/23 19:21 V30982MSA
<20.0 µg/L 20.0 50.01,2-Dibromoethane 100 03/17/23 19:21 V30982MSA
<23.0 µg/L 23.0 50.0Dibromomethane 100 03/17/23 19:21 V30982MSA
<22.0 µg/L 22.0 50.01,2-Dichlorobenzene 100 03/17/23 19:21 V30982MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 108 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-3
91107 Matrix:
3/13/2023 14:19
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30981 03/17/23 09:00 V31066 03/21/23 08:00
<19.0 µg/L 19.0 50.01,3-Dichlorobenzene 100 03/17/23 19:21 V30982MSA
<21.0 µg/L 21.0 50.01,4-Dichlorobenzene 100 03/17/23 19:21 V30982MSA
<120 µg/L 120 500Dichlorodifluoromethane 100 03/17/23 19:21 V30982MSA
<24.0 µg/L 24.0 50.01,1-Dichloroethane 100 03/17/23 19:21 V30982MSA
<15.0 µg/L 15.0 50.01,2-Dichloroethane 100 03/17/23 19:21 V30982MSA
<15.0 µg/L 15.0 50.01,1-Dichloroethene 100 03/17/23 19:21 V30982MSA
<20.0 µg/L 20.0 50.0cis-1,2-Dichloroethene 100 03/17/23 19:21 V30982MSA
<18.0 µg/L 18.0 50.0trans-1,2-Dichloroethene 100 03/17/23 19:21 V30982MSA
<19.0 µg/L 19.0 50.01,2-Dichloropropane 100 03/17/23 19:21 V30982MSA
<13.0 µg/L 13.0 50.01,3-Dichloropropane 100 03/17/23 19:21 V30982MSA
<21.0 µg/L 21.0 2002,2-Dichloropropane 100 03/17/23 19:21 V30982MSA
<20.0 µg/L 20.0 50.01,1-Dichloropropene 100 03/17/23 19:21 V30982MSA
<21.0 µg/L 21.0 50.0cis-1,3-Dichloropropene 100 03/17/23 19:21 V30982MSA
<15.0 µg/L 15.0 50.0trans-1,3-Dichloropropene 100 03/17/23 19:21 V30982MSA
<4200 µg/L 4200 20000Ethanol 100 03/17/23 19:21 V30982MSA
1360 µg/L 17.0 50.0Ethylbenzene 100 03/17/23 19:21 V30982MSA
<35.0 µg/L 35.0 300Hexachlorobutadiene 100 03/17/23 19:21 V30982MSA
<38.0 µg/L 38.0 1002-Hexanone 100 03/17/23 19:21 V30982MSA
34.8 J µg/L 18.0 50.0Isopropylbenzene 100 03/17/23 19:21 V30982MSA
<8.90 µg/L 8.90 50.04-Isopropyl toluene 100 03/17/23 19:21 V30982MSA
<71.0 µg/L 71.0 500Methyl Ethyl Ketone (MEK)100 03/17/23 19:21 V30982MSA
<14.0 µg/L 14.0 100Methyl tert-butyl ether (MTBE)100 03/17/23 19:21 V30982MSA
<7.80 µg/L 7.80 1004-Methyl-2-Pentanone 100 03/17/23 19:21 V30982MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 109 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-3
91107 Matrix:
3/13/2023 14:19
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30981 03/17/23 09:00 V31066 03/21/23 08:00
<33.0 µg/L 33.0 200Methylene Chloride 100 03/17/23 19:21 V30982MSA
311 µg/L 47.0 100Naphthalene 100 03/17/23 19:21 V30982MSA
77.8 µg/L 19.0 50.0n-Propylbenzene 100 03/17/23 19:21 V30982MSA
<22.0 µg/L 22.0 50.0Styrene 100 03/17/23 19:21 V30982MSA
<160 µg/L 160 1000tert-Butyl Alcohol (TBA)100 03/17/23 19:21 V30982MSA
<35.0 µg/L 35.0 1000tert-Butyl formate (TBF)100 03/17/23 19:21 V30982MSA
2180 µg/L 190 1000tert-Amyl Alcohol (TAA)100 03/17/23 19:21 V30982MSA
<28.0 µg/L 28.0 1000tert-Amyl Methyl Ether (TAME)100 03/17/23 19:21 V30982MSA
<16.0 µg/L 16.0 50.01,1,1,2-Tetrachloroethane 100 03/17/23 19:21 V30982MSA
<16.0 µg/L 16.0 50.01,1,2,2-Tetrachloroethane 100 03/17/23 19:21 V30982MSA
<22.0 µg/L 22.0 50.0Tetrachloroethene 100 03/17/23 19:21 V30982MSA
10400 µg/L 220 500Toluene 1000 03/21/23 23:38 V31068TBL
<38.0 µg/L 38.0 50.01,2,3-Trichlorobenzene 100 03/17/23 19:21 V30982MSA
<31.0 µg/L 31.0 50.01,2,4-Trichlorobenzene 100 03/17/23 19:21 V30982MSA
<16.0 µg/L 16.0 50.01,1,1-Trichloroethane 100 03/17/23 19:21 V30982MSA
<9.60 µg/L 9.60 50.01,1,2-Trichloroethane 100 03/17/23 19:21 V30982MSA
<18.0 µg/L 18.0 50.0Trichloroethene 100 03/17/23 19:21 V30982MSA
<18.0 µg/L 18.0 50.0Trichlorofluoromethane 100 03/17/23 19:21 V30982MSA
<27.0 µg/L 27.0 50.01,2,3-Trichloropropane 100 03/17/23 19:21 V30982MSA
822 µg/L 19.0 50.01,2,4-Trimethylbenzene 100 03/17/23 19:21 V30982MSA
314 µg/L 18.0 50.01,3,5-Trimethylbenzene 100 03/17/23 19:21 V30982MSA
<100 µg/L 100 500Vinyl Acetate 100 03/17/23 19:21 V30982MSA
<17.0 µg/L 17.0 50.0Vinyl Chloride 100 03/17/23 19:21 V30982MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 110 of 163
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-073-0013
00087
Geological Resources, Inc.
3502 Hayes Road
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 03/14/2023
Minute Man #3
Report Date : 03/30/2023
Sample ID :
Lab No :
Sampled:MW-3
91107 Matrix:
3/13/2023 14:19
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V30981 03/17/23 09:00 V31066 03/21/23 08:00
2280 µg/L 21.0 50.0o-Xylene 100 03/17/23 19:21 V30982MSA
4660 µg/L 42.0 100m,p-Xylene 100 03/17/23 19:21 V30982MSA
6940 µg/L 21.0 50.0Xylene (Total)100 03/17/23 19:21 V30982
Surrogate: 4-Bromofluorobenzene 93.6 Limits: 70-130%03/17/23 19:21100 MSA V30982
Surrogate: Dibromofluoromethane 91.6 Limits: 70-130%03/17/23 19:21100 MSA V30982
Surrogate: 1,2-Dichloroethane - d4 81.2 Limits: 70-130%03/17/23 19:21100 MSA V30982
Surrogate: Toluene-d8 87.6 Limits: 70-130%03/17/23 19:21100 MSA V30982
Surrogate: 4-Bromofluorobenzene 95.0 Limits: 70-130%03/21/23 23:381000 TBL V31068
Surrogate: Dibromofluoromethane 87.6 Limits: 70-130%03/21/23 23:381000 TBL V31068
Surrogate: 1,2-Dichloroethane - d4 88.0 Limits: 70-130%03/21/23 23:381000 TBL V31068
Surrogate: Toluene-d8 96.2 Limits: 70-130%03/21/23 23:381000 TBL V31068
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 111 of 163
SampleID Report LabNo
LRB 23‐073‐0013 LRB‐V30880
Paramater Result Units
Dilution
Factor Method AnalysisDate/Time Analyst BatchID
Oxirane 11.3 ug/L 1 625.1 3/16/202320:13 JMV V30970
HexadecanoicAcid 10.7 ug/L 1 625.1 3/16/202320:13 JMV V30970
SampleID Report LabNo
TW‐1 23‐073‐0013 V91099
Paramater Result Units
Dilution
Factor Method AnalysisDate/Time Analyst BatchID
NoTICSReported 0 ug/L 1 625.1 3/16/202322:50 JMV V30970
SampleID Report LabNo
MW‐11 23‐073‐0013 V91100
Paramater Result Units
Dilution
Factor Method AnalysisDate/Time Analyst BatchID
Ethylbenzene 33.6 ug/L 1 625.1 3/16/202323:13 JMV V30970
DimethylBenzene 64.9 ug/L 1 625.1 3/16/202323:13 JMV V30970
TrimethylBenzene 15.1 ug/L 1 625.1 3/16/202323:13 JMV V30970
HexadecanoicAcid 16.3 ug/L 1 625.1 3/16/202323:13 JMV V30970
SampleID Report LabNo
MW‐10 23‐073‐0013 V91101
Paramater Result Units
Dilution
Factor Method AnalysisDate/Time Analyst BatchID
NoTICSReported 0 ug/L 1 625.1 3/16/202323:35 JMV V30970
Page 112 of 163
SampleID Report LabNo
MW‐9 23‐073‐0013 V91103
Paramater Result Units
Dilution
Factor Method AnalysisDate/Time Analyst BatchID
Toluene 30.8 ug/L 1 625.1 3/16/202323:58 JMV V30970
Ethylbenzene 35.6 ug/L 1 625.1 3/16/202323:58 JMV V30970
DimethylBenzene 31.7 ug/L 1 625.1 3/16/202323:58 JMV V30970
PropylBenzene 19.6 ug/L 1 625.1 3/16/202323:58 JMV V30970
EthylMethylBenzene 63.8 ug/L 1 625.1 3/16/202323:58 JMV V30970
TrimethylBenzene 43.3 ug/L 1 625.1 3/16/202323:58 JMV V30970
Indane 20 ug/L 1 625.1 3/16/202323:58 JMV V30970
SampleID Report LabNo
MW‐8 23‐073‐0013 V91104
Paramater Result Units
Dilution
Factor Method AnalysisDate/Time Analyst BatchID
NoTICSReported 0 ug/L 1 625.1 3/17/20230:20 JMV V30970
SampleID Report LabNo
MW‐7 23‐073‐0013 V91105
Paramater Result Units
Dilution
Factor Method AnalysisDate/Time Analyst BatchID
NoTICSReported 0 ug/L 1 625.1 3/17/20230:43 JMV V30970
Page 113 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Metals Analysis
6010D
V31268QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3005A
QC Prep:V30872
Associated Lab Samples: 91099, 91100, 91101, 91103, 91104, 91105
LRB-V30872 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits
03/27/23 17:160.0060.002<0.002mg/LLead
LCS-V30872Laboratory Control Sample
Parameter LCS %RecLCS
Result
Spike
Conc.Units % Rec
Limits
1000.1000.100mg/LLead 80-120
V 91100-MS-V30872 V 91100-MSD-V30872Matrix Spike & Matrix Spike Duplicate
MS ResultParameter Max
RPD
MS
%Rec
MSD
Result
MSD
SpikeConc.
MS Spike
Conc.ResultUnits %Rec
Limits
MSD
%Rec RPD
0.106 97.00.1070.1000.1000.009mg/LLead 98.0 75-125 0.9 20.0
V 91100-PDS-V30872Post Digestion Spike
Parameter Analyzed%RecoveryPDSResultUnits
03/27/23 17:4796.00.244mg/LLead
Page 1 of 47Date:03/30/2023 05:08 PM
Page 114 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V30982QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V30981
Associated Lab Samples: 91106, 91107
LRB-V30981 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/17/23 14:1010.01.80<1.80µg/LAcetone
03/17/23 14:100.5000.180<0.180µg/LBenzene
03/17/23 14:100.5000.210<0.210µg/LBromobenzene
03/17/23 14:101.000.420<0.420µg/LBromochloromethane
03/17/23 14:100.5000.160<0.160µg/LBromodichloromethane
03/17/23 14:105.001.50<1.50µg/LBromoform
03/17/23 14:101.000.280<0.280µg/LBromomethane
03/17/23 14:100.5000.180<0.180µg/Ln-Butylbenzene
03/17/23 14:100.5000.200<0.200µg/Lsec-Butyl benzene
03/17/23 14:102.000.920<0.920µg/Ltert-Butyl benzene
03/17/23 14:100.5000.180<0.180µg/LCarbon Tetrachloride
03/17/23 14:100.5000.190<0.190µg/LChlorobenzene
03/17/23 14:100.5000.190<0.190µg/LChlorodibromomethane
03/17/23 14:101.000.430<0.430µg/LChloroethane
03/17/23 14:100.5000.220<0.220µg/LChloroform
03/17/23 14:100.5000.220<0.220µg/LChloromethane
03/17/23 14:100.5000.200<0.200µg/L2-Chlorotoluene
03/17/23 14:100.5000.200<0.200µg/L4-Chlorotoluene
03/17/23 14:100.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
03/17/23 14:102.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
03/17/23 14:100.5000.200<0.200µg/L1,2-Dibromoethane
03/17/23 14:100.5000.230<0.230µg/LDibromomethane
03/17/23 14:100.5000.220<0.220µg/L1,2-Dichlorobenzene
03/17/23 14:100.5000.190<0.190µg/L1,3-Dichlorobenzene
03/17/23 14:100.5000.210<0.210µg/L1,4-Dichlorobenzene
03/17/23 14:105.001.20<1.20µg/LDichlorodifluoromethane
03/17/23 14:100.5000.240<0.240µg/L1,1-Dichloroethane
Page 2 of 47Date:03/30/2023 05:08 PM
Page 115 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V30982QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V30981
Associated Lab Samples: 91106, 91107
LRB-V30981 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/17/23 14:100.5000.150<0.150µg/L1,2-Dichloroethane
03/17/23 14:100.5000.150<0.150µg/L1,1-Dichloroethene
03/17/23 14:100.5000.200<0.200µg/Lcis-1,2-Dichloroethene
03/17/23 14:100.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
03/17/23 14:100.5000.190<0.190µg/L1,2-Dichloropropane
03/17/23 14:100.5000.130<0.130µg/L1,3-Dichloropropane
03/17/23 14:102.000.210<0.210µg/L2,2-Dichloropropane
03/17/23 14:100.5000.200<0.200µg/L1,1-Dichloropropene
03/17/23 14:100.5000.210<0.210µg/Lcis-1,3-Dichloropropene
03/17/23 14:100.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
03/17/23 14:1020042.0<42.0µg/LEthanol
03/17/23 14:100.5000.170<0.170µg/LEthylbenzene
03/17/23 14:103.000.350<0.350µg/LHexachlorobutadiene
03/17/23 14:101.000.380<0.380µg/L2-Hexanone
03/17/23 14:100.5000.180<0.180µg/LIsopropylbenzene
03/17/23 14:100.5000.089<0.089µg/L4-Isopropyl toluene
03/17/23 14:105.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
03/17/23 14:101.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
03/17/23 14:101.000.078<0.078µg/L4-Methyl-2-Pentanone
03/17/23 14:102.000.330<0.330µg/LMethylene Chloride
03/17/23 14:101.000.470<0.470µg/LNaphthalene
03/17/23 14:100.5000.190<0.190µg/Ln-Propylbenzene
03/17/23 14:100.5000.220<0.220µg/LStyrene
03/17/23 14:1010.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
03/17/23 14:1010.00.350<0.350µg/Ltert-Butyl formate (TBF)
03/17/23 14:1010.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
03/17/23 14:1010.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
Page 3 of 47Date:03/30/2023 05:08 PM
Page 116 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V30982QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V30981
Associated Lab Samples: 91106, 91107
LRB-V30981 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/17/23 14:100.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
03/17/23 14:100.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
03/17/23 14:100.5000.220<0.220µg/LTetrachloroethene
03/17/23 14:100.5000.380<0.380µg/L1,2,3-Trichlorobenzene
03/17/23 14:100.5000.310<0.310µg/L1,2,4-Trichlorobenzene
03/17/23 14:100.5000.160<0.160µg/L1,1,1-Trichloroethane
03/17/23 14:100.5000.096<0.096µg/L1,1,2-Trichloroethane
03/17/23 14:100.5000.180<0.180µg/LTrichloroethene
03/17/23 14:100.5000.180<0.180µg/LTrichlorofluoromethane
03/17/23 14:100.5000.270<0.270µg/L1,2,3-Trichloropropane
03/17/23 14:100.5000.190<0.190µg/L1,2,4-Trimethylbenzene
03/17/23 14:100.5000.180<0.180µg/L1,3,5-Trimethylbenzene
03/17/23 14:105.001.00<1.00µg/LVinyl Acetate
03/17/23 14:100.5000.170<0.170µg/LVinyl Chloride
03/17/23 14:100.5000.210<0.210µg/Lo-Xylene
03/17/23 14:101.000.420<0.420µg/Lm,p-Xylene
03/17/23 14:1010.01.00<1.00µg/L3,3-Dimethyl-1-butanol
03/17/23 14:104-Bromofluorobenzene (S)93.0 70-130
03/17/23 14:10Dibromofluoromethane (S)91.2 70-130
03/17/23 14:101,2-Dichloroethane - d4 (S)82.6 70-130
03/17/23 14:10Toluene-d8 (S)90.0 70-130
LCS-V30981 LCSD-V30981Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
29.4 73.568.227.340.0µg/LAcetone 40-160 7.4 20.0
Page 4 of 47Date:03/30/2023 05:08 PM
Page 117 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V30982QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V30981
LCS-V30981 LCSD-V30981Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
22.3 11211422.820.0µg/LBenzene 70-130 2.2 20.0
18.7 93.592.018.420.0µg/LBromobenzene 70-130 1.6 20.0
22.9 11511522.920.0µg/LBromochloromethane 70-130 0.0 20.0
22.0 11010921.720.0µg/LBromodichloromethane 70-130 1.3 20.0
20.0 10010320.620.0µg/LBromoform 70-130 2.9 20.0
19.8 99.098.019.620.0µg/LBromomethane 60-140 1.0 20.0
19.6 98.010020.020.0µg/Ln-Butylbenzene 70-130 2.0 20.0
18.6 93.094.518.920.0µg/Lsec-Butyl benzene 70-130 1.6 20.0
18.1 90.591.018.220.0µg/Ltert-Butyl benzene 70-130 0.5 20.0
23.5 11812023.920.0µg/LCarbon Tetrachloride 70-130 1.6 20.0
20.3 10210621.120.0µg/LChlorobenzene 70-130 3.8 20.0
19.9 99.596.519.320.0µg/LChlorodibromomethane 70-130 3.0 20.0
25.3 12713326.620.0µg/LChloroethane 60-140 5.0 20.0
22.0 11011122.120.0µg/LChloroform 70-130 0.4 20.0
18.7 93.589.017.820.0µg/LChloromethane 60-140 4.9 20.0
18.0 90.089.517.920.0µg/L2-Chlorotoluene 70-130 0.5 20.0
17.9 89.591.518.320.0µg/L4-Chlorotoluene 70-130 2.2 20.0
21.9 11011021.920.0µg/LDi-Isopropyl Ether (DIPE)70-130 0.0 20.0
20.0 10094.018.820.0µg/L1,2-Dibromo-3-Chloropropane 70-130 6.1 20.0
20.3 10296.019.220.0µg/L1,2-Dibromoethane 70-130 5.5 20.0
22.7 11411422.720.0µg/LDibromomethane 70-130 0.0 20.0
18.7 93.593.518.720.0µg/L1,2-Dichlorobenzene 70-130 0.0 20.0
18.7 93.594.018.820.0µg/L1,3-Dichlorobenzene 70-130 0.5 20.0
18.0 90.090.018.020.0µg/L1,4-Dichlorobenzene 70-130 0.0 20.0
19.3 96.510120.220.0µg/LDichlorodifluoromethane 60-140 4.5 20.0
21.6 10811022.020.0µg/L1,1-Dichloroethane 70-130 1.8 20.0
Page 5 of 47Date:03/30/2023 05:08 PM
Page 118 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V30982QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V30981
LCS-V30981 LCSD-V30981Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
21.4 10710521.020.0µg/L1,2-Dichloroethane 70-130 1.8 20.0
22.6 11312524.920.0µg/L1,1-Dichloroethene 70-130 9.6 20.0
21.5 10810921.820.0µg/Lcis-1,2-Dichloroethene 70-130 1.3 20.0
21.5 10811022.020.0µg/Ltrans-1,2-Dichloroethene 70-130 2.2 20.0
22.4 11211222.420.0µg/L1,2-Dichloropropane 70-130 0.0 20.0
19.8 99.097.519.520.0µg/L1,3-Dichloropropane 70-130 1.5 20.0
24.3 12212525.020.0µg/L2,2-Dichloropropane 70-130 2.8 20.0
23.5 11812024.020.0µg/L1,1-Dichloropropene 70-130 2.1 20.0
23.0 11511222.420.0µg/Lcis-1,3-Dichloropropene 70-130 2.6 20.0
23.4 11711122.120.0µg/Ltrans-1,3-Dichloropropene 70-130 5.7 20.0
650 130138692500µg/LEthanol 60-140 6.2 20.0
19.4 97.010020.020.0µg/LEthylbenzene 70-130 3.0 20.0
19.0 95.095.019.020.0µg/LHexachlorobutadiene 70-130 0.0 20.0
17.7 88.581.516.320.0µg/L2-Hexanone 60-140 8.2 20.0
18.8 94.094.018.820.0µg/LIsopropylbenzene 70-130 0.0 20.0
19.4 97.097.519.520.0µg/L4-Isopropyl toluene 70-130 0.5 20.0
17.9 89.584.016.820.0µg/LMethyl Ethyl Ketone (MEK)60-140 6.3 20.0
22.0 11010721.320.0µg/LMethyl tert-butyl ether (MTBE)70-130 3.2 20.0
22.8 11410621.120.0µg/L4-Methyl-2-Pentanone 60-140 7.7 20.0
21.1 10610621.220.0µg/LMethylene Chloride 70-130 0.4 20.0
20.3 10293.018.620.0µg/LNaphthalene 70-130 8.7 20.0
18.4 92.092.518.520.0µg/Ln-Propylbenzene 70-130 0.5 20.0
19.4 97.010721.420.0µg/LStyrene 70-130 9.8 20.0
45.7 11411345.340.0µg/Ltert-Butyl Alcohol (TBA)40-140 0.8 20.0
26.9 13513226.420.0µg/Ltert-Amyl Alcohol (TAA)40-140 1.8 20.0
48.9 12212047.940.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 2.0 20.0
Page 6 of 47Date:03/30/2023 05:08 PM
Page 119 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V30982QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V30981
LCS-V30981 LCSD-V30981Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
19.4 97.010220.320.0µg/L1,1,1,2-Tetrachloroethane 70-130 4.5 20.0
20.4 10296.019.220.0µg/L1,1,2,2-Tetrachloroethane 70-130 6.0 20.0
20.7 10410220.320.0µg/LTetrachloroethene 70-130 1.9 20.0
20.6 10399.519.920.0µg/L1,2,3-Trichlorobenzene 70-130 3.4 20.0
20.2 10195.519.120.0µg/L1,2,4-Trichlorobenzene 70-130 5.5 20.0
21.5 10810921.820.0µg/L1,1,1-Trichloroethane 70-130 1.3 20.0
23.7 11911222.320.0µg/L1,1,2-Trichloroethane 70-130 6.0 20.0
21.8 10910821.620.0µg/LTrichloroethene 70-130 0.9 20.0
25.5 12813426.820.0µg/LTrichlorofluoromethane 60-140 4.9 20.0
19.4 97.085.017.020.0µg/L1,2,3-Trichloropropane 70-130 13.1 20.0
18.1 90.594.018.820.0µg/L1,2,4-Trimethylbenzene 70-130 3.7 20.0
18.5 92.594.018.820.0µg/L1,3,5-Trimethylbenzene 70-130 1.6 20.0
32.3 162*167*33.320.0µg/LVinyl Acetate 60-140 3.0 20.0
21.8 10911122.120.0µg/LVinyl Chloride 60-140 1.3 20.0
19.3 96.510320.520.0µg/Lo-Xylene 70-130 6.0 20.0
40.1 10010542.140.0µg/Lm,p-Xylene 70-130 4.8 20.0
23.9 12011322.620.0µg/L3,3-Dimethyl-1-butanol 70-130 5.5 20.0
97.893.24-Bromofluorobenzene (S)70-130
95.294.8Dibromofluoromethane (S)70-130
91.286.21,2-Dichloroethane - d4 (S)70-130
91.090.8Toluene-d8 (S)70-130
Page 7 of 47* QC Fail Date:03/30/2023 05:08 PM
Page 120 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V30984QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V30983
Associated Lab Samples: 91099, 91101, 91102, 91103, 91104, 91105
LRB-V30983 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/17/23 15:3510.01.80<1.80µg/LAcetone
03/17/23 15:350.5000.180<0.180µg/LBenzene
03/17/23 15:350.5000.210<0.210µg/LBromobenzene
03/17/23 15:351.000.420<0.420µg/LBromochloromethane
03/17/23 15:350.5000.160<0.160µg/LBromodichloromethane
03/17/23 15:355.001.50<1.50µg/LBromoform
03/17/23 15:351.000.280<0.280µg/LBromomethane
03/17/23 15:350.5000.180<0.180µg/Ln-Butylbenzene
03/17/23 15:350.5000.200<0.200µg/Lsec-Butyl benzene
03/17/23 15:352.000.920<0.920µg/Ltert-Butyl benzene
03/17/23 15:350.5000.180<0.180µg/LCarbon Tetrachloride
03/17/23 15:350.5000.190<0.190µg/LChlorobenzene
03/17/23 15:350.5000.190<0.190µg/LChlorodibromomethane
03/17/23 15:351.000.430<0.430µg/LChloroethane
03/17/23 15:350.5000.220<0.220µg/LChloroform
03/17/23 15:350.5000.220<0.220µg/LChloromethane
03/17/23 15:350.5000.200<0.200µg/L2-Chlorotoluene
03/17/23 15:350.5000.200<0.200µg/L4-Chlorotoluene
03/17/23 15:350.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
03/17/23 15:352.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
03/17/23 15:350.5000.200<0.200µg/L1,2-Dibromoethane
03/17/23 15:350.5000.230<0.230µg/LDibromomethane
03/17/23 15:350.5000.220<0.220µg/L1,2-Dichlorobenzene
03/17/23 15:350.5000.190<0.190µg/L1,3-Dichlorobenzene
03/17/23 15:350.5000.210<0.210µg/L1,4-Dichlorobenzene
03/17/23 15:355.001.20<1.20µg/LDichlorodifluoromethane
03/17/23 15:350.5000.240<0.240µg/L1,1-Dichloroethane
Page 8 of 47Date:03/30/2023 05:08 PM
Page 121 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V30984QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V30983
Associated Lab Samples: 91099, 91101, 91102, 91103, 91104, 91105
LRB-V30983 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/17/23 15:350.5000.150<0.150µg/L1,2-Dichloroethane
03/17/23 15:350.5000.150<0.150µg/L1,1-Dichloroethene
03/17/23 15:350.5000.200<0.200µg/Lcis-1,2-Dichloroethene
03/17/23 15:350.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
03/17/23 15:350.5000.190<0.190µg/L1,2-Dichloropropane
03/17/23 15:350.5000.130<0.130µg/L1,3-Dichloropropane
03/17/23 15:352.000.210<0.210µg/L2,2-Dichloropropane
03/17/23 15:350.5000.200<0.200µg/L1,1-Dichloropropene
03/17/23 15:350.5000.210<0.210µg/Lcis-1,3-Dichloropropene
03/17/23 15:350.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
03/17/23 15:3520042.0<42.0µg/LEthanol
03/17/23 15:350.5000.170<0.170µg/LEthylbenzene
03/17/23 15:353.000.350<0.350µg/LHexachlorobutadiene
03/17/23 15:351.000.380<0.380µg/L2-Hexanone
03/17/23 15:350.5000.180<0.180µg/LIsopropylbenzene
03/17/23 15:350.5000.089<0.089µg/L4-Isopropyl toluene
03/17/23 15:355.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
03/17/23 15:351.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
03/17/23 15:351.000.078<0.078µg/L4-Methyl-2-Pentanone
03/17/23 15:352.000.330<0.330µg/LMethylene Chloride
03/17/23 15:351.000.470<0.470µg/LNaphthalene
03/17/23 15:350.5000.190<0.190µg/Ln-Propylbenzene
03/17/23 15:350.5000.220<0.220µg/LStyrene
03/17/23 15:3510.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
03/17/23 15:3510.00.350<0.350µg/Ltert-Butyl formate (TBF)
03/17/23 15:3510.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
03/17/23 15:3510.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
Page 9 of 47Date:03/30/2023 05:08 PM
Page 122 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V30984QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V30983
Associated Lab Samples: 91099, 91101, 91102, 91103, 91104, 91105
LRB-V30983 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/17/23 15:350.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
03/17/23 15:350.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
03/17/23 15:350.5000.220<0.220µg/LTetrachloroethene
03/17/23 15:350.5000.220<0.220µg/LToluene
03/17/23 15:350.5000.380<0.380µg/L1,2,3-Trichlorobenzene
03/17/23 15:350.5000.310<0.310µg/L1,2,4-Trichlorobenzene
03/17/23 15:350.5000.160<0.160µg/L1,1,1-Trichloroethane
03/17/23 15:350.5000.096<0.096µg/L1,1,2-Trichloroethane
03/17/23 15:350.5000.180<0.180µg/LTrichloroethene
03/17/23 15:350.5000.180<0.180µg/LTrichlorofluoromethane
03/17/23 15:350.5000.270<0.270µg/L1,2,3-Trichloropropane
03/17/23 15:350.5000.190<0.190µg/L1,2,4-Trimethylbenzene
03/17/23 15:350.5000.180<0.180µg/L1,3,5-Trimethylbenzene
03/17/23 15:355.001.00<1.00µg/LVinyl Acetate
03/17/23 15:350.5000.170<0.170µg/LVinyl Chloride
03/17/23 15:350.5000.210<0.210µg/Lo-Xylene
03/17/23 15:351.000.420<0.420µg/Lm,p-Xylene
03/17/23 15:3510.01.00<1.00µg/L3,3-Dimethyl-1-butanol
03/17/23 15:354-Bromofluorobenzene (S)96.0 70-130
03/17/23 15:35Dibromofluoromethane (S)87.4 70-130
03/17/23 15:351,2-Dichloroethane - d4 (S)89.6 70-130
03/17/23 15:35Toluene-d8 (S)98.0 70-130
Page 10 of 47Date:03/30/2023 05:08 PM
Page 123 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V30984QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V30983
LCS-V30983 LCSD-V30983Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
34.4 86.086.034.440.0µg/LAcetone 40-160 0.0 20.0
16.7 83.586.517.320.0µg/LBenzene 70-130 3.5 20.0
16.1 80.582.516.520.0µg/LBromobenzene 70-130 2.4 20.0
16.7 83.587.017.420.0µg/LBromochloromethane 70-130 4.1 20.0
15.0 75.076.515.320.0µg/LBromodichloromethane 70-130 1.9 20.0
17.0 85.086.017.220.0µg/LBromoform 70-130 1.1 20.0
20.1 10110520.920.0µg/LBromomethane 60-140 3.9 20.0
14.3 71.573.014.620.0µg/Ln-Butylbenzene 70-130 2.0 20.0
14.7 73.577.015.420.0µg/Lsec-Butyl benzene 70-130 4.6 20.0
15.5 77.577.515.520.0µg/Ltert-Butyl benzene 70-130 0.0 20.0
15.0 75.080.016.020.0µg/LCarbon Tetrachloride 70-130 6.4 20.0
16.1 80.584.516.920.0µg/LChlorobenzene 70-130 4.8 20.0
17.8 89.090.018.020.0µg/LChlorodibromomethane 70-130 1.1 20.0
18.5 92.598.019.620.0µg/LChloroethane 60-140 5.7 20.0
15.5 77.578.515.720.0µg/LChloroform 70-130 1.2 20.0
17.0 85.087.017.420.0µg/LChloromethane 60-140 2.3 20.0
15.3 76.581.016.220.0µg/L2-Chlorotoluene 70-130 5.7 20.0
15.9 79.582.016.420.0µg/L4-Chlorotoluene 70-130 3.0 20.0
14.4 72.074.514.920.0µg/LDi-Isopropyl Ether (DIPE)70-130 3.4 20.0
19.2 96.094.018.820.0µg/L1,2-Dibromo-3-Chloropropane 70-130 2.1 20.0
17.3 86.587.017.420.0µg/L1,2-Dibromoethane 70-130 0.5 20.0
15.3 76.575.515.120.0µg/LDibromomethane 70-130 1.3 20.0
16.3 81.582.516.520.0µg/L1,2-Dichlorobenzene 70-130 1.2 20.0
15.7 78.582.516.520.0µg/L1,3-Dichlorobenzene 70-130 4.9 20.0
15.7 78.581.016.220.0µg/L1,4-Dichlorobenzene 70-130 3.1 20.0
18.5 92.592.018.420.0µg/LDichlorodifluoromethane 60-140 0.5 20.0
Page 11 of 47Date:03/30/2023 05:08 PM
Page 124 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V30984QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V30983
LCS-V30983 LCSD-V30983Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
15.5 77.582.516.520.0µg/L1,1-Dichloroethane 70-130 6.2 20.0
16.7 83.585.517.120.0µg/L1,2-Dichloroethane 70-130 2.3 20.0
14.9 74.578.515.720.0µg/L1,1-Dichloroethene 70-130 5.2 20.0
14.7 73.580.016.020.0µg/Lcis-1,2-Dichloroethene 70-130 8.4 20.0
15.6 78.081.016.220.0µg/Ltrans-1,2-Dichloroethene 70-130 3.7 20.0
16.6 83.084.516.920.0µg/L1,2-Dichloropropane 70-130 1.7 20.0
16.3 81.581.516.320.0µg/L1,3-Dichloropropane 70-130 0.0 20.0
16.4 82.085.517.120.0µg/L2,2-Dichloropropane 70-130 4.1 20.0
17.6 88.092.018.420.0µg/L1,1-Dichloropropene 70-130 4.4 20.0
15.2 76.078.515.720.0µg/Lcis-1,3-Dichloropropene 70-130 3.2 20.0
15.2 76.079.515.920.0µg/Ltrans-1,3-Dichloropropene 70-130 4.5 20.0
476 95.2113566500µg/LEthanol 60-140 17.2 20.0
16.2 81.084.516.920.0µg/LEthylbenzene 70-130 4.2 20.0
14.3 71.572.014.420.0µg/LHexachlorobutadiene 70-130 0.6 20.0
16.7 83.585.017.020.0µg/L2-Hexanone 60-140 1.7 20.0
16.4 82.085.017.020.0µg/LIsopropylbenzene 70-130 3.5 20.0
15.2 76.078.515.720.0µg/L4-Isopropyl toluene 70-130 3.2 20.0
14.2 71.073.514.720.0µg/LMethyl Ethyl Ketone (MEK)60-140 3.4 20.0
15.1 75.577.015.420.0µg/LMethyl tert-butyl ether (MTBE)70-130 1.9 20.0
15.3 76.575.515.120.0µg/L4-Methyl-2-Pentanone 60-140 1.3 20.0
15.7 78.586.517.320.0µg/LMethylene Chloride 70-130 9.6 20.0
18.5 92.590.518.120.0µg/LNaphthalene 70-130 2.1 20.0
15.4 77.080.016.020.0µg/Ln-Propylbenzene 70-130 3.8 20.0
16.2 81.081.516.320.0µg/LStyrene 70-130 0.6 20.0
32.6 81.581.232.540.0µg/Ltert-Butyl Alcohol (TBA)40-140 0.3 20.0
35.6 89.092.737.140.0µg/Ltert-Butyl formate (TBF)40-140 4.1 20.0
Page 12 of 47Date:03/30/2023 05:08 PM
Page 125 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V30984QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V30983
LCS-V30983 LCSD-V30983Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
13.4 67.085.017.020.0µg/Ltert-Amyl Alcohol (TAA)40-140 23.6*20.0
32.0 80.081.532.640.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 1.8 20.0
17.4 87.088.517.720.0µg/L1,1,1,2-Tetrachloroethane 70-130 1.7 20.0
19.5 97.596.519.320.0µg/L1,1,2,2-Tetrachloroethane 70-130 1.0 20.0
16.7 83.588.517.720.0µg/LTetrachloroethene 70-130 5.8 20.0
15.8 79.081.016.220.0µg/LToluene 70-130 2.5 20.0
16.8 84.091.018.220.0µg/L1,2,3-Trichlorobenzene 70-130 8.0 20.0
15.4 77.081.016.220.0µg/L1,2,4-Trichlorobenzene 70-130 5.0 20.0
16.1 80.580.016.020.0µg/L1,1,1-Trichloroethane 70-130 0.6 20.0
17.4 87.086.017.220.0µg/L1,1,2-Trichloroethane 70-130 1.1 20.0
15.8 79.079.015.820.0µg/LTrichloroethene 70-130 0.0 20.0
17.2 86.088.017.620.0µg/LTrichlorofluoromethane 60-140 2.2 20.0
17.1 85.590.018.020.0µg/L1,2,3-Trichloropropane 70-130 5.1 20.0
15.8 79.081.016.220.0µg/L1,2,4-Trimethylbenzene 70-130 2.5 20.0
15.9 79.578.515.720.0µg/L1,3,5-Trimethylbenzene 70-130 1.2 20.0
20.7 10496.519.320.0µg/LVinyl Acetate 60-140 7.0 20.0
16.8 84.087.017.420.0µg/LVinyl Chloride 60-140 3.5 20.0
16.0 80.082.016.420.0µg/Lo-Xylene 70-130 2.4 20.0
34.1 85.287.034.840.0µg/Lm,p-Xylene 70-130 2.0 20.0
15.4 77.092.018.420.0µg/L3,3-Dimethyl-1-butanol 70-130 17.7 20.0
98.298.24-Bromofluorobenzene (S)70-130
87.487.0Dibromofluoromethane (S)70-130
90.490.01,2-Dichloroethane - d4 (S)70-130
97.697.8Toluene-d8 (S)70-130
Page 13 of 47* QC Fail Date:03/30/2023 05:08 PM
Page 126 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31039QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31038
Associated Lab Samples: 91106
LRB-V31038 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/20/23 13:110.5000.220<0.220µg/LToluene
03/20/23 13:114-Bromofluorobenzene (S)94.2 70-130
03/20/23 13:11Dibromofluoromethane (S)93.2 70-130
03/20/23 13:111,2-Dichloroethane - d4 (S)85.2 70-130
03/20/23 13:11Toluene-d8 (S)84.8 70-130
LCS-V31038 LCSD-V31038Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
21.9 11011322.520.0µg/LToluene 70-130 2.7 20.0
94.094.64-Bromofluorobenzene (S)70-130
94.495.8Dibromofluoromethane (S)70-130
88.092.81,2-Dichloroethane - d4 (S)70-130
87.288.6Toluene-d8 (S)70-130
Page 14 of 47Date:03/30/2023 05:08 PM
Page 127 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31046QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31045
Associated Lab Samples: 91100
LRB-V31045 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/20/23 14:3810.01.80<1.80µg/LAcetone
03/20/23 14:380.5000.180<0.180µg/LBenzene
03/20/23 14:380.5000.210<0.210µg/LBromobenzene
03/20/23 14:381.000.420<0.420µg/LBromochloromethane
03/20/23 14:380.5000.160<0.160µg/LBromodichloromethane
03/20/23 14:385.001.50<1.50µg/LBromoform
03/20/23 14:381.000.280<0.280µg/LBromomethane
03/20/23 14:380.5000.180<0.180µg/Ln-Butylbenzene
03/20/23 14:380.5000.200<0.200µg/Lsec-Butyl benzene
03/20/23 14:382.000.920<0.920µg/Ltert-Butyl benzene
03/20/23 14:380.5000.180<0.180µg/LCarbon Tetrachloride
03/20/23 14:380.5000.190<0.190µg/LChlorobenzene
03/20/23 14:380.5000.190<0.190µg/LChlorodibromomethane
03/20/23 14:381.000.430<0.430µg/LChloroethane
03/20/23 14:380.5000.220<0.220µg/LChloroform
03/20/23 14:380.5000.220<0.220µg/LChloromethane
03/20/23 14:380.5000.200<0.200µg/L2-Chlorotoluene
03/20/23 14:380.5000.200<0.200µg/L4-Chlorotoluene
03/20/23 14:380.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
03/20/23 14:382.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
03/20/23 14:380.5000.230<0.230µg/LDibromomethane
03/20/23 14:380.5000.220<0.220µg/L1,2-Dichlorobenzene
03/20/23 14:380.5000.190<0.190µg/L1,3-Dichlorobenzene
03/20/23 14:380.5000.210<0.210µg/L1,4-Dichlorobenzene
03/20/23 14:385.001.20<1.20µg/LDichlorodifluoromethane
03/20/23 14:380.5000.240<0.240µg/L1,1-Dichloroethane
03/20/23 14:380.5000.150<0.150µg/L1,2-Dichloroethane
Page 15 of 47Date:03/30/2023 05:08 PM
Page 128 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31046QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31045
Associated Lab Samples: 91100
LRB-V31045 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/20/23 14:380.5000.150<0.150µg/L1,1-Dichloroethene
03/20/23 14:380.5000.200<0.200µg/Lcis-1,2-Dichloroethene
03/20/23 14:380.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
03/20/23 14:380.5000.190<0.190µg/L1,2-Dichloropropane
03/20/23 14:380.5000.130<0.130µg/L1,3-Dichloropropane
03/20/23 14:382.000.210<0.210µg/L2,2-Dichloropropane
03/20/23 14:380.5000.200<0.200µg/L1,1-Dichloropropene
03/20/23 14:380.5000.210<0.210µg/Lcis-1,3-Dichloropropene
03/20/23 14:380.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
03/20/23 14:3820042.0<42.0µg/LEthanol
03/20/23 14:380.5000.170<0.170µg/LEthylbenzene
03/20/23 14:383.000.350<0.350µg/LHexachlorobutadiene
03/20/23 14:381.000.380<0.380µg/L2-Hexanone
03/20/23 14:380.5000.180<0.180µg/LIsopropylbenzene
03/20/23 14:380.5000.089<0.089µg/L4-Isopropyl toluene
03/20/23 14:385.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
03/20/23 14:381.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
03/20/23 14:381.000.078<0.078µg/L4-Methyl-2-Pentanone
03/20/23 14:382.000.330<0.330µg/LMethylene Chloride
03/20/23 14:381.000.470<0.470µg/LNaphthalene
03/20/23 14:380.5000.190<0.190µg/Ln-Propylbenzene
03/20/23 14:380.5000.220<0.220µg/LStyrene
03/20/23 14:3810.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
03/20/23 14:3810.00.350<0.350µg/Ltert-Butyl formate (TBF)
03/20/23 14:3810.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
03/20/23 14:3810.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
03/20/23 14:380.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
Page 16 of 47Date:03/30/2023 05:08 PM
Page 129 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31046QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31045
Associated Lab Samples: 91100
LRB-V31045 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/20/23 14:380.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
03/20/23 14:380.5000.220<0.220µg/LTetrachloroethene
03/20/23 14:380.5000.220<0.220µg/LToluene
03/20/23 14:380.5000.380<0.380µg/L1,2,3-Trichlorobenzene
03/20/23 14:380.5000.310<0.310µg/L1,2,4-Trichlorobenzene
03/20/23 14:380.5000.160<0.160µg/L1,1,1-Trichloroethane
03/20/23 14:380.5000.096<0.096µg/L1,1,2-Trichloroethane
03/20/23 14:380.5000.180<0.180µg/LTrichloroethene
03/20/23 14:380.5000.180<0.180µg/LTrichlorofluoromethane
03/20/23 14:380.5000.270<0.270µg/L1,2,3-Trichloropropane
03/20/23 14:380.5000.190<0.190µg/L1,2,4-Trimethylbenzene
03/20/23 14:380.5000.180<0.180µg/L1,3,5-Trimethylbenzene
03/20/23 14:385.001.00<1.00µg/LVinyl Acetate
03/20/23 14:380.5000.170<0.170µg/LVinyl Chloride
03/20/23 14:380.5000.210<0.210µg/Lo-Xylene
03/20/23 14:381.000.420<0.420µg/Lm,p-Xylene
03/20/23 14:3810.01.00<1.00µg/L3,3-Dimethyl-1-butanol
03/20/23 14:384-Bromofluorobenzene (S)98.0 70-130
03/20/23 14:38Dibromofluoromethane (S)86.6 70-130
03/20/23 14:381,2-Dichloroethane - d4 (S)89.0 70-130
03/20/23 14:38Toluene-d8 (S)96.8 70-130
LCS-V31045 LCSD-V31045Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
34.1 85.287.034.840.0µg/LAcetone 40-160 2.0 20.0
Page 17 of 47Date:03/30/2023 05:08 PM
Page 130 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31046QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31045
LCS-V31045 LCSD-V31045Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
17.1 85.586.517.320.0µg/LBenzene 70-130 1.1 20.0
16.9 84.584.016.820.0µg/LBromobenzene 70-130 0.5 20.0
17.4 87.091.518.320.0µg/LBromochloromethane 70-130 5.0 20.0
15.8 79.080.016.020.0µg/LBromodichloromethane 70-130 1.2 20.0
18.2 91.093.018.620.0µg/LBromoform 70-130 2.1 20.0
21.8 10911723.320.0µg/LBromomethane 60-140 6.6 20.0
17.4 87.088.017.620.0µg/Ln-Butylbenzene 70-130 1.1 20.0
16.8 84.086.017.220.0µg/Lsec-Butyl benzene 70-130 2.3 20.0
17.6 88.087.017.420.0µg/Ltert-Butyl benzene 70-130 1.1 20.0
16.1 80.585.517.120.0µg/LCarbon Tetrachloride 70-130 6.0 20.0
17.1 85.591.518.320.0µg/LChlorobenzene 70-130 6.7 20.0
19.0 95.097.019.420.0µg/LChlorodibromomethane 70-130 2.0 20.0
19.0 95.010320.620.0µg/LChloroethane 60-140 8.0 20.0
16.1 80.581.016.220.0µg/LChloroform 70-130 0.6 20.0
18.2 91.094.018.820.0µg/LChloromethane 60-140 3.2 20.0
16.0 80.082.516.520.0µg/L2-Chlorotoluene 70-130 3.0 20.0
16.7 83.584.516.920.0µg/L4-Chlorotoluene 70-130 1.1 20.0
15.1 75.576.515.320.0µg/LDi-Isopropyl Ether (DIPE)70-130 1.3 20.0
20.2 10110120.220.0µg/L1,2-Dibromo-3-Chloropropane 70-130 0.0 20.0
16.0 80.082.016.420.0µg/LDibromomethane 70-130 2.4 20.0
17.8 89.090.018.020.0µg/L1,2-Dichlorobenzene 70-130 1.1 20.0
18.1 90.591.518.320.0µg/L1,3-Dichlorobenzene 70-130 1.0 20.0
17.5 87.588.517.720.0µg/L1,4-Dichlorobenzene 70-130 1.1 20.0
19.6 98.099.019.820.0µg/LDichlorodifluoromethane 60-140 1.0 20.0
15.8 79.082.016.420.0µg/L1,1-Dichloroethane 70-130 3.7 20.0
17.3 86.585.017.020.0µg/L1,2-Dichloroethane 70-130 1.7 20.0
Page 18 of 47Date:03/30/2023 05:08 PM
Page 131 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31046QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31045
LCS-V31045 LCSD-V31045Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
15.3 76.582.516.520.0µg/L1,1-Dichloroethene 70-130 7.5 20.0
15.4 77.078.015.620.0µg/Lcis-1,2-Dichloroethene 70-130 1.2 20.0
15.7 78.580.516.120.0µg/Ltrans-1,2-Dichloroethene 70-130 2.5 20.0
17.1 85.590.018.020.0µg/L1,2-Dichloropropane 70-130 5.1 20.0
16.4 82.084.016.820.0µg/L1,3-Dichloropropane 70-130 2.4 20.0
17.6 88.084.516.920.0µg/L2,2-Dichloropropane 70-130 4.0 20.0
17.8 89.091.018.220.0µg/L1,1-Dichloropropene 70-130 2.2 20.0
16.4 82.083.016.620.0µg/Lcis-1,3-Dichloropropene 70-130 1.2 20.0
15.9 79.583.516.720.0µg/Ltrans-1,3-Dichloropropene 70-130 4.9 20.0
477 95.491.0455500µg/LEthanol 60-140 4.7 20.0
16.8 84.088.517.720.0µg/LEthylbenzene 70-130 5.2 20.0
19.2 96.094.518.920.0µg/LHexachlorobutadiene 70-130 1.5 20.0
16.7 83.587.017.420.0µg/L2-Hexanone 60-140 4.1 20.0
17.4 87.088.017.620.0µg/LIsopropylbenzene 70-130 1.1 20.0
17.8 89.090.018.020.0µg/L4-Isopropyl toluene 70-130 1.1 20.0
18.1 90.590.518.120.0µg/LMethyl Ethyl Ketone (MEK)60-140 0.0 20.0
16.4 82.082.016.420.0µg/LMethyl tert-butyl ether (MTBE)70-130 0.0 20.0
15.9 79.580.516.120.0µg/L4-Methyl-2-Pentanone 60-140 1.2 20.0
17.1 85.586.017.220.0µg/LMethylene Chloride 70-130 0.5 20.0
20.1 10110120.220.0µg/LNaphthalene 70-130 0.4 20.0
16.9 84.585.017.020.0µg/Ln-Propylbenzene 70-130 0.5 20.0
17.8 89.091.018.220.0µg/LStyrene 70-130 2.2 20.0
36.1 90.285.034.040.0µg/Ltert-Butyl Alcohol (TBA)40-140 5.9 20.0
38.4 96.096.738.740.0µg/Ltert-Butyl formate (TBF)40-140 0.7 20.0
24.4 12210320.520.0µg/Ltert-Amyl Alcohol (TAA)40-140 17.3 20.0
34.0 85.084.533.840.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 0.5 20.0
Page 19 of 47Date:03/30/2023 05:08 PM
Page 132 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31046QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31045
LCS-V31045 LCSD-V31045Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
17.9 89.593.518.720.0µg/L1,1,1,2-Tetrachloroethane 70-130 4.3 20.0
18.9 94.593.018.620.0µg/L1,1,2,2-Tetrachloroethane 70-130 1.6 20.0
17.4 87.093.518.720.0µg/LTetrachloroethene 70-130 7.2 20.0
15.9 79.582.516.520.0µg/LToluene 70-130 3.7 20.0
20.6 10310220.320.0µg/L1,2,3-Trichlorobenzene 70-130 1.4 20.0
19.3 96.598.519.720.0µg/L1,2,4-Trichlorobenzene 70-130 2.0 20.0
15.9 79.580.516.120.0µg/L1,1,1-Trichloroethane 70-130 1.2 20.0
18.3 91.587.517.520.0µg/L1,1,2-Trichloroethane 70-130 4.4 20.0
17.0 85.085.017.020.0µg/LTrichloroethene 70-130 0.0 20.0
18.1 90.596.019.220.0µg/LTrichlorofluoromethane 60-140 5.8 20.0
18.1 90.585.517.120.0µg/L1,2,3-Trichloropropane 70-130 5.6 20.0
17.3 86.588.017.620.0µg/L1,2,4-Trimethylbenzene 70-130 1.7 20.0
17.4 87.086.017.220.0µg/L1,3,5-Trimethylbenzene 70-130 1.1 20.0
18.8 94.092.518.520.0µg/LVinyl Acetate 60-140 1.6 20.0
18.0 90.095.019.020.0µg/LVinyl Chloride 60-140 5.4 20.0
17.2 86.089.017.820.0µg/Lo-Xylene 70-130 3.4 20.0
35.3 88.291.736.740.0µg/Lm,p-Xylene 70-130 3.8 20.0
19.0 95.010621.220.0µg/L3,3-Dimethyl-1-butanol 70-130 10.9 20.0
95.894.44-Bromofluorobenzene (S)70-130
87.086.0Dibromofluoromethane (S)70-130
88.690.21,2-Dichloroethane - d4 (S)70-130
97.099.0Toluene-d8 (S)70-130
Page 20 of 47Date:03/30/2023 05:08 PM
Page 133 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31068QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31066
Associated Lab Samples: 91107
LRB-V31066 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/21/23 15:290.5000.220<0.220µg/LToluene
03/21/23 15:294-Bromofluorobenzene (S)94.6 70-130
03/21/23 15:29Dibromofluoromethane (S)86.6 70-130
03/21/23 15:291,2-Dichloroethane - d4 (S)88.4 70-130
03/21/23 15:29Toluene-d8 (S)96.0 70-130
LCS-V31066 LCSD-V31066Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
15.2 76.078.515.720.0µg/LToluene 70-130 3.2 20.0
95.495.84-Bromofluorobenzene (S)70-130
88.087.8Dibromofluoromethane (S)70-130
90.288.21,2-Dichloroethane - d4 (S)70-130
96.497.0Toluene-d8 (S)70-130
Page 21 of 47Date:03/30/2023 05:08 PM
Page 134 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V30879QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V30878
Associated Lab Samples: 91097, 91098
LRB-V30878 Matrix: SOLLab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/15/23 12:160.0200.002<0.002mg/KgAcetone
03/15/23 12:160.0200.001<0.001mg/KgAcrolein
03/15/23 12:160.0200.0008<0.0008mg/KgAcrylonitrile
03/15/23 12:160.0050.0006<0.0006mg/KgBenzene
03/15/23 12:160.0050.0005<0.0005mg/KgBromobenzene
03/15/23 12:160.0050.0008<0.0008mg/KgBromochloromethane
03/15/23 12:160.0050.001<0.001mg/KgBromodichloromethane
03/15/23 12:160.0050.001<0.001mg/KgBromoform
03/15/23 12:160.0100.001<0.001mg/KgBromomethane
03/15/23 12:160.0050.0005<0.0005mg/Kgn-Butylbenzene
03/15/23 12:160.0050.0006<0.0006mg/Kgsec-Butyl benzene
03/15/23 12:160.0050.0005<0.0005mg/Kgtert-Butyl benzene
03/15/23 12:160.0050.0006<0.0006mg/KgCarbon Disulfide
03/15/23 12:160.0050.001<0.001mg/KgCarbon Tetrachloride
03/15/23 12:160.0050.0007<0.0007mg/KgChlorobenzene
03/15/23 12:160.0050.0009<0.0009mg/KgChlorodibromomethane
03/15/23 12:160.0100.0009<0.0009mg/KgChloroethane
03/15/23 12:160.0050.001<0.001mg/KgChloroform
03/15/23 12:160.0100.0006<0.0006mg/KgChloromethane
03/15/23 12:160.0050.0005<0.0005mg/Kg2-Chlorotoluene
03/15/23 12:160.0050.0004<0.0004mg/Kg4-Chlorotoluene
03/15/23 12:160.0050.0007<0.0007mg/KgDi-Isopropyl Ether (DIPE)
03/15/23 12:160.0100.0004<0.0004mg/Kg1,2-Dibromo-3-Chloropropane
03/15/23 12:160.0050.0006<0.0006mg/Kg1,2-Dibromoethane
03/15/23 12:160.0050.0010<0.0010mg/KgDibromomethane
03/15/23 12:160.0050.0003<0.0003mg/Kg1,2-Dichlorobenzene
03/15/23 12:160.0050.0004<0.0004mg/Kg1,3-Dichlorobenzene
Page 22 of 47Date:03/30/2023 05:08 PM
Page 135 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V30879QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V30878
Associated Lab Samples: 91097, 91098
LRB-V30878 Matrix: SOLLab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/15/23 12:160.0050.0006<0.0006mg/Kg1,4-Dichlorobenzene
03/15/23 12:160.0100.001<0.001mg/KgDichlorodifluoromethane
03/15/23 12:160.0050.0008<0.0008mg/Kg1,1-Dichloroethane
03/15/23 12:160.0050.001<0.001mg/Kg1,2-Dichloroethane
03/15/23 12:160.0050.0007<0.0007mg/Kg1,1-Dichloroethene
03/15/23 12:160.0050.0008<0.0008mg/Kgcis-1,2-Dichloroethene
03/15/23 12:160.0050.001<0.001mg/Kgtrans-1,2-Dichloroethene
03/15/23 12:160.0050.0004<0.0004mg/Kg1,2-Dichloropropane
03/15/23 12:160.0050.0006<0.0006mg/Kg1,3-Dichloropropane
03/15/23 12:160.0050.001<0.001mg/Kg2,2-Dichloropropane
03/15/23 12:160.0050.0008<0.0008mg/Kg1,1-Dichloropropene
03/15/23 12:160.0050.0005<0.0005mg/Kgcis-1,3-Dichloropropene
03/15/23 12:160.0050.0008<0.0008mg/Kgtrans-1,3-Dichloropropene
03/15/23 12:160.0050.0006<0.0006mg/KgEthylbenzene
03/15/23 12:160.1000.0008<0.0008mg/KgEthyl Tertiary Butyl Ether (ETBE)
03/15/23 12:160.0100.0008<0.0008mg/KgHexachlorobutadiene
03/15/23 12:160.0100.0007<0.0007mg/Kgn-Hexane
03/15/23 12:160.0200.0006<0.0006mg/Kg2-Hexanone
03/15/23 12:160.0050.0005<0.0005mg/KgIsopropylbenzene
03/15/23 12:160.0050.001<0.001mg/Kg4-Isopropyl toluene
03/15/23 12:160.0200.0007<0.0007mg/KgMethyl Ethyl Ketone (MEK)
03/15/23 12:160.0050.0006<0.0006mg/KgMethyl tert-butyl ether (MTBE)
03/15/23 12:160.0050.0010.001mg/KgMethylene Chloride
03/15/23 12:160.0100.0010<0.0010mg/KgNaphthalene
03/15/23 12:160.0050.0005<0.0005mg/Kgn-Propylbenzene
03/15/23 12:160.0050.001<0.001mg/KgStyrene
03/15/23 12:160.0050.001<0.001mg/Kg1,1,1,2-Tetrachloroethane
Page 23 of 47Date:03/30/2023 05:08 PM
Page 136 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V30879QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V30878
Associated Lab Samples: 91097, 91098
LRB-V30878 Matrix: SOLLab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/15/23 12:160.0050.0003<0.0003mg/Kg1,1,2,2-Tetrachloroethane
03/15/23 12:160.0050.0009<0.0009mg/KgTetrachloroethene
03/15/23 12:160.0050.0007<0.0007mg/KgToluene
03/15/23 12:160.0100.0005<0.0005mg/Kg1,2,3-Trichlorobenzene
03/15/23 12:160.0100.0006<0.0006mg/Kg1,2,4-Trichlorobenzene
03/15/23 12:160.0050.001<0.001mg/Kg1,1,1-Trichloroethane
03/15/23 12:160.0050.0005<0.0005mg/Kg1,1,2-Trichloroethane
03/15/23 12:160.0050.0009<0.0009mg/KgTrichloroethene
03/15/23 12:160.0100.002<0.002mg/KgTrichlorofluoromethane
03/15/23 12:160.0050.0007<0.0007mg/Kg1,2,3-Trichloropropane
03/15/23 12:160.0050.0005<0.0005mg/Kg1,2,4-Trimethylbenzene
03/15/23 12:160.0050.0005<0.0005mg/Kg1,3,5-Trimethylbenzene
03/15/23 12:160.0100.0005<0.0005mg/KgVinyl Acetate
03/15/23 12:160.0100.0005<0.0005mg/KgVinyl Chloride
03/15/23 12:160.0050.0005<0.0005mg/Kgo-Xylene
03/15/23 12:160.0100.001<0.001mg/Kgm,p-Xylene
03/15/23 12:164-Bromofluorobenzene (S)102 70-130
03/15/23 12:16Dibromofluoromethane (S)100 70-130
03/15/23 12:16Toluene-d8 (S)96.8 76-129
LCS-V30878 LCSD-V30878Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
0.117 1171260.1260.100mg/KgAcetone 29-198 7.4 20
0.099 99.81040.1040.100mg/KgAcrolein 70-130 4.1 20
0.116 1161200.1200.100mg/KgAcrylonitrile 65-134 3.3 20
Page 24 of 47Date:03/30/2023 05:08 PM
Page 137 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V30879QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V30878
LCS-V30878 LCSD-V30878Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
0.049 98.899.80.0490.050mg/KgBenzene 74-127 1.0 20
0.044 89.891.00.0450.050mg/KgBromobenzene 73-125 1.3 20
0.052 1041050.0520.050mg/KgBromochloromethane 72-134 1.3 20
0.049 99.899.20.0490.050mg/KgBromodichloromethane 75-122 0.6 20
0.049 99.098.20.0490.050mg/KgBromoform 66-135 0.8 20
0.048 96.21010.0500.050mg/KgBromomethane 20-180 5.0 20
0.046 93.696.40.0480.050mg/Kgn-Butylbenzene 65-135 2.9 20
0.044 89.891.60.0450.050mg/Kgsec-Butyl benzene 66-131 1.9 20
0.045 91.292.20.0460.050mg/Kgtert-Butyl benzene 67-132 1.0 20
0.047 95.81000.0500.050mg/KgCarbon Disulfide 61-129 4.4 20
0.048 96.498.60.0490.050mg/KgCarbon Tetrachloride 64-143 2.2 20
0.048 97.696.40.0480.050mg/KgChlorobenzene 74-118 1.2 20
0.047 95.895.00.0470.050mg/KgChlorodibromomethane 73-122 0.8 20
0.051 1031070.0530.050mg/KgChloroethane 33-149 4.1 20
0.048 97.41010.0500.050mg/KgChloroform 73-127 3.4 20
0.049 98.01060.0520.050mg/KgChloromethane 45-143 7.6 20
0.045 91.292.60.0460.050mg/Kg2-Chlorotoluene 67-124 1.5 20
0.045 91.292.40.0460.050mg/Kg4-Chlorotoluene 71-126 1.3 20
0.049 98.697.60.0480.050mg/KgDi-Isopropyl Ether (DIPE)59-159 1.0 20
0.044 88.892.40.0460.050mg/Kg1,2-Dibromo-3-Chloropropane 55-157 3.9 20
0.049 99.41030.0510.050mg/Kg1,2-Dibromoethane 70-132 3.1 20
0.049 98.61020.0510.050mg/KgDibromomethane 74-133 3.7 20
0.048 96.094.60.0470.050mg/Kg1,2-Dichlorobenzene 72-123 1.4 20
0.047 94.096.00.0480.050mg/Kg1,3-Dichlorobenzene 71-120 2.1 20
0.045 91.293.20.0460.050mg/Kg1,4-Dichlorobenzene 71-123 2.1 20
0.046 93.097.00.0480.050mg/KgDichlorodifluoromethane 26-146 4.2 20
Page 25 of 47Date:03/30/2023 05:08 PM
Page 138 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V30879QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V30878
LCS-V30878 LCSD-V30878Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
0.049 98.499.40.0490.050mg/Kg1,1-Dichloroethane 74-127 1.0 20
0.050 10099.20.0490.050mg/Kg1,2-Dichloroethane 68-128 0.8 20
0.048 97.697.40.0480.050mg/Kg1,1-Dichloroethene 67-149 0.2 20
0.050 1021000.0500.050mg/Kgcis-1,2-Dichloroethene 76-134 1.5 20
0.049 98.01000.0500.050mg/Kgtrans-1,2-Dichloroethene 73-132 2.2 20
0.051 1031010.0500.050mg/Kg1,2-Dichloropropane 73-130 1.3 20
0.048 97.499.20.0490.050mg/Kg1,3-Dichloropropane 75-124 1.8 20
0.048 97.898.80.0490.050mg/Kg2,2-Dichloropropane 50-142 1.0 20
0.048 97.097.20.0480.050mg/Kg1,1-Dichloropropene 71-130 0.2 20
0.050 1021010.0500.050mg/Kgcis-1,3-Dichloropropene 71-125 0.5 20
0.053 1061090.0540.050mg/Kgtrans-1,3-Dichloropropene 68-123 2.5 20
0.046 92.293.20.0460.050mg/KgEthylbenzene 74-128 1.0 20
0.099 99.61010.1010.100mg/KgEthyl Tertiary Butyl Ether (ETBE)70-130 1.3 20
0.047 95.096.40.0480.050mg/KgHexachlorobutadiene 64-125 1.4 20
0.045 91.695.60.0470.050mg/Kgn-Hexane 70-130 4.2 20
0.050 1011070.0530.050mg/Kg2-Hexanone 61-157 5.3 20
0.045 90.491.60.0450.050mg/KgIsopropylbenzene 68-126 1.3 20
0.045 90.892.40.0460.050mg/Kg4-Isopropyl toluene 68-129 1.7 20
0.042 85.81020.0510.050mg/KgMethyl Ethyl Ketone (MEK)63-149 17.6 20
0.049 98.61010.0500.050mg/KgMethyl tert-butyl ether (MTBE)70-130 2.2 20
0.046 93.692.40.0460.050mg/KgMethylene Chloride 74-129 1.2 20
0.048 96.498.40.0490.050mg/KgNaphthalene 57-157 2.0 20
0.044 89.291.20.0450.050mg/Kgn-Propylbenzene 67-130 2.2 20
0.050 1011010.0500.050mg/KgStyrene 77-121 0.1 20
0.048 96.897.80.0480.050mg/Kg1,1,1,2-Tetrachloroethane 72-115 1.0 20
0.042 85.691.80.0450.050mg/Kg1,1,2,2-Tetrachloroethane 56-126 6.9 20
Page 26 of 47Date:03/30/2023 05:08 PM
Page 139 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V30879QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V30878
LCS-V30878 LCSD-V30878Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
0.050 1021010.0500.050mg/KgTetrachloroethene 68-130 0.7 20
0.048 96.498.40.0490.050mg/KgToluene 71-129 2.0 20
0.048 96.698.40.0490.050mg/Kg1,2,3-Trichlorobenzene 68-130 1.8 20
0.050 1021040.0520.050mg/Kg1,2,4-Trichlorobenzene 66-125 2.5 20
0.048 97.698.80.0490.050mg/Kg1,1,1-Trichloroethane 67-131 1.2 20
0.047 95.894.60.0470.050mg/Kg1,1,2-Trichloroethane 70-133 1.2 20
0.050 10099.80.0490.050mg/KgTrichloroethene 75-133 0.4 20
0.049 98.21050.0520.050mg/KgTrichlorofluoromethane 44-146 6.6 20
0.044 89.694.00.0470.050mg/Kg1,2,3-Trichloropropane 60-137 4.7 20
0.045 91.292.20.0460.050mg/Kg1,2,4-Trimethylbenzene 69-129 1.0 20
0.045 90.890.80.0450.050mg/Kg1,3,5-Trimethylbenzene 69-128 0.0 20
0.058 1171260.0630.050mg/KgVinyl Acetate 60-140 7.2 20
0.050 10198.80.0490.050mg/KgVinyl Chloride 48-147 2.4 20
0.047 95.095.00.0470.050mg/Kgo-Xylene 74-126 0.0 20
0.094 94.494.70.0940.100mg/Kgm,p-Xylene 75-124 0.3 20
99.299.44-Bromofluorobenzene (S)70-130
99.099.6Dibromofluoromethane (S)70-130
97.697.6Toluene-d8 (S)76-129
Page 27 of 47Date:03/30/2023 05:08 PM
Page 140 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V30970QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V30880
Associated Lab Samples: 91099, 91100, 91101, 91103, 91104, 91105
LRB-V30880 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/16/23 20:132.000.302<0.302µg/LAcenaphthene
03/16/23 20:132.000.297<0.297µg/LAcenaphthylene
03/16/23 20:132.000.836<0.836µg/LAnthracene
03/16/23 20:1310.01.32<1.32µg/LBenzidine
03/16/23 20:132.000.637<0.637µg/LBenzo(a)anthracene
03/16/23 20:132.001.02<1.02µg/LBenzo(a)pyrene
03/16/23 20:135.002.49<2.49µg/LBenzo(b)fluoranthene
03/16/23 20:135.001.01<1.01µg/LBenzo(g,h,i)perylene
03/16/23 20:135.001.99<1.99µg/LBenzo(k)fluoranthene
03/16/23 20:1310.01.10<1.10µg/LBenzoic Acid
03/16/23 20:135.000.684<0.684µg/LBenzyl alcohol
03/16/23 20:135.000.468<0.468µg/LBis(2-Chloroethoxy)methane
03/16/23 20:135.001.04<1.04µg/LBis(2-Chloroethyl)ether
03/16/23 20:135.001.08<1.08µg/LBis(2-Chloroisopropyl)ether
03/16/23 20:1310.03.46<3.46µg/LBis(2-ethylhexyl)phthalate
03/16/23 20:135.001.11<1.11µg/L4-Bromophenyl phenyl ether
03/16/23 20:135.001.83<1.83µg/LButyl benzyl phthalate
03/16/23 20:135.001.18<1.18µg/L4-Chloro-3-methylphenol
03/16/23 20:1320.07.38<7.38µg/L2-Chloronaphthalene
03/16/23 20:1310.00.938<0.938µg/L2-Chlorophenol
03/16/23 20:135.001.71<1.71µg/L4-Chlorophenyl phenyl ether
03/16/23 20:132.000.405<0.405µg/LChrysene
03/16/23 20:132.000.434<0.434µg/LDibenz(a,h)anthracene
03/16/23 20:135.000.856<0.856µg/LDibenzofuran
03/16/23 20:135.002.00<2.00µg/L1,2-Dichlorobenzene
03/16/23 20:135.002.00<2.00µg/L1,3-Dichlorobenzene
03/16/23 20:135.002.05<2.05µg/L1,4-Dichlorobenzene
Page 28 of 47Date:03/30/2023 05:08 PM
Page 141 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V30970QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V30880
Associated Lab Samples: 91099, 91100, 91101, 91103, 91104, 91105
LRB-V30880 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/16/23 20:135.001.89<1.89µg/L3,3'-Dichlorobenzidine
03/16/23 20:1310.01.46<1.46µg/L2,4-Dichlorophenol
03/16/23 20:135.000.745<0.745µg/LDiethyl phthalate
03/16/23 20:135.000.939<0.939µg/LDimethyl phthalate
03/16/23 20:1320.01.57<1.57µg/L2,4-Dimethylphenol
03/16/23 20:135.002.06<2.06µg/LDi-n-butyl phthalate
03/16/23 20:1310.02.07<2.07µg/L4,6-Dinitro-2-methylphenol
03/16/23 20:1310.01.92<1.92µg/L2,4-Dinitrophenol
03/16/23 20:135.001.11<1.11µg/L2,4-Dinitrotoluene
03/16/23 20:135.000.809<0.809µg/L2,6-Dinitrotoluene
03/16/23 20:135.001.65<1.65µg/LDi-n-Octyl Phthalate
03/16/23 20:132.000.250<0.250µg/LFluoranthene
03/16/23 20:132.000.807<0.807µg/LFluorene
03/16/23 20:135.000.979<0.979µg/LHexachlorobenzene
03/16/23 20:135.002.73<2.73µg/LHexachlorobutadiene
03/16/23 20:135.002.05<2.05µg/LHexachlorocyclopentadiene
03/16/23 20:135.001.76<1.76µg/LHexachloroethane
03/16/23 20:132.000.477<0.477µg/LIndeno(1,2,3-cd)pyrene
03/16/23 20:135.000.444<0.444µg/LIsophorone
03/16/23 20:132.000.728<0.728µg/LNaphthalene
03/16/23 20:135.000.905<0.905µg/LNitrobenzene
03/16/23 20:135.000.493<0.493µg/L2-Nitrophenol
03/16/23 20:1310.01.23<1.23µg/L4-Nitrophenol
03/16/23 20:135.001.10<1.10µg/LN-Nitrosodiphenylamine
03/16/23 20:135.000.641<0.641µg/LN-Nitroso-di-n-propylamine
03/16/23 20:135.001.43<1.43µg/LPentachlorophenol
03/16/23 20:132.000.428<0.428µg/LPhenanthrene
Page 29 of 47Date:03/30/2023 05:08 PM
Page 142 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V30970QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V30880
Associated Lab Samples: 91099, 91100, 91101, 91103, 91104, 91105
LRB-V30880 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/16/23 20:135.000.651<0.651µg/LPhenol
03/16/23 20:132.000.434<0.434µg/LPyrene
03/16/23 20:135.002.21<2.21µg/L1,2,4-Trichlorobenzene
03/16/23 20:135.001.32<1.32µg/L2,4,6-Trichlorophenol
03/16/23 20:132-Fluorobiphenyl (S)84.6 49-118
03/16/23 20:132-Fluorophenol (S)45.1 22-84
03/16/23 20:13Nitrobenzene-d5 (S)77.4 43-123
03/16/23 20:134-Terphenyl-d14 (S)102 49-151
03/16/23 20:132,4,6-Tribromophenol (S)87.9 31-144
03/16/23 20:13Phenol-d5 (S)29.4 10-63
LCS-V30880 LCSD-V30880Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
43.0 86.090.045.050.0µg/LAcenaphthene 47-145 4.5 20.0
41.9 83.887.243.650.0µg/LAcenaphthylene 33-145 3.9 20.0
47.7 95.497.248.650.0µg/LAnthracene 27-133 1.8 20.0
32.9 65.846.423.250.0µg/LBenzidine 15-150 34.5*20.0
45.5 91.091.245.650.0µg/LBenzo(a)anthracene 33-143 0.2 20.0
53.8 10810753.650.0µg/LBenzo(a)pyrene 17-163 0.3 20.0
48.7 97.498.249.150.0µg/LBenzo(b)fluoranthene 24-159 0.8 20.0
46.2 92.492.246.150.0µg/LBenzo(g,h,i)perylene 10-219 0.2 20.0
47.7 95.495.447.750.0µg/LBenzo(k)fluoranthene 11-162 0.0 20.0
14.7 29.429.014.550.0µg/LBenzoic Acid 10-125 1.3 20.0
33.8 67.671.035.550.0µg/LBenzyl alcohol 16-107 4.9 20.0
37.5 75.077.238.650.0µg/LBis(2-Chloroethoxy)methane 33-184 2.8 20.0
Page 30 of 47* QC Fail Date:03/30/2023 05:08 PM
Page 143 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V30970QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V30880
LCS-V30880 LCSD-V30880Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
34.4 68.868.834.450.0µg/LBis(2-Chloroethyl)ether 12-158 0.0 20.0
35.4 70.872.036.050.0µg/LBis(2-Chloroisopropyl)ether 36-166 1.6 20.0
49.8 99.699.649.850.0µg/LBis(2-ethylhexyl)phthalate 10-158 0.0 20.0
45.4 90.892.046.050.0µg/L4-Bromophenyl phenyl ether 53-127 1.3 20.0
50.5 10110351.450.0µg/LButyl benzyl phthalate 10-152 1.7 20.0
36.1 72.275.037.550.0µg/L4-Chloro-3-methylphenol 22-147 3.8 20.0
41.6 83.285.442.750.0µg/L2-Chloronaphthalene 60-118 2.6 20.0
32.2 64.467.833.950.0µg/L2-Chlorophenol 23-134 5.1 20.0
42.7 85.489.444.750.0µg/L4-Chlorophenyl phenyl ether 25-158 4.5 20.0
46.0 92.091.245.650.0µg/LChrysene 17-168 0.8 20.0
43.5 87.085.442.750.0µg/LDibenz(a,h)anthracene 10-227 1.8 20.0
43.2 86.489.244.650.0µg/LDibenzofuran 39-114 3.1 20.0
30.9 61.865.432.750.0µg/L1,2-Dichlorobenzene 32-129 5.6 20.0
30.8 61.663.831.950.0µg/L1,3-Dichlorobenzene 20-124 3.5 20.0
30.4 60.864.032.050.0µg/L1,4-Dichlorobenzene 20-124 5.1 20.0
39.2 78.478.639.350.0µg/L3,3'-Dichlorobenzidine 10-262 0.2 20.0
36.8 73.675.437.750.0µg/L2,4-Dichlorophenol 39-135 2.4 20.0
45.9 91.893.646.850.0µg/LDiethyl phthalate 10-114 1.9 20.0
43.6 87.291.045.550.0µg/LDimethyl phthalate 10-112 4.2 20.0
37.6 75.278.439.250.0µg/L2,4-Dimethylphenol 32-119 4.1 20.0
50.0 10010251.250.0µg/LDi-n-butyl phthalate 10-118 2.3 20.0
45.4 90.894.847.450.0µg/L4,6-Dinitro-2-methylphenol 10-181 4.3 20.0
47.4 94.897.448.750.0µg/L2,4-Dinitrophenol 10-191 2.7 20.0
45.5 91.095.047.550.0µg/L2,4-Dinitrotoluene 39-139 4.3 20.0
45.8 91.694.447.250.0µg/L2,6-Dinitrotoluene 50-158 3.0 20.0
51.5 10310452.150.0µg/LDi-n-Octyl Phthalate 10-146 1.1 20.0
Page 31 of 47Date:03/30/2023 05:08 PM
Page 144 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V30970QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V30880
LCS-V30880 LCSD-V30880Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
46.2 92.494.647.350.0µg/LFluoranthene 26-137 2.3 20.0
44.5 89.091.845.950.0µg/LFluorene 59-121 3.0 20.0
44.3 88.690.245.150.0µg/LHexachlorobenzene 10-152 1.7 20.0
32.2 64.467.633.850.0µg/LHexachlorobutadiene 24-116 4.8 20.0
34.0 68.072.036.050.0µg/LHexachlorocyclopentadiene 32-117 5.7 20.0
29.9 59.862.231.150.0µg/LHexachloroethane 40-113 3.9 20.0
45.7 91.489.644.850.0µg/LIndeno(1,2,3-cd)pyrene 10-171 1.9 20.0
37.2 74.476.838.450.0µg/LIsophorone 21-196 3.1 20.0
33.3 66.670.435.250.0µg/LNaphthalene 21-133 5.5 20.0
34.4 68.870.835.450.0µg/LNitrobenzene 35-180 2.8 20.0
34.3 68.670.635.350.0µg/L2-Nitrophenol 29-182 2.8 20.0
21.9 43.845.422.750.0µg/L4-Nitrophenol 10-132 3.5 20.0
56.2 11211557.650.0µg/LN-Nitrosodiphenylamine 69-152 2.4 20.0
36.0 72.073.236.650.0µg/LN-Nitroso-di-n-propylamine 10-230 1.6 20.0
50.1 10010250.850.0µg/LPentachlorophenol 14-176 1.3 20.0
46.6 93.294.447.250.0µg/LPhenanthrene 54-120 1.2 20.0
17.2 34.434.817.450.0µg/LPhenol 10-112 1.1 20.0
47.4 94.896.048.050.0µg/LPyrene 52-115 1.2 20.0
32.6 65.268.834.450.0µg/L1,2,4-Trichlorobenzene 44-142 5.3 20.0
41.2 82.485.842.950.0µg/L2,4,6-Trichlorophenol 37-144 4.0 20.0
82.086.42-Fluorobiphenyl (S)49-118
40.143.52-Fluorophenol (S)22-84
65.268.0Nitrobenzene-d5 (S)43-123
93.695.84-Terphenyl-d14 (S)49-151
86.887.62,4,6-Tribromophenol (S)31-144
Page 32 of 47Date:03/30/2023 05:08 PM
Page 145 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V30970QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V30880
LCS-V30880 LCSD-V30880Laboratory Control Sample & LCSD
LCSD
ResultParameter LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
26.328.7Phenol-d5 (S)10-63
Page 33 of 47Date:03/30/2023 05:08 PM
Page 146 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V30974QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V30932
Associated Lab Samples: 91097, 91098
LRB-V30932 Matrix: SOLLab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/17/23 17:270.6600.116<0.116mg/KgAcenaphthene
03/17/23 17:270.6600.105<0.105mg/KgAcenaphthylene
03/17/23 17:270.6600.152<0.152mg/KgAniline
03/17/23 17:270.6600.143<0.143mg/KgAnthracene
03/17/23 17:270.6600.139<0.139mg/KgBenzo(a)anthracene
03/17/23 17:270.6600.147<0.147mg/KgBenzo(a)pyrene
03/17/23 17:270.6600.146<0.146mg/KgBenzo(b)fluoranthene
03/17/23 17:270.6600.136<0.136mg/KgBenzo(g,h,i)perylene
03/17/23 17:270.6600.137<0.137mg/KgBenzo(k)fluoranthene
03/17/23 17:272.000.580<0.580mg/KgBenzoic Acid
03/17/23 17:270.6600.105<0.105mg/KgBenzyl alcohol
03/17/23 17:270.6600.118<0.118mg/KgBis(2-Chloroethoxy)methane
03/17/23 17:270.6600.107<0.107mg/KgBis(2-Chloroethyl)ether
03/17/23 17:270.3300.136<0.136mg/KgBis(2-Chloroisopropyl)ether
03/17/23 17:270.6600.120<0.120mg/KgBis(2-ethylhexyl)phthalate
03/17/23 17:270.6600.109<0.109mg/Kg4-Bromophenyl phenyl ether
03/17/23 17:270.3300.113<0.113mg/KgButyl benzyl phthalate
03/17/23 17:270.6600.092<0.092mg/Kg4-Chloro-3-methylphenol
03/17/23 17:270.3300.112<0.112mg/Kg4-Chloroaniline
03/17/23 17:270.6600.116<0.116mg/Kg2-Chloronaphthalene
03/17/23 17:270.6600.098<0.098mg/Kg2-Chlorophenol
03/17/23 17:271.000.126<0.126mg/Kg4-Chlorophenyl phenyl ether
03/17/23 17:270.6600.142<0.142mg/KgChrysene
03/17/23 17:270.6600.230<0.230mg/KgDibenz(a,h)anthracene
03/17/23 17:270.6600.119<0.119mg/KgDibenzofuran
03/17/23 17:270.6600.094<0.094mg/Kg1,2-Dichlorobenzene
03/17/23 17:270.6600.097<0.097mg/Kg1,3-Dichlorobenzene
Page 34 of 47Date:03/30/2023 05:08 PM
Page 147 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V30974QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V30932
Associated Lab Samples: 91097, 91098
LRB-V30932 Matrix: SOLLab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/17/23 17:270.3300.097<0.097mg/Kg1,4-Dichlorobenzene
03/17/23 17:270.6600.147<0.147mg/Kg3,3'-Dichlorobenzidine
03/17/23 17:270.6600.095<0.095mg/Kg2,4-Dichlorophenol
03/17/23 17:270.6600.180<0.180mg/KgDiethyl phthalate
03/17/23 17:270.6600.174<0.174mg/KgDimethyl phthalate
03/17/23 17:270.3300.108<0.108mg/Kg2,4-Dimethylphenol
03/17/23 17:270.6600.107<0.107mg/KgDi-n-butyl phthalate
03/17/23 17:271.500.240<0.240mg/Kg4,6-Dinitro-2-methylphenol
03/17/23 17:271.500.520<0.520mg/Kg2,4-Dinitrophenol
03/17/23 17:270.6600.096<0.096mg/Kg2,4-Dinitrotoluene
03/17/23 17:270.6600.108<0.108mg/Kg2,6-Dinitrotoluene
03/17/23 17:270.3300.143<0.143mg/KgDi-n-Octyl Phthalate
03/17/23 17:270.6600.123<0.123mg/KgFluoranthene
03/17/23 17:270.6600.128<0.128mg/KgFluorene
03/17/23 17:270.6600.106<0.106mg/KgHexachlorobenzene
03/17/23 17:270.6600.097<0.097mg/KgHexachlorobutadiene
03/17/23 17:270.6600.157<0.157mg/KgHexachlorocyclopentadiene
03/17/23 17:270.6600.079<0.079mg/KgHexachloroethane
03/17/23 17:270.6600.179<0.179mg/KgIndeno(1,2,3-cd)pyrene
03/17/23 17:270.6600.191<0.191mg/KgIsophorone
03/17/23 17:270.6600.106<0.106mg/Kg1-Methylnaphthalene
03/17/23 17:270.6600.100<0.100mg/Kg2-Methylnaphthalene
03/17/23 17:270.6600.097<0.097mg/Kg2-Methylphenol
03/17/23 17:270.6600.084<0.084mg/Kg3&4 Methylphenol
03/17/23 17:270.6600.144<0.144mg/KgNaphthalene
03/17/23 17:270.6600.096<0.096mg/Kg2-Nitroaniline
03/17/23 17:270.6600.120<0.120mg/Kg3-Nitroaniline
Page 35 of 47Date:03/30/2023 05:08 PM
Page 148 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V30974QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V30932
Associated Lab Samples: 91097, 91098
LRB-V30932 Matrix: SOLLab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/17/23 17:270.3300.093<0.093mg/Kg4-Nitroaniline
03/17/23 17:270.3300.116<0.116mg/KgNitrobenzene
03/17/23 17:270.6600.088<0.088mg/Kg2-Nitrophenol
03/17/23 17:270.6600.117<0.117mg/Kg4-Nitrophenol
03/17/23 17:270.6600.263<0.263mg/KgN-Nitrosodimethylamine
03/17/23 17:270.6600.181<0.181mg/KgN-Nitrosodiphenylamine
03/17/23 17:270.6600.118<0.118mg/KgN-Nitroso-di-n-propylamine
03/17/23 17:271.000.347<0.347mg/KgPentachlorophenol
03/17/23 17:270.6600.208<0.208mg/KgPhenanthrene
03/17/23 17:270.6600.112<0.112mg/KgPhenol
03/17/23 17:270.6600.134<0.134mg/KgPyrene
03/17/23 17:270.3300.079<0.079mg/KgPyridine
03/17/23 17:270.6600.107<0.107mg/Kg1,2,4-Trichlorobenzene
03/17/23 17:270.6600.096<0.096mg/Kg2,4,5-Trichlorophenol
03/17/23 17:270.6600.096<0.096mg/Kg2,4,6-Trichlorophenol
03/17/23 17:272-Fluorobiphenyl (S)88.6 44-115
03/17/23 17:272-Fluorophenol (S)80.7 35-115
03/17/23 17:27Nitrobenzene-d5 (S)82.6 37-122
03/17/23 17:274-Terphenyl-d14 (S)101 54-127
03/17/23 17:272,4,6-Tribromophenol (S)85.8 39-132
03/17/23 17:27Phenol-d5 (S)77.1 34-121
LCS-V30932 LCSD-V30932Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
1.65 98.898.21.641.67mg/KgAcenaphthene 40-123 0.6 20
Page 36 of 47Date:03/30/2023 05:08 PM
Page 149 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V30974QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V30932
LCS-V30932 LCSD-V30932Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
1.63 97.697.01.621.67mg/KgAcenaphthylene 32-132 0.6 20
3.95 237*252*4.211.67mg/KgAniline 12-197 6.3 20
1.76 1051021.711.67mg/KgAnthracene 47-123 2.8 20
1.72 10398.21.641.67mg/KgBenzo(a)anthracene 49-126 4.7 20
2.04 1221191.981.67mg/KgBenzo(a)pyrene 45-129 2.9 20
1.85 1111081.811.67mg/KgBenzo(b)fluoranthene 45-132 2.1 20
1.75 1051041.731.67mg/KgBenzo(g,h,i)perylene 43-134 1.1 20
1.85 1111081.801.67mg/KgBenzo(k)fluoranthene 47-132 2.7 20
<0.580 0.0*0.0*<0.5801.67mg/KgBenzoic Acid 10-83 0.0 20
1.61 96.491.61.531.67mg/KgBenzyl alcohol 29-122 5.0 20
1.52 91.085.61.431.67mg/KgBis(2-Chloroethoxy)methane 36-121 6.1 20
1.50 89.871.81.201.67mg/KgBis(2-Chloroethyl)ether 31-120 22.2*20
1.51 90.486.21.441.67mg/KgBis(2-Chloroisopropyl)ether 33-131 4.7 20
1.86 1111071.791.67mg/KgBis(2-ethylhexyl)phthalate 51-133 3.8 20
1.72 1031021.701.67mg/Kg4-Bromophenyl phenyl ether 46-124 1.1 20
1.84 1101091.821.67mg/KgButyl benzyl phthalate 48-132 1.0 20
1.43 85.682.61.381.67mg/Kg4-Chloro-3-methylphenol 45-122 3.5 20
1.49 89.285.01.421.67mg/Kg4-Chloroaniline 17-106 4.8 20
1.65 98.898.21.641.67mg/Kg2-Chloronaphthalene 41-114 0.6 20
1.49 89.286.21.441.67mg/Kg2-Chlorophenol 34-121 3.4 20
1.66 99.497.61.631.67mg/Kg4-Chlorophenyl phenyl ether 45-121 1.8 20
1.75 1051011.681.67mg/KgChrysene 50-124 4.0 20
1.65 98.898.21.641.67mg/KgDibenz(a,h)anthracene 45-134 0.6 20
1.64 98.297.61.631.67mg/KgDibenzofuran 44-120 0.6 20
1.45 86.882.61.381.67mg/Kg1,2-Dichlorobenzene 33-117 4.9 20
1.44 86.283.21.391.67mg/Kg1,3-Dichlorobenzene 30-115 3.5 20
Page 37 of 47* QC Fail Date:03/30/2023 05:08 PM
Page 150 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V30974QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V30932
LCS-V30932 LCSD-V30932Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
1.42 85.081.41.361.67mg/Kg1,4-Dichlorobenzene 31-115 4.3 20
1.28 76.674.81.251.67mg/Kg3,3'-Dichlorobenzidine 22-121 2.3 20
1.47 88.083.81.401.67mg/Kg2,4-Dichlorophenol 40-122 4.8 20
1.70 1021001.671.67mg/KgDiethyl phthalate 50-124 1.7 20
1.70 10299.41.661.67mg/KgDimethyl phthalate 48-124 2.3 20
1.55 92.887.41.461.67mg/Kg2,4-Dimethylphenol 30-127 5.9 20
1.89 1131091.821.67mg/KgDi-n-butyl phthalate 51-128 3.7 20
1.50 89.885.61.431.67mg/Kg4,6-Dinitro-2-methylphenol 29-132 4.7 20
0.753 45.042.20.7051.67mg/Kg2,4-Dinitrophenol 27-129 6.5 20
1.73 1041031.721.67mg/Kg2,4-Dinitrotoluene 48-126 0.5 20
1.75 1051021.711.67mg/Kg2,6-Dinitrotoluene 46-124 2.3 20
1.93 1161141.901.67mg/KgDi-n-Octyl Phthalate 45-140 1.5 20
1.73 1041021.701.67mg/KgFluoranthene 50-127 1.7 20
1.70 1021001.671.67mg/KgFluorene 43-125 1.7 20
1.69 1011011.681.67mg/KgHexachlorobenzene 45-122 0.5 20
1.47 88.080.81.351.67mg/KgHexachlorobutadiene 32-123 8.5 20
1.52 91.089.81.501.67mg/KgHexachlorocyclopentadiene 32-117 1.3 20
1.41 84.478.41.311.67mg/KgHexachloroethane 28-117 7.3 20
1.72 1031011.691.67mg/KgIndeno(1,2,3-cd)pyrene 45-133 1.7 20
1.47 88.081.41.361.67mg/KgIsophorone 30-122 7.7 20
1.47 88.084.41.411.67mg/Kg1-Methylnaphthalene 40-119 4.1 20
1.40 83.880.21.341.67mg/Kg2-Methylnaphthalene 38-122 4.3 20
1.50 89.888.01.471.67mg/Kg2-Methylphenol 32-122 2.0 20
1.34 80.277.21.291.67mg/Kg3&4 Methylphenol 34-119 3.8 20
1.43 85.681.41.361.67mg/KgNaphthalene 35-123 5.0 20
1.63 97.697.01.621.67mg/Kg2-Nitroaniline 44-127 0.6 20
Page 38 of 47Date:03/30/2023 05:08 PM
Page 151 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V30974QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V30932
LCS-V30932 LCSD-V30932Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
1.55 92.892.21.541.67mg/Kg3-Nitroaniline 33-119 0.6 20
1.69 10198.81.651.67mg/Kg4-Nitroaniline 63-147 2.3 20
1.41 84.480.81.351.67mg/KgNitrobenzene 34-122 4.3 20
1.38 82.680.21.341.67mg/Kg2-Nitrophenol 36-123 2.9 20
3.44 206*134*2.231.67mg/Kg4-Nitrophenol 30-132 42.6*20
1.36 81.477.81.301.67mg/KgN-Nitrosodimethylamine 10-146 4.5 20
2.15 129*1232.061.67mg/KgN-Nitrosodiphenylamine 38-127 4.2 20
1.46 87.483.81.401.67mg/KgN-Nitroso-di-n-propylamine 36-120 4.1 20
1.80 1081021.701.67mg/KgPentachlorophenol 25-133 5.7 20
1.77 1061031.721.67mg/KgPhenanthrene 50-121 2.8 20
1.57 94.090.41.511.67mg/KgPhenol 34-121 3.8 20
1.79 1071031.721.67mg/KgPyrene 47-127 3.9 20
1.14 68.266.41.111.67mg/KgPyridine 10-80 2.6 20
1.44 86.280.21.341.67mg/Kg1,2,4-Trichlorobenzene 34-118 7.1 20
1.59 95.292.81.551.67mg/Kg2,4,5-Trichlorophenol 41-124 2.5 20
1.63 97.695.21.591.67mg/Kg2,4,6-Trichlorophenol 39-126 2.4 20
96.497.62-Fluorobiphenyl (S)44-115
90.990.02-Fluorophenol (S)35-115
80.279.0Nitrobenzene-d5 (S)37-122
1051054-Terphenyl-d14 (S)54-127
94.896.92,4,6-Tribromophenol (S)39-132
86.785.5Phenol-d5 (S)34-121
Page 39 of 47* QC Fail Date:03/30/2023 05:08 PM
Page 152 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
EDB and DBCP by Microextraction GC/ECD
EPA-504.1
V31002QC Analytical Batch(es):
Analysis Method:
Analysis Description:
EPA-504.1(PREP)
QC Prep:V30967
Associated Lab Samples: 91099, 91100, 91101, 91103, 91104, 91105
LRB-V30967 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits
03/20/23 15:290.02000.00330<0.00330µg/L1,2-Dibromoethane
LCS-V30967 LCSD-V30967Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
0.267 1071050.2630.250µg/L1,2-Dibromoethane 70-130 1.5 20.0
V 91100-DUP-V30967Duplicate
Max RPDParameter AnalyzedRPDDUPResultResultUnits
20.0 03/20/23 17:211.4<0.0208< 0.0208µg/L1,2-Dibromoethane
V 91099-MS-V30967Matrix Spike
MS ResultParameter MaxRPDMS%RecMSDResultMSDSpike
Conc.
MS SpikeConc.ResultUnits %RecLimits
0.262 1020.257< 0.00338µg/L1,2-Dibromoethane 70-130
Page 40 of 47Date:03/30/2023 05:08 PM
Page 153 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Massachusetts EPH
MADEP-EPH
V30950QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAEPH (Prep)
QC Prep:V30918
Associated Lab Samples: 91099, 91101, 91104, 91105
LRB-V30918 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/20/23 09:1035028.2<28.2µg/LAliphatic C9-C18
03/20/23 09:10500124<124µg/LAliphatic C19-C36
03/20/23 09:1025061.2<61.2µg/LAromatic C11-C22
03/20/23 09:102-Fluorobiphenyl (S)107 40-140
03/20/23 09:102-Bromonaphthalene (S)104 40-140
03/20/23 09:10Chlorooctadecane (S)36.5 40-140
03/20/23 09:10OTP Surrogate (S)82.8 40-140
LCS-V30918 LCSD-V30918Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
569 94.885.0510600µg/LAliphatic C9-C18 40-140 10.9 50.0
923 115102813800µg/LAliphatic C19-C36 40-140 12.6 50.0
2440 144*14023801700µg/LAromatic C11-C22 40-140 2.4 50.0
1221272-Fluorobiphenyl (S)40-140
1211092-Bromonaphthalene (S)40-140
39.5*39.3*Chlorooctadecane (S)40-140
10197.7OTP Surrogate (S)40-140
Page 41 of 47* QC Fail Date:03/30/2023 05:08 PM
Page 154 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Massachusetts EPH
MADEP-EPH
V31003QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAEPH (Prep)
QC Prep:V30933
Associated Lab Samples: 91097, 91098
LRB-V30933 Matrix: SOLLab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/20/23 17:0750.09.20<9.20mg/KgAliphatic C9-C18
03/20/23 17:0750.012.2<12.2mg/KgAliphatic C19-C36
03/20/23 17:0750.014.2<14.2mg/KgAromatic C11-C22
03/20/23 17:072-Fluorobiphenyl (S)120 40-140
03/20/23 17:072-Bromonaphthalene (S)119 40-140
03/20/23 17:07Chlorooctadecane (S)81.1 40-140
03/20/23 17:07OTP Surrogate (S)103 40-140
LCS-V30933 LCSD-V30933Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
57.2 95.391.554.960.0mg/KgAliphatic C9-C18 40-140 4.1 50
89.4 11210886.480.0mg/KgAliphatic C19-C36 40-140 3.4 50
274 161*140238170mg/KgAromatic C11-C22 40-140 14.0 50
1281142-Fluorobiphenyl (S)40-140
1281132-Bromonaphthalene (S)40-140
81.077.1Chlorooctadecane (S)40-140
112100OTP Surrogate (S)40-140
Page 42 of 47* QC Fail Date:03/30/2023 05:08 PM
Page 155 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Massachusetts EPH
MADEP-EPH
V31230QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAEPH (Prep)
QC Prep:V31110
Associated Lab Samples: 91100, 91103
LRB-V31110 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/24/23 17:0235028.2<28.2µg/LAliphatic C9-C18
03/24/23 17:02500124<124µg/LAliphatic C19-C36
03/24/23 17:0225061.2<61.2µg/LAromatic C11-C22
03/24/23 17:022-Fluorobiphenyl (S)100 40-140
03/24/23 17:022-Bromonaphthalene (S)I 40-140
03/24/23 17:02Chlorooctadecane (S)75.0 40-140
03/24/23 17:02OTP Surrogate (S)84.8 40-140
LCS-V31110 LCSD-V31110Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
377 62.860.5363600µg/LAliphatic C9-C18 40-140 3.7 50.0
605 75.677.7622800µg/LAliphatic C19-C36 40-140 2.7 50.0
1620 95.298.816801700µg/LAromatic C11-C22 40-140 3.6 50.0
1051062-Fluorobiphenyl (S)40-140
I*I*2-Bromonaphthalene (S)40-140
71.776.7Chlorooctadecane (S)40-140
89.391.6OTP Surrogate (S)40-140
Page 43 of 47* QC Fail Date:03/30/2023 05:08 PM
Page 156 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V30854QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V30853
Associated Lab Samples: 91099, 91100, 91101, 91103, 91104, 91105
LRB-V30853 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/15/23 12:0350.011.5<11.5µg/LAliphatic C5-C8
03/15/23 12:0350.025.8<25.8µg/LAliphatic C9-C12
03/15/23 12:0350.04.02<4.02µg/LAromatic C9-C10
03/15/23 12:032,5-Dibromotoluene (FID) (S)94.5 70-130
03/15/23 12:032,5-Dibromotoluene (PID) (S)89.6 70-130
LCS-V30853 LCSD-V30853Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
308 10397.6293300µg/LAliphatic C5-C8 70-130 4.9 50.0
338 113110330300µg/LAliphatic C9-C12 70-130 2.3 50.0
98.0 98.096.496.4100µg/LAromatic C9-C10 70-130 1.6 50.0
86.781.72,5-Dibromotoluene (FID) (S)70-130
83.580.72,5-Dibromotoluene (PID) (S)70-130
Page 44 of 47Date:03/30/2023 05:08 PM
Page 157 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V30856QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V30855
Associated Lab Samples: 91097, 91098
LRB-V30855 Matrix: SOLLab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
03/15/23 17:378.001.22<1.22mg/KgAliphatic C5-C8
03/15/23 17:378.004.56<4.56mg/KgAliphatic C9-C12
03/15/23 17:378.000.624<0.624mg/KgAromatic C9-C10
03/15/23 17:372,5-Dibromotoluene (FID) (S)90.0 70-130
03/15/23 17:372,5-Dibromotoluene (PID) (S)87.6 70-130
LCS-V30855 LCSD-V30855Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
31.3 97.810935.032.0mg/KgAliphatic C5-C8 70-130 11.1 50
38.1 11911837.732.0mg/KgAliphatic C9-C12 70-130 1.0 50
11.8 11011011.810.7mg/KgAromatic C9-C10 70-130 0.0 50
81.182.72,5-Dibromotoluene (FID) (S)70-130
77.176.52,5-Dibromotoluene (PID) (S)70-130
Page 45 of 47Date:03/30/2023 05:08 PM
Page 158 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
Dry Weight Determination
SW-DRYWT
V30996QC Analytical Batch:
Analysis Method:
Analysis Description:
V 91097-DUPDuplicate
Max RPDParameter AnalyzedRPDDUP
Result
ResultUnits
20.0 03/20/23 18:383.019.520.1%Moisture
V 91607-DUPDuplicate
Max RPDParameter AnalyzedRPDDUP
Result
ResultUnits
20.0 03/20/23 18:380.235.135.0%Moisture
Page 46 of 47Date:03/30/2023 05:08 PM
Page 159 of 163
Quality Control Data
23-073-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
Total Organic Carbon - Walkley Black
WALK-BLACK
L671248QC Analytical Batch:
Analysis Method:
Analysis Description:
Associated Lab Samples: 91094, 91095, 91096
LRB Matrix: SOLLab Reagent Blank
Parameter AnalyzedMQLBlank
ResultUnits
03/22/23 10:250.05< 0.05%Total Organic Carbon
V 91094-DUPDuplicate
Max RPDParameter AnalyzedRPDDUP
Result
ResultUnits
20.0 03/22/23 10:250.00.110.11%Total Organic Carbon
Page 47 of 47Date:03/30/2023 05:08 PM
Page 160 of 163
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:23-073-0013
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 0.3C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:03/14/2023 13:43:38
Special precautions or instructions included?
Comments:
Page 161 of 163
Page 162 of 163
Page 163 of 163

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

10/3/2023

GeologicalResources,Inc.
LauraMinor
3502HayesRoad
Monroe,NC,28110

Ref: AnalyticalTesting
LabReportNumber:23-265-0005
ClientProjectDescription:MinuteMan#3
GRI#3148

DearLauraMinor:

WaypointAnalytical,LLC(Charlotte)receivedsample(s)on9/22/2023fortheanalysespresentedinthe
followingreport.

Theabovereferencedprojecthasbeenanalyzedperyourinstructions.Theanalyseswereperformedin
accordancewiththeapplicableanalyticalmethod.

Theanalyticaldatahasbeenvalidatedusingstandardqualitycontrolmeasuresperformedasrequiredbythe
analyticalmethod.QualityAssurance,methodvalidations,instrumentationmaintenanceandcalibrationforall
parameterswereperformedinaccordancewithguidelinesestablishedbytheUSEPA(including40CFR136
MethodUpdateRuleMay2021)unlessotherwiseindicated.

Certainparameters(chlorine,pH,dissolvedoxygen,sulfite...)arerequiredtobeanalyzedwithin15minutesof
sampling.Usually,butnotalways,anyfieldparameteranalyzedatthelaboratoryisoutsideofthisholdingtime.
Refertosampleanalysistimeforconfirmationofholdingtimecompliance.

TheresultsareshownontheattachedReportofAnalysis(s).Resultsforsolidmatricesarereportedonanas-
receivedbasisunlessotherwiseindicated.Thisreportshallnotbereproducedexceptinfullandrelatesonlyto
thesamplesincludedinthisreport.

Pleasedonothesitatetocontactmeorclientservicesifyouhaveanyquestionsorneedadditionalinformation.

Sincerely,
DanyaleLove
ProjectManager
Page 1 of 58
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202437735State ProgramNorth Carolina
12/31/2023402State ProgramNorth Carolina
07/31/202499012State ProgramSouth Carolina
12/31/202399012State ProgramSouth Carolina
Page 1 of 1 00016/23-265-0005
Page 2 of 58
Report Number:
Sample Summary Table
Client Project Description:
23-265-0005
Minute Man #3
GRI #3148
Lab No Client Sample ID Matrix Date Collected Date Received
09/21/2023 08:49Aqueous 95985 Trip Blank 09/22/2023 10:00
09/21/2023 11:22Aqueous 95986 MW-12 09/22/2023 10:00
09/21/2023 11:49Aqueous 95987 MW-13 09/22/2023 10:00
Page 3 of 58
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-265-0005
Report Limit
Project:Minute Man #3
V 95986MW-12
0.006 09/27/2023 00:286010DLeadmg/L 0.002
1.92 09/28/2023 03:316200BBenzeneµg/L 0.180
4.97 09/28/2023 03:316200Bn-Butylbenzene µg/L 0.180
3.57 09/28/2023 03:316200Bsec-Butyl benzene µg/L 0.200
110 09/28/2023 20:136200BEthylbenzeneµg/L 1.70
16.1 09/28/2023 03:316200BIsopropylbenzeneµg/L 0.180
1.61 09/28/2023 03:316200B4-Isopropyl toluene µg/L 0.089
42.8 09/28/2023 03:316200BNaphthaleneµg/L 0.470
34.3 09/28/2023 03:316200Bn-Propylbenzene µg/L 0.190
2.28 09/28/2023 03:316200BStyreneµg/L 0.220
34.9 09/28/2023 03:316200BTolueneµg/L 0.220
451 09/28/2023 20:136200B1,2,4-Trimethylbenzene µg/L 1.90
135 09/28/2023 20:136200B1,3,5-Trimethylbenzene µg/L 1.80
299 09/28/2023 20:136200Bo-Xylene µg/L 2.10
839 09/28/2023 20:136200Bm,p-Xylene µg/L 4.20
1140 09/28/2023 20:136200BXylene (Total)µg/L 2.10
J8.22 09/28/2023 11:28625.1 2,4-Dimethylphenol µg/L 1.62
16.5 09/28/2023 11:28625.1 Naphthalene µg/L 0.749
584 09/25/2023 23:57CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 11.5
1090 09/26/2023 10:05CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 258
1050 09/26/2023 10:05CALCULATIONAromatic C9-C10 (Adjusted)µg/L 40.2
J71.9 09/30/2023 17:51MADEP-EPH Aromatic C11-C22 µg/L 61.2
621 09/25/2023 23:57MADEP-VPH Aliphatic C5-C8 µg/L 11.5
3390 09/26/2023 10:05MADEP-VPH Aliphatic C9-C12 µg/L 258
1050 09/26/2023 10:05MADEP-VPH Aromatic C9-C10 µg/L 40.2
V 95987MW-13
J0.002 09/27/2023 00:326010DLeadmg/L 0.002
0.631 09/28/2023 03:566200BBenzeneµg/L 0.180
5.38 09/28/2023 03:566200Bn-Butylbenzene µg/L 0.180
1.65 09/28/2023 03:566200Bsec-Butyl benzene µg/L 0.200
46.0 09/28/2023 03:566200BEthylbenzeneµg/L 0.170
6.42 09/28/2023 03:566200BIsopropylbenzeneµg/L 0.180
2.15 09/28/2023 03:566200B4-Isopropyl toluene µg/L 0.089
J0.213 09/28/2023 03:566200BMethyl tert-butyl ether (MTBE)µg/L 0.140
53.1 09/28/2023 03:566200BNaphthaleneµg/L 0.470
16.0 09/28/2023 03:566200Bn-Propylbenzene µg/L 0.190
Page 4 of 58
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-265-0005
Report Limit
Project:Minute Man #3
V 95987MW-13
8.85 09/28/2023 03:566200BTolueneµg/L 0.220
336 09/28/2023 20:376200B1,2,4-Trimethylbenzene µg/L 1.90
109 09/28/2023 20:376200B1,3,5-Trimethylbenzene µg/L 1.80
85.0 09/28/2023 20:376200Bo-Xylene µg/L 2.10
216 09/28/2023 20:376200Bm,p-Xylene µg/L 4.20
301 09/28/2023 20:376200BXylene (Total)µg/L 2.10
12.3 09/28/2023 11:50625.1 Naphthalene µg/L 0.738
353 09/26/2023 00:21CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 11.5
1000 09/26/2023 10:29CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 258
711 09/26/2023 10:29CALCULATIONAromatic C9-C10 (Adjusted)µg/L 40.2
J62.6 09/30/2023 18:27MADEP-EPH Aromatic C11-C22 µg/L 61.2
362 09/26/2023 00:21MADEP-VPH Aliphatic C5-C8 µg/L 11.5
2060 09/26/2023 10:29MADEP-VPH Aliphatic C9-C12 µg/L 258
711 09/26/2023 10:29MADEP-VPH Aromatic C9-C10 µg/L 40.2
Page 5 of 58

Client:GeologicalResources,Inc. CASENARRATIVE
Project:MinuteMan#3
LabReportNumber:23-265-0005
Date:10/3/2023

625.1-Base/NeutralsandAcidsbyGC/MSMethod625.1
Analyte:Benzidine
QCBatchNo:V38427/V38382
RelativePercentDifference(RPD)fortheduplicateanalysiswasoutsideoftheallowableQClimits.

Analyte:BenzoicAcid
QCBatchNo:V38427/V38382
RelativePercentDifference(RPD)fortheduplicateanalysiswasoutsideoftheallowableQClimits.

VolatileOrganicCompounds-GC/MSMethod6200B
Analyte:1,2,3-Trichlorobenzene
QCBatchNo:V38456/V38455
RecoveryfortheLCSexceededtheupperacceptancelimit.However,allsampleresultsassociatedwiththe
batcharebelowtheMQL,sothishighbiashadnoimpactupontheclientdata.Theresultsareconsideredtobe
acceptable.

Analyte:1,2,3-Trichlorobenzene
QCBatchNo:V38465/V38455
RecoveryfortheLCSexceededtheupperacceptancelimit.However,allsampleresultsassociatedwiththe
batcharebelowtheMQL,sothishighbiashadnoimpactupontheclientdata.Theresultsareconsideredtobe
acceptable.

Analyte:1,2,3-Trichlorobenzene
QCBatchNo:V38531/V38455
RecoveryfortheLCSexceededtheupperacceptancelimit.However,allsampleresultsassociatedwiththe
batcharebelowtheMQL,sothishighbiashadnoimpactupontheclientdata.Theresultsareconsideredtobe
acceptable.

Analyte:1,2,4-Trichlorobenzene
QCBatchNo:V38456/V38455
RecoveryfortheLCSexceededtheupperacceptancelimit.However,allsampleresultsassociatedwiththe
batcharebelowtheMQL,sothishighbiashadnoimpactupontheclientdata.Theresultsareconsideredtobe
acceptable.

Analyte:1,2,4-Trichlorobenzene
QCBatchNo:V38465/V38455
RecoveryfortheLCSexceededtheupperacceptancelimit.However,allsampleresultsassociatedwiththe
batcharebelowtheMQL,sothishighbiashadnoimpactupontheclientdata.Theresultsareconsideredtobe
acceptable.

Analyte:1,2,4-Trichlorobenzene
QCBatchNo:V38531/V38455
RecoveryfortheLCSexceededtheupperacceptancelimit.However,allsampleresultsassociatedwiththe
batcharebelowtheMQL,sothishighbiashadnoimpactupontheclientdata.Theresultsareconsideredtobe
acceptable.
Page 6 of 58

Analyte:1,2-Dichloropropane
QCBatchNo:V38465/V38455
ThistargetanalytewasflaggedforrecoveriesoutsideQClimitsintheassociatedLCS/LCSD.Dataforthis
analyteisflagged"M"toindicatethatresultsshouldbeconsideredminimumconcentrationduetothepotentialfor
alowbias.

Analyte:CarbonTetrachloride
QCBatchNo:V38456/V38455
RecoveryfortheLCSexceededtheupperacceptancelimit.However,allsampleresultsassociatedwiththe
batcharebelowtheMQL,sothishighbiashadnoimpactupontheclientdata.Theresultsareconsideredtobe
acceptable.

Analyte:CarbonTetrachloride
QCBatchNo:V38531/V38455
RecoveryfortheLCSexceededtheupperacceptancelimit.However,allsampleresultsassociatedwiththe
batcharebelowtheMQL,sothishighbiashadnoimpactupontheclientdata.Theresultsareconsideredtobe
acceptable.

Analyte:Chloromethane
QCBatchNo:V38456/V38455
ThistargetanalytewasflaggedforrecoveriesoutsideQClimitsintheassociatedLCS/LCSD.Dataforthis
analyteisflagged"M"toindicatethatresultsshouldbeconsideredminimumconcentrationduetothepotentialfor
alowbias.

Analyte:Chloromethane
QCBatchNo:V38531/V38455
ThistargetanalytewasflaggedforrecoveriesoutsideQClimitsintheassociatedLCS/LCSD.Dataforthis
analyteisflagged"M"toindicatethatresultsshouldbeconsideredminimumconcentrationduetothepotentialfor
alowbias.

Analyte:Diisopropylether
QCBatchNo:V38465/V38455
ThistargetanalytewasflaggedforrecoveriesoutsideQClimitsintheassociatedLCS/LCSD.Dataforthis
analyteisflagged"M"toindicatethatresultsshouldbeconsideredminimumconcentrationduetothepotentialfor
alowbias.

Analyte:Diisopropylether
QCBatchNo:V38531/V38455
ThistargetanalytewasflaggedforrecoveriesoutsideQClimitsintheassociatedLCS/LCSD.Dataforthis
analyteisflagged"M"toindicatethatresultsshouldbeconsideredminimumconcentrationduetothepotentialfor
alowbias.

Analyte:Dichlorodifluoromethane
QCBatchNo:V38456/V38455
ThistargetanalytewasflaggedforrecoveriesoutsideQClimitsintheassociatedLCS/LCSD.Dataforthis
analyteisflagged"M"toindicatethatresultsshouldbeconsideredminimumconcentrationduetothepotentialfor
alowbias.

Analyte:Dichlorodifluoromethane
QCBatchNo:V38465/V38455
ThistargetanalytewasflaggedforrecoveriesoutsideQClimitsintheassociatedLCS/LCSD.Dataforthis
analyteisflagged"M"toindicatethatresultsshouldbeconsideredminimumconcentrationduetothepotentialfor
alowbias.
Page 7 of 58

Analyte:Dichlorodifluoromethane
QCBatchNo:V38531/V38455
ThistargetanalytewasflaggedforrecoveriesoutsideQClimitsintheassociatedLCS/LCSD.Dataforthis
analyteisflagged"M"toindicatethatresultsshouldbeconsideredminimumconcentrationduetothepotentialfor
alowbias.

Analyte:Ethanol
QCBatchNo:V38531/V38455
ThistargetanalytewasflaggedforrecoveriesoutsideQClimitsintheassociatedLCS/LCSD.Dataforthis
analyteisflagged"M"toindicatethatresultsshouldbeconsideredminimumconcentrationduetothepotentialfor
alowbias.

Analyte:Hexachlorobutadiene
QCBatchNo:V38456/V38455
RecoveryfortheLCSexceededtheupperacceptancelimit.However,allsampleresultsassociatedwiththe
batcharebelowtheMQL,sothishighbiashadnoimpactupontheclientdata.Theresultsareconsideredtobe
acceptable.

Analyte:Hexachlorobutadiene
QCBatchNo:V38531/V38455
RecoveryfortheLCSexceededtheupperacceptancelimit.However,allsampleresultsassociatedwiththe
batcharebelowtheMQL,sothishighbiashadnoimpactupontheclientdata.Theresultsareconsideredtobe
acceptable.

Analyte:Vinylchloride
QCBatchNo:V38465/V38455
ThistargetanalytewasflaggedforrecoveriesoutsideQClimitsintheassociatedLCS/LCSD.Dataforthis
analyteisflagged"M"toindicatethatresultsshouldbeconsideredminimumconcentrationduetothepotentialfor
alowbias.

Analyte:Vinylchloride
QCBatchNo:V38531/V38455
ThistargetanalytewasflaggedforrecoveriesoutsideQClimitsintheassociatedLCS/LCSD.Dataforthis
analyteisflagged"M"toindicatethatresultsshouldbeconsideredminimumconcentrationduetothepotentialfor
alowbias.

Analyte:tert-Butylalcohol
QCBatchNo:V38465/V38464
RelativePercentDifference(RPD)fortheduplicateanalysiswasoutsideoftheallowableQClimits.

Page 8 of 58
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-265-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 09/22/2023
Minute Man #3
Report Date : 10/03/2023
Sample ID :
Lab No :
Sampled:Trip Blank
95985 Matrix:
9/21/2023 8:49
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38455 09/27/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 09/27/23 14:44 V38456MSA
<0.180 µg/L 0.180 0.500Benzene 1 09/27/23 14:44 V38456MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 09/27/23 14:44 V38456MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 09/27/23 14:44 V38456MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 09/27/23 14:44 V38456MSA
<1.50 µg/L 1.50 5.00Bromoform 1 09/27/23 14:44 V38456MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 09/27/23 14:44 V38456MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 09/27/23 14:44 V38456MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 09/27/23 14:44 V38456MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 09/27/23 14:44 V38456MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 09/27/23 14:44 V38456MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 09/27/23 14:44 V38456MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 09/27/23 14:44 V38456MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 09/27/23 14:44 V38456MSA
<0.220 µg/L 0.220 0.500Chloroform 1 09/27/23 14:44 V38456MSA
<0.220 M µg/L 0.220 0.500Chloromethane 1 09/27/23 14:44 V38456MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 09/27/23 14:44 V38456MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 09/27/23 14:44 V38456MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 09/27/23 14:44 V38456MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 09/27/23 14:44 V38456MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 09/27/23 14:44 V38456MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 09/27/23 14:44 V38456MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 09/27/23 14:44 V38456MSA
Qualifiers/Definitions Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 9 of 58
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-265-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 09/22/2023
Minute Man #3
Report Date : 10/03/2023
Sample ID :
Lab No :
Sampled:Trip Blank
95985 Matrix:
9/21/2023 8:49
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38455 09/27/23 09:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 09/27/23 14:44 V38456MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 09/27/23 14:44 V38456MSA
<1.20 M µg/L 1.20 5.00Dichlorodifluoromethane 1 09/27/23 14:44 V38456MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 09/27/23 14:44 V38456MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 09/27/23 14:44 V38456MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 09/27/23 14:44 V38456MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 09/27/23 14:44 V38456MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 09/27/23 14:44 V38456MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 09/27/23 14:44 V38456MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 09/27/23 14:44 V38456MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 09/27/23 14:44 V38456MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 09/27/23 14:44 V38456MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 09/27/23 14:44 V38456MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 09/27/23 14:44 V38456MSA
<42.0 µg/L 42.0 200Ethanol 1 09/27/23 14:44 V38456MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 09/27/23 14:44 V38456MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 09/27/23 14:44 V38456MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 09/27/23 14:44 V38456MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 09/27/23 14:44 V38456MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 09/27/23 14:44 V38456MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 09/27/23 14:44 V38456MSA
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 09/27/23 14:44 V38456MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 09/27/23 14:44 V38456MSA
Qualifiers/Definitions Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 10 of 58
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-265-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 09/22/2023
Minute Man #3
Report Date : 10/03/2023
Sample ID :
Lab No :
Sampled:Trip Blank
95985 Matrix:
9/21/2023 8:49
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38455 09/27/23 09:00
<0.330 µg/L 0.330 2.00Methylene Chloride 1 09/27/23 14:44 V38456MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 09/27/23 14:44 V38456MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 09/27/23 14:44 V38456MSA
<0.220 µg/L 0.220 0.500Styrene 1 09/27/23 14:44 V38456MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 09/27/23 14:44 V38456MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 09/27/23 14:44 V38456MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 09/27/23 14:44 V38456MSA
<0.220 µg/L 0.220 0.500Toluene 1 09/27/23 14:44 V38456MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 09/27/23 14:44 V38456MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 09/27/23 14:44 V38456MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 09/27/23 14:44 V38456MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 09/27/23 14:44 V38456MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 09/27/23 14:44 V38456MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 09/27/23 14:44 V38456MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 09/27/23 14:44 V38456MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 09/27/23 14:44 V38456MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 09/27/23 14:44 V38456MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 09/27/23 14:44 V38456MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 09/27/23 14:44 V38456MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 09/27/23 14:44 V38456MSA
<0.420 µg/L 0.420 1.00m,p-Xylene 1 09/27/23 14:44 V38456MSA
Qualifiers/Definitions Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 11 of 58
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-265-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 09/22/2023
Minute Man #3
Report Date : 10/03/2023
Sample ID :
Lab No :
Sampled:Trip Blank
95985 Matrix:
9/21/2023 8:49
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38455 09/27/23 09:00
<0.21 µg/L 0.210 0.500Xylene (Total)1 09/27/23 14:44 V38456
Surrogate: 4-Bromofluorobenzene 91.6 Limits: 70-130%09/27/23 14:441 MSA V38456
Surrogate: Dibromofluoromethane 101 Limits: 70-130%09/27/23 14:441 MSA V38456
Surrogate: 1,2-Dichloroethane - d4 107 Limits: 70-130%09/27/23 14:441 MSA V38456
Surrogate: Toluene-d8 99.2 Limits: 70-130%09/27/23 14:441 MSA V38456
Qualifiers/Definitions Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 12 of 58
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-265-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 09/22/2023
Minute Man #3
Report Date : 10/03/2023
Sample ID :
Lab No :
Sampled:MW-12
95986 Matrix:
9/21/2023 11:22
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 09/28/23 03:31 6200BMSA
0.006 mg/L 0.002 0.006Lead 1 09/27/23 00:28 6010DJKC
Qualifiers/Definitions Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 13 of 58
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-265-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 09/22/2023
Minute Man #3
Report Date : 10/03/2023
Sample ID :
Lab No :
Sampled:MW-12
95986 Matrix:
9/21/2023 11:22
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38464 09/27/23 14:00 V38530 09/28/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 09/28/23 03:31 V38465MSA
1.92 µg/L 0.180 0.500Benzene 1 09/28/23 03:31 V38465MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 09/28/23 03:31 V38465MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 09/28/23 03:31 V38465MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 09/28/23 03:31 V38465MSA
<1.50 µg/L 1.50 5.00Bromoform 1 09/28/23 03:31 V38465MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 09/28/23 03:31 V38465MSA
4.97 µg/L 0.180 0.500n-Butylbenzene 1 09/28/23 03:31 V38465MSA
3.57 µg/L 0.200 0.500sec-Butyl benzene 1 09/28/23 03:31 V38465MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 09/28/23 03:31 V38465MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 09/28/23 03:31 V38465MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 09/28/23 03:31 V38465MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 09/28/23 03:31 V38465MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 09/28/23 03:31 V38465MSA
<0.220 µg/L 0.220 0.500Chloroform 1 09/28/23 03:31 V38465MSA
<0.220 M µg/L 0.220 0.500Chloromethane 1 09/28/23 03:31 V38465MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 09/28/23 03:31 V38465MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 09/28/23 03:31 V38465MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 09/28/23 03:31 V38465MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 09/28/23 03:31 V38465MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 09/28/23 03:31 V38465MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 09/28/23 03:31 V38465MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 09/28/23 03:31 V38465MSA
Qualifiers/Definitions Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 14 of 58
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-265-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 09/22/2023
Minute Man #3
Report Date : 10/03/2023
Sample ID :
Lab No :
Sampled:MW-12
95986 Matrix:
9/21/2023 11:22
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38464 09/27/23 14:00 V38530 09/28/23 09:00
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 09/28/23 03:31 V38465MSA
<1.20 M µg/L 1.20 5.00Dichlorodifluoromethane 1 09/28/23 03:31 V38465MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 09/28/23 03:31 V38465MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 09/28/23 03:31 V38465MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 09/28/23 03:31 V38465MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 09/28/23 03:31 V38465MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 09/28/23 03:31 V38465MSA
<0.190 M µg/L 0.190 0.5001,2-Dichloropropane 1 09/28/23 03:31 V38465MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 09/28/23 03:31 V38465MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 09/28/23 03:31 V38465MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 09/28/23 03:31 V38465MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 09/28/23 03:31 V38465MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 09/28/23 03:31 V38465MSA
<42.0 µg/L 42.0 200Ethanol 1 09/28/23 03:31 V38465MSA
110 µg/L 1.70 5.00Ethylbenzene 10 09/28/23 20:13 V38531MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 09/28/23 03:31 V38465MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 09/28/23 03:31 V38465MSA
16.1 µg/L 0.180 0.500Isopropylbenzene 1 09/28/23 03:31 V38465MSA
1.61 µg/L 0.089 0.5004-Isopropyl toluene 1 09/28/23 03:31 V38465MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 09/28/23 03:31 V38465MSA
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 09/28/23 03:31 V38465MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 09/28/23 03:31 V38465MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 09/28/23 03:31 V38465MSA
Qualifiers/Definitions Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 15 of 58
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-265-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 09/22/2023
Minute Man #3
Report Date : 10/03/2023
Sample ID :
Lab No :
Sampled:MW-12
95986 Matrix:
9/21/2023 11:22
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38464 09/27/23 14:00 V38530 09/28/23 09:00
42.8 µg/L 0.470 1.00Naphthalene 1 09/28/23 03:31 V38465MSA
34.3 µg/L 0.190 0.500n-Propylbenzene 1 09/28/23 03:31 V38465MSA
2.28 µg/L 0.220 0.500Styrene 1 09/28/23 03:31 V38465MSA
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 09/28/23 03:31 V38465MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 09/28/23 03:31 V38465MSA
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 09/28/23 03:31 V38465MSA
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 09/28/23 03:31 V38465MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 09/28/23 03:31 V38465MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 09/28/23 03:31 V38465MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 09/28/23 03:31 V38465MSA
34.9 µg/L 0.220 0.500Toluene 1 09/28/23 03:31 V38465MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 09/28/23 03:31 V38465MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 09/28/23 03:31 V38465MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 09/28/23 03:31 V38465MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 09/28/23 03:31 V38465MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 09/28/23 03:31 V38465MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 09/28/23 03:31 V38465MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 09/28/23 03:31 V38465MSA
451 µg/L 1.90 5.001,2,4-Trimethylbenzene 10 09/28/23 20:13 V38531MSA
135 µg/L 1.80 5.001,3,5-Trimethylbenzene 10 09/28/23 20:13 V38531MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 09/28/23 03:31 V38465MSA
<0.170 M µg/L 0.170 0.500Vinyl Chloride 1 09/28/23 03:31 V38465MSA
299 µg/L 2.10 5.00o-Xylene 10 09/28/23 20:13 V38531MSA
Qualifiers/Definitions Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 16 of 58
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-265-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 09/22/2023
Minute Man #3
Report Date : 10/03/2023
Sample ID :
Lab No :
Sampled:MW-12
95986 Matrix:
9/21/2023 11:22
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38464 09/27/23 14:00 V38530 09/28/23 09:00
839 µg/L 4.20 10.0m,p-Xylene 10 09/28/23 20:13 V38531MSA
1140 µg/L 2.10 5.00Xylene (Total)10 09/28/23 20:13 V38531
Surrogate: 4-Bromofluorobenzene 91.0 Limits: 70-130%09/28/23 03:311 MSA V38465
Surrogate: Dibromofluoromethane 98.8 Limits: 70-130%09/28/23 03:311 MSA V38465
Surrogate: 1,2-Dichloroethane - d4 109 Limits: 70-130%09/28/23 03:311 MSA V38465
Surrogate: Toluene-d8 92.6 Limits: 70-130%09/28/23 03:311 MSA V38465
Surrogate: 4-Bromofluorobenzene 89.2 Limits: 70-130%09/28/23 20:1310 MSA V38531
Surrogate: Dibromofluoromethane 99.0 Limits: 70-130%09/28/23 20:1310 MSA V38531
Surrogate: 1,2-Dichloroethane - d4 103 Limits: 70-130%09/28/23 20:1310 MSA V38531
Surrogate: Toluene-d8 87.0 Limits: 70-130%09/28/23 20:1310 MSA V38531
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38382 09/27/23 09:34
<0.311 µg/L 0.311 2.06
Acenaphthene 1 09/28/23 11:28 V38427AMP
<0.305 µg/L 0.305 2.06Acenaphthylene 1 09/28/23 11:28 V38427AMP
<0.861 µg/L 0.861 2.06Anthracene 1 09/28/23 11:28 V38427AMP
<1.36 µg/L 1.36 10.3Benzidine 1 09/28/23 11:28 V38427AMP
<0.656 µg/L 0.656 2.06Benzo(a)anthracene 1 09/28/23 11:28 V38427AMP
<1.05 µg/L 1.05 2.06
Benzo(a)pyrene 1 09/28/23 11:28 V38427AMP
<2.56 µg/L 2.56 5.15Benzo(b)fluoranthene 1 09/28/23 11:28 V38427AMP
<1.04 µg/L 1.04 5.15Benzo(g,h,i)perylene 1 09/28/23 11:28 V38427AMP
Qualifiers/Definitions Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 17 of 58
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-265-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 09/22/2023
Minute Man #3
Report Date : 10/03/2023
Sample ID :
Lab No :
Sampled:MW-12
95986 Matrix:
9/21/2023 11:22
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38382 09/27/23 09:34
<2.05 µg/L 2.05 5.15Benzo(k)fluoranthene 1 09/28/23 11:28 V38427AMP
<1.13 µg/L 1.13 10.3Benzoic Acid 1 09/28/23 11:28 V38427AMP
<0.704 µg/L 0.704 5.15Benzyl alcohol 1 09/28/23 11:28 V38427AMP
<0.482 µg/L 0.482 5.15Bis(2-Chloroethoxy)methane 1 09/28/23 11:28 V38427AMP
<1.07 µg/L 1.07 5.15Bis(2-Chloroethyl)ether 1 09/28/23 11:28 V38427AMP
<1.11 µg/L 1.11 5.15Bis(2-Chloroisopropyl)ether 1 09/28/23 11:28 V38427AMP
<3.56 µg/L 3.56 10.3Bis(2-ethylhexyl)phthalate 1 09/28/23 11:28 V38427AMP
<1.14 µg/L 1.14 5.154-Bromophenyl phenyl ether 1 09/28/23 11:28 V38427AMP
<1.88 µg/L 1.88 5.15Butyl benzyl phthalate 1 09/28/23 11:28 V38427AMP
<1.22 µg/L 1.22 5.154-Chloro-3-methylphenol 1 09/28/23 11:28 V38427AMP
<7.60 µg/L 7.60 20.62-Chloronaphthalene 1 09/28/23 11:28 V38427AMP
<0.966 µg/L 0.966 10.32-Chlorophenol 1 09/28/23 11:28 V38427AMP
<1.76 µg/L 1.76 5.154-Chlorophenyl phenyl ether 1 09/28/23 11:28 V38427AMP
<0.417 µg/L 0.417 2.06Chrysene 1 09/28/23 11:28 V38427AMP
<0.447 µg/L 0.447 2.06Dibenz(a,h)anthracene 1 09/28/23 11:28 V38427AMP
<0.881 µg/L 0.881 5.15Dibenzofuran 1 09/28/23 11:28 V38427AMP
<2.06 µg/L 2.06 5.151,2-Dichlorobenzene 1 09/28/23 11:28 V38427AMP
<2.06 µg/L 2.06 5.151,3-Dichlorobenzene 1 09/28/23 11:28 V38427AMP
<2.11 µg/L 2.11 5.151,4-Dichlorobenzene 1 09/28/23 11:28 V38427AMP
<1.95 µg/L 1.95 5.153,3'-Dichlorobenzidine 1 09/28/23 11:28 V38427AMP
<1.50 µg/L 1.50 10.32,4-Dichlorophenol 1 09/28/23 11:28 V38427AMP
<0.767 µg/L 0.767 5.15Diethyl phthalate 1 09/28/23 11:28 V38427AMP
<0.967 µg/L 0.967 5.15Dimethyl phthalate 1 09/28/23 11:28 V38427AMP
Qualifiers/Definitions Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 18 of 58
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-265-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 09/22/2023
Minute Man #3
Report Date : 10/03/2023
Sample ID :
Lab No :
Sampled:MW-12
95986 Matrix:
9/21/2023 11:22
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38382 09/27/23 09:34
8.22 J µg/L 1.62 20.62,4-Dimethylphenol 1 09/28/23 11:28 V38427AMP
<2.12 µg/L 2.12 5.15Di-n-butyl phthalate 1 09/28/23 11:28 V38427AMP
<2.13 µg/L 2.13 10.34,6-Dinitro-2-methylphenol 1 09/28/23 11:28 V38427AMP
<1.98 µg/L 1.98 10.32,4-Dinitrophenol 1 09/28/23 11:28 V38427AMP
<1.14 µg/L 1.14 5.152,4-Dinitrotoluene 1 09/28/23 11:28 V38427AMP
<0.833 µg/L 0.833 5.152,6-Dinitrotoluene 1 09/28/23 11:28 V38427AMP
<1.70 µg/L 1.70 5.15Di-n-Octyl Phthalate 1 09/28/23 11:28 V38427AMP
<0.257 µg/L 0.257 2.06Fluoranthene 1 09/28/23 11:28 V38427AMP
<0.831 µg/L 0.831 2.06Fluorene 1 09/28/23 11:28 V38427AMP
<1.01 µg/L 1.01 5.15Hexachlorobenzene 1 09/28/23 11:28 V38427AMP
<2.81 µg/L 2.81 5.15Hexachlorobutadiene 1 09/28/23 11:28 V38427AMP
<2.11 µg/L 2.11 5.15Hexachlorocyclopentadiene 1 09/28/23 11:28 V38427AMP
<1.81 µg/L 1.81 5.15Hexachloroethane 1 09/28/23 11:28 V38427AMP
<0.491 µg/L 0.491 2.06Indeno(1,2,3-cd)pyrene 1 09/28/23 11:28 V38427AMP
<0.457 µg/L 0.457 5.15Isophorone 1 09/28/23 11:28 V38427AMP
16.5 µg/L 0.749 2.06Naphthalene 1 09/28/23 11:28 V38427AMP
<0.932 µg/L 0.932 5.15Nitrobenzene 1 09/28/23 11:28 V38427AMP
<0.507 µg/L 0.507 5.152-Nitrophenol 1 09/28/23 11:28 V38427AMP
<1.27 µg/L 1.27 10.34-Nitrophenol 1 09/28/23 11:28 V38427AMP
<1.13 µg/L 1.13 5.15N-Nitrosodiphenylamine 1 09/28/23 11:28 V38427AMP
<0.660 µg/L 0.660 5.15N-Nitroso-di-n-propylamine 1 09/28/23 11:28 V38427AMP
<1.47 µg/L 1.47 5.15Pentachlorophenol 1 09/28/23 11:28 V38427AMP
<0.440 µg/L 0.440 2.06Phenanthrene 1 09/28/23 11:28 V38427AMP
Qualifiers/Definitions Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 19 of 58
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-265-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 09/22/2023
Minute Man #3
Report Date : 10/03/2023
Sample ID :
Lab No :
Sampled:MW-12
95986 Matrix:
9/21/2023 11:22
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38382 09/27/23 09:34
<0.670 µg/L 0.670 5.15Phenol 1 09/28/23 11:28 V38427AMP
<0.447 µg/L 0.447 2.06Pyrene 1 09/28/23 11:28 V38427AMP
<2.28 µg/L 2.28 5.151,2,4-Trichlorobenzene 1 09/28/23 11:28 V38427AMP
<1.36 µg/L 1.36 5.152,4,6-Trichlorophenol 1 09/28/23 11:28 V38427AMP
625.1Surrogate: Phenol-d5 24.7 Limits: 10-63%09/28/23 11:281 AMP
Surrogate: 2-Fluorobiphenyl 66.0 Limits: 49-118%09/28/23 11:281 AMP V38427
Surrogate: 2-Fluorophenol 35.6 Limits: 22-84%09/28/23 11:281 AMP V38427
Surrogate: Nitrobenzene-d5 56.1 Limits: 43-123%09/28/23 11:281 AMP V38427
Surrogate: 4-Terphenyl-d14 76.5 Limits: 49-151%09/28/23 11:281 AMP V38427
Surrogate: 2,4,6-Tribromophenol 78.7 Limits: 31-144%09/28/23 11:281 AMP V38427
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V38326 09/26/23 10:25
<0.00343 µg/L 0.00343 0.0208
1,2-Dibromoethane 1 09/26/23 13:51 V38379TJW
Qualifiers/Definitions Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 20 of 58
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-265-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 09/22/2023
Minute Man #3
Report Date : 10/03/2023
Sample ID :
Lab No :
Sampled:MW-12
95986 Matrix:
9/21/2023 11:22
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
584 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 09/25/23 23:57
1090 µg/L 258 500Aliphatics C9-C12 (Adjusted)10 09/26/23 10:05
1050 µg/L 40.2 500Aromatic C9-C10 (Adjusted)10 09/26/23 10:05
<61.2 µg/L 61.2 250Aromatic C11-C22 (Adjusted)1 09/28/23 11:28
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V38500 09/29/23 10:10
<28.2 µg/L 28.2 350Aliphatic C9-C18 1 09/30/23 17:51 V38527AMP
<124 µg/L 124 500Aliphatic C19-C36 1 09/30/23 17:51 V38527AMP
71.9 J
µg/L 61.2 250
Aromatic C11-C22 1 09/30/23 17:51 V38527AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene 80.3 Limits: 40-140%09/30/23 17:511 AMP
MADEP-EPHSurrogate: Chlorooctadecane 56.0 Limits: 40-140%09/30/23 17:511 AMP
MADEP-EPHSurrogate: OTP Surrogate 63.8 Limits: 40-140%09/30/23 17:511 AMP
Surrogate: 2-Fluorobiphenyl 91.0 Limits: 40-140%09/30/23 17:511 AMP V38527
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V38340 09/25/23 08:00
621 µg/L 11.5 50.0Aliphatic C5-C8 1 09/25/23 23:57 V38341TBL
3390 µg/L 258 500Aliphatic C9-C12 10 09/26/23 10:05 V38341TBL
Qualifiers/Definitions Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 21 of 58
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-265-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 09/22/2023
Minute Man #3
Report Date : 10/03/2023
Sample ID :
Lab No :
Sampled:MW-12
95986 Matrix:
9/21/2023 11:22
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V38340 09/25/23 08:00
1050 µg/L 40.2 500Aromatic C9-C10 10 09/26/23 10:05 V38341TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)105 Limits: 70-130%09/25/23 23:571 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)84.7 Limits: 70-130%09/25/23 23:571 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)107 Limits: 70-130%09/26/23 10:0510 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)101 Limits: 70-130%09/26/23 10:0510 TBL
Qualifiers/Definitions Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 22 of 58
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-265-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 09/22/2023
Minute Man #3
Report Date : 10/03/2023
Sample ID :
Lab No :
Sampled:MW-13
95987 Matrix:
9/21/2023 11:49
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 09/28/23 03:56 6200BMSA
0.002 J mg/L 0.002 0.006Lead 1 09/27/23 00:32 6010DJKC
Qualifiers/Definitions Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 23 of 58
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-265-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 09/22/2023
Minute Man #3
Report Date : 10/03/2023
Sample ID :
Lab No :
Sampled:MW-13
95987 Matrix:
9/21/2023 11:49
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38464 09/27/23 14:00 V38530 09/28/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 09/28/23 03:56 V38465MSA
0.631 µg/L 0.180 0.500Benzene 1 09/28/23 03:56 V38465MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 09/28/23 03:56 V38465MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 09/28/23 03:56 V38465MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 09/28/23 03:56 V38465MSA
<1.50 µg/L 1.50 5.00Bromoform 1 09/28/23 03:56 V38465MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 09/28/23 03:56 V38465MSA
5.38 µg/L 0.180 0.500n-Butylbenzene 1 09/28/23 03:56 V38465MSA
1.65 µg/L 0.200 0.500sec-Butyl benzene 1 09/28/23 03:56 V38465MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 09/28/23 03:56 V38465MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 09/28/23 03:56 V38465MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 09/28/23 03:56 V38465MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 09/28/23 03:56 V38465MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 09/28/23 03:56 V38465MSA
<0.220 µg/L 0.220 0.500Chloroform 1 09/28/23 03:56 V38465MSA
<0.220 M µg/L 0.220 0.500Chloromethane 1 09/28/23 03:56 V38465MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 09/28/23 03:56 V38465MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 09/28/23 03:56 V38465MSA
<0.500 M µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 09/28/23 03:56 V38465MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 09/28/23 03:56 V38465MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 09/28/23 03:56 V38465MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 09/28/23 03:56 V38465MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 09/28/23 03:56 V38465MSA
Qualifiers/Definitions Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 24 of 58
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-265-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 09/22/2023
Minute Man #3
Report Date : 10/03/2023
Sample ID :
Lab No :
Sampled:MW-13
95987 Matrix:
9/21/2023 11:49
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38464 09/27/23 14:00 V38530 09/28/23 09:00
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 09/28/23 03:56 V38465MSA
<1.20 M µg/L 1.20 5.00Dichlorodifluoromethane 1 09/28/23 03:56 V38465MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 09/28/23 03:56 V38465MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 09/28/23 03:56 V38465MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 09/28/23 03:56 V38465MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 09/28/23 03:56 V38465MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 09/28/23 03:56 V38465MSA
<0.190 M µg/L 0.190 0.5001,2-Dichloropropane 1 09/28/23 03:56 V38465MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 09/28/23 03:56 V38465MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 09/28/23 03:56 V38465MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 09/28/23 03:56 V38465MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 09/28/23 03:56 V38465MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 09/28/23 03:56 V38465MSA
<42.0 µg/L 42.0 200Ethanol 1 09/28/23 03:56 V38465MSA
46.0 µg/L 0.170 0.500Ethylbenzene 1 09/28/23 03:56 V38465MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 09/28/23 03:56 V38465MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 09/28/23 03:56 V38465MSA
6.42 µg/L 0.180 0.500Isopropylbenzene 1 09/28/23 03:56 V38465MSA
2.15 µg/L 0.089 0.5004-Isopropyl toluene 1 09/28/23 03:56 V38465MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 09/28/23 03:56 V38465MSA
0.213 J µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 09/28/23 03:56 V38465MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 09/28/23 03:56 V38465MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 09/28/23 03:56 V38465MSA
Qualifiers/Definitions Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 25 of 58
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-265-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 09/22/2023
Minute Man #3
Report Date : 10/03/2023
Sample ID :
Lab No :
Sampled:MW-13
95987 Matrix:
9/21/2023 11:49
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38464 09/27/23 14:00 V38530 09/28/23 09:00
53.1 µg/L 0.470 1.00Naphthalene 1 09/28/23 03:56 V38465MSA
16.0 µg/L 0.190 0.500n-Propylbenzene 1 09/28/23 03:56 V38465MSA
<0.220 µg/L 0.220 0.500Styrene 1 09/28/23 03:56 V38465MSA
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 09/28/23 03:56 V38465MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 09/28/23 03:56 V38465MSA
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 09/28/23 03:56 V38465MSA
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 09/28/23 03:56 V38465MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 09/28/23 03:56 V38465MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 09/28/23 03:56 V38465MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 09/28/23 03:56 V38465MSA
8.85 µg/L 0.220 0.500Toluene 1 09/28/23 03:56 V38465MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 09/28/23 03:56 V38465MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 09/28/23 03:56 V38465MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 09/28/23 03:56 V38465MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 09/28/23 03:56 V38465MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 09/28/23 03:56 V38465MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 09/28/23 03:56 V38465MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 09/28/23 03:56 V38465MSA
336 µg/L 1.90 5.001,2,4-Trimethylbenzene 10 09/28/23 20:37 V38531MSA
109 µg/L 1.80 5.001,3,5-Trimethylbenzene 10 09/28/23 20:37 V38531MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 09/28/23 03:56 V38465MSA
<0.170 M µg/L 0.170 0.500Vinyl Chloride 1 09/28/23 03:56 V38465MSA
85.0 µg/L 2.10 5.00o-Xylene 10 09/28/23 20:37 V38531MSA
Qualifiers/Definitions Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 26 of 58
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-265-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 09/22/2023
Minute Man #3
Report Date : 10/03/2023
Sample ID :
Lab No :
Sampled:MW-13
95987 Matrix:
9/21/2023 11:49
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38464 09/27/23 14:00 V38530 09/28/23 09:00
216 µg/L 4.20 10.0m,p-Xylene 10 09/28/23 20:37 V38531MSA
301 µg/L 2.10 5.00Xylene (Total)10 09/28/23 20:37 V38531
Surrogate: 4-Bromofluorobenzene 90.4 Limits: 70-130%09/28/23 03:561 MSA V38465
Surrogate: Dibromofluoromethane 98.4 Limits: 70-130%09/28/23 03:561 MSA V38465
Surrogate: 1,2-Dichloroethane - d4 109 Limits: 70-130%09/28/23 03:561 MSA V38465
Surrogate: Toluene-d8 93.0 Limits: 70-130%09/28/23 03:561 MSA V38465
Surrogate: 4-Bromofluorobenzene 84.6 Limits: 70-130%09/28/23 20:3710 MSA V38531
Surrogate: Dibromofluoromethane 98.2 Limits: 70-130%09/28/23 20:3710 MSA V38531
Surrogate: 1,2-Dichloroethane - d4 103 Limits: 70-130%09/28/23 20:3710 MSA V38531
Surrogate: Toluene-d8 95.4 Limits: 70-130%09/28/23 20:3710 MSA V38531
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38382 09/27/23 09:34
<0.306 µg/L 0.306 2.03
Acenaphthene 1 09/28/23 11:50 V38427AMP
<0.301 µg/L 0.301 2.03Acenaphthylene 1 09/28/23 11:50 V38427AMP
<0.848 µg/L 0.848 2.03Anthracene 1 09/28/23 11:50 V38427AMP
<1.35 µg/L 1.35 10.2Benzidine 1 09/28/23 11:50 V38427AMP
<0.646 µg/L 0.646 2.03Benzo(a)anthracene 1 09/28/23 11:50 V38427AMP
<1.04 µg/L 1.04 2.03
Benzo(a)pyrene 1 09/28/23 11:50 V38427AMP
<2.53 µg/L 2.53 5.08Benzo(b)fluoranthene 1 09/28/23 11:50 V38427AMP
<1.03 µg/L 1.03 5.08Benzo(g,h,i)perylene 1 09/28/23 11:50 V38427AMP
Qualifiers/Definitions Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 27 of 58
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-265-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 09/22/2023
Minute Man #3
Report Date : 10/03/2023
Sample ID :
Lab No :
Sampled:MW-13
95987 Matrix:
9/21/2023 11:49
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38382 09/27/23 09:34
<2.02 µg/L 2.02 5.08Benzo(k)fluoranthene 1 09/28/23 11:50 V38427AMP
<1.12 µg/L 1.12 10.2Benzoic Acid 1 09/28/23 11:50 V38427AMP
<0.694 µg/L 0.694 5.08Benzyl alcohol 1 09/28/23 11:50 V38427AMP
<0.475 µg/L 0.475 5.08Bis(2-Chloroethoxy)methane 1 09/28/23 11:50 V38427AMP
<1.06 µg/L 1.06 5.08Bis(2-Chloroethyl)ether 1 09/28/23 11:50 V38427AMP
<1.10 µg/L 1.10 5.08Bis(2-Chloroisopropyl)ether 1 09/28/23 11:50 V38427AMP
<3.53 µg/L 3.53 10.2Bis(2-ethylhexyl)phthalate 1 09/28/23 11:50 V38427AMP
<1.13 µg/L 1.13 5.084-Bromophenyl phenyl ether 1 09/28/23 11:50 V38427AMP
<1.86 µg/L 1.86 5.08Butyl benzyl phthalate 1 09/28/23 11:50 V38427AMP
<1.20 µg/L 1.20 5.084-Chloro-3-methylphenol 1 09/28/23 11:50 V38427AMP
<7.49 µg/L 7.49 20.32-Chloronaphthalene 1 09/28/23 11:50 V38427AMP
<0.956 µg/L 0.956 10.22-Chlorophenol 1 09/28/23 11:50 V38427AMP
<1.74 µg/L 1.74 5.084-Chlorophenyl phenyl ether 1 09/28/23 11:50 V38427AMP
<0.411 µg/L 0.411 2.03Chrysene 1 09/28/23 11:50 V38427AMP
<0.440 µg/L 0.440 2.03Dibenz(a,h)anthracene 1 09/28/23 11:50 V38427AMP
<0.869 µg/L 0.869 5.08Dibenzofuran 1 09/28/23 11:50 V38427AMP
<2.03 µg/L 2.03 5.081,2-Dichlorobenzene 1 09/28/23 11:50 V38427AMP
<2.03 µg/L 2.03 5.081,3-Dichlorobenzene 1 09/28/23 11:50 V38427AMP
<2.08 µg/L 2.08 5.081,4-Dichlorobenzene 1 09/28/23 11:50 V38427AMP
<1.92 µg/L 1.92 5.083,3'-Dichlorobenzidine 1 09/28/23 11:50 V38427AMP
<1.49 µg/L 1.49 10.22,4-Dichlorophenol 1 09/28/23 11:50 V38427AMP
<0.756 µg/L 0.756 5.08Diethyl phthalate 1 09/28/23 11:50 V38427AMP
<0.954 µg/L 0.954 5.08Dimethyl phthalate 1 09/28/23 11:50 V38427AMP
Qualifiers/Definitions Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 28 of 58
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-265-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 09/22/2023
Minute Man #3
Report Date : 10/03/2023
Sample ID :
Lab No :
Sampled:MW-13
95987 Matrix:
9/21/2023 11:49
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38382 09/27/23 09:34
<1.59 µg/L 1.59 20.32,4-Dimethylphenol 1 09/28/23 11:50 V38427AMP
<2.09 µg/L 2.09 5.08Di-n-butyl phthalate 1 09/28/23 11:50 V38427AMP
<2.11 µg/L 2.11 10.24,6-Dinitro-2-methylphenol 1 09/28/23 11:50 V38427AMP
<1.96 µg/L 1.96 10.22,4-Dinitrophenol 1 09/28/23 11:50 V38427AMP
<1.13 µg/L 1.13 5.082,4-Dinitrotoluene 1 09/28/23 11:50 V38427AMP
<0.821 µg/L 0.821 5.082,6-Dinitrotoluene 1 09/28/23 11:50 V38427AMP
<1.68 µg/L 1.68 5.08Di-n-Octyl Phthalate 1 09/28/23 11:50 V38427AMP
<0.253 µg/L 0.253 2.03Fluoranthene 1 09/28/23 11:50 V38427AMP
<0.819 µg/L 0.819 2.03Fluorene 1 09/28/23 11:50 V38427AMP
<0.994 µg/L 0.994 5.08Hexachlorobenzene 1 09/28/23 11:50 V38427AMP
<2.77 µg/L 2.77 5.08Hexachlorobutadiene 1 09/28/23 11:50 V38427AMP
<2.08 µg/L 2.08 5.08Hexachlorocyclopentadiene 1 09/28/23 11:50 V38427AMP
<1.79 µg/L 1.79 5.08Hexachloroethane 1 09/28/23 11:50 V38427AMP
<0.484 µg/L 0.484 2.03Indeno(1,2,3-cd)pyrene 1 09/28/23 11:50 V38427AMP
<0.451 µg/L 0.451 5.08Isophorone 1 09/28/23 11:50 V38427AMP
12.3 µg/L 0.738 2.03Naphthalene 1 09/28/23 11:50 V38427AMP
<0.919 µg/L 0.919 5.08Nitrobenzene 1 09/28/23 11:50 V38427AMP
<0.500 µg/L 0.500 5.082-Nitrophenol 1 09/28/23 11:50 V38427AMP
<1.25 µg/L 1.25 10.24-Nitrophenol 1 09/28/23 11:50 V38427AMP
<1.12 µg/L 1.12 5.08N-Nitrosodiphenylamine 1 09/28/23 11:50 V38427AMP
<0.651 µg/L 0.651 5.08N-Nitroso-di-n-propylamine 1 09/28/23 11:50 V38427AMP
<1.45 µg/L 1.45 5.08Pentachlorophenol 1 09/28/23 11:50 V38427AMP
<0.434 µg/L 0.434 2.03Phenanthrene 1 09/28/23 11:50 V38427AMP
Qualifiers/Definitions Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 29 of 58
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-265-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 09/22/2023
Minute Man #3
Report Date : 10/03/2023
Sample ID :
Lab No :
Sampled:MW-13
95987 Matrix:
9/21/2023 11:49
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38382 09/27/23 09:34
<0.661 µg/L 0.661 5.08Phenol 1 09/28/23 11:50 V38427AMP
<0.440 µg/L 0.440 2.03Pyrene 1 09/28/23 11:50 V38427AMP
<2.25 µg/L 2.25 5.081,2,4-Trichlorobenzene 1 09/28/23 11:50 V38427AMP
<1.34 µg/L 1.34 5.082,4,6-Trichlorophenol 1 09/28/23 11:50 V38427AMP
625.1Surrogate: Phenol-d5 24.3 Limits: 10-63%09/28/23 11:501 AMP
Surrogate: 2-Fluorobiphenyl 64.4 Limits: 49-118%09/28/23 11:501 AMP V38427
Surrogate: 2-Fluorophenol 36.0 Limits: 22-84%09/28/23 11:501 AMP V38427
Surrogate: Nitrobenzene-d5 55.9 Limits: 43-123%09/28/23 11:501 AMP V38427
Surrogate: 4-Terphenyl-d14 74.0 Limits: 49-151%09/28/23 11:501 AMP V38427
Surrogate: 2,4,6-Tribromophenol 73.7 Limits: 31-144%09/28/23 11:501 AMP V38427
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V38326 09/26/23 10:25
<0.00347 µg/L 0.00347 0.0210
1,2-Dibromoethane 1 09/26/23 14:11 V38379TJW
Qualifiers/Definitions Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 30 of 58
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-265-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 09/22/2023
Minute Man #3
Report Date : 10/03/2023
Sample ID :
Lab No :
Sampled:MW-13
95987 Matrix:
9/21/2023 11:49
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
353 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 09/26/23 00:21
1000 µg/L 258 500Aliphatics C9-C12 (Adjusted)1 09/26/23 10:29
711 µg/L 40.2 500Aromatic C9-C10 (Adjusted)10 09/26/23 10:29
<61.2 µg/L 61.2 250Aromatic C11-C22 (Adjusted)1 09/28/23 11:50
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V38500 09/29/23 10:10
<28.2 µg/L 28.2 350Aliphatic C9-C18 1 09/30/23 18:27 V38527AMP
<124 µg/L 124 500Aliphatic C19-C36 1 09/30/23 18:27 V38527AMP
62.6 J
µg/L 61.2 250
Aromatic C11-C22 1 09/30/23 18:27 V38527AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene 79.3 Limits: 40-140%09/30/23 18:271 AMP
MADEP-EPHSurrogate: Chlorooctadecane 68.1 Limits: 40-140%09/30/23 18:271 AMP
MADEP-EPHSurrogate: OTP Surrogate 64.8 Limits: 40-140%09/30/23 18:271 AMP
Surrogate: 2-Fluorobiphenyl 87.3 Limits: 40-140%09/30/23 18:271 AMP V38527
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V38340 09/25/23 08:00
362 µg/L 11.5 50.0Aliphatic C5-C8 1 09/26/23 00:21 V38341TBL
2060 µg/L 258 500Aliphatic C9-C12 10 09/26/23 10:29 V38341TBL
Qualifiers/Definitions Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 31 of 58
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-265-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #3148 Received : 09/22/2023
Minute Man #3
Report Date : 10/03/2023
Sample ID :
Lab No :
Sampled:MW-13
95987 Matrix:
9/21/2023 11:49
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V38340 09/25/23 08:00
711 µg/L 40.2 500Aromatic C9-C10 10 09/26/23 10:29 V38341TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)100 Limits: 70-130%09/26/23 00:211 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)92.5 Limits: 70-130%09/26/23 00:211 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)102 Limits: 70-130%09/26/23 10:2910 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)103 Limits: 70-130%09/26/23 10:2910 TBL
Qualifiers/Definitions Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 32 of 58
SampleID Report LabNo
LRB‐V38382 23‐265‐0005 LRB
Paramater Result Units
Dilution
Factor Method AnalysisDate/Time Analyst BatchID
NoTICsDetected N.D. ug/L
1 625 9/28/20239:35 APANN V38427
SampleID Report LabNo
MW‐12 23‐265‐0005 95986
Paramater Result Units
Dilution
Factor Method AnalysisDate/Time Analyst BatchID
Ethylbenzene 30670 ug/L
1 625 9/28/202311:28 APANN V38427
Benzene,dimethyl‐95670 ug/L
1 625 9/28/202311:28 APANN V38427
Benzene,1‐ethyl‐3‐methyl‐86090 ug/L
1 625 9/28/202311:28 APANN V38427
Benzene,1‐ethyl‐4‐methyl‐35560 ug/L
1 625 9/28/202311:28 APANN V38427
Benzene,1,2,3‐trimethyl‐49940 ug/L
1 625 9/28/202311:28 APANN V38427
Benzene,1,2,4‐trimethyl‐151500 ug/L
1 625 9/28/202311:28 APANN V38427
Indane 15670 ug/L
1 625 9/28/202311:28 APANN V38427
Benzene,ethyl‐dimethyl‐24100 ug/L
1 625 9/28/202311:28 APANN V38427
SampleID Report LabNo
MW‐13 23‐265‐0005 95987
Paramater Result Units
Dilution
Factor Method AnalysisDate/Time Analyst BatchID
Ethylbenzene 11170 ug/L 1 625 9/28/202311:50 APANN V38427
Benzene,dimethyl‐25270 ug/L
1 625 9/28/202311:50 APANN V38427
Benzene,1‐ethyl‐2‐methyl‐22670 ug/L 1 625 9/28/202311:50 APANN V38427
Benzene,1‐ethyl‐3‐methyl‐23360 ug/L 1 625 9/28/202311:50 APANN V38427
Benzene,1,2,3‐trimethyl‐36820 ug/L
1 625 9/28/202311:50 APANN V38427
Benzene,1,3,5‐trimethyl‐110670 ug/L
1 625 9/28/202311:50 APANN V38427
Indane 15970 ug/L
1 625 9/28/202311:50 APANN V38427
Benzene,4‐ethyl‐1,2‐
dimethyl‐20250 ug/L 1 625 9/28/202311:50 APANN V38427
Benzene,2‐ethyl‐1,4‐
dimethyl‐10730 ug/L 1 625 9/28/202311:50 APANN V38427
Page 33 of 58
Quality Control Data
23-265-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Metals Analysis
6010D
V38390QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3005A
QC Prep:V38250
Associated Lab Samples: 95986, 95987
LRB-V38250 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits
09/26/23 23:260.0060.002<0.002mg/LLead
LCS-V38250Laboratory Control Sample
Parameter LCS %RecLCS
Result
Spike
Conc.Units % Rec
Limits
1060.1060.100mg/LLead 80-120
V 95727-MS-V38250 V 95727-MSD-V38250Matrix Spike & Matrix Spike Duplicate
MS ResultParameter Max
RPD
MS
%Rec
MSD
Result
MSD
SpikeConc.
MS Spike
Conc.ResultUnits %Rec
Limits
MSD
%Rec RPD
0.108 1050.1070.1000.1000.003mg/LLead 104 75-125 0.9 20.0
V 95727-PDS-V38250Post Digestion Spike
Parameter Analyzed%RecoveryPDSResultUnits
09/26/23 23:391110.279mg/LLead
Page 1 of 23Date:10/03/2023 02:04 PM
Page 34 of 58
Quality Control Data
23-265-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38456QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38455
Associated Lab Samples: 95985
LRB-V38455 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
09/27/23 13:3010.01.80<1.80µg/LAcetone
09/27/23 13:300.5000.180<0.180µg/LBenzene
09/27/23 13:300.5000.210<0.210µg/LBromobenzene
09/27/23 13:301.000.420<0.420µg/LBromochloromethane
09/27/23 13:300.5000.160<0.160µg/LBromodichloromethane
09/27/23 13:305.001.50<1.50µg/LBromoform
09/27/23 13:301.000.280<0.280µg/LBromomethane
09/27/23 13:300.5000.180<0.180µg/Ln-Butylbenzene
09/27/23 13:300.5000.200<0.200µg/Lsec-Butyl benzene
09/27/23 13:302.000.920<0.920µg/Ltert-Butyl benzene
09/27/23 13:300.5000.180<0.180µg/LCarbon Tetrachloride
09/27/23 13:300.5000.190<0.190µg/LChlorobenzene
09/27/23 13:300.5000.190<0.190µg/LChlorodibromomethane
09/27/23 13:301.000.430<0.430µg/LChloroethane
09/27/23 13:300.5000.220<0.220µg/LChloroform
09/27/23 13:300.5000.220<0.220µg/LChloromethane
09/27/23 13:300.5000.200<0.200µg/L2-Chlorotoluene
09/27/23 13:300.5000.200<0.200µg/L4-Chlorotoluene
09/27/23 13:300.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
09/27/23 13:302.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
09/27/23 13:300.5000.200<0.200µg/L1,2-Dibromoethane
09/27/23 13:300.5000.230<0.230µg/LDibromomethane
09/27/23 13:300.5000.220<0.220µg/L1,2-Dichlorobenzene
09/27/23 13:300.5000.190<0.190µg/L1,3-Dichlorobenzene
09/27/23 13:300.5000.210<0.210µg/L1,4-Dichlorobenzene
09/27/23 13:305.001.20<1.20µg/LDichlorodifluoromethane
09/27/23 13:300.5000.240<0.240µg/L1,1-Dichloroethane
Page 2 of 23Date:10/03/2023 02:04 PM
Page 35 of 58
Quality Control Data
23-265-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38456QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38455
Associated Lab Samples: 95985
LRB-V38455 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
09/27/23 13:300.5000.150<0.150µg/L1,2-Dichloroethane
09/27/23 13:300.5000.150<0.150µg/L1,1-Dichloroethene
09/27/23 13:300.5000.200<0.200µg/Lcis-1,2-Dichloroethene
09/27/23 13:300.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
09/27/23 13:300.5000.190<0.190µg/L1,2-Dichloropropane
09/27/23 13:300.5000.130<0.130µg/L1,3-Dichloropropane
09/27/23 13:302.000.210<0.210µg/L2,2-Dichloropropane
09/27/23 13:300.5000.200<0.200µg/L1,1-Dichloropropene
09/27/23 13:300.5000.210<0.210µg/Lcis-1,3-Dichloropropene
09/27/23 13:300.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
09/27/23 13:3020042.0<42.0µg/LEthanol
09/27/23 13:300.5000.170<0.170µg/LEthylbenzene
09/27/23 13:303.000.350<0.350µg/LHexachlorobutadiene
09/27/23 13:301.000.380<0.380µg/L2-Hexanone
09/27/23 13:300.5000.180<0.180µg/LIsopropylbenzene
09/27/23 13:300.5000.089<0.089µg/L4-Isopropyl toluene
09/27/23 13:305.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
09/27/23 13:301.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
09/27/23 13:301.000.078<0.078µg/L4-Methyl-2-Pentanone
09/27/23 13:302.000.330<0.330µg/LMethylene Chloride
09/27/23 13:301.000.470<0.470µg/LNaphthalene
09/27/23 13:300.5000.190<0.190µg/Ln-Propylbenzene
09/27/23 13:300.5000.220<0.220µg/LStyrene
09/27/23 13:300.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
09/27/23 13:300.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
09/27/23 13:300.5000.220<0.220µg/LTetrachloroethene
09/27/23 13:300.5000.220<0.220µg/LToluene
Page 3 of 23Date:10/03/2023 02:04 PM
Page 36 of 58
Quality Control Data
23-265-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38456QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38455
Associated Lab Samples: 95985
LRB-V38455 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
09/27/23 13:300.5000.380<0.380µg/L1,2,3-Trichlorobenzene
09/27/23 13:300.5000.310<0.310µg/L1,2,4-Trichlorobenzene
09/27/23 13:300.5000.160<0.160µg/L1,1,1-Trichloroethane
09/27/23 13:300.5000.096<0.096µg/L1,1,2-Trichloroethane
09/27/23 13:300.5000.180<0.180µg/LTrichloroethene
09/27/23 13:300.5000.180<0.180µg/LTrichlorofluoromethane
09/27/23 13:300.5000.270<0.270µg/L1,2,3-Trichloropropane
09/27/23 13:300.5000.190<0.190µg/L1,2,4-Trimethylbenzene
09/27/23 13:300.5000.180<0.180µg/L1,3,5-Trimethylbenzene
09/27/23 13:305.001.00<1.00µg/LVinyl Acetate
09/27/23 13:300.5000.170<0.170µg/LVinyl Chloride
09/27/23 13:300.5000.210<0.210µg/Lo-Xylene
09/27/23 13:301.000.420<0.420µg/Lm,p-Xylene
09/27/23 13:304-Bromofluorobenzene (S)91.0 70-130
09/27/23 13:30Dibromofluoromethane (S)101 70-130
09/27/23 13:301,2-Dichloroethane - d4 (S)110 70-130
09/27/23 13:30Toluene-d8 (S)96.8 70-130
LCS-V38455 LCSD-V38455Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
40.5 10110642.340.0µg/LAcetone 40-160 4.3 20.0
19.3 96.598.019.620.0µg/LBenzene 70-130 1.5 20.0
20.8 10410420.820.0µg/LBromobenzene 70-130 0.0 20.0
21.7 10910621.220.0µg/LBromochloromethane 70-130 2.3 20.0
21.2 10610821.620.0µg/LBromodichloromethane 70-130 1.8 20.0
Page 4 of 23Date:10/03/2023 02:04 PM
Page 37 of 58
Quality Control Data
23-265-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38456QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38455
LCS-V38455 LCSD-V38455Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
22.8 11411823.620.0µg/LBromoform 70-130 3.4 20.0
19.3 96.593.518.720.0µg/LBromomethane 60-140 3.1 20.0
21.9 11011122.120.0µg/Ln-Butylbenzene 70-130 0.9 20.0
21.0 10510921.720.0µg/Lsec-Butyl benzene 70-130 3.2 20.0
21.6 10811022.020.0µg/Ltert-Butyl benzene 70-130 1.8 20.0
26.7 134*132*26.420.0µg/LCarbon Tetrachloride 70-130 1.1 20.0
22.3 11210821.520.0µg/LChlorobenzene 70-130 3.6 20.0
23.5 11812024.020.0µg/LChlorodibromomethane 70-130 2.1 20.0
14.5 72.567.513.520.0µg/LChloroethane 60-140 7.1 20.0
21.0 10510921.720.0µg/LChloroform 70-130 3.2 20.0
11.4 57.0*57.0*11.420.0µg/LChloromethane 60-140 0.0 20.0
19.9 99.510220.420.0µg/L2-Chlorotoluene 70-130 2.4 20.0
20.4 10210521.020.0µg/L4-Chlorotoluene 70-130 2.8 20.0
15.2 76.077.515.520.0µg/LDi-Isopropyl Ether (DIPE)70-130 1.9 20.0
21.6 10811923.820.0µg/L1,2-Dibromo-3-Chloropropane 70-130 9.6 20.0
18.7 93.597.519.520.0µg/L1,2-Dibromoethane 70-130 4.1 20.0
20.5 10310821.520.0µg/LDibromomethane 70-130 4.7 20.0
22.0 11011222.420.0µg/L1,2-Dichlorobenzene 70-130 1.8 20.0
22.1 11111623.120.0µg/L1,3-Dichlorobenzene 70-130 4.4 20.0
22.0 11011022.020.0µg/L1,4-Dichlorobenzene 70-130 0.0 20.0
10.9 54.5*52.5*10.520.0µg/LDichlorodifluoromethane 60-140 3.7 20.0
19.4 97.096.519.320.0µg/L1,1-Dichloroethane 70-130 0.5 20.0
21.8 10911021.920.0µg/L1,2-Dichloroethane 70-130 0.4 20.0
20.3 10210520.920.0µg/L1,1-Dichloroethene 70-130 2.9 20.0
18.9 94.598.519.720.0µg/Lcis-1,2-Dichloroethene 70-130 4.1 20.0
19.8 99.010220.320.0µg/Ltrans-1,2-Dichloroethene 70-130 2.4 20.0
Page 5 of 23* QC Fail Date:10/03/2023 02:04 PM
Page 38 of 58
Quality Control Data
23-265-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38456QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38455
LCS-V38455 LCSD-V38455Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
15.8 79.084.016.820.0µg/L1,2-Dichloropropane 70-130 6.1 20.0
18.7 93.596.519.320.0µg/L1,3-Dichloropropane 70-130 3.1 20.0
24.7 12412124.220.0µg/L2,2-Dichloropropane 70-130 2.0 20.0
22.2 11111322.520.0µg/L1,1-Dichloropropene 70-130 1.3 20.0
19.8 99.010120.220.0µg/Lcis-1,3-Dichloropropene 70-130 2.0 20.0
21.2 10610721.420.0µg/Ltrans-1,3-Dichloropropene 70-130 0.9 20.0
366 73.283.6418500µg/LEthanol 60-140 13.2 20.0
20.7 10410520.920.0µg/LEthylbenzene 70-130 0.9 20.0
26.7 134*13026.020.0µg/LHexachlorobutadiene 70-130 2.6 20.0
19.2 96.089.517.920.0µg/L2-Hexanone 60-140 7.0 20.0
22.6 11311322.620.0µg/LIsopropylbenzene 70-130 0.0 20.0
23.2 11611723.320.0µg/L4-Isopropyl toluene 70-130 0.4 20.0
16.9 84.590.018.020.0µg/LMethyl Ethyl Ketone (MEK)60-140 6.3 20.0
19.8 99.010721.420.0µg/LMethyl tert-butyl ether (MTBE)70-130 7.7 20.0
15.9 79.580.516.120.0µg/L4-Methyl-2-Pentanone 60-140 1.2 20.0
15.3 76.583.016.620.0µg/LMethylene Chloride 70-130 8.1 20.0
22.8 11411522.920.0µg/LNaphthalene 70-130 0.4 20.0
20.8 10410420.820.0µg/Ln-Propylbenzene 70-130 0.0 20.0
21.9 11011222.420.0µg/LStyrene 70-130 2.2 20.0
23.9 12011322.620.0µg/L1,1,1,2-Tetrachloroethane 70-130 5.5 20.0
17.9 89.592.518.520.0µg/L1,1,2,2-Tetrachloroethane 70-130 3.2 20.0
24.0 12011422.820.0µg/LTetrachloroethene 70-130 5.1 20.0
19.6 98.010220.420.0µg/LToluene 70-130 4.0 20.0
29.8 149*135*27.020.0µg/L1,2,3-Trichlorobenzene 70-130 9.8 20.0
26.7 134*132*26.320.0µg/L1,2,4-Trichlorobenzene 70-130 1.5 20.0
23.2 11612224.320.0µg/L1,1,1-Trichloroethane 70-130 4.6 20.0
Page 6 of 23* QC Fail Date:10/03/2023 02:04 PM
Page 39 of 58
Quality Control Data
23-265-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38456QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38455
LCS-V38455 LCSD-V38455Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
19.6 98.098.019.620.0µg/L1,1,2-Trichloroethane 70-130 0.0 20.0
21.5 10810520.920.0µg/LTrichloroethene 70-130 2.8 20.0
23.3 11711823.620.0µg/LTrichlorofluoromethane 60-140 1.2 20.0
20.4 10210621.120.0µg/L1,2,3-Trichloropropane 70-130 3.3 20.0
22.3 11211222.420.0µg/L1,2,4-Trimethylbenzene 70-130 0.4 20.0
22.3 11211523.020.0µg/L1,3,5-Trimethylbenzene 70-130 3.0 20.0
23.9 12014028.020.0µg/LVinyl Acetate 60-140 15.7 20.0
12.5 62.560.512.120.0µg/LVinyl Chloride 60-140 3.2 20.0
21.1 10610521.020.0µg/Lo-Xylene 70-130 0.4 20.0
46.0 11511345.040.0µg/Lm,p-Xylene 70-130 2.1 20.0
92.892.24-Bromofluorobenzene (S)70-130
97.699.2Dibromofluoromethane (S)70-130
1041091,2-Dichloroethane - d4 (S)70-130
98.898.0Toluene-d8 (S)70-130
Page 7 of 23Date:10/03/2023 02:04 PM
Page 40 of 58
Quality Control Data
23-265-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38465QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38464
Associated Lab Samples: 95986, 95987
LRB-V38464 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
09/28/23 02:1710.01.80<1.80µg/LAcetone
09/28/23 02:170.5000.180<0.180µg/LBenzene
09/28/23 02:170.5000.210<0.210µg/LBromobenzene
09/28/23 02:171.000.420<0.420µg/LBromochloromethane
09/28/23 02:170.5000.160<0.160µg/LBromodichloromethane
09/28/23 02:175.001.50<1.50µg/LBromoform
09/28/23 02:171.000.280<0.280µg/LBromomethane
09/28/23 02:170.5000.180<0.180µg/Ln-Butylbenzene
09/28/23 02:170.5000.200<0.200µg/Lsec-Butyl benzene
09/28/23 02:172.000.920<0.920µg/Ltert-Butyl benzene
09/28/23 02:170.5000.180<0.180µg/LCarbon Tetrachloride
09/28/23 02:170.5000.190<0.190µg/LChlorobenzene
09/28/23 02:170.5000.190<0.190µg/LChlorodibromomethane
09/28/23 02:171.000.430<0.430µg/LChloroethane
09/28/23 02:170.5000.220<0.220µg/LChloroform
09/28/23 02:170.5000.220<0.220µg/LChloromethane
09/28/23 02:170.5000.200<0.200µg/L2-Chlorotoluene
09/28/23 02:170.5000.200<0.200µg/L4-Chlorotoluene
09/28/23 02:170.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
09/28/23 02:172.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
09/28/23 02:170.5000.230<0.230µg/LDibromomethane
09/28/23 02:170.5000.220<0.220µg/L1,2-Dichlorobenzene
09/28/23 02:170.5000.190<0.190µg/L1,3-Dichlorobenzene
09/28/23 02:170.5000.210<0.210µg/L1,4-Dichlorobenzene
09/28/23 02:175.001.20<1.20µg/LDichlorodifluoromethane
09/28/23 02:170.5000.240<0.240µg/L1,1-Dichloroethane
09/28/23 02:170.5000.150<0.150µg/L1,2-Dichloroethane
Page 8 of 23Date:10/03/2023 02:04 PM
Page 41 of 58
Quality Control Data
23-265-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38465QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38464
Associated Lab Samples: 95986, 95987
LRB-V38464 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
09/28/23 02:170.5000.150<0.150µg/L1,1-Dichloroethene
09/28/23 02:170.5000.200<0.200µg/Lcis-1,2-Dichloroethene
09/28/23 02:170.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
09/28/23 02:170.5000.190<0.190µg/L1,2-Dichloropropane
09/28/23 02:170.5000.130<0.130µg/L1,3-Dichloropropane
09/28/23 02:172.000.210<0.210µg/L2,2-Dichloropropane
09/28/23 02:170.5000.200<0.200µg/L1,1-Dichloropropene
09/28/23 02:170.5000.210<0.210µg/Lcis-1,3-Dichloropropene
09/28/23 02:170.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
09/28/23 02:1720042.0<42.0µg/LEthanol
09/28/23 02:170.5000.170<0.170µg/LEthylbenzene
09/28/23 02:173.000.350<0.350µg/LHexachlorobutadiene
09/28/23 02:171.000.380<0.380µg/L2-Hexanone
09/28/23 02:170.5000.180<0.180µg/LIsopropylbenzene
09/28/23 02:170.5000.089<0.089µg/L4-Isopropyl toluene
09/28/23 02:175.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
09/28/23 02:171.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
09/28/23 02:171.000.078<0.078µg/L4-Methyl-2-Pentanone
09/28/23 02:172.000.330<0.330µg/LMethylene Chloride
09/28/23 02:171.000.470<0.470µg/LNaphthalene
09/28/23 02:170.5000.190<0.190µg/Ln-Propylbenzene
09/28/23 02:170.5000.220<0.220µg/LStyrene
09/28/23 02:1710.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
09/28/23 02:1710.00.350<0.350µg/Ltert-Butyl formate (TBF)
09/28/23 02:1710.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
09/28/23 02:1710.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
09/28/23 02:170.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
Page 9 of 23Date:10/03/2023 02:04 PM
Page 42 of 58
Quality Control Data
23-265-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38465QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38464
Associated Lab Samples: 95986, 95987
LRB-V38464 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
09/28/23 02:170.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
09/28/23 02:170.5000.220<0.220µg/LTetrachloroethene
09/28/23 02:170.5000.220<0.220µg/LToluene
09/28/23 02:170.5000.380<0.380µg/L1,2,3-Trichlorobenzene
09/28/23 02:170.5000.310<0.310µg/L1,2,4-Trichlorobenzene
09/28/23 02:170.5000.160<0.160µg/L1,1,1-Trichloroethane
09/28/23 02:170.5000.096<0.096µg/L1,1,2-Trichloroethane
09/28/23 02:170.5000.180<0.180µg/LTrichloroethene
09/28/23 02:170.5000.180<0.180µg/LTrichlorofluoromethane
09/28/23 02:170.5000.270<0.270µg/L1,2,3-Trichloropropane
09/28/23 02:175.001.00<1.00µg/LVinyl Acetate
09/28/23 02:170.5000.170<0.170µg/LVinyl Chloride
09/28/23 02:1710.01.00<1.00µg/L3,3-Dimethyl-1-butanol
09/28/23 02:174-Bromofluorobenzene (S)90.2 70-130
09/28/23 02:17Dibromofluoromethane (S)102 70-130
09/28/23 02:171,2-Dichloroethane - d4 (S)110 70-130
09/28/23 02:17Toluene-d8 (S)94.4 70-130
LCS-V38464 LCSD-V38464Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
35.0 87.584.733.940.0µg/LAcetone 40-160 3.1 20.0
17.8 89.085.017.020.0µg/LBenzene 70-130 4.5 20.0
18.7 93.590.518.120.0µg/LBromobenzene 70-130 3.2 20.0
20.7 10410320.520.0µg/LBromochloromethane 70-130 0.9 20.0
20.5 10310420.720.0µg/LBromodichloromethane 70-130 0.9 20.0
Page 10 of 23Date:10/03/2023 02:04 PM
Page 43 of 58
Quality Control Data
23-265-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38465QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38464
LCS-V38464 LCSD-V38464Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
24.6 12312124.120.0µg/LBromoform 70-130 2.0 20.0
17.6 88.083.016.620.0µg/LBromomethane 60-140 5.8 20.0
19.2 96.096.019.220.0µg/Ln-Butylbenzene 70-130 0.0 20.0
19.1 95.594.518.920.0µg/Lsec-Butyl benzene 70-130 1.0 20.0
20.4 10299.019.820.0µg/Ltert-Butyl benzene 70-130 2.9 20.0
24.5 12312023.920.0µg/LCarbon Tetrachloride 70-130 2.4 20.0
21.6 10810521.020.0µg/LChlorobenzene 70-130 2.8 20.0
22.8 11411222.320.0µg/LChlorodibromomethane 70-130 2.2 20.0
12.2 61.061.512.320.0µg/LChloroethane 60-140 0.8 20.0
19.7 98.599.519.920.0µg/LChloroform 70-130 1.0 20.0
9.22 46.1*44.5*8.9020.0µg/LChloromethane 60-140 3.5 20.0
18.3 91.587.017.420.0µg/L2-Chlorotoluene 70-130 5.0 20.0
18.9 94.592.518.520.0µg/L4-Chlorotoluene 70-130 2.1 20.0
13.0 65.0*67.0*13.420.0µg/LDi-Isopropyl Ether (DIPE)70-130 3.0 20.0
22.3 11212124.120.0µg/L1,2-Dibromo-3-Chloropropane 70-130 7.7 20.0
21.0 10511021.920.0µg/LDibromomethane 70-130 4.1 20.0
21.4 10710521.020.0µg/L1,2-Dichlorobenzene 70-130 1.8 20.0
21.1 10610621.220.0µg/L1,3-Dichlorobenzene 70-130 0.4 20.0
20.9 10510220.420.0µg/L1,4-Dichlorobenzene 70-130 2.4 20.0
10.4 52.0*51.5*10.320.0µg/LDichlorodifluoromethane 60-140 0.9 20.0
17.7 88.585.517.120.0µg/L1,1-Dichloroethane 70-130 3.4 20.0
22.4 11211322.520.0µg/L1,2-Dichloroethane 70-130 0.4 20.0
19.8 99.096.019.220.0µg/L1,1-Dichloroethene 70-130 3.0 20.0
17.8 89.088.017.620.0µg/Lcis-1,2-Dichloroethene 70-130 1.1 20.0
17.6 88.090.518.120.0µg/Ltrans-1,2-Dichloroethene 70-130 2.8 20.0
13.7 68.5*73.514.720.0µg/L1,2-Dichloropropane 70-130 7.0 20.0
Page 11 of 23* QC Fail Date:10/03/2023 02:04 PM
Page 44 of 58
Quality Control Data
23-265-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38465QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38464
LCS-V38464 LCSD-V38464Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
17.6 88.088.517.720.0µg/L1,3-Dichloropropane 70-130 0.5 20.0
20.3 10210320.520.0µg/L2,2-Dichloropropane 70-130 0.9 20.0
20.4 10299.519.920.0µg/L1,1-Dichloropropene 70-130 2.4 20.0
18.0 90.090.518.120.0µg/Lcis-1,3-Dichloropropene 70-130 0.5 20.0
20.4 10210320.520.0µg/Ltrans-1,3-Dichloropropene 70-130 0.4 20.0
381 76.275.8379500µg/LEthanol 60-140 0.5 20.0
19.7 98.596.519.320.0µg/LEthylbenzene 70-130 2.0 20.0
24.9 12512424.820.0µg/LHexachlorobutadiene 70-130 0.4 20.0
15.0 75.077.515.520.0µg/L2-Hexanone 60-140 3.2 20.0
20.4 10299.519.920.0µg/LIsopropylbenzene 70-130 2.4 20.0
21.6 10810721.420.0µg/L4-Isopropyl toluene 70-130 0.9 20.0
14.5 72.570.514.120.0µg/LMethyl Ethyl Ketone (MEK)60-140 2.7 20.0
19.9 99.510320.520.0µg/LMethyl tert-butyl ether (MTBE)70-130 2.9 20.0
14.7 73.573.514.720.0µg/L4-Methyl-2-Pentanone 60-140 0.0 20.0
14.3 71.572.514.520.0µg/LMethylene Chloride 70-130 1.3 20.0
23.8 11912324.620.0µg/LNaphthalene 70-130 3.3 20.0
18.4 92.089.517.920.0µg/Ln-Propylbenzene 70-130 2.7 20.0
20.8 10410420.720.0µg/LStyrene 70-130 0.4 20.0
36.1 90.211144.340.0µg/Ltert-Butyl Alcohol (TBA)40-140 20.3*20.0
24.4 61.061.724.740.0µg/Ltert-Butyl formate (TBF)40-140 1.2 20.0
17.9 89.585.017.020.0µg/Ltert-Amyl Alcohol (TAA)40-140 5.1 20.0
37.3 93.295.238.140.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 2.1 20.0
22.6 11311523.020.0µg/L1,1,1,2-Tetrachloroethane 70-130 1.7 20.0
15.0 75.073.514.720.0µg/L1,1,2,2-Tetrachloroethane 70-130 2.0 20.0
23.5 11811623.220.0µg/LTetrachloroethene 70-130 1.2 20.0
19.0 95.094.018.820.0µg/LToluene 70-130 1.0 20.0
Page 12 of 23* QC Fail Date:10/03/2023 02:04 PM
Page 45 of 58
Quality Control Data
23-265-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38465QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38464
LCS-V38464 LCSD-V38464Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
28.1 141*149*29.820.0µg/L1,2,3-Trichlorobenzene 70-130 5.8 20.0
26.4 132*138*27.520.0µg/L1,2,4-Trichlorobenzene 70-130 4.0 20.0
24.0 12011923.720.0µg/L1,1,1-Trichloroethane 70-130 1.2 20.0
18.6 93.094.518.920.0µg/L1,1,2-Trichloroethane 70-130 1.6 20.0
22.8 11411422.720.0µg/LTrichloroethene 70-130 0.4 20.0
23.2 11611923.820.0µg/LTrichlorofluoromethane 60-140 2.5 20.0
18.3 91.593.018.620.0µg/L1,2,3-Trichloropropane 70-130 1.6 20.0
15.5 77.583.516.720.0µg/LVinyl Acetate 60-140 7.4 20.0
10.4 52.0*51.5*10.320.0µg/LVinyl Chloride 60-140 0.9 20.0
16.0 80.097.519.520.0µg/L3,3-Dimethyl-1-butanol 70-130 19.7 20.0
87.288.64-Bromofluorobenzene (S)70-130
97.4101Dibromofluoromethane (S)70-130
1091111,2-Dichloroethane - d4 (S)70-130
96.697.8Toluene-d8 (S)70-130
Page 13 of 23* QC Fail Date:10/03/2023 02:04 PM
Page 46 of 58
Quality Control Data
23-265-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38531QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38530
Associated Lab Samples: 95986, 95987
LRB-V38530 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
09/28/23 15:160.5000.170<0.170µg/LEthylbenzene
09/28/23 15:160.5000.190<0.190µg/L1,2,4-Trimethylbenzene
09/28/23 15:160.5000.180<0.180µg/L1,3,5-Trimethylbenzene
09/28/23 15:160.5000.210<0.210µg/Lo-Xylene
09/28/23 15:161.000.420<0.420µg/Lm,p-Xylene
09/28/23 15:164-Bromofluorobenzene (S)90.4 70-130
09/28/23 15:16Dibromofluoromethane (S)100 70-130
09/28/23 15:161,2-Dichloroethane - d4 (S)108 70-130
09/28/23 15:16Toluene-d8 (S)90.2 70-130
LCS-V38530 LCSD-V38530Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
20.2 10199.519.920.0µg/LEthylbenzene 70-130 1.4 20.0
22.4 11211122.120.0µg/L1,2,4-Trimethylbenzene 70-130 1.3 20.0
22.2 11111021.920.0µg/L1,3,5-Trimethylbenzene 70-130 1.3 20.0
21.0 10510320.520.0µg/Lo-Xylene 70-130 2.4 20.0
45.0 11311044.140.0µg/Lm,p-Xylene 70-130 2.0 20.0
91.090.64-Bromofluorobenzene (S)70-130
98.6102Dibromofluoromethane (S)70-130
1021061,2-Dichloroethane - d4 (S)70-130
96.296.2Toluene-d8 (S)70-130
Page 14 of 23Date:10/03/2023 02:04 PM
Page 47 of 58
Quality Control Data
23-265-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V38427QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V38382
Associated Lab Samples: 95986, 95987
LRB-V38382 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
09/28/23 09:352.000.302<0.302µg/LAcenaphthene
09/28/23 09:352.000.297<0.297µg/LAcenaphthylene
09/28/23 09:352.000.836<0.836µg/LAnthracene
09/28/23 09:3510.01.32<1.32µg/LBenzidine
09/28/23 09:352.000.637<0.637µg/LBenzo(a)anthracene
09/28/23 09:352.001.02<1.02µg/LBenzo(a)pyrene
09/28/23 09:355.002.49<2.49µg/LBenzo(b)fluoranthene
09/28/23 09:355.001.01<1.01µg/LBenzo(g,h,i)perylene
09/28/23 09:355.001.99<1.99µg/LBenzo(k)fluoranthene
09/28/23 09:3510.01.10<1.10µg/LBenzoic Acid
09/28/23 09:355.000.684<0.684µg/LBenzyl alcohol
09/28/23 09:355.000.468<0.468µg/LBis(2-Chloroethoxy)methane
09/28/23 09:355.001.04<1.04µg/LBis(2-Chloroethyl)ether
09/28/23 09:355.001.08<1.08µg/LBis(2-Chloroisopropyl)ether
09/28/23 09:3510.03.46<3.46µg/LBis(2-ethylhexyl)phthalate
09/28/23 09:355.001.11<1.11µg/L4-Bromophenyl phenyl ether
09/28/23 09:355.001.83<1.83µg/LButyl benzyl phthalate
09/28/23 09:355.001.18<1.18µg/L4-Chloro-3-methylphenol
09/28/23 09:3520.07.38<7.38µg/L2-Chloronaphthalene
09/28/23 09:3510.00.938<0.938µg/L2-Chlorophenol
09/28/23 09:355.001.71<1.71µg/L4-Chlorophenyl phenyl ether
09/28/23 09:352.000.405<0.405µg/LChrysene
09/28/23 09:352.000.434<0.434µg/LDibenz(a,h)anthracene
09/28/23 09:355.000.856<0.856µg/LDibenzofuran
09/28/23 09:355.002.00<2.00µg/L1,2-Dichlorobenzene
09/28/23 09:355.002.00<2.00µg/L1,3-Dichlorobenzene
09/28/23 09:355.002.05<2.05µg/L1,4-Dichlorobenzene
Page 15 of 23Date:10/03/2023 02:04 PM
Page 48 of 58
Quality Control Data
23-265-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V38427QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V38382
Associated Lab Samples: 95986, 95987
LRB-V38382 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
09/28/23 09:355.001.89<1.89µg/L3,3'-Dichlorobenzidine
09/28/23 09:3510.01.46<1.46µg/L2,4-Dichlorophenol
09/28/23 09:355.000.745<0.745µg/LDiethyl phthalate
09/28/23 09:355.000.939<0.939µg/LDimethyl phthalate
09/28/23 09:3520.01.57<1.57µg/L2,4-Dimethylphenol
09/28/23 09:355.002.06<2.06µg/LDi-n-butyl phthalate
09/28/23 09:3510.02.07<2.07µg/L4,6-Dinitro-2-methylphenol
09/28/23 09:3510.01.92<1.92µg/L2,4-Dinitrophenol
09/28/23 09:355.001.11<1.11µg/L2,4-Dinitrotoluene
09/28/23 09:355.000.809<0.809µg/L2,6-Dinitrotoluene
09/28/23 09:355.001.65<1.65µg/LDi-n-Octyl Phthalate
09/28/23 09:352.000.250<0.250µg/LFluoranthene
09/28/23 09:352.000.807<0.807µg/LFluorene
09/28/23 09:355.000.979<0.979µg/LHexachlorobenzene
09/28/23 09:355.002.73<2.73µg/LHexachlorobutadiene
09/28/23 09:355.002.05<2.05µg/LHexachlorocyclopentadiene
09/28/23 09:355.001.76<1.76µg/LHexachloroethane
09/28/23 09:352.000.477<0.477µg/LIndeno(1,2,3-cd)pyrene
09/28/23 09:355.000.444<0.444µg/LIsophorone
09/28/23 09:352.000.728<0.728µg/LNaphthalene
09/28/23 09:355.000.905<0.905µg/LNitrobenzene
09/28/23 09:355.000.493<0.493µg/L2-Nitrophenol
09/28/23 09:3510.01.23<1.23µg/L4-Nitrophenol
09/28/23 09:355.001.10<1.10µg/LN-Nitrosodiphenylamine
09/28/23 09:355.000.641<0.641µg/LN-Nitroso-di-n-propylamine
09/28/23 09:355.001.43<1.43µg/LPentachlorophenol
09/28/23 09:352.000.428<0.428µg/LPhenanthrene
Page 16 of 23Date:10/03/2023 02:04 PM
Page 49 of 58
Quality Control Data
23-265-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V38427QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V38382
Associated Lab Samples: 95986, 95987
LRB-V38382 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
09/28/23 09:355.000.651<0.651µg/LPhenol
09/28/23 09:352.000.434<0.434µg/LPyrene
09/28/23 09:355.002.21<2.21µg/L1,2,4-Trichlorobenzene
09/28/23 09:355.001.32<1.32µg/L2,4,6-Trichlorophenol
09/28/23 09:352-Fluorobiphenyl (S)76.8 49-118
09/28/23 09:352-Fluorophenol (S)42.8 22-84
09/28/23 09:35Nitrobenzene-d5 (S)70.4 43-123
09/28/23 09:354-Terphenyl-d14 (S)84.8 49-151
09/28/23 09:352,4,6-Tribromophenol (S)83.5 31-144
09/28/23 09:35Phenol-d5 (S)28.3 10-63
LCS-V38382 LCSD-V38382Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
37.6 75.275.837.950.0µg/LAcenaphthene 47-145 0.7 20.0
38.9 77.878.239.150.0µg/LAcenaphthylene 33-145 0.5 20.0
41.1 82.282.241.150.0µg/LAnthracene 27-133 0.0 20.0
19.6 39.256.828.450.0µg/LBenzidine 15-150 36.6*20.0
38.9 77.877.438.750.0µg/LBenzo(a)anthracene 33-143 0.5 20.0
48.8 97.697.648.850.0µg/LBenzo(a)pyrene 17-163 0.0 20.0
47.0 94.093.246.650.0µg/LBenzo(b)fluoranthene 24-159 0.8 20.0
44.0 88.086.643.350.0µg/LBenzo(g,h,i)perylene 10-219 1.6 20.0
43.0 86.087.443.750.0µg/LBenzo(k)fluoranthene 11-162 1.6 20.0
17.3 34.625.812.950.0µg/LBenzoic Acid 10-125 29.1*20.0
34.7 69.469.034.550.0µg/LBenzyl alcohol 16-107 0.5 20.0
34.1 68.268.034.050.0µg/LBis(2-Chloroethoxy)methane 33-184 0.2 20.0
Page 17 of 23* QC Fail Date:10/03/2023 02:04 PM
Page 50 of 58
Quality Control Data
23-265-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V38427QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V38382
LCS-V38382 LCSD-V38382Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
32.8 65.667.433.750.0µg/LBis(2-Chloroethyl)ether 12-158 2.7 20.0
32.4 64.866.033.050.0µg/LBis(2-Chloroisopropyl)ether 36-166 1.8 20.0
39.2 78.477.038.550.0µg/LBis(2-ethylhexyl)phthalate 10-158 1.8 20.0
42.5 85.082.841.450.0µg/L4-Bromophenyl phenyl ether 53-127 2.6 20.0
38.5 77.076.238.150.0µg/LButyl benzyl phthalate 10-152 1.0 20.0
35.2 70.470.435.250.0µg/L4-Chloro-3-methylphenol 22-147 0.0 20.0
38.1 76.275.837.950.0µg/L2-Chloronaphthalene 60-118 0.5 20.0
33.5 67.068.434.250.0µg/L2-Chlorophenol 23-134 2.0 20.0
41.5 83.083.241.650.0µg/L4-Chlorophenyl phenyl ether 25-158 0.2 20.0
39.8 79.679.439.750.0µg/LChrysene 17-168 0.2 20.0
38.5 77.078.639.350.0µg/LDibenz(a,h)anthracene 10-227 2.0 20.0
38.7 77.477.838.950.0µg/LDibenzofuran 39-114 0.5 20.0
29.9 59.862.631.350.0µg/L1,2-Dichlorobenzene 32-129 4.5 20.0
29.9 59.860.830.450.0µg/L1,3-Dichlorobenzene 20-124 1.6 20.0
29.1 58.261.230.650.0µg/L1,4-Dichlorobenzene 20-124 5.0 20.0
43.6 87.288.444.250.0µg/L3,3'-Dichlorobenzidine 10-262 1.3 20.0
36.8 73.672.636.350.0µg/L2,4-Dichlorophenol 39-135 1.3 20.0
41.1 82.281.440.750.0µg/LDiethyl phthalate 10-114 0.9 20.0
42.3 84.684.842.450.0µg/LDimethyl phthalate 10-112 0.2 20.0
47.2 94.492.046.050.0µg/L2,4-Dimethylphenol 32-119 2.5 20.0
44.0 88.086.243.150.0µg/LDi-n-butyl phthalate 10-118 2.0 20.0
43.9 87.886.043.050.0µg/L4,6-Dinitro-2-methylphenol 10-181 2.0 20.0
38.5 77.075.237.650.0µg/L2,4-Dinitrophenol 10-191 2.3 20.0
43.0 86.084.842.450.0µg/L2,4-Dinitrotoluene 39-139 1.4 20.0
42.2 84.485.242.650.0µg/L2,6-Dinitrotoluene 50-158 0.9 20.0
45.6 91.290.445.250.0µg/LDi-n-Octyl Phthalate 10-146 0.8 20.0
Page 18 of 23Date:10/03/2023 02:04 PM
Page 51 of 58
Quality Control Data
23-265-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V38427QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V38382
LCS-V38382 LCSD-V38382Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
38.4 76.875.237.650.0µg/LFluoranthene 26-137 2.1 20.0
39.4 78.878.039.050.0µg/LFluorene 59-121 1.0 20.0
43.7 87.486.643.350.0µg/LHexachlorobenzene 10-152 0.9 20.0
30.3 60.661.230.650.0µg/LHexachlorobutadiene 24-116 0.9 20.0
39.7 79.476.638.350.0µg/LHexachlorocyclopentadiene 32-117 3.5 20.0
27.6 55.256.028.050.0µg/LHexachloroethane 40-113 1.4 20.0
44.6 89.289.844.950.0µg/LIndeno(1,2,3-cd)pyrene 10-171 0.6 20.0
31.1 62.262.431.250.0µg/LIsophorone 21-196 0.3 20.0
29.7 59.459.429.750.0µg/LNaphthalene 21-133 0.0 20.0
28.7 57.457.028.550.0µg/LNitrobenzene 35-180 0.6 20.0
33.1 66.266.433.250.0µg/L2-Nitrophenol 29-182 0.3 20.0
17.3 34.634.217.150.0µg/L4-Nitrophenol 10-132 1.1 20.0
48.1 96.297.048.550.0µg/LN-Nitrosodiphenylamine 69-152 0.8 20.0
36.2 72.471.835.950.0µg/LN-Nitroso-di-n-propylamine 10-230 0.8 20.0
44.6 89.286.043.050.0µg/LPentachlorophenol 14-176 3.6 20.0
39.2 78.477.638.850.0µg/LPhenanthrene 54-120 1.0 20.0
17.0 34.034.617.350.0µg/LPhenol 10-112 1.7 20.0
39.6 79.279.639.850.0µg/LPyrene 52-115 0.5 20.0
28.8 57.658.829.450.0µg/L1,2,4-Trichlorobenzene 44-142 2.0 20.0
38.7 77.477.038.550.0µg/L2,4,6-Trichlorophenol 37-144 0.5 20.0
75.875.82-Fluorobiphenyl (S)49-118
38.639.52-Fluorophenol (S)22-84
59.259.2Nitrobenzene-d5 (S)43-123
84.882.24-Terphenyl-d14 (S)49-151
86.282.92,4,6-Tribromophenol (S)31-144
Page 19 of 23Date:10/03/2023 02:04 PM
Page 52 of 58
Quality Control Data
23-265-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V38427QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V38382
LCS-V38382 LCSD-V38382Laboratory Control Sample & LCSD
LCSD
ResultParameter LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
24.725.2Phenol-d5 (S)10-63
Page 20 of 23Date:10/03/2023 02:04 PM
Page 53 of 58
Quality Control Data
23-265-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
EDB and DBCP by Microextraction GC/ECD
EPA-504.1
V38379QC Analytical Batch(es):
Analysis Method:
Analysis Description:
EPA-504.1(PREP)
QC Prep:V38326
Associated Lab Samples: 95986, 95987
LRB-V38326 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits
09/26/23 11:050.02000.00330<0.00330µg/L1,2-Dibromoethane
LCS-V38326 LCSD-V38326Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
0.244 97.693.60.2340.250µg/L1,2-Dibromoethane 70-130 4.1 20.0
V 96103-DUP-V38326Duplicate
Max RPDParameter AnalyzedRPDDUPResultResultUnits
20.0 09/26/23 12:300.0<0.0209< 0.0209µg/L1,2-Dibromoethane
V 95806-MS-V38326Matrix Spike
MS ResultParameter MaxRPDMS%RecMSDResultMSDSpike
Conc.
MS SpikeConc.ResultUnits %RecLimits
0.276 1060.260< 0.00343µg/L1,2-Dibromoethane 70-130
Page 21 of 23Date:10/03/2023 02:04 PM
Page 54 of 58
Quality Control Data
23-265-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Massachusetts EPH
MADEP-EPH
V38527QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAEPH (Prep)
QC Prep:V38500
Associated Lab Samples: 95986, 95987
LRB-V38500 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
09/30/23 12:2335028.2<28.2µg/LAliphatic C9-C18
09/30/23 12:23500124<124µg/LAliphatic C19-C36
09/30/23 12:2325061.2<61.2µg/LAromatic C11-C22
09/30/23 12:232-Fluorobiphenyl (S)76.7 40-140
09/30/23 12:232-Bromonaphthalene (S)76.5 40-140
09/30/23 12:23Chlorooctadecane (S)69.5 40-140
09/30/23 12:23OTP Surrogate (S)62.7 40-140
LCS-V38500 LCSD-V38500Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
256 42.651.5309600µg/LAliphatic C9-C18 40-140 18.7 50.0
670 83.798.8791800µg/LAliphatic C19-C36 40-140 16.5 50.0
1160 68.281.113801700µg/LAromatic C11-C22 40-140 17.3 50.0
75.782.22-Fluorobiphenyl (S)40-140
70.577.02-Bromonaphthalene (S)40-140
62.068.8Chlorooctadecane (S)40-140
57.368.3OTP Surrogate (S)40-140
Page 22 of 23Date:10/03/2023 02:04 PM
Page 55 of 58
Quality Control Data
23-265-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Minute Man #3
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V38341QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V38340
Associated Lab Samples: 95986, 95987
LRB-V38340 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlank
ResultUnits %
Recovery
% Rec
Limits
09/25/23 21:1250.011.5<11.5µg/LAliphatic C5-C8
09/25/23 21:1250.025.8<25.8µg/LAliphatic C9-C12
09/25/23 21:1250.04.02<4.02µg/LAromatic C9-C10
09/25/23 21:122,5-Dibromotoluene (FID) (S)115 70-130
09/25/23 21:122,5-Dibromotoluene (PID) (S)97.1 70-130
LCS-V38340 LCSD-V38340Laboratory Control Sample & LCSD
LCSD
ResultParameter MaxRPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units % Rec
Limits RPD
249 83.082.6248300µg/LAliphatic C5-C8 70-130 0.4 50.0
359 120123368300µg/LAliphatic C9-C12 70-130 2.4 50.0
106 106109109100µg/LAromatic C9-C10 70-130 2.7 50.0
1041032,5-Dibromotoluene (FID) (S)70-130
92.684.72,5-Dibromotoluene (PID) (S)70-130
Page 23 of 23Date:10/03/2023 02:04 PM
Page 56 of 58
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:23-265-0005
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 2.7C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:09/22/2023 10:36:18
Special precautions or instructions included?
Comments:
Page 57 of 58
Page 58 of 58

APPENDIX G
Historical Gauging and Ground Water Quality Data
Date: 03/30/2022 Facility ID#: 00-0-0000008172
Well No.
Date
Gauged
(mm/dd/yy)
Constructed
Well Depth
(ft. BGS)
Screened
Interval
(ft. BGS)
Bottom of
Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Elevation
Depth to
Ground Water
(ft. BGS)
Free Product
Thickness (ft.)
Ground Water
Elevation (ft.)Comments
05/12/04 10.11 0.00 118.62
05/31/06 12.59 0.00 116.14
06/19/07 11.61 0.00 117.12
12/06/07 NM NM NM
05/20/08 11.84 0.00 116.89
11/06/08 11.99 0.00 116.74
05/28/09 10.50 0.00 118.23
12/03/09 13.08 0.00 115.65
06/16/10 10.80 0.00 117.93
12/09/10 12.51 0.00 116.22
06/01/11 NM NM NM
11/08/11 13.54 0.00 115.19
06/06/12 13.35 0.00 115.38
12/05/12 14.26 0.00 114.47
06/04/13 13.71 0.00 115.02
12/02/13 13.72 0.00 115.01
06/18/14 11.33 0.00 117.40
12/08/14 13.24 0.00 115.49
06/03/15 11.07 0.00 117.66
12/15/15 11.15 0.00 117.58
06/08/16 11.48 0.00 117.25
02/20/17 12.42 0.00 116.31
05/16/18 12.50 0.00 116.23
11/13/18 12.94 0.00 115.79
11/07/19 Dry Dry Dry
06/06/12 15.50 0.45 114.26
12/05/12 14.98 0.68 113.81
06/04/13 12.94 0.00 116.43
12/02/13 13.81 0.06 115.61
06/18/14 12.92 NM NM
06/24/14 12.92 1.71 117.92
12/08/14 9.04 0.04 120.36
06/03/15 8.68 0.00 120.69
12/15/15 9.69 0.00 119.68
06/08/16 9.09 0.00 120.28
Notes:
• Ground water elevations relative to mean sea level; data reported in feet.
• Ground water elevations corrected for presence of free product with assumed density of 0.8581, if applicable.
• NM: Not measured.
• DMW-1, DMW-2 and DMW-7 were abandoned 06/29/06.
• During the December 5, 2012 monitoring event: MW-1R and MW-3R were covered; MW-21 could not be located; MW-20 was
located and sampled instead.
RBP-42 5.5 5.5 - 15.5 15.5 129.37
RBP-17 7 7 - 20 20 128.73
APPENDIX F
HISTORICAL GAUGING AND GROUND WATER QUALITY DATA
FORMER ROSEBORO BP STATION (INCIDENT NO. 6601)
Page 1 of 1
Date: 2/24/22 Facility ID#: 00-0-0000008172
Contaminant
of Concern
→
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 0.4 70 70 400 400
5,000 260,000 84,500 85,500 20,000 6,000 400 25,000 30,000 28,500 25,000
08/28/02 <1 <1 <1 <4 <2 <1 NR NR NR NR NR
05/12/04 <1.0 <1.0 <1.0 <2.0 6.1 <2.0 NR NR NR NR NR
05/31/06 <1.0 <1.0 <1.0 <3.0 4.7 <2.0 NR NR NR NR NR
06/21/07 <0.500 <0.500 <0.500 <0.500 1.15 <0.500 NR NR NR NR NR
12/06/07 NS NS NS NS NS NS NS NS NS NS NS
05/20/08 <1.0 <1.0 <1.0 1.68I 0.540I 1.10 <1.0 <1.0 <1.0 0.680I <1.0
11/06/08 <0.11 <0.10 0.27 J 1.2 J 0.66 J 0.80 JB <0.10 <0.15 <0.11 0.40 J <0.13
05/28/09 0.222 J <0.330 <0.670 <1.33 5.90 <1.00 <0.330 <0.330 <0.330 0.343 J <0.330
12/03/09 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 <0.220 <0.150 <0.220 0.483 J <0.180
06/16/10 <0.140 <0.190 <0.150 <0.220 5.63 <0.500 <0.220 <0.150 <0.220 <0.150 <0.180
12/09/10 <0.140 <0.190 0.286 J 0.617 J <0.250 <0.500 <0.220 <0.150 <0.220 0.543 J 0.189 J
06/01/11 32.9 169 31.0 114.3 <0.13 6.10 <0.16 1.1 2.7 12.2 3.2
11/08/11 31.9 53.3 26.9 97.3 <0.13 5.6 <0.16 1.2 2.7 12.1 3.1
06/06/12 18.8 31.4 14.2 70.0 <0.13 3.1 <0.16 0.69 1.3 8.6 2.2
12/05/12 47.5 199 64.4 224 <0.20 12.2 <0.20 2.1 6.4 26.0 6.1
06/04/13 23.6 101 28.9 109 <0.10 6.50 <0.10 1.1 2.8 12.9 3.1
12/02/13 10.1 49.7 13.5 51.2 <0.10 2.2 <0.10 0.38 J 1.2 4.5 1.2
06/19/14 <0.10 <0.10 <0.10 <0.20 3.1 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
12/09/14 63.5 530 94 446 <2.5 17.7 <2.5 2.8 J 8.0 J 50.8 12.8 J
06/04/15 12.2 39.5 15.1 56 <0.16 4.6 <0.16 0.74 1.9 8.9 1.8
12/15/15 18.4 49.6 26.8 94.6 <0.16 7.10 <0.16 1 2.9 15 1.7
06/08/16 10.8 65.8 8.1 37.2 <0.13 1.9 <0.13 0.36 J 0.63 2.8 0.65
02/20/17 1.40 6.4 1.5 5.7 <0.13 0.36 J <0.13 <0.13 <0.13 0.73 0.24 J
05/16/18 0.19 J 0.43 J <0.13 0.53 J <0.13 <0.13 NR NR NR NR NR
11/13/18 41.0 357 69.1 344 <1.3 16.5 NR NR NR NR NR
06/06/12 FP FP FP FP FP FP FP FP FP FP FP
12/05/12 FP FP FP FP FP FP FP FP FP FP FP
06/04/13 77.1 5,210 1,680 9,230 <5.0 347 <5.0 79.0 267 1,700 471
12/02/13 FP FP FP FP FP FP FP FP FP FP FP
06/18/14 FP FP FP FP FP FP FP FP FP FP FP
12/09/14 FP FP FP FP FP FP FP FP FP FP FP
06/04/15 0.23 J 1.3 1.1 3.5 <0.16 <0.12 <0.16 <0.12 <0.16 1.7 0.45 J
12/15/15 <0.17 <0.17 0.52 1.4 J <0.16 0.59 <0.16 <0.12 0.22 J 1 0.30 J
06/08/16 NS NS NS NS NS NS NS NS NS NS NS
Notes:
• < : Less than the reporting limit specified in the laboratory report.
• Results reported in µg/l (micrograms per liter).
• MAC: Maximum Allowable Concentration as specified in T15A NCAC 2L.0202.
• FP : Free product; NR: Not requested; NS: Not sampled.
• J: Estimated value; E: Value exceeds calibration range
• Refer to the laboratory analytical report for concentrations of compounds detected at levels below the MAC.
• GCL : Gross contamination level.
• Concentrations in bold face type exceed the MAC.
• Concentrations in italics exceed the GCL.
MW-42
MW-17 1,3,5-TrimethylbenzeneMAC (mg/l)
GCL (mg/l)MTBENaphthalene1,2-DichloroethaneIsopropylbenzenen-Propylbenzene1,2,4-TrimethylbenzeneAPPENDIX F
HISTORICAL GAUGING AND GROUND WATER QUALITY DATA
FORMER ROSEBORO BP (INCIDENT NO. 6601)
Analytical Method → EPA Method 6200B / EPA 602
Sample ID
BenzeneTolueneEthylbenzeneXylenesPage 1 of 1

APPENDIX H
Slug Test Data
0. 0.06 0.12 0.18 0.24 0.3
0.01
0.1
1.
10.
Time (min)Displacement (ft)WELL TEST ANALYSIS
Data Set: F:\...\MW-7 Graph.aqt
Date: 04/03/23 Time: 16:19:06
PROJECT INFORMATION
Company: Geological Resources, Inc.
Client: Minute Man #3
Project: 3148
Location: Roseboro, NC
Test Well: MW-7
Test Date: 03/27/2023
AQUIFER DATA
Saturated Thickness: 37.7 ft Anisotropy Ratio (Kz/Kr): 0.1
WELL DATA (MW-7)
Initial Displacement: 1.75 ft Static Water Column Height: 5.7 ft
Total Well Penetration Depth: 5.7 ft Screen Length: 5.7 ft
Casing Radius: 0.085 ft Well Radius: 0.25 ft
Gravel Pack Porosity: 0.3
SOLUTION
Aquifer Model: Unconfined Solution Method: Bouwer-Rice
K = 0.128 ft/min y0 = 2.049 ft
Page Item Value Remarks
NA Static depth to water (SDTW) from TOC SDTW 14.30 Test well
Initial DTW (IDTW) - after remove/introduce slug from TOC IDTW 16.05 Test well
Total well depth (TWD) TWD 20.00 Test well
Top of Casing Elevation (TOC) TOC 100.71 Test well
Highest historical ground water elevation at site (HGWE) HGWE 92.56 All site wells
Deepest well depth elevation (DWDE) DWDE 54.86 Deepest well
5 Project Name
Project location (city, state)
Test Well #
Date slug test conducted
6 H(o): Initial displacement (IDTW minus SDTW)H(o) 1.75 1.75' = For a 3' , 1-1/2 " bailer in a 2" dia. Well
H: Static water column height H 5.70 TWD minus SDTW
Well # MW-7 Test well ID
7 b: Saturated thickness of aquifer b 37.70
HGWE - DWDE
* If no telescoping well, use H
KV/KH: Vertical/Horizontal KV/KH 0.1 Use 0.1
8 D: Casing length 0 Use 0.0 If water table intersects screen
L: Well screen length 5.70 Use H If H is less than L
9 R(c ): Inside radius of well casing R(c) 0.085 Use 0.085 for 2" wells; use 0.167 for 4" wells
R(w): Well radius R(w) 0.2500 1/2 auger outside diameter in feet
R(sk): Well skin radius R(sk) 0.2500 1/2 auger outside diameter in feet
10 N(e): N(e): 0.3 Use 0.3
H(o): H(o) 1.75 Use H(o)
Minute Man #3
Roseboro, NC
MW-7
3/27/2023
AQTESOLV DATA ENTRY FORM
(For wells screened ACROSS water table)
File: AQTESOLV Data Entry Form
Minute Man #3
Well MW-7
Test Date 03/27/23
Initial DTW (ft) 14.30

Time Displacement
(min) (ft)
0.000 0.000
0.017 1.556
0.033 0.955
0.050 0.668
0.067 0.472
0.083 0.336
0.100 0.256
0.117 0.225
0.133 0.157
0.150 0.118
0.167 0.097
0.183 0.069
0.200 0.048
0.217 0.039
0.233 0.020
0.250 0.010
0.267 0.010
0.283 0.000

0. 0.08 0.16 0.24 0.32 0.4
0.01
0.1
1.
10.
Time (min)Displacement (ft)WELL TEST ANALYSIS
Data Set: F:\...\MW-8 Graph.aqt
Date: 04/03/23 Time: 16:19:25
PROJECT INFORMATION
Company: Geological Resources, Inc.
Client: Minute Man #3
Project: 3148
Location: Roseboro, NC
Test Well: MW-8
Test Date: 03/27/2023
AQUIFER DATA
Saturated Thickness: 37.7 ft Anisotropy Ratio (Kz/Kr): 0.1
WELL DATA (MW-8)
Initial Displacement: 1.75 ft Static Water Column Height: 5.65 ft
Total Well Penetration Depth: 5.65 ft Screen Length: 5.65 ft
Casing Radius: 0.85 ft Well Radius: 0.25 ft
Gravel Pack Porosity: 0.3
SOLUTION
Aquifer Model: Unconfined Solution Method: Bouwer-Rice
K = 2.557 ft/min y0 = 2.478 ft
Page Item Value Remarks
NA Static depth to water (SDTW) from TOC SDTW 14.35 Test well
Initial DTW (IDTW) - after remove/introduce slug from TOC IDTW 16.10 Test well
Total well depth (TWD) TWD 20.00 Test well
Top of Casing Elevation (TOC) TOC 100.76 Test well
Highest historical ground water elevation at site (HGWE) HGWE 92.56 All site wells
Deepest well depth elevation (DWDE) DWDE 54.86 Deepest well
5 Project Name
Project location (city, state)
Test Well #
Date slug test conducted
6 H(o): Initial displacement (IDTW minus SDTW)H(o) 1.75 1.75' = For a 3' , 1-1/2 " bailer in a 2" dia. Well
H: Static water column height H 5.65 TWD minus SDTW
Well # MW-8 Test well ID
7 b: Saturated thickness of aquifer b 37.70
HGWE - DWDE
* If no telescoping well, use H
KV/KH: Vertical/Horizontal KV/KH 0.1 Use 0.1
8 D: Casing length 0 Use 0.0 If water table intersects screen
L: Well screen length 5.65 Use H If H is less than L
9 R(c ): Inside radius of well casing R(c) 0.085 Use 0.085 for 2" wells; use 0.167 for 4" wells
R(w): Well radius R(w) 0.2500 1/2 auger outside diameter in feet
R(sk): Well skin radius R(sk) 0.2500 1/2 auger outside diameter in feet
10 N(e): N(e): 0.3 Use 0.3
H(o): H(o) 1.75 Use H(o)
3/27/2023
AQTESOLV DATA ENTRY FORM
(For wells screened ACROSS water table)
Minute Man #3
Roseboro, NC
MW-8
File: AQTESOLV Data Entry Form
Minute Man #3
Well MW-8
Test Date 03/27/23
Initial DTW (ft) 14.35

Time Displacement
(min) (ft)
0.000 0.000
0.017 0.464
0.033 1.369
0.050 0.945
0.067 0.669
0.083 0.483
0.100 0.346
0.117 0.257
0.133 0.197
0.150 0.148
0.167 0.109
0.183 0.089
0.200 0.069
0.217 0.049
0.233 0.039
0.250 0.030
0.267 0.020
0.283 0.010
0.300 0.010
0.317 0.000

0. 1.4 2.8 4.2 5.6 7.
0.01
0.1
1.
10.
Time (min)Displacement (ft)WELL TEST ANALYSIS
Data Set: F:\...\TW-1 Graph.aqt
Date: 04/03/23 Time: 16:19:36
PROJECT INFORMATION
Company: Geological Resources, Inc.
Client: Minute Man #3
Project: 3148
Location: Roseboro, NC
Test Well: TW-1
Test Date: 03/13/2023
AQUIFER DATA
Saturated Thickness: 37.7 ft Anisotropy Ratio (Kz/Kr): 0.1
WELL DATA (TW-1)
Initial Displacement: 1.75 ft Static Water Column Height: 31.61 ft
Total Well Penetration Depth: 31.61 ft Screen Length: 5. ft
Casing Radius: 0.085 ft Well Radius: 0.1875 ft
SOLUTION
Aquifer Model: Unconfined Solution Method: Bouwer-Rice
K = 0.002586 ft/min y0 = 2.115 ft
Page Item Value Remarks
NA Static depth to water (SDTW) from TOC SDTW 13.39 Test well (ft)
Initial DTW (IDTW) - after remove/introduce slug from TOC IDTW 15.14 Test well (ft)
Total well depth (TWD)TWD 45.00 Test well (ft)
Top of Casing Elevation (TOC)TOC 99.86 Test well (ft)
Highest ground water elevation at site (HGWE)HGWE 92.56 All site wells (ft)
Deepest well depth elevation (DWDE)DWDE 54.86 Deepest well (ft)
5 Project Name
Project location (city, state)
Test Well #
Date slug test conducted
6 H(o): Initial displacement (IDTW minus SDTW (ft))H(o)1.75 Use 1.75
H: Static water column height H 31.61 TWD minus SDTW (ft)
Well #TW-1 Test well ID
7 b: Saturated thickness of aquifer b 37.70
HGWE - DWDE
* If no telescoping well, use H
KV/KH: Vertical/Horizontal KV/KH 0.10 Use 0.1
8 D: Casing length D 26.61 TWD minus SDTW minus screen length (ft)
L: Well screen length L 5.00 Screen length (ft)
9 R(c ): Inside radius of well casing R(c)0.085 Use 0.085 for 2" wells; use 0.167 for 4" wells(ft)
R(w): Well radius R(w)0.1875 1/2 auger outside diameter (ft)
R(sk): Well skin radius R(sk)0.1875 1/2 auger outside diameter (ft)
3/13/2023
AQTESOLV DATA ENTRY FORM
(For wells screened BELOW water table)
Minute Man #3
Roseboro, NC
TW-1
File: AQTESOLV Data Entry Form
Minute Man #3
Well TW-1
Test Date 03/13/23
Initial DTW (ft) 13.39

Time Displacement
(min) (ft)
0.000 0.0000
0.017 0.2960
0.033 -0.0090
0.050 0.0000
0.067 -0.0590
0.083 0.0890
0.100 0.2960
0.117 0.3740
0.133 0.5020
0.150 0.4830
0.167 1.1820
0.183 1.0140
0.200 0.7780
0.217 1.3290
0.233 0.7090
0.250 1.1420
0.267 1.5560
0.283 1.6540
0.300 2.0180
0.317 1.9490
0.333 1.5460
0.350 1.5160
0.367 1.4870
0.383 1.4670
0.400 1.4470
0.417 1.4180
0.433 1.3980
0.450 1.3780
0.467 1.3590
0.483 1.3390
0.500 1.3190
0.517 1.3000
0.533 1.2800
0.550 1.2410
0.567 1.2210
Time Displacement
(min) (ft)
0.583 1.2210
0.600 1.2010
0.617 1.1820
0.633 1.1620
0.650 1.1420
0.667 1.1220
0.683 1.1130
0.700 1.0930
0.717 1.0730
0.733 1.0630
0.750 1.0440
0.767 1.0240
0.783 1.0140
0.800 0.9950
0.817 0.9750
0.833 0.9650
0.850 0.9450
0.867 0.9350
0.883 0.9160
0.900 0.9060
0.917 0.8860
0.933 0.8760
0.950 0.8570
0.967 0.8470
0.983 0.8370
1.000 0.8170
1.017 0.8080
1.033 0.7980
1.050 0.7880
1.067 0.7680
1.083 0.7580
1.100 0.7480
1.117 0.7390
1.133 0.7290
1.150 0.7190
1.167 0.7090
1.183 0.6990
1.200 0.6890
1.217 0.6800
1.233 0.6700
1.250 0.6600
Time Displacement
(min) (ft)
1.267 0.6400
1.283 0.6400
1.300 0.6300
1.317 0.6210
1.333 0.6110
1.350 0.6010
1.367 0.5910
1.383 0.5810
1.400 0.5710
1.417 0.5610
1.433 0.5520
1.450 0.5420
1.467 0.5320
1.483 0.5320
1.500 0.5220
1.517 0.5120
1.533 0.5020
1.550 0.4930
1.567 0.4930
1.583 0.4830
1.600 0.4730
1.617 0.4630
1.633 0.4630
1.650 0.4530
1.667 0.4430
1.683 0.4430
1.700 0.4340
1.717 0.4240
1.733 0.4140
1.750 0.4140
1.767 0.4040
1.783 0.4040
1.800 0.3940
1.817 0.3840
1.833 0.3840
1.850 0.3740
1.867 0.3740
1.883 0.3650
1.900 0.3550
1.917 0.3550
1.933 0.3450
Time Displacement
(min) (ft)
1.950 0.3450
1.967 0.3350
1.983 0.3350
2.000 0.3250
2.017 0.3250
2.033 0.3150
2.050 0.3150
2.067 0.3060
2.083 0.3060
2.100 0.2960
2.117 0.2960
2.133 0.2860
2.150 0.2860
2.167 0.2860
2.183 0.2760
2.200 0.2760
2.217 0.2660
2.233 0.2660
2.250 0.2660
2.267 0.2560
2.283 0.2560
2.300 0.2560
2.317 0.2560
2.333 0.2470
2.350 0.2470
2.367 0.2370
2.383 0.2370
2.400 0.2370
2.417 0.2270
2.433 0.2270
2.450 0.2270
2.467 0.2170
2.483 0.2170
2.500 0.2170
2.517 0.2070
2.533 0.2070
2.550 0.2070
2.567 0.1970
2.583 0.1970
2.600 0.1970
2.617 0.1870
Time Displacement
(min) (ft)
2.633 0.1870
2.650 0.1870
2.667 0.1780
2.683 0.1780
2.700 0.1780
2.717 0.1780
2.733 0.1780
2.750 0.1680
2.767 0.1680
2.783 0.1680
2.800 0.1580
2.817 0.1580
2.833 0.1580
2.850 0.1580
2.867 0.1480
2.883 0.1480
2.900 0.1480
2.917 0.1480
2.933 0.1480
2.950 0.1380
2.967 0.1380
2.983 0.1380
3.000 0.1380
3.017 0.1380
3.033 0.1280
3.050 0.1280
3.067 0.1280
3.083 0.1280
3.100 0.1280
3.117 0.1190
3.133 0.1190
3.150 0.1190
3.167 0.1190
3.183 0.1190
3.200 0.1090
3.217 0.1090
3.233 0.1090
3.250 0.1090
3.267 0.1090
3.283 0.1090
3.300 0.1090
Time Displacement
(min) (ft)
3.317 0.0990
3.333 0.0990
3.350 0.0990
3.367 0.0990
3.383 0.0990
3.400 0.0990
3.417 0.0990
3.433 0.0990
3.450 0.0890
3.467 0.0890
3.483 0.0890
3.500 0.0890
3.517 0.0890
3.533 0.0890
3.550 0.0790
3.567 0.0790
3.583 0.0790
3.600 0.0790
3.617 0.0790
3.633 0.0790
3.650 0.0790
3.667 0.0790
3.683 0.0790
3.700 0.0690
3.717 0.0690
3.733 0.0690
3.750 0.0690
3.767 0.0690
3.783 0.0690
3.800 0.0690
3.817 0.0690
3.833 0.0690
3.850 0.0690
3.867 0.0600
3.883 0.0600
3.900 0.0600
3.917 0.0600
3.933 0.0600
3.950 0.0600
3.967 0.0600
3.983 0.0600
Time Displacement
(min) (ft)
4.000 0.0600
4.017 0.0600
4.033 0.0600
4.050 0.0500
4.067 0.0500
4.083 0.0500
4.100 0.0500
4.117 0.0500
4.133 0.0500
4.150 0.0500
4.167 0.0500
4.183 0.0500
4.200 0.0500
4.217 0.0500
4.233 0.0400
4.250 0.0400
4.267 0.0400
4.283 0.0400
4.300 0.0500
4.317 0.0500
4.333 0.0500
4.350 0.0500
4.367 0.0400
4.383 0.0400
4.400 0.0400
4.417 0.0400
4.433 0.0400
4.450 0.0400
4.467 0.0400
4.483 0.0400
4.500 0.0400
4.517 0.0400
4.533 0.0400
4.550 0.0400
4.567 0.0400
4.583 0.0400
4.600 0.0400
4.617 0.0400
4.633 0.0300
4.650 0.0400
4.667 0.0300
Time Displacement
(min) (ft)
4.683 0.0300
4.700 0.0300
4.717 0.0300
4.733 0.0300
4.750 0.0300
4.767 0.0300
4.783 0.0300
4.800 0.0300
4.817 0.0300
4.833 0.0300
4.850 0.0300
4.867 0.0300
4.883 0.0300
4.900 0.0300
4.917 0.0300
4.933 0.0300
4.950 0.0300
4.967 0.0300
4.983 0.0300
5.000 0.0300
5.017 0.0200
5.033 0.0200
5.050 0.0200
5.067 0.0200
5.083 0.0200
5.100 0.0200
5.117 0.0200
5.133 0.0200
5.150 0.0200
5.167 0.0200
5.183 0.0200
5.200 0.0200
5.217 0.0200
5.233 0.0200
5.250 0.0200
5.267 0.0200
5.283 0.0200
5.300 0.0200
5.317 0.0200
5.333 0.0200
5.350 0.0200
Time Displacement
(min) (ft)
5.367 0.0200
5.383 0.0200
5.400 0.0200
5.417 0.0200
5.433 0.0200
5.450 0.0200
5.467 0.0200
5.483 0.0200
5.500 0.0200
5.517 0.0200
5.533 0.0200
5.550 0.0200
5.567 0.0200
5.583 0.0200
5.600 0.0200
5.617 0.0200
5.633 0.0100
5.650 0.0100
5.667 0.0100
5.683 0.0100
5.700 0.0100
5.717 0.0100
5.733 0.0100
5.750 0.0100
5.767 0.0100
5.783 0.0100
5.800 0.0100
5.817 0.0100
5.833 0.0100
5.850 0.0100
5.867 0.0100
5.883 0.0100
5.900 0.0100
5.917 0.0100
5.933 0.0100
5.950 0.0100
5.967 0.0100
5.983 0.0100
6.000 0.0100
6.017 0.0100
6.033 0.0100
Time Displacement
(min) (ft)
6.050 0.0100
6.067 0.0100
6.083 0.0100
6.100 0.0100
6.117 0.0100
6.133 0.0100
6.150 0.0100
6.167 0.0100
6.183 0.0100
6.200 0.0100
6.217 0.0100
6.233 0.0100
6.250 0.0100
6.267 0.0100
6.283 0.0100
6.300 0.0100
6.317 0.0100
6.333 0.0100
6.350 0.0100
6.367 0.0100
6.383 0.0100
6.400 0.0100
6.417 0.0100
6.433 0.0100
6.450 0.0100
6.467 0.0100
6.483 0.0000

APPENDIX I
Public Notification

•
•
••
October 13, 2023

Edwin W. Causey
County Manager, Sampson County
406 County Complex Road,
Building C, Suite 110
Clinton, NC 28328

Re: Comprehensive Site Assessment – Public Notice
Minute Man #3
Highway 24 & Highway 211
Roseboro, Sampson County, North Carolina
Incident #: 29769

Dear Mr. Causey,

In June 2012, a petroleum release was reported at the above referenced property. In conjunction with North
Carolina Department of Environmental Quality (NCDEQ) requirements, soil and ground water assessment
activities, including those for Site Check, Phase I Limited Site Assessment, and Comprehensive Site
Assessment (CSA), were conducted at the site.

Please find enclosed a copy of the executive summary and pertinent figures and tables associated with the
CSA Report for the above referenced site in accordance with the public notice requirements listed 15A
NCAC 2L .0114 of the Guidelines for Assessment and Corrective Action published by the UST Section of
NCDEQ.

Please do not hesitate to contact the undersigned at [phone], if you have any questions or comments.

Sincerely
Geological Resources, Inc.

Laura Minor
Project Manager

enclosure

•
•
••
October 13, 2023

Wanda Robinson
Health Director, Sampson County
360 County Complex Road
Building E, Suite 200
Clinton, NC 28328

Re: Comprehensive Site Assessment – Public Notice
Minute Man #3
Highway 24 & Highway 211
Roseboro, Sampson County, North Carolina
Incident #: 29769

Dear Ms. Robinson,

In June 2012, a petroleum release was reported at the above referenced property. In conjunction with North
Carolina Department of Environmental Quality (NCDEQ) requirements, soil and ground water assessment
activities, including those for Site Check, Phase I Limited Site Assessment, and Comprehensive Site
Assessment (CSA), were conducted at the site.

Please find enclosed a copy of the executive summary and pertinent figures and tables associated with the
CSA Report for the above referenced site in accordance with the public notice requirements listed 15A
NCAC 2L .0114 of the Guidelines for Assessment and Corrective Action published by the UST Section of
NCDEQ.

Please do not hesitate to contact the undersigned at [phone], if you have any questions or comments.

Sincerely
Geological Resources, Inc.

Laura Minor
Project Manager

enclosure

•
•
••
October 13, 2023

The Honorable Alice Butler
Mayor, Town of Roseboro
101 West Pleasant Street
Roseboro, NC 28382

Re: Comprehensive Site Assessment – Public Notice
Minute Man #3
Highway 24 & Highway 211
Roseboro, Sampson County, North Carolina
Incident #: 29769

Dear Mayor Butler,

In June 2012, a petroleum release was reported at the above referenced property. In conjunction with North
Carolina Department of Environmental Quality (NCDEQ) requirements, soil and ground water assessment
activities, including those for Site Check, Phase I Limited Site Assessment, and Comprehensive Site
Assessment (CSA), were conducted at the site.

Please find enclosed a copy of the executive summary and pertinent figures and tables associated with the
CSA Report for the above referenced site in accordance with the public notice requirements listed 15A
NCAC 2L .0114 of the Guidelines for Assessment and Corrective Action published by the UST Section of
NCDEQ.

Please do not hesitate to contact the undersigned at [phone], if you have any questions or comments.

Sincerely
Geological Resources, Inc.

Laura Minor
Project Manager

enclosure